[ { "Publication Type": "J", "Authors": "Gao, W; Emaminejad, S; Nyein, HYY; Challa, S; Chen, KV; Peck, A; Fahad, HM; Ota, H; Shiraki, H; Kiriya, D; Lien, DH; Brooks, GA; Davis, RW; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Wei; Emaminejad, Sam; Nyein, Hnin Yin Yin; Challa, Samyuktha; Chen, Kevin; Peck, Austin; Fahad, Hossain M.; Ota, Hiroki; Shiraki, Hiroshi; Kiriya, Daisuke; Lien, Der-Hsien; Brooks, George A.; Davis, Ronald W.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sensor technologies are essential to the realization of personalized medicine through continuously monitoring an individual's state of health(1-12). Sampling human sweat, which is rich in physiological information(13), could enable non-invasive monitoring. Previously reported sweat-based and other non-invasive biosensors either can only monitor a single analyte at a time or lack on-site signal processing circuitry and sensor calibration mechanisms for accurate analysis of the physiological state(14-18). Given the complexity of sweat secretion, simultaneous and multiplexed screening of target biomarkers is critical and requires full system integration to ensure the accuracy of measurements. Here we present a mechanically flexible and fully integrated (that is, no external analysis is needed) sensor array for multiplexed in situ perspiration analysis, which simultaneously and selectively measures sweat metabolites (such as glucose and lactate) and electrolytes (such as sodium and potassium ions), as well as the skin temperature (to calibrate the response of the sensors). Our work bridges the technological gap between signal transduction, conditioning (amplification and filtering), processing and wireless transmission in wearable biosensors by merging plastic-based sensors that interface with the skin with silicon integrated circuits consolidated on a flexible circuit board for complex signal processing. This application could not have been realized using either of these technologies alone owing to their respective inherent limitations. The wearable system is used to measure the detailed sweat profile of human subjects engaged in prolonged indoor and outdoor physical activities, and to make a real-time assessment of the physiological state of the subjects. This platform enables a wide range of personalized diagnostic and physiological monitoring applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3671, "Times Cited, All Databases": 4013, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2016, "Volume": 529, "Issue": 7587, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 509, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature16521", "DOI Link": "http://dx.doi.org/10.1038/nature16521", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368673800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Fatemi, V; Fang, S; Watanabe, K; Taniguchi, T; Kaxiras, E; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuan; Fatemi, Valla; Fang, Shiang; Watanabe, Kenji; Taniguchi, Takashi; Kaxiras, Efthimios; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional superconductivity in magic-angle graphene superlattices", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The behaviour of strongly correlated materials, and in particular unconventional superconductors, has been studied extensively for decades, but is still not well understood. This lack of theoretical understanding has motivated the development of experimental techniques for studying such behaviour, such as using ultracold atom lattices to simulate quantum materials. Here we report the realization of intrinsic unconventional superconductivity-which cannot be explained by weak electron-phonon interactions-in a two-dimensional superlattice created by stacking two sheets of graphene that are twisted relative to each other by a small angle. For twist angles of about 1.1 degrees-the first 'magic' angle-the electronic band structure of this 'twisted bilayer graphene' exhibits flat bands near zero Fermi energy, resulting in correlated insulating states at half-filling. Upon electrostatic doping of the material away from these correlated insulating states, we observe tunable zero-resistance states with a critical temperature of up to 1.7 kelvin. The temperature-carrier-density phase diagram of twisted bilayer graphene is similar to that of copper oxides (or cuprates), and includes dome-shaped regions that correspond to superconductivity. Moreover, quantum oscillations in the longitudinal resistance of the material indicate the presence of small Fermi surfaces near the correlated insulating states, in analogy with underdoped cuprates. The relatively high superconducting critical temperature of twisted bilayer graphene, given such a small Fermi surface (which corresponds to a carrier density of about 1011 per square centimetre), puts it among the superconductors with the strongest pairing strength between electrons. Twisted bilayer graphene is a precisely tunable, purely carbon-based, two-dimensional superconductor. It is therefore an ideal material for investigations of strongly correlated phenomena, which could lead to insights into the physics of high-critical-temperature superconductors and quantum spin liquids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5816, "Times Cited, All Databases": 6389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2018, "Volume": 556, "Issue": 7699, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 43, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature26160", "DOI Link": "http://dx.doi.org/10.1038/nature26160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429103300032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, B; Clark, G; Navarro-Moratalla, E; Klein, DR; Cheng, R; Seyler, KL; Zhong, D; Schmidgall, E; McGuire, MA; Cobden, DH; Yao, W; Xiao, D; Jarillo-Herrero, P; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren; Klein, Dahlia R.; Cheng, Ran; Seyler, Kyle L.; Zhong, Ding; Schmidgall, Emma; McGuire, Michael A.; Cobden, David H.; Yao, Wang; Xiao, Di; Jarillo-Herrero, Pablo; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the discovery of graphene(1), the family of two-dimensional materials has grown, displaying a broad range of electronic properties. Recent additions include semiconductors with spin-valley coupling(2), Ising superconductors(3-5) that can be tuned into a quantum metal(6), possible Mott insulators with tunable charge-density waves(7), and topological semimetals with edge transport(8,9). However, no two-dimensional crystal with intrinsic magnetism has yet been discovered(10-14); such a crystal would be useful in many technologies from sensing to data storage(15). Theoretically, magnetic order is prohibited in the two-dimensional isotropic Heisenberg model at finite temperatures by the Mermin-Wagner theorem(16). Magnetic anisotropy removes this restriction, however, and enables, for instance, the occurrence of two-dimensional Ising ferromagnetism. Here we use magneto-optical Kerr effect microscopy to demonstrate that monolayer chromium triiodide (CrI3) is an Ising ferromagnet with out-of-plane spin orientation. Its Curie temperature of 45 kelvin is only slightly lower than that of the bulk crystal, 61 kelvin, which is consistent with a weak interlayer coupling. Moreover, our studies suggest a layer-dependent magnetic phase, highlighting thickness-dependent physical properties typical of van der Waals crystals(17-19). Remarkably, bilayer CrI3 displays suppressed magnetization with a metamagnetic effect(20), whereas in trilayer CrI3 the interlayer ferromagnetism observed in the bulk crystal is restored. This work creates opportunities for studying magnetism by harnessing the unusual features of atomically thin materials, such as electrical control for realizing magnetoelectronics(12), and van der Waals engineering to produce interface phenomena(15).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4484, "Times Cited, All Databases": 4790, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2017, "Volume": 546, "Issue": 7657, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 270, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature22391", "DOI Link": "http://dx.doi.org/10.1038/nature22391", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402823400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghidiu, M; Lukatskaya, MR; Zhao, MQ; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Safe and powerful energy storage devices are becoming increasingly important. Charging times of seconds to minutes, with power densities exceeding those of batteries, can in principle be provided by electrochemical capacitors in particular, pseudocapacitors(1,2). Recent research has focused mainly on improving the gravimetric performance of the electrodes of such systems, but for portable electronics and vehicles volume is at a premium(3). The best volumetric capacitances of carbon-based electrodes are around 300 farads per cubic centimetre(4,5); hydrated ruthenium oxide can reach capacitances of 1,000 to 1,500 farads per cubic centimetre with great cydability, but only in thin films(6) Recently, electrodes made of two-dimensional titanium carbide (Ti3C2, a member of the 'MXene' family), produced by etching aluminium from titanium aluminium carbide (Ti3AlC2, a 'MAX' phase) in concentrated hydrofluoric acid, have been shown to have volumetric capacitances of over 300 farads per cubic centimetre(7,8). Here we report a method of producing this material using a solution of lithium fluoride and hydrochloric acid. The resulting hydrophilic material swells in volume when hydrated, and can be shaped like clay and dried into a highly conductive solid or rolled into films tens of micrometres thick. Additive-free films of this titanium carbide 'clay' have volumetric capacitances of up to 900 farads per cubic centimetre, with excellent cyclability and rate performances. This capacitance is almost twice that of our previous report(8), and our synthetic method also offers a much faster route to film production as well as the avoidance of handling hazardous concentrated hydrofluoric acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4646, "Times Cited, All Databases": 4967, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 4", "Publication Year": 2014, "Volume": 516, "Issue": 7529, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": "U171", "Article Number": null, "DOI": "10.1038/nature13970", "DOI Link": "http://dx.doi.org/10.1038/nature13970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346310800042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Kang, YJ; Huo, ZY; Zhu, ZW; Huang, WY; Xin, HLL; Snyder, JD; Li, DG; Herron, JA; Mavrikakis, M; Chi, MF; More, KL; Li, YD; Markovic, NM; Somorjai, GA; Yang, PD; Stamenkovic, VR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chen; Kang, Yijin; Huo, Ziyang; Zhu, Zhongwei; Huang, Wenyu; Xin, Huolin L.; Snyder, Joshua D.; Li, Dongguo; Herron, Jeffrey A.; Mavrikakis, Manos; Chi, Miaofang; More, Karren L.; Li, Yadong; Markovic, Nenad M.; Somorjai, Gabor A.; Yang, Peidong; Stamenkovic, Vojislav R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Crystalline Multimetallic nulloframes with Three-Dimensional Electrocatalytic Surfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control of structure at the atomic level can precisely and effectively tune catalytic properties of materials, enabling enhancement in both activity and durability. We synthesized a highly active and durable class of electrocatalysts by exploiting the structural evolution of platinum-nickel (Pt-Ni) bimetallic nullocrystals. The starting material, crystalline PtNi3 polyhedra, transforms in solution by interior erosion into Pt3Ni nulloframes with surfaces that offer three-dimensional molecular accessibility. The edges of the Pt-rich PtNi3 polyhedra are maintained in the final Pt3Ni nulloframes. Both the interior and exterior catalytic surfaces of this open-framework structure are composed of the nullosegregated Pt-skin structure, which exhibits enhanced oxygen reduction reaction (ORR) activity. The Pt3Ni nulloframe catalysts achieved a factor of 36 enhancement in mass activity and a factor of 22 enhancement in specific activity, respectively, for this reaction (relative to state-of-the-art platinum-carbon catalysts) during prolonged exposure to reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2401, "Times Cited, All Databases": 2591, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2014, "Volume": 343, "Issue": 6177, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1339, "End Page": 1343, "Article Number": null, "DOI": "10.1126/science.1249061", "DOI Link": "http://dx.doi.org/10.1126/science.1249061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333108500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rodenas, T; Luz, I; Prieto, G; Seoane, B; Miro, H; Corma, A; Kapteijn, F; Xamena, FXLI; Gascon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rodenas, Tania; Luz, Ignacio; Prieto, Gonzalo; Seoane, Beatriz; Miro, Hozanna; Corma, Avelino; Kapteijn, Freek; Llabres i Xamena, Francesc X.; Gascon, Jorge", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework nullosheets in polymer composite materials for gas separation", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Composites incorporating two-dimensional nullostructures within polymeric matrices have potential as functional components for several technologies, including gas separation. Prospectively, employing metal-organic frameworks (MOFs) as versatile nullofillers would notably broaden the scope of functionalities. However, synthesizing MOFs in the form of freestanding nullosheets has proved challenging. We present a bottom-up synthesis strategy for dispersible copper 1,4-benzenedicarboxylate MOF lamellae of micrometre lateral dimensions and nullometre thickness. Incorporating MOF nullosheets into polymer matrices endows the resultant composites with outstanding CO2 separation performance from CO2/CH4 gas mixtures, together with an unusual and highly desired increase in the separation selectivity with pressure. As revealed by tomographic focused ion beam scanning electron microscopy, the unique separation behaviour stems from a superior occupation of the membrane cross-section by the MOF nullosheets as compared with isotropic crystals, which improves the efficiency of molecular discrimination and eliminates unselective permeation pathways. This approach opens the door to ultrathin MOF-polymer composites for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1787, "Times Cited, All Databases": 1899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 48, "End Page": 55, "Article Number": null, "DOI": "10.1038/NMAT4113", "DOI Link": "http://dx.doi.org/10.1038/NMAT4113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346430100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alhabeb, M; Maleski, K; Anasori, B; Lelyukh, P; Clark, L; Sin, S; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alhabeb, Mohamed; Maleski, Kathleen; Anasori, Babak; Lelyukh, Pavel; Clark, Leah; Sin, Saleesha; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2TX MXene)", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal carbides, carbonitrides, and nitrides (MXenes) were discovered in 2011. Since the original discovery, more than 20 different compositions have been synthesized by the selective etching of MAX phase and other precursors and many more theoretically predicted. They offer a variety of different properties, making the family promising candidates in a wide range of applications, such as energy storage, electromagnetic interference shielding, water purification, electrocatalysis, and medicine. These solution-processable materials have the potential to be highly scalable, deposited by spin, spray, or dip coating, painted or printed, or fabricated in a variety of ways. Due to this promise, the amount of research on MXenes has been increasing, and methods of synthesis and processing are expanding quickly. The fast evolution, of the material can also be noticed in the wide range of synthesis and processing protocols that determine the yield of delamination, as well as the quality of the 2D flakes produced. Here we describe the experimental methods and best practices we use to synthesize the most studied MXene, titanium carbide (Ti3C2Tx), using different etchants and delamination methods. We also explain effects of synthesis parameters on the size and quality of Ti3C2Tx and suggest the optimal processes for the desired application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3628, "Times Cited, All Databases": 3822, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2017, "Volume": 29, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7633, "End Page": 7644, "Article Number": null, "DOI": "10.1021/acs.chemmater.7b02847", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.7b02847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411918900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Sun, Q; Lin, L; Wang, J; Zhang, CQ; Xia, CH; Bao, T; Wan, JJ; Huang, R; Zou, J; Yu, CZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chao; Sun, Qiang; Lin, Lina; Wang, Jing; Zhang, Chaoqi; Xia, Chunhong; Bao, Tong; Wan, Jingjing; Huang, Rong; Zou, Jin; Yu, Chengzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ternary MOF-on-MOF heterostructures with controllable architectural and compositional complexity via multiple selective assembly", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Assembly of different metal-organic framework (MOF) building blocks into hybrid MOF-on-MOF heterostructures is promising in chemistry and materials science, however the development of ternary MOF-on-MOF heterostructures with controllable architectural and compositional complexity is challenging. Here we report the synthesis of three types of ternary MOF-on-MOF heterostructures via a multiple selective assembly strategy. This strategy relies on the choice of one host MOF with more than one facet that can arrange the growth of a guest MOF, where the arrangement is site-selective without homogenous growth of guest MOF or homogenous coating of guest on host MOF. The growth of guest MOF on a selected site of host MOF in each step provides the opportunity to further vary the combinations of arrangements in multiple steps, leading to ternary MOF-on-MOF heterostructures with tunable complexity. The developed strategy paves the way towards the rational design of intricate and unprecedented MOF-based superstructures for various applications. Assembly of MOF-on-MOF hybrids with complex structures and properties is of interest, but achieving sophisticated ternary heterostructures is challenging. Here, the authors synthesize three types of ternary MOF-on-MOF heterostructures with tunable complexity via a multiple selective assembly strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4971, "DOI": "10.1038/s41467-020-18776-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18776-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577122600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Protesescu, L; Yakunin, S; Bodnarchuk, MI; Krieg, F; Caputo, R; Hendon, CH; Yang, RX; Walsh, A; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.; Krieg, Franziska; Caputo, Riccarda; Hendon, Christopher H.; Yang, Ruo Xi; Walsh, Aron; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halides perovskites, such as hybrid organic-inorganic CH3NH3PbI3, are newcomer optoelectronic materials that have attracted enormous attention as solution-deposited absorbing layers in solar cells with power conversion efficiencies reaching 20%. Herein we demonstrate a new avenue for halide perovskites by designing highly luminescent perovskite-based colloidal quantum dot materials. We have synthesized monodisperse colloidal nullocubes (4-15 nm edge lengths) of fully inorganic cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I or mixed halide systems Cl/Br and Br/I) using inexpensive commercial precursors. Through compositional modulations and quantum size-effects, the bandgap energies and emission spectra are readily tunable over the entire visible spectral region of 410-700 nm. The photoluminescence of CsPbX3 nullocrystals is characterized by narrow emission line-widths of 12-42 nm, wide color gamut covering up to 140% of the NTSC color standard, high quantum yields of up to 90%, and radiative lifetimes in the range of 1-29 ns. The compelling combination of enhanced optical properties and chemical robustness makes CsPbX3 nullocrystals appealing for optoelectronic applications, particularly for blue and green spectral regions (410-530 nm), where typical metal chalcogenide-based quantum dots suffer from photodegradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 7392, "Times Cited, All Databases": 7899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3692, "End Page": 3696, "Article Number": null, "DOI": "10.1021/nl5048779", "DOI Link": "http://dx.doi.org/10.1021/nl5048779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356316900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Joshi, RK; Carbone, P; Wang, FC; Kravets, VG; Su, Y; Grigorieva, IV; Wu, HA; Geim, AK; Nair, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Joshi, R. K.; Carbone, P.; Wang, F. C.; Kravets, V. G.; Su, Y.; Grigorieva, I. V.; Wu, H. A.; Geim, A. K.; Nair, R. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene-based materials can have well-defined nullometer pores and can exhibit low frictional water flow inside them, making their properties of interest for filtration and separation. We investigate permeation through micrometer-thick laminates prepared by means of vacuum filtration of graphene oxide suspensions. The laminates are vacuum-tight in the dry state but, if immersed in water, act as molecular sieves, blocking all solutes with hydrated radii larger than 4.5 angstroms. Smaller ions permeate through the membranes at rates thousands of times faster than what is expected for simple diffusion. We believe that this behavior is caused by a network of nullocapillaries that open up in the hydrated state and accept only species that fit in. The anomalously fast permeation is attributed to a capillary-like high pressure acting on ions inside graphene capillaries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2099, "Times Cited, All Databases": 2307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2014, "Volume": 343, "Issue": 6172, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 752, "End Page": 754, "Article Number": null, "DOI": "10.1126/science.1245711", "DOI Link": "http://dx.doi.org/10.1126/science.1245711", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331557800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, MQ; Ren, CE; Ling, Z; Lukatskaya, MR; Zhang, CF; Van Aken, KL; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng-Qiang; Ren, Chang E.; Ling, Zheng; Lukatskaya, Maria R.; Zhang, Chuanfang; Van Aken, Katherine L.; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible MXene/Carbon nullotube Composite Paper with High Volumetric Capacitance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free-standing and flexible sandwich-like MXene/carbon nullotube (CNT) paper, composed of alternating MXene and CNT layers, is fabricated using a simple filtration method. These sandwich-like papers exhibit high volumetric capacitances, good rate performances, and excellent cycling stability when employed as electrodes in supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1194, "Times Cited, All Databases": 1263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 27, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 339, "End Page": 345, "Article Number": null, "DOI": "10.1002/adma.201404140", "DOI Link": "http://dx.doi.org/10.1002/adma.201404140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347698300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nitta, N; Wu, FX; Lee, JT; Yushin, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae; Yushin, Gleb", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Li-ion battery materials: present and future", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This review covers key technological developments and scientific challenges for a broad range of Li-ion battery electrodes. Periodic table and potential/capacity plots are used to compare many families of suitable materials. Performance characteristics, current limitations, and recent breakthroughs in the development of commercial intercalation materials such as lithium cobalt oxide (LCO), lithium nickel cobalt manganese oxide (NCM), lithium nickel cobalt aluminum oxide (NCA), lithium iron phosphate (LFP), lithium titanium oxide (LTO) and others are contrasted with that of conversion materials, such as alloying anodes (Si, Ge, Sn, etc.), chalcogenides (S, Se, Te), and metal halides (F, Cl, Br, I). New polyanion cathode materials are also discussed. The cost, abundance, safety, Li and electron transport, volumetric expansion, material dissolution, and surface reactions for each type of electrode materials are described. Both general and specific strategies to overcome the current challenges are covered and categorized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5499, "Times Cited, All Databases": 6093, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 18, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 252, "End Page": 264, "Article Number": null, "DOI": "10.1016/j.mattod.2014.10.040", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.10.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354392300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Wan, CJ; Yang, YS; Yang, H; Wang, SC; Dai, ZD; Ji, KJ; Jiang, H; Chen, XD; Long, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yang; Wan, Changjin; Yang, Yongsheng; Yang, Hui; Wang, Shancheng; Dai, Zhendong; Ji, Keju; Jiang, Hui; Chen, Xiaodong; Long, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stretchable, Elastic, and Ionic Conductive Hydrogel for Artificial Soft Electronics", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High conductivity, large mechanical strength, and elongation are important parameters for soft electronic applications. However, it is difficult to find a material with balanced electronic and mechanical performance. Here, a simple method is developed to introduce ion-rich pores into strong hydrogel matrix and fabricate a novel ionic conductive hydrogel with a high level of electronic and mechanical properties. The proposed ionic conductive hydrogel is achieved by physically cross-linking the tough biocompatible polyvinyl alcohol (PVA) gel as the matrix and embedding hydroxypropyl cellulose (HPC) biopolymer fibers inside matrix followed by salt solution soaking. The wrinkle and dense structure induced by salting in PVA matrix provides large stress (1.3 MPa) and strain (975%). The well-distributed porous structure as well as ion migration-facilitated ion-rich environment generated by embedded HPC fibers dramatically enhances ionic conductivity (up to 3.4 S m(-1), at f = 1 MHz). The conductive hybrid hydrogel can work as an artificial nerve in a 3D printed robotic hand, allowing passing of stable and tunable electrical signals and full recovery under robotic hand finger movements. This natural rubber-like ionic conductive hydrogel has a promising application in artificial flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 771, "Times Cited, All Databases": 801, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2019, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806220, "DOI": "10.1002/adfm.201806220", "DOI Link": "http://dx.doi.org/10.1002/adfm.201806220", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454703900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Neal, AT; Zhu, Z; Luo, Z; Xu, XF; Tománek, D; Ye, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Han; Neal, Adam T.; Zhu, Zhen; Luo, Zhe; Xu, Xianfan; Tomanek, David; Ye, Peide D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce the 2D counterpart of layered black phosphorus, which we call phosphorene, as an unexplored p-type semiconducting material. Same as graphene and MoS2, single-layer phosphorene is flexible and can be mechanically exfoliated. We find phosphorene to be stable and, unlike graphene, to have an inherent, direct, and appreciable band gap. Our ab initio calculations indicate that the band gap is direct, depends on the number of layers and the in-layer strain, and is significantly larger than the bulk value of 0.31-036 eV. The observed photoluminescence peak of single-layer phosphorene in the visible optical range confirms that the band gap is larger than that of the bulk system. Our transport studies indicate a hole mobility that reflects the structural anisotropy of phosphorene and complements n-type MoS2. At room temperature, our few-layer phosphorene field-effect transistors with 1.0 mu m channel length display a high on-current of 194 mA/mm, a high hole field-effect mobility of 286 cm(2) N.s, and an on/off ratio of up to 10(4). We demonstrate the possibility of phosphorene integration by constructing a 2D CMOS inverter consisting of phosphorene PMOS and MoS2 NMOS transistors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5563, "Times Cited, All Databases": 5930, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4033, "End Page": 4041, "Article Number": null, "DOI": "10.1021/nn501226z", "DOI Link": "http://dx.doi.org/10.1021/nn501226z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334990600102", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HJ; Shi, R; Zhao, YX; Bian, T; Zhao, YF; Zhou, C; Waterhouse, GIN; Wu, LZ; Tung, CH; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Huijun; Shi, Run; Zhao, Yunxuan; Bian, Tong; Zhao, Yufei; Zhou, Chao; Waterhouse, Geoffrey I. N.; Wu, Li-Zhu; Tung, Chen-Ho; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkali-Assisted Synthesis of Nitrogen Deficient Graphitic Carbon Nitride with Tunable Band Structures for Efficient Visible-Light-Driven Hydrogen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile synthetic strategy for nitrogen-deficient graphitic carbon nitride (g-C3Nx) is established, involving a simple alkali-assisted thermal polymerization of urea, melamine, or thiourea. In situ introduced nitrogen vacancies significantly red-shift the absorption edge of g-C3Nx, with the defect concentration depending on the alkali to nitrogen precursor ratio. The g-C3Nx products show superior visible-light photocatalytic performance compared to pristine g-C3N4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1900, "Times Cited, All Databases": 1950, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2017, "Volume": 29, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605148, "DOI": "10.1002/adma.201605148", "DOI Link": "http://dx.doi.org/10.1002/adma.201605148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400024500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, JR; Gao, GP; Li, FT; Ma, TY; Du, AJ; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Jingrun; Gao, Guoping; Li, Fa-Tang; Ma, Tian-Yi; Du, Aijun; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalable and sustainable solar hydrogen production through photocatalytic water splitting requires highly active and stable earth-abundant co-catalysts to replace expensive and rare platinum. Here we employ density functional theory calculations to direct atomic-level exploration, design and fabrication of a MXene material, Ti3C2 nulloparticles, as a highly efficient co-catalyst. Ti3C2 nulloparticles are rationally integrated with cadmium sulfide via a hydrothermal strategy to induce a super high visible-light photocatalytic hydrogen production activity of 14,342 mu mol h(-1) g(-1) and an apparent quantum efficiency of 40.1% at 420 nm. This high performance arises from the favourable Fermi level position, electrical conductivity and hydrogen evolution capacity of Ti3C2 nulloparticles. Furthermore, Ti3C2 nulloparticles also serve as an efficient co-catalyst on ZnS or ZnxCd1-xS. This work demonstrates the potential of earth-abundant MXene family materials to construct numerous high performance and low-cost photocatalysts/photoelectrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1707, "Times Cited, All Databases": 1770, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13907, "DOI": "10.1038/ncomms13907", "DOI Link": "http://dx.doi.org/10.1038/ncomms13907", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391020200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JJ; Wang, XM; Li, SR; Liu, J; Guo, YM; Niu, GD; Yao, L; Fu, YH; Gao, L; Dong, QS; Zhao, CY; Leng, MY; Ma, FS; Liang, WX; Wang, LD; Jin, SY; Han, JB; Zhang, LJ; Etheridge, J; Wang, JB; Yan, YF; Sargent, EH; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jiajun; Wang, Xiaoming; Li, Shunran; Liu, Jing; Guo, Yueming; Niu, Guangda; Yao, Li; Fu, Yuhao; Gao, Liang; Dong, Qingshun; Zhao, Chunyi; Leng, Meiying; Ma, Fusheng; Liang, Wenxi; Wang, Liduo; Jin, Shengye; Han, Junbo; Zhang, Lijun; Etheridge, Joanne; Wang, Jianbo; Yan, Yanfa; Sargent, Edward H.; Tang, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable emission of warm-white light from lead-free halide double perovskites", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lighting accounts for one-fifth of global electricity consumption(1). Single materials with efficient and stable white-light emission are ideal for lighting applications, but photon emission covering the entire visible spectrum is difficult to achieve using a single material. Metal halide perovskites have outstanding emission properties(2,3); however, the best-performing materials of this type contain lead and have unsatisfactory stability. Here we report a lead-free double perovskite that exhibits efficient and stable white-light emission via self-trapped excitons that originate from the Jahn-Teller distortion of the AgCl6 octahedron in the excited state. By alloying sodium cations into Cs2AgInCl6, we break the dark transition (the inversion-symmetry-induced parity-forbidden transition) by manipulating the parity of the wavefunction of the self-trapped exciton and reduce the electronic dimensionality of the semiconductor(4). This leads to an increase in photoluminescence efficiency by three orders of magnitude compared to pure Cs2AgInCl6. The optimally alloyed Cs-2(Ag0.60Na0.40) InCl6 with 0.04 per cent bismuth doping emits warm-white light with 86 +/- 5 per cent quantum efficiency and works for over 1,000 hours. We anticipate that these results will stimulate research on singleemitter-based white-light-emitting phosphors and diodes for next-generation lighting and display technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1705, "Times Cited, All Databases": 1781, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2018, "Volume": 563, "Issue": 7732, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 541, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0691-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0691-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450960000050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XQ; Zhao, ZP; Cao, L; Chen, Y; Zhu, EB; Lin, ZY; Li, MF; Yan, AM; Zettl, A; Wang, YM; Duan, XF; Mueller, T; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xiaoqing; Zhao, Zipeng; Cao, Liang; Chen, Yu; Zhu, Enbo; Lin, Zhaoyang; Li, Mufan; Yan, Aiming; Zettl, Alex; Wang, Y. Morris; Duan, Xiangfeng; Mueller, Tim; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bimetallic platinum-nickel (Pt-Ni) nullostructures represent an emerging class of electrocatalysts for oxygen reduction reaction (ORR) in fuel cells, but practical applications have been limited by catalytic activity and durability. We surface-doped Pt3Ni octahedra supported on carbon with transition metals, termed M-Pt3Ni/C, where M is vanadium, chromium, manganese, iron, cobalt, molybdenum (Mo), tungsten, or rhenium. The Mo-Pt3Ni/C showed the best ORR performance, with a specific activity of 10.3 mA/cm(2) and mass activity of 6.98 A/mg(Pt), which are 81- and 73-fold enhancements compared with the commercial Pt/C catalyst (0.127 mA/cm(2) and 0.096 A/mg(Pt)). Theoretical calculations suggest that Mo prefers subsurface positions near the particle edges in vacuum and surface vertex/edge sites in oxidizing conditions, where it enhances both the performance and the stability of the Pt3Ni catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1665, "Times Cited, All Databases": 1783, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2015, "Volume": 348, "Issue": 6240, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1230, "End Page": 1234, "Article Number": null, "DOI": "10.1126/science.aaa8765", "DOI Link": "http://dx.doi.org/10.1126/science.aaa8765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356011500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Friebel, D; Louie, MW; Bajdich, M; Sanwald, KE; Cai, Y; Wise, AM; Cheng, MJ; Sokaras, D; Weng, TC; Alonso-Mori, R; Davis, RC; Bargar, JR; Norskov, JK; Nilsson, A; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Friebel, Daniel; Louie, Mary W.; Bajdich, Michal; Sanwald, Kai E.; Cai, Yun; Wise, Anna M.; Cheng, Mu-Jeng; Sokaras, Dimosthenis; Weng, Tsu-Chien; Alonso-Mori, Roberto; Davis, Ryan C.; Bargar, John R.; Norskov, Jens K.; Nilsson, Anders; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active catalysts for the oxygen evolution reaction (OER) are required for the development of photoelectrochemical devices that generate hydrogen efficiently from water using solar energy. Here, we identify the origin of a 500-fold OER activity enhancement that can be achieved with mixed (Ni,Fe)oxyhydroxides (Ni1-xFexOOH) over their pure Ni and Fe parent compounds, resulting in one of the most active currently known OER catalysts in alkaline electrolyte. Operando X-ray absorption spectroscopy (XAS) using high energy resolution fluorescence detection (HERFD) reveals that Fe3+ in Ni1-xFexOOH occupies octahedral sites with unusually short Fe-O bond distances, induced by edge-sharing with surrounding [NiO6] octahedra. Using computational methods, we establish that this structural motif results in near optimal adsorption energies of OER intermediates and low overpotentials at Fe sites. By contrast, Ni sites in Ni1-xFexOOH are not active sites for the oxidation of water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2153, "Times Cited, All Databases": 2270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2015, "Volume": 137, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1305, "End Page": 1313, "Article Number": null, "DOI": "10.1021/ja511559d", "DOI Link": "http://dx.doi.org/10.1021/ja511559d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348690100042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WS; Noh, JH; Jeon, NJ; Kim, YC; Ryu, S; Seo, J; Seok, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Woon Seok; Noh, Jun Hong; Jeon, Nam Joong; Kim, Young Chan; Ryu, Seungchan; Seo, Jangwon; Seok, Sang Il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance photovoltaic perovskite layers fabricated through intramolecular exchange", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The band gap of formamidinium lead iodide (FAPbI(3)) perovskites allows broader absorption of the solar spectrum relative to conventional methylammonium lead iodide (MAPbI(3)). Because the optoelectronic properties of perovskite films are closely related to film quality, deposition of dense and uniform films is crucial for fabricating high-performance perovskite solar cells (PSCs). We report an approach for depositing high-quality FAPbI(3) films, involving FAPbI(3) crystallization by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide. This process produces FAPbI(3) films with (111)-preferred crystallographic orientation, large-grained dense microstructures, and flat surfaces without residual PbI2. Using films prepared by this technique, we fabricated FAPbI(3)-based PSCs with maximum power conversion efficiency greater than 20%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5584, "Times Cited, All Databases": 5939, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2015, "Volume": 348, "Issue": 6240, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1234, "End Page": 1237, "Article Number": null, "DOI": "10.1126/science.aaa9272", "DOI Link": "http://dx.doi.org/10.1126/science.aaa9272", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356011500049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Zhang, KN; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jia; Zhang, Kaina; Zhang, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of antibiotics on microplastics", "Source Title": "ENVIRONMENTAL POLLUTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastics and antibiotics are two classes of emerging contaminullts with proposed negative impacts to aqueous ecosystems. Adsorption of antibiotics on microplastics may result in their long-range transport and may cause compound combination effects. In this study, we investigated the adsorption of 5 antibiotics [sulfadiazine (SDZ), amoxicillin (AMX), tetracycline (TC), ciprofloxacin (CIP), and trimethoprim (TMP)] on 5 types of microplastics [polyethylene (PE), polystyrene (PS), polypropylene (PP), polyamide (PA), and polyvinyl chloride (PVC)] in the freshwater and seawater systems. Scanning Electron Microscope (SEM) and X-ray diffractometer (XRD) analysis revealed that microplastics have different surface characterizes and various degrees of crystalline. Adsorption isotherms demonstrated that PA had the strongest adsorption capacity for antibiotics with distribution coefficient (K-d) values ranged from 7.36 +/- 0.257 to 756 +/- 48.0 L kg(-1) in the freshwater system, which can be attributed to its porous structure and hydrogen bonding. Relatively low adsorption capacity was observed on other four microplastics. The adsorption amounts of 5 antibiotics on PS, PE, PP, and PVC decreased in the order of CIP > AMX > TMP > SDZ > TC with K-f correlated positively with octanol-water partition coefficients (Log K-OW). Comparing to freshwater system, adsorption capacity in seawater decreased significantly and no adsorption was observed for CIP and AMX. Our results indicated that commonly observed polyamide particles can serve as a carrier of antibiotics in the aquatic environment. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 928, "Times Cited, All Databases": 1062, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 237, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 460, "End Page": 467, "Article Number": null, "DOI": "10.1016/j.envpol.2018.02.050", "DOI Link": "http://dx.doi.org/10.1016/j.envpol.2018.02.050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431158900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wang, T; Pohl, D; Rellinghaus, B; Dong, RH; Liu, SH; Zhuang, XD; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wang, Tao; Pohl, Darius; Rellinghaus, Bernd; Dong, Renhao; Liu, Shaohua; Zhuang, Xiaodong; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of MoS2/Ni3S2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve sustainable production of H-2 fuel through water splitting, low-cost electrocatalysts for the hydrogen-evolution reaction (HER) and the oxygen-evolution reaction (OER) are required to replace Pt and IrO2 catalysts. Herein, for the first time, we present the interface engineering of novel MoS2/Ni3S2 heterostructures, in which abundant interfaces are formed. For OER, such MoS2/Ni3S2 heterostructures show an extremely low overpotential of ca. 218 mV at 10 mAcm(-2), which is superior to that of the state-of-the-art OER electrocatalysts. Using MoS2/Ni3S2 heterostructures as bifunctional electrocatalysts, an alkali electrolyzer delivers a current density of 10 mAcm(-2) at a very low cell voltage of ca. 1.56 V. In combination with DFT calculations, this study demonstrates that the constructed interfaces synergistically favor the chemisorption of hydrogen and oxygen-containing intermediates, thus accelerating the overall electrochemical water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1508, "Times Cited, All Databases": 1520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2016, "Volume": 55, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6702, "End Page": 6707, "Article Number": null, "DOI": "10.1002/anie.201602237", "DOI Link": "http://dx.doi.org/10.1002/anie.201602237", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377921300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, LZ; Zhang, N; Guo, SJ; Zhang, X; Li, J; Yao, JL; Wu, T; Lu, G; Ma, JY; Su, D; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Lingzheng; Zhang, null; Guo, Shaojun; Zhang, Xu; Li, Jing; Yao, Jianlin; Wu, Tao; Lu, Gang; Ma, Jing-Yuan; Su, Dong; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biaxially strained PtPb/Pt core/shell nulloplate boosts oxygen reduction catalysis", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compressive surface strains have been necessary to boost oxygen reduction reaction (ORR) activity in core/shell M/platinum (Pt) catalysts (where M can be nickel, cobalt, or iron). We report on a class of platinum-lead/platinum (PtPb/Pt) core/shell nulloplate catalysts that exhibit large biaxial strains. The stable Pt (110) facets of the nulloplates have high ORR specific and mass activities that reach 7.8 milliampere (mA) per centimeter squared and 4.3 ampere per milligram of platinum at 0.9 volts versus the reversible hydrogen electrode (RHE), respectively. Density functional theory calculations reveal that the edge-Pt and top (bottom)-Pt (110) facets undergo large tensile strains that help optimize the Pt-O bond strength. The intermetallic core and uniform four layers of Pt shell of the PtPb/Pt nulloplates appear to underlie the high endurance of these catalysts, which can undergo 50,000 voltage cycles with negligible activity decay and no apparent structure and composition changes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1351, "Times Cited, All Databases": 1430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2016, "Volume": 354, "Issue": 6318, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1410, "End Page": 1414, "Article Number": null, "DOI": "10.1126/science.aah6133", "DOI Link": "http://dx.doi.org/10.1126/science.aah6133", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390261300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, J; Li, QY; Bi, YJ; Cai, M; Dunn, B; Glossmann, T; Liu, J; Osaka, T; Sugiura, R; Wu, BB; Yang, JH; Zhang, JG; Whittingham, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Jie; Li, Qiuyan; Bi, Yujing; Cai, Mei; Dunn, Bruce; Glossmann, Tobias; Liu, Jun; Osaka, Tetsuya; Sugiura, Ryuta; Wu, Bingbin; Yang, Jihui; Zhang, Ji-Guang; Whittingham, M. Stanley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding and applying coulombic efficiency in lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coulombic efficiency (CE) has been widely used in battery research as a quantifiable indicator for the reversibility of batteries. While CE helps to predict the lifespan of a lithium-ion battery, the prediction is not necessarily accurate in a rechargeable lithium metal battery. Here, we discuss the fundamental definition of CE and unravel its true meaning in lithium-ion batteries and a few representative configurations of lithium metal batteries. Through examining the similarities and differences of CE in lithium-ion batteries and lithium metal batteries, we establish a CE measuring protocol with the aim of developing high-energy long-lasting practical lithium metal batteries. The understanding of CE and the CE protocol are broadly applicable in other rechargeable metal batteries including Zn, Mg and Na batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 696, "Times Cited, All Databases": 732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": 568, "Article Number": null, "DOI": "10.1038/s41560-020-0648-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0648-z", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543286600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cho, HC; Jeong, SH; Park, MH; Kim, YH; Wolf, C; Lee, CL; Heo, JH; Sadhanala, A; Myoung, N; Yoo, S; Im, SH; Friend, RH; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cho, Himchan; Jeong, Su-Hun; Park, Min-Ho; Kim, Young-Hoon; Wolf, Christoph; Lee, Chang-Lyoul; Heo, Jin Hyuck; Sadhanala, Aditya; Myoung, NoSoung; Yoo, Seunghyup; Im, Sang Hyuk; Friend, Richard H.; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskites are emerging low-cost emitters with very high color purity, but their low luminescent efficiency is a critical drawback. We boosted the current efficiency (CE) of perovskite light-emitting diodes with a simple bilayer structure to 42.9 candela per ampere, similar to the CE of phosphorescent organic light-emitting diodes, with two modifications: We prevented the formation of metallic lead (Pb) atoms that cause strong exciton quenching through a small increase in methylammonium bromide (MABr) molar proportion, and we spatially confined the exciton in uniform MAPbBr3 nullograins (average diameter = 99.7 nullometers) formed by a nullocrystal pinning process and concomitant reduction of exciton diffusion length to 67 nullometers. These changes caused substantial increases in steady-state photoluminescence intensity and efficiency of MAPbBr(3) nullograin layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2512, "Times Cited, All Databases": 2659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 4", "Publication Year": 2015, "Volume": 350, "Issue": 6265, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1222, "End Page": 1225, "Article Number": null, "DOI": "10.1126/science.aad1818", "DOI Link": "http://dx.doi.org/10.1126/science.aad1818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365700500069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, MT; Wu, SW; Ma, YF; Zhao, YS; Chen, ZL; Frenkel, I; Strzalka, J; Zhou, H; Zhu, XY; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Mutian; Wu, Shuwang; Ma, Yanfei; Zhao, Yusen; Chen, Zilin; Frenkel, Imri; Strzalka, Joseph; Zhou, Hua; Zhu, Xinyuan; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong tough hydrogels via the synergy of freeze-casting and salting out", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural load-bearing materials such as tendons have a high water content of about 70 per cent but are still strong and tough, even when used for over one million cycles per year, owing to the hierarchical assembly of anisotropic structures across multiple length scales(1). Synthetic hydrogels have been created using methods such as electro-spinning(2), extrusion(3), compositing(4,5), freeze-casting(6,7), self-assembly(8) and mechanical stretching(9,10) for improved mechanical performance. However, in contrast to tendons, many hydrogels with the same high water content do not show high strength, toughness or fatigue resistance. Here we present a strategy to produce a multi-length-scale hierarchical hydrogel architecture using a freezing-assisted salting-out treatment. The produced poly(vinyl alcohol) hydrogels are highly anisotropic, comprising micrometre-scale honeycomb-like pore walls, which in turn comprise interconnected nullofibril meshes. These hydrogels have a water content of 70-95 per cent and properties that compare favourably to those of other tough hydrogels and even natural tendons; for example, an ultimate stress of 23.5 +/- 2.7 megapascals, strain levels of 2,900 +/- 450 per cent, toughness of 210 +/- 13 megajoules per cubic metre, fracture energy of 170 +/- 8 kilojoules per square metre and a fatigue threshold of 10.5 +/- 1.3 kilojoules per square metre. The presented strategy is generalizable to other polymers, and could expand the applicability of structural hydrogels to conditions involving more demanding mechanical loading. A strategy that combines freeze-casting and salting-out treatments produces strong, tough, stretchable and fatigue-resistant poly(vinyl alcohol) hydrogels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 998, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2021, "Volume": 590, "Issue": 7847, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03212-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03212-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621583600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rui, K; Zhao, GQ; Chen, YP; Lin, Y; Zhou, Q; Chen, JY; Zhu, JX; Sun, WP; Huang, W; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rui, Kun; Zhao, Guoqiang; Chen, Yaping; Lin, Yue; Zhou, Qian; Chen, Jiayi; Zhu, Jixin; Sun, Wenping; Huang, Wei; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid 2D Dual-Metal-Organic Frameworks for Enhanced Water Oxidation Catalysis", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) and MOF-derived nullostructures are recently emerging as promising catalysts for electrocatalysis applications. Herein, 2D MOFs nullosheets decorated with Fe-MOF nulloparticles are synthesized and evaluated as the catalysts for water oxidation catalysis in alkaline medium. A dramatic enhancement of the catalytic activity is demonstrated by introduction of electrochemically inert Fe-MOF nulloparticles onto active 2D MOFs nullosheets. In the case of active Ni-MOF nullosheets (Ni-MOF@Fe-MOF), the overpotential is 265 mV to reach a current density of 10 mA cm(-2) in 1 m KOH, which is lowered by approximate to 100 mV after hybridization due to the 2D nullosheet morphology and the synergistic effect between Ni active centers and Fe species. Similar performance improvement is also successfully demonstrated in the active NiCo-MOF nullosheets. More importantly, the real catalytic active species in the hybrid Ni-MOF@Fe-MOF catalyst are unraveled. It is found that, NiO nullograins (approximate to 5 nm) are formed in situ during oxygen evolution reaction (OER) process and act as OER active centers as well as building blocks of the porous nullosheet catalysts. These findings provide new insights into understanding MOF-based catalysts for water oxidation catalysis, and also shed light on designing highly efficient MOF-derived nullostructures for electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 582, "Times Cited, All Databases": 593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2018, "Volume": 28, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801554, "DOI": "10.1002/adfm.201801554", "DOI Link": "http://dx.doi.org/10.1002/adfm.201801554", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436104800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kayser, LV; Lipomi, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kayser, Laure, V; Lipomi, Darren J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable Conductive Polymers and Composites Based on PEDOT and PEDOT:PSS", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conductive polymer poly(3,4-ethylenedioxythiophene) (PEDOT), and especially its complex with poly(styrene sulfonate) (PEDOT:PSS), is perhaps the most well-known example of an organic conductor. It is highly conductive, largely transmissive to light, processible in water, and highly flexible. Much recent work on this ubiquitous material has been devoted to increasing its deformability beyond flexibility-a characteristic possessed by any material that is sufficiently thin-toward stretchability, a characteristic that requires engineering of the structure at the molecular- or nulloscale. Stretchability is the enabling characteristic of a range of applications envisioned for PEDOT in energy and healthcare, such as wearable, implantable, and large-area electronic devices. High degrees of mechanical deformability allow intimate contact with biological tissues and solution-processable printing techniques (e.g., roll-to-roll printing). PEDOT:PSS, however, is only stretchable up to around 10%. Here, the strategies that have been reported to enhance the stretchability of conductive polymers and composites based on PEDOT and PEDOT:PSS are highlighted. These strategies include blending with plasticizers or polymers, deposition on elastomers, formation of fibers and gels, and the use of intrinsically stretchable scaffolds for the polymerization of PEDOT.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 834, "Times Cited, All Databases": 886, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2019, "Volume": 31, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806133, "DOI": "10.1002/adma.201806133", "DOI Link": "http://dx.doi.org/10.1002/adma.201806133", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460329300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCrory, CCL; Jung, S; Ferrer, IM; Chatman, SM; Peters, JC; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M.; Chatman, Shawn M.; Peters, Jonas C.; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objective comparisons of electrocatalyst activity and stability using standard methods under identical conditions are necessary to evaluate the viability of existing electrocatalysts for integration into solar-fuel devices as well as to help inform the development of new catalytic systems. Herein, we use a standard protocol as a primary screen for evaluating the activity, short-term (2 h) stability, and electrochemically active surface area (ECSA) of 18 electrocatalysts for the hydrogen evolution reaction (HER) and 26 electrocatalysts for the oxygen evolution reaction (OER) under conditions relevant to an integrated solar water-splitting device in aqueous acidic or alkaline solution. Our primary figure of merit is the overpotential necessary to achieve a magnitude current density of 10 mA cm(-2) per geometric area, the approximate current density expected for a 10% efficient solar-to-fuels conversion device under 1 sun illumination. The specific activity per ECSA of each material is also reported. Among HER catalysts, several could operate at 10 mA cm(-2) with overpotentials <0.1 V in acidic and/or alkaline solutions. Among OER catalysts in acidic solution, no non-noble metal based materials showed promising activity and stability, whereas in alkaline solution many OER catalysts performed with similar activity achieving 10 mA cm(-2) current densities at overpotentials of similar to 0.33-0.5 V. Most OER catalysts showed comparable or better specific activity per ECSA when compared to Ir and Ru catalysts in alkaline solutions, while most HER catalysts showed much lower specific activity than Pt in both acidic and alkaline solutions. For select catalysts, additional secondary screening measurements were conducted including Faradaic efficiency and extended stability measurements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3318, "Times Cited, All Databases": 3551, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2015, "Volume": 137, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4347, "End Page": 4357, "Article Number": null, "DOI": "10.1021/ja510442p", "DOI Link": "http://dx.doi.org/10.1021/ja510442p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352752000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, Z; Ren, CE; Zhao, MQ; Yang, J; Giammarco, JM; Qiu, JS; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Zheng; Ren, Chang E.; Zhao, Meng-Qiang; Yang, Jian; Giammarco, James M.; Qiu, Jieshan; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and conductive MXene films and nullocomposites with high capacitance", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes, a new family of 2D materials, combine hydrophilic surfaces with metallic conductivity. Delamination of MXene produces single-layer nullosheets with thickness of about a nullometer and lateral size of the order of micrometers. The high aspect ratio of delaminated MXene renders it promising nullofiller in multifunctional polymer nullocomposites. Herein, Ti3C2Tx MXene was mixed with either a charged polydiallyldimethylammonium chloride (PDDA) or an electrically neutral polyvinyl alcohol (PVA) to produce Ti3C2Tx/polymer composites. The as-fabricated composites are flexible and have electrical conductivities as high as 2.2 x 10(4) S/m in the case of the Ti3C2Tx/PVA composite film and 2.4 x 105 S/m for pure Ti3C2Tx films. The tensile strength of the Ti3C2Tx/PVA composites was significantly enhanced compared with pure Ti3C2Tx or PVA films. The intercalation and confinement of the polymer between the MXene flakes not only increased flexibility but also enhanced cationic intercalation, offering an impressive volumetric capacitance of similar to 530 F/cm(3) for MXene/PVA-KOH composite film at 2 mV/s. To our knowledge, this study is a first, but crucial, step in exploring the potential of using MXenes in polymer-based multifunctional nullocomposites for a host of applications, such as structural components, energy storage devices, wearable electronics, electrochemical actuators, and radiofrequency shielding, to name a few.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1810, "Times Cited, All Databases": 1933, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2014, "Volume": 111, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16676, "End Page": 16681, "Article Number": null, "DOI": "10.1073/pnas.1414215111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1414215111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345662700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarkar, A; Wang, QS; Schiele, A; Chellali, MR; Bhattacharya, SS; Wang, D; Brezesinski, T; Hahn, H; Velasco, L; Breitung, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarkar, Abhishek; Wang, Qingsong; Schiele, Alexander; Chellali, Mohammed Reda; Bhattacharya, Subramshu S.; Wang, Di; Brezesinski, Torsten; Hahn, Horst; Velasco, Leonardo; Breitung, Ben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Oxides: Fundamental Aspects and Electrochemical Properties", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy materials, especially high-entropy alloys and oxides, have gained significant interest over the years due to their unique structural characteristics and correlated possibilities for tailoring of functional properties. The developments in the area of high-entropy oxides are highlighted here, with emphasis placed on their fundamental understanding, including entropy-dominated phase-stabilization effects and prospective applications, e.g., in the field of electrochemical energy storage. Critical comments on the different classes of high-entropy oxides are made and the underlying principles for the observed properties are summarized. The diversity of materials design, provided by the entropy-mediated phase-stabilization concept, allows engineering of new oxide candidates for practical applications, warranting further studies in this emerging field of materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 881, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 31, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806236, "DOI": "10.1002/adma.201806236", "DOI Link": "http://dx.doi.org/10.1002/adma.201806236", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474604700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, J; Ren, CE; Maleski, K; Hatter, CB; Anasori, B; Urbankowski, P; Sarycheva, A; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Jun; Ren, Chang E.; Maleski, Kathleen; Hatter, Christine B.; Anasori, Babak; Urbankowski, Patrick; Sarycheva, Asya; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A strategy to prepare flexible and conductive MXene/graphene (reduced graphene oxide, rGO) supercapacitor electrodes by using electrostatic self-assembly between positively charged rGO modified with poly(diallyldimethylammonium chloride) and negatively charged titanium carbide MXene nullosheets is presented. After electrostatic assembly, rGO nullosheets are inserted in-between MXene layers. As a result, the self-restacking of MXene nullosheets is effectively prevented, leading to a considerably increased interlayer spacing. Accelerated diffusion of electrolyte ions enables more electroactive sites to become accessible. The freestanding MXene/rGO-5 wt% electrode displays a volumetric capacitance of 1040 F cm(-3) at a scan rate of 2 mV s(-1), an impressive rate capability with 61% capacitance retention at 1 V s(-1) and long cycle life. Moreover, the fabricated binder-free symmetric supercapacitor shows an ultrahigh volumetric energy density of 32.6 Wh L-1, which is among the highest values reported for carbon and MXene based materials in aqueous electrolytes. This work provides fundamental insight into the effect of interlayer spacing on the electrochemical performance of 2D hybrid materials and sheds light on the design of next-generation flexible, portable and highly integrated supercapacitors with high volumetric and rate performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1561, "Times Cited, All Databases": 1625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2017, "Volume": 27, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701264, "DOI": "10.1002/adfm.201701264", "DOI Link": "http://dx.doi.org/10.1002/adfm.201701264", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407261700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jeong, J; Kim, M; Seo, J; Lu, HZ; Ahlawat, P; Mishra, A; Yang, YG; Hope, MA; Eickemeyer, FT; Kim, M; Yoon, YJ; Choi, IW; Darwich, BP; Choi, SJ; Jo, Y; Lee, JH; Walker, B; Zakeeruddin, SM; Emsley, L; Rothlisberger, U; Hagfeldt, A; Kim, DS; Grätzel, M; Kim, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jeong, Jaeki; Kim, Minjin; Seo, Jongdeuk; Lu, Haizhou; Ahlawat, Paramvir; Mishra, Aditya; Yang, Yingguo; Hope, Michael A.; Eickemeyer, Felix T.; Kim, Maengsuk; Yoon, Yung Jin; Choi, In Woo; Darwich, Barbara Primera; Choi, Seung Ju; Jo, Yimhyun; Lee, Jun Hee; Walker, Bright; Zakeeruddin, Shaik M.; Emsley, Lyndon; Rothlisberger, Ursula; Hagfeldt, Anders; Kim, Dong Suk; Graetzel, Michael; Kim, Jin Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites of the general formula ABX(3)-where A is a monovalent cation such as caesium, methylammonium or formamidinium; B is divalent lead, tin or germanium; and X is a halide anion-have shown great potential as light harvesters for thin-film photovoltaics(1-5). Among a large number of compositions investigated, the cubic a-phase of formamidinium lead triiodide (FAPbI(3)) hasemerged as the most promising semiconductor for highly efficient and stable perovskite solar cells(6-9), and maximizing the performance of this material in such devices is of vital importance for the perovskite researchcommunity. Here we introduce an anion engineering concept that uses the pseudo-halide anion formate (HCOO-) to suppress anion-vacancy defects that are present at grain boundaries and at the surface of the perovskite films and to augment the crystallinity of the films. Theresulting solar cell devices attain a power conversion efficiency of 25.6 per cent (certified 25.2 per cent), have long-term operational stability (450 hours) and show intense electroluminescence with external quantum efficiencies of more than 10 per cent. Our findings provide a direct route to eliminate the most abundant and deleterious lattice defects present in metal halide perovskites, providing a facile access to solution-processable films with improved optoelectronic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2467, "Times Cited, All Databases": 2580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2021, "Volume": 592, "Issue": 7854, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 381, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03406-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03406-5", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636947600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, TQ; Chen, IW; Liu, FX; Yang, CY; Bi, H; Xu, FF; Huang, FQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Tianquan; Chen, I-Wei; Liu, Fengxin; Yang, Chongyin; Bi, Hui; Xu, Fangfang; Huang, Fuqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-based supercapacitors can provide high electrical power, but they do not have sufficient energy density to directly compete with batteries. We found that a nitrogen-doped ordered mesoporous few-layer carbon has a capacitance of 855 farads per gram in aqueous electrolytes and can be bipolarly charged or discharged at a fast, carbon-like speed. The improvement mostly stems from robust redox reactions at nitrogen-associated defects that transform inert graphene-like layered carbon into an electrochemically active substance without affecting its electric conductivity. These bipolar aqueous-electrolyte electrochemical cells offer power densities and lifetimes similar to those of carbon-based supercapacitors and can store a specific energy of 41 watt-hours per kilogram (19.5 watt-hours per liter).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1835, "Times Cited, All Databases": 1899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2015, "Volume": 350, "Issue": 6267, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1508, "End Page": 1513, "Article Number": null, "DOI": "10.1126/science.aab3798", "DOI Link": "http://dx.doi.org/10.1126/science.aab3798", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366591100054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kornienko, N; Zhao, YB; Kiley, CS; Zhu, CH; Kim, D; Lin, S; Chang, CJ; Yaghi, OM; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kornienko, Nikolay; Zhao, Yingbo; Kiley, Christopher S.; Zhu, Chenhui; Kim, Dohyung; Lin, Song; Chang, Christopher J.; Yaghi, Omar M.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A key challenge in the field of electrochemical carbon dioxide reduction is the design of catalytic materials featuring high product selectivity, stability, and a composition of earth-abundant elements. In this work, we introduce thin films of nullosized metal organic frameworks (MOFs) as atomically defined and nulloscopic materials that function as catalysts for the efficient and selective reduction of carbon dioxide to carbon monoxide in aqueous electrolytes. Detailed examination of a cobalt porphyrin MOF, Al-2(OH)(2)TCPP-Co (TCPP-H-2 = 4,4',4 '',4 '''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoate) revealed a selectivity for CO production in excess of 76% and stability over 7 h with a per-site turnover number (TON) of 1400. In situ spectroelectrochemical measurements provided insights into the cobalt oxidation state during the course of reaction and showed that the majority of catalytic centers in this MOF are redox-accessible where Co(II) is reduced to Co(I) during catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 1033, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2015, "Volume": 137, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14129, "End Page": 14135, "Article Number": null, "DOI": "10.1021/jacs.5b08212", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b08212", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364727600025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuk, H; Zhang, T; Lin, ST; Parada, GA; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuk, Hyunwoo; Zhang, Teng; Lin, Shaoting; Parada, German Alberto; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough bonding of hydrogels to diverse non-porous surfaces", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In many animals, the bonding of tendon and cartilage to bone is extremely tough (for example, interfacial toughness similar to 800 J m(-2); refs 1,2), yet such tough interfaces have not been achieved between synthetic hydrogels and non-porous surfaces of engineered solids(3-9). Here, we report a strategy to design tough transparent and conductive bonding of synthetic hydrogels containing 90% water to non-porous surfaces of diverse solids, including glass, silicon, ceramics, titanium and aluminium. The design strategy is to anchor the long-chain polymer networks of tough hydrogels covalently to non-porous solid surfaces, which can be achieved by the silanation of such surfaces. Compared with physical interactions, the chemical anchorage results in a higher intrinsic work of adhesion and in significant energy dissipation of bulk hydrogel during detachment, which lead to interfacial toughness values over 1,000 J m(-2). We also demonstrate applications of robust hydrogel-solid hybrids, including hydrogel superglues, mechanically protective hydrogel coatings, hydrogel joints for robotic structures and robust hydrogel-metal conductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 912, "Times Cited, All Databases": 986, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 190, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4463", "DOI Link": "http://dx.doi.org/10.1038/NMAT4463", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368766100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, TY; Dai, S; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Tian Yi; Dai, Sheng; Jaroniec, Mietek; Qiao, Shi Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Derived Hybrid Co3O4-Carbon Porous nullowire Arrays as Reversible Oxygen Evolution Electrodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid porous nullowire arrays composed of strongly interacting Co3O4 and carbon were prepared by a facile carbonization of the metal-organic framework grown on Cu foil. The resulting material, possessing a high surface area of 251 m(2) g(-1) and a large carbon content of 52.1 wt %, can be directly used as the working electrode for oxygen evolution reaction without employing extra substrates or binders. This novel oxygen evolution electrode can smoothly operate in alkaline solutions (e.g., 0.1 and 1.0 M KOH), affording a low onset potential of 1.47 V (vs reversible hydrogen electrode) and a stable current density of 10.0 mA cm(-2) at 1.52 V in 0.1 M KOH solution for at least 30 h, associated with a high Faradaic efficiency of 99.3%. The achieved ultrahigh oxygen evolution activity and strong durability, with superior performance in comparison to the state-of-the-art noble-metal/transition-metal and nonmetal catalysts, originate from the unique nullowire array electrode configuration and in situ carbon incorporation, which lead to the large active surface area, enhanced mass/charge transport capability, easy release of oxygen gas bubbles, and strong structural stability. Furthermore, the hybrid Co3O4-carbon porous nullowire arrays can also efficiently catalyze oxygen reduction reaction, featuring a desirable four electron pathway for reversible oxygen evolution and reduction, which is potentially useful for rechargeable metal-air batteries, regenerative fuel cells, and other important clean energy devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1700, "Times Cited, All Databases": 1759, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2014, "Volume": 136, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13925, "End Page": 13931, "Article Number": null, "DOI": "10.1021/ja5082553", "DOI Link": "http://dx.doi.org/10.1021/ja5082553", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342608800072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saliba, M; Matsui, T; Domanski, K; Seo, JY; Ummadisingu, A; Zakeeruddin, SM; Correa-Baena, JP; Tress, WR; Abate, A; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saliba, Michael; Matsui, Taisuke; Domanski, Konrad; Seo, Ji-Youn; Ummadisingu, Amita; Zakeeruddin, Shaik M.; Correa-Baena, Juan-Pablo; Tress, Wolfgang R.; Abate, Antonio; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a cation cascade to create perovskite materials with excellent material properties. We achieved stabilized efficiencies of up to 21.6% (average value, 20.2%) on small areas (and a stabilized 19.0% on a cell 0.5 square centimeters in area) as well as an electroluminescence of 3.8%. The open-circuit voltage of 1.24 volts at a band gap of 1.63 electron volts leads to a loss in potential of 0.39 volts, versus 0.4 volts for commercial silicon cells. Polymer-coated cells maintained 95% of their initial performance at 85 degrees C for 500 hours under full illumination and maximum power point tracking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3166, "Times Cited, All Databases": 3333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2016, "Volume": 354, "Issue": 6309, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 206, "End Page": 209, "Article Number": null, "DOI": "10.1126/science.aah5557", "DOI Link": "http://dx.doi.org/10.1126/science.aah5557", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387816500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, JS; Kong, XH; Hu, ZX; Yang, F; Ji, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Jingsi; Kong, Xianghua; Hu, Zhi-Xin; Yang, Feng; Ji, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional crystals are emerging materials for nulloelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we present a detailed theoretical investigation of the atomic and electronic structure of few-layer black phosphorus (BP) to predict its electrical and optical properties. This system has a direct bandgap, tunable from 1.51 eV for a monolayer to 0.59 eV for a five-layer sample. We predict that the mobilities are hole-dominated, rather high and highly anisotropic. The monolayer is exceptional in having an extremely high hole mobility (of order 10,000 cm(2)V(-1)s(-1)) and anomalous elastic properties which reverse the anisotropy. Light absorption spectra indicate linear dichroism between perpendicular in-plane directions, which allows optical determination of the crystalline orientation and optical activation of the anisotropic transport properties. These results make few-layer BP a promising candidate for future electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3917, "Times Cited, All Databases": 4159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4475, "DOI": "10.1038/ncomms5475", "DOI Link": "http://dx.doi.org/10.1038/ncomms5475", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340623400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, LD; Tan, GJ; Hao, SQ; He, JQ; Pei, YL; Chi, H; Wang, H; Gong, SK; Xu, HB; Dravid, VP; Uher, C; Snyder, GJ; Wolverton, C; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Li-Dong; Tan, Gangjian; Hao, Shiqiang; He, Jiaqing; Pei, Yanling; Chi, Hang; Wang, Heng; Gong, Shengkai; Xu, Huibin; Dravid, Vinayak P.; Uher, Ctirad; Snyder, G. Jeffrey; Wolverton, Chris; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric technology, harvesting electric power directly from heat, is a promising environmentally friendly means of energy savings and power generation. The thermoelectric efficiency is determined by the device dimensionless figure of merit ZT(dev), and optimizing this efficiency requires maximizing ZT values over a broad temperature range. Here, we report a record high ZT(dev) similar to 1.34, with ZT ranging from 0.7 to 2.0 at 300 to 773 kelvin, realized in hole-doped tin selenide (SnSe) crystals. The exceptional performance arises from the ultrahigh power factor, which comes from a high electrical conductivity and a strongly enhanced Seebeck coefficient enabled by the contribution of multiple electronic valence bands present in SnSe. SnSe is a robust thermoelectric candidate for energy conversion applications in the low and moderate temperature range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1906, "Times Cited, All Databases": 2011, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 351, "Issue": 6269, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 141, "End Page": 144, "Article Number": null, "DOI": "10.1126/science.aad3749", "DOI Link": "http://dx.doi.org/10.1126/science.aad3749", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367806500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lukatskaya, MR; Kota, S; Lin, ZF; Zhao, MQ; Shpigel, N; Levi, MD; Halim, J; Taberna, PL; Barsoum, M; Simon, P; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lukatskaya, Maria R.; Kota, Sankalp; Lin, Zifeng; Zhao, Meng-Qiang; Shpigel, Netanel; Levi, Mikhael D.; Halim, Joseph; Taberna, Pierre-Louis; Barsoum, MichelW.; Simon, Patrice; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of fast surface redox storage (pseudocapacitive) mechanisms can enable devices that store much more energy than electrical double-layer capacitors (EDLCs) and, unlike batteries, can do so quite rapidly. Yet, few pseudocapacitive transition metal oxides can provide a high power capability due to their low intrinsic electronic and ionic conductivity. Here we demonstrate that two-dimensional transition metal carbides (MXenes) can operate at rates exceeding those of conventional EDLCs, but still provide higher volumetric and areal capacitance than carbon, electrically conducting polymers or transition metal oxides. We applied two distinct designs for MXene electrode architectures with improved ion accessibility to redox-active sites. A macroporous Ti(3)C(2)Tx MXene film delivered up to 210 F g(-1) at scan rates of 10Vs(-1), surpassing the best carbon supercapacitors known. In contrast, we show that MXene hydrogels are able to deliver volumetric capacitance of similar to 1,500 F cm(-3) reaching the previously unmatched volumetric performance of RuO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1847, "Times Cited, All Databases": 1936, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17105, "DOI": "10.1038/nenergy.2017.105", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411264300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Two-Dimensional nullomaterials", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The past decade has witnessed an extraordinary increase in research progress on ultrathin two-dimensional (2D) nullomaterials in the fields of condensed matter physics, materials science, and chemistry after the exfoliation of graphene from graphite in 2004. This unique class of nullomaterials has shown many unprecedented properties and thus is being explored for numerous promising applications. In this Perspective, I briefly review the state of the art in the development of ultrathin 2D nullomaterials and highlight their unique advantages. Then, I discuss the typical synthetic methods and some promising applications of ultrathin 2D nullomaterials together with some personal insights on the challenges in this research area. Finally, on the basis of the current achievement on ultrathin 2D nullomaterials, I give some personal perspectives on potential future research directions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1779, "Times Cited, All Databases": 1904, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9451, "End Page": 9469, "Article Number": null, "DOI": "10.1021/acsnullo.5b05040", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b05040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363915300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CL; Wang, QD; Yao, ZP; Wang, JL; Sánchez-Lengeling, B; Ding, FX; Qi, XG; Lu, YX; Bai, XD; Li, BH; Li, H; Aspuru-Guzik, A; Huang, XJ; Delmas, C; Wagemaker, M; Chen, LQ; Hu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chenglong; Wang, Qidi; Yao, Zhenpeng; Wang, Jianlin; Sanchez-Lengeling, Benjamin; Ding, Feixiang; Qi, Xingguo; Lu, Yaxiang; Bai, Xuedong; Li, Baohua; Li, Hong; Aspuru-Guzik, Alan; Huang, Xuejie; Delmas, Claude; Wagemaker, Marnix; Chen, Liquan; Hu, Yong-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of layered oxide materials for sodium-ion batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries have captured widespread attention for grid-scale energy storage owing to the natural abundance of sodium. The performance of such batteries is limited by available electrode materials, especially for sodium-ion layered oxides, motivating the exploration of high compositional diversity. How the composition determines the structural chemistry is decisive for the electrochemical performance but very challenging to predict, especially for complex compositions. We introduce the cationic potential that captures the key interactions of layered materials and makes it possible to predict the stacking structures. This is demonstrated through the rational design and preparation of layered electrode materials with improved performance. As the stacking structure determines the functional properties, this methodology offers a solution toward the design of alkali metal layered oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 717, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2020, "Volume": 370, "Issue": 6517, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 708, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay9972", "DOI Link": "http://dx.doi.org/10.1126/science.aay9972", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000586868600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Herzog, D; Seyda, V; Wycisk, E; Emmelmann, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Herzog, Dirk; Seyda, Vanessa; Wycisk, Eric; Emmelmann, Claus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of metals", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive Manufacturing (AM), the layer-by layer build-up of parts, has lately become an option for serial production. Today, several metallic materials including the important engineering materials steel, aluminium and titanium may be processed to full dense parts with outstanding properties. In this context, the present overview article describes the complex relationship between AM processes, microstructure and resulting properties for metals. It explains the fundamentals of Laser Beam Melting, Electron Beam Melting and Laser Metal Deposition, and introduces the commercially available materials for the different processes. Thereafter, typical microstructures for additively manufactured steel, aluminium and titanium are presented. Special attention is paid to AM specific grain structures, resulting from the complex thermal cycle and high cooling rates. The properties evolving as a consequence of the microstructure are elaborated under static and dynamic loading. According to these properties, typical applications are presented for the materials and methods for conclusion. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3267, "Times Cited, All Databases": 3546, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2016, "Volume": 117, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": 392, "Article Number": null, "DOI": "10.1016/j.actamat.2016.07.019", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.07.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383005300035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathew, S; Yella, A; Gao, P; Humphry-Baker, R; Curchod, BFE; Ashari-Astani, N; Tavernelli, I; Rothlisberger, U; Nazeeruddin, MK; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathew, Simon; Yella, Aswani; Gao, Peng; Humphry-Baker, Robin; Curchod, Basile F. E.; Ashari-Astani, Negar; Tavernelli, Ivano; Rothlisberger, Ursula; Nazeeruddin, Md. Khaja; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dye-sensitized solar cells have gained widespread attention in recent years because of their low production costs, ease of fabrication and tunable optical properties, such as colour and transparency. Here, we report a molecularly engineered porphyrin dye, coded SM315, which features the prototypical structure of a donor-pi-bridge-acceptor and both maximizes electrolyte compatibility and improves light-harvesting properties. Linear-response, time-dependent density functional theory was used to investigate the perturbations in the electronic structure that lead to improved light harvesting. Using SM315 with the cobalt(II/III) redox shuttle resulted in dye-sensitized solar cells that exhibit a high open-circuit voltage V-OC of 0.91 V, short-circuit current density J(SC) of 18.1 mA cm(-2), fill factor of 0.78 and a power conversion efficiency of 13%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3957, "Times Cited, All Databases": 4216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 242, "End Page": 247, "Article Number": null, "DOI": "10.1038/NCHEM.1861", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.1861", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331951800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, SM; Sycks, D; Chan, HF; Lin, ST; Lopez, GP; Guilak, F; Leong, KW; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Sungmin; Sycks, Dalton; Chan, Hon Fai; Lin, Shaoting; Lopez, Gabriel P.; Guilak, Farshid; Leong, Kam W.; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Highly Stretchable and Tough Hydrogels into Complex, Cellularized Structures", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 779, "Times Cited, All Databases": 875, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2015, "Volume": 27, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4035, "End Page": 4040, "Article Number": null, "DOI": "10.1002/adma.201501099", "DOI Link": "http://dx.doi.org/10.1002/adma.201501099", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357988000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, J; Zhang, YQ; Zhou, LY; Zhang, GC; Yip, HL; Lau, TK; Lu, XH; Zhu, C; Peng, HJ; Johnson, PA; Leclerc, M; Cao, Y; Ulanski, J; Li, YF; Zou, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Jun; Zhang, Yunqiang; Zhou, Liuyang; Zhang, Guichuan; Yip, Hin-Lap; Lau, Tsz-Ki; Lu, Xinhui; Zhu, Can; Peng, Hongjian; Johnson, Paul A.; Leclerc, Mario; Cao, Yong; Ulanski, Jacek; Li, Yongfang; Zou, Yingping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, non-fullerene n-type organic semiconductors have attracted significant attention as acceptors in organic photovoltaics (OPVs) due to their great potential to realize high-power conversion efficiencies. The rational design of the central fused ring unit of these acceptor molecules is crucial to maximize device performance. Here, we report a new class of non-fullerene acceptor, Y6, that employs a ladder-type electron-deficient-core-based central fused ring (dithienothiophen[3.2-b]-pyrrolobenzothiadiazole) with a benzothiadiazole (BT) core to fine-tune its absorption and electron affinity. OPVs made from Y6 in conventional and inverted architectures each exhibited a high efficiency of 15.7%, measured in two separate labs. Inverted device structures were certified at Enli Tech Laboratory demonstrated an efficiency of 14.9%. We further observed that the Y6-based devices maintain a high efficiency of 13.6% with an active layer thickness of 300 nm. The electron-deficient-core-based fused ring reported in this work opens a new door in the molecular design of high-performance acceptors for OPVs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4849, "Times Cited, All Databases": 5037, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1140, "End Page": 1151, "Article Number": null, "DOI": "10.1016/j.joule.2019.01.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.01.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465149000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, XT; Lou, Y; Chen, XB; Shi, Z; Xu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Xiaoting; Lou, Yue; Chen, Xiao-Bo; Shi, Zhan; Xu, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional flexible composite aerogels constructed through in-situ growth of metal-organic framework nulloparticles on bacterial cellulose", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible metal-organic framework (MOF) aerogels with practical macroscopic shapeability and hierarchical porosity were prepared through in-site growth of MOF nulloparticles, i.e. zeolitic imidazolate framework-8 (ZIF-8) and University of Oslo-66 (UiO-66), on bacteria cellulose (BC). The yielded composite aerogels inherit high porosities from feedstock MOFs and mechanical flexibility from BC template. BC template offers high porosity, mechanical flexibility to the composite aerogels, which significantly suppresses the aggregation of individual MOF nulloparticles. Owing to the structural characteristics of MOF and BC, BC@ZIF-8 composite aerogel sponges exhibit a low density below 0.03 g cm(-3), hierarchical porosity, large surface area, high mass transfer efficiency and superior adsorption performance of heavy metal ions. After 24 h adsorption in simulated industrial waterwastes, removal efficiency of the composite aerogels reaches up to 81% with respect to Pb2+ ion pollutants, which is 1.2 times higher than that of original ZIF-8 nulloparticle counterparts. BC@UiO-66 composite aerogel film, as a flexible lithium-sulfur battery interlayer, demonstrates a high reversible capacity of 631 mAh g(-1) at 0.5C over 100 cycles, which is attributed to its selectivity for Li+ ions and efficient inhibition to the soluble polysulfide ions. In addition, the presence of polydopamine (PDA) coating on BC@UiO-66 nullofibers in BC@UiO-66@ PDA composite aerogel films increases reversible capacity up to 739 mAh g(-1) at 0.5C over 100 cycles. This work provides a feasible solution to process MOF powders into a flexible and tailorable form, and holds a new promise to rational design and manufacturing of MOF monoliths with a great structural diversity as advanced multifunctional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2019, "Volume": 356, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 235, "Article Number": null, "DOI": "10.1016/j.cej.2018.09.034", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.09.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447004100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paton, KR; Varrla, E; Backes, C; Smith, RJ; Khan, U; O'Neill, A; Boland, C; Lotya, M; Istrate, OM; King, P; Higgins, T; Barwich, S; May, P; Puczkarski, P; Ahmed, I; Moebius, M; Pettersson, H; Long, E; Coelho, J; O'Brien, SE; McGuire, EK; Sanchez, BM; Duesberg, GS; McEvoy, N; Pennycook, TJ; Downing, C; Crossley, A; Nicolosi, V; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paton, Keith R.; Varrla, Eswaraiah; Backes, Claudia; Smith, Ronull J.; Khan, Umar; O'Neill, Arlene; Boland, Conor; Lotya, Mustafa; Istrate, Oana M.; King, Paul; Higgins, Tom; Barwich, Sebastian; May, Peter; Puczkarski, Pawel; Ahmed, Iftikhar; Moebius, Matthias; Pettersson, Henrik; Long, Edmund; Coelho, Joao; O'Brien, Sean E.; McGuire, Eva K.; Sanchez, Beatriz Mendoza; Duesberg, Georg S.; McEvoy, Niall; Pennycook, Timothy J.; Downing, Clive; Crossley, Alison; Nicolosi, Valeria; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To progress from the laboratory to commercial applications, it will be necessary to develop industrially scalable methods to produce large quantities of defect-free graphene. Here we show that high-shear mixing of graphite in suitable stabilizing liquids results in large-scale exfoliation to give dispersions of graphene nullosheets. X-ray photoelectron spectroscopy and Raman spectroscopy show the exfoliated flakes to be unoxidized and free of basal-plane defects. We have developed a simple model that shows exfoliation to occur once the local shear rate exceeds 10(4) s(-1). By fully characterizing the scaling behaviour of the graphene production rate, we show that exfoliation can be achieved in liquid volumes from hundreds of millilitres up to hundreds of litres and beyond. The graphene produced by this method performs well in applications from composites to conductive coatings. This method can be applied to exfoliate BN, MoS2 and a range of other layered crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1904, "Times Cited, All Databases": 2104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 624, "End Page": 630, "Article Number": null, "DOI": "10.1038/NMAT3944", "DOI Link": "http://dx.doi.org/10.1038/NMAT3944", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336787000025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "David, L; Bhandavat, R; Singh, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "David, Lamuel; Bhandavat, Romil; Singh, Gurpreet", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2/Graphene Composite Paper for Sodium-Ion Battery Electrodes", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study the synthesis and electrochemical and mechanical performance of layered freestanding papers composed of acid-exfoliated few-layer molybdenum disulfide (MoS2) and reduced graphene oxide (rGO) flakes for use as a self-standing flexible electrode in sodium-ion batteries. Synthesis was achieved through vacuum filtration of homogeneous dispersions consisting of varying weight percent of acid-treated MoS2 flakes in GO in DI water, followed by thermal reduction at elevated temperatures. The electrochemical performance of the crumpled composite paper (at 4 mg cm(-2)) was evaluated as counter electrode against pure Na foil in a half-cell configuration. The electrode showed good Na cycling ability with a stable charge capacity of approximately 230 mAh g(-1) with respect to total weight of the electrode with Coulombic efficiency reaching approximately 99%. In addition, static uniaxial tensile tests performed on crumpled composite papers showed high average strain to failure reaching approximately 2%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1106, "Times Cited, All Databases": 1159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1759, "End Page": 1770, "Article Number": null, "DOI": "10.1021/nn406156b", "DOI Link": "http://dx.doi.org/10.1021/nn406156b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332059200073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, Y; Mathis, TS; Zhao, MQ; Anasori, B; Dang, A; Zhou, ZH; Cho, H; Gogotsi, Y; Yang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Yu; Mathis, Tyler S.; Zhao, Meng-Qiang; Anasori, Babak; Dang, Alei; Zhou, Zehang; Cho, Hyesung; Gogotsi, Yury; Yang, Shu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thickness - independent capacitance of vertically aligned liquid-crystalline MXenes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scalable and sustainable manufacture of thick electrode films with high energy and power densities is critical for the large-scale storage of electrochemical energy for application in transportation and stationary electric grids. Two-dimensional nullomaterials have become the predominullt choice of electrode material in the pursuit of high energy and power densities owing to their large surface area-to-volume ratios and lack of solid-state diffusion(1,2). However, traditional electrode fabrication methods often lead to restacking of two-dimensional nullomaterials, which limits ion transport in thick films and results in systems in which the electrochemical performance is highly dependent on the thickness of the film(1-4). Strategies for facilitating ion transport such as increasing the interlayer spacing by intercalation(5-8) or introducing film porosity by designing nulloarchitectures(9,10)-result in materials with low volumetric energy storage as well as complex and lengthy ion transport paths that impede performance at high charge-discharge rates. Vertical alignment of two-dimensional flakes enables directional ion transport that can lead to thickness-independent electrochemical performances in thick films(11-13). However, so far only limited success(11,12) has been reported, and the mitigation of performance losses remains a major challenge when working with films of two-dimensional nullomaterials with thicknesses that are near to or exceed the industrial standard of 100 micrometres. Here we demonstrate electrochemical energy storage that is independent of film thickness for vertically aligned two-dimensional titanium carbide (Ti3C2Tx), a material from the MXene family (two dimensional carbides and nitrides of transition metals (M), where X stands for carbon or nitrogen). The vertical alignment was achieved by mechanical shearing of a discotic lamellar liquid-crystal phase of Ti3C2Tx. The resulting electrode films show excellent performance that is nearly independent of film thickness up to 200 micrometres, which makes them highly attractive for energy storage applications. Furthermore, the self-assembly approach presented here is scalable and can be extended to other systems that involve directional transport, such as catalysis and filtration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1062, "Times Cited, All Databases": 1129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2018, "Volume": 557, "Issue": 7705, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 409, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0109-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0109-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432242000057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, XL; Zhao, X; Su, YQ; Wang, LJ; Wang, HM; Dang, D; Chi, B; Liu, HF; Hensen, EJM; Lou, XW; Xia, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong; Wang, Lijuan; Wang, Hongming; Dang, Dai; Chi, Bin; Liu, Hongfang; Hensen, Emiel J. M.; Lou, Xiong Wen (David); Xia, Bao Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering bunched Pt-Ni alloy nullocages for efficient oxygen reduction in practical fuel cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of efficient and robust electrocatalysts is critical for practical fuel cells. We report one-dimensional bunched platinum-nickel (Pt-Ni) alloy nullocages with a Pt-skin structure for the oxygen reduction reaction that display high mass activity (3.52 amperes per milligram platinum) and specific activity (5.16 milliamperes per square centimeter platinum), or nearly 17 and 14 times higher as compared with a commercial platinum on carbon (Pt/C) catalyst. The catalyst exhibits high stability with negligible activity decay after 50,000 cycles. Both the experimental results and theoretical calculations reveal the existence of fewer strongly bonded platinum-oxygen (Pt-O) sites induced by the strain and ligand effects. Moreover, the fuel cell assembled by this catalyst delivers a current density of 1.5 amperes per square centimeter at 0.6 volts and can operate steadily for at least 180 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1197, "Times Cited, All Databases": 1246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 366, "Issue": 6467, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 850, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw7493", "DOI Link": "http://dx.doi.org/10.1126/science.aaw7493", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496946200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; Anasori, B; Seral-Ascaso, A; Park, SH; McEvoy, N; Shmeliov, A; Duesberg, GS; Coleman, JN; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuanfang (John); Anasori, Babak; Seral-Ascaso, Andres; Park, Sang-Hoon; McEvoy, Niall; Shmeliov, Aleksey; Duesberg, Georg S.; Coleman, Jonathan N.; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition-metal carbides and nitrides, known as MXenes, have displayed promising properties in numerous applications, such as energy storage, electromagnetic interference shielding, and catalysis. Titanium carbide MXene (Ti3C2Tx), in particular, has shown significant energy-storage capability. However, previously, only micrometer-thick, nontransparent films were studied. Here, highly transparent and conductive Ti3C2Tx films and their application as transparent, solid-state supercapacitors are reported. Transparent films are fabricated via spin-casting of Ti3C2Tx nullosheet colloidal solutions, followed by vacuum annealing at 200 degrees C. Films with transmittance of 93% (approximate to 4 nm) and 29% (approximate to 88 nm) demonstrate DC conductivity of approximate to 5736 and approximate to 9880 S cm(-1), respectively. Such highly transparent, conductive Ti3C2Tx films display impressive volumetric capacitance (676 F cm(-3)) combined with fast response. Transparent solid-state, asymmetric supercapacitors (72% transmittance) based on Ti3C2Tx and single-walled carbon nullotube (SWCNT) films are also fabricated. These electrodes exhibit high capacitance (1.6 mF cm(-2)) and energy density (0.05 mu W h cm(-2)), and long lifetime (no capacitance decay over 20 000 cycles), exceeding that of graphene or SWCNT-based transparent supercapacitor devices. Collectively, the Ti3C2Tx films are among the state-of-the-art for future transparent, conductive, capacitive electrodes, and translate into technologically viable devices for next-generation wearable, portable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 943, "Times Cited, All Databases": 984, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2017, "Volume": 29, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702678, "DOI": "10.1002/adma.201702678", "DOI Link": "http://dx.doi.org/10.1002/adma.201702678", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411379000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XX; Cullen, DA; Pan, YT; Hwang, S; Wang, MY; Feng, ZX; Wang, JY; Engelhard, MH; Zhang, HG; He, YH; Shao, YY; Su, D; More, KL; Spendelow, JS; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin; Hwang, Sooyeon; Wang, Maoyu; Feng, Zhenxing; Wang, Jingyun; Engelhard, Mark H.; Zhang, Hanguang; He, Yanghua; Shao, Yuyan; Su, Dong; More, Karren L.; Spendelow, Jacob S.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the Fenton reaction, the presence of Fe and peroxide in electrodes generates free radicals causing serious degradation of the organic ionomer and the membrane. Pt-free and Fe-free cathode catalysts therefore are urgently needed for durable and inexpensive proton exchange membrane fuel cells (PEMFCs). Herein, a high-performance nitrogen-coordinated single Co atom catalyst is derived from Co-doped metal-organic frameworks (MOFs) through a one-step thermal activation. Aberration-corrected electron microscopy combined with X-ray absorption spectroscopy virtually verifies the CoN4 coordination at an atomic level in the catalysts. Through investigating effects of Co doping contents and thermal activation temperature, an atomically Co site dispersed catalyst with optimal chemical and structural properties has achieved respectable activity and stability for the oxygen reduction reaction (ORR) in challenging acidic media (e.g., half-wave potential of 0.80 V vs reversible hydrogen electrode (RHE). The performance is comparable to Fe-based catalysts and 60 mV lower than Pt/C -60 mu g Pt cm(-2)). Fuel cell tests confirm that catalyst activity and stability can translate to high-performance cathodes in PEMFCs. The remarkably enhanced ORR performance is attributed to the presence of well-dispersed CoN4 active sites embedded in 3D porous MOF-derived carbon particles, omitting any inactive Co aggregates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 975, "Times Cited, All Databases": 1026, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 30, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706758, "DOI": "10.1002/adma.201706758", "DOI Link": "http://dx.doi.org/10.1002/adma.201706758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427111300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saliba, M; Matsui, T; Seo, JY; Domanski, K; Correa-Baena, JP; Nazeeruddin, MK; Zakeeruddin, SM; Tress, W; Abate, A; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn; Domanski, Konrad; Correa-Baena, Juan-Pablo; Nazeeruddin, Mohammad Khaja; Zakeeruddin, Shaik M.; Tress, Wolfgang; Abate, Antonio; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impurities and are less sensitive to processing conditions. This enables more reproducible device performances to reach a stabilized power output of 21.1% and similar to 18% after 250 hours under operational conditions. These properties are key for the industrialization of perovskite photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4453, "Times Cited, All Databases": 4732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1989, "End Page": 1997, "Article Number": null, "DOI": "10.1039/c5ee03874j", "DOI Link": "http://dx.doi.org/10.1039/c5ee03874j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378244200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MF; Zhao, ZP; Cheng, T; Fortunelli, A; Chen, CY; Yu, R; Zhang, QH; Gu, L; Merinov, BV; Lin, ZY; Zhu, EB; Yu, T; Jia, QY; Guo, JH; Zhang, L; Goddard, WA ; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mufan; Zhao, Zipeng; Cheng, Tao; Fortunelli, Alessandro; Chen, Chih-Yen; Yu, Rong; Zhang, Qinghua; Gu, Lin; Merinov, Boris V.; Lin, Zhaoyang; Zhu, Enbo; Yu, Ted; Jia, Qingying; Guo, Jinghua; Zhang, Liang; Goddard, William A., III; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafine jagged platinum nullowires enable ultrahigh mass activity for the oxygen reduction reaction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the platinum (9Pt) mass activity for the oxygen reduction reaction (ORR) requires optimization of both the specific activity and the electrochemically active surface area (ECSA). We found that solution-synthesized Pt/NiO core/shell nullowires can be converted into PtNi alloy nullowires through a thermal annealing process and then transformed into jagged Pt nullowires via electrochemical dealloying. The jagged nullowires exhibit an ECSA of 118 square meters per gram of Pt and a specific activity of 11.5 milliamperes per square centimeter for ORR 9 (at 0.9 volts versus reversible hydrogen electrode), yielding a mass activity of 13.6 amperes per milligram of Pt, nearly double previously reported best values. Reactive molecular dynamics simulations suggest that highly stressed, undercoordinated rhombus-rich surface configurations of the jagged nullowires enhance ORR activity versus more relaxed surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1346, "Times Cited, All Databases": 1413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2016, "Volume": 354, "Issue": 6318, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1414, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaf9050", "DOI Link": "http://dx.doi.org/10.1126/science.aaf9050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390261300041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Zheng, XL; Voznyy, O; Comin, R; Bajdich, M; García-Melchor, M; Han, LL; Xu, JX; Liu, M; Zheng, LR; de Arquer, FPG; Dinh, CT; Fan, FJ; Yuan, MJ; Yassitepe, E; Chen, N; Regier, T; Liu, PF; Li, YH; De Luna, P; Janmohamed, A; Xin, HLL; Yang, HG; Vojvodic, A; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; de Arquer, F. Pelayo Garcia; Dinh, Cao Thang; Fan, Fengjia; Yuan, Mingjian; Yassitepe, Emre; Chen, Ning; Regier, Tom; Liu, Pengfei; Li, Yuhang; De Luna, Phil; Janmohamed, Alyf; Xin, Huolin L.; Yang, Huagui; Vojvodic, Aleksandra; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Homogeneously dispersed multimetal oxygen-evolving catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earth-abundant first-row (3d) transition metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials substantially above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing nearoptimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxyhydroxides materials with an atomically homogeneous metal distribution. These gelled FeCoW oxyhydroxides exhibit the lowest overpotential (191 millivolts) reported at 10 milliamperes per square centimeter in alkaline electrolyte. The catalyst shows no evidence of degradation after more than 500 hours of operation. X-ray absorption and computational studies reveal a synergistic interplay between tungsten, iron, and cobalt in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2118, "Times Cited, All Databases": 2222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2016, "Volume": 352, "Issue": 6283, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 333, "End Page": 337, "Article Number": null, "DOI": "10.1126/science.aaf1525", "DOI Link": "http://dx.doi.org/10.1126/science.aaf1525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373990100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuan; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals integration before and beyond two-dimensional materials", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Material integration strategies, such as epitaxial growth, usually involve strong chemical bonds and are typically limited to materials with strict structure matching and processing compatibility. Van der Waals integration, in which pre-fabricated building blocks are physically assembled together through weak van der Waals interactions, offers an alternative bond-free integration strategy without lattice and processing limitations, as exemplified by two-dimensional van der Waals heterostructures. Here we review the development, challenges and opportunities of this emerging approach, generalizing it for flexible integration of diverse material systems beyond two dimensions, and discuss its potential for creating artificial heterostructures or superlattices beyond the reach of existing materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1165, "Times Cited, All Databases": 1240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2019, "Volume": 567, "Issue": 7748, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 323, "End Page": 333, "Article Number": null, "DOI": "10.1038/s41586-019-1013-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1013-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462010000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YM; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yu Ming; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Tubular Structures Composed of Co3O4 Hollow nulloparticles and Carbon nullotubes for Lithium Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hierarchical tubular structures composed of Co3O4 hollow nulloparticles and carbon nullotubes (CNTs) have been synthesized by an efficient multi-step route. Starting from polymer-cobalt acetate (Co(Ac)(2)) composite nullofibers, uniform polymer-Co(Ac)(2)@zeolitic imidazolate framework-67 (ZIF-67) core-shell nullofibers are first synthesized via partial phase transformation with 2-methylimidazole in ethanol. After the selective dissolution of polymer-Co(Ac)(2) cores, the resulting ZIF-67 tubular structures can be converted into hierarchical CNTs/Co-carbon hybrids by annealing in Ar/H-2 atmosphere. Finally, the hierarchical CNT/Co3O4 microtubes are obtained by a subsequent thermal treatment in air. Impressively, the as-prepared nullocomposite delivers a high reversible capacity of 1281mAhg(-1) at 0.1Ag(-1) with exceptional rate capability and long cycle life over 200 cycles as an anode material for lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2016, "Volume": 55, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5990, "End Page": 5993, "Article Number": null, "DOI": "10.1002/anie.201600133", "DOI Link": "http://dx.doi.org/10.1002/anie.201600133", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375865500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, LF; Yu, L; Wu, HB; Yu, XY; Zhang, XG; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Laifa; Yu, Le; Wu, Hao Bin; Yu, Xin-Yao; Zhang, Xiaogang; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the synthesis of hollow structures of transition metal oxides is well established, it is extremely challenging to fabricate complex hollow structures for mixed transition metal sulfides. Here we report an anion exchange method to synthesize a complex ternary metal sulfides hollow structure, namely nickel cobalt sulfide ball-in-ball hollow spheres. Uniform nickel cobalt glycerate solid spheres are first synthesized as the precursor and subsequently chemically transformed into nickel cobalt sulfide ball-in-ball hollow spheres. When used as electrode materials for electrochemical capacitors, these nickel cobalt sulfide hollow spheres deliver a specific capacitance of 1,036 F g(-1) at a current density of 1.0 A g(-1). An asymmetric supercapacitor based on these ball-in-ball structures shows long-term cycling performance with a high energy density of 42.3 Wh kg(-1) at a power density of 476 W kg(-1), suggesting their potential application in high-performance electrochemical capacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1214, "Times Cited, All Databases": 1232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6694, "DOI": "10.1038/ncomms7694", "DOI Link": "http://dx.doi.org/10.1038/ncomms7694", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353043600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lohse, MS; Bein, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lohse, Maria S.; Bein, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent Organic Frameworks: Structures, Synthesis, and Applications", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are crystalline porous polymers formed by a bottom-up approach from molecular building units having a predesigned geometry that are connected through covalent bonds. They offer positional control over their building blocks in two and three dimensions. This control enables the synthesis of rigid porous structures with a high regularity and the ability to fine-tune the chemical and physical properties of the network. This Feature Article provides a comprehensive overview over the structures realized to date in the fast growing field of covalent organic framework development. Different synthesis strategies to meet diverse demands, such as high crystallinity, straightforward processability, or the formation of thin films are discussed. Furthermore, insights into the growing fields of COF applications, including gas storage and separations, sensing, electrochemical energy storage, and optoelectronics are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1210, "Times Cited, All Databases": 1271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 28, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705553, "DOI": "10.1002/adfm.201705553", "DOI Link": "http://dx.doi.org/10.1002/adfm.201705553", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445192400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Wu, YZ; Yue, YF; Liu, J; Zhang, WJ; Yang, XD; Chen, H; Bi, EB; Ashraful, I; Grätzel, M; Han, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wei; Wu, Yongzhen; Yue, Youfeng; Liu, Jian; Zhang, Wenjun; Yang, Xudong; Chen, Han; Bi, Enbing; Ashraful, Islam; Graetzel, Michael; Han, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent dramatic rise in power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) has triggered intense research worldwide. However, high PCE values have often been reached with poor stability at an illuminated area of typically less than 0.1 square centimeter. We used heavily doped inorganic charge extraction layers in planar PSCs to achieve very rapid carrier extraction, even with 10- to 20-nullometer-thick layers, avoiding pinholes and eliminating local structural defects over large areas. The robust inorganic nature of the layers allowed for the fabrication of PSCs with an aperture area >1 square centimeter that have a PCE >15%, as certified by an accredited photovoltaic calibration laboratory. Hysteresis in the current-voltage characteristics was eliminated; the PSCs were stable, with >90% of the initial PCE remaining after 1000 hours of light soaking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2031, "Times Cited, All Databases": 2126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2015, "Volume": 350, "Issue": 6263, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 944, "End Page": 948, "Article Number": null, "DOI": "10.1126/science.aad1015", "DOI Link": "http://dx.doi.org/10.1126/science.aad1015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364955200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, X; Zuo, Y; Zhai, P; Shen, JH; Yang, YYW; Gao, Z; Liao, M; Wu, JX; Wang, JW; Xu, XJ; Tong, Q; Zhang, B; Wang, BJ; Sun, XM; Zhang, LH; Pei, QB; Jin, DY; Chen, PN; Peng, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xiang; Zuo, Yong; Zhai, Peng; Shen, Jiahao; Yang, Yangyiwei; Gao, Zhen; Liao, Meng; Wu, Jingxia; Wang, Jiawei; Xu, Xiaojie; Tong, Qi; Zhang, Bo; Wang, Bingjie; Sun, Xuemei; Zhang, Lihua; Pei, Qibing; Jin, Dayong; Chen, Peining; Peng, Huisheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-area display textiles integrated with functional systems", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Displays are basic building blocks of modern electronics(1,2). Integrating displays into textiles offers exciting opportunities for smart electronictextiles-the ultimate goal of wearable technology, poised to change the way in which we interact with electronic devices(3-6). Display textiles serve to bridge human-machine interactions(7-9), offering, for instance, a real-time communication tool for individuals with voice or speech difficulties. Electronictextiles capable of communicating(10), sensing(11,12) and supplying electricity(13,14) have been reported previously. However, textiles with functional, large-area displays have not yet been achieved, because it is challenging to obtain small illuminating unitsthat are both durable and easy to assemble over a wide area. Here we report a 6-metre-long, 25-centimetre-wide display textile containing 5 x10(5 )electroluminescent units spaced approximately 800 micrometres apart. Weaving conductive weft and luminescent warp fibres forms micrometre-scale electroluminescent units at the weft-warp contact points. The brightness between electroluminescent units deviates by less than 8 per cent and remains stable even when the textile is bent, stretched or pressed. Our display textile is flexible and breathable and withstands repeated machine-washing, making it suitable for practical applications. We showthat an integrated textile system consisting of display, keyboard and power supply can serve as a communication tool, demonstrating the system's potential within the Internet of things' in various areas, including healthcare. Our approach unifies the fabrication and function of electronic devices with textiles, and we expect that woven-fibre materials will shape the next generation of electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 755, "Times Cited, All Databases": 803, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 591, "Issue": 7849, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03295-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03295-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627422700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, HL; Dong, JC; Feng, YX; Allen, CS; Wan, CZ; Volosskiy, B; Li, MF; Zhao, ZP; Wang, YL; Sun, HT; An, PF; Chen, WX; Guo, ZY; Lee, C; Chen, DL; Shakir, I; Liu, MJ; Hu, TD; Li, YD; Kirkland, AI; Duan, XF; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Huilong; Dong, Juncai; Feng, Yexin; Allen, Christopher S.; Wan, Chengzhang; Volosskiy, Boris; Li, Mufan; Zhao, Zipeng; Wang, Yiliu; Sun, Hongtao; An, Pengfei; Chen, Wenxing; Guo, Zhiying; Lee, Chain; Chen, Dongliang; Shakir, Imran; Liu, Mingjie; Hu, Tiandou; Li, Yadong; Kirkland, Angus I.; Duan, Xiangfeng; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have recently attracted broad research interest as they combine the merits of both homogeneous and heterogeneous catalysts. Rational design and synthesis of SACs are of immense significance but have so far been plagued by the lack of a definitive correlation between structure and catalytic properties. Here, we report a general approach to a series of monodispersed atomic transition metals (for example, Fe, Co, Ni) embedded in nitrogen-doped graphene with a common MN4C4 moiety, identified by systematic X-ray absorption fine structure analyses and direct transmission electron microscopy imaging. The unambiguous structure determination allows density functional theoretical prediction of MN4C4 moieties as efficient oxygen evolution catalysts with activities following the trend Ni > Co > Fe, which is confirmed by electrochemical measurements. Determination of atomistic structure and its correlation with catalytic properties represents a critical step towards the rational design and synthesis of precious or nonprecious SACs with exceptional atom utilization efficiency and catalytic activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1622, "Times Cited, All Databases": 1672, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": 72, "Article Number": null, "DOI": "10.1038/s41929-017-0008-y", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0008-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428619500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, Y; He, K; Zhu, YJ; Han, FD; Xu, YH; Matsuda, I; Ishii, Y; Cumings, J; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Yang; He, Kai; Zhu, Yujie; Han, Fudong; Xu, Yunhua; Matsuda, Isamu; Ishii, Yoshitaka; Cumings, John; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Expanded graphite as superior anode for sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphite, as the most common anode for commercial Li-ion batteries, has been reported to have a very low capacity when used as a Na-ion battery anode. It is well known that electrochemical insertion of Na+ into graphite is significantly hindered by the insufficient interlayer spacing. Here we report expanded graphite as a Na-ion battery anode. Prepared through a process of oxidation and partial reduction on graphite, expanded graphite has an enlarged interlayer lattice distance of 4.3 angstrom yet retains an analogous long-range-ordered layered structure to graphite. In situ transmission electron microscopy has demonstrated that the Na-ion can be reversibly inserted into and extracted from expanded graphite. Galvanostatic studies show that expanded graphite can deliver a high reversible capacity of 284mAhg(-1) at a current density of 20mAg(-1), maintain a capacity of 184mAhg(-1) at 100mAg(-1), and retain 73.92% of its capacity after 2,000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1662, "Times Cited, All Databases": 1750, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4033, "DOI": "10.1038/ncomms5033", "DOI Link": "http://dx.doi.org/10.1038/ncomms5033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338837500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, FD; Westover, AS; Yue, J; Fan, XL; Wang, F; Chi, MF; Leonard, DN; Dudney, N; Wang, H; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Fudong; Westover, Andrew S.; Yue, Jie; Fan, Xiulin; Wang, Fei; Chi, Miaofang; Leonard, Donovan N.; Dudney, nullcyj; Wang, Howard; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid electrolytes (SEs) are widely considered as an 'enabler' of lithium anodes for high-energy batteries. However, recent reports demonstrate that the Li dendrite formation in Li7La3Zr2O12 (LLZO) and Li2S-P2S5 is actually much easier than that in liquid electrolytes of lithium batteries, by mechanisms that remain elusive. Here we illustrate the origin of the dendrite formation by monitoring the dynamic evolution of Li concentration profiles in three popular but representative SEs (LiPON, LLZO and amorphous Li3PS4) during lithium plating using time-resolved operando neutron depth profiling. Although no apparent changes in the lithium concentration in LiPON can be observed, we visualize the direct deposition of Li inside the bulk LLZO and Li3PS4. Our findings suggest the high electronic conductivity of LLZO and Li3PS4 is mostly responsible for dendrite formation in these SEs. Lowering the electronic conductivity, rather than further increasing the ionic conductivity of SEs, is therefore critical for the success of all-solid-state Li batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1272, "Times Cited, All Databases": 1394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 187, "End Page": 196, "Article Number": null, "DOI": "10.1038/s41560-018-0312-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0312-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461124600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, FY; Meng, K; Cheng, B; Wang, SY; Xu, JS; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Feiyan; Meng, Kai; Cheng, Bei; Wang, Shengyao; Xu, Jingsan; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring photocatalysts to promote CO2 photoreduction into solar fuels is of great significance. We develop TiO2/perovskite (CsPbBr3) S-scheme heterojunctions synthesized by a facile electrostatic-driven self-assembling approach. Density functional theory calculation combined with experimental studies proves the electron transfer from CsPbBr3 quantum dots (QDs) to TiO2, resulting in the construction of internal electric field (IEF) directing from CsPbBr3 to TiO2 upon hybridization. The IEF drives the photoexcited electrons in TiO2 to CsPbBr3 upon light irradiation as revealed by in-situ X-ray photoelectron spectroscopy analysis, suggesting the formation of an S-scheme heterojunction in the TiO2/CsPbBr3 nullohybrids which greatly promotes the separation of electron-hole pairs to foster efficient CO2 photoreduction. The hybrid nullofibers unveil a higher CO2-reduction rate (9.02 mu mol g(-1) h(-1)) comparing with pristine TiO2 nullofibers (4.68 mu mol g(-1) h(-1)). Isotope ((CO2)-C-13) tracer results confirm that the reduction products originate from CO2 source.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1175, "Times Cited, All Databases": 1211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4613, "DOI": "10.1038/s41467-020-18350-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18350-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604254000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wong, MY; Zysman-Colman, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wong, Michael Y.; Zysman-Colman, Eli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Purely Organic Thermally Activated Delayed Fluorescence Materials for Organic Light-Emitting Diodes", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of thermally activated delayed fluorescence (TADF) materials both as emitters and as hosts is an exploding area of research. The replacement of phosphorescent metal complexes with inexpensive organic compounds in electroluminescent (EL) devices that demonstrate comparable performance metrics is paradigm shifting, as these new materials offer the possibility of developing low-cost lighting and displays. Here, a comprehensive review of TADF materials is presented, with a focus on linking their optoelectronic behavior with the performance of the organic light-emitting diode (OLED) and related EL devices. TADF emitters are cross-compared within specific color ranges, with a focus on blue, green-yellow, orange-red, and white OLEDs. Organic small-molecule, dendrimer, polymer, and exciplex emitters are all discussed within this review, as is their use as host materials. Correlations are provided between the structure of the TADF materials and their optoelectronic properties. The success of TADF materials has ushered in the next generation of OLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1663, "Times Cited, All Databases": 1728, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2017, "Volume": 29, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605444, "DOI": "10.1002/adma.201605444", "DOI Link": "http://dx.doi.org/10.1002/adma.201605444", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402963400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Chen, LJ; Chong, SY; Little, MA; Wu, YZ; Zhu, WH; Clowes, R; Yan, Y; Zwijnenburg, MA; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoyan; Chen, Linjiang; Chong, Samantha Y.; Little, Marc A.; Wu, Yongzhen; Zhu, Wei-Hong; Clowes, Rob; Yan, Yong; Zwijnenburg, Martijn A.; Sprick, Reiner Sebastian; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature uses organic molecules for light harvesting and photosynthesis, but most man-made water splitting catalysts are inorganic semiconductors. Organic photocatalysts, while attractive because of their synthetic tunability, tend to have low quantum efficiencies for water splitting. Here we present a crystalline covalent organic framework (COF) based on a benzobis(benzothiophene sulfone) moiety that shows a much higher activity for photochemical hydrogen evolution than its amorphous or semicrystalline counterparts. The COF is stable under long-term visible irradiation and shows steady photochemical hydrogen evolution with a sacrificial electron donor for at least 50 hours. We attribute the high quantum efficiency of fusedsulfone-COF to its crystallinity, its strong visible light absorption, and its wettable, hydrophilic 3.2 nm mesopores. These pores allow the framework to be dye-sensitized, leading to a further 61% enhancement in the hydrogen evolution rate up to 16.3 mmol g(-1) h(-1). The COF also retained its photocatalytic activity when cast as a thin film onto a support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 985, "Times Cited, All Databases": 1022, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 10, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1180, "End Page": 1189, "Article Number": null, "DOI": "10.1038/s41557-018-0141-5", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0141-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450790300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Celiz, AD; Yang, J; Yang, Q; Wamala, I; Whyte, W; Seo, BR; Vasilyev, NV; Vlassak, JJ; Suo, Z; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, J.; Celiz, A. D.; Yang, J.; Yang, Q.; Wamala, I.; Whyte, W.; Seo, B. R.; Vasilyev, N. V.; Vlassak, J. J.; Suo, Z.; Mooney, D. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough adhesives for diverse wet surfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesion to wet and dynamic surfaces, including biological tissues, is important in many fields but has proven to be extremely challenging. Existing adhesives are cytotoxic, adhere weakly to tissues, or cannot be used in wet environments. We report a bioinspired design for adhesives consisting of two layers: an adhesive surface and a dissipative matrix. The former adheres to the substrate by electrostatic interactions, covalent bonds, and physical interpenetration. The latter amplifies energy dissipation through hysteresis. The two layers synergistically lead to higher adhesion energies on wet surfaces as compared with those of existing adhesives. Adhesion occurs within minutes, independent of blood exposure and compatible with in vivo dynamic movements. This family of adhesives may be useful in many areas of application, including tissue adhesives, wound dressings, and tissue repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1214, "Times Cited, All Databases": 1304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2017, "Volume": 357, "Issue": 6349, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 381, "Article Number": null, "DOI": "10.1126/science.aah6362", "DOI Link": "http://dx.doi.org/10.1126/science.aah6362", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406362300039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, LJ; Chortos, A; Yu, GH; Wang, YQ; Isaacson, S; Allen, R; Shi, Y; Dauskardt, R; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Lijia; Chortos, Alex; Yu, Guihua; Wang, Yaqun; Isaacson, Scott; Allen, Ranulfo; Shi, Yi; Dauskardt, Reinhold; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An ultra-sensitive resistive pressure sensor based on hollow-sphere microstructure induced elasticity in conducting polymer film", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure sensing is an important function of electronic skin devices. The development of pressure sensors that can mimic and surpass the subtle pressure sensing properties of natural skin requires the rational design of materials and devices. Here we present an ultra-sensitive resistive pressure sensor based on an elastic, microstructured conducting polymer thin film. The elastic microstructured film is prepared from a polypyrrole hydrogel using a multiphase reaction that produced a hollow-sphere microstructure that endows polypyrrole with structure-derived elasticity and a low effective elastic modulus. The contact area between the microstructured thin film and the electrodes increases with the application of pressure, enabling the device to detect low pressures with ultra-high sensitivity. Our pressure sensor based on an elastic microstructured thin film enables the detection of pressures of less than 1 Pa and exhibits a short response time, good reproducibility, excellent cycling stability and temperature-stable sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1296, "Times Cited, All Databases": 1389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3002, "DOI": "10.1038/ncomms4002", "DOI Link": "http://dx.doi.org/10.1038/ncomms4002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331082900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, XT; Jiao, QZ; Chen, WX; Dang, YL; Dai, Z; Suib, SL; Zhang, JT; Zhao, Y; Li, HS; Feng, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Xueting; Jiao, Qingze; Chen, Wenxing; Dang, Yanliu; Dai, Zheng; Suib, Steven L.; Zhang, Jiatao; Zhao, Yun; Li, Hansheng; Feng, Caihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cactus-like NiCo2S4@NiFe LDH hollow spheres as an effective oxygen bifunctional electrocatalyst in alkaline solution", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high-performance non-precious electrocatalysts for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are crucial to the practical application of fuel cells and metal-air batteries. Herein, a novel cactus-like NiCo2S4@NiFe LDH hollow sphere assembled by one-dimensional (1D) NiFe LDH nullowires and two-dimensional (2D) NiFe LDH nullosheets on the NiCo2S4 hollow spheres is prepared by a facile hydrothermal method. The outer NiFe LDH nullowires and NiFe LDH nullosheets can effectively suppress the collapse and corrosion of inner NiCo2S4 hollow structure during long-term stability tests. The integration of the effective OER electrocatalyst NiFe LDH into NiCo2S4 to form hetemstructures, as well as the strong electronic interaction between NiCo2S4 and NiFe LDH, can greatly boost both ORR and OER activities. Due to the above merits, the NiCo2S4@NiFe LDH achieves remarkably a small potential gap (Delta E = Ej=10-E-1/2) of only 0.667 V. This work offers a facile strategy to design efficient catalysts with heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2021, "Volume": 286, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119869, "DOI": "10.1016/j.apcatb.2020.119869", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119869", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621624900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XF; Chen, J; Zhou, J; Li, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiangfan; Chen, Jie; Zhou, Jun; Li, Baowen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal Conductivity of Polymers and Their nullocomposites", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers are usually considered as thermal insulators, and their applications are limited by their low thermal conductivity. However, recent studies have shown that certain polymers have surprisingly high thermal conductivity, some of which are comparable to that in poor metals or even silicon. Here, the experimental achievements and theoretical progress of thermal transport in polymers and their nullocomposites are outlined. The open questions and challenges of existing theories are discussed. Special attention is given to the mechanism of thermal transport, the enhancement of thermal conductivity in polymer nullocomposites/fibers, and their potential application as thermal interface materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 624, "Times Cited, All Databases": 652, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2018, "Volume": 30, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705544, "DOI": "10.1002/adma.201705544", "DOI Link": "http://dx.doi.org/10.1002/adma.201705544", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430660500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, J; Ren, PJ; Deng, DH; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Jiao; Ren, Pengju; Deng, Dehui; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Major challenges encountered when trying to replace precious-metal-based electrocatalysts of the hydrogen evolution reaction (HER) in acidic media are related to the low efficiency and stability of non-precious-metal compounds. Therefore, new concepts and strategies have to be devised to develop electrocatalysts that are based on earth-abundant materials. Herein, we report a hierarchical architecture that consists of ultrathin graphene shells (only 1-3 layers) that encapsulate a uniform CoNi nulloalloy to enhance its HER performance in acidic media. The optimized catalyst exhibits high stability and activity with an onset overpotential of almost zero versus the reversible hydrogen electrode (RHE) and an overpotential of only 142 mV at 10 mAcm(-2), which is quite close to that of commercial 40% Pt/C catalysts. Density functional theory (DFT) calculations indicate that the ultrathin graphene shells strongly promote electron penetration from the CoNi nulloalloy to the graphene surface. With nitrogen dopants, they synergistically increase the electron density on the graphene surface, which results in superior HER activity on the graphene shells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1160, "Times Cited, All Databases": 1202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2015, "Volume": 54, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2100, "End Page": 2104, "Article Number": null, "DOI": "10.1002/anie.201409524", "DOI Link": "http://dx.doi.org/10.1002/anie.201409524", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349391000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, JD; Graf, M; Liu, K; Ovchinnikov, D; Dumcenco, D; Heiranian, M; nulldigana, V; Aluru, NR; Kis, A; Radenovic, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Jiandong; Graf, Michael; Liu, Ke; Ovchinnikov, Dmitry; Dumcenco, Dumitru; Heiranian, Mohammad; nulldigana, Vishal; Aluru, Narayana R.; Kis, Andras; Radenovic, Aleksandra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-layer MoS2 nullopores as nullopower generators", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Making use of the osmotic pressure difference between fresh water and seawater is an attractive, renewable and clean way to generate power and is known as 'blue energy'(1-3). Another electrokinetic phenomenon, called the streaming potential, occurs when an electrolyte is driven through narrow pores either by a pressure gradient(4) or by an osmotic potential resulting from a salt concentration gradient(5). For this task, membranes made of two-dimensional materials are expected to be the most efficient, because water transport through a membrane scales inversely with membrane thickness(5-7). Here we demonstrate the use of single-layer molybdenum disulfide (MoS2) nullopores as osmotic nullopower generators. We observe a large, osmotically induced current produced from a salt gradient with an estimated power density of up to 10(6) watts per square metre-a current that can be attributed mainly to the atomically thin membrane of MoS2. Low power requirements for nulloelectronic and optoelectric devices can be provided by a neighbouring nullogenerator that harvests energy from the local environment(8-11)-for example, a piezoelectric zinc oxide nullowire array(8) or single-layer MoS2 (ref. 12). We use our MoS2 nullopore generator to power a MoS2 transistor, thus demonstrating a self-powered nullosystem.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 944, "Times Cited, All Databases": 1001, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2016, "Volume": 536, "Issue": 7615, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 197, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature18593", "DOI Link": "http://dx.doi.org/10.1038/nature18593", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381472100033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WQ; Nie, JH; Li, F; Wang, ZL; Sun, CQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenqiang; Nie, Jinhui; Li, Fan; Wang, Zhong Lin; Sun, Chunwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A durable and safe solid-state lithium battery with a hybrid electrolyte membrane", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-ceramic composite electrolytes are emerging as a promising solution to achieving high ionic conductivity, optimal mechanical properties, and good safety for developing high-performance all-solid-state rechargeable batteries. In this work, we report a garnet (Li7La3Zr2O12)-based hybrid solid electrolyte (HSE) membrane designed for high performance solid-state lithium batteries for the first time. The composite HSE membrane is composed of LLZO particles and PVDF-HFP polymer matrix. The solid-state lithium battery with this HSE membrane, Li metal anode and LiFePO4 cathode exhibits an initial reversible discharge capacity of 120 mA h g(-1) at a charge/discharge current density of 0.5 C at room temperature. This solid-state battery is used to store the energy harvested by a TENG at different rotation rates. The solid state battery can efficiently store the pulsed energy, especially for output at high frequencies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 45, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 413, "End Page": 419, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.01.028", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.01.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425396400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, ZY; Chen, GX; Siahrostami, S; Chen, ZH; Liu, K; Xie, J; Liao, L; Wu, T; Lin, DC; Liu, YY; Jaramillo, TF; Norskov, JK; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Zhiyi; Chen, Guangxu; Siahrostami, Samira; Chen, Zhihua; Liu, Kai; Xie, Jin; Liao, Lei; Wu, Tong; Lin, Dingchang; Liu, Yayuan; Jaramillo, Thomas F.; Norskov, Jens K.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is a valuable chemical with a wide range of applications, but the current industrial synthesis of H2O2 involves an energy-intensive anthraquinone process. The electrochemical synthesis of H2O2 from oxygen reduction offers an alternative route for on-site applications; the efficiency of this process depends greatly on identifying cost-effective catalysts with high activity and selectivity. Here, we demonstrate a facile and general approach to catalyst development via the surface oxidation of abundant carbon materials to significantly enhance both the activity and selectivity (similar to 90%) for H2O2 production by electrochemical oxygen reduction. We find that both the activity and selectivity are positively correlated with the oxygen content of the catalysts. The density functional theory calculations demonstrate that the carbon atoms adjacent to several oxygen functional groups (-COOH and C-O-C) are the active sites for oxygen reduction reaction via the two-electron pathway, which are further supported by a series of control experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1353, "Times Cited, All Databases": 1437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": 162, "Article Number": null, "DOI": "10.1038/s41929-017-0017-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0017-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428621500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shang, TX; Lin, ZF; Qi, CS; Liu, XC; Li, P; Tao, Y; Wu, ZT; Li, DW; Simon, P; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shang, Tongxin; Lin, Zifeng; Qi, Changsheng; Liu, Xiaochen; Li, Pei; Tao, Ying; Wu, Zhitan; Li, Dewang; Simon, Patrice; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Macroscopic Architectures from Self-Assembled MXene Hydrogels", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Assembly of 2D MXene sheets into a 3D macroscopic architecture is highly desirable to overcome the severe restacking problem of 2D MXene sheets and develop MXene-based functional materials. However, unlike graphene, 3D MXene macroassembly directly from the individual 2D sheets is hard to achieve for the intrinsic property of MXene. Here a new gelation method is reported to prepare a 3D structured hydrogel from 2D MXene sheets that is assisted by graphene oxide and a suitable reductant. As a supercapacitor electrode, the hydrogel delivers a superb capacitance up to 370 F g(-1) at 5 A g(-1), and more promisingly, demonstrates an exceptionally high rate performance with the capacitance of 165 F g(-1) even at 1000 A g(-1). Moreover, using controllable drying processes, MXene hydrogels are transformed into different monoliths with structures ranging from a loosely organized porous aerogel to a dense solid. As a result, a 3D porous MXene aerogel shows excellent adsorption capacity to simultaneously remove various classes of organic liquids and heavy metal ions while the dense solid has excellent mechanical performance with a high Young's modulus and hardness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 29, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903960, "DOI": "10.1002/adfm.201903960", "DOI Link": "http://dx.doi.org/10.1002/adfm.201903960", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482137900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "MacFarlane, DR; Tachikawa, N; Forsyth, M; Pringle, JM; Howlett, PC; Elliott, GD; Davis, JH; Watanabe, M; Simon, P; Angell, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "MacFarlane, Douglas R.; Tachikawa, Naoki; Forsyth, Maria; Pringle, Jennifer M.; Howlett, Patrick C.; Elliott, Gloria D.; Davis, James H., Jr.; Watanabe, Masayoshi; Simon, Patrice; Angell, C. Austen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy applications of ionic liquids", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ionic liquids offer a unique suite of properties that make them important candidates for a number of energy related applications. Cation-anion combinations that exhibit low volatility coupled with high electrochemical and thermal stability, as well as ionic conductivity, create the possibility of designing ideal electrolytes for batteries, super-capacitors, actuators, dye sensitised solar cells and thermo-electrochemical cells. In the field of water splitting to produce hydrogen they have been used to synthesize some of the best performing water oxidation catalysts and some members of the protic ionic liquid family co-catalyse an unusual, very high energy efficiency water oxidation process. As fuel cell electrolytes, the high proton conductivity of some of the protic ionic liquid family offers the potential of fuel cells operating in the optimum temperature region above 100 degrees C. Beyond electrochemical applications, the low vapour pressure of these liquids, along with their ability to offer tuneable functionality, also makes them ideal as CO2 absorbents for post-combustion CO2 capture. Similarly, the tuneable phase properties of the many members of this large family of salts are also allowing the creation of phase-change thermal energy storage materials having melting points tuned to the application. This perspective article provides an overview of these developing energy related applications of ionic liquids and offers some thoughts on the emerging challenges and opportunities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1445, "Times Cited, All Databases": 1562, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 232, "End Page": 250, "Article Number": null, "DOI": "10.1039/c3ee42099j", "DOI Link": "http://dx.doi.org/10.1039/c3ee42099j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329550700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, LT; Yang, Y; You, JB; Hong, ZR; Chang, WH; Li, G; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Letian; Yang, Yang (Micheal); You, Jingbi; Hong, Ziruo; Chang, Wei-Hsuan; Li, Gang; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution-processed hybrid perovskite photodetectors with high detectivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photodetectors capture optical signals with a wide range of incident photon flux density and convert them to electrical signals instantaneously. They have many important applications including imaging, optical communication, remote control, chemical/biological sensing and so on. Currently, GaN, Si and InGaAs photodetectors are used in commercially available products. Here we demonstrate a novel solution-processed photodetector based on an organic-inorganic hybrid perovskite material. Operating at room temperature, the photodetectors exhibit a large detectivity (the ability to detect weak signals) approaching 10(14) Jones, a linear dynamic range over 100 decibels (dB) and a fast photoresponse with 3-dB bandwidth up to 3 MHz. The performance is significantly better than most of the organic, quantum dot and hybrid photodetectors reported so far; and is comparable, or even better than, the traditional inorganic semiconductor-based photodetectors. Our results indicate that with proper device interface design, perovskite materials are promising candidates for low-cost, high-performance photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2396, "Times Cited, All Databases": 2547, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5404, "DOI": "10.1038/ncomms6404", "DOI Link": "http://dx.doi.org/10.1038/ncomms6404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345624800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JZ; Chen, MJ; Cullen, DA; Hwang, S; Wang, MY; Li, BY; Liu, KX; Karakalos, S; Lucero, M; Zhang, HG; Lei, C; Xu, H; Sterbinsky, GE; Feng, ZX; Su, D; More, KL; Wang, GF; Wang, ZB; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiazhan; Chen, Mengjie; Cullen, David A.; Hwang, Sooyeon; Wang, Maoyu; Li, Boyang; Liu, Kexi; Karakalos, Stavros; Lucero, Marcos; Zhang, Hanguang; Lei, Chao; Xu, Hui; Sterbinsky, George E.; Feng, Zhenxing; Su, Dong; More, Karren L.; Wang, Guofeng; Wang, Zhenbo; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum group metal (PGM)-free catalysts that are also iron free are highly desirable for the oxygen reduction reaction (ORR) in proton-exchange membrane fuel cells, as they avoid possible Fenton reactions. Here we report an efficient ORR catalyst that consists of atomically dispersed nitrogen-coordinated single Mn sites on partially graphitic carbon (Mn-N-C). Evidence for the embedding of the atomically dispersed MnN4 moieties within the carbon surface-exposed basal planes was established by X-ray absorption spectroscopy and their dispersion was confirmed by aberration-corrected electron microscopy with atomic resolution. The Mn-N-C catalyst exhibited a half-wave potential of 0.80 V versus the reversible hydrogen electrode, approaching that of Fe-N-C catalysts, along with significantly enhanced stability in acidic media. The encouraging performance of the Mn-N-C catalyst as a PGM-free cathode was demonstrated in fuel cell tests. First-principles calculations further support the MnN4 sites as the origin of the ORR activity via a 4e(-) pathway in acidic media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1208, "Times Cited, All Databases": 1262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 1, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 935, "End Page": 945, "Article Number": null, "DOI": "10.1038/s41929-018-0164-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0164-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452918800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Varcoe, JR; Atanassov, P; Dekel, DR; Herring, AM; Hickner, MA; Kohl, PA; Kucernak, AR; Mustain, WE; Nijmeijer, K; Scott, K; Xu, TW; Zhuang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Varcoe, John R.; Atanassov, Plamen; Dekel, Dario R.; Herring, Andrew M.; Hickner, Michael A.; Kohl, Paul. A.; Kucernak, Anthony R.; Mustain, William E.; Nijmeijer, Kitty; Scott, Keith; Xu, Tongwen; Zhuang, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion-exchange membranes in electrochemical energy systems", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article provides an up-to-date perspective on the use of anion-exchange membranes in fuel cells, electrolysers, redox flow batteries, reverse electrodialysis cells, and bioelectrochemical systems (e.g. microbial fuel cells). The aim is to highlight key concepts, misconceptions, the current state-of-the-art, technological and scientific limitations, and the future challenges (research priorities) related to the use of anion-exchange membranes in these energy technologies. All the references that the authors deemed relevant, and were available on the web by the manuscript submission date (30th April 2014), are included.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1703, "Times Cited, All Databases": 1878, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3135, "End Page": 3191, "Article Number": null, "DOI": "10.1039/c4ee01303d", "DOI Link": "http://dx.doi.org/10.1039/c4ee01303d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342884300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, LS; Cong, ZX; Cao, JB; Ke, KM; Peng, QL; Gao, JH; Yang, HH; Liu, G; Chen, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Li-Sen; Cong, Zhong-Xiao; Cao, Jian-Bo; Ke, Kai-Mei; Peng, Qiao-Li; Gao, Jinhao; Yang, Huang-Hao; Liu, Gang; Chen, Xiaoyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Fe3O4@Polydopamine Core-Shell nullocomposites for Intracellular mRNA Detection and Imaging-Guided Photothermal Therapy", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional nullocomposites have the potential to integrate sensing, diagnostic, and therapeutic functions into a single nullostructure. Herein, we synthesize Fe3O4@polydopamine core shell nullocomposites (Fe3O4@PDA NCs) through an in situ self-polymerization method. Dopamine, a melanin-like mimic of mussel adhesive proteins, can self-polymerize to form surface-adherent polydopamine (PDA) films onto a wide range of materials including Fe3O4 nulloparticles used here. In such nullocomposites, PDA provides a number of advantages, such as near-infrared absorption, high fluorescence quenching efficiency, and a surface for further functionalization with biomolecules. We demonstrate the ability of the Fe3O4@PDA NCs to act as theranostic agents for intracellular mRNA detection and multimodal imaging-guided photothermal therapy. This work would stimulate interest in the use of PDA as a useful material to construct multifunctional nullocomposites for biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 640, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3876, "End Page": 3883, "Article Number": null, "DOI": "10.1021/nn500722y", "DOI Link": "http://dx.doi.org/10.1021/nn500722y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334990600085", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McMeekin, DP; Sadoughi, G; Rehman, W; Eperon, GE; Saliba, M; Hörantner, MT; Haghighirad, A; Sakai, N; Korte, L; Rech, B; Johnston, MB; Herz, LM; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McMeekin, David P.; Sadoughi, Golnaz; Rehman, Waqaas; Eperon, Giles E.; Saliba, Michael; Hoerantner, Maximilian T.; Haghighirad, Amir; Sakai, Nobuya; Korte, Lars; Rech, Bernd; Johnston, Michael B.; Herz, Laura M.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskite photovoltaic cells could potentially boost the efficiency of commercial silicon photovoltaic modules from similar to 20 toward 30% when used in tandem architectures. An optimum perovskite cell optical band gap of similar to 1.75 electron volts (eV) can be achieved by varying halide composition, but to date, such materials have had poor photostability and thermal stability. Here we present a highly crystalline and compositionally photostable material, [HC(NH2)(2)](0.83)Cs0.17Pb(I0.6Br0.4)(3), with an optical band gap of similar to 1.74 eV, and we fabricated perovskite cells that reached open-circuit voltages of 1.2 volts and power conversion efficiency of over 17% on small areas and 14.7% on 0.715 cm(2) cells. By combining these perovskite cells with a 19%-efficient silicon cell, we demonstrated the feasibility of achieving >25%-efficient four-terminal tandem cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2577, "Times Cited, All Databases": 2797, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 351, "Issue": 6269, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 151, "End Page": 155, "Article Number": null, "DOI": "10.1126/science.aad5845", "DOI Link": "http://dx.doi.org/10.1126/science.aad5845", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367806500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SH; Wang, ZY; Zhou, S; Yu, FJ; Yu, MZ; Chiang, CY; Zhou, WZ; Zhao, JJ; Qiu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shaohong; Wang, Zhiyu; Zhou, Si; Yu, Fengjiao; Yu, Mengzhou; Chiang, Chang-Yang; Zhou, Wuzong; Zhao, Jijun; Qiu, Jieshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic-Framework-Derived Hybrid Carbon nullocages as a Bifunctional Electrocatalyst for Oxygen Reduction and Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are cornerstone reactions for many renewable energy technologies. Developing cheap yet durable substitutes of precious-metal catalysts, especially the bifunctional electrocatalysts with high activity for both ORR and OER reactions and their streamlined coupling process, are highly desirable to reduce the processing cost and complexity of renewable energy systems. Here, a facile strategy is reported for synthesizing double-shelled hybrid nullocages with outer shells of Co-N-doped graphitic carbon (Co-NGC) and inner shells of N-doped microporous carbon (NC) by templating against core-shell metal-organic frameworks. The double-shelled NC@Co-NGC nullocages well integrate the high activity of Co-NGC shells into the robust NC hollow framework with enhanced diffusion kinetics, exhibiting superior electrocatalytic properties to Pt and RuO2 as a bifunctional electrocatalyst for ORR and OER, and hold a promise as efficient air electrode catalysts in Zn-air batteries. First-principles calculations reveal that the high catalytic activities of Co-NGC shells are due to the synergistic electron transfer and redistribution between the Co nulloparticles, the graphitic carbon, and the doped N species. Strong yet favorable adsorption of an OOH* intermediate on the high density of uncoordinated hollowsite C atoms with respect to the Co lattice in the Co-NGC structure is a vital rate-determining step to achieve excellent bifunctional electrocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 735, "Times Cited, All Databases": 757, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2017, "Volume": 29, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700874, "DOI": "10.1002/adma.201700874", "DOI Link": "http://dx.doi.org/10.1002/adma.201700874", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407565700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Severson, KA; Attia, PM; Jin, N; Perkins, N; Jiang, B; Yang, Z; Chen, MH; Aykol, M; Herring, PK; Fraggedakis, D; Bazan, MZ; Harris, SJ; Chueh, WC; Braatz, RD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Severson, Kristen A.; Attia, Peter M.; Jin, Norman; Perkins, Nicholas; Jiang, Benben; Yang, Zi; Chen, Michael H.; Aykol, Muratahan; Herring, Patrick K.; Fraggedakis, Dimitrios; Bazan, Martin Z.; Harris, Stephen J.; Chueh, William C.; Braatz, Richard D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-driven prediction of battery cycle life before capacity degradation", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurately predicting the lifetime of complex, nonlinear systems such as lithium-ion batteries is critical for accelerating technology development. However, diverse aging mechanisms, significant device variability and dynamic operating conditions have remained major challenges. We generate a comprehensive dataset consisting of 124 commercial lithium iron phosphate/graphite cells cycled under fast-charging conditions, with widely varying cycle lives ranging from 150 to 2,300 cycles. Using discharge voltage curves from early cycles yet to exhibit capacity degradation, we apply machine-learning tools to both predict and classify cells by cycle life. Our best models achieve 9.1% test error for quantitatively predicting cycle life using the first 100 cycles (exhibiting a median increase of 0.2% from initial capacity) and 4.9% test error using the first 5 cycles for classifying cycle life into two groups. This work highlights the promise of combining deliberate data generation with data-driven modelling to predict the behaviour of complex dynamical systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1569, "Times Cited, All Databases": 1690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 383, "End Page": 391, "Article Number": null, "DOI": "10.1038/s41560-019-0356-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0356-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467965700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Zhai, Y; He, SM; Gan, WT; Wei, ZY; Heidarinejad, M; Dalgo, D; Mi, RY; Zhao, XP; Song, JW; Dai, JQ; Chen, CJ; Aili, A; Vellore, A; Martini, A; Yang, RG; Srebric, J; Yin, XB; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tian; Zhai, Yao; He, Shuaiming; Gan, Wentao; Wei, Zhiyuan; Heidarinejad, Mohammad; Dalgo, Daniel; Mi, Ruiyu; Zhao, Xinpeng; Song, Jianwei; Dai, Jiaqi; Chen, Chaoji; Aili, Ablimit; Vellore, Azhar; Martini, Ashlie; Yang, Ronggui; Srebric, Jelena; Yin, Xiaobo; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A radiative cooling structural material", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing human reliance on energy-inefficient cooling methods such as air conditioning would have a large impact on the global energy landscape. By a process of complete delignification and densification of wood, we developed a structural material with a mechanical strength of 404.3 megapascals, more than eight times that of natural wood. The cellulose nullofibers in our engineered material backscatter solar radiation and emit strongly in mid-infrared wavelengths, resulting in continuous subambient cooling during both day and night. We model the potential impact of our cooling wood and find energy savings between 20 and 60%, which is most pronounced in hot and dry climates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1081, "Times Cited, All Databases": 1158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2019, "Volume": 364, "Issue": 6442, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 760, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau9101", "DOI Link": "http://dx.doi.org/10.1126/science.aau9101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469296000039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, NC; Stambula, S; Wang, D; Banis, MN; Liu, J; Riese, A; Xiao, BW; Li, RY; Sham, TK; Liu, LM; Botton, GA; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Niancai; Stambula, Samantha; Wang, Da; Banis, Mohammad Norouzi; Liu, Jian; Riese, Adam; Xiao, Biwei; Li, Ruying; Sham, Tsun-Kong; Liu, Li-Min; Botton, Gianluigi A.; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum single-atom and cluster catalysis of the hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum-based catalysts have been considered the most effective electrocatalysts for the hydrogen evolution reaction in water splitting. However, platinum utilization in these electrocatalysts is extremely low, as the active sites are only located on the surface of the catalyst particles. Downsizing catalyst nulloparticles to single atoms is highly desirable to maximize their efficiency by utilizing nearly all platinum atoms. Here we report on a practical synthesis method to produce isolated single platinum atoms and clusters using the atomic layer deposition technique. The single platinum atom catalysts are investigated for the hydrogen evolution reaction, where they exhibit significantly enhanced catalytic activity (up to 37 times) and high stability in comparison with the state-of-the-art commercial platinum/carbon catalysts. The X-ray absorption fine structure and density functional theory analyses indicate that the partially unoccupied density of states of the platinum atoms' 5d orbitals on the nitrogen-doped graphene are responsible for the excellent performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1711, "Times Cited, All Databases": 1810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13638, "DOI": "10.1038/ncomms13638", "DOI Link": "http://dx.doi.org/10.1038/ncomms13638", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388872900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Frost, JM; Butler, KT; Brivio, F; Hendon, CH; van Schilfgaarde, M; Walsh, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Frost, Jarvist M.; Butler, Keith T.; Brivio, Federico; Hendon, Christopher H.; van Schilfgaarde, Mark; Walsh, Aron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of organometallic perovskite solar cells has rapidly surpassed that of both conventional dye-sensitized and organic photovoltaics. High-power conversion efficiency can be realized in both mesoporous and thin-film device architectures. We address the origin of this success in the context of the materials chemistry and physics of the bulk perovskite as described by electronic structure calculations. In addition to the basic optoelectronic properties essential for an efficient photovoltaic device (spectrally suitable band gap, high optical absorption, low carrier effective masses), the materials are structurally and compositionally flexible. As we show, hybrid perovskites exhibit spontaneous electric polarization; we also suggest ways in which this can be tuned through judicious choice of the organic cation. The presence of ferroelectric domains will result in internal junctions that may aid separation of photoexcited electron and hole pairs, and reduction of recombination through segregation of charge carriers. The combination of high dielectric constant and low effective mass promotes both Wannier-Mott exciton separation and effective ionization of donor and acceptor defects. The photoferroic effect could be exploited in nullostructured films to generate a higher open circuit voltage and may contribute to the current-voltage hysteresis observed in perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2052, "Times Cited, All Databases": 2190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2584, "End Page": 2590, "Article Number": null, "DOI": "10.1021/nl500390f", "DOI Link": "http://dx.doi.org/10.1021/nl500390f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336074800054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, WY; Tsai, HH; Asadpour, R; Blancon, JC; Neukirch, AJ; Gupta, G; Crochet, JJ; Chhowalla, M; Tretiak, S; Alam, MA; Wang, HL; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Wanyi; Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe; Neukirch, Amanda J.; Gupta, Gautam; Crochet, Jared J.; Chhowalla, Manish; Tretiak, Sergei; Alam, Muhammad A.; Wang, Hsing-Lin; Mohite, Aditya D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency solution-processed perovskite solar cells with millimeter-scale grains", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "State-of-the-art photovoltaics use high-purity, large-area, wafer-scale single-crystalline semiconductors grown by sophisticated, high-temperature crystal growth processes. We demonstrate a solution-based hot-casting technique to grow continuous, pinhole-free thin films of organometallic perovskites with millimeter-scale crystalline grains. We fabricated planar solar cells with efficiencies approaching 18%, with little cell-to-cell variability. The devices show hysteresis-free photovoltaic response, which had been a fundamental bottleneck for the stable operation of perovskite devices. Characterization and modeling attribute the improved performance to reduced bulk defects and improved charge carrier mobility in large-grain devices. We anticipate that this technique will lead the field toward synthesis of wafer-scale crystalline perovskites, necessary for the fabrication of high-efficiency solar cells, and will be applicable to several other material systems plagued by polydispersity, defects, and grain boundary recombination in solution-processed thin films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2941, "Times Cited, All Databases": 3159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2015, "Volume": 347, "Issue": 6221, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 522, "End Page": 525, "Article Number": null, "DOI": "10.1126/science.aaa0472", "DOI Link": "http://dx.doi.org/10.1126/science.aaa0472", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348639300046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, LT; Wong, AB; Yu, Y; Lai, ML; Kornienko, N; Eaton, SW; Fu, A; Bischak, CG; Ma, J; Ding, TN; Ginsberg, NS; Wang, LW; Alivisatos, AP; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Letian; Wong, Andrew B.; Yu, Yi; Lai, Minliang; Kornienko, Nikolay; Eaton, Samuel W.; Fu, Anthony; Bischak, Connor G.; Ma, Jie; Ding, Tina; Ginsberg, Naomi S.; Wang, Lin-Wang; Alivisatos, A. Paul; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically thin two-dimensional organic-inorganic hybrid perovskites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskites, which have proved to be promising semiconductor materials for photovoltaic applications, have been made into atomically thin two-dimensional (2D) sheets. We report the solution-phase growth of single-and few-unit-cell-thick single-crystalline 2D hybrid perovskites of (C4H9NH3)(2)PbBr4 with well-defined square shape and large size. In contrast to other 2D materials, the hybrid perovskite sheets exhibit an unusual structural relaxation, and this structural change leads to a band gap shift as compared to the bulk crystal. The high-quality 2D crystals exhibit efficient photoluminescence, and color tuning could be achieved by changing sheet thickness as well as composition via the synthesis of related materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1166, "Times Cited, All Databases": 1277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2015, "Volume": 349, "Issue": 6255, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1518, "End Page": 1521, "Article Number": null, "DOI": "10.1126/science.aac7660", "DOI Link": "http://dx.doi.org/10.1126/science.aac7660", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361707000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, LF; Lu, Y; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Li-Feng; Lu, Yan; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designed formation of hollow particle-based nitrogen-doped carbon nullofibers for high-performance supercapacitors", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-based materials, as one of the most important electrode materials for supercapacitors, have attracted tremendous attention. At present, it is highly desirable but remains challenging to prepare one-dimensional carbon complex hollow nullomaterials for further improving the performance of supercapacitors. Herein, we report an effective strategy for the synthesis of hollow particle-based nitrogen-doped carbon nullofibers (HPCNFs-N). By embedding ultrafine zeolitic imidazolate framework (ZIF-8) nulloparticles into electrospun polyacrylonitrile (PAN), the as-prepared composite nullofibers are carbonized into hierarchical porous nullofibers composed of interconnected nitrogen-doped carbon hollow nulloparticles. Owing to its unique structural feature and the desirable chemical composition, the derived HPCNFs-N material exhibits much enhanced electrochemical properties as an electrode material for supercapacitors with remarkable specific capacitance at various current densities, high energy/power density and long cycling stability over 10 000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 784, "Times Cited, All Databases": 811, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1777, "End Page": 1783, "Article Number": null, "DOI": "10.1039/c7ee00488e", "DOI Link": "http://dx.doi.org/10.1039/c7ee00488e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407211200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, F; Sun, TL; Nakajima, T; Kurokawa, T; Zhao, Y; Sato, K; Bin Ihsan, A; Li, XF; Guo, HL; Gong, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Feng; Sun, Tao Lin; Nakajima, Tasuku; Kurokawa, Takayuki; Zhao, Yu; Sato, Koshiro; Bin Ihsan, Abu; Li, Xufeng; Guo, Honglei; Gong, Jian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oppositely Charged Polyelectrolytes Form Tough, Self-Healing, and Rebuildable Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A series of tough polyion complex hydrogels is synthesized by sequential homopolymerization of cationic and anionic monomers. Owing to the reversible interpolymer ionic bonding, the materials are self-healable under ambient conditions with the aid of saline solution. Furthermore, self-glued bulk hydrogels can be built from their microgels, which is promising for 3D/4D printing and the additive manufacturing of hydrogels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 592, "Times Cited, All Databases": 633, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2015, "Volume": 27, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2722, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201500140", "DOI Link": "http://dx.doi.org/10.1002/adma.201500140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354217000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, RF; Wang, Y; Ma, Y; Mal, A; Gao, XY; Gao, L; Qiao, LJ; Li, XB; Wu, LZ; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Rufan; Wang, Yang; Ma, Yuan; Mal, Arindam; Gao, Xiao-Ya; Gao, Lei; Qiao, Lijie; Li, Xu-Bing; Wu, Li-Zhu; Wang, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks have recently gained increasing attention in photocatalytic hydrogen generation from water. However, their structure-property-activity relationship, which should be beneficial for the structural design, is still far-away explored. Herein, we report the designed synthesis of four isostructural porphyrinic two-dimensional covalent organic frameworks (MPor-DETH-COF, M=H-2, Co, Ni, Zn) and their photocatalytic activity in hydrogen generation. Our results clearly show that all four covalent organic frameworks adopt AA stacking structures, with high crystallinity and large surface area. Interestingly, the incorporation of different transition metals into the porphyrin rings can rationally tune the photocatalytic hydrogen evolution rate of corresponding covalent organic frameworks, with the order of CoPor-DETH-COF", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1354, "DOI": "10.1038/s41467-021-21527-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21527-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626168500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZJ; Liu, B; Wang, JQ; Zhang, SY; Lin, QQ; Gong, PW; Ma, LM; Yang, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zengjie; Liu, Bin; Wang, Jinqing; Zhang, Songying; Lin, Qianqian; Gong, Peiwei; Ma, Limin; Yang, Shengrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Wound Dressing Based on Ag/Graphene Polymer Hydrogel: Effectively Kill Bacteria and Accelerate Wound Healing", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Avoiding wound infection and retaining an appropriate level of moisture around woundz are major challenges in wound care management. Therefore, designing hydrogels with desired antibacterial performance and good water-maintaining ability is of particular significance to promote the development of wound dressing. Thus a series of hydrogels are prepared by crosslinking of Ag/graphene composites with acrylic acid and N,N'-methylene bisacrylamide at different mass ratios. The antibacterial performance and accelerated wound-healing ability of hydrogel are systematically evaluated with the aim of attaining a novel and effective wound dressing. The as-prepared hydrogel with the optimal Ag to graphene mass ratio of 5:1 (Ag5G1) exhibits stronger antibacterial abilities than other hydrogels. Meanwhile, Ag5G1 hydrogel exhibits excellent biocompatibility, high swelling ratio, and good extensibility. More importantly, in vivo experiments indicate that Ag5G1 hydrogel can significantly accelerate the healing rate of artificial wounds in rats, and histological examination reveals that it helps to successfully reconstruct intact and thickened epidermis during 15 day of healing of impaired wounds. In one word, the present approach can shed new light on designing of antibacterial material like Ag/graphene composite hydrogel with promising applications in wound dressing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 684, "Times Cited, All Databases": 707, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2014, "Volume": 24, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3933, "End Page": 3943, "Article Number": null, "DOI": "10.1002/adfm.201304202", "DOI Link": "http://dx.doi.org/10.1002/adfm.201304202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338011200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, HH; Zhang, QR; Shen, BX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Honghong; Zhang, Qianru; Shen, Boxiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application of biochar and its composites in catalysis", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With a wide range of raw materials, low cost and large specific surface area, biochar has been widely used in environmental remediation. However, the biochar has a saturated adsorption capacity when it is used as a pollutant adsorbent. Recent efforts have been made to prepare biochar and biochar-based catalysts with enhanced catalytic properties to expand their potential applications. The environmental persistent free radicals (EPFRs) of biochar could react with O-2 to induce hydroxyl radicals (center dot OH) without the addition of oxidants. When oxidants were added, biochar and biochar-based catalysts could activate them to generate center dot OH and sulfate radicals (SO4 center dot-), respectively. Moreover, biochar could act as an electron acceptor to improve the photodegradation capacity of catalysts. With reference to the information regarding biochar and biochar-based catalysts, this work provides a critical review on recent research development as follows: 1) the preparations of various types of biochar and biochar-based catalysts are summarized; 2) the effects of the synthetic conditions and transition metals on the catalytic activity of biochar-based catalysts are discussed; (3) methods for characterizing the active sites of the biochar-based catalysts are described; and (4) the environmental applications of biochar and biochar-based catalysts are discussed with regards to three aspects based on the interaction mechanisms, namely, oxidation, reduction, and photocatalysis. The synthesis conditions and loading of metal/metal-free catalyst are key parameters controlling the catalysis activity of biochar and biochar-based catalysts. This review provides new insights into the application of biochar in catalysis. Key challenges and further research directions are proposed as well. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 240, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124842, "DOI": "10.1016/j.chemosphere.2019.124842", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2019.124842", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497600800128", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, FF; Zhao, MT; Yu, YF; Chen, B; Huang, Y; Yang, J; Cao, XH; Lu, QP; Zhang, X; Zhang, ZC; Tan, CL; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Feifei; Zhao, Meiting; Yu, Yifu; Chen, Bo; Huang, Ying; Yang, Jian; Cao, Xiehong; Lu, Qipeng; Zhang, Xiao; Zhang, Zhicheng; Tan, Chaoliang; Zhang, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Two-Dimensional CoS1.097/Nitrogen-Doped Carbon nullocomposites Using Metal-Organic Framework nullosheets as Precursors for Supercapacitor Application", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) metal organic framework (MOP) nullosheets are attracting increasing research interest. Here, for the first time, we report the facile synthesis of 2D porphyrin paddlewheel framework-3 (PPF-3) MOF nullosheets with thickness of ca. 12-43 nm. Through the simultaneous sulfidation and carbonization of PPF-3 MOF nullosheets, we have prepared the nullocomposite of CoS1.097 nulloparticles (NPs) and nitrogen-doped carbon, referred to as CoSNC, in which the CoS1.097 NPs with size of ca. 10 nm are embedded in the nitrogen-doped carbon matrix. As a proof-of-concept application, the obtained 2D CoSNC nullocomposite is used as an electrode material for a supercapacitor, exhibits a specific capacitance of 360.1 F g(-1) at a current density of 1.5 A g(-1). Moreover, the composite electrode also shows high rate capability. Its specific capacitance delivered at a current density of 30.0 A g(-1) retains 56.8% of the value at 1.5 A g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 629, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2016, "Volume": 138, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6924, "End Page": 6927, "Article Number": null, "DOI": "10.1021/jacs.6b02540", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b02540", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377643300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Xie, XQ; Anasori, B; Sarycheva, A; Makaryan, T; Zhao, MQ; Urbankowski, P; Miao, L; Jiang, JJ; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Xie, Xiuqiang; Anasori, Babak; Sarycheva, Asya; Makaryan, Taron; Zhao, Mengqiang; Urbankowski, Patrick; Miao, Ling; Jiang, Jianjun; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) heterostructured materials, combining the collective advantages of individual building blocks and synergistic properties, have spurred great interest as a new paradigm in materials science. The family of 2D transition-metal carbides and nitrides, MXenes, has emerged as an attractive platform to construct functional materials with enhanced performance for diverse applications. Here, we synthesized 2D MoS2-on-MXene heterostructures through in situ sulfidation of Mo2TiC2Tx MXene. The computational results show that MoS2-on-MXene heterostructures have metallic properties. Moreover, the presence of MXene leads to enhanced Li and Li2S adsorption during the intercalation and conversion reactions. These characteristics render the as-prepared MoS2-on-MXene heterostructures stable Li-ion storage performance. This work paves the way to use MXene to construct 2D heterostructures for energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 618, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2018, "Volume": 57, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1846, "End Page": 1850, "Article Number": null, "DOI": "10.1002/anie.201710616", "DOI Link": "http://dx.doi.org/10.1002/anie.201710616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424212300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Y; Jiao, Y; Zhu, YH; Li, LH; Han, Y; Chen, Y; Du, AJ; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Yao; Jiao, Yan; Zhu, Yihan; Li, Lu Hua; Han, Yu; Chen, Ying; Du, Aijun; Jaroniec, Mietek; Qiao, Shi Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen evolution by a metal-free electrocatalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic reduction of water to molecular hydrogen via the hydrogen evolution reaction may provide a sustainable energy supply for the future, but its commercial application is hampered by the use of precious platinum catalysts. All alternatives to platinum thus far are based on nonprecious metals, and, to our knowledge, there is no report about a catalyst for electrocatalytic hydrogen evolution beyond metals. Here we couple graphitic-carbon nitride with nitrogen-doped graphene to produce a metal-free hybrid catalyst, which shows an unexpected hydrogen evolution reaction activity with comparable overpotential and Tafel slope to some of well-developed metallic catalysts. Experimental observations in combination with density functional theory calculations reveal that its unusual electrocatalytic properties originate from an intrinsic chemical and electronic coupling that synergistically promotes the proton adsorption and reduction kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1951, "Times Cited, All Databases": 2025, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3783, "DOI": "10.1038/ncomms4783", "DOI Link": "http://dx.doi.org/10.1038/ncomms4783", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335375400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chaudhuri, O; Gu, L; Klumpers, D; Darnell, M; Bencherif, SA; Weaver, JC; Huebsch, N; Lee, HP; Lippens, E; Duda, GN; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chaudhuri, Ovijit; Gu, Luo; Klumpers, Darinka; Darnell, Max; Bencherif, Sidi A.; Weaver, James C.; Huebsch, Nathaniel; Lee, Hong-pyo; Lippens, Evi; Duda, Georg N.; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogels with tunable stress relaxation regulate stem cell fate and activity", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural extracellular matrices (ECMs) are viscoelastic and exhibit stress relaxation. However, hydrogels used as synthetic ECMs for three-dimensional (3D) culture are typically elastic. Here, we report a materials approach to tune the rate of stress relaxation of hydrogels for 3D culture, independently of the hydrogel's initial elastic modulus, degradation, and cell-adhesion-ligand density. We find that cell spreading, proliferation, and osteogenic differentiation of mesenchymal stem cells (MSCs) are all enhanced in cells cultured in gels with faster relaxation. Strikingly, MSCs form a mineralized, collagen-1-rich matrix similar to bone in rapidly relaxing hydrogels with an initial elastic modulus of 17 kPa. We also show that the effects of stress relaxation are mediated by adhesion-ligand binding, actomyosin contractility and mechanical clustering of adhesion ligands. Our findings highlight stress relaxation as a key characteristic of cell-ECM interactions and as an important design parameter of biomaterials for cell culture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1758, "Times Cited, All Databases": 1971, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 326, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4489", "DOI Link": "http://dx.doi.org/10.1038/NMAT4489", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370967400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, F; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Fang; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction is a key reaction in water splitting. The common approach in the development of oxygen evolution catalysts is to search for catalytic materials with new and optimized chemical compositions and structures. Here we report an orthogonal approach to improve the activity of catalysts without alternating their compositions or structures. Specifically, liquid phase exfoliation is applied to enhance the oxygen evolution activity of layered double hydroxides. The exfoliated single-layer nullosheets exhibit significantly higher oxygen evolution activity than the corresponding bulk layered double hydroxides in alkaline conditions. The nullosheets from nickel iron and nickel cobalt layered double hydroxides outperform a commercial iridium dioxide catalyst in both activity and stability. The exfoliation creates more active sites and improves the electronic conductivity. This work demonstrates the promising catalytic activity of single-layered double hydroxides for the oxygen evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2019, "Times Cited, All Databases": 2119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4477, "DOI": "10.1038/ncomms5477", "DOI Link": "http://dx.doi.org/10.1038/ncomms5477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340623400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdel-Mageed, AM; Rungtaweevoranit, B; Parlinska-Wojtan, M; Pei, XK; Yaghi, OM; Behm, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdel-Mageed, Ali M.; Rungtaweevoranit, Bunyarat; Parlinska-Wojtan, Magdalena; Pei, Xiaokun; Yaghi, Omar M.; Behm, R. Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts are often considered as the ultimate design principle for supported catalysts, due to their unique geometric and electronic properties and their highly efficient use of precious materials. Here, we report a single-atom catalyst, Cu/UiO-66, prepared by a covalent attachment of Cu atoms to the defect sites at the zirconium oxide clusters of the metal-organic framework (MOF) UiO-66. Kinetic measurements show this catalyst to be highly active and stable under realistic reaction conditions for two important test reactions, the oxidation of CO at temperatures up to 350 degrees C, which makes this interesting for application in catalytic converters for cars, and for CO removal via selective oxidation of CO in H-2-rich feed gases, where it shows an excellent selectivity of about 100% for CO oxidation. Time-resolved operando spectroscopy measurements indicate that the activity of the catalyst is associated with atomically dispersed, positively charged ionic Cu species. Density functional theory (DFT) calculations in combination with experimental data show that Cu binds to the MOF by -OH/-OH2 ligands capping the defect sites at the Zr oxide clusters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2019, "Volume": 141, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5201, "End Page": 5210, "Article Number": null, "DOI": "10.1021/jacs.8b11386", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b11386", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463843700024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gan, DL; Xing, WS; Jiang, LL; Fang, J; Zhao, CC; Ren, FZ; Fang, LM; Wang, KF; Lu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gan, Donglin; Xing, Wensi; Jiang, Lili; Fang, Ju; Zhao, Cancan; Ren, Fuzeng; Fang, Liming; Wang, Kefeng; Lu, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plant-inspired adhesive and tough hydrogel based on Ag-Lignin nulloparticles-triggered dynamic redox catechol chemistry", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesive hydrogels have gained popularity in biomedical applications, however, traditional adhesive hydrogels often exhibit short-term adhesiveness, poor mechanical properties and lack of antibacterial ability. Here, a plant-inspired adhesive hydrogel has been developed based on Ag-Lignin nulloparticles (NPs)triggered dynamic redox catechol chemistry. Ag-Lignin NPs construct the dynamic catechol redox system, which creates long-lasting reductive-oxidative environment inner hydrogel networks. This redox system, generating catechol groups continuously, endows the hydrogel with long-term and repeatable adhesiveness. Furthermore, Ag-Lignin NPs generate free radicals and trigger self-gelation of the hydrogel under ambient environment. This hydrogel presents high toughness for the existence of covalent and non-covalent interaction in the hydrogel networks. The hydrogel also possesses good cell affinity and high antibacterial activity due to the catechol groups and bactericidal ability of Ag-Lignin NPs. This study proposes a strategy to design tough and adhesive hydrogels based on dynamic plant catechol chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 835, "Times Cited, All Databases": 867, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1487, "DOI": "10.1038/s41467-019-09351-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09351-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462985600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, QL; Sun, JL; Liu, HT; Bao, RR; Yu, RM; Zhai, JY; Pan, CF; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Qilin; Sun, Junlu; Liu, Haitao; Bao, Rongrong; Yu, Ruomeng; Zhai, Junyi; Pan, Caofeng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-inspired highly stretchable and conformable matrix networks for multifunctional sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanosensation electronics (or Electronic skin, e-skin) consists of mechanically flexible and stretchable sensor networks that can detect and quantify various stimuli to mimic the human somatosensory system, with the sensations of touch, heat/cold, and pain in skin through various sensory receptors and neural pathways. Here we present a skin-inspired highly stretchable and conformable matrix network (SCMN) that successfully expands the e-skin sensing functionality including but not limited to temperature, in-plane strain, humidity, light, magnetic field, pressure, and proximity. The actualized specific expandable sensor units integrated on a structured polyimide network, potentially in three-dimensional (3D) integration scheme, can also fulfill simultaneous multi-stimulus sensing and achieve an adjustable sensing range and large-area expandability. We further construct a personalized intelligent prosthesis and demonstrate its use in real-time spatial pressure mapping and temperature estimation. Looking forward, this SCMN has broader applications in humanoid robotics, new prosthetics, human-machine interfaces, and health-monitoring technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1204, "Times Cited, All Databases": 1273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 244, "DOI": "10.1038/s41467-017-02685-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02685-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422649500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, SE; Deng, ZP; Li, MX; Jiang, BJ; Tian, CG; Pan, QJ; Fu, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Shien; Deng, Zhaopeng; Li, Mingxia; Jiang, Baojiang; Tian, Chungui; Pan, Qingjiang; Fu, Honggang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorus-Doped Carbon Nitride Tubes with a Layered Micro-nullostructure for Enhanced Visible-Light Photocatalytic Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorus-doped hexagonal tubular carbon nitride (P-TCN) with the layered stacking structure was obtained from a hexagonal rod-like single crystal supramolecular precursor (monoclinic, C2/m). The production process of P-TCN involves two steps: 1) the precursor was prepared by self-assembly of melamine with cyanuric acid from in situ hydrolysis of melamine under phosphorous acid-assisted hydrothermal conditions; 2) the pyrolysis was initiated at the center of precursor under heating, thus giving the hexagonal P-TCN. The tubular structure favors the enhancement of light scattering and active sites. Meanwhile, the introduction of phosphorus leads to a narrow band gap and increased electric conductivity. Thus, the P-TCN exhibited a high hydrogen evolution rate of 67 mu mol.h(-1) (0.1 g catalyst, lambda > 420 nm) in the presence of sacrificial agents, and an apparent quantum efficiency of 5.68% at 420 nm, which is better than most of bulk g-C3N4 reported.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1032, "Times Cited, All Databases": 1059, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2016, "Volume": 55, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1830, "End Page": 1834, "Article Number": null, "DOI": "10.1002/anie.201508505", "DOI Link": "http://dx.doi.org/10.1002/anie.201508505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854000043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geng, SK; Zheng, Y; Li, SQ; Su, H; Zhao, X; Hu, J; Shu, HB; Jaroniec, M; Chen, P; Liu, QH; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geng, Shi-Kui; Zheng, Yao; Li, Shan-Qing; Su, Hui; Zhao, Xu; Hu, Jun; Shu, Hai-Bo; Jaroniec, Mietek; Chen, Ping; Liu, Qing-Hua; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel ferrocyanide as a high-performance urea oxidation electrocatalyst", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Urea is often present in waste water but can be used in powering fuel cells and as an alternative oxidation substrate to water in an electrolyser. However, an insufficient mechanistic understanding and the lack of efficient catalysts for the urea oxidation reaction have hampered the development of such applications. Here we demonstrate that a nickel ferrocyanide (Ni2Fe(CN)(6)) catalyst supported on Ni foam can drive the urea oxidation reaction with a higher activity and better stability than those of conventional Ni-based catalysts. Our experimental and computational data suggest a urea oxidation reaction pathway different from most other Ni-based catalysts that comprise NiOOH derivatives as the catalytically active compound. Ni2Fe(CN)(6) appears to be able to directly facilitate a two-stage reaction pathway that involves an intermediate ammonia production (on the Ni site) and its decomposition to N-2 (on the Fe site). Owing to the different rate-determining steps with more favourable thermal/kinetic energetics, Ni2Fe(CN)(6) achieves a 100 mA cm(-2) anodic current density at a potential of 1.35 V (equal to an overpotential of 0.98 V). Urea oxidation could be a lower-energy alternative to water oxidation in hydrogen-producing electrolysers, but improved catalysts are required to facilitate the reaction. Geng et al. report nickel ferrocyanide as a promising catalyst and suggest that it operates via a different pathway to that of previous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 904, "End Page": 912, "Article Number": null, "DOI": "10.1038/s41560-021-00899-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00899-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698946300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, K; Wang, YB; Yan, CY; Yao, YG; Chen, YA; Dai, JQ; Lacey, S; Wang, YB; Wan, JY; Li, T; Wang, ZY; Xu, Y; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Kun; Wang, Yibo; Yan, Chaoyi; Yao, Yonggang; Chen, Yanull; Dai, Jiaqi; Lacey, Steven; Wang, Yanbin; Wan, Jiayu; Li, Tian; Wang, Zhengyang; Xu, Yue; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene Oxide-Based Electrode Inks for 3D-Printed Lithium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-component 3D-printed lithium-ion batteries are fabricated by printing grapheneoxide-based composite inks and solid-state gel polymer electrolyte. An entirely 3D-printed full cell features a high electrode mass loading of 18 mg cm(-2), which is normalized to the overall area of the battery. This all-component printing can be extended to the fabrication of multidimensional/multiscale complex-structures of more energy-storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 610, "Times Cited, All Databases": 680, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2016, "Volume": 28, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2587, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201505391", "DOI Link": "http://dx.doi.org/10.1002/adma.201505391", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373292700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halim, J; Kota, S; Lukatskaya, MR; Naguib, M; Zhao, MQ; Moon, EJ; Pitock, J; nullda, J; May, SJ; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R.; Naguib, Michael; Zhao, Meng-Qiang; Moon, Eun Ju; Pitock, Jeremy; nullda, Jagjit; May, Steven J.; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and Characterization of 2D Molybdenum Carbide (MXene)", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large scale synthesis and delamination of 2D Mo2CTx (where T is a surface termination group) has been achieved by selectively etching gallium from the recently discovered nullolaminated, ternary transition metal carbide Mo2Ga2C. Different synthesis and delamination routes result in different flake morphologies. The resistivity of free-standing Mo2CTx films increases by an order of magnitude as the temperature is reduced from 300 to 10 K, suggesting semiconductor-like behavior of this MXene, in contrast to Ti3C2Tx which exhibits metallic behavior. At 10 K, the magnetoresistance is positive. Additionally, changes in electronic transport are observed upon annealing of the films. When 2 mu m thick films are tested as electrodes in supercapacitors, capacitances as high as 700 F cm(-3) in a 1 M sulfuric acid electrolyte and high capacity retention for at least 10,000 cycles at 10 A g(-1) are obtained. Free-standing Mo2CTx films, with approximate to 8 wt% carbon nullotubes, perform well when tested as an electrode material for Li-ions, especially at high rates. At 20 and 131 C cycling rates, stable reversible capacities of 250 and 76 mAh g(-1), respectively, are achieved for over 1000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2016, "Volume": 26, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3118, "End Page": 3127, "Article Number": null, "DOI": "10.1002/adfm.201505328", "DOI Link": "http://dx.doi.org/10.1002/adfm.201505328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377591500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, FN; Wang, H; Jia, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Fengnian; Wang, Han; Jia, Yichen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene and transition metal dichalcogenides (TMDCs) are the two major types of layered materials under intensive investigation. However, the zero-bandgap nature of graphene and the relatively low mobility in TMDCs limit their applications. Here we reintroduce black phosphorus (BP), the most stable allotrope of phosphorus with strong intrinsic in-plane anisotropy, to the layered-material family. For 15-nm-thick BP, we measure a Hall mobility of 1,000 and 600 cm(2)V(-1)s(-1) for holes along the light (x) and heavy (y) effective mass directions at 120 K. BP thin films also exhibit large and anisotropic in-plane optical conductivity from 2 to 5 mu m. Field-effect transistors using 5 nm BP along x direction exhibit an on-off current ratio exceeding 10(5), a field-effect mobility of 205 cm(2)V(-1)s(-1), and good current saturation characteristics all at room temperature. BP shows great potential for thin-film electronics, infrared optoelectronics and novel devices in which anisotropic properties are desirable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3179, "Times Cited, All Databases": 3416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4458, "DOI": "10.1038/ncomms5458", "DOI Link": "http://dx.doi.org/10.1038/ncomms5458", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340623400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Xia, MY; Wu, YZ; Zhang, GH; Gao, JF; Zhang, B; Cao, SY; Zhang, YT; Li, ZW; Fan, ZZ; Wang, C; Zhang, XM; Miller, JT; Sun, LC; Hou, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Xia, Mingyue; Wu, Yunzhen; Zhang, Guanghui; Gao, Junfeng; Zhang, Bo; Cao, Shuyan; Zhang, Yanting; Li, Zhuwei; Fan, Zhaozhong; Wang, Chen; Zhang, Xiaomeng; Miller, Jeffrey T.; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nullosheets (Ru-1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru-1/D-NiFe LDH delivers an ultralow overpotential of 18mV at 10mAcm(-2) for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru-1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O-O coupling at a Ru-O active site for oxygen evolution reaction. The Ru-1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts. Rational design of single atom catalyst is critical for efficient sustainable energy conversion. Single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nullosheets achieve superior HER and OER performance in alkaline media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 577, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4587, "DOI": "10.1038/s41467-021-24828-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24828-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680875400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Buscema, M; Groenendijk, DJ; Blanter, SI; Steele, GA; van der Zant, HSJ; Castellanos-Gomez, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Buscema, Michele; Groenendijk, Dirk J.; Blanter, Sofya I.; Steele, Gary A.; van der Zant, Herre S. J.; Castellanos-Gomez, Andres", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and Broadband Photoresponse of Few-Layer Black Phosphorus Field-Effect Transistors", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer black phosphorus, a new elemental two-dimensional (2D) material recently isolated by mechanical exfoliation, is a high-mobility layered semiconductor with a direct bandgap that is predicted to strongly depend on the number of layers, from 0.35 eV (bulk) to 2.0 eV (single layer). Therefore, black phosphorus is an appealing candidate for tunable photodetection from the visible to the infrared part of the spectrum. We study the photoresponse of field-effect transistors (FETs) made of few-layer black phosphorus (3-8 nm thick), as a function of excitation wavelength, power, and frequency. In the dark state, the black phosphorus FETs can be tuned both in hole and electron doping regimes allowing for ambipolar operation. We measure mobilities in the order of 100 cm(2)/V s and a current ON/OFF ratio larger than 10(3). Upon illumination, the black phosphorus transistors show a response to excitation wavelengths from the visible region up to 940 nm and a rise time of about 1 ms, demonstrating broadband and fast detection. The responsivity reaches 4.8 mA/W, and it could be drastically enhanced by engineering a detector based on a PN junction. The ambipolar behavior coupled to the fast and broadband photodetection make few-layer black phosphorus a promising 2D material for photodetection across the visible and near-infrared part of the electromagnetic spectrum.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1521, "Times Cited, All Databases": 1638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3347, "End Page": 3352, "Article Number": null, "DOI": "10.1021/nl5008085", "DOI Link": "http://dx.doi.org/10.1021/nl5008085", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, LB; Gao, HL; Yao, HB; Liu, L; Cölfen, H; Liu, G; Chen, SM; Li, SK; Yan, YX; Liu, YY; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Li-Bo; Gao, Huai-Ling; Yao, Hong-Bin; Liu, Lei; Colfen, Helmut; Liu, Gang; Chen, Si-Ming; Li, Shi-Kuo; Yan, You-Xian; Liu, Yang-Yi; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic nacre by predesigned matrix-directed mineralization", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although biomimetic designs are expected to play a key role in exploring future structural materials, facile fabrication of bulk biomimetic materials under ambient conditions remains a major challenge. Here, we describe a mesoscale assembly-and-mineralization approach inspired by the natural process in mollusks to fabricate bulk synthetic nacre that highly resembles both the chemical composition and the hierarchical structure of natural nacre. The millimeter-thick synthetic nacre consists of alternating organic layers and aragonite platelet layers (91 weight percent) and exhibits good ultimate strength and fracture toughness. This predesigned matrix-directed mineralization method represents a rational strategy for the preparation of robust composite materials with hierarchically ordered structures, where various constituents are adaptable, including brittle and heat-labile materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 789, "Times Cited, All Databases": 833, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2016, "Volume": 354, "Issue": 6308, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 107, "End Page": 110, "Article Number": null, "DOI": "10.1126/science.aaf8991", "DOI Link": "http://dx.doi.org/10.1126/science.aaf8991", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387777900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YH; Hwang, S; Cullen, DA; Uddin, MA; Langhorst, L; Li, BY; Karakalos, S; Kropf, AJ; Wegener, EC; Sokolowski, J; Chen, MJ; Myers, D; Su, D; More, KL; Wang, GF; Litster, S; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yanghua; Hwang, Sooyeon; Cullen, David A.; Uddin, M. Aman; Langhorst, Lisa; Li, Boyang; Karakalos, Stavros; Kropf, A. Jeremy; Wegener, Evan C.; Sokolowski, Joshua; Chen, Mengjie; Myers, Debbie; Su, Dong; More, Karren L.; Wang, Guofeng; Litster, Shawn; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active atomically dispersed CoN4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of platinum group metal (PGM)-free catalysts for oxygen reduction reaction (ORR) is essential for affordable proton exchange membrane fuel cells. Herein, a new type of atomically dispersed Co doped carbon catalyst with a core-shell structure has been developed via a surfactant-assisted metal-organic framework approach. The cohesive interactions between the selected surfactant and the Co-doped zeolitic imidazolate framework (ZIF-8) nullocrystals lead to a unique confinement effect. During the thermal activation, this confinement effect suppressed the agglomeration of Co atomic sites and mitigated the collapse of internal microporous structures of ZIF-8. Among the studied surfactants, Pluronic F127 block copolymer led to the greatest performance gains with a doubling of the active site density relative to that of the surfactant-free catalyst. According to density functional theory calculations, unlike other Co catalysts, this new atomically dispersed Co-N-C@F127 catalyst is believed to contain substantial CoN2+2 sites, which are active and thermodynamically favorable for the four-electron ORR pathway. The Co-N-C@F127 catalyst exhibits an unprecedented ORR activity with a half-wave potential (E-1/2) of 0.84 V (vs. RHE) as well as enhanced stability in the corrosive acidic media. It also demonstrated high initial performance with a power density of 0.87 W cm(-2) along with encouraging durability in H-2-O-2 fuel cells. The atomically dispersed Co site catalyst approaches that of the Fe-N-C catalyst and represents the highest reported PGM-free and Fe-free catalyst performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 789, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 260, "Article Number": null, "DOI": "10.1039/c8ee02694g", "DOI Link": "http://dx.doi.org/10.1039/c8ee02694g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457194500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, H; Yang, X; Cranston, ED; Zhu, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, He; Yang, Xuan; Cranston, Emily D.; Zhu, Shiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and Porous nullocellulose Aerogels with High Loadings of Metal-Organic-Framework Particles for Separations Applications", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible and porous aerogels are obtained by combining functional metal-organic frameworks (MOFs) and structural cellulose nullocrystals via a straightforward water-based sol-gel process, followed by freeze-drying. The aerogels have a hierarchical porous structure with controllable MOF loading up to 50 wt%. These hybrid materials can be used as absorbents for water purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2016, "Volume": 28, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7652, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201601351", "DOI Link": "http://dx.doi.org/10.1002/adma.201601351", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384680400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XL; Demir, NK; Wu, ZT; Li, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xinlei; Demir, Nilay Keser; Wu, Zhentao; Li, Kang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Water-Stable Zirconium Metal Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, continuous zirconium(IV) based metal-organic framework (Zr-MOF) membranes were prepared. The pure-phase Zr-MOF (i.e.,, UiO-66) polycrystalline membranes were fabricated on alumina hollow fibers using an in situ solvothermal synthesis method. Single-gas permeation and ion rejection tests were carried out to confirm membrane integrity and functionality. The membrane exhibited excellent multivalent ion rejection (e.g., 86.3% for Ca2+, 98.0% for Mg2+, and 99.3% for Al3+) on the basis of size exclusion With moderate permeance (0.14 L m(-2) h(-1) bar(-1)) and good permeability (0.28 L m(-2) h(-1) bar(-1) mu m). Benefiting from the exceptional chemical stability Of the UiO-66 material, no degradation of membrane performance was observed for various tests up to 170 h toward a wide range of saline solutions. The high separation performance combined with its outstanding water stability suggests the developed UiO-66 membrane as a promising candidate for water desalination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 638, "Times Cited, All Databases": 695, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2015, "Volume": 137, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6999, "End Page": 7002, "Article Number": null, "DOI": "10.1021/jacs.5b02276", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b02276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356322300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZY; Karamad, M; Yong, X; Huang, QZ; Cullen, DA; Zhu, P; Xia, CA; Xiao, QF; Shakouri, M; Chen, FY; Kim, JY; Xia, Y; Heck, K; Hu, YF; Wong, MS; Li, QL; Gates, I; Siahrostami, S; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhen-Yu; Karamad, Mohammadreza; Yong, Xue; Huang, Qizheng; Cullen, David A.; Zhu, Peng; Xia, Chuan; Xiao, Qunfeng; Shakouri, Mohsen; Chen, Feng-Yang; (Timothy) Kim, Jung Yoon; Xia, Yang; Heck, Kimberly; Hu, Yongfeng; Wong, Michael S.; Li, Qilin; Gates, Ian; Siahrostami, Samira; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemically converting nitrate, a widespread water pollutant, back to valuable ammonia is a green and delocalized route for ammonia synthesis, and can be an appealing and supplementary alternative to the Haber-Bosch process. However, as there are other nitrate reduction pathways present, selectively guiding the reaction pathway towards ammonia is currently challenged by the lack of efficient catalysts. Here we report a selective and active nitrate reduction to ammonia on Fe single atom catalyst, with a maximal ammonia Faradaic efficiency of similar to 75% and a yield rate of up to similar to 20,000 mu gh(-1) mg(cat.)(-1) (0.46mmolh(-1) cm(-2)). Our Fe single atom catalyst can effectively prevent the N-N coupling step required for N-2 due to the lack of neighboring metal sites, promoting ammonia product selectivity. Density functional theory calculations reveal the reaction mechanisms and the potential limiting steps for nitrate reduction on atomically dispersed Fe sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 998, "Times Cited, All Databases": 1023, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2870, "DOI": "10.1038/s41467-021-23115-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23115-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658736000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, F; Zhang, LL; Dai, X; Wang, XY; Niu, ZQ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Fang; Zhang, Linlin; Dai, Xi; Wang, Xinyu; Niu, Zhiqiang; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries are promising energy storage devices due to their high safety and low cost. However, they remain in their infancy because of the limited choice of positive electrodes with high capacity and satisfactory cycling performance. Furthermore, their energy storage mechanisms are not well established yet. Here we report a highly reversible zinc/sodium vanadate system, where sodium vanadate hydrate nullobelts serve as positive electrode and zinc sulfate aqueous solution with sodium sulfate additive is used as electrolyte. Different from conventional energy release/storage in zinc-ion batteries with only zinc-ion insertion/extraction, zinc/sodium vanadate hydrate batteries possess a simultaneous proton, and zinc-ion insertion/extraction process that is mainly responsible for their excellent performance, such as a high reversible capacity of 380 mAh g(-1) and capacity retention of 82% over 1000 cycles. Moreover, the quasi-solid-state zinc/sodium vanadate hydrate battery is also a good candidate for flexible energy storage device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1393, "Times Cited, All Databases": 1458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1656, "DOI": "10.1038/s41467-018-04060-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04060-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430798100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tee, SY; Win, KY; Teo, WS; Koh, LD; Liu, SH; Teng, CP; Han, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tee, Si Yin; Win, Khin Yin; Teo, Wee Siang; Koh, Leng-Duei; Liu, Shuhua; Teng, Choon Peng; Han, Ming-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Progress in Energy-Driven Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen is readily obtained from renewable and non-renewable resources via water splitting by using thermal, electrical, photonic and biochemical energy. The major hydrogen production is generated from thermal energy through steam reforming/gasification of fossil fuel. As the commonly used non-renewable resources will be depleted in the long run, there is great demand to utilize renewable energy resources for hydrogen production. Most of the renewable resources may be used to produce electricity for driving water splitting while challenges remain to improve cost-effectiveness. As the most abundant energy resource, the direct conversion of solar energy to hydrogen is considered the most sustainable energy production method without causing pollutions to the environment. In overall, this review briefly summarizes thermolytic, electrolytic, photolytic and biolytic water splitting. It highlights photonic and electrical driven water splitting together with photovoltaic-integrated solar-driven water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 795, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600337, "DOI": "10.1002/advs.201600337", "DOI Link": "http://dx.doi.org/10.1002/advs.201600337", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402740300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, F; Meng, AY; Cheng, B; Ho, WK; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Fei; Meng, Aiyun; Cheng, Bei; Ho, Wingkei; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic H2-production activity of WO3/TiO2 step-scheme heterojunction by graphene modification", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sunlight-driven photocatalytic water-splitting for hydrogen (H-2) evolution is a desirable strategy to utilize solar energy. However, this strategy is restricted by insufficient light harvesting and high photogenerated electron-hole recombination rates of TiO2-based photocatalysts. Here, a graphene-modified WO3/TiO2 step-scheme heterojunction (S-scheme heterojunction) composite photocatalyst was fabricated by a facile one-step hydrothermal method. In the ternary composite, TiO2 and WO3 nulloparticles adhered closely to reduced graphene oxide (rGO) and formed a novel S-scheme heterojunction. Moreover, rGO in the composite not only supplied abundant adsorption and catalytically active sites as an ideal support but also promoted electron separation and transfer from the conduction band of TiO2 by forming a Schottky junction between TiO2 and rGO. The positive cooperative effect of the S-scheme heterojunction formed between WO3 and TiO2 and the Schottky heterojunction formed between TiO2 and graphene sheets suppressed the recombination of relatively useful electrons and holes. This effect also enhanced the light harvesting and promoted the reduction reaction at the active sites. Thus, the novel ternary WO3/TiO2/rGO composite demonstrated a remarkably enhanced photocatalytic H-2 evolution rate of 245.8 Fmol g(-1) h(-1), which was approximately 3.5-fold that of pure TiO2. This work not only presents a low-cost graphene-based S-scheme heterojunction photocatalyst that was obtained via a feasible one-step hydrothermal approach to realize highly efficient H-2 generation without using noble metals, but also provides new insights into the design of novel heterojunction photocatalysts. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 9, "End Page": 20, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63382-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63382-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495145800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Lin, DC; Yuen, PY; Liu, K; Xie, J; Dauskardt, RH; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan; Liu, Kai; Xie, Jin; Dauskardt, Reinhold H.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nulloparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 838, "Times Cited, All Databases": 912, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2017, "Volume": 29, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605531, "DOI": "10.1002/adma.201605531", "DOI Link": "http://dx.doi.org/10.1002/adma.201605531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396166800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Guo, BL; Wu, H; Liang, YP; Ma, PX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin; Guo, Baolin; Wu, Hao; Liang, Yongping; Ma, Peter X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Injectable antibacterial conductive nullocomposite cryogels with rapid shape recovery for noncompressible hemorrhage and wound healing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing injectable antibacterial and conductive shape memory hemostatic with high blood absorption and fast recovery for irregularly shaped and noncompressible hemorrhage remains a challenge. Here we report injectable antibacterial conductive cryogels based on carbon nullotube (CNT) and glycidyl methacrylate functionalized quaternized chitosan for lethal noncompressible hemorrhage hemostasis and wound healing. These cryogels present robust mechanical strength, rapid blood-triggered shape recovery and absorption speed, and high blood uptake capacity. Moreover, cryogels show better blood-clotting ability, higher blood cell and platelet adhesion and activation than gelatin sponge and gauze. Cryogel with 4mg/mL CNT (QCSG/CNT4) shows better hemostatic capability than gauze and gelatin hemostatic sponge in mouse-liver injury model and mouse-tail amputation model, and better wound healing performance than Tegaderm (TM) film. Importantly, QCSG/CNT4 presents excellent hemostatic performance in rabbit liver defect lethal noncompressible hemorrhage model and even better hemostatic ability than Combat Gauze in standardized circular liver bleeding model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 980, "Times Cited, All Databases": 1015, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2784, "DOI": "10.1038/s41467-018-04998-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04998-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438857400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, N; Cheng, FY; Liu, JX; Wang, LB; Long, XH; Liu, XS; Li, FJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ning; Cheng, Fangyi; Liu, Junxiang; Wang, Liubin; Long, Xinghui; Liu, Xiaosong; Li, Fujun; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although alkaline zinc-manganese dioxide batteries have dominated the primary battery applications, it is challenging to make them rechargeable. Here we report a high-performance rechargeable zinc-manganese dioxide system with an aqueous mild-acidic zinc triflate electrolyte. We demonstrate that the tunnel structured manganese dioxide polymorphs undergo a phase transition to layered zinc-buserite on first discharging, thus allowing subsequent intercalation of zinc cations in the latter structure. Based on this electrode mechanism, we formulate an aqueous zinc/manganese triflate electrolyte that enables the formation of a protective porous manganese oxide layer. The cathode exhibits a high reversible capacity of 225 mAh g(-1) and long-term cyclability with 94% capacity retention over 2000 cycles. Remarkably, the pouch zinc-manganese dioxide battery delivers a total energy density of 75.2 Wh kg(-1). As a result of the superior battery performance, the high safety of aqueous electrolyte, the facile cell assembly and the cost benefit of the source materials, this zinc-manganese dioxide system is believed to be promising for large-scale energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1138, "Times Cited, All Databases": 1170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 405, "DOI": "10.1038/s41467-017-00467-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00467-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408820700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koh, A; Kang, D; Xue, Y; Lee, S; Pielak, RM; Kim, J; Hwang, T; Min, S; Banks, A; Bastien, P; Manco, MC; Wang, L; Ammann, KR; Jang, KI; Won, P; Han, S; Ghaffari, R; Paik, U; Slepian, MJ; Balooch, G; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koh, Ahyeon; Kang, Daeshik; Xue, Yeguang; Lee, Seungmin; Pielak, Rafal M.; Kim, Jeonghyun; Hwang, Taehwan; Min, Seunghwan; Banks, Anthony; Bastien, Philippe; Manco, Megan C.; Wang, Liang; Ammann, Kaitlyn R.; Jang, Kyung-In; Won, Phillip; Han, Seungyong; Ghaffari, Roozbeh; Paik, Ungyu; Slepian, Marvin J.; Balooch, Guive; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A soft, wearable microfluidic device for the capture, storage, and colorimetric sensing of sweat", "Source Title": "SCIENCE TRANSLATIONAL MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Capabilities in health monitoring enabled by capture and quantitative chemical analysis of sweat could complement, or potentially obviate the need for, approaches based on sporadic assessment of blood samples. Established sweat monitoring technologies use simple fabric swatches and are limited to basic analysis in controlled laboratory or hospital settings. We present a collection of materials and device designs for soft, flexible, and stretchable microfluidic systems, including embodiments that integrate wireless communication electronics, which can intimately and robustly bond to the surface of the skin without chemical and mechanical irritation. This integration defines access points for a small set of sweat glands such that perspiration spontaneously initiates routing of sweat through a microfluidic network and set of reservoirs. Embedded chemical analyses respond in colorimetric fashion to markers such as chloride and hydronium ions, glucose, and lactate. Wireless interfaces to digital image capture hardware serve as a means for quantitation. Human studies demonstrated the functionality of this microfluidic device during fitness cycling in a controlled environment and during long-distance bicycle racing in arid, outdoor conditions. The results include quantitative values for sweat rate, total sweat loss, pH, and concentration of chloride and lactate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1001, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2016, "Volume": 8, "Issue": 366, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "366ra165", "DOI": "10.1126/scitranslmed.aaf2593", "DOI Link": "http://dx.doi.org/10.1126/scitranslmed.aaf2593", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389449400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Si, Y; Yu, JY; Tang, XM; Ge, JL; Ding, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Si, Yang; Yu, Jianyong; Tang, Xiaomin; Ge, Jianlong; Ding, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight nullofibre-assembled cellular aerogels with superelasticity and multifunctionality", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional nullofibrous aerogels (NFAs) that are both highly compressible and resilient would have broad technological implications for areas ranging from electrical devices and bioengineering to damping materials; however, creating such NFAs has proven extremely challenging. Here we report a novel strategy to create fibrous, isotropically bonded elastic reconstructed (FIBER) NFAs with a hierarchical cellular structure and superelasticity by combining electrospun nullofibres and the fibrous freeze-shaping technique. Our approach causes the intrinsically lamellar deposited electrospun nullofibres to assemble into elastic bulk aerogels with tunable densities and desirable shapes on a large scale. The resulting FIBER NFAs exhibit densities of >0.12 mg cm(-3), rapid recovery from deformation, efficient energy absorption and multifunctionality in terms of the combination of thermal insulation, sound absorption, emulsion separation and elasticity-responsive electric conduction. The successful synthesis of such fascinating materials may provide new insights into the design and development of multifunctional NFAs for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 956, "Times Cited, All Databases": 1000, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5802, "DOI": "10.1038/ncomms6802", "DOI Link": "http://dx.doi.org/10.1038/ncomms6802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347613700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Han, TYJ; Duoss, EB; Golobic, AM; Kuntz, JD; Spadaccini, CM; Worsley, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.; Golobic, Alexandra M.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly compressible 3D periodic graphene aerogel microlattices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young's moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 940, "Times Cited, All Databases": 1021, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6962, "DOI": "10.1038/ncomms7962", "DOI Link": "http://dx.doi.org/10.1038/ncomms7962", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LJ; Su, ZX; Jiang, FL; Yang, LL; Qian, JJ; Zhou, YF; Li, WM; Hong, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linjie; Su, Zixue; Jiang, Feilong; Yang, Lingling; Qian, Jinjie; Zhou, Youfu; Li, Wenmu; Hong, Maochun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly graphitized nitrogen-doped porous carbon nullopolyhedra derived from ZIF-8 nullocrystals as efficient electrocatalysts for oxygen reduction reactions", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped graphitic porous carbons (NGPCs) have been synthesized by using a zeolite-type nulloscale metal-organic framework (NMOF) as a self-sacrificing template, which simultaneously acts as both the carbon and nitrogen sources in a facile carbonization process. The NGPCs not only retain the nullopolyhedral morphology of the parent NMOF, but also possess rich nitrogen, high surface area and hierarchical porosity with well-conducting networks. The promising potential of NGPCs as metal-free electrocatalysts for oxygen reduction reactions (ORR) in fuel cells is demonstrated. Compared with commercial Pt/C, the optimized NGPC-1000-10 (carbonized at 1000 degrees C for 10 h) catalyst exhibits comparable electrocatalytic activity via an efficient four-electron-dominullt ORR process coupled with superior methanol tolerance as well as cycling stability in alkaline media. Furthermore, the controlled experiments reveal that the optimum activity of NGPC-1000-10 can be attributed to the synergetic contributions of the abundant active sites with high graphitic-N portion, high surface area and porosity, and the high degree of graphitization. Our findings suggest that solely MOF-derived heteroatom-doped carbon materials can be a promising alternative for Pt-based catalysts in fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 725, "Times Cited, All Databases": 759, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6590, "End Page": 6602, "Article Number": null, "DOI": "10.1039/c4nr00348a", "DOI Link": "http://dx.doi.org/10.1039/c4nr00348a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337143900045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, RY; Zhang, LB; Shi, L; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Renyuan; Zhang, Lianbin; Shi, Le; Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene Ti3C2: An Effective 2D Light-to-Heat Conversion Material", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene, a new series of 2D material, has been steadily advancing its applications to a variety of fields, such as catalysis, supercapacitor, molecular separation, electromagnetic wave interference shielding. This work reports a carefully designed aqueous droplet light heating system along with a thorough mathematical procedure, which combined leads to a precise determination of internal light-to-heat conversion efficiency of a variety of nullomaterials. The internal light-to-heat conversion efficiency of MXene, more specifically Ti3C2, was measured to be 100%, indicating a perfect energy conversion. Furthermore, a self-floating MXene thin membrane was prepared by simple vacuum filtration and the membrane, in the presence of a rationally chosen heat barrier, produced a light-to-water evaporation efficiency of 84% under one sun irradiation, which is among the state of art energy efficiency for similar photothermal evaporation system. The outstanding internal light-to-heat conversion efficiency and great light-to-water evaporation efficiency reported in this work suggest that MXene is a very promising light-to-heat conversion material and thus deserves more research attention toward practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1392, "Times Cited, All Databases": 1451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3752, "End Page": 3759, "Article Number": null, "DOI": "10.1021/acsnullo.6b08415", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b08415", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400233200033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Wang, SH; Wang, GJN; Zhu, CX; Luo, SC; Jin, LH; Gu, XD; Chen, SC; Feig, VR; To, JWF; Rondeau-Gagne, S; Park, J; Schroeder, BC; Lu, C; Oh, JY; Wang, YM; Kim, YH; Yan, H; Sinclair, R; Zhou, DS; Xue, G; Murmann, B; Linder, C; Cai, W; Tok, JBH; Chung, JW; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jie; Wang, Sihong; Wang, Ging-Ji Nathan; Zhu, Chenxin; Luo, Shaochuan; Jin, Lihua; Gu, Xiaodan; Chen, Shucheng; Feig, Vivian R.; To, John W. F.; Rondeau-Gagne, Simon; Park, Joonsuk; Schroeder, Bob C.; Lu, Chien; Oh, Jin Young; Wang, Yanming; Kim, Yun-Hi; Yan, He; Sinclair, Robert; Zhou, Dongshan; Xue, Gi; Murmann, Boris; Linder, Christian; Cai, Wei; Tok, Jeffery B. -H.; Chung, Jong Won; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stretchable polymer semiconductor films through the nulloconfinement effect", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft and conformable wearable electronics require stretchable semiconductors, but existing ones typically sacrifice charge transport mobility to achieve stretchability. We explore a concept based on the nulloconfinement of polymers to substantially improve the stretchability of polymer semiconductors, without affecting charge transport mobility. The increased polymer chain dynamics under nulloconfinement significantly reduces the modulus of the conjugated polymer and largely delays the onset of crack formation under strain. As a result, our fabricated semiconducting film can be stretched up to 100% strain without affecting mobility, retaining values comparable to that of amorphous silicon. The fully stretchable transistors exhibit high biaxial stretchability with minimal change in on current even when poked with a sharp object. We demonstrate a skinlike finger-wearable driver for a light-emitting diode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1070, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2017, "Volume": 355, "Issue": 6320, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aah4496", "DOI Link": "http://dx.doi.org/10.1126/science.aah4496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391739900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, KM; Kim, D; Rungtaweevoranit, B; Trickett, CA; Barmanbek, JTD; Alshammari, AS; Yang, PD; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat; Trickett, Christopher A.; Barmanbek, Jesika Trese Deniz; Alshammari, Ahmad S.; Yang, Peidong; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmon-Enhanced PhotoCatalytic CO2 Conversion within Metal Organic Frameworks under Visible Light", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials development for artificial photosynthesis, in particular, CO2 reduction, has been under extensive efforts, ranging from inorganic semiconductors to molecular complexes. In this report, we demonstrate a metal organic framework (MOF)-coated nulloparticle photocatalyst with enhanced CO2 reduction activity and stability, which stems from having two different functional units for activity enhancement and catalytic stability combined together as a single construct. Covalently attaching a CO2-to-CO conversion photocatalyst Re-I(CO)(3)(BPYDC)Cl, BPYDC = 2,2'-bipyridine-5,5'-dicarboxylate, to a zirconium MOF, UiO-67 (Re-n-MOF), prevents dimerization leading to deactivation. By systematically controlling its density in the framework (n = 0, 1, 2, 3, 5, 11, 16, and 24 complexes per unit cell), the highest photocatalytic activity was found for Re-3-MOF. Structural analysis of Re-MOFs suggests that a fine balance of proximity between photoactive centers is needed for cooperatively enhanced photocatalytic activity, where an optimum number of Re complexes per unit cell should reach the highest activity. Based on the structure-activity correlation of Ren-M0Fs, Rea-MOF was coated onto Ag nullocubes (AgCRe3-MOF), which spatially confined photoactive Re centers to the intensified near-surface electric fields at the surface of Ag nullocubes, resulting in a 7-fold enhancement of CO2-to-CO conversion under visible light with long-term stability maintained up to 48 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 554, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2017, "Volume": 139, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 356, "End Page": 362, "Article Number": null, "DOI": "10.1021/jacs.6b11027", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b11027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392036900054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Wang, GH; Cheng, B; Yu, JG; Fan, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Juan; Wang, Guohong; Cheng, Bei; Yu, Jiaguo; Fan, Jiajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for Congo Red photodegradation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing step-scheme (S-scheme) heterojunctions has been confirmed as a promising strategy for enhancing the photocatalytic activity of composite materials. In this work, a series of sulfur-doped g-C3N4 (SCN)/TiO2 S-scheme photocatalysts were synthesized using electrospinning and calcination methods. The as-prepared SCN/TiO2 composites showed superior photocatalytic performance than pure TiO2 and SCN in the photocatalytic degradation of Congo Red (CR) aqueous solution. The significant enhancement in photocatalytic activity benefited not only from the 1D well-distributed nullostructure, but also from the S-scheme heterojunction. Furthermore, the XPS analyses and DFT calculations demonstrated that electrons were transferred from SCN to TiO2 across the interface of the SCN/TiO2 composites. The built-in electric field, band edge bending, and Coulomb interaction synergistically facilitated the recombination of relatively useless electrons and holes in hybrid when the interface was irradiated by simulated solar light. Therefore, the remaining electrons and holes with higher reducibility and oxidizability endowed the composite with supreme redox ability. These results were adequately verified by radical trapping experiments, ESR tests, and in situ XPS analyses, suggesting that the electron immigration in the photocatalyst followed the S-scheme heterojunction mechanism. This work can enrich our knowledge of the design and fabrication of novel S-scheme heterojunction photocatalysts and provide a promising strategy for solving environmental pollution in the future. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 621, "Times Cited, All Databases": 650, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 56, "End Page": 68, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63634-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63634-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JT; Wang, M; Wickramaratne, NP; Jaroniec, M; Dou, SX; Dai, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jiantie; Wang, Min; Wickramaratne, Nilantha P.; Jaroniec, Mietek; Dou, Shixue; Dai, Liming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Sodium Ion Batteries Based on a 3D Anode from Nitrogen-Doped Graphene Foams", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A 3D N-doped graphene foam with a 6.8 at% nitrogen content is prepared by annealing a freeze-dried graphene oxide foam in ammonia. It is used as an anode in sodium ion batteries to deliver a high initial reversible capacity of 852.6 mA h g -1 at 1 C between 0.02 and 3 V with a long-term retention of 69.7% after 150 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 827, "Times Cited, All Databases": 862, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2015, "Volume": 27, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2042, "End Page": 2048, "Article Number": null, "DOI": "10.1002/adma.201405370", "DOI Link": "http://dx.doi.org/10.1002/adma.201405370", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351681300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, EQ; Asada, M; Xu, Q; Dalapati, S; Addicoat, MA; Brady, MA; Xu, H; Nakamura, T; Heine, T; Chen, QH; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Enquan; Asada, Mizue; Xu, Qing; Dalapati, Sasanka; Addicoat, Matthew A.; Brady, Michael A.; Xu, Hong; Nakamura, Toshikazu; Heine, Thomas; Chen, Qiuhong; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional sp2 carbon-conjugated covalent organic frameworks", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We synthesized a two-dimensional (2D) crystalline covalent organic framework (sp(2)c-COF) that was designed to be fully pi-conjugated and constructed from all sp(2) carbons by C=C condensation reactions of tetrakis(4-formylphenyl)pyrene and 1,4-phenylenediacetonitrile. The C=C linkages topologically connect pyrene knots at regular intervals into a 2D lattice with pi conjugations extended along both x and y directions and develop an eclipsed layer framework rather than the more conventionally obtained disordered structures. The sp(2)c-COF is a semiconductor with a discrete band gap of 1.9 electron volts and can be chemically oxidized to enhance conductivity by 12 orders of magnitude. The generated radicals are confined on the pyrene knots, enabling the formation of a paramagnetic carbon structure with high spin density. The sp(2) carbon framework induces ferromagnetic phase transition to develop spin-spin coherence and align spins unidirectionally across the material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 924, "Times Cited, All Databases": 977, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2017, "Volume": 357, "Issue": 6352, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 673, "End Page": 676, "Article Number": null, "DOI": "10.1126/science.aan0202", "DOI Link": "http://dx.doi.org/10.1126/science.aan0202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407793600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grimaud, A; Diaz-Morales, O; Han, BH; Hong, WT; Lee, YL; Giordano, L; Stoerzinger, KA; Koper, MTM; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong; Hong, Wesley T.; Lee, Yueh-Lin; Giordano, Livia; Stoerzinger, Kelsey A.; Koper, Marc T. M.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding how materials that catalyse the oxygen evolution reaction (OER) function is essential for the development of efficient energy-storage technologies. The traditional understanding of the OER mechanism on metal oxides involves four concerted proton-electron transfer steps on metal-ion centres at their surface and product oxygen molecules derived from water. Here, using in situ O-18 isotope labelling mass spectrometry, we provide direct experimental evidence that the O-2 generated during the OER on some highly active oxides can come from lattice oxygen. The oxides capable of lattice-oxygen oxidation also exhibit pH-dependent OER activity on the reversible hydrogen electrode scale, indicating non-concerted proton-electron transfers in the OER mechanism. Based on our experimental data and density functional theory calculations, we discuss mechanisms that are fundamentally different from the conventional scheme and show that increasing the covalency of metal-oxygen bonds is critical to trigger lattice-oxygen oxidation and enable non-concerted proton-electron transfers during OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1718, "Times Cited, All Databases": 1786, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 457, "End Page": 465, "Article Number": null, "DOI": "10.1038/NCHEM.2695", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2695", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399785500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, V; Soklaski, R; Liang, YF; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vy Tran; Soklaski, Ryan; Liang, Yufeng; Yang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the quasiparticle band gap, excitons, and highly anisotropic optical responses of few-layer black phosphorous (phosphorene). It is shown that these materials exhibit unique many-electron effects; the electronic structures are dispersive essentially along one dimension, leading to particularly enhanced self-energy corrections and excitonic effects. Additionally, within a wide energy range, including infrared light and part of visible light, few-layer black phosphorous absorbs light polarized along the structures' armchair direction and is transparent to light polarized along the zigzag direction, making them potentially viable linear polarizers for applications. Finally, the number of phosphorene layers included in the stack controls the material's band gap, optical absorption spectrum, and anisotropic polarization energy window across a wide range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1792, "Times Cited, All Databases": 1959, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2014, "Volume": 89, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235319, "DOI": "10.1103/PhysRevB.89.235319", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.235319", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338282800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, ZG; Dong, QF; Bi, C; Shao, YC; Yuan, YB; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Zhengguo; Dong, Qingfeng; Bi, Cheng; Shao, Yuchuan; Yuan, Yongbo; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent Annealing of Perovskite-Induced Crystal Growth for Photovoltaic-Device Efficiency Enhancement", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1547, "Times Cited, All Databases": 1658, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2014, "Volume": 26, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6503, "End Page": 6509, "Article Number": null, "DOI": "10.1002/adma.201401685", "DOI Link": "http://dx.doi.org/10.1002/adma.201401685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342843600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, W; Zhu, XB; Yu, XH; Zeng, XW; Xiao, QL; Zhang, XD; Ji, XY; Wang, XS; Shi, JJ; Zhang, H; Mei, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Wei; Zhu, Xianbing; Yu, Xinghua; Zeng, Xiaowei; Xiao, Quanlan; Zhang, Xudong; Ji, Xiaoyuan; Wang, Xusheng; Shi, Jinjun; Zhang, Han; Mei, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus nullosheets as a Robust Delivery Platform for Cancer Theranostics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D black phosphorus (BP) nullo-materials are presented as a delivery platform. The endocytosis pathways and biological activities of PEGylated BP nullosheets in cancer cells are revealed for the first time. Finally, a triple-response combined therapy strategy is achieved by PEGylated BP nullosheets, showing a promising and enhanced antitumor effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 759, "Times Cited, All Databases": 797, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1603276, "DOI": "10.1002/adma.201603276", "DOI Link": "http://dx.doi.org/10.1002/adma.201603276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392729000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burke, MS; Kast, MG; Trotochaud, L; Smith, AM; Boettcher, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena; Smith, Adam M.; Boettcher, Shannon W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt-Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt oxides and (oxy)hydroxides have been widely studied as electrocatalysts for the oxygen evolution reaction (OER). For related Ni-based materials, the addition of Fe dramatically enhances OER activity. The role of Fe in Co-based materials is not well-documented. We show that the intrinsic OER activity of Co1-xFex(OOH) is similar to 100-fold higher for x approximate to 0.6-0.7 than for x = 0 on a per-metal turnover frequency basis. Fe-free CoOOH absorbs Fe from electrolyte impurities if the electrolyte is not rigorously purified. Fe incorporation and increased activity correlate with an anodic shift in the nominally Co2+/3+ redox wave, indicating strong electronic interactions between the two elements and likely substitutional doping of Fe for Co. In situ electrical measurements show that Co1-xFex(OOH) is conductive under OER conditions (similar to 0.7-4 mS cm(-1) at similar to 300 mV overpotential), but that FeOOH is an insulator with measurable conductivity (2.2 x 10(-2) mS cm(-1)) only at high overpotentials >400 mV. The apparent OER activity of FeOOH is thus limited by low conductivity. Microbalance measurements show that films with x >= 0.54 (i.e., Fe-rich) dissolve in 1 M KOH electrolyte under OER conditions. For x < 0.54, the films appear chemically stable, but the OER activity decreases by 16-62% over 2 h, likely due to conversion into denser, oxide-like phases. We thus hypothesize that Fe is the most-active site in the catalyst, while CoOOH primarily provides a conductive, high-surface area, chemically stabilizing host. These results are important as Fe-containing Co- and Ni-(oxy)hydroxides are the fastest OER catalysts known.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1655, "Times Cited, All Databases": 1743, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2015, "Volume": 137, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3638, "End Page": 3648, "Article Number": null, "DOI": "10.1021/jacs.5b00281", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b00281", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351420800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, J; Peng, ZW; Liu, YY; Ruiz-Zepeda, F; Ye, RQ; Samuel, ELG; Yacaman, MJ; Yakobson, BI; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Jian; Peng, Zhiwei; Liu, Yuanyue; Ruiz-Zepeda, Francisco; Ye, Ruquan; Samuel, Errol L. G.; Yacaman, Miguel Jose; Yakobson, Boris I.; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Laser-induced porous graphene films from commercial polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The cost effective synthesis and patterning of carbon nullomaterials is a challenge in electronic and energy storage devices. Here we report a one-step, scalable approach for producing and patterning porous graphene films with three-dimensional networks from commercial polymer films using a CO2 infrared laser. The sp(3)-carbon atoms are photothermally converted to sp(2)-carbon atoms by pulsed laser irradiation. The resulting laserinduced graphene (LIG) exhibits high electrical conductivity. The LIG can be readily patterned to interdigitated electrodes for in-plane microsupercapacitors with specific capacitances of >4 mFcm(-2) and power densities of similar to 9 mWcm(-2). Theoretical calculations partially suggest that enhanced capacitance may result from LIG's unusual ultra-polycrystalline lattice of pentagon-heptagon structures. Combined with the advantage of one-step processing of LIG in air from commercial polymer sheets, which would allow the employment of a roll-to-roll manufacturing process, this technique provides a rapid route to polymer-written electronic and energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1617, "Times Cited, All Databases": 1770, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/ncomms6714", "DOI Link": "http://dx.doi.org/10.1038/ncomms6714", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347229300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XY; Lee, H; Weisgraber, TH; Shusteff, M; DeOtte, J; Duoss, EB; Kuntz, JD; Biener, MM; Ge, Q; Jackson, JA; Kucheyev, SO; Fang, NX; Spadaccini, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaoyu; Lee, Howon; Weisgraber, Todd H.; Shusteff, Maxim; DeOtte, Joshua; Duoss, Eric B.; Kuntz, Joshua D.; Biener, Monika M.; Ge, Qi; Jackson, Julie A.; Kucheyev, Sergei O.; Fang, Nicholas X.; Spadaccini, Christopher M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight, Ultrastiff Mechanical Metamaterials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mechanical properties of ordinary materials degrade substantially with reduced density because their structural elements bend under applied load. We report a class of microarchitected materials that maintain a nearly constant stiffness per unit mass density, even at ultralow density. This performance derives from a network of nearly isotropic microscale unit cells with high structural connectivity and nulloscale features, whose structural members are designed to carry loads in tension or compression. Production of these microlattices, with polymers, metals, or ceramics as constituent materials, is made possible by projection microstereolithography (an additive micromanufacturing technique) combined with nulloscale coating and postprocessing. We found that these materials exhibit ultrastiff properties across more than three orders of magnitude in density, regardless of the constituent material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1751, "Times Cited, All Databases": 2007, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2014, "Volume": 344, "Issue": 6190, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1373, "End Page": 1377, "Article Number": null, "DOI": "10.1126/science.1252291", "DOI Link": "http://dx.doi.org/10.1126/science.1252291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337531700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kovalenko, MV; Manna, L; Cabot, A; Hens, Z; Talapin, DV; Kagan, CR; Klimov, VI; Rogach, AL; Reiss, P; Milliron, DJ; Guyot-Sionnnest, P; Konstantatos, G; Parak, WJ; Hyeon, T; Korgel, BA; Murray, CB; Heiss, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kovalenko, Maksym V.; Manna, Liberato; Cabot, Andreu; Hens, Zeger; Talapin, Dmitri V.; Kagan, Cherie R.; Klimov, Victor I.; Rogach, Andrey L.; Reiss, Peter; Milliron, Delia J.; Guyot-Sionnnest, Philippe; Konstantatos, Gerasimos; Parak, Wolfgang J.; Hyeon, Taeghwan; Korgel, Brian A.; Murray, Christopher B.; Heiss, Wolfgang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prospects of nulloscience with nullocrystals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal nullocrystals (NCs, i.e., crystalline nulloparticles) have become an important class of materials with great potential for applications ranging from medicine to electronic and optoelectronic devices. Todays strong research focus on NCs has been prompted by the tremendous progress in their synthesis. Impressively narrow size distributions of just a few percent, rational shape-engineering, compositional modulation, electronic doping, and tailored surface chemistries are now feasible for a broad range of inorganic compounds. The performance of inorganic NC-based photovoltaic and light-emitting devices has become competitive to other state-of-the-art materials. Semiconductor NCs hold unique promise for near- and mid-infrared technologies, where very few semiconductor materials are available. On a purely fundamental side, new insights into NC growth, chemical transformations, and self-organization can be gained from rapidly progressing in situ characterization and direct imaging techniques. New phenomena are constantly being discovered in the photophysics of NCs and in the electronic properties of NC solids. In this nullo Focus, we review the state of the art in research on colloidal NCs focusing on the most recent works published in the last 2 years.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1013, "Times Cited, All Databases": 1139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1012, "End Page": 1057, "Article Number": null, "DOI": "10.1021/nn506223h", "DOI Link": "http://dx.doi.org/10.1021/nn506223h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349940500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, RP; Ding, J; Gong, WB; Argyle, MD; Zhong, Q; Wang, YJ; Russell, CK; Xu, ZH; Russell, AG; Li, QH; Fan, MH; Yao, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Run-Ping; Ding, Jie; Gong, Weibo; Argyle, Morris D.; Zhong, Qin; Wang, Yujun; Russell, Christopher K.; Xu, Zhenghe; Russell, Armistead G.; Li, Qiaohong; Fan, Maohong; Yao, Yuan-Gen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO2 hydrogenation to high-value products via heterogeneous catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, carbon dioxide capture and conversion, along with hydrogen from renewable resources, provide an alternative approach to synthesis of useful fuels and chemicals. People are increasingly interested in developing innovative carbon dioxide hydrogenation catalysts, and the pace of progress in this area is accelerating. Accordingly, this perspective presents current state of the art and outlook in synthesis of light olefins, dimethyl ether, liquid fuels, and alcohols through two leading hydrogenation mechanisms: methanol reaction and Fischer-Tropsch based carbon dioxide hydrogenation. The future research directions for developing new heterogeneous catalysts with transformational technologies, including 3D printing and artificial intelligence, are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 747, "Times Cited, All Databases": 787, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 13", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5698, "DOI": "10.1038/s41467-019-13638-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13638-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503207700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, K; Gong, YH; Dai, JQ; Gong, A; Han, XG; Yao, YG; Wang, CW; Wang, YB; Chen, YN; Yan, CY; Li, YJ; Wachsman, ED; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi; Gong, Amy; Han, Xiaogang; Yao, Yonggang; Wang, Chengwei; Wang, Yibo; Chen, Yanull; Yan, Chaoyi; Li, Yiju; Wachsman, Eric D.; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, solid-state, ion-conducting membrane with 3D garnet nullofiber networks for lithium batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Beyond state-of-the-art lithium-ion battery (LIB) technology with metallic lithium anodes to replace conventional ion intercalation anode materials is highly desirable because of lithium's highest specific capacity (3,860 mA/g) and lowest negative electrochemical potential (similar to 3.040 V vs. the standard hydrogen electrode). In this work, we report for the first time, to our knowledge, a 3D lithium-ion-conducting ceramic network based on garnet-type Li6.4La3Zr2Al0.2O12 (LLZO) lithium-ion conductor to provide continuous Li+ transfer channels in a polyethylene oxide (PEO)-based composite. This composite structure further provides structural reinforcement to enhance the mechanical properties of the polymer matrix. The flexible solid-state electrolyte composite membrane exhibited an ionic conductivity of 2.5 x 10(-4) S/cm at room temperature. The membrane can effectively block dendrites in a symmetric Li vertical bar electrolyte vertical bar Li cell during repeated lithium stripping/plating at room temperature, with a current density of 0.2 mA/cm(2) for around 500 h and a current density of 0.5 mA/cm(2) for over 300 h. These results provide an all solid ion-conducting membrane that can be applied to flexible LIBs and other electrochemical energy storage systems, such as lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 801, "Times Cited, All Databases": 906, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2016, "Volume": 113, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7094, "End Page": 7099, "Article Number": null, "DOI": "10.1073/pnas.1600422113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1600422113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379033400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, JC; Lan, MH; Zhou, BJ; Liu, WM; Guo, L; Wang, H; Jia, QY; Niu, GL; Huang, X; Zhou, HY; Meng, XM; Wang, PF; Lee, CS; Zhang, WJ; Han, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Jiechao; Lan, Minhuan; Zhou, Bingjiang; Liu, Weimin; Guo, Liang; Wang, Hui; Jia, Qingyan; Niu, Guangle; Huang, Xing; Zhou, Hangyue; Meng, Xiangmin; Wang, Pengfei; Lee, Chun-Sing; Zhang, Wenjun; Han, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A graphene quantum dot photodynamic therapy agent with high singlet oxygen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Clinical applications of current photodynamic therapy (PDT) agents are often limited by their low singlet oxygen (O-1(2)) quantum yields, as well as by photobleaching and poor biocompatibility. Here we present a new PDT agent based on graphene quantum dots (GQDs) that can produce O-1(2) via a multistate sensitization process, resulting in a quantum yield of similar to 1.3, the highest reported for PDT agents. The GQDs also exhibit a broad absorption band spanning the UV region and the entire visible region and a strong deep-red emission. Through in vitro and in vivo studies, we demonstrate that GQDs can be used as PDT agents, simultaneously allowing imaging and providing a highly efficient cancer therapy. The present work may lead to a new generation of carbon-based nullomaterial PDT agents with overall performance superior to conventional agents in terms of O-1(2) quantum yield, water dispersibility, photo-and pH-stability, and biocompatibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1213, "Times Cited, All Databases": 1259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4596, "DOI": "10.1038/ncomms5596", "DOI Link": "http://dx.doi.org/10.1038/ncomms5596", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341056200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anasori, B; Xie, Y; Beidaghi, M; Lu, J; Hosler, BC; Hultman, L; Kent, PRC; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anasori, Babak; Xie, Yu; Beidaghi, Majid; Lu, Jun; Hosler, Brian C.; Hultman, Lars; Kent, Paul R. C.; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The higher the chemical diversity and structural complexity of two-dimensional (2D) materials, the higher the likelihood they possess unique and useful properties. Herein, density functional theory (DFT) is used to predict the existence of two new families of 2D ordered, carbides (MXenes), M'M-2 '' C-2 and M'M-2 '' C-2(3), where M' and M '' are two different early transition metals. In these solids, M' layers sandwich M carbide layers. By synthesizing Mo2TiC2Tx, Mo2Ti2C3Tx, and Cr2TiC2Tx (where T is a surface termination), we validated the DFT predictions. Since the Mo and Cr atoms are on the outside, they control the 2D flakes' chemical and electrochemical properties. The latter was proven by showing quite different electrochemical behavior of Mo2TiC2Tx and Ti3C2Tx. This work further expands the family of 2D materials, offering additional choices of structures, chemistries, and ultimately useful properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1476, "Times Cited, All Databases": 1593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9507, "End Page": 9516, "Article Number": null, "DOI": "10.1021/acsnullo.5b03591", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b03591", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363915300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YX; Luo, Z; Conrad, NJ; Liu, H; Gong, YJ; Najmaei, S; Ajayan, PM; Lou, J; Xu, XF; Ye, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yexin; Luo, Zhe; Conrad, Nathan J.; Liu, Han; Gong, Yongji; Najmaei, Sina; Ajayan, Pulickel M.; Lou, Jun; Xu, Xianfan; Ye, Peide D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus-Monolayer MoS2 van der Waals Heterojunction p-n Diode", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, a elemental 2D material, which is the monolayer of black phosphorus, has been mechanically exfoliated recently. In its bulk form, black phosphorus shows high carrier mobility (similar to 10000 cm(2)/V.s) and a similar to 0.3 eV direct band gap. Well-behaved p-type field-effect transistors with mobilities of up to 1000 cm(2)/V.s, as well as phototransistors, have been demonstrated on few-layer black phosphorus, showing its promise for electronics and optoelectronics applications due to its high hole mobility and thickness dependent direct band gap. However, p-n junctions, the basic building blocks of modem electronic and optoelectronic devices, have not yet been realized based on black phosphorus. In this paper, we demonstrate a gate-tunable p-n diode based on a p-type black phosphorus/n-type monolayer MoS2 van der Waals p-n heterojunction. Upon illumination, these ultrathin p-n diodes show a maximum photodetection responsivity of 418 mA/W at the wavelength of 633 nm and photovoltaic energy conversion with an external quantum efficiency of 0.3%. These p-n diodes show promise for broad-band photodetection and solar energy harvesting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1131, "Times Cited, All Databases": 1256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8292, "End Page": 8299, "Article Number": null, "DOI": "10.1021/nn5027388", "DOI Link": "http://dx.doi.org/10.1021/nn5027388", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340992300077", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, HB; Xia, BY; Yu, L; Yu, XY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Hao Bin; Xia, Bao Yu; Yu, Le; Yu, Xin-Yao; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous molybdenum carbide nullo-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting has been considered as a promising approach to produce clean and sustainable hydrogen fuel. However, the lack of high-performance and low-cost electrocatalysts for hydrogen evolution reaction hinders the large-scale application. As a new class of porous materials with tunable structure and composition, metal-organic frameworks have been considered as promising candidates to synthesize various functional materials. Here we demonstrate a metal-organic frameworks-assisted strategy for synthesizing nullo-structured transition metal carbides based on the confined carburization in metal-organic frameworks matrix. Starting from a compound consisting of copper-based metal-organic frameworks host and molybdenum-based polyoxometalates guest, mesoporous molybdenum carbide nullo-octahedrons composed of ultrafine nullocrystallites are successfully prepared as a proof of concept, which exhibit remarkable electrocatalytic performance for hydrogen production from both acidic and basic solutions. The present study provides some guidelines for the design and synthesis of nullostructured electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1227, "Times Cited, All Databases": 1270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6512, "DOI": "10.1038/ncomms7512", "DOI Link": "http://dx.doi.org/10.1038/ncomms7512", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Liu, TY; Qian, F; Han, TYJ; Duoss, EB; Kuntz, JD; Spadaccini, CM; Worsley, MA; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cheng; Liu, Tianyu; Qian, Fang; Han, T. Yong-Jin; Duoss, Eric B.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.; Li, Yat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supercapacitors Based on Three-Dimensional Hierarchical Graphene Aerogels with Periodic Macropores", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is an atomically thin, two-dimensional (2D) carbon material that offers a unique combination of low density, exceptional mechanical properties, thermal stability, large surface area, and excellent electrical conductivity. Recent progress has resulted in macro-assemblies of graphene, such as bulk graphene aerogels for a variety of applications. However, these three-dimensional (3D) graphenes exhibit physicochemical property attenuation compared to their 2D building blocks because of one-fold composition and tortuous, stochastic porous networks. These limitations can be offset by developing a graphene composite material with an engineered porous architecture. Here, we report the fabrication of 3D periodic graphene composite aerogel microlattices for supercapacitor applications, via a 3D printing technique known as direct-ink writing. The key factor in developing these novel aerogels is creating an extrudable graphene oxide-based composite ink and modifying the 3D printing method to accommodate aerogel processing. The 3D-printed graphene composite aerogel (3D-GCA) electrodes are lightweight, highly conductive, and exhibit excellent electrochemical properties. In particular, the supercapacitors using these 3D-GCA electrodes with thicknesses on the order of millimeters display exceptional capacitive retention (ca. 90% from 0.5 to 10 A. g(-1)) and power densities (>4 kW.kg(-1)) that equal or exceed those of reported devices made with electrodes 10-100 times thinner. This work provides an example of how 3D-printed materials, such as graphene aerogels, can significantly expand the design space for fabricating high-performance and fully integrable energy storage devices optimized for a broad range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3448, "End Page": 3456, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b04965", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b04965", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377642700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, GL; Gong, YJ; Lin, JH; Li, B; He, YM; Pantelides, ST; Zhou, W; Vajtai, R; Ajayan, PM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Gonglan; Gong, Yongji; Lin, Junhao; Li, Bo; He, Yongmin; Pantelides, Sokrates T.; Zhou, Wu; Vajtai, Robert; Ajayan, Pulickel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MoS2 is a promising and low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. However, the efficiency of hydrogen production is limited by the amount of active sites, for example, edges, in MoS2. Here, we demonstrate that oxygen plasma exposure and hydrogen treatment on pristine monolayer MoS2 could introduce more active sites via the formation of defects within the monolayer, leading to a high density of exposed edges and a significant improvement of the hydrogen evolution activity. These as-fabricated defects are characterized at the scale from macroscopic continuum to discrete atoms. Our work represents a facile method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1073, "Times Cited, All Databases": 1139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1097, "End Page": 1103, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b04331", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b04331", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370215200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, GF; Wang, JX; Qian, K; Chen, JW; Li, SH; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Guofa; Wang, Jiangxin; Qian, Kai; Chen, Jingwei; Li, Shaohui; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely Stretchable Strain Sensors Based on Conductive Self-Healing Dynamic Cross-Links Hydrogels for Human-Motion Detection", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 827, "Times Cited, All Databases": 870, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600190, "DOI": "10.1002/advs.201600190", "DOI Link": "http://dx.doi.org/10.1002/advs.201600190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397020800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nedelcu, G; Protesescu, L; Yakunin, S; Bodnarchuk, MI; Grotevent, MJ; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nedelcu, Georgian; Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.; Grotevent, Matthias J.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast Anion-Exchange in Highly Luminescent nullocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, I)", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Postsynthetic chemical transformations of colloidal nullocrystals, such as ion-exchange reactions, provide an avenue to compositional fine-tuning or to otherwise inaccessible materials and morphologies. While cation-exchange is facile and commonplace, anion-exchange reactions have not received substantial deployment. Here we report fast, low-temperature, deliberately partial, or complete anionexchange in highly luminescent semiconductor nullocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, I). By adjusting the halide ratios in the colloidal nullocrystal solution, the bright photoluminescence can be tuned over the entire visible spectral region (410-700 nm) while maintaining high quantum yields of 20 80% and narrow emission line widths of 10-40 nm (from blue to red). Furthermore, fast internullocrystal anion-exchange is demonstrated, leading to uniform CsPb(Cl/Br)(3) or CsPb(Br/I)(3) compositions simply by mixing CsPbCl3, CsPbBr3, and CsPbI3 nullo crystals in appropriate ratios.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2047, "Times Cited, All Databases": 2199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5635, "End Page": 5640, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b02404", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b02404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359613700119", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CP; Wu, QS; Xie, WQ; Zhang, X; Brozena, A; Zheng, J; Garaga, MN; Ko, BH; Mao, YM; He, SM; Gao, Y; Wang, PB; Tyagi, M; Jiao, F; Briber, R; Albertus, P; Wang, CS; Greenbaum, S; Hu, YY; Isogai, A; Winter, M; Xu, K; Qi, Y; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chunpeng; Wu, Qisheng; Xie, Weiqi; Zhang, Xin; Brozena, Alexandra; Zheng, Jin; Garaga, Mounesha N.; Ko, Byung Hee; Mao, Yimin; He, Shuaiming; Gao, Yue; Wang, Pengbo; Tyagi, Madhusudan; Jiao, Feng; Briber, Robert; Albertus, Paul; Wang, Chunsheng; Greenbaum, Steven; Hu, Yan-Yan; Isogai, Akira; Winter, Martin; Xu, Kang; Qi, Yue; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper-coordinated cellulose ion conductors for solid-state batteries", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By coordinating copper ions with the oxygen-containing groups of cellulose nullofibrils, the molecular spacing in the nullofibrils is increased, allowing fast transport of lithium ions and offering hopes for solid-state batteries. Although solid-state lithium (Li)-metal batteries promise both high energy density and safety, existing solid ion conductors fail to satisfy the rigorous requirements of battery operations. Inorganic ion conductors allow fast ion transport, but their rigid and brittle nature prevents good interfacial contact with electrodes. Conversely, polymer ion conductors that are Li-metal-stable usually provide better interfacial compatibility and mechanical tolerance, but typically suffer from inferior ionic conductivity owing to the coupling of the ion transport with the motion of the polymer chains(1-3). Here we report a general strategy for achieving high-performance solid polymer ion conductors by engineering of molecular channels. Through the coordination of copper ions (Cu2+) with one-dimensional cellulose nullofibrils, we show that the opening of molecular channels within the normally ion-insulating cellulose enables rapid transport of Li+ ions along the polymer chains. In addition to high Li+ conductivity (1.5 x 10(-3) siemens per centimetre at room temperature along the molecular chain direction), the Cu2+-coordinated cellulose ion conductor also exhibits a high transference number (0.78, compared with 0.2-0.5 in other polymers(2)) and a wide window of electrochemical stability (0-4.5 volts) that can accommodate both the Li-metal anode and high-voltage cathodes. This one-dimensional ion conductor also allows ion percolation in thick LiFePO4 solid-state cathodes for application in batteries with a high energy density. Furthermore, we have verified the universality of this molecular-channel engineering approach with other polymers and cations, achieving similarly high conductivities, with implications that could go beyond safe, high-performance solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2021, "Volume": 598, "Issue": 7882, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 590, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03885-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03885-6", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709352200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, SH; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Sheng-Heng; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current Status and Future Prospects of Metal-Sulfur Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries are a major focus of academic and industrial energy-storage research due to their high theoretical energy density and the use of low-cost materials. The high energy density results from the conversion mechanism that lithium-sulfur cells utilize. The sulfur cathode, being naturally abundant and environmentally friendly, makes lithium-sulfur batteries a potential next-generation energy-storage technology. The current state of the research indicates that lithium-sulfur cells are now at the point of transitioning from laboratory-scale devices to a more practical energy-storage application. Based on similar electrochemical conversion reactions, the low-cost sulfur cathode can be coupled with a wide range of metallic anodes, such as sodium, potassium, magnesium, calcium, and aluminum. These new metal-sulfur systems exhibit great potential in either lowering the production cost or producing high energy density. Inspired by the rapid development of lithium-sulfur batteries and the prospect of metal-sulfur cells, here, over 450 research articles are summarized to analyze the research progress and explore the electrochemical characteristics, cell-assembly parameters, cell-testing conditions, and materials design. In addition to highlighting the current research progress, the possible future areas of research which are needed to bring conversion-type lithium-sulfur and other metal-sulfur batteries into the market are also discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 501, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 31, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901125, "DOI": "10.1002/adma.201901125", "DOI Link": "http://dx.doi.org/10.1002/adma.201901125", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477981200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, M; Zhou, W; Tsai, MC; Zhou, JG; Guan, MY; Lin, MC; Zhang, B; Hu, YF; Wang, DY; Yang, J; Pennycook, SJ; Hwang, BJ; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Ming; Zhou, Wu; Tsai, Mon-Che; Zhou, Jigang; Guan, Mingyun; Lin, Meng-Chang; Zhang, Bo; Hu, Yongfeng; Wang, Di-Yan; Yang, Jiang; Pennycook, Stephen J.; Hwang, Bing-Joe; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active, stable and cost-effective electrocatalysts are a key to water splitting for hydrogen production through electrolysis or photoelectrochemistry. Here we report nulloscale nickel oxide/nickel heterostructures formed on carbon nullotube sidewalls as highly effective electrocatalysts for hydrogen evolution reaction with activity similar to platinum. Partially reduced nickel interfaced with nickel oxide results from thermal decomposition of nickel hydroxide precursors bonded to carbon nullotube sidewalls. The metal ion-carbon nullotube interactions impede complete reduction and Ostwald ripening of nickel species into the less hydrogen evolution reaction active pure nickel phase. A water electrolyzer that achieves similar to 20 mA cm(-2) at a voltage of 1.5V, and which may be operated by a single-cell alkaline battery, is fabricated using cheap, non-precious metal-based electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1541, "Times Cited, All Databases": 1620, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4695, "DOI": "10.1038/ncomms5695", "DOI Link": "http://dx.doi.org/10.1038/ncomms5695", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341078500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YQ; Guo, J; Han, G; Bai, YP; Ge, QC; Ma, J; Lau, CH; Shao, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yanqiu; Guo, Jing; Han, Gang; Bai, Yongping; Ge, Qingchun; Ma, Jun; Lau, Cher Hon; Shao, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecularly soldered covalent organic frameworks for ultrafast precision sieving", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The weak interlamellar interaction of covalent organic framework (COF) nullocrystals inhibit the construction of highly efficient ion/molecular sieving membranes owing to the inferior contaminullt selectivity induced by defects in stacked COF membranes and stability issues. Here, a facile in situ molecularly soldered strategy was developed to fabricate defect-free ultrathin COF membranes with precise sieving abilities using the typical chemical environment for COF condensation polymerization and dopamine self-polymerization. The experimental data and density functional theory simulations proved that the reactive oxygen species generated during dopamine polymerization catalyze the nucleophilic reactions of the COF, thus facilitating the counter-diffusion growth of thin COF layers. Notably, dopamine can eliminate the defects in the stacked COF by soldering the COF crystals, fortifying the mechanical properties of the ultrathin COF membranes. The COF membranes exhibited ultrafast precision sieving for molecular separation and ion removal in both aqueous and organic solvents, which surpasses that of state-of-the-art membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe8706", "DOI": "10.1126/sciadv.abe8706", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe8706", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000633443600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, S; Da, PM; Li, C; Wang, ZP; Yuan, ZC; Fu, F; Kawecki, M; Liu, XJ; Sakai, N; Wang, JTW; Huettner, S; Buecheler, S; Fahlman, M; Gao, F; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Sai; Da, Peimei; Li, Cheng; Wang, Zhiping; Yuan, Zhongcheng; Fu, Fan; Kawecki, Maciej; Liu, Xianjie; Sakai, Nobuya; Wang, Jacob Tse-Wei; Huettner, Sven; Buecheler, Stephan; Fahlman, Mats; Gao, Feng; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Planar perovskite solar cells with long-term stability using ionic liquid additives", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar cells based on metal halide perovskites are one of the most promising photovoltaic technologies(1-4). Over the past few years, the long-term operational stability of such devices has been greatly improved by tuning the composition of the perovskites(5-9), optimizing the interfaces within the device structures(10-13), and using new encapsulation techniques(14,15). However, further improvements are required in order to deliver a longer-lasting technology. Ion migration in the perovskite active layer-especially under illumination and heat-is arguably the most difficult aspect to mitigate(16-18). Here we incorporate ionic liquids into the perovskite film and thence into positive-intrinsic-negative photovoltaic devices, increasing the device efficiency and markedly improving the long-term device stability. Specifically, we observe a degradation in performance of only around five per cent for the most stable encapsulated device under continuous simulated full-spectrum sunlight for more than 1,800 hours at 70 to 75 degrees Celsius, and estimate that the time required for the device to drop to eighty per cent of its peak performance is about 5,200 hours. Our demonstration of long-term operational, stable solar cells under intense conditions is a key step towards a reliable perovskite photovoltaic technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 825, "Times Cited, All Databases": 847, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2019, "Volume": 571, "Issue": 7764, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1357-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1357-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474843400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, LP; Liang, YP; Chen, JY; Huang, Y; Alsareii, SA; Alamri, AM; Harraz, FA; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Lipeng; Liang, Yongping; Chen, Jueying; Huang, Ying; Alsareii, Saeed A.; Alamri, Abdulrahman Manaa; Harraz, Farid A.; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial conductive self-healing hydrogel wound dressing with dual dynamic bonds promotes infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In clinical applications, there is a lack of wound dressings that combine efficient resistance to drug-resistant bacteria with good self-healing properties. In this study, a series of adhesive self-healing conductive antibacte-rial hydrogel dressings based on oxidized sodium alginate-grafted dopamine/carboxymethyl chitosan/Fe3+ (OSD/CMC/Fe hydrogel)/polydopamine-encapsulated poly(thiophene-3-acetic acid) (OSD/CMC/Fe/PA hydro-gel) were prepared for the repair of infected wound. The Schiff base and Fe3+ coordination bonds of the hydrogel structure are dynamic bonds that can be repaired automatically after the hydrogel network is disrupted. Macroscopically, the hydrogel exhibits self-healing properties, allowing the hydrogel dressing to adapt to complex wound surfaces. The OSD/CMC/Fe/PA hydrogel showed good conductivity and photothermal anti-bacterial properties under near-infrared (NIR) light irradiation. In addition, the hydrogels exhibit tunable rheological properties, suitable mechanical properties, antioxidant properties, tissue adhesion properties and hemostatic properties. Furthermore, all hydrogel dressings improved wound healing in the infected full-thickness defect skin wound repair test in mice. The wound size repaired by OSD/CMC/Fe/PA3 hydrogel + NIR was much smaller (12%) than the control group treated with TegadermTM film after 14 days. In conclusion, the hydrogels have high antibacterial efficiency, suitable conductivity, great self-healing properties, good biocompatibility, hemostasis and antioxidant properties, making them promising candidates for wound healing dressings for the treatment of infected skin wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 30, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 129, "End Page": 141, "Article Number": null, "DOI": "10.1016/j.bioactmat.2023.07.015", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2023.07.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053110100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GB; Xu, LG; Chao, Y; Xu, J; Sun, XQ; Wu, YF; Peng, R; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Guangbao; Xu, Ligeng; Chao, Yu; Xu, Jun; Sun, Xiaoqi; Wu, Yifan; Peng, Rui; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow MnO2 as a tumor-microenvironment-responsive biodegradable nullo-platform for combination therapy favoring antitumor immune responses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, an intelligent biodegradable hollow manganese dioxide (H-MnO2) nullo-platform is developed for not only tumor microenvironment (TME)-specific imaging and on-demand drug release, but also modulation of hypoxic TME to enhance cancer therapy, resulting in comprehensive effects favoring anti-tumor immune responses. With hollow structures, H-MnO2 nulloshells post modification with polyethylene glycol (PEG) could be co-loaded with a photodynamic agent chlorine e6 (Ce6), and a chemotherapy drug doxorubicin (DOX). The obtained H-MnO2-PEG/C&D would be dissociated under reduced pH within TME to release loaded therapeutic molecules, and in the meantime induce decomposition of tumor endogenous H2O2 to relieve tumor hypoxia. As a result, a remarkable in vivo synergistic therapeutic effect is achieved through the combined chemo-photodynamic therapy, which simultaneously triggers a series of anti-tumor immune responses. Its further combination with checkpoint-blockade therapy would lead to inhibition of tumors at distant sites, promising for tumor metastasis treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1240, "Times Cited, All Databases": 1274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 902, "DOI": "10.1038/s41467-017-01050-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01050-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412860100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, LF; Wang, J; Xu, GY; Li, HS; Dou, H; Zhang, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Laifa; Wang, Jie; Xu, Guiyin; Li, Hongsen; Dou, Hui; Zhang, Xiaogang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NiCo2S4 nullosheets Grown on Nitrogen-Doped Carbon Foams as an Advanced Electrode for Supercapacitors", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To push the energy density limit of supercapacitors, a new class of electrode materials with favorable architectures is strongly needed. Binary metal sulfides hold great promise as an electrode material for high-performance energy storage devices because they offer higher electrochemical activity and higher capacity than mono-metal sulfides. Here, the rational design and fabrication of NiCo2S4 nullosheets supported on nitrogen-doped carbon foams (NCF) is presented as a novel flexible electrode for supercapacitors. A facile two-step method is developed for growth of NiCo2S4 nullosheets on NCF with robust adhesion, involving the growth of Ni-Co precursor and subsequent conversion into NiCo2S4 nullosheets through sulfidation process. Benefiting from the compositional features and 3D electrode architectures, the NiCo2S4/NCF electrode exhibits greatly improved electrochemical performance with ultrahigh capacitance (877 F g(-1) at 20 A g(-1)) and excellent cycling stability. Moreover, a binder-free asymmetric supercapacitor device is also fabricated by using NiCo2S4/NCF as the positive electrode and ordered mesoporous carbon (OMC)/NCF as the negative electrode; this demonstrates high energy density (similar to 45.5 Wh kg(-1) at 512 W kg(-1)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 759, "Times Cited, All Databases": 779, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1400977, "DOI": "10.1002/aenm.201400977", "DOI Link": "http://dx.doi.org/10.1002/aenm.201400977", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350565400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghasemi, H; Ni, G; Marconnet, AM; Loomis, J; Yerci, S; Miljkovic, N; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghasemi, Hadi; Ni, George; Marconnet, Amy Marie; Loomis, James; Yerci, Selcuk; Miljkovic, Nenad; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar steam generation by heat localization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, steam generation using solar energy is based on heating bulk liquid to high temperatures. This approach requires either costly high optical concentrations leading to heat loss by the hot bulk liquid and heated surfaces or vacuum. New solar receiver concepts such as porous volumetric receivers or nullofluids have been proposed to decrease these losses. Here we report development of an approach and corresponding material structure for solar steam generation while maintaining low optical concentration and keeping the bulk liquid at low temperature with no vacuum. We achieve solar thermal efficiency up to 85% at only 10kWm(-2). This high performance results from four structure characteristics: absorbing in the solar spectrum, thermally insulating, hydrophilic and interconnected pores. The structure concentrates thermal energy and fluid flow where needed for phase change and minimizes dissipated energy. This new structure provides a novel approach to harvesting solar energy for a broad range of phase-change applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1837, "Times Cited, All Databases": 1949, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4449, "DOI": "10.1038/ncomms5449", "DOI Link": "http://dx.doi.org/10.1038/ncomms5449", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340622900041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JY; Wang, H; Huang, HL; Xu, XD; Chen, MW; Wu, Y; Liu, XJ; Nieh, TG; An, K; Lu, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, J. Y.; Wang, H.; Huang, H. L.; Xu, X. D.; Chen, M. W.; Wu, Y.; Liu, X. J.; Nieh, T. G.; An, K.; Lu, Z. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A precipitation-hardened high-entropy alloy with outstanding tensile properties", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent studies indicated that high-entropy alloys (HEAs) possess unusual structural and thermal features, which could greatly affect dislocation motion and contribute to the mechanical performance, however, a HEA matrix alone is insufficiently strong for engineering applications and other strengthening mechanisms are urgently needed to be incorporated. In this work, we demonstrate the possibility to precipitate nullosized coherent reinforcing phase, i.e., L1(2)-Ni-3(TLA1), in a fcc-FeCoNiCr HEA matrix using minor additions of Ti and Al. Through thermomechanical processing and microstructure controlling, extraordinary balanced tensile properties at room temperature were achieved, which is due to a well combination of various hardening mechanisms, particularly precipitation hardening. The applicability and validity of the conventional strengthening theories are also discussed. The current work is a successful demonstration of using integrated strengthening approaches to manipulate the properties of fcc-HEA systems, and the resulting findings are important not only for understanding the strengthening mechanisms of metallic materials in general, but also for the future development of high-performance HEAs for industrial applications. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1963, "Times Cited, All Databases": 2061, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2016, "Volume": 102, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 187, "End Page": 196, "Article Number": null, "DOI": "10.1016/j.actamat.2015.08.076", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.08.076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365368800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JT; Yu, L; Chen, Y; Lu, XF; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang Jintao; Yu Le; Chen Ye; Lu, Xue Feng; Gao Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designed Formation of Double-Shelled Ni-Fe Layered-Double-Hydroxide nullocages for Efficient Oxygen Evolution Reaction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Delicate design of nullostructures for oxygen-evolution electrocatalysts is an important strategy for accelerating the reaction kinetics of water splitting. In this work, Ni-Fe layered-double-hydroxide (LDH) nullocages with tunable shells are synthesized via a facile one-pot self-templating method. The number of shells can be precisely controlled by regulating the template etching at the interface. Benefiting from the double-shelled structure with large electroactive surface area and optimized chemical composition, the hierarchical Ni-Fe LDH nullocages exhibit appealing electrocatalytic activity for the oxygen evolution reaction in alkaline electrolyte. Particularly, double-shelled Ni-Fe LDH nullocages can achieve a current density of 20 mA cm(-2) at a low overpotential of 246 mV with excellent stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 32, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906432, "DOI": "10.1002/adma.201906432", "DOI Link": "http://dx.doi.org/10.1002/adma.201906432", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529881300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XD; Wang, P; Wang, JL; Hu, WD; Zhou, XH; Guo, N; Huang, H; Sun, S; Shen, H; Lin, T; Tang, MH; Liao, L; Jiang, AQ; Sun, JL; Meng, XJ; Chen, XS; Lu, W; Chu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xudong; Wang, Peng; Wang, Jianlu; Hu, Weida; Zhou, Xiaohao; Guo, null; Huang, Hai; Sun, Shuo; Shen, Hong; Lin, Tie; Tang, Minghua; Liao, Lei; Jiang, Anquan; Sun, Jinglan; Meng, Xiangjian; Chen, Xiaoshuang; Lu, Wei; Chu, Junhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive and Broadband MoS2 Photodetector Driven by Ferroelectrics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A few-layer MoS2 photodetector driven by poly(vinylidene fluoride-trifluoroethylene) ferroelectrics is achieved. The detectivity and responsitivity are up to 2.2 x 10(12) Jones and 2570 A W-1, respectively, at 635 nm with ZERO gate bias. E-g of MoS2 is tuned by the ultra-high electrostatic field from the ferroelectric polarization. The photo response wavelengths of the photo detector are extended into the near-infrared (0.85-1.55 mu m).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 751, "Times Cited, All Databases": 792, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2015, "Volume": 27, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6575, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201503340", "DOI Link": "http://dx.doi.org/10.1002/adma.201503340", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364700200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, L; Wei, YY; Li, LB; Zhang, T; Wang, HH; Xue, J; Ding, LX; Wang, SQ; Caro, J; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Li; Wei, Yanying; Li, Libo; Zhang, Tao; Wang, Haihui; Xue, Jian; Ding, Liang-Xin; Wang, Suqing; Caro, Juergen; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene molecular sieving membranes for highly efficient gas separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular sieving membranes with sufficient and uniform nullochannels that break the permeability-selectivity trade-off are desirable for energy-efficient gas separation, and the arising two-dimensional (2D) materials provide new routes for membrane development. However, for 2D lamellar membranes, disordered interlayer nullochannels for mass transport are usually formed between randomly stacked neighboring nullosheets, which is obstructive for highly efficient separation. Therefore, manufacturing lamellar membranes with highly ordered nullochannel structures for fast and precise molecular sieving is still challenging. Here, we report on lamellar stacked MXene membranes with aligned and regular subnullometer channels, taking advantage of the abundant surface-terminating groups on the MXene nullosheets, which exhibit excellent gas separation performance with H-2 permeability > 2200 Barrer and H-2/CO2 selectivity > 160, superior to the state-of-the-art membranes. The results of molecular dynamics simulations quantitatively support the experiments, confirming the subnullometer interlayer spacing between the neighboring MXene nullosheets as molecular sieving channels for gas separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 895, "Times Cited, All Databases": 938, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 155, "DOI": "10.1038/s41467-017-02529-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02529-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419947200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mannix, AJ; Zhou, XF; Kiraly, B; Wood, JD; Alducin, D; Myers, BD; Liu, XL; Fisher, BL; Santiago, U; Guest, JR; Yacaman, MJ; Ponce, A; Oganov, AR; Hersam, MC; Guisinger, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mannix, Andrew J.; Zhou, Xiang-Feng; Kiraly, Brian; Wood, Joshua D.; Alducin, Diego; Myers, Benjamin D.; Liu, Xiaolong; Fisher, Brandon L.; Santiago, Ulises; Guest, Jeffrey R.; Yacaman, Miguel Jose; Ponce, Arturo; Oganov, Artem R.; Hersam, Mark C.; Guisinger, Nathan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At the atomic-cluster scale, pure boron is markedly similar to carbon, forming simple planar molecules and cage-like fullerenes. Theoretical studies predict that two-dimensional (2D) boron sheets will adopt an atomic configuration similar to that of boron atomic clusters. We synthesized atomically thin, crystalline 2D boron sheets (i.e., borophene) on silver surfaces under ultrahigh-vacuum conditions. Atomic-scale characterization, supported by theoretical calculations, revealed structures reminiscent of fused boron clusters with multiple scales of anisotropic, out-of-plane buckling. Unlike bulk boron allotropes, borophene shows metallic characteristics that are consistent with predictions of a highly anisotropic, 2D metal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2187, "Times Cited, All Databases": 2304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2015, "Volume": 350, "Issue": 6267, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1513, "End Page": 1516, "Article Number": null, "DOI": "10.1126/science.aad1080", "DOI Link": "http://dx.doi.org/10.1126/science.aad1080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366591100055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, P; Liu, B; Liang, CB; Ruan, KP; Qiu, H; Ma, ZL; Guo, YQ; Gu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Ping; Liu, Bei; Liang, Chaobo; Ruan, Kunpeng; Qiu, Hua; Ma, Zhonglei; Guo, Yongqiang; Gu, Junwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, Flexible Cellulose-Derived Carbon Aerogel@Reduced Graphene Oxide/PDMS Composites with Outstanding EMI Shielding Performances and Excellent Thermal Conductivities", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to ensure the operational reliability and information security of sophisticated electronic components and to protect human health, efficient electromagnetic interference (EMI) shielding materials are required to attenuate electromagnetic wave energy. In this work, the cellulose solution is obtained by dissolving cotton through hydrogen bond driving self-assembly using sodium hydroxide (NaOH)/urea solution, and cellulose aerogels (CA) are prepared by gelation and freeze-drying. Then, the cellulose carbon aerogel@reduced graphene oxide aerogels (CCA@rGO) are prepared by vacuum impregnation, freeze-drying followed by thermal annealing, and finally, the CCA@rGO/polydimethylsiloxane (PDMS) EMI shielding composites are prepared by backfilling with PDMS. Owing to skin-core structure of CCA@rGO, the complete three-dimensional (3D) double-layer conductive network can be successfully constructed. When the loading of CCA@rGO is 3.05 wt%, CCA@rGO/PDMS EMI shielding composites have an excellent EMI shielding effectiveness (EMI SE) of 51 dB, which is 3.9 times higher than that of the co-blended CCA/rGO/PDMS EMI shielding composites (13 dB) with the same loading of fillers. At this time, the CCA@rGO/PDMS EMI shielding composites have excellent thermal stability (T-HRI of 178.3 degrees C) and good thermal conductivity coefficient (lambda of 0.65 W m(-1) K-1). Excellent comprehensive performance makes CCA@rGO/PDMS EMI shielding composites great prospect for applications in lightweight, flexible EMI shielding composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 588, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 91, "DOI": "10.1007/s40820-021-00624-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00624-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629787500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, HL; Dong, JC; Arellano-Jiménez, MJ; Ye, GL; Kim, ND; Samuel, ELG; Peng, ZW; Zhu, Z; Qin, F; Bao, JM; Yacaman, MJ; Ajayan, PM; Chen, DL; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Huilong; Dong, Juncai; Arellano-Jimenez, M. Josefina; Ye, Gonglan; Kim, Nam Dong; Samuel, Errol L. G.; Peng, Zhiwei; Zhu, Zhuan; Qin, Fan; Bao, Jiming; Yacaman, Miguel Jose; Ajayan, Pulickel M.; Chen, Dongliang; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic cobalt on nitrogen-doped graphene for hydrogen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts. Here we report an electrocatalyst for hydrogen generation based on very small amounts of cobalt dispersed as individual atoms on nitrogen-doped graphene. This catalyst is robust and highly active in aqueous media with very low overpotentials (30 mV). A variety of analytical techniques and electrochemical measurements suggest that the catalytically active sites are associated with the metal centres coordinated to nitrogen. This unusual atomic constitution of supported metals is suggestive of a new approach to preparing extremely efficient single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1468, "Times Cited, All Databases": 1527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8668, "DOI": "10.1038/ncomms9668", "DOI Link": "http://dx.doi.org/10.1038/ncomms9668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364936200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nasalevich, MA; Becker, R; Ramos-Fernulldez, EV; Castellanos, S; Veber, SL; Fedin, MV; Kapteijn, F; Reek, JNH; van der Vlugt, JI; Gascon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nasalevich, M. A.; Becker, R.; Ramos-Fernulldez, E. V.; Castellanos, S.; Veber, S. L.; Fedin, M. V.; Kapteijn, F.; Reek, J. N. H.; van der Vlugt, J. I.; Gascon, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co@NH2-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H2 production", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 364, "End Page": 375, "Article Number": null, "DOI": "10.1039/c4ee02853h", "DOI Link": "http://dx.doi.org/10.1039/c4ee02853h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346563600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, L; Wan, G; Zhang, R; Zhou, H; Yu, SH; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Long; Wan, Gang; Zhang, Rui; Zhou, Hua; Yu, Shu-Hong; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It remains highly desired but a great challenge to achieve atomically dispersed metals in high loadings for efficient catalysis. Now porphyrinic metal-organic frameworks (MOFs) have been synthesized based on a novel mixed-ligand strategy to afford high-content (1.76wt%) single-atom (SA) iron-implanted N-doped porous carbon (Fe-SA-N-C) via pyrolysis. Thanks to the single-atom Fe sites, hierarchical pores, oriented mesochannels and high conductivity, the optimized Fe-SA-N-C exhibits excellent oxygen reduction activity and stability, surpassing almost all non-noble-metal catalysts and state-of-the-art Pt/C, in both alkaline and more challenging acidic media. More far-reaching, this MOF-based mixed-ligand strategy opens a novel avenue to the precise fabrication of efficient single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 734, "Times Cited, All Databases": 762, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2018, "Volume": 57, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8525, "End Page": 8529, "Article Number": null, "DOI": "10.1002/anie.201803262", "DOI Link": "http://dx.doi.org/10.1002/anie.201803262", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437668700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DD; Eaton, SW; Yu, Y; Dou, LT; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dandan; Eaton, Samuel W.; Yu, Yi; Dou, Letian; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution-Phase Synthesis of Cesium Lead Halide Perovskite nullowires", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskites have attracted much attention over the past 5 years as a promising class of materials for optoelectronic applications. However, compared to hybrid organic-inorganic perovskites, the study of their pure inorganic counterparts, like cesium lead halides (CsPbX3), lags far behind. Here, a catalyst-free, solution-phase synthesis of CsPbX3 nullowires (NWs) is reported. These NWs are single-crystalline, with uniform growth direction, and crystallize in the orthorhombic phase. Both CsPbBr3 and CsPbI3 are photoluminescence active, with composition-dependent temperature and self-trapping behavior. These NWs with a well-defined morphology could serve as an ideal platform for the investigation of fundamental properties and the development of future applications in nulloscale optoelectronic devices based on all-inorganic perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 882, "Times Cited, All Databases": 955, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2015, "Volume": 137, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9230, "End Page": 9233, "Article Number": null, "DOI": "10.1021/jacs.5b05404", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b05404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358896600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aguirre, ME; Zhou, RX; Eugene, AJ; Guzman, MI; Grela, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aguirre, Matias E.; Zhou, Ruixin; Eugene, Alexis J.; Guzman, Marcelo I.; Grela, Maria A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu2O/TiO2 heterostructures for CO2 reduction through a direct Z-scheme: Protecting Cu2O from photocorrosion", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of artificial photosynthesis aims to solve the increasing energy demand and associated environmental problems. A model photosynthetic system employing a composite of semiconductors with a Z-scheme can potentially mimic the combined power of photosystems 1 and 2 to transfer electrons. In this work, octahedral cuprous oxide covered with titanium dioxide nulloparticles (Cu2O/TiO2) are synthesized by a solvothermal strategy that provides high morphological and crystallographic control. The formation of a p-n heterojunction and characterization of the Type II band alignment of the composite are performed by diffuse reflectance UV-visible (DRUV) spectroscopy, ultraviolet photoelectron spectroscopy (UPS), and X-ray photoelectron spectroscopy (XPS). Upon UV-visible irradiation (lambda >= 305 nm) of the composite in the presence of water vapor as the hole scavenger, the photoreduction of CO2(g) proceeds selectively to generate CO(g). The production rate of CO by the composite, R-CO = 2.11 mu mol g(cat)(-1) h(-1), is 4-times larger than for pure Cu2O under identical conditions. Contrasting XPS analyses of Cu2O and Cu2O/TiO2, during photocatalysts operation and the detection of photogenerated hydroxyl radicals (HO center dot) in the heterostructure at variance with the results obtained for pure Cu2O are taken as evidences that TiO2 protects Cu2O from undergoing photocorrosion. These results provide direct evidence of an efficient Z-scheme as the main mechanism for harvesting energy during CO2 reduction in the synthesized materials. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 501, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 217, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 485, "End Page": 493, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.05.058", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.05.058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405158000049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YJ; Tao, XY; Wang, Y; Jiang, C; Ma, C; Sheng, OW; Lu, GX; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yujing; Tao, Xinyong; Wang, Yao; Jiang, Chi; Ma, Cong; Sheng, Ouwei; Lu, Gongxun; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy density lithium (Li) metal batteries (LMBs) are promising for energy storage applications but suffer from uncontrollable electrolyte degradation and the consequently formed unstable solid-electrolyte interphase (SEI). In this study, we designed self-assembled monolayers (SAMs) with high-density and long-range-ordered polar carboxyl groups linked to an aluminum oxide-coated separator to provide strong dipole moments, thus offering excess electrons to accelerate the degradation dynamics of carbon-fluorine bond cleavage in Li bis(trifluoromethanesulfonyl)imide. Hence, an SEI with enriched lithium fluoride (LiF) nullocrystals is generated, facilitating rapid Li+ transfer and suppressing dendritic Li growth. In particular, the SAMs endow the full cells with substantially enhanced cyclability under high cathode loading, limited Li excess, and lean electrolyte conditions. As such, our work extends the long-established SAMs technology into a platform to control electrolyte degradation and SEI formation toward LMBs with ultralong life spans.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 569, "Times Cited, All Databases": 589, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2022, "Volume": 375, "Issue": 6582, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 739, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn1818", "DOI Link": "http://dx.doi.org/10.1126/science.abn1818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758142600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Nam-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite solar cells: an emerging photovoltaic technology", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells based on organometal halides represent an emerging photovoltaic technology. Perovskite solar cells stem from dye-sensitized solar cells. In a liquid-based dye-sensitized solar cell structure, the adsorption of methylammonium lead halide perovskite on a nullocrystalline TiO2 surface produces a photocurrent with a power conversion efficiency (PCE) of around 3-4%, as first discovered in 2009. The PCE was doubled after 2 years by optimizing the perovskite coating conditions. However, the liquid-based perovskite solar cell receives little attention because of its stability issues, including instant dissolution of the perovskite in a liquid electrolyte. A long-term, stable, and high efficiency (similar to 10%) perovskite solar cell was developed in 2012 by substituting the solid hole conductor with a liquid electrolyte. Efficiencies have quickly risen to 18% in just 2 years. Since PCE values over 20% are realistically anticipated with the use of cheap organometal halide perovskite materials, perovskite solar cells are a promising photovoltaic technology. In this review, the opto-electronic properties of perovskite materials and recent progresses in perovskite solar cells are described. In addition, comments on the issues to current and future challenges are mentioned.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1531, "Times Cited, All Databases": 1685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 18, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 72, "Article Number": null, "DOI": "10.1016/j.mattod.2014.07.007", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.07.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349625100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vilé, G; Albani, D; Nachtegaal, M; Chen, ZP; Dontsova, D; Antonietti, M; López, N; Pérez-Ramírez, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vile, Gianvito; Albani, Davide; Nachtegaal, Maarten; Chen, Zupeng; Dontsova, Dariya; Antonietti, Markus; Lopez, Nuria; Perez-Ramirez, Javier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Stable Single-Site Palladium Catalyst for Hydrogenations", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the preparation and hydrogenation performance of a single-site palladium catalyst that was obtained by the anchoring of Pd atoms into the cavities of mesoporous polymeric graphitic carbon nitride. The characterization of the material confirmed the atomic dispersion of the palladium phase throughout the sample. The catalyst was applied for three-phase hydrogenations of alkynes and nitroarenes in a continuous-flow reactor, showing its high activity and product selectivity in comparison with benchmark catalysts based on nulloparticles. Density functional theory calculations provided fundamental insights into the material structure and attributed the high catalyst activity and selectivity to the facile hydrogen activation and hydrocarbon adsorption on atomically dispersed Pd sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 805, "Times Cited, All Databases": 851, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2015, "Volume": 54, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11265, "End Page": 11269, "Article Number": null, "DOI": "10.1002/anie.201505073", "DOI Link": "http://dx.doi.org/10.1002/anie.201505073", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363389400052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, HS; Liu, XY; Wang, AQ; Zhang, LL; Qiao, BT; Yang, XF; Huang, YQ; Miao, S; Liu, JY; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Haisheng; Liu, Xiaoyan; Wang, Aiqin; Zhang, Leilei; Qiao, Botao; Yang, Xiaofeng; Huang, Yanqiang; Miao, Shu; Liu, Jingyue; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic hydrogenation of nitroarenes is an environmentally benign technology for the production of anilines, which are key intermediates for manufacturing agrochemicals, pharmaceuticals and dyes. Most of the precious metal catalysts, however, suffer from low chemoselectivity when one or more reducible groups are present in a nitroarene molecule. Herein we report FeOx-supported platinum single-atom and pseudo-single-atom structures as highly active, chemoselective and reusable catalysts for hydrogenation of a variety of substituted nitroarenes. For hydrogenation of 3-nitrostyrene, the catalyst yields a TOF of similar to 1,500 h(-1), 20-fold higher than the best result reported in literature, and a selectivity to 3-aminostyrene close to 99%, the best ever achieved over platinum group metals. The superior performance can be attributed to the presence of positively charged platinum centres and the absence of Pt-Pt metallic bonding, both of which favour the preferential adsorption of nitro groups.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 969, "Times Cited, All Databases": 1040, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5634, "DOI": "10.1038/ncomms6634", "DOI Link": "http://dx.doi.org/10.1038/ncomms6634", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347226900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lipatov, A; Alhabeb, M; Lukatskaya, MR; Boson, A; Gogotsi, Y; Sinitskii, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R.; Boson, Alex; Gogotsi, Yury; Sinitskii, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti3C2 MXene Flakes", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition metal carbide Ti3C2Tx (T stands for surface termination), the most widely studied MXene, has shown outstanding electrochemical properties and promise for a number of bulk applications. However, electronic properties of individual MXene flakes, which are important for understanding the potential of these materials, remain largely unexplored. Herein, a modified synthetic method is reported for producing high-quality monolayer Ti(3)C(2)Tx flakes. Field-effect transistors (FETs) based on monolayer Ti(3)C(2)Tx flakes are fabricated and their electronic properties are measured. Individual Ti(3)C(2)Tx flakes exhibit a high conductivity of 4600 +/- 1100 S cm(-1) and field-effect electron mobility of 2.6 +/- 0.7 cm(2) V-1 s(-1). The resistivity of multilayer Ti(3)C(2)Tx films is only one order of magnitude higher than the resistivity of individual flakes, which indicates a surprisingly good electron transport through the surface terminations of different flakes, unlike in many other 2D materials. Finally, the fabricated FETs are used to investigate the environmental stability and kinetics of oxidation of Ti(3)C(2)Tx flakes in humid air. The high-quality Ti(3)C(2)Tx flakes are reasonably stable and remain highly conductive even after their exposure to air for more than 24 h. It is demonstrated that after the initial exponential decay the conductivity of Ti(3)C(2)Tx flakes linearly decreases with time, which is consistent with their edge oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1314, "Times Cited, All Databases": 1363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600255, "DOI": "10.1002/aelm.201600255", "DOI Link": "http://dx.doi.org/10.1002/aelm.201600255", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392939300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, F; Xu, Z; Jensen, ACS; Au, H; Lu, YX; Araullo-Peters, V; Drew, AJ; Hu, YS; Titirici, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Fei; Xu, Zhen; Jensen, Anders C. S.; Au, Heather; Lu, Yaxiang; Araullo-Peters, Vicente; Drew, Alan J.; Hu, Yong-Sheng; Titirici, Maria-Magdalena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hard-Soft Carbon Composite Anodes with Synergistic Sodium Storage Performance", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A series of hard-soft carbon composite materials is produced from biomass and oil waste and applied as low-cost anodes for sodium-ion batteries to study the fundamentals behind the dependence of Na storage on their structural features. A good reversible capacity of 282 mAh g(-1) is obtained at a current density of 30 mA g(-1) with a high initial Coulombic efficiency of 80% at a carbonization temperature of only 1000 degrees C by adjusting the ratio of hard to soft carbon. The performance is superior to the pure hard or soft carbon anodes produced at the same temperatures. This synergy between hard and soft carbon resulting in an excellent performance is due to the blockage of some open pores in hard carbon by the soft carbon, which suppresses the solid electrolyte interface formation and increases the reversible sodium storage capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 29, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901072, "DOI": "10.1002/adfm.201901072", "DOI Link": "http://dx.doi.org/10.1002/adfm.201901072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471074000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, HW; Peng, MH; Strauss, I; Mundstock, A; Meng, H; Caro, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Hongwei; Peng, Manhua; Strauss, Ina; Mundstock, Alexander; Meng, Hong; Caro, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-in-COF molecular sieving membrane for selective hydrogen separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are promising materials for advanced molecular-separation membranes, but their wide nullometer-sized pores prevent selective gas separation through molecular sieving. Herein, we propose a MOF-in-COF concept for the confined growth of metal-organic framework (MOFs) inside a supported COF layer to prepare MOF-in-COF membranes. These membranes feature a unique MOF-in-COF micro/nullopore network, presumably due to the formation of MOFs as a pearl string-like chain of unit cells in the 1D channel of 2D COFs. The MOF-in-COF membranes exhibit an excellent hydrogen permeance (>3000 GPU) together with a significant enhancement of separation selectivity of hydrogen over other gases. The superior separation performance for H-2/CO2 and H-2/CH4 surpasses the Robeson upper bounds, benefiting from the synergy combining precise size sieving and fast molecular transport through the MOF-in-COF channels. The synthesis of different combinations of MOFs and COFs in robust MOF-in-COF membranes demonstrates the versatility of our design strategy. Covalent organic frameworks (COFs) are promising materials for separation membranes, but their wide pores prevent selective gas separation through molecular sieving. Here, the authors demonstrate a Metal-organic framework (MOF)-in-COF membrane with a significant enhancement of separation selectivity of hydrogen over other gases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 38, "DOI": "10.1038/s41467-020-20298-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20298-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665627200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JN; Li, QH; Ouyang, CY; Yu, XQ; Ge, MY; Huang, XJ; Hu, EY; Ma, C; Li, SF; Xiao, RJ; Yang, WL; Chu, Y; Liu, YJ; Yu, HG; Yang, XQ; Huang, XJ; Chen, LQ; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jie-null; Li, Qinghao; Ouyang, Chuying; Yu, Xiqian; Ge, Mingyuan; Huang, Xiaojing; Hu, Enyuan; Ma, Chao; Li, Shaofeng; Xiao, Ruijuan; Yang, Wanli; Chu, Yong; Liu, Yijin; Yu, Huigen; Yang, Xiao-Qing; Huang, Xuejie; Chen, Liquan; Li, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6V", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "LiCoO2 is a dominullt cathode material for lithium-ion (Li-ion) batteries due to its high volumetric energy density, which could potentially be further improved by charging to high voltages. However, practical adoption of high-voltage charging is hindered by LiCoO2 's structural instability at the deeply delithiated state and the associated safety concerns. Here, we achieve stable cycling of LiCoO2 at 4.6V (versus Li/Li+) through trace Ti-Mg-Al co-doping. Using state-of-the-art synchrotron X-ray imaging and spectroscopic techniques, we report the incorporation of Mg and Al into the LiCoO2 lattice, which inhibits the undesired phase transition at voltages above 4.5 V. We also show that, even in trace amounts, Ti segregates significantly at grain boundaries and on the surface, modifying the microstructure of the particles while stabilizing the surface oxygen at high voltages. These dopants contribute through different mechanisms and synergistically promote the cycle stability of LiCoO2 at 4.6 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 688, "Times Cited, All Databases": 732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 594, "End Page": 603, "Article Number": null, "DOI": "10.1038/s41560-019-0409-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0409-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474920100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, X; Liu, MM; Chen, XY; Sun, JM; Du, CH; Zhang, Y; Zhai, JY; Hu, WG; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Xiong; Liu, Mengmeng; Chen, Xiangyu; Sun, Jiangman; Du, Chunhua; Zhang, Yang; Zhai, Junyi; Hu, Weiguo; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastretchable, transparent triboelectric nullogenerator as electronic skin for biomechanical energy harvesting and tactile sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid advancements in stretchable and multifunctional electronics impose the challenge on corresponding power devices that they should have comparable stretchability and functionality. We report a soft skin-like triboelectric nullogenerator (STENG) that enables both biomechanical energy harvesting and tactile sensing by hybridizing elastomer and ionic hydrogel as the electrification layer and electrode, respectively. For the first time, ultrahigh stretchability (uniaxial strain, 1160%) and transparency (average transmittance, 96.2% for visible light) are achieved simultaneously for an energy-harvesting device. The soft TENG is capable of outputting alternative electricity with an instantaneous peak power density of 35 mW m(-2) and driving wearable electronics (for example, an electronic watch) with energy converted from human motions, whereas the STENG is pressuresensitive, enabling its application as artificial electronic skin for touch/pressure perception. Our work provides new opportunities for multifunctional power sources and potential applications in soft/wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1103, "Times Cited, All Databases": 1164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700015", "DOI": "10.1126/sciadv.1700015", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419752300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, L; Wang, SN; Xiao, JJ; Bian, XJ; Zhang, YH; Scanlon, MD; Hu, XL; Tang, Y; Liu, BH; Girault, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Lei; Wang, Sinong; Xiao, Jingjing; Bian, Xiaojun; Zhang, Yahong; Scanlon, Micheal D.; Hu, Xile; Tang, Yi; Liu, Baohong; Girault, Hubert H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A nulloporous molybdenum carbide nullowire as an electrocatalyst for hydrogen evolution reaction", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A highly active and stable electrochemical catalyst of nulloporous molybdenum carbide nullowires (np-Mo2C NWs) has been developed for hydrogen evolution reaction (HER). The np-Mo2C NWs were synthesized simply by pyrolysis of a MoOx,/amine hybrid precursor with sub-nullosized periodic structure under an inert atmosphere. The enriched nulloporosity and large reactive surface of these highly dispersed nullowires with uniform Mo2C nullocrystallites provide an efficient electrocatalysis, leading to their superior HER activity with lower onset overpotential and higher current densities than Mo2C microparticles. This study opens a new perspective for the development of highly active non-noble electrocatalysts for hydrogen production from water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 955, "Times Cited, All Databases": 1006, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 387, "End Page": 392, "Article Number": null, "DOI": "10.1039/c3ee42441c", "DOI Link": "http://dx.doi.org/10.1039/c3ee42441c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329550700028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WL; Gang, Y; Hu, Z; Yan, ZC; Li, WJ; Li, YC; Gu, QF; Wang, ZX; Chou, SL; Liu, HK; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wanlin; Gang, Yong; Hu, Zhe; Yan, Zichao; Li, Weijie; Li, Yongcheng; Gu, Qin-Fen; Wang, Zhixing; Chou, Shu-Lei; Liu, Hua-Kun; Dou, Shi-Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron-based Prussian blue analogs are promising low-cost and easily prepared cathode materials for sodium-ion batteries. Their materials quality and electrochemical performance are heavily reliant on the precipitation process. Here we report a controllable precipitation method to synthesize high-performance Prussian blue for sodium-ion storage. Characterization of the nucleation and evolution processes of the highly crystalline Prussian blue microcubes reveals a rhombohedral structure that exhibits high initial Coulombic efficiency, excellent rate performance, and cycling properties. The phase transitions in the as-obtained material are investigated by synchrotron in situ powder X-ray diffraction, which shows highly reversible structural transformations between rhombohedral, cubic, and tetragonal structures upon sodium-ion (de)intercalations. Moreover, the Prussian blue material from a large-scale synthesis process shows stable cycling performance in a pouch full cell over 1000 times. We believe that this work could pave the way for the real application of Prussian blue materials in sodium-ion batteries. Here the authors deploy a scalable synthesis route to prepare sodium-rich Na2-xFeFe(CN)(6) cathode materials for sodium-ion battery. The highly reversible structural evolution during cycling between rhombohedral, cubic and tetragonal phases is the key to enable the good performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 980, "DOI": "10.1038/s41467-020-14444-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14444-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517260700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, K; Ricco, R; Doherty, CM; Styles, MJ; Bell, S; Kirby, N; Mudie, S; Haylock, D; Hill, AJ; Doonull, CJ; Falcaro, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Kang; Ricco, Raffaele; Doherty, Cara M.; Styles, Mark J.; Bell, Stephen; Kirby, Nigel; Mudie, Stephen; Haylock, David; Hill, Anita J.; Doonull, Christian J.; Falcaro, Paolo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancing the robustness of functional biomacromolecules is a critical challenge in biotechnology, which if addressed would enhance their use in pharmaceuticals, chemical processing and biostorage. Here we report a novel method, inspired by natural biomineralization processes, which provides unprecedented protection of biomacromolecules by encapsulating them within a class of porous materials termed metal-organic frameworks. We show that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules. The resulting biocomposite is stable under conditions that would normally decompose many biological macromolecules. For example, urease and horseradish peroxidase protected within a metal-organic framework shell are found to retain bioactivity after being treated at 80 degrees C and boiled in dimethylformamide (153 degrees C), respectively. This rapid, low-cost biomimetic mineralization process gives rise to new possibilities for the exploitation of biomacromolecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1177, "Times Cited, All Databases": 1249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7240, "DOI": "10.1038/ncomms8240", "DOI Link": "http://dx.doi.org/10.1038/ncomms8240", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357169000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, C; Feng, ZX; Scherer, GG; Barber, J; Shao-Horn, Y; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Chao; Feng, Zhenxing; Scherer, Gunther G.; Barber, James; Shao-Horn, Yang; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition-Metal Spinels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring efficient and low-cost electrocatalysts for the oxygen-reduction reaction (ORR) and oxygen-evolution reaction (OER) is critical for developing renewable energy technologies such as fuel cells, metal-air batteries, and water electrolyzers. A rational design of a catalyst can be guided by identifying descriptors that determine its activity. Here, a descriptor study on the ORR/OER of spinel oxides is presented. With a series of MnCo2O4, the Mn in octahedral sites is identified as an active site. This finding is then applied to successfully explain the ORR/OER activities of other transition-metal spinels, including MnxCo3-xO4 (x = 2, 2.5, 3), LixMn2O4 (x = 0.7, 1), XCo2O4 (X = Co, Ni, Zn), and XFe2O4 (X = Mn, Co, Ni). A general principle is concluded that the e(g) occupancy of the active cation in the octahedral site is the activity descriptor for the ORR/OER of spinels, consolidating the role of electron orbital filling in metal oxide catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 603, "Times Cited, All Databases": 620, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 29, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1606800, "DOI": "10.1002/adma.201606800", "DOI Link": "http://dx.doi.org/10.1002/adma.201606800", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403280600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XJ; Wang, Y; Zhang, XY; Xu, GQ; Wang, DM; Lv, J; Zheng, ZX; Wu, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xuejun; Wang, Yu; Zhang, Xinyi; Xu, Guangqing; Wang, Dongmei; Lv, Jun; Zheng, Zhixiang; Wu, Yucheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NiS and MoS2 nullosheet co-modified graphitic C3N4 ternary heterostructure for high efficient visible light photodegradation of antibiotic", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient solar driven catalytic system for the degradation of antibiotics has become increasingly important in environmental protection and remediation. Non-noble-metal NiS and MoS2 nullosheet co-modified graphitic C3N4 ternary heterostructure has been synthesized via a facile combination of hydrothermal and ultrasound method, and the ternary heterostructure has been utilized for photocatalytic degradation of antibiotic agents. The antibiotics of ciprofloxacin (CIP) and tetracycline hydrochloride (TC) were photodegraded by the hybrid under the visible light. The optimal photodegradation rate of the ternary heterostructure reaches about 96% after 2 h irradiation, which is 2.1 times higher than that of pure g-C3N4 for TC degradation. The photocatalytic degradation rates of the ternary heterostructure for both CIP and TC obey the pseudo-first-order kinetic model. The enhanced visible light adsorption and charge separation efficiency contribute to the photocatalytic performance of the ternary heterostructure. This work provides new insights and pathways by which efficient degradation of antibiotics can be achieved and will stimulate further studies in this important field. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 341, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10, "End Page": 19, "Article Number": null, "DOI": "10.1016/j.jhazmat.2017.07.004", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2017.07.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412378700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HJ; Li, X; Zhao, XX; Li, CY; Song, XH; Zhang, P; Huo, PW; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Huijie; Li, Xin; Zhao, Xiaoxue; Li, Chunyan; Song, Xianghai; Zhang, Peng; Huo, Pengwei; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A review on heterogeneous photocatalysis for environmental remediation: From semiconductors to modification strategies", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous photocatalysis, an advanced oxidation process, has garnered extensive attention in the field of environmental remediation because it involves the direct utilization of solar energy for the removal of numerous pollutants. However, the application of heterogeneous photocatalysis in environmental remediation has not achieved the expected consequences due to enormous challenges such as low photocatalytic efficiencies and high costs of heterogeneous photocatalysts in large-scale practical applications. Furthermore, pollutants in the natural environment, including water, air, and solid phases, are diverse and complex. Therefore, extensive efforts should be made to better understand and apply heterogeneous photocatalysis for environmental remediation. Herein, the fundamentals of heterogeneous photocatalysis for environmental remediation are introduced. Then, potential semiconductors and their modification strategies for environmental photocatalysis are systematically presented. Finally, conclusions and prospects are briefly summarized, and the direction for the future development of environmental photocatalysis is explored. This review may provide reference directions toward understanding, researching, and designing photocatalytic re mediation systems for various environmental pollutants. (c) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 568, "Times Cited, All Databases": 591, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 178, "End Page": 214, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63910-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63910-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, S; Shaner, MR; Beardslee, JA; Lichterman, M; Brunschwig, BS; Lewis, NS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Shu; Shaner, Matthew R.; Beardslee, Joseph A.; Lichterman, Michael; Brunschwig, Bruce S.; Lewis, Nathan S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous TiO2 coatings stabilize Si, GaAs, and GaP photoanodes for efficient water oxidation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although semiconductors such as silicon (Si), gallium arsenide (GaAs), and gallium phosphide (GaP) have band gaps that make them efficient photoanodes for solar fuel production, these materials are unstable in aqueous media. We show that TiO2 coatings (4 to 143 nullometers thick) grown by atomic layer deposition prevent corrosion, have electronic defects that promote hole conduction, and are sufficiently transparent to reach the light-limited performance of protected semiconductors. In conjunction with a thin layer or islands of Ni oxide electrocatalysts, Si photoanodes exhibited continuous oxidation of 1.0 molar aqueous KOH to O-2 for more than 100 hours at photocurrent densities of >30 milliamperes per square centimeter and similar to 100% Faradaic efficiency. TiO2-coated GaAs and GaP photoelectrodes exhibited photovoltages of 0.81 and 0.59 V and light-limiting photocurrent densities of 14.3 and 3.4 milliamperes per square centimeter, respectively, for water oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1172, "Times Cited, All Databases": 1316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2014, "Volume": 344, "Issue": 6187, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1005, "End Page": 1009, "Article Number": null, "DOI": "10.1126/science.1251428", "DOI Link": "http://dx.doi.org/10.1126/science.1251428", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336495800039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ML; Zhao, ZP; Duan, XF; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Meiling; Zhao, Zipeng; Duan, Xiangfeng; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale Structure Design for High-Performance Pt-Based ORR Catalysts", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton-exchange-membrane fuel cells (PEMFCs) are of considerable interest for direct chemical-to-electrical energy conversion and may represent an ultimate solution for mobile power supply. However, PEMFCs today are primarily limited by the sluggish kinetics of the cathodic oxygen reduction reaction (ORR), which requires a significant amount of Pt-based catalyst with a substantial contribution to the overall cost. Hence, promoting the activity and stability of the needed catalyst and minimizing the amount of Pt loaded are central to reducing the cost of PEMFCs for commercial deployment. Considerable efforts have been devoted to improving the catalytic performance of Pt-based ORR catalysts, including the development of various Pt nullostructures with tunable sizes and chemical compositions, controlled shapes with selectively displayed crystallographic surfaces, tailored surface strains, surface doping, geometry engineering, and interface engineering. Herein, a brief introduction of some fundamentals of fuel cells and ORR catalysts with performance metrics is provided, followed by a detailed description of a series of strategies for pushing the limit of high-performance Pt-based catalysts. A brief perspective and new insights on the remaining challenges and future directions of Pt-based ORR catalysts for fuel cells are also presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 679, "Times Cited, All Databases": 714, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 31, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802234, "DOI": "10.1002/adma.201802234", "DOI Link": "http://dx.doi.org/10.1002/adma.201802234", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459630600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, XY; Wang, JG; Liu, C; Wang, HT; Yao, HB; Zheng, GY; Seh, ZW; Cai, QX; Li, WY; Zhou, GM; Zu, CX; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Xinyong; Wang, Jianguo; Liu, Chong; Wang, Haotian; Yao, Hongbin; Zheng, Guangyuan; Seh, Zhi Wei; Cai, Qiuxia; Li, Weiyang; Zhou, Guangmin; Zu, Chenxi; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium-sulfur battery design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries have attracted attention due to their six-fold specific energy compared with conventional lithium-ion batteries. Dissolution of lithium polysulfides, volume expansion of sulfur and uncontrollable deposition of lithium sulfide are three of the main challenges for this technology. State-of-the-art sulfur cathodes based on metal-oxide nullostructures can suppress the shuttle-effect and enable controlled lithium sulfide deposition. However, a clear mechanistic understanding and corresponding selection criteria for the oxides are still lacking. Herein, various nonconductive metal-oxide nulloparticle-decorated carbon flakes are synthesized via a facile biotemplating method. The cathodes based on magnesium oxide, cerium oxide and lanthanum oxide show enhanced cycling performance. Adsorption experiments and theoretical calculations reveal that polysulfide capture by the oxides is via monolayered chemisorption. Moreover, we show that better surface diffusion leads to higher deposition efficiency of sulfide species on electrodes. Hence, oxide selection is proposed to balance optimization between sulfide-adsorption and diffusion on the oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1247, "Times Cited, All Databases": 1319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11203, "DOI": "10.1038/ncomms11203", "DOI Link": "http://dx.doi.org/10.1038/ncomms11203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373622000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, L; Lin, CY; Dou, S; Feng, S; Chen, DW; Liu, DD; Huo, J; Xia, ZH; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Li; Lin, Chun-Yu; Dou, Shuo; Feng, Shi; Chen, Dawei; Liu, Dongdong; Huo, Jia; Xia, Zhenhai; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creating coordinatively unsaturated metal sites in metal-organic-frameworks as efficient electrocatalysts for the oxygen evolution reaction: Insights into the active centers", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic-frameworks (MOFs), in which metal ions are single-atomically dispersed, are regarded as one of the most promising single-atom doped catalysts. Co-based species have been considered as a potential candidate to replace the precious RuO2 to electrocatalyze oxygen evolution reaction (OER). Zeolitic imidazolate frameworks-67 (ZIF-67), a Co-containing MOF, may be an excellent precursor for single-atom OER electrocatalysts due to its rich and uniform distribution of cobalt species. In principle, Co ions are fully coordinated (except for those on the surfaces) in ZIF-67 without accessible sites for electrocatalysis. One way to utilize this single-atom material as electrocatalysts is to remove some of the ligands attached to Co atoms to create coordinately unsaturated metal sites (CUMSs) as the catalytic centers for OER. Herein, we, for the first time, have created CUMSs in ZIF-67 through dielectric barrier discharge (DBD) plasma etching. The CUMSs act as excellent catalytic centers for OER with a promising electrocatalytic activity, even comparable to the precious RuO2. Interestingly, the OER activity of the CUMSs is reversible by supplementing the missing ligands. Our density-functional theory calculations also demonstrated the contribution of the unsaturated metal sites to the high catalytic activity for OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 41, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 417, "End Page": 425, "Article Number": null, "DOI": "10.1016/j.nulloen.2017.09.055", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2017.09.055", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415302600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Lu, J; Luo, K; Li, YB; Chang, KK; Chen, K; Zhou, J; Rosen, J; Hultman, L; Eklund, P; Persson, POÅ; Du, SY; Chai, ZF; Huang, ZR; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mian; Lu, Jun; Luo, Kan; Li, Youbing; Chang, Keke; Chen, Ke; Zhou, Jie; Rosen, Johanna; Hultman, Lars; Eklund, Per; Persson, Per O. A.; Du, Shiyu; Chai, Zhifang; Huang, Zhengren; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize nullolaminated MAX Phases and MXenes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullolaminated materials are important because of their exceptional properties and wide range of applications. Here, we demonstrate a general approach to synthesizing a series of Zn-based MAX phases and Cl-terminated MXenes originating from the replacement reaction between the MAX phase and the late transition-metal halides. The approach is a top-down route that enables the late transitional element atom (Zn in the present case) to occupy the A site in the pre-existing MAX phase structure. Using this replacement reaction between the Zn element from molten ZnCl2 and the Al element in MAX phase precursors (Ti3AlC2, Ti2AlC, Ti2AlN, and V2AlC), novel MAX phases Ti3ZnC2, Ti2ZnC, Ti2ZnN, and V2ZnC were synthesized. When employing excess ZnCl2, Cl-terminated MXenes (such as Ti3C2Cl2 and Ti2CCl2) were derived by a subsequent exfoliation of Ti3ZnC2 and Ti2ZnC due to the strong Lewis acidity of molten ZnCl2. These results indicate that A-site element replacement in traditional MAX phases by late transition-metal halides opens the door to explore MAX phases that are not thermodynamically stable at high temperature and would be difficult to synthesize through the commonly employed powder metallurgy approach. In addition, this is the first time that exclusively Cl-terminated MXenes were obtained, and the etching effect of Lewis acid in molten salts provides a green and viable route to preparing MXenes through an HF-free chemical approach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1024, "Times Cited, All Databases": 1083, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 141, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4730, "End Page": 4737, "Article Number": null, "DOI": "10.1021/jacs.9b00574", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00574", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462260400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, H; Song, C; Hong, YS; Kim, MS; Cho, HR; Kang, T; Shin, K; Choi, SH; Hyeon, T; Kim, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hyunjae; Song, Changyeong; Hong, Yong Seok; Kim, Min Sung; Cho, Hye Rim; Kang, Taegyu; Shin, Kwangsoo; Choi, Seung Hong; Hyeon, Taeghwan; Kim, Dae-Hyeong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable/disposable sweat-based glucose monitoring device with multistage transdermal drug delivery module", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical analysis of sweat using soft bioelectronics on human skin provides a new route for noninvasive glucose monitoring without painful blood collection. However, sweat-based glucose sensing still faces many challenges, such as difficulty in sweat collection, activity variation of glucose oxidase due to lactic acid secretion and ambient temperature changes, and delamination of the enzyme when exposed to mechanical friction and skin deformation. Precise point-of-care therapy in response to the measured glucose levels is still very challenging. We present a wearable/disposable sweat-based glucose monitoring device integrated with a feedback transdermal drug delivery module. Careful multilayer patch design and miniaturization of sensors increase the efficiency of the sweat collection and sensing process. Multimodal glucose sensing, as well as its real-time correction based on pH, temperature, and humidity measurements, maximizes the accuracy of the sensing. The minimal layout design of the same sensors also enables a strip-type disposable device. Drugs for the feedback transdermal therapy are loaded on two different temperature-responsive phase change nulloparticles. These nulloparticles are embedded in hyaluronic acid hydrogel microneedles, which are additionally coated with phase change materials. This enables multistage, spatially patterned, and precisely controlled drug release in response to the patient's glucose level. The system provides a novel closed-loop solution for the noninvasive sweat-based management of diabetes mellitus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 895, "Times Cited, All Databases": 971, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601314", "DOI": "10.1126/sciadv.1601314", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601314", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397044000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rost, CM; Sachet, E; Borman, T; Moballegh, A; Dickey, EC; Hou, D; Jones, JL; Curtarolo, S; Maria, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rost, Christina M.; Sachet, Edward; Borman, Trent; Moballegh, Ali; Dickey, Elizabeth C.; Hou, Dong; Jones, Jacob L.; Curtarolo, Stefano; Maria, Jon-Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy-stabilized oxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Configurational disorder can be compositionally engineered into mixed oxide by populating a single sublattice with many distinct cations. The formulations promote novel and entropy-stabilized forms of crystalline matter where metal cations are incorporated in new ways. Here, through rigorous experiments, a simple thermodynamic model, and a five-component oxide formulation, we demonstrate beyond reasonable doubt that entropy predominates the thermodynamic landscape, and drives a reversible solid-state transformation between a multiphase and single-phase state. In the latter, cation distributions are proven to be random and homogeneous. The findings validate the hypothesis that deliberate configurational disorder provides an orthogonal strategy to imagine and discover new phases of crystalline matter and untapped opportunities for property engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2203, "Times Cited, All Databases": 2351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8485, "DOI": "10.1038/ncomms9485", "DOI Link": "http://dx.doi.org/10.1038/ncomms9485", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363146400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZF; Huang, RK; Zheng, BN; Guo, WT; Li, CK; He, WY; Wei, YG; Du, Y; Wang, HM; Wu, DC; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zifeng; Huang, Rongkang; Zheng, Bingna; Guo, Wentai; Li, Chuangkun; He, Wenyi; Wei, Yingqi; Du, Yang; Wang, Huaiming; Wu, Dingcai; Wang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stretchable, Adhesive, Biocompatible, and Antibacterial Hydrogel Dressings for Wound Healing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Treatment of wounds in special areas is challenging due to inevitable movements and difficult fixation. Common cotton gauze suffers from incomplete joint surface coverage, confinement of joint movement, lack of antibacterial function, and frequent replacements. Hydrogels have been considered as good candidates for wound dressing because of their good flexibility and biocompatibility. Nevertheless, the adhesive, mechanical, and antibacterial properties of conventional hydrogels are not satisfactory. Herein, cationic polyelectrolyte brushes grafted from bacterial cellulose (BC) nullofibers are introduced into polydopamine/polyacrylamide hydrogels. The 1D polymer brushes have rigid BC backbones to enhance mechanical property of hydrogels, realizing high tensile strength (21-51 kPa), large tensile strain (899-1047%), and ideal compressive property. Positively charged quaternary ammonium groups of tethered polymer brushes provide long-lasting antibacterial property to hydrogels and promote crawling and proliferation of negatively charged epidermis cells. Moreover, the hydrogels are rich in catechol groups and capable of adhering to various surfaces, meeting adhesive demand of large movement for special areas. With the above merits, the hydrogels demonstrate less inflammatory response and faster healing speed for in vivo wound healing on rats. Therefore, the multifunctional hydrogels show stable covering, little displacement, long-lasting antibacteria, and fast wound healing, demonstrating promise in wound dressing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003627, "DOI": "10.1002/advs.202003627", "DOI Link": "http://dx.doi.org/10.1002/advs.202003627", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625411600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "null, HY; Wang, ZL; Wang, WH; Liang, Z; Lu, Y; Chen, Q; He, DW; Tan, PH; Miao, F; Wang, XR; Wang, JL; Ni, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "null, Haiyan; Wang, Zilu; Wang, Wenhui; Liang, Zheng; Lu, Yan; Chen, Qian; He, Daowei; Tan, Pingheng; Miao, Feng; Wang, Xinran; Wang, Jinlan; Ni, Zhenhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Photoluminescence Enhancement of MoS2 through Defect Engineering and Oxygen Bonding", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on a strong photoluminescence (PL) enhancement of monolayer MoS2 through defect engineering and oxygen bonding. Micro-PL and Raman images clearly reveal that the PL enhancement occurs at cracks/defects formed during high-temperature annealing. The PL enhancement at crack/defect sites could be as high as thousands of times after considering the laser spot size. The main reasons of such huge PL enhancement include the following: (1) the oxygen chemical adsorption induced heavy p doping and the conversion from trion to exciton; (2) the suppression of nonradiative recombination of excitons at defect sites, which was verified by low-temperature PL measurements. First-principle calculations reveal a strong binding energy of similar to 2.395 eV for an oxygen molecule adsorbed on a S vacancy of MoS2. The chemically adsorbed oxygen also provides a much more effective charge transfer (0.997 electrons per O-2) compared to physically adsorbed oxygen on an ideal MoS2 surface. We also demonstrate that the defect engineering and oxygen bonding could be easily realized by mild oxygen plasma irradiation. X-ray photoelectron spectroscopy further confirms the formation of Mo-O bonding. Our results provide a new route for modulating the optical properties of two-dimensional semiconductors. The strong and stable PL from defects sites of MoS2 may have promising applications in optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1041, "Times Cited, All Databases": 1132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5738, "End Page": 5745, "Article Number": null, "DOI": "10.1021/nn500532f", "DOI Link": "http://dx.doi.org/10.1021/nn500532f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338089200037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YZ; Lee, KH; Anjum, DH; Sougrat, R; Jiang, Q; Kim, H; Alshareefit, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yi-Zhou; Lee, Kang Hyuck; Anjum, Dalaver H.; Sougrat, Rachid; Jiang, Qiu; Kim, Hyunho; Alshareefit, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXenes stretch hydrogel sensor performance to new limits", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of wearable electronics, point-of-care testing, and soft robotics requires strain sensors that are highly sensitive, stretchable, capable of adhering conformably to arbitrary and complex surfaces, and preferably self-healable. Conductive hydrogels hold great promise as sensing materials for these applications. However, their sensitivities are generally low, and they suffer from signal hysteresis and fluctuation due to their viscoelastic property, which can compromise their sensing performance. We demonstrate that hydrogel composites incorporating MXene (Ti3C2Tx) outperform all reported hydrogels for strain sensors. The obtained composite hydrogel [MXene-based hydrogel (M-hydrogel)] exhibits outstanding tensile strain sensitivity with a gauge factor (GF) of 25, which is 10 times higher than that of pristine hydrogel. Furthermore, the M-hydrogel exhibits remarkable stretchability of more than 3400%, an instantaneous self-healing ability, excellent conformability, and adhesiveness to various surfaces, including human skin. The M-hydrogel composite exhibits much higher sensitivity under compressive strains (GF of 80) than under tensile strains. We exploit this asymmetrical strain sensitivity coupled with viscous deformation (self-recoverable residual deformation) to add new dimensions to the sensing capability of hydrogels. Consequently, both the direction and speed of motions on the hydrogel surface can be detected conveniently. Based on this effect, M-hydrogel demonstrates superior sensing performance in advanced sensing applications. Thus, the traditionally disadvantageous viscoelastic property of hydrogels can be transformed into an advantage for sensing, which reveals prospects for hydrogel sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 656, "Times Cited, All Databases": 686, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat0098", "DOI": "10.1126/sciadv.aat0098", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat0098", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, A; Hudson, AR; Shiwarski, DJ; Tashman, JW; Hinton, TJ; Yerneni, S; Bliley, JM; Campbell, PG; Feinberg, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, A.; Hudson, A. R.; Shiwarski, D. J.; Tashman, J. W.; Hinton, T. J.; Yerneni, S.; Bliley, J. M.; Campbell, P. G.; Feinberg, A. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D bioprinting of collagen to rebuild components of the human heart", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Collagen is the primary component of the extracellular matrix in the human body. It has proved challenging to fabricate collagen scaffolds capable of replicating the structure and function of tissues and organs. We present a method to 3D-bioprint collagen using freeform reversible embedding of suspended hydrogels (FRESH) to engineer components of the human heart at various scales, from capillaries to the full organ. Control of pH-driven gelation provides 20-micrometer filament resolution, a porous microstructure that enables rapid cellular infiltration and microvascularization, and mechanical strength for fabrication and perfusion of multiscale vasculature and tri-leaflet valves. We found that FRESH 3D-bioprinted hearts accurately reproduce patient-specific anatomical structure as determined by micro-computed tomography. Cardiac ventricles printed with human cardiomyocytes showed synchronized contractions, directional action potential propagation, and wall thickening up to 14% during peak systole.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1229, "Times Cited, All Databases": 1394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2019, "Volume": 365, "Issue": 6452, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 482, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav9051", "DOI Link": "http://dx.doi.org/10.1126/science.aav9051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485768400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schmidt, LC; Pertegás, A; González-Carrero, S; Malinkiewicz, O; Agouram, S; Espallargas, GM; Bolink, HJ; Galian, RE; Pérez-Prieto, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schmidt, Luciana C.; Pertegas, Antonio; Gonzalez-Carrero, Soranyel; Malinkiewicz, Olga; Agouram, Said; Minguez Espallargas, Guillermo; Bolink, Henk J.; Galian, Raquel E.; Perez-Prieto, Julia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nontemplate Synthesis of CH3NH3PbBr3 Perovskite nulloparticles", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date, there is no example in the literature of free, nullometer-sized, organolead halide CH3NH3PbBr3 perovskites. We report here the preparation of 6 nm-sized nulloparticles of this type by a simple and fast method based on the use of an ammonium bromide with a medium-sized chain that keeps the nulloparticles dispersed in a wide range of organic solvents. These nulloparticles can be maintained stable in the solid state as well as in concentrated solutions for more than three months, without requiring a mesoporous material. This makes it possible to prepare homogeneous thin films of these nulloparticles by spin-coating on a quartz substrate. Both the colloidal solution and the thin film emit light within a narrow bandwidth of the visible spectrum and with a high quantum yield (ca. 20%); this could be advantageous in the design of optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1116, "Times Cited, All Databases": 1217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2014, "Volume": 136, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 850, "End Page": 853, "Article Number": null, "DOI": "10.1021/ja4109209", "DOI Link": "http://dx.doi.org/10.1021/ja4109209", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330202300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Q; Lin, YX; Zhang, KY; Li, MJ; Tang, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Qian; Lin, Youxiu; Zhang, Kangyao; Li, Meijin; Tang, Dianping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced graphene oxide/BiFeO3 nullohybrids-based signal-on photoelectrochemical sensing system for prostate-specific antigen detection coupling with magnetic microfluidic device", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel magnetic controlled photoelectrochemical (PEC) sensing system was designed for sensitive detection of prostate-specific antigen (PSA) using reduced graphene oxide-functionalized BiFeO3 (rGO-BiFeO3) as the photoactive material and target-triggered hybridization chain reaction (HCR) for signal amplification. Remarkably enhanced PEC performance could be obtained by using rGO-BiFeO3 as the photoelectrode material due to its accelerated charge transfer and improved the visible light absorption. Additionally, efficient and simple operation could be achieved by introducing magnetic controlled flow-through device. The assay mainly involved in anchor DNA-conjugated magnetic bead (MB-aDNA), PSA aptamer/trigger DNA (Apt-tDNA) and two glucose oxidase-labeled hairpins (H1-GOx and H2-GOx). Upon addition of target PSA, the analyte initially reacted with the aptamer to release the trigger DNA, which partially hybridized with the anchor DNA on the MB. Thereafter, the unpaired trigger DNA on the MB opened the hairpin DNA structures in sequence and propagated a chain reaction of hybridization events between two alternating hairpins to form a long nicked double-helix with numerous GOx enzymes on it. Subsequently, the enzymatic product (H2O2) generated and consumed the photo excited electrons from rGO-BiFeO3 under visible light irradiation to enhance the photocurrent. Under optimal conditions, the magnetic controlled PEC sensing system exhibited good photocurrent responses toward target PSA within the linear range of 0.001 - 100 ng/mL with a detection limit of 0.31 pg/mL. Moreover, favorable selectivity, good stability and satisfactory accuracy were obtained. The excellent analytical performance suggested that the rGO-BiFeO3-based PEC sensing platform could be a promising tool for sensitive, efficient and low cost detection of PSA in disease diagnostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 101, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 146, "End Page": 152, "Article Number": null, "DOI": "10.1016/j.bios.2017.10.027", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2017.10.027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418982600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pelaz, B; Alexiou, CH; Alvarez -Puebla, RA; Alves, F; Andrews, AM; Ashraf, S; Balogh, LP; Ballerini, L; Bestetti, A; Brendel, C; Bosi, S; Carril, M; Chan, WCW; Chen, CY; Chen, XD; Chen, XY; Cheng, Z; Cui, DX; Du, JZ; Dullin, C; Escudero, A; Feliu, N; Gao, MY; George, M; Gogotsi, Y; Grünweller, A; Gu, ZW; Halas, NJ; Hampp, N; Hartmann, RK; Hersam, MC; Hunziker, P; Jian, J; Jiang, XY; Jungebluth, P; Kadhiresan, P; Kataoka, K; Khademhosseini, A; Kopecek, J; Kotov, NA; Krug, HF; Lee, DS; Lehr, CM; Leong, KW; Liang, XJ; Lim, ML; Liz-Marzán, LM; Ma, XM; Macchiarini, P; Meng, H; Möhwald, H; Mulvaney, P; Nel, AE; Nie, SM; Nordlander, P; Okano, T; Oliveira, J; Park, TH; Penner, RM; Prato, M; Puntes, V; Rotello, VM; Samarakoon, A; Schaak, RE; Shen, YQ; Sjöqvist, S; Skirtach, AG; Soliman, MG; Stevens, MM; Sung, HW; Tang, BZ; Tietze, R; Udugama, BN; VanEpps, JS; Weil, T; Weiss, PS; Willner, I; Wu, YZ; Yang, LL; Yue, Z; Zhang, Q; Zhang, Q; Zhang, XE; Zhao, YL; Zhou, X; Parak, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pelaz, Beatriz; Alexiou, Christoph; Alvarez -Puebla, Ramon A.; Alves, Frauke; Andrews, Anne M.; Ashraf, Sumaira; Balogh, Lajos P.; Ballerini, Laura; Bestetti, Alessandra; Brendel, Cornelia; Bosi, Susanna; Carril, Monica; Chan, Warren C. W.; Chen, Chunying; Chen, Xiaodong; Chen, Xiaoyuan; Cheng, Zhen; Cui, Daxiang; Du, Jianzhong; Dullin, Christian; Escudero, Alberto; Feliu, Neus; Gao, Mingyuan; George, Michael; Gogotsi, Yury; Grunweller, Arnold; Gu, Zhongwei; Halas, Naomi J.; Hampp, Norbert; Hartmann, Roland K.; Hersam, Mark C.; Hunziker, Patrick; Jian, Ji; Jiang, Xingyu; Jungebluth, Philipp; Kadhiresan, Pranav; Kataoka, Kazunori; Khademhosseini, Ali; Kopecek, Jindirich; Kotov, Nicholas A.; Krug, Harald F.; Lee, Dong Soo; Lehr, Claus-Michael; Leong, Kam W.; Liang, Xing-Jie; Lim, Mei Ling; Liz-Marzan, Luis M.; Ma, Xiaowei; Macchiarini, Paolo; Meng, Huan; Mohwald, Helmuth; Mulvaney, Paul; Nel, Andre E.; Nie, Shuming; Nordlander, Peter; Okano, Teruo; Oliveira, Jose; Park, Tai Hyun; Penner, Reginald M.; Prato, Maurizio; Puntes, Victor; Rotello, Vincent M.; Samarakoon, Amila; Schaak, Raymond E.; Shen, Youqing; Sjoqvist, Sebastian; Skirtach, Andre G.; Soliman, Mahmoud G.; Stevens, Molly M.; Sung, Hsing-Wen; Tang, Ben Zhong; Tietze, Rainer; Udugama, Buddhisha N.; VanEpps, J. Scott; Weil, Tanja; Weiss, Paul S.; Willner, Itamar; Wu, Yuzhou; Yang, Lily; Yue, Zhao; Zhang, Qian; Zhang, Qiang; Zhang, Xian-En; Zhao, Yuliang; Zhou, Xin; Parak, Wolfgang J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diverse Applications of nullomedicine", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and use of materials in the nulloscale size range for addressing medical and health-related issues continues to receive increasing interest. Research in nullomedicine spans a multitude of areas, including drug delivery, vaccine development, antibacterial, diagnosis and imaging tools, wearable devices, implants, high-throughput screening platforms, etc. using biological, nonbiological, biomimetic, or hybrid materials. Many of these developments are starting to be translated into viable clinical products. Here, we provide an overview of recent developments in nullomedicine and highlight the current challenges and upcoming opportunities for the field and translation to the clinic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 964, "Times Cited, All Databases": 1039, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2313, "End Page": 2381, "Article Number": null, "DOI": "10.1021/acsnullo.6b06040", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b06040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398014900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JH; Wang, Z; Hou, MY; Dong, XL; Liu, Y; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jianhang; Wang, Zhuo; Hou, Mengyan; Dong, Xiaoli; Liu, Yao; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyaniline-intercalated manganese dioxide nullolayers as a high-performance cathode material for an aqueous zinc-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable zinc-manganese dioxide batteries that use mild aqueous electrolytes are attracting extensive attention due to high energy density and environmental friendliness. Unfortunately, manganese dioxide suffers from substantial phase changes (e.g., from initial alpha-, beta-, or gamma-phase to a layered structure and subsequent structural collapse) during cycling, leading to very poor stability at high charge/discharge depth. Herein, cyclability is improved by the design of a polyaniline-intercalated layered manganese dioxide, in which the polymerstrengthened layered structure and nulloscale size of manganese dioxide serves to eliminate phase changes and facilitate charge storage. Accordingly, an unprecedented stability of 200 cycles with at a high capacity of 280 mA h g(-1) (i.e., 90% utilization of the theoretical capacity of manganese dioxide) is achieved, as well as a long-term stability of 5000 cycles at a utilization of 40%. The encouraging performance sheds light on the design of advanced cathodes for aqueous zinc-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1198, "Times Cited, All Databases": 1253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2906, "DOI": "10.1038/s41467-018-04949-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04949-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439687600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Fu, RZ; Duan, ZG; Zhu, CH; Fan, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yang; Fu, Rongzhan; Duan, Zhiguang; Zhu, Chenhui; Fan, Daidi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of multifunctional hydrogel based on the tannic acid-metal coating decorated MoS2 dual nullozyme for bacteria-infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial infection, tissue hypoxia and inflammatory response can hinder the infected wound repair process. To mitigate the above issues, tannic acid-chelated Fe-decorated molybdenum disulfide nullosheets (MoS2@TA/Fe NSs) with dual enzyme activities were developed and anchored to a multifunctional hydrogel. The hydrogel exhibited excellent antibacterial ability owing to the combined effects of photothermal therapy (PTT), glutathione (GSH) loss, and the peroxidase (POD)-like activity (catalyse H2O2 into center dot OH under acid condition) of MoS2@TA/Fe NSs. Benefitting from the catalase (CAT)-like activity, the hydrogel could decompose H2O2 into O-2 at neutral pH to relieve hypoxia and supply adequate O-2. POD-like activity was mainly attributed to MoS2 NSs, while CAT-like activity was primarily due to TA/Fe complex. Moreover, MoS2@TA/Fe NSs endowed the hydrogel with outstanding anti-oxidant ability to scavenge redundant reactive oxygen species (ROS) and reactive nitrogen species (RNS) under neutral environment to maintain the balance of antioxidant systems and prevent inflammation. In addition, the hydrogel could inhibit the release of inflammatory factors for the anti-inflammatory property of TA. TA retained partial phenolic hydroxyl groups, which cross-linked the nullosheets to the network structure of the hydrogel and promoted the adhesion of hydrogels. Due to the dynamic boron ester bonds between polyvinyl alcohol (PVA), dextran (Dex), MoS2@TA/Fe, and borax, the hydrogel demonstrated fast self-healing and rapid shape adaptability. This shape-adaptable adhesive hydrogel could fill the whole wound and closely contact the wound, ensuring that it achieved its functions with maximum efficiency. The MoS2@TA/Fe nullozyme-anchored multifunctional hydrogel showed high potential for bacteria-infected wound healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 461, "End Page": 474, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.07.023", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.07.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000736275600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TY; Kim, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tingyi Leo; Kim, Chang-Jin CJ", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Turning a surface superrepellent even to completely wetting liquids", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superhydrophobic and superoleophobic surfaces have so far been made by roughening a hydrophobic material. However, no surfaces were able to repel extremely-low-energy liquids such as fluorinated solvents, which completely wet even the most hydrophobic material. We show how roughness alone, if made of a specific doubly reentrant structure that enables very low liquid-solid contact fraction, can render the surface of any material superrepellent. Starting from a completely wettable material (silica), we micro-and nullostructure its surface to make it superomniphobic and bounce off all available liquids, including perfluorohexane. The same superomniphobicity is further confirmed with identical surfaces of a metal and a polymer. Free of any hydrophobic coating, the superomniphobic silica surface also withstands temperatures over 1000 degrees C and resists biofouling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 929, "Times Cited, All Databases": 1009, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2014, "Volume": 346, "Issue": 6213, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1096, "End Page": 1100, "Article Number": null, "DOI": "10.1126/science.1254787", "DOI Link": "http://dx.doi.org/10.1126/science.1254787", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345763400038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, HC; Xu, DK; Du, CW; Zhang, DW; Li, XG; Huang, LY; Deng, LP; Tu, YC; Mol, JMC; Terryn, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Hongchang; Xu, Dake; Du, Cuiwei; Zhang, Dawei; Li, Xiaogang; Huang, Luyao; Deng, Leping; Tu, Yunchao; Mol, Johannes M. C.; Terryn, Herman A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work introduces a new self-healing superhydrophobic coating based on dual actions by the corrosion inhibitor benzotriazole (BTA) and an epoxy-based shape memory polymer (SMP). Damage to the surface morphology (e.g., crushed areas and scratches) and the corresponding superhydrophobicity are shown to be rapidly healed through a simple heat treatment at 60 degrees C for 20 min. Electrochemical impedance spectroscopy (EIS) and scanning electrochemical microscopy (SECM) were used to study the anti-corrosion performance of the scratched and the healed superhydrophobic coatings immersed in a 3.5 wt% NaCl solution. The results revealed that the anticorrosion performance of the scratched coatings was improved upon the incorporation of BTA. After the heat treatment, the scratched superhydrophobic coatings exhibited excellent recovery of their anti-corrosion performance, which is attributed to the closure of the scratch by the shape memory effect and to the improved inhibition efficiency of BTA. Furthermore, we found that the pre-existing corrosion product inside the coating scratch could hinder the scratch closure by the shape memory effect and reduce the coating adhesion in the scratched region. However, the addition of BTA effectively suppressed the formation of corrosion products and enhanced the self-healing and adhesion performance under these conditions. Importantly, we also demonstrated that these coatings can be autonomously healed within 1 h in an outdoor environment using sunlight as the heat source.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 433, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2017, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2355, "End Page": 2364, "Article Number": null, "DOI": "10.1039/c6ta10903a", "DOI Link": "http://dx.doi.org/10.1039/c6ta10903a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395074300062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, T; Zhao, YL; Tong, Y; Jiao, ZB; Wei, J; Cai, JX; Han, XD; Chen, D; Hu, A; Kai, JJ; Lu, K; Liu, Y; Liu, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, T.; Zhao, Y. L.; Tong, Y.; Jiao, Z. B.; Wei, J.; Cai, J. X.; Han, X. D.; Chen, D.; Hu, A.; Kai, J. J.; Lu, K.; Liu, Y.; Liu, C. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicomponent intermetallic nulloparticles and superb mechanical behaviors of complex alloys", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alloy design based on single-principal-element systems has approached its limit for performance enhancements. A substantial increase in strength up to gigapascal levels typically causes the premature failure of materials with reduced ductility. Here, we report a strategy to break this trade-off by controllably introducing high-density ductile multicomponent intermetallic nulloparticles (MCINPs) in complex alloy systems. Distinct from the intermetallic-induced embrittlement under conventional wisdom, such MCINP-strengthened alloys exhibit superior strengths of 1.5 gigapascals and ductility as high as 50% in tension at ambient temperature. The plastic instability, a major concern for high-strength materials, can be completely eliminated by generating a distinctive multistage work-hardening behavior, resulting from pronounced dislocation activities and deformation-induced microbands. This MCINP strategy offers a paradigm to develop next-generation materials for structural applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1151, "Times Cited, All Databases": 1205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2018, "Volume": 362, "Issue": 6417, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 933, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aas8815", "DOI Link": "http://dx.doi.org/10.1126/science.aas8815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451124500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, YH; Koelewijn, SF; Van den Bossche, G; Van Aelst, J; Van den Bosch, S; Renders, T; Navare, K; Nicolai, T; Van Aelst, K; Maesen, M; Matsushima, H; Thevelein, JM; Van Acker, K; Lagrain, B; Verboekend, D; Sels, BF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Yuhe; Koelewijn, Steven-Friso; Van den Bossche, Gil; Van Aelst, Joost; Van den Bosch, Sander; Renders, Tom; Navare, Kranti; Nicolai, Thomas; Van Aelst, Korneel; Maesen, Maarten; Matsushima, Hironori; Thevelein, Johan M.; Van Acker, Karel; Lagrain, Bert; Verboekend, Danny; Sels, Bert F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A sustainable wood biorefinery for low-carbon footprint chemicals production", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The profitability and sustainability of future biorefineries are dependent on efficient feedstock use. Therefore, it is essential to valorize lignin when using wood. We have developed an integrated biorefinery that converts 78 weight % (wt %) of birch into xylochemicals. Reductive catalytic fractionation of the wood produces a carbohydrate pulp amenable to bioethanol production and a lignin oil. After extraction of the lignin oil, the crude, unseparated mixture of phenolic monomers is catalytically funneled into 20 wt % of phenol and 9 wt % of propylene (on the basis of lignin weight) by gas-phase hydroprocessing and dealkylation; the residual phenolic oligomers (30 wt %) are used in printing ink as replacements for controversial para-nonylphenol. A techno-economic analysis predicts an economically competitive production process, and a life-cycle assessment estimates a lower carbon dioxide footprint relative to that of fossil-based production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 745, "Times Cited, All Databases": 772, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 367, "Issue": 6484, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1385, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau1567", "DOI Link": "http://dx.doi.org/10.1126/science.aau1567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522167400054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, L; Wang, T; Zhang, HB; Chang, K; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Li; Wang, Tao; Zhang, Huabin; Chang, Kun; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatic Self-Assembly of nullosized Carbon Nitride nullosheet onto a Zirconium Metal-Organic Framework for Enhanced Photocatalytic CO2 Reduction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "UiO-66, a zirconium based metal-organic framework, is incorporated with nullosized carbon nitride nullosheets via a facile electrostatic self-assembly method. This hybrid structure exhibits a large surface area and strong CO2 capture ability due to the introduction of UiO-66. We demonstrate that electrons from the photoexcited carbon nitride nullosheet can transfer to UiO-66, which can substantially suppress electron-hole pair recombination in the carbon nitride nullosheet, as well as supply long-lived electrons for the reduction of CO2 molecules that are adsorbed in UiO-66. As a result, the UiO-66/carbon nitride nullosheet heterogeneous photocatalyst exhibits a much higher photocatalytic activity for the CO2 conversion than that of bare carbon nitride nullosheets. We believe this self-assembly method can be extended to other carbon nitride nullosheet loaded materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2015, "Volume": 25, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5360, "End Page": 5367, "Article Number": null, "DOI": "10.1002/adfm.201502253", "DOI Link": "http://dx.doi.org/10.1002/adfm.201502253", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360724600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Roo, J; Ibáñez, M; Geiregat, P; Nedelcu, G; Walravens, W; Maes, J; Martins, JC; Van Driessche, I; Koyalenko, MV; Hens, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Roo, Jonathan; Ibanez, Maria; Geiregat, Pieter; Nedelcu, Georgian; Walravens, Willem; Maes, Jorick; Martins, Jose C.; Van Driessche, Isabel; Koyalenko, Maksym V.; Hens, Zeger", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite nullocrystals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite materials have attracted significant attention in the context of photovoltaics and other optoelectronic applications, and recently, research efforts have been directed to nullostructured lead halide perovskites. Collodial nullocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit bright photoluminescence, with emission tunable over the entire visible spectral region. However, previous studies on CsPbX3 NCs did not address key aspects of their chemistry and photophysics such as surface chemistry and quantitative light absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface chemistry. In addition, the intrinsic absorption coefficient was determined experimentally by combining elemental analysis with accurate optical absorption measurements. H-1 solution nuclear magnetic resonullce spectroscopy was used to characterize sample purity, elucidate the surface chemistry, and evaluate the influence of purification methods on the surface composition. We find that ligand binding to the NC surface is highly dynamic, and therefore, ligands are easily lost during the isolation and purification procedures. However, when a small amount of both oleic acid and oleylamine is added, the NCs can be purified, maintaining optical, colloidal, and material integrity. In addition, we find that a high amine content in the ligand shell increases the quantum yield due to the improved binding of the carboxylic acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1547, "Times Cited, All Databases": 1636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2071, "End Page": 2081, "Article Number": null, "DOI": "10.1021/acsnullo.5b06295", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b06295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370987400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, YJ; Lei, SD; Ye, GL; Li, B; He, YM; Keyshar, K; Zhang, X; Wang, QZ; Lou, J; Liu, Z; Vajtai, R; Zhou, W; Ajayan, PM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Yongji; Lei, Sidong; Ye, Gonglan; Li, Bo; He, Yongmin; Keyshar, Kunttal; Zhang, Xiang; Wang, Qizhong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pulickel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Step Growth of Two-Dimensional WSe2/MoSe2 Heterostructures", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, this two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 mu m) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. A photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 15, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6135, "End Page": 6141, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b02423", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b02423", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361252700073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YC; Zhou, T; Jiang, K; Da, PM; Peng, Z; Tang, J; Kong, BA; Cai, WB; Yang, ZQ; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yongcheng; Zhou, Tong; Jiang, Kun; Da, Peimei; Peng, Zheng; Tang, Jing; Kong, Biao; Cai, Wen-Bin; Yang, Zhongqin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced Mesoporous Co3O4 nullowires as Efficient Water Oxidation Electrocatalysts and Supercapacitor Electrodes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While electrochemical water splitting is one of the most promising methods to store light/electrical energy in chemical bonds, a key challenge remains in the realization of an efficient oxygen evolution reaction catalyst with large surface area, good electrical conductivity, high catalytic properties, and low fabrication cost. Here, a facile solution reduction method is demonstrated for mesoporous Co3O4 nullowires treated with NaBH4. The high-surface-area mesopore feature leads to efficient surface reduction in solution at room temperature, which allows for retention of the nullowire morphology and 1D charge transport behavior, while at the same time substantially increasing the oxygen vacancies on the nullowire surface. Compared to pristine Co3O4 nullowires, the reduced Co3O4 nullowires exhibit a much larger current of 13.1 mA cm(-2) at 1.65 V vs reversible hydrogen electrode (RHE) and a much lower onset potential of 1.52 V vs RHE. Electrochemical supercapacitors based on the reduced Co3O4 nullowires also show a much improved capacitance of 978 F g(-1) and reduced charge transfer resistance. Density-functional theory calculations reveal that the existence of oxygen vacancies leads to the formation of new gap states in which the electrons previously associated with the Co-O bonds tend to be delocalized, resulting in the much higher electrical conductivity and electrocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 635, "Times Cited, All Databases": 644, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2014, "Volume": 4, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1400696, "DOI": "10.1002/aenm.201400696", "DOI Link": "http://dx.doi.org/10.1002/aenm.201400696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345314800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DD; Wu, HH; Lim, WQ; Phua, SZF; Xu, PP; Chen, QW; Guo, Z; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongdong; Wu, Huihui; Lim, Wei Qi; Phua, Soo Zeng Fiona; Xu, Pengping; Chen, Qianwang; Guo, Zhen; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Mesoporous nulloenzyme Derived from Metal-Organic Frameworks with Endogenous Oxygen Generation to Alleviate Tumor Hypoxia for Significantly Enhanced Photodynamic Therapy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tumor hypoxia compromises the therapeutic efficiency of photodynamic therapy (PDT) as the local oxygen concentration plays an important role in the generation of cytotoxic singlet oxygen (O-1(2)). Herein, a versatile mesoporous nulloenzyme (NE) derived from metal-organic frameworks (MOFs) is presented for in situ generation of endogenous O-2 to enhance the PDT efficacy under bioimaging guidance. The mesoporous NE is constructed by first coating a manganese-based MOFs with mesoporous silica, followed by a facile annealing process under the ambient atmosphere. After removing the mesoporous silica shell and post-modifying with polydopamine and poly(ethylene glycol) for improving the biocompatibility, the obtained mesoporous NE is loaded with chlorin e6 (Ce6), a commonly used photosensitizer in PDT, with a high loading capacity. Upon the O-2 generation through the catalytic reaction between the catalytic amount NE and the endogenous H2O2, the hypoxic tumor microenvironment is relieved. Thus, Ce6-loaded NE serves as a H2O2-activated oxygen supplier to increase the local O-2 concentration for significantly enhanced antitumor PDT efficacy in vitro and in vivo. In addition, the NE also shows T-2-weighted magnetic resonullce imaging ability for its in vivo tracking. This work presents an interesting biomedical use of MOF-derived mesoporous NE as a multifunctional theranostic agent in cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 31, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901893, "DOI": "10.1002/adma.201901893", "DOI Link": "http://dx.doi.org/10.1002/adma.201901893", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477981200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, DHS; Chen, YT; Yang, HD; Bao, W; Sreenarayanull, B; Doux, JM; Li, WK; Lu, BY; Ham, SY; Sayahpour, B; Scharf, J; Wu, EA; Deysher, G; Han, HE; Hah, HJ; Jeong, H; Lee, JB; Chen, Z; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi; Bao, Wurigumula; Sreenarayanull, Bhagath; Doux, Jean-Marie; Li, Weikang; Lu, Bingyu; Ham, So-Yeon; Sayahpour, Baharak; Scharf, Jonathan; Wu, Erik A.; Deysher, Grayson; Han, Hyea Eun; Hah, Hoe Jin; Jeong, Hyeri; Lee, Jeong Beom; Chen, Zheng; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of silicon anodes for lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, we enabled the stable operation of a 99.9 weight % microsilicon anode by using the interface passivating properties of sulfide solid electrolytes. Bulk and surface characterization, and quantification of interfacial components, showed that such an approach eliminates continuous interfacial growth and irreversible lithium losses. Microsilicon full cells were assembled and found to achieve high areal current density, wide operating temperature range, and high areal loadings for the different cells. The promising performance can be attributed to both the desirable interfacial property between microsilicon and sulfide electrolytes and the distinctive chemomechanical behavior of the lithium-silicon alloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 592, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2021, "Volume": 373, "Issue": 6562, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1494, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg7217", "DOI Link": "http://dx.doi.org/10.1126/science.abg7217", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698977800047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Diercks, CS; Lin, S; Komienko, N; Kapustin, EA; Nichols, EM; Zhu, CH; Zhao, YB; Chang, CJ; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Diercks, Christian S.; Lin, Song; Komienko, Nikolay; Kapustin, Eugene A.; Nichols, Eva M.; Zhu, Chenhui; Zhao, Yingbo; Chang, Christopher J.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for Electrocatalytic Carbon Dioxide Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic character of porphyrin active sites for electrocatalytic reduction of CO2 to CO in a two-dimensional covalent organic framework (COF) was tuned by modification of the reticular structure.-Efficient charge transport along the COF backbone promotes electronic, connectivity between remote functional groups and the active sites, and-enables the modulation of the catalytic properties of the system. A series of oriented: thin :films of-these COFs was found to reduce CO2 to CO at low overpotential (550 mV) with high selectivity (fatadaic efficiency of 87%) and at high. current densities (65 mA/mg), a performance well beyond related molecular catalysts in regard to selectivity and efficiency. The catalysts are stable for more than 12 h without any loss in reactivity. X-ray absorption measurements on the cobalt L-edge for the modified COFs enable correlations between the inductive effects of the appended functionality and the electronic character of the reticulated molecular active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 495, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2018, "Volume": 140, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1116, "End Page": 1122, "Article Number": null, "DOI": "10.1021/jacs.7b11940", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b11940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423496700040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Zhu, XR; Wen, XJ; Zhou, YY; Zhou, L; Li, H; Tao, L; Li, QL; Du, SQ; Liu, TT; Yan, DF; Xie, C; Zou, YQ; Wang, YY; Chen, R; Huo, J; Li, YF; Cheng, J; Su, H; Zhao, X; Cheng, WR; Liu, QH; Lin, HZ; Luo, J; Chen, J; Dong, MD; Cheng, K; Li, CG; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chen; Zhu, Xiaorong; Wen, Xiaojian; Zhou, Yangyang; Zhou, Ling; Li, Hao; Tao, Li; Li, Qiling; Du, Shiqian; Liu, Tingting; Yan, Dafeng; Xie, Chao; Zou, Yuqin; Wang, Yanyong; Chen, Ru; Huo, Jia; Li, Yafei; Cheng, Jun; Su, Hui; Zhao, Xu; Cheng, Weiren; Liu, Qinghua; Lin, Hongzhen; Luo, Jun; Chen, Jun; Dong, Mingdong; Cheng, Kai; Li, Conggang; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of nitrogen fertilizers has been estimated to have supported 27% of the world's population over the past century. Urea (CO(NH2)(2)) is conventionally synthesized through two consecutive industrial processes, N-2 + H-2 -> NH(3)followed by NH3 + CO2 -> urea. Both reactions operate under harsh conditions and consume more than 2% of the world's energy. Urea synthesis consumes approximately 80% of the NH(3)produced globally. Here we directly coupled N(2)and CO(2)in H2O to produce urea under ambient conditions. The process was carried out using an electrocatalyst consisting of PdCu alloy nulloparticles on TiO(2)nullosheets. This coupling reaction occurs through the formation of C-N bonds via the thermodynamically spontaneous reaction between *N=N* and CO. Products were identified and quantified using isotope labelling and the mechanism investigated using isotope-labelled operando synchrotron-radiation Fourier transform infrared spectroscopy. A high rate of urea formation of 3.36 mmol g(-1) h(-1) and corresponding Faradic efficiency of 8.92% were measured at -0.4 V versus reversible hydrogen electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 676, "Times Cited, All Databases": 706, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41557-020-0481-9", "DOI Link": "http://dx.doi.org/10.1038/s41557-020-0481-9", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540397300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seyedin, S; Uzun, S; Levitt, A; Anasori, B; Dion, G; Gogotsi, Y; Razal, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seyedin, Shayan; Uzun, Simge; Levitt, Ariana; Anasori, Babak; Dion, Genevieve; Gogotsi, Yury; Razal, Joselito M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene Composite and Coaxial Fibers with High Stretchability and Conductivity for Wearable Strain Sensing Textiles", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of nullomaterials with high conductivity into stretchable polymer fibers can achieve novel functionalities such as sensing physical deformations. With a metallic conductivity that exceeds other solution-processed nullomaterials, 2D titanium carbide MXene is an attractive material to produce conducting and stretchable fibers. Here, a scalable wet-spinning technique is used to produce Ti3C2Tx MXene/polyurethane (PU) composite fibers that show both conductivity and high stretchability. The conductivity at a very low percolation threshold of approximate to 1 wt% is demonstrated, which is lower than the previously reported values for MXene-based polymer composites. When used as a strain sensor, the MXene/PU composite fibers show a high gauge factor of approximate to 12900 (approximate to 238 at 50% strain) and a large sensing strain of approximate to 152%. The cyclic strain sensing performance is further improved by producing fibers with MXene/PU sheath and pure PU core using a coaxial wet-spinning process. Using a commercial-scale knitting machine, MXene/PU fibers are knitted into a one-piece elbow sleeve, which can track various movements of the wearer's elbow. This study establishes fundamental insights into the behavior of MXene in elastomeric composites and presents strategies to achieve MXene-based fibers and textiles with strain sensing properties suitable for applications in health, sports, and entertainment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 30, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1910504, "DOI": "10.1002/adfm.201910504", "DOI Link": "http://dx.doi.org/10.1002/adfm.201910504", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511521300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, ST; Yuk, H; Zhang, T; Parada, GA; Koo, H; Yu, CJ; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Shaoting; Yuk, Hyunwoo; Zhang, Teng; Parada, German Alberto; Koo, Hyunwoo; Yu, Cunjiang; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable Hydrogel Electronics and Devices", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable hydrogel electronics and devices are designed by integrating stretchable conductors, functional chips, drug-delivery channels, and reservoirs into stretchable, robust, and biocompatible hydrogel matrices. Novel applications include a smart wound dressing capable of sensing the temperatures of various locations on the skin, delivering different drugs to these locations, and subsequently maintaining sustained release of drugs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 586, "Times Cited, All Databases": 638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2016, "Volume": 28, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 4497, "End Page": 4505, "Article Number": null, "DOI": "10.1002/adma.201504152", "DOI Link": "http://dx.doi.org/10.1002/adma.201504152", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377123500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CG; Wang, M; Xu, TZ; Zhang, XX; Lin, C; Gao, WY; Xu, HZ; Lei, B; Mao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenggui; Wang, Min; Xu, Tianzhen; Zhang, Xingxing; Lin, Cai; Gao, Weiyang; Xu, Huazi; Lei, Bo; Mao, Cong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Bioactive Self-Healing Antibacterial Exosomes Hydrogel for Promoting Chronic Diabetic Wound Healing and Complete Skin Regeneration", "Source Title": "THERANOSTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rationale: Chronic nonhealing diabetic wound therapy and complete skin regeneration remains a critical clinical challenge. The controlled release of bioactive factors from a multifunctional hydrogel was a promising strategy to repair chronic wounds. Methods: Herein, for the first time, we developed an injectable, self-healing and antibacterial polypeptide-based FHE hydrogel (F127/OHA-EPL) with stimuli-responsive adipose-derived mesenchymal stem cells exosomes (AMSCs-exo) release for synergistically enhancing chronic wound healing and complete skin regeneration. The materials characterization, antibacterial activity, stimulated cellular behavior and in vivo full-thickness diabetic wound healing ability of the hydrogels were performed and analyzed. Results: The FHE hydrogel possessed multifunctional properties including fast self-healing process, shear-thinning injectable ability, efficient antibacterial activity, and long term pH-responsive bioactive exosomes release behavior. In vitro, the FHE@exosomes (FHE@exo) hydrogel significantly promoted the proliferation, migration and tube formation ability of human umbilical vein endothelial cells (HUVECs). In vivo, the FHE@exo hydrogel significantly enhanced the healing efficiency of diabetic full-thickness cutaneous wounds, characterized with enhanced wound closure rates, fast angiogenesis, re-epithelization and collagen deposition within the wound site. Moreover, the FHE@exo hydrogel displayed better healing outcomes than those of exosomes or FHE hydrogel alone, suggesting that the sustained release of exosomes and FHE hydrogel can synergistically facilitate diabetic wound healing. Skin appendages and less scar tissue also appeared in FHE@exo hydrogel treated wounds, indicating its potent ability to achieve complete skin regeneration. Conclusion: This work offers a new approach for repairing chronic wounds completely through a multifunctional hydrogel with controlled exosomes release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 648, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 76, "Article Number": null, "DOI": "10.7150/thno.29766", "DOI Link": "http://dx.doi.org/10.7150/thno.29766", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452508600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, FP; Liu, YP; Ben Hammouda, S; Doshi, B; Guijarro, N; Min, XB; Tang, CJ; Sillanpää, M; Sivula, K; Wang, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Feiping; Liu, Yongpeng; Ben Hammouda, Samia; Doshi, Bhairavi; Guijarro, Nestor; Min, Xiaobo; Tang, Chong-Jian; Sillanpaa, Mika; Sivula, Kevin; Wang, Shaobin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MIL-101(Fe)/g-C3N4 for enhanced visible-light-driven photocatalysis toward simultaneous reduction of Cr(VI) and oxidation of bisphenol A in aqueous media", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterostructured composites with an excellent photocatalytic activity have attracted increasing attention because of their great application in environmental remediation. Herein, a MIL-101(Fe)/g-C3N4 heterojunction was synthesized via in-situ growth of MIL-101(Fe) onto g-C3N4 surface. The heterojunctions were applied as a bifunctional photocatalyst for simultaneous reduction of Cr(VI) and degradation of bisphenol-A (BPA) under visible light and exhibited an obvious enhancement in photocatalytic performance compared with MIL-101(Fe) or g-C3N4. The improved activity could be attributed to the enhanced light absorption and efficient charge carrier separation by forming a direct Z-scheme heterojunction with appropriate band alignment between MIL-101(Fe) and g-C3N4. The radical trapping and electron spin resonullce showed that photo-generated electrons are responsible for the reduction of Cr(VI) and BPA degradation, following an oxygen-induced pathway. This work provides new insight into the construction of metal-free semiconductor/MOFs heterojunctions as a bifunctional visible-light-driven photocatalyst for efficient and simultaneous treatment of multiple toxic pollutants in water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2020, "Volume": 272, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119033, "DOI": "10.1016/j.apcatb.2020.119033", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533148700038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YJ; Guan, BY; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yongjin; Guan, Bu Yuan; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of CuS@CoS2 Double-Shelled nulloboxes with Enhanced Sodium Storage Properties", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal sulfides have received considerable attention for efficient sodium storage owing to their high capacity and decent redox reversibility. However, the poor rate capability and fast capacity decay greatly hinder their practical application in sodium-ion batteries. Herein, an elegant multi-step templating strategy has been developed to rationally synthesize hierarchical double-shelled nulloboxes with the CoS2 nullosheet-constructed outer shell supported on the CuS inner shell. Their structure and composition enable these hierarchical CuS@CoS2 nulloboxes to show boosted electrochemical properties with high capacity, outstanding rate capability, and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2019, "Volume": 58, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7739, "End Page": 7743, "Article Number": null, "DOI": "10.1002/anie.201902583", "DOI Link": "http://dx.doi.org/10.1002/anie.201902583", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474804800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CP; Yin, YX; Zhang, SF; Li, NW; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng; Li, Nian-Wu; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is one of the most attractive anode materials for electrochemical energy storage. However, the growth of Li dendrites during electrochemical deposition, which leads to a low Coulombic efficiency and safety concerns, has long hindered the application of rechargeable Li-metal batteries. Here we show that a 3D current collector with a submicron skeleton and high electroactive surface area can significantly improve the electrochemical deposition behaviour of Li. Li anode is accommodated in the 3D structure without uncontrollable Li dendrites. With the growth of Li dendrites being effectively suppressed, the Li anode in the 3D current collector can run for 600 h without short circuit and exhibits low voltage hysteresis. The exceptional electrochemical performance of the Li-metal anode in the 3D current collector highlights the importance of rational design of current collectors and reveals a new avenue for developing Li anodes with a long lifespan.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1180, "Times Cited, All Databases": 1209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8058, "DOI": "10.1038/ncomms9058", "DOI Link": "http://dx.doi.org/10.1038/ncomms9058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360352600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Ashouri, A; Köhnen, E; Li, B; Magomedov, A; Hempel, H; Caprioglio, P; Márquez, JA; Vilches, ABM; Kasparavicius, E; Smith, JA; Phung, N; Menzel, D; Grischek, M; Kegelmann, L; Skroblin, D; Gollwitzer, C; Malinauskas, T; Jost, M; Matic, G; Rech, B; Schlatmann, R; Topic, M; Korte, L; Abate, A; Stannowski, B; Neher, D; Stolterfoht, M; Unold, T; Getautis, V; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Ashouri, Amran; Kohnen, Eike; Li, Bor; Magomedov, Artiom; Hempel, Hannes; Caprioglio, Pietro; Marquez, Jose A.; Vilches, Anna Belen Morales; Kasparavicius, Ernestas; Smith, Joel A.; Phung, Nga; Menzel, Dorothee; Grischek, Max; Kegelmann, Lukas; Skroblin, Dieter; Gollwitzer, Christian; Malinauskas, Tadas; Jost, Marko; Matic, Gasper; Rech, Bernd; Schlatmann, Rutger; Topic, Marko; Korte, Lars; Abate, Antonio; Stannowski, Bernd; Neher, Dieter; Stolterfoht, Martin; Unold, Thomas; Getautis, Vytautas; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tandem solar cells that pair silicon with a metal halide perovskite are a promising option for surpassing the single-cell efficiency limit. We report a monolithic perovskite/silicon tandem with a certified power conversion efficiency of 29.15%. The perovskite absorber, with a bandgap of 1.68 electron volts, remained phase-stable under illumination through a combination of fast hole extraction and minimized nonradiative recombination at the hole-selective interface. These features were made possible by a self-assembled, methyl-substituted carbazole monolayer as the hole-selective layer in the perovskite cell. The accelerated hole extraction was linked to a low ideality factor of 1.26 and single-junction fill factors of up to 84%, while enabling a tandem open-circuit voltage of as high as 1.92 volts. In air, without encapsulation, a tandem retained 95% of its initial efficiency after 300 hours of operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1420, "Times Cited, All Databases": 1485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2020, "Volume": 370, "Issue": 6522, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1300, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd4016", "DOI Link": "http://dx.doi.org/10.1126/science.abd4016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597271300039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, SY; Lu, SY; Geng, YJ; Zhu, SJ; Redfern, SAT; Song, YB; Feng, TL; Xu, WQ; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Songyuan; Lu, Siyu; Geng, Yijia; Zhu, Shoujun; Redfern, Simon A. T.; Song, Yubin; Feng, Tanglue; Xu, Weiqing; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Metal-Free Polymer Carbon Dots: A New Class of Room-Temperature Phosphorescent Materials", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer carbon dots (PCDs) are proposed as a new class of room-temperature phosphorescence (RTP) materials. The abundant energy levels in PCDs increase the probability of intersystem crossing (ISC) and their covalently crosslinked framework structures greatly suppress the nonradiative transitions. The efficient methods allow the manufacture of PCDs with unique RTP properties in air without additional metal complexation or complicated matrix composition. They thus provide a route towards the rational design of metal-free RTP materials that may be synthesized easily. Furthermore, we find that RTP is associated with a crosslink-enhanced emission (CEE) effect, which provides further routes to design improved PCDs with diverse RTP performance. Our results show the potential of PCDs as a universal route to achieve effective metal-free RTP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2018, "Volume": 57, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2393, "End Page": 2398, "Article Number": null, "DOI": "10.1002/anie.201712662", "DOI Link": "http://dx.doi.org/10.1002/anie.201712662", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425453300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarkar, A; Velasco, L; Wang, D; Wang, QS; Talasila, G; de Biasi, L; Kübel, C; Brezesinski, T; Bhattacharya, SS; Hahn, H; Breitung, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarkar, Abhishek; Velasco, Leonardo; Wang, Di; Wang, Qingsong; Talasila, Gopichand; de Biasi, Lea; Kuebel, Christian; Brezesinski, Torsten; Bhattacharya, Subramshu S.; Hahn, Horst; Breitung, Ben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High entropy oxides for reversible energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the concept of entropy stabilization of crystal structures in oxide systems has led to an increased research activity in the field of high entropy oxides. These compounds comprise the incorporation of multiple metal cations into single-phase crystal structures and interactions among the various metal cations leading to interesting novel and unexpected properties. Here, we report on the reversible lithium storage properties of the high entropy oxides, the underlying mechanisms governing these properties, and the influence of entropy stabilization on the electrochemical behavior. It is found that the stabilization effect of entropy brings significant benefits for the storage capacity retention of high entropy oxides and greatly improves the cycling stability. Additionally, it is observed that the electrochemical behavior of the high entropy oxides depends on each of the metal cations present, thus providing the opportunity to tailor the electrochemical properties by simply changing the elemental composition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 924, "Times Cited, All Databases": 980, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3400, "DOI": "10.1038/s41467-018-05774-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05774-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442594800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Drozdov, AP; Eremets, MI; Troyan, IA; Ksenofontov, V; Shylin, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Drozdov, A. P.; Eremets, M. I.; Troyan, I. A.; Ksenofontov, V.; Shylin, S. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A superconductor is a material that can conduct electricity without resistance below a superconducting transition temperature, T-c. The highest T-c that has been achieved to date is in the copper oxide system(1): 133 kelvin at ambient pressure(2) and 164 kelvin at high pressures(3). As the nature of superconductivity in these materials is still not fully understood (they are not conventional superconductors), the prospects for achieving still higher transition temperatures by this route are not clear. In contrast, the Bardeen-Cooper-Schrieffer theory of conventional superconductivity gives a guide for achieving high T-c with no theoretical upper bound-all that is needed is a favourable combination of high-frequency phonons, strong electron-phonon coupling, and a high density of states(4). These conditions can in principle be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen(5,6), as hydrogen atoms provide the necessary high-frequency phonon modes as well as the strong electron-phonon coupling. Numerous calculations support this idea and have predicted transition temperatures in the range 50-235 kelvin for many hydrides(7), but only a moderate T-c of 17 kelvin has been observed experimentally(8). Here we investigate sulfur hydride(9), where a T-c of 80 kelvin has been predicted(10). We find that this system transforms to a metal at a pressure of approximately 90 gigapascals. On cooling, we see signatures of superconductivity: a sharp drop of the resistivity to zero and a decrease of the transition temperature with magnetic field, with magnetic susceptibility measurements confirming a T-c of 203 kelvin. Moreover, a pronounced isotope shift of T-c in sulfur deuteride is suggestive of an electron-phonon mechanism of superconductivity that is consistent with the Bardeen-Cooper-Schrieffer scenario. We argue that the phase responsible for high-T-c superconductivity in this system is likely to be H3S, formed from H2S by decomposition under pressure. These findings raise hope for the prospects for achieving room-temperature superconductivity in other hydrogen-based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1830, "Times Cited, All Databases": 1999, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2015, "Volume": 525, "Issue": 7567, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 73, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature14964", "DOI Link": "http://dx.doi.org/10.1038/nature14964", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360594100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, JQ; Liu, Q; Cheng, NY; Asiri, AM; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Jingqi; Liu, Qian; Cheng, Ningyan; Asiri, Abdullah M.; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Supported Cu3P nullowire Arrays as an Integrated High-Performance Three-Dimensional Cathode for Generating Hydrogen from Water", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for inexpensive hydrogen evolution reaction (HER) electrocatalysts with high activity has attracted considerable research interest in the past years. Reported herein is the topotactic fabrication of self-supported Cu3P nullowire arrays on commercial porous copper foam (Cu3P NW/CF) from its Cu(OH)(2) NW/CF precursor by a low-temperature phosphidation reaction. Remarkably, as an integrated three-dimensional hydrogen-evolving cathode operating in acidic electrolytes, Cu3P NW/CF maintains its activity for at least 25 hours and exhibits an onset overpotential of 62 mV, a Tafel slope of 67 mVdec(-1), and a Faradaic efficiency close to 100%. Catalytic current density can approach 10 mAcm(-2) at an overpotential of 143 mV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 834, "Times Cited, All Databases": 863, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2014, "Volume": 53, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9577, "End Page": 9581, "Article Number": null, "DOI": "10.1002/anie.201403842", "DOI Link": "http://dx.doi.org/10.1002/anie.201403842", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342677000029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, XY; Li, H; Ma, YC; Xue, M; Fang, QR; Yan, YS; Valtchev, V; Qiu, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Xinyu; Li, Hui; Ma, Yunchao; Xue, Ming; Fang, Qianrong; Yan, Yushan; Valtchev, Valentin; Qiu, Shilun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemically stable polyarylether-based covalent organic frameworks", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of crystalline porous materials with high chemical stability is of paramount importance for their practical application. Here, we report the synthesis of polyarylether-based covalent organic frameworks (PAE-COFs) with high crystallinity, porosity and chemical stability, including towards water, owing to the inert nature of their polyarylether-based building blocks. The PAE-COFs are synthesized through nucleophilic aromatic substitution reactions between ortho-difluoro benzene and catechol building units, which form ether linkages. The resulting materials are shown to be stable against harsh chemical environments including boiling water, strong acids and bases, and oxidation and reduction conditions. Their stability surpasses the performance of other known crystalline porous materials such as zeolites, metal-organic frameworks and covalent organic frameworks. We also demonstrate the post-synthetic functionalization of these materials with carboxyl or amino functional groups. The functionalized PAE-COFs combine porosity, high stability and recyclability. A preliminary application of these materials is demonstrated with the removal of antibiotics from water over a wide pH range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 587, "End Page": 594, "Article Number": null, "DOI": "10.1038/s41557-019-0238-5", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0238-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468760800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Withers, F; Del Pozo-Zamudio, O; Mishchenko, A; Rooney, AP; Gholinia, A; Watanabe, K; Taniguchi, T; Haigh, SJ; Geim, AK; Tartakovskii, AI; Novoselov, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Withers, F.; Del Pozo-Zamudio, O.; Mishchenko, A.; Rooney, A. P.; Gholinia, A.; Watanabe, K.; Taniguchi, T.; Haigh, S. J.; Geim, A. K.; Tartakovskii, A. I.; Novoselov, K. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-emitting diodes by band-structure engineering in van der Waals heterostructures", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of graphene and related 2D materials1,2 has recently led to a new technology: heterostructures based on these atomically thin crystals(3). The paradigm proved itself extremely versatile and led to rapid demonstration of tunnelling diodes with negative differential resistance(4), tunnelling transistors(5), photovoltaic devices(6,7) and so on. Here, we take the complexity and functionality of such van der Waals heterostructures to the next level by introducing quantum wells (QWs) engineered with one atomic plane precision. We describe light-emitting diodes (LEDs) made by stacking metallic graphene, insulating hexagonal boron nitride and various semiconducting monolayers into complex but carefully designed sequences. Our first devices already exhibit an extrinsic quantum efficiency of nearly 10% and the emission can be tuned over a wide range of frequencies by appropriately choosing and combining 2D semiconductors (monolayers of transition metal dichalcogenides). By preparing the heterostructures on elastic and transparent substrates, we show that they can also provide the basis for flexible and semi-transparent electronics. The range of functionalities for the demonstrated heterostructures is expected to grow further on increasing the number of available 2D crystals and improving their electronic quality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1407, "Times Cited, All Databases": 1559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 301, "End Page": 306, "Article Number": null, "DOI": "10.1038/nmat4205", "DOI Link": "http://dx.doi.org/10.1038/nmat4205", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350136400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuk, H; Zhang, T; Parada, GA; Liu, XY; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuk, Hyunwoo; Zhang, Teng; Parada, German Alberto; Liu, Xinyue; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-inspired hydrogel-elastomer hybrids with robust interfaces and functional microstructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by mammalian skins, soft hybrids integrating the merits of elastomers and hydrogels have potential applications in diverse areas including stretchable and bio-integrated electronics, microfluidics, tissue engineering, soft robotics and biomedical devices. However, existing hydrogel-elastomer hybrids have limitations such as weak interfacial bonding, low robustness and difficulties in patterning microstructures. Here, we report a simple yet versatile method to assemble hydrogels and elastomers into hybrids with extremely robust interfaces (interfacial toughness over 1,000 Jm(-2)) and functional microstructures such as microfluidic channels and electrical circuits. The proposed method is generally applicable to various types of tough hydrogels and diverse commonly used elastomers including polydimethylsiloxane Sylgard 184, polyurethane, latex, VHB and Ecoflex. We further demonstrate applications enabled by the robust and microstructured hydrogel-elastomer hybrids including anti-dehydration hydrogel-elastomer hybrids, stretchable and reactive hydrogel-elastomer microfluidics, and stretchable hydrogel circuit boards patterned on elastomer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 802, "Times Cited, All Databases": 879, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12028, "DOI": "10.1038/ncomms12028", "DOI Link": "http://dx.doi.org/10.1038/ncomms12028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391865000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YJ; Luan, DY; Chen, Y; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang Yongjin; Luan Deyan; Chen Ye; Gao Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationally Designed Three-Layered Cu2S@Carbon@MoS2 Hierarchical nulloboxes for Efficient Sodium Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid materials, integrating the merits of individual components, are ideal structures for efficient sodium storage. However, the construction of hybrid structures with decent physical/electrochemical properties is still challenging. Now, the elaborate design and synthesis of hierarchical nulloboxes composed of three-layered Cu2S@carbon@MoS2 as anode materials for sodium-ion batteries is reported. Through a facile multistep template-engaged strategy, ultrathin MoS2 nullosheets are grown on nitrogen-doped carbon-coated Cu2S nulloboxes to realize the Cu2S@carbon@MoS2 configuration. The design shortens the diffusion path of electrons/Na+ ions, accommodates the volume change of electrodes during cycling, enhances the electric conductivity of the hybrids, and offers abundant active sites for sodium uptake. By virtue of these advantages, these three-layered Cu2S@carbon@MoS2 hierarchical nulloboxes show excellent electrochemical properties in terms of decent rate capability and stable cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2020, "Volume": 59, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7178, "End Page": 7183, "Article Number": null, "DOI": "10.1002/anie.201915917", "DOI Link": "http://dx.doi.org/10.1002/anie.201915917", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526818900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Zhu, CX; Pfattner, R; Yan, HP; Jin, LH; Chen, SC; Molina-Lopez, F; Lissel, F; Liu, J; Rabiah, NI; Chen, Z; Chung, JW; Linder, C; Toney, MF; Murmann, B; Bao, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yue; Zhu, Chenxin; Pfattner, Raphael; Yan, Hongping; Jin, Lihua; Chen, Shucheng; Molina-Lopez, Francisco; Lissel, Franziska; Liu, Jia; Rabiah, Noelle I.; Chen, Zheng; Chung, Jong Won; Linder, Christian; Toney, Michael F.; Murmann, Boris; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly stretchable, transparent, and conductive polymer", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Previous breakthroughs in stretchable electronics stem from strain engineering and nullocomposite approaches. Routes toward intrinsically stretchable molecular materials remain scarce but, if successful, will enable simpler fabrication processes, such as direct printing and coating, mechanically robust devices, and more intimate contact with objects. We report a highly stretchable conducting polymer, realized with a range of enhancers that serve a dual function: (i) they change morphology and (ii) they act as conductivity-enhancing dopants in poly(3,4-ethylene-dioxythiophene): poly(styrenesulfonate) (PEDOT: PSS). The polymer films exhibit conductivities comparable to the best reported values for PEDOT: PSS, with over 3100 S/cm under 0% strain and over 4100 S/cm under 100% strain-among the highest for reported stretchable conductors. It is highly durable under cyclic loading, with the conductivity maintained at 3600 S/cm even after 1000 cycles to 100% strain. The conductivity remained above 100 S/cmunder 600% strain, with a fracture strain of 800%, which is superior to even the best silver nullowire-or carbon nullotube-based stretchable conductor films. The combination of excellent electrical and mechanical properties allowed it to serve as interconnects for field-effect transistor arrays with a device density that is five times higher than typical lithographically patterned wavy interconnects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1260, "Times Cited, All Databases": 1384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602076", "DOI": "10.1126/sciadv.1602076", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397044000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DY; Qiu, D; Gibson, MA; Zheng, YF; Fraser, HL; StJohn, DH; Easton, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Duyao; Qiu, Dong; Gibson, Mark A.; Zheng, Yufeng; Fraser, Hamish L.; StJohn, David H.; Easton, Mark A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of ultrafine-grained high-strength titanium alloys", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing, often known as three-dimensional (3D) printing, is a process in which a part is built layer-by-layer and is a promising approach for creating components close to their final (net) shape. This process is challenging the dominullce of conventional manufacturing processes for products with high complexity and low material waste(1). Titanium alloys made by additive manufacturing have been used in applications in various industries. However, the intrinsic high cooling rates and high thermal gradient of the fusion-based metal additive manufacturing process often leads to a very fine microstructure and a tendency towards almost exclusively columnar grains, particularly in titanium-based alloys(1). (Columnar grains in additively manufactured titanium components can result in anisotropic mechanical properties and are therefore undesirable(2).) Attemptsto optimize the processing parameters of additive manufacturing have shown that it is difficult to alter the conditions to promote equiaxed growth of titaniumgrains(3). In contrast with other common engineering alloys such as aluminium, there is no commercial grain refiner for titanium that is able to effectively refine the microstructure. To address this challenge, here we report on the development of titanium-copper alloys that have a high constitutional supercooling capacity as a result of partitioning of the alloying element during solidification, which can override the negative effect of a high thermal gradient in the laser-melted region during additive manufacturing. Without any special process control or additional treatment, our as-printed titanium-copper alloy specimens have a fully equiaxed fine-grained microstructure. They also display promising mechanical properties, such as high yield strength and uniform elongation, compared to conventional alloys under similar processing conditions, owing to the formation of an ultrafine eutectoid microstructure that appears as a result of exploiting the high cooling rates and multiple thermal cycles of the manufacturing process. We anticipate that this approach will be applicable to other eutectoid-forming alloy systems, and that it will have applications in the aerospace and biomedical industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 745, "Times Cited, All Databases": 798, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2019, "Volume": 576, "Issue": 7785, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 91, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1783-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1783-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000501599200046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, D; Chen, Y; Yan, JC; Qian, LB; Han, L; Chen, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Da; Chen, Yun; Yan, Jingchun; Qian, Linbo; Han, Lu; Chen, Mengfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activation mechanism of peroxymonosulfate by biochar for catalytic degradation of 1,4-dioxane: Important role of biochar defect structures", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbonaceous materials have been emerged as promising metal-free catalysts to activate peroxymonosulfate (PMS) for the degradation of organic contaminullts. In the present study, a low-cost carbonaceous material, pine needle biochar was prepared under the oxygen limited pyrolyzation process and applied to activate PMS for the catalytic degradation of potentially carcinogenic 1,4-dioxane. Based on the batch experiments, the pyrolysis temperature has a significant influence on the potency of biochar to activate PMS. Within the biochar/PMS system, the degradation efficiencies of 1,4-dioxane were increased from 4.1 to 84.2% when the biochar pyrolysis temperatures were increased from 300 degrees C to 800 degrees C. Electron paramagnetic resonullce (EPR) study and the quenching experiment verified that the dominullt free radical within the system of biochar/PMS was center dot OH. The EPR combined X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) and Raman analysis implied that the defect of biochar contributed to the generation of SO4 center dot- and center dot OH and high pyrolysis temperatures would eliminate the excess of oxygen functional groups in biochar, which could modulate and transform sp(3) carbons, generating more defect structures, therefore, enhancing the activation potency of biochar towards PMS. Simultaneously, five major intermediates were identified and three possible degradation pathways were proposed in this study. In addition, 71.4% and 57.5% of 1,4-dioxane removal rates were achieved in 1,4-dioxane contaminated tap water and groundwater, indicating that biochar activating PMS is a promising technique for the remediation of 1,4-dioxane contaminated water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 492, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2019, "Volume": 370, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 614, "End Page": 624, "Article Number": null, "DOI": "10.1016/j.cej.2019.03.235", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.03.235", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467387200057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chou, HH; Nguyen, A; Chortos, A; To, JWF; Lu, C; Mei, JG; Kurosawa, T; Bae, WG; Tok, JBH; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chou, Ho-Hsiu; Nguyen, Amanda; Chortos, Alex; To, John W. F.; Lu, Chien; Mei, Jianguo; Kurosawa, Tadanori; Bae, Won-Gyu; Tok, Jeffrey B. -H.; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A chameleon-inspired stretchable electronic skin with interactive colour changing controlled by tactile sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Some animals, such as the chameleon and cephalopod, have the remarkable capability to change their skin colour. This unique characteristic has long inspired scientists to develop materials and devices to mimic such a function. However, it requires the complex integration of stretchability, colour-changing and tactile sensing. Here we show an all-solution processed chameleon-inspired stretchable electronic skin (e-skin), in which the e-skin colour can easily be controlled through varying the applied pressure along with the applied pressure duration. As such, the e-skin's colour change can also be in turn utilized to distinguish the pressure applied. The integration of the stretchable, highly tunable resistive pressure sensor and the fully stretchable organic electrochromic device enables the demonstration of a stretchable electrochromically active e-skin with tactile-sensing control. This system will have wide range applications such as interactive wearable devices, artificial prosthetics and smart robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 817, "Times Cited, All Databases": 885, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8011, "DOI": "10.1038/ncomms9011", "DOI Link": "http://dx.doi.org/10.1038/ncomms9011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360351600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klaus, S; Cai, Y; Louie, MW; Trotochaud, L; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klaus, Shannon; Cai, Yun; Louie, Mary W.; Trotochaud, Lena; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of Fe Electrolyte Impurities on Ni(OH)2/NiOOH Structure and Oxygen Evolution Activity", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-(oxy)hydroxide-based materials are promising earth-abundant catalysts for electrochemical water oxidation in basic media. Recent findings demonstrate that incorporation of trace Fe impurities from commonly used KOH electrolytes significantly improves oxygen evolution reaction (OER) activity over NiOOH electrocatalysts. Because nearly all previous studies detailing structural differences between alpha-Ni(OH)(2)/gamma-NiOOH and beta-Ni(OH)(2)/beta-NiOOH were completed in unpurified electrolytes, it is unclear whether these structural changes are unique to the aging phase transition in the Ni-(oxy)hydroxide matrix or if they arise fully or in part from inadvertent Fe incorporation. Here, we report an investigation of the effects of Fe incorporation on structureactivity relationships in Ni-(oxy)hydroxide. Electrochemical, in situ Raman, X-ray photoelectron spectroscopy, and electrochemical quartz crystal microbalance measurements were employed to investigate Ni(OH)(2) thin films aged in Fe-free and unpurified (reagent-grade) 1 M KOH (<1 ppm Fe). We find that Ni films aged in unpurified electrolyte can incorporate >= 20% Fe after 5 weeks of aging, and the maximum catalyst activity is comparable to that reported for optimized Ni1-xFexOOH catalysts. Conversely, Fe-free Ni(OH)(2) films exhibit a substantially lower activity and higher Tafel slope for the OER. Films aged in Fe-free electrolyte are predominulltly disordered beta-Ni(OH)(2)/beta-NiOOH if maintained below 0.7 V vs Hg/HgO in 1 M KOH and will overcharge to form a mixture of gamma- and beta-NiOOH above this potential. Fe-containing Ni(OH)(2) films evidence a lesser extent of beta-Ni(OH)(2) formation and instead exhibit NiOOH structural changes in accordance with the formation of a Ni-Fe-layered double hydroxide phase. Furthermore, turnover frequency calculations indicate that Fe is the active site within this phase, and above similar to 11% Fe content, a separate, Fe-rich phase forms. These findings are the first to demonstrate the in situ changes in the catalyst structure resulting from the incorporation of Fe electrolyte impurities within Ni-(oxy)hydroxide, providing direct evidence that a NiFe layered double (oxy)hydroxide (LDH) phase is critical for high OER activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 905, "Times Cited, All Databases": 957, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2015, "Volume": 119, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7243, "End Page": 7254, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b00105", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b00105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352329500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CMJ; Fang, RH; Wang, KC; Luk, BT; Thamphiwatana, S; Dehaini, D; Nguyen, P; Angsantikul, P; Wen, CH; Kroll, AV; Carpenter, C; Ramesh, M; Qu, V; Patel, SH; Zhu, J; Shi, W; Hofman, FM; Chen, TC; Gao, WW; Zhang, K; Chien, S; Zhang, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Che-Ming J.; Fang, Ronnie H.; Wang, Kuei-Chun; Luk, Brian T.; Thamphiwatana, Soracha; Dehaini, Diana; Phu Nguyen; Angsantikul, Pavimol; Wen, Cindy H.; Kroll, Ashley V.; Carpenter, Cody; Ramesh, Manikantan; Qu, Vivian; Patel, Sherrina H.; Zhu, Jie; Shi, William; Hofman, Florence M.; Chen, Thomas C.; Gao, Weiwei; Zhang, Kang; Chien, Shu; Zhang, Liangfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticle biointerfacing by platelet membrane cloaking", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of functional nulloparticles can be encumbered by unullticipated material properties and biological events, which can affect nulloparticle effectiveness in complex, physiologically relevant systems(1-3). Despite the advances in bottom-up nulloengineering and surface chemistry, reductionist functionalization approaches remain inadequate in replicating the complex interfaces present in nature and cannot avoid exposure of foreign materials. Here we report on the preparation of polymeric nulloparticles enclosed in the plasma membrane of human platelets, which are a unique population of cellular fragments that adhere to a variety of disease-relevant substrates(4-7). The resulting nulloparticles possess a right-side-out unilamellar membrane coating functionalized with immunomodulatory and adhesion antigens associated with platelets. Compared to uncoated particles, the platelet membrane-cloaked nulloparticles have reduced cellular uptake by macrophage-like cells and lack particle-induced complement activation in autologous human plasma. The cloaked nulloparticles also display platelet-mimicking properties such as selective adhesion to damaged human and rodent vasculatures as well as enhanced binding to platelet-adhering pathogens. In an experimental rat model of coronary restenosis and a mouse model of systemic bacterial infection, docetaxel and vancomycin, respectively, show enhanced therapeutic efficacy when delivered by the platelet-mimetic nulloparticles. The multifaceted biointerfacing enabled by the platelet membrane cloaking method provides a new approach in developing functional nulloparticles for disease-targeted delivery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1388, "Times Cited, All Databases": 1500, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2015, "Volume": 526, "Issue": 7571, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 118, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature15373", "DOI Link": "http://dx.doi.org/10.1038/nature15373", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362095100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, WY; Li, RF; Chen, ZH; Gu, JY; Tian, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Wuyan; Li, Ruifeng; Chen, Zhaohui; Gu, Jiayang; Tian, Yingtao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A comparative study on microstructure and properties of traditional laser cladding and high-speed laser cladding of Ni45 alloy coatings", "Source Title": "SURFACE & COATINGS TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-speed laser cladding technology can significantly improve the efficiency of coating preparation and effectively widen the application range of laser cladding. In this study, the Ni45 powders were deposited on steel substrate by traditional low speed laser cladding and high-speed laser cladding process, respectively. The cladding efficiency, surface forming, cross-sectional microstructure, microhardness, wear and corrosion resistance properties of the traditional and high-speed laser cladded Ni45 alloy coatings were compared. It can be seen that the thickness of the high-speed laser cladding coating was much thinner than that of the traditional laser cladding coating. Compared with traditional laser cladding, high-speed laser cladding could achieve a cladding speed of 76.86 m/min and a cladding efficiency of 156.79 cm(2)/min. The microstructure of the two kinds of coatings shows the same growth law, but the microstructure in high-speed laser cladding was smaller and denser, and the columnar crystal interval was narrower, only about 6 mu m. It is found that the cooling rate of the traditional laser cladding coating was smaller than that of the high-speed laser cladding, and as the cladding speed increased, the cooling rate became higher and higher. The cross-section microhardness of the traditional laser cladding coating was relatively uniform of 337 HV0.2, while the microhardness of high-speed laser cladding surface increased to about 543 HV0.2. In addition, the wear and corrosion resistance of high-speed laser cladded coatings were better than that of traditional laser cladded coatings. As the cladding speed increased, the wear and corrosion resistance of the cladded coatings became better.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 405, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126582, "DOI": "10.1016/j.surfcoat.2020.126582", "DOI Link": "http://dx.doi.org/10.1016/j.surfcoat.2020.126582", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604583200055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, A; Zheng, GY; Shi, FF; Li, YZ; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, Allen; Zheng, Guangyuan; Shi, Feifei; Li, Yuzhang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale Nucleation and Growth of Electrodeposited Lithium Metal", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has re-emerged as an exciting anode for high energy lithium-ion batteries due to its high specific capacity of 3860 mAh g(-1) and lowest electrochemical potential of all known materials. However, lithium has been plagued by the issues of dendrite formation, high chemical reactivity with electrolyte, and infinite relative volume expansion during plating and stripping, which present safety hazards and low cycling efficiency in batteries with lithium metal electrodes. There have been a lot of recent studies on Li metal although little work has focused on the initial nucleation and growth behavior of Li metal, neglecting a critical fundamental scientific foundation of Li plating. Here, we study experimentally the morphology of lithium in the early stages of nucleation and growth on planar copper electrodes in liquid organic electrolyte. We elucidate the dependence of lithium nuclei size, shape, and areal density on current rate, consistent with classical nucleation and growth theory. We found that the nuclei size is proportional to the inverse of overpotential and the number density of nuclei is proportional to the cubic power of overpotential. Based on this understanding, we propose a strategy to increase the uniformity of electrodeposited lithium on the electrode surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1287, "Times Cited, All Databases": 1380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1132, "End Page": 1139, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b04755", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b04755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393848800075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XH; Wang, XH; Huang, JF; Li, SX; Meng, A; Li, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xuehua; Wang, Xianghu; Huang, Jianfeng; Li, Shaoxiang; Meng, Alan; Li, Zhenjiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of Z-scheme heterostructure is of great significance for realizing efficient photocatalytic water splitting. However, the conscious modulation of Z-scheme charge transfer is still a great challenge. Herein, interfacial Mo-S bond and internal electric field modulated Z-scheme heterostructure composed by sulfur vacancies-rich ZnIn2S4 and MoSe2 was rationally fabricated for efficient photocatalytic hydrogen evolution. Systematic investigations reveal that Mo-S bond and internal electric field induce the Z-scheme charge transfer mechanism as confirmed by the surface photovoltage spectra, DMPO spin-trapping electron paramagnetic resonullce spectra and density functional theory calculations. Under the intense synergy among the Mo-S bond, internal electric field and S-vacancies, the optimized photocatalyst exhibits high hydrogen evolution rate of 63.21mmol.g(-1)h(-1) with an apparent quantum yield of 76.48% at 420nm monochromatic light, which is about 18.8-fold of the pristine ZIS. This work affords a useful inspiration on consciously modulating Z-scheme charge transfer by atomic-level interface control and internal electric field to signally promote the photocatalytic performance. The construction of Z-scheme heterostructures is of great significance for realizing efficient photocatalytic water splitting. Here, the authors report an interfacial chemical bond and internal electric field modulated Z-Scheme S-v-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 714, "Times Cited, All Databases": 722, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4112, "DOI": "10.1038/s41467-021-24511-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24511-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672713100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Matsubu, JC; Zhang, SY; DeRita, L; Marinkovic, NS; Chen, JGG; Graham, GW; Pan, XQ; Christopher, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Matsubu, John C.; Zhang, Shuyi; DeRita, Leo; Marinkovic, Nebojsa S.; Chen, Jingguang G.; Graham, George W.; Pan, Xiaoqing; Christopher, Phillip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorbate-mediated strong metal-support interactions in oxide-supported Rh catalysts", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The optimization of supported metal catalysts predominulltly focuses on engineering the metal site, for which physical insights based on extensive theoretical and experimental contributions have enabled the rational design of active sites. Although it is well known that supports can influence the catalytic properties of metals, insights into how metal-support interactions can be exploited to optimize metal active-site properties are lacking. Here we utilize in situ spectroscopy and microscopy to identify and characterize a support effect in oxide-supported heterogeneous Rh catalysts. This effect is characterized by strongly bound adsorbates (HCOx) on reducible oxide supports (TiO2 and Nb2O5) that induce oxygen-vacancy formation in the support and cause HCOx-functionalized encapsulation of Rh nulloparticles by the support. The encapsulation layer is permeable to reactants, stable under the reaction conditions and strongly influences the catalytic properties of Rh, which enables rational and dynamic tuning of CO2-reduction selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 686, "Times Cited, All Databases": 730, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 120, "End Page": 127, "Article Number": null, "DOI": "10.1038/NCHEM.2607", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2607", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394541900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dionigi, F; Zeng, ZH; Sinev, I; Merzdorf, T; Deshpande, S; Lopez, MB; Kunze, S; Zegkinoglou, I; Sarodnik, H; Fan, DX; Bergmann, A; Drnec, J; de Araujo, JF; Gliech, M; Teschner, D; Zhu, J; Li, WX; Greeley, J; Roldan Cuenya, B; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dionigi, Fabio; Zeng, Zhenhua; Sinev, Ilya; Merzdorf, Thomas; Deshpande, Siddharth; Lopez, Miguel Bernal; Kunze, Sebastian; Zegkinoglou, Ioannis; Sarodnik, Hannes; Fan, Dingxin; Bergmann, Arno; Drnec, Jakub; de Araujo, Jorge Ferreira; Gliech, Manuel; Teschner, Detre; Zhu, Jing; Li, Wei-Xue; Greeley, Jeffrey; Roldan Cuenya, Beatriz; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NiFe and CoFe (MFe) layered double hydroxides (LDHs) are among the most active electrocatalysts for the alkaline oxygen evolution reaction (OER). Herein, we combine electrochemical measurements, operando X-ray scattering and absorption spectroscopy, and density functional theory (DFT) calculations to elucidate the catalytically active phase, reaction center and the OER mechanism. We provide the first direct atomic-scale evidence that, under applied anodic potentials, MFe LDHs oxidize from as-prepared alpha -phases to activated gamma -phases. The OER-active gamma -phases are characterized by about 8% contraction of the lattice spacing and switching of the intercalated ions. DFT calculations reveal that the OER proceeds via a Mars van Krevelen mechanism. The flexible electronic structure of the surface Fe sites, and their synergy with nearest-neighbor M sites through formation of O-bridged Fe-M reaction centers, stabilize OER intermediates that are unfavorable on pure M-M centers and single Fe sites, fundamentally accounting for the high catalytic activity of MFe LDHs. NiFe and CoFe layered double hydroxides are among the most active electrocatalysts for the alkaline oxygen evolution reaction. Here, by combining operando experiments and rigorous DFT calculations, the authors unravel their active phase, the reaction center and the catalytic mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 757, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2522, "DOI": "10.1038/s41467-020-16237-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16237-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537059500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SB; Guan, BY; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sibo; Guan, Bu Yuan; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational Design of Three-Layered TiO2@Carbon@MoS2 Hierarchical nullotubes for Enhanced Lithium Storage", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we demonstrate the rational design and synthesis of three-layered TiO2@carbon@MoS2 hierarchical nullotubes for anode applications in lithium-ion batteries (LIBs). Through an efficient step-by-step strategy, ultrathin MoS2 nullosheets are grown on nitrogen-doped carbon (NC) coated TiO2 nullotubes to achieve the TiO2@NC@MoS2 tubular nullostructures. This smart design can effectively shorten the diffusion length of Li+ ions, increase electric conductivity of the electrode, relax volume variation of electrode materials upon cycling, and provide more active sites for electrochemical reactions. Owing to these structural and compositional features, the hierarchical TiO2@NC@MoS2 nullotubes manifest remarkable lithium storage performance with good rate capability and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 4", "Publication Year": 2017, "Volume": 29, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702724, "DOI": "10.1002/adma.201702724", "DOI Link": "http://dx.doi.org/10.1002/adma.201702724", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412184100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, SY; Zhang, X; Zhou, W; Gao, R; Xu, WQ; Ye, YF; Lin, LL; Wen, XD; Liu, P; Chen, BB; Crumlin, E; Guo, JH; Zuo, ZJ; Li, WZ; Xie, JL; Lu, L; Kiely, CJ; Gu, L; Shi, C; Rodriguez, JA; Ma, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Siyu; Zhang, Xiao; Zhou, Wu; Gao, Rui; Xu, Wenqian; Ye, Yifan; Lin, Lili; Wen, Xiaodong; Liu, Ping; Chen, Bingbing; Crumlin, Ethan; Guo, Jinghua; Zuo, Zhijun; Li, Weizhen; Xie, Jinglin; Lu, Li; Kiely, Christopher J.; Gu, Lin; Shi, Chuan; Rodriguez, Jose A.; Ma, Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The water-gas shift (WGS) reaction (where carbon monoxide plus water yields dihydrogen and carbon dioxide) is an essential process for hydrogen generation and carbon monoxide removal in various energy-related chemical operations. This equilibrium-limited reaction is favored at a low working temperature. Potential application in fuel cells also requires a WGS catalyst to be highly active, stable, and energy-efficient and to match the working temperature of on-site hydrogen generation and consumption units. We synthesized layered gold (Au) clusters on a molybdenum carbide (alpha-MoC) substrate to create an interfacial catalyst system for the ultralow-temperature WGS reaction. Water was activated over alpha-MoC at 303 kelvin, whereas carbon monoxide adsorbed on adjacent Au sites was apt to react with surface hydroxyl groups formed from water splitting, leading to a high WGS activity at low temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 644, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2017, "Volume": 357, "Issue": 6349, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 389, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aah4321", "DOI Link": "http://dx.doi.org/10.1126/science.aah4321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406362300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, G; Li, G; Boriskina, SV; Li, HX; Yang, WL; Zhang, TJ; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, George; Li, Gabriel; Boriskina, Svetlana V.; Li, Hongxia; Yang, Weilin; Zhang, TieJun; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steam generation under one sun enabled by a floating structure with thermal concentration", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting solar energy as heat has many applications, such as power generation, residential water heating, desalination, distillation and wastewater treatment. However, the solar flux is diffuse, and often requires optical concentration, a costly component, to generate the high temperatures needed for some of these applications. Here we demonstrate a floating solar receiver capable of generating 100 degrees C steam under ambient air conditions without optical concentration. The high temperatures are achieved by using thermal concentration and heat localization, which reduce the convective, conductive and radiative heat losses. This demonstration of a low-cost and scalable solar vapour generator holds the promise of significantly expanding the application domain and reducing the cost of solar thermal systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 986, "Times Cited, All Databases": 1037, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16126, "DOI": "10.1038/NENERGY.2016.126", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.126", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394184700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuk, H; Lu, BY; Lin, S; Qu, K; Xu, JK; Luo, JH; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuk, Hyunwoo; Lu, Baoyang; Lin, Shen; Qu, Kai; Xu, Jingkun; Luo, Jianhong; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of conducting polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conducting polymers are promising material candidates in diverse applications including energy storage, flexible electronics, and bioelectronics. However, the fabrication of conducting polymers has mostly relied on conventional approaches such as ink-jet printing, screen printing, and electron-beam lithography, whose limitations have hampered rapid innovations and broad applications of conducting polymers. Here we introduce a high-performance 3D printable conducting polymer ink based on poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) for 3D printing of conducting polymers. The resultant superior printability enables facile fabrication of conducting polymers into high resolution and high aspect ratio microstructures, which can be integrated with other materials such as insulating elastomers via multi-material 3D printing. The 3D-printed conducting polymers can also be converted into highly conductive and soft hydrogel microstructures. We further demonstrate fast and streamlined fabrications of various conducting polymer devices, such as a soft neural probe capable of in vivo single-unit recording.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 722, "Times Cited, All Databases": 756, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604, "DOI": "10.1038/s41467-020-15316-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15316-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563559600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WD; Hu, Q; Bai, S; Bao, CX; Miao, YF; Yuan, ZC; Borzda, T; Barker, AJ; Tyukalova, E; Hu, ZJ; Kawecki, M; Wang, HY; Yan, ZB; Liu, XJ; Shi, XB; Uvdal, K; Fahlman, M; Zhang, WJ; Duchamp, M; Liu, JM; Petrozza, A; Wang, JP; Liu, LM; Huang, W; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Weidong; Hu, Qi; Bai, Sai; Bao, Chunxiong; Miao, Yanfeng; Yuan, Zhongcheng; Borzda, Tetiana; Barker, Alex J.; Tyukalova, Elizaveta; Hu, Zhangjun; Kawecki, Maciej; Wang, Heyong; Yan, Zhibo; Liu, Xianjie; Shi, Xiaobo; Uvdal, Kajsa; Fahlman, Mats; Zhang, Wenjing; Duchamp, Martial; Liu, Jun-Ming; Petrozza, Annamaria; Wang, Jianpu; Liu, Li-Min; Huang, Wei; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational molecular passivation for high-performance perovskite light-emitting diodes", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A major efficiency limit for solution-processed perovskite optoelectronic devices, for example light-emitting diodes, is trap-mediated non-radiative losses. Defect passivation using organic molecules has been identified as an attractive approach to tackle this issue. However, implementation of this approach has been hindered by a lack of deep understanding of how the molecular structures influence the effectiveness of passivation. We show that the so far largely ignored hydrogen bonds play a critical role in affecting the passivation. By weakening the hydrogen bonding between the passivating functional moieties and the organic cation featuring in the perovskite, we significantly enhance the interaction with defect sites and minimize non-radiative recombination losses. Consequently, we achieve exceptionally high-performance near-infrared perovskite light-emitting diodes with a record external quantum efficiency of 21.6%. In addition, our passivated perovskite light-emitting diodes maintain a high external quantum efficiency of 20.1% and a wall-plug efficiency of 11.0% at a high current density of 200 mA cm(-2), making them more attractive than the most efficient organic and quantum-dot light-emitting diodes at high excitations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1058, "Times Cited, All Databases": 1112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 418, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-019-0390-x", "DOI Link": "http://dx.doi.org/10.1038/s41566-019-0390-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468752300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, C; Zhang, Y; Wang, CX; Xue, DZ; Bai, Y; Antonov, S; Dai, LH; Lookman, T; Su, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Cheng; Zhang, Yan; Wang, Changxin; Xue, Dezhen; Bai, Yang; Antonov, Stoichko; Dai, Lanhong; Lookman, Turab; Su, Yanjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning assisted design of high entropy alloys with desired property", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We formulate a materials design strategy combining a machine learning (ML) surrogate model with experimental design algorithms to search for high entropy alloys (HEAs) with large hardness in a model Al-Co-Cr-Cu-Fe-Ni system. We fabricated several alloys with hardness 10% higher than the best value in the original training dataset via only seven experiments. We find that a strategy using both the compositions and descriptors based on a knowledge of the properties of HEAs, outperforms that merely based on the compositions alone. This strategy offers a recipe to rapidly optimize multi-component systems, such as bulk metallic glasses and superalloys, towards desired properties. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 170, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 109, "End Page": 117, "Article Number": null, "DOI": "10.1016/j.actamat.2019.03.010", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2019.03.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466252400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HZ; Shang, L; Zhang, QH; Shi, R; Waterhouse, GIN; Gu, L; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hongzhou; Shang, Lu; Zhang, Qinghua; Shi, Run; Waterhouse, Geoffrey I. N.; Gu, Lin; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is interest in metal single atom catalysts due to their remarkable activity and stability. However, the synthesis of metal single atom catalysts remains somewhat ad hoc, with no universal strategy yet reported that allows their generic synthesis. Herein, we report a universal synthetic strategy that allows the synthesis of transition metal single atom catalysts containing Cr, Mn, Fe, Co, Ni, Cu, Zn, Ru, Pt or combinations thereof. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure spectroscopy confirm that the transition metal atoms are uniformly dispersed over a carbon black support. The introduced synthetic method allows the production of carbon-supported metal single atom catalysts in large quantities (>1 kg scale) with high metal loadings. A Ni single atom catalyst exhibits outstanding activity for electrochemical reduction of carbon dioxide to carbon monoxide, achieving a 98.9% Faradaic efficiency at -1.2 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 532, "Times Cited, All Databases": 551, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4585, "DOI": "10.1038/s41467-019-12510-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12510-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489101300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, YX; Lin, ZY; Zhong, X; Huang, XQ; Weiss, NO; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yuxi; Lin, Zhaoyang; Zhong, Xing; Huang, Xiaoqing; Weiss, Nathan O.; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Holey graphene frameworks for highly efficient capacitive energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supercapacitors represent an important strategy for electrochemical energy storage, but are usually limited by relatively low energy density. Here we report a three-dimensional holey graphene framework with a hierarchical porous structure as a high-performance binder-free supercapacitor electrode. With large ion-accessible surface area, efficient electron and ion transport pathways as well as a high packing density, the holey graphene framework electrode can deliver a gravimetric capacitance of 298 F g(-1) and a volumetric capacitance of 212 F cm(-3) in organic electrolyte. Furthermore, we show that a fully packaged device stack can deliver gravimetric and volumetric energy densities of 35 Wh kg(-1) and 49 Whl(-1), respectively, approaching those of lead acid batteries. The achievement of such high energy density bridges the gap between traditional supercapacitors and batteries, and can open up exciting opportunities for mobile power supply in diverse applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1211, "Times Cited, All Databases": 1279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4554, "DOI": "10.1038/ncomms5554", "DOI Link": "http://dx.doi.org/10.1038/ncomms5554", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341047500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, K; Bae, J; Bakarich, SE; Yang, CH; Gately, RD; Spinks, GM; Panhuis, MIH; Suo, ZG; Vlassak, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Kevin; Bae, Jinhye; Bakarich, Shannon E.; Yang, Canhui; Gately, Reece D.; Spinks, Geoffrey M.; Panhuis, Marc In Het; Suo, Zhigang; Vlassak, Joost J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Transparent and Conductive Heterogeneous Hydrogel-Elastomer Systems", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A hydrogel-dielectric-elastomer system, polyacrylamide and poly(dimethylsiloxane) (PDMS), is adapted for extrusion printing for integrated device fabrication. A lithium-chloride-containing hydrogel printing ink is developed and printed onto treated PDMS with no visible signs of delamination and geometrically scaling resistance under moderate uniaxial tension and fatigue. A variety of designs are demonstrated, including a resistive strain gauge and an ionic cable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2017, "Volume": 29, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604827, "DOI": "10.1002/adma.201604827", "DOI Link": "http://dx.doi.org/10.1002/adma.201604827", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396166800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parvez, K; Wu, ZS; Li, RJ; Liu, XJ; Graf, R; Feng, XL; Müllen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parvez, Khaled; Wu, Zhong-Shuai; Li, Rongjin; Liu, Xianjie; Graf, Robert; Feng, Xinliang; Muellen, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mass production of high-quality graphene sheets is essential for their practical application in electronics, optoelectronics, composite materials, and energy-storage devices. Here we report a prompt electrochemical exfoliation of graphene sheets into aqueous solutions of different inorganic salts ((NH4)(2)SO4, Na2SO4, K2SO4, etc.). Exfoliation in these electrolytes leads to graphene with a high yield (>85%, <= 3 layers), large lateral size (up to 44 mu m), low oxidation degree (a C/O ratio of 17.2), and a remarkable hole mobility of 310 cm(2) V-1 s(-1). Further, highly conductive graphene films (11 Omega sq(-1)) are readily fabricated on an A4-size paper by applying brush painting of a concentrated graphene ink (10 mg mL(-1), in N,N'-dimethylformamide). All-solid-state flexible supercapacitors manufactured on the basis of such graphene films deliver a high area capacitance of 11.3 mF cm(-2) and an excellent rate capability of 5000 mV s(-1). The described electrochemical exfoliation shows great promise for the industrial-scale synthesis of high-quality graphene for numerous advanced applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1172, "Times Cited, All Databases": 1261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2014, "Volume": 136, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6083, "End Page": 6091, "Article Number": null, "DOI": "10.1021/ja5017156", "DOI Link": "http://dx.doi.org/10.1021/ja5017156", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335086100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teng, ZY; Zhang, QT; Yang, HB; Kato, K; Yang, WJ; Lu, YR; Liu, SX; Wang, CY; Yamakata, A; Su, CL; Liu, B; Ohno, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teng, Zhenyuan; Zhang, Qitao; Yang, Hongbin; Kato, Kosaku; Yang, Wenjuan; Lu, Ying-Rui; Liu, Sixiao; Wang, Chengyin; Yamakata, Akira; Su, Chenliang; Liu, Bin; Ohno, Teruhisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis offers a promising strategy to produce hydrogen peroxide (H2O2)-an environmentally friendly oxidant and a clean fuel. However, the low activity and selectivity of the two-electron oxygen reduction reaction (ORR) in the photocatalytic process greatly restricts the H2O2 production efficiency. Here we show a robust antimony single-atom photocatalyst (Sb-SAPC, single Sb atoms dispersed on carbon nitride) for the synthesis of H2O2 in a simple water and oxygen mixture under visible light irradiation. An apparent quantum yield of 17.6% at 420 nm together with a solar-to-chemical conversion efficiency of 0.61% for H2O2 synthesis was achieved. On the basis of time-dependent density function theory calculations, isotopic experiments and advanced spectroscopic characterizations, the photocatalytic performance is ascribed to the notably promoted two-electron ORR by forming mu-peroxide at the Sb sites and highly concentrated holes at the neighbouring N atoms. The in situ generated O-2 via water oxidation is rapidly consumed by ORR, leading to boosted overall reaction kinetics. Hydrogen peroxide is an interesting target for artificial photosynthesis, although its actual production via the two-electron oxygen reduction reaction remains limited. Now, a carbon nitride-supported antimony single atom photocatalyst has been developed with a superior performance for this process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 374, "End Page": 384, "Article Number": null, "DOI": "10.1038/s41929-021-00605-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00605-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653054400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, XF; Liu, JW; Fu, L; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Xiaofeng; Liu, Junwei; Fu, Liang; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum spin Hall effect in two-dimensional transition metal dichalcogenides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin Hall (QSH) effect materials feature edge states that are topologically protected from backscattering. However, the small band gap in materials that have been identified as QSH insulators limits applications. We use first-principles calculations to predict a class of large-gap QSH insulators in two-dimensional transition metal dichalcogenides with 1T' structure, namely, 1T'-MX2 with M = (tungsten or molybdenum) and X = (tellurium, selenium, or sulfur). A structural distortion causes an intrinsic band inversion between chalcogenide-p and metal-d bands. Additionally, spin-orbit coupling opens a gap that is tunable by vertical electric field and strain. We propose a topological field effect transistor made of van der Waals heterostructures of 1T'-MX2 and two-dimensional dielectric layers that can be rapidly switched off by electric field through a topological phase transition instead of carrier depletion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1675, "Times Cited, All Databases": 1820, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 12", "Publication Year": 2014, "Volume": 346, "Issue": 6215, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1344, "End Page": 1347, "Article Number": null, "DOI": "10.1126/science.1256815", "DOI Link": "http://dx.doi.org/10.1126/science.1256815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346189600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jing, X; Li, H; Mi, HY; Liu, YJ; Feng, PY; Tan, YM; Turng, LS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jing, Xin; Li, Heng; Mi, Hao-Yang; Liu, Yue-Jun; Feng, Pei-Yong; Tan, Yi-Min; Turng, Lih-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly transparent, stretchable, and rapid self-healing polyvinyl alcohol/cellulose nullofibril hydrogel sensors for sensitive pressure sensing and human motion detection", "Source Title": "SENSORS AND ACTUATORS B-CHEMICAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sensors have emerged as favored novel devices for human healthcare. Current sensors, however, suffer from low sensitivity, non-transparency, and lack of self-healing ability. In this study, we synthesized a polyvinyl alcohol/cellulose nullofibril (PVA/CNF) hydrogel with dual-crosslinked networks for highly transparent, stretchable, and self-healing pressure and strain sensors. The hydrogel contains dynamic borate bonds, metal-carboxylate coordination bonds, and hydrogen bonds, all of which contribute to the hydrogel's superior dimensional stability, mechanical strength and flexibility, and spontaneous self-healing ability as compared to traditional PVA hydrogels. The developed hydrogel has a moderate modulus of 11.2 kPa, and a high elongation rate of 1900%. It spontaneously self-heals within 15 s upon contact without any external stimuli, has a high transmittance of over 90%, and has excellent compatibility with human fibroblasts. The capacitive sensor developed based on the PVA/CNF hydrogel has high sensitivity to very subtle pressure changes, such as small water droplets. When used as a strain sensor, it was capable of detecting and monitoring various human motions such as finger, knee, elbow, and head movements, breathing, and gentle tapping. The developed hydrogel and sensors not only show great potential in electronic skin, personal healthcare, and wearable devices, but may also inspire the development of transparent, intelligent skin-like sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2019, "Volume": 295, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 159, "End Page": 167, "Article Number": null, "DOI": "10.1016/j.snb.2019.05.082", "DOI Link": "http://dx.doi.org/10.1016/j.snb.2019.05.082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469849800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, L; Zhu, Q; Song, SW; McElhenny, B; Wang, DZ; Wu, CZ; Qin, ZJ; Bao, JM; Yu, Y; Chen, S; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Luo; Zhu, Qing; Song, Shaowei; McElhenny, Brian; Wang, Dezhi; Wu, Chunzheng; Qin, Zhaojun; Bao, Jiming; Yu, Ying; Chen, Shuo; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater is one of the most abundant natural resources on our planet. Electrolysis of seawater is not only a promising approach to produce clean hydrogen energy, but also of great significance to seawater desalination. The implementation of seawater electrolysis requires robust and efficient electrocatalysts that can sustain seawater splitting without chloride corrosion, especially for the anode. Here we report a three-dimensional core-shell metal-nitride catalyst consisting of NiFeN nulloparticles uniformly decorated on NiMoN nullorods supported on Ni foam, which serves as an eminently active and durable oxygen evolution reaction catalyst for alkaline seawater electrolysis. Combined with an efficient hydrogen evolution reaction catalyst of NiMoN nullorods, we have achieved the industrially required current densities of 500 and 1000 mA cm(-2) at record low voltages of 1.608 and 1.709 V, respectively, for overall alkaline seawater splitting at 60 degrees C. This discovery significantly advances the development of seawater electrolysis for large-scale hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 985, "Times Cited, All Databases": 1017, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5106, "DOI": "10.1038/s41467-019-13092-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13092-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495393000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shearer, GC; Chavan, S; Bordiga, S; Svelle, S; Olsbye, U; Lillerud, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shearer, Greig C.; Chavan, Sachin; Bordiga, Silvia; Svelle, Stian; Olsbye, Unni; Lillerud, Karl Petter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect Engineering: Tuning the Porosity and Composition of the Metal-Organic Framework UiO-66 via Modulated Synthesis", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when synthesized in the presence of monocarboxylic acid modulators under the most commonly employed conditions. We unequivocally demonstrate that missing cluster defects are the predominullt defect and that their concentration (and thus the porosity and composition of the material) can be tuned to a remarkable extent by altering the concentration and/or acidity of the modulator. Finally, we attempt to rationalize these observations by speculating on the underlying solution chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1032, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2016, "Volume": 28, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3749, "End Page": 3761, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b00602", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b00602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378016400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, PF; Yao, YG; Huang, ZN; Liu, ZY; Zhang, JL; Li, TY; Wang, GF; Shahbazian-Yassar, R; Hu, LB; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Pengfei; Yao, Yonggang; Huang, Zhennull; Liu, Zhenyu; Zhang, Junlei; Li, Tangyuan; Wang, Guofeng; Shahbazian-Yassar, Reza; Hu, Liangbing; Wang, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient decomposition of ammonia using high-entropy alloy catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia represents a promising liquid fuel for hydrogen storage, but its large-scale application is limited by the need for precious metal ruthenium (Ru) as catalyst. Here we report on highly efficient ammonia decomposition using novel high-entropy alloy (HEA) catalysts made of earth abundant elements. Quinary CoMoFeNiCu nulloparticles are synthesized in a single solid-solution phase with robust control over the Co/Mo atomic ratio, including those ratios considered to be immiscible according to the Co-Mo bimetallic phase diagram. These HEA nulloparticles demonstrate substantially enhanced catalytic activity and stability for ammonia decomposition, with improvement factors achieving >20 versus Ru catalysts. Catalytic activity of HEA nulloparticles is robustly tunable by varying the Co/Mo ratio, allowing for the optimization of surface property to maximize the reactivity under different reaction conditions. Our work highlights the great potential of HEAs for catalyzing chemical transformation and energy conversion reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 540, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4011, "DOI": "10.1038/s41467-019-11848-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11848-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483922400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, GP; O'Mullane, AP; Du, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Guoping; O'Mullane, Anthony P.; Du, Aijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D MXenes: A New Family of Promising Catalysts for the Hydrogen Evolution Reaction", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing highly conductive, stable, and active nonprecious hydrogen evolution reaction (HER) catalysts is a key step for the proposed hydrogen economy. However, few catalysts, except for noble metals, meet all the requirements. By using state-of-the-art density functional calculations, herein we demonstrate that 2D MXenes, like Ti2C, V2C, and Ti3C2, are terminated by a mixture of oxygen atoms and hydroxyl, while Nb2C and Nb4C3O2 are fully terminated by oxygen atoms under standard conditions [pH 0, p(H-2) = 1 bar, U = 0 V vs standard hydrogen electrode], findings in good agreement with experimental observation. Furthermore, all these MXenes are conductive under standard conditions, thus allowing high charge transfer kinetics during the HER. Remarkably, the Gibbs free energy for the adsorption of atomic hydrogen (Delta G(H)(0)*) on the terminated O atoms (e.g., Ti2CO2) is close to the ideal value (0 eV). Our results demonstrate terminated oxygens as catalytic active sites for the HER at these materials and highlight a family of promising two-dimensional catalysts for water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 914, "Times Cited, All Databases": 952, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 494, "End Page": 500, "Article Number": null, "DOI": "10.1021/acscatal.6b02754", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b02754", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391783200058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ugeda, MM; Bradley, AJ; Shi, SF; da Jornada, FH; Zhang, Y; Qiu, DY; Ruan, W; Mo, SK; Hussain, Z; Shen, ZX; Wang, F; Louie, SG; Crommie, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ugeda, Miguel M.; Bradley, Aaron J.; Shi, Su-Fei; da Jornada, Felipe H.; Zhang, Yi; Qiu, Diana Y.; Ruan, Wei; Mo, Sung-Kwan; Hussain, Zahid; Shen, Zhi-Xun; Wang, Feng; Louie, Steven G.; Crommie, Michael F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant bandgap renormalization and excitonic effects in a monolayer transition metal dichalcogenide semiconductor", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal dichalcogenides (TMDs) are emerging as a new platform for exploring 2D semiconductor physics(1-9). Reduced screening in two dimensions results in markedly enhanced electron-electron interactions, which have been predicted to generate giant bandgap renormalization and excitonic effects(10-13). Here we present a rigorous experimental observation of extraordinarily large exciton binding energy in a 2D semiconducting TMD. We determine the single-particle electronic bandgap of single-layer MoSe2 by means of scanning tunnelling spectroscopy (STS), as well as the two-particle exciton transition energy using photoluminescence (PL) spectroscopy. These yield an exciton binding energy of 0.55 eV for monolayer MoSe2 on graphene-orders of magnitude larger than what is seen in conventional 3D semiconductors and significantly higher than what we see for MoSe2 monolayers in more highly screening environments. This finding is corroborated by our ab initio GW and Bethe-Salpeter equation calculations(14,15) which include electron correlation effects. The renormalized bandgap and large exciton binding observed here will have a profound impact on electronic and optoelectronic device technologies based on single-layer semiconducting TMDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1528, "Times Cited, All Databases": 1717, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1091, "End Page": 1095, "Article Number": null, "DOI": "10.1038/NMAT4061", "DOI Link": "http://dx.doi.org/10.1038/NMAT4061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345432200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kandambeth, S; Venkatesh, V; Shinde, DB; Kumari, S; Halder, A; Verma, S; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kandambeth, Sharath; Venkatesh, V.; Shinde, Digambar B.; Kumari, Sushma; Halder, Arjun; Verma, Sandeep; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-templated chemically stable hollow spherical covalent organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks are a family of crystalline porous materials with promising applications. Although active research on the design and synthesis of covalent organic frameworks has been ongoing for almost a decade, the mechanisms of formation of covalent organic frameworks crystallites remain poorly understood. Here we report the synthesis of a hollow spherical covalent organic framework with mesoporous walls in a single-step template-free method. A detailed time-dependent study of hollow sphere formation reveals that an inside-out Ostwald ripening process is responsible for the hollow sphere formation. The synthesized covalent organic framework hollow spheres are highly porous (surface area similar to 1,500m(2) g(-1)), crystalline and chemically stable, due to the presence of strong intramolecular hydrogen bonding. These mesoporous hollow sphere covalent organic frameworks are used for a trypsin immobilization study, which shows an uptake of 15.5 mu mol g(-1) of trypsin.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 524, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6786, "DOI": "10.1038/ncomms7786", "DOI Link": "http://dx.doi.org/10.1038/ncomms7786", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353702500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CW; Ping, WW; Bai, Q; Cui, HC; Hensleigh, R; Wang, RL; Brozena, AH; Xu, ZP; Dai, JQ; Pei, Y; Zheng, CL; Pastel, G; Gao, JL; Wang, XZ; Wang, H; Zhao, JC; Yang, B; Zheng, XY; Luo, J; Mo, YF; Dunn, B; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chengwei; Ping, Weiwei; Bai, Qiang; Cui, Huachen; Hensleigh, Ryan; Wang, Ruiliu; Brozena, Alexandra H.; Xu, Zhenpeng; Dai, Jiaqi; Pei, Yong; Zheng, Chaolun; Pastel, Glenn; Gao, Jinlong; Wang, Xizheng; Wang, Howard; Zhao, Ji-Cheng; Yang, Bao; Zheng, Xiaoyu (Rayne); Luo, Jian; Mo, Yifei; Dunn, Bruce; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general method to synthesize and sinter bulk ceramics in seconds", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ceramics are an important class of materials with widespread applications because of their high thermal, mechanical. and chemical stability. Computational predictions based on first principles methods can be a valuable tool in accelerating materials discovery to develop improved ceramics. It is essential to experimentally confirm the material properties of such predictions. However, materials screening rates are limited by the long processing times and the poor compositional control from volatile element loss in conventional ceramic sintering techniques. To overcome these limitations, we developed an ultrafast high-temperature sintering (UHS) process for the fabrication of ceramic materials by radiative heating under an inert atmosphere. We provide several examples of the UHS process to demonstrate its potential utility and applications, including advancements in solid-state electrolytes, mufticomponent structures, and high-throughput materials screening.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2020, "Volume": 368, "Issue": 6490, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 521, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz7681", "DOI Link": "http://dx.doi.org/10.1126/science.aaz7681", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531178400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WY; Yao, HB; Yan, K; Zheng, GY; Liang, Z; Chiang, YM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Weiyang; Yao, Hongbin; Yan, Kai; Zheng, Guangyuan; Liang, Zheng; Chiang, Yet-Ming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and low Coulombic efficiency. Here we demonstrate that the growth of lithium dendrites can be suppressed by exploiting the reaction between lithium and lithium polysulfide, which has long been considered as a critical flaw in lithium-sulfur batteries. We show that a stable and uniform solid electrolyte interphase layer is formed due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-based electrolyte, preventing dendrite growth and minimizing electrolyte decomposition. Our findings allow for re-evaluation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and provide insights into solving the problems associated with lithium metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1668, "Times Cited, All Databases": 1813, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7436, "DOI": "10.1038/ncomms8436", "DOI Link": "http://dx.doi.org/10.1038/ncomms8436", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357176700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Z; Wang, HS; Kong, X; Huang, W; Tsao, YC; Mackanic, DG; Wang, KC; Wang, XC; Huang, WX; Choudhury, S; Zheng, Y; Amanchukwu, CV; Hung, ST; Ma, YT; Lomeli, EG; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhiao; Wang, Hansen; Kong, Xian; Huang, William; Tsao, Yuchi; Mackanic, David G.; Wang, Kecheng; Wang, Xinchang; Huang, Wenxiao; Choudhury, Snehashis; Zheng, Yu; Amanchukwu, Chibueze, V; Hung, Samantha T.; Ma, Yuting; Lomeli, Eder G.; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering is critical for developing Li metal batteries. While recent works improved Li metal cyclability, a methodology for rational electrolyte design remains lacking. Herein, we propose a design strategy for electrolytes that enable anode-free Li metal batteries with single-solvent single-salt formations at standard concentrations. Rational incorporation of -CF2- units yields fluorinated 1,4-dimethoxylbutane as the electrolyte solvent. Paired with 1 M lithium bis(fluorosulfonyl)imide, this electrolyte possesses unique Li-F binding and high anion/solvent ratio in the solvation sheath, leading to excellent compatibility with both Li metal anodes (Coulombic efficiency similar to 99.52% and fast activation within five cycles) and high-voltage cathodes (similar to 6 V stability). Fifty-mu m-thick Li|NMC batteries retain 90% capacity after 420 cycles with an average Coulombic efficiency of 99.98%. Industrial anode-free pouch cells achieve similar to 325 Wh kg(-1)single-cell energy density and 80% capacity retention after 100 cycles. Our design concept for electrolytes provides a promising path to high-energy, long-cycling Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 823, "Times Cited, All Databases": 858, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": 533, "Article Number": null, "DOI": "10.1038/s41560-020-0634-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0634-5", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542060100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SN; Dong, GH; Hailili, R; Yang, LP; Li, YX; Wang, F; Zeng, YB; Wang, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shuna; Dong, Guohui; Hailili, Reshalaiti; Yang, Liping; Li, Yingxuan; Wang, Fu; Zeng, Yubin; Wang, Chuanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective photocatalytic H2O2 production under visible light irradiation at g-C3N4 modulated by carbon vacancies", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is of great significance in biological and environmental processes as well as in chemical industry. Even though anthraquinone autoxidation (AO) process has been the major artificial way to produce H2O2, its energy cost and non-green nature have been motivating people to develop more efficient, economic and green technologies as alternatives. Here we demonstrated that photocatalytic H2O2 production at g-C3N4 could be improved by as much as 14 times in the absence of organic scavenger through a carbon vacancy-based strategy. Both the experimental and theoretical calculation results indicated that the creation of carbon vacancies could reduce the symmetry of g-C3N4 and produce the effect of electron delocalization. This will allow g-C3N4 to possess more excitable electrons and a narrower band gap. On the other hand, carbon vacancies provided more sites to adsorb molecular oxygen and thereby help electrons transfer from g-C3N4 to the surface adsorbed O-2. More interestingly, the presence of carbon vacancies changed the H2O2 generation pathway from a two-step single-electron indirect reduction to an one-step two-electron direct reduction. This study could not only develop a novel strategy to improve the H2O2 production activity of semiconductors, but also shed light on the deep understanding of the role played by surface defect structure on photocatalytic activity of semiconductor photocatalysts. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 564, "Times Cited, All Databases": 589, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2016, "Volume": 190, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26, "End Page": 35, "Article Number": null, "DOI": "10.1016/j.apcatb.2016.03.004", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2016.03.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374604900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, GF; Darmawan, P; Cui, MQ; Wang, JX; Chen, JW; Magdassi, S; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Guofa; Darmawan, Peter; Cui, Mengqi; Wang, Jiangxin; Chen, Jingwei; Magdassi, Shlomo; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitors", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silver grids are attractive for replacing indium tin oxide as flexible transparent conductors. This work aims to improve the electrochemical stability of silver-based transparent conductors. A silver grid/PEDOT:PSS hybrid film with high conductivity and excellent stability is successfully fabricated. Its functionality for flexible electrochromic applications is demonstrated by coating one layer of WO3 nulloparticles on the silver grid/PEDOT:PSS hybrid film. This hybrid structure presents a large optical modulation of 81.9% at 633 nm, fast switching, and high coloration efficiency (124.5 cm(2) C-1). More importantly, an excellent electrochemical cycling stability (sustaining 79.1% of their initial transmittance modulation after 1000 cycles) and remarkable mechanical flexibility (optical modulation decay of only 7.5% after 1200 compressive bending cycles) is achieved. A novel smart supercapacitor is presented that functions as a regular energy-storage device and simultaneously monitors the level of stored energy by a rapid and reversible color variation even at high current charge/discharge conditions. The film sustains an optical modulation of 87.7% and a specific capacitance of 67.2% at 10 A g(-1) compared to their initial value at a current density of 1 A g(-1). The high-performance silver grid/PEDOT:PSS hybrid transparent films exhibit promising features for various emerging flexible electronics and optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2016, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501882, "DOI": "10.1002/aenm.201501882", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501882", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371147000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yakunin, S; Protesescu, L; Krieg, F; Bodnarchuk, MI; Nedelcu, G; Humer, M; De Luca, G; Fiebig, M; Heiss, W; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska; Bodnarchuk, Maryna I.; Nedelcu, Georgian; Humer, Markus; De Luca, Gabriele; Fiebig, Manfred; Heiss, Wolfgang; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-threshold amplified spontaneous emission and lasing from colloidal nullocrystals of caesium lead halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide semiconductors with perovskite crystal structures have recently emerged as highly promising optoelectronic materials. Despite the recent surge of reports on microcrystalline, thin-film and bulk single-crystalline metal halides, very little is known about the photophysics of metal halides in the form of uniform, size-tunable nullocrystals. Here we report low-threshold amplified spontaneous emission and lasing from similar to 10nm monodisperse colloidal nullocrystals of caesium lead halide perovskites CsPbX3 (X = Cl, Br or I, or mixed Cl/Br and Br/I systems). We find that room-temperature optical amplification can be obtained in the entire visible spectral range (440-700 nm) with low pump thresholds down to 5 +/- 1 mu J cm(-2) and high values of modal net gain of at least 450 +/- 30 cm(-1). Two kinds of lasing modes are successfully observed: whispering-gallery-mode lasing using silica microspheres as high-finesse resonators, conformally coated with CsPbX3 nullocrystals and random lasing in films of CsPbX3 nullocrystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1310, "Times Cited, All Databases": 1406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8056, "DOI": "10.1038/ncomms9056", "DOI Link": "http://dx.doi.org/10.1038/ncomms9056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360352600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DY; Zhang, DZ; Li, P; Yang, ZM; Mi, QA; Yu, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongyue; Zhang, Dongzhi; Li, Peng; Yang, Zhimin; Mi, Qian; Yu, Liandong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrospinning of Flexible Poly(vinyl alcohol)/MXene nullofiber-Based Humidity Sensor Self-Powered by Monolayer Molybdenum Diselenide Piezoelectric nullogenerator", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional material has been widely investigated for potential applications in sensor and flexible electronics. In this work, a self-powered flexible humidity sensing device based on poly(vinyl alcohol)/Ti3C2Tx (PVA/MXene) nullofibers film and monolayer molybdenum diselenide (MoSe2) piezoelectric nullogenerator (PENG) was reported for the first time. The monolayer MoSe2-based PENG was fabricated by atmospheric pressure chemical vapor deposition techniques, which can generate a peak output of 35 mV and a power density of 42 mW m(-2). The flexible PENG integrated on polyethylene terephthalate (PET) substrate can harvest energy generated by different parts of human body and exhibit great application prospects in wearable devices. The electrospinned PVA/MXene nullofiber-based humidity sensor with flexible PET substrate under the driven of monolayer MoSe2 PENG, shows high response of similar to 40, fast response/recovery time of 0.9/6.3 s, low hysteresis of 1.8% and excellent repeatability. The self-powered flexible humidity sensor yields the capability of detecting human skin moisture and ambient humidity. This work provides a pathway to explore the high-performance humidity sensor integrated with PENG for the self-powered flexible electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57, "DOI": "10.1007/s40820-020-00580-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00580-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609817400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Zhang, W; Zheng, WT; Cui, XQ; Rojo, T; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dong; Zhang, Wei; Zheng, Weitao; Cui, Xiaoqiang; Rojo, Teofilo; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards High-Safe Lithium Metal Anodes: Suppressing Lithium Dendrites via Tuning Surface Energy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of lithium dendrites induces the notorious safety issue and poor cycling life of energy storage devices, such as lithium-sulfur and lithium-air batteries. We propose a surface energy model to describe the complex interface between the lithium anode and electrolyte. A universal strategy of hindering formation of lithium dendrites via tuning surface energy of the relevant thin film growth is suggested. The merit of the novel motif lies not only fundamentally a perfect correlation between electrochemistry and thin film fields, but also significantly promotes larger-scale application of lithium-sulfur and lithium-air batteries, as well as other metal batteries (e.g., Zn, Na, K, Cu, Ag, and Sn).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 514, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600168, "DOI": "10.1002/advs.201600168", "DOI Link": "http://dx.doi.org/10.1002/advs.201600168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392400200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Q; Rosen, J; Zhou, Y; Hutchings, GS; Kimmel, YC; Chen, JGG; Jiao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Qi; Rosen, Jonathan; Zhou, Yang; Hutchings, Gregory S.; Kimmel, Yannick C.; Chen, Jingguang G.; Jiao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A selective and efficient electrocatalyst for carbon dioxide reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Converting carbon dioxide to useful chemicals in a selective and efficient manner remains a major challenge in renewable and sustainable energy research. Silver is an interesting electrocatalyst owing to its capability of converting carbon dioxide to carbon monoxide selectively at room temperature; however, the traditional polycrystalline silver electrocatalyst requires a large overpotential. Here we report a nulloporous silver electrocatalyst that is able to electrochemically reduce carbon dioxide to carbon monoxide with approximately 92% selectivity at a rate (that is, current) over 3,000 times higher than its polycrystalline counterpart under moderate overpotentials of <0.50V. The high activity is a result of a large electrochemical surface area (approximately 150 times larger) and intrinsically high activity (approximately 20 times higher) compared with polycrystalline silver. The intrinsically higher activity may be due to the greater stabilization of CO2- intermediates on the highly curved surface, resulting in smaller overpotentials needed to overcome the thermodynamic barrier.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1305, "Times Cited, All Databases": 1435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3242, "DOI": "10.1038/ncomms4242", "DOI Link": "http://dx.doi.org/10.1038/ncomms4242", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331143500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Chen, Y; Fang, YJ; Zhang, JT; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiao; Chen, Ye; Fang, Yongjin; Zhang, Jintao; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Cobalt Sulfide Multi-shelled nulloboxes with Precisely Controlled Two to Five Shells for Sodium-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the synthesis of cobalt sulfide multi-shelled nulloboxes through metal-organic framework (MOF)-based complex anion conversion and exchange processes. The polyvanadate ions react with cobalt-based zeolitic imidazolate framework-67 (ZIF-67) nullocubes to form ZIF-67/cobalt polyvanadate yolk-shelled particles. The as-formed yolk-shelled particles are gradually converted into cobalt divanadate multi-shelled nulloboxes by solvothermal treatment. The number of shells can be easily controlled from 2 to 5 by varying the temperature. Finally, cobalt sulfide multi-shelled nulloboxes are produced through ion-exchange with S2- ions and subsequent annealing. The as-obtained cobalt sulfide multi-shelled nulloboxes exhibit enhanced sodium-storage properties when evaluated as anodes for sodium-ion batteries. For example, a high specific capacity of 438 mAhg(-1) can be retained after 100 cycles at the current density of 500 mAg(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2019, "Volume": 58, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2675, "End Page": 2679, "Article Number": null, "DOI": "10.1002/anie.201812387", "DOI Link": "http://dx.doi.org/10.1002/anie.201812387", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459807200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jabbari, V; Veleta, JM; Zarei-Chaleshtori, M; Gardea-Torresdey, J; Villagrán, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jabbari, V.; Veleta, J. M.; Zarei-Chaleshtori, M.; Gardea-Torresdey, J.; Villagran, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of magnetic MOF@GO and MOF@CNT hybrid nullocomposites with high adsorption capacity towards organic pollutants", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid nullocomposites based on Cu-BTC MOF, graphene oxide (GO), carbon nullotubes (CNTs), and Fe3O4 magnetic nulloparticles (MNPs) were developed via a simple green solvothermal method, at which GO and 'CNT were used as platforms to load nullostructured Cu-BTC MOF and Fe3O4 MNPs. The as synthesized hybrid nullocomposites were characterized by XRD, SEM, TEM, XPS, IR, Raman, TGA, and BET techniques. XRD measurements show highly crystalline structures for the prepared hybrid nullocomposites. Morphological analyses carried out by SEM and TEM also confirm successful growth of Fe3O4 MNPs and nulloparticulate Cu-BTC MOF over the carbon-based platforms. Chemical, elemental, and TGA analyses verify chemical bonding and successful compositing of the parent materials. Nitrogen isotherms show a cumulative pore volume of 0.360 cm(3) g(-1) for the hybrid nullocomposite of Fe3O4/Cu-BTC@GO compared to 0.030 cm(3) g(-1), of the sole Cu-BTC MOF, which suggests potential uses towards small molecule adsorption. We have found that use of GO and CNT substrates (i) diminish the aggregation and increases dispersive forces within the MOFs, (ii) lead to MOFs with different morphology and size, and (iii) result in formation of small pores between the MOF and the platforms. Adsorption capacity of the prepared nullomaterials was examined over methylene blue (MB) as a model organic pollutant. The developed hybrid nullomaterials show enhanced pollutant adsorption capacity compared to that of the parent materials. The improved adsorption capacity is attributed to the synergetic effect of covalent bonding between the parent materials as well as to the unique. features of the nulloscale MOF. Overall, these novel materials may be considered as excellent candidates towards a variety of environmental applications such as water remediation. (C) 2016 Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2016, "Volume": 304, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 774, "End Page": 783, "Article Number": null, "DOI": "10.1016/j.cej.2016.06.034", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2016.06.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384777200086", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, FD; Zhu, YZ; He, XF; Mo, YF; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Fudong; Zhu, Yizhou; He, Xingfeng; Mo, Yifei; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Stability of Li10GeP2S12 and Li7La3Zr2O12 Solid Electrolytes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical stability window of solid electrolyte is overestimated by the conventional experimental method using a Li/electrolyte/inert metal semiblocking electrode because of the limited contact area between solid electrolyte and inert metal. Since the battery is cycled in the overestimated stability window, the decomposition of the solid electrolyte at the interfaces occurs but has been ignored as a cause for high interfacial resistances in previous studies, limiting the performance improvement of the bulk-type solid-state battery despite the decades of research efforts. Thus, there is an urgent need to identify the intrinsic stability window of the solid electrolyte. The thermodynamic electrochemical stability window of solid electrolytes is calculated using first principles computation methods, and an experimental method is developed to measure the intrinsic electrochemical stability window of solid electrolytes using a Li/electrolyte/electrolyte-carbon cell. The most promising solid electrolytes, Li10GeP2S12 and cubic Li-garnet Li7La3Zr2O12, are chosen as the model materials for sulfide and oxide solid electrolytes, respectively. The results provide valuable insights to address the most challenging problems of the interfacial stability and resistance in high-performance solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 911, "Times Cited, All Databases": 988, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2016, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501590, "DOI": "10.1002/aenm.201501590", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501590", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374703900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZN; Zhang, H; Lu, SB; Wang, ZT; Tang, SY; Shao, JD; Sun, ZB; Xie, HH; Wang, HY; Yu, XF; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhinull; Zhang, Han; Lu, Shunbin; Wang, Zhiteng; Tang, Siying; Shao, Jundong; Sun, Zhengbo; Xie, Hanhan; Wang, Huaiyu; Yu, Xue-Feng; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From Black Phosphorus to Phosphorene: Basic Solvent Exfoliation, Evolution of Raman Scattering, and Applications to Ultrafast Photonics", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although phosphorene has attracted much attention in electronics and optoelectronics as a new type of two-dimensional material, in-depth investigations and applications have been limited by the current synthesis techniques. Herein, a basic N-methyl-2-pyrrolidone (NMP) liquid exfoliation method is described to produce phosphorene with excellent water stability, controllable size and layer number, as well as in high yield. Phosphorene samples composed of one to four layers exhibit layer-dependent Raman scattering characteristics thus providing a fast and efficient means for the in situ determination of the thickness (layer number) of phosphorene. The linear and nonlinear ultrafast absorption behavior of the as-exfoliated phosphorene is investigated systematically by UV-vis-NIR absorption and Z-scan measurements. By taking advantage of their unique nonlinear absorption, ultrashort pulse generation applicable to optical saturable absorbers is demonstrated. In addition to a unique fabrication technique, our work also reveals the large potential of phosphorene in ultrafast photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 915, "Times Cited, All Databases": 970, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2015, "Volume": 25, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6996, "End Page": 7002, "Article Number": null, "DOI": "10.1002/adfm.201502902", "DOI Link": "http://dx.doi.org/10.1002/adfm.201502902", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366502900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, YB; Giri, G; Ayzner, AL; Zoombelt, AP; Mannsfeld, SCB; Chen, JH; Nordlund, D; Toney, MF; Huang, JS; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Yongbo; Giri, Gaurav; Ayzner, Alexander L.; Zoombelt, Arjan P.; Mannsfeld, Stefan C. B.; Chen, Jihua; Nordlund, Dennis; Toney, Michael F.; Huang, Jinsong; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high mobility transparent organic thin film transistors grown by an off-centre spin-coating method", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic semiconductors with higher carrier mobility and better transparency have been actively pursued for numerous applications, such as flat-panel display backplane and sensor arrays. The carrier mobility is an important figure of merit and is sensitively influenced by the crystallinity and the molecular arrangement in a crystal lattice. Here we describe the growth of a highly aligned meta-stable structure of 2,7-dioctyl[1]benzothieno[3,2-b][1] benzothiophene (C8-BTBT) from a blended solution of C8-BTBT and polystyrene by using a novel off-centre spin-coating method. Combined with a vertical phase separation of the blend, the highly aligned, meta-stable C8-BTBT films provide a significantly increased thin film transistor hole mobility up to 43 cm(2)Vs(-1) (25 cm(2)Vs(-1) on average), which is the highest value reported to date for all organic molecules. The resulting transistors show high transparency of >90% over the visible spectrum, indicating their potential for transparent, high-performance organic electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 919, "Times Cited, All Databases": 932, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3005, "DOI": "10.1038/ncomms4005", "DOI Link": "http://dx.doi.org/10.1038/ncomms4005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331082900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, MZ; Zhou, W; Tavakoli, H; Bautista, C; Xia, JF; Wang, ZH; Li, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Mengzhen; Zhou, Wan; Tavakoli, Hamed; Bautista, Cynthia; Xia, Jianfei; Wang, Zonghua; Li, XiuJun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aptamer-functionalized metal-organic frameworks (MOFs) for biosensing", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a class of crystalline porous materials, metal-organic frameworks (MOFs) have attracted increasing attention. Due to the nulloscale framework structure, adjustable pore size, large specific surface area, and good chemical stability, MOFs have been applied widely in many fields such as biosensors, biomedicine, electrocatalysis, energy storage and conversions. Especially when they are combined with aptamer functionalization, MOFs can be utilized to construct high-performance biosensors for numerous applications ranging from medical diagnostics and food safety inspection, to environmental surveillance. Herein, this article reviews recent innovations of aptamer-functionalized MOFs-based biosensors and their bio-applications. We first briefly introduce different functionalization methods of MOFs with aptamers, which provide a foundation for the construction of MOFsbased aptasensors. Then, we comprehensively summarize different types of MOFs-based aptasensors and their applications, in which MOFs serve as either signal probes or signal probe carriers for optical, electrochemical, and photoelectrochemical detection, with an emphasis on the former. Given recent substantial research interests in stimuli-responsive materials and the microfluidic lab-on-a-chip technology, we also present the stimuli responsive aptamer-functionalized MOFs for sensing, followed by a brief overview on the integration of MOFs on microfluidic devices. Current limitations and prospective trends of MOFs-based biosensors are discussed at the end.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 176, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112947, "DOI": "10.1016/j.bios.2020.112947", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2020.112947", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612675000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, QH; Brocks, G; Bieberle-Hutter, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Qiuhua; Brocks, Geert; Bieberle-Hutter, Anja", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen evolution reaction (OER) mechanism under alkaline and acidic conditions", "Source Title": "JOURNAL OF PHYSICS-ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Density functional theory (DFT) simulations of the oxygen evolution reaction (OER) are considered essential for understanding the limitations of water splitting. Most DFT calculations of the OER use an acidic reaction mechanism and the standard hydrogen electrode (SHE) as reference electrode. However, experimental studies are usually carried out under alkaline conditions using the reversible hydrogen electrode (RHE) as reference electrode. The difference between the conditions in experiment and calculations is then usually taken into account by applying a pH-dependent correction factor to the latter. As, however, the OER reaction mechanisms under acidic and under alkaline conditions are quite different, it is not clear a priori whether a simple correction factor can account for this difference. We derive in this paper step by step the theory to simulate the OER based on the alkaline reaction mechanism and explain the OER process with this mechanism and the RHE as reference electrode. We compare the mechanisms for alkaline and acidic OER catalysis and highlight the roles of the RHE and the SHE. Our detailed analysis validates current OER simulations in the literature and explains the differences in OER calculations with acidic and alkaline mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26001, "DOI": "10.1088/2515-7655/abdc85", "DOI Link": "http://dx.doi.org/10.1088/2515-7655/abdc85", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629535000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JJ; Li, R; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Junjun; Li, Rui; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Dots: A New Type of Carbon-Based nullomaterial with Wide Applications", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots (CDs), as a new type of carbon-based nullomaterial, have attracted broad research interest for years, because of their diverse physicochemical properties and favorable attributes like good biocompatibility, unique optical properties, low cost, ecofriendliness, abundant functional groups (e.g., amino, hydroxyl, carboxyl), high stability, and electron mobility. In this Outlook, we comprehensively summarize the classification of CDs based on the analysis of their formation mechanism, micro-/nullostructure and property features, and describe their synthetic methods and optical properties including strong absorption, photoluminescence, and phosphorescence. Furthermore, the recent significant advances in diverse applications, including optical (sensor, anticounterfeiting), energy (light-emitting diodes, catalysis, photovoltaics, supercapacitors), and promising biomedicine, are systematically highlighted. Finally, we envisage the key issues to be challenged, future research directions, and perspectives to show a full picture of CDs-based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1163, "Times Cited, All Databases": 1193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2020, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2179, "End Page": 2195, "Article Number": null, "DOI": "10.1021/acscentsci.0c01306", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c01306", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000603399200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JS; Wang, Y; Liu, CH; Li, SL; Wang, YG; Dong, LZ; Dai, ZH; Li, YF; Lan, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ji-Sen; Wang, Yu; Liu, Chun-Hui; Li, Shun-Li; Wang, Yu-Guang; Dong, Long-Zhang; Dai, Zhi-Hui; Li, Ya-Fei; Lan, Ya-Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupled molybdenum carbide and reduced graphene oxide electrocatalysts for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting is one of the most economical and sustainable methods for large-scale hydrogen production. However, the development of low-cost and earth-abundant non-noble-metal catalysts for the hydrogen evolution reaction remains a challenge. Here we report a two-dimensional coupled hybrid of molybdenum carbide and reduced graphene oxide with a ternary polyoxometalate-polypyrrole/reduced graphene oxide nullocomposite as a precursor. The hybrid exhibits outstanding electrocatalytic activity for the hydrogen evolution reaction and excellent stability in acidic media, which is, to the best of our knowledge, the best among these reported non-noble-metal catalysts. Theoretical calculations on the basis of density functional theory reveal that the active sites for hydrogen evolution stem from the pyridinic nitrogens, as well as the carbon atoms, in the graphene. In a proof-of-concept trial, an electrocatalyst for hydrogen evolution is fabricated, which may open new avenues for the design of nullomaterials utilizing POMs/conducting polymer/reduced-graphene oxide nullocomposites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 950, "Times Cited, All Databases": 983, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11204, "DOI": "10.1038/ncomms11204", "DOI Link": "http://dx.doi.org/10.1038/ncomms11204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373478700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, A; Madden, DG; Lusi, M; Chen, KJ; Daniels, EA; Curtin, T; Perry, JJ; Zaworotko, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Amrit; Madden, David G.; Lusi, Matteo; Chen, Kai-Jie; Daniels, Emma A.; Curtin, Teresa; Perry, John J.; Zaworotko, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Air Capture of CO2 by Physisorbent Materials", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sequestration of CO2, either from gas mixtures or directly from air (direct air capture, DAC), could mitigate carbon emissions. Here five materials are investigated for their ability to adsorb CO2 directly from air and other gas mixtures. The sorbents studied are benchmark materials that encompass four types of porous material, one chemisorbent, TEPA-SBA-15 (amine-modified mesoporous silica) and four physisorbents: Zeolite 13X (inorganic); HKUST-1 and Mg-MOF-74/Mg-dobdc (metal-organic frameworks, MOFs); SIFSIX-3-Ni, (hybrid ultramicroporous material). Temperature-programmed desorption (TPD) experiments afforded information about the contents of each sorbent under equilibrium conditions and their ease of recycling. Accelerated stability tests addressed projected shelf-life of the five sorbents. The four physisorbents were found to be capable of carbon capture from CO2-rich gas mixtures, but competition and reaction with atmospheric moisture significantly reduced their DAC performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 432, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2015, "Volume": 54, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14372, "End Page": 14377, "Article Number": null, "DOI": "10.1002/anie.201506952", "DOI Link": "http://dx.doi.org/10.1002/anie.201506952", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367724000029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, C; Wu, MH; He, DS; Pei, YL; Wu, CF; Wu, XF; Yu, HL; Zhu, FY; Wang, KD; Chen, Y; Huang, L; Li, JF; He, JQ; Zhao, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Cheng; Wu, Minghui; He, Dongsheng; Pei, Yanling; Wu, Chao-Feng; Wu, Xuefeng; Yu, Hulei; Zhu, Fangyuan; Wang, Kedong; Chen, Yue; Huang, Li; Li, Jing-Feng; He, Jiaqing; Zhao, Li-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D charge and 2D phonon transports leading to high out-of-plane ZT in n-type SnSe crystals", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric technology enables the harvest of waste heat and its direct conversion into electricity. The conversion efficiency is determined by the materials figure of merit ZT. Here we show a maximum ZT of similar to 2.8 +/- 0.5 at 773 kelvin in n-type tin selenide (SnSe) crystals out of plane. The thermal conductivity in layered SnSe crystals is the lowest in the out-of-plane direction [two-dimensional (2D) phonon transport]. We doped SnSe with bromine to make n-type SnSe crystals with the overlapping interlayer charge density (3D charge transport). A continuous phase transition increases the symmetry and diverges two converged conduction bands. These two factors improve carrier mobility, while preserving a large Seebeck coefficient. Our findings can be applied in 2D layered materials and provide a new strategy to enhance out-of-plane electrical transport properties without degrading thermal properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 960, "Times Cited, All Databases": 1009, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2018, "Volume": 360, "Issue": 6390, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 778, "End Page": 782, "Article Number": null, "DOI": "10.1126/science.aaq1479", "DOI Link": "http://dx.doi.org/10.1126/science.aaq1479", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432473500046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, C; Jiao, Y; Shi, BY; Liu, JN; Xie, ZH; Chen, X; Zhang, Q; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Cheng; Jiao, Yan; Shi, Bingyang; Liu, Jia-Ning; Xie, Zhenhua; Chen, Xiao; Zhang, Qiang; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination Tunes Selectivity: Two-Electron Oxygen Reduction on High-Loading Molybdenum Single-Atom Catalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have great potential in electrocatalysis. Their performance can be rationally optimized by tailoring the metal atoms, adjacent coordinative dopants, and metal loading. However, doing so is still a great challenge because of the limited synthesis approach and insufficient understanding of the structure-property relationships. Herein, we report a new kind of Mo SAC with a unique O,S coordination and a high metal loading over 10 wt %. The isolation and local environment was identified by high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure. The SACs catalyze the oxygen reduction reaction (ORR) via a 2 e(-) pathway with a high H2O2 selectivity of over 95 % in 0.10 m KOH. The critical role of the Mo single atoms and the coordination structure was revealed by both electrochemical tests and theoretical calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2020, "Volume": 59, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9171, "End Page": 9176, "Article Number": null, "DOI": "10.1002/anie.202003842", "DOI Link": "http://dx.doi.org/10.1002/anie.202003842", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000524335500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hunt, ST; Milina, M; Alba-Rubio, AC; Hendon, CH; Dumesic, JA; Román-Leshkov, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hunt, Sean T.; Milina, Maria; Alba-Rubio, Ana C.; Hendon, Christopher H.; Dumesic, James A.; Roman-Leshkov, Yuriy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembly of noble metal monolayers on transition metal carbide nulloparticle catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrated the self-assembly of transition metal carbide nulloparticles coated with atomically thin noble metal monolayers by carburizing mixtures of noble metal salts and transition metal oxides encapsulated in removable silica templates. This approach allows for control of the final core-shell architecture, including particle size, monolayer coverage, and heterometallic composition. Carbon-supported Ti0.1W0.9C nulloparticles coated with Pt or bimetallic PtRu monolayers exhibited enhanced resistance to sintering and CO poisoning, achieving an order of magnitude increase in specific activity over commercial catalysts for methanol electrooxidation after 10,000 cycles. These core-shell materials provide a new direction to reduce the loading, enhance the activity, and increase the stability of noble metal catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 509, "Times Cited, All Databases": 534, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2016, "Volume": 352, "Issue": 6288, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 974, "End Page": 978, "Article Number": null, "DOI": "10.1126/science.aad8471", "DOI Link": "http://dx.doi.org/10.1126/science.aad8471", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376147800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Dar, MI; Ono, LK; Zhang, TY; Kan, M; Li, YW; Zhang, LJ; Wang, XT; Yang, YG; Gao, XY; Qi, YB; Grätzel, M; Zhao, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yong; Dar, M. Ibrahim; Ono, Luis K.; Zhang, Taiyang; Kan, Miao; Li, Yawen; Zhang, Lijun; Wang, Xingtao; Yang, Yingguo; Gao, Xingyu; Qi, Yabing; Gratzel, Michael; Zhao, Yixin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamically stabilized β-CsPbI3-based perovskite solar cells with efficiencies >18%", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although beta-CsPbI3 has a bandgap favorable for application in tandem solar cells, depositing and stabilizing beta-CsPbI3 experimentally has remained a challenge. We obtained highly crystalline beta-CsPbI3 films with an extended spectral response and enhanced phase stability. Synchrotron-based x-ray scattering revealed the presence of highly oriented beta-CsPbI3 grains, and sensitive elemental analyses-including inductively coupled plasma mass spectrometry and time-of-flight secondary ion mass spectrometry-confirmed their all-inorganic composition. We further mitigated the effects of cracks and pinholes in the perovskite layer by surface treating with choline iodide, which increased the charge-carrier lifetime and improved the energy-level alignment between the beta-CsPbI3 absorber layer and carrier-selective contacts. The perovskite solar cells made from the treated material have highly reproducible and stable efficiencies reaching 18.4% under 45 +/- 5 degrees C ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1035, "Times Cited, All Databases": 1070, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2019, "Volume": 365, "Issue": 6453, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 591, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav8680", "DOI Link": "http://dx.doi.org/10.1126/science.aav8680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483195200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, LL; Liu, XJ; Chen, JP; Lin, RQ; Liu, HX; Lü, F; Bak, S; Liang, ZX; Zhao, SZ; Stavitski, E; Luo, J; Adzic, RR; Xin, HLL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Lili; Liu, Xijun; Chen, Jinping; Lin, Ruoqian; Liu, Haoxuan; Lue, Fang; Bak, Seongmin; Liang, Zhixiu; Zhao, Shunzheng; Stavitski, Eli; Luo, Jun; Adzic, Radoslav R.; Xin, Huolin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NH3 synthesis by the electrocatalytic N-2 reduction reaction (NRR) under ambient conditions is an appealing alternative to the currently employed industrial method-the Haber-Bosch process-that requires high temperature and pressure. We report single Mo atoms anchored to nitrogen-doped porous carbon as a cost-effective catalyst for the NRR. Benefiting from the optimally high density of active sites and hierarchically porous carbon frameworks, this catalyst achieves a high NH3 yield rate (34.0 +/- 3.6 mu gNH3 h(-1) mg(cat.)(-1)) and a high Faradaic efficiency (14.6 +/- 1.6 %) in 0.1 m KOH at room temperature. These values are considerably higher compared to previously reported non-precious-metal electrocatalysts. Moreover, this catalyst displays no obvious current drop during a 50 000 s NRR, and high activity and durability are achieved in 0.1 m HCl. The findings provide a promising lead for the design of efficient and robust single-atom non-precious-metal catalysts for the electrocatalytic NRR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 612, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2019, "Volume": 58, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2321, "End Page": 2325, "Article Number": null, "DOI": "10.1002/anie.201811728", "DOI Link": "http://dx.doi.org/10.1002/anie.201811728", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458417700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ramalingam, V; Varadhan, P; Fu, HC; Kim, H; Zhang, DL; Chen, SM; Song, L; Ma, D; Wang, Y; Alshareef, HN; He, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ramalingam, Vinoth; Varadhan, Purushothaman; Fu, Hui-Chun; Kim, Hyunho; Zhang, Daliang; Chen, Shuangming; Song, Li; Ma, Ding; Wang, Yun; Alshareef, Husam N.; He, Jr-Hau", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A titanium carbide (Ti3C2Tx) MXene is employed as an efficient solid support to host a nitrogen (N) and sulfur (S) coordinated ruthenium single atom (Ru-SA) catalyst, which displays superior activity toward the hydrogen evolution reaction (HER). X-ray absorption fine structure spectroscopy and aberration corrected scanning transmission electron microscopy reveal the atomic dispersion of Ru on the Ti3C2Tx MXene support and the successful coordination of Ru-SA with the N and S species on the Ti3C2Tx MXene. The resultant Ru-SA-N-S-Ti3C2Tx catalyst exhibits a low overpotential of 76 mV to achieve the current density of 10 mA cm(-2). Furthermore, it is shown that integrating the Ru-SA-N-S-Ti3C2Tx catalyst on n(+)np(+)-Si photocathode enables photoelectrochemical hydrogen production with exceptionally high photocurrent density of 37.6 mA cm(-2) that is higher than the reported precious Pt and other noble metals catalysts coupled to Si photocathodes. Density functional theory calculations suggest that Ru-SA coordinated with N and S sites on the Ti3C2Tx MXene support is the origin of this enhanced HER activity. This work would extend the possibility of using the MXene family as a solid support for the rational design of various single atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 423, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 31, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903841, "DOI": "10.1002/adma.201903841", "DOI Link": "http://dx.doi.org/10.1002/adma.201903841", "Book DOI": null, "Early Access Date": "OCT 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490755400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, CL; Wang, YS; Zhang, YC; Tan, LW; Qian, Y; Tao, Y; Xiong, SL; Feng, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Chuanliang; Wang, Yusheng; Zhang, Yuchan; Tan, Liwen; Qian, Yi; Tao, Yuan; Xiong, Shenglin; Feng, Jinkui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and stable 3D lithium metal anodes based on self-standing MXene/COF frameworks for high-performance lithium-sulfur batteries", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal (Li) is believed to be the ultimate anode for lithium-ion batteries (LIBs) owing to the advantages of high theoretical capacity, the lowest electrochemical potential, and light weight. Nevertheless, issues such as uncontrollable growth of Li dendrites, large volume changes, high chemical reactivity, and unstable solid electrolyte interphase (SEI) hinder its rapid development and practical application. Herein a stable and dendrite-free Li-metal anode is obtained by designing a flexible and freestanding MXene/COF framework for metallic Li. COF-LZU1 microspheres are distributed among the MXene film framework. Lithiophilic COF-LZU1 microspheres as nucleation seeds can promote uniform Li nucleation by homogenizing the Li+ flux and lowering the nucleation barrier, finally resulting in dense and dendrite-free U deposition. Under the regulation of the COF-LZU1 seeds, the Coulombic efficiency of the MXene/COF-LZU1 framework and electrochemical stability of corresponding symmetric cells are obviously enhanced. Li-S full cells with the modified Li-metal anode and sulfurizecl polyacrylonitrile (S@PAN) cathode also exhibited a superior electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 3576, "End Page": 3584, "Article Number": null, "DOI": "10.1007/s12274-021-3433-9", "DOI Link": "http://dx.doi.org/10.1007/s12274-021-3433-9", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637476400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasool, K; Helal, M; Ali, A; Ren, CE; Gogotsi, Y; Mahmoud, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasool, Kashif; Helal, Mohamed; Ali, Adnull; Ren, Chang E.; Gogotsi, Yury; Mahmoud, Khaled A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial Activity of Ti3C2Tx MXene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a family of atomically thin, two-dimensional (2D) transition metal carbides and carbonitrides with many attractive properties. Two-dimensional Ti3C2TX (MXene) has been recently explored for applications in water desalination/purification membranes. A. major success indicator for any water treatment membrane is the resistance to biofouling. To validate this and to understand better the health and environmental impacts of the new 2D carbides, we investigated the antibacterial properties of single- and few-Iayer Ti3C2TX MXene flakes in colloidal solution. The antibacterial properties of Ti3C2TX were tested against Escherichia coli (E.,coli) and Bacillus subtilis (B. subtilis) by using bacterial growth curves based on optical densities (OD) and colonies growth on agar nutritive plates. Ti3C2T shows a higher antibacterial efficiency toward both Gram-negative E. coli and Gram-positive. B. subtilis compared with graphene oxide (GO), which has been widely reported as an antibacterial agent. Concentration dependent antibacterial activity was observed and more than 98% bacterial cell viability loss was found at 200 jzg/mL Ti3C2TX for both bacterial cells within 4 h of exposure, as confirmed by colony forming unit (CFU) and regrowth curve. Antibacterial mechanism investigation by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) coupled with lactate dehydrogenase (LDH) release assay indicated the damage to the cell membrane, which resulted in release of cytoplasmic materials from the bacterial cells. Reactive oxygen species (ROS) dependent and independent stress induction by Ti3C2TX was investigated in two separate abiotic assays. MXenes are expected to be resistant to biofouling and offer bactericidal properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1013, "Times Cited, All Databases": 1055, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3674, "End Page": 3684, "Article Number": null, "DOI": "10.1021/acsnullo.6b00181", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b00181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372855400072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LG; Zhou, HP; Hu, JN; Huang, BL; Sun, MZ; Dong, BW; Zheng, GHJ; Huang, Y; Chen, YH; Li, L; Xu, ZQ; Li, NX; Liu, Z; Chen, Q; Sun, LD; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ligang; Zhou, Huanping; Hu, Junnull; Huang, Bolong; Sun, Mingzi; Dong, Bowei; Zheng, Guanghaojie; Huang, Yuan; Chen, Yihua; Li, Liang; Xu, Ziqi; Li, Nengxu; Liu, Zheng; Chen, Qi; Sun, Ling-Dong; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Eu3+-Eu2+ ion redox shuttle imparts operational durability to Pb-I perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The components with soft nature in the metal halide perovskite absorber usually generate lead (Pb)degrees and iodine (I)degrees defects during device fabrication and operation. These defects serve as not only recombination centers to deteriorate device efficiency but also degradation initiators to hamper device lifetimes. We show that the europium ion pair Eu3+-Eu2+ acts as the redox shuttle that selectively oxidized Pb degrees and reduced I degrees defects simultaneously in a cyclical transition. The resultant device achieves a power conversion efficiency (PCE) of 21.52% (certified 20.52%) with substantially improved long-term durability. The devices retained 92% and 89% of the peak PCE under 1-sun continuous illumination or heating at 850 degrees C for 1500 hours and 91% of the original stable PCE after maximum power point tracking for 500 hours, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 864, "Times Cited, All Databases": 910, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2019, "Volume": 363, "Issue": 6424, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau5701", "DOI Link": "http://dx.doi.org/10.1126/science.aau5701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456140700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On Maxwell's displacement current for energy and sensors: the origin of nullogenerators", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-powered system is a system that can sustainably operate without an external power supply for sensing, detection, data processing and data transmission. nullogenerators were first developed for self-powered systems based on piezoelectric effect and triboelectrification effect for converting tiny mechanical energy into electricity, which have applications in internet of things, environmental/infrastructural monitoring, medical science and security. In this paper, we present the fundamental theory of the nullogenerators starting from the Maxwell equations. In the Maxwell's displacement current, the first term epsilon(0) partial derivative E/partial derivative t gives the birth of electromagnetic wave, which is the foundation of wireless communication, radar and later the information technology. Our study indicates that the second term partial derivative P/partial derivative t in the Maxwell's displacement current is directly related to the output electric current of the nullogenerator, meaning that our nullogenerators are the applications of Maxwell's displacement current in energy and sensors. By contrast, electromagnetic generators are built based on Lorentz force driven flow of free electrons in a conductor. This study presents the similarity and differences between pieozoelectric nullogenerator and triboelectric nullogenerator, as well as the classical electromagnetic generator, so that the impact and uniqueness of the nullogenerators can be clearly understood. We also present the three major applications of nullogenerators as micro/nullo-power source, self-powered sensors and blue energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1592, "Times Cited, All Databases": 1610, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 74, "End Page": 82, "Article Number": null, "DOI": "10.1016/j.mattod.2016.12.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2016.12.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398895800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, C; Qiu, YR; Xia, Y; Zhu, P; King, G; Zhang, X; Wu, ZY; Kim, JY; Cullen, DA; Zheng, DX; Li, P; Shakouri, M; Heredia, E; Cui, PX; Alshareef, HN; Hu, YF; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Chuan; Qiu, Yunrui; Xia, Yang; Zhu, Peng; King, Graham; Zhang, Xiao; Wu, Zhenyu; Kim, Jung Yoon (Timothy); Cullen, David A.; Zheng, Dongxing; Li, Peng; Shakouri, Mohsen; Heredia, Emilio; Cui, Peixin; Alshareef, Husam N.; Hu, Yongfeng; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis of single-atom catalysts with high metal loading using graphene quantum dots", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition-metal single-atom catalysts present extraordinary activity per metal atomic site, but suffer from low metal-atom densities (typically less than 5 wt% or 1 at.%), which limits their overall catalytic performance. Here we report a general method for the synthesis of single-atom catalysts with high transition-metal-atom loadings of up to 40 wt% or 3.8 at.%, representing several-fold improvements compared to benchmarks in the literature. Graphene quantum dots, later interweaved into a carbon matrix, were used as a support, providing numerous anchoring sites and thus facilitating the generation of high densities of transition-metal atoms with sufficient spacing between the metal atoms to avoid aggregation. A significant increase in activity in electrochemical CO2 reduction (used as a representative reaction) was demonstrated on a Ni single-atom catalyst with increased Ni loading.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 887, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-021-00734-x", "DOI Link": "http://dx.doi.org/10.1038/s41557-021-00734-x", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665817700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, ZH; Hu, X; Wan, YS; Wang, SS; Gao, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Zhuhong; Hu, Xin; Wan, Yongshan; Wang, Shengsen; Gao, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Removal of lead, copper, cadmium, zinc, and nickel from aqueous solutions by alkali-modified biochar: Batch and column tests", "Source Title": "JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineered biochar was obtained through slow pyrolysis of hickory wood and then further modified with NaOH. After modification, biochar's surface area, cation-exchange capacity, and thermal stability were significantly improved. The modified biochar exhibited much larger (2.6-5.8 times) metal adsorption capacities than the pristine biochar. Competitive batch adsorption of mixed metal ions (Pb2+, Cd2+, Cu2+, Zn2+, and Ni2+) showed preferential adsorption of Pb2+ and Cu2+ onto the modified biochar. The alkali-modified biochar in a fixed-bed column also showed strong ability to filter heavy metals from aqueous solutions. The alkali-modified biochar thus can serve as alternative absorbent for heavy metals. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2016, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 239, "End Page": 245, "Article Number": null, "DOI": "10.1016/j.jiec.2015.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.jiec.2015.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367111100030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, D; Resasco, J; Yu, Y; Asiri, AM; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Dohyung; Resasco, Joaquin; Yu, Yi; Asiri, Abdullah Mohamed; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold-copper bimetallic nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly efficient and selective electrochemical reduction of carbon dioxide represents one of the biggest scientific challenges in artificial photosynthesis, where carbon dioxide and water are converted into chemical fuels from solar energy. However, our fundamental understanding of the reaction is still limited and we do not have the capability to design an outstanding catalyst with great activity and selectivity a priori. Here we assemble uniform gold-copper bimetallic nulloparticles with different compositions into ordered monolayers, which serve as a well-defined platform to understand their fundamental catalytic activity in carbon dioxide reduction. We find that two important factors related to intermediate binding, the electronic effect and the geometric effect, dictate the activity of gold-copper bimetallic nulloparticles. These nulloparticle monolayers also show great mass activities, outperforming conventional carbon dioxide reduction catalysts. The insights gained through this study may serve as a foundation for designing better carbon dioxide electrochemical reduction catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1134, "Times Cited, All Databases": 1231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4948, "DOI": "10.1038/ncomms5948", "DOI Link": "http://dx.doi.org/10.1038/ncomms5948", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342984800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Lu, XM; Zhang, MR; Hu, K; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tong; Lu, Xian-Mao; Zhang, Ming-Rong; Hu, Kuan; Li, Zhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Peptide-based nullomaterials: Self-assembly, properties and applications", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peptide-based materials that have diverse structures and functionalities are an important type of biomaterials. In former times, peptide-based nullomaterials with excellent stability were constructed through self-assembly. Compared with individual peptides, peptide-based self-assembly nullomaterials that form well-ordered superstructures possess many advantages such as good thermo- and mechanical stability, semiconductivity, piezoelectricity and optical properties. Moreover, due to their excellent biocompatibility and biological activity, peptide-based self-assembly nullomaterials have been vastly used in different fields. In this review, we provide the advances of peptide-based self-assembly nullostructures, focusing on the driving forces that dominate peptide self-assembly and assembly mechanisms of peptides. After that, we outline the synthesis and properties of peptide-based nullomaterials, followed by the applications of functional peptide nullomaterials. Finally, we provide perspectives on the challenges and future of peptide-based nullomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 11, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": 282, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.09.029", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.09.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748988200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Guan, BY; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Guan, Bu Yuan; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of Double-Shelled Zinc-Cobalt Sulfide Dodecahedral Cages from Bimetallic Zeolitic Imidazolate Frameworks for Hybrid Supercapacitors", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Complex metal-organic frameworks used as precursors allow design and construction of various nullostructured functional materials which might not be accessible by other methods. Here, we develop a sequential chemical etching and sulfurization strategy to prepare well-defined double-shelled zinc-cobalt sulfide (Zn-Co-S) rhombic dodecahedral cages (RDCs). Yolk-shelled zinc/cobalt-based zeolitic imidazolate framework (Zn/Co-ZIF) RDCs are first synthesized by a controlled chemical etching process, followed by a hydrothermal sulfurization reaction to prepare double-shelled Zn-Co-S RDCs. Moreover, the strategy reported in this work enables easy control of the Zn/Co molar ratio in the obtained double-shelled Zn-Co-S RDCs. Owing to the structural and compositional benefits, the obtained double-shelled Zn-Co-S RDCs exhibit enhanced performance with high specific capacitance (1266 Fg(-1) at 1 Ag-1), good rate capability and long-term cycling stability (91% retention over 10,000 cycles) as a battery-type electrode material for hybrid supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2017, "Volume": 56, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7141, "End Page": 7145, "Article Number": null, "DOI": "10.1002/anie.201702649", "DOI Link": "http://dx.doi.org/10.1002/anie.201702649", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402857800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, XW; Hasa, I; Saurel, D; Vaalma, C; Wu, LM; Buchholz, D; Bresser, D; Komaba, S; Passerini, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Xinwei; Hasa, Ivana; Saurel, Damien; Vaalma, Christoph; Wu, Liming; Buchholz, Daniel; Bresser, Dominic; Komaba, Shinichi; Passerini, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hard carbons for sodium-ion batteries: Structure, analysis, sustainability, and electrochemistry", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard carbons are extensively studied for application as anode materials in sodium-ion batteries, but only recently a great interest has been focused toward the understanding of the sodium storage mechanism and the comprehension of the structure-function correlation. Although several interesting mechanisms have been proposed, a general mechanism explaining the observed electrochemical processes is still missing, which is essentially originating from the remaining uncertainty on the complex hard carbons structure. The achievement of an in-depth understanding of the processes occurring upon sodiation, however, is of great importance for a rational design of optimized anode materials. In this review, we aim at providing a comprehensive overview of the up-to-date known structural models of hard carbons and their correlation with the proposed models for the sodium-ion storage mechanisms. In this regard, a particular focus is set on the most powerful analytical tools to study the structure of hard carbons (upon de-/sodiation) and a critical discussion on how to interpret and perform such analysis. Targeting the eventual commercialization of hard carbon anodes for sodiumion batteries - after having established a fundamental understanding - we close this review with a careful evaluation of potential strategies to ensure a high degree of sustainability, since this is undoubtedly a crucial parameter to take into account for the future large-scale production of hard carbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 681, "Times Cited, All Databases": 715, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 23, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 87, "End Page": 104, "Article Number": null, "DOI": "10.1016/j.mattod.2018.12.040", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2018.12.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461359100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, Z; Shi, YY; Zhu, XJ; Cai, L; Lu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Zhen; Shi, Yuyang; Zhu, Xiaojie; Cai, Lei; Lu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and Waterproof 2D/1D/0D Construction of MXene-Based nullocomposites for Electromagnetic Wave Absorption, EMI Shielding, and Photothermal Conversion", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance electromagnetic wave absorption and electromagnetic interference (EMI) shielding materials with multifunctional characters have attracted extensive scientific and technological interest, but they remain a huge challenge. Here, we reported an electrostatic assembly approach for fabricating 2D/1D/0D construction of Ti3C2Tx/carbon nullotubes/Co nulloparticles (Ti3C2Tx/CNTs/Co) nullocomposites with an excellent electromagnetic wave absorption, EMI shielding efficiency, flexibility, hydrophobicity, and photothermal conversion performance. As expected, a strong reflection loss of -85.8 dB and an ultrathin thickness of 1.4 mm were achieved. Meanwhile, the high EMI shielding efficiency reached 110.1 dB. The excellent electromagnetic wave absorption and shielding performances were originated from the charge carriers, electric/magnetic dipole polarization, interfacial polarization, natural resonullce, and multiple internal reflections. Moreover, a thin layer of polydimethylsiloxane rendered the hydrophilic hierarchical Ti3C2Tx/CNTs/Co hydrophobic, which can prevent the degradation/oxidation of the MXene in high humidity condition. Interestingly, the Ti3C2Tx/CNTs/Co film exhibited a remarkable photothermal conversion performance with high thermal cycle stability and tenability. Thus, the multifunctional Ti3C2Tx/CNTs/Co nullocomposites possessing a unique blend of outstanding electromagnetic wave absorption and EMI shielding, light-driven heating performance, and flexible water-resistant features were highly promising for the next-generation intelligent electromagnetic attenuation system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 150, "DOI": "10.1007/s40820-021-00673-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00673-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667047100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, Y; Xia, XH; Shi, F; Zhan, JY; Tu, JP; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yu; Xia, Xinhui; Shi, Fan; Zhan, Jiye; Tu, Jiangping; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition Metal Carbides and Nitrides in Energy Storage and Conversion", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance electrode materials are the key to advances in the areas of energy conversion and storage (e.g., fuel cells and batteries). In this Review, recent progress in the synthesis and electrochemical application of transition metal carbides (TMCs) and nitrides (TMNs) for energy storage and conversion is summarized. Their electrochemical properties in Li-ion and Na-ion batteries as well as in supercapacitors, and electrocatalytic reactions (oxygen evolution and reduction reactions, and hydrogen evolution reaction) are discussed in association with their crystal structure/morphology/composition. Advantages and benefits of nullostructuring (e.g., 2D MXenes) are highlighted. Prospects of future research trends in rational design of high-performance TMCs and TMNs electrodes are provided at the end.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1005, "Times Cited, All Databases": 1050, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500286, "DOI": "10.1002/advs.201500286", "DOI Link": "http://dx.doi.org/10.1002/advs.201500286", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377783100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JR; Hartmann, G; Lee, M; Hwang, GS; Chen, YF; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Jiarui; Hartmann, Gregory; Lee, Myungsuk; Hwang, Gyeong S.; Chen, Yuanfu; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Freestanding 1T MoS2/graphene heterostructures as a highly efficient electrocatalyst for lithium polysulfides in Li-S batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel approach to effectively suppress the polysulfide shuttle in Li-S batteries is presented by designing a freestanding, three-dimensional graphene/1T MoS2 (3DG/TM) heterostructure with highly efficient electrocatalysis properties for lithium polysulfides (LiPSs). The 3DG/TM heterostructure is constructed by few-layered graphene nullosheets sandwiched by hydrophilic, metallic, few-layered 1T MoS2 nullosheets with abundant active sites. The porous 3D structure and the hydrophilic feature of 1T-MoS2 are beneficial for electrolyte penetration and Li-ion transfer, and the high conductivities of both graphene and the 1T MoS2 nullosheets facilitate electron transfer. These merits lead to a high electrocatalytic efficiency for LiPSs due to excellent ion/electron transfer and the presence of sufficient electrocatalytic active sites. Therefore, the cells with 3DG/TM exhibit outstanding electrochemical performance, with a high reversible discharge capacity of 1181 mA h g(-1) and a capacity retention of 96.3% after 200 cycles. The electrocatalysis mechanism of LiPSs is further experimentally and theoretically revealed, which provides new insights and opportunities to develop advanced Li-S batteries with highly efficient electrocatalysts for LiPS conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 344, "End Page": 350, "Article Number": null, "DOI": "10.1039/c8ee03252a", "DOI Link": "http://dx.doi.org/10.1039/c8ee03252a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457194500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, S; Li, L; Tu, HY; Zhang, H; Silvester, DS; Banks, CE; Zou, GQ; Hou, HS; Ji, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shuo; Li, Lin; Tu, Hanyu; Zhang, Hao; Silvester, Debbie S.; Banks, Craig E.; Zou, Guoqiang; Hou, Hongshuai; Ji, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The development of carbon dots: From the perspective of materials chemistry", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advance of materials chemistry has influenced significantly the lifestyle of mankind. By virtue of their fascinating physicochemical nature - including ultrasmall size (<10 nm), rich functional groups, fluorescence, chemical stability, biocompatibility, and nontoxicity - carbon dots have been acclaimed as another epoch-making carbon-based nullomaterial following on from fullerene, nullotubes, and graphene. However, the field of carbon dot-based materials chemistry remains incomplete because of their wide structural diversity, meaning that much fundamental knowledge still needs to be uncovered. Herein, this review proposed several novel viewpoints in term of carbon dot-based material chemistry, including the development history, classification, design principle and applications of carbon dots-based materials. Finally, several sound prospects in this fascinating filed are also given.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 188, "End Page": 207, "Article Number": null, "DOI": "10.1016/j.mattod.2021.07.028", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.07.028", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733411900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, FC; Yang, Y; Chen, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Fangcai; Yang, Yang; Chen, Qianwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Theoretical and experimental results have revealed that the lithium-ion storage capacity for nitrogen-doped graphene largely depends on the nitrogen-doping level. However, most nitrogen-doped carbon materials used for lithium-ion batteries are reported to have a nitrogen content of approximately 10 wt% because a higher number of nitrogen atoms in the two-dimensional honeycomb lattice can result in structural instability. Here we report nitrogen-doped graphene particle analogues with a nitrogen content of up to 17.72 wt% that are prepared by the pyrolysis of a nitrogen-containing zeolitic imidazolate framework at 800 degrees C under a nitrogen atmosphere. As an anode material for lithium-ion batteries, these particles retain a capacity of 2,132 mA hg(-1) after 50 cycles at a current density of 100 mA g(-1), and 785 mAh g(-1) after 1,000 cycles at 5 A g(-1). The remarkable performance results from the graphene analogous particles doped with nitrogen within the hexagonal lattice and edges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1350, "Times Cited, All Databases": 1397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5261, "DOI": "10.1038/ncomms6261", "DOI Link": "http://dx.doi.org/10.1038/ncomms6261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345685500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, YN; Tang, J; Wang, ZL; Kang, YM; Bando, Y; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Yanna; Tang, Jing; Wang, Zhongli; Kang, Yong-Mook; Bando, Yoshio; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elaborately assembled core-shell structured metal sulfides as a bifunctional catalyst for highly efficient electrochemical overall water splitting", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low efficiency, short lifetimes, and limited kinds of catalysts are still three fundamental shortcomings that have plagued electrochemical water splitting. Herein, we rationally synthesized a cost-effective Co3S4@MoS2 hetero-structured catalyst that has proven to be a highly active and stable bifunctional catalyst for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in an alkaline environment. The heterostructure was obtained via a first hydrothermal approach to obtain hollow Co3S4 nulloboxes based on the ionic exchange reaction between Fe(CN)(6)(3-) of Co-Fe Prussian blue analogue (PBA) and S2- at 120 degrees C, and the subsequent in situ growth of MoS2 nullosheets on the surface of Co3S4 nulloboxes at an elevated temperature of 200 degrees C. The synergistic effects between the active and stable HER catalyst of MoS2 and the efficient OER catalyst of Co3S4, as well as the morphological superiority of hollow and core-shell structures, endow Co3S4@MoS2 with remarkable electrocatalytic performance and robust durability toward overall water splitting. As a result, the designed non-noble electrocatalyst of Co3S4@MoS2 exhibits a low overpotential of 280 mV for OER and 136 mV for HER at a current density of 10 mA cm(-2) in an alkaline solution. Meanwhile, a low cell voltage of 1.58 V is achieved by using the heterostructure as both anode and cathode catalysts. This work paves the way to the design and construction of other prominent electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 494, "End Page": 502, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.03.012", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.03.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430057000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SI; Lee, KH; Mun, HA; Kim, HS; Hwang, SW; Roh, JW; Yang, DJ; Shin, WH; Li, XS; Lee, YH; Snyder, GJ; Kim, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sang Il; Lee, Kyu Hyoung; Mun, Hyeon A.; Kim, Hyun Sik; Hwang, Sung Woo; Roh, Jong Wook; Yang, Dae Jin; Shin, Weon Ho; Li, Xiang Shu; Lee, Young Hee; Snyder, G. Jeffrey; Kim, Sung Wng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widespread use of thermoelectric technology is constrained by a relatively low conversion efficiency of the bulk alloys, which is evaluated in terms of a dimensionless figure of merit (zT). The zT of bulk alloys can be improved by reducing lattice thermal conductivity through grain boundary and point-defect scattering, which target low-and high-frequency phonons. Dense dislocation arrays formed at low-energy grain boundaries by liquid-phase compaction in Bi0.5Sb1.5Te3 (bismuth antimony telluride) effectively scatter midfrequency phonons, leading to a substantially lower lattice thermal conductivity. Full-spectrum phonon scattering with minimal charge-carrier scattering dramatically improved the zT to 1.86 +/- 0.15 at 320 kelvin (K). Further, a thermoelectric cooler confirmed the performance with a maximum temperature difference of 81 K, which is much higher than current commercial Peltier cooling devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1702, "Times Cited, All Databases": 1788, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2015, "Volume": 348, "Issue": 6230, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 109, "End Page": 114, "Article Number": null, "DOI": "10.1126/science.aaa4166", "DOI Link": "http://dx.doi.org/10.1126/science.aaa4166", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352079500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZH; Zhang, JQ; Yin, LC; Hu, GJ; Fang, RP; Cheng, HM; Li, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zhenhua; Zhang, Jingqi; Yin, Lichang; Hu, Guangjian; Fang, Ruopian; Cheng, Hui-Ming; Li, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the rechargeable lithium-sulfur battery is an advanced energy storage system, its practical implementation has been impeded by many issues, in particular the shuttle effect causing rapid capacity fade and low Coulombic efficiency. Herein, we report a conductive porous vanadium nitride nulloribbon/graphene composite accommodating the catholyte as the cathode of a lithium-sulfur battery. The vanadium nitride/graphene composite provides strong anchoring for polysulfides and fast polysulfide conversion. The anchoring effect of vanadium nitride is confirmed by experimental and theoretical results. Owing to the high conductivity of vanadium nitride, the composite cathode exhibits lower polarization and faster redox reaction kinetics than a reduced graphene oxide cathode, showing good rate and cycling performances. The initial capacity reaches 1,471mAhg(-1) and the capacity after 100 cycles is 1,252 mAhg(-1) at 0.2 C, a loss of only 15%, offering a potential for use in high energy lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1068, "Times Cited, All Databases": 1134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14627, "DOI": "10.1038/ncomms14627", "DOI Link": "http://dx.doi.org/10.1038/ncomms14627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395280000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Wang, ZX; Lin, SH; Jin, HL; Gao, SJ; Zhu, YZ; Jin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhenyi; Wang, Zhangxin; Lin, Shihong; Jin, Huile; Gao, Shoujian; Zhu, Yuzhang; Jin, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticle-templated nullofiltration membranes for ultrahigh performance desalination", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullofiltration (NF) membranes with ultrahigh permeance and high rejection are highly beneficial for efficient desalination and wastewater treatment. Improving water permeance while maintaining the high rejection of state-of-the-art thin film composite (TFC) NF membranes remains a great challenge. Herein, we report the fabrication of a TFC NF membrane with a crumpled polyamide (PA) layer via interfacial polymerization on a single-walled carbon nullotubes/polyether sulfone composite support loaded with nulloparticles as a sacrificial templating material, using metal-organic framework nulloparticles (ZIF-8) as an example. The nulloparticles, which can be removed by water dissolution after interfacial polymerization, facilitate the formation of a rough PA active layer with crumpled nullostructure. The NF membrane obtained thereby exhibits high permeance up to 53.5 l m(-2)h(-1) bar(-1) with a rejection above 95% for Na2SO4, yielding an overall desalination performance superior to state-of-the-art NF membranes reported so far. Our work provides a simple avenue to fabricate advanced PA NF membranes with outstanding performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 840, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004, "DOI": "10.1038/s41467-018-04467-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04467-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432535300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, L; Wang, T; Zhang, HB; Chang, K; Meng, XG; Liu, HM; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Li; Wang, Tao; Zhang, Huabin; Chang, Kun; Meng, Xianguang; Liu, Huimin; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Amine-Functionalized Iron(III) Metal-Organic Framework as Efficient Visible-Light Photocatalyst for Cr(VI) Reduction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photocatalytic reduction of Cr(VI) is investigated over iron(III)-based metal-organic frameworks (MOFs) structured as MIL-88B. It is found that MIL-88B (Fe) MOFs, containing Fe-3-mu(3)-oxo clusters, can be used as photocatalyst for the reduction of Cr(VI) under visible light irradiation, which is due to the direct excitation of Fe-3-mu(3)-oxo clusters. The amine-functionalized MIL-88B (Fe) MOFs (denoted as NH2-MIL-88B (Fe)) shows much higher efficiency for the photocatalytic Cr(VI) reduction under visible-light irradiation compared with MIL-88B (Fe). It is revealed that in addition to the direct excitation of Fe-3-mu(3)-oxo clusters, the amine functionality in NH2-MIL-88B (Fe) can also be excited and then transferred an electron to Fe-3-mu(3) -oxo clusters, which is responsible for the enhanced photocatalytic activity for Cr(VI) reduction. The enhanced photocatalytic activity for Cr(VI) reduction is also achieved for other two amine-functionalized iron(III)-based MOFs (NH2-MIL-53 (Fe) and NH2-MIL-101 (Fe)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500006, "DOI": "10.1002/advs.201500006", "DOI Link": "http://dx.doi.org/10.1002/advs.201500006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368941800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dall'Agnese, Y; Taberna, PL; Gogotsi, Y; Simon, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dall'Agnese, Yohan; Taberna, Pierre-Louis; Gogotsi, Yury; Simon, Patrice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Vanadium Carbide (MXene) as Positive Electrode for Sodium-Ion Capacitors", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ion capacitors store energy through intercalation of cations into an electrode at a faster rate than in batteries and within a larger potential window. These devices reach a higher energy density compared to electrochemical double layer capacitor. Li-ion capacitors are already produced commercially, but the development of Na-ion capacitors is hindered by lack of materials that would allow fast intercalation of Na-ions. Here we investigated the electrochemical behavior of 2D vanadium carbide, V2C, from the MXene family. We investigated the mechanism of Na intercalation by XRD and achieved capacitance of similar to 100 F/g at 0.2 mV/s. We assembled a full cell with hard carbon as negative electrode, a known anode material for Na ion batteries, and achieved capacity of 50 mAh/g with a maximum cell voltage of 3.5 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2015, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2305, "End Page": 2309, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b00868", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b00868", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356758100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, JP; Huang, BL; Chao, YG; Chen, X; Guo, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Jianping; Huang, Bolong; Chao, Yuguang; Chen, Xu; Guo, Shaojun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly Coupled Nickel-Cobalt Nitrides/Carbon Hybrid nullocages with Pt-Like Activity for Hydrogen Evolution Catalysis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing non-precious-metal catalysts with comparable mass activity to state-of-the-art noble-metal catalysts for the hydrogen evolution reaction (HER) in alkaline solution still remains a significant challenge. Herein a new strongly coupled nickel-cobalt nitrides/carbon complex nullocage (NiCoNzocage) is rationally designed via chemical etching of ZIF-67 nullocubes with Ni(NO3)(2) under sonication at room temperature, following nitridation. The as-prepared strongly coupled NiCoN/C nullocages exhibit a mass activity of 0.204 mA mu g(-1) at an overpotential of 200 mV for the HER in alkaline solution, which is comparable to that of commercial Pt/C (0.451 mA mu g(-1)). The strongly coupled NiCoN/C nullocages also possess superior stability for the HER with negligible current loss under the overpotentials of 200 mV for 10 h. Density functional theory (DFT) calculations reveal that the excellent HER performance under alkaline condition arises from the robust Co2+-> Co-0 transformation achieved by strong (Ni, Co)-N-bonding-induced efficient d-p-d coupled electron transfer, which is a key for optimal initial water adsorption and splitting. The high degree of amorphization urges the C-sites to be an electron-pushing bath to promote the inter-layer/sites electron-transfer with loss of the orbital-selection-forbidden-rule, which uniformly boosts the surface catalytic activities up to a high level independent of the individual surface active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 31, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805541, "DOI": "10.1002/adma.201805541", "DOI Link": "http://dx.doi.org/10.1002/adma.201805541", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455111100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, W; Wang, JQ; Chu, CC; Chen, W; Wu, CS; Liu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Wen; Wang, Junqing; Chu, Chengchao; Chen, Wei; Wu, Chunsheng; Liu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal Organic Framework-Based Stimuli-Responsive Systems for Drug Delivery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapid development of nullotechnology, stimuli-responsive nullomaterials have provided an alternative for designing controllable drug delivery systems due to their spatiotemporally controllable properties. As a new type of porous material, metal-organic frameworks (MOFs) have been widely used in biomedical applications, especially drug delivery systems, owing to their tunable pore size, high surface area and pore volume, and easy surface modification. Here, recent progress in MOF-based stimuli-responsive systems is presented, including pH-, magnetic-, ion-, temperature-, pressure-, light-, humidity-, redox-, and multiple stimuli-responsive systems for the delivery of anticancer drugs. The remaining challenges and suggestions for future directions for the rational design of MOF-based nullomedicines are also discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 604, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2019, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801526, "DOI": "10.1002/advs.201801526", "DOI Link": "http://dx.doi.org/10.1002/advs.201801526", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455199400024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, P; Yuan, XH; Xia, YB; Zhang, Y; Fu, LJ; Liu, LL; Yu, NF; Huang, QH; Wang, B; Hu, XW; Wu, YP; van Ree, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Peng; Yuan, Xinhai; Xia, Yingbin; Zhang, Yi; Fu, Lijun; Liu, Lili; Yu, Nengfei; Huang, Qinghong; Wang, Bin; Hu, Xianwei; Wu, Yuping; van Ree, Teunis", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Artificial Polyacrylonitrile Coating Layer Confining Zinc Dendrite Growth for Highly Reversible Aqueous Zinc-Based Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous rechargeable zinc-metal-based batteries are an attractive alternative to lithium-ion batteries for grid-scale energy-storage systems because of their high specific capacity, low cost, eco-friendliness, and nonflammability. However, uncontrollable zinc dendrite growth limits the cycle life by piercing the separator, resulting in low zinc utilization in both alkaline and mild/neutral electrolytes. Herein, a polyacrylonitrile coating layer on a zinc anode produced by a simple drop coating approach to address the dendrite issue is reported. The coating layer not only improves the hydrophilicity of the zinc anode but also regulates zinc-ion transport, consequently facilitating the uniform deposition of zinc ions to avoid dendrite formation. A symmetrical cell with the polymer-coating-layer-modified Zn anode displays dendrite-free plating/stripping with a long cycle lifespan (>1100 h), much better than that of the bare Zn anode. The modified zinc anode coupled with a Mn-doped V2O5 cathode forms a stable rechargeable full battery. This method is a facile and feasible way to solve the zinc dendrite problem for rechargeable aqueous zinc-metal batteries, providing a solid basis for application of aqueous rechargeable Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 8, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100309, "DOI": "10.1002/advs.202100309", "DOI Link": "http://dx.doi.org/10.1002/advs.202100309", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634747100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Dang, LN; Shearer, MJ; Sheng, HY; Li, WJ; Chen, J; Xiao, P; Zhang, YH; Hamers, RJ; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yang; Dang, Lianna; Shearer, Melinda J.; Sheng, Hongyuan; Li, Wenjie; Chen, Jie; Xiao, Peng; Zhang, Yunhuai; Hamers, Robert J.; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Active Trimetallic NiFeCr Layered Double Hydroxide Electrocatalysts for Oxygen Evolution Reaction", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient and robust earth-abundant electrocatalysts for the oxygen evolution reaction (OER) is an ongoing challenge. Here, a novel and stable trimetallic NiFeCr layered double hydroxide (LDH) electrocatalyst for improving OER kinetics is rationally designed and synthesized. Electrochemical testing of a series of trimetallic NiFeCr LDH materials at similar catalyst loading and electrochemical surface area shows that the molar ratio Ni:Fe:Cr = 6:2:1 exhibits the best intrinsic OER catalytic activity compared to other NiFeCr LDH compositions. Furthermore, these nullostructures are directly grown on conductive carbon paper for a high surface area 3D electrode that can achieve a catalytic current density of 25 mA cm(-2) at an overpotential as low as 225 mV and a small Tafel slope of 69 mV dec(-1) in alkaline electrolyte. The optimized NiFeCr catalyst is stable under OER conditions and X-ray photoelectron spectroscopy, electron paramagnetic resonullce spectroscopy, and elemental analysis confirm the stability of trimetallic NiFeCr LDH after electrochemical testing. Due to the synergistic interactions among the metal centers, trimetallic NiFeCr LDH is significantly more active than NiFe LDH and among the most active OER catalysts to date. This work also presents general strategies to design more efficient metal oxide/hydroxide OER electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 602, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2018, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703189, "DOI": "10.1002/aenm.201703189", "DOI Link": "http://dx.doi.org/10.1002/aenm.201703189", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434031400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JD; Xie, HH; Huang, H; Li, ZB; Sun, ZB; Xu, YH; Xiao, QL; Yu, XF; Zhao, YT; Zhang, H; Wang, HY; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jundong; Xie, Hanhan; Huang, Hao; Li, Zhibin; Sun, Zhengbo; Xu, Yanhua; Xiao, Quanlan; Yu, Xue-Feng; Zhao, Yuetao; Zhang, Han; Wang, Huaiyu; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable black phosphorus-based nullospheres for in vivo photothermal cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) offers many advantages such as high efficiency and minimal invasiveness, but clinical adoption of PTT nulloagents have been stifled by unresolved concerns such as the biodegradability as well as long-term toxicity. Herein, poly (lactic-co-glycolic acid) (PLGA) loaded with black phosphorus quantum dots (BPQDs) is processed by an emulsion method to produce biodegradable BPQDs/PLGA nullospheres. The hydrophobic PLGA not only isolates the interior BPQDs from oxygen and water to enhance the photothermal stability, but also control the degradation rate of the BPQDs. The in vitro and in vivo experiments demonstrate that the BPQDs/PLGA nullospheres have inappreciable toxicity and good biocompatibility, and possess excellent PTT efficiency and tumour targeting ability as evidenced by highly efficient tumour ablation under near infrared (NIR) laser illumination. These BP-based nullospheres combine biodegradability and biocompatibility with high PTT efficiency, thus promising high clinical potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 892, "Times Cited, All Databases": 934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12967, "DOI": "10.1038/ncomms12967", "DOI Link": "http://dx.doi.org/10.1038/ncomms12967", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385456600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grigoryan, B; Paulsen, SJ; Corbett, DC; Sazer, DW; Fortin, CL; Zaita, AJ; Greenfield, PT; Calafat, NJ; Gounley, JP; Ta, AH; Johansson, F; Randles, A; Rosenkrantz, JE; Louis-Rosenberg, JD; Galie, PA; Stevens, KR; Miller, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grigoryan, Bagrat; Paulsen, Samantha J.; Corbett, Daniel C.; Sazer, Daniel W.; Fortin, Chelsea L.; Zaita, Alexander J.; Greenfield, Paul T.; Calafat, Nicholas J.; Gounley, John P.; Ta, Anderson H.; Johansson, Fredrik; Randles, Amanda; Rosenkrantz, Jessica E.; Louis-Rosenberg, Jesse D.; Galie, Peter A.; Stevens, Kelly R.; Miller, Jordan S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "BIOMEDICINE Multivascular networks and functional intravascular topologies within biocompatible hydrogels", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid organs transport fluids through distinct vascular networks that are biophysically and biochemically entangled, creating complex three-dimensional (3D) transport regimes that have remained difficult to produce and study. We establish intravascular andmultivascular design freedoms with photopolymerizable hydrogels by using food dye additives as biocompatible yet potent photoabsorbers for projection stereolithography. We demonstrate monolithic transparent hydrogels, produced in minutes, comprising efficient intravascular 3D fluid mixers and functional bicuspid valves. We further elaborate entangled vascular networks from space-filling mathematical topologies and explore the oxygenation and flow of human red blood cells during tidal ventilation and distension of a proximate airway. In addition, we deploy structured biodegradable hydrogel carriers in a rodent model of chronic liver injury to highlight the potential translational utility of this materials innovation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 996, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 364, "Issue": 6439, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 458, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav9750", "DOI Link": "http://dx.doi.org/10.1126/science.aav9750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466809600028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, JJ; Chen, S; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Jingjing; Chen, Sheng; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin metal-organic framework array for efficient electrocatalytic water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional metal-organic frameworks represent a family of materials with attractive chemical and structural properties, which are usually prepared in the form of bulk powders. Here we show a generic approach to fabricate ultrathin nullosheet array of metal-organic frameworks on different substrates through a dissolution-crystallization mechanism. These materials exhibit intriguing properties for electrocatalysis including highly exposed active molecular metal sites owning to ultra-small thickness of nullosheets, improved electrical conductivity and a combination of hierarchical porosity. We fabricate a nickel-iron-based metal-organic framework array, which demonstrates superior electrocatalytic performance towards oxygen evolution reaction with a small overpotential of 240 mV at 10 mA cm(-2), and robust operation for 20,000 s with no detectable activity decay. Remarkably, the turnover frequency of the electrode is 3.8 s(-1) at an overpotential of 400 mV. We further demonstrate the promise of these electrodes for other important catalytic reactions including hydrogen evolution reaction and overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1090, "Times Cited, All Databases": 1117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15341, "DOI": "10.1038/ncomms15341", "DOI Link": "http://dx.doi.org/10.1038/ncomms15341", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402742100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eperon, GE; Leijtens, T; Bush, KA; Prasanna, R; Green, T; Wang, JTW; McMeekin, DP; Volonakis, G; Milot, RL; May, R; Palmstrom, A; Slotcavage, DJ; Belisle, RA; Patel, JB; Parrott, ES; Sutton, RJ; Ma, W; Moghadam, F; Conings, B; Babayigit, A; Boyen, HG; Bent, S; Giustino, F; Herz, LM; Johnston, MB; McGehee, MD; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A.; Prasanna, Rohit; Green, Thomas; Wang, Jacob Tse-Wei; McMeekin, David P.; Volonakis, George; Milot, Rebecca L.; May, Richard; Palmstrom, Axel; Slotcavage, Daniel J.; Belisle, Rebecca A.; Patel, Jay B.; Parrott, Elizabeth S.; Sutton, Rebecca J.; Ma, Wen; Moghadam, Farhad; Conings, Bert; Babayigit, Aslihan; Boyen, Hans-Gerd; Bent, Stacey; Giustino, Feliciano; Herz, Laura M.; Johnston, Michael B.; McGehee, Michael D.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-perovskite tandem photovoltaics with optimized band gaps", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate four-and two-terminal perovskite-perovskite tandem solar cells with ideally matched band gaps. We develop an infrared-absorbing 1.2-electron volt band-gap perovskite, FA(0.75)Cs(0.25)Sn(0.5)Pb(0.5)I(3), that can deliver 14.8% efficiency. By combining this material with a wider-band gap FA(0.83)Cs(0.17)Pb(I0.5Br0.5)(3) material, we achieve monolithic two-terminal tandem efficiencies of 17.0% with > 1.65-volt open-circuit voltage. We also make mechanically stacked four-terminal tandem cells and obtain 20.3% efficiency. Notably, we find that our infrared-absorbing perovskite cells exhibit excellent thermal and atmospheric stability, not previously achieved for Sn-based perovskites. This device architecture and materials set will enable all-perovskite thin-film solar cells to reach the highest efficiencies in the long term at the lowest costs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1224, "Times Cited, All Databases": 1316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2016, "Volume": 354, "Issue": 6314, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 861, "End Page": 865, "Article Number": null, "DOI": "10.1126/science.aaf9717", "DOI Link": "http://dx.doi.org/10.1126/science.aaf9717", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388531900034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZJ; Yin, HJ; Wang, Y; Chuang, CH; Xing, L; Dong, MY; Lu, YR; Casillas-Garcia, G; Zheng, YL; Chen, S; Dou, YH; Liu, P; Cheng, QL; Zhao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zhengju; Yin, Huajie; Wang, Yun; Chuang, Cheng-Hao; Xing, Lei; Dong, Mengyang; Lu, Ying-Rui; Casillas-Garcia, Gilberto; Zheng, Yonglong; Chen, Shan; Dou, Yuhai; Liu, Porun; Cheng, Qilin; Zhao, Huijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coexisting Single-Atomic Fe and Ni Sites on Hierarchically Ordered Porous Carbon as a Highly Efficient ORR Electrocatalyst", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of oxygen reduction reaction (ORR) electrocatalysts based on earth-abundant nonprecious materials is critically important for sustainable large-scale applications of fuel cells and metal-air batteries. Herein, a hetero-single-atom (h-SA) ORR electrocatalyst is presented, which has atomically dispersed Fe and Ni coanchored to a microsized nitrogen-doped graphitic carbon support with unique trimodal-porous structure configured by highly ordered macropores interconnected through mesopores. Extended X-ray absorption fine structure spectra confirm that Fe- and Ni-SAs are affixed to the carbon support via Fe-N(4)and Ni-N(4)coordination bonds. The resultant Fe/Ni h-SA electrocatalyst exhibits an outstanding ORR activity, outperforming SA electrocatalysts with only Fe- or Ni-SAs, and the benchmark Pt/C. The obtained experimental results indicate that the achieved outstanding ORR performance results from the synergetic enhancement induced by the coexisting Fe-N(4)and Ni-N(4)sites, and the superior mass-transfer capability promoted by the trimodal-porous-structured carbon support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 510, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 32, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004670, "DOI": "10.1002/adma.202004670", "DOI Link": "http://dx.doi.org/10.1002/adma.202004670", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569825900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Togo, A; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Togo, Atsushi; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First principles phonon calculations in materials science", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonon plays essential roles in dynamical behaviors and thermal properties, which are central topics in fundamental issues of materials science. The importance of first principles phonon calculations cannot be overly emphasized. Phonopy is an open source code for such calculations launched by the present authors, which has been world-widely used. Here we demonstrate phonon properties with fundamental equations and show examples how the phonon calculations are applied in materials science. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.orgilicenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 8499, "Times Cited, All Databases": 8915, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 5, "Article Number": null, "DOI": "10.1016/j.scriptamat.2015.07.021", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2015.07.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360250700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Zhao, SY; Johannessen, B; Veder, JP; Saunders, M; Rowles, MR; Cheng, M; Liu, C; Chisholm, MF; De Marco, R; Cheng, HM; Yang, SZ; Jiang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yi; Zhao, Shiyong; Johannessen, Bernt; Veder, Jean-Pierre; Saunders, Martin; Rowles, Matthew R.; Cheng, Min; Liu, Chang; Chisholm, Matthew F.; De Marco, Roland; Cheng, Hui-Ming; Yang, Shi-Ze; Jiang, San Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Dispersed Transition Metals on Carbon nullotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) are the smallest entities for catalytic reactions with projected high atomic efficiency, superior activity, and selectivity; however, practical applications of SACs suffer from a very low metal loading of 1-2 wt%. Here, a class of SACs based on atomically dispersed transition metals on nitrogen-doped carbon nullotubes (MSA-N-CNTs, where M = Ni, Co, NiCo, CoFe, and NiPt) is synthesized with an extraordinarily high metal loading, e.g., 20 wt% in the case of NiSA-N-CNTs, using a new multistep pyrolysis process. Among these materials, NiSA-N-CNTs show an excellent selectivity and activity for the electrochemical reduction of CO2 to CO, achieving a turnover frequency (TOF) of 11.7 s(-1) at -0.55 V (vs reversible hydrogen electrode (RHE)), two orders of magnitude higher than Ni nullo-particles supported on CNTs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 563, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2018, "Volume": 30, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706287, "DOI": "10.1002/adma.201706287", "DOI Link": "http://dx.doi.org/10.1002/adma.201706287", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428793600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bekenstein, Y; Koscher, BA; Eaton, SW; Yang, PD; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bekenstein, Yehonadav; Koscher, Brent A.; Eaton, Samuel W.; Yang, Peidong; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Luminescent Colloidal nulloplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anisotropic colloidal quasi-two-dimensional nulloplates (NPLs) hold great promise as functional materials due to their combination of low dimensional optoelectronic properties and versatility through colloidal synthesis. Recently, lead-halide perovskites have emerged as important optoelectronic materials with excellent efficiencies in photovoltaic and light-emitting applications. Here we report the synthesis of quantum confined all inorganic cesium lead halide nulloplates in the perovskite crystal structure that are also highly luminescent (PLQY 84%). The controllable self-assembly of nulloplates either into stacked columnar phases or crystallographic-oriented thin-sheet structures is demonstrated. The broad accessible emission range, high native quantum yields, and ease of self-assembly make perovskite NPLs an ideal platform for fundamental optoelectronic studies and the investigation of future devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1009, "Times Cited, All Databases": 1105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2015, "Volume": 137, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16008, "End Page": 16011, "Article Number": null, "DOI": "10.1021/jacs.5b11199", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367636600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meza, LR; Das, S; Greer, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meza, Lucas R.; Das, Satyajit; Greer, Julia R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong, lightweight, and recoverable three-dimensional ceramic nullolattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ceramics have some of the highest strength- and stiffness-to-weight ratios of any material but are suboptimal for use as structural materials because of their brittleness and sensitivity to flaws. We demonstrate the creation of structural metamaterials composed of nulloscale ceramics that are simultaneously ultralight, strong, and energy-absorbing and can recover their original shape after compressions in excess of 50% strain. Hollow-tube alumina nullolattices were fabricated using two-photon lithography, atomic layer deposition, and oxygen plasma etching. Structures were made with wall thicknesses of 5 to 60 nullometers and densities of 6.3 to 258 kilograms per cubic meter. Compression experiments revealed that optimizing the wall thickness-to-radius ratio of the tubes can suppress brittle fracture in the constituent solid in favor of elastic shell buckling, resulting in ductile-like deformation and recoverability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1189, "Times Cited, All Databases": 1366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2014, "Volume": 345, "Issue": 6202, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1322, "End Page": 1326, "Article Number": null, "DOI": "10.1126/science.1255908", "DOI Link": "http://dx.doi.org/10.1126/science.1255908", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341483800058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sagara, N; Kamimura, S; Tsubota, T; Ohno, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sagara, Nobuhiro; Kamimura, Sunao; Tsubota, Toshiki; Ohno, Teruhisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoelectrochemical CO2 reduction by a p-type boron-doped g-C3N4 electrode under visible light", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphitic carbon nitride (g-C3N4) has attracted much attention as a metal-free semiconductor having visible light absorption and relatively high chemical stability under visible light irradiation. Graphitic carbon nitride (g-C3N4) and boron-doped g-C3N4 (B-doped g-C3N4, BCNx) were prepared by heating melamine and a mixture of dicyanodiamide and BH3NH3, respectively. X-ray diffraction, a Brunauer, Emmett and Teller (BET) apparatus, and UV-vis spectra were used to analyze the physical properties of the prepared samples. Electrodes of these samples were prepared by using the electrophoresis method. X-ray photoelectron spectroscopy analyses confirmed the incorporation of boron atoms in the g-C3N4 framework as well as the amount of boron atoms. Au, Ag or Rh as a co-catalyst was coated on the surface of g-C3N4 and B-doped g-C3N4 by using the magnetron sputtering method. The photocurrent response was observed using a solar simulator as a light source. The photocurrent response of B-doped g-C3N4 was about 5-times larger than that of pure g-C3N4. B-doped g-C3N4 coated with Rh as a co-catalyst showed the highest photocurrent response under solar light irradiation, its photocurrent being about 10-times larger than that of original g-C3N4. Under photoelectrochemical conditions, we also observed the products in gas phase and aqueous phase. C2H5OH was observed as a main product, while small amounts of CO and H-2 were observed in gas phase. We also discuss the relationship between co-catalysts and photocurrent responses and the carbon source of C2H5OH as a main product. The source of carbon of C2H5OH obtained by CO2 reduction is discussed on the basis of results of a labeling experiment using (CO2)-C-13. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2016, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": 198, "Article Number": null, "DOI": "10.1016/j.apcatb.2016.03.055", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2016.03.055", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375887500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arora, N; Dar, MI; Hinderhofer, A; Pellet, N; Schreiber, F; Zakeeruddin, SM; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arora, Neha; Dar, M. Ibrahim; Hinderhofer, Alexander; Pellet, Norman; Schreiber, Frank; Zakeeruddin, Shaik Mohammed; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20%", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) with efficiencies greater than 20% have been realized only with expensive organic hole-transporting materials. We demonstrate PSCs that achieve stabilized efficiencies exceeding 20% with copper(I) thiocyanate (CuSCN) as the hole extraction layer. A fast solvent removal method enabled the creation of compact, highly conformal CuSCN layers that facilitate rapid carrier extraction and collection. The PSCs showed high thermal stability under long-term heating, although their operational stability was poor. This instability originated from potential-induced degradation of the CuSCN/Au contact. The addition of a conductive reduced graphene oxide spacer layer between CuSCN and gold allowed PSCs to retain >95% of their initial efficiency after aging at a maximum power point for 1000 hours under full solar intensity at 60 degrees C. Under both continuous full-sun illumination and thermal stress, CuSCN-based devices surpassed the stability of spiro-OMeTAD-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1299, "Times Cited, All Databases": 1382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2017, "Volume": 358, "Issue": 6364, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 768, "End Page": 771, "Article Number": null, "DOI": "10.1126/science.aam5655", "DOI Link": "http://dx.doi.org/10.1126/science.aam5655", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414847100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, XZ; Liu, ZY; Zhang, QH; Lopez, J; Wang, H; Wu, HC; Niu, SM; Yan, HP; Wang, SH; Lei, T; Li, JH; Qi, DP; Huang, PG; Huang, JP; Zhang, Y; Wang, YY; Li, GL; Tok, JBH; Chen, XD; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Xuzhou; Liu, Zhiyuan; Zhang, Qiuhong; Lopez, Jeffrey; Wang, Hui; Wu, Hung-Chin; Niu, Simiao; Yan, Hongping; Wang, Sihong; Lei, Ting; Li, Junheng; Qi, Dianpeng; Huang, Pingao; Huang, Jianping; Zhang, Yu; Wang, Yuanyuan; Li, Guanglin; Tok, Jeffery B. -H.; Chen, Xiaodong; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quadruple H-Bonding Cross-Linked Supramolecular Polymeric Materials as Substrates for Stretchable, Antitearing, and Self-Healable Thin Film Electrodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we report a de novo chemical design of supramolecular polymer materials (SPMs-1-3) by condensation polymerization, consisting of (i) soft polymeric chains (polytetramethylene glycol and tetraethylene glycol) and (ii) strong and reversible quadruple H-bonding cross-linkers (from 0 to 30 mol %). The former contributes to the formation of the soft domain of the SPMs, and the latter furnishes the SPMs with desirable mechanical properties, thereby producing soft, stretchable, yet tough elastomers. The resulting SPM-2 was observed to be highly stretchable (up to 17 000% strain), tough (fracture energy similar to 30000 J/m(2)), and self-healing, which are highly desirable properties and are superior to previously reported elastomers and tough hydrogels. Furthermore, a gold, thin film electrode deposited on this SPM substrate retains its conductivity and combines high stretchability (similar to 400%), fracture/notch insensitivity, self-healing, and good interfacial adhesion with the gold film. Again, these properties are all highly complementary to commonly used polydimethylsiloxane-based thin film metal electrodes. Last, we proceed to demonstrate the practical utility of our fabricated electrode via both in vivo and in vitro measurements of electromyography signals. This fundamental understanding obtained from the investigation of these SPMs will facilitate the progress of intelligent soft materials and flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 522, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 140, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5280, "End Page": 5289, "Article Number": null, "DOI": "10.1021/jacs.8b01682", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b01682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430642000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ying, HZ; Zhang, YF; Cheng, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ying, Hanze; Zhang, Yanfeng; Cheng, Jianjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic urea bond for the design of reversible and self-healing polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers bearing dynamic covalent bonds may exhibit dynamic properties, such as self-healing, shape memory and environmental adaptation. However, most dynamic covalent chemistries developed so far require either catalyst or change of environmental conditions to facilitate bond reversion and dynamic property change in bulk materials. Here we report the rational design of hindered urea bonds (urea with bulky substituent attached to its nitrogen) and the use of them to make polyureas and poly(urethane-urea)s capable of catalyst-free dynamic property change and autonomous repairing at low temperature. Given the simplicity of the hindered urea bond chemistry (reaction of a bulky amine with an isocyanate), incorporation of the catalyst-free dynamic covalent urea bonds to conventional polyurea or urea-containing polymers that typically have stable bulk properties may further broaden the scope of applications of these widely used materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 781, "Times Cited, All Databases": 864, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3218, "DOI": "10.1038/ncomms4218", "DOI Link": "http://dx.doi.org/10.1038/ncomms4218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332664000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, SL; Chen, CJ; Xia, QQ; Liu, Y; Yao, Y; Chen, QY; Hartsfield, M; Brozena, A; Tu, KK; Eichhorn, SJ; Yao, YG; Li, JG; Gan, WT; Shi, SQ; Yang, VW; Lo Ricco, M; Zhu, JY; Burgert, I; Luo, A; Li, T; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Shaoliang; Chen, Chaoji; Xia, Qinqin; Liu, Yu; Yao, Yuan; Chen, Qiongyu; Hartsfield, Matt; Brozena, Alexandra; Tu, Kunkun; Eichhorn, Stephen J.; Yao, Yonggang; Li, Jianguo; Gan, Wentao; Shi, Sheldon Q.; Yang, Vina W.; Lo Ricco, Marco; Zhu, J. Y.; Burgert, Ingo; Luo, Alan; Li, Teng; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, strong, moldable wood via cell wall engineering as a sustainable structural material", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wood is a sustainable structural material, but it cannot be easily shaped while maintaining its mechanical properties. We report a processing strategy that uses cell wall engineering to shape flat sheets of hardwood into versatile three-dimensional (3D) structures. After breaking down wood's lignin component and closing the vessels and fibers by evaporating water, we partially re-swell the wood in a rapid water-shock process that selectively opens the vessels. This forms a distinct wrinkled cell wall structure that allows the material to be folded and molded into desired shapes. The resulting 3D-molded wood is six times stronger than the starting wood and comparable to widely used lightweight materials such as aluminum alloys. This approach widens wood's potential as a structural material, with lower environmental impact for buildings and transportation applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2021, "Volume": 374, "Issue": 6566, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 465, "End Page": 471, "Article Number": null, "DOI": "10.1126/science.abg9556", "DOI Link": "http://dx.doi.org/10.1126/science.abg9556", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000710251800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, ZY; Tung, PY; Xie, RW; Wei, Y; Zhang, HB; Ferrari, A; Klaver, TPC; Körmann, F; Sukumar, PT; da Silva, AK; Chen, Y; Li, ZM; Ponge, D; Neugebauer, J; Gutfleisch, O; Bauer, S; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Ziyuan; Tung, Po-Yen; Xie, Ruiwen; Wei, Ye; Zhang, Hongbin; Ferrari, Alberto; Klaver, T. P. C.; Koermann, Fritz; Sukumar, Prithiv Thoudden; da Silva, Alisson Kwiatkowski; Chen, Yao; Li, Zhiming; Ponge, Dirk; Neugebauer, Joerg; Gutfleisch, Oliver; Bauer, Stefan; Raabe, Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning-enabled high-entropy alloy discovery", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys are solid solutions of multiple principal elements that are capable of reaching composition and property regimes inaccessible for dilute materials. Discovering those with valuable properties, however, too often relies on serendipity, because thermodynamic alloy design rules alone often fail in high-dimensional composition spaces. We propose an active learning strategy to accelerate the design of high-entropy Invar alloys in a practically infinite compositional space based on very sparse data. Our approach works as a closed-loop, integrating machine learning with density-functional theory, thermodynamic calculations, and experiments. After processing and characterizing 17 new alloys out of millions of possible compositions, we identified two high-entropy Invar alloys with extremely low thermal expansion coefficients around 2 x 10-6 per degree kelvin at 300 kelvin. We believe this to be a suitable pathway for the fast and automated discovery of high-entropy alloys with optimal thermal, magnetic, and electrical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2022, "Volume": 378, "Issue": 6615, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 84, "Article Number": null, "DOI": "10.1126/science.abo4940", "DOI Link": "http://dx.doi.org/10.1126/science.abo4940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909870100058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HT; Xu, SC; Tsai, C; Li, YZ; Liu, C; Zhao, J; Liu, YY; Yuan, HY; Abild-Pedersen, F; Prinz, FB; Norskov, JK; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haotian; Xu, Shicheng; Tsai, Charlie; Li, Yuzhang; Liu, Chong; Zhao, Jie; Liu, Yayuan; Yuan, Hongyuan; Abild-Pedersen, Frank; Prinz, Fritz B.; Norskov, Jens K.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct and continuous strain control of catalysts with tunable battery electrode materials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a method for using battery electrode materials to directly and continuously control the lattice strain of platinum (Pt) catalyst and thus tune its catalytic activity for the oxygen reduction reaction (ORR). Whereas the common approach of using metal overlayers introduces ligand effects in addition to strain, by electrochemically switching between the charging and discharging status of battery electrodes the change in volume can be precisely controlled to induce either compressive or tensile strain on supported catalysts. Lattice compression and tension induced by the lithium cobalt oxide substrate of similar to 5% were directly observed in individual Pt nulloparticles with aberration-corrected transmission electron microscopy. We observed 90% enhancement or 40% suppression in Pt ORR activity under compression or tension, respectively, which is consistent with theoretical predictions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 565, "Times Cited, All Databases": 604, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2016, "Volume": 354, "Issue": 6315, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1031, "End Page": 1036, "Article Number": null, "DOI": "10.1126/science.aaf7680", "DOI Link": "http://dx.doi.org/10.1126/science.aaf7680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388531800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, Y; Zheng, Y; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Yan; Zheng, Yao; Jaroniec, Mietek; Qiao, Shi Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of the Electrocatalytic Oxygen Reduction Activity of Graphene-Based Catalysts: A Roadnnap to Achieve the Best Performance", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mutually corroborated electrochemical measurements and density functional theory (DFT) calculations were used to uncover the origin of electrocatalytic activity of graphene-based electrocatalysts for oxygen reduction reaction (ORR). A series of graphenes doped with nonmetal elements was designed and synthesized, and their ORR performance was evaluated in terms of four electrochemical descriptors: exchange current density, on-set potential, reaction pathway selectivity and kinetic current density. It is shown that these descriptors are in good agreement with DFT calculations, allowing derivation of a volcano plot between the ORR activity and the adsorption free energy of intermediates on metal-free materials, similarly as in the case of metallic catalysts. The molecular orbital concept was used to justify this volcano plot, and to theoretically predict the ORR performance of an ideal graphene-based catalyst, the ORR activity of which is comparable to the state-of-the-art Pt catalyst. Moreover, this study may stimulate the development of metal-free electrocatalysts for other key energy conversion processes including hydrogen evolution and oxygen evolution reactions and largely expand the spectrum of catalysts for energy-related electrocatalysis reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 966, "Times Cited, All Databases": 1012, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2014, "Volume": 136, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4394, "End Page": 4403, "Article Number": null, "DOI": "10.1021/ja500432h", "DOI Link": "http://dx.doi.org/10.1021/ja500432h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333435500042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chuang, CHM; Brown, PR; Bulovic, V; Bawendi, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chuang, Chia-Hao M.; Brown, Patrick R.; Bulovic, Vladimir; Bawendi, Moungi G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved performance and stability in quantum dot solar cells through band alignment engineering", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution processing is a promising route for the realization of low-cost, large-area, flexible and lightweight photovoltaic devices with short energy payback time and high specific power. However, solar cells based on solution-processed organic, inorganic and hybrid materials reported thus far generally suffer from poor air stability, require an inert-atmosphere processing environment or necessitate high-temperature processing(1), all of which increase manufacturing complexities and costs. Simultaneously fulfilling the goals of high efficiency, low-temperature fabrication conditions and good atmospheric stability remains a major technical challenge, which may be addressed, as we demonstrate here, with the development of room-temperature solution-processed ZnO/PbS quantum dot solar cells. By engineering the band alignment of the quantum dot layers through the use of different ligand treatments, a certified efficiency of 8.55% has been reached. Furthermore, the performance of unencapsulated devices remains unchanged for over 150 days of storage in air. This material system introduces a new approach towards the goal of high-performance air-stable solar cells compatible with simple solution processes and deposition on flexible substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1220, "Times Cited, All Databases": 1238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 13, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 796, "End Page": 801, "Article Number": null, "DOI": "10.1038/NMAT3984", "DOI Link": "http://dx.doi.org/10.1038/NMAT3984", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339647800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Ma, X; Wu, SF; Tian, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hui; Ma, Xiang; Wu, Shuaifan; Tian, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Rapidly Self-Healing Supramolecular Polymer Hydrogel with Photostimulated Room-Temperature Phosphorescence Responsiveness", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of self-healing and photostimulated luminescent supramolecular polymeric materials is important for artificial soft materials. A supramolecular polymeric hydrogel is reported based on the host-guest recognition between a beta-cyclodextrin (beta-CD) host polymer (poly-beta-CD) and an alpha-bromonaphthalene (alpha-BrNp) polymer (poly-BrNp) without any additional gelator, which can self-heal within only about one minute under ambient atmosphere without any additive. This supramolecular polymer system can be excited to engender room-temperature phosphorescence (RTP) signals based on the fact that the inclusion of beta-CD macrocycle with alpha-BrNp moiety is able to induce RTP emission (CD-RTP). The RTP signal can be adjusted reversibly by competitive complexation of beta-CD with azobenzene moiety under specific irradiation by introducing another azobenzene guest polymer (polyAzo).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2014, "Volume": 53, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14149, "End Page": 14152, "Article Number": null, "DOI": "10.1002/anie.201407402", "DOI Link": "http://dx.doi.org/10.1002/anie.201407402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346484400035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thompson, AP; Aktulga, HM; Berger, R; Bolintineanu, DS; Brown, WM; Crozier, PS; Veld, PJI; Kohlmeyer, A; Moore, SG; Nguyen, TD; Shan, R; Stevens, MJ; Tranchida, J; Trott, C; Plimpton, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thompson, Aidan P.; Aktulga, H. Metin; Berger, Richard; Bolintineanu, Dan S.; Brown, W. Michael; Crozier, Paul S.; Veld, Pieter J. in 't; Kohlmeyer, Axel; Moore, Stan G.; Nguyen, Trung Dac; Shan, Ray; Stevens, Mark J.; Tranchida, Julien; Trott, Christian; Plimpton, Steven J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LAMMPS-a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the classical molecular dynamics simulator LAMMPS was released as an open source code in 2004, it has become a widely-used tool for particle-based modeling of materials at length scales ranging from atomic to mesoscale to continuum. Reasons for its popularity are that it provides a wide variety of particle interaction models for different materials, that it runs on any platform from a single CPU core to the largest supercomputers with accelerators, and that it gives users control over simulation details, either via the input script or by adding code for new interatomic potentials, constraints, diagnostics, or other features needed for their models. As a result, hundreds of people have contributed new capabilities to LAMMPS and it has grown from fifty thousand lines of code in 2004 to a million lines today. In this paper several of the fundamental algorithms used in LAMMPS are described along with the design strategies which have made it flexible for both users and developers. We also highlight some capabilities recently added to the code which were enabled by this flexibility, including dynamic load balancing, on-the-fly visualization, magnetic spin dynamics models, and quantum-accuracy machine learning interatomic potentials. Program Summary Program Title: Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) CPC Library link to program files: https://doi .org /10 .17632 /cxbxs9btsv.1 Developer's repository link: https://github .com /lammps /lammps Licensing provisions: GPLv2 Programming language: C++, Python, C, Fortran Supplementary material: https://www.lammps .org Nature of problem: Many science applications in physics, chemistry, materials science, and related fields require parallel, scalable, and efficient generation of long, stable classical particle dynamics trajectories. Within this common problem definition, there lies a great diversity of use cases, distinguished by different particle interaction models, external constraints, as well as timescales and lengthscales ranging from atomic to mesoscale to macroscopic. Solution method: The LAMMPS code uses parallel spatial decomposition, distributed neighbor lists, and parallel FFTs for long-range Coulombic interactions [1]. The time integration algorithm is based on the Stormer-Verlet symplectic integrator [2], which provides better stability than higher-order non-symplectic methods. In addition, LAMMPS supports a wide range of interatomic potentials, constraints, diagnostics, software interfaces, and pre- and post-processing features. Additional comments including restrictions and unusual features: This paper serves as the definitive reference for the LAMMPS code. References [1] S. Plimpton, Fast parallel algorithms for short-range molecular dynamics. J. Comp. Phys. 117 (1995) 1-19. [2] L. Verlet, Computer experiments on classical fluids: I. Thermodynamical properties of Lennard-Jones molecules, Phys. Rev. 159 (1967) 98-103. (c) 2021 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5692, "Times Cited, All Databases": 5969, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 271, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108171, "DOI": "10.1016/j.cpc.2021.108171", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.108171", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720461800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JM; Wang, BB; Liu, XJ; Bai, JT; Wang, H; Wang, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiamei; Wang, Beibei; Liu, Xiaojie; Bai, Jintao; Wang, Hui; Wang, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prussian blue analogs (PBA) derived porous bimetal (Mn, Fe) selenide with carbon nullotubes as anode materials for sodium and potassium ion batteries", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of sodium/potassium-ion batteries with excellent performance would break the conflict between the limited lithium resources and low-price requirement of lithium-ion batteries. However, because of the bigger sizes of sodium/potassium ion in comparison to lithium ion, the requirement of anode materials with suitable structure for sodium/potassium ions insertion/extraction is still challenging. Here, porous MnSe/FeSe2 (Mn-Fe-Se) adhered/inserted with interlaced carbon nullotubes (CNTs) have been successfully designed and prepared via a simple chemical precipitation approach and a subsequent one-step carbonization-selenization of Mn-Fe Prussian blue analogs precursor process. Characterization results demonstrate that the prepared Mn-Fe-Se/CNTs with high conductive network architecture are constructed by Mn-Fe-Se sphere adhered/inserted with interlaced CNTs, each Mn-Fe-Se sphere is assembled using several tens of nulloparticles and numerous voids, and the individual nulloparticle is uniformly coated by a thin nitrogen-doped amorphous carbon layer. Due to such unique porous architecture and synergistic effect of the heterogeneous components, Mn-Fe-Se/CNTs anode possesses reversible sodium/potassium storage with excellent rate performance and prominent cycling stability. Furthermore, the sodium and potassium storage mechanisms and kinetics verify the fundamental principles of improved electrochemical performance. This study will shed light on the development of other metal selenides with interlaced carbon nullotubes for high-performance sodium/potassium-ion batteries and other energy storage equipment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2020, "Volume": 382, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123050, "DOI": "10.1016/j.cej.2019.123050", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.123050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503381200215", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, GL; Robertson, AW; Li, MMJ; Kuo, WCH; Darby, MT; Muhieddine, MH; Lin, YC; Suenaga, K; Stamatakis, M; Warner, JH; Tsang, SCE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Guoliang; Robertson, Alex W.; Li, Molly Meng-Jung; Kuo, Winson C. H.; Darby, Matthew T.; Muhieddine, Mohamad H.; Lin, Yung-Chang; Suenaga, Kazu; Stamatakis, Michail; Warner, Jamie H.; Tsang, Shik Chi Edman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2 monolayer catalyst doped with isolated Co atoms for the hydrodeoxygenation reaction", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of oxygen-rich biomass into hydrocarbon fuels requires efficient hydrodeoxygenation catalysts during the upgrading process. However, traditionally prepared CoMoS2 catalysts, although efficient for hydrodesulfurization, are not appropriate due to their poor activity, sulfur loss and rapid deactivation at elevated temperature. Here, we report the synthesis of MoS2 monolayer sheets decorated with isolated Co atoms that bond covalently to sulfur vacancies on the basal planes that, when compared with conventionally prepared samples, exhibit superior activity, selectivity and stability for the hydrodeoxygenation of 4-methylphenol to toluene. This higher activity allows the reaction temperature to be reduced from the typically used 300 degrees C to 180 degrees C and thus allows the catalysis to proceed without sulfur loss and deactivation. Experimental analysis and density functional theory calculations reveal a large number of sites at the interface between the Co and Mo atoms on the MoS2 basal surface and we ascribe the higher activity to the presence of sulfur vacancies that are created local to the observed Co-S-Mo interfacial sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 746, "Times Cited, All Databases": 788, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 810, "End Page": 816, "Article Number": null, "DOI": "10.1038/NCHEM.2740", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2740", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406206400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JT; Dou, YH; Wei, ZX; Ma, JM; Deng, YH; Li, YT; Liu, HK; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jiantie; Dou, Yuhai; Wei, Zengxi; Ma, Jianmin; Deng, Yonghong; Li, Yutao; Liu, Huakun; Dou, Shixue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) with higher energy density are very necessary to meet the increasing demand for devices with better performance. With the commercial success of lithiated graphite, other graphite intercalation compounds (GICs) have also been intensively reported, not only for LIBs, but also for other metal (Na, K, Al) ion batteries. In this Progress Report, we briefly review the application of GICs as anodes and cathodes in metal (Li, Na, K, Al) ion batteries. After a brief introduction on the development history of GICs, the electrochemistry of cationic GICs and anionic GICs is summarized. We further briefly summarize the use of cationic GICs and anionic GICs in alkali ion batteries and the use of anionic GICs in aluminium-ion batteries. Finally, we reach some conclusions on the drawbacks, major progress, emerging challenges, and some perspectives on the development of GICs for metal (Li, Na, K, Al) ion batteries. Further development of GICs for metal (Li, Na, K, Al) ion batteries is not only a strong supplement to the commercialized success of lithiated-graphite for LIBs, but also an effective strategy to develop diverse high-energy batteries for stationary energy storage in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 478, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700146, "DOI": "10.1002/advs.201700146", "DOI Link": "http://dx.doi.org/10.1002/advs.201700146", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413166700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pellet, N; Gao, P; Gregori, G; Yang, TY; Nazeeruddin, MK; Maier, J; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pellet, Norman; Gao, Peng; Gregori, Giuliano; Yang, Tae-Youl; Nazeeruddin, Mohammad K.; Maier, Joachim; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic lead halide perovskite APbX(3) pigments, such as methylammonium lead iodide, have recently emerged as excellent light harvesters in solid-state mesoscopic solar cells. An important target for the further improvement of the performance of perovskite-based photovoltaics is to extend their optical-absorption onset further into the red to enhance solar-light harvesting. Herein, we show that this goal can be reached by using a mixture of formamidinium (HN=CHNH3+, FA) and methylammonium (CH3NH3+, MA) cations in the Aposition of the APbI(3) perovskite structure. This combination leads to an enhanced short-circuit current and thus superior devices to those based on only CH3NH3+. This concept has not been applied previously in perovskite-based solar cells. It shows great potential as a versatile tool to tune the structural, electrical, and optoelectronic properties of the light-harvesting materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1140, "Times Cited, All Databases": 1226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2014, "Volume": 53, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3151, "End Page": 3157, "Article Number": null, "DOI": "10.1002/anie.201309361", "DOI Link": "http://dx.doi.org/10.1002/anie.201309361", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332747700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eperon, GE; Paternò, GM; Sutton, RJ; Zampetti, A; Haghighirad, AA; Cacialli, F; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eperon, Giles E.; Paterno, Giuseppe M.; Sutton, Rebecca J.; Zampetti, Andrea; Haghighirad, Amir Abbas; Cacialli, Franco; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inorganic caesium lead iodide perovskite solar cells", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The vast majority of perovskite solar cell research has focused on organic-inorganic lead trihalide perovskites. Herein, we present working inorganic CsPbI3 perovskite solar cells for the first time. CsPbI3 normally resides in a yellow non-perovskite phase at room temperature, but by careful processing control and development of a low-temperature phase transition route we have stabilised the material in the black perovskite phase at room temperature. As such, we have fabricated solar cell devices in a variety of architectures, with current-voltage curve measured efficiency up to 2.9% for a planar heterojunction architecture, and stabilised power conversion efficiency of 1.7%. The well-functioning planar junction devices demonstrate long-range electron and hole transport in this material. Importantly, this work identifies that the organic cation is not essential, but simply a convenience for forming lead triiodide perovskites with good photovoltaic properties. We additionally observe significant rate-dependent current-voltage hysteresis in CsPbI3 devices, despite the absence of the organic polar molecule previously thought to be a candidate for inducing hysteresis via ferroelectric polarisation. Due to its space group, CsPbI3 cannot be a ferroelectric material, and thus we can conclude that ferroelectricity is not required to explain current-voltage hysteresis in perovskite solar cells. Our report of working inorganic perovskite solar cells paves the way for further developments likely to lead to much more thermally stable perovskite solar cells and other optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1534, "Times Cited, All Databases": 1626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19688, "End Page": 19695, "Article Number": null, "DOI": "10.1039/c5ta06398a", "DOI Link": "http://dx.doi.org/10.1039/c5ta06398a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362041300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, HL; Zhang, Y; Qiu, Y; Wu, HP; Qin, WY; Liao, YB; Yu, QM; Cheng, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Honglei; Zhang, Yue; Qiu, Ye; Wu, Huaping; Qin, Weiyang; Liao, Yabin; Yu, Qingmin; Cheng, Huanyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable piezoelectric energy harvesters and self-powered sensors for wearable and implantable devices", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable and implantable bio-integrated electronics have started to gain momentum because of their essential role in improving the quality of life for various patients and healthy individuals. However, their continuous operation is often limited by traditional battery technologies with a limited lifespan, creating a significant challenge for their development. Thus, it is highly desirable to harvest biomechanical energies from human motion for self-powered bio-integrated functional devices. Piezoelectric energy harvesters are ideal candidates to achieve this goal by converting biomechanical energy to electric energy. Because of their applications on soft and highly deformable tissues of the human body, these devices also need to be mechanically flexible and stretchable, thus posing a significant challenge. Effective methods to address the challenge include the exploration of new stretchable piezoelectric materials (e.g., hybrid composite material) and stretchable structures (e.g., buckled shapes, serpentine mesh layouts, kirigami designs, among others). This review presents an overview of the recent developments in new intrinsically stretchable piezoelectric materials and rigid inorganic piezoelectric materials with novel stretchable structures for flexible and stretchable piezoelectric sensors and energy harvesters. Following the discussion of theoretical modeling of the piezoelectric materials to convert mechanical deformations into electrical signals, the representative applications of stretchable piezoelectric materials and structures in wearable and implantable devices are briefly summarized. The present limitations and future research directions of flexible and stretchable piezoelectric devices are then discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2020, "Volume": 168, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112569, "DOI": "10.1016/j.bios.2020.112569", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2020.112569", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000574928500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, V; Xu, N; Liu, JC; Tang, G; Geng, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Vei; Xu, null; Liu, Jin-Cheng; Tang, Gang; Geng, Wen-Tong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "VASPKIT: A user-friendly interface facilitating high-throughput computing and analysis using VASP code", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the VASPKIT, a command-line program that aims at providing a robust and user-friendly interface to perform high-throughput analysis of a variety of material properties from the raw data produced by the VASP code. It consists of mainly the pre-and post-processing modules. The former module is designed to prepare and manipulate input files such as the necessary input files generation, symmetry analysis, supercell transformation, k-path generation for a given crystal structure. The latter module is designed to extract and analyze the raw data about elastic mechanics, electronic structure, charge density, electrostatic potential, linear optical coefficients, wave function plots in real space, etc. This program can run conveniently in either interactive user interface or command line mode. The command-line options allow the user to perform high-throughput calculations together with bash scripts. This article gives an overview of the program structure and presents illustrative examples for some of its usages. The program can run on Linux, macOS, and Windows platforms. The executable versions of VASPKIT and the related examples and tutorials are available on its official website vaspkit .com. Program summary Program title: VASPKIT CPC Library link to program files: https://doi.org/10.17632/v3bvcypg9v.1 Licensing provisions: GPLv3 Programming language: Fortran, Python Nature of problem: This program has the purpose of providing a powerful and user-friendly interface to perform high-throughput calculations together with the widely-used VASP code. Solution method: VASPKIT can extract, calculate and even plot the mechanical, electronic, optical and magnetic properties from density functional calculations together with bash and python scripts. It can run in either interactive user interface or command line mode. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3941, "Times Cited, All Databases": 4028, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 267, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108033, "DOI": "10.1016/j.cpc.2021.108033", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.108033", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678508900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, ZR; Lv, XH; Hou, Y; Wang, KF; Ren, FZ; Xu, DG; Wang, Q; Fan, KL; Xie, CM; Lu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Zhanrong; Lv, Xuanhan; Hou, Yue; Wang, Kefeng; Ren, Fuzeng; Xu, Dingguo; Wang, Qun; Fan, Kelong; Xie, Chaoming; Lu, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mussel-inspired nullozyme catalyzed conductive and self-setting hydrogel for adhesive and antibacterial bioelectronics", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesive hydrogels have broad applications ranging from tissue engineering to bioelectronics; however, fabricating adhesive hydrogels with multiple functions remains a challenge. In this study, a mussel-inspired tannic acid chelated-Ag (TA-Ag) nullozyme with peroxidase (POD)-like activity was designed by the in situ reduction of ultrasmall Ag nulloparticles (NPs) with TA. The ultrasmall TA-Ag nullozyme exhibited high catalytic activity to induce hydrogel self-setting without external aid. The nullozyme retained abundant phenolic hydroxyl groups and maintained the dynamic redox balance of phenol-quinone, providing the hydrogels with long-term and repeatable adhesiveness, similar to the adhesion of mussels. The phenolic hydroxyl groups also afforded uniform distribution of the nullozyme in the hydrogel network, thereby improving its mechanical properties and conductivity. Furthermore, the nullozyme endowed the hydrogel with antibacterial activity through synergistic effects of the reactive oxygen species generated via POD-like catalytic reactions and the intrinsic bactericidal activity of Ag. Owing to these advantages, the ultrasmall TA-Ag nullozyme-catalyzed hydrogel could be effectively used as an adhesive, antibacterial, and implantable bioelectrode to detect bio-signals, and as a wound dressing to accelerate tissue regeneration while preventing infection. Therefore, this study provides a promising approach for the fabrication of adhesive hydrogel bioelectronics with multiple functions via mussel-inspired nullozyme catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2676, "End Page": 2687, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.01.033", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.01.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662249100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paille, G; Gomez-Mingot, M; Roch-Marchal, C; Lassalle-Kaiser, B; Mialane, P; Fontecave, M; Mellot-Draznieks, C; Dolbecq, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paille, Gregoire; Gomez-Mingot, Maria; Roch-Marchal, Catherine; Lassalle-Kaiser, Benedikt; Mialane, Pierre; Fontecave, Marc; Mellot-Draznieks, Caroline; Dolbecq, Anne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Fully Noble Metal-Free Photosystem Based on Cobalt-Polyoxometalates Immobilized in a Porphyrinic Metal-Organic Framework for Water Oxidation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sandwich-type polyoxometalate (POM) [(PW9O34)(2)Co-4(H2O)(2)](10-) was immobilized in the hexagonal channels of the Zr(IV) porphyrinic MOF-545 hybrid framework. The resulting composite was fully characterized by a panel of physicochemical techniques. Calculations allowed identifying the localization of the POM in the vicinity of the Zr-6 clusters and porphyrin linkers constituting the MOF. The material exhibits a high photocatalytic activity and good stability for visible-light-driven water oxidation. It thus represents a rare example of an all-in-one fully noble metal-free supramolecular heterogeneous photocatalytic system, with the catalyst and the photo-sensitizer within the same porous solid material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 140, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3613, "End Page": 3618, "Article Number": null, "DOI": "10.1021/jacs.7b11788", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b11788", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427910700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dris, R; Gasperi, J; Saad, M; Mirande, C; Tassin, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dris, Rachid; Gasperi, Johnny; Saad, Mohamed; Mirande, Cecile; Tassin, Bruno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic fibers in atmospheric fallout: A source of microplastics in the environment?", "Source Title": "MARINE POLLUTION BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sources, pathways and reservoirs of microplastics, plastic particles smaller than 5 mm, remain poorly documented in an urban context. While some studies pointed out wastewater treatment plants as a potential pathway of microplastics, none have focused on the atmospheric compartment. In this work, the atmospheric fallout of microplastics was investigated in two different urban and sub-urban sites. Microplastics were collected continuously with a stainless steel funnel. Samples were then filtered and observed with a stereomicroscope. Fibers accounted for almost all the microplastics collected. An atmospheric fallout between 2 and 355 particles/m(2)/day was highlighted. Registered fluxes were systematically higher at the urban than at the sub-urban site. Chemical characterization allowed to estimate at 29% the proportion of these fibers being all synthetic (made with petrochemicals), or a mixture of natural and synthetic material. Extrapolation using weight and volume estimates of the collected fibers, allowed a rough estimation showing that between 3 and 10 tons of fibers are deposited by atmospheric fallout at the scale of the Parisian agglomeration every year (2500 km(2)). These results could serve the scientific community working on the different sources of microplastic in both continental and marine environments. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1336, "Times Cited, All Databases": 1518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2016, "Volume": 104, "Issue": "1-2", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 293, "Article Number": null, "DOI": "10.1016/j.marpolbul.2016.01.006", "DOI Link": "http://dx.doi.org/10.1016/j.marpolbul.2016.01.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374198100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Desai, SB; Madhvapathy, SR; Sachid, AB; Llinas, JP; Wang, QX; Ahn, GH; Pitner, G; Kim, MJ; Bokor, J; Hu, CM; Wong, HSP; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Desai, Sujay B.; Madhvapathy, Surabhi R.; Sachid, Angada B.; Llinas, Juan Pablo; Wang, Qingxiao; Ahn, Geun Ho; Pitner, Gregory; Kim, Moon J.; Bokor, Jeffrey; Hu, Chenming; Wong, H. -S. Philip; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2 transistors with 1-nullometer gate lengths", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scaling of silicon (Si) transistors is predicted to fail below 5-nullometer (nm) gate lengths because of severe short channel effects. As an alternative to Si, certain layered semiconductors are attractive for their atomically uniform thickness down to a monolayer, lower dielectric constants, larger band gaps, and heavier carrier effective mass. Here, we demonstrate molybdenum disulfide (MoS2) transistors with a 1-nm physical gate length using a single-walled carbon nullotube as the gate electrode. These ultrashort devices exhibit excellent switching characteristics with near ideal subthreshold swing of similar to 65 millivolts per decade and an On/Off current ratio of similar to 10(6). Simulations show an effective channel length of similar to 3.9 nm in the Off state and similar to 1 nm in the On state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1217, "Times Cited, All Databases": 1368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2016, "Volume": 354, "Issue": 6308, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 99, "End Page": 102, "Article Number": null, "DOI": "10.1126/science.aah4698", "DOI Link": "http://dx.doi.org/10.1126/science.aah4698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387777900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GG; Zhu, JW; Yuan, PF; Hu, YF; Qu, G; Lu, BA; Xue, XY; Yin, HB; Cheng, WZ; Cheng, JQ; Xu, WJ; Li, J; Hu, JS; Mu, SC; Zhang, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Gege; Zhu, Jiawei; Yuan, Pengfei; Hu, Yongfeng; Qu, Gan; Lu, Bang-An; Xue, Xiaoyi; Yin, Hengbo; Cheng, Wenzheng; Cheng, Junqi; Xu, Wenjing; Li, Jin; Hu, Jinsong; Mu, Shichun; Zhang, Jia-null", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As low-cost electrocatalysts for oxygen reduction reaction applied to fuel cells and metal-air batteries, atomic-dispersed transition metal-nitrogen-carbon materials are emerging, but the genuine mechanism thereof is still arguable. Herein, by rational design and synthesis of dual-metal atomically dispersed Fe,Mn/N-C catalyst as model object, we unravel that the O-2 reduction preferentially takes place on Fe-III in the FeN4/C system with intermediate spin state which possesses one e(g) electron (t(2g)4e(g)1) readily penetrating the antibonding pi-orbital of oxygen. Both magnetic measurements and theoretical calculation reveal that the adjacent atomically dispersed Mn-N moieties can effectively activate the Fe-III sites by both spin-state transition and electronic modulation, rendering the excellent ORR performances of Fe, Mn/N-C in both alkaline and acidic media (halfwave positionals are 0.928 V in 0.1 M KOH, and 0.804 V in 0.1 M HClO4), and good durability, which outperforms and has almost the same activity of commercial Pt/C, respectively. In addition, it presents a superior power density of 160.8 mW cm(-2) and long-term durability in reversible zinc-air batteries. The work brings new insight into the oxygen reduction reaction process on the metal-nitrogen-carbon active sites, undoubtedly leading the exploration towards high effective low-cost non-precious catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 702, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1734, "DOI": "10.1038/s41467-021-21919-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21919-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631927600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SS; Dai, XZ; Xu, S; Jiao, HY; Zhao, L; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shangshang; Dai, Xuezeng; Xu, Shuang; Jiao, Haoyang; Zhao, Liang; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing perovskite-substrate interfaces for high-performance perovskite modules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interfaces of perovskite solar cells (PSCs) are important in determining their efficiency and stability, but the morphology and stability of imbedded perovskite-substrate interfaces have received less attention than have top interfaces. We found that dimethyl sulfoxide (DMSO), which is a liquid additive broadly applied to enhance perovskite film morphology, was trapped during film formation and led to voids at perovskite-substrate interfaces that accelerated the film degradation under illumination. Partial replacement of DMSO with solid-state carbohydrazide reduces interfacial voids. A maximum stabilized power conversion efficiency (PCE) of 23.6% was realized for blade-coated p-type/intrinsic/n-type (p-i-n) structure PSCs with no efficiency loss after 550-hour operational stability tests at 60 degrees C. The perovskite mini-modules showed certified PCEs of 19.3 and 19.2%, with aperture areas of 18.1 and 50.0 square centimeters, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 597, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2021, "Volume": 373, "Issue": 6557, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 902, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abi6323", "DOI Link": "http://dx.doi.org/10.1126/science.abi6323", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686562400034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, HR; Pan, YM; Wang, X; Liu, CT; Shen, CY; Schubert, DW; Guo, ZH; Liu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Haoran; Pan, Yamin; Wang, Xin; Liu, Chuntai; Shen, Changyu; Schubert, Dirk W.; Guo, Zhanhu; Liu, Xianhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni Flower/MXene-Melamine Foam Derived 3D Magnetic/Conductive Networks for Ultra-Efficient Microwave Absorption and Infrared Stealth", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of multifunctional and efficient electromagnetic wave absorbing materials is a challenging research hotspot. Here, the magnetized Ni flower/MXene hybrids are successfully assembled on the surface of melamine foam (MF) through electrostatic self-assembly and dip-coating adsorption process, realizing the integration of microwave absorption, infrared stealth, and flame retardant. Remarkably, the Ni/MXene-MF achieves a minimum reflection loss (RLmin) of - 62.7 dB with a corresponding effective absorption bandwidth (EAB) of 6.24 GHz at 2 mm and an EAB of 6.88 GHz at 1.8 mm. Strong electromagnetic wave absorption is attributed to the three-dimensional magnetic/conductive networks, which provided excellent impedance matching, dielectric loss, magnetic loss, interface polarization, and multiple attenuations. In addition, the Ni/MXene-MF endows low density, excellent heat insulation, infrared stealth, and flame-retardant functions. This work provided a new development strategy for the design of multifunctional and efficient electromagnetic wave absorbing materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 63, "DOI": "10.1007/s40820-022-00812-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00812-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758821300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mamtani, K; Jain, D; Dogu, D; Gustin, V; Gunduz, S; Co, AC; Ozkan, US", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mamtani, Kuldeep; Jain, Deeksha; Dogu, Doruk; Gustin, Vance; Gunduz, Seval; Co, Anne C.; Ozkan, Unit S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) active sites for nitrogen-doped carbon nullostructures (CNx) in acidic media", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study demonstrates promising bifunctionality of nitrogen-doped carbon nullostructures (CNX ) for ORR and OER in acidic medium. Although CNX catalysts are not as active as Pt/C in ORR and Ir/C in OER, they exhibit significantly lower combined overpotential for ORR and OER relative to those shown by the two commercial catalysts, which are highly active only for one of the two reactions, but not both. The effect of various nitrogen functionalities on the ORR and OER activity of CNX catalysts was also studied. CNX samples with higher pyridinic-N site density exhibited higher ORR and OER activity. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 220, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 88, "End Page": 97, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.07.086", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.07.086", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412957200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Si, Y; Wang, XQ; Dou, LY; Yu, JY; Ding, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Si, Yang; Wang, Xueqin; Dou, Lvye; Yu, Jianyong; Ding, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight and fire-resistant ceramic nullofibrous aerogels with temperature-invariant superelasticity", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultralight aerogels that are both highly resilient and compressible have been fabricated from various materials including polymer, carbon, and metal. However, it has remained a great challenge to realize high elasticity in aerogels solely based on ceramic components. We report a scalable strategy to create superelastic lamellar-structured ceramic nullofibrous aerogels (CNFAs) by combining SiO2 nullofibers with aluminoborosilicate matrices. This approach causes the random-deposited SiO2 nullofibers to assemble into elastic ceramic aerogels with tunable densities and desired shapes on a large scale. The resulting CNFAs exhibit the integrated properties of flyweight densities of >0.15mg cm(-3), rapid recovery from 80% strain, zero Poisson's ratio, and temperature-invariant superelasticity to 1100 degrees C. The integral ceramic nature also provided the CNFAs with robust fire resistance and thermal insulation performance. The successful synthesis of these fascinating materials may provide new insights into the development of ceramics in a lightweight, resilient, and structurally adaptive form.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaas8925", "DOI": "10.1126/sciadv.aas8925", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aas8925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431374900070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, LM; Zhang, F; Chen, YQ; Guan, L; Zhu, YQ; Chen, M; Wang, HL; Putra, BR; Zhang, R; Fan, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Limeng; Zhang, Fan; Chen, Yongqiang; Guan, Li; Zhu, Yanqiu; Chen, Mao; Wang, Hailong; Putra, Budi Riza; Zhang, Rui; Fan, Bingbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional SiC@SiO2 nullofiber Aerogel with Ultrabroadband Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional ceramic materials are generally brittle and not flexible with high production costs, which seriously hinders their practical applications. Multifunctional nullofiber ceramic aerogels are highly desirable for applications in extreme environments, however, the integration of multiple functions in their preparation is extremely challenging. To tackle these challenges, we fabricated a multifunctional SiC@SiO2 nullofiber aerogel (SiC@SiO2 NFA) with a three-dimensional (3D) porous cross-linked structure through a simple chemical vapor deposition method and subsequent heat-treatment process. The as-prepared SiC@SiO2 NFA exhibits an ultralow density (similar to 11 mg cm(- 3)), ultra-elastic, fatigue-resistant and refractory performance, high temperature thermal stability, thermal insulation properties, and significant strain-dependent piezoresistive sensing behavior. Furthermore, the SiC@SiO2 NFA shows a superior electromagnetic wave absorption performance with a minimum refection loss (RLmin) value of - 50.36 dB and a maximum effective absorption bandwidth (EAB(max)) of 8.6 GHz. The successful preparation of this multifunctional aerogel material provides a promising prospect for the design and fabrication of the cutting-edge ceramic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 152, "DOI": "10.1007/s40820-022-00905-6", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00905-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000832688000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZY; Chen, FY; Lie, B; Yu, SW; Finfrock, YZ; Meira, DM; Yan, QQ; Zhu, P; Chen, MX; Song, TW; Yin, Z; Liang, HW; Zhang, S; Wang, G; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhen-Yu; Chen, Feng-Yang; Lie, Boyang; Yu, Shen-Wei; Finfrock, Y. Zou; Meira, Debora Motta; Yan, Qiang-Qiang; Zhu, Peng; Chen, Ming-Xi; Song, Tian-Wei; Yin, Zhouyang; Liang, Hai-Wei; Zhang, Sen; Wang, Guofeng; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-iridium-based electrocatalyst for durable acidic oxygen evolution reaction in proton exchange membrane water electrolysis", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iridium-based electrocatalysts remain the only practical anode catalysts for proton exchange membrane (PEM) water electrolysis, due to their excellent stability under acidic oxygen evolution reaction (OER), but are greatly limited by their high cost and low reserves. Here, we report a nickel-stabilized, ruthenium dioxide (Ni-RuO2) catalyst, a promising alternative to iridium, with high activity and durability in acidic OER for PEM water electrolysis. While pristine RuO2 showed poor acidic OER stability and degraded within a short period of continuous operation, the incorporation of Ni greatly stabilized the RuO2 lattice and extended its durability by more than one order of magnitude. When applied to the anode of a PEM water electrolyser, our Ni-RuO2 catalyst demonstrated >1,000 h stability under a water-splitting current of 200 mA cm(-2), suggesting potential for practical applications. Density functional theory studies, coupled with operando differential electrochemical mass spectroscopy analysis, confirmed the adsorbate-evolving mechanism on Ni-RuO2, as well as the critical role of Ni dopants in stabilization of surface Ru and subsurface oxygen for improved OER durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 494, "Times Cited, All Databases": 503, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 22, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 100, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01380-5", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01380-5", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870615900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZL; Zhu, YH; Asakura, H; Zhang, B; Zhang, JG; Zhou, MX; Han, Y; Tanaka, T; Wang, AQ; Zhang, T; Yan, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zailei; Zhu, Yihan; Asakura, Hiroyuki; Zhang, Bin; Zhang, Jiaguang; Zhou, Maoxiang; Han, Yu; Tanaka, Tsunehiro; Wang, Aiqin; Zhang, Tao; Yan, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally stable single atom Pt/m-Al2O3 for selective hydrogenation and CO oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom metal catalysts offer a promising way to utilize precious noble metal elements more effectively, provided that they are catalytically active and sufficiently stable. Herein, we report a synthetic strategy for Pt single-atom catalysts with outstanding stability in several reactions under demanding conditions. The Pt atoms are firmly anchored in the internal surface of mesoporous Al2O3, likely stabilized by coordinatively unsaturated pentahedral Al3+ centres. The catalyst keeps its structural integrity and excellent performance for the selective hydrogenation of 1,3-butadiene after exposure to a reductive atmosphere at 200 degrees C for 24 h. Compared to commercial Pt nulloparticle catalyst on Al2O3 and control samples, this system exhibits significantly enhanced stability and performance for n-hexane hydro-reforming at 550 degrees C for 48 h, although agglomeration of Pt single-atoms into clusters is observed after reaction. In CO oxidation, the Pt single-atom identity was fully maintained after 60 cycles between 100 and 400 degrees C over a one-month period.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 663, "Times Cited, All Databases": 697, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16100, "DOI": "10.1038/ncomms16100", "DOI Link": "http://dx.doi.org/10.1038/ncomms16100", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406360300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HP; Wu, HH; Ge, MY; Li, LJ; Yuan, YF; Yao, Q; Chen, J; Xia, LF; Zheng, JM; Chen, ZY; Duan, J; Kisslinger, K; Zeng, XC; Lee, WK; Zhang, QB; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Huiping; Wu, Hong-Hui; Ge, Mingyuan; Li, Lingjun; Yuan, Yifei; Yao, Qi; Chen, Jie; Xia, Lingfeng; Zheng, Jiangming; Chen, Zhaoyong; Duan, Junfei; Kisslinger, Kim; Zeng, Xiao Cheng; Lee, Wah-Keat; Zhang, Qiaobao; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A critical challenge in the commercialization of layer-structured Ni-rich materials is the fast capacity drop and voltage fading due to the interfacial instability and bulk structural degradation of the cathodes during battery operation. Herein, with the guidance of theoretical calculations of migration energy difference between La and Ti from the surface to the inside of LiNi0.8Co0.1Mn0.1O2, for the first time, Ti-doped and La4NiLiO8-coated LiNi0.8Co0.1Mn0.1O2 cathodes are rationally designed and prepared, via a simple and convenient dual-modification strategy of synchronous synthesis and in situ modification. Impressively, the dual modified materials show remarkably improved electrochemical performance and largely suppressed voltage fading, even under exertive operational conditions at elevated temperature and under extended cutoff voltage. Further studies reveal that the nulloscale structural degradation on material surfaces and the appearance of intergranular cracks associated with the inconsistent evolution of structural degradation at the particle level can be effectively suppressed by the synergetic effect of the conductive La4NiLiO8 coating layer and the strong TiO bond. The present work demonstrates that our strategy can simultaneously address the two issues with respect to interfacial instability and bulk structural degradation, and it represents a significant progress in the development of advanced cathode materials for high-performance lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 562, "Times Cited, All Databases": 587, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2019, "Volume": 29, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1808825, "DOI": "10.1002/adfm.201808825", "DOI Link": "http://dx.doi.org/10.1002/adfm.201808825", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463732400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, WJ; Zhu, JB; Wang, Z; Gao, YF; Xiao, D; Gu, Y; Zhang, ZY; Zhu, WG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Wenjun; Zhu, Jianbao; Wang, Zhe; Gao, Yanfei; Xiao, Di; Gu, Yi; Zhang, Zhenyu; Zhu, Wenguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interest in two-dimensional (2D) van der Waals materials has grown rapidly across multiple scientific and engineering disciplines in recent years. However, ferroelectricity, the presence of a spontaneous electric polarization, which is important in many practical applications, has rarely been reported in such materials so far. Here we employ first-principles calculations to discover a branch of the 2D materials family, based on In2Se3 and other III2-VI3 van der Waals materials, that exhibits room-temperature ferroelectricity with reversible spontaneous electric polarization in both out-of-plane and in-plane orientations. The device potential of these 2D ferroelectric materials is further demonstrated using the examples of van der Waals heterostructures of In2Se3/graphene, exhibiting a tunable Schottky barrier, and In2Se3/WSe2, showing a significant band gap reduction in the combined system. These findings promise to substantially broaden the tunability of van der Waals heterostructures for a wide range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1055, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14956, "DOI": "10.1038/ncomms14956", "DOI Link": "http://dx.doi.org/10.1038/ncomms14956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398455400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WG; Zhang, LL; Yan, WS; Liu, XY; Yang, XF; Miao, S; Wang, WT; Wang, AQ; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wengang; Zhang, Leilei; Yan, Wensheng; Liu, Xiaoyan; Yang, Xiaofeng; Miao, Shu; Wang, Wentao; Wang, Aiqin; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom dispersed Co-N-C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Co-N-C catalysts are promising candidates for substituting platinum in electrocatalysis and organic transformations. The heterogeneity of the Co species resulting from high-temperature pyrolysis, however, encumbers the structural identification of active sites. Herein, we report a self-supporting Co-N-C catalyst wherein cobalt is dispersed exclusively as single atoms. By using sub-Angstrom-resolution HAADF-STEM in combination with XAFS and DFT calculation, the exact structure of the Co-N-C is identified to be CoN4C8-1-2O(2), where the Co center atom is coordinated with four pyridinic N atoms in the graphitic layer, while two oxygen molecules are weakly adsorbed on Co atoms in perpendicular to the Co-N-4 plane. This single-atom dispersed Co-N-C catalyst presents excellent performance for the chemoselective hydrogenation of nitroarenes to produce azo compounds under mild reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 584, "Times Cited, All Databases": 613, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5758, "End Page": 5764, "Article Number": null, "DOI": "10.1039/c6sc02105k", "DOI Link": "http://dx.doi.org/10.1039/c6sc02105k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382488500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Armitage, NP; Mele, EJ; Vishwanath, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Armitage, N. P.; Mele, E. J.; Vishwanath, Ashvin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weyl and Dirac semimetals in three-dimensional solids", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl and Dirac semimetals are three-dimensional phases of matter with gapless electronic excitations that are protected by topology and symmetry. As three-dimensional analogs of graphene, they have generated much recent interest. Deep connections exist with particle physics models of relativistic chiral fermions, and, despite their gaplessness, to solid-state topological and Chern insulators. Their characteristic electronic properties lead to protected surface states and novel responses to applied electric and magnetic fields. The theoretical foundations of these phases, their proposed realizations in solid-state systems, and recent experiments on candidate materials as well as their relation to other states of matter are reviewed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3294, "Times Cited, All Databases": 3505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2018, "Volume": 90, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15001, "DOI": "10.1103/RevModPhys.90.015001", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.015001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423135000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YF; Hu, AG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Youfu; Hu, Aiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon quantum dots: synthesis, properties and applications", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon quantum dots (CQDs, C-dots or CDs), which are generally small carbon nulloparticles (less than 10 nm in size) with various unique properties, have found wide use in more and more fields during the last few years. In this feature article, we describe the recent progress in the field of CQDs, focusing on their synthetic methods, size control, modification strategies, photoelectric properties, luminescent mechanism, and applications in biomedicine, optronics, catalysis and sensor issues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1876, "Times Cited, All Databases": 1986, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6921, "End Page": 6939, "Article Number": null, "DOI": "10.1039/c4tc00988f", "DOI Link": "http://dx.doi.org/10.1039/c4tc00988f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340587100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, Y; Han, JC; Zhang, YM; Zhang, XH; Xu, P; Yuan, Q; Samad, L; Wang, XJ; Wang, Y; Zhang, ZH; Zhang, P; Cao, XZ; Song, B; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Ying; Han, Jiecai; Zhang, Yumin; Zhang, Xinghong; Xu, Ping; Yuan, Quan; Samad, Leith; Wang, Xianjie; Wang, Yi; Zhang, Zhihua; Zhang, Peng; Cao, Xingzhong; Song, Bo; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contributions of Phase, Sulfur Vacancies, and Edges to the Hydrogen Evolution Reaction Catalytic Activity of Porous Molybdenum Disulfide nullosheets", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum disulfide (MoS2) is a promising nonprecious catalyst for the hydrogen evolution reaction (HER) that has been extensively studied due to its excellent performance, but the lack of understanding of the factors that impact its catalytic activity hinders further design and enhancement of MoS2-based electrocatalysts. Here, by using novel porous (holey) metallic 1T phase MoS2 nullosheets synthesized by a liquid-ammonia-assisted lithiation route, we systematically investigated the contributions of crystal structure (phase), edges, and sulfur vacancies (S-vacancies) to the catalytic activity toward HER from five representative MoS2 nullosheet samples, including 2H and IT phase, porous 2H and IT phase, and sulfur-compensated porous 2H phase. Superior HER catalytic activity was achieved in the porous IT phase MoS2 nullosheets that have even more edges and S-vacancies than conventional 1T phase MoS2. A comparative study revealed that the phase serves as the key role in determining the HER performance, as IT phase MoS2 always outperforms the corresponding 2H phase MoS2 samples, and that both edges and S-vacancies also contribute significantly to the catalytic activity in porous MoS2 samples. Then, using combined defect characterization techniques of electron spin resonullce spectroscopy and positron annihilation lifetime spectroscopy to quantify the S-vacancies, the contributions of each factor were individually elucidated. This study presents new insights and opens up new avenues for designing electrocatalysts based on MoS2 or other layered materials with enhanced HER performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1095, "Times Cited, All Databases": 1163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2016, "Volume": 138, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7965, "End Page": 7972, "Article Number": null, "DOI": "10.1021/jacs.6b03714", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b03714", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378984300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, B; Shi, AM; Wang, Q; Binks, BP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Bo; Shi, Aimin; Wang, Qiang; Binks, Bernard P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Internal-Phase Pickering Emulsions Stabilized Solely by Peanut-Protein-Isolate Microgel Particles with Multiple Potential Applications", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-internal-phase Pickering emulsions have various applications in materials science. However, the biocompatibility and biodegradability of inorganic or synthetic stabilizers limit their applications. Herein, we describe high-internal-phase Pickering emulsions with 87% edible oil or 88% n-hexane in water stabilized by peanut-protein-isolate microgel particles. These dispersed phase fractions are the highest in all known food-grade Pickering emulsions. The protein-based microgel particles are in different aggregate states depending on the pHvalue. The emulsions can be utilized for multiple potential applications simply by changing the internal-phase composition. A substitute for partially hydrogenated vegetable oils is obtained when the internal phase is an edible oil. If the internal phase is n-hexane, the emulsion can be used as a template to produce porous materials, which are advantageous for tissue engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2018, "Volume": 57, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9274, "End Page": 9278, "Article Number": null, "DOI": "10.1002/anie.201801350", "DOI Link": "http://dx.doi.org/10.1002/anie.201801350", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438712600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZQ; Liao, T; Dou, YH; Hwang, SM; Park, MS; Jiang, L; Kim, JH; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Ziqi; Liao, Ting; Dou, Yuhai; Hwang, Soo Min; Park, Min-Sik; Jiang, Lei; Kim, Jung Ho; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generalized self-assembly of scalable two-dimensional transition metal oxide nullosheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal oxide systems present exotic electronic properties and high specific surface areas, and also demonstrate promising applications ranging from electronics to energy storage. Yet, in contrast to other types of nullostructures, the question as to whether we could assemble 2D nullomaterials with an atomic thickness from molecules in a general way, which may give them some interesting properties such as those of graphene, still remains unresolved. Herein, we report a generalized and fundamental approach to molecular self-assembly synthesis of ultrathin 2D nullosheets of transition metal oxides by rationally employing lamellar reverse micelles. It is worth emphasizing that the synthesized crystallized ultrathin transition metal oxide nullosheets possess confined thickness, high specific surface area and chemically reactive facets, so that they could have promising applications in nullostructured electronics, photonics, sensors, and energy conversion and storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 731, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3813, "DOI": "10.1038/ncomms4813", "DOI Link": "http://dx.doi.org/10.1038/ncomms4813", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337372200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, J; Liu, ZW; Wu, XH; Li, GY; Fang, D; Zhang, XT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Jing; Liu, Zengwei; Wu, Xiaohan; Li, Guangyong; Fang, Dan; Zhang, Xuetong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullofibrous Kevlar Aerogel Films and Their Phase-Change Composites for Highly Efficient Infrared Stealth", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Infrared (IR) stealth is essential not only in high technology and modern military but also in fundamental material science. However, effectively hiding targets and rendering them invisible to thermal infrared detectors have been great challenges in past decades. Herein, flexible, foldable, and robust Kevlar nullofiber aerogel (KNA) films with high porosity and specific surface area were fabricated first. The KNA films display excellent thermal insulation performance and can be employed to incorporate with phase-change materials (PCMs), such as polyethylene glycol, to fabricate KNA/PCM composite films. The KNA/PCM films with high thermal management capability and infrared emissivity comparable to that of various backgrounds demonstrate high performance in IR stealth in outdoor environments with solar illumination variations. To further realize hiding hot targets from IR detection, combined structures constituted of thermal insulation layers (KNA films) and ultralow IR transmittance layers (KNA/PCM) are proposed. A hot target covered with this combined structure becomes completely invisible in infrared images. Such KNA/PCM films and KNA-KNA/PCM combined structures hold great promise for broad applications in infrared thermal stealth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2236, "End Page": 2245, "Article Number": null, "DOI": "10.1021/acsnullo.8b08913", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b08913", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460199400121", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, Z; Bei, H; Pharr, GM; George, EP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Z.; Bei, H.; Pharr, G. M.; George, E. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compared to decades-old theories of strengthening in dilute solid solutions, the mechanical behavior of concentrated solid solutions is relatively poorly understood. A special subset of these materials includes alloys in which the constituent elements are present in equal atomic proportions, including the high-entropy alloys of recent interest. A unique characteristic of equiatomic alloys is the absence of solvent and solute atoms, resulting in a breakdown of the textbook picture of dislocations moving through a solvent lattice and encountering discrete solute obstacles. To clarify the mechanical behavior of this interesting new class of materials, we investigate here a family of equiatomic binary, ternary and quaternary alloys based on the elements Fe, Ni, Co, Cr and Mn that were previously shown to be single-phase face-centered cubic (fcc) solid solutions. The alloys were arc-melted, drop-cast, homogenized, cold-rolled and recrystallized to produce equiaxed microstructures with comparable grain sizes. Tensile tests were performed at an engineering strain rate of 10(-3) s(-1) at temperatures in the range 77-673 K. Unalloyed fcc Ni was processed similarly and tested for comparison. The flow stresses depend to varying degrees on temperature, with some (e.g. NiCoCr, NiCoCrMn and FeNiCoCr) exhibiting yield and ultimate strengths that increase strongly with decreasing temperature, while others (e.g. NiCo and Ni) exhibit very weak temperature dependencies. To better understand this behavior, the temperature dependencies of the yield strength and strain hardening were analyzed separately. Lattice friction appears to be the predominullt component of the temperature-dependent yield stress, possibly because the Peierls barrier height decreases with increasing temperature due to a thermally induced increase of dislocation width. In the early stages of plastic flow (5-13% strain, depending on material), the temperature dependence of strain hardening is due mainly to the temperature dependence of the shear modulus. In all the equiatomic alloys, ductility and strength increase with decreasing temperature down to 77 K. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1592, "Times Cited, All Databases": 1659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 428, "End Page": 441, "Article Number": null, "DOI": "10.1016/j.actamat.2014.08.026", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2014.08.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345179800041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HW; Ross, MB; Kornienko, N; Zhang, L; Guo, JH; Yang, PD; McCloskey, BD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyo Won; Ross, Michael B.; Kornienko, Nikolay; Zhang, Liang; Guo, Jinghua; Yang, Peidong; McCloskey, Bryan D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical oxygen reduction has garnered attention as an emerging alternative to the traditional anthraquinone oxidation process to enable the distributed production of hydrogen peroxide. Here, we demonstrate a selective and efficient non-precious electrocatalyst, prepared through an easily scalable mild thermal reduction of graphene oxide, to form hydrogen peroxide from oxygen. During oxygen reduction, certain variants of the mildly reduced graphene oxide electrocatalyst exhibit highly selective and stable peroxide formation activity at low overpotentials (<10 mV) under basic conditions, exceeding the performance of current state-of-the-art alkaline catalysts. Spectroscopic structural characterization and in situ Raman spectroelectrochemistry provide strong evidence that sp(2)-hybridized carbon near-ring ether defects along sheet edges are the most active sites for peroxide production, providing new insight into the electrocatalytic design of carbon-based materials for effective peroxide production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 816, "Times Cited, All Databases": 870, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 282, "End Page": 290, "Article Number": null, "DOI": "10.1038/s41929-018-0044-2", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0044-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430451900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, YF; Wang, Q; Lu, J; Liu, CT; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Y. F.; Wang, Q.; Lu, J.; Liu, C. T.; Yang, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy alloy: challenges and prospects", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) are presently of great research interest in materials science and engineering. Unlike conventional alloys, which contain one and rarely two base elements, HEAs comprise multiple principal elements, with the possible number of HEA compositions extending considerably more than conventional alloys. With the advent of HEAs, fundamental issues that challenge the proposed theories, models, and methods for conventional alloys also emerge. Here, we provide a critical review of the recent studies aiming to address the fundamental issues related to phase formation in HEAs. In addition, novel properties of HEAs are also discussed, such as their excellent specific strength, superior mechanical performance at high temperatures, exceptional ductility and fracture toughness at cryogenic temperatures, superparamagnetism, and superconductivity. Due to their considerable structural and functional potential as well as richness of design, HEAs are promising candidates for new applications, which warrants further studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2039, "Times Cited, All Databases": 2176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2016, "Volume": 19, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 349, "End Page": 362, "Article Number": null, "DOI": "10.1016/j.mattod.2015.11.026", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.11.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380759200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, H; Zhang, CZ; Liu, F; Hou, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Han; Zhang, Chenzhen; Liu, Fei; Hou, Yanglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid of Iron Nitride and Nitrogen-Doped Graphene Aerogel as Synergistic Catalyst for Oxygen Reduction Reaction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is extremely desirable but challenging to create highly active, stable, and low-cost catalysts towards oxygen reduction reaction to replace Pt-based catalysts in order to perform the commercialization of fuel cells. Here, a novel iron nitride/nitrogen doped-graphene aerogel hybrid, synthesized by a facile two-step hydrothermal process, in which iron phthalocyanine is uniformly dispersed and anchored on graphene surface with the assist of - stacking and oxygen-containing functional groups, is reported. As a result, there exist strong interactions between Fe x N nulloparticles and graphene substrates, leading to a synergistic effect towards oxygen reduction reaction. It is worth noting that the onset potential and current density of the hybrid are significantly better and the charge transfer resistance is much lower than that of pure nitrogen-doped graphene aerogel, free Fe x N and their physical mixtures. The hybrid also exhibits comparable catalytic activity as commercial Pt/C at the same catalyst loading, while its stability and resistance to methanol crossover are superior. Interestingly, it is found that, apart from the active nature of the hybrid, the large surface area and porosity are responsible for its excellent onset potential and the high density of Fe-N-C sties and small size of Fe x N particles boost charge transfer rate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 24, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2930, "End Page": 2937, "Article Number": null, "DOI": "10.1002/adfm.201303902", "DOI Link": "http://dx.doi.org/10.1002/adfm.201303902", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337487300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZW; Chen, P; Duan, XD; Zang, KT; Luo, J; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhengwei; Chen, Peng; Duan, Xidong; Zang, Ketao; Luo, Jun; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust epitaxial growth of two-dimensional heterostructures, multiheterostructures, and superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a general synthetic strategy for highly robust growth of diverse lateral heterostructures, multiheterostructures, and superlattices from two-dimensional (2D) atomic crystals. A reverse flow during the temperature-swing stage in the sequential vapor deposition growth process allowed us to cool the existing 2D crystals to prevent undesired thermal degradation and uncontrolled homogeneous nucleation, thus enabling highly robust block-by-block epitaxial growth. Raman and photoluminescence mapping studies showed that a wide range of 2D heterostructures (such as WS2-WSe2 and WS2-MoSe2), multiheterostructures (such as WS2-WSe2-MoS2 and WS2-MoSe2-WSe2), and superlattices (such as WS2-WSe2-WS2-WSe2-WS2) were readily prepared with precisely controlled spatial modulation. Transmission electron microscope studies showed clear chemical modulation with atomically sharp interfaces. Electrical transport studies of WSe2-WS2 lateral junctions showed well-defined diode characteristics with a rectification ratio up to 10(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 570, "Times Cited, All Databases": 601, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2017, "Volume": 357, "Issue": 6353, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 788, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aan6814", "DOI Link": "http://dx.doi.org/10.1126/science.aan6814", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408327900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huynh, TP; Sonar, P; Haick, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huynh, Tan-Phat; Sonar, Prashant; Haick, Hossam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced Materials for Use in Soft Self-Healing Devices", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Devices integrated with self-healing ability can benefit from long-term use as well as enhanced reliability, maintenullce and durability. This progress report reviews the developments in the field of self-healing polymers/composites and wearable devices thereof. One part of the progress report presents and discusses several aspects of the self-healing materials chemistry (from non-covalent to reversible covalent-based mechanisms), as well as the required main approaches used for functionalizing the composites to enhance their electrical conductivity, magnetic, dielectric, electroactive and/or photoactive properties. The second and complementary part of the progress report links the self-healing materials with partially or fully self-healing device technologies, including wearable sensors, supercapacitors, solar cells and fabrics. Some of the strong and weak points in the development of each self-healing device are clearly highlighted and criticized, respectively. Several ideas regarding further improvement of soft self-healing devices are proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 29, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604973, "DOI": "10.1002/adma.201604973", "DOI Link": "http://dx.doi.org/10.1002/adma.201604973", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401170600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, CM; Wei, T; Zhang, YY; Song, XH; Huan, Y; Liu, H; Zhao, MW; Yu, JH; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Chaomin; Wei, Tao; Zhang, Yanyan; Song, Xiaohan; Huan, Yu; Liu, Hong; Zhao, Mingwen; Yu, Jinghua; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Photoresponsive Rutile TiO2 Heterojunction with Enhanced Electron-Hole Separation for High-Performance Hydrogen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rutile titanium dioxide (TiO2) is a promising photocatalyst due to its high thermodynamic stability and few intragrain defects. However, it has not yet achieved photocatalytic activity comparable to that of anatase TiO2 owing to its higher recombination rate of electron-hole pairs. To effectively separate the electron-hole pairs in rutile TiO2, a facet heterojunction (FH) structure to prolong the lifetime of the photogenerated electrons is proposed. Ultrathin TiO2 nullosheets with different facets are coated in situ onto TiO2 nullorod (NR) substrates, where FHs are built among the nullosheets as well as between the nullosheets and NR substrates. The as-prepared rutile TiO2, with an FH structure (FH-TiO2), serves as an effective photocatalyst for water splitting. More than 45 and 18 times higher photogenerated current density and H-2 production rate, respectively, are obtained compared to those of pure rutile TiO2 NRs. Moreover, FH-TiO2 delivers a 0.566 mmol g(-1) h(-1) H-2 production rate even in pure water. This study offers important insights into the rational design of rutile TiO2 structures for highly efficient photocatalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 31, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806596, "DOI": "10.1002/adma.201806596", "DOI Link": "http://dx.doi.org/10.1002/adma.201806596", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459798700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SL; Guan, BY; Lu, XF; Xi, SB; Du, YH; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Song Lin; Guan, Bu Yuan; Lu, Xue Feng; Xi, Shibo; Du, Yonghua; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal Atom-Doped Co3O4Hierarchical nulloplates for Electrocatalytic Oxygen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysts based on hierarchically structured and heteroatom-doped non-noble metal oxide materials are of great importance for efficient and low-cost electrochemical water splitting systems. Herein, the synthesis of a series of hierarchical hollow nulloplates (NPs) composed of ultrathin Co(3)O(4)nullosheets doped with 13 different metal atoms is reported. The synthesis involves a cooperative etching-coordination-reorganization approach starting from zeolitic imidazolate framework-67 (ZIF-67) NPs. First, metal atom decorated ZIF-67 NPs with unique cross-channels are formed through a Lewis acid etching and metal species coordination process. Afterward, the composite NPs are converted to hollow Co(3)O(4)hierarchical NPs composed of ultrathin nullosheets through a solvothermal reaction, during which the guest metal species is doped into the octahedral sites of Co3O4. Density functional theory calculations suggest that doping of small amount of Fe atoms near the surface of Co(3)O(4)can greatly enhance the electrocatalytic activity toward the oxygen evolution reaction (OER). Benefiting from the structural and compositional advantages, the obtained Fe-doped Co(3)O(4)hierarchical NPs manifest superior electrocatalytic performance for OER with an overpotential of 262 mV at 10 mA cm(-2), a Tafel slope of 43 mV dec(-1), and excellent stability even at a high current density of 100 mA cm(-2)for 50 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 32, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002235, "DOI": "10.1002/adma.202002235", "DOI Link": "http://dx.doi.org/10.1002/adma.202002235", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543132200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, Q; Chen, Z; Cheng, JX; Zhang, B; Zhang, YF; Li, HG; He, XN; Yuan, C; Liu, J; Magdassi, S; Qu, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Qi; Chen, Zhe; Cheng, Jianxiang; Zhang, Biao; Zhang, Yuan-Fang; Li, Honggeng; He, Xiangnull; Yuan, Chao; Liu, Ji; Magdassi, Shlomo; Qu, Shaoxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of highly stretchable hydrogel with diverse UV curable polymers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogel-polymer hybrids have been widely used for various applications such as biomedical devices and flexible electronics. However, the current technologies constrain the geometries of hydrogel-polymer hybrid to laminates consisting of hydrogel with silicone rubbers. This greatly limits functionality and performance of hydrogel-polymer-based devices and machines. Here, we report a simple yet versatile multimaterial 3D printing approach to fabricate complex hybrid 3D structures consisting of highly stretchable and high-water content acrylamide-PEGDA (AP) hydrogels covalently bonded with diverse UV curable polymers. The hybrid structures are printed on a self-built DLP-based multimaterial 3D printer. We realize covalent bonding between AP hydrogel and other polymers through incomplete polymerization of AP hydrogel initiated by the water-soluble photoinitiator TPO nulloparticles. We demonstrate a few applications taking advantage of this approach. The proposed approach paves a new way to realize multifunctional soft devices and machines by bonding hydrogel with other polymers in 3D forms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba4261", "DOI": "10.1126/sciadv.aba4261", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba4261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000606331400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kozen, AC; Lin, CF; Pearse, AJ; Schroeder, MA; Han, XG; Hu, LB; Lee, SB; Rubloff, GW; Noked, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.; Schroeder, Marshall A.; Han, Xiaogang; Hu, Liangbing; Lee, Sang-Bok; Rubloff, Gary W.; Noked, Malachi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is considered to be the most promising anode for next-generation batteries due to its high energy density of 3840 mAh g(-1). However, the extreme reactivity of the Li surface can induce parasitic reactions with solvents, contamination, and shuttled active species in the electrolyte, reducing the performance of batteries employing Li metal anodes. One promising solution to this issue is application of thin chemical protection layers to the Li metal surface. Using a custom-made ultrahigh vacuum integrated deposition and characterization system, we demonstrate atomic layer deposition (ALD) of protection layers directly on Li metal with exquisite thickness control. We demonstrate as a proof-of-concept that a 14 nm thick ALD Al2O3 layer can protect the Li surface from corrosion due to atmosphere, sulfur, and electrolyte exposure. Using Li-S battery cells as a test system, we demonstrate an improved capacity retention using ALD-protected anodes over cells assembled with bare Li metal anodes for up to 100 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 700, "Times Cited, All Databases": 784, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5884, "End Page": 5892, "Article Number": null, "DOI": "10.1021/acsnullo.5b02166", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b02166", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356988500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, YX; Shen, YK; Tian, L; Hu, YG; Zhu, PL; Sun, R; Wong, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Yaoxu; Shen, Youkang; Tian, Lan; Hu, Yougen; Zhu, Pengli; Sun, Rong; Wong, Ching-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A flexible, ultra-highly sensitive and stable capacitive pressure sensor with convex microarrays for motion and health monitoring", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, flexible sensors endowed with high sensitivity, low detection limit, broad working pressure range and fast response have aroused widespread concern owing to their vital role in the development of wearable artificial devices, human-machine interaction and healthcare systems. Herein, flexible and highly sensitive capacitive pressure sensors were fabricated based on flexible electrodes with convex microarrays and ultrathin dielectric layer. The proposed sensor is constructed by sandwiching a top micro-arrayed electrode, a middle ultrathin dielectric layer and a bottom micro-arrayed electrode, and it demonstrates an ultra-high sensitivity of 30.2 kPa(-1) (0-130 Pa), fast response time of 25 ms, low detection limit of 0.7 Pa and extreme stability of 100 000 cycles without fatigue. The finite-element analysis indicates that the changes of contact area and distance between two electrodes under external stimulus are critical to achieve superior properties of the sensor. Benefitting from the outstanding comprehensive performance, the enormous potential ability of the capacitive sensor in monitoring physiological signals and robot hand grabbing motions have been successfully demonstrated, which indicates promising applications in wearable intelligent electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 433, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 70, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104436, "DOI": "10.1016/j.nulloen.2019.104436", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2019.104436", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521052900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TX; Liao, YC; Lin, CC; Su, YH; Ting, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thi Xuyen Nguyen; Liao, Yi-Cheng; Lin, Chia-Chun; Su, Yen-Hsun; Ting, Jyh-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced High Entropy Perovskite Oxide Electrocatalyst for Oxygen Evolution Reaction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new type of lanthanum-based high entropy perovskite oxide (HEPO) electrocatalyst for the oxygen evolution reaction is reported. The B-site lattices in the HEPO consist of five consecutive first-row transition metals, including Cr, Mn, Fe, Co, and Ni. Equimolar and five non-equimolar HEPO electrocatalysts are studied for their OER electrocatalytic performance. In the five non-equimolar HEPOs, the concentration of one of the five transition metals is doubled in individual samples. The performances of all the HEPOs outperform the single perovskite oxides. The optimized La(CrMnFeCo2Ni)O-3 HEPO exhibits an outstanding OER overpotential of 325 mV at a current density of 10 mA cm(-2) and excellent electrochemical stability after 50 h of testing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 31, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101632, "DOI": "10.1002/adfm.202101632", "DOI Link": "http://dx.doi.org/10.1002/adfm.202101632", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000646958100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, CG; Yu, JC; Chen, YL; Hu, QY; Xiao, XZ; Sun, WJ; Wang, C; Feng, PJ; Shen, QD; Gu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Chenggen; Yu, Jicheng; Chen, Yulei; Hu, Quanyin; Xiao, Xuanzhong; Sun, Wujin; Wang, Chao; Feng, Peijian; Shen, Qun-Dong; Gu, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-Activated Hypoxia-Responsive nullocarriers for Enhanced Anticancer Therapy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A light-activated hypoxia-responsive conjugated polymer-based nullocarrier is developed for efficiently producing singlet oxygen (O-1(2)) and inducing hypoxia to promote release of its cargoes in tumor cells, leading to enhanced antitumor efficacy. This dual-responsive nullocarrier provides an innovative design guideline for enhancing traditional photodynamic therapeutic efficacy integrated with a controlled drug-release modality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2016, "Volume": 28, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3313, "End Page": 3320, "Article Number": null, "DOI": "10.1002/adma.201505869", "DOI Link": "http://dx.doi.org/10.1002/adma.201505869", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375059200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halim, J; Cook, KM; Naguib, M; Eklund, P; Gogotsi, Y; Rosen, J; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halim, Joseph; Cook, Kevin M.; Naguib, Michael; Eklund, Per; Gogotsi, Yury; Rosen, Johanna; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)", "Source Title": "APPLIED SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a detailed high resolution X-ray photoelectron spectroscopy (XPS) analysis is presented for select MXenes a recently discovered family of two-dimensional (2D) carbides and carbonitrides. Given their 2D nature, understanding their surface chemistry is paramount. Herein we identify and quantify the surface groups present before, and after, sputter-cleaning as well as freshly prepared vs. aged multi layered cold pressed discs. The nominal compositions of the MXenes studied here are Ti-3 C2Tx,Ti3CNTx, Nb2CTx and Nb4C3Tx where T represents surface groups that this work attempts to quantify. In all the cases, the presence of three surface terminations, O, OH and F, in addition to OH-terminations relatively strongly bonded to H2O molecules, was confirmed. From XPS peak fits, it was possible to establish the average sum of the negative charges of the terminations for the aforementioned MXenes. Based on this work, it is now possible to quantify the nature of the surface terminations. This information can, in turn, be used to better design and tailor these novel 2D materials for various applications. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1559, "Times Cited, All Databases": 1628, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2016, "Volume": 362, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": 417, "Article Number": null, "DOI": "10.1016/j.apsusc.2015.11.089", "DOI Link": "http://dx.doi.org/10.1016/j.apsusc.2015.11.089", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368657900056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YT; Liang, YP; Chen, JY; Duan, XL; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yutong; Liang, Yongping; Chen, Jueying; Duan, Xianglong; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mussel-inspired adhesive antioxidant antibacterial hemostatic composite hydrogel wound dressing via photo-polymerization for infected skin wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the increasing prevalence of drug-resistant bacterial infections and the slow healing of chronically infected wounds, the development of new antibacterial and accelerated wound healing dressings has become a serious challenge. In order to solve this problem, we developed photo-crosslinked multifunctional antibacterial adhesive anti-oxidant hemostatic hydrogel dressings based on polyethylene glycol monomethyl ether modified glycidyl methacrylate functionalized chitosan (CSG-PEG), methacrylamide dopamine (DMA) and zinc ion for disinfection of drug-resistant bacteria and promoting wound healing. The mechanical properties, rheological properties and morphology of hydrogels were characterized, and the biocompatibility of these hydrogels was studied through cell compatibility and blood compatibility tests. These hydrogels were tested for the in vitro blood-clotting ability of whole blood and showed good hemostatic ability in the mouse liver hemorrhage model and the mouse-tail amputation model. In addition, it has been confirmed that the multifunctional hydrogels have good inherent antibacterial properties against Methicillin-resistant Staphylococcus aureus (MRSA). In the full-thickness skin defect model infected with MRSA, the wound closure ratio, thickness of granulation tissue, number of collagen deposition, regeneration of blood vessels and hair follicles were measured. The inflammation-related cytokines (CD68) and angiogenesis-related cytokines (CD31) expressed during skin regeneration were studied. All results indicate that these multifunctional antibacterial adhesive hemostatic hydrogels have better healing effects than commercially available Tegaderm (TM) Film, revealing that they have become promising alternative in the healing of infected wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 341, "End Page": 354, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.06.014", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.06.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751867500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Zhao, SY; Li, HB; He, S; Veder, JP; Johannessen, B; Xiao, JP; Lu, SF; Pan, J; Chisholm, MF; Yang, SZ; Liu, C; Chen, JG; Jiang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yi; Zhao, Shiyong; Li, Haobo; He, Shuai; Veder, Jean-Pierre; Johannessen, Bernt; Xiao, Jianping; Lu, Shanfu; Pan, Jian; Chisholm, Mattew F.; Yang, Shi-Ze; Liu, Chang; Chen, Jingguang G.; Jiang, San Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supported single atom catalysts (SACs), emerging as a new class of catalytic materials, have been attracting increasing interests. Here we developed a Ni SAC on microwave exfoliated graphene oxide (Ni-N-MEGO) to achieve single atom loading of similar to 6.9 wt%, significantly higher than previously reported SACs. The atomically dispersed Ni atoms, stabilized by coordination with nitrogen, were found to be predominulltly anchored along the edges of nullopores (< 6 nm) using a combination of X-ray absorption spectroscopy (XAS) and aberration corrected scanning transmission electron microscopy (AC-STEM). The Ni-N-MEGO exhibits an onset over potential of 0.18 V, and a current density of 53.6 mA mg(-1) at overpotential of 0.59 V for CO2 reduction reaction (CO2RR), representing one of the best non-precious metal SACs reported so far in the literature. Density functional theory (DFT) calculations suggest that the electrochemical CO2-to-CO conversion occurs more readily on the edge-anchored unsaturated nitrogen coordinated Ni single atoms that lead to enhanced activity toward CO2RR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 243, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 294, "End Page": 303, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.10.046", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.10.046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453616800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XY; Zhao, F; Guo, YH; Rosenberger, B; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xingyi; Zhao, Fei; Guo, Youhong; Rosenberger, Brian; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Architecting highly hydratable polymer networks to tune the water state for solar water purification", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water purification by solar distillation is a promising technology to produce fresh water. However, solar vapor generation, is energy intensive, leading to a low water yield under natural sunlight. Therefore, developing new materials that can reduce the energy requirement of water vaporization and speed up solar water purification is highly desirable. Here, we introduce a highly hydratable light-absorbing hydrogel (h-LAH) consisting of polyvinyl alcohol and chitosan as the hydratable skeleton and polypyrrole as the light absorber, which can use less energy (<50% of bulk water) for water evaporation. We demonstrate that enhancing the hydrability of the h-LAH could change the water state and partially activate the water, hence facilitating water evaporation. The h-LAH raises the solar vapor generation to a record rate of similar to 3.6 kg m(-2) hour(-1) under 1 sun. The h-LAH-based solar still also exhibits long-termdurability and antifouling functionality toward complex ionic contaminullts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 772, "Times Cited, All Databases": 805, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw5484", "DOI": "10.1126/sciadv.aaw5484", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw5484", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473798500083", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, BR; Wang, SR; Lin, M; Jin, Y; Zhang, SJ; Cui, XY; Gong, Y; Li, A; Xu, F; Lu, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Birui; Wang, Shurui; Lin, Min; Jin, Ying; Zhang, Shujing; Cui, Xingye; Gong, Yan; Li, Ang; Xu, Feng; Lu, Tian Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upconversion nulloparticles based FRET aptasensor for rapid and ultrasenstive bacteria detection", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pathogenic bacteria cause serious harm to human health, which calls for the development of advanced detection methods. Herein, we developed a novel detection platform based on fluorescence resonullce energy transfer (FRET) for rapid, ultrasensitive and specific bacteria detection, where gold nulloparticles (AuNPs, acceptor) were conjugated with aptamers while upconversion nulloparticles (UCNPs, donor) were functionalized with corresponding complementary DNA (cDNA). The spectral overlap between UCNPs fluorescence emission and AuNPs absorption enables the occurrence of FRET when hybridizing the targeted aptamer and cDNA, causing upconversion fluorescence quenching. In the presence of target bacteria, the aptamers preferentially bind to bacteria forming a three-dimensional structure and thereby dissociate UCNPs-cDNA from AuNPs-aptamers, resulting in the recovery of upconversion fluorescence. Using the UCNPs based FRET aptasensor, we successfully detected Escherichia coli ATCC 8739 (as a model analyte) with a detection range of 5-10(6) du/mL and detection limit of 3 cfu/mL. The aptasensor was further used to detect E. coli in real food and water samples (e.g., tap/pond water, milk) within 20 min. The novel UCNPs based FRET aptasensor could be used to detect a broad range of targets from whole cells to metal ions by using different aptamer sequences, holding great potential in environmental monitoring, medical diagnostics and food safety analysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2017, "Volume": 90, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 525, "End Page": 533, "Article Number": null, "DOI": "10.1016/j.bios.2016.10.029", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2016.10.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392768000068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saidaminov, MI; Abdelhady, AL; Murali, B; Alarousu, E; Burlakov, VM; Peng, W; Dursun, I; Wang, LF; He, Y; Maculan, G; Goriely, A; Wu, T; Mohammed, OF; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saidaminov, Makhsud I.; Abdelhady, Ahmed L.; Murali, Banavoth; Alarousu, Erkki; Burlakov, Victor M.; Peng, Wei; Dursun, Ibrahim; Wang, Lingfei; He, Yao; Maculan, Giacomo; Goriely, Alain; Wu, Tom; Mohammed, Omar F.; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals of methylammonium lead trihalide perovskites (MAPbX(3); MA = CH3NH3+, X = Br- or I-) have shown remarkably low trap density and charge transport properties; however, growth of such high-quality semiconductors is a time-consuming process. Here we present a rapid crystal growth process to obtain MAPbX(3) single crystals, an order of magnitude faster than previous reports. The process is based on our observation of the substantial decrease of MAPbX(3) solubility, in certain solvents, at elevated temperatures. The crystals can be both size- and shape-controlled by manipulating the different crystallization parameters. Despite the rapidity of the method, the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPbX(3) reported to date. The phenomenon of inverse or retrograde solubility and its correlated inverse temperature crystallization strategy present a major step forward for advancing the field on perovskite crystallization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1605, "Times Cited, All Databases": 1720, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7586, "DOI": "10.1038/ncomms8586", "DOI Link": "http://dx.doi.org/10.1038/ncomms8586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358855800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, YZ; Zhu, YZ; Liu, C; Lee, KR; Hung, WS; Wang, ZY; Li, YY; Elimelech, M; Jin, J; Lin, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Yuanzhe; Zhu, Yuzhang; Liu, Cheng; Lee, Kueir-Rarn; Hung, Wei-Song; Wang, Zhenyi; Li, Youyong; Elimelech, Menachem; Jin, Jian; Lin, Shihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyamide nullofiltration membrane with highly uniform sub-nullometre pores for sub-1Å precision separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Separating molecules or ions with sub-Angstrom scale precision is important but technically challenging. Achieving such a precise separation using membranes requires Angstrom scale pores with a high level of pore size uniformity. Herein, we demonstrate that precise solute-solute separation can be achieved using polyamide membranes formed via surfactant-assembly regulated interfacial polymerization (SARIP). The dynamic, self-assembled network of surfactants facilitates faster and more homogeneous diffusion of amine monomers across the water/hexane interface during interfacial polymerization, thereby forming a polyamide active layer with more uniform sub-nullometre pores compared to those formed via conventional interfacial polymerization. The polyamide membrane formed by SARIP exhibits highly size-dependent sieving of solutes, yielding a step-wise transition from low rejection to near-perfect rejection over a solute size range smaller than half Angstrom. SARIP represents an approach for the scalable fabrication of ultra-selective membranes with uniform nullopores for precise separation of ions and small solutes. Separating molecules or ions with sub-Angstrom scale precision is important but technically challenging. Here, the authors demonstrate that precise solute-solute separation can be achieved using polyamide membranes formed via surfactant-assembly regulated interfacial polymerization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 461, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2015, "DOI": "10.1038/s41467-020-15771-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15771-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558822900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, ZJ; Yin, TY; Jiang, JB; He, Y; Xiang, T; Zhou, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Zijian; Yin, Tianyu; Jiang, Jinbo; He, Yang; Xiang, Tao; Zhou, Shaobing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wound microenvironment self-adaptive hydrogel with efficient angiogenesis for promoting diabetic wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neovascularization is critical to improve the diabetic microenvironment, deliver abundant nutrients to the wound and promote wound closure. However, the excess of oxidative stress impedes the healing process. Herein, a self-adaptive multifunctional hydrogel with self-healing property and injectability is fabricated through a boronic ester-based reaction between the phenylboronic acid groups of the 3-carboxyl-4-fluorophenylboronic acid -grafted quaternized chitosan and the hydroxyl groups of the polyvinyl alcohol, in which pro-angiogenic drug of desferrioxamine (DFO) is loaded in the form of gelatin microspheres (DFO@G). The boronic ester bonds of the hydrogel can self-adaptively react with hyperglycemic and hydrogen peroxide to alleviate oxidative stress and release DFO@G in the early phase of wound healing. A sustained release of DFO is then realized by responding to overexpressed matrix metalloproteinases. In a full-thickness diabetic wound model, the DFO@G loaded hydrogel accelerates angiogenesis by upregulating expression of hypoxia-inducible factor-1 and angiogenic growth factors, resulting in collagen deposition and rapid wound closure. This multifunctional hydrogel can not only self-adaptively change the microenvironment to a pro-healing state by decreasing oxidative stress, but also respond to matrix metalloproteinases to release DFO. The self-adaptive multifunctional hydrogel has a potential for treating diabetic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": 573, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.06.018", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.06.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826897500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Sun, PF; Cong, S; Wu, J; Gao, LJ; Wang, Y; Dai, X; Yi, QH; Zou, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hao; Sun, Pengfei; Cong, Shan; Wu, Jiang; Gao, Lijun; Wang, Yun; Dai, Xiao; Yi, Qinghua; Zou, Guifu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Doped Carbon Dots for green Quantum Dot Solar Cells", "Source Title": "nullOSCALE RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Considering the environment protection, green materials are increasingly explored for photovoltaics. Here, we developed a kind of quantum dots solar cell based on nitrogen-doped carbon dots. The nitrogen-doped carbon dots were prepared by direct pyrolysis of citric acid and ammonia. The nitrogen-doped carbon dots' excitonic absorption depends on the N-doping content in the carbon dots. The N-doping can be readily modified by the mass ratio of reactants. The constructed green nitrogen-doped carbon dots solar cell achieves the best power conversion efficiency of 0.79 % under AM 1.5 G one full sun illumination, which is the highest efficiency for carbon dot-based solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2016, "Volume": 11, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27, "DOI": "10.1186/s11671-016-1231-1", "DOI Link": "http://dx.doi.org/10.1186/s11671-016-1231-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391736800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Castellanos-Gomez, A; Vicarelli, L; Prada, E; Island, JO; Narasimha-Acharya, KL; Blanter, SI; Groenendijk, DJ; Buscema, M; Steele, GA; Alvarez, JV; Zandbergen, HW; Palacios, JJ; van der Zant, HSJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Castellanos-Gomez, Andres; Vicarelli, Leonardo; Prada, Elsa; Island, Joshua O.; Narasimha-Acharya, K. L.; Blanter, Sofya I.; Groenendijk, Dirk J.; Buscema, Michele; Steele, Gary A.; Alvarez, J. V.; Zandbergen, Henny W.; Palacios, J. J.; van der Zant, Herre S. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolation and characterization of few-layer black phosphorus", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Isolation and characterization of mechanically exfoliated black phosphorus flakes with a thickness down to two single-layers is presented. A modification of the mechanical exfoliation method, which provides higher yield of atomically thin flakes than conventional mechanical exfoliation, has been developed. We present general guidelines to determine the number of layers using optical microscopy, Raman spectroscopy and transmission electron microscopy (TEM) in a fast and reliable way. Moreover, we demonstrate that the exfoliated flakes are highly crystalline and that they are stable even in free-standing form through Raman spectroscopy and TEM measurements. A strong thickness dependence of the band structure is found by density functional theory (DFT) calculations. The exciton binding energy, within an effective mass approximation, is also calculated for different number of layers. Our computational results for the optical gap are consistent with preliminary photoluminescence results on thin flakes. Finally, we study the environmental stability of black phosphorus flakes finding that the flakes are very hydrophilic and that long term exposure to air moisture etches black phosphorus away. Nonetheless, we demonstrate that the aging of the flakes is slow enough to allow fabrication of field-effect transistors with strong ambipolar behavior. DFT calculations also give us insight into the water-induced changes of the structural and electronic properties of black phosphorus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2241, "Times Cited, All Databases": 2549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25001, "DOI": "10.1088/2053-1583/1/2/025001", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/1/2/025001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353650400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dualeh, A; Tétreault, N; Moehl, T; Gao, P; Nazeeruddin, MK; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dualeh, Amalie; Tetreault, Nicolas; Moehl, Thomas; Gao, Peng; Nazeeruddin, Mohammad Khaja; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskites have attracted attention as successful light harvesting materials for mesoscopic solid-state solar cells and led to record breaking efficiencies. The photovoltaic performance of these devices is greatly dependent on the film morphology, which in turn is dependent on the deposition techniques and subsequent treatments employed. In this work the perovskite film is deposited by spin-coating a precursor solution of PbCl2 and CH3NH3I (1 to 3 molar ratio) in dimethylformamide. Here, the role of the temperature used in the annealing process required to convert the as deposited solution into the perovskite material is investigated. It is found that the conversion requires sufficiently high temperatures to ensure the vaporization of solvent and the crystallization of the perovskite material. However, increasing the annealing temperature too high leads to the additional formation of PbI2, which is detrimental to the photovoltaic performance. Furthermore, the effect of the annealing temperature on the film formation, morphology, and composition is examined and correlated with the photovoltaic performance and device working mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 863, "Times Cited, All Databases": 944, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 24, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3250, "End Page": 3258, "Article Number": null, "DOI": "10.1002/adfm.201304022", "DOI Link": "http://dx.doi.org/10.1002/adfm.201304022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337489400021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, ZY; Bao, CX; Liu, Y; Jiang, Q; Wu, WQ; Chen, SS; Dai, XZ; Chen, B; Hartweg, B; Yu, ZS; Holman, Z; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Zhenyi; Bao, Chunxiong; Liu, Ye; Jiang, Qi; Wu, Wu-Qiang; Chen, Shangshang; Dai, Xuezeng; Chen, Bo; Hartweg, Barry; Yu, Zhengshan; Holman, Zachary; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resolving spatial and energetic distributions of trap states in metal halide perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the profiling of spatial and energetic distributions of trap states in metal halide perovskite single-crystalline and polycrystalline solar cells. The trap densities in single crystals varied by five orders of magnitude, with a lowest value of 2 x 10(11) per cubic centimeter and most of the deep traps located at crystal surfaces. The charge trap densities of all depths of the interfaces of the polycrystalline films were one to two orders of magnitude greater than that of the film interior, and the trap density at the film interior was still two to three orders of magnitude greater than that in high-quality single crystals. Suprisingly, after surface passivation, most deep traps were detected near the interface of perovskites and hole transport layers, where a large density of nullocrystals were embedded, limiting the efficiency of solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 916, "Times Cited, All Databases": 958, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 367, "Issue": 6484, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1352, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba0893", "DOI Link": "http://dx.doi.org/10.1126/science.aba0893", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522167400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, HX; Ghorbani-Asl, M; Ly, KH; Zhang, JC; Ge, J; Wang, MC; Liao, ZQ; Makarov, D; Zschech, E; Brunner, E; Weidinger, IM; Zhang, J; Krasheninnikov, AV; Kaskel, S; Dong, RH; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Haixia; Ghorbani-Asl, Mahdi; Ly, Khoa Hoang; Zhang, Jichao; Ge, Jin; Wang, Mingchao; Liao, Zhongquan; Makarov, Denys; Zschech, Ehrenfried; Brunner, Eike; Weidinger, Inez M.; Zhang, Jian; Krasheninnikov, Arkady V.; Kaskel, Stefan; Dong, Renhao; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic electroreduction of carbon dioxide to carbon monoxide on bimetallic layered conjugated metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly effective electrocatalysts promoting CO2 reduction reaction (CO2RR) is extremely desirable to produce value-added chemicals/fuels while addressing current environmental challenges. Herein, we develop a layer-stacked, bimetallic two-dimensional conjugated metal-organic framework (2D c-MOF) with copper-phthalocyanine as ligand (CuN4) and zinc-bis(dihydroxy) complex (ZnO4) as linkage (PcCu-O-8-Zn). The PcCu-O-8-Zn exhibits high CO selectivity of 88%, turnover frequency of 0.39s(-1) and long-term durability (>10h), surpassing thus by far reported MOF-based electrocatalysts. The molar H-2/CO ratio (1:7 to 4:1) can be tuned by varying metal centers and applied potential, making 2D c-MOFs highly relevant for syngas industry applications. The contrast experiments combined with operando spectroelectrochemistry and theoretical calculation unveil a synergistic catalytic mechanism; ZnO4 complexes act as CO2RR catalytic sites while CuN4 centers promote the protonation of adsorbed CO2 during CO2RR. This work offers a strategy on developing bimetallic MOF electrocatalysts for synergistically catalyzing CO2RR toward syngas synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1409, "DOI": "10.1038/s41467-020-15141-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15141-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521328300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Zheng, YJ; Ma, T; Yang, CD; Peng, YF; Zhou, ZH; Zhou, M; Li, S; Wang, YH; Cheng, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ben; Zheng, Yijuan; Ma, Tian; Yang, Chengdong; Peng, Yifei; Zhou, Zhihao; Zhou, Mi; Li, Shuang; Wang, Yinghan; Cheng, Chong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing MOF nulloarchitectures for Electrochemical Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting has attracted significant attention as a key pathway for the development of renewable energy systems. Fabricating efficient electrocatalysts for these processes is intensely desired to reduce their overpotentials and facilitate practical applications. Recently, metal-organic framework (MOF) nulloarchitectures featuring ultrahigh surface areas, tunable nullostructures, and excellent porosities have emerged as promising materials for the development of highly active catalysts for electrochemical water splitting. Herein, the most pivotal advances in recent research on engineering MOF nulloarchitectures for efficient electrochemical water splitting are presented. First, the design of catalytic centers for MOF-based/derived electrocatalysts is summarized and compared from the aspects of chemical composition optimization and structural functionalization at the atomic and molecular levels. Subsequently, the fast-growing breakthroughs in catalytic activities, identification of highly active sites, and fundamental mechanisms are thoroughly discussed. Finally, a comprehensive commentary on the current primary challenges and future perspectives in water splitting and its commercialization for hydrogen production is provided. Hereby, new insights into the synthetic principles and electrocatalysis for designing MOF nulloarchitectures for the practical utilization of water splitting are offered, thus further promoting their future prosperity for a wide range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 435, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 33, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2006042, "DOI": "10.1002/adma.202006042", "DOI Link": "http://dx.doi.org/10.1002/adma.202006042", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631171200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Huang, JH; Guo, ZW; Dong, XL; Liu, Y; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhuo; Huang, Jianhang; Guo, Zhaowei; Dong, Xiaoli; Liu, Yao; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc metal featuring low cost, high capacity, low potential, and environmental benignity is an exciting anode material for aqueous energy storage devices. Unfortunately, the dendrite growth, limited reversibility, and undesired hydrogen evolution hinder its application. Herein, we demonstrate that MOF ZIF-8 annealed at 500 degrees C (ZIF-8-500) can be used as a host material for high-efficiency (approximately 100%) and dendrite-free Zn plating and stripping because of its porous structure, trace amount of zinc in the framework, and high over-potential for hydrogen evolution. The Zn@ZIF-8-500 anode (i.e., ZIF-8-500 pre-plated with 10.0 mAh cm(-2) Zn) is coupled with an activated carbon cathode or an I-2 cathode to form a hybrid supercapacitor or a rechargeable battery, respectively. The supercapacitor delivers a high energy density of 140.8 Wh kg(-1) (normalized to the mass of active materials in electrodes) while retaining 72% capacity over 20,000 cycles, and the battery shows a long life of 1,600 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 753, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1289, "End Page": 1300, "Article Number": null, "DOI": "10.1016/j.joule.2019.02.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.02.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467969300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, Y; Ma, ZR; Xiao, YY; Yin, YC; Huang, WM; Huang, ZC; Zheng, YZ; Mu, FY; Huang, R; Shi, GY; Sun, YY; Xia, XH; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yi; Ma, Zhi-Rui; Xiao, Yi-Ying; Yin, Yun-Chao; Huang, Wen-Mao; Huang, Zhi-Chao; Zheng, Yun-Zhe; Mu, Fang-Ya; Huang, Rong; Shi, Guo-Yue; Sun, Yi-Yang; Xia, Xing-Hua; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic metal-support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tuning metal-support interaction has been considered as an effective approach to modulate the electronic structure and catalytic activity of supported metal catalysts. At the atomic level, the understanding of the structure-activity relationship still remains obscure in heterogeneous catalysis, such as the conversion of water (alkaline) or hydronium ions (acid) to hydrogen (hydrogen evolution reaction, HER). Here, we reveal that the fine control over the oxidation states of single-atom Pt catalysts through electronic metal-support interaction significantly modulates the catalytic activities in either acidic or alkaline HER. Combined with detailed spectroscopic and electrochemical characterizations, the structure-activity relationship is established by correlating the acidic/alkaline HER activity with the average oxidation state of single-atom Pt and the Pt-H/Pt-OH interaction. This study sheds light on the atomic-level mechanistic understanding of acidic and alkaline HER, and further provides guidelines for the rational design of high-performance single-atom catalysts. Insights into the rational design of single-atom metal catalysts remains obscure in heterogeneous catalysis. Here, the authors establish the atomic-level structure-activity relationship for a wide-pH-range hydrogen evolution reaction through the electronic metal-support interaction modulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3021, "DOI": "10.1038/s41467-021-23306-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23306-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658766200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, WL; Gao, BA; Mei, SX; Xiang, B; Fu, JJ; Wang, L; Zhang, QB; Chu, PK; Huo, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Weili; Gao, Biao; Mei, Shixiong; Xiang, Ben; Fu, Jijiang; Wang, Lei; Zhang, Qiaobao; Chu, Paul K.; Huo, Kaifu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although silicon is a promising anode material for lithium-ion batteries, scalable synthesis of silicon anodes with good cyclability and low electrode swelling remains a significant challenge. Herein, we report a scalable top-down technique to produce ant-nest-like porous silicon from magnesium-silicon alloy. The ant-nest-like porous silicon comprising threedimensional interconnected silicon nulloligaments and bicontinuous nullopores can prevent pulverization and accommodate volume expansion during cycling resulting in negligible particle-level outward expansion. The carbon-coated porous silicon anode delivers a high capacity of 1,271 mAh g(-1) at 2,100 mA g(-1) with 90% capacity retention after 1,000 cycles and has a low electrode swelling of 17.8% at a high areal capacity of 5.1 mAh cm(-2). The full cell with the prelithiated silicon anode and Li(Ni1/3Co1/3Mn1/3)O-2 cathode boasts a high energy density of 502 Wh Kg(-1) and 84% capacity retention after 400 cycles. This work provides insights into the rational design of alloy anodes for high-energy batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 655, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1447, "DOI": "10.1038/s41467-019-09510-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09510-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462722200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YM; Hu, YS; Titirici, MM; Chen, LQ; Huang, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yunming; Hu, Yong-Sheng; Titirici, Maria-Magdalena; Chen, Liquan; Huang, Xuejie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hard Carbon Microtubes Made from Renewable Cotton as High-Performance Anode Material for Sodium-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) have attracted more and more attention for scalable electrical energy storage due to the abundance and wide distribution of Na resources. However, the anode still remains a great challenge for the application of SIBs. Here the production of uniform hard carbon micro-tubes (HCTs) made from natural cotton through one simple carbonization process and their application as an anode are reported. The study shows that the electrochemical performance of the HCTs is seriously affected by the carbonization temperature due to the difference in their microstructure and heteroatomic content. The HCTs carbonized at 1300 degrees C deliver the highest reversible capacity of 315 mAh g(-1) and good rate capability due to their unique tubular structure. This contribution not only provides a new approach for the preparation of hard carbon materials with unique tubular microstructure using natural inspiration, but it also deepens the fundamental understanding of the sodium storage mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 558, "Times Cited, All Databases": 576, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2016, "Volume": 6, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600659, "DOI": "10.1002/aenm.201600659", "DOI Link": "http://dx.doi.org/10.1002/aenm.201600659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387132200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, P; Chen, W; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Peng; Chen, Wei; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Review of Phosphide-Based Materials for Electrocatalytic Hydrogen Evolution", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution by means of electrocatalytic water-splitting is pivotal for efficient and economical production of hydrogen, which relies on the development of inexpensive, highly active catalysts. In addition to sulfides, the search for non-noble metal catalysts has been mainly directed at phosphides due to the superb activity of phosphides for hydrogen evolution reaction (HER) and their low-cost considering the abundance of the non-noble constituents of phosphides. Here, recent research focusing on phosphides is summarized based on their synthetic methodology. A comparative study of the catalytic activity of different phosphides towards HER is then conducted. The catalytic activity is evaluated by overpotentials at fixed current density, Tafel slope, turnover frequency, and the Gibbs free energy of hydrogen adsorption. Based on the methods discussed, perspectives for the various methods of phosphides synthesis are given, and the origins of the high activity and the role of phosphorus on the improved activity towards HER are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 799, "Times Cited, All Databases": 830, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2015, "Volume": 5, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500985, "DOI": "10.1002/aenm.201500985", "DOI Link": "http://dx.doi.org/10.1002/aenm.201500985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367218400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, Q; Huang, BL; Zhang, N; Sun, MZ; Shao, Q; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Qing; Huang, Bolong; Zhang, null; Sun, Mingzi; Shao, Qi; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Channel-Rich RuCu nullosheets for pH-Universal Overall Water Splitting Electrocatalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Channel-rich RuCu snowflake-like nullosheets (NSs) composed of crystallized Ru and amorphous Cu were used as efficient electrocatalysts for oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and overall water splitting in pH-universal electrolytes. The optimized RuCu NSs/C-350 degrees C and RuCu NSs/C-250 degrees C show attractive activities of OER and HER with low overpotentials and small Tafel slopes, respectively. When applied to overall water splitting, the optimized RuCu NSs/C can reach 10 mA cm(-2) at cell voltages of only 1.49, 1.55, 1.49 and 1.50 V in 1 m KOH, 0.1 m KOH, 0.5 m H2SO4 and 0.05 m H2SO4, respectively, much lower than those of commercial Ir/C parallel to Pt/C. The optimized electrolyzer exhibits superior durability with small potential change after up to 45 h in 1 m KOH, showing a class of efficient functional electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2019, "Volume": 58, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13983, "End Page": 13988, "Article Number": null, "DOI": "10.1002/anie.201908092", "DOI Link": "http://dx.doi.org/10.1002/anie.201908092", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481236300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, YH; Xiao, ZG; Bi, C; Yuan, YB; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng; Yuan, Yongbo; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large photocurrent hysteresis observed in many organometal trihalide perovskite solar cells has become a major hindrance impairing the ultimate performance and stability of these devices, while its origin was unknown. Here we demonstrate the trap states on the surface and grain boundaries of the perovskite materials to be the origin of photocurrent hysteresis and that the fullerene layers deposited on perovskites can effectively passivate these charge trap states and eliminate the notorious photocurrent hysteresis. Fullerenes deposited on the top of the perovskites reduce the trap density by two orders of magnitude and double the power conversion efficiency of CH3NH3PbI3 solar cells. The elucidation of the origin of photocurrent hysteresis and its elimination by trap passivation in perovskite solar cells provides important directions for future enhancements to device efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2804, "Times Cited, All Databases": 2934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5784, "DOI": "10.1038/ncomms6784", "DOI Link": "http://dx.doi.org/10.1038/ncomms6784", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347613200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MF; Duanmu, KN; Wan, CZ; Cheng, T; Zhang, L; Dai, S; Chen, WX; Zhao, ZP; Li, P; Fei, HL; Zhu, YM; Yu, R; Luo, J; Zang, KT; Lin, ZY; Ding, MN; Huang, J; Sun, HT; Guo, JH; Pan, XQ; Goddard, WA ; Sautet, P; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mufan; Duanmu, Kaining; Wan, Chengzhang; Cheng, Tao; Zhang, Liang; Dai, Sheng; Chen, Wenxin; Zhao, Zipeng; Li, Peng; Fei, Huilong; Zhu, Yuanming; Yu, Rong; Luo, Jun; Zang, Ketao; Lin, Zhaoyang; Ding, Mengning; Huang, Jin; Sun, Hongtao; Guo, Jinghua; Pan, Xiaoqing; Goddard, William A., III; Sautet, Philippe; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom tailoring of platinum nullocatalysts for high-performance multifunctional electrocatalysis", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum-based nullocatalysts play a crucial role in various electrocatalytic systems that are important for renewable, clean energy conversion, storage and utilization. However, the scarcity and high cost of Pt seriously limit the practical application of these catalysts. Decorating Pt catalysts with other transition metals offers an effective pathway to tailor their catalytic properties, but often at the sacrifice of the electrochemical active surface area (ECSA). Here we report a single-atom tailoring strategy to boost the activity of Pt nullocatalysts with minimal loss in surface active sites. By starting with PtNi alloy nullowires and using a partial electrochemical dealloying approach, we create single-nickel-atom-modified Pt nullowires with an optimum combination of specific activity and ECSA for the hydrogen evolution, methanol oxidation and ethanol oxidation reactions. The single-atom tailoring approach offers an effective strategy to optimize the activity of surface Pt atoms and enhance the mass activity for diverse reactions, opening a general pathway to the design of highly efficient and durable precious metal-based catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 503, "Article Number": null, "DOI": "10.1038/s41929-019-0279-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0279-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471291500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, AZ; He, B; Fan, XY; Liu, ZK; Urban, JJ; Alivisatos, AP; He, L; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Aizhao; He, Bo; Fan, Xiaoyun; Liu, Zeke; Urban, Jeffrey J.; Alivisatos, A. Paul; He, Ling; Liu, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insight into the Ligand-Mediated Synthesis of Colloidal CsPbBr3 Perovskite nullocrystals: The Role of Organic Acid, Base, and Cesium Precursors", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While convenient solution-based procedures have been realized for the synthesis of colloidal perovskite nullocrystals, the impact of surfactant ligands on the shape, size, and surface properties still remains poorly understood, which calls for a more detailed structure morphology study. Herein we have systematically varied the hydrocarbon chain composition of carboxylic acids and amines to investigate the surface chemistry and the independent impact of acid and amine on the size and shape of perovskite nullocrystals. Solution phase studies on purified nullocrystal samples by H-1 NMR and IR spectroscopies have confirmed the presence of both carboxylate and alkylammonium ligands on surfaces, with the alkylammonium ligand being much more mobile and susceptible to detachment from the nullocrystal surfaces during polar solvent washes. Moreover, the chain length variation of carboxylic acids and amines, ranging from 18 carbons down to two carbons, has shown independent correlation to the size and shape of nullocrystals in addition to the temperature effect. We have additionally demonstrated that employing a more soluble cesium acetate precursor in place of the universally used Cs2CO3 results in enhanced processability without sacrificing optical properties, thus offering a more versatile recipe for perovskite nullocrystal synthesis that allows the use of organic acids and amines bearing chains shorter than eight carbon atoms. Overall our studies have shed light on the influence of ligand chemistry on crystal growth and stabilization of the nullocrystals, which opens the door to functionalizable perovskite nullocrsytals through surface ligand manipulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 751, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7943, "End Page": 7954, "Article Number": null, "DOI": "10.1021/acsnullo.6b03863", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b03863", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381959100079", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Kim, JC; Wu, RJ; Martinez, J; Song, XJ; Yang, J; Zhao, F; Mkhoyan, KA; Jeong, HY; Chhowalla, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yan; Kim, Jong Chan; Wu, Ryan J.; Martinez, Jenny; Song, Xiuju; Yang, Jieun; Zhao, Fang; Mkhoyan, K. Andre; Jeong, Hu Young; Chhowalla, Manish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals contacts between three-dimensional metals and two-dimensional semiconductors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the dimensions of the semiconducting channels in fieldeffect transistors decrease, the contact resistance of the metalsemiconductor interface at the source and drain electrodes increases, dominating the performance of devices(1-3). Two-dimensional (2D) transition-metal dichalcogenides such as molybdenum disulfide (MoS2) have been demonstrated to be excellent semiconductors for ultrathin field-effect transistors(4,5). However, unusually high contact resistance has been observed across the interface between the metal and the 2D transition-metal dichalcogenide(3,5-9). Recent studies have shown that van der Waals contacts formed by transferred graphene(10,11) and metals(12) on few-layered transitionmetal dichalcogenides produce good contact properties. However, van der Waals contacts between a three-dimensional metal and a monolayer 2D transition-metal dichalcogenide have yet to be demonstrated. Here we report the realization of ultraclean van der Waals contacts between 10-nullometre-thick indium metal capped with 100-nullometre-thick gold electrodes and monolayer MoS2. Using scanning transmission electron microscopy imaging, we show that the indium and gold layers form a solid solution after annealing at 200 degrees Celsius and that the interface between the gold-capped indium and the MoS2 is atomically sharp with no detectable chemical interaction between the metal and the 2D transition-metal dichalcogenide, suggesting van-der-Waals-type bonding between the gold-capped indium and monolayer MoS2. The contact resistance of the indium/gold electrodes is 3,000 +/- 300 ohm micrometres for monolayer MoS2 and 800 +/- 200 ohm micrometres for few-layered MoS2. These values are among the lowest observed for three-dimensional metal electrodes evaporated onto MoS2, enabling high-performance field-effect transistors with a mobility of 167 +/- 20 square centimetres per volt per second. We also demonstrate a low contact resistance of 220 +/- 50 ohm micrometres on ultrathin niobium disulfide (NbS2) and near-ideal band offsets, indicative of defect-free interfaces, in tungsten disulfide (WS2) and tungsten diselenide (WSe2) contacted with indium alloy. Our work provides a simple method of making ultraclean van der Waals contacts using standard laboratory technology on monolayer 2D semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 653, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2019, "Volume": 568, "Issue": 7750, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 70, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1052-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1052-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463384900041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YS; Che, FL; Liu, M; Zou, CQ; Liang, ZQ; De Luna, P; Yuan, HF; Li, J; Wang, ZQ; Xie, HP; Li, HM; Chen, PN; Bladt, E; Quintero-Bermudez, R; Sham, TK; Bals, S; Hofkens, J; Sinton, D; Chen, G; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yansong; Che, Fanglin; Liu, Min; Zou, Chengqin; Liang, Zhiqin; De Luna, Phil; Yuan, Haifeng; Li, Jun; Wang, Zhiqiang; Xie, Haipeng; Li, Hongmei; Chen, Peining; Bladt, Eva; Quintero-Bermudez, Rafael; Sham, Tsun-Kong; Bals, Sara; Hofkens, Johan; Sinton, David; Chen, Gang; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of CO2 to multi-carbon products has attracted much attention because it provides an avenue to the synthesis of value-added carbon-based fuels and feedstocks using renewable electricity. Unfortunately, the efficiency of CO2 conversion to C-2 products remains below that necessary for its implementation at scale. Modifying the local electronic structure of copper with positive valence sites has been predicted to boost conversion to C-2 products. Here, we use boron to tune the ratio of Cu delta+ to Cu-0 active sites and improve both stability and C-2-product generation. Simulations show that the ability to tune the average oxidation state of copper enables control over CO adsorption and dimerization, and makes it possible to implement a preference for the electrosynthesis of C-2 products. We report experimentally a C-2 Faradaic efficiency of 79 +/- 2% on boron-doped copper catalysts and further show that boron doping leads to catalysts that are stable for in excess of similar to 40 hours while electrochemically reducing CO2 to multi-carbon hydrocarbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 886, "Times Cited, All Databases": 924, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 974, "End Page": 980, "Article Number": null, "DOI": "10.1038/s41557-018-0092-x", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0092-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442395200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Xue, JJ; Wang, KL; Wang, ZK; Luo, YQ; Fenning, D; Xu, GW; Nuryyeva, S; Huang, TY; Zhao, YP; Yang, JL; Zhu, JH; Wang, MH; Tan, S; Yavuz, I; Houk, KN; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Xue, Jingjing; Wang, Kai-Li; Wang, Zhao-Kui; Luo, Yanqi; Fenning, David; Xu, Guangwei; Nuryyeva, Selbi; Huang, Tianyi; Zhao, Yepin; Yang, Jonathan Lee; Zhu, Jiahui; Wang, Minhuan; Tan, Shaun; Yavuz, Ilhan; Houk, Kendall N.; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface trap-mediated nonradiative charge recombination is a major limit to achieving high-efficiency metal-halide perovskite photovoltaics. The ionic character of perovskite lattice has enabled molecular defect passivation approaches through interaction between functional groups and defects. However, a lack of in-depth understanding of how the molecular configuration influences the passivation effectiveness is a challenge to rational molecule design. Here, the chemical environment of a functional group that is activated for defect passivation was systematically investigated with theophylline, caffeine, and theobromine. When N-H and C=O were in an optimal configuration in the molecule, hydrogen-bond formation between N-H and I (iodine) assisted the primary C=O binding with the antisite Pb (lead) defect to maximize surface-defect binding. A stabilized power conversion efficiency of 22.6% of photovoltaic device was demonstrated with theophylline treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1051, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2019, "Volume": 366, "Issue": 6472, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1509, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay9698", "DOI Link": "http://dx.doi.org/10.1126/science.aay9698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503861000054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stoumpos, CC; Cao, DH; Clark, DJ; Young, J; Rondinelli, JM; Jang, JI; Hupp, JT; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.; Young, Joshua; Rondinelli, James M.; Jang, Joon I.; Hupp, Joseph T.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ruddlesden-Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hybrid two-dimensional (2D) halide perovskites have recently drawn significant interest because they can serve as excellent photoabsorbers in perovskite solar cells. Here we present the large scale synthesis, crystal structure, and optical characterization of the 2D (CH3(CH2)(3)NH3)(2)(CH3NR3)(n-1)PbnI3n+1 (n = 1, 2, 3, 4, infinity) perovskites, a family of layered compounds with tunable semiconductor characteristics. These materials consist of well-defined inorganic perovskite layers intercalated with bulky butylammonium cations that act as spacers between these fragments, adopting the crystal structure of the Ruddlesden-Popper type. We find that the perovskite thickness (n) can be synthetically controlled by adjusting the ratio between the spacer cation and the small organic cation, thus allowing the isolation of compounds in pure form and large scale. The orthorhombic crystal structures of (CH3(CH2)(3)NH3)(2)(CH3NH3)-Pb2I7 (n = 2, Cc2m; a = 8.9470(4), b = 39.347(2) angstrom, c = 8.8589(6)), (CH3(CH2)(3)NH3)(2)(CH3NH3)(2)Pb3I10 (n = 3, C2cb; a = 8.9275(6), b = 51.959(4) angstrom, c = 8.8777(6)), and (CH3(CH2)(3)NH3)(2)(CH3NH3)(3)Pb4I13 (n = 4, Cc2m; a = 8.9274(4), b = 64.383(4) angstrom, c = 8.8816(4)) have been solved by single-crystal X-ray diffraction and are reported here for the first time. The compounds are noncentrosymmetric, as supported by measurements of the nonlinear optical properties of the compounds and density functional theory (DFT) calculations. The band gaps of the series change progressively between 2.43 eV for the n = 1 member to 1.50 eV for the n = infinity adopting intermediate values of 2.17 eV (n = 2), 2.03 eV (n = 3), and 1.91 eV (n = 4) for those between the two compositional extrema. DFT calculations confirm this experimental trend and predict a direct band gap for all the members of the Ruddlesden Popper series. The estimated effective masses have values of m(h) = 0.14 m(0) and m(e) = 0.08 m(0) for holes and electrons, respectively, and are found to be nearly composition independent. The band gaps of higher n members indicate that these compounds can be used as efficient light absorbers in solar cells, which offer better solution processability and good environmental stability. The compounds exhibit intense room-temperature photoluminescence with emission wavelengths consistent with their energy gaps, 2.35 eV (n = 1), 2.12 eV (n = 2), 2.01 eV (n = 3), and 1.90 eV (n = 4) and point to their potential use in light-emitting diodes. In addition, owing to the low dimensionality and the difference in dielectric properties between the organic spacers and the inorganic perovskite layers, these compounds are naturally occurring multiple quantum well structures, which give rise to stable excitons at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1704, "Times Cited, All Databases": 1861, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2016, "Volume": 28, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2852, "End Page": 2867, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b00847", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b00847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375244500043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JQ; Zhuang, TZ; Zhang, Q; Peng, HJ; Chen, CM; Wei, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jia-Qi; Zhuang, Ting-Zhou; Zhang, Qiang; Peng, Hong-Jie; Chen, Cheng-Meng; Wei, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Permselective Graphene Oxide Membrane for Highly Stable and Anti-Self-Discharge Lithium-Sulfur Batteries", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries hold great promise for serving as next generation high energy density batteries. However, the Shuttle of pdlysulfide induces rapid capacity degradation.aticl poor cycling stability of lithium sulfur tells. Herein, we proposed a unique lithium sulfur battery configuration with an ultrathin graphene oxide (GO) membrane for high stability. The oxygen electronegative atoms modifieci60 into a polar plane, and the carboxyl groups acted as ion-hopping sites of positively charged species (Lit) and rejected the transportation of negatively charged species (S-n(2-)) due to the electrostatic interactions. Such electrostatic repulsion and physical inhibition largely decreased the transferenceof polysulfides across the GO:membrane in the lithium sulfur system. Consequently, the GO membrane with highly tunable functionalizatidn properties, high mechanical strength, low electric conductivity', and facile fabrication procedure is an effective permselective separator system in lithium sulfur batteries. By the incorporation of a=permselective do membrane, the cyclic capacity decay rate is also reduced from 0.49 to 0.23%/cycle. As the GO membrane blocks the diffusion of polystilfides through the membrane, it is also with advantages of antkelfdischarge properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 729, "Times Cited, All Databases": 786, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3002, "End Page": 3011, "Article Number": null, "DOI": "10.1021/nn507178a", "DOI Link": "http://dx.doi.org/10.1021/nn507178a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351791800073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, BL; Lin, CC; Yuan, Z; He, Y; Chen, MW; Li, K; Hu, JW; Yang, YL; Xia, ZZL; Cai, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Bailong; Lin, Chuanchuan; Yuan, Zhang; He, Ye; Chen, Maowen; Li, Ke; Hu, Jingwei; Yang, Yulu; Xia, Zengzilu; Cai, Kaiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near infrared light-triggered on-demand Cur release from Gel-PDA@Cur composite hydrogel for antibacterial wound healing", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of antibacterial and rapid hemostatic wound dressing with good biocompatibility is urgently required for promoting non-healing wounds. In this work, a multifunctional near infrared (NIR) laser-induced hydrogel for infected wound healing is presented. The hydrogel was composed of dibenzaldehyde-grafted poly (ethylene glycol) (PEGDA), lauric acid-terminated chitosan (Chi-LA), and curcumin (Cur)-loaded mesoporous polydopamine nulloparticles (PDA@Cur) via Schiff base and/or Michael addition reaction. The Cur could rapidly release from Gel-PDA@Cur hydrogel under NIR laser irradiation with on-demand release property. Meanwhile, NIR irradiation could activate the photothermal PDA NPs in Gel-PDA@Cur hydrogel and generate local hyperthermia for killing Escherichia coli and Staphylococcus aureus. It was realized by inducing the out-diffusion of K+, inactivating the respiratory chain dehydrogenase and beta-galactosidase activity, causing cellular components leakage (protein, DNA and RNA, etc.), reducing the ATP level, and destroying bacterial membrane. Moreover, the Gel-PDA@Cur hydrogel exhibited good biocompatibility. Furthermore, in vivo treatment in a S. aureus-infected full-thickness skin defect model revealed that the Gel-PDA@Cur hydrogel presented good hemostatic function, prominent antibacterial ability, strong anti-inflammatory effect, and good wound healing capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 403, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126182, "DOI": "10.1016/j.cej.2020.126182", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.126182", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579752500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, Y; Zhu, B; Lu, ZD; Liu, N; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Yan; Zhu, Bin; Lu, Zhenda; Liu, Nian; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon, because of its high specific capacity, is intensively pursued as one of the most promising anode material for next-generation lithium-ion batteries. In the past decade, various nullostructures are successfully demonstrated to address major challenges for reversible Si anodes related to pulverization and solid-electrolyte interphase. However, the electrochemical performance is still limited by challenges that stem from the use of nullomaterials. In this progress report, the focus is on the challenges and recent progress in the development of Si anodes for lithium-ion battery, including initial Coulombic efficiency, areal capacity, and material cost, which call for more research effort and provide a bright prospect for the widespread applications of silicon anodes in the future lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 862, "Times Cited, All Databases": 909, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 6", "Publication Year": 2017, "Volume": 7, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700715, "DOI": "10.1002/aenm.201700715", "DOI Link": "http://dx.doi.org/10.1002/aenm.201700715", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423878500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JM; Zhang, WK; Yuan, HD; Jin, CB; Zhang, LY; Huang, H; Liang, C; Xia, Y; Zhang, J; Gan, YP; Tao, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jianmin; Zhang, Wenkui; Yuan, Huadong; Jin, Chengbin; Zhang, Liyuan; Huang, Hui; Liang, Chu; Xia, Yang; Zhang, Jun; Gan, Yongping; Tao, Xinyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pillared Structure Design of MXene with Ultralarge Interlayer Spacing for High-Performance Lithium-Ion Capacitors", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition-metal carbide materials (termed MXene) have attracted huge attention in the field of electrochemical energy storage due to their excellent electrical conductivity, high volumetric capacity, etc. Herein, with inspiration from the interesting structure of pillared interlayered clays, we attempt to fabricate pillared Ti3C2 MXene (CTAB-Sn(IV)@Ti3C2) via a facile liquid-phase cetyltrimethylammonium bromide (CTAB) prepillaring and Sn4+ pillaring method. The interlayer spacing of Ti3C2 MXene can be controlled according to the size of the intercalated prepillaring agent (cationic surfactant) and can reach 2.708 nm with 177% increase compared with the original spacing of 0.977 nm, which is currently the maximum value according to our knowledge. Because of the pillar effect, the assembled LIC exhibits a superior energy density of 239.50 Wh kg(-1) based on the weight of CTAB-Sn(IV)@Ti3C2 even under higher power density of 10.8 kW kg(-1). When CTAB-Sn(IV)@Ti3C2 anode couples with commercial AC cathode, LIC reveals higher energy density and power density compared with conventional MXene materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 746, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2459, "End Page": 2469, "Article Number": null, "DOI": "10.1021/acsnullo.6b07668", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b07668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398014900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Denny, MS; Cohen, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Denny, Michael S., Jr.; Cohen, Seth M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Processable films of metal-organic frameworks (MOFs) have been long sought to advance the application of MOFs in various technologies from separations to catalysis. Herein, MOF-polymer mixed-matrix membranes (MMMs) are described, formed on several substrates using a wide variety of MOF materials. These MMMs can be delaminated from their substrates to create free-standing MMMs that are mechanically stable and pliable. The MOFs in these MMMs remain highly crystalline, porous, and accessible for further chemical modification through postsynthetic modification (PSM) and postsynthetic exchange (PSE) processes. Overall, the findings here demonstrate a versatile approach to preparing stable functional MMMs that should contribute significantly to the advancement of these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2015, "Volume": 54, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9029, "End Page": 9032, "Article Number": null, "DOI": "10.1002/anie.201504077", "DOI Link": "http://dx.doi.org/10.1002/anie.201504077", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358501500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, ZT; Ji, XS; Sarker, PK; Tang, JH; Ge, LQ; Xia, MS; Xi, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Z. T.; Ji, X. S.; Sarker, P. K.; Tang, J. H.; Ge, L. Q.; Xia, M. S.; Xi, Y. Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A comprehensive review on the applications of coal fly ash", "Source Title": "EARTH-SCIENCE REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coal fly ash, an industrial by-product, is derived from coal combustion in thermal power plants. It is one of the most complex anthropogenic materials, and its improper disposal has become an environmental concern and resulted in a waste of recoverable resources. There is a pressing and ongoing need to develop new recycling methods for coal fly ash. The present review first describes the generation, physicochemical properties and hazards of coal fly ash at the global level, and then focuses on its current and potential applications, including use in the soil amelioration, construction industry, ceramic industry, catalysis, depth separation, zeolite synthesis, etc. Finally, the advantages and disadvantages of these applications, the mode of fly ash utilization worldwide and directions for future research are considered. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1249, "Times Cited, All Databases": 1415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 141, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 105, "End Page": 121, "Article Number": null, "DOI": "10.1016/j.earscirev.2014.11.016", "DOI Link": "http://dx.doi.org/10.1016/j.earscirev.2014.11.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349586100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tee, BCK; Chortos, A; Berndt, A; Nguyen, AK; Tom, A; McGuire, A; Lin, ZLC; Tien, K; Bae, WG; Wang, HL; Mei, P; Chou, HH; Cui, BX; Deisseroth, K; Ng, TN; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tee, Benjamin C. -K.; Chortos, Alex; Berndt, Andre; Nguyen, Amanda Kim; Tom, Ariane; McGuire, Allister; Lin, Ziliang Carter; Tien, Kevin; Bae, Won-Gyu; Wang, Huiliang; Mei, Ping; Chou, Ho-Hsiu; Cui, Bianxiao; Deisseroth, Karl; Ng, Tse Nga; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A skin-inspired organic digital mechanoreceptor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Human skin relies on cutaneous receptors that output digital signals for tactile sensing in which the intensity of stimulation is converted to a series of voltage pulses. We present a power-efficient skin-inspired mechanoreceptor with a flexible organic transistor circuit that transduces pressure into digital frequency signals directly. The output frequency ranges between 0 and 200 hertz, with a sublinear response to increasing force stimuli that mimics slow-adapting skin mechanoreceptors. The output of the sensors was further used to stimulate optogenetically engineered mouse somatosensory neurons of mouse cortex in vitro, achieving stimulated pulses in accordance with pressure levels. This work represents a step toward the design and use of large-area organic electronic skins with neural-integrated touch feedback for replacement limbs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 726, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2015, "Volume": 350, "Issue": 6258, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 313, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaa9306", "DOI Link": "http://dx.doi.org/10.1126/science.aaa9306", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362838700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, DL; Zhu, CR; Xia, XH; Liu, JL; Zhang, X; Wang, J; Liang, P; Lin, JY; Zhang, H; Shen, ZX; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Dongliang; Zhu, Changrong; Xia, Xinhui; Liu, Jilei; Zhang, Xiao; Wang, Jin; Liang, Pei; Lin, Jianyi; Zhang, Hua; Shen, Ze Xiang; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene Quantum Dots Coated VO2 Arrays for Highly Durable Electrodes for Li and Na Ion Batteries", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale surface engineering is playing important role in enhancing the performance of battery electrode. VO2 is one of high-capacity but less-stable materials and has been used mostly in the form of powders for Li-ion battery cathode with mediocre performance. In this work, we design a new type of binder-free cathode by bottom-up growth of biface VO2 arrays directly on a graphene network for both high-performance Li-ion and Na-ion battery cathodes. More importantly, graphene quantum dots (GQDs) are coated onto the VO2 surfaces as a highly efficient surface sensitizer and protection to further boost the electrochemical properties. The integrated electrodes deliver a Na storage capacity of 306 mAh/g at 100 mA/g, and a capacity of more than 110 mAh/g after 1500 cycles at 18 A/g. Our result on Na-ion battery may pave the way to next generation postlithium batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 493, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 565, "End Page": 573, "Article Number": null, "DOI": "10.1021/nl504038s", "DOI Link": "http://dx.doi.org/10.1021/nl504038s", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348086100089", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WW; Chen, LJ; Dai, S; Zhao, CX; Ma, C; Wei, L; Zhu, MH; Chong, SY; Yang, HF; Liu, LJ; Bai, Y; Yu, MJ; Xu, YJ; Zhu, XW; Zhu, Q; An, SH; Sprick, RS; Little, MA; Wu, XF; Jiang, S; Wu, YZ; Zhang, YB; Tian, H; Zhu, WH; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Weiwei; Chen, Linjiang; Dai, Sheng; Zhao, Chengxi; Ma, Cheng; Wei, Lei; Zhu, Minghui; Chong, Samantha Y.; Yang, Haofan; Liu, Lunjie; Bai, Yang; Yu, Miaojie; Xu, Yongjie; Zhu, Xiao-Wei; Zhu, Qiang; An, Shuhao; Sprick, Reiner Sebastian; Little, Marc A.; Wu, Xiaofeng; Jiang, Shan; Wu, Yongzhen; Zhang, Yue-Biao; Tian, He; Zhu, Wei-Hong; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstructed covalent organic frameworks", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are distinguished from other organic polymers by their crystallinity(1-3), but it remains challenging to obtain robust, highly crystalline COFs because the framework-forming reactions are poorly reversible(4,5). More reversible chemistry can improve crystallinity(6-9), but this typically yields COFs with poor physicochemical stability and limited application scope(5). Here we report a general and scalable protocol to prepare robust, highly crystalline imine COFs, based on an unexpected framework reconstruction. In contrast to standard approaches in which monomers are initially randomly aligned, our method involves the pre-organization of monomers using a reversible and removable covalent tether, followed by confined polymerization. This reconstruction route produces reconstructed COFs with greatly enhanced crystallinity and much higher porosity by means of a simple vacuum-free synthetic procedure. The increased crystallinity in the reconstructed COFs improves charge carrier transport, leading to sacrificial photocatalytic hydrogen evolution rates of up to 27.98 mmol h(-1) g(-1). This nulloconfinement-assisted reconstruction strategy is a step towards programming function in organic materials through atomistic structural control.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2022, "Volume": 604, "Issue": 7904, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04443-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04443-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779100400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rivera, P; Schaibley, JR; Jones, AM; Ross, JS; Wu, SF; Aivazian, G; Klement, P; Seyler, K; Clark, G; Ghimire, NJ; Yan, JQ; Mandrus, DG; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rivera, Pasqual; Schaibley, John R.; Jones, Aaron M.; Ross, Jason S.; Wu, Sanfeng; Aivazian, Grant; Klement, Philip; Seyler, Kyle; Clark, Genevieve; Ghimire, Nirmal J.; Yan, Jiaqiang; Mandrus, D. G.; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of long-lived interlayer excitons in monolayer MoSe2-WSe2 heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals bound heterostructures constructed with two-dimensional materials, such as graphene, boron nitride and transition metal dichalcogenides, have sparked wide interest in device physics and technologies at the two-dimensional limit. One highly coveted heterostructure is that of differing monolayer transition metal dichalcogenides with type-II band alignment, with bound electrons and holes localized in individual monolayers, that is, interlayer excitons. Here, we report the observation of interlayer excitons in monolayer MoSe2-WSe2 heterostructures by photoluminescence and photoluminescence excitation spectroscopy. We find that their energy and luminescence intensity are highly tunable by an applied vertical gate voltage. Moreover, we measure an interlayer exciton lifetime of similar to 1.8 ns, an order of magnitude longer than intralayer excitons in monolayers. Our work demonstrates optical pumping of interlayer electric polarization, which may provoke further exploration of interlayer exciton condensation, as well as new applications in two-dimensional lasers, light-emitting diodes and photovoltaic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1304, "Times Cited, All Databases": 1433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6242, "DOI": "10.1038/ncomms7242", "DOI Link": "http://dx.doi.org/10.1038/ncomms7242", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350202400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wood, JD; Wells, SA; Jariwala, D; Chen, KS; Cho, E; Sangwan, VK; Liu, XL; Lauhon, LJ; Marks, TJ; Hersam, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wood, Joshua D.; Wells, Spencer A.; Jariwala, Deep; Chen, Kan-Sheng; Cho, EunKyung; Sangwan, Vinod K.; Liu, Xiaolong; Lauhon, Lincoln J.; Marks, Tobin J.; Hersam, Mark C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy are employed to characterize the structure and chemistry of the degradation process, suggesting that O-2 saturated H2O irreversibly reacts with BP to form oxidized phosphorus species. This interpretation is further supported by the observation that BP degradation occurs more rapidly on hydrophobic octadecyltrichlorosilane self-assembled monolayers and on H-Si(111) versus hydrophilic SiO2. For unencapsulated BP field-effect transistors, the ambient degradation causes large increases in threshold voltage after 6 h in ambient, followed by a similar to 10(3) decrease in FET current on/off ratio and mobility after 48 h. Atomic layer deposited AlOx overlayers effectively suppress ambient degradation, allowing encapsulated BP FETs to maintain high on/off ratios of similar to 103 and mobilities of similar to 100 cm(2) V-1 s(-1) for over 2 weeks in ambient conditions. This work shows that the ambient degradation of BP can be managed effectively when the flakes are sufficiently passivated. In turn, our strategy for enhancing BP environmental stability will accelerate efforts to implement BP in electronic and optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1330, "Times Cited, All Databases": 1466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 14, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6964, "End Page": 6970, "Article Number": null, "DOI": "10.1021/nl5032293", "DOI Link": "http://dx.doi.org/10.1021/nl5032293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346322800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YH; Zhao, JB; Li, ZK; Mu, C; Ma, W; Hu, HW; Jiang, K; Lin, HR; Ade, H; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuhang; Zhao, Jingbo; Li, Zhengke; Mu, Cheng; Ma, Wei; Hu, Huawei; Jiang, Kui; Lin, Haoran; Ade, Harald; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the field of polymer solar cell has seen much progress in device performance in the past few years, several limitations are holding back its further development. For instance, current high-efficiency (>9.0%) cells are restricted to material combinations that are based on limited donor polymers and only one specific fullerene acceptor. Here we report the achievement of high-performance (efficiencies up to 10.8%, fill factors up to 77%) thick-film polymer solar cells for multiple polymer: fullerene combinations via the formation of a near-ideal polymer: fullerene morphology that contains highly crystalline yet reasonably small polymer domains. This morphology is controlled by the temperature-dependent aggregation behaviour of the donor polymers and is insensitive to the choice of fullerenes. The uncovered aggregation and design rules yield three high-efficiency (>10%) donor polymers and will allow further synthetic advances and matching of both the polymer and fullerene materials, potentially leading to significantly improved performance and increased design flexibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2552, "Times Cited, All Databases": 2661, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5293, "DOI": "10.1038/ncomms6293", "DOI Link": "http://dx.doi.org/10.1038/ncomms6293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345653900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, R; Li, DH; Zhou, HL; Wang, C; Yin, AX; Jiang, S; Liu, Y; Chen, Y; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Rui; Li, Dehui; Zhou, Hailong; Wang, Chen; Yin, Anxiang; Jiang, Shan; Liu, Yuan; Chen, Yu; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electroluminescence and Photocurrent Generation from Atomically Sharp WSe2/MoS2 Heterojunction p-n Diodes", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The p-n diodes represent the most fundamental device building blocks for diverse optoelectronic functions, but are difficult to achieve in atomically thin transition metal dichalcogenides (TMDs) due to the challenges in selectively doping them into p- or n-type semiconductors. Here, we demonstrate that an atomically thin and sharp heterojunction p-n diode can be created by vertically stacking p-type monolayer tungsten diselenide (WSe2) and n-type few-layer molybdenum disulfide (MoS2). Electrical measurements of the vertically staked WSe2/MoS2 heterojunctions reveal excellent current rectification behavior with an ideality factor of 1.2. Photocurrent mapping shows rapid photoresponse over the entire overlapping region with a highest external quantum efficiency up to 12%. Electroluminescence studies show prominent band edge excitonic emission and strikingly enhanced hot-electron luminescence. A systematic investigation shows distinct layer-number dependent emission characteristics and reveals important insight about the origin of hot-electron luminescence and the nature of electron-orbital interaction in TMDs. We believe that these atomically thin heterojunction p-n diodes represent an interesting system for probing the fundamental electro-optical properties in TMDs and can open up a new pathway to novel optoelectronic devices such as atomically thin photodetectors, photovoltaics, as well as spin- and valley-polarized light emitting diodes, on-chip lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 1067, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5590, "End Page": 5597, "Article Number": null, "DOI": "10.1021/nl502075n", "DOI Link": "http://dx.doi.org/10.1021/nl502075n", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343016400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Q; Su, X; Lei, D; Qin, Y; Wen, JG; Guo, FM; Wu, YMA; Rong, YC; Kou, RH; Xiao, XH; Aguesse, F; Bareño, J; Ren, Y; Lu, WQ; Li, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qi; Su, Xin; Lei, Dan; Qin, Yan; Wen, Jianguo; Guo, Fangmin; Wu, Yimin A.; Rong, Yangchun; Kou, Ronghui; Xiao, Xianghui; Aguesse, Frederic; Bareno, Javier; Ren, Yang; Lu, Wenquan; Li, Yangxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching the capacity limit of lithium cobalt oxide in lithium ion batteries via lanthanum and aluminium doping", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium cobalt oxides (LiCoO2) possess a high theoretical specific capacity of 274 mAh g(-1). However, cycling LiCoO2-based batteries to voltages greater than 4.35 V versus Li/Li+ causes significant structural instability and severe capacity fade. Consequently, commercial LiCoO2 exhibits a maximum capacity of only similar to 165 mAh g(-1). Here, we develop a doping technique to tackle this long-standing issue of instability and thus increase the capacity of LiCoO2. La and Al are concurrently doped into Co-containing precursors, followed by high-temperature calcination with lithium carbonate. The dopants are found to reside in the crystal lattice of LiCoO2, where La works as a pillar to increase the c axis distance and Al as a positively charged centre, facilitating Li+ diffusion, stabilizing the structure and suppressing the phase transition during cycling, even at a high cut-off voltage of 4.5 V. This doped LiCoO2 displays an exceptionally high capacity of 190 mAh g(-1), cyclability with 96% capacity retention over 50 cycles and significantly enhanced rate capability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 634, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 936, "End Page": 943, "Article Number": null, "DOI": "10.1038/s41560-018-0180-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0180-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449518300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Gui, H; Banfield, CC; Wen, Y; Zang, HD; Dippold, MA; Charlton, A; Jones, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jie; Gui, Heng; Banfield, Callum C.; Wen, Yuan; Zang, Huadong; Dippold, Michaela A.; Charlton, Adam; Jones, Davey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The microplastisphere: Biodegradable microplastics addition alters soil microbial community structure and function", "Source Title": "SOIL BIOLOGY & BIOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics accumulating in the environment, especially microplastics (defined as particles <5 mm), can lead to a range of problems and potential loss of ecosystem services. Polyhydroxyalkanoates (PHAs) are biodegradable plastics used in mulch films, and in packaging material to minimize plastic waste and to reduce soil pollution. Little is known, however, about the effect of microbioplastics on soil-plant interactions, especially soil microbial community structure and functioning in agroecosystems. For the first time, we combined zymography (to localize enzyme activity hotspots) with substrate-induced growth respiration to investigate the effect of PHAs addition on soil microbial community structure, growth, and exoenzyme kinetics in the microplastisphere (i.e. interface between soil and microplastic particles) compared to the rhizosphere and bulk soil. We used a common PHAs biopolymer, poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and showed that PHBV was readily used by the microbial community as a source of carbon (C) resulting in an increased specific microbial growth rate and a more active microbial biomass in the microplastisphere in comparison to the bulk soil. Higher ss-glucosidase and leucine aminopeptidase activities (0.6-5.0 times higher Vmax) and lower enzyme affinities (1.5-2.0 times higher Km) were also detected in the microplastisphere relative to the rhizosphere. Furthermore, the PHBV addition changed the soil bacterial community at different taxonomical levels and increased the alpha diversity, as well as the relative abundance of Acidobacteria and Verrucomicrobia phyla, compared to the untreated soils. Overall, PHBV addition created soil hotspots where C and nutrient turnover is greatly enhanced, mainly driven by the accelerated microbial biomass and activity. In conclusion, microbioplastics have the potential to alter soil ecological functioning and biogeochemical cycling (e.g., SOM decomposition).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 156, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108211, "DOI": "10.1016/j.soilbio.2021.108211", "DOI Link": "http://dx.doi.org/10.1016/j.soilbio.2021.108211", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640189100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JK; Pu, J; Hsu, CL; Chiu, MH; Juang, ZY; Chang, YH; Chang, WH; Iwasa, Y; Takenobu, T; Li, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jing-Kai; Pu, Jiang; Hsu, Chang-Lung; Chiu, Ming-Hui; Juang, Zhen-Yu; Chang, Yung-Huang; Chang, Wen-Hao; Iwasa, Yoshihiro; Takenobu, Taishi; Li, Lain-Jong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Area Synthesis of Highly Crystalline WSe2 Mono layers and Device Applications", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The monolayer transition metal dichalcogenides have recently attracted much attention owing to their potential in valleytronics, flexible and low-power electronics, and optoelectronic devices. Recent reports have demonstrated the growth of large-size two-dimensional MoS2 layers by the sulfurization of molybdenum oxides. However, the growth of a transition metal selenide monolayer has still been a challenge. Here we report that the introduction of hydrogen in the reaction chamber helps to activate the selenization of WO3, where large size WSe2 monolayer flakes or thin films can be successfully grown. The top-gated field-effect transistors based on WSe2 monolayers using ionic gels as the dielectrics exhibit ambipolar characteristics, where the hole and electron mobility values are up to 90 and 7 cm(2)/Vs, respectively. These films can be transferred onto arbitrary substrates, which may inspire research efforts to explore their properties and applications. The resistor-loaded inverter based on a WSe2 film, with a gain of similar to 13, further demonstrates its applicability for logic-circuit integrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 925, "Times Cited, All Databases": 1035, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 923, "End Page": 930, "Article Number": null, "DOI": "10.1021/nn405719x", "DOI Link": "http://dx.doi.org/10.1021/nn405719x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330542900096", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rong, CL; Shen, XJ; Wang, Y; Thomsen, L; Zhao, TW; Li, YB; Lu, XY; Amal, R; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rong, Chengli; Shen, Xiangjian; Wang, Yuan; Thomsen, Lars; Zhao, Tingwen; Li, Yibing; Lu, Xunyu; Amal, Rose; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Structure Engineering of Single-Atom Ru Sites via Co-N4 Sites for Bifunctional pH-Universal Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of bifunctional water-splitting electrocatalysts that are efficient and stable over a wide range of pH is of great significance but challenging. Here, an atomically dispersed Ru/Co dual-sites catalyst is reported anchored on N-doped carbon (Ru/Co-N-C) for outstanding oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes. The Ru/Co-N-C catalyst requires the overpotential of only 13 and 23 mV for HER, 232 and 247 mV for OER to deliver a current density of 10 mA cm(geo)(-2) in 0.5 m H2SO4 and 1 m KOH, respectively, outperforming benchmark catalysts Pt/C and RuO2. Theoretical calculations reveal that the introduction of Co-N4 sites into Ru/Co-N-C efficiently modify the electronic structure of Ru by enlarging Ru-O covalency and increasing Ru electron density, which in turn optimize the bonding strength between oxygen/hydrogen intermediate species with Ru sites, thereby enhancing OER and HER performance. Furthermore, the incorporation of Co-N4 sites induces electron redistribution around Ru-N4, thus enhancing corrosion-resistance of Ru/Co-N-C during acid and alkaline electrolysis. The Ru/Co-N-C has been applied in a proton exchange membrane water electrolyzer and steady operation is demonstrated at a high current density of 450 mA cm(geo)(-2) for 330 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 34, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110103, "DOI": "10.1002/adma.202110103", "DOI Link": "http://dx.doi.org/10.1002/adma.202110103", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786440900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HZ; Liu, YH; Ahlawat, P; Mishra, A; Tress, WR; Eickemeyer, FT; Yang, YG; Fu, F; Wang, ZW; Avalos, CE; Carlsen, BI; Agarwalla, A; Zhang, X; Li, XG; Zhan, YQ; Zakeeruddin, SM; Emsley, L; Rothlisberger, U; Zheng, LR; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Haizhou; Liu, Yuhang; Ahlawat, Paramvir; Mishra, Aditya; Tress, Wolfgang R.; Eickemeyer, Felix T.; Yang, Yingguo; Fu, Fan; Wang, Zaiwei; Avalos, Claudia E.; Carlsen, Brian, I; Agarwalla, Anulld; Zhang, Xin; Li, Xiaoguo; Zhan, Yiqiang; Zakeeruddin, Shaik M.; Emsley, Lyndon; Rothlisberger, Ursula; Zheng, Lirong; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapor-assisted deposition of highly efficient, stable black-phase FAPbI3 perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixtures of cations or halides with FAPbI(3) (where FA is formamidinium) lead to high efficiency in perovskite solar cells (PSCs) but also to blue-shifted absorption and long-term stability issues caused by loss of volatile methylammonium (MA) and phase segregation. We report a deposition method using MA thiocyanate (MASCN) or FASCN vapor treatment to convert yellow delta-FAPbI(3) perovskite films to the desired pure alpha-phase. NMR quantifies MA incorporation into the framework. Molecular dynamics simulations show that SCN- anions promote the formation and stabilization of alpha-FAPbI(3) below the thermodynamic phase-transition temperature. We used these low-defect-density alpha-FAPbI(3) films to make PSCs with >23% power-conversion efficiency and long-term operational and thermal stability, as well as a low (330 millivolts) open-circuit voltage loss and a low (0.75 volt) turn-on voltage of electroluminescence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 636, "Times Cited, All Databases": 660, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2020, "Volume": 370, "Issue": 6512, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 74, "End Page": "+", "Article Number": "eabb8985", "DOI": "10.1126/science.abb8985", "DOI Link": "http://dx.doi.org/10.1126/science.abb8985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579169000046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Wu, D; Zhu, YH; Cho, YJ; He, Q; Yang, X; Herrera, K; Chu, ZD; Han, Y; Downer, MC; Peng, HL; Lai, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yu; Wu, Di; Zhu, Yihan; Cho, Yujin; He, Qing; Yang, Xiao; Herrera, Kevin; Chu, Zhaodong; Han, Yu; Downer, Michael C.; Peng, Hailin; Lai, Keji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Out-of-Plane Piezoelectricity and Ferroelectricity in Layered α-In2Se3 nulloflakes", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric and ferroelectric properties in the two-dimensional (2D) limit are highly desired for nulloelectronic, electromechanical, and optoelectronic applications. Here we report the first experimental evidence of out-of-plane piezoelectricity and ferroelectricity in van der Waals layered alpha-In2Se3 nulloflakes. The noncentrosymmetric R3m symmetry of the alpha-In2Se3 samples is confirmed by scanning transmission electron microscopy, second-harmonic generation, and Raman spectroscopy measurements. Domains with opposite polarizations are visualized by piezo-response force microscopy. Single-point poling experiments suggest that the polarization is potentially switchable for alpha-In2Se3 nulloflakes with thicknesses down to similar to 10 nm. The piezotronic effect is demonstrated in two-terminal devices, where the Schottky barrier can be modulated by the strain-induced piezopotential. Our work on polar alpha-In2Se3, one of the model 2D piezoelectrics and ferroelectrics with simple crystal structures, shows its great potential in electronic and photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 698, "Times Cited, All Databases": 718, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 17, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5508, "End Page": 5513, "Article Number": null, "DOI": "10.1021/acs.nullolett.7b02198", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.7b02198", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411043500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, KN; Zhang, SS; Li, YH; Fan, JJ; Lv, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Kaining; Zhang, Sushu; Li, Yuhan; Fan, Jiajie; Lv, Kangle", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXenes as noble-metal-alternative co-catalysts in photocatalysis", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalysis has become a focal point in research as a clean and sustainable technology with the potential to solve environmental problems and energy crises. The loading of noble-metal co-catalysts can substantially improve the photocatalytic efficiency of semiconductors. Because the high cost and scarcity of noble metals markedly limit their large-scale applications, finding a noble-metal-alternative co-catalyst is crucial. MXene, a novel 2D transition metal material, has attracted considerable attention as a promising substitute for noble metal co-catalysts owing to its cost-efficiency, unique 2D layered structure, and excellent electrical, optical, and thermodynamic properties. This review focuses on the latest advancements in research on MXenes as co-catalysts in relatively popular photocatalytic applications (hydrogen production, CO2 reduction, nitrogen fixation, and organic pollutant oxidation). The synthesis methods and photocatalytic mechanisms of MXenes as co-catalysts are also summarized according to the type of MXene-based material. Finally, the crucial opportunities and challenges in the prospective development of MXene-based photocatalysts are outlined. We emphasize that modern techniques should be used to demonstrate the effects of MXenes on photocatalysis and that the photocatalytic activity of MXene-based photocatalysts can be further improved using defective engineering and recent phenomena such as the localized surface plasmon resonullce effect and single-atom catalysis. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 3, "End Page": 14, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63630-0", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63630-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, XH; Shi, QR; Zhu, WL; Liu, D; Tian, HY; Fu, SF; Cheng, N; Li, SQ; Smith, JN; Du, D; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Xiangheng; Shi, Qiurong; Zhu, Wenlei; Liu, Dong; Tian, Hangyu; Fu, Shaofang; Cheng, null; Li, Suiqiong; Smith, Jordan N.; Du, Dan; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unprecedented peroxidase-mimicking activity of single-atom nullozyme with atomically dispersed Fe-Nx moieties hosted by MOF derived porous carbon", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to robustness, easy large-scale preparation and low cost, nullomaterials with enzyme-like characteristics (defined as 'nullozymes') are attracting increasing interest for various applications. However, most of currently developed nullozymes show much lower activity in comparison with natural enzymes, and the deficiency greatly hinders their use in sensing and biomedicine. Single-atom catalysts (SACs) offer the unique feature of maximum atomic utilization, providing a potential pathway to improve the catalytic activity of nullozymes. Herein, we propose a Fe-N-C single-atom nullozyme (SAN) that exhibits unprecedented peroxidase-mimicking activity. The SAN consists of atomically dispersed Fe-N-x moieties hosted by metal-organic frameworks (MOF) derived porous carbon. Thanks to the 100% single-atom active Fe dispersion and the large surface area of the porous support, the Fe-N-C SAN provided a specific activity of 57.76 U mg(-1), which was almost at the same level as natural horseradish peroxidase (HRP). Attractively, the SAN presented much better storage stability and robustness against harsh environments. As a proof-of-concept application, highly sensitive biosensing of butyrylcholinesterase (BChE) activity using the Fe-N-C SAN as a substitute for natural HRP was further verified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 142, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111495, "DOI": "10.1016/j.bios.2019.111495", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2019.111495", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487175000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hanlon, D; Backes, C; Doherty, E; Cucinotta, CS; Berner, NC; Boland, C; Lee, K; Harvey, A; Lynch, P; Gholamvand, Z; Zhang, SF; Wang, KP; Moynihan, G; Pokle, A; Ramasse, QM; McEvoy, N; Blau, WJ; Wang, J; Abellan, G; Hauke, F; Hirsch, A; Sanvito, S; O'Regan, DD; Duesberg, GS; Nicolosi, V; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hanlon, Damien; Backes, Claudia; Doherty, Evie; Cucinotta, Clotilde S.; Berner, Nina C.; Boland, Conor; Lee, Kangho; Harvey, Andrew; Lynch, Peter; Gholamvand, Zahra; Zhang, Saifeng; Wang, Kangpeng; Moynihan, Glenn; Pokle, Anuj; Ramasse, Quentin M.; McEvoy, Niall; Blau, Werner J.; Wang, Jun; Abellan, Gonzalo; Hauke, Frank; Hirsch, Andreas; Sanvito, Stefano; O'Regan, David D.; Duesberg, Georg S.; Nicolosi, Valeria; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer black phosphorus (BP) is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of environmental stability severely limits its synthesis and processing. Here we demonstrate that high-quality, few-layer BP nullosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase exfoliation under ambient conditions in solvents such as N-cyclohexyl-2-pyrrolidone (CHP). nullosheets are surprisingly stable in CHP, probably due to the solvation shell protecting the nullosheets from reacting with water or oxygen. Experiments, supported by simulations, show reactions to occur only at the nullosheet edge, with the rate and extent of the reaction dependent on the water/oxygen content. We demonstrate that liquid-exfoliated BP nullosheets are potentially useful in a range of applications from ultrafast saturable absorbers to gas sensors to fillers for composite reinforcement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 954, "Times Cited, All Databases": 1016, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8563, "DOI": "10.1038/ncomms9563", "DOI Link": "http://dx.doi.org/10.1038/ncomms9563", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364932600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Lang, Q; Yildirimer, L; Lin, ZY; Cui, WG; Annabi, N; Ng, KW; Dokmeci, MR; Ghaemmaghami, AM; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin; Lang, Qi; Yildirimer, Lara; Lin, Zhi Yuan; Cui, Wenguo; Annabi, Nasim; Ng, Kee Woei; Dokmeci, Mehmet R.; Ghaemmaghami, Amir M.; Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocrosslinkable Gelatin Hydrogel for Epidermal Tissue Engineering", "Source Title": "ADVANCED HEALTHCARE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural hydrogels are promising scaffolds to engineer epidermis. Currently, natural hydrogels used to support epidermal regeneration are mainly collagen-or gelatin-based, which mimic the natural dermal extracellular matrix but often suffer from insufficient and uncontrollable mechanical and degradation properties. In this study, a photocrosslinkable gelatin (i.e., gelatin methacrylamide (GelMA)) with tunable mechanical, degradation, and biological properties is used to engineer the epidermis for skin tissue engineering applications. The results reveal that the mechanical and degradation properties of the developed hydrogels can be readily modified by varying the hydrogel concentration, with elastic and compressive moduli tuned from a few kPa to a few hundred kPa, and the degradation times varied from a few days to several months. Additionally, hydrogels of all concentrations displayed excellent cell viability (>90%) with increasing cell adhesion and proliferation corresponding to increases in hydrogel concentrations. Furthermore, the hydrogels are found to support keratinocyte growth, differentiation, and stratification into a reconstructed multilayered epidermis with adequate barrier functions. The robust and tunable properties of GelMA hydrogels suggest that the keratinocyte laden hydrogels can be used as epidermal substitutes, wound dressings, or substrates to construct various in vitro skin models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 717, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 108, "End Page": 118, "Article Number": null, "DOI": "10.1002/adhm.201500005", "DOI Link": "http://dx.doi.org/10.1002/adhm.201500005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368144200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Tuo, YX; Lu, Q; Lu, H; Zhang, SY; Zhou, Y; Zhang, J; Liu, ZN; Kang, ZX; Feng, X; Chen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chen; Tuo, Yongxiao; Lu, Qing; Lu, Han; Zhang, Shengyang; Zhou, Yan; Zhang, Jun; Liu, Zhanning; Kang, Zixi; Feng, Xiang; Chen, De", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical trimetallic Co-Ni-Fe oxides derived from core-shell structured metal-organic frameworks for highly efficient oxygen evolution reaction", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) have recently emerged as promising precursors to construct efficient nonnoble metal electrocatalyst for oxygen evolution reaction (OER). Herein, a Co-Ni-Fe spinet oxide-carbonitrides hybrids (CoNiFeOx-NC) electrocatalyst with hierarchical structure was synthesized from Fe-MIL-101-NH2 through a unique ion-exchange based strategy. The ion exchange of Fe-MIL-101-NH2 with both Ni and Co ions induced a hierarchically structured 2-D ternary metal MOF shell layer encapsulated 3-D octahedral MOF crystals as a core. This prevents the collapse of MOF frameworks during the air calcination process and affords highly porous structure and large surface area. Additionally, the unique combination of Co-Ni-Fe in spinet oxides derived from calcination of the hierarchically structured core-shell MOF provides a favorable electronic environment for the adsorption of OER intermediates, which was further verified by the XPS characterizations and DFT calculations. DFT study revealed the Ni-Co coordinated O-h sites in the MFe2O4 reverse spinet structures as the main active sites, which tuned the binding strength of oxygen species with a catalyst through electron transfer of Fe -> Co -> Ni, thereby lowered the energy barriers for OER. As a result, the rationally designed CoNiFeOx-NC catalyst manifests superior OER performance with a low overpotential of 265 mV at 50 mA cm(-2) and a decent Tafel slope of 64.1 mV dec(-1). The ion-exchange based strategy may serve as a versatile platform for rational design and synthesis of multi-metallic MOF derived electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 287, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119953, "DOI": "10.1016/j.apcatb.2021.119953", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2021.119953", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627553300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SJ; Koh, HJ; Ren, CE; Kwon, O; Maleski, K; Cho, SY; Anasori, B; Kim, CK; Choi, YK; Kim, J; Gogotsi, Y; Jung, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Seon Joon; Koh, Hyeong-Jun; Ren, Chang E.; Kwon, Ohmin; Maleski, Kathleen; Cho, Soo-Yeon; Anasori, Babak; Kim, Choong-Ki; Choi, Yang-Kyu; Kim, Jihan; Gogotsi, Yury; Jung, Hee-Tae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic Ti3C2TX MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving high sensitivity in solid-state gas sensors can allow the precise detection of chemical agents. In particular, detection of volatile organic compounds (VOCs) at the parts per billion (ppb) level is critical for the early diagnosis of diseases. To obtain high sensitivity, two requirements need to be simultaneously satisfied: (i) low electrical noise and (ii) strong signal, which existing sensor materials cannot meet. Here, we demonstrate that 2D metal carbide MXenes, which possess high metallic conductivity for low noise and a fully functionalized surface for a strong signal, greatly outperform the sensitivity of conventional semiconductor channel materials. Ti3C2Tx MXene gas sensors exhibited a very low limit of detection of 50-100 ppb for VOC gases at room temperature. Also, the extremely low noise led to a signal-to-noise ratio 2 orders of magnitude higher than that of other 2D materials, surpassing the best sensors known. Our results provide insight in utilizing highly functionalized metallic sensing channels for developing highly sensitive sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1286, "Times Cited, All Databases": 1349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 986, "End Page": 993, "Article Number": null, "DOI": "10.1021/acsnullo.7b07460", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b07460", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426615600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, BJ; Zhang, J; Zhong, Q; Li, WB; Li, S; Li, H; Cheng, P; Meng, S; Chen, L; Wu, KH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Baojie; Zhang, Jin; Zhong, Qing; Li, Wenbin; Li, Shuai; Li, Hui; Cheng, Peng; Meng, Sheng; Chen, Lan; Wu, Kehui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental realization of two-dimensional boron sheets", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of two-dimensional materials have been reported in recent years, yet single-element systems such as graphene and black phosphorus have remained rare. Boron analogues have been predicted, as boron atoms possess a short covalent radius and the flexibility to adopt sp(2) hybridization, features that favour the formation of two-dimensional allotropes, and one example of such a borophene material has been reported recently. Here, we present a parallel experimental work showing that two-dimensional boron sheets can be grown epitaxially on a Ag(111) substrate. Two types of boron sheet, a beta(12) sheet and a chi(3) sheet, both exhibiting a triangular lattice but with different arrangements of periodic holes, are observed by scanning tunnelling microscopy. Density functional theory simulations agree well with experiments, and indicate that both sheets are planar without obvious vertical undulations. The boron sheets are quite inert to oxidization and interact only weakly with their substrate. We envisage that such boron sheets may find applications in electronic devices in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1511, "Times Cited, All Databases": 1584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 564, "End Page": 569, "Article Number": null, "DOI": "10.1038/NCHEM.2491", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376529000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Wang, SY; Wang, TS; Yang, SZ; Johannessen, B; Chen, H; Liu, CW; Ye, YS; Wu, YC; Peng, YC; Liu, C; Jiang, SP; Zhang, QF; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Wang, Shiyong; Wang, Tianshuai; Yang, Shi-Ze; Johannessen, Bernt; Chen, Hao; Liu, Chenwei; Ye, Yusheng; Wu, Yecun; Peng, Yucan; Liu, Chang; Jiang, San Ping; Zhang, Qianfan; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theoretical Calculation Guided Design of Single-Atom Catalysts toward Fast Kinetic and Long-Life Li-S Batteries", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries are promising next-generation energy storage technologies due to their high theoretical energy density, environmental friendliness, and low cost. However, low conductivity of sulfur species, dissolution of polysulfides, poor conversion from sulfur reduction, and lithium sulfide (Li2S) oxidation reactions during discharge-charge processes hinder their practical applications. Herein, under the guidance of density functional theory calculations, we have successfully synthesized large-scale single atom vanadium catalysts seeded on graphene to achieve high sulfur content (80 wt % sulfur), fast kinetic (a capacity of 645 mAh g(-1) at 3 C rate), and long-life Li-S batteries. Both forward (sulfur reduction) and reverse reactions (Li2S oxidation) are significantly improved by the single atom catalysts. This finding is confirmed by experimental results and consistent with theoretical calculations. The ability of single metal atoms to effectively trap the dissolved lithium polysulfides (LiPSs) and catalytically convert the LiPSs/Li2S during cycling significantly improved sulfur utilization, rate capability, and cycling life. Our work demonstrates an efficient design pathway for single atom catalysts and provides solutions for the development of high energy/power density Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 463, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1252, "End Page": 1261, "Article Number": null, "DOI": "10.1021/acs.nullolett.9b04719", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.9b04719", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514255400054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, CC; Li, JX; Zhang, MH; Zhang, YH; Yang, F; Lee, JZ; Lee, MH; Alvarado, J; Schroeder, MA; Yang, YYC; Lu, BY; Williams, N; Ceja, M; Yang, L; Cai, M; Gu, J; Xu, K; Wang, XF; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Chengcheng; Li, Jinxing; Zhang, Minghao; Zhang, Yihui; Yang, Fan; Lee, Jungwoo Z.; Lee, Min-Han; Alvarado, Judith; Schroeder, Marshall A.; Yang, Yangyuchen; Lu, Bingyu; Williams, Nicholas; Ceja, Miguel; Yang, Li; Cai, Mei; Gu, Jing; Xu, Kang; Wang, Xuefeng; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying inactive lithium in lithium metal batteries", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal anodes offer high theoretical capacities (3,860 milliampere-hours per gram)(1), but rechargeable batteries built with such anodes suffer from dendrite growth and low Coulombic efficiency (the ratio of charge output to charge input), preventing their commercial adoption(2,3). The formation of inactive ('dead') lithium- which consists of both (electro)chemically formed Li+ compounds in the solid electrolyte interphase and electrically isolated unreacted metallic Li-0 (refs(4,5))-causes capacity loss and safety hazards. Quantitatively distinguishing between Li+ in components of the solid electrolyte interphase and unreacted metallic Li-0 has not been possible, owing to the lack of effective diagnostic tools. Optical microscopy(6), in situ environmental transmission electron microscopy(7,8), X-ray microtomography(9) and magnetic resonullce imaging(10) provide a morphological perspective with little chemical information. Nuclear magnetic resonullce(11), X-ray photoelectron spectroscopy(12) and cryogenic transmission electron microscopy(13,14) can distinguish between Li+ in the solid electrolyte interphase and metallic Li-0, but their detection ranges are limited to surfaces or local regions. Here we establish the analytical method of titration gas chromatography to quantify the contribution of unreacted metallic Li-0 to the total amount of inactive lithium. We identify the unreacted metallic Li-0, not the (electro)chemically formed Li+ in the solid electrolyte interphase, as the dominullt source of inactive lithium and capacity loss. By coupling the unreacted metallic Li-0 content to observations of its local microstructure and nullostructure by cryogenic electron microscopy (both scanning and transmission), we also establish the formation mechanism of inactive lithium in different types of electrolytes and determine the underlying cause of low Coulombic efficiency in plating and stripping (the charge and discharge processes, respectively, in a full cell) of lithium metal anodes. We propose strategies for making lithium plating and stripping more efficient so that lithium metal anodes can be used for next-generation high-energy batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 817, "Times Cited, All Databases": 903, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2019, "Volume": 572, "Issue": 7770, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1481-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1481-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482219600042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, JP; Wang, YX; Li, W; Wang, LJ; Fan, YC; Jiang, W; Luo, W; Wang, Y; Kong, B; Selomulya, C; Liu, HK; Dou, SX; Zhao, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jianping; Wang, Yunxiao; Li, Wei; Wang, Lianjun; Fan, Yuchi; Jiang, Wan; Luo, Wei; Wang, Yang; Kong, Biao; Selomulya, Cordelia; Liu, Hua Kun; Dou, Shi Xue; Zhao, Dongyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous TiO2 Shells: A Vital Elastic Buffering Layer on Silicon nulloparticles for High-Performance and Safe Lithium Storage", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Smart surface coatings of silicon (Si) nulloparticles are shown to be good examples for dramatically improving the cyclability of lithium-ion batteries. Most coating materials, however, face significant challenges, including a low initial Coulombic efficiency, tedious processing, and safety assessment. In this study, a facile sol-gel strategy is demonstrated to synthesize commercial Si nulloparticles encapsulated by amorphous titanium oxide (TiO2), with core-shell structures, which show greatly superior electrochemical performance and high-safety lithium storage. The amorphous TiO2 shell (approximate to 3 nm) shows elastic behavior during lithium discharging and charging processes, maintaining high structural integrity. Interestingly, it is found that the amorphous TiO2 shells offer superior buffering properties compared to crystalline TiO2 layers for unprecedented cycling stability. Moreover, accelerating rate calorimetry testing reveals that the TiO2-encapsulated Si nulloparticles are safer than conventional carbon-coated Si-based anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 435, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2017, "Volume": 29, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700523, "DOI": "10.1002/adma.201700523", "DOI Link": "http://dx.doi.org/10.1002/adma.201700523", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418272000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, J; Zhou, GM; Yan, K; Xie, J; Li, YZ; Liao, L; Jin, Y; Liu, K; Hsu, PC; Wang, JY; Cheng, HM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jie; Zhou, Guangmin; Yan, Kai; Xie, Jin; Li, Yuzhang; Liao, Lei; Jin, Yang; Liu, Kai; Hsu, Po-Chun; Wang, Jiangyan; Cheng, Hui-Ming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-capacity anodes is a must to improve the energy density of lithium batteries for electric vehicle applications. Alloy anodes are one promising option, but without pre-stored lithium, the overall energy density is limited by the low-capacity lithium metal oxide cathodes. Recently, lithium metal has been revived as a high-capacity anode, but faces several challenges owing to its high reactivity and uncontrolled dendrite growth. Here, we show a series of Li-containing foils inheriting the desirable properties of alloy anodes and pure metal anodes. They consist of densely packed LixM (M= Si, Sn, or Al) nulloparticles encapsulated by large graphene sheets. With the protection of graphene sheets, the large and freestanding LixM/graphene foils are stable in different air conditions. With fully expanded LixSi confined in the highly conductive and chemically stable graphene matrix, this LixSi/graphene foil maintains a stable structure and cyclability in half cells (400 cycles with 98% capacity retention). This foil is also paired with high-capacity Li-free V2O5 and sulfur cathodes to achieve stable full-cell cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 12, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 993, "End Page": 999, "Article Number": null, "DOI": "10.1038/NnullO.2017.129", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2017.129", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412432500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, SM; Dong, YS; Liu, B; Liu, J; Liu, SK; Zhao, ZY; Li, WT; Tian, BS; Zhao, RX; He, F; Gai, SL; Xie, Y; Yang, PP; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Shuming; Dong, Yushan; Liu, Bin; Liu, Jing; Liu, Shikai; Zhao, Zhiyu; Li, Wenting; Tian, Boshi; Zhao, Ruoxi; He, Fei; Gai, Shili; Xie, Ying; Yang, Piaoping; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Guiding Transition Metal-Doped Hollow Cerium Tandem nullozymes with Elaborately Regulated Multi-Enzymatic Activities for Intensive Chemodynamic Therapy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Clinical applications of nullozyme-initiated chemodynamic therapy (NCDT) have been severely limited by the poor catalytic efficiency of nullozymes, insufficient endogenous hydrogen peroxide (H2O2) content, and its off-target consumption. Herein, the authors developed a hollow mesoporous Mn/Zr-co-doped CeO2 tandem nullozyme (PHMZCO-AT) with regulated multi-enzymatic activities, that is, the enhancement of superoxide dismutase (SOD)-like and peroxidase (POD)-like activities and inhibition of catalase (CAT)-like activity. PHMZCO-AT as a H2O2 homeostasis disruptor promotes H2O2 evolution and restrains off-target elimination of H2O2 to achieve intensive NCDT. PHMZCO-AT with SOD-like activity catalyzes endogenous superoxide anion (O-2(center dot-)) into H2O2 in the tumor region. The suppression of CAT activity and depletion of glutathione by PHMZCO-AT largely weaken the off-target decomposition of H2O2 to H2O. Elevated H2O2 is then catalyzed by the downstream POD-like activity of PHMZCO-AT to generate toxic hydroxyl radicals, further inducing tumor apoptosis and death. T-1-weighted magnetic resonullce imaging and X-ray computed tomography imaging are also achieved using PHMZCO-AT due to the existence of paramagnetic Mn2+ and the high X-ray attenuation ability of elemental Zr, permitting in vivo tracking of the therapeutic process. This work presents a typical paradigm to achieve intensive NCDT efficacy by regulating multi-enzymatic activities of nullozymes to perturb the H2O2 homeostasis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 34, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2107054, "DOI": "10.1002/adma.202107054", "DOI Link": "http://dx.doi.org/10.1002/adma.202107054", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740636900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, DG; Park, EJ; Zhu, WL; Shi, QR; Zhou, Y; Tian, HY; Lin, YH; Serov, A; Zulevi, B; Baca, ED; Fujimoto, C; Chung, HT; Kim, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dongguo; Park, Eun Joo; Zhu, Wenlei; Shi, Qiurong; Zhou, Yang; Tian, Hangyu; Lin, Yuehe; Serov, Alexey; Zulevi, Barr; Baca, Ehren Donel; Fujimoto, Cy; Chung, Hoon T.; Kim, Yu Seung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly quaternized polystyrene ionomers for high performance anion exchange membrane water electrolysers", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkaline anion exchange membrane (AEM) electrolysers to produce hydrogen from water are still at an early stage of development, and their performance is far lower than that of systems based on proton exchange membranes. Here, we report an ammonium-enriched anion exchange ionomer that improves the performance of an AEM electrolyser to levels approaching that of state-of-the-art proton exchange membrane electrolysers. Using rotating-disk electrode experiments, we show that a high pH (>13) in the electrode binder is the critical factor for improving the activity of the hydrogen- and oxygen-evolution reactions in AEM electrolysers. Based on this observation, we prepared and tested several quaternized polystyrene electrode binders in an AEM electrolyser. Using the binder with the highest ionic concentration and a NiFe oxygen evolution catalyst, we demonstrated performance of 2.7 A cm(-2) at 1.8 V without a corrosive circulating alkaline solution. The limited durability of the AEM electrolyser remains a challenge to be addressed in the future. Anion exchange membrane water electrolysers have potential cost advantages over proton exchange membrane electrolysers, but their performance has lagged behind. Here the authors investigate the cause of the poor performance of anion exchange membrane electrolysers and design ionomers that can overcome some of the challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 385, "Article Number": null, "DOI": "10.1038/s41560-020-0577-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0577-x", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518736900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mak, KF; McGill, KL; Park, J; McEuen, PL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mak, K. F.; McGill, K. L.; Park, J.; McEuen, P. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The valley Hall effect in MoS2 transistors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrons in two-dimensional crystals with a honeycomb lattice structure possess a valley degree of freedom (DOF) in addition to charge and spin. These systems are predicted to exhibit an anomalous Hall effect whose sign depends on the valley index. Here, we report the observation of this so-called valley Hall effect (VHE). Monolayer MoS2 transistors are illuminated with circularly polarized light, which preferentially excites electrons into a specific valley, causing a finite anomalous Hall voltage whose sign is controlled by the helicity of the light. No anomalous Hall effect is observed in bilayer devices, which have crystal inversion symmetry. Our observation of the VHE opens up new possibilities for using the valley DOF as an information carrier in next-generation electronics and optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1600, "Times Cited, All Databases": 1802, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2014, "Volume": 344, "Issue": 6191, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1489, "End Page": 1492, "Article Number": null, "DOI": "10.1126/science.1250140", "DOI Link": "http://dx.doi.org/10.1126/science.1250140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337889900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, SY; Belopolski, I; Alidoust, N; Neupane, M; Bian, G; Zhang, CL; Sankar, R; Chang, GQ; Yuan, ZJ; Lee, CC; Huang, SM; Zheng, H; Ma, J; Sanchez, DS; Wang, BK; Bansil, A; Chou, FC; Shibayev, PP; Lin, H; Jia, S; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Su-Yang; Belopolski, Ilya; Alidoust, Nasser; Neupane, Madhab; Bian, Guang; Zhang, Chenglong; Sankar, Raman; Chang, Guoqing; Yuan, Zhujun; Lee, Chi-Cheng; Huang, Shin-Ming; Zheng, Hao; Ma, Jie; Sanchez, Daniel S.; Wang, BaoKai; Bansil, Arun; Chou, Fangcheng; Shibayev, Pavel P.; Lin, Hsin; Jia, Shuang; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of a Weyl fermion semimetal and topological Fermi arcs", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Weyl semimetal is a new state of matter that hosts Weyl fermions as emergent quasiparticles and admits a topological classification that protects Fermi arc surface states on the boundary of a bulk sample. This unusual electronic structure has deep analogies with particle physics and leads to unique topological properties. We report the experimental discovery of a Weyl semimetal, tantalum arsenide (TaAs). Using photoemission spectroscopy, we directly observe Fermi arcs on the surface, as well as the Weyl fermion cones and Weyl nodes in the bulk of TaAs single crystals. We find that Fermi arcs terminate on the Weyl fermion nodes, consistent with their topological character. Our work opens the field for the experimental study of Weyl fermions in physics and materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2782, "Times Cited, All Databases": 2968, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2015, "Volume": 349, "Issue": 6248, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 613, "End Page": 617, "Article Number": null, "DOI": "10.1126/science.aaa9297", "DOI Link": "http://dx.doi.org/10.1126/science.aaa9297", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359092900034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Li, B; Li, XL; Zeng, XH; Zhang, SL; Yang, FH; Liu, SL; Li, D; Wu, C; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Li, Bo; Li, Xiaolong; Zeng, Xiaohui; Zhang, Shilin; Yang, Fuhua; Liu, Sailin; Li, Dan; Wu, Chao; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An In-Depth Study of Zn Metal Surface Chemistry for Advanced Aqueous Zn-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although Zn metal has been regarded as the most promising anode for aqueous batteries, it persistently suffers from serious side reactions and dendrite growth in mild electrolyte. Spontaneous Zn corrosion and hydrogen evolution damage the shelf life and calendar life of Zn-based batteries, severely affecting their industrial applications. Herein, a robust and homogeneous ZnS interphase is built in situ on the Zn surface by a vapor-solid strategy to enhance Zn reversibility. The thickness of the ZnS film is controlled via the treatment temperature, and the performance of the protected Zn electrode is optimized. The dense ZnS artificial layer obtained at 350 degrees C not only suppresses Zn corrosion by forming a physical barrier on the Zn surface, but also inhibits dendrite growth via guiding the Zn plating/stripping underneath the artificial layer. Accordingly, a side reaction-free and dendrite-free Zn electrode is developed, the effectiveness of which is also convincing in a MnO2/ZnS@Zn full-cell with 87.6% capacity retention after 2500 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 901, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 32, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003021, "DOI": "10.1002/adma.202003021", "DOI Link": "http://dx.doi.org/10.1002/adma.202003021", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546717000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, J; Tang, MX; Hu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jin; Tang, Mingxue; Hu, Yan-Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium Ion Pathway within Li7La3Zr2O12-Polyethylene Oxide Composite Electrolytes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-ceramic composite electrolytes are emerging as a promising solution to deliver high ionic conductivity, optimal mechanical properties, and good safety for developing high-performance all-solid-state rechargeable batteries. Composite electrolytes have been prepared with cubic-phase Li7La3Zr2O12 (LLZO) garnet and polyethylene oxide (PEO) and employed in symmetric lithium battery cells. By combining selective isotope labeling and high-resolution solid-state Li NMR, we are able to track Li ion pathways within LLZO-PEO composite electrolytes by monitoring the replacement of Li-7 in the composite electrolyte by Li-6 from the Li-6 metal electrodes during battery cycling. We have provided the first experimental evidence to show that Li ions favor the pathway through the LLZO ceramic phase instead of the PEO-LLZO interface or PEO. This approach can be widely applied to study ion pathways in ionic conductors and to provide useful insights for developing composite materials for energy storage and harvesting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 563, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2016, "Volume": 55, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12538, "End Page": 12542, "Article Number": null, "DOI": "10.1002/anie.201607539", "DOI Link": "http://dx.doi.org/10.1002/anie.201607539", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389050400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, TL; Li, J; Li, HY; Tian, CC; Su, J; Tong, GQ; Ono, LK; Wang, C; Lin, ZP; Chai, NAY; Zhang, XL; Chang, JJ; Lu, JF; Zhong, J; Huang, WC; Qi, YB; Cheng, YB; Huang, FZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Tongle; Li, Jing; Li, Hengyi; Tian, Congcong; Su, Jie; Tong, Guoqing; Ono, Luis K.; Wang, Chao; Lin, Zhipeng; Chai, Nianyao; Zhang, Xiao-Li; Chang, Jingjing; Lu, Jianfeng; Zhong, Jie; Huang, Wenchao; Qi, Yabing; Cheng, Yi-Bing; Huang, Fuzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead halide-templated crystallization of methylamine-free perovskite for efficient photovoltaic modules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Upscaling efficient and stable perovskite layers is one of the most challenging issues in the commercialization of perovskite solar cells. Here, a lead halide-templated crystallization strategy is developed for printing formamidinium (FA)-cesium (Cs) lead triiodide perovskite films. High-quality large-area films are achieved through controlled nucleation and growth of a lead halide_N-methyl-2-pyrrolidone adduct that can react in situ with embedded FAI/CsI to directly form alpha-phase perovskite, sidestepping the phase transformation from delta-phase. A nonencapsulated device with 23% efficiency and excellent long-term thermal stability (at 85 degrees C) in ambient air (similar to 80% efficiency retention after 500 hours) is achieved with further addition of potassium hexafluorophosphate. The slot die-printed minimodules achieve champion efficiencies of 20.42% (certified efficiency 19.3%) and 19.54% with an active area of 17.1 and 65.0 square centimeters, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2021, "Volume": 372, "Issue": 6548, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1327, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh1035", "DOI Link": "http://dx.doi.org/10.1126/science.abh1035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665616000032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, SH; Li, XH; Li, J; Wei, BQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Shaohui; Li, Xuanhua; Li, Ju; Wei, Bingqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting photocatalytic hydrogen production from water by photothermally induced biphase systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven hydrogen production from water using particulate photocatalysts is considered the most economical and effective approach to produce hydrogen fuel with little environmental concern. However, the efficiency of hydrogen production from water in particulate photocatalysis systems is still low. Here, we propose an efficient biphase photocatalytic system composed of integrated photothermal-photocatalytic materials that use charred wood substrates to convert liquid water to water steam, simultaneously splitting hydrogen under light illumination without additional energy. The photothermal-photocatalytic system exhibits biphase interfaces of photothermally-generated steam/photocatalyst/hydrogen, which significantly reduce the interface barrier and drastically lower the transport resistance of the hydrogen gas by nearly two orders of magnitude. In this work, an impressive hydrogen production rate up to 220.74 mu molh(-1)cm(-2) in the particulate photocatalytic systems has been achieved based on the wood/CoO system, demonstrating that the photothermal-photocatalytic biphase system is cost-effective and greatly advantageous for practical applications. The solar-driven H-2 production from water by particulate photocatalysts is an effective approach to produce H-2 fuel. Here, the authors propose an integrated photothermal-photocatalytic biphase system, which lowers the reaction barrier and the delivery resistance of the H-2, boosting the catalytic H-2 evolution rate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1343, "DOI": "10.1038/s41467-021-21526-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21526-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000624979400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mredha, MTI; Guo, YZ; Nonoyama, T; Nakajima, T; Kurokawa, T; Gong, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mredha, Md. Tariful Islam; Guo, Yun Zhou; Nonoyama, Takayuki; Nakajima, Tasuku; Kurokawa, Takayuki; Gong, Jian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Facile Method to Fabricate Anisotropic Hydrogels with Perfectly Aligned Hierarchical Fibrous Structures", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural structural materials (such as tendons and ligaments) are comprised of multiscale hierarchical architectures, with dimensions ranging from nullo- to macroscale, which are difficult to mimic synthetically. Here a bioinspired, facile method to fabricate anisotropic hydrogels with perfectly aligned multiscale hierarchical fibrous structures similar to those of tendons and ligaments is reported. The method includes drying a diluted physical hydrogel in air by confining its length direction. During this process, sufficiently high tensile stress is built along the length direction to align the polymer chains and multiscale fibrous structures (from nullo- to submicro- to microscale) are spontaneously formed in the bulk material, which are well-retained in the reswollen gel. The method is useful for relatively rigid polymers (such as alginate and cellulose), which are susceptible to mechanical signal. By controlling the drying with or without prestretching, the degree of alignment, size of superstructures, and the strength of supramolecular interactions can be tuned, which sensitively influence the strength and toughness of the hydrogels. The mechanical properties are comparable with those of natural ligaments. This study provides a general strategy for designing hydrogels with highly ordered hierarchical structures, which opens routes for the development of many functional biomimetic materials for biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 30, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1704937, "DOI": "10.1002/adma.201704937", "DOI Link": "http://dx.doi.org/10.1002/adma.201704937", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426491600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karaolia, P; Michael-Kordatou, I; Hapeshi, E; Drosou, C; Bertakis, Y; Christofilos, D; Armatas, GS; Sygellou, L; Schwartz, T; Xekoukoulotakis, NP; Fatta-Kassinos, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karaolia, Popi; Michael-Kordatou, Irene; Hapeshi, Evroula; Drosou, Catherine; Bertakis, Yannis; Christofilos, Dimitris; Armatas, Gerasimos S.; Sygellou, Labrini; Schwartz, Thomas; Xekoukoulotakis, Nikolaos P.; Fatta-Kassinos, Despo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Removal of antibiotics, antibiotic-resistant bacteria and their associated genes by graphene-based TiO2 composite photocatalysts under solar radiation in urban wastewaters", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present work investigated: (i) the removal of the antibiotics sulfamethoxazole (SMX), erythromycin (ERY) and clarithromycin (CIA); (ii) the inactivation of the total and antibiotic-resistant E. coil along with their regrowth potential after treatment; (iii) the removal of the total genomic DNA content; and (iv) the removal of selected antibiotic resistance genes (ARGs), namely sell, ampC, ermB, mecA, as well as species-specific sequences, namely ecfX for Pseudomonas aeruginosa and enterococci-specific 23S rRNA, by graphene-based TiO2 composite photocatalysts under solar radiation, in real urban wastewaters. TiO2-reduced graphene oxide (TiO2-rGO) composite photocatalysts were synthesized by two ex-situ synthesis methods, namely hydrothermal (HD) treatment and photocatalytic (PH) treatment, starting from graphene oxide and Aeroxide P25 TiO2, and were characterized with various techniques, such as XRD, FT-IR, Raman, XPS, SEM and surface area (BET) analyses. The potential of the synthesized TiO2-rGO composites for the removal of the above mentioned antibiotic-related microcontaminullts was compared to the efficiency shown by pristine Aeroxide P25 TiO2 under simulated solar radiation, in real urban wastewater effluents treated by a membrane bioreactor. The results showed that TiO2-rGO-PH was more efficient in the photocatalytic degradation of ERY (84 +/- 2%) and CIA (86 +/- 5%), while degradation of SMX (87 +/- 4%) was found to be slightly higher with Aeroxide P25 TiO2. It was also demonstrated that more than 180 min of treatment were satisfactory for the complete inactivation and complete absence of post-treatment regrowth of E. colt bacteria (< LOD) even 24 h after the end of the treatment, for all examined photocatalytic materials. The least amount of regrowth at all experimental times was observed in the presence of TiO2-rGO-HD. Moreover, the synthesized graphene-based photocatalysts successfully removed ampC and significantly reduced ecfX abundance of Pseudomonas aeruginosa, but sell, ermB and 23S rRNA for enterococci sequences were found to be persistent throughout treatment with all catalyst types. Finally, the total DNA concentration remained stable throughout the photocatalytic treatment (4.2-4.8 ng mu L-1), indicating the high total genomic DNA stability in treated wastewater and its resistance to photocatalytic treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 224, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 810, "End Page": 824, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.11.020", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.11.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424960700084", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, TC; Cai, XH; Tu, MWY; Zhang, XO; Huang, BV; Wilson, NP; Seyler, KL; Zhu, L; Taniguchi, T; Watanabe, K; McGuire, MA; Cobden, DH; Xiao, D; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan; Zhang, Xiaoou; Huang, Bevin; Wilson, Nathan P.; Seyler, Kyle L.; Zhu, Lin; Taniguchi, Takashi; Watanabe, Kenji; McGuire, Michael A.; Cobden, David H.; Xiao, Di; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic multilayer devices that exploit magnetoresistance are the backbone of magnetic sensing and data storage technologies. Here, we report multiple-spin-filter magnetic tunnel junctions (sf-MTJs) based on van der Waals (vdW) heterostructures in which atomically thin chromium triiodide (CrI3) acts as a spin-filter tunnel barrier sandwiched between graphene contacts. We demonstrate tunneling magnetoresistance that is drastically enhanced with increasing CrI3 layer thickness, reaching a record 19,000% for magnetic multilayer structures using four-layer sf-MTJs at low temperatures. Using magnetic circular dichroism measurements, we attribute these effects to the intrinsic layer-by-layer antiferromagnetic ordering of the atomically thin CrI3. Our work reveals the possibility to push magnetic information storage to the atomically thin limit and highlights CrI3 as a superlative magnetic tunnel barrier for vdW heterostructure spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 997, "Times Cited, All Databases": 1079, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 360, "Issue": 6394, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1214, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar4851", "DOI Link": "http://dx.doi.org/10.1126/science.aar4851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435360400049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, JJ; Tong, K; Pei, QB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Jiajie; Tong, Kwing; Pei, Qibing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Water-Based Silver-nullowire Screen-Print Ink for the Fabrication of Stretchable Conductors and Wearable Thin-Film Transistors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A water-based silver-nullowire (AgNW) ink is formulated for screen printing. Screen-printed AgNW patterns have uniform sharp edges, approximate to 50 mu m resolution, and electrical conductivity as high as 4.67 x 10(4) S cm(-1). The screen-printed AgNW patterns are used to fabricate a stretchable composite conductor, and a fully printed and intrinsically stretchable thin-film transistor array is also realized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2016, "Volume": 28, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5986, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201600772", "DOI Link": "http://dx.doi.org/10.1002/adma.201600772", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382400900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halim, J; Lukatskaya, MR; Cook, KM; Lu, J; Smith, CR; Näslund, LÅ; May, SJ; Hultman, L; Gogotsi, Y; Eklund, P; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M.; Lu, Jun; Smith, Cole R.; Naslund, Lars-Ake; May, Steven J.; Hultman, Lars; Gogotsi, Yury; Eklund, Per; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the discovery of graphene, the quest for two-dimensional (2D) materials has intensified greatly. Recently, a new family of 2D transition metal carbides and carbonitrides (MXenes) was discovered that is both conducting and hydrophilic, an uncommon combination. To date MXenes have been produced as powders, flakes, and colloidal solutions. Herein, we report on the fabrication of similar to 1 x 1 cm(2) Ti3C2 films by selective etching of Al, from sputter-deposited epitaxial Ti3AlC2 films, in aqueous HF or NH4HF2. Films that were about 19 nm thick, etched with NH4HF2, transmit similar to 90% of the light in the visible-to-infrared range and exhibit metallic conductivity down to similar to 100 K. Below 100 K, the films' resistivity increases with decreasing temperature and they exhibit negative magnetoresistance-both observations consistent with a weak localization phenomenon characteristic of many 2D defective solids. This advance opens the door for the use of MXenes in electronic, photonic, and sensing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1269, "Times Cited, All Databases": 1382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2014, "Volume": 26, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2374, "End Page": 2381, "Article Number": null, "DOI": "10.1021/cm500641a", "DOI Link": "http://dx.doi.org/10.1021/cm500641a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334572300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Luo, M; Liu, ZX; Peng, M; Chen, DC; Lu, YR; Chan, TS; de Groot, FMF; Tan, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kang; Luo, Min; Liu, Zhixiao; Peng, Ming; Chen, Dechao; Lu, Ying-Rui; Chan, Ting-Shan; de Groot, Frank M. F.; Tan, Yongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational strain engineering of single-atom ruthenium on nulloporous MoS2 for highly efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Maximizing the catalytic activity of single-atom catalysts is vital for the application of single-atom catalysts in industrial water-alkali electrolyzers, yet the modulation of the catalytic properties of single-atom catalysts remains challenging. Here, we construct strain-tunable sulphur vacancies around single-atom Ru sites for accelerating the alkaline hydrogen evolution reaction of single-atom Ru sites based on a nulloporous MoS2-based Ru single-atom catalyst. By altering the strain of this system, the synergistic effect between sulphur vacancies and Ru sites is amplified, thus changing the catalytic behavior of active sites, namely, the increased reactant density in strained sulphur vacancies and the accelerated hydrogen evolution reaction process on Ru sites. The resulting catalyst delivers an overpotential of 30mV at a current density of 10mAcm(-2), a Tafel slope of 31mV dec(-1), and a long catalytic lifetime. This work provides an effective strategy to improve the activities of single-atom modified transition metal dichalcogenides catalysts by precise strain engineering. The modulation of single-atom catalyst properties for industrial applications remains challenging. Here, authors use strain engineering to amplify the synergistic effect between MoS2's sulphur vacancies and single-atom Ru sites and accelerate H-2 evolution electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1687, "DOI": "10.1038/s41467-021-21956-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21956-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629990000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, RP; Zhao, ST; Ding, J; Chong, Y; Jia, T; Ophus, C; Asta, M; Ritchie, RO; Minor, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ruopeng; Zhao, Shiteng; Ding, Jun; Chong, Yan; Jia, Tao; Ophus, Colin; Asta, Mark; Ritchie, Robert O.; Minor, Andrew M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Short-range order and its impact on the CrCoNi medium-entropy alloy", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional metallic alloys are mixtures of elements in which the atoms of minority species tend to be distributed randomly if they are below their solubility limit, or to form secondary phases if they are above it. The concept of multiple-principal-element alloys has recently expanded this view, as these materials are single-phase solid solutions of generally equiatomic mixtures of metallic elements. This group of materials has received much interest owing to their enhanced mechanical properties(1-5). They are usually called medium-entropy alloys in ternary systems and high-entropy alloys in quaternary or quinary systems, alluding to their high degree of configurational entropy. However, the question has remained as to how random these solid solutions actually are, with the influence of short-range order being suggested in computational simulations but not seen experimentally(6,7). Here we report the observation, using energy-filtered transmission electron microscopy, of structural features attributable to short-range order in the CrCoNi medium-entropy alloy. Increasing amounts of such order give rise to both higher stacking-fault energy and hardness. These findings suggest that the degree of local ordering at the nullometre scale can be tailored through thermomechanical processing, providing a new avenue for tuning the mechanical properties of medium- and high-entropy alloys. Metal alloys consisting of three or more major elemental components show enhanced mechanical properties, which are now shown to be correlated with short-range order observed with electron microscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 877, "Times Cited, All Databases": 918, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 581, "Issue": 7808, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 283, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2275-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2275-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000534818200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, TT; Yang, Y; Yu, DY; Wali, Q; Wang, ZY; Cao, XS; Fan, W; Liu, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Tiantian; Yang, Yi; Yu, Dingyi; Wali, Qamar; Wang, Zhenyu; Cao, Xuesong; Fan, Wei; Liu, Tianxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Integrated Gradient-Conductive MXene/CNT/Polyimide Aerogel Frames for Electromagnetic Interference Shielding with Ultra-Low Reflection", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of advanced electromagnetic interference (EMI) shielding materials with miniaturized, programmable structure and low reflection are promising but challenging. Herein, an integrated transition-metal carbides/carbon nullotube/polyimide (gradient-conductive MXene/CNT/PI, GCMCP) aerogel frame with hierarchical porous structure and gradient-conductivity has been constructed to achieve EMI shielding with ultra-low reflection. The gradient-conductive structures are obtained by continuous 3D printing of MXene/CNT/poly (amic acid) inks with different CNT contents, where the slightly conductive top layer serves as EM absorption layer and the highly conductive bottom layer as reflection layer. In addition, the hierarchical porous structure could extend the EM dissipation path and dissipate EM by multiple reflections. Consequently, the GCMCP aerogel frames exhibit an excellent average EMI shielding efficiency (68.2 dB) and low reflection (R = 0.23). Furthermore, the GCMCP aerogel frames with miniaturized and programmable structures can be used as EMI shielding gaskets and effectively block wireless power transmission, which shows a prosperous application prospect in defense industry and aerospace.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45, "DOI": "10.1007/s40820-023-01017-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01017-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931727400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hod, I; Sampson, MD; Deria, P; Kubiak, CP; Farha, OK; Hupp, JT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hod, Idan; Sampson, Matthew D.; Deria, Pravas; Kubiak, Clifford P.; Farha, Omar K.; Hupp, Joseph T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe-Porphyrin-Based Metal-Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO2", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realization of heterogeneous electrochemical CO2-to-fuel conversion via molecular catalysis under high-flux conditions requires the assembly of large quantities of reactant-accessible catalysts on conductive surfaces. As a proof of principle, we demonstrate that electrophoretic deposition of thin films of an appropriately chosen metal-organic framework (MOF) material is an effective method for immobilizing the needed quantity of catalyst. For electrocatalytic CO2 reduction, we used a material that contains functionalized Fe-porphyrins as catalytically competent, redox-conductive linkers. The approach yields a high effective surface coverage of electrochemically addressable catalytic sites (similar to 10(15) sites/cm(2)). The chemical products of the reduction, obtained with similar to 100% Faradaic efficiency, are mixtures of CO and H-2. These results validate the strategy of using MOF chemistry to obtain porous, electrode-immobilized, networks of molecular catalysts having competency for energy-relevant electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 695, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6302, "End Page": 6309, "Article Number": null, "DOI": "10.1021/acscatal.5b01767", "DOI Link": "http://dx.doi.org/10.1021/acscatal.5b01767", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364441300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheema, SS; Kwon, D; Shanker, N; dos Reis, R; Hsu, SL; Xiao, J; Zhang, HG; Wagner, R; Datar, A; McCarter, MR; Serrao, CR; Yadav, AK; Karbasian, G; Hsu, CH; Tan, AJ; Wang, LC; Thakare, V; Zhang, X; Mehta, A; Karapetrova, E; Chopdekar, R; Shafer, P; Arenholz, E; Hu, CM; Proksch, R; Ramesh, R; Ciston, J; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheema, Suraj S.; Kwon, Daewoong; Shanker, Nirmaan; dos Reis, Roberto; Hsu, Shang-Lin; Xiao, Jun; Zhang, Haigang; Wagner, Ryan; Datar, Adhiraj; McCarter, Margaret R.; Serrao, Claudy R.; Yadav, Ajay K.; Karbasian, Golnaz; Hsu, Cheng-Hsiang; Tan, Ava J.; Wang, Li-Chen; Thakare, Vishal; Zhang, Xiang; Mehta, Apurva; Karapetrova, Evguenia; Chopdekar, Rajesh, V; Shafer, Padraic; Arenholz, Elke; Hu, Chenming; Proksch, Roger; Ramesh, Ramamoorthy; Ciston, Jim; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced ferroelectricity in ultrathin films grown directly on silicon", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin ferroelectric materials could potentially enable low-power perovskite ferroelectric tetragonality logic and nonvolatile memories(1,2). As ferroelectric materials are made thinner, however, the ferroelectricity is usually suppressed. Size effects in ferroelectrics have been thoroughly investigated in perovskite oxides-the archetypal ferroelectric system(3). Perovskites, however, have so far proved unsuitable for thickness scaling and integration with modern semiconductor processes(4). Here we report ferroelectricity in ultrathin doped hafnium oxide (HfO2), a fluorite-structure oxide grown by atomic layer deposition on silicon. We demonstrate the persistence of inversion symmetry breaking and spontaneous, switchable polarization down to a thickness of one nullometre. Our results indicate not only the absence of a ferroelectric critical thickness but also enhanced polar distortions as film thickness is reduced, unlike in perovskite ferroelectrics. This approach to enhancing ferroelectricity in ultrathin layers could provide a route towards polarization-driven memories and ferroelectric-based advanced transistors. This work shifts the search for the fundamental limits of ferroelectricity to simpler transition-metal oxide systems-that is, from perovskite-derived complex oxides to fluorite-structure binary oxides-in which 'reverse' size effects counterintuitively stabilize polar symmetry in the ultrathin regime. Enhanced switchable ferroelectric polarization is achieved in doped hafnium oxide films grown directly onto silicon using low-temperature atomic layer deposition, even at thicknesses of just one nullometre.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 634, "Times Cited, All Databases": 670, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 580, "Issue": 7804, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 478, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2208-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2208-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528065800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, RQ; James, DK; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Ruquan; James, Dustin K.; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Laser-Induced Graphene: From Discovery to Translation", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser-induced graphene (LIG) is a 3D porous material prepared by direct laser writing with a CO2 laser on carbon materials in ambient atmosphere. This technique combines 3D graphene preparation and patterning into a single step without the need for wet chemical steps. Since its discovery in 2014, LIG has attracted broad research interest, with several papers being published per month using this approach. These serve to delineate the mechanism of the LIG-forming process and to showcase the translation into many application areas. Herein, the strategies that have been developed to synthesize LIG are summarized, including the control of LIG properties such as porosity, composition, and surface characteristics, and the advancement in methodology to convert diverse carbon precursors into LIG. Taking advantage of the LIG properties, the applications of LIG in broad fields, such as microfluidics, sensors, and electrocatalysts, are highlighted. Finally, future development in biodegradable and biocompatible materials is briefly discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 647, "Times Cited, All Databases": 690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2019, "Volume": 31, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803621, "DOI": "10.1002/adma.201803621", "DOI Link": "http://dx.doi.org/10.1002/adma.201803621", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454786200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HP; Rebollar, D; He, HY; Chong, LN; Liu, YZ; Liu, C; Sun, CJ; Li, T; Muntean, JV; Winulls, RE; Liu, DJ; Xu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Haiping; Rebollar, Dominic; He, Haiying; Chong, Lina; Liu, Yuzi; Liu, Cong; Sun, Cheng-Jun; Li, Tao; Muntean, John, V; Winulls, Randall E.; Liu, Di-Jia; Xu, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective electrocatalytic CO2reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct electrochemical conversion of CO(2)to ethanol offers a promising strategy to lower CO(2)emissions while storing energy from renewable electricity. However, current electrocatalysts offer only limited selectivity toward ethanol. Here we report a carbon-supported copper (Cu) catalyst, synthesized by an amalgamated Cu-Li method, that achieves a single-product Faradaic efficiency (FE) of 91% at -0.7 V (versus the reversible hydrogen electrode) and onset potential as low as -0.4 V (reversible hydrogen electrode) for electrocatalytic CO2-to-ethanol conversion. The catalyst operated stably over 16 h. The FE of ethanol was highly sensitive to the initial dispersion of Cu atoms and decreased significantly when CuO and large Cu clusters become predominullt species. Operando X-ray absorption spectroscopy identified a reversible transformation from atomically dispersed Cu atoms to Cu(n)clusters (n = 3 and 4) on application of electrochemical conditions. First-principles calculations further elucidate the possible catalytic mechanism of CO(2)reduction over Cu-n. Electrocatalytically reducing CO(2)to ethanol can provide renewably generated fuel, but catalysts are often poorly selective for this conversion. Here the authors use a Cu catalyst to produce ethanol with high selectivity. Cu dispersion is key to the performance and operando studies indicate that it changes under reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 524, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 623, "End Page": 632, "Article Number": null, "DOI": "10.1038/s41560-020-0666-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0666-x", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552931500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ducrot, E; Chen, YL; Bulters, M; Sijbesma, RP; Creton, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ducrot, Etienne; Chen, Yulan; Bulters, Markus; Sijbesma, Rint P.; Creton, Costantino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toughening Elastomers with Sacrificial Bonds and Watching Them Break", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elastomers are widely used because of their large-strain reversible deformability. Most unfilled elastomers suffer from a poor mechanical strength, which limits their use. Using sacrificial bonds, we show how brittle, unfilled elastomers can be strongly reinforced in stiffness and toughness (up to 4 megapascals and 9 kilojoules per square meter) by introducing a variable proportion of isotropically prestretched chains that can break and dissipate energy before the material fails. Chemoluminescent cross-linking molecules, which emit light as they break, map in real time where and when many of these internal bonds break ahead of a propagating crack. The simple methodology that we use to introduce sacrificial bonds, combined with the mapping of where bonds break, has the potential to stimulate the development of new classes of unfilled tough elastomers and better molecular models of the fracture of soft materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 930, "Times Cited, All Databases": 1008, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2014, "Volume": 344, "Issue": 6180, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 186, "End Page": 189, "Article Number": null, "DOI": "10.1126/science.1248494", "DOI Link": "http://dx.doi.org/10.1126/science.1248494", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334096300032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Y; Jiao, Y; Li, LH; Xing, T; Chen, Y; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Yao; Jiao, Yan; Li, Lu Hua; Xing, Tan; Chen, Ying; Jaroniec, Mietek; Qiao, Shi Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward Design of Synergistically Active Carbon-Based Catalysts for Electrocatalytic Hydrogen Evolution", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Replacement of precious Pt catalyst with cost-effective alternatives would be significantly beneficial for hydrogen production via electrocatalytic hydrogen evolution reaction (HER). All candidates thus far are exclusively metallic catalysts, which suffer inherent corrosion and oxidation susceptibility during acidic proton-exchange membrane electrolysis. Herein, based on theoretical predictions, we designed and synthesized nitrogen (N) and phosphorus (P) dual-doped graphene as a nonmetallic electrocatalyst for sustainable and efficient hydrogen production. The N and P heteroatoms could coactivate the adjacent C atom in the graphene matrix by affecting its valence orbital energy levels to induce a synergistically enhanced reactivity toward HER. As a result, the dual-doped electrocatalytic HER activity than single-doped ones and comparable performance to some of the traditional metallic catalysts. graphene showed higher", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 927, "Times Cited, All Databases": 964, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5290, "End Page": 5296, "Article Number": null, "DOI": "10.1021/nn501434a", "DOI Link": "http://dx.doi.org/10.1021/nn501434a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336640600122", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Zhang, DN; Fan, JJ; Xiang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yang; Zhang, Dainull; Fan, Jiajie; Xiang, Quanjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly crystalline carbon nitride hollow spheres with enhanced photocatalytic performance", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphitic carbon nitride (g-C3N4) has emerged as a remarkably promising photocatalyst for addressing environmental and energy issues; however, it exhibits only moderate photocatalytic activity because of its low specific surface area and high recombination of carriers. Preparation of crystalline g-C3N4 by the molten salt method has proven to be an effective method to improve the photocatalytic activity. However, crystalline g-C3N4 prepared by the conventional molten salt method exhibits a less regular morphology. Herein, highly crystalline g-C3N4 hollow spheres (CCNHS) were successfully prepared by the molten salt method using cyanuric acid-melamine as a precursor. The higher crystallization of the CCNHS samples not only repaired the structural defects at the surface of the CCNHS samples but also established a built-in electric field between heptazine-based g-C3N4 and triazine-based g-C3N4. The hollow structure improved the level of light energy utilization and increased the number of active sites for photocatalytic reactions. Because of the above characteristics, the as-prepared CCNHS samples simultaneously realized photocatalytic hydrogen evolution with the degradation of the plasticizer bisphenol A. This research offers a new perspective on the structural optimization of supramolecular self-assembly. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 42, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 627, "End Page": 636, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63684-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63684-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582726900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, YL; Sheng, ZZ; Fu, C; Kong, J; Zhang, XT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Yinglai; Sheng, Zhizhi; Fu, Chen; Kong, Jie; Zhang, Xuetong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hygroscopic holey graphene aerogel fibers enable highly efficient moisture capture, heat allocation and microwave absorption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aerogel fibers have been recognized as the rising star in the fields of thermal insulation and wearable textiles. Yet, the lack of functionalization in aerogel fibers limits their applications. Herein, we report hygroscopic holey graphene aerogel fibers (LiCl@HGAFs) with integrated functionalities of highly efficient moisture capture, heat allocation, and microwave absorption. LiCl@HGAFs realize the water sorption capacity over 4.15 g g(-1), due to the high surface area and high water uptake kinetics. Moreover, the sorbent can be regenerated through both photo-thermal and electro-thermal approaches. Along with the water sorption and desorption, LiCl@HGAFs experience an efficient heat transfer process, with a heat storage capacity of 6.93 kJ g(-1). The coefficient of performance in the heating and cooling mode can reach 1.72 and 0.70, respectively. Notably, with the entrapped water, LiCl@HGAFs exhibit broad microwave absorption with a bandwidth of 9.69 GHz, good impedance matching, and a high attenuation constant of 585. In light of these findings, the multifunctional LiCl@HGAFs open an avenue for applications in water harvest, heat allocation, and microwave absorption. This strategy also suggests the possibility to functionalize aerogel fibers towards even broader applications. Functionalization of aerogel fibers, characterized by high porosity and low thermal conductivity, to obtain multifunctional materials is highly desirable. Here the authors report hygroscopic holey graphene aerogel fibers hosting LiCl salt, enabling moisture capture, heat allocation, and microwave absorption performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1227, "DOI": "10.1038/s41467-022-28906-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28906-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766759300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MM; Qiao, S; Zheng, YL; Andaloussi, YH; Li, X; Zhang, ZJ; Li, A; Cheng, P; Ma, SQ; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mingmin; Qiao, Shan; Zheng, Yunlong; Andaloussi, Yassin H.; Li, Xia; Zhang, Zhenjie; Li, Ang; Cheng, Peng; Ma, Shengqian; Chen, Yao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabricating Covalent Organic Framework Capsules with Commodious Microenvironment for Enzymes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzyme immobilization has been demonstrated to be a favorable protocol to promote industrialization of biomacromolecules. Despite tremendous efforts to develop new strategies and materials to realize this process, maintaining enzyme activity is still a formidable challenge. Herein we created a sacrificial templating method, using metal-organic frameworks (MOFs) as sacrificial templates to construct hollow covalent organic framework (COF) capsules for enzyme encapsulation. This strategy can provide a capacious microenvironment to unleash enzyme molecules. The improved conformational freedom of enzymes, enhanced mass transfer, and protective effect against the external environment ultimately boosted the enzymatic activities. We also found that this strategy possesses high versatility that is suitable for diverse biomacromolecules, MOF templates, and COF capsules. Moreover, the dimensions, pore sizes, and shell thickness of COF capsules can be conveniently tuned, allowing for customizing bioreactors for specific functions. For example, coencapsulation of different enzymes with synergistic functions were successfully demonstrated using this bioreactor platform. This study not only opens up a new avenue to overcome the present limitations of enzymatic immobilization in porous matrixes but also provides new opportunities for construction of biomicrodevices or artificial organelles based on crystalline porous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2020, "Volume": 142, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6675, "End Page": 6681, "Article Number": null, "DOI": "10.1021/jacs.0c00285", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c00285", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526394200028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ML; Shi, QF; He, TYY; Yi, ZR; Ma, YM; Yang, B; Chen, T; Lee, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Minglu; Shi, Qingfeng; He, Tianyiyi; Yi, Zhiran; Ma, Yiming; Yang, Bin; Chen, Tao; Lee, Chengkuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Powered and Self-Functional Cotton Sock Using Piezoelectric and Triboelectric Hybrid Mechanism for Healthcare and Sports Monitoring", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable devices rely on hybrid mechanisms that possess the advantages of establishing a smarter system for healthcare, sports monitoring, and smart home applications. Socks with sensing capabilities can reveal more direct sensory information on the body for longer duration in daily life. However, the limitation of suitable materials for smart textile makes the development of multifunctional socks a major challenge. In this paper, we have developed a self-powered and self-functional sock (S-2-sock) to realize diversified functions including energy harvesting and sensing various physiological signals, i.e., gait, contact force, sweat level, etc., by hybrid integrating poly(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT:PSS)-coated fabric triboelectric nullogenerator (TENG) and lead zirconate titanate (PZT) piezoelectric chips. An output power of 1.71 mW is collected from a PEDOT:PSS-coated sock with mild jumping at 2 Hz and load resistance of 59.7 M Omega The study shows that cotton socks worn daily can potentially be a power source for enabling self-sustained socks comprising wireless transmission modules and integrated circuits in the future. We also investigate the influences of environmental humidity, temperature, and weight variations and verify that our S-2-sock can successfully achieve walking pattern recognition and motion tracking for smart home applications. On the basis of the sensor fusion concept, the outputs from TENG and PZT sensors under exercise activities are effectively merged together for quick detection of the sweat level. By leveraging the hybrid S-2-sock, we can achieve more functionality in the applications of foot-based energy harvesting and monitoring the diversified physiological signals for healthcare, smart homes, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1940, "End Page": 1952, "Article Number": null, "DOI": "10.1021/acsnullo.8b08329", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b08329", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460199400093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Matsumoto, M; Valentino, L; Stiehl, GM; Balch, HB; Corcos, AR; Wang, F; Ralph, DC; Mariñas, BJ; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Matsumoto, Michio; Valentino, Lauren; Stiehl, Gregory M.; Balch, Halleh B.; Corcos, Amanda R.; Wang, Feng; Ralph, Daniel C.; Marinas, Benito J.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lewis-Acid-Catalyzed Interfacial Polymerization of Covalent Organic Framework Films", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are crystalline polymers with covalent bonds in two or three dimensions, providing pores 1-5 nm in diameter. COFs are typically isolated as microcrystalline powders, which are unsuitable for many applications that would leverage their tunable structures, such as opto-electronic devices and nullofiltration membranes. Here, we report the interfacial polymerization of polyfunctional amine and aldehyde monomers with a Lewis acid catalyst, Sc(OTf)(3). Immiscible solutions segregate the catalyst from the monomers, confining polymerization to the solution interface. This method provides large-area, continuous COF films (several cm(2)) with a thickness tuned from 100 mu m to 2.5 nm. Relatively thick films were crystalline, whereas the films that are a few nullometers thick were presumably amorphous. The COF films were transferred onto polyethersulfone supports, and the resulting membranes showed enhanced rejection of Rhodamine WT, a model water contaminullt. The large area, tunable pore size, and tailored molecular composition show promise for nullofiltration applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 308, "End Page": 317, "Article Number": null, "DOI": "10.1016/j.chempr.2017.12.011", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.12.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429434000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YA; McNulty, I; Liu, C; Lau, KC; Liu, Q; Paulikas, AP; Sun, CJ; Cai, ZH; Guest, JR; Ren, Y; Stamenkovic, V; Curtiss, LA; Liu, YZ; Rajh, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yimin A.; McNulty, Ian; Liu, Cong; Lau, Kah Chun; Liu, Qi; Paulikas, Arvydas P.; Sun, Cheng-Jun; Cai, Zhonghou; Guest, Jeffrey R.; Ren, Yang; Stamenkovic, Vojislav; Curtiss, Larry A.; Liu, Yuzi; Rajh, Tijana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facet-dependent active sites of a single Cu2O particle photocatalyst for CO2 reduction to methanol", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic-level understanding of the active sites and transformation mechanisms under realistic working conditions is a prerequisite for rational design of high-performance photocatalysts. Here, by using correlated scanning fluorescence X-ray microscopy and environmental transmission electron microscopy at atmospheric pressure, in operando, we directly observe that the (110) facet of a single Cu2O photocatalyst particle is photocatalytically active for CO2 reduction to methanol while the (100) facet is inert. The oxidation state of the active sites changes from Cu(I) towards Cu(II) due to CO2 and H2O co-adsorption and changes back to Cu(I) after CO2 conversion under visible light illumination. The Cu2O photocatalyst oxidizes water as it reduces CO2. Concomitantly, the crystal lattice expands due to CO2 adsorption then reverts after CO2 conversion. The internal quantum yield for unassisted wireless photocatalytic reduction of CO2 to methanol using Cu2O crystals is similar to 72%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 957, "End Page": 968, "Article Number": null, "DOI": "10.1038/s41560-019-0490-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0490-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496958300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, T; Song, Q; Liu, K; Liu, HY; Pan, JJ; Liu, W; Dai, L; Zhang, M; Wang, YX; Si, CL; Du, HS; Zhang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ting; Song, Qun; Liu, Kun; Liu, Huayu; Pan, Junjie; Liu, Wei; Dai, Lin; Zhang, Meng; Wang, Yaxuan; Si, Chuanling; Du, Haishun; Zhang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose-Assisted Construction of Multifunctional MXene-Based Aerogels with Engineering Biomimetic Texture for Pressure Sensor and Compressible Electrode", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional architecture with intriguing structural design is highly desired for realizing the promising performances in wearable sensors and flexible energy storage devices. Cellulose nullofiber (CNF) is employed for assisting in building conductive, hyperelastic, and ultralight Ti3C2Tx MXene hybrid aerogels with oriented tracheid-like texture. The biomimetic hybrid aerogels are constructed by a facile bidirectional freezing strategy with CNF, carbon nullotube (CNT), and MXene based on synergistic electrostatic interaction and hydrogen bonding. Entangled CNF and CNT mortars bonded with MXene bricks of the tracheid structure produce good interfacial binding, and superior mechanical strength (up to 80% compressibility and extraordinary fatigue resistance of 1000 cycles at 50% strain). Benefiting from the biomimetic texture, CNF/CNT/MXene aerogel shows ultralow density of 7.48 mg cm(-3) and excellent electrical conductivity (similar to 2400 S m(-1)). Used as pressure sensors, such aerogels exhibit appealing sensitivity performance with the linear sensitivity up to 817.3 kPa(-1), which affords their application in monitoring body surface information and detecting human motion. Furthermore, the aerogels can also act as electrode materials of compressive solid-state supercapacitors that reveal satisfactory electrochemical performance (849.2 mF cm(-2) at 0.8 mA cm(-2)) and superior long cycle compression performance (88% after 10,000 cycles at a compressive strain of 30%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 98, "DOI": "10.1007/s40820-023-01073-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01073-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968816500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, KK; Gong, YH; Liu, BY; Zhu, YZ; Xu, SM; Yao, YG; Luo, W; Wang, CW; Lacey, SD; Dai, JQ; Chen, YN; Mo, YF; Wachsman, E; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang; Zhu, Yizhou; Xu, Shaomao; Yao, Yonggang; Luo, Wei; Wang, Chengwei; Lacey, Steven D.; Dai, Jiaqi; Chen, Yanull; Mo, Yifei; Wachsman, Eric; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward garnet electrolyte-based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet-type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10(-3) to 10(-4) S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm.cm(2) for the pristine garnet/Li and 75 ohm.cm(2) for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601659", "DOI": "10.1126/sciadv.1601659", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, QS; Zhang, LX; Feng, R; Lu, QH; An, K; Chuang, AC; Poplawsky, JD; Liaw, PK; Lu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Qingsong; Zhang, Liangxue; Feng, Rui; Lu, Qiuhong; An, Ke; Chuang, Andrew Chihpin; Poplawsky, Jonathan D.; Liaw, Peter K.; Lu, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient cell-structured high-entropy alloy with exceptional strength and ductility", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Similar to conventional materials, most multicomponent high-entropy alloys (HEAs) lose ductility as they gain strength. In this study, we controllably introduced gradient nulloscaled dislocation cell structures in a stable single-phase HEA with face-centered cubic structure, thus resulting in enhanced strength without apparent loss of ductility. Upon application of strain, the sample-level structural gradient induces progressive formation of a high density of tiny stacking faults (SFs) and twins, nucleating from abundant low-angle dislocation cells. Furthermore, the SF-induced plasticity and the resultant refined structures, coupled with intensively accumulated dislocations, contribute to plasticity, increased strength, and work hardening. These findings offer a promising paradigm for tailoring properties with gradient dislocation cells at the nulloscale and advance our fundamental understanding of the intrinsic deformation behavior of HEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 470, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2021, "Volume": 374, "Issue": 6570, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 984, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj8114", "DOI Link": "http://dx.doi.org/10.1126/science.abj8114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720789200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maiyalagan, T; Jarvis, KA; Therese, S; Ferreira, PJ; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maiyalagan, Thandavarayan; Jarvis, Karalee A.; Therese, Soosairaj; Ferreira, Paulo J.; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of efficient, affordable electrocatalysts for the oxygen evolution reaction and the oxygen reduction reaction is critical for rechargeable metal-air batteries. Here we present lithium cobalt oxide, synthesized at 400 degrees C (designated as LT-LiCoO2) that adopts a lithiated spinel structure, as an inexpensive, efficient electrocatalyst for the oxygen evolution reaction. The catalytic activity of LT-LiCoO2 is higher than that of both spinel cobalt oxide and layered lithium cobalt oxide synthesized at 800 degrees C (designated as HT-LiCoO2) for the oxygen evolution reaction. Although LT-LiCoO2 exhibits poor activity for the oxygen reduction reaction, the chemically delithiated LT-Li1-xCoO2 samples exhibit a combination of high oxygen reduction reaction and oxygen evolution reaction activities, making the spinel-type LTLi0,5CoO2 a potential bifunctional electrocatalyst for rechargeable metal-air batteries. The high activities of these delithiated compositions are attributed to the Co4O4 cubane subunits and a pinning of the Co3+/4+:3d energy with the top of the O2-:2p band.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 603, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3949, "DOI": "10.1038/ncomms4949", "DOI Link": "http://dx.doi.org/10.1038/ncomms4949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337505800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bubnova, O; Khan, ZU; Wang, H; Braun, S; Evans, DR; Fabretto, M; Hojati-Talemi, P; Dagnelund, D; Arlin, JB; Geerts, YH; Desbief, S; Breiby, DW; Andreasen, JW; Lazzaroni, R; Chen, WMM; Zozoulenko, I; Fahlman, M; Murphy, PJ; Berggren, M; Crispin, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bubnova, Olga; Khan, Zia Ullah; Wang, Hui; Braun, Slawomir; Evans, Drew R.; Fabretto, Manrico; Hojati-Talemi, Pejman; Dagnelund, Daniel; Arlin, Jean-Baptiste; Geerts, Yves H.; Desbief, Simon; Breiby, Dag W.; Andreasen, Jens W.; Lazzaroni, Roberto; Chen, Weimin M.; Zozoulenko, Igor; Fahlman, Mats; Murphy, Peter J.; Berggren, Magnus; Crispin, Xavier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semi-metallic polymers", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers are lightweight, flexible, solution-processable materials that are promising for low-cost printed electronics as well as for mass-produced and large-area applications. Previous studies demonstrated that they can possess insulating, semiconducting or metallic properties; here we report that polymers can also be semi-metallic. Semi-metals, exemplified by bismuth, graphite and telluride alloys, have no energy bandgap and a very low density of states at the Fermi level. Furthermore, they typically have a higher Seebeck coefficient and lower thermal conductivities compared with metals, thus being suitable for thermoelectric applications. We measure the thermoelectric properties of various poly( 3,4-ethylenedioxythiophene) samples, and observe a marked increase in the Seebeck coefficient when the electrical conductivity is enhanced through molecular organization. This initiates the transition from a Fermi glass to a semi-metal. The high Seebeck value, the metallic conductivity at room temperature and the absence of unpaired electron spins makes polymer semi-metals attractive for thermoelectrics and spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 727, "Times Cited, All Databases": 786, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 190, "End Page": 194, "Article Number": null, "DOI": "10.1038/nmat3824", "DOI Link": "http://dx.doi.org/10.1038/nmat3824", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330182700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gelebart, AH; Mulder, DJ; Varga, M; Konya, A; Vantomme, G; Meijer, EW; Selinger, RLB; Broer, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gelebart, Anne Helene; Mulder, Dirk Jan; Varga, Michael; Konya, Andrew; Vantomme, Ghislaine; Meijer, E. W.; Selinger, Robin L. B.; Broer, Dirk J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making waves in a photoactive polymer film", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oscillating materials(1-4) that adapt their shapes in response to external stimuli are of interest for emerging applications in medicine and robotics. For example, liquid-crystal networks can be programmed to undergo stimulus-induced deformations in various geometries, including in response to light(5,6). Azobenzene molecules are often incorporated into liquid-crystal polymer films to make them photoresponsive(7-11); however, in most cases only the bending responses of these films have been studied, and relaxation after photo-isomerization is rather slow. Modifying the core or adding substituents to the azobenzene moiety can lead to marked changes in photophysical and photochemical properties(12-15), providing an opportunity to circumvent the use of a complex set-up that involves multiple light sources, lenses or mirrors. Here, by incorporating azobenzene derivatives with fast cis-to-trans thermal relaxation into liquid-crystal networks, we generate photoactive polymer films that exhibit continuous, directional, macroscopic mechanical waves under constant light illumination, with a feedback loop that is driven by self-shadowing. We explain the mechanism of wave generation using a theoretical model and numerical simulations, which show good qualitative agreement with our experiments. We also demonstrate the potential application of our photoactive films in light-driven locomotion and self-cleaning surfaces, and anticipate further applications in fields such as photomechanical energy harvesting and miniaturized transport.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 817, "Times Cited, All Databases": 862, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2017, "Volume": 546, "Issue": 7660, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 632, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature22987", "DOI Link": "http://dx.doi.org/10.1038/nature22987", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404332000043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YS; Arneri, A; Bersini, S; Shin, SR; Zhu, K; Goli-Malekabadi, Z; Aleman, J; Colosi, C; Busignulli, F; Dell'Erba, V; Bishop, C; Shupe, T; Demarchi, D; Moretti, M; Rasponi, M; Dokmeci, MR; Atala, A; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yu Shrike; Arneri, Andrea; Bersini, Simone; Shin, Su-Ryon; Zhu, Kai; Goli-Malekabadi, Zahra; Aleman, Julio; Colosi, Cristina; Busignulli, Fabio; Dell'Erba, Valeria; Bishop, Colin; Shupe, Thomas; Demarchi, Danilo; Moretti, Matteo; Rasponi, Marco; Dokmeci, Mehmet Remzi; Atala, Anthony; Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioprinting 3D microfibrous scaffolds for engineering endothelialized myocardium and heart-on-a-chip", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering cardiac tissues and organ models remains a great challenge due to the hierarchical structure of the native myocardium. The need of integrating blood vessels brings additional complexity, limiting the available approaches that are suitable to produce integrated cardiovascular organoids. In this work we propose a novel hybrid strategy based on 3D bioprinting, to fabricate endothelialized myocardium. Enabled by the use of our composite bioink, endothelial cells directly bioprinted within microfibrous hydrogel scaffolds gradually migrated towards the peripheries of the microfibers to form a layer of confluent endothelium. Together with controlled anisotropy, this 3D endothelial bed was then seeded with cardiomyocytes to generate aligned myocardium capable of spontaneous and synchronous contraction. We further embedded the organoids into a specially designed microfluidic perfusion bioreactor to complete the endothelialized-myocardium-on-a-chip platform for cardiovascular toxicity evaluation. Finally, we demonstrated that such a technique could be translated to human cardiomyocytes derived from induced pluripotent stem cells to construct endothelialized human myocardium. We believe that our method for generation of endothelialized organoids fabricated through an innovative 3D bioprinting technology may find widespread applications in regenerative medicine, drug screening, and potentially disease modeling. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 657, "Times Cited, All Databases": 732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": 59, "Article Number": null, "DOI": "10.1016/j.biomaterials.2016.09.003", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2016.09.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386188500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XF; Chen, Y; Wang, SB; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xue Feng; Chen, Ye; Wang, Sibo; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacing Manganese Oxide and Cobalt in Porous Graphitic Carbon Polyhedrons Boosts Oxygen Electrocatalysis for Zn-Air Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design and synthesis of highly active and robust bifunctional non-noble electrocatalysts for both oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are urgently required for efficient rechargeable metal-air batteries. Herein, abundant MnO/Co heterointerfaces are engineered in porous graphitic carbon (MnO/Co/PGC) polyhedrons via a facile hydrothermal-calcination route with a bimetal-organic framework as the precursor. The in situ generated Co nullocrystals not only create well-defined heterointerfaces with high conductivity to overcome the poor OER activity but also promote the formation of robust graphitic carbon. Owing to the desired composition and formation of the heterostructures, the resulting MnO/Co/PGC exhibits superior activity and stability toward both OER and ORR, which makes it an efficient air cathode for the rechargeable Zn-air battery. Importantly, the homemade Zn-air battery is able to deliver excellent performance including a peak power density of 172 mW cm(-2) and a specific capacity of 872 mAh g(-1), as well as excellent cycling stability (350 cycles), outperforming commercial mixed Pt/C||RuO2 catalysts. This work highlights the synergy from heterointerfaces in oxygen electrocatalysis, thus providing a promising approach for advanced metal-air cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 31, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902339, "DOI": "10.1002/adma.201902339", "DOI Link": "http://dx.doi.org/10.1002/adma.201902339", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479691300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, X; Dong, K; Ye, CY; Jiang, Y; Zhai, SY; Cheng, RW; Liu, D; Gao, XP; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Xiao; Dong, Kai; Ye, Cuiying; Jiang, Yang; Zhai, Siyuan; Cheng, Renwei; Liu, Di; Gao, Xiaoping; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A breathable, biodegradable, antibacterial, and self-powered electronic skin based on all-nullofiber triboelectric nullogenerators", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mimicking the comprehensive functions of human sensing via electronic skins (e-skins) is highly interesting for the development of human-machine interactions and artificial intelligences. Some e-skins with high sensitivity and stability were developed; however, little attention is paid to their comfortability, environmental friendliness, and antibacterial activity. Here, we report a breathable, biodegradable, and antibacterial e-skin based on all-nullofiber triboelectric nullogenerators, which is fabricated by sandwiching silver nullowire (Ag NW) between polylactic-coglycolic acid (PLGA) and polyvinyl alcohol (PVA). With micro-to-nullo hierarchical porous structure, the e-skin has high specific surface area for contact electrification and numerous capillary channels for thermal-moisture transfer. Through adjusting the concentration of Ag NW and the selection of PVA and PLGA, the antibacterial and biodegradable capability of e-skins can be tuned, respectively. Our e-skin can achieve real-time and self-powered monitoring of whole-body physiological signal and joint movement. This work provides a previously unexplored strategy for multifunctional e-skins with excellent practicability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 735, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba9624", "DOI": "10.1126/sciadv.aba9624", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba9624", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543504100033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, MP; Wang, YY; Xu, YX; Ye, LQ; Huang, YP; Jia, BH; Li, H; Ren, JQ; Deng, Y; Chen, JH; Zhou, Y; Lei, K; Wang, L; Liu, W; Huang, HW; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Mingpu; Wang, Yongye; Xu, Yixue; Ye, Liqun; Huang, Yingping; Jia, Baohua; Li, Hui; Ren, Jiaqi; Deng, Yu; Chen, Jiahao; Zhou, Ying; Lei, Kai; Wang, Li; Liu, Wei; Huang, Hongwei; Ma, Tianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecularly Engineered Covalent Organic Frameworks for Hydrogen Peroxide Photosynthesis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthesizing H2O2 from water and air via a photocatalytic approach is ideal for efficient production of this chemical at small-scale. However, the poor activity and selectivity of the 2 e(-) water oxidation reaction (WOR) greatly restricts the efficiency of photocatalytic H2O2 production. Herein we prepare a bipyridine-based covalent organic framework photocatalyst (denoted as COF-TfpBpy) for H2O2 production from water and air. The solar-to-chemical conversion (SCC) efficiency at 298 K and 333 K is 0.57 % and 1.08 %, respectively, which are higher than the current reported highest value. The resulting H2O2 solution is capable of degrading pollutants. A mechanistic study revealed that the excellent photocatalytic activity of COF-TfpBpy is due to the protonation of bipyridine monomer, which promotes the rate-determining reaction (2 e(-) WOR) and then enhances Yeager-type oxygen adsorption to accelerate 2 e(-) one-step oxygen reduction. This work demonstrates, for the first time, the COF-catalyzed photosynthesis of H2O2 from water and air; and paves the way for wastewater treatment using photocatalytic H2O2 solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2022, "Volume": 61, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202200413", "DOI": "10.1002/anie.202200413", "DOI Link": "http://dx.doi.org/10.1002/anie.202200413", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760773800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Loiudice, A; Lobaccaro, P; Kamali, EA; Thao, T; Huang, BH; Ager, JW; Buonsanti, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A.; Thao, Timothy; Huang, Brandon H.; Ager, Joel W.; Buonsanti, Raffaella", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring Copper nullocrystals towards C2 Products in Electrochemical CO2 Reduction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Favoring the CO2 reduction reaction (CO2RR) over the hydrogen evolution reaction and controlling the selectivity towards multicarbon products are currently major scientific challenges in sustainable energy research. It is known that the morphology of the catalyst can modulate catalytic activity and selectivity, yet this remains a relatively underexplored area in electrochemical CO2 reduction. Here, we exploit the material tunability afforded by colloidal chemistry to establish unambiguous structure/property relations between Cu nullocrystals and their behavior as electrocatalysts for CO2 reduction. Our study reveals a non-monotonic size-dependence of the selectivity in cube-shaped copper nullocrystals. Among 24nm, 44nm and 63nm cubes tested, the cubes with 44nm edge length exhibited the highest selectivity towards CO2RR (80%) and faradaic efficiency for ethylene (41%). Statistical analysis of the surface atom density suggests the key role played by edge sites in CO2RR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 717, "Times Cited, All Databases": 762, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2016, "Volume": 55, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5789, "End Page": 5792, "Article Number": null, "DOI": "10.1002/anie.201601582", "DOI Link": "http://dx.doi.org/10.1002/anie.201601582", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375118500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boland, CS; Khan, U; Ryan, G; Barwich, S; Charifou, R; Harvey, A; Backes, C; Li, Z; Ferreira, MS; Möbius, ME; Young, RJ; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boland, Conor S.; Khan, Umar; Ryan, Gavin; Barwich, Sebastian; Charifou, Romina; Harvey, Andrew; Backes, Claudia; Li, Zheling; Ferreira, Mauro S.; Mobius, Matthias E.; Young, Robert J.; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive electromechanical sensors using viscoelastic graphene-polymer nullocomposites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite its widespread use in nullocomposites, the effect of embedding graphene in highly viscoelastic polymer matrices is not well understood. We added graphene to a lightly crosslinked polysilicone, often encountered as Silly Putty, changing its electromechanical properties substantially. The resulting nullocomposites display unusual electromechanical behavior, such as postdeformation temporal relaxation of electrical resistance and nonmonotonic changes in resistivity with strain. These phenomena are associated with the mobility of the nullosheets in the low-viscosity polymer matrix. By considering both the connectivity and mobility of the nullosheets, we developed a quantitative model that completely describes the electromechanical properties. These nullocomposites are sensitive electromechanical sensors with gauge factors >500 that can measure pulse, blood pressure, and even the impact associated with the footsteps of a small spider.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 708, "Times Cited, All Databases": 768, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 9", "Publication Year": 2016, "Volume": 354, "Issue": 6317, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1257, "End Page": 1260, "Article Number": null, "DOI": "10.1126/science.aag2879", "DOI Link": "http://dx.doi.org/10.1126/science.aag2879", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389598800053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YM; Yu, ST; Feng, R; Bernard, A; Liu, Y; Zhang, Y; Duan, HZ; Shang, W; Tao, P; Song, CY; Deng, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yanming; Yu, Shengtao; Feng, Rui; Bernard, Antoine; Liu, Yang; Zhang, Yao; Duan, Haoze; Shang, Wen; Tao, Peng; Song, Chengyi; Deng, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Bioinspired, Reusable, Paper-Based System for High-Performance Large-Scale Evaporation", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A bioinspired, reusable, paper-based gold-nulloparticle film is fabricated by depositing an as-prepared gold-nulloparticle thin film on airlaid paper. This paper-based system with enhanced surface roughness and low thermal conductivity exhibits increased efficiency of evaporation, scale-up potential, and proven reusability. It is also demonstrated to be potentially useful in sea-water desalination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 726, "Times Cited, All Databases": 773, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2015, "Volume": 27, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2768, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201500135", "DOI Link": "http://dx.doi.org/10.1002/adma.201500135", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354217000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, SW; Liu, XF; Yuan, YP; Zhang, ZY; Liao, YS; Fang, J; Loo, SCJ; Sum, TC; Xue, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Shao-Wen; Liu, Xin-Feng; Yuan, Yu-Peng; Zhang, Zhen-Yi; Liao, Yu-Sen; Fang, Jun; Loo, Say Chye Joachim; Sum, Tze Chien; Xue, Can", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar-to-fuels conversion over In2O3/g-C3N4 hybrid photocatalysts", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have achieved in-situ growth of In2O3 nullocrystals onto the sheet-like g-C3N4 surface. The resulting In2O3-g-C3N4 hybrid structures exhibit considerable improvement on the photocatalytic activities for H-2 generation and CO2 reduction. The enhanced activities are attributed to the interfacial transfer of photogenerated electrons and holes between g-C3N4 and In2O3, leading to effective charge separation on both parts. Further studies by transient PL spectroscopy confirm that the In2O3-g-C3N4 heterojunctions remarkably promote the charge transfer efficiency, thereby increase the charge carrier lifetime for the photocatalytic reactions. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2014, "Volume": 147, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 940, "End Page": 946, "Article Number": null, "DOI": "10.1016/j.apcatb.2013.10.029", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2013.10.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330489400103", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Wu, ZS; Zhang, X; Li, LW; Li, YY; Xu, HM; Li, XX; Yu, XL; Zhang, ZS; Liang, YY; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xing; Wu, Zishan; Zhang, Xiao; Li, Liewu; Li, Yanyan; Xu, Haomin; Li, Xiaoxiao; Yu, Xiaolu; Zhang, Zisheng; Liang, Yongye; Wang, Hailiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective and active CO2 reduction electro-catalysts based on cobalt phthalocyanine/carbon nullotube hybrid structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of carbon dioxide with renewable energy is a sustainable way of producing carbon-neutral fuels. However, developing active, selective and stable electrocatalysts is challenging and entails material structure design and tailoring across a range of length scales. Here we report a cobalt-phthalocyanine-based high-performance carbon dioxide reduction electrocatalyst material developed with a combined nulloscale and molecular approach. On the nulloscale, cobalt phthalocyanine (CoPc) molecules are uniformly anchored on carbon nullotubes to afford substantially increased current density, improved selectivity for carbon monoxide, and enhanced durability. On the molecular level, the catalytic performance is further enhanced by introducing cyano groups to the CoPc molecule. The resulting hybrid catalyst exhibits 495% Faradaic efficiency for carbon monoxide production in a wide potential range and extraordinary catalytic activity with a current density of 15.0mAcm(-2) and a turnover frequency of 4.1 s(-1) at the overpotential of 0.52V in a near-neutral aqueous solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1195, "Times Cited, All Databases": 1246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14675, "DOI": "10.1038/ncomms14675", "DOI Link": "http://dx.doi.org/10.1038/ncomms14675", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395727800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, SF; Choi, SI; Lu, N; Roling, LT; Herron, JA; Zhang, L; Park, J; Wang, JG; Kim, MJ; Xie, ZX; Mavrikakis, M; Xia, YN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Shuifen; Choi, Sang-Il; Lu, Ning; Roling, Luke T.; Herron, Jeffrey A.; Zhang, Lei; Park, Jinho; Wang, Jinguo; Kim, Moon J.; Xie, Zhaoxiong; Mavrikakis, Manos; Xia, Younull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Layer-by-Layer Deposition of Pt on Pd nullocubes for Catalysts with Enhanced Activity and Durability toward Oxygen Reduction", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An effective strategy for reducing the Pt content while retaining the activity of a Pt-based catalyst is to deposit the Pt atoms as ultrathin skins of only a few atomic layers thick on nulloscale substrates made of another metal. During deposition, however, the Pt atoms often take an island growth mode because of a strong bonding between Pt atoms. Here we report a versatile route to the conformal deposition of Pt as uniform, ultrathin shells on Pd nullocubes in a solution phase. The introduction of the Pt precursor at a relatively slow rate and high temperature allowed the deposited Pt atoms to spread across the entire surface of a Pd nullocube to generate a uniform shell. The thickness of the Pt shell could be controlled from one to six atomic layers by varying the amount of Pt precursor added into the system. Compared to a commercial Pt/C catalyst, the Pd@Pt-nL (n = 1-6) core-shell nullocubes showed enhancements in specific activity and durability toward the oxygen reduction reaction (ORR). Density functional theory (DFT) calculations on model (100) surfaces suggest that the enhancement in specific activity can be attributed to the weakening of OH binding through ligand and strain effects, which, in turn, increases the rate of OH hydrogenation. A volcano-type relationship between the ORR specific activity and the number of Pt atomic layers was derived, in good agreement with the experimental results. Both theoretical and experimental studies indicate that the ORR specific activity was maximized for the catalysts based on Pd@Pt2-3L nullocubes. Because of the reduction in Pt content used and the enhancement in specific activity, the Pd@Pt-1L nullocubes showed a Pt mass activity with almost three-fold enhancement relative to the Pt/C catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3570, "End Page": 3576, "Article Number": null, "DOI": "10.1021/nl501205j", "DOI Link": "http://dx.doi.org/10.1021/nl501205j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, WR; Zhang, CR; Jiang, W; Li, FF; Liang, RP; Liu, JW; Qiu, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Wei-Rong; Zhang, Cheng-Rong; Jiang, Wei; Li, Fang-Fang; Liang, Ru-Ping; Liu, Juewen; Qiu, Jian-Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regenerable and stable sp2 carbon-conjugated covalent organic frameworks for selective detection and extraction of uranium", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uranium is a key element in the nuclear industry, but its unintended leakage has caused health and environmental concerns. Here we report a sp(2) carbon-conjugated fluorescent covalent organic framework (COF) named TFPT-BTAN-AO with excellent chemical, thermal and radiation stability is synthesized by integrating triazine-based building blocks with amidoxime-substituted linkers. TFPT-BTAN-AO shows an exceptional UO22+ adsorption capacity of 427mgg(-1) attributable to the abundant selective uranium-binding groups on the highly accessible pore walls of open 1D channels. In addition, it has an ultra-fast response time (2s) and an ultra-low detection limit of 6.7nM UO22+ suitable for on-site and real-time monitoring of UO22+, allowing not only extraction but also monitoring the quality of the extracted water. This study demonstrates great potential of fluorescent COFs for radionuclide detection and extraction. By rational designing target ligands, this strategy can be extended to the detection and extraction of other contaminullts. Porous materials for uranium capture have been developed in the past, but materials for simultaneous uranium capture and detection are scarce. Here the authors develop a stable covalent organic framework capable of adsorbing and detecting uranyl ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 436, "DOI": "10.1038/s41467-020-14289-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14289-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558877100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, LZ; Ge, L; Liu, HL; Jiang, ZR; Jia, Y; Li, ZH; Yang, DJ; Hocking, RK; Li, MR; Zhang, LZ; Wang, X; Yao, XD; Zhu, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Linzhou; Ge, Lei; Liu, Hongli; Jiang, Zongrui; Jia, Yi; Li, Zhiheng; Yang, Dongjiang; Hocking, Rosalie K.; Li, Mengran; Zhang, Longzhou; Wang, Xin; Yao, Xiangdong; Zhu, Zhonghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Surfactant-Free and Scalable General Strategy for Synthesizing Ultrathin Two-Dimensional Metal-Organic Framework nullosheets for the Oxygen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic framework (MOFs) two-dimensional (2D) nullosheets have many coordinatively unsaturated metal sites that act as active centres for catalysis. To date, limited numbers of 2D MOFs nullosheets can be obtained through top-down or bottom-up synthesis strategies. Herein, we report a 2D oxide sacrifice approach (2dOSA) to facilely synthesize ultrathin MOF-74 and BTC MOF nullosheets with a flexible combination of metal sites, which cannot be obtained through the delamination of their bulk counterparts (top-down) or the conventional solvothermal method (bottom-up). The ultrathin iron-cobalt MOF-74 nullosheets prepared are only 2.6 nm thick. The sample enriched with surface coordinatively unsaturated metal sites, exhibits a significantly higher oxygen evolution reaction reactivity than bulk FeCo MOF-74 particles and the state-of-the-art MOF catalyst. It is believed that this 2dOSA could provide a new and simple way to synthesize various ultrathin MOF nullosheets for wide applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2019, "Volume": 58, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13565, "End Page": 13572, "Article Number": null, "DOI": "10.1002/anie.201907600", "DOI Link": "http://dx.doi.org/10.1002/anie.201907600", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000480977700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TF; Li, GR; Liang, YM; Cheng, TY; Dai, J; Yang, XX; Liu, BY; Zeng, ZD; Huang, ZL; Luo, YW; Xie, T; Yang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tiefeng; Li, Guorui; Liang, Yiming; Cheng, Tingyu; Dai, Jing; Yang, Xuxu; Liu, Bangyuan; Zeng, Zedong; Huang, Zhilong; Luo, Yingwu; Xie, Tao; Yang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast-moving soft electronic fish", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft robots driven by stimuli-responsive materials have unique advantages over conventional rigid robots, especially in their high adaptability for field exploration and seamless interaction with humans. The grand challenge lies in achieving self-powered soft robots with high mobility, environmental tolerance, and long endurance. We are able to advance a soft electronic fish with a fully integrated onboard system for power and remote control. Without any motor, the fish is driven solely by a soft electroactive structure made of dielectric elastomer and ionically conductive hydrogel. The electronic fish can swim at a speed of 6.4 cm/s (0.69 body length per second), which is much faster than previously reported untethered soft robotic fish driven by soft responsive materials. The fish shows consistent performance in a wide temperature range and permits stealth sailing due to its nearly transparent nature. Furthermore, the fish is robust, as it uses the surrounding water as the electric ground and can operate for 3 hours with one single charge. The design principle can be potentially extended to a variety of flexible devices and soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 701, "Times Cited, All Databases": 782, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602045", "DOI": "10.1126/sciadv.1602045", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morales-Guio, CG; Cave, ER; Nitopi, SA; Feaster, JT; Wang, L; Kuhl, KP; Jackson, A; Johnson, NC; Abram, DN; Hatsukade, T; Hahn, C; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morales-Guio, Carlos G.; Cave, Etosha R.; Nitopi, Stephanie A.; Feaster, Jeremy T.; Wang, Lei; Kuhl, Kendra P.; Jackson, Ariel; Johnson, Natalie C.; Abram, David N.; Hatsukade, Toru; Hahn, Christopher; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of materials for the electrochemical transformation of carbon dioxide into liquid fuels has the potential to impact large-scale storage of renewable energies and reduce carbon emissions. Here, we report the discovery of an electrocatalyst composed of gold nulloparticles on a polycrystalline copper foil (Au/Cu) that is highly active for CO2 reduction to alcohols. At low overpotentials, the Au/Cu electrocatalyst is over 100 times more selective for the formation of products containing C-C bonds versus methane or methanol, largely favouring the generation of alcohols over hydrocarbons. A combination of electrochemical testing and transport modelling supports the hypothesis that CO2 reduction on gold generates a high CO concentration on nearby copper, where CO is further reduced to alcohols such as ethanol and n-propanol under locally alkaline conditions. The bimetallic Au/Cu electrocatalyst exhibits synergistic activity and selectivity superior to gold, copper or AuCu alloys, and opens new possibilities for the development of CO2 reduction electrodes exploiting tandem catalysis mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 586, "Times Cited, All Databases": 634, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 1, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 764, "End Page": 771, "Article Number": null, "DOI": "10.1038/s41929-018-0139-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0139-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447080500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sagara, Y; Yamane, S; Mitani, M; Weder, C; Kato, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sagara, Yoshimitsu; Yamane, Shogo; Mitani, Masato; Weder, Christoph; Kato, Takashi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanoresponsive Luminescent Molecular Assemblies: An Emerging Class of Materials", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The possibility to change the molecular assembled structures of organic and organometallic materials through mechanical stimulation is emerging as a general and powerful concept for the design of functional materials. In particular, the photophysical properties such as photoluminescence color, quantum yield, and emission lifetime of organic and organometallic fluorophores can significantly depend on the molecular packing, enabling the development of molecular materials with mechanoresponsive luminescence characteristics. Indeed, an increasing number of studies have shown in recent years that mechanical force can be utilized to change the molecular arrangement, and thereby the optical response, of luminescent molecular assemblies of -conjugated organic or organometallic molecules. Here, the development of such mechanoresponsive luminescent (MRL) molecular assemblies consisting of organic or organometallic molecules is reviewed and emerging trends in this research field are summarized. After a brief introduction of mechanoresponsive luminescence observed in molecular assemblies, the concept of luminescent molecular domino is introduced, before molecular materials that show turn-on/off of photoluminescence in response to mechanical stimulation are reviewed. Mechanically stimulated multicolor changes and water-soluble MRL materials are also highlighted and approaches that combine the concept of MRL molecular assemblies with other materials types are presented in the last part of this progress report.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 769, "Times Cited, All Databases": 784, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2016, "Volume": 28, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1073, "End Page": 1095, "Article Number": null, "DOI": "10.1002/adma.201502589", "DOI Link": "http://dx.doi.org/10.1002/adma.201502589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370062100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avci, C; Imaz, I; Carné-Sánchez, A; Pariente, JA; Tasios, N; Pérez-Carvajal, J; Alonso, MI; Blanco, A; Dijkstra, M; López, C; Maspoch, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avci, Civan; Imaz, Inhar; Carne-Sanchez, Arnau; Angel Pariente, Jose; Tasios, Nikos; Perez-Carvajal, Javier; Isabel Alonso, Maria; Blanco, Alvaro; Dijkstra, Marjolein; Lopez, Cefe; Maspoch, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembly of polyhedral metal-organic framework particles into three-dimensional ordered superstructures", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-assembly of particles into long-range, three-dimensional, ordered superstructures is crucial for the design of a variety of materials, including plasmonic sensing materials, energy or gas storage systems, catalysts and photonic crystals. Here, we have combined experimental and simulation data to show that truncated rhombic dodecahedral particles of the metal-organic framework (MOF) ZIF-8 can self-assemble into millimetre-sized superstructures with an underlying three-dimensional rhombohedral lattice that behave as photonic crystals. Those superstructures feature a photonic bandgap that can be tuned by controlling the size of the ZIF-8 particles and is also responsive to the adsorption of guest substances in the micropores of the ZIF-8 particles. In addition, superstructures with different lattices can also be assembled by tuning the truncation of ZIF-8 particles, or by using octahedral UiO-66 MOF particles instead. These well-ordered, submicrometre-sized superstructures might ultimately facilitate the design of three-dimensional photonic materials for applications in sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 84, "Article Number": null, "DOI": "10.1038/NCHEM.2875", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2875", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423143500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pang, SY; Wong, YT; Yuan, SG; Liu, Y; Tsang, MK; Yang, ZB; Huang, HT; Wong, WT; Hao, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pang, Sin-Yi; Wong, Yuen-Ting; Yuan, Shuoguo; Liu, Yan; Tsang, Ming-Kiu; Yang, Zhibin; Huang, Haitao; Wong, Wing-Tak; Hao, Jianhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal Strategy for HF-Free Facile and Rapid Synthesis of Two-dimensional MXenes as Multifunctional Energy Materials", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional MXenes are promising for various energy-related applications such as energy storage devices and electrocatalysis of water-splitting. MXenes prepared from hydrofluoric (HF) acid etching have been widely reported. Nonetheless, the acute toxicity of HF acid impedes the large-scale fabrication of MXenes and their wide utilization in energy-related applications. It is thus greatly encouraging to explore a more innocuous protocol for MXenes synthesis. Thereby, a universal strategy based on thermal-assisted electrochemical etching route is developed to synthesize MXenes (e.g., Ti2CTx, Cr2CTx, and V2CTx). Furthermore, the cobalt ion doped MXenes show an exceptionally enhanced capability of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activity, demonstrating their multifunctionalities, which is comparable to the commercialized catalysts. Moreover, we successfully exploited our MXenes as cathodes for the novel aqueous rechargeable battery, with proficient retention and excellent electrical output performance. This work paves a nontoxic and HF-free route to prepare various MXenes and demonstrates practical applications of the materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 141, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9610, "End Page": 9616, "Article Number": null, "DOI": "10.1021/jacs.9b02578", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b02578", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471835600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, ZS; Luo, YF; Tang, YX; Wei, JQ; Zhu, ZQ; Zhou, XR; Li, WL; Zeng, Y; Zhang, W; Zhang, YY; Qi, DP; Pan, SW; Loh, XJ; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Zhisheng; Luo, Yifei; Tang, Yuxin; Wei, Jiaqi; Zhu, Zhiqiang; Zhou, Xinran; Li, Wenlong; Zeng, Yi; Zhang, Wei; Zhang, Yanyan; Qi, Dianpeng; Pan, Shaowu; Loh, Xian Jun; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Editable Supercapacitors with Customizable Stretchability Based on Mechanically Strengthened Ultralong MnO2 nullowire Composite", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although some progress has been made on stretchable supercapacitors, traditional stretchable supercapacitors fabricated by predesigning structured electrodes for device assembling still lack the device-level editability and programmability. To adapt to wearable electronics with arbitrary configurations, it is highly desirable to develop editable supercapacitors that can be directly transferred into desirable shapes and stretchability. In this work, editable supercapacitors for customizable shapes and stretchability using electrodes based on mechanically strengthened ultralong MnO2 nullowire composites are developed. A supercapacitor edited with honeycomb-like structure shows a specific capacitance of 227.2 mF cm(-2) and can be stretched up to 500% without degradation of electrochemical performance, which is superior to most of the state-of-the-art stretchable supercapacitors. In addition, it maintains nearly 98% of the initial capacitance after 10 000 stretch-and-release cycles under 400% tensile strain. As a representative of concept for system integration, the editable supercapacitors are integrated with a strain sensor, and the system exhibits a stable sensing performance even under arm swing. Being highly stretchable, easily programmable, as well as connectable in series and parallel, an editable supercapacitor with customizable stretchability is promising to produce stylish energy storage devices to power various portable, stretchable, and wearable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2018, "Volume": 30, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1704531, "DOI": "10.1002/adma.201704531", "DOI Link": "http://dx.doi.org/10.1002/adma.201704531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419454800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, NX; Tao, SX; Chen, YH; Niu, XX; Onwudinullti, CK; Hu, C; Qiu, ZW; Xu, ZQ; Zheng, GHJ; Wang, LG; Zhang, Y; Li, L; Liu, HF; Lun, YZ; Hong, JW; Wang, XY; Liu, YQ; Xie, HP; Gao, YL; Bai, Y; Yang, SH; Brocks, G; Chen, Q; Zhou, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Nengxu; Tao, Shuxia; Chen, Yihua; Niu, Xiuxiu; Onwudinullti, Chidozie K.; Hu, Chen; Qiu, Zhiwen; Xu, Ziqi; Zheng, Guanhaojie; Wang, Ligang; Zhang, Yu; Li, Liang; Liu, Huifen; Lun, Yingzhuo; Hong, Jiawang; Wang, Xueyun; Liu, Yuquan; Xie, Haipeng; Gao, Yongli; Bai, Yang; Yang, Shihe; Brocks, Geert; Chen, Qi; Zhou, Huanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects play an important role in the degradation processes of hybrid halide perovskite absorbers, impeding their application for solar cells. Among all defects, halide anion and organic cation vacancies are ubiquitous, promoting ion diffusion and leading to thin-film decomposition at surfaces and grain boundaries. Here, we employ fluoride to simultaneously passivate both anion and cation vacancies, by taking advantage of the extremely high electronegativity of fluoride. We obtain a power conversion efficiency of 21.46% (and a certified 21.3%-efficient cell) in a device based on the caesium, methylammonium (MA) and for-mamidinium (FA) triple-cation perovskite (Cs(0.05)FA(0.54)MA(0.41))Pb(I0.98Br0.02)(3) treated with sodium fluoride. The device retains 90% of its original power conversion efficiency after 1,000 h of operation at the maximum power point. With the help of first-principles density functional theory calculations, we argue that the fluoride ions suppress the formation of halide anion and organic cation vacancies, through a unique strengthening of the chemical bonds with the surrounding lead and organic cations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 951, "Times Cited, All Databases": 992, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 408, "End Page": 415, "Article Number": null, "DOI": "10.1038/s41560-019-0382-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0382-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467965700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HM; Lin, CC; Luo, WQ; Shu, ST; Liu, ZG; Liu, YS; Kong, JT; Ma, E; Cao, YG; Liu, RS; Chen, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Haomiao; Lin, Chun Che; Luo, Wenqin; Shu, Situan; Liu, Zhuguang; Liu, Yongsheng; Kong, Jintao; Ma, En; Cao, Yongge; Liu, Ru-Shi; Chen, Xueyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mn4+-activated fluoride compounds, as an alternative to commercial (oxy) nitride phosphors, are emerging as a new class of non-rare-earth red phosphors for high-efficacy warm white LEDs. Currently, it remains a challenge to synthesize these phosphors with high photoluminescence quantum yields through a convenient chemical route. Herein we propose a general but convenient strategy based on efficient cation exchange reaction, which had been originally regarded only effective in synthesizing nullo-sized materials before, for the synthesis of Mn4+-activated fluoride microcrystals such as K2TiF6, K2SiF6, NaGdF4 and NaYF4. Particularly we achieve a photoluminescence quantum yield as high as 98% for K2TiF6:Mn4+. By employing it as red phosphor, we fabricate a high-performance white LED with low correlated colour temperature (3,556 K), high-colour-rendering index (R-a = 81) and luminous efficacy of 116 lm W-1. These findings show great promise of K2TiF6:Mn4+ as a commercial red phosphor in warm white LEDs, and open up new avenues for the exploration of novel non-rare-earth red emitting phosphors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 948, "Times Cited, All Databases": 974, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4312, "DOI": "10.1038/ncomms5312", "DOI Link": "http://dx.doi.org/10.1038/ncomms5312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340615500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, F; Xu, ZY; Liang, QF; Li, HF; Peng, LQ; Wu, MM; Zhao, XL; Cui, X; Ruan, CS; Liu, WG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Fei; Xu, Ziyang; Liang, Qingfei; Li, Haofei; Peng, Liuqi; Wu, Mingming; Zhao, Xiaoli; Cui, Xu; Ruan, Changshun; Liu, Wenguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Osteochondral Regeneration with 3D-Printed Biodegradable High-Strength Supramolecular Polymer Reinforced-Gelatin Hydrogel Scaffolds", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomacromolecules with poor mechanical properties cannot satisfy the stringent requirement for load-bearing as bioscaffolds. Herein, a biodegradable high-strength supramolecular polymer strengthened hydrogel composed of cleavable poly(N-acryloyl 2-glycine) (PACG) and methacrylated gelatin (GelMA) (PACG-GelMA) is successfully constructed by photo-initiated polymerization. Introducing hydrogen bond-strengthened PACG contributes to a significant increase in the mechanical strengths of gelatin hydrogel with a high tensile strength (up to 1.1 MPa), outstanding compressive strength (up to 12.4 MPa), large Young's modulus (up to 320 kPa), and high compression modulus (up to 837 kPa). In turn, the GelMA chemical crosslinking could stabilize the temporary PACG network, showing tunable biodegradability by adjusting ACG/GelMA ratios. Further, a biohybrid gradient scaffold consisting of top layer of PACG-GelMA hydrogel-Mn2+ and bottom layer of PACG-GelMA hydrogel-bioactive glass is fabricated for repair of osteochondral defects by a 3D printing technique. In vitro biological experiments demonstrate that the biohybrid gradient hydrogel scaffold not only supports cell attachment and spreading but also enhances gene expression of chondrogenic-related and osteogenic-related differentiation of human bone marrow stem cells. Around 12 weeks after in vivo implantation, the biohybrid gradient hydrogel scaffold significantly facilitates concurrent regeneration of cartilage and subchondral bone in a rat model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2019, "Volume": 6, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900867, "DOI": "10.1002/advs.201900867", "DOI Link": "http://dx.doi.org/10.1002/advs.201900867", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479063700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HB; Miao, JW; Hung, SF; Chen, JZ; Tao, HB; Wang, XZ; Zhang, LP; Chen, R; Gao, JJ; Chen, HM; Dai, LM; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu; Chen, Jiazang; Tao, Hua Bing; Wang, Xizu; Zhang, Liping; Chen, Rong; Gao, Jiajian; Chen, Hao Ming; Dai, Liming; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are critical to renewable energy conversion and storage technologies. Heteroatom-doped carbon nullomaterials have been reported to be efficient metal-free electrocatalysts for ORR in fuel cells for energy conversion, as well as ORR and OER in metal-air batteries for energy storage. We reported that metal-free three-dimensional (3D) graphene nulloribbon networks (N-GRW) doped with nitrogen exhibited superb bifunctional electrocatalytic activities for both ORR and OER, with an excellent stability in alkaline electrolytes (for example, KOH). For the first time, it was experimentally demonstrated that the electron-donating quaternary N sites were responsible for ORR, whereas the electron-withdrawing pyridinic N moieties in N-GRW served as active sites for OER. The unique 3D nulloarchitecture provided a high density of the ORR and OER active sites and facilitated the electrolyte and electron transports. As a result, the as-prepared N-GRW holds great potential as a low-cost, highly efficient air cathode in rechargeable metal-air batteries. Rechargeable zinc-air batteries with the N-GRW air electrode in a two-electrode configuration exhibited an open-circuit voltage of 1.46 V, a specific capacity of 873 mAh g(-1), and a peak power density of 65 mW cm(-2), which could be continuously charged and discharged with an excellent cycling stability. Our work should open up new avenues for the development of various carbon-based metal-free bifunctional electrocatalysts of practical significance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1086, "Times Cited, All Databases": 1123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501122", "DOI": "10.1126/sciadv.1501122", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380072100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, F; Tang, ZW; Huang, SQ; Chen, LY; Liang, YR; Mai, WC; Zhong, H; Fu, RW; Wu, DC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Fei; Tang, Zhiwei; Huang, Siqi; Chen, Luyi; Liang, Yeru; Mai, Weicong; Zhong, Hui; Fu, Ruowen; Wu, Dingcai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile synthesis of ultrahigh-surface-area hollow carbon nullospheres for enhanced adsorption and energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exceptionally large surface area and well-defined nullostructure are both critical in the field of nulloporous carbons for challenging energy and environmental issues. The pursuit of ultrahigh surface area while maintaining definite nullostructure remains a formidable challenge because extensive creation of pores will undoubtedly give rise to the damage of nullostructures, especially below 100 nm. Here we report that high surface area of up to 3,022 m(2) g(-1) can be achieved for hollow carbon nullospheres with an outer diameter of 69 nm by a simple carbonization procedure with carefully selected carbon precursors and carbonization conditions. The tailor-made pore structure of hollow carbon nullospheres enables target-oriented applications, as exemplified by their enhanced adsorption capability towards organic vapours, and electrochemical performances as electrodes for super-capacitors and sulphur host materials for lithium-sulphur batteries. The facile approach may open the doors for preparation of highly porous carbons with desired nullostructure for numerous applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 604, "Times Cited, All Databases": 630, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7221, "DOI": "10.1038/ncomms8221", "DOI Link": "http://dx.doi.org/10.1038/ncomms8221", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357167500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; McKeon, L; Kremer, MP; Park, SH; Ronull, O; Seral-Ascaso, A; Barwich, S; Coileáin, CO; McEvoy, N; Nerl, HC; Anasori, B; Coleman, JN; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuanfang (John); McKeon, Lorcan; Kremer, Matthias P.; Park, Sang-Hoon; Ronull, Oskar; Seral-Ascaso, Andres; Barwich, Sebastian; Coileain, Cormac O.; McEvoy, Niall; Nerl, Hannah C.; Anasori, Babak; Coleman, Jonathan N.; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive-free MXene inks and direct printing of micro-supercapacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct printing of functional inks is critical for applications in diverse areas including electrochemical energy storage, smart electronics and healthcare. However, the available printable ink formulations are far from ideal. Either surfactants/additives are typically involved or the ink concentration is low, which add complexity to the manufacturing and compromises the printing resolution. Here, we demonstrate two types of two-dimensional titanium carbide (Ti3C2Tx) MXene inks, aqueous and organic in the absence of any additive or binary-solvent systems, for extrusion printing and inkjet printing, respectively. We show examples of all-MXene-printed structures, such as micro-supercapacitors, conductive tracks and ohmic resistors on untreated plastic and paper substrates, with high printing resolution and spatial uniformity. The volumetric capacitance and energy density of the all-MXene-printed micro-supercapacitors are orders of magnitude greater than existing inkjet/extrusion-printed active materials. The versatile direct-ink-printing technique highlights the promise of additive-free MXene inks for scalable fabrication of easy-to-integrate components of printable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 802, "Times Cited, All Databases": 841, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1795, "DOI": "10.1038/s41467-019-09398-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09398-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464976500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DD; Wu, HH; Phua, SZF; Yang, GB; Lim, WQ; Gu, L; Qian, C; Wang, HB; Guo, Z; Chen, HZ; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongdong; Wu, Huihui; Phua, Soo Zeng Fiona; Yang, Guangbao; Lim, Wei Qi; Gu, Long; Qian, Cheng; Wang, Haibao; Guo, Zhen; Chen, Hongzhong; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembled single-atom nullozyme for enhanced photodynamic therapy treatment of tumor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hypoxia of solid tumor compromises the therapeutic outcome of photodynamic therapy (PDT) that relies on localized O-2 molecules to produce highly cytotoxic singlet oxygen (O-1(2)) species. Herein, we present a safe and versatile self-assembled PDT nulloagent, i.e., OxgeMCC-r single-atom enzyme (SAE), consisting of single-atom ruthenium as the active catalytic site anchored in a metal-organic framework Mn-3[Co(CN)(6)](2) with encapsulated chlorin e6 (Ce6), which serves as a catalase-like nullozyme for oxygen generation. Coordination-driven self-assembly of organic linkers and metal ions in the presence of a biocompatible polymer generates a nulloscale network that adaptively encapsulates Ce6. The resulted OxgeMCC-r SAE possesses well-defined morphology, uniform size distribution and high loading capacity. When conducting the in situ O-2 generation through the reaction between endogenous H2O2 and single-atom Ru species of OxgeMCC-r SAE, the hypoxia in tumor microenvironment is relieved. Our study demonstrates a promising self-assembled nullozyme with highly efficient single-atom catalytic sites for cancer treatment. The hypoxic microenvironment in solid tumors limits the efficacy of photodynamic therapy (PDT) since oxygen is necessary to produce high cytotoxic singlet oxygen species. Here, the authors develop an improved self-assembled single-atom nullozyme which allows oxygen generation to enhance PDT efficacy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 357, "DOI": "10.1038/s41467-019-14199-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14199-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514637800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Pan, YH; Yang, R; Bao, LH; Meng, L; Luo, HL; Cai, YQ; Liu, GD; Zhao, WJ; Zhou, Z; Wu, LM; Zhu, ZL; Huang, M; Liu, LW; Liu, L; Cheng, P; Wu, KH; Tian, SB; Gu, CZ; Shi, YG; Guo, YF; Cheng, ZG; Hu, JP; Zhao, L; Yang, GH; Sutter, E; Sutter, P; Wang, YL; Ji, W; Zhou, XJ; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yuan; Pan, Yu-Hao; Yang, Rong; Bao, Li-Hong; Meng, Lei; Luo, Hai-Lan; Cai, Yong-Qing; Liu, Guo-Dong; Zhao, Wen-Juan; Zhou, Zhang; Wu, Liang-Mei; Zhu, Zhi-Li; Huang, Ming; Liu, Li-Wei; Liu, Lei; Cheng, Peng; Wu, Ke-Hui; Tian, Shi-Bing; Gu, Chang-Zhi; Shi, You-Guo; Guo, Yan-Feng; Cheng, Zhi Gang; Hu, Jiang-Ping; Zhao, Lin; Yang, Guan-Hua; Sutter, Eli; Sutter, Peter; Wang, Ye-Liang; Ji, Wei; Zhou, Xing-Jiang; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal mechanical exfoliation of large-area 2D crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials provide extraordinary opportunities for exploring phenomena arising in atomically thin crystals. Beginning with the first isolation of graphene, mechanical exfoliation has been a key to provide high-quality two-dimensional materials, but despite improvements it is still limited in yield, lateral size and contamination. Here we introduce a contamination-free, one-step and universal Au-assisted mechanical exfoliation method and demonstrate its effectiveness by isolating 40 types of single-crystalline monolayers, including elemental two-dimensional crystals, metal-dichalcogenides, magnets and superconductors. Most of them are of millimeter-size and high-quality, as shown by transfer-free measurements of electron microscopy, photo spectroscopies and electrical transport. Large suspended two-dimensional crystals and heterojunctions were also prepared with high-yield. Enhanced adhesion between the crystals and the substrates enables such efficient exfoliation, for which we identify a gold-assisted exfoliation method that underpins a universal route for producing large-area monolayers and thus supports studies of fundamental properties and potential application of two-dimensional materials. Here, the authors develop a one-step, contamination-free, Au-assisted mechanical exfoliation method for 2D materials, and isolate 40 types of single-crystalline monolayers, including elemental 2D crystals, metal-dichalcogenides, magnets and superconductors with millimetre size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 687, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2453, "DOI": "10.1038/s41467-020-16266-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16266-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Z; Mogni, LV; Miller, EC; Railsback, JG; Barnett, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Zhan; Mogni, Liliana V.; Miller, Elizabeth C.; Railsback, Justin G.; Barnett, Scott A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A perspective on low-temperature solid oxide fuel cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article provides a perspective on solid oxide fuel cells operating at low temperature, defined here to be the range from similar to 400 degrees C to 650 degrees C. These low-temperature solid oxide fuel cells (LT-SOFCs) have seen considerable research and development and are widely viewed as the next generation technology, following the 650-850 degrees C SOFCs that are currently undergoing commercialization. LT-SOFCs have potential advantages for conventional SOFC applications such as stationary power generation, and may be viable for new portable and transportation power applications, along with electrolytic fuel production and energy storage. The characteristics of electrolyte and electrode materials are reviewed, with a focus on materials that have demonstrated good properties and cell performance at low temperature. Only oxygen-ion-conducting electrolytes are considered here. Anode materials are discussed, primarily the various Ni-cermet anode compositions that yield good low-temperature performance. Mixed ionically and electronically conducting cathode materials are described in detail, reflecting the extensive research activity that has aimed at providing useful oxygen reduction kinetics at low operating temperature. Cell design, materials compatibility, processing methods, and resulting microstructures are discussed, along with their role in determining cell performance. Results from state of the art LT-SOFCs are presented, and future prospects are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 625, "Times Cited, All Databases": 659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1602, "End Page": 1644, "Article Number": null, "DOI": "10.1039/c5ee03858h", "DOI Link": "http://dx.doi.org/10.1039/c5ee03858h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375699500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, DL; Zhu, C; Song, M; Liang, P; Zhang, X; Tiep, NH; Zhao, HF; Wang, J; Wang, RM; Zhang, H; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Dongliang; Zhu, Changrong (Rose); Song, Ming; Liang, Pei; Zhang, Xiao; Nguyen Huy Tiep; Zhao, Haofei; Wang, John; Wang, Rongming; Zhang, Hua; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A High-Rate and Stable Quasi-Solid-State Zinc-Ion Battery with Novel 2D Layered Zinc Orthovanadate Array", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc-ion batteries are under current research focus because of their uniqueness in low cost and high safety. However, it is still desirable to improve the rate performance by improving the Zn2+ (de)intercalation kinetics and long-cycle stability by eliminating the dendrite formation problem. Herein, the first paradigm of a high-rate and ultrastable flexible quasi-solid-state zinc-ion battery is constructed from a novel 2D ultrathin layered zinc orthovanadate array cathode, a Zn array anode supported by a conductive porous graphene foam, and a gel electrolyte. The nulloarray structure for both electrodes assures the high rate capability and alleviates the dendrite growth. The flexible Zn-ion battery has a depth of discharge of approximate to 100% for the cathode and 66% for the anode, and delivers an impressive high-rate of 50 C (discharge in 60 s), long-term durability of 2000 cycles at 20 C, and unprecedented energy density approximate to 115 Wh kg(-1), together with a peak power density approximate to 5.1 kW kg(-1) (calculation includes masses of cathode, anode, and current collectors). First principles calculations and quantitative kinetics analysis show that the high-rate and stable properties are correlated with the 2D fast ion-migration pathways and the introduced intercalation pseudocapacitance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 632, "Times Cited, All Databases": 655, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2018, "Volume": 30, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803181, "DOI": "10.1002/adma.201803181", "DOI Link": "http://dx.doi.org/10.1002/adma.201803181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440813300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XP; Li, Y; Li, XF; Song, DK; Min, P; Hu, C; Zhang, HB; Koratkar, N; Yu, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiao-Peng; Li, Yue; Li, Xiaofeng; Song, Dekui; Min, Peng; Hu, Chen; Zhang, Hao-Bin; Koratkar, Nikhil; Yu, Zhong-Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly sensitive, reliable and flexible piezoresistive pressure sensors featuring polyurethane sponge coated with MXene sheets", "Source Title": "JOURNAL OF COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible pressure sensors still face a great challenge to combine fast frequency response, wide pressure range, multiple detection modes, satisfactory mechanical and environmental stability, and simple fabrication process into a sensor. Herein, flexible piezoresistive pressure sensors are fabricated by treating the backbone of polyurethane (PU) sponge with chitosan (CS) to obtain positively charged CS@PU sponge, followed by dip-coating of negatively charged Ti3C2Tx MXene sheets. The resulting MXene@CS@PU sponge-based sensor provides a versatile sensing platform with potentials for detecting both small and large pressure signals. Due to the highly compressive resilience of the PU sponge and its polar interaction with the MXene sheets, the MXene@CS@PU sensor has high compressibility and stable piezoresistive response for compressive strains of up to 85% with a stress of 245.7 kPa, and it also exhibits a satisfactory reproducibility for 5000 compression-release cycles. Even after washing in water for 1 h, the sensor still shows good performances. With a rapid response time of only 19 ms and a low detection limit of 30 mu N corresponding to a pressure of 9 Pa, the MXene sponge sensor is promising for detecting human physiological signals and insect movements. In addition to the contact mode detection, the sponge sensor could detect voices and human breaths by a non-contact detection mode. (C) 2019 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2019, "Volume": 542, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 54, "End Page": 62, "Article Number": null, "DOI": "10.1016/j.jcis.2019.01.123", "DOI Link": "http://dx.doi.org/10.1016/j.jcis.2019.01.123", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461536400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Li, XL; Zhang, SL; Yang, FH; Zeng, XH; Zhang, S; Bo, GY; Wang, CS; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Li, Xiaolong; Zhang, Shilin; Yang, Fuhua; Zeng, Xiaohui; Zhang, Shuai; Bo, Guyue; Wang, Chunsheng; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Dendrite-Free Zinc Anodes for Advanced Aqueous Zinc Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn metal has been regarded as the most promising anode for aqueous batteries due to its high capacity, low cost, and environmental benignity. Zn anode still suffers, however, from low Coulombic efficiency due to the side reactions and dendrite growth in slightly acidic electrolytes. Here, the Zn plating/stripping mechanism is thoroughly investigated in 1 m ZnSO4 electrolyte, demonstrating that the poor performance of Zn metal in mild electrolyte should be ascribed to the formation of a porous by-product (Zn4SO4(OH)(6)center dot xH(2)O) layer and serious dendrite growth. To suppress the side reactions and dendrite growth, a highly viscoelastic polyvinyl butyral film, functioning as an artificial solid/electrolyte interphase (SEI), is homogeneously deposited on the Zn surface via a simple spin-coating strategy. This dense artificial SEI film not only effectively blocks water from the Zn surface but also guides the uniform stripping/plating of Zn ions underneath the film due to its good adhesion, hydrophilicity, ionic conductivity, and mechanical strength. Consequently, this side-reaction-free and dendrite-free Zn electrode exhibits high cycling stability and enhanced Coulombic efficiency, which also contributes to enhancement of the full-cell performance when it is coupled with MnO2 and LiFePO4 cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 756, "Times Cited, All Databases": 791, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 30, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001263, "DOI": "10.1002/adfm.202001263", "DOI Link": "http://dx.doi.org/10.1002/adfm.202001263", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537764400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hirscher, M; Yartys, VA; Baricco, M; von Colbe, JB; Blanchard, D; Bowman, RC; Broom, DP; Buckley, CE; Chang, F; Chen, P; Cho, YW; Crivello, JC; Cuevas, F; David, WIF; de Jongh, PE; Denys, RV; Dornheim, M; Felderhoff, M; Filinchuk, Y; Froudakis, GE; Grant, DM; Gray, EM; Hauback, BC; He, T; Humphries, TD; Jensen, TR; Kim, S; Kojima, Y; Latroche, M; Li, HW; Lototskyy, MV; Makepeace, JW; Moller, KT; Naheed, L; Ngene, P; Noréus, D; Nygård, MM; Orimo, SI; Paskevicius, M; Pasquini, L; Ravnsbæk, DB; Sofianos, MV; Udovic, TJ; Vegge, T; Walker, GS; Webb, CJ; Weidenthaler, C; Zlotea, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hirscher, Michael; Yartys, Volodymyr A.; Baricco, Marcello; von Colbe, Jose Bellosta; Blanchard, Didier; Bowman, Robert C., Jr.; Broom, Darren P.; Buckley, Craig E.; Chang, Fei; Chen, Ping; Cho, Young Whan; Crivello, Jean-Claude; Cuevas, Fermin; David, William I. F.; de Jongh, Petra E.; Denys, Roman, V; Dornheim, Martin; Felderhoff, Michael; Filinchuk, Yaroslav; Froudakis, George E.; Grant, David M.; Gray, Evan MacA; Hauback, Bjorn C.; He, Teng; Humphries, Terry D.; Jensen, Torben R.; Kim, Sangryun; Kojima, Yoshitsugu; Latroche, Michel; Li, Hai-Wen; Lototskyy, Mykhaylo, V; Makepeace, Joshua W.; Moller, Kasper T.; Naheed, Lubna; Ngene, Peter; Noreus, Dag; Nygard, Magnus Moe; Orimo, Shin-ichi; Paskevicius, Mark; Pasquini, Luca; Ravnsbaek, Dorthe B.; Sofianos, M. Veronica; Udovic, Terrence J.; Vegge, Tejs; Walker, Gavin S.; Webb, Colin J.; Weidenthaler, Claudia; Zlotea, Claudia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Materials for hydrogen-based energy storage - past, recent progress and future outlook", "Source Title": "JOURNAL OF ALLOYS AND COMPOUNDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Globally, the accelerating use of renewable energy sources, enabled by increased efficiencies and reduced costs, and driven by the need to mitigate the effects of climate change, has significantly increased research in the areas of renewable energy production, storage, distribution and end-use. Central to this discussion is the use of hydrogen, as a clean, efficient energy vector for energy storage. This review, by experts of Task 32, Hydrogen-based Energy Storage of the International Energy Agency, Hydrogen TCP, reports on the development over the last 6 years of hydrogen storage materials, methods and techniques, including electrochemical and thermal storage systems. An overview is given on the background to the various methods, the current state of development and the future prospects. The following areas are covered; porous materials, liquid hydrogen carriers, complex hydrides, intermetallic hydrides, electrochemical storage of energy, thermal energy storage, hydrogen energy systems and an outlook is presented for future prospects and research on hydrogen-based energy storage. (C) 2020 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 638, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2020, "Volume": 827, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 153548, "DOI": "10.1016/j.jallcom.2019.153548", "DOI Link": "http://dx.doi.org/10.1016/j.jallcom.2019.153548", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520405900065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Dong, MY; Huang, WJ; Gao, JC; Dai, K; Guo, J; Zheng, GQ; Liu, CT; Shen, CY; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hu; Dong, Mengyao; Huang, Wenju; Gao, Jiachen; Dai, Kun; Guo, Jiang; Zheng, Guoqiang; Liu, Chuntai; Shen, Changyu; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight conductive graphene/thermoplastic polyurethane foams with ultrahigh compressibility for piezoresistive sensing", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lightweight conductive porous graphene/thermoplastic polyurethane (TPU) foams with ultrahigh compressibility were successfully fabricated by using the thermal induced phase separation (TISP) technique. The density and porosity of the foams were calculated to be about 0.11 g cm(-3) and 90% owing to the porous structure. Compared with pure TPU foams, the addition of graphene could effectively increase the thickness of the cell wall and hinder the formation of small holes, leading to a robust porous structure with excellent compression property. Meanwhile, the cell walls with small holes and a dendritic structure were observed due to the flexibility of graphene, endowing the foam with special positive piezoresistive behaviors and peculiar response patterns with a deflection point during the cyclic compression. This could effectively enhance the identifiability of external compression strain when used as piezoresistive sensors. In addition, larger compression sensitivity was achieved at a higher compression rate. Due to high porosity and good elasticity of TPU, the conductive foams demonstrated good compressibility and stable piezoresistive sensing signals at a strain of up to 90%. During the cyclic piezoresistive sensing test under different compression strains, the conductive foam exhibited good recoverability and reproducibility after the stabilization of cyclic loading. All these suggest that the fabricated conductive foam possesses great potential to be used as lightweight, flexible, highly sensitive, and stable piezoresistive sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 619, "Times Cited, All Databases": 654, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2017, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 73, "End Page": 83, "Article Number": null, "DOI": "10.1039/c6tc03713e", "DOI Link": "http://dx.doi.org/10.1039/c6tc03713e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392423200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Xue, ZQ; Liu, QL; Jia, YL; Li, YL; Liu, K; Lin, YY; Liu, M; Li, GQ; Su, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yamei; Xue, Ziqian; Liu, Qinglin; Jia, Yaling; Li, Yinle; Liu, Kang; Lin, Yiyang; Liu, Min; Li, Guangqin; Su, Cheng-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36mV at a current density of 10mAcm(-2) in 1M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design. Developing high-performance, neutral-media H-2-evolution electrocatalysts is important for clean and sustainable hydrogen energy, yet rare, expensive elements are most active. Here, authors show that metal-organic frameworks modified with single ruthenium atoms as high-performances catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1369, "DOI": "10.1038/s41467-021-21595-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21595-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626168500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Inzana, JA; Olvera, D; Fuller, SM; Kelly, JP; Graeve, OA; Schwarz, EM; Kates, SL; Awad, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Inzana, Jason A.; Olvera, Diana; Fuller, Seth M.; Kelly, James P.; Graeve, Olivia A.; Schwarz, Edward M.; Kates, Stephen L.; Awad, Hani A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of composite calcium phosphate and collagen scaffolds for bone regeneration", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low temperature 3D printing of calcium phosphate scaffolds holds great promise for fabricating synthetic bone graft substitutes with enhanced performance over traditional techniques. Many design parameters, such as the binder solution properties, have yet to be optimized to ensure maximal biocompatibility and osteoconductivity with sufficient mechanical properties. This study tailored the phosphoric acid-based binder solution concentration to 8.75 wt% to maximize cytocompatibility and mechanical strength, with a supplementation of Tween 80 to improve printing. To further enhance the formulation, collagen was dissolved into the binder solution to fabricate collagen-calcium phosphate composites. Reducing the viscosity and surface tension through a physiologic heat treatment and Tween 80, respectively, enabled reliable thermal inkjet printing of the collagen solutions. Supplementing the binder solution with 1-2 wt% collagen significantly improved maximum flexural strength and cell viability. To assess the bone healing performance, we implanted 3D printed scaffolds into a critically sized murine femoral defect for 9 weeks. The implants were confirmed to be osteoconductive, with new bone growth incorporating the degrading scaffold materials. In conclusion, this study demonstrates optimization of material parameters for 3D printed calcium phosphate scaffolds and enhancement of material properties by volumetric collagen incorporation via inkjet printing. (c) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 630, "Times Cited, All Databases": 749, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 35, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4026, "End Page": 4034, "Article Number": null, "DOI": "10.1016/j.biomaterials.2014.01.064", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2014.01.064", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334481000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CZ; Shi, QR; Xu, BZ; Fu, SF; Wan, G; Yang, C; Yao, SY; Song, JH; Zhou, H; Du, D; Beckman, SP; Su, D; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Chengzhou; Shi, Qiurong; Xu, Bo Z.; Fu, Shaofang; Wan, Gang; Yang, Ce; Yao, Siyu; Song, Junhua; Zhou, Hua; Du, Dan; Beckman, Scott P.; Su, Dong; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically Porous M-N-C (M = Co and Fe) Single-Atom Electrocatalysts with Robust MNx Active Moieties Enable Enhanced ORR Performance", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The great interest in fuel cells inspires a substantial amount of research on nonprecious metal catalysts as alternatives to Pt-based oxygen reduction reaction (ORR) electrocatalysts. In this work, bimodal template-based synthesis strategies are proposed for the scalable preparation of hierarchically porous M-N-C (M = Fe or Co) single-atom electrocatalysts featured with active and robust MN2 active moieties. Multiscale tuning of M-N-C catalysts regarding increasing the number of active sites and boosting the intrinsic activity of each active site is realized simultaneously at a single-atom scale. In addition to the antipoisoning power and high affinity for O-2, the optimized Fe-N-C catalysts with FeN2 active site presents a superior electrocatalytic activity for ORR with a half-wave potential of 0.927 V (vs reversible hydrogen electrode (RHE)) in an alkaline medium, which is 49 and 55 mV higher than those of the Co-N-C counterpart and commercial Pt/C, respectively. Density functional theory calculations reveal that the FeN2 site is more active than the CoN2 site for ORR due to the lower energy barriers of the intermediates and products involved. The present work may help rational design of more robust ORR electrocatalysts at the atomic level, realizing the significant advances in electrochemical conversion and storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 614, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2018, "Volume": 8, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801956, "DOI": "10.1002/aenm.201801956", "DOI Link": "http://dx.doi.org/10.1002/aenm.201801956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447257000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JW; Zheng, XL; Feng, ZP; Lu, ZY; Zhang, ZW; Huang, W; Li, YB; Vuckovic, D; Li, YQ; Dai, S; Chen, GX; Wang, KC; Wang, HS; Chen, JK; Mitch, W; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jinwei; Zheng, Xueli; Feng, Zhiping; Lu, Zhiyi; Zhang, Zewen; Huang, William; Li, Yanbin; Vuckovic, Djordje; Li, Yuanqing; Dai, Sheng; Chen, Guangxu; Wang, Kecheng; Wang, Hansen; Chen, James K.; Mitch, William; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic wastewater treatment by a single-atom catalyst and electrolytically produced H2O2", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The presence of organic contaminullts in wastewater poses considerable risks to the health of both humans and ecosystems. Although advanced oxidation processes that rely on highly reactive radicals to destroy organic contaminullts are appealing treatment options, substantial energy and chemical inputs limit their practical applications. Here we demonstrate that Cu single atoms incorporated in graphitic carbon nitride can catalytically activate H2O2 to generate hydroxyl radicals at pH 7.0 without energy input, and show robust stability within a filtration device. We further design an electrolysis reactor for the on-site generation of H2O2 from air, water and renewable energy. Coupling the single-atom catalytic filter and the H2O2 electrolytic generator in tandem delivers a wastewater treatment system. These findings provide a promising path toward reducing the energy and chemical demands of advanced oxidation processes, as well as enabling their implementation in remote areas and isolated communities. Here the authors design an electrolysis reactor to generate H2O2 which could be further catalytically activated by Cu single atoms to yield hydroxyl radicals. Combining the two reactions enables a system that could treat organic wastewater, providing a path toward sustainable advanced oxidation processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 233, "End Page": 241, "Article Number": null, "DOI": "10.1038/s41893-020-00635-w", "DOI Link": "http://dx.doi.org/10.1038/s41893-020-00635-w", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000588002700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faber, MS; Lukowski, MA; Ding, Q; Kaiser, NS; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faber, Matthew S.; Lukowski, Mark A.; Ding, Qi; Kaiser, Nicholas S.; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Earth-Abundant Metal Pyrites (FeS2, CoS2, NiS2, and Their Alloys) for Highly Efficient Hydrogen Evolution and Polysulfide Reduction Electrocatalysis", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many materials have been explored as potential hydrogen evolution reaction (HER) electrocatalysts to generate clean hydrogen fuel via water electrolysis, but none so far compete with the highly efficient and stable (but cost prohibitive) noble metals. Similarly, noble metals often excel as electrocatalytic counter electrode materials in regenerative liquid-junction photoelectrochemical solar cells, such as quantum dot-sensitized solar cells (QDSSCs) that employ the sulfide/polysulfide redox electrolyte as the hole mediator. Here, we systematically investigate thin films of the earth-abundant pyrite-phase transition metal disulfides (FeS2, CoS2, NiS2, and their alloys) as promising alternative electrocatalysts for both the HER and polysulfide reduction. Their electrocatalytic activity toward the HER is correlated to their composition and morphology. The emergent trends in their performance suggest that cobalt plays an important role in facilitating the HER, with CoS2 exhibiting highest overall performance. Additionally, we demonstrate the high activity of the transition metal pyrites toward polysulfide reduction and highlight the particularly high intrinsic activity of NiS2, which could enable improved QDSSC performance. Furthermore, structural disorder introduced by alloying different transition metal pyrites could increase their areal density of active sites for catalysis, leading to enhanced performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2014, "Volume": 118, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21347, "End Page": 21356, "Article Number": null, "DOI": "10.1021/jp506288w", "DOI Link": "http://dx.doi.org/10.1021/jp506288w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342118500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, HL; Yang, CX; Yan, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are a novel class of porous materials, and offer great potential for various applications. However, the applications of COFs in chiral separation and chiral catalysis are largely underexplored due to the very limited chiral COFs available and their challenging synthesis. Here we show a bottom-up strategy to construct chiral COFs and an in situ growth approach to fabricate chiral COF-bound capillary columns for chiral gas chromatography. We incorporate the chiral centres into one of the organic ligands for the synthesis of the chiral COFs. We subsequently in situ prepare the COF-bound capillary columns. The prepared chiral COFs and their bound capillary columns give high resolution for the separation of enulltiomers with excellent repeatability and reproducibility. The proposed strategy provides a promising platform for the synthesis of chiral COFs and their chiral separation application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12104, "DOI": "10.1038/ncomms12104", "DOI Link": "http://dx.doi.org/10.1038/ncomms12104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380743600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Tang, Y; Song, JH; Yang, W; Wang, MS; Zhu, CZ; Zhao, WG; Zheng, JM; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xing; Tang, Yao; Song, Junhua; Yang, Wei; Wang, Mingshan; Zhu, Chengzhou; Zhao, Wengao; Zheng, Jianming; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-supporting activated carbon/carbon nullotube/reduced graphene oxide flexible electrode for high performance supercapacitor", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A self-supporting and flexible activated carbon/carbon nullotube/reduced graphene oxide (AC/CNT/RGO) film has been rationally designed for constructing high-performance supercapacitor. The AC/CNT/RGO film is prepared by anchoring the AC particles with a 3D and porous framework built by hierarchically weaving the 1 D CNT and 2D RGO using their intrinsic van derWaals force. The CNT network is beneficial for improving the electronic conductivity of the electrode, while the AC particles could effectively suppress the aggregation of RGO and CNT due to their blocking effect. The synergistic effects among the AC, CNT and RGO validate the AC/CNT/RGO as a promising electrode for supercapacitor, exhibiting greatly enhanced electrochemical performances in comparison with the pure RGO film, pure CNT film and AC electrode. The AC/CNT/RGO electrode delivers a high specific capacitance of 101 F g(-1) at the current density of 0.2 A g(-1), offering a maximum energy density of 30.0 W h kg(-1) in organic electrolyte at the cut-off voltage range of 0.001-3.0 V. The findings of this work open a new avenue for the design of self-supporting electrodes for the development of flexible and light weight energy storage supercapacitor. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 129, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 236, "End Page": 244, "Article Number": null, "DOI": "10.1016/j.carbon.2017.11.099", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2017.11.099", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424885800026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, TZ; Wu, C; Wang, YL; Tomsia, AP; Li, MZ; Saiz, E; Fang, SL; Baughman, RH; Jiang, L; Cheng, QF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Tianzhu; Wu, Chao; Wang, Yanlei; Tomsia, Antoni P.; Li, Mingzhu; Saiz, Eduardo; Fang, Shaoli; Baughman, Ray H.; Jiang, Lei; Cheng, Qunfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Super-tough MXene-functionalized graphene sheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible reduced graphene oxide (rGO) sheets are being considered for applications in portable electrical devices and flexible energy storage systems. However, the poor mechanical properties and electrical conductivities of rGO sheets are limiting factors for the development of such devices. Here we use MXene (M) nullosheets to functionalize graphene oxide platelets through Ti-O-C covalent bonding to obtain MrGO sheets. A MrGO sheet was crosslinked by a conjugated molecule (1-aminopyrene-disuccinimidyl suberate, AD). The incorporation of MXene nullosheets and AD molecules reduces the voids within the graphene sheet and improves the alignment of graphene platelets, resulting in much higher compactness and high toughness. In situ Raman spectroscopy and molecular dynamics simulations reveal the synergistic interfacial interaction mechanisms of Ti-O-C covalent bonding, sliding of MXene nullosheets, and -pi bridging. Furthermore, a supercapacitor based on our super-tough MXene-functionalized graphene sheets provides a combination of energy and power densities that are high for flexible supercapacitors. p id=Par Poor mechanical properties of reduced graphene oxide sheets hinder development of flexible energy storage systems. MXene functionalised graphene oxide with Ti-O-C bonding and additional crosslinking is here reported to dramatically increase toughness for flexible supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2077, "DOI": "10.1038/s41467-020-15991-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15991-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531855500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, NN; Wang, L; Wang, Q; Deng, J; Wang, Y; Lu, P; Huang, J; Li, G; Zhang, Y; Yang, JL; Xie, KW; Zhao, XH; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Ningning; Wang, Liu; Wang, Qi; Deng, Jue; Wang, Yan; Lu, Peng; Huang, Jun; Li, Gang; Zhang, Yuan; Yang, Junlong; Xie, Kewei; Zhao, Xuanhe; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graded intrafillable architecture-based iontronic pressure sensor with ultra-broad-range high sensitivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sensitivity is a crucial parameter for flexible pressure sensors and electronic skins. While introducing microstructures (e.g., micro-pyramids) can effectively improve the sensitivity, it in turn leads to a limited pressure-response range due to the poor structural compressibility. Here, we report a strategy of engineering intrafillable microstructures that can significantly boost the sensitivity while simultaneously broadening the pressure responding range. Such intrafillable microstructures feature undercuts and grooves that accommodate deformed surface microstructures, effectively enhancing the structural compressibility and the pressure-response range. The intrafillable iontronic sensor exhibits an unprecedentedly high sensitivity (S-min > 220 kPa(-1)) over a broad pressure regime (0.08 Pa-360 kPa), and an ultrahigh pressure resolution (18 Pa or 0.0056%) over the full pressure range, together with remarkable mechanical stability. The intrafillable structure is a general design expected to be applied to other types of sensors to achieve a broader pressure-response range and a higher sensitivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 631, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 209, "DOI": "10.1038/s41467-019-14054-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14054-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551459800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Lin, DC; Liang, Z; Zhao, J; Yan, K; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yayuan; Lin, Dingchang; Liang, Zheng; Zhao, Jie; Yan, Kai; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is the ideal anode for the next generation of high-energy-density batteries. Nevertheless, dendrite growth, side reactions and infinite relative volume change have prevented it from practical applications. Here, we demonstrate a promising metallic lithium anode design by infusing molten lithium into a polymeric matrix. The electrospun polyimide employed is stable against highly reactive molten lithium and, via a conformal layer of zinc oxide coating to render the surface lithiophilic, molten lithium can be drawn into the matrix, affording a nullo-porous lithium electrode. Importantly, the polymeric backbone enables uniform lithium stripping/plating, which successfully confines lithium within the matrix, realizing minimum volume change and effective dendrite suppression. The porous electrode reduces the effective current density; thus, flat voltage profiles and stable cycling of more than 100 cycles is achieved even at a high current density of 5 mA cm(-2) in both carbonate and ether electrolyte. The advantages of the porous, polymeric matrix provide important insights into the design principles of lithium metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 770, "Times Cited, All Databases": 853, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10992, "DOI": "10.1038/ncomms10992", "DOI Link": "http://dx.doi.org/10.1038/ncomms10992", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372408900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JC; Ma, C; Chi, MF; Liang, CD; Dudney, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Juchuan; Ma, Cheng; Chi, Miaofang; Liang, Chengdu; Dudney, nullcy J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid Electrolyte: the Key for High-Voltage Lithium Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2015, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1401408, "DOI": "10.1002/aenm.201401408", "DOI Link": "http://dx.doi.org/10.1002/aenm.201401408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350566000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wang, T; Liu, P; Liao, ZQ; Liu, SH; Zhuang, XD; Chen, MW; Zschech, E; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wang, Tao; Liu, Pan; Liao, Zhongquan; Liu, Shaohua; Zhuang, Xiaodong; Chen, Mingwei; Zschech, Ehrenfried; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi4 electrocatalyst supported by MoO2 cuboids on nickel foam (MoNi4/MoO2@Ni), which is constructed by controlling the outward diffusion of nickel atoms on annealing precursor NiMoO4 cuboids on nickel foam. Experimental and theoretical results confirm that a rapid Tafel-step-decided hydrogen evolution proceeds on MoNi4 electrocatalyst. As a result, the MoNi4 electrocatalyst exhibits zero onset overpotential, an overpotential of 15 mV at 10 mA cm(-2) and a low Tafel slope of 30 mV per decade in 1M potassium hydroxide electrolyte, which are comparable to the results for platinum and superior to those for state-of-the-art platinum-free electrocatalysts. Benefiting from its scalable preparation and stability, the MoNi4 electrocatalyst is promising for practical water-alkali electrolysers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 995, "Times Cited, All Databases": 1031, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15437, "DOI": "10.1038/ncomms15437", "DOI Link": "http://dx.doi.org/10.1038/ncomms15437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401513800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Q; Jiang, DE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Qing; Jiang, De-en", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of Hydrogen Evolution Reaction on 1T-MoS2 from First Principles", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The IT phase of transition-metal dichalcogenides (TMDs) has been demonstrated in recent experiments to display excellent catalytic activity for hydrogen evolution reaction (HER), but the catalytic mechanism has not been elucidated so far. Herein, using IT MoS2 as the prototypical TMD material, we studied the HER activity on its basal plane from periodic density functional theory (DFT) calculations. Compared to the nonreactive basal plane of 2H phase MoS2, the catalytic activity of the basal plane of IT phase MoS2 mainly arises from its affinity for binding H at the surface S sites. Using the binding free energy (Delta G(H)) of H as the descriptor, we found that the optimum evolution of H-2 will proceed at surface H coverage of 12.5% similar to 25%. Within this coverage, we examined the reaction energy and barrier for the three elementary steps of the HER process. The Volmer step was found to be facile, whereas the subsequent Heyrovsky reaction is kinetically more favorable than the Tafel reaction. Our results suggest that at low overpotential, HER can take place readily on the basal plane of IT MoS2 via the Volmer Heyrovsky mechanism. We further screened the dopants for the HER activity and found that substitutional doping of the Mo atom by metals such as Mn, Cr, Cu, Ni, and Fe can make IT MoS2 a better HER catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 745, "Times Cited, All Databases": 775, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4953, "End Page": 4961, "Article Number": null, "DOI": "10.1021/acscatal.6b01211", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b01211", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381236700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, MJ; Yang, CP; Li, BY; Dong, Q; Wu, ML; Hwang, S; Xie, H; Wang, XZ; Wang, GF; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Mingjin; Yang, Chunpeng; Li, Boyang; Dong, Qi; Wu, Meiling; Hwang, Sooyeon; Xie, Hua; Wang, Xizheng; Wang, Guofeng; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Metal Sulfide nulloparticles Promise High-Performance Oxygen Evolution Reaction", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal sulfides with a multi-elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high-entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)S-x) solid solution nulloparticles is reported. Computational and X-ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)S-x exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)S-x nulloparticles show one of the best activities (low overpotential 295 mV at 100 mA cm(-2) in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high-entropy compound nulloparticles for highly efficient electrocatalysis applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002887, "DOI": "10.1002/aenm.202002887", "DOI Link": "http://dx.doi.org/10.1002/aenm.202002887", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000594732500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holoubek, J; Liu, HD; Wu, ZH; Yin, YJ; Xing, X; Cai, GR; Yu, SC; Zhou, HY; Pascal, TA; Chen, Z; Liu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holoubek, John; Liu, Haodong; Wu, Zhaohui; Yin, Yijie; Xing, Xing; Cai, Guorui; Yu, Sicen; Zhou, Hongyao; Pascal, Tod A.; Chen, Zheng; Liu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries hold promise for pushing cell-level energy densities beyond 300 Wh kg(-1) while operating at ultra-low temperatures (below -30 degrees C). Batteries capable of both charging and discharging at these temperature extremes are highly desirable due to their inherent reduction in the need for external warming. Here we demonstrate that the local solvation structure of the electrolyte defines the charge-transfer behaviour at ultra-low temperature, which is crucial for achieving high Li metal Coulombic efficiency and avoiding dendritic growth. These insights were applied to Li metal full-cells, where a high-loading 3.5 mAh cm(-2) sulfurized polyacrylonitrile (SPAN) cathode was paired with a onefold excess Li metal anode. The cell retained 84% and 76% of its room temperature capacity when cycled at -40 and -60 degrees C, respectively, which presented stable performance over 50 cycles. This work provides design criteria for ultra-low-temperature lithium metal battery electrolytes, and represents a defining step for the performance of low-temperature batteries. Charging and discharging Li-metal batteries (LMBs) at low temperatures is problematic due to the sluggish charge-transfer process. Here the authors discuss the roles of solvation structures of Li-ions in the charge-transfer kinetics and design an electrolyte to enable low-temperature operations of LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 546, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 303, "End Page": 313, "Article Number": null, "DOI": "10.1038/s41560-021-00783-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00783-z", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621706600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, L; Zhang, R; Wan, G; Yang, WJ; Wan, X; Zhou, H; Shui, JL; Yu, SH; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Long; Zhang, Rui; Wan, Gang; Yang, Weijie; Wan, Xin; Zhou, Hua; Shui, Jianglan; Yu, Shu-Hong; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocasting SiO2 into metal-organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have sparked broad interest recently while the low metal loading poses a big challenge for further applications. Herein, a dual protection strategy has been developed to give high-content SACs by nullocasting SiO2 into porphyrinic metal-organic frameworks (MOFs). The pyrolysis of SiO2@MOF composite affords single-atom Fe implanted N-doped porous carbon (Fe-SA-N-C) with high Fe loading (3.46wt%). The spatial isolation of Fe atoms centered in porphyrin linkers of MOF sets the first protective barrier to inhibit the Fe agglomeration during pyrolysis. The SiO2 in MOF provides additional protection by creating thermally stable FeN4/SiO2 interfaces. Thanks to the high-density Fe-SA sites, Fe-SA-N-C demonstrates excellent oxygen reduction performance in both alkaline and acidic medias. Meanwhile, Fe-SA-N-C also exhibits encouraging performance in proton exchange membrane fuel cell, demonstrating great potential for practical application. More far-reaching, this work grants a general synthetic methodology toward high-content SACs (such as Fe-SA, Co-SA, Ni-SA). Single-atom catalysts (SACs) with high metal loading are highly desired to improve catalytic performance. Here, the authors report a dual protection strategy by nullocasting SiO2 into metal-organic frameworks to prepare high-loading SACs with excellent catalytic performance toward oxygen reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16715-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16715-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540523000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, XH; Chao, DL; Fan, ZX; Guan, C; Cao, XH; Zhang, H; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Xinhui; Chao, Dongliang; Fan, Zhanxi; Guan, Cao; Cao, Xiehong; Zhang, Hua; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Type of Porous Graphite Foams and Their Integrated Composites with Oxide/Polymer Core/Shell nullowires for Supercapacitors: Structural Design, Fabrication, and Full Supercapacitor Demonstrations", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We attempt to meet the general design requirements for high-performance supercapacitor electrodes by combining the strategies of lightweight substrate, porous nullostructure design, and conductivity modification. We fabricate a new type of 3D porous and thin graphite foams (GF) and use as the light and conductive substrates for the growth of metal oxide core/shell nullowire arrays to form integrated electrodes. The nullowire core is Co3O4, and the shell is a composite of conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) and metal oxide (MnO2). To show the advantage of this integrated electrode design (viz., GF + Co3O4/PEDOT MnO2 core/shell nullowire arrays), three other different less-integrated electrodes are also prepared for comparison. Full supercapacitor devices based on the GF + Co3O4/PEDOT-MnO2 as positive electrodes exhibit the best performance compared to other three counterparts due to an optimal design of structure and a synergistic effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1651, "End Page": 1658, "Article Number": null, "DOI": "10.1021/nl5001778", "DOI Link": "http://dx.doi.org/10.1021/nl5001778", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335720300086", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Zhou, JD; Song, JL; Xu, JQ; Zhang, HT; Zhang, XN; Guo, J; Zhu, L; Wei, DH; Han, GC; Min, J; Zhang, Y; Xie, ZQ; Yi, YP; Yan, H; Gao, F; Liu, F; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chao; Zhou, Jiadong; Song, Jiali; Xu, Jinqiu; Zhang, Huotian; Zhang, Xuning; Guo, Jing; Zhu, Lei; Wei, Donghui; Han, Guangchao; Min, Jie; Zhang, Yuan; Xie, Zengqi; Yi, Yuanping; Yan, He; Gao, Feng; Liu, Feng; Sun, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular design of acceptor and donor molecules has enabled major progress in organic photovoltaics. Li et al. show that branched alkyl chains in non-fullerene acceptors allow favourable morphology in the active layer, enabling a certified device efficiency of 17.9%. Molecular design of non-fullerene acceptors is of vital importance for high-efficiency organic solar cells. The branched alkyl chain modification is often regarded as a counter-intuitive approach, as it may introduce an undesirable steric hindrance that reduces charge transport in non-fullerene acceptors. Here we show the design and synthesis of a highly efficient non-fullerene acceptor family by substituting the beta position of the thiophene unit on a Y6-based dithienothiophen[3,2-b]-pyrrolobenzothiadiazole core with branched alkyl chains. It was found that such a modification to a different alkyl chain length could completely change the molecular packing behaviour of non-fullerene acceptors, leading to improved structural order and charge transport in thin films. An unprecedented efficiency of 18.32% (certified value of 17.9%) with a fill factor of 81.5% is achieved for single-junction organic solar cells. This work reveals the importance of the branched alkyl chain topology in tuning the molecular packing and blend morphology, which leads to improved organic photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1693, "Times Cited, All Databases": 1745, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 605, "End Page": 613, "Article Number": null, "DOI": "10.1038/s41560-021-00820-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00820-x", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648836900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suss, ME; Porada, S; Sun, X; Biesheuvel, PM; Yoon, J; Presser, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suss, M. E.; Porada, S.; Sun, X.; Biesheuvel, P. M.; Yoon, J.; Presser, V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water desalination via capacitive deionization: what is it and what can we expect from it?", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Capacitive deionization (CDI) is an emerging technology for the facile removal of charged ionic species from aqueous solutions, and is currently being widely explored for water desalination applications. The technology is based on ion electrosorption at the surface of a pair of electrically charged electrodes, commonly composed of highly porous carbon materials. The CDI community has grown exponentially over the past decade, driving tremendous advances via new cell architectures and system designs, the implementation of ion exchange membranes, and alternative concepts such as flowable carbon electrodes and hybrid systems employing a Faradaic (battery) electrode. Also, vast improvements have been made towards unraveling the complex processes inherent to interfacial electrochemistry, including the modelling of kinetic and equilibrium aspects of the desalination process. In our perspective, we critically review and evaluate the current state-of-the-art of CDI technology and provide definitions and performance metric nomenclature in an effort to unify the fast-growing CDI community. We also provide an outlook on the emerging trends in CDI and propose future research and development directions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1370, "Times Cited, All Databases": 1490, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2296, "End Page": 2319, "Article Number": null, "DOI": "10.1039/c5ee00519a", "DOI Link": "http://dx.doi.org/10.1039/c5ee00519a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358730600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, MY; Zhao, ZH; Hu, ZF; Liu, LQ; Ji, HM; Shen, ZR; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Meng-Yang; Zhao, Zhi-Hao; Hu, Zhuo-Feng; Liu, Le-Quan; Ji, Hui-Ming; Shen, Zhu-Rui; Ma, Tian-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "0D/2D Heterojunctions of Vanadate Quantum Dots/Graphitic Carbon Nitride nullosheets for Enhanced Visible-Light-Driven Photocatalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "0D/2D heterojunctions, especially quantum dots (QDs)/nullosheets (NSs) have attracted significant attention for use of photoexcited electrons/holes due to their high charge mobility. Herein, unprecedent heterojunctions of vanadate (AgVO3, BiVO4, InVO4 and CuV2O6) QDs/graphitic carbon nitride (g-C3N4) NSs exhibiting multiple unique advances beyond traditional 0D/2D composites have been developed. The photoactive contribution, up-conversion absorption, and nitrogen coordinating sites of g-C3N4 NSs, highly dispersed vanadate nullocrystals, as well as the strong coupling and band alignment between them lead to superior visible-light-driven photoelectrochemical (PEC) and photocatalytic performance, competing with the best reported photocatalysts. This work is expected to provide a new concept to construct multifunctional 0D/2D nullocomposites for a large variety of opto-electronic applications, not limited in photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2017, "Volume": 56, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 8407, "End Page": 8411, "Article Number": null, "DOI": "10.1002/anie.201611127", "DOI Link": "http://dx.doi.org/10.1002/anie.201611127", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404739200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, S; Yang, XW; Pei, W; Liu, NS; Zhao, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Si; Yang, Xiaowei; Pei, Wei; Liu, nullshu; Zhao, Jijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterostructures of MXenes and N-doped graphene as highly active bifunctional electrocatalysts", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes with versatile chemistry and superior electrical conductivity are prevalent candidate materials for energy storage and catalysts. Inspired by recent experiments of hybridizing MXenes with carbon materials, here we theoretically design a series of heterostructures of N-doped graphene supported by MXene monolayers as bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER). Our first-principles calculations show that the graphitic sheet on V2C and Mo2C MXenes are highly active with an ORR overpotential down to 0.36 V and reaction free energies for the HER approaching zero, both with low kinetic barriers. Such outstanding catalytic activities originate from the electronic coupling between the graphitic sheet and the MXene, and can be correlated with the pz band center of surface carbon atoms and the work function of the heterostructures. Our findings screen a novel form of highly active electrocatalysts by taking advantage of the fast charge transfer kinetics and strong interfacial coupling of MXenes, and illuminate a universal mechanism for modulating the catalytic properties of two-dimensional hybrid materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2018, "Volume": 10, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10876, "End Page": 10883, "Article Number": null, "DOI": "10.1039/c8nr01090k", "DOI Link": "http://dx.doi.org/10.1039/c8nr01090k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435358600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, CG; Qian, X; Li, QK; Deng, B; Zhu, YB; Han, ZJ; Zhang, WQ; Wang, WC; Feng, SP; Chen, G; Liu, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Cheng-Gong; Qian, Xin; Li, Qikai; Deng, Biao; Zhu, Yongbin; Han, Zhijia; Zhang, Wenqing; Wang, Weichao; Feng, Shien-Ping; Chen, Gang; Liu, Weishu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant thermopower of ionic gelatin near room temperature", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting heat from the environment into electricity has the potential to power Internet-of-things (IoT) sensors, freeing them from cables or batteries and thus making them especially useful for wearable devices. We demonstrate a giant positive thermopower of 17.0 millivolts per degree Kelvin in a flexible, quasi-solid-state, ionic thermoelectric material using synergistic thermodiffusion and thermogalvanic effects. The ionic thermoelectric material is a gelatin matrix modulated with ion providers (KCl, NaCl, and KNO3) for thermodiffusion effect and a redox couple [Fe(CN)(6)(4-)/Fe(CN)(6)(3-)] for thermogalvanic effect. A proof-of-concept wearable device consisting of 25 unipolar elements generated more than 2 volts and a peak power of 5 microwatts using body heat. This ionic gelatin shows promise for environmental heat-to-electric energy conversion using ions as energy carriers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2020, "Volume": 368, "Issue": 6495, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1091, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz5045", "DOI Link": "http://dx.doi.org/10.1126/science.aaz5045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000539738400040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, XP; Wu, XY; Deng, YD; Liu, J; Lu, J; Zhong, C; Hu, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Xiaopeng; Wu, Xiaoyu; Deng, Yida; Liu, Jian; Lu, Jun; Zhong, Cheng; Hu, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafine Pt nulloparticle-Decorated Pyrite-Type CoS2 nullosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To improve the utilization efficiency of precious metals, metal-supported materials provide a direction for fabricating highly active and stable heterogeneous catalysts. Herein, carbon cloth (CC)-supported Earth-abundant CoS2 nullosheet arrays (CoS2/CC) are presented as ideal substrates for ultrafine Pt deposition (Pt-CoS2/CC) to achieve remarkable performance toward the hydrogen and oxygen evolution reactions (HER/OER) in alkaline solutions. Notably, the Pt-CoS2/CC hybrid delivers an overpotential of 24 mV at 10 mA cm(-2) and a mass activity of 3.89 A Pt-mg(-1), which is 4.7 times higher than that of commercial Pt/C, at an overpotential of 130 mV for catalyzing the HER. An alkali-electrolyzer using Pt-CoS2/CC as a bifunctional electrode enables a water-splitting current density of 10 mA cm(-2) at a low voltage of 1.55 V and can sustain for more than 20 h, which is superior to that of the state-of-the-art Pt/C+RuO2 catalyst. Further experimental and theoretical simulation studies demonstrate that strong electronic interaction between Pt and CoS2 synergistically optimize hydrogen adsorption/desorption behaviors and facilitate the in situ generation of OER active species, enhancing the overall water-splitting performance. This work highlights the regulation of interfacial and electronic synergy in pursuit of highly efficient and durable supported catalysts for hydrogen and oxygen electrocatalytic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2018, "Volume": 8, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800935, "DOI": "10.1002/aenm.201800935", "DOI Link": "http://dx.doi.org/10.1002/aenm.201800935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442731100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YY; Liu, J; Guo, T; Wang, JJ; Tang, XZ; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yunyi; Liu, Ji; Guo, Tong; Wang, Jing Jing; Tang, Xiuzhi; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Ti3C2Tx MXene Composite Hydrogels with Strain Sensitivity toward Absorption-Dominated Electromagnetic- Interference Shielding", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fast development of terahertz technologies demands high-performance electromagnetic interference (EMI) shielding materials to create safe electromagnetic environments. Despite tremendous breakthroughs in achieving superb shielding efficiency (SE), conventional shielding materials have high reflectivity and cannot be re-edited or recycled once formed, resulting in detrimental secondary electromagnetic pollution and poor adaptability. Herein, a hydrogel-type shielding material incorporating MXene and poly(acrylic acid) is fabricated through a biomineralization-inspired assembly route. The composite hydrogel exhibits excellent stretchability and recyclability, favorable shape adaptability and adhesiveness, and fast self-healing capability, demonstrating great application flexibility and reliability. More interestingly, the shielding performance of the hydrogel shows absorption-dominated feature due to the combination of the porous structure, moderate conductivity, and internal water-rich environment. High EMI SE of 45.3 dB and broad effective absorption bandwidth (0.2-2.0 THz) with excellent refection loss of 23.2 dB can be simultaneously achieved in an extremely thin hydrogel (0.13 mm). Furthermore, such hydrogel demonstrates sensitive deformation responses and can be used as an on-skin sensor. This work provides not only an alternative strategy for designing next-generation EMI shielding material but also a highly efficient and convenient method for fabricating MXene composite on macroscopic scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2021, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1465, "End Page": 1474, "Article Number": null, "DOI": "10.1021/acsnullo.0c08830", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c08830", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613942700118", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lang, R; Xi, W; Liu, JC; Cui, YT; Li, TB; Lee, AF; Chen, F; Chen, Y; Li, L; Li, L; Lin, J; Miao, S; Liu, XY; Wang, AQ; Wang, XD; Luo, J; Qiao, BT; Li, J; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lang, Rui; Xi, Wei; Liu, Jin-Cheng; Cui, Yi-Tao; Li, Tianbo; Lee, Adam Fraser; Chen, Fang; Chen, Yang; Li, Lei; Li, Lin; Lin, Jian; Miao, Shu; Liu, Xiaoyan; Wang, Ai-Qin; Wang, Xiaodong; Luo, Jun; Qiao, Botao; Li, Jun; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non defect-stabilized thermally stable single-atom catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface-supported isolated atoms in single-atom catalysts (SACs) are usually stabilized by diverse defects. The fabrication of high-metal-loading and thermally stable SACs remains a formidable challenge due to the difficulty of creating high densities of underpinning stable defects. Here we report that isolated Pt atoms can be stabilized through a strong covalent metal-support interaction (CMSI) that is not associated with support defects, yielding a high-loading and thermally stable SAC by trapping either the already deposited Pt atoms or the PtO2 units vaporized from nulloparticles during high-temperature calcination. Experimental and computational modeling studies reveal that iron oxide reducibility is crucial to anchor isolated Pt atoms. The resulting high concentrations of single atoms enable specific activities far exceeding those of conventional nulloparticle catalysts. This non defect-stabilization strategy can be extended to non-reducible supports by simply doping with iron oxide, thus paving a new way for constructing high-loading SACs for diverse industrially important catalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 579, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 234, "DOI": "10.1038/s41467-018-08136-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08136-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455761000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LQ; Yang, XL; Jiang, Q; Wang, PY; Yin, ZG; Zhang, XW; Tan, HR; Yang, Y; Wei, MY; Sutherland, BR; Sargent, EH; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Liuqi; Yang, Xiaolei; Jiang, Qi; Wang, Pengyang; Yin, Zhigang; Zhang, Xingwang; Tan, Hairen; Yang, Yang Michael; Wei, Mingyang; Sutherland, Brandon R.; Sargent, Edward H.; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic perovskites such as CsPbX3 (X = Cl, Br, I) have attracted attention due to their excellent thermal stability and high photoluminescence quantum efficiency. However, the electroluminescence quantum efficiency of their light-emitting diodes was <1%. We posited that this low efficiency was a result of high leakage current caused by poor perovskite morphology, high non-radiative recombination at interfaces and perovskite grain boundaries, and also charge injection imbalance. Here, we incorporated a small amount of methylammonium organic cation into the CsPbBr3 lattice and by depositing a hydrophilic and insulating polyvinyl pyrrolidine polymer atop the ZnO electron-injection layer to overcome these issues. As a result, we obtained light-emitting diodes exhibiting a high brightness of 91,000 cd m(-2) and a high external quantum efficiency of 10.4% using a mixed-cation perovskite Cs(0.87)MA(0.13)PbBr(3) as the emitting layer. To the best of our knowledge, this is the brightest and most-efficient green perovskite light-emitting diodes reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 791, "Times Cited, All Databases": 850, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15640, "DOI": "10.1038/ncomms15640", "DOI Link": "http://dx.doi.org/10.1038/ncomms15640", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402804700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, YG; Huang, HL; Zhang, YX; Kang, CF; Chen, SM; Song, L; Liu, DH; Zhong, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Yaguang; Huang, Hongliang; Zhang, Yuxi; Kang, Chufan; Chen, Shuangming; Song, Li; Liu, Dahuan; Zhong, Chongli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A versatile MOF-based trap for heavy metal ion capture and dispersion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current technologies for removing heavy metal ions are typically metal ion specific. Herein we report the development of a broad-spectrum heavy metal ion trap by incorporation of ethylenediaminetetraacetic acid into a robust metal-organic framework. The capture experiments for a total of 22 heavy metal ions, covering hard, soft, and borderline Lewis metal ions, show that the trap is very effective, with removal efficiencies of >99% for single-component adsorption, multi-component adsorption, or in breakthrough processes. The material can also serve as a host for metal ion loading with arbitrary selections of metal ion amounts/types with a controllable uptake ratio to prepare well-dispersed single or multiple metal catalysts. This is supported by the excellent performance of the prepared Pd2+-loaded composite toward the Suzuki coupling reaction. This work proposes a versatile heavy metal ion trap that may find applications in the fields of separation and catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 641, "Times Cited, All Databases": 676, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 187, "DOI": "10.1038/s41467-017-02600-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02600-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422646500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Higgins, TM; Park, SH; King, PJ; Zhang, C; MoEvoy, N; Berner, NC; Daly, D; Shmeliov, A; Khan, U; Duesberg, G; Nicolosi, V; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Higgins, Thomas M.; Park, Sang-Hoon; King, Paul J.; Zhang, Chuanfan (John); MoEvoy, Niall; Berner, Nina C.; Daly, Dermot; Shmeliov, Aleksey; Khan, Umar; Duesberg, Georg; Nicolosi, Valeria; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon nulloparticle-Based Lithium-Ion Battery Negative Electrodes", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work describes silicon nulloparticlebased lithium -ion battery negative electrodes where multiple nonactive electrode additives (usually carbon black and an inert polymer binder) are replaced with a single conductive binder, in this case, the conducting polymer PEDOT:PSS. While enabling the production of well -mixed slurry -cast electrodes with high silicon content (up to 95 wt %), this combination eliminates the well-known occurrence of capacity losses due to physical separation of the silicon and traditional inorganic conductive additives during repeated lithiation/delithiation processes. Using an in situ secondary doping treatment of the PEDOT:PSS with small quantities of formic acid, electrodes containing 80 wt % SiNPs can be prepared with electrical conductivity as high as 4.2 S/cm. Even at the relatively high areal loading of 1 mg/cm(2), this system demonstrated a first cycle lithiation capacity of 3685 inkh/g (based on the SiNP mass) and a first, cycle efficiency of 78%. After 100 repeated cycles at 1 A/g this electrode was still able to store an impressive 1950 mAth/g normalized to Si mass (-75% capacity retention), corresponding to 1542 mAh/g when the capacity is normalized by the total electrode mass. At the maximum electrode thickness studied (-4.5 mg/cm2), a high areal capacity of 3 mA.h/cm(2) was achieved. Importantly, these electrodes are based on commercially available components and are produced by the standard slurry coating methods required for large-scale electrode production. Hence, the results presented here are highly relevant for the realization of commercial LiB negative electrodes that surpass the performance of current graphite-based negative electrode systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3702, "End Page": 3713, "Article Number": null, "DOI": "10.1021/acsnullo.6b00218", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b00218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372855400075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XD; Dong, L; Zhang, HL; Yu, RM; Pan, CF; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiandi; Dong, Lin; Zhang, Hanlu; Yu, Ruomeng; Pan, Caofeng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Progress in Electronic Skin", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The skin is the largest organ of the human body and can sense pressure, temperature, and other complex environmental stimuli or conditions. The mimicry of human skin's sensory ability via electronics is a topic of innovative research that could find broad applications in robotics, artificial intelligence, and human-machine interfaces, all of which promote the development of electronic skin (e-skin). To imitate tactile sensing via e-skins, flexible and stretchable pressure sensor arrays are constructed based on different transduction mechanisms and structural designs. These arrays can map pressure with high resolution and rapid response beyond that of human perception. Multi-modal force sensing, temperature, and humidity detection, as well as self-healing abilities are also exploited for multi-functional e-skins. Other recent progress in this field includes the integration with high-density flexible circuits for signal processing, the combination with wireless technology for convenient sensing and energy/data transfer, and the development of self-powered e-skins. Future opportunities lie in the fabrication of highly intelligent e-skins that can sense and respond to variations in the external environment. The rapidly increasing innovations in this area will be important to the scientific community and to the future of human life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 802, "Times Cited, All Databases": 850, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500169, "DOI": "10.1002/advs.201500169", "DOI Link": "http://dx.doi.org/10.1002/advs.201500169", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368999600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Zhong, M; Huang, Y; Zhu, MS; Pei, ZX; Wang, ZF; Xue, Q; Xie, XM; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yan; Zhong, Ming; Huang, Yang; Zhu, Minshen; Pei, Zengxia; Wang, Zifeng; Xue, Qi; Xie, Xuming; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A self-healable and highly stretchable supercapacitor based on a dual crosslinked polyelectrolyte", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superior self-healability and stretchability are critical elements for the practical wide-scale adoption of personalized electronics such as portable and wearable energy storage devices. However, the low healing efficiency of self-healable supercapacitors and the small strain of stretchable supercapacitors are fundamentally limited by conventional polyvinyl alcohol-based acidic electrolytes, which are intrinsically neither self-healable nor highly stretchable. Here we report an electrolyte comprising polyacrylic acid dual crosslinked by hydrogen bonding and vinyl hybrid silica nulloparticles, which displays all superior functions and provides a solution to the intrinsic self-healability and high stretchability problems of a supercapacitor. Supercapacitors with this electrolyte are non-autonomic self-healable, retaining the capacitance completely even after 20 cycles of breaking/healing. These supercapacitors are stretched up to 600% strain with enhanced performance using a designed facile electrode fabrication procedure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 616, "Times Cited, All Databases": 643, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10310, "DOI": "10.1038/ncomms10310", "DOI Link": "http://dx.doi.org/10.1038/ncomms10310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367585000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, WH; Sheng, JQ; Huang, QQ; Wang, GH; Chen, JB; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Weihua; Sheng, Jiaqi; Huang, Qianqian; Wang, Gehuan; Chen, Jiabin; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environmentally Friendly and Multifunctional Shaddock Peel-Based Carbon Aerogel for Thermal-Insulation and Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsThe eco-friendly shaddock peel-derived carbon aerogels were prepared by a freeze-drying method.Multiple functions such as thermal insulation, compression resistance and microwave absorption can be integrated into one material-carbon aerogel.Novel computer simulation technology strategy was selected to simulate significant radar cross-sectional reduction values under real far field condition..AbstractEco-friendly electromagnetic wave absorbing materials with excellent thermal infrared stealth property, heat-insulating ability and compression resistance are highly attractive in practical applications. Meeting the aforesaid requirements simultaneously is a formidable challenge. Herein, ultra-light carbon aerogels were fabricated via fresh shaddock peel by facile freeze-drying method and calcination process, forming porous network architecture. With the heating platform temperature of 70 degrees C, the upper surface temperatures of the as-prepared carbon aerogel present a slow upward trend. The color of the sample surface in thermal infrared images is similar to that of the surroundings. With the maximum compressive stress of 2.435 kPa, the carbon aerogels can provide favorable endurance. The shaddock peel-based carbon aerogels possess the minimum reflection loss value (RLmin) of - 29.50 dB in X band. Meanwhile, the effective absorption bandwidth covers 5.80 GHz at a relatively thin thickness of only 1.7 mm. With the detection theta of 0 degrees, the maximum radar cross-sectional (RCS) reduction values of 16.28 dB m(2) can be achieved. Theoretical simulations of RCS have aroused extensive interest owing to their ingenious design and time-saving feature. This work paves the way for preparing multi-functional microwave absorbers derived from biomass raw materials under the guidance of RCS simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102, "DOI": "10.1007/s40820-021-00635-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00635-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637357900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, FF; Shang, LR; Chen, ZY; Yu, YR; Zhao, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Fanfan; Shang, Luoran; Chen, Zhuoyue; Yu, Yunru; Zhao, Yuanjin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired living structural color hydrogels", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structural color materials from existing natural organisms have been widely studied to enable artificial manufacture. Variable iridescence has attracted particular interest because of the displays of various brilliant examples. Existing synthetic, variable, structural color materials require external stimuli to provide changing displays, despite autonomous regulation being widespread among natural organisms, and therefore suffer from inherent limitations. Inspired by the structural color regulation mechanism of chameleons, we present a conceptually different structural color material that has autonomic regulation capability by assembling engineered cardiomyocyte tissues on synthetic inverse opal hydrogel films. The cell elongation and contraction in the beating processes of the cardiomyocytes caused the inverse opal structure of the substrate film to follow the same cycle of volume or morphology changes. This was observed as the synchronous shifting of its photonic band gap and structural colors. Such biohybrid structural color hydrogels can be used to construct a variety of living materials, such as two-dimensional self-regulating structural color patterns and three-dimensional dynamic Morpho butterflies. These examples indicated that the stratagem could provide an intrinsic color-sensing feedback to modify the system behavior/action for future biohybrid robots. In addition, by integrating the biohybrid structural color hydrogels into microfluidics, we developed a heart-on-a-chip platform featuring microphysiological visuality for biological research and drug screening. This biohybrid, living, structural color hydrogel may be widely used in the design of a variety of intelligent actuators and soft robotic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2018, "Volume": 3, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar8580", "DOI": "10.1126/scirobotics.aar8580", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.aar8580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441685600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, EK; Sun, Y; Kumar, N; Muechler, L; Sun, AL; Jiao, L; Yang, SY; Liu, DF; Liang, AJ; Xu, QN; Kroder, J; Süss, V; Borrmann, H; Shekhar, C; Wang, ZS; Xi, CY; Wang, WH; Schnelle, W; Wirth, S; Chen, YL; Goennenwein, STB; Felser, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Enke; Sun, Yan; Kumar, Nitesh; Muechler, Lukas; Sun, Aili; Jiao, Lin; Yang, Shuo-Ying; Liu, Defa; Liang, Aiji; Xu, Qiunull; Kroder, Johannes; Suess, Vicky; Borrmann, Horst; Shekhar, Chandra; Wang, Zhaosheng; Xi, Chuanying; Wang, Wenhong; Schnelle, Walter; Wirth, Steffen; Chen, Yulin; Goennenwein, Sebastian T. B.; Felser, Claudia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant anomalous Hall effect in a ferromagnetic kagome-lattice semimetal", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic Weyl semimetals with broken time-reversal symmetry are expected to generate strong intrinsic anomalous Hall effects, due to their large Berry curvature. Here, we report a magnetic Weyl semimetal candidate, Co3Sn2S2, with a quasi-two-dimensional crystal structure consisting of stacked kagome lattices. This lattice provides an excellent platform for hosting exotic topological quantum states. We observe a negative magnetoresistance that is consistent with the chiral anomaly expected from the presence of Weyl fermions close to the Fermi level. The anomalous Hall conductivity is robust against both increased temperature and charge conductivity, which corroborates the intrinsic Berry-curvature mechanism in momentum space. Owing to the low carrier density in this material and the considerably enhanced Berry curvature from its band structure, the anomalous Hall conductivity and the anomalous Hall angle simultaneously reach 1,130 Omega(-1) cm(-1) and 20%, respectively, an order of magnitude larger than typical magnetic systems. Combining the kagome-lattice structure and the long-range out-of-plane ferromagnetic order of Co3Sn2S2, we expect that this material is an excellent candidate for observation of the quantum anomalous Hall state in the two-dimensional limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1020, "Times Cited, All Databases": 1097, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1125, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-018-0234-5", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0234-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448973100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Drobek, M; Kim, JH; Bechelany, M; Vallicari, C; Julbe, A; Kim, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Drobek, Martin; Kim, Jae-Hun; Bechelany, Mikhael; Vallicari, Cyril; Julbe, Anne; Kim, Sang Sub", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-Based Membrane Encapsulated ZnO nullowires for Enhanced Gas Sensor Selectivity", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gas sensors are of a great interest for applications including toxic or explosive gases detection in both in-house and industrial environments, air quality monitoring, medical diagnostics, or control of food/cosmetic properties. In the area of semiconductor metal oxides (SMOs)-based sensors, a lot of effort has been devoted to improve the sensing characteristics. In this work, we report on a general methodology for improving the selectivity of SMOx nullowires sensors, based on the coverage of ZnO nullowires with a thin ZIF-8 molecular sieve membrane. The optimized ZnO@ZIF-8-based nullocomposite sensor shows markedly selective response to H-2 in comparison with the pristine ZnO nullowires sensor, while showing the negligible sensing response to C7H8 and C6H6. This original MOF-membrane encapsulation strategy applied to nullowires sensor architecture pave the way for other complex 3D architectures and various types of applications requiring either gas or ion selectivity, such as biosensors, photo(catalysts), and electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2016, "Volume": 8, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8323, "End Page": 8328, "Article Number": null, "DOI": "10.1021/acsami.5b12062", "DOI Link": "http://dx.doi.org/10.1021/acsami.5b12062", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373748200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Q; Hutchings, GS; Yu, WT; Zhou, Y; Forest, RV; Tao, RZ; Rosen, J; Yonemoto, BT; Cao, ZY; Zheng, HM; Xiao, JQ; Jiao, F; Chen, JGG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Qi; Hutchings, Gregory S.; Yu, Weiting; Zhou, Yang; Forest, Robert V.; Tao, Runzhe; Rosen, Jonathan; Yonemoto, Bryan T.; Cao, Zeyuan; Zheng, Haimei; Xiao, John Q.; Jiao, Feng; Chen, Jingguang G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A robust and efficient non-precious metal catalyst for hydrogen evolution reaction is one of the key components for carbon dioxide-free hydrogen production. Here we report that a hierarchical nulloporous copper-titanium bimetallic electrocatalyst is able to produce hydrogen from water under a mild overpotential at more than twice the rate of state-of-the-art carbon-supported platinum catalyst. Although both copper and titanium are known to be poor hydrogen evolution catalysts, the combination of these two elements creates unique copper-copper-titanium hollow sites, which have a hydrogen-binding energy very similar to that of platinum, resulting in an exceptional hydrogen evolution activity. In addition, the hierarchical porosity of the nulloporous copper-titanium catalyst also contributes to its high hydrogen evolution activity, because it provides a large-surface area for electrocatalytic hydrogen evolution, and improves the mass transport properties. Moreover, the catalyst is self-supported, eliminating the overpotential associated with the catalyst/support interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 488, "Times Cited, All Databases": 530, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6567, "DOI": "10.1038/ncomms7567", "DOI Link": "http://dx.doi.org/10.1038/ncomms7567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Harrington, TJ; Gild, J; Sarker, P; Toher, C; Rost, CM; Dippo, OF; McElfresh, C; Kaufmann, K; Marin, E; Borowski, L; Hopkins, PE; Luo, J; Curtarolo, S; Brenner, DW; Vecchio, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Harrington, Tyler J.; Gild, Joshua; Sarker, Pranab; Toher, Cormac; Rost, Christina M.; Dippo, Olivia F.; McElfresh, Cameron; Kaufmann, Kevin; Marin, Eduardo; Borowski, Lucas; Hopkins, Patrick E.; Luo, Jian; Curtarolo, Stefano; Brenner, Donald W.; Vecchio, Kenneth S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase stability and mechanical properties of novel high entropy transition metal carbides", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Twelve different equiatomic five-metal carbides of group IVB, VB, and VIB refractory transition metals are synthesized via high-energy ball milling and spark plasma sintering. Implementation of a newly developed ab initio entropy descriptor aids in selection of candidate compositions for synthesis of high entropy and entropy stabilized carbides. Phase formation and composition uniformity are analyzed via XRD, EDS, STEM-EDS, and EXAFS. Nine of the twelve candidates form true single-phase materials with the rocksalt (B1) structure when sintered at 2473 K and can therefore be investigated as high entropy carbides (HECs). The composition (V0.2Nb0.2Ta0.2Mo0.2W0.2)C is presented as a likely candidate for further investigation as an entropy stabilized carbide. Seven of the carbides are examined for mechanical properties via nulloindentation. The HECs show significantly enhanced hardness when compared to a rule of mixtures average of the constituent binary carbides and to the highest hardness of the binary constituents. The mechanical properties are correlated to the electronic structure of the solid solutions, offering a future route to tunability of the mechanical properties of carbide ceramics via exploration of a new complex composition space. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 541, "Times Cited, All Databases": 581, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 166, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 280, "Article Number": null, "DOI": "10.1016/j.actamat.2018.12.054", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.12.054", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459358200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, BW; Seok, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Byung-wook; Seok, Sang Il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Instability of Inorganic-Organic Hybrid Halide Perovskite Materials", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid lead halide perovskite materials are used in solar cells and show efficiencies greater than 23%. Furthermore, they are applied in light-emitting diodes, X-ray detectors, thin-film transistors, thermoelectrics, and memory devices. Lead trihalide hybrid materials contain methylammonium (MA) or formamidinium (FA) (or a mixture), or long alkylammonium halides, as alternative organic cations. However, the intrinsic stability of hybrid lead halide perovskites is not very high, and they are chemically unstable when exposed to moisture, light, or heat because of their organic contents and low formation energies. Therefore, although improvements in the chemical stability are crucial, changing the material composition is challenging because it is directly related to the desired application requirements. Fortunately, hybrid lead halide perovskites have a very high tolerance toward changes in physical properties arising from doping or addition of different cations and anions, in many cases showing improved properties. Here, the intrinsic instability of hybrid lead halide perovskites is reviewed in relation to the crystal phase and chemical stability. It is suggested that FA should be used for lead halide perovskites for chemical stability instead of MA. Furthermore, additives that stabilize the crystal phase with alpha-FAPbI(3) should eschew MA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2019, "Volume": 31, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805337, "DOI": "10.1002/adma.201805337", "DOI Link": "http://dx.doi.org/10.1002/adma.201805337", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471970500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Yang, MX; Yuan, FP; Wu, GL; Wei, YJ; Huang, XX; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaolei; Yang, Muxin; Yuan, Fuping; Wu, Guilin; Wei, Yujie; Huang, Xiaoxu; Zhu, Yuntian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterogeneous lamella structure unites ultrafine-grain strength with coarse-grain ductility", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Grain refinement can make conventional metals several times stronger, but this comes at dramatic loss of ductility. Here we report a heterogeneous lamella structure in Ti produced by asymmetric rolling and partial recrystallization that can produce an unprecedented property combination: as strong as ultrafine-grained metal and at the same time as ductile as conventional coarse-grained metal. It also has higher strain hardening than coarse-grained Ti, which was hitherto believed impossible. The heterogeneous lamella structure is characterized with soft micrograined lamellae embedded in hard ultrafine-grained lamella matrix. The unusual high strength is obtained with the assistance of high back stress developed from heterogeneous yielding, whereas the high ductility is attributed to back-stress hardening and dislocation hardening. The process discovered here is amenable to large-scale industrial production at low cost, and might be applicable to other metal systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1471, "Times Cited, All Databases": 1557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2015, "Volume": 112, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14501, "End Page": 14505, "Article Number": null, "DOI": "10.1073/pnas.1517193112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1517193112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365173100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Jiao, MG; Lu, LL; Barkholtz, HM; Li, YP; Wang, Y; Jiang, LH; Wu, ZJ; Liu, DJ; Zhuang, L; Ma, C; Zeng, J; Zhang, BS; Su, DS; Song, P; Xing, W; Xu, WL; Wang, Y; Jiang, Z; Sun, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jing; Jiao, Menggai; Lu, Lanlu; Barkholtz, Heather M.; Li, Yuping; Wang, Ying; Jiang, Luhua; Wu, Zhijian; Liu, Di-Jia; Zhuang, Lin; Ma, Chao; Zeng, Jie; Zhang, Bingsen; Su, Dangsheng; Song, Ping; Xing, Wei; Xu, Weilin; Wang, Ying; Jiang, Zheng; Sun, Gongquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performance platinum single atom electrocatalyst for oxygen reduction reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/methanol tolerance for the cathodic oxygen reduction reaction. The acidic single-cell with such a catalyst as cathode delivers high performance, with power density up to 680 mW cm(-2) at 80 degrees C with a low platinum loading of 0.09 mg(Pt) cm(-2), corresponding to a platinum utilization of 0.13 g(Pt) kW(-1) in the fuel cell. Good fuel cell durability is also observed. Theoretical calculations reveal that the main effective sites on such platinum single-atom electrocatalysts are single-pyridinic-nitrogen-atom-anchored single-platinum-atom centres, which are tolerant to carbon monoxide/methanol, but highly active for the oxygen reduction reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 621, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15938, "DOI": "10.1038/ncomms15938", "DOI Link": "http://dx.doi.org/10.1038/ncomms15938", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406144700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, M; Cheng, YF; Yue, Y; Chen, Y; Gao, H; Li, L; Cai, B; Liu, WJ; Wang, ZY; Guo, HZ; Liu, NS; Gao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Mei; Cheng, Yongfa; Yue, Yang; Chen, Yu; Gao, Han; Li, Lei; Cai, Bin; Liu, Weijie; Wang, Ziyu; Guo, Haizhong; Liu, Nishuang; Gao, Yihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Flexible Pressure Sensor with a Self-Healing Function for Tactile Feedback", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance flexible pressure sensors have attracted a great deal of attention, owing to its potential applications such as human activity monitoring, man-machine interaction, and robotics. However, most high-performance flexible pressure sensors are complex and costly to manufacture. These sensors cannot be repaired after external mechanical damage and lack of tactile feedback applications. Herein, a high-performance flexible pressure sensor based on MXene/polyurethane (PU)/interdigital electrodes is fabricated by using a low-cost and universal spray method. The sprayed MXene on the spinosum structure PU and other arbitrary flexible substrates (represented by polyimide and membrane filter) act as the sensitive layer and the interdigital electrodes, respectively. The sensor shows an ultrahigh sensitivity (up to 509.8 kPa(-1)), extremely fast response speed (67.3 ms), recovery speed (44.8 ms), and good stability (10 000 cycles) due to the interaction between the sensitive layer and the interdigital electrodes. In addition, the hydrogen bond of PU endows the device with the self-healing function. The sensor can also be integrated with a circuit, which can realize tactile feedback function. This MXene-based high-performance pressure sensor, along with its designing/fabrication, is expected to be widely used in human activity detection, electronic skin, intelligent robots, and many other aspects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 9, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200507, "DOI": "10.1002/advs.202200507", "DOI Link": "http://dx.doi.org/10.1002/advs.202200507", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785894700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jellicoe, TC; Richter, JM; Glass, HFJ; Tabachnyk, M; Brady, R; Dutton, SE; Rao, A; Friend, RH; Credgington, D; Greenham, NC; Böhm, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jellicoe, Tom C.; Richter, Johannes M.; Glass, Hugh F. J.; Tabachnyk, Maxim; Brady, Ryan; Dutton, Sian E.; Rao, Akshay; Friend, Richard H.; Credgington, Dan; Greenham, Neil C.; Boehm, Marcus L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite nullocrystals", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskite crystal structures have emerged as a class of optoelectronic materials, which combine the ease of solution processability with excellent optical absorption and emission qualities. Restricting the physical dimensions of the perovskite crystallites to a few nullometers can also unlock spatial confinement effects, which allow large spectral tunability and high luminescence quantum yields at low excitation densities. However, the most promising perovskite structures rely on lead as a cationic species, thereby hindering commercial application. The replacement of lead with nontoxic alternatives such as tin has been demonstrated in bulk films, but not in spatially confined nullocrystals. Here, we synthesize CsSnX3 (X = Cl, Cl0.5Br05, Br, Br0.5I0.5, I) perovskite nullocrystals and provide evidence of their spectral tunability through both quantum confinement effects and control of the anionic composition. We show that luminescence from Sn-based perovskite nullocrystals occurs on pico- to nullosecond time scales via two spectrally distinct radiative decay processes, which we assign to band-to-band emission and radiative recombination at shallow intrinsic defect sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 827, "Times Cited, All Databases": 879, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2016, "Volume": 138, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2941, "End Page": 2944, "Article Number": null, "DOI": "10.1021/jacs.5b13470", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b13470", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371945800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, HS; Han, Y; Zhao, WQ; Yang, J; Zhang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Hongshuang; Han, Yi; Zhao, Weiqiang; Yang, Jing; Zhang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universally autonomous self-healing elastomer with high stretchability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing autonomous self-healing materials for applications in harsh conditions is challenging because the reconstruction of interaction in material for self-healing will experience significant resistance and fail. Herein, a universally self-healing and highly stretchable supramolecular elastomer is designed by synergistically incorporating multi-strength H-bonds and disulfide metathesis in polydimethylsiloxane polymers. The resultant elastomer exhibits high stretchability for both unnotched (14000%) and notched (1300%) samples. It achieves fast autonomous self-healing under universal conditions, including at room temperature (10min for healing), ultralow temperature (-40 degrees C), underwater (93% healing efficiency), supercooled high-concentrated saltwater (30% NaCl solution at -10 degrees C, 89% efficiency), and strong acid/alkali environment (pH = 0 or 14, 88% or 84% efficiency). These properties are attributable to synergistic interaction of the dynamic strong and weak H-bonds and stronger disulfide bonds. A self-healing and stretchable conducting device built with the developed elastomer is demonstrated, thereby providing a direction for future e-skin applications. Developing autonomous self-healing materials for application under extreme conditions is challenging. Here, the authors design a highly stretchable elastomer by incorporation of H-bonds and disulphide methathesis, which shows efficient self-healing under extreme conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2037, "DOI": "10.1038/s41467-020-15949-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15949-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530488100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bellardita, M; García-López, EI; Marcì, G; Krivtsov, I; García, JR; Palmisano, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bellardita, Marianna; Garcia-Lopez, Elisa I.; Marci, Giuseppe; Krivtsov, Igor; Garcia, Jose R.; Palmisano, Leonardo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective photocatalytic oxidation of aromatic alcohols in water by using P-doped g-C3N4", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A set of bare and P-doped graphitic carbon nitride (g-C3N4) photocatalysts has been prepared by thermal condensation of melamine, urea or thiourea. For the sake of comparison, a g-C3N4 sample obtained in the presence of cyanuric acid and thermally exfoliated C3N4 powders were also studied. The materials were physicochemically characterized and their photocatalytic activity was studied for the selective oxidation of benzyl alcohol (BA), 4-methoxy benzyl alcohol (4-MBA) and piperonyl alcohol (PA) in water suspension both under UV and visible light irradiation. The influence of the type and position of the substituents on conversion and selectivity to aldehyde was remarkable. The presence of P in the C3N4 material improved the selectivity of the reaction towards the aldehyde.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 220, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": 233, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.08.033", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.08.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412957200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Denissen, W; Rivero, G; Nicolaÿ, R; Leibler, L; Winne, JM; Du Prez, FE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Denissen, Wim; Rivero, Guadalupe; Nicolay, Renaud; Leibler, Ludwik; Winne, Johan M.; Du Prez, Filip E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vinylogous Urethane Vitrimers", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vitrimers are a new class of polymeric materials with very attractive properties, since they can be reworked to any shape while being at the same time permanently cross-linked. As an alternative to the use of transesterification chemistry, we explore catalyst-free transamination of vinylogous urethanes as an exchange reaction for vitrimers. First, a kinetic study on model compounds reveals the occurrence of transamination of vinylogous urethanes in a good temperature window without side reactions. Next, poly(vinylogous urethane) networks with a storage modulus of approximate to 2.4 GPa and a glass transition temperature above 80 degrees C are prepared by bulk polymerization of cyclohexane dimethanol bisacetoacetate, m-xylylene diamine, and tris(2-aminoethyl) amine. The vitrimer nature of these networks is examined by solubility, stress-relaxation, and creep experiments. Relaxation times as short as 85 s at 170 degrees C are observed without making use of any catalyst. In addition, the networks are recyclable up to four times by consecutive grinding/compression molding cycles without signifi cant mechanical or chemical degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 855, "Times Cited, All Databases": 940, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2015, "Volume": 25, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2451, "End Page": 2457, "Article Number": null, "DOI": "10.1002/adfm.201404553", "DOI Link": "http://dx.doi.org/10.1002/adfm.201404553", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353572600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, CX; Yang, J; Bai, S; Xu, WD; Yan, ZB; Xu, QY; Liu, JM; Zhang, WJ; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Chunxiong; Yang, Jie; Bai, Sai; Xu, Weidong; Yan, Zhibo; Xu, Qingyu; Liu, Junming; Zhang, Wenjing; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Performance and Stable All-Inorganic Metal Halide Perovskite-Based Photodetectors for Optical Communication Applications", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photodetectors are critical parts of an optical communication system for achieving efficient photoelectronic conversion of signals, and the response speed directly determines the bandwidth of the whole system. Metal halide perovskites, an emerging class of low-cost solution-processed semiconductors, exhibiting strong optical absorption, low trap states, and high carrier mobility, are widely investigated in photodetection applications. Herein, through optimizing the device engineering and film quality, high-performance photodetectors based on all-inorganic cesium lead halide perovskite (CsPbIxBr3-x), which simultaneously possess high sensitivity and fast response, are demonstrated. The optimized devices processed from CsPbIBr2 perovskite show a practically measured detectable limit of about 21.5 pW cm(-2) and a fast response time of 20 ns, which are both among the highest reported device performance of perovskite-based photodetectors. Moreover, the photodetectors exhibit outstanding long-term environmental stability, with negligible degradation of the photoresponse property after 2000 h under ambient conditions. In addition, the resulting perovskite photodetector is successfully integrated into an optical communication system and its applications as an optical signal receiver on transmitting text and audio signals is demonstrated. The results suggest that all-inorganic metal halide perovskite-based photodetectors have great application potential for optical communication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 467, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2018, "Volume": 30, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803422, "DOI": "10.1002/adma.201803422", "DOI Link": "http://dx.doi.org/10.1002/adma.201803422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444671900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hassan, Y; Park, JH; Crawford, ML; Sadhanala, A; Lee, J; Sadighian, JC; Mosconi, E; Shivanna, R; Radicchi, E; Jeong, M; Yang, C; Choi, H; Park, SH; Song, MH; De Angelis, F; Wong, CY; Friend, RH; Lee, BR; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hassan, Yasser; Park, Jong Hyun; Crawford, Michael L.; Sadhanala, Aditya; Lee, Jeongjae; Sadighian, James C.; Mosconi, Edoardo; Shivanna, Ravichandran; Radicchi, Eros; Jeong, Mingyu; Yang, Changduk; Choi, Hyosung; Park, Sung Heum; Song, Myoung Hoon; De Angelis, Filippo; Wong, Cathy Y.; Friend, Richard H.; Lee, Bo Ram; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand-engineered bandgap stability in mixed-halide perovskite LEDs", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskites are promising semiconductors for light-emitting applications because they exhibit bright, bandgap-tunable luminescence with high colour purity(1,2). Photoluminescence quantum yields close to unity have been achieved for perovskite nullocrystals across a broad range of emission colours, and light-emitting diodes with external quantum efficiencies exceeding 20 per cent-approaching those of commercial organic light-emitting diodes-have been demonstrated in both the infrared and the green emission channels(1,3,4). However, owing to the formation of lower-bandgap iodide-rich domains, efficient and colour-stable red electroluminescence from mixed-halide perovskites has not yet been realized(5,6). Here we report the treatment of mixed-halide perovskite nullocrystals with multidentate ligands to suppress halide segregation under electroluminescent operation. We demonstrate colour-stable, red emission centred at 620 nullometres, with an electroluminescence external quantum efficiency of 20.3 per cent. We show that a key function of the ligand treatment is to 'clean' the nullocrystal surface through the removal of lead atoms. Density functional theory calculations reveal that the binding between the ligands and the nullocrystal surface suppresses the formation of iodine Frenkel defects, which in turn inhibits halide segregation. Our work exemplifies how the functionality of metal halide perovskites is extremely sensitive to the nature of the (nullo)crystalline surface and presents a route through which to control the formation and migration of surface defects. This is critical to achieve bandgap stability for light emission and could also have a broader impact on other optoelectronic applications-such as photovoltaics-for which bandgap stability is required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2021, "Volume": 591, "Issue": 7848, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03217-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03217-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626921700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SW; Hua, MT; Alsaid, Y; Du, YJ; Ma, YF; Zhao, YS; Lo, CY; Wang, CR; Wu, D; Yao, BW; Strzalka, J; Zhou, H; Zhu, XY; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuwang; Hua, Mutian; Alsaid, Yousif; Du, Yingjie; Ma, Yanfei; Zhao, Yusen; Lo, Chiao-Yueh; Wang, Canran; Wu, Dong; Yao, Bowen; Strzalka, Joseph; Zhou, Hua; Zhu, Xinyuan; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(vinyl alcohol) Hydrogels with Broad-Range Tunable Mechanical Properties via the Hofmeister Effect", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels, exhibiting wide applications in soft robotics, tissue engineering, implantable electronics, etc., often require sophisticately tailoring of the hydrogel mechanical properties to meet specific demands. For examples, soft robotics necessitates tough hydrogels; stem cell culturing demands various tissue-matching modulus; and neuron probes desire dynamically tunable modulus. Herein, a strategy to broadly alter the mechanical properties of hydrogels reversibly via tuning the aggregation states of the polymer chains by ions based on the Hofmeister effect is reported. An ultratough poly(vinyl alcohol) (PVA) hydrogel as an exemplary material (toughness 150 +/- 20 MJ m(-3)), which surpasses synthetic polymers like poly(dimethylsiloxane), synthetic rubber, and natural spider silk is fabricated. With various ions, the hydrogel's various mechanical properties are continuously and reversibly in situ modulated over a large window: tensile strength from 50 +/- 9 kPa to 15 +/- 1 MPa, toughness from 0.0167 +/- 0.003 to 150 +/- 20 MJ m(-3), elongation from 300 +/- 100% to 2100 +/- 300%, and modulus from 24 +/- 2 to 2500 +/- 140 kPa. Importantly, the ions serve as gelation triggers and property modulators only, not necessarily required to remain in the gel, maintaining the high biocompatibility of PVA without excess ions. This strategy, enabling high mechanical performance and broad dynamic tunability, presents a universal platform for broad applications from biomedicine to wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 33, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007829, "DOI": "10.1002/adma.202007829", "DOI Link": "http://dx.doi.org/10.1002/adma.202007829", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615816100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yakunin, S; Sytnyk, M; Kriegner, D; Shrestha, S; Richter, M; Matt, GJ; Azimi, H; Brabec, CJ; Stangl, J; Kovalenko, MV; Heiss, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yakunin, Sergii; Sytnyk, Mykhailo; Kriegner, Dominik; Shrestha, Shreetu; Richter, Moses; Matt, Gebhard J.; Azimi, Hamed; Brabec, Christoph J.; Stangl, Julian; Kovalenko, Maksym V.; Heiss, Wolfgang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detection of X-ray photons by solution-processed lead halide perovskites", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The evolution of real-time medical diagnostic tools such as angiography and computer tomography from radiography based on photographic plates was enabled by the development of integrated solid-state X-ray photon detectors made from conventional solid-state semiconductors. Recently, for optoelectronic devices operating in the visible and near-infrared spectral regions, solution-processed organic and inorganic semiconductors have also attracted a great deal of attention. Here, we demonstrate a possibility to use such inexpensive semiconductors for the sensitive detection of X-ray photons by direct photon-to-current conversion. In particular, methylammonium lead iodide perovskite (CH3NH3PbI3) offers a compelling combination of fast photoresponse and a high absorption cross-section for X-rays, owing to the heavy Pb and I atoms. Solution-processed photodiodes as well as photoconductors are presented, exhibiting high values of X-ray sensitivity (up to 25 mu C mGy(air)(-1) cm(-3)) and responsivity (1.9 x 10(4) carriers/photon), which are commensurate with those obtained by the current solid-state technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 938, "Times Cited, All Databases": 1014, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 444, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.82", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.82", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357406300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ou, XY; Qin, X; Huang, BL; Zan, J; Wu, QX; Hong, ZZ; Xie, LL; Bian, HY; Yi, ZG; Chen, XF; Wu, YM; Song, XR; Li, J; Chen, QS; Yang, HH; Liu, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ou, Xiangyu; Qin, Xian; Huang, Bolong; Zan, Jie; Wu, Qinxia; Hong, Zhongzhu; Xie, Lili; Bian, Hongyu; Yi, Zhigao; Chen, Xiaofeng; Wu, Yiming; Song, Xiaorong; Li, Juan; Chen, Qiushui; Yang, Huanghao; Liu, Xiaogang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-resolution X-ray luminescence extension imaging", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current X-ray imaging technologies involving flat-panel detectors have difficulty in imaging three-dimensional objects because fabrication of large-area, flexible, silicon-based photodetectors on highly curved surfaces remains a challenge(1-3). Here we demonstrate ultralong-lived X-ray trapping for flat-panel-free, high-resolution, three-dimensional imaging using a series of solution-processable, lanthanide-doped nulloscintillators. Corroborated by quantum mechanical simulations of defect formation and electronic structures, our experimental characterizations reveal that slow hopping of trapped electrons due to radiation-triggered anionic migration in host lattices can induce more than 30 days of persistent radioluminescence. We further demonstrate X-ray luminescence extension imaging with resolution greater than 20 line pairs per millimetre and optical memory longer than 15 days. These findings provide insight into mechanisms underlying X-ray energy conversion through enduring electron trapping and offer a paradigm to motivate future research in wearable X-ray detectors for patient-centred radiography and mammography, imaging-guided therapeutics, high-energy physics and deep learning in radiology. Using lanthanide-doped nullomaterials and flexible substrates, an approach that enables flat-panel-free, high-resolution, three-dimensional imaging is demonstrated and termed X-ray luminescence extension imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2021, "Volume": 590, "Issue": 7846, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03251-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03251-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683860300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YB; Fu, J; Zhong, C; Wu, TP; Chen, ZW; Hu, WB; Amine, K; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yingbo; Fu, Jing; Zhong, Cheng; Wu, Tianpin; Chen, Zhongwei; Hu, Wenbin; Amine, Khalil; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Advances in Flexible Zinc-Based Rechargeable Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible Zn-based batteries are regarded as promising alternatives to flexible lithium-ion batteries for wearable electronics owing to the natural advantages of zinc, such as environmental friendliness and low cost. In the past few years, flexible Zn-based batteries have been studied intensively and exciting achievements have been obtained in this field. However, the development of flexible Zn-based batteries is still at an early stage. The challenges of developing flexible lithium-ion batteries are presented here. Then, a brief overview of recent progress in flexible zinc secondary batteries from the perspective of advanced materials and some issues that remain to be addressed are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802605, "DOI": "10.1002/aenm.201802605", "DOI Link": "http://dx.doi.org/10.1002/aenm.201802605", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454769900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Wen, YW; Hu, XL; Ji, XL; Yan, MY; Mai, LQ; Hu, P; Shan, B; Huang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chaoji; Wen, Yanwei; Hu, Xianluo; Ji, Xiulei; Yan, Mengyu; Mai, Liqiang; Hu, Pei; Shan, Bin; Huang, Yunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are emerging as a highly promising technology for large-scale energy storage applications. However, it remains a significant challenge to develop an anode with superior long-term cycling stability and high-rate capability. Here we demonstrate that the Na+ intercalation pseudocapacitance in TiO2/graphene nullocomposites enables high-rate capability and long cycle life in a sodium-ion battery. This hybrid electrode exhibits a specific capacity of above 90mAh g(-1) at 12,000mAg(-1) (similar to 36 C). The capacity is highly reversible for more than 4,000 cycles, the longest demonstrated cyclability to date. First-principle calculations demonstrate that the intimate integration of graphene with TiO2 reduces the diffusion energy barrier, thus enhancing the Na+ intercalation pseudocapacitive process. The Na-ion intercalation pseudocapacitance enabled by tailor-deigned nullostructures represents a promising strategy for developing electrode materials with high power density and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1061, "Times Cited, All Databases": 1081, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6929, "DOI": "10.1038/ncomms7929", "DOI Link": "http://dx.doi.org/10.1038/ncomms7929", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JL; Li, XY; Xiong, JB; Yuan, CQ; Semin, S; Rasing, T; Bu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jialiang; Li, Xinyue; Xiong, Jianbo; Yuan, Chunqing; Semin, Sergey; Rasing, Theo; Bu, Xian-He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halide Perovskites for Nonlinear Optics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskites provide an ideal platform for engineering highly promising semiconductor materials for a wide range of applications in optoelectronic devices, such as photovoltaics, light-emitting diodes, photodetectors, and lasers. More recently, increasing research efforts have been directed toward the nonlinear optical properties of halide perovskites because of their unique chemical and electronic properties, which are of crucial importance for advancing their applications in next-generation photonic devices. Here, the current state of the art in the field of nonlinear optics (NLO) in halide perovskite materials is reviewed. Halide perovskites are categorized into hybrid organic/inorganic and pure inorganic ones, and their second-, third-, and higher-order NLO properties are summarized. The performance of halide perovskite materials in NLO devices such as upconversion lasers and ultrafast laser modulators is analyzed. Several potential perspectives and research directions of these promising materials for nonlinear optics are presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2020, "Volume": 32, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806736, "DOI": "10.1002/adma.201806736", "DOI Link": "http://dx.doi.org/10.1002/adma.201806736", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508654900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Han, XP; Cheng, FY; Hu, YX; Chen, CC; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chun; Han, Xiaopeng; Cheng, Fangyi; Hu, Yuxiang; Chen, Chengcheng; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase and composition controllable synthesis of cobalt manganese spinel nulloparticles towards efficient oxygen electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spinel-type oxides are technologically important in many fields, including electronics, magnetism, catalysis and electrochemical energy storage and conversion. Typically, these materials are prepared by conventional ceramic routes that are energy consuming and offer limited control over shape and size. Moreover, for mixed-metal oxide spinels (for example, CoxMn3-xO4), the crystallographic phase sensitively correlates with the metal ratio, posing great challenges to synthesize active product with simultaneously tuned phase and composition. Here we report a general synthesis of ultrasmall cobalt manganese spinels with tailored structural symmetry and composition through facile solution-based oxidationprecipitation and insertion-crystallization process at modest condition. As an example application, the nullocrystalline spinels catalyse the oxygen reduction/evolution reactions, showing phase and composition co-dependent performance. Furthermore, the mild synthetic strategy allows the formation of homogeneous and strongly coupled spinel/carbon nullocomposites, which exhibit comparable activity but superior durability to Pt/C and serve as efficient catalysts to build rechargeable Zn-air and Li-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 536, "Times Cited, All Databases": 566, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7345, "DOI": "10.1038/ncomms8345", "DOI Link": "http://dx.doi.org/10.1038/ncomms8345", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357173300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karapinar, D; Huan, NT; Sahraie, NR; Li, JK; Wakerley, D; Touati, N; Zanna, S; Taverna, D; Tizei, LHG; Zitolo, A; Jaouen, F; Mougel, V; Fontecave, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karapinar, Dilan; Huan, Ngoc Tran; Sahraie, Nastaran Ranjbar; Li, Jingkun; Wakerley, David; Touati, Nadia; Zanna, Sandrine; Taverna, Dario; Tizei, Luiz Henrique Galvao; Zitolo, Andrea; Jaouen, Frederic; Mougel, Victor; Fontecave, Marc", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electroreduction of CO2 on Single-Site Copper-Nitrogen-Doped Carbon Material: Selective Formation of Ethanol and Reversible Restructuration of the Metal Sites", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is generally believed that CO2 electroreduction to multi-carbon products such as ethanol or ethylene may be catalyzed with significant yield only on metallic copper surfaces, implying large ensembles of copper atoms. Here, we report on an inexpensive Cu-N-C material prepared via a simple pyrolytic route that exclusively feature single copper atoms with a CuN4 coordination environment, atomically dispersed in a nitrogen-doped conductive carbon matrix. This material achieves aqueous CO2 electroreduction to ethanol at a Faradaic yield of 55 % under optimized conditions (electrolyte: 0.1 m CsHCO3, potential: -1.2 V vs. RHE and gas-phase recycling set up), as well as CO electroreduction to C-2-products (ethanol and ethylene) with a Faradaic yield of 80 %. During electrolysis the isolated sites transiently convert into metallic copper nulloparticles, as shown by operando XAS analysis, which are likely to be the catalytically active species. Remarkably, this process is reversible and the initial material is recovered intact after electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2019, "Volume": 58, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15098, "End Page": 15103, "Article Number": null, "DOI": "10.1002/anie.201907994", "DOI Link": "http://dx.doi.org/10.1002/anie.201907994", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485492500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, M; Luo, YF; Wang, T; Wan, CJ; Pan, L; Pan, SW; He, K; Neo, A; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ming; Luo, Yifei; Wang, Ting; Wan, Changjin; Pan, Liang; Pan, Shaowu; He, Ke; Neo, Aden; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial Skin Perception", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin is the largest organ, with the functionalities of protection, regulation, and sensation. The emulation of human skin via flexible and stretchable electronics gives rise to electronic skin (e-skin), which has realized artificial sensation and other functions that cannot be achieved by conventional electronics. To date, tremendous progress has been made in data acquisition and transmission for e-skin systems, while the implementation of perception within systems, that is, sensory data processing, is still in its infancy. Integrating the perception functionality into a flexible and stretchable sensing system, namely artificial skin perception, is critical to endow current e-skin systems with higher intelligence. Here, recent progress in the design and fabrication of artificial skin perception devices and systems is summarized, and challenges and prospects are discussed. The strategies for implementing artificial skin perception utilize either conventional silicon-based circuits or novel flexible computing devices such as memristive devices and synaptic transistors, which enable artificial skin to surpass human skin, with a distributed, low-latency, and energy-efficient information-processing ability. In future, artificial skin perception would be a new enabling technology to construct next-generation intelligent electronic devices and systems for advanced applications, such as robotic surgery, rehabilitation, and prosthetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 33, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003014, "DOI": "10.1002/adma.202003014", "DOI Link": "http://dx.doi.org/10.1002/adma.202003014", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569893900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goossens, S; Navickaite, G; Monasterio, C; Gupta, S; Piqueras, JJ; Pérez, R; Burwell, G; Nikitskiy, I; Lasanta, T; Galán, T; Puma, E; Centeno, A; Pesquera, A; Zurutuza, A; Konstantatos, G; Koppens, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goossens, Stijn; Navickaite, Gabriele; Monasterio, Carles; Gupta, Shuchi; Piqueras, Juan Jos; Perez, Raul; Burwell, Gregory; Nikitskiy, Ivan; Lasanta, Tania; Galan, Teresa; Puma, Eric; Centeno, Alba; Pesquera, Amaia; Zurutuza, Amaia; Konstantatos, Gerasimos; Koppens, Frank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband image sensor array based on graphene-CMOS integration", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integrated circuits based on complementary metal-oxide-semiconductors (CMOS) are at the heart of the technological revolution of the past 40 years, enabling compact and low-cost microelectronic circuits and imaging systems. However, the diversification of this platform into applications other than microcircuits and visible-light cameras has been impeded by the difficulty to combine semiconductors other than silicon with CMOS. Here, we report the monolithic integration of a CMOS integrated circuit with graphene, operating as a high-mobility phototransistor. We demonstrate a high-resolution, broadband image sensor and operate it as a digital camera that is sensitive to ultraviolet, visible and infrared light (300-2,000 nm). The demonstrated graphene-CMOS integration is pivotal for incorporating 2D materials into the next-generation microelectronics, sensor arrays, low-power integrated photonics and CMOS imaging systems covering visible, infrared and terahertz frequencies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 640, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 366, "End Page": 371, "Article Number": null, "DOI": "10.1038/NPHOTON.2017.75", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2017.75", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402602500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Zhang, JT; Guan, BY; Wang, D; Liu, LM; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhen; Zhang, Jintao; Guan, Buyuan; Wang, Da; Liu, Li-Min; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries show advantages for next-generation electrical energy storage due to their high energy density and cost effectiveness. Enhancing the conductivity of the sulfur cathode and moderating the dissolution of lithium polysulfides are two key factors for the success of lithium-sulfur batteries. Here we report a sulfur host that overcomes both obstacles at once. With inherent metallic conductivity and strong adsorption capability for lithium-polysulfides, titanium monoxide@carbon hollow nullospheres can not only generate sufficient electrical contact to the insulating sulfur for high capacity, but also effectively confine lithium-polysulfides for prolonged cycle life. Additionally, the designed composite cathode further maximizes the lithium-polysulfide restriction capability by using the polar shells to prevent their outward diffusion, which avoids the need for chemically bonding all lithium-polysulfides on the surfaces of polar particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 615, "Times Cited, All Databases": 639, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13065, "DOI": "10.1038/ncomms13065", "DOI Link": "http://dx.doi.org/10.1038/ncomms13065", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385729500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, DW; Liu, TF; Su, J; Bosch, M; Wei, ZW; Wan, W; Yuan, DQ; Chen, YP; Wang, X; Wang, KC; Lian, XZ; Gu, ZY; Park, J; Zou, XD; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Dawei; Liu, Tian-Fu; Su, Jie; Bosch, Mathieu; Wei, Zhangwen; Wan, Wei; Yuan, Daqiang; Chen, Ying-Pin; Wang, Xuan; Wang, Kecheng; Lian, Xizhen; Gu, Zhi-Yuan; Park, Jihye; Zou, Xiaodong; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymatic catalytic processes possess great potential in chemical manufacturing, including pharmaceuticals, fuel production and food processing. However, the engineering of enzymes is severely hampered due to their low operational stability and difficulty of reuse. Here, we develop a series of stable metal-organic frameworks with rationally designed ultra-large mesoporous cages as single-molecule traps (SMTs) for enzyme encapsulation. With a high concentration of mesoporous cages as SMTs, PCN-333(Al) encapsulates three enzymes with record-high loadings and recyclability. Immobilized enzymes that most likely undergo single-enzyme encapsulation (SEE) show smaller Km than free enzymes while maintaining comparable catalytic efficiency. Under harsh conditions, the enzyme in SEE exhibits better performance than free enzyme, showing the effectiveness of SEE in preventing enzyme aggregation or denaturation. With extraordinarily large pore size and excellent chemical stability, PCN-333 may be of interest not only for enzyme encapsulation, but also for entrapment of other nulloscaled functional moieties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 557, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5979, "DOI": "10.1038/ncomms6979", "DOI Link": "http://dx.doi.org/10.1038/ncomms6979", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348811700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, SW; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Shengwei; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric-field switching of two-dimensional van der Waals magnets", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling magnetism by purely electrical means is a key challenge to better information technology(1). A variety of material systems, including ferromagnetic (FM) metals(2-4), FM semiconductors(5), multiferroics(6-8) and magnetoelectric (ME) materials(9,10), have been explored for the electric-field control of magnetism. The recent discovery of two-dimensional (2D) van der Waals magnets(11,12) has opened a new door for the electrical control of magnetism at the nullometre scale through a van der Waals heterostructure device platform(13). Here we demonstrate the control of magnetism in bilayer CrI3, an antiferromagnetic (AFM) semiconductor in its ground state(12), by the application of small gate voltages in field-effect devices and the detection of magnetization using magnetic circular dichroism (MCD) microscopy. The applied electric field creates an interlayer potential difference, which results in a large linear ME effect, whose sign depends on the interlayer AFM order. We also achieve a complete and reversible electrical switching between the interlayer AFM and FM states in the vicinity of the interlayer spin-flip transition. The effect originates from the electric-field dependence of the interlayer exchange bias.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 742, "Times Cited, All Databases": 810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 17, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-018-0040-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-018-0040-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430942800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nam, KW; Park, SS; dos Reis, R; Dravid, VP; Kim, H; Mirkin, CA; Stoddart, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nam, Kwan Woo; Park, Sarah S.; dos Reis, Roberto; Dravid, Vinayak P.; Kim, Heejin; Mirkin, Chad A.; Stoddart, J. Fraser", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, there is considerable interest in developing advanced rechargeable batteries that boast efficient distribution of electricity and economic feasibility for use in large-scale energy storage systems. Rechargeable aqueous zinc batteries are promising alternatives to lithium-ion batteries in terms of rate performance, cost, and safety. In this investigation, we employ Cu-3(HHTP)(2), a two-dimensional (2D) conductive metal-organic framework (MOF) with large one-dimensional channels, as a zinc battery cathode. Owing to its unique structure, hydrated Zn2+ ions which are inserted directly into the host structure, Cu-3(HHTP)(2), allow high diffusion rate and low interfacial resistance which enable the Cu-3(HHTP) 2 cathode to follow the intercalation pseudocapacitance mechanism. Cu-3(HHTP)(2) exhibits a high reversible capacity of 228 mAh g(-1) at 50 mA g(-1). At a high current density of 4000 mA g(-1) (-18 C), 75.0% of the initial capacity is maintained after 500 cycles. These results provide key insights into high-performance, 2D conductive MOF designs for battery electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4948, "DOI": "10.1038/s41467-019-12857-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12857-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493275600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JR; Bai, DL; Jin, ZW; Bian, H; Wang, K; Sun, J; Wang, Q; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jingru; Bai, Dongliang; Jin, Zhiwen; Bian, Hui; Wang, Kang; Sun, Jie; Wang, Qian; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D-2D-0D Interface Profiling for Record Efficiency All-Inorganic CsPbBrI2 Perovskite Solar Cells with Superior Stability", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic CsPbBrI2 perovskite has great advantages in terms of ambient phase stability and suitable band gap (1.91 eV) for photovoltaic applications. However, the typically used structure causes reduced device performance, primarily due to the large recombination at the interface between the perovskite, and the hole-extraction layer (HEL). In this paper, an efficient CsPbBrI2 perovskite solar cell (PSC) with a dimensionally graded heterojunction is reported, in which the CsPbBrI2 material is distributed within bulk-nullosheet-quantum dots or 3D-2D-0D dimension-profiled interface structure so that the energy alignment is optimized in between the valence and conduction bands of both CsPbBrI2 and the HEL layers. Specifically, the valence-/conduction-band edge is leveraged to bend with synergistic advantages: the graded combination enhances the hole extraction and conduction efficiency with effectively decreased recombination loss during the hole-transfer process, leading to an enhanced built-in electric field, hence a high V-OC of as much as 1.19 V. The profiled structure induces continuously upshifted energy levels, resulting in a higher J(SC) of as much as 12.93 mA cm(-2) and fill factor as high as 80.5%, and therefore record power conversion efficiency (PCE) of 12.39%. As far as it is known, this is the highest PCE for CsPbBrI2 perovskite-based PSC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 616, "Times Cited, All Databases": 628, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2018, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703246, "DOI": "10.1002/aenm.201703246", "DOI Link": "http://dx.doi.org/10.1002/aenm.201703246", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434031400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HJ; Hao, Q; Chen, T; Zhang, LH; Chen, DM; Ma, C; Yao, WQ; Zhu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Haojie; Hao, Qiang; Chen, Tong; Zhang, Linghua; Chen, Daimei; Ma, Chao; Yao, Wenqing; Zhu, Yongfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-performance Bi2O3/Bi2SiO5 p-n heterojunction photocatalyst induced by phase transition of Bi2O3", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, Bi2O3/Bi2SiO5 p-n heterojunction photocatalyst was successfully fabricated via a facile one-step synthesis using Bi(NO3)(3) and nullo-SiO2 as precursors. With the increasing amount of SiO2, alpha-Bi2O3 gradually transferred into beta-Bi2O3, and Bi2O3/Bi2SiO5 p-n heterojunction was obtained at the same time. The as-prepared samples were systematically characterized by XRD, scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS). The Bi2O3/Bi2SiO5 heterojunction photocatalysts exhibited higher photocatalytic activity than alpha-Bi2O3 on the degradation of organic pollutants under simulated sunlight irradiation. The enhanced photocatalytic activity could be ascribed to the larger specific surface area, the larger contact angle, the formation of beta-Bi2O3 and construction of p-n heterojunction. More importantly, the phase transition mechanism of Bi2O3 in Bi2O3/Bi2SiO5 heterojunction photocatalyst was proposed, which is significant for the theoretical study and application of photocatalytic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2018, "Volume": 237, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": 67, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.05.069", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.05.069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442973700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cong, S; Yuan, YY; Chen, ZG; Hou, JY; Yang, M; Su, YL; Zhang, YY; Li, L; Li, QW; Geng, FX; Zhao, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cong, Shan; Yuan, Yinyin; Chen, Zhigang; Hou, Junyu; Yang, Mei; Su, Yanli; Zhang, Yongyi; Li, Liang; Li, Qingwen; Geng, Fengxia; Zhao, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Noble metal-comparable SERS enhancement from semiconducting metal oxides by making oxygen vacancies", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface-enhanced Raman spectroscopy (SERS) represents a very powerful tool for the identification of molecular species, but unfortunately it has been essentially restricted to noble metal supports (Au, Ag and Cu). While the application of semiconductor materials as SERS substrate would enormously widen the range of uses for this technique, the detection sensitivity has been much inferior and the achievable SERS enhancement was rather limited, thereby greatly limiting the practical applications. Here we report the employment of non-stoichiometric tungsten oxide nullostructure, sea urchin-like W18O49 nullowire, as the substrate material, to magnify the substrate-analyte molecule interaction, leading to significant magnifications in Raman spectroscopic signature. The enrichment of surface oxygen vacancy could bring additional enhancements. The detection limit concentration was as low as 10(-7) M and the maximum enhancement factor was 3.4 x 10(5), in the rank of the highest sensitivity, to our best knowledge, among semiconducting materials, even comparable to noble metals without 'hot spots'.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 605, "Times Cited, All Databases": 623, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7800, "DOI": "10.1038/ncomms8800", "DOI Link": "http://dx.doi.org/10.1038/ncomms8800", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358860100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YZ; Ma, YH; Zhao, YB; Sun, XX; Gandara, F; Furukawa, H; Liu, Z; Zhu, HY; Zhu, CH; Suenaga, K; Oleynikov, P; Alshammari, AS; Zhang, X; Terasaki, O; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuzhong; Ma, Yanhang; Zhao, Yingbo; Sun, Xixi; Gandara, Felipe; Furukawa, Hiroyasu; Liu, Zheng; Zhu, Hanyu; Zhu, Chenhui; Suenaga, Kazutomo; Oleynikov, Peter; Alshammari, Ahmad S.; Zhang, Xiang; Terasaki, Osamu; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weaving of organic threads into a crystalline covalent organic framework", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A three-dimensional covalent organic framework (COF-505) constructed from helical organic threads, designed to be mutually weaving at regular intervals, has been synthesized by imine condensation reactions of aldehyde functionalized copper(I)-bisphenullthroline tetrafluoroborate, Cu(PDB)(2)(BF4), and benzidine (BZ). The copper centers are topologically independent of the weaving within the COF structure and serve as templates for bringing the threads into a woven pattern rather than the more commonly observed parallel arrangement. The copper(I) ions can be reversibly removed and added without loss of the COF structure, for which a tenfold increase in elasticity accompanies its demetalation. The threads in COF-505 have many degrees of freedom for enormous deviations to take place between them, throughout the material, without undoing the weaving of the overall structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 466, "Times Cited, All Databases": 505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2016, "Volume": 351, "Issue": 6271, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 365, "End Page": 369, "Article Number": null, "DOI": "10.1126/science.aad4011", "DOI Link": "http://dx.doi.org/10.1126/science.aad4011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368440500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vyas, VS; Haase, F; Stegbauer, L; Savasci, G; Podjaski, F; Ochsenfeld, C; Lotsch, BV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vyas, Vijay S.; Haase, Frederik; Stegbauer, Linus; Savasci, Goekcen; Podjaski, Filip; Ochsenfeld, Christian; Lotsch, Bettina V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A tunable azine covalent organic framework platform for visible light-induced hydrogen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution from photocatalytic reduction of water holds promise as a sustainable source of carbon-free energy. Covalent organic frameworks (COFs) present an interesting new class of photoactive materials, which combine three key features relevant to the photocatalytic process, namely crystallinity, porosity and tunability. Here we synthesize a series of water-and photostable 2D azine-linked COFs from hydrazine and triphenylarene aldehydes with varying number of nitrogen atoms. The electronic and steric variations in the precursors are transferred to the resulting frameworks, thus leading to a progressively enhanced light-induced hydrogen evolution with increasing nitrogen content in the frameworks. Our results demonstrate that by the rational design of COFs on a molecular level, it is possible to precisely adjust their structural and optoelectronic properties, thus resulting in enhanced photocatalytic activities. This is expected to spur further interest in these photofunctional frameworks where rational supramolecular engineering may lead to new material applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 988, "Times Cited, All Databases": 1034, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8508, "DOI": "10.1038/ncomms9508", "DOI Link": "http://dx.doi.org/10.1038/ncomms9508", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363149200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Diao, JX; Qiu, Y; Liu, SQ; Wang, WT; Chen, K; Li, HL; Yuan, WY; Qu, YT; Guo, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Diao, Jinxiang; Qiu, Yu; Liu, Shuangquan; Wang, Weitao; Chen, Kai; Li, Hailong; Yuan, Wenyu; Qu, Yunteng; Guo, Xiaohui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Engineering of W2N/WC Heterostructures Derived from Solid-State Synthesis: A Highly Efficient Trifunctional Electrocatalyst for ORR, OER, and HER", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To meet the practical demand of overall water splitting and regenerative metal-air batteries, highly efficient, low-cost, and durable electrocatalysts for the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) are required to displace noble metal catalysts. In this work, a facile solid-state synthesis strategy is developed to construct the interfacial engineering of W2N/WC heterostructures, in which abundant interfaces are formed. Under high temperature (800 degrees C), volatile CNx species from dicyanodiamide are trapped by WO3 nullorods, followed by simultaneous nitridation and carbonization, to form W2N/WC heterostructure catalysts. The resultant W2N/WC heterostructure catalysts exhibit an efficient and stable electrocatalytic performance toward the ORR, OER, and HER, including a half-wave potential of 0.81 V (ORR) and a low overpotential at 10 mA cm(-2) for the OER (320 mV) and HER (148.5 mV). Furthermore, a W2N/WC-based Zn-air battery shows outstanding high power density (172 mW cm(-2)). Density functional theory and X-ray absorption fine structure analysis computations reveal that W2N/WC interfaces synergistically facilitate transport and separation of charge, thus accelerating the electrochemical ORR, OER, and HER. This work paves a novel avenue for constructing efficient and low-cost electrocatalysts for electrochemical energy devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 32, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1905679, "DOI": "10.1002/adma.201905679", "DOI Link": "http://dx.doi.org/10.1002/adma.201905679", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496844000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, G; Sun, JH; Hou, WP; Jiang, SD; Huang, Y; Geng, JX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guoxing; Sun, Jinhua; Hou, Wenpeng; Jiang, Shidong; Huang, Yong; Geng, Jianxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional porous carbon composites containing high sulfur nulloparticle content for high-performance lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfur is a promising cathode material for lithium-sulfur batteries because of its high theoretical capacity (1,675 mA h g(-1)); however, its low electrical conductivity and the instability of sulfur-based electrodes limit its practical application. Here we report a facile in situ method for preparing three-dimensional porous graphitic carbon composites containing sulfur nulloparticles (3D S@PGC). With this strategy, the sulfur content of the composites can be tuned to a high level (up to 90 wt%). Because of the high sulfur content, the nulloscale distribution of the sulfur particles, and the covalent bonding between the sulfur and the PGC, the developed 3D S@PGC cathodes exhibit excellent performance, with a high sulfur utilization, high specific capacity (1,382, 1,242 and 1,115 mA h g(-1) at 0.5, 1 and 2 C, respectively), long cycling life (small capacity decay of 0.039% per cycle over 1,000 cycles at 2 C) and excellent rate capability at a high charge/discharge current.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 742, "Times Cited, All Databases": 775, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10601, "DOI": "10.1038/ncomms10601", "DOI Link": "http://dx.doi.org/10.1038/ncomms10601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371019700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, X; Song, HB; Lin, SZ; Zhou, Y; Zhan, XJ; Hu, ZM; Zhang, Q; Sun, JY; Yang, B; Li, TQ; Jiao, LY; Zhou, J; Tang, J; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Xu; Song, Huaibing; Lin, Shizhe; Zhou, Ying; Zhan, Xiaojun; Hu, Zhimi; Zhang, Qi; Sun, Jiyu; Yang, Bo; Li, Tianqi; Jiao, Liying; Zhou, Jun; Tang, Jiang; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable salt-templated synthesis of two-dimensional transition metal oxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional atomic crystals, such as two-dimensional oxides, have attracted much attention in energy storage because nearly all of the atoms can be exposed to the electrolyte and involved in redox reactions. However, current strategies are largely limited to intrinsically layered compounds. Here we report a general strategy that uses the surfaces of water-soluble salt crystals as growth templates and is applicable to not only layered compounds but also various transition metal oxides, such as hexagonal-MoO3, MoO2, MnO and hexagonal-WO3. The planar growth is hypothesized to occur via a match between the crystal lattices of the salt and the growing oxide. Restacked two-dimensional hexagonal-MoO3 exhibits high pseudocapacitive performances (for example, 300 F cm(-3) in an Al-2(SO4)(3) electrolyte). The synthesis of various two-dimensional transition metal oxides and the demonstration of high capacitance are expected to enable fundamental studies of dimensionality effects on their properties and facilitate their use in energy storage and other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11296, "DOI": "10.1038/ncomms11296", "DOI Link": "http://dx.doi.org/10.1038/ncomms11296", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374574000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZK; Zhou, B; Zhang, Y; Wang, ZJ; Weng, HM; Prabhakaran, D; Mo, SK; Shen, ZX; Fang, Z; Dai, X; Hussain, Z; Chen, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Z. K.; Zhou, B.; Zhang, Y.; Wang, Z. J.; Weng, H. M.; Prabhakaran, D.; Mo, S-K; Shen, Z. X.; Fang, Z.; Dai, X.; Hussain, Z.; Chen, Y. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of a Three-Dimensional Topological Dirac Semimetal, Na3Bi", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) topological Dirac semimetals (TDSs) represent an unusual state of quantum matter that can be viewed as 3D graphene. In contrast to 2D Dirac fermions in graphene or on the surface of 3D topological insulators, TDSs possess 3D Dirac fermions in the bulk. By investigating the electronic structure of Na3Bi with angle-resolved photoemission spectroscopy, we detected 3D Dirac fermions with linear dispersions along all momentum directions. Furthermore, we demonstrated the robustness of 3D Dirac fermions in Na3Bi against in situ surface doping. Our results establish Na3Bi as a model system for 3D TDSs, which can serve as an ideal platform for the systematic study of quantum phase transitions between rich topological quantum states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1970, "Times Cited, All Databases": 2081, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2014, "Volume": 343, "Issue": 6173, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 864, "End Page": 867, "Article Number": null, "DOI": "10.1126/science.1245085", "DOI Link": "http://dx.doi.org/10.1126/science.1245085", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331552600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, W; Yan, PY; Li, BY; Bahri, M; Liu, LJ; Zhou, X; Clowes, R; Browning, ND; Wu, Y; Ward, JW; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Wei; Yan, Peiyao; Li, Boyu; Bahri, Mounib; Liu, Lunjie; Zhou, Xiang; Clowes, Rob; Browning, Nigel D.; Wu, Yue; Ward, John W.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-throughput sonochemical synthesis and testing strategy was developed to discover covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers were synthesized, including 60 crystalline COFs of which 18 were previously unreported. These COFs were then screened for photocatalytic hydrogen peroxide (H2O2) production using water and oxygen. One of these COFs, sonoCOF-F2, was found to be an excellent photocatalyst for photocatalytic H2O2 production even in the absence of sacrificial donors. However, after long-term photocatalytic tests (96 h), the imine sonoCOF-F2 transformed into an amide-linked COF with reduced crystallinity and loss of electronic conjugation, decreasing the photocatalytic activity. When benzyl alcohol was introduced to form a two-phase catalytic system, the photostability of sonoCOF-F2 was greatly enhanced, leading to stable H2O2 production for at least 1 week.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2022, "Volume": 144, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9902, "End Page": 9909, "Article Number": null, "DOI": "10.1021/jacs.2c02666", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c02666", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810004300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seo, DH; Lee, J; Urban, A; Malik, R; Kang, S; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander; Malik, Rahul; Kang, ShinYoung; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries are now reaching the energy density limits set by their electrode materials, requiring new paradigms for Li+ and electron hosting in solid-state electrodes. Reversible oxygen redox in the solid state in particular has the potential to enable high energy density as it can deliver excess capacity beyond the theoretical transition-metal redox-capacity at a high voltage. Nevertheless, the structural and chemical origin of the process is not understood, preventing the rational design of better cathode materials. Here, we demonstrate how very specific local Li-excess environments around oxygen atoms necessarily lead to labile oxygen electrons that can be more easily extracted and participate in the practical capacity of cathodes. The identification of the local structural components that create oxygen redox sets a new direction for the design of high-energy-density cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1190, "Times Cited, All Databases": 1265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 692, "End Page": 697, "Article Number": null, "DOI": "10.1038/NCHEM.2524", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2524", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378280400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, J; Sun, YM; Pasta, M; Zhou, GM; Li, YZ; Liu, W; Xiong, F; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Jie; Sun, Yongming; Pasta, Mauro; Zhou, Guangmin; Li, Yuzhang; Liu, Wei; Xiong, Feng; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entrapment of Polysulfides by a Black-Phosphorus-Modified Separator for Lithium-Sulfur Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A bifunctional separator modified by black-phosphorus nulloflakes is prepared to overcome the challenges associated with the polysulfide diffusion in lithium-sulfur batteries. It brings the benefits of the entrapment of various sulfur species via the strong binding energy and reactivation of the trapped sulfur species due to its high electron conductivity as well as Li-ion diffusivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2016, "Volume": 28, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9797, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201602172", "DOI Link": "http://dx.doi.org/10.1002/adma.201602172", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392721400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, GD; Zhao, ZJ; Mu, RT; Zha, SJ; Li, LL; Chen, S; Zang, KT; Luo, J; Li, ZL; Purdy, SC; Kropf, AJ; Miller, JT; Zeng, L; Gong, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Guodong; Zhao, Zhi-Jian; Mu, Rentao; Zha, Shenjun; Li, Lulu; Chen, Sai; Zang, Ketao; Luo, Jun; Li, Zhenglong; Purdy, Stephen C.; Kropf, A. Jeremy; Miller, Jeffrey T.; Zeng, Liang; Gong, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble-metal alloys are widely used as heterogeneous catalysts. However, due to the existence of scaling properties of adsorption energies on transition metal surfaces, the enhancement of catalytic activity is frequently accompanied by side reactions leading to a reduction in selectivity for the target product. Herein, we describe an approach to breaking the scaling relationship for propane dehydrogenation, an industrially important reaction, by assembling single atom alloys (SAAs), to achieve simultaneous enhancement of propylene selectivity and propane conversion. We synthesize gamma-alumina-supported platinum/copper SAA catalysts by incipient wetness co-impregnation method with a high copper to platinum ratio. Single platinum atoms dispersed on copper nulloparticles dramatically enhance the desorption of surface-bounded propylene and prohibit its further dehydrogenation, resulting in high propylene selectivity (-90%). Unlike previous reported SAA applications at low temperatures (<400 degrees C), Pt/Cu SAA shows excellent stability of more than 120 h of operation under atmospheric pressure at 520 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 569, "Times Cited, All Databases": 615, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4454, "DOI": "10.1038/s41467-018-06967-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06967-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448414100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muravev, V; Spezzati, G; Su, YQ; Parastaev, A; Chiang, FK; Longo, A; Escudero, C; Kosinov, N; Hensen, EJM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muravev, Valery; Spezzati, Giulia; Su, Ya-Qiong; Parastaev, Alexander; Chiang, Fu-Kuo; Longo, Alessandro; Escudero, Carlos; Kosinov, Nikolay; Hensen, Emiel J. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface dynamics of Pd-CeO2 single-atom catalysts during CO oxidation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, noble metals atomically dispersed on solid oxide supports have become a frontier of heterogeneous catalysis. In pursuit of an ultimate atom efficiency, the stability of single-atom catalysts is pivotal. Here we compare two Pd/CeO2 single-atom catalysts that are active in low-temperature CO oxidation and display drastically different structural dynamics under the reaction conditions. These catalysts were obtained by conventional impregnation on hydrothermally synthesized CeO2 and one-step flame spray pyrolysis. The oxidized Pd atoms in the impregnated catalyst were prone to reduction and sintering during CO oxidation, whereas they remained intact on the surface of the Pd-doped CeO2 derived by flame spray pyrolysis. A detailed in situ characterization linked the stability of the Pd single atoms to the reducibility of the Pd-CeO2 interface and the extent of reverse oxygen spillover. To understand the chemical phenomena that underlie the metal-support interactions is crucial to the rational design of stable single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 469, "End Page": 478, "Article Number": null, "DOI": "10.1038/s41929-021-00621-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00621-1", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657606600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YF; Cheng, Y; Zhang, H; Zhou, M; Yu, YJ; Lin, SC; Jiang, B; Zhao, XZ; Miao, LY; Wei, CW; Liu, QY; Lin, YW; Du, Y; Butch, CJ; Wei, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yufeng; Cheng, Yuan; Zhang, He; Zhou, Min; Yu, Yijun; Lin, Shichao; Jiang, Bo; Zhao, Xiaozhi; Miao, Leiying; Wei, Chuan-Wan; Liu, Quanyi; Lin, Ying-Wu; Du, Yan; Butch, Christopher J.; Wei, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated cascade nullozyme catalyzes in vivo ROS scavenging for anti-inflammatory therapy", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, an integrated cascade nullozyme with a formulation of Pt@PCN222-Mn is developed to eliminate excessive reactive oxygen species (ROS). This nullozyme mimics superoxide dismutase by incorporation of a Mn-[5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato]-based metal-organic framework compound capable of transforming oxygen radicals to hydrogen peroxide. The second mimicked functionality is that of catalase by incorporation of Pt nulloparticles, which catalyze hydrogen peroxide disproportionation to water and oxygen. Both in vitro and in vivo experimental measurements reveal the synergistic ROS-scavenging capacity of such an integrated cascade nullozyme. Two forms of inflammatory bowel disease (IBD; i.e., ulcerative colitis and Crohn's disease) can be effectively relieved by treatment with the cascade nullozyme. This study not only provides a new method for constructing enzyme-like cascade systems but also illustrates their efficient therapeutic promise in the treatment of in vivo IBDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 6, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb2695", "DOI": "10.1126/sciadv.abb2695", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb2695", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552227800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, D; Guo, JW; Du, J; Xia, CX; Zeng, LH; Tian, YZ; Shi, ZF; Tian, YT; Li, XJ; Tsang, YH; Jie, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Di; Guo, Jiawen; Du, Juan; Xia, Congxin; Zeng, Longhui; Tian, Yongzhi; Shi, Zhifeng; Tian, Yongtao; Li, Xin Jian; Tsang, Yuen Hong; Jie, Jiansheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Polarization-Sensitive, Broadband, Self-Powered Photodetector Based on Graphene/PdSe2/Germanium Heterojunction", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polarization-sensitive photodetection in a broad spectrum range is highly desired due to the great significance in military and civilian applications. Palladium diselenide (PdSe2), a newly explored air-stable, group 10 two-dimensional (2D) noble metal dichalcogenide with a puckered pentagonal structure, holds promise for polarization-sensitive photodetection. Herein, we report a highly polarization-sensitive, broadband, self-powered photodetector based on graphene/PdSe2/germanium heterojunction. Owing to the enhanced light absorption of the mixed- dimensional van der Waals heterojunction and the effective carrier collection with graphene transparent electrode, the photodetector exhibits superior device performance in terms of a large photoresponsivity, a high specific detectivity, a fast response speed to follow nullosecond pulsed light signal, and a broadband photosensitivity ranging from deep ultraviolet (DUV) to mid-infrared (MIR). Significantly, highly polarization-sensitive broadband photodetection with an ultrahigh polarization sensitivity of 112.2 is achieved, which represents the best result for 2D layered material-based photodetectors. Further, we demonstrated the high-resolution polarization imaging based on the heterojunction device. This work reveals the great potential of 2D PdSe2 for high-performance, air-stable, and polarization-sensitive broadband photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 522, "Times Cited, All Databases": 539, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9907, "End Page": 9917, "Article Number": null, "DOI": "10.1021/acsnullo.9b03994", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b03994", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487859600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YW; Zhang, ZT; Wang, YX; Li, DL; Coen, CT; Hwaun, E; Chen, G; Wu, HC; Zhong, DL; Niu, SM; Wang, WC; Saberi, A; Lai, JC; Wu, YL; Wang, Y; Trotsyuk, AA; Loh, KY; Shih, CC; Xu, WH; Liang, K; Zhang, KL; Bai, YH; Gurusankar, G; Hu, WP; Jia, W; Cheng, Z; Dauskardt, RH; Gurtner, GC; Tok, JBH; Deisseroth, K; Soltesz, I; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuanwen; Zhang, Zhitao; Wang, Yi-Xuan; Li, Deling; Coen, Charles-Theophile; Hwaun, Ernie; Chen, Gan; Wu, Hung-Chin; Zhong, Donglai; Niu, Simiao; Wang, Weichen; Saberi, Aref; Lai, Jian-Cheng; Wu, Yilei; Wang, Yang; Trotsyuk, Artem A.; Loh, Kang Yong; Shih, Chien-Chung; Xu, Wenhui; Liang, Kui; Zhang, Kailiang; Bai, Yihong; Gurusankar, Gurupranav; Hu, Wenping; Jia, Wang; Cheng, Zhen; Dauskardt, Reinhold H.; Gurtner, Geoffrey C.; Tok, Jeffrey B-H; Deisseroth, Karl; Soltesz, Ivan; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological supramolecular network enabled high-conductivity, stretchable organic bioelectronics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsically stretchable bioelectronic devices based on soft and conducting organic materials have been regarded as the ideal interface for seamless and biocompatible integration with the human body. A remaining challenge is to combine high mechanical robustness with good electrical conduction, especially when patterned at small feature sizes. We develop a molecular engineering strategy based on a topological supramolecular network, which allows for the decoupling of competing effects from multiple molecular building blocks to meet complex requirements. We obtained simultaneously high conductivity and crack-onset strain in a physiological environment, with direct photopatternability down to the cellular scale. We further collected stable electromyography signals on soft and malleable octopus and performed localized neuromodulation down to single-nucleus precision for controlling organ-specific activities through the delicate brainstem.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2022, "Volume": 375, "Issue": 6587, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1411, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj7564", "DOI Link": "http://dx.doi.org/10.1126/science.abj7564", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778894800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, F; Zhou, HQ; Huang, YF; Sun, JY; Qin, F; Bao, JM; Goddardiii, WA; Chen, S; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fang; Zhou, Haiqing; Huang, Yufeng; Sun, Jingying; Qin, Fan; Bao, Jiming; Goddardiii, William A.; Chen, Shuo; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water electrolysis is an advanced energy conversion technology to produce hydrogen as a clean and sustainable chemical fuel, which potentially stores the abundant but intermittent renewable energy sources scalably. Since the overall water splitting is an uphill reaction in low efficiency, innovative breakthroughs are desirable to greatly improve the efficiency by rationally designing non-precious metal-based robust bifunctional catalysts for promoting both the cathodic hydrogen evolution and anodic oxygen evolution reactions. We report a hybrid catalyst constructed by iron and dinickel phosphides on nickel foams that drives both the hydrogen and oxygen evolution reactions well in base, and thus substantially expedites overall water splitting at 10 mA cm(-2) with 1.42 V, which outperforms the integrated iridium (IV) oxide and platinum couple (1.57 V), and are among the best activities currently. Especially, it delivers 500 mA cm(-2) at 1.72 V without decay even after the durability test for 40 h, providing great potential for large-scale applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1028, "Times Cited, All Databases": 1058, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2551, "DOI": "10.1038/s41467-018-04746-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04746-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436791400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naguib, M; Unocic, RR; Armstrong, BL; nullda, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naguib, Michael; Unocic, Raymond R.; Armstrong, Beth L.; nullda, Jagjit", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale delamination of multi-layers transition metal carbides and carbonitrides MXenes", "Source Title": "DALTON TRANSACTIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein we report on a general approach to delaminate multilayered MXenes using an organic base to induce swelling that in turn weakens the bonds between the MX layers. Simple agitation or mild sonication of the swollen MXene in water resulted in the large-scale delamination of the MXene layers. The delamination method is demonstrated for vanadium carbide and titanium carbonitride MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 712, "Times Cited, All Databases": 775, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 44, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9353, "End Page": 9358, "Article Number": null, "DOI": "10.1039/c5dt01247c", "DOI Link": "http://dx.doi.org/10.1039/c5dt01247c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354999800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, DH; Zhang, C; Zhou, GM; Lv, W; Ling, GW; Zhi, LJ; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Donghai; Zhang, Chen; Zhou, Guangmin; Lv, Wei; Ling, Guowei; Zhi, Linjie; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic Effects in Lithium-Sulfur Batteries: Promoted Sulfur Transformation and Reduced Shuttle Effect", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) battery has emerged as one of the most promising next-generation energy-storage systems. However, the shuttle effect greatly reduces the battery cycle life and sulfur utilization, which is great deterrent to its practical use. This paper reviews the tremendous efforts that are made to find a remedy for this problem, mostly through physical or chemical confinement of the lithium polysulfides (LiPSs). Intrinsically, this confinement has a relatively limited effect on improving the battery performance because in most cases, the LiPSs are passively blocked and cannot be reused. Thus, this strategy becomes less effective with a high sulfur loading and ultralong cycling. A more positive method that not only traps but also increases the subsequent conversion of LiPSs back to lithium sulfides is urgently needed to fundamentally solve the shuttle effect. Here, recent advances on catalytic effects in increasing the rate of conversion of soluble long-chain LiPSs to insoluble short-chain Li2S2/Li2S, and vice versa, are reviewed, and the roles of noble metals, metal oxides, metal sulfides, metal nitrides, and some metal-free materials in this process are highlighted. Challenges and potential solutions for the design of catalytic cathodes and interlayers in Li-S battery are discussed in detail.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 812, "Times Cited, All Databases": 846, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700270, "DOI": "10.1002/advs.201700270", "DOI Link": "http://dx.doi.org/10.1002/advs.201700270", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422658700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, KL; Wang, ZL; Han, CB; Ke, XX; Wang, CH; Jin, YH; Zhang, QQ; Liu, JB; Wang, H; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Kai Ling; Wang, Zelin; Han, Chang Bao; Ke, Xiaoxing; Wang, Changhao; Jin, Yuhong; Zhang, Qianqian; Liu, Jingbing; Wang, Hao; Yan, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts provide an effective approach to reduce the amount of precious metals meanwhile maintain their catalytic activity. However, the sluggish activity of the catalysts for alkaline water dissociation has hampered advances in highly efficient hydrogen production. Herein, we develop a single-atom platinum immobilized NiO/Ni heterostructure (Pt-SA-NiO/Ni) as an alkaline hydrogen evolution catalyst. It is found that Pt single atom coupled with NiO/Ni heterostructure enables the tunable binding abilities of hydroxyl ions (OH*) and hydrogen (H*), which efficiently tailors the water dissociation energy and promotes the H* conversion for accelerating alkaline hydrogen evolution reaction. A further enhancement is achieved by constructing Pt-SA-NiO/Ni nullosheets on Ag nullowires to form a hierarchical three-dimensional morphology. Consequently, the fabricated Pt-SA-NiO/Ni catalyst displays high alkaline hydrogen evolution performances with a quite high mass activity of 20.6Amg(-1) for Pt at the overpotential of 100mV, significantly outperforming the reported catalysts. While H-2 evolution from water may represent a renewable energy source, there is a strong need to improve catalytic efficiencies while maximizing materials utilization. Here, authors examine single-atom Pt on nickel-based heterostructures as highly active electrocatalysts for alkaline H-2 evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3783, "DOI": "10.1038/s41467-021-24079-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24079-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665040300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, B; Bai, ZY; Lv, HL; Yan, ZK; Du, YQ; Guo, XQ; Zhang, JC; Wu, LM; Deng, JS; Zhang, DW; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Biao; Bai, Zhongyi; Lv, Hualiang; Yan, Zhikai; Du, Yiqian; Guo, Xiaoqin; Zhang, Jincang; Wu, Limin; Deng, Jiushuai; Zhang, David Wei; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Healing Liquid Metal Magnetic Hydrogels for Smart Feedback Sensors and High-Performance Electromagnetic Shielding", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels exhibit potential applications in smart wearable devices because of their exceptional sensitivity to various external stimuli. However, their applications are limited by challenges in terms of issues in biocompatibility, custom shape, and self-healing. Herein, a conductive, stretchable, adaptable, self-healing, and biocompatible liquid metal GaInSn/Ni-based composite hydrogel is developed by incorporating a magnetic liquid metal into the hydrogel framework through crosslinking polyvinyl alcohol (PVA) with sodium tetraborate. The excellent stretchability and fast self-healing capability of the PVA/liquid metal hydrogel are derived from its abundant hydrogen binding sites and liquid metal fusion. Significantly, owing to the magnetic constituent, the PVA/liquid metal hydrogel can be guided remotely using an external magnetic field to a specific position to repair the broken wires with no need for manual operation. The composite hydrogel also exhibits sensitive deformation responses and can be used as a strain sensor to monitor various body motions. Additionally, the multifunctional hydrogel displays absorption-dominated electromagnetic interference (EMI) shielding properties. The total shielding performance of the composite hydrogel increases to similar to 62.5 dB from similar to 31.8 dB of the pure PVA hydrogel at the thickness of 3.0 mm. The proposed bioinspired multifunctional magnetic hydrogel demonstrates substantial application potential in the field of intelligent wearable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 79, "DOI": "10.1007/s40820-023-01043-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01043-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961824700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, H; Harley-Trochimczyk, A; Pham, T; Tang, ZR; Shi, TL; Zettl, A; Carraro, C; Worsley, MA; Maboudian, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Hu; Harley-Trochimczyk, Anna; Thang Pham; Tang, Zirong; Shi, Tielin; Zettl, Alex; Carraro, Carlo; Worsley, Marcus A.; Maboudian, Roya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Surface Area MoS2/Graphene Hybrid Aerogel for Ultrasensitive NO2 Detection", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A MoS2/graphene hybrid aerogel synthesized with two-dimensional MoS2 sheets coating a high surface area graphene aerogel scaffold is characterized and used for ultrasensitive NO2 detection. The combination of graphene and MoS2 leads to improved sensing properties with the graphene scaffold providing high specific surface area and high electrical and thermal conductivity and the single to few-layer MoS2 sheets providing high sensitivity and selectivity to NO2. The hybrid aerogel is integrated onto a low-power micro-heater platform to probe the gas sensing performance. At room temperature, the sensor exhibits an ultralow detection limit of 50 ppb NO2. By heating the material to 200 degrees C, the response and recovery times to reach 90% of the final signal decrease to <1 min, while retaining the low detection limit. The MoS2/graphene hybrid also shows good selectivity for NO2 against H-2 and CO, especially when compared to bare graphene aerogel. The unique structure of the hybrid aerogel is responsible for the ultrasensitive, selective, and fast NO2 sensing. The improved sensing performance of this hybrid aerogel also suggests the possibility of other 2D material combinations for further sensing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2016, "Volume": 26, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5158, "End Page": 5165, "Article Number": null, "DOI": "10.1002/adfm.201601562", "DOI Link": "http://dx.doi.org/10.1002/adfm.201601562", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380890200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, TM; Peng, R; Hood, ZD; Naguib, M; Ivanov, IN; Keum, JK; Qin, ZZ; Guo, ZH; Wu, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Tongming; Peng, Rui; Hood, Zachary D.; Naguib, Michael; Ivanov, Ilia N.; Keum, Jong Kahk; Qin, Zuzeng; Guo, Zhanhu; Wu, Zili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Step Synthesis of Nb2O5/C/Nb2C (MXene) Composites and Their Use as Photocatalysts for Hydrogen Evolution", "Source Title": "CHEMSUSCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen production through facile photocatalytic water splitting is regarded as a promising strategy to solve global energy problems. Transition-metal carbides (MXenes) have recently drawn attention as potential co-catalyst candidates for photocatalysts. Here, we report niobium pentoxide/carbon/niobium carbide (MXene) hybrid materials (Nb2O5/C/Nb2C) as photocatalysts for hydrogen evolution from water splitting. The Nb2O5/C/Nb2C composites were synthesized by one-step CO2 oxidation of Nb2CTx. Nb2O5 grew homogeneously on Nb2C after mild oxidation, during which some amorphous carbon was also formed. With an optimized oxidation time of 1.0 h, Nb2O5/C/Nb2C showed the highest hydrogen generation rate (7.81 mu mol h(-1) g(cat)(-1)), a value that was four times higher than that of pure Nb2O5. The enhanced performance of Nb2O5/C/Nb2C was attributed to intimate contact between Nb2O5 and conductive Nb2C and the separation of photogenerated charge carriers at the Nb2O5/Nb2C interface; the results presented herein show that transition-metal carbide are promising co-catalysts for photocatalytic hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2018, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 688, "End Page": 699, "Article Number": null, "DOI": "10.1002/cssc.201702317", "DOI Link": "http://dx.doi.org/10.1002/cssc.201702317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425730600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, Z; Bi, YM; Hu, EY; Liu, W; Dwarica, N; Tian, Y; Li, XL; Kuang, Y; Li, YP; Yang, XQ; Wang, HL; Sun, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Zhao; Bi, Yongmin; Hu, Enyuan; Liu, Wen; Dwarica, Nico; Tian, Yang; Li, Xiaolin; Kuang, Yun; Li, Yaping; Yang, Xiao-Qing; Wang, Hailiang; Sun, Xiaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Crystalline Ultrathin Co3O4 nullosheets with Massive Vacancy Defects for Enhanced Electrocatalysis", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The role of vacancy defects is demonstrated to be positive in various energy-related processes. However, introducing vacancy defects into single-crystalline nullostructures with given facets and studying their defect effect on electrocatalytic properties remains a great challenge. Here this study deliberately introduces oxygen defects into single-crystalline ultrathin Co3O4 nullosheets with O-terminated {111} facets by mild solvothermal reduction using ethylene glycol under alkaline condition. As-prepared defect-rich Co3O4 nullosheets show a low overpotential of 220 mV with a small Tafel slope of 49.1 mV dec(-1) for the oxygen evolution reaction (OER), which is among the best Co-based OER catalysts to date and even more active than the state-of-the-art IrO2 catalyst. Such vacancy defects are formed by balancing with reducing environments under solvothermal conditions, but are surprisingly stable even after 1000 cycles of scanning under OER working conditions. Density functional theory plus U calculation attributes the enhanced performance to the oxygen vacancies and consequently exposed second-layered Co metal sites, which leads to the lowered OER activation energy of 2.26 eV and improved electrical conductivity. This mild solvothermal reduction concept opens a new door for the understanding and future designing of advanced defect-based electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2018, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701694, "DOI": "10.1002/aenm.201701694", "DOI Link": "http://dx.doi.org/10.1002/aenm.201701694", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423342400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, K; Xing, RR; Zou, QL; Ma, GH; Möhwald, H; Yan, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kai; Xing, Ruirui; Zou, Qianli; Ma, Guanghui; Mohwald, Helmuth; Yan, Xuehai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simple Peptide-Tuned Self-Assembly of Photosensitizers towards Anticancer Photodynamic Therapy", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peptide-tuned self-assembly of functional components offers a strategy towards improved properties and unique functions of materials, but the requirement of many different functions and a lack of understanding of complex structures present a high barrier for applications. Herein, we report a photosensitive drug delivery system for photodynamic therapy (PDT) by a simple dipeptide- or amphiphilic amino-acid-tuned self-assembly of photosensitizers (PSs). The assembled nullodrugs exhibit multiple favorable therapeutic features, including tunable size, high loading efficiency, and on-demand drug release responding to pH, surfactant, and enzyme stimuli, as well as preferable cellular uptake and biodistribution. These features result in greatly enhanced PDT efficacy invitro and invivo, leading to almost complete tumor eradication in mice receiving a single drug dose and a single exposure to light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 477, "Times Cited, All Databases": 490, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2016, "Volume": 55, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3036, "End Page": 3039, "Article Number": null, "DOI": "10.1002/anie.201509810", "DOI Link": "http://dx.doi.org/10.1002/anie.201509810", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370656200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Wang, RY; Feng, BW; Zhong, XX; Ostrikov, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qing; Wang, Ruoyu; Feng, Bowen; Zhong, Xiaoxia; Ostrikov, Kostya (Ken)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoluminescence mechanism of carbon dots: triggering high-color-purity red fluorescence emission through edge amino protonation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to complex structure and surface functionalities, photoluminescence mechanisms of Carbon Dots are unknown, and it is challenging to synthesize Carbon Dots to achieve the desired optical properties. Herein, Carbon Dots simultaneously exhibiting high-color-purity (FWHM-24 nm) long wavelength one-photon fluorescence emission at 620 nm and NIR induced two-photon fluorescence emission at 630 and 680 nm are prepared by edge amino protonation treatment. Systematic analysis reveals that the protonation of 2,3-diaminophenazine changes the molecular state of Carbon Dots, decreases the photon transition band gap, and triggers red fluorescence emission with the dramatically narrowed peak width. As the oxidation products of reactant o-phenylendiamine, the emergence of 2,3-diaminophenazine as a photoluminescence determiner suggests that fluorophore products of precursor conversion are viable determinullts of the desired luminescence properties of Carbon Dots. This work shows a new way for predicting and controlling photoluminescence properties of Carbon Dots, and may guide the development of tunable Carbon Dots for a broad range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6856, "DOI": "10.1038/s41467-021-27071-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27071-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722866700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Komaba, S; Hasegawa, T; Dahbi, M; Kubota, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Komaba, Shinichi; Hasegawa, Tatsuya; Dahbi, Mouad; Kubota, Kei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potassium intercalation into graphite to realize high-voltage/high-power potassium-ion batteries and potassium-ion capacitors", "Source Title": "ELECTROCHEMISTRY COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly reversible potassium intercalation into graphite in carbonate ester solution at room temperature is achieved by electrochemical reduction at the potential approaching to K+/K standard potential which is lower than that of Li+/Li. The intercalation results in formation of stage-1 KC8 compound with delivering 244 mAh g(-1) of reversible capacity. The initial irreversible capacity is suppressed by polycarboxylate binder compared to poly(vinyledene fluoride) binder. The lower potential, good cyclability, and excellent rate capability are first demonstrated for energy storage applications. Because of the lowest potential and weakest solvation among Li+, Na+, K+, Mg2+, and Ca2+ ion carriers, potassium shuttlecock mechanism between two insertion materials as potassium-ion battery is advantageous for higher-voltage/-power rechargeable batteries. The excellent rate performance is beneficial for the application to hybrid-type capacitor, potassium-ion capacitor, as an alternative to lithium-ion capacitors. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 923, "Times Cited, All Databases": 974, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 60, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 172, "End Page": 175, "Article Number": null, "DOI": "10.1016/j.elecom.2015.09.002", "DOI Link": "http://dx.doi.org/10.1016/j.elecom.2015.09.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364797700040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nyein, HYY; Tai, LC; Ngo, QP; Chao, MH; Zhang, GB; Gao, W; Bariya, M; Bullock, J; Kim, H; Fahad, HM; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nyein, Hnin Yin Yin; Tai, Li-Chia; Quynh Phuong Ngo; Chao, Minghan; Zhang, George B.; Gao, Wei; Bariya, Mallika; Bullock, James; Kim, Hyungjin; Fahad, Hossain M.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Wearable Microfluidic Sensing Patch for Dynamic Sweat Secretion Analysis", "Source Title": "ACS SENSORS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sweat sensing is a rapidly rising research area driven by its promising potential in health, fitness, and diagnostic applications. Despite the growth in the field, major challenges in relation to sweat metrics remain to be addressed. These challenges include sweat rate monitoring for its complex relation with sweat compositions and sweat sampling for sweat dynamics studies. In this work, we present a flexible microfluidic sweat sensing patch that enhances real-time electrochemical sensing and sweat rate analysis via sweat sampling. The device contains a spiral-patterned microfluidic component that is embedded with ion-selective sensors and an electrical impedance-based sweat rate sensor on a flexible plastic substrate. The patch is enabled to autonomously perform sweat analysis by interfacing the sensing component with a printed circuit board that is capable of on-site signal conditioning, analysis, and transmission. Progressive sweat flow in the microfluidic device, governed by the pressure induced by the secreted sweat, enhances sweat sampling and electrochemical detection via a defined sweat collection chamber and a directed sweat route. The characteristic of the sweat rate sensor is validated through a theoretical simulation, and the precision and accuracy of the flow rate is verified with a commercial syringe pump and a Macroduct sweat collector. On-body simultaneous monitoring of ion (H+, Na+, K+, Cl-) concentration and sweat rate is also demonstrated for sensor functionality. This sweat sensing patch provides an integrated platform for a comprehensive sweat secretion analysis and facilitates physiological and clinical investigations by closely monitoring interrelated sweat parameters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 944, "End Page": 952, "Article Number": null, "DOI": "10.1021/acssensors.7b00961", "DOI Link": "http://dx.doi.org/10.1021/acssensors.7b00961", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433635300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, YJ; Ota, H; Schaler, EW; Chen, K; Zhao, A; Gao, W; Fahad, HM; Leng, YG; Zheng, AZ; Xiong, FR; Zhang, CC; Tai, LC; Zhao, PD; Fearing, RS; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yuji; Ota, Hiroki; Schaler, Ethan W.; Chen, Kevin; Zhao, Allan; Gao, Wei; Fahad, Hossain M.; Leng, Yonggang; Zheng, Anzong; Xiong, Furui; Zhang, Chuchu; Tai, Li-Chia; Zhao, Peida; Fearing, Ronald S.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable Microfluidic Diaphragm Pressure Sensor for Health and Tactile Touch Monitoring", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible pressure sensors have many potential applications in wearable electronics, robotics, health monitoring, and more. In particular, liquid-metal-based sensors are especially promising as they can undergo strains of over 200% without failure. However, current liquid-metal-based strain sensors are incapable of resolving small pressure changes in the few kPa range, making them unsuitable for applications such as heart-rate monitoring, which require a much lower pressure detection resolution. In this paper, a microfluidic tactile diaphragm pressure sensor based on embedded Galinstan microchannels (70 mu m width x 70 mu m height) capable of resolving sub-50 Pa changes in pressure with sub-100 Pa detection limits and a response time of 90 ms is demonstrated. An embedded equivalent Wheatstone bridge circuit makes the most of tangential and radial strain fields, leading to high sensitivities of a 0.0835 kPa(-1) change in output voltage. The Wheatstone bridge also provides temperature self-compensation, allowing for operation in the range of 20-50 degrees C. As examples of potential applications, a polydimethylsiloxane (PDMS) wristband with an embedded microfluidic diaphragm pressure sensor capable of real-time pulse monitoring and a PDMS glove with multiple embedded sensors to provide comprehensive tactile feedback of a human hand when touching or holding objects are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2017, "Volume": 29, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701985, "DOI": "10.1002/adma.201701985", "DOI Link": "http://dx.doi.org/10.1002/adma.201701985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412925600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JH; Zhu, CZ; Xu, BZ; Fu, SF; Engelhard, MH; Ye, RF; Du, D; Beckman, SP; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Junhua; Zhu, Chengzhou; Xu, Bo Z.; Fu, Shaofang; Engelhard, Mark H.; Ye, Ranfeng; Du, Dan; Beckman, Scott P.; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimetallic Cobalt-Based Phosphide Zeolitic Imidazolate Framework: CoPx Phase-Dependent Electrical Conductivity and Hydrogen Atom Adsorption Energy for Efficient Overall Water Splitting", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt-based bimetallic phosphide encapsulated in carbonized zeolitic imadazolate frameworks has been successfully synthesized and showed excellent activities toward both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Density functional theory calculation and electrochemical measurements reveal that the electrical conductivity and electrochemical activity are closely associated with the Co2P/CoP mixed phase behaviors upon Cu metal doping. This relationship is found to be the decisive factor for enhanced electrocatalytic performance. Moreover, the precise control of Cu content in Co-host lattice effectively alters the Gibbs free energy for H* adsorption, which is favorable for facilitating reaction kinetics. Impressively, an optimized performance has been achieved with mild Cu doping in Cu0.3Co2.7P/nitrogen-doped carbon (NC) which exhibits an ultralow overpotential of 0.19 V at 10 mA cm(-2) and satisfying stability for OER. Cu0.3Co2.7P/NC also shows excellent HER activity, affording a current density of 10 mA cm(-2) at a low overpotential of 0.22 V. In addition, a homemade electrolyzer with Cu0.3Co2.7P/NC paired electrodes shows 60% larger current density than Pt/RuO2 couple at 1.74 V, along with negligible catalytic deactivation after 50 h operation. The manipulation of electronic structure by controlled incorporation of second metal sheds light on understanding and synthesizing bimetallic transition metal phosphides for electrolysis-based energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1601555, "DOI": "10.1002/aenm.201601555", "DOI Link": "http://dx.doi.org/10.1002/aenm.201601555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393580900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Siakavelas, GI; Charisiou, ND; AlKhoori, S; AlKhoori, AA; Sebastian, V; Hinder, SJ; Baker, MA; Yentekakis, IV; Polychronopoulou, K; Goula, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Siakavelas, G., I; Charisiou, N. D.; AlKhoori, S.; AlKhoori, A. A.; Sebastian, V; Hinder, S. J.; Baker, M. A.; Yentekakis, I., V; Polychronopoulou, K.; Goula, M. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective and stable nickel catalysts supported on ceria promoted with Sm2O3, Pr2O3 and MgO for the CO2 methanation reaction", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present work reports on the investigation of the catalytic performance for the methanation of CO2 over Ni catalysts based on CeO2, and for the first time, of Ni catalysts supported on binary CeO2-based oxides, namely, Sm2O3-CeO2, Pr2O3-CeO2 and MgO-CeO2. The supports were obtained using the microwave assisted sol-gel method under reflux, while the catalysts were prepared by the wet impregnation method. For the investigation of the morphological, textural, structural and other intrinsic properties of the catalytic materials a variety of characterization techniques were used, i.e., Raman spectroscopy, XRD, N-2 physisorption-desorption, CO2-TPD, H-2-TPR, H-2-TPD, XPS and TEM. Carbon deposition and sintering were investigated using TEM. It was shown that the addition of Sm3+ or Pr3+, incorporated into the lattice of CeO2, generated oxygen vacancies, but the Ni/Pr-Ce catalyst was found to possess more surface oxygen vacancies (e.g. Ce4+-Ov-Pr3+ entities). Moreover, modification of CeO2 using Sm3+ or Pr3+ restricted the agglomeration of nickel active sites and led to the genesis of Lewis basic positions. These characteristics improved the hydrogenation reaction at lower temperature. On the other hand, the addition of Mg2+ resulted at strong metal support interactions reinforcing the resistance of the Ni/Mg-Ce catalyst against sintering. Furthermore, the addition of Sm3+, Pr3+ and Mg2+ cations increased the overall basicity and the moderate adsorption sites and led to the formation of smaller Ni nullo particles; these physico-chemical properties enhanced the CO2 methanation reaction. Finally, the activity experiments (WGHSV = 25,000 mL g(-1) h(-1), H-2/CO2 = 4:1, T =350 degrees C) showed that at lower reaction temperature the Ni/Pr-Ce had the highest catalytic performance in terms of CO2 conversion (54.5%) and CH4 yield (54.5%) and selectivity (100%). The TOF values were found to follow the order Ni/Pr-Ce > > Ni/Mg-Ce > Ni/Sm-Ce > Ni/Ce.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 282, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119562, "DOI": "10.1016/j.apcatb.2020.119562", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119562", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591695500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, N; Fang, ZZ; Zou, WK; Zhao, Q; Xie, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Ning; Fang, Zizheng; Zou, Weike; Zhao, Qian; Xie, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoset Shape-Memory Polyurethane with Intrinsic Plasticity Enabled by Transcarbamoylation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoset polymers are known for their superior thermomechanical properties, but the chemical crosslinking typically leads to intractability. This is reflected in the great differences between thermoset and thermoplastic shape-memory polymers; the former exhibit a robust shape memory but are not capable of redefining the permanent shape. Contrary to current knowledge, we reveal here that a classical thermoset shape-memory polyurethane is readily capable of permanent reshaping (plasticity) after a topological network rearrangement that is induced by transcarbamoylation. By employing the Jianzhi technique (also known as kirigami), unexpected shape-shifting versatility was observed for this otherwise classical material. As the essential carbamate moiety in polyurethanes is one of the most common polymer building units, we anticipate that our finding will have significant benefits beyond shape shifting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 533, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2016, "Volume": 55, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11421, "End Page": 11425, "Article Number": null, "DOI": "10.1002/anie.201602847", "DOI Link": "http://dx.doi.org/10.1002/anie.201602847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383748900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, H; Bodnarchuk, MI; Kershaw, SV; Kovalenko, MV; Rogach, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, He; Bodnarchuk, Maryna I.; Kershaw, Stephen V.; Kovalenko, Maksym V.; Rogach, Andrey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead Halide Perovskite nullocrystals in the Research Spotlight: Stability and Defect Tolerance", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This Perspective outlines basic structural and optical properties of lead halide perovskite colloidal nullocrystals, highlighting differences and similarities between them and conventional II-VI and III-V semiconductor quantum dots. A detailed insight into two important issues inherent to lead halide perovskite nullocrystals then follows, namely, the advantages of defect tolerance and the necessity to improve their stability in environmental conditions. The defect tolerance of lead halide perovskites offers an impetus to search for similar attributes in other related heavy metal-free compounds. We discuss the origins of the significantly blue-shifted emission from CsPbBr3 nullocrystals and the synthetic strategies toward fabrication of stable perovskite nullocrystal materials with emission in the red and infrared parts of the optical spectrum, which are related to fabrication of mixed cation compounds guided by Goldschmidt tolerance factor considerations. We conclude with the view on perspectives of use of the colloidal perovskite nullocrystals for applications in backlighting of liquid-crystal TV displays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 987, "Times Cited, All Databases": 1070, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2071, "End Page": 2083, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00547", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00547", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410600500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Mathis, TS; Li, K; Lin, Z; Vlcek, L; Torita, T; Osti, NC; Hatter, C; Urbankowski, P; Sarycheva, A; Tyagi, M; Mamontov, E; Simon, P; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xuehang; Mathis, Tyler S.; Li, Ke; Lin, Zifeng; Vlcek, Lukas; Torita, Takeshi; Osti, Naresh C.; Hatter, Christine; Urbankowski, Patrick; Sarycheva, Asia; Tyagi, Madhusudan; Mamontov, Eugene; Simon, Patrice; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influences from solvents on charge storage in titanium carbide MXenes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pseudocapacitive energy storage in supercapacitor electrodes differs significantly from the electrical double-layer mechanism of porous carbon materials, which requires a change from conventional thinking when choosing appropriate electrolytes. Here we show how simply changing the solvent of an electrolyte system can drastically influence the pseudocapacitive charge storage of the two-dimensional titanium carbide, Ti3C2 (a representative member of the MXene family). Measurements of the charge stored by Ti3C2 in lithium-containing electrolytes with nitrile-, carbonate- and sulfoxide-based solvents show that the use of a carbonate solvent doubles the charge stored by Ti3C2 when compared with the other solvent systems. We find that the chemical nature of the electrolyte solvent has a profound effect on the arrangement of molecules/ions in Ti3C2, which correlates directly to the total charge being stored. Having nearly completely desolvated lithium ions in Ti3C2 for the carbonate-based electrolyte leads to high volumetric capacitance at high charge-discharge rates, demonstrating the importance of considering all aspects of an electrochemical system during development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 438, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 241, "End Page": 248, "Article Number": null, "DOI": "10.1038/s41560-019-0339-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0339-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461124600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, LL; Song, AY; Li, W; Hsu, PC; Lin, DC; Catrysse, PB; Liu, YY; Peng, YC; Chen, J; Wang, HX; Xu, JW; Yang, AK; Fan, SH; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Lili; Song, Alex Y.; Li, Wei; Hsu, Po-Chun; Lin, Dingchang; Catrysse, Peter B.; Liu, Yayuan; Peng, Yucan; Chen, Jun; Wang, Hongxia; Xu, Jinwei; Yang, Ankun; Fan, Shanhui; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spectrally Selective nullocomposite Textile for Outdoor Personal Cooling", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Outdoor heat stress poses a serious public health threat and curtails industrial labor supply and productivity, thus adversely impacting the wellness and economy of the entire society. With climate change, there will be more intense and frequent heat waves that further present a grand challenge for sustainability. However, an efficient and economical method that can provide localized outdoor cooling of the human body without intensive energy input is lacking. Here, a novel spectrally selective nullocomposite textile for radiative outdoor cooling using zinc oxide nulloparticle-embedded polyethylene is demonstrated. By reflecting more than 90% solar irradiance and selectively transmitting out human body thermal radiation, this textile can enable simulated skin to avoid overheating by 5-13 degrees C compared to normal textile like cotton under peak daylight condition. Owing to its superior passive cooling capability and compatibility with large-scale production, this radiative outdoor cooling textile is promising to widely benefit the sustainability of society in many aspects spanning from health to economy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 481, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2018, "Volume": 30, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802152, "DOI": "10.1002/adma.201802152", "DOI Link": "http://dx.doi.org/10.1002/adma.201802152", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442732400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sick, T; Hufnagel, AG; Kampmann, J; Kondofersky, I; Calik, M; Rotter, JM; Evans, A; Döblinger, M; Herbert, S; Peters, K; Böhm, D; Knochel, P; Medina, DD; Fattakhova-Rohlfing, D; Bein, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sick, Torben; Hufnagel, Alexander G.; Kampmann, Jonathan; Kondofersky, Ilina; Calik, Mona; Rotter, Julian M.; Evans, Austin; Doeblinger, Markus; Herbert, Simon; Peters, Kristina; Boehm, Daniel; Knochel, Paul; Medina, Dana D.; Fattakhova-Rohlfing, Dina; Bein, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oriented Films of Conjugated 2D Covalent Organic Frameworks as Photocathodes for Water Splitting", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-driven water electrolysis at a semiconductor surface is a promising way to generate hydrogen from sustainable energy sources, but its efficiency is limited by the performance of available photoabsorbers. Here we report the first time investigation of covalent organic frameworks (COFs) as a new class of photoelectrodes. The presented 2D-COF structure is assembled from aromatic amine-functionalized tetraphenylethylene and thiophene-based dialdehyde building blocks to form conjugated polyimine sheets, which pi-stack in the third dimension to create photoactive porous frameworks. Highly oriented COF films absorb light in the visible range to generate photoexcited electrons that diffuse to the surface and are transferred to the electrolyte, resulting in proton reduction and hydrogen evolution. The observed photoelectrochemical activity of the 2D-COF films and their photocorrosion stability in water pave the way for a novel class of photoabsorber materials with versatile optical and electronic properties that are tunable through the selection of appropriate building blocks and their three-dimensional stacking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2018, "Volume": 140, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2085, "End Page": 2092, "Article Number": null, "DOI": "10.1021/jacs.7b06081", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06081", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425475300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, HF; Lin, S; Goetze, J; Pletcher, P; Guo, H; Kovarik, L; Artyushkova, K; Weckhuysen, BM; Datye, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Haifeng; Lin, Sen; Goetze, Joris; Pletcher, Paul; Guo, Hua; Kovarik, Libor; Artyushkova, Kateryna; Weckhuysen, Bert M.; Datye, Abhaya K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally Stable and Regenerable Platinum-Tin Clusters for Propane Dehydrogenation Prepared by Atom Trapping on Ceria", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ceria (CeO2) supports are unique in their ability to trap ionic platinum (Pt), providing exceptional stability for isolated single atoms of Pt. The reactivity and stability of single-atom Pt species was explored for the industrially important light alkane dehydrogenation reaction. The single-atom Pt/CeO2 catalysts are stable during propane dehydrogenation, but are not selective for propylene. DFT calculations show strong adsorption of the olefin produced, leading to further unwanted reactions. In contrast, when tin (Sn) is added to CeO2, the single-atom Pt catalyst undergoes an activation phase where it transforms into Pt-Sn clusters under reaction conditions. Formation of small Pt-Sn clusters allows the catalyst to achieve high selectivity towards propylene because of facile desorption of the product. The CeO2-supported Pt-Sn clusters are very stable, even during extended reaction at 680 degrees C. Coke formation is almost completely suppressed by adding water vapor to the feed. Furthermore, upon oxidation the Pt-Sn clusters readily revert to the atomically dispersed species on CeO2, making Pt-Sn/CeO2 a fully regenerable catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2017, "Volume": 56, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8986, "End Page": 8991, "Article Number": null, "DOI": "10.1002/anie.201701115", "DOI Link": "http://dx.doi.org/10.1002/anie.201701115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424260200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HZ; Li, Q; Tao, CN; Hong, Y; Xu, ZQ; Shen, WD; Kaur, S; Ghosh, P; Qiu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Huanzheng; Li, Qiang; Tao, Chenning; Hong, Yu; Xu, Ziquan; Shen, Weidong; Kaur, Sandeep; Ghosh, Pintu; Qiu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multispectral camouflage for infrared, visible, lasers and microwave with radiative cooling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interminable surveillance and reconnaissance through various sophisticated multispectral detectors present threats to military equipment and manpower. However, a combination of detectors operating in different wavelength bands (from hundreds of nullometers to centimeters) and based on different principles raises challenges to the conventional single-band camouflage devices. In this paper, multispectral camouflage is demonstrated for the visible, mid-infrared (MIR, 3-5 and 8-14 mu m), lasers (1.55 and 10.6 mu m) and microwave (8-12GHz) bands with simultaneous efficient radiative cooling in the non-atmospheric window (5-8 mu m). The device for multispectral camouflage consists of a ZnS/Ge multilayer for wavelength selective emission and a Cu-ITO-Cu metasurface for microwave absorption. In comparison with conventional broadband low emittance material (Cr), the IR camouflage performance of this device manifests 8.4/5.9 degrees C reduction of inner/surface temperature, and 53.4/13.0% IR signal decrease in mid/long wavelength IR bands, at 2500W.m(-2) input power density. Furthermore, we reveal that the natural convection in the atmosphere can be enhanced by radiation in the non-atmospheric window, which increases the total cooling power from 136W.m(-2) to 252W.m(-2) at 150 degrees C surface temperature. This work may introduce the opportunities for multispectral manipulation, infrared signal processing, thermal management, and energy-efficient applications. Manipulating electromagnetic waves to camouflage objects is an important tool. Here, the authors present a camouflage that covers a wide range of frequencies based on multilayer and metasurface technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805, "DOI": "10.1038/s41467-021-22051-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22051-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634785200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, W; Han, XG; Hu, H; Chang, MQ; Ding, L; Xiang, HJ; Chen, Y; Li, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Wei; Han, Xiuguo; Hu, Hui; Chang, Meiqi; Ding, Li; Xiang, Huijing; Chen, Yu; Li, Yuehua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D vanadium carbide MXenzyme to alleviate ROS-mediated inflammatory and neurodegenerative diseases", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reactive oxygen species (ROS) are generated and consumed in living organism for normal metabolism. Paradoxically, the overproduction and/or mismanagement of ROS have been involved in pathogenesis and progression of various human diseases. Here, we reported a two-dimensional (2D) vanadium carbide (V2C) MXene nulloenzyme (MXenzyme) that can mimic up to six naturally-occurring enzymes, including superoxide dismutase (SOD), catalase (CAT), peroxidase (POD), glutathione peroxidase (GPx), thiol peroxidase (TPx) and haloperoxidase (HPO). Based on these enzyme-mimicking properties, the constructed 2D V2C MXenzyme not only possesses high biocompatibility but also exhibits robust in vitro cytoprotection against oxidative stress. Importantly, 2D V2C MXenzyme rebuilds the redox homeostasis without perturbing the endogenous antioxidant status and relieves ROS-induced damage with benign in vivo therapeutic effects, as demonstrated in both inflammation and neurodegeneration animal models. These findings open an avenue to enable the use of MXenzyme as a remedial nulloplatform to treat ROS-mediated inflammatory and neurodegenerative diseases. Materials with enzymatic-like activities are of interest for a wide range of applications. Here, the authors report on 2D vanadium carbide MXene nullozymes capable of mimicking multiple enzymes and demonstrate application to treat reactive oxygen species-mediated inflammatory and neurodegenerative diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203, "DOI": "10.1038/s41467-021-22278-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22278-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640638000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, L; Yan, LW; Wang, KF; Fang, LM; Zhang, HP; Tang, YH; Ding, YH; Weng, LT; Xu, JL; Weng, J; Liu, YJ; Ren, FZ; Lu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Lu; Yan, Liwei; Wang, Kefeng; Fang, Liming; Zhang, Hongping; Tang, Youhong; Ding, Yonghui; Weng, Lu-Tao; Xu, Jielong; Weng, Jie; Liu, Yujie; Ren, Fuzeng; Lu, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough, self-healable and tissue-adhesive hydrogel with tunable multifunctionality", "Source Title": "NPG ASIA MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An ideal hydrogel for biomedical engineering should mimic the intrinsic properties of natural tissue, especially high toughness and self-healing ability, in order to withstand cyclic loading and repair skin and muscle damage. In addition, excellent cell affinity and tissue adhesiveness enable integration with the surrounding tissue after implantation. Inspired by the natural mussel adhesive mechanism, we designed a polydopamine-polyacrylamide (PDA-PAM) single network hydrogel by preventing the overoxidation of dopamine to maintain enough free catechol groups in the hydrogel. Therefore, the hydrogel possesses super stretchability, high toughness, stimuli-free self-healing ability, cell affinity and tissue adhesiveness. More remarkably, the current hydrogel can repeatedly be adhered on/stripped from a variety of surfaces for many cycles without loss of adhesion strength. Furthermore, the hydrogel can serve as an excellent platform to host various nullo-building blocks, in which multiple functionalities are integrated to achieve versatile potential applications, such as magnetic and electrical therapies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2017, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e372", "DOI": "10.1038/am.2017.33", "DOI Link": "http://dx.doi.org/10.1038/am.2017.33", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399409500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, LB; Ji, RB; Li, XM; Bai, GX; Liu, CP; Hao, JH; Lin, JY; Jiang, HX; Teng, KS; Yang, ZB; Lau, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Libin; Ji, Rongbin; Li, Xueming; Bai, Gongxun; Liu, Chao Ping; Hao, Jianhua; Lin, Jingyu; Jiang, Hongxing; Teng, Kar Seng; Yang, Zhibin; Lau, Shu Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Ultraviolet to Near-Infrared Emission and Photoresponse in Layered N-Doped Graphene Quantum Dots", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Material that can emit broad spectral wavelengths covering deep ultraviolet, visible, and near-infrared is highly desirable. It can lead to important applications such as broadband modulators, photodetectors, solar cells, bioimaging, and fiber communications. However, there is currently no material that meets such desirable requirement. Here, we report the layered structure of nitrogen-doped graphene quantum dots (N-GQDs) which possess broadband emission ranging from 300 to >1000 nm. The broadband emission is attributed to the layered structure of the N-GQDs that contains a large conjugated system and provides extensive delocalized pi electrons. In addition, a broadband photodetector with responsivity as high as 325 V/W is demonstrated by coating N-GQDs onto interdigital gold electrodes. The unusual negative photocurrent is observed which is attributed to the trapping sites induced by the self-passivated surface states in the N-GQDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 459, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6312, "End Page": 6320, "Article Number": null, "DOI": "10.1021/nn501796r", "DOI Link": "http://dx.doi.org/10.1021/nn501796r", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338089200099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nellaiappan, S; Katiyar, NK; Kumar, R; Parui, A; Malviya, KD; Pradeep, KG; Singh, AK; Sharma, S; Tiwary, CS; Biswas, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nellaiappan, Subramanian; Katiyar, Nirmal Kumar; Kumar, Ritesh; Parui, Arko; Malviya, Kirtiman Deo; Pradeep, K. G.; Singh, Abhishek K.; Sharma, Sudhanshu; Tiwary, Chandra Sekhar; Biswas, Krishanu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Alloys as Catalysts for the CO2 and CO Reduction Reactions: Experimental Realization", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conversion of carbon dioxide into selective hydrocarbon using a stable catalyst remains a holy grail in the catalysis community. The high overpotential, stability, and selectivity in the use of a single-metal-based catalyst still remain a challenge. In current work, instead of using pure noble metals (Ag, Au, and Pt) as the catalyst, a nullocrystalline high-entropy alloy (HEA: AuAgPtPdCu) has been used for the conversion of CO2 into gaseous hydrocarbons. Utilizing an approach of multimetallic HEA, a faradic efficiency of about 100% toward gaseous products is obtained at a low applied potential (-0.3 V vs reversible hydrogen electrode). The reason behind the catalytic activity and selectivity of the high-entropy alloy (HEA) toward CO2 electroreduction was established through first-principles-based density functional theory (DFT) by comparing it with the pristine Cu(111) surface. This is attributed to the reversal in adsorption trends for two out of the total eight intermediates-*OCH3 and *O on Cu(111) and HEA surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3658, "End Page": 3663, "Article Number": null, "DOI": "10.1021/acscatal.9b04302", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b04302", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526394500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CL; Xu, Y; Zhou, M; Liang, LY; Dong, HS; Wu, MH; Yang, Y; Lei, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chenglin; Xu, Yang; Zhou, Min; Liang, Liying; Dong, Huishuang; Wu, Minghong; Yang, Yi; Lei, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potassium Prussian Blue nulloparticles: A Low-Cost Cathode Material for Potassium-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (KIBs) in organic electrolytes hold great promise as an electrochemical energy storage technology owing to the abundance of potassium, close redox potential to lithium, and similar electrochemistry with lithium system. Although carbon materials have been studied as KIB anodes, investigations on KIB cathodes have been scarcely reported. A comprehensive study on potassium Prussian blue K0.220Fe[Fe(CN)(6)](0.805)4.01H(2)O nulloparticles as a potential cathode material is for the first time reported. The cathode exhibits a high discharge voltage of 3.1-3.4 V, a high reversible capacity of 73.2 mAh g(-1), and great cyclability at both low and high rates with a very small capacity decay rate of approximate to 0.09% per cycle. Electrochemical reaction mechanism analysis identifies the carbon-coordinated Fe-III/Fe-II couple as redox-active site and proves structural stability of the cathode during charge/discharge. Furthermore, for the first time, a KIB full-cell is presented by coupling the nulloparticles with commercial carbon materials. The full-cell delivers a capacity of 68.5 mAh g(-1) at 100 mA g(-1) and retains 93.4% of the capacity after 50 cycles. Considering the low cost and material sustainability as well as the great electrochemical performances, this work may pave the way toward more studies on KIB cathodes and trigger future attention on rechargeable KIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 495, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 27, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604307, "DOI": "10.1002/adfm.201604307", "DOI Link": "http://dx.doi.org/10.1002/adfm.201604307", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394671200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, DL; Zhu, CR; Yang, PH; Xia, XH; Liu, JL; Wang, J; Fan, XF; Savilov, SV; Lin, JY; Fan, HJ; Shen, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Dongliang; Zhu, Changrong; Yang, Peihua; Xia, Xinhui; Liu, Jilei; Wang, Jin; Fan, Xiaofeng; Savilov, Serguei V.; Lin, Jianyi; Fan, Hong Jin; Shen, Ze Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Array of nullosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nullostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis. The graphene foam supported tin(II) sulfide nulloarray anode delivers a high reversible capacity of similar to 1,100 mAhg(-1) at 30 mA g (-1) and similar to 420 mAh g(-1) at 30 A g(-1), which even outperforms its lithium-ion storage performance. The surface-dominated redox reaction rendered by our tailored ultrathin tin(II) sulfide nullostructures may also work in other layered materials for high-performance sodium-ion storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1196, "Times Cited, All Databases": 1215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12122, "DOI": "10.1038/ncomms12122", "DOI Link": "http://dx.doi.org/10.1038/ncomms12122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379114900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, YQ; Xu, HR; Li, ZL; Zhangji, AD; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Yuqing; Xu, Huiru; Li, Zhenlong; Zhangji, Aodi; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired Injectable Self-Healing Hydrogel Sealant with Fault-Tolerant and Repeated Thermo-Responsive Adhesion for Sutureless Post-Wound-Closure and Wound Healing", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels with multifunctionalities, including sufficient bonding strength, injectability and self-healing capacity, responsive-adhesive ability, fault-tolerant and repeated tissue adhesion, are urgently demanded for invasive wound closure and wound healing. Motivated by the adhesive mechanism of mussel and brown algae, bioinspired dynamic bonds cross-linked multifunctional hydrogel adhesive is designed based on sodium alginate (SA), gelatin (GT) and protocatechualdehyde, with ferric ions added, for sutureless post-wound-closure. The dynamic hydrogel cross-linked through Schiff base bond, catechol-Fe coordinate bond and the strong interaction between GT with temperature-dependent phase transition and SA, endows the resulting hydrogel with sufficient mechanical and adhesive strength for efficient wound closure, injectability and self-healing capacity, and repeated closure of reopened wounds. Moreover, the temperature-dependent adhesive properties endowed mispositioning hydrogel to be removed/repositioned, which is conducive for the fault-tolerant adhesion of the hydrogel adhesives during surgery. Besides, the hydrogels present good biocompatibility, near-infrared-assisted photothermal antibacterial activity, antioxidation and repeated thermo-responsive reversible adhesion and good hemostatic effect. The in vivo incision closure evaluation demonstrated their capability to promote the post-wound-closure and wound healing of the incisions, indicating that the developed reversible adhesive hydrogel dressing could serve as versatile tissue sealant.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 185, "DOI": "10.1007/s40820-022-00928-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00928-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853340700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hurley, RR; Lusher, AL; Olsen, M; Nizzetto, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hurley, Rachel R.; Lusher, Amy L.; Olsen, Marianne; Nizzetto, Luca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Validation of a Method for Extracting Microplastics from Complex, Organic-Rich, Environmental Matrices", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Complex and organic-rich solid substrates such as sludge and soil have been shown to be contaminated by microplastics; however, methods for extracting plastic particles have not yet been systemically tested or standardized. This study investigated four main protocols for the removal of organic material during analysis of microplastics from complex solid matrices: oxidation using H2O2, Fenton's reagent, and alkaline digestion with NaOH and KOH. Eight common polymer types were used to assess the influence of reagent exposure on particle integrity. Organic matter removal efficiencies were established for test sludge and soil samples. Fenton's reagent was identified as the optimum protocol. All other methods showed signs of particle degradation or resulted in an insufficient reduction in organic matter content. A further validation procedure revealed high microplastic extraction efficiencies for particles with different morphologies. This confirmed the suitability of Fenton's reagent for use in conjunction with density separation for extracting microplastics. This approach affords greater comparability with existing studies that utilize a density-based technique. Recommendations for further method optimization were also identified to improve the recovery of microplastic from complex, organic-rich environmental samples.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 590, "Times Cited, All Databases": 663, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2018, "Volume": 52, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7409, "End Page": 7417, "Article Number": null, "DOI": "10.1021/acs.est.8b01517", "DOI Link": "http://dx.doi.org/10.1021/acs.est.8b01517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438007600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jayaramulu, K; Dubal, DP; Nagar, B; Ranc, V; Tomanec, O; Petr, M; Datta, KKR; Zboril, R; Gómez-Romero, P; Fischer, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jayaramulu, Kolleboyina; Dubal, Deepak P.; Nagar, Bhawna; Ranc, Vaclav; Tomanec, Ondrej; Petr, Martin; Datta, Kasibhatta Kumara Ramanatha; Zboril, Radek; Gomez-Romero, Pedro; Fischer, Roland A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Hierarchical Porous Carbon nullosheets for High-Performance Supercapacitors and Redox Electrolyte Energy Storage", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of advanced high-energy-density supercapacitors requires the design of unique materials that combine hierarchical nulloporous structures with high surface area to facilitate ion transport and excellent electrolyte permeability. Here, shape-controlled 2D nulloporous carbon sheets (NPSs) with graphitic wall structure through the pyrolysis of metal-organic frameworks (MOFs) are developed. As a proof-of-concept application, the obtained NPSs are used as the electrode material for a supercapacitor. The carbon-sheet-based symmetric cell shows an ultrahigh Brunauer-Emmett-Teller (BET)-area-normalized capacitance of 21.4 mu F cm(-2) (233 F g(-1)), exceeding other carbon-based supercapacitors. The addition of potassium iodide as redox-active species in a sulfuric acid (supporting electrolyte) leads to the ground-breaking enhancement in the energy density up to 90 Wh kg(-1), which is higher than commercial aqueous rechargeable batteries, maintaining its superior power density. Thus, the new material provides a double profits strategy such as battery-level energy and capacitor-level power density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2018, "Volume": 30, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705789, "DOI": "10.1002/adma.201705789", "DOI Link": "http://dx.doi.org/10.1002/adma.201705789", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430101200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, ZW; Lv, XL; He, SH; Bai, SM; Liu, XC; Hou, LX; He, JJ; Tong, DM; Ruan, RJ; Zhang, J; Ding, JX; Yang, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Ziwen; Lv, Xueli; He, Shaohua; Bai, Shumeng; Liu, Xiaochen; Hou, Linxi; He, Jingjing; Tong, Dongmei; Ruan, Renjie; Zhang, Jin; Ding, Jianxun; Yang, Huanghao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mussel-inspired supramolecular hydrogel with robust tissue anchor for rapid hemostasis of arterial and visceral bleedings", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the developed hemostatic technologies are still difficult to be applied to the hemostasis of massive arterial and visceral hemorrhage, owing to their weak hemostatic function, inferior wet tissue adhesion, and low mechanical properties. Herein, a mussel-inspired supramolecular interaction-cross-linked hydrogel with robust mechanical property (308.47 +/- 29.20 kPa) and excellent hemostatic efficiency (96.5% +/- 2.1%) was constructed as a hemostatic sealant. Typically, we combined chitosan (CS) with silk fibmin (SF) by cross-linking them through tannic acid (TA) to maintain the structural stability of the hydrogel, especially for wet tissue adhesion ability (shear adhesive strength = 29.66 +/- 0.36 kPa). Compared with other materials reported previously, the obtained CS/TA/SF hydrogel yielded a lower amount of blood loss and shorter time to hemostasis in various arterial and visceral bleeding models, which could be ascribed to the synergistic effect of wound closure under wet state as well as intrinsic hemostatic activity of CS. As a superior hemostatic sealant, the unique hydrogel proposed in this work can be exploited to offer significant advantages in the acute wound and massive hemorrhage with the restrictive access of therapeutic moieties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2829, "End Page": 2840, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.01.039", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.01.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662249100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; Verdaguer-Casadevall, A; Arnarson, L; Silvio, L; Colic, V; Frydendal, R; Rossmeisl, J; Chorkendorff, I; Stephens, IEL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Sungeun; Verdaguer-Casadevall, Arnau; Arnarson, Logi; Silvio, Luca; Colic, Viktor; Frydendal, Rasmus; Rossmeisl, Jan; Chorkendorff, Ib; Stephens, Ifan E. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward the Decentralized Electrochemical Production of H2O2: A Focus on the Catalysis", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "H2O2 is a valuable, environmentally friendly oxidizing agent with a wide range of uses from the provision of clean water to the synthesis of valuable chemicals. The on-site electrolytic production of H2O2 would bring the chemical to applications beyond its present reach. The successful commercialization of electrochemical H2O2 (p)roduction requires cathode catalysts with high activity, selectivity, and stability. In this Perspective, we highlight our current understanding of the factors that control the cathode performance. We review the influence of catalyst material, electrolyte, and the structure of the interface at the mesoscopic scale. We provide original theoretical data on the role of the geometry of the active site and its influence on activity and selectivity. We have also conducted a series of original experiments on (i) the effect of pH on H2O2 production on glassy carbon, pure metals, and metal-mercury alloys, and (ii) the influence of cell geometry and mass transport in liquid half-cells in comparison to membrane electrode assemblies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 848, "Times Cited, All Databases": 906, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4064, "End Page": 4081, "Article Number": null, "DOI": "10.1021/acscatal.8b00217", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b00217", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431727300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Huang, WW; Luo, ZQ; Liu, LJ; Lu, Y; Li, YX; Li, L; Hu, JY; Ma, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qing; Huang, Weiwei; Luo, Zhiqiang; Liu, Luojia; Lu, Yong; Li, Yixin; Li, Lin; Hu, Jinyan; Ma, Hua; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-capacity aqueous zinc batteries using sustainable quinone electrodes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quinones, which are ubiquitous in nature, can act as sustainable and green electrode materials but face dissolution in organic electrolytes, resulting in fast fading of capacity and short cycle life. We report that quinone electrodes, especially calix[4] quinone (C4Q) in rechargeable metal zinc batteries coupled with a cation-selective membrane using an aqueous electrolyte, exhibit a high capacity of 335mA h g(-1) with an energy efficiency of 93% at 20 mA g(-1) and a long life of 1000 cycles with a capacity retention of 87% at 500 mA g(-1). The pouch zinc batteries with a respective depth of discharge of 89% (C4Q) and 49% (zinc anode) can deliver an energy density of 220 Wh kg(-1) by mass of both a C4Q cathode and a theoretical Zn anode. We also develop an electrostatic potential computing method to demonstrate that carbonyl groups are active centers of electrochemistry. Moreover, the structural evolution and dissolution behavior of activematerials during discharge and charge processes are investigated by operando spectral techniques such as IR, Raman, and ultraviolet-visible spectroscopies. Our results show that batteries using quinone cathodes and metal anodes in aqueous electrolyte are reliable approaches for mass energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao1761", "DOI": "10.1126/sciadv.aao1761", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao1761", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427892700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, AD; Xie, YS; Zhu, SJ; Guo, ZQ; Zhu, SQ; Guo, J; Shi, P; James, TD; Tian, H; Zhu, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Andong; Xie, Yongshu; Zhu, Shaojia; Guo, Zhiqian; Zhu, Shiqin; Guo, Jin; Shi, Ping; James, Tony D.; Tian, He; Zhu, Wei-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Far-Red and Near-IR AIE-Active Fluorescent Organic nulloprobes with Enhanced Tumor-Targeting Efficacy: Shape-Specific Effects", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of high-performance fluorescent materials for cancer targeting in vivo is still challenging. A unique molecular design strategy is presented that involves tailoring aggregation-induced emission (AIE)-active organic molecules to realize preferable far-red and NIR fluorescence, well-controlled morphology (from rod-like to spherical), and also tumor-targeted bioimaging. The shape-tailored organic quinoline-malononitrile (QM) nulloprobes are biocompatible and highly desirable for cell-tracking applications. Impressively, the spherical shape of QM-5 nulloaggregates exhibits excellent tumor-targeted bioimaging performance after intravenously injection into mice, but not the rod-like aggregates of QM-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2015, "Volume": 54, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7275, "End Page": 7280, "Article Number": null, "DOI": "10.1002/anie.201501478", "DOI Link": "http://dx.doi.org/10.1002/anie.201501478", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356390300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, ZL; Cao, T; O'Brien, K; Zhu, HY; Yin, XB; Wang, Y; Louie, SG; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Ziliang; Cao, Ting; O'Brien, Kevin; Zhu, Hanyu; Yin, Xiaobo; Wang, Yuan; Louie, Steven G.; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing excitonic dark states in single-layer tungsten disulphide", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dichalcogenide (TMDC) monolayers have recently emerged as an important class of two-dimensional semiconductors with potential for electronic and optoelectronic devices(1,2). Unlike semi-metallic graphene, layered TMDCs have a sizeable bandgap(3). More interestingly, when thinned down to a monolayer, TMDCs transform from indirect-bandgap to direct-bandgap semiconductors(4,5), exhibiting a number of intriguing optical phenomena such as valley-selective circular dichroism(6-8), doping-dependent charged excitons(9,10) and strong photocurrent responses(11). However, the fundamental mechanism underlying such a strong light-matter interaction is still under intensive investigation. First-principles calculations have predicted a quasi-particle bandgap much larger than the measured optical gap, and an optical response dominated by excitonic effects(12-14). In particular, a recent study based on a GW plus Bethe-Salpeter equation (GW-BSE) approach, which employed many-body Green's-function methodology to address electron-electron and electron-hole interactions, theoretically predicted a diversity of strongly bound exdtons(14). Here we report experimental evidence of a series of excitonic dark states in single-layer WS2 using two-photon excitation spectroscopy. In combination with GW-BSE theory, we prove that the excitons are of Wannier type, meaning that each exciton wavefunction extends over multiple unit cells, but with extraordinarily large binding energy (similar to 0.7 electron-volts), leading to a quasiparticle bandgap of 2.7 electronvolts. These strongly bound exciton states are observed to be stable even at room temperature. We reveal an exciton series that deviates substantially from hydrogen models, with a novel energy dependence on the orbital angular momentum. These excitonic energy levels are experimentally found to be robust against environmental perturbations. The discovery of excitonic dark states and exceptionally large binding energy not only sheds light on the importance of many-electron effects in this two-dimensional gapped system, but also holds potential for the device application of TMDC monolayers and their heterostructures(15) in computing, communication and bio-sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 865, "Times Cited, All Databases": 979, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2014, "Volume": 513, "Issue": 7517, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": 218, "Article Number": null, "DOI": "10.1038/nature13734", "DOI Link": "http://dx.doi.org/10.1038/nature13734", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341362800046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, GF; Ma, TY; Liu, ZQ; Li, N; Su, YZ; Davey, K; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Gao-Feng; Ma, Tian Yi; Liu, Zhao-Qing; Li, null; Su, Yu-Zhi; Davey, Kenneth; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and Stable Bifunctional Electrocatalysts Ni/NixMy (M = P, S) for Overall Water Splitting", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of easy-to-make, highly active, and stable bifunctional electrocatalysts for water splitting is important for future renewable energy systems. Three-dimension (3D) porous Ni/Ni8P3 and Ni/Ni9S8 electrodes are prepared by sequential treatment of commercial Ni-foam with acid activation, followed by phosphorization or sulfurization. The resultant materials can act as self-supported bifunctional electrocatalytic electrodes for direct water splitting with excellent activity toward oxygen evolution reaction and hydrogen evolution reaction in alkaline media. Stable performance can be maintained for at least 24 h, illustrating their versatile and practical nature for clean energy generation. Furthermore, an advanced water electrolyzer through exploiting Ni/Ni8P3 as both anode and cathode is fabricated, which requires a cell voltage of 1.61 V to deliver a 10 mA cm(-2) water splitting current density in 1.0 M KOH solution. This performance is significantly better than that of the noble metal benchmark-integrated Ni/IrO2 and Ni/Pt-C electrodes. Therefore, these bifunctional electrodes have significant potential for realistic large-scale production of hydrogen as a replacement clean fuel to polluting and limited fossil-fuels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 851, "Times Cited, All Databases": 873, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2016, "Volume": 26, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3314, "End Page": 3323, "Article Number": null, "DOI": "10.1002/adfm.201505626", "DOI Link": "http://dx.doi.org/10.1002/adfm.201505626", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377593000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mosadegh, B; Polygerinos, P; Keplinger, C; Wennstedt, S; Shepherd, RF; Gupta, U; Shim, J; Bertoldi, K; Walsh, CJ; Whitesides, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mosadegh, Bobak; Polygerinos, Panagiotis; Keplinger, Christoph; Wennstedt, Sophia; Shepherd, Robert F.; Gupta, Unmukt; Shim, Jongmin; Bertoldi, Katia; Walsh, Conor J.; Whitesides, George M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pneumatic Networks for Soft Robotics that Actuate Rapidly", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft robots actuated by inflation of a pneumatic network (a pneu-net) of small channels in elastomeric materials are appealing for producing sophisticated motions with simple controls. Although current designs of pneu-nets achieve motion with large amplitudes, they do so relatively slowly (over seconds). This paper describes a new design for pneu-nets that reduces the amount of gas needed for inflation of the pneu-net, and thus increases its speed of actuation. A simple actuator can bend from a linear to a quasi-circular shape in 50 ms when pressurized at P = 345 kPa. At high rates of pressurization, the path along which the actuator bends depends on this rate. When inflated fully, the chambers of this new design experience only one-tenth the change in volume of that required for the previous design. This small change in volume requires comparably low levels of strain in the material at maximum amplitudes of actuation, and commensurately low rates of fatigue and failure. This actuator can operate over a million cycles without significant degradation of performance. This design for soft robotic actuators combines high rates of actuation with high reliability of the actuator, and opens new areas of application for them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1201, "Times Cited, All Databases": 1398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 24, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2163, "End Page": 2170, "Article Number": null, "DOI": "10.1002/adfm.201303288", "DOI Link": "http://dx.doi.org/10.1002/adfm.201303288", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334281400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Phang, WJ; Jo, H; Lee, WR; Song, JH; Yoo, K; Kim, B; Hong, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Phang, Won Ju; Jo, Hyuna; Lee, Woo Ram; Song, Jeong Hwa; Yoo, Kicheon; Kim, BongSoo; Hong, Chang Seop", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superprotonic Conductivity of a UiO-66 Framework Functionalized with Sulfonic Acid Groups by Facile Postsynthetic Oxidation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Facile postsynthetic oxidation of the thiol-laced UiO-66-type framework UiO-66(SH)(2) enabled the generation of UiO-66(SO3H)(2) with sulfonic acid groups covalently linked to the backbone of the system. The oxidized material exhibited a superprotonic conductivity of 8.4 x 10(-2) S cm(-1) at 80 degrees C and 90% relative humidity, and long-term stability of the conductivity was observed. This level of conductivity exceeds that of any proton-conducting MOF reported to date and is equivalent to the conductivity of the most effective known electrolyte, Nafion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 465, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2015, "Volume": 54, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5142, "End Page": 5146, "Article Number": null, "DOI": "10.1002/anie.201411703", "DOI Link": "http://dx.doi.org/10.1002/anie.201411703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354190800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Z; Rudnicki, PE; Zhang, ZW; Huang, ZJ; Celik, H; Oyakhire, ST; Chen, YL; Kong, X; Kim, SC; Xiao, X; Wang, HS; Zheng, Y; Kamat, GA; Kim, MS; Bent, SF; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhiao; Rudnicki, Paul E.; Zhang, Zewen; Huang, Zhuojun; Celik, Hasan; Oyakhire, Solomon T.; Chen, Yuelang; Kong, Xian; Kim, Sang Cheol; Xiao, Xin; Wang, Hansen; Zheng, Yu; Kamat, Gaurav A.; Kim, Mun Sek; Bent, Stacey F.; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational solvent molecule tuning for high-performance lithium metal battery electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering improved cycling of Li metal batteries and anode-free cells at low current densities; however, high-rate capability and tuning of ionic conduction in electrolytes are desirable yet less-studied. Here, we design and synthesize a family of fluorinated-1,2-diethoxyethanes as electrolyte solvents. The position and amount of F atoms functionalized on 1,2-diethoxyethane were found to greatly affect electrolyte performance. Partially fluorinated, locally polar -CHF2 is identified as the optimal group rather than fully fluorinated -CF3 in common designs. Paired with 1.2 M lithium bis(fluorosulfonyl)imide, these developed single-salt-single-solvent electrolytes simultaneously enable high conductivity, low and stable overpotential, >99.5% Li||Cu half-cell efficiency (up to 99.9%, +/- 0.1% fluctuation) and fast activation (Li efficiency >99.3% within two cycles). Combined with high-voltage stability, these electrolytes achieve roughly 270 cycles in 50-mu m-thin Li||high-loading-NMC811 full batteries and >140 cycles in fast-cycling Cu||microparticle-LiFePO4 industrial pouch cells under realistic testing conditions. The correlation of Li+-solvent coordination, solvation environments and battery performance is investigated to understand structure-property relationships. Cycling capability, especially at high rates, is limited for lithium metal batteries. Here the authors report electrolyte solvent design through fine-tuning of molecular structures to address the cyclability issue and unravel the electrolyte structure-property relationship for battery applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 106, "Article Number": null, "DOI": "10.1038/s41560-021-00962-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00962-y", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742253900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rui, N; Zhang, XS; Zhang, F; Liu, ZY; Cao, XX; Xie, ZH; Zou, R; Senullayake, SD; Yang, YH; Rodriguez, JA; Liu, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rui, Ning; Zhang, Xiaoshan; Zhang, Feng; Liu, Zongyuan; Cao, Xinxiang; Xie, Zhenhua; Zou, Rui; Senullayake, Sanjaya D.; Yang, Yanhui; Rodriguez, Jose A.; Liu, Chang-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active Ni/CeO2 catalyst for CO2 methanation: Preparation and characterization", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Ni/CeO2 catalyst was prepared via decomposition of nickel precursor by gas discharge plasma, followed by hydrogen reduction thermally. The activity of the obtained catalyst reaches the highest level towards CO2 methanation with methane selectivity above 99 % at reaction temperatures lower than 300 degrees C. For example, the CH4 formation rate at 275 degrees C is 100.3 mu mol gcat(-1) s(-1), higher than the reported catalysts at the same reaction temperature. Characterization results indicate that the plasma decomposition leads to an interfacial structure where Ni atoms bind with O atoms from ceria. A strong metal-support interaction is caused. Rich interfacial Ni-CeO2 sites are thus formed with excellent redox property. The unique interfacial structure confines small nickel particles on the ceria surface, exposing more metallic Ni as active sites for splitting H-2. Therefore, the plasma prepared Ni/CeO2 catalyst shows balanced active sites for H-2 splitting and CO2 activation, improving low temperature catalytic activity significantly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 282, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119581, "DOI": "10.1016/j.apcatb.2020.119581", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119581", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591692300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schuh, B; Mendez-Martin, F; Völker, B; George, EP; Clemens, H; Pippan, R; Hohenwarter, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuh, B.; Mendez-Martin, F.; Voelker, B.; George, E. P.; Clemens, H.; Pippan, R.; Hohenwarter, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties, microstructure and thermal stability of a nullocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An equiatomic CoCrFeMnNi high-entropy alloy (HEA), produced by arc melting and drop casting, was subjected to severe plastic deformation (SPD) using high-pressure torsion. This process induced substantial grain refinement in the coarse-grained casting leading to a grain size of approximately 50 nm. As a result, strength increased significantly to 1950 MPa, and hardness to similar to 520 MV. Analyses using transmission electron microscopy (TEM) and 3-dimensional atom probe tomography (3D-APT) showed that, after SPD, the alloy remained a true single-phase solid solution down to the atomic scale. Subsequent investigations characterized the evolution of mechanical properties and microstructure of this nullocrystalline HEA upon annealing. Isochronal (for 1 h) and isothermal heat treatments were performed followed by microhardness and tensile tests. The isochronal anneals led to a marked hardness increase with a maximum hardness of similar to 630 HV at about 450 degrees C before softening set in at higher temperatures. The isothermal anneals, performed at this peak hardness temperature, revealed an additional hardness rise to a maximum of about 910 MV after 100 h. To clarify this unexpected annealing response, comprehensive microstructural analyses were performed using TEM and 3D-APT. New nullo-scale phases were observed to form in the originally single-phase HEA. After times as short as 5 min at 450 degrees C, a NiMn phase and Cr-rich phase formed. With increasing annealing time, their volume fractions increased and a third phase, FeCo, also formed. It appears that the surfeit of grain boundaries in the nullocrystalline HEA offer many fast diffusion pathways and nucleation sites to facilitate this phase decomposition. The hardness increase, especially for the longer annealing times, can be attributed to these nullo-scaled phases embedded in the HEA matrix. The present results give new valuable insights into the phase stability of single-phase high-entropy alloys as well as the mechanisms controlling the mechanical properties of nullostructured multiphase composites. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1065, "Times Cited, All Databases": 1124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2015, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 258, "End Page": 268, "Article Number": null, "DOI": "10.1016/j.actamat.2015.06.025", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.06.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358459900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tu, C; Wei, J; Guan, F; Liu, Y; Sun, YH; Luo, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tu, Chen; Wei, Jing; Guan, Feng; Liu, Ying; Sun, Yuhuan; Luo, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biochar and bacteria inoculated biochar enhanced Cd and Cu immobilization and enzymatic activity in a polluted soil", "Source Title": "ENVIRONMENT INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of biochar in the remediation of heavy metal contaminated soil has received increasing global attention during the past decade. Although there has been some review work on the mechanism of heavy metals stabilization by biochar, the effects and mechanisms of interaction between biochar and functional microbes such as heavy metal tolerant, adsorption and transformation microbial strains remains unclear. In this paper, maize biochar and a heavy metal-tolerant strain Pseudomonas sp. NT-2 were selected to investigate the dynamic effects and potential mechanisms of biochar and bacteria loaded biochar on the stabilization of Cd and Cu mixed contaminated soil by a 75-day pot experiment. The results showed that, compared to the single biochar amendment, the application of biochar inoculated with NT-2 strain at the rate of 5% significantly increased the soil pH at the initial stage of incubation, and followed by a slight decline to a neutral-alkaline range during the reaction. The addition of NT-2 loaded biochar could also significantly increase the proportion of residual fraction of Cd and Cu, thus reduce the proportion of exchangeable and carbonate bound species in the soil, which lead to the decreasing of plant and human bioavailability of the metal in the soil indicated by DTPA and simulated human gastric solution extraction (UBM), respectively. Finally, the application of bacterial loaded biochar also markedly enhanced soil urease and catalase activities during the later stage of the incubation, and improved soil microbial community at the end of incubation, which indicates a recovery of soil function after the metal stabilization. The research results may provide some new insights into the development of functional materials and technologies for the green and sustainable remediation of heavy metal contaminated soil by the combination of biochar and functional microorganisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105576, "DOI": "10.1016/j.envint.2020.105576", "DOI Link": "http://dx.doi.org/10.1016/j.envint.2020.105576", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517970800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, P; Zhang, C; Duan, XG; Sun, HQ; Liu, SM; Tade, MO; Wang, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Ping; Zhang, Chi; Duan, Xiaoguang; Sun, Hongqi; Liu, Shaomin; Tade, Moses O.; Wang, Shaobin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An insight into metal organic framework derived N-doped graphene for the oxidative degradation of persistent contaminullts: formation mechanism and generation of singlet oxygen from peroxymonosulfate", "Source Title": "ENVIRONMENTAL SCIENCE-nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of carbonaceous materials from a metal organic framework (MIL-100), organic linker and N-precursor was comprehensively investigated, and the structures of the products were characterized. It was found that simple pyrolysis of mixed MIL-100 (Fe)/dicyandiamide (DCDA) could produce nitrogen-doped graphene (N-graphene). The N-graphene showed excellent performances in peroxymonosulfate (PMS) activation, which were superior to those of counterparts of graphene, iron(II, III) oxide, manganese(IV) oxide and cobalt(II, III) oxide. With PMS activation, N-graphene exhibited efficient catalytic degradation of various organic pollutants such as phenol, 2,4,6-trichlorophenol (TCP), sulfachloropyridazine (SCP) and p-hydroxybenzoic acid (PHBA). Electron paramagnetic resonullce (EPR) spectroscopy and radical quenching tests were employed to investigate the PMS activation and organic degradation processes. It was found that singlet oxygen ((1)O2) was mainly produced during the activation of PMS by N-graphene, and contributed to the catalytic oxidation instead of sulfate and/or hydroxyl radicals. These findings provide new insights into PMS activation by metal-free carbon catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 493, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 315, "End Page": 324, "Article Number": null, "DOI": "10.1039/c6en00633g", "DOI Link": "http://dx.doi.org/10.1039/c6en00633g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Environmental Sciences & Ecology; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395876000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, FL; Yuan, T; Sui, LZ; Wang, ZB; Xi, ZF; Li, YC; Li, XH; Fan, LZ; Tan, ZA; Chen, AM; Jin, MX; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Fanglong; Yuan, Ting; Sui, Laizhi; Wang, Zhibin; Xi, Zifan; Li, Yunchao; Li, Xiaohong; Fan, Louzhen; Tan, Zhan'ao; Chen, Anmin; Jin, Mingxing; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering triangular carbon quantum dots with unprecedented narrow bandwidth emission for multicolored LEDs", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon quantum dots (CQDs) have emerged as promising materials for optoelectronic applications on account of carbon's intrinsic merits of high stability, low cost, and environment-friendliness. However, the CQDs usually give broad emission with full width at half maximum exceeding 80 nm, which fundamentally limit their display applications. Here we demonstrate multicolored narrow bandwidth emission (full width at half maximum of 30 nm) from triangular CQDs with a quantum yield up to 54-72%. Detailed structural and optical characterizations together with theoretical calculations reveal that the molecular purity and crystalline perfection of the triangular CQDs are key to the high color-purity. Moreover, multicolored light-emitting diodes based on these CQDs display good stability, high color-purity, and high-performance with maximum luminullce of 1882-4762 cd m(-2) and current efficiency of 1.22-5.11 cd A(-1). This work will set the stage for developing nextgeneration high-performance CQDs-based light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 825, "Times Cited, All Databases": 862, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2249, "DOI": "10.1038/s41467-018-04635-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04635-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434648400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, DQ; Tress, W; Dar, MI; Gao, P; Luo, JS; Renevier, C; Schenk, K; Abate, A; Giordano, F; Baena, JPC; Decoppet, JD; Zakeeruddin, SM; Nazeeruddin, MK; Grätzel, M; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Dongqin; Tress, Wolfgang; Dar, M. Ibrahim; Gao, Peng; Luo, Jingshan; Renevier, Clementine; Schenk, Kurt; Abate, Antonio; Giordano, Fabrizio; Baena, Juan-Pablo Correa; Decoppet, Jean-David; Zakeeruddin, Shaik Mohammed; Nazeeruddin, Mohammad Khaja; Gratzel, Michael; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient luminescent solar cells based on tailored mixed-cation perovskites", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on a new metal halide perovskite photovoltaic cell that exhibits both very high solar-to-electric power-conversion efficiency and intense electroluminescence. We produce the perovskite films in a single step from a solution containing a mixture of FAI, PbI2, MABr, and PbBr2 (where FA stands for formamidinium cations andMA stands for methylammonium cations). Using mesoporous TiO2 and Spiro-OMeTAD as electron-and hole-specific contacts, respectively, we fabricate perovskite solar cells that achieve a maximum power-conversion efficiency of 20.8% for a PbI2/FAImolar ratio of 1.05 in the precursor solution. Rietveld analysis of x-ray diffraction data reveals that the excess PbI2 content incorporated into such a film is about 3 wt %. Time-resolved photoluminescence decay measurements show that the small excess of PbI2 suppresses nonradiative charge carrier recombination. This in turn augments the external electroluminescence quantum efficiency to values of about 0.5%, a record for perovskite photovoltaics approaching that of the best silicon solar cells. Correspondingly, the open-circuit photovoltage reaches 1.18 V under AM 1.5 sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1672, "Times Cited, All Databases": 1748, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501170", "DOI": "10.1126/sciadv.1501170", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501170", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376972900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Su, R; Liu, XF; Xing, J; Sum, TC; Xiong, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qing; Su, Rui; Liu, Xinfeng; Xing, Jun; Sum, Tze Chien; Xiong, Qihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Quality Whispering-Gallery-Mode Lasing from Cesium Lead Halide Perovskite nulloplatelets", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor micro/nullo-cavities with high quality factor (Q) and small modal volume provide critical platforms for exploring strong light-matter interactions and quantum optics, enabling further development of coherent and quantum photonic devices. Constrained by exciton binding energy and thermal fluctuation, only a handful of wide-band semiconductors such as ZnO and GaN have stable excitons at room temperature. Metal halide perovskite with cubic lattice and well-controlled exciton may provide solutions. In this work, high-quality single-crystalline cesium lead halide CsPbX3 (X = Cl, Br, I) whispering-gallery-mode (WGM) microcavities are synthesized by vapor-phase van der Waals epitaxy method. The as-grown perovskites show strong emission and stable exciton at room temperature over the whole visible spectra range. By varying the halide composition, multi-color (400-700 nm). WGM excitonic lasing is achieved at room temperature with low threshold (similar to 2.0 mu J cm(-2)) and high spectra coherence (similar to 0.14-0.15 nm). The results advocate the promise of inorganic perovskites towards development of opto-electronic devices and strong light-matter coupling in quantum optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 568, "Times Cited, All Databases": 599, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2016, "Volume": 26, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6238, "End Page": 6245, "Article Number": null, "DOI": "10.1002/adfm.201601690", "DOI Link": "http://dx.doi.org/10.1002/adfm.201601690", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383609300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, HC; Choi, C; Ding, LX; Jiang, Z; Hang, ZS; Jia, MW; Fan, Q; Gao, YN; Wang, HH; Robertson, AW; Hong, S; Jung, YS; Liu, SZ; Sun, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Hengcong; Choi, Changhyeok; Ding, Liang-Xin; Jiang, Zheng; Hang, Zishan; Jia, Mingwen; Fan, Qun; Gao, Yunnull; Wang, Haihui; Robertson, Alex W.; Hong, Song; Jung, Yousung; Liu, Shizhen; Sun, Zhenyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen fixation under ambient conditions remains a significant challenge. Here, we report nitrogen fixation by Ru single-atom electrocatalytic reduction at room temperature and pressure. In contrast to Ru nulloparticles, single Ru sites supported on N-doped porous carbon greatly promoted electroreduction of aqueous N-2 selectively to NH3, affording an NH3 formation rate of 3.665 mg(NH3) h(-1) mg(Ru)(-1) at -0.21 V versus the reversible hydrogen electrode. Importantly, the addition of ZrO2 was found to significantly suppress the competitive hydrogen evolution reaction. An NH3 faradic efficiency of about 21% was achieved at a low overpotential (0.17 V), surpassing many other reported catalysts. Experiments combined with density functional theory calculations showed that the Ru sites with oxygen vacancies were major active centers that permitted stabilization of *NNH, destabilization of *H, and enhanced N-2 adsorption. We envision that optimization of ZrO2 loading could further facilitate electroreduction of N-2 at both high NH3 synthesis rate and faradic efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 804, "Times Cited, All Databases": 845, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 214, "Article Number": null, "DOI": "10.1016/j.chempr.2018.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455452800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, X; Huang, DK; Fu, XQ; Wen, M; Jiang, XX; Lv, XW; Li, M; Gao, L; Liu, SS; Wang, MK; Zhao, C; Shen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Xin; Huang, Dekang; Fu, Xongqing; Wen, Ming; Jiang, Xingxing; Lv, Xiaowei; Li, Man; Gao, Lin; Liu, Shuangshuang; Wang, Mingkui; Zhao, Chuan; Shen, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering NiS/Ni2P Heterostructures for Efficient Electrocatalytic Water Splitting", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-active and low-cost bifunctional materials for catalyzing the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) holds a pivotal role in water splitting. Therefore, we present a new strategy to form NiS/Ni2P heterostructures. The as-obtained NiS/Ni2P/carbon cloth (CC) requires overpotentials of 111 mV for the HER and 265 mV for the OER to reach a current density of 20 mA cm(-2), outperforming their counterparts such as NiS and Ni2P under the same conditions. Additionally, the NiS/Ni2P/CC electrode requires a 1.67 V cell voltage to deliver 10 mA cm(-2) in a two-electrode electrolysis system, which is comparable to the cell using the benchmark Pt/C parallel to RuO2 electrode. Detailed characterizations reveal that strong electronic interactions between NiS and Ni2P, abundant active sites, and smaller charge-transfer resistance contribute to the improved HER and OER activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2018, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4689, "End Page": 4696, "Article Number": null, "DOI": "10.1021/acsami.7b16430", "DOI Link": "http://dx.doi.org/10.1021/acsami.7b16430", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424851600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Q; Chen, YP; Zhao, GQ; Lin, Y; Yu, ZW; Xu, X; Wang, XL; Liu, HK; Sun, WP; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Qian; Chen, Yaping; Zhao, Guoqiang; Lin, Yue; Yu, Zhenwei; Xu, Xun; Wang, Xiaolin; Liu, Hua Kun; Sun, Wenping; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active-Site-Enriched Iron-Doped Nickel/Cobalt Hydroxide nullosheets for Enhanced Oxygen Evolution Reaction", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active, durable, and inexpensive nullostructured catalysts are crucial for achieving efficient and economical electrochemical water splitting. However, developing efficient approaches to further improve the catalytic ability of the well-defined nullostructured catalysts is still a big challenge. Herein, we report a facile and universal cation-exchange process for synthesizing Fe-doped Ni(OH)(2) and Co(OH)(2) nullosheets with enriched active sites toward enhanced oxygen evolution reaction (OER). In comparison with typical NiFe layered double hydroxide (LDH) nullosteets prepared by the conventional one-pot method, Fe-doped Ni(OH)(2) nullosheets evolving from Ni(OH)(2) via an Fe3+/ Ni2+ cation-exchange process possess nulloporous surfaces with abundant defects. Accordingly, Fe-doped Ni(OH)(2) nullosheets exhibit higher electrochemical active surface area (ECSA) and improved surface wettability in comparison to NiFe LDH nullosheets and deliver significantly enhanced catalytic activity over NiFe LDH. Specifically, a low overpotential of only 245 mV is required to reach a current density of 10 mA cm(-2) for Ni0.83Fe0.17(OH)(2) nullosheets with a low Tafel slope of 61 mV dec(-1), which is greatly decreased in comparison with those of NiFe LDH (310 mV and 78 mV dec-1). Additionally, this cation exchange process is successfully extended to prepare Fe-doped Co(OH)(2) nullosheets with improved catalytic activity for oxygen evolution. The results suggest that this cation-exchange process should have great potential in the rational design of defect enriched catalysts toward high-performance electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 347, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5382, "End Page": "+", "Article Number": null, "DOI": "10.1021/acscatal.8b01332", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b01332", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434369600066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Wu, XY; Pan, WF; Zhang, GK; Chen, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jun; Wu, Xiaoyong; Pan, Wenfeng; Zhang, Gaoke; Chen, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vacancy-Rich Monolayer BiO2-x as a Highly Efficient UV, Visible, and Near-Infrared Responsive Photocatalyst", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vacancy-rich layered materials with good electron-transfer property are of great interest. Herein, a full-spectrum responsive vacancy-rich monolayer BiO2-x has been synthesized. The increased density of states at the conduction band (CB) minimum in the monolayer BiO2-x is responsible for the enhanced photon response and photo-absorption, which were confirmed by UV/Vis-NIR diffuse reflectance spectra (DRS) and photocurrent measurements. Compared to bulk BiO2-x, monolayer BiO2-x has exhibited enhanced photocatalytic performance for rhodamine B and phenol removal under UV, visible, and near-infrared light (NIR) irradiation, which can be attributed to the vacancy VBi-O''' as confirmed by the positron annihilation spectra. The presence of VBi-O''' defects in monolayer BiO2-x promoted the separation of electrons and holes. This finding provides an atomic level understanding for developing highly efficient UV, visible, and NIR light responsive photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2018, "Volume": 57, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 491, "End Page": 495, "Article Number": null, "DOI": "10.1002/anie.201708709", "DOI Link": "http://dx.doi.org/10.1002/anie.201708709", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419110500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hartlieb, KJ; Holcroft, JM; Moghadam, PZ; Vermeulen, NA; Algaradah, MM; Nassar, MS; Botros, YY; Snurr, RQ; Stoddart, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hartlieb, Karel J.; Holcroft, James M.; Moghadam, Peyman Z.; Vermeulen, Nicolaas A.; Algaradah, Mohammed M.; Nassar, Majed S.; Botros, Youssry Y.; Snurr, Randall Q.; Stoddart, J. Fraser", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CD-MOF: A Versatile Separation Medium", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous metal organic frameworks (MOFs) have been studied in the context of a wide variety of applications, particularly in relation to molecular storage and separation sciences. Recently, we reported a green, renewable framework material composed of gamma-cyclodextrin (gamma-CD) and alkali metal salts namely, CD-MOF. This porous material has been shown to facilitate the separation of mixtures of alkylaromatic compounds, including the BTEX mixture (benzene, toluene, ethylbenzene, and the regioisomers of xylene), into their pure components, in both the liquid and gas phases, in an energy-efficient manner which could have implications for the petrochemical industry. Here, we report the ability of CD-MOF to separate a wide variety of mixtures, including ethylbenzene from styrene, haloaromatics, terpinenes, pinenes and other chiral compounds. CD-MOF retains saturated compounds to a greater extent than their unsaturated analogues. Also, the location of a double bond within a molecule influences its retention within the extended framework, as revealed in the case of the structural isomers of pinene and terpinine, where the isomers with exocyclic double bonds are more highly retained than those with endocyclic double bonds. The ability of CD-MOF to separate various mono-and disubstituted haloaromatic compounds appears to be controlled by both the size of the halogen substituents and the strength of the noncovalent bonding interactions between the analyte and the framework, an observation which has been confirmed by molecular simulations. Since CD-MOF is a homochiral framework, it is also able to resolve the enulltiomers of chiral analytes, including those of limonene and 1-phenylethanol. These findings could lead to cheaper and easier-to-prepare stationary phases for HPLC separations when compared with other chiral stationary phases, such as CD-bonded silica particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2016, "Volume": 138, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2292, "End Page": 2301, "Article Number": null, "DOI": "10.1021/jacs.5b12860", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b12860", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371103900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, HP; Li, XL; Song, JH; Zhang, X; Luo, LL; He, Y; Li, BS; Cai, Y; Hu, SY; Xiao, XC; Wang, CM; Rosso, KM; Yi, R; Patel, R; Zhang, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Haiping; Li, Xiaolin; Song, Junhua; Zhang, Xin; Luo, Langli; He, Yang; Li, Binsong; Cai, Yun; Hu, Shenyang; Xiao, Xingcheng; Wang, Chongmin; Rosso, Kevin M.; Yi, Ran; Patel, Rajankumar; Zhang, Ji-Guang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical porous silicon structures with extraordinary mechanical strength as high-performance lithium-ion battery anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous structured silicon has been regarded as a promising candidate to overcome pulverization of silicon-based anodes. However, poor mechanical strength of these porous particles has limited their volumetric energy density towards practical applications. Here we design and synthesize hierarchical carbon-nullotube@silicon@carbon microspheres with both high porosity and extraordinary mechanical strength (>200MPa) and a low apparent particle expansion of 40% upon full lithiation. The composite electrodes of carbon-nullotube@silicon@carbon-graphite with a practical loading (3mAhcm(-2)) deliver 750mAhg(-1) specific capacity, <20% initial swelling at 100% state-of-charge, and 92% capacity retention over 500 cycles. Calendered electrodes achieve 980mAhcm(-3) volumetric capacity density and <50% end-of-life swell after 120 cycles. Full cells with LiNi1/3Mn1/3Co1/3O2 cathodes demonstrate >92% capacity retention over 500 cycles. This work is a leap in silicon anode development and provides insights into the design of electrode materials for other batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1474, "DOI": "10.1038/s41467-020-15217-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15217-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522138100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SZ; Hu, WH; Zhang, X; He, PL; Pattengale, B; Liu, CM; Cendejas, M; Hermans, I; Zhang, XY; Zhang, J; Huang, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Sizhuo; Hu, Wenhui; Zhang, Xin; He, Peilei; Pattengale, Brian; Liu, Cunming; Cendejas, Melissa; Hermans, Ive; Zhang, Xiaoyi; Zhang, Jian; Huang, Jier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D Covalent Organic Frameworks as Intrinsic Photocatalysts for Visible Light-Driven CO2 Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic framework (COF) represents an emerging class of porous materials that have exhibited great potential in various applications, particularly in catalysis. In this work, we report a newly designed 2D COF with incorporated Re complex, which exhibits intrinsic light absorption and charge separation (CS) properties. We show that this hybrid catalyst can efficiently reduce CO2 to form CO under visible light illumination with high electivity (98%) and better activity than its homogeneous Re counterpart. More importantly, using advanced transient optical and X-ray absorption spectroscopy and in situ diffuse reflectance spectroscopy, we unraveled three key intermediates that are responsible for CS, the induction period, and rate limiting step in catalysis. This work not only demonstrates the potential of COFs as next generation photocatalysts for solar fuel conversion but also provide unprecedented insight into the mechanistic origins for light-driven CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2018, "Volume": 140, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14614, "End Page": 14618, "Article Number": null, "DOI": "10.1021/jacs.8b09705", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b09705", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449887800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, ZH; Padilla, JA; Xuriguera, E; Brillas, E; Sires, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Zhihong; Padilla, Jose A.; Xuriguera, Elena; Brillas, Enric; Sires, Ignasi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic MIL(Fe)-type MOF-derived N-doped nullo-ZVI@C rods as heterogeneous catalyst for the electro-Fenton degradation of gemfibrozil in a complex aqueous matrix", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of metal-organic frameworks (MOFs) as suspended heterogeneous catalysts in electro-Fenton (EF) process for water treatment is almost inexistent. Fe-MOFs synthesized from phthalic acid-based linkers were spindle-shaped MIL(Fe)-88B and NH2-MIL(Fe)-88B crystals, whereas their calcination yielded nullo-ZVI@C and nullo-ZVI@C-N. The lipid regulator gemfibrozil was spiked into 0.050 M Na2SO4 solutions or urban wastewater and treated in electrolytic cells with an air-diffusion cathode to generate H2O2. The nullo-ZVI@C-N catalyst obtained at 800 degrees C showed the highest activity, with high stability as deduced from the low iron leaching and high recyclability. Almost total drug removal and significant mineralization was feasible in both matrices at near-neutral pH. The presence of core-shell nullo-ZVI and Fe3O4 nulloparticles encapsulated in N-doped fusiform porous carbon rods was revealed, ensuring the Fe(III) conversion to Fe(II). Carbon doping with N contributed to the enhanced catalytic activity, and the strong magnetism facilitated the post-treatment catalyst recovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2020, "Volume": 266, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118604, "DOI": "10.1016/j.apcatb.2020.118604", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.118604", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517665200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Spezzati, G; Benavidez, AD; DeLaRiva, AT; Su, YQ; Hofmann, JP; Asahina, S; Olivier, EJ; Neethling, JH; Miller, JT; Datye, AK; Hensen, EJM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Spezzati, Giulia; Benavidez, Angelica D.; DeLaRiva, Andrew T.; Su, Yaqiong; Hofmann, Jan P.; Asahina, Shunsuke; Olivier, Ezra J.; Neethling, Johannes H.; Miller, Jeffrey T.; Datye, Abhaya K.; Hensen, Emiel J. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO oxidation by Pd supported on CeO2(100) and CeO2(111) facets", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pd/CeO2 is an active component in emission control catalysts for CO oxidation. nullostructured CeO2 powders can be prepared in the form of rods exposing predominulltly (111) surfaces and cubes exposing (100) surfaces. While differences in the reactivity of Pd supported on these facets of ceria have been reported, the origins of the reactivity differences are not well understood. Pd supported on (111) surfaces of ceria rods exhibits room temperature CO oxidation activity, while Pd on (100) surface of ceria cubes shows comparable activity at a temperature that is 60 degrees C higher. Earlier, we established that Pd/CeO2-rods are active due to a Langmuir-Hinshelwood mechanism involving isolated Pd atoms in the form of Pd1O and Pd1O2 species. Here, we establish using in situ CO IR spectroscopy and density functional theory (DFT) that, in addition to TEM-visible Pd nulloparticles, Pd/CeO2-cubes also contain isolated Pd species, predominulltly in the form of Pd1O. DFT calculations show that CO oxidation proceeds via a Mars-van Krevelen pathway, which is possible for the (100) surface because of the lower Ce-O binding energy compared to the (111) surface. Overall, the catalytic cycle for CO oxidation on Pd/CeO2(100) involves a higher free energy barrier than on Pd/CeO2(111) in keeping with the experimentally observed activity difference. EXAFS measurements show that the active Pd phase in both Pd/CeO2-rods and Pd/CeO2-cubes responds dynamically with respect to reducing and oxidizing conditions. The redispersion of Pd in oxidative conditions is more pronounced for Pd/CeO2-rods and the catalyst is more active after an oxidative treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 243, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 36, "End Page": 46, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.10.015", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.10.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453616800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, H; Sun, MZ; Wu, SL; Huang, BL; Lee, CS; Zhang, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Hao; Sun, Mingzi; Wu, Shuilin; Huang, Bolong; Lee, Chun-Sing; Zhang, Wenjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen-Incorporated NiMoP nullotube Arrays as Efficient Bifunctional Electrocatalysts For Urea-Assisted Energy-Saving Hydrogen Production in Alkaline Electrolyte", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To couple hydrogen evolution reaction (HER) with urea oxidation reaction (UOR) is a promising approach to produce H-2 with reduced energy consumption. However, the development of a low-cost and high-performance bifunctional electrocatalyst toward HER and UOR is still a challenge. In this work, oxygen-incorporated nickel molybdenum phosphide nullotube arrays are synthesized on nickel foam (O-NiMoP/NF) via electrodeposition accompanied with in-situ template etching. Benefiting from the modulated electronic structure and the nullotube array architecture of O-NiMoP, the self-supporting O-NiMoP/NF electrodes demonstrate highly efficient bifunctional catalytic activity toward HER and UOR. Particularly, in the HER and UOR (HER||UOR) coupled system for H-2 production, a significantly reduced cell voltage of 1.55 V is obtained at the current density of 50 mA cm(-2), which is about 300 mV lower than that of the conventional water electrolysis. Density functional theory calculations reveal that the remarkable HER and UOR activities originated from the Ni sites with the modulated electronic environment induced by Mo, P and O atoms, which facilitate the water dissociation during HER and balance the adsorption/desorption of the intermediates during UOR. The development of Ni-based phosphides nullotube arrays as a bifunctional electrocatalyst in HER||OER system provides a new approach enabling energy-saving H-2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 31, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104951, "DOI": "10.1002/adfm.202104951", "DOI Link": "http://dx.doi.org/10.1002/adfm.202104951", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678691200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, Y; Zhang, YM; Gao, TL; Yao, T; Zhang, XH; Han, JC; Wang, XJ; Zhang, ZH; Xu, P; Zhang, P; Cao, XZ; Song, B; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Ying; Zhang, Yumin; Gao, Tangling; Yao, Tai; Zhang, Xinghong; Han, Jiecai; Wang, Xianjie; Zhang, Zhihua; Xu, Ping; Zhang, Peng; Cao, Xingzhong; Song, Bo; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Phase and Disorder Engineering in 1T-MoSe2 nullosheets for Enhanced Hydrogen-Evolution Reaction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MoSe2 is a promising earth-abundant electrocatalyst for the hydrogen-evolution reaction (HER), even though it has received much less attention among the layered dichalcogenide (MX2) materials than MoS2 so far. Here, a novel hydrothermal-synthesis strategy is presented to achieve simultaneous and synergistic modulation of crystal phase and disorder in partially crystallized 1T-MoSe2 nullosheets to dramatically enhance their HER catalytic activity. Careful structural characterization and defect characterization using positron annihilation lifetime spectroscopy correlated with electrochemical measurements show that the formation of the 1T phase under a large excess of the NaBH4 reductant during synthesis can effectively improve the intrinsic activity and conductivity, and the disordered structure from a lower reaction temperature can provide abundant unsaturated defects as active sites. Such synergistic effects lead to superior HER catalytic activity with an overpotential of 152 mV versus reversible hydrogen electrode (RHE) for the electrocatalytic current density of j = -10 mA cm(-2), and a Tafel slope of 52 mV dec(-1). This work paves a new pathway for improving the catalytic activity of MoSe2 and generally MX2-based electrocatalysts via a synergistic modulation strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2017, "Volume": 29, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700311, "DOI": "10.1002/adma.201700311", "DOI Link": "http://dx.doi.org/10.1002/adma.201700311", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406030900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schroeder, TBH; Guha, A; Lamoureux, A; VanRenterghem, G; Sept, D; Shtein, M; Yang, J; Mayer, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schroeder, Thomas B. H.; Guha, Anirvan; Lamoureux, Aaron; VanRenterghem, Gloria; Sept, David; Shtein, Max; Yang, Jerry; Mayer, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An electric-eel-inspired soft power source from stacked hydrogels", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Progress towards the integration of technology into living organisms requires electrical power sources that are biocompatible, mechanically flexible, and able to harness the chemical energy available inside biological systems. Conventional batteries were not designed with these criteria in mind. The electric organ of the knifefish Electrophorus electricus (commonly known as the electric eel) is, however, an example of an electrical power source that operates within biological constraints while featuring power characteristics that include peak potential differences of 600 volts and currents of 1 ampere(1,2). Here we introduce an electric-eel-inspired power concept that uses gradients of ions between miniature polyacrylamide hydrogel compartments bounded by a repeating sequence of cation-and anion-selective hydrogel membranes. The system uses a scalable stacking or folding geometry that generates 110 volts at open circuit or 27 milliwatts per square metre per gel cell upon simultaneous, self-registered mechanical contact activation of thousands of gel compartments in series while circumventing power dissipation before contact. Unlike typical batteries, these systems are soft, flexible, transparent, and potentially biocompatible. These characteristics suggest that artificial electric organs could be used to power next-generation implant materials such as pacemakers, implantable sensors, or prosthetic devices in hybrids of living and non-living systems(3-6).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2017, "Volume": 552, "Issue": 7684, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature24670", "DOI Link": "http://dx.doi.org/10.1038/nature24670", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418029500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, DC; Yuen, PY; Liu, YY; Liu, W; Liu, N; Dauskardt, RH; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Dingchang; Yuen, Pak Yan; Liu, Yayuan; Liu, Wei; Liu, Nian; Dauskardt, Reinhold H.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Silica-Aerogel-Reinforced Composite Polymer Electrolyte with High Ionic Conductivity and High Modulus", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy all-solid-state lithium (Li) batteries have great potential as next-generation energy-storage devices. Among all choices of electrolytes, polymer-based systems have attracted widespread attention due to their low density, low cost, and excellent processability. However, they are generally mechanically too weak to effectively suppress Li dendrites and have lower ionic conductivity for reasonable kinetics at ambient temperature. Herein, an ultrastrong reinforced composite polymer electrolyte (CPE) is successfully designed and fabricated by introducing a stiff mesoporous SiO2 aerogel as the backbone for a polymer-based electrolyte. The interconnected SiO2 aerogel not only performs as a strong backbone strengthening the whole composite, but also offers large and continuous surfaces for strong anion adsorption, which produces a highly conductive pathway across the composite. As a consequence, a high modulus of approximate to 0.43 GPa and high ionic conductivity of approximate to 0.6 mS cm(-1) at 30 degrees C are simultaneously achieved. Furthermore, LiFePO4-Li full cells with good cyclability and rate capability at ambient temperature are obtained. Full cells with cathode capacity up to 2.1 mAh cm(-2) are also demonstrated. The aerogel-reinforced CPE represents a new design principle for solid-state electrolytes and offers opportunities for future all-solid-state Li batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2018, "Volume": 30, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802661, "DOI": "10.1002/adma.201802661", "DOI Link": "http://dx.doi.org/10.1002/adma.201802661", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440813300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, CY; Lei, XX; Hu, JJ; Jiang, YL; Li, QJ; Song, YT; Zhang, QY; Li-Ling, J; Xie, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Chen-Yu; Lei, Xiong-Xin; Hu, Juan-Juan; Jiang, Yan-Lin; Li, Qian-Jin; Song, Yu-Ting; Zhang, Qing-Yi; Li-Ling, Jesse; Xie, Hui-Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-crosslinking hydrogels with robust bio-adhesion and pro-coagulant activity for first-aid hemostasis and infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bio-adhesive polysaccharide-based hydrogels have attracted much attention in first-aid hemostasis and wound healing for excellent biocompatibility, antibacterial property and pro-healing bioactivity. Yet, the inadequate mechanical properties and bio-adhesion limit their applications. Herein, based on dynamic covalent bonds, photo-triggered covalent bonds and hydrogen bonds, multifunctional bio-adhesive hydrogels comprising modified carboxymethyl chitosan, modified sodium alginate and tannic acid are developed. Multi-crosslinking strategy endows hydrogels with improved strength and flexibility simultaneously. Owing to cohesion enhancement strategy and self-healing ability, considerable bio-adhesion is presented by the hydrogel with a maximal adhesion strength of 162.6 kPa, 12.3-fold that of commercial fibrin glue. Based on bio-adhesion and procoagulant activity (e.g., the stimulative aggregation and adhesion of erythrocytes and platelets), the hydrogel reveals superior hemostatic performance in rabbit liver injury model with blood loss of 0.32 g, only 54.2% of that in fibrin glue. The healing efficiency of hydrogel for infected wounds is markedly better than commercial EGF Gel and Ag+ Gel due to the enhanced antibacterial and antioxidant properties. Through the multi-crosslinking strategy, the hydrogels show enhanced mechanical properties, fabulous bio-adhesion, superior hemostatic performance and promoting healing ability, thereby have an appealing application value for the first-aid hemostasis and infected wound healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 388, "End Page": 402, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.02.034", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.02.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788758100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Agarwal, N; Freakley, SJ; McVicker, RU; Althahban, SM; Dimitratos, N; He, Q; Morgan, DJ; Jenkins, RL; Willock, DJ; Taylor, SH; Kiely, CJ; Hutchings, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Agarwal, Nishtha; Freakley, Simon J.; McVicker, Rebecca U.; Althahban, Sultan M.; Dimitratos, Nikolaos; He, Qian; Morgan, David J.; Jenkins, Robert L.; Willock, David J.; Taylor, Stuart H.; Kiely, Christopher J.; Hutchings, Graham J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous Au-Pd colloids catalyze selective CH4 oxidation to CH3OH with O2 under mild conditions", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The selective oxidation of methane, the primary component of natural gas, remains an important challenge in catalysis. We used colloidal gold-palladium nulloparticles, rather than the same nulloparticles supported on titanium oxide, to oxidize methane to methanol with high selectivity (92%) in aqueous solution at mild temperatures. Then, using isotopically labeled oxygen (O-2) as an oxidant in the presence of hydrogen peroxide (H2O2), we demonstrated that the resulting methanol incorporated a substantial fraction (70%) of gas-phase O-2. More oxygenated products were formed than the amount of H2O2 consumed, suggesting that the controlled breakdown of H2O2 activates methane, which subsequently incorporates molecular oxygen through a radical process. If a source of methyl radicals can be established, then the selective oxidation of methane to methanol using molecular oxygen is possible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2017, "Volume": 358, "Issue": 6360, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 223, "End Page": 226, "Article Number": null, "DOI": "10.1126/science.aan6515", "DOI Link": "http://dx.doi.org/10.1126/science.aan6515", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412841500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, L; Yuan, S; Zhang, LL; Tan, K; Li, JL; Kirchon, A; Liu, LM; Zhang, P; Han, Y; Chabal, YJ; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Liang; Yuan, Shuai; Zhang, Liang-Liang; Tan, Kui; Li, Jia-Luo; Kirchon, Angelo; Liu, Ling-Mei; Zhang, Peng; Han, Yu; Chabal, Yves J.; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal-Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sufficient pore size, appropriate stability, and hierarchical porosity are three prerequisites for open frameworks designed for drug delivery, enzyme immobilization, and catalysis involving large molecules. Herein, we report a powerful and general strategy, linker thermolysis, to construct ultrastable hierarchically porous metalorganic frameworks (HP-MOFs) with tunable pore size distribution. Linker instability, usually an undesirable trait of MOFs, was exploited to create mesopores by generating crystal defects throughout a microporous MOF crystal via thermolysis. The crystallinity and stability of HP-MOFs remain after thermolabile linkers are selectively removed from multivariate metalorganic frameworks (MTV-MOFs) through a decarboxylation process. A domain-based linker spatial distribution was found to be critical for creating hierarchical pores inside MTV-MOFs. Furthermore, linker thermolysis promotes the formation of ultrasmall metal oxide nulloparticles immobilized in an open framework that exhibits high catalytic activity for Lewis acid-catalyzed reactions. Most importantly, this work provides fresh insights into the connection between linker apportionment and vacancy distribution, which may shed light on probing the disordered linker apportionment in multivariate systems, a long-standing challenge in the study of MTV-MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2018, "Volume": 140, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2363, "End Page": 2372, "Article Number": null, "DOI": "10.1021/jacs.7b12916", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b12916", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425475300055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, TZ; Sun, SN; Song, JJ; Xi, SB; Du, YH; Chen, B; Sasangka, WA; Liao, HB; Gan, CL; Scherer, GG; Zeng, L; Wang, HJ; Li, H; Grimaud, A; Xu, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Tianze; Sun, Shengnull; Song, Jiajia; Xi, Shibo; Du, Yonghua; Chen, Bo; Sasangka, Wardhana Aji; Liao, Hanbin; Gan, Chee Lip; Scherer, Guenther G.; Zeng, Lin; Wang, Haijiang; Li, Hui; Grimaud, Alexis; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient and low-cost electrocatalysts for the oxygen evolution reaction (OER) is critical for improving the efficiency of water electrolysis. Here, we report a strategy using Fe substitution to enable the inactive spinel CoAl2O4 to become highly active and superior to the benchmark IrO2. The Fe substitution is revealed to facilitate surface reconstruction into active Co oxyhydroxides under OER conditions. It also activates deprotonation on the reconstructed oxyhydroxide to induce negatively charged oxygen as an active site, thus significantly enhancing the OER activity of CoAl2O4. Furthermore, it promotes the pre-oxidation of Co and introduces great structural flexibility due to the uplift of the oxygen 2p levels. This results in the accumulation of surface oxygen vacancies along with lattice oxygen oxidation that terminates as Al3+ leaches, preventing further reconstruction. We showcase a promising way to achieve tunable electrochemical reconstruction by optimizing the electronic structure for low-cost and robust spinel oxide OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 817, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 763, "End Page": 772, "Article Number": null, "DOI": "10.1038/s41929-019-0325-4", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0325-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486144700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YG; Zhang, YF; Lin, MS; Long, JL; Zhang, ZZ; Lin, HX; Wu, JCS; Wang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yangen; Zhang, Yongfan; Lin, Mousheng; Long, Jinlin; Zhang, Zizhong; Lin, Huaxiang; Wu, Jeffrey C-S.; Wang, Xuxu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolayered Bi2WO6 nullosheets mimicking heterojunction interface with open surfaces for photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional-layered heterojunctions have attracted extensive interest recently due to their exciting behaviours in electronic/optoelectronic devices as well as solar energy conversion systems. However, layered heterojunction materials, especially those made by stacking different monolayers together by strong chemical bonds rather than by weak van der Waal interactions, are still challenging to fabricate. Here the monolayer Bi2WO6 with a sandwich substructure of [BiO](+)-[WO4](2-)-[BiO](+) is reported. This material may be characterized as a layered heterojunction with different monolayer oxides held together by chemical bonds. Coordinatively unsaturated Bi atoms are present as active sites on the surface. On irradiation, holes are generated directly on the active surface layer and electrons in the middle layer, which leads to the outstanding performances of the monolayer material in solar energy conversion. Our work provides a general bottom-up route for designing and preparing novel monolayer materials with ultrafast charge separation and active surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 661, "Times Cited, All Databases": 680, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8340, "DOI": "10.1038/ncomms9340", "DOI Link": "http://dx.doi.org/10.1038/ncomms9340", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363021700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, P; Lethien, C; Pinaud, S; Brousse, K; Laloo, R; Turq, V; Respaud, M; Demortière, A; Daffos, B; Taberna, PL; Chaudret, B; Gogotsi, Y; Simon, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, P.; Lethien, C.; Pinaud, S.; Brousse, K.; Laloo, R.; Turq, V.; Respaud, M.; Demortiere, A.; Daffos, B.; Taberna, P. L.; Chaudret, B.; Gogotsi, Y.; Simon, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-chip and freestanding elastic carbon films for micro-supercapacitors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integration of electrochemical capacitors with silicon-based electronics is a major challenge, limiting energy storage on a chip. We describe a wafer-scale process for manufacturing strongly adhering carbide-derived carbon films and interdigitated micro-supercapacitors with embedded titanium carbide current collectors, fully compatible with current microfabrication and silicon-based device technology. Capacitance of those films reaches 410 farads per cubic centimeter/200 millifarads per square centimeter in aqueous electrolyte and 170 farads per cubic centimeter/85 millifarads per square centimeter in organic electrolyte. We also demonstrate preparation of self-supported, mechanically stable, micrometer-thick porous carbon films with a Young's modulus of 14.5 gigapascals, with the possibility of further transfer onto flexible substrates. These materials are interesting for applications in structural energy storage, tribology, and gas separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 630, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2016, "Volume": 351, "Issue": 6274, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 691, "End Page": 695, "Article Number": null, "DOI": "10.1126/science.aad3345", "DOI Link": "http://dx.doi.org/10.1126/science.aad3345", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369810000036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XJ; Feng, W; Chang, J; Tan, YW; Li, JC; Chen, M; Sun, Y; Li, FY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xingjun; Feng, Wei; Chang, Jian; Tan, Yan-Wen; Li, Jiachang; Chen, Min; Sun, Yun; Li, Fuyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-feedback upconversion nullocomposite for accurate photothermal therapy at facile temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) at present, following the temperature definition for conventional thermal therapy, usually keeps the temperature of lesions at 42-45 degrees C or even higher. Such high temperature kills cancer cells but also increases the damage of normal tissues near lesions through heat conduction and thus brings about more side effects and inhibits therapeutic accuracy. Here we use temperature-feedback upconversion nulloparticle combined with photothermal material for real-time monitoring of microscopic temperature in PTT. We observe that microscopic temperature of photothermal material upon illumination is high enough to kill cancer cells when the temperature of lesions is still low enough to prevent damage to normal tissue. On the basis of the above phenomenon, we further realize high spatial resolution photothermal ablation of labelled tumour with minimal damage to normal tissues in vivo. Our work points to a method for investigating photothermal properties at nulloscale, and for the development of new generation of PTT strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 892, "Times Cited, All Databases": 940, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10437, "DOI": "10.1038/ncomms10437", "DOI Link": "http://dx.doi.org/10.1038/ncomms10437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371011500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YZ; He, XF; Mo, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yizhou; He, Xingfeng; Mo, Yifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations were performed to investigate the electrochemical stability of lithium solid electrolyte materials in all-solid-state Li-ion batteries. The common solid electrolytes were found to have a limited electrochemical window. Our results suggest that the outstanding stability of the solid electrolyte materials is not thermodynamically intrinsic but is originated from kinetic stabilizations. The sluggish kinetics of the decomposition reactions cause a high overpotential leading to a nominally wide electrochemical window observed in many experiments. The decomposition products, similar to the solid-electrolyte-interphases, mitigate the extreme chemical potential from the electrodes and protect the solid electrolyte from further decompositions. With the aid of the first-principles calculations, we revealed the passivation mechanism of these decomposition interphases and quantified the extensions of the electrochemical window from the interphases. We also found that the artificial coating layers applied at the solid electrolyte and electrode interfaces have a similar effect of passivating the solid electrolyte. Our newly gained understanding provided general principles for developing solid electrolyte materials with enhanced stability and for engineering interfaces in all-solid-state Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1461, "Times Cited, All Databases": 1607, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2015, "Volume": 7, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23685, "End Page": 23693, "Article Number": null, "DOI": "10.1021/acsami.5b07517", "DOI Link": "http://dx.doi.org/10.1021/acsami.5b07517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363994700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gottesfeld, S; Dekel, DR; Page, M; Bae, C; Yan, YS; Zelenay, P; Kim, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gottesfeld, Shimshon; Dekel, Dario R.; Page, Miles; Bae, Chulsung; Yan, Yushan; Zelenay, Piotr; Kim, Yu Seung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion exchange membrane fuel cells: Current status and remaining challenges", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The anion exchange membrane fuel cell (AEMFC) is an attractive alternative to acidic proton exchange membrane fuel cells, which to date have required platinum-based catalysts, as well as acid-tolerant stack hardware. The AEMFC could use non-platinum-group metal catalysts and less expensive metal hardware thanks to the high pH of the electrolyte. Over the last decade, substantial progress has been made in improving the performance and durability of the AEMFC through the development of new materials and the optimization of system design and operation conditions. In this perspective article, we describe the current status of AEMFCs as having reached beginning of life performance very close to that of PEMFC5 when using ultra-low loadings of Pt, while advancing towards operation on non-platinum-group metal catalysts alone. In the latter sections, we identify the remaining technical challenges, which require further research and development, focusing on the materials and operational factors that critically impact AEMFC performance and/or durability. These perspectives may provide useful insights for the development of next-generation of AEMFCs. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 753, "Times Cited, All Databases": 817, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2018, "Volume": 375, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 170, "End Page": 184, "Article Number": null, "DOI": "10.1016/j.jpowsour.2017.08.010", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2017.08.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418463700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, XL; Ji, X; Chen, L; Chen, J; Deng, T; Han, FD; Yue, J; Piao, N; Wang, RX; Zhou, XQ; Xiao, XZ; Chen, LX; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Xiulin; Ji, Xiao; Chen, Long; Chen, Ji; Deng, Tao; Han, Fudong; Yue, Jie; Piao, null; Wang, Ruixing; Zhou, Xiuquan; Xiao, Xuezhang; Chen, Lixin; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbonate electrolytes are commonly used in commercial non-aqueous Li-ion batteries. However, the high affinity between the solvents and the ions and high flammability of the carbonate electrolytes limits the battery operation temperature window to -20 to + 50 degrees C and the voltage window to 0.0 to 4.3 V. Here, we tame the affinity between solvents and Li ions by dissolving fluorinated electrolytes into highly fluorinated non-polar solvents. In addition to their non-flammable characteristic, our electrolytes enable high electrochemical stability in a wide voltage window of 0.0 to 5.6 V, and high ionic conductivities in a wide temperature range from -125 to + 70 degrees C. We show that between -95 and + 70 degrees C, the electrolytes enable LiNi0.8Co0.15Al0.05O2 cathodes to achieve high Coulombic efficiencies of >99.9%, and the aggressive Li anodes and the high-voltage (5.4 V) LiCoMnO4 to achieve Coulombic efficiencies of >99.4% and 99%, respectively. Even at -85 degrees C, the LiNi0.8Co0.15Al0.05O2 parallel to Li battery can still deliver similar to 50% of its room-temperature capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 696, "Times Cited, All Databases": 750, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 882, "End Page": 890, "Article Number": null, "DOI": "10.1038/s41560-019-0474-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0474-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489768100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCalla, E; Abakumov, AM; Saubanère, M; Foix, D; Berg, EJ; Rousse, G; Doublet, ML; Gonbeau, D; Novák, P; Van Tendeloo, G; Dominko, R; Tarascon, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCalla, Eric; Abakumov, Artem M.; Saubanere, Matthieu; Foix, Dominique; Berg, Erik J.; Rousse, Gwenaelle; Doublet, Marie-Liesse; Gonbeau, Danielle; Novak, Petr; Van Tendeloo, Gustaaf; Dominko, Robert; Tarascon, Jean-Marie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion (Li-ion) batteries that rely on cationic redox reactions are the primary energy source for portable electronics. One pathway toward greater energy density is through the use of Li-rich layered oxides. The capacity of this class of materials (>270 milliampere hours per gram) has been shown to be nested in anionic redox reactions, which are thought to form peroxo-like species. However, the oxygen-oxygen (O-O) bonding pattern has not been observed in previous studies, nor has there been a satisfactory explanation for the irreversible changes that occur during first delithiation. By using Li2IrO3 as a model compound, we visualize the O-O dimers via transmission electron microscopy and neutron diffraction. Our findings establish the fundamental relation between the anionic redox process and the evolution of the O-O bonding in layered oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 701, "Times Cited, All Databases": 740, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2015, "Volume": 350, "Issue": 6267, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1516, "End Page": 1521, "Article Number": null, "DOI": "10.1126/science.aac8260", "DOI Link": "http://dx.doi.org/10.1126/science.aac8260", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366591100056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, JH; Hu, ZX; Probert, M; Li, K; Lv, DH; Yang, XN; Gu, L; Mao, NN; Feng, QL; Xie, LM; Zhang, J; Wu, DZ; Zhang, ZY; Jin, CH; Ji, W; Zhang, XX; Yuan, J; Zhang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Jinhua; Hu, Zhixin; Probert, Matt; Li, Kun; Lv, Danhui; Yang, Xinull; Gu, Lin; Mao, nullnull; Feng, Qingliang; Xie, Liming; Zhang, Jin; Wu, Dianzhong; Zhang, Zhiyong; Jin, Chuanhong; Ji, Wei; Zhang, Xixiang; Yuan, Jun; Zhang, Ze", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring atomic defects in molybdenum disulphide monolayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects usually play an important role in tailoring various properties of two-dimensional materials. Defects in two-dimensional monolayer molybdenum disulphide may be responsible for large variation of electric and optical properties. Here we present a comprehensive joint experiment-theory investigation of point defects in monolayer molybdenum disulphide prepared by mechanical exfoliation, physical and chemical vapour deposition. Defect species are systematically identified and their concentrations determined by aberration-corrected scanning transmission electron microscopy, and also studied by ab-initio calculation. Defect density up to 3.5 x 10(13) cm(-2) is found and the dominullt category of defects changes from sulphur vacancy in mechanical exfoliation and chemical vapour deposition samples to molybdenum antisite in physical vapour deposition samples. Influence of defects on electronic structure and charge-carrier mobility are predicted by calculation and observed by electric transport measurement. In light of these results, the growth of ultra-high-quality monolayer molybdenum disulphide appears a primary task for the community pursuing high-performance electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1249, "Times Cited, All Databases": 1361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6293, "DOI": "10.1038/ncomms7293", "DOI Link": "http://dx.doi.org/10.1038/ncomms7293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350289800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sanchez-Valencia, JR; Dienel, T; Gröning, O; Shorubalko, I; Mueller, A; Jansen, M; Amsharov, K; Ruffieux, P; Fasel, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sanchez-Valencia, Juan Ramon; Dienel, Thomas; Groening, Oliver; Shorubalko, Ivan; Mueller, Andreas; Jansen, Martin; Amsharov, Konstantin; Ruffieux, Pascal; Fasel, Roman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlled synthesis of single-chirality carbon nullotubes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past two decades, single-walled carbon nullotubes (SWCNTs) have received much attention because their extraordinary properties are promising for numerous applications(1,2). Many of these properties depend sensitively on SWCNT structure, which is characterized by the chiral index (n,m) that denotes the length and orientation of the circumferential vector in the hexagonal carbon lattice. Electronic properties are particularly strongly affected, with subtle structural changes switching tubes from metallic to semiconducting with various band-gaps. Monodisperse 'single-chirality' (that is, with a single (n, m) index) SWCNTs are thus needed to fully exploit their technological potential(1,2). Controlled synthesis through catalyst engineering(3-6), end-cap engineering(7) or cloning strategies(8,9), and also tube sorting based on chromatography(10,11), density-gradient centrifugation, electrophoresis and other techniques(12), have delivered SWCNT samples with narrow distributions of tube diameter and a large fraction of a predetermined tube type. But an effective pathway to truly monodisperse SWCNTs remains elusive. The use of template molecules to unambiguously dictate the diameter and chirality of the resulting nullotube(8,13-16) holds great promise in this regard, but has hitherto had only limited practical success(7,17,18). Here we show that this bottom-up strategy can produce targeted nullotubes: we convert molecular precursors into ultrashort singly capped (6,6) 'armchair' nullotube seeds using surface-catalysed cyclodehydrogenation on a platinum (111) surface, and then elongate these during a subsequent growth phase to produce single-chirality and essentially defect-free SWCNTs with lengths up to a few hundred nullometres. We expect that our on-surface synthesis approach will provide a route to nullotube-based materials with highly optimized properties for applications such as light detectors, photovoltaics, field-effect transistors and sensors(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 477, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2014, "Volume": 512, "Issue": 7512, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 61, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature13607", "DOI Link": "http://dx.doi.org/10.1038/nature13607", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339908000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, JJ; Liu, XY; Jiang, N; Yetisen, AK; Yuk, H; Yang, CX; Khademhosseini, A; Zhao, XH; Yun, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Jingjing; Liu, Xinyue; Jiang, null; Yetisen, Ali K.; Yuk, Hyunwoo; Yang, Changxi; Khademhosseini, Ali; Zhao, Xuanhe; Yun, Seok-Hyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stretchable, Strain Sensing Hydrogel Optical Fibers", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A core-clad fiber made of elastic, tough hydrogels is highly stretchable while guiding light. Fluorescent dyes are easily doped into the hydrogel fiber by diffusion. When stretched, the transmission spectrum of the fiber is altered, enabling the strain to be measured and also its location.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 28, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10244, "End Page": 10249, "Article Number": null, "DOI": "10.1002/adma.201603160", "DOI Link": "http://dx.doi.org/10.1002/adma.201603160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392726400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blancon, JC; Tsai, H; Nie, W; Stoumpos, CC; Pedesseau, L; Katan, C; Kepenekian, M; Soe, CMM; Appavoo, K; Sfeir, MY; Tretiak, S; Ajayan, PM; Kanatzidis, MG; Even, J; Crochet, JJ; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blancon, J. -C.; Tsai, H.; Nie, W.; Stoumpos, C. C.; Pedesseau, L.; Katan, C.; Kepenekian, M.; Soe, C. M. M.; Appavoo, K.; Sfeir, M. Y.; Tretiak, S.; Ajayan, P. M.; Kanatzidis, M. G.; Even, J.; Crochet, J. J.; Mohite, A. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PEROVSKITE PHYSICS Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding and controlling charge and energy flow in state-of-the-art semiconductor quantum wells has enabled high-efficiency optoelectronic devices. Two-dimensional (2D) Ruddlesden-Popper perovskites are solution-processed quantum wells wherein the band gap can be tuned by varying the perovskite-layer thickness, which modulates the effective electron-hole confinement. We report that, counterintuitive to classical quantum-confined systems where photogenerated electrons and holes are strongly bound by Coulomb interactions or excitons, the photophysics of thin films made of Ruddlesden-Popper perovskites with a thickness exceeding two perovskite-crystal units (>1.3 nullometers) is dominated by lower-energy states associated with the local intrinsic electronic structure of the edges of the perovskite layers. These states provide a direct pathway for dissociating excitons into longer-lived free carriers that substantially improve the performance of optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 922, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2017, "Volume": 355, "Issue": 6331, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1288, "End Page": 1291, "Article Number": null, "DOI": "10.1126/science.aal4211", "DOI Link": "http://dx.doi.org/10.1126/science.aal4211", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397082900033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yadav, AK; Nelson, CT; Hsu, SL; Hong, Z; Clarkson, JD; Schlepüetz, CM; Damodaran, AR; Shafer, P; Arenholz, E; Dedon, LR; Chen, D; Vishwanath, A; Minor, AM; Chen, LQ; Scott, JF; Martin, LW; Ramesh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yadav, A. K.; Nelson, C. T.; Hsu, S. L.; Hong, Z.; Clarkson, J. D.; Schlepueetz, C. M.; Damodaran, A. R.; Shafer, P.; Arenholz, E.; Dedon, L. R.; Chen, D.; Vishwanath, A.; Minor, A. M.; Chen, L. Q.; Scott, J. F.; Martin, L. W.; Ramesh, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of polar vortices in oxide superlattices", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complex interplay of spin, charge, orbital and lattice degrees of freedom provides a plethora of exotic phases and physical phenomena(1-5). In recent years, complex spin topologies have emerged as a consequence of the electronic band structure and the interplay between spin and spin-orbit coupling in materials-(6,7). Here we produce complex topologies of electrical polarization-namely, nullometre-scale vortex-antivortex (that is, clockwise-anticlockwise) arrays that are reminiscent of rotational spin topologies(6)-by making use of the competition between charge, orbital and lattice degrees of freedom in superlattices of alternating lead titanate and strontium titanate layers. Atomic-scale mapping of the polar atomic displacements by scanning transmission electron microscopy reveals the presence of long-range ordered vortex-antivortex arrays that exhibit nearly continuous polarization rotation. Phase-field modelling confirms that the vortex array is the low-energy state for a range of superlattice periods. Within this range, the large gradient energy from the vortex structure is counterbalanced by the corresponding large reduction in overall electrostatic energy (which would otherwise arise from polar discontinuities at the lead titanate/strontium titanate interfaces) and the elastic energy associated with epitaxial constraints and domain formation. These observations have implications for the creation of new states of matter (such as dipolar skyrmions, hedgehog states) and associated phenomena in ferroic materials, such as electrically controllable chirality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 775, "Times Cited, All Databases": 843, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2016, "Volume": 530, "Issue": 7589, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 198, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature16463", "DOI Link": "http://dx.doi.org/10.1038/nature16463", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369916700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WX; Huang, ZS; Zhang, WL; Li, YR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenxu; Huang, Zhishuo; Zhang, Wanli; Li, Yanrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional semiconductors with possible high room temperature mobility", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have calculated the longitudinal acoustic phonon limited electron mobility of 14 two-dimensional semiconductors with composition of MX2, where M (= Mo, W, Sn, Hf, Zr and Pt) is the transition metal, and X is S, Se and Te. We treated the scattering matrix by the deformation potential approximation. We found that out of 14 compounds, MoTe2, HfSe2 and ZrSe2 are promising regarding to their possible high mobility and finite band gap. The phonon limited mobility can be above 2,500 cm(2).V-1.s(-1) at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 660, "Times Cited, All Databases": 694, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1731, "End Page": 1737, "Article Number": null, "DOI": "10.1007/s12274-014-0532-x", "DOI Link": "http://dx.doi.org/10.1007/s12274-014-0532-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346641400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, ZH; Wu, N; Wei, JJ; Yang, YF; Wu, TT; Li, B; Hauser, SB; Yang, WD; Liu, JR; Zhao, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Zhi-Hui; Wu, Na; Wei, Jing-Jiang; Yang, Yun-Fei; Wu, Ting-Ting; Li, Bin; Hauser, Stefanie Beatrice; Yang, Wei-Dong; Liu, Jiu-Rong; Zhao, Shan-Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous and Ultra-Flexible Crosslinked MXene/Polyimide Composites for Multifunctional Electromagnetic Interference Shielding", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lightweight, ultra-flexible, and robust crosslinked transition metal carbide (Ti3C2 MXene) coated polyimide (PI) (C-MXene @PI) porous composites are manufactured via a scalable dip-coating followed by chemical crosslinking approach. In addition to the hydrophobicity, anti-oxidation and extreme-temperature stability, efficient utilization of the intrinsic conductivity of MXene, the interfacial polarization between MXene and PI, and the micrometer-sized pores of the composite foams are achieved. Consequently, the composites show a satisfactory X-band electromagnetic interference (EMI) shielding effectiveness of 22.5 to 62.5 dB at a density of 28.7 to 48.7 mg cm(-3) leading to an excellent surface-specific SE of 21,317 dB cm(2) g(-1). Moreover, the composite foams exhibit excellent electrothermal performance as flexible heaters in terms of a prominent, rapid reproducible, and stable electrothermal effect at low voltages and superior heat performance and more uniform heat distribution compared with the commercial heaters composed of alloy plates. Furthermore, the composite foams are well attached on a human body to check their electromechanical sensing performance, demonstrating the sensitive and reliable detection of human motions as wearable sensors. The excellent EMI shielding performance and multifunctionalities, along with the facile and easy-to-scalable manufacturing techniques, imply promising perspectives of the porous C-MXene@PI composites in next-generation flexible electronics, aerospace, and smart devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 59, "DOI": "10.1007/s40820-022-00800-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00800-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753413800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holland, C; Numata, K; Rnjak-Kovacina, J; Seib, FP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holland, Chris; Numata, Keiji; Rnjak-Kovacina, Jelena; Seib, F. Philipp", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Biomedical Use of Silk: Past, Present, Future", "Source Title": "ADVANCED HEALTHCARE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Humans have long appreciated silk for its lustrous appeal and remarkable physical properties, yet as the mysteries of silk are unraveled, it becomes clear that this outstanding biopolymer is more than a high-tech fiber. This progress report provides a critical but detailed insight into the biomedical use of silk. This journey begins with a historical perspective of silk and its uses, including the long-standing desire to reverse engineer silk. Selected silk structure-function relationships are then examined to appreciate past and current silk challenges. From this, biocompatibility and biodegradation are reviewed with a specific focus of silk performance in humans. The current clinical uses of silk (e.g., sutures, surgical meshes, and fabrics) are discussed, as well as clinical trials (e.g., wound healing, tissue engineering) and emerging biomedical applications of silk across selected formats, such as silk solution, films, scaffolds, electrospun materials, hydrogels, and particles. The journey finishes with a look at the roadmap of next-generation recombinullt silks, especially the development pipeline of this new industry for clinical use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800465, "DOI": "10.1002/adhm.201800465", "DOI Link": "http://dx.doi.org/10.1002/adhm.201800465", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455779200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Zhang, HT; Dong, HL; Meng, LQ; Jiang, LF; Jiang, L; Wang, Y; Yu, JS; Sun, YM; Hu, WP; Heeger, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jie; Zhang, Hantang; Dong, Huanli; Meng, Lingqiang; Jiang, Longfeng; Jiang, Lang; Wang, Ying; Yu, Junsheng; Sun, Yanming; Hu, Wenping; Heeger, Alan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High mobility emissive organic semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of high charge carrier mobility and high luminescence in an organic semiconductor is challenging. However, there is need of such materials for organic light-emitting transistors and organic electrically pumped lasers. Here we show a novel organic semiconductor, 2,6-diphenylanthracene (DPA), which exhibits not only high emission with single crystal absolute florescence quantum yield of 41.2% but also high charge carrier mobility with single crystal mobility of 34 cm(2) V-1 s(-1). Organic light-emitting diodes (OLEDs) based on DPA give pure blue emission with brightness up to 6,627 cd m(-2) and turn-on voltage of 2.8 V. 2,6-Diphenylanthracene OLED arrays are successfully driven by DPA field-effect transistor arrays, demonstrating that DPA is a high mobility emissive organic semiconductor with potential in organic optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 474, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10032, "DOI": "10.1038/ncomms10032", "DOI Link": "http://dx.doi.org/10.1038/ncomms10032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367567700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, RX; Li, WB; Li, J; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Ruixiang; Li, Wenbin; Li, Ju; Yang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant piezoelectricity of monolayer group IV monochalcogenides: SnSe, SnS, GeSe, and GeS", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We predict enormous, anisotropic piezoelectric effects in intrinsic monolayer group IV monochalcogenides (MX, M=Sn or Ge, X=Se or S), including SnSe, SnS, GeSe, and GeS. Using first-principle simulations based on the modern theory of polarization, we find that their piezoelectric coefficients are about one to two orders of magnitude larger than those of other 2D materials, such as MoS2 and GaSe, and bulk quartz and AlN which are widely used in industry. This enhancement is a result of the unique puckered C-2v symmetry and electronic structure of monolayer group IV monochalcogenides. Given the achieved experimental advances in the fabrication of monolayers, their flexible character, and ability to withstand enormous strain, these 2D structures with giant piezoelectric effects may be promising for a broad range of applications such as nullo-sized sensors, piezotronics, and energy harvesting in portable electronic devices. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 672, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2015, "Volume": 107, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 173104, "DOI": "10.1063/1.4934750", "DOI Link": "http://dx.doi.org/10.1063/1.4934750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364234200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CX; Yang, J; Pachfule, P; Li, S; Ye, MY; Schmidt, J; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Changxia; Yang, Jin; Pachfule, Pradip; Li, Shuang; Ye, Meng-Yang; Schmidt, Johannes; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight covalent organic framework/graphene aerogels with hierarchical porosity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fabrication of macroscopic objects from covalent organic frameworks (COFs) is challenging but of great significance to fully exploit their chemical functionality and porosity. Herein, COF/reduced graphene oxide (rGO) aerogels synthesized by a hydrothermal approach are presented. The COFs grow in situ along the surface of the 2D graphene sheets, which are stacked in a 3D fashion, forming an ultralight aerogel with a hierarchical porous structure after freeze-drying, which can be compressed and expanded several times without breaking. The COF/rGO aerogels show excellent absorption capacity (uptake of >200g organic solvent/g aerogel), which can be used for removal of various organic liquids from water. Moreover, as active material of supercapacitor devices, the aerogel delivers a high capacitance of 269Fg(-1) at 0.5Ag(-1) and cycling stability over 5000 cycles. Macroscopic architectures of covalent organic frameworks (COF) allow to fully exploit their chemical functionality and porosity but achieving three-dimensional hierarchical porous COF architectures remains challenging. Here, the authors present a COF/reduced graphene oxide aerogel which is synthesized by growing COF during a hydrothermal process along the surface of graphene sheets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4712, "DOI": "10.1038/s41467-020-18427-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18427-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573732600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maleki, H; Duraes, L; Portugal, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maleki, Hajar; Duraes, Luisa; Portugal, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An overview on silica aerogels synthesis and different mechanical reinforcing strategies", "Source Title": "JOURNAL OF NON-CRYSTALLINE SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silica aerogels are lightweight and highly porous materials, with a three-dimensional network of silica particles, which are obtained by extracting the liquid phase of silica gels under supercritical conditions. Due to their outstanding characteristics, such as extremely low thermal conductivity, low density, high porosity and high specific surface area, they have found excellent potential application for thermal insulation systems in aeronautical/aerospace and earthly domains, for environment clean up and protection, heat storage devices, transparent windows systems, thickening agents in paints, etc. However, native silica aerogels are fragile and sensitive at relatively low stresses, which limit their application. More durable aerogels, with higher strength and stiffness, can be obtained by proper selection of the silane precursors, and constructing the silica inorganic networks by compounding them with different organic polymers or different fiber networks. Recent studies showed that adding flexible organic polymers to the hydroxyl groups on the silica gel surface would be an effective mechanical reinforcing method of silica aerogels. More versatile polymer reinforcement approach can be readily achieved if proper functional groups are introduced on the surface of silica aerogels and then co-polymerized with appropriate organic monomers. The mechanical reinforced silica aerogels, with their very open texture, can be an outstanding thermal insulator material for different industrial and aerospace applications. This paper presents a review of the literature on the methods for mechanical reinforcing of silica aerogels and discusses the recent achievements in improving the strength and elastic response of native silica aerogels along with cost effectiveness of each methodology. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 578, "Times Cited, All Databases": 650, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2014, "Volume": 385, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 55, "End Page": 74, "Article Number": null, "DOI": "10.1016/j.jnoncrysol.2013.10.017", "DOI Link": "http://dx.doi.org/10.1016/j.jnoncrysol.2013.10.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331662500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FC; You, L; Seyler, KL; Li, XB; Yu, P; Lin, JH; Wang, XW; Zhou, JD; Wang, H; He, HY; Pantelides, ST; Zhou, W; Sharma, P; Xu, XD; Ajayan, PM; Wang, JL; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fucai; You, Lu; Seyler, Kyle L.; Li, Xiaobao; Yu, Peng; Lin, Junhao; Wang, Xuewen; Zhou, Jiadong; Wang, Hong; He, Haiyong; Pantelides, Sokrates T.; Zhou, Wu; Sharma, Pradeep; Xu, Xiaodong; Ajayan, Pulickel M.; Wang, Junling; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature ferroelectricity in CuInP2S6 ultrathin flakes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials have emerged as promising candidates for various optoelectronic applications based on their diverse electronic properties, ranging from insulating to superconducting. However, cooperative phenomena such as ferroelectricity in the 2D limit have not been well explored. Here, we report room-temperature ferroelectricity in 2D CuInP2S6 (CIPS) with a transition temperature of similar to 320 K. Switchable polarization is observed in thin CIPS of similar to 4 nm. To demonstrate the potential of this 2D ferroelectric material, we prepare a van der Waals (vdW) ferroelectric diode formed by CIPS/Si heterostructure, which shows good memory behaviour with on/off ratio of similar to 100. The addition of ferroelectricity to the 2D family opens up possibilities for numerous novel applications, including sensors, actuators, non-volatile memory devices, and various vdW heterostructures based on 2D ferroelectricity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 856, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12357, "DOI": "10.1038/ncomms12357", "DOI Link": "http://dx.doi.org/10.1038/ncomms12357", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381525200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zarzar, LD; Sresht, V; Sletten, EM; Kalow, JA; Blankschtein, D; Swager, TM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zarzar, Lauren D.; Sresht, Vishnu; Sletten, Ellen M.; Kalow, Julia A.; Blankschtein, Daniel; Swager, Timothy M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamically reconfigurable complex emulsions via tunable interfacial tensions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emulsification is a powerful, well-known technique for mixing and dispersing immiscible components within a continuous liquid phase. Consequently, emulsions are central components of medicine, food and performance materials. Complex emulsions, including Janus droplets (that is, droplets with faces of differing chemistries) and multiple emulsions, are of increasing importance' in pharmaceuticals and medical diagnostics', in the fabrication of microparticles and capsules' for food', in chemical separations', in cosmetics', and in dynamic optics'. Because complex emulsion properties and functions are related to the droplet geometry and composition, the development of rapid, simple fabrication approaches allowing precise control over the droplets' physical and chemical characteristics is critical. Significant advances in the fabrication of complex emulsions have been made using a number of procedures, ranging from largescale, less precise techniques that give compositional heterogeneity using high-shear mixers and membranes'', to small-volume but more precise microfluidic methodsn'''. However, such approaches have yet to create droplet morphologies that can be controllably altered after emulsification. Reconfigurable complex liquids potentially have great utility as dynamically tunable materials. Here we describe an approach to the one-step fabrication of three- and four-phase complex emulsions with highly controllable and reconfigurable morphologies. The fabrication makes use of the temperature-sensitive miscibility of hydrocarbon, silicone and fluorocarbon liquids, and is applied to both the microfluidic and the scalable batch production of complex droplets. We demonstrate that droplet geometries can be alternated between encapsulated and Janus configurations by varying the interfacial tensions using hydrocarbon and fluorinated surfactants including stimuli-responsive and cleavable surfactants. This yields a generalizable strategy for the fabrication of multiphase emulsions with controllably reconfigurable morphologies and the potential to create a wide range of responsive materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2015, "Volume": 518, "Issue": 7540, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 520, "End Page": 524, "Article Number": null, "DOI": "10.1038/nature14168", "DOI Link": "http://dx.doi.org/10.1038/nature14168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350097300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kojima, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kojima, Yoshitsugu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen storage materials for hydrogen and energy carriers", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen storage technology is essentially necessary to promote renewable energy. Many kinds of hydrogen storage materials, which are hydrogen storage alloys, inorganic chemical hydrides, carbon materials and liquid hydrides have been studied. In those materials, ammonia (NH3) is easily liquefied by compression at 1 MPa and 298 K, and has a highest volumetric hydrogen density of 10.7 kg H-2/100 L. It also has a high gravimetric hydrogen density of 17.8 wt%. The theoretical hydrogen conversion efficiency is about 90%. NH3 is burnable without emission of CO2 and has advantages as hydrogen and energy carriers. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2019, "Volume": 44, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18179, "End Page": 18192, "Article Number": null, "DOI": "10.1016/j.ijhydene.2019.05.119", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2019.05.119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476964900068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, JJ; Jin, RX; Li, A; Bi, YP; Ruan, QS; Deng, YC; Zhang, YJ; Yao, SY; Sankar, G; Ma, D; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Jijia; Jin, Renxi; Li, Ang; Bi, Yingpu; Ruan, Qiushi; Deng, Yucheng; Zhang, Yajun; Yao, Siyu; Sankar, Gopinathan; Ma, Ding; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective oxidation of methane to methanol at ambient conditions by titanium dioxide-supported iron species", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methane activation under moderate conditions and with good selectivity for value-added chemicals still remains a huge challenge. Here, we present a highly selective catalyst for the transformation of methane to methanol composed of highly dispersed iron species on titanium dioxide. The catalyst operates under moderate light irradiation (close to one Sun) and at ambient conditions. The optimized sample shows a 15% conversion rate for methane with an alcohol selectivity of over 97% (methanol selectivity over 90%) and a yield of 18 moles of alcohol per mole of iron active site in just 3 hours. X-ray photoelectron spectroscopy measurements with and without xenon lamp irradiation, light-intensity-modulated spectroscopies, photoelectrochemical measurements, X-ray absorption near-edge structure and extended X-ray absorption fine structure spectra, as well as isotopic analysis confirm the function of the major iron-containing species-namely, FeOOH and Fe2O3, which enhance charge transfer and separation, decrease the overpotential of the reduction reaction and improve selectivity towards methanol over carbon dioxide production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 445, "Times Cited, All Databases": 478, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 889, "End Page": 896, "Article Number": null, "DOI": "10.1038/s41929-018-0170-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0170-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449799200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, FJ; Zang, YP; Huang, DZ; Di, CA; Zhu, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fengjiao; Zang, Yaping; Huang, Dazhen; Di, Chong-an; Zhu, Daoben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and self-powered temperature-pressure dual-parameter sensors using microstructure-frame-supported organic thermoelectric materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin-like temperature-and pressure-sensing capabilities are essential features for the next generation of artificial intelligent products. Previous studies of e-skin and smart elements have focused on flexible pressure sensors, whereas the simultaneous and sensitive detection of temperature and pressure with a single device remains a challenge. Here we report developing flexible dual-parameter temperature-pressure sensors based on microstructure-frame-supported organic thermoelectric (MFSOTE) materials. The effective transduction of temperature and pressure stimuli into two independent electrical signals permits the instantaneous sensing of temperature and pressure with an accurate temperature resolution of <0.1 K and a high-pressure-sensing sensitivity of up to 28.9 kPa(-1). More importantly, these dual-parameter sensors can be self-powered with outstanding sensing performance. The excellent sensing properties of MFSOTE-based devices, together with their unique advantages of low cost and large-area fabrication, make MFSOTE materials possess promising applications in e-skin and health-monitoring elements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 525, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8356, "DOI": "10.1038/ncomms9356", "DOI Link": "http://dx.doi.org/10.1038/ncomms9356", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363022000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, XH; He, C; Li, BY; He, YH; Cullen, DA; Wegener, EC; Kropf, AJ; Martinez, U; Cheng, YW; Engelhard, MH; Bowden, ME; Song, M; Lemmon, T; Li, XS; Nie, ZM; Liu, J; Myers, DJ; Zelenay, P; Wang, GF; Wu, G; Ramani, V; Shao, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Xiaohong; He, Cheng; Li, Boyang; He, Yanghua; Cullen, David A.; Wegener, Evan C.; Kropf, A. Jeremy; Martinez, Ulises; Cheng, Yingwen; Engelhard, Mark H.; Bowden, Mark E.; Song, Miao; Lemmon, Teresa; Li, Xiaohong S.; Nie, Zimin; Liu, Jian; Myers, Deborah J.; Zelenay, Piotr; Wang, Guofeng; Wu, Gang; Ramani, Vijay; Shao, Yuyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance enhancement and degradation mechanism identification of a single-atom Co-N-C catalyst for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of catalysts free of platinum-group metals and with both a high activity and durability for the oxygen reduction reaction in proton exchange membrane fuel cells is a grand challenge. Here we report an atomically dispersed Co and N co-doped carbon (Co-N-C) catalyst with a high catalytic oxygen reduction reaction activity comparable to that of a similarly synthesized Fe-N-C catalyst but with a four-time enhanced durability. The Co-N-C catalyst achieved a current density of 0.022 A cm(-2) at 0.9 ViR-free (internal resistance-compensated voltage) and peak power density of 0.64 W cm(-2) in 1.0 bar H-2/O-2 fuel cells, higher than that of non-iron platinum-group-metal-free catalysts reported in the literature. Importantly, we identified two main degradation mechanisms for metal (M)-N-C catalysts: catalyst oxidation by radicals and active-site demetallation. The enhanced durability of Co-N-C relative to Fe-N-C is attributed to the lower activity of Co ions for Fenton reactions that produce radicals from the main oxygen reduction reaction by-product, H2O2, and the significantly enhanced resistance to demetallation of Co-N-C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1044, "End Page": 1054, "Article Number": null, "DOI": "10.1038/s41929-020-00546-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00546-1", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000594808400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamiyama, A; Kubota, K; Igarashi, D; Youn, Y; Tateyama, Y; Ando, H; Gotoh, K; Komaba, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamiyama, Azusa; Kubota, Kei; Igarashi, Daisuke; Youn, Yong; Tateyama, Yoshitaka; Ando, Hideka; Gotoh, Kazuma; Komaba, Shinichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MgO-Template Synthesis of Extremely High Capacity Hard Carbon for Na-Ion Battery", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extremely high capacity hard carbon for Na-ion battery, delivering 478 mAh g(-1), is successfully synthesized by heating a freeze-dried mixture of magnesium gluconate and glucose by a MgO-template technique. Influences of synthetic conditions and nullo-structures on electrochemical Na storage properties in the hard carbon are systematically studied to maximize the reversible capacity. nullo-sized MgO particles are formed in a carbon matrix prepared by pre-treatment of the mixture at 600 degrees C. Through acid leaching of MgO and carbonization at 1500 degrees C, resultant hard carbon demonstrates an extraordinarily large reversible capacity of 478 mAh g(-1) with a high Coulombic efficiency of 88 % at the first cycle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 60, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5114, "End Page": 5120, "Article Number": null, "DOI": "10.1002/anie.202013951", "DOI Link": "http://dx.doi.org/10.1002/anie.202013951", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609284600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, HY; Zhang, Y; Guo, LT; Wang, PH; He, X; Dai, GZ; Zheng, HW; Chen, CY; Wang, AC; Xu, C; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Haiyang; Zhang, Ying; Guo, Litong; Wang, Peihong; He, Xu; Dai, Guozhang; Zheng, Haiwu; Chen, Chaoyu; Wang, Aurelia Chi; Xu, Cheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying the triboelectric series", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectrification is a well-known phenomenon that commonly occurs in nature and in our lives at any time and any place. Although each and every material exhibits triboelectrification, its quantification has not been standardized. A triboelectric series has been qualitatively ranked with regards to triboelectric polarization. Here, we introduce a universal standard method to quantify the triboelectric series for a wide range of polymers, establishing quantitative triboelectrification as a fundamental materials property. By measuring the tested materials with a liquid metal in an environment under well-defined conditions, the proposed method standardizes the experimental set up for uniformly quantifying the surface triboelectrification of general materials. The normalized triboelectric charge density is derived to reveal the intrinsic character of polymers for gaining or losing electrons. This quantitative triboelectric series may serve as a textbook standard for implementing the application of triboelectrification for energy harvesting and self-powered sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1082, "Times Cited, All Databases": 1139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1427, "DOI": "10.1038/s41467-019-09461-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09461-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462721900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Guan, XF; Zhou, H; Ramadoss, K; Adam, S; Liu, HJ; Lee, S; Shi, J; Tsuchiya, M; Fong, DD; Ramanathan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, You; Guan, Xiaofei; Zhou, Hua; Ramadoss, Koushik; Adam, Suhare; Liu, Huajun; Lee, Sungsik; Shi, Jian; Tsuchiya, Masaru; Fong, Dillon D.; Ramanathan, Shriram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly correlated perovskite fuel cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fuel cells convert chemical energy directly into electrical energy with high efficiencies and environmental benefits, as compared with traditional heat engines(1-4). Yttria-stabilized zirconia is perhaps the material with the most potential as an electrolyte in solid oxide fuel cells (SOFCs), owing to its stability and near-unity ionic transference number(5). Although there exist materials with superior ionic conductivity, they are often limited by their ability to suppress electronic leakage when exposed to the reducing environment at the fuel interface. Such electronic leakage reduces fuel cell power output and the associated chemo-mechanical stresses can also lead to catastrophic fracture of electrolyte membranes(6). Here we depart from traditional electrolyte design that relies on cation substitution to sustain ionic conduction. Instead, we use a perovskite nickelate as an electrolyte with high initial ionic and electronic conductivity. Since many such oxides are also correlated electron systems, we can suppress the electronic conduction through a filling-controlled Mott transition induced by spontaneous hydrogen incorporation. Using such a nickelate as the electrolyte in free-standing membrane geometry, we demonstrate a low-temperature micro-fabricated SOFC with high performance. The ionic conductivity of the nickelate perovskite is comparable to the best-performing solid electrolytes in the same temperature range, with a very low activation energy. The results present a design strategy for high-performance materials exhibiting emergent properties arising from strong electron correlations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 432, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2016, "Volume": 534, "Issue": 7606, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 231, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature17653", "DOI Link": "http://dx.doi.org/10.1038/nature17653", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377475100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Janabi, N; Hill, P; Torrente-Murciano, L; Garforth, A; Gorgojo, P; Siperstein, F; Fan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Janabi, Nadeen; Hill, Patrick; Torrente-Murciano, Laura; Garforth, Arthur; Gorgojo, Patricia; Siperstein, Flor; Fan, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mapping the Cu-BTC metal-organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu-BTC metal-organic framework (HKUST-1) was evaluated as the model material for CO2 capture from flue gas streams. This paper presents an optimised hydrothermal synthesis of HKUST-1 and an analysis of water stability of HKUST-1. Substantial improvements of the hydrothermal synthesis process of HKUST-1 are shown to increase the quantitative yield up to 89.4% at 100 degrees C. Single-component adsorption experiments were carried out under conditions relevant for flue gases adsorption (45-60 degrees C, 0-1 barG) to evaluate the performance of HKUST-1 in terms of adsorption capacity, showing that the amount adsorbed of water can reach up to 21.7 mmol g(-1), about one order of magnitude higher than CO2 (1.75 mmol g(-1)) and almost two orders of magnitude higher than N-2 (0.17 mmol g(-1)). The hydration process of HKUST-1 framework was investigated using dynamic vapour adsorption under the flue gas emitting conditions. HKUST-1 is sensitive to humid streams and dynamic deformation of its porous structure takes place at 40-50 degrees C and various relative humidity values, leading to the irreversible decomposition of HKUST-1 framework and the consequent deterioration in its adsorption capacity. Under humid conditions, water displaces the organic linkers from the copper centres causing the collapse of HKUST-1 framework. These results provide fundamental knowledge to enable future material design for the modification of the hydrophilic nature of copper sites in HKUST-1 to improve its moisture stability. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2015, "Volume": 281, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 669, "End Page": 677, "Article Number": null, "DOI": "10.1016/j.cej.2015.07.020", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2015.07.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362308200073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, WW; Mochalin, VN; Liu, D; Qin, S; Gogotsi, Y; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Weiwei; Mochalin, Vadym N.; Liu, Dan; Qin, Si; Gogotsi, Yury; Chen, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron nitride colloidal solutions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manufacturing of aerogels and membranes from hexagonal boron nitride (h-BN) is much more difficult than from graphene or graphene oxides because of the poor dispersibility of h-BN in water, which limits its exfoliation and preparation of colloidal solutions. Here, a simple, one-step mechano-chemical process to exfoliate and functionalize h-BN into highly water-dispersible, few-layer h-BN containing amino groups is presented. The colloidal solutions of few-layer h-BN can have unprecedentedly high concentrations, up to 30 mg ml(-1), and are stable for up to several months. They can be used to produce ultralight aerogels with a density of 1.4 mgcm(-3), which is similar to 1,500 times less than bulk h-BN, and freestanding membranes simply by cryodrying and filtration, respectively. The material shows strong blue light emission under ultraviolet excitation, in both dispersed and dry state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 707, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8849, "DOI": "10.1038/ncomms9849", "DOI Link": "http://dx.doi.org/10.1038/ncomms9849", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366295800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, Q; Si, WY; He, JJ; Sun, L; Zhang, CF; Wang, N; Yang, Z; Li, XD; Wang, X; Deng, WQ; Long, YZ; Huang, CS; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Qing; Si, Wenyan; He, Jianjiang; Sun, Lei; Zhang, Chunfang; Wang, Ning; Yang, Ze; Li, Xiaodong; Wang, Xin; Deng, Weiqiao; Long, Yunze; Huang, Changshui; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selectively nitrogen-doped carbon materials as superior metal-free catalysts for oxygen reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Doping with pyridinic nitrogen atoms is known as an effective strategy to improve the activity of carbon-based catalysts for the oxygen reduction reaction. However, pyridinic nitrogen atoms prefer to occupy at the edge or defect sites of carbon materials. Here, a carbon framework named as hydrogen-substituted graphdiyne provides a suitable carbon matrix for pyridinic nitrogen doping. In hydrogen-substituted graphdiyne, three of the carbon atoms in a benzene ring are bonded to hydrogen and serve as active sites, like the edge or defect positions of conventional carbon materials, on which pyridinic nitrogen can be selectively doped. The as-synthesized pyridinic nitrogen-doped hydrogen-substituted graphdiyne shows much better electrocatalytic performance for the oxygen reduction reaction than that of the commercial platinum-based catalyst in alkaline media and comparable activity in acidic media. Density functional theory calculations demonstrate that the pyridinic nitrogen-doped hydrogen-substituted graphdiyne is more effective than pyridinic nitrogen-doped graphene for oxygen reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 524, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3376, "DOI": "10.1038/s41467-018-05878-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05878-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442521500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paluselli, A; Fauvelle, V; Galgani, F; Sempéré, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paluselli, Andrea; Fauvelle, Vincent; Galgani, Francois; Sempere, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phthalate Release from Plastic Fragments and Degradation in Seawater", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic debris in the environment contains plasticizers, such as phthalates (PAEs), that can be released during plastic aging. Here, two common plastic materials, an insulation layer of electric cables (polyvinyl chloride, PVC-cables) and plastic garbage bag (polyethylene, PE-bags), were incubated in natural seawater under laboratory conditions, and the PAE migration to the seawater phase was studied with varying light and bacterial conditions over a 90-day time course. Free PAEs diluted in seawater were also studied for bacterial degradation. Our results showed that, within the first month of incubation, both plastic materials significantly leached out PAEs into the surrounding water. We found that di-isobutyl phthalate (DiBP) and di-n-butyl phthalate (DnBP) were the main PAEs released from the PE-bags, with the highest values of 83.4 +/- 12.5 and 120.1 +/- 18.0 ng g(-1) of plastic, respectively. Furthermore, dimethyl phthalate (DMP) and diethyl phthalate (DEP) were the main PAEs released from PVC-cables, with mass fractions as high as 9.5 +/- 1.4 and 68.9 +/- 10.3 ng g(-1), respectively. Additionally, we found that light and bacterial exposure increased the total amount of PAEs released from PVC-cables by a factor of up to 5, whereas they had no influence in the case of PE-bags.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 53, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 166, "End Page": 175, "Article Number": null, "DOI": "10.1021/acs.est.8b05083", "DOI Link": "http://dx.doi.org/10.1021/acs.est.8b05083", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455076600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, LL; Luo, QQ; Chen, JJ; Wang, L; Lin, Y; Wang, HJ; Liu, XK; Shen, XY; Zhang, W; Liu, W; Qi, ZM; Jiang, Z; Yang, JL; Yao, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Linlin; Luo, Qiquan; Chen, Jiajia; Wang, Lan; Lin, Yue; Wang, Huijuan; Liu, Xiaokang; Shen, Xinyi; Zhang, Wei; Liu, Wei; Qi, Zeming; Jiang, Zheng; Yang, Jinlong; Yao, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving active and stable oxygen evolution reaction (OER) in acid media based on single-atom catalysts is highly promising for cost-effective and sustainable energy supply in proton electrolyte membrane electrolyzers. Here, we report an atomically dispersed Ru-1-N-4 site anchored on nitrogen-carbon support (Ru-N-C) as an efficient and durable electrocatalyst for acidic OER. The single-atom Ru-N-C catalyst delivers an exceptionally intrinsic activity, reaching a mass activity as high as 3571 A g(metal)(-1) and turnover frequency of 3348 O-2 h(-1) with a low overpotential of 267 mV at a current density of 10 mA cm(-2). The catalyst shows no evident deactivation or decomposition after 30-hour operation in acidic environment. Operando synchrotron radiation X-ray absorption spectroscopy and infrared spectroscopy identify the dynamic adsorption of single oxygen atom on Ru site under working potentials, and theoretical calculations demonstrate that the O-Ru-1-N-4 site is responsible for the high OER activity and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 564, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4849, "DOI": "10.1038/s41467-019-12886-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12886-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492140800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YY; Liu, YP; Li, GD; Zou, X; Lian, XR; Wang, DJ; Sun, L; Asefa, T; Zou, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yuanyuan; Liu, Yipu; Li, Guo-Dong; Zou, Xu; Lian, Xinran; Wang, Dejun; Sun, Lei; Asefa, Tewodros; Zou, Xiaoxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient electrocatalysis of overall water splitting by ultrasmall NixCo3-xS4 coupled Ni3S2 nullosheet arrays", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The overall water splitting into hydrogen and oxygen is one of the most promising ways to store intermittent solar and wind energy in the form of chemical fuels. However, this process is quite thermodynamically uphill, and thus needs to be mediated simultaneously by efficient hydrogen evolving and oxygen evolving catalysts to get any feasible output from it. Herein, we report the synthesis of such a catalyst comprising ultrasmall NixCo3-xS4-decorated Ni3S2 nullosheet arrays supported on nickel foam (NF) via a partial cation exchange reaction between NF-supported Ni3S2 nullosheet arrays and cobalt(II) ions. We show that the as-prepared material, denoted as NixCo3-xS4/Ni3S2/NF, can serve as a self-standing, noble metal-free, highly active and stable, bifunctional electrocatalyst for the two half reactions involved in the overall water splitting: the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Furthermore, we demonstrate that a high-performance electrolyzer for the overall water splitting reaction can be assembled by using NixCo3-xS4/Ni3S2/NF as the electrocatalyst at both the cathode and the anode sides of the electrolyzer. This electrolyzer delivers water-splitting current densities of 10 and 100 mA/cm(2) at applied potentials of 1.53 and 1.80 V, respectively, with remarkable stability for >200 h in both cases. The electrolyzer's performance is much better than the performances of electrolyzers assembled from many types of other bifunctional electrocatalysts as catalyst couple. Moreover, the overall performance of the electrolyzer is comparable with the performances of electrolyzers containing two different, benchmark, monofunctional HER and OER electrocatalyst couple (i.e., Pt/C-IrO2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 35, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 161, "End Page": 170, "Article Number": null, "DOI": "10.1016/j.nulloen.2017.03.024", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2017.03.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400647900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lan, K; Liu, Y; Zhang, W; Liu, Y; Elzatahry, A; Wang, RC; Xia, YY; Al-Dhayan, D; Zheng, NF; Zhao, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lan, Kun; Liu, Yao; Zhang, Wei; Liu, Yong; Elzatahry, Ahmed; Wang, Ruicong; Xia, Yongyao; Al-Dhayan, Dhaifallah; Zheng, nullfeng; Zhao, Dongyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uniform Ordered Two-Dimensional Mesoporous TiO2 nullosheets from Hydrothermal-Induced Solvent-Confined Monomicelle Assembly", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) nullomaterials have been the focus of substantial research interest recently owing to their fascinating and excellent properties. However, 2D porous materials have remained quite rare due to the difficulty of creating pores in 2D nullostructures. Here, we have synthesized a novel type of single-layered 2D mesoporous TiO2 nullosheets with very uniform size and thickness as well as ordered mesostructure from an unprecedented hydrothermal-induced solvent-confined assembly approach. The F127/TiO2 spherical monomicelles are first formed and redispersed in ethanol and glycerol, followed by a hydrothermal treatment to assemble these subunits into single layered 2D mesostructure owing to the confinement effect of highly adhered glycerol solvent. The obtained 2D mesoporous TiO2 nullosheets have a relative mean size at around 500 x 500 nm and can be randomly stacked into a bulk. The TiO2 nullosheets possess only one layer of ordered mesopores with a pore size of 4.0 nm, a very high surface area of 210 m(2) g(-1) and a uniform thickness of 5.5 nm. The thickness can be further manipulated from 5.5 to 27.6 nm via simply tuning precursor concentration or solvent ratio. Due to the well-defined 2D morphology and large mesoporosity as well as crystalline anatase mesopore walls, these uniform TiO2 nullosheets are capable of providing large accessible voids for sodium ion adsorption and intercalation as well as preventing volume expansion. As expected, these mesoporous TiO2 nullosheets have exhibited an excellent reversible capacity of 220 mAh g(-1) at 100 mA g(-1) as sodium-ion battery anodes, and they can retain at 199 mAh g(-1) after numerous cycles at different current densities. The capacity is retained at 44 mAh g(-1) even at a large current density of 10 A g(-1) after 10 000 cycles, demonstrating a remarkable performance for energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2018, "Volume": 140, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4135, "End Page": 4143, "Article Number": null, "DOI": "10.1021/jacs.8b00909", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b00909", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428356000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, K; Chen, ZS; Yu, JH; Zeng, HZ; Wu, J; Wu, ZX; Jia, QY; Li, P; Fu, YQ; Chang, HL; Yuan, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Kai; Chen, Zhensheng; Yu, Jiahao; Zeng, Haozhe; Wu, Jin; Wu, Zixuan; Jia, Qingyan; Li, Peng; Fu, Yongqing; Chang, Honglong; Yuan, Weizheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-Sensitive, Deformable, and Transparent Triboelectric Tactile Sensor Based on Micro-Pyramid Patterned Ionic Hydrogel for Interactive Human-Machine Interfaces", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid advances in wearable electronics and mechno-sensational human-machine interfaces impose great challenges in developing flexible and deformable tactile sensors with high efficiency, ultra-sensitivity, environment-tolerance, and self-sustainability. Herein, a tactile hydrogel sensor (THS) based on micro-pyramid-patterned double-network (DN) ionic organohydrogels to detect subtle pressure changes by measuring the variations of triboelectric output signal without an external power supply is reported. By the first time of pyramidal-patterned hydrogel fabrication method and laminated polydimethylsiloxane (PDMS) encapsulation process, the self-powered THS shows the advantages of remarkable flexibility, good transparency (approximate to 85%), and excellent sensing performance, including extraordinary sensitivity (45.97 mV Pa-1), fast response (approximate to 20 ms), very low limit of detection (50 Pa) as well as good stability (36 000 cycles). Moreover, with the LiBr immersion treatment method, the THS possesses excellent long-term hyper anti-freezing and anti-dehydrating properties, broad environmental tolerance (-20 to 60 degrees C), and instantaneous peak power density of 20 mu W cm(-2), providing reliable contact outputs with different materials and detecting very slight human motions. By integrating the signal acquisition/process circuit, the THS with excellent self-power sensing ability is utilized as a switching button to control electric appliances and robotic hands by simulating human finger gestures, offering its great potentials for wearable and multi-functional electronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104168, "DOI": "10.1002/advs.202104168", "DOI Link": "http://dx.doi.org/10.1002/advs.202104168", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748514200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HJ; Huang, JQ; Zhao, MQ; Zhang, Q; Cheng, XB; Liu, XY; Qian, WZ; Wei, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Hong-Jie; Huang, Jia-Qi; Zhao, Meng-Qiang; Zhang, Qiang; Cheng, Xin-Bing; Liu, Xin-Yan; Qian, Wei-Zhong; Wei, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloarchitectured Graphene/CNT@Porous Carbon with Extraordinary Electrical Conductivity and Interconnected Micro/Mesopores for Lithium- Sulfur Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sp(2)-hybridizednullocarbon (e.g., carbon nullotubes (CNTs) and graphene) exhibits extraordinary mechanical strength and electrical conductivity but limited external accessible surface area and a small amount of pores, while nullostructured porous carbon affords a huge surface area and abundant pore structures but very poor electrical conductance. Herein the rational hybridization of the sp(2) nullocarbon and nullostructured porous carbon into hierarchical all-carbon nulloarchitectures is demonstrated, with full inherited advantages of the component materials. The sp(2) graphene/CNT interlinked networks give the composites good electrical conductivity and a robust framework, while the meso-/microporous carbon and the interlamellar compartment between the opposite graphene accommodate sulfur and polysulfides. The strong confinement induced by micro-/mesopores of all-carbon nulloarchitectures renders the transformation of S 8 crystal into amorphous cyclo-S-8 molecular clusters, restraining the shuttle phenomenon for high capacity retention of a lithium-sulfur cell. Therefore, the composite cathode with an ultrahigh specific capacity of 1121 mAh g(-1) at 0.5 C, a favorable high-rate capability of 809 mAh g(-1) at 10 C, a very low capacity decay of 0.12% per cycle, and an impressive cycling stability of 877 mAh g(-1) after 150 cycles at 1 C. As sulfur loading increases from 50 wt% to 77 wt%, high capacities of 970, 914, and 613 mAh g(-1) are still available at current densities of 0.5, 1, and 5 C, respectively. Based on the total mass of packaged devices, gravimetric energy density of GSH@APC-S//Li cell is expected to be 400 Wh kg(-1) at a power density of 10 000 W kg(-1), matching the level of engine driven systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 509, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 24, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2772, "End Page": 2781, "Article Number": null, "DOI": "10.1002/adfm.201303296", "DOI Link": "http://dx.doi.org/10.1002/adfm.201303296", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336248400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YJ; Ji, SF; Zhao, S; Chen, WX; Dong, JC; Cheong, WC; Shen, RA; Wen, XD; Zheng, LR; Rykov, AI; Cai, SC; Tang, HL; Zhuang, ZB; Chen, C; Peng, Q; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuanjun; Ji, Shufang; Zhao, Shu; Chen, Wenxing; Dong, Juncai; Cheong, Weng-Chon; Shen, Rongan; Wen, Xiaodong; Zheng, Lirong; Rykov, Alexandre I.; Cai, Shichang; Tang, Haolin; Zhuang, Zhongbin; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient, durable and inexpensive electrocatalysts that accelerate sluggish oxygen reduction reaction kinetics and achieve high-performance are highly desirable. Here we develop a strategy to fabricate a catalyst comprised of single iron atomic sites supported on a nitrogen, phosphorus and sulfur co-doped hollow carbon polyhedron from a metal-organic framework@polymer composite. The polymer-based coating facilitates the construction of a hollow structure via the Kirkendall effect and electronic modulation of an active metal center by long-range interaction with sulfur and phosphorus. Benefiting from structure functionalities and electronic control of a single-atom iron active center, the catalyst shows a remarkable performance with enhanced kinetics and activity for oxygen reduction in both alkaline and acid media. Moreover, the catalyst shows promise for substitution of expensive platinum to drive the cathodic oxygen reduction reaction in zinc-air batteries and hydrogenair fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 747, "Times Cited, All Databases": 774, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5422, "DOI": "10.1038/s41467-018-07850-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07850-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454137600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, JK; Shang, TY; Ren, LL; Yao, YM; Zhang, T; Xie, JQ; Zhang, BT; Zeng, XL; Sun, R; Xu, JB; Wong, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Jiake; Shang, Tianyu; Ren, Linlin; Yao, Yimin; Zhang, Tao; Xie, Jinqi; Zhang, Baotan; Zeng, Xiaoliang; Sun, Rong; Xu, Jian-Bin; Wong, Ching-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Through-plane assembly of carbon fibers into 3D skeleton achieving enhanced thermal conductivity of a thermal interface material", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal management has become one of the most important issues for electronic devices due to the continual increase in power density and consumption. Thermal interface materials (TIMs), applied between heat sources and heat sinks, are essential ingredients of thermal management. Carbon fibers are promising fillers because of its numerous advantages including high thermal conductivity, high strength-to-weight ratio, desired fatigue resistance, and corrosion resistance. However, they are rarely considered in preparing TIMs at present, because the one-dimensional structure of carbon fibers largely enhance the viscosity of the composites using conventional methods, and thus increase the complexity of processing. Herein, we report a thermally conducive TIM based on the construction of three dimensional and vertically aligned carbon fibers (3D-CFs) skeleton. The 3D-CFs skeleton is fabricated by vertical freezing the solution of CFs followed by freeze-dying to remove the ice and then infiltrating them with epoxy resin matrix. At a relatively low CFs loading of 13.0 vol%, the composites show an enhanced through-plane thermal conductivity (2.84 W m(-1) K-1) compared to that of a neat epoxy resin (0.19 W m(-1) K-1). Theoretical models qualitatively demonstrate that the interfacial thermal resistance is mainly originated from CFs-CFs interface not CFs-epoxy interface in oriented CFs/epoxy composites. In addition, the composites also possess a low thermal expansion coefficient (CTE) of 23.63 ppm K-1 , and an increased glass transition temperature of 222.8 degrees C at a relatively small CFs loading (13.0 vol%) compared to that of pure epoxy resin. Our fabrication of through-plane assembly of carbon fibers skeleton has broad application prospects in TIMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2020, "Volume": 380, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 122550, "DOI": "10.1016/j.cej.2019.122550", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.122550", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494815600124", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amat, A; Mosconi, E; Ronca, E; Quarti, C; Umari, P; Nazeeruddin, MK; Grätzel, M; De Angelis, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amat, Anna; Mosconi, Edoardo; Ronca, Enrico; Quarti, Claudio; Umari, Paolo; Nazeeruddin, Md. K.; Graetzel, Michael; De Angelis, Filippo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin-Orbit Coupling and Octahedra Tilting", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organohalide lead perovskites have revolutionized the scenario of emerging photovoltaic technologies. The prototype MAPbI(3) perovskite (MA = CH3NH3+) has dominated the field, despite only harvesting photons above 750 nm (similar to 1.6 eV). Intensive research efforts are being devoted to find new perovskites with red-shifted absorption onset, along with good charge transport properties. Recently, a new perovskite based on the formamidinium cation ((NH2)(2)CH+ = FA) has shown potentially superior properties in terms of band gap and charge transport compared to MAPbI(3). The results have been interpreted in terms of the cation size, with the larger FA cation expectedly delivering reduced band-gaps in Pb-based perovskites. To provide a full understanding of the interplay among size, structure, and organic/inorganic interactions in determining the properties of APbI(3) perovskites, in view of designing new materials and fully exploiting them for solar cells applications, we report a fully first-principles investigation on APbI(3) perovskites with A = Cs+, MA, and FA. Our results evidence that the tetragonal-to-quasi cubic structural evolution observed when moving from MA to FA is due to the interplay of size effects and enhanced hydrogen bonding between the FA cations and the inorganic matrix altering the covalent/ionic character of Pb-I bonds. Most notably, the observed cation-induced structural variability promotes markedly different electronic and optical properties in the MAPbI(3) and FAPbI(3) perovskites, mediated by the different spin-orbit coupling, leading to improved charge transport and red-shifted absorption in FAPbI(3) and in general in pseudocubic structures. Our theoretical model constitutes the basis for the rationale design of new and more efficient organohalide perovskites for solar cells applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3608, "End Page": 3616, "Article Number": null, "DOI": "10.1021/nl5012992", "DOI Link": "http://dx.doi.org/10.1021/nl5012992", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, ZW; Karan, S; Livingston, AG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Zhiwei; Karan, Santanu; Livingston, Andrew G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water Transport through Ultrathin Polyamide nullofilms Used for Reverse Osmosis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thin-film composite membranes comprising a polyamide nullofilm separating layer on a support material are state of the art for desalination by reverse osmosis. nullofilm thickness is thought to determine the rate of water transport through the membranes; although due to the fast and relatively uncontrolled interfacial polymerization reaction employed to form these nullofilms, they are typically crumpled and the separating layer is reported to be approximate to 50-200 nm thick. This crumpled structure has confounded exploration of the independent effects of thickness, permeation mechanism, and the support material. Herein, smooth sub-8 nm polyamide nullofilms are fabricated at a free aqueous-organic interface, exhibiting chemical homogeneity at both aqueous and organic facing surfaces. Transfer of these ultrathin nullofilms onto porous supports provides fast water transport through the resulting nullofilm composite membranes. Manipulating the intrinsic nullofilm thickness from approximate to 15 down to 8 nm reveals that water permeance increases proportionally with the thickness decrease, after which it increases nonlinearly to 2.7 L m(-2) h(-1) bar(-1) as the thickness is further reduced to approximate to 6 nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2018, "Volume": 30, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705973, "DOI": "10.1002/adma.201705973", "DOI Link": "http://dx.doi.org/10.1002/adma.201705973", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430101200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, T; Sang, XH; Unocic, RR; Kinch, RT; Liu, XF; Hu, J; Liu, HL; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Tian; Sang, Xiahan; Unocic, Raymond R.; Kinch, Richard T.; Liu, Xiaofei; Hu, Jun; Liu, Honglai; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanochemical-Assisted Synthesis of High-Entropy Metal Nitride via a Soft Urea Strategy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystalline high-entropy ceramics (CHC), a new class of solids that contain five or more elemental species, have attracted increasing interest because of their unique structure and potential applications. Up to now, only a couple of CHCs (e.g., high-entropy metal oxides and diborides) have been successfully synthesized. Here, a new strategy for preparing high-entropy metal nitride (HEMN-1) is proposed via a soft urea method assisted by mechanochemical synthesis. The as-prepared HEMN-1 possesses five highly dispersed metal components, including V, Cr, Nb, Mo, Zr, and simultaneously exhibits an interesting cubic crystal structure of metal nitrides. By taking advantage of these unique features, HEMN-1 can function as a promising candidate for supercapacitor applications. A specific capacitance of 78 F g(-1) is achieved at a scan rate of 100 mV s(-1) in 1 M KOH. In addition, such a facile synthetic strategy can be further extended to the fabrication of other types of HEMNs, paving the way for the synthesis of HEMNs with attractive properties for task-specific applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2018, "Volume": 30, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1707512, "DOI": "10.1002/adma.201707512", "DOI Link": "http://dx.doi.org/10.1002/adma.201707512", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434036000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hod, O; Meyer, E; Zheng, QS; Urbakh, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hod, Oded; Meyer, Ernst; Zheng, Quanshui; Urbakh, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural superlubricity and ultralow friction across the length scales", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structural superlubricity, a state of ultralow friction and wear between crystalline surfaces, is a fundamental phenomenon in modern tribology that defines a new approach to lubrication. Early measurements involved nullometre-scale contacts between layered materials, but recent experimental advances have extended its applicability to the micrometre scale. This is an important step towards practical utilization of structural superlubricity in future technological applications, such as durable nullo- and micro-electromechanical devices, hard drives, mobile frictionless connectors, and mechanical bearings operating under extreme conditions. Here we provide an overview of the field, including its birth and main achievements, the current state of the art and the challenges to fulfilling its potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2018, "Volume": 563, "Issue": 7732, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 485, "End Page": 492, "Article Number": null, "DOI": "10.1038/s41586-018-0704-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0704-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450960000041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Sun, SN; Yang, HT; Xi, SB; Gracia, J; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yuanmiao; Sun, Shengnull; Yang, Haitao; Xi, Shibo; Gracia, Jose; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-Related Electron Transfer and Orbital Interactions in Oxygen Electrocatalysis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution and reduction reactions play a critical role in determining the efficiency of the water cycling (H2O & x21d4; H-2+12O(2)), in which the hydrogen serves as the energy carrier. That calls for a comprehensive understanding of oxygen electrocatalysis for efficient catalyst design. Current opinions on oxygen electrocatalysis have been focused on the thermodynamics of the reactant/intermediate adsorption on the catalysts. Because the oxygen molecule is paramagnetic, its production from or its reduction to diamagnetic hydroxide/water involves spin-related electron transfer. Both electron transfer and orbital interactions between the catalyst and the reactant/intermediate show spin-dependent character, making the reaction kinetics and thermodynamics sensitive to the spin configurations. Herein, a brief introduction on the spintronic explanation of the catalytic phenomena on oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is given. The local spin configurations and orbital interactions in the benchmark transition-metal-based catalysts for OER and ORR are analyzed as examples. To further understand the spintronic oxygen electrocatalysis and to develop more efficient spintronic catalysts, the challenges are summarized and future opportunities proposed. Spin electrocatalysis may emerge as an important topic in the near future and help integrate a comprehensive understanding of oxygen electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 32, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003297, "DOI": "10.1002/adma.202003297", "DOI Link": "http://dx.doi.org/10.1002/adma.202003297", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000557379700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZL; Bai, Y; Liu, X; Chueh, CC; Yang, SH; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zonglong; Bai, Yang; Liu, Xiao; Chueh, Chu-Chen; Yang, Shihe; Jen, Alex K. -Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Efficiency and Stability of Inverted Perovskite Solar Cells Using Highly Crystalline SnO2 nullocrystals as the Robust Electron-Transporting Layer", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly crystalline SnO2 is demonstrated to serve as a stable and robust electron-transporting layer for high-performance perovskite solar cells. Benefiting from its high crystallinity, the relatively thick SnO2 electron-transporting layer (approximate to 120 nm) provides a respectable electron-transporting property to yield a promising power conversion efficiency (PCE)(18.8%) Over 90% of the initial PCE can be retained after 30 d storage in ambient with approximate to 70% relative humidity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2016, "Volume": 28, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6478, "End Page": 6484, "Article Number": null, "DOI": "10.1002/adma.201600619", "DOI Link": "http://dx.doi.org/10.1002/adma.201600619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382480100025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, L; Zhang, Y; Huang, LB; Liu, XZ; Zhang, QH; He, C; Wu, ZY; Zhang, LJ; Wu, JP; Yang, WL; Gu, L; Hu, JS; Wan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lu; Zhang, Yun; Huang, Lin-Bo; Liu, Xiao-Zhi; Zhang, Qing-Hua; He, Chao; Wu, Ze-Yuan; Zhang, Lin-Juan; Wu, Jinpeng; Yang, Wanli; Gu, Lin; Hu, Jin-Song; Wan, Li-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although single-atomically dispersed metal-N-x on carbon support (M-NC) has great potential in heterogeneous catalysis, the scalable synthesis of such single-atom catalysts (SACs) with high-loading metal-Nx is greatly challenging since the loading and single-atomic dispersion have to be balanced at high temperature for forming metal-Nx. Herein, we develop a general cascade anchoring strategy for the mass production of a series of M-NC SACs with a metal loading up to 12.1 wt%. Systematic investigation reveals that the chelation of metal ions, physical isolation of chelate complex upon high loading, and the binding with N-species at elevated temperature are essential to achieving high-loading M-NC SACs. As a demonstration, high-loading Fe-NC SAC shows superior electrocatalytic performance for O-2 reduction and Ni-NC SAC exhibits high electrocatalytic activity for CO2 reduction. The strategy paves a universal way to produce stable M-NC SAC with high-density metal-N-x sites for diverse high-performance applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 713, "Times Cited, All Databases": 736, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1278, "DOI": "10.1038/s41467-019-09290-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09290-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461757800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Luna, P; Quintero-Bermudez, R; Dinh, CT; Ross, MB; Bushuyev, OS; Todorovic, P; Regier, T; Kelley, SO; Yang, PD; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Luna, Phil; Quintero-Bermudez, Rafael; Cao-Thang Dinh; Ross, Michael B.; Bushuyev, Oleksandr S.; Todorovic, Petar; Regier, Tom; Kelley, Shana O.; Yang, Peidong; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reduction of carbon dioxide to renewable fuels and feedstocks offers opportunities for large-scale, long-term energy storage. The synthesis of efficient CO2 reduction electrocatalysts with high C2:C1 selectivity remains a field of intense interest. Here we present electro-redeposition, the dissolution and redeposition of copper from a sol-gel, to enhance copper catalysts in terms of their morphology, oxidation state and consequent performance. We utilized in situ soft X-ray absorption spectroscopy to track the oxidation state of copper under CO2 reduction conditions with time resolution. The sol-gel material slows the electrochemical reduction of copper, enabling control over nulloscale morphology and the stabilization of Cu+ at negative potentials. CO2 reduction experiments, in situ X-ray spectroscopy and density functional theory simulations revealed the beneficial interplay between sharp morphologies and Cu+ oxidation state. The catalyst exhibits a partial ethylene current density of 160 mA cm(-2) (-1.0 V versus reversible hydrogen electrode) and an ethylene/methane ratio of 200.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 799, "Times Cited, All Databases": 839, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": 110, "Article Number": null, "DOI": "10.1038/s41929-017-0018-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0018-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428621500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Tian, HZ; Jin, Y; Tao, XY; Liu, BF; Zhang, RF; Seh, ZW; Zhuo, D; Liu, YY; Sun, J; Zhao, J; Zu, CX; Wu, DS; Zhang, QF; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Tian, Hongzhen; Jin, Yang; Tao, Xinyong; Liu, Bofei; Zhang, Rufan; Seh, Zhi Wei; Zhuo, Denys; Liu, Yayuan; Sun, Jie; Zhao, Jie; Zu, Chenxi; Wu, David Sichen; Zhang, Qianfan; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic oxidation of Li2S on the surface of metal sulfides for Li-S batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polysulfide binding and trapping to prevent dissolution into the electrolyte by a variety of materials has been well studied in Li-S batteries. Here we discover that some of those materials can play an important role as an activation catalyst to facilitate oxidation of the discharge product, Li2S, back to the charge product, sulfur. Combining theoretical calculations and experimental design, we select a series of metal sulfides as a model system to identify the key parameters in determining the energy barrier for Li2S oxidation and polysulfide adsorption. We demonstrate that the Li2S decomposition energy barrier is associated with the binding between isolated Li ions and the sulfur in sulfides; this is the main reason that sulfide materials can induce lower overpotential compared with commonly used carbon materials. Fundamental understanding of this reaction process is a crucial step toward rational design and screening of materials to achieve high reversible capacity and long cycle life in Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1097, "Times Cited, All Databases": 1149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2017, "Volume": 114, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 840, "End Page": 845, "Article Number": null, "DOI": "10.1073/pnas.1615837114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1615837114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393196300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ke, YJ; Zhou, CZ; Zhou, Y; Wang, SC; Chan, SH; Long, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ke, Yujie; Zhou, Chengzhi; Zhou, Yang; Wang, Shancheng; Chan, Siew Hwa; Long, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging Thermal-Responsive Materials and Integrated Techniques Targeting the Energy-Efficient Smart Window Application", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Architectural windows that smartly regulate indoor solar radiation by changing their optical transmittance in response to thermostimuli are developed as a promising solution toward reducing the energy consumption of buildings. Recently, energy-efficient smart window technology has attracted increasing scientific interest, with the exploration of energy-efficient novel materials as well as integration with practical techniques to generate various desired multifunctionalities. This review systematically summarizes emerging thermoresponsive materials for smart window applications, including hydrogels, ionic liquids, perovskites, metamaterials, and liquid crystals. These are compared with vanadium dioxide (VO2), a conventional and extensively studied material for thermochromic smart window applications. In addition, recent progress on cutting-edge integrated techniques for smart windows is covered, including electrothermal techniques, self-cleaning, wettability, and also integration with solar cells for bifunctional energy conservation and generation. Finally, opportunities and challenges relating to thermochromic smart windows and prospects for future development are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2018, "Volume": 28, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800113, "DOI": "10.1002/adfm.201800113", "DOI Link": "http://dx.doi.org/10.1002/adfm.201800113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434030800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CZ; Zhang, XQ; Cheng, XB; Zhang, R; Xu, R; Chen, PY; Peng, HJ; Huang, JQ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing; Zhang, Rui; Xu, Rui; Chen, Peng-Yu; Peng, Hong-Jie; Huang, Jia-Qi; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is strongly regarded as a promising electrode material in next-generation rechargeable batteries due to its extremely high theoretical specific capacity and lowest reduction potential. However, the safety issue and short lifespan induced by uncontrolled dendrite growth have hindered the practical applications of lithium metal anodes. Hence, we propose a flexible anion-immobilized ceramic-polymer composite electrolyte to inhibit lithium dendrites and construct safe batteries. Anions in the composite electrolyte are tethered by a polymer matrix and ceramic fillers, inducing a uniform distribution of space charges and lithium ions that contributes to a dendrite-free lithium deposition. The dissociation of anions and lithium ions also helps to reduce the polymer crystallinity, rendering stable and fast transportation of lithium ions. Ceramic fillers in the electrolyte extend the electrochemically stable window to as wide as 5.5 V and provide a barrier to short circuiting for realizing safe batteries at elevated temperature. The anion-immobilized electrolyte can be applied in all-solid-state batteries and exhibits a small polarization of 15 mV. Cooperated with LiFePO4 and LiNi0.5Co0.2Mn0.3O2 cathodes, the all-solid-state lithium metal batteries render excellent specific capacities of above 150 mAh.g(-1) and well withstand mechanical bending. These results reveal a promising opportunity for safe and flexible next-generation lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 744, "Times Cited, All Databases": 796, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2017, "Volume": 114, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11069, "End Page": 11074, "Article Number": null, "DOI": "10.1073/pnas.1708489114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1708489114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413237900037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Lu, SB; Zheng, J; Du, J; Wen, SC; Tang, DY; Loh, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, H.; Lu, S. B.; Zheng, J.; Du, J.; Wen, S. C.; Tang, D. Y.; Loh, K. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molybdenum disulfide (MoS2) as a broadband saturable absorber for ultra-fast photonics", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The nonlinear optical property of few-layered MoS2 nulloplatelets synthesized by the hydrothermal exfoliation method was investigated from the visible to the near-infrared band using lasers. Both open-aperture Z-scan and balanced-detector measurement techniques were used to demonstrate the broadband saturable absorption property of few-layered MoS2. To explore its potential applications in ultrafast photonics, we fabricated a passive mode locker for ytterbium-doped fibre laser by depositing few-layered MoS2 onto the end facet of optical fiber by means of an optical trapping approach. Our laser experiment shows that few-layer MoS2-based mode locker allows for the generation of stable mode-locked laser pulse, centered at 1054.3 nm, with a 3-dB spectral bandwidth of 2.7 nm and a pulse duration of 800 ps. Our finding suggests that few-layered MoS2 nulloplatelets can be useful nonlinear optical material for laser photonics devices, such as passive laser mode locker, Q-switcher, optical limiter, optical switcher and so on. (C) 2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1028, "Times Cited, All Databases": 1087, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2014, "Volume": 22, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7249, "End Page": 7260, "Article Number": null, "DOI": "10.1364/OE.22.007249", "DOI Link": "http://dx.doi.org/10.1364/OE.22.007249", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333579300104", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZN; Gadipelli, S; Li, HC; Howard, CA; Brett, DJL; Shearing, PR; Guo, ZX; Parkin, IP; Li, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhuangnull; Gadipelli, Srinivas; Li, Hucheng; Howard, Christopher A.; Brett, Dan J. L.; Shearing, Paul R.; Guo, Zhengxiao; Parkin, Ivan P.; Li, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the interlayer spacing of graphene laminate films for efficient pore utilization towards compact capacitive energy storage", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The volumetric performance of supercapacitors needs to be improved, but the usual trade-off between porosity and density is a problem. Here the authors develop a graphene laminate film with tunable porosity that leads to a volumetric energy density of 88.1 Wh l(-1) at the device level. Supercapacitors have shown extraordinary promise for miniaturized electronics and electric vehicles, but are usually limited by electrodes with rather low volumetric performance, which is largely due to the inefficient utilization of pores in charge storage. Herein, we design a freestanding graphene laminate film electrode with highly efficient pore utilization for compact capacitive energy storage. The interlayer spacing of this film can be precisely adjusted, which enables a tunable porosity. By systematically tailoring the pore size for the electrolyte ions, pores are utilized optimally and thereby the volumetric capacitance is maximized. Consequently, the fabricated supercapacitor delivers a stack volumetric energy density of 88.1 Wh l(-1) in an ionic liquid electrolyte, representing a critical breakthrough for optimizing the porosity towards compact energy storage. Moreover, the optimized film electrode is assembled into an ionogel-based, all-solid-state, flexible smart device with multiple optional outputs and superior stability, demonstrating enormous potential as a portable power supply in practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 160, "End Page": 168, "Article Number": null, "DOI": "10.1038/s41560-020-0560-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0560-6", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514052800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, N; Wang, Y; Yang, H; Deng, J; Wu, JH; Li, YF; Li, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Na; Wang, Yu; Yang, Hui; Deng, Jun; Wu, Jinghua; Li, Yafei; Li, Yanguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin bismuth nullosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic carbon dioxide reduction to formate is desirable but challenging. Current attention is mostly focused on tin-based materials, which, unfortunately, often suffer from limited Faradaic efficiency. The potential of bismuth in carbon dioxide reduction has been suggested but remained understudied. Here, we report that ultrathin bismuth nullosheets are prepared from the in situ topotactic transformation of bismuth oxyiodide nullosheets. They process single crystallinity and enlarged surface areas. Such an advantageous nullostructure affords the material with excellent electrocatalytic performance for carbon dioxide reduction to formate. High selectivity (similar to 100%) and large current density are measured over a broad potential, as well as excellent durability for >10 h. Its selectivity for formate is also understood by density functional theory calculations. In addition, bismuth nullosheets were coupled with an iridium-based oxygen evolution electrocatalyst to achieve efficient full-cell electrolysis. When powered by two AA-size alkaline batteries, the full cell exhibits impressive Faradaic efficiency and electricity-to-formate conversion efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 750, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1320, "DOI": "10.1038/s41467-018-03712-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03712-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429004500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, XL; Luo, JM; null, HX; Zou, HB; Chen, R; Shu, T; Li, XH; Li, YW; Song, HY; Liao, SJ; Adzic, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Xinlong; Luo, Junming; null, Haoxiong; Zou, Haobin; Chen, Rong; Shu, Ting; Li, Xiuhua; Li, Yingwei; Song, Huiyu; Liao, Shijun; Adzic, Radoslav R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition Metal Nitride Coated with Atomic Layers of Pt as a Low-Cost, Highly Stable Electrocatalyst for the Oxygen Reduction Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The main challenges to the commercial viability of polymer electrolyte membrane fuel cells are (i) the high cost associated with using large amounts of Pt in fuel cell cathodes to compensate for the sluggish kinetics of the oxygen reduction reaction, (ii) catalyst degradation, and (iii) carbon-support corrosion. To address these obstacles, our group has focused on robust, carbon-free transition metal nitride materials with low Pt content that exhibit tunable physical and catalytic properties. Here, we report on the high performance of a novel catalyst with low Pt content, prepared by placing several layers of Pt atoms on nulloparticles of titanium nickel binary nitride. For the ORR, the catalyst exhibited a more than 400% and 200% increase in mass activity and specific activity, respectively, compared with the commercial Pt/C catalyst. It also showed excellent stability/durability, experiencing only a slight performance loss after 10 000 potential cycles, while TEM results showed its structure had remained intact. The catalyst's outstanding performance may have resulted from the ultrahigh dispersion of Pt (several atomic layers coated on the nitride nulloparticles), and the excellent stability/durability may have been due to the good stability of nitride and synergetic effects between ultrathin Pt layer and the robust TiNiN support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2016, "Volume": 138, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1575, "End Page": 1583, "Article Number": null, "DOI": "10.1021/jacs.5b11364", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11364", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370215400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, BW; Heo, S; Ji, S; Bien, F; Park, JU", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Byeong Wan; Heo, Sanghyun; Ji, Sangyoon; Bien, Franklin; Park, Jang-Ung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent and flexible fingerprint sensor array with multiplexed detection of tactile pressure and skin temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We developed a transparent and flexible, capacitive fingerprint sensor array with multiplexed, simultaneous detection of tactile pressure and finger skin temperature for mobile smart devices. In our approach, networks of hybrid nullostructures using ultra-long metal nullofibers and finer nullowires were formed as transparent, flexible electrodes of a multifunctional sensor array. These sensors exhibited excellent optoelectronic properties and outstanding reliability against mechanical bending. This fingerprint sensor array has a high resolution with good transparency. This sensor offers a capacitance variation similar to 17 times better than the variation for the same sensor pattern using conventional ITO electrodes. This sensor with the hybrid electrode also operates at high frequencies with negligible degradation in its performance against various noise signals from mobile devices. Furthermore, this fingerprint sensor array can be integrated with all transparent forms of tactile pressure sensors and skin temperature sensors, to enable the detection of a finger pressing on the display.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2458, "DOI": "10.1038/s41467-018-04906-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04906-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437101200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, MK; Shuck, CE; Rakhmanov, R; Parchment, D; Anasori, B; Koo, CM; Friedman, G; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Meikang; Shuck, Christopher Eugene; Rakhmanov, Roman; Parchment, David; Anasori, Babak; Koo, Chong Min; Friedman, Gary; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beyond Ti3C2Tx: MXenes for Electromagnetic Interference Shielding", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New ultrathin and multifunctional electromagnetic interference (EMI) shielding materials are required for protecting electronics against electromagnetic pollution in the fifth-generation networks and Internet of Things era. Micrometer-thin Ti3C2Tx MXene films have shown the best EMI shielding performance among synthetic materials so far. Yet, the effects of elemental composition, layer structure, and transition-metal arrangement on EMI shielding properties of MXenes have not been explored, despite the fact that more than 30 different MXenes have been reported, and many more are possible. Here, we report on a systematic study of EMI shielding properties of 16 different MXenes, which cover singlemetal MXenes, ordered double-metal carbide MXenes, and random solid solution MXenes of M and X elements. This is the largest set of MXene compositions ever reported in a comparative study. Films with thicknesses ranging from nullometers to micrometers were produced by spin-casting, spraycoating, and vacuum-assisted filtration. All MXenes achieved effective EMI shielding (>20 dB) in micrometer-thick films The EMI shielding effectiveness of sprayed Ti3C2Tx film with a thickness of only , similar to 40 nm reaches 21 dB. Adjustable EMI shielding properties were achieved in solid solution MXenes with different ratios of elements. A transfer matrix model was shown to fit EMI shielding data for highly conductive MXenes but could not describe the behavior of materials with low conductivity. This work shows that many members of the large MXene family can be used for EMI shielding, contributing to designing ultrathin, flexible, and multifunctional EMI shielding films benefiting from specific characteristics of individual MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2020, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5008, "End Page": 5016, "Article Number": null, "DOI": "10.1021/acsnullo.0c01312", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c01312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529895500116", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LH; Han, LL; Liu, HX; Liu, XJ; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lihan; Han, Lili; Liu, Haoxuan; Liu, Xijun; Luo, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potential-Cycling Synthesis of Single Platinum Atoms for Efficient Hydrogen Evolution in Neutral Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have exhibited high activities for the hydrogen evolution reaction (HER) electrocatalysis in acidic or alkaline media, when they are used with binders on cathodes. However, to date, no SACs have been reported for the HER electrocatalysis in neutral media. We demonstrate a potential-cycling method to synthesize a catalyst comprising single Pt atoms on CoP-based nullotube arrays supported bya Ni foam, termed PtSA-NT-NF. This binder-free catalyst is centimeter-scale and scalable. It is directly used as HER cathodes, whose performances at low and high current densities in phosphate buffer solutions (pH 7.2) are comparable to and better than, respectively, those of commercial Pt/C. The Pt mass activity of PtSA-NT-NF is 4 times of that of Pt/C, and its electrocatalytic stability is also better than that of Pt/C. This work provides a large-scale production strategy for binder-free Pt SAC electrodes for efficient HER in neutral media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2017, "Volume": 56, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13694, "End Page": 13698, "Article Number": null, "DOI": "10.1002/anie.201706921", "DOI Link": "http://dx.doi.org/10.1002/anie.201706921", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413314800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, Y; Lohe, MR; Zhang, J; Liu, SH; Zhuang, XD; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Yang; Lohe, Martin R.; Zhang, Jian; Liu, Shaohua; Zhuang, Xiaodong; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertically oriented cobalt selenide/NiFe layered-double-hydroxide nullosheets supported on exfoliated graphene foil: an efficient 3D electrode for overall water splitting", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing cost-effective electrocatalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in basicmedia is critical to renewable energy conversion technologies. Here, we report a ternary hybrid that is constructed by in situ growth of cobalt selenide (Co0.85Se) nullosheets vertically oriented on electrochemically exfoliated graphene foil, with subsequent deposition of NiFe layered-double-hydroxide by a hydrothermal treatment. The resulting 3D hierarchical hybrid, possessing a high surface area of 156 m(2) g(-1) and strong coupling effect, exhibits excellent catalytic activity for OER, which only requires overpotentials of 1.50 and 1.51 V to attain current densities of 150 and 250 mA cm(-2), respectively. These overpotentials are much lower than those reported for other non-noble-metal materials and Ir/C catalysts. The hybrid also efficiently catalyzes HER in base with a current density of 10 mA cm(-2) at an overpotential of -0.26 V. Most importantly, we achieve a current density of 20 mA cm(-2) at 1.71 V by using the 3D hybrid as both a cathode and an anode for overall water splitting, which is well comparable to the integrated performance of Pt/C and Ir/C catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 755, "Times Cited, All Databases": 775, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 478, "End Page": 483, "Article Number": null, "DOI": "10.1039/c5ee03440j", "DOI Link": "http://dx.doi.org/10.1039/c5ee03440j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369744500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LB; Yu, Y; Yan, C; Li, K; Zheng, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Libin; Yu, You; Yan, Casey; Li, Kan; Zheng, Zijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable energy-dense and power-dense supercapacitor yarns enabled by scalable graphene-metallic textile composite electrodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One-dimensional flexible supercapacitor yarns are of considerable interest for future wearable electronics. The bottleneck in this field is how to develop devices of high energy and power density, by using economically viable materials and scalable fabrication technologies. Here we report a hierarchical graphene-metallic textile composite electrode concept to address this challenge. The hierarchical composite electrodes consist of low-cost graphene sheets immobilized on the surface of Ni-coated cotton yarns, which are fabricated by highly scalable electroless deposition of Ni and electrochemical deposition of graphene on commercial cotton yarns. Remarkably, the volumetric energy density and power density of the all solid-state supercapacitor yarn made of one pair of these composite electrodes are 6.1 mWhcm(-3) and 1,400 mWcm(-3), respectively. In addition, this SC yarn is lightweight, highly flexible, strong, durable in life cycle and bending fatigue tests, and integratable into various wearable electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 596, "Times Cited, All Databases": 614, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7260, "DOI": "10.1038/ncomms8260", "DOI Link": "http://dx.doi.org/10.1038/ncomms8260", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357170100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Zhou, CK; Filatov, AS; Cho, WJ; Lagunas, F; Wang, MZ; Vaikuntanathan, S; Liu, C; Klie, RF; Talapin, DV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Di; Zhou, Chenkun; Filatov, Alexander S.; Cho, Wooje; Lagunas, Francisco; Wang, Mingzhan; Vaikuntanathan, Suriyanarayanull; Liu, Chong; Klie, Robert F.; Talapin, Dmitri V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition-metal carbides and nitrides (MXenes) are a large family of materials actively studied for various applications, especially in the field of energy storage. MXenes are commonly synthesized by etching the layered ternary compounds, called MAX phases. We demonstrate a direct synthetic route for scalable and atom-economic synthesis of MXenes, including compounds that have not been synthesized from MAX phases, by the reactions of metals and metal halides with graphite, methane, or nitrogen. The direct synthesis enables chemical vapor deposition growth of MXene carpets and complex spherulite-like morphologies that form through buckling and release of MXene carpet to expose fresh surface for further reaction. The directly synthesized MXenes showed excellent energy storage capacity for lithium-ion intercalation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 379, "Issue": 6638, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1242, "End Page": 1247, "Article Number": null, "DOI": "10.1126/science.add9204", "DOI Link": "http://dx.doi.org/10.1126/science.add9204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994409800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, X; Zhang, YW; Takle, K; Bilsel, O; Li, ZJ; Lee, H; Zhang, ZJ; Li, DS; Fan, W; Duan, CY; Chan, EM; Lois, C; Xiang, Y; Han, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiang; Zhang, Yuanwei; Takle, Kendra; Bilsel, Osman; Li, Zhanjun; Lee, Hyungseok; Zhang, Zijiao; Li, Dongsheng; Fan, Wei; Duan, Chunying; Chan, Emory M.; Lois, Carlos; Xiang, Yang; Han, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dye-Sensitized Core/Active Shell Upconversion nulloparticles for Optogenetics and Bioimaging Applications", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near-infrared (NIR) dye-sensitized upconversion nulloparticles (UCNPs) can broaden the absorption range and boost upconversion efficiency of UCNPs. Here, we achieved significantly enhanced up conversion luminescence in dye-sensitized core/active shell UCNPs via the doping of ytterbium ions (Yb3+) in the UCNP shell, which bridged the energy transfer from the dye to the UCNP core. As a result, we synergized the two most practical upconversion booster effectors (dye-sensitizing and core/shell enhancement) to amplify upconversion efficiency. We demonstrated two biomedical applications using these UCNPs. By using dye-sensitized core/active shell UCNP embedded poly(methyl methacrylate) polymer implantable systems, we successfully shifted the optogenetic neuron excitation window to a biocompatible and deep tissue penetrable 800 nm wavelength. Furthermore, UCNPs were water-solubilized with Pluronic F127 with high upconversion efficiency and can be imaged in a mouse model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1060, "End Page": 1066, "Article Number": null, "DOI": "10.1021/acsnullo.5b06383", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b06383", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369115800115", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rezaei, SD; Dong, ZG; Chan, JYE; Trisno, J; Ng, RJH; Ruan, QF; Qiu, CW; Mortensen, NA; Yang, JKW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rezaei, Soroosh Daqiqeh; Dong, Zhaogang; Chan, John You En; Trisno, Jonathan; Ng, Ray Jia Hong; Ruan, Qifeng; Qiu, Cheng-Wei; Mortensen, N. Asger; Yang, Joel K. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullophotonic Structural Colors", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structural colors traditionally refer to colors arising from the interaction of light with structures with periodicities on the order of the wavelength. Recently, the definition has been broadened to include colors arising from individual resonators that can be subwavelength in dimension, for example, plasmonic and dielectric nulloantennas. For instance, diverse metallic and dielectric nullostructure designs have been utilized to generate structural colors based on various physical phenomena, such as localized surface plasmon resonullces (LSPRs), Mie resonullces, thin-film Fabry-Perot interference, and Rayleigh-Wood diffraction anomalies from 2D periodic lattices and photonic crystals. Here, we provide our perspective of the key application areas where structural colors really shine and other areas where more work is needed. We review major classes of materials and structures employed to generate structural coloration and highlight the main physical resonullces involved. We discuss mechanisms to tune structural colors and review recent advances in dynamic structural colors. In the end, we propose the concept of a universal pixel that could be crucial in realizing next-generation displays based on nullophotonic structural colors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2021, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18, "End Page": 33, "Article Number": null, "DOI": "10.1021/acsphotonics.0c00947", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.0c00947", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612567900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chittari, BL; Park, Y; Lee, D; Han, M; MacDonald, AH; Hwang, E; Jung, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chittari, Bheema Lingam; Park, Youngju; Lee, Dongkyu; Han, Moonsup; MacDonald, Allan H.; Hwang, Euyheon; Jung, Jeil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic and magnetic properties of single-layer MPX3 metal phosphorous trichalcogenides", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We survey the electronic structure and magnetic properties of two-dimensional (2D) MPX3 (M = V, Cr, Mn, Fe, Co, Ni, Cu, Zn, and X = S, Se, Te) transition-metal chalcogenophosphates to shed light on their potential role as single-layer van der Waals materials that possess magnetic order. Our ab initio calculations predict that most of these single-layer materials are antiferromagnetic semiconductors. The band gaps of the antiferromagnetic states decrease as the atomic number of the chalcogen atom increases (from S to Se to Te), leading in some cases to half-metallic ferromagnetic states or to nonmagnetic metallic states. We find that the competition between antiferromagnetic and ferromagnetic states can be substantially influenced by gating and by strain engineering. The sensitive interdependence we find between magnetic, structural, and electronic properties establishes the potential of this 2D materials class for applications in spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2016, "Volume": 94, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 184428, "DOI": "10.1103/PhysRevB.94.184428", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.184428", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388465200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Lee, DW; Ahn, BK; Seo, S; Kaufman, Y; Israelachvili, JN; Waite, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qiang; Lee, Dong Woog; Ahn, B. Kollbe; Seo, Sungbaek; Kaufman, Yair; Israelachvili, Jacob N.; Waite, J. Herbert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Underwater contact adhesion and microarchitecture in polyelectrolyte complexes actuated by solvent exchange", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyelectrolyte complexation is critical to the formation and properties of many biological and polymeric materials, and is typically initiated by aqueous mixing(1) followed by fluid-fluid phase separation, such as coacervation(2-5). Yet little to nothing is known about how coacervates evolve into intricate solid microarchitectures. Inspired by the chemical features of the cement proteins of the sandcastle worm, here we report a versatile and strong wet-contact microporous adhesive resulting from polyelectrolyte complexation triggered by solvent exchange. After premixing a catechol-functionalized weak polyanion with a polycation in dimethyl sulphoxide (DMSO), the solution was applied underwater to various substrates whereupon electrostatic complexation, phase inversion, and rapid setting were simultaneously actuated by water-DMSO solvent exchange. Spatial and temporal coordination of complexation, inversion and setting fostered rapid (similar to 25 s) and robust underwater contact adhesion (Wad >= 2 Jm(-2)) of complexed catecholic polyelectrolytes to all tested surfaces including plastics, glasses, metals and biological materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 407, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4539", "DOI Link": "http://dx.doi.org/10.1038/NMAT4539", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372591700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, SY; Xu, SM; Agrawral, A; Choudhury, S; Lu, YY; Tu, ZY; Ma, L; Archer, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Shuya; Xu, Shaomao; Agrawral, Akanksha; Choudhury, Snehashis; Lu, Yingying; Tu, Zhengyuan; Ma, Lin; Archer, Lynden A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stable room-temperature sodium-sulfur battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy rechargeable batteries based on earth-abundant materials are important for mobile and stationary storage technologies. Rechargeable sodium-sulfur batteries able to operate stably at room temperature are among the most sought-after platforms because such cells take advantage of a two-electron-redox process to achieve high storage capacity from inexpensive electrode materials. Here we report a room-temperature sodium-sulfur battery that uses a microporous carbon-sulfur composite cathode, and a liquid carbonate electrolyte containing the ionic liquid 1-methyl-3-propylimidazolium-chlorate tethered to SiO2 nulloparticles. We show that these cells can cycle stably at a rate of 0.5 C (1 C = 1675 mAh g(-1)) with 600 mAh g(-1) reversible capacity and nearly 100% Coulombic efficiency. By means of spectroscopic and electrochemical analysis, we find that the particles form a sodium-ion conductive film on the anode, which stabilizes deposition of sodium. We also find that sulfur remains interred in the carbon pores and undergo solid-state electrochemical reactions with sodium ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 512, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11722, "DOI": "10.1038/ncomms11722", "DOI Link": "http://dx.doi.org/10.1038/ncomms11722", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377910800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, CJ; Chen, C; Zhang, MW; Lin, LH; Ye, XX; Lin, S; Antonietti, M; Wang, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Caijin; Chen, Cheng; Zhang, Mingwen; Lin, Lihua; Ye, Xinxin; Lin, Sen; Antonietti, Markus; Wang, Xinchen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-doped BN nullosheets for metal-free photoredox catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The generation of sustainable and stable semiconductors for solar energy conversion by photoredox catalysis, for example, light-induced water splitting and carbon dioxide reduction, is a key challenge of modern materials chemistry. Here we present a simple synthesis of a ternary semiconductor, boron carbon nitride, and show that it can catalyse hydrogen or oxygen evolution from water as well as carbon dioxide reduction under visible light illumination. The ternary B-C-N alloy features a delocalized two-dimensional electron system with sp(2) carbon incorporated in the h-BN lattice where the bandgap can be adjusted by the amount of incorporated carbon to produce unique functions. Such sustainable photocatalysts made of lightweight elements facilitate the innovative construction of photoredox cascades to utilize solar energy for chemical conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 484, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7698, "DOI": "10.1038/ncomms8698", "DOI Link": "http://dx.doi.org/10.1038/ncomms8698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, Y; Chen, D; Han, B; Wang, J; Feng, R; Yang, T; Zhao, C; Zhao, YL; Guo, W; Shimizu, Y; Liu, CT; Liaw, PK; Inoue, K; Nagai, Y; Hu, A; Kai, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Y.; Chen, D.; Han, B.; Wang, J.; Feng, R.; Yang, T.; Zhao, C.; Zhao, Y. L.; Guo, W.; Shimizu, Y.; Liu, C. T.; Liaw, P. K.; Inoue, K.; Nagai, Y.; Hu, A.; Kai, J. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Outstanding tensile properties of a precipitation-strengthened FeCoNiCrTi0.2 high-entropy alloy at room and cryogenic temperatures", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A FeCoNiCrTi0.2 high-entropy alloy strengthened by two types of coherent nullo-precipitates but with the same composition was fabricated, and its tensile properties at room (293 K) and cryogenic temperatures (77 K) and the corresponding defect-structure evolution were investigated. Compared with the single-phase FeCoNiCr parent alloy, the precipitation-strengthened FeCoNiCrTi0.2 high-entropy alloy exhibits a significant increase in yield strength and ultimate tensile strength but with little sacrifice in ductility. Similar to the single-phase FeCoNiCr high-entropy alloy, the deformation behavior of this precipitation-strengthened FeCoNiCrTi0.2 high-entropy alloy shows strong temperature dependence. When the temperature decreases from 293 K to 77 K, its yield strength and ultimate tensile strength are increased from 700 MPa to 860 MPa and from 1.24 GPa to 1.58 GPa, respectively, associated with a ductility improvement from 36% to 46%. However, different from the single-phase FeCoNiCr high-entropy alloy with a twinning-dominullt deformation mode at 77 K. multiple-layered stacking faults with a hierarchical substructure prevail in the precipitation-strengthened FeCoNiCrTi0.2 high-entropy alloy when deformed at 77 K. The mechanism of twinning inhibition in this precipitation-strengthened high-entropy alloy is the high energy barrier for twin nucleation in the ordered gamma' nullo-particles. Our results may provide a guide for the design of tough high-entropy alloys for applications at cryogenic temperatures through combining precipitation strengthening and twinning/stacking faults. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 501, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 165, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": 240, "Article Number": null, "DOI": "10.1016/j.actamat.2018.11.049", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.11.049", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457665100021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XW; Shi, QQ; Zha, ZB; Zhu, DD; Zheng, LR; Shi, LX; Wei, XW; Lian, L; Wu, KL; Cheng, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xianwen; Shi, Qianqian; Zha, Zhengbao; Zhu, Dongdong; Zheng, Lirong; Shi, Luoxiang; Wei, Xianwen; Lian, Lian; Wu, Konglin; Cheng, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper single-atom catalysts with photothermal performance and enhanced nullozyme activity for bacteria-infected wound therapy", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullozymes have become a new generation of antibiotics with exciting broad-spectrum antibacterial properties and negligible biological toxicity. However, their inherent low catalytic activity limits their antibacterial properties. Herein, Cu single-atom sites/N doped porous carbon (Cu SASs/NPC) is successfully constructed for photothermal-catalytic antibacterial treatment by a pyrolysis-etching-adsorption-pyrolysis (PEAP) strategy. Cu SASs/NPC have stronger peroxidase-like catalytic activity, glutathione (GSH)-depleting function, and photothermal property compared with non-Cu-doped NPC, indicating that Cu doping significantly improves the catalytic performance of nullozymes. Cu SASs/NPC can effectively induce peroxidase-like activity in the presence of H2O2, thereby generating a large amount of hydroxyl radicals (center dot OH), which have a certain killing effect on bacteria and make bacteria more susceptible to temperature. The introduction of near-infrared (NIR) light can generate hyperthermia to fight bacteria, and enhance the peroxidase-like catalytic activity, thereby generating additional center dot OH to destroy bacteria. Interestingly, Cu SASs/NPC can act as GSH peroxidase (GSH-Px)-like nullozymes, which can deplete GSH in bacteria, thereby significantly improving the sterilization effect. PTT-catalytic synergistic antibacterial strategy produces almost 100% antibacterial efficiency against Escherichia coli (E. coli) and methicillin-resistant Staphylococcus aureus (MRSA). In vivo experiments show a better PTTcatalytic synergistic therapeutic performance on MRSA-infected mouse wounds. Overall, our work highlights the wide antibacterial and anti-infective bio-applications of Cu single-atom-containing catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4389, "End Page": 4401, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.04.024", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.04.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709332400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YL; Li, LF; Yao, W; Song, SR; Sun, JT; Pan, JB; Ren, X; Li, C; Okunishi, E; Wang, YQ; Wang, EY; Shao, Y; Zhang, YY; Yang, HT; Schwier, EF; Iwasawa, H; Shimada, K; Taniguchi, M; Cheng, ZH; Zhou, SY; Du, SX; Pennycook, SJ; Pantelides, ST; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yeliang; Li, Linfei; Yao, Wei; Song, Shiru; Sun, J. T.; Pan, Jinbo; Ren, Xiao; Li, Chen; Okunishi, Eiji; Wang, Yu-Qi; Wang, Eryin; Shao, Yan; Zhang, Y. Y.; Yang, Hai-tao; Schwier, Eike F.; Iwasawa, Hideaki; Shimada, Kenya; Taniguchi, Masaki; Cheng, Zhaohua; Zhou, Shuyun; Du, Shixuan; Pennycook, Stephen J.; Pantelides, Sokrates T.; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolayer PtSe2, a New Semiconducting Transition-Metal-Dichalcogenide, Epitaxially Grown by Direct Selenization of Pt", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-layer transition-metal dichalcogenides (TMDs) receive, significant attention due to their intriguing physical properties for both fundamental research and potential applications in electronics, optoelectronics, spintronics, catalysis, and so on. Here, we demonstrate the epitaxial growth of high-quality single-crystal, monolayer platinum diselenide (PtSe2), a new member of the layered TMDs family, by a single step of direct selenization of a Pt(111) substrate. A combination of atomic-resolution experimental characterizations and first-principle theoretic calculations reveals the atomic structure of the monolayer PtSe2/-Pt(111). Angle-resolved photoemission spectroscopy measurements confirm for the first time the semiconducting electronic Structure of monolayer PtSe2 (in contrast to its semimetallic bulk counterpart). The photocatalytic activity of monolayer PtSe2 film is evaluated by a methylene-blue photodegradation experiment, demonstrating its practical application as a promising photocatalyst. Moreover, circular polarization calculations predict that monolayer PtSe2 has also potential application's in valleytronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 607, "Times Cited, All Databases": 638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4013, "End Page": 4018, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b00964", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b00964", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356316900054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JL; Zhang, LL; Wu, HB; Lin, JY; Shen, ZX; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jilei; Zhang, Lili; Wu, Hao Bin; Lin, Jianyi; Shen, Zexiang; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance flexible asymmetric supercapacitors based on a new graphene foam/carbon nullotube hybrid film", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we report the fabrication of a new 3D graphene foam (GF)/carbon nullotube (CNT) hybrid film with high flexibility and robustness as the ideal support for deposition of large amounts of electrochemically active materials per unit area. To demonstrate the concept, we have deposited MnO2 and polypyrrole (Ppy) on the GF/CNT films and successfully fabricated lightweight and flexible asymmetric supercapacitors (ASCs). These ASCs assembled from GF/CNT/MnO2 and GF/CNT/Ppy hybrid films with high loading of electroactive materials in an aqueous electrolyte are able to function with an output voltage of 1.6 V, and deliver high energy/power density (22.8 W h kg(-1) at 860 W kg(-1) and 2.7 kW kg(-1) at 6.2 W h kg(-1)). The rate performance can be further improved with less loading of electroactive materials (10.3 kW kg(-1) at 10.9 W h kg(-1)). The ASCs demonstrate remarkable cycling stability (capacitance retention of 90.2-83.5% after 10 000 cycles), which is among the best reported for ASCs with both electrodes made of non-carbon electroactive materials. Also the ASCs are able to perfectly retain their electrochemical performance at different bending angles. These ASCs demonstrate great potential as power sources for flexible and lightweight electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 547, "Times Cited, All Databases": 563, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3709, "End Page": 3719, "Article Number": null, "DOI": "10.1039/c4ee01475h", "DOI Link": "http://dx.doi.org/10.1039/c4ee01475h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343974700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, JR; Fu, SB; Deng, YP; Xu, X; Laima, S; Liu, DZ; Zhang, PY; Zhou, J; Zhao, H; Yu, HX; Dang, SX; Zhang, JI; Zhao, YD; Li, H; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Jingran; Fu, Shubin; Deng, Yuanpeng; Xu, Xiang; Laima, Shujin; Liu, Dizhou; Zhang, Pengyu; Zhou, Jian; Zhao, Han; Yu, Hongxuan; Dang, Shixuan; Zhang, Jianing; Zhao, Yingde; Li, Hui; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hypocrystalline ceramic aerogels for thermal insulation at extreme conditions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal insulation under extreme conditions requires materials that can withstand complex thermomechanical stress and retain excellent thermal insulation properties at temperatures exceeding 1,000 degrees Celsius(1-3). Ceramic aerogels are attractive thermal insulating materials; however, at very high temperatures, they often show considerably increased thermal conductivity and limited thermomechanical stability that can lead to catastrophic failure(4-6). Here we report a multiscale design of hypocrystalline zircon nullofibrous aerogels with a zig-zag architecture that leads to exceptional thermomechanical stability and ultralow thermal conductivity at high temperatures. The aerogels show a near-zero Poisson's ratio (3.3 x 10(-4)) and a near-zero thermal expansion coefficient (1.2 x 10(-7 )per degree Celsius), which ensures excellent structural flexibility and thermomechanical properties. They show high thermal stability with ultralow strength degradation (less than 1 per cent) after sharp thermal shocks, and a high working temperature (up to 1,300 degrees Celsius). By deliberately entrapping residue carbon species in the constituent hypocrystalline zircon fibres, we substantially reduce the thermal radiation heat transfer and achieve one of the lowest high-temperature thermal conductivities among ceramic aerogels so far-104 milliwatts per metre per kelvin at 1,000 degrees Celsius. The combined thermomechanical and thermal insulating properties offer an attractive material system for robust thermal insulation under extreme conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2022, "Volume": 606, "Issue": 7916, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 909, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04784-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04784-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818775000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Waller, PJ; Lyle, SJ; Popp, TMO; Diercks, CS; Reimer, JA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Waller, Peter J.; Lyle, Steven J.; Popp, Thomas M. Osborn; Diercks, Christian S.; Reimer, Jeffrey A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical Conversion of Linkages in Covalent Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The imine linkages of two layered, porous covalent organic frameworks (COFs), TPB-TP-COF ([C6H3(C6H4N)(3)](2)[C6H4( CH)(2)](3), 1) and 4PE-1P-COF ([C-2(C6H4N)(4)][C6H4(CH)(2)](2), 2), have been transformed into amide linkages to make the respective isostructural amide COFs 1' and 2' by direct oxidation with retention of crystallinity and permanent porosity. Remarkably, the oxidation of both imine COFs is complete, as assessed by FT-IR and C-13 CP-MAS NMR spectroscopy and demonstrates (a) the first chemical conversion of a COF linkage and (b) how the usual crystallization problem encountered in COF chemistry can be bypassed to access COFs, such as these amides, that are typically thought to be difficult to obtain by the usual de novo methods. The amide COFs show improved chemical stability relative to their imine progenitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2016, "Volume": 138, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15519, "End Page": 15522, "Article Number": null, "DOI": "10.1021/jacs.6b08377", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b08377", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389623800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, D; Yang, RX; Wang, K; Wu, CC; Zhu, XJ; Feng, JS; Ren, XD; Fang, GJ; Priya, S; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dong; Yang, Ruixia; Wang, Kai; Wu, Congcong; Zhu, Xuejie; Feng, Jiangshan; Ren, Xiaodong; Fang, Guojia; Priya, Shashank; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High efficiency planar-type perovskite solar cells with negligible hysteresis using EDTA-complexed SnO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Even though the mesoporous-type perovskite solar cell (PSC) is known for high efficiency, its planar-type counterpart exhibits lower efficiency and hysteretic response. Herein, we report success in suppressing hysteresis and record efficiency for planar-type devices using EDTA-complexed tin oxide (SnO2) electron-transport layer. The Fermi level of EDTA-complexed SnO2 is better matched with the conduction band of perovskite, leading to high open-circuit voltage. Its electron mobility is about three times larger than that of the SnO2. The record power conversion efficiency of planar-type PSCs with EDTA-complexed SnO2 increases to 21.60% (certified at 21.52% by Newport) with negligible hysteresis. Meanwhile, the low-temperature processed EDTA-complexed SnO2 enables 18.28% efficiency for a flexible device. Moreover, the unsealed PSCs with EDTA-complexed SnO2 degrade only by 8% exposed in an ambient atmosphere after 2880 h, and only by 14% after 120 h under irradiation at 100 mW cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1244, "Times Cited, All Databases": 1290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3239, "DOI": "10.1038/s41467-018-05760-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05760-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441382000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schwierz, F; Pezoldt, J; Granzner, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schwierz, F.; Pezoldt, J.; Granzner, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional materials and their prospects in transistor electronics", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "During the past decade, two-dimensional materials have attracted incredible interest from the electronic device community. The first two-dimensional material studied in detail was graphene and, since 2007, it has intensively been explored as a material for electronic devices, in particular, transistors. While graphene transistors are still on the agenda, researchers have extended their work to two-dimensional materials beyond graphene and the number of two-dimensional materials under examination has literally exploded recently. Meanwhile several hundreds of different two-dimensional materials are known, a substantial part of them is considered useful for transistors, and experimental transistors with channels of different two-dimensional materials have been demonstrated. In spite of the rapid progress in the field, the prospects of two-dimensional transistors still remain vague and optimistic opinions face rather reserved assessments. The intention of the present paper is to shed more light on the merits and drawbacks of two-dimensional materials for transistor electronics and to add a few more facets to the ongoing discussion on the prospects of two-dimensional transistors. To this end, we compose a wish list of properties for a good transistor channel material and examine to what extent the two-dimensional materials fulfill the criteria of the list. The state-of-the-art two-dimensional transistors are reviewed and a balanced view of both the pros and cons of these devices is provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 567, "Times Cited, All Databases": 628, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8261, "End Page": 8283, "Article Number": null, "DOI": "10.1039/c5nr01052g", "DOI Link": "http://dx.doi.org/10.1039/c5nr01052g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354044600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, YH; Yi, P; Xu, WB; Sun, X; Deng, G; Liu, XF; Shui, JL; Yu, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Yuanhang; Yi, Peng; Xu, Wenbin; Sun, Xin; Deng, Gao; Liu, Xiaofang; Shui, Jianglan; Yu, Ronghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environmentally Tough and Stretchable MXene Organohydrogel with Exceptionally Enhanced Electromagnetic Interference Shielding Performances", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive hydrogels have potential applications in shielding electromagnetic (EM) radiation interference in deformable and wearable electronic devices, but usually suffer from poor environmental stability and stretching-induced shielding performance degradation. Although organohydrogels can improve the environmental stability of materials, their development is at the expense of reducing electrical conductivity and thus weakening EM interference shielding ability. Here, a MXene organohydrogel is prepared which is composed of MXene network for electron conduction, binary solvent channels for ion conduction, and abundant solvent-polymer-MXene interfaces for EM wave scattering. This organohydrogel possesses excellent anti-drying ability, low-temperature tolerance, stretchability, shape adaptability, adhesion and rapid self-healing ability. Two effective strategies have been proposed to solve the problems of current organohydrogel shielding materials. By reasonably controlling the MXene content and the glycerol-water ratio in the gel, MXene organohydrogel can exhibit exceptionally enhanced EM interference shielding performances compared to MXene hydrogel due to the increased physical cross-linking density of the gel. Moreover, MXene organohydrogel shows attractive stretching-enhanced interference effectiveness, caused by the connection and parallel arrangement of MXene nullosheets. This well-designed MXene organohydrogel has potential applications in shielding EM interference in deformable and wearable electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 176, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77, "DOI": "10.1007/s40820-022-00819-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00819-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771472800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, KC; Dong, KC; Li, JC; Gordon, MP; Reichertz, FG; Kim, H; Rho, Y; Wang, QJ; Lin, CY; Grigoropoulos, CP; Javey, A; Urban, JJ; Yao, J; Levinson, R; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Kechao; Dong, Kaichen; Li, Jiachen; Gordon, Madeleine P.; Reichertz, Finnegan G.; Kim, Hyungjin; Rho, Yoonsoo; Wang, Qingjun; Lin, Chang-Yu; Grigoropoulos, Costas P.; Javey, Ali; Urban, Jeffrey J.; Yao, Jie; Levinson, Ronnen; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-adaptive radiative coating for all-season household thermal regulation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sky is a natural heat sink that has been extensively used for passive radiative cooling of households. A lot of focus has been on maximizing the radiative cooling power of roof coating in the hot daytime using static, cooling-optimized material properties. However, the resultant overcooling in cold night or winter times exacerbates the heating cost, especially in climates where heating dominates energy consumption. We approached thermal regulation from an all-season perspective by developing a mechanically flexible coating that adapts its thermal emittance to different ambient temperatures. The fabricated temperature-adaptive radiative coating (TARC) optimally absorbs the solar energy and automatically switches thermal emittance from 0.20 for ambient temperatures lower than 15 degrees C to 0.90 for temperatures above 30 degrees C, driven by a photonically amplified metal-insulator transition. Simulations show that this system outperforms existing roof coatings for energy saving in most climates, especially those with substantial seasonal variations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2021, "Volume": 374, "Issue": 6574, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1504, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf7136", "DOI Link": "http://dx.doi.org/10.1126/science.abf7136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733380100054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, ZQ; Liu, K; Liu, QL; Li, YL; Li, MR; Su, CY; Ogiwara, N; Kobayashi, H; Kitagawa, H; Liu, M; Li, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Ziqian; Liu, Kang; Liu, Qinglin; Li, Yinle; Li, Manrong; Su, Cheng-Yong; Ogiwara, Naoki; Kobayashi, Hirokazu; Kitagawa, Hiroshi; Liu, Min; Li, Guangqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Missing-linker metal-organic frameworks for oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) have been recognized as compelling platforms for the development of miscellaneous applications because of their structural diversity and functional tunability. Here, we propose that the electrocatalytic properties could be well modified by incorporating missing linkers into the MOF. Theoretical calculations suggest the electronic structure of MOFs can be tuned by introducing missing linkers, which improves oxygen evolution reaction (OER) performance of the MOF. Inspired by these aspects, we introduced various missing linkers into a layered-pillared MOF Co-2(OH)(2)(C8H4O4) (termed as CoBDC) to prepare missing-linker MOFs. Transmission electron microscope and synchrotron X-ray measurements confirmed that the missing linkers in the MOF could be introduced and well controlled by our strategy. The self-supported MOF nulloarrays with missing linkers of carboxyferrocene exhibit excellent OER performance with ultralow overpotential of 241 mV at 100 mA cm(-2). This work opens a new prospect to develop efficient MOF-based electro-catalysts by introducing missing linkers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 533, "Times Cited, All Databases": 546, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5048, "DOI": "10.1038/s41467-019-13051-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13051-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494635900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, K; Moody, G; Wu, FC; Lu, XB; Choi, J; Kim, K; Rai, A; Sanchez, DA; Quan, JM; Singh, A; Embley, J; Zepeda, A; Campbell, M; Autry, T; Taniguchi, T; Watanabe, K; Lu, NS; Banerjee, SK; Silverman, KL; Kim, S; Tutuc, E; Yang, L; MacDonald, AH; Li, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kha Tran; Moody, Galan; Wu, Fengcheng; Lu, Xiaobo; Choi, Junho; Kim, Kyounghwan; Rai, Amritesh; Sanchez, Daniel A.; Quan, Jiamin; Singh, Akshay; Embley, Jacob; Zepeda, Andre; Campbell, Marshall; Autry, Travis; Taniguchi, Takashi; Watanabe, Kenji; Lu, nullshu; Banerjee, Sanjay K.; Silverman, Kevin L.; Kim, Suenne; Tutuc, Emanuel; Yang, Li; MacDonald, Allan H.; Li, Xiaoqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for moire excitons in van der Waals heterostructures", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in the isolation and stacking of monolayers of van der Waals materials have provided approaches for the preparation of quantum materials in the ultimate two-dimensional limit(1,2). In van der Waals heterostructures formed by stacking two monolayer semiconductors, lattice mismatch or rotational misalignment introduces an in-plane moire superlattice(3). It is widely recognized that the moire superlattice can modulate the electronic band structure of the material and lead to transport properties such as unconventional superconductivity(4) and insulating behaviour driven by correlations(5-7); however, the influence of the moire superlattice on optical properties has not been investigated experimentally. Here we report the observation of multiple interlayer exciton resonullces with either positive or negative circularly polarized emission in a molybdenum diselenide/tungsten diselenide (MoSe2/WSe2) heterobilayer with a small twist angle. We attribute these resonullces to excitonic ground and excited states confined within the moire potential. This interpretation is supported by recombination dynamics and by the dependence of these interlayer exciton resonullces on twist angle and temperature. These results suggest the feasibility of engineering artificial excitonic crystals using van der Waals heterostructures for nullophotonics and quantum information applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 893, "Times Cited, All Databases": 988, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2019, "Volume": 567, "Issue": 7746, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-0975-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-0975-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460426900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, YG; Wu, Q; Liang, XZ; Wang, ZY; Zheng, ZK; Wang, P; Liu, YY; Dai, Y; Whangbo, MH; Huang, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yugang; Wu, Qian; Liang, Xizhuang; Wang, Zeyan; Zheng, Zhaoke; Wang, Peng; Liu, Yuanyuan; Dai, Ying; Whangbo, Myung-Hwan; Huang, Baibiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu2O nulloparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO2 Electroreduction to Ethylene", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu2O nulloparticles (NPs) enclosed with different crystal facets, namely, c-Cu2O NPs with {100} facets, o-Cu2O NPs with {111} facets, and t-Cu2O NPs with both {111} and {100} facets, are prepared and their electrocatalytic properties for the reduction of CO2 to C2H4 are evaluated. It is shown that the selectivity and activity of the C2H4 production depend strongly on the crystal facets exposed in Cu2O NPs. The selectivities for the C2H4 production increases in the order, c-Cu2O < o-Cu2O < t-Cu2O, (with FEC2H4 = 38%, 45%, and 59%, respectively). This study suggests that Cu2O NPs are more likely responsible for the selectivity and activity for the C2H4 production than the metallic Cu NPs produced on the surface of Cu2O NPs. This work provides a new route for enhancing the selectivity of the electrocatalytic CO2 reduction by crystal facet engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902820, "DOI": "10.1002/advs.201902820", "DOI Link": "http://dx.doi.org/10.1002/advs.201902820", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510186600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barpanda, P; Oyama, G; Nishimura, S; Chung, SC; Yamada, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi; Chung, Sai-Cheong; Yamada, Atsuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 3.8-V earth-abundant sodium battery electrode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium batteries have ushered the wireless revolution over last two decades and are now matured to enable green automobiles. However, the growing concern on scarcity and large-scale applications of lithium resources have steered effort to realize sustainable sodium-ion batteries, Na and Fe being abundant and low-cost charge carrier and redox centre, respectively. However, their performance is limited owing to low operating voltage and sluggish kinetics. Here we report a hitherto-unknown material with entirely new composition and structure with the first alluaudite-type sulphate framework, Na2Fe2(SO4)(3), registering the highest-ever Fe3+/ Fe2+ redox potential at 3.8V (versus Na, and hence 4.1V versus Li) along with fast rate kinetics. Rare-metal-free Na-ion rechargeable battery system compatible with the present Li-ion battery is now in realistic scope without sacrificing high energy density and high power, and paves way for discovery of new earth-abundant sustainable cathodes for large-scale batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 718, "Times Cited, All Databases": 751, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4358, "DOI": "10.1038/ncomms5358", "DOI Link": "http://dx.doi.org/10.1038/ncomms5358", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340615500049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YL; Yang, T; Tong, Y; Wang, J; Luan, JH; Jiao, ZB; Chen, D; Yang, Y; Hu, A; Liu, CT; Kai, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Y. L.; Yang, T.; Tong, Y.; Wang, J.; Luan, J. H.; Jiao, Z. B.; Chen, D.; Yang, Y.; Hu, A.; Liu, C. T.; Kai, J. -J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterogeneous precipitation behavior and stacking-fault-mediated deformation in a CoCrNi-based medium-entropy alloy", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining high strength and good ductility is highly-desired yet challenging for conventional structural materials. Newly emerging concentrated multi-component alloys with face-centered-cubic structure provide an ultra-ductile matrix, and the precipitation hardening based on these alloys provides a very effective way to achieve a superior strength-ductility combination. Here, we report a high-strength CoCrNi-based medium-entropy alloy hardened by nulloscale L1(2)-(Ni, Co, Cr)(3)(Ti, AD-type particles with mixing heterogeneous and homogeneous precipitation behaviors. Compared to the single-phase CoCrNi medium-entropy alloy, the yield strength and the tensile strength of the precipitation strengthened CoCrNi medium-entropy alloy were increased by-70% to-750 MPa and-44% to -1.3 GPa, respectively, whereas a good ductility,-45%, was still achieved. The underlying deformation micro-mechanisms were systematically investigated using transmission electron microscope. In the single-phase CoCrNi medium-entropy alloy, the deformation mode was dominated by mechanical twinning. In the precipitation-hardened medium-entropy alloy, however, a high density of stacking faults prevailed. We revealed that the absence of mechanical twinning in this low stacking fault energy precipitation-strengthened medium-entropy alloy could relate to the increasing critical twinning stress affected by the channel width of the matrix. We further calculated that the increment of the yield strength was substantially from precipitation strengthening. Our present findings provide not only a fundamental understanding of the deformation micro-mechanism of the precipitation-strengthened CoCrNi medium-entropy alloy but also a useful guidance for the development of precipitation hardened concentrated multi-component alloys in the future. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 656, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2017, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": 82, "Article Number": null, "DOI": "10.1016/j.actamat.2017.07.029", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.07.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410018200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, CH; Cao, Y; Cheng, YR; Wang, DD; Xu, TL; Su, L; Zhang, XJ; Dong, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Conghui; Cao, Yu; Cheng, Yaru; Wang, Dongdong; Xu, Tailin; Su, Lei; Zhang, Xueji; Dong, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An open source and reduce expenditure ROS generation strategy for chemodynamic/photodynamic synergistic therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The therapeutic effect of reactive oxygen species (ROS)-involved cancer therapies is significantly limited by shortage of oxy-substrates, such as hypoxia in photodynamic therapy (PDT) and insufficient hydrogen peroxide (H2O2) in chemodynamic therapy (CDT). Here, we report a H2O2/O-2 self-supplying nulloagent, (MSNs@CaO2-ICG)@LA, which consists of manganese silicate (MSN)-supported calcium peroxide (CaO2) and indocyanine green (ICG) with further surface modification of phase-change material lauric acid (LA). Under laser irradiation, ICG simultaneously generates singlet oxygen and emits heat to melt the LA. The exposed CaO2 reacts with water to produce O-2 and H2O2 for hypoxia-relieved ICG-mediated PDT and H2O2-supplying MSN-based CDT, acting as an open source strategy for ROS production. Additionally, the MSNs-induced glutathione depletion protects ROS from scavenging, termed reduce expenditure. This open source and reduce expenditure strategy is effective in inhibiting tumor growth both in vitro and in vivo, and significantly improves ROS generation efficiency from multi-level for ROS-involved cancer therapies. The supply of oxygen species for dynamic therapy is a major limitation. Here, the authors report on a complex of calcium peroxide with photo/chemo dynamic agents, where NIR heating causes the release of calcium peroxide to generate oxygen and hydrogen peroxide for photodynamic and chemodynamic therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1735, "DOI": "10.1038/s41467-020-15591-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15591-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558836800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, TY; Chen, SQ; Pang, H; Xue, HG; Yu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tianyi; Chen, Shuangqiang; Pang, Huan; Xue, Huaiguo; Yu, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2-Based nullocomposites for Electrochemical Energy Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Typical layered transition-metal chalcogenide materials, in particular layered molybdenum disulfide (MoS2) nullocomposites, have attracted increasing attention in recent years due to their excellent chemical and physical properties in various research fieldsHere, a general overview of synthetic MoS2 based nullocomposites via different preparation approaches and their applications in energy storage devices (Li-ion battery, Na-ion battery, and supercapacitor) is presented. The relationship between morphologies and the electrochemical performances of MoS2-based nullocomposites in the three typical and promising rechargeable systems is also discussed. Finally, perspectives on major challenges and opportunities faced by MoS2-based materials to address the practical problems of MoS2-based materials are presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600289, "DOI": "10.1002/advs.201600289", "DOI Link": "http://dx.doi.org/10.1002/advs.201600289", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397020800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Xia, Y; Zhao, HY; Wang, GF; Xiang, L; Xu, JL; Komarneni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jing; Xia, Yi; Zhao, Hongyuan; Wang, Guifang; Xiang, Lan; Xu, Jianlong; Komarneni, Sridhar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen defects-mediated Z-scheme charge separation in g-C3N4/ZnO photocatalysts for enhanced visible-light degradation of 4-chlorophenol and hydrogen evolution", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "g-C3N4 nullosheets were coupled with oxygen-defective ZnO nullorods (OD-ZnO) to form a heterojunction photocatalyst with a core-shell structure. Multiple optical and electrochemical analysis including electrochemical impedance spectroscopy, photocurrent response and steady/transient photoluminescence spectroscopy revealed that the g-C3N4/OD-ZnO heterojunction exhibited increased visible-light absorption, improved charge generation/separation efficiency as well as prolonged lifetime, leading to the enhanced photocatalytic activities for the degradation of 4-chlorophenol under visible-light illumination (lambda > 420 nm). An oxygen defects-mediated Z-scheme mechanism was proposed for the charge separation in the heterojunction, which involved the recombining of photoinduced electrons that were trapped in the oxygen defects-level of OD-ZnO directly with the holes in the valence band of g-C3N4 at the heterojunction interface. The detection of surface generated reactive species including O-center dot(2-) and (OH)-O-center dot clearly supported the Z-scheme mechanism. Moreover, the g-C3(N4)/OD-ZnO photocatalysts also exhibited enhanced visible-light Z-scheme H-2 evolution activity, with an optimal H-2 evolution rate of about 5 times than that of pure g-C3N4. The present work not only provided an alternative strategy for construction of novel visible-light-driven Z-scheme photocatalysts, but also gained some new insights into the role of oxygen-defects of semiconductors in mediating the Z-scheme charge separation. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2017, "Volume": 206, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": 416, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.01.067", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.01.067", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395602000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, GB; Liu, P; Liao, ZQ; Sun, FF; He, YH; Zhong, HX; Zhang, T; Zschech, E; Chen, MW; Wu, G; Zhang, J; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Guangbo; Liu, Pan; Liao, Zhongquan; Sun, Fanfei; He, Yanghua; Zhong, Haixia; Zhang, Tao; Zschech, Ehrenfried; Chen, Mingwei; Wu, Gang; Zhang, Jian; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc-Mediated Template Synthesis of Fe-N-C Electrocatalysts with Densely Accessible Fe-Nx Active Sites for Efficient Oxygen Reduction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to their earth abundance, high atom utilization, and excellent activity, single iron atoms dispersed on nitrogen-doped carbons (Fe-N-C) have emerged as appealing alternatives to noble-metal platinum (Pt) for catalyzing the oxygen reduction reaction (ORR). However, the ORR activity of current Fe-N-C is seriously limited by the low density and inferior exposure of active Fe-N-x species. Here, a novel zinc-mediated template synthesis strategy is demonstrated for constructing densely exposed Fe-N-x moieties on hierarchically porous carbon (SA-Fe-NHPC). During the thermal treatment of 2,6-diaminopyridine/ZnFe/SiO2 complex, the zinc prevents the formation of iron carbide nulloparticles and the SiO2 template promotes the generation of hierarchically pores for substantially improving the accessibility of Fe-N-x moieties after subsequent leaching. As a result, the SA-Fe-NHPC electrocatalysts exhibit an unprecedentedly high ORR activity with a half-wave potential (E-1/2) of 0.93 V in a 0.1 m KOH aqueous solution, which outperforms those for Pt/C catalyst and state-of-the-art noble metal-free electrocatalysts. As the air electrode in zinc-air batteries, the SA-Fe-NHPC demonstrates a large peak power density of 266.4 mW cm(-2) and superior long-term stability. Therefore, the developed zinc-mediated template synthesis strategy for boosting the density and accessibility of Fe-N-x species paves a new avenue toward high-performance ORR electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 32, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1907399, "DOI": "10.1002/adma.201907399", "DOI Link": "http://dx.doi.org/10.1002/adma.201907399", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507416600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, ZL; Feng, LZ; Hao, Y; Li, QG; Chen, MC; Yang, ZJ; Zhao, H; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Ziliang; Feng, Liangzhu; Hao, Yu; Li, Quguang; Chen, Muchao; Yang, Zhijuan; Zhao, He; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of CaCO3-Based nullomedicine for Enhanced Sonodynamic Therapy via Amplification of Tumor Oxidative Stress", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of multifunctional stimuli-responsive nullomedicine is appealing for effective cancer treatment. Herein, we utilize the biocompatible CaCO3 nulloparticles as the template to guide the formation of pH-dissociable hollow coordination nullostructures, in which meso-tetra-(4-carboxyphenyl)porphine (TCPP), a sonosensitizer, acts as the organic bridging molecule and ferric ion serves as the metallic center L-buthionine sulfoximine (BSO), an inhibitor for glutathione (GSH) biosynthesis, can be simultaneously loaded during the preparation of TCPP-Fe@CaCO3, obtaining BSO-TCPP-Fe@CaCO3 with pH-responsive dissociation to endow fast release of Ca2+ and BSO under an acidic tumor microenvironment. Such BSO-TCPP-Fe@-CaCO3 confers synergistic oxidative stress amplification via intracellular Ca2+-overloading-induced mitochondria dam. age, BSO-mediated GSH depletion, and TCPP-mediated sonodynamic therapy (SDT), leading to remarkable cell death. Consequently, tumors on the mice treated with BSO-TCPP-Fe@CaCO3 administration and subsequent ultrasound exposure are effectively suppressed Our work thus highlights a facile strategy to prepare pH-dissociable nullomedicine for effective SDT treatment of tumors via triple amplification of tumor oxidative stress.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2020, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1391, "End Page": 1407, "Article Number": null, "DOI": "10.1016/j.chempr.2020.02.020", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.02.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540905600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HY; Liu, YL; Guo, ZY; Lei, BF; Zhuang, JL; Zhang, XJ; Liu, ZM; Hu, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Haiyao; Liu, Yingliang; Guo, Zhouyi; Lei, Bingfu; Zhuang, Jianle; Zhang, Xuejie; Liu, Zhiming; Hu, Chaofan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrophobic carbon dots with blue dispersed emission and red aggregation-induced emission", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots (CDs) have been studied for years as one of the most promising fluorescent nullomaterials. However, CDs with red or solid-state fluorescence are rarely reported. Herein, through a one-pot solvothermal treatment, hydrophobic CDs (H-CDs) with blue dispersed emission and red aggregation-induced emission are obtained. When water is introduced, the hydrophobic interaction leads to aggregation of the H-CDs. The formation of H-CD clusters induces the turning off of the blue emission, as the carbonized cores suffer from pi-pi stacking interactions, and the turning on of the red fluorescence, due to restriction of the surfaces' intramolecular rotation around disulfide bonds, which conforms to the aggregation-induced-emission phenomenon. This on-off fluorescence of the H-CDs is reversible when the H-CD powder is completely dissolved. Moreover, the H-CD solution dispersed in filter paper is nearly colorless. Finally, we develop a reversible two switch-mode luminescence ink for advanced anti-counterfeiting and dual-encryption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 597, "Times Cited, All Databases": 625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1789, "DOI": "10.1038/s41467-019-09830-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09830-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464976200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SH; Yeon, YK; Lee, JM; Chao, JR; Lee, YJ; Seo, YB; Sultan, MT; Lee, OJ; Lee, JS; Yoon, SI; Hong, IS; Khang, G; Lee, SJ; Yoo, JJ; Park, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Soon Hee; Yeon, Yeung Kyu; Lee, Jung Min; Chao, Janet Ren; Lee, Young Jin; Seo, Ye Been; Sultan, Md. Tipu; Lee, Ok Joo; Lee, Ji Seung; Yoon, Sung-il; Hong, In-Sun; Khang, Gilson; Lee, Sang Jin; Yoo, James J.; Park, Chan Hum", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precisely printable and biocompatible silk fibroin bioink for digital light processing 3D printing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although three-dimensional (3D) bioprinting technology has gained much attention in the field of tissue engineering, there are still several significant engineering challenges to overcome, including lack of bioink with biocompatibility and printability. Here, we show a bioink created from silk fibroin (SF) for digital light processing (DLP) 3D bioprinting in tissue engineering applications. The SF-based bioink (Sil-MA) was produced by a methacrylation process using glycidyl methacrylate (GMA) during the fabrication of SF solution. The mechanical and rheological properties of Sil-MA hydrogel proved to be outstanding in experimental testing and can be modulated by varying the Sil-MA contents. This Sil-MA bioink allowed us to build highly complex organ structures, including the heart, vessel, brain, trachea and ear with excellent structural stability and reliable biocompatibility. Sil-MA bioink is well-suited for use in DLP printing process and could be applied to tissue and organ engineering depending on the specific biological requirements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 688, "Times Cited, All Databases": 735, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1620, "DOI": "10.1038/s41467-018-03759-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03759-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430674000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JZ; Liu, GG; Zhu, YZ; Su, M; Yin, PF; Wu, XJ; Lu, QP; Tan, CL; Zhao, MT; Liu, ZQ; Yang, WM; Li, H; Nam, GH; Zhang, LP; Chen, ZH; Huang, X; Radjenovic, PM; Huang, W; Tian, ZQ; Li, JF; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Junze; Liu, Guigao; Zhu, Yue-zhou; Su, Min; Yin, Pengfei; Wu, Xue-jun; Lu, Qipeng; Tan, Chaoliang; Zhao, Meiting; Liu, Zhengqing; Yang, Weimin; Li, Hai; Nam, Gwang-Hyeon; Zhang, Liping; Chen, Zhenhua; Huang, Xiao; Radjenovic, Petar M.; Huang, Wei; Tian, Zhong-qun; Li, Jian-feng; Zhang, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ag@MoS2 Core-Shell Heterostructure as SERS Platform to Reveal the Hydrogen Evolution Active Sites of Single-Layer MoS2", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the reaction mechanism for the catalytic process is essential to the rational design and synthesis of highly efficient catalysts. MoS2 has been reported to be an efficient catalyst toward the electrochemical hydrogen evolution reaction (HER), but it still lacks direct experimental evidence to reveal the mechanism for MoS2-catalyzed electrochemical HER process at the atomic level. In this work, we develop a wet-chemical synthetic method to prepare the single-layer MoS2-coated polyhedral Ag core-shell heterostructure (Ag@MoS2) with tunable sizes as efficient catalysts for the electrochemical HER. The Ag@MoS2 core-shell heterostructures are used as ideal platforms for the real-time surface-enhanced Raman spectroscopy (SERS) study owing to the strong electromagnetic field generated in the plasmonic Ag core. The in situ SERS results provide solid Raman spectroscopic evidence proving the S-H bonding formation on the MoS2 surface during the HER process, suggesting that the S atom of MoS2 is the catalytic active site for the electrochemical HER It paves the way on the design and synthesis of heterostructures for exploring their catalytic mechanism at atomic level based on the in situ SERS measurement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 142, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7161, "End Page": 7167, "Article Number": null, "DOI": "10.1021/jacs.0c01649", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c01649", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526300600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gild, J; Zhang, Y; Harrington, T; Jiang, S; Hu, T; Quinn, MC; Mellor, WM; Zhou, N; Vecchio, K; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gild, Joshua; Zhang, Yuanyao; Harrington, Tyler; Jiang, Sicong; Hu, Tao; Quinn, Matthew C.; Mellor, William M.; Zhou, Naixie; Vecchio, Kenneth; Luo, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seven equimolar, five-component, metal diborides were fabricated via high-energy ball milling and spark plasma sintering. Six of them, including (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B-2, (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B-2, (Hf0.2Zr0.2Mo0.2Nb0.2Ti0.2)B-2, (Hf0.2Mo0.2Ta0.2Nb0.2Ti0.2)B-2, (Mo0.2Zr0.2Ta0.2Nb0.2Ti0.2)B-2, and (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B-2, possess virtually one solid-solution boride phase of the hexagonal AlB2 structure. Revised Hume-Rothery size-difference factors are used to rationalize the formation of high-entropy solid solutions in these metal diborides. Greater than 92% of the theoretical densities have been generally achieved with largely uniform compositions from nulloscale to microscale. Aberration-corrected scanning transmission electron microscopy (AC STEM), with high-angle annular dark-field and annular bright-field (HAADF and ABF) imaging and nulloscale compositional mapping, has been conducted to confirm the formation of 2-D high-entropy metal layers, separated by rigid 2-D boron nets, without any detectable layered segregation along the c-axis. These materials represent a new type of ultra-high temperature ceramics (UHTCs) as well as a new class of high-entropy materials, which not only exemplify the first high-entropy non-oxide ceramics (borides) fabricated but also possess a unique non-cubic (hexagonal) and layered (quasi-2D) high-entropy crystal structure that markedly differs from all those reported in prior studies. Initial property assessments show that both the hardness and the oxidation resistance of these high-entropy metal diborides are generally higher/better than the average performances of five individual metal diborides made by identical fabrication processing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 901, "Times Cited, All Databases": 985, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37946, "DOI": "10.1038/srep37946", "DOI Link": "http://dx.doi.org/10.1038/srep37946", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388791700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hai, X; Xi, SB; Mitchell, S; Harrath, K; Xu, HM; Akl, DF; Kong, DB; Li, J; Li, ZJ; Sun, T; Yang, HM; Cui, YG; Su, CL; Zhao, XX; Li, J; Pérez-Ramírez, J; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hai, Xiao; Xi, Shibo; Mitchell, Sharon; Harrath, Karim; Xu, Haomin; Akl, Dario Faust; Kong, Debin; Li, Jing; Li, Zejun; Sun, Tao; Yang, Huimin; Cui, Yige; Su, Chenliang; Zhao, Xiaoxu; Li, Jun; Perez-Ramirez, Javier; Lu, Jiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A general versatile approach combining wet-chemistry impregnation and two-step annealing is devised for the scalable synthesis of a library of ultra-high-density single-atom catalysts with drastically enhanced reactivity. The stabilization of transition metals as isolated centres with high areal density on suitably tailored carriers is crucial for maximizing the industrial potential of single-atom heterogeneous catalysts. However, achieving single-atom dispersions at metal contents above 2 wt% remains challenging. Here we introduce a versatile approach combining impregnation and two-step annealing to synthesize ultra-high-density single-atom catalysts with metal contents up to 23 wt% for 15 metals on chemically distinct carriers. Translation to a standardized, automated protocol demonstrates the robustness of our method and provides a path to explore virtually unlimited libraries of mono- or multimetallic catalysts. At the molecular level, characterization of the synthesis mechanism through experiments and simulations shows that controlling the bonding of metal precursors with the carrier via stepwise ligand removal prevents their thermally induced aggregation into nulloparticles. The drastically enhanced reactivity with increasing metal content exemplifies the need to optimize the surface metal density for a given application. Moreover, the loading-dependent site-specific activity observed in three distinct catalytic systems reflects the well-known complexity in heterogeneous catalyst design, which now can be tackled with a library of single-atom catalysts with widely tunable metal loadings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 174, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-021-01022-y", "DOI Link": "http://dx.doi.org/10.1038/s41565-021-01022-y", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722472000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, LL; Liu, PF; Yan, XC; Gu, L; Yang, ZZ; Yang, HG; Qiu, SL; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Lili; Liu, Peng Fei; Yan, Xuecheng; Gu, Lin; Yang, Zhen Zhong; Yang, Hua Gui; Qiu, Shilun; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen production through electrochemical process is at the heart of key renewable energy technologies including water splitting and hydrogen fuel cells. Despite tremendous efforts, exploring cheap, efficient and durable electrocatalysts for hydrogen evolution still remains as a great challenge. Here we synthesize a nickel-carbon-based catalyst, from carbonization of metal-organic frameworks, to replace currently best-known platinum-based materials for electrocatalytic hydrogen evolution. This nickel-carbon-based catalyst can be activated to obtain isolated nickel atoms on the graphitic carbon support when applying electrochemical potential, exhibiting highly efficient hydrogen evolution performance with high exchange current density of 1.2 mA cm(-2) and impressive durability. This work may enable new opportunities for designing and tuning properties of electrocatalysts at atomic scale for large-scale water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 599, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10667, "DOI": "10.1038/ncomms10667", "DOI Link": "http://dx.doi.org/10.1038/ncomms10667", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371021000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, J; Wood, JD; Wells, SA; Lee, JH; Liu, XL; Chen, KS; Hersam, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Joohoon; Wood, Joshua D.; Wells, Spencer A.; Lee, Jae-Hyeok; Liu, Xiaolong; Chen, Kan-Sheng; Hersam, Mark C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent Exfoliation of Electronic-Grade, Two-Dimensional Black Phosphorus", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution dispersions of two-dimensional (2D) black phosphorus (BP) often referred to as phosphorene are achieved by solvent exfoliation. These pristine, electronic-grade BP dispersions are produced with anhydrous organic solvents in a sealed-tip ultrasonication system, which circumvents BP degradation that would otherwise occur via solvated O-2 or H2O. Among conventional solvents, N-methylpyrrolidone (NMP) is found to provide stable, highly concentrated (similar to 0.4 mg/mL) BP dispersions. Atomic force microscopy, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy show that the structure and chemistry of solvent-exfoliated BP nullosheets are comparable to mechanically exfoliated BP flakes. Additionally, residual NMP from the liquid-phase processing suppresses the rate of BP oxidation in ambient conditions. Solvent-exfoliated BP nullosheet field-effect transistors exhibit ambipolar behavior with current on/off ratios and mobilities up to similar to 10(4) and similar to 50 cm(2) V-1 s(-1), respectively. Overall, this study shows that stable, highly concentrated, electronic-grade 2D BP dispersions can be realized by scalable solvent exfoliation, thereby presenting opportunities for large-area, high-performance BP device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 641, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3596, "End Page": 3604, "Article Number": null, "DOI": "10.1021/acsnullo.5b01143", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b01143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353867000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Dong, YF; Li, HJ; Zhao, ZB; Wu, HB; Hao, C; Liu, SH; Qiu, JS; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhiyu; Dong, Yanfeng; Li, Hongjiang; Zhao, Zongbin; Wu, Hao Bin; Hao, Ce; Liu, Shaohong; Qiu, Jieshan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing lithium-sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulphur batteries are one very appealing power source with high energy density. But their practical use is still hindered by several issues including short lifespan, low efficiency and safety concern from the lithium anode. Polysulphide dissolution and insulating nature of sulphur are generally considered responsible for the capacity degradation. However, the detachment of discharge products, that is, highly polar lithium sulphides, from nonpolar carbon matrix (for example, graphene) has been rarely studied as one critical factor. Here we report the strongly covalent stabilization of sulphur and its discharge products on amino-functionalized reduced graphene oxide that enables stable capacity retention of 80% for 350 cycles with high capacities and excellent high-rate response up to 4 C. The present study demonstrates a feasible and effective strategy to solve the long-term cycling difficulty for lithium-sulphur batteries and also helps to understand the capacity decay mechanism involved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 977, "Times Cited, All Databases": 1020, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5002, "DOI": "10.1038/ncomms6002", "DOI Link": "http://dx.doi.org/10.1038/ncomms6002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342985700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, ZP; Chen, ZZ; Chen, ZB; Lv, CC; Humphrey, MG; Zhang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Zhipeng; Chen, Zhongzhong; Chen, Zhibo; Lv, Cuncai; Humphrey, Mark G.; Zhang, Chi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt phosphide nullorods as an efficient electrocatalyst for the hydrogen evolution reaction", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt phosphide (CO2P) nullorods are found to exhibit efficient catalytic activity for the hydrogen evolution reaction (HER), with the overpotential required for the current density of 20 mA/cm(2) as small as 167 mV in acidic solution and 171 mV in basic solution. In addition, the Co2P nullorods can work stably in both acidic and basic solution during hydrogen production. This performance can be favorably compared to typical high efficient non-precious catalysts, and suggests the promising application potential of Co2P nullorods in the field of hydrogen production. The HER process follows a Volmer-Heyrovsky mechanism, and the rates of the discharge step and desorption step appear to be comparable during the HER process. The similarity of charged natures of Co and P in the Co2P nullorods to those of the hydride-acceptor and proton-acceptor in highly efficient Ni2P catalysts, [NiFe] hydrogenase, and its analogues implies that the HER catalytic activity of the Co2P nullorods might be correlated with the charged natures of Co and P. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 373, "End Page": 382, "Article Number": null, "DOI": "10.1016/j.nulloen.2014.08.013", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2014.08.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344632800042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, F; Zhou, XR; Lv, J; Chen, J; Chen, JT; Kongcharoen, H; Zhang, YH; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Feng; Zhou, Xinran; Lv, Jian; Chen, Jian; Chen, Juntong; Kongcharoen, Haruethai; Zhang, Yihui; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable, Breathable, and Stable Lead-Free Perovskite/Polymer nullofiber Composite for Hybrid Triboelectric and Piezoelectric Energy Harvesting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide-perovskite-based mechanical energy harvesters display excellent electrical output due to their unique ferroelectricity and dielectricity. However, their high toxicity and moisture sensitivity impede their practical applications. Herein, a stretchable, breathable, and stable nullofiber composite (LPPS-NFC) is fabricated through electrospinning of lead-free perovskite/poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) and styrene-ethylene-butylene-styrene (SEBS). The Cs3Bi2Br9 perovskites serve as efficient electron acceptors and local nucleating agents for the crystallization of polymer chains, thereby enhancing the electron-trapping capacity and polar crystalline phase in LPPS-NFC. The excellent energy level matching between Cs3Bi2Br9 and PVDF-HFP boosts the electron transfer efficiency and reduces the charge loss, thereby promoting the electron-trapping process. Consequently, this LPPS-NFC-based energy harvester displays an excellent electrical output (400 V, 1.63 mu A cm(-2), and 2.34 W m(-2)), setting a record of the output voltage among halide-perovskite-based nullogenerators. The LPPS-NFC also exhibits excellent stretchability, waterproofness, and breathability, enabling the fabrication of robust wearable devices that convert mechanical energy from different biomechanical motions into electrical power to drive common electronic devices. The LPPS-NFC-based energy harvesters also endure extreme mechanical deformations (washing, folding, and crumpling) without performance degradation, and maintain stable electrical output up to 5 months, demonstrating their promising potential for use as smart textiles and wearable power sources.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200042, "DOI": "10.1002/adma.202200042", "DOI Link": "http://dx.doi.org/10.1002/adma.202200042", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770842200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tonda, S; Kumar, S; Bhardwaj, M; Yadav, P; Ogale, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tonda, Surendar; Kumar, Santosh; Bhardwaj, Monika; Yadav, Poonam; Ogale, Satishchandra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "g-C3N4/NiAl-LDH 2D/2D Hybrid Heterojunction for High-Performance Photocatalytic Reduction of CO2 into Renewable Fuels", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D/2D interface heterostructures of g-C3N4 and NiAl-LDH are synthesized utilizing strong electrostatic interactions between positively charged 2D NiAl-LDH sheets and negatively charged 2D g-C3N4 nullosheets. This new 2D/2D interface heterojunction showed remarkable performance for photocatalytic CO, reduction to produce renewable fuels such as CO and H-2 under visible-light irradiation, far superior to that of either single phase g-C3N4 or NiAl-LDH nullosheets. The enhancement of photocatalytic activity could be attributed mainly to the excellent interfacial contact at the heterojunction of gC(3)N(4)/NiAl-LDH, which subsequently results in suppressed recombination, and improved transfer and separation of photogenerated charge carriers. In addition, the optimal g-C3N4/NiAl-LDH nullocomposite possessed high photostability after successive experimental runs with no obvious change in the production of CO from CO, reduction. Our findings regarding the design, fabrication and photophysical properties of 2D/2D heterostructure systems may find use in other photocatalytic applications including H-2 production and water purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 475, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2018, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2667, "End Page": 2678, "Article Number": null, "DOI": "10.1021/acsami.7b18835", "DOI Link": "http://dx.doi.org/10.1021/acsami.7b18835", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423496500055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, Y; Zhang, JW; Kong, Y; Zhao, Y; Chen, SS; Li, D; Liu, W; Chen, YF; Xie, TF; Cui, JY; Li, C; Domen, K; Zhang, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Yu; Zhang, Jiangwei; Kong, Yuan; Zhao, Yue; Chen, Shanshan; Li, Deng; Liu, Wei; Chen, Yifan; Xie, Tengfeng; Cui, Junyan; Li, Can; Domen, Kazunari; Zhang, Fuxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis offers an integrated means to convert light to fuel, but efficiencies are often low. Here, authors report a Z-scheme system utilizing Ir and FeCoOx co-catalysts to enhance charge separation on BiVO4 facets that achieves high quantum efficiencies for overall water splitting. Bismuth vanadate (BiVO4) has been widely investigated as a photocatalyst or photoanode for solar water splitting, but its activity is hindered by inefficient cocatalysts and limited understanding of the underlying mechanism. Here we demonstrate significantly enhanced water oxidation on the particulate BiVO4 photocatalyst via in situ facet-selective photodeposition of dual-cocatalysts that exist separately as metallic Ir nulloparticles and nullocomposite of FeOOH and CoOOH (denoted as FeCoOx), as revealed by advanced techniques. The mechanism of water oxidation promoted by the dual-cocatalysts is experimentally and theoretically unraveled, and mainly ascribed to the synergistic effect of the spatially separated dual-cocatalysts (Ir, FeCoOx) on both interface charge separation and surface catalysis. Combined with the H-2-evolving photocatalysts, we finally construct a Z-scheme overall water splitting system using [Fe(CN)(6)](3-/4-) as the redox mediator, whose apparent quantum efficiency at 420 nm and solar-to-hydrogen conversion efficiency are optimized to be 12.3% and 0.6%, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 484, "DOI": "10.1038/s41467-022-28146-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28146-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747410400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, WQ; Zhang, Y; Hu, CL; Mao, JG; Ye, HY; Li, PF; Huang, SPD; Xiong, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Wei-Qiang; Zhang, Yi; Hu, Chun-Li; Mao, Jiang-Gao; Ye, Heng-Yun; Li, Peng-Fei; Huang, Songping D.; Xiong, Ren-Gen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A lead-halide perovskite molecular ferroelectric semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic semiconductor ferroelectrics such as BiFeO3 have shown great potential in photovoltaic and other applications. Currently, semiconducting properties and the corresponding application in optoelectronic devices of hybrid organo-plumbate or stannate are a hot topic of academic research; more and more of such hybrids have been synthesized. Structurally, these hybrids are suitable for exploration of ferroelectricity. Therefore, the design of molecular ferroelectric semiconductors based on these hybrids provides a possibility to obtain new or high-performance semiconductor ferroelectrics. Here we investigated Pb-layered perovskites, and found the layer perovskite (benzylammonium)(2)PbCl4 is ferroelectric with semiconducting behaviours. It has a larger ferroelectric spontaneous polarization P-s = 13 mu C cm(-2) and a higher Curie temperature T-c = 438 K with a band gap of 3.65 eV. This finding throws light on the new properties of the hybrid organo-plumbate or stannate compounds and provides a new way to develop new semiconductor ferroelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 620, "Times Cited, All Databases": 644, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7338, "DOI": "10.1038/ncomms8338", "DOI Link": "http://dx.doi.org/10.1038/ncomms8338", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355540900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Millet, MM; Algara-Siller, G; Wrabetz, S; Mazheika, A; Girgsdies, F; Teschner, D; Seitz, F; Tarasov, A; Leychenko, SV; Schlögl, R; Frei, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Millet, Marie-Mathilde; Algara-Siller, Gerardo; Wrabetz, Sabine; Mazheika, Aliaksei; Girgsdies, Frank; Teschner, Detre; Seitz, Friedrich; Tarasov, Andrey; Leychenko, Sergey V.; Schloegl, Robert; Frei, Elias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni Single Atom Catalysts for CO2 Activation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the activation of CO2 on Ni single-atom catalysts. These catalysts were synthesized using a solid solution approach by controlled substitution of 1-10 atom % of Mg2+ by Ni2+ inside the MgO structure. The Ni atoms are preferentially located on the surface of the MgO and, as predicted by hybrid functional calculations, favor low-coordinated sites. The isolated Ni atoms are active for CO2 conversion through the reverse water-gas shift (rWGS) but are unable to conduct its further hydrogenation to CH4 (or MeOH), for which Ni clusters are needed. The CO formation rates correlate linearly with the concentration of Ni on the surface evidenced by XPS and microcalorimetry. The calculations show that the substitution of Mg atoms by Ni atoms on the surface of the oxide structure reduces the strength of the CO2 binding at low-coordinated sites and also promotes H-2 dissociation. Astonishingly, the single-atom catalysts stayed stable over 100 h on stream, after which no clusters or particle formation could be detected. Upon catalysis, a surface carbonate adsorbate-layer was formed, of which the decompositions appear to be directly linked to the aggregation of Ni. This study on atomically dispersed Ni species brings new fundamental understanding of Ni active sites for reactions involving CO2 and clearly evidence the limits of single-atom catalysis for complex reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2019, "Volume": 141, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2451, "End Page": 2461, "Article Number": null, "DOI": "10.1021/jacs.8b11729", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b11729", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459222100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, KZ; Wang, PT; Guo, SJ; Zhang, X; Shen, X; Lu, G; Su, D; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kezhu; Wang, Pengtang; Guo, Shaojun; Zhang, Xu; Shen, Xuan; Lu, Gang; Su, Dong; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ordered PdCu-Based nulloparticles as Bifunctional Oxygen-Reduction and Ethanol-Oxidation Electrocatalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of superior non-platinum electrocatalysts for enhancing the electrocatalytic activity and stability for the oxygen-reduction reaction (ORR) and liquid fuel oxidation reaction is very important for the commercialization of fuel cells, but still a great challenge. Herein, we demonstrate a new colloidal chemistry technique for making structurally ordered PdCu-based nulloparticles (NPs) with composition control from PdCu to PdCuNi and PtCuCo. Under the dual tuning on the composition and intermetallic phase, the ordered PdCuCo NPs exhibit better activity and much enhanced stability for ORR and ethanol-oxidation reaction (EOR) than those of disordered PdCuM NPs, the commercial Pt/C and Pd/C catalysts. The density functional theory (DFT) calculations reveal that the improved ORR activity on the PdCuM NPs stems from the catalytically active hollow sites arising from the ligand effect and the compressive strain on the Pd surface owing to the smaller atomic size of Cu, Co, and Ni.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2016, "Volume": 55, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9030, "End Page": 9035, "Article Number": null, "DOI": "10.1002/anie.201603022", "DOI Link": "http://dx.doi.org/10.1002/anie.201603022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383253700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WN; Zhao, KN; Huo, WC; Wang, YZ; Yao, G; Gu, X; Cheng, HW; Mai, LQ; Hu, CG; Wang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Weina; Zhao, Kangning; Huo, Wangchen; Wang, Yizhan; Yao, Guang; Gu, Xiao; Cheng, Hongwei; Mai, Liqiang; Hu, Chenguo; Wang, Xudong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diethyl ether as self-healing electrolyte additive enabled long-life rechargeable aqueous zinc ion batteries", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous rechargeable zinc ion batteries (ARZIBs) is considered one of the most compelling candidates for grid-scale energy storage owing to their cost effectiveness, good safety, eco-friendliness, high output voltage, and high capacity. However, their practical applications are still largely limited by the undesirable cyclability and high-rate capability. Here, we report a discovery that using a small amount (2 vol%) of diethyl ether (Et2O) as the electrolyte additive could largely improve the performance of Zn-MnO2 batteries. The addition of Et2O yielded the first cycle coulombic efficiency of 95.6% at 50 mA/g, a high capacity of 115.9 mAh/g at 5 A/g and 97.7% retention of initial capacity after 4000 cycles, demonstrating an outstanding rate capability and cycling performance among the reported Mn-based zinc ions batteries in mild electrolyte. Ex-situ characterizations revealed that appropriate amount of Et2O molecules could effectively suppress the formation of Zn dendrites on Zn anode, which is the main mechanism for cyclability improvements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 551, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 275, "End Page": 281, "Article Number": null, "DOI": "10.1016/j.nulloen.2019.05.042", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2019.05.042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474636100032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, XK; Wu, HB; Guan, BY; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Xian-Kai; Wu, Hao Bin; Guan, Bu Yuan; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confining Sub-nullometer Pt Clusters in Hollow Mesoporous Carbon Spheres for Boosting Hydrogen Evolution Activity", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting is considered as a promising approach to produce clean and sustainable hydrogen fuel. As a new class of nullomaterials with high ratio of surface atoms and tunable composition and electronic structure, metal clusters are promising candidates as catalysts. Here, a new strategy is demonstrated to synthesize active and stable Pt-based electrocatalysts for hydrogen evolution by confining Pt clusters in hollow mesoporous carbon spheres (Pt-5/HMCS). Such a structure would effectively stabilize the Pt clusters during the ligand removal process, leading to remarkable electrocatalytic performance for hydrogen production in both acidic and alkaline solutions. Particularly, the optimal Pt-5/HMCS electrocatalyst exhibits 12 times the mass activity of Pt in commercial Pt/C catalyst with similar Pt loading. This study exemplifies a simple yet effective approach to improve the cost effectiveness of precious-metal-based catalysts with stabilized metal clusters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 32, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901349, "DOI": "10.1002/adma.201901349", "DOI Link": "http://dx.doi.org/10.1002/adma.201901349", "Book DOI": null, "Early Access Date": "DEC 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000504452600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akri, M; Zhao, S; Li, XY; Zang, KT; Lee, AF; Isaacs, MA; Xi, W; Gangarajula, Y; Luo, J; Ren, YJ; Cui, YT; Li, L; Su, Y; Pan, XL; Wen, W; Pan, Y; Wilson, K; Li, L; Qiao, BT; Ishii, H; Liao, YF; Wang, AQ; Wang, XD; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akri, Mohcin; Zhao, Shu; Li, Xiaoyu; Zang, Ketao; Lee, Adam F.; Isaacs, Mark A.; Xi, Wei; Gangarajula, Yuvaraj; Luo, Jun; Ren, Yujing; Cui, Yi-Tao; Li, Lei; Su, Yang; Pan, Xiaoli; Wen, Wu; Pan, Yang; Wilson, Karen; Li, Lin; Qiao, Botao; Ishii, Hirofumi; Liao, Yen-Fa; Wang, Aiqin; Wang, Xiaodong; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed nickel as coke-resistant active sites for methane dry reforming", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dry reforming of methane (DRM) is an attractive route to utilize CO2 as a chemical feedstock with which to convert CH4 into valuable syngas and simultaneously mitigate both greenhouse gases. Ni-based DRM catalysts are promising due to their high activity and low cost, but suffer from poor stability due to coke formation which has hindered their commercialization. Herein, we report that atomically dispersed Ni single atoms, stabilized by interaction with Ce-doped hydroxyapatite, are highly active and coke-resistant catalytic sites for DRM. Experimental and computational studies reveal that isolated Ni atoms are intrinsically coke-resistant due to their unique ability to only activate the first C-H bond in CH4, thus avoiding methane deep decomposition into carbon. This discovery offers new opportunities to develop large-scale DRM processes using earth abundant catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5181, "DOI": "10.1038/s41467-019-12843-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12843-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496713100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Cai, W; Yang, Y; Song, XD; Neale, Z; Wang, HE; Sui, JH; Cao, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xu; Cai, Wei; Yang, Ying; Song, Xuedan; Neale, Zachary; Wang, Hong-En; Sui, Jiehe; Cao, Guozhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoSe2 nullosheets perpendicularly grown on graphene with Mo-C bonding for sodium-ion capacitors", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) MoSe2/graphene nullocomposites show great potential as anode materials for sodium ion batteries (SIBs). In this work, we report the controlled growth of oriented, interlayer-expanded MoSe2 nullosheets on graphene with Mo-C bonding via a surfactant-directed hydrothermal reaction. The resulting 2D nullocomposite with strong electronic coupling facilitates both electron and Na-ion transfer across the interface and reversible insertion/ extraction of Na-ion, enabling fast pseudocapacitive Na-ion storage with reduced voltage hysteresis and excellent durability over 1500 cycles. Density Functional Theory (DFT) calculation demonstrated MoSe2/graphene established a charge accumulation at the interface and promoted sodium-ion transport through the interface. Such outstanding Na-ion storage capability propels their potential application in sodium-ion capacitors (SICs). As a proof-of-concept, a model hybrid SIC was demonstrated by assembling with MoSe2/graphene composite as anode and activated carbon as cathode, delivering an impressive energy density of 82 Wh kg(-1) and power output of 10,752 W kg(-1) within a voltage window of 0.5-3 V. The SIC also delivered a superior rate capability (66% capacitance retention after increasing the current density from 0.1 to 25.6 A g(-1)) and cyclability (81% capacitance retention over 5000 cycles at 5 A g(-1)), which shows promise for bridging the performance gap between conventional batteries and supercapacitors. The proposed strategy based on hierarchical hybridization combined with chemical bonding and interlayer engineering may hold great promise for developing advanced electrode materials for next-generation clean energy systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 224, "End Page": 234, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.03.002", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.03.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430057000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HG; Chung, HT; Cullen, DA; Wagner, S; Kramm, UI; More, KL; Zelenay, P; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hanguang; Chung, Hoon T.; Cullen, David A.; Wagner, Stephan; Kramm, Ulrike I.; More, Karren L.; Zelenay, Piotr; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum group metal-free (PGM-free) catalysts for the oxygen reduction reaction (ORR) with atomically dispersed FeN4 sites have emerged as a potential replacement for low-PGM catalysts in acidic polymer electrolyte fuel cells (PEFCs). In this work, we carefully tuned the doped Fe content in zeolitic imidazolate framework (ZIF)-8 precursors and achieved complete atomic dispersion of FeN4 sites, the sole Fe species in the catalyst based on Mo ss bauer spectroscopy data. The Fe-N-C catalyst with the highest density of active sites achieved respectable ORR activity in rotating disk electrode (RDE) testing with a half-wave potential (E-1/2) of 0.88 +/- 0.01 V vs. the reversible hydrogen electrode (RHE) in 0.5 M H2SO4 electrolyte. The activity degradation was found to be more significant when holding the potential at 0.85 V relative to standard potential cycling (0.6-1.0 V) in O-2 saturated acid electrolyte. The post-mortem electron microscopy analysis provides insights into possible catalyst degradation mechanisms associated with Fe-N coordination cleavage and carbon corrosion. High ORR activity was confirmed in fuel cell testing, which also divulged the promising performance of the catalysts at practical PEFC voltages. We conclude that the key factor behind the high ORR activity of the Fe-N-C catalyst is the optimum Fe content in the ZIF-8 precursor. While too little Fe in the precursors results in an insufficient density of FeN4 sites, too much Fe leads to the formation of clusters and an ensuing significant loss in catalytic activity due to the loss of atomically dispersed Fe to inactive clusters or even nulloparticles. Advanced electron microscopy was used to obtain insights into the clustering of Fe atoms as a function of the doped Fe content. The Fe content in the precursor also affects other key catalyst properties such as the particle size, porosity, nitrogen-doping level, and carbon microstructure. Thanks to using model catalysts exclusively containing FeN4 sites, it was possible to directly correlate the ORR activity with the density of FeN4 species in the catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2019, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1039/c9ee00877b", "DOI Link": "http://dx.doi.org/10.1039/c9ee00877b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479082800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, HH; Yan, N; Yu, R; Chang, CR; Zhou, G; Hu, HS; Rong, HP; Niu, ZQ; Mao, JJ; Asakura, H; Tanaka, T; Dyson, PJ; Li, J; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Haohong; Yan, Ning; Yu, Rong; Chang, Chun-Ran; Zhou, Gang; Hu, Han-Shi; Rong, Hongpan; Niu, Zhiqiang; Mao, Junjie; Asakura, Hiroyuki; Tanaka, Tsunehiro; Dyson, Paul Joseph; Li, Jun; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin rhodium nullosheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite significant advances in the fabrication and applications of graphene-like materials, it remains a challenge to prepare single-layered metallic materials, which have great potential applications in physics, chemistry and material science. Here we report the fabrication of poly(vinylpyrrolidone)-supported single-layered rhodium nullosheets using a facile solvothermal method. Atomic force microscope shows that the thickness of a rhodium nullosheet is <4 angstrom. Electron diffraction and X-ray absorption spectroscopy measurements suggest that the rhodium nullosheets are composed of planar single-atom-layered sheets of rhodium. Density functional theory studies reveal that the single-layered Rh nullosheet involves a delta-bonding framework, which stabilizes the single-layered structure together with the poly(vinylpyrrolidone) ligands. The poly(vinylpyrrolidone)-supported single-layered rhodium nullosheet represents a class of metallic two-dimensional structures that might inspire further fundamental advances in physics, chemistry and material science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3093, "DOI": "10.1038/ncomms4093", "DOI Link": "http://dx.doi.org/10.1038/ncomms4093", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331084400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, XZ; Song, SY; Zhao, SN; Hao, ZM; Zhu, M; Meng, X; Wu, LL; Zhang, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Xue-Zhi; Song, Shu-Yan; Zhao, Shu-Na; Hao, Zhao-Min; Zhu, Min; Meng, Xing; Wu, Lan-Lan; Zhang, Hong-Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Crystal-to-Single-Crystal Transformation of a Europium(III) Metal-Organic Framework Producing a Multi-responsive Luminescent Sensor", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A sensor with a red-emission signal is successfully obtained by the solvothermal reaction of Eu3+ and heterofunctional ligand bpydbH(2) (4,4'-(4,4'-bipyridine-2,6-diyl) dibenzoic acid), followed by terminal-ligand exchange in a single-crystal-to-single-crystal transformation. As a result of treatments both before and after the metal-organic framework formation, accessible Lewis-base sites and coordinated water molecules are successfully anchored onto the host material, and they act as signal transmission media for the recognition of analytes at the molecular level. This is the first reported sensor based on a metal-organic framework (MOF) with multi-responsive optical sensing properties. It is capable of sensing small organic molecules and inorganic ions, and unprecedentedly it can discriminate among the homologues and isomers of aliphatic alcohols as well as detect highly explosive 2,4,6-trinitrophenol (TNP) in water or in the vapor phase. This work highlights the practical application of luminescent MOFs as sensors, and it paves the way toward other multi-responsive sensors by demonstrating the incorporation of various functional groups into a single framework.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 556, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 24, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4034, "End Page": 4041, "Article Number": null, "DOI": "10.1002/adfm.201303986", "DOI Link": "http://dx.doi.org/10.1002/adfm.201303986", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339565300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GY; Li, XL; Liao, QB; Liu, YF; Xi, K; Huang, WY; Jia, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guiyang; Li, Xinle; Liao, Qiaobo; Liu, Yanfeng; Xi, Kai; Huang, Wenyu; Jia, Xudong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water-dispersible PEG-curcumin/amine-functionalized covalent organic framework nullocomposites as smart carriers for in vivo drug delivery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) as drug-delivery carriers have been mostly evaluated in vitro due to the lack of COFs nullocarriers that are suitable for in vivo studies. Here we develop a series of water-dispersible polymer-COF nullocomposites through the assembly of polyethylene-glycol-modified monofunctional curcumin derivatives (PEG-CCM) and amine-functionalized COFs (APTES-COF-1) for in vitro and in vivo drug delivery. The real-time fluorescence response shows efficient tracking of the COF-based materials upon cellular uptake and anticancer drug (doxorubicin (DOX)) release. Notably, in vitro and in vivo studies demonstrate that PEG-CCM@APTES-COF-1 is a smart carrier for drug delivery with superior stability, intrinsic biodegradability, high DOX loading capacity, strong and stable fluorescence, prolonged circulation time and improved drug accumulation in tumors. More intriguingly, PEG350-CCM@APTES-COF-1 presents an effective targeting strategy for brain research. We envisage that PEG-CCM@APTES-COF-1 nullocomposites represent a great promise toward the development of a multifunctional platform for cancer-targeted in vivo drug delivery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2785, "DOI": "10.1038/s41467-018-04910-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04910-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438857400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YX; Wan, JY; Yang, YF; Ye, YS; Xiao, X; Boyle, DT; Burke, W; Huang, ZJ; Chen, H; Cui, Y; Yu, ZA; Oyakhire, ST", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yinxing; Wan, Jiayu; Yang, Yufei; Ye, Yusheng; Xiao, Xin; Boyle, David T.; Burke, Will; Huang, Zhuojun; Chen, Hao; Cui, Yi; Yu, Zhiao; Oyakhire, Solomon T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable, Ultrathin, and High-Temperature-Resistant Solid Polymer Electrolytes for Energy-Dense Lithium Metal Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state batteries (ASSBs) demonstrate great promise, offering high energy density, good thermal stability, and safe operation compared with traditional Li-ion batteries. Among various solid-state electrolytes (SSEs), solid polymer electrolytes (SPEs) offer an attractive choice due to their thinness, low density, and good manufacturability. However, ultrathin SPEs that work with practical current densities or at high temperatures remain challenging, limiting applicable conditions of SPE-based batteries. Here, the authors report a novel scalable, ultrathin, and high-temperature-resistant SPE for ASSBs. This design includes an electrospun polyacrylonitrile (PAN) matrix and polyethylene oxide (PEO)/Li salt ionic conductor, which offers a stable LiF and Li3N containing SSE/Li interface. The unique interface-as well as the good mechanical strength-inhibits lithium dendrites and prevents short circuiting. As a result, symmetrical Li-Li cells deliver more than 300 h cyclability at 0.5 mA cm(-2). ASSBs fabricated with only 5 mu m-thickness PAN-PEO/lithium bis(trifluoromethanesulfonyl)imide reach 300 cycles at 0.3 C rate at 60 degrees C. The excellent thermal stability of PAN also results in safer SPEs at high temperatures. The design extends battery operation up to temperatures of 120 and 150 degrees C, where it achieves 500 cycles at C/2 rate and 100 cycles at 2C rate, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 12, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103720, "DOI": "10.1002/aenm.202103720", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103720", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760882000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, YJ; Yang, FY; Lu, XF; Yan, YJ; Cho, YH; Ma, LG; Niu, XH; Kim, S; Son, YW; Feng, DL; Li, SY; Cheong, SW; Chen, XH; Zhang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Yijun; Yang, Fangyuan; Lu, Xiu Fang; Yan, Ya Jun; Cho, Yong-Heum; Ma, Liguo; Niu, Xiaohai; Kim, Sejoong; Son, Young-Woo; Feng, Donglai; Li, Shiyan; Cheong, Sang-Wook; Chen, Xian Hui; Zhang, Yuanbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable phase transitions in thin flakes of 1T-TaS2", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to tune material properties using gating by electric fields is at the heart of modern electronic technology. It is also a driving force behind recent advances in two-dimensional systems, such as the observation of gate electric-field-induced superconductivity and metal-insulator transitions. Here, we describe an ionic field-effect transistor (termed an iFET), in which gate-controlled Li ion intercalation modulates the material properties of layered crystals of 1T-TaS2. The strong charge doping induced by the tunable ion intercalation alters the energetics of various charge-ordered states in 1T-TaS2 and produces a series of phase transitions in thin-flake samples with reduced dimensionality. We find that the charge-density wave states in 1T-TaS2 collapse in the two-dimensional limit at critical thicknesses. Meanwhile, at low temperatures, the ionic gating induces multiple phase transitions from Mott-insulator to metal in 1T-TaS2 thin flakes, with five orders of magnitude modulation in resistance, and superconductivity emerges in a textured charge-density wave state induced by ionic gating. Our method of gate-controlled intercalation opens up possibilities in searching for novel states of matter in the extreme charge-carrier-concentration limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 642, "Times Cited, All Databases": 725, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2015, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 270, "End Page": 276, "Article Number": null, "DOI": "10.1038/NnullO.2014.323", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2014.323", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350799700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JT; Zhang, M; Zeng, Y; Chen, JS; Qiu, LX; Zhou, H; Sun, CJ; Yu, Y; Zhu, CZ; Zhu, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiting; Zhang, Meng; Zeng, Yon; Chen, Jisheng; Qiu, Lingxi; Zhou, Hua; Sun, Chengjun; Yu, Ying; Zhu, Chengzhou; Zhu, Zhihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single Fe Atom on Hierarchically Porous S, N-Codoped nullocarbon Derived from Porphyra Enable Boosted Oxygen Catalysis for Rechargeable Zn-Air Batteries", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron-nitrogen-carbon materials (Fe-N-C) are known for their excellent oxygen reduction reaction (ORR) performance. Unfortunately, they generally show a laggard oxygen evolution reaction (OER) activity, which results in a lethargic charging performance in rechargeable Zn-air batteries. Here porous S-doped Fe-N-C nullosheets are innovatively synthesized utilizing a scalable FeCl3-encapsulated-porphyra precursor pyrolysis strategy. The obtained electrocatalyst exhibits ultrahigh ORR activity (E-1/2 = 0.84 V vs reversible hydrogen electrode) and impressive OER performance (E-j= 10 = 1.64 V). The potential gap (Delta E = E-j= 10 - E-1/2) is 0.80 V, outperforming that of most highly active bifunctional electrocatalysts reported to date. Furthermore, the key role of S involved in the atomically dispersed Fe-Nx species on the enhanced ORR and OER activities is expounded for the first time by ultrasound-assisted extraction of the exclusive S source (taurine) from porphyra. Moreover, the assembled rechargeable Zn-air battery comprising this bifunctional electrocatalyst exhibits higher power density (225.1 mW cm(-2)) and lower charging-discharging overpotential (1.00 V, 100 mA cm(-2) compared to Pt/C + RuO2 catalyst). The design strategy can expand the utilization of earth-abundant biomaterial-derived catalysts, and the mechanism investigations of S doping on the structure-activity relationship can inspire the progress of other functional electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 15, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900307, "DOI": "10.1002/smll.201900307", "DOI Link": "http://dx.doi.org/10.1002/smll.201900307", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471711300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, C; Wang, MY; Han, SB; Wang, Q; Zhang, Q; Zhu, YM; Yang, XM; Wu, DJ; Zu, XT; Sterbinsky, GE; Feng, ZX; Gu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Chao; Wang, Maoyu; Han, Shaobo; Wang, Qi; Zhang, Qing; Zhu, Yuanmin; Yang, Xuming; Wu, Duojie; Zu, Xiaotao; Sterbinsky, George E.; Feng, Zhenxing; Gu, Meng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh Oxygen Evolution Reaction Activity Achieved Using Ir Single Atoms on Amorphous CoOx nullosheets", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing efficient electrocatalysts for an oxygen evolution reaction (OER) is important for renewable energy storage. Here, we design high-density Ir single-atom catalysts supported by CoOx amorphous nullosheets (ANSs) for the OER. Experimental results show that Ir single atoms are anchored by abundant surface-absorbed O in CoOx ANSs. Ir single-atom catalysts possess ultrahigh mass activity that is 160-fold of commercial IrO2. The OER of IrCoOx ANSs reached a record low onset overpotential of less than 30 mV. In situ X-ray absorption spectroscopy reveals that Ir-O-Co pairs directly boosted the OER efficiency and enhanced the Ir stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 123, "End Page": 130, "Article Number": null, "DOI": "10.1021/acscatal.0c04656", "DOI Link": "http://dx.doi.org/10.1021/acscatal.0c04656", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000606833100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, LZ; Guo, SJ; Zhang, X; Shen, X; Su, D; Lu, G; Zhu, X; Yao, JL; Guo, J; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Lingzheng; Guo, Shaojun; Zhang, Xu; Shen, Xuan; Su, Dong; Lu, Gang; Zhu, Xing; Yao, Jianlin; Guo, Jun; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface engineering of hierarchical platinum-cobalt nullowires for efficient electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite intense research in past decades, the lack of high-performance catalysts for fuel cell reactions remains a challenge in realizing fuel cell technologies for transportation applications. Here we report a facile strategy for synthesizing hierarchical platinum-cobalt nullowires with high-index, platinum-rich facets and ordered intermetallic structure. These structural features enable unprecedented performance for the oxygen reduction and alcohol oxidation reactions. The specific/mass activities of the platinum-cobalt nullowires for oxygen reduction reaction are 39.6/33.7 times higher than commercial Pt/C catalyst, respectively. Density functional theory simulations reveal that the active threefold hollow sites on the platinum-rich high-index facets provide an additional factor in enhancing oxygen reduction reaction activities. The nullowires are stable in the electrochemical conditions and also thermally stable. This work may represent a key step towards scalable production of high-performance platinum-based nullowires for applications in catalysis and energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 663, "Times Cited, All Databases": 690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11850, "DOI": "10.1038/ncomms11850", "DOI Link": "http://dx.doi.org/10.1038/ncomms11850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379108100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, ZY; Zhao, WJ; Palomaki, TA; Sun, BS; Miller, MK; Zhao, ZY; Yan, JQ; Xu, XD; Cobden, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Zaiyao; Zhao, Wenjin; Palomaki, Tauno A.; Sun, Bosong; Miller, Moira K.; Zhao, Zhiying; Yan, Jiaqiang; Xu, Xiaodong; Cobden, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric switching of a two-dimensional metal", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A ferroelectric is a material with a polar structure whose polarity can be reversed (switched) by applying an electric field(1,2). In metals, itinerant electrons screen electrostatic forces between ions, which explains in part why polar metals are very rare(3-7). Screening also excludes external electric fields, apparently ruling out the possibility of ferroelectric switching. However, in principle, a thin enough polar metal could be sufficiently penetrated by an electric field to have its polarity switched. Here we show that the topological semimetal WTe2 provides an embodiment of this principle. Although monolayer WTe2 is centro-symmetric and thus non-polar, the stacked bulk structure is polar. We find that two-or three-layer WTe2 exhibits spontaneous out-of-plane electric polarization that can be switched using gate electrodes. We directly detect and quantify the polarization using graphene as an electric-field sensor(8). Moreover, the polarization states can be differentiated by conductivity and the carrier density can be varied to modify the properties. The temperature at which polarization vanishes is above 350 kelvin, and even when WTe2 is sandwiched between graphene layers it retains its switching capability at room temperature, demonstrating a robustness suitable for applications in combination with other two-dimensional materials(9-12).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 752, "Times Cited, All Databases": 814, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2018, "Volume": 560, "Issue": 7718, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 336, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0336-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0336-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441673400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, J; Jin, J; Lu, M; Huang, BL; Zhang, H; Peng, Y; Xi, PX; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Jie; Jin, Jing; Lu, Min; Huang, Bolong; Zhang, Hong; Peng, Yong; Xi, Pinxian; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iridium Single Atoms Coupling with Oxygen Vacancies Boosts Oxygen Evolution Reaction in Acid Media", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneous realization of improved activity, enhanced stability, and reduced cost remains a desirable yet challenging goal in the search of electrocatalysis oxygen evolution reaction (OER) in acid. Herein, we report a novel strategy to prepare iridium single-atoms (Ir-SAs) on ultrathin NiCo2O4 porous nullosheets (Ir-NiCo2O4 NSs) by the co-electrodeposition method. The surface-exposed Ir-SAs couplings with oxygen vacancies (V-o) exhibit boosting the catalysts OER activity and stability in acid media. They display superior OER performance with an ultralow overpotential of 240 mV at j = 10 mA cm(-2) and long-term stability of 70 h in acid media. The TOFs of 1.13 and 6.70 s(-1) at an overpotential of 300 and 370 mV also confirm their remarkable performance. Density functional theory (DFT) calculations reveal that the prominent OER performance arises from the surface electronic exchange-andtransfer activities contributed by atomic Ir incorporation on the intrinsic V-o existed NiCo2O4 surface. The atomic Ir sites substantially elevate the electronic activity of surface lower coordinated Co sites nearby V-o, which facilitate the surface electronic exchange-and-transfer capabilities. With this trend, the preferred H2O activation and stabilized *O have been reached toward competitively lower overpotential. This is a generalized key for optimally boosting OER performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2020, "Volume": 142, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18378, "End Page": 18386, "Article Number": null, "DOI": "10.1021/jacs.0c05050", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c05050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582673500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XX; Guo, LZ; Xu, X; Shang, SB; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xinxin; Guo, Lizhen; Xu, Xu; Shang, Shibin; Liu, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fully bio-based epoxy vitrimer: Self-healing, triple-shape memory and reprocessing triggered by dynamic covalent bond exchange", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vitrimers are a new type of polymers with promising applications in innovativematerials. Epoxidized soybean oil (ESO) is an ideal candidate for vitrimer preparation owing to its abundant epoxy groups. However, preparing plant oil-based vitrimers with high glass transition temperatures (T-g) and strength remains challenging. A novel and fully bio-based vitrimer with a T-g above room temperature was synthesized from ESO and a rosin derivative-fumaropimaric acid (FPA) and exhibited excellent self-healing, shape memory, and reprocessing due to the presence of dynamic covalent bond exchange. The fully bio-based ESO-FPA vitrimer exhibited a T-g of 65 degrees C and a tensile strength of 16 MPa, which resulted from the rigid structure and tricarboxylic groups of FPA. The effect of transesterification reactions on the network structure was confirmed through stress relaxation. Our work expands the applications of commercial ESO in vitrimer materials and provides a novel approach to prepare bio-based vitrimers with desirable properties. (C) 2019 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2020, "Volume": 186, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108248, "DOI": "10.1016/j.matdes.2019.108248", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2019.108248", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000505221700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, B; Li, GW; Cao, ER; Luo, JL; Zhao, X; Huang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Ben; Li, Guowei; Cao, Ertai; Luo, Jinlong; Zhao, Xin; Huang, Heyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress of antibacterial hydrogels in wound dressings", "Source Title": "MATERIALS TODAY BIO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are essential biomaterials due to their favorable biocompatibility, mechanical properties similar to human soft tissue extracellular matrix, and tissue repair properties. In skin wound repair, hydrogels with antibacterial functions are especially suitable for dressing applications, so novel antibacterial hydrogel wound dressings have attracted widespread attention, including the design of components, optimization of preparation methods, strategies to reduce bacterial resistance, etc. In this review, we discuss the fabrication of antibacterial hydrogel wound dressings and the challenges associated with the crosslinking methods and chemistry of the materials. We have investigated the advantages and limitations (antibacterial effects and antibacterial mechanisms) of different antibacterial components in the hydrogels to achieve good antibacterial properties, and the response of hydrogels to stimuli such as light, sound, and electricity to reduce bacterial resistance. Conclusively, we provide a systematic summary of antibacterial hydrogel wound dressings findings (crosslinking methods, antibacterial components, antibacterial methods) and an outlook on long-lasting antibacterial effects, a broader antibacterial spectrum, diversified hydrogel forms, and the future development prospects of the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100582, "DOI": "10.1016/j.mtbio.2023.100582", "DOI Link": "http://dx.doi.org/10.1016/j.mtbio.2023.100582", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000951460200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, WX; Scott, TF; Kloxin, CJ; Bowman, CN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Weixian; Scott, Timothy F.; Kloxin, Christopher J.; Bowman, Christopher N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Click Chemistry in Materials Science", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite originating only a little more than a decade ago, click chemistry has become one of the most powerful paradigms in materials science, synthesis, and modification. By developing and implementing simple, robust chemistries that do not require difficult separations or harsh conditions, the ability to form, modify, and control the structure of materials on various length scales has become more broadly available to those in the materials science community. As such, click chemistry has seen broad implementation in polymer functionalization, surface modification, block copolymer and dendrimer synthesis, biomaterials fabrication, biofunctionalization, and in many other areas of materials science. Here, the basic reactions, approaches, and applications of click chemistry in materials science are highlighted, and a brief look is taken into the future enabling developments in this field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 530, "Times Cited, All Databases": 589, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 24, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2572, "End Page": 2590, "Article Number": null, "DOI": "10.1002/adfm.201302847", "DOI Link": "http://dx.doi.org/10.1002/adfm.201302847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335978900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bandodkar, AJ; Gutruf, P; Choi, J; Lee, K; Sekine, Y; Reeder, JT; Jeang, WJ; Aranyosi, AJ; Lee, SP; Model, JB; Ghaffari, R; Su, CJ; Leshock, JP; Ray, T; Verrillo, A; Thomas, K; Krishnamurthi, V; Han, S; Kim, J; Krishnull, S; Hang, T; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bandodkar, Amay J.; Gutruf, Philipp; Choi, Jungil; Lee, KunHyuck; Sekine, Yurina; Reeder, Jonathan T.; Jeang, William J.; Aranyosi, Alexander J.; Lee, Stephen P.; Model, Jeffrey B.; Ghaffari, Roozbeh; Su, Chun-Ju; Leshock, John P.; Ray, Tyler; Verrillo, Anthony; Thomas, Kyle; Krishnamurthi, Vaishnavi; Han, Seungyong; Kim, Jeonghyun; Krishnull, Siddharth; Hang, Tao; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Battery-free, skin-interfaced microfluidic/electronic systems for simultaneous electrochemical, colorimetric, and volumetric analysis of sweat", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sweat sensors rely either on electronics for electrochemical detection or on colorimetry for visual readout. Non-ideal form factors represent disadvantages of the former, while semiquantitative operation and narrow scope of measurable biomarkers characterize the latter. Here, we introduce a battery-free, wireless electronic sensing platform inspired by biofuel cells that integrates chronometric microfluidic platforms with embedded colorimetric assays. The resulting sensors combine advantages of electronic and microfluidic functionality in a platform that is significantly lighter, cheaper, and smaller than alternatives. A demonstration device simultaneously monitors sweat rate/loss, pH, lactate, glucose, and chloride. Systematic studies of the electronics, microfluidics, and integration schemes establish the key design considerations and performance attributes. Two-day human trials that compare concentrations of glucose and lactate in sweat and blood suggest a potential basis for noninvasive, semi-quantitative tracking of physiological status.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 548, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav3294", "DOI": "10.1126/sciadv.aav3294", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav3294", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457547900059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, M; Cai, SH; Pan, C; Wang, CY; Lian, XJ; Zhuo, Y; Xu, K; Cao, TJ; Pan, XQ; Wang, BG; Liang, SJ; Yang, JJ; Wang, P; Miao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Miao; Cai, Songhua; Pan, Chen; Wang, Chenyu; Lian, Xiaojuan; Zhuo, Ye; Xu, Kang; Cao, Tianjun; Pan, Xiaoqing; Wang, Baigeng; Liang, Shi-Jun; Yang, J. Joshua; Wang, Peng; Miao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust memristors based on layered two-dimensional materials", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals heterostructures are formed by stacking layers of different two-dimensional materials and offer the possibility to design new materials with atomic-level precision. By combining the valuable properties of different 2D systems, such heterostructures could potentially be used to address existing challenges in the development of electronic devices, particularly those that require vertical multi-layered structures. Here we show that robust memristors with good thermal stability, which is lacking in traditional memristors, can be created from a van der Waals heterostructure composed of graphene/MoS2-xOx/graphene. The devices exhibit excellent switching performance with an endurance of up to 10(7) and a high operating temperature of up to 340 degrees C. With the help of in situ electron microscopy, we show that the thermal stability is due to the MoS2-xOx switching layer, as well as the graphene electrodes and the atomically sharp interface between the electrodes and the switching layer. We also show that the devices have a well-defined conduction channel and a switching mechanism that is based on the migration of oxygen ions. Finally, we demonstrate that the memristor devices can be fabricated on a polyimide substrate and exhibit good endurance against over 1,000 bending cycles, illustrating their potential for flexible electronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 627, "Times Cited, All Databases": 659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 130, "End Page": 136, "Article Number": null, "DOI": "10.1038/s41928-018-0021-4", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0021-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444072900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halder, A; Ghosh, M; Khayum, MA; Bera, S; Addicoat, M; Sasmal, HS; Karak, S; Kurungot, S; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halder, Arjun; Ghosh, Meena; Khayum, Abdul M.; Bera, Saibal; Addicoat, Matthew; Sasmal, Himadri Sekhar; Karak, Suvendu; Kurungot, Sreekumar; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interlayer Hydrogen-Bonded Covalent Organic Frameworks as High-Performance Supercapacitors", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) have emerged as promising electrode materials in supercapacitors (SCs). However, their insoluble powder-like nature, poor capacitive performance in pristine form, integrated with inferior electrochemical stability is a primary concern for their long-term use in electrochemical devices. Keeping this in perspective, herein we report a redox active and hydrogen bonded COF with ultrahigh stability in conc. H2SO4 (18 M), conc. HCl (12 M) and NaOH (9 M). The as-synthesized COF fabricated as thin sheets were efficiently employed as a free-standing supercapacitor electrode material using 3 M aq. H2SO4 as an electrolyte. Moreover, the pristine COF sheet showcased outstanding areal capacitance 1600 mF cm(-2) (gravimetric 169 F g(-1)) and excellent cyclic stability (>100 000) without compromising its capacitive performance or Coulombic efficiency. Moreover, as a proof-of-concept, a solid-state supercapacitor device was also assembled and subsequently tested.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2018, "Volume": 140, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10941, "End Page": 10945, "Article Number": null, "DOI": "10.1021/jacs.8b06460", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b06460", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444219100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, D; Yang, G; Abo-Dief, HM; Dong, JW; Su, FM; Liu, CT; Li, YF; Xu, BB; Murugadoss, V; Naik, N; El-Bahy, SM; El-Bahy, ZM; Huang, MA; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Duo; Yang, Gui; Abo-Dief, Hala M.; Dong, Jingwen; Su, Fengmei; Liu, Chuntai; Li, Yifan; Xu, Ben Bin; Murugadoss, Vignesh; Naik, Nithesh; El-Bahy, Salah M.; El-Bahy, Zeinhom M.; Huang, Minull; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertically Aligned Silicon Carbide nullowires/ Boron Nitride Cellulose Aerogel Networks Enhanced Thermal Conductivity and Electromagnetic Absorbing of Epoxy Composites", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the innovation of microelectronics technology, the heat dissipation problem inside the device will face a severe test. In this work, cellulose aerogel (CA) with highly enhanced thermal conductivity (TC) in vertical planes was successfully obtained by constructing a vertically aligned silicon carbide nullowires (SiC NWs)/boron nitride (BN) network via the ice template-assisted strategy. The unique network structure of SiC NWs connected to BN ensures that the TC of the composite in the vertical direction reaches 2.21 W m(-1) K-1 at a low hybrid filler loading of 16.69 wt%, which was increased by 890% compared to pure epoxy (EP). In addition, relying on unique porous network structure of CA, EP-based composite also showed higher TC than other comparative samples in the horizontal direction. Meanwhile, the composite exhibits good electrically insulating with a volume electrical resistivity about 2.35 x 1011 Omega cm and displays excellent electromagnetic wave absorption performance with a minimum reflection loss of - 21.5 dB and a wide effective absorption bandwidth (< - 10 dB) from 8.8 to 11.6 GHz. Therefore, this work provides a new strategy for manufacturing polymer-based composites with excellent multifunctional performances in microelectronic packaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118, "DOI": "10.1007/s40820-022-00863-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00863-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789072200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, R; Liang, ZB; Zou, RQ; Xu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ruo; Liang, Zibin; Zou, Ruqiang; Xu, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) and their derivatives are two developing families of functional materials for energy storage and conversion. Their high porosity, versatile functionalities, diverse structures, and controllable chemical compositions offer immense possibilities in the search for adequate electrode materials for rechargeable batteries. Despite these advantageous features, MOFs and their derivatives as electrode materials face various challenging issues, which impede their practical applications. From this perspective, we present both the opportunities and challenges that MOFs/MOF composites and MOF-derived materials bring to rechargeable batteries, including lithium-ion batteries, lithium-sulfur batteries, lithium-oxygen batteries, and sodium-ion batteries. By discussing the development of MOFs/MOF composites and MOF-derived materials in each battery system, some design principles that dominate the specific electrochemical behaviors are outlined, with the key requirements that a practical electrode should fulfill At the end, a basic guidance and future directions for further development are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 500, "Times Cited, All Databases": 521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2018, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2235, "End Page": 2259, "Article Number": null, "DOI": "10.1016/j.joule.2018.09.019", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.09.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450940600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QQ; Shen, JY; Yu, XH; Yang, XF; Liu, W; Yang, J; Tang, H; Xu, H; Li, HM; Li, YY; Xu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qinqin; Shen, Jiyou; Yu, Xiaohui; Yang, Xiaofei; Liu, Wei; Yang, Juan; Tang, Hua; Xu, Hui; Li, Huaming; Li, Youyong; Xu, Jingsan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the origin of boosted photocatalytic hydrogen evolution in simultaneously (S, P, O)-Codoped and exfoliated ultrathin g-C3N4 nullosheets", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, metal-free graphitic carbon nitride (g-C3N4) has been recognized as a potential candidate for high-performance photocatalytic hydrogen production while challenges still remain due to poor electronic properties and limited surface active sites. We demonstrate that g-C(3)N(4)can be simultaneously co-doped with S, P and O nonmetal-atoms and exfoliated into ultrathin 2D nullosheets with a thickness of similar to 3 nm by a simple, sequential thermal synthesis. The multi-atoms doping and nullostructure modulation remarkably enhanced the photocatalytic hydrogen production under illumination, with the optimal H-2 evolution rate reaching 2480 mu mol g(-1) h(-1). First-principle calculations and experimental evidences suggest that, upon elemental doping within the g-C(3)N(4 )framework, S atoms occupied the interstitial sites and P and O atoms replaced the C and N atoms, respectively. Consequently, photo-induced charge transfer and separation significantly improved owing to the construction of a more favorable charge transfer pathway. Furthermore, introducing heteroatoms into the structure of g-C3N4 narrowed the bandgap and negatively shifted the conduction band edge, leading to extended visible-light absorption and stronger electron reducibility for subsequent H-2 production. Importantly, the in-situ generated 2D g-C3N4 nullosheets exhibited more catalytic surface sites, which was highly beneficial to the photocatalytic water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2019, "Volume": 248, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 84, "End Page": 94, "Article Number": null, "DOI": "10.1016/j.apcatb.2019.02.020", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2019.02.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463126200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Radha, B; Esfandiar, A; Wang, FC; Rooney, AP; Gopinadhan, K; Keerthi, A; Mishchenko, A; Janardanull, A; Blake, P; Fumagalli, L; Lozada-Hidalgo, M; Garaj, S; Haigh, SJ; Grigorieva, IV; Wu, HA; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Radha, B.; Esfandiar, A.; Wang, F. C.; Rooney, A. P.; Gopinadhan, K.; Keerthi, A.; Mishchenko, A.; Janardanull, A.; Blake, P.; Fumagalli, L.; Lozada-Hidalgo, M.; Garaj, S.; Haigh, S. J.; Grigorieva, I. V.; Wu, H. A.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular transport through capillaries made with atomic-scale precision", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullometre-scale pores and capillaries have long been studied because of their importance in many natural phenomena and their use in numerous applications(1). A more recent development is the ability to fabricate artificial capillaries with nullometre dimensions, which has enabled new research on molecular transport and led to the emergence of nullofluidics(2-4). But surface roughness in particular makes it challenging to produce capillaries with precisely controlled dimensions at this spatial scale. Here we report the fabrication of narrow and smooth capillaries through van der Waals assembly(5), with atomically flat sheets at the top and bottom separated by spacers made of two-dimensional crystals(6) with a precisely controlled number of layers. We use graphene and its multilayers as archetypal two-dimensional materials to demonstrate this technology, which produces structures that can be viewed as if individual atomic planes had been removed from a bulk crystal to leave behind flat voids of a height chosen with atomic-scale precision. Water transport through the channels, ranging in height from one to several dozen atomic planes, is characterized by unexpectedly fast flow (up to 1 metre per second) that we attribute to high capillary pressures (about 1,000 bar) and large slip lengths. For channels that accommodate only a few layers of water, the flow exhibits a marked enhancement that we associate with an increased structural order in nulloconfined water. Our work opens up an avenue to making capillaries and cavities with sizes tunable to angstrom precision, and with permeation properties further controlled through a wide choice of atomically flat materials available for channel walls.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 557, "Times Cited, All Databases": 592, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2016, "Volume": 538, "Issue": 7624, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature19363", "DOI Link": "http://dx.doi.org/10.1038/nature19363", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386671000040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, S; Huang, XL; Ma, DL; Wang, HG; Meng, FZ; Zhang, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Shuang; Huang, Xiao-lei; Ma, De-long; Wang, Heng-guo; Meng, Fan-zhi; Zhang, Xin-bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engraving Copper Foil to Give Large-Scale Binder-Free Porous CuO Arrays for a High-Performance Sodium-Ion Battery Anode", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 26, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2273, "End Page": 2279, "Article Number": null, "DOI": "10.1002/adma.201304469", "DOI Link": "http://dx.doi.org/10.1002/adma.201304469", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334398400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, M; Li, S; Wang, Y; Herron, JA; Xu, Y; Allard, LF; Lee, S; Huang, J; Mavrikakis, M; Flytzani-Stephanopoulos, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Ming; Li, Sha; Wang, Yuan; Herron, Jeffrey A.; Xu, Ye; Allard, Lawrence F.; Lee, Sungsik; Huang, Jun; Mavrikakis, Manos; Flytzani-Stephanopoulos, Maria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytically active Au-O(OH)x-species stabilized by alkali ions on zeolites and mesoporous oxides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report that the addition of alkali ions (sodium or potassium) to gold on KLTL-zeolite and mesoporous MCM-41 silica stabilizes mononuclear gold in Au-O(OH)(x)-(Na or K) ensembles. This single-site gold species is active for the low-temperature (<200 degrees C) water-gas shift (WGS) reaction. Unexpectedly, gold is thus similar to platinum in creating -O linkages with more than eight alkali ions and establishing an active site on various supports. The intrinsic activity of the single-site gold species is the same on irreducible supports as on reducible ceria, iron oxide, and titania supports, apparently all sharing a common, similarly structured gold active site. This finding paves the way for using earth-abundant supports to disperse and stabilize precious metal atoms with alkali additives for the WGS and potentially other fuel-processing reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 550, "Times Cited, All Databases": 596, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2014, "Volume": 346, "Issue": 6216, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1498, "End Page": 1501, "Article Number": null, "DOI": "10.1126/science.1260526", "DOI Link": "http://dx.doi.org/10.1126/science.1260526", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346536500060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parastaev, A; Muravev, V; Osta, EH; van Hoof, AJF; Kimpel, TF; Kosinov, N; Hensen, EJM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parastaev, Alexander; Muravev, Valery; Osta, Elisabet Huertas; van Hoof, Arno J. F.; Kimpel, Tobias F.; Kosinov, Nikolay; Hensen, Emiel J. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting CO2 hydrogenation via size-dependent metal-support interactions in cobalt/ceria-based catalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-support interactions have a strong impact on the performance of heterogeneous catalysts. Specific sites at the metal-support interface can give rise to unusual high reactivity, and there is a growing interest in optimizing not only the properties of metal particles but also the metal-support interface. Here, we demonstrate how varying the particle size of the support (ceria-zirconia) can be used to tune the metal-support interactions, resulting in a substantially enhanced CO2 hydrogenation rate. A combination of X-ray diffraction, X-ray absorption spectroscopy, near-ambient pressure X-ray photoelectron spectroscopy, transmission electron microscopy and infrared spectroscopy provides insight into the active sites at the interface between cobalt and ceria-zirconia involved in CO2 hydrogenation to CH4. Reverse oxygen spillover from the support during treatment in hydrogen results in the generation of oxygen vacancies. Stabilization of cobalt particles by ceria-zirconia particles of intermediate size leads to oxygen spillover to the support during the CO2 and CO dissociation steps, followed by further hydrogenation of the resulting intermediates on cobalt. Metal-support interactions can effectively modify the catalytic properties of heterogeneous composites. Here, the authors report the possibility of controlling the interaction between cobalt and a ceria-zirconia support by changing the particle size of the latter, resulting in a superior CO2 hydrogenation system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": 533, "Article Number": null, "DOI": "10.1038/s41929-020-0459-4", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0459-4", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531778200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Shi, CY; Qu, DH; Long, YT; Feringa, B; Tian, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qi; Shi, Chen-Yu; Qu, Da-Hui; Long, Yi-Tao; Feringa, Ben L.; Tian, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring a naturally tailored small molecule for stretchable, self-healing, and adhesive supramolecular polymers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymeric materials with integrated functionalities are required to match their ever-expanding practical applications, but there is always a trade-off between complex material performances and synthetic simplification. A simple and effective synthesis route is reported to transform a small molecule of biological origin, thioctic acid, into a high-performance supramolecular polymeric material, which combines processability, ultrahigh stretchability, rapid self-healing ability, and reusable adhesivity to surfaces. The proposed one-step preparation process of this material involves the mixing of three commercially available feedstocks at mild temperature without any external solvent and a subsequent cooling process that resulted in a dynamic, high-density, and dry supramolecular polymeric network cross-linked by three different types of dynamic chemical bonds, whose cooperative effects in the network enable high performance of this supramolecular polymeric material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 550, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat8192", "DOI": "10.1126/sciadv.aat8192", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat8192", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moore, AL; Shi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moore, Arden L.; Shi, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging challenges and materials for thermal management of electronics", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid development of faster, cheaper, and more powerful computing has led to some of the most important technological and societal advances in modern history. However, the physical means associated with enhancing computing capabilities at the device and die levels have also created a very challenging set of circumstances for keeping electronic devices cool, a critical factor in determining their speed, efficiency, and reliability. With advances in nulloelectronics and the emergence of new application areas such as three-dimensional chip stack architectures and flexible electronics, now more than ever there are both needs and opportunities for novel materials to help address some of these pressing thermal management challenges. In this paper a number of cubic crystals, two-dimensional layered materials, nullostructure networks and composites, molecular layers and surface functionalization, and aligned polymer structures are examined for potential applications as heat spreading layers and substrates, thermal interface materials, and underfill materials in future-generation electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1564, "Times Cited, All Databases": 1726, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 17, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 163, "End Page": 174, "Article Number": null, "DOI": "10.1016/j.mattod.2014.04.003", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.04.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336479600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feaster, JT; Shi, C; Cave, ER; Hatsukade, TT; Abram, DN; Kuhl, KP; Hahn, C; Norskov, JK; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feaster, Jeremy T.; Shi, Chuan; Cave, Etosha R.; Hatsukade, Tom T.; Abram, David N.; Kuhl, Kendra P.; Hahn, Christopher; Norskov, Jens K.; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increases in energy demand and in chemical production, together with the rise in CO2 levels in the atmosphere, motivate the development of renewable energy sources. Electrochemical CO2 reduction to fuels and chemicals is an appealing alternative to traditional pathways to fuels and chemicals due to its intrinsic ability to couple to solar and wind energy sources. Formate (HCOO-) is a key chemical for many industries; however, greater understanding is needed regarding the mechanism and key intermediates for HCOO- production. This work reports a joint experimental and theoretical investigation of the electrochemical reduction of CO2 to HCOO- on polycrystalline Sn surfaces, which have been identified as promising catalysts for selectively producing HCOO-. Our results show that Sn electrodes produce HCOO-, carbon monoxide (CO), and hydrogen (H-2) across a range of potentials and that HCOO- production becomes favored at potentials more negative than -0.8 V vs RHE, reaching a maximum Faradaic efficiency of 70% at -0.9 V vs RHE. Scaling relations for Sn and other transition metals are examined using experimental current densities and density functional theory (DFT) binding energies. While *COOH was determined to be the key intermediate for CO production on metal surfaces, we suggest that it is unlikely to be the primary intermediate for HCOO- production. Instead, *OCHO is suggested to be the key intermediate for the CO2RR to HCOO- transformation, and Sn's optimal *OCHO binding energy supports its high selectivity for HCOO-. These results suggest that oxygen-bound intermediates are critical to understand the mechanism of CO2 reduction to HCOO- on metal surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 736, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4822, "End Page": 4827, "Article Number": null, "DOI": "10.1021/acscatal.7b00687", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b00687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405360800075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Hsu, PC; Lee, HW; Ye, M; Zheng, GY; Liu, NA; Li, WY; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chong; Hsu, Po-Chun; Lee, Hyun-Wook; Ye, Meng; Zheng, Guangyuan; Liu, Nian; Li, Weiyang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent air filter for high-efficiency PM2.5 capture", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Particulate matter (PM) pollution has raised serious concerns for public health. Although outdoor individual protection could be achieved by facial masks, indoor air usually relies on expensive and energy-intensive air-filtering devices. Here, we introduce a transparent air filter for indoor air protection through windows that uses natural passive ventilation to effectively protect the indoor air quality. By controlling the surface chemistry to enable strong PM adhesion and also the microstructure of the air filters to increase the capture possibilities, we achieve transparent, high air flow and highly effective air filters of similar to 90% transparency with >95.00% removal of PM2.5 under extreme hazardous air-quality conditions (PM2.5 mass concentration >250 mu g m(-3)). A field test in Beijing shows that the polyacrylonitrile transparent air filter has the best PM2.5 removal efficiency of 98.69% at high transmittance of similar to 77% during haze occurrence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 837, "Times Cited, All Databases": 901, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6205, "DOI": "10.1038/ncomms7205", "DOI Link": "http://dx.doi.org/10.1038/ncomms7205", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350201100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YW; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yawen; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Highly Uniform Molybdenum-Glycerate Spheres and Their Conversion into Hierarchical MoS2 Hollow nullospheres for Lithium-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly uniform Mo-glycerate solid spheres are synthesized for the first time through a solvothermal process. The size of these Mo-glycerate spheres can be easily controlled in the range of 400-1000 nm by varying the water content in the mixed solvent. As a precursor, these Mo-glycerate solid spheres can be converted into hierarchical MoS2 hollow nullospheres through a subsequent sulfidation reaction. Owing to the unique ultrathin subunits and hollow interior, the as-prepared MoS2 hollow nullospheres exhibit appealing performance as the anode material for lithium-ion batteries. Impressively, these hierarchical structures deliver a high capacity of about 1100 mAh g(-1) at 0.5 A g(-1) with good rate retention and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2016, "Volume": 55, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7423, "End Page": 7426, "Article Number": null, "DOI": "10.1002/anie.201601673", "DOI Link": "http://dx.doi.org/10.1002/anie.201601673", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383077400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, MR; Liang, JX; Zheng, YR; Xu, YF; Jiang, J; Gao, Q; Li, J; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Min-Rui; Liang, Jin-Xia; Zheng, Ya-Rong; Xu, Yun-Fei; Jiang, Jun; Gao, Qiang; Li, Jun; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An efficient molybdenum disulfide/cobalt diselenide hybrid catalyst for electrochemical hydrogen generation", "Source Title": "Nature Communications", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electroreduction of water for sustainable hydrogen production is a critical component of several developing clean-energy technologies, such as water splitting and fuel cells. However, finding a cheap and efficient alternative catalyst to replace currently used platinum-based catalysts is still a prerequisite for the commercialization of these technologies. Here we report a robust and highly active catalyst for hydrogen evolution reaction that is constructed by in situ growth of molybdenum disulfide on the surface of cobalt diselenide. In acidic media, the molybdenum disulfide/cobalt diselenide catalyst exhibits fast hydrogen evolution kinetics with onset potential of - 11mV and Tafel slope of 36 mV per decade, which is the best among the non-noble metal hydrogen evolution catalysts and even approaches to the commercial platinum/carbon catalyst. The high hydrogen evolution activity of molybdenum disulfide/cobalt diselenide hybrid is likely due to the electrocatalytic synergistic effects between hydrogen evolution-active molybdenum disulfide and cobalt diselenide materials and the much increased catalytic sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 620, "Times Cited, All Databases": 668, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5982, "DOI": "10.1038/ncomms6982", "DOI Link": "http://dx.doi.org/10.1038/ncomms6982", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348829000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JZ; Sheng, HY; Ross, RD; Han, JC; Wang, XJ; Song, B; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jinzhen; Sheng, Hongyuan; Ross, R. Dominic; Han, Jiecai; Wang, Xianjie; Song, Bo; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modifying redox properties and local bonding of Co3O4 by CeO2 enhances oxygen evolution catalysis in acid", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution reaction is the bottleneck for water splitting using proton exchange membrane electrolyzers. Here, we show that nullocrystalline CeO2 in a Co3O4/CeO2 nullocomposite can modify the redox properties of Co3O4 and enhances its intrinsic oxygen evolution reaction activity, and combine electrochemical and structural characterizations including kinetic isotope effect, pH- and temperature-dependence, in situ Raman and ex situ X-ray absorption spectroscopy analyses to understand the origin. The local bonding environment of Co3O4 can be modified after the introduction of nullocrystalline CeO2, which allows the Co-III species to be easily oxidized into catalytically active Co-IV species, bypassing the potential-determining surface reconstruction process. Co3O4/CeO2 displays a comparable stability to Co3O4 thus breaks the activity/stability tradeoff. This work not only establishes an efficient earth-abundant catalysts for acidic oxygen evolution reaction, but also provides strategies for designing more active catalysts for other reactions. Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution reaction is challenging. Here, the authors modify the local bonding environment of Co3O4 by CeO2 nullocrystallites to regulate the redox properties, thus enhance the catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3036, "DOI": "10.1038/s41467-021-23390-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23390-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658769300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, HJ; Zhao, SL; Zhao, K; Muqsit, A; Tang, HJ; Chang, L; Zhao, HJ; Gao, Y; Tang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Huajie; Zhao, Shenlong; Zhao, Kun; Muqsit, Abdul; Tang, Hongjie; Chang, Lin; Zhao, Huijun; Gao, Yan; Tang, Zhiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin platinum nullowires grown on single-layered nickel hydroxide with high hydrogen evolution activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design and synthesis of effective electrocatalysts for hydrogen evolution reaction in alkaline environments is critical to reduce energy losses in alkaline water electrolysis. Here we report a hybrid nullomaterial comprising of one-dimensional ultrathin platinum nullowires grown on two-dimensional single-layered nickel hydroxide. Judicious surface chemistry to generate the fully exfoliated nickel hydroxide single layers is explored to be the key for controllable growth of ultrathin platinum nullowires with diameters of about 1.8 nm. Impressively, this hybrid nullomaterial exhibits superior electrocatalytic activity for hydrogen evolution reaction in alkaline solution, which outperforms currently reported catalysts, and the obviously improved catalytic stability. We believe that this work may lead towards the development of single-layered metal hydroxide-based hybrid materials for applications in catalysis and energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 890, "Times Cited, All Databases": 923, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6430, "DOI": "10.1038/ncomms7430", "DOI Link": "http://dx.doi.org/10.1038/ncomms7430", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352633900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naguib, M; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naguib, Michael; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ten Years of Progress in the Synthesis and Development of MXenes", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since their discovery in 2011, the number of 2D transition metal carbides and nitrides (MXenes) has steadily increased. Currently more than 40 MXene compositions exist. The ultimate number is far greater and in time they may develop into the largest family of 2D materials known. MXenes' unique properties, such as their metal-like electrical conductivity reaching approximate to 20 000 S cm(-1), render them quite useful in a large number of applications, including energy storage, optoelectronic, biomedical, communications, and environmental. The number of MXene papers and patents published has been growing quickly. The first MXene generation is synthesized using selective etching of metal layers from the MAX phases, layered transition metal carbides and carbonitrides using hydrofluoric acid. Since then, multiple synthesis approaches have been developed, including selective etching in a mixture of fluoride salts and various acids, non-aqueous etchants, halogens, and molten salts, allowing for the synthesis of new MXenes with better control over their surface chemistries. Herein, a brief historical overview of the first 10 years of MXene research and a perspective on their synthesis and future development are provided. The fact that their production is readily scalable in aqueous environments, with high yields bodes well for their commercialization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 833, "Times Cited, All Databases": 867, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 33, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103393, "DOI": "10.1002/adma.202103393", "DOI Link": "http://dx.doi.org/10.1002/adma.202103393", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000685973200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, LL; Poddar, S; Lin, YJ; Long, ZH; Zhang, DQ; Zhang, QP; Shu, L; Qiu, X; Kam, M; Javey, A; Fan, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Leilei; Poddar, Swapnadeep; Lin, Yuanjing; Long, Zhenghao; Zhang, Daquan; Zhang, Qianpeng; Shu, Lei; Qiu, Xiao; Kam, Matthew; Javey, Ali; Fan, Zhiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A biomimetic eye with a hemispherical perovskite nullowire array retina", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A biomimetic electrochemical eye is presented that has a hemispherical retina made from a high-density array of perovskite nullowires that are sensitive to light, mimicking the photoreceptors of a biological retina. Human eyes possess exceptional image-sensing characteristics such as an extremely wide field of view, high resolution and sensitivity with low aberration(1). Biomimetic eyes with such characteristics are highly desirable, especially in robotics and visual prostheses. However, the spherical shape and the retina of the biological eye pose an enormous fabrication challenge for biomimetic devices(2,3). Here we present an electrochemical eye with a hemispherical retina made of a high-density array of nullowires mimicking the photoreceptors on a human retina. The device design has a high degree of structural similarity to a human eye with the potential to achieve high imaging resolution when individual nullowires are electrically addressed. Additionally, we demonstrate the image-sensing function of our biomimetic device by reconstructing the optical patterns projected onto the device. This work may lead to biomimetic photosensing devices that could find use in a wide spectrum of technological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 581, "Issue": 7808, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 278, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2285-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2285-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000534818200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, CT; Bolink, HJ; Han, HW; Huang, JS; Cahen, D; Ding, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Chuantian; Bolink, Henk J.; Han, Hongwei; Huang, Jinsong; Cahen, David; Ding, Liming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in Perovskite Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organolead halide perovskite materials possess a combination of remarkable optoelectronic properties, such as steep optical absorption edge and high absorption coefficients, long charge carrier diffusion lengths and lifetimes. Taken together with the ability for low temperature preparation, also from solution, perovskite-based devices, especially photovoltaic (PV) cells have been studied intensively, with remarkable progress in performance, over the past few years. The combination of high efficiency, low cost and additional (non-PV) applications provides great potential for commercialization. Performance and applications of perovskite solar cells often correlate with their device structures. Many innovative device structures were developed, aiming at large-scale fabrication, reducing fabrication cost, enhancing the power conversion efficiency and thus broadening potential future applications. This review summarizes typical structures of perovskite solar cells and comments on novel device structures. The applications of perovskite solar cells are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 548, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500324, "DOI": "10.1002/advs.201500324", "DOI Link": "http://dx.doi.org/10.1002/advs.201500324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379935500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, J; Liao, L; Shi, FF; Lei, T; Chen, GX; Pei, A; Sun, J; Yan, K; Zhou, GM; Xie, J; Liu, C; Li, YZ; Liang, Z; Bao, ZN; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jie; Liao, Lei; Shi, Feifei; Lei, Ting; Chen, Guangxu; Pei, Allen; Sun, Jie; Yan, Kai; Zhou, Guangmin; Xie, Jin; Liu, Chong; Li, Yuzhang; Liang, Zheng; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Significant increases in the energy density of batteries must be achieved by exploring new materials and cell configurations. Lithium metal and, lithiated silicon are two promising high-capacity anode materials. Unfortunately, both of these anodes require a reliable passivating layer to survive the serious environmental corrosion during handling and cycling. Here we developed a surface fluorination process to form a homogeneous and dense LiF coating on reactive anode materials, with in situ generated fluorine gas, by using a fluoropolymer, CYTOP, as the precursor. The process is effectively a reaction in the beaker, avoiding direct handling of highly toxic fluorine gas. For lithium metal, this LiF coating serves as a chemically stable and mechanically strong interphase, which minimizes: the reaction with carbonate electrolytes and suppresses dendrite formation, enabling dendrite-free and stable cycling over 300 cycles with current densities up to 5 mA/cm(2). Lithiated silicon can serve as either a pre-lithiation additive, for existing lithium-ion batteries or-a replacement for lithium metal in Li-O-2, and Li-S batteries. However, lithiated silicon reacts vigorously with the standard slurry solvent,N-methyl-2-pyrrolidinone (NMP), indicating it is not compatible with the real battery fabrication process. With the protection-of crystalline and dense LiF coating, LixSi can be processed in anhydrous NMP with a high capacity of 2504 mAh/g. With low solubility of LiF in water, this protection layer also allows LixSi to be stable in humid air (similar to 40% relative humidity). Therefore; this facile surface fluorination process brings huge benefit to both the existing lithium-ion batteries and next-generation lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 433, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2017, "Volume": 139, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11550, "End Page": 11558, "Article Number": null, "DOI": "10.1021/jacs.7b05251", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b05251", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408519600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grancini, G; Roldán-Carmona, C; Zimmermann, I; Mosconi, E; Lee, X; Martineau, D; Narbey, S; Oswald, F; De Angelis, F; Graetzel, M; Nazeeruddin, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grancini, G.; Roldan-Carmona, C.; Zimmermann, I.; Mosconi, E.; Lee, X.; Martineau, D.; Narbey, S.; Oswald, F.; De Angelis, F.; Graetzel, M.; Nazeeruddin, Mohammad Khaja", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Year stable perovskite solar cells by 2D/3D interface engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the impressive photovoltaic performances with power conversion efficiency beyond 22%, perovskite solar cells are poorly stable under operation, failing by far the market requirements. Various technological approaches have been proposed to overcome the instability problem, which, while delivering appreciable incremental improvements, are still far from a market-proof solution. Here we show one-year stable perovskite devices by engineering an ultra-stable 2D/3D (HOOC(CH2)(4)NH3)(2)PbI4/CH3NH3PbI3 perovskite junction. The 2D/3D forms an exceptional gradually-organized multi-dimensional interface that yields up to 12.9% efficiency in a carbon-based architecture, and 14.6% in standard mesoporous solar cells. To demonstrate the up-scale potential of our technology, we fabricate 10 x 10 cm(2) solar modules by a fully printable industrial-scale process, delivering 11.2% efficiency stable for >10,000 h with zero loss in performances measured under controlled standard conditions. This innovative stable and low-cost architecture will enable the timely commercialization of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1255, "Times Cited, All Databases": 1262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15684, "DOI": "10.1038/ncomms15684", "DOI Link": "http://dx.doi.org/10.1038/ncomms15684", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402524300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ZD; Wang, R; Peng, CX; Chen, WJ; Wu, TQ; Hu, B; Weng, WJ; Yao, Y; Zeng, JX; Chen, ZH; Liu, PY; Liu, YC; Li, GS; Guo, J; Lu, HB; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Zedong; Wang, Rong; Peng, Chengxin; Chen, Wuji; Wu, Tianqi; Hu, Bo; Weng, Weijun; Yao, Ying; Zeng, Jiaxi; Chen, Zhihong; Liu, Peiying; Liu, Yicheng; Li, Guisheng; Guo, Jia; Lu, Hongbin; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Horizontally arranged zinc platelet electrodeposits modulated by fluorinated covalent organic framework film for high-rate and durable aqueous zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries (RZIBs) provide a promising complementarity to the existing lithium-ion batteries due to their low cost, non-toxicity and intrinsic safety. However, Zn anodes suffer from zinc dendrite growth and electrolyte corrosion, resulting in poor reversibility. Here, we develop an ultrathin, fluorinated two-dimensional porous covalent organic framework (FCOF) film as a protective layer on the Zn surface. The strong interaction between fluorine (F) in FCOF and Zn reduces the surface energy of the Zn (002) crystal plane, enabling the preferred growth of (002) planes during the electrodeposition process. As a result, Zn deposits show horizontally arranged platelet morphology with (002) orientations preferred. Furthermore, F-containing nullochannels facilitate ion transport and prevent electrolyte penetration for improving corrosion resistance. The FCOF@Zn symmetric cells achieve stability for over 750 h at an ultrahigh current density of 40 mA cm(-2). The high-areal-capacity full cells demonstrate hundreds of cycles under high Zn utilization conditions. Rechargeable aqueous zinc-ion batteries are promising but the zinc anode suffers from dendrite growth and electrolyte corrosion. Here, the authors develop a fluorinated covalent organic framework film as a protective layer for aqueous zinc anode battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 485, "Times Cited, All Databases": 495, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6606, "DOI": "10.1038/s41467-021-26947-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26947-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719546000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, H; Battaglia, C; Carraro, C; Nemsak, S; Ozdol, B; Kang, JS; Bechtel, HA; Desai, SB; Kronast, F; Unal, AA; Conti, G; Conlon, C; Palsson, GK; Martin, MC; Minor, AM; Fadley, CS; Yablonovitch, E; Maboudian, R; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Hui; Battaglia, Corsin; Carraro, Carlo; Nemsak, Slavomir; Ozdol, Burak; Kang, Jeong Seuk; Bechtel, Hans A.; Desai, Sujay B.; Kronast, Florian; Unal, Ahmet A.; Conti, Giuseppina; Conlon, Catherine; Palsson, Gunnar K.; Martin, Michael C.; Minor, Andrew M.; Fadley, Charles S.; Yablonovitch, Eli; Maboudian, Roya; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong interlayer coupling in van der Waals heterostructures built from single-layer chalcogenides", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor heterostructures are the fundamental platform for many important device applications such as lasers, light-emitting diodes, solar cells, and high-electron-mobility transistors. Analogous to traditional heterostructures, layered transition metal dichalcogenide heterostructures can be designed and built by assembling individual single layers into functional multilayer structures, but in principle with atomically sharp interfaces, no interdiffusion of atoms, digitally controlled layered components, and no lattice parameter constraints. Nonetheless, the optoelectronic behavior of this new type of van der Waals (vdW) semiconductor heterostructure is unknown at the single-layer limit. Specifically, it is experimentally unknown whether the optical transitions will be spatially direct or indirect in such heterobilayers. Here, we investigate artificial semiconductor heterostructures built from single-layer WSe2 and MoS2. We observe a large Stokes-like shift of similar to 100 meV between the photoluminescence peak and the lowest absorption peak that is consistent with a type II band alignment having spatially direct absorption but spatially indirect emission. Notably, the photoluminescence intensity of this spatially indirect transition is strong, suggesting strong interlayer coupling of charge carriers. This coupling at the hetero-interface can be readily tuned by inserting dielectric layers into the vdW gap, consisting of hexagonal BN. Consequently, the generic nature of this interlayer coupling provides a new degree of freedom in band engineering and is expected to yield a new family of semiconductor heterostructures having tunable optoelectronic properties with customized composite layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 950, "Times Cited, All Databases": 1060, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2014, "Volume": 111, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6198, "End Page": 6202, "Article Number": null, "DOI": "10.1073/pnas.1405435111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1405435111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335199000035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, QS; Pospischil, A; Bhuiyan, M; Jiang, H; Tian, H; Farmer, D; Deng, BC; Li, C; Han, SJ; Wang, H; Xia, QF; Ma, TP; Mueller, T; Xia, FN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Qiushi; Pospischil, Andreas; Bhuiyan, Maruf; Jiang, Hao; Tian, He; Farmer, Damon; Deng, Bingchen; Li, Cheng; Han, Shu-Jen; Wang, Han; Xia, Qiangfei; Ma, Tso-Ping; Mueller, Thomas; Xia, Fengnian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus Mid-Infrared Photodetectors with High Gain", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, black phosphorus (BP) has joined the two-dimensional material family as a promising candidate for photonic applications due to its moderate bandgap, high carrier mobility, and compatibility with a diverse range of substrates. Photodetectors are probably the most explored BP photonic devices, however, their unique potential compared with other layered materials in the mid-infrared wavelength range has not been revealed. Here, we demonstrate BP mid-infrared detectors at 3.39 mu m with high internal gain, resulting in an external responsivity of 82 A/W. Noise measurements show that such BP photodetectors are capable of sensing mid-infrared light in the picowatt range. Moreover, the high photoresponse remains effective at kilohertz modulation frequencies, because of the fast carrier dynamics arising from BP's moderate bandgap. The high photoresponse at mid-infrared wavelengths and the large dynamic bandwidth, together with its unique polarization dependent response induced by low crystalline symmetry, can be coalesced to promise photonic applications such as chip-scale mid-infrared sensing and imaging at low light levels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 657, "Times Cited, All Databases": 708, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 16, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4648, "End Page": 4655, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b01977", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b01977", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379794200098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Li, WT; Yin, LQ; Liu, YJ; Guo, HZ; Lai, JW; Han, Y; Li, G; Li, M; Zhang, JH; Vajtai, R; Ajayan, PM; Wu, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Liang; Li, Weitao; Yin, Luqiao; Liu, Yijian; Guo, Huazhang; Lai, Jiawei; Han, Yu; Li, Gao; Li, Ming; Zhang, Jianhua; Vajtai, Robert; Ajayan, Pulickel M.; Wu, Minghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-color fluorescent carbon quantum dots", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum dots have innate advantages as the key component of optoelectronic devices. For white light-emitting diodes (WLEDs), the modulation of the spectrum and color of the device often involves various quantum dots of different emission wavelengths. Here, we fabricate a series of carbon quantum dots (CQDs) through a scalable acid reagent engineering strategy. The growing electron-withdrawing groups on the surface of CQDs that originated from acid reagents boost their photoluminescence wavelength red shift and raise their particle sizes, elucidating the quantum size effect. These CQDs emit bright and remarkably stable full-color fluorescence ranging from blue to red light and even white light. Full-color emissive polymer films and all types of high-color rendering index WLEDs are synthesized by mixing multiple kinds of CQDs in appropriate ratios. The universal electron-donating/withdrawing group engineering approach for synthesizing tunable emissive CQDs will facilitate the progress of carbon-based luminescent materials for manufacturing forward-looking films and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 477, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb6772", "DOI": "10.1126/sciadv.abb6772", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb6772", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579157800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Whitesides, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Whitesides, George M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft Robotics", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This description of soft robotics is not intended to be a conventional review, in the sense of a comprehensive technical summary of a developing field. Rather, its objective is to describe soft robotics as a new fieldone that offers opportunities to chemists and materials scientists who like to make things and to work with macroscopic objects that move and exert force. It will give one (personal) view of what soft actuators and robots are, and how this class of soft devices fits into the more highly developed field of conventional hard robotics. It will also suggest how and why soft robotics is more than simply a minor technical tweak on hard robotics and propose a unique role for chemistry, and materials science, in this field. Soft robotics is, at its core, intellectually and technologically different from hard robotics, both because it has different objectives and uses and because it relies on the properties of materials to assume many of the roles played by sensors, actuators, and controllers in hard robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 602, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2018, "Volume": 57, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 4258, "End Page": 4273, "Article Number": null, "DOI": "10.1002/anie.201800907", "DOI Link": "http://dx.doi.org/10.1002/anie.201800907", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429536600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mukherjee, S; Cullen, DA; Karakalos, S; Liu, KX; Zhang, H; Zhao, S; Xu, H; More, KL; Wang, GF; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mukherjee, Shreya; Cullen, David A.; Karakalos, Stavros; Liu, Kexi; Zhang, Hao; Zhao, Shuai; Xu, Hui; More, Karren L.; Wang, Guofeng; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework- derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia (NH3) is considered an important chemical for both agriculture fertilizer and renewable energy. The conventional Haber-Bosh process to produce NH3 is energy intensive and leads to significant CO2 emission. Alternatively, electrochemical synthesis of ammonia (ESA) through the nitrogen reduction reaction (NRR) by using renewable electricity has recently attracted significant attention. Herein, we report a metal-organic framework- derived nitrogen-doped nulloporous carbon as an electrocatalyst for the NRR. It exhibits a remarkable production rate of NH3 up to 3.4x10(-6) mol cm(-2) h(-1) with a Faradaic efficiency (FE) of 10.2% at -0.3 V vs. RHE under room temperature and ambient pressure using aqueous 0.1M KOH electrolyte. Increasing the temperature to 60 degrees C further improves production rates to 7.3x10(-6) mol cm(-2) h(-1). The stability of the nitrogendoped carbon electrocatalyst was demonstrated during an 18-h continuous test with constant production rates. First principles calculations were used to elucidate the possible active sites and reaction pathway. The moiety, which consists of three pyridinic N atoms (N-3) adjacent with one carbon vacancy embedded in a carbon layer, is able to strongly adsorb N-2 and further realize N = N triple bond dissociation for the subsequent protonation process. The rate-determining step of the NRR is predicted to be the adsorption and bond activation of N-2 molecule. Increasing overpotentials is favorable for the protonation process during NH3 generation. Further doping Fe into the nitrogen-doped carbon likely blocks the N-3 active sites and facilitates the hydrogen evolution reaction, a strong competitor to the NRR, thus yielding negative effect on ammonia production. This work provides a new insight into the rational design and synthesis of nitrogen-doped and defect-rich carbon as efficient NRR catalysts for NH3 synthesis at ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 48, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 217, "End Page": 226, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.03.059", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.03.059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432604600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SY; Luo, T; Li, XQ; Chen, KJ; Fu, JW; Liu, K; Cai, C; Wang, QY; Li, HM; Chen, Y; Ma, C; Zhu, L; Lu, YR; Chan, TS; Zhu, MS; Cortes, E; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shanyong; Luo, Tao; Li, Xiaoqing; Chen, Kejun; Fu, Junwei; Liu, Kang; Cai, Chao; Wang, Qiyou; Li, Hongmei; Chen, Yu; Ma, Chao; Zhu, Li; Lu, Ying-Rui; Chan, Ting-Shan; Zhu, Mingshan; Cortes, Emiliano; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of the Highly Active Co-N4 Coordination Motif for Selective Oxygen Reduction to Hydrogen Peroxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrosynthesis of hydrogen peroxide (H2O2) through oxygen reduction reaction (ORR) is an environment-friendly and sustainable route for obtaining a fundamental product in the chemical industry. Co-N4 single-atom catalysts (SAC) have sparkled attention for being highly active in both 2e- ORR, leading to H2O2 and 4e- ORR, in which H2O is the main product. However, there is still a lack of fundamental insights into the structure-function relationship between CoN4 and the ORR mechanism over this family of catalysts. Here, by combining theoretical simulation and experiments, we unveil that pyrrole-type CoN4 (Co-N SACDp) is mainly responsible for the 2e- ORR, while pyridine-type CoN4 catalyzes the 4e- ORR. Indeed, Co-N SACDp exhibits a remarkable H2O2 selectivity of 94% and a superb H2O2 yield of 2032 mg for 90 h in a flow cell, outperforming most reported catalysts in acid media. Theoretical analysis and experimental investigations confirm that Co-N SACDp-with weakening O-2/HOO* interaction-boosts the H2O2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 144, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14505, "End Page": 14516, "Article Number": null, "DOI": "10.1021/jacs.2c01194", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c01194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860150500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YZ; Lu, RH; Tao, XF; Qiu, ZJ; Chen, GB; Yang, J; Zhao, Y; Feng, XL; Müllen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yazhou; Lu, Ruihu; Tao, Xiafang; Qiu, Zijie; Chen, Guangbo; Yang, Juan; Zhao, Yan; Feng, Xinliang; Muellen, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Oxygen Electrocatalytic Activity of Fe-N-C Catalysts by Phosphorus Incorporation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped graphitic carbon materials hosting single-atom iron (Fe-N-C) are major non-precious metal catalysts for the oxygen reduction reaction (ORR). The nitrogen-coordinated Fe sites are described as the first coordination sphere. As opposed to the good performance in ORR, that in the oxygen evolution reaction (OER) is extremely poor due to the sluggish O-O coupling process, thus hampering the practical applications of rechargeable zinc (Zn)-air batteries. Herein, we succeed in boosting the OER activity of Fe-N-C by additionally incorporating phosphorus atoms into the second coordination sphere, here denoted as P/Fe-N-C. The resulting material exhibits excellent OER activity in 0.1 M KOH with an overpotential as low as 304 mV at a current density of 10 mA cm-2. Even more importantly, they exhibit a remarkably small ORR/OER potential gap of 0.63 V. Theoretical calculations using first-principles density functional theory suggest that the phosphorus enhances the electrocatalytic activity by balancing the *OOH/*O adsorption at the FeN4 sites. When used as an air cathode in a rechargeable Zn-air battery, P/Fe-N-C delivers a charge-discharge performance with a high peak power density of 269 mW cm-2, highlighting its role as the state-of-the-art bifunctional oxygen electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 145, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3647, "End Page": 3655, "Article Number": null, "DOI": "10.1021/jacs.2c12933", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c12933", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928853600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, D; Wang, RX; Tang, GS; Mou, ZP; Lei, JD; Han, JQ; De Smedt, S; Xiong, RH; Huang, CB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Dan; Wang, Ruoxue; Tang, Guosheng; Mou, Zhipeng; Lei, Jiandu; Han, Jingquan; De Smedt, Stefaan; Xiong, Ranhua; Huang, Chaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ecofriendly Electrospun Membranes Loaded with Visible-Light Responding nulloparticles for Multifunctional Usages: Highly Efficient Air Filtration, Dye Scavenging, and Bactericidal Activity", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient particulate matter pollution has posed serious threats to global environment and public health. However, highly efficient filtration of submicron particles, the so-named secondary pollution caused by, e.g., bacterial growth in filters and the use of nondegradable filter materials, remains a serious challenge. In this study, poly(vinyl alcohol) (PVA) and konjac glucomannull (KGM)-based nullofiber membranes, loaded with ZnO nulloparticles, were prepared through green electrospinning and ecofriendly thermal cross-linking. Thus obtained fibrous membranes not only show highly efficient air-filtration performance but also show superior photocatalytic activity and antibacterial activity. The filtration efficiency of the ZnO@PVA/KGM membranes for ultrafine-particles (300 nm) was higher than 99.99%, being superior to that of commercial HEPA filters. By virtue of the high photocatalytic activity, methyl orange was efficiently decolorized with a removal efficiency of more than 98% at an initial concentration of 20 mg under 120 min of solar irradiation. A multifunctional membrane with high removal efficiency, low flow resistance, superior photocatalytic activity, and superior antibacterial activity was successfully achieved. It is conceivable that the combination of a biodegradable polymer and an active metal particle would form an unprecedented photocatalytic system, which will be quite promising for environmental remediation such as air filtration and water treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2019, "Volume": 11, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12880, "End Page": 12889, "Article Number": null, "DOI": "10.1021/acsami.9b01508", "DOI Link": "http://dx.doi.org/10.1021/acsami.9b01508", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463843900079", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, SW; Dong, XL; Huang, JY; Li, SH; Li, YW; Chen, Z; Lai, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Shouwei; Dong, Xiuli; Huang, Jianying; Li, Shuhui; Li, Yuwei; Chen, Zhong; Lai, Yuekun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil-water separation", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the existing effort, fabricating superhydrophobic substrate through an environmental friendly approach remains a great challenge. In the current work, we present a simple approach to fabricate robust superhydrophobic surfaces on different kinds of substrates using phase-separation method. This method uses polydimethylsiloxane (PDMS) as the binder, tetrahydrofuran (THF) as the solvent, and water as nonsolvent. The emulsion prepared under optimum proportion of THF and water was stable and showed no obvious change even after being stored for 6 weeks. The coated substrates exhibit superhydrophobic property with a water contact angle (CA) larger than 155.0 degrees. Moreover, because the solution is rich of water, and the surface modification condition is mild, the PDMS coating enjoys a high degree of transparency. Finally, superhydrophobic cotton and sponge were successfully demonstrated for oil-water and oil-in-water emulsion separation. This facile synthesis method has a potential for a broad range of applications in large-scale fabrication of superhydrophobic surfaces and filtration membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2018, "Volume": 333, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 621, "End Page": 629, "Article Number": null, "DOI": "10.1016/j.cej.2017.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417304500065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Chen, H; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Chen, Hao; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formulating energy density for designing practical lithium-sulfur batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-S batteries are a promising next-generation storage technology and the assessment of their performance is critical for their development. Here the authors analyse key Li-S cell parameters, formulate the energy density calculation and discuss design targets for practical applications. The lithium-sulfur (Li-S) battery is one of the most promising battery systems due to its high theoretical energy density and low cost. Despite impressive progress in its development, there has been a lack of comprehensive analyses of key performance parameters affecting the energy density of Li-S batteries. Here, we analyse the potential causes of energy loss during battery operations. We identify two key descriptors (R-weight and R-energy) that represent the mass- and energy-level compromise of the full-cell energy density, respectively. A formulation for energy density calculations is proposed based on critical parameters, including sulfur mass loading, sulfur mass ratio, electrolyte/sulfur ratio and negative-to-positive electrode material ratio. The current progress of Ah-level Li-S batteries is also summarized and analysed. Finally, future research directions, targets and prospects for designing practical high-performance Li-S batteries are proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 576, "Times Cited, All Databases": 591, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 312, "End Page": 319, "Article Number": null, "DOI": "10.1038/s41560-022-01001-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01001-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787803100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, HB; Yang, LQ; Jiang, X; Li, GC; Zhang, TR; Yao, QF; Zheng, GW; Lee, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Haibin; Yang, Liuqing; Jiang, Xi; Li, Guochun; Zhang, Tianran; Yao, Qiaofeng; Zheng, Guangyuan Wesley; Lee, Jim Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrocatalysis of polysulfide conversion by sulfur-deficient MoS2 nulloflakes for lithium-sulfur batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries are promising next-generation energy storage devices due to their high energy density and low material cost. Efficient conversion of lithium polysulfides to lithium sulfide (during discharge) and to sulfur (during recharge) is a performance-determining factor for lithium-sulfur batteries. Here we show that MoS2-x/reduced graphene oxide (MoS2-x/rGO) can be used to catalyze the polysulfide reactions to improve the battery performance. It was confirmed, through microstructural characterization of the materials, that sulfur deficiencies on the surface participated in the polysulfide reactions and significantly enhanced the polysulfide conversion kinetics. The fast conversion of soluble polysulfides decreased their accumulation in the sulfur cathode and their loss from the cathode by diffusion. Hence in the presence of a small amount of MoS2-x/rGO (4 wt% of the cathode mass), high rate (8C) performance of the sulfur cathode was improved from a capacity of 161.1 mA h g(-1) to 826.5 mA h g(-1). In addition, MoS2-x/rGO also enhanced the cycle stability of the sulfur cathode from a capacity fade rate of 0.373% per cycle (over 150 cycles) to 0.083% per cycle (over 600 cycles) at a typical 0.5C rate. These results provide direct experimental evidence for the catalytic role of MoS2-x/rGO in promoting the polysulfide conversion kinetics in the sulfur cathode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 836, "Times Cited, All Databases": 867, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2017, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1476, "End Page": 1486, "Article Number": null, "DOI": "10.1039/c7ee01047h", "DOI Link": "http://dx.doi.org/10.1039/c7ee01047h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403320300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, WQ; VahidMohammadi, A; Reid, MS; Wang, Z; Ouyang, LQ; Erlandsson, J; Pettersson, T; Wagberg, L; Beidaghi, M; Hamedi, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Weiqian; VahidMohammadi, Armin; Reid, Michael S.; Wang, Zhen; Ouyang, Liangqi; Erlandsson, Johan; Pettersson, Torbjorn; Wagberg, Lars; Beidaghi, Majid; Hamedi, Mahiar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional nullocomposites with High Strength and Capacitance Using 2D MXene and 1D nullocellulose", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The family of two-dimensional (2D) metal carbides and nitrides, known as MXenes, are among the most promising electrode materials for supercapacitors thanks to their high metal-like electrical conductivity and surface-functional-group-enabled pseudocapacitance. A major drawback of these materials is, however, the low mechanical strength, which prevents their applications in lightweight, flexible electronics. A strategy of assembling freestanding and mechanically robust MXene (Ti3C2Tx) nullocomposites with one-dimensional (1D) cellulose nullofibrils (CNFs) from their stable colloidal dispersions is reported. The high aspect ratio of CNF (width of approximate to 3.5 nm and length reaching tens of micrometers) and their special interactions with MXene enable nullocomposites with high mechanical strength without sacrificing electrochemical performance. CNF loading up to 20%, for example, shows a remarkably high mechanical strength of 341 MPa (an order of magnitude higher than pristine MXene films of 29 MPa) while still maintaining a high capacitance of 298 F g(-1) and a high conductivity of 295 S cm(-1). It is also demonstrated that MXene/CNF hybrid dispersions can be used as inks to print flexible micro-supercapacitors with precise dimensions. This work paves the way for fabrication of robust multifunctional MXene nullocomposites for printed and lightweight structural devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 31, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902977, "DOI": "10.1002/adma.201902977", "DOI Link": "http://dx.doi.org/10.1002/adma.201902977", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482085200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, YJ; Zeng, DQ; Ong, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Yijie; Zeng, Deqian; Ong, Wee-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial engineering of graphitic carbon nitride (g-C3N4)-based metal sulfide heterojunction photocatalysts for energy conversion: A review", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemical, graphitic carbon nitride (g-C3N4) has become research hotspots in the community. However, g-C3N4 photocatalyst still suffers from many problems, resulting in unsatisfactory photocatalytic activity such as low specific surface area, high charge recombination and insufficient visible light utilization. Since 2009, g-C3N4-based heterostructures have attracted the attention of scientists worldwide for their greatly enhanced photocatalytic performance. Overall, this review summarizes the recent advances of g-C3N4-based nullocomposites modified with transition metal sulfide (TMS), including (1) preparation of pristine g-C3N4, (2) modification strategies of g-C3N4, (3) design principles of TMS-modified g-C3N4 heterostructured photocatalysts, and (4) applications in energy conversion. What is more, the characteristics and transfer mechanisms of each classification of the metal sulfide heterojunction system will be critically reviewed, spanning from the following categories: (1) Type I heterojunction, (2) Type II heterojunction, (3) p-n heterojunction, (4) Schottky junction and (5) Z-scheme heterojunction. Apart from that, the application of g-C3N4-based heterostructured photocatalysts in H-2 evolution, CO2 reduction, N-2 fixation and pollutant degradation will also be systematically presented. Last but not least, this review will conclude with invigorating perspectives, limitations and prospects for further advancing g-C3N4-based heterostructured photocatalysts toward practical benefits for a sustainable future. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 474, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 40, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 289, "End Page": 319, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63293-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63293-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466263200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bailie, CD; Christoforo, MG; Mailoa, JP; Bowring, AR; Unger, EL; Nguyen, WH; Burschka, J; Pellet, N; Lee, JZ; Grätzel, M; Noufi, R; Buonassisi, T; Salleo, A; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bailie, Colin D.; Christoforo, M. Greyson; Mailoa, Jonathan P.; Bowring, Andrea R.; Unger, Eva L.; Nguyen, William H.; Burschka, Julian; Pellet, Norman; Lee, Jungwoo Z.; Graetzel, Michael; Noufi, Rommel; Buonassisi, Tonio; Salleo, Alberto; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semi-transparent perovskite solar cells for tandems with silicon and CIGS", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A promising approach for upgrading the performance of an established low-bandgap solar technology without adding much cost is to deposit a high bandgap polycrystalline semiconductor on top to make a tandem solar cell. We use a transparent silver nullowire electrode on perovskite solar cells to achieve a semi-transparent device. We place the semi-transparent cell in a mechanically-stacked tandem configuration onto copper indium gallium diselenide (CIGS) and low-quality multicrystalline silicon (Si) to achieve solid-state polycrystalline tandem solar cells with a net improvement in efficiency over the bottom cell alone. This work paves the way for integrating perovskites into a low-cost and high-efficiency (>25%) tandem cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 700, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 956, "End Page": 963, "Article Number": null, "DOI": "10.1039/c4ee03322a", "DOI Link": "http://dx.doi.org/10.1039/c4ee03322a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352274600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, TY; Liang, WY; Li, YW; Sun, YH; Xiang, YJ; Zhang, YP; Dai, ZG; Duo, YH; Wu, LM; Qi, K; Shiyanullju, BN; Zhang, LJ; Cui, XQ; Zhang, H; Bao, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Tianyu; Liang, Weiyuan; Li, Yawen; Sun, Yuanhui; Xiang, Yuanjiang; Zhang, Yupeng; Dai, Zhigao; Duo, Yanhong; Wu, Leiming; Qi, Kun; Shiyanullju, Bannur nulljunda; Zhang, Lijun; Cui, Xiaoqiang; Zhang, Han; Bao, Qiaoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive detection of miRNA with an antimonene-based surface plasmon resonullce sensor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MicroRNA exhibits differential expression levels in cancer and can affect cellular transformation, carcinogenesis and metastasis. Although fluorescence techniques using dye molecule labels have been studied, label-free molecular-level quantification of miRNA is extremely challenging. We developed a surface plasmon resonullce sensor based on two-dimensional nullomaterial of antimonene for the specific label-free detection of clinically relevant biomarkers such as miRNA-21 and miRNA-155. First-principles energetic calculations reveal that antimonene has substantially stronger interaction with ssDNA than the graphene that has been previously used in DNA molecule sensing, due to thanking for more delocalized 5s/5p orbitals in antimonene. The detection limit can reach 10 aM, which is 2.3-10,000 times higher than those of existing miRNA sensors. The combination of not-attempted-before exotic sensing material and SPR architecture represents an approach to unlocking the ultrasensitive detection of miRNA and DNA and provides a promising avenue for the early diagnosis, staging, and monitoring of cancer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 693, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28, "DOI": "10.1038/s41467-018-07947-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07947-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, LZ; Frauenheim, T; Chen, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Liangzhi; Frauenheim, Thomas; Chen, Changfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene as a Superior Gas Sensor: Selective Adsorption and Distinct I-V Response", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent reports on the fabrication of phosphorene, that is, mono- or few-layer black phosphorus, have raised exciting prospects of an outstanding two-dimensional (2D) material that exhibits excellent properties for nullodevice applications. Here, we study by first-principles calculations the adsorption of CO, CO2, NH3, NO, and NO2 gas molecules on a monolayer phosphorene. Our results predict superior sensing performance of phosphorene that rivals or even surpasses that of other 2D materials such as graphene and MoS2. We determine the optimal adsorption positions of these molecules on the phosphorene and identify molecular doping, that is, charge transfer between the molecules and phosphorene, as the driving mechanism for the high adsorption strength. We further calculated the current-voltage (I-V) relation using the nonequilibrium Green's function (NEGF) formalism. The transport features show large (1-2 orders of magnitude) anisotropy along different (armchair or zigzag) directions, which is consistent with the anisotropic electronic band structure of phosphorene. Remarkably, the I-V relation exhibits distinct responses with a marked change of the I-V relation along either the armchair or the zigzag directions depending on the type of molecules. Such selectivity and sensitivity to adsorption makes phosphorene a superior gas sensor that promises wide-ranging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 910, "Times Cited, All Databases": 940, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2014, "Volume": 5, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2675, "End Page": 2681, "Article Number": null, "DOI": "10.1021/jz501188k", "DOI Link": "http://dx.doi.org/10.1021/jz501188k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340222200031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duerloo, KAN; Li, Y; Reed, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duerloo, Karel-Alexander N.; Li, Yao; Reed, Evan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural phase transitions in two-dimensional Mo- and W-dichalcogenide monolayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mo- and W-dichalcogenide compounds have a two-dimensional monolayer form that differs from graphene in an important respect: it can potentially have more than one crystal structure. Some of these monolayers exhibit tantalizing hints of a poorly understood structural metal-to-insulator transition with the possibility of long metastable lifetimes. If controllable, such a transition could bring an exciting new application space to monolayer materials beyond graphene. Here we discover that mechanical deformations provide a route to switching thermodynamic stability between a semiconducting and a metallic crystal structure in these monolayer materials. Based on state-of-the-art density functional and hybrid Hartree-Fock/density functional calculations including vibrational energy corrections, we discover that MoTe2 is an excellent candidate phase change material. We identify a range from 0.3 to 3% for the tensile strains required to transform MoTe2 under uniaxial conditions at room temperature. The potential for mechanical phase transitions is predicted for all six studied compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 918, "Times Cited, All Databases": 996, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4214, "DOI": "10.1038/ncomms5214", "DOI Link": "http://dx.doi.org/10.1038/ncomms5214", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340611600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, L; Cheng, RH; Yi, M; Hung, WS; Japip, S; Tian, L; Zhang, X; Jiang, SD; Li, S; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Liang; Cheng, Ruihuan; Yi, Ming; Hung, Wei-Song; Japip, Susilo; Tian, Lian; Zhang, Xuan; Jiang, Shudong; Li, Song; Wang, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyamide-based membranes with structural homogeneity for ultrafast molecular sieving", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thin-film composite membranes formed by conventional interfacial polymerization generally suffer from the depth heterogeneity of the polyamide layer, i.e., nonuniformly distributed free volume pores, leading to the inefficient permselectivity. Here, we demonstrate a facile and versatile approach to tune the nulloscale homogeneity of polyamide-based thin-film composite membranes via inorganic salt-mediated interfacial polymerization process. Molecular dynamics simulations and various characterization techniques elucidate in detail the underlying molecular mechanism by which the salt addition confines and regulates the diffusion of amine monomers to the water-oil interface and thus tunes the nulloscale homogeneity of the polyamide layer. The resulting thin-film composite membranes with thin, smooth, dense, and structurally homogeneous polyamide layers demonstrate a permeance increment of similar to 20-435% and/or solute rejection enhancement of similar to 10-170% as well as improved antifouling property for efficient reverse/forward osmosis and nullofiltration separations. This work sheds light on the tunability of the polyamide layer homogeneity via salt-regulated interfacial polymerization process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 500, "DOI": "10.1038/s41467-022-28183-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28183-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747410400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, J; Hu, YX; Liang, Y; Kong, BA; Zhang, J; Song, JC; Bao, QL; Simon, GP; Jiang, SP; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Jing; Hu, Yaoxin; Liang, Yan; Kong, Biao; Zhang, Jin; Song, Jingchao; Bao, Qiaoliang; Simon, George P.; Jiang, San Ping; Wang, Huanting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Doped nulloporous Carbon/Graphene nullo-Sandwiches: Synthesis and Application for Efficient Oxygen Reduction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A zeolitic-imidazolate-framework (ZIF) nullocrystal layer-protected carbonization route is developed to prepare N-doped nulloporous carbon/graphene nullo-sandwiches. The ZIF/graphene oxide/ZIF sandwich-like structure with ultrasmall ZIF nullocrystals (i.e., approximate to 20 nm) fully covering the graphene oxide (GO) is prepared via a homogenous nucleation followed by a uniform deposition and confined growth process. The uniform coating of ZIF nullocrystals on the GO layer can effectively inhibit the agglomeration of GO during high-temperature treatment (800 degrees C). After carbonization and acid etching, N-doped nulloporous carbon/graphene nullosheets are formed, with a high specific surface area (1170 m(2) g(-1)). These N-doped nulloporous carbon/graphene nullosheets are used as the nonprecious metal electrocatalysts for oxygen reduction and exhibit a high onset potential (0.92 V vs reversible hydrogen electrode; RHE) and a large limiting current density (5.2 mA cm(-2) at 0.60 V). To further increase the oxygen reduction performance, nulloporous Co-N-x/carbon nullosheets are also prepared by using cobalt nitrate and zinc nitrate as cometal sources, which reveal higher onset potential (0.96 V) than both commercial Pt/C (0.94 V) and N-doped nulloporous carbon/graphene nullosheets. Such nulloporous Co-N-x/carbon nullosheets also exhibit good performance such as high activity, stability, and methanol tolerance in acidic media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2015, "Volume": 25, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5768, "End Page": 5777, "Article Number": null, "DOI": "10.1002/adfm.201502311", "DOI Link": "http://dx.doi.org/10.1002/adfm.201502311", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362517900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, SS; Rathi, P; Wu, XH; Ghim, D; Jun, YS; Singamaneni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Sisi; Rathi, Priya; Wu, Xuanhao; Ghim, Deoukchen; Jun, Young-Shin; Singamaneni, Srikanth", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cellulose nullomaterials in Interfacial Evaporators for Desalination: A Natural Choice", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, the recent advances in realizing highly efficient cellulose-based solar evaporators for alleviating the global water crisis are summarized. Fresh water scarcity is one of the most threatening issues for sustainable development. Solar steam generation, which harnesses the abundant sunlight, has been recognized as a sustainable approach to harvest fresh water. In contrast to synthetic polymeric materials that can pose serious negative environmental impacts, cellulose-based materials, owing to their biocompatibility, renewability, and sustainability, are highly attractive for realizing solar steam generators. The molecular and macromolecular features of cellulose and the physicochemical properties of extracted cellulose nulloparticles (cellulose nullocrystals and cellulose nullofibrils (CNF)) and natural cellulose materials (wood and bacterial nullocellulose (BNC)) that make them attractive as supporting substrate materials in solar steam generators are briefly discussed. Recent progress in designing highly efficient cellulose-based solar evaporators, including utilizing extracted cellulose nulloparticles via bottom-up assembly CNF, natural cellulose materials with intrinsic hierarchical structure (wood and BNC), and commercial planar cellulose substrates (air-laid paper, cellulose paper, and cotton fabric) is reviewed. The outstanding challenges that need to be addressed for these materials and devices to be utilized in the real-world and in overcoming global water crisis are also briefly highlighted.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 33, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000922, "DOI": "10.1002/adma.202000922", "DOI Link": "http://dx.doi.org/10.1002/adma.202000922", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672917500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Jin, XY; Zhu, C; Liu, YP; Tan, H; Ku, RQ; Zhang, YQ; Zhou, LJ; Liu, Z; Hwang, SJ; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhe; Jin, Xiaoyan; Zhu, Chao; Liu, Yipu; Tan, Hua; Ku, Ruiqi; Zhang, Yongqi; Zhou, Liujiang; Liu, Zheng; Hwang, Seong-Ju; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Dispersed Co2-N6 and Fe-N4 Costructures Boost Oxygen Reduction Reaction in Both Alkaline and Acidic Media", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polynary transition-metal atom catalysts are promising to supersede platinum (Pt)-based catalysts for oxygen reduction reaction (ORR). Regulating the local configuration of atomic catalysts is the key to catalyst performance enhancement. Different from the previously reported single-atom or dual-atom configurations, a new type of ternary-atom catalyst, which consists of atomically dispersed, nitrogen-coordinated Co-Co dimers, and Fe single sites (i.e., Co-2-N-6 and Fe-N-4 structures) that are coanchored on highly graphitized carbon supports is developed. This unique atomic ORR catalyst outperforms the catalysts with only Co-2-N-6 or Fe-N-4 sites in both alkaline and acid conditions. Density functional theory calculations clearly unravels the synergistic effect of the Co-2-N-6 and Fe-N-4 sites, which can induce higher filling degree of Fe-d orbitals and favors the binding capability to *OH intermediates (the rate determining step). This ternary-atom catalyst may be a promising alternative to Pt to drive the cathodic ORR in zinc-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 33, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104718, "DOI": "10.1002/adma.202104718", "DOI Link": "http://dx.doi.org/10.1002/adma.202104718", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000705539500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, H; Hong, J; Park, YU; Kim, J; Hwang, I; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Haegyeom; Hong, Jihyun; Park, Young-Uk; Kim, Jinsoo; Hwang, Insang; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sodium Storage Behavior in Natural Graphite using Ether-based Electrolyte Systems", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work reports that natural graphite is capable of Na insertion and extraction with a remarkable reversibility using ether-based electrolytes. Natural graphite (the most well-known anode material for Li-ion batteries) has been barely studied as a suitable anode for Na rechargeable batteries due to the lack of Na intercalation capability. Herein, graphite is not only capable of Na intercalation but also exhibits outstanding performance as an anode for Na ion batteries. The graphite anode delivers a reversible capacity of approximate to 150 mAh g(-1) with a cycle stability for 2500 cycles, and more than 75 mAh g(-1) at 10 A g(-1) despite its micrometer-size (approximate to 100 m). An Na storage mechanism in graphite, where Na+-solvent co-intercalation occurs combined with partial pseudocapacitive behaviors, is revealed in detail. It is demonstrated that the electrolyte solvent species significantly affect the electrochemical properties, not only rate capability but also redox potential. The feasibility of graphite in a Na full cell is also confirmed in conjunction with the Na1.5VPO4.8F0.7 cathode, delivering an energy of approximate to 120 Wh kg(-1) while maintaining approximate to 70% of the initial capacity after 250 cycles. This exceptional behavior of natural graphite promises new avenues for the development of cost-effective and reliable Na ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 651, "Times Cited, All Databases": 692, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2015, "Volume": 25, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 534, "End Page": 541, "Article Number": null, "DOI": "10.1002/adfm.201402984", "DOI Link": "http://dx.doi.org/10.1002/adfm.201402984", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348856500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Umari, P; Mosconi, E; De Angelis, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Umari, Paolo; Mosconi, Edoardo; De Angelis, Filippo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Relativistic GW calculations on CH3NH3PbI3 and CH3NH3SnI3 Perovskites for Solar Cell Applications", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid AMX(3) perovskites (A = Cs, CH3NH3; M = Sn, Pb; X = halide) have revolutionized the scenario of emerging photovoltaic technologies, with very recent results demonstrating 15% efficient solar cells. The CH3NH3PbI3/MAPb( I1-xClx)(3) perovskites have dominated the field, while the similar CH3NH3SnI3 has not been exploited for photovoltaic applications. Replacement of Pb by Sn would facilitate the large uptake of perovskite- based photovoltaics. Despite the extremely fast progress, the materials electronic properties which are key to the photovoltaic performance are relatively little understood. Density Functional Theory electronic structure methods have so far delivered an unbalanced description of Pb- and Sn- based perovskites. Here we develop an effectiveGWmethod incorporating spin- orbit coupling which allows us to accurately model the electronic, optical and transport properties of CH3NH3SnI3 and CH3NH3PbI3, opening the way to new materials design. The different CH3NH3SnI3 and CH3NH3PbI3 electronic properties are discussed in light of their exploitation for solar cells, and found to be dominulltly due to relativistic effects. These effects stabilize the CH3NH3PbI3 material towards oxidation, by inducing a deeper valence band edge. Relativistic effects, however, also increase the material band- gap compared to CH3NH3SnI3, due to the valence band energy downshift (similar to 0.7 eV) being only partly compensated by the conduction band downshift (similar to 0.2 eV).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1110, "Times Cited, All Databases": 1180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 26", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4467, "DOI": "10.1038/srep04467", "DOI Link": "http://dx.doi.org/10.1038/srep04467", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333387800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, L; Peng, ZR; Lin, RF; Li, Z; Wang, YL; Huang, XY; Xue, KH; Xu, HY; Liu, F; Xia, H; Wang, P; Xu, MS; Xiong, W; Hu, WD; Xu, JB; Zhang, XL; Ye, L; Miao, XS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Lei; Peng, Zhuiri; Lin, Runfeng; Li, Zheng; Wang, Yilun; Huang, Xinyu; Xue, Kan-Hao; Xu, Hangyu; Liu, Feng; Xia, Hui; Wang, Peng; Xu, Mingsheng; Xiong, Wei; Hu, Weida; Xu, Jianbin; Zhang, Xinliang; Ye, Lei; Miao, Xiangshui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D materials-based homogeneous transistor-memory architecture for neuromorphic hardware", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In neuromorphic hardware, peripheral circuits and memories based on heterogeneous devices are generally physically separated. Thus, exploration of homogeneous devices for these components is key for improving module integration and resistance matching. Inspired by the ferroelectric proximity effect on two-dimensional (2D) materials, we present a tungsten diselenide-on-lithium niobate cascaded architecture as a basic device that functions as a nonlinear transistor, assisting the design of operational amplifiers for analog signal processing (ASP). This device also functions as a nonvolatile memory cell, achieving memory operating (MO) functionality. On the basis of this homogeneous architecture, we also investigated an ASP-MO integrated system for binary classification and the design of ternary content-addressable memory for potential use in neuromorphic hardware.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 17", "Publication Year": 2021, "Volume": 373, "Issue": 6561, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1353, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg3161", "DOI Link": "http://dx.doi.org/10.1126/science.abg3161", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000697488600048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, T; Yan, DY; Jiao, Y; Wang, H; Zheng, Y; Zheng, XL; Mao, J; Du, XW; Hu, ZP; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Tao; Yan, Dong-Yang; Jiao, Yan; Wang, Hui; Zheng, Yao; Zheng, Xueli; Mao, Jing; Du, Xi-Wen; Hu, Zhenpeng; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering surface atomic structure of single-crystal cobalt (II) oxide nullorods for superior electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering the surface structure at the atomic level can be used to precisely and effectively manipulate the reactivity and durability of catalysts. Here we report tuning of the atomic structure of one-dimensional single-crystal cobalt (II) oxide (CoO) nullorods by creating oxygen vacancies on pyramidal nullofacets. These CoO nullorods exhibit superior catalytic activity and durability towards oxygen reduction/evolution reactions. The combined experimental studies, microscopic and spectroscopic characterization, and density functional theory calculations reveal that the origins of the electrochemical activity of single-crystal CoO nullorods are in the oxygen vacancies that can be readily created on the oxygen-terminated {111} nullofacets, which favourably affect the electronic structure of CoO, assuring a rapid charge transfer and optimal adsorption energies for intermediates of oxygen reduction/evolution reactions. These results show that the surface atomic structure engineering is important for the fabrication of efficient and durable electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 581, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12876, "DOI": "10.1038/ncomms12876", "DOI Link": "http://dx.doi.org/10.1038/ncomms12876", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385384100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YS; Liu, J; Lee, BJ; Qiao, RM; Yang, ZZ; Xu, SY; Yu, XQ; Gu, L; Hu, YS; Yang, WL; Kang, K; Li, H; Yang, XQ; Chen, LQ; Huang, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; Kang, Kisuk; Li, Hong; Yang, Xiao-Qing; Chen, Liquan; Huang, Xuejie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, because of the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, for example, Na0.44MnO2, were proposed, few negative electrode materials, for example, activated carbon and NaTi2(PO4)(3), are available. Here we show that Ti-substituted Na0.44MnO2 (Na-0.44[Mn1-xTix] O-2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/ charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na-0.44[Mn1-xTix]O-2 is a promising negative electrode material for aqueous sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6401, "DOI": "10.1038/ncomms7401", "DOI Link": "http://dx.doi.org/10.1038/ncomms7401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352586300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Ma, YL; Lu, Y; Li, L; Wan, F; Zhang, K; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qiu; Ma, Yilin; Lu, Yong; Li, Lin; Wan, Fang; Zhang, Kai; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating electrolyte structure for ultralow temperature aqueous zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous batteries are an up-and-coming system for potential large-scale energy storage due to their high safety and low cost. However, the freeze of aqueous electrolyte limits the low-temperature operation of such batteries. Here, we report the breakage of original hydrogen-bond network in ZnCl2 solution by modulating electrolyte structure, and thus suppressing the freeze of water and depressing the solid-liquid transition temperature of the aqueous electrolyte from 0 to -114 degrees C. This ZnCl2-based low-temperature electrolyte renders polyaniline||Zn batteries available to operate in an ultra-wide temperature range from -90 to +60 degrees C, which covers the earth surface temperature in record. Such polyaniline parallel to Zn batteries are robust at -70 degrees C (84.9 mA h g(-1)) and stable during over 2000 cycles with similar to 100% capacity retention. This work significantly provides an effective strategy to propel low-temperature aqueous batteries via tuning the electrolyte structure and widens the application range of temperature adaptation of aqueous batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 637, "Times Cited, All Databases": 660, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4463, "DOI": "10.1038/s41467-020-18284-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18284-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607102200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rafiee, M; Farahani, RD; Therriault, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rafiee, Mohammad; Farahani, Rouhollah D.; Therriault, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-Material 3D and 4D Printing: A Survey", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in multi-material 3D and 4D printing (time as the fourth dimension) show that the technology has the potential to extend the design space beyond complex geometries. The potential of these additive manufacturing (AM) technologies allows for functional inclusion in a low-cost single-step manufacturing process. Different composite materials and various AM technologies can be used and combined to create customized multi-functional objects to suit many needs. In this work, several types of 3D and 4D printing technologies are compared and the advantages and disadvantages of each technology are discussed. The various features and applications of 3D and 4D printing technologies used in the fabrication of multi-material objects are reviewed. Finally, new avenues for the development of multi-material 3D and 4D printed objects are proposed, which reflect the current deficiencies and future opportunities for inclusion by AM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902307, "DOI": "10.1002/advs.201902307", "DOI Link": "http://dx.doi.org/10.1002/advs.201902307", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529631900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, DH; Chen, XQ; Yu, L; Wu, X; Liu, QF; Liu, Y; Yang, HX; Tian, HF; Hu, YF; Du, PP; Si, R; Wang, JH; Cui, XJ; Li, HB; Xiao, JP; Xu, T; Deng, J; Yang, F; Duchesne, PN; Zhang, P; Zhou, JG; Sun, LT; Li, JQ; Pan, XL; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Dehui; Chen, Xiaoqi; Yu, Liang; Wu, Xing; Liu, Qingfei; Liu, Yun; Yang, Huaixin; Tian, Huanfang; Hu, Yongfeng; Du, Peipei; Si, Rui; Wang, Junhu; Cui, Xiaoju; Li, Haobo; Xiao, Jianping; Xu, Tao; Deng, Jiao; Yang, Fan; Duchesne, Paul N.; Zhang, Peng; Zhou, Jigang; Sun, Litao; Li, Jianqi; Pan, Xiulian; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coordinatively unsaturated (CUS) iron sites are highly active in catalytic oxidation reactions; however, maintaining the CUS structure of iron during heterogeneous catalytic reactions is a great challenge. Here, we report a strategy to stabilize single-atom CUS iron sites by embedding highly dispersed FeN4 centers in the graphene matrix. The atomic structure of FeN4 centers in graphene was revealed for the first time by combining high- resolution transmission electron microscopy/high-angle annular dark-field scanning transmission electron microscopy with lowtemperature scanning tunneling microscopy. These confined single-atom iron sites exhibit high performance in the direct catalytic oxidation of benzene to phenol at room temperature, with a conversion of 23.4% and a yield of 18.7%, and can even proceed efficiently at 0 degrees C with a phenol yield of 8.3% after 24 hours. Both experimental measurements and density functional theory calculations indicate that the formation of the Fe = O intermediate structure is a key step to promoting the conversion of benzene to phenol. These findings could pave the way toward highly efficient nonprecious catalysts for low-temperature oxidation reactions in heterogeneous catalysis and electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 761, "Times Cited, All Databases": 798, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500462", "DOI": "10.1126/sciadv.1500462", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500462", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216604200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, BW; Sun, ZY; Huang, PJJ; Liu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Biwu; Sun, Ziyi; Huang, Po-Jung Jimmy; Liu, Juewen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen Peroxide Displacing DNA from nulloceria: Mechanism and Detection of Glucose in Serum", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is a key molecule in biology. As a byproduct of many enzymatic reactions, H2O2 is also a popular biosensor target. Recently, interfacing H2O2 with inorganic nulloparticles has produced a number of nullozymes showing peroxidase or catalase activities. CeO2 nulloparticle (nulloceria) is a classical nullozyme. Herein, a fluorescently labeled DNA is used as a probe, and H2O2 can readily displace adsorbed DNA from nulloceria, resulting in over 20-fold fluorescence enhancement. The displacement mechanism instead of oxidative DNA cleavage is confirmed by denaturing gel electrophoresis and surface group pKa measurement. This system can sensitively detect H2O2 down to 130 nM (4.4 parts-per-billion). When coupled with glucose oxidase, glucose is detected down to 8.9 mu M in buffer. Detection in serum is also achieved with results comparable with that from a commercial glucose meter. With an understanding of the ligand role of H2O2, new applications in rational materials design, sensor development, and drug delivery can be further exploited.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2015, "Volume": 137, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1290, "End Page": 1295, "Article Number": null, "DOI": "10.1021/ja511444e", "DOI Link": "http://dx.doi.org/10.1021/ja511444e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348690100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amani, M; Lien, DH; Kiriya, D; Xiao, J; Azcatl, A; Noh, J; Madhvapathy, SR; Addou, R; Santosh, KC; Dubey, M; Cho, K; Wallace, RM; Lee, SC; He, JH; Ager, JW; Zhang, X; Yablonovitch, E; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amani, Matin; Lien, Der-Hsien; Kiriya, Daisuke; Xiao, Jun; Azcatl, Angelica; Noh, Jiyoung; Madhvapathy, Surabhi R.; Addou, Rafik; Santosh, K. C.; Dubey, Madan; Cho, Kyeongjae; Wallace, Robert M.; Lee, Si-Chen; He, Jr-Hau; Ager, Joel W., III; Zhang, Xiang; Yablonovitch, Eli; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-unity photoluminescence quantum yield in MoS2", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal dichalcogenides have emerged as a promising material system for optoelectronic applications, but their primary figure of merit, the room-temperature photoluminescence quantum yield (QY), is extremely low. The prototypical 2D material molybdenum disulfide (MoS2) is reported to have a maximum QY of 0.6%, which indicates a considerable defect density. Herewe report on an air-stable, solution-based chemical treatment by an organic superacid, which uniformly enhances the photoluminescence and minority carrier lifetime of MoS2 monolayers by more than two orders of magnitude. The treatment eliminates defect-mediated nonradiative recombination, thus resulting in a final QY of more than 95%, with a longest-observed lifetime of 10.8 0.6 nulloseconds. Our ability to obtain optoelectronic monolayers with near-perfect properties opens the door for the development of highly efficient light-emitting diodes, lasers, and solar cells based on 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2015, "Volume": 350, "Issue": 6264, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1065, "End Page": 1068, "Article Number": null, "DOI": "10.1126/science.aad2114", "DOI Link": "http://dx.doi.org/10.1126/science.aad2114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366422600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YJ; Ma, Y; Dreyer, SL; Wang, QS; Wang, K; Goonetilleke, D; Omar, A; Mikhailova, D; Hahn, H; Breitung, B; Brezesinski, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yanjiao; Ma, Yuan; Dreyer, Soeren Lukas; Wang, Qingsong; Wang, Kai; Goonetilleke, Damian; Omar, Ahmad; Mikhailova, Daria; Hahn, Horst; Breitung, Ben; Brezesinski, Torsten", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Metal-Organic Frameworks for Highly Reversible Sodium Storage", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prussian blue analogues (PBAs) are reported to be efficient sodium storage materials because of the unique advantages of their metal-organic framework structure. However, the issues of low specific capacity and poor reversibility, caused by phase transitions during charge/discharge cycling, have thus far limited the applicability of these materials. Herein, a new approach is presented to substantially improve the electrochemical properties of PBAs by introducing high entropy into the crystal structure. To achieve this, five different metal species are introduced, sharing the same nitrogen-coordinated site, thereby increasing the configurational entropy of the system beyond 1.5R. By careful selection of the elements, high-entropy PBA (HE-PBA) presents a quasi-zero-strain reaction mechanism, resulting in increased cycling stability and rate capability. The key to such improvement lies in the high entropy and associated effects as well as the presence of several active redox centers. The gassing behavior of PBAs is also reported. Evolution of dimeric cyanogen due to oxidation of the cyanide ligands is detected, which can be attributed to the structural degradation of HE-PBA during battery operation. By optimizing the electrochemical window, a Coulombic efficiency of nearly 100% is retained after cycling for more than 3000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 33, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101342, "DOI": "10.1002/adma.202101342", "DOI Link": "http://dx.doi.org/10.1002/adma.202101342", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000671482900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SL; Pan, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Sanliang; Pan, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supercapacitors Performance Evaluation", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of a supercapacitor can be characterized by a series of key parameters, including the cell capacitance, operating voltage, equivalent series resistance, power density, energy density, and time constant. To accurately measure these parameters, a variety of methods have been proposed and are used in academia and industry. As a result, some confusion has been caused due to the inconsistencies between different evaluation methods and practices. Such confusion hinders effective communication of new research findings, and creates a hurdle in transferring novel supercapacitor technologies from research labs to commercial applications. Based on public sources, this article is an attempt to inventory, critique and hopefully streamline the commonly used instruments, key performance metrics, calculation methods, and major affecting factors for supercapacitor performance evaluation. Thereafter the primary sources of inconsistencies are identified and possible solutions are suggested, with emphasis on device performance vs. material properties and the rate dependency of supercapacitors. We hope, by using reliable, intrinsic, and comparable parameters produced, the existing inconsistencies and confusion can be largely eliminated so as to facilitate further progress in the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 840, "Times Cited, All Databases": 845, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2015, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1401401, "DOI": "10.1002/aenm.201401401", "DOI Link": "http://dx.doi.org/10.1002/aenm.201401401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351613200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, Z; Wang, J; Guo, ZY; Xie, F; Liu, HY; Yadegari, H; Tebyetekerwa, M; Ryan, MP; Hu, YS; Titirici, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zhen; Wang, Jing; Guo, Zhenyu; Xie, Fei; Liu, Haoyu; Yadegari, Hossein; Tebyetekerwa, Mike; Ryan, Mary P.; Hu, Yong-Sheng; Titirici, Maria-Magdalena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Role of Hydrothermal Carbonization in Sustainable Sodium-Ion Battery Anodes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries as a prospective alternative to lithium-ion batteries are facing the challenge of developing high-performance, low-cost and sustainable anode materials. Hard carbons are appropriate to store sodium ions, but major energy and environmental concerns during their fabrication process (i.e., high-temperature carbonization) have not been properly assessed. Furthermore, the rational design of high-performing hard carbon anodes is usually limited by the conventional direct carbonization of organic precursors. Here, the hydrothermal carbonization process is employed as a versatile pre-treatment method of renewable precursors, followed by high-temperature carbonization, for producing advanced hard carbon anodes. The critical role of hydrothermal pre-treatment in regulating the structure for an optimized performance of hard carbon anodes is elucidated, while revealing the sodium-ion storage mechanism using electrochemical kinetic calculations, advanced characterization and multi-scale modeling. Furthermore, the environmental impacts of hydrothermal pre-treatment and subsequent carbonization are evaluated using life cycle assessment compared to direct carbonization. By comparing hard carbon anodes with and without the hydrothermal pre-treatment, it is verified that the additional hydrothermal process is responsible for enhanced electrochemical performance, increased carbon yields and reduced carbon emissions. The work provides a systematic understanding of functions and energy consumptions of hydrothermal systems to achieve next-generation sustainable sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 12, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200208, "DOI": "10.1002/aenm.202200208", "DOI Link": "http://dx.doi.org/10.1002/aenm.202200208", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770635800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, BQ; Weng, HM; Fu, BB; Wang, XP; Miao, H; Ma, J; Richard, P; Huang, XC; Zhao, LX; Chen, GF; Fang, Z; Dai, X; Qian, T; Ding, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, B. Q.; Weng, H. M.; Fu, B. B.; Wang, X. P.; Miao, H.; Ma, J.; Richard, P.; Huang, X. C.; Zhao, L. X.; Chen, G. F.; Fang, Z.; Dai, X.; Qian, T.; Ding, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Discovery of Weyl Semimetal TaAs", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are a class of materials that can be regarded as three-dimensional analogs of graphene upon breaking time-reversal or inversion symmetry. Electrons in a Weyl semimetal behave as Weyl fermions, which have many exotic properties, such as chiral anomaly and magnetic monopoles in the crystal momentum space. The surface state of a Weyl semimetal displays pairs of entangled Fermi arcs at two opposite surfaces. However, the existence of Weyl semimetals has not yet been proved experimentally. Here, we report the experimental realization of a Weyl semimetal in TaAs by observing Fermi arcs formed by its surface states using angle-resolved photoemission spectroscopy. Our first-principles calculations, which match remarkably well with the experimental results, further confirm that TaAs is a Weyl semimetal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2287, "Times Cited, All Databases": 2423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31013, "DOI": "10.1103/PhysRevX.5.031013", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.031013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shang, HS; Zhou, XY; Dong, JC; Li, A; Zhao, X; Liu, QH; Lin, Y; Pei, JJ; Li, Z; Jiang, ZL; Zhou, DN; Zheng, LR; Wang, Y; Zhou, J; Yang, ZK; Cao, R; Sarangi, R; Sun, TT; Yang, X; Zheng, XS; Yan, WS; Zhuang, ZB; Li, J; Chen, WX; Wang, DS; Zhang, JT; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shang, Huishan; Zhou, Xiangyi; Dong, Juncai; Li, Ang; Zhao, Xu; Liu, Qinghua; Lin, Yue; Pei, Jiajing; Li, Zhi; Jiang, Zhuoli; Zhou, Danni; Zheng, Lirong; Wang, Yu; Zhou, Jing; Yang, Zhengkun; Cao, Rui; Sarangi, Ritimukta; Sun, Tingting; Yang, Xin; Zheng, Xusheng; Yan, Wensheng; Zhuang, Zhongbin; Li, Jia; Chen, Wenxing; Wang, Dingsheng; Zhang, Jiatao; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic interface regulation is thought to be an efficient method to adjust the performance of single atom catalysts. Herein, a practical strategy was reported to rationally design single copper atoms coordinated with both sulfur and nitrogen atoms in metal-organic framework derived hierarchically porous carbon (S-Cu-ISA/SNC). The atomic interface configuration of the copper site in S-Cu-ISA/SNC is detected to be an unsymmetrically arranged Cu-S1N3 moiety. The catalyst exhibits excellent oxygen reduction reaction activity with a half-wave potential of 0.918V vs. RHE. Additionally, through in situ X-ray absorption fine structure tests, we discover that the low-valent Cuprous-S1N3 moiety acts as an active center during the oxygen reduction process. Our discovery provides a universal scheme for the controllable synthesis and performance regulation of single metal atom catalysts toward energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 688, "Times Cited, All Databases": 705, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3049, "DOI": "10.1038/s41467-020-16848-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16848-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542988800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hsu, PC; Liu, C; Song, AY; Zhang, Z; Peng, YC; Xie, J; Liu, K; Wu, CL; Catrysse, PB; Cai, LL; Zhai, S; Majumdar, A; Fan, SH; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hsu, Po-Chun; Liu, Chong; Song, Alex Y.; Zhang, Ze; Peng, Yucan; Xie, Jin; Liu, Kai; Wu, Chun-Lan; Catrysse, Peter B.; Cai, Lili; Zhai, Shang; Majumdar, Arun; Fan, Shanhui; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A dual-mode textile for human body radiative heating and cooling", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Maintaining human body temperature is one of the most basic needs for living, which often consumes a huge amount of energy to keep the ambient temperature constant. To expand the ambient temperature range while maintaining human thermal comfort, the concept of personal thermal management has been recently demonstrated in heating and cooling textiles separately through human body infrared radiation control. Realizing these two opposite functions within the same textile would represent an exciting scientific challenge and a significant technological advancement. We demonstrate a dual-mode textile that can perform both passive radiative heating and cooling using the same piece of textile without any energy input. The dual-mode textile is composed of a bilayer emitter embedded inside an infrared-transparent nulloporous polyethylene (nulloPE) layer. We demonstrate that the asymmetrical characteristics of both emissivity and nulloPE thickness can result in two different heat transfer coefficients and achieve heating when the low-emissivity layer is facing outside and cooling by wearing the textile inside out when the high-emissivity layer is facing outside. This can expand the thermal comfort zone by 6.5 degrees C. Numerical fitting of the data further predicts 14.7 degrees C of comfort zone expansion for dual-mode textiles with large emissivity contrast.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700895", "DOI": "10.1126/sciadv.1700895", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700895", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418002000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Provis, JL; Palomo, A; Shi, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Provis, John L.; Palomo, Angel; Shi, Caijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in understanding alkali-activated materials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkali activation is a highly active and rapidly developing field of activity in the global research and development community. Commercial-scale deployment of alkali-activated cements and concretes is now proceeding rapidly in multiple nations. This paper reviews the key developments in alkali-activated materials since 2011, with a particular focus on advances in characterisation techniques and structural understanding, binder precursors and activation approaches, durability testing and design, processing, and sustainability. The scientific and engineering developments described in this paper have underpinned the on-going scale-up activities. We also identify important needs for future research and development to support the optimal and appropriate utilisation of alkali activated materials as a component of a sustainable future construction materials industry. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1053, "Times Cited, All Databases": 1115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 78, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 110, "End Page": 125, "Article Number": null, "DOI": "10.1016/j.cemconres.2015.04.013", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2015.04.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364254800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, A; Cao, Q; Zhou, GY; Schmidt, BVKJ; Zhu, WJ; Yuan, XT; Huo, HL; Gong, JL; Antonietti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ang; Cao, Qian; Zhou, Guangye; Schmidt, Bernhard V. K. J.; Zhu, Wenjin; Yuan, Xintong; Huo, Hailing; Gong, Jinlong; Antonietti, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-Phase Photocatalysis for the Enhanced Selectivity and Activity of CO2 Reduction on a Hydrophobic Surface", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photocatalytic CO2 reduction reaction (CRR) represents a promising route for the clean utilization of stranded renewable resources, but poor selectivity resulting from the competing hydrogen evolution reaction (HER) in aqueous solution limits its practical applicability. In the present contribution a photocatalyst with hydrophobic surfaces was fabricated. It facilitates an efficient three-phase contact of CO2 (gas), H2O (liquid), and catalyst (solid). Thus, concentrated CO2 molecules in the gas phase contact the catalyst surface directly, and can overcome the mass-transfer limitations of CO2, inhibit the HER because of lowering proton contacts, and overall enhance the CRR. Even when loaded with platinum nulloparticles, one of the most efficient HER promotion cocatalysts, the three-phase photocatalyst maintains a selectivity of 87.9 %. Overall, three-phase photocatalysis provides a general and reliable method to enhance the competitiveness of the CRR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2019, "Volume": 58, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14549, "End Page": 14555, "Article Number": null, "DOI": "10.1002/anie.201908058", "DOI Link": "http://dx.doi.org/10.1002/anie.201908058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487856700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gludovatz, B; Hohenwarter, A; Thurston, KVS; Bei, HB; Wu, ZG; George, EP; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gludovatz, Bernd; Hohenwarter, Anton; Thurston, Keli V. S.; Bei, Hongbin; Wu, Zhenggang; George, Easo P.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys are an intriguing new class of metallic materials that derive their properties from being multi-element systems that can crystallize as a single phase, despite containing high concentrations of five or more elements with different crystal structures. Here we examine an equiatomic medium-entropy alloy containing only three elements, CrCoNi, as a single-phase face-centred cubic solid solution, which displays strength-toughness properties that exceed those of all high-entropy alloys and most multi-phase alloys. At room temperature, the alloy shows tensile strengths of almost 1 GPa, failure strains of similar to 70% and K-JIc fracture-toughness values above 200 MPa m(1/2); at cryogenic temperatures strength, ductility and toughness of the CrCoNi alloy improve to strength levels above 1.3 GPa, failure strains up to 90% and K-JIc values of 275 MPa m(1/2). Such properties appear to result from continuous steady strain hardening, which acts to suppress plastic instability, resulting from pronounced dislocation activity and deformation-induced nullo-twinning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1416, "Times Cited, All Databases": 1498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10602, "DOI": "10.1038/ncomms10602", "DOI Link": "http://dx.doi.org/10.1038/ncomms10602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371019700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, KY; Shuhendler, AJ; Jokerst, JV; Mei, JG; Gambhir, SS; Bao, ZN; Rao, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Kanyi; Shuhendler, Adam J.; Jokerst, Jesse V.; Mei, Jianguo; Gambhir, Sanjiv S.; Bao, Zhenull; Rao, Jianghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semiconducting polymer nulloparticles as photoacoustic molecular imaging probes in living mice", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoacoustic imaging holds great promise for the visualization of physiology and pathology at the molecular level with deep tissue penetration and fine spatial resolution. To fully utilize this potential, photoacoustic molecular imaging probes have to be developed. Here, we introduce near-infrared light absorbing semiconducting polymer nulloparticles as a new class of contrast agents for photoacoustic molecular imaging. These nulloparticles can produce a stronger signal than the commonly used single-walled carbon nullotubes and gold nullorods on a per mass basis, permitting whole-body lymph-node photoacoustic mapping in living mice at a low systemic injection mass. Furthermore, the semiconducting polymer nulloparticles possess high structural flexibility, narrow photoacoustic spectral profiles and strong resistance to photodegradation and oxidation, enabling the development of the first near-infrared ratiometric photoacoustic probe for in vivo real-time imaging of reactive oxygen species-vital chemical mediators of many diseases. These results demonstrate semiconducting polymer nulloparticles to be an ideal nulloplatform for developing photoacoustic molecular probes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1030, "Times Cited, All Databases": 1082, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 233, "End Page": 239, "Article Number": null, "DOI": "10.1038/NnullO.2013.302", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2013.302", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332637200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, D; Baek, DJ; Hong, SS; Kourkoutis, LF; Hikita, Y; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Di; Baek, David J.; Hong, Seung Sae; Kourkoutis, Lena F.; Hikita, Yasuyuki; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to create and manipulate materials in two-dimensional (2D) form has repeatedly had transformative impact on science and technology. In parallel with the exfoliation and stacking of intrinsically layered crystals(1-5), atomic-scale thin film growth of complex materials has enabled the creation of artificial 2D heterostructures with novel functionality(6-9) and emergent phenomena, as seen in perovskite heterostructures(10-12). However, separation of these layers from the growth substrate has proved challenging, limiting the manipulation capabilities of these heterostructures with respect to exfoliated materials. Here we present a general method to create freestanding perovskite membranes. The key is the epitaxial growth of water-soluble Sr3Al2O6 on perovskite substrates, followed by in situ growth of films and heterostructures. Millimetre-size single-crystalline membranes are produced by etching the Sr3Al2O6 layer in water, providing the opportunity to transfer them to arbitrary substrates and integrate them with heterostructures of semiconductors and layered compounds's(13,14).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 15, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1255, "End Page": 1260, "Article Number": null, "DOI": "10.1038/nmat4749", "DOI Link": "http://dx.doi.org/10.1038/nmat4749", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389104400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, SD; Chen, JR; Liu, YF; Jiang, Y; Jiang, CG; Yin, ZL; Xiao, YG; Cao, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Shidong; Chen, Juanrong; Liu, Yifei; Jiang, Ying; Jiang, Caiguo; Yin, Zhengliang; Xiao, Yingguan; Cao, Shunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silver nulloparticles confined in shell-in-shell hollow TiO2 manifesting efficiently photocatalytic activity and stability", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complete degradation of tetracycline still is a challenge for TiO2-based photocatalysts under simulated solar light irradiation. To tackle this challenge, we devise Ag nulloparticles (Ag NPs) confined in shell-in-shell hollow TiO2 photocatalyst (HTAT). This strategy mainly involves the construction of CPS@TiO2 core-shell composites, the form of TiO2 inner shell, AgNPs loading by photo-deposition, the assembly of TiO2 outer shell, and phase transition of anatase TiO2 by calcination at 450 degrees C. All characterizations including TEM, STEM Mapping, BET, and XPS confirm the unique structure of the as-synthesized HTAT photocatalyst. As expected, the complete degradation of tetracycline (TC and TCH) can be realized by using HTAT photocatalyst under simulated solar light irradiation because its TiO2 two shells simultaneously take part in the photodegrading reaction of TC or TCH. The transformation intermediates and degradation pathway were analyzed by LC/MS. Our work effectively overcomes the disadvantages of many previously reported TiO2-based photocatalysts for the incomplete degradation of tetracycline.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2019, "Volume": 367, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 249, "End Page": 259, "Article Number": null, "DOI": "10.1016/j.cej.2019.02.123", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.02.123", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461380400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZH; Sedighi, M; Lea-Langton, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ziheng; Sedighi, Majid; Lea-Langton, Amanda", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Filtration of microplastic spheres by biochar: removal efficiency and immobilisation mechanisms", "Source Title": "WATER RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extensive presence of microplastic pollution in the aquatic environment has recently been identified as a critical global challenge. A large proportion of the microplastic in aquatic environments originates from the effluent discharges from wastewater treatment plants and urban runoff. We present an experimental study on the removal of microplastic spheres using biochar as potential low-cost material for integra-tion in sand filter systems to improve their efficiency for removing microbeads in wastewater treatment plants. Based on the results of a series of filtration tests and microscopic characterisation, the major mechanisms of interactions between the microplastic spheres and biochar and immobilisation processes are presented. The results of leaching column tests on three biochar samples produced at three different temperatures from corn straw and a hardwood biochar are compared. The results show that the biochar filters provide significant capacity for the removal and immobilisation of 10 mu m diameter microplastic spheres (above 95%) which is much larger than that of similar grain-sized sand filter studied. The extensive ESEM microscopic examination on the samples retrieved after the leaching tests show that the microplastic spheres were immobilised through three morphologically controlled mechanisms which are conceptualised to be ' Stuck ', ' Trapped ' and ' Entangled ' whilst the microplastic spheres only ' Stuck ' in sand filter. The presence of abundant honeycomb structures and thin chips to the high removal and immobilisation capacity of corn straw biochar produced at 500 degrees C and the hardwood biochar. In this study, we demonstrate that biochar can offer extensive potential for immobilisation of microplastic spheres (microbeads). This capacity can in principle be investigated and utilised to improve the efficiency of sand filters to remove microplastic in wastewater treatment plants. (c) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2020, "Volume": 184, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.watres.2020.116165", "DOI Link": "http://dx.doi.org/10.1016/j.watres.2020.116165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000589969100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LX; Chen, W; Zhang, HB; Ye, LX; Wang, ZG; Zhang, Y; Min, P; Yu, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Liu-Xin; Chen, Wei; Zhang, Hao-Bin; Ye, Lvxuan; Wang, Zhenguo; Zhang, Yu; Min, Peng; Yu, Zhong-Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Super-Tough and Environmentally Stable Aramid nullofiber@MXene Coaxial Fibers with Outstanding Electromagnetic Interference Shielding Efficiency", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although electrically conductive and hydrophilic MXene sheets are promising for multifunctional fibers and electronic textiles, it is still a challenge to simultaneously ANF enhance both conductivity and mechanical properties of MXene fibers because of the high rigidity of MXene sheets and insufficient inter-sheet interactions. Herein, we demonstrate a core-shell wet-spinning methodology for fabricating highly conductive, super-tough, ultra-strong, and environmentally stable Ti3C2Tx MXene-based core-shell fibers with conductive MXene cores and tough aramid nullofiber (ANF) shells. The highly orientated and low-defect structure endows the ANF@MXene core-shell fiber with super-toughness of similar to 48.1 MJ m(-3), high strength of 502.9 MPa, and high conductivity of similar to 3.0 x10(5) S m(-1). The super-tough and conductive ANF@MXene fibers can be woven into textiles, exhibiting an excellent electromagnetic interference (EMI) shielding efficiency of 83.4 dB at a small thickness of 213 mu m. Importantly, the protection of the ANF shells provides the fibers with satisfactory cyclic stability under dynamic stretching and bending, and excellent resistance to acid, alkali, seawater, cryogenic and high temperatures, and fire. The oxidation resistance of the fibers is demonstrated by their well-maintained EMI shielding performances. The multifunctional core-shell fibers would be highly promising in the fields of EMI shielding textiles, wearable electronics and aerospace.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111, "DOI": "10.1007/s40820-022-00853-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00853-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786406500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, G; Zandavi, SH; Javid, SM; Boriskina, SV; Cooper, TA; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, George; Zandavi, Seyed Hadi; Javid, Seyyed Morteza; Boriskina, Svetlana V.; Cooper, Thomas A.; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A salt-rejecting floating solar still for low-cost desalination", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although desalination technologies have been widely adopted as a means to produce freshwater, many of them require large installations and access to advanced infrastructure. Recently, floating structures for solar evaporation have been proposed, employing the concept of interfacial solar heat localization as a high-efficiency approach to desalination. However, the challenge remains to prevent salt accumulation while simultaneously maintaining heat localization. This paper presents an experimental demonstration of a salt-rejecting evaporation structure that can operate continuously under sunlight to generate clean vapor while floating in a saline body of water such as an ocean. The evaporation structure is coupled with a low-cost polymer film condensation cover to produce freshwater at a rate of 2.5 L m(-2) day(-1), enough to satisfy individual drinking needs. The entire system's material cost is $3 m(-2) - over an order of magnitude lower than conventional solar stills, does not require energy infrastructure, and can provide cheap drinking water to water-stressed and disaster-stricken communities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 743, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2018, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1510, "End Page": 1519, "Article Number": null, "DOI": "10.1039/c8ee00220g", "DOI Link": "http://dx.doi.org/10.1039/c8ee00220g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435351000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ze, QJ; Wu, S; Nishikawa, J; Dai, JZ; Sun, Y; Leanza, S; Zemelka, C; Novelino, LS; Paulino, GH; Zhao, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ze, Qiji; Wu, Shuai; Nishikawa, Jun; Dai, Jize; Sun, Yue; Leanza, Sophie; Zemelka, Cole; Novelino, Larissa S.; Paulino, Glaucio H.; Zhao, Ruike Renee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft robotic origami crawler", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimetic soft robotic crawlers have attracted extensive attention in various engineering fields, owing to their adaptivity to different terrains. Earthworm-like crawlers realize locomotion through in-plane contraction, while inchworm-like crawlers exhibit out-of-plane bending-based motions. Although in-plane contraction crawlers demonstrate effective motion in confined spaces, miniaturization is challenging because of limited actuation methods and complex structures. Here, we report a magnetically actuated small-scale origami crawler with inplane contraction. The contraction mechanism is achieved through a four-unit Kresling origami assembly consisting of two Kresling dipoles with two-level symmetry. Magnetic actuation is used to provide appropriate torque distribution, enabling a small-scale and untethered robot with both crawling and steering capabilities. The crawler can overcome large resistances from severely confined spaces by its anisotropic and magnetically tunable structural stiffness. The multifunctionality of the crawler is explored by using the internal cavity of the crawler for drug storage and release. The magnetic origami crawler can potentially serve as a minimally invasive device for biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 8, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm7834", "DOI": "10.1126/sciadv.abm7834", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm7834", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778886800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, LY; Wang, HF; Li, CX; Xu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Liyu; Wang, Hao-Fan; Li, Caixia; Xu, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimetallic metal-organic frameworks and their derivatives", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bimetallic metal-organic frameworks (MOFs) have two different metal ions in the inorganic nodes. According to the metal distribution, the architecture of bimetallic MOFs can be classified into two main categories namely solid solution and core-shell structures. Various strategies have been developed to prepare bimetallic MOFs with controlled compositions and structures. Bimetallic MOFs show a synergistic effect and enhanced properties compared to their monometallic counterparts and have found many applications in the fields of gas adsorption, catalysis, energy storage and conversion, and luminescence sensing. Moreover, bimetallic MOFs can serve as excellent precursors/templates for the synthesis of functional nullomaterials with controlled sizes, compositions, and structures. Bimetallic MOF derivatives show exposed active sites, good stability and conductivity, enabling them to extend their applications to the catalysis of more challenging reactions and electrochemical energy storage and conversion. This review provides an overview of the significant advances in the development of bimetallic MOFs and their derivatives with special emphases on their preparation and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2020, "Volume": 11, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5369, "End Page": 5403, "Article Number": null, "DOI": "10.1039/d0sc01432j", "DOI Link": "http://dx.doi.org/10.1039/d0sc01432j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000538158300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JP; Hu, Y; Zhang, LA; Zhou, JP; Lu, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jipeng; Hu, Yang; Zhang, Lina; Zhou, Jinping; Lu, Ang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent, Ultra-Stretching, Tough, Adhesive Carboxyethyl Chitin/Polyacrylamide Hydrogel Toward High-Performance Soft Electronics", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date, hydrogels have gained increasing attentions as a flexible conductive material in fabricating soft electronics. However, it remains a big challenge to integrate multiple functions into one gel that can be used widely under various conditions. Herein, a kind of multifunctional hydrogel with a combination of desirable characteristics, including remarkable transparency, high conductivity, ultra-stretchability, toughness, good fatigue resistance, and strong adhesive ability is presented, which was facilely fabricated through multiple noncovalent crosslinking strategy. The resultant versatile sensors are able to detect both weak and large deformations, which owns a low detection limit of 0.1% strain, high stretchability up to 1586%, ultrahigh sensitivity with a gauge factor up to 18.54, as well as wide pressure sensing range (0-600 kPa). Meanwhile, the fabrication of conductive hydrogel-based sensors is demonstrated for various soft electronic devices, including a flexible human-machine interactive system, the soft tactile switch, an integrated electronic skin for unprecedented nonplanar visualized pressure sensing, and the stretchable triboelectric nullogenerators with excellent biomechanical energy harvesting ability. This work opens up a simple route for multifunctional hydrogel and promises the practical application of soft and self-powered wearable electronics in various complex scenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8, "DOI": "10.1007/s40820-022-00980-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00980-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000895260600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, T; Grossman, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Tian; Grossman, Jeffrey C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal Graph Convolutional Neural Networks for an Accurate and Interpretable Prediction of Material Properties", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of machine learning methods for accelerating the design of crystalline materials usually requires manually constructed feature vectors or complex transformation of atom coordinates to input the crystal structure, which either constrains the model to certain crystal types or makes it difficult to provide chemical insights. Here, we develop a crystal graph convolutional neural networks framework to directly learn material properties from the connection of atoms in the crystal, providing a universal and interpretable representation of crystalline materials. Our method provides a highly accurate prediction of density functional theory calculated properties for eight different properties of crystals with various structure types and compositions after being trained with 104 data points. Further, our framework is interpretable because one can extract the contributions from local chemical environments to global properties. Using an example of perovskites, we show how this information can be utilized to discover empirical rules for materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1518, "Times Cited, All Databases": 1718, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2018, "Volume": 120, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 145301, "DOI": "10.1103/PhysRevLett.120.145301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.145301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429451000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Paek, E; Hwang, GS; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong S.; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulphur batteries with a high theoretical energy density are regarded as promising energy storage devices for electric vehicles and large-scale electricity storage. However, the low active material utilization, low sulphur loading and poor cycling stability restrict their practical applications. Herein, we present an effective strategy to obtain Li/polysulphide batteries with high-energy density and long-cyclic life using three-dimensional nitrogen/sulphur codoped graphene sponge electrodes. The nitrogen/sulphur codoped graphene sponge electrode provides enough space for a high sulphur loading, facilitates fast charge transfer and better immobilization of polysulphide ions. The hetero-doped nitrogen/sulphur sites are demonstrated to show strong binding energy and be capable of anchoring polysulphides based on first-principles calculations. As a result, a high specific capacity of 1,200 mAhg(-1) at 0.2C rate, a high-rate capacity of 430 mAhg(-1) at 2C rate and excellent cycling stability for 500 cycles with similar to 0.078% capacity decay per cycle are achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 955, "Times Cited, All Databases": 1005, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7760, "DOI": "10.1038/ncomms8760", "DOI Link": "http://dx.doi.org/10.1038/ncomms8760", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carrington, EJ; McAnally, CA; Fletcher, AJ; Thompson, SP; Warren, M; Brammer, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carrington, Elliot J.; McAnally, Craig A.; Fletcher, Ashleigh J.; Thompson, Stephen P.; Warren, Mark; Brammer, Lee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent-switchable continuous-breathing behaviour in a diamondoid metal-organic framework and its influence on CO2 versus CH4 selectivity", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the behaviour of flexible metal-organic frameworks (MOFs)-porous crystalline materials that undergo a structural change upon exposure to an external stimulus-underpins their design as responsive materials for specific applications, such as gas separation, molecular sensing, catalysis and drug delivery. Reversible transformations of a MOF between open-and closed-pore forms-a behaviour known as 'breathing'-typically occur through well-defined crystallographic transitions. By contrast, continuous breathing is rare, and detailed characterization has remained very limited. Here we report a continuous-breathing mechanism that was studied by single-crystal diffraction in a MOF with a diamondoid network, (Me2NH2)[In(ABDC)(2)] (ABDC, 2-aminobenzene-1,4-dicarboxylate). Desolvation of the MOF in two different solvents leads to two polymorphic activated forms with very different pore openings, markedly different gas-adsorption capacities and different CO2 versus CH4 selectivities. Partial desolvation introduces a gating pressure associated with CO2 adsorption, which shows that the framework can also undergo a combination of stepped and continuous breathing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 882, "End Page": 889, "Article Number": null, "DOI": "10.1038/NCHEM.2747", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2747", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408323300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khurana, R; Schaefer, JL; Archer, LA; Coates, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khurana, Rachna; Schaefer, Jennifer L.; Archer, Lynden A.; Coates, Geoffrey W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid polymer electrolyte (SPE) membranes are a critical component of high specific energy rechargeable Li-metal polymer (LMP) batteries. SPEs exhibit low volatility and thus increase the safety of Li-based batteries compared to current state-of-the-art Li-ion batteries that use flammable small-molecule electrolytes. However, most SPEs exhibit low ionic conductivity at room temperature, and often allow the growth of lithium dendrites that short-circuit the batteries. Both of these deficiencies are significant barriers to the commercialization of LMP batteries. Herein we report a cross-linked polyethylene/poly(ethylene oxide) SPE with both high ionic conductivity (>1.0 x 10(-4) S/cm at 25 degrees C) and excellent resistance to dendrite growth. It has been proposed that SPEs with shear moduli of the same order of magnitude as lithium could be used to suppress dendrite growth, leading to increased lifetime and safety for LMP batteries. In contrast to the theoretical predictions, the low-modulus (G' approximate to 1.0 X 10(5) Pa at 90 degrees C) cross-linked SPEs reported herein exhibit remarkable dendrite growth resistance. These results suggest that a high-modulus SPE is not a requirement for the control of dendrite proliferation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 743, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2014, "Volume": 136, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7395, "End Page": 7402, "Article Number": null, "DOI": "10.1021/ja502133j", "DOI Link": "http://dx.doi.org/10.1021/ja502133j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336416600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, F; Tian, H; Shen, Y; Hou, Z; Ren, J; Gou, GY; Sun, YB; Yang, Y; Ren, TL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fan; Tian, He; Shen, Yang; Hou, Zhan; Ren, Jie; Gou, Guangyang; Sun, Yabin; Yang, Yi; Ren, Tian-Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertical MoS2 transistors with sub-1-nm gate lengths", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-scaled transistors are of interest in the development of next-generation electronic devices(1-3). Although atomically thin molybdenum disulfide (MoS2) transistors have been reported(4), the fabrication of devices with gate lengths below 1 nm has been challenging(5). Here we demonstrate side-wall MoS2 transistors with an atomically thin channel and a physical gate length of sub-1 nm using the edge of a graphene layer as the gate electrode. The approach uses large-area graphene and MoS2 films grown by chemical vapour deposition for the fabrication of side-wall transistors on a 2-inch wafer. These devices have On/Off ratios up to 1.02 x 10(5) and subthreshold swing values down to 117 mV dec(-1). Simulation results indicate that the MoS2 side-wall effective channel length approaches 0.34 nm in the On state and 4.54 nm in the Off state. This work can promote Moore's law of the scaling down of transistors for next-generation electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 358, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 603, "Issue": 7900, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 259, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04323-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04323-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918198200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, HW; Wang, RY; Pasta, M; Lee, SW; Liu, N; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hyun-Wook; Wang, Richard Y.; Pasta, Mauro; Lee, Seok Woo; Liu, Nian; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potential applications of sodium-ion batteries in grid-scale energy storage, portable electronics and electric vehicles have revitalized research interest in these batteries. However, the performance of sodium-ion electrode materials has not been competitive with that of lithium-ion electrode materials. Here we present sodium manganese hexacyanomanganate (Na2MnII[Mn-II(CN)(6)]), an open-framework crystal structure material, as a viable positive electrode for sodium-ion batteries. We demonstrate a high discharge capacity of 209 mAh g(-1) at C/5 (40 mA g(-1)) and excellent capacity retention at high rates in a propylene carbonate electrolyte. We provide chemical and structural evidence for the unprecedented storage of 50% more sodium cations than previously thought possible during electrochemical cycling. These results represent a step forward in the development of sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 721, "Times Cited, All Databases": 760, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5280, "DOI": "10.1038/ncomms6280", "DOI Link": "http://dx.doi.org/10.1038/ncomms6280", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343985900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Couly, C; Alhabeb, M; Van Aken, KL; Kurra, N; Gomes, L; Navarro-Suárez, AM; Anasori, B; Alshareef, HN; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Couly, Cedric; Alhabeb, Mohamed; Van Aken, Katherine L.; Kurra, Narendra; Gomes, Luisa; Navarro-Suarez, Adriana M.; Anasori, Babak; Alshareef, Husam N.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Asymmetric Flexible MXene-Reduced Graphene Oxide Micro-Supercapacitor", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current microfabrication of micro-supercapacitors often involves multistep processing and delicate lithography protocols. In this study, simple fabrication of an asymmetric MXene-based micro-supercapacitor that is flexible, binder-free, and current-collector-free is reported. The interdigitated device architecture is fabricated using a custom-made mask and a scalable spray coating technique onto a flexible, transparent substrate. The electrode materials are comprised of titanium carbide MXene (Ti3C2Tx) and reduced graphene oxide (rGO), which are both 2D layered materials that contribute to the fast ion diffusion in the interdigitated electrode architecture. This MXene-based asymmetric micro-supercapacitor operates at a 1 V voltage window, while retaining 97% of the initial capacitance after ten thousand cycles, and exhibits an energy density of 8.6 mW h cm(-3) at a power density of 0.2 W cm(-3). Further, these micro-supercapacitors show a high level of flexibility during mechanical bending. Utilizing the ability of Ti3C2Tx-MXene electrodes to operate at negative potentials in aqueous electrolytes, it is shown that using Ti3C2Tx as a negative electrode and rGO as a positive one in asymmetric architectures is a promising strategy for increasing both energy and power densities of micro-supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700339, "DOI": "10.1002/aelm.201700339", "DOI Link": "http://dx.doi.org/10.1002/aelm.201700339", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419670400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Qin, ZD; Ries, L; Hong, S; Michel, T; Yang, J; Salameh, C; Bechelany, M; Miele, P; Kaplan, D; Chhowalla, M; Voiry, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Lei; Qin, Zhaodan; Ries, Lucie; Hong, Song; Michel, Thierry; Yang, Jieun; Salameh, Chrystelle; Bechelany, Mikhael; Miele, Philippe; Kaplan, Daniel; Chhowalla, Manish; Voiry, Damien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of Sulfur Vacancies and Undercoordinated Mo Regions in MoS2 nullosheets toward the Evolution of Hydrogen", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-dimensional materials have been examined as electrocatalysts for the hydrogen evolution reaction (HER). Among them, two-dimensional transition metal dichalcogenides (2D-TMDs) such as MoS2 have been identified as potential candidates. However, the performance of TMDs toward HER in both acidic and basic media remains inferior to that of noble metals such as Pt and its alloys. This calls for investigating the influence of controlled defect engineering of 2D TMDs on their performance toward hydrogen production. Here, we explored the HER activity from defective multilayered MoS2 over a large range of surface S vacancy concentrations up to 90%. Amorphous MoS2 and 2H MoS2 with ultrarich S vacancies demonstrated the highest HER performance in acid and basic electrolytes, respectively. We also report that the HER performance from multilayered MoS2 can be divided into two domains corresponding to point defects at low concentrations of surface S vacancies (Stage 1) and large regions of undercoordinated Mo atoms for high concentrations of surface S vacancies (Stage 2). The highest performance is obtained for Stage 2 in the presence of undercoordinated Mo atoms with a TOF of similar to 2 s(-1) at an overpotential of 160 mV in 0.1 M KOH which compares favorably to the best results in the literature. Overall, our work provides deeper insight on the HER mechanism from defected MoS2 and provides guidance for the development of defect-engineered TMD-based electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6824, "End Page": 6834, "Article Number": null, "DOI": "10.1021/acsnullo.9b01583", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b01583", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473248300066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uheida, A; Mejia, HG; Abdel-Rehim, M; Hamd, W; Dutta, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uheida, Abdusalam; Mejia, Hugo Giraldo; Abdel-Rehim, Mohamed; Hamd, Wael; Dutta, Joydeep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible light photocatalytic degradation of polypropylene microplastics in a continuous water flow system", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastic pollution of water and ecosystem is attracting continued attention worldwide. Due to their small sizes (<= 5 mm) microplastic particles can be discharged to the environment from treated wastewater effluents. As microplastics have polluted most of our aquatic ecosystems, often finding its way into drinking water, there is urgent need to find new solutions for tackling the menace of microplastic pollution. In this work, sustainable green photocatalytic removal of microplastics from water activated by visible light is proposed as a tool for the removal of microplastics from water. We propose a novel strategy for the elimination of microplastics using glass fiber substrates to trap low density microplastic particles such as polypropylene (PP) which in parallel support the photocatalyst material. Photocatalytic degradation of PP microplastics spherical particles suspended in water by visible light irradiation of zinc oxide nullorods (ZnO NRs) immobilized onto glass fibers substrates in a flow through system is demonstrated. Upon irradiation of PP microplastics for two weeks under visible light reduced led to a reduction of the average particle volume by 65%. The major photodegradation by-products were identified using GC/MS and found to be molecules that are considered to be mostly nontoxic in the literature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 406, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124299, "DOI": "10.1016/j.jhazmat.2020.124299", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2020.124299", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662119400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Back, S; Lim, J; Kim, NY; Kim, YH; Jung, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Back, Seoin; Lim, Juhyung; Kim, Na-Young; Kim, Yong-Hyun; Jung, Yousung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom catalysts for CO2 electroreduction with significant activity and selectivity improvements", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A single-atom catalyst (SAC) has an electronic structure that is very different from its bulk counterparts, and has shown an unexpectedly high specific activity with a significant reduction in noble metal usage for CO oxidation, fuel cell and hydrogen evolution applications, although physical origins of such performance enhancements are still poorly understood. Herein, by means of density functional theory (DFT) calculations, we for the first time investigate the great potential of single atom catalysts for CO2 electroreduction applications. In particular, we study a single transition metal atom anchored on defective graphene with single or double vacancies, denoted M@sv-Gr or M@dv-Gr, where M = Ag, Au, Co, Cu, Fe, Ir, Ni, Os, Pd, Pt, Rh or Ru, as a CO2 reduction catalyst. Many SACs are indeed shown to be highly selective for the CO2 reduction reaction over a competitive H-2 evolution reaction due to favorable adsorption of carboxyl (*COOH) or formate (*OCHO) over hydrogen (*H) on the catalysts. On the basis of free energy profiles, we identified several promising candidate materials for different products; Ni@dv-Gr (limiting potential U-L = -0.41 V) and Pt@dv-Gr (-0.27 V) for CH3OH production, and Os@dvGr (-0.52 V) and Ru@dv-Gr (-0.52 V) for CH4 production. In particular, the Pt@dv-Gr catalyst shows remarkable reduction in the limiting potential for CH3OH production compared to any existing catalysts, synthesized or predicted. To understand the origin of the activity enhancement of SACs, we find that the lack of an atomic ensemble for adsorbate binding and the unique electronic structure of the single atom catalysts as well as orbital interaction play an important role, contributing to binding energies of SACs that deviate considerably from the conventional scaling relation of bulk transition metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1090, "End Page": 1096, "Article Number": null, "DOI": "10.1039/c6sc03911a", "DOI Link": "http://dx.doi.org/10.1039/c6sc03911a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395428300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geng, XM; Sun, WW; Wu, W; Chen, B; Al-Hilo, A; Benamara, M; Zhu, HL; Watanabe, F; Cui, JB; Chen, TP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geng, Xiumei; Sun, Weiwei; Wu, Wei; Chen, Benjamin; Al-Hilo, Alaa; Benamara, Mourad; Zhu, Hongli; Watanabe, Fumiya; Cui, Jingbiao; Chen, Tar-pin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pure and stable metallic phase molybdenum disulfide nullosheets for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic-phase MoS2 (M-MoS2) is metastable and does not exist in nature. Pure and stable M-MoS2 has not been previously prepared by chemical synthesis, to the best of our knowledge. Here we report a hydrothermal process for synthesizing stable two-dimensional M-MoS2 nullosheets in water. The metal-metal Raman stretching mode at 146 cm(-1) in the M-MoS2 structure, as predicted by theoretical calculations, is experimentally observed. The stability of the M-MoS2 is associated with the adsorption of a monolayer of water molecules on both sides of the nullosheets, which reduce restacking and prevent aggregation in water. The obtained M-MoS2 exhibits excellent stability in water and superior activity for the hydrogen evolution reaction, with a current density of 10mAcm(-2) at a low potential of -175mV and a Tafel slope of 41mV per decade.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 833, "Times Cited, All Databases": 874, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10672, "DOI": "10.1038/ncomms10672", "DOI Link": "http://dx.doi.org/10.1038/ncomms10672", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371021000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, H; Li, MJ; Li, QS; Liang, SJ; Tan, YY; Sheng, L; Shi, W; Zhang, SXA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Hui; Li, Minjie; Li, Quanshun; Liang, Shaojun; Tan, Yingying; Sheng, Lan; Shi, Wei; Zhang, Sean Xiao-An", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Dots with Continuously Tunable Full-Color Emission and Their Application in Ratiometric pH Sensing", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two types of carbon dots (C dots) exhibiting respective excitation-independent blue emission and excitation-dependent full-color emissions have been synthesized via a mild one-pot process from chloroform and diethylamine. This new bottom-up synthetic strategy leads to highly stable crystalline C dots with tunable surface functionalities in high reproducibility. By detailed characterization and comparison of the two types of C dots, it is proved concretely that the surface functional groups, such as C=O and C=N, can efficiently introduce new energy levels for electron transitions and result in the continuously adjustable full-color emissions. A simplified energy level and electron transition diagram has been proposed to help understand how surface functional groups affect the emission properties. By taking advantage of the unique excitation-dependent full-color emissions, various new applications can be anticipated. Here, as an example, a ratiometric pH sensor using two emission wavelengths of the C dots as independent references has been constructed to improve the reliability and accuracy, and the pH sensor is applied to the measurement of intracellular pH values and cancer diagnosis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 831, "Times Cited, All Databases": 877, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 27", "Publication Year": 2014, "Volume": 26, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3104, "End Page": 3112, "Article Number": null, "DOI": "10.1021/cm5003669", "DOI Link": "http://dx.doi.org/10.1021/cm5003669", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336637000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XL; Tang, YB; Zhang, F; Lee, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaolong; Tang, Yongbing; Zhang, Fan; Lee, Chun-Sing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Aluminum-Graphite Dual-Ion Battery", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1748, "Times Cited, All Databases": 1772, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2016, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1502588, "DOI": "10.1002/aenm.201502588", "DOI Link": "http://dx.doi.org/10.1002/aenm.201502588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379311500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, BH; Liu, DY; Mubeen, S; Chuong, TT; Moskovits, M; Stucky, GD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Binghui; Liu, Deyu; Mubeen, Syed; Chuong, Tracy T.; Moskovits, Martin; Stucky, Galen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic Growth of TiO2 onto Gold nullorods for Plasmon-Enhanced Hydrogen Production from Water Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmonic metal/semiconductor heterostructures show promise for visible-light-driven photo catalysis. Gold nullorods (AuNRs) semi-coated with TiO2 are expected to be ideally structured systems for hydrogen evolution. Synthesizing such structures by wet-chemistry methods, however, has proved challenging. Here we report the bottom-up synthesis of AuNR/TiO2 nullodumbbells (NDs) with spatially separated Au/TiO2 regions, whose structures are governed by the NRs' diameter, and the higher curvature and lower density of C-n TAB surfactant at the NRs' tips than on their lateral surfaces, as well as the morphology's dependence on concentration, and alkyl chain length of C-n TAB. The NDs show plasmon-enhanced H-2 evolution under visible and near-infrared light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2016, "Volume": 138, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1114, "End Page": 1117, "Article Number": null, "DOI": "10.1021/jacs.5b11341", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11341", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369558000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, HB; Yu, RF; Ma, SC; Xu, KZ; Chen, Y; Jiang, K; Fang, Y; Zhu, CX; Liu, XC; Tang, Y; Wu, LZ; Wu, YQ; Jiang, QK; He, P; Liu, ZP; Tan, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Huibo; Yu, Ruofan; Ma, Sicong; Xu, Kaizhuang; Chen, Yang; Jiang, Kun; Fang, Yuan; Zhu, Caixia; Liu, Xiaochen; Tang, Yu; Wu, Lizhi; Wu, Yingquan; Jiang, Qike; He, Peng; Liu, Zhipan; Tan, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of Cu1-O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-based catalysts for the hydrogenation of CO2 to methanol have attracted much interest. The complex nature of these catalysts, however, renders the elucidation of their structure-activity properties difficult. Here we report a copper-based catalyst with isolated active copper sites for the hydrogenation of CO2 to methanol. It is revealed that the single-atom Cu-Zr catalyst with Cu-1-O-3 units contributes solely to methanol synthesis around 180 degrees C, while the presence of small copper clusters or nulloparticles with Cu-Cu structural patterns are responsible for forming the CO by-product. Furthermore, the gradual migration of Cu-1-O-3 units with a quasiplanar structure to the catalyst surface is observed during the catalytic process and accelerates CO2 hydrogenation. The highly active, isolated copper sites and the distinguishable structural pattern identified here extend the horizon of single-atom catalysts for applications in thermal catalytic CO2 hydrogenation and could guide the further design of high-performance copper-based catalysts to meet industrial demand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 818, "End Page": 831, "Article Number": null, "DOI": "10.1038/s41929-022-00840-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00840-0", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854746500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YM; Zhao, JH; Wang, H; Xiao, B; Zhang, W; Zhao, XB; Lv, TP; Thangamuthu, M; Zhang, J; Guo, Y; Ma, JN; Lin, LN; Tang, JW; Huang, R; Liu, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yumin; Zhao, Jianhong; Wang, Hui; Xiao, Bin; Zhang, Wen; Zhao, Xinbo; Lv, Tianping; Thangamuthu, Madasamy; Zhang, Jin; Guo, Yan; Ma, Jiani; Lin, Lina; Tang, Junwang; Huang, Rong; Liu, Qingju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Cu anchored catalysts for photocatalytic renewable H2 production with a quantum efficiency of 56%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts anchoring offers a desirable pathway for efficiency maximization and cost-saving for photocatalytic hydrogen evolution. However, the single-atoms loading amount is always within 0.5% in most of the reported due to the agglomeration at higher loading concentrations. In this work, the highly dispersed and large loading amount (>1 wt%) of copper single-atoms were achieved on TiO2, exhibiting the H-2 evolution rate of 101.7 mmol g(-1) h(-1) under simulated solar light irradiation, which is higher than other photocatalysts reported, in addition to the excellent stability as proved after storing 380 days. More importantly, it exhibits an apparent quantum efficiency of 56% at 365 nm, a significant breakthrough in this field. The highly dispersed and large amount of Cu single-atoms incorporation on TiO2 enables the efficient electron transfer via Cu2+-Cu+ process. The present approach paves the way to design advanced materials for remarkable photocatalytic activity and durability. In this work, the highly dispersed and large loading amount (>1 wt%) of copper single-atoms were achieved on TiO2, resulting into an apparent quantum efficiency of 56% at 365 nm, in addition to an excellent thermal stability as proved after storing 380 days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 58, "DOI": "10.1038/s41467-021-27698-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27698-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781259400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YN; Liu, NS; Li, LY; Hu, XK; Zou, ZG; Wang, JB; Luo, SJ; Gao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yanull; Liu, Nishuang; Li, Luying; Hu, Xiaokang; Zou, Zhengguang; Wang, Jianbo; Luo, Shijun; Gao, Yihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly flexible and sensitive piezoresistive sensor based on MXene with greatly changed interlayer distances", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the successful synthesis of the first MXenes, application developments of this new family of two-dimensional materials on energy storage, electromagnetic interference shielding, transparent conductive electrodes and field-effect transistors, and other applications have been widely reported. However, no one has found or used the basic characteristics of greatly changed interlayer distances of MXene under an external pressure for a real application. Here we report a highly flexible and sensitive piezoresistive sensor based on this essential characteristics. An in situ transmission electron microscopy study directly illustrates the characteristics of greatly changed interlayer distances under an external pressure, supplying the basic working mechanism for the piezoresistive sensor. The resultant device also shows high sensitivity (Gauge Factor similar to 180.1), fast response (< 30 ms) and extraordinarily reversible compressibility. The MXene-based piezoresistive sensor can detect human being's subtle bending-release activities and other weak pressure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1207, "DOI": "10.1038/s41467-017-01136-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01136-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414032200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Huang, X; Zhang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuyan; Huang, Xin; Zhang, Xinxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrarobust, tough and highly stretchable self-healing materials based on cartilage-inspired noncovalent assembly nullostructure", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing materials integrated with excellent mechanical strength and simultaneously high healing efficiency would be of great use in many fields, however their fabrication has been proven extremely challenging. Here, inspired by biological cartilage, we present an ultrarobust self-healing material by incorporating high density noncovalent bonds at the interfaces between the dentritic tannic acid-modified tungsten disulfide nullosheets and polyurethane matrix to collectively produce a strong interfacial interaction. The resultant nullocomposite material with interwoven network shows excellent tensile strength (52.3MPa), high toughness (282.7 MJ m(3), which is 1.6 times higher than spider silk and 9.4 times higher than metallic aluminum), high stretchability (1020.8%) and excellent healing efficiency (80-100%), which overturns the previous understanding of traditional noncovalent bonding self-healing materials where high mechanical robustness and healing ability are mutually exclusive. Moreover, the interfacical supramolecular crosslinking structure enables the functional-healing ability of the resultant flexible smart actuation devices. This work opens an avenue toward the development of ultrarobust self-healing materials for various flexible functional devices. Strong self-healing materials with high healing efficiency are of great use in many fields but their fabrication is extremely challenging. Here, the authors present a robust self-healing material by incorporating high density noncovalent bonds at the interfaces between dentritic tannic acid-modified tungsten disulfide nullosheets and a polyurethane matrix to collectively produce a strong interfacial interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1291, "DOI": "10.1038/s41467-021-21577-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21577-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000624978300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, XW; Dai, C; Wang, X; Hu, JY; Zhang, JY; Zheng, LX; Mao, L; Zheng, HJ; Zhu, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xiaowei; Dai, Chao; Wang, Xin; Hu, Jiayue; Zhang, Junying; Zheng, Lingxia; Mao, Liang; Zheng, Huajun; Zhu, Mingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An alternative approach to defect-trapped Pt single-sites on a semiconductor is reported. Here, protruding Pt sites inhibit charge recombination and cause a tip effect which enhances H-2 evolution yield rates with minimal co-catalyst loading. Single-site cocatalysts engineered on supports offer a cost-efficient pathway to utilize precious metals, yet improving the performance further with minimal catalyst loading is still highly desirable. Here we have conducted a photochemical reaction to stabilize ultralow Pt co-catalysts (0.26 wt%) onto the basal plane of hexagonal ZnIn2S4 nullosheets (Pt-SS-ZIS) to form a Pt-S-3 protrusion tetrahedron coordination structure. Compared with the traditional defect-trapped Pt single-site counterparts, the protruding Pt single-sites on h-ZIS photocatalyst enhance the H-2 evolution yield rate by a factor of 2.2, which could reach 17.5 mmol g(-1) h(-1) under visible light irradiation. Importantly, through simple drop-casting, a thin Pt-SS-ZIS film is prepared, and large amount of observable H-2 bubbles are generated, providing great potential for practical solar-light-driven H-2 production. The protruding single Pt atoms in Pt-SS-ZIS could inhibit the recombination of electron-hole pairs and cause a tip effect to optimize the adsorption/desorption behavior of H through effective proton mass transfer, which synergistically promote reaction thermodynamics and kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1287, "DOI": "10.1038/s41467-022-28995-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28995-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767892300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Guo, JH; Wang, Y; Sun, LY; Zhao, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hui; Guo, Jiahui; Wang, Yu; Sun, Lingyu; Zhao, Yuanjin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable and Conductive Composite Structural Color Hydrogel Films as Bionic Electronic Skins", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic skins have received increasing attention in biomedical areas. Current efforts about electronic skins are focused on the development of multifunctional materials to improve their performance. Here, the authors propose a novel natural-synthetic polymers composite structural color hydrogel film with high stretchability, flexibility, conductivity, and superior self-reporting ability to construct ideal multiple-signal bionic electronic skins. The composite hydrogel film is prepared by using the mixture of polyacrylamide (PAM), silk fibroin (SF), poly(3,4-ethylenedioxythiophene):poly (4-styrene sulfonate) (PEDOT:PSS, PP), and graphene oxide (GO) to replicate colloidal crystal templates and construct inverse opal scaffolds, followed by subsequent acid treatment. Due to these specific structures and components, the resultant film is imparted with vivid structural color and high conductivity while retaining the composite hydrogel's original stretchability and flexibility. The authors demonstrate that the composite hydrogel film has obvious color variation and electromechanical properties during the stretching and bending process, which could thus be utilized as a multi-signal response electronic skin to realize real-time color sensing and electrical response during human motions. These features indicate that the proposed composite structural color hydrogel film can widen the practical value of bionic electronic skins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102156, "DOI": "10.1002/advs.202102156", "DOI Link": "http://dx.doi.org/10.1002/advs.202102156", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000688530200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, YL; Li, PF; Zhu, CL; Ning, N; Zhang, SY; Vancso, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Yunlong; Li, Pengfei; Zhu, Chenglei; Ning, Ning; Zhang, Shiyong; Vancso, G. Julius", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional and Recyclable Photothermally Responsive Cryogels as Efficient Platforms for Wound Healing", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A growth in the use of antibiotics and the related evolution of patients' drug resistance calls for an urgent response for the development of novel curing approaches without using synthetic antibiotics. Here, the fabrication of a low-cost cryogel for wound dressing applications is demonstrated. The cryogel is composed of only naturally derived components, including chitosan/silk fibroin as the scaffold and tannic acid/ferric ion (TA/Fe3+) as the stimuli-responsive agent for photothermal therapy. Based on the multiple weak hydrogen bonds and metal ligand coordination, the cryogel exhibits good flexibility and recoverability. Its highly porous structure renders the cryogel to be strongly hygroscopic to absorb blood for hemostasis. The cryogel exhibits excellent antibacterial activity to both Gram-negative and positive bacteria, benefiting from the high photothermal transition activity of the TA/Fe3+ complex. Furthermore, the cryogel can efficiently promote cell proliferation in vitro. Significantly, animal experiments also reveal that the cryogel effectively eradicate microbes at the wound and accelerate the wound healing process. In summary, this novel biorenewable cryogel demonstrates excellent hygroscopic and hemostatic performance, photothermal antimicrobial activity, and accelerates skin regeneration, which has great application potential as a promising wound dressing material in the clinical use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 29, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904402, "DOI": "10.1002/adfm.201904402", "DOI Link": "http://dx.doi.org/10.1002/adfm.201904402", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476297800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fahrenholtz, WG; Hilmas, GE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fahrenholtz, William G.; Hilmas, Greg E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high temperature ceramics: Materials for extreme environments", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper identifies gaps in the present state of knowledge and describes emerging research directions for ultra-high temperature ceramics. Borides, carbides, and nitrides of early transition metals such as Zr, Hf, Nb, and Ta have the highest melting points of any known compounds, making them suitable for use in extreme environments. Studies of synthesis, processing, densification, thermal properties, mechanical behavior, and oxidation of ultra-high temperature ceramics have generated a substantial base of knowledge, but left unullswered questions. Emerging research directions include testing/characterization in extreme environments, composites, computational studies, and new materials. (C) 2016 Acta Materialia Inc Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 670, "Times Cited, All Databases": 717, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2017, "Volume": 129, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 99, "Article Number": null, "DOI": "10.1016/j.scriptamat.2016.10.018", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2016.10.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390513900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Wang, Y; Gu, M; Wang, MY; Zhang, ZS; Pan, WY; Jiang, Z; Zheng, HZ; Lucero, M; Wang, HL; Sterbinsky, GE; Ma, Q; Wang, YG; Feng, ZX; Li, J; Dai, HJ; Liang, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao; Wang, Yang; Gu, Meng; Wang, Maoyu; Zhang, Zisheng; Pan, Weiying; Jiang, Zhan; Zheng, Hongzhi; Lucero, Marcos; Wang, Hailiang; Sterbinsky, George E.; Ma, Qing; Wang, Yang-Gang; Feng, Zhenxing; Li, Jun; Dai, Hongjie; Liang, Yongye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular engineering of dispersed nickel phthalocyanines on carbon nullotubes for selective CO2 reduction", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO(2)is a promising route for sustainable production of fuels. A grand challenge is developing low-cost and efficient electrocatalysts that can enable rapid conversion with high product selectivity. Here we design a series of nickel phthalocyanine molecules supported on carbon nullotubes as molecularly dispersed electrocatalysts (MDEs), achieving CO(2)reduction performances that are superior to aggregated molecular catalysts in terms of stability, activity and selectivity. The optimized MDE with methoxy group functionalization solves the stability issue of the original nickel phthalocyanine catalyst and catalyses the conversion of CO(2)to CO with >99.5% selectivity at high current densities of up to -300 mA cm(-2)in a gas diffusion electrode device with stable operation at -150 mA cm(-2)for 40 h. The well-defined active sites of MDEs also facilitate the in-depth mechanistic understandings from in situ/operando X-ray absorption spectroscopy and theoretical calculations on structural factors that affect electrocatalytic performance. Widespread deployment of electrochemical CO(2)reduction requires low-cost catalysts that perform well at high current densities. Zhang et al. show that methoxy-functionalized nickel phthalocyanine molecules on carbon nullotubes can operate as high-performing molecularly dispersed electrocatalysts at current densities of up to -300 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 684, "End Page": 692, "Article Number": null, "DOI": "10.1038/s41560-020-0667-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0667-9", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558156800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, L; Liu, Q; Gao, J; Zhang, SJ; Li, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lei; Liu, Qing; Gao, Jing; Zhang, Shujun; Li, Jing-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-Free Antiferroelectric Silver Niobate Tantalate with High Energy Storage Performance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferroelectric materials that display double ferroelectric hysteresis loops are receiving increasing attention for their superior energy storage density compared to their ferroelectric counterparts. Despite the good properties obtained in antiferroelectric La-doped Pb(Zr,Ti)O-3-based ceramics, lead-free alternatives are highly desired due to the environmental concerns, and AgNbO3 has been highlighted as a ferrielectric/antiferroelectric perovskite for energy storage applications. Enhanced energy storage performance, with recoverable energy density of 4.2 J cm(-3) and high thermal stability of the energy storage density (with minimal variation of <=+/- 5%) over 20-120 degrees C, can be achieved in Ta-modified AgNbO3 ceramics. It is revealed that the incorporation of Ta to the Nb site can enhance the antiferroelectricity because of the reduced polarizability of B-site cations, which is confirmed by the polarization hysteresis, dielectric tunability, and selected-area electron diffraction measurements. Additionally, Ta addition in AgNbO3 leads to decreased grain size and increased bulk density, increasing the dielectric breakdown strength, up to 240 kV cm(-1) versus 175 kV cm(-1) for the pure counterpart, together with the enhanced antiferroelectricity, accounting for the high energy storage density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 710, "Times Cited, All Databases": 730, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2017, "Volume": 29, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701824, "DOI": "10.1002/adma.201701824", "DOI Link": "http://dx.doi.org/10.1002/adma.201701824", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407565700028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, X; Sheng, P; Tu, ZY; Zhang, FJ; Wang, JH; Geng, H; Zou, Y; Di, CA; Yi, YP; Sun, YM; Xu, W; Zhu, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xing; Sheng, Peng; Tu, Zeyi; Zhang, Fengjiao; Wang, Junhua; Geng, Hua; Zou, Ye; Di, Chong-an; Yi, Yuanping; Sun, Yimeng; Xu, Wei; Zhu, Daoben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, studies on organic two-dimensional (2D) materials with special optic-electronic properties are attracting great research interest. However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT = benzenehexathiol), is prepared via a liquid-liquid interface reaction between BHT/dichloromethane and copper(II) nitrate/H2O. The morphology and structure characterization reveal that this film is piled up by nullosheets of 2D lattice of [Cu-3(C6S6)](n), which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580 S cm (-1), which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99 cm(2) V (-1) s (-1) for holes and 116 cm(2) V (-1) s (-1) for electrons) under field-effect modulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 669, "Times Cited, All Databases": 705, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7408, "DOI": "10.1038/ncomms8408", "DOI Link": "http://dx.doi.org/10.1038/ncomms8408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SS; Rotaru, AE; Shrestha, PM; Malvankar, NS; Liu, FH; Fan, W; Nevin, KP; Lovley, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shanshan; Rotaru, Amelia-Elena; Shrestha, Pravin Malla; Malvankar, Nikhil S.; Liu, Fanghua; Fan, Wei; Nevin, Kelly P.; Lovley, Derek R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting Interspecies Electron Transfer with Biochar", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biochar, a charcoal-like product of the incomplete combustion of organic materials, is an increasingly popular soil amendment designed to improve soil fertility. We investigated the possibility that biochar could promote direct interspecies electron transfer ( DIET) in a manner similar to that previously reported for granular activated carbon (GAC). Although the biochars investigated were 1000 times less conductive than GAC, they stimulated DIET in co-cultures of Geobacter metallireducens with Geobacter sulfurreducens or Methanosarcina barkeri in which ethanol was the electron donor. Cells were attached to the biochar, yet not in close contact, suggesting that electrons were likely conducted through the biochar, rather than biological electrical connections. The finding that biochar can stimulate DIET may be an important consideration when amending soils with biochar and can help explain why biochar may enhance methane production from organic wastes under anaerobic conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 563, "Times Cited, All Databases": 642, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5019, "DOI": "10.1038/srep05019", "DOI Link": "http://dx.doi.org/10.1038/srep05019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336206700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, D; Xie, CL; Becknell, N; Yu, Y; Karamad, M; Chan, K; Crumlin, EJ; Norskov, JK; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Dohyung; Xie, Chenlu; Becknell, Nigel; Yu, Yi; Karamad, Mohammadreza; Chan, Karen; Crumlin, Ethan J.; Norskov, Jens K.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu nulloparticles", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precise control of elemental configurations within multi metallic nulloparticles (NPs) could enable access to functional nullomaterials with significant performance benefits. This can be achieved down to the atomic level by the disorder-to-order transformation of individual NPs. Here, by systematically controlling the ordering degree, we show that the atomic ordering transformation, applied to AuCu NPs, activates them to perform as selective electrocatalysts for CO2 reduction. In contrast to the disordered alloy NP, which is catalytically active for hydrogen evolution, ordered AuCu NPs selectively converted CO2 to CO at faradaic efficiency reaching 80%. CO formation could be achieved with a reduction in overpotential of similar to 200 mV, and catalytic turnover was enhanced by 3.2-fold. In comparison to those obtained with a pure gold catalyst, mass activities could be improved as well. Atomic-level structural investigations revealed three Atomic gold layers over the intermetallic core to be sufficient for enhanced catalytic behavior, which is further supported by DFT analysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 559, "Times Cited, All Databases": 593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 139, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8329, "End Page": 8336, "Article Number": null, "DOI": "10.1021/jacs.7b03516", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b03516", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404090100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GX; Gong, ZG; Luo, XL; Chen, LH; Shuai, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Guangxu; Gong, Zhenggang; Luo, Xiaolin; Chen, Lihui; Shuai, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bonding wood with uncondensed lignins as adhesives", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plywood is widely used in construction, such as for flooring and interior walls, as well as in the manufacture of household items such as furniture and cabinets. Such items are made of wood veneers that are bonded together with adhesives such as urea-formaldehyde and phenol-formaldehyde resins1,2. Researchers in academia and industry have long aimed to synthesize lignin-phenol-formaldehyde resin adhesives using biomass-derived lignin, a phenolic polymer that can be used to substitute the petroleum-derived phenol3-6. However, lignin-phenol-formaldehyde resin adhesives are less attractive to plywood manufacturers than urea-formaldehyde and phenol-formaldehyde resins owing to their appearance and cost. Here we report a simple and practical strategy for preparing lignin-based wood adhesives from lignocellulosic biomass. Our strategy involves separation of uncondensed or slightly condensed lignins from biomass followed by direct application of a suspension of the lignin and water as an adhesive on wood veneers. Plywood products with superior performances could be prepared with such lignin adhesives at a wide range of hot-pressing temperatures, enabling the use of these adhesives as promising alternatives to traditional wood adhesives in different market segments. Mechanistic studies indicate that the adhesion mechanism of such lignin adhesives may involve softening of lignin by water, filling of vessels with softened lignin and crosslinking of lignins in adhesives with those in the cell wall. A straightforward strategy for preparing lignin-based wood adhesives from lignocellulosic biomass is described, with the resulting adhesives demonstrating performance attractive for plywood manufacture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2023, "Volume": 621, "Issue": 7979, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06507-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06507-5", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059705300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HM; Lang, XY; Zhu, C; Timoshenko, J; Rüscher, M; Bai, LC; Guijarro, N; Yin, HB; Peng, Y; Li, JH; Liu, Z; Wang, WC; Roldan Cuenya, B; Luo, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huimin; Lang, Xiuyao; Zhu, Chao; Timoshenko, Janis; Ruescher, Martina; Bai, Lichen; Guijarro, Nestor; Yin, Haibo; Peng, Yue; Li, Junhua; Liu, Zheng; Wang, Weichao; Roldan Cuenya, Beatriz; Luo, Jingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical nitrate reduction reaction (NITRR) provides a promising solution for restoring the imbalance in the global nitrogen cycle while enabling a sustainable and decentralized route to source ammonia. Here, we demonstrate a novel electrocatalyst for NITRR consisting of Rh clusters and single-atoms dispersed onto Cu nullowires (NWs), which delivers a partial current density of 162 mA cm(-2) for NH3 production and a Faradaic efficiency (FE) of 93 % at -0.2 V vs. RHE. The highest ammonia yield rate reached a record value of 1.27 mmol h(-1) cm(-2). Detailed investigations by electron paramagnetic resonullce, in situ infrared spectroscopy, differential electrochemical mass spectrometry and density functional theory modeling suggest that the high activity originates from the synergistic catalytic cooperation between Rh and Cu sites, whereby adsorbed hydrogen on Rh site transfers to vicinal *NO intermediate species adsorbed on Cu promoting the hydrogenation and ammonia formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2022, "Volume": 61, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202202556", "DOI": "10.1002/anie.202202556", "DOI Link": "http://dx.doi.org/10.1002/anie.202202556", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780914100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, DW; Cortie, M; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Dawei; Cortie, Michael; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabrication of N-doped Graphene-Carbon nullotube Hybrids from Prussian Blue for Lithium-Sulfur Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid nullostructures containing 1D carbon nullotubes and 2D graphene sheets have many promising applications due to their unique physical and chemical properties. In this study, the authors find Prussian blue (dehydrated sodium ferrocyanide) can be converted to N-doped graphene-carbon nullotube hybrid materials through a simple one-step pyrolysis process. Through field emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, atomic force microscopy, and isothermal analyses, the authors identify that 2D graphene and 1D carbon nullotubes are bonded seamlessly during the growth stage. When used as the sulfur scaffold for lithium-sulfur batteries, it demonstrates outstanding electrochemical performance, including a high reversible capacity (1221 mA h g(-1) at 0.2 C rate), excellent rate capability (458 and 220 mA h g(-1) at 5 and 10 C rates, respectively), and excellent cycling stability (321 and 164 mA h g(-1) at 5 and 10 C (1 C = 1673 mA g(-1)) after 1000 cycles). The enhancement of electrochemical performance can be attributed to the 3D architecture of the hybrid material, in which, additionally, the nitrogen doping generates defects and active sites for improved interfacial adsorption. Furthermore, the nitrogen doping enables the effective trapping of lithium polysulfides on electroactive sites within the cathode, leading to a much-improved cycling performance. Therefore, the hybrid material functions as a redox shuttle to catenate and bind polysulfides, and convert them to insoluble lithium sulfide during reduction. The strategy reported in this paper could open a new avenue for low cost synthesis of N-doped graphene-carbon nullotube hybrid materials for high performance lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2017, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1602014, "DOI": "10.1002/aenm.201602014", "DOI Link": "http://dx.doi.org/10.1002/aenm.201602014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399721700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HT; Lee, HW; Deng, Y; Lu, ZY; Hsu, PC; Liu, YY; Lin, DC; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haotian; Lee, Hyun-Wook; Deng, Yong; Lu, Zhiyi; Hsu, Po-Chun; Liu, Yayuan; Lin, Dingchang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bifunctional non-noble metal oxide nulloparticle electrocatalysts through lithium-induced conversion for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing earth-abundant, active and stable electrocatalysts which operate in the same electrolyte for water splitting, including oxygen evolution reaction and hydrogen evolution reaction, is important for many renewable energy conversion processes. Here we demonstrate the improvement of catalytic activity when transition metal oxide (iron, cobalt, nickel oxides and their mixed oxides) nulloparticles (similar to 20 nm) are electrochemically transformed into ultra-small diameter (2-5 nm) nulloparticles through lithium-induced conversion reactions. Different from most traditional chemical syntheses, this method maintains excellent electrical interconnection among nulloparticles and results in large surface areas and many catalytically active sites. We demonstrate that lithium-induced ultra-small NiFeOx nulloparticles are active bifunctional catalysts exhibiting high activity and stability for overall water splitting in base. We achieve 10mAcm(-2) water-splitting current at only 1.51V for over 200 h without degradation in a two-electrode configuration and 1M KOH, better than the combination of iridium and platinum as benchmark catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 802, "Times Cited, All Databases": 807, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7261, "DOI": "10.1038/ncomms8261", "DOI Link": "http://dx.doi.org/10.1038/ncomms8261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357170100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, C; Ganapathy, S; Van Eck, ERH; Wang, H; Basak, S; Li, ZL; Wagemaker, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Chuang; Ganapathy, Swapna; Van Eck, Ernst R. H.; Wang, Heng; Basak, Shibabrata; Li, Zhaolong; Wagemaker, Marnix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accessing the bottleneck in all-solid state batteries, lithium-ion transport over the solid-electrolyte-electrode interface", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state batteries potentially offer increased lithium-ion battery energy density and safety as required for large-scale production of electrical vehicles. One of the key challenges toward high-performance solid-state batteries is the large impedance posed by the electrode-electrolyte interface. However, direct assessment of the lithium-ion transport across realistic electrode-electrolyte interfaces is tedious. Here we report two-dimensional lithium-ion exchange NMR accessing the spontaneous lithium-ion transport, providing insight on the influence of electrode preparation and battery cycling on the lithium-ion transport over the interface between an argyrodite solid-electrolyte and a sulfide electrode. Interfacial conductivity is shown to depend strongly on the preparation method and demonstrated to drop dramatically after a few electrochemical (dis)charge cycles due to both losses in interfacial contact and increased diffusional barriers. The reported exchange NMR facilitates non-invasive and selective measurement of lithium-ion interfacial transport, providing insight that can guide the electrolyte-electrode interface design for future all-solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1086, "DOI": "10.1038/s41467-017-01187-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01187-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413353500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Liu, H; Tian, ZQ; Lu, D; Yu, Y; Cestellos-Blanco, S; Sakimoto, KK; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hao; Liu, Hao; Tian, Zhiquan; Lu, Dylan; Yu, Yi; Cestellos-Blanco, Stefano; Sakimoto, Kelsey K.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bacteria photosensitized by intracellular gold nulloclusters for solar fuel production", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The demand for renewable and sustainable fuel has prompted the rapid development of advanced nullotechnologies to effectively harness solar power. The construction of photosynthetic biohybrid systems (PBSs) aims to link preassembled biosynthetic pathways with inorganic light absorbers. This strategy inherits both the high light-harvesting efficiency of solid-state semiconductors and the superior catalytic performance of whole-cell microorganisms. Here, we introduce an intracellular, biocompatible light absorber, in the form of gold nulloclusters (AuNCs), to circumvent the sluggish kinetics of electron transfer for existing PBSs. Translocation of these AuNCs into non-photosynthetic bacteria enables photosynthesis of acetic acid from CO2. The AuNCs also serve as inhibitors of reactive oxygen species (ROS) to maintain high bacterium viability. With the dual advantages of light absorption and biocompatibility, this new generation of PBS can efficiently harvest sunlight and transfer photogenerated electrons to cellular metabolism, realizing CO2 fixation continuously over several days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 13, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 900, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-018-0267-z", "DOI Link": "http://dx.doi.org/10.1038/s41565-018-0267-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446501100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Louisia, S; Yu, S; Jin, JB; Roh, I; Chen, CB; Guzman, MVF; Feijóo, J; Chen, PC; Wang, HS; Pollock, CJ; Huang, X; Shao, YT; Wang, C; Muller, DA; Abruña, HD; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yao; Louisia, Sheena; Yu, Sunmoon; Jin, Jianbo; Roh, Inwhan; Chen, Chubai; Fonseca Guzman, Maria V.; Feijoo, Julian; Chen, Peng-Cheng; Wang, Hongsen; Pollock, Christopher J.; Huang, Xin; Shao, Yu-Tsun; Wang, Cheng; Muller, David A.; Abruna, Hector D.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando studies reveal active Cu nullograins for CO2 electroreduction", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide electroreduction facilitates the sustainable synthesis of fuels and chemicals(1). Although Cu enables CO2-to-multicarbon product (C2+) conversion, the nature of the active sites under operating conditions remains elusive(2). Importantly, identifying active sites of high-performance Cu nullocatalysts necessitates nulloscale, time-resolved operando techniques(3-5). Here, we present a comprehensive investigation of the structural dynamics during the life cycle of Cu nullocatalysts. A 7 nm Cu nulloparticle ensemble evolves into metallic Cu nullograins during electrolysis before complete oxidation to single-crystal Cu2O nullocubes following post-electrolysis air exposure. Operando analytical and four-dimensional electrochemical liquid-cell scanning transmission electron microscopy shows the presence of metallic Cu nullograins under CO2 reduction conditions. Correlated high-energy-resolution time-resolved X-ray spectroscopy suggests that metallic Cu, rich in nullograin boundaries, supports undercoordinated active sites for C-C coupling. Quantitative structure-activity correlation shows that a higher fraction of metallic Cu nullograins leads to higher C2+ selectivity. A 7 nm Cu nulloparticle ensemble, with a unity fraction of active Cu nullograins, exhibits sixfold higher C2+ selectivity than the 18 nm counterpart with one-third of active Cu nullograins. The correlation of multimodal operando techniques serves as a powerful platform to advance our fundamental understanding of the complex structural evolution of nullocatalysts under electrochemical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2023, "Volume": 614, "Issue": 7947, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 262, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05540-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05540-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938818200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, YY; Li, GR; Guo, Y; Li, ZP; Liang, CD; Peng, XS; Lin, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Yiyin; Li, Gaoran; Guo, Yi; Li, Zhoupeng; Liang, Chengdu; Peng, Xinsheng; Lin, Zhan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Foldable interpenetrated metal-organic frameworks/carbon nullotubes thin film for lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries are promising technologies for powering flexible devices due to their high energy density, low cost and environmental friendliness, when the insulating nature, shuttle effect and volume expansion of sulfur electrodes are well addressed. Here, we report a strategy of using foldable interpenetrated metal-organic frameworks/carbon nullotubes thin film for binder-free advanced lithium-sulfur batteries through a facile confinement conversion. The carbon nullotubes interpenetrate through the metal-organic frameworks crystal and interweave the electrode into a stratified structure to provide both conductivity and structural integrity, while the highly porous metal-organic frameworks endow the electrode with strong sulfur confinement to achieve good cyclability. These hierarchical porous interpenetrated three-dimensional conductive networks with well confined S-8 lead to high sulfur loading and utilization, as well as high volumetric energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14628, "DOI": "10.1038/ncomms14628", "DOI Link": "http://dx.doi.org/10.1038/ncomms14628", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395503300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, JH; Wang, PC; Wang, HH; Li, C; Si, XQ; Qi, JL; Cao, J; Zhong, ZX; Fei, WD; Feng, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Jinghuang; Wang, Pengcheng; Wang, Haohan; Li, Chun; Si, Xiaoqing; Qi, Junlei; Cao, Jian; Zhong, Zhengxiang; Fei, Weidong; Feng, Jicai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-Rich Heterogeneous MoS2/NiS2 nullosheets Electrocatalysts for Efficient Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing and constructing bifunctional electrocatalysts is vital for water splitting. Particularly, the rational interface engineering can effectively modify the active sites and promote the electronic transfer, leading to the improved splitting efficiency. Herein, free-standing and defect-rich heterogeneous MoS2/NiS2 nullosheets for overall water splitting are designed. The abundant heterogeneous interfaces in MoS2/NiS2 can not only provide rich electroactive sites but also facilitate the electron transfer, which further cooperate synergistically toward electrocatalytic reactions. Consequently, the optimal MoS2/NiS2 nullosheets show the enhanced electrocatalytic performances as bifunctional electrocatalysts for overall water splitting. This study may open up a new route for rationally constructing heterogeneous interfaces to maximize their electrochemical performances, which may help to accelerate the development of nonprecious electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 946, "Times Cited, All Databases": 984, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900246, "DOI": "10.1002/advs.201900246", "DOI Link": "http://dx.doi.org/10.1002/advs.201900246", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477711600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, ZW; Sun, XT; Zhu, SF; Dong, K; Liu, XQ; Wang, LL; Zhang, XS; Qu, LJ; Zhang, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Zhiwei; Sun, Xuantong; Zhu, Shifeng; Dong, Kai; Liu, Xuqing; Wang, Lili; Zhang, Xiansheng; Qu, Lijun; Zhang, Xueji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature Inspired MXene-Decorated 3D Honeycomb-Fabric Architectures Toward Efficient Water Desalination and Salt Harvesting", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar steam generation technology has emerged as a promising approach for seawater desalination, wastewater purification, etc. However, simultaneously achieving superior light absorption, thermal management, and salt harvesting in an evaporator remains challenging. Here, inspired by nature, a 3D honeycomb-like fabric decorated with hydrophilic Ti3C2Tx (MXene) is innovatively designed and successfully woven as solar evaporator. The honeycomb structure with periodically concave arrays creates the maximum level of light-trapping by multiple scattering and omnidirectional light absorption, synergistically cooperating with light absorbance of MXene. The minimum thermal loss is available by constructing the localized photothermal generation, contributed by a thermal-insulating barrier connected with 1D water path, and the concave structure of efficiently recycling convective and radiative heat loss. The evaporator demonstrates high solar efficiency of up to 93.5% and evaporation rate of 1.62 kg m(-2) h(-1) under one sun irradiation. Moreover, assisted by a 1D water path in the center, the salt solution transporting in the evaporator generates a radial concentration gradient from the center to the edge so that the salt is crystallized at the edge even in 21% brine, enabling the complete separation of water/solute and efficient salt harvesting. This research provides a large-scale manufacturing route of high-performance solar steam generator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10, "DOI": "10.1007/s40820-021-00748-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00748-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000726284100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CX; Xu, ZZ; Cheng, H; Lin, HH; Humphrey, MG; Zhang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chuanxi; Xu, Zhenzhu; Cheng, Hao; Lin, Huihui; Humphrey, Mark G.; Zhang, Chi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A hydrothermal route to water-stable luminescent carbon dots as nullosensors for pH and temperature", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots (CDs) as a class of heavy-metal-free fluorescent nullomaterials has drawn increasing attention in recent years due to their high optical absorptivity, chemical stability, biocompatibility, and low toxicity. Herein, we report a facile method to prepare stable CDs by hydrothermal treatment of glucose (glc) in the presence of glutathione (GSH). With this approach, the formation and the surface passivation of CDs are carried out simultaneously, resulting in intrinsic fluorescence emission. The influence of reaction temperature, reaction time and feed ratio of GSH/glc on the photoluminescence property of CDs is studied. The as-prepared CDs are characterized by UV-Vis, photoluminescence, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and transmission electron microscope, from which their structural information and property are interpreted. These CDs may be useful as pH sensors or as versatile nullothermometry devices based on the pronounced temperature dependence of their steady-state fluorescence emission spectra, which changes considerably over the physiological temperature range (15-60 degrees C). (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 82, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 87, "End Page": 95, "Article Number": null, "DOI": "10.1016/j.carbon.2014.10.035", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2014.10.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345683100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, EY; Yu, XQ; Lin, RQ; Bi, XX; Lu, J; Bak, SM; Nam, KW; Xin, HLL; Jaye, C; Fischer, DA; Amine, K; Yang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian; Bi, Xuanxuan; Lu, Jun; Bak, Seongmin; Nam, Kyung-Wan; Xin, Huolin L.; Jaye, Cherno; Fischer, Daniel A.; Amine, Kahlil; Yang, Xiao-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Voltage fade is a major problem in battery applications for high-energy lithium- and manganese-rich (LMR) layered materials. As a result of the complexity of the LMR structure, the voltage fade mechanism is not well understood. Here we conduct both in situ and ex situ studies on a typical LMR material (Li1.2Ni0.15Co0.1Mn0.55O2) during charge-discharge cycling, using multi-lengthscale X-ray spectroscopic and three-dimensional electron microscopic imaging techniques. Through probing from the surface to the bulk, and from individual to whole ensembles of particles, we show that the average valence state of each type of transition metal cation is continuously reduced, which is attributed to oxygen release from the LMR material. Such reductions activate the lower-voltage Mn3+/Mn4+ and Co2+ /Co3+ redox couples in addition to the original redox couples including Ni2+/Ni3+, Ni3+/Ni4+ and O2-/O-, directly leading to the voltage fade. We also show that the oxygen release causes microstructural defects such as the formation of large pores within particles, which also contributes to the voltage fade. Surface coating and modification methods are suggested to be effective in suppressing the voltage fade through reducing the oxygen release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 789, "Times Cited, All Databases": 836, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 698, "Article Number": null, "DOI": "10.1038/s41560-018-0207-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0207-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441098100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, D; Yang, YJ; Yang, J; Fang, MM; Tang, BZ; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dan; Yang, Yujie; Yang, Jie; Fang, Manman; Tang, Ben Zhong; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stimuli responsive luminescent materials are important in applied research but many of these materials are based on fluorescent stimuli responsive materials. Here, the authors report a stimulus-responsive room temperature phosphorescent materials composed of a phosphorescent chromophore of arylboronic acid and poly(vinylalcohol) with color tunable and water process able properties. Many luminescent stimuli responsive materials are based on fluorescence emission, while stimuli-responsive room temperature phosphorescent materials are less explored. Here, we show a kind of stimulus-responsive room temperature phosphorescence materials by the covalent linkage of phosphorescent chromophore of arylboronic acid and polymer matrix of poly(vinylalcohol). Attributed to the rigid environment offered from hydrogen bond and B-O covalent bond between arylboronic acid and poly(vinylalcohol), the yielded polymer film exhibits ultralong room temperature phosphorescence with lifetime of 2.43 s and phosphorescence quantum yield of 7.51%. Interestingly, the RTP property of this film is sensitive to the water and heat stimuli, because water could destroy the hydrogen bonds between adjacent poly(vinylalcohol) polymers, then changing the rigidity of this system. Furthermore, by introducing another two fluorescent dyes to this system, the color of afterglow with stimulus response effect could be adjusted from blue to green to orange through triplet-to-singlet Forster-resonullce energy-transfer. Finally, due to the water/heat-sensitive, multicolor and completely aqueous processable feature for these three afterglow hybrids, they are successfully applied in multifunctional ink for anti-counterfeit, screen printing and fingerprint record.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 347, "DOI": "10.1038/s41467-022-28011-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28011-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744540800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, P; Lv, F; Li, N; Zhang, YL; Mu, ZJ; Tang, YH; Lai, JP; Chao, YG; Luo, MC; Lin, F; Zhou, JH; Su, D; Guo, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Peng; Lv, Fan; Li, Na; Zhang, Yelong; Mu, Zijie; Tang, Yonghua; Lai, Jianping; Chao, Yuguang; Luo, Mingchuan; Lin, Fei; Zhou, Jinhui; Su, Dong; Guo, Shaojun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strengthening reactive metal-support interaction to stabilize high-density Pt single atoms on electron-deficient g-C3N4 for boosting photocatalytic H2 production", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tuning reactive metal-support interaction (RMSI) is a promising approach to optimizing catalytic active sites via the electronic, geometric and compositional effects. In general, the RMSI is conducted on the reducible oxides via a high-temperature reaction ( > 550 degrees C). Herein we report a strong RMSI between N single atom (NSA) and nonoxide-based g-C3N4 built by an in-situ photocatalytic reduction method at a sub-zero temperature. The experimental observation confirms that the rich N vacancies in g-C(3)N(4)4 produce an obvious electron-deficient effect, which greatly enhances the RMSI. This strong RMSI contributes to the highest NSA coverage density of 0.35 mg m(-2) reported to date in carbon-based materials and outstanding H-2-evolution activity of 174.5 mmol g(-1)h(-1) per NSA relative to those on the electron-rich g-C3N4. The structure simulation reveals that the RMSI can not only stabilize the NSA on the electron-deficient g-C3N4 via the strong chemical bond between NSA and the two-coordinated C (C-2C) sites caused by the N vacancies, but also promises the NSA with an optimized electronic and geometric structures for capturing photogenerated electrons and producing H-2. This finding opens a new channel for designing and manipulating single atom-loaded photocatalyst via the RMSI at a sub-zero low temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 56, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 127, "End Page": 137, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.11.033", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.11.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455264600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZM; Wang, YS; Xie, ZM; Wang, DL; Yuan, Y; Kang, HJ; Su, BL; Cheng, ZJ; Liu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zhimin; Wang, Youshan; Xie, Zhimin; Wang, Duola; Yuan, Yin; Kang, Hongjun; Su, Benlong; Cheng, Zhongjun; Liu, Yuyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modified MXene/Holey Graphene Films for Advanced Supercapacitor Electrodes with Superior Energy Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene films are attractive for advanced supercapacitor electrodes requiring high volumetric energy density due to their high redox capacitance combined with extremely high packing density. However, the self-restacking of MXene flakes unavoidably decreases the volumetric performance, mass loading, and rate capability. Herein, a simple strategy is developed to prepare a flexible and free-standing modified MXene/holey graphene film by filtration of the alkalized MXene and holey graphene oxide dispersions, followed by a mild annealing treatment. After terminal groups (-F/-OH) are removed, the increased proportion of Ti atoms enables more pseudocapacitive reaction. Meanwhile, the embedded holey graphene effectively prevents the self-restacking of MXene and forms a high nullopore connectivity network, which is able to immensely accelerate the ion transport and shorten transport pathways for both ion and electron. When applied as electrode materials for super-capacitors, it can deliver an ultrahigh volumetric capacitance (1445 F cm(-3)) at 2 mV s(-1), excellent rate capability, and high mass loading. In addition, the assembled symmetric supercapacitor demonstrates a fantastic volumetric energy density (38.6 Wh L-1), which is the highest value reported for MXene-based electrodes in aqueous electrolytes. This work opens a new avenue for the further exploration of MXene materials in energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800750, "DOI": "10.1002/advs.201800750", "DOI Link": "http://dx.doi.org/10.1002/advs.201800750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tekinalp, HL; Kunc, V; Velez-Garcia, GM; Duty, CE; Love, LJ; Naskar, AK; Blue, CA; Ozcan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tekinalp, Halil L.; Kunc, Vlastimil; Velez-Garcia, Gregorio M.; Duty, Chad E.; Love, Lonnie J.; Naskar, Amit K.; Blue, Craig A.; Ozcan, Soydan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly oriented carbon fiber-polymer composites via additive manufacturing", "Source Title": "COMPOSITES SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing is distinguished from traditional manufacturing techniques such as casting and machining by its ability to handle complex shapes with great design flexibility and without the typical waste. Although this technique has been mainly used for rapid prototyping, interest is growing in direct manufacture of actual parts. For wide spread application of 3D additive manufacturing, both techniques and feedstock materials require improvements to meet the mechanical requirements of load-bearing components. Here, we investigated short fiber (0.2-0.4 mm) reinforced acrylonitrile-butadiene-styrene composites as a feedstock for 3D-printing in terms of their processibility, microstructure and mechanical performance. The additive components are also compared with traditional compression molded composites. The tensile strength and modulus of 3D-printed samples increased similar to 115% and similar to 700%, respectively. 3D-printing yielded samples with very high fiber orientation in the printing direction (up to 91.5%), whereas, compression molding process yielded samples with significantly lower fiber orientation. Microstructure-mechanical property relationships revealed that although a relatively high porosity is observed in 3D-printed composites as compared to those produced by the conventional compression molding technique, they both exhibited comparable tensile strength and modulus. This phenomenon is explained based on the changes in fiber orientation, dispersion and void formation. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1076, "Times Cited, All Databases": 1216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2014, "Volume": 105, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 144, "End Page": 150, "Article Number": null, "DOI": "10.1016/j.compscitech.2014.10.009", "DOI Link": "http://dx.doi.org/10.1016/j.compscitech.2014.10.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346943400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoke, ET; Slotcavage, DJ; Dohner, ER; Bowring, AR; Karunadasa, HI; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hoke, Eric T.; Slotcavage, Daniel J.; Dohner, Emma R.; Bowring, Andrea R.; Karunadasa, Hemamala I.; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on reversible, light-induced transformations in (CH3NH3) Pb(BrxI1-x) 3. Photoluminescence (PL) spectra of these perovskites develop a new, red-shifted peak at 1.68 eV that grows in intensity under constant, 1-sun illumination in less than a minute. This is accompanied by an increase in sub-bandgap absorption at similar to 1.7 eV, indicating the formation of luminescent trap states. Light soaking causes a splitting of X-ray diffraction (XRD) peaks, suggesting segregation into two crystalline phases. Surprisingly, these photo-induced changes are fully reversible; the XRD patterns and the PL and absorption spectra revert to their initial states after the materials are left for a few minutes in the dark. We speculate that photoexcitation may cause halide segregation into iodide-rich minority and bromide-enriched majority domains, the former acting as a recombination center trap. This instability may limit achievable voltages from some mixed-halide perovskite solar cells and could have implications for the photostability of halide perovskites used in optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1783, "Times Cited, All Databases": 1947, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 613, "End Page": 617, "Article Number": null, "DOI": "10.1039/c4sc03141e", "DOI Link": "http://dx.doi.org/10.1039/c4sc03141e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345901600072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Venkateshvaran, D; Nikolka, M; Sadhanala, A; Lemaur, V; Zelazny, M; Kepa, M; Hurhangee, M; Kronemeijer, AJ; Pecunia, V; Nasrallah, I; Romanov, I; Broch, K; McCulloch, I; Emin, D; Olivier, Y; Cornil, J; Beljonne, D; Sirringhaus, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Venkateshvaran, Deepak; Nikolka, Mark; Sadhanala, Aditya; Lemaur, Vincent; Zelazny, Mateusz; Kepa, Michal; Hurhangee, Michael; Kronemeijer, Auke Jisk; Pecunia, Vincenzo; Nasrallah, Iyad; Romanov, Igor; Broch, Katharina; McCulloch, Iain; Emin, David; Olivier, Yoann; Cornil, Jerome; Beljonne, David; Sirringhaus, Henning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching disorder-free transport in high-mobility conjugated polymers", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymers enable the production of flexible semiconductor devices that can be processed from solution at low temperatures. Over the past 25 years, device performance has improved greatly as a wide variety of molecular structures have been studied(1). However, one major limitation has not been overcome; transport properties in polymer films are still limited by pervasive conformational and energetic disorder(2-5). This not only limits the rational design of materials with higher performance, but also prevents the study of physical phenomena associated with an extended pi-electron delocalization along the polymer backbone. Here we report a comparative transport study of several high-mobility conjugated polymers by field-effect-modulated Seebeck, transistor and sub-bandgap optical absorption measurements. We show that in several of these polymers, most notably in a recently reported, indacenodithiophene-based donor-acceptor copolymer with a near-amorphous microstructure(6), the charge transport properties approach intrinsic disorder-free limits at which all molecular sites are thermally accessible. Molecular dynamics simulations identify the origin of this long sought-after regime as a planar, torsion-free backbone conformation that is surprisingly resilient to side-chain disorder. Our results provide molecular-design guidelines for 'disorder-free' conjugated polymers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 887, "Times Cited, All Databases": 970, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2014, "Volume": 515, "Issue": 7527, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 384, "End Page": 388, "Article Number": null, "DOI": "10.1038/nature13854", "DOI Link": "http://dx.doi.org/10.1038/nature13854", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345770600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, QF; Ding, P; Xu, MQ; Zhu, XR; Wang, MY; Deng, J; Ma, Q; Han, N; Zhu, Y; Lu, J; Feng, ZX; Li, YF; Zhou, W; Li, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Qiufang; Ding, Pan; Xu, Mingquan; Zhu, Xiaorong; Wang, Maoyu; Deng, Jun; Ma, Qing; Han, Na; Zhu, Yong; Lu, Jun; Feng, Zhenxing; Li, Yafei; Zhou, Wu; Li, Yanguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural defects on converted bismuth oxide nullotubes enable highly active electrocatalysis of carbon dioxide reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formic acid (or formate) is suggested to be one of the most economically viable products from electrochemical carbon dioxide reduction. However, its commercial viability hinges on the development of highly active and selective electrocatalysts. Here we report that structural defects have a profound positive impact on the electrocatalytic performance of bismuth. Bismuth oxide double-walled nullotubes with fragmented surface are prepared as a template, and are cathodically converted to defective bismuth nullotubes. This converted electrocatalyst enables carbon dioxide reduction to formate with excellent activity, selectivity and stability. Most significantly, its current density reaches similar to 288 mA cm(-2) at -0.61 V versus reversible hydrogen electrode within a flow cell reactor under ambient conditions. Using density functional theory calculations, the excellent activity and selectivity are rationalized as the outcome of abundant defective bismuth sites that stabilize the *OCHO intermediate. Furthermore, this electrocatalyst is coupled with silicon photocathodes and achieves high-performance photoelectrochemical carbon dioxide reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 559, "Times Cited, All Databases": 579, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2807, "DOI": "10.1038/s41467-019-10819-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10819-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472840400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bella, F; Griffini, G; Correa-Baena, JP; Saracco, G; Grätzel, M; Hagfeldt, A; Turri, S; Gerbaldi, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bella, Federico; Griffini, Gianmarco; Correa-Baena, Juan-Pablo; Saracco, Guido; Gratzel, Michael; Hagfeldt, Anders; Turri, Stefano; Gerbaldi, Claudio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometal halide perovskite solar cells have demonstrated high conversion efficiency but poor long-term stability against ultraviolet irradiation and water. We show that rapid light-induced free-radical polymerization at ambient temperature produces multifunctional fluorinated photopolymer coatings that confer luminescent and easy-cleaning features on the front side of the devices, while concurrently forming a strongly hydrophobic barrier toward environmental moisture on the back contact side. The luminescent photopolymers re-emit ultraviolet light in the visible range, boosting perovskite solar cells efficiency to nearly 19% under standard illumination. Coated devices reproducibly retain their full functional performance during prolonged operation, even after a series of severe aging tests carried out for more than 6 months.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 755, "Times Cited, All Databases": 806, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2016, "Volume": 354, "Issue": 6309, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 203, "End Page": 206, "Article Number": null, "DOI": "10.1126/science.aah4046", "DOI Link": "http://dx.doi.org/10.1126/science.aah4046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387816500038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rhodes, D; Chae, SH; Ribeiro-Palau, R; Hone, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rhodes, Daniel; Chae, Sang Hoon; Ribeiro-Palau, Rebeca; Hone, James", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Disorder in van der Waals heterostructures of 2D materials", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing the full potential of any materials system requires understanding and controlling disorder, which can obscure intrinsic properties and hinder device performance. Here we examine both intrinsic and extrinsic disorder in two-dimensional (2D) materials, in particular graphene and transition metal dichalcogenides (TMDs). Minimizing disorder is crucial for realizing desired properties in 2D materials and improving device performance and repeatability for practical applications. We discuss the progress in disorder control for graphene and TMDs, as well as in van der Waals heterostructures realized by combining these materials with hexagonal boron nitride. Furthermore, we showcase how atomic defects or disorder can also be harnessed to provide useful electronic, optical, chemical and magnetic functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 18, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 541, "End Page": 549, "Article Number": null, "DOI": "10.1038/s41563-019-0366-8", "DOI Link": "http://dx.doi.org/10.1038/s41563-019-0366-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468511800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, T; Mao, XN; Zhang, Y; Wu, XP; Wang, L; Chu, MY; Pao, CW; Yang, SZ; Xu, Y; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Tang; Mao, Xinnull; Zhang, Ying; Wu, Xiaoping; Wang, Lu; Chu, Mingyu; Pao, Chih-Wen; Yang, Shize; Xu, Yong; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination tailoring of Cu single sites on C3N4 realizes selective CO2 hydrogenation at low temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 hydrogenation has attracted intense scientific attention yet suffers from the disadvantage of poor activity and low selectivity. Here, the authors report that Cu single atom catalysts with tailored coordination environments on C3N4 serve as highly selective catalysts for CO2 hydrogenation. CO2 hydrogenation has attracted great attention, yet the quest for highly-efficient catalysts is driven by the current disadvantages of poor activity, low selectivity, and ambiguous structure-performance relationship. We demonstrate here that C3N4-supported Cu single atom catalysts with tailored coordination structures, namely, Cu-N-4 and Cu-N-3, can serve as highly selective and active catalysts for CO2 hydrogenation at low temperature. The modulation of the coordination structure of Cu single atom is readily realized by simply altering the treatment parameters. Further investigations reveal that Cu-N-4 favors CO2 hydrogenation to form CH3OH via the formate pathway, while Cu-N-3 tends to catalyze CO2 hydrogenation to produce CO via the reverse water-gas-shift (RWGS) pathway. Significantly, the CH3OH productivity and selectivity reach 4.2 mmol g(-1) h(-1) and 95.5%, respectively, for Cu-N-4 single atom catalyst. We anticipate this work will promote the fundamental researches on the structure-performance relationship of catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6022, "DOI": "10.1038/s41467-021-26316-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26316-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000707661200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Witting, IT; Chasapis, TC; Ricci, F; Peters, M; Heinz, NA; Hautier, G; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Witting, Ian T.; Chasapis, Thomas C.; Ricci, Francesco; Peters, Matthew; Heinz, Nicholas A.; Hautier, Geoffroy; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Thermoelectric Properties of Bismuth Telluride", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bismuth telluride is the working material for most Peltier cooling devices and thermoelectric generators. This is because Bi2Te3 (or more precisely its alloys with Sb2Te3 for p-type and Bi2Se3 for n-type material) has the highest thermoelectric figure of merit, zT, of any material around room temperature. Since thermoelectric technology will be greatly enhanced by improving Bi2Te3 or finding a superior material, this review aims to identify and quantify the key material properties that make Bi2Te3 such a good thermoelectric. The large zT can be traced to the high band degeneracy, low effective mass, high carrier mobility, and relatively low lattice thermal conductivity, which all contribute to its remarkably high thermoelectric quality factor. Using literature data augmented with newer results, these material parameters are quantified, giving clear insight into the tailoring of the electronic band structure of Bi2Te3 by alloying, or reducing thermal conductivity by nullostructuring. For example, this analysis clearly shows that the minority carrier excitation across the small bandgap significantly limits the thermoelectric performance of Bi2Te3, even at room temperature, showing that larger bandgap alloys are needed for higher temperature operation. Such effective material parameters can also be used for benchmarking future improvements in Bi2Te3 or new replacement materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 563, "Times Cited, All Databases": 592, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800904, "DOI": "10.1002/aelm.201800904", "DOI Link": "http://dx.doi.org/10.1002/aelm.201800904", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471049100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, J; Meng, WN; Khayat, KH; Bao, Y; Guo, PW; Lyu, ZH; Abu-obeidah, A; Nassif, H; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Jiang; Meng, Weina; Khayat, Kamal H.; Bao, Yi; Guo, Pengwei; Lyu, Zhenghua; Abu-obeidah, Adi; Nassif, Hani; Wang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New development of ultra-high-performance concrete (UHPC)", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-high-performance concrete (UHPC) is a type of cement-based composite for new construction and/or restoration of existing structures to extend service life. UHPC features superior workability, mechanical properties, and durability compared with conventional concrete. However, some challenges limit the wider application of UHPC, such as low workability for large-volume production, high autogenous shrinkage, insufficient flexural/tensile properties, and unpredictable durability after concrete cracking. Therefore, this paper reviews the state-of-the-art technologies for developing UHPC mixtures with improved properties. This review covers the following aspects: (1) the existing design methodologies; (2) the typical ingredients (e.g., binders, aggregates, chemical admixtures, and fibers) for preparation of UHPC and the underlying working principals; (3) the technologies for improving and controlling key properties (e.g., workability, autogenous shrinkage, compressive performance, tensile/flexural properties, and durability); and (4) the representative successful applications. This review is expected to advance the fundamental knowledge of UHPC and promote further research and applications of UHPC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2021, "Volume": 224, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 109220, "DOI": "10.1016/j.compositesb.2021.109220", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2021.109220", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000702841900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Freakley, SJ; He, Q; Harrhy, JH; Lu, L; Crole, DA; Morgan, DJ; Ntainjua, EN; Edwards, JK; Carley, AF; Borisevich, AY; Kiely, CJ; Hutchings, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Freakley, Simon J.; He, Qian; Harrhy, Jonathan H.; Lu, Li; Crole, David A.; Morgan, David J.; Ntainjua, Edwin N.; Edwards, Jennifer K.; Carley, Albert F.; Borisevich, Albina Y.; Kiely, Christopher J.; Hutchings, Graham J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The direct synthesis of hydrogen peroxide (H2O2) from H-2 and O-2 represents a potentially atom-efficient alternative to the current industrial indirect process. We show that the addition of tin to palladium catalysts coupled with an appropriate heat treatment cycle switches off the sequential hydrogenation and decomposition reactions, enabling selectivities of >95% toward H2O2. This effect arises from a tin oxide surface layer that encapsulates small Pd-rich particles while leaving larger Pd-Sn alloy particles exposed. We show that this effect is a general feature for oxide-supported Pd catalysts containing an appropriate second metal oxide component, and we set out the design principles for producing high-selectivity Pd-based catalysts for direct H2O2 production that do not contain gold.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 508, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2016, "Volume": 351, "Issue": 6276, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 965, "End Page": 968, "Article Number": null, "DOI": "10.1126/science.aad5705", "DOI Link": "http://dx.doi.org/10.1126/science.aad5705", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370821400039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zavabeti, A; Ou, JZ; Carey, BJ; Syed, N; Orrell-Trigg, R; Mayes, ELH; Xu, CL; Kavehei, O; O'Mullane, AP; Kaner, RB; Kalantar-Zadeh, K; Daeneke, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zavabeti, Ali; Ou, Jian Zhen; Carey, Benjamin J.; Syed, Nitu; Orrell-Trigg, Rebecca; Mayes, Edwin L. H.; Xu, Chenglong; Kavehei, Omid; O'Mullane, Anthony P.; Kaner, Richard B.; Kalantar-zadeh, Kourosh; Daeneke, Torben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) oxides have a wide variety of applications in electronics and other technologies. However, many oxides are not easy to synthesize as 2D materials through conventional methods. We used nontoxic eutectic gallium-based alloys as a reaction solvent and co-alloyed desired metals into the melt. On the basis of thermodynamic considerations, we predicted the composition of the self-limiting interfacial oxide. We isolated the surface oxide as a 2D layer, either on substrates or in suspension. This enabled us to produce extremely thin subnullometer layers of HfO2, Al2O3, and Gd2O3. The liquid metal-based reaction route can be used to create 2D materials that were previously inaccessible with preexisting methods. The work introduces room-temperature liquid metals as a reaction environment for the synthesis of oxide nullomaterials with low dimensionality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 676, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2017, "Volume": 358, "Issue": 6361, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 332, "End Page": 335, "Article Number": null, "DOI": "10.1126/science.aao4249", "DOI Link": "http://dx.doi.org/10.1126/science.aao4249", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413251000034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SB; Ran, Q; Yao, RQ; Shi, H; Wen, Z; Zhao, M; Lang, XY; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sheng-Bo; Ran, Qing; Yao, Rui-Qi; Shi, Hang; Wen, Zi; Zhao, Ming; Lang, Xing-You; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lamella-nullostructured eutectic zinc-aluminum alloys as reversible and dendrite-free anodes for aqueous rechargeable batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic zinc is an attractive anode material for aqueous rechargeable batteries because of its high theoretical capacity and low cost. However, state-of-the-art zinc anodes suffer from low coulombic efficiency and severe dendrite growth during stripping/plating processes, hampering their practical applications. Here we show that eutectic-composition alloying of zinc and aluminum as an effective strategy substantially tackles these irreversibility issues by making use of their lamellar structure, composed of alternating zinc and aluminum nullolamellas. The lamellar nullostructure not only promotes zinc stripping from precursor eutectic Zn88Al12 (at%) alloys, but produces core/shell aluminum/aluminum sesquioxide interlamellar nullopatterns in situ to in turn guide subsequent growth of zinc, enabling dendrite-free zinc stripping/plating for more than 2000h in oxygen-absent aqueous electrolyte. These outstanding electrochemical properties enlist zinc-ion batteries constructed with Zn88Al12 alloy anode and KxMnO2 cathode to deliver high-density energy at high levels of electrical power and retain 100% capacity after 200hours. Aqueous rechargeable Zn-ion batteries are attractive energy storage devices, but their wide adoption is impeded by the irreversible metallic Zn anode. Here the authors report lamellar-nullostructured eutectic Zn/Al alloys as reversible and dendrite-free anodes for improved battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 596, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1634, "DOI": "10.1038/s41467-020-15478-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15478-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000525081200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YJ; Yi, XX; Wang, SL; Li, T; Tan, BE; Chen, CC; Majima, T; Waclawik, ER; Zhu, HY; Wang, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yajuan; Yi, Xiaoxuan; Wang, Shaolei; Li, Tao; Tan, Bien; Chen, Chuncheng; Majima, Tetsuro; Waclawik, Eric R.; Zhu, Huaiyong; Wang, Jingyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective photocatalytic CO2 reduction in aerobic environment by microporous Pd-porphyrin-based polymers coated hollow TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct photocatalytic CO2 reduction from primary sources, such as flue gas and air, into fuels, is highly desired, but the thermodynamically favored O-2 reduction almost completely impedes this process. Herein, we report on the efficacy of a composite photocatalyst prepared by hyper-crosslinking porphyrin-based polymers on hollow TiO2 surface and subsequent coordinating with Pd(II). Such composite exhibits high resistance against O-2 inhibition, leading to 12% conversion yield of CO2 from air after 2-h UV-visible light irradiation. In contrast, the CO2 reduction over Pd/TiO2 without the polymer is severely inhibited by the presence of O-2 ( >= 0.2 %). This study presents a feasible strategy, building Pd(II) sites into CO2-adsorptive polymers on hollow TiO2 surface, for realizing CO2 reduction with H2O in an aerobic environment by the high CO2/O-2 adsorption selectivity of polymers and efficient charge separation for CO2 reduction and H2O oxidation on Pd(II) sites and hollow TiO2, respectively. While selective CO2 reduction is crucial for its removal from the environment, the presence of O-2 hinders this process. Here authors show CO2 photoreduction in the presence of O-2 by incorporating Pd(II) sites into a coordination polymer on TiO2 to selectively adsorb CO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1400, "DOI": "10.1038/s41467-022-29102-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29102-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770426200037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, CE; Zhao, MQ; Makaryan, T; Halim, J; Boota, M; Kota, S; Anasori, B; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Chang E.; Zhao, Meng-Qiang; Makaryan, Taron; Halim, Joseph; Boota, Muhammad; Kota, Sankalp; Anasori, Babak; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage", "Source Title": "CHEMELECTROCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein we develop a chemical etching method to produce porous two-dimensional (2D) Ti3C2Tx MXenes at room temperature in aqueous solutions. The as-produced porous Ti3C2Tx (p-Ti3C2Tx) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nullotubes (CNTs). The as-fabricated p-Ti3C2Tx/CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti3C2Tx based films, with a very high capacity of approximate to 1250 mAhg(-1) at 0.1 C, excellent cycling stability, and good rate performance (330 mAhg(-1) at 10 C). Using the same chemical etching method, we also made porous Nb2CTx and V2CTx MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 689, "End Page": 693, "Article Number": null, "DOI": "10.1002/celc.201600059", "DOI Link": "http://dx.doi.org/10.1002/celc.201600059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379985500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, Y; Zhao, Y; Zhou, M; Tan, SJ; Peymanfar, R; Aslibeiki, B; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yue; Zhao, Yue; Zhou, Ming; Tan, Shujuan; Peymanfar, Reza; Aslibeiki, Bagher; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrabroad Microwave Absorption Ability and Infrared Stealth Property of nullo-Micro CuS@rGO Lightweight Aerogels", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing ultrabroad radar-infrared compatible stealth materials has turned into a research hotspot, which is still a problem to be solved. Herein, the copper sulfide wrapped by reduced graphene oxide to obtain three-dimensional (3D) porous network composite aerogels (CuS@rGO) were synthesized via thermal reduction ways (hydrothermal, ascorbic acid reduction) and freeze-drying strategy. It was discovered that the phase components (rGO and CuS phases) and micro/nullo structure (microporous and nullosheet) were well-modified by modulating the additive amounts of CuS and changing the reduction ways, which resulted in the variation of the pore structure, defects, complex permittivity, microwave absorption, radar cross section (RCS) reduction value and infrared (IR) emissivity. Notably, the obtained CuS@rGO aerogels with a single dielectric loss type can achieve an ultrabroad bandwidth of 8.44 GHz at 2.8 mm with the low filler content of 6 wt% by a hydrothermal method. Besides, the composite aerogel via the ascorbic acid reduction realizes the minimum reflection loss (RLmin) of - 60.3 dB with the lower filler content of 2 wt%. The RCS reduction value can reach 53.3 dB m(2), which effectively reduces the probability of the target being detected by the radar detector. Furthermore, the laminated porous architecture and multicomponent endowed composite aerogels with thermal insulation and IR stealth versatility. Thus, this work offers a facile method to design and develop porous rGO-based composite aerogel absorbers with radar-IR compatible stealth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 171, "DOI": "10.1007/s40820-022-00906-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00906-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842159200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Wu, BH; Sun, ST; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Wu, Baohu; Sun, Shengtong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable ionic skins are intriguing in mimicking the versatile sensations of natural skins. However, for their applications in advanced electronics, good elastic recovery, self-healing, and more importantly, skin-like nonlinear mechanoresponse (strain-stiffening) are essential but can be rarely met in one material. Here we demonstrate a robust proton-conductive ionic skin design via introducing an entropy-driven supramolecular zwitterionic reorganizable network to the hydrogen-bonded polycarboxylic acid network. The design allows two dynamic networks with distinct interacting strength to sequentially debond with stretch, and the conflict among elasticity, self-healing, and strain-stiffening can be thus defeated. The representative polyacrylic acid/betaine elastomer exhibits high stretchability (1600% elongation), immense strain-stiffening (24-fold modulus enhancement), similar to 100% self-healing, excellent elasticity (97.9 +/- 1.1% recovery ratio, <14% hysteresis), high transparency (99.7 +/- 0.1%), moisture-preserving, anti-freezing (elastic at -40 degrees C), water reprocessibility, as well as easy-to-peel adhesion. The combined advantages make the present ionic elastomer very promising in wearable iontronic sensors for human-machine interfacing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4082, "DOI": "10.1038/s41467-021-24382-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24382-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672163900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, Y; Zhang, CL; Zhou, M; Fu, Q; Zhao, CX; Wu, MH; Lei, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yang; Zhang, Chenglin; Zhou, Min; Fu, Qun; Zhao, Chengxi; Wu, Minghong; Lei, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly nitrogen doped carbon nullofibers with superior rate capability and cyclability for potassium ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries are a promising alternative to lithium-ion batteries. However, it is challenging to achieve fast charging/discharging and long cycle life with the current electrode materials because of the sluggish potassiation kinetics. Here we report a soft carbon anode, namely highly nitrogen-doped carbon nullofibers, with superior rate capability and cyclability. The anode delivers reversible capacities of 248 mAh g(-1) at 25 mA g(-1) and 101 mAh g(-1) at 20 A g(-1), and retains 146 mAh g(-1) at 2 A g(-1) after 4000 cycles. Surface-dominated K-storage is verified by quantitative kinetics analysis and theoretical investigation. A full cell coupling the anode and Prussian blue cathode delivers a reversible capacity of 195 mAh g(-1) at 0.2 A g(-1). Considering the cost-effectiveness and material sustainability, our work may shed some light on searching for K-storage materials with high performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1010, "Times Cited, All Databases": 1045, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1720, "DOI": "10.1038/s41467-018-04190-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04190-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431113000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, YH; Sakai, N; Da, P; Wu, JY; Sansom, HC; Ramadan, AJ; Mahesh, S; Liu, JL; Oliver, RDJ; Lim, J; Aspitarte, L; Sharma, K; Madhu, PK; Morales-Vilches, AB; Nayak, PK; Bai, S; Gao, F; Grovenor, CRM; Johnston, MB; Labram, JG; Durrant, JR; Ball, JM; Wenger, B; Stannowski, B; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yen-Hung; Sakai, Nobuya; Da, Peimei; Wu, Jiaying; Sansom, Harry C.; Ramadan, Alexandra J.; Mahesh, Suhas; Liu, Junliang; Oliver, Robert D. J.; Lim, Jongchul; Aspitarte, Lee; Sharma, Kshama; Madhu, P. K.; Morales-Vilches, Anna B.; Nayak, Pabitra K.; Bai, Sai; Gao, Feng; Grovenor, Chris R. M.; Johnston, Michael B.; Labram, John G.; Durrant, James R.; Ball, James M.; Wenger, Bernard; Stannowski, Bernd; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A piperidinium salt stabilizes efficient metal-halide perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60 degrees and 85 degrees C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 540, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2020, "Volume": 369, "Issue": 6499, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 96, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba1628", "DOI Link": "http://dx.doi.org/10.1126/science.aba1628", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548751700053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pang, Q; Shyamsunder, A; Narayanull, B; Kwok, CY; Curtiss, LA; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pang, Quan; Shyamsunder, Abhinulldan; Narayanull, Badri; Kwok, Chun Yuen; Curtiss, Larry A.; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li-S batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lithium-sulfur battery is promising as an alternative to conventional lithium-ion technology due to the high energy density of both sulfur and lithium metal electrodes. An extended lifetime has been demonstrated, but two notable challenges still exist to realize its full potential: to overcome the undesired high electrolyte/sulfur ratio required for the catholyte-type mechanism that governs most cell configurations, and to inhibit Li dendrite growth and its parasitic reaction with the electrolyte that results in cell degradation. Here, we demonstrate that by tuning the electrolyte structure, the challenges at both electrodes can be tackled simultaneously. Specifically, the sulfur speciation pathway transforms from a dissolution-precipitation route to a quasi-solid state conversion in the presence of a lowered solvent activity and an extended electrolyte network, curtailing the need for high electrolyte volumes. Ab initio calculations reveal the nature of the network structure. With such an optimized structure, the electrolyte allows dendrite-free Li plating and shows a 20-fold reduction in parasitic reactions with Li, which avoids electrolyte consumption and greatly extends the life time of a low electrolyte/sulfur (5 mu l mg(-1)) sulfur cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 783, "End Page": 791, "Article Number": null, "DOI": "10.1038/s41560-018-0214-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0214-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444121800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Datta, SJ; Mayoral, A; Bettahalli, NMS; Bhatt, PM; Karunakaran, M; Carja, ID; Fan, D; Mileo, PGM; Semino, R; Maurin, G; Terasaki, O; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Datta, Shuvo Jit; Mayoral, Alvaro; Bettahalli, Narasimha Murthy Srivatsa; Bhatt, Prashant M.; Karunakaran, Madhavan; Carja, Ionela Daniela; Fan, Dong; Mileo, Paulo Graziane M.; Semino, Rocio; Maurin, Guillaume; Terasaki, Osamu; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of mixed-matrix metal-organic framework membranes for molecular separations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional separation technologies to separate valuable commodities are energy intensive, consuming 15% of the worldwide energy. Mixed-matrix membranes, combining processable polymers and selective adsorbents, offer the potential to deploy adsorbent distinct separation properties into processable matrix. We report the rational design and construction of a highly efficient, mixed-matrix metal-organic framework membrane based on three interlocked criteria: (i) a fluorinated metal-organic framework, AlFFIVE-1-Ni, as a molecular sieve adsorbent that selectively enhances hydrogen sulfide and carbon dioxide diffusion while excluding methane; (ii) tailoring crystal morphology into nullosheets with maximally exposed (001) facets; and (iii) in-plane alignment of (001) nullosheets in polymer matrix and attainment of [001]-orientedmembrane. The membrane demonstrated exceptionally high hydrogen sulfide and carbon dioxide separation from natural gas under practical working conditions. This approach offers great potential to translate other key adsorbents into processable matrix.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2022, "Volume": 376, "Issue": 6597, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1080, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abe0192", "DOI Link": "http://dx.doi.org/10.1126/science.abe0192", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806053500041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hung, SF; Xu, AN; Wang, X; Li, FW; Hsu, SH; Li, YH; Wicks, J; Cervantes, EG; Rasouli, AS; Li, YGC; Luo, MC; Nam, DH; Wang, N; Peng, T; Yan, Y; Lee, G; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hung, Sung-Fu; Xu, Aoni; Wang, Xue; Li, Fengwang; Hsu, Shao-Hui; Li, Yuhang; Wicks, Joshua; Cervantes, Eduardo Gonzalez; Rasouli, Armin Sedighian; Li, Yuguang C.; Luo, Mingchuan; Nam, Dae-Hyun; Wang, Ning; Peng, Tao; Yan, Yu; Lee, Geonhui; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped graphene-supported single atoms convert CO2 to CO, but fail to provide further hydrogenation to methane - a finding attributable to the weak adsorption of CO intermediates. To regulate the adsorption energy, here we investigate the metal-supported single atoms to enable CO2 hydrogenation. We find a copper-supported iron-single-atom catalyst producing a high-rate methane. Density functional theory calculations and in-situ Raman spectroscopy show that the iron atoms attract surrounding intermediates and carry out hydrogenation to generate methane. The catalyst is realized by assembling iron phthalocyanine on the copper surface, followed by in-situ formation of single iron atoms during electrocatalysis, identified using operando X-ray absorption spectroscopy. The copper-supported iron-single-atom catalyst exhibits a CO2-to-methane Faradaic efficiency of 64% and a partial current density of 128 mA cm(-2), while the nitrogen-doped graphene-supported one produces only CO. The activity is 32 times higher than a pristine copper under the same conditions of electrolyte and bias. Converting CO2 and H2O into value-added chemical feedstocks and fuels offers a carbon neutral approach to tackling global energy and climate concerns. Here the authors report a metal supported single-atom catalytic site enabling the electrocatalytic reduction of CO2 to methane.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 819, "DOI": "10.1038/s41467-022-28456-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28456-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754037600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parker, RM; Guidetti, G; Williams, CA; Zhao, TH; Narkevicius, A; Vignolini, S; Frka-Petesic, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parker, Richard M.; Guidetti, Giulia; Williams, Cyan A.; Zhao, Tianheng; Narkevicius, Aurimas; Vignolini, Silvia; Frka-Petesic, Bruno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Self-Assembly of Cellulose nullocrystals: Hierarchical Design of Visual Appearance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By controlling the interaction of biological building blocks at the nulloscale, natural photonic nullostructures have been optimized to produce intense coloration. Inspired by such biological nullostructures, the possibility to design the visual appearance of a material by guiding the hierarchical self-assembly of its constituent components, ideally using natural materials, is an attractive route for rationally designed, sustainable manufacturing. Within the large variety of biological building blocks, cellulose nullocrystals are one of the most promising biosourced materials, primarily for their abundance, biocompatibility, and ability to readily organize into photonic structures. Here, the mechanisms underlying the formation of iridescent, vividly colored materials from colloidal liquid crystal suspensions of cellulose nullocrystals are reviewed and recent advances in structural control over the hierarchical assembly process are reported as a toolbox for the design of sophisticated optical materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 438, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2018, "Volume": 30, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1704477, "DOI": "10.1002/adma.201704477", "DOI Link": "http://dx.doi.org/10.1002/adma.201704477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431616700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, SM; Pu, HH; Wells, SA; Wen, ZH; Mao, S; Chang, JB; Hersam, MC; Chen, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Shumao; Pu, Haihui; Wells, Spencer A.; Wen, Zhenhai; Mao, Shun; Chang, Jingbo; Hersam, Mark C.; Chen, Junhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh sensitivity and layer-dependent sensing performance of phosphorene-based gas sensors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) layered materials have attracted significant attention for device applications because of their unique structures and outstanding properties. Here, a field-effect transistor (FET) sensor device is fabricated based on 2D phosphorene nullosheets (PNSs). The PNS sensor exhibits an ultrahigh sensitivity to NO2 in dry air and the sensitivity is dependent on its thickness. A maximum response is observed for 4.8-nm-thick PNS, with a sensitivity up to 190% at 20 parts per billion (p.p.b.) at room temperature. First-principles calculations combined with the statistical thermodynamics modelling predict that the adsorption density is similar to 10(15) cm(-2) for the 4.8-nm-thick PNS when exposed to 20 p.p.b. NO2 at 300 K. Our sensitivity modelling further suggests that the dependence of sensitivity on the PNS thickness is dictated by the band gap for thinner sheets (<10 nm) and by the effective thickness on gas adsorption for thicker sheets (>10 nm).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 646, "Times Cited, All Databases": 678, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8632, "DOI": "10.1038/ncomms9632", "DOI Link": "http://dx.doi.org/10.1038/ncomms9632", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364934700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, F; Shen, HD; Sun, X; Xue, WW; Shoneye, A; Ma, JN; Luo, L; Wang, DJ; Wang, JG; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Feng; Shen, Huidong; Sun, Xiang; Xue, Wenwen; Shoneye, Ayoola; Ma, Jiani; Luo, Lei; Wang, Danjun; Wang, Jianguo; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic effect of surface oxygen vacancies and interfacial charge transfer on Fe(III)/Bi2MoO6 for efficient photocatalysis", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel Fe(III) clusters grafted Bi2MoO6 nullosheets with surface oxygen vacancies (denoted as F/BMO-SOVs) heterostructured composite have been firstly fabricated via a reliable calcination process combined with impregnation approach. The surface oxygen vacancies (SOVs) in Bi2MoO6 were formed due to controlled calcination process. The presence of Fe (III) clusters was confirmed by HRTEM, XPS, and UV-vis DRS. Under visible light irradiation, the optimum molar ratio of 15% F/BMO-SOVs achieved 93.4% degradation efficiency of phenol within 180 min, representing nearly 80 times higher activity than the pure Bi2MoO6, confirmed by both absorption spectrum and TOC measurement. The dramatically enhanced photocatalytic activity is attributed to the synergistic effect between the SOVs, Fe(III) clusters and Bi2MoO6, which not only narrows the band gap, improving the visible light response ability, but also facilitates the direct interfacial charge transfer (IFCT) from the SOVs to the surface Fe(III) clusters, greatly promoting the efficient separation of photogenerated electron-hole pairs. According to the trapping experiments and ESR measurements results, center dot O-2(-), center dot OH, and h(+) all participated in the phenol photodegradation process over F/BMO-SOVs. Thus, this work not only provides a synergistic effect between SOVs, Fe(III) clusters and Bi2MoO6 involving an IFCT process, but also proposes an efficient approach to fabricating highly active photocatalysts in environmental remediation and solar fuel synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2019, "Volume": 247, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 150, "End Page": 162, "Article Number": null, "DOI": "10.1016/j.apcatb.2019.01.056", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2019.01.056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460715100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chong, LA; Gao, GP; Wen, JG; Li, HX; Xu, HP; Green, Z; Sugar, JD; Kropf, AJ; Xu, WQ; Lin, XM; Xu, H; Wang, LW; Liu, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chong, Lina; Gao, Guoping; Wen, Jianguo; Li, Haixia; Xu, Haiping; Green, Zach; Sugar, Joshua D.; Kropf, A. Jeremy; Xu, Wenqian; Lin, Xiao-Min; Xu, Hui; Wang, Lin-Wang; Liu, Di-Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "La- and Mn-doped cobalt spinel oxygen evolution catalyst for proton exchange membrane electrolysis", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discovery of earth-abundant electrocatalysts to replace iridium for the oxygen evolution reaction (OER) in a proton exchange membrane water electrolyzer (PEMWE) represents a critical step in reducing the cost for green hydrogen production. We report a nullofibrous cobalt spinel catalyst codoped with lanthanum (La) and manganese (Mn) prepared from a zeolitic imidazolate framework embedded in electrospun polymer fiber. The catalyst demonstrated a low overpotential of 353 millivolts at 10 milliamperes per square centimeter and a low degradation for OER over 360 hours in acidic electrolyte. A PEMWE containing this catalyst at the anode demonstrated a current density of 2000 milliamperes per square centimeter at 2.47 volts (Nafion 115 membrane) or 4000 milliamperes per square centimeter at 3.00 volts (Nafion 212 membrane) and low degradation in an accelerated stress test.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2023, "Volume": 380, "Issue": 6645, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 609, "End Page": 616, "Article Number": null, "DOI": "10.1126/science.ade1499", "DOI Link": "http://dx.doi.org/10.1126/science.ade1499", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000999020900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortazavi, B; Javvaji, B; Shojaei, F; Rabczuk, T; Shapeev, A; Zhuang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortazavi, Bohayra; Javvaji, Brahmanulldam; Shojaei, Fazel; Rabczuk, Timon; Shapeev, Alexander, V; Zhuang, Xiaoying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional piezoelectricity, high thermal conductivity and stiffness and promising photocatalysis in two-dimensional MoSi2N4 family confirmed by first-principles", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical vapor deposition has been most recently employed to fabricate centimeter-scale high-quality singlelayer MoSi2N4 (Science; 2020;369; 670). Motivated by this exciting experimental advance, herein we conduct extensive first-principles based simulations to explore the stability, mechanical properties, lattice thermal conductivity, piezoelectric and flexoelectric response, and photocatalytic and electronic features of MA(2)Z(4) (M = Cr, Mo, W; A = Si, Ge; Z = N, P) monolayers. The considered nullosheets are found to exhibit dynamical stability and remarkably high mechanical properties. Moreover, they show diverse electronic properties from antiferromagnetic metal to half metal and to semiconductors with band gaps ranging from 0.31 to 2.57 eV. Among the studied nullosheets, the MoSi2N4 and WSi2N4 monolayers yield appropriate band edge positions, high electron and hole mobilities, and strong visible light absorption, highly promising for applications in optoelectronics and photocatalytic water splitting. The MoSi2N4 and WSi2N4 monolayers are also predicted to show outstandingly high lattice thermal conductivity of 440 and 500 W/mK, respectively. For the first time we show that machine learning interatomic potentials trained over small supercells can be employed to examine the flexoelectric and piezoelectric properties of complex structures. As the most exciting finding, WSi2N4, CrSi2N4 and MoSi2N4 are found to exhibit the highest piezoelectric coefficients, outperforming all other-known 2D materials. Our results highlight that MA(2)Z(4) nullosheets not only undoubtedly outperform the transition metal dichalcogenides family but also can compete with graphene for applications in nulloelectronics, optoelectronic, energy storage/conversion and thermal management systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 82, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105716, "DOI": "10.1016/j.nulloen.2020.105716", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105716", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634235000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JJ; Ma, SC; Sun, J; Gold, JI; Tiwary, C; Kim, B; Zhu, LY; Chopra, N; Odeh, IN; Vajtai, R; Yu, AZ; Luo, R; Lou, J; Ding, GQ; Kenis, PJA; Ajayan, PM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jingjie; Ma, Sichao; Sun, Jing; Gold, Jake I.; Tiwary, ChandraSekhar; Kim, Byoungsu; Zhu, Lingyang; Chopra, Nitin; Odeh, Ihab N.; Vajtai, Robert; Yu, Aaron Z.; Luo, Raymond; Lou, Jun; Ding, Guqiao; Kenis, Paul J. A.; Ajayan, Pulickel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of carbon dioxide into higher-energy liquid fuels and chemicals is a promising but challenging renewable energy conversion technology. Among the electrocatalysts screened so far for carbon dioxide reduction, which includes metals, alloys, organometallics, layered materials and carbon nullostructures, only copper exhibits selectivity towards formation of hydrocarbons and multi-carbon oxygenates at fairly high efficiencies, whereas most others favour production of carbon monoxide or formate. Here we report that nullometre-size N-doped graphene quantum dots (NGQDs) catalyse the electrochemical reduction of carbon dioxide into multi-carbon hydrocarbons and oxygenates at high Faradaic efficiencies, high current densities and low overpotentials. The NGQDs show a high total Faradaic efficiency of carbon dioxide reduction of up to 90%, with selectivity for ethylene and ethanol conversions reaching 45%. The C2 and C3 product distribution and production rate for NGQD-catalysed carbon dioxide reduction is comparable to those obtained with copper nulloparticle-based electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 507, "Times Cited, All Databases": 519, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 13", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13869, "DOI": "10.1038/ncomms13869", "DOI Link": "http://dx.doi.org/10.1038/ncomms13869", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389672200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; He, XY; Zhang, PH; Andaloussi, YH; Zhang, HL; Jiang, ZY; Chen, Y; Ma, SQ; Cheng, P; Zhang, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yi; He, Xueyi; Zhang, Penghui; Andaloussi, Yassin H.; Zhang, Hailu; Jiang, Zhongyi; Chen, Yao; Ma, Shengqian; Cheng, Peng; Zhang, Zhenjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combined Intrinsic and Extrinsic Proton Conduction in Robust Covalent Organic Frameworks for Hydrogen Fuel Cell Applications", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing new materials for the fabrication of proton exchange membranes (PEMs) for fuel cells is of great significance. Herein, a series of highly crystalline, porous, and stable new covalent organic frameworks (COFs) have been developed by a stepwise synthesis strategy. The synthesized COFs exhibit high hydrophilicity and excellent stability in strong acid or base (e.g., 12 m NaOH or HCl) and boiling water. These features make them ideal platforms for proton conduction applications. Upon loading with H3PO4, the COFs (H3PO4@COFs) realize an ultrahigh proton conductivity of 1.13x10(-1) S cm(-1), the highest among all COF materials, and maintain high proton conductivity across a wide relative humidity (40-100 %) and temperature range (20-80 degrees C). Furthermore, membrane electrode assemblies were fabricated using H3PO4@COFs as the solid electrolyte membrane for proton exchange resulting in a maximum power density of 81 mW cm(-2) and a maximum current density of 456 mA cm(-2), which exceeds all previously reported COF materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2020, "Volume": 59, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3678, "End Page": 3684, "Article Number": null, "DOI": "10.1002/anie.201913802", "DOI Link": "http://dx.doi.org/10.1002/anie.201913802", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509748300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CL; Wang, H; Chen, YY; Day, T; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Cheng-Lung; Wang, Heng; Chen, Yang-Yuan; Day, Tristan; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoelectric properties of p-type polycrystalline SnSe doped with Ag", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many IV-VI semiconductors tend to be good thermoelectric materials, these include all Pb chalcogenides as well as Pb-free SnTe: all of which crystallize in a NaCl cubic structure. Another group of IV-VI compounds form layered orthorhombic structures. SnSe is one of these compounds, whose transport properties as a polycrystalline thermoelectric material have rarely been studied. Here we present our study of p-type polycrystalline SnSe doped with Ag, prepared by melting and hot pressing. SnSe has anisotropic properties with hysteresis observed in resistivity between 300 and 650 K regardless of doping. Ag is not an ideal dopant but is able to increase the carrier density significantly, as a result a peak zT of 0.6 was observed at 750 K. Transport properties of doped SnSe can be explained with a single parabolic band model, which suggests promising potential for this compound together with its challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11171, "End Page": 11176, "Article Number": null, "DOI": "10.1039/c4ta01643b", "DOI Link": "http://dx.doi.org/10.1039/c4ta01643b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339004100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Ye, JW; Wang, HP; Pan, M; Yin, SY; Wei, ZW; Zhang, LY; Wu, K; Fan, YN; Su, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ling; Ye, Jia-Wen; Wang, Hai-Ping; Pan, Mei; Yin, Shao-Yun; Wei, Zhang-Wen; Zhang, Lu-Yin; Wu, Kai; Fan, Ya-null; Su, Cheng-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast water sensing and thermal imaging by a metal-organic framework with switchable luminescence", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A convenient, fast and selective water analysis method is highly desirable in industrial and detection processes. Here a robust microporous Zn-MOF (metal-organic framework, Zn(hpi2cf)(DMF)(H2O)) is assembled from a dual-emissive H(2)hpi2cf (5-(2-(5-fluoro-2-hydroxyphenyl)-4,5-bis(4-fluorophenyl)-1H-imidazol-1-yl) isophthalic acid) ligand that exhibits characteristic excited state intramolecular proton transfer (ESIPT). This Zn-MOF contains amphipathic micropores (<3 angstrom) and undergoes extremely facile single-crystal-to-single-crystal transformation driven by reversible removal/uptake of coordinating water molecules simply stimulated by dry gas blowing or gentle heating at 70 degrees C, manifesting an excellent example of dynamic reversible coordination behaviour. The interconversion between the hydrated and dehydrated phases can turn the ligand ESIPT process on or off, resulting in sensitive two-colour photoluminescence switching over cycles. Therefore, this Zn-MOF represents an excellent PL water-sensing material, showing a fast (on the order of seconds) and highly selective response to water on a molecular level. Furthermore, paper or in situ grown ZnO-based sensing films have been fabricated and applied in humidity sensing (RH<1%), detection of traces of water (<0.05% v/v) in various organic solvents, thermal imaging and as a thermometer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15985, "DOI": "10.1038/ncomms15985", "DOI Link": "http://dx.doi.org/10.1038/ncomms15985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404454800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Chen, B; Guan, DQ; Xu, MG; Ran, R; Ni, M; Zhou, W; O'Hayre, R; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuan; Chen, Bin; Guan, Daqin; Xu, Meigui; Ran, Ran; Ni, Meng; Zhou, Wei; O'Hayre, Ryan; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal-expansion offset for high-performance fuel cell cathodes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One challenge for the commercial development of solid oxide fuel cells as efficient energy-conversion devices isthermo-mechanical instability. Large internal-strain gradients caused by the mismatch in thermal expansion behaviour between different fuel cell components are the main cause of this instability, which can lead to cell degradation, delamination or fracture(1-4). Here we demonstrate an approach to realizing full thermo-mechanical compatibility between the cathode and other cell components by introducing a thermal-expansion offset. We use reactive sintering to combine a cobalt-based perovskite with high electrochemical activity and large thermal-expansion coefficient with a negative-thermal-expansion material, thus forming a composite electrode with a thermal-expansion behaviour that is well matched to that of the electrolyte. A new interphase is formed because of the limited reaction between the two materials in the composite during the calcination process, which also creates A-site deficiencies in the perovskite. As a result, the composite shows both high activity and excellent stability. The introduction of reactive negative-thermal-expansion components may provide a general strategy for the development of fully compatible and highly active electrodes for solid oxide fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 591, "Issue": 7849, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 246, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03264-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03264-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627422700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, YC; Chen, LW; Li, JN; Guo, Y; Su, X; Shu, M; Zhang, QH; Gao, WY; Li, SW; Yu, ZL; Gu, L; Feng, X; Yin, AX; Si, R; Zhang, YW; Wang, B; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Yu-Chen; Chen, Li-Wei; Li, Jiani; Guo, Yu; Su, Xin; Shu, Miao; Zhang, Qinghua; Gao, Wen-Yan; Li, Siwu; Yu, Zi-Long; Gu, Lin; Feng, Xiao; Yin, An-Xiang; Si, Rui; Zhang, Ya-Wen; Wang, Bo; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework membranes with single-atomic centers for photocatalytic CO2 and O2 reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The demand for sustainable energy has motivated the development of artificial photosynthesis. Yet the catalyst and reaction interface designs for directly fixing permanent gases (e.g. CO2, O-2, N-2) into liquid fuels are still challenged by slow mass transfer and sluggish catalytic kinetics at the gas-liquid-solid boundary. Here, we report that gas-permeable metal-organic framework (MOF) membranes can modify the electronic structures and catalytic properties of metal single-atoms (SAs) to promote the diffusion, activation, and reduction of gas molecules (e.g. CO2, O-2) and produce liquid fuels under visible light and mild conditions. With Ir SAs as active centers, the defect-engineered MOF (e.g. activated NH2-UiO-66) particles can reduce CO2 to HCOOH with an apparent quantum efficiency (AQE) of 2.51% at 420nm on the gas-liquid-solid reaction interface. With promoted gas diffusion at the porous gas-solid interfaces, the gas-permeable SA/MOF membranes can directly convert humid CO2 gas into HCOOH with a near-unity selectivity and a significantly increased AQE of 15.76% at 420nm. A similar strategy can be applied to the photocatalytic O-2-to-H2O2 conversions, suggesting the wide applicability of our catalyst and reaction interface designs. Photoreduction of permanent gas faces challenges in reactant diffusion and activation at the three-phase interface. Here the authors showed porous metal-organic framework membranes decorated by metal single atoms can boost the photoreduction of CO2 and O-2 at the high-throughput gas-solid interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2682, "DOI": "10.1038/s41467-021-22991-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22991-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658723900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghidiu, M; Halim, J; Kota, S; Bish, D; Gogotsi, Y; Barsourm, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghidiu, Michael; Halim, Joseph; Kota, Sankalp; Bish, David; Gogotsi, Yury; Barsourm, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion-Exchange and Cation Solvation Reactions in Ti3C2 MXene", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ti3C2 and other two-dimensional transition metal carbides known as MXenes are currently being explored for many applications involving intercalated ions, from electrochemical energy storage, to contaminullt sorption from water, to selected ion sieving. We report here a systematic investigation of ion exchange in Ti3C2 MXene and its hydration/dehydration behavior. We have investigated the effects of the presence of LiCl during the chemical etching of the MAX phase Ti3AlC2 into MXene Ti3C2Tx (T stands for surface termination) and found that the resulting MXene has Li+ cations in the interlayer space. We successfully exchanged the Li+ cations with K+, Na+, Rb+, Mg2+, and Ca2+ (supported by X-ray photoelectron and energy-dispersive spectroscopy) and found that the exchanged material expands on the unit-cell level in response to changes in humidity, with the nature expansion dependent on the intercalated cation, similar to behavior of clay minerals; stepwise expansions of the basal spacing were observed, with changes consistent with the size of the H2O molecule. Thermogravimetric analysis of the dehydration behavior of these materials shows that the amounts of H2O contained at ambient humidity correlates simply with the hydration enthalpy of the intercalated cation, and that the diffusion of the exiting H2O proceeds with kinetics similar to clays. These results have implications for understanding, controlling, and exploiting structural changes and H2O sorption in MXene films and powders utilized in applications involving ions, such as electrochemical capacitors, sensors, reverse osmosis membranes, or contaminullt sorbents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2016, "Volume": 28, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3507, "End Page": 3514, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b01275", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b01275", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376825700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hantanasirisakul, K; Zhao, MQ; Urbankowski, P; Halim, J; Anasori, B; Kota, S; Ren, CE; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hantanasirisakul, Kanit; Zhao, Meng-Qiang; Urbankowski, Patrick; Halim, Joseph; Anasori, Babak; Kota, Sankalp; Ren, Chang E.; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabrication of Ti3C2Tx MXene Transparent Thin Films with Tunable Optoelectronic Properties", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes, a new class of 2D transition metal carbides and carbonitrides, show great promise in supercapacitors, Li-ion batteries, fuel cells, and sensor applications. A unique combination of their metallic conductivity, hydrophilic surface, and excellent mechanical properties renders them attractive for transparent conductive electrode application. Here, a simple, scalable method is proposed to fabricate transparent conductive thin films using delaminated Ti3C2 MXene flakes by spray coating. Homogenous films, 5-70 nm thick, are produced at ambient conditions over a large area as shown by scanning electron microscopy and atomic force microscopy. The sheet resistances (R-s) range from 0.5 to 8 k Omega sq(-1) at 40% to 90% transmittance, respectively, which corresponds to figures of merit (the ratio of electronic to optical conductivities, sigma(DC)/sigma(opt)) around 0.5-0.7. Flexible, transparent, and conductive films are also produced and exhibit stable R-s values at up to 5 mm bend radii. Furthermore, the films' optoelectronic properties are tuned by chemical or electrochemical intercalation of cations. The films show reversible changes of transmittance in the UV-visible region during electrochemical intercalation/deintercalation of tetramethylammonium hydroxide. This work shows the potential of MXenes to be used as transparent conductors in electronic, electrochromic, and sensor applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 632, "Times Cited, All Databases": 676, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600050, "DOI": "10.1002/aelm.201600050", "DOI Link": "http://dx.doi.org/10.1002/aelm.201600050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379912100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, PF; Li, XF; Min, P; Chang, XY; Shu, C; Ding, Y; Yu, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Pengfei; Li, Xiaofeng; Min, Peng; Chang, Xiyuan; Shu, Chao; Ding, Yun; Yu, Zhong-Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Lamellar-Structured Graphene Aerogels for Thermal Interface Composites with High Through-Plane Thermal Conductivity and Fracture Toughness", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although thermally conductive graphene sheets are efficient in enhancing in-plane thermal conductivities of polymers, the resulting nullocomposites usually exhibit low through-plane thermal conductivities, limiting their application as thermal interface materials. Herein, lamellar-structured polyamic acid salt/graphene oxide (PAAS/GO) hybrid aerogels are constructed by bidirectional freezing of PAAS/GO suspension followed by lyophilization. Subsequently, PAAS monomers are polymerized to polyimide (PI), while GO is converted to thermally reduced graphene oxide (RGO) during thermal annealing at 300 degrees C. Final graphitization at 2800 degrees C converts PI to graphitized carbon with the inductive effect of RGO, and simultaneously, RGO is thermally reduced and healed to high-quality graphene. Consequently, lamellar-structured graphene aerogels with superior through-plane thermal conduction capacity are fabricated for the first time, and its superior through-plane thermal conduction capacity results from its vertically aligned and closely stacked high-quality graphene lamellae. After vacuum-assisted impregnation with epoxy, the resultant epoxy composite with 2.30 vol% of graphene exhibits an outstanding through-plane thermal conductivity of as high as 20.0 W m(-1) K-1, 100 times of that of epoxy, with a record-high specific thermal conductivity enhancement of 4310%. Furthermore, the lamellar-structured graphene aerogel endows epoxy with a high fracture toughness, similar to 1.71 times of that of epoxy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 22, "DOI": "10.1007/s40820-020-00548-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00548-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000593959800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, YJ; Li, YQ; Zhu, LC; Liu, Y; Lei, XQ; Wang, G; Wu, YX; Mi, ZL; Liu, JB; Wang, HT; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Yujie; Li, Yongqiang; Zhu, Lianchun; Liu, Yao; Lei, Xianqi; Wang, Gang; Wu, Yanxin; Mi, Zhenli; Liu, Jiabin; Wang, Hongtao; Gao, Huajian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evading the strength- ductility trade-off dilemma in steel through gradient hierarchical nullotwins", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The strength-ductility trade-off has been a long-standing dilemma in materials science. This has limited the potential of many structural materials, steels in particular. Here we report a way of enhancing the strength of twinning-induced plasticity steel at no ductility trade-off. After applying torsion to cylindrical twinning-induced plasticity steel samples to generate a gradient nullotwinned structure along the radial direction, we find that the yielding strength of the material can be doubled at no reduction in ductility. It is shown that this evasion of strength-ductility trade-off is due to the formation of a gradient hierarchical nullotwinned structure during pre-torsion and subsequent tensile deformation. A series of finite element simulations based on crystal plasticity are performed to understand why the gradient twin structure can cause strengthening and ductility retention, and how sequential torsion and tension lead to the observed hierarchical nullotwinned structure through activation of different twinning systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 878, "Times Cited, All Databases": 934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3580, "DOI": "10.1038/ncomms4580", "DOI Link": "http://dx.doi.org/10.1038/ncomms4580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335220300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, XJ; Huang, XP; Ai, ZH; Zhao, JC; Zhang, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Xiaojing; Huang, Xiaopeng; Ai, Zhihui; Zhao, Jincai; Zhang, Lizhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ascorbic acid/Fe@Fe2O3: A highly efficient combined Fenton reagent to remove organic contaminullts", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, we demonstrate that the combination of ascorbic acid and Fe@Fe2O3 core -shell nullowires (AA/Fe@Fe2O3) offers a highly efficient Fenton reagent. This combined Fenton reagent exhibited extremely high activity on the decomposition of H2O2 to produce center dot OH for the degradation of various organic contaminullts, including rhodamine B, methylene blue, alachlor, atrazine, siduron, lincomycin, and chloroamphenicol. The contaminullt degradation constants in the AA/Fe@Fe2O3/H2O2 Fenton systems were 38-53 times higher than those in the conventional homogeneous Fenton system (Fe(II)/H2O2) at pH 3.8. Moreover, the center dot OH generation rate constant in the AA/Fe@Fe2O3/H2O2 Fenton system was 1-3 orders of magnitudes greater than those of heterogeneous Fenton systems developed with other iron -containing materials (alpha-FeOOH, alpha-Fe2O3, FeOCl, and so on). The high activity of AA/Fe@Fe2O3 was attributed to the effective Fe(III)/Fe(II) cycle and the iron-ascorbate complex formation to stabilize ferrous ions with desirable and steady concentrations. During the AA/Fe@Fe2O3/H2O2 Fenton process, ascorbic acid served as a reducing and complexing reagent, enabling the reuse of Fe@Fe2O3 nullowires. We systematically investigated the alachlor and ascorbic acid degradation and found that they could be (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2016, "Volume": 310, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 170, "End Page": 178, "Article Number": null, "DOI": "10.1016/j.jhazmat.2016.01.020", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2016.01.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374804000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Fang, YJ; Lu, XF; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yi; Fang, Yongjin; Lu, Xue Feng; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co3O4Hollow nulloparticles Embedded in Mesoporous Walls of Carbon nulloboxes for Efficient Lithium Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Confining nullostructured electrode materials in porous carbon represents an effective strategy for improving the electrochemical performance of lithium-ion batteries. Herein, we report the design and synthesis of hybrid hollow nullostructures composed of highly dispersed Co(3)O(4)hollow nulloparticles (sub-20 nm) embedded in the mesoporous walls of carbon nulloboxes (denoted as H-Co3O4@MCNBs) as an anode material for lithium-ion batteries. The facile metal-organic framework (MOF)-engaged strategy for the synthesis of H-Co3O4@MCNBs involves chemical etching-coordination and subsequent two-step annealing treatments. Owing to the unique structural merits including more active interfacial sites, effectively alleviated volume variation, good and stable electrical contact, and easy access of Li(+)ions, the H-Co3O4@MCNBs exhibit excellent lithium-storage performance in terms of high specific capacity, excellent rate capability, and cycling stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2020, "Volume": 59, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19914, "End Page": 19918, "Article Number": null, "DOI": "10.1002/anie.202008987", "DOI Link": "http://dx.doi.org/10.1002/anie.202008987", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564122500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baltz, V; Manchon, A; Tsoi, M; Moriyama, T; Ono, T; Tserkovnyak, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baltz, V.; Manchon, A.; Tsoi, M.; Moriyama, T.; Ono, T.; Tserkovnyak, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antiferromagnetic spintronics", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferromagnetic materials could represent the future of spintronic applications thanks to the numerous interesting features they combine: they are robust against perturbation due to magnetic fields, produce no stray fields, display ultrafast dynamics, and are capable of generating large magnetotransport effects. Intense research efforts over the past decade have been invested in unraveling spin transport properties in antiferromagnetic materials. Whether spin transport can be used to drive the antiferromagnetic order and how subsequent variations can be detected are some of the thrilling challenges currently being addressed. Antiferromagnetic spintronics started out with studies on spin transfer and has undergone a definite revival in the last few years with the publication of pioneering articles on the use of spin-orbit interactions in antiferromagnets. This paradigm shift offers possibilities for radically new concepts for spin manipulation in electronics. Central to these endeavors are the need for predictive models, relevant disruptive materials, and new experimental designs. This paper reviews the most prominent spintronic effects described based on theoretical and experimental analysis of antiferromagnetic materials. It also details some of the remaining bottlenecks and suggests possible avenues for future research. This review covers both spin-transfer-related effects, such as spin-transfer torque, spin penetration length, domain-wall motion, and magnetization dynamics, and spin-orbit related phenomena, such as (tunnel) anisotropic magnetoresistance, spin Hall, and inverse spin galvanic effects. Effects related to spin caloritronics, such as the spin Seebeck effect, are linked to the transport of magnons in antiferromagnets. The propagation of spin waves and spin superfluids in antiferromagnets is also covered.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1831, "Times Cited, All Databases": 1930, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2018, "Volume": 90, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15005, "DOI": "10.1103/RevModPhys.90.015005", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.015005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425095700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, ZH; Wang, CX; Siqueira, G; Han, DX; Huch, A; Abdolhosseinzadeh, S; Heier, J; Nüesch, F; Zhang, CF; Nyström, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Zhihui; Wang, Changxian; Siqueira, Gilberto; Han, Daxin; Huch, Anja; Abdolhosseinzadeh, Sina; Heier, Jakob; Nueesch, Frank; Zhang, Chuanfang (John); Nystroem, Gustav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose-MXene Biomimetic Aerogels with Orientation-Tunable Electromagnetic Interference Shielding Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing lightweight nullostructured aerogels for high-performance electromagnetic interference (EMI) shielding is crucial yet challenging. Ultrathin cellulose nullofibrils (CNFs) are employed for assisting in building ultralow-density, robust, and highly flexible transition metal carbides and nitrides (MXenes) aerogels with oriented biomimetic cell walls. A significant influence of the angles between oriented cell walls and the incident EM wave electric field direction on the EMI shielding performance is revealed, providing an intriguing microstructure design strategy. MXene bricks bonded by CNF mortars of the nacre-like cell walls induce high mechanical strength, electrical conductivity, and interfacial polarization, yielding the resultant MXene/CNF aerogels an ultrahigh EMI shielding performance. The EMI shielding effectiveness (SE) of the aerogels reaches 74.6 or 35.5 dB at a density of merely 8.0 or 1.5 mg cm(-3), respectively. The normalized surface specific SE is up to 189 400 dB cm(2) g(-1), significantly exceeding that of other EMI shielding materials reported so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 7, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000979, "DOI": "10.1002/advs.202000979", "DOI Link": "http://dx.doi.org/10.1002/advs.202000979", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543735600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HL; Wu, Y; He, JY; Wang, H; Liu, XJ; An, K; Wu, W; Lu, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Hailong; Wu, Yuan; He, Junyang; Wang, Hui; Liu, Xiongjun; An, Ke; Wu, Wei; Lu, Zhaoping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-Transformation Ductilization of Brittle High-Entropy Alloys via Metastability Engineering", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) in which interesting physical, chemical, and structural properties are being continuously revealed have recently attracted extensive attention. Body-centered cubic (bcc) HEAs, particularly those based on refractory elements are promising for high-temperature application but generally fail by early cracking with limited plasticity at room temperature, which limits their malleability and widespread uses. Here, the metastability-engineering strategy is exploited in brittle bcc HEAs via tailoring the stability of the constituent phases, and transformation-induced ductility and workhardening capability are successfully achieved. This not only sheds new insights on the development of HEAs with excellent combination of strength and ductility, but also has great implications on overcoming the long-standing strength-ductility tradeoff of metallic materials in general.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 565, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2017, "Volume": 29, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701678, "DOI": "10.1002/adma.201701678", "DOI Link": "http://dx.doi.org/10.1002/adma.201701678", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407048800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, Y; Ouyang, B; Liu, J; Byeon, YW; Cai, ZJ; Miara, LJ; Wang, Y; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Yan; Ouyang, Bin; Liu, Jue; Byeon, Young-Woon; Cai, Zijian; Miara, Lincoln J.; Wang, Yan; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy mechanism to boost ionic conductivity", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in solid-state batteries have primarily been driven by the discovery of superionic conducting structural frameworks that function as solid electrolytes. We demonstrate the ability of high-entropy metal cation mixes to improve ionic conductivity in a compound, which leads to less reliance on specific chemistries and enhanced synthesizability. The local distortions introduced into high-entropy materials give rise to an overlapping distribution of site energies for the alkali ions so that they can percolate with low activation energy. Experiments verify that high entropy leads to orders-of-magnitude higher ionic conductivities in lithium (Li)-sodium (Na) superionic conductor (Li-NASICON), sodium NASICON (Na-NASICON), and Li-garnet structures, even at fixed alkali content. We provide insight into selecting the optimal distortion and designing high-entropy superionic conductors across the vast compositional space.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2022, "Volume": 378, "Issue": 6626, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1320, "End Page": 1324, "Article Number": null, "DOI": "10.1126/science.abq1346", "DOI Link": "http://dx.doi.org/10.1126/science.abq1346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905457800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, HL; Wu, Z; Zhang, LH; Ying, YR; Liu, Y; Fei, LF; Chen, XX; Jia, YM; Wang, YJ; Wang, FF; Ju, S; Qiao, JL; Lam, CH; Huang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Huilin; Wu, Zheng; Zhang, Luohong; Ying, Yiran; Liu, Yan; Fei, Linfeng; Chen, Xinxin; Jia, Yanmin; Wang, Yaojin; Wang, Feifei; Ju, Sheng; Qiao, Jinli; Lam, Chi-Hang; Huang, Haitao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harvesting the Vibration Energy of BiFeO3 nullosheets for Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, mechanical vibration is used for hydrogen generation and decomposition of dye molecules, with the help of BiFeO3 (BFO) square nullosheets. A high hydrogen production rate of approximate to 124.1 mu mol g(-1) is achieved under mechanical vibration (100 W) for 1 h at the resonullt frequency of the BFO nullosheets. The decomposition ratio of Rhodamine B dye reaches up to approximate to 94.1 % after mechanical vibration of the BFO catalyst for 50 min. The vibration-induced catalysis of the BFO square nullosheets may be attributed to the piezocatalytic properties of BFO and the high specific surface area of the nullosheets. The uncompensated piezoelectric charges on the surfaces of BFO nullosheets induced by mechanical vibration result in a built-in electric field across the nullosheets. Unlike a photocatalyst for water splitting, which requires a proper band edge position for hydrogen evolution, such a requirement is not needed in piezocatalytic water splitting, where the band tilting under the induced piezoelectric field will make the conduction band of BFO more negative than the H-2/H2O redox potential (0 V) for hydrogen generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2019, "Volume": 58, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11779, "End Page": 11784, "Article Number": null, "DOI": "10.1002/anie.201906181", "DOI Link": "http://dx.doi.org/10.1002/anie.201906181", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476269300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Saliba, M; Moore, DT; Pathak, SK; Hörantner, MT; Stergiopoulos, T; Stranks, SD; Eperon, GE; Alexander-Webber, JA; Abate, A; Sadhanala, A; Yao, SH; Chen, YL; Friend, RH; Estroff, LA; Wiesner, U; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Saliba, Michael; Moore, David T.; Pathak, Sandeep K.; Hoerantner, Maximilian T.; Stergiopoulos, Thomas; Stranks, Samuel D.; Eperon, Giles E.; Alexander-Webber, Jack A.; Abate, Antonio; Sadhanala, Aditya; Yao, Shuhua; Chen, Yulin; Friend, Richard H.; Estroff, Lara A.; Wiesner, Ulrich; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasmooth organic-inorganic perovskite thin-film formation and crystallization for efficient planar heterojunction solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date, there have been a plethora of reports on different means to fabricate organic-inorganic metal halide perovskite thin films; however, the inorganic starting materials have been limited to halide-based anions. Here we study the role of the anions in the perovskite solution and their influence upon perovskite crystal growth, film formation and device performance. We find that by using a non-halide lead source (lead acetate) instead of lead chloride or iodide, the perovskite crystal growth is much faster, which allows us to obtain ultrasmooth and almost pinhole-free perovskite films by a simple one-step solution coating with only a few minutes annealing. This synthesis leads to improved device performance in planar heterojunction architectures and answers a critical question as to the role of the anion and excess organic component during crystallization. Our work paves the way to tune the crystal growth kinetics by simple chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 809, "Times Cited, All Databases": 877, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6142, "DOI": "10.1038/ncomms7142", "DOI Link": "http://dx.doi.org/10.1038/ncomms7142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348832400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarker, P; Harrington, T; Toher, C; Oses, C; Samiee, M; Maria, JP; Brenner, DW; Vecchio, KS; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarker, Pranab; Harrington, Tyler; Toher, Cormac; Oses, Corey; Samiee, Mojtaba; Maria, Jon-Paul; Brenner, Donald W.; Vecchio, Kenneth S.; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy high-hardness metal carbides discovered by entropy descriptors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy materials have attracted considerable interest due to the combination of useful properties and promising applications. Predicting their formation remains the major hindrance to the discovery of new systems. Here we propose a descriptor-entropy forming ability-for addressing synthesizability from first principles. The formalism, based on the energy distribution spectrum of randomized calculations, captures the accessibility of equally-sampled states near the ground state and quantifies configurational disorder capable of stabilizing high-entropy homogeneous phases. The methodology is applied to disordered refractory 5-metal carbides-promising candidates for high-hardness applications. The descriptor correctly predicts the ease with which compositions can be experimentally synthesized as rock-salt high-entropy homogeneous phases, validating the ansatz, and in some cases, going beyond intuition. Several of these materials exhibit hardness up to 50% higher than rule of mixtures estimations. The entropy descriptor method has the potential to accelerate the search for high-entropy systems by rationally combining first principles with experimental synthesis and characterization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 823, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4980, "DOI": "10.1038/s41467-018-07160-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07160-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451176100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JT; Han, G; Zhao, DL; Lu, KJ; Gao, J; Chung, TS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jiangtao; Han, Gang; Zhao, Dieling; Lu, Kangjia; Gao, Jie; Chung, Tai-Shung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-standing and flexible covalent organic framework (COF) membranes for molecular separation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Almost all covalent organic framework (COF) materials conventionally fabricated by solvothermal method at high temperatures and pressures are insoluble and unprocessable powders, which severely hinder their widespread applications. This work develops an effective and facile strategy to construct flexible and free-standing pure COF membranes via the liquid-liquid interface-confined reaction at room temperature and atmospheric pressure. The aperture size and channel chemistry of COF membranes can be rationally designed by bridging various molecular building blocks via strong covalent bonds. Benefiting from the highly-ordered honeycomb lattice, high solvent permeances are successfully obtained and follow the trend of acetonitrile > acetone > methanol > ethanol > isopropanol. Interestingly, the imine-linked COF membrane shows higher nonpolar solvent permeances than b-ketoenamine-linked COF due to their difference in pore polarity. Both kinds of COF membranes exhibit high solvent permeances, precise molecular sieving, excellent shape selectivity, and sufficient flexibility for membrane-based separation science and technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 6, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb1110", "DOI": "10.1126/sciadv.abb1110", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb1110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579161500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Z; Zhang, R; Wang, HY; Zhou, SY; Pan, ZY; Huang, YC; Sun, D; Tang, YG; Ji, XB; Amine, K; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Zheng; Zhang, Rui; Wang, Haiyan; Zhou, Siyu; Pan, Zhiyi; Huang, Yuancheng; Sun, Dan; Tang, Yougen; Ji, Xiaobo; Amine, Khalil; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g-1 at 20 mA g-1 (plateau capacity of 293 mAh g-1 for the second cycle), as well as good rate and stable cycling performances (85.4% after 400 cycles at 500 mA g-1). Deep insights into the closed pore formation will greatly forward the rational design of hard carbon anode with high capacity. It is essential to investigate the formation mechanism of closed pore, which contributes to low-voltage plateau capacity of hard carbon anode in sodium ion batteries. Herein, the authors explore the impact of wood precursor components and carbonization temperature on closed pore formation in hard carbon for enhanced battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6024, "DOI": "10.1038/s41467-023-39637-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39637-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001095471200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Shi, MS; Xu, FY; Qiu, Y; Zhang, P; Shen, KL; Zhao, Q; Yu, JG; Zhang, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Shi, Miusi; Xu, Feiyan; Qiu, Yun; Zhang, Peng; Shen, Kailun; Zhao, Qin; Yu, Jiaguo; Zhang, Yufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphdiyne-modified TiO2 nullofibers with osteoinductive and enhanced photocatalytic antibacterial activities to prevent implant infection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Titanium implants have been widely used in bone tissue engineering for decades. However, orthopedic implant-associated infections increase the risk of implant failure and even lead to amputation in severe cases. Although TiO2 has photocatalytic activity to produce reactive oxygen species (ROS), the recombination of generated electrons and holes limits its antibacterial ability. Here, we describe a graphdiyne (GDY) composite TiO2 nullofiber that combats implant infections through enhanced photocatalysis and prolonged antibacterial ability. In addition, GDY-modified TiO2 nullofibers exert superior biocompatibility and osteoinductive abilities for cell adhesion and differentiation, thus contributing to the bone tissue regeneration process in drug-resistant bacteria-induced implant infection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4465, "DOI": "10.1038/s41467-020-18267-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18267-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604254200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jawad, A; Zhan, K; Wang, HB; Shahzad, A; Zeng, ZH; Wang, J; Zhou, XQ; Ullah, H; Chen, ZL; Chen, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jawad, Ali; Zhan, Kun; Wang, Haibin; Shahzad, Ajmal; Zeng, Zehua; Wang, Jia; Zhou, Xinquan; Ullah, Habib; Chen, Zhulei; Chen, Zhuqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning of Persulfate Activation from a Free Radical to a Nonradical Pathway through the Incorporation of Non-Redox Magnesium Oxide", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonradical-based advanced oxidation processes for pollutant removal have attracted much attention due to their inherent advantages. Herein we report that magnesium oxides (MgO) in Cu0MgO/Fe3O4 not only enhanced the catalytic properties but also switched the free radical peroxymonosulfate (PMS)-activated process into the O-1(2) based nonradical process. CuOMgO/Fe3O4 catalyst exhibited consistent performance in a wide pH range from 5.0 to 10.0, and the degradation kinetics were not inhibited by the common free radical scavengers, anions, or natural organic matter. Quantitative structure-activity relationships (QSARs) revealed the relationship between the degradation rate constant of 14 substituted phenols and their conventional descriptor variables (i.e., Hammett constants sigma, sigma(-), sigma(+)), half-wave oxidation potential (E-1/2), and pK(a) values. QSARs together with the kinetic isotopic effect (KIE) recognized the electron transfer as the dominullt oxidation process. Characterizations and DFT calculation indicated that the incorporated MgO alters the copper sites to highly oxidized metal centers, offering a more suitable platform for PMS to generate metastable copper intermediates. These highly oxidized metals centers of copper played the key role in producing O-2(center dot-) after accepting an electron from another PMS molecule, and finally O-1(2) as sole reactive species was generated from the direct oxidation of O-2(center dot-) through thermodynamically feasible reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 461, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2020, "Volume": 54, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2476, "End Page": 2488, "Article Number": null, "DOI": "10.1021/acs.est.9b04696", "DOI Link": "http://dx.doi.org/10.1021/acs.est.9b04696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514759000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZQ; Zhao, YZ; Wang, X; Sun, YC; Zhao, ZG; Li, YJ; Zhou, HP; Chen, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zongqi; Zhao, Yingzhi; Wang, Xi; Sun, Yuchao; Zhao, Zhiguo; Li, Yujing; Zhou, Huanping; Chen, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cost Analysis of Perovskite Tandem Photovoltaics", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, metal halide perovskite photovoltaics (PV) are marching toward commercialization. The possibility for perovskite absorbers to be incorporated into multi-junction solar cells is also being discussed, which suggests alternative market entry. Although intensive investigations are being made on their technical feasibility, serious analysis on the cost of perovskite-based tandem modules is lacking. The levelized cost of electricity (LCOE) of solar modules is often used to evaluate technoeconomic competitiveness. Here, we performed a detailed cost analysis on two perovskite-based tandem modules (the perovskite/ c-silicon and the perovskite/ perovskite tandem module) compared with standard multi-crystalline silicon and single-junction perovskite solar cells. We found that perovskite PVs (both single junction and multi-junction) are competitive in the context of LCOE if the module lifetime is comparable with that of c-silicon solar cells. This encourages further efforts to push perovskite tandem modules onto the market in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1559, "End Page": 1572, "Article Number": null, "DOI": "10.1016/j.joule.2018.05.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.05.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441627400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yankowitz, M; Chen, SW; Polshyn, H; Zhang, YX; Watanabe, K; Taniguchi, T; Graf, D; Young, AF; Dean, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yankowitz, Matthew; Chen, Shaowen; Polshyn, Hryhoriy; Zhang, Yuxuan; Watanabe, K.; Taniguchi, T.; Graf, David; Young, Andrea F.; Dean, Cory R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning superconductivity in twisted bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with flat electronic bands often exhibit exotic quantum phenomena owing to strong correlations. An isolated low-energy flat band can be induced in bilayer graphene by simply rotating the layers by 1.1 degrees, resulting in the appearance of gate-tunable superconducting and correlated insulating phases. In this study, we demonstrate that in addition to the twist angle, the interlayer coupling can be varied to precisely tune these phases. We induce superconductivity at a twist angle larger than 1.1 degrees-in which correlated phases are otherwise absent-by varying the interlayer spacing with hydrostatic pressure. Our low-disorder devices reveal details about the superconducting phase diagram and its relationship to the nearby insulator. Our results demonstrate twisted bilayer graphene to be a distinctively tunable platform for exploring correlated states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1693, "Times Cited, All Databases": 1844, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2019, "Volume": 363, "Issue": 6431, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1059, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav1910", "DOI Link": "http://dx.doi.org/10.1126/science.aav1910", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460750100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Mckeon, L; Garcia, J; Pinilla, S; Barwich, S; Möbius, M; Stamenov, P; Coleman, JN; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ji; Mckeon, Lorcan; Garcia, James; Pinilla, Sergio; Barwich, Sebastian; Mobius, Matthias; Stamenov, Plamen; Coleman, Jonathan N.; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive Manufacturing of Ti3C2-MXene-Functionalized Conductive Polymer Hydrogels for Electromagnetic-Interference Shielding", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ongoing miniaturization of devices and development of wireless and implantable technologies demand electromagnetic interference (EMI)-shielding materials with customizability. Additive manufacturing of conductive polymer hydrogels with favorable conductivity and biocompatibility can offer new opportunities for EMI-shielding applications. However, simultaneously achieving high conductivity, design freedom, and shape fidelity in 3D printing of conductive polymer hydrogels is still very challenging. Here, an aqueous Ti3C2-MXene-functionalized poly(3,4-ethylenedioxythiophene):polystyrene sulfonate ink is developed for extrusion printing to create 3D objects with arbitrary geometries, and a freeze-thawing protocol is proposed to transform the printed objects directly into highly conductive and robust hydrogels with high shape fidelity on both the macro- and microscale. The as-obtained hydrogel exhibits a high conductivity of 1525.8 S m(-1) at water content up to 96.6 wt% and also satisfactory mechanical properties with flexibility, stretchability, and fatigue resistance. Furthermore, the use of the printed hydrogel for customizable EMI-shielding applications is demonstrated. The proposed easy-to-manufacture approach, along with the highlighted superior properties, expands the potential of conductive polymer hydrogels in future customizable applications and represents a real breakthrough from the current state of the art.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 34, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2106253, "DOI": "10.1002/adma.202106253", "DOI Link": "http://dx.doi.org/10.1002/adma.202106253", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750549600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, XC; Jiang, BZ; Wang, XL; Liu, WB; Dong, LB; Kang, FY; Xu, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Xuechao; Jiang, Baozheng; Wang, Xianli; Liu, Wenbao; Dong, Liubing; Kang, Feiyu; Xu, Chengjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Aqueous Zinc-Ion Batteries Realized by MOF Materials", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries (ZIBs) have been gaining increasing interest for large-scale energy storage applications due to their high safety, good rate capability, and low cost. However, the further development of ZIBs is impeded by two main challenges: Currently reported cathode materials usually suffer from rapid capacity fading or high toxicity, and meanwhile, unstable zinc stripping/plating on Zn anode seriously shortens the cycling life of ZIBs. In this paper, metal-organic framework (MOF) materials are proposed to simultaneously address these issues and realize high-performance ZIBs with Mn(BTC) MOF cathodes and ZIF-8-coated Zn (ZIF-8@Zn) anodes. Various MOF materials were synthesized, and Mn(BTC) MOF was found to exhibit the best Zn2+-storage ability with a capacity of 112 mAh g(-1). Zn(2+)storage mechanism of the Mn(BTC) was carefully studied. Besides, ZIF-8@Zn anodes were prepared by coating ZIF-8 MOF material on Zn foils. Unique porous structure of the ZIF-8 coating guided uniform Zn stripping/plating on the surface of Zn anodes. As a result, the ZIF-8@Zn anodes exhibited stable Zn stripping/plating behaviors, with 8 times longer cycle life than bare Zn foils. Based on the above, high-performance aqueous ZIBs were constructed using the Mn(BTC) cathodes and the ZIF-8@Zn anodes, which displayed an excellent long-cycling stability without obvious capacity fading after 900 charge/discharge cycles. This work provides a new opportunity for high-performance energy storage system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2020, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 152, "DOI": "10.1007/s40820-020-00487-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00487-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549602800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Q; Yu, J; Zou, XH; Liao, KM; Tan, P; Zhou, W; Ni, M; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Qian; Yu, Jie; Zou, Xiaohong; Liao, Kaiming; Tan, Peng; Zhou, Wei; Ni, Meng; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Catalyzed Growth of Co, N-Codoped CNTs on Carbon-Encased CoSx Surface: A Noble-Metal-Free Bifunctional Oxygen Electrocatalyst for Flexible Solid Zn-Air Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The self-catalyzed growth of nullostructures on material surfaces is one of the most time- and cost-effective ways to design multifunctional catalysts for a wide range of applications. Herein, the use of this technique to develop a multicomponent composite catalyst with CoSx core encapsulated in an ultrathin porous carbon shell entangled with Co, N-codoped carbon nullotubes is reported. The as-prepared catalyst has a superior catalytic activity for oxygen evolution and oxygen reduction reactions, an ultralow potential gap of 0.74 V, and outstanding durability, surpassing most previous reports. Such superiority is ascribed, in part, to the unique 3D electrode architecture of the composite, which is favorable for transporting oxygen species and electrons and creates a synergy between the components with different functionalities. Moreover, the flexible solid Zn-air battery assembled with such an air electrode shows a steady discharge voltage plateau of 1.25 V and a round-trip efficiency of 70% at 1 mA cm(-2). This work presents a simple strategy to design highly efficient bifunctional oxygen electrocatalysts and may pave the way for the practical application of these materials in many energy conversion/storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 29, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904481, "DOI": "10.1002/adfm.201904481", "DOI Link": "http://dx.doi.org/10.1002/adfm.201904481", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476276800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, C; Li, L; Liu, Y; Fang, B; Ding, H; Song, JN; Liu, YB; Xiang, KJ; Lin, S; Li, ZW; Si, WJ; Li, B; Sheng, X; Wang, DZ; Wei, XD; Wu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Chao; Li, Lei; Liu, Ying; Fang, Ben; Ding, He; Song, Jianull; Liu, Yibo; Xiang, Kejia; Lin, Sen; Li, Ziwei; Si, Wenjie; Li, Bo; Sheng, Xing; Wang, Dongze; Wei, Xiaoding; Wu, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly compressible and anisotropic lamellar ceramic sponges with superior thermal insulation and acoustic absorption performances", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced ceramic sponge materials with temperature-invariant high compressibility are urgently needed as thermal insulators, energy absorbers, catalyst carriers, and high temperature air filters. However, the application of ceramic sponge materials is severely limited due to their complex preparation process. Here, we present a facile method for large-scale fabrication of highly compressible, temperature resistant SiO2-Al2O3 composite ceramic sponges by blow spinning and subsequent calcination. We successfully produce anisotropic lamellar ceramic sponges with numerous stacked microfiber layers and density as low as 10mgcm(-3). The anisotropic lamellar ceramic sponges exhibit high compression fatigue resistance, strain-independent zero Poisson's ratio, robust fire resistance, temperature-invariant compression resilience from -196 to 1000 degrees C, and excellent thermal insulation with a thermal conductivity as low as 0.034Wm(-1) K-1. In addition, the lamellar structure also endows the ceramic sponges with excellent sound absorption properties, representing a promising alternative to existing thermal insulation and acoustic absorption materials. Temperature-invariant highly compressible ceramic sponges are attractive for thermal insulators and energy absorbers, but development is limited by complex preparation processes. Here the authors report large-scale fabrication of silica-alumina composite ceramic sponges via blow spinning and calcination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3732, "DOI": "10.1038/s41467-020-17533-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17533-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556361600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, J; Liu, GP; Huang, K; Jin, WQ; Lee, KR; Xu, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Jie; Liu, Gongping; Huang, Kang; Jin, Wanqin; Lee, Kueir-Rarn; Xu, nullping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Membranes with Fast and Selective Gas-Transport Channels of Laminar Graphene Oxide for Efficient CO2 Capture", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene oxide (GO) nullosheets were engineered to be assembled into laminar structures having fast and selective transport channels for gas separation. With molecular-sieving interlayer spaces and straight diffusion pathways, the GO laminates endowed as-prepared membranes with excellent preferential CO2 permeation performance (CO2 permeability: 100Barrer, CO2/N-2 selectivity: 91) and extraordinary operational stability (>6000min), which are attractive for implementation of practical CO2 capture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2015, "Volume": 54, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 578, "End Page": 582, "Article Number": null, "DOI": "10.1002/anie.201409563", "DOI Link": "http://dx.doi.org/10.1002/anie.201409563", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347238800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, Y; Tan, PC; Shi, BJ; Ouyang, H; Jiang, DJ; Liu, Z; Li, H; Yu, M; Wang, C; Qu, XC; Zhao, LM; Fan, YB; Wang, ZL; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Yang; Tan, Puchuan; Shi, Bojing; Ouyang, Han; Jiang, Dongjie; Liu, Zhuo; Li, Hu; Yu, Min; Wang, Chan; Qu, Xuecheng; Zhao, Luming; Fan, Yubo; Wang, Zhong Lin; Li, Zhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A bionic stretchable nullogenerator for underwater sensing and energy harvesting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft wearable electronics for underwater applications are of interest, but depend on the development of a waterproof, long-term sustainable power source. In this work, we report a bionic stretchable nullogenerator for underwater energy harvesting that mimics the structure of ion channels on the cytomembrane of electrocyte in an electric eel. Combining the effects of triboelectrification caused by flowing liquid and principles of electrostatic induction, the bionic stretchable nullogenerator can harvest mechanical energy from human motion underwater and output an open-circuit voltage over 10 V. Underwater applications of a bionic stretchable nullogenerator have also been demonstrated, such as human body multi-position motion monitoring and an undersea rescue system. The advantages of excellent flexibility, stretchability, outstanding tensile fatigue resistance (over 50,000 times) and underwater performance make the bionic stretchable nullogenerator a promising sustainable power source for the soft wearable electronics used underwater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2695, "DOI": "10.1038/s41467-019-10433-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10433-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472032300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, PP; Dai, Q; Gao, HP; Liu, HD; Zhang, MH; Li, MQ; Chen, Y; An, K; Meng, YS; Liu, P; Li, YR; Spangenberger, JS; Gaines, L; Lu, J; Chen, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Panpan; Dai, Qiang; Gao, Hongpeng; Liu, Haodong; Zhang, Minghao; Li, Mingqian; Chen, Yan; An, Ke; Meng, Ying Shirley; Liu, Ping; Li, Yanran; Spangenberger, Jeffrey S.; Gaines, Linda; Lu, Jun; Chen, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Direct Recycling of Lithium-Ion Battery Cathodes by Targeted Healing", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recycling of spent lithium-ion batteries (LIBs) is an urgent need to address their environmental and global sustainability issues. Here, we report an efficient and environmentally benign LIB regeneration method based on defect- targeted healing, which represents a paradigm-shift LIB recycling strategy. Specifically, by combining lowtemperature aqueous solution relithiation and rapid post-annealing, we demonstrate successful direct regeneration of spent LiFePO4 (LFP) cathodes, one of the most important materials for EVs and grid storage applications. We show revitalization of composition, structure, and electrochemical performance of LFP with various degradation conditions to the same levels as the pristine LFP. Life-cycle analysis of different LIB recycling processes shows that this defect-targeted direct reycling approach can significantly reduce energy usage and greenhouse gas (GHG) emissions, leading to more economic and environmental benefits compared with today's hydrometallurgical and pyrometallurgical methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 438, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2020, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2609, "End Page": 2626, "Article Number": null, "DOI": "10.1016/j.joule.2020.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599924800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Zhen, X; Wang, B; Gao, XM; Ren, ZC; Wang, JQ; Xie, YJ; Li, JR; Peng, Q; Pu, KY; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jie; Zhen, Xu; Wang, Bin; Gao, Xuming; Ren, Zichun; Wang, Jiaqiang; Xie, Yujun; Li, Jianrong; Peng, Qian; Pu, Kanyi; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The influence of the molecular packing on the room temperature phosphorescence of purely organic luminogens", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic luminogens with persistent room temperature phosphorescence (RTP) have attracted great attention for their wide applications in optoelectronic devices and bioimaging. However, these materials are still very scarce, partially due to the unclear mechanism and lack of designing guidelines. Herein we develop seven 10-phenyl-10H-phenothiazine-5,5dioxide- based derivatives, reveal their different RTP properties and underlying mechanism, and exploit their potential imaging applications. Coupled with the preliminary theoretical calculations, it is found that strong pi-pi interactions in solid state can promote the persistent RTP. Particularly, CS-CF3 shows the unique photo-induced phosphorescence in response to the changes in molecular packing, further confirming the key influence of the molecular packing on the RTP property. Furthermore, CS-F with its long RTP lifetime could be utilized for real-time excitation-free phosphorescent imaging in living mice. Thus, our study paves the way for the development of persistent RTP materials, in both the practical applications and the inherent mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 810, "Times Cited, All Databases": 832, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 840, "DOI": "10.1038/s41467-018-03236-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03236-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426049300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LM; Chen, ZJ; Wang, JJ; Zhang, DL; Zhu, YH; Ling, SL; Huang, KW; Belmabkhout, Y; Adil, K; Zhang, YX; Slater, B; Eddaoudi, M; Han, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Lingmei; Chen, Zhijie; Wang, Jianjian; Zhang, Daliang; Zhu, Yihan; Ling, Sanliang; Huang, Kuo-Wei; Belmabkhout, Youssef; Adil, Karim; Zhang, Yuxin; Slater, Ben; Eddaoudi, Mohamed; Han, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imaging defects and their evolution in a metal-organic framework at sub-unit-cell resolution", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defect engineering of metal-organic frameworks (MOFs) offers promising opportunities for tailoring their properties to specific functions and applications. However, determining the structures of defects in MOFs-either point defects or extended ones-has proved challenging owing to the difficulty of directly probing local structures in these typically fragile crystals. Here we report the real-space observation, with sub-unit-cell resolution, of structural defects in the catalytic MOF UiO-66 using a combination of low-dose transmission electron microscopy and electron crystallography. Ordered 'missing linker' and 'missing cluster' defects were found to coexist. The missing-linker defects, reconstructed three-dimensionally with high precision, were attributed to terminating formate groups. The crystallization of the MOF was found to undergo an Ostwald ripening process, during which the defects also evolve: on prolonged crystallization, only the missing-linker defects remained. These observations were rationalized through density functional theory calculations. Finally, the missing-cluster defects were shown to be more catalytically active than their missing-linker counterparts for the isomerization of glucose to fructose.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 622, "End Page": 628, "Article Number": null, "DOI": "10.1038/s41557-019-0263-4", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0263-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472546800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, DN; Deng, SB; Zhao, TN; Wang, B; Wang, YJ; Huang, J; Yu, G; Winglee, J; Wiesner, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Danna; Deng, Shubo; Zhao, Tianning; Wang, Bin; Wang, Yujue; Huang, Jun; Yu, Gang; Winglee, Judy; Wiesner, Mark R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of ultrafine magnetic biochar and activated carbon for pharmaceutical adsorption and subsequent degradation by ball milling", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ball milling was used to prepare two ultrafine magnetic biochar/Fe3O4 and activated carbon (AC)/Fe3O4 hybrid materials targeted for use in pharmaceutical removal by adsorption and mechanochemical degradation of pharmaceutical compounds. Both hybrid adsorbents prepared after 2 h milling exhibited high removal of carbamazepine (CBZ), and were easily separated magnetically. These adsorbents exhibited fast adsorption of CBZ and tetracycline (TC) in the initial 1 h. The biochar/Fe3O4 had a maximum adsorption capacity of 62.7 mg/g for CBZ and 94.2 mg/g for TC, while values obtained for AC/Fe3O4 were 135.1 mg/g for CBZ and 45.3 mg/g for TC respectively when data were fitted using the Langmuir expression. Solution pH values slightly affected the sorption of TC on the adsorbents, while CBZ sorption was almost pH-independent. The spent adsorbents with adsorbed CBZ and TC were milled to degrade the adsorbed pollutants. The adsorbed TC itself was over 97% degraded after 3 h of milling, while about half of adsorbed CBZ were remained. The addition of quartz sand was found to improve the mechanochemical degradation of CBZ on biochar/Fe3O4, and its degradation percent was up to 98.4% at the dose of 0.3 g quarts sand/g adsorbent. This research provided an easy method to prepare ultrafine magnetic adsorbents for the effective removal of typical pharmaceuticals from water or wastewater and degrade them using ball milling. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2016, "Volume": 305, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": 163, "Article Number": null, "DOI": "10.1016/j.jhazmat.2015.11.047", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2015.11.047", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369451400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Häussler, M; Eck, M; Rothauer, D; Mecking, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Haeussler, Manuel; Eck, Marcel; Rothauer, Dario; Mecking, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Closed-loop recycling of polyethylene-like materials", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics are key components of almost any technology today. Although their production consumes substantial feedstock resources, plastics are largely disposed of after their service life. In terms of a circular economy(1-8), reuse of post-consumer sorted polymers ('mechanical recycling') is hampered by deterioration of materials performance(9,10). Chemical recycling(1,11) via depolymerization to monomer offers an alternative that retains high-performance properties. The linear hydrocarbon chains of polyethylene(12) enable crystalline packing and provide excellent materials properties(13). Their inert nature hinders chemical recycling, however, necessitating temperatures above 600 degrees Celsius and recovering ethylene with a yield of less than 10 per cent(3,11,14). Here we show that renewable polycarbonates and polyesters with a low density of in-chain functional groups as break points in a polyethylene chain can be recycled chemically by solvolysis with a recovery rate of more than 96 per cent. At the same time, the break points do not disturb the crystalline polyethylene structure, and the desirable materials properties (like those of high-density polyethylene) are fully retained upon recycling. Processing can be performed by common injection moulding and the materials are well-suited for additive manufacturing, such as 3D printing. Selective removal from model polymer waste streams is possible. In our approach, the initial polymers result from polycondensation of long-chain building blocks, derived by state-of-the-art catalytic schemes from common plant oil feedstocks, or microalgae oils(15). This allows closed-loop recycling of polyethylene-like materials. Polycarbonates and polyesters with materials properties like those of high-density polyethylene can be recycled chemically by depolymerization to their constituent monomers, re-polymerization yielding material with uncompromised processing and materials properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2021, "Volume": 590, "Issue": 7846, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-020-03149-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-03149-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683860300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, JJ; Yang, HB; Huang, X; Hung, SF; Cai, WZ; Jia, CM; Miao, S; Chen, HM; Yang, XF; Huang, YQ; Zhang, T; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Jiajian; Yang, Hong Bin; Huang, Xiang; Hung, Sung-Fu; Cai, Weizheng; Jia, Chunmiao; Miao, Shu; Chen, Hao Ming; Yang, Xiaofeng; Huang, Yanqiang; Zhang, Tao; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling Direct H2O2 Production in Acidic Media through Rational Design of Transition Metal Single Atom Catalyst", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical oxygen reduction reaction in acidic media offers an attractive route for direct hydrogen peroxide (H2O2) generation and on-site applications, Unfortunately there is still a lack of cost-effective electrocatalysts with high catalytic performance. Here, we theoretically designed and experimentally demonstrated that a cobalt single-atom catalyst (Co SAC) anchored in nitrogen-doped graphene, with optimized adsorption energy of the *OOH intermediate, exhibited a high H2O2 production rate, which even slightly outperformed the state-of-the-art noble-metal-based electrocatalysts. The kinetic current of H2O2 production over Co SAC could reach 1 mA/cm(disk)(2) at 0.6 V versus reversible hydrogen electrode in 0.1 M HClO4 with H2O2 faraday efficiency > 90%, and these performance measures could be sustained for 10 h without decay. Further kinetic analysis and operando X-ray absorption study combined with density functional theory (DFT) calculation demonstrated that the nitrogen-coordinated single Co atom was the active site and the reaction was rate-limited by the first electron transfer step.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 562, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 658, "End Page": 674, "Article Number": null, "DOI": "10.1016/j.chempr.2019.12.008", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.12.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519997200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PT; Zhang, X; Zhang, J; Wan, S; Guo, SJ; Lu, G; Yao, JL; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengtang; Zhang, Xu; Zhang, Jin; Wan, Sheng; Guo, Shaojun; Lu, Gang; Yao, Jianlin; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precise tuning in platinum-nickel/ nickel sulfide interface nullowires for synergistic hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Comprising abundant interfaces, multicomponent heterostructures can integrate distinct building blocks into single entities and yield exceptional functionalities enabled by the synergistic components. Here we report an efficient approach to construct one-dimensional metal/sulfide heterostructures by directly sulfuring highly composition-segregated platinum-nickel nullowires. The heterostructures possess a high density of interfaces between platinum- nickel and nickel sulfide components, which cooperate synergistically towards alkaline hydrogen evolution reaction. The platinum-nickel/nickel sulfide heterostructures can deliver a current density of 37.2mAcm (-2) at an overpotential of 70mV, which is 9.7 times higher than that of commercial Pt/C. The heterostructures also offer enhanced stability revealed by long-term chronopotentiometry measurements. The present work highlights a potentially powerful interface-engineering strategy for designing multicomponent heterostructures with advanced performance in hydrogen evolution reaction and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 752, "Times Cited, All Databases": 764, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14580, "DOI": "10.1038/ncomms14580", "DOI Link": "http://dx.doi.org/10.1038/ncomms14580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394796600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Jiang, P; Chen, L; Yuan, FP; Zhu, YTT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, XiaoLei; Jiang, Ping; Chen, Liu; Yuan, Fuping; Zhu, Yuntian T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinary strain hardening by gradient structure", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "tGradient structures have evolved over millions of years through natural selection and optimization in many biological systems such as bones and plant stems, where the structures change gradually from the surface to interior. The advantage of gradient structures is their maximization of physical and mechanical performance while minimizing material cost. Here we report that the gradient structure in engineering materials such as metals renders a unique extra strain hardening, which leads to high ductility. The grain-size gradient under uniaxial tension induces a macroscopic strain gradient and converts the applied uniaxial stress to multiaxial stresses due to the evolution of incompatible deformation along the gradient depth. Thereby the accumulation and interaction of dislocations are promoted, resulting in an extra strain hardening and an obvious strain hardening rate up-turn. Such extraordinary strain hardening, which is inherent to gradient structures and does not exist in homogeneous materials, provides a hitherto unknown strategy to develop strong and ductile materials by architecting heterogeneous nullostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1066, "Times Cited, All Databases": 1140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2014, "Volume": 111, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7197, "End Page": 7201, "Article Number": null, "DOI": "10.1073/pnas.1324069111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1324069111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336168100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grande, L; Paillard, E; Hassoun, J; Park, JB; Lee, YJ; Sun, YK; Passerini, S; Scrosati, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grande, Lorenzo; Paillard, Elie; Hassoun, Jusef; Park, Jin-Bum; Lee, Yung-Jung; Sun, Yang-Kook; Passerini, Stefano; Scrosati, Bruno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Lithium/Air Battery: Still an Emerging System or a Practical Reality?", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium/air is a fascinating energy storage system. The effective exploitation of air as a battery electrode has been the long-time dream of the battery community. Air is, in principle, a no-cost material characterized by a very high specific capacity value. In the particular case of the lithium/air system, energy levels approaching that of gasoline have been postulated. It is then not surprising that, in the course of the last decade, great attention has been devoted to this battery by various top academic and industrial laboratories worldwide. This intense investigation, however, has soon highlighted a series of issues that prevent a rapid development of the Li/air electrochemical system. Although several breakthroughs have been achieved recently, the question on whether this battery will have an effective economic and societal impact remains. In this review, a critical evaluation of the progress achieved so far is made, together with an attempt to propose future R&D trends. A forecast on whether Li/air may have a role in the next years' battery technology is also postulated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 535, "Times Cited, All Databases": 582, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2015, "Volume": 27, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 784, "End Page": 800, "Article Number": null, "DOI": "10.1002/adma.201403064", "DOI Link": "http://dx.doi.org/10.1002/adma.201403064", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349226900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, J; Walter, D; Ren, YH; Tebyetekerwa, M; Wu, YL; Duong, T; Lin, QL; Li, JT; Lu, T; Mahmud, MA; Lem, OLC; Zhao, SY; Liu, WZ; Liu, Y; Shen, HP; Li, L; Kremer, F; Nguyen, HT; Choi, DY; Weber, KJ; Catchpole, KR; White, TP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jun; Walter, Daniel; Ren, Yuhao; Tebyetekerwa, Mike; Wu, Yiliang; Duong, The; Lin, Qiaoling; Li, Juntao; Lu, Teng; Mahmud, Md Arafat; Lem, Olivier Lee Cheong; Zhao, Shenyou; Liu, Wenzhu; Liu, Yun; Shen, Heping; Li, Li; Kremer, Felipe; Nguyen, Hieu T.; Choi, Duk-Yong; Weber, Klaus J.; Catchpole, Kylie R.; White, Thomas P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale localized contacts for high fill factors in polymer-passivated perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer passivation layers can improve the open-circuit voltage of perovskite solar cells when inserted at the perovskite-charge transport layer interfaces. Unfortunately, many such layers are poor conductors, leading to a trade-off between passivation quality (voltage) and series resistance (fill factor, FF). Here, we introduce a nullopatterned electron transport layer that overcomes this trade-off by modifying the spatial distribution of the passivation layer to form nulloscale localized charge transport pathways through an otherwise passivated interface, thereby providing both effective passivation and excellent charge extraction. By combining the nullopatterned electron transport layer with a dopant-free hole transport layer, we achieved a certified power conversion efficiency of 21.6% for a 1-square-centimeter cell with FF of 0.839, and demonstrate an encapsulated cell that retains similar to 91.7% of its initial efficiency after 1000 hours of damp heat exposure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2021, "Volume": 371, "Issue": 6527, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 390, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb8687", "DOI Link": "http://dx.doi.org/10.1126/science.abb8687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609884600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, JJ; Wang, JQ; Li, HQ; Wu, Z; Xing, YQ; Chen, YF; Liu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Junjie; Wang, Jianqiao; Li, Huiqin; Wu, Ze; Xing, Youqiang; Chen, Yunfei; Liu, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2/MXene Aerogel with Conformal Heterogeneous Interfaces Tailored by Atomic Layer Deposition for Tunable Microwave Absorption", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the design of electromagnetic (EM) wave absorbing materials, it is still a great challenge to optimize the relationship between the attenuation capability and impedance matching synergistically. Herein, a 3D porous MoS2/MXene hybrid aerogel architecture with conformal heterogeneous interface has been built by atomic layer deposition (ALD) based on specific porous templates to optimize the microwave absorption (MA) performance comprehensively. The original porous structure of pristine Ti3C2Tx aerogel used as templates can be preserved well during ALD fabrication, which prolongs the reflection and scattering path and ameliorates the dielectric loss. Meanwhile, plenty of heterointerfaces between MoS2 and Ti3C2Tx have been fabricated based on conformally ALD-deposited MoS2 with controlled thickness on the porous surfaces of the templates, which can effectively optimize the impedance matching and transform its response to EM waves from shielding into absorbing. Moreover, the interaction between the attenuation capability and impedance matching can also be modulated by the number of ALD cycle in MoS2 fabrication. After optimization, MoS2/MXene hybrid aerogel obtained under 300 ALD cycles shows a minimum reflection loss of -61.65 dB at the thickness of 4.53 mm. In addition, its preferable lightweight, high surface area, mechanical, and hydrophobicity properties will also be conducive to further practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101988, "DOI": "10.1002/advs.202101988", "DOI Link": "http://dx.doi.org/10.1002/advs.202101988", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745850400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, B; Zhang, Q; Liu, H; Xu, B; Zhang, SL; Zhou, TF; Mao, JF; Pang, WK; Guo, ZP; Li, A; Zhou, JS; Chen, XH; Song, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Bin; Zhang, Qing; Liu, Huan; Xu, Bin; Zhang, Shilin; Zhou, Tengfei; Mao, Jianfeng; Pang, Wei Kong; Guo, Zaiping; Li, Ang; Zhou, Jisheng; Chen, Xiaohong; Song, Huaihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphitic Carbon nullocage as a Stable and High Power Anode for Potassium-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As an emerging electrochemical energy storage device, potassium-ion batteries (PIBs) have drawn growing interest due to the resource-abundance and low cost of potassium. Graphite-based materials, as the most common anodes for commercial Li-ion batteries, have a very low capacity when used an anode for Na-ion batteries, but they show reasonable capacities as anodes for PIBs. The practical application of graphitic materials in PIBs suffers from poor cyclability, however, due to the large interlayer expansion/shrinkage caused by the intercalation/deintercalation of potassium ions. Here, a highly graphitic carbon nullocage (CNC) is reported as a PIBs anode, which exhibits excellent cyclability and superior depotassiation capacity of 175 mAh g(-1) at 35 C. The potassium storage mechanism in CNC is revealed by cyclic voltammetry as due to redox reactions (intercalation/deintercalation) and double-layer capacitance (surface adsorption/desorption). The present results give new insights into structural design for graphitic anode materials in PIBs and understanding the double-layer capacitance effect in alkali metal ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2018, "Volume": 8, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801149, "DOI": "10.1002/aenm.201801149", "DOI Link": "http://dx.doi.org/10.1002/aenm.201801149", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443674100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Deng, HC; Sha, XB; Chen, WJ; Wang, RZ; Chen, YH; Wu, D; Chu, JR; Kivshar, YS; Xiao, SM; Qiu, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yang; Deng, Huachun; Sha, Xinbo; Chen, Weijin; Wang, Ruize; Chen, Yu-Hang; Wu, Dong; Chu, Jiaru; Kivshar, Yuri S. S.; Xiao, Shumin; Qiu, Cheng-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of intrinsic chiral bound states in the continuum", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photons with spin angular momentum possess intrinsic chirality, which underpins many phenomena including nonlinear optics(1), quantum optics(2), topological photonics(3) and chiroptics(4). Intrinsic chirality is weak in natural materials, and recent theoretical proposals(5-7) aimed to enlarge circular dichroism by resonullt metasurfaces supporting bound states in the continuum that enhance substantially chiral light-matter interactions. Those insightful works resort to three-dimensional sophisticated geometries, which are too challenging to be realized for optical frequencies(8). Therefore, most of the experimental attempts(9-11) showing strong circular dichroism rely on false/extrinsic chirality by using either oblique incidence(9,10) or structural anisotropy(11). Here we report on the experimental realization of true/intrinsic chiral response with resonullt metasurfaces in which the engineered slant geometry breaks both in-plane and out-of-plane symmetries. Our result marks, to our knowledge, the first observation of intrinsic chiral bound states in the continuum with near-unity circular dichroism of 0.93 and a high quality factor exceeding 2,663 for visible frequencies. Our chiral metasurfaces may lead to a plethora of applications in chiral light sources and detectors, chiral sensing, valleytronics and asymmetric photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 613, "Issue": 7944, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 474, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05467-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05467-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955590300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, K; Chen, H; Ji, YF; Huang, H; Claesson, PM; Daniel, Q; Philippe, B; Rensmo, H; Li, FS; Luo, Y; Sun, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Ke; Chen, Hong; Ji, Yongfei; Huang, Hui; Claesson, Per Martin; Daniel, Quentin; Philippe, Bertrand; Rensmo, Hakan; Li, Fusheng; Luo, Yi; Sun, Licheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel-vanadium monolayer double hydroxide for efficient electrochemical water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active and low-cost electrocatalysts for water oxidation are required due to the demands on sustainable solar fuels; however, developing highly efficient catalysts to meet industrial requirements remains a challenge. Herein, we report a monolayer of nickel-vanadium-layered double hydroxide that shows a current density of 27 mA cm(-2) (57 mA cm(-2) after ohmic-drop correction) at an overpotential of 350 mV for water oxidation. Such performance is comparable to those of the best-performing nickel-iron-layered double hydroxides for water oxidation in alkaline media. Mechanistic studies indicate that the nickel-vanadium-layered double hydroxides can provide high intrinsic catalytic activity, mainly due to enhanced conductivity, facile electron transfer and abundant active sites. This work may expand the scope of cost-effective electrocatalysts for water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 900, "Times Cited, All Databases": 925, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11981, "DOI": "10.1038/ncomms11981", "DOI Link": "http://dx.doi.org/10.1038/ncomms11981", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378815100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dagdeviren, C; Su, YW; Joe, P; Yona, R; Liu, YH; Kim, YS; Huang, YA; Damadoran, AR; Xia, J; Martin, LW; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dagdeviren, Canull; Su, Yewang; Joe, Pauline; Yona, Raissa; Liu, Yuhao; Kim, Yun-Soung; Huang, YongAn; Damadoran, Anoop R.; Xia, Jing; Martin, Lane W.; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformable amplified lead zirconate titanate sensors with enhanced piezoelectric response for cutaneous pressure monitoring", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to measure subtle changes in arterial pressure using devices mounted on the skin can be valuable for monitoring vital signs in emergency care, detecting the early onset of cardiovascular disease and continuously assessing health status. Conventional technologies are well suited for use in traditional clinical settings, but cannot be easily adapted for sustained use during daily activities. Here we introduce a conformal device that avoids these limitations. Ultrathin inorganic piezoelectric and semiconductor materials on elastomer substrates enable amplified, low hysteresis measurements of pressure on the skin, with high levels of sensitivity (similar to 0.005 Pa) and fast response times (similar to 0.1 ms). Experimental and theoretical studies reveal enhanced piezoelectric responses in lead zirconate titanate that follow from integration on soft supports as well as engineering behaviours of the associated devices. Calibrated measurements of pressure variations of blood flow in near-surface arteries demonstrate capabilities for measuring radial artery augmentation index and pulse pressure velocity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 790, "Times Cited, All Databases": 866, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4496, "DOI": "10.1038/ncomms5496", "DOI Link": "http://dx.doi.org/10.1038/ncomms5496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341039800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eames, C; Islam, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eames, Christopher; Islam, M. Saiful", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion Intercalation into Two-Dimensional Transition-Metal Carbides: Global Screening for New High-Capacity Battery Materials", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal carbides (termed MXenes) are a new family of compounds generating considerable interest due to their unique properties and potential applications. Intercalation of ions into MXenes has recently been demonstrated with good electro-chemical performance, making them viable electrode materials for rechargeable batteries. Here we have performed global screening of the capacity and voltage for a variety of intercalation ions (Li+, Na+, K+, and Mg2+) into a large number of M2C-based compounds (M = Sc, Ti, V, Cr, Zr, Nb, Mo, Hf, Ta) with F-, H-, O-, and OH-functionalized surfaces using density functional theory methods. In terms of gravimetric capacity a greater amount of Lit or Mg2+ can be intercalated into an MXene than Na+ or Kt, which is related to the size of the intercalating ion. Variation of the surface functional group and transition metal species can significantly affect the voltage and capacity of an MXene, with oxygen termination leading to the highest capacity. The most promising group of M2C materials in terms of anode voltage and gravimetric capacity (>400 mAh/g) are compounds containing light transition metals (e.g., Sc, Ti, V, and Cr) with nonfunctionalized or O-terminated surfaces. The results presented here provide valuable insights into exploring a rich variety of high-capacity MXenes for potential battery applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2014, "Volume": 136, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16270, "End Page": 16276, "Article Number": null, "DOI": "10.1021/ja508154e", "DOI Link": "http://dx.doi.org/10.1021/ja508154e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345308700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CX; Chen, CH; Dong, HX; Shen, JR; Dau, H; Zhao, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chunxi; Chen, Changhui; Dong, Hongxing; Shen, Jian-Ren; Dau, Holger; Zhao, Jingquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photosynthetic splitting of water into oxygen by plants, algae, and cyanobacteria is catalyzed by the oxygen-evolving center (OEC). Synthetic mimics of the OEC, which is composed of an asymmetric manganese-calcium-oxygen cluster bound to protein groups, may promote insight into the structural and chemical determinullts of biological water oxidation and lead to development of superior catalysts for artificial photosynthesis. We synthesized a Mn4Ca-cluster similar to the native OEC in both the metal-oxygen core and the binding protein groups. Like the native OEC, the synthetic cluster can undergo four redox transitions and shows two magnetic resonullce signals assignable to redox and structural isomerism. Comparison with previously synthesized Mn3CaO4-cubane clusters suggests that the fourth Mn ion determines redox potentials and magnetic properties of the native OEC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2015, "Volume": 348, "Issue": 6235, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 693, "Article Number": null, "DOI": "10.1126/science.aaa6550", "DOI Link": "http://dx.doi.org/10.1126/science.aaa6550", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354045700045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, Y; Bladt, E; Aygüler, MF; Manzi, A; Milowska, KZ; Hintermayr, VA; Docampo, P; Bals, S; Urban, AS; Polavarapu, L; Feldmann, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Yu; Bladt, Eva; Aygueler, Meltem F.; Manzi, Aurora; Milowska, Karolina Z.; Hintermayr, Verena A.; Docampo, Pablo; Bals, Sara; Urban, Alexander S.; Polavarapu, Lakshminarayana; Feldmann, Jochen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Luminescent Cesium Lead Halide Perovskite nullocrystals with Tunable Composition and Thickness by Ultrasonication", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We describe the simple, scalable, single-step, and polar-solvent-free synthesis of high-quality colloidal CsPbX3 (X=Cl, Br, and I) perovskite nullocrystals (NCs) with tunable halide ion composition and thickness by direct ultrasonication of the corresponding precursor solutions in the presence of organic capping molecules. High angle annular dark field scanning transmission electron microscopy (HAADF-STEM) revealed the cubic crystal structure and surface termination of the NCs with atomic resolution. The NCs exhibit high photoluminescence quantum yields, narrow emission line widths, and considerable air stability. Furthermore, we investigated the quantum size effects in CsPbBr3 and CsPbI3 nulloplatelets by tuning their thickness down to only three to six monolayers. The high quality of the prepared NCs (CsPbBr3) was confirmed by amplified spontaneous emission with low thresholds. The versatility of this synthesis approach was demonstrated by synthesizing different perovskite NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 660, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2016, "Volume": 55, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13887, "End Page": 13892, "Article Number": null, "DOI": "10.1002/anie.201605909", "DOI Link": "http://dx.doi.org/10.1002/anie.201605909", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387024200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Zhou, GM; Liu, ZB; Ma, XM; Chen, J; Zhang, ZY; Ma, XL; Li, F; Cheng, HM; Ren, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Long; Zhou, Guangmin; Liu, Zhibo; Ma, Xiaomeng; Chen, Jing; Zhang, Zhiyong; Ma, Xiuliang; Li, Feng; Cheng, Hui-Ming; Ren, Wencai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable Clean Exfoliation of High-Quality Few-Layer Black Phosphorus for a Flexible Lithium Ion Battery", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer black phosphorus (BP) nullo-sheets that are clean and of high quality, are efficiently produced by exfoliating bulk BP crystals, which are prepared by a scalable gas-phase catalytic transformation method in water. They are stable enough in water for further processing and applications. As an example, these BP nullo sheets are combined with graphene to give high-performance flexible lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2016, "Volume": 28, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 510, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201503678", "DOI Link": "http://dx.doi.org/10.1002/adma.201503678", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368712900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Shi, BB; Yang, H; Guan, JY; Liang, X; Fan, CY; You, XD; Wang, YA; Zhang, Z; Wu, H; Cheng, T; Zhang, RN; Jiang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoyao; Shi, Benbing; Yang, Hao; Guan, Jingyuan; Liang, Xu; Fan, Chunyang; You, Xinda; Wang, Yanull; Zhang, Zhe; Wu, Hong; Cheng, Tao; Zhang, Runnull; Jiang, Zhongyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assembling covalent organic framework membranes with superior ion exchange capacity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ionic covalent organic framework membranes (iCOFMs) hold great promise in ion conduction-relevant applications because the high content and monodispersed ionic groups could afford superior ion conduction. The key to push the upper limit of ion conductivity is to maximize the ion exchange capacity (IEC). Here, we explore iCOFMs with a superhigh ion exchange capacity of 4.6 mmol g(-1), using a dual-activation interfacial polymerization strategy. Fukui function is employed as a descriptor of monomer reactivity. We use Bronsted acid to activate aldehyde monomers in organic phase and Bronsted base to activate ionic amine monomers in water phase. After the dual-activation, the reaction between aldehyde monomer and amine monomer at the water-organic interface is significantly accelerated, leading to iCOFMs with high crystallinity. The resultant iCOFMs display a prominent proton conductivity up to 0.66 S cm(-1), holding great promise in ion transport and ionic separation applications. Covalent organic framework-based membranes are highly tunable materials with potential use in a variety of applications. Here the authors report a dual-activation interfacial polymerization strategy to prepare ionic covalent organic framework membranes with high ion exchange capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1020, "DOI": "10.1038/s41467-022-28643-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28643-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760426000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XF; Shi, SH; Tang, YL; Wang, GZ; Zhou, MF; Zhao, GQ; Zhou, XC; Lin, SW; Meng, FB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xuefei; Shi, Shaohua; Tang, Yulin; Wang, Guizhen; Zhou, Maofan; Zhao, Guoqing; Zhou, Xuechun; Lin, Shiwei; Meng, Fanbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Growth of NiAl-Layered Double Hydroxide on Graphene toward Excellent Anticorrosive Microwave Absorption Application", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance microwave absorbers with special features are desired to meet the requirements of more complex modern service environments, especially corrosive environments. Therefore, high-efficiency microwave absorbers with corrosion resistance should be developed urgently. Herein, a 3D NiAl-layered double hydroxide/graphene (NiAl-LDH/G) composite synthesized by atomic-layer-deposition-assisted in situ growth is presented as an anticorrosive microwave absorber. The content of NiAl-LDH in the composite is optimized to achieve impedance matching. Furthermore, under the cooperative effects of the interface polarization loss, conduction loss, and 3D porous sandwich-like structure, the optimal NiAl-LDH/G shows excellent microwave absorption performance with a minimum reflection loss of -41.5 dB and a maximum effective absorption bandwidth of 4.4 GHz at a loading of only 7 wt% in epoxy. Remarkably, the encapsulation effect of NiAl-LDH can restrain the galvanic corrosion owing to graphene. The epoxy coating with the NiAl-LDH/G microwave absorber on carbon steel exhibits long-term corrosion resistance, owing to the synergetic effect of the superior impermeability of graphene and the chloridion-capture capacity of the NiAl-LDH. The NiAl-LDH/G composite is a promising anticorrosive microwave absorber, and the findings of this study may motivate the development of functional microwave absorbers that meet the demands of anticorrosive performance of coatings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002658, "DOI": "10.1002/advs.202002658", "DOI Link": "http://dx.doi.org/10.1002/advs.202002658", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605169800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seh, ZW; Yu, JH; Li, WY; Hsu, PC; Wang, HT; Sun, YM; Yao, HB; Zhang, QF; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seh, Zhi Wei; Yu, Jung Ho; Li, Weiyang; Hsu, Po-Chun; Wang, Haotian; Sun, Yongming; Yao, Hongbin; Zhang, Qianfan; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional layered transition metal disulphides for effective encapsulation of high-capacity lithium sulphide cathodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fully lithiated lithium sulphide (Li2S) is currently being explored as a promising cathode material for emerging energy storage applications. Like their sulphur counterparts, Li2S cathodes require effective encapsulation to reduce the dissolution of intermediate lithium polysulphide (Li2Sn, n = 4-8) species into the electrolyte. Here we report, the encapsulation of Li2S cathodes using two-dimensional layered transition metal disulphides that possess a combination of high conductivity and strong binding with Li2S/Li2Sn species. In particular, using titanium disulphide as an encapsulation material, we demonstrate a high specific capacity of 503 mAh g(Li2S)(-1) under high C-rate conditions (4C) as well as high areal capacity of 3.0 mAhcm(-2) under high mass-loading conditions (5.3 mg(Li2S) cm(-2)). This work opens up the new prospect of using transition metal disulphides instead of conventional carbon-based materials for effective encapsulation of high-capacity electrode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 582, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5017, "DOI": "10.1038/ncomms6017", "DOI Link": "http://dx.doi.org/10.1038/ncomms6017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342985900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XR; Zhu, XR; Bo, SW; Chen, C; Qiu, MY; Wei, XX; He, NH; Xie, C; Chen, W; Zheng, JY; Chen, PS; Jiang, SP; Li, YF; Liu, QH; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoran; Zhu, Xiaorong; Bo, Shuowen; Chen, Chen; Qiu, Mengyi; Wei, Xiaoxiao; He, Nihan; Xie, Chao; Chen, Wei; Zheng, Jianyun; Chen, Pinsong; Jiang, San Ping; Li, Yafei; Liu, Qinghua; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying and tailoring C-N coupling site for efficient urea synthesis over diatomic Fe-Ni catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic urea synthesis emerged as the promising alternative of Haber-Bosch process and industrial urea synthetic protocol. Here, we report that a diatomic catalyst with bonded Fe-Ni pairs can significantly improve the efficiency of electrochemical urea synthesis. Compared with isolated diatomic and single-atom catalysts, the bonded Fe-Ni pairs act as the efficient sites for coordinated adsorption and activation of multiple reactants, enhancing the crucial C-N coupling thermodynamically and kinetically. The performance for urea synthesis up to an order of magnitude higher than those of single-atom and isolated diatomic electrocatalysts, a high urea yield rate of 20.2 mmol h(-1) g(-1) with corresponding Faradaic efficiency of 17.8% has been successfully achieved. A total Faradaic efficiency of about 100% for the formation of value-added urea, CO, and NH3 was realized. This work presents an insight into synergistic catalysis towards sustainable urea synthesis via identifying and tailoring the atomic site configurations. The direct electrocatalytic synthesis of urea via C-N coupling is of great significance. The authors report a diatomic catalyst with bonded Fe-Ni pairs to improve the efficiency of electrochemical urea synthesis from nitrate and CO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5337, "DOI": "10.1038/s41467-022-33066-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33066-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000852397300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hellman, F; Hoffmann, A; Tserkovnyak, Y; Beach, GSD; Fullerton, EE; Leighton, C; MacDonald, AH; Ralph, DC; Arena, DA; Dürr, HA; Fischer, P; Grollier, J; Heremans, JP; Jungwirth, T; Kimel, AV; Koopmans, B; Krivorotov, IN; May, SJ; Petford-Long, AK; Rondinelli, JM; Samarth, N; Schuller, IK; Slavin, AN; Stiles, MD; Tchernyshyov, O; Thiaville, A; Zink, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hellman, Frances; Hoffmann, Axel; Tserkovnyak, Yaroslav; Beach, Geoffrey S. D.; Fullerton, Eric E.; Leighton, Chris; MacDonald, Allan H.; Ralph, Daniel C.; Arena, Dario A.; Durr, Hermann A.; Fischer, Peter; Grollier, Julie; Heremans, Joseph P.; Jungwirth, Tomas; Kimel, Alexey V.; Koopmans, Bert; Krivorotov, Ilya N.; May, Steven J.; Petford-Long, Amanda K.; Rondinelli, James M.; Samarth, Nitin; Schuller, Ivan K.; Slavin, Andrei N.; Stiles, Mark D.; Tchernyshyov, Oleg; Thiaville, Andre; Zink, Barry L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface-induced phenomena in magnetism", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article reviews static and dynamic interfacial effects in magnetism, focusing on interfacially driven magnetic effects and phenomena associated with spin-orbit coupling and intrinsic symmetry breaking at interfaces. It provides a historical background and literature survey, but focuses on recent progress, identifying the most exciting new scientific results and pointing to promising future research directions. It starts with an introduction and overview of how basic magnetic properties are affected by interfaces, then turns to a discussion of charge and spin transport through and near interfaces and how these can be used to control the properties of the magnetic layer. Important concepts include spin accumulation, spin currents, spin-transfer torque, and spin pumping. An overview is provided to the current state of knowledge and existing review literature on interfacial effects such as exchange bias, exchange-spring magnets, the spin Hall effect, oxide heterostructures, and topological insulators. The article highlights recent discoveries of interface-induced magnetism and noncollinear spin textures, nonlinear dynamics including spin-transfer torque and magnetization reversal induced by interfaces, and interfacial effects in ultrafast magnetization processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 722, "Times Cited, All Databases": 781, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2017, "Volume": 89, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25006, "DOI": "10.1103/RevModPhys.89.025006", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.89.025006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402675100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, J; Li, HB; Wang, SH; Ding, D; Chen, MS; Liu, C; Tian, ZQ; Novoselov, KS; Ma, C; Deng, DH; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Jiao; Li, Haobo; Wang, Suheng; Ding, Ding; Chen, Mingshu; Liu, Chuan; Tian, Zhongqun; Novoselov, K. S.; Ma, Chao; Deng, Dehui; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiscale structural and electronic control of molybdenum disulfide foam for highly efficient hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen production through water splitting has been considered as a green, pure and high-efficient technique. As an important half-reaction involved, hydrogen evolution reaction is a complex electrochemical process involving liquid-solid-gas three-phase interface behaviour. Therefore, new concepts and strategies of material design are needed to smooth each pivotal step. Here we report a multiscale structural and electronic control of molybdenum disulfide foam to synergistically promote the hydrogen evolution process. The optimized three-dimensional molybdenum disulfide foam with uniform mesopores, vertically aligned two-dimensional layers and cobalt atoms doping demonstrated a high hydrogen evolution activity and stability. In addition, density functional theory calculations indicate that molybdenum disulfide with moderate cobalt doping content possesses the optimal activity. This study demonstrates the validity of multiscale control in molybdenum disulfide via overall consideration of the mass transport, and the accessibility, quantity and capability of active sites towards electrocatalytic hydrogen evolution, which may also be extended to other energy-related processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14430, "DOI": "10.1038/ncomms14430", "DOI Link": "http://dx.doi.org/10.1038/ncomms14430", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399080600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, RT; Ren, ZF; Liang, Y; Zhang, GH; Dittrich, T; Liu, RZ; Liu, Y; Zhao, Y; Pang, S; An, HY; Ni, CW; Zhou, PW; Han, KL; Fan, FT; Li, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ruotian; Ren, Zefeng; Liang, Yu; Zhang, Guanhua; Dittrich, Thomas; Liu, Runze; Liu, Yang; Zhao, Yue; Pang, Shan; An, Hongyu; Ni, Chenwei; Zhou, Panwang; Han, Keli; Fan, Fengtao; Li, Can", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spatiotemporal imaging of charge transfer in photocatalyst particles", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The water-splitting reaction using photocatalyst particles is a promising route for solar fuel production(1-4). Photo-induced charge transfer from a photocatalyst to catalytic surface sites is key in ensuring photocatalytic efficiency(5); however, it is challenging to understand this process, which spans a wide spatiotemporal range from nullometres to micrometres and from femtoseconds to seconds(6-8). Although the steady-state charge distribution on single photocatalyst particles has been mapped by microscopic techniques(9-11), and the charge transfer dynamics in photocatalyst aggregations have been revealed by time-resolved spectroscopy(12,13), spatiotemporally evolving charge transfer processes in single photocatalyst particles cannot be tracked, and their exact mechanism is unknown. Here we perform spatiotemporally resolved surface photovoltage measurements on cuprous oxide photocatalyst particles to map holistic charge transfer processes on the femtosecond to second timescale at the single-particle level. We find that photogenerated electrons are transferred to the catalytic surface quasi-ballistically through inter-facet hot electron transfer on a subpicosecond timescale, whereas photogenerated holes are transferred to a spatially separated surface and stabilized through selective trapping on a microsecond timescale. We demonstrate that these ultrafast-hot-electron-transfer and anisotropic-trapping regimes, which challenge the classical perception of a drift-diffusion model, contribute to the efficient charge separation in photocatalysis and improve photocatalytic performance. We anticipate that our findings will be used to illustrate the universality of other photoelectronic devices and facilitate the rational design of photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2022, "Volume": 610, "Issue": 7931, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 296, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05183-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05183-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867324800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YX; Zhang, Q; Feringa, BL; Tian, H; Qu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yuanxin; Zhang, Qi; Feringa, Ben L.; Tian, He; Qu, Da-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toughening a Self-Healable Supramolecular Polymer by Ionic Cluster-Enhanced Iron-Carboxylate Complexes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supramolecular polymers that can heal themselves automatically usually exhibit weakness in mechanical toughness and stretchability. Here we exploit a toughening strategy for a dynamic dry supramolecular network by introducing ionic cluster-enhanced iron-carboxylate complexes. The resulting dry supramolecular network simultaneous exhibits tough mechanical strength, high stretchability, self-healing ability, and processability at room temperature. The excellent performance of these distinct supramolecular polymers is attributed to the hierarchical existence of four types of dynamic combinations in the high-density dry network, including dynamic covalent disulfide bonds, noncovalent H-bonds, iron-carboxylate complexes and ionic clustering interactions. The extremely facile preparation method of this self-healing polymer offers prospects for high-performance low-cost material among others for coatings and wearable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 59, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5278, "End Page": 5283, "Article Number": null, "DOI": "10.1002/anie.201913893", "DOI Link": "http://dx.doi.org/10.1002/anie.201913893", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515397000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uliana, AA; Bui, NT; Kamcev, J; Taylor, MK; Urban, JJ; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uliana, Adam A.; Bui, Ngoc T.; Kamcev, Jovan; Taylor, Mercedes K.; Urban, Jeffrey J.; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion-capture electrodialysis using multifunctional adsorptive membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Technologies that can efficiently purify nontraditional water sources are needed to meet rising global demand for clean water. Water treatment plants typically require a series of costly separation units to achieve desalination and the removal of toxic trace contaminullts such as heavy metals and boron. We report a series of robust, selective, and tunable adsorptive membranes that feature porous aromatic framework nulloparticles embedded within ion exchange polymers and demonstrate their use in an efficient, one-step separation strategy termed ion-capture electrodialysis. This process uses electrodialysis configurations with adsorptive membranes to simultaneously desalinate complex water sources and capture diverse target solutes with negligible capture of competing ions. Our methods are applicable to the development of efficient and selective multifunctional separations that use adsorptive membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2021, "Volume": 372, "Issue": 6539, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 296, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf5991", "DOI Link": "http://dx.doi.org/10.1126/science.abf5991", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641286700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CR; Wang, AL; Xiao, W; Chao, DL; Zhang, X; Tiep, NH; Chen, S; Kang, JN; Wang, X; Ding, J; Wang, J; Zhang, H; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Changrong; Wang, An-Liang; Xiao, Wen; Chao, Dongliang; Zhang, Xiao; Nguyen Huy Tiep; Chen, Shi; Kang, Jiani; Wang, Xin; Ding, Jun; Wang, John; Zhang, Hua; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Grown Epitaxial Heterojunction Exhibits High-Performance Electrocatalytic Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic performance can be enhanced by engineering a purposely designed nulloheterojunction and fine-tuning the interface electronic structure. Herein a new approach of developing atomic epitaxial in-growth in Co-Ni3N nullowires array is devised, where a nulloconfinement effect is reinforced at the interface. The Co-Ni3N heterostructure array is formed by thermal annealing NiCo2O4 precursor nullowires under an optimized condition, during which the nullowire morphology is retained. The epitaxial in-growth structure of Co-Ni3N at nullometer scale facilitates the electron transfer between the two different domains at the epitaxial interface, leading to a significant enhancement in catalytic activities for both hydrogen and oxygen evolution reactions (10 and 16 times higher in the respective turnover frequency compared to Ni3N-alone nullorods). The interface transfer effect is verified by electronic binding energy shift and density functional theory (DFT) calculations. This nulloconfinement effect occurring during in situ atomic epitaxial in-growth of the two compatible materials shows an effective pathway toward high-performance electrocatalysis and energy storages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2018, "Volume": 30, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705516, "DOI": "10.1002/adma.201705516", "DOI Link": "http://dx.doi.org/10.1002/adma.201705516", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428793600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, CY; Lin, LL; Liu, JJ; Zhang, JP; Zhang, F; Zhou, T; Rui, N; Yao, SY; Deng, YC; Yang, F; Xu, WQ; Luo, J; Zhao, Y; Yan, BH; Wen, XD; Rodriguez, JA; Ma, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Congyi; Lin, Lili; Liu, Jinjia; Zhang, Jingpeng; Zhang, Feng; Zhou, Tong; Rui, Ning; Yao, Siyu; Deng, Yuchen; Yang, Feng; Xu, Wenqian; Luo, Jun; Zhao, Yue; Yan, Binhang; Wen, Xiao-Dong; Rodriguez, Jose A.; Ma, Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverse ZrO2/Cu as a highly efficient methanol synthesis catalyst from CO2 hydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancing the intrinsic activity and space time yield of Cu based heterogeneous methanol synthesis catalysts through CO2 hydrogenation is one of the major topics in CO2 conversion into value-added liquid fuels and chemicals. Here we report inverse ZrO2/Cu catalysts with a tunable Zr/Cu ratio have been prepared via an oxalate co-precipitation method, showing excellent performance for CO2 hydrogenation to methanol. Under optimal condition, the catalyst composed by 10% of ZrO2 supported over 90% of Cu exhibits the highest mass-specific methanol formation rate of 524 g(MeOH)kg(cat)(-1)h(-1) at 220 degrees C, 3.3 times higher than the activity of traditional Cu/ZrO2 catalysts (159 g(MeOH)kg(cat)(-1)h(-1)). In situ XRD-PDF, XAFS and AP-XPS structural studies reveal that the inverse ZrO2/Cu catalysts are composed of islands of partially reduced 1-2nm amorphous ZrO2 supported over metallic Cu particles. The ZrO2 islands are highly active for the CO2 activation. Meanwhile, an intermediate of formate adsorbed on the Cu at 1350cm(-1) is discovered by the in situ DRIFTS. This formate intermediate exhibits fast hydrogenation conversion to methoxy. The activation of CO2 and hydrogenation of all the surface oxygenate intermediates are significantly accelerated over the inverse ZrO2/Cu configuration, accounting for the excellent methanol formation activity observed. Enhancing the intrinsic activity and space time yield of Cu based heterogeneous methanol synthesis catalysts is one of the major topics in CO2 hydrogenation. Here the authors develop a highly active inverse catalyst composed of fine ZrO2 islands dispersed on metallic Cu nulloparticles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5767, "DOI": "10.1038/s41467-020-19634-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19634-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000594648000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, ZK; Zhao, WJ; Lam, JWY; Peng, Q; Ma, HL; Liang, GD; Shuai, ZG; Tang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Zikai; Zhao, Weijun; Lam, Jacky W. Y.; Peng, Qian; Ma, Huili; Liang, Guodong; Shuai, Zhigang; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "White light emission from a single organic molecule with dual phosphorescence at room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of single molecule white light emitters is extremely challenging for pure phosphorescent metal-free system at room temperature. Here we report a single pure organic phosphor, namely 4-chlorobenzoyldibenzothiophene, emitting white room temperature phosphorescence with Commission Internationale de l'Eclair-age coordinates of (0.33, 0.35). Experimental and theoretical investigations reveal that the white light emission is emerged from dual phosphorescence, which emit from the first and second excited triplet states. We also demonstrate the validity of the strategy to achieve metal-free pure phosphorescent single molecule white light emitters by intrasystem mixing dual room temperature phosphorescence arising from the low-and high-lying triplet states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 683, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 416, "DOI": "10.1038/s41467-017-00362-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00362-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409393900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, C; Wang, J; Zhang, XH; Kang, LX; Cao, X; Zhang, YY; Niu, YT; Yu, YY; Fu, HL; Shen, ZJ; Wu, KJ; Yong, ZZ; Zou, JY; Wang, B; Chen, Z; Yang, ZP; Li, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Cao; Wang, Jing; Zhang, Xiaohang; Kang, Lixing; Cao, Xun; Zhang, Yongyi; Niu, Yutao; Yu, Yingying; Fu, Huili; Shen, Zongjie; Wu, Kunjie; Yong, Zhenzhong; Zou, Jingyun; Wang, Bin; Chen, Zhou; Yang, Zhengpeng; Li, Qingwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow Gradient-Structured Iron-Anchored Carbon nullospheres for Enhanced Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present paper, a microwave absorber with nulloscale gradient structure was proposed for enhancing the electromagnetic absorption performance. The inorganic-organic competitive coating strategy was employed, which can effectively adjust the thermodynamic and kinetic reactions of iron ions during the solvothermal process. As a result, Fe nulloparticles can be gradually decreased from the inner side to the surface across the hollow carbon shell. The results reveal that it offers an outstanding reflection loss value in combination with broadband wave absorption and flexible adjustment ability, which is superior to other relative graded distribution structures and satisfied with the requirements of lightweight equipment. In addition, this work elucidates the intrinsic microwave regulation mechanism of the multiscale hybrid electromagnetic wave absorber. The excellent impedance matching and moderate dielectric parameters are exhibited to be the dominative factors for the promotion of microwave absorption performance of the optimized materials. This strategy to prepare gradient-distributed microwave absorbing materials initiates a new way for designing and fabricating wave absorber with excellent impedance matching property in practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7, "DOI": "10.1007/s40820-022-00963-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00963-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000893586900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YW; Tang, QC; Zhang, Y; Wang, JB; Stimming, U; Lee, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yunwei; Tang, Qiaochu; Zhang, Yao; Wang, Jiabin; Stimming, Ulrich; Lee, Alpha A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying degradation patterns of lithium ion batteries from impedance spectroscopy using machine learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Forecasting the state of health and remaining useful life of Li-ion batteries is an unsolved challenge that limits technologies such as consumer electronics and electric vehicles. Here, we build an accurate battery forecasting system by combining electrochemical impedance spectroscopy (EIS)-a real-time, non-invasive and information-rich measurement that is hitherto underused in battery diagnosis-with Gaussian process machine learning. Over 20,000 EIS spectra of commercial Li-ion batteries are collected at different states of health, states of charge and temperatures-the largest dataset to our knowledge of its kind. Our Gaussian process model takes the entire spectrum as input, without further feature engineering, and automatically determines which spectral features predict degradation. Our model accurately predicts the remaining useful life, even without complete knowledge of past operating conditions of the battery. Our results demonstrate the value of EIS signals in battery management systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706, "DOI": "10.1038/s41467-020-15235-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15235-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564279100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Scheiger, JM; Levkin, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Lei; Scheiger, Johannes M.; Levkin, Pavel A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and Applications of Photoresponsive Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are the most relevant biochemical scaffold due to their tunable properties, inherent biocompatibility, and similarity with tissue and cell environments. Over the past decade, hydrogels have developed from static materials to smart responsive materials adapting to various stimuli, such as pH, temperature, chemical, electrical, or light. Light stimulation is particularly interesting for many applications because of the capability of contact-free remote manipulation of biomaterial properties and inherent spatial and temporal control. Moreover, light can be finely adjusted in its intrinsic properties, such as wavelength and intensity (i.e., the energy of an individual photon as well as the number of photons over time). Water is almost transparent for light in the photochemically relevant range (NIR-UV), thus hydrogels are well-suited scaffolds for light-responsive functionality. Hydrogels' chemical and physical variety combined with light responsiveness makes photoresponsive hydrogels ideal candidates for applications in several fields, ranging from biomaterials, medicine to soft robotics. Herein, the progress and new developments in the field of light-responsive hydrogels are elaborated by first introducing the relevant photochemistries before discussing selected applications in detail.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 465, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 31, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1807333, "DOI": "10.1002/adma.201807333", "DOI Link": "http://dx.doi.org/10.1002/adma.201807333", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474604700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LD; Yan, JQ; Wang, T; Zhao, ZJ; Zhang, J; Gong, JL; Guan, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Landong; Yan, Junqing; Wang, Tuo; Zhao, Zhi-Jian; Zhang, Jian; Gong, Jinlong; Guan, Naijia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-10 nm rutile titanium dioxide nulloparticles for efficient visible-light-driven photocatalytic hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Titanium dioxide is a promising photocatalyst for water splitting, but it suffers from low visible light activity due to its wide band gap. Doping can narrow the band gap of titanium dioxide; however, new charge-carrier recombination centres may be introduced. Here we report the design of sub-10 nm rutile titanium dioxide nulloparticles, with an increased amount of surface/sub-surface defects to overcome the negative effects from bulk defects. Abundant defects can not only shift the top of the valence band of rutile titanium dioxide upwards for band-gap narrowing but also promote charge-carrier separation. The role of titanium(III) is to enhance, rather than initiate, the visible-light-driven water splitting. The sub-10nm rutile nulloparticles exhibit the state-of-the-art activity among titanium dioxide-based semiconductors for visible-light-driven water splitting and the concept of ultra-small nulloparticles with abundant defects may be extended to the design of other robust semiconductor photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 707, "Times Cited, All Databases": 732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5881, "DOI": "10.1038/ncomms6881", "DOI Link": "http://dx.doi.org/10.1038/ncomms6881", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348740700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zecevic, J; Vanbutsele, G; de Jong, KP; Martens, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zecevic, Jovana; Vanbutsele, Gina; de Jong, Krijn P.; Martens, Johan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to control nulloscale features precisely is increasingly being exploited to develop and improve monofunctional catalysts(1-4). Striking effects might also be expected in the case of bifunctional catalysts, which are important in the hydrocracking of fossil and renewable hydrocarbon sources to provide high-quality diesel fuel(5-7). Such bifunctional hydrocracking catalysts contain metal sites and acid sites, and for more than 50 years the so-called intimacy criterion(8) has dictated the maximum distance between the two types of site, beyond which catalytic activity decreases. A lack of synthesis and material-characterization methods with nullometre precision has long prevented in-depth exploration of the intimacy criterion, which has often been interpreted simply as 'the closer the better' for positioning metal and acid sites(8-11). Here we show for a bifunctional catalyst-comprising an intimate mixture of zeolite Y and alumina binder, and with platinum metal controllably deposited on either the zeolite or the binder-that closest proximity between metal and zeolite acid sites can be detrimental. Specifically, the selectivity when cracking large hydrocarbon feedstock molecules for high-quality diesel production is optimized with the catalyst that contains platinum on the binder, that is, with a nulloscale rather than closest intimacy of the metal and acid sites. Thus, cracking of the large and complex hydrocarbon molecules that are typically derived from alternative sources, such as gas-to-liquid technology, vegetable oil or algal oil(6,7), should benefit especially from bifunctional catalysts that avoid locating platinum on the zeolite (the traditionally assumed optimal location). More generally, we anticipate that the ability demonstrated here to spatially organize different active sites at the nulloscale will benefit the further development and optimization of the emerging generation of multifunctional catalysts(12-15).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2015, "Volume": 528, "Issue": 7581, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature16173", "DOI Link": "http://dx.doi.org/10.1038/nature16173", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366053300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MC; Guan, KC; Ji, YF; Liu, GP; Jin, WQ; Xu, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mengchen; Guan, Kecheng; Ji, Yufan; Liu, Gongping; Jin, Wanqin; Xu, nullping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controllable ion transport by surface-charged graphene oxide membrane", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ion transport is crucial for biological systems and membrane-based technology. Atomic-thick two-dimensional materials, especially graphene oxide (GO), have emerged as ideal building blocks for developing synthetic membranes for ion transport. However, the exclusion of small ions in a pressured filtration process remains a challenge for GO membranes. Here we report manipulation of membrane surface charge to control ion transport through GO membranes. The highly charged GO membrane surface repels high-valent co-ions owing to its high interaction energy barrier while concomitantly restraining permeation of electrostatically attracted low-valent counter-ions based on balancing overall solution charge. The deliberately regulated surface-charged GO membranes demonstrate remarkable enhancement of ion rejection with intrinsically high water permeance that exceeds the performance limits of state-of-the-art nullofiltration membranes. This facile and scalable surface charge control approach opens opportunities in selective ion transport for the fields of water transport, biomimetic ion channels and biosensors, ion batteries and energy conversions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 475, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1253, "DOI": "10.1038/s41467-019-09286-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09286-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461557200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, F; Markus, IM; Nordlund, D; Weng, TC; Asta, MD; Xin, HLL; Doeff, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Feng; Markus, Isaac M.; Nordlund, Dennis; Weng, Tsu-Chien; Asta, Mark D.; Xin, Huolin L.; Doeff, Marca M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present study sheds light on the long-standing challenges associated with high-voltage operation of LiNixMnxCo1-2xO2 cathode materials for lithium-ion batteries. Using correlated ensemble-averaged high-throughput X-ray absorption spectroscopy and spatially resolved electron microscopy and spectroscopy, here we report structural reconstruction (formation of a surface reduced layer, R (3) over barm to Fm (3) over barm transition) and chemical evolution (formation of a surface reaction layer) at the surface of LiNixMnxCo1-2xO2 particles. These are primarily responsible for the prevailing capacity fading and impedance buildup under high-voltage cycling conditions, as well as the first-cycle coulombic inefficiency. It was found that the surface reconstruction exhibits a strong anisotropic characteristic, which predominulltly occurs along lithium diffusion channels. Furthermore, the surface reaction layer is composed of lithium fluoride embedded in a complex organic matrix. This work sets a refined example for the study of surface reconstruction and chemical evolution in battery materials using combined diagnostic tools at complementary length scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1247, "Times Cited, All Databases": 1338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3529, "DOI": "10.1038/ncomms4529", "DOI Link": "http://dx.doi.org/10.1038/ncomms4529", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334302800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YT; Ameyama, K; Anderson, PM; Beyerlein, IJ; Gao, HJ; Kim, HS; Lavernia, E; Mathaudhu, S; Mughrabi, H; Ritchie, RO; Tsuji, N; Zhang, XY; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yuntian; Ameyama, Kei; Anderson, Peter M.; Beyerlein, Irene J.; Gao, Huajian; Kim, Hyoung Seop; Lavernia, Enrique; Mathaudhu, Suveen; Mughrabi, Hael; Ritchie, Robert O.; Tsuji, Nobuhiro; Zhang, Xiangyi; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterostructured materials: superior properties from hetero-zone interaction", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterostructured materials are an emerging class of materials with superior performances that are unattainable by their conventional homogeneous counterparts. They consist of heterogeneous zones with dramatic (>100%) variations in mechanical and/or physical properties. The interaction in these hetero-zones produces a synergistic effect where the integrated property exceeds the prediction by the rule-of-mixtures. The heterostructured materials field explores heterostructures to control defect distributions, long-range internal stresses, and nonlinear inter-zone interactions for unprecedented performances. This paper is aimed to provide perspectives on this novel field, describe the state-of-the-art of heterostructured materials, and identify and discuss key issues that deserve additional studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 635, "Times Cited, All Databases": 646, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2021, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 31, "Article Number": null, "DOI": "10.1080/21663831.2020.1796836", "DOI Link": "http://dx.doi.org/10.1080/21663831.2020.1796836", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000576627300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZR; Joshi, S; Savel'ev, S; Song, WH; Midya, R; Li, YN; Rao, MY; Yan, P; Asapu, S; Zhuo, Y; Jiang, H; Lin, P; Li, C; Yoon, JH; Upadhyay, NK; Zhang, JM; Hu, M; Strachan, JP; Barnell, M; Wu, Q; Wu, HQ; Williams, RS; Xia, QF; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhongrui; Joshi, Saumil; Savel'ev, Sergey; Song, Wenhao; Midya, Rivu; Li, Yunning; Rao, Mingyi; Yan, Peng; Asapu, Shiva; Zhuo, Ye; Jiang, Hao; Lin, Peng; Li, Can; Yoon, Jung Ho; Upadhyay, Navnidhi K.; Zhang, Jiaming; Hu, Miao; Strachan, John Paul; Barnell, Mark; Wu, Qing; Wu, Huaqiang; Williams, R. Stanley; Xia, Qiangfei; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully memristive neural networks for pattern classification with unsupervised learning", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neuromorphic computers consisting of artificial neurons and synapses could provide a more efficient approach to implementing neural network algorithms than traditional hardware. Recently, artificial neurons based on memristors have been developed, but with limited bio-realistic dynamics and no direct interaction with the artificial synapses in an integrated network. Here we show that a diffusive memristor based on silver nulloparticles in a dielectric film can be used to create an artificial neuron with stochastic leaky integrate-and-fire dynamics and tunable integration time, which is determined by silver migration alone or its interaction with circuit capacitance. We integrate these neurons with non-volatile memristive synapses to build fully memristive artificial neural networks. With these integrated networks, we experimentally demonstrate unsupervised synaptic weight updating and pattern classification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 609, "Times Cited, All Databases": 639, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 137, "End Page": 145, "Article Number": null, "DOI": "10.1038/s41928-018-0023-2", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0023-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444072900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JM; Chang, WE; Chang, YT; Chang, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jyh Ming; Chang, Wei En; Chang, Yu Ting; Chang, Chih-Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezo-Catalytic Effect on the Enhancement of the Ultra-High Degradation Activity in the Dark by Single- and Few-Layers MoS2 nulloflowers", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single- and few-layer MoS2 nullo flowers are first discovered to have a piezocatalyst effect, exhibiting an ultra-high degradation activity in the dark by introducing external mechanical strains. The degradation ratio of the Rhodamine-B dye solution reaches 93% within 60 s under ultrasonic-wave assistance in the dark.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2016, "Volume": 28, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3718, "End Page": 3725, "Article Number": null, "DOI": "10.1002/adma.201505785", "DOI Link": "http://dx.doi.org/10.1002/adma.201505785", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376480500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, J; Zhang, H; Dong, SH; Liu, YP; Nai, CT; Shin, HS; Jeong, HY; Liu, B; Loh, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jian; Zhang, Han; Dong, Shaohua; Liu, Yanpeng; Nai, Chang Tai; Shin, Hyeon Suk; Jeong, Hu Young; Liu, Bo; Loh, Kian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition-metal dichalcogenides like molybdenum disulphide have attracted great interest as two-dimensional materials beyond graphene due to their unique electronic and optical properties. Solution-phase processes can be a viable method for producing printable single-layer chalcogenides. Molybdenum disulphide can be exfoliated into monolayer flakes using organolithium reduction chemistry; unfortunately, the method is hampered by low yield, submicron flake size and long lithiation time. Here we report a high-yield exfoliation process using lithium, potassium and sodium naphthalenide where an intermediate ternary LixMXn crystalline phase (X = selenium, sulphur, and so on) is produced. Using a two-step expansion and intercalation method, we produce high-quality single-layer molybdenum disulphide sheets with unprecedentedly large flake size, that is up to 400 mu m(2). Single-layer dichalcogenide inks prepared by this method may be directly inkjet-printed on a wide range of substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 690, "Times Cited, All Databases": 768, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2995, "DOI": "10.1038/ncomms3995", "DOI Link": "http://dx.doi.org/10.1038/ncomms3995", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331081200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, J; Yang, Y; Hoffmann, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Jonghun; Yang, Yang; Hoffmann, Michael R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activation of Peroxymonosulfate by Oxygen Vacancies-Enriched Cobalt-Doped Black TiO2 nullotubes for the Removal of Organic Pollutants", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt-mediated activation of peroxymonosulfate (PMS) has been widely investigated for the oxidation of organic pollutants. Herein, we employ cobalt-doped Black TiO2 nullotubes (Co-Black TNT) for the efficient, stable, and reusable activator of PMS for the degradation of organic pollutants. Co-Black TNTs induce the activation of PMS by itself and stabilized oxygen vacancies that enhance the bonding with PMS and provide catalytic active sites for PMS activation. A relatively high electronic conductivity associated with the coexistence of Ti4+ and Ti3+ in Co-Black TNT enables an efficient electron transfer between PMS and the catalyst. As a result, Co-Black TNT is an effective catalyst for PMS activation, leading to the degradation of selected organic pollutants when compared to other TNTs (TNT, Co-TNT, and Black TNT) and other Co-based materials (Co3O4, Co-TiO2, CoFe2O4, and Co3O4/rGO). The observed organic compound degradation kinetics are retarded in the presence of methanol and natural organic matter as sulfate radical scavengers. These results demonstrate that sulfate radical is the primary oxidant generated via PMS activation on Co-Black TNT. The strong interaction between Co and TiO2 through Co-O-Ti bonds and rapid redox cycle of Co2+/Co3+ in Co-Black TNT prevents cobalt leaching and enhances catalyst stability over a wide pH range and repetitive uses of the catalyst. Electrode-supported Co-Black TNT facilitates the recovery of the catalyst from the treated water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2019, "Volume": 53, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6972, "End Page": 6980, "Article Number": null, "DOI": "10.1021/acs.est.9b01449", "DOI Link": "http://dx.doi.org/10.1021/acs.est.9b01449", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472682900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McGuire, MA; Dixit, H; Cooper, VR; Sales, BC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R.; Sales, Brian C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI3", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have examined the crystallographic and magnetic properties of single crystals of CrI3, an easily cleavable, layered and insulating ferromagnet with a Curie temperature of 61 K. Our X-ray diffraction studies reveal a first-order crystallographic phase transition occurring near 210-220 K upon warming, with significant thermal hysteresis. The low-temperature structure is rhombohedral (R (3) over bar, BiI3-type) and the high-temperature structure is monoclinic (C-2/m, AlCl3-type). We find evidence for coupling between the crystallographic and magnetic degrees of freedom in CrI3, observing an anomaly in the interlayer spacing at the Curie temperature and an anomaly in the magnetic susceptibility at the structural transition. First-principles calculations reveal the importance of proper treatment of the long-ranged interlayer forces, and van der Waals density functional theory does an excellent job of predicting the crystal structures and their relative stability. Calculations also suggest that the ferromagnetic order found in the bulk material may persist into monolayer form, suggesting that CrI3 and other chromium trihalides may be promising materials for spintronic and magnetoelectronic research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 780, "Times Cited, All Databases": 841, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2015, "Volume": 27, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 612, "End Page": 620, "Article Number": null, "DOI": "10.1021/cm504242t", "DOI Link": "http://dx.doi.org/10.1021/cm504242t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348618400027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dumcenco, D; Ovchinnikov, D; Marinov, K; Lazic, P; Gibertini, M; Marzari, N; Sanchez, OL; Kung, YC; Krasnozhon, D; Chen, MW; Bertolazzi, S; Gillet, P; Morral, AFI; Radenovic, A; Kis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dumcenco, Dumitru; Ovchinnikov, Dmitry; Marinov, Kolyo; Lazic, Predrag; Gibertini, Marco; Marzari, Nicola; Sanchez, Oriol Lopez; Kung, Yen-Cheng; Krasnozhon, Daria; Chen, Ming-Wei; Bertolazzi, Simone; Gillet, Philippe; Fontcuberta i Morral, Anna; Radenovic, Aleksandra; Kis, Andras", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Area Epitaxial Mono layer MoS2", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional semiconductors such as MoS2 are an emerging material family with wide-ranging potential applications in electronics, optoelectronics, and energy harvesting. Large-area growth methods are needed to open the way to applications. Control over lattice orientation during growth remains a challenge. This is needed to minimize or even avoid the formation of grain boundaries, detrimental to electrical, optical, and mechanical properties of MoS2 and other 2D semiconductors. Here, we report on the growth of high-quality monolayer MoS2 with control over lattice orientation. We show that the monolayer film is composed of coalescing single islands with limited numbers of lattice orientation due to an epitaxial growth mechanism. Optical absorbance spectra acquired over large areas show significant absorbance in the high-energy part of the spectrum, indicating that MoS2 could also be interesting for harvesting this region of the solar spectrum and fabrication of UV-sensitive photodetectors. Even though the interaction between the growth substrate and MoS2 is strong enough to induce lattice alignment via van der Waals interaction, we can easily transfer the grown material and fabricate devices. Local potential mapping along channels in field-effect transistors shows that the single-crystal MoS2 grains in our film are well connected, with interfaces that do not degrade the electrical conductivity. This is also confirmed by the relatively large and length-independent mobility in devices with a channel length reaching 80 mu m.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 751, "Times Cited, All Databases": 817, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4611, "End Page": 4620, "Article Number": null, "DOI": "10.1021/acsnullo.5b01281", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b01281", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353867000130", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, YS; Chou, LY; Liu, YY; Wang, HS; Lee, HK; Huang, WX; Wan, JY; Liu, K; Zhou, GM; Yang, YF; Yang, AK; Xiao, X; Gao, X; Boyle, DT; Chen, H; Zhang, WB; Kim, SC; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Yusheng; Chou, Lien-Yang; Liu, Yayuan; Wang, Hansen; Lee, Hiang Kwee; Huang, Wenxiao; Wan, Jiayu; Liu, Kai; Zhou, Guangmin; Yang, Yufei; Yang, Ankun; Xiao, Xin; Gao, Xin; Boyle, David Thomas; Chen, Hao; Zhang, Wenbo; Kim, Sang Cheol; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight and fire-extinguishing current collectors for high-energy and high-safety lithium-ion batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inactive components and safety hazards are two critical challenges in realizing high-energy lithium-ion batteries. Metal foil current collectors with high density are typically an integrated part of lithium-ion batteries yet deliver no capacity. Meanwhile, high-energy batteries can entail increased fire safety issues. Here we report a composite current collector design that simultaneously minimizes the 'dead weight' within the cell and improves fire safety. An ultralight polyimide-based current collector (9 mu m thick, specific mass 1.54 mg cm(-2)) is prepared by sandwiching a polyimide embedded with triphenyl phosphate flame retardant between two superthin Cu layers (similar to 500 nm). Compared to lithium-ion batteries assembled with the thinnest commercial metal foil current collectors (similar to 6 mu m), batteries equipped with our composite current collectors can realize a 16-26% improvement in specific energy and rapidly self-extinguish fires under extreme conditions such as short circuits and thermal runaway. Batteries need to be energy-dense as well as safe. Yi Cui and team develop an ultralight polyimide-based current collector with embedded fire retardants that enables lithium-ion batteries with much-enhanced safety and energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 786, "End Page": 793, "Article Number": null, "DOI": "10.1038/s41560-020-00702-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-00702-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000578091500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karlsson, M; Yi, ZY; Reichert, S; Luo, XY; Lin, WH; Zhang, ZY; Bao, CX; Zhang, R; Bai, S; Zheng, GHJ; Teng, PP; Duan, L; Lu, Y; Zheng, KB; Pullerits, T; Deibel, C; Xu, WD; Friend, R; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karlsson, Max; Yi, Ziyue; Reichert, Sebastian; Luo, Xiyu; Lin, Weihua; Zhang, Zeyu; Bao, Chunxiong; Zhang, Rui; Bai, Sai; Zheng, Guanhaojie; Teng, Pengpeng; Duan, Lian; Lu, Yue; Zheng, Kaibo; Pullerits, Tonu; Deibel, Carsten; Xu, Weidong; Friend, Richard; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bright and efficient blue emission is key to further development of metal halide perovskite light-emitting diodes. Although modifying bromide/chloride composition is straightforward to achieve blue emission, practical implementation of this strategy has been challenging due to poor colour stability and severe photoluminescence quenching. Both detrimental effects become increasingly prominent in perovskites with the high chloride content needed to produce blue emission. Here, we solve these critical challenges in mixed halide perovskites and demonstrate spectrally stable blue perovskite light-emitting diodes over a wide range of emission wavelengths from 490 to 451 nullometres. The emission colour is directly tuned by modifying the halide composition. Particularly, our blue and deep-blue light-emitting diodes based on three-dimensional perovskites show high EQE values of 11.0% and 5.5% with emission peaks at 477 and 467nm, respectively. These achievements are enabled by a vapour-assisted crystallization technique, which largely mitigates local compositional heterogeneity and ion migration. Achieving bright and efficient blue emission in metal halide perovskite light-emitting diodes has proven to be challenging. Here, the authors demonstrate high EQE and spectrally stable blue light-emitting diodes based on mixed halide perovskites, with emission from 490 to 451nm by using a vapour-assisted crystallization technique.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 361, "DOI": "10.1038/s41467-020-20582-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20582-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609611000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, BT; Fang, JF; Xu, CY; Cao, H; Zhang, RX; Zhao, BA; Huang, MQ; Wang, XY; Lv, HL; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Bintong; Fang, Jiefeng; Xu, Chunyang; Cao, Hui; Zhang, Ruixuan; Zhao, Biao; Huang, Mengqiu; Wang, Xiangyu; Lv, Hualiang; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Dimensional Magnetic FeCoNi Alloy Toward Low-Frequency Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational designing of one-dimensional (1D) magnetic alloy to facilitate electromagnetic (EM) wave attenuation capability in low-frequency (2-6 GHz) microwave absorption field is highly desired but remains a significant challenge. In this study, a composite EM wave absorber made of a FeCoNi medium-entropy alloy embedded in a 1D carbon matrix framework is rationally designed through an improved electrospinning method. The 1D-shaped FeCoNi alloy embedded composite demonstrates the high-density and continuous magnetic network using off-axis electronic holography technique, indicating the excellent magnetic loss ability under an external EM field. Then, the in-depth analysis shows that many factors, including 1D anisotropy and intrinsic physical features of the magnetic medium-entropy alloy, primarily contribute to the enhanced EM wave absorption performance. Therefore, the fabricated EM wave absorber shows an increasing effective absorption band of 1.3 GHz in the low-frequency electromagnetic field at an ultrathin thickness of 2 mm. Thus, this study opens up a new method for the design and preparation of high-performance 1D magnetic EM absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 170, "DOI": "10.1007/s40820-022-00920-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00920-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842159200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZW; Li, YZ; Xu, R; Zhou, WJ; Li, YB; Oyakhire, ST; Wu, YC; Xu, JW; Wang, HS; Yu, ZA; Boyle, DT; Huang, W; Ye, YS; Chen, H; Wan, JY; Bao, ZN; Chiu, W; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zewen; Li, Yuzhang; Xu, Rong; Zhou, Weijiang; Li, Yanbin; Oyakhire, Solomon T.; Wu, Yecun; Xu, Jinwei; Wang, Hansen; Yu, Zhiao; Boyle, David T.; Huang, William; Ye, Yusheng; Chen, Hao; Wan, Jiayu; Bao, Zhenull; Chiu, Wah; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capturing the swelling of solid-electrolyte interphase in lithium metal batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although liquid-solid interfaces are foundational in broad areas of science, characterizing this delicate interface remains inherently difficult because of shortcomings in existing tools to access liquid and solid phases simultaneously at the nulloscale. This leads to substantial gaps in our understanding of the structure and chemistry of key interfaces in battery systems. We adopt and modify a thin film vitrification method to preserve the sensitive yet critical interfaces in batteries at native liquid electrolyte environments to enable cryo-electron microscopy and spectroscopy. We report substantial swelling of the solid-electrolyte interphase (SEI) on lithium metal anode in various electrolytes. The swelling behavior is dependent on electrolyte chemistry and is highly correlated to battery performance. Higher degrees of SEI swelling tend to exhibit poor electrochemical cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2022, "Volume": 375, "Issue": 6576, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 66, "End Page": "+", "Article Number": "eabi8703", "DOI": "10.1126/science.abi8703", "DOI Link": "http://dx.doi.org/10.1126/science.abi8703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740261400041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Katsoulidis, AP; Antypov, D; Whitehead, GFS; Carrington, EJ; Adams, DJ; Berry, NG; Darling, GR; Dyer, MS; Rosseinsky, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Katsoulidis, Alexandros P.; Antypov, Dmytro; Whitehead, George F. S.; Carrington, Elliot J.; Adams, Dave J.; Berry, Neil G.; Darling, George R.; Dyer, Matthew S.; Rosseinsky, Matthew J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical control of structure and guest uptake by a conformationally mobile porous material", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are crystalline synthetic porous materials formed by binding organic linkers to metal nodes: they can be either rigid(1,2) or flexible(3). Zeolites and rigid MOFs have widespread applications in sorption, separation and catalysis that arise from their ability to control the arrangement and chemistry of guest molecules in their pores via the shape and functionality of their internal surface, defined by their chemistry and structure(4,5). Their structures correspond to an energy landscape with a single, albeit highly functional, energy minimum. By contrast, proteins function by navigating between multiple metastable structures using bond rotations of the polypeptide(6,7), where each structure lies in one of the minima of a conformational energy landscape and can be selected according to the chemistry of the molecules that interact with the protein. These structural changes are realized through the mechanisms of conformational selection (where a higher-energy minimum characteristic of the protein is stabilized by small-molecule binding) and induced fit (where a small molecule imposes a structure on the protein that is not a minimum in the absence of that molecule)(8). Here we show that rotation about covalent bonds in a peptide linker can change a flexible MOF to afford nine distinct crystal structures, revealing a conformational energy landscape that is characterized by multiple structural minima. The uptake of small-molecule guests by the MOF can be chemically triggered by inducing peptide conformational change. This change transforms the material from a minimum on the landscape that is inactive for guest sorption to an active one. Chemical control of the conformation of a flexible organic linker offers a route to modifying the pore geometry and internal surface chemistry and thus the function of open-framework materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 565, "Issue": 7738, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 213, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0820-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0820-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455231000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Wu, JH; Zheng, MT; Jin, X; Shen, ZH; Li, ZH; Wang, YJ; Wang, Q; Wang, XB; Wei, H; Zhang, JW; Wang, P; Zhang, SQ; Yu, LY; Dong, LF; Zhu, QS; Zhang, HG; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuo; Wu, Jianghua; Zheng, Mengting; Jin, Xin; Shen, Zihan; Li, Zhonghua; Wang, Yanjun; Wang, Quan; Wang, Xuebin; Wei, Hui; Zhang, Jiangwei; Wang, Peng; Zhang, Shanqing; Yu, Liyan; Dong, Lifeng; Zhu, Qingshan; Zhang, Huigang; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe/Cu diatomic catalysts for electrochemical nitrate reduction to ammonia", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical conversion of nitrate to ammonia offers an efficient approach to reducing nitrate pollutants and a potential technology for low-temperature and low-pressure ammonia synthesis. However, the process is limited by multiple competing reactions and NO3- adsorption on cathode surfaces. Here, we report a Fe/Cu diatomic catalyst on holey nitrogen-doped graphene which exhibits high catalytic activities and selectivity for ammonia production. The catalyst enables a maximum ammonia Faradaic efficiency of 92.51% (-0.3 V(RHE)) and a high NH3 yield rate of 1.08 mmol h(-1) mg(-1) (at - 0.5 V(RHE)). Computational and theoretical analysis reveals that a relatively strong interaction between NO3- and Fe/Cu promotes the adsorption and discharge of NO3- anions. Nitrogen-oxygen bonds are also shown to be weakened due to the existence of hetero-atomic dual sites which lowers the overall reaction barriers. The dual-site and hetero-atom strategy in this work provides a flexible design for further catalyst development and expands the electrocatalytic techniques for nitrate reduction and ammonia synthesis. Nitrate electroreduction to ammonia can decrease pollutants and produce high-value ammonia. Here, the authors design a Fe/Cu diatomic catalyst on nitrogen-doped graphene, which exhibits high catalytic activities of and selectivity for ammonia.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3634, "DOI": "10.1038/s41467-023-39366-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39366-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001015306500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XF; Wang, Q; Cheng, ZY; Zhu, ML; Zhou, H; Jiang, P; Zhou, LL; Xue, QQ; Yuan, FP; Zhu, J; Wu, XL; Ma, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xuefei; Wang, Qi; Cheng, Zhiying; Zhu, Mingliu; Zhou, Hao; Jiang, Ping; Zhou, Lingling; Xue, Qiqi; Yuan, Fuping; Zhu, Jing; Wu, Xiaolei; Ma, En", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of chemical short-range order in a medium-entropy alloy", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct experimental evidence of chemical short-range atomic-scale ordering (CSRO) in a VCoNi medium-entropy alloy is provided via diffraction and electron microscopy, analysed from specific crystallographic directions. Complex concentrated solutions of multiple principal elements are being widely investigated as high- or medium-entropy alloys (HEAs or MEAs)(1-11), often assuming that these materials have the high configurational entropy of an ideal solution. However, enthalpic interactions among constituent elements are also expected at normal temperatures, resulting in various degrees of local chemical order(12-22). Of the local chemical orders that can develop, chemical short-range order (CSRO) is arguably the most difficult to decipher and firm evidence of CSRO in these materials has been missing thus far(16,22). Here we discover that, using an appropriate zone axis, micro/nullobeam diffraction, together with atomic-resolution imaging and chemical mapping via transmission electron microscopy, can explicitly reveal CSRO in a face-centred-cubic VCoNi concentrated solution. Our complementary suite of tools provides concrete information about the degree/extent of CSRO, atomic packing configuration and preferential occupancy of neighbouring lattice planes/sites by chemical species. Modelling of the CSRO order parameters and pair correlations over the nearest atomic shells indicates that the CSRO originates from the nearest-neighbour preference towards unlike (V-Co and V-Ni) pairs and avoidance of V-V pairs. Our findings offer a way of identifying CSRO in concentrated solution alloys. We also use atomic strain mapping to demonstrate the dislocation interactions enhanced by the CSROs, clarifying the effects of these CSROs on plasticity mechanisms and mechanical properties upon deformation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 496, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2021, "Volume": 592, "Issue": 7856, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 712, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03428-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03428-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645368900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, Z; Wu, YS; Wang, MY; Jiang, JB; Yang, K; Huo, SJ; Wang, XF; Ma, Q; Brudvig, GW; Batista, VS; Liang, YY; Feng, ZX; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Zhe; Wu, Yueshen; Wang, Maoyu; Jiang, Jianbing; Yang, Ke; Huo, Shengjuan; Wang, Xiao-Feng; Ma, Qing; Brudvig, Gary W.; Batista, Victor S.; Liang, Yongye; Feng, Zhenxing; Wang, Hailiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Restructuring-induced catalytic activity is an intriguing phenomenon of fundamental importance to rational design of high-performance catalyst materials. We study three copper-complex materials for electrocatalytic carbon dioxide reduction. Among them, the copper(II) phthalocyanine exhibits by far the highest activity for yielding methane with a Faradaic efficiency of 66% and a partial current density of 13 mA cm(-2) at the potential of -1.06 V versus the reversible hydrogen electrode. Utilizing in-situ and operando X-ray absorption spectroscopy, we find that under the working conditions copper(II) phthalocyanine undergoes reversible structural and oxidation state changes to form similar to 2 nm metallic copper clusters, which catalyzes the carbon dioxide-to-methane conversion. Density functional calculations rationalize the restructuring behavior and attribute the reversibility to the strong divalent metal ion-ligand coordination in the copper(II) phthalocyanine molecular structure and the small size of the generated copper clusters under the reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 563, "Times Cited, All Databases": 590, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 415, "DOI": "10.1038/s41467-018-02819-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-02819-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423431900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Lei, DN; He, YB; Yuan, YF; Yun, QB; Ni, B; Lv, W; Li, BH; Yang, QH; Kang, FY; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Heng; Lei, Danni; He, Yan-Bing; Yuan, Yifei; Yun, Qinbai; Ni, Bin; Lv, Wei; Li, Baohua; Yang, Quan-Hong; Kang, Feiyu; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite-Free Lithium Metal Anode Current Collector", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of lithium (Li) metal anodes Li metal batteries faces huge challenges such as uncontrolled Li dendrite growth and large volume change during Li plating/stripping, resulting in severe capacity decay and high safety hazards. A 3D porous copper (Cu) current collector as a host for Li deposition can effectively settle these problems. However, constructing a uniform and compact 3D porous Cu structure is still an enormous challenge. Herein, an electrochemical etching method for Cu-Zinc (Zn) alloy is reported to precisely engrave a 3D Cu structure with uniform, smooth, and compact porous network. Such a continuous structure endows 3D Cu excellent mechanical properties and high electrical conductivity. The uniform and smooth pores with a large internal surface area ensures well dispersed current density for homogeneous Li metal deposition and accommodation. A smooth and stable solid electrolyte interphase is formed and meanwhile Li dendrites and dead Li are effectively suppressed. The Li metal anode conceived 3D Cu current collector can stably cycle for 400 h under an Li plating/stripping capacity of 1 mA h cm(-2) and a current density of 1 mA cm(-2). The Li@3D Cu||LiFePO4 full cells present excellent cycling and rate performances. The electrochemical dealloying is a robust method to construct 3D Cu current collectors for dendrite-free Li metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2018, "Volume": 8, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800266, "DOI": "10.1002/aenm.201800266", "DOI Link": "http://dx.doi.org/10.1002/aenm.201800266", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437667800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Campbell, MG; Liu, SF; Swager, TM; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M.; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemiresistive Sensor Arrays from Conductive 2D Metal-Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Applications of porous metal-organic frameworks (MOFs) in electronic devices are rare, owing in large part to a lack of MOFs that display electrical conductivity. Here, we describe the use of conductive two-dimensional (2D) MOFs as a new class of materials for cherniresistive sensing of volatile organic compounds (VOCs). We demonstrate that a family of structurally analogous 2D MOFs can be used to construct a cross-reactive sensor array that allows for clear discrimination between different categories of VOCs. Experimental data show that multiple sensing mechanisms are operative with high degrees of orthogonality, establishing that the 2D MOFs used here are mechanistically unique and offer advantages relative to other known chemiresistor materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 666, "Times Cited, All Databases": 704, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2015, "Volume": 137, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13780, "End Page": 13783, "Article Number": null, "DOI": "10.1021/jacs.5b09600", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b09600", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364355900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Jia, S; Kholmanov, I; Dong, L; Er, DQ; Chen, WB; Guo, H; Jin, ZH; Shenoy, VB; Shi, L; Lou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jing; Jia, Shuai; Kholmanov, Iskandar; Dong, Liang; Er, Dequan; Chen, Weibing; Guo, Hua; Jin, Zehua; Shenoy, Vivek B.; Shi, Li; Lou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Janus Monolayer Transition-Metal Dichalcogenides", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystal configuration of sandwiched S-Mo-Se structure (Janus SMoSe) at the monolayer limit has been synthesized and carefully characterized in this work. By controlled sulfurization of monolayer MoSe2, the top layer of selenium atoms is substituted by sulfur atoms, while the bottom selenium layer remains intact. The structure of this material is systematically investigated by Raman, photoluminescence, transmission electron microscopy, and X-ray photoelectron spectroscopy and confirmed by time-of-flight secondary ion mass spectrometry. Density functional theory (DFT) calculations are performed to better understand the Raman vibration modes and electronic structures of the Janus SMoSe monolayer, which are found to correlate well with corresponding experimental results. Finally, high basal plane hydrogen evolution reaction activity is discovered for the Janus monolayer, and DFT calculation implies that the activity originates from the synergistic effect of the intrinsic defects and structural strain inherent in the Janus structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1206, "Times Cited, All Databases": 1260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8192, "End Page": 8198, "Article Number": null, "DOI": "10.1021/acsnullo.7b03186", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b03186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408520900069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, N; Yang, YF; Wang, CX; Wu, QL; Pan, F; Zhang, RA; Liu, JR; Zeng, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Na; Yang, Yunfei; Wang, Changxian; Wu, Qilei; Pan, Fei; Zhang, Runa; Liu, Jiurong; Zeng, Zhihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Cellulose nullofiber Assisted Ambient-Pressure-Dried, Ultralight, Mechanically Robust, Multifunctional MXene Aerogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient-pressure-dried (APD) preparation of transition metal carbide/nitrides (MXene) aerogels is highly desirable yet remains highly challenging. Here, ultrathin, high-strength-to-weight-ratio, renewable cellulose nullofibers (CNFs) are efficiently utilized to assist in the APD preparation of ultralight yet robust, highly conductive, large-area MXene-based aerogels via a facile, energy-efficient, eco-friendly, and scalable freezing-exchanging-drying approach. The strong interactions of large-aspect-ratio CNF and MXene as well as the biomimetic nacre-like microstructure induce high mechanical strength and stability to avoid the structure collapse of aerogels in the APD process. Abundant functional groups of CNFs facilitate the chemical crosslinking of MXene-based aerogels, significantly improving the hydrophobicity, water resistance, and even oxidation stability. The ultrathin, 1D nature of the CNF renders the minimal MXenes' interlayered gaps and numerous heterogeneous interfaces, yielding the excellent conductivity and electromagnetic interference (EMI) shielding performance of aerogels. The synergies of the MXene, CNF, and abundant pores efficiently improve the EMI shielding performance, photothermal conversion, and absorption of viscous crude oil. This work shows great promises of the APD, multifunctional MXene-based aerogels in electromagnetic protection or compatibility, thermal therapy, and oil-water separation applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 35, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207969", "DOI Link": "http://dx.doi.org/10.1002/adma.202207969", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891050600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, KT; Lin, H; Yang, TS; Jia, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Keng-Te; Lin, Han; Yang, Tieshan; Jia, Baohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structured graphene metamaterial selective absorbers for high efficiency and omnidirectional solar thermal energy conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An ideal solar-thermal absorber requires efficient selective absorption with a tunable bandwidth, excellent thermal conductivity and stability, and a simple structure for effective solar thermal energy conversion. Despite various solar absorbers having been demonstrated, these conditions are challenging to achieve simultaneously using conventional materials and structures. Here, we propose and demonstrate three-dimensional structured graphene metamaterial (SGM) that takes advantages of wavelength selectivity from metallic trench-like structures and broadband dispersionless nature and excellent thermal conductivity from the ultrathin graphene metamaterial film. The SGM absorbers exhibit superior solar selective and omnidirectional absorption, flexible tunability of wavelength selective absorption, excellent photothermal performance, and high thermal stability. Impressive solar-to-thermal conversion efficiency of 90.1% and solar-to-vapor efficiency of 96.2% have been achieved. These superior properties of the SGM absorber suggest it has a great potential for practical applications of solar thermal energy harvesting and manipulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1389, "DOI": "10.1038/s41467-020-15116-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15116-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563553600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, XH; Yu, ZW; Gong, L; Tao, Y; Gao, Z; Wang, L; Yin, WH; Yang, L; Luo, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Xiao Hong; Yu, Zhi Wu; Gong, Le Le; Tao, Yuan; Gao, Zhi; Wang, Li; Yin, Wen Hui; Yang, Li Xiao; Luo, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ammoniating Covalent Organic Framework (COF) for High-Performance and Selective Extraction of Toxic and Radioactive Uranium Ions", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An ideal porous adsorbent toward uranium with not only large adsorption capacity and high selectivity but also broad applicability even under rigorous conditions is highly desirable but still extremely scarce. In this work, a porous adsorbent, namely [NH4](+)[COF-SO3-], prepared by ammoniating a SO3H-decorated covalent organic framework (COF) enables remarkable performance for uranium extraction. Relative to the pristine SO3H-decorated COF (COF-SO3H) with uranium adsorption capacity of 360 mg g(-1), the ammoniated counterpart of [NH4](+)[COF-SO3-] affords ultrahigh uranium uptake up to 851 mg g(-1), creating a 2.4-fold enhancement. Such a value is the highest among all reported porous adsorbents for uranium. Most importantly, a large distribution coefficient, K-d(U), up to 9.8 x 10(6) mL g(-1) is observed, implying extremely strong affinity toward uranium. Consequently, [NH4](+)[COF-SO3-] affords highly selective adsorption of uranium over a broad range of metal ions such as S-U/Cs = 821, S-U/Na = 277, and S-U/Sr = 124, making it as effective uranium adsorbent from seawater, resulting in amazing uranium adsorption capacity of 17.8 mg g(-1). Moreover, its excellent chemostability also make it an effective uranium adsorbent even under rigorous conditions (pH = 1, 8, and 3 m acidity).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2019, "Volume": 6, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900547, "DOI": "10.1002/advs.201900547", "DOI Link": "http://dx.doi.org/10.1002/advs.201900547", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482048100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ou, G; Xu, YS; Wen, B; Lin, R; Ge, BH; Tang, Y; Liang, YW; Yang, C; Huang, K; Zu, D; Yu, R; Chen, WX; Li, J; Wu, H; Liu, LM; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ou, Gang; Xu, Yushuai; Wen, Bo; Lin, Rui; Ge, Binghui; Tang, Yan; Liang, Yuwei; Yang, Cheng; Huang, Kai; Zu, Di; Yu, Rong; Chen, Wenxing; Li, Jun; Wu, Hui; Liu, Li-Min; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning defects in oxides at room temperature by lithium reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects can greatly influence the properties of oxide materials; however, facile defect engineering of oxides at room temperature remains challenging. The generation of defects in oxides is difficult to control by conventional chemical reduction methods that usually require high temperatures and are time consuming. Here, we develop a facile room-temperature lithium reduction strategy to implant defects into a series of oxide nulloparticles including titanium dioxide (TiO2), zinc oxide (ZnO), tin dioxide (SnO2), and cerium dioxide (CeO2). Our lithium reduction strategy shows advantages including all-room-temperature processing, controllability, time efficiency, versatility and scalability. As a potential application, the photocatalytic hydrogen evolution performance of defective TiO2 is examined. The hydrogen evolution rate increases up to 41.8 mmol g(-1) h(-1) under one solar light irradiation, which is similar to 3 times higher than that of the pristine nulloparticles. The strategy of tuning defect oxides used in this work may be beneficial for many other related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 550, "Times Cited, All Databases": 566, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1302, "DOI": "10.1038/s41467-018-03765-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03765-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429003900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, SM; Han, J; Shi, ZJ; Chen, K; Xu, N; Wang, YF; Zheng, RZ; Tao, YZ; Sun, QJ; Wang, ZL; Yang, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Sanming; Han, Jing; Shi, Zhijun; Chen, Kun; Xu, Nuo; Wang, Yifei; Zheng, Ruizhu; Tao, Yongzhen; Sun, Qijun; Wang, Zhong Lin; Yang, Guang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable, Super-Strong, and Conductive Cellulose Macrofibers for Fabric-Based Triboelectric nullogenerator", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic fibers used to fabricate wearable triboelectric nullogenerator (TENG) for harvesting human mechanical energy have been extensively explored. However, little attention is paid to their mutual advantages of environmental friendliness, mechanical properties, and stability. Here, we report a super-strong, biodegradable, and washable cellulose-based conductive macrofibers, which is prepared by wet-stretching and wet-twisting bacterial cellulose hydrogel incorporated with carbon nullotubes and polypyrrole. The cellulose-based conductive macrofibers possess high tensile strength of 449 MPa (able to lift 2 kg weights), good electrical conductivity (similar to 5.32 S cm(-1)), and excellent stability (Tensile strength and conductivity only decrease by 6.7% and 8.1% after immersing in water for 1 day). The degradation experiment demonstrates macrofibers can be degraded within 108 h in the cellulase solution. The designed fabric-based TENG from the cellulose-base conductive macrofibers shows a maximum open-circuit voltage of 170 V, short-circuit current of 0.8 mu A, and output power at 352 mu W, which is capable of powering the commercial electronics by charging the capacitors. More importantly, the fabric-based TENGs can be attached to the human body and work as self-powered sensors to effectively monitor human motions. This study suggests the potential of biodegradable, super-strong, and washable conductive cellulose-based fiber for designing eco-friendly fabric-based TENG for energy harvesting and biomechanical monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115, "DOI": "10.1007/s40820-022-00858-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00858-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788598500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, GF; Chen, JL; Yu, TQ; Liu, JC; Luo, L; Yin, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Guangfu; Chen, Jinli; Yu, Tianqi; Liu, Jiacheng; Luo, Lin; Yin, Shibin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-Phase Heterojunction NiMo-Based nullo-Needle for Water Splitting at Industrial Alkaline Condition", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting (WS). Herein, we design and prepare an N-doped-carbon-encapsulated Ni/MoO2 nullo-needle with three-phase heterojunction (Ni/MoO2 @CN) for accelerating the WS under industrial alkaline condition. Density functional theory calculations reveal that the electrons are redistributed at the three-phase heterojunction interface, which optimizes the adsorption energy of H- and O-containing intermediates to obtain the best AG H . for hydrogen evolution reaction (HER) and decrease the AG value of rate-determining step for oxygen evolution reaction (OER), thus enhancing the HER/OER catalytic activity. Electrochemical results confirm that Ni/MoO2@CN exhibits good activity for HER (eta(-)(10)=33 mV, eta(-)(1000) =267 mV) and OER (eta(10) =250 mV, eta(1000) =420 mV). It shows a low potential of 1.86 V at 1000 mA cm(-2) for WS in 6.0 M KOH solution at 60 degrees C and can steadily operate for 330 h. This good HER/OER performance can be attributed to the three-phase heterojunction with high intrinsic activity and the self-supporting nullo-needle with more active sites, faster mass diffusion, and bubbles release. This work provides a unique idea for designing high efficiency catalytic materials for WS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20, "DOI": "10.1007/s40820-021-00744-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00744-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000728578300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, SZ; Qiu, KY; Meng, FB; Park, SH; McAlpine, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Shuang-Zhuang; Qiu, Kaiyan; Meng, Fanben; Park, Sung Hyun; McAlpine, Michael C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Stretchable Tactile Sensors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of methods for the 3D printing of multifunctional devices could impact areas ranging from wearable electronics and energy harvesting devices to smart prosthetics and human-machine interfaces. Recently, the development of stretchable electronic devices has accelerated, concomitant with advances in functional materials and fabrication processes. In particular, novel strategies have been developed to enable the intimate biointegration of wearable electronic devices with human skin in ways that bypass the mechanical and thermal restrictions of traditional microfabrication technologies. Here, a multimaterial, multiscale, and multifunctional 3D printing approach is employed to fabricate 3D tactile sensors under ambient conditions conformally onto freeform surfaces. The customized sensor is demonstrated with the capabilities of detecting and differentiating human movements, including pulse monitoring and finger motions. The custom 3D printing of functional materials and devices opens new routes for the biointegration of various sensors in wearable electronics systems, and toward advanced bionic skin applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2017, "Volume": 29, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701218, "DOI": "10.1002/adma.201701218", "DOI Link": "http://dx.doi.org/10.1002/adma.201701218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405410700030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, XJ; Li, HB; Wang, Y; Hu, YL; Hua, L; Li, HY; Han, XW; Liu, QF; Yang, F; He, LM; Chen, XQ; Li, QY; Xiao, JP; Deng, DH; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Xiaoju; Li, Haobo; Wang, Yan; Hu, Yuanli; Hua, Lei; Li, Haiyang; Han, Xiuwen; Liu, Qingfei; Yang, Fan; He, Limin; Chen, Xiaoqi; Li, Qingyun; Xiao, Jianping; Deng, Dehui; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-Temperature Methane Conversion by Graphene-Confined Single Iron Atoms", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct conversion of methane to high-value-added chemicals is a major challenge in catalysis, which usually requires high-energy input to overcome the reaction barrier. We report that graphene-confined single Fe atoms can be used as an efficient non-precious catalyst to directly convert methane to C1 oxygenated products at room temperature. A series of graphene-confined 3d transition metals (Mn, Fe, Co, Ni, and Cu) were screened, yet only single Fe atoms could catalyze the methane conversion. Combining in operando time-of-flight mass spectrometry, C-13 nuclear magnetic resonullce, and density functional theory calculations, we found that methane conversion proceeds on the O-FeN4-O active site along a radical pathway to produce CH3OH and CH3OOH first, and then the generated CH3OH can be further catalyzed to form HOCH2OOH and HCOOH at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2018, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1902, "End Page": 1910, "Article Number": null, "DOI": "10.1016/j.chempr.2018.05.006", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.05.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441194300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, LL; Wang, JY; Teng, X; Meyer, TJ; Chen, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Lvlv; Wang, Jianying; Teng, Xue; Meyer, Thomas J.; Chen, Zuofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CoP nulloframes as Bifunctional Electrocatalysts for Efficient Overall Water Splitting", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition-metal phosphides have been shown to be promising electrocatalysts in water for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). To maximize reactivity toward both entails limiting the catalyst size while maintaining reactivity and avoiding aggregation. Frame-like hollow nullostructures (nulloframes) provide the required open structure with sufficient channels into the interior volume. We demonstrate here the design and synthesis of CoP nulloframes (CoP NFs) by a strategy involving precipitation, chemical etching, and low-temperature phosphidation steps. It results in impressive bifunctional catalytic activities for both HER and OER and consequently enables a highly efficient water electrolyzer with a current density of 10 mA cm(-2) driven by a cell voltage of only 1.65 V. The strategy has been generalized for the preparation of nulloframe Co dichalcogenides CoX2 NFs, with X = S, Se, and Te. The results of electrochemical measurements, supported by density functional theory calculations, show that HER catalytic activities for the series follow the sequence: CoP NFs > CoSe2 NFs > CoS2 NFs > CoTe2 NFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 412, "End Page": 419, "Article Number": null, "DOI": "10.1021/acscatal.9b03623", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b03623", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506725100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, YZ; An, TC; Yap, LW; Zhu, BW; Gong, S; Cheng, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Yunzhi; An, Tiance; Yap, Lim Wei; Zhu, Bowen; Gong, Shu; Cheng, Wenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Disruptive, Soft, Wearable Sensors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The wearable industry is on the rise, with a myriad of technical applications ranging from real-time health monitoring, the Internet of Things, and robotics, to name but a few. However, there is a saying wearable is not wearable because the current market-available wearable sensors are largely bulky and rigid, leading to uncomfortable wearing experience, motion artefacts, and poor data accuracy. This has aroused a world-wide intensive research quest for novel materials, with the aim of fabricating next-generation ultra-lightweight and soft wearable devices. Such disruptive second-skin-like biosensing technologies may enable a paradigm shift from current wearable 1.0 to future wearable 2.0 products. Here, the state-of-the-art progress made in the key phases for future wearable technology, namely, wear -> sense -> communicate -> analyze -> interpret -> decide, is summarized. Without a doubt, materials innovation is the key, which is the main focus of the discussion. In addition, emphasis is also given to wearable energy, multicomponent integration, and wireless communication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 32, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904664, "DOI": "10.1002/adma.201904664", "DOI Link": "http://dx.doi.org/10.1002/adma.201904664", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496029700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, Z; Yeh, MH; Guo, HY; Wang, J; Zi, YL; Xu, WD; Deng, JN; Zhu, L; Wang, X; Hu, CG; Zhu, LP; Sun, XH; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Zhen; Yeh, Min-Hsin; Guo, Hengyu; Wang, Jie; Zi, Yunlong; Xu, Weidong; Deng, Jianull; Zhu, Lei; Wang, Xin; Hu, Chenguo; Zhu, Liping; Sun, Xuhui; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-powered textile for wearable electronics by hybridizing fiber-shaped nullogenerators, solar cells, and supercapacitors", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable electronics fabricated on lightweight and flexible substrate are believed to have great potential for portable devices, but their applications are limited by the life span of their batteries. We propose a hybridized self-charging power textile system with the aim of simultaneously collecting outdoor sunshine and random body motion energies and then storing them in an energy storage unit. Both of the harvested energies can be easily converted into electricity by using fiber-shaped dye-sensitized solar cells (for solar energy) and fiber-shaped triboelectric nullogenerators (for random body motion energy) and then further stored as chemical energy in fiber-shaped supercapacitors. Because of the all-fiber-shaped structure of the entire system, our proposed hybridized self-charging textile system can be easily woven into electronic textiles to fabricate smart clothes to sustainably operate mobile or wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 766, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1600097", "DOI": "10.1126/sciadv.1600097", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1600097", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387991500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, C; Zhang, XD; Huang, SS; Hu, Y; Yang, Z; Li, TT; Li, QP; Qian, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Cheng; Zhang, Xiaodeng; Huang, Shengsheng; Hu, Yue; Yang, Zhi; Li, Ting-Ting; Li, Qipeng; Qian, Jinjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-on-MOF-Derived Hollow Co3O4/In2O3 nullostructure for Efficient Photocatalytic CO2 Reduction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photocatalytic transformation of carbon dioxide (CO2) into carbon-based fuels or chemicals using sustainable solar energy is considered an ideal strategy for simultaneously alleviating the energy shortage and environmental crises. However, owing to the low energy utilization of sunlight and inferior catalytic activity, the conversion efficiency of CO2 photoreduction is far from satisfactory. In this study, a MOF-derived hollow bimetallic oxide nullomaterial is prepared for the efficient photoreduction of CO2. First, a unique ZIF-67-on-InOF-1 heterostructure is successfully obtained by growing a secondary Co-based ZIF-67 onto the initial InOF-1 nullorods. The corresponding hollow counterpart has a larger specific surface area after acid etching, and the oxidized bimetallic H-Co3O4/In2O3 material exhibits abundant heterogeneous interfaces that expose more active sites. The energy band structure of H-Co3O4/In2O3 corresponds well with the photosensitizer of [Ru(bpy)(3)]Cl-2, which results in a high CO yield of 4828 +/- 570 mu mol h(-1) g(-1) and stable activity over a consecutive of six runs, demonstrating adequate photocatalytic performance. This study demonstrates that the rational design of MOF-on-MOF heterostructures can completely exploit the synergistic effects between different components, which may be extended to other MOF-derived nullomaterials as promising catalysts for practical energy conversion and storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300797", "DOI Link": "http://dx.doi.org/10.1002/advs.202300797", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971490100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, PJ; Ren, WL; Zheng, TX; Ren, ZM; Hou, XL; Peng, JC; Hu, PF; Gao, YF; Zhong, YB; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Peijian; Ren, Weili; Zheng, Tianxiang; Ren, Zhongming; Hou, Xueling; Peng, Jianchao; Hu, Pengfei; Gao, Yanfei; Zhong, Yunbo; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced strength-ductility synergy in ultrafine-grained eutectic high-entropy alloys by inheriting microstructural lamellae", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing improved strength-ductility synergy in eutectic alloys acting as in situ composite materials remains a challenge in conventional eutectic systems, which is why eutectic high-entropy alloys (EHEAs), a newly-emerging multi-principal-element eutectic category, may offer wider in situ composite possibilities. Here, we use an AlCoCrFeNi2.1 EHEA to engineer an ultrafine-grained duplex microstructure that deliberately inherits its composite lamellar nature by tailored thermo-mechanical processing to achieve property combinations which are not accessible to previously-reported reinforcement methodologies. The as-prepared samples exhibit hierarchically-structural heterogeneity due to phase decomposition, and the improved mechanical response during deformation is attributed to both a two-hierarchical constraint effect and a self-generated microcrack-arresting mechanism. This work provides a pathway for strengthening eutectic alloys and widens the design toolbox for high-performance materials based upon EHEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 703, "Times Cited, All Databases": 737, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 489, "DOI": "10.1038/s41467-019-08460-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08460-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457130800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HD; Zhang, ZH; Liu, JX; Do-Thanh, CL; Chen, H; Xu, SH; Lin, QJ; Jiao, Y; Wang, JL; Wang, Y; Chen, YQ; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Haidi; Zhang, Zihao; Liu, Jixing; Chi-Linh Do-Thanh; Chen, Hao; Xu, Shuhao; Lin, Qinjing; Jiao, Yi; Wang, Jianli; Wang, Yun; Chen, Yaoqiang; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy-stabilized single-atom Pd catalysts via high-entropy fluorite oxide supports", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have attracted considerable attention in the catalysis community. However, fabricating intrinsically stable SACs on traditional supports (N-doped carbon, metal oxides, etc.) remains a formidable challenge, especially under high-temperature conditions. Here, we report a novel entropy-driven strategy to stabilize Pd single-atom on the high-entropy fluorite oxides (CeZrHfTiLa)O-x (HEFO) as the support by a combination of mechanical milling with calcination at 900 degrees C. Characterization results reveal that single Pd atoms are incorporated into HEFO (Pd-1@HEFO) sublattice by forming stable Pd-O-M bonds (M=Ce/Zr/La). Compared to the traditional support stabilized catalysts such as Pd@CeO2, Pd-1@HEFO affords the improved reducibility of lattice oxygen and the existence of stable Pd-O-M species, thus exhibiting not only higher low-temperature CO oxidation activity but also outstanding resistance to thermal and hydrothermal degradation. This work therefore exemplifies the superiority of high-entropy materials for the preparation of SACs. Fabricating intrinsically stable single-atom catalysts (SACs) on traditional supports remains a formidable challenge in catalysis. Here, the authors propose a new strategy to construct a sintering-resistant Pd SAC on a novel equimolar high-entropy fluorite oxide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3908, "DOI": "10.1038/s41467-020-17738-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17738-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561120500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Y; Liu, ZY; Matsuhisa, N; Qi, DP; Leow, WR; Yang, H; Yu, JC; Chen, G; Liu, YQ; Wan, CJ; Liu, ZJ; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Ying; Liu, Zhiyuan; Matsuhisa, Naoji; Qi, Dianpeng; Leow, Wan Ru; Yang, Hui; Yu, Jiancan; Chen, Geng; Liu, Yaqing; Wan, Changjin; Liu, Zhuangjian; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Auxetic Mechanical Metamaterials to Enhance Sensitivity of Stretchable Strain Sensors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable strain sensors play a pivotal role in wearable devices, soft robotics, and Internet-of-Things, yet these viable applications, which require subtle strain detection under various strain, are often limited by low sensitivity. This inadequate sensitivity stems from the Poisson effect in conventional strain sensors, where stretched elastomer substrates expand in the longitudinal direction but compress transversely. In stretchable strain sensors, expansion separates the active materials and contributes to the sensitivity, while Poisson compression squeezes active materials together, and thus intrinsically limits the sensitivity. Alternatively, auxetic mechanical metamaterials undergo 2D expansion in both directions, due to their negative structural Poisson's ratio. Herein, it is demonstrated that such auxetic metamaterials can be incorporated into stretchable strain sensors to significantly enhance the sensitivity. Compared to conventional sensors, the sensitivity is greatly elevated with a 24-fold improvement. This sensitivity enhancement is due to the synergistic effect of reduced structural Poisson's ratio and strain concentration. Furthermore, microcracks are elongated as an underlying mechanism, verified by both experiments and numerical simulations. This strategy of employing auxetic metamaterials can be further applied to other stretchable strain sensors with different constituent materials. Moreover, it paves the way for utilizing mechanical metamaterials into a broader library of stretchable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2018, "Volume": 30, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706589, "DOI": "10.1002/adma.201706589", "DOI Link": "http://dx.doi.org/10.1002/adma.201706589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428348000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HM; Shen, X; Kim, EY; Wang, MY; Lee, JH; Chen, HM; Zhang, GC; Kim, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hongming; Shen, Xi; Kim, Eunyoung; Wang, Mingyue; Lee, Jeng-Hun; Chen, Haomin; Zhang, Guangcheng; Kim, Jang-Kyo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated Water and Thermal Managements in Bioinspired Hierarchical MXene Aerogels for Highly Efficient Solar-Powered Water Evaporation", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-powered water evaporation is a straightforward, practical approach to use solar energy for water desalination. Solar absorbers made from photothermal materials capable of effectively confining heat and pumping water to the evaporation surface are essential for a high energy efficiency. However, separate designs of water transport routes and thermal insulating layers are required to simultaneously achieve desired water and thermal managements. This work reports an integrated design for efficient multifunctional capabilities through rational assembly of spectrally modified Ti3C2Tx (SM-Ti3C2Tx) nullosheets and polyvinyl alcohol (PVA) into a multiscale 3D aerogel with a feather-like microstructure. The aerogel contains longitudinal struts with transversely parallel ligaments developed at an angle of approximate to 60 degrees from the struts, resembling the microstructure of down feathers in penguins and thus leading to excellent thermal insulation. The hydrophilic porous ligaments serve as upward water transport channels, pumping the water to the evaporation surface while confining it within the ligaments to avoid oversaturation. These functional features endow the composite aerogel with a high energy efficiency of 88.52% and an evaporation rate of 0.92 kg m(-2) h(-1) at a weak solar irradiance of 0.5-sun, indicating its great potential for practical solar-powered water desalination under natural sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 32, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2111794, "DOI": "10.1002/adfm.202111794", "DOI Link": "http://dx.doi.org/10.1002/adfm.202111794", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751389900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miner, EM; Fukushima, T; Sheberla, D; Sun, L; Surendranath, Y; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis; Sun, Lei; Surendranath, Yogesh; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni-3(HITP)(2) (HITP = 2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni-3(HITP)(2) exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N-4 sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N-4 units. Ni-3(HITP)(2) and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. Such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 645, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10942, "DOI": "10.1038/ncomms10942", "DOI Link": "http://dx.doi.org/10.1038/ncomms10942", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371725600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LK; Kim, J; Jin, CH; Ye, GJ; Qiu, DY; da Jornada, FH; Shi, ZW; Chen, L; Zhang, ZC; Yang, FY; Watanabe, K; Taniguchi, T; Ren, W; Louie, SG; Chen, XH; Zhang, YB; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Likai; Kim, Jonghwan; Jin, Chenhao; Ye, Guo Jun; Qiu, Diana Y.; da Jornada, Felipe H.; Shi, Zhiwen; Chen, Long; Zhang, Zuocheng; Yang, Fangyuan; Watanabe, Kenji; Taniguchi, Takashi; Ren, Wencai; Louie, Steven G.; Chen, Xian Hui; Zhang, Yuanbo; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of the layer-dependent electronic structure in phosphorene", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new two-dimensional (2D) material that holds promise for electronic and photonic technologies(1-5). Here we experimentally demonstrate that the electronic structure of few-layer phosphorene varies significantly with the number of layers, in good agreement with theoretical predictions. The interband optical transitions cover a wide, technologically important spectral range from the visible to the mid-infrared. In addition, we observe strong photoluminescence in few-layer phosphorene at energies that closely match the absorption edge, indicating that they are direct bandgap semiconductors. The strongly layer-dependent electronic structure of phosphorene, in combination with its high electrical mobility, gives it distinct advantages over other 2D materials in electronic and opto-electronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 672, "Times Cited, All Databases": 738, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21, "End Page": 25, "Article Number": null, "DOI": "10.1038/NnullO.2016.171", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2016.171", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392042400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, F; Stoumpos, CC; Guo, PJ; Zhou, NJ; Marks, TJ; Chang, RPH; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Feng; Stoumpos, Constantinos C.; Guo, Peijun; Zhou, nulljia; Marks, Tobin J.; Chang, Robert P. H.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent-Mediated Crystallization of CH3NH3SnI3 Films for Heterojunction Depleted Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organo-lead halide perovskite solar cells have gained enormous significance and have now achieved power conversion efficiencies of similar to 20%. However, the potential toxicity of lead in these systems raises environmental concerns for widespread deployment. Here we investigate solvent effects on the crystallization of the lead-free methylammonium tin triiodide (CH3NH3SnI3) perovskite films in a solution growth process. Highly uniform, pinhole-free perovskite films are obtained from a dimethyl sulfoxide (DMSO) solution via a transitional SnI2 center dot 3DMSO intermediate phase. This high-quality perovskite film enables the realization of heterojunction depleted solar cells based on mesoporous TiO2 layer but in the absence of any hole-transporting material with an unprecedented photocurrent up to 21 mA cm(-2). Charge extraction and transient photovoltage decay measurements reveal high carrier densities in the CH3NH3SnI3 perovskite device which are one order of magnitude larger than CH3NH3PbI3-based devices but with comparable recombination lifetimes in both devices. The relatively high background dark carrier density of the Sn-based perovskite is responsible for the lower photovoltaic efficiency in comparison to the Pb-based analogues. These results provide important progress toward achieving improved perovskite morphology control in realizing solution-processed highly efficient lead-free perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 635, "Times Cited, All Databases": 663, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2015, "Volume": 137, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11445, "End Page": 11452, "Article Number": null, "DOI": "10.1021/jacs.5b06658", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b06658", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361251600038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bak, SM; Hu, EY; Zhou, YN; Yu, XQ; Senullayake, SD; Cho, SJ; Kim, KB; Chung, KY; Yang, XQ; Nam, KW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning; Yu, Xiqian; Senullayake, Sanjaya D.; Cho, Sung-Jin; Kim, Kwang-Bum; Chung, Kyung Yoon; Yang, Xiao-Qing; Nam, Kyung-Wan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural Changes and Thermal Stability of Charged LiNixMnyCozO2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal stability of charged LiNixMnyCozO2 (NMC, with x + y + z = 1, x:y:z = 4:3:3 (NMC433), 5:3:2 (NMC532), 6:2:2 (NMC622), and 8:1:1 (NMC811)) cathode materials is systematically studied using combined in situ time-resolved X-ray diffraction and mass spectroscopy (TR-XRD/MS) techniques upon heating up to 600 degrees C. The TR-XRD/MS results indicate that the content of Ni, Co, and Mn significantly affects both the structural changes and the oxygen release features during heating: the more Ni and less Co and Mn, the lower the onset temperature of the phase transition (i.e., thermal decomposition) and the larger amount of oxygen release. Interestingly, the NMC532 seems to be the optimized composition to maintain a reasonably good thermal stability, comparable to the low-nickel-content materials (e.g., NMC333 and NMC433), while having a high capacity close to the high-nickel-content materials (e.g., NMC811 and NMC622). The origin of the thermal decomposition of NMC cathode materials was elucidated by the changes in the oxidation states of each transition metal (TM) cations (i.e., Ni, Co, and Mn) and their site preferences during thermal decomposition. It is revealed that Mn ions mainly occupy the 3a octahedral sites of a layered structure (R (3) over barm) but Co ions prefer to migrate to the 8a tetrahedral sites of a spinel structure (Fd (3) over barm) during the thermal decomposition. Such element-dependent cation migration plays a very important role in the thermal stability of NMC cathode materials. The reasonably good thermal stability and high capacity characteristics of the NMC532 composition is originated from the well-balanced ratio of nickel content to manganese and cobalt contents. This systematic study provides insight into the rational design of NMC-based cathode materials with a desired balance between thermal stability and high energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 791, "Times Cited, All Databases": 871, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 24", "Publication Year": 2014, "Volume": 6, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22594, "End Page": 22601, "Article Number": null, "DOI": "10.1021/am506712c", "DOI Link": "http://dx.doi.org/10.1021/am506712c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347139400101", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ke, WJ; Xiao, CX; Wang, CL; Saparov, B; Duan, HS; Zhao, DW; Xiao, ZW; Schulz, P; Harvey, SP; Liao, WQ; Meng, WW; Yu, Y; Cimaroli, AJ; Jiang, CS; Zhu, K; Al-Jassim, M; Fang, GJ; Mitzi, DB; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ke, Weijun; Xiao, Chuanxiao; Wang, Changlei; Saparov, Bayrammurad; Duan, Hsin-Sheng; Zhao, Dewei; Xiao, Zewen; Schulz, Philip; Harvey, Steven P.; Liao, Weiqiang; Meng, Weiwei; Yu, Yue; Cimaroli, Alexander J.; Jiang, Chun-Sheng; Zhu, Kai; Al-Jassim, Mowafak; Fang, Guojia; Mitzi, David B.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Employing Lead Thiocyanate Additive to Reduce the Hysteresis and Boost the Fill Factor of Planar Perovskite Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead thiocyanate in the perovskite precursor can increase the grain size of a perovskite thin film and reduce the conductivity of the grain boundaries, leading to perovskite solar cells with reduced hysteresis and enhanced fill factor. A planar perovskite solar cell with grain boundary and interface passivation achieves a steady-state efficiency of 18.42%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2016, "Volume": 28, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5214, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201600594", "DOI Link": "http://dx.doi.org/10.1002/adma.201600594", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379938800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, MQ; Zhang, Q; Huang, JQ; Tian, GL; Nie, JQ; Peng, HJ; Wei, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng-Qiang; Zhang, Qiang; Huang, Jia-Qi; Tian, Gui-Li; Nie, Jing-Qi; Peng, Hong-Jie; Wei, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unstacked double-layer templated graphene for high-rate lithium-sulphur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Preventing the stacking of graphene is essential to exploiting its full potential in energy-storage applications. The introduction of spacers into graphene layers always results in a change in the intrinsic properties of graphene and/or induces complexity at the interfaces. Here we show the synthesis of an intrinsically unstacked double-layer templated graphene via template-directed chemical vapour deposition. The as-obtained graphene is composed of two unstacked graphene layers separated by a large amount of mesosized protuberances and can be used for high-power lithium-sulphur batteries with excellent high-rate performance. Even after 1,000 cycles, high reversible capacities of ca. 530mA h g (-1) and 380mA h g (-1) are retained at 5 C and 10 C, respectively. This type of double-layer graphene is expected to be an important platform that will enable the investigation of stabilized three-dimensional topological porous systems and demonstrate the potential of unstacked graphene materials for advanced energy storage, environmental protection, nullocomposite and healthcare applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 646, "Times Cited, All Databases": 685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3410, "DOI": "10.1038/ncomms4410", "DOI Link": "http://dx.doi.org/10.1038/ncomms4410", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334299400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tijing, LD; Woo, YC; Shim, WG; He, T; Choi, JS; Kim, SH; Shon, HK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tijing, Leonard D.; Woo, Yun Chul; Shim, Wang-Geun; He, Tao; Choi, June-Seok; Kim, Seung-Hyun; Shon, Ho Kyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superhydrophobic nullofiber membrane containing carbon nullotubes for high-performance direct contact membrane distillation", "Source Title": "JOURNAL OF MEMBRANE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tailoring the membrane to have superhydrophobicity, coupled with high porosity, adequate pore sizes and narrow pore size distribution, and thin thickness could find potential application for high-performing direct contact membrane distillation (DCMD) process. Electrospinning is an excellent approach in fabricating nullofiber membranes with adequate properties required of an MD membrane. In this study, superhydrophobic, robust, mixed matrix polyvinylidene fluoride-co-hexafluoropropylene (PcH) nullofiber membranes were fabricated incorporating different concentrations (1-5 wt%) of carbon nullotubes (CNTs) as nullofillers to impart additional mechanical and hydrophobic properties. The electrospun membrane has been designed to have two cohesive layers, a thin CNT/PcH top layer and a thick neat PcH bottom layer. Through different characterization techniques, CNTs were found to be widely distributed on/in the nullofibers, where more beads-on-string were formed at higher CNT content. However, the beads-on-string did not significantly affect the membrane porosity and pore size, as well as did not degrade the MD performance. Highly-porous structure was observed for all membranes and the nullofiber membrane showed comparable pore sizes with a commercial flat-sheet PVDF membrane but at a much higher porosity ( > 85%). The contact angle increased to superhydrophobic at 158.5 degrees upon the incorporation of 5 wt% CNTs in the nullofiber due to increased roughness and added effect of hydrophobic CNTs. The liquid entry pressure also increased when 5 wt% CNT was added compared to the neat PcH nullofiber membrane. The resulting flux of the 5 wt% CNT-incorporated nullofiber membrane (2429.5 L/m(2) h) was consistently higher than the commercial PVDF membrane (18-18.5 L/m(2) h), with an average increase of 33-59% depending on the feed water type (35 or 70 g/L NaCI solution) without compromising the salt rejection ( > 99.99%). The present nullofiber membranes containing CNTs with one-step electrospinning fabrication show high potential for DCMD desalination application. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2016, "Volume": 502, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 158, "End Page": 170, "Article Number": null, "DOI": "10.1016/j.memsci.2015.12.014", "DOI Link": "http://dx.doi.org/10.1016/j.memsci.2015.12.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368631400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JW; Leung, FKC; Stuart, MCA; Kajitani, T; Fukushima, T; van der Giessen, E; Feringa, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jiawen; Leung, Franco King-Chi; Stuart, Marc C. A.; Kajitani, Takashi; Fukushima, Takanori; van der Giessen, Erik; Feringa, Ben L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial muscle-like function from hierarchical supramolecular assembly of photoresponsive molecular motors", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A striking feature of living systems is their ability to produce motility by amplification of collective molecular motion from the nulloscale up to macroscopic dimensions. Some of nature's protein motors, such as myosin in muscle tissue, consist of a hierarchical supramolecular assembly of very large proteins, in which mechanical stress induces a coordinated movement. However, artificial molecular muscles have often relied on covalent polymer-based actuators. Here, we describe the macroscopic contractile muscle-like motion of a supramolecular system (comprising 95% water) formed by the hierarchical self-assembly of a photoresponsive amphiphilic molecular motor. The molecular motor first assembles into nullofibres, which further assemble into aligned bundles that make up centimetre-long strings. Irradiation induces rotary motion of the molecular motors, and propagation and accumulation of this motion lead to contraction of the fibres towards the light source. This system supports large-amplitude motion, fast response, precise control over shape, as well as weight-lifting experiments in water and air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 132, "End Page": 138, "Article Number": null, "DOI": "10.1038/NCHEM.2887", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2887", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423144000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rutz, AL; Hyland, KE; Jakus, AE; Burghardt, WR; Shah, RN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rutz, Alexandra L.; Hyland, Kelly E.; Jakus, Adam E.; Burghardt, Wesley R.; Shah, Ramille N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Multimaterial Bioink Method for 3D Printing Tunable, Cell-Compatible Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A multimaterial bio-ink method using polyethylene glycol crosslinking is presented for expanding the biomaterial palette required for 3D bioprinting of more mimetic and customizable tissue and organ constructs. Lightly crosslinked, soft hydrogels are produced from precursor solutions of various materials and 3D printed. Rheological and biological characterizations are presented, and the promise of this new bio-ink synthesis strategy is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2015, "Volume": 27, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1607, "End Page": 1614, "Article Number": null, "DOI": "10.1002/adma.201405076", "DOI Link": "http://dx.doi.org/10.1002/adma.201405076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350541100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CH; Wu, DY; Li, Z; Zhang, R; Kuai, CG; Zhao, XR; Dong, CK; Qiao, SZ; Liu, H; Du, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Cui-Hong; Wu, Deyao; Li, Zhe; Zhang, Rui; Kuai, Chun-Guang; Zhao, Xue-Ru; Dong, Cun-Ku; Qiao, Shi-Zhang; Liu, Hui; Du, Xi-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ruthenium-Based Single-Atom Alloy with High Electrocatalytic Activity for Hydrogen Evolution", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly efficient and stable catalysts for the hydrogen evolution reaction, especially in alkaline conditions are crucial for the practical demands of electrochemical water splitting. Here, the synthesis of a novel RuAu single-atom alloy (SAA) by laser ablation in liquid is reported. The SAA exhibits a high stability and a low overpotential, 24 mV@10 mA cm(-2), which is much lower than that of a Pt/C catalyst (46 mV) in alkaline media. Moreover, the turnover frequency of RuAu SAA is three times that of Pt/C catalyst. Density functional theory computation indicates the excellent catalytic activity of RuAu SAAs originates from the relay catalysis of Ru and Au active sites. This work opens a new avenue toward high-performance SAAs via fast quenching of immiscible metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2019, "Volume": 9, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803913, "DOI": "10.1002/aenm.201803913", "DOI Link": "http://dx.doi.org/10.1002/aenm.201803913", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468796000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, K; Wang, JM; Liu, DY; Lei, CX; Liu, D; Lei, WW; Fu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Kai; Wang, Jiemin; Liu, Dingyao; Lei, Chuxin; Liu, Dan; Lei, Weiwei; Fu, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Thermoconductive, Thermostable, and Super-Flexible Film by Engineering 1D Rigid Rod-Like Aramid nullofiber/2D Boron Nitride nullosheets", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-based thermal management materials have many irreplaceable advantages not found in metals or ceramics, such as easy processing, low density, and excellent flexibility. However, their limited thermal conductivity and unsatisfactory resistance to elevated temperatures (<200 degrees C) still prevent effective heat dissipation during applications with high-temperature conditions or powerful operation. Therefore, herein highly thermoconductive and thermostable polymer nullocomposite films prepared by engineering 1D aramid nullofiber (ANF) with worm-like microscopic morphologies into rigid rod-like structures with 2D boron nitride nullosheets (BNNS) are reported. With no coils or entanglements, the rigid polymer chain enables a well-packed crystalline structure resulting in a 20-fold (or greater) increase in axial thermal conductivity. Additionally, strong interfacial interactions between the weaved ANF rod and the stacked BNNS facilitate efficient heat flux through the 1D/2D configuration. Hence, unprecedented in-plane thermal conductivities as high as 46.7 W m(-1) K-1 can be achieved at only 30 wt% BNNS loading, a value of 137% greater than that of a worm-like ANF/BNNS counterpart. Moreover, the thermally stable nullocomposite films with light weight (28.9 W m(-1) K-1/10(3) (kg m(-3))) and high strength (>100 MPa, 450 degrees C) enable effective thermal management for microelectrodes operating at temperatures beyond 200 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 32, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906939, "DOI": "10.1002/adma.201906939", "DOI Link": "http://dx.doi.org/10.1002/adma.201906939", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507437200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, K; Cui, XQ; Gu, L; Yu, SS; Fan, XF; Luo, MC; Xu, S; Li, NB; Zheng, LR; Zhang, QH; Ma, JY; Gong, Y; Lv, F; Wang, K; Huang, HH; Zhang, W; Guo, SJ; Zheng, WT; Liu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Kun; Cui, Xiaoqiang; Gu, Lin; Yu, Shansheng; Fan, Xiaofeng; Luo, Mingchuan; Xu, Shan; Li, Ningbo; Zheng, Lirong; Zhang, Qinghua; Ma, Jingyuan; Gong, Yue; Lv, Fan; Wang, Kai; Huang, Haihua; Zhang, Wei; Guo, Shaojun; Zheng, Weitao; Liu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom cobalt array bound to distorted 1T MoS2 with ensemble effect for hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The grand challenge in the development of atomically dispersed metallic catalysts is their low metal-atom loading density, uncontrollable localization and ambiguous interactions with supports, posing difficulty in maximizing their catalytic performance. Here, we achieve an interface catalyst consisting of atomic cobalt array covalently bound to distorted 1T MoS2 nullosheets (SA Co-D 1T MoS2). The phase of MoS2 transforming from 2H to D-1T, induced by strain from lattice mismatch and formation of Co-S covalent bond between Co and MoS2 during the assembly, is found to be essential to form the highly active single-atom array catalyst. SA Co-D 1T MoS2 achieves Pt-like activity toward HER and high long-term stability. Active-site blocking experiment together with density functional theory (DFT) calculations reveal that the superior catalytic behaviour is associated with an ensemble effect via the synergy of Co adatom and S of the D-1T MoS2 support by tuning hydrogen binding mode at the interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5231, "DOI": "10.1038/s41467-019-12997-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12997-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497691000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, YP; Dong, Y; Guo, S; Jiang, L; Kang, HJ; Wang, TM; Wen, B; Wang, ZJ; Jie, JC; Cao, ZQ; Ruan, HH; Li, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yiping; Dong, Yong; Guo, Sheng; Jiang, Li; Kang, Huijun; Wang, Tongmin; Wen, Bin; Wang, Zhijun; Jie, Jinchuan; Cao, Zhiqiang; Ruan, Haihui; Li, Tingju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Promising New Class of High-Temperature Alloys: Eutectic High-Entropy Alloys", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) can have either high strength or high ductility, and a simultaneous achievement of both still constitutes a tough challenge. The inferior castability and compositional segregation of HEAs are also obstacles for their technological applications. To tackle these problems, here we proposed a novel strategy to design HEAs using the eutectic alloy concept, i.e. to achieve a microstructure composed of alternating soft fcc and hard bcc phases. As a manifestation of this concept, an AlCoCrFeNi2.1 (atomic portion) eutectic high-entropy alloy (EHEA) was designed. The as-cast EHEA possessed a fine lamellar fcc/B2 microstructure, and showed an unprecedented combination of high tensile ductility and high fracture strength at room temperature. The excellent mechanical properties could be kept up to 700 degrees C. This new alloy design strategy can be readily adapted to large-scale industrial production of HEAs with simultaneous high fracture strength and high ductility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 828, "Times Cited, All Databases": 839, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6200, "DOI": "10.1038/srep06200", "DOI Link": "http://dx.doi.org/10.1038/srep06200", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340933300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JD; Ruan, CS; Xie, HH; Li, ZB; Wang, HY; Chu, PK; Yu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jundong; Ruan, Changshun; Xie, Hanhan; Li, Zhibin; Wang, Huaiyu; Chu, Paul K.; Yu, Xue-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black-Phosphorus-Incorporated Hydrogel as a Sprayable and Biodegradable Photothermal Platform for Postsurgical Treatment of Cancer", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PIT) is a fledgling therapeutic strategy for cancer treatment with minimal invasiveness but clinical adoption has been stifled by concerns such as insufficient biodegradability of the PTT agents and lack of an efficient delivery system. Here, black phosphorus (BP) nullosheets are incorporated with a thermosensitive hydrogel [poly(oplactide)-poly(ethylene glycol)-poly(bplactide) (PDLLA-PEG-PDLLA: PLEL)] to produce a new PTT system for postoperative treatment of cancer. The BP@PLEL hydrogel exhibits excellent near infrared (NIR) photothermal performance and a rapid NIR-induced sol-gel transition as well as good biodegradability and biocompatibility in vitro and in vivo. Based on these merits, an in vivo PTT postoperative treatment strategy is established. Under N IR irradiation, the sprayed BP@PLEL hydrogel enables rapid gelation forming a gelled membrane on wounds and offers high PTT efficacy to eliminate residual tumor tissues after tumor removal surgery. Furthermore, the good photothermal antibacterial performance prevents infection and this efficient and biodegradable PTT system is very promising in postoperative treatment of cancer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700848, "DOI": "10.1002/advs.201700848", "DOI Link": "http://dx.doi.org/10.1002/advs.201700848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435852800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, WR; Zhang, HB; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Weiren; Zhang, Huabin; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exposing unsaturated Cu1-O2 sites in nulloscale Cu-MOF for efficient electrocatalytic hydrogen evolution", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive metal-organic framework (MOF) materials have been recently considered as effective electrocatalysts. However, they usually suffer from two major drawbacks, poor electrochemical stability and low electrocatalytic activity in bulk form. Here, we have developed a rational strategy to fabricate a promising electrocatalyst composed of a nulloscale conductive copper-based MOF (Cu-MOF) layer fully supported over synergetic iron hydr(oxy)oxide [Fe(OH)(x)] nulloboxes. Owing to the highly exposed active centers, enhanced charge transfer, and robust hollow nullostructure, the obtained Fe(OH)(x)@Cu-MOF nulloboxes exhibit superior activity and stability for the electrocatalytic hydrogen evolution reaction (HER). Specifically, it needs an overpotential of 112 mV to reach a current density of 10 mA cm(-2) with a small Tafel slope of 76 mV dec(-1). X-ray absorption fine structure spectroscopy combined with density functional theory calculations unravels that the highly exposed coordinatively unsaturated Cu-1-O-2 centers could effectively accelerate the formation of key *H intermediates toward fast HER kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg2580", "DOI": "10.1126/sciadv.abg2580", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg2580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645464500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ilyas, RA; Zuhri, MYM; Aisyah, HA; Asyraf, MRM; Hassan, SA; Zainudin, ES; Sapuan, SM; Sharma, S; Bangar, SP; Jumaidin, R; Nawab, Y; Faudzi, AAM; Abral, H; Asrofi, M; Syafri, E; Sari, NH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ilyas, R. A.; Zuhri, M. Y. M.; Aisyah, H. A.; Asyraf, M. R. M.; Hassan, S. A.; Zainudin, E. S.; Sapuan, S. M.; Sharma, S.; Bangar, S. P.; Jumaidin, R.; Nawab, Y.; Faudzi, A. A. M.; Abral, H.; Asrofi, M.; Syafri, E.; Sari, N. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural Fiber-Reinforced Polylactic Acid, Polylactic Acid Blends and Their Composites for Advanced Applications", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polylactic acid (PLA) is a thermoplastic polymer produced from lactic acid that has been chiefly utilized in biodegradable material and as a composite matrix material. PLA is a prominent biomaterial that is widely used to replace traditional petrochemical-based polymers in various applications owing environmental concerns. Green composites have gained greater attention as ecological consciousness has grown since they have the potential to be more appealing than conventional petroleum-based composites, which are toxic and nonbiodegradable. PLA-based composites with natural fiber have been extensively utilized in a variety of applications, from packaging to medicine, due to their biodegradable, recyclable, high mechanical strength, low toxicity, good barrier properties, friendly processing, and excellent characteristics. A summary of natural fibers, green composites, and PLA, along with their respective properties, classification, functionality, and different processing methods, are discussed to discover the natural fiber-reinforced PLA composite material development for a wide range of applications. This work also emphasizes the research and properties of PLA-based green composites, PLA blend composites, and PLA hybrid composites over the past few years. PLA's potential as a strong material in engineering applications areas is addressed. This review also covers issues, challenges, opportunities, and perspectives in developing and characterizing PLA-based green composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 202, "DOI": "10.3390/polym14010202", "DOI Link": "http://dx.doi.org/10.3390/polym14010202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752546100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, PD; Tran, TV; Orio, M; Torelli, S; Truong, QD; Nayuki, K; Sasaki, Y; Chiam, SY; Yi, R; Honma, I; Barber, J; Artero, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tran, Phong D.; Tran, Thu V.; Orio, Maylis; Torelli, Stephane; Truong, Quang Duc; Nayuki, Keiichiro; Sasaki, Yoshikazu; Chiam, Sing Yang; Yi, Ren; Honma, Itaru; Barber, James; Artero, Vincent", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum sulfides are very attractive noble-metal-free electrocatalysts for the hydrogen evolution reaction (HER) from water. The atomic structure and identity of the catalytically active sites have been well established for crystalline molybdenum disulfide (c-MoS2) but not for amorphous molybdenum sulfide (a-MoSx), which exhibits significantly higher HER activity compared to its crystalline counterpart. Here we show that HER-active a-MoSx, prepared either as nulloparticles or as films, is a molecular-based coordination polymer consisting of discrete [Mo3S13](2-) building blocks. Of the three terminal disulfide (S-2(2-)) ligands within these clusters, two are shared to form the polymer chain. The third one remains free and generates molybdenum hydride moieties as the active site under H-2 evolution conditions. Such a molecular structure therefore provides a basis for revisiting the mechanism of a-MoSx catalytic activity, as well as explaining some of its special properties such as reductive activation and corrosion. Our findings open up new avenues for the rational optimization of this HER electrocatalyst as an alternative to platinum.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 513, "Times Cited, All Databases": 531, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 640, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4588", "DOI Link": "http://dx.doi.org/10.1038/NMAT4588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376528000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Wang, L; Cao, Z; Kozlov, SM; de Arquer, FPG; Dinh, CT; Li, J; Wang, ZY; Zheng, XL; Zhang, LS; Wen, YZ; Voznyy, O; Comin, R; De Luna, P; Regier, T; Bi, WL; Alp, EE; Pao, CW; Zheng, LR; Hu, YF; Ji, YJ; Li, YY; Zhang, Y; Cavallo, L; Peng, HS; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bo; Wang, Lie; Cao, Zhen; Kozlov, Sergey M.; Garcia de Arquer, F. Pelayo; Dinh, Cao Thang; Li, Jun; Wang, Ziyun; Zheng, Xueli; Zhang, Longsheng; Wen, Yunzhou; Voznyy, Oleksandr; Comin, Riccardo; De Luna, Phil; Regier, Tom; Bi, Wenli; Alp, E. Ercan; Pao, Chih-Wen; Zheng, Lirong; Hu, Yongfeng; Ji, Yujin; Li, Youyong; Zhang, Ye; Cavallo, Luigi; Peng, Huisheng; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-valence metals improve oxygen evolution reaction performance by modulating 3dmetal oxidation cycle energetics", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multimetal oxyhydroxides have recently been reported that outperform noble metal catalysts for oxygen evolution reaction (OER). In such 3d-metal-based catalysts, the oxidation cycle of 3dmetals has been posited to act as the OER thermodynamic-limiting process; however, further tuning of its energetics is challenging due to similarities among the electronic structures of neighbouring 3dmetal modulators. Here we report a strategy to reprogram the Fe, Co and Ni oxidation cycles by incorporating high-valence transition-metal modulators X (X = W, Mo, Nb, Ta, Re and MoW). We use in situ and ex situ soft and hard X-ray absorption spectroscopies to characterize the oxidation transition in modulated NiFeX and FeCoX oxyhydroxide catalysts, and conclude that the lower OER overpotential is facilitated by the readier oxidation transition of 3dmetals enabled by high-valence modulators. We report an similar to 17-fold mass activity enhancement compared with that for the OER catalysts widely employed in industrial water-splitting electrolysers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 985, "End Page": 992, "Article Number": null, "DOI": "10.1038/s41929-020-00525-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00525-6", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579724100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZX; Zhang, X; Kang, YK; Yu, CC; Wen, YY; Hu, ML; Meng, D; Song, WY; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhenxing; Zhang, Xin; Kang, Yikun; Yu, Cheng Cheng; Wen, Yangyang; Hu, Mingliang; Meng, Dong; Song, Weiyu; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of Co-LDH@MOF Heterojunction in Highly Stable and Efficient Oxygen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical splitting of water into hydrogen and oxygen is considered one of the most promising approaches to generate clean and sustainable energy. However, the low efficiency of the oxygen evolution reaction (OER) acts as a bottleneck in the water splitting process. Herein, interface engineering heterojunctions between ZIF-67 and layered double hydroxide (LDH) are designed to enhance the catalytic activity of the OER and the stability of Co-LDH. The interface is built by the oxygen (O) of Co-LDH and nitrogen (N) of the 2-methylimidazole ligand in ZIF-67, which modulates the local electronic structure of the catalytic active site. Density functional theory calculations demonstrate that the interfacial interaction can enhance the strength of the Co-O-out bond in Co-LDH, which makes it easier to break the H-O-out bond and results in a lower free energy change in the potential-determining step at the heterointerface in the OER process. Therefore, the Co-LDH@ZIF-67 exhibits superior OER activity with a low overpotential of 187 mV at a current density of 10 mA cm(-2) and long-term electrochemical stability for more than 50 h. This finding provides a design direction for improving the catalytic activity of OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002631, "DOI": "10.1002/advs.202002631", "DOI Link": "http://dx.doi.org/10.1002/advs.202002631", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591882300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, CG; Bai, SQ; Liu, YT; Tang, YS; Chen, LD; Zhao, XB; Zhu, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Chenguang; Bai, Shengqiang; Liu, Yintu; Tang, Yunshan; Chen, Lidong; Zhao, Xinbing; Zhu, Tiejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state thermoelectric technology offers a promising solution for converting waste heat to useful electrical power. Both high operating temperature and high figure of merit zT are desirable for high-efficiency thermoelectric power generation. Here we report a high zT of similar to 1.5 at 1,200 K for the p-type FeNbSb heavy-band half-Heusler alloys. High content of heavier Hf dopant simultaneously optimizes the electrical power factor and suppresses thermal conductivity. Both the enhanced point-defect and electron-phonon scatterings contribute to a significant reduction in the lattice thermal conductivity. An eight couple prototype thermoelectric module exhibits a high conversion efficiency of 6.2% and a high power density of 2.2 Wcm(-2) at a temperature difference of 655 K. These findings highlight the optimization strategy for heavy-band thermoelectric materials and demonstrate a realistic prospect of high-temperature thermoelectric modules based on half-Heusler alloys with low cost, excellent mechanical robustness and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1041, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8144, "DOI": "10.1038/ncomms9144", "DOI Link": "http://dx.doi.org/10.1038/ncomms9144", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363015800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ZH; Zhou, LL; Li, SX; Liu, D; Li, YH; Gao, YK; Liu, YB; Dai, YJ; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Zhihao; Zhou, Linglin; Li, Shaoxin; Liu, Di; Li, Yanhong; Gao, Yikui; Liu, Yuebo; Dai, Yejing; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selection rules of triboelectric materials for direct-current triboelectric nullogenerator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid development of Internet of Things and artificial intelligence brings increasing attention on the harvesting of distributed energy by using triboelectric nullogenerator (TENG), especially the direct current TENG (DC-TENG). It is essential to select appropriate triboelectric materials for obtaining a high performance TENG. In this work, we provide a set of rules for selecting the triboelectric materials for DC-TENG based on several basic parameters, including surface charge density, friction coefficient, polarization, utilization rate of charges, and stability. On the basis of the selection rules, polyvinyl chloride, used widely in industry rather than in TENG, is selected as the triboelectric layer. Its effective charge density can reach up to similar to 8.80 mC m(-2) in a microstructure-designed DC-TENG, which is a new record for all kinds of TENGs. This work can offer a basic guideline for the triboelectric materials selection and promote the practical applications of DC-TENG.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4686, "DOI": "10.1038/s41467-021-25046-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25046-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684184800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tongay, S; Sahin, H; Ko, C; Luce, A; Fan, W; Liu, K; Zhou, J; Huang, YS; Ho, CH; Yan, JY; Ogletree, DF; Aloni, S; Ji, J; Li, SS; Li, JB; Peeters, FM; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tongay, Sefaattin; Sahin, Hasan; Ko, Changhyun; Luce, Alex; Fan, Wen; Liu, Kai; Zhou, Jian; Huang, Ying-Sheng; Ho, Ching-Hwa; Yan, Jinyuan; Ogletree, D. Frank; Aloni, Shaul; Ji, Jie; Li, Shushen; Li, Jingbo; Peeters, F. M.; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolayer behaviour in bulk ReS2 due to electronic and vibrational decoupling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconducting transition metal dichalcogenides consist of monolayers held together by weak forces where the layers are electronically and vibrationally coupled. Isolated monolayers show changes in electronic structure and lattice vibration energies, including a transition from indirect to direct bandgap. Here we present a new member of the family, rhenium disulphide (ReS2), where such variation is absent and bulk behaves as electronically and vibrationally decoupled monolayers stacked together. From bulk to monolayers, ReS2 remains direct bandgap and its Raman spectrum shows no dependence on the number of layers. Interlayer decoupling is further demonstrated by the insensitivity of the optical absorption and Raman spectrum to interlayer distance modulated by hydrostatic pressure. Theoretical calculations attribute the decoupling to Peierls distortion of the 1T structure of ReS2, which prevents ordered stacking and minimizes the interlayer overlap of wavefunctions. Such vanishing interlayer coupling enables probing of two-dimensional-like systems without the need for monolayers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 967, "Times Cited, All Databases": 1055, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3252, "DOI": "10.1038/ncomms4252", "DOI Link": "http://dx.doi.org/10.1038/ncomms4252", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332666700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Sun, XL; Zheng, XP; Li, B; Gao, DP; Zhang, SF; Wu, X; Li, S; Gong, JQ; Luther, JM; Li, ZA; Zhu, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhen; Sun, Xianglang; Zheng, Xiaopeng; Li, Bo; Gao, Danpeng; Zhang, Shoufeng; Wu, Xin; Li, Shuai; Gong, Jianqiu; Luther, Joseph M.; Li, Zhong'an; Zhu, Zonglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs can be thermally unstable. We report a thermally robust hole-selective layer comprised of nickel oxide (NiOx) nulloparticle film with a surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that can improve and stabilize the NiOx/perovskite interface. The energetic alignment and favorable contact and binding between NiOx/MeO-4PADBC and perovskite reduced the voltage deficit of PSCs with various perovskite compositions and led to strong interface toughening effects under thermal stress. The resulting 1.53-electron-volt devices achieved 25.6% certified power conversion efficiency and maintained >90% of their initial efficiency after continuously operating at 65 degrees Celsius for 1200 hours under 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2023, "Volume": 382, "Issue": 6668, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": 289, "Article Number": null, "DOI": "10.1126/science.ade9637", "DOI Link": "http://dx.doi.org/10.1126/science.ade9637", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001138559400027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, P; Yin, LC; Yang, YQ; Liu, G; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Ping; Yin, Li-Chang; Yang, Yong-Qiang; Liu, Gang; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Increasing the Visible Light Absorption of Graphitic Carbon Nitride (Melon) Photocatalysts by Homogeneous Self-Modification with Nitrogen Vacancies", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel reduced melon photocatalyst with a bandgap of 2.03 eV developed here has a widened visible light absorption range and suppressed radiative recombination of photo-excited charge carriers due to the homogeneous self-modification with nitrogen vacancies. As a consequence, the reduced melon shows a much superior photocatalytic activity compared to the pristine melon in generating center dot OH radicals and degrading the organic pollutant Rhodamine B.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 678, "Times Cited, All Databases": 694, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2014, "Volume": 26, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8046, "End Page": 8052, "Article Number": null, "DOI": "10.1002/adma.201404057", "DOI Link": "http://dx.doi.org/10.1002/adma.201404057", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346263100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akbari, A; Sheath, P; Martin, ST; Shinde, DB; Shaibani, M; Banerjee, PC; Tkacz, R; Bhattacharyya, D; Majumder, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akbari, Abozar; Sheath, Phillip; Martin, Samuel T.; Shinde, Dhanraj B.; Shaibani, Mahdokht; Banerjee, Parama Chakraborty; Tkacz, Rachel; Bhattacharyya, Dibakar; Majumder, Mainak", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-area graphene-based nullofiltration membranes by shear alignment of discotic nematic liquid crystals of graphene oxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene-based membranes demonstrating ultrafast water transport, precise molecular sieving of gas and solvated molecules shows great promise as novel separation platforms; however, scale-up of these membranes to large-areas remains an unresolved problem. Here we demonstrate that the discotic nematic phase of graphene oxide (GO) can be shear aligned to form highly ordered, continuous, thin films of multi-layered GO on a support membrane by an industrially adaptable method to produce large-area membranes (13 X 14 cm(2)) in <5 s. Pressure driven transport data demonstrate high retention (490%) for charged and uncharged organic probe molecules with a hydrated radius above 5 A as well as modest (30-40%) retention of monovalent and divalent salts. The highly ordered graphene sheets in the plane of the membrane make organized channels and enhance the permeability (71 +/- 5lm(-2) hr(-1) bar(-1) for 150 +/- 15 nm thick membranes).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10891, "DOI": "10.1038/ncomms10891", "DOI Link": "http://dx.doi.org/10.1038/ncomms10891", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371719700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, Y; Yu, XQ; Yin, YX; Nam, KW; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Ya; Yu, Xiqian; Yin, Yaxia; Nam, Kyung-Wan; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode materials is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na+ ions per formula unit. However, increasing the Na content in PBAs cathode materials remains a major challenge. Here we show that sodium iron hexacyanoferrate with high Na content can be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mAh center dot g(-1) and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism has been systematically studied by in situ Raman spectroscopy, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate can function as a plenteous Na reservoir and has great potential as a cathode material for practical Na-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 117, "End Page": 128, "Article Number": null, "DOI": "10.1007/s12274-014-0588-7", "DOI Link": "http://dx.doi.org/10.1007/s12274-014-0588-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348200300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, FF; Chen, ZY; Zhao, Z; Wang, H; Shang, LR; Gu, ZZ; Zhao, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Fanfan; Chen, Zhuoyue; Zhao, Ze; Wang, Huan; Shang, Luoran; Gu, Zhongze; Zhao, Yuanjin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-inspired self-healing structural color hydrogel", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biologically inspired self-healing structural color hydrogels were developed by adding a glucose oxidase (GOX)- and catalase (CAT)-filled glutaraldehyde cross-linked BSA hydrogel into methacrylated gelatin (GelMA) inverse opal scaffolds. The composite hydrogel materials with the polymerized GelMA scaffold could maintain the stability of an inverse opal structure and its resultant structural colors, whereas the protein hydrogel filler could impart self-healing capability through the reversible covalent attachment of glutaraldehyde to lysine residues of BSA and enzyme additives. A series of unprecedented structural color materials could be created by assembling and healing the elements of the composite hydrogel. In addition, as both the GelMA and the protein hydrogels were derived from organisms, the composite materials presented high biocompatibility and plasticity. These features of self-healing structural color hydrogels make them excellent functional materials for different applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2017, "Volume": 114, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5900, "End Page": 5905, "Article Number": null, "DOI": "10.1073/pnas.1703616114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1703616114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402703800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abellán-Llobregat, A; Jeerapan, I; Bandodkar, A; Vidal, L; Canals, A; Wang, J; Morallón, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abellan-Llobregat, A.; Jeerapan, Itthipon; Bandodkar, A.; Vidal, L.; Canals, A.; Wang, J.; Morallon, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stretchable and screen-printed electrochemical sensor for glucose determination in human perspiration", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we present two types of all-printable, highly stretchable, and inexpensive devices based on platinum (Pt)-decorated graphite for glucose determination in physiological fluids. Said devices are: a non-enzymatic sensor and an enzymatic biosensor, the latter showing promising results. Glucose has been quantified by measuring hydrogen peroxide (H2O2) reduction by chronoamperometry at -0.35 V (vs pseudo-Ag/AgCI) using glucose oxidase immobilized on Pt-decorated graphite. The sensor performs well for the quantification of glucose in phosphate buffer solution (0.25 M PBS, pH 7.0), with a linear range between 0 mM and 0.9 mM, high sensitivity and selectivity, and a low limit of detection (LOD). Thus, it provides an alternative non-invasive and on-body quantification of glucose levels in human perspiration. This biosensor has been successfully applied on real human perspiration samples and results also show a significant correlation between glucose concentration in perspiration and glucose concentration in blood measured by a commercial glucose meter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2017, "Volume": 91, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 885, "End Page": 891, "Article Number": null, "DOI": "10.1016/j.bios.2017.01.058", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2017.01.058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395599000122", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, S; Li, TX; Tong, Z; Chao, JW; Zhai, TY; Xu, JX; Yan, TS; Wu, MQ; Xu, ZY; Bao, H; Deng, T; Wang, RZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Si; Li, Tingxian; Tong, Zhen; Chao, Jingwei; Zhai, Tianyao; Xu, Jiaxing; Yan, Taisen; Wu, Minqiang; Xu, Zhenyuan; Bao, Hua; Deng, Tao; Wang, Ruzhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Thermally Conductive Phase Change Composites by Large-Size Oriented Graphite Sheets for Scalable Thermal Energy Harvesting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient thermal energy harvesting using phase-change materials (PCMs) has great potential for cost-effective thermal management and energy storage applications. However, the low thermal conductivity of PCMs (K-PCM) is a long-standing bottleneck for high-power-density energy harvesting. Although PCM-based nullocomposites with an enhanced thermal conductivity can address this issue, achieving a higher K (>10 W m(-1) K-1) at filler loadings below 50 wt% remains challenging. A strategy for synthesizing highly thermally conductive phase-change composites (PCCs) by compression-induced construction of large aligned graphite sheets inside PCCs is demonstrated. The millimeter-sized graphite sheet consists of lateral van-der-Waals-bonded and oriented graphite nulloplatelets at the micro/nulloscale, which together with a thin PCM layer between the sheets synergistically enhance K-PCM in the range of 4.4-35.0 W m(-1) K-1 at graphite loadings below 40.0 wt%. The resulting PCCs also demonstrate homogeneity, no leakage, and superior phase change behavior, which can be easily engineered into devices for efficient thermal energy harvesting by coordinating the sheet orientation with the thermal transport direction. This method offers a promising route to high-power-density and low-cost applications of PCMs in large-scale thermal energy storage, thermal management of electronics, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 31, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1905099, "DOI": "10.1002/adma.201905099", "DOI Link": "http://dx.doi.org/10.1002/adma.201905099", "Book DOI": null, "Early Access Date": "OCT 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490755300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, YZ; Chen, PN; Wang, L; Li, SY; Wang, ZY; Abed, J; Mao, XN; Min, YM; Dinh, CT; De Luna, P; Huang, R; Zhang, LS; Wang, L; Wang, LP; Nielsen, RJ; Li, HH; Zhuang, TT; Ke, CC; Voznyy, O; Hu, YF; Li, YY; Goddard, WA ; Zhang, B; Peng, HS; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Yunzhou; Chen, Peining; Wang, Lu; Li, Shangyu; Wang, Ziyun; Abed, Jehad; Mao, Xinnull; Min, Yimeng; Dinh, Cao Thang; De Luna, Phil; Huang, Rui; Zhang, Longsheng; Wang, Lie; Wang, Liping; Nielsen, Robert J.; Li, Huihui; Zhuang, Taotao; Ke, Changchun; Voznyy, Oleksandr; Hu, Yongfeng; Li, Youyong; Goddard, William A., III; Zhang, Bo; Peng, Huisheng; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing Highly Active Ru Sites by Suppressing Lattice Oxygen Participation in Acidic Water Oxidation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In hydrogen production, the anodic oxygen evolution reaction (OER) limits the energy conversion efficiency and also impacts stability in proton-exchange membrane water electrolyzers. Widely used Ir-based catalysts suffer from insufficient activity, while more active Ru-based catalysts tend to dissolve under OER conditions. This has been associated with the participation of lattice oxygen (lattice oxygen oxidation mechanism (LOM)), which may lead to the collapse of the crystal structure and accelerate the leaching of active Ru species, leading to low operating stability. Here we develop Sr-Ru-Ir ternary oxide electrocatalysts that achieve high OER activity and stability in acidic electrolyte. The catalysts achieve an overpotential of 190 mV at 10 mA cm(-2) and the overpotential remains below 225 mV following 1,500 h of operation. X-ray absorption spectroscopy and O-18 isotope-labeled online mass spectroscopy studies reveal that the participation of lattice oxygen during OER was suppressed by interactions in the Ru-O-Ir local structure, offering a picture of how stability was improved. The electronic structure of active Ru sites was modulated by Sr and Ir, optimizing the binding energetics of OER oxo-intermediates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 350, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2021, "Volume": 143, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6482, "End Page": 6490, "Article Number": null, "DOI": "10.1021/jacs.1c00384", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c00384", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648704100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, JP; Song, XF; Liu, JZ; Yan, Z; Huo, CX; Zhang, SL; Su, M; Liao, L; Wang, WH; Ni, ZH; Hao, YF; Zeng, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Jianping; Song, Xiufeng; Liu, Jizi; Yan, Zhong; Huo, Chengxue; Zhang, Shengli; Su, Meng; Liao, Lei; Wang, Wenhui; Ni, Zhenhua; Hao, Yufeng; Zeng, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional antimonene single crystals grown by van der Waals epitaxy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unlike the unstable black phosphorous, another two-dimensional group-VA material, antimonene, was recently predicted to exhibit good stability and remarkable physical properties. However, the synthesis of high-quality monolayer or few-layer antimonenes, sparsely reported, has greatly hindered the development of this new field. Here, we report the van der Waals epitaxy growth of few-layer antimonene monocrystalline polygons, their atomical microstructure and stability in ambient condition. The high-quality, few-layer antimonene monocrystalline polygons can be synthesized on various substrates, including flexible ones, via van der Waals epitaxy growth. Raman spectroscopy and transmission electron microscopy reveal that the obtained antimonene polygons have buckled rhombohedral atomic structure, consistent with the theoretically predicted most stable beta-phase allotrope. The very high stability of antimonenes was observed after aging in air for 30 days. First-principle and molecular dynamics simulation results confirmed that compared with phosphorene, antimonene is less likely to be oxidized and possesses higher thermodynamic stability in oxygen atmosphere at room temperature. Moreover, antimonene polygons show high electrical conductivity up to 10(4)Sm(-1) and good optical transparency in the visible light range, promising in transparent conductive electrode applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 833, "Times Cited, All Databases": 864, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13352, "DOI": "10.1038/ncomms13352", "DOI Link": "http://dx.doi.org/10.1038/ncomms13352", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387971500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YQ; Liu, ST; Sun, LY; Wu, SS; Hu, GQ; Pang, XL; Smith, AT; Hu, CF; Zeng, SS; Wang, WX; Liu, YL; Zheng, MT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yuqiong; Liu, Shuting; Sun, Luyi; Wu, Shuangshuang; Hu, Guangqi; Pang, Xiaoliang; Smith, Andrew T.; Hu, Chaofan; Zeng, Songshan; Wang, Weixing; Liu, Yingliang; Zheng, Mingtao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong lifetime and efficient room temperature phosphorescent carbon dots through multi-confinement structure design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Room temperature phosphorescence materials have inspired extensive attention owing to their great potential in optical applications. However, it is hard to achieve a room temperature phosphorescence material with simultaneous long lifetime and high phosphorescence quantum efficiency. Herein, multi-confined carbon dots were designed and fabricated, enabling room temperature phosphorescence material with simultaneous ultralong lifetime, high phosphorescence quantum efficiency, and excellent stability. The multi-confinement by a highly rigid network, stable covalent bonding, and 3D spatial restriction efficiently rigidified the triplet excited states of carbon dots from non-radiative deactivation. The as-designed multi-confined carbon dots exhibit ultralong lifetime of 5.72 s, phosphorescence quantum efficiency of 26.36%, and exceptional stability against strong oxidants, acids and bases, as well as polar solvents. This work provides design principles and a universal strategy to construct metal-free room temperature phosphorescence materials with ultralong lifetime, high phosphorescence quantum efficiency, and high stability for promising applications, especially under harsh conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5591, "DOI": "10.1038/s41467-020-19422-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19422-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612233600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Zhao, TL; Ju, WW; Shi, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yue; Zhao, Tianlu; Ju, Wangwei; Shi, Siqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Materials discovery and design using machine learning", "Source Title": "JOURNAL OF MATERIOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The screening of novel materials with good performance and the modelling of quantitative structure-activity relationships (QSARs), among other issues, are hot topics in the field of materials science. Traditional experiments and computational modelling often consume tremendous time and resources and are limited by their experimental conditions and theoretical foundations. Thus, it is imperative to develop a new method of accelerating the discovery and design process for novel materials. Recently, materials discovery and design using machine learning have been receiving increasing attention and have achieved great improvements in both time efficiency and prediction accuracy. In this review, we first outline the typical mode of and basic procedures for applying machine learning in materials science, and we classify and compare the main algorithms. Then, the current research status is reviewed with regard to applications of machine learning in material property prediction, in new materials discovery and for other purposes. Finally, we discuss problems related to machine learning in materials science, propose possible solutions, and forecast potential directions of future research. By directly combining computational studies with experiments, we hope to provide insight into the parameters that affect the properties of materials, thereby enabling more efficient and target-oriented research on materials discovery and design. (C) 2017 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 885, "Times Cited, All Databases": 1022, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 159, "End Page": 177, "Article Number": null, "DOI": "10.1016/j.jmat.2017.08.002", "DOI Link": "http://dx.doi.org/10.1016/j.jmat.2017.08.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410727500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, S; Tang, YL; Hong, Z; Gonçalves, MAP; McCarter, MR; Klewe, C; Nguyen, KX; Gómez-Ortiz, F; Shafer, P; Arenholz, E; Stoica, VA; Hsu, SL; Wang, B; Ophus, C; Liu, JF; Nelson, CT; Saremi, S; Prasad, B; Mei, AB; Schlom, DG; Iñiguez, J; García-Fernández, P; Muller, DA; Chen, LQ; Junquera, J; Martin, LW; Ramesh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, S.; Tang, Y. L.; Hong, Z.; Goncalves, M. A. P.; McCarter, M. R.; Klewe, C.; Nguyen, K. X.; Gomez-Ortiz, F.; Shafer, P.; Arenholz, E.; Stoica, V. A.; Hsu, S. -L.; Wang, B.; Ophus, C.; Liu, J. F.; Nelson, C. T.; Saremi, S.; Prasad, B.; Mei, A. B.; Schlom, D. G.; Iniguez, J.; Garcia-Fernulldez, P.; Muller, D. A.; Chen, L. Q.; Junquera, J.; Martin, L. W.; Ramesh, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of room-temperature polar skyrmions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Complex topological configurations are fertile ground for exploring emergent phenomena and exotic phases in condensed-matter physics. For example, the recent discovery of polarization vortices and their associated complex-phase coexistence and response under applied electric fields in superlattices of (PbTiO3)(n)/(SrTiO3)(n) suggests the presence of a complex, multi-dimensional system capable of interesting physical responses, such as chirality, negative capacitance and large piezo-electric responses(1-3). Here, by varying epitaxial constraints, we discover room-temperature polar-skyrmion bubbles in a lead titanate layer confined by strontium titanate layers, which are imaged by atomic-resolution scanning transmission electron microscopy. Phase-field modelling and second-principles calculations reveal that the polar-skyrmion bubbles have a skyrmion number of +1, and resonullt soft-X-ray diffraction experiments show circular dichroism, confirming chirality. Such nullometre-scale polar-skyrmion bubbles are the electric analogues of magnetic skyrmions, and could contribute to the advancement of ferroelectrics towards functionalities incorporating emergent chirality and electrically controllable negative capacitance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 569, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2019, "Volume": 568, "Issue": 7752, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 368, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1092-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1092-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464950700051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, N; Chen, X; Krishna, R; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Ning; Chen, Xiong; Krishna, Rajamani; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ordered open channels found in two-dimensional covalent organic frameworks (2D COFs) could enable them to adsorb carbon dioxide. However, the frameworks' dense layer architecture results in low porosity that has thus far restricted their potential for carbon dioxide adsorption. Here we report a strategy for converting a conventional 2D COF into an outstanding platform for carbon dioxide capture through channel-wall functionalization. The dense layer structure enables the dense integration of functional groups on the channel walls, creating a new version of COFs with high capacity, reusability, selectivity, and separation productivity for flue gas. These results suggest that channel-wall functional engineering could be a facile and powerful strategy to develop 2D COFs for high-performance gas storage and separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 679, "Times Cited, All Databases": 727, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2015, "Volume": 54, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2986, "End Page": 2990, "Article Number": null, "DOI": "10.1002/anie.201411262", "DOI Link": "http://dx.doi.org/10.1002/anie.201411262", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350302300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, NN; Xu, DM; Wang, Z; Wang, FL; Liu, JR; Liu, W; Shao, Q; Liu, H; Gao, Q; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, nullnull; Xu, Dongmei; Wang, Zhou; Wang, Fenglong; Liu, Jiurong; Liu, Wei; Shao, Qian; Liu, Hu; Gao, Qiang; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving superior electromagnetic wave absorbers through the novel metal-organic frameworks derived magnetic porous carbon nullorods", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High absorption capacity and broad absorption bandwidth electromagnetic wave (EMW) absorption materials (namely, EMW absorbers) are highly desirable due to the interference with electronics and harms on human beings' health. In search for rational design on nullostructured absorbers, we have synthesized and demonstrated the rod-shape composites with Fe-containing magnetic nulloparticles (Fe3O4, Fe3C and Fe NPs) embedded into nullo-porous carbon (NPC) through pyrolysis of Fe-based metal-organic frameworks (MOFs). The morphologies, compositions, and graphitization degree of the Fe-MOFs derived magnetic NPC nullorods can be effectively controlled via adjusting the pyrolysis temperatures. The graphitization level has a significant influence on the permittivity of the composites upon variation of pyrolysis temperatures, thereby a tunable electromagnetic wave (EMW) absorption is observed. Consequently, the resulting magnetic NPC nullorods obtained at pyrolysis temperature of 600 and 700 degrees C exhibit the most remarkable EMW absorption performance with a strong reflection loss of -52.9 dB and broad effective bandwidth (f(e)) of 4.64 GHz at 3.07 mm. With a thickness of 3.5 mm, the f(e) for the magnetic NPC nullorods at 600 degrees C covers the whole X-band from 7.92 to 12.48 GHz. The noticeable EMW absorption performances have been greatly enhanced compared to those reported Fe3O4 based absorbers, owing to the synergy of multiple components and the porous structures inherited from MOFs. (c) 2019 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 145, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 433, "End Page": 444, "Article Number": null, "DOI": "10.1016/j.carbon.2019.01.028", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2019.01.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466073000046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morgan, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morgan, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resolving ruthenium: XPS studies of common ruthenium materials", "Source Title": "SURFACE AND INTERFACE ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray photoelectron spectroscopy (XPS) utilising monochromatic Al K radiation has been employed to study metallic ruthenium and the catalytically and technologically important ruthenium compounds RuO2, RuCl3, Ru(NO)(NO3)(3) and Ru(AcAc)(3). The results improve on the accuracy of already published Ru(3d) binding energies, expand known Ru(3p) binding energies and also report spin-orbit splitting for the core levels. For RuO2, the difference between anhydrous and hydrated samples is explored, and the effect on curve fitting such spectra is discussed. Analysis of RuCl3 has allowed, for the first time, the positive identification of Ru(OH)(3) by XPS. Copyright (c) 2015 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 861, "Times Cited, All Databases": 902, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 47, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1072, "End Page": 1079, "Article Number": null, "DOI": "10.1002/sia.5852", "DOI Link": "http://dx.doi.org/10.1002/sia.5852", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363025400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noel, NK; Stranks, SD; Abate, A; Wehrenfennig, C; Guarnera, S; Haghighirad, AA; Sadhanala, A; Eperon, GE; Pathak, SK; Johnston, MB; Petrozza, A; Herz, LM; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noel, Nakita K.; Stranks, Samuel D.; Abate, Antonio; Wehrenfennig, Christian; Guarnera, Simone; Haghighirad, Amir-Abbas; Sadhanala, Aditya; Eperon, Giles E.; Pathak, Sandeep K.; Johnston, Michael B.; Petrozza, Annamaria; Herz, Laura M.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-free organic-inorganic tin halide perovskites for photovoltaic applications", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Already exhibiting solar to electrical power conversion efficiencies of over 17%, organic-inorganic lead halide perovskite solar cells are one of the most promising emerging contenders in the drive to provide a cheap and clean source of energy. One concern however, is the potential toxicology issue of lead, a key component in the archetypical material. The most likely substitute is tin, which like lead, is also a group 14 metal. While organic-inorganic tin halide perovskites have shown good semiconducting behaviour, the instability of tin in its 2+ oxidation state has thus far proved to be an overwhelming challenge. Here, we report the first completely lead-free, CH3NH3SnI3 perovskite solar cell processed on a mesoporous TiO2 scaffold, reaching efficiencies of over 6% under 1 sun illumination. Remarkably, we achieve open circuit voltages over 0.88 V from a material which has a 1.23 eV band gap.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2157, "Times Cited, All Databases": 2294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3061, "End Page": 3068, "Article Number": null, "DOI": "10.1039/c4ee01076k", "DOI Link": "http://dx.doi.org/10.1039/c4ee01076k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340450100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GX; Su, ZH; Canil, L; Hughes, D; Aldamasy, MH; Dagar, J; Trofimov, S; Wang, LY; Zuo, WW; Jeronimo-Rendon, JJ; Byranvand, MM; Wang, CY; Zhu, R; Zhang, ZH; Yang, F; Nasti, G; Naydenov, B; Tsoi, WC; Li, Z; Gao, XY; Wang, ZK; Jia, Y; Unger, E; Saliba, M; Li, M; Abate, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guixiang; Su, Zhenhuang; Canil, Laura; Hughes, Declan; Aldamasy, Mahmoud H.; Dagar, Janardan; Trofimov, Sergei; Wang, Luyao; Zuo, Weiwei; Jeronimo-Rendon, Jose J.; Byranvand, Mahdi Malekshahi; Wang, Chenyue; Zhu, Rui; Zhang, Zuhong; Yang, Feng; Nasti, Giuseppe; Naydenov, Boris; Tsoi, Wing C.; Li, Zhe; Gao, Xingyu; Wang, Zhaokui; Jia, Yu; Unger, Eva; Saliba, Michael; Li, Meng; Abate, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient p-i-n perovskite solar cells that endure temperature variations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilized the perovskite black phase and improved solar cell performance using the ordered dipolar structure of beta-poly(1,1-difluoroethylene) to control perovskite film crystallization and energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimeters and 23.1% over 1 square centimeter, which retained 96 and 88% of the efficiency after 1000 hours of 1-sunmaximum power point tracking at 25 degrees and 75 degrees C, respectively. Devices under rapid thermal cycling between -60 degrees and +80 degrees C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2023, "Volume": 379, "Issue": 6630, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 399, "End Page": 403, "Article Number": null, "DOI": "10.1126/science.add7331", "DOI Link": "http://dx.doi.org/10.1126/science.add7331", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058669200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Avellan, A; Li, H; Liu, XT; Noel, V; Lou, ZM; Wang, Y; Kaegi, R; Henkelman, G; Lowry, GV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jiang; Avellan, Astrid; Li, Hao; Liu, Xitong; Noel, Vincent; Lou, Zimo; Wang, Yan; Kaegi, Raelf; Henkelman, Graeme; Lowry, Gregory V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur Loading and Speciation Control the Hydrophobicity, Electron Transfer, Reactivity, and Selectivity of Sulfidized nulloscale Zerovalent Iron", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfidized nulloscale zerovalent iron (SNZVI) is a promising material for groundwater remediation. However, the relationships between sulfur content and speciation and the properties of SNZVI materials are unknown, preventing rational design. Here, the effects of sulfur on the crystalline structure, hydrophobicity, sulfur speciation, corrosion potential, and electron transfer resistance are determined. Sulfur incorporation extended the nullo-Fe-0 BCC lattice parameter, reduced the Fe local vacancies, and lowered the resistance to electron transfer. Impacts of the main sulfur species (FeS and FeS2) on hydrophobicity (water contact angles) are consistent with density functional theory calculations for these FeSx phases. These properties well explain the reactivity and selectivity of SNZVI during the reductive dechlorination of trichloroethylene (TCE), a hydrophobic groundwater contaminullt. Controlling the amount and speciation of sulfur in the SNZVI made it highly reactive (up to 0.41 L m(-2) d(-1)) and selective for TCE degradation over water (up to 240 moles TCE per mole H2O), with an electron efficiency of up to 70%, and these values are 54-fold, 98-fold, and 160-fold higher than for NZVI, respectively. These findings can guide the rational design of robust SNZVI with properties tailored for specific application scenarios.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 32, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906910, "DOI": "10.1002/adma.201906910", "DOI Link": "http://dx.doi.org/10.1002/adma.201906910", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530300000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, LD; Zuo, TT; Kwok, CY; Kim, SY; Assoud, A; Zhang, Q; Janek, J; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Laidong; Zuo, Tong-Tong; Kwok, Chun Yuen; Kim, Se Young; Assoud, Abdeljalil; Zhang, Qiang; Janek, Juergen; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666-xCl4 (0 <= x <= 0.666), with high ionic conductivity (up to 2.0 mS cm(-1)) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 x 10(-10) S cm(-1)), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. High cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm(-2) (similar to 190 mAh g(-1)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 83, "End Page": 93, "Article Number": null, "DOI": "10.1038/s41560-021-00952-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00952-0", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737783400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, L; Yu, Q; Wang, Z; Ell, J; Huang, MX; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, L.; Yu, Qin; Wang, Z.; Ell, Jon; Huang, M. X.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making ultrastrong steel tough by grain-boundary delamination", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing ultrahigh-strength steels that are ductile, fracture resistant, and cost effective would be attractive for a variety of structural applications. We show that improved fracture resistance in a steel with an ultrahigh yield strength of nearly 2 gigapascals can be achieved by activating delamination toughening coupled with transformation-induced plasticity. Delamination toughening associated with intensive but controlled cracking at manganese-enriched prior-austenite grain boundaries normal to the primary fracture surface dramatically improves the overall fracture resistance. As a result, fracture under plane-strain conditions is automatically transformed into a series of fracture processes in parallel plane-stress conditions through the thickness. The present high-strength induced multidelamination strategy offers a different pathway to develop engineering materials with ultrahigh strength and superior toughness at economical materials cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2020, "Volume": 368, "Issue": 6497, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1347, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba9413", "DOI Link": "http://dx.doi.org/10.1126/science.aba9413", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544017600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Manthiram, K; Beberwyck, BJ; Aivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Manthiram, Karthish; Beberwyck, Brandon J.; Aivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible nulloscale Copper Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the vast majority of hydrocarbon fuels and products are presently derived from petroleum, there is much interest in the development of routes for synthesizing these same products by hydrogenating CO2. The simplest hydrocarbon target is methane, which can utilize existing infrastructure for natural gas storage, distribution, and consumption. Electrochemical methods for methanizing CO2 currently suffer from a combination of low activities and poor selectivities. We demonstrate that copper nulloparticles supported on glassy carbon (n-Cu/C) achieve up to 4 times greater methanation current densities compared to high-purity copper foil electrodes. The n-Cu/C electrocatalyst also exhibits an average Faradaic efficiency for methanation of 80% during extended electrolysis, the highest Faradaic efficiency for room-temperature methanation reported to date. We find that the level of copper catalyst loading on the glassy carbon support has an enormous impact on the morphology of the copper under catalytic conditions and the resulting Faradaic efficiency for methane. The improved activity and Faradaic efficiency for methanation involves a mechanism that is distinct from what is generally thought to occur on copper foils. Electrochemical data indicate that the early steps of methanation on n-Cu/C involve a pre-equilibrium one-electron transfer to CO2 to form an adsorbed radical, followed by a rate-limiting non-electrochemical step in which the adsorbed CO2 radical reacts with a second CO2 molecule from solution. These nulloscale copper electrocatalysts represent a first step toward the preparation of practical methanation catalysts that can be incorporated into membrane-electrode assemblies in electrolyzers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2014, "Volume": 136, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13319, "End Page": 13325, "Article Number": null, "DOI": "10.1021/ja5065284", "DOI Link": "http://dx.doi.org/10.1021/ja5065284", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342328200047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZY; Ma, X; Chen, DK; Wan, XY; Wang, XB; Fang, Z; Peng, XS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhuoyi; Ma, Xu; Chen, Danke; Wan, Xinyi; Wang, Xiaobin; Fang, Zhou; Peng, Xinsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyaniline-Coated MOFs nullorod Arrays for Efficient Evaporation-Driven Electricity Generation and Solar Steam Desalination", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though evaporation-driven electricity generation has emerged as a novel eco-friendly energy and attracted intense interests, it is typically demonstrated in pure water or a very low salt concentration. Integrating evaporation-driven electricity generation and solar steam desalination simultaneously should be more promising. Herein, a polyaniline coated metal-organic frameworks (MOFs) nullorod arrays membrane is synthesized which inherits the merits of both polyaniline and MOFs, demonstrating nice stability, good interfacial solar steam desalination, and evaporation-driven electricity generation. Moreover, an integrated system based on this hybrid membrane achieves good interfacial solar-heating evaporation and prominently enhanced evaporation-driven electricity generation under one sun. Notably, the realization of effective seawater desalination and efficient evaporation-driven electricity generation simultaneously by the non-carbon-based materials is reported for the first time, which provides a new alternative way for cogenerating both freshwater and electricity by harvesting energy from seawater and solar light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004552, "DOI": "10.1002/advs.202004552", "DOI Link": "http://dx.doi.org/10.1002/advs.202004552", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613293100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, S; Yu, HF; Li, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Shuai; Yu, Haifeng; Li, Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular Chirality Transfer toward Chiral Aggregation: Asymmetric Hierarchical Self-Assembly", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-assembly, as a typical bottom-up strategy for the fabrication of functional materials, has been applied to fabricate chiral materials with subtle chiral nullostructures. The chiral nullostructures exhibit great potential in asymmetric catalysis, chiral sensing, chiral electronics, photonics, and even the realization of several biological functions. According to existing studies, the supramolecular chirality transfer process combined with hierarchical self-assembly plays a vital role in the fabrication of multiscale chiral structures. This progress report focuses on the hierarchical self-assembly of chiral or achiral molecules that aggregate with asymmetric spatial structures such as twisted bands, helices, and superhelices in different environments. Herein, recent studies on the chirality transfer induced self-assembly based on a variety of supramolecular interactions are summarized. In addition, the influence of different environments and the states of systems including solutions, condensed states, gel systems, interfaces on the asymmetric hierarchical self-assembly, and the expression of chirality are explored. Moreover, both the driving forces that facilitate chiral bias and the supramolecular interactions that play an important role in the expression, transfer, and amplification of the chiral sense are correspondingly discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002132, "DOI": "10.1002/advs.202002132", "DOI Link": "http://dx.doi.org/10.1002/advs.202002132", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623498400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, WB; Xie, XY; Qiu, JD; Fang, WH; Liang, RP; Ren, X; Ji, XQ; Cui, GW; Asiri, AM; Cui, GL; Tang, B; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Weibin; Xie, Xiao-Ying; Qiu, Jianding; Fang, Wei-Hai; Liang, Ruping; Ren, Xiang; Ji, Xuqiang; Cui, Guanwei; Asiri, Abdullah M.; Cui, Ganglong; Tang, Bo; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance artificial nitrogen fixation at ambient conditions using a metal-free electrocatalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conversion of naturally abundant nitrogen to ammonia is a key (bio)chemical process to sustain life and represents a major challenge in chemistry and biology. Electrochemical reduction is emerging as a sustainable strategy for artificial nitrogen fixation at ambient conditions by tackling the hydrogen- and energy-intensive operations of the Haber-Bosch process. However, it is severely challenged by nitrogen activation and requires efficient catalysts for the nitrogen reduction reaction. Here we report that a boron carbide nullosheet acts as a metal-free catalyst for high-performance electrochemical nitrogen-to-ammonia fixation at ambient conditions. The catalyst can achieve a high ammonia yield of 26.57 mu g h(-1) mg(cat)(-1). and a fairly high Faradaic efficiency of 15.95% at -0.75 V versus reversible hydrogen electrode, placing it among the most active aqueous-based nitrogen reduction reaction electrocatalysts. Notably, it also shows high electrochemical stability and excellent selectivity. The catalytic mechanism is assessed using density functional theory calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 667, "Times Cited, All Databases": 692, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3485, "DOI": "10.1038/s41467-018-05758-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05758-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442909300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ha, KH; Zhang, WY; Jang, H; Kang, SM; Wang, L; Tan, P; Hwang, H; Lu, NS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ha, Kyoung-Ho; Zhang, Weiyi; Jang, Hongwoo; Kang, Seungmin; Wang, Liu; Tan, Philip; Hwang, Hochul; Lu, nullshu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Sensitive Capacitive Pressure Sensors over a Wide Pressure Range Enabled by the Hybrid Responses of a Highly Porous nullocomposite", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Past research aimed at increasing the sensitivity of capacitive pressure sensors has mostly focused on developing dielectric layers with surface/porous structures or higher dielectric constants. However, such strategies have only been effective in improving sensitivities at low pressure ranges (e.g., up to 3 kPa). To overcome this well-known obstacle, herein, a flexible hybrid-response pressure sensor (HRPS) composed of an electrically conductive porous nullocomposite (PNC) laminated with an ultrathin dielectric layer is devised. Using a nickel foam template, the PNC is fabricated with carbon nullotubes (CNTs)-doped Ecoflex to be 86% porous and electrically conductive. The PNC exhibits hybrid piezoresistive and piezocapacitive responses, resulting in significantly enhanced sensitivities (i.e., more than 400%) over wide pressure ranges, from 3.13 kPa(-1) within 0-1 kPa to 0.43 kPa(-1) within 30-50 kPa. The effect of the hybrid responses is differentiated from the effect of porosity or high dielectric constants by comparing the HRPS with its purely piezocapacitive counterparts. Fundamental understanding of the HRPS and the prediction of optimal CNT doping are achieved through simplified analytical models. The HRPS is able to measure pressures from as subtle as the temporal arterial pulse to as large as footsteps.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 33, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103320, "DOI": "10.1002/adma.202103320", "DOI Link": "http://dx.doi.org/10.1002/adma.202103320", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000700676400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jian, MP; Qiu, RS; Xia, Y; Lu, J; Chen, Y; Gu, QF; Liu, RP; Hu, CZ; Qu, JH; Wang, HT; Zhang, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jian, Meipeng; Qiu, Ruosang; Xia, Yun; Lu, Jun; Chen, Yu; Gu, Qinfen; Liu, Ruiping; Hu, Chengzhi; Qu, Jiuhui; Wang, Huanting; Zhang, Xiwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin water-stable metal-organic framework membranes for ion separation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the rich porosity and uniform pore size, metal-organic frameworks (MOFs) offer substantial advantages over other materials for the precise and fast membrane separation. However, achieving ultrathin water-stable MOF membranes remains a great challenge. Here, we first report the successful exfoliation of two-dimensional (2D) monolayer aluminum tetra-(4-carboxyphenyl) porphyrin framework (termed Al-MOF) nullosheets. Ultrathin water-stable Al-MOF membranes are assembled by using the exfoliated nullosheets as building blocks. While achieving a water flux of up to 2.2 mol m(-2) hour(-1) bar(-1) , the obtained 2D Al-MOF laminar membranes exhibit rejection rates of nearly 100% on investigated inorganic ions. The simulation results confirm that intrinsic nullopores of the Al-MOF nullosheets domain the ion/water separation, and the vertically aligned aperture channels are the main transport pathways for water molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay3998", "DOI": "10.1126/sciadv.aay3998", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay3998", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540787200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, F; Chen, ZX; Fang, GZ; Wang, ZQ; Cai, YS; Tang, BY; Zhou, J; Liang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fei; Chen, Zixian; Fang, Guozhao; Wang, Ziqing; Cai, Yangsheng; Tang, Boya; Zhou, Jiang; Liang, Shuquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "V2O5 nullospheres with Mixed Vanadium Valences as High Electrochemically Active Aqueous Zinc-Ion Battery Cathode", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsHollow V4+-V2O5 nullospheres are prepared by a novel and simple method using VOOH as the precursor.V4+-V2O5 with mixed vanadium valences is firstly constructed as an electrochemically active cathode for aqueous zinc-ion batteries.The V4+-V2O5 cathode exhibits a prominent cycling performance up to 1000 cycles and an excellent rate capability. AbstractA V4+-V2O5 cathode with mixed vanadium valences was prepared via a novel synthetic method using VOOH as the precursor, and its zinc-ion storage performance was evaluated. The products are hollow spheres consisting of nulloflakes. The V4+-V2O5 cathode exhibits a prominent cycling performance, with a specific capacity of 140 mAh g(-1) after 1000 cycles at 10 A g(-1), and an excellent rate capability. The good electrochemical performance is attributed to the presence of V4+, which leads to higher electrochemical activity, lower polarization, faster ion diffusion, and higher electrical conductivity than V2O5 without V4+. This engineering strategy of valence state manipulation may pave the way for designing high-performance cathodes for elucidating advanced battery chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25, "DOI": "10.1007/s40820-019-0256-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-019-0256-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462303300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, B; Gao, MZ; Boakye-Yiadom, KO; Ho, W; Yu, W; Xu, XY; Zhang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Bin; Gao, Mingzhu; Boakye-Yiadom, Kofi Oti; Ho, William; Yu, Wei; Xu, Xiaoyang; Zhang, Xue-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An intrinsically bioactive hydrogel with on-demand drug release behaviors for diabetic wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prolonged, intense inflammation and excessive oxidative stress hinder diabetic wounds from healing normally, leading to disorders downstream including the postponement of re-epithelialization and extracellular matrix (ECM) formation. Herein, we report a hyaluronic acid (HA) and chitosan based hydrogel (OHA-CMC) with inherent antibacterial and hemostatic activities fabricated via Schiff base reaction. By encapsulating nullotechnologically-modified curcumin (CNP) and epidermal growth factor (EGF) into the hydrogel, OHA-CMC/CNP/EGF exhibited extraordinary antioxidant, anti-inflammatory, and migration-promoting effects in vitro. Meanwhile, OHA-CMC/CNP/EGF presented on-demand drug release in synchrony with the phases of the wound healing process. Specifically, curcumin was rapidly and constantly released to alleviate inflammation and oxidative stress in the early phase of wound healing, while a more gradual and sustained release of EGF supported late proliferation and ECM remodeling. In a diabetic full-thickness skin defect model, OHA-CMC/CNP/EGF dramatically improved wound healing with ideal re-epithelialization, granulation tissue formation, and skin appendage regeneration, highlighting the enormous therapeutic potential this biomaterial holds as a diabetic wound dressing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4592, "End Page": 4606, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.04.040", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.04.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709332400027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, DL; Ye, C; Xie, FX; Zhou, WH; Zhang, QH; Gu, QF; Davey, K; Gu, L; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Dongliang; Ye, Chao; Xie, Fangxi; Zhou, Wanhai; Zhang, Qinghua; Gu, Qinfen; Davey, Kenneth; Gu, Lin; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Engineering Catalyzed MnO2 Electrolysis Kinetics for a Hybrid Aqueous Battery with High Power and Energy Density", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research interest and achievements in zinc aqueous batteries, such as alkaline Zn//Mn, Zn//Ni/Co, Zn-air batteries, and near-neutral Zn-ion and hybrid ion batteries, have surged throughout the world due to their features of low-cost and high-safety. However, practical application of Zn-based secondary batteries is plagued by restrictive energy and power densities in which an inadequate output plateau voltage and sluggish kinetics are mutually accountable. Here, a novel paradigm high-rate and high-voltage Zn-Mn hybrid aqueous battery (HAB) is constructed with an expanded electrochemical stability window over 3.4 V that is affordable. As a proof of concept, catalyzed MnO2/Mn2+ electrolysis kinetics is demonstrated in the HAB via facile introduction of Ni2+ into the electrolyte. Various techniques are employed, including in situ synchrotron X-ray powder diffraction, ex situ X-ray absorption fine structure, and electron energy loss spectroscopy, to reveal the reversible charge-storage mechanism and the origin of the boosted rate-capability. Density functional theory (DFT) calculations reveal enhanced active electron states and charge delocalization after introducing strongly electronegative Ni. Simulations of the reaction pathways confirm the enhanced catalyzed electrolysis kinetics by the facilitated charge transfer at the active O sites around Ni dopants. These findings significantly advance aqueous batteries a step closer toward practical low-cost application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 32, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001894, "DOI": "10.1002/adma.202001894", "DOI Link": "http://dx.doi.org/10.1002/adma.202001894", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533600600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhen, X; Tao, Y; An, ZF; Chen, P; Xu, CJ; Chen, RF; Huang, W; Pu, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhen, Xu; Tao, Ye; An, Zhongfu; Chen, Peng; Xu, Chenjie; Chen, Runfeng; Huang, Wei; Pu, Kanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong Phosphorescence of Water-Soluble Organic nulloparticles for In Vivo Afterglow Imaging", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Afterglow or persistent luminescence eliminates the need for light excitation and thus circumvents the issue of autofluorescence, holding promise for molecular imaging. However, current persistent luminescence agents are rare and limited to inorganic nulloparticles. This study reports the design principle, synthesis, and proof-of-concept application of organic semiconducting nulloparticles (OSNs) with ultralong phosphorescence for in vivo afterglow imaging. The design principle leverages the formation of aggregates through a top-down nulloparticle formulation to greatly stabilize the triplet excited states of a phosphorescent molecule. This prolongs the particle luminesce to the timescale that can be detected by the commercial whole-animal imaging system after removal of external light source. Such ultralong phosphorescent of OSNs is inert to oxygen and can be repeatedly activated, permitting imaging of lymph nodes in living mice with a high signal-to-noise ratio. This study not only introduces the first category of water-soluble ultralong phosphorescence organic nulloparticles but also reveals a universal design principle to prolong the lifetime of phosphorescent molecules to the level that can be effective for molecular imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 459, "Times Cited, All Databases": 474, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2017, "Volume": 29, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1606665, "DOI": "10.1002/adma.201606665", "DOI Link": "http://dx.doi.org/10.1002/adma.201606665", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408933600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Castellanos-Gomez, A; Buscema, M; Molenaar, R; Singh, V; Janssen, L; van der Zant, HSJ; Steele, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Castellanos-Gomez, Andres; Buscema, Michele; Molenaar, Rianda; Singh, Vibhor; Janssen, Laurens; van der Zant, Herre S. J.; Steele, Gary A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deterministic transfer of two-dimensional materials by all-dry viscoelastic stamping", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The deterministic transfer of two-dimensional crystals constitutes a crucial step towards the fabrication of heterostructures based on the artificial stacking of two-dimensional materials. Moreover, controlling the positioning of two-dimensional crystals facilitates their integration in complex devices, which enables the exploration of novel applications and the discovery of new phenomena in these materials. To date, deterministic transfer methods rely on the use of sacrificial polymer layers and wet chemistry to some extent. Here, we develop an all-dry transfer method that relies on viscoelastic stamps and does not employ any wet chemistry step. This is found to be very advantageous to freely suspend these materials as there are no capillary forces involved in the process. Moreover, the whole fabrication process is quick, efficient, clean and it can be performed with high yield.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 691, "Times Cited, All Databases": 700, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11002, "DOI": "10.1088/2053-1583/1/1/011002", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/1/1/011002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353649900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MM; Gu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, Md. Muntasir; Gu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Radiative Cooling: Principles, Progress, and Potentials", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent progress on radiative cooling reveals its potential for applications in highly efficient passive cooling. This approach utilizes the maximized emission of infrared thermal radiation through the atmospheric window for releasing heat and minimized absorption of incoming atmospheric radiation. These simultaneous processes can lead to a device temperature substantially below the ambient temperature. Although the application of radiative cooling for nighttime cooling was demonstrated a few decades ago, significant cooling under direct sunlight has been achieved only recently, indicating its potential as a practical passive cooler during the day. In this article, the basic principles of radiative cooling and its performance characteristics for nonradiative contributions, solar radiation, and atmospheric conditions are discussed. The recent advancements over the traditional approaches and their material and structural characteristics are outlined. The key characteristics of the thermal radiators and solar reflectors of the current state-of-the-art radiative coolers are evaluated and their benchmarks are remarked for the peak cooling ability. The scopes for further improvements on radiative cooling efficiency for optimized device characteristics are also theoretically estimated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 623, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500360, "DOI": "10.1002/advs.201500360", "DOI Link": "http://dx.doi.org/10.1002/advs.201500360", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379935500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, JL; Xiao, DD; Ge, MY; Yu, XQ; Chu, Y; Huang, XJ; Zhang, XD; Yin, YX; Yang, XQ; Guo, YG; Gu, L; Wan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Ji-Lei; Xiao, Dong-Dong; Ge, Mingyuan; Yu, Xiqian; Chu, Yong; Huang, Xiaojing; Zhang, Xu-Dong; Yin, Ya-Xia; Yang, Xiao-Qing; Guo, Yu-Guo; Gu, Lin; Wan, Li-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Capacity Cathode Material with High Voltage for Li-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical energy storage devices with a high energy density are an important technology in modern society, especially for electric vehicles. The most effective approach to improve the energy density of batteries is to search for high-capacity electrode materials. According to the concept of energy quality, a high-voltage battery delivers a highly useful energy, thus providing a new insight to improve energy density. Based on this concept, a novel and successful strategy to increase the energy density and energy quality by increasing the discharge voltage of cathode materials and preserving high capacity is proposed. The proposal is realized in high-capacity Li-rich cathode materials. The average discharge voltage is increased from 3.5 to 3.8 V by increasing the nickel content and applying a simple after-treatment, and the specific energy is improved from 912 to 1033 Wh kg(-1). The current work provides an insightful universal principle for developing, designing, and screening electrode materials for high energy density and energy quality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 30, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705575, "DOI": "10.1002/adma.201705575", "DOI Link": "http://dx.doi.org/10.1002/adma.201705575", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426491600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Ren, DS; Hsu, HJ; Feng, XN; Xu, GL; Zhuang, MH; Gao, H; Lu, LG; Han, XB; Chu, ZY; Li, JQ; He, XM; Amine, K; Ouyang, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiang; Ren, Dongsheng; Hsu, Hungjen; Feng, Xuning; Xu, Gui-Liang; Zhuang, Minghao; Gao, Han; Lu, Languang; Han, Xuebing; Chu, Zhengyu; Li, Jianqiu; He, Xiangming; Amine, Khalil; Ouyang, Minggao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal Runaway of Lithium-Ion Batteries without Internal Short Circuit", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate herein that not only internal short circuiting, but also chemical crossover, is the mechanism behind thermal runaway that can occur in lithium-ion batteries due to abuse conditions. In situ experiments showed that during thermal runaway, the cathode releases oxygen by a phase transition, and this oxygen is consumed by the lithiated anode. The released highly oxidative gas reacts with reductive LiCx with tremendous heat generation centered at 274.2 degrees C with heat flow of 87,8 W g(-1) To confirm the proposed mechanism, we froze a battery undergoing the thermal runaway process by liquid nitrogen and subjected it to detailed post-test analysis. Our results revealed the hidden thermal runaway mechanism of chemical crossover between the battery components without a severe internal short circuit. These findings provide an important insight into the rational design of automotive lithium-ion batteries as well as solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 568, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2018, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2047, "End Page": 2064, "Article Number": null, "DOI": "10.1016/j.joule.2018.06.015", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.06.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447735000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Wang, PF; Ao, YH; Chen, J; Gao, X; Jia, BH; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Wang, Peifang; Ao, Yanhui; Chen, Juan; Gao, Xin; Jia, Baohua; Ma, Tianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directing Charge Transfer in a Chemical-Bonded BaTiO3@ReS2 Schottky Heterojunction for Piezoelectric Enhanced Photocatalysis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The piezo-assisted photocatalysis system, which can utilize solar energy and mechanical energy simulteneously, is promising but still challenging in the environmental remediation field. In this work, a novel metal-semiconductor BaTiO3@ReS2 Schottky heterostructure is designed and it shows high-efficiency on piezo-assisted photocatalytic molecular oxygen activation. By combining experiment and calculation results, the distorted metal-phase ReS2 nullosheets are found to be closely anchored on the surface of the BaTiO3 nullorods, through interfacial Re-O covalent bonds. The Schottky heterostructure not only forms electron-transfer channels but also exhibits enhanced oxygen activation capacity, which are helpful to produce more superoxide radicals. The polarization field induced by the piezoelectric BaTiO3 can lower the Schottky barrier and thus reduce the transfer resistance of photogenerated electrons directing to the ReS2. As a result of the synergy effect between the two components, the BaTiO3@ReS2 exhibits untrahigh activity for degradation of pollutants with an apparent rate constant of 0.133 min(-1) for piezo-assisted photocatalysis, which is 16.6 and 2.44 times as that of piezocatalysis and photocatalysis, respectively. This performance is higher than most reported BaTiO3-based piezo-assisted photocatalysis systems. This work paves the way for the design of high-efficiency piezo-assisted photocatalytic materials for environmental remediation through using green energies in nature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 34, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202508, "DOI": "10.1002/adma.202202508", "DOI Link": "http://dx.doi.org/10.1002/adma.202202508", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806734000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, X; Guo, X; Wu, WJ; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Xiao; Guo, Xin; Wu, Wenjian; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D Metal Carbides and Nitrides (MXenes) as High-Performance Electrode Materials for Lithium-Based Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tremendous efforts are devoted to developing advanced electrode materials with superior electrochemical performance, high energy density, and high power density for energy storage and conversion. Two-dimensional (2D) materials, owing to their unique properties, have shown great potential for energy storage. Following the discovery of graphene, a new family of 2D transition metal carbides/nitrides, MXenes, derived from MAX phase precursors, have attracted extensive attention in recent years. The superior physical and chemical properties of MXenes include high mechanical strength, excellent electrical conductivity, multiple possible surface terminations, hydrophilic features, superior specific surface area, and the ability to accommodate intercalants. When applied as electrodes in lithium-based batteries, MXenes have demonstrated excellent performance. In this progress report, the authors summarize the recent advances of MXenes and MXene-based composites in terms of synthesis strategies, morphology engineering, physical/chemical properties, and their applications in lithium-ion batteries and lithium-sulfur batteries. Furthermore, challenges and perspectives for MXenes and MXene-based composites for lithium-based energy storage devices are also outlined.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2018, "Volume": 8, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801897, "DOI": "10.1002/aenm.201801897", "DOI Link": "http://dx.doi.org/10.1002/aenm.201801897", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451181900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, L; Zhao, Q; Huang, SJ; Zheng, JH; Guan, XW; Patterson, R; Kim, J; Shi, L; Lin, CH; Lei, Q; Chu, DW; Tao, W; Cheong, SS; Tilley, RD; Ho-Baillie, AWY; Luther, JM; Yuan, JY; Wu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Long; Zhao, Qian; Huang, Shujuan; Zheng, Jianghui; Guan, Xinwei; Patterson, Robert; Kim, Jiyun; Shi, Lei; Lin, Chun-Ho; Lei, Qi; Chu, Dewei; Tao, Wan; Cheong, Soshan; Tilley, Richard D.; Ho-Baillie, Anita W. Y.; Luther, Joseph M.; Yuan, Jianyu; Wu, Tom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and efficient perovskite quantum dot solar cells via hybrid interfacial architecture", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic CsPbI3 perovskite quantum dots have received substantial research interest for photovoltaic applications because of higher efficiency compared to solar cells using other quantum dots materials and the various exciting properties that perovskites have to offer. These quantum dot devices also exhibit good mechanical stability amongst various thin-film photovoltaic technologies. We demonstrate higher mechanical endurance of quantum dot films compared to bulk thin film and highlight the importance of further research on high-performance and flexible optoelectronic devices using nulloscale grains as an advantage. Specifically, we develop a hybrid interfacial architecture consisting of CsPbI3 quantum dot/PCBM heterojunction, enabling an energy cascade for efficient charge transfer and mechanical adhesion. The champion CsPbI3 quantum dot solar cell has an efficiency of 15.1% (stabilized power output of 14.61%), which is among the highest report to date. Building on this strategy, we further demonstrate a highest efficiency of 12.3% in flexible quantum dot photovoltaics. Perovskite quantum dots film has better mechanical stability and structural integrity compared to bulk thin film. Here, the authors demonstrate higher endurance of quantum dot films and develop hybrid CsPbI3 QD/PCBM device with PCE of 15.1% and 12.3% on rigid and flexible substrates, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 466, "DOI": "10.1038/s41467-020-20749-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20749-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613566500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JW; Jia, ZR; Liu, XH; Dou, JL; Xu, BH; Wang, BB; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianwei; Jia, Zirui; Liu, Xuehua; Dou, Jinlei; Xu, Binghui; Wang, Bingbing; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of 1D Heterostructure NiCo@C/ZnO nullorod with Enhanced Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered double hydroxides (LDHs) have a special structure and atom composition, which are expected to be an excellent electromagnetic wave (EMW) absorber. However, it is still a problem that obtaining excellent EMW-absorbing materials from LDHs. Herein, we designed heterostructure NiCo-LDHs@ZnO nullorod and then subsequent heat treating to derive NiCo@C/ZnO composites. Finally, with the synergy of excellent dielectric loss and magnetic loss, an outstanding absorption performance could be achieved with the reflection loss of - -60.97 dB at the matching thickness of 2.3 mm, and the widest absorption bandwidth of 6.08 GHz was realized at 2.0 mm. Moreover, this research work provides a reference for the development and utilization of LDHs materials in the field of microwave absorption materials and can also provide ideas for the design of layered structural absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 175, "DOI": "10.1007/s40820-021-00704-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00704-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686648200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Song, JW; Zhu, SZ; Li, YJ; Kuang, YD; Wan, JY; Kirsch, D; Xu, LS; Wang, YB; Gao, TT; Wang, YL; Huang, H; Gan, WT; Gong, A; Li, T; Xie, J; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chaoji; Song, Jianwei; Zhu, Shuze; Li, Yiju; Kuang, Yudi; Wan, Jiayu; Kirsch, Dylan; Xu, Lisha; Wang, Yanbin; Gao, Tingting; Wang, Yilin; Huang, Hao; Gan, Wentao; Gong, Amy; Li, Teng; Xie, Jia; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable and Sustainable Approach toward Highly Compressible, Anisotropic, Lamellar Carbon Sponge", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we demonstrate that wood can be directly converted into a highly compressible wood carbon sponge (WCS) by lignin and hemicellulose removal followed by carbonization. The significant removal of lignin and hemicellulose via chemical treatment destroys the thin cell walls of natural wood, giving rise to a lamellar structure with numerous stacked arched layers. The lamellar structure can be well preserved even after high-temperature carbonization. Interestingly, such a lamellar structure renders a high compressibility up to 80% and high fatigue resistance of 10,000 compression cycles at 50% strain. Further experimental and modeling studies reveal that WCS can accommodate substantial compression from the bending and flattening of the curved layers, resulting in minimum stretching of individual layers. The WCS also demonstrates a sensitive electrical conductivity change upon compression. Using this lamellar sponged structure and the excellent mechanical and electrical properties of WCS as an example, we demonstrate the great potential of WCS for highly sensitive strain sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 530, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 544, "End Page": 554, "Article Number": null, "DOI": "10.1016/j.chempr.2017.12.028", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.12.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429434900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, PP; Huang, JH; Pantovich, SA; Carl, AD; Fenton, TG; Caputo, CA; Grimm, RL; Frenkel, AI; Li, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Peipei; Huang, Jiahao; Pantovich, Sebastian A.; Carl, Alexander D.; Fenton, Thomas G.; Caputo, Christine A.; Grimm, Ronald L.; Frenkel, Anatoly I.; Li, Gonghu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective CO2 Reduction Catalyzed by Single Cobalt Sites on Carbon Nitride under Visible-Light Irradiation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Framework nitrogen atoms of carbon nitride (C3N4) can coordinate with and activate metal sites for catalysis. In this study, C3N4 was employed to harvest visible light and activate Co2+ sites, without the use of additional ligands, in photochemical CO2 reduction. Photocatalysts containing single Co2+ sites on C3N4 were prepared by a simple deposition method and demonstrated excellent activity and product selectivity toward CO formation. A turnover number of more than 200 was obtained for CO production using the synthesized photocatalyst under visible-light irradiation. Inactive cobalt oxides formed at relatively high cobalt loadings but did not alter product selectivity. Further studies with X-ray absorption spectroscopy confirmed the presence of single Co2+ sites on C3N4 and their important role in achieving selective CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2018, "Volume": 140, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16042, "End Page": 16047, "Article Number": null, "DOI": "10.1021/jacs.8b10380", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b10380", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451933100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brousse, T; Bélanger, D; Long, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brousse, Thierry; Belanger, Daniel; Long, Jeffrey W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "To Be or Not To Be Pseudocapacitive?", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There are an increasing number of studies regarding active electrode materials that undergo faradaic reactions but are used for electrochemical capacitor applications. Unfortunately, some of these materials are described as pseudocapacitive materials despite the fact that their electrochemical signature (e.g., cyclic voltarnmogram and charge/discharge curve) is analogous to that of a battery material, as commonly observed for Ni(OH)(2) and cobalt oxides in KOH electrolyte. Conversely, true pseudocapacitive electrode materials such as MnO2 display electrochemical behavior typical of that observed for a capacitive carbon electrode. The difference between these two classes of materials will be explained, and we demonstrate why it is inappropriate to describe nickel oxide or hydroxide and cobalt oxide/hydroxide as pseudocapacitive electrode materials. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commerdial reuse; distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2139, "Times Cited, All Databases": 2245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 162, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A5185", "End Page": "A5189", "Article Number": null, "DOI": "10.1149/2.0201505jes", "DOI Link": "http://dx.doi.org/10.1149/2.0201505jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351976200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XX; Hwang, S; Pan, YT; Chen, K; He, YH; Karakalos, S; Zhang, HG; Spendelow, JS; Su, D; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiao Xia; Hwang, Sooyeon; Pan, Yung-Tin; Chen, Kate; He, Yanghua; Karakalos, Stavros; Zhang, Hanguang; Spendelow, Jacob S.; Su, Dong; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ordered Pt3Co Intermetallic nulloparticles Derived from Metal-Organic Frameworks for Oxygen Reduction", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly ordered Pt alloy structures are proven effective to improve their catalytic activity and stability for the oxygen reduction reaction (ORR) for proton exchange membrane fuel cells. Here, we report a new approach to preparing ordered Pt3Co intermetallic nulloparticles through a facile thermal treatment of Pt nulloparticles supported on Co-doped metal-organic-framework (MOF)-derived carbon. In particular, the atomically dispersed Co sites, which are originally embedded into MOF-derived carbon, diffuse into Pt nullocrystals and form ordered Pt3Co structures. It is very crucial for the formation of the ordered Pt3Co to carefully control the doping content of Co into the MOFs and the heating temperatures for Co diffusion. The optimal Pt3Co nulloparticle catalyst has achieved significantly enhanced activity and stability, exhibiting a half-wave potential up to 0.92 V vs reversible hydrogen electrode (RHE) and only losing 12 mV after 30 000 potential cycling between 0.6 and 1.0 V. The highly ordered intermetallic structure was retained after the accelerated stress tests made evident by atomic-scale elemental mapping. Fuel cell tests further verified the high intrinsic activity of the ordered Pt3Co catalysts. Unlike the direct use of MOF-derived carbon supports for depositing Pt, we utilized MOF-derived carbon containing atomically dispersed Co sites as Co sources to prepare ordered Pt3Co intermetallic catalysts. The new synthesis approach provides an effective strategy to develop active and stable Pt alloy catalysts by leveraging the unique properties of MOFs such as 3D structures, high surface areas, and controlled nitrogen and transition metal dopings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 18, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4163, "End Page": 4171, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b00978", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b00978", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439008300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, QS; Zhang, XY; Feng, XL; Lu, SY; Chen, ZL; Yong, X; Redfern, SAT; Wei, HT; Wang, HY; Shen, HZ; Zhang, W; Zheng, WT; Zhang, H; Tse, JS; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Qingsen; Zhang, Xiaoyu; Feng, Xiaolei; Lu, Siyu; Chen, Zhaolai; Yong, Xue; Redfern, Simon A. T.; Wei, Haotong; Wang, Haiyu; Shen, Huaizhong; Zhang, Wei; Zheng, Weitao; Zhang, Hao; Tse, John S.; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymer-Passivated Inorganic Cesium Lead Mixed-Halide Perovskites for Stable and Efficient Solar Cells with High Open-Circuit Voltage over 1.3 V", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cesium-based trihalide perovskites have been demonstrated as promising light absorbers for photovoltaic applications due to their superb composition stability. However, the large energy losses (E-loss) observed in inorganic perovskite solar cells has become a major hindrance impairing the ultimate efficiency. Here, an effective and reproducible method of modifying the interface between a CsPbI2Br absorber and polythiophene hole-acceptor to minimize the E-loss is reported. It is demonstrated that polythiophene, deposited on the top of CsPbI2Br, can significantly reduce electron-hole recombination within the perovskite, which is due to the electronic passivation of surface defect states. In addition, the interfacial properties are improved by a simple annealing process, leading to significantly reduced energy disorder in polythiophene and enhanced hole-injection into the hole-acceptor. Consequently, one of the highest power conversion efficiency (PCE) of 12.02% from a reverse scan in inorganic mixed-halide perovskite solar cells is obtained. Modifying the perovskite films with annealing polythiophene enables an open-circuit voltage (V-OC) of up to 1.32 V and E-loss of down to 0.5 eV, which both are the optimal values reported among cesium-lead mixed-halide perovskite solar cells to date. This method provides a new route to further improve the efficiency of perovskite solar cells by minimizing the E-loss.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 30, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705393, "DOI": "10.1002/adma.201705393", "DOI Link": "http://dx.doi.org/10.1002/adma.201705393", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426491600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, HX; Zhao, X; Qiao, ZH; Jung, J; Zhu, YW; Lu, YL; Zhang, LL; MacDonald, AH; Ruoff, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Hengxing; Zhao, Xin; Qiao, Zhenhua; Jung, Jeil; Zhu, Yanwu; Lu, Yalin; Zhang, Li Li; MacDonald, Allan H.; Ruoff, Rodney S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capacitance of carbon-based electrical double-layer capacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Experimental electrical double-layer capacitances of porous carbon electrodes fall below ideal values, thus limiting the practical energy densities of carbon-based electrical double-layer capacitors. Here we investigate the origin of this behaviour by measuring the electrical double-layer capacitance in one to five-layer graphene. We find that the capacitances are suppressed near neutrality, and are anomalously enhanced for thicknesses below a few layers. We attribute the first effect to quantum capacitance effects near the point of zero charge, and the second to correlations between electrons in the graphene sheet and ions in the electrolyte. The large capacitance values imply gravimetric energy storage densities in the single-layer graphene limit that are comparable to those of batteries. We anticipate that these results shed light on developing new theoretical models in understanding the electrical double-layer capacitance of carbon electrodes, and on opening up new strategies for improving the energy density of carbon-based capacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 636, "Times Cited, All Databases": 689, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3317, "DOI": "10.1038/ncomms4317", "DOI Link": "http://dx.doi.org/10.1038/ncomms4317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332668300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bansil, A; Lin, H; Das, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bansil, A.; Lin, Hsin; Das, Tanmoy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloquium: Topological band theory", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The first-principles band theory paradigm has been a key player not only in the process of discovering new classes of topologically interesting materials, but also for identifying salient characteristics of topological states, enabling direct and sharpened confrontation between theory and experiment. This review begins by discussing underpinnings of the topological band theory, which involve a layer of analysis and interpretation for assessing topological properties of band structures beyond the standard band theory construct. Methods for evaluating topological invariants are delineated, including crystals without inversion symmetry and interacting systems. The extent to which theoretically predicted properties and protections of topological states have been verified experimentally is discussed, including work on topological crystalline insulators, disorder and interaction driven topological insulators (TIs), topological superconductors, Weyl semimetal phases, and topological phase transitions. Successful strategies for new materials discovery process are outlined. A comprehensive survey of currently predicted 2D and 3D topological materials is provided. This includes binary, ternary, and quaternary compounds, transition metal and f-electron materials, Weyl and 3D Dirac semimetals, complex oxides, organometallics, skutterudites, and antiperovskites. Also included is the emerging area of 2D atomically thin films beyond graphene of various elements and their alloys, functional thin films, multilayer systems, and ultrathin films of 3D TIs, all of which hold exciting promise of wide-ranging applications. This Colloquium concludes by giving a perspective on research directions where further work will broadly benefit the topological materials field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1219, "Times Cited, All Databases": 1292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2016, "Volume": 88, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21004, "DOI": "10.1103/RevModPhys.88.021004", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.88.021004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378882600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McEnulley, JM; Crompton, JC; Callejas, JF; Popczun, EJ; Biacchi, AJ; Lewis, NS; Schaak, RE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McEnulley, Joshua M.; Crompton, J. Chance; Callejas, Juan F.; Popczun, Eric J.; Biacchi, Adam J.; Lewis, Nathan S.; Schaak, Raymond E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous Molybdenum Phosphide nulloparticles for Electrocatalytic Hydrogen Evolution", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Amorphous molybdenum phosphide (MoP) nulloparticles have been synthesized and characterized as electrocatalysts for the hydrogen-evolution reaction (HER) in 0.50 M H2SO4 (pH 0.3). Amorphous MoP nulloparticles (having diameters of 4.2 +/- 0.5 nm) formed upon heating Mo(CO)(6) and trioctylphosphine in squalane at 320 degrees C, and the nulloparticles remained amorphous after heating at 450 degrees C in H-2(5%)/Ar(95%) to remove the surface ligands. At mass loadings of 1 mg cm(-2), MoP/Ti electrodes exhibited overpotentials of -90 and -105 mV (-110 and -140 mV without iR correction) at current densities of 10 and 20 mA cm(-2), respectively. These HER overpotentials remained nearly constant over 500 cyclic voltammetric sweeps and 18 h of galvanostatic testing, indicating stability in acidic media under operating conditions. Amorphous MoP nulloparticles are therefore among the most active known molybdenum-based HER systems and are part of a growing family of active, acid-stable, non-noble-metal HER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2014, "Volume": 26, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4826, "End Page": 4831, "Article Number": null, "DOI": "10.1021/cm502035s", "DOI Link": "http://dx.doi.org/10.1021/cm502035s", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340992900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, K; Zhou, W; Kang, JC; He, S; Shi, SL; Zhang, QH; Pan, Y; Wen, W; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Kang; Zhou, Wei; Kang, Jincan; He, Shun; Shi, Shulin; Zhang, Qinghong; Pan, Yang; Wen, Wu; Wang, Ye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bifunctional Catalysts for One-Step Conversion of Syngas into Aromatics with Excellent Selectivity and Stability", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Syngas (CO/H-2) is a key platform for chemical utilization of non-petroleum carbon resources. Among syngas transformation routes, the direct synthesis of aromatics, which are among the most important bulk chemicals, is less successful because of the limited selectivity and poor catalyst stability. We report a successful design of bifunctional catalysts composed of Zn-doped ZrO2 nulloparticles dispersed on zeolite H-ZSM-5 for one-step conversion of syngas to aromatics with high selectivity and stability. Aromatics with 80% selectivity at CO conversion of 20% were achieved, and there was no catalyst deactivation in 1,000 hr. Methanol and dimethyl ether were formed as major intermediates on Zn-doped ZrO2, which were subsequently converted into aromatics on H-ZSM-5 via olefins. We discovered a self-promotion mechanism of CO in the selective formation of aromatics. As well as being a reactant, CO facilitates the removal of hydrogen species formed on H-ZSM-5 in the dehydrogenative aromatization of olefins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2017, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 334, "End Page": 347, "Article Number": null, "DOI": "10.1016/j.chempr.2017.05.007", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.05.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408622600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdulhameed, O; Al-Ahmari, A; Ameen, W; Mian, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdulhameed, Osama; Al-Ahmari, Abdulrahman; Ameen, Wadea; Mian, Syed Hammad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing: Challenges, trends, and applications", "Source Title": "ADVANCES IN MECHANICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing is a recent trend in production processes owing to its many benefits. It can be defined as the process of producing parts through the deposition of material in a layer-by-layer fashion. It has been a topic of intense study and review by many researchers. In this work, a comprehensive review pertaining to additive manufacturing has been accomplished. The evolution of additive manufacturing as a prominent technology and its various phases are discussed. The importance of part orientation, build time estimation, and cost computation has also been reviewed. The remarkable aspect of this work is the identification of problems associated with different additive manufacturing methods. Because of the imperfections in additive manufacturing, its hybridization with other methods, such as subtractive manufacturing, has been emphasized. This review will help readers understand the different aspects of additive manufacturing and explore new avenues for future research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2019, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1687814018822880, "DOI": "10.1177/1687814018822880", "DOI Link": "http://dx.doi.org/10.1177/1687814018822880", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461024400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Sun, FF; Zhou, S; Hu, W; Zhang, H; Dong, JC; Jiang, Z; Zhao, JJ; Li, JF; Yan, WS; Wang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jian; Sun, Fanfei; Zhou, Si; Hu, Wei; Zhang, Hao; Dong, Jinchao; Jiang, Zheng; Zhao, Jijun; Li, Jianfeng; Yan, Wensheng; Wang, Mei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of great importance to understand the origin of high oxygen-evolving activity of state-of the-art multimetal oxides/(oxy)hydroxides at atomic level. Herein we report an evident improvement of oxygen evolution reaction activity via incorporating iron and vanadium into nickel hydroxide lattices. X-ray photoelectron/absorption spectroscopies reveal the synergistic interaction between iron/vanadium dopants and nickel in the host matrix, which subtly modulates local coordination environments and electronic structures of the iron/vanadium/nickel cations. Further, in-situ X-ray absorption spectroscopic analyses manifest contraction of metal-oxygen bond lengths in the activated catalyst, with a short vanadium-oxygen bond distance. Density functional theory calculations indicate that the vanadium site of the iron/ vanadium co-doped nickel (oxy)hydroxide gives near-optimal binding energies of oxygen evolution reaction intermediates and has lower overpotential compared with nickel and iron sites. These findings suggest that the doped vanadium with distorted geometric and disturbed electronic structures makes crucial contribution to high activity of the trimetallic catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 798, "Times Cited, All Databases": 816, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2885, "DOI": "10.1038/s41467-018-05341-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05341-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439426100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sohn, SS; da Silva, AK; Ikeda, Y; Körmann, F; Lu, WJ; Choi, WS; Gault, B; Ponge, D; Neugebauer, J; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sohn, Seok Su; da Silva, Alisson Kwiatkowski; Ikeda, Yuji; Koermann, Fritz; Lu, Wenjun; Choi, Won Seok; Gault, Baptiste; Ponge, Dirk; Neugebauer, Joerg; Raabe, Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastrong Medium-Entropy Single-Phase Alloys Designed via Severe Lattice Distortion", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Severe lattice distortion is a core effect in the design of multiprincipal element alloys with the aim to enhance yield strength, a key indicator in structural engineering. Yet, the yield strength values of medium- and high-entropy alloys investigated so far do not substantially exceed those of conventional alloys owing to the insufficient utilization of lattice distortion. Here it is shown that a simple VCoNi equiatomic medium-entropy alloy exhibits a near 1 GPa yield strength and good ductility, outperforming conventional solid-solution alloys. It is demonstrated that a wide fluctuation of the atomic bond distances in such alloys, i.e., severe lattice distortion, improves both yield stress and its sensitivity to grain size. In addition, the dislocation-mediated plasticity effectively enhances the strength-ductility relationship by generating nullosized dislocation substructures due to massive pinning. The results demonstrate that severe lattice distortion is a key property for identifying extra-strong materials for structural engineering applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 31, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1807142, "DOI": "10.1002/adma.201807142", "DOI Link": "http://dx.doi.org/10.1002/adma.201807142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459798700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Williams, SW; Martina, F; Addison, AC; Ding, J; Pardal, G; Colegrove, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Williams, S. W.; Martina, F.; Addison, A. C.; Ding, J.; Pardal, G.; Colegrove, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire plus Arc Additive Manufacturing", "Source Title": "MATERIALS SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Depositing large components (>10 kg) in titanium, aluminium, steel and other metals is possible using Wire + Arc Additive Manufacturing. This technology adopts arc welding tools and wire as feedstock for additive manufacturing purposes. High deposition rates, low material and equipment costs, and good structural integrity make Wire + Arc Additive Manufacturing a suitable candidate for replacing the current method of manufacturing from solid billets or large forgings, especially with regards to low and medium complexity parts. A variety of components have been successfully manufactured with this process, including Ti-6Al-4V spars and landing gear assemblies, aluminium wing ribs, steel wind tunnel models and cones. Strategies on how to manage residual stress, improve mechanical properties and eliminate defects such as porosity are suggested. Finally, the benefits of non-destructive testing, online monitoring and in situ machining are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1158, "Times Cited, All Databases": 1263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 32, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 641, "End Page": 647, "Article Number": null, "DOI": "10.1179/1743284715Y.0000000073", "DOI Link": "http://dx.doi.org/10.1179/1743284715Y.0000000073", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378338600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JR; Cai, LH; Weitz, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jinrong; Cai, Li-Heng; Weitz, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough Self-Healing Elastomers by Molecular Enforced Integration of Covalent and Reversible Networks", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing polymers crosslinked by solely reversible bonds are intrinsically weaker than common covalently crosslinked networks. Introducing covalent crosslinks into a reversible network would improve mechanical strength. It is challenging, however, to apply this concept to dry elastomers, largely because reversible crosslinks such as hydrogen bonds are often polar motifs, whereas covalent crosslinks are nonpolar motifs. These two types of bonds are intrinsically immiscible without cosolvents. Here, we design and fabricate a hybrid polymer network by crosslinking randomly branched polymers carrying motifs that can form both reversible hydrogen bonds and permanent covalent crosslinks. The randomly branched polymer links such two types of bonds and forces them to mix on the molecular level without cosolvents. This enables a hybrid dry elastomer that is very tough with fracture energy 13500 Jm(-2) comparable to that of natural rubber. Moreover, the elastomer can self-heal at room temperature with a recovered tensile strength 4 MPa, which is 30% of its original value, yet comparable to the pristine strength of existing self-healing polymers. The concept of forcing covalent and reversible bonds to mix at molecular scale to create a homogenous network is quite general and should enable development of tough, self-healing polymers of practical usage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 29, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702616, "DOI": "10.1002/adma.201702616", "DOI Link": "http://dx.doi.org/10.1002/adma.201702616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412452500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, JH; Fong, PWK; Liu, H; Huang, CS; Lu, XH; Lu, SR; Abdelsamie, M; Kodalle, T; Sutter-Fella, CM; Yang, Y; Li, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Jiehao; Fong, Patrick W. K.; Liu, Heng; Huang, Chieh-Szu; Lu, Xinhui; Lu, Shirong; Abdelsamie, Maged; Kodalle, Tim; Sutter-Fella, Carolin M.; Yang, Yang; Li, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "19.31% binary organic solar cell and low non-radiative recombination enabled by non-monotonic intermediate state transition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-radiative recombination loss suppression is critical for boosting performance of organic solar cells. Here, the authors regulate self-organization of bulk-heterojunction in a non-monotonic manner, and achieve device efficiency over 19% with low non-radiative recombination loss down to 0.168 eV. Non-fullerene acceptors based organic solar cells represent the frontier of the field, owing to both the materials and morphology manipulation innovations. Non-radiative recombination loss suppression and performance boosting are in the center of organic solar cell research. Here, we developed a non-monotonic intermediate state manipulation strategy for state-of-the-art organic solar cells by employing 1,3,5-trichlorobenzene as crystallization regulator, which optimizes the film crystallization process, regulates the self-organization of bulk-heterojunction in a non-monotonic manner, i.e., first enhancing and then relaxing the molecular aggregation. As a result, the excessive aggregation of non-fullerene acceptors is avoided and we have achieved efficient organic solar cells with reduced non-radiative recombination loss. In PM6:BTP-eC9 organic solar cell, our strategy successfully offers a record binary organic solar cell efficiency of 19.31% (18.93% certified) with very low non-radiative recombination loss of 0.190 eV. And lower non-radiative recombination loss of 0.168 eV is further achieved in PM1:BTP-eC9 organic solar cell (19.10% efficiency), giving great promise to future organic solar cell research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-37526-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37526-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961133600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, CJ; Meng, JS; Wang, XP; Han, CH; Yan, MY; Zhao, KN; Xu, XM; Ren, WH; Zhao, YL; Xu, L; Zhang, QJ; Zhao, DY; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Chaojiang; Meng, Jiashen; Wang, Xuanpeng; Han, Chunhua; Yan, Mengyu; Zhao, Kangning; Xu, Xiaoming; Ren, Wenhao; Zhao, Yunlong; Xu, Lin; Zhang, Qingjie; Zhao, Dongyuan; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis of complex nullotubes by gradient electrospinning and controlled pyrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullowires and nullotubes have been the focus of considerable efforts in energy storage and solar energy conversion because of their unique properties. However, owing to the limitations of synthetic methods, most inorganic nullotubes, especially for multi-element oxides and binary-metal oxides, have been rarely fabricated. Here we design a gradient electrospinning and controlled pyrolysis method to synthesize various controllable 1D nullostructures, including mesoporous nullotubes, pea-like nullotubes and continuous nullowires. The key point of this method is the gradient distribution of low-/middle-/high-molecular-weight poly(vinyl alcohol) during the electrospinning process. This simple technique is extended to various inorganic multi-element oxides, binary-metal oxides and single-metal oxides. Among them, Li3V2(PO4)(3), Na0.7Fe0.7Mn0.3O2 and Co3O4 mesoporous nullotubes exhibit ultrastable electrochemical performance when used in lithium-ion batteries, sodium-ion batteries and supercapacitors, respectively. We believe that a wide range of new materials available from our composition gradient electrospinning and pyrolysis methodology may lead to further developments in research on 1D systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7402, "DOI": "10.1038/ncomms8402", "DOI Link": "http://dx.doi.org/10.1038/ncomms8402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Wu, JY; Zhang, SH; Shang, NZ; Zhao, XX; Alshehri, SM; Ahamad, T; Yamauchi, Y; Xu, XT; Bando, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ying; Wu, Jingyu; Zhang, Shuaihua; Shang, Ningzhao; Zhao, Xiaoxian; Alshehri, Saad M.; Ahamad, Tanir; Yamauchi, Yusuke; Xu, Xingtao; Bando, Yoshio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-on-MOF nulloarchitectures for selectively functionalized nitrogen-doped carbon-graphitic carbon/carbon nullotubes heterostructure with high capacitive deionization performance", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-carbon heterostructures are an emerging material paradigm to promote the development of capacitive deionization (CDI). The synthesis of this heterostructure with designed functionalities derived from metalorganic frameworks (MOFs) is interesting, but it has always been challenging. We develop MOF-on-MOF nulloarchitectures to obtain a selectively functionalized nitrogen-doped carbon@graphitic carbon/carbon nullotubes heterostructure (NC@GC/CNTs) via the direct pyrolysis of elaborately designed ZIF-L@ZIF-67 coreshell precursors. In this core-shell nulloarchitecture, the inner Zn-based ZIF-L provides a well-defined 2D interface for the oriented growth of the Co-based ZIF-67 outer layer, which will then convert to NC nullosheets with a high nitrogen doping content and large specific surface area for the accommodation of more ions. Meanwhile, the outer ZIF-67 layer creates highly graphitized GC/CNTs architecture offering fast electron transfer and good chemical stability, and it addresses the possible aggregation or collapse of the inner ZIF-L precursors during pyrolysis. As expected, the newly developed NC@GC/CNTs material with well-designed functionalities exhibits high salt adsorption capacity, rapid salt adsorption rate, and excellent CDI cycling stability, which highlight the significance of the carbon-carbon heterostructure to potential CDI applications and the importance of MOF-on-MOF nulloarchitectures on nullomaterials synthetic chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 97, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107146, "DOI": "10.1016/j.nulloen.2022.107146", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2022.107146", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791248400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YB; Yu, JL; Sun, MZ; Chen, B; Zhou, XC; Ye, CL; Guan, ZQ; Guo, WH; Wang, G; Lu, SY; Xia, DS; Wang, YH; He, Z; Zheng, L; Yun, QB; Wang, LQ; Zhou, JW; Lu, PY; Yin, JW; Zhao, YF; Luo, ZB; Zhai, L; Liao, LW; Zhu, ZL; Ye, RQ; Chen, Y; Lu, Y; Xi, SB; Huang, BL; Lee, CS; Fan, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yangbo; Yu, Jinli; Sun, Mingzi; Chen, Bo; Zhou, Xichen; Ye, Chenliang; Guan, Zhiqiang; Guo, Weihua; Wang, Gang; Lu, Shiyao; Xia, Dongsheng; Wang, Yunhao; He, Zhen; Zheng, Long; Yun, Qinbai; Wang, Liqiang; Zhou, Jingwen; Lu, Pengyi; Yin, Jinwen; Zhao, Yifei; Luo, Zhongbin; Zhai, Li; Liao, Lingwen; Zhu, Zonglong; Ye, Ruquan; Chen, Ye; Lu, Yang; Xi, Shibo; Huang, Bolong; Lee, Chun-Sing; Fan, Zhanxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confined Growth of Silver-Copper Janus nullostructures with {100} Facets for Highly Selective Tandem Electrocatalytic Carbon Dioxide Reduction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic carbon dioxide reduction reaction (CO2RR) holds significant potential to promote carbon neutrality. However, the selectivity toward multicarbon products in CO2RR is still too low to meet practical applications. Here the authors report the delicate synthesis of three kinds of Ag-Cu Janus nullostructures with {100} facets (JNS-100) for highly selective tandem electrocatalytic reduction of CO2 to multicarbon products. By controlling the surfactant and reduction kinetics of Cu precursor, the confined growth of Cu with {100} facets on one of the six equal faces of Ag nullocubes is realized. Compared with Cu nullocubes, Ag-65-Cu-35 JNS-100 demonstrates much superior selectivity for both ethylene and multicarbon products in CO2RR at less negative potentials. Density functional theory calculations reveal that the compensating electronic structure and carbon monoxide spillover in Ag-65-Cu-35 JNS-100 contribute to the enhanced CO2RR performance. This study provides an effective strategy to design advanced tandem catalysts toward the extensive application of CO2RR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 34, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110607, "DOI": "10.1002/adma.202110607", "DOI Link": "http://dx.doi.org/10.1002/adma.202110607", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777971700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, TL; Halouane, F; Mathias, D; Barras, A; Wang, ZW; Lv, AQ; Lu, SX; Xu, WG; Meziane, D; Tiercelin, N; Szunerits, S; Boukherroub, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Tianlong; Halouane, Fatima; Mathias, Dolci; Barras, Alexandre; Wang, Ziwen; Lv, Anqi; Lu, Shixiang; Xu, Wenguo; Meziane, Dalila; Tiercelin, Nicolas; Szunerits, Sabine; Boukherroub, Rabah", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of magnetic, superhydrophobic/superoleophilic polyurethane sponge: Separation of oil/water mixture and demulsification", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Regular problems faced due to chemical leaks and oil spills have caused tremendous threats to lakes and sea water. Therefore, there is an urgent need to develop efficient strategies to remove oil and organic pollutants from water surfaces. The aim of this study is to develop a high performance magnetic, superhydrophobic/superoleophilic three-dimensional porous composite material for efficient and selective adsorption of organic pollutants from water. The composite material was fabricated by simple immersion of a commercially available polyurethane (PU) sponge into a solution of high-density polyethylene (HDPE) containing pre-synthesized magnetic (Fe3O4) nulloparticles. The composite material exhibited a water contact of similar to 155 degrees and an oil contact angle of similar to 0 degrees. The presence of the Fe3O4 particles allowed magnetic-controlled elimination of underwater oil, while the superhydrophobic character of the functionalized PU sponge permitted efficient separation of oil/water mixtures and demulsification of toluene/water emulsions. Moreover, the HDPE coating not only firmly immobilized the magnetic particles, but also contributed to the excellent stability of the composite sponge which withstood acid, base, salts, seawater or temperature variation from - 20 degrees C to 105 degrees C. In addition, the composite material maintained its oil adsorption ability over 10 cycles. The ease of fabrication of the magnetic super wetting 3D material sponge along with its durability and reusability makes it an interesting material with potential for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2020, "Volume": 384, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123339, "DOI": "10.1016/j.cej.2019.123339", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.123339", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000504405000115", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZM; Wu, HH; Liu, HD; Zhang, QB; He, X; Yu, SC; Petrova, V; Feng, J; Kostecki, R; Liu, P; Peng, DL; Liu, ML; Wang, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhiming; Wu, Hong-Hui; Liu, Haodong; Zhang, Qiaobao; He, Xin; Yu, Sicen; Petrova, Victoria; Feng, Jun; Kostecki, Robert; Liu, Ping; Peng, Dong-Liang; Liu, Meilin; Wang, Ming-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Fast and Durable Lithium Storage through Amorphous FeP nulloparticles Encapsulated in Ultrathin 3D P-Doped Porous Carbon nullosheets", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conversion-type transition-metal phosphide anode materials with high theoretical capacity usually suffer from low-rate capability and severe capacity decay, which are mainly caused by their inferior electronic conductivities and large volumetric variations together with the poor reversibility of discharge product (Li3P), impeding their practical applications. Herein, guided by density functional theory calculations, these obstacles are simultaneously mitigated by confining amorphous FeP nulloparticles into ultrathin 3D interconnected P-doped porous carbon nullosheets (denoted as FeP@CNs) via a facile approach, forming an intriguing 3D flake-CNs-like configuration. As an anode for lithium-ion batteries (LIBs), the resulting FeP@CNs electrode not only reaches a high reversible capacity (837 mA h g(-1) after 300 cycles at 0.2 A g(-1)) and an exceptional rate capability (403 mA h g(-1) at 16 A g(-1)) but also exhibits extraordinary durability (2500 cycles, 563 mA h(-1) g(-1) at 4 A 98% capacity retention). By combining DFT calculations, in situ transmission electron microscopy, and a suite of ex situ microscopic and spectroscopic techniques, we show that the superior performances of FeP@CNs anode originate from its prominent structural and compositional merits, which render fast electron/ion-transport kinetics and abundant active sites (amorphous FeP nulloparticles and structural defects in P-doped CNs) for charge storage, promote the reversibility of conversion reactions, and buffer the volume variations while preventing pulverization/aggregation of FeP during cycling, thus enabling a high rate and highly durable lithium storage. Furthermore, a full cell composed of the prelithiated FeP@CNs anode and commercial LiFePO4 cathode exhibits impressive rate performance while maintaining superior cycling stability. This work fundamentally and experimentally presents a facile and effective structural engineering strategy for markedly improving the performance of conversion-type anodes for advanced LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2020, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9545, "End Page": 9561, "Article Number": null, "DOI": "10.1021/acsnullo.9b08575", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b08575", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566341000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, LJ; Zhu, MM; Wu, BH; Li, ZL; Sun, ST; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Lijing; Zhu, Miaomiao; Wu, Baohu; Li, Zhaoling; Sun, Shengtong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductance-stable liquid metal sheath-core microfibers for stretchy smart fabrics and self-powered sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly conductive and stretchy fibers are crucial components for smart fabrics and wearable electronics. However, most of the existing fiber conductors are strain sensitive with deteriorated conductance upon stretching, and thus, a compromised strategy via introducing merely geometric distortion of conductive path is often used for stable conductance. Here, we report a coaxial wet-spinning process for continuously fabricating intrinsically stretchable, highly conductive yet conductance-stable, liquid metal sheath-core microfibers. The microfiber can be stretched up to 1170%, and upon fully activating the conductive path, a very high conductivity of 4.35 x 10(4) S/m and resistance change of only 4% at 200% strain are realized, arising from both stretch-induced channel opening and stretching out of tortuous serpentine conductive path of the percolating liquid metal network. Moreover, the microfibers can be easily woven into an everyday glove or fabric, acting as excellent joule heaters, electrothermochromic displays, and self-powered wearable sensors to monitor human activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 7, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg4041", "DOI": "10.1126/sciadv.abg4041", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg4041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000655906900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FQ; Wang, WP; Yin, YX; Zhang, SF; Shi, JL; Wang, L; Zhang, XD; Zheng, Y; Zhou, JJ; Li, L; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Feng-Quan; Wang, Wen-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng; Shi, Ji-Lei; Wang, Lu; Zhang, Xu-Dong; Zheng, Yue; Zhou, Jian-Jun; Li, Lin; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy lithium metal batteries (LMBs) are expected to play important roles in the next-generation energy storage systems. However, the uncontrolled Li dendrite growth in liquid electrolytes still impedes LMBs from authentic commercialization. Upgrading the traditional electrolyte system from liquid to solid and quasi-solid has therefore become a key issue for prospective LMBs. From this premise, it is particularly urgent to exploit facile strategies to accomplish this goal. We report that commercialized liquid electrolyte can be easily converted into a novel quasi-solid gel polymer electrolyte (GPE) via a simple and efficient in situ gelation strategy, which, in essence, is to use LiPF6 to induce the cationic polymerization of the ether-based 1,3-dioxolane and 1,2-dimethoxyethane liquid electrolyte under ambient temperature. The newly developed GPE exhibits elevated protective effects on Li anodes and has universality for diversified cathodes including but not restricted to sulfur, olivine-type LiFePO4, and layered LiNi0.6Co0.2Mn0.2O2, revealing tremendous potential in promoting the large-scale application of future LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat5383", "DOI": "10.1126/sciadv.aat5383", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat5383", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449221200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SK; Dai, XM; Stogin, BB; Wong, TS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shikuan; Dai, Xianming; Stogin, Birgitt Boschitsch; Wong, Tak-Sing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive surface-enhanced Raman scattering detection in common fluids", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detecting target analytes with high specificity and sensitivity in any fluid is of fundamental importance to analytical science and technology. Surface-enhanced Raman scattering (SERS) has proven to be capable of detecting single molecules with high specificity, but achieving single-molecule sensitivity in any highly diluted solutions remains a challenge. Here we demonstrate a universal platform that allows for the enrichment and delivery of analytes into the SERS-sensitive sites in both aqueous and nonaqueous fluids, and its subsequent quantitative detection of Rhodamine 6G (R6G) down to similar to 75 fM level (10(-15) mol.L-1). Our platform, termed slippery liquid-infused porous surface-enhanced Raman scattering (SLIPSERS), is based on a slippery, omniphobic substrate that enables the complete concentration of analytes and SERS substrates (e.g., Au nulloparticles) within an evaporating liquid droplet. Combining our SLIPSERS platform with a SERS mapping technique, we have systematically quantified the probability, p(c), of detecting R6G molecules at concentrations c ranging from 750 fM (p > 90%) down to 75 aM (10(-18) mol.L-1) levels (p <= 1.4%). The ability to detect analytes down to attomolar level is the lowest limit of detection for any SERS-based detection reported thus far. We have shown that analytes present in liquid, solid, or air phases can be extracted using a suitable liquid solvent and subsequently detected through SLIPSERS. Based on this platform, we have further demonstrated ultrasensitive detection of chemical and biological molecules as well as environmental contaminullts within a broad range of common fluids for potential applications related to analytical chemistry, molecular diagnostics, environmental monitoring, and national security.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 595, "Times Cited, All Databases": 627, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2016, "Volume": 113, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": 273, "Article Number": null, "DOI": "10.1073/pnas.1518980113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1518980113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367881500030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dieny, B; Chshiev, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dieny, B.; Chshiev, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perpendicular magnetic anisotropy at transition metal/oxide interfaces and applications", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin electronics is a rapidly expanding field stimulated by a strong synergy between breakthrough basic research discoveries and industrial applications in the fields of magnetic recording, magnetic field sensors, nonvolatile memories [magnetic random access memories (MRAM) and especially spin-transfer-torque MRAM (STT-MRAM)]. In addition to the discovery of several physical phenomena (giant magnetoresistance, tunnel magnetoresistance, spin-transfer torque, spin-orbit torque, spin Hall effect, spin Seebeck effect, etc.), outstanding progress has been made on the growth and nullopatterning of magnetic multilayered films and nullostructures in which these phenomena are observed. Magnetic anisotropy is usually observed in materials that have large spin-orbit interactions. However, in 2002 perpendicular magnetic anisotropy (PMA) was discovered to exist at magnetic metal/oxide interfaces [for instance Co(Fe)/alumina]. Surprisingly, this PMA is observed in systems where spin-orbit interactions are quite weak, but its amplitude is remarkably large-comparable to that measured at Co/Pt interfaces, a reference for large interfacial anisotropy (anisotropy similar to 1.4 erg/cm(2) = 1.4 mJ/m(2)). Actually, this PMA was found to be very common at magnetic metal/oxide interfaces since it has been observed with a large variety of amorphous or crystalline oxides, including AlOx, MgO, TaOx, HfOx, etc. This PMA is thought to be the result of electronic hybridization between the oxygen and the magnetic transition metal orbit across the interface, a hypothesis supported by ab initio calculations. Interest in this phenomenon was sparked in 2010 when it was demonstrated that the PMA at magnetic transition metal/oxide interfaces could be used to build out-of-plane magnetized magnetic tunnel junctions for STT-MRAM cells. In these systems, the PMA at the CoFeB/MgO interface can be used to simultaneously obtain good memory retention, thanks to the large PMA amplitude, and a low write current, thanks to a relatively weak Gilbert damping. These two requirements for memories tend to be difficult to reconcile since they rely on the same spin-orbit coupling. PMA-based approaches have now become ubiquitous in the designs for perpendicular STT-MRAM, and major microelectronics companies are actively working on their development with the first goal of addressing embedded FLASH and static random access memory-type of applications. Scalability of STT-MRAM devices based on this interfacial PMA is expected to soon exceed the 20-nm nodes. Several very active new fields of research also rely on interfacial PMA at magnetic metal/oxide interfaces, including spin-orbit torques associated with Rashba or spin Hall effects, record high speed domain wall propagation in buffer/magnetic metal/oxide-based magnetic wires, and voltage-based control of anisotropy. This review deals with PMA at magnetic metal/oxide interfaces from its discovery, by examining the diversity of systems in which it has been observed and the physicochemical methods through which the key roles played by the electronic hybridization at the metal/oxide interface were elucidated. The physical origins of the phenomenon are also covered and how these are supported by ab initio calculations is dealt with. Finally, some examples of applications of this interfacial PMA in STT-MRAM are listed along with the various emerging research topics taking advantage of this PMA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 607, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2017, "Volume": 89, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25008, "DOI": "10.1103/RevModPhys.89.025008", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.89.025008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404344600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tolley, MT; Shepherd, RF; Mosadegh, B; Galloway, KC; Wehner, M; Karpelson, M; Wood, RJ; Whitesides, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tolley, Michael T.; Shepherd, Robert F.; Mosadegh, Bobak; Galloway, Kevin C.; Wehner, Michael; Karpelson, Michael; Wood, Robert J.; Whitesides, George M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Resilient, Untethered Soft Robot", "Source Title": "SOFT ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A pneumatically powered, fully untethered mobile soft robot is described. Composites consisting of silicone elastomer, polyaramid fabric, and hollow glass microspheres were used to fabricate a sufficiently large soft robot to carry the miniature air compressors, battery, valves, and controller needed for autonomous operation. Fabrication techniques were developed to mold a 0.65-meter-long soft body with modified Pneu-Net actuators capable of operating at the elevated pressures (up to 138 kPa) required to actuate the legs of the robot and hold payloads of up to 8 kg. The soft robot is safe to interact with during operation, and its silicone body is innately resilient to a variety of adverse environmental conditions including snow, puddles of water, direct (albeit limited) exposure to flames, and the crushing force of being run over by an automobile.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 892, "Times Cited, All Databases": 1078, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 213, "End Page": 223, "Article Number": null, "DOI": "10.1089/soro.2014.0008", "DOI Link": "http://dx.doi.org/10.1089/soro.2014.0008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364567400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, RQ; Wang, XJ; Kuang, YD; Huang, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Ruiqiang; Wang, Xinjiang; Kuang, Youdi; Huang, Baoling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles study of anisotropic thermoelectric transport properties of IV-VI semiconductor compounds SnSe and SnS", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin selenide (SnSe) and tin sulfide (SnS) have recently attracted particular interest due to their great potential for large-scale thermoelectric applications. A complete prediction of the thermoelectric performance and the understanding of underlying heat and charge transport details are the key to further improvement of their thermoelectric efficiency. We conduct comprehensive investigations of both thermal and electrical transport properties of SnSe and SnS using first-principles calculations combined with the Boltzmann transport theory. Due to the distinct layered lattice structure, SnSe and SnS exhibit similarly anisotropic thermal and electrical behaviors. The cross-plane lattice thermal conductivity kappa(L) is 40-60% lower than the in-plane values. Extremely low kappa(L) is found for both materials because of high anharmonicity, while the average kappa(L) of SnS is similar to 8% higher than that of SnSe from 300 to 750 K. It is suggested that nullostructuring would be difficult to further decrease kappa(L) because of the short mean free paths of dominullt phonon modes (1-30 nm at 300 K), while alloying would be efficient in reducing kappa(L) considering that the relative kappa(L) contribution (similar to 65%) of optical phonons is remarkably large. On the electrical side, the anisotropic electrical conductivities are mainly due to the different effective masses of holes and electrons along the a, b, and c axes. This leads to the highest optimal ZT values along the b axis and lowest ones along the a axis in both p-type materials. However, the n-type ones exhibit the highest ZTs along the a axis due to the enhancement of power factor when the chemical potential gradually approaches the secondary conduction band valley that causes significant increase in electron mobility and density of states. Owing to the larger mobility and smaller kappa(L) along the given direction, SnSe exhibits larger optimal ZTs compared with SnS in both p-and n-type materials. For both materials, the peak ZTs of n-type materials are much higher than those of p-type ones along the same direction. The predicted highest ZT values at 750 K are 1.0 in SnSe and 0.6 in SnS along the b axis for the p-type doping, while those for the n-type doping reach 2.7 in SnSe and 1.5 in SnS along the a axis, rendering them among the best bulk thermoelectric materials for large-scale applications. Our calculations show reasonable agreements with the experimental results and quantitatively predict the great potential in further enhancing the thermoelectric performance of SnSe and SnS, especially for the n-type materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 450, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2015, "Volume": 92, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115202, "DOI": "10.1103/PhysRevB.92.115202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.115202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360331300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bae, K; Kang, G; Cho, SK; Park, W; Kim, K; Padilla, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bae, Kyuyoung; Kang, Gumin; Cho, Suehyun K.; Park, Wounjhang; Kim, Kyoungsik; Padilla, Willie J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible thin-film black gold membranes with ultrabroadband plasmonic nullofocusing for efficient solar vapour generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar steam generation has been achieved by surface plasmon heating with metallic nulloshells or nulloparticles, which have inherently narrow absorption bandwidth. For efficient light-to-heat conversion from a wider solar spectrum, we employ adiabatic plasmonic nullofocusing to attain both polarization-independent ultrabroadband light absorption and high plasmon dissipation loss. Here we demonstrate large area, flexible thin-film black gold membranes, which have multiscale structures of varying metallic nulloscale gaps (0-200 nm) as well as microscale funnel structures. The adiabatic nullofocusing of self-aggregated metallic nullowire bundle arrays produces average absorption of 91% at 400-2,500 nm and the microscale funnel structures lead to average reflection of 7% at 2.5-17 mu m. This membrane allows heat localization within the few micrometre-thick layer and continuous water provision through micropores. We efficiently generate water vapour with solar thermal conversion efficiency up to 57% at 20 k Wm(-2). This new structure has a variety of applications in solar energy harvesting, thermoplasmonics and related technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 862, "Times Cited, All Databases": 907, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10103, "DOI": "10.1038/ncomms10103", "DOI Link": "http://dx.doi.org/10.1038/ncomms10103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367569800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marinho, ALA; Toniolo, FS; Noronha, FB; Epron, F; Duprez, D; Bion, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marinho, Andre L. A.; Toniolo, Fabio S.; Noronha, Fabio B.; Epron, Florence; Duprez, Daniel; Bion, Nicolas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-based mesoporous mixed CeO2-Al2O3 oxide catalysts prepared by one pot Evaporation Induced Self Assembly (EISA) were tested in dry reforming of methane. The textural, structural and physicochemical properties of the catalysts were studied by N-2 adsorption-desorption, TEM-EDS, XRD and elemental analysis. The mobility of oxygen in the structure and the redox properties were investigated by OSCC measurements, TPR and in situ DRIFTS. Finally, the post-reaction samples were analyzed by TGA, RAMAN and TEM. The calcined catalysts prepared by EISA method present mesoporous structures with highly dispersed Ni in the form of NiAl2O4 spinel clusters. After reduction, small size metallic Ni particles are observed (< 5 nm). The presence of Ce in the structure interacting strongly with Al2O3 promotes the oxygen mobility and acts as sites for CO2 adsorption, increasing the activity of the catalyst and promoting the carbon removal mechanism. In absence of Ce in the mesoporous alumina support, the activity for carbon gasification is limited and C filaments accumulate inside the reactor. The same behavior occurs with CeO2-Al2O3 oxide prepared by EISA method when Ni is post-im-pregnated because of the presence of isolated larger Ni particles which promotes the decomposition of CH4. Therefore, Ni-based CeO2-Al2O3 catalysts prepared by one pot EISA method exhibited high activity and stability for the dry reforming of methane thanks to both properties which are the confinement of Ni particles and the inhibition of carbon deposition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 281, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119459, "DOI": "10.1016/j.apcatb.2020.119459", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119459", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591344500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Navarro-Sánchez, J; Argente-García, AI; Moliner-Martínez, Y; Roca-Sanjuán, D; Antypov, D; Campíns-Falcó, P; Rosseinsky, MJ; Martí-Gastaldo, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Navarro-Sanchez, Jose; Argente-Garcia, Ana I.; Moliner-Martinez, Yolanda; Roca-Sanjuan, Daniel; Antypov, Dmytro; Campins-Falco, Pilar; Rosseinsky, Matthew J.; Marti-Gastaldo, Carlos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Peptide Metal-Organic Frameworks for Enulltioselective Separation of Chiral Drugs", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the use of a chiral Cu(II) 3D metal organic framework (MOF) based on the tripeptide Gly-L-His-Gly (GHG) for the enulltioselective separation of metamphetamine and ephedrine. Monte Carlo simulations suggest that chiral recognition is linked to preferential binding of one of the enulltiomers as a result of either stronger or additional H-bonds with the framework that lead to energetically more stable diastereomeric adducts. Solid-phase extraction of a racemic mixture by using Cu(GHG) as the extractive phase permits isolating >50% of the (+)-ephedrine enulltiomer as target compound in only 4 min. To our knowledge, this represents the first example of a MOF capable of separating chiral polar drugs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2017, "Volume": 139, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4294, "End Page": 4297, "Article Number": null, "DOI": "10.1021/jacs.7b00280", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b00280", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398247100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SS; Wang, L; Su, H; Hong, AN; Wang, YX; Yang, HJ; Ge, L; Song, WY; Liu, J; Ma, TY; Bu, XH; Feng, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Songsong; Wang, Lu; Su, Hui; Hong, Anh N.; Wang, Yanxiang; Yang, Huajun; Ge, Lei; Song, Weiyu; Liu, Jian; Ma, Tianyi; Bu, Xianhui; Feng, Pingyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron Redistributed S-Doped Nickel Iron Phosphides Derived from One-Step Phosphatization of MOFs for Significantly Boosting Electrochemical Water Splitting", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonprecious transition metal-organic frameworks (MOFs) are one of the most promising precursors for developing electrocatalysts with high porosity and structural rigidity. This study reports the synthesis of high efficiency electrocatalysts based on S-doped NiFeP. MOF-derived S-doped NiFeP structure is synthesized by a one-step phosphorization process with using S-doped MOFs as the precursor, which is more convenient and environment friendly, and also helps retain the samples' framework. The oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) performance of the NiFeP catalysts can be improved after partially replacing P by S due to the tunable electronic structure. The optimized CCS-NiFeP-10 reaches a current density of 10 mA cm(-2) for OER with an overpotential of 201 mV and outperforms most NiFe-based catalysts. The S doping plays an important role in tuning the Delta G values for intermediates formation in Ni atoms to a suitable value and exhibits a pronouncedly improved the OER performance. CCS-NiFeP-20 sample presents excellent HER performance due to the d-band center downshifting from the Fermi level. When the voltage of the electrolytic cell is 1.50 V, a current density of 10 mA cm(-2) can be obtained. This strategy paves the way for designing highly active none-noble metal catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 32, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200733, "DOI": "10.1002/adfm.202200733", "DOI Link": "http://dx.doi.org/10.1002/adfm.202200733", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763774400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GB; Phua, SZF; Lim, WQ; Zhang, R; Feng, LZ; Liu, GF; Wu, HW; Bindra, AK; Jana, D; Liu, Z; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Guangbao; Phua, Soo Zeng Fiona; Lim, Wei Qi; Zhang, Rui; Feng, Liangzhu; Liu, Guofeng; Wu, Hongwei; Bindra, Anivind Kaur; Jana, Deblin; Liu, Zhuang; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Hypoxia-Responsive Albumin-Based nullosystem for Deep Tumor Penetration and Excellent Therapeutic Efficacy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uncontrolled cancer cell proliferation, insufficient blood flow, and inadequate endogenous oxygen lead to hypoxia in tumor tissues. Herein, a unique type of hypoxia-responsive human serum albumin (HSA)-based nullosystem (HCHOA) is reported, prepared by cross-linking the hypoxia-sensitive azobenzene group between photosensitizer chlorin e6 (Ce6)-conjugated HSA (HC) and oxaliplatin prodrug-conjugated HSA (HO). The HCHOA nullosystem is stable under normal oxygen partial pressure with a size of 100-150 nm. When exposed to the hypoxic tumor microenvironment, the nullosystem can quickly dissociate into ultrasmall HC and HO therapeutic nulloparticles with a diameter smaller than 10 nm, significantly enabling their enhanced intratumoral penetration. After the dissociation, the quenched fluorescence of Ce6 in the produced HC nulloparticles can be recovered for bioimaging. At the same time, the production of singlet oxygen is increased because of the enhancement in the photoactivity of the photosensitizer. On account of these improvements, combined photodynamic therapy and chemotherapy is realized to display superior antitumor efficacy in vivo. Based on this simple strategy, it is possible to achieve the dissociation of hypoxic-responsive nullosystem to enhance the tumor penetration and therapeutic effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 31, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901513, "DOI": "10.1002/adma.201901513", "DOI Link": "http://dx.doi.org/10.1002/adma.201901513", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475269900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, ZP; Gan, LY; Yang, HB; Su, XZ; Gao, JJ; Liu, W; Matsumoto, H; Gong, J; Zhang, JM; Cai, WZ; Zhang, ZY; Yan, YB; Liu, B; Chen, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Zhiping; Gan, Li Yong; Yang, Hong Bin; Su, Xiaozhi; Gao, Jiajian; Liu, Wei; Matsumoto, Hiroaki; Gong, Jun; Zhang, Junming; Cai, Weizhen; Zhang, Zheye; Yan, Yibo; Liu, Bin; Chen, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orbital coupling of hetero-diatomic nickel-iron site for bifunctional electrocatalysis of CO2 reduction and oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While inheriting the exceptional merits of single atom catalysts, diatomic site catalysts (DASCs) utilize two adjacent atomic metal species for their complementary functionalities and synergistic actions. Herein, a DASC consisting of nickel-iron hetero-diatomic pairs anchored on nitrogen-doped graphene is synthesized. It exhibits extraordinary electrocatalytic activities and stability for both CO2 reduction reaction (CO2RR) and oxygen evolution reaction (OER). Furthermore, the rechargeable Zn-CO2 battery equipped with such bifunctional catalyst shows high Faradaic efficiency and outstanding rechargeability. The in-depth experimental and theoretical analyses reveal the orbital coupling between the catalytic iron center and the adjacent nickel atom, which leads to alteration in orbital energy level, unique electronic states, higher oxidation state of iron, and weakened binding strength to the reaction intermediates, thus boosted CO2RR and OER performance. This work provides critical insights to rational design, working mechanism, and application of hetero-DASCs. Diatomic site catalysts utilize two adjacent atomic metal species for their complementary functionalities and synergistic actions. Here, the authors report the orbital coupling of hetero-diatomic nickel-iron site boosts CO2 reduction reaction and oxygen evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4088, "DOI": "10.1038/s41467-021-24052-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24052-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672164300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dall'Agnese, Y; Lukatskaya, MR; Cook, KM; Taberna, PL; Gogotsi, Y; Simon, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dall'Agnese, Yohan; Lukatskaya, Maria R.; Cook, Kevin M.; Taberna, Pierre-Louis; Gogotsi, Yury; Simon, Patrice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High capacitance of surface-modified 2D titanium carbide in acidic electrolyte", "Source Title": "ELECTROCHEMISTRY COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical behavior of Ti3C2, a two-dimensional titanium carbide from the MXene family, in H2SO4 electrolyte is reported. To demonstrate the effect of surface chemistry on capacitive performance, Ti3C2 was modified by delamination or intercalation treatments. Electrochemical testing revealed an increase in capacitance, which was attributed to oxygen-containing functional groups. An extraordinary high intercalation capacitance of 415 F.cm(-3) at 5 A.g(-1) was obtained from electrodes with a specific surface area of just 98 m(2).g(-1). Values up to 520 F.cm(-3) were recorded for delaminated MXene films at 2 mV.s(-1). This study highlights that the behavior of materials from the large family of two-dimensional MXene can be tuned by suitable modification of their surface chemistry. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 48, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 118, "End Page": 122, "Article Number": null, "DOI": "10.1016/j.elecom.2014.09.002", "DOI Link": "http://dx.doi.org/10.1016/j.elecom.2014.09.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345208000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, PQ; Soenksen, LR; Donghia, NM; Angenent-Mari, NM; de Puig, H; Huang, A; Lee, R; Slomovic, S; Galbersanini, T; Lansberry, G; Sallum, HM; Zhao, EM; Niemi, JB; Collins, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, Peter Q.; Soenksen, Luis R.; Donghia, Nina M.; Angenent-Mari, Nicolaas M.; de Puig, Helena; Huang, Ally; Lee, Rose; Slomovic, Shimyn; Galbersanini, Tommaso; Lansberry, Geoffrey; Sallum, Hani M.; Zhao, Evan M.; Niemi, James B.; Collins, James J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable materials with embedded synthetic biology sensors for biomolecule detection", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable materials are endowed with synthetic biology circuits to detect biomolecules, including SARS-CoV-2 RNA. Integrating synthetic biology into wearables could expand opportunities for noninvasive monitoring of physiological status, disease states and exposure to pathogens or toxins. However, the operation of synthetic circuits generally requires the presence of living, engineered bacteria, which has limited their application in wearables. Here we report lightweight, flexible substrates and textiles functionalized with freeze-dried, cell-free synthetic circuits, including CRISPR-based tools, that detect metabolites, chemicals and pathogen nucleic acid signatures. The wearable devices are activated upon rehydration from aqueous exposure events and report the presence of specific molecular targets by colorimetric changes or via an optical fiber network that detects fluorescent and luminescent outputs. The detection limits for nucleic acids rival current laboratory methods such as quantitative PCR. We demonstrate the development of a face mask with a lyophilized CRISPR sensor for wearable, noninvasive detection of SARS-CoV-2 at room temperature within 90 min, requiring no user intervention other than the press of a button.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 39, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1366, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41587-021-00950-3", "DOI Link": "http://dx.doi.org/10.1038/s41587-021-00950-3", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667605500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Valentine, AD; Busbee, TA; Boley, JW; Raney, JR; Chortos, A; Kotikian, A; Berrigan, JD; Durstock, MF; Lewis, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Valentine, Alexander D.; Busbee, Travis A.; Boley, John William; Raney, Jordan R.; Chortos, Alex; Kotikian, Arda; Berrigan, John Daniel; Durstock, Michael F.; Lewis, Jennifer A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid 3D Printing of Soft Electronics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid 3D printing is a new method for producing soft electronics that combines direct ink writing of conductive and dielectric elastomeric materials with automated pick-and-place of surface mount electronic components within an integrated additive manufacturing platform. Using this approach, insulating matrix and conductive electrode inks are directly printed in specific layouts. Passive and active electrical components are then integrated to produce the desired electronic circuitry by using an empty nozzle (in vacuum-on mode) to pick up individual components, place them onto the substrate, and then deposit them (in vacuum-off mode) in the desired location. The components are then interconnected via printed conductive traces to yield soft electronic devices that may find potential application in wearable electronics, soft robotics, and biomedical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 29, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703817, "DOI": "10.1002/adma.201703817", "DOI Link": "http://dx.doi.org/10.1002/adma.201703817", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413406200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, YP; Gao, XZ; Jiang, L; Chen, ZN; Wang, TM; Jie, JC; Kang, HJ; Zhang, YB; Guo, S; Ruan, HH; Zhao, YH; Cao, ZQ; Li, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yiping; Gao, Xuzhou; Jiang, Li; Chen, Zongning; Wang, Tongmin; Jie, Jinchuan; Kang, Huijun; Zhang, Yubo; Guo, Sheng; Ruan, Haihui; Zhao, Yonghao; Cao, Zhiqiang; Li, Tingju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High entropy alloys (HEAs) usually possess weak liquidity and castability, and considerable compositional inhomogeneity, mainly because they contain multiple elements with high concentrations. As a result, large-scale production of HEAs by casting is limited. To address the issue, the concept of eutectic high entropy alloys (EHEAs) was proposed, which has led to some promise in achieving good quality industrial scale HEAs ingots, and more importantly also good mechanical properties. In the practical large-scale casting, the actual composition of designed EHEAs could potentially deviate from the eutectic composition. The influence of such deviation on mechanical properties of EHEAs is important for industrial production, which constitutes the topic of the current work. Here we prepared industrial-scale HEAs ingots near the eutectic composition: hypoeutectic alloy, eutectic alloy and hypereutectic alloy. Our results showed that the deviation from eutectic composition does not significantly affect the mechanical properties, castability and the good mechanical properties of EHEAs can be achieved in a wide compositional range, and at both room and cryogenic temperatures. Our results suggested that EHEAs with simultaneous high strength and high ductility, and good liquidity and castability can be readily adapted to large-scale industrial production. The deformation behavior and microstructure evolution of the eutectic and near-eutectic HEAs were thoroughly studied using a combination of techniques, including strain measurement by digital image correlation, in-situ synchrotron X-ray diffraction, and transmission electron microscopy. The wavy strain distribution and the therefore resulted delay of necking in EHEAs were reported for the first time. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 877, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 143, "End Page": 150, "Article Number": null, "DOI": "10.1016/j.actamat.2016.11.016", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.11.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393000800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, CY; Lian, C; Hu, SC; Deng, ZS; Gong, JQ; Li, MD; Liu, HL; Xing, MY; Zhang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Chunyang; Lian, Cheng; Hu, Songchang; Deng, Zesheng; Gong, Jianqiu; Li, Mingde; Liu, Honglai; Xing, Mingyang; Zhang, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum nulloparticles (Pt NPs) are one of the most efficient cocatalysts in photocatalysis, and their size determines the activity and the selectivity of the catalytic reaction. Nevertheless, an in-depth understanding of the platinum's size effect in the carbon dioxide photocatalytic reduction is still lacking. Through analyses of the geometric features and electronic properties with variable-sized Pt NPs, here we show a prominent size effect of Pt NPs in both the activity and selectivity of carbon dioxide photocatalytic reduction. Decreasing the size of Pt NPs promotes the charge transfer efficiency, and thus enhances both the carbon dioxide photocatalytic reduction and hydrogen evolution reaction (HER) activity, but leads to higher selectivity towards hydrogen over methane. Combining experimental results and theoretical calculations, in Pt NPs, the terrace sites are revealed as the active sites for methane generation; meanwhile, the low-coordinated sites are more favorable in the competing HER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1252, "DOI": "10.1038/s41467-018-03666-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03666-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428520600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WB; Su, PC; Li, ZJ; Xu, ZH; Wang, F; Ou, HS; Zhang, JH; Zhang, GL; Zeng, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wanbin; Su, Pengcheng; Li, Zhanjun; Xu, Zehai; Wang, Fei; Ou, Huase; Zhang, Jiaheng; Zhang, Guoliang; Zeng, Eddy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin metal-organic framework membrane production by gel-vapour deposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin, molecular sieving membranes composed of microporous materials offer great potential to realize high permeances and selectivities in separation applications, but strategies for their production have remained a challenge. Here we show a route for the scalable production of nullometre-thick metal-organic framework (MOF) molecular sieving membranes, specifically via gel-vapour deposition, which combines sol-gel coating with vapour deposition for solvent-/modification-free and precursor-/time-saving synthesis. The uniform MOF membranes thus prepared have controllable thicknesses, down to similar to 17 nm, and show one to three orders of magnitude higher gas permeances than those of conventional membranes, up to 215.4 x 10(-7) mol m(-2) s(-1) Pa-1 for H-2, and H-2/C3H8, CO2/C3H8 and C3H6/C3H8 selectivities of as high as 3,400, 1,030 and 70, respectively. We further demonstrate the in situ scale-up processing of a MOF membrane module (30 polymeric hollow fibres with membrane area of 340 cm(2)) without deterioration in selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 406, "DOI": "10.1038/s41467-017-00544-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00544-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408820700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, CJ; Chen, G; Fu, YM; Wang, M; Matsuhisa, N; Pan, SW; Pan, L; Yang, H; Wan, Q; Zhu, LQ; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Changjin; Chen, Geng; Fu, Yangming; Wang, Ming; Matsuhisa, Naoji; Pan, Shaowu; Pan, Liang; Yang, Hui; Wan, Qing; Zhu, Liqiang; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Artificial Sensory Neuron with Tactile Perceptual Learning", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sensory neurons within skin form an interface between the external physical reality and the inner tactile perception. This interface enables sensory information to be organized identified, and interpreted through perceptual learningthe process whereby the sensing abilities improve through experience. Here, an artificial sensory neuron that can integrate and differentiate the spatiotemporal features of touched patterns for recognition is shown. The system comprises sensing, transmitting, and processing components that are parallel to those found in a sensory neuron. A resistive pressure sensor converts pressure stimuli into electric signals, which are transmitted to a synaptic transistor through interfacial ionic/electronic coupling via a soft ionic conductor. Furthermore, the recognition error rate can be dramatically decreased from 44% to 0.4% by integrating with the machine learning method. This work represents a step toward the design and use of neuromorphic electronic skin with artificial intelligence for robotics and prosthetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2018, "Volume": 30, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801291, "DOI": "10.1002/adma.201801291", "DOI Link": "http://dx.doi.org/10.1002/adma.201801291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439737700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QY; Cao, JJ; Wang, X; Liu, Y; Zhao, YJ; Wang, H; Liu, Y; Huang, H; Liao, F; Shao, MW; Kang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qingyao; Cao, Jingjing; Wang, Xiao; Liu, Yan; Zhao, Yajie; Wang, Hui; Liu, Yang; Huang, Hui; Liao, Fan; Shao, Mingwang; Kang, Zhenghui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A metal-free photocatalyst for highly efficient hydrogen peroxide photoproduction in real seawater", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis of H2O2 from H2O and O-2, as a spotless method, has aroused widespread interest. Up to date, most photocatalysts still suffer from serious salt-deactivated effects with huge consumption of photogenerated charges, which severely limit their wide application. Herein, by using a phenolic condensation approach, carbon dots, organic dye molecule procyanidins and 4-methoxybenzaldehyde are composed into a metal-free photocatalyst for the photosynthetic production of H2O2 in seawater. This catalyst exhibits high photocatalytic ability to produce H2O2 with the yield of 1776 mu mol g(-1)h(-1) (lambda >= 420nm; 34.8mWcm(-2)) in real seawater, about 4.8 times higher than the pure polymer. Combining with in-situ photoelectrochemical and transient photovoltage analysis, the active site and the catalytic mechanism of this composite catalyst in seawater are also clearly clarified. This work opens up an avenue for a highly efficient and practical, available catalyst for H2O2 photoproduction in real seawater. It is a challenge to produce hydrogen peroxide in seawater by photocatalysis. Here, the authors design and synthesize a metal-free photocatalyst based on carbon dots with a salt-protective electron sink effect, which exhibits enhanced hydrogen peroxide photoproduction in real seawater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 483, "DOI": "10.1038/s41467-020-20823-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20823-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613566500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XR; Han, XP; Cao, YH; Zhang, Y; Nordlund, D; Wang, JH; Chou, SL; Liu, H; Li, LL; Zhong, C; Deng, YD; Hu, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xuerong; Han, Xiaopeng; Cao, Yanhui; Zhang, Yan; Nordlund, Dennis; Wang, Jihui; Chou, Shulei; Liu, Hui; Li, Lanlan; Zhong, Cheng; Deng, Yida; Hu, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying Dense NiSe2/CoSe2 Heterointerfaces Coupled with Surface High-Valence Bimetallic Sites for Synergistically Enhanced Oxygen Electrocatalysis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing heterostructures with abundant interfaces is essential for integrating the multiple functionalities in single entities. Herein, the synthesis of NiSe2/CoSe2 heterostructures with different interfacial densities via an innovative strategy of successive ion injection is reported. The resulting hybrid electrocatalyst with dense heterointerfaces exhibits superior electrocatalytic properties in an alkaline electrolyte, superior to other benchmarks and precious metal catalysts. Advanced synchrotron techniques, post structural characterizations, and density functional theory (DFT) simulations reveal that the introduction of atomic-level interfaces can lower the oxidation overpotential of bimetallic Ni and Co active sites (whereas Ni2+ can be more easily activated than Co2+) and induce the electronic interaction between the core selenides and surface in situ generated oxides/hydroxides, which play a critical role in synergistically reducing energetic barriers and accelerating reaction kinetics for catalyzing the oxygen evolution. Hence, the heterointerface structure facilitates the catalytic performance enhancement via increasing the intrinsic reactivity of metallic atoms and enhancing the synergistic effect between the inner selenides and surface oxidation species. This work not only complements the understanding on the origins of the activity of electrocatalysts based on metal selenides, but also sheds light on further surface and interfacial engineering of advanced hybrid materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 32, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000607, "DOI": "10.1002/adma.202000607", "DOI Link": "http://dx.doi.org/10.1002/adma.202000607", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535525600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, WY; Wang, CY; Wang, HM; Jian, MQ; Lu, WD; Liang, XP; Zhang, X; Yang, FC; Zhang, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Wenya; Wang, Chunya; Wang, Huimin; Jian, Muqiang; Lu, Wangdong; Liang, Xiaoping; Zhang, Xin; Yang, Fengchun; Zhang, Yingying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated textile sensor patch for real-time and multiplex sweat analysis", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sweat analysis devices for monitoring of multiple health-related biomarkers with high sensitivity are highly desired for noninvasive and real-time monitoring of human health. Here, we report a flexible sweat analysis patch based on a silk fabric-derived carbon textile for simultaneous detection of six health-related biomarkers. The intrinsically N-doped graphitic structure and the hierarchical woven, porous structure provided the carbon textile good electrical conductivity, rich active sites, and good water wettability for efficient electron transmission and abundant access to reactants, enabling it to serve as an excellent working electrode in electrochemical sensors. On the basis of the above, we fabricated a multiplex sweat analysis patch that is capable of simultaneous detection of glucose, lactate, ascorbic acid, uric acid, Na+, and K+. The integration of selective detectors with signal collection and transmission components in this device has enabled us to realize real-time analysis of sweat.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax0649", "DOI": "10.1126/sciadv.aax0649", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax0649", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499736100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, H; Ma, L; Wan, QX; Tan, SZ; Yang, B; Wang, ZL; Mai, WJ; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Hang; Ma, Liang; Wan, Qixiang; Tan, Shaozao; Yang, Bo; Wang, Zilong; Mai, Wenjie; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting Surface Reconstruction of NiFe Layered Double Hydroxide for Enhanced Oxygen Evolution", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A dynamic surface reconstruction of oxide electrocatalysts in alkaline media is widely observed especially for layered double hydroxide (LDH), but little is known about how to promote the reconstruction toward desired surfaces for improved oxygen evolution reaction (OER). Here, surface reconstruction of NiFe LDH nullosheets is successfully induced to a higher degree via in situ sulfur doping than that by natural electrochemical activation. Theoretical calculations, operando Raman, and various ex situ characterizations reveal the S anion-induced effect can lower the energy barrier and facilitate the phase transformation into highly active S-doped oxyhydroxides. The generated S-NixFeyOOH can optimize the intermediate adsorption and facilitate the OER kinetics. The reconstructed S-oxyhydroxides catalyst presents superior OER activity and long-term durability compared to undoped ones. This work provides a structure-composition-activity relationship during the in situ surface restructuring of NiFe LDH pre-catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 12, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202202522", "DOI Link": "http://dx.doi.org/10.1002/aenm.202202522", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000876131900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, XW; Luo, MM; Liu, G; Wang, XS; Tao, W; Lin, YX; Ji, XY; Nie, L; Mei, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Xiaowei; Luo, Miaomiao; Liu, Gan; Wang, Xusheng; Tao, Wei; Lin, Yaoxin; Ji, Xiaoyuan; Nie, Lin; Mei, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine-Modified Black Phosphorous nullocapsule with Enhanced Stability and Photothermal Performance for Tumor Multimodal Treatments", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a novel 2D material, black phosphorus (BP) nullosheets are considered as a promising candidate for drug delivery platform for synergistic chemo/photothermal therapy. However, the intrinsic instability of bare BP poses a challenge in its biomedical applications. To date, some strategies have been employed to prevent BP from rapid ambient degradation. Unfortunately, most of these strategies are not suitable for the drug delivery systems. Here, a simple polydopamine modification method is developed to enhance the stability and photothermal performance of bare BP nullosheets. Then, this nullocapsule is used as a multifunctional codelivery system for the targeted chemo, gene, and photothermal therapy against multidrug-resistant cancer. The enhanced tumor therapy effect is demonstrated by both in vitro and in vivo studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 500, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800510, "DOI": "10.1002/advs.201800510", "DOI Link": "http://dx.doi.org/10.1002/advs.201800510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YJ; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yongjin; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Advances on Mixed Metal Sulfides for Advanced Sodium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) have drawn enormous attention in the past few years from both academic and industrial battery communities in view of the fascinating advantages of rich abundance and low cost of sodium resources. Among various electrode materials, mixed metal sulfides (MMSs) stand out as promising negative electrode materials for SIBs considering their superior structural and compositional advantages, such as decent electrochemical reversibility, high electronic conductivity, and rich redox reactions. Here, a summary of some recent developments in the rational design and synthesis of various kinds of MMSs with tailorable architectures, structural/compositional complexity, controllable morphologies, and enhanced electrochemical properties is presented. The effect of structural engineering and compositional design of MMSs on the sodium storage properties is highlighted. It is anticipated that further innovative works on the material design of advanced electrodes for batteries can be inspired.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 32, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002976, "DOI": "10.1002/adma.202002976", "DOI Link": "http://dx.doi.org/10.1002/adma.202002976", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567835200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YM; Kravchenko, II; Briggs, DP; Valentine, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yuanmu; Kravchenko, Ivan I.; Briggs, Dayrl P.; Valentine, Jason", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-dielectric metasurface analogue of electromagnetically induced transparency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurface analogues of electromagnetically induced transparency (EIT) have been a focus of the nullophotonics field in recent years, due to their ability to produce high-quality factor ( Q-factor) resonullces. Such resonullces are expected to be useful for applications such as low-loss slow-light devices and highly sensitive optical sensors. However, ohmic losses limit the achievable Q-factors in conventional plasmonic EIT metasurfaces to values < similar to 10, significantly hampering device performance. Here we experimentally demonstrate a classical analogue of EIT using all-dielectric silicon-based metasurfaces. Due to extremely low absorption loss and coherent interaction of neighbouring meta-atoms, a Q-factor of 483 is observed, leading to a refractive index sensor with a figure-of-merit of 103. Furthermore, we show that the dielectric metasurfaces can be engineered to confine the optical field in either the silicon resonator or the environment, allowing one to tailor light-matter interaction at the nulloscale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 842, "Times Cited, All Databases": 895, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5753, "DOI": "10.1038/ncomms6753", "DOI Link": "http://dx.doi.org/10.1038/ncomms6753", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347611700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bentel, MJ; Yu, YC; Xu, LH; Li, Z; Wong, BM; Men, YJ; Liu, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bentel, Michael J.; Yu, Yaochun; Xu, Lihua; Li, Zhong; Wong, Bryan M.; Men, Yujie; Liu, Jinyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defluorination of Per- and Polyfluoroalkyl Substances (PFASs) with Hydrated Electrons: Structural Dependence and Implications to PFAS Remediation and Management", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigates critical structure reactivity relationships within 34 representative per- and polyfluoroalkyl substances (PFASs) undergoing defluorination with UV-generated hydrated electrons. While CnF2n+1-COO- with variable fluoroalkyl chain lengths (n = 2 to 10) exhibited a similar rate and extent of parent compound decay and defluorination, the reactions of telomeric CnF2n+1-CH2CH2-COO- and CnF2n+1-SO3- showed an apparent dependence on the length of the fluoroalkyl chain. Cross comparison of experimental results, including different rates of decay and defluorination of specific PFAS categories, the incomplete defluorination from most PFAS structures, and the surprising 100% defluorination from CF3COO-, leads to the elucidation of new mechanistic insights into PFAS degradation. Theoretical calculations on the C-F bond dissociation energies (BDEs) of all PFAS structures reveal strong relationships among (i) the rate and extent of decay and defluorination, (ii) head functional groups, (iii) fluoroalkyl chain length, and (iv) the position and number of C-F bonds with low BDEs. These relationships are further supported by the spontaneous cleavage of specific bonds during calculated geometry optimization of PFAS structures bearing one extra electron, and by the product analyses with high-resolution mass spectrometry. Multiple reaction pathways, including H/F exchange, dissociation of terminal functional groups, and decarboxylation-triggered HF elimination and hydrolysis, result in the formation of variable defluorination products. The selectivity and ease of C-F bond cleavage highly depends on molecular structures. These findings provide critical information for developing PFAS treatment processes and technologies to destruct a wide scope of PFAS pollutants and for designing fluorochemical formulations to avoid releasing recalcitrant PFASs into the environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 53, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3718, "End Page": 3728, "Article Number": null, "DOI": "10.1021/acs.est.8b06648", "DOI Link": "http://dx.doi.org/10.1021/acs.est.8b06648", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463679600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LJ; O'Farrell, ECT; Loh, KP; Eda, G; Özyilmaz, B; Neto, AHC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, L. J.; O'Farrell, E. C. T.; Loh, K. P.; Eda, G.; Ozyilmaz, B.; Neto, A. H. Castro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling many-body states by the electric-field effect in a two-dimensional material", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To understand the complex physics of a system with strong electron-electron interactions, the ideal is to control and monitor its properties while tuning an external electric field applied to the system (the electric-field effect). Indeed, complete electric-field control of many-body states in strongly correlated electron systems is fundamental to the next generation of condensed matter research and devices(1-3). However, the material must be thin enough to avoid shielding of the electric field in the bulk material. Two-dimensional materials do not experience electrical screening, and their charge-carrier density can be controlled by gating. Octahedral titanium diselenide (1T-TiSe2) is a prototypical two-dimensional material that reveals a charge-density wave (CDW) and superconductivity in its phase diagram(4), presenting several similarities with other layered systems such as copper oxides(5), iron pnictides(6), and crystals of rare-earth elements and actinide atoms(7). By studying 1T-TiSe2 single crystals with thicknesses of 10 nullometres or less, encapsulated in two-dimensional layers of hexagonal boron nitride, we achieve unprecedented control over the CDW transition temperature (tuned from 170 kelvin to 40 kelvin), and over the superconductivity transition temperature (tuned from a quantum critical point at 0 kelvin up to 3 kelvin). Electrically driving TiSe2 over different ordered electronic phases allows us to study the details of the phase transitions between many-body states. Observations of periodic oscillations of magnetoresistance induced by the Little-Parks effect show that the appearance of superconductivity is directly correlated with the spatial texturing of the amplitude and phase of the superconductivity order parameter, corresponding to a two-dimensional matrix of superconductivity. We infer that this superconductivity matrix is supported by a matrix of incommensurate CDW states embedded in the commensurate CDW states. Our results show that spatially modulated electronic states are fundamental to the appearance of two-dimensional superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2016, "Volume": 529, "Issue": 7585, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 185, "End Page": "U129", "Article Number": null, "DOI": "10.1038/nature16175", "DOI Link": "http://dx.doi.org/10.1038/nature16175", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368015700031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, SB; Wang, BX; Gong, WB; He, ZZ; Xu, Q; Chen, WX; Zhang, QH; Zhu, YQ; Yang, JR; Fu, Q; Chen, C; Bu, YX; Gu, L; Sun, XM; Zhao, HJ; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Shubo; Wang, Bingxue; Gong, Wanbing; He, Zizhan; Xu, Qi; Chen, Wenxing; Zhang, Qinghua; Zhu, Youqi; Yang, Jiarui; Fu, Qiang; Chen, Chun; Bu, Yuxiang; Gu, Lin; Sun, Xiaoming; Zhao, Huijun; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically monodispersed heterogeneous catalysts with uniform active sites and high atom utilization efficiency are ideal heterogeneous catalytic materials. Designing such type of catalysts, however, remains a formidable challenge. Herein, using a wet-chemical method, we successfully achieved a mesoporous graphitic carbon nitride (mpg-C3N4) supported dual-atom Pt-2 catalyst, which exhibited excellent catalytic performance for the highly selective hydrogenation of nitrobenzene to aniline. The conversion of (>)99% is significantly superior to the corresponding values of mpg-C3N4-supported single Pt atoms and ultra-small Pt nulloparticles (similar to 2 nm). First-principles calculations revealed that the excellent and unique catalytic performance of the Pt-2 species originates from the facile H-2 dissociation induced by the diatomic characteristics of Pt and the easy desorption of the aniline product. The produced Pt-2/mpg-C3N4 samples are versatile and can be applied in catalyzing other important reactions, such as the selective hydrogenation of benzaldehyde and the epoxidation of styrene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3181, "DOI": "10.1038/s41467-021-23517-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23517-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658301200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Cheng, RY; Zhao, X; Zhang, YH; Tam, A; Yan, YF; Shen, HK; Zhang, YS; Qi, J; Feng, Y; Liu, L; Pan, GQ; Cui, WG; Deng, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Cheng, Ruoyu; Zhao, Xin; Zhang, Yuhui; Tam, Allison; Yan, Yufei; Shen, Haokai; Zhang, Yu Shrike; Qi, Jin; Feng, Yonghai; Liu, Lei; Pan, Guoqing; Cui, Wenguo; Deng, Lianfu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An injectable self-healing coordinative hydrogel with antibacterial and angiogenic properties for diabetic skin wound repair", "Source Title": "NPG ASIA MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report here an injectable, self-healing coordinative hydrogel with antibacterial and angiogenic properties for diabetic wound regeneration. The hydrogel was prepared by coordinative cross-linking of multi-arm thiolated polyethylene glycol (SH-PEG) with silver nitrate (AgNO3). Due to the dynamic nature of Ag-S coordination bond and bacteria-killing activity of Ag+, the resultant coordinative hydrogel featured self-healing, injectable and antibacterial properties. In this study, we synchronously loaded an angiogenic drug, desferrioxamine (DFO), in the coordinative hydrogel during cross-linking. We finally obtained a multifunctional hydrogel that is manageable, resistant to mechanical irritation, antibacterial and angiogenic in vitro. Our in vivo studies further demonstrated that the injectable self-healing hydrogel could efficiently repair diabetic skin wounds with low bacteria-infection and enhance angiogenic activity. In short, besides diabetic skin wound repair, such dynamic multifunctional hydrogel scaffolds would show great promise in the regeneration of different types of exposed wounds, in particular, in situations with disturbed physiological functions, high risk of bacterial infections, and external mechanical irritation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2019, "Volume": 11, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3, "DOI": "10.1038/s41427-018-0103-9", "DOI Link": "http://dx.doi.org/10.1038/s41427-018-0103-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457015500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Todaro, CJ; Easton, MA; Qiu, D; Zhang, D; Bermingham, MJ; Lui, EW; Brandt, M; StJohn, DH; Qian, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Todaro, C. J.; Easton, M. A.; Qiu, D.; Zhang, D.; Bermingham, M. J.; Lui, E. W.; Brandt, M.; StJohn, D. H.; Qian, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain structure control during metal 3D printing by high-intensity ultrasound", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) of metals, also known as metal 3D printing, typically leads to the formation of columnar grain structures along the build direction in most as-built metals and alloys. These long columnar grains can cause property anisotropy, which is usually detrimental to component qualification or targeted applications. Here, without changing alloy chemistry, we demonstrate an AM solidification-control solution to printing metallic alloys with an equiaxed grain structure and improved mechanical properties. Using the titanium alloy Ti-6Al-4V as a model alloy, we employ high-intensity ultrasound to achieve full transition from columnar grains to fine (similar to 100 mu m) equiaxed grains in AM Ti-6Al-4V samples by laser powder deposition. This results in a 12% improvement in both the yield stress and tensile strength compared with the conventional AM columnar Ti-6Al-4V. We further demonstrate the generality of our technique by achieving similar grain structure control results in the nickel-based superalloy Inconel 625, and expect that this method may be applicable to other metallic materials that exhibit columnar grain structures during AM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 525, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1038/s41467-019-13874-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13874-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511897900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miranda, I; Souza, A; Sousa, P; Ribeiro, J; Castanheira, EMS; Lima, R; Minas, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miranda, Ines; Souza, Andrews; Sousa, Paulo; Ribeiro, Joao; Castanheira, Elisabete M. S.; Lima, Rui; Minas, Graca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Properties and Applications of PDMS for Biomedical Engineering: A Review", "Source Title": "JOURNAL OF FUNCTIONAL BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydimethylsiloxane (PDMS) is an elastomer with excellent optical, electrical and mechanical properties, which makes it well-suited for several engineering applications. Due to its biocompatibility, PDMS is widely used for biomedical purposes. This widespread use has also led to the massification of the soft-lithography technique, introduced for facilitating the rapid prototyping of micro and nullostructures using elastomeric materials, most notably PDMS. This technique has allowed advances in microfluidic, electronic and biomedical fields. In this review, an overview of the properties of PDMS and some of its commonly used treatments, aiming at the suitability to those fields' needs, are presented. Applications such as microchips in the biomedical field, replication of cardiovascular flow and medical implants are also reviewed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2, "DOI": "10.3390/jfb13010002", "DOI Link": "http://dx.doi.org/10.3390/jfb13010002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000774935800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, XZ; Lu, YP; Zhang, B; Liang, NN; Wu, GZ; Sha, G; Liu, JZ; Zhao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xuzhou; Lu, Yiping; Zhang, Bo; Liang, Ningning; Wu, Guanzhong; Sha, Gang; Liu, Jizi; Zhao, Yonghao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructural origins of high strength and high ductility in an AlCoCrFeNi2.1 eutectic high-entropy alloy", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent studies indicate that eutectic high-entropy alloys can simultaneously possess high strength and high ductility, which have potential applications in industrial fields. Nevertheless, microstructural origins of the excellent strength-ductility combination remain unclear. In this study, an AlCoCrFeNi2.1 eutectic high-entropy alloy was prepared with face-centered cubic (FCC)(L1(2))/body-centered-cubic (BCC)(B2) modulated lamellar structures and a remarkable combination of ultimate tensile strength (1351 MPa) and ductility (15.4%) using the classical casting technique. Post-deformation transmission electron microscopy revealed that the FCC(L1(2)) phase was deformed in a matter of planar dislocation slip, with a slip system of {111} <110>, and stacking faults due to low stacking fault energy. Due to extreme solute drag, high densities of dislocations are distributed homogeneously at {111} slip plane. In the BCC(B2) phase, some dislocations exist on two {110) slip bands. The atom probe tomography analysis revealed a high density of Cr-enriched nullo-precipitates, which strengthened the BCC(B2) phase by Orowan mechanisms. Fracture surface observation revealed a ductile fracture in the FCC(L1(2)) phase and a brittle-like fracture in the BCC(B2) lamella. The underlying mechanism for the high strength and high ductility of AlCoCrFeNi2.1 eutectic high-entropy alloy was finally analyzed based on the coupling between the ductile FCC(L1(2)) and brittle BCC(B2) phases. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 604, "Times Cited, All Databases": 634, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 141, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": 66, "Article Number": null, "DOI": "10.1016/j.actamat.2017.07.041", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.07.041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415768100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, B; Tawiah, B; Wang, LQ; Yuen, ACY; Zhang, ZC; Shen, LL; Lin, B; Fei, B; Yang, W; Li, A; Zhu, SE; Hu, EZ; Lu, HD; Yeoh, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Bin; Tawiah, Benjamin; Wang, Lin-Qiang; Yuen, Anthony Chun Yin; Zhang, Zhen-Cheng; Shen, Lu-Lu; Lin, Bo; Fei, Bin; Yang, Wei; Li, Ao; Zhu, San-E; Hu, En-Zhu; Lu, Hong-Dian; Yeoh, Guan Heng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface decoration of exfoliated MXene ultra-thin nullosheets for fire and smoke suppressions of thermoplastic polyurethane elastomer", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoplastic polyurethane (TPU) has broad applications as lightweight materials due to its multiple advantages and unique properties. Nevertheless, toxicity emission under fire conditions remains a major concern, particularly in building fire scenarios. To circumvent the problem, it is imperative that an effective flame retardant is sought to suppress the flame and release of combustion/smoke products whilst maintaining the favorable material properties of TPU. In the current work, a simple method is proposed for the preparation and utilization of cetyltrimethyl ammonium bromide (CTAB) and tetrabutyl phosphine chloride (TBPC) modified Ti3C2 (MXene) ultra-thin nullosheets. During the cone calorimeter tests, significant reduction in peak heat release rate (51.2% and 52.2%), peak smoke production rate (57.1% and 57.4%), peak CO production (39.4% and 41.6%) and peak CO2 production (49.7% and 51.7%) were recorded by the mere introduction of 2 wt.% CTAB-Ti3C2 and TBPC-Ti3C2 to TPU. These superior fire safety properties resulting from the significant reduction of the fire, smoke and toxicity hazards are attributed to the excellent dispersion, catalytic and barrier effect of Ti3C2 ultra-thin nullosheets in TPU. Future applications of exfoliated MXene nullosheets as flame retardant appear to be very promising.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2019, "Volume": 374, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 110, "End Page": 119, "Article Number": null, "DOI": "10.1016/j.jhazmat.2019.04.026", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2019.04.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472694500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luc, W; Fu, XB; Shi, JJ; Lv, JJ; Jouny, M; Ko, BH; Xu, YB; Tu, Q; Hu, XB; Wu, JS; Yue, Q; Liu, YY; Jiao, F; Kang, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luc, Wesley; Fu, Xianbiao; Shi, Jianjian; Lv, Jing-Jing; Jouny, Matthew; Ko, Byung Hee; Xu, Yaobin; Tu, Qing; Hu, Xiaobing; Wu, Jinsong; Yue, Qin; Liu, Yuanyue; Jiao, Feng; Kang, Yijin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional copper nullosheets for electrochemical reduction of carbon monoxide to acetate", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Upgrading carbon dioxide to high-value multicarbon (C2+) products is one promising avenue for fuel and chemical production. Among all the monometallic catalysts, copper has attracted much attention because of its unique ability to convert CO2 or CO into C(2+)( )products with an appreciable selectivity. Although numerous attempts have been made to synthesize Cu materials that expose the desired facets, it still remains a challenge to obtain high-quality nullostructured Cu catalysts for the electroreduction of CO2/CO. Here we report a facile synthesis of freestanding triangular-shaped two-dimensional Cu nullosheets that selectively expose the (111) surface. In a 2 M KOH electrolyte, the Cu nullosheets exhibit an acetate Faradaic efficiency of 48% with an acetate partial current density up to 131mA cm(-2) in electrochemical CO reduction. Further analysis suggest that the high acetate selectivity is attributed to the suppression of ethylene and ethanol formation, probably due to the reduction of exposed (100) and (110) surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 423, "End Page": 430, "Article Number": null, "DOI": "10.1038/s41929-019-0269-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0269-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467975700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mo, RW; Rooney, D; Sun, KN; Yang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mo, Runwei; Rooney, David; Sun, Kening; Yang, Hui Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nulloarchitecture for high-performance flexible Li-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible electrochemical energy storage devices have attracted extensive attention as promising power sources for the ever-growing field of flexible and wearable electronic products. However, the rational design of a novel electrode structure with a good flexibility, high capacity, fast charge-discharge rate and long cycling lifetimes remains a long-standing challenge for developing next-generation flexible energy-storage materials. Herein, we develop a facile and general approach to three-dimensional (3D) interconnected porous nitrogen-doped graphene foam with encapsulated Ge quantum dot/nitrogen-doped graphene yolk-shell nullo architecture for high specific reversible capacity (1,220mAhg(-1)), long cycling capability (over 96% reversible capacity retention from the second to 1,000 cycles) and ultra-high rate performance (over 800 mAhg(-1) at 40 degrees C). This work paves a way to develop the 3D interconnected graphene-based high-capacity electrode material systems, particularly those that suffer from huge volume expansion, for the future development of high-performance flexible energy storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13949, "DOI": "10.1038/ncomms13949", "DOI Link": "http://dx.doi.org/10.1038/ncomms13949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391128100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huynh, M; Shi, CY; Billinge, SJL; Nocera, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L.; Nocera, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of Activated Manganese Oxide for Oxygen Evolution", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrodeposited manganese oxide films (MnOx) are promising stable oxygen evolution catalysts. They are able to catalyze the oxygen evolution reaction in acidic solutions but with only modest activity when prepared by constant anodic potential deposition. We now show that the performance of these catalysts is improved when they are activated by potential cycling protocols, as measured by Tafel analysis (where lower slope is better): upon activation the Tafel slope decreases from similar to 120 to similar to 70 mV/decade in neutral conditions and from similar to 650 to similar to 90 mV/decade in acidic solutions. Electrochemical, spectroscopic, and structural methods were employed to study the activation process and support a mechanism where the original bimessite-like MnOx (delta-MnO2) undergoes a phase change, induced by comproportionation with cathodically generated Mn(OH)2, to a hausmannite-like intermediate (alpha-Mn3O4). Subsequent anodic conditioning from voltage cycling or water oxidation produces a disordered birnessite-like phase, which is highly active for oxygen evolution. At pH 2.5, the current density of activated MnOx (at an overpotential of 600 mV) is 2 orders of magnitude higher than that of the original MnOx and begins to approach that of Ru and Ir oxides in acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2015, "Volume": 137, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14887, "End Page": 14904, "Article Number": null, "DOI": "10.1021/jacs.5b06382", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b06382", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365930600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Q; Xiong, PX; Liu, JJ; Xie, Z; Wang, QC; Yang, XQ; Hu, EY; Cao, Y; Sun, J; Xu, YH; Chen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Qiang; Xiong, Peixun; Liu, Jingjuan; Xie, Zhen; Wang, Qinchao; Yang, Xiao-Qing; Hu, Enyuan; Cao, Yu; Sun, Jie; Xu, Yunhua; Chen, Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Redox-Active 2D Metal-Organic Framework for Efficient Lithium Storage with Extraordinary High Capacity", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic framework cathodes usually exhibit low capacity and poor electrochemical performance for Li-ion storage owing to intrinsic low conductivity and inferior redox activity. Now a redox-active 2D copper-benzoquinoid (Cu-THQ) MOF has been synthesized by a simple solvothermal method. The abundant porosity and intrinsic redox character endow the 2D Cu-THQ MOF with promising electrochemical activity. Superior performance is achieved as a Li-ion battery cathode with a high reversible capacity (387 mA h g(-1)), large specific energy density (775 Wh kg(-1)), and good cycling stability. The reaction mechanism is unveiled by comprehensive spectroscopic techniques: a three-electron redox reaction per coordination unit and one-electron redox reaction per copper ion mechanism is demonstrated. This elucidatory understanding sheds new light on future rational design of high-performance MOF-based cathode materials for efficient energy storage and conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 59, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5273, "End Page": 5277, "Article Number": null, "DOI": "10.1002/anie.201914395", "DOI Link": "http://dx.doi.org/10.1002/anie.201914395", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509620500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, HJ; Huang, H; Li, MH; Gao, XX; Yin, L; Qi, RX; Wu, RS; Chen, XJ; Ma, YX; Shi, KR; Li, CH; Maus, TM; Huang, B; Lu, C; Lin, MY; Zhou, S; Lou, ZY; Gu, Y; Chen, YM; Lei, YS; Wang, XY; Wang, RT; Yue, WT; Yang, XY; Bian, YZ; Mu, J; Park, G; Xiang, S; Cai, SQ; Corey, PW; Wang, JS; Xu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Hongjie; Huang, Hao; Li, Mohan; Gao, Xiaoxiang; Yin, Lu; Qi, Ruixiang; Wu, Ray S.; Chen, Xiangjun; Ma, Yuxiang; Shi, Keren; Li, Chenghai; Maus, Timothy M.; Huang, Brady; Lu, Chengchangfeng; Lin, Muyang; Zhou, Sai; Lou, Zhiyuan; Gu, Yue; Chen, Yimu; Lei, Yusheng; Wang, Xinyu; Wang, Ruotao; Yue, Wentong; Yang, Xinyi; Bian, Yizhou; Mu, Jing; Park, Geonho; Xiang, Shu; Cai, Shengqiang; Corey, Paul W.; Wang, Joseph; Xu, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A wearable cardiac ultrasound imager", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous imaging of cardiac functions is highly desirable for the assessment of long-term cardiovascular health, detection of acute cardiac dysfunction and clinical management of critically ill or surgical patients(1-4). However, conventional non-invasive approaches to image the cardiac function cannot provide continuous measurements owing to device bulkiness(5-11), and existing wearable cardiac devices can only capture signals on the skin(12-16). Here we report a wearable ultrasonic device for continuous, real-time and direct cardiac function assessment. We introduce innovations in device design and material fabrication that improve the mechanical coupling between the device and human skin, allowing the left ventricle to be examined from different views during motion. We also develop a deep learning model that automatically extracts the left ventricular volume from the continuous image recording, yielding waveforms of key cardiac performance indices such as stroke volume, cardiac output and ejection fraction. This technology enables dynamic wearable monitoring of cardiac performance with substantially improved accuracy in various environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 613, "Issue": 7945, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-022-05498-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05498-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930959700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarycheva, A; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarycheva, Asia; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2Tx MXene", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Raman spectroscopy is one of the most useful tools for the analysis of two-dimensional (2D) materials. While MXenes are a very large family of 2D transition metal carbides and nitrides, there have been just a few Raman studies of materials from this family. Here, we report on a systematic study of the most widely used and most important MXene to date: Ti3C2Tx. By synthesizing material using different methods, we show that Raman spectra of Ti3C2Tx are affected not only by the composition and surface groups but also by intercalated species and stacking. Due to a plasmonic peak of Ti3C2Tx around 785 nm, resonullt conditions are achieved, enabling us to observe an extra peak at similar to 120 cm(-1), when excited with a red diode laser. We report differences in Raman spectra collected from single flakes of Ti3C2Tx colloidal solutions, and multilayer films. Lastly, we show how an undesirable photoluminescent background could serve as evidence of material degradation, which leads to the formation of defective titania and amorphous carbon. This study shows how Raman spectroscopy can be used for the characterization of important emerging 2D materials: MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 965, "Times Cited, All Databases": 992, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2020, "Volume": 32, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3480, "End Page": 3488, "Article Number": null, "DOI": "10.1021/acs.chemmater.0c00359", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.0c00359", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529878600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Clark, EL; Hahn, C; Jaramillo, TF; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Clark, Ezra L.; Hahn, Christopher; Jaramillo, Thomas F.; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical CO2 Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of carbon dioxide using renewably generated electricity offers a potential means for producing fuels and chemicals in a sustainable manner. To date, copper has been found to be the most effective catalyst for electrochemically reducing carbon dioxide to products such as methane, ethene, and ethanol. Unfortunately, the current efficiency of the process is limited by competition with the relatively facile hydrogen evolution reaction. Since multi-carbon products are more valuable precursors to chemicals and fuels than methane, there is considerable interest in modifying copper to enhance the multi-carbon product selectivity. Here, we report our investigations of electrochemical carbon dioxide reduction over CuAg bimetallic electrodes and surface alloys, which we find to be more selective for the formation of multi-carbon products than pure copper: This selectivity enhancement is a result of the selective suppression of hydrogen evolution, which occurs due to compressive strain induced by the formation of a CuAg surface alloy. Furthermore, we report that these bimetallic electrocatalysts exhibit an unusually high selectivity for the formation of multi-carbon carbonyl-containing products, which we hypothesize to be the consequence of a reduced coverage of adsorbed hydrogen and the reduced oxophilicity of the compressively strained copper. Thus, we show that promoting copper surface with small amounts of Ag is a promising means for improving the multi-carbon oxygenated product selectivity of copper during electrochemical CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 550, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2017, "Volume": 139, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15848, "End Page": 15857, "Article Number": null, "DOI": "10.1021/jacs.7b08607", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b08607", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415028200046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, Y; Xia, QN; Dong, L; Liu, XH; Han, X; Parker, SF; Cheng, YQ; Daemen, LL; Ramirez-Cuesta, AJ; Yang, SH; Wang, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Yi; Xia, Qineng; Dong, Lin; Liu, Xiaohui; Han, Xue; Parker, Stewart F.; Cheng, Yongqiang; Daemen, Luke L.; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Wang, Yanqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective production of arenes via direct lignin upgrading over a niobium-based catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignin is the only large-volume renewable source of aromatic chemicals. Efficient depolymerization and deoxygenation of lignin while retaining the aromatic functionality are attractive but extremely challenging. Here we report the selective production of arenes via direct hydrodeoxygenation of organosolv lignin over a porous Ru/Nb2O5 catalyst that enabled the complete removal of the oxygen content from lignin. The conversion of birch lignin to monomer C-7-C-9 hydrocarbons is nearly quantitative based on its monomer content, with a total mass yield of 35.5 wt% and an exceptional arene selectivity of 71 wt%. Inelastic neutron scattering and DFT calculations confirm that the Nb2O5 support is catalytically unique compared with other traditional oxide supports, and the disassociation energy of C-aromatic-OH bonds in phenolics is significantly reduced upon adsorption on Nb2O5, resulting in its distinct selectivity to arenes. This one-pot process provides a promising approach for improved lignin valorization with general applicability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 483, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16104, "DOI": "10.1038/ncomms16104", "DOI Link": "http://dx.doi.org/10.1038/ncomms16104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406151500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, CY; Tian, CC; Jiang, JS; Dang, Y; Liu, Y; Duan, XX; Li, QN; Chen, XJ; Xie, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Chunyu; Tian, Chengcheng; Jiang, Jiashun; Dang, Yu; Liu, Yang; Duan, Xuexin; Li, Quanning; Chen, Xuejiao; Xie, Mengying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive Linear Capacitive Pressure Sensor with Wrinkled Microstructures for Tactile Perception", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrasensitive flexible pressure sensors with excellent linearity are essential for achieving tactile perception. Although microstructured dielectrics have endowed capacitive sensors with ultrahigh sensitivity, the compromise of sensitivity with increasing pressure is an issue yet to be resolved. Herein, a spontaneously wrinkled MWCNT/PDMS dielectric layer is proposed to realize the excellent sensitivity and linearity of capacitive sensors for tactile perception. The synergistic effect of a high dielectric constant and wrinkled microstructures enables the sensor to exhibit linearity up to 21 kPa with a sensitivity of 1.448 kPa(-1) and a detection limit of 0.2 Pa. Owing to these merits, the sensor monitors subtle physiological signals such as various arterial pulses and respiration. This sensor is further integrated into a fully multimaterial 3D-printed soft pneumatic finger to realize material hardness perception. Eight materials with different hardness values are successfully discriminated, and the capacitance of the sensor varies linearly (R-2 > 0.975) with increasing hardness. Moreover, the sensitivity to the material hardness can be tuned by controlling the inflation pressure of the soft finger. As a proof of concept, the finger is used to discriminate pork fats with different hardness, paving the way for hardness discrimination in clinical palpation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206807", "DOI Link": "http://dx.doi.org/10.1002/advs.202206807", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000949965000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, JW; Ruan, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Junwei; Ruan, Kunpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking Through Bottlenecks for Thermally Conductive Polymer Composites: A Perspective for Intrinsic Thermal Conductivity, Interfacial Thermal Resistance and Theoretics", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid development of energy, electrical and electronic technologies has put forward higher requirements for the thermal conductivities of polymers and their composites. However, the thermal conductivity coefficient (lambda) values of prepared thermally conductive polymer composites are still difficult to achieve expectations, which has become the bottleneck in the fields of thermally conductive polymer composites. Aimed at that, based on the accumulation of the previous research works by related researchers and our research group, this paper proposes three possible directions for breaking through the bottlenecks: (1) preparing and synthesizing intrinsically thermally conductive polymers, (2) reducing the interfacial thermal resistance in thermally conductive polymer composites, and (3) establishing suitable thermal conduction models and studying inner thermal conduction mechanism to guide experimental optimization. Also, the future development trends of the three above-mentioned directions are foreseen, hoping to provide certain basis and guidance for the preparation, researches and development of thermally conductive polymers and their composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110, "DOI": "10.1007/s40820-021-00640-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00640-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640377900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Filippidi, E; Cristiani, TR; Eisenbach, CD; Waite, JH; Israelachvili, JN; Ahn, BK; Valentine, MT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filippidi, Emmanouela; Cristiani, Thomas R.; Eisenbach, Claus D.; Waite, J. Herbert; Israelachvili, Jacob N.; Ahn, B. Kollbe; Valentine, Megan T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toughening elastomers using mussel-inspired iron-catechol complexes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials often exhibit a trade-off between stiffness and extensibility; for example, strengthening elastomers by increasing their cross-link density leads to embrittlement and decreased toughness. Inspired by cuticles of marine mussel byssi, we circumvent this inherent trade-off by incorporating sacrificial, reversible iron-catechol cross-links into a dry, loosely cross-linked epoxy network. The iron-containing network exhibits two to three orders of magnitude increases in stiffness, tensile strength, and tensile toughness compared to its iron-free precursor while gaining recoverable hysteretic energy dissipation and maintaining its original extensibility. Compared to previous realizations of this chemistry in hydrogels, the dry nature of the network enables larger property enhancement owing to the cooperative effects of both the increased cross-link density given by the reversible iron-catecholate complexes and the chain-restricting ionomeric nullodomains that they form.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 582, "Times Cited, All Databases": 625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2017, "Volume": 358, "Issue": 6362, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 502, "End Page": 505, "Article Number": null, "DOI": "10.1126/science.aao0350", "DOI Link": "http://dx.doi.org/10.1126/science.aao0350", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413757500040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Li, B; Li, Y; Fan, XB; Zhang, FB; Zhang, GL; Peng, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jun; Li, Bin; Li, Yang; Fan, Xiaobin; Zhang, Fengbao; Zhang, Guoliang; Peng, Wenchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile Synthesis of Atomic Fe-N-C Materials and Dual Roles Investigation of Fe-N4 Sites in Fenton-Like Reactions", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fenton-like reactions with persulfates as the oxidants have attracted increasing attentions for the remediation of emerging antibiotic pollutions. However, developing effective activators with outstanding activities and long-term stabilities remains a great challenge in these reactions. Herein, a novel activator is successfully synthesized with single iron atoms anchored on porous N-doped carbon (Fe-N-PC) by a facile chemical vapor deposition (CVD) method. The single Fe atoms are coordinated with four N atoms according to the XANES, and the Fe-N-4-PC shows enhanced activity for the activation of peroxymonosulfate (PMS) to degrade sulfamethoxazole (SMX). The experiments and density functional theory (DFT) calculations reveal that the introduction of single Fe atoms will regulate the main active sites from graphite N into Fe-N-4, thus could enhance the stability and tune the PMS activation pathway from non-radical into radical dominated process. In addition, the N atoms connected with single Fe atoms in the Fe-N-4-C structure can be used to enhance the adsorption of organic molecules on these materials. Therefore, the Fe-N-4-C here has dual roles for antibiotics adsorption and PMS activation. The CVD synthesized Fe-N-4-C shows enhanced performance in persulfates based Fenton-like reactions, thus has great potential in the environmental remediation field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 8, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101824, "DOI": "10.1002/advs.202101824", "DOI Link": "http://dx.doi.org/10.1002/advs.202101824", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000706545400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, FH; Goo, H; Hao, JN; Zhang, SL; Li, P; Liu, YQ; Chen, J; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Fuhua; Goo, Hong; Hao, Junnull; Zhang, Shilin; Li, Peng; Liu, Yuqing; Chen, Jun; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Yolk-Shell Structured FeP@C nulloboxes as Advanced Anode Materials for Rechargeable Lithium-/Potassium-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Maintaining structural stability and alleviating the intrinsic poor conductivity of conversion-type reaction anode materials are of great importance for practical application. Introducing void space and a highly conductive host to accommodate the volume changes and enhance the conductivity would be a smart design to achieve robust construction; effective electron and ion transportation, thus, lead to prolonged cycling life and excellent rate performance. Herein, uniform yolk-shell FeP@C nulloboxes (FeP@CNBs) with the inner FeP nulloparticles completely protected by a thin and self-supported carbon shell are synthesized through a phosphidation process with yolk-shell Fe2O3@CNBs as a precursor. The volumetric variation of the inner FeP nulloparticles during cycling is alleviated, and the FeP nulloparticles can expand without deforming the carbon shell, thanks to the internal void space of the unique yolk-shell structure, thus preserving the electrode microstructure. Furthermore, the presence of the highly conductive carbon shell enhances the conductivity of the whole electrode. Benefiting from the unique design of the yolk-shell structure, the FeP@CNBs manifests remarkable lithium/potassium storage performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2019, "Volume": 29, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1808291, "DOI": "10.1002/adfm.201808291", "DOI Link": "http://dx.doi.org/10.1002/adfm.201808291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467385200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fathieh, F; Kalmutzki, MJ; Kapustin, EA; Waller, PJ; Yang, JJ; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fathieh, Farhad; Kalmutzki, Markus J.; Kapustin, Eugene A.; Waller, Peter J.; Yang, Jingjing; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Practical water production from desert air", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy-efficient production of water from desert air has not been developed. A proof-of-concept device for harvesting water at low relative humidity was reported; however, it used external cooling and was not desert-tested. We report a laboratory-to-desert experiment where a prototype using up to 1.2 kg of metal-organic framework (MOF)-801 was tested in the laboratory and later in the desert of Arizona, USA. It produced 100 g of water per kilogram of MOF-801 per day-and-night cycle, using only natural cooling and ambient sunlight as a source of energy. We also report an aluminum based MOF-303, which delivers more than twice the amount of water. The desert experiment uncovered key parameters pertaining to the energy, material, and air requirements for efficient production of water from desert air, even at a subzero dew point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat3198", "DOI": "10.1126/sciadv.aat3198", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat3198", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YP; Yi, NB; Huang, L; Zhang, TF; Fang, SL; Chang, HC; Li, N; Oh, J; Lee, JA; Kozlov, M; Chipara, AC; Terrones, H; Xiao, P; Long, GK; Huang, Y; Zhang, F; Zhang, L; Lepró, X; Haines, C; Lima, MD; Lopez, NP; Rajukumar, LP; Elias, AL; Feng, SM; Kim, SJ; Narayanull, NT; Ajayan, PM; Terrones, M; Aliev, A; Chu, PF; Zhang, Z; Baughman, RH; Chen, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yingpeng; Yi, Ningbo; Huang, Lu; Zhang, Tengfei; Fang, Shaoli; Chang, Huicong; Li, Na; Oh, Jiyoung; Lee, Jae Ah; Kozlov, Mikhail; Chipara, Alin C.; Terrones, Humberto; Xiao, Peishuang; Long, Guankui; Huang, Yi; Zhang, Fan; Zhang, Long; Lepro, Xavier; Haines, Carter; Lima, Marcio Dias; Lopez, Nestor Perea; Rajukumar, Lakshmy P.; Elias, Ana L.; Feng, Simin; Kim, Seon Jeong; Narayanull, N. T.; Ajayan, Pulickel M.; Terrones, Mauricio; Aliev, Ali; Chu, Pengfei; Zhang, Zhong; Baughman, Ray H.; Chen, Yongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensionally bonded spongy graphene material with super compressive elasticity and near-zero Poisson's ratio", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is a challenge to fabricate graphene bulk materials with properties arising from the nature of individual graphene sheets, and which assemble into monolithic three-dimensional structures. Here we report the scalable self-assembly of randomly oriented graphene sheets into additive-free, essentially homogenous graphene sponge materials that provide a combination of both cork-like and rubber-like properties. These graphene sponges, with densities similar to air, display Poisson's ratios in all directions that are near-zero and largely strain-independent during reversible compression to giant strains. And at the same time, they function as enthalpic rubbers, which can recover up to 98% compression in air and 90% in liquids, and operate between -196 and 900 degrees C. Furthermore, these sponges provide reversible liquid absorption for hundreds of cycles and then discharge it within seconds, while still providing an effective near-zero Poisson's ratio.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6141, "DOI": "10.1038/ncomms7141", "DOI Link": "http://dx.doi.org/10.1038/ncomms7141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348832400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LS; Yang, J; Yang, YQ; Qian, FR; Wang, Q; Sun-Waterhouse, D; Shang, L; Zhang, TR; Waterhouse, GIN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lishan; Yang, Jiao; Yang, Yuqi; Qian, Fangren; Wang, Qing; Sun-Waterhouse, Dongxiao; Shang, Lu; Zhang, Tierui; Waterhouse, Geoffrey I. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesopore-Rich Fe-N-C Catalyst with FeN4-O-NC Single-Atom Sites Delivers Remarkable Oxygen Reduction Reaction Performance in Alkaline Media", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fe-N-C catalysts offer excellent performance for the oxygen reduction reaction (ORR) in alkaline media. With a view toward boosting the intrinsic ORR activity of Fe single-atom sites in Fe-N-C catalysts, fine-tuning the local coordination of the Fe sites to optimize the binding energies of ORR intermediates is imperative. Herein, a porous FeN4-O-NCR electrocatalyst rich in catalytically accessible FeN4-O sites (wherein the Fe single atoms are coordinated to four in-plane nitrogen atoms and one subsurface axial oxygen atom) supported on N-doped carbon nullorods (NCR) is reported. Fe K-edge X-ray absorption spectroscopy (XAS) verifies the presence of FeN4-O active sites in FeN4-O-NCR, while density functional theory calculations reveal that the FeN4-O coordination offers a lower energy and more selective 4-electron/4-proton ORR pathway compared to traditional FeN4 sites. Electrochemical tests validate the outstanding intrinsic activity of FeN4-O-NCR for alkaline ORR, outperforming Pt/C and almost all other M-N-C catalysts reported to date. A primary zinc-air battery constructed using FeN4-O-NCR delivers a peak power density of 214.2 mW cm(-2) at a current density of 334.1 mA cm(-2), highlighting the benefits of optimizing the local coordination of iron single atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 34, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202544, "DOI": "10.1002/adma.202202544", "DOI Link": "http://dx.doi.org/10.1002/adma.202202544", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809631500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, XY; Wong, R; Anisa, A; Ma, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Xueying; Wong, Raymond; Anisa, Anee; Ma, Shengqian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent development of metal-organic framework nullocomposites for biomedical applications", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Albeit metal-organic framework (MOF) composites have been extensively explored, reducing the size and dimensions of various contents within the composition, to the nulloscale regime, has recently presented unique opportunities for enhanced properties with the formation of MOF-based nullocomposites. Many distinctive strategies have been used to fabricate these nullocomposites such as through the introduction of nulloparticles (NPs) into a MOF precursor solution or vice versa to achieve a core-shell or heterostructure configuration. As such, MOF-based nullocomposites offer seemingly limitless possibilities and promising solutions for the vast range of applications across biomedical disciplines especially for improving in vivo implementation. In this review, we focus on the recent development of MOF-based nullocomposites, outline their classification according to the type of integrations (NPs, coating materials, and different MOF-derived nullocomposites), and direct special attention towards the various approaches and strategies employed to construct these nullocomposites for their prospective utilization in biomedical applications including biomimetic enzymes and photo, chemo, sonodynamic, starvation and hyperthermia therapies. Lastly, our work aims to highlight the exciting potential as well as the challenges of MOF-based nullocomposites to help guide future research as well as to contribute to the progress of MOF-based nullotechnology in biomedicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 281, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121322, "DOI": "10.1016/j.biomaterials.2021.121322", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2021.121322", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779492300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, SM; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Simiao; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theoretical systems of triboelectric nullogenerators", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerator (TENG) technology based on contact electrification and electrostatic induction is an emerging new mechanical energy harvesting technology with numerous advantages. The current area power density of TENGs has reached 313 W/m(2) and their volume energy density has reached 490 kW/m(3). In this review, we systematically analyzed the theoretical system of triboelectric nullogenerators. Starting from the physics of TENGs, we thoroughly discussed their fundamental working principle and simulation method. Then the intrinsic output characteristics, load characteristics, and optimization strategy is in-depth discussed. TENGs have inherent capacitive behavior and their governing equation is their V-Q-x relationship. There are two capacitance formed between the tribo-charged dielectric surface and the two metal electrodes, respectively. The ratio of these two capacitances changes with the position of this dielectric surface, inducing electrons to transfer between the metal electrodes under short circuit conditions. This is the core working mechanism of triboelectric generators and different TENG fundamental modes can be classified based on the changing behavior of these two capacitances. Their first-order lumped-parameter equivalent circuit model is a voltage source in series with a capacitor. Their resistive load characteristics have a three-working-region behavior because of the impedance match mechanism. Besides, when TENGs are utilized to charge a capacitor with a bridge rectifier in multiple motion cycles, it is equivalent to utilizing a constant DC voltage source with an internal resistance to charge. The optimization techniques for all TENG fundamental modes are also discussed in detail. The theoretical system reviewed in this work provides a theoretical basis of TENGs and can be utilized as a guideline for TENG designers to continue improving TENG output performance. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 887, "Times Cited, All Databases": 917, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 14, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 161, "End Page": 192, "Article Number": null, "DOI": "10.1016/j.nulloen.2014.11.034", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2014.11.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356984500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, LL; Ke, WJ; Pedesseau, L; Wu, YL; Katan, C; Even, J; Wasielewski, MR; Stoumpos, CC; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Lingling; Ke, Weijun; Pedesseau, Laurent; Wu, Yilei; Katan, Claudine; Even, Jacky; Wasielewski, Michael R.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Dion-Jacobson 2D Lead Iodide Perovskites", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The three-dimensional hybrid organic-inorganic perovskites have shown huge potential for use in solar cells and other optoelectronic devices. Although these materials are under intense investigation, derivative materials with lower dimensionality are emerging, offering higher tunability of physical properties and new capabilities. Here, we present two new series of hybrid two-dimensional (2D) perovskites that adopt the Dion-Jacobson (DJ) structure type, which are the first complete homologous series reported in halide perovskite chemistry. Lead iodide DJ perovskites adopt a general formula A'A(n-1),PbnI3n+1 (A' = 3-(aminomethyl)piperidinium (3AMP) or 4-(aminomethyl)piperidinium (4AMP), A = methylammonium (MA)). These materials have layered structures where the stacking of inorganic layers is unique as they lay exactly on top of another. With a slightly different position of the functional group in the templating cation 3AMP and 4AMP, the as-formed DJ perovskites show different optical properties, with the 3AMP series having smaller band gaps than the 4AMP series. Analysis on the crystal structures and density functional theory (DFT) calculations suggest that the origin of the systematic band gap shift is the strong but indirect influence of the organic cation on the inorganic framework. Fabrication of photovoltaic devices utilizing these materials as light absorbers reveals that (3AMP)(MA)(3)Pb4I13 has the best power conversion efficiency (PCE) of 7.32%, which is much higher than that of the corresponding (4AMP)(MA)(3)Pb4I13.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 764, "Times Cited, All Databases": 831, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 140, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3775, "End Page": 3783, "Article Number": null, "DOI": "10.1021/jacs.8b00542", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b00542", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427910700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XL; Zhang, XW; Deng, JX; Chu, ZM; Jiang, Q; Meng, JH; Wang, PY; Zhang, LQ; Yin, ZG; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaolei; Zhang, Xingwang; Deng, Jinxiang; Chu, Zema; Jiang, Qi; Meng, Junhua; Wang, Pengyang; Zhang, Liuqi; Yin, Zhigang; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient green light-emitting diodes based on quasi-two-dimensional composition and phase engineered perovskite with surface passivation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes (LEDs) are attracting great attention due to their efficient and narrow emission. Quasi-two-dimensional perovskites with Ruddlesden-Popper-type layered structures can enlarge exciton binding energy and confine charge carriers and are considered good candidate materials for efficient LEDs. However, these materials usually contain a mixture of phases and the phase impurity could cause low emission efficiency. In addition, converting three-dimensional into quasi-two-dimensional perovskite introduces more defects on the surface or at the grain boundaries due to the reduction of crystal sizes. Both factors limit the emission efficiency of LEDs. Here, firstly, through composition and phase engineering, optimal quasi-two-dimensional perovskites are selected. Secondly, surface passivation is carried out by coating organic small molecule trioctylphosphine oxide on the perovskite thin film surface. Accordingly, green LEDs based on quasi-two-dimensional perovskite reach a current efficiency of 62.4 cd A(-1) and external quantum efficiency of 14.36%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 908, "Times Cited, All Databases": 983, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 570, "DOI": "10.1038/s41467-018-02978-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-02978-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424451300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bérardan, D; Franger, S; Dragoe, D; Meena, AK; Dragoe, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Berardan, David; Franger, Sylvain; Dragoe, Diana; Meena, Arun Kumar; Dragoe, Nita", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colossal dielectric constant in high entropy oxides", "Source Title": "PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Entropic contributions to the stability of solids are very well understood and the mixing entropy has been used for forming various solids, for instance such as inverse spinels, see Nawrotsky et al., J. Inorg. Nucl. Chem. 29, 2701 (1967) [1]. A particular development was related to high entropy alloys by Yeh et al., Adv. Eng. Mater. 6, 299 (2004) [2] and Cantor et al., Mater. Sci. Eng. A 375-377, 213 (2004) [3] (for recent reviews see Zhang et al., Prog. Mater. Sci. 61, 1 (2014) [4] and Tsai et al., Mater. Res. Lett. 2, 107 (2014) [5]) in which the configurational disorder is responsible for forming simple solid solutions and which are thoroughly studied for various applications especially due to their mechanical properties, e.g. Gludovatz et al., Science 345, 1153 (2014) [6] and Lu et al., Sci. Rep. 4, 6200 (2014) [7], but also electrical properties, Kozelj et al., Phys. Rev. Lett. 113, 107001 (2014) [8], hydrogen storage, Kao et al., Int. J. Hydrogen Energy 35, 9046 (2010) [9], magnetic properties, Zhang et al., Sci. Rep. 3, 1455 (2013) [10]. Many unexplored compositions and properties still remain for this class of materials due to their large phase space. In a recent report it has been shown that the configurational disorder can be used for stabilizing simple solid solutions of oxides, which should normally not form solid solutions, see Rost et al., Nature Commun. 6, 8485 (2015) [11] these new materials were called entropy-stabilized oxides. In this pioneering report, it was shown that mixing five equimolar binary oxides yielded, after heating at high temperature and quenching, an unexpected rock salt structure compound with statistical distribution of the cations in a face centered cubic lattice. Following this seminal study, we show here that these high entropy oxides (named HEOx hereafter) can be substituted by aliovalent elements with a charge compensation mechanism. This possibility largely increases the potential development of new materials by widening their (already complex) phase space. As a first example, we report here that at least one HEOx composition exhibits colossal dielectric constants, which could make it very promising for applications as large-k dielectric materials. (C) 2016 WILEY-VCH Verlag GmbH &Co. KGaA, Weinheim", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 558, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 328, "End Page": 333, "Article Number": null, "DOI": "10.1002/pssr.201600043", "DOI Link": "http://dx.doi.org/10.1002/pssr.201600043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375111400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Shen, RC; Ma, S; Chen, XB; Xie, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xin; Shen, Rongchen; Ma, Song; Chen, Xiaobo; Xie, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-based heterojunction photocatalysts", "Source Title": "APPLIED SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to their unique physicochemical, optical and electrical properties, 2D semimetallic or semiconducting graphene has been extensively utilized to construct highly efficient heterojunction photocatalysts for driving a variety of redox reactions under proper light irradiation. In this review, we carefully addressed the fundamental mechanism of heterogeneous photocatalysis, fundamental properties and advantages of graphene in photocatalysis, and classification and comparison of graphene-based heterojunction photocatalysts. Subsequently, we thoroughly highlighted and discussed various graphene-based heterojunction photocatalysts, including Schottky junctions, Type-II heterojunctions, Z-scheme heterojunctions, Van der Waals heterostructures, in plane heterojunctions and multicomponent heterojunctions. Several important photocatalytic applications, such as photocatalytic water splitting (H-2 evolution and overall water splitting), degradation of pollutants, carbon dioxide reduction and bacteria disinfection, are also summarized. Through reviewing the important advances on this topic, it may inspire some new ideas for exploiting highly effective graphene-based heterojunction photocatalysts for a number of applications in photocatlysis and other fields, such as photovoltaic, (photo) electrocatalysis, lithium battery, fuel cell, supercapacitor and adsorption separation. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2018, "Volume": 430, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 53, "End Page": 107, "Article Number": null, "DOI": "10.1016/j.apsusc.2017.08.194", "DOI Link": "http://dx.doi.org/10.1016/j.apsusc.2017.08.194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416961500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, T; Shi, SX; Liang, C; Shen, SD; Cheng, L; Wang, C; Song, XJ; Goel, S; Barnhart, TE; Cai, WB; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Teng; Shi, Sixiang; Liang, Chao; Shen, Sida; Cheng, Liang; Wang, Chao; Song, Xuejiao; Goel, Shreya; Barnhart, Todd E.; Cai, Weibo; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron Oxide Decorated MoS2 nullosheets with Double PEGylation for Chelator-Free Radio labeling and Multimodal Imaging Guided Photothermal Therapy", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Theranostics for in vivo cancer diagnosis and treatment generally requires well-designed nulloscale platforms with multiple integrated functionalities. In this study, we uncover that functionalized iron oxide nulloparticles (IONPs) could be self-assembled on the surface of two-dimensional MoS2 nullosheets via sulfur chemistry, forming MoS2-IO nullocomposites, which are then modified with two types of polyethylene glycol (PEG) to acquire enhanced stability in physiological environments. Interestingly, Cu-64, a commonly used positron-emitting radioisotope, could be firmly adsorbed on the surface of MoS2 without the need of chelating molecules, to enable in vivo positron emission tomography (PET) imaging. On the other hand, the strong near-infrared (NIR) and superparamagnetism of MoS2-IO-PEG could also be utilized for photoacoustic tomography (PAT) and magnetic resonullce (MR) imaging, respectively. Under the guidance by such triple-modal imaging, which uncovers efficient tumor retention of MoS2-IO-(d)PEG upon intravenous injection, in vivo photothermal therapy is finally conducted, achieving effective tumor ablation in an animal tumor model. Our study highlights the promise of constructing multifunctional theranostic nullocomposites based on 2D transitional metal dichalcogenides for multimodal imaging-guided cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 950, "End Page": 960, "Article Number": null, "DOI": "10.1021/nn506757x", "DOI Link": "http://dx.doi.org/10.1021/nn506757x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348619000105", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Chen, H; Yang, ZZ; Liang, JY; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tao; Chen, Hao; Yang, Zhenzhen; Liang, Jiyuan; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy perovskite fluorides (HEPFs) have great potential in electrocatalysis that has not been realized because of the limitation of a high-temperature synthetic route and the limited understanding of high-entropy materials. The use of HEPFs in effective oxygen evolution catalysis and a feasible synthesis route for HEPFs in a boiled solution by combining a hydrothermal method with mechanochemistry are first reported here. These HEPFs consisting of cost-effective elements dramatically gave excellent catalytic activity for the oxygen evolution reaction in an alkaline media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2020, "Volume": 142, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4550, "End Page": 4554, "Article Number": null, "DOI": "10.1021/jacs.9b12377", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12377", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526392200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Gao, L; Gao, WR; Ge, CY; Du, X; Li, Z; Yang, Y; Niu, GD; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chao; Gao, Liang; Gao, Wanru; Ge, Cong; Du, Xinyuan; Li, Zha; Yang, Ying; Niu, Guangda; Tang, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Circularly polarized light detection using chiral hybrid perovskite", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Circularly polarized light (CPL) detection is required in various fields such as drug screening, security surveillance and quantum optics. Conventionally, CPL photodetector needs the installation of optical elements, imposing difficulties for integrated and flexible devices. The established CPL detectors without optical elements rely on chiral organic semiconductor and metal metamaterials, but they suffer from extremely low responsivity. Organic-inorganic hybrid materials combine CPL-sensitive absorption induced by chiral organics and efficient charge transport of inorganic frameworks, providing an option for direct CPL detection. Here we report the CPL detector using chiral organic-inorganic hybrid perovskites, and obtain a device with responsivity of 797 mAW(-1), detectivity of 7.1 x 10(11) Jones, 3-dB frequency of 150 Hz and one-month stability, a competitive combined feature for circularly polarized light detection. Thanks to the solution processing, we further demonstrate flexible devices on polyethylene terephthalate substrate with comparable performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1927, "DOI": "10.1038/s41467-019-09942-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09942-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465835500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brent, JR; Savjani, N; Lewis, EA; Haigh, SJ; Lewis, DJ; O'Brien, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brent, Jack R.; Savjani, Nicky; Lewis, Edward A.; Haigh, Sarah J.; Lewis, David J.; O'Brien, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Production of few-layer phosphorene by liquid exfoliation of black phosphorus", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the liquid exfoliation of black phosphorus in N-methyl-2-pyrrolidone to form few-layer phosphorene nullosheets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 679, "Times Cited, All Databases": 741, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2014, "Volume": 50, "Issue": 87, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13338, "End Page": 13341, "Article Number": null, "DOI": "10.1039/c4cc05752j", "DOI Link": "http://dx.doi.org/10.1039/c4cc05752j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343965700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SQ; Xu, XW; Veetil, RM; Valuckas, V; Paniagua-Domínguez, R; Kuznetsov, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shi-Qiang; Xu, Xuewu; Veetil, Rasna Maruthiyodan; Valuckas, Vytautas; Paniagua-Dominguez, Ramon; Kuznetsov, Arseniy I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-only transmissive spatial light modulator based on tunable dielectric metasurface", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapidly developing augmented reality, solid-state light detection and ranging (LIDAR), and holographic display technologies require spatial light modulators (SLMs) with high resolution and viewing angle to satisfy increasing customer demands. Performance of currently available SLMs is limited by their large pixel sizes on the order of several micrometers. Here, we propose a concept of tunable dielectric metasurfaces modulated by liquid crystal, which can provide abrupt phase change, thus enabling pixel-size miniaturization. We present a metasurface-based transmissive SLM, configured to generate active beam steering with >35% efficiency and a large beam deflection angle of 11 degrees. The high resolution and steering angle obtained provide opportunities to develop the next generation of LIDAR and display technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2019, "Volume": 364, "Issue": 6445, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1087, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw6747", "DOI Link": "http://dx.doi.org/10.1126/science.aaw6747", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471306700045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, Y; Kim, S; Kang, JK; Cohen, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Yeob; Kim, Sangjun; Kang, Jeung Ku; Cohen, Seth M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal-organic framework under visible light irradiation", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Postsynthetic exchange (PSE) of Ti(IV) into a Zr(IV)-based MOF enabled photocatalytic CO2 reduction to HCOOH under visible light irradiation with the aid of BNAH and TEOA. Use of a mixed-ligand strategy enhanced the photocatalytic activity of the MOF by introducing new energy levels in the band structure of the MOF.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 51, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5735, "End Page": 5738, "Article Number": null, "DOI": "10.1039/c5cc00686d", "DOI Link": "http://dx.doi.org/10.1039/c5cc00686d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351476300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, HB; Liu, SJ; Lin, WP; Zhang, KY; Lv, W; Huang, X; Huo, FW; Yang, HR; Jenkins, G; Zhao, Q; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Huibin; Liu, Shujuan; Lin, Wenpeng; Zhang, Kenneth Yin; Lv, Wen; Huang, Xiao; Huo, Fengwei; Yang, Huiran; Jenkins, Gareth; Zhao, Qiang; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smart responsive phosphorescent materials for data recording and security protection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Smart luminescent materials that are responsive to external stimuli have received considerable interest. Here we report ionic iridium (III) complexes simultaneously exhibiting mechanochromic, vapochromic and electrochromic phosphorescence. These complexes share the same phosphorescent iridium (III) cation with a N-H moiety in the N boolean AND N ligand and contain different anions, including hexafluorophosphate, tetrafluoroborate, iodide, bromide and chloride. The anionic counterions cause a variation in the emission colours of the complexes from yellow to green by forming hydrogen bonds with the N-H proton. The electronic effect of the N-H moiety is sensitive towards mechanical grinding, solvent vapour and electric field, resulting in mechanochromic, vapochromic and electrochromic phosphorescence. On the basis of these findings, we construct a data-recording device and demonstrate data encryption and decryption via fluorescence lifetime imaging and time-gated luminescence imaging techniques. Our results suggest that rationally designed phosphorescent complexes may be promising candidates for advanced data recording and security protection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 746, "Times Cited, All Databases": 760, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3601, "DOI": "10.1038/ncomms4601", "DOI Link": "http://dx.doi.org/10.1038/ncomms4601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335220700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, EH; Zhu, QH; Huang, JH; Liu, J; Tan, GQ; Sun, CJ; Li, T; Liu, S; Li, YM; Wang, HZ; Wan, XD; Wen, ZH; Fan, FT; Zhang, JT; Ariga, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Erhuan; Zhu, Qianhong; Huang, Junheng; Liu, Jia; Tan, Guoqiang; Sun, Chengjun; Li, Tao; Liu, Shan; Li, Yuemei; Wang, Hongzhi; Wan, Xiaodong; Wen, Zhenhai; Fan, Fengtao; Zhang, Jiatao; Ariga, Katsuhiko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visually resolving the direct Z-scheme heterojunction in CdS@ZnIn2S4 hollow cubes for photocatalytic evolution of H2 and H2O2 from pure water", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The direct Z-scheme heterojunction has been recently emerging as an appealing architecture for photocatalysts design. Its efficiency depends on the interfacial and structural features of the photocatalysts. Herein, the twodimensional ZnIn2S4 nullosheets are grown on the surface of CdS hollow cubes to construct the CdS@ZnIn2S4 hierarchical hollow photocatalysts with chemically bonded interface. The visualized measurements based on spatial-resolved surface photovoltage spectroscopy, combined with other spectroscopic and simulation investigations, clearly disclose that the CdS@ZnIn2S4 hollow cubes constitute a highly efficient direct Z-scheme system. This accounts for the stoichiometric generation of H2 and H2O2 from pure water observed for the CdS@ZnIn2S4 sulfide-only photocatalysts under visible light irradiation with an apparent quantum efficiency of 1.63 % at 400 nm. The present work demonstrates an effective protocol to achieve comprehensive insights into the charge transfer route at semiconductor heterojunction, and offers a viable way for constructing efficient sulfide-only photocatalysts for driving water splitting reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2021, "Volume": 293, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120213, "DOI": "10.1016/j.apcatb.2021.120213", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2021.120213", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663202100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ning, ZY; Li, GC; Melvin, DLR; Chen, Y; Bu, JF; Spencer-Jolly, D; Liu, JL; Hu, BK; Gao, XW; Perera, J; Gong, C; Pu, SDD; Zhang, SM; Liu, BY; Hartley, GO; Bodey, AJ; Todd, RI; Grant, PS; Armstrong, DEJ; Marrow, TJ; Monroe, CW; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ning, Ziyang; Li, Guanchen; Melvin, Dominic L. R.; Chen, Yang; Bu, Junfu; Spencer-Jolly, Dominic; Liu, Junliang; Hu, Bingkun; Gao, Xiangwen; Perera, Johann; Gong, Chen; Pu, Shengda D.; Zhang, Shengming; Liu, Boyang; Hartley, Gareth O.; Bodey, Andrew J.; Todd, Richard I.; Grant, Patrick S.; Armstrong, David E. J.; Marrow, T. James; Monroe, Charles W.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dendrite initiation and propagation in lithium metal solid-state batteries", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state batteries with a Li anode and ceramic electrolyte have the potential to deliver a step change in performance compared with today's Li-ion batteries(1,2). However, Li dendrites (filaments) form on charging at practical rates and penetrate the ceramic electrolyte, leading to short circuit and cell failure(3,4). Previous models of dendrite penetration have generally focused on a single process for dendrite initiation and propagation, with Li driving the crack at its tip(5-9). Here we show that initiation and propagation are separate processes. Initiation arises from Li deposition into subsurface pores, by means of microcracks that connect the pores to the surface. Once filled, further charging builds pressure in the pores owing to the slow extrusion of Li (viscoplastic flow) back to the surface, leading to cracking. By contrast, dendrite propagation occurs by wedge opening, with Li driving the dry crack from the rear, not the tip. Whereas initiation is determined by the local (microscopic) fracture strength at the grain boundaries, the pore size, pore population density and current density, propagation depends on the (macroscopic) fracture toughness of the ceramic, the length of the Li dendrite (filament) that partially occupies the dry crack, current density, stack pressure and the charge capacity accessed during each cycle. Lower stack pressures suppress propagation, markedly extending the number of cycles before short circuit in cells in which dendrites have initiated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2023, "Volume": 618, "Issue": 7964, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 287, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05970-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05970-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004543600025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, P; Ma, ZL; Qiu, H; Ru, YF; Gu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Ping; Ma, Zhonglei; Qiu, Hua; Ru, Yifan; Gu, Junwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Efficiency Electromagnetic Interference Shielding of rGO@FeNi/Epoxy Composites with Regular Honeycomb Structures", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapid development of fifth-generation mobile communication technology and wearable electronic devices, electromagnetic interference and radiation pollution caused by electromagnetic waves have attracted worldwide attention. Therefore, the design and development of highly efficient EMI shielding materials are of great importance. In this work, the three-dimensional graphene oxide (GO) with regular honeycomb structure (GH) is firstly constructed by sacrificial template and freeze-drying methods. Then, the amino functionalized FeNi alloy particles (f-FeNi) are loaded on the GH skeleton followed by in-situ reduction to prepare rGH@FeNi aerogel. Finally, the rGH@FeNi/epoxy EMI shielding composites with regular honeycomb structure is obtained by vacuum-assisted impregnation of epoxy resin. Benefitting from the construction of regular honeycomb structure and electromagnetic synergistic effect, the rGH@ FeNi/epoxy composites with a low rGH@FeNi mass fraction of 2.1 wt% (rGH andf-FeNi are 1.2 and 0.9 wt%, respectively) exhibit a high EMI shielding effectiveness (EMI SE) of 46 dB, which is 5.8 times of that (8 dB) for rGO/FeNi/epoxy composites with the same rGO/FeNi mass fraction. At the same time, the rGH@FeNi/epoxy composites also possess excellent thermal stability (heat-resistance index and temperature at the maximum decomposition rate are 179.1 and 389.0 degrees C respectively) and mechanical properties (storage modulus is 8296.2 MPa).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 51, "DOI": "10.1007/s40820-022-00798-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00798-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748704300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Wu, ZC; You, WB; Yang, LT; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiao; Wu, Zhengchen; You, Wenbin; Yang, Liting; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Assembly MXene-rGO/CoNi Film with Massive Continuous Heterointerfaces and Enhanced Magnetic Coupling for Superior Microwave Absorber", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene, as a rising star of two-dimensional (2D) materials, has been widely applied in fields of microwave absorption and electromagnetic shielding to cope with the arrival of the 5G era. However, challenges arise due to the excessively high permittivity and the difficulty of surface modification of few-layered MXenes severely, which infect the microwave absorption performance. Herein, for the first time, a carefully designed and optimized electrostatic self-assembly strategy to fabricate magnetized MXene-rGO/CoNi film was reported. Inside the synthesized composite film, rGO nullosheets decorated with highly dispersed CoNi nulloparticles are interclacted into MXene layers, which effectively suppresses the originally self-restacked of MXene nullosheets, resulting in a reduction of high permittivity. In addition, owing to the strong magnetic coupling between the magnetic FeCo alloy nulloparticles on the rGO substrate, the entire MXene-rGO/CoNi film exhibits a strong magnetic loss capability. Moreover, the local dielectric polarized fields exist at the continuous hetero-interfaces between 2D MXene and rGO further improve the capacity of microwave loss. Hence, the synthesized composite film exhibits excellent microwave absorption property with a maximum reflection loss value of - 54.1 dB at 13.28 GHz. The electromagnetic synergy strategy is expected to guide future exploration of high-efficiency MXene-based microwave absorption materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 73, "DOI": "10.1007/s40820-022-00811-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00811-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766593800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, W; Chen, JH; Yao, Y; Zheng, D; Ji, XD; Feng, LW; Moore, D; Glavin, NR; Xie, M; Chen, Y; Pankow, RM; Surendran, A; Wang, Z; Xia, Y; Bai, LB; Rivnay, J; Ping, JF; Guo, XG; Cheng, YH; Marks, TJ; Facchetti, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Wei; Chen, Jianhua; Yao, Yao; Zheng, Ding; Ji, Xudong; Feng, Liang-Wen; Moore, David; Glavin, Nicholas R.; Xie, Miao; Chen, Yao; Pankow, Robert M.; Surendran, Abhijith; Wang, Zhi; Xia, Yu; Bai, Libing; Rivnay, Jonathan; Ping, Jianfeng; Guo, Xugang; Cheng, Yuhua; Marks, Tobin J.; Facchetti, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertical organic electrochemical transistors for complementary circuits", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic electrochemical transistors (OECTs) and OECT-based circuitry offer great potential in bioelectronics, wearable electronics and artificial neuromorphic electronics because of their exceptionally low driving voltages (< 1 V), low power consumption (< 1 mu W), high transconductances (> 10 mS) and biocompatibility(1-5). However, the successful realization of critical complementary logic OECTs is currently limited by temporal and/or operational instability, slow redox processes and/or switching, incompatibility with high-density monolithic integration and inferior n-type OECT performance(6-8). Here we demonstrate p- and n-type vertical OECTs with balanced and ultra-high performance by blending redox-active semiconducting polymers with a redox-inactive photocurable and/or photopatternable polymer to form an ion-permeable semiconducting channel, implemented in a simple, scalable vertical architecture that has a dense, impermeable top contact. Footprint current densities exceeding 1 kA cm(-2) at less than +/- 0.7 V, transconductances of 0.2-0.4 S, short transient times of less than 1 ms and ultra-stable switching (> 50,000 cycles) are achieved in, to our knowledge, the first vertically stacked complementary vertical OECT logic circuits. This architecture opens many possibilities for fundamental studies of organic semiconductor redox chemistry and physics in nulloscopically confined spaces, without macroscopic electrolyte contact, as well as wearable and implantable device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 613, "Issue": 7944, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 496, "End Page": 502, "Article Number": null, "DOI": "10.1038/s41586-022-05592-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05592-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922739000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, HL; Cai, SC; Xie, SL; Wang, ZB; Tong, YX; Pan, M; Lu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Haolin; Cai, Shichang; Xie, Shilei; Wang, Zhengbang; Tong, Yexiang; Pan, Mu; Lu, Xihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic-Framework-Derived Dual Metal- and Nitrogen-Doped Carbon as Efficient and Robust Oxygen Reduction Reaction Catalysts for Microbial Fuel Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500265, "DOI": "10.1002/advs.201500265", "DOI Link": "http://dx.doi.org/10.1002/advs.201500265", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370336500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giannozzi, P; Andreussi, O; Brumme, T; Bunau, O; Nardelli, MB; Calandra, M; Car, R; Cavazzoni, C; Ceresoli, D; Cococcioni, M; Colonna, N; Carnimeo, I; Dal Corso, A; de Gironcoli, S; Delugas, P; DiStasio, RA; Ferretti, A; Floris, A; Fratesi, G; Fugallo, G; Gebauer, R; Gerstmann, U; Giustino, F; Gorni, T; Jia, J; Kawamura, M; Ko, HY; Kokalj, A; Küçükbenli, E; Lazzeri, M; Marsili, M; Marzari, N; Mauri, F; Nguyen, NL; Nguyen, HV; Otero-de-la-Roza, A; Paulatto, L; Poncé, S; Rocca, D; Sabatini, R; Santra, B; Schlipf, M; Seitsonen, AP; Smogunov, A; Timrov, I; Thonhauser, T; Umari, P; Vast, N; Wu, X; Baroni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giannozzi, P.; Andreussi, O.; Brumme, T.; Bunau, O.; Nardelli, M. Buongiorno; Calandra, M.; Car, R.; Cavazzoni, C.; Ceresoli, D.; Cococcioni, M.; Colonna, N.; Carnimeo, I.; Dal Corso, A.; de Gironcoli, S.; Delugas, P.; DiStasio, R. A., Jr.; Ferretti, A.; Floris, A.; Fratesi, G.; Fugallo, G.; Gebauer, R.; Gerstmann, U.; Giustino, F.; Gorni, T.; Jia, J.; Kawamura, M.; Ko, H-Y; Kokalj, A.; Kucukbenli, E.; Lazzeri, M.; Marsili, M.; Marzari, N.; Mauri, F.; Nguyen, N. L.; Nguyen, H-V; Otero-de-la-Roza, A.; Paulatto, L.; Ponce, S.; Rocca, D.; Sabatini, R.; Santra, B.; Schlipf, M.; Seitsonen, A. P.; Smogunov, A.; Timrov, I.; Thonhauser, T.; Umari, P.; Vast, N.; Wu, X.; Baroni, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced capabilities for materials modelling with QUANTUM ESPRESSO", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "QUANTUM ESPRESSO is an integrated suite of open-source computer codes for quantum simulations of materials using state-of-the-art electronic-structure techniques, based on density-functional theory, density-functional perturbation theory, and many-body perturbation theory, within the plane-wave pseudopotential and projector-augmented-wave approaches. QUANTUM ESPRESSO owes its popularity to the wide variety of properties and processes it allows to simulate, to its performance on an increasingly broad array of hardware architectures, and to a community of researchers that rely on its capabilities as a core open-source development platform to implement their ideas. In this paper we describe recent extensions and improvements, covering new methodologies and property calculators, improved parallelization, code modularization, and extended interoperability both within the distribution and with external software.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 6474, "Times Cited, All Databases": 6784, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2017, "Volume": 29, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 465901, "DOI": "10.1088/1361-648X/aa8f79", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/aa8f79", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413705400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, LH; Lin, SH; Li, ZJ; Zhang, ZX; Zhang, TF; Xie, C; Mak, CH; Chai, Y; Lau, SP; Luo, LB; Tsang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Long-Hui; Lin, Sheng-Huang; Li, Zhong-Jun; Zhang, Zhi-Xiang; Zhang, Teng-Fei; Xie, Chao; Mak, Chun-Hin; Chai, Yang; Lau, Shu Ping; Luo, Lin-Bao; Tsang, Yuen Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast, Self-Driven, Air-Stable, and Broadband Photodetector Based on Vertically Aligned PtSe2/GaAs Heterojunction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Group-10 layered transitional metal dichalcogenides including PtS2, PtSe2, and PtTe2 are excellent potential candidates for optoelectronic devices due to their unique properties such as high carrier mobility, tunable bandgap, stability, and flexibility. Large-area platinum diselenide (PtSe2) with semiconducting characteristics is far scarcely investigated. Here, the development of a high-performance photodetector based on vertically aligned PtSe2-GaAs heterojunction which exhibits a broadband sensitivity from deep ultraviolet to near-infrared light, with peak sensitivity from 650 to 810 nm, is reported. The I-light/I-dark ratio and responsivity of photodetector are 3 x 10(4) and 262 mA W-1 measured at 808 nm under zero bias voltage. The response speed of tau(r)/tau(f) is 5.5/6.5 mu s, which represents the best result achieved for Group-10 TMDs based optoelectronic device thus far. According to first-principle density functional theory, the broad photoresponse ranging from visible to near-infrared region is associated with the semiconducting characteristics of PtSe2 which has interstitial Se atoms within the PtSe2 layers. It is also revealed that the PtSe2/GaAs photodetector does not exhibit performance degradation after six weeks in air. The generality of the above good results suggests that the vertically aligned PtSe2 is an ideal material for high-performance optoelectronic systems in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 475, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 28, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705970, "DOI": "10.1002/adfm.201705970", "DOI Link": "http://dx.doi.org/10.1002/adfm.201705970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430163700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, YX; He, YR; Jin, Y; Ding, F; Yang, L; Ye, YQ; Zhong, SM; Lin, YY; He, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Yanxia; He, Yingran; Jin, Yi; Ding, Fei; Yang, Liu; Ye, Yuqian; Zhong, Shoumin; Lin, Yinyue; He, Sailing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic and metamaterial structures as electromagnetic absorbers", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic absorbers have drawn increasing attention in many areas. A series of plasmonic and metamaterial structures can work as efficient narrowband absorbers due to the excitation of plasmonic or photonic resonullces, providing a great potential for applications in designing selective thermal emitters, biosensing, etc. In other applications such as solar-energy harvesting and photonic detection, the bandwidth of light absorbers is required to be quite broad. Under such a background, a variety of mechanisms of broadband/multiband absorption have been proposed, such as mixing multiple resonullces together, exciting phase resonullces, slowing down light by anisotropic metamaterials, employing high loss materials and so on.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 495, "End Page": 520, "Article Number": null, "DOI": "10.1002/lpor.201400026", "DOI Link": "http://dx.doi.org/10.1002/lpor.201400026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339068800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, MK; Li, YL; Liu, QL; Xue, ZA; Wang, HP; Fan, YN; Zhu, KL; Ke, ZF; Su, CY; Li, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Mengke; Li, Yinle; Liu, Qinglin; Xue, Zigian; Wang, Haiping; Fan, Yanull; Zhu, Kelong; Ke, Zhuofeng; Su, Cheng-Yong; Li, Guangqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Step Construction of Hydrophobic MOFs@COFs Core-Shell Composites for Heterogeneous Selective Catalysis", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of novel porous core-shell materials is of great significance because of their prospectively improved performance and extensive applications in separation, energy conversion, and catalysis. Here, mesoporous metal-organic frameworks (MOFs) NH2-MIL-101(Fe) as a core generate a shell with mesoporous covalent organic frameworks (COFs) NUT-COF-1(NTU) by a covalent linking process, the composite NH2-MIL-101(Fe)@NTU keeping retentive crystallinity with hierarchical porosity well. Importantly, the NH2-MIL-101(Fe)@NTU composite shows significantly enhanced catalytic conversion and selectivity during styrene oxidation. It is mainly due to the hydrophilic MOF nullocrystals readily gathering the hydrophobic reactants styrene and boosting the radical mechanism path after combining the hydrophobic COFs shell. The synthetic strategy in this systematic study develops a new rational design for the synthesis of other core-shell MOF/COF-based hybrid materials, which can expand the promising applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802365, "DOI": "10.1002/advs.201802365", "DOI Link": "http://dx.doi.org/10.1002/advs.201802365", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464827300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, P; Tanaka, S; Ito, S; Tetreault, N; Manabe, K; Nishino, H; Nazeeruddin, MK; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Peng; Tanaka, Soichiro; Ito, Seigo; Tetreault, Nicolas; Manabe, Kyohei; Nishino, Hitoshi; Nazeeruddin, Mohammad Khaja; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organo-lead halide perovskites have attracted much attention for solar cell applications due to their unique optical and electrical properties. With either low-temperature solution processing or vacuum evaporation, the overall conversion efficiencies of perovskite solar cells with organic hole-transporting material were quickly improved to over 15% during the last 2 years. However, the organic hole-transporting materials used are normally quite expensive due to complicated synthetic procedure or high-purity requirement. Here, we demonstrate the application of an effective and cheap inorganic p-type hole-transporting material, copper thiocyanate, on lead halide perovskite-based devices. With low-temperature solution-process deposition method, a power conversion efficiency of 12.4% was achieved under full sun illumination. This work represents a well-defined cell configuration with optimized perovskite morphology by two times of lead iodide deposition, and opens the door for integration of a class of abundant and inexpensive material for photovoltaic application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 831, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3834, "DOI": "10.1038/ncomms4834", "DOI Link": "http://dx.doi.org/10.1038/ncomms4834", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337373200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Sheng S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Problems and their origins of Ni-rich layered oxide cathode materials", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-rich layered oxides, LiNixCoyMnzO2 (NCM) and LiNixCoyAlzO2 (NCA) with x + y + z = 1 and x >= 0.8, are regarded to be the best choice for the cathode material of high energy Li-ion batteries due to their combined advantages in capacity, working potential and manufacture cost. However, their application in practical Li-ion batteries is hindered by two essential problems of (1) performance degradation and (2) safety hazard over the whole life of battery. Performance degradation behaves as declines in battery's capacity and working voltage as well as the battery's swelling and impedance growth; Safety hazard arises from thermal runaway under abuse conditions such as overcharging, overheating, and electric shorting. It appears that nearly all problems can be ultimately attributed to the loss of oxygen, especially caused by the oxidation of lattice oxygen in H3 phase where the capacities are contributed by both of the Ni and O redox couples. In this review, the problems and their origins of Ni-rich layered oxides are overviewed, and the solutions attempted to mitigate these problems are outlined.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 583, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 24, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 247, "End Page": 254, "Article Number": null, "DOI": "10.1016/j.ensm.2019.08.013", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2019.08.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500484000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Guler, U; Kinsey, N; Naik, GV; Boltasseva, A; Guan, JG; Shalaev, VM; Kildishev, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Guler, Urcan; Kinsey, Nathaniel; Naik, Gururaj V.; Boltasseva, Alexandra; Guan, Jianguo; Shalaev, Vladimir M.; Kildishev, Alexander V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Refractory Plasmonics with Titanium Nitride: Broadband Metamaterial Absorber", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-temperature stable broadband plasmonic absorber is designed, fabricated, and optically characterized. A broadband absorber with an average high absorption of 95% and a total thickness of 240 nm is fabricated, using a refractory plasmonic material, titanium nitride. This absorber integrates both the plasmonic resonullces and the dielectric-like loss. It opens a path for the interesting applications such as solar thermophotovoltaics and optical circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 676, "Times Cited, All Databases": 729, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2014, "Volume": 26, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7959, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201401874", "DOI Link": "http://dx.doi.org/10.1002/adma.201401874", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346263100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, YT; Xu, MZ; He, T; Chen, BJ; Gu, F; Zu, LH; Meng, RJ; Yang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Yutong; Xu, Mengzhu; He, Ting; Chen, Bingjie; Gu, Feng; Zu, Lianhai; Meng, Ruijin; Yang, Jinhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CoPSe: A New Ternary Anode Material for Stable and High-Rate Sodium/Potassium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of ideal electrode materials overcoming the critical problems of large electrode volume changes and sluggish redox kinetics induced by large ionic radius of Na+/K+ ions is highly desirable for sodium/potassium-ion batteries (SIBs/PIBs) toward large-scale applications. The present work demonstrates that single-phase ternary cobalt phosphoselenide (CoPSe) in the form of nulloparticles embedded in a layered metal-organic framework (MOF)-derived N-doped carbon matrix (CoPSe/NC) represents an ultrastable and high-rate anode material for SIBs/PIBs. The CoPSe/NC is fabricated by using the MOF as both a template and precursor, coupled with in situ synchronous phosphorization/selenization reactions. The CoPSe anode holds a set of intrinsic merits such as lower mechanical stress, enhanced reaction kinetics, as well as higher theoretical capacity and lower discharge voltage relative to its counterpart of CoSe2, and suppressed shuttle effect with higher intrinsic electrical conductivity relative to CoPS. The involved mechanisms are evidenced by substantial characterizations and density functional theory (DFT) calculations. Consequently, the CoPSe/NC anode shows an outstanding long-cycle stability and rate performance for SIBs and PIBs. Moreover, the CoPSe/NC-based Na-ion full cell can achieve a higher energy density of 274 Wh kg(-1), surpassing that based on CoSe2/NC and most state-of-the-art Na-ion full cells based on P-, Se-, or S-containing binary/ternary anodes to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 33, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007262, "DOI": "10.1002/adma.202007262", "DOI Link": "http://dx.doi.org/10.1002/adma.202007262", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626949500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jie, XY; Li, WS; Slocombe, D; Gao, YG; Banerjee, I; Gonzalez-Cortes, S; Yao, BZ; AlMegren, H; Alshihri, S; Dilworth, J; Thomas, J; Xiao, TC; Edwards, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jie, Xiangyu; Li, Weisong; Slocombe, Daniel; Gao, Yige; Banerjee, Ira; Gonzalez-Cortes, Sergio; Yao, Benzhen; AlMegren, Hamid; Alshihri, Saeed; Dilworth, Jonathan; Thomas, John; Xiao, Tiancun; Edwards, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microwave-initiated catalytic deconstruction of plastic waste into hydrogen and high-value carbons", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ubiquitous challenge of plastic waste has led to the modern descriptor plastisphere to represent the human-made plastic environment and ecosystem. Here we report a straightforward rapid method for the catalytic deconstruction of various plastic feedstocks into hydrogen and high-value carbons. We use microwaves together with abundant and inexpensive iron-based catalysts as microwave susceptors to initiate the catalytic deconstruction process. The one-step process typically takes 30-90 s to transform a sample of mechanically pulverized commercial plastic into hydrogen and (predominulltly) multiwalled carbon nullotubes. A high hydrogen yield of 55.6 mmol g(plastic)(-1) is achieved, with over 97% of the theoretical mass of hydrogen being extracted from the deconstructed plastic. The approach is demonstrated on widely used, real-world plastic waste. This proof-of-concept advance highlights the potential of plastic waste itself as a valuable energy feedstock for the production of hydrogen and high-value carbon materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 902, "End Page": 912, "Article Number": null, "DOI": "10.1038/s41929-020-00518-5", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00518-5", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577033300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZJ; Sheng, HW; Wang, ZJ; Gludovatz, B; Zhang, Z; George, EP; Yu, Q; Mao, SX; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zijiao; Sheng, Hongwei; Wang, Zhangjie; Gludovatz, Bernd; Zhang, Ze; George, Easo P.; Yu, Qian; Mao, Scott X.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dislocation mechanisms and 3D twin architectures generate exceptional strength-ductility-toughness combination in CrCoNi medium-entropy alloy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combinations of high strength and ductility are hard to attain in metals. Exceptions include materials exhibiting twinning-induced plasticity. To understand how the strength-ductility trade-off can be defeated, we apply in situ, and aberration-corrected scanning, transmission electron microscopy to examine deformation mechanisms in the medium-entropy alloy CrCoNi that exhibits one of the highest combinations of strength, ductility and toughness on record. Ab initio modelling suggests that it has negative stacking-fault energy at 0K and high propensity for twinning. With deformation we find that a three-dimensional (3D) hierarchical twin network forms from the activation of three twinning systems. This serves a dual function: conventional twin-boundary (TB) strengthening from blockage of dislocations impinging on TBs, coupled with the 3D twin network which offers pathways for dislocation glide along, and cross-slip between, intersecting TB-matrix interfaces. The stable twin architecture is not disrupted by interfacial dislocation glide, serving as a continuous source of strength, ductility and toughness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 625, "Times Cited, All Databases": 670, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14390, "DOI": "10.1038/ncomms14390", "DOI Link": "http://dx.doi.org/10.1038/ncomms14390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394455900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ai, XZ; Ho, CJH; Aw, J; Attia, ABE; Mu, J; Wang, Y; Wang, XY; Wang, Y; Liu, XG; Chen, HB; Gao, MY; Chen, XY; Yeow, EKL; Liu, G; Olivo, M; Xing, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ai, Xiangzhao; Ho, Chris Jun Hui; Aw, Junxin; Attia, Amalina Binte Ebrahim; Mu, Jing; Wang, Yu; Wang, Xiaoyong; Wang, Yong; Liu, Xiaogang; Chen, Huabing; Gao, Mingyuan; Chen, Xiaoyuan; Yeow, Edwin K. L.; Liu, Gang; Olivo, Malini; Xing, Bengang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In vivo covalent cross-linking of photon-converted rare-earth nullostructures for tumour localization and theranostics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of precision nullomedicines to direct nullostructure-based reagents into tumour-targeted areas remains a critical challenge in clinics. Chemical reaction-mediated localization in response to tumour environmental perturbations offers promising opportunities for rational design of effective nullo-theranostics. Here, we present a unique microenvironment-sensitive strategy for localization of peptide-premodified upconversion nullocrystals (UCNs) within tumour areas. Upon tumour-specific cathepsin protease reactions, the cleavage of peptides induces covalent cross-linking between the exposed cysteine and 2-cyanobenzothiazole on neighbouring particles, thus triggering the accumulation of UCNs into tumour site. Such enzyme-triggered cross-linking of UCNs leads to enhanced upconversion emission upon 808 nm laser irradiation, and in turn amplifies the singlet oxygen generation from the photosensitizers attached on UCNs. Importantly, this design enables remarkable tumour inhibition through either intratumoral UCNs injection or intravenous injection of nulloparticles modified with the targeting ligand. Our strategy may provide a multimodality solution for effective molecular sensing and site-specific tumour treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10432, "DOI": "10.1038/ncomms10432", "DOI Link": "http://dx.doi.org/10.1038/ncomms10432", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369022600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, QX; Tang, XL; Huang, B; Hu, T; Tan, LC; Chen, L; Chen, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Qingxia; Tang, Xianglan; Huang, Bin; Hu, Ting; Tan, Licheng; Chen, Lie; Chen, Yiwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Progress on the Long-Term Stability of Perovskite Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As rapid progress has been achieved in emerging thin film solar cell technology, organic-inorganic hybrid perovskite solar cells (PVSCs) have aroused many concerns with several desired properties for photovoltaic applications, including large absorption coefficients, excellent carrier mobility, long charge carrier diffusion lengths, low-cost, and unbelievable progress. Power conversion efficiencies increased from 3.8% in 2009 up to the current world record of 22.1%. However, poor long-term stability of PVSCs limits the future commercial application. Here, the degradation mechanisms for unstable perovskite materials and their corresponding solar cells are discussed. The strategies for enhancing the stability of perovskite materials and PVSCs are also summarized. This review is expected to provide helpful insights for further enhancing the stability of perovskite materials and PVSCs in this exciting field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700387, "DOI": "10.1002/advs.201700387", "DOI Link": "http://dx.doi.org/10.1002/advs.201700387", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435852800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Vara, M; Luo, M; Huang, HW; Ruditskiy, A; Park, J; Bao, SX; Liu, JY; Howe, J; Chi, MF; Xie, ZX; Xia, YN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xue; Vara, Madeline; Luo, Ming; Huang, Hongwen; Ruditskiy, Aleksey; Park, Jinho; Bao, Shixiong; Liu, Jingyue; Howe, Jane; Chi, Miaofang; Xie, Zhaoxiong; Xia, Younull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pd@Pt Core-Shell Concave Decahedra: A Class of Catalysts for the Oxygen Reduction Reaction with Enhanced Activity and Durability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a facile synthesis of multiply twinned Pd@Pt core shell concave decahedra by controlling the deposition of Pt on preformed Pd decahedral seeds. The Pt atoms are initially deposited on the vertices of a decahedral seed, followed by surface diffusion to other regions along the edges/ridges and then across the faces. Different from the coating of a Pd icosahedral seed, the Pt atoms prefer to stay at the vertices and edges/ridges of a decahedral seed even when the deposition is conducted at 200 degrees C, naturally generating a core shell structure covered by concave facets. The nonuniformity in the Pt coating can be attributed to the presence of twin boundaries at the vertices, as well as the {100} facets and twin defects along the edges/ridges of a decahedron, effectively trapping the Pt adatoms at these high-energy sites. As compared to a commercial Pt/C catalyst, the Pd@Pt concave decahedra show substantial enhancement in both catalytic activity and durability toward the oxygen reduction reaction (ORR). For the concave decahedra with 29.6% Pt by weight, their specific (1.66 mA/cm(pt)(2)) and mass (1.60 A/mg/0 ORR activities are enhanced by 4.4 and 6.6 times relative to those of the Pt/C catalyst (0.36 mA/cm(pt)(2) and 0.32 A/mgpt, respectively). After 10 000 cycles of accelerated durability test, the concave decahedra still exhibit a mass activity of 0.69 A/mgpt, more than twice that of the pristine Pt/C catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2015, "Volume": 137, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15036, "End Page": 15042, "Article Number": null, "DOI": "10.1021/jacs.5b10059", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b10059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365930600029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kongkanulld, A; Mathias, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kongkanulld, Anusorn; Mathias, Mark F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Priority and Challenge of High-Power Performance of Low-Platinum Proton-Exchange Membrane Fuel Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Substantial progress has been made in reducing proton-exchange membrane fuel cell (PEMFC) cathode platinum loadings from 0.4-0.8 mg(Pt)/cm(2) to about 0.1 mg(Pt)/cm(2). However, at this level of cathode Pt loading, large performance loss is observed at high-current density (>1 A/cm(2)), preventing a reduction in the overall stack cost. This next developmental step is being limited by the presence of a resistance term exhibited at these lower Pt loadings and apparently due to a phenomenon at or near the catalyst surface. This issue can be addressed through the design of catalysts with high and stable Pt dispersion as well as through development and implementation of ionomers designed to interact with Pt in a way that does not constrain oxygen reduction reaction rates. Extrapolating from progress made in past decades, we are optimistic that the concerted efforts of materials and electrode designers can resolve this issue, thus enabling a large step toward fuel cell vehicles that are affordable for the mass market.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 973, "Times Cited, All Databases": 1066, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2016, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1127, "End Page": 1137, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b00216", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b00216", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373867600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yong, TY; Zhang, XQ; Bie, NN; Zhang, HB; Zhang, XT; Li, FY; Hakeem, A; Hu, J; Gan, L; Santos, HA; Yang, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yong, Tuying; Zhang, Xiaoqiong; Bie, nulla; Zhang, Hongbo; Zhang, Xuting; Li, Fuying; Hakeem, Abdul; Hu, Jun; Gan, Lu; Santos, Helder A.; Yang, Xiangliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tumor exosome-based nulloparticles are efficient drug carriers for chemotherapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing biomimetic nulloparticles without loss of the integrity of proteins remains a major challenge in cancer chemotherapy. Here, we develop a biocompatible tumor-cell-exocytosed exosome-biomimetic porous silicon nulloparticles (PSiNPs) as drug carrier for targeted cancer chemotherapy. Exosome-sheathed doxorubicin-loaded PSiNPs (DOX@E-PSiNPs), generated by exocytosis of the endocytosed DOX-loaded PSiNPs from tumor cells, exhibit enhanced tumor accumulation, extravasation from blood vessels and penetration into deep tumor parenchyma following intravenous administration. In addition, DOX@E-PSiNPs, regardless of their origin, possess significant cellular uptake and cytotoxicity in both bulk cancer cells and cancer stem cells (CSCs). These properties endow DOX@E-PSiNPs with great in vivo enrichment in total tumor cells and side population cells with features of CSCs, resulting in anticancer activity and CSCs reduction in subcutaneous, orthotopic and metastatic tumor models. These results provide a proof-of-concept for the use of exosome-biomimetic nulloparticles exocytosed from tumor cells as a promising drug carrier for efficient cancer chemotherapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 609, "Times Cited, All Databases": 636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3838, "DOI": "10.1038/s41467-019-11718-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11718-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482398900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, EP; Wu, D; Jia, C; Wang, YG; Yuan, HY; Zeng, LH; Xu, TT; Shi, ZF; Tian, YT; Li, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Enping; Wu, Di; Jia, Cheng; Wang, Yuange; Yuan, Huiyu; Zeng, Longhui; Xu, Tingting; Shi, Zhifeng; Tian, Yongtao; Li, Xinjian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Fabrication of 2D WS2/Si Type-II Heterojunction for Self-Powered Broadband Photodetector with Response up to Mid-Infrared", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high-performance broadband photodetectors have attracted intensive scientific interests due to their potential applications in optoelectronic systems. Despite great achievements in two-dimensional (2D) materials based photodetectors such as graphene and black phosphorus, obvious disadvantages such as low optical absorbance and instability preclude their usage for the broadband photodetectors with the desired performance. An alternative approach is to find promising 2D materials and fabricate heterojunction structures for multifunctional hybrid photo detectors. In this work, 2D WS2/Si heterojunction with a type-II band alignment is formed in situ. This heterojunction device produced a high I-on/I-off ratio over 10,(6) responsivity of 224 mA/W, specific detectivity of 1.5 x 10(12) Jones, high polarization sensitivity, and broadband response up to 3043 nm. Furthermore, a 4 x 4 device array of WS2/Si heterojunction device is demonstrated with high stability and reproducibility. These results suggest that the WS2/Si type-II heterojunction is an ideal photodetector in broadband detection and integrated optoelectronic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 565, "End Page": "+", "Article Number": null, "DOI": "10.1021/acsphotonics.8b01675", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.8b01675", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459642800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, BW; Xiang, Z; Xiong, J; Liu, ZC; Yu, LZ; Lu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Baiwen; Xiang, Zhen; Xiong, Juan; Liu, Zhicheng; Yu, Lunzhou; Lu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sandwich-Like Fe&TiO2@C nullocomposites Derived from MXene/Fe-MOFs Hybrids for Electromagnetic Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic pollution has been causing a series of problems in people's life, and electromagnetic absorbers with lightweight and broad absorbing bandwidth properties are widely desired. In this work, novel sandwich-like 2D laminated Fe&TiO2 nulloparticles@C nullocomposites were rationally designed and successfully developed from the MXene-MOFs hybrids. The formation of Fe and rutile-TiO2 nulloparticles sandwiched by the two-dimensional carbon nullosheets provided strong electromagnetic energy attenuation and good impedance matching for electromagnetic wave (EMW) absorption. As expected, the nullocomposites achieved a broad effective absorption bandwidth of 6.5 GHz at a thickness of only 1.6 mm and the minimum reflection loss (RL) value of - 51.8 dB at 6.6 GHz with a thickness of 3 mm. This work not only provides a good design and fabricating concept for the laminated metal and functional nulloparticles@C nullocomposites with good EMW absorption, but also offers an important guideline to fabricate various two-dimensional nullocomposites derived from the MXene precursors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2020, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 55, "DOI": "10.1007/s40820-020-0398-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-0398-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519268900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZX; Yang, PF; Li, QC; Xiao, WP; Li, ZJ; Xu, GR; Liu, FS; Jia, BH; Ma, TY; Feng, SH; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zexing; Yang, Pengfei; Li, Qichang; Xiao, Weiping; Li, Zhenjiang; Xu, Guangrui; Liu, Fusheng; Jia, Baohua; Ma, Tianyi; Feng, Shouhua; Wang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microwave Synthesis of Pt Clusters on Black TiO2 with Abundant Oxygen Vacancies for Efficient Acidic Electrocatalytic Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen vacancies-enriched black TiO2 is one promising support for enhancing hydrogen evolution reaction (HER). Herein, oxygen vacancies enriched black TiO2 supported sub-nullometer Pt clusters (Pt/TiO2-OV) with metal support interactions is designed through solvent-free microwave and following low-temperature electroless approach for the first time. High-temperature and strong reductants are not required and then can avoid the aggregation of decorated Pt species. Experimental and theoretical calculation verify that the created oxygen vacancies and Pt clusters exhibit synergistic effects for optimizing the reaction kinetics. Based on it, Pt/TiO2-OV presents remarkable electrocatalytic performance with 18 mV to achieve 10 mAcm(-2) coupled with small Tafel slope of 12 mVdec(-1). This work provides quick synthetic strategy for preparing black titanium dioxide based nullomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2023, "Volume": 62, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202300406", "DOI": "10.1002/anie.202300406", "DOI Link": "http://dx.doi.org/10.1002/anie.202300406", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936769900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, ZY; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Zhouyue; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A supramolecular biomimetic skin combining a wide spectrum of mechanical properties and multiple sensory capabilities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimetic skin-like materials, capable of adapting shapes to variable environments and sensing external stimuli, are of great significance in a wide range of applications, including artificial intelligence, soft robotics, and smart wearable devices. However, such highly sophisticated intelligence has been mainly found in natural creatures while rarely realized in artificial materials. Herein, we fabricate a type of biomimetic iontronics to imitate natural skins using supramolecular polyelectrolyte hydrogels. The dynamic viscoelastic networks provide the biomimetic skin with a wide spectrum of mechanical properties, including flexible reconfiguration ability, robust elasticity, extremely large stretchability, autonomous self-healability, and recyclability. Meanwhile, polyelectrolytes' ionic conductivity allows multiple sensory capabilities toward temperature, strain, and stress. This work provides not only insights into dynamic interactions and sensing mechanism of supramolecular iontronics, but may also promote the development of biomimetic skins with sophisticated intelligence similar to natural skins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1134, "DOI": "10.1038/s41467-018-03456-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03456-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427698700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kulbak, M; Gupta, S; Kedem, N; Levine, I; Bendikov, T; Hodes, G; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kulbak, Michael; Gupta, Satyajit; Kedem, Nir; Levine, Igal; Bendikov, Tatyana; Hodes, Gary; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct comparison between perovskite-structured hybrid organic inorganic methylammonium lead bromide (MAPbBr(3)) and all-inorganic cesium lead bromide (CsPbBr3), allows identifying possible fundamental differences in their structural, thermal and electronic characteristics. Both materials possess a similar direct optical band gap, but CsPbBr3 demonstrates a higher thermal stability than MAPbBr(3). In order to compare device properties, we fabricated solar cells, with similarly synthesized MAPbBr(3) or CsPbBr3, over mesoporous titania scaffolds. Both cell types demonstrated comparable photovoltaic performances under AM1.5 illumination, reaching power conversion efficiencies of similar to 6% with a poly aryl amine-based derivative as hole transport material. Further analysis shows that Cs-based devices are as efficient as, and more stable than methylammonium-based ones, after aging (storing the cells for 2 weeks in a dry (relative humidity 15-20%) air atmosphere in the dark) for 2 weeks, under constant illumination (at maximum power), and under electron beam irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 879, "Times Cited, All Databases": 936, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2016, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 167, "End Page": 172, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b02597", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b02597", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367968700029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Z; Kim, D; Hong, DC; Yu, Y; Xu, J; Lin, S; Wen, XD; Nichols, EM; Jeong, K; Reimer, JA; Yang, PD; Chang, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Zhi; Kim, Dohyung; Hong, Dachao; Yu, Yi; Xu, Jun; Lin, Song; Wen, Xiaodong; Nichols, Eva M.; Jeong, Keunhong; Reimer, Jeffrey A.; Yang, Peidong; Chang, Christopher J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Molecular Surface Functionalization Approach to Tuning nulloparticle Electrocatalysts for Carbon Dioxide Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conversion of the greenhouse gas carbon dioxide (CO2) to value-added products is an important challenge for sustainable energy research, and nullomaterials offer a broad class of heterogeneous catalysts for such transformations. Here we report a molecular surface functionalization approach to tuning gold nulloparticle (Au NP) electrocatalysts for reduction of CO2 to CO. The N-heterocyclic (NHC) carbene-functionalized Au NP catalyst exhibits improved faradaic efficiency (FE = 83%) for reduction of CO2 to CO in water at neutral pH at an overpotential of 0.46 V with a 7.6-fold increase in current density compared to that of the parent Au NP (FE = 53%). Tafel plots of the NHC carbene-functionalized Au NP (72 mV/decade) vs parent Au NP (138 mV/decade) systems further show that the molecular ligand influences mechanistic pathways for CO2 reduction. The results establish molecular surface functionalization as a complementary approach to size, shape, composition, and defect control for nulloparticle catalyst design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2016, "Volume": 138, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8120, "End Page": 8125, "Article Number": null, "DOI": "10.1021/jacs.6b02878", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b02878", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379455600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathis, TS; Maleski, K; Goad, A; Sarycheva, A; Anayee, M; Foucher, AC; Hantanasirisakul, K; Shuck, CE; Stach, EA; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathis, Tyler S.; Maleski, Kathleen; Goad, Adam; Sarycheva, Asia; Anayee, Mark; Foucher, Alexandre C.; Hantanasirisakul, Kanit; Shuck, Christopher E.; Stach, Eric A.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti3C2 MXene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the primary factors limiting further research and commercial use of the two-dimensional (2D) titanium carbide MXene Ti3C2, as well as MXenes in general, is the rate at which freshly made samples oxidize and degrade when stored as aqueous suspensions. Here, we show that including excess aluminum during synthesis of the Ti3AlC2 MAX phase precursor leads to Ti3AlC2 grains with improved crystallinity and carbon stoichiometry (termed Al-Ti3AlC2). MXene nullosheets (Al-Ti3C2) produced from this precursor are of higher quality, as evidenced by their increased resistance to oxidation and an increase in their electronic conductivity up to 20 000 S/cm. Aqueous suspensions of stoichiometric single-to few-layer Al-Ti3C2 flakes produced from the modified Al-Ti3AlC2 have a shelf life of over ten months, compared to 1 to 2 weeks for previously published Ti3C2, even when stored in ambient conditions. Freestanding films made from Al-Ti3C2 suspensions stored for ten months show minimal decreases in electrical conductivity and negligible oxidation. Furthermore, oxidation of the improved Al-Ti3C2 in air initiates at temperatures that are 100-150 degrees C higher than that of conventional Ti3C2. The observed improvements in both the shelf life and properties of Al-Ti3C2 will facilitate the widespread use of this material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 624, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2021, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6420, "End Page": 6429, "Article Number": null, "DOI": "10.1021/acsnullo.0c08357", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c08357", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645436800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, ZM; Xiao, X; Jin, HY; Li, TQ; Chen, M; Liang, Z; Guo, ZF; Li, J; Wan, J; Huang, L; Zhang, YR; Feng, G; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zhimi; Xiao, Xu; Jin, Huanyu; Li, Tianqi; Chen, Ming; Liang, Zhun; Guo, Zhengfeng; Li, Jia; Wan, Jun; Huang, Liang; Zhang, Yanrong; Feng, Guang; Zhou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid mass production of two-dimensional metal oxides and hydroxides via the molten salts method", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Because of their exotic electronic properties and abundant active sites, two-dimensional (2D) materials have potential in various fields. Pursuing a general synthesis methodology of 2D materials and advancing it from the laboratory to industry is of great importance. This type of method should be low cost, rapid and highly efficient. Here, we report the high-yield synthesis of 2D metal oxides and hydroxides via a molten salts method. We obtained a high-yield of 2D ion-intercalated metal oxides and hydroxides, such as cation-intercalated manganese oxides (Na0.55Mn2O4 center dot 1.5H(2)O and K0.27MnO2 center dot 0.54H(2)O), cation-intercalated tungsten oxides (Li2WO4 and Na2W4O13), and anion-intercalated metal hydroxides (Zn-5(OH)(8)(NO3)(2)center dot 2H(2)O and Cu-2(OH)(3)NO3), with a large lateral size and nullometre thickness in a short time. Using 2D Na2W4O13 as an electrode, a high performance electrochemical supercapacitor is achieved. We anticipate that our method will enable new path to the high-yield synthesis of 2D materials for applications in energy-related fields and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15630, "DOI": "10.1038/ncomms15630", "DOI Link": "http://dx.doi.org/10.1038/ncomms15630", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402304600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwon, MS; Lee, D; Seo, S; Jung, J; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwon, Min Sang; Lee, Dongwook; Seo, Sungbaek; Jung, Jaehun; Kim, Jinsang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring Intermolecular Interactions for Efficient Room-Temperature Phosphorescence from Purely Organic Materials in Amorphous Polymer Matrices", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein we report a rational design strategy for tailoring intermolecular interactions to enhance room-temperature phosphorescence from purely organic materials in amorphous matrices at ambient conditions. The built-in strong halogen and hydrogen bonding between the newly developed phosphor G1 and the poly(vinyl alcohol) (PVA) matrix efficiently suppresses vibrational dissipation and thus enables bright room-temperature phosphorescence (RTP) with quantum yields reaching 24%. Furthermore, we found that modulation of the strength of halogen and hydrogen bonding in the G1-PVA system by water molecules produced unique reversible phosphorescence-to-fluorescence switching behavior. This unique system can be utilized as a ratiometric water sensor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2014, "Volume": 53, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11177, "End Page": 11181, "Article Number": null, "DOI": "10.1002/anie.201404490", "DOI Link": "http://dx.doi.org/10.1002/anie.201404490", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343751100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bulushev, DA; Zacharska, M; Lisitsyn, AS; Podyacheva, OY; Hage, FS; Ramasse, QM; Bangert, U; Bulusheva, LG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bulushev, Dmitri A.; Zacharska, Monika; Lisitsyn, Alexander S.; Podyacheva, Olga Yu.; Hage, Fredrik S.; Ramasse, Quentin M.; Bangert, Ursel; Bulusheva, Lyubov G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single Atoms of Pt-Group Metals Stabilized by N-Doped Carbon nullofibers for Efficient Hydrogen Production from Formic Acid", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formic acid is a valuable chemical derived from biomass, as it has a high hydrogen-storage capacity and appears to be an attractive source of hydrogen for various applications. Hydrogen production via formic acid decomposition is often based on using supported catalysts with Pt-group metal nulloparticles. In the present paper, we show that the decomposition of the acid proceeds more rapidly on single metal atoms (by up to 1 order of magnitude). These atoms can be obtained by rather simple means through anchoring Pt-group metals onto mesoporous N-functionalized carbon nullofibers. A thorough evaluation of the structure of the active site by aberration-corrected scanning transmission electron microscopy (ac-STEM) in high-angle annular dark field (HAADF) mode and by CO chemisorption, X-ray photoelectron spectroscopy (XPS), and quantum chemical calculations reveals that the metal atom is coordinated by a pair of pyridinic nitrogen atoms at the edge of graphene sheets. The chelate binding provides an ionic/electron-deficient state of these atoms that prevents their aggregation and thereby leads to an excellent stability under the reaction conditions. Catalysts with single atoms have also shown very high selectivity. Evidently, the findings can be extended to hydrogen production from other chemicals and can be helpful for improving other energy-related and environmentally benign catalytic processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3442, "End Page": 3451, "Article Number": null, "DOI": "10.1021/acscatal.6b00476", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b00476", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377326700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Asadi, M; Kumar, B; Behranginia, A; Rosen, BA; Baskin, A; Repnin, N; Pisasale, D; Phillips, P; Zhu, W; Haasch, R; Klie, RF; Král, P; Abiade, J; Salehi-Khojin, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Asadi, Mohammad; Kumar, Bijandra; Behranginia, Amirhossein; Rosen, Brian A.; Baskin, Artem; Repnin, Nikita; Pisasale, Davide; Phillips, Patrick; Zhu, Wei; Haasch, Richard; Klie, Robert F.; Kral, Petr; Abiade, Jeremiah; Salehi-Khojin, Amin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust carbon dioxide reduction on molybdenum disulphide edges", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of carbon dioxide has been recognized as an efficient way to convert carbon dioxide to energy-rich products. Noble metals (for example, gold and silver) have been demonstrated to reduce carbon dioxide at moderate rates and low overpotentials. Nevertheless, the development of inexpensive systems with an efficient carbon dioxide reduction capability remains a challenge. Here we identify molybdenum disulphide as a promising cost-effective substitute for noble metal catalysts. We uncover that molybdenum disulphide shows superior carbon dioxide reduction performance compared with the noble metals with a high current density and low overpotential (54 mV) in an ionic liquid. Scanning transmission electron microscopy analysis and first principle modelling reveal that the molybdenum-terminated edges of molybdenum disulphide are mainly responsible for its catalytic performance due to their metallic character and a high d-electron density. This is further experimentally supported by the carbon dioxide reduction performance of vertically aligned molybdenum disulphide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 643, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4470, "DOI": "10.1038/ncomms5470", "DOI Link": "http://dx.doi.org/10.1038/ncomms5470", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340623400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pazos-Outón, LM; Szumilo, M; Lamboll, R; Richter, JM; Crespo-Quesada, M; Abdi-Jalebi, M; Beeson, HJ; Vrucinic, M; Alsari, M; Snaith, HJ; Ehrler, B; Friend, RH; Deschler, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pazos-Outon, Luis M.; Szumilo, Monika; Lamboll, Robin; Richter, Johannes M.; Crespo-Quesada, Micaela; Abdi-Jalebi, Mojtaba; Beeson, Harry J.; Vrucinic, Milan; Alsari, Mejd; Snaith, Henry J.; Ehrler, Bruno; Friend, Richard H.; Deschler, Felix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photon recycling in lead iodide perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead-halide perovskites have emerged as high-performance photovoltaic materials. We mapped the propagation of photogenerated luminescence and charges from a local photoexcitation spot in thin films of lead tri-iodide perovskites. We observed light emission at distances of >= 50 micrometers and found that the peak of the internal photon spectrum red-shifts from 765 to >= 800 nullometers. We used a lateral-contact solar cell with selective electron-and hole-collecting contacts and observed that charge extraction for photoexcitation >50 micrometers away from the contacts arose from repeated recycling between photons and electron-hole pairs. Thus, energy transport is not limited by diffusive charge transport but can occur over long distances through multiple absorption-diffusionemission events. This process creates high excitation densities within the perovskite layer and allows high open-circuit voltages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 587, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2016, "Volume": 351, "Issue": 6280, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1430, "End Page": 1433, "Article Number": null, "DOI": "10.1126/science.aaf1168", "DOI Link": "http://dx.doi.org/10.1126/science.aaf1168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372756200043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mower, TM; Long, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mower, Todd M.; Long, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical behavior of additive manufactured, powder-bed laser-fused materials", "Source Title": "MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanical behavior of four metallic alloys fabricated with layered, laser-heated methods of additive manufacturing (AM) was compared to that of similar alloys produced with conventional methods (wrought and machined). AM materials were produced by a leading commercial service provider, as opposed to incorporating material specimens produced by unique or specially-adapted equipment. The elastic moduli were measured in flexure, stress-strain characteristics were measured in tensile deformation, and fatigue strengths were measured in fully reversed bending. The effects of fabrication orientation, surface polishing, and hot isostatic pressing upon mechanical behavior were studied. The fatigue strengths exhibited by SLM AlSi10Mg and DMLS Ti6AI4V in the as-fabricated condition proved to be significantly inferior to that of conventional material. These lower fatigue strengths are a consequence of multiple fatigue cracks initiating at surface defects, internal voids and microcracks, and growing simultaneously during cyclic loading. Measured fatigue strengths of DMLS 316L and 17-4PH approached those of corresponding wrought materials when subjected to principal stresses aligned with the build planes. When cyclic stresses were applied across the build planes of the DMLS stainless steels, fatigue fractures often developed prematurely by separation of material. Post-processing the DMIS Ti6Al4V and SS316L with hot isostatic pressure elevated the fatigue strength significantly. Measurements of surface roughness with an optical profilometer, examinations of the material microstructures, and fractography contribute to an understanding of the mechanical of the additive materials. (C) 2015 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 737, "Times Cited, All Databases": 810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2016, "Volume": 651, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 198, "End Page": 213, "Article Number": null, "DOI": "10.1016/j.msea.2015.10.068", "DOI Link": "http://dx.doi.org/10.1016/j.msea.2015.10.068", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367486800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, TR; Levin, BDA; Guzman, JJL; Enders, A; Muller, DA; Angenent, LT; Lehmann, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Tianran; Levin, Barnaby D. A.; Guzman, Juan J. L.; Enders, Akio; Muller, David A.; Angenent, Largus T.; Lehmann, Johannes", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid electron transfer by the carbon matrix in natural pyrogenic carbon", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface functional groups constitute major electroactive components in pyrogenic carbon. However, the electrochemical properties of pyrogenic carbon matrices and the kinetic preference of functional groups or carbon matrices for electron transfer remain unknown. Here we show that environmentally relevant pyrogenic carbon with average H/ C and O/ C ratios of less than 0.35 and 0.09 can directly transfer electrons more than three times faster than the charging and discharging cycles of surface functional groups and have a 1.5V potential range for biogeochemical reactions that invoke electron transfer processes. Surface functional groups contribute to the overall electron flux of pyrogenic carbon to a lesser extent with greater pyrolysis temperature due to lower charging and discharging capacities, although the charging and discharging kinetics remain unchanged. This study could spur the development of a new generation of biogeochemical electron flux models that focus on the bacteria-carbon-mineral conductive network.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14873, "DOI": "10.1038/ncomms14873", "DOI Link": "http://dx.doi.org/10.1038/ncomms14873", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397881200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, GL; Liu, Q; Lau, KKS; Liu, Y; Liu, X; Gao, H; Zhou, XW; Zhuang, MH; Ren, Y; Li, JD; Shao, MH; Ouyang, MG; Pan, F; Chen, ZH; Amine, K; Chen, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Gui-Liang; Liu, Qiang; Lau, Kenneth K. S.; Liu, Yuzi; Liu, Xiang; Gao, Han; Zhou, Xinwei; Zhuang, Minghao; Ren, Yang; Li, Jiadong; Shao, Minhua; Ouyang, Minggao; Pan, Feng; Chen, Zonghai; Amine, Khalil; Chen, Guohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building ultraconformal protective layers on both secondary and primary particles of layered lithium transition metal oxide cathodes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite their relatively high capacity, layered lithium transition metal oxides suffer from crystal and interfacial structural instability under aggressive electrochemical and thermal driving forces, leading to rapid performance degradation and severe safety concerns. Here we report a transformative approach using an oxidative chemical vapour deposition technique to build a protective conductive polymer (poly(3,4-ethylenedioxythiophene)) skin on layered oxide cathode materials. The ultraconformal poly(3,4-ethylenedioxythiophene) skin facilitates the transport of lithium ions and electrons, significantly suppresses the undesired layered to spinel/rock-salt phase transformation and the associated oxygen loss, mitigates intergranular and intragranular mechanical cracking, and effectively stabilizes the cathode-electrolyte interface. This approach remarkably enhances the capacity and thermal stability under high-voltage operation. Building a protective skin at both secondary and primary particle levels of layered oxides offers a promising design strategy for Ni-rich cathodes towards high-energy, long-life and safe lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 484, "End Page": 494, "Article Number": null, "DOI": "10.1038/s41560-019-0387-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0387-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471295000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, DL; Zhu, M; Kang, PB; Zhu, T; Yuan, HC; Lan, JL; Yang, XP; Sui, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Dongli; Zhu, Ming; Kang, Peibin; Zhu, Tao; Yuan, Haocheng; Lan, Jinle; Yang, Xiaoping; Sui, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Enhancing Gel Polymer Electrolyte by In Situ Construction for Enabling Safe Lithium Metal Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal battery (LMB) possessing a high theoretical capacity is a promising candidate of advanced energy storage devices. However, its safety and stability are challenged by lithium dendrites and the leakage of liquid electrolyte. Here, a self-enhancing gel polymer electrolyte (GPE) is created by in situ polymerizing 1,3-dioxolane (DOL) in the nullofibrous skeleton for enabling safe LMB. The nullofiber membrane possesses a better affinity with poly-DOL (PDOL) than commercial separator for constructing homogeneous GPE with enhanced ion conductivity. Furthermore, polydopamine is introduced on nullofiber membrane to form hydrogen bonding with PDOL and bis((trifluoromethyl)sulfonyl)imide anion, dramatically improving the mechanical strength, ionic conductivity, and transference number of GPE. Besides, molecular dynamic simulation is used to reveal the intrinsic factors of high ionic conductivity and reinforcing effect in the meantime. Consequently, the LiFePO4//Li batteries using self-enhancing GPE show extraordinary cyclic stability over 800 cycles under high current density of 2 C, with a capacity decay of 0.021% per cycle, effectively suppressing the growth of lithium dendrites. This ingenious strategy is expected to manufacture advanced performance and high safety LMBs and compatible with the current battery production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103663, "DOI": "10.1002/advs.202103663", "DOI Link": "http://dx.doi.org/10.1002/advs.202103663", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000729105400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Zhang, Y; Lu, HY; Wang, YF; Xu, JS; Zhu, JX; Zhang, C; Liu, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Le; Zhang, Yu; Lu, Hengyi; Wang, Yufeng; Xu, Jingsan; Zhu, Jixin; Zhang, Chao; Liu, Tianxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cryopolymerization enables anisotropic polyaniline hybrid hydrogels with superelasticity and highly deformation-tolerant electrochemical energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of energy storage devices that can endure large and complex deformations is central to emerging wearable electronics. Hydrogels made from conducting polymers give rise to a promising integration of high conductivity and versatility in processing. However, the emergence of conducting polymer hydrogels with a desirable network structure cannot be readily achieved using conventional polymerization methods. Here we present a cryopolymerization strategy for preparing an intrinsically stretchable, compressible and bendable anisotropic polyvinyl alcohol/polyaniline hydrogel with a complete recovery of 100% stretching strain, 50% compressing strain and fully bending. Due to its high mechanical strength, superelastic properties and bi-continuous phase structure, the as-obtained anisotropic polyvinyl alcohol/polyaniline hydrogel can work as a stretching/compressing/bending electrode, maintaining its stable output under complex deformations for an all-solid-state supercapacitor. In particular, it achieves an extremely high energy density of 27.5 Wh kg(-1), which is among that of state-of-the-art stretchable supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 62, "DOI": "10.1038/s41467-019-13959-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13959-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511962400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, B; Zhang, MH; Wu, LJ; Wang, J; Xia, YG; Qian, DN; Liu, HD; Hy, S; Chen, Y; An, K; Zhu, YM; Liu, ZP; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Bao; Zhang, Minghao; Wu, Lijun; Wang, Jun; Xia, Yonggao; Qian, Danna; Liu, Haodong; Hy, Sunny; Chen, Yan; An, Ke; Zhu, Yimei; Liu, Zhaoping; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gas-solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice oxygen can play an intriguing role in electrochemical processes, not only maintaining structural stability, but also influencing electron and ion transport properties in high-capacity oxide cathode materials for Li-ion batteries. Here, we report the design of a gas-solid interface reaction to achieve delicate control of oxygen activity through uniformly creating oxygen vacancies without affecting structural integrity of Li-rich layered oxides. Theoretical calculations and experimental characterizations demonstrate that oxygen vacancies provide a favourable ionic diffusion environment in the bulk and significantly suppress gas release from the surface. The target material is achievable in delivering a discharge capacity as high as 301 mAhg(-1) with initial Coulombic efficiency of 93.2%. After 100 cycles, a reversible capacity of 300 mAhg(-1) still remains without any obvious decay in voltage. This study sheds light on the comprehensive design and control of oxygen activity in transition-metal-oxide systems for next-generation Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 624, "Times Cited, All Databases": 667, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12108, "DOI": "10.1038/ncomms12108", "DOI Link": "http://dx.doi.org/10.1038/ncomms12108", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379911200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, X; Liu, HL; Yin, Q; Wu, JC; Chen, PZ; Zhang, GZ; Liu, GM; Wu, CZ; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Xu; Liu, Huili; Yin, Qin; Wu, Junchi; Chen, Pengzuo; Zhang, Guangzhao; Liu, Guangming; Wu, Changzheng; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A zwitterionic gel electrolyte for efficient solid-state supercapacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gel electrolytes have attracted increasing attention for solid-state supercapacitors. An ideal gel electrolyte usually requires a combination of advantages of high ion migration rate, reasonable mechanical strength and robust water retention ability at the solid state for ensuring excellent work durability. Here we report a zwitterionic gel electrolyte that successfully brings the synergic advantages of robust water retention ability and ion migration channels, manifesting in superior electrochemical performance. When applying the zwitterionic gel electrolyte, our graphene-based solid-state supercapacitor reaches a volume capacitance of 300.8 F cm(-3) at 0.8 A cm(-3) with a rate capacity of only 14.9% capacitance loss as the current density increases from 0.8 to 20 A cm(-3), representing the best value among the previously reported graphene-based solid-state supercapacitors, to the best of our knowledge. We anticipate that zwitterionic gel electrolyte may be developed as a gel electrolyte in solid-state supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11782, "DOI": "10.1038/ncomms11782", "DOI Link": "http://dx.doi.org/10.1038/ncomms11782", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376674700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Zhai, PB; Li, AW; Wei, B; Si, KP; Wei, Y; Wang, XG; Zhu, GD; Chen, Q; Gu, XK; Zhang, RF; Zhou, W; Gong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Zhai, Pengbo; Li, Aowen; Wei, Bo; Si, Kunpeng; Wei, Yi; Wang, Xingguo; Zhu, Guangda; Chen, Qian; Gu, Xiaokang; Zhang, Ruifeng; Zhou, Wu; Gong, Yongji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical CO2 reduction to ethylene by ultrathin CuO nulloplate arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 to multi-carbon fuels and chemical feedstocks is an appealing approach to mitigate excessive CO2 emissions. However, the reported catalysts always show either a low Faradaic efficiency of the C2+ product or poor long-term stability. Herein, we report a facile and scalable anodic corrosion method to synthesize oxygen-rich ultrathin CuO nulloplate arrays, which form Cu/Cu2O heterogeneous interfaces through self-evolution during electrocatalysis. The catalyst exhibits a high C2H4 Faradaic efficiency of 84.5%, stable electrolysis for similar to 55 h in a flow cell using a neutral KCI electrolyte, and a full-cell ethylene energy efficiency of 27.6% at 200 mA cm(-2) in a membrane electrode assembly electrolyzer. Mechanism analyses reveal that the stable nullostructures, stable Cu/Cu2O interfaces, and enhanced adsorption of the *OCCOH intermediate preserve selective and prolonged C2H4 production. The robust and scalable produced catalyst coupled with mild electrolytic conditions facilitates the practical application of electrochemical CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1877, "DOI": "10.1038/s41467-022-29428-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29428-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779311200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Locardi, F; Cirignullo, M; Baranov, D; Dang, ZY; Prato, M; Drago, F; Ferretti, M; Pinchetti, V; Fanciulli, M; Brovelli, S; De Trizio, L; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Locardi, Federico; Cirignullo, Matilde; Baranov, Dmitry; Dang, Zhiya; Prato, Mirko; Drago, Filippo; Ferretti, Maurizio; Pinchetti, Valerio; Fanciulli, Marco; Brovelli, Sergio; De Trizio, Luca; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 nullocrystals", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show here the first colloidal synthesis of double perovskite Cs2AgInCl6 nullocrystals (NCs) with a control over their size distribution. In our approach, metal carboxylate precursors and ligands (oleylamine and oleic acid) are dissolved in diphenyl ether and reacted at 105 degrees C with benzoyl chloride. The resulting Cs2AgInCl6 NCs exhibit the expected double perovskite crystal structure, are stable under air, and show a broad spectrum white photoluminescence (PL) with quantum yield of similar to 1.6 +/- 1%. The optical properties of these NCs were improved by synthesizing Mn-doped Cs2AgInCl6 NCs through the simple addition of Mn-acetate to the reaction mixture. The NC products were characterized by the same double perovskite crystal structure, and Mn doping levels up to 1.5%, as confirmed by elemental analyses. The effective incorporation of Mn ions inside Cs2AgInCl6 NCs was also proved by means of electron spin resonullce spectroscopy. A bright orange emission characterized our Mn-doped Cs2AgInCl6 NCs with a PL quantum yield as high as similar to 16 +/- 4%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 457, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2018, "Volume": 140, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12989, "End Page": 12995, "Article Number": null, "DOI": "10.1021/jacs.8b07983", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b07983", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447354800050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JH; Yamada, Y; Sodeyama, K; Chiang, CH; Tateyama, Y; Yamada, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro; Chiang, Ching Hua; Tateyama, Yoshitaka; Yamada, Atsuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconcentrated electrolytes for a high-voltage lithium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Finding a viable electrolyte for next-generation 5V-class lithium-ion batteries is of primary importance. A long-standing obstacle has been metal-ion dissolution at high voltages. The LiPF6 salt in conventional electrolytes is chemically unstable, which accelerates transition metal dissolution of the electrode material, yet beneficially suppresses oxidative dissolution of the aluminium current collector; replacing LiPF6 with more stable lithium salts may diminish transition metal dissolution but unfortunately encounters severe aluminium oxidation. Here we report an electrolyte design that can solve this dilemma. By mixing a stable lithium salt LiN(SO2F)(2) with dimethyl carbonate solvent at extremely high concentrations, we obtain an unusual liquid showing a three-dimensional network of anions and solvent molecules that coordinate strongly to Li+ ions. This simple formulation of superconcentrated LiN(SO2F)(2)/dimethyl carbonate electrolyte inhibits the dissolution of both aluminium and transition metal at around 5V, and realizes a high-voltage LiNi0.5Mn1.5O4/graphite battery that exhibits excellent cycling durability, high rate capability and enhanced safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 905, "Times Cited, All Databases": 966, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12032, "DOI": "10.1038/ncomms12032", "DOI Link": "http://dx.doi.org/10.1038/ncomms12032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379110300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, CW; Li, QY; Wu, CZ; Zhang, J; Jin, YG; MacFarlane, DR; Sun, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chuangwei; Li, Qinye; Wu, Chengzhang; Zhang, Jie; Jin, Yonggang; MacFarlane, Douglas R.; Sun, Chenghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Boron Catalysts for Nitrogen Reduction Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Boron has been explored as p-block catalysts for nitrogen reduction reaction (NRR) by density functional theory. Unlike transition metals, on which the active centers need empty d orbitals to accept the lone-pair electrons of the nitrogen molecule, the sp(3) hybrid orbital of the boron atom can form B-to-N pi-back bonding. This results in the population of the N-N pi* orbital and the concomitant decrease of the N-N bond order. We demonstrate that the catalytic activity of boron is highly correlated with the degree of charge transfer between the boron atom and the substrate. Among the 21 concept-catalysts, single boron atoms supported on graphene and substituted into h-MoS2 are identified as the most promising NRR catalysts, offering excellent energy efficiency and selectivity against hydrogen evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 553, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 141, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2884, "End Page": 2888, "Article Number": null, "DOI": "10.1021/jacs.8b13165", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b13165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459642000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chai, YC; Han, X; Li, WY; Liu, SS; Yao, SK; Wang, C; Shi, W; Da-Silva, I; Manuel, P; Cheng, YQ; Daemen, LD; Ramirez-Cuesta, AJ; Tang, CC; Jiang, L; Yang, SH; Guan, NJ; Li, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chai, Yuchao; Han, Xue; Li, Weiyao; Liu, Shanshan; Yao, Sikai; Wang, Chong; Shi, Wei; da-Silva, Ivan; Manuel, Pascal; Cheng, Yongqiang; Daemen, Luke D.; Ramirez-Cuesta, Anibal J.; Tang, Chiu C.; Jiang, Ling; Yang, Sihai; Guan, Naijia; Li, Landong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of zeolite pore interior for chemoselective alkyne/olefin separations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficient removal of alkyne impurities for the production of polymer-grade lower olefins remains an important and challenging goal for many industries. We report a strategy to control the pore interior of faujasite (FAU) zeolites by the confinement of isolated open nickel(II) sites in their six-membered rings. Under ambient conditions, Ni@FAU showed remarkable adsorption of alkynes and efficient separations of acetylene/ethylene, propyne/propylene. and butyne/1,3-butadiene mixtures, with unprecedented dynamic separation selectivities of 100, 92, and 83, respectively. In situ neutron diffraction and inelastic neutron scattering revealed that confined nickel(II) sites enabled chemoselective and reversible binding to acetylene through the formation of metastable [Ni(II)(C2H2)(3)] complexes. Control of the chemistry of pore interiors of easily scalable zeolites has unlocked their potential in challenging industrial separations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2020, "Volume": 368, "Issue": 6494, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1002, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay8447", "DOI Link": "http://dx.doi.org/10.1126/science.aay8447", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000538332600046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Buin, A; Ip, AH; Li, W; Voznyy, O; Comin, R; Yuan, MJ; Jeon, S; Ning, ZJ; McDowell, JJ; Kanjanaboos, P; Sun, JP; Lan, XZ; Quan, LN; Kim, DH; Hill, IG; Maksymovych, P; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jixian; Buin, Andrei; Ip, Alexander H.; Li, Wei; Voznyy, Oleksandr; Comin, Riccardo; Yuan, Mingjian; Jeon, Seokmin; Ning, Zhijun; McDowell, Jeffrey J.; Kanjanaboos, Pongsakorn; Sun, Jon-Paul; Lan, Xinzheng; Quan, Li Na; Kim, Dong Ha; Hill, Ian G.; Maksymovych, Peter; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-fullerene hybrid materials suppress hysteresis in planar diodese", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed planar perovskite devices are highly desirable in a wide variety of optoelectronic applications; however, they are prone to hysteresis and current instabilities. Here we report the first perovskite-PCBM hybrid solid with significantly reduced hysteresis and recombination loss achieved in a single step. This new material displays an efficient electrically coupled microstructure: PCBM is homogeneously distributed throughout the film at perovskite grain boundaries. The PCBM passivates the key PbI3- antisite defects during the perovskite self-assembly, as revealed by theory and experiment. Photoluminescence transient spectroscopy proves that the PCBM phase promotes electron extraction. We showcase this mixed material in planar solar cells that feature low hysteresis and enhanced photovoltage. Using conductive AFM studies, we reveal the memristive properties of perovskite films. We close by positing that PCBM, by tying up both halide-rich antisites and unincorporated halides, reduces electric field-induced anion migration that may give rise to hysteresis and unstable diode behaviour.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1090, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7081, "DOI": "10.1038/ncomms8081", "DOI Link": "http://dx.doi.org/10.1038/ncomms8081", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355531400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Wang, C; Zhao, YY; Zhang, YX; Gao, JF; Sun, LC; Hou, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Wang, Chen; Zhao, Yuanyuan; Zhang, Yanxue; Gao, Junfeng; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design efficient transition metal-based electrocatalysts for oxygen evolution reaction (OER) is critical for water splitting. However, industrial water-alkali electrolysis requires large current densities at low overpotentials, always limited by intrinsic activity. Herein, we report hierarchical bimetal nitride/hydroxide (NiMoN/NiFe LDH) array as model catalyst, regulating the electronic states and tracking the relationship of structure-activity. As-activated NiMoN/NiFe LDH exhibits the industrially required current density of 1000 mA cm(-2) at overpotential of 266 mV with 250 h stability for OER. Especially, in-situ electrochemical spectroscopic reveals that heterointerface facilitates dynamic structure evolution to optimize electronic structure. Operando electrochemical impedance spectroscopy implies accelerated OER kinetics and intermediate evolution due to fast charge transport. The OER mechanism is revealed by the combination of theoretical and experimental studies, indicating as-activated NiMoN/NiFe LDH follows lattice oxygen oxidation mechanism with accelerated kinetics. This work paves an avenue to develop efficient catalysts for industrial water electrolysis via tuning electronic states. Rational design of efficient electrocatalysts for oxygen evolution reaction is critical for water-alkali electrolysis. Here, the authors fabricate a NiMoN/NiFe layered double hydroxide and show the accelerated oxygen evolution kinetics are due to the heterointerface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1873, "DOI": "10.1038/s41467-023-37091-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37091-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983843800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, XH; Ding, D; Chen, DC; Waller, G; Bu, YF; Wang, ZX; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Xunhui; Ding, Dong; Chen, Dongchang; Waller, Gordon; Bu, Yunfei; Wang, Zhixing; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional ultrathin Ni(OH)2 nullosheets grown on nickel foam for high-performance supercapacitors", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, we report the growth of ultrathin Ni(OH)(2) nullosheets on nickel foam at room temperature via a cost-effective and simple process, oxidizing fresh nickel foam in a wet environment followed by a morphology transformation in a mixed alkaline and oxidative solution without the need for any additional nickel sources, templates, or surfactants. When tested as electrode for a supercapacitor, the Ni(OH)(2) nullosheets grown on nickel foam displayed excellent performance, demonstrating specific capacitance of 2384.3 F g(-1) at a charge and discharge current density of 1 A g(-1) and 1288.1 F g(-1) at 5 A g(-1) with a good cycling ability (similar to 75% of the initial specific capacitance remained after 3000 cycles). The excellent electrochemical performance is attributed to its unique nullostructures, which may facilitate rapid ion transport near electrode surfaces, while allowing facile redox reactions associated with charge storage by the nullosheets. The demonstrated high specific capacity and the remarkable rate performance of the Ni(OH)(2) nullosheets, together with the flexibility of the nickel foam substrate, make the three-dimensional nullostructured electrodes ideally suited for low-cost, high-performance supercapacitor applications. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 11, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 154, "End Page": 161, "Article Number": null, "DOI": "10.1016/j.nulloen.2014.10.029", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2014.10.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351194300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noor, N; Shapira, A; Edri, R; Gal, I; Wertheim, L; Dvir, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noor, Nadav; Shapira, Assaf; Edri, Reuven; Gal, Idan; Wertheim, Lior; Dvir, Tal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Personalized Thick and Perfusable Cardiac Patches and Hearts", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Generation of thick vascularized tissues that fully match the patient still remains an unmet challenge in cardiac tissue engineering. Here, a simple approach to 3D-print thick, vascularized, and perfusable cardiac patches that completely match the immunological, cellular, biochemical, and anatomical properties of the patient is reported. To this end, a biopsy of an omental tissue is taken from patients. While the cells are reprogrammed to become pluripotent stem cells, and differentiated to cardiomyocytes and endothelial cells, the extracellular matrix is processed into a personalized hydrogel. Following, the two cell types are separately combined with hydrogels to form bioinks for the parenchymal cardiac tissue and blood vessels. The ability to print functional vascularized patches according to the patient's anatomy is demonstrated. Blood vessel architecture is further improved by mathematical modeling of oxygen transfer. The structure and function of the patches are studied in vitro, and cardiac cell morphology is assessed after transplantation, revealing elongated cardiomyocytes with massive actinin striation. Finally, as a proof of concept, cellularized human hearts with a natural architecture are printed. These results demonstrate the potential of the approach for engineering personalized tissues and organs, or for drug screening in an appropriate anatomical structure and patient-specific biochemical microenvironment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 750, "Times Cited, All Databases": 840, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2019, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900344, "DOI": "10.1002/advs.201900344", "DOI Link": "http://dx.doi.org/10.1002/advs.201900344", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470189500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, XD; Zhao, WX; Zhang, F; Cao, Y; Liu, F; Bia, S; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Xiaodong; Zhao, Wuxue; Zhang, Fan; Cao, Yu; Liu, Feng; Bia, Shuai; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A two-dimensional conjugated polymer framework with fully sp2-bonded carbon skeleton", "Source Title": "POLYMER CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of crystalline two-dimensional (2D) covalent organic frameworks (COFs) with fully unsaturated carbon-carbon backbones via a solution approach remains a great challenge. In this work, we report the first example of an olefin-linked 2D conjugated COF using a Knoevenagel polycondensation reaction of 1,4-phenylene diacetonitrile and three armed aromatic aldehyde. The resulting 2D poly(phenelyenevinylene) framework (2DPPV) possesses a sheet morphology, and a crystalline layered structure featuring a fully sp(2)-bonded carbon skeleton with pendant cyanide groups. Its unique alternating structure with a serrated configuration has been essentially evaluated using HR-TEM TEM analysis, nitrogen physisorption measurements, PXRD studies and theoretical simulations. Upon thermal and activation treatments, the as-prepared 2DPPV can be facilely converted into porous carbon nullosheets with large specific surface areas of up to 880 m(2) g(-1) which exhibit an excellent electrochemical performance as supercapacitor electrodes and electrocatalysts for the oxygen reduction reaction. This represents an economic non-template approach to 2D porous carbon materials for energy-related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4176, "End Page": 4181, "Article Number": null, "DOI": "10.1039/c6py00561f", "DOI Link": "http://dx.doi.org/10.1039/c6py00561f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378395900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, PS; Wang, MY; Duan, XX; Zheng, LR; Cheng, XP; Zhang, YF; Kuang, Y; Li, YP; Ma, Q; Feng, ZX; Liu, W; Sun, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Pengsong; Wang, Maoyu; Duan, Xinxuan; Zheng, Lirong; Cheng, Xiaopeng; Zhang, Yuefei; Kuang, Yun; Li, Yaping; Ma, Qing; Feng, Zhenxing; Liu, Wen; Sun, Xiaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting oxygen evolution of single-atomic ruthenium through electronic coupling with cobalt-iron layered double hydroxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single atom catalyst, which contains isolated metal atoms singly dispersed on supports, has great potential for achieving high activity and selectivity in hetero-catalysis and electrocatalysis. However, the activity and stability of single atoms and their interaction with support still remains a mystery. Here we show a stable single atomic ruthenium catalyst anchoring on the surface of cobalt iron layered double hydroxides, which possesses a strong electronic coupling between ruthenium and layered double hydroxides. With 0.45 wt.% ruthenium loading, the catalyst exhibits outstanding activity with overpotential 198 mV at the current density of 10 mA cm(-2) and a small Tafel slope of 39 mV dec(-1) for oxygen evolution reaction. By using operando X-ray absorption spectroscopy, it is disclosed that the isolated single atom ruthenium was kept under the oxidation states of 4+ even at high overpotential due to synergetic electron coupling, which endow exceptional electrocatalytic activity and stability simultaneously.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1711, "DOI": "10.1038/s41467-019-09666-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09666-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464338100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XL; Zhang, B; De Luna, P; Liang, YF; Comin, R; Voznyy, O; Han, LL; de Arquer, FPG; Liu, M; Dinh, CT; Regier, T; Dynes, JJ; He, SS; Xin, HLL; Peng, HS; Prendergast, D; Du, XW; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xueli; Zhang, Bo; De Luna, Phil; Liang, Yufeng; Comin, Riccardo; Voznyy, Oleksandr; Han, Lili; de Arquer, F. Pelayo Garcia; Liu, Min; Cao Thang Dinh; Regier, Tom; Dynes, James J.; He, Sisi; Xin, Huolin L.; Peng, Huisheng; Prendergast, David; Du, Xiwen; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiency with which renewable fuels and feedstocks are synthesized from electrical sources is limited at present by the sluggish oxygen evolution reaction (OER) in pH-neutral media. We took the view that generating transition-metal sites with high valence at low applied bias should improve the activity of neutral OER catalysts. Here, using density functional theory, we find that the formation energy of desired Ni4+ sites is systematically modulated by incorporating judicious combinations of Co, Fe and non-metal P. We therefore synthesized NiCoFeP oxyhydroxides and probed their oxidation kinetics with in situ soft X-ray absorption spectroscopy (sXAS). In situ sXAS studies of neutral-pH OER catalysts indicate ready promotion of Ni4+ under low overpotential conditions. The NiCoFeP catalyst outperforms IrO2 and retains its performance following 100 h of operation. We showcase NiCoFeP in a membrane-free CO2 electroreduction system that achieves a 1.99 V cell voltage at 10 mA cm(-2), reducing CO2 into CO and oxidizing H2O to O-2 with a 64% electricity-to-chemical-fuel efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 528, "Times Cited, All Databases": 545, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 149, "End Page": 154, "Article Number": null, "DOI": "10.1038/NCHEM.2886", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2886", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423144000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Pereira-Hernández, XI; Chen, YZ; Xu, J; Zhao, JK; Pao, CW; Fang, CY; Zeng, J; Wang, Y; Gates, BC; Liu, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xu; Pereira-Hernulldez, Xavier Isidro; Chen, Yizhen; Xu, Jia; Zhao, Jiankang; Pao, Chih-Wen; Fang, Chia-Yu; Zeng, Jie; Wang, Yong; Gates, Bruce C.; Liu, Jingyue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional CeOx nulloglues for robust atomically dispersed catalysts", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts(1) make exceptionally efficient use of expensive noble metals and can bring out unique properties(1-3). However, applications are usually compromised by limited catalyst stability, which is due to sintering(3,4). Although sintering can be suppressed by anchoring the metal atoms to oxide supports(1,5,6), strong metal-oxygen interactions often leave too few metal sites available for reactant binding and catalysis(6,7), and when exposed to reducing conditions at sufficiently high temperatures, even oxide-anchored single-atom catalysts eventually sinter(4,8,9). Here we show that the beneficial effects of anchoring can be enhanced by confining the atomically dispersed metal atoms on oxide nulloclusters or 'nulloglues', which themselves are dispersed and immobilized on a robust, high-surface-area support. We demonstrate the strategy by grafting isolated and defective CeOx nulloglue islands onto high-surface-area SiO2; the nulloglue islands then each host on average one Pt atom. We find that the Pt atoms remain dispersed under both oxidizing and reducing environments at high temperatures, and that the activated catalyst exhibits markedly increased activity for CO oxidation. We attribute the improved stability under reducing conditions to the support structure and the much stronger affinity of Pt atoms for CeOx than for SiO2, which ensures the Pt atoms can move but remain confined to their respective nulloglue islands. The strategy of using functional nulloglues to confine atomically dispersed metals and simultaneously enhance their reactivity is general, and we anticipate that it will take single-atom catalysts a step closer to practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2022, "Volume": 611, "Issue": 7935, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05251-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05251-6", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000875061600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YX; Qiu, G; Wang, RX; Huang, SY; Wang, QX; Liu, YY; Du, YC; Goddard, WA ; Kim, MJ; Xu, XF; Ye, PD; Wu, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yixiu; Qiu, Gang; Wang, Ruoxing; Huang, Shouyuan; Wang, Qingxiao; Liu, Yuanyue; Du, Yuchen; Goddard, William A., III; Kim, Moon J.; Xu, Xianfan; Ye, Peide D.; Wu, Wenzhuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-effect transistors made from solution-grown two-dimensional tellurene", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reliable production of two-dimensional (2D) crystals is essential for the development of new technologies based on 2D materials. However, current synthesis methods suffer from a variety of drawbacks, including limitations in crystal size and stability. Here, we report the fabrication of large-area, high-quality 2D tellurium (tellurene) using a substrate-free solution process. Our approach can create crystals with process-tunable thickness, from a monolayer to tens of nullometres, and with lateral sizes of up to 100 mu m. The chiral-chain van der Waals structure of tellurene gives rise to strong in-plane anisotropic properties and large thickness-dependent shifts in Raman vibrational modes, which is not observed in other 2D layered materials. We also fabricate tellurene field-effect transistors, which exhibit air-stable performance at room temperature for over two months, on/off ratios on the order of 10(6), and field-effect mobilities of about 700 cm(2) V-1 s(-1). Furthermore, by scaling down the channel length and integrating with high-k dielectrics, transistors with a significant on-state current density of 1 A mm(-1) are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 701, "Times Cited, All Databases": 758, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": 236, "Article Number": null, "DOI": "10.1038/s41928-018-0058-4", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0058-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444074900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Acharjya, A; Ye, MY; Rabeah, J; Li, S; Kochovski, Z; Youk, S; Roeser, J; Grüneberg, J; Penschke, C; Schwarze, M; Wang, TY; Lu, Y; van de Krol, R; Oschatz, M; Schomäcker, R; Saalfrank, P; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jin; Acharjya, Amitava; Ye, Meng-Yang; Rabeah, Jabor; Li, Shuang; Kochovski, Zdravko; Youk, Sol; Roeser, Jerome; Grueneberg, Julia; Penschke, Christopher; Schwarze, Michael; Wang, Tianyi; Lu, Yan; van de Krol, Roel; Oschatz, Martin; Schomaecker, Reinhard; Saalfrank, Peter; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protonated Imine-Linked Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) have emerged as an important class of organic semiconductors and photocatalysts for the hydrogen evolution reaction (HER)from water. To optimize their photocatalytic activity, typically the organic moieties constituting the frameworks are considered and the most suitable combinations of them are searched for. However, the effect of the covalent linkage between these moieties on the photocatalytic performance has rarely been studied. Herein, we demonstrate that donor-acceptor (D-A) type imine-linked COFs can produce hydrogen with a rate as high as 20.7 mmol g(-1) h(-1) under visible light irradiation, upon protonation of their imine linkages. A significant red-shift in light absorbance, largely improved charge separation efficiency, and an increase in hydrophilicity triggered by protonation of the Schiff-base moieties in the imine-linked COFs, are responsible for the improved photocatalytic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2021, "Volume": 60, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19797, "End Page": 19803, "Article Number": null, "DOI": "10.1002/anie.202104870", "DOI Link": "http://dx.doi.org/10.1002/anie.202104870", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678854200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, B; Yang, ZC; Chen, YT; Yuan, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Bo; Yang, Zhengchun; Chen, Yantao; Yuan, Zhihao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel cobalt phosphide with three-dimensional nullostructure as a highly efficient electrocatalyst for hydrogen evolution reaction in both acidic and alkaline electrolytes", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal phosphides (TMPs) are promising candidates for noble metal free electrocatalysts in water splitting applications. In this work, we present the facile synthesis of nickel cobalt phosphide electrocatalyst with three-dimensional nullostructure (3D-NiCoP) on the nickel foam, via hydrothermal reaction and phosphorization. The as-prepared electrocatalyst exhibits an excellent activity for hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes, with small overpotentials to drive 10 mA/cm(2) (80 mV for 0.5 M H2SO4, 105 mV for 1 M KOH), small Tafel slopes (37 mV/dec for 0.5 M H2SO4, 79 mV/dec for 1 M KOH), and satisfying durability in long-term electrolysis. 3D-NiCoP also shows a superior HER activity compared to single metal phosphide, such as cobalt phosphide and nickel phosphide. The outstanding performance for HER suggests the great potential of 3D-NiCoP as a highly efficient electrocatalyst for water splitting technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 375, "End Page": 380, "Article Number": null, "DOI": "10.1007/s12274-018-2226-2", "DOI Link": "http://dx.doi.org/10.1007/s12274-018-2226-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455549200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, L; Ai, MH; Huang, CY; Yin, L; Liu, X; Zhang, RR; Wang, SB; Jiang, Z; Zhang, XW; Zou, JJ; Mi, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Lun; Ai, Minhua; Huang, Chenyu; Yin, Li; Liu, Xiang; Zhang, Rongrong; Wang, Songbo; Jiang, Zheng; Zhang, Xiangwen; Zou, Ji-Jun; Mi, Wenbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulating spin polarization of titanium dioxide for efficient photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalysis has been regarded as a promising strategy for hydrogen production and high-value-added chemicals synthesis, in which the activity of photocatalyst depends significantly on their electronic structures, however the effect of electron spin polarization has been rarely considered. Here we report a controllable method to manipulate its electron spin polarization by tuning the concentration of Ti vacancies. The characterizations confirm the emergence of spatial spin polarization among Ti-defected TiO2, which promotes the efficiency of charge separation and surface reaction via the parallel alignment of electron spin orientation. Specifically, Ti0.936O2, possessing intensive spin polarization, performs 20-fold increased photocatalytic hydrogen evolution and 8-fold increased phenol photodegradation rates, compared with stoichiometric TiO2. Notably, we further observed the positive effect of external magnetic fields on photocatalytic activity of spin-polarized TiO2, attributed to the enhanced electron-spin parallel alignment. This work may create the opportunity for tailoring the spin-dependent electronic structures in metal oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 418, "DOI": "10.1038/s41467-020-14333-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14333-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511941200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schmidt, H; Wang, SF; Chu, LQ; Toh, M; Kumar, R; Zhao, WJ; Neto, AHC; Martin, J; Adam, S; Özyilmaz, B; Eda, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schmidt, Hennrik; Wang, Shunfeng; Chu, Leiqiang; Toh, Minglin; Kumar, Rajeev; Zhao, Weijie; Neto, A. H. Castro; Martin, Jens; Adam, Shaffique; Oezyilmaz, Barbaros; Eda, Goki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transport Properties of Monolayer MoS2 Grown by Chemical Vapor Deposition", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent success in the growth of monolayer MoS2 via chemical vapor deposition (CVD) has opened up prospects for the implementation of these materials into thin film electronic and optoelectronic devices. Here, we investigate the electronic transport properties of individual crystallites of high quality CVD-grown monolayer MoS2. The devices show low temperature mobilities up to 500 cm(2) V-1 s(-1) and a clear signature of metallic conduction at high doping densities. These characteristics are comparable to the electronic properties of the best mechanically exfoliated monolayers in literature, verifying the high electronic quality of the CVD-grown materials. We analyze the different scattering mechanisms and show that the short-range scattering plays a dominullt role in the highly conducting regime at low temperatures. Additionally, the influence of optical phonons as a limiting factor is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1909, "End Page": 1913, "Article Number": null, "DOI": "10.1021/nl4046922", "DOI Link": "http://dx.doi.org/10.1021/nl4046922", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334572400035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SB; Xiao, J; Lu, XF; Wang, J; Wang, X; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Subiao; Xiao, Jing; Lu, Xue Feng; Wang, Jiong; Wang, Xin; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Electrochemical Reduction of CO2 to HCOOH over Sub-2nm SnO2 Quantum Wires with Exposed Grain Boundaries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 could mitigate environmental problems originating from CO2 emission. Although grain boundaries (GBs) have been tailored to tune binding energies of reaction intermediates and consequently accelerate the CO2 reduction reaction (CO2RR), it is challenging to exclusively clarify the correlation between GBs and enhanced reactivity in nullostructured materials with small dimension (<10nm). Now, sub-2nm SnO2 quantum wires (QWs) composed of individual quantum dots (QDs) and numerous GBs on the surface were synthesized and examined for CO2RR toward HCOOH formation. In contrast to SnO2 nulloparticles (NPs) with a larger electrochemically active surface area (ECSA), the ultrathin SnO2 QWs with exposed GBs show enhanced current density (j), an improved Faradaic efficiency (FE) of over 80% for HCOOH and ca. 90% for C1 products as well as energy efficiency (EE) of over 50% in a wide potential window; maximum values of FE (87.3%) and EE (52.7%) are achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2019, "Volume": 58, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8499, "End Page": 8503, "Article Number": null, "DOI": "10.1002/anie.201903613", "DOI Link": "http://dx.doi.org/10.1002/anie.201903613", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476608700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, NC; Montini, T; Zhang, J; Fornasiero, P; Fonda, E; Hou, TT; Nie, W; Lu, JM; Liu, JX; Heggen, M; Lin, L; Ma, CT; Wang, M; Fan, FT; Jin, SY; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Nengchao; Montini, Tiziano; Zhang, Jian; Fornasiero, Paolo; Fonda, Emiliano; Hou, Tingting; Nie, Wei; Lu, Jianmin; Liu, Junxue; Heggen, Marc; Lin, Long; Ma, Changtong; Wang, Min; Fan, Fengtao; Jin, Shengye; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible-light-driven coproduction of diesel precursors and hydrogen from lignocellulose-derived methylfurans", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic hydrogen production from biomass is a promising alternative to water splitting thanks to the oxidation half-reaction being more facile and its ability to simultaneously produce solar fuels and value-added chemicals. Here, we demonstrate the coproduction of H-2 and diesel fuel precursors from lignocellulose-derived methylfurans via acceptorless dehydrogenative C-C coupling, using a Ru-doped ZnIn2S4 catalyst and driven by visible light. With this chemistry, up to 1.04 g g(catalyst)(-1)h(-1) of diesel fuel precursors (similar to 41% of which are precursors of branched-chain alkanes) are produced with selectivity higher than 96%, together with 6.0 mmol g(catalyst)(-1) h(-1) of H-2. Subsequent hydrodeoxygenation reactions yield the desired diesel fuels comprising straight- and branched-chain alkanes. We suggest that Ru dopants, substituted in the position of indium ions in the ZnIn2S4 matrix, improve charge separation efficiency, thereby accelerating C-H activation for the coproduction of H-2 and diesel fuel precursors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 575, "End Page": 584, "Article Number": null, "DOI": "10.1038/s41560-019-0403-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0403-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474920100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YM; Fu, JJ; Zhou, Y; Chang, YC; Min, QH; Zhu, JJ; Lin, YH; Zhu, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yanming; Fu, Jiaju; Zhou, Yang; Chang, Yu-Chung; Min, Qianhao; Zhu, Jun-Jie; Lin, Yuehe; Zhu, Wenlei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) are promising candidates to catalyze electrochemical CO2 reduction (ECR) due to maximized atomic utilization. However, products are usually limited to CO instead of hydrocarbons or oxygenates due to unfavorable high energy barrier for further electron transfer on synthesized single atom catalytic sites. Here we report a novel partial-carbonization strategy to modify the electronic structures of center atoms on SACs for lowering the overall endothermic energy of key intermediates. A carbon-dots-based SAC margined with unique CuN2O2 sites was synthesized for the first time. The introduction of oxygen ligands brings remarkably high Faradaic efficiency (78%) and selectivity (99% of ECR products) for electrochemical converting CO2 to CH4 with current density of 40mA.cm(-2) in aqueous electrolytes, surpassing most reported SACs which stop at two-electron reduction. Theoretical calculations further revealed that the high selectivity and activity on CuN2O2 active sites are due to the proper elevated CH4 and H-2 energy barrier and fine-tuned electronic structure of Cu active sites. Single-atom catalysts (SACs) are promising candidates to catalyze CO2 reduction for the formation of high value hydrocarbons but most of the reactions yield CO. Here, the authors show a low-temperature calcining process to fabricate a carbon-dots-based SAC to efficiently convert CO2 to methane.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 586, "DOI": "10.1038/s41467-020-20769-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20769-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614030100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Adekoya, D; Hencz, L; Ma, J; Chen, S; Yan, C; Zhao, HJ; Cui, GL; Zhang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Adekoya, David; Hencz, Luke; Ma, Jun; Chen, Su; Yan, Cheng; Zhao, Huijun; Cui, Guanglei; Zhang, Shanqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable Seamless Interfaces and Rapid Ionic Conductivity of Ca-CeO2/LiTFSI/PEO Composite Electrolyte for High-Rate and High-Voltage All-Solid-State Battery", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stable and seamless interfaces among solid components in all-solid-state batteries (ASSBs) are crucial for high ionic conductivity and high rate performance. This can be achieved by the combination of functional inorganic material and flexible polymer solid electrolyte. In this work, a flexible all-solid-state composite electrolyte is synthesized based on oxygen-vacancy-rich Ca-doped CeO2 (Ca-CeO2) nullotube, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), and poly(ethylene oxide) (PEO), namely Ca-CeO2/LiTFSI/PEO. Ca-CeO2 nullotubes play a key role in enhancing the ionic conductivity and mechanical strength while the PEO offers flexibility and assures the stable seamless contact between the solid electrolyte and the electrodes in ASSBs. The as-prepared electrolyte exhibits high ionic conductivity of 1.3 x 10(-4) S cm(-1) at 60 degrees C, a high lithium ion transference number of 0.453, and high-voltage stability. More importantly, various electrochemical characterizations and density functional theory (DFT) calculations reveal that Ca-CeO2 helps dissociate LiTFSI, produce free Li ions, and therefore enhance ionic conductivity. The ASSBs based on the as-prepared Ca-CeO2/LiTFSI/PEO composite electrolyte deliver high-rate capability and high-voltage stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 10, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000049, "DOI": "10.1002/aenm.202000049", "DOI Link": "http://dx.doi.org/10.1002/aenm.202000049", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000539283600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aitbekova, A; Wu, LH; Wrasman, CJ; Boubnov, A; Hoffman, AS; Goodman, ED; Bare, SR; Cargnello, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aitbekova, Aisulu; Wu, Liheng; Wrasman, Cody J.; Boubnov, Alexey; Hoffman, Adam S.; Goodman, Emmett D.; Bare, Simon R.; Cargnello, Matteo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Temperature Restructuring of CeO2-Supported Ru nulloparticles Determines Selectivity in CO2 Catalytic Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 reduction to higher value products is a promising way to produce fuels and key chemical building blocks while reducing CO2 emissions. The reaction at atmospheric pressure mainly yields CH4 via methanation and CO via the reverse water-gas shift (RWGS) reaction. Describing catalyst features that control the selectivity of these two pathways is important to determine the formation of specific products. At the same time, identification of morphological changes occurring to catalysts under reaction conditions can be crucial to tune their catalytic performance. In this contribution we investigate the dependency of selectivity for CO2 reduction on the size of Ru nulloparticles (NPs) and on support. We find that even at rather low temperatures (210 degrees C), oxidative pretreatment induces redispersion of Ru NPs supported on CeO2 and leads to a complete switch in the performance of this material from a well-known selective methanation catalyst to an active and selective RWGS catalyst. By utilizing in situ X-ray absorption spectroscopy, we demonstrate that the low-temperature redispersion process occurs via decomposition of the metal oxide phase with size dependent kinetics, producing stable single-site RuOx/CeO2 species strongly bound to the CeO2 support that are remarkably selective for CO production. These results show that reaction selectivity can be heavily dependent on catalyst structure and that structural changes of the catalyst can occur even at low temperatures and can go unseen in materials with less defined structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2018, "Volume": 140, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13736, "End Page": 13745, "Article Number": null, "DOI": "10.1021/jacs.8b07615", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b07615", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448755200037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, LB; Zou, PC; Wang, CY; Jiang, JH; Ma, L; Tan, S; Beyer, KA; Xu, F; Hu, EY; Xin, HLL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Libing; Zou, Peichao; Wang, Chunyang; Jiang, Jiahao; Ma, Lu; Tan, Sha; Beyer, Kevin A.; Xu, Feng; Hu, Enyuan; Xin, Huolin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy and Superstructure-Stabilized Layered Oxide Cathodes for Sodium-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered transition metal oxides are appealing cathodes for sodium-ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high-entropy design with the superlattice-stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as-prepared high-entropy Na2/3Li1/6Fe1/6Co1/6Ni1/6Mn1/3O2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g(-1) at 0.1 C), a high energy density (531 Wh kg(-1)), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast-charging capability (78 mAh g(-1) at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 12, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201989, "DOI": "10.1002/aenm.202201989", "DOI Link": "http://dx.doi.org/10.1002/aenm.202201989", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000851238700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Son, IH; Park, JH; Kwon, S; Park, S; Rümmeli, MH; Bachmatiuk, A; Song, HJ; Ku, J; Choi, JW; Choi, JM; Doo, SG; Chang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Son, In Hyuk; Park, Jong Hwan; Kwon, Soonchul; Park, Seongyong; Ruemmeli, Mark H.; Bachmatiuk, Alicja; Song, Hyun Jae; Ku, Junhwan; Choi, Jang Wook; Choi, Jae-man; Doo, Seok-Gwang; Chang, Hyuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silicon carbide-free graphene growth on silicon for lithium-ion battery with high volumetric energy density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon is receiving discernable attention as an active material for next generation lithium-ion battery anodes because of its unparalleled gravimetric capacity. However, the large volume change of silicon over charge-discharge cycles weakens its competitiveness in the volumetric energy density and cycle life. Here we report direct graphene growth over silicon nulloparticles without silicon carbide formation. The graphene layers anchored onto the silicon surface accommodate the volume expansion of silicon via a sliding process between adjacent graphene layers. When paired with a commercial lithium cobalt oxide cathode, the silicon carbide-free graphene coating allows the full cell to reach volumetric energy densities of 972 and 700 Whl(-1) at first and 200th cycle, respectively, 1.8 and 1.5 times higher than those of current commercial lithium-ion batteries. This observation suggests that two-dimensional layered structure of graphene and its silicon carbide-free integration with silicon can serve as a prototype in advancing silicon anodes to commercially viable technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7393, "DOI": "10.1038/ncomms8393", "DOI Link": "http://dx.doi.org/10.1038/ncomms8393", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175300026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Wei, MF; Mao, HY; Pei, XK; Alshmimri, SA; Reimer, JA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bing; Wei, Mufeng; Mao, Haiyan; Pei, Xiaokun; Alshmimri, Sultan A.; Reimer, Jeffrey A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystalline Dioxin-Linked Covalent Organic Frameworks from Irreversible Reactions", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triangular 2,3,6,7,10,11-hexahydroxytriphenylene (HHTP) and linear tetrafluorophthalonitrile (TFPN) or 2,3,5,6-tetrafluoro-4-pyridinecarbonitrile (TFPC) were linked by 1,4-dioxin linkages to form crystalline 2D covalent organic frameworks, termed COF-316 and -318. Unlike the condensation reactions commonly used to crystallize the great majority of COFs, the reactions used in this report are based on nucleophilic aromatic substitution reactions (SNAr) that are considered irreversible. Our studies show that the reactivity of TFPN and TFPC with HHTP is enhanced by the nitrile substituents leading to facile reactions of planar building units to yield the present 1,4-dioxin linked COFs. Because these reactions are irreversible, the resultant frameworks have high chemical stability in both acid and base. This has led to postsynthetic modifications of COF-316 by reactions necessitating extreme conditions to covalently install functionalities not otherwise accessible. We also report the permanent porosity of these COFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2018, "Volume": 140, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12715, "End Page": 12719, "Article Number": null, "DOI": "10.1021/jacs.8b08374", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b08374", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447354800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, RT; Granqvist, CG; Niklasson, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Rui-Tao; Granqvist, Claes G.; Niklasson, Gunnar A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is keen interest in the use of amorphous WO3 thin films as cathodic electrodes in transmittance-modulating electrochromic devices1-4. However, these films suffer from ion-trapping-induced degradation of optical modulation and reversibility on extended Li+-ion exchange. Here, we demonstrate that ion-trapping-induced degradation, which is commonly believed to be irreversible, can be successfully eliminated by constant-current-driven de-trapping; that is, WO3 films can be rejuvenated and regain their initial highly reversible electrochromic performance. Pronounced ion trapping occurs when x exceeds similar to 0.65 in LixWO3 during ion insertion. We find two main kinds of Li+-ion-trapping site (intermediate and deep) in WO3, where the intermediate ones are most prevalent. Li+ ions can be completely removed from intermediate traps but are irreversibly bound in deep traps. Our results provide a general framework for developing and designing superior electrochromic materials and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 996, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4368", "DOI Link": "http://dx.doi.org/10.1038/NMAT4368", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361771800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Zhu, TX; Li, SH; Huang, JY; Mao, JJ; Yang, H; Gao, SW; Chen, Z; Lai, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yan; Zhu, Tianxue; Li, Shuhui; Huang, Jianying; Mao, Jiajun; Yang, Hui; Gao, Shouwei; Chen, Zhong; Lai, Yuekun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel strategy for fabricating robust superhydrophobic fabrics by environmentally-friendly enzyme etching", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superhydrophobic silk fabrics were prepared using an environmentally friendly enzyme-etching approach, followed by the modification with methyltrichlorosilane (MTCS) via a simple thermal chemical vapor deposition (CVD) process at 70 degrees C. The effects of the concentration, treatment time and temperature of enzyme on the etched surface properties were discussed. The composite superhydrophobic silk fabrics demonstrated excellent self-cleaning ability, relatively unscathed effecting their intrinsic properties such as the luster, softness, color and style of the fabrics. Furthermore, these treated fabrics demonstrated excellent mechanical durability after silane-treatment as evidenced by the cyclic abrasion and laundering tests. The composite superhydrophobic cotton fabrics have also demonstrated a high efficiency in oil-water separation. The facile technology via enzymatic hydrolysis to etch the substrate possesses extensive potential applications on various other cellulose-based substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 355, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 298, "Article Number": null, "DOI": "10.1016/j.cej.2018.08.113", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.08.113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445416900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, H; Zhou, TF; Zheng, Y; Zhang, Q; Liu, YQ; Chen, J; Liu, HK; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Hong; Zhou, Tengfei; Zheng, Yang; Zhang, Qing; Liu, Yuqing; Chen, Jun; Liu, Huakun; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CoS Quantum Dot nulloclusters for High-Energy Potassium-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (PIBs) are a promising alternative to lithium-ion batteries because potassium is an abundant natural resource. To date, PIBs are in the early stages of exploration and only a few anode materials have been investigated. This study reports a cobalt sulfide and graphene (CoS@G) composite as anode electrode for PIBs for the first time. The composite features interconnect quantum dots of CoS nulloclusters uniformly anchored on graphene nullosheets. The coexistence of CoS quantum dot nulloclusters and graphene nullosheets endows the composite with large surface area, highly conductive network, robust structural stability, and excellent electrochemical energy storage performance. An unprecedented capacity of 310.8 mA h g(-1) at 500 mA g(-1) is obtained after 100 cycles, with a rate capability better than an equivalent sodium-ion batteries (SIBs). This work provides the evidence that PIBs can be a promising alternative to SIBs, especially at high charge-discharge rates. The development of the CoS@G anode material also provides the basis of expanding the library of suitable anode materials for PIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2017, "Volume": 27, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702634, "DOI": "10.1002/adfm.201702634", "DOI Link": "http://dx.doi.org/10.1002/adfm.201702634", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416693600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YF; Xu, JK; Ruan, YC; Yu, MK; O'Laughlin, M; Wise, H; Chen, D; Tian, L; Shi, DF; Wang, JL; Chen, SH; Feng, JQ; Chow, DHK; Xie, XH; Zheng, LZ; Huang, L; Huang, S; Leung, K; Lu, N; Zhao, L; Li, HF; Zhao, DW; Guo, X; Chan, KM; Witte, F; Chan, HC; Zheng, YF; Qin, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yifeng; Xu, Jiankun; Ruan, Ye Chun; Yu, Mei Kuen; O'Laughlin, Micheal; Wise, Helen; Chen, Di; Tian, Li; Shi, Dufang; Wang, Jiali; Chen, Sihui; Feng, Jian Q.; Chow, Dick Ho Kiu; Xie, Xinhui; Zheng, Lizhen; Huang, Le; Huang, Shuo; Leung, Kwoksui; Lu, Na; Zhao, Lan; Li, Huafang; Zhao, Dewei; Guo, Xia; Chan, Kaiming; Witte, Frank; Chan, Hsiao Chang; Zheng, Yufeng; Qin, Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Implant-derived magnesium induces local neuronal production of CGRP to improve bone-fracture healing in rats", "Source Title": "NATURE MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Orthopedic implants containing biodegradable magnesium have been used for fracture repair with considerable efficacy; however, the underlying mechanisms by which these implants improve fracture healing remain elusive. Here we show the formation of abundant new bone at peripheral cortical sites after intramedullary implantation of a pin containing ultrapure magnesium into the intact distal femur in rats. This response was accompanied by substantial increases of neuronal calcitonin gene-related polypeptide-alpha (CGRP) in both the peripheral cortex of the femur and the ipsilateral dorsal root ganglia (DRG). Surgical removal of the periosteum, capsaicin denervation of sensory nerves or knockdown in vivo of the CGRP-receptor-encoding genes Cakrl or Ramp1 substantially reversed the magnesium-induced osteogenesis that we observed in this model. Overexpression of these genes, however, enhanced magnesium-induced osteogenesis. We further found that an elevation of extracellular magnesium induces magnesium transporter 1 (MAGT1)-dependent and transient receptor potential cation channel, subfamily M, member 7 (TRPM7)-dependent magnesium entry, as well as an increase in intracellular adenosine triphosphate (ATP) and the accumulation of terminal synaptic vesicles in isolated rat DRG neurons. In isolated rat periosteum-derived stem cells, CGRP induces CALCRL- and RAMP1-dependent activation of cAMP-responsive element binding protein 1 (CREB1) and SP7 (also known as osterix), and thus enhances osteogenic differentiation of these stem cells. Furthermore, we have developed an innovative, magnesium containing intramedullary nail that facilitates femur fracture repair in rats with ovariectomy-induced osteoporosis. Taken together, these findings reveal a previously undefined role of magnesium in promoting CGRP-mediated osteogenic differentiation, which suggests the therapeutic potential of this ion in orthopedics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 771, "Times Cited, All Databases": 849, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 22, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1160, "End Page": 1169, "Article Number": null, "DOI": "10.1038/nm.4162", "DOI Link": "http://dx.doi.org/10.1038/nm.4162", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384872500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharma, L; Katiyar, NK; Parui, A; Das, R; Kumar, R; Tiwary, CS; Singh, AK; Halder, A; Biswas, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharma, Lalita; Katiyar, Nirmal Kumar; Parui, Arko; Das, Rakesh; Kumar, Ritesh; Tiwary, Chandra Sekhar; Singh, Abhisek K.; Halder, Aditi; Biswas, Krishanu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-cost high entropy alloy (HEA) for high-efficiency oxygen evolution reaction (OER)", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction (OER) is the key step involved both in water splitting devices and rechargeable metal-air batteries, and hence, there is an urgent need for a stable and low-cost material for efficient OER. In the present investigation, Co-Fe-Ga-Ni-Zn (CFGNZ) high entropy alloy (HEA) has been utilized as a low-cost electrocatalyst for OER. Herein, after cyclic voltammetry activation, CFGNZ-nulloparticles (NPs) are covered with oxidized surface and form high entropy (oxy) hydroxides (HE0s), exhibiting a low overpotential of 370 mV to achieve a current density of 10 mA/cm(2) with a small Tafel slope of 71 mV/dec. CFGNZ alloy has higher electrochemical stability in comparison to state-of-the art RuO2 electrocatalyst as no degradation has been observed up to 10 h of chronoamperometry. Transmission electron microscopy (TEM) studies after 10 h of long-term chronoamperometry test showed no change in the crystal structure, which confirmed the high stability of CFGNZ. The density functional theory (DFT) based calculations show that the closeness of d(p)-band centers to the Fermi level (E-F) plays a major role in determining active sites.This work highlights the tremendous potential of CFGNZ HEA for OER, which is the primary reaction involved in water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4799, "End Page": 4806, "Article Number": null, "DOI": "10.1007/s12274-021-3802-4", "DOI Link": "http://dx.doi.org/10.1007/s12274-021-3802-4", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694799000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schütt, KT; Sauceda, HE; Kindermans, PJ; Tkatchenko, A; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuett, K. T.; Sauceda, H. E.; Kindermans, P. -J.; Tkatchenko, A.; Mueller, K. -R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "SchNet - A deep learning architecture for molecules and materials", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep learning has led to a paradigm shift in artificial intelligence, including web, text, and image search, speech recognition, as well as bioinformatics, with growing impact in chemical physics. Machine learning, in general, and deep learning, in particular, are ideally suitable for representing quantum-mechanical interactions, enabling us to model nonlinear potential-energy surfaces or enhancing the exploration of chemical compound space. Here we present the deep learning architecture SchNet that is specifically designed to model atomistic systems by making use of continuous-filter convolutional layers. We demonstrate the capabilities of SchNet by accurately predicting a range of properties across chemical space for molecules and materials, where our model learns chemically plausible embeddings of atom types across the periodic table. Finally, we employ SchNet to predict potential-energy surfaces and energy-conserving force fields for molecular dynamics simulations of small molecules and perform an exemplary study on the quantum-mechanical properties of C-20-fullerene that would have been infeasible with regular ab initio molecular dynamics. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1389, "Times Cited, All Databases": 1517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 148, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 241722, "DOI": "10.1063/1.5019779", "DOI Link": "http://dx.doi.org/10.1063/1.5019779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437190300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Kim, M; Lee, MS; Kim, K; Ji, S; Kim, YT; Park, J; Na, K; Bae, KH; Kim, HK; Bien, F; Lee, CY; Park, JU", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Joohee; Kim, Minji; Lee, Mi-Sun; Kim, Kukjoo; Ji, Sangyoon; Kim, Yun-Tae; Park, Jihun; Na, Kyungmin; Bae, Kwi-Hyun; Kim, Hong Kyun; Bien, Franklin; Lee, Chang Young; Park, Jang-Ung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable smart sensor systems integrated on soft contact lenses for wireless ocular diagnostics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable contact lenses which can monitor physiological parameters have attracted substantial interests due to the capability of direct detection of biomarkers contained in body fluids. However, previously reported contact lens sensors can only monitor a single analyte at a time. Furthermore, such ocular contact lenses generally obstruct the field of vision of the subject. Here, we developed a multifunctional contact lens sensor that alleviates some of these limitations since it was developed on an actual ocular contact lens. It was also designed to monitor glucose within tears, as well as intraocular pressure using the resistance and capacitance of the electronic device. Furthermore, in-vivo and in-vitro tests using a live rabbit and bovine eyeball demonstrated its reliable operation. Our developed contact lens sensor can measure the glucose level in tear fluid and intraocular pressure simultaneously but yet independently based on different electrical responses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 763, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14997, "DOI": "10.1038/ncomms14997", "DOI Link": "http://dx.doi.org/10.1038/ncomms14997", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400154000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, Y; Zhang, BL; Sun, RW; Liu, WF; Zhu, QB; Zhang, X; Wang, RR; Chen, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yue; Zhang, Bolun; Sun, Ruowei; Liu, Wenfang; Zhu, Qubo; Zhang, Xun; Wang, Rongrong; Chen, Chuanpin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PLGA-based biodegradable microspheres in drug delivery: recent advances in research and application", "Source Title": "DRUG DELIVERY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biodegradable microspheres have been widely used in the field of medicine due to their ability to deliver drug molecules of various properties through multiple pathways and their advantages of low dose and low side effects. Poly (lactic-co-glycolic acid) copolymer (PLGA) is one of the most widely used biodegradable material currently and has good biocompatibility. In application, PLGA with a specific monomer ratio (lactic acid and glycolic acid) can be selected according to the properties of drug molecules and the requirements of the drug release rate. PLGA-based biodegradable microspheres have been studied in the field of drug delivery, including the delivery of various anticancer drugs, protein or peptide drugs, bacterial or viral DNA, etc. This review describes the basic knowledge and current situation of PLGA biodegradable microspheres and discusses the selection of PLGA polymer materials. Then, the preparation methods of PLGA microspheres are introduced, including emulsification, microfluidic technology, electrospray, and spray drying. Finally, this review summarizes the application of PLGA microspheres in drug delivery and the treatment of pulmonary and ocular-related diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 28, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1397, "End Page": 1418, "Article Number": null, "DOI": "10.1080/10717544.2021.1938756", "DOI Link": "http://dx.doi.org/10.1080/10717544.2021.1938756", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667958800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Billaud, J; Clément, RJ; Armstrong, AR; Canales-Vázquez, J; Rozier, P; Grey, CP; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Billaud, Juliette; Clement, Raphaele J.; Armstrong, A. Robert; Canales-Vazquez, Jesus; Rozier, Patrick; Grey, Clare P.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "β-NaMnO2: A High-Performance Cathode for Sodium-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is much interest in Na-ion batteries for grid storage because of the lower projected cost compared with Li-ion. Identifying Earth-abundant, low-cost, and safe materials that can function as intercalation cathodes in Na-ion batteries is an important challenge facing the field. Here we investigate such a material, beta-NaMnO2, with a different structure from that of NaMnO2 polymorphs and other compounds studied extensively in the past. It exhibits a high capacity (of ca. 190 mA h g(-1) at a rate of C/20), along with a good rate capability (142 mA h g(-1) at a rate of 2C) and a good capacity retention (100 mA h g(-1)after 100 Na extraction/insertion cycles at a rate of 2C). Powder XRD, HRTEM, and Na-23 NMR studies revealed that this compound exhibits a complex structure consisting of intergrown regions of a-NaMnO2 and beta-NaMnO2 domains. The collapse of the long-range structure at low Na content is expected to compromise the reversibility of the Na extraction and insertion processes occurring upon charge and discharge of the cathode material, respectively. Yet stable, reproducible, and reversible Na intercalation is observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2014, "Volume": 136, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17243, "End Page": 17248, "Article Number": null, "DOI": "10.1021/ja509704t", "DOI Link": "http://dx.doi.org/10.1021/ja509704t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346544200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Dong, YC; Yan, TJ; Hu, ZX; Ali, FM; Meira, DM; Duchesne, PN; Loh, JYY; Qiu, CY; Storey, EE; Xu, YF; Sun, W; Ghoussoub, M; Kherani, NP; Helmy, AS; Ozin, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lu; Dong, Yuchan; Yan, Tingjiang; Hu, Zhixin; Ali, Feysal M.; Meira, Debora Motta; Duchesne, Paul N.; Loh, Joel Yi Yang; Qiu, Chenyue; Storey, Emily E.; Xu, Yangfan; Sun, Wei; Ghoussoub, Mireille; Kherani, Nazir P.; Helmy, Amr S.; Ozin, Geoffrey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black indium oxide a photothermal CO2 hydrogenation catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured forms of stoichiometric In2O3 are proving to be efficacious catalysts for the gas-phase hydrogenation of CO2. These conversions can be facilitated using either heat or light; however, until now, the limited optical absorption intensity evidenced by the pale-yellow color of In2O3 has prevented the use of both together. To take advantage of the heat and light content of solar energy, it would be advantageous to make indium oxide black. Herein, we present a synthetic route to tune the color of In2O3 to pitch black by controlling its degree of non-stoichiometry. Black indium oxide comprises amorphous non-stoichiometric domains of In2O3-x on a core of crystalline stoichiometric In2O3, and has 100% selectivity towards the hydrogenation of CO2 to CO with a turnover frequency of 2.44s(-1). The utilization of white-colored, wide-bandgap CO2 hydrogenation photocatalysts has been hindered by their limited light-harvesting ability. By making stoichiometric white indium oxide non-stoichiometric and black, it is transformed from a highly inactive to a highly active photothermal catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2432, "DOI": "10.1038/s41467-020-16336-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16336-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Wu, J; Zhang, T; Wang, YF; Liu, DT; Chen, H; Ji, L; Liu, CH; Ahmad, W; Chen, ZD; Li, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Wu, Jiang; Zhang, Ting; Wang, Yafei; Liu, Detao; Chen, Hao; Ji, Long; Liu, Chunhua; Ahmad, Waseem; Chen, Zhi David; Li, Shibin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite Solar Cells with ZnO Electron-Transporting Materials", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) have developed rapidly over the past few years, and the power conversion efficiency of PSCs has exceeded 20%. Such high performance can be attributed to the unique properties of perovskite materials, such as high absorption over the visible range and long diffusion length. Due to the different diffusion lengths of holes and electrons, electron transporting materials (ETMs) used in PSCs play a critical role in PSCs performance. As an alternative to TiO2 ETM, ZnO materials have similar physical properties to TiO2 but with much higher electron mobility. In addition, there are many simple and facile methods to fabricate ZnO nullomaterials with low cost and energy consumption. This review focuses on recent developments in the use of ZnO ETM for PSCs. The fabrication methods of ZnO materials are briefly introduced. The influence of different ZnO ETMs on performance of PSCs is then reviewed. The limitations of ZnO ETM-based PSCs and some solutions to these challenges are also discussed. The review provides a systematic and comprehensive understanding of the influence of different ZnO ETMs on PSCs performance and potentially motivates further development of PSCs by extending the knowledge of ZnO-based PSCs to TiO2-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2018, "Volume": 30, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703737, "DOI": "10.1002/adma.201703737", "DOI Link": "http://dx.doi.org/10.1002/adma.201703737", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429097600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YH; Yu, XY; Fang, YJ; Zhu, XS; Bao, JC; Zhou, XS; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuhan; Yu, Xin-Yao; Fang, Yongjin; Zhu, Xiaoshu; Bao, Jianchun; Zhou, Xiaosi; Lou, Xiong Wen David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confining SnS2 Ultrathin nullosheets in Hollow Carbon nullostructures for Efficient Capacitive Sodium Storage", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin disulfide (SnS2) is a promising anode material for sodium-ion batteries because of its high specific capacity. However, the low conductivity and large volume change during reaction with Na+ ions greatly limit its practical application. Herein, a multistep templating method has been exploited for the rational design and synthesis of SnS2 nullosheets confined in carbon nullotubes (SnS2@CNTs). To demonstrate the universality of this method, SnS2 nullosheets confined in carbon nulloboxes (SnS2@CNBs) and hollow carbon nullospheres (SnS2@CNSs) have also been synthesized by simply changing the template in the reaction system. Due to their unique structural merits, the SnS2@CNTs, SnS2@CNBs, and SnS2@CNSs show improved sodium storage performance in terms of high specific capacity, good cycling stability, and superior rate capability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 725, "End Page": 735, "Article Number": null, "DOI": "10.1016/j.joule.2018.01.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.01.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435091900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, SY; Li, XG; Li, LY; Wei, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Shuyan; Li, Xiaoge; Li, Lingyu; Wei, Xianjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A versatile biomass derived carbon material for oxygen reduction reaction, supercapacitors and oil/water separation", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Directly pyrolyzing biowastes has attracted intensive interest, probably because this economical and facile method provides an efficient and versatile platform for synthesizing functional carbons. This study describes the synthesis of different functional carbons from poplar catkins via different processes for multi-purpose applications. Nitrogen and oxygen dual-doped carbon (NODC-800) derived from catkins delivers superior electrochemical characteristics as oxygen reduction reaction (ORR) catalyst in alkaline fuel cell to that of commercial Pt/C in terms of catalytic activity, stability, resistance to methanol cross-over and CO poisoning. In addition, NODC-800 exhibits a high capacity (similar to 251 F g(-1) at 0.5 A g(-1)) with nearly 100% retention rate after 1000 cycles as supercapacitors electrodes. An oleophylic carbon aerogel derived from catkins is proven to be superoleophilic and porous enough to wet with oils and organic liquids and repel water completely to achieve oil/water separation. This work is a successful case to take full advantage of raw materials from nature via multiple technologies to achieve energy sustainable development and protect environmental from oils and organic solvents spill.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 334, "End Page": 342, "Article Number": null, "DOI": "10.1016/j.nulloen.2017.01.045", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2017.01.045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397314200037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharma, RK; Ganesan, P; Tyagi, VV; Metselaar, HSC; Sandaran, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharma, R. K.; Ganesan, P.; Tyagi, V. V.; Metselaar, H. S. C.; Sandaran, S. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developments in organic solid-liquid phase change materials and their applications in thermal energy storage", "Source Title": "ENERGY CONVERSION AND MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal energy storage as sensible or latent heat is an efficient way to conserve the waste heat and excess energy available such as solar radiation. Storage of latent heat using organic phase change materials (PCMs) offers greater energy storage density over a marginal melting and freezing temperature difference in comparison to inorganic materials. These favorable characteristics of organic PCMs make them suitable in a wide range of applications. These materials and their eutectic mixtures have been successfully tested and implemented in many domestic and commercial applications such as, building, electronic devices, refrigeration and air-conditioning, solar air/water heating, textiles, automobiles, food, and space industries. This review focuses on three aspects: the materials, encapsulation and applications of organic PCMs, and provides an insight on the recent developments in applications of these materials. Organic PCMs have inherent characteristic of low thermal conductivity (0.15-0.35 W/m K), hence, a larger surface area is required to enhance the heat transfer rate. Therefore, attention is also given to the thermal conductivity enhancement of the materials, which helps to keep the area of the system to a minimum. Besides, various available techniques for material characterization have also been discussed. It has been found that a wide range of the applications of organic PCMs in buildings and other low and medium temperature solar energy applications are in abundant use but these materials are not yet popular among space applications and virtual data storage media. In addition, it has also been observed that because of the low melting point of organic PCMs, they have not yet been explored for high temperature applications such as in power plants. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 619, "Times Cited, All Databases": 680, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2015, "Volume": 95, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": 228, "Article Number": null, "DOI": "10.1016/j.enconman.2015.01.084", "DOI Link": "http://dx.doi.org/10.1016/j.enconman.2015.01.084", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352169300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, XF; Cao, BQ; Yuan, S; Chen, XF; Qiu, ZW; Jiang, YA; Ye, Q; Wang, HQ; Zeng, HB; Liu, J; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Xiaofeng; Cao, Bingqiang; Yuan, Shuai; Chen, Xiangfeng; Qiu, Zhiwen; Jiang, Yanull; Ye, Qian; Wang, Hongqiang; Zeng, Haibo; Liu, Jian; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From unstable CsSnI3 to air-stable Cs2SnI6: A lead-free perovskite solar cell light absorber with bandgap of 1.48 eV and high absorption coefficient", "Source Title": "SOLAR ENERGY MATERIALS AND SOLAR CELLS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic and lead-free cesium tin halides (CsSnX3, X=Cl, Br, I) are highly desirable for substituting the organolead halide perovskite solar cells. However, the poor stability of CsSnX3 perovskites has so far prevented the fabrication of devices that can withstand sustained operation under normal conditions. In this paper, a two-step sequential deposition method is developed to grow high-quality B-gamma-CsSnI3 thin films and their unique phase change in atmosphere is explored in detail. We find the spontaneous oxidative conversion from unstable B-gamma-CsSnI3 to air-stable Cs2SnI6 in air. Allowing the phase conversion of the CsSnI3 film to evolve in ambient air it gives the semiconducting perovskite Cs2SnI6 with a bandgap of 1.48 eV and high absorption coefficient (over 10(5) cm(-1) from 1.7 eV). More importantly, the Cs2SnI6 film, for the first time, is adopted as a light absorber layer for a lead-free perovskite solar cell and a preliminary estimate of the power conversion efficiency (PCE) about 1% with open-circuit voltage of 0.51 V and short-circuit current of 5.41 mA/cm(2) is realized by optimizing the perovskite absorber thickness. According to the bandgap and the Shockley-Queisser limit, such inorganic perovskite solar cell with higher efficiency and pronounced stability can be expected by material quality improvement and device engineering. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 159, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 234, "Article Number": null, "DOI": "10.1016/j.solmat.2016.09.022", "DOI Link": "http://dx.doi.org/10.1016/j.solmat.2016.09.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388053600027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Si, YF; Dong, ZC; Jiang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Si, Yifan; Dong, Zhichao; Jiang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired Designs of Superhydrophobic and Superhydrophilic Materials", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioinspired designs of superhydrophobic and superhydrophilic materials have been an important and fascinating area of research in recent years for their extensive potential application prospects from industry to our daily life. Despite extensive progress, existing research achievements are far from real applications. From biomimetic performance to service life, the related research has faced serious problems at present. A timely outlook is therefore necessary to summarize the existing research, to discuss the challenges faced, and to propose constructive advice for the ongoing scientific trend. Here, we comb the process of development of bioinspired superhydrophobic and superhydrophilic materials at first. Then, we also describe how to design artificial superhydrophobic and superhydrophilic materials. Furthermore, current challenges faced by bioinspired designs of superhydrophobic and superhydrophilic materials are pointed out, separately, and the possible solutions are discussed. Emerging applications in this field are also briefly considered. Finally, the development trend within this field is highlighted to lead future research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2018, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1102, "End Page": 1112, "Article Number": null, "DOI": "10.1021/acscentsci.8b00504", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.8b00504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445724800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LZ; Jia, Y; Gao, GP; Yan, XC; Chen, N; Chen, J; Soo, MT; Wood, B; Yang, DJ; Du, AJ; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Longzhou; Jia, Yi; Gao, Guoping; Yan, Xuecheng; Chen, Ning; Chen, Jun; Soo, Mun Teng; Wood, Barry; Yang, Dongjiang; Du, Aijun; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Downsizing the catalyst to atomic scale provides an effective way to maximize the atom efficiency and enhance activity for electrocatalysis. Here, we report a concept whereby graphene defects trap atomic Ni species (aNi) inside to form an integrity (aNi@defect). X-ray adsorption characterization and density-functional-theory calculation revealed that the diverse defects in graphene can induce different local electronic densities of state (DOSs) of aNi, which suggests that aNi@defect serves as an active site for unique electrocatalytic reactions. As examples, aNi@G585 is responsible for the oxygen evolution reaction (OER), and aNi@G5775 activates the hydrogen evolution reaction (HER). The derived catalyst exhibits exceptionally good activity for both HER and OER, e.g., an overpotential of 70 mV at 10 mA/cm(2) for HER (analogous to the commercial Pt/C) and 270 mV at 10 mA/cm(2) for OER (much superior to that of Ir oxide).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 646, "Times Cited, All Databases": 663, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 285, "End Page": 297, "Article Number": null, "DOI": "10.1016/j.chempr.2017.12.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.12.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429434000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, Z; Lin, DC; Zhao, J; Lu, ZD; Liu, YY; Liu, C; Lu, YY; Wang, HT; Yan, K; Tao, XY; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Zheng; Lin, Dingchang; Zhao, Jie; Lu, Zhenda; Liu, Yayuan; Liu, Chong; Lu, Yingying; Wang, Haotian; Yan, Kai; Tao, Xinyong; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal-based battery is considered one of the best energy storage systems due to its high theoretical capacity and lowest anode potential of all. However, dendritic growth and virtually relative infinity volume change during long-term cycling often lead to severe safety hazards and catastrophic failure. Here, a stable lithium-scaffold composite electrode is developed by lithium melt infusion into a 3D porous carbon matrix with lithiophilic coating. Lithium is uniformly entrapped on the matrix surface and in the 3D structure. The resulting composite electrode possesses a high conductive surface area and excellent structural stability upon galvanostatic cycling. We showed stable cycling of this composite electrode with small Li plating/stripping overpotential (<90 mV) at a high current density of 3 mA/cm(2) over 80 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 764, "Times Cited, All Databases": 849, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2016, "Volume": 113, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2862, "End Page": 2867, "Article Number": null, "DOI": "10.1073/pnas.1518188113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1518188113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372014200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fagan, R; McCormack, DE; Dionysiou, DD; Pillai, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fagan, Rachel; McCormack, Declan E.; Dionysiou, Dionysios D.; Pillai, Suresh C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A review of solar and visible light active TiO2 photocatalysis for treating bacteria, cyanotoxins and contaminullts of emerging concern", "Source Title": "MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research into the development of solar and visible light active photocatalysts has been significantly increased in recent years due to its wide range of applications in treating contaminullts of emerging concern (CECs), endocrine disrupting compounds (EDCs), bacteria and cyanotoxins. Solar photocatalysis is found to be highly effective in treating a wide range of CECs from sources such as pharmaceuticals, steroids, antibiotics, phthalates, disinfectants, pesticides, fragrances (musk), preservatives and additives. Similarly, a number of EDCs including polycyclic aromatic hydrocarbons (PAHs), alkylphenols (APs), bisphenol A (BPA), organotins (OTs), volatile organic compounds (VOCs), natural and synthetic estrogenic and androgenic chemicals, pesticides, and heavy metals can be removed from contaminated water by using solar photocatalysis. Photocatalysis was also found effective in treating a wide range of bacteria such as Staphylococcus aureus, Bacillus subtilis, Escherichia coli, Salmonella typhi and Micrococcus lylae. The current review also compares the effectiveness of various visible light activated TiO2 photocatalysts for treating these pollutants. Doping or co-doping of TiO2 using nitrogen, nitrogen-silver, sulphur, carbon, copper and also incorporation of graphene nullo-sheets are discussed. The use of immobilised TiO2 for improving the photocatalytic activity is also presented. Decorating titania photocatalyst with graphene oxide (GO) is of particular interest due to GO's ability to increase the photocatalytic activity of TiO2. The use GO to increase the photocatalytic activity of TiO2 against microcystin-LR (MC-LR) under UV-A and solar irciation is discussed. The enhanced photocatalytic activity of GO-TiO2 compared to the control material is attributed to the effective inhibition of the electron-hole recombination by controlling the interfacial charge transfer process. It is concluded that there is a critical need for further improvement of the efficiency of these materials if they are to be considered for bulk industrial use. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 42, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 2, "End Page": 14, "Article Number": null, "DOI": "10.1016/j.mssp.2015.07.052", "DOI Link": "http://dx.doi.org/10.1016/j.mssp.2015.07.052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367638100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZY; Zhang, ZZ; Zhang, N; Gao, WX; Li, J; Pu, YJ; He, B; Xie, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhaoyuan; Zhang, Zhuangzhuang; Zhang, null; Gao, Wenxia; Li, Jing; Pu, Yuji; He, Bin; Xie, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Mg2+/polydopamine composite hydrogel for the acceleration of infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial infection is a vital factor to delay the wound healing process. The antibiotics abuse leads to drug resistance of some pathogenic bacteria. Non-antibiotic-dependent multifunctional biomaterials with accelerated wound healing performance are urgently desired. Herein, we reported a composite antibacterial hydrogel PDA-PAM/Mg2+ that shows excellent self-healing and tissue adhesive property, and photothermal antibacterial functions for accelerating wound healing. The gel was composed of polyacrylamide (PAM), polydopamine (PDA), and magnesium (Mg2+) and prepared via a two-step procedure: an alkali-induced dopamine pre-polymerization and followed radical polymerization process. The composite gel shows excellent tissue adhesiveness and Mg2+ synergized photothermal antibacterial activity, inducing a survival rate of 5.29% for S. aureus and 7.06% for E. coli after near infrared light irradiation. The composite hydrogel further demonstrated efficient bacteria inhibition, enhanced wound healing and collagen deposition in a full-thickness skin defect rat model. Together, the PDA-PAM/Mg2+ hydrogel presents an excellent wound dressing with excellent tissue adhesion, wound healing, and antibacterial functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 15, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 203, "End Page": 213, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.11.036", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.11.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787533900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Urbankowski, P; Anasori, B; Hantanasirisakul, K; Yang, L; Zhang, LH; Haines, B; May, SJ; Billinge, SJL; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Urbankowski, Patrick; Anasori, Babak; Hantanasirisakul, Kanit; Yang, Long; Zhang, Lihua; Haines, Bernard; May, Steven J.; Billinge, Simon J. L.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a rapidly growing class of 2D transition metal carbides and nitrides, finding applications in fields ranging from energy storage to electromagnetic interference shielding and transparent conductive coatings. However, while more than 20 carbide MXenes have already been synthesized, Ti4N3 and Ti2N are the only nitride MXenes reported so far. Here by ammoniation of Mo2CTx and V2CTx MXenes at 600 degrees C, we report on their transformation to 2D metal nitrides. Carbon atoms in the precursor MXenes are replaced with N atoms, resulting from the decomposition of ammonia molecules. The crystal structures of the resulting Mo2N and V2N were determined with transmission electron microscopy and X-ray pair distribution function analysis. Our results indicate that Mo2N retains the MXene structure and V2C transforms to a mixed layered structure of trigonal V2N and cubic VN. Temperature-dependent resistivity measurements of the nitrides reveal that they exhibit metallic conductivity, as opposed to semiconductor-like behavior of their parent carbides. As important, room-temperature electrical conductivity values of Mo2N and V2N are three and one order of magnitude larger than those of the Mo2CTx and V2CTx precursors, respectively. This study shows how gas treatment synthesis such as ammoniation can transform carbide MXenes into 2D nitrides with higher electrical conductivities and metallic behavior, opening a new avenue in 2D materials synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2017, "Volume": 9, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17722, "End Page": 17730, "Article Number": null, "DOI": "10.1039/c7nr06721f", "DOI Link": "http://dx.doi.org/10.1039/c7nr06721f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416825000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Christians, JA; Herrera, PAM; Kamat, PV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Christians, Jeffrey A.; Miranda Herrera, Pierre A.; Kamat, Prashant V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transformation of the Excited State and Photovoltaic Efficiency of CH3NH3PbI3 Perovskite upon Controlled Exposure to Humidified Air", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Humidity has been an important factor, in both negative and positive ways, in the development of perovskite solar cells and will prove critical in the push to commercialize this exciting new photovoltaic technology. The interaction between CH3NH3PbI3 and H2O vapor is investigated by characterizing the ground-state and excited-state optical absorption properties and probing morphology and crystal structure. These undertakings reveal that H2O exposure does not simply cause CH3NH3PbI3 to revert to PbI2. It is shown that, in the dark, H2O is able to complex with the perovskite, forming a hydrate product similar to (CH3NH3)4PbI(6)center dot 2H(2)O. This causes a decrease in absorption across the visible region of the spectrum and a distinct change in the crystal structure of the material. Femtosecond transient absorption spectroscopic measurements show the effect that humidity has on the ultrafast excited state dynamics of CH3NH3PbI3. More importantly, the deleterious effects of humidity on complete solar cells, specifically on photovoltaic efficiency and stability, are explored in the light of these spectroscopic understandings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1173, "Times Cited, All Databases": 1275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2015, "Volume": 137, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1530, "End Page": 1538, "Article Number": null, "DOI": "10.1021/ja511132a", "DOI Link": "http://dx.doi.org/10.1021/ja511132a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349138600027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FC; Zheng, SJ; He, XX; Chaturvedi, A; He, JF; Chow, WL; Mion, TR; Wang, XL; Zhou, JD; Fu, QD; Fan, HJ; Tay, BK; Song, L; He, RH; Kloc, C; Ajayan, PM; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fucai; Zheng, Shoujun; He, Xuexia; Chaturvedi, Apoorva; He, Junfeng; Chow, Wai Leong; Mion, Thomas R.; Wang, Xingli; Zhou, Jiadong; Fu, Qundong; Fan, Hong Jin; Tay, Beng Kang; Song, Li; He, Rui-Hua; Kloc, Christian; Ajayan, Pulickel M.; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Sensitive Detection of Polarized Light Using Anisotropic 2D ReS2", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the novel optical and optoelectronic properties, 2D materials have received increasing interests for optoelectronics applications. Discovering new properties and functionalities of 2D materials is challenging yet promising. Here broadband polarization sensitive photodetectors based on few layer ReS2 are demonstrated. The transistor based on few layer ReS2 shows an n-type behavior with the mobility of about 40 cm(2) V-1 s(-1) and on/off ratio of 10(5). The polarization dependence of photoresponse is ascribed to the unique anisotropic in-plane crystal structure, consistent with the optical absorption anisotropy. The linear dichroic photodetection with a high photoresponsivity reported here demonstrates a route to exploit the intrinsic anisotropy of 2D materials and the possibility to open up new ways for the applications of 2D materials for light polarization detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2016, "Volume": 26, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1169, "End Page": 1177, "Article Number": null, "DOI": "10.1002/adfm.201504546", "DOI Link": "http://dx.doi.org/10.1002/adfm.201504546", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371078100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Yang, YF; Boyle, DT; Jeong, YK; Xu, R; de Vasconcelos, LS; Huang, ZJ; Wang, HS; Wang, HX; Huang, WX; Li, HQ; Wang, JY; Gu, HK; Matsumoto, R; Motohashi, K; Nakayama, Y; Zhao, KJ; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Yang, Yufei; Boyle, David T.; Jeong, You Kyeong; Xu, Rong; de Vasconcelos, Luize Scalco; Huang, Zhuojun; Wang, Hansen; Wang, Hongxia; Huang, Wenxiao; Li, Huiqiao; Wang, Jiangyan; Gu, Hanke; Matsumoto, Ryuhei; Motohashi, Kazunari; Nakayama, Yuri; Zhao, Kejie; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Free-standing ultrathin lithium metal-graphene oxide host foils with controllable thickness for lithium batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thin (<= 20 mu m) and free-standing Li metal foils would enable precise prelithiation of anode materials and high-energy-density Li batteries. Existing Li metal foils are too thick (typically 50 to 750 mu m) or too mechanically fragile for these applications. Here, we developed a facile and scalable process for the synthesis of an ultrathin (0.5 to 20 mu m), free-standing and mechanically robust Li metal foil within a graphene oxide host. In addition to low areal capacities of similar to 0.1 to 3.7 mAh cm(-2), this Li foil also has a much-improved mechanical strength over conventional pure Li metal foil. Our Li foil can improve the initial Coulombic efficiency of graphite (93%) and silicon (79.4%) anodes to around 100% without generating excessive Li residue, and increases the capacity of Li-ion full cells by 8%. The cycle life of Li metal full cells is prolonged by nine times using this thin Li composite anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 790, "End Page": 798, "Article Number": null, "DOI": "10.1038/s41560-021-00833-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00833-6", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652456000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blomgren, GE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blomgren, George E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Development and Future of Lithium Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This year, the battery industry celebrates the 25th anniversary of the introduction of the lithium ion rechargeable battery by Sony Corporation. The discovery of the system dates back to earlier work by Asahi Kasei in Japan, which used a combination of lower temperature carbons for the negative electrode to prevent solvent degradation and lithium cobalt dioxide modified somewhat from Goodenough's earlier work. The development by Sony was carried out within a few years by bringing together technology in film coating from their magnetic tape division and electrochemical technology from their battery division. The past 25 years has shown rapid growth in the sales and in the benefits of lithium ion in comparison to all the earlier rechargeable battery systems. Recent work on new materials shows that there is a good likelihood that the lithium ion battery will continue to improve in cost, energy, safety and power capability and will be a formidable competitor for some years to come. (C) The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1428, "Times Cited, All Databases": 1596, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 164, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A5019", "End Page": "A5025", "Article Number": null, "DOI": "10.1149/2.0251701jes", "DOI Link": "http://dx.doi.org/10.1149/2.0251701jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394508400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, MM; Bai, Y; Zeiske, S; Ren, L; Liu, JX; Yuan, YB; Zarrabi, N; Cheng, NY; Ghasemi, M; Chen, P; Lyu, MQ; He, DX; Yun, JH; Du, Y; Wang, Y; Ding, SS; Armin, A; Meredith, P; Liu, G; Cheng, HM; Wang, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Mengmeng; Bai, Yang; Zeiske, Stefan; Ren, Long; Liu, Junxian; Yuan, Yongbo; Zarrabi, Nasim; Cheng, Ningyan; Ghasemi, Mehri; Chen, Peng; Lyu, Miaoqiang; He, Dongxu; Yun, Jung-Ho; Du, Yi; Wang, Yun; Ding, Shanshan; Armin, Ardalan; Meredith, Paul; Liu, Gang; Cheng, Hui-Ming; Wang, Lianzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand-assisted cation-exchange engineering for high-efficiency colloidal Cs1-xFAxPbI3 quantum dot solar cells with reduced phase segregation", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixed-cation perovskite quantum dot solar cells possess decent phase stability but considerably low efficiency. Here Hao et al. show that ligands are key to the formation of quantum dots with lower defect density and demonstrate devices that are more stable and efficient than their bulk counterparts. The mixed caesium and formamidinium lead triiodide perovskite system (Cs(1-x)FA(x)PbI(3)) in the form of quantum dots (QDs) offers a pathway towards stable perovskite-based photovoltaics and optoelectronics. However, it remains challenging to synthesize such multinary QDs with desirable properties for high-performance QD solar cells (QDSCs). Here we report an effective oleic acid (OA) ligand-assisted cation-exchange strategy that allows controllable synthesis of Cs(1-x)FA(x)PbI(3) QDs across the whole composition range (x = 0-1), which is inaccessible in large-grain polycrystalline thin films. In an OA-rich environment, the cross-exchange of cations is facilitated, enabling rapid formation of Cs(1-x)FA(x)PbI(3) QDs with reduced defect density. The hero Cs(0.5)FA(0.5)PbI(3) QDSC achieves a certified record power conversion efficiency (PCE) of 16.6% with negligible hysteresis. We further demonstrate that the QD devices exhibit substantially enhanced photostability compared with their thin-film counterparts because of suppressed phase segregation, and they retain 94% of the original PCE under continuous 1-sun illumination for 600 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 79, "End Page": 88, "Article Number": null, "DOI": "10.1038/s41560-019-0535-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0535-7", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508323000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, DY; Lopes, PP; Martins, PFBD; He, HY; Kawaguchi, T; Zapol, P; You, HD; Tripkovic, D; Strmcnik, D; Zhu, YS; Seifert, S; Lee, SS; Stamenkovic, VR; Markovic, NM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Dong Young; Lopes, Pietro P.; Martins, Pedro Farinazzo Bergamo Dias; He, Haiying; Kawaguchi, Tomoya; Zapol, Peter; You, Hoydoo; Tripkovic, Dusan; Strmcnik, Dusan; Zhu, Yisi; Seifert, Soenke; Lee, Sungsik; Stamenkovic, Vojislav R.; Markovic, Nenad M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H-2 production. Here, by studying the activity-stability trends for the oxygen evolution reaction on conductive (MOxHy)-O-1, Fe-(MOxHy)-O-1 and Fe-(MMOxHy)-M-1-O-2 hydr(oxy)oxide clusters (M-1 = Ni, Co, Fe; M-2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe-M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces. Understanding what underpins the activity and stability of oxygen evolution catalysts is an ongoing issue in the field of water splitting. Now, researchers show that balancing the rate of Fe dissolution and deposition over a metal hydr(oxy)oxide host yields dynamically stable Fe active sites, with the Fe-host interaction key to the performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 690, "Times Cited, All Databases": 711, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": 230, "Article Number": null, "DOI": "10.1038/s41560-020-0576-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0576-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520704000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XW; Chen, X; Hong, H; Hu, RB; Liu, JS; Liu, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xuewei; Chen, Xi; Hong, Hua; Hu, Rubei; Liu, Jiashang; Liu, Changsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decellularized extracellular matrix scaffolds: Recent trends and emerging strategies in tissue engineering", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of scaffolding materials is believed to hold enormous potential for tissue regeneration. Despite the widespread application and rapid advance of several tissue-engineered scaffolds such as natural and synthetic polymer-based scaffolds, they have limited repair capacity due to the difficulties in overcoming the immunogenicity, simulating in-vivo microenvironment, and performing mechanical or biochemical properties similar to native organs/tissues. Fortunately, the emergence of decellularized extracellular matrix (dECM) scaffolds provides an attractive way to overcome these hurdles, which mimic an optimal non-immune environment with native three-dimensional structures and various bioactive components. The consequent cell-seeded construct based on dECM scaffolds, especially stem cell-recellularized construct, is considered an ideal choice for regenerating functional organs/tissues. Herein, we review recent developments in dECM scaffolds and put forward perspectives accordingly, with particular focus on the concept and fabrication of decellularized scaffolds, as well as the application of decellularized scaffolds and their combinations with stem cells (recellularized scaffolds) in tissue engineering, including skin, bone, nerve, heart, along with lung, liver and kidney.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 507, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15, "End Page": 31, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.09.014", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.09.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000743258200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Garza, AJ; Bell, AT; Head-Gordon, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garza, Alejandro J.; Bell, Alexis T.; Head-Gordon, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of CO2 Reduction at Copper Surfaces: Pathways to C2 Products", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On the basis of constraints from reported experimental observations and density functional theory simulations, we propose a mechanism for the reduction of CO2 to C-2 products on copper electrodes. To model the effects of an applied potential bias on the reactions, calculations are carried out with a variable, fractional number of electrons on the unit cell, which is optimized so that the Fermi level matches the actual chemical potential of electrons (i.e., the applied bias); an implicit electrolyte model allows for compensation of the surface charge so that neutrality is maintained in the overall simulation cell. Our mechanism explains the presence of the seven C-2 species that have been detected in the reaction, as well as other notable experimental observations. Furthermore, our results shed light on the difference in activities toward C-2 products between the (100) and (111) facets of copper. We compare our methodologies and findings with those in other recent mechanistic studies of the copper-catalyzed CO2 reduction reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 699, "Times Cited, All Databases": 762, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1490, "End Page": 1499, "Article Number": null, "DOI": "10.1021/acscatal.7b03477", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b03477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424735000093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, ZH; Sun, HM; Chen, X; Liu, HH; Zhao, YR; Li, HX; Xie, W; Cheng, FY; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Zhenhua; Sun, Hongming; Chen, Xiang; Liu, Huanhuan; Zhao, Yaran; Li, Haixia; Xie, Wei; Cheng, Fangyi; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion insertion enhanced electrodeposition of robust metal hydroxide/oxide electrodes for oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical deposition is a facile strategy to prepare functional materials but suffers from limitation in thin films and uncontrollable interface engineering. Here we report a universal electrosynthesis of metal hydroxides/oxides on varied substrates via reduction of oxyacid anions. On graphitic substrates, we find that the insertion of nitrate ion in graphene layers significantly enhances the electrodeposit-support interface, resulting in high mass loading and super hydrophilic/aerophobic properties. For the electrocatalytic oxygen evolution reaction, the nullocrystalline cerium dioxide and amorphous nickel hydroxide co-electrodeposited on graphite exhibits low overpotential (177 mV@10 mA cm(-2)) and sustains long-term durability (over 300 h) at a large current density of 1000 mA cm(-2). In situ Raman and operando X-ray diffraction unravel that the integration of cerium promotes the formation of electrocatalytically active gamma-phase nickel oxyhydroxide with exposed (003) facets. Therefore, combining anion intercalation with cathodic electrodeposition allows building robust electrodes with high electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2373, "DOI": "10.1038/s41467-018-04788-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04788-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435453200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZQ; Chen, YG; Zhou, LQ; Chen, C; Han, Z; Zhang, BS; Wu, Q; Yang, LJ; Du, LY; Bu, YF; Wang, P; Wang, XZ; Yang, H; Hu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhiqi; Chen, Yugang; Zhou, Liqi; Chen, Chi; Han, Zhen; Zhang, Bingsen; Wu, Qiang; Yang, Lijun; Du, Lingyu; Bu, Yongfeng; Wang, Peng; Wang, Xizhang; Yang, Hui; Hu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-site catalysts feature high catalytic activity but their facile construction and durable utilization are highly challenging. Herein, we report a simple impregnation-adsorption method to construct platinum single-site catalysts by synergic micropore trapping and nitrogen anchoring on hierarchical nitrogen-doped carbon nullocages. The optimal catalyst exhibits a record-high electrocatalytic hydrogen evolution performance with low overpotential, high mass activity and long stability, much superior to the platinum-based catalysts to date. Theoretical simulations and experiments reveal that the micropores with edge-nitrogendopants favor the formation of isolated platinum atoms by the micropore trapping and nitrogen anchoring of [PtCI6](2-), followed by the spontaneous dechlorination. The platinum-nitrogen bonds are more stable than the platinum-carbon ones in the presence of adsorbed hydrogen atoms, leading to the superior hydrogen evolution stability of platinum single-atoms on nitrogen-doped carbon. This method has been successfully applied to construct the single-site catalysts of other precious metals such as palladium, gold and iridium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1657, "DOI": "10.1038/s41467-019-09596-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09596-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463984400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Richards, WD; Miara, LJ; Wang, Y; Kim, JC; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Richards, William D.; Miara, Lincoln J.; Wang, Yan; Kim, Jae Chul; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Stability in Solid-State Batteries", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of high conductivity solid-state electrolytes for lithium ion batteries has proceeded rapidly in recent years, but incorporating these new materials into high-performing batteries has proven difficult. Interfacial resistance is now the limiting factor in many systems, but the exact mechanisms of this resistance have not been fully explained in part because experimental evaluation of the interface can be very difficult. In this work, we develop a computational methodology to examine the thermodynamics of formation of resistive interfacial phases. The predicted interfacial phase formation is well correlated with experimental interfacial observations and battery performance. We calculate that thiophosphate electrolytes have especially high reactivity with high voltage cathodes and a narrow electrochemical stability window. We also find that a number of known electrolytes are not inherently stable but react in situ with the electrode to form passivating but ionically conducting barrier layers. As a reference for experimentalists, we tabulate the stability and expected decomposition products for a wide range of electrolyte, coating, and electrode materials including a number of high-performing combinations that have not yet been attempted experimentally.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1245, "Times Cited, All Databases": 1374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2016, "Volume": 28, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 266, "End Page": 273, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b04082", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b04082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368322600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZF; Bommier, C; Sen Chong, Z; Jian, ZL; Surta, TW; Wang, XF; Xing, ZY; Neuefeind, JC; Stickle, WF; Dolgos, M; Greaney, PA; Ji, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhifei; Bommier, Clement; Sen Chong, Zhi; Jian, Zelang; Surta, Todd Wesley; Wang, Xingfeng; Xing, Zhenyu; Neuefeind, Joerg C.; Stickle, William F.; Dolgos, Michelle; Greaney, P. Alex; Ji, Xiulei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of Na-Ion Storage in Hard Carbon Anodes Revealed by Heteroatom Doping", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard carbon is the leading candidate anode for commercialization of Na-ion batteries. Hard carbon has a unique local atomic structure, which is composed of nullodomains of layered rumpled sheets that have short-range local order resembling graphene within each layer, but complete disorder along the c-axis between layers. A primary challenge holding back the development of Na-ion batteries is that a complete understanding of the structure-capacity correlations of Na-ion storage in hard carbon has remained elusive. This article presents two key discoveries: first, the characteristics of hard carbons structure can be modified systematically by heteroatom doping, and second, that these structural changes greatly affect Na-ion storage properties, which reveals the mechanisms for Na storage in hard carbon. Specifically, via P or S doping, the interlayer spacing is dilated, which extends the low-voltage plateau capacity, while increasing the defect concentrations with P or B doping leads to higher sloping sodiation capacity. The combined experimental studies and first principles calculations reveal that it is the Na-ion-defect binding that corresponds to the sloping capacity, while the Na intercalation between graphenic layers causes the low-potential plateau capacity. The understanding suggests a new design principle of hard carbon anode: more reversibly binding defects and dilated turbostratic domains, given that the specific surface area is maintained low.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2017, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1602894, "DOI": "10.1002/aenm.201602894", "DOI Link": "http://dx.doi.org/10.1002/aenm.201602894", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411182500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Y; Rojas, T; Wang, K; Liu, S; Wang, DW; Chen, TH; Wang, HY; Ngo, AT; Wang, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yue; Rojas, Tomas; Wang, Ke; Liu, Shuai; Wang, Daiwei; Chen, Tianhang; Wang, Haiying; Ngo, Anh T.; Wang, Donghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-temperature and high-rate-charging lithium metal batteries enabled by an electrochemically active monolayer-regulated interface", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stable operation of rechargeable lithium-based batteries at low temperatures is important for cold-climate applications, but is plagued by dendritic Li plating and unstable solid-electrolyte interphase (SEI). Here, we report on high-performance Li metal batteries under low-temperature and high-rate-charging conditions. The high performance is achieved by using a self-assembled monolayer of electrochemically active molecules on current collectors that regulates the nullostructure and composition of the SEI and deposition morphology of Li metal anodes. A multilayer SEI that contains a lithium fluoride-rich inner phase and amorphous outer layer effectively seals the Li surface, in contrast to the conventional SEI, which is non-passive at low temperatures. Consequently, galvanic Li corrosion and self-discharge are suppressed, stable Li deposition is achieved from -60 degrees C to 45 degrees C, and a Li | LiCoO(2)cell with a capacity of 2.0 mAh cm(-2)displays a 200-cycle life at -15 degrees C with a recharge time of 45 min. In addition to high energy, batteries need to possess high power and to be able to operate in all climates. Here, the authors present an electrochemically active monolayer-coated current collector that is used to produce high-performance Li metal batteries under low-temperature and high-rate-charging conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 534, "End Page": 542, "Article Number": null, "DOI": "10.1038/s41560-020-0640-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0640-7", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542060100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, MY; Wu, XL; Lu, MC; Huang, LZ; Li, WX; Lin, HJ; Chen, JR; Wang, SB; Duan, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Mengying; Wu, Xi-Lin; Lu, Meichi; Huang, Lizhou; Li, Wenxuan; Lin, Hongjun; Chen, Jianrong; Wang, Shaobin; Duan, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulation of Charge Trapping by Island-like Single-Atom Cobalt Catalyst for Enhanced Photo-Fenton-Like reaction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Composites-based photocatalysis relies on the interfacial electron transfer between the metallic cocatalyst and photosensitizer (the semiconductor) to realize spatial separation of charge carriers. Herein, an ingenious heterojunction between Co-CN single atom catalysts (SACs) and g-C3N4 is constructed for heterogeneous photo-Fenton-like reactions. Driven by built-in electric field across the heterojunctions, the separation and migration of the photogenerated charge carriers is promoted, leading to the fast electron transfer from the g-C3N4 to the Co-CN SACs. Theoretical calculations and transient absorption spectroscopy reveal the modulated charge transfer and trapping in the SA-Co-CN/g-C3N4 heterostructure, resulting in the remarkably enhanced generation of reactive oxygen species via peroxymonosulfate activation under light irradiation. This ingenious SA-Co-CN/g-C3N4/PMS/vis system is efficient for the oxidation of various antibiotics with high removal efficiency (>98%), a wide operating pH range (pH 3-11) and excellent stability in long-term operation. This study provides a new tactic for rational design of SACs-based heterojunctions to bridge photocatalysis and heterogeneous catalysis, attaining superior photoredox activity via interfacial coupling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 33, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202208688", "DOI Link": "http://dx.doi.org/10.1002/adfm.202208688", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000908288600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baek, J; Rungtaweevoranit, B; Pei, XK; Park, M; Fakra, SC; Liu, YS; Matheu, R; Alshmimri, SA; Alshehri, S; Trickett, CA; Somorjai, GA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baek, Jayeon; Rungtaweevoranit, Bunyarat; Pei, Xiaokun; Park, Myeongkee; Fakra, Sirine C.; Liu, Yi-Sheng; Matheu, Roc; Alshmimri, Sultan A.; Alshehri, Saeed; Trickett, Christopher A.; Somorjai, Gabor A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired Metal-Organic Framework Catalysts for Selective Methane Oxidation to Methanol", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Particulate methane monooxygenase (pMMO) is an enzyme that oxidizes methane to methanol with high activity and selectivity. Limited success has been achieved in incorporating biologically relevant ligands for the formation of such active site in a synthetic system. Here, we report the design and synthesis of metal-organic framework (MOF) catalysts inspired by pMMO for selective methane oxidation to methanol. By judicious selection of a framework with appropriate topology and chemical functionality, MOF-808 was used to postsynthetically install ligands bearing imidazole units for subsequent metalation with Cu(I) in the presence of dioxygen. The catalysts show high selectivity for methane oxidation to methanol under isothermal conditions at 150 degrees C. Combined spectroscopies and density functional theory calculations suggest bis(mu-oxo) dicopper species as probable active site of the catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 26", "Publication Year": 2018, "Volume": 140, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18208, "End Page": 18216, "Article Number": null, "DOI": "10.1021/jacs.8b11525", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b11525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454751800050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, C; Li, WJ; Liu, HK; Dou, SX; Wang, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Chao; Li, Weijie; Liu, Hua Kun; Dou, Shixue; Wang, Jiazhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Principals and strategies for constructing a highly reversible zinc metal anode in aqueous batteries", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among all the electrochemical energy storage systems, zinc-based batteries, such as zinc-air, zinc-metal, zinc-ion batteries, etc., have been recognized as an important group of candidates that could be potential alternatives to the currently dominullt lead-acid and lithium-ion battery systems, because they have many unbeatable merits, including direct use of zinc metal as electrode; compatible with low cost, non-flammable, and environement-friendly aqueous electrolyte; assembly in ambient conditions; environmental benignity; and high safety. Currently, however, the capacitance, cycle life, and safety of zinc-based batteries were significantly degraded by zinc-water interaction problems that took place on the zinc metal electrode, including corrosion, passivation, shape change, and dendrite formation. This review gives a specific, comprehensive and in-depth summary of the mechanisms behind these problems; as well as state-of-the-art progress in the protection of the zinc electrode via intrinsic zinc alloy, zinc surface coating and electrolyte engineering in full pH range aqueous electrolyte. Future development trends, perspective and outlooks on the further blossom of these strategies are also presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 74, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104880, "DOI": "10.1016/j.nulloen.2020.104880", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.104880", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546639800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, P; Li, J; Brushett, FR; Bazant, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Peng; Li, Ju; Brushett, Fikile R.; Bazant, Martin Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition of lithium growth mechanisms in liquid electrolytes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation high-energy batteries will require a rechargeable lithium metal anode, but lithium dendrites tend to form during recharging, causing short-circuit risk and capacity loss, by mechanisms that still remain elusive. Here, we visualize lithium growth in a glass capillary cell and demonstrate a change of mechanism from root-growing mossy lithium to tip-growing dendritic lithium at the onset of electrolyte diffusion limitation. In sandwich cells, we further demonstrate that mossy lithium can be blocked by nulloporous ceramic separators, while dendritic lithium can easily penetrate nullopores and short the cell. Our results imply a fundamental design constraint for metal batteries (Sand's capacity''), which can be increased by using concentrated electrolytes with stiff, permeable, nulloporous separators for improved safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1211, "Times Cited, All Databases": 1330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3221, "End Page": 3229, "Article Number": null, "DOI": "10.1039/c6ee01674j", "DOI Link": "http://dx.doi.org/10.1039/c6ee01674j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386336200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gild, J; Samiee, M; Braun, JL; Harrington, T; Vega, H; Hopkins, PE; Vecchio, K; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gild, Joshua; Samiee, Mojtaba; Braun, Jeffrey L.; Harrington, Tyler; Vega, Heidy; Hopkins, Patrick E.; Vecchio, Kenneth; Luo, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy fluorite oxides", "Source Title": "JOURNAL OF THE EUROPEAN CERAMIC SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Eleven fluorite oxides with five principal cations (in addition to a four-principal-cation (Hf0.25Zr0.25Ce0.25Y0.25) O2-delta as a start point and baseline) were fabricated via high-energy ball milling, spark plasma sintering, and annealing in air. Eight of the compositions, namely (Hf0.25Zr0.25Ce0.25Y0.25)O2-delta, (Hf0.25Zr0.25Ce0.25) (Y0.125Yb0.125)O2-delta, (Hf0.2Zr0.2Ce0.2)Y0.2Yb0.2)O2-delta, (Hf0.25Zr0.25Ce0.25)(Y0.125Ca0.125)O2-delta, (Hf0.25Zr0.25Ce0.25) (Y0.125Gd0.125)O2-delta, (Hf0.2Zr0.2Ce0.2)(Y0.2Gd0.2)O2-delta, (Hf0.25Zr0.25Ce0.25)(Yb0.125Gd0.125)O2-delta, and (Hf0.2Zr0.2Ce0.2) (Yb0.2Gd0.2)O2-delta, possess single-phase solid solutions of the fluorite crystal structure with high configurational entropies (on the cation sublattices), akin to those high-entropy alloys and ceramics reported in prior studies. Most high-entropy fluorite oxides (HEFOs), except for the two containing both Yb and Gd, can be sintered to high relative densities. These single-phase HEFOs exhibit lower electrical conductivities and comparable hardness (even with higher contents of softer components such as Y2O3 and Yb2O3), in comparison with 8 mol. % Y2O3-stabilized ZrO2 (8YSZ). Notably, these single-phase HEFOs possess lower thermal conductivities than that of 8YSZ, presumably due to high phonon scattering by multiple cations and strained lattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 38, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3578, "End Page": 3584, "Article Number": null, "DOI": "10.1016/j.jeurceramsoc.2018.04.010", "DOI Link": "http://dx.doi.org/10.1016/j.jeurceramsoc.2018.04.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432768900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, CJ; Zhang, MM; Tang, DT; Yan, XZ; Zhang, ZY; Zhou, ZX; Song, B; Wang, H; Li, XP; Yin, SC; Sepehrpour, H; Stang, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Chenjie; Zhang, Mingming; Tang, Danting; Yan, Xuzhou; Zhang, ZeYuan; Zhou, Zhixuan; Song, Bo; Wang, Heng; Li, Xiaopeng; Yin, Shouchun; Sepehrpour, Hajar; Stang, Peter J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorescent Metallacage-Core Supramolecular Polymer Gel Formed by Orthogonal Metal Coordination and Host-Guest Interactions", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we report the preparation of a multifunctional metallacage-core supramolecular gel by orthogonal metal coordination and host-guest interactions. A tetragonal prismatic cage with four appended 21-crown-7 (21C7) moieties in its pillar parts was first prepared via the metal-coordination-driven self-assembly of cis-Pt(PEt3)(2)(OTf)(2), tetraphenylethene (TPE)-based sodium benzoate ligands and linear dipyridyl ligands. Further addition of a bisammonium linker to the cage delivered a supramolecular polymer network via the host-guest interactions between the 21C7 moieties and ammonium salts, which formed a supramolecular gel at relatively higher concentrations. Due to the incorporation of a TPE derivative as the fluorophore, the gel shows emission properties. Multiple stimuli responsiveness and good self-healing properties were also observed because of the dynamic metal coordination and host-guest interactions used to stabilize the whole network structure. Moreover, the storage and loss moduli of the gel are 10-fold those of the gel without the metallacage cores, indicating that the rigid metallacage plays a significant role in enhancing the stiffness of the gel. The studies described herein not only enrich the functionalization of fluorescent metallacages via elegant ligand design but also provide a way to prepare stimuli-responsive and self-healing supramolecular gels as robust and smart materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2018, "Volume": 140, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7674, "End Page": 7680, "Article Number": null, "DOI": "10.1021/jacs.8b03781", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b03781", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436211600047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsai, C; Li, H; Park, S; Park, J; Han, HS; Norskov, JK; Zheng, XL; Abild-Pedersen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsai, Charlie; Li, Hong; Park, Sangwook; Park, Joonsuk; Han, Hyun Soo; Norskov, Jens K.; Zheng, Xiaolin; Abild-Pedersen, Frank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, sulfur (S)-vacancies created on the basal plane of 2H-molybdenum disulfide (MoS2) using argon plasma exposure exhibited higher intrinsic activity for the electrochemical hydrogen evolution reaction than the edge sites and metallic 1T-phase of MoS2 catalysts. However, a more industrially viable alternative to the argon plasma desulfurization process is needed. In this work, we introduce a scalable route towards generating S-vacancies on the MoS2 basal plane using electrochemical desulfurization. Even though sulfur atoms on the basal plane are known to be stable and inert, we find that they can be electrochemically reduced under accessible applied potentials. This can be done on various 2H-MoS2 nullostructures. By changing the applied desulfurization potential, the extent of desulfurization and the resulting activity can be varied. The resulting active sites are stable under extended desulfurization durations and show consistent HER activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 635, "Times Cited, All Databases": 669, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15113, "DOI": "10.1038/ncomms15113", "DOI Link": "http://dx.doi.org/10.1038/ncomms15113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399985300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZY; Mao, Z; Zhang, XP; Ou, DP; Mu, YX; Zhang, Y; Zhao, CY; Liu, SW; Chi, ZG; Xu, JR; Wu, YC; Lu, PY; Lien, A; Bryce, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zhiyong; Mao, Zhu; Zhang, Xuepeng; Ou, Depei; Mu, Yingxiao; Zhang, Yi; Zhao, Cunyuan; Liu, Siwei; Chi, Zhenguo; Xu, Jiarui; Wu, Yuan-Chun; Lu, Po-Yen; Lien, Alan; Bryce, Martin R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intermolecular Electronic Coupling of Organic Units for Efficient Persistent Room-Temperature Phosphorescence", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although persistent room-temperature phosphorescence (RTP) emission has been observed for a few pure crystalline organic molecules, there is no consistent mechanism and no universal design strategy for organic persistent RTP (pRTP) materials. A new mechanism for pRTP is presented, based on combining the advantages of different excited-state configurations in coupled intermolecular units, which may be applicable to a wide range of organic molecules. By following this mechanism, we have developed a successful design strategy to obtain bright pRTP by utilizing a heavy halogen atom to further increase the intersystem crossing rate of the coupled units. RTP with a remarkably long lifetime of 0.28s and a very high quantum efficiency of 5% was thus obtained under ambient conditions. This strategy represents an important step in the understanding of organic pRTP emission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 578, "Times Cited, All Databases": 590, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2016, "Volume": 55, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2181, "End Page": 2185, "Article Number": null, "DOI": "10.1002/anie.201509224", "DOI Link": "http://dx.doi.org/10.1002/anie.201509224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854700043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, QB; Zhan, GT; Zhang, ZL; Yong, TY; Yang, XL; Gan, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Qingbo; Zhan, Guiting; Zhang, Zelong; Yong, Tuying; Yang, Xiangliang; Gan, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manganese porphyrin-based metal-organic framework for synergistic sonodynamic therapy and ferroptosis in hypoxic tumors", "Source Title": "THERANOSTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of efficient therapeutic strategy to incorporate ultrasound (US)-triggered sonodynamic therapy (SDT) and ferroptosis is highly promising in cancer therapy. However, the SDT efficacy is severely limited by the hypoxia and high glutathione (GSH) in the tumor microenvironment, and ferroptosis is highly associated with reactive oxygen species (ROS) and GSH depletion. Methods: A manganese porphyrin-based metal-organic framework (Mn-MOF) was constructed as a nullosensitizer to self-supply oxygen (O-2) and decrease GSH for enhanced SDT and ferroptosis. In vitro and in vivo analysis, including characterization, O-2 generation, GSH depletion, ROS generation, lipid peroxidation, antitumor efficacy and tumor immune microenvironment were systematically evaluated. Results: Mn-MOF exhibited catalase-like and GSH decreasing activity in vitro. After efficient internalization into cancer cells, Mn-MOF persistently catalyzed tumor-overexpressed H2O2 to in-situ produce O-2 to relieve tumor hypoxia and decrease GSH and GPX4, which facilitated the formation of ROS and ferroptosis to kill cancer cells upon US irradiation in hypoxic tumors. Thus, strong anticancer and anti-metastatic activity was found in H22 and 4T1 tumor-bearing mice after a single administration of Mn-MOF upon a single US irradiation. In addition, Mn-MOF showed strong antitumor immunity and improved immunosuppressive microenvironment upon US irradiation by increasing the numbers of activated CD8(+) T cells and matured dendritic cells and decreaing the numbers of myeloid-derived suppressor cells in tumor tissues. Conclusions: Mn-MOF holds great potential for hypoxic cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2021, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1937, "End Page": 1952, "Article Number": null, "DOI": "10.7150/thno.45511", "DOI Link": "http://dx.doi.org/10.7150/thno.45511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600553900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, GJ; Wang, JX; Liang, Z; Jia, K; Ma, J; Zhuang, ZF; Zhou, GM; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Guanjun; Wang, Junxiong; Liang, Zheng; Jia, Kai; Ma, Jun; Zhuang, Zhaofeng; Zhou, Guangmin; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct regeneration of degraded lithium-ion battery cathodes with a multifunctional organic lithium salt", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable recycle of spent Li ion batteries is an effective strategy to alleviate environmental concerns and support resource conservation. Here, authors report the direct regeneration of LiFePO4 cathode using multifunctional organic lithium salts, leading to high environmental and economic benefits. The recycling of spent lithium-ion batteries is an effective approach to alleviating environmental concerns and promoting resource conservation. LiFePO4 batteries have been widely used in electric vehicles and energy storage stations. Currently, lithium loss, resulting in formation of Fe(III) phase, is mainly responsible for the capacity fade of LiFePO4 cathode. Another factor is poor electrical conductivity that limits its rate capability. Here, we report the use of a multifunctional organic lithium salt (3,4-dihydroxybenzonitrile dilithium) to restore spent LiFePO4 cathode by direct regeneration. The degraded LiFePO4 particles are well coupled with the functional groups of the organic lithium salt, so that lithium fills vacancies and cyano groups create a reductive atmosphere to inhibit Fe(III) phase. At the same time, pyrolysis of the salt produces an amorphous conductive carbon layer that coats the LiFePO4 particles, which improves Li-ion and electron transfer kinetics. The restored LiFePO4 cathode shows good cycling stability and rate performance (a high capacity retention of 88% after 400 cycles at 5 C). This lithium salt can also be used to recover degraded transition metal oxide-based cathodes. A techno-economic analysis suggests that this strategy has higher environmental and economic benefits, compared with the traditional recycling methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 584, "DOI": "10.1038/s41467-023-36197-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36197-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, QK; Qian, YN; Huang, YJ; Ding, F; Qi, XL; Shen, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Qiankun; Qian, Yuna; Huang, Yijing; Ding, Feng; Qi, Xiaoliang; Shen, Jianliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine nulloparticle-dotted food gum hydrogel with excellent antibacterial activity and rapid shape adaptability for accelerated bacteria-infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most commonly used wound dressings have severe problems, such as an inability to adapt to wound shape or a lack of antibacterial capacity, affecting their ability to meet the requirements of clinical applications. Here, a nullocomposite hydrogel (XKP) is developed by introducing polydopamine nulloparticles (PDA NPs) into a food gum matrix (XK, consisting of xanthan gum and konjac glucomannull, both FDA-approved food thickening agents) for skin wound healing. In this system, the embedded PDA NPs not only interact with the food gum matrix to form a hydrogel with excellent mechanical strength, but also act as photothermal transduction agents to convert near-infrared laser radiation to heat, thereby triggering bacterial death. Moreover, the XKP hydrogel has high elasticity and tunable water content, enabling it to adapt to the shape of the wound and insulate it, providing a moist environment suitable for healing. In-vivo skin wound healing results clearly demonstrate that XKP can significantly accelerate the healing of wounds by reducing the inflammatory response and promoting vascular reconstruction. In summary, this strategy provides a simple and practical method to overcome the drawbacks of traditional wound dressings, and provides further options when choosing suitable wound healing materials for clinical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2647, "End Page": 2657, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.01.035", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.01.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662249100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, X; Luo, L; Liu, YJ; Leng, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Xue; Luo, Lan; Liu, Yanju; Leng, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Ink Writing Based 4D Printing of Materials and Their Applications", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "4D printing has attracted academic interest in the recent years because it endows static printed structures with dynamic properties with the change of time. The shapes, functionalities, or properties of the 4D printed objects could alter under various stimuli such as heat, light, electric, and magnetic field. Briefly, 4D printing is the development of 3D printing with the fourth dimension of time. Among the fabrication techniques that have been employed for 4D printing, the direct ink writing technique shows superiority due to its open source for various types of materials. Herein, the state-of-the-art achievements about the topic of 4D printing through direct ink writing are summarized. The types of materials, printing strategies, actuated methods, and their potential applications are discussed in detail. To date, most efforts have been devoted to shape-shifting materials, including shape memory polymers, hydrogels, and liquid crystal elastomers, showing great prospects in areas ranging from the biomedical field to robotics. Finally, the current challenges and outlook toward 4D printing based on direct ink writing are also pointed out to leave open a significant space for future innovation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 7, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001000, "DOI": "10.1002/advs.202001000", "DOI Link": "http://dx.doi.org/10.1002/advs.202001000", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543978900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, X; Wang, H; Huang, SX; Xia, FN; Dresselhaus, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Xi; Wang, Han; Huang, Shengxi; Xia, Fengnian; Dresselhaus, Mildred S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The renaissance of black phosphorus", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One hundred years after its first successful synthesis in the bulk form in 1914, black phosphorus (black P) was recently rediscovered from the perspective of a 2D layered material, attracting tremendous interest from condensed matter physicists, chemists, semiconductor device engineers, and material scientists. Similar to graphite and transition metal dichalcogenides (TMDs), black P has a layered structure but with a unique puckered single-layer geometry. Because the direct electronic band gap of thin film black P can be varied from 0.3 eV to around 2 eV, depending on its film thickness, and because of its high carrier mobility and anisotropic in-plane properties, black P is promising for novel applications in nulloelectronics and nullophotonics different from graphene and TMDs. Black P as a nullomaterial has already attracted much attention from researchers within the past year. Here, we offer our opinions on this emerging material with the goal of motivating and inspiring fellow researchers in the 2D materials community and the broad readership of PNAS to discuss and contribute to this exciting new field. We also give our perspectives on future 2D and thin film black P research directions, aiming to assist researchers coming from a variety of disciplines who are desirous of working in this exciting research field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1189, "Times Cited, All Databases": 1307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2015, "Volume": 112, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4523, "End Page": 4530, "Article Number": null, "DOI": "10.1073/pnas.1416581112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1416581112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352856800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, CB; Liu, TF; Sheng, OW; Li, M; Liu, TC; Yuan, YF; Nai, JW; Ju, ZJ; Zhang, WK; Liu, YJ; Wang, Y; Lin, Z; Lu, J; Tao, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Chengbin; Liu, Tiefeng; Sheng, Ouwei; Li, Matthew; Liu, Tongchao; Yuan, Yifei; Nai, Jianwei; Ju, Zhijin; Zhang, Wenkui; Liu, Yujing; Wang, Yao; Lin, Zhan; Lu, Jun; Tao, Xinyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rejuvenating dead lithium supply in lithium metal anodes by iodine redox", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inactive lithium (more frequently called dead lithium) in the forms of solid-electrolyte interphase and electrically isolated metallic lithium is principally responsible for the performance decay commonly observed in lithium metal batteries. A fundamental solution of recovering dead lithium is urgently needed to stabilize lithium metal batteries. Here we quantify the solid-electrolyte interphase components, and determine their relation with the formation of electrically isolated dead lithium metal. We present a lithium restoration method based on a series of iodine redox reactions mainly involving I-3(-)/I-. Using a biochar capsule host for iodine, we show that the I-3(-)/I- redox takes place spontaneously, effectively rejuvenating dead lithium to compensate the lithium loss. Through this design, a full-cell using a very limited lithium metal anode exhibits an excellent lifespan of 1,000 cycles with a high Coulombic efficiency of 99.9%. We also demonstrate the design with a commercial cathode in pouch cells. Cycling lithium batteries often results in inactive lithium that no longer participates in redox reactions, leading to performance deterioration. Here the authors use an iodic species to react with inactive lithium, bringing it back to life and thus making batteries last longer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 387, "Article Number": null, "DOI": "10.1038/s41560-021-00789-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00789-7", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627674900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, Q; Peng, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Qun; Peng, Xihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior mechanical flexibility of phosphorene and few-layer black phosphorus", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, fabricated two dimensional (2D) phosphorene crystal structures have demonstrated great potential in applications of electronics. Mechanical strain was demonstrated to be able to significantly modify the electronic properties of phosphorene and few-layer black phosphorus. In this work, we employed first principles density functional theory calculations to explore the mechanical properties of phosphorene, including ideal tensile strength and critical strain. It was found that a monolayer phosphorene can sustain tensile strain up to 27% and 30% in the zigzag and armchair directions, respectively. This enormous strain limit of phosphorene results from its unique puckered crystal structure. We found that the tensile strain applied in the armchair direction stretches the pucker of phosphorene, rather than significantly extending the P-P bond lengths. The compromised dihedral angles dramatically reduce the required strain energy. Compared to other 2D materials, such as graphene, phosphorene demonstrates superior flexibility with an order of magnitude smaller Young's modulus. This is especially useful in practical large-magnitude-strain engineering. Furthermore, the anisotropic nature of phosphorene was also explored. We derived a general model to calculate the Young's modulus along different directions for a 2D system. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 953, "Times Cited, All Databases": 1008, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2014, "Volume": 104, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 251915, "DOI": "10.1063/1.4885215", "DOI Link": "http://dx.doi.org/10.1063/1.4885215", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338515900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, HR; null, KW; Bai, WB; Huang, W; Bai, K; Lu, LY; Zhou, CQ; Liu, YP; Liu, F; Wang, JT; Han, MD; Yan, Z; Luan, HW; Zhang, YJ; Zhang, YT; Zhao, JN; Cheng, X; Li, MY; Lee, JW; Liu, Y; Fang, DN; Li, XL; Huang, YG; Zhang, YH; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Haoran; null, Kewang; Bai, Wubin; Huang, Wen; Bai, Ke; Lu, Luyao; Zhou, Chaoqun; Liu, Yunpeng; Liu, Fei; Wang, Juntong; Han, Mengdi; Yan, Zheng; Luan, Haiwen; Zhang, Yijie; Zhang, Yutong; Zhao, Jianing; Cheng, Xu; Li, Moyang; Lee, Jung Woo; Liu, Yuan; Fang, Daining; Li, Xiuling; Huang, Yonggang; Zhang, Yihui; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphable 3D mesostructures and microelectronic devices by multistable buckling mechanics", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) structures capable of reversible transformations in their geometrical layouts have important applications across a broad range of areas. Most morphable 3D systems rely on concepts inspired by origami/kirigami or techniques of 3D printing with responsive materials. The development of schemes that can simultaneously apply across a wide range of size scales and with classes of advanced materials found in state-of-the-art microsystem technologies remains challenging. Here, we introduce a set of concepts for morphable 3D mesostructures in diverse materials and fully formed planar devices spanning length scales from micrometres to millimetres. The approaches rely on elastomer platforms deformed in different time sequences to elastically alter the 3D geometries of supported mesostructures via nonlinear mechanical buckling. Over 20 examples have been experimentally and theoretically investigated, including mesostructures that can be reshaped between different geometries as well as those that can morph into three or more distinct states. An adaptive radiofrequency circuit and a concealable electromagnetic device provide examples of functionally reconfigurable microelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-017-0011-3", "DOI Link": "http://dx.doi.org/10.1038/s41563-017-0011-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426012000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, M; Jiang, Y; Wang, G; Wu, WJ; Chen, WX; Yu, P; Lin, YQ; Mao, JJ; Mao, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Min; Jiang, Ying; Wang, Guo; Wu, Wenjie; Chen, Wenxing; Yu, Ping; Lin, Yuqing; Mao, Junjie; Mao, Lanqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Ni-N4 provides a robust cellular NO sensor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitric oxide (NO) has been implicated in a variety of physiological and pathological processes. Monitoring cellular levels of NO requires a sensor to feature adequate sensitivity, transient recording ability and biocompatibility. Herein we report a single-atom catalysts (SACs)-based electrochemical sensor for the detection of NO in live cellular environment. The system employs nickel single atoms anchored on N-doped hollow carbon spheres (Ni SACs/N-C) that act as an excellent catalyst for electrochemical oxidation of NO. Notably, Ni SACs/N-C shows superior electrocatalytic performance to the commonly used Ni based nullomaterials, attributing from the greatly reduced Gibbs free energy that are required for Ni SACs/N-C in activating NO oxidation. Moreover, Ni SACs-based flexible and stretchable sensor shows high biocompatibility and low nullomolar sensitivity, enabling the real-time monitoring of NO release from cells upon drug and stretch stimulation. Our results demonstrate a promising means of using SACs for electrochemical sensing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3188, "DOI": "10.1038/s41467-020-17018-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17018-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548926500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Yang, JL; Hou, XY; Li, G; Wang, L; Bai, NN; Cai, MK; Zhao, LY; Wang, Y; Zhang, JM; Chen, K; Wu, X; Yang, CH; Dai, Y; Zhang, ZY; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuan; Yang, Junlong; Hou, Xingyu; Li, Gang; Wang, Liu; Bai, Ningning; Cai, Minkun; Zhao, Lingyu; Wang, Yan; Zhang, Jianming; Chen, Ke; Wu, Xiang; Yang, Canhui; Dai, Yuan; Zhang, Zhengyou; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stable flexible pressure sensors with a quasi-homogeneous composition and interlinked interfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "E-skins often have poor interfaces that lead to unstable performances. Here, authors report e-skins with a quasi-homogeneous composition and bonded micro-structured interfaces, through which both the sensitivity and stability of the devices are improved. Electronic skins (e-skins) are devices that can respond to mechanical stimuli and enable robots to perceive their surroundings. A great challenge for existing e-skins is that they may easily fail under extreme mechanical conditions due to their multilayered architecture with mechanical mismatch and weak adhesion between the interlayers. Here we report a flexible pressure sensor with tough interfaces enabled by two strategies: quasi-homogeneous composition that ensures mechanical match of interlayers, and interlinked microconed interface that results in a high interfacial toughness of 390 J center dot m(-2). The tough interface endows the sensor with exceptional signal stability determined by performing 100,000 cycles of rubbing, and fixing the sensor on a car tread and driving 2.6 km on an asphalt road. The topological interlinks can be further extended to soft robot-sensor integration, enabling a seamless interface between the sensor and robot for highly stable sensing performance during manipulation tasks under complicated mechanical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1317, "DOI": "10.1038/s41467-022-29093-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29093-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767467900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Leow, WR; Wang, T; Wang, J; Yu, JC; He, K; Qi, DP; Wan, CJ; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hui; Leow, Wan Ru; Wang, Ting; Wang, Juan; Yu, Jiancan; He, Ke; Qi, Dianpeng; Wan, Changjin; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Photoresponsive Devices Based on Shape Memory Composites", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compared with traditional stimuli-responsive devices with simple planar or tubular geometries, 3D printed stimuli-responsive devices not only intimately meet the requirement of complicated shapes at macrolevel but also satisfy various conformation changes triggered by external stimuli at the microscopic scale. However, their development is limited by the lack of 3D printing functional materials. This paper demonstrates the 3D printing of photo-responsive shape memory devices through combining fused deposition modeling printing technology and photoresponsive shape memory composites based on shape memory polymers and carbon black with high photothermal conversion efficiency. External illumination triggers the shape recovery of 3D printed devices from the temporary shape to the original shape. The effect of materials thickness and light density on the shape memory behavior of 3D printed devices is quantified and calculated. Remarkably, sunlight also triggers the shape memory behavior of these 3D printed devices. This facile printing strategy would provide tremendous opportunities for the design and fabrication of biomimetic smart devices and soft robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2017, "Volume": 29, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701627, "DOI": "10.1002/adma.201701627", "DOI Link": "http://dx.doi.org/10.1002/adma.201701627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408933600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SG; Vogt, DM; Rus, D; Wood, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shuguang; Vogt, Daniel M.; Rus, Daniela; Wood, Robert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluid-driven origami-inspired artificial muscles", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial muscles hold promise for safe and powerful actuation for myriad common machines and robots. However, the design, fabrication, and implementation of artificial muscles are often limited by their material costs, operating principle, scalability, and single-degree-of-freedom contractile actuation motions. Here we propose an architecture for fluid-driven origami-inspired artificial muscles. This concept requires only a compressible skeleton, a flexible skin, and a fluid medium. A mechanical model is developed to explain the interaction of the three components. A fabrication method is introduced to rapidly manufacture low-cost artificial muscles using various materials and at multiple scales. The artificial muscles can be programed to achieve multiaxial motions including contraction, bending, and torsion. These motions can be aggregated into systems with multiple degrees of freedom, which are able to produce controllable motions at different rates. Our artificial muscles can be driven by fluids at negative pressures (relative to ambient). This feature makes actuation safer than most other fluidic artificial muscles that operate with positive pressures. Experiments reveal that these muscles can contract over 90% of their initial lengths, generate stresses of similar to 600 kPa, and produce peak power densities over 2 kW/kg-all equal to, or in excess of, natural muscle. This architecture for artificial muscles opens the door to rapid design and low-cost fabrication of actuation systems for numerous applications at multiple scales, ranging from miniature medical devices to wearable robotic exoskeletons to large deployable structures for space exploration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 595, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 12", "Publication Year": 2017, "Volume": 114, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13132, "End Page": 13137, "Article Number": null, "DOI": "10.1073/pnas.1713450114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1713450114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417806200048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, R; Metzger, M; Maglia, F; Stinner, C; Gasteiger, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Roland; Metzger, Michael; Maglia, Filippo; Stinner, Christoph; Gasteiger, Hubert A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen Release and Its Effect on the Cycling Stability of LiNixMnyCozO2 (NMC) Cathode Materials for Li-Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered LiNixMnyCozO2 (NMC) is a widely used class of cathode materials with LiNi1/3Mn1/3Co1/3O2 (NMC111) being the most common representative. However, Ni-rich NMCs are more and more in the focus of current research due to their higher specific capacity and energy. In this work we will compare LiNi1/3Mn1/3Co1/3O2 (NMC111), LiNi0.6Mn0.2Co0.2O2 (NMC622), and LiNi0.8Mn0.1Co0.1O2 (NMC811) with respect to their cycling stability in NMC-graphite full-cells at different end-of-charge potentials. It will be shown that stable cycling is possible up to 4.4 V for NMC111 and NMC622 and only up to 4.0 V for NMC811. At higher potentials, significant capacity fading was observed, which was traced back to an increase in the polarization of the NMC electrode, contrary to the nearly constant polarization of the graphite electrode. Furthermore, we show that the increase in the polarization occurs when the NMC materials are cycled up to a high-voltage feature in the dq/dV plot, which occurs at similar to 4.7 V vs. Li/Li+ for NMC111 and NMC622 and at similar to 4.3 V vs. Li/Li+ for NMC811. For the latter material, this feature corresponds to the H2 -> H3 phase transition. Contrary to the common understanding that the electrochemical oxidation of carbonate electrolytes causes the CO2 and CO evolution at potentials above 4.7 V vs. Li/Li+, we believe that the observed CO2 and CO are mainly due to the chemical reaction of reactive lattice oxygen with the electrolyte. This hypothesis is based on gas analysis using On-line Electrochemical Mass Spectrometry (OEMS), by which we prove that all three materials release oxygen from the particle surface and that the oxygen evolution coincides with the onset of CO2 and CO evolution. Interestingly, the onsets of oxygen evolution for the different NMCs correlate well with the high-voltage redox feature at similar to 4.7 V vs. Li/Li+ for NMC111 and NMC622 as well as at similar to 4.3 V vs. Li/Li+ for NMC811. To support this hypothesis, we show that no CO2 or CO is evolved for the LiNi0.43Mn1.57O4 (LNMO) spinel up to 5 V vs. Li/Li+, consistent with the absence of oxygen release. Lastly, we demonstrate by the use of C-13 labeled conductive carbon that it is the electrolyte rather than the conductive carbon which is oxidized by the released lattice oxygen. Taking these findings into consideration, a mechanism is proposed for the reaction of released lattice oxygen with ethylene carbonate yielding CO2, CO, and H2O. (C) The Author(s) 2017. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 978, "Times Cited, All Databases": 1050, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 164, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A1361", "End Page": "A1377", "Article Number": null, "DOI": "10.1149/2.0021707jes", "DOI Link": "http://dx.doi.org/10.1149/2.0021707jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404397300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Cao, SW; Hu, CL; Chen, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jing; Cao, Shaowen; Hu, Chenglong; Chen, Chunhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A comparison study of alkali metal-doped g-C3N4 for visible-light photocatalytic hydrogen evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic hydrogen production based on semiconductor photocatalysts has been considered as one of the most promising strategies to resolve the global energy shortage. Graphitic carbon nitride (g-C3N4) has been a star visible-light photocatalyst in this field due to its various advantages. However, pristine g-C3N4 usually exhibits limited activity. Herein, to enhance the performance of g-C3N4, alkali metal ion (Li+, Na+, or K+)-doped g-C3N4 are prepared via facile high-temperature treatment. The prepared samples are characterized and analyzed using the technique of XRD, ICP-AES, SEM, UV-vis DRS, BET, XPS, PL, TRPL, photoelectrochemical measurements, photocatalytic tests, etc. The resultant doped photocatalysts show enhanced visible-light photocatalytic activities for hydrogen production, benefiting from the increased specific surface areas (which provide more active sites), decreased band gaps for extended visible-light absorption, and improved electronic structures for efficient charge transfer. In particular, because of the optimal tuning of both microstructure and electronic structure, the Na-doped g-C3N4 shows the most effective utilization of photogenerated electrons during the water reduction process. As a result, the highest photocatalytic performance is achieved over the Na-doped g-C3N4 photocatalyst (18.7 mu mol/h), 3.7 times that of pristine g-C3N4 (5.0 mu mol/h). This work gives a systematic study for the understanding of doping effect of alkali metals in semiconductor photocatalysis. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 38, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1981, "End Page": 1989, "Article Number": null, "DOI": "10.1016/S1872-2067(17)62936-X", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(17)62936-X", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423004400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rimoldi, M; Howarth, AJ; DeStefano, MR; Lin, L; Goswami, S; Li, P; Hupp, JT; Farha, OK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R.; Lin, Lu; Goswami, Subhadip; Li, Peng; Hupp, Joseph T.; Farha, Omar K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic Zirconium/Hafnium-Based Metal-Organic Frameworks", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are highly versatile materials that find applications in several fields. Highly stable zirconium/hafnium-based MOFs were recently introduced and nowadays represent a rapidly growing family. Their unique and intriguing properties make them privileged materials and outstanding candidates in heterogeneous catalysis, finding use either as catalysts or catalyst supports. Various techniques have been developed to incorporate active species into Zr-MOFs, giving rise to catalysts that often demonstrate higher performances or unusual activity when compared with their homogeneous analogues. Catalytic functions are commonly incorporated at the zirconium-oxide node, at the linker, or encapsulated in the pores. Representative examples are discussed, and advantages in adopting Zr- and Hf-MOFs in catalytic applications are highlighted.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 997, "End Page": 1014, "Article Number": null, "DOI": "10.1021/acscatal.6b02923", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b02923", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393539200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, QB; Li, B; Yang, DD; Liu, C; Feng, S; Chen, ML; Sun, Y; Tian, YN; Su, X; Wang, XM; Qiu, S; Li, QW; Li, XM; Zeng, HB; Cheng, HM; Sun, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Qian-Bing; Li, Bo; Yang, Dan-Dan; Liu, Chi; Feng, Shun; Chen, Mao-Lin; Sun, Yun; Tian, Ya-null; Su, Xin; Wang, Xiao-Mu; Qiu, Song; Li, Qing-Wen; Li, Xiao-Ming; Zeng, Hai-Bo; Cheng, Hui-Ming; Sun, Dong-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A flexible ultrasensitive optoelectronic sensor array for neuromorphic vision systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The challenges of developing neuromorphic vision systems inspired by the human eye come not only from how to recreate the flexibility, sophistication, and adaptability of animal systems, but also how to do so with computational efficiency and elegance. Similar to biological systems, these neuromorphic circuits integrate functions of image sensing, memory and processing into the device, and process continuous analog brightness signal in real-time. High-integration, flexibility and ultra-sensitivity are essential for practical artificial vision systems that attempt to emulate biological processing. Here, we present a flexible optoelectronic sensor array of 1024 pixels using a combination of carbon nullotubes and perovskite quantum dots as active materials for an efficient neuromorphic vision system. The device has an extraordinary sensitivity to light with a responsivity of 5.1x10(7)A/W and a specific detectivity of 2x10(16) Jones, and demonstrates neuromorphic reinforcement learning by training the sensor array with a weak light pulse of 1 mu W/cm(2). To emulate nature biological processing, highly-integrated ultra-sensitive artificial neuromorphic system is highly desirable. Here, the authors report flexible sensor array of 1024 pixels using combination of carbon nullotubes and perovskite QDs as active matetials, achieving highly responsive device for reinforcement learning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1798, "DOI": "10.1038/s41467-021-22047-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22047-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631934900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, HB; Hudson, ZM; Winnik, MA; Manners, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Huibin; Hudson, Zachary M.; Winnik, Mitchell A.; Manners, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multidimensional hierarchical self-assembly of amphiphilic cylindrical block comicelles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-assembly of molecular and block copolymer amphiphiles represents a well-established route to micelles with a wide variety of shapes and gel-like phases. We demonstrate an analogous process, but on a longer length scale, in which amphiphilic P-H-P and H-P-H cylindrical triblock comicelles with hydrophobic (H) or polar (P) segments that are monodisperse in length are able to self-assemble side by side or end to end in nonsolvents for the central or terminal segments, respectively. This allows the formation of cylindrical supermicelles and one-dimensional (1D) or 3D superstructures that persist in both solution and the solid state. These assemblies possess multiple levels of structural hierarchy in combination with existence on a multimicrometer-length scale, features that are generally only found in natural materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2015, "Volume": 347, "Issue": 6228, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1329, "End Page": 1332, "Article Number": null, "DOI": "10.1126/science.1261816", "DOI Link": "http://dx.doi.org/10.1126/science.1261816", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351219600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singh, MR; Kwon, Y; Lum, Y; Ager, JW; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singh, Meenesh R.; Kwon, Youngkook; Lum, Yanwei; Ager, Joel W., III; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO2 over Ag and Cu", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte cation size is known to influence the electrochemical reduction of CO2 over metals; however, a satisfactory explanation for this phenomenon has not been developed. We report here that these effects can be attributed to a previously unrecognized consequence of cation hydrolysis occurring in the vicinity of the cathode. With increasing cation size, the pKa for cation hydrolysis decreases and is sufficiently low for hydrated K+, Rb+, and Cs+ to serve as buffering agents. Buffering lowers the pH near the cathode, leading to an increase in the local concentration of dissolved CO2. The consequences of these changes are an increase in cathode activity, a decrease in Faradaic efficiencies for H-2 and CH4, and an increase in Faradaic efficiencies for CO, C2H4, and C2H5OH, in full agreement with experimental observations for CO2 reduction over Ag and Cu.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 737, "Times Cited, All Databases": 812, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2016, "Volume": 138, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13006, "End Page": 13012, "Article Number": null, "DOI": "10.1021/jacs.6b07612", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b07612", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384952100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Esfandiar, A; Radha, B; Wang, FC; Yang, Q; Hu, S; Garaj, S; Nair, RR; Geim, AK; Gopinadhan, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Esfandiar, A.; Radha, B.; Wang, F. C.; Yang, Q.; Hu, S.; Garaj, S.; Nair, R. R.; Geim, A. K.; Gopinadhan, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size effect in ion transport through angstrom-scale slits", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the field of nullofluidics, it has been an ultimate but seemingly distant goal to controllably fabricate capillaries with dimensions approaching the size of small ions and water molecules. We report ion transport through ultimately narrow slits that are fabricated by effectively removing a single atomic plane from a bulk crystal. The atomically flat angstrom-scale slits exhibit little surface charge, allowing elucidation of the role of steric effects. We find that ions with hydrated diameters larger than the slit size can still permeate through, albeit with reduced mobility. The confinement also leads to a notable asymmetry between anions and cations of the same diameter. Our results provide a platform for studying the effects of angstrom-scale confinement, which is important for the development of nullofluidics, molecular separation, and other nulloscale technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 610, "Times Cited, All Databases": 648, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2017, "Volume": 358, "Issue": 6362, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": 513, "Article Number": null, "DOI": "10.1126/science.aan5275", "DOI Link": "http://dx.doi.org/10.1126/science.aan5275", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413757500042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, WT; Zhu, BE; Fang, K; Li, XY; Hansen, TW; Ou, Y; Yang, HS; Wagner, JB; Gao, Y; Wang, Y; Zhang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Wentao; Zhu, Beien; Fang, Ke; Li, Xiao-Yan; Hansen, Thomas W.; Ou, Yang; Yang, Hangsheng; Wagner, Jakob B.; Gao, Yi; Wang, Yong; Zhang, Ze", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ manipulation of the active Au-TiO2 interface with atomic precision during CO oxidation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interface between metal catalyst and support plays a critical role in heterogeneous catalysis. An epitaxial interface is generally considered to be rigid, and tuning its intrinsic microstructure with atomic precision during catalytic reactions is challenging. Using aberration-corrected environmental transmission electron microscopy, we studied the interface between gold (Au) and a titanium dioxide (TiO2) support. Direct atomic-scale observations showed an unexpected dependence of the atomic structure of the Au-TiO2 interface with the epitaxial rotation of gold nulloparticles on a TiO2 surface during carbon monoxide (CO) oxidation. Taking advantage of the reversible and controllable rotation, we achieved in situ manipulation of the active Au-TiO2 interface by changing gas and temperature. This result suggests that real-time design of the catalytic interface in operating conditions may be possible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 371, "Issue": 6528, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 517, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abe3558", "DOI Link": "http://dx.doi.org/10.1126/science.abe3558", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612983100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, Q; Sakhaei, AH; Lee, H; Dunn, CK; Fang, NX; Dunn, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Qi; Sakhaei, Amir Hosein; Lee, Howon; Dunn, Conner K.; Fang, Nicholas X.; Dunn, Martin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multimaterial 4D Printing with Tailorable Shape Memory Polymers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a new 4D printing approach that can create high resolution (up to a few microns), multimaterial shape memory polymer (SMP) architectures. The approach is based on high resolution projection microstereolithography (P mu SL) and uses a family of photo-curable methacrylate based copolymer networks. We designed the constituents and compositions to exhibit desired thermomechanical behavior (including rubbery modulus, glass transition temperature and failure strain which is more than 300% and larger than any existing printable materials) to enable controlled shape memory behavior. We used a high resolution, high contrast digital micro display to ensure high resolution of photo-curing methacrylate based SMPs that requires higher exposure energy than more common acrylate based polymers. An automated material exchange process enables the manufacture of 3D composite architectures from multiple photo-curable SMPs. In order to understand the behavior of the 3D composite microarchitectures, we carry out high fidelity computational simulations of their complex nonlinear, time-dependent behavior and study important design considerations including local deformation, shape fixity and free recovery rate. Simulations are in good agreement with experiments for a series of single and multimaterial components and can be used to facilitate the design of SMP 3D structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 839, "Times Cited, All Databases": 934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31110, "DOI": "10.1038/srep31110", "DOI Link": "http://dx.doi.org/10.1038/srep31110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392100600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Laplanche, G; Kostka, A; Reinhart, C; Hunfeld, J; Eggeler, G; George, EP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Laplanche, G.; Kostka, A.; Reinhart, C.; Hunfeld, J.; Eggeler, G.; George, E. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The tensile properties of CrCoNi, a medium-entropy alloy, have been shown to be significantly better than those of CrMnFeCoNi, a high-entropy alloy. To understand the deformation mechanisms responsible for its superiority, tensile tests were performed on CrCoNi at liquid nitrogen temperature (77 K) and room temperature (293 K) and interrupted at different strains. Microstructural analyses by transmission electron microscopy showed that, during the early stage of plasticity, deformation occurs by the glide of 1/2 < 110 > dislocations dissociated into 1/6 < 112 > Shockley partials on 011) planes, similar to the behavior of CrMnFeCoNi. Measurements of the partial separations yielded a stacking fault energy of 22 +/- 4 mJ m(-2), which is similar to 25% lower than that of CrMnFeCoNi. With increasing strain, nullotwinning appears as an additional deformation mechanism in CrCoNi. The critical resolved shear stress for twinning in CrCoNi with 16 mu m grain size is 260 +/- 30 MPa, roughly independent of temperature, and comparable to that of CrMnFeCoNi having similar grain size. However, the yield strength and work hardening rate of CrCoNi are higher than those of CrMnFeCoNi. Consequently, the twinning stress is reached earlier (at lower strains) in CrCoNi. This in turn results in an extended strain range where nullotwinning can provide high, steady work hardening, leading to the superior mechanical properties (ultimate strength, ductility, and toughness) of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 984, "Times Cited, All Databases": 1028, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2017, "Volume": 128, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 292, "End Page": 303, "Article Number": null, "DOI": "10.1016/j.actamat.2017.02.036", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.02.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397692600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, EF; Fu, YJ; Wang, YJ; Feng, YQ; Liu, HM; Wan, XG; Zhou, W; Wang, BG; Shao, LB; Ho, CH; Huang, YS; Cao, ZY; Wang, LG; Li, AD; Zeng, JW; Song, FQ; Wang, XR; Shi, Y; Yuan, HT; Hwang, HY; Cui, Y; Miao, F; Xing, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Erfu; Fu, Yajun; Wang, Yaojia; Feng, Yanqing; Liu, Huimei; Wan, Xiangang; Zhou, Wei; Wang, Baigeng; Shao, Lubin; Ho, Ching-Hwa; Huang, Ying-Sheng; Cao, Zhengyi; Wang, Laiguo; Li, Aidong; Zeng, Junwen; Song, Fengqi; Wang, Xinran; Shi, Yi; Yuan, Hongtao; Hwang, Harold Y.; Cui, Yi; Miao, Feng; Xing, Dingyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated digital inverters based on two-dimensional anisotropic ReS2 field-effect transistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconducting two-dimensional transition metal dichalcogenides are emerging as top candidates for post-silicon electronics. While most of them exhibit isotropic behaviour, lowering the lattice symmetry could induce anisotropic properties, which are both scientifically interesting and potentially useful. Here we present atomically thin rhenium disulfide (ReS2) flakes with unique distorted 1T structure, which exhibit in-plane anisotropic properties. We fabricated monolayer and few-layer ReS2 field-effect transistors, which exhibit competitive performance with large current on/off ratios (similar to 10(7)) and low subthreshold swings (100mV per decade). The observed anisotropic ratio along two principle axes reaches 3.1, which is the highest among all known two-dimensional semiconducting materials. Furthermore, we successfully demonstrated an integrated digital inverter with good performance by utilizing two ReS2 anisotropic field-effect transistors, suggesting the promising implementation of large-scale two-dimensional logic circuits. Our results underscore the unique properties of two-dimensional semiconducting materials with low crystal symmetry for future electronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 570, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6991, "DOI": "10.1038/ncomms7991", "DOI Link": "http://dx.doi.org/10.1038/ncomms7991", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355528800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, JL; Liu, XY; Chen, RS; Li, QH; Wang, Y; Chen, PH; Gan, LY; Lee, SJ; Nordlund, D; Liu, YJ; Yu, XQ; Bai, XD; Li, H; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Jiliang; Liu, Xinyu; Chen, Rusong; Li, Qinghao; Wang, Yi; Chen, Penghao; Gan, Luyu; Lee, Sang-Jun; Nordlund, Dennis; Liu, Yijin; Yu, Xiqian; Bai, Xuedong; Li, Hong; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling Stable Cycling of 4.2 V High-Voltage All-Solid-State Batteries with PEO-Based Solid Electrolyte", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poly(ethylene oxide) (PEO)-based solid electrolytes are expected to be exploited in solid-state batteries with high safety. Its narrow electrochemical window, however, limits the potential for high voltage and high energy density applications. Herein the electrochemical oxidation behavior of PEO and the failure mechanisms of LiCoO2-PEO solid-state batteries are studied. It is found that although for pure PEO it starts to oxidize at a voltage of above 3.9 V versus Li/Li+, the decomposition products have appropriate Li+ conductivity that unexpectedly form a relatively stable cathode electrolyte interphase (CEI) layer at the PEO and electrode interface. The performance degradation of the LiCoO2-PEO battery originates from the strong oxidizing ability of LiCoO2 after delithiation at high voltages, which accelerates the decomposition of PEO and drives the self-oxygen-release of LiCoO2, leading to the unceasing growth of CEI and the destruction of the LiCoO2 surface. When LiCoO2 is well coated or a stable cathode LiMn0.7Fe0.3PO4 is used, a substantially improved electrochemical performance can be achieved, with 88.6% capacity retention after 50 cycles for Li1.4Al0.4Ti1.6(PO4)(3) coated LiCoO2 and 90.3% capacity retention after 100 cycles for LiMn0.7Fe0.3PO4. The results suggest that, when paired with stable cathodes, the PEO-based solid polymer electrolytes could be compatible with high voltage operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 30, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1909392, "DOI": "10.1002/adfm.201909392", "DOI Link": "http://dx.doi.org/10.1002/adfm.201909392", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537167400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XZ; Zhang, ZH; Dong, JC; Yi, D; Niu, JJ; Wu, MH; Lin, L; Yin, RK; Li, MQ; Zhou, JY; Wang, SX; Sun, JL; Duan, XJ; Gao, P; Jiang, Y; Wu, XS; Peng, HL; Ruoff, RS; Liu, ZF; Yu, DP; Wang, EG; Ding, F; Liu, KH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiaozhi; Zhang, Zhihong; Dong, Jichen; Yi, Ding; Niu, Jingjing; Wu, Muhong; Lin, Li; Yin, Rongkang; Li, Mingqiang; Zhou, Jingyuan; Wang, Shaoxin; Sun, Junliang; Duan, Xiaojie; Gao, Peng; Jiang, Ying; Wu, Xiaosong; Peng, Hailin; Ruoff, Rodney S.; Liu, Zhongfan; Yu, Dapeng; Wang, Enge; Ding, Feng; Liu, Kaihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast epitaxial growth of metre-sized single-crystal graphene on industrial Cu foil", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A foundation of the modern technology that uses single-crystal silicon has been the growth of highquality single-crystal Si ingots with diameters up to 12 inches or larger. For many applications of graphene, large-area high-quality (ideally of single-crystal) material will be enabling. Since the first growth on copper foil a decade ago, inch-sized single-crystal graphene has been achieved. We present here the growth, in 20 min, of a graphene film of (5 x 50) cm(2) dimension with >99% ultra-highly oriented grains. This growth was achieved by: (1) synthesis of metre-sized single-crystal Cu(1 1 1) foil as substrate; (2) epitaxial growth of graphene islands on the Cu(1 1 1) surface; (3) seamless merging of such graphene islands into a graphene film with high single crystallinity and (4) the ultrafast growth of graphene film. These achievements were realized by a temperature-gradient-driven annealing technique to produce single-crystal Cu(1 1 1) from industrial polycrystalline Cu foil and the marvellous effects of a continuous oxygen supply from an adjacent oxide. The as-synthesized graphene film, with very few misoriented grains (if any), has a mobility up to similar to 23,000 cm(2) V-1 s(-1) at 4 K and room temperature sheet resistance of similar to 230 Omega/rectangle. It is very likely that this approach can be scaled up to achieve exceptionally large and high-quality graphene films with single crystallinity, and thus realize various industrial-level applications at a low cost. (C)2017 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 488, "Times Cited, All Databases": 530, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2017, "Volume": 62, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1074, "End Page": 1080, "Article Number": null, "DOI": "10.1016/j.scib.2017.07.005", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2017.07.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409432100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JZ; Zhang, HG; Samarakoon, W; Shan, WT; Cullen, DA; Karakalos, S; Chen, MJ; Gu, DM; More, KL; Wang, GF; Feng, ZX; Wang, ZB; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiazhan; Zhang, Hanguang; Samarakoon, Widitha; Shan, Weitao; Cullen, David A.; Karakalos, Stavros; Chen, Mengjie; Gu, Daming; More, Karren L.; Wang, Guofeng; Feng, Zhenxing; Wang, Zhenbo; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN4 Sites for Oxygen Reduction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "FeN4 moieties embedded in partially graphitized carbon are the most efficient platinum group metal free active sites for the oxygen reduction reaction in acidic proton-exchange membrane fuel cells. However, their formation mechanisms have remained elusive for decades because the Fe-N bond formation process always convolutes with uncontrolled carbonization and nitrogen doping during high-temperature treatment. Here, we elucidate the FeN4 site formation mechanisms through hosting Fe ions into a nitrogen-doped carbon followed by a controlled thermal activation. Among the studied hosts, the ZIF-8-derived nitrogen-doped carbon is an ideal model with well-defined nitrogen doping and porosity. This approach is able to deconvolute Fe-N bond formation from complex carbonization and nitrogen doping, which correlates Fe-N bond properties with the activity and stability of FeN4 sites as a function of the thermal activation temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2019, "Volume": 58, "Issue": 52, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18971, "End Page": 18980, "Article Number": null, "DOI": "10.1002/anie.201909312", "DOI Link": "http://dx.doi.org/10.1002/anie.201909312", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495516300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, N; Peng, XS; Xu, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Ning; Peng, Xinsheng; Xu, Zhiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Water Permeation in Graphene Oxide Membranes", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water transport through graphene-derived membranes has gained much interest recently due to its promising potential in filtration and separation applications. In this work, we explore water permeation in graphene oxide membranes using atomistic simulations and theoretical analysis, by considering flow through the interlayer gallery, expanded channels such as wrinkles of interedge spaces, and pores within the sheet. We find that, although flow enhancement can be established by nulloconfinement, fast water transport through pristine graphene channels is prohibited by a prominent side-pinning effect from capillaries formed within oxidized regions. We then discuss several flow enhancement mechanisms through the porous microstructures of graphene oxide membranes. These understandings are integrated into a complete picture to understand water permeation through the layer-by-layer and porous microstructure and can guide rational design of functional membranes for energy and environmental applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2014, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5877, "End Page": 5883, "Article Number": null, "DOI": "10.1021/am500777b", "DOI Link": "http://dx.doi.org/10.1021/am500777b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335086000066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grundner, S; Markovits, MAC; Li, G; Tromp, M; Pidko, EA; Hensen, EJM; Jentys, A; Sanchez-Sanchez, M; Lercher, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grundner, Sebastian; Markovits, Monica A. C.; Li, Guanna; Tromp, Moniek; Pidko, Evgeny A.; Hensen, Emiel J. M.; Jentys, Andreas; Sanchez-Sanchez, Maricruz; Lercher, Johannes A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-exchanged zeolites with mordenite structure mimic the nuclearity and reactivity of active sites in particulate methane monooxygenase, which are enzymes able to selectively oxidize methane to methanol. Here we show that the mordenite micropores provide a perfect confined environment for the highly selective stabilization of trinuclear copper-oxo clusters that exhibit a high reactivity towards activation of carbon-hydrogen bonds in methane and its subsequent transformation to methanol. The similarity with the enzymatic systems is also implied from the similarity of the reversible rearrangements of the trinuclear clusters occurring during the selective transformations of methane along the reaction path towards methanol, in both the enzyme system and copper-exchanged mordenite.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 618, "Times Cited, All Databases": 686, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7546, "DOI": "10.1038/ncomms8546", "DOI Link": "http://dx.doi.org/10.1038/ncomms8546", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357180100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, XZ; Jiang, ZL; Zhou, J; Liu, HJ; Zhou, DN; Shang, HS; Ni, XM; Peng, Z; Yang, F; Chen, WX; Qi, ZM; Wang, DS; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Xiaozhi; Jiang, Zhuoli; Zhou, Jing; Liu, Hengjie; Zhou, Danni; Shang, Huishan; Ni, Xingming; Peng, Zheng; Yang, Fan; Chen, Wenxing; Qi, Zeming; Wang, Dingsheng; Wang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Complementary Operando Spectroscopy identification of in-situ generated metastable charge-asymmetry Cu2-CuN3 clusters for CO2 reduction to ethanol", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-based materials can reliably convert carbon dioxide into multi-carbon products but they suffer from poor activity and product selectivity. The atomic structure-activity relationship of electrocatalysts for the selectivity is controversial due to the lacking of systemic multiple dimensions for operando condition study. Herein, we synthesized high-performance CO2RR catalyst comprising of CuO clusters supported on N-doped carbon nullosheets, which exhibited high C2+ products Faradaic efficiency of 73% including decent ethanol selectivity of 51% with a partial current density of 14.4 mA/cm(-2) at -1.1 V vs. RHE. We evidenced catalyst restructuring and tracked the variation of the active states under reaction conditions, presenting the atomic structure-activity relationship of this catalyst. Operando XAS, XANES simulations and Quasi-in-situ XPS analyses identified a reversible potential-dependent transformation from dispersed CuO clusters to Cu-2-CuN3 clusters which are the optimal sites. This cluster can't exist without the applied potential. The N-doping dispersed the reduced Cu-n clusters uniformly and maintained excellent stability and high activity with adjusting the charge distribution between the Cu atoms and N-doped carbon interface. By combining Operando FTIR and DFT calculations, it was recognized that the Cu-2-CuN3 clusters displayed charge-asymmetric sites which were intensified by CH3* adsorbing, beneficial to the formation of the high-efficiency asymmetric ethanol. Copper-based materials can convert carbon dioxide into multi-carbon products but suffer from poor activity and selectivity. Here, the authors report CuO clusters supported on nitrogen-doped carbon nullosheets for the reduction CO2-to-ethanol, and investigate the change in the catalytic sites while in operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1322, "DOI": "10.1038/s41467-022-29035-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29035-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767892300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, KZ; Zhao, DD; Guo, SJ; Zhang, X; Zhu, X; Guo, J; Lu, G; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kezhu; Zhao, Dandan; Guo, Shaojun; Zhang, Xu; Zhu, Xing; Guo, Jun; Lu, Gang; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient oxygen reduction catalysis by subnullometer Pt alloy nullowires", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The common knowledge is that Pt and Pt alloy nulloparticles (NPs) less than 2 nm are not desirable for oxygen reduction reaction (ORR). However, whether the same trend is expected in Pt-based nullowires (NWs) and nullo-plates remains questionable because there is no scalable approach to make such Pt nullostructures. We report a general approach for preparing subnullometer Pt alloy NWs with a diameter of only 4 to 5 atomic layer thickness, ranging from monometallic Pt NWs to bimetallic PtNi and PtCo NWs and to trimetallic PtNiCo NWs. In a sharp contrast to Pt alloy NPs, the subnullometer Pt alloy NWs demonstrate exceptional mass and specific activities of 4.20 A/mg and 5.11 mA/cm(2) at 0.9 V versus reversible hydrogen electrode (RHE), respectively, 32.3 and 26.9 times higher than those of the commercial Pt/C. Density functional theory simulations reveal that the enhanced ORR activities are attributed to the catalytically active sites on high-density (111) facets in the subnullometer Pt alloy NWs. They are also very stable under the ORR condition with negligible activity decay over the course of 30,000 cycles. Our work presents a new approach to maximize Pt catalytic efficiency with atomic level utilization for efficient heterogeneous catalysis and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601705", "DOI": "10.1126/sciadv.1601705", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601705", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397039500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holliday, S; Ashraf, RS; Wadsworth, A; Baran, D; Yousaf, SA; Nielsen, CB; Tan, CH; Dimitrov, SD; Shang, ZR; Gasparini, N; Alamoudi, M; Laquai, F; Brabec, CJ; Salleo, A; Durrant, JR; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holliday, Sarah; Ashraf, Raja Shahid; Wadsworth, Andrew; Baran, Derya; Yousaf, Syeda Amber; Nielsen, Christian B.; Tan, Ching-Hong; Dimitrov, Stoichko D.; Shang, Zhengrong; Gasparini, Nicola; Alamoudi, Maha; Laquai, Frederic; Brabec, Christoph J.; Salleo, Alberto; Durrant, James R.; McCulloch, Iain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed organic photovoltaics (OPV) offer the attractive prospect of low-cost, light-weight and environmentally benign solar energy production. The highest efficiency OPV at present use low-bandgap donor polymers, many of which suffer from problems with stability and synthetic scalability. They also rely on fullerene-based acceptors, which themselves have issues with cost, stability and limited spectral absorption. Here we present a new non-fullerene acceptor that has been specifically designed to give improved performance alongside the wide bandgap donor poly(3-hexylthiophene), a polymer with significantly better prospects for commercial OPV due to its relative scalability and stability. Thanks to the well-matched optoelectronic and morphological properties of these materials, efficiencies of 6.4% are achieved which is the highest reported for fullerene-free P3HT devices. In addition, dramatically improved air stability is demonstrated relative to other high-efficiency OPV, showing the excellent potential of this new material combination for future technological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1048, "Times Cited, All Databases": 1120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11585, "DOI": "10.1038/ncomms11585", "DOI Link": "http://dx.doi.org/10.1038/ncomms11585", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377909600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Attia, PM; Grover, A; Jin, N; Severson, KA; Markov, TM; Liao, YH; Chen, MH; Cheong, B; Perkins, N; Yang, Z; Herring, PK; Aykol, M; Harris, SJ; Braatz, RD; Ermon, S; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Attia, Peter M.; Grover, Aditya; Jin, Norman; Severson, Kristen A.; Markov, Todor M.; Liao, Yang-Hung; Chen, Michael H.; Cheong, Bryan; Perkins, Nicholas; Yang, Zi; Herring, Patrick K.; Aykol, Muratahan; Harris, Stephen J.; Braatz, Richard D.; Ermon, Stefano; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Closed-loop optimization of fast-charging protocols for batteries with machine learning", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneously optimizing many design parameters in time-consuming experiments causes bottlenecks in a broad range of scientific and engineering disciplines(1,2). One such example is process and control optimization for lithium-ion batteries during materials selection, cell manufacturing and operation. A typical objective is to maximize battery lifetime; however, conducting even a single experiment to evaluate lifetime can take months to years(3-5). Furthermore, both large parameter spaces and high sampling variability(3,6,7) necessitate a large number of experiments. Hence, the key challenge is to reduce both the number and the duration of the experiments required. Here we develop and demonstrate a machine learning methodology to efficiently optimize a parameter space specifying the current and voltage profiles of six-step, ten-minute fast-charging protocols for maximizing battery cycle life, which can alleviate range anxiety for electric-vehicle users(8,9). We combine two key elements to reduce the optimization cost: an early-prediction model(5), which reduces the time per experiment by predicting the final cycle life using data from the first few cycles, and a Bayesian optimization algorithm(10,11), which reduces the number of experiments by balancing exploration and exploitation to efficiently probe the parameter space of charging protocols. Using this methodology, we rapidly identify high-cycle-life charging protocols among 224 candidates in 16 days (compared with over 500 days using exhaustive search without early prediction), and subsequently validate the accuracy and efficiency of our optimization approach. Our closed-loop methodology automatically incorporates feedback from past experiments to inform future decisions and can be generalized to other applications in battery design and, more broadly, other scientific domains that involve time-intensive experiments and multi-dimensional design spaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2020, "Volume": 578, "Issue": 7795, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 397, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-1994-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-1994-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543762000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, CH; Arju, N; Kelp, G; Fan, JA; Dominguez, J; Gonzales, E; Tutuc, E; Brener, I; Shvets, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Chihhui; Arju, Nihal; Kelp, Glen; Fan, Jonathan A.; Dominguez, Jason; Gonzales, Edward; Tutuc, Emanuel; Brener, Igal; Shvets, Gennady", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spectrally selective chiral silicon metasurfaces based on infrared Fano resonullces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterials and metasurfaces represent a remarkably versatile platform for light manipulation, biological and chemical sensing, and nonlinear optics. Many of these applications rely on the resonullt nature of metamaterials, which is the basis for extreme spectrally selective concentration of optical energy in the near field. In addition, metamaterial-based optical devices lend themselves to considerable miniaturization because of their subwavelength features. This additional advantage sets metamaterials apart from their predecessors, photonic crystals, which achieve spectral selectivity through their long-range periodicity. Unfortunately, spectral selectivity of the overwhelming majority of metamaterials that are made of metals is severely limited by high plasmonic losses. Here we propose and demonstrate Fano-resonullt all-dielectric metasurfaces supporting optical resonullces with quality factors Q > 100 that are based on CMOS-compatible materials: silicon and its oxide. We also demonstrate that these infrared metasurfaces exhibit extreme planar chirality, opening exciting possibilities for efficient ultrathin circular polarizers and narrow-band thermal emitters of circularly polarized radiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3892, "DOI": "10.1038/ncomms4892", "DOI Link": "http://dx.doi.org/10.1038/ncomms4892", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337503800036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jacobsson, TJ; Correa-Baena, JP; Anaraki, EH; Philippe, B; Stranks, SD; Bouduban, MEF; Tress, W; Schenk, K; Teuscher, J; Moser, JE; Rensmo, H; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jacobsson, T. Jesper; Correa-Baena, Juan-Pablo; Anaraki, Elham Halvani; Philippe, Bertrand; Stranks, Samuel D.; Bouduban, Marine E. F.; Tress, Wolfgang; Schenk, Kurt; Teuscher, Joel; Moser, Jacques-E.; Rensmo, Hakan; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unreacted PbI2 as a Double-Edged Sword for Enhancing the Performance of Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskites have over the past few years attracted considerable interest as photo absorbers in PV applications with record efficiencies now reaching 22%. It has recently been found that not only the composition but also the precise stoichiometry is important for the device performance. Recent reports have, for example, demonstrated small amount of PbI2 in the perovskite films to be beneficial for the overall performance of both the standard perovskite, CH3NH3PbI3, as well as for the mixed perovskites (CH3NH3)(x)-(CH(NH2)(2))((1x))PbBryI(3y). In this work a broad range of characterization techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), photo electron spectroscopy (PES), transient absorption spectroscopy (TAS), UVvis, electroluminescence (EL), photoluminescence (PL), and confocal PL mapping have been used to further understand the importance of remnullt PbI2 in perovskite solar cells. Our best devices were over 18% efficient, and had in line with previous results a small amount of excess PbI2. For the PbI2-deficient samples, the photocurrent dropped, which could be attributed to accumulation of organic species at the grain boundaries, low charge carrier mobility, and decreased electron injection into the TiO2. The PbI2-deficient compositions did, however, also have advantages. The record V-oc was as high as 1.20 V and was found in PbI2-deficient samples. This was correlated with high crystal quality, longer charge carrier lifetimes, and high PL yields and was rationalized as a consequence of the dynamics of the perovskite formation. We further found the ion migration to be obstructed in the PbI2-deficient samples, which decreased the JV hysteresis and increased the photostability. PbI2-deficient synthesis conditions can thus be used to deposit perovskites with excellent crystal quality but with the downside of grain boundaries enriched in organic species, which act as a barrier toward current transport. Exploring ways to tune the synthesis conditions to give the high crystal quality obtained under PbI2-poor condition while maintaining the favorable grain boundary characteristics obtained under PbI2-rich conditions would thus be a strategy toward more efficiency devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 752, "Times Cited, All Databases": 804, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2016, "Volume": 138, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10331, "End Page": 10343, "Article Number": null, "DOI": "10.1021/jacs.6b06320", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b06320", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381715700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CL; Wang, HL; Wang, F; Li, TF; Xu, MJ; Wang, H; Wang, Z; Zhan, XW; Hu, WD; Shen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chenglong; Wang, Hailu; Wang, Fang; Li, Tengfei; Xu, Mengjian; Wang, Hao; Wang, Zhen; Zhan, Xiaowei; Hu, Weida; Shen, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast and broadband photodetectors based on a perovskite/organic bulk heterojunction for large-dynamic-range imaging", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskites peer into near-infrared Novel photodetectors developed by researchers in China provide imaging in the near-infrared (NIR) region with record-breaking efficiency and speed. A new class of semiconducting materials called organic-inorganic hybrid perovskites (OIHPs) display excellent optical and electrical properties for thin-film solar cells, LEDs and light detectors. To expand their detection range to NIR, which is useful for biomedical applications, OIHPs can be combined with structures called organic bulk-heterojunctions (BHJs). Now, Weida Hu, Liang Shen and co-workers at Jilin University, Chinese Academy of Sciences and Peking University have designed new OIHP-BHJ photodetectors that efficiently detect a wide range of both visible and NIR radiation. Their prototype sensors have ultra-fast response times of just 5.6 nulloseconds and remain sensitive even in low brightness, suggesting that they could accelerate the movement of OIHP devices from lab tests to commercial imaging. Organic-inorganic hybrid perovskite (OIHP) photodetectors that simultaneously achieve an ultrafast response and high sensitivity in the near-infrared (NIR) region are prerequisites for expanding current monitoring, imaging, and optical communication capbilities. Herein, we demonstrate photodetectors constructed by OIHP and an organic bulk heterojunction (BHJ) consisting of a low-bandgap nonfullerene and polymer, which achieve broadband response spectra up to 1 mu m with a highest external quantum efficiency of approximately 54% at 850 nm, an ultrafast response speed of 5.6 ns and a linear dynamic range (LDR) of 191 dB. High sensitivity, ultrafast speed and a large LDR are preeminent prerequisites for the practical application of photodetectors. Encouragingly, due to the high-dynamic-range imaging capacity, high-quality visible-NIR actual imaging is achieved by employing the OIHP photodetectors. We believe that state-of-the-art OIHP photodetectors can accelerate the translation of solution-processed photodetector applications from the laboratory to the imaging market.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1038/s41377-020-0264-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0264-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517904800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JD; Chen, CH; Qin, MK; Li, B; Lin, BB; Mao, Q; Yang, HB; Liu, B; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jiadong; Chen, Chunhong; Qin, Minkai; Li, Ben; Lin, Binbin; Mao, Qing; Yang, Hongbin; Liu, Bin; Wang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble metal electrocatalysts (e.g., Pt, Ru, etc.) suffer from sluggish kinetics of water dissociation for the electrochemical reduction of water to molecular hydrogen in alkaline and neutral pH environments. Herein, we found that an integration of Ru nulloparticles (NPs) on oxygen-deficient WO3-x manifested a 24.0-fold increase in hydrogen evolution reaction (HER) activity compared with commercial Ru/C electrocatalyst in neutral electrolyte. Oxygen-deficient WO3-x is shown to possess large capacity for storing protons, which could be transferred to the Ru NPs under cathodic potential. This significantly increases the hydrogen coverage on the surface of Ru NPs in HER and thus changes the rate-determining step of HER on Ru from water dissociation to hydrogen recombination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5382, "DOI": "10.1038/s41467-022-33007-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33007-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853935100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Si, MW; Saha, AK; Gao, SJ; Qiu, G; Qin, JK; Duan, YQ; Jian, J; Niu, C; Wang, HY; Wu, WZ; Gupta, SK; Ye, PDD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Si, Mengwei; Saha, Atanu K.; Gao, Shengjie; Qiu, Gang; Qin, Jingkai; Duan, Yuqin; Jian, Jie; Niu, Chang; Wang, Haiyan; Wu, Wenzhuo; Gupta, Sumeet K.; Ye, Peide D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A ferroelectric semiconductor field-effect transistor", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectric field-effect transistors employ a ferroelectric material as a gate insulator, the polarization state of which can be detected using the channel conductance of the device. As a result, the devices are potentially of use in non-volatile memory technology, but they suffer from short retention times, which limits their wider application. Here, we report a ferroelectric semiconductor field-effect transistor in which a two-dimensional ferroelectric semiconductor, indium selenide (alpha-In2Se3), is used as the channel material in the device. alpha-In2Se3 was chosen due to its appropriate bandgap, room-temperature ferroelectricity, ability to maintain ferroelectricity down to a few atomic layers and its potential for large-area growth. A passivation method based on the atomic layer deposition of aluminium oxide (Al2O3) was developed to protect and enhance the performance of the transistors. With 15-nm-thick hafnium oxide (HfO2) as a scaled gate dielectric, the resulting devices offer high performance with a large memory window, a high on/off ratio of over 10(8), a maximum on current of 862 mu A mu m(-1) and a low supply voltage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 484, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 580, "End Page": 586, "Article Number": null, "DOI": "10.1038/s41928-019-0338-7", "DOI Link": "http://dx.doi.org/10.1038/s41928-019-0338-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512908500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kittner, N; Lill, F; Kammen, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kittner, Noah; Lill, Felix; Kammen, Daniel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy storage deployment and innovation for the clean energy transition", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The clean energy transition requires a co-evolution of innovation, investment, and deployment strategies for emerging energy storage technologies. A deeply decarbonized energy system research platform needs materials science advances in battery technology to overcome the intermittency challenges of wind and solar electricity. Simultaneously, policies designed to build market growth and innovation in battery storage may complement cost reductions across a suite of clean energy technologies. Further integration of R&D and deployment of new storage technologies paves a clear route toward cost-effective low-carbon electricity. Here we analyse deployment and innovation using a two-factor model that integrates the value of investment in materials innovation and technology deployment over time from an empirical dataset covering battery storage technology. Complementary advances in battery storage are of utmost importance to decarbonization alongside improvements in renewable electricity sources. We find and chart a viable path to dispatchable US$1W(-)1 solar with US$100kWh(-1) battery storage that enables combinations of solar, wind, and storage to compete directly with fossil-based electricity options.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 806, "Times Cited, All Databases": 874, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17125, "DOI": "10.1038/nenergy.2017.125", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.125", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415189100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Darmanin, T; Guittard, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Darmanin, Thierry; Guittard, Frederic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superhydrophobic and superoleophobic properties in nature", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this review, we report on superhydrophobic and superoleophobic properties found in nature, which are strongly expected to benefit various potential applications. Mimicry of nature is the easiest way to reproduce such properties because nature has for millennia produced plants, insects and animals able to repel water as well as low surface tension liquids such as oils. The most famous example is the lotus leaf, but we may also consider insects able to walk on vertical surfaces or on the water surface, insects with colored structured wings or insects with antifogging and anti-reflective eyes. Most of the time, nature produces nullostructured waxes to obtain superhydrophobic properties. Very recently, the repellency of oils has been reported in springtails, for example. While several publications have reported the fabrication of superoleophobic surfaces using re-entrant geometry, in all of these publications fluorinated compounds were used because they have high hydrophobic properties but also relatively important oleophobic properties in comparison to hydrocarbon analogs even if they are intrinsically oleophilic. However, nature is not able to synthesize fluorinated compounds. In the case of the springtails, the surface structures consists of regular patterns with negative overhangs. The chemical composition of the cuticles is composed of three different layers: an inner cuticle layer made of a lamellar chitin skeleton with numerous pore channels, an epicuticular structures made of structural proteins such glycine (more than 50%), tyrosine and serine an the topmost envelope composed of lipids such as hydrocarbon acids and esters, steroids and terpenes. This discovery will help the scientific community to create superoleophobic materials without the use of fluorinated compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 588, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 18, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 273, "End Page": 285, "Article Number": null, "DOI": "10.1016/j.mattod.2015.01.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.01.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354392300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, RX; Faghaninia, A; Soklaski, R; Yan, JA; Lo, C; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Ruixiang; Faghaninia, Alireza; Soklaski, Ryan; Yan, Jia-An; Lo, Cynthia; Yang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Thermoelectric Efficiency via Orthogonal Electrical and Thermal Conductances in Phosphorene", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric devices that utilize the Seebeck effect convert heat flow into electrical energy and are highly desirable for the development of portable, solid state, passively powered electronic systems. The conversion efficiencies of such devices are quantified by the dimensionless thermoelectric figure of merit (ZT), which is proportional to the ratio of a devices electrical conductance to its thermal conductance. In this paper, a recently fabricated two-dimensional (2D) semiconductor called phosphorene (monolayer black phosphorus) is assessed for its thermoelectric capabilities. First-principles and model calculations reveal not only that phosphorene possesses a spatially anisotropic electrical conductance, but that its lattice thermal conductance exhibits a pronounced spatial-anisotropy as well. The prominent electrical and thermal conducting directions are orthogonal to one another, enhancing the ratio of these conductances. As a result, ZT may reach the criterion for commercial deployment along the armchair direction of phosphorene at T = 500 K and is close to 1 even at room temperature given moderate doping (similar to 2cx 10(16) m(-2) or 2 x10(12) cm(-2)). Ultimately, phosphorene hopefully stands out as an environmentally sound thermoelectric material with unprecedented qualities. Intrinsically, it is a mechanically flexible material that converts heat energy with high efficiency at low temperatures (similar to 300 K), one whose performance does not require any sophisticated engineering techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 691, "Times Cited, All Databases": 735, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6393, "End Page": 6399, "Article Number": null, "DOI": "10.1021/nl502865s", "DOI Link": "http://dx.doi.org/10.1021/nl502865s", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345723800057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JC; Dong, PF; Dang, K; Zhang, YN; Yan, QL; Xiang, H; Su, J; Liu, ZH; Si, MW; Gao, JC; Kong, MF; Zhou, H; Hao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jincheng; Dong, Pengfei; Dang, Kui; Zhang, Yanni; Yan, Qinglong; Xiang, Hu; Su, Jie; Liu, Zhihong; Si, Mengwei; Gao, Jiacheng; Kong, Moufu; Zhou, Hong; Hao, Yue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-wide bandgap semiconductor Ga2O3 power diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-wide bandgap semiconductor Ga2O3 based electronic devices are expected to perform beyond wide bandgap counterparts GaN and SiC. However, the reported power figure-of-merit hardly can exceed, which is far below the projected Ga2O3 material limit. Major obstacles are high breakdown voltage requires low doping material and PN junction termination, contradicting with low specific on-resistance and simultaneous achieving of n- and p-type doping, respectively. In this work, we demonstrate that Ga2O3 heterojunction PN diodes can overcome above challenges. By implementing the holes injection in the Ga2O3, bipolar transport can induce conductivity modulation and low resistance in a low doping Ga2O3 material. Therefore, breakdown voltage of 8.32 kV, specific on-resistance of 5.24 m Omega.cm(2), power figure-of-merit of 13.2 GW/cm(2), and turn-on voltage of 1.8 V are achieved. The power figure-of-merit value surpasses the 1-D unipolar limit of GaN and SiC. Those Ga2O3 power diodes demonstrate their great potential for next-generation power electronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3900, "DOI": "10.1038/s41467-022-31664-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31664-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821634700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XY; Xie, J; Chen, XB; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xinyong; Xie, Jun; Chen, Xiaobo; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering MPx (M = Fe, Co or Ni) interface electron transfer channels for boosting photocatalytic H2 evolution over g-C3N4/MoS2 layered heterojunctions", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is challenging to develop highly efficient, multifunctional and low-cost cocatalysts to accelerate transfer, separation and utilization of charge carriers for fundamentally boosting photocatalytic H-2 evolution. So far, the famous metallic MPx (M = Fe, Co or Ni) H-2-evolution cocatalyst have never been used as interface electron transfer channels between semiconductors and cocatalysts. Herein, we, for the first time, demonstrated that metal phosphide (MP) cocatalyts could be used as an interface electronic bridge to greatly enhance the photocatalytic H-2 evolution over 2D/2D g-C3N4/MoS2 layered heterojunctions. The results clearly prove that Ni2P could serve as much better interface electron transfer channel than CoP and Fe2P. The highest hydrogen production rate of ternary g-C3N4-1%Ni2P-1.5%MoS2 could reach 532.41 mu molg(-1)h(-1), which was 2.47 and 5.15 times than those of g-C3N4-1.5%MoS2 and g-C3N4-1%Ni2P, respectively. More importantly, the bi-functional roles of MP cocatalyts in boosting photocatalytic H-2 evolution were also carefully revealed. Apparently, the metallic MP cocatalyts could not only serve as normal cocatalysts to boost the H-2-evolution kinetics through decreasing the overpotential, but also can act as excellent interface electron transfer channels to achieve efficient transfer of more electrons from g-C3N4 to the surface active sites of MoS2, thus synergistically leading to the significantly boosted H-2 evolution. This work would open up opportunities to develop high-efficiency and low-cost photocatalytic system using the rationally designed metallic earth-abundant cocatalysts as the interface electron bridge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2019, "Volume": 252, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 259, "Article Number": null, "DOI": "10.1016/j.apcatb.2019.04.012", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2019.04.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469906200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, RF; Zhang, QL; Gao, W; Pei, A; Ren, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Renfeng; Zhang, Qilu; Gao, Wei; Pei, Allen; Ren, Biye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Light-Driven TiO2-Au Janus Micromotors", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A highly efficient light-driven photocatalytic TiO2-Au Janus micromotor with wireless steering and velocity control is described. Unlike chemically propelled micromotors which commonly require the addition of surfactants or toxic chemical fuels, the fuel-free Janus micromotor (diameter similar to 1.0 mu m) can be powered in pure water under an extremely low ultraviolet light intensity (2.5 x 10(-3) W/cm(2)), and with 40 x 10(-3) W/cm(2), they can reach a high speed of 25 body length/s, which is comparable to common Pt-based chemically induced self-electrophoretic Janus micromotors. The photocatalytic propulsion can be switched on and off by incident light modulation. In addition, the speed of the photo catalytic TiO2-Au Janus micromotor can be accelerated by increasing the light intensity or by adding low concentrations of chemical fuel H2O2 (i.e., 0.1%). The attractive fuel-free propulsion performance, fast movement triggering response, low light energy requirement, and precise motion control of the TiO2-Au Janus photocatalytic micromotor hold considerable promise for diverse practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 839, "End Page": 844, "Article Number": null, "DOI": "10.1021/acsnullo.5b05940", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b05940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369115800091", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JZ; Dai, YF; Singewald, K; Liu, CC; Saxena, S; Zhang, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jianzhi; Dai, Yifan; Singewald, Kevin; Liu, Chung-Chiun; Saxena, Sunil; Zhang, Huichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of MnO2 of different structures on activation of peroxymonosulfate for bisphenol A degradation under acidic conditions", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MnO2 with various structures, including three tunnel structures (alpha-, 1 beta-, gamma-MnO2) and a layered structure (MnO2), were synthesized and investigated for peroxymonosulfate (PMS) activation. The effects of different structured MnO2 on PMS activation in contaminullt degradation, as quantified by the pseudo-first order rate constants of bisphenol A (BPA) oxidation, followed the order: alpha-MnO2> gamma-MnO2> beta-MnO2> delta-MnO2. Results showed that under acidic conditions, BPA was degraded by both catalytic oxidation by PMS-MnO2 and direct oxidation by MnO2, and the relative importance of the two mechanisms differed for different MnO2. The direct oxidation accounted for 25.2, 7.4, 34.1, and 94.5% of the total reactivity of alpha-, beta-, gamma-, and delta-MnO2, respectively. Physicochemical properties of MnO2 including crystal structure, morphology, surface Mn oxidation states, surface area, oxygen species and conductivity were characterized and correlated with the catalytic reactivity. The results demonstrated that the crystallinity of MnO2 was the dominullt factor in the catalytic reactivity, resulting in the lowest reactivity for the least crystalline delta-MnO2. For the crystalline MnO2, the catalytic reactivity linearly correlated with Mn average oxidation state, Mn(III) content, and conductivity. Electron spin resonullce (ESR) and quenching experiments with ethanol and tert-butanol suggested that sulfate radicals (SO4 center dot-) were the dominullt radicals in the systems, while hydroxyl radicals (OH) played a minor role. In addition, nonradical mechanisms such as singlet oxygen (O-1(2)) also contributed to the BPA degradation, especially when delta-MnO2 was the catalyst. These findings offered new insights into the contaminullt degradation mechanisms in PMS-MnO2 and provided guidance to develop cost-effective catalysts for water/wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2019, "Volume": 370, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 906, "End Page": 915, "Article Number": null, "DOI": "10.1016/j.cej.2019.03.238", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.03.238", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467387200133", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JM; Wang, CL; Wang, H; Hu, XF; Matios, E; Lu, X; Zhang, WK; Tao, XY; Li, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jianmin; Wang, Chuanlong; Wang, Huan; Hu, Xiaofei; Matios, Edward; Lu, Xuan; Zhang, Wenkui; Tao, Xinyong; Li, Weiyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pillared MXene with Ultralarge Interlayer Spacing as a Stable Matrix for High Performance Sodium Metal Anodes", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium (Na) metal is a promising alternative to lithium metal as an anode material for the next-generation energy storage systems due to its high theoretical capacity, low cost, and natural abundance. However, dendritic/mossy Na growth caused by uncontrollable plating/stripping results in serious safe concerns and rapid electrode degradation. This study presents Sn2+ pillared Ti3C2 MXene serving as a stable matrix for high-performance dendrite-free Na metal anode. The intercalated Sn2+ between Ti3C2 layers not only induces Na to nucleate and grow within Ti3C2 interlayers, but also endows the Ti3C2 with larger interlayer space to accommodate the deposited Na by taking advantage of the pillar effect, contributing to uniform Na deposition. As a result, the pillar-structured MXene-based Na metal electrode could enable high current density (up to 10 mA cm(-2)) along with high areal capacity (up to 5 mAh cm(-2)) over long-term cycling (up to 500 cycles). The full cell using MXene-based Na metal anode exhibits superior electrochemical performance than that using host-less commercial Na. It is believed that the well-controlled MXene-based Na anode not only extends the application scope of MXene, but also provides guidance in designing high-performance Na metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 29, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805946, "DOI": "10.1002/adfm.201805946", "DOI Link": "http://dx.doi.org/10.1002/adfm.201805946", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459625400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, KW; Yang, LM; Wang, X; Guo, LP; Cheng, G; Zhang, C; Jin, SB; Tan, B; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kewei; Yang, Li-Ming; Wang, Xi; Guo, Liping; Cheng, Guang; Zhang, Chun; Jin, Shangbin; Tan, Bien; Cooper, Andrew", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent Triazine Frameworks via a Low-Temperature Polycondensation Approach", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent triazine frameworks (CTFs) are normally synthesized by ionothermal methods. The harsh synthetic conditions and associated limited structural diversity do not benefit for further development and practical large-scale synthesis of CTFs. Herein we report a new strategy to construct CTFs (CTF-HUSTs) via a polycondensation approach, which allows the synthesis of CTFs under mild conditions from a wide array of building blocks. Interestingly, these CTFs display a layered structure. The CTFs synthesized were also readily scaled up to gram quantities. The CTFs are potential candidates for separations, photocatalysis and for energy storage applications. In particular, CTF-HUSTs are found to be promising photocatalysts for sacrificial photocatalytic hydrogen evolution with a maximum rate of 2647 mu mol h(-1) g(-1) under visible light. We also applied a pyrolyzed form of CTF-HUST-4 as an anode material in a sodiumion battery achieving an excellent discharge capacity of 467 mAh g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 488, "Times Cited, All Databases": 512, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2017, "Volume": 56, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14149, "End Page": 14153, "Article Number": null, "DOI": "10.1002/anie.201708548", "DOI Link": "http://dx.doi.org/10.1002/anie.201708548", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413896400042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tchalala, MR; Bhatt, PM; Chappanda, KN; Tavares, SR; Adil, K; Belmabkhout, Y; Shkurenko, A; Cadiau, A; Heymans, N; De Weireld, G; Maurin, G; Salama, KN; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tchalala, M. R.; Bhatt, P. M.; Chappanda, K. N.; Tavares, S. R.; Adil, K.; Belmabkhout, Y.; Shkurenko, A.; Cadiau, A.; Heymans, N.; De Weireld, G.; Maurin, G.; Salama, K. N.; Eddaoudi, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional SO2 scrubbing agents, namely calcium oxide and zeolites, are often used to remove SO2 using a strong or irreversible adsorption-based process. However, adsorbents capable of sensing and selectively capturing this toxic molecule in a reversible manner, with in-depth understanding of structure-property relationships, have been rarely explored. Here we report the selective removal and sensing of SO2 using recently unveiled fluorinated metal-organic frameworks (MOFs). Mixed gas adsorption experiments were performed at low concentrations ranging from 250 p.p.m. to 7% of SO2. Direct mixed gas column breakthrough and/or column desorption experiments revealed an unprecedented SO2 affinity for KAUST-7 (NbOFFIVE-1-Ni) and KAUST-8 (AlFFIVE-1-Ni) MOFs. Furthermore, MOF-coated quartz crystal microbalance transducers were used to develop sensors with the ability to detect SO2 at low concentrations ranging from 25 to 500 p.p.m.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1328, "DOI": "10.1038/s41467-019-09157-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09157-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461995000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GR; Rivarola, FWR; Davis, NJLK; Bai, S; Jellicoe, TC; de la Peña, F; Hou, SC; Ducati, C; Gao, F; Friend, RH; Greenham, NC; Tan, ZK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guangru; Rivarola, Florencia Wisnivesky Rocca; Davis, Nathaniel J. L. K.; Bai, Sai; Jellicoe, Tom C.; de la Pena, Francisco; Hou, Shaocong; Ducati, Caterina; Gao, Feng; Friend, Richard H.; Greenham, Neil C.; Tan, Zhi-Kuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Perovskite nullocrystal Light-Emitting Diodes Enabled by a Universal Crosslinking Method", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The preparation of highly efficient perovskite nullocrystal light-emitting diodes is shown. A new trimethylaluminum vapor-based crosslinking method to render the nullocrystal films insoluble is applied. The resulting near-complete nullocrystal film coverage, coupled with the natural confinement of injected charges within the perovskite crystals, facilitates electron-hole capture and give rise to a remarkable electroluminescence yield of 5.7%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 824, "Times Cited, All Databases": 882, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2016, "Volume": 28, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3528, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201600064", "DOI Link": "http://dx.doi.org/10.1002/adma.201600064", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376250600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, S; Fei, Z; Ma, Q; Rodin, AS; Wagner, M; McLeod, AS; Liu, MK; Gannett, W; Regan, W; Watanabe, K; Taniguchi, T; Thiemens, M; Dominguez, G; Neto, AHC; Zettl, A; Keilmann, F; Jarillo-Herrero, P; Fogler, MM; Basov, DN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, S.; Fei, Z.; Ma, Q.; Rodin, A. S.; Wagner, M.; McLeod, A. S.; Liu, M. K.; Gannett, W.; Regan, W.; Watanabe, K.; Taniguchi, T.; Thiemens, M.; Dominguez, G.; Castro Neto, A. H.; Zettl, A.; Keilmann, F.; Jarillo-Herrero, P.; Fogler, M. M.; Basov, D. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Phonon Polaritons in Atomically Thin van der Waals Crystals of Boron Nitride", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "van der Waals heterostructures assembled from atomically thin crystalline layers of diverse two-dimensional solids are emerging as a new paradigm in the physics of materials. We used infrared nulloimaging to study the properties of surface phonon polaritons in a representative van der Waals crystal, hexagonal boron nitride. We launched, detected, and imaged the polaritonic waves in real space and altered their wavelength by varying the number of crystal layers in our specimens. The measured dispersion of polaritonic waves was shown to be governed by the crystal thickness according to a scaling law that persists down to a few atomic layers. Our results are likely to hold true in other polar van der Waals crystals and may lead to new functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 984, "Times Cited, All Databases": 1099, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2014, "Volume": 343, "Issue": 6175, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1125, "End Page": 1129, "Article Number": null, "DOI": "10.1126/science.1246833", "DOI Link": "http://dx.doi.org/10.1126/science.1246833", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332331500045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HJ; Zhai, YM; Li, Y; Cao, Y; Shi, BB; Li, RL; Zhu, ZT; Jiang, HF; Guo, ZY; Wang, MD; Chen, L; Liu, YW; Zhou, KG; Pan, FS; Jiang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hongjian; Zhai, Yeming; Li, Yang; Cao, Yu; Shi, Benbing; Li, Runlai; Zhu, Zingting; Jiang, Haifei; Guo, Zheyuan; Wang, Meidi; Chen, Long; Liu, Yawei; Zhou, Kai-Ge; Pan, Fusheng; Jiang, Zhongyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent organic framework membranes for efficient separation of monovalent cations", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COF), with rigid, highly ordered and tunable structures, can actively manipulate the synergy of entropic selectivity and enthalpic selectivity, holding great potential as next-generation membrane materials for ion separations. Here, we demonstrated the efficient separation of monovalent cations by COF membrane. The channels of COF membrane are decorated with three different kinds of acid groups. A concept of confined cascade separation was proposed to elucidate the separation process. The channels of COF membrane comprised two kinds of domains, acid-domains and acid-free-domains. The acid-domains serve as confined stages, rendering high selectivity, while the acid-free-domains preserve the pristine channel size, rendering high permeation flux. A set of descriptors of stage properties were designed to elucidate their effect on selective ion transport behavior. The resulting COF membrane acquired high ion separation performances, with an actual selectivity of 4.2-4.7 for K+/Li+ binary mixtures and an ideal selectivity of similar to 13.7 for K+/Li+.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7123, "DOI": "10.1038/s41467-022-34849-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-34849-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000886221900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Treat, NJ; Sprafke, H; Kramer, JW; Clark, PG; Barton, BE; de Alaniz, JR; Fors, BP; Hawker, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Treat, Nicolas J.; Sprafke, Hazel; Kramer, John W.; Clark, Paul G.; Barton, Bryan E.; de Alaniz, Javier Read; Fors, Brett P.; Hawker, Craig J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Free Atom Transfer Radical Polymerization", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Significantly, block copolymer formation was facile and could be combined with other controlled radical processes leading to structural and synthetic versatility. We believe that these new organic-based photoredox catalysts will enable new applications for controlled radical polymerizations and also be of further value in both small molecule and polymer chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 777, "Times Cited, All Databases": 858, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2014, "Volume": 136, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16096, "End Page": 16101, "Article Number": null, "DOI": "10.1021/ja510389m", "DOI Link": "http://dx.doi.org/10.1021/ja510389m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344906100049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, PP; Li, YY; Wang, AQ; Tan, R; Liu, YH; Liang, X; Sheng, FM; Tang, GG; Ge, L; Wu, L; Song, QL; McKeown, NB; Yang, ZJ; Xu, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Peipei; Li, Yuanyuan; Wang, Anqi; Tan, Rui; Liu, Yahua; Liang, Xian; Sheng, Fangmeng; Tang, Gonggen; Ge, Liang; Wu, Liang; Song, Qilei; McKeown, Neil B.; Yang, Zhengjin; Xu, Tongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfonated Microporous Polymer Membranes with Fast and Selective Ion Transport for Electrochemical Energy Conversion and Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membranes which allow fast and selective transport of protons and cations are required for a wide range of electrochemical energy conversion and storage devices, such as proton-exchange membrane (PEM) fuel cells (PEMFCs) and redox flow batteries (RFBs). Herein we report a new approach to designing solution-processable ion-selective polymer membranes with both intrinsic microporosity and ion-conductive functionality. Polymers are synthesized with rigid and contorted backbones, which incorporate hydrophobic fluorinated and hydrophilic sulfonic acid functional groups, to produce membranes with negatively charged subnullometer-sized confined ionic channels. The ready transport of protons and cations through these membranes, and the high selectivity towards nullometer-sized redox-active molecules, enable efficient and stable operation of an aqueous alkaline quinone redox flow battery and a hydrogen PEM fuel cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2020, "Volume": 59, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9564, "End Page": 9573, "Article Number": null, "DOI": "10.1002/anie.202000012", "DOI Link": "http://dx.doi.org/10.1002/anie.202000012", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522516700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eaton, SW; Lai, ML; Gibson, NA; Wong, AB; Dou, LT; Ma, J; Wang, LW; Leone, SR; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.; Wong, Andrew B.; Dou, Letian; Ma, Jie; Wang, Lin-Wang; Leone, Stephen R.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lasing in robust cesium lead halide perovskite nullowires", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapidly growing field of nulloscale lasers can be advanced through the discovery of new, tunable light sources. The emission wavelength tunability demonstrated in perovskite materials is an attractive property for nulloscale lasers. Whereas organic-inorganic lead halide perovskite materials are known for their instability, cesium lead halides offer a robust alternative without sacrificing emission tunability or ease of synthesis. Here, we report the low-temperature, solution-phase growth of cesium lead halide nullowires exhibiting low-threshold lasing and high stability. The as-grown nullowires are single crystalline with well-formed facets, and act as high-quality laser cavities. The nullowires display excellent stability while stored and handled under ambient conditions over the course of weeks. Upon optical excitation, Fabry-Perot lasing occurs in CsPbBr3 nullowires with an onset of 5 mu J cm(-2) with the nullowire cavity displaying a maximum quality factor of 1,009 +/- 5. Lasing under constant, pulsed excitation can be maintained for over 1 h, the equivalent of 109 excitation cycles, and lasing persists upon exposure to ambient atmosphere. Wavelength tunability in the green and blue regions of the spectrum in conjunction with excellent stability makes these nullowire lasers attractive for device fabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 695, "Times Cited, All Databases": 759, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2016, "Volume": 113, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1993, "End Page": 1998, "Article Number": null, "DOI": "10.1073/pnas.1600789113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1600789113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370620300034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feig, VR; Tran, H; Lee, M; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feig, Vivian R.; Tran, Helen; Lee, Minah; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically tunable conductive interpenetrating network hydrogels that mimic the elastic moduli of biological tissue", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive and stretchable materials that match the elastic moduli of biological tissue (0.5-500 kPa) are desired for enhanced interfacial and mechanical stability. Compared with inorganic and dry polymeric conductors, hydrogels made with conducting polymers are promising soft electrode materials due to their high water content. Nevertheless, most conducting polymer-based hydrogels sacrifice electronic performance to obtain useful mechanical properties. Here we report a method that overcomes this limitation using two interpenetrating hydrogel networks, one of which is formed by the gelation of the conducting polymer PEDOT: PSS. Due to the connectivity of the PEDOT: PSS network, conductivities up to 23 Sm-1 are achieved, a record for stretchable PEDOT: PSS-based hydrogels. Meanwhile, the low concentration of PEDOT:PSS enables orthogonal control over the composite mechanical properties using a secondary polymer network. We demonstrate tunability of the elastic modulus over three biologically relevant orders of magnitude without compromising stretchability (> 100%) or conductivity (> 10 Sm-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 483, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2740, "DOI": "10.1038/s41467-018-05222-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05222-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438683100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chandrasekaran, S; Hu, R; Yao, L; Sui, LJ; Liu, YP; Abdelkader, A; Li, YL; Ren, XZ; Deng, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chandrasekaran, Sundaram; Hu, Rong; Yao, Lei; Sui, Lijun; Liu, Yongping; Abdelkader, Amor; Li, Yongliang; Ren, Xiangzhong; Deng, Libo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mutual Self-Regulation of d-Electrons of Single Atoms and Adjacent nulloparticles for Bifunctional Oxygen Electrocatalysis and Rechargeable Zinc-Air Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable zinc-air batteries (ZABs) are a promising energy conversion device, which rely critically on electrocatalysts to accelerate their rate-determining reactions such as oxygen reduction (ORR) and oxygen evolution reactions (OER). Herein, we fabricate a range of bifunctional M-N-C (metal-nitrogen-carbon) catalysts containing M-Nx coordination sites and M/MxC nulloparticles (M = Co, Fe, and Cu) using a new class of gamma-cyclodextrin (CD) based metal-organic framework as the precursor. With the two types of active sites interacting with each other in the catalysts, the obtained Fe@C-FeNC and Co@C-CoNC display superior alkaline ORR activity in terms of low half-wave (E-1/2) potential (similar to 0.917 and 0.906 V, respectively), which are higher than Cu@C-CuNC (similar to 0.829 V) and the commercial Pt/C (similar to 0.861 V). As a bifunctional electrocatalyst, the Co@C-CoNC exhibits the best performance, showing a bifunctional ORR/OER overpotential (Delta E) of similar to 0.732 V, which is much lower than that of Fe@C-FeNC (similar to 0.831 V) and Cu@C-CuNC (similar to 1.411 V), as well as most of the robust bifunctional electrocatalysts reported to date. Synchrotron X-ray absorption spectroscopy and density functional theory simulations reveal that the strong electronic correlation between metallic Co nulloparticles and the atomic Co-N-4 sites in the Co@C-CoNC catalyst can increase the d-electron density near the Fermi level and thus effectively optimize the adsorption/desorption of intermediates in ORR/OER, resulting in an enhanced bifunctional electrocatalytic performance. The Co@C-CoNC-based rechargeable ZAB exhibited a maximum power density of 162.80 mW cm(-2) at 270.30 mA cm(-2), higher than the combination of commercial Pt/C + RuO2 (similar to 158.90 mW cm(-2) at 265.80 mA cm(-2)) catalysts. During the galvanostatic discharge at 10 mA cm(-2), the ZAB delivered an almost stable discharge voltage of 1.2 V for similar to 140 h, signifying the virtue of excellent bifunctional ORR/OER electrocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 48, "DOI": "10.1007/s40820-023-01022-8", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01022-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930001600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Mao, JF; Pang, WK; Zheng, T; Sencadas, V; Chen, YZ; Liu, YJ; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qing; Mao, Jianfeng; Pang, Wei Kong; Zheng, Tian; Sencadas, Vitor; Chen, Yuanzhen; Liu, Yajie; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting the Potassium Storage Performance of Alloy-Based Anode Materials via Electrolyte Salt Chemistry", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (PIBs) are promising energy storage systems because of the abundance and low cost of potassium. The formidable challenge is to develop suitable electrode materials and electrolytes for accommodating the relatively large size and high activity of potassium. Herein, Bi-based materials are reported as novel anodes for PIBs. nullostructural design and proper selection of the electrolyte salt have been used to achieve excellent cycling performance. It is found that the potassiation of Bi undergoes a solid-solution reaction, followed by two typical two-phase reactions, corresponding to Bi <-> Bi(K) and Bi(K) <-> K5Bi4 <-> K3Bi, respectively. By choosing potassium bis(fluorosulfonyl)imide (KFSI) to replace potassium hexafluorophosphate (KPF6) in carbonate electrolyte, a more stable solid electrolyte interphase layer is achieved and results in notably enhanced electrochemical performance. More importantly, the KFSI salt is very versatile and can significantly promote the electrochemical performance of other alloy-based anode materials, such as Sn and Sb.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2018, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703288, "DOI": "10.1002/aenm.201703288", "DOI Link": "http://dx.doi.org/10.1002/aenm.201703288", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434031400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, HY; Du, XF; Zhao, JW; Wang, YT; Ju, JW; Chen, Z; Hu, ZL; Yan, DP; Zhou, XH; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Huayu; Du, Xiaofan; Zhao, Jingwen; Wang, Yantao; Ju, Jiangwei; Chen, Zheng; Hu, Zhenglin; Yan, Dongpeng; Zhou, Xinhong; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface chemistry of solid electrolyte interphase is one of the critical factors that govern the cycling life of rechargeable batteries. However, this chemistry is less explored for zinc anodes, owing to their relatively high redox potential and limited choices in electrolyte. Here, we report the observation of a zinc fluoride-rich organic/inorganic hybrid solid electrolyte interphase on zinc anode, based on an acetamide-Zn(TFSI)(2) eutectic electrolyte. A combination of experimental and modeling investigations reveals that the presence of anioncomplexing zinc species with markedly lowered decomposition energies contributes to the in situ formation of an interphase. The as-protected anode enables reversible (similar to 100% Coulombic efficiency) and dendrite-free zinc plating/stripping even at high areal capacities (>2.5 mAh cm(-2)), endowed by the fast ion migration coupled with high mechanical strength of the protective interphase. With this interphasial design the assembled zinc batteries exhibit excellent cycling stability with negligible capacity loss at both low and high rates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 716, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5374, "DOI": "10.1038/s41467-019-13436-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13436-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498795200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, HL; Su, Y; Zhang, BS; Lee, AF; Isaacs, MA; Wilson, K; Li, L; Ren, YG; Huang, JH; Haruta, M; Qiao, BT; Liu, X; Jin, CZ; Su, DS; Wang, JH; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Hailian; Su, Yang; Zhang, Bingsen; Lee, Adam F.; Isaacs, Mark A.; Wilson, Karen; Li, Lin; Ren, Yuegong; Huang, Jiahui; Haruta, Masatake; Qiao, Botao; Liu, Xin; Jin, Changzi; Su, Dangsheng; Wang, Junhu; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Classical strong metal-support interactions between gold nulloparticles and titanium dioxide", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supported metal catalysts play a central role in the modern chemical industry but often exhibit poor on-stream stability. The strong metal-support interaction (SMSI) offers a route to control the structural properties of supported metals and, hence, their reactivity and stability. Conventional wisdom holds that supported Au cannot manifest a classical SMSI, which is characterized by reversible metal encapsulation by the support upon high-temperature redox treatments. We demonstrate a classical SMSI for Au/TiO2, evidenced by suppression of CO adsorption, electron transfer from TiO2 to Au nulloparticles, and gold encapsulation by a TiOx overlayer following high-temperature reduction (reversed by subsequent oxidation), akin to that observed for titania-supported platinum group metals. In the SMSI state, Au/TiO2 exhibits markedly improved stability toward CO oxidation. The SMSI extends to Au supported over other reducible oxides (Fe3O4 and CeO2) and other group IB metals (Cu and Ag) over titania. This discovery highlights the general nature of the classical SMSI and unlocks the development of thermochemically stable IB metal catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700231", "DOI": "10.1126/sciadv.1700231", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700231", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417998700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maier, GP; Rapp, MV; Waite, JH; Israelachvili, JN; Butler, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maier, Greg P.; Rapp, Michael V.; Waite, J. Herbert; Israelachvili, Jacob N.; Butler, Alison", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adaptive synergy between catechol and lysine promotes wet adhesion by surface salt displacement", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In physiological fluids and seawater, adhesion of synthetic polymers to solid surfaces is severely limited by high salt, pH, and hydration, yet these conditions have not deterred the evolution of effective adhesion by mussels. Mussel foot proteins provide insights about adhesive adaptations: Notably, the abundance and proximity of catecholic Dopa (3,4-dihydroxyphenylalanine) and lysine residues hint at a synergistic interplay in adhesion. Certain siderophores-bacterial iron chelators-consist of paired catechol and lysine functionalities, thereby providing a convenient experimental platform to explore molecular synergies in bioadhesion. These siderophores and synthetic analogs exhibit robust adhesion energies (E-ad >= -15 millijoules per square meter) to mica in saline pH 3.5 to 7.5 and resist oxidation. The adjacent catechol-lysine placement provides a one-two punch, whereby lysine evicts hydrated cations from the mineral surface, allowing catechol binding to underlying oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 594, "Times Cited, All Databases": 665, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2015, "Volume": 349, "Issue": 6248, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 628, "End Page": 632, "Article Number": null, "DOI": "10.1126/science.aab0556", "DOI Link": "http://dx.doi.org/10.1126/science.aab0556", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359092900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WL; Wang, Z; Wang, G; Liu, GL; Chen, J; Pu, XJ; Xi, Y; Wang, X; Guo, HY; Hu, CG; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wenlin; Wang, Zhao; Wang, Gao; Liu, Guanlin; Chen, Jie; Pu, Xianjie; Xi, Yi; Wang, Xue; Guo, Hengyu; Hu, Chenguo; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated charge excitation triboelectric nullogenerator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Performance of triboelectric nullogenerators is limited by low and unstable charge density on tribo-layers. An external-charge pumping method was recently developed and presents a promising and efficient strategy towards high-output triboelectric nullogenerators. However, integratibility and charge accumulation efficiency of the system is rather low. Inspired by the historical development of electromagnetic generators, here, we propose and realize a self-charge excitation triboelectric nullogenerator system towards high and stable output in analogy to the principle of traditional magnetic excitation generators. By rational design of the voltage-multiplying circuits, the completed external and self-charge excitation modes with stable and tailorable output over 1.25 mC m(-2) in contact-separation mode have been realized in ambient condition. The realization of the charge excitation system in this work may provide a promising strategy for achieving high-output triboelectric nullogenerators towards practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1426, "DOI": "10.1038/s41467-019-09464-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09464-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462721900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CH; Yang, SZ; Wu, JJ; Liu, MJ; Yazdi, S; Ren, MQ; Sha, JW; Zhong, J; Nie, KQ; Jalilov, AS; Li, ZY; Li, HM; Yakobson, BI; Wu, Q; Ringe, EL; Xu, H; Ajayan, PM; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chenhao; Yang, Shize; Wu, Jingjie; Liu, Mingjie; Yazdi, Sadegh; Ren, Muqing; Sha, Junwei; Zhong, Jun; Nie, Kaiqi; Jalilov, Almaz S.; Li, Zhenyuan; Li, Huaming; Yakobson, Boris I.; Wu, Qin; Ringe, Emilie; Xu, Hui; Ajayan, Pulickel M.; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical CO2 Reduction with Atomic Iron-Dispersed on Nitrogen-Doped Graphene", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 provides an opportunity to reach a carbon-neutral energy recycling regime, in which CO2 emissions from fuel use are collected and converted back to fuels. The reduction of CO2 to CO is the first step toward the synthesis of more complex carbon-based fuels and chemicals. Therefore, understanding this step is crucial for the development of high-performance electrocatalyst for CO2 conversion to higher order products such as hydrocarbons. Here, atomic iron dispersed on nitrogen-doped graphene (Fe/NG) is synthesized as an efficient electrocatalyst for CO2 reduction to CO. Fe/NG has a low reduction overpotential with high Faradic efficiency up to 80%. The existence of nitrogen-confined atomic Fe moieties on the nitrogen-doped graphene layer is confirmed by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and X-ray absorption fine structure analysis. The Fe/NG catalysts provide an ideal platform for comparative studies of the effect of the catalytic center on the electrocatalytic performance. The CO2 reduction reaction mechanism on atomic Fe surrounded by four N atoms (Fe-N-4) embedded in nitrogen-doped graphene is further investigated through density functional theory calculations, revealing a possible promotional effect of nitrogen doping on graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2018, "Volume": 8, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703487, "DOI": "10.1002/aenm.201703487", "DOI Link": "http://dx.doi.org/10.1002/aenm.201703487", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437667800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, R; Inoue, T; Zheng, YJ; Kumamoto, A; Qian, Y; Sato, Y; Liu, M; Tang, DM; Gokhale, D; Guo, J; Hisama, K; Yotsumoto, S; Ogamoto, T; Arai, H; Kobayashi, Y; Zhang, H; Hou, B; Anisimov, A; Maruyama, M; Miyata, Y; Okada, S; Chiashi, S; Li, Y; Kong, J; Kauppinen, EI; Ikuhara, Y; Suenaga, K; Maruyama, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Rong; Inoue, Taiki; Zheng, Yongjia; Kumamoto, Akihito; Qian, Yang; Sato, Yuta; Liu, Ming; Tang, Daiming; Gokhale, Devashish; Guo, Jia; Hisama, Kaoru; Yotsumoto, Satoshi; Ogamoto, Tatsuro; Arai, Hayato; Kobayashi, Yu; Zhang, Hao; Hou, Bo; Anisimov, Anton; Maruyama, Mina; Miyata, Yasumitsu; Okada, Susumu; Chiashi, Shohei; Li, Yan; Kong, Jing; Kauppinen, Esko I.; Ikuhara, Yuichi; Suenaga, Kazu; Maruyama, Shigeo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-dimensional van der Waals heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the experimental synthesis of one-dimensional (1D) van der Waals heterostructures, a class of materials where different atomic layers are coaxially stacked. We demonstrate the growth of single-crystal layers of hexagonal boron nitride (BN) and molybdenum disulfide (MoS2) crystals on single-walled carbon nullotubes (SWCNTs). For the latter, larger-diameter nullotubes that overcome strain effect were more readily synthesized. We also report a 5-nullometer-diameter heterostructure consisting of an inner SWCNT, a middle three-layer BN nullotube, and an outer MoS2 nullotube. Electron diffraction verifies that all shells in the heterostructures are single crystals. This work suggests that all of the materials in the current 2D library could be rolled into their 1D counterparts and a plethora of function-designable 1D heterostructures could be realized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2020, "Volume": 367, "Issue": 6477, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 537, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz2570", "DOI Link": "http://dx.doi.org/10.1126/science.aaz2570", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512377600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, J; Zeng, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Jun; Zeng, Xiao Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bilayer Phosphorene: Effect of Stacking Order on Bandgap and Its Potential Applications in Thin-Film Solar Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, a monolayer of black phosphorus, is promising for nulloelectronic applications not only because it is a natural p-type semiconductor but also because it possesses a layer-number-dependent direct bandgap (in the range of 0.3 to 1.5 eV). On basis of the density functional theory calculations, we investigate electronic properties of the bilayer phosphorene with different stacking orders. We find that the direct bandgap of the bilayers can vary from 0.78 to 1.04 eV with three different stacking orders. In addition, a vertical electric field can further reduce the bandgap to 0.56 eV (at the field strength 0.5 V/angstrom). More importantly, we find that when a monolayer of MoS2 is superimposed with the p-type AA- or AB-stacked bilayer phosphorene, the combined trilayer can be an effective solar-cell material with type-II heterojunction alignment. The power conversion efficiency is predicted to be similar to 18 or 16% with AA- or AB-stacked bilayer phosphorene, higher than reported efficiencies of the state-of-the-art trilayer graphene/transition metal dichalcogenide solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 805, "Times Cited, All Databases": 851, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2014, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1289, "End Page": 1293, "Article Number": null, "DOI": "10.1021/jz500409m", "DOI Link": "http://dx.doi.org/10.1021/jz500409m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333947700040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XG; Yang, JH; Fu, YH; Yang, DW; Xu, QL; Yu, LP; Wei, SH; Zhang, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin-Gang; Yang, Ji-Hui; Fu, Yuhao; Yang, Dongwen; Xu, Qiaoling; Yu, Liping; Wei, Su-Huai; Zhang, Lijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Lead-Free Inorganic Halide Perovskites for Solar Cells via Cation-Transmutation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic inorganic halide perovskites with the prototype material of CH3NH3PbI3 have recently attracted intense interest as low-cost and high-performance photovoltaic absorbers. Despite the high power conversion efficiency exceeding 20% achieved by their solar cells, two key issues-the poor device stabilities associated with their intrinsic material instability and the toxicity due to water-soluble Pb2+-need to be resolved before large-scale commercialization. Here, we address these issues by exploiting the 6 strategy of cation-transmutation to design stable inorganic Pb-free halide perovskites for solar cells. The idea is to convert two divalent Pb2+ ions into one monovalent M+ and one trivalent M3+ ions, forming a rich class of quaternary halides in double-perovskite structure. We find through first-principles calculations this class of materials have good phase stability against decomposition and wide range tunable optoelectronic properties. With photovoltaic-functionality-directed materials screening, we identify 11 optimal materials with intrinsic thermodynamic stability, suitable band gaps, small carrier effective masses, and low excitons binding energies as promising candidates to replace Pb-based photovoltaic absorbers in perovskite solar cells. The chemical trends of phase stabilities and electronic properties are also established for this class of materials, offering useful guidance for the development of perovskite solar cells fabricated with them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 770, "Times Cited, All Databases": 803, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2017, "Volume": 139, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2630, "End Page": 2638, "Article Number": null, "DOI": "10.1021/jacs.6b09645", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b09645", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394829200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Man, TT; Xu, CX; Liu, XY; Li, D; Tsung, CK; Pei, H; Wan, Y; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Man, Tiantian; Xu, Caixia; Liu, Xiao-Yuan; Li, Dan; Tsung, Chia-Kuang; Pei, Hao; Wan, Ying; Li, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically encapsulating enzymes with multi-shelled metal-organic frameworks for tandem biocatalytic reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biocatalytic transformations in living organisms, such as multi-enzyme catalytic cascades, proceed in different cellular membrane-compartmentalized organelles with high efficiency. Nevertheless, it remains challenging to mimicking biocatalytic cascade processes in natural systems. Herein, we demonstrate that multi-shelled metal-organic frameworks (MOFs) can be used as a hierarchical scaffold to spatially organize enzymes on nulloscale to enhance cascade catalytic efficiency. Encapsulating multi-enzymes with multi-shelled MOFs by epitaxial shell-by-shell overgrowth leads to 5.8 similar to 13.5-fold enhancements in catalytic efficiencies compared with free enzymes in solution. Importantly, multi-shelled MOFs can act as a multi-spatial-compartmental nulloreactor that allows physically compartmentalize multiple enzymes in a single MOF nulloparticle for operating incompatible tandem biocatalytic reaction in one pot. Additionally, we use nulloscale Fourier transform infrared (nullo-FTIR) spectroscopy to resolve nulloscale heterogeneity of vibrational activity associated to enzymes encapsulated in multi-shelled MOFs. Furthermore, multi-shelled MOFs enable facile control of multi-enzyme positions according to specific tandem reaction routes, in which close positioning of enzyme-1-loaded and enzyme-2-loaded shells along the inner-to-outer shells could effectively facilitate mass transportation to promote efficient tandem biocatalytic reaction. This work is anticipated to shed new light on designing efficient multi-enzyme catalytic cascades to encourage applications in many chemical and pharmaceutical industrial processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 305, "DOI": "10.1038/s41467-022-27983-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-27983-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742409800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shalom, M; Ressnig, D; Yang, XF; Clavel, G; Fellinger, TP; Antonietti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shalom, Menny; Ressnig, Debora; Yang, Xiaofei; Clavel, Guylhaine; Fellinger, Tim Patrick; Antonietti, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel nitride as an efficient electrocatalyst for water splitting", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient, robust and low cost materials as electrocatalysts for energy-related applications are highly desired for the future of renewable energy production. Here we show a simple method to fabricate nickel nitride (Ni3N) on nickel (Ni) foam for electrocatalytic applications. The Ni3N/Ni-foam exhibits extremely low overpotential (similar to 50 mV), high current density and excellent stability for the hydrogen evolution reaction (HER) in alkaline solution. In addition, the modified foam demonstrates enhanced activity in the oxygen evolution (OER) and reduction (ORR) reaction compared to original Ni-foam. The activity enhancement can be attributed to the facile formation of a Ni(OH)(2) layer on the nitride layer due to improved lattice matching. The formation of the Ni3N/Ni(OH)(2) catalyst results in lower overpotentials due to easier water dissociation on the nickel hydroxide layer. In addition, the HER is further improved due to stronger adsorption of hydrogen to the metal nitride than to the pure metal. We believe that the utilization of nickel nitride as an electrocatalyst opens opportunities for energy-related devices such as batteries and fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8171, "End Page": 8177, "Article Number": null, "DOI": "10.1039/c5ta00078e", "DOI Link": "http://dx.doi.org/10.1039/c5ta00078e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352441100062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, MS; Wang, Y; Wang, P; Zhou, XH; Xia, H; Luo, C; Huang, SY; Zhang, GW; Yan, HG; Fan, ZY; Wu, X; Chen, XS; Lu, W; Hu, WD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Mingsheng; Wang, Yang; Wang, Peng; Zhou, Xiaohao; Xia, Hui; Luo, Chen; Huang, Shenyang; Zhang, Guowei; Yan, Hugen; Fan, Zhiyong; Wu, Xing; Chen, Xiaoshuang; Lu, Wei; Hu, Weida", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Palladium Diselenide Long-Wavelength Infrared Photodetector with High Sensitivity and Stability", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A long-wavelength infrared photodetector based on two-dimensional materials working at room temperature would have wide applications in many aspects in remote sensing, thermal imaging, biomedical optics, and medical imaging. However, sub-bandgap light detection in graphene and black phosphorus has been a long-standing scientific challenge because of their low photoresponsivity, instability in the air, and high dark current. In this study, we report a highly sensitive, air-stable, and operable long-wavelength infrared photodetector at room temperature based on PdSe2 phototransistors and their heterostructure. A high photoresponsivity of similar to 42.1 AW(-1) (at 10.6 mu m) was demonstrated, which is an order of magnitude higher than the current record of platinum diselenide. Moreover, the dark current and noise power density were suppressed effectively by fabricating a van der Waals heterostructure. This work fundamentally contributes to establishing long-wavelength infrared detection by PdSe2 at the forefront of long-IR two-dimensional-materials-based photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2511, "End Page": 2519, "Article Number": null, "DOI": "10.1021/acsnullo.8b09476", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b09476", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460199400150", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Pei, A; Lin, DC; Xie, J; Yang, AK; Xu, JW; Lin, KX; Wang, JY; Wang, HS; Shi, FF; Boyle, D; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Pei, Allen; Lin, Dingchang; Xie, Jin; Yang, Ankun; Xu, Jinwei; Lin, Kaixiang; Wang, Jiangyan; Wang, Hansen; Shi, Feifei; Boyle, David; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial solid-electrolyte interphase (SEI) is one of the key approaches in addressing the low reversibility and dendritic growth problems of lithium metal anode, yet its current effect is still insufficient due to insufficient stability. Here, a new principle of simultaneous high ionic conductivity and homogeneity is proposed for stabilizing SEI and lithium metal anodes. Fabricated by a facile, environmentally friendly, and low-cost lithium solid-sulfur vapor reaction at elevated temperature, a designed lithium sulfide protective layer successfully maintains its protection function during cycling, which is confirmed by both simulations and experiments. Stable dendrite-free cycling of lithium metal anode is realized even at a high areal capacity of 5 mAh cm(-2), and prototype Li-Li4Ti5O12 cell with limited lithium also achieves 900 stable cycles. These findings give new insight into the ideal SEI composition and structure and provide new design strategies for stable lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 9, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900858, "DOI": "10.1002/aenm.201900858", "DOI Link": "http://dx.doi.org/10.1002/aenm.201900858", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471132800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, BH; Thukral, A; Xie, ZQ; Liu, LM; Zhang, XN; Huang, W; Yu, XG; Yu, CJ; Marks, TJ; Facchetti, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Binghao; Thukral, Anish; Xie, Zhaoqian; Liu, Limei; Zhang, Xinull; Huang, Wei; Yu, Xinge; Yu, Cunjiang; Marks, Tobin J.; Facchetti, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and stretchable metal oxide nullofiber networks for multimodal and monolithically integrated wearable electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fiber-based electronics enabling lightweight and mechanically flexible/stretchable functions are desirable for numerous e-textile/e-skin optoelectronic applications. These wearable devices require low-cost manufacturing, high reliability, multifunctionality and long-term stability. Here, we report the preparation of representative classes of 3D-inorganic nullofiber network (FN) films by a blow-spinning technique, including semiconducting indium-gallium-zinc oxide (IGZO) and copper oxide, as well as conducting indium-tin oxide and copper metal. Specifically, thin-film transistors based on IGZO FN exhibit negligible performance degradation after one thousand bending cycles and exceptional room-temperature gas sensing performance. Owing to their great stretchability, these metal oxide FNs can be laminated/embedded on/into elastomers, yielding multifunctional single-sensing resistors as well as fully monolithically integrated e-skin devices. These can detect and differentiate multiple stimuli including analytes, light, strain, pressure, temperature, humidity, body movement, and respiratory functions. All of these FN-based devices exhibit excellent sensitivity, response time, and detection limits, making them promising candidates for versatile wearable electronics. Designing energy efficient, flexible opto-electronic systems integrated with textiles remains a challenge. Here, the authors propose a solution-based blow-spinning technique for 3D flexible and stretchable metal oxide nullofiber networks for multimodal and monolithically integrated wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2405, "DOI": "10.1038/s41467-020-16268-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16268-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, CE; Hatzell, KB; Alhabeb, M; Ling, Z; Mahmoud, KA; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Chang E.; Hatzell, Kelsey B.; Alhabeb, Mohamed; Ling, Zheng; Mahmoud, Khaled A.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge- and Size-Selective Ion Sieving Through Ti3C2Tx MXene Membranes", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullometer-thin sheets of 2D Ti3C2Tx (MXene) have been assembled into freestanding or supported membranes for the charge- and size-selective rejection of ions and molecules. MXene membranes with controllable thicknesses ranging from hundreds of nullometers to several micrometers exhibited flexibility, high mechanical strength, hydrophilic surfaces, and electrical conductivity that render them promising for separation applications. Micrometer-thick MXene membranes demonstrated ultrafast water flux of 37.4 L/(Bar.h.m(2)) and differential sieving of salts depending on both the hydration radius and charge of the ions. Cations with a larger charge and hydration radii smaller than the interlayer spacing of MXene (similar to 6 angstrom) demonstrate an order of magnitude slower permeation compared to single-charged cations. Our findings may open a door for developing efficient and highly selective separation membranes from 2D carbides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 776, "Times Cited, All Databases": 834, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2015, "Volume": 6, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4026, "End Page": 4031, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b01895", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b01895", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363083900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, QS; Xie, XJ; Huang, BL; Liang, LL; Han, SY; Yi, ZG; Wang, Y; Li, Y; Fan, DY; Huang, L; Liu, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Qiushui; Xie, Xiaoji; Huang, Bolong; Liang, Liangliang; Han, Sanyang; Yi, Zhigao; Wang, Yu; Li, Ying; Fan, Dianyuan; Huang, Ling; Liu, Xiaogang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confining Excitation Energy in Er3+-Sensitized Upconversion nullocrystals through Tm3+-Mediated Transient Energy Trapping", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new class of lanthanide-doped upconversion nulloparticles are presented that are without Yb3+ or Nd3+ sensitizers in the host lattice. In erbium-enriched core-shell NaErF4:Tm (0.5 mol%)@ NaYF4 nulloparticles, a high degree of energy migration between Er3+ ions occurs to suppress the effect of concentration quenching upon surface coating. Unlike the conventional Yb3+-Er3+ system, the Er3+ ion can serve as both the sensitizer and activator to enable an effective upconversion process. Importantly, an appropriate doping of Tm3+ has been demonstrated to further enhance upconversion luminescence through energy trapping. This endows the resultant nulloparticles with bright red (about 700-fold enhancement) and near-infrared luminescence that is achievable under multiple excitation wavelengths. This is a fundamental new pathway to mitigate the concentration quenching effect, thus offering a convenient method for red-emitting upconversion nulloprobes for biological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2017, "Volume": 56, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7605, "End Page": 7609, "Article Number": null, "DOI": "10.1002/anie.201703012", "DOI Link": "http://dx.doi.org/10.1002/anie.201703012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403017000049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trickett, CA; Popp, TMO; Su, J; Yan, C; Weisberg, J; Huq, A; Urban, P; Jiang, JC; Kalmutzki, MJ; Liu, QN; Baek, J; Head-Gordon, MP; Somorjai, GA; Reimer, JA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trickett, Christopher A.; Popp, Thomas M. Osborn; Su, Ji; Yan, Chang; Weisberg, Jonathan; Huq, Ashfia; Urban, Philipp; Jiang, Juncong; Kalmutzki, Markus J.; Liu, Qingni; Baek, Jayeon; Head-Gordon, Martin P.; Somorjai, Gabor A.; Reimer, Jeffrey A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of the strong Bronsted acid site in a metal-organic framework solid acid catalyst", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It remains difficult to understand the surface of solid acid catalysts at the molecular level, despite their importance for industrial catalytic applications. A sulfated zirconium-based metal-organic framework, MOF-808-SO4, was previously shown to be a strong solid Bronsted acid material. In this report, we probe the origin of its acidity through an array of spectroscopic, crystallographic and computational characterization techniques. The strongest Bronsted acid site is shown to consist of a specific arrangement of adsorbed water and sulfate moieties on the zirconium clusters. When a water molecule adsorbs to one zirconium atom, it participates in a hydrogen bond with a sulfate moiety that is chelated to a neighbouring zirconium atom; this motif, in turn, results in the presence of a strongly acidic proton. On dehydration, the material loses its acidity. The hydrated sulfated MOF exhibits a good catalytic performance for the dimerization of isobutene (2-methyl-1-propene), and achieves a 100% selectivity for C8 products with a good conversion efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 170, "End Page": 176, "Article Number": null, "DOI": "10.1038/s41557-018-0171-z", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0171-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456665900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XY; Hong, JJ; Shin, W; Ma, L; Liu, TC; Bi, XX; Yuan, YF; Qi, YT; Surta, TW; Huang, WX; Neuefeind, J; Wu, TP; Greaney, PA; Lu, J; Ji, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xianyong; Hong, Jessica J.; Shin, Woochul; Ma, Lu; Liu, Tongchao; Bi, Xuanxuan; Yuan, Yifei; Qi, Yitong; Surta, T. Wesley; Huang, Wenxi; Neuefeind, Joerg; Wu, Tianpin; Greaney, P. Alex; Lu, Jun; Ji, Xiulei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of Faradaic battery electrodes that exhibit high rate capability and long cycle life equivalent to those of the electrodes of electrical double-layer capacitors is a big challenge. Here we report a strategy to fill this performance gap using the concept of Grotthuss proton conduction, in which proton transfer takes place by means of concerted cleavage and formation of O-H bonds in a hydrogen-bonding network. We show that in a hydrated Prussian blue analogue (Turnbull's blue) the abundant lattice water molecules with a contiguous hydrogen-bonding network facilitate Grotthuss proton conduction during redox reactions. When using it as a battery electrode, we find high-rate behaviours at 4,000 C (380 Ag-1, 508 mA cm(-2)), and a long cycling life of 0.73 million cycles. These results for diffusion-free Grotthuss topochemistry of protons, in contrast to orthodox battery electrochemistry, which requires ion diffusion inside electrodes, indicate a potential direction to revolutionize electrochemical energy storage for high-power applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 123, "End Page": 130, "Article Number": null, "DOI": "10.1038/s41560-018-0309-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0309-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458547300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lipatov, A; Lu, HD; Alhabeb, M; Anasori, B; Gruverman, A; Gogotsi, Y; Sinitskii, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lipatov, Alexey; Lu, Haidong; Alhabeb, Mohamed; Anasori, Babak; Gruverman, Alexei; Gogotsi, Yury; Sinitskii, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, are a large class of materials that are finding numerous applications ranging from energy storage and electromagnetic interference shielding to water purification and antibacterial coatings. Yet, despite the fact that more than 20 different MXenes have been synthesized, the mechanical properties of a MXene monolayer have not been experimentally studied. We measured the elastic properties of monolayers and bilayers of the most important MXene material to date, Ti3C2Tx (T-x stands for surface termination). We developed a method for preparing well-strained membranes of Ti3C2Tx monolayers and bilayers, and performed their nulloindentation with the tip of an atomic force microscope to record the force-displacement curves. The effective Young's modulus of a single layer of Ti3C2Tx was found to be 0.33 +/- 0.03 TPa, which is the highest among the mean values reported in nulloindentation experiments for other solution-processed 2D materials, including graphene oxide. This work opens a pathway for investigating the mechanical properties of monolayers and bilayers of other MXenes and extends the already broad range of MXenes' applications to structural composites, protective coatings, nulloresonators, and membranes that require materials with exceptional mechanical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 800, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat0491", "DOI": "10.1126/sciadv.aat0491", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat0491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HY; Yi, X; Liu, T; Liu, J; Wu, QA; Ding, YH; Liu, ZZ; Wang, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haiyan; Yi, Xin; Liu, Tao; Liu, Jing; Wu, Qinull; Ding, Yonghui; Liu, Zhenzhen; Wang, Qingwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Integrally Formed Janus Hydrogel for Robust Wet-Tissue Adhesive and Anti-Postoperative Adhesion", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Facile fabrication of asymmetrically adhesive hydrogel with robust wet tissue adhesion simultaneously with effective anti-postoperative adhesion still remains a great challenge. In this work, an integrally formed Janus hydrogel is facilely fabricated in one step by controlling the interfacial distribution of free carboxyl groups on the two sides of hydrogels. At a lower stirring speed, the generated bigger sized emulsion droplets mainly occupy the top surface of hydrogel, which effectively hinders the exposition of carboxyl groups on the top surface, driving them to be more distributed on the bottom surface, ultimately resulting in the poor adhesion of top surface but robust adhesion of bottom surface to various wet tissue even underwater. The difference in adhesive strength achieves as high as 20 times between the two surfaces. In vivo rabbit experiment outcomes clearly validate that the bottom surface of hydrogel firmly adheres to the stomach defect, and the other opposite surface can efficiently address the postoperative adhesion problem. Besides, this hydrogel exhibits superior mechanical toughness and conductivity which has been used as a highly adhesive strain sensor to real-time monitor the beating heart in vivo. This simple yet effective strategy provides a much more feasible approach for creating Janus hydrogels bioadhesives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300394", "DOI Link": "http://dx.doi.org/10.1002/adma.202300394", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000963419400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HT; Jia, B; Zhang, ZC; Qu, XH; Li, GN; Lin, WJ; Zhu, DH; Dai, KR; Zheng, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hongtao; Jia, Bo; Zhang, Zechuan; Qu, Xinhua; Li, Guannull; Lin, Wenjiao; Zhu, Donghui; Dai, Kerong; Zheng, Yufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloying design of biodegradable zinc as promising bone implants for load-bearing applications", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium-based biodegradable metals (BMs) as bone implants have better mechanical properties than biodegradable polymers, yet their strength is roughly less than 350 MPa. In this work, binary Zn alloys with alloying elements Mg, Ca, Sr, Li, Mn, Fe, Cu, and Ag respectively, are screened systemically by in vitro and in vivo studies. Li exhibits the most effective strengthening role in Zn, followed by Mg. Alloying leads to accelerated degradation, but adequate mechanical integrity can be expected for Zn alloys when considering bone fracture healing. Adding elements Mg, Ca, Sr and Li into Zn can improve the cytocompatibility, osteogenesis, and osseointegration. Further optimization of the ternary Zn-Li alloy system results in Zn-0.8Li-0.4 Mg alloy with the ultimate tensile strength 646.69 +/- 12.79 MPa and Zn-0.8Li-0.8 Mn alloy with elongation 103.27 +/- 20%. In summary, biocompatible Zn-based BMs with strength close to pure Ti are promising candidates in orthopedics for load-bearing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 401, "DOI": "10.1038/s41467-019-14153-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14153-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511940400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YH; Guo, H; Hwang, S; Yang, XX; He, ZZ; Braaten, J; Karakalos, S; Shan, WT; Wang, MY; Zhou, H; Feng, ZX; More, KL; Wang, GF; Su, D; Cullen, DA; Fei, L; Litster, S; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yanghua; Guo, Hui; Hwang, Sooyeon; Yang, Xiaoxuan; He, Zizhou; Braaten, Jonathan; Karakalos, Stavros; Shan, Weitao; Wang, Maoyu; Zhou, Hua; Feng, Zhenxing; More, Karren L.; Wang, Guofeng; Su, Dong; Cullen, David A.; Fei, Ling; Litster, Shawn; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single Cobalt Sites Dispersed in Hierarchically Porous nullofiber Networks for Durable and High-Power PGM-Free Cathodes in Fuel Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing catalytic activity and durability of atomically dispersed metal-nitrogen-carbon (M-N-C) catalysts for the oxygen reduction reaction (ORR) cathode in proton-exchange-membrane fuel cells remains a grand challenge. Here, a high-power and durable Co-N-C nullofiber catalyst synthesized through electrospinning cobalt-doped zeolitic imidazolate frameworks into selected polyacrylonitrile and poly(vinylpyrrolidone) polymers is reported. The distinct porous fibrous morphology and hierarchical structures play a vital role in boosting electrode performance by exposing more accessible active sites, providing facile electron conductivity, and facilitating the mass transport of reactant. The enhanced intrinsic activity is attributed to the extra graphitic N dopants surrounding the CoN(4)moieties. The highly graphitized carbon matrix in the catalyst is beneficial for enhancing the carbon corrosion resistance, thereby promoting catalyst stability. The unique nulloscale X-ray computed tomography verifies the well-distributed ionomer coverage throughout the fibrous carbon network in the catalyst. The membrane electrode assembly achieves a power density of 0.40 W cm(-2)in a practical H-2/air cell (1.0 bar) and demonstrates significantly enhanced durability under accelerated stability tests. The combination of the intrinsic activity and stability of single Co sites, along with unique catalyst architecture, provide new insight into designing efficient PGM-free electrodes with improved performance and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 32, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003577, "DOI": "10.1002/adma.202003577", "DOI Link": "http://dx.doi.org/10.1002/adma.202003577", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577679700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parra-Puerto, A; Ng, KL; Fahy, K; Goode, AE; Ryan, MP; Kucernak, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parra-Puerto, Andres; Ng, Kai Ling; Fahy, Kieran; Goode, Angela E.; Ryan, Mary P.; Kucernak, Anthony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supported Transition Metal Phosphides: Activity Survey for HER, ORR, OER, and Corrosion Resistance in Acid and Alkaline Electrolytes", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-supported MxPy (M = Ni, Co, W, Cr, and Mo) were prepared via pyrolysis using a very simple and scalable method utilizing nontoxic metal and phosphorus precursors. The electrochemical hydrogen evolution (HER), oxygen reduction (ORR), and oxygen evolution (OER) reactions and corrosion resistance under both acidic and alkaline conditions were examined for all these catalysts and compared to those for the benchmark catalysts Pt/C (HER/ORR) and IrO2 (OER). The highest activities were found in alkaline solutions for Co2P for HER and ORR and Ni2P for OER Good activity was also found in acid for some of these reactions, although the catalysts suffered from susceptibility to corrosion. Co2P was further studied in an alkaline environment, as it shows high catalytic activity toward the oxygen reduction reaction (ORR) without significant hysteresis. The onset potential (at 0.5 mA cm(-2)) obtained was 0.8 V vs RHE, and a Tafel slope value of 38 mV dec(-1) was found with a maximum kinetic mass activity of 2870 A g(Co)(-1) at 0.7 V vs RHE. Utilizing high-resolution transmission electron microscopy, it is possible to observe high-surface-area needle-like single-crystal cobalt oxide structures on the surface of the Co2P particles at the beginning of the ORR Hence the high rates of initial corrosion of the Co2P appear to be associated with the dissolution and precipitation of cobalt oxide on the particle surface. The as -synthesized Co2P/C also shows good performance in an 8-h stability test for the OER, carried out at 1.6 V vs RHE in alkaline conditions, with negligible drop in current density over time. Interestingly, in an acidic environment the catalyst is very active toward two-electron oxygen reduction, leading to H2O2 with high selectivity (85%). It is intriguing that the pH dependence of this catalyst toward the ORR is similar to that seen for gold.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11515, "End Page": 11529, "Article Number": null, "DOI": "10.1021/acscatal.9b03359", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b03359", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502169900084", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Loebel, C; Rodell, CB; Chen, MH; Burdick, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Loebel, Claudia; Rodell, Christopher B.; Chen, Minna H.; Burdick, Jason A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shear-thinning and self-healing hydrogels as injectable therapeutics and for 3D-printing", "Source Title": "NATURE PROTOCOLS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of injectable hydrogel systems addresses the growing demand for minimally invasive approaches for local and sustained delivery of therapeutics. We developed a class of hyaluronic acid (HA) hydrogels that form through noncovalent guest-host interactions, undergo disassembly (shear-thinning) when injected through a syringe and then reassemble within seconds (self-healing) when shear forces are removed. Its unique properties enable the use of this hydrogel system for numerous applications, such as injection in vivo (including with cells and therapeutic molecules) or as a 'bioink' in 3D-printing applications. Here, we describe the functionalization of HA either with adamantanes (guest moieties) via controlled esterification or with b-cyclodextrins (host moieties) through amidation. We also describe how to modify the HA derivatives with methacrylates for secondary covalent cross-linking and for reaction with fluorophores for in vitro and in vivo imaging. HA polymers are rationally designed from relatively low-molecular-weight starting materials, with the degree of modification controlled, and have matched guest-to-host stoichiometry, allowing the preparation of hydrogels with tailored properties. This procedure takes 3-4 weeks to complete. We detail the preparation and characterization of the guest-host hydrogels, including assessment of their rheological properties, erosion and biomolecule release in vitro. We furthermore demonstrate how to encapsulate cells in vitro and provide procedures for quantitative assessment of in vivo hydrogel degradation by imaging of fluorescently derivatized materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 463, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1521, "End Page": 1541, "Article Number": null, "DOI": "10.1038/nprot.2017.053", "DOI Link": "http://dx.doi.org/10.1038/nprot.2017.053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404865300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HM; Li, J; Xie, GH; Lin, GQ; Chen, RF; Peng, ZK; Yang, CL; Wang, BS; Sun, JL; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Huimin; Li, Jian; Xie, Guohua; Lin, Guiqing; Chen, Rufan; Peng, Zhengkang; Yang, Chuluo; Wang, Baoshan; Sun, Junliang; Wang, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An AIEgen-based 3D covalent organic framework for white light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and synthesis of three-dimensional covalent organic frameworks (3D COFs) have still been considered as a big challenge. Here we report the design and synthesis of an AIEgen-based 3D COF (3D-TPE-COF), with a high surface area (1084 m(2)g(-1)). According to powder X-ray diffraction and continuous rotation electron diffraction analyses, 3D-TPE-COF is identified to adopt a seven-fold interpenetrated pts topology. Interestingly, 3D-TPE-COF emits yellow fluorescence upon excitation, with a photoluminescence quantum yield of 20%. Moreover, by simply coating 3D-TPE-COF onto a commercial blue light-emitting diode (LED), a prototype white LED (WLED) under continuously driving without degradation for 1200 h was demonstrated. The present work suggests the possibility of using COF materials for stable WLEDs, which will greatly inspire us to design and synthesize fluorescent 3D COFs and facilitate the development of COF-based WLEDs in future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5234, "DOI": "10.1038/s41467-018-07670-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07670-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452633000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Deng, SQ; Liu, H; Wu, J; Qi, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Liang; Deng, Shiqing; Liu, Hui; Wu, Jie; Qi, He; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation advanced high/pulsed power capacitors rely heavily on dielectric ceramics with high energy storage performance. However, thus far, the huge challenge of realizing ultrahigh recoverable energy storage density (W-rec) accompanied by ultrahigh efficiency (eta) still existed and has become a key bottleneck restricting the development of dielectric materials in cutting-edge energy storage applications. Here, we propose a high-entropy strategy to design local polymorphic distortion including rhombohedral-orthorhombic-tetragonal-cubic multiphase nulloclusters and random oxygen octahedral tilt, resulting inultra small polar nulloregions, an enhanced breakdown electric field, and delayed polarization saturation. A giant W-rec similar to 10.06 J cm(-3) is realized in lead-free relaxor ferroelectrics, especially with an ultrahigh eta similar to 90.8%, showing breakthrough progress in the comprehensive energy storage performance for lead-free bulk ceramics. This work opens up an effective avenue to design dielectric materials with ultrahigh comprehensive energy storage performance to meet the demanding requirements of advanced energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3089, "DOI": "10.1038/s41467-022-30821-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30821-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805202900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weingarten, AS; Kazantsev, RV; Palmer, LC; McClendon, M; Koltonow, AR; Samuel, APS; Kiebala, DJ; Wasielewski, MR; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weingarten, Adam S.; Kazantsev, Roman V.; Palmer, Liam C.; McClendon, Mark; Koltonow, Andrew R.; Samuel, Amanda P. S.; Kiebala, Derek J.; Wasielewski, Michael R.; Stupp, Samuel I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembling hydrogel scaffolds for photocatalytic hydrogen production", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integration into a soft material of all the molecular components necessary to generate storable fuels is an interesting target in supramolecular chemistry. The concept is inspired by the internal structure of photosynthetic organelles, such as plant chloroplasts, which colocalize molecules involved in light absorption, charge transport and catalysis to create chemical bonds using light energy. We report here on the light-driven production of hydrogen inside a hydrogel scaffold built by the supramolecular self-assembly of a perylene monoimide amphiphile. The charged ribbons formed can electrostatically attract a nickel-based catalyst, and electrolyte screening promotes gelation. We found the emergent phenomenon that screening by the catalyst or the electrolytes led to two-dimensional crystallization of the chromophore assemblies and enhanced the electronic coupling among the molecules. Photocatalytic production of hydrogen is observed in the three-dimensional environment of the hydrogel scaffold and the material is easily placed on surfaces or in the pores of solid supports.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 964, "End Page": 970, "Article Number": null, "DOI": "10.1038/NCHEM.2075", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344476000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, SB; Fu, Q; Chen, WX; Feng, QC; Chen, Z; Zhang, J; Cheong, WC; Yu, R; Gu, L; Dong, JC; Luo, J; Chen, C; Peng, Q; Draxl, C; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Shubo; Fu, Qiang; Chen, Wenxing; Feng, Quanchen; Chen, Zheng; Zhang, Jian; Cheong, Weng-Chon; Yu, Rong; Gu, Lin; Dong, Juncai; Luo, Jun; Chen, Chen; Peng, Qing; Draxl, Claudia; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon nitride supported Fe2 cluster catalysts with superior performance for alkene epoxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sub-nullo metal clusters often exhibit unique and unexpected properties, which make them particularly attractive as catalysts. Herein, we report a precursor-preselected wet-chemistry strategy to synthesize highly dispersed Fe-2 clusters that are supported on mesoporous carbon nitride (mpg-C3N4). The obtained Fe-2/mpg-C3N4 sample exhibits superior catalytic performance for the epoxidation of trans-stilbene to trans-stilbene oxide, showing outstanding selectivity of 93% at high conversion of 91%. Molecular oxygen is the only oxidant and no aldehyde is used as co-reagent. Under the same condition, by contrast, iron porphyrin, single-atom Fe, and small Fe nulloparticles (ca. 3 nm) are nearly reactively inert. First-principles calculations reveal that the unique reactivity of the Fe-2 clusters originates from the formation of active oxygen species. The general applicability of the synthesis approach is further demonstrated by producing other diatomic clusters like Pd-2 and Ir-2, which lays the foundation for discovering diatomic cluster catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2353, "DOI": "10.1038/s41467-018-04845-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04845-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435438000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pcrcira-Hcrnándcz, XI; DeLaRiva, A; Muravev, V; Kunwar, D; Xiong, H; Sudduth, B; Engelhard, M; Kovarlk, L; Hcnscn, EJM; Wang, Y; Datye, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pcrcira-Hcrnulldcz, Xavier Isidro; DeLaRiva, Andrew; Muravev, Valery; Kunwar, Deepak; Xiong, Haifeng; Sudduth, Berlin; Engelhard, Mark; Kovarlk, Libor; Hcnscn, Emlel J. M.; Wang, Yong; Datye, Abhaya K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we compare the CO oxidation performance of Pt single atom catalysts (SACs) prepared via two methods: (1) conventional wet chemical synthesis (strong electrostatic adsorption-SEA) with calcination at 350 degrees C in air; and (2) high temperature vapor phase synthesis (atom trapping-AT) with calcination in air at 800 degrees C leading to ionic Pt being trapped on the CeO2 in a thermally stable form. As-synthesized, both SACs are inactive for low temperature (<150 degrees C) CO oxidation. After treatment in CO at 275 degrees C, both catalysts show enhanced reactivity. Despite similar Pt metal particle size, the AT catalyst is significantly more active, with onset of CO oxidation near room temperature. A combination of near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) and CO temperature-programmed reduction (CO-TPR) shows that the high reactivity at low temperatures can be related to the improved reducibility of lattice oxygen on the CeO2 support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1358, "DOI": "10.1038/s41467-019-09308-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09308-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462142200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Sun, MC; Wu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tao; Sun, Mingchao; Wu, Shaohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "State-of-the-Art Review of Electrospun Gelatin-Based nullofiber Dressings for Wound Healing Applications", "Source Title": "nullOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrospun nullofiber materials have been considered as advanced dressing candidates in the perspective of wound healing and skin regeneration, originated from their high porosity and permeability to air and moisture, effective barrier performance of external pathogens, and fantastic extracellular matrix (ECM) fibril mimicking property. Gelatin is one of the most important natural biomaterials for the design and construction of electrospun nullofiber-based dressings, due to its excellent biocompatibility and biodegradability, and great exudate-absorbing capacity. Various crosslinking approaches including physical, chemical, and biological methods have been introduced to improve the mechanical stability of electrospun gelatin-based nullofiber mats. Some innovative electrospinning strategies, including blend electrospinning, emulsion electrospinning, and coaxial electrospinning, have been explored to improve the mechanical, physicochemical, and biological properties of gelatin-based nullofiber mats. Moreover, numerous bioactive components and therapeutic agents have been utilized to impart the electrospun gelatin-based nullofiber dressing materials with multiple functions, such as antimicrobial, anti-inflammation, antioxidation, hemostatic, and vascularization, as well as other healing-promoting capacities. Noticeably, electrospun gelatin-based nullofiber mats integrated with specific functions have been fabricated to treat some hard-healing wound types containing burn and diabetic wounds. This work provides a detailed review of electrospun gelatin-based nullofiber dressing materials without or with therapeutic agents for wound healing and skin regeneration applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 784, "DOI": "10.3390/nullo12050784", "DOI Link": "http://dx.doi.org/10.3390/nullo12050784", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771256600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, YS; Xu, X; Bi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yangsen; Xu, Xi; Bi, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-entropy spinel ceramic oxide as the cathode for proton-conducting solid oxide fuel cells", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-entropy ceramic oxide is used as the cathode for the first time for proton-conducting solid oxide fuel cells (H-SOFCs). The Fe0.6Mn0.6Co0.6Ni0.6Cr0.6O4 (FMCNC) high-entropy spinel oxide has been successfully prepared, and the in situ chemical stability test demonstrates that the FMCNC material has good stability against CO2. The first-principles calculation indicates that the high-entropy structure enhances the properties of the FMCNC material that surpasses their individual components, leading to lower O-2 adsorption energy for FMCNC than that for the individual components. The H-SOFC using the FMCNC cathode reaches an encouraging peak power density (PPD) of 1052 mW.cm(-2) at 700 degrees C, which is higher than those of the H-SOFCs reported recently. Additional comparison was made between the high-entropy FMCNC cathode and the traditional Mn1.6Cu1.4O4 (MCO) spinel cathode without the high-entropy structure, revealing that the formation of the high-entropy material allows the enhanced protonation ability as well as the movement of the O p-band center closer to the Fermi level, thus improving the cathode catalytic activity. As a result, the high-entropy FMCNC has a much-decreased polarization resistance of 0.057 Omega.cm(2) at 700 degrees C, which is half of that for the traditional MCO spinel cathode without the high-entropy design. The excellent performance of the FMCNC cell indicates that the high-entropy design makes a new life for the spinel oxide as the cathode for H-SOFCs, offering a novel and promising route for the development of high-performance materials for H-SOFCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 11, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 794, "End Page": 804, "Article Number": null, "DOI": "10.1007/s40145-022-0573-7", "DOI Link": "http://dx.doi.org/10.1007/s40145-022-0573-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783826800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, B; Ma, Y; Dong, F; Yu, J; Ma, ML; Thabet, HK; El-Bahy, SM; Ibrahim, MM; Huang, MN; Seok, I; Roymahapatra, G; Naik, N; Xu, BB; Ding, JX; Li, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Bo; Ma, Yong; Dong, Feng; Yu, Jia; Ma, Mingliang; Thabet, Hamdy Khamees; El-Bahy, Salah M.; Ibrahim, Mohamed M.; Huang, Mina; Seok, Ilwoo; Roymahapatra, Gourisankar; Naik, Nithesh; Xu, Ben Bin; Ding, Jianxu; Li, Tingxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overview of MXene and conducting polymer matrix composites for electromagnetic wave absorption", "Source Title": "ADVANCED COMPOSITES AND HYBRID MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapidly developing wireless communication technology, electromagnetic pollution problems have become more prominent. Electromagnetic pollution has caused great harm to wireless equipment, precision instruments, military safety, etc., which urgently requires the development of lightweight, high-efficiency, broadband electromagnetic waves (EMW) absorbing materials. MXene is an emerging two-dimensional (2D) material with the advantages of lamellar structure, excellent conductivity, and abundant surface groups. At the same time, conducting polymers (CPs) have excellent performance in terms of conductivity, surface activity, quality, and electromagnetic loss, making them have excellent potential in EMW absorbing direction. This article examines the preparation, structure, and performance of MXene and CPs-based radar-absorbing materials (RAM). A comprehensive summary and objective analysis of the nowadays study progress on the EMW absorbing performances of MXene and CPs, and a comprehension of the absorbing mechanism are reviewed. Finally, the research direction of absorbing materials has been prospected.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 704, "End Page": 754, "Article Number": null, "DOI": "10.1007/s42114-022-00510-6", "DOI Link": "http://dx.doi.org/10.1007/s42114-022-00510-6", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819706300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, JL; Jurado, Z; Chen, Z; Fan, SH; Minnich, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Jun-Long; Jurado, Zoila; Chen, Zhen; Fan, Shanhui; Minnich, Austin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Daytime Radiative Cooling Using Near-Black Infrared Emitters", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent works have demonstrated that daytime radiative cooling under direct sunlight can be achieved using multilayer thin films designed to emit in the infrared atmospheric transparency window while reflecting visible light. Here, we demonstrate that a polymer-coated fused silica mirror, as a near-ideal blackbody in the mid-infrared and near-ideal reflector in the solar spectrum, achieves radiative cooling below ambient air temperature under direct sunlight (8.2 degrees C) and at night (8.4 degrees C). Its performance exceeds that of a multilayer thin film stack fabricated using vacuum deposition methods by nearly 3 degrees C. Furthermore, we estimate the cooler has an average net cooling power of about 127 W m(-2) during daytime at ambient temperature even considering the significant influence of external conduction and convection, more than twice that reported previously. Our work demonstrates that abundant materials and straightforward fabrication can be used to achieve daytime radiative cooling, advancing applications such as dry cooling of thermal power plants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 626, "End Page": 630, "Article Number": null, "DOI": "10.1021/acsphotonics.6b00991", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.6b00991", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396808000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GJ; Guo, F; Wu, H; Wen, XK; Yang, L; Jin, W; Zhang, WF; Chang, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Gaojie; Guo, Fei; Wu, Hao; Wen, Xiaokun; Yang, Li; Jin, Wen; Zhang, Wenfeng; Chang, Haixin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Above-room-temperature strong intrinsic ferromagnetism in 2D van der Waals Fe3GaTe2 with large perpendicular magnetic anisotropy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The absence of two-dimensional (2D) van der Waals (vdW) ferromagnetic crystals with both above-room-temperature strong intrinsic ferromagnetism and large perpendicular magnetic anisotropy (PMA) severely hinders practical applications of 2D vdW crystals in next-generation low-power magnetoelectronic and spintronic devices. Here, we report a vdW intrinsic ferromagnetic crystal Fe3GaTe2 that exhibits record-high above-room-temperature Curie temperature (T-c, similar to 350-380 K) for known 2D vdW intrinsic ferromagnets, high saturation magnetic moment (40.11 emu/g), large PMA energy density (similar to 4.79 x 10(5)J/m(3)), and large anomalous Hall angle (3%) at room temperature. Such large room-temperature PMA is better than conventional widely-used ferromagnetic films like CoFeB, and one order of magnitude larger than known 2D vdW intrinsic ferromagnets. Room-temperature thickness and angledependent anomalous Hall devices and direct magnetic domains imaging based on Fe3GaTe2 nullosheet have been realized. This work provides an avenue for room-temperature 2D ferromagnetism, electrical control of 2D ferromagnetism and promote the practical applications of 2D-vdW-integrated spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5067, "DOI": "10.1038/s41467-022-32605-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32605-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000847533800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Manjakkal, L; Pullanchiyodan, A; Yogeswaran, N; Hosseini, ES; Dahiya, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Manjakkal, Libu; Pullanchiyodan, Abhilash; Yogeswaran, Nivasan; Hosseini, Ensieh S.; Dahiya, Ravinder", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Wearable Supercapacitor Based on Conductive PEDOT:PSS-Coated Cloth and a Sweat Electrolyte", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A sweat-based flexible supercapacitor (SC) for self-powered smart textiles and wearable systems is presented. The developed SC uses sweat as the electrolyte and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the active electrode. With PEDOT:PSS coated onto cellulose/polyester cloth, the SC shows specific capacitance of 8.94 F g(-1) (10 mF cm(-2)) at 1 mV s(-1). With artificial sweat, the energy and power densities of the SC are 1.36 Wh kg(-1) and 329.70 W kg(-1), respectively for 1.31 V and its specific capacitance is 5.65 F g(-1). With real human sweat the observed energy and power densities are 0.25 Wh kg(-1), and 30.62 W kg(-1), respectively. The SC performance is evaluated with different volumes of sweat (20, 50, and 100 mu L), bending radii (10, 15, 20 mm), charging/discharging stability (4000 cycles), and washability. With successful on-body testing, the first demonstration of the suitability of a sweat-based SC for self-powered cloth-based sensors to monitor sweat salinity is presented. With attractive performance and the use of body fluids, the presented approach is a safe and sustainable route to meet the power requirements in wearable systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 32, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1907254, "DOI": "10.1002/adma.201907254", "DOI Link": "http://dx.doi.org/10.1002/adma.201907254", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531718600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CX; Liu, Y; Jia, ZR; Zhao, WR; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenxi; Liu, Yue; Jia, Zirui; Zhao, Wanru; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicomponent nulloparticles Synergistic One-Dimensional nullofibers as Heterostructure Absorbers for Tunable and Efficient Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Application of novel radio technologies and equipment inevitably leads to electromagnetic pollution. One-dimensional polymer-based composite membrane structures have been shown to be an effective strategy to obtain high-performance microwave absorbers. Herein, we reported a one-dimensional N-doped carbon nullofibers material which encapsulated the hollow Co3SnC0.7 nullocubes in the fiber lumen by electrospinning. Space charge stacking formed between nulloparticles can be channeled by longitudinal fibrous structures. The dielectric constant of the fibers is highly related to the carbonization temperature, and the great impedance matching can be achieved by synergetic effect between Co3SnC0.7 and carbon network. At 800 & DEG;C, the necklace-like Co3SnC0.7/CNF with 5% low load achieves an excellent RL value of - 51.2 dB at 2.3 mm and the effective absorption bandwidth of 7.44 GHz with matching thickness of 2.5 mm. The multiple electromagnetic wave (EMW) reflections and interfacial polarization between the fibers and the fibers internal contribute a major effect to attenuating the EMW. These strategies for regulating electromagnetic performance can be expanded to other electromagnetic functional materials which facilitate the development of emerging absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13, "DOI": "10.1007/s40820-022-00986-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00986-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000899513300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pati, F; Jang, J; Ha, DH; Kim, SW; Rhie, JW; Shim, JH; Kim, DH; Cho, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pati, Falguni; Jang, Jinah; Ha, Dong-Heon; Kim, Sung Won; Rhie, Jong-Won; Shim, Jin-Hyung; Kim, Deok-Ho; Cho, Dong-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Printing three-dimensional tissue analogues with decellularized extracellular matrix bioink", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to print and pattern all the components that make up a tissue (cells and matrix materials) in three dimensions to generate structures similar to tissues is an exciting prospect of bioprinting. However, the majority of the matrix materials used so far for bioprinting cannot represent the complexity of natural extracellular matrix (ECM) and thus are unable to reconstitute the intrinsic cellular morphologies and functions. Here, we develop a method for the bioprinting of cell-laden constructs with novel decellularized extracellular matrix (dECM) bioink capable of providing an optimized microenvironment conducive to the growth of three-dimensional structured tissue. We show the versatility and flexibility of the developed bioprinting process using tissue-specific dECM bioinks, including adipose, cartilage and heart tissues, capable of providing crucial cues for cells engraftment, survival and long-term function. We achieve high cell viability and functionality of the printed dECM structures using our bioprinting method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1385, "Times Cited, All Databases": 1560, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3935, "DOI": "10.1038/ncomms4935", "DOI Link": "http://dx.doi.org/10.1038/ncomms4935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338831800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, Y; Kang, Q; Liu, YJ; Zhu, YK; Jiang, PK; Mai, YW; Huang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Ying; Kang, Qi; Liu, Yijie; Zhu, Yingke; Jiang, Pingkai; Mai, Yiu-Wing; Huang, Xingyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, Highly Thermally Conductive and Electrically Insulating Phase Change Materials for Advanced Thermal Management of 5G Base Stations and Thermoelectric Generators", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal management has become a crucial problem for high-power-density equipment and devices. Phase change materials (PCMs) have great prospects in thermal management applications because of their large capacity of heat storage and isothermal behavior during phase transition. However, low intrinsic thermal conductivity, ease of leakage, and lack of flexibility severely limit their applications. Solving one of these problems often comes at the expense of other performance of the PCMs. In this work, we report core-sheath structured phase change nullocomposites (PCNs) with an aligned and interconnected boron nitride nullosheet network by combining coaxial electrospinning, electrostatic spraying, and hot-pressing. The advanced PCN films exhibit an ultrahigh thermal conductivity of 28.3 W m(-1) K-1 at a low BNNS loading (i.e., 32 wt%), which thereby endows the PCNs with high enthalpy (> 101 J g(-1)), outstanding ductility (> 40%) and improved fire retardancy. Therefore, our core-sheath strategies successfully balance the trade-off between thermal conductivity, flexibility, and phase change enthalpy of PCMs. Further, the PCNs provide powerful cooling solutions on 5G base station chips and thermoelectric generators, displaying promising thermal management applications on high-power-density equipment and thermoelectric conversion devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1007/s40820-022-01003-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-01003-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911314100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, Y; Ren, CJ; Zheng, LR; Xu, XY; Long, R; Zhang, WQ; Yang, Y; Zhang, YC; Yao, YF; Chi, HQ; Wang, JL; Shen, Q; Xiong, YJ; Zou, ZG; Zhou, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Yan; Ren, Chunjin; Zheng, Lirong; Xu, Xiaoyong; Long, Ran; Zhang, Wenqing; Yang, Yong; Zhang, Yongcai; Yao, Yingfang; Chi, Haoqiang; Wang, Jinlan; Shen, Qing; Xiong, Yujie; Zou, Zhigang; Zhou, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A photocatalyst for CO2 reduction to C3H8 is prepared by implanting Cu single atoms on vacancy rich TiO2 single layers. Key reaction intermediates, *CHOCO and *CH2OCOCO, are stabilized on the catalyst which promotes C-C bond formation. Photochemical conversion of CO2 into high-value C2+ products is difficult to achieve due to the energetic and mechanistic challenges in forming multiple C-C bonds. Herein, an efficient photocatalyst for the conversion of CO2 into C3H8 is prepared by implanting Cu single atoms on Ti0.91O2 atomically-thin single layers. Cu single atoms promote the formation of neighbouring oxygen vacancies (V(O)s) in Ti0.91O2 matrix. These oxygen vacancies modulate the electronic coupling interaction between Cu atoms and adjacent Ti atoms to form a unique Cu-Ti-V-O unit in Ti0.91O2 matrix. A high electron-based selectivity of 64.8% for C3H8 (product-based selectivity of 32.4%), and 86.2% for total C2+ hydrocarbons (product-based selectivity of 50.2%) are achieved. Theoretical calculations suggest that Cu-Ti-V-O unit may stabilize the key *CHOCO and *CH2OCOCO intermediates and reduce their energy levels, tuning both C-1-C-1 and C-1-C-2 couplings into thermodynamically-favourable exothermal processes. Tandem catalysis mechanism and potential reaction pathway are tentatively proposed for C3H8 formation, involving an overall (20e(-) - 20H(+)) reduction and coupling of three CO2 molecules at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1117, "DOI": "10.1038/s41467-023-36778-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36778-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942107800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, JM; Jena, HS; Krishnaraj, C; Rawat, KS; Abednatanzi, S; Chakraborty, J; Laemont, A; Liu, WL; Chen, H; Liu, YY; Leus, K; Vrielinck, H; Van Speybroeck, V; van der Voort, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Jiamin; Jena, Himanshu Sekhar; Krishnaraj, Chidharth; Rawat, Kuber Singh; Abednatanzi, Sara; Chakraborty, Jeet; Laemont, Andreas; Liu, Wanlu; Chen, Hui; Liu, Ying-Ya; Leus, Karen; Vrielinck, Henk; Van Speybroeck, Veronique; Van Der Voort, Pascal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pyrene-Based Covalent Organic Frameworks for Photocatalytic Hydrogen Peroxide Production", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Four highly porous covalent organic frameworks (COFs) containing pyrene units were prepared and explored for photocatalytic H2O2 production. The experimental studies are complemented by density functional theory calculations, proving that the pyrene unit is more active for H2O2 production than the bipyridine and (diarylamino)benzene units reported previously. H2O2 decomposition experiments verified that the distribution of pyrene units over a large surface area of COFs plays an important role in catalytic performance. The Py-Py-COF though contains more pyrene units than other COFs which induces a high H2O2 decomposition due to a dense concentration of pyrene in close proximity over a limited surface area. Therefore, a two-phase reaction system (water-benzyl alcohol) was employed to inhibit H2O2 decomposition. This is the first report on applying pyrene-based COFs in a two-phase system for photocatalytic H2O2 generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2023, "Volume": 62, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202216719", "DOI": "10.1002/anie.202216719", "DOI Link": "http://dx.doi.org/10.1002/anie.202216719", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961538800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Owusu, KA; Qu, LB; Li, JT; Wang, ZY; Zhao, KN; Yang, C; Hercule, KM; Lin, C; Shi, CW; Wei, QL; Zhou, L; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Owusu, Kwadwo Asare; Qu, Longbing; Li, Jiantao; Wang, Zhaoyang; Zhao, Kangning; Yang, Chao; Hercule, Kalele Mulonda; Lin, Chao; Shi, Changwei; Wei, Qiulong; Zhou, Liang; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-crystalline iron oxide hydroxide nulloparticle anode for high-performance supercapacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon materials are generally preferred as anodes in supercapacitors; however, their low capacitance limits the attained energy density of supercapacitor devices with aqueous electrolytes. Here, we report a low-crystalline iron oxide hydroxide nulloparticle anode with comprehensive electrochemical performance at a wide potential window. The iron oxide hydroxide nulloparticles present capacitances of 1,066 and 716 Fg(-1) at mass loadings of 1.6 and 9.1 mgcm(-2), respectively, a rate capability with 74.6% of capacitance retention at 30Ag(-1), and cycling stability retaining 91% of capacitance after 10,000 cycles. The performance is attributed to a dominullt capacitive charge-storage mechanism. An aqueous hybrid supercapacitor based on the iron oxide hydroxide anode shows stability during float voltage test for 450 h and an energy density of 104Whkg(-)1 at a power density of 1.27kWkg(-1). A packaged device delivers gravimetric and volumetric energy densities of 33.14Whkg(-1) and 17.24Whl(-1), respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 621, "Times Cited, All Databases": 645, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14264, "DOI": "10.1038/ncomms14264", "DOI Link": "http://dx.doi.org/10.1038/ncomms14264", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395500800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Jiang, GB; Chen, SQ; Guo, ZN; Yu, XF; Zhao, CJ; Zhang, H; Bao, QL; Wen, SC; Tang, DY; Fan, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yu; Jiang, Guobao; Chen, Shuqing; Guo, Zhinull; Yu, Xuefeng; Zhao, Chujun; Zhang, Han; Bao, Qiaoliang; Wen, Shuangchun; Tang, Dingyuan; Fan, Dianyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus (BP), an emerging narrow direct band-gap two-dimensional (2D) layered material that can fill the gap between the semi-metallic graphene and the wide-bandgap transition metal dichalcogenides (TMDs), had been experimentally found to exhibit the saturation of optical absorption if under strong light illumination. By taking advantage of this saturable absorption property, we could fabricate a new type of optical saturable absorber (SA) based on mechanically exfoliated BPs, and further demonstrate the applications for ultra-fast laser photonics. Based on the balanced synchronous twin-detector measurement method, we have characterized the saturable absorption property of the fabricated BPSAs at the telecommunication band. By incorporating the BP-based SAs device into the all-fiber Erbium-doped fiber laser cavities, we are able to obtain either the passive Q-switching (with maximum pulse energy of 94.3 nJ) or the passive mode-locking operation (with pulse duration down to 946 fs). Our results show that BP could also be developed as an effective SA for pulsed fiber or solid-state lasers. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 920, "Times Cited, All Databases": 973, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2015, "Volume": 23, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12823, "End Page": 12833, "Article Number": null, "DOI": "10.1364/OE.23.012823", "DOI Link": "http://dx.doi.org/10.1364/OE.23.012823", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354706800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Griffin, DR; Archang, MM; Kuan, CH; Weaver, WM; Weinstein, JS; Feng, AC; Ruccia, A; Sideris, E; Ragkousis, V; Koh, J; Plikus, MV; Di Carlo, D; Segura, T; Scumpia, PO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Griffin, Donald R.; Archang, Maani M.; Kuan, Chen-Hsiang; Weaver, Westbrook M.; Weinstein, Jason S.; Feng, An Chieh; Ruccia, Amber; Sideris, Elias; Ragkousis, Vasileios; Koh, Jaekyung; Plikus, Maksim, V; Di Carlo, Dino; Segura, Tatiana; Scumpia, Philip O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating an adaptive immune response from a hydrogel scaffold imparts regenerative wound healing", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microporous annealed particle (MAP) scaffolds are flowable, in situ crosslinked, microporous scaffolds composed of microgel building blocks and were previously shown to accelerate wound healing. To promote more extensive tissue ingrowth before scaffold degradation, we aimed to slow MAP degradation by switching the chirality of the crosslinking peptides from L- to D-amino acids. Unexpectedly, despite showing the predicted slower enzymatic degradation in vitro, D-peptide crosslinked MAP hydrogel (D-MAP) hastened material degradation in vivo and imparted significant tissue regeneration to healed cutaneous wounds, including increased tensile strength and hair neogenesis. MAP scaffolds recruit IL-33 type 2 myeloid cells, which is amplified in the presence of D-peptides. Remarkably, D-MAP elicited significant antigen-specific immunity against the D-chiral peptides, and an intact adaptive immune system was required for the hydrogel-induced skin regeneration. These findings demonstrate that the generation of an adaptive immune response from a biomaterial is sufficient to induce cutaneous regenerative healing despite faster scaffold degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 20, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 560, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-00844-w", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-00844-w", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000587948400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, J; He, QJ; Yang, GM; Zhou, W; Shao, ZP; Ni, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Jie; He, Qijiao; Yang, Guangming; Zhou, Wei; Shao, Zongping; Ni, Meng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Advances and Prospective in Ruthenium-Based Materials for Electrochemical Water Splitting", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a highly appealing technology for hydrogen generation, water electrolysis including oxygen evolution reaction (OER) at the anode and hydrogen evolution reaction (HER) at the cathode largely depends on the availability of efficient electrocatalysts. Accordingly, over the past years, much effort has been made to develop various electrocatalysts with superior performance and reduced cost. Among them, ruthenium (Ru)-based materials for OER and HER are very promising because of their prominent catalytic activity, pH-universal application, the cheapest price among the precious metal family, and so on. Herein, recent advances in this hot research field are comprehensively reviewed. A general description about water splitting is presented to understand the reaction mechanism and proposed scaling relations toward activities, and key stability issues for Ru-based materials are further given. Subsequently, various Ru-involving electrocatalysts are introduced and classified into different groups for improving or optimizing electrocatalytic properties, with a special focus on several significant bifunctional electrocatalysts along with a simulated water electrolyzer. Finally, a perspective on the existing challenges and future progress of Ru-based catalysts toward OER and HER is provided. The main aim here is to shed some light on the design and construction of emerging catalysts for energy storage and conversion technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 603, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9973, "End Page": 10011, "Article Number": null, "DOI": "10.1021/acscatal.9b02457", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b02457", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494549700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, WJ; Upadhyaya, P; Zhang, W; Yu, GQ; Jungfleisch, MB; Fradin, FY; Pearson, JE; Tserkovnyak, Y; Wang, KL; Heinonen, O; te Velthuis, SGE; Hoffmann, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Wanjun; Upadhyaya, Pramey; Zhang, Wei; Yu, Guoqiang; Jungfleisch, M. Benjamin; Fradin, Frank Y.; Pearson, John E.; Tserkovnyak, Yaroslav; Wang, Kang L.; Heinonen, Olle; te Velthuis, Suzanne G. E.; Hoffmann, Axel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blowing magnetic skyrmion bubbles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of soap bubbles from thin films is accompanied by topological transitions. Here we show how a magnetic topological structure, a skyrmion bubble, can be generated in a solid-state system in a similar manner. Using an inhomogeneous in-plane current in a system with broken inversion symmetry, we experimentally blow magnetic skyrmion bubbles from a geometrical constriction. The presence of a spatially divergent spin-orbit torque gives rise to instabilities of the magnetic domain structures that are reminiscent of Rayleigh-Plateau instabilities in fluid flows. We determine a phase diagram for skyrmion formation and reveal the efficient manipulation of these dynamically created skyrmions, including depinning and motion. The demonstrated current-driven transformation from stripe domains to magnetic skyrmion bubbles could lead to progress in skyrmion-based spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1212, "Times Cited, All Databases": 1288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2015, "Volume": 349, "Issue": 6245, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 283, "End Page": 286, "Article Number": null, "DOI": "10.1126/science.aaa1442", "DOI Link": "http://dx.doi.org/10.1126/science.aaa1442", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358218600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, RN; Tian, WG; Bai, HT; Zhang, JM; Wang, S; Zhang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Ruonull; Tian, Weiguo; Bai, Haotian; Zhang, Jinming; Wang, Shu; Zhang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amine-responsive cellulose-based ratiometric fluorescent materials for real-time and visual detection of shrimp and crab freshness", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we design and prepare cellulose-based ratiometric fluorescent materials with superior amine-response, which offers the real-time and visual detection of seafood freshness. Through utilizing the reactive hydroxyl groups along cellulose chains, we covalently immobilize the fluorescein isothiocyanate (FITC) as indicator and protoporphyrin IX (PpIX) as internal reference onto cellulose acetate (CA), respectively. Subsequently, a series of dual-emission solid fluorescent materials are achieved by simply blending green emitting CA-FITC with red-emitting CA-PpIX with varying ratios. They exhibit a sensitive, color-responsive, rapid and linear response to ammonia in a wide range of 5.0 ppm to 2.5 x 10(4) ppm. Benefiting from the excellent solubility and processibility of cellulose derivatives, the as-prepared materials are readily processed into different material forms, including printing ink, coating, flexible film, and nullofibrous membrane. The electrospun nullofibrous membrane is successfully employed as a low-cost, high-contrasting, quick-responsive fluorescent trademark for visual monitoring the freshness of shrimp and crab.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 795, "DOI": "10.1038/s41467-019-08675-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08675-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458755400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LW; Wang, JK; Zhang, DW; Huang, Y; Huang, LY; Wang, PJ; Qian, HC; Li, XG; Terryn, HA; Mol, JMC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Lingwei; Wang, Jinke; Zhang, Dawei; Huang, Yao; Huang, Luyao; Wang, Panjun; Qian, Hongchang; Li, Xiaogang; Terryn, Herman A.; Mol, Johannes M. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-action self-healing protective coatings with photothermal responsive corrosion inhibitor nullocontainers", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work introduces a novel nullocomposite coating with dual-action self-healing corrosion protection activated by the photothermal response of plasmonic titanium nitride nulloparticles (TiN NPs). TiN@mesoporous SiO2 core-shell nullocontainers were developed as reservoirs for benzotriazole (BTA) corrosion inhibitors and incorporated into the shape memory epoxy coating matrix. Under near-infrared (NIR) light irradiation, the thermogenesis effect of TiN could not only promote the release of corrosion inhibitors from nullocontainers into the crevice, but also trigger the shape memory effect of damaged epoxy to merge the coating scratch. As such, the dual-action self-healing mechanisms combining the formation of an inhibitor-based protective layer and the scratch closure efficiently suppressed the corrosion process at the exposed metal surface. Surface characterization and electrochemical measurement results proved that the nullocomposite coating incorporated with 2 wt% of TiN-BTA@SiO2 exhibited the optimal corrosion protection as well as an excellent self-healing performance that can be initiated within 30 s of NIR illumination. This photo-controlled self-healing approach is potentially useful in designing next-generation self-healing coatings with ultrafast response time and high healing efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 404, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127118, "DOI": "10.1016/j.cej.2020.127118", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.127118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600981800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, SY; Salim, T; Mathews, N; Duchamp, M; Boothroyd, C; Xing, GC; Sum, TC; Lam, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Shuangyong; Salim, Teddy; Mathews, Nripan; Duchamp, Martial; Boothroyd, Chris; Xing, Guichuan; Sum, Tze Chien; Lam, Yeng Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work reports a study into the origin of the high efficiency in solution-processable bilayer solar cells based on methylammonium lead iodide (CH(3)NH(3)Pbl(3)) and [6,6]-phenyl-C-61-butyric acid methyl ester (PC61BM). Our cell has a power conversion efficiency (PCE) of 5.2% under simulated AM 1.5G irradiation (100 mW cm(-2)) and an internal quantum efficiency of close to 100%, which means that nearly all the absorbed photons are converted to electrons and are efficiently collected at the electrodes. This implies that the exciton diffusion, charge transfer and charge collection are highly efficient. The high exciton diffusion efficiency is enabled by the long diffusion length of CH(3)NH(3)Pbl(3) relative to its thickness. Furthermore, the low exciton binding energy of CH(3)NH(3)Pbl(3) implies that exciton splitting at the CH(3)NH(3)Pbl(3)/PC61BM interface is very efficient. With further increase in CH(3)NH(3)Pbl(3) thickness, a higher PCE of 7.4% could be obtained. This is the highest efficiency attained for low temperature solution-processable bilayer solar cells to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 978, "Times Cited, All Databases": 1053, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 399, "End Page": 407, "Article Number": null, "DOI": "10.1039/c3ee43161d", "DOI Link": "http://dx.doi.org/10.1039/c3ee43161d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329550700030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, SJ; Luo, M; Ai, CZ; Zhang, Y; Liu, B; Huang, L; Jiang, Z; Zhang, QH; Gu, L; Lin, SW; Wang, XL; Yu, L; Wen, JG; Wang, JA; Pan, GX; Xia, XH; Tu, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Shengjue; Luo, Mi; Ai, Changzhi; Zhang, Yan; Liu, Bo; Huang, Lei; Jiang, Zheng; Zhang, Qinghua; Gu, Lin; Lin, Shiwei; Wang, Xiuli; Yu, Lei; Wen, Jianguo; Wang, Jiaao; Pan, Guoxiang; Xia, Xinhui; Tu, Jiangping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Doping and Intercalation: Realizing Deep Phase Modulation on MoS2 Arrays for High-Efficiency Hydrogen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A synergistic N doping plus PO43- intercalation strategy is used to induce high conversion (ca. 41 %) of 2H-MoS2 into 1T-MoS2, which is much higher than single N doping (ca. 28 %) or single PO43- intercalation (ca. 10 %). A scattering mechanism is proposed to illustrate the synergistic phase transformation from the 2H to the 1T phase, which was confirmed by synchrotron radiation and spherical aberration TEM. To further enhance reaction kinetics, the designed (N,PO43-)-MoS2 nullosheets are combined with conductive vertical graphene (VG) skeleton forming binder-free arrays for high-efficiency hydrogen evolution reaction (HER). Owing to the decreased band gap, lower d-band center, and smaller hydrogen adsorption/desorption energy, the designed (N,PO43-)-MoS2/VG electrode shows excellent HER performance with a lower Tafel slope and overpotential than N-MoS2/VG, PO43--MoS2/VG counterparts, and other Mo-base catalysts in the literature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2019, "Volume": 58, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16289, "End Page": 16296, "Article Number": null, "DOI": "10.1002/anie.201909698", "DOI Link": "http://dx.doi.org/10.1002/anie.201909698", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487456400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Si, RT; Liu, HS; Chen, N; Wang, Q; Adair, K; Wang, ZQ; Chen, JT; Song, ZX; Li, JJ; Banis, MN; Li, RY; Sham, TK; Gu, M; Liu, LM; Botton, GA; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lei; Si, Rutong; Liu, Hanshuo; Chen, Ning; Wang, Qi; Adair, Keegan; Wang, Zhiqiang; Chen, Jiatang; Song, Zhongxin; Li, Junjie; Banis, Mohammad Norouzi; Li, Ruying; Sham, Tsun-Kong; Gu, Meng; Liu, Li-Min; Botton, Gianluigi A.; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic layer deposited Pt-Ru dual-metal dimers and identifying their active sites for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single atom catalysts exhibit particularly high catalytic activities in contrast to regular nullomaterial-based catalysts. Until recently, research has been mostly focused on single atom catalysts, and it remains a great challenge to synthesize bimetallic dimer structures. Herein, we successfully prepare high-quality one-to-one A-B bimetallic dimer structures (Pt-Ru dimers) through an atomic layer deposition (ALD) process. The Pt-Ru dimers show much higher hydrogen evolution activity (more than 50 times) and excellent stability compared to commercial Pt/C catalysts. X-ray absorption spectroscopy indicates that the Pt-Ru dimers structure model contains one Pt-Ru bonding configuration. First principle calculations reveal that the Pt-Ru dimer generates a synergy effect by modulating the electronic structure, which results in the enhanced hydrogen evolution activity. This work paves the way for the rational design of bimetallic dimers with good activity and stability, which have a great potential to be applied in various catalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4936, "DOI": "10.1038/s41467-019-12887-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12887-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493275600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boland, CS; Khan, U; Backes, C; O'Neill, A; McCauley, J; Duane, S; Shanker, R; Liu, Y; Jurewicz, I; Dalton, AB; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boland, Conor S.; Khan, Umar; Backes, Claudia; O'Neill, Arlene; McCauley, Joe; Duane, Shane; Shanker, Ravi; Liu, Yang; Jurewicz, Izabela; Dalton, Alan B.; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive, High-Strain, High-Rate Bodily Motion Sensors Based on Graphene-Rubber Composites", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monitoring of human bodily motion requires wearable sensors that can detect position, velocity and acceleration. They should be cheap, lightweight, mechanically compliant and display reasonable sensitivity at high strains and strain rates. No reported material has simultaneously demonstrated all the above requirements. Here we describe a simple method to infuse liquid-exfoliated graphene into natural rubber to create conducting composites. These materials are excellent strain sensors displaying 10(4)-fold increases in resistance and working at strains exceeding 800%. The sensitivity is reasonably high, with gauge factors of up to 35 observed. More importantly, these sensors can effectively track dynamic strain, working well at vibration frequencies of at least 160 Hz. At 60 Hz, we could monitor strains of at least 6% at strain rates exceeding 6000%/s. We have used these composites as bodily motion sensors, effectively monitoring joint and muscle motion as well and breathing and pulse.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 660, "Times Cited, All Databases": 723, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8819, "End Page": 8830, "Article Number": null, "DOI": "10.1021/nn503454h", "DOI Link": "http://dx.doi.org/10.1021/nn503454h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342184400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhan, CH; Xu, Y; Bu, LZ; Zhu, HZ; Feng, YG; Yang, T; Zhang, Y; Yang, ZQ; Huang, BL; Shao, Q; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhan, Changhong; Xu, Yong; Bu, Lingzheng; Zhu, Huaze; Feng, Yonggang; Yang, Tang; Zhang, Ying; Yang, Zhiqing; Huang, Bolong; Shao, Qi; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subnullometer high-entropy alloy nullowires enable remarkable hydrogen oxidation catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) have attracted increasing attention in diverse field. Here, the authors report PtRuNiCoFeMo HEA with enhanced activity, stability and preferable CO anti-poisoning in alkaline hydrogen oxidation reaction. High-entropy alloys (HEAs) with unique physicochemical properties have attracted tremendous attention in many fields, yet the precise control on dimension and morphology at atomic level remains formidable challenges. Herein, we synthesize unique PtRuNiCoFeMo HEA subnullometer nullowires (SNWs) for alkaline hydrogen oxidation reaction (HOR). The mass and specific activities of HEA SNWs/C reach 6.75 A mg(Pt+Ru)(-1) and 8.96 mA cm(-2), respectively, which are 2.8/2.6, 4.1/2.4, and 19.8/18.7 times higher than those of HEA NPs/C, commercial PtRu/C and Pt/C, respectively. It can even display enhanced resistance to CO poisoning during HOR in the presence of 1000 ppm CO. Density functional theory calculations reveal that the strong interactions between different metal sites in HEA SNWs can greatly regulate the binding strength of proton and hydroxyl, and therefore enhances the HOR activity. This work not only provides a viable synthetic route for the fabrication of Pt-based HEA subnullo/nullo materials, but also promotes the fundamental researches on catalysis and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6261, "DOI": "10.1038/s41467-021-26425-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26425-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000712910500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, H; Chen, L; Lian, YB; Yang, WJ; Lin, L; Chen, YF; Xu, JB; Wang, D; Yang, XQ; Rümmerli, MH; Guo, J; Zhong, J; Deng, Z; Jiao, Y; Peng, Y; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Hao; Chen, Ling; Lian, Yuebin; Yang, Wenjuan; Lin, Ling; Chen, Yufeng; Xu, Jiabin; Wang, Dan; Yang, Xiaoqin; Rummerli, Mark H.; Guo, Jun; Zhong, Jun; Deng, Zhao; Jiao, Yan; Peng, Yang; Qiao, Shizhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topotactically Transformed Polygonal Mesopores on Ternary Layered Double Hydroxides Exposing Under-Coordinated Metal Centers for Accelerated Water Dissociation", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered double hydroxides (LDHs) have been recognized as potent electrocatalysts for oxygen evolution reaction (OER), but are lacking in hydrogen evolution reaction (HER) activities due to the sluggish kinetics of water dissociation in alkaline medium. Herein, aiming to simultaneously bolster the HER and OER kinetics, a metal-organic framework (MOF) mediated topotactic transformation tactic is deployed to fabricate holey ternary CoFeNi LDHs on nickel foam, exposing polygonal mesopores with atomistic edge steps and lattice defects. The optimized catalyst requires only an external voltage of 1.49 V to afford the water splitting current density of 10 mA cm(-2) apart from the superb electrolytic stability, far surpassing the benchmark Pt/C||RuO2 couple. More importantly, mechanistic investigations utilizing advanced spectroscopies in conjunction with density function theory (DFT) understandings unravel while the synergetic effect among under-coordinated metal centers lowers the energy barrier of water dissociation, Fe-doping enables further modulating the d-band density of states (DOS) of Co and Ni in favor of intermediates binding, thereby promoting the intrinsic HER activity. Operando Raman studies reveal negligible structural change of the LDHs during the HER process, whereas for OER the active sites can quickly turn into oxyhydroxides in the presence of lattice defects and under-coordinated metal centers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 32, "Issue": 52, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2006784, "DOI": "10.1002/adma.202006784", "DOI Link": "http://dx.doi.org/10.1002/adma.202006784", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000588659800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, F; Jin, SB; Zhong, H; Wu, DC; Yang, XQ; Chen, X; Wei, H; Fu, RW; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Fei; Jin, Shangbin; Zhong, Hui; Wu, Dingcai; Yang, Xiaoqing; Chen, Xiong; Wei, Hao; Fu, Ruowen; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically active, crystalline, mesoporous covalent organic frameworks on carbon nullotubes for synergistic lithium-ion battery energy storage", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic batteries free of toxic metal species could lead to a new generation of consumer energy storage devices that are safe and environmentally benign. However, the conventional organic electrodes remain problematic because of their structural instability, slow ion-diffusion dynamics, and poor electrical conductivity. Here, we report on the development of a redox-active, crystalline, mesoporous covalent organic framework (COF) on carbon nullotubes for use as electrodes; the electrode stability is enhanced by the covalent network, the ion transport is facilitated by the open meso-channels, and the electron conductivity is boosted by the carbon nullotube wires. These effects work synergistically for the storage of energy and provide lithium-ion batteries with high efficiency, robust cycle stability, and high rate capability. Our results suggest that redox-active COFs on conducting carbons could serve as a unique platform for energy storage and may facilitate the design of new organic electrodes for high-performance and environmentally benign battery devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8225, "DOI": "10.1038/srep08225", "DOI Link": "http://dx.doi.org/10.1038/srep08225", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348767600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; You, WB; Xu, CY; Wang, L; Yang, LT; Li, YS; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiao; You, Wenbin; Xu, Chunyang; Wang, Lei; Yang, Liting; Li, Yuesheng; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Seed-Germination-Like MXene with In Situ Growing CNTs/Ni Heterojunction for Enhanced Microwave Absorption via Polarization and Magnetization", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ti3C2Tx MXene is widely regarded as a potential microwave absorber due to its dielectric multi-layered structure. However, missing magnetic loss capability of pure MXene leads to the unmatched electromagnetic parameters and unsatisfied impedance matching condition. Herein, with the inspiration from dielectric-magnetic synergy, this obstruction is solved by fabricating magnetic CNTs/Ni hetero-structure decorated MXene substrate via a facile in situ induced growth method. Ni2+ ions are successfully attached on the surface and interlamination of each MXene unit by intensive electrostatic adsorption. Benefiting from the possible seed-germination effect, the seeds Ni2+ grow into buds Ni nulloparticles and stem carbon nullotubes (CNTs) from the enlarged soil of MXene skeleton. Due to the improved impedance matching condition, the MXene-CNTs/Ni hybrid holds a superior microwave absorption performance of - 56.4 dB at only 2.4 mm thickness. Such a distinctive 3D architecture endows the hybrids: (i) a large-scale 3D magnetic coupling network in each dielectric unit that leading to the enhanced magnetic loss capability, (ii) a massive multi-heterojunction interface structure that resulting in the reinforced polarization loss capability, confirmed by the off-axis electron holography. These outstanding results provide novel ideas for developing magnetic MXene-based absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 157, "DOI": "10.1007/s40820-021-00680-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00680-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000674624700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chin, XY; Cortecchia, D; Yin, J; Bruno, A; Soci, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chin, Xin Yu; Cortecchia, Daniele; Yin, Jun; Bruno, Annalisa; Soci, Cesare", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead iodide perovskite light-emitting field-effect transistor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the widespread use of solution-processable hybrid organic-inorganic perovskites in photovoltaic and light-emitting applications, determination of their intrinsic charge transport parameters has been elusive due to the variability of film preparation and history-dependent device performance. Here we show that screening effects associated to ionic transport can be effectively eliminated by lowering the operating temperature of methylammonium lead iodide perovskite (CH3NH3PbI3) field-effect transistors. Field-effect carrier mobility is found to increase by almost two orders of magnitude below 200 K, consistent with phonon scattering-limited transport. Under balanced ambipolar carrier injection, gate-dependent electroluminescence is also observed from the transistor channel, with spectra revealing the tetragonal to orthorhombic phase transition. This demonstration of CH3NH3PbI3 light-emitting field-effect transistors provides intrinsic transport parameters to guide materials and solar cell optimization, and will drive the development of new electro-optic device concepts, such as gated light-emitting diodes and lasers operating at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 660, "Times Cited, All Databases": 700, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7383, "DOI": "10.1038/ncomms8383", "DOI Link": "http://dx.doi.org/10.1038/ncomms8383", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Yang, B; Tyo, E; Seifert, S; DeBartolo, J; von Issendorff, B; Zapol, P; Vajda, S; Curtiss, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Cong; Yang, Bing; Tyo, Eric; Seifert, Soenke; DeBartolo, Janae; von Issendorff, Bernd; Zapol, Peter; Vajda, Stefan; Curtiss, Larry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Dioxide Conversion to Methanol over Size-Selected Cu4 Clusters at Low Pressures", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The activation of CO2 and its hydrogenation to methanol are of much interest as a way to utilize captured CO2. Here, we investigate the use of size-selected Cu-4 clusters supported on Al2O3 thin films for CO2 reduction in the presence of hydrogen. The catalytic activity was measured under near-atmospheric reaction conditions with a low CO2 partial pressure, and the oxidation state of the clusters was investigated by in situ grazing incidence X-ray absorption spectroscopy. The results indicate that size-selected Cu-4 clusters are the most active low-pressure catalyst for catalytic CO2 conversion to CH3OH. Density functional theory calculations reveal that Cu-4 clusters have a low activation barrier for conversion of CO2 to CH3OH. This study suggests that small Cu clusters may be excellent and efficient catalysts for the recycling of released CO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2015, "Volume": 137, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8676, "End Page": 8679, "Article Number": null, "DOI": "10.1021/jacs.5b03668", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b03668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358186700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Peng, ZX; Huang, CL; Zhang, BW; Xing, C; Chen, HM; Cheng, HY; Wang, J; Tang, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Cheng; Peng, Zhixiang; Huang, Chunlei; Zhang, Bingwen; Xing, Chao; Chen, Huamin; Cheng, Huanyu; Wang, Jun; Tang, Shaolong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-energy all-in-one stretchable micro-supercapacitor arrays based on 3D laser-induced graphene foams decorated with mesoporous ZnP nullosheets for self-powered stretchable systems", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Micro-supercapacitors are promising energy storage devices that can complement or even replace lithium-ion batteries in wearable and stretchable microelectronics. However, they often possess a relatively low energy density and limited mechanical stretchability. Here, we report an all-in-one planar micro-supercapacitor arrays (MSCAs) based on hybrid electrodes with ultrathin ZnP nullosheets anchored on 3D laser-induced graphene foams (ZnP@LIG) arranged in island-bridge device architecture. The hybrid electrodes with a large specific surface area demonstrate excellent ionic and electrical conductivities, impressive gravimetric (areal) capacitance of 1425 F g(-1) (7.125 F cm(-2)) at 1 A g(-1), and long-term stability. In addition to high energy (245 m Wh cm(-2)) and power (12.50 mW kg(-1) at 145 m Wh cm(-2)) densities, the MSCAs with excellent cycling stability also showcase adjustable voltage and current outputs through serial and parallel connections of MSC cells in the island-bridge design, which also allows the system to be reversibly stretched up to 100%. Meanwhile, theoretical calculations validated by UV-vis absorption spectra partially suggest that the enhanced capacitance and rate capability may result from the improved electrical conductivity and number of adsorbed charged ions (Na+ in Na2SO4 aqueous electrolyte and K+ in PVA/KCl gel electrolyte) on the pseudocapacitive non-layered ultrathin ZnP nullosheets. The integration of the all-in-one stretchable MSCAs with a crumpled Au-based triboelectric nullogenerator and stretchable crumpled graphene-based strain sensor demonstrates a self-powered stretchable system. The coupled design principle of electronic materials and device architecture provides a promising method to develop high-performance wearable/stretchable energy storage devices and self-powered stretchable systems for future bio-integrated electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105609, "DOI": "10.1016/j.nulloen.2020.105609", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105609", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620327200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, Y; Ho, WSW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Yang; Ho, W. S. Winston", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymeric membranes for CO2 separation and capture", "Source Title": "JOURNAL OF MEMBRANE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past decade, CO2 separation and capture have become the new bandwagon for polymer science and membrane research. This review presents the fundamentals of CO2/gas separation in polymeric membranes and discusses how these principles underpin opportunities and challenges for post-combustion carbon capture (CO2/ N2), hydrogen purification (CO2/H2), and natural gas and biogas sweetening (CO2/CH4). Emerging polymeric membrane materials are discussed, including a few polymers containing a high content of polar functional groups (i.e., ether oxygen-rich polymers and polymeric ionic liquids), shape-persisting glassy polymers (i.e., perfluoropolymers, thermally rearranged polymers, iptycene-containing polymers), and reactive polymers featuring facilitated transport. Moreover, the promising candidates for each CO2 separation application are highlighted. Finally, the permeability-selectivity data reviewed were plotted against their 2008 and 2019 upper bounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 628, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119244, "DOI": "10.1016/j.memsci.2021.119244", "DOI Link": "http://dx.doi.org/10.1016/j.memsci.2021.119244", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640907600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LF; Zhang, XY; Ikram, M; Ullah, M; Wu, HY; Shi, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Laifeng; Zhang, Xueyi; Ikram, Muhammad; Ullah, Mohib; Wu, Hongyuan; Shi, Keying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controllable synthesis of an intercalated ZIF-67/EG structure for the detection of ultratrace Cd2+, Cu2+, Hg2+ and Pb2+ ions", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fabricated intercalated structure composed of a Co-based zeolitic imidazolate framework (ZIF-67) and expanded graphite (EG) has been prepared using a facile and simple one-pot hydrothermal reaction. This framework was used to detect heavy metal ions (HMIs) via a square wave anodic stripping voltammetry (SWASV) method for the first time. Here, the composite material is useful for the selective electrochemical detection of nullomolar Cd2+, Pb2+, Cu2+ and Hg2+ in aqueous solutions simultaneously or individually. The operational parameters such as pH, electrolyte, deposition potential, and deposition time were optimized to detect various HMIs. The electrochemical properties and applications of the modified electrode were also studied. The constructed electrochemical sensor displays good performance with a large electrochemically active surface areas, high sensitivity and low limit of detection (LOD). These impressive features originate from the synergistic effects of ZIF-67 and EG. This study proposes a new strategy for heavy metal ion detection using a novel morphology of a metal-organic framework (MOF) composite.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2020, "Volume": 395, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125216, "DOI": "10.1016/j.cej.2020.125216", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.125216", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537390100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Wang, ZY; Dinh, CT; Li, J; Ozden, A; Kibria, MG; Seifitokaldani, A; Tan, CS; Gabardo, CM; Luo, MC; Zhou, H; Li, FW; Lum, Y; McCallum, C; Xu, Y; Liu, MX; Proppe, A; Johnston, A; Todorovic, P; Zhuang, TT; Sinton, D; Kelley, SO; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuhang; Wang, Ziyun; Dinh, Cao-Thang; Li, Jun; Ozden, Adnull; Golam Kibria, Md; Seifitokaldani, Ali; Tan, Chih-Shan; Gabardo, Christine M.; Luo, Mingchuan; Zhou, Hua; Li, Fengwang; Lum, Yanwei; McCallum, Christopher; Xu, Yi; Liu, Mengxia; Proppe, Andrew; Johnston, Andrew; Todorovic, Petar; Zhuang, Tao-Tao; Sinton, David; Kelley, Shana O.; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalyst synthesis under CO2 electroreduction favours faceting and promotes renewable fuels electrosynthesis", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic reduction of CO2 to multicarbon products is useful for producing high-value chemicals and fuels. Here the authors present a strategy that is based on the in situ electrodeposition of copper under CO2 reduction conditions that preferentially expose and maintain Cu(100) facets, which favour the formation of C2+ products. The electrosynthesis of C2+ hydrocarbons from CO2 has attracted recent attention in light of the relatively high market price per unit energy input. Today's low selectivities and stabilities towards C2+ products at high current densities curtail system energy efficiency, which limits their prospects for economic competitiveness. Here we present a materials processing strategy based on in situ electrodeposition of copper under CO2 reduction conditions that preferentially expose and maintain Cu(100) facets, which favour the formation of C2+ products. We observe capping of facets during catalyst synthesis and achieve control over faceting to obtain a 70% increase in the ratio of Cu(100) facets to total facet area. We report a 90% Faradaic efficiency for C2+ products at a partial current density of 520 mA cm(-2) and a full-cell C2+ power conversion efficiency of 37%. We achieve nearly constant C2H4 selectivity over 65 h operation at 350 mA cm(-2) in a membrane electrode assembly electrolyser.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 98, "End Page": 106, "Article Number": null, "DOI": "10.1038/s41929-019-0397-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0397-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514627300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, JK; Qian, XF; Lin, RB; Krishna, R; Wu, H; Zhou, W; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Junkuo; Qian, Xuefeng; Lin, Rui-Biao; Krishna, Rajamani; Wu, Hui; Zhou, Wei; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed Metal-Organic Framework with Multiple Binding Sites for Efficient C2H2/CO2 Separation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The separation of C2H2/CO2 is particularly challenging owing to their similarities in physical properties and molecular sizes. Reported here is a mixed metal-organic framework (M ' MOF), [Fe(pyz)Ni(CN)(4)] (FeNi-M ' MOF, pyz=pyrazine), with multiple functional sites and compact one-dimensional channels of about 4.0 angstrom for C2H2/CO2 separation. This MOF shows not only a remarkable volumetric C2H2 uptake of 133 cm(3) cm(-3), but also an excellent C2H2/CO2 selectivity of 24 under ambient conditions, resulting in the second highest C2H2-capture amount of 4.54 mol L-1, thus outperforming most previous benchmark materials. The separation performance of this material is driven by pi-pi stacking and multiple intermolecular interactions between C2H2 molecules and the binding sites of FeNi-M ' MOF. This material can be facilely synthesized at room temperature and is water stable, highlighting FeNi-M ' MOF as a promising material for C2H2/CO2 separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2020, "Volume": 59, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4396, "End Page": 4400, "Article Number": null, "DOI": "10.1002/anie.202000323", "DOI Link": "http://dx.doi.org/10.1002/anie.202000323", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510030900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; Park, SY; Yao, CL; Lu, HP; Dunfield, SP; Xiao, CX; Ulicná, S; Zhao, XM; Du Hill, L; Chen, XH; Wang, XM; Mundt, LE; Stone, KH; Schelhas, LT; Teeter, G; Parkin, S; Ratcliff, EL; Loo, YL; Berry, JJ; Beard, MC; Yan, YF; Larson, BW; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fei; Park, So Yeon; Yao, Canglang; Lu, Haipeng; Dunfield, Sean P.; Xiao, Chuanxiao; Ulicna, Sona; Zhao, Xiaoming; Du Hill, Linze; Chen, Xihan; Wang, Xiaoming; Mundt, Laura E.; Stone, Kevin H.; Schelhas, Laura T.; Teeter, Glenn; Parkin, Sean; Ratcliff, Erin L.; Loo, Yueh-Lin; Berry, Joseph J.; Beard, Matthew C.; Yan, Yanfa; Larson, Bryon W.; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metastable Dion-Jacobson 2D structure enables efficient and stable perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of three-dimensional (3D) organic-inorganic halide perovskite solar cells (PSCs) can be enhanced through surface treatment with 2D layered perovskites that have efficient charge transport. We maximized hole transport across the layers of a metastable Dion-Jacobson (DJ) 2D perovskite that tuned the orientational arrangements of asymmetric bulky organic molecules. The reduced energy barrier for hole transport increased out-of-plane transport rates by a factor of 4 to 5, and the power conversion efficiency (PCE) for the 2D PSC was 4.9%. With the metastable DJ 2D surface layer, the PCE of three common 3D PSCs was enhanced by approximately 12 to 16% and could reach approximately 24.7%. For a triple-cation-mixed-halide PSC, 90% of the initial PCE was retained after 1000 hours of 1-sun operation at similar to 40 degrees C in nitrogen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2022, "Volume": 375, "Issue": 6576, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": "eabj2637", "DOI": "10.1126/science.abj2637", "DOI Link": "http://dx.doi.org/10.1126/science.abj2637", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740261400042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chiu, MH; Zhang, CD; Shiu, HW; Chuu, CP; Chen, CH; Chang, CYS; Chen, CH; Chou, MY; Shih, CK; Li, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chiu, Ming-Hui; Zhang, Chendong; Shiu, Hung-Wei; Chuu, Chih-Piao; Chen, Chang-Hsiao; Chang, Chih-Yuan S.; Chen, Chia-Hao; Chou, Mei-Yin; Shih, Chih-Kang; Li, Lain-Jong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of band alignment in the single-layer MoS2/WSe2 heterojunction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of two-dimensional electronic materials has stimulated proposals of novel electronic and photonic devices based on the heterostructures of transition metal dichalcogenides. Here we report the determination of band offsets in the heterostructures of transition metal dichalcogenides by using microbeam X-ray photoelectron spectroscopy and scanning tunnelling microscopy/spectroscopy. We determine a type-II alignment between MoS2 and WSe2 with a valence band offset value of 0.83 eV and a conduction band offset of 0.76 eV. First-principles calculations show that in this heterostructure with dissimilar chalcogen atoms, the electronic structures of WSe2 and MoS2 are well retained in their respective layers due to a weak interlayer coupling. Moreover, a valence band offset of 0.94 eV is obtained from density functional theory, consistent with the experimental determination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 564, "Times Cited, All Databases": 614, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7666, "DOI": "10.1038/ncomms8666", "DOI Link": "http://dx.doi.org/10.1038/ncomms8666", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chernikov, A; Berkelbach, TC; Hill, HM; Rigosi, A; Li, YL; Aslan, OB; Reichman, DR; Hybertsen, MS; Heinz, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chernikov, Alexey; Berkelbach, Timothy C.; Hill, Heather M.; Rigosi, Albert; Li, Yilei; Aslan, Ozgur Burak; Reichman, David R.; Hybertsen, Mark S.; Heinz, Tony F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton Binding Energy and Nonhydrogenic Rydberg Series in Monolayer WS2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have experimentally determined the energies of the ground and first four excited excitonic states of the fundamental optical transition in monolayer WS2, a model system for the growing class of atomically thin two-dimensional semiconductor crystals. From the spectra, we establish a large exciton binding energy of 0.32 eV and a pronounced deviation from the usual hydrogenic Rydberg series of energy levels of the excitonic states. We explain both of these results using a microscopic theory in which the nonlocal nature of the effective dielectric screening modifies the functional form of the Coulomb interaction. These strong but unconventional electron-hole interactions are expected to be ubiquitous in atomically thin materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1978, "Times Cited, All Databases": 2243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2014, "Volume": 113, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76802, "DOI": "10.1103/PhysRevLett.113.076802", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.076802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341115700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, YB; Chen, J; Li, N; Tian, JQ; Li, KX; Jiang, JZ; Liu, JY; Tian, QH; Chen, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Yibo; Chen, Jie; Li, null; Tian, Jingqi; Li, Kaixin; Jiang, Jizhou; Liu, Jiyang; Tian, Qinghua; Chen, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Systematic Bandgap Engineering of Graphene Quantum Dots and Applications for Photocatalytic Water Splitting and CO2 Reduction", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene quantum dots (GQDs), which is the latest addition to the nullocarbon material family, promise a wide spectrum of applications. Herein, we demonstrate two different functionalization strategies to systematically tailor the bandgap structures of GQDs whereby making them snugly suitable for particular applications. Furthermore, the functionalized GQDs with a narrow bandgap and intramolecular Z-scheme structure are employed as the efficient photocatalysts for water splitting and carbon dioxide reduction under visible light. The underlying mechanisms of our observations are studied and discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 12, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3523, "End Page": 3532, "Article Number": null, "DOI": "10.1021/acsnullo.8b00498", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b00498", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431088200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QS; Sarkar, A; Wang, D; Velasco, L; Azmi, R; Bhattacharya, SS; Bergfeldt, T; Düvel, A; Heitjans, P; Brezesinski, T; Hahn, H; Breitung, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qingsong; Sarkar, Abhishek; Wang, Di; Velasco, Leonardo; Azmi, Raheleh; Bhattacharya, Subramshu S.; Bergfeldt, Thomas; Duevel, Andre; Heitjans, Paul; Brezesinski, Torsten; Hahn, Horst; Breitung, Ben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-anionic and -cationic compounds: new high entropy materials for advanced Li-ion batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, a new class of high entropy materials for energy storage applications is introduced. Multi-anionic and -cationic compounds are prepared by facile mechanochemistry using a recently designed multi-cationic transition-metal-based high entropy oxide as the precursor and LiF or NaCl as the reactant, leading to formation of lithiated or sodiated materials. Notably, the Li-containing entropy-stabilized oxyfluoride described herein (Li-x(Co0.2Cu0.2Mg0.2Ni0.2Zn0.2)(O)Fx) exhibits a working potential of 3.4 V vs. Li+/Li, enabling its use as a cathode active material. Unlike conventional (non-entropy-stabilized) oxyfluorides, this new material shows enhanced Li storage properties due to entropy stabilization, which, in general, facilitates tailoring the cycling performance by varying the constituent elements in yet unprecedented ways. In addition, we demonstrate that the concept of entropy stabilization is also applicable to Na-containing oxychlorides with a rock-salt structure, thus paving the way toward development of (next-generation) post-Li battery technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2019, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1039/c9ee00368a", "DOI Link": "http://dx.doi.org/10.1039/c9ee00368a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479082800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Zhang, YX; Wu, YZ; Gao, JF; Zhang, B; Cao, SY; Zhang, YT; Li, ZW; Sun, LC; Hou, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Zhang, Yanxue; Wu, Yunzhen; Gao, Junfeng; Zhang, Bo; Cao, Shuyan; Zhang, Yanting; Li, Zhuwei; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of the catalysts is impressive for sustainable energy conversion. However, there is a grand challenge to engineer active sites at the interface. Herein, hierarchical transition bimetal oxides/sulfides heterostructure arrays interacting two-dimensional MoOx/MoS2 nullosheets attached to one-dimensional NiOx/Ni3S2 nullorods were fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy. The NiMoOx/NiMoS heterostructure array exhibits the overpotentials of 38mV for hydrogen evolution and 186mV for oxygen evolution at 10mAcm(-2), even surviving at a large current density of 500mAcm(-2) with long-term stability. Due to optimized adsorption energies and accelerated water splitting kinetics by theory calculations, the assembled two-electrode cell delivers the industrially relevant current densities of 500 and 1000mAcm(-2) at record low cell voltages of 1.60 and 1.66V with excellent durability. This research provides a promising avenue to enhance the electrocatalytic performance of the catalysts by engineering interfacial active sites toward large-scale water splitting. While water splitting is an appealing carbon-neutral strategy for renewable energy generation, there is a need to develop new active, cost-effective catalysts. Here, authors prepare a nickel-molybdenum oxide/sulfide heterojunctions as bifunctional H-2 and O-2 evolution electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 525, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5462, "DOI": "10.1038/s41467-020-19214-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19214-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591379900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, X; Wu, TZ; Sun, YM; Li, Y; Xian, GY; Liu, XH; Shen, CM; Gracia, J; Gao, HJ; Yang, HT; Xu, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xiao; Wu, Tianze; Sun, Yuanmiao; Li, Yan; Xian, Guoyu; Liu, Xianhu; Shen, Chengmin; Gracia, Jose; Gao, Hong-Jun; Yang, Haitao; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-polarized oxygen evolution reaction under magnetic field", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, authors demonstrate the ferromagnetic catalyst to facilitate spin polarization in water oxidation reaction. They find the ferromagnetic-exchange-like behaviour between the ferromagnetic catalyst and the adsorbed oxygen species. The oxygen evolution reaction (OER) is the bottleneck that limits the energy efficiency of water-splitting. The process involves four electrons' transfer and the generation of triplet state O-2 from singlet state species (OH- or H2O). Recently, explicit spin selection was described as a possible way to promote OER in alkaline conditions, but the specific spin-polarized kinetics remains unclear. Here, we report that by using ferromagnetic ordered catalysts as the spin polarizer for spin selection under a constant magnetic field, the OER can be enhanced. However, it does not applicable to non-ferromagnetic catalysts. We found that the spin polarization occurs at the first electron transfer step in OER, where coherent spin exchange happens between the ferromagnetic catalyst and the adsorbed oxygen species with fast kinetics, under the principle of spin angular momentum conservation. In the next three electron transfer steps, as the adsorbed O species adopt fixed spin direction, the OER electrons need to follow the Hund rule and Pauling exclusion principle, thus to carry out spin polarization spontaneously and finally lead to the generation of triplet state O-2. Here, we showcase spin-polarized kinetics of oxygen evolution reaction, which gives references in the understanding and design of spin-dependent catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2608, "DOI": "10.1038/s41467-021-22865-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22865-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687305500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XY; Xu, YK; Zhang, C; Leonard, DP; Markir, A; Lu, J; Ji, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xianyong; Xu, Yunkai; Zhang, Chong; Leonard, Daniel P.; Markir, Aaron; Lu, Jun; Ji, Xiulei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dual-ion batteries are known for anion storage in the cathode coupled to cation incorporation in the anode. We flip the sequence of the anion/cation-storage chemistries of the anode and the cathode in dual-ion batteries (DIBs) by allowing the anode to take in anions and a cation-deficient cathode to host cations, thus operating as a reverse dual-ion battery (RDIB). The anion-insertion anode is a nullo-composite having ferrocene encapsulated inside a micro-porous carbon, and the cathode is a Zn-insertion Prussian blue, Zn-3[Fe(CN)(6)](2). This unique battery configuration benefits from the usage of a 30 m ZnCl2 water-in-salt electrolyte. This electrolyte minimizes the dissolution of ferrocene; it raises the cation-insertion potential in the cathode, and it depresses the anion-insertion potential in the anode, thus widening the full cell's voltage by 0.35 V compared with a dilute ZnCl2 electrolyte. RDIBs provide a configuration-based solution to exploit the practicality of cation-deficient cathode materials in aqueous electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 141, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6338, "End Page": 6344, "Article Number": null, "DOI": "10.1021/jacs.9b00617", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465188800030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Cherevan, AS; Hannecart, C; Naghdi, S; nulldan, SP; Gupta, T; Eder, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jia; Cherevan, Alexey S.; Hannecart, Celine; Naghdi, Shaghayegh; nulldan, Sreejith P.; Gupta, Tushar; Eder, Dominik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti-based MOFs: New insights on the impact of ligand composition and hole scavengers on stability, charge separation and photocatalytic hydrogen evolution", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We synthesized a series of isostructural MIL-125-Ti with various terephthalic: amino-terephthalic acid ratios and evaluated their photostability and performance for photocatalytic hydrogen evolution in aqueous solutions with different hole scavengers. We demonstrate that the commonly used triethanolamine corroded the MOFs under photocatalytic conditions, in contrast to methanol. The combination of MIL-125-Ti and methanol outperformed the photocatalytic activity of NH2-MIL-125-Ti by 45 times under broad UV irradiation. Photoluminescence spectroscopy under simulated photocatalytic conditions and in solid-state as well as time-resolved emission studies reveal that the holes residing in the metal-oxo cluster can be effectively scavenged by methanol, leading to high HER activity, while the holes residing in the NH2-groups in the ligand favour charge recombination and are thus detrimental to the photocatalytic performance. The mixed-ligand MOFs follow a dual-excitation pathway, introducing new states and transitions. These results are expected to advance our understanding of MOF-based photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 283, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119626, "DOI": "10.1016/j.apcatb.2020.119626", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119626", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600017400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, YW; Wang, BB; He, F; Bradley, MJ; Tratnyek, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Yawei; Wang, Binbin; He, Feng; Bradley, Miranda J.; Tratnyek, Paul G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanochemically Sulfidated Microscale Zero Valent Iron: Pathways, Kinetics, Mechanism, and Efficiency of Trichloroethylene Dechlorination", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In water treatment processes that involve contaminullt reduction by zerovalent iron (ZVI), reduction of water to dihydrogen is a competing reaction that must be minimized to maximize the efficiency of electron utilization from the ZVI. Sulfidation has recently been shown to decrease H-2 formation significantly, such that the overall electron efficiency of (or selectivity for) contaminullt reduction can be greatly increased. To date, this work has focused on nulloscale ZVI (nZVI) and solution-phase sulfidation agents (e.g., bisulfide, dithionite or thiosulfate), both of which pose challenges for up-scaling the production of sulfidated ZVI for field applications. To overcome these challenges, we developed a process for sulfidation of microscale ZVI by ball milling ZVI with elemental sulfur. The resulting material (S-mZVI(bm)) exhibits reduced aggregation, relatively homogeneous distribution of Fe and S throughout the particle (not core shell structure), enhanced reactivity with trichloroethylene (TCE), less H2 formation, and therefore greatly improved electron efficiency of TCE dechlorination (epsilon(e)). Under ZVI-limited conditions (initial Fe-0/TCE = 1.6 mol/mol), S-mZVI(bm) gave surface-area normalized reduction rate constants (k'(sA)) and epsilon(e) that were similar to 2- and 10-fold greater than the unsulfidated ball-milled control (mZVI(bm)). Under TCE-limited conditions (initial Fe-0/TCE = 2000 mol/mol), sulfidation increased ksA and epsilon(e) approximate to 5- and 50-fold, respectively. The major products from TCE degradation by S-mZVI(bm) were acetylene, ethene, and ethane, which is consistent with dechlorination by beta-elimination, as is typical of ZVI, iron oxides, and/or sulfides. However, electrochemical characterization shows that the sulfidated material has redox properties intermediate between ZVI and Fe3O4, mostly likely significant coverage of the surface with FeS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2017, "Volume": 51, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12653, "End Page": 12662, "Article Number": null, "DOI": "10.1021/acs.est.7b03604", "DOI Link": "http://dx.doi.org/10.1021/acs.est.7b03604", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414887200068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YL; Zhu, YL; Ma, XL; Borisevich, AY; Morozovska, AN; Eliseev, EA; Wang, WY; Wang, YJ; Xu, YB; Zhang, ZD; Pennycook, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Y. L.; Zhu, Y. L.; Ma, X. L.; Borisevich, A. Y.; Morozovska, A. N.; Eliseev, E. A.; Wang, W. Y.; Wang, Y. J.; Xu, Y. B.; Zhang, Z. D.; Pennycook, S. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of a periodic array of flux-closure quadrants in strained ferroelectric PbTiO3 films", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale ferroelectrics are expected to exhibit various exotic domain configurations, such as the full flux-closure pattern that is well known in ferromagnetic materials. Here we observe not only the atomic morphology of the flux-closure quadrant but also a periodic array of flux closures in ferroelectric PbTiO3 films, mediated by tensile strain on a GdScO3 substrate. Using aberration-corrected scanning transmission electron microscopy, we directly visualize an alternating array of clockwise and counterclockwise flux closures, whose periodicity depends on the PbTiO3 film thickness. In the vicinity of the core, the strain is sufficient to rupture the lattice, with strain gradients up to 10(9) per meter. Engineering strain at the nulloscale may facilitate the development of nulloscale ferroelectric devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2015, "Volume": 348, "Issue": 6234, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 547, "End Page": 551, "Article Number": null, "DOI": "10.1126/science.1259869", "DOI Link": "http://dx.doi.org/10.1126/science.1259869", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353778100035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chuang, HJ; Chamlagain, B; Koehler, M; Perera, MM; Yan, JQ; Mandrus, D; Tománek, D; Zhou, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chuang, Hsun-Jen; Chamlagain, Bhim; Koehler, Michael; Perera, Meeghage Madusanka; Yan, Jiaqiang; Mandrus, David; Tomanek, David; Zhou, Zhixian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Resistance 2D/2D Ohmic Contacts: A Universal Approach to High-Performance WSe2, MoS2, and MoSe2 Transistors", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a new strategy for fabricating 2D/2D low-resistance ohmic contacts for a variety of transition metal dichalcogenides (TMDs) using van der Waals assembly of substitutionally doped TMDs as drain/source contacts and TMDs with no intentional doping as channel materials. We demonstrate that few-layer WSe2 field-effect transistors (FETs) with 2D/2D contacts exhibit low contact resistances of similar to 0.3 k Omega mu m high on/off ratios up to >10(9), and high drive currents exceeding 320 mu A mu m(-1). These favorable characteristics are combined with a two-terminal field-effect hole mobility mu(FE) approximate to 2 X 10(2) cm(2) V(-1)s(-1) at room temperature, which increases to >2 X 10(3) cm(2) V-1 s(-1) at cryogenic temperatures. We observe a similar performance also in MoS2 and MoSe2 FETs with 2D/2D drain and source contacts. The 2D/2D low-resistance ohmic contacts presented here represent a new device paradigm that overcomes a significant bottleneck in the performance of TMDs and a wide variety of other 2D materials as the channel materials in postsilicon electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1896, "End Page": 1902, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b05066", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b05066", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371946300056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LZ; Tian, Z; Jiang, GC; Luo, X; Chen, CH; Hu, XY; Zhang, HJ; Zhong, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lizhong; Tian, Ze; Jiang, Guochen; Luo, Xiao; Chen, Changhao; Hu, Xinyu; Zhang, Hongjun; Zhong, Minlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous dewetting transitions of droplets during icing & melting cycle", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anti-icing superhydrophobic surfaces have been a key research topic due to their potential application value in aviation, telecommunication, energy, etc. However, superhydrophobicity is easily lost during icing & melting cycles, where the water-repellent Cassie-Baxter state turns to the sticky Wenzel state. The reversible transition during icing & melting cycle without external assistance is challenging but vital for reliable anti-icing superhydrophobic performance, such a topic has rarely been reported. Here we demonstrate a spontaneous Wenzel to Cassie-Baxter dewetting transition during icing & melting cycle on well-designed superhydrophobic surfaces. Bubbles in ice droplets rapidly impact the micro-nullo valleys under Marangoni force, prompting the continuous recovery of air pockets during melting processes. We establish models to confirm the bubbles movement broadens the dewetting conditions greatly and present three criteria for the dewetting transitions. This research deepens the understanding of wettability theory and extends the design of anti-icing superhydrophobic surfaces. Despite promising for anti-icing applications, structured superhydrophobic surfaces usually lose their hydrophobicity after a few icing/melting cycles. Here, authors investigate specific structured surfaces and air bubbles on frozen ice droplets to propose three criteria to enable dewetting transitions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 378, "DOI": "10.1038/s41467-022-28036-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28036-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744588000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, ZW; Huang, AB; Ming, C; Bell, J; Yu, P; Sun, YY; Jin, LM; Ma, LY; Luo, HJ; Jin, P; Cao, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Zewei; Huang, Aibin; Ming, Chen; Bell, John; Yu, Pu; Sun, Yi-Yang; Jin, Liangmao; Ma, Liyun; Luo, Hongjie; Jin, Ping; Cao, Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-solid-state proton-based tandem structures for fast-switching electrochromic devices", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state tandem structures that use protons as the diffusing species can be used to create electrochromic devices that exhibit high contrast ratios, fast responses, good colouration efficiency and excellent cycling stability. All-solid-state electrochromic devices can be used to create smart windows that regulate the transmittance of solar radiation by applying a voltage. However, the devices suffer from a limited ion diffusion speed, which leads to slow colouration and bleaching processes. Here we report fast-switching electrochromic devices that are based on an all-solid-state tandem structure and use protons as the diffusing species. We use tungsten trioxide (WO3) as the electrochromic material, and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) as the solid-state proton source. This structure exhibits a low contrast ratio (that is, the difference between on and off transmittance); however, we add a solid polymeric electrolyte layer on top of PEDOT:PSS, which provides sodium ions to PEDOT:PSS and pumps protons to the WO3 layer through ion exchange. The resulting electrochromic devices exhibit high contrast ratios (more than 90% at 650 nm), fast responses (colouration to 90% in 0.7 s and bleaching to 65% in 0.9 s and 90% in 7.1 s), good colouration efficiency (109 cm(2) C-1 at 670 nm) and excellent cycling stability (less than 10% degradation of contrast ratio after 3,000 cycles). We also fabricate large-area (30 x 40 cm(2)) and flexible devices, illustrating the scaling potential of the approach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": 52, "Article Number": null, "DOI": "10.1038/s41928-021-00697-4", "DOI Link": "http://dx.doi.org/10.1038/s41928-021-00697-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746336800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, R; Ma, XY; Li, JM; Cao, J; Gao, HZ; Li, TS; Zhang, XY; Wang, LC; Zhang, QH; Wang, G; Hou, CY; Li, YG; Palacios, T; Lin, YX; Wang, HZ; Ling, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ran; Ma, Xiaoyuan; Li, Jianmin; Cao, Jun; Gao, Hongze; Li, Tianshu; Zhang, Xiaoyu; Wang, Lichao; Zhang, Qinghong; Wang, Gang; Hou, Chengyi; Li, Yaogang; Palacios, Tomas; Lin, Yuxuan; Wang, Hongzhi; Ling, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and high-performance electrochromic devices enabled by self-assembled 2D TiO2/MXene heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxides (TMOs) are promising electrochromic (EC) materials for applications such as smart windows and displays, yet the challenge still exists to achieve good flexibility, high coloration efficiency and fast response simultaneously. MXenes (e.g. Ti3C2Tx) and their derived TMOs (e.g. 2D TiO2) are good candidates for high-performance and flexible EC devices because of their 2D nature and the possibility of assembling them into loosely networked structures. Here we demonstrate flexible, fast, and high-coloration-efficiency EC devices based on self-assembled 2D TiO2/Ti3C2Tx heterostructures, with the Ti3C2Tx layer as the transparent electrode, and the 2D TiO2 layer as the EC layer. Benefiting from the well-balanced porosity and connectivity of these assembled nullometer-thick heterostructures, they present fast and efficient ion and electron transport, as well as superior mechanical and electrochemical stability. We further demonstrate large-area flexible devices which could potentially be integrated onto curved and flexible surfaces for future ubiquitous electronics. Though two-dimensional (2D) nullocomposite materials have been attractive for flexible electrochromic (EC) devices, achieving both high performance and durability remains a challenge. Here, the authors report high-performance, environmentally stable 2D MXene/transition metal oxide-based EC devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1587, "DOI": "10.1038/s41467-021-21852-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21852-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629597700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lian, LY; Zheng, MY; Zhang, WZ; Yin, LX; Du, XY; Zhang, P; Zhang, XW; Gao, JB; Zhang, DL; Gao, L; Niu, GD; Song, HS; Chen, R; Lan, XZ; Tang, J; Zhang, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lian, Linyuan; Zheng, Moyan; Zhang, Weizhuo; Yin, Lixiao; Du, Xinyuan; Zhang, Peng; Zhang, Xiuwen; Gao, Jianbo; Zhang, Daoli; Gao, Liang; Niu, Guangda; Song, Haisheng; Chen, Rong; Lan, Xinzheng; Tang, Jiang; Zhang, Jianbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and Reabsorption-Free Radioluminescence in Cs3Cu2I5 nullocrystals with Self-Trapped Excitons", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radioluminescent materials (scintillators) are widely applied in medical imaging, nondestructive testing, security inspection, nuclear and radiation industries, and scientific research. Recently, all-inorganic lead halide perovskite nullocrystal (NC) scintillators have attracted great attention due to their facile solution processability and ultrasensitive X-ray detection, which allows for large area and flexible X-ray imaging. However, the light yield of these perovskite NCs is relatively low because of the strong self-absorption that reduces the light out-coupling efficiency. Here, NCs with self-trapped excitons emission are demonstrated to be sensitive, reabsorption-free scintillators. Highly luminescent and stable Cs3Cu2I5 NCs with a photoluminescence quantum yields of 73.7%, which is a new record for blue emission lead-free perovskite or perovskite-like NCs, is produced with the assistance of InI3. The PL peak of the Cs3Cu2I5 NCs locates at 445 nm that matches with the response peak of a silicon photomultiplier. Thus, Cs3Cu2I5 NCs are demonstrated as efficient scintillators with zero self-absorption and extremely high light yield (approximate to 79 279 photons per MeV). Both Cs3Cu2I5 NC colloidal solution and film exhibit strong radioluminescence under X-ray irradiation. The potential application of Cs3Cu2I5 NCs as reabsorption-free, low cost, large area, and flexible scintillators is demonstrated by a prototype X-ray imaging with a high spatial resolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000195, "DOI": "10.1002/advs.202000195", "DOI Link": "http://dx.doi.org/10.1002/advs.202000195", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541137700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, W; Ji, XY; Xu, XD; Islam, MA; Li, ZJ; Chen, S; Saw, PE; Zhang, H; Bharwani, Z; Guo, ZL; Shi, JJ; Farokhzad, OC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Wei; Ji, Xiaoyuan; Xu, Xiaoding; Islam, Mohammad Ariful; Li, Zhongjun; Chen, Si; Saw, Phei Er; Zhang, Han; Bharwani, Zameer; Guo, Zilei; Shi, Jinjun; Farokhzad, Omid C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antimonene Quantum Dots: Synthesis and Application as Near-Infrared Photothermal Agents for Effective Cancer Therapy", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) has shown significant potential for cancer therapy. However, developing nullomaterials (NMs)-based photothermal agents (PTAs) with satisfactory photothermal conversion efficacy (PTCE) and biocompatibility remains a key challenge. Herein, a new generation of PTAs based on two-dimensional (2D) antimonene quantum dots (AMQDs) was developed by a novel liquid exfoliation method. Surface modification of AMQDs with polyethylene glycol (PEG) significantly enhanced both biocompatibility and stability in physiological medium. The PEG-coated AMQDs showed a PTCE of 45.5%, which is higher than many other NMs-based PTAs such as graphene, Au, MoS2, and black phosphorus (BP). The AMQDs-based PTAs also exhibited a unique feature of NIR-induced rapid degradability. Through both invitro and invivo studies, the PEG-coated AMQDs demonstrated notable NIR-induced tumor ablation ability. This work is expected to expand the utility of 2D antimonene (AM) to biomedical applications through the development of an entirely novel PTA platform.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2017, "Volume": 56, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11896, "End Page": 11900, "Article Number": null, "DOI": "10.1002/anie.201703657", "DOI Link": "http://dx.doi.org/10.1002/anie.201703657", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410810600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JS; Lian, J; Hou, L; Zhang, JC; Gou, HY; Xia, MR; Zhao, YF; Strobel, TA; Tao, L; Gao, FM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Junshuang; Lian, Jie; Hou, Li; Zhang, Junchuan; Gou, Huiyang; Xia, Meirong; Zhao, Yufeng; Strobel, Timothy A.; Tao, Lu; Gao, Faming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh volumetric capacitance and cyclic stability of fluorine and nitrogen co-doped carbon microspheres", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly porous nullostructures with large surface areas are typically employed for electrical double-layer capacitors to improve gravimetric energy storage capacity; however, high surface area carbon-based electrodes result in poor volumetric capacitance because of the low packing density of porous materials. Here, we demonstrate ultrahigh volumetric capacitance of 521 F cm(-3) in aqueous electrolytes for non-porous carbon microsphere electrodes co-doped with fluorine and nitrogen synthesized by low-temperature solvothermal route, rivaling expensive RuO2 or MnO2 pseudo-capacitors. The new electrodes also exhibit excellent cyclic stability without capacitance loss after 10,000 cycles in both acidic and basic electrolytes at a high charge current of 5 Ag-1. This work provides a new approach for designing high-performance electrodes with exceptional volumetric capacitance with high mass loadings and charge rates for long-lived electrochemical energy storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 573, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8503, "DOI": "10.1038/ncomms9503", "DOI Link": "http://dx.doi.org/10.1038/ncomms9503", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363148900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sprick, RS; Jiang, JX; Bonillo, B; Ren, SJ; Ratvijitvech, T; Guiglion, P; Zwijnenburg, MA; Adams, DJ; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sprick, Reiner Sebastian; Jiang, Jia-Xing; Bonillo, Baltasar; Ren, Shijie; Ratvijitvech, Thanchanok; Guiglion, Pierre; Zwijnenburg, Martijn A.; Adams, Dave J.; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Organic Photocatalysts for Visible-Light-Driven Hydrogen Evolution", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic hydrogen production from water offers an abundant, clean fuel source, but it is challenging to produce photocatalysts that use the solar spectrum effectively. Many hydrogen-evolving photocatalysts are active in the ultraviolet range, but ultraviolet light accounts for only 3% of the energy available in the solar spectrum at ground level. Solid-state crystalline photocatalysts have light absorption profiles that are a discrete function of their crystalline phase and that are not always tunable. Here, we prepare a series of amorphous, microporous organic polymers with exquisite synthetic control over the optical gap in the range 1.94-2.95 eV. Specific monomer compositions give polymers that are robust and effective photocatalysts for the evolution of hydrogen from water in the presence of a sacrificial electron donor, without the apparent need for an added metal cocatalyst. Remarkably, unlike other organic systems, the best performing polymer is only photoactive under visible rather than ultraviolet irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 754, "Times Cited, All Databases": 793, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2015, "Volume": 137, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3265, "End Page": 3270, "Article Number": null, "DOI": "10.1021/ja511552k", "DOI Link": "http://dx.doi.org/10.1021/ja511552k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351187200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, B; Zhao, CZ; Wang, ZQ; Yang, KA; Cheng, XB; Liu, WF; Yu, WZ; Lin, SY; Zhao, YC; Cheung, KM; Lin, HS; Hojaiji, H; Weiss, PS; Stojanovic, MN; Tomiyama, AJ; Andrews, AM; Emaminejad, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Bo; Zhao, Chuanzhen; Wang, Zhaoqing; Yang, Kyung-Ae; Cheng, Xuanbing; Liu, Wenfei; Yu, Wenzhuo; Lin, Shuyu; Zhao, Yichao; Cheung, Kevin M.; Lin, Haisong; Hojaiji, Hannulleh; Weiss, Paul S.; Stojanovic, Milan N.; Tomiyama, A. Janet; Andrews, Anne M.; Emaminejad, Sam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable aptamer-field-effect transistor sensing system for noninvasive cortisol monitoring", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable technologies for personalized monitoring require sensors that track biomarkers often present at low levels. Cortisol-a key stress biomarker-is present in sweat at low nullomolar concentrations. Previous wearable sensing systems are limited to analytes in the micromolar-millimolar ranges. To overcome this and other limitations, we developed a flexible field-effect transistor (FET) biosensor array that exploits a previously unreported cortisol aptamer coupled to nullometer-thin-film In2O3 FETs. Cortisol levels were determined via molecular recognition by aptamers where binding was transduced to electrical signals on FETs. The physiological relevance of cortisol as a stress biomarker was demonstrated by tracking salivary cortisol levels in participants in a Trier Social Stress Test and establishing correlations between cortisol in diurnal saliva and sweat samples. These correlations motivated the development and on-body validation of an aptamer-FET array-based smartwatch equipped with a custom, multichannel, self-referencing, and autonomous source measurement unit enabling seamless, real-time cortisol sweat sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabk0967", "DOI": "10.1126/sciadv.abk0967", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abk0967", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742086300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JQ; Lin, XY; Tan, H; Zhang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jiaqiang; Lin, Xiuyi; Tan, Hong; Zhang, Biao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuth Microparticles as Advanced Anodes for Potassium-Ion Battery", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (KIBs) are important alternatives to lithium- and sodium-ion batteries. Herein, microsized a Bi electrode delivers exceptional potassium storage capacity, stability, and rate capability by the formation of an elastic and adhesive oligomer-containing solid electrolyte interface with the assistance of diglyme electrolytes. The kinetics-controlled K-Bi phase transitions are unraveled combining electrochemical profiles, in situ X-ray diffraction and density functional theory calculations. Reversible, stepwise Bi-KBi2-K3Bi2-K3Bi transitions govern the electrochemical processes after the initial continuous surface potassiation. The Bi electrode outperforms the other anode counterparts considering both capacity and potential. This work provides critical insights into the rational design of high-performance anode materials for KIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2018, "Volume": 8, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703496, "DOI": "10.1002/aenm.201703496", "DOI Link": "http://dx.doi.org/10.1002/aenm.201703496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437667800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Visser, J; Melchels, FPW; Jeon, JE; van Bussel, EM; Kimpton, LS; Byrne, HM; Dhert, WJA; Dalton, PD; Hutmacher, DW; Malda, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Visser, Jetze; Melchels, Ferry P. W.; Jeon, June E.; van Bussel, Erik M.; Kimpton, Laura S.; Byrne, Helen M.; Dhert, Wouter J. A.; Dalton, Paul D.; Hutmacher, Dietmar W.; Malda, Jos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reinforcement of hydrogels using three-dimensionally printed microfibres", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite intensive research, hydrogels currently available for tissue repair in the musculoskeletal system are unable to meet the mechanical, as well as the biological, requirements for successful outcomes. Here we reinforce soft hydrogels with highly organized, high-porosity microfibre networks that are 3D-printed with a technique termed as melt electrospinning writing. We show that the stiffness of the gel/scaffold composites increases synergistically (up to 54-fold), compared with hydrogels or microfibre scaffolds alone. Modelling affirms that reinforcement with defined microscale structures is applicable to numerous hydrogels. The stiffness and elasticity of the composites approach that of articular cartilage tissue. Human chondrocytes embedded in the composites are viable, retain their round morphology and are responsive to an in vitro physiological loading regime in terms of gene expression and matrix production. The current approach of reinforcing hydrogels with 3D-printed microfibres offers a fundament for producing tissue constructs with biological and mechanical compatibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 618, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6933, "DOI": "10.1038/ncomms7933", "DOI Link": "http://dx.doi.org/10.1038/ncomms7933", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, J; Duan, XG; Wang, C; Sun, HQ; Tan, XY; Tade, MO; Wang, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Jian; Duan, Xiaoguang; Wang, Chen; Sun, Hongqi; Tan, Xiaoyao; Tade, Moses O.; Wang, Shaobin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-doped bamboo-like carbon nullotubes with Ni encapsulation for persulfate activation to remove emerging contaminullts with excellent catalytic stability", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped bamboo-like carbon nullotubes encapsulated with nickel nulloparticles (Ni@NCNTs) were feasibly fabricated by a one-pot pyrolysis route. The characterization techniques revealed the surface morphology, structure and chemical composition of the as-prepared catalysts synthesized in different conditions. Ni@NCNTs were employed as both adsorbents and catalysts for activating persulfate to remove an emerging pollutant, antibiotic sulfachloropyridazine. The nitrogen modification enhanced both adsorption capacity and catalytic ability of Ni@NCNTs and proved to be a promising alternative to metal oxides and other carbon catalysts. Moreover, Ni@NCNTs showed an excellent stability because of nitrogen heteroatom doping and Ni nulloparticle encapsulation. Electron paramagnetic resonullce (EPR) and classical radical quenching tests discovered a simultaneous radical/non-radical mechanism in Ni@NCNTs/persulfate system. The results indicated that the novel nullo-architectured catalyst materials can show emerging functionalities for environmental remediation processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2018, "Volume": 332, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 398, "End Page": 408, "Article Number": null, "DOI": "10.1016/j.cej.2017.09.102", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.09.102", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414913700045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hannagan, RT; Giannakakis, G; Réocreux, R; Schumann, J; Finzel, J; Wang, YC; Michaelides, A; Deshlahra, P; Christopher, P; Flytzani-Stephanopoulos, M; Stamatakis, M; Sykes, ECH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hannagan, Ryan T.; Giannakakis, Georgios; Reocreux, Romain; Schumann, Julia; Finzel, Jordan; Wang, Yicheng; Michaelides, Angelos; Deshlahra, Prashant; Christopher, Phillip; Flytzani-Stephanopoulos, Maria; Stamatakis, Michail; Sykes, E. Charles H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles design of a single-atom-alloy propane dehydrogenation catalyst", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complexity of heterogeneous catalysts means that a priori design of new catalytic materials is difficult, but the well-defined nature of single-atom-alloy catalysts has made it feasible to perform unambiguous theoretical modeling and precise surface science experiments. Herein we report the theory-led discovery of a rhodium-copper (RhCu) single-atom-alloy catalyst for propane dehydrogenation to propene. Although Rh is not generally considered for alkane dehydrogenation, first-principles calculations revealed that Rh atoms disperse in Cu and exhibit low carbon-hydrogen bond activation barriers. Surface science experiments confirmed these predictions, and together these results informed the design of a highly active, selective, and coke-resistant RhCu nulloparticle catalyst that enables low-temperature nonoxidative propane dehydrogenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 372, "Issue": 6549, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1444, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg8389", "DOI Link": "http://dx.doi.org/10.1126/science.abg8389", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665860000048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, K; Yan, QM; Chen, M; Fan, W; Sun, YH; Suh, J; Fu, DY; Lee, S; Zhou, J; Tongay, S; Ji, J; Neaton, JB; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kai; Yan, Qimin; Chen, Michelle; Fan, Wen; Sun, Yinghui; Suh, Joonki; Fu, Deyi; Lee, Sangwook; Zhou, Jian; Tongay, Sefaattin; Ji, Jie; Neaton, Jeffrey B.; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic Properties of Chemical-Vapor-Deposited Monolayer MoS2, WS2, and Their Bilayer Heterostructures", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elastic properties of materials are an important factor in their integration in applications. Chemical vapor deposited (CVD) monolayer semiconductors are proposed as key components in industrial-scale flexible devices and building blocks of 2D van der Waals heterostructures. However, their mechanical and elastic properties have not been fully characterized. Here we report high 2D elastic moduli of CVD monolayer MoS2 and WS2 (similar to 170 N/m), which is very close to the value of exfoliated MoS2 monolayers and almost half the value of the strongest material, graphene. The 2D moduli of their bilayer heterostructures are lower than the sum of 2D modulus of each layer, but comparable to the corresponding bilayer homostructure, implying similar interactions between the hetero monolayers as between homo monolayers. These results not only provide deep insight to understanding interlayer interactions in 2D van der Waals structures, but also potentially allow engineering of their elastic properties as desired.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 551, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 14, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5097, "End Page": 5103, "Article Number": null, "DOI": "10.1021/nl501793a", "DOI Link": "http://dx.doi.org/10.1021/nl501793a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341544500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Di, J; Chen, C; Yang, SZ; Chen, SM; Duan, ML; Xiong, J; Zhu, C; Long, R; Hao, W; Chi, Z; Chen, HL; Weng, YX; Xia, JX; Song, L; Li, SZ; Li, HM; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Di, Jun; Chen, Chao; Yang, Shi-Ze; Chen, Shuangming; Duan, Meilin; Xiong, Jun; Zhu, Chao; Long, Ran; Hao, Wei; Chi, Zhen; Chen, Hailong; Weng, Yu-Xiang; Xia, Jiexiang; Song, Li; Li, Shuzhou; Li, Huaming; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated single atom cobalt in Bi3O4Br atomic layers to trigger efficient CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of efficient and stable photocatalysts for robust CO2 reduction without sacrifice reagent or extra photosensitizer is still challenging. Herein, a single-atom catalyst of isolated single atom cobalt incorporated into Bi3O4Br atomic layers is successfully prepared. The cobalt single atoms in the Bi3O4Br favors the charge transition, carrier separation, CO2 adsorption and activation. It can lower the CO2 activation energy barrier through stabilizing the COOH* intermediates and tune the rate-limiting step from the formation of adsorbed intermediate COOH* to be CO* desorption. Taking advantage of cobalt single atoms and two-dimensional ultrathin Bi3O4Br atomic layers, the optimized catalyst can perform light-driven CO2 reduction with a selective CO formation rate of 107.1 mu mol g(-1) h(-1), roughly 4 and 32 times higher than that of atomic layer Bi3O4Br and bulk Bi3O4Br, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2840, "DOI": "10.1038/s41467-019-10392-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10392-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473132200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YW; Meng, L; Yang, Y; Xu, GY; Hong, ZR; Chen, Q; You, JB; Li, G; Yang, Y; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yaowen; Meng, Lei; Yang, Yang (Michael); Xu, Guiying; Hong, Ziruo; Chen, Qi; You, Jingbi; Li, Gang; Yang, Yang; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency robust perovskite solar cells on ultrathin flexible substrates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wide applications of personal consumer electronics have triggered tremendous need for portable power sources featuring light-weight and mechanical flexibility. Perovskite solar cells offer a compelling combination of low-cost and high device performance. Here we demonstrate high-performance planar heterojunction perovskite solar cells constructed on highly flexible and ultrathin silver-mesh/conducting polymer substrates. The device performance is comparable to that of their counterparts on rigid glass/indium tin oxide substrates, reaching a power conversion efficiency of 14.0%, while the specific power (the ratio of power to device weight) reaches 1.96 kW kg(-1), given the fact that the device is constructed on a 57-mu m-thick polyethylene terephthalate based substrate. The flexible device also demonstrates excellent robustness against mechanical deformation, retaining >95% of its original efficiency after 5,000 times fully bending. Our results confirmed that perovskite thin films are fully compatible with our flexible substrates, and are thus promising for future applications in flexible and bendable solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 726, "Times Cited, All Databases": 787, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10214, "DOI": "10.1038/ncomms10214", "DOI Link": "http://dx.doi.org/10.1038/ncomms10214", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369019900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Cheng, DJ; Xu, HX; Zeng, XF; Wan, X; Shui, JL; Xiang, ZH; Cao, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Liu; Cheng, Daojian; Xu, Haoxiang; Zeng, Xiaofei; Wan, Xin; Shui, Jianglan; Xiang, Zhonghua; Cao, Dapeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is still a grand challenge to develop a highly efficient nonprecious-metal electrocatalyst to replace the Pt-based catalysts for oxygen reduction reaction (ORR). Here, we propose a surfactant-assisted method to synthesize single-atom iron catalysts (SA-Fe/NG). The half-wave potential of SA-Fe/NG is only 30 mV less than 20% Pt/C in acidic medium, while it is 30 mV superior to 20% Pt/C in alkaline medium. Moreover, SA-Fe/NG shows extremely high stability with only 12 mV and 15 mV negative shifts after 5,000 cycles in acidic and alkaline media, respectively. Impressively, the SA-Fe/NG-based acidic proton exchange membrane fuel cell (PEMFC) exhibits a high power density of 823 mW cm(-2). Combining experimental results and density-functional theory (DFT) calculations, we further reveal that the origin of high-ORR activity of SA-Fe/NG is from the Fe-pyrrolic-N species, because such molecular incorporation is the key, leading to the active site increase in an order of magnitude which successfully clarifies the bottleneck puzzle of why a small amount of iron in the SA-Fe catalysts can exhibit extremely superior ORR activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 539, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2018, "Volume": 115, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6626, "End Page": 6631, "Article Number": null, "DOI": "10.1073/pnas.1800771115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1800771115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436245000056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Lin, RC; Wang, X; Xue, JM; Deng, CJ; Feng, C; Zhuang, H; Ma, JG; Qin, C; Wan, L; Chang, J; Wu, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Meng; Lin, Rongcai; Wang, Xin; Xue, Jianmin; Deng, Cuijun; Feng, Chun; Zhuang, Hui; Ma, Jingge; Qin, Chen; Wan, Li; Chang, Jiang; Wu, Chengtie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of Haversian bone-mimicking scaffolds for multicellular delivery in bone regeneration", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of structure and function for tissue engineering scaffolds is of great importance in mimicking native bone tissue. However, the complexity of hierarchical structures, the requirement for mechanical properties, and the diversity of bone resident cells are the major challenges in constructing biomimetic bone tissue engineering scaffolds. Herein, a Haversian bone- mimicking scaffold with integrated hierarchical Haversian bone structure was successfully prepared via digital laser processing (DLP)-based 3D printing. The compressive strength and porosity of scaffolds could be well controlled by altering the parameters of the Haversian bone-mimicking structure. The Haversian bone-mimicking scaffolds showed great potential for multicellular delivery by inducing osteogenic, angiogenic, and neurogenic differentiation in vitro and accelerated the ingrowth of blood vessels and new bone formation in vivo. The work offers a new strategy for designing structured and functionalized biomaterials through mimicking native complex bone tissue for tissue regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz6725", "DOI": "10.1126/sciadv.aaz6725", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz6725", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521937000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "González-Herrero, H; Gómez-Rodríguez, JM; Mallet, P; Moaied, M; Palacios, JJ; Salgado, C; Ugeda, MM; Veuillen, JY; Yndurain, F; Brihuega, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonzalez-Herrero, Hector; Gomez-Rodriguez, Jose M.; Mallet, Pierre; Moaied, Mohamed; Jose Palacios, Juan; Salgado, Carlos; Ugeda, Miguel M.; Veuillen, Jean-Yves; Yndurain, Felix; Brihuega, Ivan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-scale control of graphene magnetism by using hydrogen atoms", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Isolated hydrogen atoms absorbed on graphene are predicted to induce magnetic moments. Here we demonstrate that the adsorption of a single hydrogen atom on graphene induces a magnetic moment characterized by a similar to 20-millielectron volt spin-split state at the Fermi energy. Our scanning tunneling microscopy (STM) experiments, complemented by first-principles calculations, show that such a spin-polarized state is essentially localized on the carbon sublattice opposite to the one where the hydrogen atom is chemisorbed. This atomically modulated spin texture, which extends several nullometers away from the hydrogen atom, drives the direct coupling between the magnetic moments at unusually long distances. By using the STM tip to manipulate hydrogen atoms with atomic precision, it is possible to tailor the magnetism of selected graphene regions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 598, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2016, "Volume": 352, "Issue": 6284, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 437, "End Page": 441, "Article Number": null, "DOI": "10.1126/science.aad8038", "DOI Link": "http://dx.doi.org/10.1126/science.aad8038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374479700041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YM; Yang, L; He, HJ; Sun, L; Wang, HL; Fang, X; Zhao, YL; Zheng, DY; Qi, Y; Li, Z; Deng, WQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yimeng; Yang, Li; He, Huijie; Sun, Lei; Wang, Honglei; Fang, Xu; Zhao, Yanliang; Zheng, Daoyuan; Qi, Yu; Li, Zhen; Deng, Weiqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ photodeposition of platinum clusters on a covalent organic framework for photocatalytic hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous covalent organic frameworks have arisen as tunable photocatalysts for H-2 production. Here, authors report frameworks engineered with co-catalyst binding sites to improve photocatalytic H-2 evolution performances. Photocatalytic hydrogen production has been considered a promising approach to obtain green hydrogen energy. Crystalline porous materials have arisen as key photocatalysts for efficient hydrogen production. Here, we report a strategy to in situ photodeposit platinum clusters as cocatalyst on a covalent organic framework, which makes it an efficient photocatalyst for light-driven hydrogen evolution. Periodically dispersed adsorption sites of platinum species are constructed by introducing adjacent hydroxyl group and imine-N in the region of the covalent organic framework structural unit where photogenerated electrons converge, leading to the in situ reduction of the adsorbed platinum species into metal clusters by photogenerated electrons. The widespread platinum clusters on the covalent organic framework expose large active surface and greatly facilitate the electron transfer, finally contributing to a high photocatalytic hydrogen evolution rate of 42432 mu mol g(-1) h(-1) at 1 wt% platinum loading. This work provides a direction for structural design on covalent organic frameworks to precisely manipulate cocatalyst morphologies and positions at the atomic level for developing efficient photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1355, "DOI": "10.1038/s41467-022-29076-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29076-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804856300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, SB; Miao, LL; Guo, ZN; Qi, X; Zhao, CJ; Zhang, H; Wen, SC; Tang, DY; Fan, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, S. B.; Miao, L. L.; Guo, Z. N.; Qi, X.; Zhao, C. J.; Zhang, H.; Wen, S. C.; Tang, D. Y.; Fan, D. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband nonlinear optical response in multi-layer black phosphorus: an emerging infrared and mid-infrared optical material", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorous (BP), the most thermodynamically stable allotrope of phosphorus, is a high-mobility layered semiconductor with direct band-gap determined by the number of layers from 0.3 eV (bulk) to 2.0 eV (single layer). Therefore, BP is considered as a natural candidate for broadband optical applications, particularly in the infrared (IR) and mid-IR part of the spectrum. The strong light-matter interaction, narrow direct band-gap, and wide range of tunable optical response make BP as a promising nonlinear optical material, particularly with great potentials for infrared and mid-infrared opto-electronics. Herein, we experimentally verified its broadband and enhanced saturable absorption of multi-layer BP (with a thickness of similar to 10 nm) by wide-band Z-scan measurement technique, and anticipated that multi-layer BPs could be developed as another new type of two-dimensional saturable absorber with operation bandwidth ranging from the visible (400 nm) towards mid-IR (at least 1930 nm). Our results might suggest that ultra-thin multi-layer BP films could be potentially developed as broadband ultra-fast photonics devices, such as passive Q-switcher, mode-locker, optical switcher etc. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 643, "Times Cited, All Databases": 685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2015, "Volume": 23, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11183, "End Page": 11194, "Article Number": null, "DOI": "10.1364/OE.23.011183", "DOI Link": "http://dx.doi.org/10.1364/OE.23.011183", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354337700031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JF; Li, ZY; Liu, XM; Li, CY; Zheng, YF; Yeung, KWK; Cui, ZD; Liang, YQ; Zhu, SL; Hu, WB; Qi, YJ; Zhang, TJ; Wang, XB; Wu, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianfang; Li, Zhaoyang; Liu, Xiangmei; Li, Changyi; Zheng, Yufeng; Yeung, Kelvin Wai Kwok; Cui, Zhenduo; Liang, Yanqin; Zhu, Shengli; Hu, Wenbin; Qi, Yajun; Zhang, Tianjin; Wang, Xianbao; Wu, Shuilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial engineering of Bi2S3/Ti3C2Tx MXene based on work function for rapid photo-excited bacteria-killing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In view of increasing drug resistance, ecofriendly photoelectrical materials are promising alternatives to antibiotics. Here we design an interfacial Schottky junction of Bi2S3/Ti3C2Tx resulting from the contact potential difference between Ti3C2Tx and Bi2S3. The different work functions induce the formation of a local electrophilic/nucleophilic region. The self-driven charge transfer across the interface increases the local electron density on Ti3C2Tx. The formed Schottky barrier inhibits the backflow of electrons and boosts the charge transfer and separation. The photocatalytic activity of Bi2S3/Ti3C2Tx intensively improved the amount of reactive oxygen species under 808nm near-infrared radiation. They kill 99.86% of Staphylococcus aureus and 99.92% of Escherichia coli with the assistance of hyperthermia within 10min. We propose the theory of interfacial engineering based on work function and accordingly design the ecofriendly photoresponsive Schottky junction using two kinds of components with different work functions to effectively eradicate bacterial infection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1224, "DOI": "10.1038/s41467-021-21435-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21435-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621931000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, MF; Zhou, WJ; Wang, AR; Huang, AX; Chen, JZ; Xu, JL; Wong, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Minfeng; Zhou, Weijun; Wang, Anran; Huang, Aixiang; Chen, Jizhang; Xu, Junling; Wong, Ching-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anti-freezing flexible aqueous Zn-MnO2 batteries working at-35 °C enabled by a borax-crosslinked polyvinyl alcohol/glycerol gel electrolyte", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible aqueous zinc-ion batteries (AZIBs) are promising to satisfy the emerging wearable electronics. However, conventional hydrogel electrolytes are unable to work at subzero temperatures because they inevitably freeze. In this work, a borax-crosslinked polyvinyl alcohol (PVA)/glycerol gel electrolyte is developed, in which glycerol can strongly interact with PVA chains, thus effectively prohibiting the formation of ice crystals within the whole gel network. Thanks to this, the freezing point of this gel electrolyte is below -60 degrees C, which allows it to work in extremely cold environments. Even at -35 degrees C, it still exhibits a high ionic conductivity of 10.1 mS cm(-1) and great mechanical properties. On the basis of this anti-freezing gel electrolyte, a flexible quasi-solid-state aqueous Zn-MnO2 battery is assembled and realizes an impressive energy density of 46.8 mW h cm(-3) (1330 mu W h cm(-2)) at a power density of 96 mW cm(-3) (2.7 mW cm(-2)) at 25 degrees C, outperforming nearly all the reported AZIBs. More importantly, when the temperature is reduced to -35 degrees C, a rather high energy density (25.8 mW h cm(-3), 732 mu W h cm(-2)) can still be achieved, and 53.3% of that value can be retained when the power density is increased to about 10-fold. This battery also shows excellent cycling durability (around 90% capacity retention over 2000 cycles) and great tolerance to various extreme conditions even when the temperature is down to -35 degrees C. These findings provide valuable insights into designing aqueous batteries/supercapacitors that can work in cold climates and high-altitude areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2020, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6828, "End Page": 6841, "Article Number": null, "DOI": "10.1039/d0ta01553a", "DOI Link": "http://dx.doi.org/10.1039/d0ta01553a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526953200038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, ST; Liu, XY; Liu, J; Yuk, H; Loh, HC; Parada, GA; Settens, C; Song, J; Masic, A; McKinley, GH; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Shaoting; Liu, Xinyue; Liu, Ji; Yuk, Hyunwoo; Loh, Hyun-Chae; Parada, German A.; Settens, Charles; Song, Jake; Masic, Admir; McKinley, Gareth H.; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anti-fatigue-fracture hydrogels", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emerging applications of hydrogels in devices and machines require hydrogels to maintain robustness under cyclicmechanical loads. Whereas hydrogels have been made tough to resist fracture under a single cycle of mechanical load, these toughened gels still suffer from fatigue fracture under multiple cycles of loads. The reported fatigue threshold for synthetic hydrogels is on the order of 1 to 100 J/m(2). We propose that designing anti-fatigue-fracture hydrogels requires making the fatigue crack encounter and fracture objects with energies per unit area much higher than that for fracturing a single layer of polymer chains. We demonstrate that the controlled introduction of crystallinity in hydrogels can substantially enhance their anti-fatigue-fracture properties. The fatigue threshold of polyvinyl alcohol (PVA) with a crystallinity of 18.9 weight % in the swollen state can exceed 1000 J/m(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau8528", "DOI": "10.1126/sciadv.aau8528", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau8528", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457547900077", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, Q; Ma, H; Hou, QZ; Li, YX; Ren, J; Dai, XZ; Yao, ZB; Zhou, Y; Xiang, LC; Du, HY; He, HC; Wang, N; Jiang, KL; Lin, H; Zhang, HW; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Qiang; Ma, He; Hou, Qinzhi; Li, Yingxiang; Ren, Jing; Dai, Xuezeng; Yao, Zhibo; Zhou, Yu; Xiang, Lichen; Du, Huayun; He, Hongcai; Wang, Ning; Jiang, Kaili; Lin, Hong; Zhang, Huaiwu; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Carbon-Electrode-Based Endurable Flexible Perovskite Solar Cells", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Endured, low-cost, and high-performance flexible perovskite solar cells (PSCs) featuring lightweight and mechanical flexibility have attracted tremendous attention for portable power source applications. However, flexible PSCs typically use expensive and fragile indium-tin oxide as transparent anode and high-vacuum processed noble metal as cathode, resulting in dramatic performance degradation after continuous bending or thermal stress. Here, all-carbon-electrode-based flexible PSCs are fabricated employing graphene as transparent anode and carbon nullotubes as cathode. All-carbon-electrode-based flexible devices with and without spiro-OMeTAD (2,2,7,7-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9-spirobifluorene) hole conductor achieve power conversion efficiencies (PCEs) of 11.9% and 8.4%, respectively. The flexible carbon-electrode-based solar cells demonstrate superior robustness against mechanical deformation in comparison with their counterparts fabricated on flexible indium-tin oxide substrates. Moreover, all carbon-electrode-based flexible PSCs also show significantly enhanced stability compared to the flexible devices with gold and silver cathodes under continuous light soaking or 60 degrees C thermal stress in air, retaining over 90% of their original PCEs after 1000 h. The promising durability and stability highlight that flexible PSCs are fully compatible with carbon materials and pave the way toward the realization of rollable and low-cost flexible perovskite photovoltaic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 28, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706777, "DOI": "10.1002/adfm.201706777", "DOI Link": "http://dx.doi.org/10.1002/adfm.201706777", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427110100031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alvarado, J; Schroeder, MA; Pollard, TP; Wang, XF; Lee, JZ; Zhang, MH; Wynn, T; Ding, M; Borodin, O; Meng, YS; Xu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alvarado, Judith; Schroeder, Marshall A.; Pollard, Travis P.; Wang, Xuefeng; Lee, Jungwoo Z.; Zhang, Minghao; Wynn, Thomas; Ding, Michael; Borodin, Oleg; Meng, Ying Shirley; Xu, Kang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bisalt ether electrolytes: a pathway towards lithium metal batteries with Ni-rich cathodes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical performance and mechanistic effects of incorporating two salts in an ether electrolyte in Li-metal cells were investigated experimentally and via molecular scale modeling. Improvements in efficiency and cycling stability over baseline electrolytes in lithium (Li) versus copper (Cu) cells were directly correlated to the initial Li-nucleation process, as observed via cryogenic-focused ion beam (cryo-FIB) prepared cross sections, which revealed that Li films deposited with the bisalt electrolyte were significantly thinner and denser than those from the baseline. This behavior was further traced back to the initial nucleation process via cryogenic transmission electron microscopy (cryo-TEM), which shows stark differences in the morphology and conformality of deposited Li as a function of electrolyte chemistry. X-ray photoelectron spectroscopy (XPS) indicated that the solid electrolyte interphase (SEI) formed from the bisalt electrolyte primarily consists of larger anion fragments, suggesting that the anion chemistry strongly influences the extent of reduction and resulting surface chemistry. Ab initio DFT-based and force field-based molecular dynamics calculations revealed the complex interplay (positioning, orientation, reactivity, kinetics) between the FSI- and TFSI- anions in the double layer at both electrode-electrolyte interfaces and the ramifications for stabilizing these interfaces. As a result of the unique interphasial chemistry brought by this bisalt system, this electrolyte supports an unprecedented (for an ether-based electrolyte) capacity retention (>88%) after 300 cycles (approximate to 2 months of cycling) in a 4.4 V NMC622-Li cell, and a >30% improvement in capacity retention over baseline after 50 cycles in 4.4 V NMC622-Cu anode-free cells. Altogether, these results provide new insight into how the bisalt effect can be leveraged for regulating the timescale, chemistry, and extent of interfacial reactions. When balanced properly, this promotes efficient plating/deplating of Li, and potentially supports widespread implementation of high nickel content NMC cell configurations with limited or no excess lithium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 780, "End Page": 794, "Article Number": null, "DOI": "10.1039/c8ee02601g", "DOI Link": "http://dx.doi.org/10.1039/c8ee02601g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459741700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kawai, S; Benassi, A; Gnecco, E; Söde, H; Pawlak, R; Feng, XL; Müllen, K; Passerone, D; Pignedoli, CA; Ruffieux, P; Fasel, R; Meyer, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kawai, Shigeki; Benassi, Andrea; Gnecco, Enrico; Soede, Hajo; Pawlak, Remy; Feng, Xinliang; Muellen, Klaus; Passerone, Daniele; Pignedoli, Carlo A.; Ruffieux, Pascal; Fasel, Roman; Meyer, Ernst", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superlubricity of graphene nulloribbons on gold surfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The state of vanishing friction known as superlubricity has important applications for energy saving and increasing the lifetime of devices. Superlubricity, as detected with atomic force microscopy, appears when sliding large graphite flakes or gold nulloclusters across surfaces, for example. However, the origin of the behavior is poorly understood because of the lack of a controllable nullocontact. We demonstrated the superlubricity of graphene nulloribbons when sliding on gold with a joint experimental and computational approach. The atomically well-defined contact allows us to trace the origin of superlubricity, unraveling the role played by ribbon size and elasticity, as well as by surface reconstruction. Our results pave the way to the scale-up of superlubricity and thus to the realization of frictionless coatings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2016, "Volume": 351, "Issue": 6276, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 957, "End Page": 961, "Article Number": null, "DOI": "10.1126/science.aad3569", "DOI Link": "http://dx.doi.org/10.1126/science.aad3569", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370821400037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, H; Chen, Y; Delattre, B; Tomsia, AP; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Hao; Chen, Yuan; Delattre, Benjamin; Tomsia, Antoni P.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired large-scale aligned porous materials assembled with dual temperature gradients", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural materials, such as bone, teeth, shells, and wood, exhibit outstanding properties despite being porous and made of weak constituents. Frequently, they represent a source of inspiration to design strong, tough, and lightweight materials. Although many techniques have been introduced to create such structures, a long-range order of the porosity as well as a precise control of the final architecture remain difficult to achieve. These limitations severely hinder the scale-up fabrication of layered structures aimed for larger applications. We report on a bidirectional freezing technique to successfully assemble ceramic particles into scaffolds with large-scale aligned, lamellar, porous, nacre-like structure and long-range order at the centimeter scale. This is achieved by modifying the cold finger with a polydimethylsiloxane (PDMS) wedge to control the nucleation and growth of ice crystals under dual temperature gradients. Our approach could provide an effective way of manufacturing novel bioinspired structural materials, in particular advanced materials such as composites, where a higher level of control over the structure is required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500849", "DOI": "10.1126/sciadv.1500849", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500849", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216604200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhadra, M; Kandambeth, S; Sahoo, MK; Addicoat, M; Balaraman, E; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhadra, Mohitosh; Kandambeth, Sharath; Sahoo, Manoj K.; Addicoat, Matthew; Balaraman, Ekambaram; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E-Z Isomerization of Olefins", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions. Although precious metal/organic dyes based homogeneous photocatalysts have been developed, their toxic and nonreusable nature makes them inappropriate for large-scale production. Therefore, we have synthesized a triazine and a keto functionalized nonmetal based covalent organic framework (TpTt) for heterogeneous photo catalysis. As the catalyst shows significant absorption of visible light, it has been applied for the photocatalytic uphill conversion of trans-stilbene to cis-stilbene in the presence of blue light-emitting diodes with broad substrate scope via an energy transfer process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 141, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6152, "End Page": 6156, "Article Number": null, "DOI": "10.1021/jacs.9b01891", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b01891", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465188800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aziz, MAA; Jalil, AA; Triwahyono, S; Mukti, RR; Taufiq-Yap, YH; Sazegar, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aziz, M. A. A.; Jalil, A. A.; Triwahyono, S.; Mukti, R. R.; Taufiq-Yap, Y. H.; Sazegar, M. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active Ni-promoted mesostructured silica nulloparticles for CO2 methanation", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mesostructured silica nulloparticles (MSN) and Ni loaded onto MSN (Ni/MSN) for the methanation of CO2 were prepared by the sol-gel and impregnation methods. Catalytic testing was conducted in the temperature range of 423-723 K under atmospheric pressure in the presence of H-2. Ni supported on MSN was compared with others types of support such as MCM-41 (Mobile Crystalline Material), HY (protonated Y zeolite), SiO2 and gamma-Al2O3. The activity of CO2 methanation followed the order: Ni/MSN > Ni/MCM-41 > Ni/HY > Ni/SiO2 > Ni/gamma-Al2O3. The nitrogen physisorption and pyrrole adsorbed IR spectroscopy results indicated that the high activity of Ni/MSN is due to the presence of both intra- and inter-particle porosity which led to the high concentration of basic sites. In addition, the correlation between N-H band intensity and the turnover frequency revealed that the methanation activity increased with increasing of the concentration of basic sites. The presence of defect sites or oxygen vacancies in MSN was responsible for the formation of surface carbon species, while Ni sites dissociated hydrogen to form atomic hydrogen. The surface carbon species then interacted with atomic hydrogen to form methane. The Ni/MSN catalyst performed with good stability and no deactivation up to 200 h. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2014, "Volume": 147, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 359, "End Page": 368, "Article Number": null, "DOI": "10.1016/j.apcatb.2013.09.015", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2013.09.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330489400040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wright, AD; Verdi, C; Milot, RL; Eperon, GE; Pérez-Osorio, MA; Snaith, HJ; Giustino, F; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.; Eperon, Giles E.; Perez-Osorio, Miguel A.; Snaith, Henry J.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-phonon coupling in hybrid lead halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)(2)PbI3, HC(NH2)(2)PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Frohlich interaction is the dominullt source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Frohlich coupling constants of similar to 40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1065, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11755, "DOI": "10.1038/ncomms11755", "DOI Link": "http://dx.doi.org/10.1038/ncomms11755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376674500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Liu, XM; Tan, L; Cui, ZD; Yang, XJ; Liang, YQ; Li, ZY; Zhu, SL; Zheng, YF; Yeung, KWK; Wang, XB; Wu, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jun; Liu, Xiangmei; Tan, Lei; Cui, Zhenduo; Yang, Xianjin; Liang, Yanqin; Li, Zhaoyang; Zhu, Shengli; Zheng, Yufeng; Yeung, Kelvin Wai Kwok; Wang, Xianbao; Wu, Shuilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc-doped Prussian blue enhances photothermal clearance of Staphylococcus aureus and promotes tissue repair in infected wounds", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of photothermal therapy to treat bacterial infections remains a challenge, as the high temperatures required for bacterial elimination can damage healthy tissues. Here, we develop an exogenous antibacterial agent consisting of zinc-doped Prussian blue (ZnPB) that kills methicillin-resistant Staphylococcus aureus in vitro and in a rat model of cutaneous wound infection. Local heat triggered by the photothermal effect accelerates the release and penetration of ions into the bacteria, resulting in alteration of intracellular metabolic pathways and bacterial killing without systemic toxicity. ZnPB treatment leads to the upregulation of genes involved in tissue remodeling, promotes collagen deposition and enhances wound repair. The efficient photothermal conversion of ZnPB allows the use of relatively few doses and low laser flux, making the platform a potential alternative to current antibiotic therapies against bacterial wound infections.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4490, "DOI": "10.1038/s41467-019-12429-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12429-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488774200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SH; Yu, L; Wang, SS; Zhang, L; Chen, L; Xu, X; Song, ZQ; Liu, H; Chen, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Siheng; Yu, Le; Wang, Shanshan; Zhang, Lei; Chen, Lu; Xu, Xu; Song, Zhanqian; Liu, He; Chen, Chaoji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong, tough, ionic conductive, and freezing-tolerant all-natural hydrogel enabled by cellulose-bentonite coordination interactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cellulose based ion conductive hydrogels are emerging materials for application in flexible electronics but achieving simultaneously high conductivity and good mechanical properties remains challenging. Here, the authors propose a supramolecular engineering strategy to strengthen cellulosic hydrogel and to improve simultaneously its ionic conductivity and freezing tolerance. Ionic conductive hydrogels prepared from naturally abundant cellulose are ideal candidates for constructing flexible electronics from the perspective of commercialization and environmental sustainability. However, cellulosic hydrogels featuring both high mechanical strength and ionic conductivity remain extremely challenging to achieve because the ionic charge carriers tend to destroy the hydrogen-bonding network among cellulose. Here we propose a supramolecular engineering strategy to boost the mechanical performance and ionic conductivity of cellulosic hydrogels by incorporating bentonite (BT) via the strong cellulose-BT coordination interaction and the ion regulation capability of the nulloconfined cellulose-BT intercalated nullostructure. A strong (compressive strength up to 3.2 MPa), tough (fracture energy up to 0.45 MJ m(-3)), yet highly ionic conductive and freezing tolerant (high ionic conductivities of 89.9 and 25.8 mS cm(-1) at 25 and -20 degrees C, respectively) all-natural cellulose-BT hydrogel is successfully realized. These findings open up new perspectives for the design of cellulosic hydrogels and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3408, "DOI": "10.1038/s41467-022-30224-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30224-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000814343700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CB; Li, YF; Yu, S; Louisia, S; Jin, JB; Li, MF; Ross, MB; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chubai; Li, Yifan; Yu, Sunmoon; Louisia, Sheena; Jin, Jianbo; Li, Mufan; Ross, Michael B.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu-Ag Tandem Catalysts for High-Rate CO2 Electrolysis toward Multicarbons", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tandem electrocatalysis decouples individual steps within a chemically complicated pathway via multicomponent catalyst design. Such a concept is attractive for CO2 electro-conversion to multicarbons (C2+), especially at high rates. Here, we show that a Cu-Ag tandem catalyst on a gas diffusion electrode (GDE) can enhance the C2+ production rate from CO2 through CO2 reduction to CO on Ag and subsequent carbon coupling on Cu. With added Ag, the C2+ partial current over a Cu surface increases from 37 to 160 mA/cm(2) at 0.70 V versus reversible hydrogen electrode (RHE) in 1 M KOH with no mutual interference between the two metals. Moreover, the intrinsic C2H4 and C2H5 OH activity in the tandem platform is significantly higher than Cu alone under either pure CO2 or CO atmosphere. Our results indicate that the CO-enriched local environment generated by Ag can enhance C(2+ )formation on Cu beyond CO2 or CO feeding, suggesting new mechanisms in a tandem three-phase environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2020, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1688, "End Page": 1699, "Article Number": null, "DOI": "10.1016/j.joule.2020.07.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.07.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561454400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, LZ; Chen, CF; Smith, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Liangzhi; Chen, Changfeng; Smith, Sean C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene: Fabrication, Properties, and Applications", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, the single- or few-layer form of black phosphorus, was recently rediscovered as a two-dimensional layered material holding great promise for applications in electronics and optoelectronics. Research into its fundamental properties and device applications has since seen exponential growth. In this Perspective, we review recent progress in phosphorene research, touching upon topics on fabrication, properties, and applications; we also discuss challenges and future research directions. We highlight the intrinsically anisotropic electronic, transport, optoelectronic, thermoelectric, and mechanical properties of phosphorene resulting from its puckered structure in contrast to those of graphene and transition-metal dichalcogenides. The facile fabrication and novel properties of phosphorene have inspired design and demonstration of new nullodevices; however, further progress hinges on resolutions to technical obstructions like surface degradation effects and nonscalable fabrication techniques. We also briefly describe the latest developments of more sophisticated design concepts and implementation schemes that address some of the challenges in phosphorene research. It is expected that this fascinating material will continue to offer tremendous opportunities for research and development for the foreseeable future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 724, "Times Cited, All Databases": 759, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2015, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2794, "End Page": 2805, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b01094", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b01094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358339600024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SF; Ji, X; Piao, N; Chen, J; Eidson, N; Xu, JJ; Wang, PF; Chen, L; Zhang, JX; Deng, T; Hou, S; Jin, T; Wan, HL; Li, JR; Tu, JP; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Sufu; Ji, Xiao; Piao, null; Chen, Ji; Eidson, Nico; Xu, Jijian; Wang, Pengfei; Chen, Long; Zhang, Jiaxun; Deng, Tao; Hou, Singyuk; Jin, Ting; Wan, Hongli; Li, Jingru; Tu, Jiangping; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Inorganic-Rich Solid Electrolyte Interphase for Advanced Lithium-Metal Batteries in Carbonate Electrolytes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In carbonate electrolytes, the organic-inorganic solid electrolyte interphase (SEI) formed on the Li-metal anode surface is strongly bonded to Li and experiences the same volume change as Li, thus it undergoes continuous cracking/reformation during plating/stripping cycles. Here, an inorganic-rich SEI is designed on a Li-metal surface to reduce its bonding energy with Li metal by dissolving 4m concentrated LiNO3 in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene-carbonate (FEC)-based electrolyte. Due to the aggregate structure of NO3- ions and their participation in the primary Li+ solvation sheath, abundant Li2O, Li3N, and LiNxOy grains are formed in the resulting SEI, in addition to the uniform LiF distribution from the reduction of PF6- ions. The weak bonding of the SEI (high interface energy) to Li can effectively promote Li diffusion along the SEI/Li interface and prevent Li dendrite penetration into the SEI. As a result, our designed carbonate electrolyte enables a Li anode to achieve a high Li plating/stripping Coulombic efficiency of 99.55 % (1 mA cm(-2), 1.0 mAh cm(-2)) and the electrolyte also enables a Li||LiNi0.8Co0.1Mn0.1O2 (NMC811) full cell (2.5 mAh cm(-2)) to retain 75 % of its initial capacity after 200 cycles with an outstanding CE of 99.83 %.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2021, "Volume": 60, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3661, "End Page": 3671, "Article Number": null, "DOI": "10.1002/anie.202012005", "DOI Link": "http://dx.doi.org/10.1002/anie.202012005", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599074500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HB; Liu, YY; Chen, T; Zhang, JT; Zhang, J; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huabin; Liu, Yanyu; Chen, Tao; Zhang, Jintao; Zhang, Jing; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the Activity Origin of Electrocatalytic Oxygen Evolution over Isolated Ni Atoms Supported on a N-Doped Carbon Matrix", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring highly efficient electrocatalysts for the oxygen evolution reaction (OER) and unveiling their activity origin are pivotal for energy conversion technologies. Herein, atomically distributed Ni sites over a N-doped hollow carbon matrix are reported as a promising electrocatalyst for OER in alkaline conditions. Significantly boosted activity is observed after the decoration of the active Ni sites with well-controlled coordination geometry. Results of X-ray absorption spectroscopy investigation and density functional theory (DFT) calculation reveal that the effective electronic coupling via the Ni-N coordination can move down the Fermi level and lower the adsorption energy of intermediates, thus resulting in the facilitated OER kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 31, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904548, "DOI": "10.1002/adma.201904548", "DOI Link": "http://dx.doi.org/10.1002/adma.201904548", "Book DOI": null, "Early Access Date": "OCT 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490651400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, UH; Jun, DW; Park, KJ; Zhang, Q; Kaghazchi, P; Aurbach, D; Major, DT; Goobes, G; Dixit, M; Leifer, N; Wang, CM; Yan, P; Ahn, D; Kim, KH; Yoon, CS; Sun, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, U. -H.; Jun, D. -W.; Park, K. -J.; Zhang, Q.; Kaghazchi, P.; Aurbach, D.; Major, D. T.; Goobes, G.; Dixit, M.; Leifer, N.; Wang, C. M.; Yan, P.; Ahn, D.; Kim, K. -H.; Yoon, C. S.; Sun, Y. -K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pushing the limit of layered transition metal oxide cathodes for high-energy density rechargeable Li ion batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of advanced high energy density lithium ion batteries is important for promoting electromobility. Making electric vehicles attractive and competitive compared to conventional automobiles depends on the availability of reliable, safe, high power, and highly energetic batteries whose components are abundant and cost effective. Nickel rich Li[NixCoyMn1-x-y]O-2 layered cathode materials (x > 0.5) are of interest because they can provide very high specific capacity without pushing charging potentials to levels that oxidize the electrolyte solutions. However, these cathode materials suffer from stability problems. We discovered that doping these materials with tungsten (1 mol%) remarkably increases their stability due to a partial layered to cubic (rock salt) phase transition. We demonstrate herein highly stable Li ion battery prototypes consisting of tungsten-stabilized Ni rich cathode materials (x > 0.9) with specific capacities >220 mA h g(-1). This development can increase the energy density of Li ion batteries more than 30% above the state of the art without compromising durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2018, "Volume": 11, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1271, "End Page": 1279, "Article Number": null, "DOI": "10.1039/c8ee00227d", "DOI Link": "http://dx.doi.org/10.1039/c8ee00227d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432599100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HP; Lin, Q; Zhang, C; Yu, XY; Cheng, Z; Li, GD; Hu, Q; Ren, XZ; Zhang, QL; Liu, JH; He, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hengpan; Lin, Qing; Zhang, Chao; Yu, Xinyao; Cheng, Zhong; Li, Guodong; Hu, Qi; Ren, Xiangzhong; Zhang, Qianling; Liu, Jianhong; He, Chuanxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon dioxide electroreduction on single-atom nickel decorated carbon membranes with industry compatible current densities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide electroreduction provides a useful source of carbon monoxide, but comparatively few catalysts could be sustained at current densities of industry level. Herein, we construct a high-yield, flexible and self-supported single-atom nickel-decorated porous carbon membrane catalyst. This membrane possesses interconnected nullofibers and hierarchical pores, affording abundant effective nickel single atoms that participate in carbon dioxide reduction. Moreover, the excellent mechanical strength and well-distributed nickel atoms of this membrane combines gas-diffusion and catalyst layers into one architecture. This integrated membrane could be directly used as a gas diffusion electrode to establish an extremely stable three-phase interface for high-performance carbon dioxide electroreduction, producing carbon monoxide with a 308.4mAcm(-2) partial current density and 88% Faradaic efficiency for up to 120h. We hope this work will provide guidance for the design and application of carbon dioxide electro-catalysts at the potential industrial scale. Here the authors deploy Ni single atom-decorated carbon membranes as integrated gas diffusion electrodes to construct an extremely stable three-phase interface for CO2 electroreduction, producing CO with a partial current density of 308.4mAcm(-2) and a Faradaic efficiency of 88% for up to 120h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-14402-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14402-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543981700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raja, SN; Bekenstein, Y; Koc, MA; Fischer, S; Zhang, D; Lin, L; Ritchie, RO; Yang, P; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A.; Fischer, Stefan; Zhang, Dandan; Lin, Liwei; Ritchie, Robert O.; Yang, Peidong; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encapsulation of Perovskite nullocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskites hold promise for photonic devices, due to their superior optoelectronic properties. However, their use is limited by poor stability and toxicity. We demonstrate enhanced water and light stability of high-surface-area colloidal perovskite nullocrystals by encapsulation of colloidal CsPbBr3 quantum dots into matched hydrophobic macroscale polymeric matrices. This is achieved by mixing the quantum dots with presynthesized high molecular-weight polymers. We monitor the photoluminescence quantum yield of the perovskite-polymer nullocomposite films under water-soaking for the first time, finding no change even after >4 months of continuous immersion in water. Furthermore, photo stability is greatly enhanced in the macroscale polymer-encapsulated nullocrystal perovskites, which sustain >10(10) absorption events per quantum dot prior to photodegradation, a significant threshold for potential device use. Control of the quantum dot shape in these thin-film polymer composite enables color tunability via strong quantum-confinement in nulloplates and significant room temperature polarized emission from perovskite nullowires. Not only does the high-molecular-weight polymer protect the perovskites from the environment but also no escaped lead was detected in water that was in contact with the encapsulated perovskites for months. Our ligand-passivated perovskite-macroscale polymer composites provide a robust platform for diverse photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2016, "Volume": 8, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 35523, "End Page": 35533, "Article Number": null, "DOI": "10.1021/acsami.6b09443", "DOI Link": "http://dx.doi.org/10.1021/acsami.6b09443", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391081700064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, LF; Cao, YL; Henderson, WA; Sushko, ML; Shao, YY; Xiao, J; Wang, W; Engelhard, MH; Nie, ZM; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Lifen; Cao, Yuliang; Henderson, Wesley A.; Sushko, Maria L.; Shao, Yuyan; Xiao, Jie; Wang, Wei; Engelhard, Mark H.; Nie, Zimin; Liu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hard carbon nulloparticles as high-capacity, high-stability anodic materials for Na-ion batteries", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard carbon nulloparticles (HCNP) were synthesized by the pyrolysis of a polyaniline precursor. The measured Na+ cation diffusion coefficient (10(-13)-10(-15) cm(2) s(-1)) in the HCNP obtained at 1150 degrees C is two orders of magnitude lower than that of Li+ in graphite (10(-10)-10(-13) cm(2) s(-1)), indicating that reducing the carbon particle size is very important for improving electrochemical performance. These measurements also enable a clear visualization of the stepwise reaction phases and rate changes which occur throughout the insertion/extraction processes in HCNP, The electrochemical measurements also show that the nullo -sized HCNP obtained at 1150 degrees C exhibited higher practical capacity at voltages lower than 1.2 V (vs. Na/Na+), as well as a prolonged cycling stability, which is attributed to an optimum spacing of 0.366 nm between the graphitic layers and the nullo particular size resulting in a low -barrier Na+ cation insertion. These results suggest that HCNP is a very promising high-capacity/stability anode for low cost sodium-ion batteries (SIBS). (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 279, "End Page": 288, "Article Number": null, "DOI": "10.1016/j.nulloen.2015.10.034", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2015.10.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369565400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XG; Yan, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaogang; Yan, Dongpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-afterglow metal-organic frameworks: reversible guest-induced phosphorescence tunability", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Luminescent metal-organic frameworks (MOFs) have received much attention due to their wide structural tunability and potential application in light-emitting diodes, biological imaging and chemical sensors. However, successful examples of long-persistent afterglow MOFs are still quite limited to date. In this work, we report that two types of Zn-terephthalate (TPA) MOFs (namely [Zn(TPA)(DMF)] (1-DMF) and MOF-5) could exhibit an obvious room-temperature afterglow emission with a time-resolved luminescence lifetime as high as 0.47 seconds. The phosphorescence-based afterglow was also highly sensitive to the temperature, and the reversible emission intensity could be recycled under high/low temperatures. Moreover, both 1-DMF and MOF-5 showed highly tunable afterglow phosphorescence colors (from cyan to yellow and from green to red, respectively) upon treatment with pyridine solution. The fluorescence/phosphorescence emission color of MOF-5 can be reversibly switched due to the addition and removal of a pyridine guest to and from the host nullochannel, as shown in both experimental and computational studies. Therefore, this work not only shows a facile method to develop MOF-based long-afterglow materials at room temperature, but also presents a strategy to tune their phosphorescence in a wide range based on host-guest interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4519, "End Page": 4526, "Article Number": null, "DOI": "10.1039/c6sc00563b", "DOI Link": "http://dx.doi.org/10.1039/c6sc00563b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378715000068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ovchinnikov, D; Allain, A; Huang, YS; Dumcenco, D; Kis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ovchinnikov, Dmitry; Allain, Adrien; Huang, Ying-Sheng; Dumcenco, Dumitru; Kis, Andras", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical Transport Properties of Single-Layer WS2", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the fabrication of field-effect transistors based on single layers and bilayers of the semiconductor WS2 and the investigation of their electronic transport properties. We find that the doping level strongly depends on the device environment and that long in situ annealing drastically improves the contact transparency, allowing four-terminal measurements to be performed and the pristine properties of the material to be recovered. Our devices show n-type behavior with a high room temperature on/off current ratio of similar to 10(6). They show clear metallic behavior at high charge carrier densities and mobilities as high as similar to 140 cm(2)/(V s) at low temperatures (above 300 cm(2)/(V s) in the case of bilayers). In the insulating regime, the devices exhibit variable range hopping, with a localization length of about 2 nm that starts to increase as the Fermi level enters the conduction band. The promising electronic properties of WS2, comparable to those of single layer MoS2 and WSe2, together with its strong spin-orbit coupling, make it interesting for future applications in electronic, optical, and valleytronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 651, "Times Cited, All Databases": 713, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8174, "End Page": 8181, "Article Number": null, "DOI": "10.1021/nn502362b", "DOI Link": "http://dx.doi.org/10.1021/nn502362b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340992300062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HC; Hou, J; Hu, YX; Wang, PY; Ou, RW; Jiang, L; Liu, JZ; Freeman, BD; Hill, AJ; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huacheng; Hou, Jue; Hu, Yaoxin; Wang, Peiyao; Ou, Ranwen; Jiang, Lei; Liu, Jefferson Zhe; Freeman, Benny D.; Hill, Anita J.; Wang, Huanting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast selective transport of alkali metal ions in metal organic frameworks with subnullometer pores", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous membranes with ultrafast ion permeation and high ion selectivity are highly desirable for efficient mineral separation, water purification, and energy conversion, but it is still a huge challenge to efficiently separate monatomic ions of the same valence and similar sizes using synthetic membranes. We report metal organic framework (MOF) membranes, including ZIF-8 and UiO-66 membranes with uniform subnullometer pores consisting of angstrom-sized windows and nullometer-sized cavities for ultrafast selective transport of alkali metal ions. The angstrom-sized windows acted as ion selectivity filters for selection of alkali metal ions, whereas the nullometersized cavities functioned as ion conductive pores for ultrafast ion transport. The ZIF-8 and UiO-66 membranes showed a LiCl/RbCl selectivity of similar to 4.6 and similar to 1.8, respectively, which are much greater than the LiCl/RbCl selectivity of 0.6 to 0.8 measured in traditional porous membranes. Molecular dynamics simulations suggested that ultrafast and selective ion transport in ZIF-8 was associated with partial dehydration effects. This study reveals ultrafast and selective transport of monovalent ions in subnullometer MOF pores and opens up a new avenue to develop unique MOF platforms for efficient ion separations in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaq0066", "DOI": "10.1126/sciadv.aaq0066", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaq0066", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426845500050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mou, Y; Wu, XD; Qin, CC; Chen, JY; Zhao, YL; Jiang, LB; Zhang, C; Yuan, XZ; Ang, EH; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mou, Yi; Wu, Xiaodong; Qin, Chencheng; Chen, Junying; Zhao, Yanlan; Jiang, Longbo; Zhang, Chen; Yuan, Xingzhong; Ang, Edison Huixiang; Wang, Hou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Linkage Microenvironment of Azoles-Related Covalent Organic Frameworks Precisely Regulates Photocatalytic Generation of Hydrogen Peroxide", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial H2O2 photosynthesis by covalent organic frameworks (COFs) photocatalysts is promising for wastewater treatment. The effect of linkage chemistry of COFs as functional basis to photoelectrochemical properties and photocatalysis remains a significant challenge. In this study, three kinds of azoles-linked COFs including thiazole-linked TZ-COF, oxazole-linked OZ-COF and imidazole-linked IZ-COF were successfully synthesized. More accessible channels of charge transfer were constructed in TZ-COF via the donor-& pi;-acceptor structure between thiazole linkage and pyrene linker, leading to efficient suppression of photoexcited charge recombination. Density functional theory calculations support the experimental studies, demonstrating that the thiazole linkage is more favorable for the formation of *O-2 intermediate in H2O2 production than that of the oxazole and imidazole linkages. The real active sites in COFs located at the benzene ring fragment between pyrene unit and azole linkage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2023, "Volume": 62, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202309480", "DOI Link": "http://dx.doi.org/10.1002/anie.202309480", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001034834300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Verdaguer-Casadevall, A; Deiana, D; Karamad, M; Siahrostami, S; Malacrida, P; Hansen, TW; Rossmeisl, J; Chorkendorff, I; Stephens, IEL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Verdaguer-Casadevall, Arnau; Deiana, Davide; Karamad, Mohammadreza; Siahrostami, Samira; Malacrida, Paolo; Hansen, Thomas W.; Rossmeisl, Jan; Chorkendorff, Ib; Stephens, Ifan E. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trends in the Electrochemical Synthesis of H2O2: Enhancing Activity and Selectivity by Electrocatalytic Site Engineering", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The direct electrochemical synthesis of hydrogen peroxide is a promising alternative to currently used batch synthesis methods. Its industrial viability is dependent on the effective catalysis of the reduction of oxygen at the cathode. Herein, we study the factors controlling activity and selectivity for H2O2 production on metal surfaces. Using this approach, we discover two new catalysts for the reaction, Ag-Hg and Pd-Hg, with unique electrocatalytic properties both of which exhibit performance that far exceeds the current state-of-the art.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 590, "Times Cited, All Databases": 639, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1603, "End Page": 1608, "Article Number": null, "DOI": "10.1021/nl500037x", "DOI Link": "http://dx.doi.org/10.1021/nl500037x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335720300079", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HD; Du, CF; Liao, LL; Zhang, HJ; Zhou, HQ; Zhou, WC; Ren, TN; Sun, ZC; Lu, YF; Nie, ZT; Xu, F; Zhu, JX; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Haodong; Du, Chengfeng; Liao, Liling; Zhang, Hongjian; Zhou, Haiqing; Zhou, Weichang; Ren, Tianning; Sun, Zhicheng; Lu, Yufei; Nie, Zhentao; Xu, Feng; Zhu, Jixin; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching intrinsic dynamics of MXenes hybrid hydrogel for 3D printed multimodal intelligent devices with ultrahigh superelasticity and temperature sensitivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are investigated broadly in flexible sensors which have been applied into wearable electronics. However, further application of hydrogels is restricted by the ambiguity of the sensing mechanisms, and the multi-functionalization of flexible sensing systems based on hydrogels in terms of cost, difficulty in integration, and device fabrication remains a challenge, obstructing the specific application scenarios. Herein, cost-effective, structure-specialized and scenario-applicable 3D printing of direct ink writing (DIW) technology fabricated two-dimensional (2D) transition metal carbides (MXenes) bonded hydrogel sensor with excellent strain and temperature sensing performance is developed. Gauge factor (GF) of 5.7 (0 - 191% strain) and high temperature sensitivity (-5.27% degrees C-1) within wide working range (0 - 80 degrees C) can be achieved. In particular, the corresponding mechanisms are clarified based on finite element analysis and the first use of in situ temperature-dependent Raman technology for hydrogels, and the printed sensor can realize precise temperature indication of shape memory solar array hinge. Cost effective device fabrication of powerful hydrogel sensors remains challenging. Here, the authors propose a cost-effective and structure-specialized direct ink writing technique for the fabrication of two-dimensional MXene bonded hydrogel sensors with excellent strain and temperature sensing performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3420, "DOI": "10.1038/s41467-022-31051-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31051-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000811535600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, BH; Carlton, CE; Kongkanulld, A; Kukreja, RS; Theobald, BR; Gan, L; O'Malley, R; Strasser, P; Wagner, FT; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Binghong; Carlton, Christopher E.; Kongkanulld, Anusorn; Kukreja, Ratandeep S.; Theobald, Brian R.; Gan, Lin; O'Malley, Rachel; Strasser, Peter; Wagner, Frederick T.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate the unprecedented proton exchange membrane fuel cell (PEMFC) performance durability of a family of dealloyed Pt-Ni nulloparticle catalysts for the oxygen reduction reaction (ORR), exceeding scientific and technological state-of-art activity and stability targets. We provide atomic-scale insight into key factors controlling the stability of the cathode catalyst by studying the influence of particle size, the dealloying protocol and post-acid-treatment annealing on nulloporosity and passivation of the alloy nulloparticles. Scanning transmission electron microscopy coupled to energy dispersive spectroscopy data revealed the compositional variations of Ni in the particle surface and core, which were combined with an analysis of the particle morphology evolution during PEMFC voltage cycling; together, this enabled the elucidation of alloy structure and compositions conducive to long-term PEMFC device stability. We found that smaller size, less-oxidative acid treatment and annealing significantly reduced Ni leaching and nulloporosity formation while encouraged surface passivation, all resulting in improved stability and higher catalytic ORR activity. This study demonstrates a successful example of how a translation of basic catalysis research into a real-life device technology may be done.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 258, "End Page": 266, "Article Number": null, "DOI": "10.1039/c4ee02144d", "DOI Link": "http://dx.doi.org/10.1039/c4ee02144d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346563600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MJ; Guo, X; Ma, W; Ade, H; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Maojie; Guo, Xia; Ma, Wei; Ade, Harald; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Large-Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1045, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2015, "Volume": 27, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4655, "End Page": 4660, "Article Number": null, "DOI": "10.1002/adma.201502110", "DOI Link": "http://dx.doi.org/10.1002/adma.201502110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359911500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, HR; Wang, PF; Gong, Y; Zhang, JN; Yu, XQ; Gu, L; OuYang, CY; Yin, YX; Hu, EY; Yang, XQ; Stavitski, E; Guo, YG; Wan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Hu-Rong; Wang, Peng-Fei; Gong, Yue; Zhang, Jienull; Yu, Xiqian; Gu, Lin; OuYang, Chuying; Yin, Ya-Xia; Hu, Enyuan; Yang, Xiao-Qing; Stavitski, Eli; Guo, Yu-Guo; Wan, Li-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As promising high-capacity cathode materials for Na-ion batteries, O3-type Na-based metal oxides always suffer from their poor air stability originating from the spontaneous extraction of Na and oxidation of transition metals when exposed to air. Herein, a combined structure modulation is proposed to tackle concurrently the two handicaps via reducing Na layers spacing and simultaneously increasing valence state of transition Metals. Guided by density functional theory calculations, we demonstrate such a modulation can be subtly realized through cosubstitution of one kind of heteroatom with comparable electronegativity and another one with Substantially different Fermi level, by adjusting, the structure of nulli0.5Mn0.5O2 via Cu/Ti codoping. The as-obtained nulli0.45Cu0.05Mn0.4Ti0.1O2 exhibits an increase of 20 times in stable air-exposure period and 9 times in capacity retention after 500 cycles,. and even retains its structure and capacity after being soaked in water. Such a simple and effective structure modulation reveals a new avenue for high-performance O3-type cathodes and pushes the large-scale industrialization of Na-ion batteries a decisive step forward.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2017, "Volume": 139, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8440, "End Page": 8443, "Article Number": null, "DOI": "10.1021/jacs.7b05176", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b05176", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404809600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, JQ; Kong, LQ; Ji, YJ; White, J; Li, YY; Zhang, J; An, PF; Liu, SZ; Lee, ST; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Junqing; Kong, Lingqiao; Ji, Yujin; White, Jai; Li, Youyong; Zhang, Jing; An, Pengfei; Liu, Shengzhong; Lee, Shuit-Tong; Ma, Tianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single atom tungsten doped ultrathin α-Ni(OH)2 for enhanced electrocatalytic water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic water oxidation is a rate-determining step in the water splitting reaction. Here, we report one single atom W6+ doped Ni(OH)(2) nullosheet sample (w-Ni(OH)(2)) with an outstanding oxygen evolution reaction (OER) performance that is, in a 1 M KOH medium, an overpotential of 237 mV is obtained reaching a current density of 10 mA/cm(2). Moreover, at high current density of 80 mA/cm(2), the overpotential value is 267 mV. The corresponding Tafel slope is measured to be 33 mV/dec. The d(0) W6+ atom with a low spin-state has more outermost vacant orbitals, resulting in more water and OH- groups being adsorbed on the exposed W sites of the Ni(OH)(2) nullosheet. Density functional theory (DFT) calculations confirm that the O radical and O-O coupling are both generated at the same site of W6+. This work demonstrates that W6+ doping can promote the electrocatalytic water oxidation activity of Ni(OH)(2) with the highest performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2149, "DOI": "10.1038/s41467-019-09845-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09845-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467836900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JY; Li, JJ; Xiong, DH; Zhang, BS; Liu, YF; Wu, KH; Amorim, I; Li, W; Liu, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Junyuan; Li, Junjie; Xiong, Dehua; Zhang, Bingsen; Liu, Yuefeng; Wu, Kuang-Hsu; Amorim, Isilda; Li, Wei; Liu, Lifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trends in activity for the oxygen evolution reaction on transition metal (M = Fe, Co, Ni) phosphide precatalysts", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal phosphides (TMPs) have recently emerged as a new class of pre-catalysts that can efficiently catalyze the oxygen evolution reaction (OER). However, how the OER activity of TMPs varies with the catalyst composition has not been systematically explored. Here, we report the alkaline OER electrolysis of a series of nulloparticulate phosphides containing different equimolar metal (M = Fe, Co, Ni) components. Notable trends in OER activity are observed, following the order of FeP < NiP < CoP < FeNiP < FeCoP < CoNiP < FeCoNiP, which indicate that the introduction of a secondary metal(s) to a mono-metallic TMP substantially boosts the OER performance. We ascribe the promotional effect to the enhanced oxidizing power of bi-and tri-metallic TMPs that can facilitate the formation of MOH and chemical adsorption of OH- groups, which are the rate-limiting steps for these catalysts according to our Tafel analysis. Remarkably, the tri-metallic FeCoNiP pre-catalyst exhibits exceptionally high apparent and intrinsic OER activities, requiring only 200 mV to deliver 10 mA cm(-2) and showing a high turnover frequency (TOF) of >= 0.94 s(-1) at the overpotential of 350 mV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 492, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2018, "Volume": 9, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3470, "End Page": 3476, "Article Number": null, "DOI": "10.1039/c7sc05033j", "DOI Link": "http://dx.doi.org/10.1039/c7sc05033j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429203500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HJ; Chen, F; Li, XW; Huang, HW; Zhang, QY; Su, SQ; Wang, KY; Mao, EY; Mei, BT; Mul, GD; Ma, TY; Zhang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Hongjian; Chen, Fang; Li, Xiaowei; Huang, Hongwei; Zhang, Qiuyu; Su, Shaoqiang; Wang, Keyang; Mao, Enyang; Mei, Bastian; Mul, Guido; Ma, Tianyi; Zhang, Yihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergy of ferroelectric polarization and oxygen vacancy to promote CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-light driven CO2 reduction into value-added chemicals and fuels emerges as a significant approach for CO2 conversion. However, inefficient electron-hole separation and the complex multi-electrons transfer processes hamper the efficiency of CO2 photoreduction. Herein, we prepare ferroelectric Bi3TiNbO9 nullosheets and employ corona poling to strengthen their ferroelectric polarization to facilitate the bulk charge separation within Bi3TiNbO9 nullosheets. Furthermore, surface oxygen vacancies are introduced to extend the photo-absorption of the synthesized materials and also to promote the adsorption and activation of CO2 molecules on the catalysts' surface. More importantly, the oxygen vacancies exert a pinning effect on ferroelectric domains that enables Bi3TiNbO9 nullosheets to maintain superb ferroelectric polarization, tackling above-mentioned key challenges in photocatalytic CO2 reduction. This work highlights the importance of ferroelectric properties and controlled surface defect engineering, and emphasizes the key roles of tuning bulk and surface properties in enhancing the CO2 photoreduction performance. Solar-driven CO2 reduction into value-added chemicals and fuels is attracting worldwide attention. Here, substantially enhanced photocatalytic CO2 reduction activity is achieved via the synergy of surface oxygen vacancies and ferroelectric polarization over Bi3TiNbO9 photocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4594, "DOI": "10.1038/s41467-021-24882-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24882-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680876500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Song, JW; Zhao, XP; Yang, Z; Pastel, G; Xu, SM; Jia, C; Dai, JQ; Chen, CJ; Gong, A; Jiang, F; Yao, YG; Fan, TZ; Yang, B; Wågberg, L; Yang, RG; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tian; Song, Jianwei; Zhao, Xinpeng; Yang, Zhi; Pastel, Glenn; Xu, Shaomao; Jia, Chao; Dai, Jiaqi; Chen, Chaoji; Gong, Amy; Jiang, Feng; Yao, Yonggang; Fan, Tianzhu; Yang, Bao; Wagberg, Lars; Yang, Ronggui; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic, lightweight, strong, and super thermally insulating nullowood with naturally aligned nullocellulose", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been a growing interest in thermal management materials due to the prevailing energy challenges and unfulfilled needs for thermal insulation applications. We demonstrate the exceptional thermal management capabilities of a large-scale, hierarchal alignment of cellulose nullofibrils directly fabricated from wood, hereafter referred to as nullowood. nullowood exhibits anisotropic thermal properties with an extremely low thermal conductivity of 0.03 W/m.K in the transverse direction (perpendicular to the nullofibrils) and approximately two times higher thermal conductivity of 0.06 W/m.K in the axial direction due to the hierarchically aligned nullofibrils within the highly porous backbone. The anisotropy of the thermal conductivity enables efficient thermal dissipation along the axial direction, thereby preventing local overheating on the illuminated side while yielding improved thermal insulation along the backside that cannot be obtained with isotropic thermal insulators. The nullowood also shows a low emissivity of <5% over the solar spectrum with the ability to effectively reflect solar thermal energy. Moreover, the nullowood is lightweight yet strong, owing to the effective bonding between the aligned cellulose nullofibrils with a high compressive strength of 13 MPa in the axial direction and 20 MPa in the transverse direction at 75% strain, which exceeds other thermal insulation materials, such as silica and polymer aerogels, Styrofoam, and wool. The excellent thermal management, abundance, biodegradability, high mechanical strength, low mass density, and manufacturing scalability of the nullowood make this material highly attractive for practical thermal insulation applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar3724", "DOI": "10.1126/sciadv.aar3724", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar3724", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427892700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Volonakis, G; Filip, MR; Haghighirad, AA; Sakai, N; Wenger, B; Snaith, HJ; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Volonakis, George; Filip, Marina R.; Haghighirad, Amir Abbas; Sakai, Nobuya; Wenger, Bernard; Snaith, Henry J.; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-Free Halide Double Perovskites via Heterovalent Substitution of Noble Metals", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead-based halide perovskites are emerging as the most promising class of materials for next-generation optoelectronics; however, despite the enormous success of lead-halide perovskite solar cells, the issues of stability and toxicity are yet to be resolved. Here we report on the computational design and the experimental synthesis of a new family of Pb-free inorganic halide double perovskites based on bismuth or antimony and noble metals. Using first-principles calculations we show that this hitherto unknown family of perovskites exhibits very promising optoelectronic properties, such as tunable band gaps in the visible range and low carrier effective masses. Furthermore, we successfully synthesize the double perovskite Cs2BiAgCl6, perform structural refinement using single-crystal X-ray diffraction, and characterize its optical properties via optical absorption and photoluminescence measurements. This new perovskite belongs to the Fm (3) over barm space group and consists of BiCl6 and AgCl6 octahedra alternating in a rock-salt face-centered cubic structure. From UV-vis and photoluminescence measurements we obtain an indirect gap of 2.2 eV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 833, "Times Cited, All Databases": 874, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2016, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1254, "End Page": 1259, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b00376", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b00376", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373867600028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YP; Zuo, XQ; Guo, Y; Huang, H; Zhang, H; Wang, T; Wen, NX; Chen, H; Cong, TZ; Muhammad, J; Yang, X; Wang, XN; Fan, Z; Pan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yongpeng; Zuo, Xueqing; Guo, Yuan; Huang, Hui; Zhang, Hao; Wang, Ting; Wen, Ningxuan; Chen, Huan; Cong, Tianze; Muhammad, Javid; Yang, Xuan; Wang, Xinnull; Fan, Zeng; Pan, Lujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural Engineering of Hierarchical Aerogels Comprised of Multi-dimensional Gradient Carbon nulloarchitectures for Highly Efficient Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, multilevel structural carbon aerogels are deemed as attractive candidates for microwave absorbing materials. Nevertheless, excessive stack and agglomeration for low-dimension carbon nullomaterials inducing impedance mismatch are significant challenges. Herein, the delicate 3D helix-2D sheet-1D fiber-0D dot hierarchical aerogels have been successfully synthesized, for the first time, by sequential processes of hydrothermal self-assembly and in-situ chemical vapor deposition method. Particularly, the graphene sheets are uniformly intercalated by 3D helical carbon nullocoils, which give a feasible solution to the mentioned problem and endows the as-obtained aerogel with abundant porous structures and better dielectric properties. Moreover, by adjusting the content of 0D core-shell structured particles and the parameters for growth of the 1D carbon nullofibers, tunable electromagnetic properties and excellent impedance matching are achieved, which plays a vital role in the microwave absorption performance. As expected, the optimized aerogels harvest excellent performance, including broad effective bandwidth and strong reflection loss at low filling ratio and thin thickness. This work gives valuable guidance and inspiration for the design of hierarchical materials comprised of dimensional gradient structures, which holds great application potential for electromagnetic wave attenuation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144, "DOI": "10.1007/s40820-021-00667-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00667-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661923800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boutry, CM; Kaizawa, Y; Schroeder, BC; Chortos, A; Legrand, A; Wang, Z; Chang, J; Fox, P; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boutry, Clementine M.; Kaizawa, Yukitoshi; Schroeder, Bob C.; Chortos, Alex; Legrand, Anais; Wang, Zhen; Chang, James; Fox, Paige; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stretchable and biodegradable strain and pressure sensor for orthopaedic application", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to monitor, in real time, the mechanical forces on tendons after surgical repair could allow personalized rehabilitation programmes to be developed for recovering patients. However, the development of devices capable of such measurements has been hindered by the strict requirements of biocompatible materials and the need for sensors with satisfactory performance. Here we report an implantable pressure and strain sensor made entirely of biodegradable materials. The sensor is designed to degrade after its useful lifetime, eliminating the need for a second surgery to remove the device. It can measure strain and pressure independently using two vertically isolated sensors capable of discriminating strain as small as 0.4% and the pressure exerted by a grain of salt (12 Pa), without them interfering with one another. The device has minimal hysteresis, a response time in the millisecond range, and an excellent cycling stability for strain and pressure sensing, respectively. We have incorporated a biodegradable elastomer optimized to improve the strain cycling performances by 54%. An in vivo study shows that the sensor exhibits excellent biocompatibility and function in a rat model, illustrating the potential applicability of the device to the real-time monitoring of tendon healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 529, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 1, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 314, "End Page": 321, "Article Number": null, "DOI": "10.1038/s41928-018-0071-7", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0071-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444075900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, WT; Ma, C; Tan, S; Ma, MG; Wan, PB; Chen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Wentao; Ma, Chang; Tan, Shuo; Ma, Mingguo; Wan, Pengbo; Chen, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin and Flexible CNTs/MXene/Cellulose nullofibrils Composite Paper for Electromagnetic Interference Shielding", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the rapid development of portable and wearable devices, different electromagnetic interference (EMI) shielding materials with high efficiency have been desired to eliminate the resulting radiation pollution. However, limited EMI shielding materials are successfully used in practical applications, due to the heavy thickness and absence of sufficient strength or flexibility. Herein, an ultrathin and flexible carbon nullotubes/MXene/cellulose nullofibrils composite paper with gradient and sandwich structure is constructed for EMI shielding application via a facile alternating vacuum-assisted filtration process. The composite paper exhibits outstanding mechanical properties with a tensile strength of 97.9 +/- 5.0 MPa and a fracture strain of 4.6 +/- 0.2%. Particularly, the paper shows a high electrical conductivity of 2506.6 S m(-1) and EMI shielding effectiveness (EMI SE) of 38.4 dB due to the sandwich structure in improving EMI SE, and the gradient structure on regulating the contributions from reflection and absorption. This strategy is of great significance in fabricating ultrathin and flexible composite paper for highly efficient EMI shielding performance and in broadening the practical applications of MXene-based composite materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2019, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 72, "DOI": "10.1007/s40820-019-0304-y", "DOI Link": "http://dx.doi.org/10.1007/s40820-019-0304-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000484940600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Florez, M; Guerra-Rodríguez, E; Cazón, P; Vázquez, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Florez, Maria; Guerra-Rodriguez, Esther; Cazon, Patricia; Vazquez, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chitosan for food packaging: Recent advances in active and intelligent films", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The massive and uncontrolled use of food packaging derived from petroleum-based plastics has created a serious environmental problem. Hence, the food packaging industry needs to develop packaging from biodegradable polymers. Among the many raw materials studied in the literature, chitosan is one of the most abundant polysaccharides in the nature. Chitosan has attracted attention due to its non-toxicity, antimicrobial, and antifungal properties. Because of this, chitosan is considered a perfect material for the development of films for food use. In this review, recent studies on active and/or intelligent chitosan-based films has been evaluated. Active packaging maintains or improves the condition of packaged food or extends its shelf-life meanwhile intelligent packaging monitors the condition of packaged food or the environment surrounding the food. The effect of the addition of active compounds on the mechanical, barrier and functional properties of chitosan-based films has been assessed. The antimicrobial and antioxidant activity, as well as the potential application of these active and intelligent composite films have also been revised. Literature shows that the presence of phenolic compounds improves both mechanical and barrier properties of chitosan films. The antimicrobial and antioxidant capacity of the films improved significantly by the addition of essential oils, phenolic compounds, and other fruit extracts. Intelligent pH-indicator chitosan-based films have been extensively studied. Further research on chitosan and its combinations with other materials is needed to study which type of foodstuffs could be in contact with chitosan packaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 124, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107328, "DOI": "10.1016/j.foodhyd.2021.107328", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2021.107328", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719793800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, R; Chen, X; Shen, X; Zhang, XQ; Chen, XR; Cheng, XB; Yan, C; Zhao, CZ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Rui; Chen, Xiang; Shen, Xin; Zhang, Xue-Qiang; Chen, Xiao-Ru; Cheng, Xin-Bing; Yan, Chong; Zhao, Chen-Zi; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is among the most promising anode materials in next-generation energy-storage systems. However, Li dendrite growth and unstable solid electrolyte interphase have hindered its practical applications. Structured current collectors have been widely proposed to settle these issues, whereas the prefilling of Li metal into structured anode is challenging. We proposed a coralloid silver-coated carbon fiber-based composite Li anode (CF/Ag-Li) through Ag electroplating and molten Li infusion. The molten Li can be infused into the carbon fiber framework due to the lithiophilic nature of Ag. In addition, a dendrite-free morphology and extraordinary electrochemical performance are achieved in Li-LiFePO4 and Li-sulfur cells. The CF/Ag-LilLi symmetrical cells can cycle for 160 cycles at 10.0 mA cm(-2) and 10.0 mAh cm(-2). The CF/Ag-LiIS cells exhibited a high initial discharge capacity of 785 mAh g(-1) and a large capacity retention rate after 400 cycles at 0.5C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 664, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 764, "End Page": 777, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435091900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, XL; Chen, BH; Wang, LP; Sun, YX; Jin, Z; Liu, XY; Ouyang, LP; Liao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Xiaoling; Chen, Baohui; Wang, Luping; Sun, Yingxiao; Jin, Zhao; Liu, Xuanyong; Ouyang, Liping; Liao, Yun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chitosan@Puerarin hydrogel for accelerated wound healing in diabetic subjects by miR-29ab1 mediated inflammatory axis suppression", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wound healing is one of the major global health concerns in patients with diabetes. Overactivation of proinflammatory M1 macrophages is associated with delayed wound healing in diabetes. miR-29ab1 plays a critical role in diabetes-related macrophage inflammation. Hence, inhibition of inflammation and regulation of miR-29 expression have been implicated as new points for skin wound healing. In this study, the traditional Chinese medicine, puerarin, was introduced to construct an injectable and self-healing chitosan@puerarin (C@P) hydrogel. The C@P hydrogel promoted diabetic wound healing and accelerated angiogenesis, which were related to the inhibition of the miR-29 mediated inflammation response. Compared to healthy subjects, miR-29a and miR-29b1 were ectopically increased in the skin wound of the diabetic model, accompanied by upregulated M1-polarization, and elevated levels of IL-1 beta and TNF-alpha. Further evaluations by miR-29ab1 knockout mice exhibited superior wound healing and attenuated inflammation. The present results suggested that miR-29ab1 is essential for diabetic wound healing by regulating the inflammatory response. Suppression of miR-29ab1 by the C@P hydrogel has the potential for improving medical approaches for wound repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 653, "End Page": 665, "Article Number": null, "DOI": "10.1016/j.bioactmat.2024.04.032", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2024.04.032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800039200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Chi, ZG; Chong, KC; Batsanov, AS; Yang, Z; Mao, Z; Yang, ZY; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chengjian; Chi, Zhenguo; Chong, Kok Chan; Batsanov, Andrei S.; Yang, Zhan; Mao, Zhu; Yang, Zhiyong; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbazole isomers induce ultralong organic phosphorescence", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Commercial carbazole has been widely used to synthesize organic functional materials A carbazole isomer, typically present as an impurity in commercially produced carbazole batches, is shown to be responsible for the ultralong phosphorescence observed in these compounds and their derivatives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 175, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-0797-2", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-0797-2", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571692500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kosco, J; Bidwell, M; Cha, H; Martin, T; Howells, CT; Sachs, M; Anjum, DH; Gonzalez Lopez, S; Zou, LY; Wadsworth, A; Zhang, WM; Zhang, LS; Tellam, J; Sougrat, R; Laquai, F; DeLongchamp, DM; Durrant, JR; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kosco, Jan; Bidwell, Matthew; Cha, Hyojung; Martin, Tyler; Howells, Calvyn T.; Sachs, Michael; Anjum, Dalaver H.; Gonzalez Lopez, Sandra; Zou, Lingyu; Wadsworth, Andrew; Zhang, Weimin; Zhang, Lisheng; Tellam, James; Sougrat, Rachid; Laquai, Frederic; DeLongchamp, Dean M.; Durrant, James R.; McCulloch, Iain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic hydrogen evolution from organic semiconductor heterojunction nulloparticles", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalysts formed from a single organic semiconductor can suffer from inefficient charge generation leading to low photocatalytic activities. Incorporating a heterojunction between a donor polymer and non-fullerene acceptor in organic nulloparticles leads to enhanced photocatalytic hydrogen evolution. Photocatalysts formed from a single organic semiconductor typically suffer from inefficient intrinsic charge generation, which leads to low photocatalytic activities. We demonstrate that incorporating a heterojunction between a donor polymer (PTB7-Th) and non-fullerene acceptor (EH-IDTBR) in organic nulloparticles (NPs) can result in hydrogen evolution photocatalysts with greatly enhanced photocatalytic activity. Control of the nullomorphology of these NPs was achieved by varying the stabilizing surfactant employed during NP fabrication, converting it from a core-shell structure to an intermixed donor/acceptor blend and increasing H-2 evolution by an order of magnitude. The resulting photocatalysts display an unprecedentedly high H-2 evolution rate of over 60,000 mu mol h(-1) g(-1) under 350 to 800 nm illumination, and external quantum efficiencies over 6% in the region of maximum solar photon flux.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 19, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 559, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-019-0591-1", "DOI Link": "http://dx.doi.org/10.1038/s41563-019-0591-1", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510823100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Siqueira, G; Kokkinis, D; Libanori, R; Hausmann, MK; Gladman, AS; Neels, A; Tingaut, P; Zimmermann, T; Lewis, JA; Studart, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Siqueira, Gilberto; Kokkinis, Dimitri; Libanori, Rafael; Hausmann, Michael K.; Gladman, Amelia Sydney; Neels, Antonia; Tingaut, Philippe; Zimmermann, Tanja; Lewis, Jennifer A.; Studart, Andre R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cellulose nullocrystal Inks for 3D Printing of Textured Cellular Architectures", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D printing of renewable building blocks like cellulose nullocrystals offers an attractive pathway for fabricating sustainable structures. Here, viscoelastic inks composed of anisotropic cellulose nullocrystals (CNC) that enable patterning of 3D objects by direct ink writing are designed and formulated. These concentrated inks are composed of CNC particles suspended in either water or a photopolymerizable monomer solution. The shear-induced alignment of these anisotropic building blocks during printing is quantified by atomic force microscopy, polarized light microscopy, and 2D wide-angle X-ray scattering measurements. Akin to the microreinforcing effect in plant cell walls, the alignment of CNC particles during direct writing yields textured composites with enhanced stiffness along the printing direction. The observations serve as an important step forward toward the development of sustainable materials for 3D printing of cellular architectures with tailored mechanical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 465, "Times Cited, All Databases": 505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2017, "Volume": 27, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604619, "DOI": "10.1002/adfm.201604619", "DOI Link": "http://dx.doi.org/10.1002/adfm.201604619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397349400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, ZY; Zhang, J; Gong, ZH; Lei, H; Zhou, D; Zhang, NA; Mai, WJ; Zhao, SJ; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Zuyun; Zhang, Jun; Gong, Zhiheng; Lei, Hang; Zhou, Deng; Zhang, Nian; Mai, Wenjie; Zhao, Shijun; Chen, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxides or (oxy)hydroxides have been intensively investigated as promising electrocatalysts for energy and environmental applications. Oxygen in the lattice was reported recently to actively participate in surface reactions. Herein, we report a sacrificial template-directed approach to synthesize Mo-doped NiFe (oxy)hydroxide with modulated oxygen activity as an enhanced electrocatalyst towards oxygen evolution reaction (OER). The obtained MoNiFe (oxy)hydroxide displays a high mass activity of 1910 A/g(metal) at the overpotential of 300 mV. The combination of density functional theory calculations and advanced spectroscopy techniques suggests that the Mo dopant upshifts the O 2p band and weakens the metal-oxygen bond of NiFe (oxy)hydroxide, facilitating oxygen vacancy formation and shifting the reaction pathway for OER. Our results provide critical insights into the role of lattice oxygen in determining the activity of (oxy)hydroxides and demonstrate tuning oxygen activity as a promising approach for constructing highly active electrocatalysts. While (oxy)hydroxides are effective oxygen evolution electrocatalysts, the impacts of pre-catalyst properties on catalyst activities are challenging to assess. Here, authors find Mo dopants in Ni-Fe (oxyhydroxides) to promote lattice oxygen participation and to boost oxygen evolution activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2191, "DOI": "10.1038/s41467-022-29875-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29875-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785003900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kanik, M; Orguc, S; Varnavides, G; Kim, J; Benavides, T; Gonzalez, D; Akintilo, T; Tasan, CC; Chandrakasan, AP; Fink, Y; Anikeeva, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kanik, Mehmet; Orguc, Sirma; Varnavides, Georgios; Kim, Jinwoo; Benavides, Thomas; Gonzalez, Dani; Akintilo, Timothy; Tasan, C. Cem; Chandrakasan, Anulltha P.; Fink, Yoel; Anikeeva, Polina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain-programmable fiber-based artificial muscle", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial muscles may accelerate the development of robotics, haptics, and prosthetics. Although advances in polymer-based actuators have delivered unprecedented strengths, producing these devices at scale with tunable dimensions remains a challenge. We applied a high-throughput iterative fiber-drawing technique to create strain-programmable artificial muscles with dimensions spanning three orders of magnitude. These fiber-based actuators are thermally and optically controllable, can lift more than 650 times their own weight, and withstand strains of >1000%. Integration of conductive nullowire meshes within these fiber-based muscles offers piezoresistive strain feedback and demonstrates long-term resilience across >10(5) deformation cycles. The scalable dimensions of these fiber-based actuators and their strength and responsiveness may extend their impact from engineering fields to biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 350, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2019, "Volume": 365, "Issue": 6449, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 145, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw2502", "DOI Link": "http://dx.doi.org/10.1126/science.aaw2502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474905400038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, JB; Yang, YM; Hong, ZR; Song, TB; Meng, L; Liu, YS; Jiang, CY; Zhou, HP; Chang, WH; Li, G; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Jingbi; Yang, (Michael) Yang; Hong, Ziruo; Song, Tze-Bin; Meng, Lei; Liu, Yongsheng; Jiang, Chengyang; Zhou, Huanping; Chang, Wei-Hsuan; Li, Gang; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Moisture assisted perovskite film growth for high performance solar cells", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moisture is assumed to be detrimental to organometal trihalide perovskite, as excess water can damage the crystallinity of the perovskite structure. Here, we report a growth mode for via thermal annealing of the perovskite precursor film in a humid environment (e. g., ambient air) to greatly improve the film quality, grain size, carrier mobility, and lifetime. Our method produces devices with maximum power conversion efficiency of 17.1% and a fill factor of 80%, revealing a promising route to achieve high quality perovskite polycrystalline films with superior optoelectronic properties that can pave the way towards efficient photovoltaic conversion. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 750, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 3", "Publication Year": 2014, "Volume": 105, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 183902, "DOI": "10.1063/1.4901510", "DOI Link": "http://dx.doi.org/10.1063/1.4901510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345000000085", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burke, DW; Sun, C; Castano, I; Flanders, NC; Evans, AM; Vitaku, E; McLeod, DC; Lambeth, RH; Chen, LX; Gianneschi, NC; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burke, David W.; Sun, Chao; Castano, Ioannina; Flanders, Nathan C.; Evans, Austin M.; Vitaku, Edon; McLeod, David C.; Lambeth, Robert H.; Chen, Lin X.; Gianneschi, Nathan C.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acid Exfoliation of Imine-linked Covalent Organic Frameworks Enables Solution Processing into Crystalline Thin Films", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are highly modular porous crystalline polymers that are of interest for applications such as charge-storage devices, nullofiltration membranes, and optoelectronic devices. COFs are typically synthesized as microcrystalline powders, which limits their performance in these applications, and their limited solubility precludes large-scale processing into more useful morphologies and devices. We report a general, scalable method to exfoliate two-dimensional imine-linked COF powders by temporarily protonating their linkages. The resulting suspensions were cast into continuous crystalline COF films up to 10 cm in diameter, with thicknesses ranging from 50 nm to 20 mu m depending on the suspension composition, concentration, and casting protocol. Furthermore, we demonstrate that the film fabrication process proceeds through a partial depolymerization/repolymerization mechanism, providing mechanically robust films that can be easily separated from their substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 59, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5165, "End Page": 5171, "Article Number": null, "DOI": "10.1002/anie.201913975", "DOI Link": "http://dx.doi.org/10.1002/anie.201913975", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512808300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jayaramulu, K; Horn, M; Schneemann, A; Saini, H; Bakandritsos, A; Ranc, V; Petr, M; Stavila, V; Narayana, C; Scheibe, B; Kment, S; Otyepka, M; Motta, N; Dubal, D; Zboril, R; Fischer, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jayaramulu, Kolleboyina; Horn, Michael; Schneemann, Andreas; Saini, Haneesh; Bakandritsos, Aristides; Ranc, Vaclav; Petr, Martin; Stavila, Vitalie; Narayana, Chandrabhas; Scheibe, Blazej; Kment, Stepan; Otyepka, Michal; Motta, Nunzio; Dubal, Deepak; Zboril, Radek; Fischer, Roland A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent Graphene-MOF Hybrids for High-Performance Asymmetric Supercapacitors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, the covalent attachment of an amine functionalized metal-organic framework (UiO-66-NH2 = Zr6O4(OH)(4)(bdc-NH2)(6); bdc-NH2 = 2-amino-1,4-benzenedicarboxylate) (UiO-Universitetet i Oslo) to the basal-plane of carboxylate functionalized graphene (graphene acid = GA) via amide bonds is reported. The resultant GA@UiO-66-NH2 hybrid displayed a large specific surface area, hierarchical pores and an interconnected conductive network. The electrochemical characterizations demonstrated that the hybrid GA@UiO-66-NH2 acts as an effective charge storing material with a capacitance of up to 651 F g(-1), significantly higher than traditional graphene-based materials. The results suggest that the amide linkage plays a key role in the formation of a p-conjugated structure, which facilitates charge transfer and consequently offers good capacitance and cycling stability. Furthermore, to realize the practical feasibility, an asymmetric supercapacitor using a GA@UiO-66-NH2 positive electrode with Ti3C2TX MXene as the opposing electrode has been constructed. The cell is able to deliver a power density of up to 16 kW kg(-1) and an energy density of up to 73 Wh kg(-1), which are comparable to several commercial devices such as Pb-acid and Ni/MH batteries. Under an intermediate level of loading, the device retained 88% of its initial capacitance after 10 000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 33, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004560, "DOI": "10.1002/adma.202004560", "DOI Link": "http://dx.doi.org/10.1002/adma.202004560", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596065400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hinton, TJ; Jallerat, Q; Palchesko, RN; Park, JH; Grodzicki, MS; Shue, HJ; Ramadan, MH; Hudson, AR; Feinberg, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hinton, Thomas J.; Jallerat, Quentin; Palchesko, Rachelle N.; Park, Joon Hyung; Grodzicki, Martin S.; Shue, Hao-Jan; Ramadan, Mohamed H.; Hudson, Andrew R.; Feinberg, Adam W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional printing of complex biological structures by freeform reversible embedding of suspended hydrogels", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate the additive manufacturing of complex three-dimensional (3D) biological structures using soft protein and polysaccharide hydrogels that are challenging or impossible to create using traditional fabrication approaches. These structures are built by embedding the printed hydrogel within a secondary hydrogel that serves as a temporary, thermoreversible, and biocompatible support. This process, termed freeform reversible embedding of suspended hydrogels, enables 3D printing of hydrated materials with an elastic modulus <500 kPa including alginate, collagen, and fibrin. Computer-aided design models of 3D optical, computed tomography, and magnetic resonullce imaging data were 3D printed at a resolution of similar to 200 mm and at low cost by leveraging open-source hardware and software tools. Proof-of-concept structures based on femurs, branched coronary arteries, trabeculated embryonic hearts, and human brains were mechanically robust and recreated complex 3D internal and external anatomical architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1275, "Times Cited, All Databases": 1521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 1, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/sciadv.1500758", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216598200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Read, N; Wang, W; Essa, K; Attallah, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Read, Noriko; Wang, Wei; Essa, Khamis; Attallah, Moataz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective laser melting of AlSi10Mg alloy: Process optimisation and mechanical properties development", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The influence of selective laser melting (SLM) process parameters (laser power, scan speed, scan spacing, and island size using a Concept Laser M2 system) on the porosity development in AlSi10Mg alloy builds has been investigated, using statistical design of experimental approach, correlated with the energy density model. A two-factor interaction model showed that the laser power, scan speed, and the interaction between the scan speed and scan spacing have the major influence on the porosity development in the builds. By driving the statistical method to minimise the porosity fraction, optimum process parameters were obtained. The optimum build parameters were validated, and subsequently used to build rodshaped samples to assess the room temperature and high temperature (creep) mechanical properties. The samples produced using SLM showed better strength and elongation properties, compared to die cast Al-alloys of similar composition. Creep results showed better rupture life than cast alloy, with a good agreement with the Larson-Miller literature data for this alloy composition. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 932, "Times Cited, All Databases": 1016, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 65, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 417, "End Page": 424, "Article Number": null, "DOI": "10.1016/j.matdes.2014.09.044", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2014.09.044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345520000051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin Imran, A; Esaki, K; Gotoh, H; Seki, T; Ito, K; Sakai, Y; Takeoka, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin Imran, Abu; Esaki, Kenta; Gotoh, Hiroaki; Seki, Takahiro; Ito, Kohzo; Sakai, Yasuhiro; Takeoka, Yukikazu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely stretchable thermosensitive hydrogels by introducing slide-ring polyrotaxane cross-linkers and ionic groups into the polymer network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stimuli-sensitive hydrogels changing their volumes and shapes in response to various stimulations have potential applications in multiple fields. However, these hydrogels have not yet been commercialized due to some problems that need to be overcome. One of the most significant problems is that conventional stimuli-sensitive hydrogels are usually brittle. Here we prepare extremely stretchable thermosensitive hydrogels with good toughness by using polyrotaxane derivatives composed of alpha-cyclodextrin and polyethylene glycol as cross-linkers and introducing ionic groups into the polymer network. The ionic groups help the polyrotaxane cross-linkers to become well extended in the polymer network. The resulting hydrogels are surprisingly stretchable and tough because the cross-linked alpha-cyclodextrin molecules can move along the polyethylene glycol chains. In addition, the polyrotaxane cross-linkers can be used with a variety of vinyl monomers; the mechanical properties of the wide variety of polymer gels can be improved by using these cross-linkers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5124, "DOI": "10.1038/ncomms6124", "DOI Link": "http://dx.doi.org/10.1038/ncomms6124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343980100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hinuma, Y; Grüneis, A; Kresse, G; Oba, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hinuma, Yoyo; Grueneis, Andreas; Kresse, Georg; Oba, Fumiyasu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band alignment of semiconductors from density-functional theory and many-body perturbation theory", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The band lineup, or alignment, of semiconductors is investigated via first-principles calculations based on density functional theory (DFT) and many-body perturbation theory (MBPT). Twenty-one semiconductors including C, Si, and Ge in the diamond structure, BN, AlP, AlAs, AlSb, GaP, GaAs, GaSb, InP, InAs, InSb, ZnS, ZnSe, ZnTe, CdS, CdSe, and CdTe in the zinc-blende structure, and GaN and ZnO in the wurtzite structure are considered in view of their fundamental and technological importance. Band alignments are determined using the valence and conduction band offsets from heterointerface calculations, the ionization potential (IP) and electron affinity (EA) from surface calculations, and the valence band maximum and conduction band minimum relative to the branch point energy, or charge neutrality level, from bulk calculations. The performance of various approximations to DFT and MBPT, namely the Perdew-Burke-Ernzerhof (PBE) semilocal functional, the Heyd-Scuseria-Ernzerhof (HSE) hybrid functional, and the GW approximation with and without vertex corrections in the screened Coulomb interaction, is assessed using the GW Gamma 1 approximation as a reference, where first-order vertex corrections are included in the self-energy. The experimental IPs, EAs, and band offsets are well reproduced by GW Gamma 1 for most of the semiconductor surfaces and heterointerfaces considered in this study. The PBE and HSE functionals show sizable errors in the IPs and EAs, in particular for group II-VI semiconductors with wide band gaps, but are much better in the prediction of relative band positions or band offsets due to error cancellation. The performance of the GW approximation is almost on par with GW Gamma 1 as far as relative band positions are concerned. The band alignments based on average interfacial band offsets for all pairs of 17 semiconductors and branch point energies agree with explicitly calculated interfacial band offsets with small mean absolute errors of both similar to 0.1 eV, indicating a good overall transitivity of the band offsets. The alignment based on IPs from selected nonpolar surfaces performs comparably well in the prediction of band offsets at most of the considered interfaces. The maximum errors are, however, as large as 0.3, 0.4, and 0.7 eV for the alignments based on the average band offsets, branch point energies, and IPs, respectively. This margin of error should be taken into account when performing materials screening using these alignments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2014, "Volume": 90, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 155405, "DOI": "10.1103/PhysRevB.90.155405", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.155405", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344013700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, HL; Zhang, T; Li, N; Cong, HP; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Haili; Zhang, Tan; Li, Na; Cong, Huai-Ping; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic and self-healing hydrogels with multi-responsive actuating capability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by smart biological tissues, artificial muscle-like actuators offer fascinating prospects due to their distinctive shape transformation and self-healing function under external stimuli. However, further practical application is hindered by the lack of simple and general routes to fabricate ingenious soft materials with anisotropic responsiveness. Here, we describe a general in situ polymerization strategy for the fabrication of anisotropic hydrogels composed of highly-ordered lamellar network crosslinked by the metal nullostructure assemblies, accompanied with remarkably anisotropic performances on mechanical, optical, de-swelling and swelling behaviors. Owing to the dynamic thiolate-metal coordination as healing motifs, the composites exhibit rapid and efficient multi-responsive self-healing performance under NIR irradiation and low pH condition. Dependent on well-defined anisotropic structures, the hydrogel presents controllable solvent-responsive mechanical actuating performance. Impressively, the integrated device through a healing-induced assembly way can deliver more complicated, elaborate forms of actuation, demonstrating its great potentials as superior soft actuators like smart robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202, "DOI": "10.1038/s41467-019-10243-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10243-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468174600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, W; Li, NW; Zhang, XL; Zhao, SY; Cao, R; Yin, YY; Xing, Y; Wang, JN; Guo, YG; Li, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Wei; Li, Nian-Wu; Zhang, Xiuling; Zhao, Shuyu; Cao, Ran; Yin, Yingying; Xing, Yi; Wang, Jiaona; Guo, Yu-Guo; Li, Congju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Dual-Salt Gel Polymer Electrolyte with 3D Cross-Linked Polymer Network for Dendrite-Free Lithium Metal Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries show great potential in energy storage because of their high energy density. Nevertheless, building a stable solid electrolyte interphase (SEI) and restraining the dendrite growth are difficult to realize with traditional liquid electrolytes. Solid and gel electrolytes are considered promising candidates to restrain the dendrites growth, while they are still limited by low ionic conductivity and incompatible interphases. Herein, a dual-salt (LiTFSI-LiPF6) gel polymer electrolyte (GPE) with 3D cross-linked polymer network is designed to address these issues. By introducing a dual salt in 3D structure fabricated using an in situ polymerization method, the 3D-GPE exhibits a high ionic conductivity (0.56 mS cm(-1) at room temperature) and builds a robust and conductive SEI on the lithium metal surface. Consequently, the Li metal batteries using 3D-GPE can markedly reduce the dendrite growth and achieve 87.93% capacity retention after cycling for 300 cycles. This work demonstrates a promising method to design electrolytes for lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800559, "DOI": "10.1002/advs.201800559", "DOI Link": "http://dx.doi.org/10.1002/advs.201800559", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444940600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YX; Liu, YC; Xu, Z; Ye, HC; Yang, Z; You, JX; Liu, M; He, YH; Kanatzidis, MG; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yunxia; Liu, Yucheng; Xu, Zhuo; Ye, Haochen; Yang, Zhou; You, Jiaxue; Liu, Ming; He, Yihui; Kanatzidis, Mercouri G.; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nucleation-controlled growth of superior lead-free perovskite Cs3Bi2I9 single-crystals for high-performance X-ray detection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The organic-inorganic hybrid lead halide perovskites have emerged as a series of star materials for solar cells, lasers and detectors. However, the issues raised by the toxic lead element and marginal stability due to the volatile organic components have severely limited their potential applications. In this work, we develop a nucleation-controlled solution method to grow large size high-quality Cs3Bi2I9 perovskite single crystals (PSCs). Using the technique, we harvest some centimeter-sized single crystals and achieved high device performance. We find that X-ray detectors based on PSCs exhibit high sensitivity of 1652.3 mu CGy(air)(-1)cm(-2) and very low detectable dose rate of 130nGy(air)s(-1), both desired in medical diagnostics. In addition, its outstanding thermal stability inspires us to develop a high temperature X-ray detector with stable response at up to 100 degrees C. Furthermore, PSCs exhibit high X-ray imaging capability thanks to its negligible signal drifting and extremely high stability. Organic-inorganic hybrid halide perovskites have been emerged as promising candidates for X-ray detectors while toxicity and instability are known issues. Here, Zhang et al. grow large size lead-free single crystals for high performance X-ray detection and imaging devices that can operate at 100 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16034-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16034-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533936800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Narita, A; Feng, XL; Hernulldez, Y; Jensen, SA; Bonn, M; Yang, HF; Verzhbitskiy, IA; Casiraghi, C; Hansen, MR; Koch, AHR; Fytas, G; Ivasenko, O; Li, B; Mali, KS; Balandina, T; Mahesh, S; De Feyter, S; Müllen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Narita, Akimitsu; Feng, Xinliang; Hernulldez, Yenny; Jensen, Soren A.; Bonn, Mischa; Yang, Huafeng; Verzhbitskiy, Ivan A.; Casiraghi, Cinzia; Hansen, Michael Ryan; Koch, Amelie H. R.; Fytas, George; Ivasenko, Oleksandr; Li, Bing; Mali, Kunal S.; Balandina, Tatyana; Mahesh, Sankarapillai; De Feyter, Steven; Muellen, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of structurally well-defined and liquid-phase-processable graphene nulloribbons", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The properties of graphene nulloribbons (GNRs) make them good candidates for next-generation electronic materials. Whereas 'top-down' methods, such as the lithographical patterning of graphene and the unzipping of carbon nullotubes, give mixtures of different GNRs, structurally well-defined GNRs can be made using a 'bottom-up' organic synthesis approach through solution-mediated or surface-assisted cyclodehydrogenation reactions. Specifically, non-planar polyphenylene precursors were first 'built up' from small molecules, and then 'graphitized' and 'planarized' to yield GNRs. However, fabrication of processable and longitudinally well-extended GNRs has remained a major challenge. Here we report a bottom-up solution synthesis of long (> 200 nm) liquid-phase-processable GNRs with a well-defined structure and a large optical bandgap of 1.88 eV. Self-assembled monolayers of GNRs can be observed by scanning probe microscopy, and non-contact time-resolved terahertz conductivity measurements reveal excellent charge-carrier mobility within individual GNRs. Such structurally well-defined GNRs may prove useful for fundamental studies of graphene nullostructures, as well as the development of GNR-based nulloelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 126, "End Page": 132, "Article Number": null, "DOI": "10.1038/NCHEM.1819", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.1819", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330187300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jing, HP; Wang, CC; Zhang, YW; Wang, P; Li, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jing, Huan-Ping; Wang, Chong-Chen; Zhang, Yi-Wen; Wang, Peng; Li, Ran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic degradation of methylene blue in ZIF-8", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs), a new class of porous crystalline materials, have attracted great interest as a promising candidate for sustainable energy and environmental remediation. In this study, ZIF-8, a versatile MOF based on imidazolate ligands, was selected as a photocatalyst to decompose methylene blue (MB) under UV light irradiation. The influence factors, kinetics, and mechanism of photocatalytic MB degradation and stability of ZIF-8, were also studied. The results revealed that the ZIF-8 photocatalyst exhibited efficiently photocatalytic activity for MB degradation under UV irradiation, which was confirmed through the detection of hydroxyl radicals ((OH)-O-center dot) by a fluorescence method. The MB degradation over the ZIF-8 photocatalyst followed a pseudo-first-order kinetics model. ZIF-8 worked effectively over a wide pH range from 4.0 to 12.0, and showed both high adsorption capacity and degradation efficiency for MB in a strong alkaline environment. The enhanced efficiency in a strong alkaline environment resulted from the higher charged ZIF-8 (pH > pH(pzc)) and the elevated yield of (OH)-O-center dot facilitated by increased OH- concentration. The possible pathway of photocatalytic degradation of MB in ZIF-8 was proposed. The results indicated that ZIF-8 can be used as a highly efficient photocatalyst to decompose organic pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 4, "Issue": 97, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 54454, "End Page": 54462, "Article Number": null, "DOI": "10.1039/c4ra08820d", "DOI Link": "http://dx.doi.org/10.1039/c4ra08820d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344600400039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, H; Lin, Y; Wu, H; Zhang, WH; Sun, ZH; Cheng, H; Liu, W; Wang, CL; Li, JJ; Huang, XH; Yao, T; Yang, JL; Wei, SQ; Lu, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Huan; Lin, Yue; Wu, Hong; Zhang, Wenhua; Sun, Zhihu; Cheng, Hao; Liu, Wei; Wang, Chunlei; Li, Junjie; Huang, Xiaohui; Yao, Tao; Yang, Jinlong; Wei, Shiqiang; Lu, Junling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bottom-up precise synthesis of stable platinum dimers on graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supported metal clusters containing only a few atoms are of great interest. Progress has been made in synthesis of metal single-atom catalysts. However, precise synthesis of metal dimers on high-surface area support remains a grand challenge. Here, we show that Pt-2 dimers can be fabricated with a bottom-up approach on graphene using atomic layer deposition, through proper nucleation sites creation, Pt-1 single-atom deposition and attaching a secondary Pt atom selectively on the preliminary one. Scanning transmission electron microscopy, x-ray absorption spectroscopy, and theoretical calculations suggest that the Pt-2 dimers are likely in the oxidized form of Pt2Ox. In hydrolytic dehydrogenation of ammonia borane, Pt-2 dimers exhibit a high specific rate of 2800 mol(H2) mol(Pt)(-1) min(-1) at room temperature, similar to 17- and 45-fold higher than graphene supported Pt single atoms and nulloparticles, respectively. These findings open an avenue to bottom-up fabrication of supported atomically precise ultrafine metal clusters for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 530, "Times Cited, All Databases": 563, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1070, "DOI": "10.1038/s41467-017-01259-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01259-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413353500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goh, GD; Dikshit, V; Nagalingam, AP; Goh, GL; Agarwala, S; Sing, SL; Wei, J; Yeong, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goh, G. D.; Dikshit, V.; Nagalingam, A. P.; Goh, G. L.; Agarwala, S.; Sing, S. L.; Wei, J.; Yeong, W. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of mechanical properties and fracture mode of additively manufactured carbon fiber and glass fiber reinforced thermoplastics", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous fiber-reinforced polymer (FRP) composites have been used for many applications to create strong yet lightweight products due to their high strength-to-weight and stiffness-to-weight ratios. Aerospace [1], automotive [2], and sport [3] industries are three of the few industries that have been using FRP composites. The increasing need for prototyping and customization of fiber reinforced polymer composite parts is prompting innovations in new manufacturing processes to realize short manufacturing cycle time and low production cost, which is challenging to accomplish using conventional molding process. Fused filament fabrication (FFF) - a material extrusion additive manufacturing (AM) technique trademarked as fused deposition modelling (FDM) by Stratasys-holds promise to achieve low-cost production on continuous fiber-reinforced thermoplastic (FRTP) composites. In this paper, the FFF technique is employed to fabricate continuous carbon and glass FRTP composites and its microstructural characteristics and the resulting tensile, flexural, and quasi-static indentation characteristics of the printed composites are examined. Additionally, the fracture behavior of each test sample is evaluated and discussed in detail. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 79, "End Page": 89, "Article Number": null, "DOI": "10.1016/j.matdes.2017.10.021", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2017.10.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414669500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuang, Y; Kenney, MJ; Meng, YT; Hung, WH; Liu, YJ; Huang, JE; Prasanna, R; Li, PS; Li, YP; Wang, L; Lin, MC; McGehee, MD; Sun, XM; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuang, Yun; Kenney, Michael J.; Meng, Yongtao; Hung, Wei-Hsuan; Liu, Yijin; Huang, Jianull Erick; Prasanna, Rohit; Li, Pengsong; Li, Yaping; Wang, Lei; Lin, Meng-Chang; McGehee, Michael D.; Sun, Xiaoming; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolysis of water to generate hydrogen fuel is an attractive renewable energy storage technology. However, grid-scale freshwater electrolysis would put a heavy strain on vital water resources. Developing cheap electrocatalysts and electrodes that can sustain seawater splitting without chloride corrosion could address the water scarcity issue. Here we present a multilayer anode consisting of a nickel-iron hydroxide (NiFe) electrocatalyst layer uniformly coated on a nickel sulfide (NiSx) layer formed on porous Ni foam (NiFe/NiSx-Ni), affording superior catalytic activity and corrosion resistance in solar-driven alkaline seawater electrolysis operating at industrially required current densities (0.4 to 1 A/cm(2)) over 1,000 h. A continuous, highly oxygen evolution reaction-active NiFe electrocatalyst layer drawing anodic currents toward water oxidation and an in situ-generated polyatomic sulfate and carbonate-rich passivating layers formed in the anode are responsible for chloride repelling and superior corrosion resistance of the salty-water-splitting anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 686, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 116, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6624, "End Page": 6629, "Article Number": null, "DOI": "10.1073/pnas.1900556116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1900556116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463069900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choudhury, S; Mangal, R; Agrawal, A; Archer, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choudhury, Snehashis; Mangal, Rahul; Agrawal, Akanksha; Archer, Lynden A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly reversible room-temperature lithium metal battery based on crosslinked hairy nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rough electrodeposition, uncontrolled parasitic side-reactions with electrolytes and dendrite-induced short-circuits have hindered development of advanced energy storage technologies based on metallic lithium, sodium and aluminium electrodes. Solid polymer electrolytes and nulloparticle-polymer composites have shown promise as candidates to suppress lithium dendrite growth, but the challenge of simultaneously maintaining high mechanical strength and high ionic conductivity at room temperature has so far been unmet in these materials. Here we report a facile and scalable method of fabricating tough, freestanding membranes that combine the best attributes of solid polymers, nullocomposites and gel-polymer electrolytes. Hairy nulloparticles are employed as multifunctional nodes for polymer crosslinking, which produces mechanically robust membranes that are exceptionally effective in inhibiting dendrite growth in a lithium metal battery. The membranes are also reported to enable stable cycling of lithium batteries paired with conventional intercalating cathodes. Our findings appear to provide an important step towards room-temperature dendrite-free batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10101, "DOI": "10.1038/ncomms10101", "DOI Link": "http://dx.doi.org/10.1038/ncomms10101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367569800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, RY; Wang, YF; Duan, XP; Lu, KD; Micheroni, D; Hu, AG; Lin, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ruoyu; Wang, Youfu; Duan, Xiaopin; Lu, Kuangda; Micheroni, Daniel; Hu, Aiguo; Lin, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale Metal-Organic Frameworks for Ratiometric Oxygen Sensing in Live Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the design of a phosphorescence/fluorescence dual-emissive nulloscale metal-organic framework (NMOF), R-UiO, as an intracellular oxygen (O-2) sensor. R-UiO contains a Pt(II)-porphyrin ligand as an O-2-sensitive probe and a Rhodamine-B isothiocyanate ligand as an O-2-insensitive reference probe. It exhibits good crystallinity, high stability, and excellent ratiometric luminescence response to O-2 partial pressure. In vitro experiments confirmed the applicability of R-UiO as an intracellular O-2 biosensor. This work is the first report of a NMOF-based intracellular oxygen sensor and should inspire the design of ratiometric NMOF sensors for other important analytes in biological systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2016, "Volume": 138, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2158, "End Page": 2161, "Article Number": null, "DOI": "10.1021/jacs.5b13458", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b13458", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371103900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Qiao, Y; Guo, SH; Xu, ZM; Zhu, H; Zhang, XY; Yuan, Y; He, P; Ishida, M; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiang; Qiao, Yu; Guo, Shaohua; Xu, Zhenming; Zhu, Hong; Zhang, Xiaoyu; Yuan, Yang; He, Ping; Ishida, Masayoshi; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Visualization of the Reversible O2-/O- Redox Process in Li-Rich Cathode Materials", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional cathodes of Li-ion batteries mainly operate through an insertion-extraction process involving transition metal redox. These cathodes will not be able to meet the increasing requirements until lithium-rich layered oxides emerge with beyond-capacity performance. Nevertheless, in-depth understanding of the evolution of crystal and excess capacity delivered by Li-rich layered oxides is insufficient. Herein, various in situ technologies such as X-ray diffraction and Raman spectroscopy are employed for a typical material Li1.2Ni0.2Mn0.6O2, directly visualizing O--O- (peroxo oxygen dimers) bonding mostly along the c-axis and demonstrating the reversible O2-/O- redox process. Additionally, the formation of the peroxo O-O bond is calculated via density functional theory, and the corresponding O-O bond length of approximate to 1.3 angstrom matches well with the in situ Raman results. These findings enrich the oxygen chemistry in layered oxides and open opportunities to design high-performance positive electrodes for lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2018, "Volume": 30, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705197, "DOI": "10.1002/adma.201705197", "DOI Link": "http://dx.doi.org/10.1002/adma.201705197", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429410300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Island, JO; Steele, GA; van der Zant, HSJ; Castellanos-Gomez, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Island, Joshua O.; Steele, Gary A.; van der Zant, Herre S. J.; Castellanos-Gomez, Andres", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environmental instability of few-layer black phosphorus", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study the environmental instability of mechanically exfoliated few-layer black phosphorus (BP). From continuous measurements of flake topography over several days, we observe an increase of over 200% in volume due to the condensation of moisture from air. We find that long term exposure to ambient conditions results in a layer-by-layer etching process of BP flakes. Interestingly, flakes can be etched down to single layer (phosphorene) thicknesses. BP's strong affinity for water greatly modifies the performance of fabricated field-effect transistors (FETs) measured in ambient conditions. Upon exposure to air, we differentiate between two timescales for changes in BP FET transfer characteristics: a short timescale (minutes) in which a shift in the threshold voltage occurs due to physisorbed oxygen and nitrogen, and a long timescale (hours) in which strong p-type doping occurs from water absorption. Continuous measurements of BP FETs in air reveal eventual degradation and break-down of the channel material after several days due to the layer-by-layer etching process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 862, "Times Cited, All Databases": 935, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11002, "DOI": "10.1088/2053-1583/2/1/011002", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/2/1/011002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354987200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DD; Wu, HH; Wang, CL; Gu, L; Chen, HZ; Jana, D; Feng, LL; Liu, JW; Wang, XY; Xu, PP; Guo, Z; Chen, QW; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongdong; Wu, Huihui; Wang, Changlai; Gu, Long; Chen, Hongzhong; Jana, Deblin; Feng, Lili; Liu, Jiawei; Wang, Xueying; Xu, Pengping; Guo, Zhen; Chen, Qianwang; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Assembled Single-Site nullozyme for Tumor-Specific Amplified Cascade Enzymatic Therapy", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullomaterials with enzyme-mimicking activity (nullozymes) show potential for therapeutic interventions. However, it remains a formidable challenge to selectively kill tumor cells through enzymatic reactions, while leaving normal cells unharmed. Herein, we present a new strategy based on a single-site cascade enzymatic reaction for tumor-specific therapy that avoids off-target toxicity to normal tissues. A copper hexacyanoferrate (Cu-HCF) nullozyme with active single-site copper exhibited cascade enzymatic activity within the tumor microenvironment: Tumor-specific glutathione oxidase activity by the Cu-HCF single-site nullozymes (SSNEs) led to the depletion of intracellular glutathione and the conversion of single-site Cu-II species into Cu-I for subsequent amplified peroxidase activity through a Fenton-type Harber-Weiss reaction. In this way, abundant highly toxic hydroxyl radicals were generated for tumor cell apoptosis. The results show that SSNEs could amplify the tumor-killing efficacy of reactive oxygen species and suppress tumor growth in vivo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2021, "Volume": 60, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3001, "End Page": 3007, "Article Number": null, "DOI": "10.1002/anie.202008868", "DOI Link": "http://dx.doi.org/10.1002/anie.202008868", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596886200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Huang, ZQ; Ma, YY; Gao, W; Li, J; Cao, FX; Li, L; Chang, CR; Qu, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Sai; Huang, Zheng-Qing; Ma, Yuanyuan; Gao, Wei; Li, Jing; Cao, Fangxian; Li, Lin; Chang, Chun-Ran; Qu, Yongquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nullorods of CeO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identification on catalytic sites of heterogeneous catalysts at atomic level is important to understand catalytic mechanism. Surface engineering on defects of metal oxides can construct new active sites and regulate catalytic activity and selectivity. Here we outline the strategy by controlling surface defects of nulloceria to create the solid frustrated Lewis pair (FLP) metal oxide for efficient hydrogenation of alkenes and alkynes. Porous nullorods of ceria (PN-CeO2) with a high concentration of surface defects construct new Lewis acidic sites by two adjacent surface Ce3+. The neighbouring surface lattice oxygen as Lewis base and constructed Lewis acid create solid FLP site due to the rigid lattice of ceria, which can easily dissociate H-H bond with low activation energy of 0.17 eV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15266, "DOI": "10.1038/ncomms15266", "DOI Link": "http://dx.doi.org/10.1038/ncomms15266", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401508600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, TT; Jiang, K; Ta, N; Hu, YF; Zeng, J; Liu, JY; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Tingting; Jiang, Kun; Ta, Na; Hu, Yongfeng; Zeng, Jie; Liu, Jingyue; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scaling up of electrocatalytic CO2 reduction for practical applications is still hindered by a few challenges: low selectivity, small current density tomaintain a reasonable selectivity, and the cost of the catalytic materials. Here we report a facile synthesis of earth-abundant Ni single-atom catalysts on commercial carbon black, which were further employed in a gas-phase electrocatalytic reactor under ambient conditions. As a result, those single-atomic sites exhibit an extraordinary performance in reducing CO2 to CO, yielding a current density above 100 mA cm(-2), with nearly 100% selectivity for CO and around 1% toward the hydrogen evolution side reaction. By further scaling up the electrode into a 10 3 10-cm(2) modular cell, the overall current in one unit cell can easily ramp up to more than 8 A while maintaining an exclusive CO evolution with a generation rate of 3.34 L hr(-1) per unit cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 716, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 278, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.015", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rivnay, J; Inal, S; Collins, BA; Sessolo, M; Stavrinidou, E; Strakosas, X; Tassone, C; Delongchamp, DM; Malliaras, GG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rivnay, Jonathan; Inal, Sahika; Collins, Brian A.; Sessolo, Michele; Stavrinidou, Eleni; Strakosas, Xenofon; Tassone, Christopher; Delongchamp, Dean M.; Malliaras, George G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural control of mixed ionic and electronic transport in conducting polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate), PEDOT: PSS, has been utilized for over two decades as a stable, solution-processable hole conductor. While its hole transport properties have been the subject of intense investigation, recent work has turned to PEDOT: PSS as a mixed ionic/electronic conductor in applications including bioelectronics, energy storage and management, and soft robotics. Conducting polymers can efficiently transport both holes and ions when sufficiently hydrated, however, little is known about the role of morphology on mixed conduction. Here, we show that bulk ionic and electronic mobilities are simultaneously affected by processing-induced changes in nullo- and meso-scale structure in PEDOT: PSS films. We quantify domain composition, and find that domain purification on addition of dispersion co-solvents limits ion mobility, even while electronic conductivity improves. We show that an optimal morphology allows for the balanced ionic and electronic transport that is critical for prototypical mixed conductor devices. These findings may pave the way for the rational design of polymeric materials and processing routes to enhance devices reliant on mixed conduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 710, "Times Cited, All Databases": 783, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11287, "DOI": "10.1038/ncomms11287", "DOI Link": "http://dx.doi.org/10.1038/ncomms11287", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374291300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QX; Liu, Y; Shi, JL; Liu, ZG; Wang, Q; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qingxian; Liu, Yuan; Shi, Junli; Liu, Zhiguang; Wang, Quan; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Porosity Foam-Based Iontronic Pressure Sensor with Superhigh Sensitivity of 9280 kPa-1", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible pressure sensors with high sensitivity are desired in the fields of electronic skins, human-machine interfaces, and health monitoring. Employing ionic soft materials with microstructured architectures in the functional layer is an effective way that can enhance the amplitude of capacitance signal due to generated electron double layer and thus improve the sensitivity of capacitive-type pressure sensors. However, the requirement of specific apparatus and the complex fabrication process to build such microstructures lead to high cost and low productivity. Here, we report a simple strategy that uses open-cell polyurethane foams with high porosity as a continuous three-dimensional network skeleton to load with ionic liquid in a one-step soak process, serving as the ionic layer in iontronic pressure sensors. The high porosity (95.4%) of PU-IL composite foam shows a pretty low Young's modulus of 3.4 kPa and good compressibility. A superhigh maximum sensitivity of 9,280 kPa(-1) in the pressure regime and a high pressure resolution of 0.125% are observed in this foam-based pressure sensor. The device also exhibits remarkable mechanical stability over 5,000 compression-release or bending-release cycles. Such high porosity of composite structure provides a simple, cost-effective and scalable way to fabricate super sensitive pressure sensor, which has prominent capability in applications of water wave detection, underwater vibration sensing, and mechanical fault monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21, "DOI": "10.1007/s40820-021-00770-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00770-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000728578300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, L; Zhang, P; Wen, QY; Fan, JJ; Xiang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Lei; Zhang, Peng; Wen, Qiye; Fan, Jiajie; Xiang, Quanjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper and platinum dual-single-atoms supported on crystalline graphitic carbon nitride for enhanced photocatalytic CO2 reduction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom Pt catalysts are designed to promote efficient atom utilization, whereas effective decrease of Pt loading and improvement of photocatalytic activity in monoatomic Pt-deposited systems is still ongoing. Atomically dispersed metal species in crystalline carbon nitride are still challenging owing to their high crystallization and structural stability. In this study, we developed a novel single-atomic Pt-Cu catalyst for reducing noble metal loading by combining Pt with earth-abundant Cu atoms and enhancing photocatalytic CO2 reduction. N-vacancy-rich crystalline carbon nitride was used as a fine-tuning ligand for isolated Pt-Cu atom dispersion based on its accessible functional N vacancies as the seeded centers. The synthesized dimetal Pt-Cu atoms on crystalline carbon nitride (PtCu-crCN) exhibited high selectivity and activity for CO2 conversion without the addition of any cocatalyst or sacrificial agent. In particular, we demonstrated that the diatomic Pt-Cu exhibited high mass activity with only 0.32 wt% Pt loading and showed excellent photocatalytic selectivity toward CH4 generation. The mechanism of CO2 photoreduction for PtCu-crCN was proposed based on the observations and analysis of aberration-corrected high-angle annular dark-field scanning transmission electron microscopy images, in situ irradiated X-ray photoelectron spectroscopy, and in situ diffuse reflectance infrared Fourier transform spectroscopy. The findings of this work provide insights for abrogating specific bifunctional atomic metal sites in noble metal-based photocatalysts by reducing noble metal loading and maximizing their effective mass activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 451, "End Page": 460, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63879-2", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63879-2", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745616200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsai, C; Chan, KR; Norskov, JK; Abild-Pedersen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsai, Charlie; Chan, Karen; Norskov, Jens K.; Abild-Pedersen, Frank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theoretical insights into the hydrogen evolution activity of layered transition metal dichalcogenides", "Source Title": "SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A thermodynamic descriptor-based approach using density functional theory calculations was used to investigate the activity and stability of 26 different transition metal dichalcogenide catalysts for the hydrogen evolution reaction (HER). We considered variations in the transition metal (Ti, V, Nb, Ta, Mo, W, Pd, Pt), the chalcogen (S and Se), the crystal structure (1T and 2H), and the surface termination (basal plane or edge). We find that the HER activity is strongly related to the stability of the catalyst, setting practical limitations on their potential application in HER. For the basal planes, the metallicity is found to be the most important parameter in determining the activity rather than structure or composition. However, systematic improvements in activity are strongly limited by a decrease in stability. For the edges, the activity and stability relationship are similar regardless of structure or chalcogen, and it is possible to achieve optimal hydrogen binding with a stable surface. Nudged elastic band calculations were carried out to probe the possible mechanisms for HER; the insurmountably high barrier for the Tafel mechanism suggests that HER may occur solely via the Volmer-Heyrovsky route for these materials. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 640, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 133, "End Page": 140, "Article Number": null, "DOI": "10.1016/j.susc.2015.01.019", "DOI Link": "http://dx.doi.org/10.1016/j.susc.2015.01.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359167800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, LL; Song, SJ; Liu, MJ; Yao, SY; Liang, ZX; Cheng, H; Ren, ZH; Liu, W; Lin, RQ; Qi, GC; Liu, XJ; Wu, Q; Luo, J; Xin, HLL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Lili; Song, Shoujie; Liu, Mingjie; Yao, Siyu; Liang, Zhixiu; Cheng, Hao; Ren, Zhouhong; Liu, Wei; Lin, Ruoqian; Qi, Gaocan; Liu, Xijun; Wu, Qin; Luo, Jun; Xin, Huolin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable and Efficient Single-Atom Zn Catalyst for CO2 Reduction to CH4", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly active and durable catalysts for electrochemical reduction of CO2 (ERC) to CH4 in aqueous media is an efficient and environmentally friendly solution to address global problems in energy and sustainability. In this work, an electrocatalyst consisting of single Zn atoms supported on microporous N-doped carbon was designed to enable multielectron transfer for catalyzing ERC to CH4 in 1 M KHCO3 solution. This catalyst exhibits a high Faradaic efficiency (FE) of 85%, a partial current density of -31.8 mA cm(-2) at a potential of -1.8 V versus saturated calomel electrode, and remarkable stability, with neither an obvious current drop nor large FE fluctuation observed during 35 h of ERC, indicating a far superior performance than that of dominullt Cu-based catalysts for ERC to CH4. Theoretical calculations reveal that single Zn atoms largely block CO generation and instead facilitate the production of CH4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2020, "Volume": 142, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12563, "End Page": 12567, "Article Number": null, "DOI": "10.1021/jacs.9b12111", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555420600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YP; Cui, Y; Alshareef, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yunpei; Cui, Yi; Alshareef, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Anode-Free Zn-MnO2 Battery", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-based batteries are attractive because of the low cost and high theoretical capacity of the Zn metal anode. However, the Zn-based batteries developed so far utilize an excess amount of Zn (i.e., thick Zn metal anode), which decreases the energy density of the whole battery. Herein, we demonstrate an anode-free design (i.e., zero-excess Zn), which is enabled by employing a nullocarbon nucleation layer. Electrochemical studies show that this design allows for uniform Zn electrodeposition with high efficiency and stability over a range of current densities and plating capacities. Using this anode-free configuration, we showcase a Zn-MnO2 battery prototype, showing 68.2% capacity retention after 80 cycles. Our anode-free design opens a new direction for implementing aqueous Zn-based batteries in energy storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2021, "Volume": 21, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1446, "End Page": 1453, "Article Number": null, "DOI": "10.1021/acs.nullolett.0c04519", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.0c04519", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619638600033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, H; Ma, J; Ma, J; Zhang, QH; Liu, XZ; Guan, B; Gu, L; Zhang, X; Zhang, YJ; Li, LL; Shen, Y; Lin, YH; null, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Hao; Ma, Jing; Ma, Ji; Zhang, Qinghua; Liu, Xiaozhi; Guan, Bo; Gu, Lin; Zhang, Xin; Zhang, Yu-Jun; Li, Liangliang; Shen, Yang; Lin, Yuan-Hua; null, Ce-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance film dielectrics for capacitive energy storage has been a great challenge for modern electrical devices. Despite good results obtained in lead titanate-based dielectrics, lead-free alternatives are strongly desirable due to environmental concerns. Here we demonstrate that giant energy densities of similar to 70 J cm(-3), together with high efficiency as well as excellent cycling and thermal stability, can be achieved in lead-free bismuth ferrite-strontium titanate solid-solution films through domain engineering. It is revealed that the incorporation of strontium titanate transforms the ferroelectric micro-domains of bismuth ferrite into highly-dynamic polar nullo-regions, resulting in a ferroelectric to relaxor-ferroelectric transition with concurrently improved energy density and efficiency. Additionally, the introduction of strontium titanate greatly improves the electrical insulation and breakdown strength of the films by suppressing the formation of oxygen vacancies. This work opens up a feasible and propagable route, i.e., domain engineering, to systematically develop new lead-free dielectrics for energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1813, "DOI": "10.1038/s41467-018-04189-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04189-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431629700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, WC; Xie, SJ; Zhang, XG; Sun, FF; Kang, JC; Jiang, Z; Zhang, QH; Wu, DY; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Wenchao; Xie, Shunji; Zhang, Xia-Guang; Sun, Fanfei; Kang, Jincan; Jiang, Zheng; Zhang, Qinghong; Wu, De-Yin; Wang, Ye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic reduction of CO2 to fuels and chemicals is one of the most attractive routes for CO2 utilization. Current catalysts suffer from low faradaic efficiency of a CO2-reduction product at high current density (or reaction rate). Here, we report that a sulfur-doped indium catalyst exhibits high faradaic efficiency of formate (>85%) in a broad range of current density (25-100 mA cm(-2)) for electrocatalytic CO2 reduction in aqueous media. The formation rate of formate reaches 1449 mu mol h(-1) cm(-2) with 93% faradaic efficiency, the highest value reported to date. Our studies suggest that sulfur accelerates CO2 reduction by a unique mechanism. Sulfur enhances the activation of water, forming hydrogen species that can readily react with CO2 to produce formate. The promoting effect of chalcogen modifiers can be extended to other metal catalysts. This work offers a simple and useful strategy for designing both active and selective electrocatalysts for CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 554, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 892, "DOI": "10.1038/s41467-019-08805-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08805-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459284600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hunter, BM; Hieringer, W; Winkler, JR; Gray, HB; Müller, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hunter, B. M.; Hieringer, W.; Winkler, J. R.; Gray, H. B.; Mueller, A. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of interlayer anions on [NiFe]-LDH nullosheet water oxidation activity", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We synthesized nickel-iron layered double hydroxide ([NiFe]-LDH) nullosheets with different interlayer anions to probe their role in water oxidation catalysis. In alkaline electrolyte in ambient air, carbonate rapidly replaced other interlayer anions and catalytic activity was highest. Electrocatalytic water oxidation in virtually carbonate-free alkaline electrolyte revealed that activity was a function of anion basicity. Our [NiFe]-LDH nullosheets, prepared by pulsed laser ablation in liquids, were regenerated in carbonate-containing aqueous KOH. Anion binding motifs were assessed by X-ray photoelectron spectroscopy in combination with density functional theory calculations, suggesting that nitrite species bound to edge-site Fe in the precatalyst correlated with higher water oxidation activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 484, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1734, "End Page": 1743, "Article Number": null, "DOI": "10.1039/c6ee00377j", "DOI Link": "http://dx.doi.org/10.1039/c6ee00377j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375699500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, JJ; Suh, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jiajia; Suh, Sangwon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategies to reduce the global carbon footprint of plastics", "Source Title": "NATURE CLIMATE CHANGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past four decades, global plastics production has quadrupled(1). If this trend were to continue, the GHG emissions from plastics would reach 15% of the global carbon budget by 2050(2). Strategies to mitigate the life-cycle GHG emissions of plastics, however, have not been evaluated on a global scale. Here, we compile a dataset covering ten conventional and five bio-based plastics and their life-cycle GHG emissions under various mitigation strategies. Our results show that the global life-cycle GHG emissions of conventional plastics were 1.7 Gt of CO2-equivalent (CO(2)e) in 2015, which would grow to 6.5 GtCO(2)e by 2050 under the current trajectory. However, aggressive application of renewable energy, recycling and demand-management strategies, in concert, has the potential to keep 2050 emissions comparable to 2015 levels. In addition, replacing fossil fuel feedstock with biomass can further reduce emissions and achieve an absolute reduction from the current level. Our study demonstrates the need for integrating energy, materials, recycling and demand-management strategies to curb growing life-cycle GHG emissions from plastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 724, "Times Cited, All Databases": 795, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 374, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41558-019-0459-z", "DOI Link": "http://dx.doi.org/10.1038/s41558-019-0459-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466122200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gélinas, S; Rao, A; Kumar, A; Smith, SL; Chin, AW; Clark, J; van der Poll, TS; Bazan, GC; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gelinas, Simon; Rao, Akshay; Kumar, Abhishek; Smith, Samuel L.; Chin, Alex W.; Clark, Jenny; van der Poll, Tom S.; Bazan, Guillermo C.; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast Long-Range Charge Separation in Organic Semiconductor Photovoltaic Diodes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the charge-separation mechanism in organic photovoltaic cells (OPVs) could facilitate optimization of their overall efficiency. Here we report the time dependence of the separation of photogenerated electron hole pairs across the donor-acceptor heterojunction in OPV model systems. By tracking the modulation of the optical absorption due to the electric field generated between the charges, we measure similar to 200 millielectron volts of electrostatic energy arising from electron-hole separation within 40 femtoseconds of excitation, corresponding to a charge separation distance of at least 4 nullometers. At this separation, the residual Coulomb attraction between charges is at or below thermal energies, so that electron and hole separate freely. This early time behavior is consistent with charge separation through access to delocalized pi-electron states in ordered regions of the fullerene acceptor material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 816, "Times Cited, All Databases": 878, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2014, "Volume": 343, "Issue": 6170, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 512, "End Page": 516, "Article Number": null, "DOI": "10.1126/science.1246249", "DOI Link": "http://dx.doi.org/10.1126/science.1246249", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330343700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Seo, DH; Kim, H; Park, I; Yoo, JK; Jung, SK; Park, YU; Goddard, WA ; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jongsoon; Seo, Dong-Hwa; Kim, Hyungsub; Park, Inchul; Yoo, Jung-Keun; Jung, Sung-Kyun; Park, Young-Uk; Goddard, William A., III; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unexpected discovery of low-cost maricite NaFePO4 as a high-performance electrode for Na-ion batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Battery chemistry based on earth-abundant elements has great potential for the development of cost-effective, large-scale energy storage systems. Herein, we report, for the first time, that maricite NaFePO4 can function as an excellent cathode material for Na ion batteries, an unexpected result since it has been regarded as an electrochemically inactive electrode for rechargeable batteries. Our investigation of the Na re-(de)intercalation mechanism reveals that all Na ions can be deintercalated from the nullo-sized maricite NaFePO4 with simultaneous transformation into amorphous FePO4. Our quantum mechanics calculations show that the underlying reason for the remarkable electrochemical activity of NaFePO4 is the significantly enhanced Na mobility in the transformed phase, which is similar to one fourth of the hopping activation barrier. Maricite NaFePO4, fully sodiated amorphous FePO4, delivered a capacity of 142 mA h g(-1) (92% of the theoretical value) at the first cycle, and showed outstanding cyclability with a negligible capacity fade after 200 cycles (95% retention of the initial cycle).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 540, "End Page": 545, "Article Number": null, "DOI": "10.1039/c4ee03215b", "DOI Link": "http://dx.doi.org/10.1039/c4ee03215b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349616900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, WY; Jiang, XF; Lai, SN; Peroulis, D; Stanciu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Winston Yenyu; Jiang, Xiaofan; Lai, Sz-Nian; Peroulis, Dimitrios; Stanciu, Lia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullohybrids of a MXene and transition metal dichalcogenide for selective detection of volatile organic compounds", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal carbides/nitrides, known as MXenes, have been recently receiving attention for gas sensing. However, studies on hybridization of MXenes and 2D transition metal dichalcogenides as gas-sensing materials are relatively rare at this time. Herein, Ti3C2Tx and WSe2 are selected as model materials for hybridization and implemented toward detection of various volatile organic compounds. The Ti(3)C(2)Tx/WSe2 hybrid sensor exhibits low noise level, ultrafast response/recovery times, and good flexibility for various volatile organic compounds. The sensitivity of the hybrid sensor to ethanol is improved by over 12-fold in comparison with pristine Ti3C2Tx. Moreover, the hybridization process provides an effective strategy against MXene oxidation by restricting the interaction of water molecules from the edges of Ti3C2Tx. An enhancement mechanism for Ti3C2Tx/WSe2 heterostructured materials is proposed for highly sensitive and selective detection of oxygencontaining volatile organic compounds. The scientific findings of this work could guide future exploration of next-generation field-deployable sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 466, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1302, "DOI": "10.1038/s41467-020-15092-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15092-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549170900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sprick, RS; Bonillo, B; Clowes, R; Guiglion, P; Brownbill, NJ; Slater, BJ; Blanc, F; Zwijnenburg, MA; Adams, DJ; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sprick, Reiner Sebastian; Bonillo, Baltasar; Clowes, Rob; Guiglion, Pierre; Brownbill, Nick J.; Slater, Benjamin J.; Blanc, Frederic; Zwijnenburg, Martijn A.; Adams, Dave J.; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible-Light-Driven Hydrogen Evolution Using Planarized Conjugated Polymer Photocatalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Linear poly(p-phenylene)s are modestly active UV photocatalysts for hydrogen production in the presence of a sacrificial electron donor. Introduction of planarized fluorene, carbazole, dibenzo[b,d]thiophene or dibenzo[b, d]thiophene sulfone units greatly enhances the H-2 evolution rate. The most active dibenzo[b, d] thiophene sulfone copolymer has a UV photocatalytic activity that rivals TiO2, but is much more active under visible light. The dibenzo[b, d]thiophene sulfone co-polymer has an apparent quantum yield of 2.3% at 420 nm, as compared to 0.1% for platinized commercial pristine carbon nitride.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2016, "Volume": 55, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1824, "End Page": 1828, "Article Number": null, "DOI": "10.1002/anie.201510542", "DOI Link": "http://dx.doi.org/10.1002/anie.201510542", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854000041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, SH; Zhou, QH; Ouyang, YX; Guo, YL; Li, Q; Wang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Shuaihua; Zhou, Qionghua; Ouyang, Yixin; Guo, Yilv; Li, Qiang; Wang, Jinlan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated discovery of stable lead-free hybrid organic-inorganic perovskites via machine learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapidly discovering functional materials remains an open challenge because the traditional trial-and-error methods are usually inefficient especially when thousands of candidates are treated. Here, we develop a target-driven method to predict undiscovered hybrid organic-inorganic perovskites (HOIPs) for photovoltaics. This strategy, combining machine learning techniques and density functional theory calculations, aims to quickly screen the HOIPs based on bandgap and solve the problems of toxicity and poor environmental stability in HOIPs. Successfully, six orthorhombic lead-free HOIPs with proper bandgap for solar cells and room temperature thermal stability are screened out from 5158 unexplored HOIPs and two of them stand out with direct bandgaps in the visible region and excellent environmental stability. Essentially, a close structure-property relationship mapping the HOIPs bandgap is established. Our method can achieve high accuracy in a flash and be applicable to a broad class of functional material design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 591, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3405, "DOI": "10.1038/s41467-018-05761-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05761-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442594800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, RJ; Liu, LJ; Lu, Y; Wang, CC; Li, YX; Li, L; Yan, ZH; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Ruijuan; Liu, Luojia; Lu, Yong; Wang, Chenchen; Li, Yixin; Li, Lin; Yan, Zhenhua; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-rich covalent organic frameworks with multiple carbonyls for high-performance sodium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks with designable periodic skeletons and ordered nullopores have attracted increasing attention as promising cathode materials for rechargeable batteries. However, the reported cathodes are plagued by limited capacity and unsatisfying rate performance. Here we report a honeycomb-like nitrogen-rich covalent organic framework with multiple carbonyls. The sodium storage ability of pyrazines and carbonyls and the up-to twelve sodium-ion redox chemistry mechanism for each repetitive unit have been demonstrated by in/ex-situ Fourier transform infrared spectra and density functional theory calculations. The insoluble electrode exhibits a remarkably high specific capacity of 452.0 mAh g(-1), excellent cycling stability (similar to 96% capacity retention after 1000 cycles) and high rate performance (134.3 mAh g(-1) at 10.0 A g(-1)). Furthermore, a pouch-type battery is assembled, displaying the gravimetric and volumetric energy density of 101.1 Wh kg(cell)(-1) and 78.5 Wh L-cell(-1), respectively, indicating potentially practical applications of conjugated polymers in rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 178, "DOI": "10.1038/s41467-019-13739-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13739-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551458600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Y; Jiao, Y; Zhu, YH; Li, LH; Han, Y; Chen, Y; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Yao; Jiao, Yan; Zhu, Yihan; Li, Lu Hua; Han, Yu; Chen, Ying; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction (HER) is a critical process due to its fundamental role in electrocatalysis. Practically, the development of high-performance electrocatalysts for HER in alkaline media is of great importance for the conversion of renewable energy to hydrogen fuel via photoelectrochemical water splitting. However, both mechanistic exploration and materials development for HER under alkaline conditions are very limited. Precious. Pt metal, which still serves as the state-of-the-art catalyst for HER, is unable to guarantee a sustainable hydrogen supply. Here we report an anomalously structured Ru catalyst that shows 2.5 times higher hydrogen generation rate than Pt and is among the most active HER electrocatalysts yet reported in alkaline solutions. The identification of new face-centered cubic crystallographic structure of Ru nulloparticles was investigated by high-resolution transmission electron microscopy imaging, and its formation mechanism was revealed by spectroscopic characterization and theoretical analysis. For the first time, it is found that the Ru nullo catalyst showed a pronounced effect of the crystal structure on the electrocatalytic activity tested under different conditions. The combination of electrochemical reaction rate measurements and density functional theory computation shows that the high activity of anomalous Ru catalyst in alkaline solution originates from its suitable adsorption energies to some key reaction intermediates and reaction kinetics in the HER process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 918, "Times Cited, All Databases": 941, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 138, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16174, "End Page": 16181, "Article Number": null, "DOI": "10.1021/jacs.6b11291", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b11291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389962800057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YX; Yang, JP; Chou, SL; Liu, HK; Zhang, WX; Zhao, DY; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yun-Xiao; Yang, Jianping; Chou, Shu-Lei; Liu, Hua Kun; Zhang, Wei-xian; Zhao, Dongyuan; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uniform yolk-shell iron sulfide-carbon nullospheres for superior sodium-iron sulfide batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-metal sulfide battery holds great promise for sustainable and cost-effective applications. Nevertheless, achieving high capacity and cycling stability remains a great challenge. Here, uniform yolk-shell iron sulfide-carbon nullospheres have been synthesized as cathode materials for the emerging sodium sulfide battery to achieve remarkable capacity of similar to 545 mA h g(-1) over 100 cycles at 0.2 C (100mAg(-1)), delivering ultrahigh energy density of similar to 438 Wh kg(-1). The proven conversion reaction between sodium and iron sulfide results in high capacity but severe volume changes. nullostructural design, including of nullosized iron sulfide yolks (similar to 170 nm) with porous carbon shells (similar to 30 nm) and extra void space (similar to 20 nm) in between, has been used to achieve excellent cycling performance without sacrificing capacity. This sustainable sodium-iron sulfide battery is a promising candidate for stationary energy storage. Furthermore, this spatially confined sulfuration strategy offers a general method for other yolk-shell metal sulfide-carbon composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8689, "DOI": "10.1038/ncomms9689", "DOI Link": "http://dx.doi.org/10.1038/ncomms9689", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364937600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, XH; Waller, G; Ding, D; Chen, DC; Rainwater, B; Zhao, BT; Wang, ZX; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Xunhui; Waller, Gordon; Ding, Dong; Chen, Dongchang; Rainwater, Ben; Zhao, Bote; Wang, Zhixing; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlled synthesis of NiCo2S4 nullostructured arrays on carbon fiber paper for high-performance pseudocapacitors", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile hydrothermal method is utilized to produce nullostructured NiCo2S4 arrays on carbon fiber paper with controlled morphologies to study the effect of morphology on their electrochemical performance in supercapacitors. Specifically, NiCo2S4 solid nullofiber, nullotube, and hollow nulloneedle of the same crystalline structure are synthesized by controlling the conditions of the hydrothermal synthesis. Among the three different morphologies studied, the hollow nulloneedle of NiCo2S4 shows the highest capacity and the longest cycling life, demonstrating a specific capacitance of similar to 1154 F g(-1) at a charge-discharge current density of 1 A g(-)(1) and negligible capacity loss after 8000 cycles (at a rate of 10 A g(-1)). This high performance is attributed to the unique nullostructure of the hollow nulloneedle, suggesting that the morphology of NiCo2S4 plays a vital role in determining the electrochemical performance. Further, an asymmetric capacitor consisting of NiCo2S4 hollow nulloneedle electrode and a tape-cast activated carbon film electrode achieves an energy density of 17.3 Wh kg(-1) at 1 A g(-1) and a power density of 0.2 kW kg(-1) at 20 A g(-1) in a voltage range of 0-1.5 V, implying that it has a great potential for a wide variety of practical applications. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 80, "Article Number": null, "DOI": "10.1016/j.nulloen.2015.06.018", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2015.06.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364579300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, M; Pang, XC; Liu, XQ; Jiang, BB; He, YJ; Snaith, H; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Ming; Pang, Xinchang; Liu, Xueqin; Jiang, Beibei; He, Yanjie; Snaith, Henry; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monodisperse Dual-Functional Upconversion nulloparticles Enabled Near-Infrared Organolead Halide Perovskite Solar Cells", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extending the spectral absorption of organolead halide perovskite solar cells from visible into near-infrared (NIR) range renders the minimization of non-absorption loss of solar photons with improved energy alignment. Herein, we report on, for the first time, a viable strategy of capitalizing on judiciously synthesized monodisperse NaYF4:Yb/Er upconversion nulloparticles (UCNPs) as the mesoporous electrode for CH3NH3PbI3 perovskite solar cells and more importantly confer perovskite solar cells to be operative under NIR light. Uniform NaYF4:Yb/Er UCNPs are first crafted by employing rationally designed double hydrophilic star-like poly(acrylic acid)-block-poly(ethylene oxide) (PAA-b-PEO) diblock copolymer as nulloreactor, imparting the solubility of UCNPs and the tunability of film porosity during the manufacturing process. The subsequent incorporation of NaYF4:Yb/Er UCNPs as the mesoporous electrode led to a high efficiency of 17.8%, which was further increased to 18.1% upon NIR irradiation. The insitu integration of upconversion materials as functional components of perovskite solar cells offers the expanded flexibility for engineering the device architecture and broadening the solar spectral use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2016, "Volume": 55, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4280, "End Page": 4284, "Article Number": null, "DOI": "10.1002/anie.201600702", "DOI Link": "http://dx.doi.org/10.1002/anie.201600702", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373006100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hart, JL; Hantanasirisakul, K; Lang, AC; Anasori, B; Pinto, D; Pivak, Y; van Omme, JT; May, SJ; Gogotsi, Y; Taheri, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C.; Anasori, Babak; Pinto, David; Pivak, Yevheniy; van Omme, J. Tijn; May, Steven J.; Gogotsi, Yury; Taheri, Mitra L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of MXenes' electronic properties through termination and intercalation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are an emerging family of highly-conductive 2D materials which have demonstrated state-of-the-art performance in electromagnetic interference shielding, chemical sensing, and energy storage. To further improve performance, there is a need to increase MXenes' electronic conductivity. Tailoring the MXene surface chemistry could achieve this goal, as density functional theory predicts that surface terminations strongly influence MXenes' Fermi level density of states and thereby MXenes' electronic conductivity. Here, we directly correlate MXene surface de-functionalization with increased electronic conductivity through in situ vacuum annealing, electrical biasing, and spectroscopic analysis within the transmission electron microscope. Furthermore, we show that intercalation can induce transitions between metallic and semiconductor-like transport (transitions from a positive to negative temperature-dependence of resistance) through inter-flake effects. These findings lay the groundwork for intercalation-and termination-engineered MXenes, which promise improved electronic conductivity and could lead to the realization of semiconducting, magnetic, and topologically insulating MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 950, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 522, "DOI": "10.1038/s41467-018-08169-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08169-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457291300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, C; Kwon, S; Cheng, T; Xu, MJ; Tieu, P; Lee, C; Cai, J; Lee, HM; Pan, XQ; Duan, XF; Goddard, WA ; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Chungseok; Kwon, Soonho; Cheng, Tao; Xu, Mingjie; Tieu, Peter; Lee, Changsoo; Cai, Jin; Lee, Hyuck Mo; Pan, Xiaoqing; Duan, Xiangfeng; Goddard, William A., III; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active and stable stepped Cu surface for enhanced electrochemical CO2 reduction to C2H4", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO(2)reduction to value-added chemical feedstocks is of considerable interest for renewable energy storage and renewable source generation while mitigating CO2 emissions from human activity. Copper represents an effective catalyst in reducing CO2 to hydrocarbons or oxygenates, but it is often plagued by a low product selectivity and limited long-term stability. Here we report that copper nullowires with rich surface steps exhibit a remarkably high Faradaic efficiency for C2H4 that can be maintained for over 200 hours. Computational studies reveal that these steps are thermodynamically favoured compared with Cu(100) surface under the operating conditions and the stepped surface favours C-2 products by suppressing the C-1 pathway and hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 804, "End Page": 812, "Article Number": null, "DOI": "10.1038/s41929-020-00504-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00504-x", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566893900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, L; Fu, L; Liu, HF; Xu, YX; Xing, JL; Chang, CR; Yang, DY; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Lei; Fu, Lei; Liu, Huifen; Xu, Youxun; Xing, Jialiang; Chang, Chun-Ran; Yang, Dong-Yuan; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methane (CH4) oxidation to high value chemicals under mild conditions through photocatalysis is a sustainable and appealing pathway, nevertheless confronting the critical issues regarding both conversion and selectivity. Herein, under visible irradiation (420 nm), the synergy of palladium (Pd) atom cocatalyst and oxygen vacancies (OVs) on In2O3 nullorods enables superior photocatalytic CH4 activation by O-2. The optimized catalyst reaches ca. 100 mu mol h(-1) of C1 oxygenates, with a selectivity of primary products (CH3OH and CH3OOH) up to 82.5%. Mechanism investigation elucidates that such superior photocatalysis is induced by the dedicated function of Pd single atoms and oxygen vacancies on boosting hole and electron transfer, respectively. O-2 is proven to be the only oxygen source for CH3OH production, while H2O acts as the promoter for efficient CH4 activation through center dot OH production and facilitates product desorption as indicated by DFT modeling. This work thus provides new understandings on simultaneous regulation of both activity and selectivity by the synergy of single atom cocatalysts and oxygen vacancies. CH4 oxidation to high value chemicals under mild conditions through photocatalysis confronts critical issues regarding both conversion and selectivity. Here, atomic Pd and oxygen vacancies were integrated on In2O3 nullorods, leading to visible-driven CH4 conversion with a remarkable yield of oxygenates and high selectivity of primary products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2930, "DOI": "10.1038/s41467-022-30434-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30434-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000802797000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, F; Shao, TY; Yu, YP; Xiong, YJ; Yang, LH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Feng; Shao, Tianyi; Yu, Yunpeng; Xiong, Yujie; Yang, Lihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface-bound reactive oxygen species generating nullozymes for selective antibacterial action", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Acting by producing reactive oxygen species (ROS) in situ, nullozymes are promising as antimicrobials. ROS' intrinsic inability to distinguish bacteria from mammalian cells, however, deprives nullozymes of the selectivity necessary for an ideal antimicrobial. Here we report that nullozymes that generate surface-bound ROS selectively kill bacteria over mammalian cells. This result is robust across three distinct nullozymes that universally generate surface-bound ROS, with an oxidase-like silver-palladium bimetallic alloy nullocage, AgPd0.38, being the lead model. The selectivity is attributable to both the surface-bound nature of ROS these nullozymes generate and an unexpected antidote role of endocytosis. Though surface-bound, the ROS on AgPd0.38 efficiently eliminated antibiotic-resistant bacteria and effectively delayed the onset of bacterial resistance emergence. When used as coating additives, AgPd0.38 enabled an inert substrate to inhibit biofilm formation and suppress infection-related immune responses in mouse models. This work opens an avenue toward biocompatible nullozymes and may have implication in our fight against antimicrobial resistance. nullozymes have been used for antibacterial applications but have potential toxicity to mammalian cells. Here the authors suggest that nullozymes that generate surface bound reactive oxygen species disrupt bacterial cell walls but not mammalian cells walls due to the different particle uptake mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 745, "DOI": "10.1038/s41467-021-20965-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-20965-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617063000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gumilar, G; Kaneti, YV; Henzie, J; Chatterjee, S; Na, J; Yuliarto, B; Nugraha, N; Patah, A; Bhaumik, A; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gumilar, Gilang; Kaneti, Yusuf Valentino; Henzie, Joel; Chatterjee, Sauvik; Na, Jongbeom; Yuliarto, Brian; Nugraha, Nugraha; Patah, Aep; Bhaumik, Asim; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis of hierarchical sheet/plate-like M-BDC (M = Cu, Mn, Ni, and Zr) metal-organic frameworks for electrochemical non-enzymatic glucose sensing", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional metal-organic frameworks (2D MOFs) are an attractive platform to develop new kinds of catalysts because of their structural tunability and large specific surface area that exposes numerous active sites. In this work, we report a general method to synthesize benzene dicarboxylic acid (BDC)-based MOFs with hierarchical 3D morphologies composed of 2D nullosheets or nulloplates. In our proposed strategy, acetonitrile helps solvate the metal ions in solution and affects the morphology, while polyvinylpyrrolidone (PVP) serves as a shape-control agent to assist in the nucleation and growth of MOF nullosheets. PVP also acts as a depletion agent to drive the assembly of the hierarchical sheet/plate-like M-BDC under solvothermal conditions. Further, we also demonstrate the flexibility of the proposed method using numerous coordinating metal ions (M = Cu, Mn, Ni, and Zr). The potential of these MOFs for electrochemical glucose sensing is examined using the hierarchical sheet-like Ni-BDC MOF as the optimum sample. It drives the electrocatalytic oxidation of glucose over a wide range (0.01 mM to 0.8 mM) with high sensitivity (635.9 mu A mM(-1) cm(-2)) in the absence of modification with carbon or the use of conductive substrates. It also demonstrates good selectivity with low limit of detection (LoD = 6.68 mu M; signal/noise = 3), and fast response time (<5 s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2020, "Volume": 11, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3644, "End Page": 3655, "Article Number": null, "DOI": "10.1039/c9sc05636j", "DOI Link": "http://dx.doi.org/10.1039/c9sc05636j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000525512500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CH; Sha, JW; Fei, HL; Liu, MJ; Yazdi, S; Zhang, JB; Zhong, QF; Zou, XL; Zhao, NQ; Yu, HS; Jiang, Z; Ringe, E; Yakobson, BI; Dong, JC; Chen, DL; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chenhao; Sha, Junwei; Fei, Huilong; Liu, Mingjie; Yazdi, Sadegh; Zhang, Jibo; Zhong, Qifeng; Zou, Xiaolong; Zhao, Naiqin; Yu, Haisheng; Jiang, Zheng; Ringe, Emilie; Yakobson, Boris I.; Dong, Juncai; Chen, Dongliang; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Atomic Ruthenium Catalytic Sites on Nitrogen-Doped Graphene for Oxygen Reduction Reaction in Acidic Medium", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The cathodic oxygen reduction reaction (ORR) is essential in the electrochemical energy conversion of fuel cells. Here, through the NH3 atmosphere annealing of a graphene oxide (GO) precursor containing trace amounts of Ru, we have synthesized atomically dispersed Ru on nitrogen-doped graphene that performs as an electrocatalyst for the ORR in acidic medium. The Ru/nitrogendoped GO catalyst exhibits excellent four-electron ORR activity, offering onset and half-wave potentials of 0.89 and 0.75 V, respectively, vs a reversible hydrogen electrode (RHE) in 0.1 M HClO4, together with better durability and tolerance toward methanol and carbon monoxide poisoning than seen in commercial Pt/C catalysts. X-ray adsorption fine structure analysis and aberration-corrected high-angle annular dark-field scanning transmission electron microscopy are performed and indicate that the chemical structure of Ru is predominulltly composed of isolated Ru atoms coordinated with nitrogen atoms on the graphene substrate. Furthermore, a density function theory study of the ORR mechanism suggests that a Ru-oxo-N-4 structure appears to be responsible for the ORR catalytic activity in the acidic medium. These findings provide a route for the design of efficient ORR single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6930, "End Page": 6941, "Article Number": null, "DOI": "10.1021/acsnullo.7b02148", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b02148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406649700041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SS; Lin, YC; Zhao, W; Wu, J; Wang, Z; Hu, ZH; Shen, YD; Tang, DM; Wang, JY; Zhang, Q; Zhu, H; Chu, LQ; Zhao, WJ; Liu, C; Sun, ZP; Taniguchi, T; Osada, M; Chen, W; Xu, QH; Wee, ATS; Suenaga, K; Ding, F; Eda, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shisheng; Lin, Yung-Chang; Zhao, Wen; Wu, Jing; Wang, Zhuo; Hu, Zehua; Shen, Youde; Tang, Dai-Ming; Wang, Junyong; Zhang, Qi; Zhu, Hai; Chu, Leiqiang; Zhao, Weijie; Liu, Chang; Sun, Zhipei; Taniguchi, Takaaki; Osada, Minoru; Chen, Wei; Xu, Qing-Hua; Wee, Andrew Thye Shen; Suenaga, Kazu; Ding, Feng; Eda, Goki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapour-liquid-solid growth of monolayer MoS2 nulloribbons", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical vapour deposition of two-dimensional materials typically involves the conversion of vapour precursors to solid products in a vapour-solid-solid mode. Here, we report the vapour-liquid-solid growth of monolayer MoS2, yielding highly crystalline ribbons with a width of few tens to thousands of nullometres. This vapour-liquid-solid growth is triggered by the reaction between MoO3 and NaCl, which results in the formation of molten Na-Mo-O droplets. These droplets mediate the growth of MoS2 ribbons in the 'crawling mode' when saturated with sulfur. The locally well-defined orientations of the ribbons reveal the regular horizontal motion of the droplets during growth. Using atomic-resolution scanning transmission electron microscopy and second harmonic generation microscopy, we show that the ribbons are grown homoepitaxially on monolayer MoS2 with predominulltly 2H-or 3R-type stacking. Our findings highlight the prospects for the controlled growth of atomically thin nullo-structure arrays for nulloelectronic devices and the development of unique mixed-dimensional structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 535, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-018-0055-z", "DOI Link": "http://dx.doi.org/10.1038/s41563-018-0055-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432928300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wadley, P; Howells, B; Zelezny, J; Andrews, C; Hills, V; Campion, RP; Novák, V; Olejník, K; Maccherozzi, F; Dhesi, SS; Martin, SY; Wagner, T; Wunderlich, J; Freimuth, F; Mokrousov, Y; Kunes, J; Chauhan, JS; Grzybowski, MJ; Rushforth, AW; Edmonds, KW; Gallagher, BL; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wadley, P.; Howells, B.; Zelezny, J.; Andrews, C.; Hills, V.; Campion, R. P.; Novak, V.; Olejnik, K.; Maccherozzi, F.; Dhesi, S. S.; Martin, S. Y.; Wagner, T.; Wunderlich, J.; Freimuth, F.; Mokrousov, Y.; Kunes, J.; Chauhan, J. S.; Grzybowski, M. J.; Rushforth, A. W.; Edmonds, K. W.; Gallagher, B. L.; Jungwirth, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical switching of an antiferromagnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferromagnets are hard to control by external magnetic fields because of the alternating directions of magnetic moments on individual atoms and the resulting zero net magnetization. However, relativistic quantum mechanics allows for generating current-induced internal fields whose sign alternates with the periodicity of the antiferromagnetic lattice. Using these fields, which couple strongly to the antiferromagnetic order, we demonstrate room-temperature electrical switching between stable configurations in antiferromagnetic CuMnAs thin-film devices by applied current with magnitudes of order 10(6) ampere per square centimeter. Electrical writing is combined in our solid-state memory with electrical readout and the stored magnetic state is insensitive to and produces no external magnetic field perturbations, which illustrates the unique merits of antiferromagnets for spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1158, "Times Cited, All Databases": 1233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2016, "Volume": 351, "Issue": 6273, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 587, "End Page": 590, "Article Number": null, "DOI": "10.1126/science.aab1031", "DOI Link": "http://dx.doi.org/10.1126/science.aab1031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369291600036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, Z; Zhang, Y; Xu, HF; Chen, WJ; Liu, BY; Zhang, JY; Zhang, H; Wang, ZH; Kang, DH; Zeng, JR; Gao, XY; Wang, QS; Hu, HJ; Zhou, HM; Cai, XB; Tian, XY; Reiss, P; Xu, BM; Kirchartz, T; Xiao, ZG; Dai, SY; Park, NG; Ye, JJ; Pan, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Zheng; Zhang, Yong; Xu, Huifen; Chen, Wenjing; Liu, Boyuan; Zhang, Jiyao; Zhang, Hui; Wang, Zihan; Kang, Dong-Ho; Zeng, Jianrong; Gao, Xingyu; Wang, Qisheng; Hu, Huijie; Zhou, Hongmin; Cai, Xiangbin; Tian, Xingyou; Reiss, Peter; Xu, Baomin; Kirchartz, Thomas; Xiao, Zhengguo; Dai, Songyuan; Park, Nam-Gyu; Ye, Jiajiu; Pan, Xu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Homogenizing out-of-plane cation composition in perovskite solar cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells with the formula FA(1-x)CsxPbI(3), where FA is formamidinium, provide an attractive option for integrating high efficiency, durable stability and compatibility with scaled-up fabrication. Despite the incorporation of Cs cations, which could potentially enable a perfect perovskite lattice(1,2), the compositional inhomogeneity caused by A-site cation segregation is likely to be detrimental to the photovoltaic performance of the solar cells(3,4). Here we visualized the out-of-plane compositional inhomogeneity along the vertical direction across perovskite films and identified the underlying reasons for the inhomogeneity and its potential impact for devices. We devised a strategy using 1-(phenylsulfonyl)pyrrole to homogenize the distribution of cation composition in perovskite films. The resultant p-i-n devices yielded a certified steady-state photon-to-electron conversion efficiency of 25.2% and durable stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2023, "Volume": 624, "Issue": 7992, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 557, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06784-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06784-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169177500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HW; Ly, KCS; Liu, XH; Chen, ZH; Yan, M; Wu, ZL; Wang, X; Zheng, YB; Zhou, H; Fan, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Haiwen; Ly, Kally C. S.; Liu, Xianghui; Chen, Zhihan; Yan, Max; Wu, Zilong; Wang, Xin; Zheng, Yuebing; Zhou, Han; Fan, Tongxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biologically inspired flexible photonic films for efficient passive radiative cooling", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Temperature is a fundamental parameter for all forms of lives. Natural evolution has resulted in organisms which have excellent thermoregulation capabilities in extreme climates. Bioinspired materials that mimic biological solution for thermoregulation have proven promising for passive radiative cooling. However, scalable production of artificial photonic radiators with complex structures, outstanding properties, high throughput, and low cost is still challenging. Herein, we design and demonstrate biologically inspired photonic materials for passive radiative cooling, after discovery of longicorn beetles' excellent thermoregulatory function with their dual-scale fluffs. The natural fluffs exhibit a finely structured triangular cross-section with two thermoregulatory effects which effectively reflects sunlight and emits thermal radiation, thereby decreasing the beetles' body temperature. Inspired by the finding, a photonic film consisting of a micropyramid-arrayed polymer matrix with random ceramic particles is fabricated with high throughput. The film reflects similar to 95% of solar irradiance and exhibits an infrared emissivity >0.96. The effective cooling power is found to be similar to 90.8 W center dot m(-2) and a temperature decrease of up to 5.1 degrees C is recorded under direct sunlight. Additionally, the film exhibits hydrophobicity, superior flexibility, and strong mechanical strength, which is promising for thermal management in various electronic devices and wearable products. Our work paves the way for designing and fabrication of high-performance thermal regulation materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2020, "Volume": 117, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14657, "End Page": 14666, "Article Number": null, "DOI": "10.1073/pnas.2001802117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2001802117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548159300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, SY; Wang, T; Liu, TT; Yan, XC; Li, Z; Xu, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Shuyuan; Wang, Tao; Liu, Tingting; Yan, Xicheng; Li, Zhong; Xu, Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active modulation of electromagnetically induced transparency analogue in terahertz hybrid metal-graphene metamaterials", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterial analogues of electromagnetically induced transparency (EIT) have been intensively studied and widely employed for slow light and enhanced nonlinear effects. In particular, the active modulation of the EIT analogue and well-controlled group delay in metamaterials have shown great prospects in optical communication networks. Here we integrate a monolayer graphene into metal-based terahertz (THz) metamaterials, and realize a complete modulation in the resonullce strength of the EIT analogue via manipulating the Fermi level of graphene. The physical mechanism lies in the active tuning of the damping rate of the dark mode resonator through the recombination effect of the conductive graphene. This work presents a novel modulation strategy of the EIT analogue in the hybrid metamaterials, and paves the way towards designing very compact slow light devices to meet the future demand of ultrafast optical signal processing. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 126, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 278, "Article Number": null, "DOI": "10.1016/j.carbon.2017.10.035", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2017.10.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415319700031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lucci, FR; Liu, JL; Marcinkowski, MD; Yang, M; Allard, LF; Flytzani-Stephanopoulos, M; Sykes, ECH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D.; Yang, Ming; Allard, Lawrence F.; Flytzani-Stephanopoulos, Maria; Sykes, E. Charles H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective hydrogenation of 1,3-butadiene on platinum-copper alloys at the single-atom limit", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum is ubiquitous in the production sectors of chemicals and fuels; however, its scarcity in nature and high price will limit future proliferation of platinum-catalysed reactions. One promising approach to conserve platinum involves understanding the smallest number of platinum atoms needed to catalyse a reaction, then designing catalysts with the minimal platinum ensembles. Here we design and test a new generation of platinum-copper nulloparticle catalysts for the selective hydrogenation of 1,3-butadiene,, an industrially important reaction. Isolated platinum atom geometries enable hydrogen activation and spillover but are incapable of C-C bond scission that leads to loss of selectivity and catalyst deactivation. gamma-Alumina-supported single-atom alloy nulloparticle catalysts with <1 platinum atom per 100 copper atoms are found to exhibit high activity and selectivity for butadiene hydrogenation to butenes under mild conditions, demonstrating transferability from the model study to the catalytic reaction under practical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8550, "DOI": "10.1038/ncomms9550", "DOI Link": "http://dx.doi.org/10.1038/ncomms9550", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364930800035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "King, WE; Barth, HD; Castillo, VM; Gallegos, GF; Gibbs, JW; Hahn, DE; Kamath, C; Rubenchik, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "King, Wayne E.; Barth, Holly D.; Castillo, Victor M.; Gallegos, Gilbert F.; Gibbs, John W.; Hahn, Douglas E.; Kamath, Chandrika; Rubenchik, Alexander M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of keyhole-mode laser melting in laser powder-bed fusion additive manufacturing", "Source Title": "JOURNAL OF MATERIALS PROCESSING TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser powder-bed fusion additive manufacturing of metals employs high-power focused laser beams. Typically, the depth of the molten pool is controlled by conduction of heat in the underlying solid material. But, under certain conditions, the mechanism of melting can change from conduction to so-called keyhole-mode laser melting. In this mode, the depth of the molten pool is controlled by evaporation of the metal. Keyhole-mode laser melting results in melt pool depths that can be much deeper than observed in conduction mode. In addition, the collapse of the vapor cavity that is formed by the evaporation of the metal can result in a trail of voids in the wake of the laser beam. In this paper, the experimental observation of keyhole-mode laser melting in a laser powder-bed fusion additive manufacturing setting for 316L stainless steel is presented. The conditions required to transition from conduction controlled melting to keyhole-mode melting are identified. (c) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1086, "Times Cited, All Databases": 1265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 214, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2915, "End Page": 2925, "Article Number": null, "DOI": "10.1016/j.jmatprotec.2014.06.005", "DOI Link": "http://dx.doi.org/10.1016/j.jmatprotec.2014.06.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342245500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuai, L; Chen, Z; Liu, SJ; Kan, EJ; Yu, N; Ren, YM; Fang, CH; Li, XY; Li, YD; Geng, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuai, Long; Chen, Zheng; Liu, Shoujie; Kan, Erjie; Yu, null; Ren, Yiming; Fang, Caihong; Li, Xingyang; Li, Yadong; Geng, Baoyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Titania supported synergistic palladium single atoms and nulloparticles for room temperature ketone and aldehydes hydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selective reduction of ketone/aldehydes to alcohols is of great importance in green chemistry and chemical engineering. Highly efficient catalysts are still demanded to work under mild conditions, especially at room temperature. Here we present a synergistic function of single-atom palladium (Pd-1) and nulloparticles (Pd-NPs) on TiO2 for highly efficient ketone/aldehydes hydrogenation to alcohols at room temperature. Compared to simple but inferior Pd-1/TiO2 and Pd-NPs/TiO2 catalysts, more than twice activity enhancement is achieved with the Pd1+NPs/TiO2 catalyst that integrates both Pd-1 and Pd NPs on mesoporous TiO2 supports, obtained by a simple but large-scaled spray pyrolysis route. The synergistic function of Pd-1 and Pd-NPs is assigned so that the partial Pd-1 dispersion contributes enough sites for the activation of C=O group while Pd-NPs site boosts the dissociation of H-2 molecules to H atoms. This work not only contributes a superior catalyst for ketone/aldehydes hydrogenation, but also deepens the knowledge on their hydrogenation mechanism and guides people to engineer the catalytic behaviors as needed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 48, "DOI": "10.1038/s41467-019-13941-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13941-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511959800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, L; Lei, JY; Wang, FC; Wang, LZ; Hoffmann, MR; Liu, YD; In, SI; Zhang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Liang; Lei, Juying; Wang, Fuchen; Wang, Lingzhi; Hoffmann, Michael R.; Liu, Yongdi; In, Su-Il; Zhang, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon nitride nullotubes with in situ grafted hydroxyl groups for highly efficient spontaneous H2O2 production", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An active and inexpensive photocatalyst for H2O2 production is desirable for industrial applications. However, obtaining high photocatalytic activity from metal-free catalysts without the use of sacrificial electron donors is difficult. Herein, g-C3N4 (CN) nullotubes functionalized with surface > OH groups that are grafted in situ were successfully synthesized via a novel alkalinization process. The nullotube structures provide a large surface area and improved mass transfer properties. In situ grafted > OH groups can capture photogenerated holes to promote separation of photogenerated charge, enabling the ready availability of electrons and hydrogen ions for H2O2 production. Further, the surface > OH groups help to suppress H2O2 self-decomposition. Consequently, a high rate of 240.36 mu mol h(-1) g(-1) of H2O2 production can be achieved without sacrificial agents, which is the highest H2O2 production in a spontaneous system for metal-free photocatalysts. This work provides a new strategy for an efficient and spontaneous H2O2 production method using a metal-free CN photocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2021, "Volume": 288, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119993, "DOI": "10.1016/j.apcatb.2021.119993", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2021.119993", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632996500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nyein, HYY; Gao, W; Shahpar, Z; Emaminejad, S; Challa, S; Chen, K; Fahad, HM; Tai, LC; Ota, H; Davis, RW; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nyein, Hnin Yin Yin; Gao, Wei; Shahpar, Ziba; Emaminejad, Sam; Challa, Samyuktha; Chen, Kevin; Fahad, Hossain M.; Tai, Li-Chia; Ota, Hiroki; Davis, Ronald W.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Wearable Electrochemical Platform for Noninvasive Simultaneous Monitoring of Ca2+ and pH", "Source Title": "ACS nullo", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Homeostasis of ionized calcium in biofluids is critical for human biological functions and organ systems. Measurement of ionized calcium for clinical applications is not easily accessible due to its strict procedures and dependence on pH. pH balance in body fluids greatly affects metabolic reactions and biological transport systems. Here, we demonstrate a wearable electrochemical device for continuous monitoring of ionized calcium and pH of body fluids using a disposable and flexible array of Ca2+ and pH sensors that interfaces with a flexible printed circuit board. This platform enables real-time quantitative analysis of these sensing elements in body fluids such as sweat, urine, and tears. Accuracy of Ca2+ concentration and pH measured by the wearable sensors is validated through inductively coupled plasma-mass spectrometry technique and a commercial pH meter, respectively. Our results show that the wearable sensors have high repeatability and selectivity to the target ions. Real-time on-body assessment of sweat is also performed, and our results indicate that calcium concentration increases with decreasing pH. This platform can be used in noninvasive continuous analysis of ionized calcium and pH in body fluids for disease diagnosis such as primary hyperparathyroidism and kidney stones.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 525, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7216, "End Page": 7224, "Article Number": null, "DOI": "10.1021/acsnullo.6b04005", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b04005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380576600089", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ferrero, GA; Preuss, K; Marinovic, A; Jorge, AB; Mansor, N; Brett, DJL; Fuertes, AB; Sevilla, M; Titirici, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ferrero, Guillermo A.; Preuss, Kathrin; Marinovic, Adam; Jorge, Ana Belen; Mansor, Noramalina; Brett, Dan J. L.; Fuertes, Antonio B.; Sevilla, Marta; Titirici, Maria-Magdalena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe-N-Doped Carbon Capsules with Outstanding Electrochemical Performance and Stability for the Oxygen Reduction Reaction in Both Acid and Alkaline Conditions", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High surface area N-doped mesoporous carbon capsules with iron traces exhibit outstanding electrocatalytic activity for the oxygen reduction reaction in both alkaline and acidic media. In alkaline conditions, they exhibit more positive onset (0.94 V vs RHE) and half-wave potentials (0.83 V vs RHE,) than commercial Pt/C, while in acidic media the onset potential is comparable to that of commercial Pt/C with a peroxide yield lower than 10%. The Fe N-doped carbon catalyst combines high catalytic activity with remarkable performance stability (3500 cycles between 0.6 and 1.0 V vs RHE), which stems from the fact that iron is coordinated to nitrogen. Additionally, the newly developed electrocatalyst is unaffected by the methanol crossover effect in both acid and basic media, contrary to commercial Pt/C. The excellent catalytic behavior of the Fe N-doped carbon, even in the more relevant acid medium, is attributable to the combination of chemical functions (N-pyridinic, N-quaternary, and Fe-N coordination sites) and structural properties (large surface area, open mesoporous structure, and short diffusion paths), which guarantees a large number of highly active and fully accessible catalytic sites and rapid mass-transfer kinetics. Thus, this catalyst represents an important step forward toward replacing Pt catalysts with cheaper alternatives. In this regard, an alkaline anion exchange membrane fuel cell was assembled with Fe-N-doped mesoporous carbon capsules as the cathode catalyst to provide current and power densities matching those of a commercial Pt/C, which indicates the practical applicability of the Fe N-carbon catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5922, "End Page": 5932, "Article Number": null, "DOI": "10.1021/acsnullo.6b01247", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b01247", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378973700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YH; Peng, E; Shao, YC; Xiao, ZG; Dong, QF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yehao; Peng, Edwin; Shao, Yuchuan; Xiao, Zhengguo; Dong, Qingfeng; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organolead trihalide perovskites (OTPs) are nature abundant materials with prospects as future low-cost renewable energy sources boosted by the solution process capability of these materials. Here we report the fabrication of efficient OTP devices by a simple, high throughput and low-cost doctor-blade coating process which can be compatible with the roll-to-roll fabrication process for the large scale production of perovskite solar cell panels. The formulation of appropriate precursor inks by removing impurities is shown to be critical in the formation of continuous, pinhole free and phase-pure perovskite films on large area substrates, which is assisted by a high deposition temperature to guide the nucleation and grain growth process. The domain size reached 80-250 mu m in 1.5-2 mu m thick bladed films. By controlling the stoichiometry and thickness of the OTP films, highest device efficiencies of 12.8% and 15.1% are achieved in the devices fabricated on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate and cross-linked N4, N4'-bis(4-(6-((3-ethyloxetan-3-yl) methoxy) hexyl) phenyl)-N4, N4'-diphenylbiphenyl-4,4'-diamine covered ITO substrates. Interestingly, the carrier diffusion length in doctor-bladed OTP films is beyond 3.5 mu m which is significantly larger than in the spin-coated films, due to the formation of crystalline grains with a very large size by the doctor-blade coating method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 611, "Times Cited, All Databases": 662, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1544, "End Page": 1550, "Article Number": null, "DOI": "10.1039/c4ee03907f", "DOI Link": "http://dx.doi.org/10.1039/c4ee03907f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354192900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, RC; Xie, J; Xiang, QJ; Chen, XB; Jiang, JZ; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Rongchen; Xie, Jun; Xiang, Quanjun; Chen, Xiaobo; Jiang, Jizhou; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni-based photocatalytic H2-production cocatalysts", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalysis is believed to be one of the best methods to realize sustainable H-2 production. However, achieving this through heterogeneous photocatalysis still remains a great challenge owing to the absence of active sites, sluggish surface reaction kinetics, insufficient charge separation, and a high thermodynamic barrier. Therefore, cocatalysts are necessary and of great significance in boosting photocatalytic H-2 generation. This review will focus on the promising and appealing low-cost Ni-based H-2-generation cocatalysts as the alternatives for the high-cost and low-abundance noble metal cocatalysts. Special emphasis has been placed on the design principle, modification strategies for further enhancing the activity and stability of Ni-based cocatalysts, and identification of the exact active sites and surface reaction mechanisms. Particularly, four types of modification strategies based on increased light harvesting, enhanced charge separation, strengthened interface interaction, and improved electrocatalytic activity have been thoroughly discussed and compared in detail. This review may open a new avenue for designing highly active and durable Ni-based cocatalysts for photocatalytic H-2 generation. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 40, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": 288, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63294-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63294-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466263200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, CZ; Alvarado, J; Xu, J; Clément, RJ; Kodur, M; Tong, W; Grey, CP; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Chuze; Alvarado, Judith; Xu, Jing; Clement, Raphaele J.; Kodur, Moses; Tong, Wei; Grey, Clare P.; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring Oxygen Activity in the High Energy P2-Type Na0.78Ni0.23Mn0.69O2 Cathode Material for Na-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale electric energy storage is fundamental to the use of renewable energy. Recently, research and development efforts on room-temperature sodium-ion batteries (NIBs) have been revitalized, as NIBs are considered promising, low-cost alternatives to the current Li-ion battery technology for large-scale applications. Herein, we introduce a novel layered oxide cathode material, Na0.78Ni0.23Mn0.69O2. This new compound provides a high reversible capacity of 138 mAh g(-1) and an average potential of 3.25 V vs Na+/Na with a single smooth voltage profile. Its remarkable rate and cycling performances are attributed to the elimination of the P2-O2 phase transition upon cycling to 4.5 V. The first charge process yields an abnormally excess capacity, which has yet to be observed in other P2 layered oxides. Metal K-edge XANES results show that the major charge compensation at the metal site during Na-ion deintercalation is achieved via the oxidation of nickel (Ni2+) ions, whereas, to a large extent, manganese (Mn) ions remain in their Mn4+ state. Interestingly, electron energy loss spectroscopy (EELS) and soft X-ray absorption spectroscopy (sXAS) results reveal differences in electronic structures in the bulk and at the surface of electrochemically cycled particles. At the surface, transition metal ions (TM ions) are in a lower valence state than in the bulk, and the 0 K-edge prepeak disappears. On the basis of previous reports on related Li-excess LIB cathodes, it is proposed that part of the charge compensation mechanism during the first cycle takes place at the lattice oxygen site, resulting in a surface to bulk transition metal gradient. We believe that by optimizing and controlling oxygen activity, Na layered oxide materials with higher capacities can be designed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2017, "Volume": 139, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4835, "End Page": 4845, "Article Number": null, "DOI": "10.1021/jacs.7b00164", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b00164", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398764000037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chai, GL; Qiu, KP; Qiao, M; Titirici, MM; Shang, CX; Guo, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chai, Guo-Liang; Qiu, Kaipei; Qiao, Mo; Titirici, Maria-Magdalena; Shang, Congxiao; Guo, Zhengxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active sites engineering leads to exceptional ORR and OER bifunctionality in P,N Co-doped graphene frameworks", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bifunctional catalysts for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) are highly desirable for rechargeable metal-air batteries and regenerative fuel cells. However, the commercial oxygen electrocatalysts (mainly noble metal based) can only exhibit either ORR or OER activity and also suffer from inherent cost and stability issues. It remains challenging to achieve efficient ORR and OER bifunctionality on a single catalyst. Metal-free structures offer relatively large scope for this bifunctionality to be engineered within one catalyst, together with improved cost-effectiveness and durability. Herein, by closely coupled computational design and experimental development, highly effective bifunctionality was achieved in a phosphorus and nitrogen co-doped graphene framework (PNGF) - with both ORR and OER activities reaching the theoretical limits of metal-free catalysts, superior to their noble metal counterparts in both (bi)functionality and durability. In particular, with the identification of active P-N sites for OER and N-doped sites for ORR, we successfully intensified these sites by one-pot synthesis to tailor the PNGF. The resulting catalyst achieved an ORR potential of 0.845 V vs. RHE at 3 mA cm(-2) and an OER potential of 1.55 V vs. RHE at 10 mA cm(-2). Its combined ORR and OER overpotential of 705 mV is much lower than those previously reported for metal-free bifunctional catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 455, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1186, "End Page": 1195, "Article Number": null, "DOI": "10.1039/c6ee03446b", "DOI Link": "http://dx.doi.org/10.1039/c6ee03446b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401408500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, HL; Yang, ZH; Liu, B; Wu, GL; Lou, ZC; Fei, B; Wu, RB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Hualiang; Yang, Zhihong; Liu, Bo; Wu, Guanglei; Lou, Zhichao; Fei, Ben; Wu, Renbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A flexible electromagnetic wave-electricity harvester", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing an ultimate electromagnetic (EM)-absorbing material that can not only dissipate EM energy but also convert the generated heat into electricity is highly desired but remains a significant challenge. Here, we report a hybrid Sn@C composite with a biological cell-like splitting ability to address this challenge. The composite consisting of Sn nulloparticles embedded within porous carbon would split under a cycled annealing treatment, leading to more dispersed nulloparticles with an ultrasmall size. Benefiting from an electron-transmitting but a phonon-blocking structure created by the splitting behavior, an EM wave-electricity device constructed by the optimum Sn@C composite could achieve an efficiency of EM to heat at widely used frequency region and a maximum thermoelectric figure of merit of 0.62 at 473K, as well as a constant output voltage and power under the condition of microwave radiation. This work provides a promising solution for solving EM interference with self-powered EM devices. Materials that can harvest electromagnetic (EM) waves and harness the resulting energy would have many applications. Here, the authors present a hybrid composite that produces thermoelectricity from the heating in the EM absorption under microwave radiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 834, "DOI": "10.1038/s41467-021-21103-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21103-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617500200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takaya, CA; Fletcher, LA; Singh, S; Anyikude, KU; Ross, AB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takaya, C. A.; Fletcher, L. A.; Singh, S.; Anyikude, K. U.; Ross, A. B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphate and ammonium sorption capacity of biochar and hydrochar from different wastes", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The potential for biochar and hydrochar to adsorb phosphate and ammonium is important for understanding the influence of these materials when added to soils, compost or other high nutrient containing environments. The influence of physicochemical properties such as mineral content, surface functionality, pH and cation exchange capacity has been investigated for a range of biochars and hydrochars produced from waste-derived biomass feedstocks. Hydrochars produced from hydrothermal carbonisation at 250 degrees C have been compared to low and high temperature pyrolysis chars produced at 400 450 degrees C and 600-650 degrees C respectively for oak wood, presscake from anaerobic digestate (AD), treated municipal waste and greenhouse waste. In spite of differences in char physicochemical properties and processing conditions, PO4-P and NH4-N sorption capacities ranged from about 0 to 30 mg g(-1) and 105.8-146.4 mg g(-1) respectively. Chars with high surface areas did not possess better ammonium adsorption capacities than low surface area chars, which suggests that surface area is not the most important factor influencing char ammonium adsorption capacity, while char calcium and magnesium contents may influence phosphate adsorption. Desorption experiments only released a small fraction of adsorbed ammonium or phosphate (<5 mg g(-1) and a maximum of 8.5 mg g(-1) respectively). (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 145, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 518, "End Page": 527, "Article Number": null, "DOI": "10.1016/j.chemosphere.2015.11.052", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2015.11.052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369196300066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LZ; Hu, TP; Dai, K; Zhang, JF; Liang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Lizhong; Hu, Taiping; Dai, Kai; Zhang, Jinfeng; Liang, Changhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel step-scheme BiVO4/Ag3VO4 photocatalyst for enhanced photocatalytic degradation activity under visible light irradiation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past few years, the emission of organic pollutants into the environment has increased tremendously. Therefore, various photocatalysts have been developed for the degradation of organic pollutants. In this study, a step-scheme BiVO4/Ag3VO4 composite was synthesized via a hydrothermal and chemical deposition process for the degradation of methylene blue. The composite showed strong redox ability under visible light. The 40%BiVO4/Ag3VO4 composite showed excellent photocatalytic degradation properties with a K-app of 0.05588 min(-1), which is 22.76 and 1.76 times higher than those of BiVO4 (0.00247 min(-1)) and Ag3VO4 (0.03167 min(-1)), respectively. The composite showed a stable performance and could retain 90% of its photocatalytic activity even after four cycles. The improved catalytic performance of the composite as compared to BiVO4 and Ag3VO4 can be attributed to its novel step-scheme mechanism, which facilitated the separation of the photogenerated charges and increased their lifetime. The photoluminescence measurement results and transient photocurrent response revealed that the composite showed efficient extraction of charge carriers. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 46, "End Page": 55, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63560-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63560-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, KH; Bai, Q; Kim, DH; Oh, DY; Zhu, YZ; Mo, YF; Jung, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Kern Ho; Bai, Qiang; Kim, Dong Hyeon; Oh, Dae Yang; Zhu, Yizhou; Mo, Yifei; Jung, Yoon Seok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design Strategies, Practical Considerations, and New Solution Processes of Sulfide Solid Electrolytes for All-Solid-State Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the ever-increasing safety concerns about conventional lithium-ion batteries, whose applications have expanded to include electric vehicles and grid-scale energy storage, batteries with solidified electrolytes that utilize nonflammable inorganic materials are attracting considerable attention. In particular, owing to their superionic conductivities (as high as approximate to 10(-2) S cm(-1)) and deformability, sulfide materials as the solid electrolytes (SEs) are considered the enabling material for high-energy bulk-type all-solid-state batteries. Herein the authors provide a brief review on recent progress in sulfide Li- and Na-ion SEs for all-solid-state batteries. After the basic principles in designing SEs are considered, the experimental exploration of multicomponent systems and ab initio calculations that accelerate the search for stronger candidates are discussed. Next, other issues and challenges that are critical for practical applications, such as instability in air, electrochemical stability, and compatibility with active materials, are discussed. Then, an emerging progress in liquid-phase synthesis and solution process of SEs and its relevant prospects in ensuring intimate ionic contacts and fabricating sheet-type electrodes is highlighted. Finally, an outlook on the future research directions for all-solid-state batteries employing sulfide superionic conductors is provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 484, "Times Cited, All Databases": 519, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2018, "Volume": 8, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800035, "DOI": "10.1002/aenm.201800035", "DOI Link": "http://dx.doi.org/10.1002/aenm.201800035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436103300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SW; Wang, G; Wang, Q; Jia, YD; Yi, J; Zhai, QJ; Liu, JB; Sun, BA; Chu, HJ; Shen, J; Liaw, PK; Liu, CT; Zhang, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, S. W.; Wang, G.; Wang, Q.; Jia, Y. D.; Yi, J.; Zhai, Q. J.; Liu, J. B.; Sun, B. A.; Chu, H. J.; Shen, J.; Liaw, P. K.; Liu, C. T.; Zhang, T. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of strength-ductility trade-off in a high-entropy alloy through a heterogeneous structure", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The improvement in strength is usually accompanied by ductility loss in structural materials, which is a long-standing conflict referred as the strength-ductility trade-off. Here we present a heterogeneous-structures-architecting strategy, in which we design bulk high-entropy alloys with the largely enhanced strength-ductility trade-off, possessing a yield strength of 711 MPa, a tensile strength of 928 MPa, and a uniform elongation of 30.3%. Such an enhancement of the strength-ductility trade-off is due to the microstructure comprised with a combination of the non-recrystallized and recrystallized grains arranged in complex heterogeneous structures with a characteristic dimension spanning from the submicron scale to the coarse-sized scale. The heterogeneous structures in the high-entropy alloy are produced by cold-rolling, followed by intermediate-temperature-annealing. Our results demonstrate that heterogeneous designs can be accomplished effectively by simple thermal treatments, which offer a design strategy towards a new generation of high-strength and high-ductility high-entropy alloys. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 165, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 444, "End Page": 458, "Article Number": null, "DOI": "10.1016/j.actamat.2018.12.012", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.12.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457665100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XS; Vasileff, A; Jiao, Y; Zheng, Y; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xuesi; Vasileff, Anthony; Jiao, Yon; Zheng, Yao; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic and Structural Engineering of Carbon-Based Metal-Free Electrocatalysts for Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since first being reported as possible electrocatalysts to substitute platinum for the oxygen reduction reaction (ORR), carbon-based metal-free nullomaterials have been considered a class of promising low-cost materials for clean and sustainable energy-conversion reactions. However, beyond the ORR, the development of carbon-based catalysts for other electrocatalytic reactions is still limited. More importantly, the intrinsic activity of most carbon-based metal-free catalysts is inadequate compared to their metal-based counterparts. To address this challenge, more design strategies are needed in order to improve the overall performance of carbon-based materials. Herein, using water splitting as an example, some state-of-the-art strategies in promoting carbon-based nullomaterials are summarized, including graphene, carbon nullotubes, and graphitic-carbon nitride, as highly active electrocatalysts for hydrogen evolution and oxygen evolution reactions. It is shown that by rationally tuning the electronic and/or physical structure of the carbon nullomaterials, adsorption of reaction intermediates is optimized, consequently improving the apparent electrocatalytic performance. These strategies may facilitate the development in this area and lead to the discovery of advanced carbon-based nullomaterials for various applications in energy-conversion processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 31, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803625, "DOI": "10.1002/adma.201803625", "DOI Link": "http://dx.doi.org/10.1002/adma.201803625", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463970200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dietl, T; Ohno, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dietl, Tomasz; Ohno, Hideo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dilute ferromagnetic semiconductors: Physics and spintronic structures", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This review compiles results of experimental and theoretical studies on thin films and quantum structures of semiconductors with randomly distributed Mn ions, which exhibit spintronic functionalities associated with collective ferromagnetic spin ordering. Properties of p-type Mn-containing III-V as well as II-VI, IV-VI, V-2 -VI3, I-II-V, and elemental group IV semiconductors are described, paying particular attention to the most thoroughly investigated system (Ga, Mn)As that supports the hole-mediated ferromagnetic order up to 190 K for the net concentration of Mn spins below 10%. Multilayer structures showing efficient spin injection and spin-related magnetotransport properties as well as enabling magnetization manipulation by strain, light, electric fields, and spin currents are presented together with their impact on metal spintronics. The challenging interplay between magnetic and electronic properties in topologically trivial and nontrivial systems is described, emphasizing the entangled roles of disorder and correlation at the carrier localization boundary. Finally, the case of dilute magnetic insulators is considered, such as (Ga, Mn)N, where low-temperature spin ordering is driven by short-ranged superexchange that is ferromagnetic for certain charge states of magnetic impurities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 798, "Times Cited, All Databases": 838, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2014, "Volume": 86, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1103/RevModPhys.86.187", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.86.187", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334225000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CY; Wang, B; Li, WB; Huang, SQ; Kong, L; Li, ZC; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Congyang; Wang, Bo; Li, Wanbin; Huang, Shouqiang; Kong, Long; Li, Zhichun; Li, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conversion of invisible metal-organic frameworks to luminescent perovskite nullocrystals for confidential information encryption and decryption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional smart fluorescent materials, which have been attracting increasing interest for security protection, are usually visible under either ambient or UV light, making them adverse to the potential application of confidential information protection. Herein, we report an approach to realize confidential information protection and storage based on the conversion of lead-based metal-organic frameworks (MOFs) to luminescent perovskite nullocrystals (NCs). Owing to the invisible and controlled printable characteristics of lead-based MOFs, confidential information can be recorded and encrypted by MOF patterns, which cannot be read through common decryption methods. Through our conversion strategy, highly luminescent perovskite NCs can be formed quickly and simply by using a halide salt trigger that reacts with the MOF, thus promoting effective information decryption. Finally, through polar solvents impregnation and halide salt conversion, the luminescence of the perovskite NCs can be quenched and recovered, leading to reversible on/off switching of the luminescence signal for multiple information encryption and decryption processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1138, "DOI": "10.1038/s41467-017-01248-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01248-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414031700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, J; Jeong, B; Kim, J; Nam, VB; Yoon, Y; Jung, J; Hong, S; Lee, H; Eom, H; Yeo, J; Choi, J; Lee, D; Ko, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Jaeho; Jeong, Buseong; Kim, Jinmo; Vu Binh Nam; Yoon, Yeosang; Jung, Jinwook; Hong, Sukjoon; Lee, Habeom; Eom, Hyeonjin; Yeo, Junyeob; Choi, Joonhwa; Lee, Daeho; Ko, Seung Hwan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive Wearable Temperature Sensor with Seamless Monolithic Integration", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate temperature field measurement provides critical information in many scientific problems. Herein, a new paradigm for highly sensitive, flexible, negative temperature coefficient (NTC) thermistor-based artificial skin is reported, with the highest temperature sensing ability reported to date among previously reported NTC thermistors. This artificial skin is achieved through the development of a novel monolithic laser-induced reductive sintering scheme and unique monolithic structures. The unique seamless monolithic structure simultaneously integrates two different components (a metal electrode and metal oxide sensing channel) from the same material at ambient pressure, which cannot be achieved by conventional heterogeneous integration through multiple, complex steps of photolithography or vacuum deposition. In addition to superior performance, electronic skin with high temperature sensitivity can be fabricated on heat-sensitive polymer substrates due to the low-temperature requirements of the process. As a proof of concept, temperature-sensitive artificial skin is tested with conformally attachable physiological temperature sensor arrays in the measurement of the temperatures of exhaled breath for the early detection of pathogenic progression in the respiratory system. The proposed highly sensitive flexible temperature sensor and monolithic selective laser reductive sintering are expected to greatly contribute to the development of essential components in various emerging research fields, including soft robotics and healthcare systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 32, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1905527, "DOI": "10.1002/adma.201905527", "DOI Link": "http://dx.doi.org/10.1002/adma.201905527", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494870400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XE; Zhang, C; Sawczyk, M; Yuan, QH; Chen, FF; Mendes, TC; Howlett, PC; Fu, CK; Kral, P; Hawker, CJ; Whittaker, A; Forsyth, M; Sun, J; Wang, YQ; Tan, X; Searles, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoen; Zhang, Cheng; Sawczyk, Michal; Yuan, Qinghong; Chen, Fangfang; Mendes, Tiago C.; Howlett, Patrick C.; Fu, Changkui; Kral, Petr; Hawker, Craig J.; Whittaker, Andrew; Forsyth, Maria; Sun, Ju; Wang, Yiqing; Tan, Xiao; Searles, Debra J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-stable all-solid-state sodium metal batteries enabled by perfluoropolyether-based electrolytes", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable batteries paired with sodium metal anodes are considered to be one of the most promising high-energy and low-cost energy-storage systems. However, the use of highly reactive sodium metal and the formation of sodium dendrites during battery operation have caused safety concerns, especially when highly flammable liquid electrolytes are used. Here we design and develop solvent-free solid polymer electrolytes (SPEs) based on a perfluoropolyether-terminated polyethylene oxide (PEO)-based block copolymer for safe and stable all-solid-state sodium metal batteries. Compared with traditional PEO SPEs, our results suggest that block copolymer design allows for the formation of self-assembled nullostructures leading to high storage modulus at elevated temperatures with the PEO domains providing transport channels even at high salt concentration (ethylene oxide/sodium = 8/2). Moreover, it is demonstrated that the incorporation of perfluoropolyether segments enhances the Na+ transference number of the electrolyte to 0.46 at 80 degrees C and enables a stable solid electrolyte interface. The new SPE exhibits highly stable symmetric cell-cycling performance at high current density (0.5 mA cm(-2) and 1.0 mAh cm(-2), up to 1,000 h). Finally, the assembled all-solid-state sodium metal batteries demonstrate outstanding capacity retention, long-term charge/discharge stability (Coulombic efficiency, 99.91%; >900 cycles with Na3V2(PO4)(3) cathode) and good capability with high loading NaFePO4 cathode (>1 mAh cm(-2)). Rechargeable batteries with sodium metal anodes are promising as energy-storage systems despite safety concerns related to reactivity and dendrite formation. Solvent-free perfluoropolyether-based electrolytes are now reported for safe and stable all-solid-state sodium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 21, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1057, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01296-0", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01296-0", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000820540500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lignos, I; Stavrakis, S; Nedelcu, G; Protesescu, L; Demello, AJ; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lignos, Ioannis; Stavrakis, Stavros; Nedelcu, Georgian; Protesescu, Loredana; deMello, Andrew J.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Cesium Lead Halide Perovskite nullocrystals in a Droplet-Based Microfluidic Platform: Fast Parametric Space Mapping", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prior to this work, fully inorganic nullocrystals of cesium lead halide perovskite (CsPbX3, X = Br, I, Cl and Cl/Br and Br/I mixed halide systems), exhibiting bright and tunable photoluminescence, have been synthesized using conventional batch (flask-based) reactions. Unfortunately, our understanding of the parameters governing the formation of these nullocrystals is still very limited due to extremely fast reaction kinetics and multiple variables involved in ion-metathesis-based synthesis of such multinary halide systems. Herein, we report the use of a droplet-based microfluidic platform for the synthesis of CsPbX3 nullocrystals. The combination of online photoluminescence and absorption measurements and the fast mixing of reagents within such a platform allows the rigorous and rapid mapping of the reaction parameters, including molar ratios of Cs, Pb, and halide precursors, reaction temperatures, and reaction times. This translates into enormous savings in reagent usage and screening times when compared to analogous batch synthetic approaches. The early-stage insight into the mechanism of nucleation of metal halide nullocrystals suggests similarities with multinary metal chalcogenide systems, albeit with much faster reaction kinetics in the case of halides. Furthermore, we show that microfluidics-optimized synthesis parameters are also directly transferrable to the conventional flask-based reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 557, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1869, "End Page": 1877, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b04981", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b04981", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371946300052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QX; Liu, ZG; Li, CG; Xie, KW; Zhu, P; Shao, BQ; Zhang, JM; Yang, JL; Zhang, J; Wang, Q; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qingxian; Liu, Zhiguang; Li, Chenggao; Xie, Kewei; Zhu, Pang; Shao, Biqi; Zhang, Jianming; Yang, Junlong; Zhang, Jin; Wang, Quan; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Transparent and Flexible Iontronic Pressure Sensors Based on an Opaque to Transparent Transition", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Human-computer interfaces, smart glasses, touch screens, and some electronic skins require highly transparent and flexible pressure-sensing elements. Flexible pressure sensors often apply a microstructured or porous active material to improve their sensitivity and response speed. However, the microstructures or small pores will result in high haze and low transparency of the device, and thus it is challenging to balance the sensitivity and transparency simultaneously in flexible pressure sensors or electronic skins. Here, for a capacitive-type sensor that consists of a porous polyvinylidene fluoride (PVDF) film sandwiched between two transparent electrodes, the challenge is addressed by filling the pores with ionic liquid that has the same refractive index with PVDF, and the transmittance of the film dramatically boosts from 0 to 94.8% in the visible range. Apart from optical matching, the ionic liquid also significantly improves the signal intensity as well as the sensitivity due to the formation of an electric double layer at the dielectric-electrode interfaces, and improves the toughness and stretchability of the active material benefiting from a plasticization effect. Such transparent and flexible sensors will be useful in smart windows, invisible bands, and so forth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000348, "DOI": "10.1002/advs.202000348", "DOI Link": "http://dx.doi.org/10.1002/advs.202000348", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536690400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, WZ; Tang, X; Guo, X; Choi, S; Wang, CY; Gogotsi, Y; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Weizhai; Tang, Xiao; Guo, Xin; Choi, Sinho; Wang, Chengyin; Gogotsi, Yury; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Cryo-Dried MXene for Efficient Capacitive Deionization", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aerogel-like, porous Ti3C2Tx MXene architecture electrode displayed a high electroadsorption capacity for capacitive deionization of saline water. A vacuum freeze-drying process was employed to prevent the restacking of MXene nullosheets due to van der Waals forces, leading to the formation of a porous structure with a large specific surface area. When applied as electrode materials for capacitive deionization, porous MXene demonstrated a high specific capacitance of 156 F/g and a volumetric capacitance of 410 F/cm(3) in 1 M sodium chloride (NaCl) electrolyte. The porous Ti3C2Tx MXene electrodes can deliver a high electroadsorption capacity of 118 mg/cm(3) (45 mg/g) in 10,000 mg/L NaCl solution (applied voltage: 1 2 V) and excellent cycling stability (up to 60 cycles) in comparison with the restacked MXene and activated carbon electrodes, indicating its promising potential for desalination applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 778, "End Page": 787, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.018", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435091900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Outlook on Lithium Ion Battery Technology", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium ion batteries as a power source are dominating in portable electronics, penetrating the electric vehicle market, and on the verge of entering the utility market for grid-energy storage. Depending on the application, trade-offs among the various performance parameters. energy, power, cycle life, cost, safety, and environmental impact. are often needed, which are linked to severe materials chemistry challenges. The current lithium ion battery technology is based on insertion-reaction electrodes and organic liquid electrolytes. With an aim to increase the energy density or optimize the other performance parameters, new electrode materials based on both insertion reaction and dominulltly conversion reaction along with solid electrolytes and lithium metal anode are being intensively pursued. This article presents an outlook on lithium ion technology by providing first the current status and then the progress and challenges with the ongoing approaches. In light of the formidable challenges with some of the approaches, the article finally points out practically viable near-term strategies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1183, "Times Cited, All Databases": 1298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1063, "End Page": 1069, "Article Number": null, "DOI": "10.1021/acscentsci.7b00288", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00288", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413697100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CW; Hong, J; May, AF; Bansal, D; Chi, S; Hong, T; Ehlers, G; Delaire, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, C. W.; Hong, J.; May, A. F.; Bansal, D.; Chi, S.; Hong, T.; Ehlers, G.; Delaire, O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orbitally driven giant phonon anharmonicity in SnSe", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding elementary excitations and their couplings in condensed matter systems is critical for developing better energy-conversion devices. In thermoelectric materials, the heat-to-electricity conversion efficiency is directly improved by suppressing the propagation of phonon quasiparticles responsible for macroscopic thermal transport. The current record material for thermoelectric conversion efficiency, SnSe, has an ultralow thermal conductivity, but the mechanism behind the strong phonon scattering remains largely unknown. From inelastic neutron scattering measurements and first-principles simulations, we mapped the four-dimensional phonon dispersion surfaces of SnSe, and found the origin of the ionic-potential anharmonicity responsible for the unique properties of SnSe. We show that the giant phonon scattering arises from an unstable electronic structure, with orbital interactions leading to a ferroelectric-like lattice instability. The present results provide a microscopic picture connecting electronic structure and phonon anharmonicity in SnSe, and offers new insights on how electron-phonon and phonon-phonon interactions may lead to the realization of ultralow thermal conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 580, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1063, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3492", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3492", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365898400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, Y; Fang, Y; Miao, QQ; Zhen, X; Ding, D; Pu, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Yan; Fang, Yuan; Miao, Qingqing; Zhen, Xu; Ding, Dan; Pu, Kanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intraparticle Molecular Orbital Engineering of Semiconducting Polymer nulloparticles as Amplified Theranostics for in Vivo Photoacoustic Imaging and Photothermal Therapy", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical theranostic nulloagents that seamlessly and synergistically integrate light-generated signals with photothermal or photodynamic therapy can provide opportunities for cost-effective precision medicine, while the potential for clinical translation requires them to have good biocompatibility and high imaging/therapy performance. We herein report an intraparticle molecular orbital engineering approach to simultaneously enhance photoacoustic brightness and photothermal therapy efficacy of semiconducting polymer nulloparticles (SPNs) for in vivo imaging and treatment of cancer. The theranostic SPNs have a binary optical component nullostructure, wherein a near-infrared absorbing semiconducting polymer and an ultrasmall carbon dot (fullerene) interact with each other to induce photoinduced electron transfer upon light irradiation. Such an intraparticle optoelectronic interaction augments heat generation and consequently enhances the photoacoustic signal and maximum photothermal temperature of SPNs by 2.6- and 1.3-fold, respectively. With the use of the amplified SPN as the theranostic nulloagent, it permits enhanced photoacoustic imaging and photothermal ablation of tumor in living mice. Our study thus not only introduces a category of purely organic optical theranostics but also highlights a molecular guideline to amplify the effectiveness of light intensive imaging and therapeutic nullosystems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 474, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4472, "End Page": 4481, "Article Number": null, "DOI": "10.1021/acsnullo.6b00168", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b00168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375245000065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lau, VWH; Moudrakovski, I; Botari, T; Weinberger, S; Mesch, MB; Duppel, V; Senker, J; Blum, V; Lotsch, BV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lau, Vincent Wing-hei; Moudrakovski, Igor; Botari, Tiago; Weinberger, Simon; Mesch, Maria B.; Duppel, Viola; Senker, Juergen; Blum, Volker; Lotsch, Bettina V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The heptazine-based polymer melon (also known as graphitic carbon nitride, g-C3N4) is a promising photocatalyst for hydrogen evolution. Nonetheless, attempts to improve its inherently low activity are rarely based on rational approaches because of a lack of fundamental understanding of its mechanistic operation. Here we employ molecular heptazine-based model catalysts to identify the cyanamide moiety as a photocatalytically relevant 'defect'. We exploit this knowledge for the rational design of a carbon nitride polymer populated with cyanamide groups, yielding a material with 12 and 16 times the hydrogen evolution rate and apparent quantum efficiency (400 nm), respectively, compared with the unmodified melon. Computational modelling and material characterization suggest that this moiety improves coordination (and, in turn, charge transfer kinetics) to the platinum co-catalyst and enhances the separation of the photogenerated charge carriers. The demonstrated knowledge transfer for rational catalyst design presented here provides the conceptual framework for engineering high-performance heptazine-based photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 684, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12165, "DOI": "10.1038/ncomms12165", "DOI Link": "http://dx.doi.org/10.1038/ncomms12165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380305400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peterson, EJ; Delariva, AT; Lin, S; Johnson, RS; Guo, H; Miller, JT; Kwak, JH; Peden, CHF; Kiefer, B; Allard, LF; Ribeiro, FH; Datye, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peterson, Eric J.; Delariva, Andrew T.; Lin, Sen; Johnson, Ryan S.; Guo, Hua; Miller, Jeffrey T.; Kwak, Ja Hun; Peden, Charles H. F.; Kiefer, Boris; Allard, Lawrence F.; Ribeiro, Fabio H.; Datye, Abhaya K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on alumina", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Catalysis by single isolated atoms of precious metals has attracted much recent interest, as it promises the ultimate in atom efficiency. Most previous reports are on reducible oxide supports. Here we show that isolated palladium atoms can be catalytically active on industrially relevant g-alumina supports. The addition of lanthanum oxide to the alumina, long known for its ability to improve alumina stability, is found to also help in the stabilization of isolated palladium atoms. Aberration-corrected scanning transmission electron microscopy and operando X-ray absorption spectroscopy confirm the presence of intermingled palladium and lanthanum on the gamma-alumina surface. Carbon monoxide oxidation reactivity measurements show onset of catalytic activity at 40 degrees C. The catalyst activity can be regenerated by oxidation at 700 degrees C in air. The high-temperature stability and regenerability of these ionic palladium species make this catalyst system of potential interest for low-temperature exhaust treatment catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 573, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4885, "DOI": "10.1038/ncomms5885", "DOI Link": "http://dx.doi.org/10.1038/ncomms5885", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342983300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ketov, SV; Sun, YH; Nachum, S; Lu, Z; Checchi, A; Beraldin, AR; Bai, HY; Wang, WH; Louzguine-Luzgin, DV; Carpenter, MA; Greer, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ketov, S. V.; Sun, Y. H.; Nachum, S.; Lu, Z.; Checchi, A.; Beraldin, A. R.; Bai, H. Y.; Wang, W. H.; Louzguine-Luzgin, D. V.; Carpenter, M. A.; Greer, A. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rejuvenation of metallic glasses by non-affine thermal strain", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When a spatially uniform temperature change is imposed on a solid with more than one phase, or on a polycrystal of a single, non-cubic phase (showing anisotropic expansion-contraction), the resulting thermal strain is inhomogeneous (non-affine). Thermal cycling induces internal stresses, leading to structural and property changes that are usually deleterious. Glasses are the solids that form on cooling a liquid if crystallization is avoided-they might be considered the ultimate, uniform solids, without the microstructural features and defects associated with polycrystals. Here we explore the effects of cryogenic thermal cycling on glasses, specifically metallic glasses. We show that, contrary to the null effect expected from uniformity, thermal cycling induces rejuvenation, reaching less relaxed states of higher energy. We interpret these findings in the context that the dynamics in liquids become heterogeneous on cooling towards the glass transition(1), and that there may be consequent heterogeneities in the resulting glasses. For example, the vibrational dynamics of glassy silica at long wavelengths are those of an elastic continuum, but at wavelengths less than approximately three nullometres the vibrational dynamics are similar to those of a polycrystal with anisotropic grains(2). Thermal cycling of metallic glasses is easily applied, and gives improvements in compressive plasticity. The fact that such effects can be achieved is attributed to intrinsic non-uniformity of the glass structure, giving a non-uniform coefficient of thermal expansion. While metallic glasses may be particularly suitable for thermal cycling, the non-affine nature of strains in glasses in general deserves further study, whether they are induced by applied stresses or by temperature change.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 628, "Times Cited, All Databases": 661, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2015, "Volume": 524, "Issue": 7564, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 200, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature14674", "DOI Link": "http://dx.doi.org/10.1038/nature14674", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359386900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, PP; Pei, W; Wang, XW; Ma, YF; Jiang, QK; Liang, J; Zhou, S; Zhao, JJ; Liu, J; Lu, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Panpan; Pei, Wei; Wang, Xiaowei; Ma, Yanfu; Jiang, Qike; Liang, Ji; Zhou, Si; Zhao, Jijun; Liu, Jian; Lu, Gao Qing (Max)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional Electrochemical HER Performance with Enhanced Electron Transfer between Ru nulloparticles and Single Atoms Dispersed on a Carbon Substrate", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precisely regulating the electronic structures of metal active species is highly desirable for electrocatalysis. However, carbon with inert surface provide weak metal-support interaction, which is insufficient to modulate the electronic structures of metal nulloparticles. Herein, we propose a new method to control the electrocatalytic behavior of supported metal nulloparticles by dispersing single metal atoms on an O-doped graphene. Ideal atomic metal species are firstly computationally screened. We then verify this concept by deposition of Ru nulloparticles onto an O-doped graphene decorated with single metal atoms (e.g., Fe, Co, and Ni) for hydrogen evolution reaction (HER). Consistent with theoretical predictions, such hybrid catalysts show outstanding HER performance, much superior to other reported electrocatalysts such as the state-of-the-art Pt/C. This work offers a new strategy for modulating the activity and stability of metal nulloparticles for electrocatalysis processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2021, "Volume": 60, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16044, "End Page": 16050, "Article Number": null, "DOI": "10.1002/anie.202103557", "DOI Link": "http://dx.doi.org/10.1002/anie.202103557", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661297300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Calik, M; Auras, F; Salonen, LM; Bader, K; Grill, I; Handloser, M; Medina, DD; Dogru, M; Löbermann, F; Trauner, D; Hartschuh, A; Bein, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Calik, Mona; Auras, Florian; Salonen, Laura M.; Bader, Kathrin; Grill, Irene; Handloser, Matthias; Medina, Dana D.; Dogru, Mirjam; Loebermann, Florian; Trauner, Dirk; Hartschuh, Achim; Bein, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraction of Photogenerated Electrons and Holes from a Covalent Organic Framework Integrated Heterojunction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) offer a strategy to position molecular semiconductors within a rigid network in a highly controlled and predictable manner. The pi-stacked columns of layered two-dimensional COFs enable electronic interactions between the COF sheets, thereby providing a path for exciton and charge carrier migration. Frameworks comprising two electronically separated subunits can form highly defined interdigitated donor-acceptor heterojunctions, which can drive the photogeneration of free charge carriers. Here we report the first example of a photovoltaic device that utilizes exclusively a crystalline organic framework with an inherent type II heterojunction as the active layer. The newly developed triphenylene-porphyrin COF was grown as an oriented thin film with the donor and acceptor units forming one-dimensional stacks that extend along the substrate normal, thus providing an optimal geometry for charge carrier transport. As a result of the degree of morphological precision that can be achieved with COFs and the enormous diversity of functional molecular building blocks that can be used to construct the frameworks, these materials show great potential as model systems for organic heterojunctions and might ultimately provide an alternative to the current disordered bulk heterojunctions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 24", "Publication Year": 2014, "Volume": 136, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17802, "End Page": 17807, "Article Number": null, "DOI": "10.1021/ja509551m", "DOI Link": "http://dx.doi.org/10.1021/ja509551m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347139200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JS; Yi, XH; Xu, XT; Ji, HD; Alanazi, AM; Wang, CC; Zhao, C; Kaneti, YV; Wang, P; Liu, W; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jia-Sheng; Yi, Xiao-Hong; Xu, Xingtao; Ji, Haodong; Alanazi, Amer M.; Wang, Chong-Chen; Zhao, Chen; Kaneti, Yusuf Valentino; Wang, Peng; Liu, Wen; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Eliminating tetracycline antibiotics matrix via photoactivated sulfate radical-based advanced oxidation process over the immobilized MIL-88A: Batch and continuous experiments", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work demonstrates the successful immobilization of MIL-88A(Fe) MOF on cotton fibers to fabricate MIL-88A (Fe)/cotton fibers (MC) by an eco-friendly method. The prepared MC is used to activate peroxydisulfate for eliminating multiple tetracycline antibiotics, such as oxytetracycline (OTC), tetracycline (TTC), and chlortetracycline (CTC) in simulated wastewater under UV-light irradiation. The photoactivated sulfate radical-advanced oxidation processes (SR-AOPs) towards the removal of tetracycline antibiotics matrix (initial concentration of 10.0 mg/L) using MC were initially investigated using a batch method. The results reveal that 97.5% OTC, 95.2% TTC, and 100.0% CTC can be degraded in the MC/UV/PDS system in the presence of 2 g/L of MC and 1 mM of PDS. The degradation pathways of OTC, TTC, and CTC were clarified via liquid chromatography-mass spectrometry analysis and DFT calculations. The quantitative structure-activity relationship analysis shows that the tetracycline antibiotics are transformed into their corresponding intermediates with lower toxicity within 8.0 min. A self-designed fixed bed reactor, in which the MC was packed into the annular channel, was adopted to test the long-term operation possibility of the MC in the continuous photoactivated SR-AOP system. The findings demonstrate that the whole antibiotics matrix can be removed completely within 22 h. This work is the first to demonstrate the use of MOFs as catalysts for SR-AOP to achieve continuous purification of simulated wastewater. The findings highlight a new possibility for the use of MOFs in large-scale wastewater treatment over.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 431, "Issue": null, "Part Number": 3, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 133213, "DOI": "10.1016/j.cej.2021.133213", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.133213", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790277800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, XC; Yu, P; Wu, D; Singh, B; Zeng, QS; Lin, H; Zhou, W; Lin, JH; Suenaga, K; Liu, Z; Wang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Xuechao; Yu, Peng; Wu, Di; Singh, Bahadur; Zeng, Qingsheng; Lin, Hsin; Zhou, Wu; Lin, Junhao; Suenaga, Kazu; Liu, Zheng; Wang, Qi Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically thin noble metal dichalcogenide: a broadband mid-infrared semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interest in mid-infrared technologies surrounds plenty of important optoelectronic applications ranging from optical communications, biomedical imaging to night vision cameras, and so on. Although narrow bandgap semiconductors, such as Mercury Cadmium Telluride and Indium Antimonide, and quantum superlattices based on inter-subband transitions in wide bandgap semiconductors, have been employed for mid-infrared applications, it remains a daunting challenge to search for other materials that possess suitable bandgaps in this wavelength range. Here, we demonstrate experimentally for the first time that twodimensional (2D) atomically thin PtSe2 has a variable bandgap in the mid-infrared via layer and defect engineering. Here, we show that bilayer PtSe2 combined with defects modulation possesses strong light absorption in the mid-infrared region, and we realize a mid-infrared photoconductive detector operating in a broadband mid-infrared range. Our results pave the way for atomically thin 2D noble metal dichalcogenides to be employed in high-performance mid-infrared optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1545, "DOI": "10.1038/s41467-018-03935-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03935-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430286800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, JM; Cao, Y; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jeong Min; Cao, Yuan; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable strongly coupled superconductivity in magic-angle twisted trilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moire superlattices(1,2) have recently emerged as a platform upon which correlated physics and superconductivity can be studied with unprecedented tunability(3-6). Although correlated effects have been observed in several other moire system(7-17), magic-angle twisted bilayergraphene remains the only one in which robust superconductivity has been reproducibly measured(4-6). Here we realize a moire superconductor in magic-angle twisted trilayer graphene (MATTG)(18), which has better tunability of its electronic structure and superconducting properties than magic-angle twisted bilayer graphene. Measurements ofthe Hall effect and quantum oscillations as a function of density and electric field enable us to determine the tunable phase boundaries of the system in the normal metallic state. Zero-magnetic-field resistivity measurements reveal that the existence of superconductivity is intimately connected to the broken-symmetry phase that emerges from two carriers per moire unit cell. We find that the superconducting phase is suppressed and bounded at the Van Hove singularities that partially surround the broken-symmetry phase, which is difficult to reconcile with weak-coupling Bardeen-Cooper-Schrieffer theory. Moreover, the extensive in situ tunability of our system allows us to reach the ultrastrong-coupling regime, characterized by a Ginzburg-Landau coherence length that reaches the average inter-particle distance, and very large T-BKT/F, values, in excess of 0.1 (where T-BKT and T-F are the Berezinskii-Kosterlitz-Thouless transition and Fermi temperatures, respectively). These observations suggest that MATTG can be electrically tuned close to the crossover to a two-dimensional Bose-Einstein condensate. Our results establish a family of tunable moire superconductors that have the potential to revolutionize our fundamental understanding of and the applications for strongly coupled superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 613, "Times Cited, All Databases": 673, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2021, "Volume": 590, "Issue": 7845, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03192-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03192-0", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613628300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, WS; Gao, X; Li, Q; Li, HP; Chao, YH; Li, MJ; Mahurin, SM; Li, HM; Zhu, HY; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Wenshuai; Gao, Xiang; Li, Qian; Li, Hongping; Chao, Yanhong; Li, Meijun; Mahurin, Shannon M.; Li, Huaming; Zhu, Huiyuan; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlled Gas Exfoliation of Boron Nitride into Few-Layered nullosheets", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The controlled exfoliation of hexagonal boron nitride (h-BN) into single- or few-layered nullosheets remains a grand challenge and becomes the bottleneck to essential studies and applications of h-BN. Here, we present an efficient strategy for the scalable synthesis of few-layered h-BN nullosheets (BNNS) using a novel gas exfoliation of bulk h-BN in liquid N-2 (L-N-2). The essence of this strategy lies in the combination of a high temperature triggered expansion of bulk h-BN and the cryogenic L-N-2 gasification to exfoliate the h-BN. The produced BNNS after ten cycles (BNNS-10) consisted primarily of fewer than five atomic layers with a high mass yield of 16-20%. N-2 sorption and desorption isotherms show that the BNNS-10 exhibited a much higher specific surface area of 278m(2)g(-1) than that of bulk BN (10m(2)g(-1)). Through the investigation of the exfoliated intermediates combined with a theoretical calculation, we found that the huge temperature variation initiates the expansion and curling of the bulk h-BN. Subseqently, the L-N-2 penetrates into the interlayers of h-BN along the curling edge, followed by an immediate drastic gasification of L-N-2, further peeling off h-BN. This novel gas exfoliation of high surface area BNNS not only opens up potential opportunities for wide applications, but also can be extended to produce other layered materials in high yields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2016, "Volume": 55, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10766, "End Page": 10770, "Article Number": null, "DOI": "10.1002/anie.201605515", "DOI Link": "http://dx.doi.org/10.1002/anie.201605515", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383473600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, XL; Constantin, L; Lu, YF; Silvain, JF; Nastasi, M; Cui, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Xueliang; Constantin, Loic; Lu, Yongfeng; Silvain, Jean-Francois; Nastasi, Michael; Cui, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "(Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramics with low thermal conductivity", "Source Title": "JOURNAL OF THE AMERICAN CERAMIC SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel high-entropy carbide ceramic, (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C, with a single-phase rock salt structure, was synthesized by spark plasma sintering. X-ray diffraction confirmed the formation of a single-phase rock salt structure at 26-1140 degrees C in Argon atmosphere, in which the 5 metal elements may share a cation position while the C element occupies the anion position. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C exhibits a much lower thermal diffusivity and conductivity than the binary carbides HfC, ZrC, TaC, and TiC, which may result from the significant phonon scattering at its distorted anion sublattice. (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C inherits the high elastic modulus and hardness of the binary carbide ceramics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 101, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4486, "End Page": 4491, "Article Number": null, "DOI": "10.1111/jace.15779", "DOI Link": "http://dx.doi.org/10.1111/jace.15779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440554000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saidaminov, MI; Adinolfi, V; Comin, R; Abdelhady, AL; Peng, W; Dursun, I; Yuan, M; Hoogland, S; Sargent, EH; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saidaminov, Makhsud I.; Adinolfi, Valerio; Comin, Riccardo; Abdelhady, Ahmed L.; Peng, Wei; Dursun, Ibrahim; Yuan, Mingjian; Hoogland, Sjoerd; Sargent, Edward H.; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Planar-integrated single-crystalline perovskite photodetectors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid perovskites are promising semiconductors for optoelectronic applications. However, they suffer from morphological disorder that limits their optoelectronic properties and, ultimately, device performance. Recently, perovskite single crystals have been shown to overcome this problem and exhibit impressive improvements: low trap density, low intrinsic carrier concentration, high mobility, and long diffusion length that outperform perovskite-based thin films. These characteristics make the material ideal for realizing photodetection that is simultaneously fast and sensitive; unfortunately, these macroscopic single crystals cannot be grown on a planar substrate, curtailing their potential for optoelectronic integration. Here we produce large-area planar-integrated films made up of large perovskite single crystals. These crystalline films exhibit mobility and diffusion length comparable with those of single crystals. Using this technique, we produced a high-performance light detector showing high gain (above 10(4) electrons per photon) and high gain-bandwidth product (above 10(8) Hz) relative to other perovskite-based optical sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 621, "Times Cited, All Databases": 636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8724, "DOI": "10.1038/ncomms9724", "DOI Link": "http://dx.doi.org/10.1038/ncomms9724", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366290600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, CW; Jiang, ZJ; Qi, SB; Wang, PX; Jensen, LR; Johansen, M; Christensen, CK; Zhang, YF; Ravnsbaek, DB; Yue, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Chengwei; Jiang, Zhenjing; Qi, Shibin; Wang, Peixing; Jensen, Lars Rosgaard; Johansen, Morten; Christensen, Christian Kolle; Zhang, Yanfei; Ravnsbaek, Dorthe Bomholdt; Yue, Yuanzheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Glass Anode with an Exceptional Cycling-Induced Capacity Enhancement for Lithium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) hold great promise as high-energy anode materials for next-generation lithium-ion batteries (LIBs) due to their tunable chemistry, pore structure and abundant reaction sites. However, the pore structure of crystalline MOFs tends to collapse during lithium-ion insertion and extraction, and hence, their electrochemical performances are rather limited. As a critical breakthrough, a MOF glass anode for LIBs has been developed in the present work. In detail, it is fabricated by melt-quenching Cobalt-ZIF-62 (Co(Im)(1.75)(bIm)(0.25)) to glass, and then by combining glass with carbon black and binder. The derived anode exhibits high lithium storage capacity (306 mAh g(-1) after 1000 cycles at of 2 A g(-1)), outstanding cycling stability, and superior rate performance compared with the crystalline Cobalt-ZIF-62 and the amorphous one prepared by high-energy ball-milling. Importantly, it is found that the Li-ion storage capacity of the MOF glass anode continuously rises with charge-discharge cycling and even tripled after 1000 cycles. Combined spectroscopic and structural analyses, along with density functional theory calculations, reveal the origin of the cycling-induced enhancement of the performances of the MOF glass anode, that is, the increased distortion and local breakage of the Co-N coordination bonds making the Li-ion intercalation sites more accessible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 34, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110048, "DOI": "10.1002/adma.202110048", "DOI Link": "http://dx.doi.org/10.1002/adma.202110048", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748520600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, S; Kucharczyk, CJ; Liang, YG; Zhang, XH; Takeuchi, I; Ji, HI; Haile, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Sihyuk; Kucharczyk, Chris J.; Liang, Yangang; Zhang, Xiaohang; Takeuchi, Ichiro; Ji, Ho-Il; Haile, Sossina M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past several years, important strides have been made in demonstrating protonic ceramic fuel cells (PCFCs). Such fuel cells offer the potential of environmentally sustainable and cost-effective electric power generation. However, their power outputs have lagged behind predictions based on their high electrolyte conductivities. Here we overcome PCFC performance and stability challenges by employing a high-activity cathode, PrBa0.5Sr0.5Co1.5Fe0.5O5+delta (PBSCF), in combination with a chemically stable electrolyte, BaZr0.4Ce0.4Y0.1Yb0.1O3 (BZCYYb4411). We deposit a thin dense interlayer film of the cathode material onto the electrolyte surface to mitigate contact resistance, an approach which is made possible by the proton permeability of PBSCF. The peak power densities of the resulting fuel cells exceed 500 mW cm(-2) at 500 degrees C, while also offering exceptional, long-term stability under CO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 680, "Times Cited, All Databases": 721, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 202, "End Page": 210, "Article Number": null, "DOI": "10.1038/s41560-017-0085-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-017-0085-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427602200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peters, RJRW; Marguet, M; Marais, S; Fraaije, MW; van Hest, JCM; Lecommandoux, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peters, Ruud J. R. W.; Marguet, Maite; Marais, Sebastien; Fraaije, Marco W.; van Hest, Jan C. M.; Lecommandoux, Sebastien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cascade Reactions in Multicompartmentalized Polymersomes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzyme-filled polystyrene-b-poly(3-(isocyano-L-alanyl-aminoethyl)thiophene) (PS-b-PIAT) nulloreactors are encapsulated together with free enzymes and substrates in a larger polybutadiene-b-poly(ethylene oxide) (PB-b-PEO) polymersome, forming a multicompartmentalized structure, which shows structural resemblance to the cell and its organelles. An original cofactor-dependent three-enzyme cascade reaction is performed, using either compatible or incompatible enzymes, which takes place across multiple compartments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2014, "Volume": 53, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 146, "End Page": 150, "Article Number": null, "DOI": "10.1002/anie.201308141", "DOI Link": "http://dx.doi.org/10.1002/anie.201308141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000328714900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XF; Zhang, SL; Sim, WL; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xue Feng; Zhang, Song Lin; Sim, Wei Lok; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorized CoNi2S4 Yolk-Shell Spheres for Highly Efficient Hydrogen Production via Water and Urea Electrolysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring earth-abundant electrocatalysts with excellent activity, robust stability, and multiple functions is crucial for electrolytic hydrogen generation. Porous phosphorized CoNi2S4 yolk-shell spheres (P-CoNi2S4 YSSs) were rationally designed and synthesized by a combined hydrothermal sulfidation and gas-phase phosphorization strategy. Benefiting from the strengthened Ni3+/Ni2+ couple, enhanced electronic conductivity, and hollow structure, the P-CoNi2S4 YSSs exhibit excellent activity and durability towards hydrogen/oxygen evolution and urea oxidation reactions in alkaline solution, affording low potentials of -0.135 V, 1.512 V, and 1.306 V (versus reversible hydrogen electrode) at 10 mA cm(-2), respectively. Remarkably, when used as the anode and cathode simultaneously, the P-CoNi2S4 catalyst merely requires a cell voltage of 1.544 V in water splitting and 1.402 V in urea electrolysis to attain 10 mA cm(-2) with excellent durability for 100 h, outperforming most of the reported nickel-based sulfides and even noble-metal-based electrocatalysts. This work promotes the application of sulfides in electrochemical hydrogen production and provides a feasible approach for urea-rich wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2021, "Volume": 60, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22885, "End Page": 22891, "Article Number": null, "DOI": "10.1002/anie.202108563", "DOI Link": "http://dx.doi.org/10.1002/anie.202108563", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694648200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, YH; Chang, TH; Zhang, HL; Yao, CH; Zheng, QF; Yang, VW; Mi, HY; Kim, M; Cho, SJ; Park, DW; Jiang, H; Lee, J; Qiu, YJ; Zhou, WD; Cai, ZY; Gong, SQ; Ma, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Yei Hwan; Chang, Tzu-Hsuan; Zhang, Huilong; Yao, Chunhua; Zheng, Qifeng; Yang, Vina W.; Mi, Hongyi; Kim, Munho; Cho, Sang June; Park, Dong-Wook; Jiang, Hao; Lee, Juhwan; Qiu, Yijie; Zhou, Weidong; Cai, Zhiyong; Gong, Shaoqin; Ma, Zhenqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance green flexible electronics based on biodegradable cellulose nullofibril paper", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Today's consumer electronics, such as cell phones, tablets and other portable electronic devices, are typically made of non-renewable, non-biodegradable, and sometimes potentially toxic (for example, gallium arsenide) materials. These consumer electronics are frequently upgraded or discarded, leading to serious environmental contamination. Thus, electronic systems consisting of renewable and biodegradable materials and minimal amount of potentially toxic materials are desirable. Here we report high-performance flexible microwave and digital electronics that consume the smallest amount of potentially toxic materials on biobased, biodegradable and flexible cellulose nullofibril papers. Furthermore, we demonstrate gallium arsenide microwave devices, the consumer wireless workhorse, in a transferrable thin-film form. Successful fabrication of key electrical components on the flexible cellulose nullofibril paper with comparable performance to their rigid counterparts and clear demonstration of fungal biodegradation of the cellulose-nullofibril-based electronics suggest that it is feasible to fabricate high-performance flexible electronics using ecofriendly materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 724, "Times Cited, All Databases": 779, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7170, "DOI": "10.1038/ncomms8170", "DOI Link": "http://dx.doi.org/10.1038/ncomms8170", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355534400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uekert, T; Kasap, H; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uekert, Taylor; Kasap, Hatice; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoreforming of Nonrecyclable Plastic Waste over a Carbon Nitride/Nickel Phosphide Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With over 8 billion tons of plastic produced since 1950, polymers represent one of the most widely used-and most widely discarded-materials. Ambient-temperature photoreforming offers a simple and low-energy means for transforming plastic waste into fuel and bulk chemicals but has previously only been reported using precious-metal- or Cd-based photocatalysts. Here, an inexpensive and nontoxic carbon nitride/nickel phosphide (CNxINi2P) photocatalyst is utilized to successfully reform poly(ethylene terephthalate) (PET) and poly(lactic acid) (PLA) to clean H-2 fuel and a variety of organic chemicals under alkaline aqueous conditions. Ni2P synthesized on cyanamide-functionalized carbon nitride is shown to promote efficient charge separation and catalysis, with a photostability of at least 5 days. The real-world applicability of photoreforming is further verified by generating H-2 and organics from a selection of nonrecyclable waste-including microplastics (polyester microfibers) and food-contaminated plastic-and upscaling the system from 2 to 120 mL while maintaining its efficiency for plastic conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2019, "Volume": 141, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15201, "End Page": 15210, "Article Number": null, "DOI": "10.1021/jacs.9b06872", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b06872", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488322500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Christians, JA; Schulz, P; Tinkham, JS; Schloemer, TH; Harvey, SP; de Villers, BJT; Sellinger, A; Berry, JJ; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.; Schloemer, Tracy H.; Harvey, Steven P.; de Villers, Bertrand J. Tremolet; Sellinger, Alan; Berry, Joseph J.; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term device stability is the most pressing issue that impedes perovskite solar cell commercialization, given the achieved 22.7% efficiency. The perovskite absorber material itself has been heavily scrutinized for being prone to degradation by water, oxygen and ultraviolet light. To date, most reports characterize device stability in the absence of these extrinsic factors. Here we show that, even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells can retain 94% of peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). Each interface and contact layer throughout the device stack plays an important role in the overall stability which, when appropriately modified, yields devices in which both the initial rapid decay (often termed burn-in) and the gradual slower decay are suppressed. This extensively modified device architecture and the understanding developed will lead towards durable long-term device performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 744, "Times Cited, All Databases": 799, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 68, "End Page": 74, "Article Number": null, "DOI": "10.1038/s41560-017-0067-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-017-0067-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419976100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, JD; Mura, C; Lampe, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, James D.; Mura, Cameron; Lampe, Kyle J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stimuli-Responsive, Pentapeptide, nullofiber Hydrogel for Tissue Engineering", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Short peptides are uniquely versatile building blocks for self-assembly. Supramolecular peptide assemblies can be used to construct functional hydrogel biomaterials-an attractive approach for neural tissue engineering. Here, we report a new class of short, five-residue peptides that form hydrogels with nullofiber structures. Using rheology and spectroscopy, we describe how sequence variations, pH, and peptide concentration alter the mechanical properties of our pentapeptide hydrogels. We find that this class of seven unmodified peptides forms robust hydrogels from 0.2-20 kPa at low weight percent (less than 3 wt %) in cell culture media and undergoes shear-thinning and rapid self-healing. The peptides self-assemble into long fibrils with sequence-dependent fibrillar morphologies. These fibrils exhibit a unique twisted ribbon shape, as visualized by transmission electron microscopy (TEM) and Cryo-EM imaging, with diameters in the low tens of nullometers and periodicities similar to amyloid fibrils. Experimental gelation behavior corroborates our molecular dynamics simulations, which demonstrate peptide assembly behavior, an increase in beta-sheet content, and patterns of variation in solvent accessibility. Our rapidly assembling pentapeptides for injectable delivery (RAPID) hydrogels are syringe-injectable and support cytocompatible encapsulation of oligodendrocyte progenitor cells (OPCs), as well as their proliferation and three-dimensional process extension. Furthermore, RAPID gels protect OPCs from mechanical membrane disruption and acute loss of viability when ejected from a syringe needle, highlighting the protective capability of the hydrogel as potential cell carriers for transplantation therapies. The tunable mechanical and structural properties of these supramolecular assemblies are shown to be permissive to cell expansion and remodeling, making this hydrogel system suitable as an injectable material for cell delivery and tissue engineering applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 141, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4886, "End Page": 4899, "Article Number": null, "DOI": "10.1021/jacs.8b13363", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b13363", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462950800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, CX; Guo, YH; Guan, WX; Lu, HY; Shi, W; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Chuxin; Guo, Youhong; Guan, Weixin; Lu, Hengyi; Shi, Wen; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyzwitterionic Hydrogels for Efficient Atmospheric Water Harvesting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atmospheric water harvesting (AWH) is regarded as one of the promising strategies for freshwater production desirable to provide sustainable water for landlocked and arid regions. Hygroscopic materials have attracted widespread attention because of their water harvesting performance. However, the introduction of many inorganic salts often leads to aggregation and leakage issues in practical use. Here, polyzwitterionic hydrogels are developed as an effective AWH material platform. Via anti-polyelectrolyte effects, the hygroscopic salt coordinated with polymer chains could capture moisture and enhance the swelling property, leading to a strong moisture sorption capacity. The hydrogel shows superior AWH performance (0.62 g g(-1), 120 minutes for equilibrium at 30 % relative humidity) and produces 5.87 L kg(-1) freshwater per day. It is anticipated that the polyzwitterionic hydrogels with unique salt-responsive properties could provide new insights into the design and synthesis of next-generation AWH materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2022, "Volume": 61, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202200271", "DOI": "10.1002/anie.202200271", "DOI Link": "http://dx.doi.org/10.1002/anie.202200271", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753680000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LC; Lopez-Haro, M; Lopes, CW; Rojas-Buzo, S; Concepcion, P; Manzorro, R; Simonelli, L; Sattler, A; Serna, P; Calvino, JJ; Corma, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Lichen; Lopez-Haro, Miguel; Lopes, Christian W.; Rojas-Buzo, Sergio; Concepcion, Patricia; Manzorro, Ramon; Simonelli, Laura; Sattler, Aaron; Serna, Pedro; Calvino, Jose J.; Corma, Avelino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural modulation and direct measurement of subnullometric bimetallic PtSn clusters confined in zeolites", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modulating the structures of subnullometric metal clusters at the atomic level is a great synthetic and characterization challenge in catalysis. Here, we show how the catalytic properties of subnullometric platinum clusters (0.5-0.6 nm) confined in the sinusoidal 10R channels of purely siliceous MFI zeolite are modulated upon introduction of partially reduced tin species that interact with the noble metal at the metal/support interface. The platinum-tin clusters are stable in H(2)over an extended period of time (>6 h), even at high temperatures (for example, 600 degrees C), which is determined by only a few additional tin atoms added to the platinum clusters. The structural features of platinum-tin clusters, which are not immediately visible by conventional characterization techniques but can be established after combination of in situ extended X-ray absorption fine structure, high-angle annular dark-field scanning transmission electron microscopy and CO infrared data, are key to providing a one-order of magnitude lower deactivation rate in the propane dehydrogenation reaction while maintaining high intrinsic (initial) catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 628, "End Page": 638, "Article Number": null, "DOI": "10.1038/s41929-020-0472-7", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0472-7", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542101500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XT; Shi, WX; Jin, Z; Huang, WF; Lin, J; Ma, GS; Li, SZ; Guo, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaotian; Shi, Wenxiong; Jin, Zhao; Huang, Weifeng; Lin, Jie; Ma, Guanshui; Li, Shuzhou; Guo, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Remarkable SERS Activity Observed from Amorphous ZnO nullocages", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancement of the semiconductor-molecule interaction, in particular, promoting the interfacial charge transfer process (ICTP), is key to improving the sensitivity of semiconductor-based surface enhanced Raman scattering (SERS). Herein, by developing amorphous ZnO nullocages (a-ZnO NCs), we successfully obtained an ultrahigh enhancement factor of up to 6.62 X 10(5). This remarkable SERS sensitivity can be attributed to high-efficiency ICTP within a-ZnO NC molecule system, which is caused by metastable electronic states of a-ZnO NCs. First-principles density functional theory (DFT) simulations further confirmed a stronger ICTP in a-ZnO NCs than in their crystalline counterparts. The efficient ICTP can even generate pi bonding in Zn-S bonds peculiar to the mercapto molecule adsorbed a-ZnO NCs, which has been verified through the X-ray absorption near-edge structure (XANES) characterization. To the best of our knowledge, this is the first time such remarkable SERS activity has been observed within amorphous semiconductor nullomaterials, which could open a new frontier for developing highly sensitive and stable SERS technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2017, "Volume": 56, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9851, "End Page": 9855, "Article Number": null, "DOI": "10.1002/anie.201705187", "DOI Link": "http://dx.doi.org/10.1002/anie.201705187", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406798700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Dong, XL; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Long; Dong, Xiaoli; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-cost alkaline water electrolysis has been considered a sustainable approach to producing hydrogen using renewable energy inputs, but preventing hydrogen/oxygen mixing and efficiently using the instable renewable energy are challenging. Here, using nickel hydroxide as a redox mediator, we decouple the hydrogen and oxygen production in alkaline water electrolysis, which overcomes the gas-mixing issue and may increase the use of renewable energy. In this architecture, the hydrogen production occurs at the cathode by water reduction, and the anodic Ni(OH)(2) is simultaneously oxidized into NiOOH. The subsequent oxygen production involves a cathodic NiOOH reduction (NiOOH -> Ni(OH)(2)) and an anodic OH- oxidization. Alternatively, the NiOOH formed during hydrogen production can be coupled with a zinc anode to form a NiOOH-Zn battery, and its discharge product (that is, Ni(OH)(2)) can be used to produce hydrogen again. This architecture brings a potential solution to facilitate renewables-to-hydrogen conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11741, "DOI": "10.1038/ncomms11741", "DOI Link": "http://dx.doi.org/10.1038/ncomms11741", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376206800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, N; Dufresne, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Ning; Dufresne, Alain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose in biomedicine: Current status and future prospect", "Source Title": "EUROPEAN POLYMER JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocellulose, a unique and promising natural material extracted from native cellulose, has gained much attention for its use as biomedical material, because of its remarkable physical properties, special surface chemistry and excellent biological properties (biocompatibility, biodegradability and low toxicity). Three different types of nullocellulose, viz. cellulose nullocrystals (CNC), cellulose nullofibrils (CNF) and bacterial cellulose (BC), are introduced and compared in terms of production, properties and biomedical applications in this article. The advancement of nullocellulose-based biomedical materials is summarized and discussed on the analysis of latest studies (especially reports from the past five years). Selected studies with significant findings are emphasized, and focused topics for nullocellulose in biomedicine research in this article include the discussion at the level of molecule (e.g. tissue bioscaffolds for cellular culture; drug excipient and drug delivery; and immobilization and recognition of enzyme/protein) as well as at the level of macroscopic biomaterials (e.g. blood vessel and soft tissue substitutes; skin and bone tissue repair materials; and antimicrobial materials). Functional modification of nullocellulose will determine the potential biomedical application for nullocellulose, which is also introduced as a separated section in the article. Finally, future perspectives and possible research points are proposed in Section 5. (C) 2014 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1147, "Times Cited, All Databases": 1216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 59, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 302, "End Page": 325, "Article Number": null, "DOI": "10.1016/j.eurpolymj.2014.07.025", "DOI Link": "http://dx.doi.org/10.1016/j.eurpolymj.2014.07.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343341100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, SS; Li, Q; Xue, HG; Pang, H; Xu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Shasha; Li, Qing; Xue, Huaiguo; Pang, Huan; Xu, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly alkaline-stable metal oxide@metal-organic framework composite for high-performance electrochemical energy storage", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most metal-organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co3O4 nullocube@Co-MOF (Co3O4@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co3O4@Co-MOF composite shows a specific capacitance as high as 1020 F g(-1) at 0.5 A g(-1) and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g(-1). The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm(-3).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 541, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 305, "End Page": 314, "Article Number": null, "DOI": "10.1093/nsr/nwz137", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwz137", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528014900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoo, JS; Rong, X; Liu, YS; Kolpak, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoo, Jong Suk; Rong, Xi; Liu, Yusu; Kolpak, Alexie M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of Lattice Oxygen Participation in Understanding Trends in the Oxygen Evolution Reaction on Perovskites", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study demonstrates the importance of considering lattice oxygen participation in understanding trends in the oxygen evolution reaction (OER) on ABO(3) (A = lanthanum or strontium, B = transition metal) perovskites. Using density functional theory, we show that the lattice oxygen mechanism (LOM) can lead to higher OER activity than the conventional adsorbate evolving mechanism (AEM) by minimizing the thermodynamically required overpotential. We also show that the OER activity volcano for AEM is universal for all perovskites, whereas that for LOM depends on the identity of the A cation in ABO3. This explains experimental observations that perovskites such as Pr0.5Ba0.5CoO3-delta and SrCoO3-delta show higher OER activities than the conventionally predicted optimum compounds such as LaNiO3 and SrCoO3. Furthermore, we show that LOM is preferred to AEM in achieving bifunctional catalysts capable of promoting both OER and ORR Using our overall activity volcano, we finally suggest several candidate materials that are predicted to be highly active for OER via LOM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4628, "End Page": 4636, "Article Number": null, "DOI": "10.1021/acscatal.8b00612", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b00612", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431727300099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dvorák, F; Camellone, MF; Tovt, A; Tran, ND; Negreiros, FR; Vorokhta, M; Skála, T; Matolínová, I; Myslivecek, J; Matolín, V; Fabris, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dvorak, Filip; Camellone, Matteo Farnesi; Tovt, Andrii; Nguyen-Dung Tran; Negreiros, Fabio R.; Vorokhta, Mykhailo; Skala, Tomas; Matolinova, Iva; Myslivecek, Josef; Matolin, Vladimir; Fabris, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creating single-atom Pt-ceria catalysts by surface step decoration", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts maximize the utilization of supported precious metals by exposing every single metal atom to reactants. To avoid sintering and deactivation at realistic reaction conditions, single metal atoms are stabilized by specific adsorption sites on catalyst substrates. Here we show by combining photoelectron spectroscopy, scanning tunnelling microscopy and density functional theory calculations that Pt single atoms on ceria are stabilized by the most ubiquitous defects on solid surfaces-monoatomic step edges. Pt segregation at steps leads to stable dispersions of single Pt2+ ions in planar PtO4 moieties incorporating excess O atoms and contributing to oxygen storage capacity of ceria. We experimentally control the step density on our samples, to maximize the coverage of monodispersed Pt2+ and demonstrate that step engineering and step decoration represent effective strategies for understanding and design of new single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10801, "DOI": "10.1038/ncomms10801", "DOI Link": "http://dx.doi.org/10.1038/ncomms10801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371041600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Sun, N; Zhu, QZ; Soomro, RA; Xu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, He; Sun, Ning; Zhu, Qizhen; Soomro, Razium Ali; Xu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microcrystalline Hybridization Enhanced Coal-Based Carbon Anode for Advanced Sodium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) are regarded as a kind of promising candidate for large-scale energy storage technology. The development of advanced carbon anodes with high Na-storage capacity and initial Coulombic efficiency (ICE) from low cost, resources abundant precursors is critical for SIBs. Here, a carbon microcrystalline hybridization route to synthesize hard carbons with extensive pseudo-graphitic regions from lignite coal with the assistance of sucrose is proposed. Employing the cross-linked interaction between sucrose and lignite coal to generate carbon-based hybrid microcrystalline states, the obtained hard carbons possess pseudo-graphitic dominullt phases with large interlayer spaces that facilitate Na ion's storage and transportation, as well as fewer surface defects that guarantee high ICE. The LCS-73 with an optimum cross-link demonstrates the highest Na-storage capacity of 356 mAh g(-1) and an ICE of 82.9%. The corresponding full-cell delivers a high energy density of 240 Wh kg(-1) (based on the mass of anode and cathode materials) and excellent rate capability of 106 mAh g(-1) at 10 C in addition to outstanding cycle performance with 80% retention over 500 cycles at 2 C. The proposed work offers an efficient route to develop high-performance, low-cost carbon-based anode materials with potential application for advanced SIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 9, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200023, "DOI": "10.1002/advs.202200023", "DOI Link": "http://dx.doi.org/10.1002/advs.202200023", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790500300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Fu, TM; Cheng, ZG; Hong, GS; Zhou, T; Jin, LH; Duvvuri, M; Jiang, Z; Kruskal, P; Xie, C; Suo, ZG; Fang, Y; Lieber, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jia; Fu, Tian-Ming; Cheng, Zengguang; Hong, Guosong; Zhou, Tao; Jin, Lihua; Duvvuri, Madhavi; Jiang, Zhe; Kruskal, Peter; Xie, Chong; Suo, Zhigang; Fang, Ying; Lieber, Charles M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Syringe-injectable electronics", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seamless and minimally invasive three-dimensional interpenetration of electronics within artificial or natural structures could allow for continuous monitoring and manipulation of their properties. Flexible electronics provide a means for conforming electronics to non-planar surfaces, yet targeted delivery of flexible electronics to internal regions remains difficult. Here, we overcome this challenge by demonstrating the syringe injection (and subsequent unfolding) of sub-micrometre-thick, centimetre-scale macroporous mesh electronics through needles with a diameter as small as 100 mu m. Our results show that electronic components can be injected into man-made and biological cavities, as well as dense gels and tissue, with >90% device yield. We demonstrate several applications of syringe-injectable electronics as a general approach for interpenetrating flexible electronics with three-dimensional structures, including (1) monitoring internal mechanical strains in polymer cavities, (2) tight integration and low chronic immunoreactivity with several distinct regions of the brain, and (3) in vivo multiplexed neural recording. Moreover, syringe injection enables the delivery of flexible electronics through a rigid shell, the delivery of large-volume flexible electronics that can fill internal cavities, and co-injection of electronics with other materials into host structures, opening up unique applications for flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 605, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 629, "End Page": "+", "Article Number": null, "DOI": "10.1038/NnullO.2015.115", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2015.115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357485600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, M; Hong, J; Lopez, J; Sun, YM; Feng, DW; Lim, K; Chueh, WC; Toney, MF; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Minah; Hong, Jihyun; Lopez, Jeffrey; Sun, Yongming; Feng, Dawei; Lim, Kipil; Chueh, William C.; Toney, Michael F.; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance sodium-organic battery by realizing four-sodium storage in disodium rhodizonate", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) for grid-scale applications need active materials that combine a high energy density with sustainability. Given the high theoretical specific capacity 501 mAh g(-1), and Earth abundance of disodium rhodizonate (Na2C6O6), it is one of the most promising cathodes for SIBs. However, substantially lower reversible capacities have been obtained compared with the theoretical value and the understanding of this discrepancy has been limited. Here, we reveal that irreversible phase transformation of Na2C6O6 during cycling is the origin of the deteriorating redox activity of Na2C6O6. The active-particle size and electrolyte conditions were identified as key factors to decrease the activation barrier of the phase transformation during desodiation. On the basis of this understanding, we achieved four-sodium storage in a Na2C6O6 electrode with a reversible capacity of 484 mAh g(-1), an energy density of 726 Wh kg(cathode)(-1), an energy efficiency above 87% and a good cycle retention.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41560-017-0014-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-017-0014-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418243200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YJ; Li, SJ; Wang, HL; Hou, WT; Hao, YL; Yang, R; Sercombe, TB; Zhang, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Y. J.; Li, S. J.; Wang, H. L.; Hou, W. T.; Hao, Y. L.; Yang, R.; Sercombe, T. B.; Zhang, L. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure, defects and mechanical behavior of beta-type titanium porous structures manufactured by electron beam melting and selective laser melting", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigates the differences in the microstructure, defects and mechanical behavior of porous structures from a beta-type Ti-24Nb-4Zr-8Sn manufactured by electron beam melting (EBM) and selective laser melting (SLM). The phases, size and shape of melt pool, volume and distribution of defects are analyzed and correlated to the compressive mechanical and fatigue properties. Due to different powder bed temperatures, the microstructure of EBM and SLM samples consists of alpha+beta phases and a single phase, respectively. The faster cooling rate during SLM promotes the formation of fine beta dendrites, which leads to a higher compressive strength (50 +/- 0.9 MPa) and lower Young's Modulus (0.95 +/- 0.05 GPa) in comparison to the EBM parts (45 +/- 1.1 MPa and 1.34 +/- 0.04 GPa respectively). The large defects present within solid strut are likely a result of tin vaporization. The tin vapor is more easily trapped during the SLM process due to a smaller laser spot size and a faster cooling rate. This results in a 10 times increase in the number of defects. These defects have a limited influence on both the static properties and low stresses level fatigue strength, but it causes a reduced and variable fatigue life at high stresses level. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 113, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 56, "End Page": 67, "Article Number": null, "DOI": "10.1016/j.actamat.2016.04.029", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.04.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378670300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, H; Rao, SR; Kapustin, EA; Zhao, L; Yang, S; Yaghi, OM; Wang, EN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyunho; Rao, Sameer R.; Kapustin, Eugene A.; Zhao, Lin; Yang, Sungwoo; Yaghi, Omar M.; Wang, Evelyn N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption-based atmospheric water harvesting device for arid climates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water scarcity is a particularly severe challenge in arid and desert climates. While a substantial amount of water is present in the form of vapour in the atmosphere, harvesting this water by state-of-the-art dewing technology can be extremely energy intensive and impractical, particularly when the relative humidity (RH) is low (i.e., below similar to 40% RH). In contrast, atmospheric water generators that utilise sorbents enable capture of vapour at low RH conditions and can be driven by the abundant source of solar-thermal energy with higher efficiency. Here, we demonstrate an air-cooled sorbent-based atmospheric water harvesting device using the metal-organic framework (MOF)-801 [Zr6O4(OH)(4)(fumarate)(6)] operating in an exceptionally arid climate (10-40% RH) and sub-zero dew points (Tempe, Arizona, USA) with a thermal efficiency (solar input to water conversion) of similar to 14%. We predict that this device delivered over 0.25 L of water per kg of MOF for a single daily cycle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 571, "Times Cited, All Databases": 623, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1191, "DOI": "10.1038/s41467-018-03162-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03162-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428039500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, RZ; Chen, DC; Waller, G; Ouyang, YP; Chen, Y; Zhao, BT; Rainwater, B; Yang, CH; Zhu, M; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Renzong; Chen, Dongchang; Waller, Gordon; Ouyang, Yunpeng; Chen, Yu; Zhao, Bote; Rainwater, Ben; Yang, Chenghao; Zhu, Min; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dramatically enhanced reversibility of Li2O in SnO2-based electrodes: the effect of nullostructure on high initial reversible capacity", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of irreversible Li2O during discharge is believed to be the main cause of large capacity loss and low Coulombic efficiency of oxide negative electrodes for Li batteries. This assumption may have misguided the development of high-capacity SnO2-based anodes in recent years. Here we demonstrated that contrary to this perception, Li2O can indeed be highly reversible in a SnO2 electrode with controlled nullostructure and achieved an initial Coulombic efficiency of similar to 95.5%, much higher than that previously believed to be possible (52.4%). In situ spectroscopic and diffraction analyses corroborate highly reversible electrochemical cycling, suggesting that the interfaces and grain boundaries of nullo-sized SnO2 may suppress the coarsening of Sn and enable the conversion between Li2O and Sn to amorphous SnO2 when de-lithiated. These results provide important insight into the rational design of high-performance oxide electrodes for Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 595, "End Page": 603, "Article Number": null, "DOI": "10.1039/c5ee03367e", "DOI Link": "http://dx.doi.org/10.1039/c5ee03367e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369744500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, ZD; Yang, QS; Xu, Y; Guo, SY; Sun, WW; Liu, H; Lv, LP; Zhang, Y; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Zhendong; Yang, Qinsi; Xu, Yi; Guo, Siyu; Sun, Weiwei; Liu, Hao; Lv, Li-Ping; Zhang, Yong; Wang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymeric molecules have been heralded as promising electrode materials for the next-generation energy-storage technologies owing to their chemical flexibility at the molecular level, environmental benefit, and cost advantage. However, before any practical implementation takes place, the low capacity, poor structural stability, and sluggish ion/electron diffusion kinetics remain the obstacles that have to be overcome. Here, we report the synthesis of a few-layered two-dimensional covalent organic framework trapped by carbon nullotubes as the anode of lithium-ion batteries. Remarkably, upon activation, this organic electrode delivers a large reversible capacity of 1536 mAh g(-1) and can sustain 500 cycles at 100 mA g(-1). Aided by theoretical calculations and electrochemical probing of the electrochemical behavior at different stages of cycling, the storage mechanism is revealed to be governed by 14-electron redox chemistry for a covalent organic framework monomer with one lithium ion per C=N group and six lithium ions per benzene ring. This work may pave the way to the development of high-capacity electrodes for organic rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 576, "DOI": "10.1038/s41467-018-02889-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-02889-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424451600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, SL; Zhao, BJ; Li, MC; Wang, H; Zhu, JY; Li, QT; Gao, HC; Feng, Q; Cao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Shuangli; Zhao, Bangjiao; Li, Maocai; Wang, Hao; Zhu, Jiayi; Li, Qingtao; Gao, Huichang; Feng, Qi; Cao, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microenvironment responsive nullocomposite hydrogel with NIR photothermal therapy, vascularization and anti-inflammation for diabetic infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial infection, excessive inflammation and damaging blood vessels network are the major factors to delay the healing of diabetic ulcer. At present, most of wound repair materials are passive and can't response to the wound microenvironment, resulting in a low utilization of bioactive substances and hence a poor therapeutic effect. Therefore, it's essential to design an intelligent wound dressing responsive to the wound microenviron-ment to achieve the release of drugs on-demand on the basis of multifunctionality. In this work, metformin-laden CuPDA NPs composite hydrogel (Met@ CuPDA NPs/HG) was fabricated by dynamic phenylborate bonding of gelatin modified by dopamine (Gel-DA), Cu-loaded polydopamine nulloparticles (CuPDA NPs) with hyaluronic acid modified by phenyl boronate acid (HA-PBA), which possessed good injectability, self-healing, adhesive and DPPH scavenging performance. The slow release of metformin was achieved by the interaction with CuPDA NPs, boric groups (B-N coordination) and the constraint of hydrogel network. Metformin had a pH and glucose responsive release behavior to treat different wound microenvironment intelligently. Moreover, CuPDA NPs endowed the hydrogel excellent photothermal responsiveness to kill bacteria of >95% within 10 min and also the slow release of Cu2+ to protect wound from infection for a long time. Met@ CuPDA NPs/HG also recruited cells to a certain direction and promoted vascularization by releasing Cu2+. More importantly, Met@CuPDA NPs/HG effectively decreased the inflammation by eliminating ROS and inhibiting the activation of NF-kappa B pathway. Animal experiments demonstrated that Met@CuPDA NPs/HG significantly promoted wound healing of diabetic SD rats by killing bacteria, inhibiting inflammation, improving angiogenesis and accelerating the deposition of ECM and collagen. Therefore, Met@CuPDA NPs/HG had a great application potential for diabetic wound healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 306, "End Page": 320, "Article Number": null, "DOI": "10.1016/j.bioactmat.2023.03.005", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2023.03.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955053000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bobbert, FSL; Lietaert, K; Eftekhari, AA; Pouran, B; Ahmadi, SM; Weinulls, H; Zadpoor, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bobbert, F. S. L.; Lietaert, K.; Eftekhari, A. A.; Pouran, B.; Ahmadi, S. M.; Weinulls, H.; Zadpoor, A. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additively manufactured metallic porous biomaterials based on minimal surfaces: A unique combination of topological, mechanical, and mass transport properties", "Source Title": "ACTA BIOMATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous biomaterials that simultaneously mimic the topological, mechanical, and mass transport properties of bone are in great demand but are rarely found in the literature. In this study, we rationally designed and additively manufactured (AM) porous metallic biomaterials based on four different types of triply periodic minimal surfaces (TPMS) that mimic the properties of bone to an unprecedented level of multi-physics detail. Sixteen different types of porous biomaterials were rationally designed and fabricated using selective laser melting (SLM) from a titanium alloy (Ti-6Al-4V). The topology, quasi-static mechanical properties, fatigue resistance, and permeability of the developed biomaterials were then characterized. In terms of topology, the biomaterials resembled the morphological properties of trabecular bone including mean surface curvatures close to zero. The biomaterials showed a favorable but rare combination of relatively low elastic properties in the range of those observed for trabecular bone and high yield strengths exceeding those reported for cortical bone. This combination allows for simultaneously avoiding stress shielding, while providing ample mechanical support for bone tissue regeneration and osseointegration. Furthermore, as opposed to other AM porous biomaterials developed to date for which the fatigue endurance limit has been found to be of their yield (or plateau) stress, some of the biomaterials developed in the current study show extremely high fatigue resistance with endurance limits up to 60% of their yield stress. It was also found that the permeability values measured for the developed biomaterials were in the range of values reported for trabecular bone. In summary, the developed porous metallic biomaterials based on TPMS mimic the topological, mechanical, and physical properties of trabecular bone to a great degree. These properties make them potential candidates to be applied as parts of orthopedic implants and/or as bone-substituting biomaterials. Statement of Significance Bone-substituting biomaterials aim to mimic bone properties. Although mimicking some of bone properties is feasible, biomaterials that could simultaneously mimic all or most of the relevant bone properties are rare. We used rational design and additive manufacturing to develop porous metallic biomaterials that exhibit an interesting combination of topological, mechanical, and mass transport properties. The topology of the developed biomaterials resembles that of trabecular bone including a mean curvature close to zero. Moreover, the developed biomaterials show an unusual combination of low elastic modulus to avoid stress shielding and high strength to provide mechanical support. The fatigue resistance of the developed biomaterials is also exceptionally high, while their permeability is in the range of values reported for bone. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 586, "Times Cited, All Databases": 625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2017, "Volume": 53, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 572, "End Page": 584, "Article Number": null, "DOI": "10.1016/j.actbio.2017.02.024", "DOI Link": "http://dx.doi.org/10.1016/j.actbio.2017.02.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401679100050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vitaku, E; Gannett, CN; Carpenter, KL; Shen, LX; Abruña, HD; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vitaku, Edon; Gannett, Cara N.; Carpenter, Keith L.; Shen, Luxi; Abruna, Hector D.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phenazine-Based Covalent Organic Framework Cathode Materials with High Energy and Power Densities", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Redox-active covalent organic frameworks (COFs) are promising materials for energy storage devices because of their high density of redox sites, permanent and controlled porosity, high surface areas, and tunable structures. However, the low electrochemical accessibility of their redox-active sites has limited COF-based devices either to thin films (<250 nm) grown on conductive substrates or to thicker films (1 pm) when a conductive polymer is introduced into the COF pores. Electrical energy storage devices constructed from bulk microcrystalline COF powders, eliminating the need for both thin-film formation and conductive polymer guests, would offer both improved capacity and potentially scalable fabrication processes. Here we report on the synthesis and electrochemical evaluation of a new phenazine-based 2D COF (DAPH-TFP COF), as well as its composite with poly(3,4-ethylenedioxythiophene) (PEDOT). Both the COF and its PEDOT composite were evaluated as powders that were solution-cast onto bulk electrodes serving as current collectors. The unmodified DAPH-TFP COF exhibited excellent electrical access to its redox sites, even without PEDOT functionalization, and outperformed the PEDOT composite of our previously reported anthraquinone-based system. Devices containing DAPH-TFP COF were able to deliver both high-energy and high-power densities, validating the promise of unmodified redox-active COFs that are easily incorporated into electrical energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2020, "Volume": 142, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16, "End Page": 20, "Article Number": null, "DOI": "10.1021/jacs.9b08147", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b08147", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507144400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martindale, BCM; Hutton, GAM; Caputo, CA; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martindale, Benjamin C. M.; Hutton, Georgina A. M.; Caputo, Christine A.; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar Hydrogen Production Using Carbon Quantum Dots and a Molecular Nickel Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon quantum dots (CQDs) are established as excellent photosensitizers in combination with a molecular catalyst for solar light driven hydrogen production in aqueous solution. The inexpensive CQDs an be prepared, by straightforward thermolysis of citric acid in a simple one-pot,, multigram synthesis and are therefore scalable. The CQDs produced reducing equivalents under solar irradiation in a homogeneous photocatalytic system: with a Ni-bis-(diphosphine) catalyst, giving: an activity of 398 mu mol(H2) (g(CQD))(-1) h(-1) and a per Ni catalyst turnover frequency of 41 h(-1). The CQDs displayed activity in the visible region beyond lambda > 4:55 Am and maintained their full photocatalytic, activity for at least 1 day under full Solar spectrum irradiation. A high quantum efficiency of 1.4% was recorded for the noble- and toxic-metal free photocatalytic system. Thus, CQDs are shown to be a highly sustainable light absorbing material for photocatalytic schemes, which are not limited by cost, toxicity, or lack of scalability. The photocatalytic hybrid system was limited by the lifetime of the molecular catalyst, and intriguingly, no photo catalytic activity Was observed using the CQDs and 3d transition metal salts or platinum precursors: This observation highlights the advantage of using a molecular catalyst over commonly used:heterogeneous catalysts in this photocatalytic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 534, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2015, "Volume": 137, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6018, "End Page": 6025, "Article Number": null, "DOI": "10.1021/jacs.5b01650", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b01650", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354910500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, QN; Chen, ZJ; Shao, Y; Gong, XQ; Wang, HF; Liu, XH; Parker, SF; Han, X; Yang, SH; Wang, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Qineng; Chen, Zongjia; Shao, Yi; Gong, Xueqing; Wang, Haifeng; Liu, Xiaohui; Parker, Stewart F.; Han, Xue; Yang, Sihai; Wang, Yanqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct hydrodeoxygenation of raw woody biomass into liquid alkanes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Being the only sustainable source of organic carbon, biomass is playing an ever-increasingly important role in our energy landscape. The conversion of renewable lignocellulosic biomass into liquid fuels is particularly attractive but extremely challenging due to the inertness and complexity of lignocellulose. Here we describe the direct hydrodeoxygenation of raw woods into liquid alkanes with mass yields up to 28.1 wt% over a multifunctional Pt/NbOPO4 catalyst in cyclohexane. The superior performance of this catalyst allows simultaneous conversion of cellulose, hemicellulose and, more significantly, lignin fractions in the wood sawdust into hexane, pentane and alkylcyclohexanes, respectively. Investigation on the molecular mechanism reveals that a synergistic effect between Pt, NbOx species and acidic sites promotes this highly efficient hydrodeoxygenation of bulk lignocellulose. No chemical pretreatment of the raw woody biomass or separation is required for this one-pot process, which opens a general and energy-efficient route for converting raw lignocellulose into valuable alkanes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11162, "DOI": "10.1038/ncomms11162", "DOI Link": "http://dx.doi.org/10.1038/ncomms11162", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373293800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Edri, E; Kirmayer, S; Henning, A; Mukhopadhyay, S; Gartsman, K; Rosenwaks, Y; Hodes, G; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Edri, Eran; Kirmayer, Saar; Henning, Alex; Mukhopadhyay, Sabyasachi; Gartsman, Konstantin; Rosenwaks, Yossi; Hodes, Gary; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Why Lead Methylammonium Tri-Iodide Perovskite-Based Solar Cells Require a Mesoporous Electron Transporting Scaffold (but Not Necessarily a Hole Conductor)", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CH3NH3PbI3-based solar cells were characterized with electron beam-induced current (EBIC) and compared to CH3NH3PbI3-xClx ones. A spatial map of charge separation efficiency in working cells shows p-i-n structures for both thin film cells. Effective diffusion lengths, L-D, (from EBIC profile) show that holes are extracted significantly more efficiently than electrons in CH3NH3PbI3, explaining why CH3NH3PbI3-based cells require mesoporous electron conductors, while CH3NH3PbI3-xClx ones, where L-D values are comparable for both charge types, do not.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 526, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1000, "End Page": 1004, "Article Number": null, "DOI": "10.1021/nl404454h", "DOI Link": "http://dx.doi.org/10.1021/nl404454h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331343900092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, J; Guo, HZ; Baker, AL; Lanagan, MT; Kupp, ER; Messing, GL; Randall, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Jing; Guo, Hanzheng; Baker, Amanda L.; Lanagan, Michael T.; Kupp, Elizabeth R.; Messing, Gary L.; Randall, Clive A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cold Sintering: A Paradigm Shift for Processing and Integration of Ceramics", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper describes a sintering technique for ceramics and ceramic-based composites, using water as a transient solvent to effect densification (i.e. sintering) at temperatures between room temperature and 200 degrees C. To emphasize the incredible reduction in sintering temperature relative to conventional thermal sintering this new approach is named the Cold Sintering Process (CSP). Basically CSP uses a transient aqueous environment to effect densification by a mediated dissolution-precipitation process. CSP of NaCl, alkali molybdates and V2O5 with small concentrations of water are described in detail, but the process is extended and demonstrated for a diverse range of chemistries (oxides, carbonates, bromides, fluorides, chlorides and phosphates), multiple crystal structures, and multimaterial applications. Furthermore, the properties of selected CSP samples are demonstrated to be essentially equivalent as samples made by conventional thermal sintering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2016, "Volume": 55, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11457, "End Page": 11461, "Article Number": null, "DOI": "10.1002/anie.201605443", "DOI Link": "http://dx.doi.org/10.1002/anie.201605443", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383748900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, BY; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Bu Yuan; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of Single-Holed Cobalt/N-Doped Carbon Hollow Particles with Enhanced Electrocatalytic Activity toward Oxygen Reduction Reaction in Alkaline Media", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design and construction of metal-organic framework (MOF) composite precursors have recently been considered as a promising strategy for the preparation of different structured metal/carbon-based functional materials. Here, an MOF composite-assisted strategy to synthesize single-holed cobalt/N-doped carbon hollow particles is reported. The yolk-shell polystyrene@zeolitic imidazolate framework-67 (PS@ZIF-67) composite precursors are first synthesized, followed by a controlled pyrolysis to obtain cobalt/N-doped carbon hollow particles with a large single hole on each shell. Moreover, the MOF-coating approach reported in this work can be extended to prepare various core-shell ZIF-67 composites with different structures and compositions. Benefiting from the structural and compositional advantages, the as-derived single-holed cobalt/N-doped carbon hollow particles manifest superior electrocatalytic oxygen reduction performance with high activity and excellent durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700247, "DOI": "10.1002/advs.201700247", "DOI Link": "http://dx.doi.org/10.1002/advs.201700247", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413166700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Liu, XH; Schubert, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xin; Liu, Xianhu; Schubert, Dirk W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Sensitive Ultrathin Flexible Thermoplastic Polyurethane/Carbon Black Fibrous Film Strain Sensor with Adjustable Scaffold Networks", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsThe sensors displayed high sensitivity (8962.7), fast response time (60 ms), outstanding stability and durability (>10,000 cycles) and widely workable stretching range (0-160%).A theoretical approach was used to analyze mechanical property, and a model based on tunneling theory was modified to describe the relative change of resistance.Two equations were proposed and offered an effective but simple approach to analyze the change of number of conductive paths and distance of adjacent conductive particles. AbstractIn recently years, high-performance wearable strain sensors have attracted great attention in academic and industrial. Herein, a conductive polymer composite of electrospun thermoplastic polyurethane (TPU) fibrous film matrix-embedded carbon black (CB) particles with adjustable scaffold network was fabricated for high-sensitive strain sensor. This work indicated the influence of stereoscopic scaffold network structure built under various rotating speeds of collection device in electrospinning process on the electrical response of TPU/CB strain sensor. This structure makes the sensor exhibit combined characters of high sensitivity under stretching strain (gauge factor of 8962.7 at 155% strain), fast response time (60 ms), outstanding stability and durability (>10,000 cycles) and a widely workable stretching range (0-160%). This high-performance, wearable, flexible strain sensor has a broad vision of application such as intelligent terminals, electrical skins, voice measurement and human motion monitoring. Moreover, a theoretical approach was used to analyze mechanical property and a model based on tunneling theory was modified to describe the relative change of resistance upon the applied strain. Meanwhile, two equations based from this model were first proposed and offered an effective but simple approach to analyze the change of number of conductive paths and distance of adjacent conductive particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64, "DOI": "10.1007/s40820-021-00592-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00592-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613667500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JC; Zhuang, ZC; Cao, KC; Gao, GH; Wang, C; Lai, FL; Lu, SL; Ma, PM; Dong, WF; Liu, TX; Du, ML; Zhu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Jiace; Zhuang, Zechao; Cao, Kecheng; Gao, Guohua; Wang, Chan; Lai, Feili; Lu, Shuanglong; Ma, Piming; Dong, Weifu; Liu, Tianxi; Du, Mingliang; Zhu, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling the electronegativity-dominated intermediate adsorption on high-entropy alloy electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloy catalysts are an emerging class of materials and identification of catalytically active sites is critical. Here, we provide evidence that metal site electronegativity differences stabilize bound *OH and *H intermediates. High-entropy alloys have received considerable attention in the field of catalysis due to their exceptional properties. However, few studies hitherto focus on the origin of their outstanding performance and the accurate identification of active centers. Herein, we report a conceptual and experimental approach to overcome the limitations of single-element catalysts by designing a FeCoNiXRu (X: Cu, Cr, and Mn) High-entropy alloys system with various active sites that have different adsorption capacities for multiple intermediates. The electronegativity differences between mixed elements in HEA induce significant charge redistribution and create highly active Co and Ru sites with optimized energy barriers for simultaneously stabilizing OH* and H* intermediates, which greatly enhances the efficiency of water dissociation in alkaline conditions. This work provides an in-depth understanding of the interactions between specific active sites and intermediates, which opens up a fascinating direction for breaking scaling relation issues for multistep reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2662, "DOI": "10.1038/s41467-022-30379-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30379-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000795204200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, NJ; Wang, HH; Kim, SP; Kim, HM; Lee, WH; Hu, C; Bae, JY; Sim, ES; Chung, YC; Jang, JH; Yoo, SJ; Zhuang, YB; Lee, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, nulljun; Wang, Ho Hyun; Kim, Sun Pyo; Kim, Hae Min; Lee, Won Hee; Hu, Chuan; Bae, Joon Yong; Sim, Eun Seob; Chung, Yong-Chae; Jang, Jue-Hyuk; Yoo, Sung Jong; Zhuang, Yongbing; Lee, Young Moo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(fluorenyl aryl piperidinium) membranes and ionomers for anion exchange membrane fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-cost anion exchange membrane fuel cells have been investigated as a promising alternative to proton exchange membrane fuel cells for the last decade. The major barriers to the viability of anion exchange membrane fuel cells are their unsatisfactory key components-anion exchange ionomers and membranes. Here, we present a series of durable poly(fluorenyl aryl piperidinium) ionomers and membranes where the membranes possess high OH- conductivity of 208 mS cm(-1) at 80 degrees C, low H-2 permeability, excellent mechanical properties (84.5 MPa TS), and 2000 h ex-situ durability in 1 M NaOH at 80 degrees C, while the ionomers have high water vapor permeability and low phenyl adsorption. Based on our rational design of poly(fluorenyl aryl piperidinium) membranes and ionomers, we demonstrate alkaline fuel cell performances of 2.34 W cm(-2) in H-2-O-2 and 1.25 W cm(-2) in H-2-air (CO2-free) at 80 degrees C. The present cells can be operated stably under a 0.2 A cm(-2) current density for similar to 200 h. Developing high-performance anion exchange membranes and ionomers is crucial for low-cost alkaline fuel cells. Here, the authors explore rigid and high ion conductive poly(fluorenyl aryl piperidinium) copolymers, extending their applications to anion exchange membrane fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2367, "DOI": "10.1038/s41467-021-22612-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22612-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642744500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SZ; Chen, YJ; Wang, SY; Li, P; Mirkin, CA; Farha, OK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shunzhi; Chen, Yijing; Wang, Shuya; Li, Peng; Mirkin, Chad A.; Farha, Omar K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DNA-Functionalized Metal-Organic Framework nulloparticles for Intracellular Delivery of Proteins", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to their large size, charged surfaces, and environmental sensitivity, proteins do not naturally cross cell-membranes in intact form and, therefore, are difficult to deliver for both diagnostic and therapeutic purposes. Based upon the observation that clustered oligonucleotides can naturally engage scavenger receptors that facilitate cellular transfection, nucleic acid-metal organic framework nulloparticle (MOF NP) conjugates have been designed and synthesized from NU-1000 and PCN-222/MOF-545, respectively, and phosphate-terminated oligonucleotides. They have been characterized structurally and with respect to their ability to enter mammalian cells. The MOFs act as protein hosts, and their densely functionalized, oligonucleotide-rich surfaces make them colloidally stable and ensure facile cellular entry. With insulin as a model protein, high loading and a 10-fold enhancement of cellular uptake (as compared to that of the native protein) were achieved. Importantly, this approach can be generalized to facilitate the delivery of a variety of proteins as biological probes or potential therapeutics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2019, "Volume": 141, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2215, "End Page": 2219, "Article Number": null, "DOI": "10.1021/jacs.8b12705", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b12705", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459222100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shown, I; Samireddi, S; Chang, YC; Putikam, R; Chang, PH; Sabbah, A; Fu, FY; Chen, WF; Wu, CI; Yu, TY; Chung, PW; Lin, MC; Chen, LC; Chen, KH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shown, Indrajit; Samireddi, Satyanarayana; Chang, Yu-Chung; Putikam, Raghunath; Chang, Po-Han; Sabbah, Amr; Fu, Fang-Yu; Chen, Wei-Fu; Wu, Chih-, I; Yu, Tsyr-Yan; Chung, Po-Wen; Lin, M. C.; Chen, Li-Chyong; Chen, Kuei-Hsien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-doped SnS2 nullostructure as a high-efficiency solar fuel catalyst under visible light", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic formation of hydrocarbons using solar energy via artificial photosynthesis is a highly desirable renewable-energy source for replacing conventional fossil fuels. Using an L-cysteine-based hydrothermal process, here we synthesize a carbon-doped SnS2 (SnS2-C) metal dichalcogenide nullostructure, which exhibits a highly active and selective photocatalytic conversion of CO2 to hydrocarbons under visible-light. The interstitial carbon doping induced microstrain in the SnS2 lattice, resulting in different photophysical properties as compared with undoped SnS2. This SnS2-C photocatalyst significantly enhances the CO2 reduction activity under visible light, attaining a photochemical quantum efficiency of above 0.7%. The SnS2-C photocatalyst represents an important contribution towards high quantum efficiency artificial photosynthesis based on gas phase photocatalytic CO2 reduction under visible light, where the in situ carbon-doped SnS2 nullostructure improves the stability and the light harvesting and charge separation efficiency, and significantly enhances the photocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 169, "DOI": "10.1038/s41467-017-02547-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02547-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419949100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uzun, S; Seyedin, S; Stoltzfus, AL; Levitt, AS; Alhabeb, M; Anayee, M; Strobel, CJ; Razal, JM; Dion, G; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uzun, Simge; Seyedin, Shayan; Stoltzfus, Amy L.; Levitt, Ariana S.; Alhabeb, Mohamed; Anayee, Mark; Strobel, Christina J.; Razal, Joselito M.; Dion, Genevieve; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Knittable and Washable Multifunctional MXene-Coated Cellulose Yarns", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Textile-based electronics enable the next generation of wearable devices, which have the potential to transform the architecture of consumer electronics. Highly conductive yarns that can be manufactured using industrial-scale processing and be washed like everyday yarns are needed to fulfill the promise and rapid growth of the smart textile industry. By coating cellulose yarns with Ti3C2Tx MXene, highly conductive and electroactive yarns are produced, which can be knitted into textiles using an industrial knitting machine. It is shown that yarns with MXene loading of approximate to 77 wt% (approximate to 2.2 mg cm(-1)) have conductivity of up to 440 S cm(-1). After washing for 45 cycles at temperatures ranging from 30 to 80 degrees C, MXene-coated cotton yarns exhibit a minimal increase in resistance while maintaining constant MXene loading. The MXene-coated cotton yarn electrode offers a specific capacitance of 759.5 mF cm(-1) at 2 mV s(-1). A fully knitted textile-based capacitive pressure sensor is also prepared, which offers high sensitivity (gauge factor of approximate to 6.02), wide sensing range of up to approximate to 20% compression, and excellent cycling stability (2000 cycles at approximate to 14% compression strain). This work provides new and practical insights toward the development of platform technology that can integrate MXene in cellulose-based yarns for textile-based devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 29, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1905015, "DOI": "10.1002/adfm.201905015", "DOI Link": "http://dx.doi.org/10.1002/adfm.201905015", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485338200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thebo, KH; Qian, XT; Zhang, Q; Chen, L; Cheng, HM; Ren, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thebo, Khalid Hussain; Qian, Xitang; Zhang, Qing; Chen, Long; Cheng, Hui-Ming; Ren, Wencai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stable graphene-oxide-based membranes with superior permeability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing fresh water demand for drinking and agriculture is one of the grand challenges of our age. Graphene oxide (GO) membranes have shown a great potential for desalination and water purification. However, it is challenging to further improve the water permeability without sacrificing the separation efficiency, and the GO membranes are easily delaminated in aqueous solutions within few hours. Here, we report a class of reduced GO membranes with enlarged interlayer distance fabricated by using theanine amino acid and tannic acid as reducing agent and cross-linker. Such membranes show water permeance over 10,000 Lm(-2) h(-1) bar(-1), which is 10-1000 times higher than those of previously reported GO-based membranes and commercial membranes, and good separation efficiency, e.g., rhodamine B and methylene blue rejection of similar to 100%. Moreover, they show no damage or delamination in water, acid, and basic solutions even after months.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1486, "DOI": "10.1038/s41467-018-03919-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03919-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430057800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, HM; Fang, C; Fang, Z; Bernevig, BA; Dai, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Hongming; Fang, Chen; Fang, Zhong; Bernevig, B. Andrei; Dai, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weyl Semimetal Phase in Noncentrosymmetric Transition-Metal Monophosphides", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on first-principle calculations, we show that a family of nonmagnetic materials including TaAs, TaP, NbAs, and NbP are Weyl semimetals (WSM) without inversion centers. We find twelve pairs of Weyl points in the whole Brillouin zone (BZ) for each of them. In the absence of spin-orbit coupling (SOC), band inversions in mirror-invariant planes lead to gapless nodal rings in the energy-momentum dispersion. The strong SOC in these materials then opens full gaps in the mirror planes, generating nonzero mirror Chern numbers and Weyl points off the mirror planes. The resulting surface-state Fermi arc structures on both (001) and (100) surfaces are also obtained, and they show interesting shapes, pointing to fascinating playgrounds for future experimental studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1901, "Times Cited, All Databases": 2042, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11029, "DOI": "10.1103/PhysRevX.5.011029", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.011029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351507700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, HH; Qiu, Y; Peng, XY; Wang, JA; Mi, YY; Zhao, SZ; Liu, XJ; Liu, YF; Cao, R; Zhuo, LC; Ren, JQ; Sun, JQ; Luo, J; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Haihong; Qiu, Yuan; Peng, Xianyun; Wang, Jia-ao; Mi, Yuying; Zhao, Shunzheng; Liu, Xijun; Liu, Yifan; Cao, Rui; Zhuo, Longchao; Ren, Junqiang; Sun, Jiaqiang; Luo, Jun; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated copper single sites for high-performance electroreduction of carbon monoxide to multicarbon products", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical carbon monoxide reduction is a promising strategy for the production of value-added multicarbon compounds, albeit yielding diverse products with low selectivities and Faradaic efficiencies. Here, copper single atoms anchored to Ti3C2Tx MXene nullosheets are firstly demonstrated as effective and robust catalysts for electrochemical carbon monoxide reduction, achieving an ultrahigh selectivity of 98% for the formation of multicarbon products. Particularly, it exhibits a high Faradaic efficiency of 71% towards ethylene at -0.7V versus the reversible hydrogen electrode, superior to the previously reported copper-based catalysts. Besides, it shows a stable activity during the 68-h electrolysis. Theoretical simulations reveal that atomically dispersed Cu-O-3 sites favor the C-C coupling of carbon monoxide molecules to generate the key *CO-CHO species, and then induce the decreased free energy barrier of the potential-determining step, thus accounting for the high activity and selectivity of copper single atoms for carbon monoxide reduction. Electrochemical carbon monoxide reduction is a promising strategy to yield valuable multicarbon products but low selectivities and Faradaic efficiencies are common. Here the authors show single atom copper catalyst supported on MXene with high CO reduction performance and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 238, "DOI": "10.1038/s41467-020-20336-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20336-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670284400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Azad, FN; Ghaedi, M; Dashtian, K; Hajati, S; Pezeshkpour, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Azad, F. Nasiri; Ghaedi, M.; Dashtian, K.; Hajati, S.; Pezeshkpour, V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasonically assisted hydrothermal synthesis of activated carbon-HKUST-1-MOF hybrid for efficient simultaneous ultrasound-assisted removal of ternary organic dyes and antibacterial investigation: Taguchi optimization", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Activated carbon (AC) composite with HKUST-1 metal organic framework (AC-HKUST-1 MOF) was prepared by ultrasonically assisted hydrothermal method and characterized by FTIR, SEM and XRD analysis and laterally was applied for the simultaneous ultrasound-assisted removal of crystal violet (CV), disulfine blue (DSB) and quinoline yellow (QY) dyes in their ternary solution. In addition, this material, was screened in vitro for their antibacterial actively against Methicillin-resistant Staphylococcus aureus (MRSA) and Pseudomonas aeruginosa (PAO1) bacteria. In dyes removal process, the effects of important variables such as initial concentration of dyes, adsorbent mass, pH and sonication time on adsorption process optimized by Taguchi approach. Optimum values of 4, 0.02 g, 4 min, 10 mg L-1 were obtained for pH, AC-HKUST-1 MOF mass, sonication time and the concentration of each dye, respectively. At the optimized condition, the removal percentages of CV, DSB and QY were found to be 99.76%, 91.10%, and 90.75%, respectively, with desirability of 0.989. Kinetics of adsorption processes follow pseudo-second-order model. The Langmuir model as best method with high applicability for representation of experimental data, while maximum mono layer adsorption capacity for CV, DSB and QY on AC-HKUST-1 estimated to be 133.33, 129.87 and 65.37 mg g(-1) which significantly were higher than HKUST-1 as sole material with Q(m) to equate 59.45, 57.14 and 38.80 mg g(-1), respectively. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 31, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 383, "End Page": 393, "Article Number": null, "DOI": "10.1016/j.ultsonch.2016.01.024", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2016.01.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373419900046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SH; Ramirez-Cuesta, AJ; Newby, R; Garcia-Sakai, V; Manuel, P; Callear, SK; Campbell, SI; Tang, CC; Schröder, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Sihai; Ramirez-Cuesta, Anibal J.; Newby, Ruth; Garcia-Sakai, Victoria; Manuel, Pascal; Callear, Samantha K.; Campbell, Stuart I.; Tang, Chiu C.; Schroeder, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular binding and separation of hydrocarbons within a functionalized porous metal-organic framework", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supramolecular interactions are fundamental to host-guest binding in many chemical and biological processes. Direct visualization of such supramolecular interactions within host-guest systems is extremely challenging, but crucial to understanding their function. We report a comprehensive study that combines neutron scattering, synchrotron X-ray and neutron diffraction, and computational modelling to define the detailed binding at a molecular level of acetylene, ethylene and ethane within the porous host NOTT-300. This study reveals simultaneous and cooperative hydrogen-bonding, pi center dot center dot center dot pi stacking interactions and intermolecular dipole interactions in the binding of acetylene and ethylene to give up to 12 individual weak supramolecular interactions aligned within the host to form an optimal geometry for the selective binding of hydrocarbons. We also report the cooperative binding of a mixture of acetylene and ethylene within the porous host, together with the corresponding breakthrough experiments and analysis of adsorption isotherms of gas mixtures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 121, "End Page": 129, "Article Number": null, "DOI": "10.1038/nchem.2114", "DOI Link": "http://dx.doi.org/10.1038/nchem.2114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348599600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naguib, M; Mashtalir, O; Lukatskaya, MR; Dyatkin, B; Zhang, CF; Presser, V; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naguib, Michael; Mashtalir, Olha; Lukatskaya, Maria R.; Dyatkin, Boris; Zhang, Chuanfang; Presser, Volker; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-step synthesis of nullocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein we show that heating 2D Ti3C2 in air results in TiO2 nullo-crystals enmeshed in thin sheets of disordered graphitic carbon structures that can handle extremely high cycling rates when tested as anodes in lithium ion batteries. Oxidation of 2D Ti3C2 in either CO2 or pressurized water also resulted in TiO2-C hybrid structures. Similarly, other hybrids can be produced, as we show here for Nb2O5/C from 2D Nb2C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 658, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 50, "Issue": 56, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7420, "End Page": 7423, "Article Number": null, "DOI": "10.1039/c4cc01646g", "DOI Link": "http://dx.doi.org/10.1039/c4cc01646g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338115600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, HH; Huang, K; Wang, D; Zhang, RY; Ge, BH; Ma, JY; Wen, B; Zhang, S; Li, QY; Lei, M; Zhang, C; Irawan, J; Liu, LM; Wu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Hehe; Huang, Kai; Wang, Da; Zhang, Ruoyu; Ge, Binghui; Ma, Jingyuan; Wen, Bo; Zhang, Shuai; Li, Qunyang; Lei, Ming; Zhang, Cheng; Irawan, Joshua; Liu, Li-Min; Wu, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nullocrystal growth", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photochemical solution-phase reactions have been widely applied for the syntheses of nullocrystals. In particular, tuning of the nucleation and growth of solids has been a major area of focus. Here we demonstrate a facile approach to generate atomically dispersed platinum via photochemical reduction of frozen chloroplatinic acid solution using ultraviolet light. Using this iced-photochemical reduction, the aggregation of atoms is prevented, and single atoms are successfully stabilized. The platinum atoms are deposited on various substrates, including mesoporous carbon, graphene, carbon nullotubes, titanium dioxide nullo-particles, and zinc oxide nullowires. The atomically dispersed platinum on mesoporous carbon exhibits efficient catalytic activity for the electrochemical hydrogen evolution reaction, with an overpotential of only 65 mV at a current density of 100 mA cm(-2) and long-time durability (> 10 h), superior to state-of-the-art platinum/carbon. This iced-photochemical reduction may be extended to other single atoms, for example gold and silver, as demonstrated in this study.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1490, "DOI": "10.1038/s41467-017-01521-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01521-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415124000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YZ; Chen, WS; Xia, QQ; Guo, BT; Wang, QW; Liu, SX; Liu, YX; Li, J; Yu, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yongzhuang; Chen, Wenshuai; Xia, Qinqin; Guo, Bingtuo; Wang, Qingwen; Liu, Shouxin; Liu, Yixing; Li, Jian; Yu, Haipeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Cleavage of Lignin-Carbohydrate Complexes and Ultrafast Extraction of Lignin Oligomers from Wood Biomass by Microwave-Assisted Treatment with Deep Eutectic Solvent", "Source Title": "CHEMSUSCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignocellulosic biomass is an abundant and renewable resource for the production of biobased value-added fuels, chemicals, and materials, but its effective exploitation by an energy-efficient and environmentally friendly strategy remains a challenge. Herein, a facile approach for efficiently cleaving lignin-carbohydrate complexes and ultrafast fractionation of components from wood by microwave-assisted treatment with deep eutectic solvent is reported. The solvent was composed of sustainable choline chloride and oxalic acid dihydrate, and showed a hydrogen-bond acidity of 1.31. Efficient fractionation of lignocellulose with the solvent was realized by heating at 80 degrees C under 800W microwave irradiation for 3min. The extracted lignin showed a low molecular weight of 913, a low polydispersity of 1.25, and consisted of lignin oligomers with high purity (ca. 96%), and thus shows potential in downstream production of aromatic chemicals. The other dissolved matter mainly comprised glucose, xylose, and hydroxymethylfurfural. The undissolved material was cellulose with crystalI structure and a crystallinity of approximately 75%, which can be used for fabricating nullocellulose. Therefore, this work promotes an ultrafast lignin-first biorefinery approach while simultaneously keeping the undissolved cellulose available for further utilization. This work is expected to contribute to improving the economics of overall biorefining of lignocellulosic biomass.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2017, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1692, "End Page": 1700, "Article Number": null, "DOI": "10.1002/cssc.201601795", "DOI Link": "http://dx.doi.org/10.1002/cssc.201601795", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399954300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YS; Lu, HZ; Liang, JT; Rosenthal, A; Liu, HW; Sneddon, G; McCarroll, I; Zhao, ZZ; Li, W; Guo, AM; Cairney, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yi-Sheng; Lu, Hongzhou; Liang, Jiangtao; Rosenthal, Alexander; Liu, Hongwei; Sneddon, Glenn; McCarroll, Ingrid; Zhao, Zhengzhi; Li, Wei; Guo, Aimin; Cairney, Julie M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of hydrogen trapping at dislocations, grain boundaries, and precipitates", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen embrittlement of high-strength steel is an obstacle for using these steels in sustainable energy production. Hydrogen embrittlement involves hydrogen-defect interactions at multiple-length scales. However, the challenge of measuring the precise location of hydrogen atoms limits our understanding. Thermal desorption spectroscopy can identify hydrogen retention or trapping, but data cannot be easily linked to the relative contributions of different microstructural features. We used cryo-transfer atom probe tomography to observe hydrogen at specific microstructural features in steels. Direct observation of hydrogen at carbon-rich dislocations and grain boundaries provides validation for embrittlement models. Hydrogen observed at an incoherent interface between niobium carbides and the surrounding steel provides direct evidence that these incoherent boundaries can act as trapping sites. This information is vital for designing embrittlement-resistant steels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 367, "Issue": 6474, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 171, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz0122", "DOI Link": "http://dx.doi.org/10.1126/science.aaz0122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506811300034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, J; Tang, JC; Zhang, Z; Wang, L; Liu, QL; Liu, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Juan; Tang, Jingchun; Zhang, Zheng; Wang, Lan; Liu, Qinglong; Liu, Xiaomei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic ball-milled FeS@biochar as persulfate activator for degradation of tetracycline", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, composite of iron sulfide and biochar (FeS@BC) was synthesized successfully via physical ball milling and applied to the oxidative removal of tetracycline (TC) in the presence of persulfate (PS). Characterization results showed that FeS@BC, which has a small particle size, can be synthesized at a preset FeS-BC mass ratio. In addition, the ball-milled FeS@BC showed sufficient ferromagnetism. The effects of pH, dosages of FeS@BC and PS, and co-existing anions on TC degradation were investigated. Our results showed that TC degradation efficiency was enhanced at low pH and high dosages of PS and FeS@BC. Under optimal conditions (pH = 3.6, [FeS@BC] = 0.3 g/L and [PS] = 10 mA4), a TC removal efficiency of 87.4% could be achieved after 30 min. Nevertheless, the TC removal rate was slightly inhibited by inorganic anions in the order of CO32- > Cl- > NO3-. Surface-bound Fe(II) and S(II) acted as electron donors in the activation process and generated SO4 and 'OH at the surface of FeS@BC. In addition, S(II) also participated in Fe(III) reduction. BC not only reduced the agglomeration of FeS, serving as a continuous source of effective Fe, but also acted as an electron shuttle and a suitable carbon-based adsorption material, facilitating fast electron transfer among PS, electron donors, and pollutants. Moreover, non-radical degradation processes might also exist in the FeS@BC/PS/TC system. The FeS@BC could be a promising effective activator for the remediation of other emerging organic contaminullts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 404, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126997, "DOI": "10.1016/j.cej.2020.126997", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.126997", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607583700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, X; Ji, PX; Wang, PY; Tan, X; Chen, L; Mu, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Xu; Ji, Pengxia; Wang, Pengyan; Tan, Xin; Chen, Lei; Mu, Shichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spherical Ni3S2/Fe-NiPx Magic Cube with Ultrahigh Water/Seawater Oxidation Efficiency", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational construction of earth-abundant and advanced electrocatalysts for oxygen evolution reaction (OER) is extremely desired and significant to seawater electrolysis. Herein, by directly etching Ni3S2 nullosheets through potassium ferricyanide, a novel self-sacrificing template strategy is proposed to realize the in situ growth of NiFe-based Prussian blue analogs (NiFe PBA) on Ni3S2 in an interfacial redox reaction. The well-designed Ni3S2@NiFe PBA composite as precursor displays a unique spherical magic cube architecture composed of nullocubes, which even maintains after a phosphating treatment to obtain the derived Ni3S2/Fe-NiPx on nickel foam. Specifically, in alkaline seawater, the Ni3S2/Fe-NiPx as OER precatalyst marvelously realizes the ultralow overpotentials of 336 and 351 mV at large current densities of 500 and 1000 mA cm(-2), respectively, with remarkable durability for over 225 h, outperforming most reported advanced OER electrocatalysts. Experimentally, a series of characterization results confirm the reconstruction behavior in the Ni3S2/Fe-NiPx surface, leading to the in situ formation of Ni(OH)(2)/Ni(Fe)OOH with abundant oxygen vacancies and grain boundaries, which constructs the Ni3S2/Fe-NiPx reconstruction system responsible for the remarkable OER catalytic activity. Theoretical calculation results further verify the enhanced OER activity for Ni3S2/Fe-NiPx reconstruction system, and unveil that the Fe-Ni2P/FeOOH as active origin contributes to the central OER activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104846, "DOI": "10.1002/advs.202104846", "DOI Link": "http://dx.doi.org/10.1002/advs.202104846", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764170700031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Forse, AC; Griffin, JM; Merlet, C; Carretero-Gonzalez, J; Raji, ARO; Trease, NM; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Forse, Alexander C.; Griffin, John M.; Merlet, Celine; Carretero-Gonzalez, Javier; Raji, Abdul-Rahman O.; Trease, Nicole M.; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of ion dynamics in supercapacitor electrodes using in situ diffusion NMR spectroscopy", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ionic transport inside porous carbon electrodes underpins the storage of energy in supercapacitors and the rate at which they can charge and discharge, yet few studies have elucidated the materials properties that influence ion dynamics. Here we use in situ pulsed field gradient NMR spectroscopy to measure ionic diffusion in supercapacitors directly. We find that confinement in the nulloporous electrode structures decreases the effective self-diffusion coefficients of ions by over two orders of magnitude compared with neat electrolyte, and in-pore diffusion is modulated by changes in ion populations at the electrode/electrolyte interface during charging. Electrolyte concentration and carbon pore size distributions also affect in-pore diffusion and the movement of ions in and out of the nullopores. In light of our findings we propose that controlling the charging mechanism may allow the tuning of the energy and power performances of supercapacitors for a range of different applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16216, "DOI": "10.1038/nenergy.2016.216", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2016.216", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398408500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Walkey, CD; Olsen, JB; Song, FY; Liu, R; Guo, HB; Olsen, DWH; Cohen, Y; Emili, A; Chan, WCW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Walkey, Carl D.; Olsen, Jonathan B.; Song, Fayi; Liu, Rong; Guo, Hongbo; Olsen, D. Wesley H.; Cohen, Yoram; Emili, Andrew; Chan, Warren C. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protein Corona Fingerprinting Predicts the Cellular Interaction of Gold and Silver nulloparticles", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using quantitative models to predict the biological interactions of nulloparticles will accelerate the translation of nullotechnology. Here, we characterized the serum protein corona 'fingerprint' formed around a library of 105 surface-modified gold nulloparticles. Applying a bioinformatics-inspired approach, we developed a multivariate model that uses the protein corona fingerprint to predict cell association 50% more accurately than a model that uses parameters describing nulloparticle size, aggregation state, and surface charge. Our model implicates a set of hyaluronull-binding proteins as mediators of nulloparticle cell interactions. This study establishes a framework for developing a comprehensive database of protein corona fingerprints and biological responses for multiple nulloparticle types. Such a database can be used to develop quantitative relationships that predict the biological responses to nulloparticles and will aid in uncovering the fundamental mechanisms of nullo-bio interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 658, "Times Cited, All Databases": 757, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2439, "End Page": 2455, "Article Number": null, "DOI": "10.1021/nn406018q", "DOI Link": "http://dx.doi.org/10.1021/nn406018q", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333539400057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Zhang, JT; Chen, YM; Li, J; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhen; Zhang, Jin Tao; Chen, Yu Ming; Li, Ju; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pie-like electrode design for high-energy density lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the overwhelming advantage in energy density, lithium-sulfur (Li-S) battery is a promising next-generation electrochemical energy storage system. Despite many efforts in pursuing long cycle life, relatively little emphasis has been placed on increasing the areal energy density. Herein, we have designed and developed a 'pie' structured electrode, which provides an excellent balance between gravimetric and areal energy densities. Combining lotus root-like multichannel carbon nullofibers 'filling' and amino-functionalized graphene 'crust', the free-standing paper electrode (S mass loading: 3.6 mgcm(-2)) delivers high specific capacity of 1,314 mAhg(-1) (4.7mAhcm(-2)) at 0.1 C (0.6mAcm(-2)) accompanied with good cycling stability. Moreover, the areal capacity can be further boosted to more than 8mAhcm(-2) by stacking three layers of paper electrodes with S mass loading of 10.8 mgcm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8850, "DOI": "10.1038/ncomms9850", "DOI Link": "http://dx.doi.org/10.1038/ncomms9850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366295800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, TC; Srivastava, YK; Ako, RT; Wang, WH; Bhaskaran, M; Sriram, S; Al-Naib, I; Plum, E; Singh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Thomas CaiWei; Srivastava, Yogesh Kumar; Ako, Rajour Tanyi; Wang, Wenhao; Bhaskaran, Madhu; Sriram, Sharath; Al-Naib, Ibraheem; Plum, Eric; Singh, Ranjan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active Control of nullodielectric-Induced THz Quasi-BIC in Flexible Metasurfaces: A Platform for Modulation and Sensing", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A bound state in the continuum (BIC) is a nonradiating state of light embedded in the continuum of propagating modes providing drastic enhancement of the electromagnetic field and its localization at micro-nulloscale. However, access to such modes in the far-field requires symmetry breaking. Here, it is demonstrated that a nullometric dielectric or semiconductor layer, 1000 times thinner than the resonullt wavelength (lambda/1000), induces a dynamically controllable quasi-bound state in the continuum (QBIC) with ultrahigh quality factor in a symmetric metallic metasurface at terahertz frequencies. Photoexcitation of nullostrips of germanium activates ultrafast switching of a QBIC resonullce with 200% transmission intensity modulation and complete recovery within 7 ps on a low-loss flexible substrate. The nullostrips also form microchannels that provide an opportunity for BIC-based refractive index sensing. An optimization model is presented for (switchable) QBIC resonullces of metamaterial arrays of planar symmetric resonators modified with any (active) dielectric for inverse metamaterial design that can serve as an enabling platform for active micro-nullophotonic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 33, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100836, "DOI": "10.1002/adma.202100836", "DOI Link": "http://dx.doi.org/10.1002/adma.202100836", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000655824300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, YF; Huang, SY; Li, YP; Steinmann, SN; Yang, WT; Cao, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Yifei; Huang, Sheng-Yang; Li, Yanpeng; Steinmann, Stephan N.; Yang, Weitao; Cao, Linyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-Dependent Electrocatalysis of MoS2 for Hydrogen Evolution", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantitative correlation of the catalytic activity with the microscopic structure of heterogeneous catalysts is a major challenge for the field of catalysis science. It requests synergistic capabilities to tailor the structure with atomic scale precision and to control the catalytic reaction to proceed through well-defined pathways. Here we leverage on the controlled growth of MoS2 atomically thin films to demonstrate that the catalytic activity of MoS2 for the hydrogen evolution reaction decreases by a factor of similar to 4.47 for the addition of every one more layer. Similar layer dependence is also found in edge-riched MoS2 pyramid platelets. This layer-dependent electrocatalysis can be correlated to the hopping of electrons in the vertical direction of MoS2 layers over an interlayer potential barrier. Our experimental results suggest the potential barrier to be 0.119 V, consistent with theoretical calculations. Different from the conventional wisdom, which states that the number of edge sites is important, our results suggest that increasing the hopping efficiency of electrons in the vertical direction is a key for the development of high-efficiency two-dimensional material catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 655, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 553, "End Page": 558, "Article Number": null, "DOI": "10.1021/nl403620g", "DOI Link": "http://dx.doi.org/10.1021/nl403620g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331343900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, X; Chen, XR; Hou, TZ; Li, BQ; Cheng, XB; Zhang, R; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiang; Chen, Xiao-Ru; Hou, Ting-Zheng; Li, Bo-Quan; Cheng, Xin-Bing; Zhang, Rui; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithiophilicity chemistry of heteroatom-doped carbon to guide uniform lithium nucleation in lithium metal anodes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The uncontrollable growth of lithium (Li) dendrites seriously impedes practical applications of Li metal batteries. Various lithiophilic conductive frameworks, especially carbon hosts, are used to guide uniform Li nucleation and thus deliver a dendrite-free composite anode. However, the lithiophilic nature of these carbon hosts is poorly understood. Herein, the lithiophilicity chemistry of heteroatom-doped carbon is investigated through both first principles calculations and experimental verifications to guide uniform Li nucleation. The electronegativity, local dipole, and charge transfer are proposed to reveal the lithiophilicity of doping sites. Li bond chemistry further deepens the understanding of lithiophilicity. The O-doped and O/B-co-doped carbons exhibit the best lithiophilicity among single-doped and codoped carbons, respectively. The excellent lithiophilicity achieved by O-doping carbon is further validated by Li nucleation overpotential measurement. This work uncovers the lithiophilicity chemistry of heteroatom-doped carbons and affords a mechanistic guidance to Li metal anode frameworks for safe rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 573, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau7728", "DOI": "10.1126/sciadv.aau7728", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau7728", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YQ; Tao, S; Lin, H; Wang, GP; Zhao, KN; Cai, RM; Tao, KW; Zhang, CX; Sun, MZ; Hu, J; Huang, BL; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yaqiong; Tao, Shi; Lin, He; Wang, Gaopeng; Zhao, Kangning; Cai, Rongmin; Tao, Kewen; Zhang, Chengxu; Sun, Mingzi; Hu, Jue; Huang, Bolong; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically targeting NiFe LDH to create multivacancies for OER catalysis with a small organic anchor", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fabrication of porous structure in the ultrathin materials still faces high difficulties. In particular, the precise modulations in the porosity and size are highly challenging. In this work, we have introduced small molecules to overcome such a challenge. And this substantially contributes to the energy related applications, especially to the water-energy (WE) treatment. Electrocatalytic water-splitting is hindered by the sluggish kinetics of water oxidation, requiring efficient earth-abundant electrocatalysts for the oxygen evolution reaction (OER). Herein we demonstrate the robust OER activity by introducing metal and oxygen multivacancies in noble-metal-free layered double hydroxides (LDHs) through the specific electron-withdrawing organic molecule methyl-isorhodanate (CH3NCS). Our work reveals that the metal and oxygen vacancies endow NiFe LDH with enhanced electron transfer and modulate the H2O adsorption, thereby boosting the OER electrocatalytic properties. Remarkably, the best-performing laminar NiFe LDH nullosheets with metal and oxygen multivacancies (v-L-LDHs) show an ultra-low overpotential of 230 mV at 100 mA cm(2) and Tafel slope of 37.1 mV dec 1. Density functional theory (DFT) has revealed the improved OER performance is realized by the co-existence of metal and O vacancies in NiFe LDH, where the defective region activates the electroactivity of Ni sites and O sites to promote the electron transfer and intermediate transformation. The Fe sites play a key role to preserve the high electroactivity of the Ni sites in long-term applications. The superior OER performance underpins the high potential of the reported facile organic anchor strategy for designing and synthesizing advanced electrocatalysts in both LDH and other potential 2D layered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105606, "DOI": "10.1016/j.nulloen.2020.105606", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620327600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Agrawal, A; Choudhary, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Agrawal, Ankit; Choudhary, Alok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective: Materials informatics and big data: Realization of the fourth paradigm of science in materials science", "Source Title": "APL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Our ability to collect big data has greatly surpassed our capability to analyze it, underscoring the emergence of the fourth paradigm of science, which is data-driven discovery. The need for data informatics is also emphasized by the Materials Genome Initiative (MGI), further boosting the emerging field of materials informatics. In this article, we look at how data-driven techniques are playing a big role in deciphering processing-structure-property-performance relationships in materials, with illustrative examples of both forward models (property prediction) and inverse models (materials discovery). Such analytics can significantly reduce time-to-insight and accelerate cost-effective materials discovery, which is the goal of MGI. (C) 2016 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 828, "Times Cited, All Databases": 958, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 53208, "DOI": "10.1063/1.4946894", "DOI Link": "http://dx.doi.org/10.1063/1.4946894", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377720400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Furchi, MM; Pospischil, A; Libisch, F; Burgdörfer, J; Mueller, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Furchi, Marco M.; Pospischil, Andreas; Libisch, Florian; Burgdoerfer, Joachim; Mueller, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photovoltaic Effect in an Electrically Tunable van der Waals Heterojunction", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor heterostructures form the cornerstone of many electronic and optoelectronic devices and are traditionally fabricated using epitaxial growth techniques. More recently, heterostructures have also been obtained by vertical stacking of two-dimensional crystals, such as graphene and related two-dimensional materials. These layered designer materials are held together by van der Waals forces and contain atomically sharp interfaces. Here, we report on a typeII van der Waals heterojunction made of molybdenum disulfide and tungsten diselenide monolayers. The junction is electrically tunable, and under appropriate gate bias an atomically thin diode is realized. Upon optical illumination, charge transfer occurs across the planar interface and the device exhibits a photovoltaic effect. Advances in large-scale production of two-dimensional crystals could thus lead to a new photovoltaic solar technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 934, "Times Cited, All Databases": 1030, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4785, "End Page": 4791, "Article Number": null, "DOI": "10.1021/nl501962c", "DOI Link": "http://dx.doi.org/10.1021/nl501962c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340446200091", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, C; Wang, Q; Shao, YC; Yuan, YB; Xiao, ZG; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Cheng; Wang, Qi; Shao, Yuchuan; Yuan, Yongbo; Xiao, Zhengguo; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-aspect-ratio grains are needed in polycrystalline thin-film solar cells for reduced charge recombination at grain boundaries; however, the grain size in organolead trihalide perovskite (OTP) films is generally limited by the film thickness. Here we report the growth of OTP grains with high average aspect ratio of 2.3-7.9 on a wide range of non-wetting hole transport layers (HTLs), which increase nucleus spacing by suppressing heterogeneous nucleation and facilitate grain boundary migration in grain growth by imposing less drag force. The reduced grain boundary area and improved crystallinity dramatically reduce the charge recombination in OTP thin films to the level in OTP single crystals. Combining the high work function of several HTLs, a high stabilized device efficiency of 18.3% in low-temperature-processed planar-heterojunction OTP devices under 1 sun illumination is achieved. This simple method in enhancing OTP morphology paves the way for its application in other optoelectronic devices for enhanced performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1462, "Times Cited, All Databases": 1526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7747, "DOI": "10.1038/ncomms8747", "DOI Link": "http://dx.doi.org/10.1038/ncomms8747", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858500053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, KP; Zhao, XT; Ren, GQ; Yang, T; Ren, YJ; Lee, AF; Su, Y; Pan, XL; Zhang, JC; Chen, ZQ; Yang, JY; Liu, XY; Zhou, T; Xi, W; Luo, J; Zeng, CB; Matsumoto, H; Liu, W; Jiang, QK; Wilson, K; Wang, AQ; Qiao, BT; Li, WZ; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kaipeng; Zhao, Xintian; Ren, Guoqing; Yang, Tao; Ren, Yujing; Lee, Adam Fraser; Su, Yang; Pan, Xiaoli; Zhang, Jingcai; Chen, Zhiqiang; Yang, Jingyi; Liu, Xiaoyan; Zhou, Tong; Xi, Wei; Luo, Jun; Zeng, Chaobin; Matsumoto, Hiroaki; Liu, Wei; Jiang, Qike; Wilson, Karen; Wang, Aiqin; Qiao, Botao; Li, Weizhen; Zhang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have demonstrated superior catalytic performance in numerous heterogeneous reactions. However, producing thermally stable SACs, especially in a simple and scalable way, remains a formidable challenge. Here, we report the synthesis of Ru SACs from commercial RuO2 powders by physical mixing of sub-micron RuO2 aggregates with a MgAl1.2Fe0.8O4 spinel. Atomically dispersed Ru is confirmed by aberration-corrected scanning transmission electron microscopy and X-ray absorption spectroscopy. Detailed studies reveal that the dispersion process does not arise from a gas atom trapping mechanism, but rather from anti-Ostwald ripening promoted by a strong covalent metal-support interaction. This synthetic strategy is simple and amenable to the large-scale manufacture of thermally stable SACs for industrial applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1263, "DOI": "10.1038/s41467-020-14984-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14984-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549165100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, WB; Jiang, TM; Yang, Z; Zhang, H; Su, YR; Chen, Z; Chen, XY; Ma, YG; Zhu, WJ; Yu, X; Zhu, HM; Qiu, JB; Liu, X; Xu, XH; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Wenbo; Jiang, Tingming; Yang, Ze; Zhang, Hao; Su, Yirong; Chen, Zeng; Chen, Xinya; Ma, Yaoguang; Zhu, Wenjuan; Yu, Xue; Zhu, Haiming; Qiu, Jianbei; Liu, Xu; Xu, Xuhui; Yang, Yang (Michael)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Resolved and Robust Dynamic X-Ray Imaging Using Perovskite Glass-Ceramic Scintillator with Reduced Light Scattering", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic perovskite quantum dots (QDs) CsPbX3 (X = Cl, Br, and I) have recently emerged as a new promising class of X-ray scintillators. However, the instability of perovskite QDs and the strong optical scattering of the thick opaque QD scintillator film imped it to realize high-quality and robust X-ray image. Herein, the europium (Eu) doped CsPbBr3 QDs are in situ grown inside transparent amorphous matrix to form glass-ceramic (GC) scintillator with glass phase serving as both matrix and encapsulation for the perovskite QD scintillators. The small amount of Eu dopant optimizes the crystallization of CsPbBr3 QDs and makes their distribution more uniform in the glass matrix, which can significantly reduce the light scattering and also enhance the photoluminescence emission of CsPbBr3 QDs. As a result, a remarkably high spatial resolution of 15.0 lp mm(-1) is realized thanks to the reduced light scattering, which is so far a record resolution for perovskite scintillator based X-ray imaging, and the scintillation stability is also significantly improved compared to the bare perovskite QD scintillators. Those results provide an effective platform particularly for the emerging perovskite nullocrystal scintillators to reduce light scattering and improve radiation hardness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003728, "DOI": "10.1002/advs.202003728", "DOI Link": "http://dx.doi.org/10.1002/advs.202003728", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000656826600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YW; Lee, HWH; Sokhoyan, R; Pala, RA; Thyagarajan, K; Han, S; Tsai, DP; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yao-Wei; Lee, Ho Wai Howard; Sokhoyan, Ruzan; Pala, Ragip A.; Thyagarajan, Krishnull; Han, Seunghoon; Tsai, Din Ping; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-Tunable Conducting Oxide Metasurfaces", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces composed of planar arrays of subwavelength artificial structures show promise for extraordinary light manipulation. They have-yielded novel-ultrathin optical components such as flat lenses, wave plates, holographic surfaces, and orbital angular momentum manipulation and detection over a broad range of the electromagnetic spectrum. However, the optical properties of metasurfaces developed to date do not allow for versatile tunability Of reflected or transmitted wave amplitude and phase after their fabrication,. thus limiting their use in a wide range of applications. Here, we experimentally, demonstrate :a gate-tunable metasurface :that enables dynamic electrical control,of the phase and amplitude of the plane wave reflected from the metasurface. Tunability arises from field-effect modulation Of the complex refractive index Of conducting oxide layers incorporated, into metasurface antenna elements which are configured in reflectarray geometry:We measure a phase shift of 180 degrees and similar to 30% change in the reflectance by applying 2.5 V gate bias. Additionally, we demonstrate modulation at-frequencies exceeding 10 MHz and electrical switching of +/- 1 order diffracted beams by electrical control over subgroups of metasurface elements, a basic requirement for electrically tunable beam-steering phased array metasurfaces. In principle, electrically gated phase and amplitude control allows for electrical addressability of individual metasurface elements and opens the path to applications in ultrathin optical components for imaging and sensing technologies, such as reconfigurable bearh steering devices, dynamic holograms, tunable ultrathin lenses, nulloprojectors, and nulloscale spatial light modulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 591, "Times Cited, All Databases": 709, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 16, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5319, "End Page": 5325, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b00555", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b00555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383412100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YS; Xiao, RJ; Hu, YS; Avdeev, M; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuesheng; Xiao, Ruijuan; Hu, Yong-Sheng; Avdeev, Maxim; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "P2-Na0.6[Cr0.6Ti0.4]O2 cation-disordered electrode for high-rate symmetric rechargeable sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most P2-type layered oxides exhibit Na+/vacancy-ordered superstructures because of strong Na+-Na+ interaction in the alkali metal layer and charge ordering in the transition metal layer. These superstructures evidenced by voltage plateaus in the electrochemical curves limit the Na+ ion transport kinetics and cycle performance in rechargeable batteries. Here we show that such Na+/vacancy ordering can be avoided by choosing the transition metal ions with similar ionic radii and different redox potentials, for example, Cr3+ and Ti4+. The designed P2-Na-0.6[Cr0.6Ti0.4]O-2 is completely Na+/vacancy-disordered at any sodium content and displays excellent rate capability and long cycle life. A symmetric sodium-ion battery using the same P2-Na-0.6[Cr0.6Ti0.4]O-2 electrode delivers 75% of the initial capacity at 12C rate. Our contribution demonstrates that the approach of preventing Na+/vacancy ordering by breaking charge ordering in the transition metal layer opens a simple way to design disordered electrode materials with high power density and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 486, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6954, "DOI": "10.1038/ncomms7954", "DOI Link": "http://dx.doi.org/10.1038/ncomms7954", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Choi, SI; Roling, LT; Luo, M; Ma, C; Zhang, L; Chi, MF; Liu, JY; Xie, ZX; Herron, JA; Mavrikakis, M; Xia, YN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xue; Choi, Sang-Il; Roling, Luke T.; Luo, Ming; Ma, Cheng; Zhang, Lei; Chi, Miaofang; Liu, Jingyue; Xie, Zhaoxiong; Herron, Jeffrey A.; Mavrikakis, Manos; Xia, Younull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Palladium-platinum core-shell icosahedra with substantially enhanced activity and durability towards oxygen reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conformal deposition of platinum as ultrathin shells on facet-controlled palladium nullocrystals offers a great opportunity to enhance the catalytic performance while reducing its loading. Here we report such a system based on palladium icosahedra. Owing to lateral confinement imposed by twin boundaries and thus vertical relaxation only, the platinum overlayers evolve into a corrugated structure under compressive strain. For the core-shell nullocrystals with an average of 2.7 platinum overlayers, their specific and platinum mass activities towards oxygen reduction are enhanced by eight- and sevenfold, respectively, relative to a commercial catalyst. Density functional theory calculations indicate that the enhancement can be attributed to the weakened binding of hydroxyl to the compressed platinum surface supported on palladium. After 10,000 testing cycles, the mass activity of the core-shell nullocrystals is still four times higher than the commercial catalyst. These results demonstrate an effective approach to the development of electrocatalysts with greatly enhanced activity and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 474, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7594, "DOI": "10.1038/ncomms8594", "DOI Link": "http://dx.doi.org/10.1038/ncomms8594", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358856100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, SX; Zhao, FW; Zhang, QQ; Lau, TK; Li, TF; Liu, K; Ling, QD; Wang, CR; Lu, XH; You, W; Zhan, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Shuixing; Zhao, Fuwen; Zhang, Qianqian; Lau, Tsz-Ki; Li, Tengfei; Liu, Kuan; Ling, Qidan; Wang, Chunru; Lu, Xinhui; You, Wei; Zhan, Xiaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We design and synthesize four fused-ring electron acceptors based on-6,6,12,12-tetrakis(4-hexylphenyl)-indacenobis(dithieno[3,2-b-2',3'-d]thiophene) as the electron-rich unit and 1,1-dicyanomethylene-3-indanones with 0-2 fluorine substituents as the electron-deficient units. These four molecules exhibit broad (550-850 nm) and strong absorption with high extinction coefficients of (2.1-2.5) x 10(5) M-1 cm(-1). Fluorine substitution downshifts the LUMO energy level, red-shifts the absorption spectrum, and enhances electron mobility. The polymer solar cells based on the fluorinated electron acceptors exhibit power conversion efficiencies as high as 11.5%, much higher than that of their nonfluorinated counterpart (7.7%). We investigate the effects of the fluorine atom number and position on electronic properties, charge transport, film morphology, and photovoltaic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 823, "Times Cited, All Databases": 844, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 139, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1336, "End Page": 1343, "Article Number": null, "DOI": "10.1021/jacs.6b12755", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b12755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393541000041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, J; Shang, YQ; Yin, J; De Bastiani, M; Peng, W; Dursun, I; Sinatra, L; El-Zohry, AM; Hedhili, MN; Emwas, AH; Mohammed, OF; Ning, ZJ; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Jun; Shang, Yuequn; Yin, Jun; De Bastiani, Michele; Peng, Wei; Dursun, Ibrahim; Sinatra, Lutfan; El-Zohry, Ahmed M.; Hedhili, Mohamed N.; Emwas, Abdul-Hamid; Mohammed, Omar F.; Ning, Zhijun; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bidentate Ligand-Passivated CsPbI3 Perovskite nullocrystals for Stable Near-Unity Photoluminescence Quantum Yield and Efficient Red Light-Emitting Diodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although halide perovskite :nullocrystals (NCs) are promising materials for optoelectronic devices, they suffer severely from chemical and phase instabilities. Moreover, the common capping'.ligands like oleic acid and oleylamine that encapsulate the NCs will form an insulating layer, precluding their futility in optoelectronic devices. To overcome these limitations, we develop a postsynthesis passivation process for CsPbI3 NCs by using a bidentate ligand, namely 2,2'-iminodibenzoic acid. Our passivated NCs exhibit narrow red photoluminescence with exceptional quantum yield (close to unity) and substantially improved stability. The passivated NCs enabled us to realize red light-emitting diodes (LEDs) with 5.02% external quantum efficiency and 748 cd/m(2) luminullce, surpassing by far LEDs made from the nonpassivated NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 790, "Times Cited, All Databases": 826, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2018, "Volume": 140, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 562, "End Page": 565, "Article Number": null, "DOI": "10.1021/jacs.7b10647", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b10647", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423012600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dang, SS; Qin, B; Yang, Y; Wang, H; Cai, J; Han, Y; Li, SG; Gao, P; Sun, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dang, Shanshan; Qin, Bin; Yang, Yong; Wang, Hui; Cai, Jun; Han, Yong; Li, Shenggang; Gao, Peng; Sun, Yuhan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationally designed indium oxide catalysts for CO2 hydrogenation to methanol with high activity and selectivity", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Renewable energy-driven methanol synthesis from CO2 and green hydrogen is a viable and key process in both the methanol economy and liquid sunshine visions. Recently, In2O3-based catalysts have shown great promise in overcoming the disadvantages of traditional Cu-based catalysts. Here, we report a successful case of theory-guided rational design of a much higher performance In(2)O(3 )nullocatalyst. Density functional theory calculations of CO2 hydrogenation pathways over stable facets of cubic and hexagonal In2O3 predict the hexagonal In2O3 (104) surface to have far superior catalytic performance. This promotes the synthesis and evaluation of In2O3 in pure phases with different morphologies. Confirming our theoretical prediction, a novel hexagonal In2O3 nullomaterial with high proportion of the exposed {104} surface exhibits the highest activity and methanol selectivity with high catalytic stability. The synergy between theory and experiment proves highly effective in the rational design and experimental realization of oxide catalysts for industry-relevant reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz2060", "DOI": "10.1126/sciadv.aaz2060", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz2060", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542299800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, KG; Zheng, Y; Jiao, Y; Zhang, XX; Dai, S; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Konggang; Zheng, Yao; Jiao, Yan; Zhang, Xianxi; Dai, Sheng; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine-Inspired, Dual Heteroatom-Doped Carbon nullotubes for Highly Efficient Overall Water Splitting", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Overall water splitting involved hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are critical for renewable energy conversion and storage. Heteroatom-doped carbon materials have been extensively employed as efficient electrocatalysts for independent HER or OER processes, while those as the bifunctional catalysts for simultaneously generating H-2 and O-2 by splitting water have been seldom reported. Inspired by the unparalleled virtues of polydopamine, the authors devise the facile synthesis of nitrogen and sulfur dual-doped carbon nullotubes with in situ, homogenous and high concentration sulfur doping. The newly developed dual-doped electrocatalysts display superb bifunctional catalytic activities for both HER and OER in alkaline solutions, outperforming all other reported carbon counterparts. Experimental characterizations confirm that the excellent performance is attributed to the multiple doping together with efficient mass and charge transfer, while theoretical computations reveal the promotion effect of secondary sulfur dopant to enhance the spin density of dual-doped samples and consequently to form highly electroactive sites for both HER and OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2017, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1602068, "DOI": "10.1002/aenm.201602068", "DOI Link": "http://dx.doi.org/10.1002/aenm.201602068", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401719900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, ZW; Wang, XY; Gardner, A; Wang, X; Chong, SY; Neri, G; Cowan, AJ; Liu, LJ; Li, XB; Vogel, A; Clowes, R; Bilton, M; Chen, LJ; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Zhiwei; Wang, Xiaoyan; Gardner, Adrian; Wang, Xue; Chong, Samantha Y.; Neri, Gaia; Cowan, Alexander J.; Liu, Lunjie; Li, Xiaobo; Vogel, Anastasia; Clowes, Rob; Bilton, Matthew; Chen, Linjiang; Sprick, Reiner Sebastian; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stable covalent organic framework for photocatalytic carbon dioxide reduction", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic conversion of CO2 into fuels is an important challenge for clean energy research and has attracted considerable interest. Here we show that tethering molecular catalysts-a rhenium complex, [Re(bpy)(CO)(3)Cl]-together in the form of a crystalline covalent organic framework (COF) affords a heterogeneous photocatalyst with a strong visible light absorption, a high CO2 binding affinity, and ultimately an improved catalytic performance over its homogeneous Re counterpart. The COF incorporates bipyridine sites, allowing for ligation of the Re complex, into a fully pi-conjugated backbone that is chemically robust and promotes light-harvesting. A maximum rate of 1040 mu mol g(-1) h(-1) for CO production with 81% selectivity was measured. CO production rates were further increased up to 1400 mu mol g(-1) h(-1), with an improved selectivity of 86%, when a photosensitizer was added. Addition of platinum resulted in production of syngas, hence, the co-formation of H-2 and CO, the chemical composition of which could be adjusted by varying the ratio of COF to platinum. An amorphous analog of the COF showed significantly lower CO production rates, suggesting that crystallinity of the COF is beneficial to its photocatalytic performance in CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2020, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 543, "End Page": 550, "Article Number": null, "DOI": "10.1039/c9sc03800k", "DOI Link": "http://dx.doi.org/10.1039/c9sc03800k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000505529100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Santodonato, LJ; Zhang, Y; Feygenson, M; Parish, CM; Gao, MC; Weber, RJK; Neuefeind, JC; Tang, Z; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Santodonato, Louis J.; Zhang, Yang; Feygenson, Mikhail; Parish, Chad M.; Gao, Michael C.; Weber, Richard J. K.; Neuefeind, Joerg C.; Tang, Zhi; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deviation from high-entropy configurations in the atomic distributions of a multi-principal-element alloy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The alloy-design strategy of combining multiple elements in near-equimolar ratios has shown great potential for producing exceptional engineering materials, often known as 'high-entropy alloys'. Understanding the elemental distribution, and, thus, the evolution of the configurational entropy during solidification, is undertaken in the present study using the Al1.3CoCr-CuFeNi model alloy. Here we show that, even when the material undergoes elemental segregation, precipitation, chemical ordering and spinodal decomposition, a significant amount of disorder remains, due to the distributions of multiple elements in the major phases. The results suggest that the high-entropy alloy-design strategy may be applied to a wide range of complex materials, and should not be limited to the goal of creating single-phase solid solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 574, "Times Cited, All Databases": 613, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5964, "DOI": "10.1038/ncomms6964", "DOI Link": "http://dx.doi.org/10.1038/ncomms6964", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348811100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, Z; Zhou, DJ; Wang, MY; Bak, SM; Wu, YS; Wu, ZS; Tian, Y; Xiong, XY; Li, YP; Liu, W; Siahrostami, S; Kuang, Y; Yang, XQ; Duan, HH; Feng, ZX; Wang, HL; Sun, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Zhao; Zhou, Daojin; Wang, Maoyu; Bak, Seong-Min; Wu, Yueshen; Wu, Zishan; Tian, Yang; Xiong, Xuya; Li, Yaping; Liu, Wen; Siahrostami, Samira; Kuang, Yun; Yang, Xiao-Qing; Duan, Haohong; Feng, Zhenxing; Wang, Hailiang; Sun, Xiaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Introducing Fe2+ into Nickel-Iron Layered Double Hydroxide: Local Structure Modulated Water Oxidation Activity", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring materials with regulated local structures and understanding how the atomic motifs govern the reactivity and durability of catalysts are a critical challenge for designing advanced catalysts. Herein we report the tuning of the local atomic structure of nickel-iron layered double hydroxides (NiFe-LDHs) by partially substituting Ni2+ with Fe2+ to introduce Fe-O-Fe moieties. These Fe2+-containing NiFe-LDHs exhibit enhanced oxygen evolution reaction (OER) activity with an ultralow overpotential of 195 mV at the current density of 10 mA cm(-2), which is among the best OER catalytic performance to date. In-situ X-ray absorption, Raman, and electrochemical analysis jointly reveal that the Fe-O-Fe motifs could stabilize high-valent metal sites at low overpotentials, thereby enhancing the OER activity. These results reveal the importance of tuning the local atomic structure for designing high efficiency electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2018, "Volume": 57, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9392, "End Page": 9396, "Article Number": null, "DOI": "10.1002/anie.201804881", "DOI Link": "http://dx.doi.org/10.1002/anie.201804881", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438712600029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, XY; Chen, GD; Lin, ST; Zhang, JJ; Wang, L; Zhang, P; Wang, ZY; Wang, ZB; Lan, Y; Ge, Q; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Xiangyu; Chen, Guangda; Lin, Shaoting; Zhang, Jiajun; Wang, Liu; Zhang, Pei; Wang, Zeyu; Wang, Zongbao; Lan, Yang; Ge, Qi; Liu, Ji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropically Fatigue-Resistant Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature builds biological materials from limited ingredients, however, with unparalleled mechanical performances compared to artificial materials, by harnessing inherent structures across multi-length-scales. In contrast, synthetic material design overwhelmingly focuses on developing new compounds, and fails to reproduce the mechanical properties of natural counterparts, such as fatigue resistance. Here, a simple yet general strategy to engineer conventional hydrogels with a more than 100-fold increase in fatigue thresholds is reported. This strategy is proven to be universally applicable to various species of hydrogel materials, including polysaccharides (i.e., alginate, cellulose), proteins (i.e., gelatin), synthetic polymers (i.e., poly(vinyl alcohol)s), as well as corresponding polymer composites. These fatigue-resistant hydrogels exhibit a record-high fatigue threshold over most synthetic soft materials, making them low-cost, high-performance, and durable alternatives to soft materials used in those circumstances including robotics, artificial muscles, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 33, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102011, "DOI": "10.1002/adma.202102011", "DOI Link": "http://dx.doi.org/10.1002/adma.202102011", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659786300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guesh, K; Caiuby, CAD; Mayoral, A; Díaz-García, M; Díaz, I; Sanchez-Sanchez, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guesh, Kiros; Caiuby, Clarice A. D.; Mayoral, Alvaro; Diaz-Garcia, Manuel; Diaz, Isabel; Sanchez-Sanchez, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainable Preparation of MIL-100(Fe) and Its Photocatalytic Behavior in the Degradation of Methyl Orange in Water", "Source Title": "CRYSTAL GROWTH & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The real industrial establishment of metal organic frameworks (MOFs) requires significant advances in economic and chemical sustainability. This work describes a novel and simple method to prepare one of the most widely studied MOF materials, i.e., MIL-100(Fe), which significantly improves the sustainability of the conventional process in several aspects. This MOF material is prepared (i) at room temperature (instead of 150 degrees C used in the conventional method), (ii) after a few hours (instead of 6 days), (iii) in the absence of any inorganic corrosive acid (significant amounts of HF and HNO3 are used in the conventional method), and (iv) it is washed at room temperature (unlike the washing at 80 degrees C for 3 h). Interestingly, the only difference in the preparation method of MIL-100(Fe) compared with that of semiamorphous Fe-BTC (MOF material commercialized as Basolite F300 having the same metal and linker, and which can be also prepared under similar sustainable conditions) is to start from Fe(II) or Fe(III) sources, respectively, which opens certain versatility options in the room temperature synthesis procedures of MOF materials. The prepared samples were characterized using X-ray diffraction, thermogravimetric analysis, N-2 adsorption/desorption isotherms, C-s-aberration corrected scanning transmission electron microscopy, and UV-vis diffuse reflectance spectroscopy. These two room-temperature-made Fe-BTC materials were tested in the industrially demanded photocatalytic degradation of methyl orange under both ultraviolet and solar light radiation. MIL100(Fe) was a very active photocatalyst in comparison with its homologue. That difference was mainly attributed to the presence of larger cavities within its structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 17, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1806, "End Page": 1813, "Article Number": null, "DOI": "10.1021/acs.cgd.6b01776", "DOI Link": "http://dx.doi.org/10.1021/acs.cgd.6b01776", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Crystallography; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398884400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, FY; Meng, K; Zhu, BC; Liu, HB; Xu, JS; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Feiyan; Meng, Kai; Zhu, Bicheng; Liu, Huibiao; Xu, Jingsan; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphdiyne: A New Photocatalytic CO2 Reduction Cocatalyst", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring new and efficient cocatalysts to boost photocatalytic CO2 reduction is of critical importance for solar-to-fuel conversion. As an emerging carbon allotrope, graphdiyne (GDY) features 2D characteristics and unique carbon-carbon bonds. Herein, a novel GDY cocatalyst coupled TiO2 nullofibers for boosted photocatalytic CO2 reduction, synthesized by an electrostatic self-assembly approach is reported. First-principle calculation and in situ X-ray photoelectron spectroscopy measurement reveal that the delocalized electrons in GDY can hybrid with the empty orbitals in TiO2 within the TiO2/GDY network, leading to the formation of an internal electric field at the interfaces, pointing from GDY to TiO2. The theoretical simulation further implies strong chemisorption and deformation of CO2 molecules upon GDY, which can be verified by in situ diffuse reflectance infrared Fourier transform spectroscopy. These effects, in combination with the photothermal effect of GDY, result in enhanced charge separation and directed electron transfer, enhanced CO2 adsorption and activation as well as accelerated catalytic reactions over the TiO2/GDY heterostructure, thereby resulting in significantly improved CO2 photoreduction efficiency and meanwhile with remarkable selectivity. This work demonstrates that GYD can function as a highly effective cocatalyst for solar energy harvesting and may be used in other catalysis processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 29, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904256, "DOI": "10.1002/adfm.201904256", "DOI Link": "http://dx.doi.org/10.1002/adfm.201904256", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481347000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, BL; Zhao, WK; Lin, CC; Yuan, Z; He, Y; Lu, L; Chen, MW; Ding, Y; Yang, YL; Xia, ZZL; Cai, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Bailong; Zhao, Weikang; Lin, Chuanchuan; Yuan, Zhang; He, Ye; Lu, Lu; Chen, Maowen; Ding, Yao; Yang, Yulu; Xia, Zengzilu; Cai, Kaiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface modification of titanium implants by ZIF-8@Levo/LBL coating for inhibition of bacterial-associated infection and enhancement of in vivo osseointegration", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bone implant-associated infection is one of the major concerns in orthopedics, and may even result in implant failure. To this end, we developed a strategy for the fabrication of an antibacterial coating on titanium (Ti) implants with pH-response to combat bacteria-mediated acidification of the local microenvironment. It includes three steps: first, we synthesized levofloxacin (Levo)-loaded zeolitic imidazolate framework-8 (ZIF-8@Levo) nulloparticles; second, the nulloparticles were loaded onto the collagen-modified Ti substrates by the cathode electrophoresis deposition (EPD) method; third, gelatin (Gel) and chitosan (Chi) multilayers were spin-coated on the modified Ti substrates, since the chelating effect of Gel and Chi would reduce the hydrolysis of ZIF-8@Levo for a sustained release of Levo and Zn2+. The fabricated samples of MOF@Levo/LBL promoted in vitro adhesion, proliferation, and differentiation of osteoblasts. Moreover, the MOF@Levo/LBL samples exhibited strong antibacterial ability against Escherichia coli and Staphylococcus aureus through hydrolysis of ZIF-8 nulloparticles, thereby creating a marginally alkaline microenvironment. Furthermore, in vivo implantation in a femur-infected rat model revealed that MOF@Levo/LBL implants effectively inhibited bacterial adhesion, apart from significantly improving osseointegration of the Ti implants. The study provides a promising alternative for fabricating multifunctional Ti implants with strong antibacterial capacity and enhanced bone formation for potential orthopedic application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2020, "Volume": 390, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124621, "DOI": "10.1016/j.cej.2020.124621", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.124621", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522640100122", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goikolea, E; Palomares, V; Wang, SJ; de Larramendi, IR; Guo, X; Wang, GX; Rojo, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goikolea, Eider; Palomares, Veronica; Wang, Shijian; de Larramendi, Idoia Ruiz; Guo, Xin; Wang, Guoxiu; Rojo, Teofilo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Na-Ion Batteries-Approaching Old and New Challenges", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The last 10 years established the beginning of a post-lithium era in the field of energy storage, with the renaissance of Na-ion batteries (NIBs) as alternative for Li-based systems. The development of this technology has required intense work in materials research in order to produce and optimize anodes, cathodes, and electrolytes for NIBs. The strong and weak points of the main families of compounds for each battery component are analyzed in this progress report. Taking into account the achievements made in materials for NIBs, the industrial scene is analyzed through the existing prototypes and commercial cells and also from an economical viewpoint. In this scenario, where Na-ion technology seems to be ready for a coming second generation, the use of Na can be extended to almost the whole spectrum of electrochemical energy storage systems: the new room temperature Na-S systems, high-energy Na-air technology, or high-power Na-based hybrid supercapacitors. Thus, the degree of development of NIBs, together with the promising performance of newer Na-based energy storage systems, makes Na the key to the coming commercial post-lithium systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 10, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002055, "DOI": "10.1002/aenm.202002055", "DOI Link": "http://dx.doi.org/10.1002/aenm.202002055", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000576659400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CW; Wang, XM; Bi, EB; Jiang, FY; Park, SM; Li, Y; Chen, L; Wang, ZW; Zeng, LW; Chen, H; Liu, YJ; Grice, CR; Abudulimu, A; Chung, JH; Xian, YM; Zhu, T; Lai, HG; Chen, B; Ellingson, RJ; Fu, F; Ginger, DS; Song, ZN; Sargent, EH; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chongwen; Wang, Xiaoming; Bi, Enbing; Jiang, Fangyuan; Park, So Min; Li, You; Chen, Lei; Wang, Zaiwei; Zeng, Lewei; Chen, Hao; Liu, Yanjiang; Grice, Corey R.; Abudulimu, Abasi; Chung, Jaehoon; Xian, Yeming; Zhu, Tao; Lai, Huagui; Chen, Bin; Ellingson, Randy J.; Fu, Fan; Ginger, David S.; Song, Zhaoning; Sargent, Edward H.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of Lewis base molecules for stable and efficient inverted perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lewis base molecules that bind undercoordinated lead atoms at interfaces and grain boundaries (GBs) are known to enhance the durability of metal halide perovskite solar cells (PSCs). Using density functional theory calculations, we found that phosphine-containing molecules have the strongest binding energy among members of a library of Lewis base molecules studied herein. Experimentally, we found that the best inverted PSC treated with 1,3-bis(diphenylphosphino)propane (DPPP), a diphosphine Lewis base that passivates, binds, and bridges interfaces and GBs, retained a power conversion efficiency (PCE) slightly higher than its initial PCE of similar to 23% after continuous operation under simulated AM1.5 illumination at the maximum power point and at similar to 40 degrees C for >3500 hours. DPPP-treated devices showed a similar increase in PCE after being kept under open-circuit conditions at 85 degrees C for >1500 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2023, "Volume": 379, "Issue": 6633, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 694, "Article Number": null, "DOI": "10.1126/science.ade3970", "DOI Link": "http://dx.doi.org/10.1126/science.ade3970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001016371000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Schweitzer, NM; League, AB; Bernales, V; Peters, AW; Getsoian, A; Wang, TC; Miller, JT; Vjunov, A; Fulton, JL; Lercher, JA; Cramer, CJ; Gagliardi, L; Hupp, JT; Farha, OK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B.; Bernales, Varinia; Peters, Aaron W.; Getsoian, Andrew Bean; Wang, Timothy C.; Miller, Jeffrey T.; Vjunov, Aleksei; Fulton, John L.; Lercher, Johannes A.; Cramer, Christopher J.; Gagliardi, Laura; Hupp, Joseph T.; Farha, Omar K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing supported single-site catalysts is an important goal in heterogeneous catalysis since the well-defined active sites afford opportunities for detailed mechanistic studies, thereby facilitating the design of improved catalysts. We present herein a method for installing Ni ions uniformly and precisely on the node of a Zr-based metal-organic framework (MOF), NU-1000, in high density and large quantity (denoted as Ni-AIM) using atomic layer deposition (ALD) in a MOF (AIM). Ni-AIM is demonstrated to be an efficient gas-phase hydrogenation catalyst upon activation. The structure of the active sites in Ni-AIM is proposed, revealing its single-site nature. More importantly, due to the organic linker used to construct the MOF support, the Ni ions stay isolated throughout the hydrogenation catalysis, in accord with its long-term stability. A quantum chemical characterization of the catalyst and the catalytic process complements the experimental results. With validation of computational modeling protocols, we further targeted ethylene oligomerization catalysis by Ni-AIM guided by theoretical prediction. Given the generality of the AIM methodology, this emerging class of materials should prove ripe for the discovery of new catalysts for the transformation of volatile substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2016, "Volume": 138, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1977, "End Page": 1982, "Article Number": null, "DOI": "10.1021/jacs.5b12515", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b12515", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370582900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Poerwoprajitno, AR; Gloag, L; Watt, J; Cheong, S; Tan, X; Lei, H; Tahini, HA; Henson, A; Subhash, B; Bedford, NM; Miller, BK; O'Mara, PB; Benedetti, TM; Huber, DL; Zhang, WH; Smith, SC; Gooding, JJ; Schuhmann, W; Tilley, RD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Poerwoprajitno, Agus R.; Gloag, Lucy; Watt, John; Cheong, Soshan; Tan, Xin; Lei, Han; Tahini, Hassan A.; Henson, Aaron; Subhash, Bijil; Bedford, Nicholas M.; Miller, Benjamin K.; O'Mara, Peter B.; Benedetti, Tania M.; Huber, Dale L.; Zhang, Wenhua; Smith, Sean C.; Gooding, J. Justin; Schuhmann, Wolfgang; Tilley, Richard D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A single-Pt-atom-on-Ru-nulloparticle electrocatalyst for CO-resilient methanol oxidation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single Pt atom catalysts are key targets because a high exposure of Pt substantially enhances electrocatalytic activity. In addition, PtRu alloy nulloparticles are the most active catalysts for the methanol oxidation reaction. To combine the exceptional activity of single Pt atom catalysts with an active Ru support we must overcome the synthetic challenge of forming single Pt atoms on noble metal nulloparticles. Here we demonstrate a process that grows and spreads Pt islands on Ru branched nulloparticles to create single-Pt-atom-on-Ru catalysts. By following the spreading process by in situ TEM, we found that the formation of a stable single atom structure is thermodynamically driven by the formation of strong Pt-Ru bonds and the lowering of the surface energy of the Pt islands. The stability of the single-Pt-atom-on-Ru structure and its resilience to CO poisoning result in a high current density and mass activity for the methanol oxidation reaction over time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 231, "End Page": 237, "Article Number": null, "DOI": "10.1038/s41929-022-00756-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00756-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783096900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nakatsuka, N; Yang, KA; Abendroth, JM; Cheung, KM; Xu, XB; Yang, HY; Zhao, CZ; Zhu, BW; Rim, YS; Yang, Y; Weiss, PS; Stojanovic, MN; Andrews, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nakatsuka, Nako; Yang, Kyung-Ae; Abendroth, John M.; Cheung, Kevin M.; Xu, Xiaobin; Yang, Hongyan; Zhao, Chuanzhen; Zhu, Bowen; Rim, You Seung; Yang, Yang; Weiss, Paul S.; Stojanovic, Milan N.; Andrews, Anne M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aptamer-field-effect transistors overcome Debye length limitations for small-molecule sensing", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detection of analytes by means of field-effect transistors bearing ligand-specific receptors is fundamentally limited by the shielding created by the electrical double layer (the Debye length limitation). We detected small molecules under physiological high-ionic strength conditions by modifying printed ultrathin metal-oxide field-effect transistor arrays with deoxyribonucleotide aptamers selected to bind their targets adaptively. Target-induced conformational changes of negatively charged aptamer phosphodiester backbones in close proximity to semiconductor channels gated conductance in physiological buffers, resulting in highly sensitive detection. Sensing of charged and electroneutral targets (serotonin, dopamine, glucose, and sphingosine-1-phosphate) was enabled by specifically isolated aptameric stem-loop receptors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 693, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2018, "Volume": 362, "Issue": 6412, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 319, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aao6750", "DOI Link": "http://dx.doi.org/10.1126/science.aao6750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447680100043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, Y; Li, RY; Jin, Y; Zhuo, SF; Shi, L; Chang, J; Hong, S; Ng, KC; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yusuf; Li, Renyuan; Jin, Yong; Zhuo, Sifei; Shi, Le; Chang, Jian; Hong, Seunghyun; Ng, Kim-Choon; Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 3D Photothermal Structure toward Improved Energy Efficiency in Solar Steam Generation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energy efficiency in solar steam generation by 2D photothermal materials has approached its limit. In this work, we fabricated 3D cylindrical cup-shaped structures of mixed metal oxide as solar evaporator, and the 3D structure led to a high energy efficiency close to 100% under one-sun illumination due to the capability of the cup wall to recover the diffuse reflectance and thermal radiation heat loss from the 2D cup bottom. Additional heat was gained from the ambient air when the 3D structure was exposed under one-sun illumination, leading to an extremely high steam generation rate of 2.04 kg m(-2) h(-1). The 3D structure has a high thermal stability and shows great promise in practical applications including domestic wastewater volume reduction and seawater desalination. The results of this work inspire further research efforts to use 3D photothermal structures to break through the energy efficiency limit of 2D photothermal materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 586, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2018, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1171, "End Page": 1186, "Article Number": null, "DOI": "10.1016/j.joule.2018.03.013", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.03.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437403100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Yuan, LB; Ye, C; Chao, DL; Davey, K; Guo, ZP; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Yuan, Libei; Ye, Chao; Chao, Dongliang; Davey, Kenneth; Guo, Zaiping; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Zinc Electrode Reversibility in Aqueous Electrolytes by Using Low-Cost Antisolvents", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antisolvent addition has been widely studied in crystallization in the pharmaceutical industries by breaking the solvation balance of the original solution. Here we report a similar antisolvent strategy to boost Zn reversibility via regulation of the electrolyte on a molecular level. By adding for example methanol into ZnSO4 electrolyte, the free water and coordinated water in Zn2+ solvation sheath gradually interact with the antisolvent, which minimizes water activity and weakens Zn2+ solvation. Concomitantly, dendrite-free Zn deposition occurs via change in the deposition orientation, as evidenced by in situ optical microscopy. Zn reversibility is significantly boosted in antisolvent electrolyte of 50 % methanol by volume (Anti-M-50 %) even under harsh environments of -20 degrees C and 60 degrees C. Additionally, the suppressed side reactions and dendrite-free Zn plating/stripping in Anti-M-50 % electrolyte significantly enhance performance of Zn/polyaniline coin and pouch cells. We demonstrate this low-cost strategy can be readily generalized to other solvents, indicating its practical universality. Results will be of immediate interest and benefit to a range of researchers in electrochemistry and energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 696, "Times Cited, All Databases": 719, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2021, "Volume": 60, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7366, "End Page": 7375, "Article Number": null, "DOI": "10.1002/anie.202016531", "DOI Link": "http://dx.doi.org/10.1002/anie.202016531", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621048500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Ren, QY; Gu, ZQ; Duan, CM; Wang, JZ; Zhu, F; Fu, YY; Hao, JP; Zhu, JF; He, LH; Wang, CW; Lu, YY; Ma, J; Ma, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kai; Ren, Qingyong; Gu, Zhenqi; Duan, Chaomin; Wang, Jinzhu; Zhu, Feng; Fu, Yuanyuan; Hao, Jipeng; Zhu, Jinfeng; He, Lunhua; Wang, Chin-Wei; Lu, Yingying; Ma, Jie; Ma, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A cost-effective and humidity-tolerant chloride solid electrolyte for lithium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-ion-conducting chloride solid electrolytes receive considerable attention due to their physicochemical characteristics such as high ionic conductivity, deformability and oxidative stability. However, the raw materials are expensive, and large-scale use of this class of inorganic superionic conductors seems unlikely. Here, a cost-effective chloride solid electrolyte, Li2ZrCl6, is reported. Its raw materials are several orders of magnitude cheaper than those for the state-of-the-art chloride solid electrolytes, but high ionic conductivity (0.81 mS cm(-1) at room temperature), deformability, and compatibility with 4V-class cathodes are still simultaneously achieved in Li2ZrCl6. Moreover, Li2ZrCl6 demonstrates a humidity tolerance with no sign of moisture uptake or conductivity degradation after exposure to an atmosphere with 5% relative humidity. By combining Li2ZrCl6 with the Li-In anode and the single-crystal LiNi0.8Mn0.1Co0.1O2 cathode, we report a room-temperature all-solid-state cell with a stable specific capacity of about 150 mAh g(-1) for 200 cycles at 200mAg(-1). Stable inorganic solid electrolytes are instrumental in developing high-voltage Li metal batteries. Here, the authors present the synthesis and electrochemical energy storage properties of a cost-effective and humidity-tolerant chloride solid electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4410, "DOI": "10.1038/s41467-021-24697-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24697-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677641700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Engel, M; Steiner, M; Avouris, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Engel, Michael; Steiner, Mathias; Avouris, Phaedon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus Photodetector for Multispectral, High-Resolution Imaging", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus is a layered semiconductor that is intensely researched in view of applications in optoelectronics. In this letter, we investigate a multilayer black phosphorus photodetector that is capable of acquiring high-contrast (V > 0.9) images both in the visible (lambda(VIS) = 532 nm) as well as in the infrared (lambda(IR) = 1550 nm) spectral regime. In a first step, by using photocurrent microscopy, we map the active area of the device and we characterize responsivity and gain. In a second step, by deploying the black phosphorus device as a point-like detector in a confocal microsope setup, we acquire diffraction-limited optical images with submicron resolution. The results demonstrate the usefulness of black phosphorus as an optoelectronic material for hyperspectral imaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 630, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6414, "End Page": 6417, "Article Number": null, "DOI": "10.1021/nl502928y", "DOI Link": "http://dx.doi.org/10.1021/nl502928y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345723800060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, Y; Oh, JY; Xu, W; Kim, O; Kim, TR; Kang, J; Kim, Y; Son, D; Tok, JBH; Park, MJ; Bao, ZN; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Yeongjun; Oh, Jin Young; Xu, Wentao; Kim, Onnuri; Kim, Taeho Roy; Kang, Jiheong; Kim, Yeongin; Son, Donghee; Tok, Jeffery B-H; Park, Moon Jeong; Bao, Zhenull; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable organic optoelectronic sensorimotor synapse", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emulation of human sensory and motor functions becomes a core technology in bioinspired electronics for next-generation electronic prosthetics and neurologically inspired robotics. An electronic synapse functionalized with an artificial sensory receptor and an artificial motor unit can be a fundamental element of bioinspired soft electronics. Here, we report an organic optoelectronic sensorimotor synapse that uses an organic optoelectronic synapse and a neuromuscular system based on a stretchable organic nullowire synaptic transistor (s-ONWST). The voltage pulses of a self-powered photodetector triggered by optical signals drive the s-ONWST, and resultant informative synaptic outputs are used not only for optical wireless communication of human-machine interfaces but also for light-interactive actuation of an artificial muscle actuator in the same way that a biological muscle fiber contracts. Our organic optoelectronic sensorimotor synapse suggests a promising strategy toward developing bioinspired soft electronics, neurologically inspired robotics, and electronic prostheses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat7387", "DOI": "10.1126/sciadv.aat7387", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat7387", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452212000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burger, B; Maffettone, PM; Gusev, VV; Aitchison, CM; Bai, Y; Wang, XY; Li, XB; Alston, B; Li, BY; Clowes, R; Rankin, N; Harris, B; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burger, Benjamin; Maffettone, Phillip M.; Gusev, Vladimir V.; Aitchison, Catherine M.; Bai, Yang; Wang, Xiaoyan; Li, Xiaobo; Alston, Ben M.; Li, Buyi; Clowes, Rob; Rankin, Nicola; Harris, Brandon; Sprick, Reiner Sebastian; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mobile robotic chemist", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Technologies such as batteries, biomaterials and heterogeneous catalysts have functionsthat are defined by mixtures of molecular and mesoscale components. As yet, this multi-length-scale complexity cannot be fully captured by atomistic simulations, and the design of such materials from first principles is still rare(1-5). Likewise, experimental complexity scales exponentially with the number of variables, restricting most searches to narrow areas of materials space. Robots can assist in experimental searches(6-14)but their widespread adoption in materials research is challenging because of the diversity of sample types, operations, instruments and measurements required. Here we use a mobile robot to search for improved photocatalysts for hydrogen production from water(15). The robot operated autonomously over eight days, performing 688 experiments within a ten-variable experimental space, driven by a batched Bayesian search algorithm(16-18). This autonomous search identified photocatalyst mixturesthat were six times more active than the initial formulations, selecting beneficial components and deselecting negative ones. Our strategy uses a dexterous(19,20)free-roaming robot(21-24), automating the researcher ratherthan the instruments. This modular approach could be deployed in conventional laboratories for a range of research problems beyond photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 793, "Times Cited, All Databases": 877, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2020, "Volume": 583, "Issue": 7815, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 237, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2442-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2442-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546767100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, A; Jiang, ZW; Wu, Y; Hussain, H; Rawle, J; Briggs, ME; Little, MA; Livingston, AG; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Ai; Jiang, Zhiwei; Wu, Yue; Hussain, Hadeel; Rawle, Jonathan; Briggs, Michael E.; Little, Marc A.; Livingston, Andrew G.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The separation of multicomponent mixtures is performed by distillation, as multiple-membrane cascades are too complex. Here, a porous organic cage composite undergoes solid-state transformation in solvent; this alters pore size, enabling graded separation of three dyes with a single membrane. Membranes with high selectivity offer an attractive route to molecular separations, where technologies such as distillation and chromatography are energy intensive. However, it remains challenging to fine tune the structure and porosity in membranes, particularly to separate molecules of similar size. Here, we report a process for producing composite membranes that comprise crystalline porous organic cage films fabricated by interfacial synthesis on a polyacrylonitrile support. These membranes exhibit ultrafast solvent permeance and high rejection of organic dyes with molecular weights over 600 g mol(-1). The crystalline cage film is dynamic, and its pore aperture can be switched in methanol to generate larger pores that provide increased methanol permeance and higher molecular weight cut-offs (1,400 g mol(-1)). By varying the water/methanol ratio, the film can be switched between two phases that have different selectivities, such that a single, 'smart' crystalline membrane can perform graded molecular sieving. We exemplify this by separating three organic dyes in a single-stage, single-membrane process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 21, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 463, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-021-01168-z", "DOI Link": "http://dx.doi.org/10.1038/s41563-021-01168-z", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741634500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, NW; Guiver, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, nullwen; Guiver, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion Transport by nullochannels in Ion-Containing Aromatic Copolymers", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for the next generation of highly ion-conducting polymer electrolyte membranes has been a subject of intense research because of their potential applications in energy storage and transformation devices, such as fuel cells, vanadium flow batteries, membrane-based artificial photosynthesis, water electrolysis, or water treatment processes such as electrodialysis desalination. nullochannels that contain ionic groups, through which hydrated ions can pass, are believed to be of key importance for efficient ion transport in polymer electrolytes membranes. In this Perspective, we present an overview of the approaches to induce ion-conducting nullochannel formation by self-assembly, using polymer architecture such as block or comb-shaped copolymers. The transport properties of ion-containing aromatic copolymers are examined to obtain an insight into the fundamental behavior of these materials, which are targeted toward applications in fuel cells and other electrochemical devices. Challenges in obtaining well-defined nullochannel morphologies, and possible strategies to improve transport properties in aromatic copolymers having structures with the potential to withstand operation in electrochemical/chemical devices, are discussed. Opportunities for the application of ion-containing aromatic copolymer membranes in fuel cells, vanadium flow batteries, membrane-based artificial photosynthesis, electrolysis, and electrodialysis are also reviewed. Research needs for further improvements in ionic conductivity and durability, and their applications are identified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2014, "Volume": 47, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2175, "End Page": 2198, "Article Number": null, "DOI": "10.1021/ma402254h", "DOI Link": "http://dx.doi.org/10.1021/ma402254h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338807300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HT; Xiao, R; Huang, JR; Jiang, Y; Zhao, CX; Yang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Haotian; Xiao, Rong; Huang, Jingran; Jiang, Yan; Zhao, Chengxiao; Yang, Xiaofei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ construction of protonated g-C3N4/Ti3C2 MXene Schottky heterojunctions for efficient photocatalytic hydrogen production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Converting sustainable solar energy into hydrogen energy over semiconductor-based photocatalytic materials provides an alternative to fossil fuel consumption. However, efficient photocatalytic splitting of water to realize carbon-free hydrogen production remains a challenge. Heterojunction photocatalysts with well-defined dimensionality and perfectly matched interfaces are promising for achieving highly efficient solar-to-hydrogen conversion. Herein, we report the fabrication of a novel type of protonated graphitic carbon nitride (PCN)/Ti(3)C(2)MXene heterojunctions with strong interfacial interactions. As expected, the two-dimensional (2D) PCN/2D Ti3C2 MXene interface heterojunction achieves a highly improved hydrogen evolution rate (2181 mu mol.g(-1)) in comparison with bulk g-C3N4 (393 mu mol.g(-1)) and protonated g-C3N4 (816 mu mol.g(-1)). The charge-regulated surfaces of PCN and the accelerated charge transport at the face-to-face 2D/2D Schottky heterojunction interface are the major contributors to the excellent hydrogen evolution performance of the composite photocatalyst. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 107, "End Page": 114, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63559-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63559-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Jia, GR; Cui, XQ; Zhao, X; Zhang, QH; Gu, L; Zheng, LR; Li, LH; Wu, Q; Singh, DJ; Matsumura, D; Tsuji, T; Cui, YT; Zhao, J; Zheng, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ying; Jia, Guangri; Cui, Xiaoqiang; Zhao, Xiao; Zhang, Qinghua; Gu, Lin; Zheng, Lirong; Li, Lu Hua; Wu, Qiong; Singh, David J.; Matsumura, Daiju; Tsuji, Takuya; Cui, Yi-Tao; Zhao, Jingxiang; Zheng, Weitao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination Number Regulation of Molybdenum Single-Atom nullozyme Peroxidase-like Specificity", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullozymes are promising alternatives to natural enzymes, but their use remains limited owing to poor specificity. Overcoming this and controlling the targeted enzyme-like performance of traditional nullozymes is extremely challenging due to the intrinsic structural complexity of these systems. We report theoretical design and experimental realization of a series of heterogeneous molybdenum single-atom nullozymes (named Mo-SA-N-x-C), wherein we find that the peroxidase-like specificity is well regulated by the coordination numbers of single Mo sites. The resulting Mo-SA-N-3-C catalyst shows exclusive peroxidase-like behavior. It achieves this behavior via a homolytic pathway, whereas Mo-SA-N-2-C and Mo-SA-N-4-C catalysts have a different heterolytic pathway. The mechanism of this coordination-number-dependent enzymatic specificity is attributed to geometrical structure differences and orientation relationships of the frontier molecular orbitals toward these Mo-SA-N-x-C peroxidase mimics. This study demonstrates the rational design of peroxidase-specific nullozymes and precise regulation of their enzymatic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2021, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 436, "End Page": 449, "Article Number": null, "DOI": "10.1016/j.chempr.2020.10.023", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.10.023", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628784800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YT; Li, M; Pan, GY; Chen, JY; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yutong; Li, Meng; Pan, Guoying; Chen, Jueying; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple Stimuli-Responsive nullozyme-Based Cryogels with Controlled NO Release as Self-Adaptive Wound Dressing for Infected Wound Healing", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wound with drug-resistant bacterial infections has become a serious challenge for the healthcare system, and designing wound dressing to self-adapt to the need of different stage of wound healing remains challenging. Herein, self-adaptive wound dressings with multiple stimuli-responsiveness and antibacterial activity are developed. Specifically, MoS2 carrying a reactive oxygen species (ROS) responsive nitric oxide (NO) release precursor L-arginine (MSPA) is designed and incorporated into carboxymethyl chitosan/poly(N-isopropylacrylamide) based cryogels (CMCS/PNIPAM) with multiple responsiveness (pH, near infrared (NIR), and temperature) to form self-adaptive antibacterial cryogels that adapt to the therapeutic needs of different stages in infected wound healing. In response to the slightly acidic environment of bacterial infection, the cryogels assist the bacterial capture capacity through acid-triggered protonation behavior, and effectively enhance the photodynamic antibacterial efficiency. Controllable on-demand delivery of ROS, NO, and remote management of infected biofluid are achieved with NIR light as a trigger switch. The multiple stimuli-responsive nullozyme-based cryogels efficiently eliminate MRSA bacterial biofilm through NO assisted photodynamicand photothermal therapy (PDT&PTT). The multiple enzyme-like activities of the cryogels effectively relieved oxidative damage. Notably, these cryogels effectively reduce wound infection, alleviated oxidative stress, and accelerate collagen deposition and angiogenesis in infected wounds, indicating that multiple stimuli-responsive self-adaptive wound dressings provide new ideas for infected wound treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 33, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202214089", "DOI Link": "http://dx.doi.org/10.1002/adfm.202214089", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972871900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, L; Hamidinejad, M; Zhao, B; Liang, CY; Park, CB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Li; Hamidinejad, Mahdi; Zhao, Biao; Liang, Caiyun; Park, Chul B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layered Foam/Film Polymer nullocomposites with Highly Efficient EMI Shielding Properties and Ultralow Reflection", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lightweight, high-efficiency and low reflection electromagnetic interference (EMI) shielding polymer composites are greatly desired for addressing the challenge of ever-increasing electromagnetic pollution. Lightweight layered foam/film PVDF nullocomposites with efficient EMI shielding effectiveness and ultralow reflection power were fabricated by physical foaming. The unique layered foam/film structure was composed of PVDF/SiCnw/MXene (Ti3C2Tx) composite foam as absorption layer and highly conductive PVDF/MWCNT/GnPs composite film as a reflection layer. The foam layer with numerous heterogeneous interfaces developed between the SiC nullowires (SiCnw) and 2D MXene nullosheets imparted superior EM wave attenuation capability. Furthermore, the microcellular structure effectively tuned the impedance matching and prolonged the wave propagating path by internal scattering and multiple reflections. Meanwhile, the highly conductive PVDF/MWCNT/GnPs composite (similar to 220 S m(-1)) exhibited superior reflectivity (R) of 0.95. The tailored structure in the layered foam/film PVDF nullocomposite exhibited an EMI SE of 32.6 dB and a low reflection bandwidth of 4 GHz (R < 0.1) over the Ku-band (12.4 - 18.0 GHz) at a thickness of 1.95 mm. A peak SER of 3.1 x 10(-4) dB was obtained which corresponds to only 0.0022% reflection efficiency. In consequence, this study introduces a feasible approach to develop lightweight, high-efficiency EMI shielding materials with ultralow reflection for emerging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 19, "DOI": "10.1007/s40820-021-00759-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00759-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000728327000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Malta, G; Kondrat, SA; Freakley, SJ; Davies, CJ; Lu, L; Dawson, S; Thetford, A; Gibson, EK; Morgan, DJ; Jones, W; Wells, PP; Johnston, P; Catlow, CRA; Kiely, CJ; Hutchings, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Malta, Grazia; Kondrat, Simon A.; Freakley, Simon J.; Davies, Catherine J.; Lu, Li; Dawson, Simon; Thetford, Adam; Gibson, Emma K.; Morgan, David J.; Jones, Wilm; Wells, Peter P.; Johnston, Peter; Catlow, C. Richard A.; Kiely, Christopher J.; Hutchings, Graham J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of single-site gold catalysis in acetylene hydrochlorination", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There remains considerable debate over the active form of gold under operating conditions of a recently validated gold catalyst for acetylene hydrochlorination. We have performed an in situ x-ray absorption fine structure study of gold/carbon (Au/C) catalysts under acetylene hydrochlorination reaction conditions and show that highly active catalysts comprise single-site cationic Au entities whose activity correlates with the ratio of Au(I): Au(III) present. We demonstrate that these Au/C catalysts are supported analogs of single-site homogeneous Au catalysts and propose a mechanism, supported by computational modeling, based on a redox couple of Au(I)-Au(III) species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2017, "Volume": 355, "Issue": 6332, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1399, "End Page": 1402, "Article Number": null, "DOI": "10.1126/science.aal3439", "DOI Link": "http://dx.doi.org/10.1126/science.aal3439", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397809500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, LL; Liu, SF; Wang, LL; Ma, CD; Wu, JY; An, LY; Hu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Linli; Liu, Shenfang; Wang, Linlin; Ma, Changdan; Wu, Jiayi; An, Liying; Hu, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-doped porous carbons from low-temperature and single-step sodium amide activation of carbonized water chestnut shell with excellent CO2 capture performance", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this study is to exploit low-cost N-doped porous carbonaceous adsorbents with excellent CO2 adsorption properties. Herein, the N-enriched porous carbons were obtained through a single-step sodium amide activation of carbonized water chestnut shell at 400-500 degrees C. The optimal sample possesses high CO2 uptake of 4.50 mmol/g (25 degrees C) and 6.04 mmol/g (0 degrees C) at atmospheric pressure. Additionally, this sample displays high CO2/N-2 selectivity, stable cyclic ability, moderate CO2 isosteric heat of adsorption, fast CO2 adsorption rate, and high dynamic CO2 uptake. In addition to the two well-known factors i.e. volume of narrow micropore and N content, the pore size distribution is also found to play major role in deciding CO2 adsorption performance for these adsorbents. The features of excellent CO2 adsorption properties, low-cost raw materials, low reaction temperature and facile preparation demonstrate that these adsorbents are prospective in the application of CO2 capture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2019, "Volume": 359, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 428, "End Page": 435, "Article Number": null, "DOI": "10.1016/j.cej.2018.11.065", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.11.065", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454137400043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Y; Li, JH; Solomon, SA; Min, JH; Tu, JB; Guo, W; Xu, CH; Song, Y; Gao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, You; Li, Jiahong; Solomon, Samuel A.; Min, Jihong; Tu, Jiaobing; Guo, Wei; Xu, Changhao; Song, Yu; Gao, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-printed soft human-machine interface for robotic physicochemical sensing", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrasensitive multimodal physicochemical sensing for autonomous robotic decision-making has numerous applications in agriculture, security, environmental protection, and public health. Previously reported robotic sensing technologies have primarily focused on monitoring physical parameters such as pressure and temperature. Integrating chemical sensors for autonomous dry-phase analyte detection on a robotic platform is rather extremely challenging and substantially underdeveloped. Here, we introduce an artificial intelligence-powered multimodal robotic sensing system (M-Bot) with an all-printed mass-producible soft electronic skin-based human-machine interface. A scalable inkjet printing technology with custom-developed nullomaterial inks was used to manufacture flexible physicochemical sensor arrays for electrophysiology recording, tactile perception, and robotic sensing of a wide range of hazardous materials including nitroaromatic explosives, pesticides, nerve agents, and infectious pathogens such as SARS-CoV-2. The M-Bot decodes the surface electromyography signals collected from the human body through machine learning algorithms for remote robotic control and can perform in situ threat compound detection in extreme or contaminated environments with user-interactive tactile and threat alarm feedback. The printed electronic skin-based robotic sensing technology can be further generalized and applied to other remote sensing platforms. Such diversity was validated on an intelligent multimodal robotic boat platform that can efficiently track the source of trace amounts of hazardous compounds through autonomous and intelligent decision-making algorithms. This fully printed human-machine interactive multimodal sensing technology could play a crucial role in designing future intelligent robotic systems and can be easily reconfigured toward numerous practical wearable and robotic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2022, "Volume": 7, "Issue": 67, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabn0495", "DOI": "10.1126/scirobotics.abn0495", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.abn0495", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853410700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, L; Liang, ZM; Wu, LM; Chen, YX; Song, YF; Dhanabalan, SC; Ponraj, JS; Dong, BQ; Xiang, YJ; Xing, F; Fan, DY; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Lu; Liang, Zhiming; Wu, Leiming; Chen, YunXiang; Song, Yufeng; Dhanabalan, Sathish Chander; Ponraj, Joice Sophia; Dong, Biqin; Xiang, Yuanjiang; Xing, Feng; Fan, Dianyuan; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Few-layer Bismuthene: Sonochemical Exfoliation, Nonlinear Optics and Applications for Ultrafast Photonics with Enhanced Stability", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the last element in Group VA, bismuthene has garnered substantial interest for its unique electronic and mechanical properties and its enhanced stability. However, the mechanism that drives the light-bismuthene interaction remains completely unclear. Herein, a sonochemical exfoliation approach is employed to deliver a successful synthesis of few-layer bismuthene. The corresponding nonlinear optical response at the visible wavelength is investigated. The nonlinear refractive index is approximate to 10(-6) cm(2)/W and was measured by spatial self-phase modulation. Thanks to its direct energy band-gap at 1550 nm, the saturable absorption property of bismuthene is experimentally illustrated at the telecommunication band with an optical modulation depth of approximate to 2.03% and a saturable intensity of approximate to 30 MW/cm(2). The optimization of the laser parameters resulted in the generation of an approximate to 652-femtosecond optical pulse centered at 1559.18 nm. This result indicates that the bismuthene-based saturable absorber is indeed a new and excellent material for an ultrafast saturable absorber device. Our work highlights the promise of this material in ultrafast photonics and may be considered as an important step towards bismuthene-based photonics devices (optical modulator, optical switcher, detector, etc.).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700221, "DOI": "10.1002/lpor.201700221", "DOI Link": "http://dx.doi.org/10.1002/lpor.201700221", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419666500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Iscen, A; Palmer, LC; Schatz, GC; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chuang; Iscen, Aysenur; Palmer, Liam C.; Schatz, George C.; Stupp, Samuel, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-Driven Expansion of Spiropyran Hydrogels", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The incorporation of molecular switches in organic structures is of great interest in the chemical design of stimuli-responsive materials that mimic the complex functions of living systems. Merocyanine dyes that convert to spiropyran moieties upon exposure to visible light have been extensively studied as they can be incorporated in hydrated covalent networks that will expel water when this conversion occurs and induce a volumetric shrinkage. We report here on a sulfonate-based water-soluble photoswitch that, in contrast to the well-known systems, triggers a volumetric expansion in hydrogels upon exposure to photons. Contraction is in turn observed under dark conditions in a highly reversible manner. The novel behavior of the photoswitch incorporated in the covalent network was predicted by coarse-grained simulations of the system's chemical structure. Using pH control and polymeric structures that differ in lower critical solution temperature, we were able to develop hydrogels with highly tunable volumetric expansion. The novel molecular function of the systems developed here led to materials with the negative phototaxis observed in plants and could expand the potential use of hydrogels as sensors, soft robots, and actuators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 554, "Times Cited, All Databases": 595, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2020, "Volume": 142, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8447, "End Page": 8453, "Article Number": null, "DOI": "10.1021/jacs.0c02201", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c02201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535173500045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YG; Wu, ZS; Lu, PF; Wang, X; Liu, W; Liu, ZB; Ma, JY; Ren, WC; Jiang, Z; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yaguang; Wu, Zhong-Shuai; Lu, Pengfei; Wang, Xiao; Liu, Wei; Liu, Zhibo; Ma, Jingyuan; Ren, Wencai; Jiang, Zheng; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Valence Nickel Single-Atom Catalysts Coordinated to Oxygen Sites for Extraordinarily Activating Oxygen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) are efficient for maximizing electrocatalytic activity, but have unsatisfactory activity for the oxygen evolution reaction (OER). Herein, the NaCl template synthesis of individual nickel (Ni) SACs is reported, bonded to oxygen sites on graphene-like carbon (denoted as Ni-O-G SACs) with superior activity and stability for OER. A variety of characterizations unveil that the Ni-O-G SACs present 3D porous framework constructed by ultrathin graphene sheets, single Ni atoms, coordinating nickel atoms to oxygen. Consequently, the catalysts are active and robust for OER with extremely low overpotential of 224 mV at current density of 10 mA cm(-2), 42 mV dec(-1) Tafel slope, oxygen production turn over frequency of 1.44 S-1 at 300 mV, and long-term durability without significant degradation for 50 h at exceptionally high current of 115 mA cm(-1), outperforming the state-of-the-art OER SACs. A theoretical simulation further reveals that the bonding between single nickel and oxygen sites results in the extraordinary boosting of OER performance of Ni-O-G SACs. Therefore, this work opens numerous opportunities for creating unconventional SACs via metal-oxygen bonding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903089, "DOI": "10.1002/advs.201903089", "DOI Link": "http://dx.doi.org/10.1002/advs.201903089", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507977100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, YF; Qiu, Y; Cai, KF; Yao, Q; Chen, S; Chen, LD; He, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Yufei; Qiu, Yang; Cai, Kefeng; Yao, Qin; Chen, Song; Chen, Lidong; He, Jiaqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performance n-type Ag2Se film on nylon membrane for flexible thermoelectric power generator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Researches on flexible thermoelectric materials usually focus on conducting polymers and conducting polymer-based composites; however, it is a great challenge to obtain high thermoelectric properties comparable to inorganic counterparts. Here, we report an n-type Ag2Se film on flexible nylon membrane with an ultrahigh power factor similar to 987.4 +/- 104.1 mu Wm(-1)K(-2) at 300 K and an excellent flexibility (93% of the original electrical conductivity retention after 1000 bending cycles around a 8-mm diameter rod). The flexibility is attributed to a synergetic effect of the nylon membrane and the Ag2Se film intertwined with numerous highaspect- ratio Ag2Se grains. A thermoelectric prototype composed of 4-leg of the Ag2Se film generates a voltage and a maximum power of 18 mV and 460 nW, respectively, at a temperature difference of 30 K. This work opens opportunities of searching for high performance thermoelectric film for flexible thermoelectric devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 841, "DOI": "10.1038/s41467-019-08835-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08835-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459056000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alezi, D; Belmabkhout, Y; Suyetin, M; Bhatt, PM; Weselinski, LJ; Solovyeva, V; Adil, K; Spanopoulos, I; Trikalitis, PN; Emwas, AH; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alezi, Dalal; Belmabkhout, Youssef; Suyetin, Mikhail; Bhatt, Prashant M.; Weselinski, Lukasz J.; Solovyeva, Vera; Adil, Karim; Spanopoulos, Ioannis; Trikalitis, Pantelis N.; Emwas, Abdul-Hamid; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The molecular building block approach was employed effectively to construct a series of novel isoreticular, highly porous and stable, aluminum-based metal organic frameworks with soc topology. From this platform, three compounds were experimentally isolated and fully characterized: namely, the parent Al-soc-MOF-1 and its naphthalene and anthracene analogues. Al-soc-MOF-1 exhibits outstanding gravimetric methane uptake (total and working capacity). It is shown experimentally, for the first time, that the Al-soc-MOP platform can address the challenging Department of Energy dual target of 0.5 g/g (gravimetric) and 264 cm(3) (STP)/cm(3) (volumetric) methane storage. Furthermore, Al-soc-MOF exhibited the highest total gravimetric and volumetric uptake for carbon dioxide and the utmost total and deliverable uptake for oxygen at relatively high pressures among all microporous MOFs. In order to correlate the MOP pore structure and functionality to the gas storage properties, to better understand the structure property relationship, we performed a molecular simulation study and evaluated the methane storage performance of the Al-soc-MOP platform using diverse organic linkers. It was found that shortening the parent Al-soc-MOP-1 linker resulted in a noticeable enhancement in the working volumetric capacity at specific temperatures and pressures with amply conserved gravimetric uptake/working capacity. In contrast, further expansion of the organic linker (branches and/or core) led to isostructural Al-soc-MOFs with enhanced gravimetric uptake but noticeably lower volumetric capacity. The collective experimental and simulation studies indicated that the parent Al-soc-MOP-1 exhibits the best compromise between the volumetric and gravimetric total and working uptakes under a wide range of pressure and temperature conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 707, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2015, "Volume": 137, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13308, "End Page": 13318, "Article Number": null, "DOI": "10.1021/jacs.5b07053", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b07053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363438600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JC; Wang, N; Yu, Y; Yan, Y; Zhang, HY; Li, JY; Yu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jiancong; Wang, Ning; Yu, Yue; Yan, Yan; Zhang, Hongyue; Li, Jiyang; Yu, Jihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon dots in zeolites: A new class of thermally activated delayed fluorescence materials with ultralong lifetimes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermally activated delayed fluorescence (TADF) materials are inspiring intensive research in optoelectronic applications. To date, most of the TADF materials are limited to metal-organic complexes and organic molecules with lifetimes of several microseconds/milliseconds that are sensitive to oxygen. We report a facial and general dots-in-zeolites strategy to in situ confine carbon dots (CDs) in zeolitic matrices during hydrothermal/solvothermal crystallization to generate high-efficient TADF materials with ultralong lifetimes. The resultant CDs@zeolite composites exhibit high quantum yields up to 52.14% and ultralong lifetimes up to 350 ms at ambient temperature and atmosphere. This intriguing TADF phenomenon is due to the fact that nulloconfined space of zeolites can efficiently stabilize the triplet states of CDs, thus enabling the reverse intersystem crossing process for TADF. Meanwhile, zeolite frameworks can also hinder oxygen quenching to present TADF behavior at air atmosphere. This design concept introduces a new perspective to develop materials with unique TADF performance and various novel delayed fluorescence-based applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1603171", "DOI": "10.1126/sciadv.1603171", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603171", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419752300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Xu, MJ; Wen, JY; Wan, Y; Zhao, QF; Cao, X; Ding, Y; Wang, ZL; Li, HX; Bian, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yao; Xu, Mengjiao; Wen, Jieya; Wan, Yu; Zhao, Qingfei; Cao, Xia; Ding, Yong; Wang, Zhong Lin; Li, Hexing; Bian, Zhenfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective recovery of precious metals through photocatalysis", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recovering precious resources from waste is essential to implement a circular economy, but the available methods carry environmental costs. In this Article, a greener photocatalytic process is shown to recover up to seven precious metals from waste successfully, offering the potential for wide application. Precious metals such as gold and platinum are valued materials for a variety of important applications, but their scarcity poses a risk of supply disruption. Recycling precious metals from waste provides a promising solution; however, conventional metallurgical methods bear high environmental costs and energy consumption. Here, we report a photocatalytic process that enables one to selectively retrieve seven precious metals-silver (Ag), gold (Au), palladium (Pd), platinum (Pt), rhodium (Rh), ruthenium (Ru) and iridium (Ir)-from waste circuit boards, ternary automotive catalysts and ores. The whole process does not involve strong acids or bases or toxic cyanide, but needs only light and photocatalysts such as titanium dioxide (TiO2). More than 99% of the targeted elements in the waste sources can be dissolved and the precious metals recovered after a simple reducing reaction that shows a high purity (>= 98%). By demonstrating success at the kilogram scale and showing that the catalysts can be reused more than 100 times, we suggest that this approach might be industry compatible. This research opens up a new path in the development of sustainable technologies for recycling the Earth's resources and contributing to a circular economy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 618, "End Page": 626, "Article Number": null, "DOI": "10.1038/s41893-021-00697-4", "DOI Link": "http://dx.doi.org/10.1038/s41893-021-00697-4", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632771900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bérardan, D; Franger, S; Meena, AK; Dragoe, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Berardan, D.; Franger, S.; Meena, A. K.; Dragoe, N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature lithium superionic conductivity in high entropy oxides", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Impedance spectroscopy measurements evidence superionic Li+ mobility (>10(-3) S cm(-1)) at room temperature and fast ionic mobility for Na+ (5 x 10(-6) S cm(-1)) in high entropy oxides, a new family of oxide-based materials with the general formula (MgCoNiCuZn)(1-x-y)Ga(y)A(x)O (with A = Li, Na, K). Structural investigations indicate that the conduction path probably involves oxygen vacancies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 556, "Times Cited, All Databases": 599, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 4, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9536, "End Page": 9541, "Article Number": null, "DOI": "10.1039/c6ta03249d", "DOI Link": "http://dx.doi.org/10.1039/c6ta03249d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378946700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lou, ZC; Wang, QY; Kara, U; Mamtani, RS; Zhou, XD; Bian, HY; Yang, ZH; Li, YJ; Lv, HL; Adera, S; Wang, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lou, Zhichao; Wang, Qiuyi; Kara, Ufuoma, I; Mamtani, Rajdeep S.; Zhou, Xiaodi; Bian, Huiyang; Yang, Zhihong; Li, Yanjun; Lv, Hualiang; Adera, Solomon; Wang, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-Derived Carbon Heterostructures Enable Environmentally Adaptive Wideband Electromagnetic Wave Absorbers", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although advances in wireless technologies such as miniature and wearable electronics have improved the quality of our lives, the ubiquitous use of electronics comes at the expense of increased exposure to electromagnetic (EM) radiation. Up to date, extensive efforts have been made to develop high-performance EM absorbers based on synthetic materials. However, the design of an EM absorber with both exceptional EM dissipation ability and good environmental adaptability remains a substantial challenge. Here, we report the design of a class of carbon heterostructures via hierarchical assembly of graphitized lignocellulose derived from bamboo. Specifically, the assemblies of nullofibers and nullosheets behave as a nullometer-sized antenna, which results in an enhancement of the conductive loss. In addition, we show that the composition of cellulose and lignin in the precursor significantly influences the shape of the assembly and the formation of covalent bonds, which affect the dielectric response-ability and the surface hydrophobicity (the apparent contact angle of water can reach 135 degrees). Finally, we demonstrate that the obtained carbon heterostructure maintains its wideband EM absorption with an effective absorption frequency ranging from 12.5 to 16.7 GHz under conditions that simulate the real-world environment, including exposure to rainwater with slightly acidic/alkaline pH values. Overall, the advances reported in this work provide new design principles for the synthesis of high-performance EM absorbers that can find practical applications in real-world environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11, "DOI": "10.1007/s40820-021-00750-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00750-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000726284100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yong, ZJ; Guo, SQ; Ma, JP; Zhang, JY; Li, ZY; Chen, YM; Zhang, BB; Zhou, Y; Shu, J; Gu, JL; Zheng, LR; Bakr, OM; Sun, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yong, Zi-Jun; Guo, Shao-Qang; Ma, Ju-Ping; Zhang, Jun-Ying; Li, Zhi-Yong; Chen, Ya-Meng; Zhang, Bin-Bin; Zhou, Yang; Shu, Jie; Gu, Jia-Li; Zheng, Li-Rong; Bakr, Osman M.; Sun, Hong-Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping-Enhanced Short-Range Order of Perovskite nullocrystals for Near-Unity Violet Luminescence Quantum Yield", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic perovskite nullocrystals (NCs) have emerged as a new generation of low-cost semiconducting luminescent system for optoelectronic applications. The room-temperature photoluminescence quantum yields (PLQYs) of these NCs in the green and red spectral range approach unity. However, their PLQYs in the violet are much lower, and an insightful understanding of such poor performance remains missing. We report a general strategy for the synthesis of all inorganic violet-emitting perovskite NCs with near-unity PLQYs through engineering local order of the lattice by nickel ion doping. A broad range of experimental characterizations, including steady-state and time-resolved luminescence spectroscopy, X-ray absorption spectra, and magic angle spinning nuclear magnetic resonullce spectra, reveal that the low PLQY in undoped NCs is associated with short-range disorder of the lattice induced by intrinsic defects such as halide vacancies and that Ni doping can substantially eliminate these defects and result in increased short-range order of the lattice. Density functional theory calculations reveal that Ni doping of perovskites causes an increase of defect formation energy and does not introduce deep trap states in the band gap, which is suggested to be the main reason for the improved local structural order and near-unity PLQY. Our ability to obtain violet-emitting perovskite NCs with near-perfect properties opens the door for a range of applications in violet-emitting perovskite-based devices such as light-emitting diodes, single-photon sources, lasers, and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 583, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2018, "Volume": 140, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9942, "End Page": 9951, "Article Number": null, "DOI": "10.1021/jacs.8b04763", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b04763", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441475800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, HL; Zhu, YB; Mao, LB; Wang, FC; Luo, XS; Liu, YY; Lu, Y; Pan, Z; Ge, J; Shen, W; Zheng, YR; Xu, L; Wang, LJ; Xu, WH; Wu, HA; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Huai-Ling; Zhu, Yin-Bo; Mao, Li-Bo; Wang, Feng-Chao; Luo, Xi-Sheng; Liu, Yang-Yi; Lu, Yang; Pan, Zhao; Ge, Jin; Shen, Wei; Zheng, Ya-Rong; Xu, Liang; Wang, Lin-Jun; Xu, Wei-Hong; Wu, Heng-An; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-density compressible materials enable various applications but are often hindered by structure-derived fatigue failure, weak elasticity with slow recovery speed and large energy dissipation. Here we demonstrate a carbon material with microstructure-derived superelasticity and high fatigue resistance achieved by designing a hierarchical lamellar architecture composed of thousands of microscale arches that serve as elastic units. The obtained monolithic carbon material can rebound a steel ball in spring-like fashion with fast recovery speed (similar to 580 mm s(-1)), and demonstrates complete recovery and small energy dissipation (similar to 0.2) in each compress-release cycle, even under 90% strain. Particularly, the material can maintain structural integrity after more than 106 cycles at 20% strain and 2.5 x 10(5) cycles at 50% strain. This structural material, although constructed using an intrinsically brittle carbon constituent, is simultaneously super-elastic, highly compressible and fatigue resistant to a degree even greater than that of previously reported compressible foams mainly made from more robust constituents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12920, "DOI": "10.1038/ncomms12920", "DOI Link": "http://dx.doi.org/10.1038/ncomms12920", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385386800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moreno, C; Vilas-Varela, M; Kretz, B; Garcia-Lekue, A; Costache, MV; Paradinas, M; Panighel, M; Ceballos, G; Valenzuela, SO; Peña, D; Mugarza, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moreno, Cesar; Vilas-Varela, Manuel; Kretz, Bernhard; Garcia-Lekue, Aran; Costache, Marius V.; Paradinas, Markos; Panighel, Mirko; Ceballos, Gustavo; Valenzuela, Sergio O.; Pena, Diego; Mugarza, Aitor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bottom-up synthesis of multifunctional nulloporous graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullosize pores can turn semimetallic graphene into a semiconductor and, from being impermeable, into the most efficient molecular-sieve membrane. However, scaling the pores down to the nullometer, while fulfilling the tight structural constraints imposed by applications, represents an enormous challenge for present top-down strategies. Here we report a bottom-up method to synthesize nulloporous graphene comprising an ordered array of pores separated by ribbons, which can be tuned down to the 1-nullometer range. The size, density, morphology, and chemical composition of the pores are defined with atomic precision by the design of the molecular precursors. Our electronic characterization further reveals a highly anisotropic electronic structure, where orthogonal one-dimensional electronic bands with an energy gap of similar to 1 electron volt coexist with confined pore states, making the nulloporous graphene a highly versatile semiconductor for simultaneous sieving and electrical sensing of molecular species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2018, "Volume": 360, "Issue": 6385, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 199, "End Page": 203, "Article Number": null, "DOI": "10.1126/science.aar2009", "DOI Link": "http://dx.doi.org/10.1126/science.aar2009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429805400045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZZ; Zhou, P; Pan, W; Li, N; Tang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhengze; Zhou, Ping; Pan, Wei; Li, Na; Tang, Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A biomimetic nulloreactor for synergistic chemiexcited photodynamic therapy and starvation therapy against tumor metastasis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photodynamic therapy (PDT) is ineffective against deeply seated metastatic tumors due to poor penetration of the excitation light. Herein, we developed a biomimetic nulloreactor (bio-NR) to achieve synergistic chemiexcited photodynamic-starvation therapy against tumor metastasis. Photosensitizers on the hollow mesoporous silica nulloparticles (HMSNs) are excited by chemical energy in situ of the deep metastatic tumor to generate singlet oxygen (O-1(2)) for PDT, and glucose oxidase (GOx) catalyzes glucose into hydrogen peroxide (H2O2). Remarkably, this process not only blocks the nutrient supply for starvation therapy but also provides H2O2 to synergistically enhance PDT. Cancer cell membrane coating endows the nulloparticle with biological properties of homologous adhesion and immune escape. Thus, bio-NRs can effectively convert the glucose into O-1(2) in metastatic tumors. The excellent therapeutic effects of bio-NRs in vitro and in vivo indicate their great potential for cancer metastasis therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5044, "DOI": "10.1038/s41467-018-07197-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07197-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451433800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Strmcnik, D; Lopes, PP; Genorio, B; Stamenkovic, VR; Markovic, NM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Strmcnik, Dusan; Lopes, Pietro Papa; Genorio, Bostjan; Stamenkovic, Vojislav R.; Markovic, Nenad M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design principles for hydrogen evolution reaction catalyst materials", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design and synthesis of active, stable and cost-effective materials for efficient hydrogen production (hydrogen evolution reaction, HER) is of paramount importance for the successful deployment of hydrogen -based alternative energy technologies. The HER, seemingly one of the simplest electrochemical reactions, has served for decades to bridge the gap between fundamental electrocatalysis and practical catalyst design. However, there are still many open questions that need to be answered before it would be possible to claim that design principles of catalyst materials are fully developed for the efficient hydrogen production. In this review, by summarizing key results for the HER on well-characterized electrochemical interfaces in acidic and alkaline media, we have broadened our understanding of the HER in the whole range of pH by considering three main parameters: the nature of the proton donor (H3O+ in acid and H2O in alkaline), the energy of adsorption of H-ad and OHad, and the presence of spectator species. Simply by considering these three parameters we show that great deal has already been learned and new trends are beginning to emerge, giving some predictive ability with respect to the nature of electrochemical interface and electrocatalytic activity of the HER. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 723, "Times Cited, All Databases": 751, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 29, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 29, "End Page": 36, "Article Number": null, "DOI": "10.1016/j.nulloen.2016.04.017", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2016.04.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389624100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GX; Jia, Y; Zhang, C; Xiong, XY; Sun, K; Chen, RD; Chen, WX; Kuang, Y; Zheng, LR; Tang, HL; Liu, W; Liu, JF; Sun, XM; Lin, WF; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guoxin; Jia, Yin; Zhang, Cong; Xiong, Xuya; Sun, Kai; Chen, Ruida; Chen, Wenxing; Kuang, Yun; Zheng, Lirong; Tang, Haolin; Liu, Wen; Liu, Junfeng; Sun, Xiaoming; Lin, Wen-Feng; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general route via formamide condensation to prepare atomically dispersed metal-nitrogen-carbon electrocatalysts for energy technologies", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom electrocatalysts (SAECs) have gained tremendous attention due to their unique active sites and strong metal-substrate interactions. However, the current synthesis of SAECs mostly relies on costly precursors and rigid synthetic conditions and often results in very low content of single-site metal atoms. Herein, we report an efficient synthesis method to prepare metal-nitrogen-carbon SAECs based on formamide condensation and carbonization, featuring a cost-effective general methodology for the mass production of SAECs with high loading of atomically dispersed metal sites. The products with metal inclusion were termed as formamide-converted metal-nitrogen-carbon (shortened as f-MNC) materials. Seven types of single-metallic f-MNC (Fe, Co, Ni, Mn, Zn, Mo and Ir), two bi-metallic (ZnFe and ZnCo) and one tri-metallic (ZnFeCo) SAECs were synthesized to demonstrate the generality of the methodology developed. Remarkably, these f-MNC SAECs can be coated onto various supports with an ultrathin layer as pyrolysis-free electrocatalysts, among which the carbon nullotube-supported f-FeNC and f-NiNC SAECs showed high performance for the O-2 reduction reaction (ORR) and the CO2 reduction reaction (CO2RR), respectively. Furthermore, the pyrolysis products of supported f-MNC can still render isolated metallic sites with excellent activity, as exemplified by the bi-metallic f-FeCoNC SAEC, which exhibited outstanding ORR performance in both alkaline and acid electrolytes by delivering approximate to 70 and approximate to 20 mV higher half-wave potentials than that of commercial 20 wt% Pt/C, respectively. This work offers a feasible approach to design and manufacture SAECs with tuneable atomic metal components and high density of single-site metal loading, and thus may accelerate the deployment of SAECs for various energy technology applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2019, "Volume": 12, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1317, "End Page": 1325, "Article Number": null, "DOI": "10.1039/c9ee00162j", "DOI Link": "http://dx.doi.org/10.1039/c9ee00162j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465275800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giordano, F; Abate, A; Baena, JPC; Saliba, M; Matsui, T; Im, SH; Zakeeruddin, SM; Nazeeruddin, MK; Hagfeldt, A; Graetzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giordano, Fabrizio; Abate, Antonio; Baena, Juan Pablo Correa; Saliba, Michael; Matsui, Taisuke; Im, Sang Hyuk; Zakeeruddin, Shaik M.; Nazeeruddin, Mohammad Khaja; Hagfeldt, Anders; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced electronic properties in mesoporous TiO2 via lithium doping for high-efficiency perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells are one of the most promising photovoltaic technologies with their extraordinary progress in efficiency and the simple processes required to produce them. However, the frequent presence of a pronounced hysteresis in the current voltage characteristic of these devices arises concerns on the intrinsic stability of organo-metal halides, challenging the reliability of technology itself. Here, we show that n-doping of mesoporous TiO2 is accomplished by facile post treatment of the films with lithium salts. We demonstrate that the Li-doped TiO2 electrodes exhibit superior electronic properties, by reducing electronic trap states enabling faster electron transport. Perovskite solar cells prepared using the Li-doped films as scaffold to host the CH3NH3PbI3 light harvester produce substantially higher performances compared with undoped electrodes, improving the power conversion efficiency from 17 to over 19% with negligible hysteretic behaviour (lower than 0.3%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 796, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10379, "DOI": "10.1038/ncomms10379", "DOI Link": "http://dx.doi.org/10.1038/ncomms10379", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369022100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, N; Sun, QM; Zhang, TJ; Mayoral, A; Li, L; Zhou, X; Xu, J; Zhang, P; Yu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ning; Sun, Qiming; Zhang, Tianjun; Mayoral, Alvaro; Li, Lin; Zhou, Xue; Xu, Jun; Zhang, Peng; Yu, Jihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impregnating Subnullometer Metallic nullocatalysts into Self-Pillared Zeolite nullosheets", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Impregnation is the most commonly used approach to prepare supported metal catalysts in industry. However, this method suffers from the formation of large metal particles with uneven dispersion, poor thermal stability, and thus unsatisfied catalytic performance. Here, we demonstrate that the self-pillared MFI zeolite (silicalite-1 and ZSM-5) nullosheets with larger surface area and abundant Si-OH groups are ideal supports to immobilize ultrasmall monometallic (e.g., Rh and Ru) and various bimetallic clusters via simple incipient wetness impregnation method. The loaded subnullometric metal clusters are uniformly dispersed within sinusoidal five-membered rings of MFI and remain stable at high temperatures. The Rh/SP-S-1 is highly efficient in ammonia borane (AB) hydrolysis, showing a TOF value of 430 mol(H2) mol(Rh)(-1) min(-1) at 298 K, which is more than 6-fold improvement over that of nullosized zeolite-supported Rh catalyst and even comparable with that of zeolite-supported Rh single-atom catalyst. Because of the synergistic effect between bimetallic Rh-Ru clusters and zeolite acidity, the H-2 generation rate from AB hydrolysis over Rh0.8Ru0.2/SP-ZSM-5-100 reaches up to 1006 mol(H2) mol(metal)(-1) min(-1) at 298 K, and also shows record activities in cascade hydrogenation of various nitroarenes by coupling with the hydrolysis of AB. This work demonstrates that zeolite nullosheets are excellent supports to anchor diverse ultrasmall metallic species via the simple impregnation method, and the obtained nullocatalysts can be applied in various industrially important catalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2021, "Volume": 143, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6905, "End Page": 6914, "Article Number": null, "DOI": "10.1021/jacs.1c00578", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c00578", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000651748000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, QF; Wang, Y; Hu, Q; Zhou, JG; Feng, RF; Duchesne, PN; Zhang, P; Chen, FJ; Han, N; Li, YF; Jin, CH; Li, YG; Lee, ST", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Qiufang; Wang, Yu; Hu, Qi; Zhou, Jigang; Feng, Renfei; Duchesne, Paul N.; Zhang, Peng; Chen, Fengjiao; Han, Na; Li, Yafei; Jin, Chuanhong; Li, Yanguang; Lee, Shuit-Tong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasmall and phase-pure W2C nulloparticles for efficient electrocatalytic and photoelectrochemical hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earlier research has been primarily focused on WC as one of the most promising earth-abundant electrocatalysts for hydrogen evolution reaction (HER), whereas the other compound in this carbide family-W2C-has received far less attention. Our theoretical calculations suggest that such a focus is misplaced and W2C is potentially more HER-active than WC. Nevertheless, the preparation of phase pure and sintering-free W2C nullostructures represents a formidable challenge. Here we develop an improved carburization method and successfully prepare ultrasmall and phase-pure W2C nulloparticles. When evaluated for HER electrocatalysis, W2C nulloparticles exhibit a small onset overpotential of 50 mV, a Tafel slope of 45 mV dec(-1) and outstanding long-term cycling stability, which are dramatically improved over all existing WC-based materials. In addition, the integration of W2C nulloparticles with p-type Si nullowires enables highly active and sustainable solar-driven hydrogen production. Our results highlight the great potential of this traditionally non-popular material in HER electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13216, "DOI": "10.1038/ncomms13216", "DOI Link": "http://dx.doi.org/10.1038/ncomms13216", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385538400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moliner, M; Gabay, JE; Kliewer, CE; Carr, RT; Guzman, J; Casty, GL; Serna, P; Corma, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moliner, Manuel; Gabay, Jadeene E.; Kliewer, Chris E.; Carr, Robert T.; Guzman, Javier; Casty, Gary L.; Serna, Pedro; Corma, Avelino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible Transformation of Pt nulloparticles into Single Atoms inside High-Silica Chabazite Zeolite", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the encapsulation of platinum species in highly siliceous chabazite (CHA) crystallized in the presence of N,N,N-trimethyl-1-adamantammonium and a thiol-stabilized Pt complex. When compared to Pt/SiO2 or Pt-containing Al-rich zeolites, the materials in this work show enhanced stability toward metal sintering in a variety of industrial conditions, including H-2, O-2, and H2O. Remarkably, temperatures in the range 650-750 degrees C can be reached without significant sintering of the noble metal. Detailed structural determinations by X-ray absorption spectroscopy and aberration-corrected high-angle annular dark-field scanning transmission electron microscopy demonstrate subtle control of the supported metal structures from similar to 1 nm nulloparticles to site-isolated single Pt atoms via reversible interconversion of one species into another in reducing and oxidizing atmospheres. The combined used of microscopy and spectroscopy is critical to understand these surface-mediated transformations. When tested in hydrogenation reactions, Pt/CHA converts ethylene (similar to 80%) but not propylene under identical conditions, in contrast to Pt/SiO2, which converts both at similar rates. These differences are attributed to the negligible diffusivity of propylene through the small-pore zeolite and provide final evidence of the metal encapsulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2016, "Volume": 138, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15743, "End Page": 15750, "Article Number": null, "DOI": "10.1021/jacs.6b10169", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b10169", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389623800035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, C; Lindgren, F; Philippe, B; Gorgoi, M; Björefors, F; Edström, K; Gustafsson, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Chao; Lindgren, Fredrik; Philippe, Bertrand; Gorgoi, Mihaela; Bjorefors, Fredrik; Edstrom, Kristina; Gustafsson, Torbjorn", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon as a negative electrode material for lithium-ion batteries has attracted tremendous attention due to its high theoretical capacity, and fluoroethylene carbonate (FEC) was used as an electrolyte additive, which significantly improved the cyclability of silicon-based electrodes in this study. The decomposition of the FEC additive was investigated by synchrotron-based X-ray photoelectron spectroscopy (PES) giving a chemical composition depth-profile. The reduction products of FEC were found to mainly consist of LiF and -CHF-OCO2-type compounds. Moreover, FEC influenced the lithium hexafluorophosphate (LiPF6) decomposition reaction and may have suppressed further salt degradation. The solid electrolyte interphase (SEI) formed from the decomposition of ethylene carbonate (EC) and diethyl carbonate (DEC), without the FEC additive present, covered surface voids and lead to an increase in polarization. However, in the presence of FEC, which degrades at a higher reduction potential than EC and DEC, instantaneously a conformal SEI was formed on the silicon electrode. This stable SEI layer sufficiently limited the emergence of large cracks and preserved the original surface morphology as well as suppressed the additional SEI formation from the other solvent. This study highlights the vital importance of how the chemical composition and morphology of the SEI influence battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 600, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2015, "Volume": 27, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2591, "End Page": 2599, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b00339", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b00339", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353176100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, Y; Zhang, LZ; Zhuang, LZ; Liu, HL; Yan, XC; Wang, X; Liu, JD; Wang, JC; Zheng, YR; Xiao, ZH; Taran, E; Chen, J; Yang, DJ; Zhu, ZH; Wang, SY; Dai, LM; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Yi; Zhang, Longzhou; Zhuang, Linzhou; Liu, Hongli; Yan, Xuecheng; Wang, Xin; Liu, Jiandang; Wang, Jiancheng; Zheng, Yarong; Xiao, Zhaohui; Taran, Elena; Chen, Jun; Yang, Dongjiang; Zhu, Zhonghua; Wang, Shuangyin; Dai, Liming; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of active sites for acidic oxygen reduction on carbon catalysts with and without nitrogen doping", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the difficulty in controlling the dopant or defect types and their homogeneity in carbon materials, it is still a controversial issue to identify the active sites of carbon-based metal-free catalysts. Here we report a proof-of-concept study on the active-site evaluation for a highly oriented pyrolytic graphite catalyst with specific pentagon carbon defective patterns (D-HOPG). It is demonstrated that specific carbon defect types (an edged pentagon in this work) could be selectively created via controllable nitrogen doping. Work-function analyses coupled with macro and micro-electrochemical performance measurements suggest that the pentagon defects in D-HOPG served as major active sites for the acidic oxygen reduction reaction, even much superior to the pyridinic nitrogen sites in nitrogen-doped highly oriented pyrolytic graphite. This work enables us to elucidate the relative importance of the specific carbon defects versus nitrogen-dopant species and their respective contributions to the observed overall acidic oxygen reduction reaction activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 688, "End Page": 695, "Article Number": null, "DOI": "10.1038/s41929-019-0297-4", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0297-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481511400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JSM; Briggs, ME; Hu, CC; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jet-Sing M.; Briggs, Michael E.; Hu, Chi-Chang; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling electric double-layer capacitance and pseudocapacitance in heteroatom-doped carbons derived from hypercrosslinked microporous polymers", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hypercrosslinked polymers (HCPs) are an important class of porous materials that can be synthesized from aromatic precursors using a one-step knitting procedure. This scalable process allows wide synthetic diversity and ease of functionalization. However, pristine HCPs lack electrical conductivity, which limits their potential for electrochemical applications. Supercapacitors are energy storage devices with advantages over conventional batteries such as high power densities, rapid charge speeds, and superior cyclability. In this work, carbonization of functionalized HCPs yields highly conductive and porous materials that can be used as supercapacitor electrodes. Both electric double-layer capacitance (EDLC) and pseudocapacitance (PC) mechanisms are observed. The relative EDLC and PC contributions were quantified for a range of 20 HCP-derived materials, thus allowing a controlled approach to tuning the energy storage properties. The HCP-based carbons show ideal supercapacitor behavior and the best performing material, which shows 63% PC, displays exceptionally high capacitances of up to 374 F g(-1), excellent capacitance retention at fast charging speeds, and stability for up to 15,000 charge/discharge cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 277, "End Page": 289, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.01.042", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.01.042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427924000033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, DY; Li, CX; Feng, T; Zhang, YD; Sha, G; Lewandowski, JJ; Liaw, PK; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dongyue; Li, Chengxin; Feng, Tao; Zhang, Yidong; Sha, Gang; Lewandowski, John J.; Liaw, Peter K.; Zhang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy Al0.3CoCrFeNi alloy fibers with high tensile strength and ductility at ambient and cryogenic temperatures", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) are multi-component systems based on novel alloy composition designs with entropy maximization. They feature an array of unique mechanical properties when compared with traditional alloys. In this study, HEA fibers with diameters ranging from 1 to 3.15 mm in diameter, with the composition of Al0.3CoCrFeNi (atomic percent, at.%), were successfully fabricated by hot-drawing, followed by microstructural characterization using scanning-electron microscopy (SEM) and transmission-electron microscopy (TEM). The compositional variations within and between fibers were determined using energy-dispersive X-ray spectroscopy in TEM along with atomic-probe tomography (APT). These analyses revealed a homogeneous face-centered cubic (FCC) structure in the as-cast material, while post processing (e.g., forging and wire drawing) produced nullosized B2 particles in an FCC matrix. Electron back-scatter diffraction (EBSD) was used to determine the evolution of the texture and grain boundary character after processing of the fibers. The tensile strength and plasticity of the fibers were determined at both 298 K (1207 MPa/7.8%) and 77 K (1600 MPa/17.5%). Detailed TEM analyses revealed that the improvement of mechanical properties at 77 K (i.e. increased strength and ductility) is due to a change in deformation mechanisms from the planar slip of dislocations to nullo-twinning. Such properties could be beneficial for cryogenic applications. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2017, "Volume": 123, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 285, "End Page": 294, "Article Number": null, "DOI": "10.1016/j.actamat.2016.10.038", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.10.038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389556500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Buscema, M; Groenendijk, DJ; Steele, GA; van der Zant, HSJ; Castellanos-Gomez, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Buscema, Michele; Groenendijk, Dirk J.; Steele, Gary A.; van der Zant, Herre S. J.; Castellanos-Gomez, Andres", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photovoltaic effect in few-layer black phosphorus PN junctions defined by local electrostatic gating", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In conventional photovoltaic solar cells, photogenerated carriers are extracted by the built-in electric field of a semiconductor PN junction, defined by ionic dopants. In atomically thin semiconductors, the doping level can be controlled by the field effect, enabling the implementation of electrically tunable PN junctions. However, most two-dimensional (2D) semiconductors do not show ambipolar transport, which is necessary to realize PN junctions. Few-layer black phosphorus (b-P) is a recently isolated 2D semiconductor with direct bandgap, high mobility, large current on/off ratios and ambipolar operation. Here we fabricate few-layer b-P field-effect transistors with split gates and hexagonal boron nitride dielectric. We demonstrate electrostatic control of the local charge carrier type and density in the device. Illuminating a gate-defined PN junction, we observe zero-bias photocurrents and significant open-circuit voltages due to the photovoltaic effect. The small bandgap of the material allows power generation for illumination wavelengths up to 940 nm, attractive for energy harvesting in the near-infrared.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 682, "Times Cited, All Databases": 744, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4651, "DOI": "10.1038/ncomms5651", "DOI Link": "http://dx.doi.org/10.1038/ncomms5651", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341057500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, Z; Tai, CW; Niklasson, GA; Edvinsson, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Zhen; Tai, Cheuk-Wai; Niklasson, Gunnar A.; Edvinsson, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of active catalyst surface phases and the effect of dynamic self-optimization in NiFe-layered double hydroxides for alkaline water splitting", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earth-abundant transition metal-based compounds are of high interest as catalysts for sustainable hydrogen fuel generation. The realization of effective electrolysis of water, however, is still limited by the requirement of a high sustainable driving potential above thermodynamic requirements. Here, we report dynamically self-optimized (DSO) NiFe layered double hydroxide (LDH) nullosheets with promising bi-functional performance. Compared with pristine NiFe LDH, DSO NiFe LDH exhibits much lower overpotential for the hydrogen evolution reaction (HER), even outperforming platinum. Under 1 M KOH aqueous electrolyte, the bi-functional DSO catalysts show an overpotential of 184 and -59 mV without iR compensation for oxygen evolution reaction (OER) and HER at 10 mA cm(-2). The material system operates at 1.48 V and 1.29 V to reach 10 and 1 mA cm(-2) in two-electrode measurements, corresponding to 83% and 95% electricity-to-fuel conversion efficiency with respect to the lower heating value of hydrogen. The material is seen to dynamically reform the active phase of the surface layer during HER and OER, where the pristine and activated catalysts are analyzed with ex situ XPS, SAED and EELS as well as with in situ Raman spectro-electrochemistry. The results show transformation into different active interfacial species during OER and HER, revealing a synergistic interplay between iron and nickel in facilitating water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 572, "End Page": 581, "Article Number": null, "DOI": "10.1039/c8ee03282c", "DOI Link": "http://dx.doi.org/10.1039/c8ee03282c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459741700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LL; Wei, ZY; Wan, CZ; Li, J; Chen, Z; Zhu, D; Baumann, D; Liu, HT; Allen, CS; Xu, X; Kirkland, AI; Shakir, I; Almutairi, Z; Tolbert, S; Dunn, B; Huang, Y; Sautet, P; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lele; Wei, Ziyang; Wan, Chengzhang; Li, Jing; Chen, Zhuo; Zhu, Dan; Baumann, Daniel; Liu, Haotian; Allen, Christopher S.; Xu, Xiang; Kirkland, Angus I.; Shakir, Imran; Almutairi, Zeyad; Tolbert, Sarah; Dunn, Bruce; Huang, Yu; Sautet, Philippe; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fundamental look at electrocatalytic sulfur reduction reaction", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fundamental kinetics of the electrocatalytic sulfur reduction reaction (SRR), a complex 16-electron conversion process in lithium-sulfur batteries, is so far insufficiently explored. Here, by directly profiling the activation energies in the multistep SRR, we reveal that the initial reduction of sulfur to the soluble polysulfides is relatively easy owing to the low activation energy, whereas the subsequent conversion of the polysulfides into the insoluble Li2S2/Li2S has a much higher activation energy, contributing to the accumulation of polysulfides and exacerbating the polysulfide shuttling effect. We use heteroatom-doped graphene as a model system to explore electrocatalytic SRR. We show that nitrogen and sulfur dual-doped graphene considerably reduces the activation energy to improve SRR kinetics. Density functional calculations confirm that the doping tunes the p-band centre of the active carbons for an optimal adsorption strength of intermediates and electroactivity. This study establishes electrocatalysis as a promising pathway to tackle the fundamental challenges facing lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 612, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 762, "End Page": 770, "Article Number": null, "DOI": "10.1038/s41929-020-0498-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0498-x", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564491500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, ZW; Dong, RJ; Evans, AM; Biere, N; Ebrahim, MA; Li, SY; Anselmetti, D; Dichtel, WR; Livingston, AG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Zhiwei; Dong, Ruijiao; Evans, Austin M.; Biere, Niklas; Ebrahim, Mahmood A.; Li, Siyao; Anselmetti, Dario; Dichtel, William R.; Livingston, Andrew G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aligned macrocycle pores in ultrathin films for accurate molecular sieving", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer membranes are widely used in separation processes including desalination(1), organic solvent nullofiltration(2,3) and crude oil fractionation(4,5). Nevertheless, direct evidence of subnullometre pores and a feasible method of manipulating their size is still challenging because of the molecular fluctuations of poorly defined voids in polymers(6). Macrocycles with intrinsic cavities could potentially tackle this challenge. However, unfunctionalized macrocycles with indistinguishable reactivities tend towards disordered packing in films hundreds of nullometres thick(7-9), hindering cavity interconnection and formation of through-pores. Here, we synthesized selectively functionalized macrocycles with differentiated reactivities that preferentially aligned to create well-defined pores across an ultrathin nullofilm. The ordered structure was enhanced by reducing the nullofilm thickness down to several nullometres. This orientated architecture enabled direct visualization of subnullometre macrocycle pores in the nullofilm surfaces, with the size tailored to angstrom precision by varying the macrocycle identity. Aligned macrocycle membranes provided twice the methanol permeance and higher selectivity compared to disordered counterparts. Used in high-value separations, exemplified here by enriching cannabidiol oil, they achieved one order of magnitude faster ethanol transport and threefold higher enrichment than commercial state-of-the-art membranes. This approach offers a feasible strategy for creating subnullometre channels in polymer membranes, and demonstrates their potential for accurate molecular separations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2022, "Volume": 609, "Issue": 7925, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 58, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05032-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05032-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849436200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZY; Yi, YF; Song, TC; Clark, G; Huang, B; Shan, YW; Wu, S; Huang, D; Gao, CL; Chen, ZH; McGuire, M; Cao, T; Xiao, D; Liu, WT; Yao, W; Xu, XD; Wu, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zeyuan; Yi, Yangfan; Song, Tiancheng; Clark, Genevieve; Huang, Bevin; Shan, Yuwei; Wu, Shuang; Huang, Di; Gao, Chunlei; Chen, Zhanghai; McGuire, Michael; Cao, Ting; Xiao, Di; Liu, Wei-Tao; Yao, Wang; Xu, Xiaodong; Wu, Shiwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant nonreciprocal second-harmonic generation from antiferromagnetic bilayer CrI3", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered antiferromagnetism is the spatial arrangement of ferromagnetic layers with antiferromagnetic interlayer coupling. The van der Waals magnet chromium triiodide (CrI3) has been shown to be a layered antiferromagnetic insulator in its few-layer form(1), opening up opportunities for various functionalities(2-7) in electronic and optical devices. Here we report an emergent nonreciprocal second-order nonlinear optical effect in bilayer CrI3. The observed second-harmonic generation (SHG; a nonlinear optical process that converts two photons of the same frequency into one photon of twice the fundamental frequency) is several orders of magnitude larger than known magnetization-induced SHG(8-11) and comparable to the SHG of the best (in terms of nonlinear susceptibility) two-dimensional nonlinear optical materials studied so far(12,13) (for example, molybdenum disulfide). We show that although the parent lattice of bilayer CrI3 is centrosymmetric, and thus does not contribute to the SHG signal, the observed giant nonreciprocal SHG originates only from the layered antiferromagnetic order, which breaks both the spatial-inversion symmetry and the time-reversal symmetry. Furthermore, polarization-resolved measurements reveal underlying C-2h crystallographic symmetry-and thus monoclinic stacking order-in bilayer CrI3, providing key structural information for the microscopic origin of layered antiferromagnetism(14-18). Our results indicate that SHG is a highly sensitive probe of subtle magnetic orders and open up possibilities for the use of two-dimensional magnets in nonlinear and nonreciprocal optical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2019, "Volume": 572, "Issue": 7770, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 497, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1445-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1445-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482219600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YA; Cheng, YF; Wang, J; Fu, S; Zhou, MJ; Yang, Y; Li, BW; Zhang, X; null, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yanull; Cheng, Yongfa; Wang, Jian; Fu, Si; Zhou, Mengjun; Yang, Yue; Li, Baowen; Zhang, Xin; null, Ce-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and highly-sensitive pressure sensor based on controllably oxidized MXene", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive Ti3C2Tx MXenes have been widely investigated for the construction of flexible and highly-sensitive pressure sensors. Although the inevitable oxidation of solution-processed MXene has been recognized, the effect of the irreversible oxidation of MXene on its electrical conductivity and sensing properties is yet to be understood. Herein, we construct a highly-sensitive and degradable piezoresistive pressure sensor by coating Ti3C2Tx MXene flakes with different degrees of in situ oxidation onto paper substrates using the dipping-drying method. In situ oxidation can tune the intrinsic resistance and expand the interlayer distance of MXene nullosheets. The partially oxidized MXene-based piezoresistive pressure sensor exhibits a high sensitivity of 28.43 kPa(-1), which is greater than those of pristine MXene, over-oxidized MXene, and state-of-the-art paper-based pressure sensors. Additionally, these sensors exhibit a short response time of 98.3 ms, good durability over 5000 measurement cycles, and a low force detection limit of 0.8 Pa. Moreover, MXene-based sensing elements are easily degraded and environmentally friendly. The MXene-based pressure sensor shows promise for practical applications in tracking body movements, sports coaching, remote health monitoring, and human-computer interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e12328", "DOI": "10.1002/inf2.12328", "DOI Link": "http://dx.doi.org/10.1002/inf2.12328", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804479300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gosselin, C; Duballet, R; Roux, P; Gaudillière, N; Dirrenberger, J; Morel, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gosselin, C.; Duballet, R.; Roux, Ph.; Gaudilliere, N.; Dirrenberger, J.; Morel, Ph.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale 3D printing of ultra-high performance concrete - a new processing route for architects and builders", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present paper a new additive manufacturing processing route is introduced for ultra-high performance concrete. Interdisciplinary work involving materials science, computation, robotics, architecture and design resulted in the development of an innovative way of 3D printing cementitious materials. The 3D printing process involved is based on a FDM-like technique, in the sense that a material is deposited layer by layer through an extrusion printhead mounted on a 6-axis robotic arm. The mechanical properties of 3D printed materials are assessed. The proposed technology succeeds in solving many of the problems that can be found in the literature. Most notably, this process allows the production of 3D large-scale complex geometries, without the use of temporary supports, as opposed to 2.5D examples found in the literature for concrete 3D printing. Architectural cases of application are used as examples in order to demonstrate the potentialities of the technology. Two structural elements were produced and constitute some of the largest 3D printed concrete parts available until now. Multifunctionality was enabled for both structural elements by taking advantage of the complex geometry which can be achieved using our technology for large-scale additive manufacturing. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 599, "Times Cited, All Databases": 668, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2016, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 102, "End Page": 109, "Article Number": null, "DOI": "10.1016/j.matdes.2016.03.097", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2016.03.097", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375412800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, G; Chernikov, A; Glazov, MM; Heinz, TF; Marie, X; Amand, T; Urbaszek, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Gang; Chernikov, Alexey; Glazov, Mikhail M.; Heinz, Tony F.; Marie, Xavier; Amand, Thierry; Urbaszek, Bernhard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloquium: Excitons in atomically thin transition metal dichalcogenides", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin materials such as graphene and monolayer transition metal dichalcogenides (TMDs) exhibit remarkable physical properties resulting from their reduced dimensionality and crystal symmetry. The family of semiconducting transition metal dichalcogenides is an especially promising platform for fundamental studies of two-dimensional (2D) systems, with potential applications in optoelectronics and valleytronics due to their direct band gap in the monolayer limit and highly efficient light-matter coupling. A crystal lattice with broken inversion symmetry combined with strong spin-orbit interactions leads to a unique combination of the spin and valley degrees of freedom. In addition, the 2D character of the monolayers and weak dielectric screening from the environment yield a significant enhancement of the Coulomb interaction. The resulting formation of bound electron-hole pairs, or excitons, dominates the optical and spin properties of the material. Here recent progress in understanding of the excitonic properties in monolayer TMDs is reviewed and future challenges are laid out. Discussed are the consequences of the strong direct and exchange Coulomb interaction, exciton light-matter coupling, and influence of finite carrier and electron-hole pair densities on the exciton properties in TMDs. Finally, the impact on valley polarization is described and the tuning of the energies and polarization observed in applied electric and magnetic fields is summarized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1439, "Times Cited, All Databases": 1579, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2018, "Volume": 90, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21001, "DOI": "10.1103/RevModPhys.90.021001", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.021001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429123700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eom, W; Shin, H; Ambade, RB; Lee, SH; Lee, KH; Kang, DJ; Han, TH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eom, Wonsik; Shin, Hwansoo; Ambade, Rohan B.; Lee, Sang Hoon; Lee, Ki Hyun; Kang, Dong Jun; Han, Tae Hee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale wet-spinning of highly electroconductive MXene fibers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ti3C2Tx MXene is an emerging class of two-dimensional nullomaterials with exceptional electroconductivity and electrochemical properties, and is promising in the manufacturing of multifunctional macroscopic materials and nullomaterials. Herein, we develop a straightforward, continuously controlled, additive/binder-free method to fabricate pure MXene fibers via a large-scale wet-spinning assembly. Our MXene sheets (with an average lateral size of 5.11 mu m(2)) are highly concentrated in water and do not form aggregates or undergo phase separation. Introducing ammonium ions during the coagulation process successfully assembles MXene sheets into flexible, meter-long fibers with very high electrical conductivity (7,713Scm(-1)). The fabricated MXene fibers are comprehensively integrated by using them in electrical wires to switch on a light-emitting diode light and transmit electrical signals to earphones to demonstrate their application in electrical devices. Our wet-spinning strategy provides an approach for continuous mass production of MXene fibers for high-performance, next-generation, and wearable electronic devices. Large-scale production of fibers from two dimensional materials opens a pathway to promising applications. Here the authors report meter-long MXene fibers with high electrical conductivity that are fabricated via continuous wet spinning and demonstrated in electrical wires.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 4", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16671-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16671-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540513300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yasuda, K; Wang, XR; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yasuda, Kenji; Wang, Xirui; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking-engineered ferroelectricity in bilayer boron nitride", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) ferroelectrics with robust polarization down to atomic thicknesses provide building blocks for functional heterostructures. Experimental realization remains challenging because of the requirement of a layered polar crystal. Here, we demonstrate a rational design approach to engineering 2D ferroelectrics from a nonferroelectric parent compound by using van der Waals assembly. Parallel-stacked bilayer boron nitride exhibits out-of-plane electric polarization that reverses depending on the stacking order. The polarization switching is probed through the resistance of an adjacently stacked graphene sheet. Twisting the boron nitride sheets by a small angle changes the dynamics of switching because of the formation of moire ferroelectricity with staggered polarization. The ferroelectricity persists to room temperature while keeping the high mobility of graphene, paving the way for potential ultrathin nonvolatile memory applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 372, "Issue": 6549, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1458, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd3230", "DOI Link": "http://dx.doi.org/10.1126/science.abd3230", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665860000051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CM; Nie, YH; Sanvito, S; Du, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chunmei; Nie, Yihan; Sanvito, Stefano; Du, Aijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-Principles Prediction of a Room-Temperature Ferromagnetic Janus VSSe Monolayer with Piezoelectricity, Ferroelasticity, and Large Valley Polarization", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by recent experiments on the successful fabrication of monolayer Janus transition-metal dichalcogenides [Lu, A.-Y.; et al. Nat. nullotechnol. 2017, 12, (8), 744 and ferromagnetic VSe2 [Bonilla, M.; et al. Nat. nullotechnol. 2018, 13, (4), 289], we predict a highly stable room-temperature ferromagnetic Janus monolayer (VSSe) by density functional theory methods and further confirmed the stability by a global minimum search with the particle-swarm optimization method. The VSSe monolayer exhibits a large valley polarization due to the broken space- and time-reversal symmetry. Moreover, its low symmetry C-3v point group results in giant in-plane piezoelectric polarization. Most interestingly, a strain-driven 90 degrees lattice rotation is found in the magnetic VSSe monolayer with an extremely high reversal strain (73%), indicating an intrinsic ferroelasticity. The combination of piezoelectricity and valley polarization make magnetic 2D Janus VSSe a tantalizing material for potential applications in nulloelectronics, optoelectronics, and valleytronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 19, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1366, "End Page": 1370, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b05050", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b05050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459222300098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, KK; Tong, Y; Zhang, SH; He, RY; Xiao, L; Iqbal, Z; Zhang, YH; Gao, J; Zhang, L; Jiang, LB; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Kaikai; Tong, Yu; Zhang, Shihao; He, Ruiying; Xiao, Lan; Iqbal, Zoya; Zhang, Yuhong; Gao, Jie; Zhang, Lei; Jiang, Libo; Li, Yulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible Bicolorimetric Polyacrylamide/Chitosan Hydrogels for Smart Real-Time Monitoring and Promotion of Wound Healing", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Real-time monitoring of wound healing remains a major challenge in clinical tissue regeneration, calling the need for the development of biomaterial-guided on-site monitoring wound healing technology. In this study, multifunctional double colorimetry-integrated polyacrylamide-quaternary ammonium chitosan-carbon quantum dots (CQDs)-phenol red hydrogels are presented, aiming to simultaneously detect the wound pH level, reduce bacterial infection, and promote wound healing. The hybridization of CQDs and pH indicator (phenol red) with the hydrogels enables their high responsiveness, reversibility, and accurate indication of pH variability to reflect the dynamic wound status in the context of both ultraviolet and visible light. Furthermore, these visual images can be collected by smartphones and converted into on-site wound pH signals, allowing for a real-time evaluation of the wound dynamic conditions in a remote approach. Notably, the hydrogels exhibit excellent hemostatic and adhesive properties, maintain sufficient wound moisture, and promote wound healing via their high antibacterial activity (against Staphylococcus Aureus, and Escherichia Coli) and skin repair function. Overall, the resulting hydrogels have high potential as a novel smart and flexible wound dressing platform for theranostic skin regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 31, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102599, "DOI": "10.1002/adfm.202102599", "DOI Link": "http://dx.doi.org/10.1002/adfm.202102599", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662306900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, F; Zhang, SJ; Yang, TN; Xu, Z; Zhang, N; Liu, G; Wang, JJ; Wang, JL; Cheng, ZX; Ye, ZG; Luo, J; Shrout, TR; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fei; Zhang, Shujun; Yang, Tiannull; Xu, Zhuo; Zhang, null; Liu, Gang; Wang, Jianjun; Wang, Jianli; Cheng, Zhenxiang; Ye, Zuo-Guang; Luo, Jun; Shrout, Thomas R.; Chen, Long-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution single crystals is a breakthrough in ferroelectric materials. A key signature of relaxor-ferroelectric solid solutions is the existence of polar nulloregions, a nulloscale inhomogeneity, that coexist with normal ferroelectric domains. Despite two decades of extensive studies, the contribution of polar nulloregions to the underlying piezoelectric properties of relaxor ferroelectrics has yet to be established. Here we quantitatively characterize the contribution of polar nulloregions to the dielectric/piezoelectric responses of relaxor-ferroelectric crystals using a combination of cryogenic experiments and phase-field simulations. The contribution of polar nulloregions to the room-temperature dielectric and piezoelectric properties is in the range of 50-80%. A mesoscale mechanism is proposed to reveal the origin of the high piezoelectricity in relaxor ferroelectrics, where the polar nulloregions aligned in a ferroelectric matrix can facilitate polarization rotation. This mechanism emphasizes the critical role of local structure on the macroscopic properties of ferroelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 535, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13807, "DOI": "10.1038/ncomms13807", "DOI Link": "http://dx.doi.org/10.1038/ncomms13807", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389880200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MD; Liu, ZJ; Zhuang, MH; Yan, XX; Xu, GL; Gadre, CA; Tyagi, A; Abidi, IH; Sun, CJ; Wong, OL; Guda, A; Hao, YF; Pan, XQ; Amine, K; Luo, ZT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, Md Delowar; Liu, Zhenjing; Zhuang, Minghao; Yan, Xingxu; Xu, Gui-Liang; Gadre, Chaitanya Avinash; Tyagi, Abhishek; Abidi, Irfan Haider; Sun, Cheng-Jun; Wong, Hoilun; Guda, Alexander; Hao, Yufeng; Pan, Xiaoqing; Amine, Khalil; Luo, Zhengtang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational Design of Graphene-Supported Single Atom Catalysts for Hydrogen Evolution Reaction", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The proper choice of nonprecious transition metals as single atom catalysts (SACs) remains unclear for designing highly efficient electrocatalysts for hydrogen evolution reaction (HER). Herein, reported is an activity correlation with catalysts, electronic structure, in order to clarify the origin of reactivity for a series of transition metals supported on nitrogen-doped graphene as SACs for HER by a combination of density functional theory calculations and electrochemical measurements. Only few of the transition metals (e.g., Co, Cr, Fe, Rh, and V) as SACs show good catalytic activity toward HER as their Gibbs free energies are varied between the range of -0.20 to 0.30 eV but among which Co-SAC exhibits the highest electrochemical activity at 0.13 eV. Electronic structure studies show that the energy states of active valence d(z)(2) orbitals and their resulting antibonding state determine the catalytic activity for HER. The fact that the antibonding state orbital is neither completely empty nor fully filled in the case of Co-SAC is the main reason for its ideal hydrogen adsorption energy. Moreover, the electrochemical measurement shows that Co-SAC exhibits a superior hydrogen evolution activity over Ni-SAC and W-SAC, confirming the theoretical calculation. This systematic study gives a fundamental understanding about the design of highly efficient SACs for HER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2019, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803689, "DOI": "10.1002/aenm.201803689", "DOI Link": "http://dx.doi.org/10.1002/aenm.201803689", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461062900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, XM; Liu, L; Wu, YS; Yuan, DS; Wang, J; Zhang, CJ; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Xiameng; Liu, Ling; Wu, Yusi; Yuan, Dengsen; Wang, Jing; Zhang, Chengjiao; Wang, Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aerogel-Functionalized Thermoplastic Polyurethane as Waterproof, Breathable Freestanding Films and Coatings for Passive Daytime Radiative Cooling", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive daytime radiative cooling (PDRC) is an emerging sustainable technology that can spontaneously radiate heat to outer space through an atmospheric transparency window to achieve self-cooling. PDRC has attracted considerable attention and shows great potential for personal thermal management (PTM). However, PDRC polymers are limited to polyethylene, polyvinylidene fluoride, and their derivatives. In this study, a series of polymer films based on thermoplastic polyurethane (TPU) and their composite films with silica aerogels (aerogel-functionalized TPU (AFTPU)) are prepared using a simple and scalable non-solvent-phase-separation strategy. The TPU and AFTPU films are freestanding, mechanically strong, show high solar reflection up to 94%, and emit strongly in the atmospheric transparency window, thereby achieving subambient cooling of 10.0 and 7.7 degrees C on a hot summer day for the TPU and AFTPU film (10 wt%), respectively. The AFTPU films can be used as waterproof and moisture permeable coatings for traditional textiles, such as cotton, polyester, and nylon, and the highest temperature drop of 17.6 degrees C is achieved with respect to pristine nylon fabric, in which both the cooling performance and waterproof properties are highly desirable for the PTM applications. This study opens up a promising route for designing common polymers for highly efficient PDRC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 9, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201190, "DOI": "10.1002/advs.202201190", "DOI Link": "http://dx.doi.org/10.1002/advs.202201190", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787713900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Sapkota, D; Taniguchi, T; Watanabe, K; Mandrus, D; Morpurgo, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhe; Sapkota, Deepak; Taniguchi, Takashi; Watanabe, Kenji; Mandrus, David; Morpurgo, Alberto F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunneling Spin Valves Based on Fe3GeTe2/hBN/Fe3GeTe2 van der Waals Heterostructures", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thin van der Waals (vdW) layered magnetic materials hold the possibility of realizing vdW heterostructures with new functionalities. Here, we report on the realization and investigation of tunneling spin valves based on van der Waals heterostructures consisting of an atomically thin hBN layer acting as tunnel barrier and two exfoliated Fe3GeTe2 crystals acting as ferromagnetic electrodes. Low-temperature anomalous Hall effect measurements show that thin Fe3GeTe2 crystals are metallic ferromagnets with an easy axis perpendicular to the layers and a very sharp magnetization switching at magnetic field values that depends slightly on their geometry. In Fe3GeTe2/hBN/Fe3GeTe2 heterostructures, we observe textbook behavior of the tunneling resistance, which is minimum (maximum) when the magnetization in the two electrodes is parallel (antiparallel) to each other. The magnetoresistance is 160% at low temperature, from which we determine the spin polarization of Fe3GeTe2 to be 0.66, corresponding to 83% and 17% of the majority and minority carriers, respectively. The measurements also show that, with increasing temperature, the evolution of the spin polarization extracted from the tunneling magnetoresistance is proportional to the temperature dependence of the magnetization extracted from the analysis of the anomalous Hall conductivity. This suggests that the magnetic properties of the surface are representative of those of the bulk, as may be expected for vdW materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 18, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4303, "End Page": 4308, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b01278", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b01278", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439008300035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lambert, S; Wagner, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lambert, Scott; Wagner, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterisation of nulloplastics during the degradation of polystyrene", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The release of plastics into the environment has been identified as an important issue for some time. Recent publications have suggested that the degradation of plastic materials will result in the release of nullo-sized plastic particles to the environment. nulloparticle tracking analysis was applied to characterise the formation of nulloplastics during the degradation of a polystyrene (PS) disposable coffee cup lid. The results clearly show an increase in the formation of nulloplastics over time. After 56 days' exposure the concentration of nulloplastics in the PS sample was 1.26 x 10(8) particles/ml (average particles size 224 nm) compared to 0.41 x 10(8) particles/ml in the control. (C) 2015 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 790, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 145, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 268, "Article Number": null, "DOI": "10.1016/j.chemosphere.2015.11.078", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2015.11.078", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369196300033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yartys, VA; Lototskyy, MV; Akiba, E; Albert, R; Antonov, VE; Ares, JR; Baricco, M; Bourgeois, N; Buckley, CE; von Colbe, JMB; Crivello, JC; Cuevas, F; Denys, RV; Dornheim, M; Felderhoff, M; Grant, DM; Hauback, BC; Humphries, TD; Jacob, I; Jensen, TR; de Jongh, PE; Joubert, JM; Kuzovnikov, MA; Latroche, M; Paskevicius, M; Pasquini, L; Popilevsky, L; Skripnyuk, VM; Rabkin, E; Sofianos, MV; Stuart, A; Walker, G; Wang, H; Webb, CJ; Zhu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yartys, V. A.; Lototskyy, M. V.; Akiba, E.; Albert, R.; Antonov, V. E.; Ares, J. R.; Baricco, M.; Bourgeois, N.; Buckley, C. E.; von Colbe, J. M. Bellosta; Crivello, J. -C.; Cuevas, F.; Denys, R. V.; Dornheim, M.; Felderhoff, M.; Grant, D. M.; Hauback, B. C.; Humphries, T. D.; Jacob, I.; Jensen, T. R.; de Jongh, P. E.; Joubert, J. -M.; Kuzovnikov, M. A.; Latroche, M.; Paskevicius, M.; Pasquini, L.; Popilevsky, L.; Skripnyuk, V. M.; Rabkin, E.; Sofianos, M. V.; Stuart, A.; Walker, G.; Wang, Hui; Webb, C. J.; Zhu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnesium based materials for hydrogen based energy storage: Past, present and future", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium hydride owns the largest share of publications on solid materials for hydrogen storage. The Magnesium group of international experts contributing to IEA Task 32 Hydrogen Based Energy Storage recently published two review papers presenting the activities of the group focused on magnesium hydride based materials and on Mg based compounds for hydrogen and energy storage. This review article not only overviews the latest activities on both fundamental aspects of Mg-based hydrides and their applications, but also presents a historic overview on the topic and outlines projected future developments. Particular attention is paid to the theoretical and experimental studies of Mg-H system at extreme pressures, kinetics and thermodynamics of the systems based on MgH2, nullostructuring, new Mg-based compounds and novel composites, and catalysis in the Mg based H storage systems. Finally, thermal energy storage and upscaled H storage systems accommodating MgH2 are presented. (C) 2019 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 559, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 44, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 7809, "End Page": 7859, "Article Number": null, "DOI": "10.1016/j.ijhydene.2018.12.212", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2018.12.212", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463306900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, Y; Phua, SZF; Li, YB; Zhou, XJ; Jana, D; Liu, GF; Lim, WQ; Ong, WK; Yang, CL; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yan; Phua, Soo Zeng Fiona; Li, Youbing; Zhou, Xianju; Jana, Deblin; Liu, Guofeng; Lim, Wei Qi; Ong, Wee Kong; Yang, Chaolong; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong room temperature phosphorescence from amorphous organic materials toward confidential information encryption and decryption", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultralong room temperature phosphorescence (URTP) emitted from pure amorphous organic molecules is very rare. Although a few crystalline organic molecules could realize URTP with long lifetimes (>100 ms), practical applications of these crystalline organic phosphors are still challenging because the formation and maintenullce of high-quality crystals are very difficult and complicated. Herein, we present a rational design for minimizing the vibrational dissipation of pure amorphous organic molecules to achieve URTP. By using this strategy, a series of URTP films with long lifetimes and high phosphorescent quantum yields (up to 0.75 s and 11.23%, respectively) were obtained from amorphous organic phosphors without visible fluorescence and phosphorescence under ambient conditions. On the basis of the unique features of URTP films, a new green screen printing technology without using any ink was developed toward confidential information encryption and decryption. This work presents a breakthrough strategy in applying amorphous organic materials for URTP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 579, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaas9732", "DOI": "10.1126/sciadv.aas9732", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aas9732", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432440600049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, SH; Deng, JJ; Jin, YH; Qian, B; Lv, WQ; Zhou, QQ; Mei, EH; Neisiany, RE; Liu, YH; You, ZW; Pan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Sihan; Deng, Jiajia; Jin, Yuhui; Qian, Bo; Lv, Wanqi; Zhou, Qiangqiang; Mei, Enhua; Neisiany, Rasoul Esmaeely; Liu, Yuehua; You, Zhengwei; Pan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breathable, antifreezing, mechanically skin-like hydrogel textile wound dressings with dual antibacterial mechanisms", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are emerging as the most promising dressings due to their excellent biocompatibility, extracellular matrix mimicking structure, and drug loading ability. However, existing hydrogel dressings exhibit limited breathability, poor environmental adaptability, potential drug resistance, and limited drug options, which extremely restrict their therapeutic effect and working scenarios. Here, the current research introduces the first paradigm of hydrogel textile dressings based on novel gelatin glycerin hydrogel (glyhydrogel) fibers fabricated by the Hofmeister effect based wet spinning. Benefiting from the unique knitted structure, the textile dressing features excellent breathability (1800 times that of the commercially available 3 M dressing) and stretchability (535.51 & PLUSMN; 38.66%). Furthermore, the glyhydrogel textile dressing can also withstand the extreme temperature of-80 C, showing the potential for application in subzero environments. Moreover, the introduction of glycerin endows the textile dressing with remarkable antibacterial property and expands the selection of loaded drugs (e. g., clindamycin). The prepared glyhydrogel textile dressing shows an excellent infected wound healing effect with a complete rat skin closure within 14 days. All these functions have not been achievable by traditional hydrogel dressings and provide a new approach for the development of hydrogel dressings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 313, "End Page": 323, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.08.014", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.08.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000861611800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YY; Upputuri, PK; Xie, C; Zeng, ZL; Sharma, A; Zhen, X; Li, JC; Huang, JG; Pramanik, M; Pu, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuyan; Upputuri, Paul Kumar; Xie, Chen; Zeng, Ziling; Sharma, Arunima; Zhen, Xu; Li, Jingchao; Huang, Jiaguo; Pramanik, Manojit; Pu, Kanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metabolizable Semiconducting Polymer nulloparticles for Second Near-Infrared Photoacoustic Imaging", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoacoustic (PA) imaging in the second near-infrared (NIR-II) window (1000-1700 nm) holds great promise for deep-tissue diagnosis due to the reduced light scattering and minimized tissue absorption; however, exploration of such a noninvasive imaging technique is greatly constrained by the lack of biodegradable NIR-II absorbing agents. Herein, the first series of metabolizable NIR-II PA agents are reported based on semiconducting polymer nulloparticles (SPNs). Such completely organic nulloagents consist of pi-conjugated yet oxidizable optical polymer as PA generator and hydrolyzable amphiphilic polymer as particle matrix to provide water solubility. The obtained SPNs are readily degraded by myeloperoxidase and lipase abundant in phagocytes, transforming from nonfluorescent nulloparticles (30 nm) into NIR fluorescent ultrasmall metabolites (approximate to 1 nm). As such, these nulloagents can be effectively cleared out via both hepatobiliary and renal excretions after systematic administration, leaving no toxicity to living mice. Particularly these nulloagents possess high photothermal conversion efficiencies and emit bright PA signals at 1064 nm, enabling sensitive NIR-II PA imaging of both subcutaneous tumor and deep brain vasculature through intact skull in living animals at a low systematic dosage. This study thus provides a generalized molecular design toward organic metabolizable semiconducting materials for biophotonic applications in NIR-II window.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2019, "Volume": 31, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1808166, "DOI": "10.1002/adma.201808166", "DOI Link": "http://dx.doi.org/10.1002/adma.201808166", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461575300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZJ; Mao, MM; Wang, JW; Gludovatz, B; Zhang, Z; Mao, SX; George, EP; Yu, Q; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, ZiJiao; Mao, M. M.; Wang, Jiangwei; Gludovatz, Bernd; Zhang, Ze; Mao, Scott X.; George, Easo P.; Yu, Qian; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Damage tolerance can be an elusive characteristic of structural materials requiring both high strength and ductility, properties that are often mutually exclusive. High-entropy alloys are of interest in this regard. Specifically, the single-phase CrMnFeCoNi alloy displays tensile strength levels of similar to 1GPa, excellent ductility (similar to 60-70%) and exceptional fracture toughness (K-JIc>200 MPa root m). Here through the use of in situ straining in an aberration-corrected transmission electron microscope, we report on the salient atomistic to micro-scale mechanisms underlying the origin of these properties. We identify a synergy of multiple deformation mechanisms, rarely achieved in metallic alloys, which generates high strength, work hardening and ductility, including the easy motion of Shockley partials, their interactions to form stacking-fault parallelepipeds, and arrest at planar slip bands of undissociated dislocations. We further show that crack propagation is impeded by twinned, nulloscale bridges that form between the near-tip crack faces and delay fracture by shielding the crack tip.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 666, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10143, "DOI": "10.1038/ncomms10143", "DOI Link": "http://dx.doi.org/10.1038/ncomms10143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367571300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaneti, YV; Guo, YN; Septiani, NLW; Iqbal, M; Jiang, XC; Takei, T; Yuliarto, B; Alothman, ZA; Golberg, D; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kaneti, Yusuf Valentino; Guo, Yanna; Septiani, Ni Luh Wulan; Iqbal, Muhammad; Jiang, Xuchuan; Takei, Toshiaki; Yuliarto, Brian; Alothman, Zeid A.; Golberg, Dmitri; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-templated fabrication of hierarchical hollow manganese-cobalt phosphide yolk-shell spheres for enhanced oxygen evolution reaction", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hierarchical nullostructures with hollow architectures can provide rich active sites, improved transport of ions, and highly robust structure for electrochemical applications. In this work, we report the self-templated fabrication of hierarchical manganese-cobalt phosphide (Mn-Co phosphide) yolk-shell spheres using highly uniform cobalt glycerate spheres as sacrificial templates. Through a simple exchange reaction with the manganese precursor solution at room temperature, these cobalt glycerate spheres are readily converted to hierarchical MnCo LDH yolk-shell spheres, which can be further phosphidized at 350 degrees C under inert atmosphere to generate hierarchical Mn-Co phosphide with distinct yolk-shell morphology. When tested as an electrocatalyst for oxygen evolution reaction (OER), the hierarchical Mn-Co phosphide yolk-shell spheres exhibit an overpotential of 330 mV at a current density of 10 mA cm(-2) and a Tafel slope of 59.0 mV dec(-1), which are higher than those of Mn-Co oxide yolk-shell spheres (480 mV and 113 mV dec(-1)) and hierarchical cobalt phosphide spheres (410 mV and 61.3 mV dec(-1)). Post-OER analysis by XPS reveals that the high activity of the hierarchical Mn-Co phosphide yolk-shell catalyst originates from the existence of Mn4+/Mn3+ and Co2+/Co3+ redox couples and the formation of active metal oxyhydroxide species on its surface. The proposed self-sacrificial templating strategy will provide useful guidance for future construction of hollow inorganic metal nullostructures with yolk-shell morphology for energy storage and conversion applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 405, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126580, "DOI": "10.1016/j.cej.2020.126580", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.126580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621234200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chou, TC; Chang, CC; Yu, HL; Yu, WY; Dong, CL; Velasco-Vélez, JJ; Chuang, CH; Chen, LC; Lee, JF; Chen, JM; Wu, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chou, Tsu-Chin; Chang, Chiao-Chun; Yu, Hung-Ling; Yu, Wen-Yueh; Dong, Chung-Li; Velasco-Velez, Juan Jesus; Chuang, Cheng-Hao; Chen, Li-Chyong; Lee, Jyh-Fu; Chen, Jin-Ming; Wu, Heng-Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling the Oxidation State of the Cu Electrode and Reaction Intermediates for Electrochemical CO2 Reduction to Ethylene", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the role of the oxidation state of the Cu surface and surface-adsorbed intermediate species in electrochemical CO2 reduction is crucial for the development of selective CO2-to-fuel electrocatalysts. In this study, the electrochemical CO2 reduction mechanism over the Cu catalysts with various oxidation states was studied by using in situ surface-enhanced infrared absorption spectroscopy (SEIRAS), in situ soft X-ray absorption spectroscopy (Cu L-edge), and online gas chromatography measurements. The atop-adsorbed CO (COatop) intermediate is obtained on the electrodeposited Cu surface which primarily has the oxidation state of Cu(I). CO atop is further reduced, followed by the formation of C-1 product such as CH4. The residual bridge-adsorbed CO (CObridge) is formed on the as-prepared Cu surface with Cu(0) which inhibits hydrocarbon formation. In contrast, the CV-treated Cu electrode prepared by oxidizing the as-prepared Cu surface contains different amounts of Cu(I) and Cu(0) states. The major theme of this work is that in situ SEIRAS results show the coexistence of COatop and CObridge as the reaction intermediates during CO2 reduction and that the selectivity of CO2-to-ethylene conversion is further enhanced in the CV-treated Cu electrode. The Cu catalysts modulated by the electrochemical method exhibit different oxidation states and reaction intermediates as well as electrocatalytic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2020, "Volume": 142, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2857, "End Page": 2867, "Article Number": null, "DOI": "10.1021/jacs.9b11126", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b11126", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514255300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Realini, CE; Marcos, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Realini, Carolina E.; Marcos, Begonya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active and intelligent packaging systems for a modern society", "Source Title": "MEAT SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active and intelligent packaging systems are continuously evolving in response to growing challenges from a modern society. This article reviews: (1) the different categories of active and intelligent packaging concepts and currently available commercial applications, (2) latest packaging research trends and innovations, and (3) the growth perspectives of the active and intelligent packaging market Active packaging aiming at extending shelf life or improving safety while maintaining quality is progressing towards the incorporation of natural active agents into more sustainable packaging materials. Intelligent packaging systems which monitor the condition of the packed food or its environment are progressing towards more cost-effective, convenient and integrated systems to provide innovative packaging solutions. Market growth is expected for active packaging with leading shares for moisture absorbers, oxygen scavengers, microwave susceptors and antimicrobial packaging. The market for intelligent packaging is also promising with strong gains for time-temperature indicator labels and advancements in the integration of intelligent concepts into packaging materials. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 98, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 404, "End Page": 419, "Article Number": null, "DOI": "10.1016/j.meatsci.2014.06.031", "DOI Link": "http://dx.doi.org/10.1016/j.meatsci.2014.06.031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341466900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KJ; Liu, K; An, PD; Li, HJW; Lin, YY; Hu, JH; Jia, CK; Fu, JW; Li, HM; Liu, H; Lin, Z; Li, WZ; Li, JH; Lu, YR; Chan, TS; Zhang, N; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Kejun; Liu, Kang; An, Pengda; Li, Huangjingwei; Lin, Yiyang; Hu, Junhua; Jia, Chuankun; Fu, Junwei; Li, Hongmei; Liu, Hui; Lin, Zhang; Li, Wenzhang; Li, Jiahang; Lu, Ying-Rui; Chan, Ting-Shan; Zhang, Ning; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron phthalocyanine with coordination induced electronic localization to boost oxygen reduction reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron phthalocyanine (FePc) is a promising non-precious catalyst for the oxygen reduction reaction (ORR). Unfortunately, FePc with plane-symmetric FeN4 site usually exhibits an unsatisfactory ORR activity due to its poor O-2 adsorption and activation. Here, we report an axial Fe-O coordination induced electronic localization strategy to improve its O-2 adsorption, activation and thus the ORR performance. Theoretical calculations indicate that the Fe-O coordination evokes the electronic localization among the axial direction of O-FeN4 sites to enhance O-2 adsorption and activation. To realize this speculation, FePc is coordinated with an oxidized carbon. Synchrotron X-ray absorption and Mossbauer spectra validate Fe-O coordination between FePc and carbon. The obtained catalyst exhibits fast kinetics for O-2 adsorption and activation with an ultralow Tafel slope of 27.5mVdec(-1) and a remarkable half-wave potential of 0.90V. This work offers a new strategy to regulate catalytic sites for better performance. Iron phthalocyanine with a 2D structure and symmetric electron distribution around Fe-N-4 active sites is not optimal for O-2 adsorption and activation. Here, the authors report an axial Fe-O coordination induced electronic localization strategy to enhance oxygen reduction reaction performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 540, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4173, "DOI": "10.1038/s41467-020-18062-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18062-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568893000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pihosh, Y; Turkevych, I; Mawatari, K; Uemura, J; Kazoe, Y; Kosar, S; Makita, K; Sugaya, T; Matsui, T; Fujita, D; Tosa, M; Kondo, M; Kitamori, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pihosh, Yuriy; Turkevych, Ivan; Mawatari, Kazuma; Uemura, Jin; Kazoe, Yutaka; Kosar, Sonya; Makita, Kikuo; Sugaya, Takeyoshi; Matsui, Takuya; Fujita, Daisuke; Tosa, Masahiro; Kondo, Michio; Kitamori, Takehiko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic generation of hydrogen by core-shell WO3/BiVO4 nullorods with ultimate water splitting efficiency", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient photocatalytic water splitting requires effective generation, separation and transfer of photo-induced charge carriers that can hardly be achieved simultaneously in a single material. Here we show that the effectiveness of each process can be separately maximized in a nullostructured heterojunction with extremely thin absorber layer. We demonstrate this concept on WO3/BiVO4+CoPi core-shell nullostructured photoanode that achieves near theoretical water splitting efficiency. BiVO4 is characterized by a high recombination rate of photogenerated carriers that have much shorter diffusion length than the thickness required for sufficient light absorption. This issue can be resolved by the combination of BiVO4 with more conductive WO3 nullorods in a form of coreshell heterojunction, where the BiVO4 absorber layer is thinner than the carrier diffusion length while it's optical thickness is reestablished by light trapping in high aspect ratio nullostructures. Our photoanode demonstrates ultimate water splitting photocurrent of 6.72 mA cm(-2) under 1 sun illumination at 1.23 VRHE that corresponds to -90% of the theoretically possible value for BiVO4. We also demonstrate a self-biased operation of the photoanode in tandem with a double-junction GaAs/InGaAsP photovoltaic cell with stable water splitting photocurrent of 6.56 mA cm(-2) that corresponds to the solar to hydrogen generation efficiency of 8.1%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11141, "DOI": "10.1038/srep11141", "DOI Link": "http://dx.doi.org/10.1038/srep11141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356070900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, L; Wang, K; Sarkar, A; Njel, C; Karkera, G; Wang, QS; Azmi, R; Fichtner, M; Hahn, H; Schweidler, S; Breitung, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Ling; Wang, Kai; Sarkar, Abhishek; Njel, Christian; Karkera, Guruprakash; Wang, Qingsong; Azmi, Raheleh; Fichtner, Maximilian; Hahn, Horst; Schweidler, Simon; Breitung, Ben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Sulfides as Electrode Materials for Li-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy sulfides (HESs) containing 5 equiatomic transition metals (M), with different M:S ratios, are prepared by a facile one-step mechanochemical approach. Two new types of single-phase HESs with pyrite (Pa-3) and orthorhombic (Pnma) structures are obtained and demonstrate a homogeneously mixed solid solution. The straightforward synthesis method can easily tune the desired metal to sulfur ratio for HESs with different stoichiometries, by utilizing the respective metal sulfides, even pure metals, and sulfur as precursor chemicals. The structural details and solid solution nature of HESs are studied by X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy, electron energy loss spectroscopy, X-ray photoelectron spectroscopy, inductively coupled plasma optical emission spectroscopy, and Mossbauer spectroscopy. Since transition metal sulfides are a very versatile material class, here the application of HESs is presented as electrode materials for reversible electrochemical energy storage, in which the HESs show high specific capacities and excellent rate capabilities in secondary Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103090, "DOI": "10.1002/aenm.202103090", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103090", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000738815000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, CY; Wang, L; Li, X; Qian, X; Wu, ZC; You, WB; Pei, K; Qin, G; Zeng, QW; Yang, ZQ; Jin, C; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Chunyang; Wang, Lei; Li, Xiao; Qian, Xiang; Wu, Zhengchen; You, Wenbin; Pei, Ke; Qin, Gang; Zeng, Qingwen; Yang, Ziqi; Jin, Chen; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Magnetic Network Constructed by CoFe nulloparticles Suspended Within Tubes on Rods Matrix Toward Enhanced Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsThree-dimension hierarchical core-shell Mo2N@CoFe@C/CNT composites were successfully constructed via a fast MOF-based ligand exchange strategy.Abundant magnetic CoFe nulloparticles suspended within nullotubes on microrods matrix exhibited strong magnetic loss capability, confirmed by off-axis electron holography.Hierarchical Mo2N@CoFe@C/CNT composites displayed remarkable microwave absorption value of -53.5 dB. AbstractHierarchical magnetic-dielectric composites are promising functional materials with prospective applications in microwave absorption (MA) field. Herein, a three-dimension hierarchical nullotubes on microrods, core-shell magnetic metal-carbon composite is rationally constructed for the first time via a fast metal-organic frameworks-based ligand exchange strategy followed by a carbonization treatment with melamine. Abundant magnetic CoFe nulloparticles are embedded within one-dimensional graphitized carbon/carbon nullotubes supported on micro-scale Mo2N rod (Mo2N@CoFe@C/CNT), constructing a special multi-dimension hierarchical MA material. Ligand exchange reaction is found to determine the formation of hierarchical magnetic-dielectric composite, which is assembled by dielectric Mo2N as core and spatially dispersed CoFe nulloparticles within C/CNTs as shell. Mo2N@CoFe@C/CNT composites exhibit superior MA performance with maximum reflection loss of -53.5 dB at 2 mm thickness and show a broad effective absorption bandwidth of 5.0 GHz. The Mo2N@CoFe@C/CNT composites hold the following advantages: (1) hierarchical core-shell structure offers plentiful of heterojunction interfaces and triggers interfacial polarization, (2) unique electronic migration/hop paths in the graphitized C/CNTs and Mo2N rod facilitate conductive loss, (3) highly dispersed magnetic CoFe nulloparticles within tubes on rods matrix build multi-scale magnetic coupling network and reinforce magnetic response capability, confirmed by the off-axis electron holography.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 47, "DOI": "10.1007/s40820-020-00572-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00572-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607061500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shekhah, O; Belmabkhout, Y; Chen, ZJ; Guillerm, V; Cairns, A; Adil, K; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shekhah, Osama; Belmabkhout, Youssef; Chen, Zhijie; Guillerm, Vincent; Cairns, Amy; Adil, Karim; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct air capture is regarded as a plausible alternate approach that, if economically practical, can mitigate the increasing carbon dioxide emissions associated with two of the main carbon polluting sources, namely stationary power plants and transportation. Here we show that metal-organic framework crystal chemistry permits the construction of an isostructural metal-organic framework (SIFSIX-3-Cu) based on pyrazine/copper(II) two-dimensional periodic 4(4) square grids pillared by silicon hexafluoride anions and thus allows further contraction of the pore system to 3.5 versus 3.84 angstrom for the parent zinc(II) derivative. This enhances the adsorption energetics and subsequently displays carbon dioxide uptake and selectivity at very low partial pressures relevant to air capture and trace carbon dioxide removal. The resultant SIFSIX-3-Cu exhibits uniformly distributed adsorption energetics and offers enhanced carbon dioxide physical adsorption properties, uptake and selectivity in highly diluted gas streams, a performance, to the best of our knowledge, unachievable with other classes of porous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 576, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4228, "DOI": "10.1038/ncomms5228", "DOI Link": "http://dx.doi.org/10.1038/ncomms5228", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338839900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, GQ; Xu, R; Xing, ZY; Yuan, YF; Lu, J; Wen, JG; Liu, C; Ma, L; Zhan, C; Liu, Q; Wu, TP; Jian, ZL; Shahbazian-Yassar, R; Ren, Y; Miller, DJ; Curtiss, LA; Ji, XL; Amine, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Guoqiang; Xu, Rui; Xing, Zhenyu; Yuan, Yifei; Lu, Jun; Wen, Jianguo; Liu, Cong; Ma, Lu; Zhan, Chun; Liu, Qi; Wu, Tianpin; Jian, Zelang; Shahbazian-Yassar, Reza; Ren, Yang; Miller, Dean J.; Curtiss, Larry A.; Ji, Xiulei; Amine, Khalil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Burning lithium in CS2 for high-performing compact Li2S-graphene nullocapsules for Li-S batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tremendous efforts have been made to design the cathode of Li-S batteries to improve their energy density and cycling life. However, challenges remain in achieving fast electronic and ionic transport while accommodating the significant cathode volumetric change, especially for the cathode with a high practical mass loading. Here we report a cathode architecture, which is constructed by burning lithium foils in a CS2 vapour. The obtained structure features crystalline Li2S nulloparticles wrapped by few-layer graphene (Li2S@ graphene nullocapsules). Because of the improvement on the volumetric efficiency for accommodating sulfur active species and electrical properties, the cathode design enables promising electrochemical performance. More notably, at a loading of 10 mg(Li2S) cm(-2), the electrode exhibits a high reversible capacity of 1,160 mAh g(-1) s, namely, an area capacity of 8.1 mAhcm(-2). Li2S@ graphene cathode demonstrates a great potential for Li-ion batteries, where the Li2S@ graphene-cathode//graphite-anode cell displays a high capacity of 730 mAh g(-1) s aswell as stable cycle performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17090, "DOI": "10.1038/nenergy.2017.90", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.90", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406499200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SY; Shi, W; Cheng, P; Zaworotko, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shi-Yuan; Shi, Wei; Cheng, Peng; Zaworotko, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Mixed-Crystal Lanthanide Zeolite-like Metal-Organic Framework as a Fluorescent Indicator for Lysophosphatidic Acid, a Cancer Biomarker", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two lanthanide zeolite-like metal-organic frameworks (Ln-ZMOFs) with rho topology, Tb-ZMOF and Eu-ZMOF, were constructed by self-assembly of a 4-connected lanthanide molecular building block and a bipyridine-dicarboxylate ligand. Varying the Tb3+ and Eu3+ ratio during synthesis afforded three mixed-crystal isostructural MZMOFs with variable Eu:Tb stoichiometry. Fluorescence studies revealed that a methanol suspension of one of these mixed crystals, MZMOF-3, exhibits selective detection of lysophosphatidic acid (LPA), a biomarker for ovarian cancer and other gynecologic cancers. Linear correlation between the integrated fluorescence intensity and the concentration of LPA was observed, enabling quantitative analysis of LPA in physiologically relevant ranges (1.4-43.3 mu M). MZ-MOF-3 therefore has the potential to act as a self-referencing and self-calibrating fluorescent indicator for LPA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2015, "Volume": 137, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12203, "End Page": 12206, "Article Number": null, "DOI": "10.1021/jacs.5b06929", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b06929", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362243300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PY; Zhang, XW; Zhou, YQ; Jiang, Q; Ye, QF; Chu, ZM; Li, XX; Yang, XL; Yin, ZG; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengyang; Zhang, Xingwang; Zhou, Yuqin; Jiang, Qi; Ye, Qiufeng; Chu, Zema; Li, Xingxing; Yang, Xiaolei; Yin, Zhigang; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent-controlled growth of inorganic perovskite films in dry environment for efficient and stable solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic halide perovskites such as cesium lead halide are promising due to their excellent thermal stability. Cesium lead iodide (CsPbI3) has a bandgap of 1.73 eV and is very suitable for making efficient tandem solar cells, either with low-bandgap perovskite or silicon. However, the phase instability of CsPbI3 is hindering the further optimization of device performance. Here, we show that high quality and stable a-phase CsPbI3 film is obtained via solvent-controlled growth of the precursor film in a dry environment. A 15.7% power conversion efficiency of CsPbI3 solar cells is achieved, which is the highest efficiency reported for inorganic perovskite solar cells up to now. And more importantly, the devices can tolerate continuous light soaking for more than 500 h without efficiency drop.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 551, "Times Cited, All Databases": 581, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2225, "DOI": "10.1038/s41467-018-04636-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04636-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434644200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "D'Innocenzo, V; Grancini, G; Alcocer, MJP; Kandada, ARS; Stranks, SD; Lee, MM; Lanzani, G; Snaith, HJ; Petrozza, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "D'Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P.; Kandada, Ajay Ram Srimath; Stranks, Samuel D.; Lee, Michael M.; Lanzani, Guglielmo; Snaith, Henry J.; Petrozza, Annamaria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitons versus free charges in organo-lead tri-halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Excitonic solar cells, within which bound electron-hole pairs have a central role in energy harvesting, have represented a hot field of research over the last two decades due to the compelling prospect of low-cost solar energy. However, in such cells, exciton dissociation and charge collection occur with significant losses in energy, essentially due to poor charge screening. Organic-inorganic perovskites show promise for overcoming such limitations. Here, we use optical spectroscopy to estimate the exciton binding energy in the mixed-halide crystal to be in the range of 50 meV. We show that such a value is consistent with almost full ionization of the exciton population under photovoltaic cell operating conditions. However, increasing the total photoexcitation density, excitonic species become dominullt, widening the perspective of this material for a host of optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1547, "Times Cited, All Databases": 1633, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3586, "DOI": "10.1038/ncomms4586", "DOI Link": "http://dx.doi.org/10.1038/ncomms4586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335220400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Satheeshkumar, E; Makaryan, T; Melikyan, A; Minassian, H; Gogotsi, Y; Yoshimura, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Satheeshkumar, Elumalai; Makaryan, Taron; Melikyan, Armen; Minassian, Hayk; Gogotsi, Yury; Yoshimura, Masahiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-step Solution Processing of Ag, Au and Pd@MXene Hybrids for SERS", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on one-step hybridization of silver, gold and palladium nulloparticles from solution onto exfoliated two-dimensional (2D) Ti3C2 titanium carbide (MXene) nullosheets. The produced hybrid materials can be used as substrates for surface-enhanced Raman spectroscopy (SERS). An approximate analytical approach is also developed for the calculation of the surface plasmon resonullce (SPR) frequency of nulloparticles immersed in a medium, near the interface of two dielectric media with different dielectric constants. We obtained a good match with the experimental data for SPR wavelengths, 440 nm and 558 nm, respectively for silver and gold nulloparticles. In the case of palladium, our calculated SPR wavelength for the planar geometry was 160 nm, demonstrating that non-spherical palladium nulloparticles coupled with 2D MXene yield a broad, significanlty red-shifted SPR band with a peak at 230 nm. We propose a possible mechanism of the plasmonic hybridization of nulloparticles with MXene. The as-prepared noble metal nulloparticles on MXene show a highly sensitive SERS detection of methylene blue (MB) with calculated enhancement factors on the order of 10(5). These findings open a pathway for extending visible-range SERS applications of novel 2D hybrid materials in sensors, catalysis, and biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 32049, "DOI": "10.1038/srep32049", "DOI Link": "http://dx.doi.org/10.1038/srep32049", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381883400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoo, HD; Markevich, E; Salitra, G; Sharon, D; Aurbach, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoo, Hyun Deog; Markevich, Elena; Salitra, Gregory; Sharon, Daniel; Aurbach, Doron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the challenge of developing advanced technologies for electrochemical energy storage and conversion", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The accelerated production of sophisticated miniaturized mobile electronic devices, challenges such as the electrochemical propulsion of electric vehicles (EVs), and the need for large-scale storage of sustainable energy (i.e. load-levelling applications) motivate and stimulate the development of novel rechargeable batteries and super-capacitors. While batteries deliver high energy density but limited cycle life and power density, super-capacitors provide high power density and very prolonged cycling. Lithium-ion batteries are the focus of intensive R&D efforts because they promise very high energy density that may be suitable for electrical propulsion. Here, we review research on batteries with an emphasis on Li-ion battery technology, examining its suitability for EV applications. We also briefly examine other battery systems that may be of importance for load-levelling applications, including rechargeable magnesium batteries. We give a short review of the status of technologies beyond Li-ion batteries, including Li-sulfur and Li-oxygen systems. Finally, we briefly discuss recent progress in the R&D of advanced super-capacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 522, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 110, "End Page": 121, "Article Number": null, "DOI": "10.1016/j.mattod.2014.02.014", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.02.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334584400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZF; Yang, Y; Zhao, ZF; Zhang, PH; Zhang, YS; Liu, JJ; Ma, SQ; Cheng, P; Chen, Y; Zhang, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhifang; Yang, Yi; Zhao, Zhengfeng; Zhang, Penghui; Zhang, Yushu; Liu, Jinjin; Ma, Shengqian; Cheng, Peng; Chen, Yao; Zhang, Zhenjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of olefin-linked covalent organic frameworks for hydrogen fuel cell applications", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Green synthesis of crystalline porous materials for energy-related applications is of great significance but very challenging. Here, we create a green strategy to fabricate a highly crystalline olefin-linked pyrazine-based covalent organic framework (COF) with high robustness and porosity under solvent-free conditions. The abundant nitrogen sites, high hydrophilicity, and well-defined one-dimensional nullochannels make the resulting COF an ideal platform to confine and stabilize the H3PO4 network in the pores through hydrogen-bonding interactions. The resulting material exhibits low activation energy (E-a) of 0.06eV, and ultrahigh proton conductivity across a wide relative humidity (10-90%) and temperature range (25-80 degrees C). A realistic proton exchange membrane fuel cell using the olefin-linked COF as the solid electrolyte achieve a maximum power of 135mWcm(-2) and a current density of 676mAcm(-2), which exceeds all reported COF materials. Developing eco-friendly synthetic routes for fabricating robust covalent organic frameworks (COFs) remains a challenge. Herein, the authors created a green strategy to fabricate a highly crystalline olefin-linked COF which exhibited great promise application in proton exchange membrane fuel cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1982, "DOI": "10.1038/s41467-021-22288-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22288-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636879000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, JW; Zhao, ZH; Shang, HS; Peng, B; Chen, WX; Pei, JJ; Zheng, LR; Dong, JC; Cao, R; Sarangi, R; Jiang, ZL; Zhou, DN; Zhuang, ZB; Zhang, JT; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Jiawei; Zhao, Zhenghang; Shang, Huishan; Peng, Bo; Chen, Wenxing; Pei, Jiajing; Zheng, Lirong; Dong, Juncai; Cao, Rui; Sarangi, Ritimukta; Jiang, Zhuoli; Zhou, Danni; Zhuang, Zhongbin; Zhang, Jiatao; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Phosphatizing of Triphenylphosphine Encapsulated within Metal-Organic Frameworks to Design Atomic Co1-P1N3 Interfacial Structure for Promoting Catalytic Performance", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The engineering coordination environment offers great opportunity in performance tunability of isolated metal single-atom catalysts. For the most popular metal-N-x(MNx) structure, the replacement of N atoms by some other atoms with relatively weak electronegativity has been regarded as a promising strategy for optimizing the coordination environment of an active metal center and promoting its catalytic performance, which is still a challenge. Herein, we proposed a new synthetic strategy of an in situ phosphatizing of triphenylphosphine encapsulated within metal-organic frameworks for designing atomic Co-1-P1N3 interfacial structure, where a cobalt single atom is costabilized by one P atom and three N atoms (denoted as Co-SA/P-in situ). In the acidic media, the Co-SA/P-in situ catalyst with Co-x-P1N3 interfacial structure exhibits excellent activity and durability for the hydrogen evolution reaction (HER) with a low overpotential of 98 mV at 10 mA cm(-2) and a small Tafel slope of 47 mV dec(-1), which are greatly superior to those of catalyst with Co-1-N-4 interfacial structure. We discover that the bond-length-extended high-valence Co-x-P1N3 atomic interface structure plays a crucial role in boosting the HER performance, which is supported by in situ X-ray absorption fine structure (XAFS) measurements and density functional theory (DFT) calculation. We hope this work will promote the development of high performance metal single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2020, "Volume": 142, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8431, "End Page": 8439, "Article Number": null, "DOI": "10.1021/jacs.0c02229", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c02229", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535173500043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, BL; Wen, TQ; Nguyen, MC; Hao, LY; Wang, CZ; Chu, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Beilin; Wen, Tongqi; Manh Cuong Nguyen; Hao, Luyao; Wang, Cai-Zhuang; Chu, Yanhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles study, fabrication and characterization of (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramics", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation possibility of a new (Zr0.25Nb0.25Ti0.25V0.25)C high-entropy ceramics (ZHC-1) was first analyzed by the first-principles calculations and thermodynamical analysis and then it was successfully fabricated by hot pressing sintering technique. The first-principles calculation results showed that the mixing enthalpy of ZHC-1 was 5.526 kJ/cool and the mixing entropy of ZHC-1 was in the range of 0.693R -1.040R. The thermodynamical analysis results showed that ZHC-1 was thermodynamically stable above 959 K owing to its negative mixing Gibbs free energy. The experimental results showed that the as prepared ZHC-1 (95.1% relative density) possessed a single rock-salt crystal structure, some interesting nulloplate-like structures, and high compositional uniformity from nulloscale to microscale. By taking advantage of these unique features, compared with the initial metal carbides (ZrC, NbC, TiC and VC), it showed a relatively low thermal conductivity of 15.3 +/- 0.3 W/(m.K) at room temperature, which was due to the presence of solid solution effects, nulloplates and porosity. Meanwhile, it exhibited the relatively high nullohardness of 30.3 +/- 0.7 GPa and elastic modulus of 460.4 +/- 19.2 GPa and the higher fracture toughness of 4.7 +/- 0.5 MPa m(1/2), which were attributed to the solid solution strengthening mechanism and nulloplate pullout and microcrack deflection toughening mechanism. (C) 2019 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 170, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15, "End Page": 23, "Article Number": null, "DOI": "10.1016/j.actamat.2019.03.021", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2019.03.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466252400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, WJ; He, Q; Meng, KY; Tan, XL; Zhou, ZH; Zhang, GQ; Yang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Wenjing; He, Qiang; Meng, Keyu; Tan, Xulong; Zhou, Zhihao; Zhang, Gaoqiang; Yang, Jin; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-knitted washable sensor array textile for precise epidermal physiological signal monitoring", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable textile electronics are highly desirable for realizing personalized health management. However, most reported textile electronics can either periodically target a single physiological signal or miss the explicit details of the signals, leading to a partial health assessment. Furthermore, textiles with excellent property and comfort still remain a challenge. Here, we report a triboelectric all-textile sensor array with high pressure sensitivity and comfort. It exhibits the pressure sensitivity (7.84 mV Pa-1), fast response time (20 ms), stability (>100,000 cycles), wide working frequency bandwidth (up to 20 Hz), and machine washability (>40 washes). The fabricated TATSAs were stitched into different parts of clothes to monitor the arterial pulse waves and respiratory signals simultaneously. We further developed a health monitoring system for long-term and noninvasive assessment of cardiovascular disease and sleep apnea syndrome, which exhibits great advancement for quantitative analysis of some chronic diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay2840", "DOI": "10.1126/sciadv.aay2840", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay2840", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520866800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nemani, SK; Zhang, BW; Wyatt, BC; Hood, ZD; Manna, S; Khaledialidusti, R; Hong, WC; Sternberg, MG; Sankaranarayanull, SKRS; Anasori, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nemani, Srinivasa Kartik; Zhang, Bowen; Wyatt, Brian C.; Hood, Zachary D.; Manna, Sukriti; Khaledialidusti, Rasoul; Hong, Weichen; Sternberg, Michael G.; Sankaranarayanull, Subramanian K. R. S.; Anasori, Babak", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy 2D Carbide MXenes: TiVNbMoC3 and TiVCrMoC3", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, are a fast-growing family of 2D materials. MXenes 2D flakes have n + 1 (n = 1-4) atomic layers of transition metals interleaved by carbon/nitrogen layers, but to-date remain limited in composition to one or two transition metals. In this study, by implementing four transition metals, we report the synthesis of multi-principal-element high-entropy M4C3Tx MXenes. Specifically, we introduce two high-entropy MXenes, TiVNbMoC3Tx and TiVCrMoC3Tx, as well as their precursor TiVNbMoAlC3 and TiVCrMoAlC3 high-entropy MAX phases. We used a combination of real and reciprocal space characterization (X-ray diffraction, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, and scanning transmission electron microscopy) to establish the structure, phase purity, and equimolar distribution of the four transition metals in high-entropy MAX and MXene phases. We use first-principles calculations to compute the formation energies and explore synthesizability of these high-entropy MAX phases. We also show that when three transition metals are used instead of four, under similar synthesis conditions to those of the four-transition-metal MAX phase, two different MAX phases can be formed (i.e., no pure single-phase forms). This finding indicates the importance of configurational entropy in stabilizing the desired single-phase high-entropy MAX over multiphases of MAX, which is essential for the synthesis of phase-pure high-entropy MXenes. The synthesis of high-entropy MXenes significantly expands the compositional variety of the MXene family to further tune their properties, including electronic, magnetic, electrochemical, catalytic, high temperature stability, and mechanical behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2021, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12815, "End Page": 12825, "Article Number": null, "DOI": "10.1021/acsnullo.1c02775", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.1c02775", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000693105500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JZ; Seyedin, S; Qin, S; Wang, ZY; Moradi, S; Yang, FL; Lynch, PA; Yang, WR; Liu, JQ; Wang, XG; Razal, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jizhen; Seyedin, Shayan; Qin, Si; Wang, Zhiyu; Moradi, Sepehr; Yang, Fangli; Lynch, Peter A.; Yang, Wenrong; Liu, Jingquan; Wang, Xungai; Razal, Joselito M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Conductive Ti3C2Tx MXene Hybrid Fibers for Flexible and Elastic Fiber-Shaped Supercapacitors", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fiber-shaped supercapacitors (FSCs) are promising energy storage solutions for powering miniaturized or wearable electronics. However, the scalable fabrication of fiber electrodes with high electrical conductivity and excellent energy storage performance for use in FSCs remains a challenge. Here, an easily scalable one-step wet-spinning approach is reported to fabricate highly conductive fibers using hybrid formulations of Ti3C2Tx MXene nullosheets and poly(3,4-ethylenedioxythiophene):polystyrene sulfonate. This approach produces fibers with a record conductivity of approximate to 1489 S cm(-1), which is about five times higher than other reported Ti3C2Tx MXene-based fibers (up to approximate to 290 S cm(-1)). The hybrid fiber at approximate to 70 wt% MXene shows a high volumetric capacitance (approximate to 614.5 F cm(-3) at 5 mV s(-1)) and an excellent rate performance (approximate to 375.2 F cm(-3) at 1000 mV s(-1)). When assembled into a free-standing FSC, the energy and power densities of the device reach approximate to 7.13 Wh cm(-3) and approximate to 8249 mW cm(-3), respectively. The excellent strength and flexibility of the hybrid fibers allow them to be wrapped on a silicone elastomer fiber to achieve an elastic FSC with 96% capacitance retention when cyclically stretched to 100% strain. This work demonstrates the potential of MXene-based fiber electrodes and their scalable production for fiber-based energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1804732, "DOI": "10.1002/smll.201804732", "DOI Link": "http://dx.doi.org/10.1002/smll.201804732", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459488300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, MZ; Hua, WB; Xiao, J; Cortiel, D; Chen, WH; Wang, EH; Hu, Z; Gu, QF; Wang, XL; Indris, S; Chou, SL; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Mingzhe; Hua, Weibo; Xiao, Jin; Cortiel, David; Chen, Weihua; Wang, Enhui; Hu, Zhe; Gu, Qinfen; Wang, Xiaolin; Indris, Sylvio; Chou, Shu-Lei; Dou, Shi-Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NASICON-type air-stable and all-climate cathode for sodium-ion batteries with low cost and high-power density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-cost and long-lasting all-climate cathode materials for the sodium ion battery has been one of the key issues for the success of large-scale energy storage. One option is the utilization of earth-abundant elements such as iron. Here, we synthesize a NASICON-type tuneable Na4Fe3(PO4)(2)(P2O7)/C nullocomposite which shows both excellent rate performance and outstanding cycling stability over more than 4400 cycles. Its air stability and all-climate properties are investigated, and its potential as the sodium host in full cells has been studied. A remarkably low volume change of 4.0% is observed. Its high sodium diffusion coefficient has been measured and analysed via first-principles calculations, and its three-dimensional sodium ion diffusion pathways are identified. Our results indicate that this low-cost and environmentally friendly Na4Fe3(PO4)(2)(P2O7)/C nullocomposite could be a competitive candidate material for sodium ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1480, "DOI": "10.1038/s41467-019-09170-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09170-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462858700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JG; Gu, XG; Ma, HL; Peng, Q; Huang, XB; Zheng, XY; Sung, SHP; Shan, GG; Lam, JWY; Shuai, ZG; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianguo; Gu, Xinggui; Ma, Huili; Peng, Qian; Huang, Xiaobo; Zheng, Xiaoyan; Sung, Simon H. P.; Shan, Guogang; Lam, Jacky W. Y.; Shuai, Zhigang; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A facile strategy for realizing room temperature phosphorescence and single molecule white light emission", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research on materials with pure organic room temperature phosphorescence (RTP) and their application as organic single-molecule white light emitters is a hot area and relies on the design of highly efficient pure organic RTP luminogens. Herein, a facile strategy of heavy-atom-participated anion-pi(+) interactions is proposed to construct RTP-active organic salt compounds (1,2,3,4-tetraphenyloxazoliums with different counterions). Those compounds with heavy-atom counterions (bromide and iodide ions) exhibit outstanding RTP due to the external heavy atom effect via anion-pi(+) interactions, evidently supported by the single-crystal X-ray diffraction analysis and theoretical calculation. Their single-molecule white light emission is realized by tuning the degree of crystallization. Such white light emission also performs well in polymer matrices and their use in 3D printing is demonstrated by white light lampshades.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2963, "DOI": "10.1038/s41467-018-05298-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05298-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439971400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Q; Li, AJ; Li, N; Li, S; Zangiabadi, A; Li, TD; Huang, WL; Li, AC; Jin, TW; Song, QQ; Xu, WH; Ni, N; Zhai, HW; Dontigny, M; Zaghib, K; Chuan, XY; Su, D; Yan, K; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Qian; Li, Aijun; Li, Na; Li, Shuang; Zangiabadi, Amirali; Li, Tai-De; Huang, Wenlong; Li, Alex Ceng; Jin, Tianwei; Song, Qingquan; Xu, Weiheng; Ni, null; Zhai, Haowei; Dontigny, Martin; Zaghib, Karim; Chuan, Xiuyun; Su, Dong; Yan, Kai; Yang, Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based nullocomposite Coating", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state Li-metal batteries are promising to improve both safety and energy density compared to conventional Li-ion batteries. However, various high-performance and low-cost solid electrolytes are incompatible with Li, which is indispensable for enhancing energy density. Here, we utilize a chemically inert and mechanically robust boron nitride (BN) film as the interfacial protection to preclude the reduction of Li1.3Al0.3Ti1.7(PO4)(3) (LATP) solid electrolyte by Li, which is validated by in situ transmission electron microscopy. When combined with similar to 1-2 mu m PEO polymer electrolyte at the Li/BN interface, Li/Li symmetric cells show a cycle life of over 500 h at 0.3 mA.cm(-2). In contrast, the same configuration with bare LATP dies after 81 h. The LiFePO4/LATP/BN/PEO/Li solid-state batteries show high capacity retention of 96.6% after 500 cycles. This study offers a general strategy to protect solid electrolytes that are unstable against Li and opens possibilities for adopting them in solid-state Li-metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1510, "End Page": 1522, "Article Number": null, "DOI": "10.1016/j.joule.2019.03.022", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.03.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472067900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, JW; Chen, P; Shukla, A; Krajnc, A; Wang, TS; Li, XM; Doasa, R; Tizei, LHG; Chan, B; Johnstone, DN; Lin, RJ; Schülli, TU; Martens, I; Appadoo, D; Ari, MS; Wang, ZL; Wei, T; Lo, SC; Lu, MY; Li, SC; Namdas, EB; Mali, G; Cheetham, AK; Collins, SM; Chen, V; Wang, LZ; Bennett, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Jingwei; Chen, Peng; Shukla, Atul; Krajnc, Andraz; Wang, Tiesheng; Li, Xuemei; Doasa, Rana; Tizei, Luiz H. G.; Chan, Bun; Johnstone, Duncan N.; Lin, Rijia; Schulli, Tobias U.; Martens, Isaac; Appadoo, Dominique; Ari, Mark S'; Wang, Zhiliang; Wei, Tong; Lo, Shih-Chun; Lu, Mingyuan; Li, Shichun; Namdas, Ebinazar B.; Mali, Gregor; Cheetham, Anthony K.; Collins, Sean M.; Chen, Vicki; Wang, Lianzhou; Bennett, Thomas D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid-phase sintering of lead halide perovskites and metal-organic framework glasses", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite (LHP) semiconductors show exceptional optoelectronic properties. Barriers for their applications, however, lie in their polymorphism, instability to polar solvents, phase segregation, and susceptibility to the leaching of lead ions. We report a family of scalable composites fabricated through liquid-phase sintering of LHPs and metal-organic framework glasses. The glass acts as a matrix for LHPs, effectively stabilizing nonequilibrium perovskite phases through interfacial interactions. These interactions also passivate LHP surface defects and impart bright, narrow-band photoluminescence with a wide gamut for creating white light-emitting diodes (LEDs). The processable composites show high stability against immersion in water and organic solvents as well as exposure to heat, light, air, and ambient humidity. These properties, together with their lead self-sequestration capability, can enable breakthrough applications for LHPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2021, "Volume": 374, "Issue": 6567, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 621, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf4460", "DOI Link": "http://dx.doi.org/10.1126/science.abf4460", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714943400042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JR; Xi, Z; Pan, YT; Spendelow, JS; Duchesne, PN; Su, D; Li, Q; Yu, C; Yin, ZY; Shen, B; Kim, YS; Zhang, P; Sun, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Junrui; Xi, Zheng; Pan, Yung-Tin; Spendelow, Jacob S.; Duchesne, Paul N.; Su, Dong; Li, Qing; Yu, Chao; Yin, Zhouyang; Shen, Bo; Kim, Yu Seung; Zhang, Peng; Sun, Shouheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe Stabilization by Intermetallic L10-FePt and Pt Catalysis Enhancement in L10-FePt/Pt nulloparticles for Efficient Oxygen Reduction Reaction in Fuel Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report in this article a detailed study on how to stabilize a first-row transition metal (M) in an intermetallic L1(0)-MPt alloy nulloparticle (NP) structure and how to surround the L1(0)-MPt with an atomic layer of Pt to enhance the electrocatalysis of Pt for oxygen reduction reaction (ORR) in fuel cell operation conditions. Using 8 nm FePt NPs as an example, we demonstrate that Fe can be stabilized more efficiently in a core/shell structured L1(0)-FePt/Pt with a 5 A Pt shell. The presence of Fe in the alloy core induces the desired compression of the thin Pt shell, especially the two atomic layers of Pt shell, further improving the ORR catalysis. This leads to much enhanced Pt catalysis for ORR in 0.1 M HCIO4 solution (at both room temperature and 60 degrees C) and in the membrane electrode assembly (MEA) at 80 degrees C. The L1(0)-FePt/Pt catalyst has a mass activity of 0.7 A/mg(Pt) from the half-cell ORR test and shows no obvious mass activity loss after 30 000 potential cycles between 0.6 and 0.95 V at 80 degrees C in the MEA, meeting the DOE 2020 target (<40% loss in mass activity). We are extending the concept and preparing other L1(0)-MPt/Pt NPs, such as L1(0)-CoPt/Pt NPs, with reduced NP size as a highly efficient ORR catalyst for automotive fuel cell applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2018, "Volume": 140, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2926, "End Page": 2932, "Article Number": null, "DOI": "10.1021/jacs.7b12829", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b12829", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426617700038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vanda, H; Dai, YT; Wilson, EG; Verpoorte, R; Choi, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vanda, Henni; Dai, Yuntao; Wilson, Erica G.; Verpoorte, Robert; Choi, Young Hae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green solvents from ionic liquids and deep eutectic solvents to natural deep eutectic solvents", "Source Title": "COMPTES RENDUS CHIMIE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural deep eutectic solvents (NADESs) are defined as mixtures of certain molar ratios of natural compounds such as sugars, organic acids, amino acids, and organic bases that are abundant in organisms. The melting points of these mixtures are considerably lower than those of their individual ingredients and far below ambient temperature. The first publications on the NADES concept in 2011 created a great expectation regarding their potential as green solvents that could replace conventional organic solvents in a wide range of applications. This was largely because many of the drawbacks of conventional synthetic ionic liquids (ILs) and deep eutectic solvents (DESs), particularly their toxicity and environmental hazards, could be solved using NADESs. Throughout the last 7 years, the interest in NADESs has increased enormously as reflected by the exponential growth of the number of related publications. The research on NADESs has rapidly expanded particularly into the evaluation of the feasibility of their application in diverse fields such as the extraction of (targeted) bioactive compounds from natural sources, as media for enzymatic or chemical reactions, preservatives of labile compounds, or as vehicles of non-water-soluble compounds for pharmaceutical purposes. Along with the exploration of these potential applications, there have been a large number of other studies related to their physicochemical features, the search for new NADESs, the research into the interactions between NADES components or with solutes, the recovery of solutes from NADES solutions, and the ways of circumventing inherent problems of NADESs such as their high viscosity and the consequent difficulties in handling them. This article contains a review of the applications of NADESs as extraction solvents, reaction media, and preservative, providing also a perspective of their future. (C) 2018 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 21, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 628, "End Page": 638, "Article Number": null, "DOI": "10.1016/j.crci.2018.04.002", "DOI Link": "http://dx.doi.org/10.1016/j.crci.2018.04.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439254700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XQ; Li, JL; Lu, JY; Xu, N; Chen, CL; Min, XZ; Zhu, B; Li, HX; Zhou, L; Zhu, SN; Zhang, TJ; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiuqiang; Li, Jinlei; Lu, Jinyou; Xu, Ning; Chen, Chuanlu; Min, Xinzhe; Zhu, Bin; Li, Hongxia; Zhou, Lin; Zhu, Shining; Zhang, Tiejun; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of Interfacial Solar Vapor Generation by Environmental Energy", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For the first time, we demonstrated that careful structural designs can exploit environmental energy to enhance the performance of an interfacial solar vapor generation device to well above the theoretical limit of vapor output, assuming 100% solar-to-vapor energy transfer efficiency, under various light intensities. This concept can have direct implications in various important processes, such as wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1331, "End Page": 1338, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439698900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Svetlizky, D; Das, M; Zheng, BL; Vyatskikh, AL; Bose, S; Bandyopadhyay, A; Schoenung, JM; Lavernia, EJ; Eliaz, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Svetlizky, David; Das, Mitun; Zheng, Baolong; Vyatskikh, Alexandra L.; Bose, Susmita; Bandyopadhyay, Amit; Schoenung, Julie M.; Lavernia, Enrique J.; Eliaz, Noam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directed energy deposition (DED) additive manufacturing: Physical characteristics, defects, challenges and applications", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Directed energy deposition (DED) is a branch of additive manufacturing (AM) processes in which a feedstock material in the form of powder or wire is delivered to a substrate on which an energy source such as laser beam, electron beam, or plasma/electric arc is simultaneously focused, thus forming a small melt pool and continuously depositing material, layer by layer. DED has several unique advantages compared to other AM processes, such as site-specific deposition and repair, alloy design, and three-dimensional printing of complex shapes. Herein, recent advances as well as the main aspects governing laser-material interactions during the DED process, melt pool thermal behavior, advanced in situ monitoring, and interaction mechanisms are critically reviewed. The most critical processing variables and their influence on the deposited material properties, along with defect formation mechanisms and characterization techniques, are also identified and discussed. An overview of high end applications, current challenges associated with DED processing, and a critical outlook of the technology are presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 603, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 49, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 295, "Article Number": null, "DOI": "10.1016/j.mattod.2021.03.020", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.03.020", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000726828500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, SJ; Zhang, CF; Wong, D; Pedramrazi, Z; Tsai, HZ; Jia, CJ; Moritz, B; Claassen, M; Ryu, H; Kahn, S; Jiang, J; Yan, H; Hashimoto, M; Lu, DH; Moore, RG; Hwang, CC; Hwang, C; Hussain, Z; Chen, YL; Ugeda, MM; Liu, Z; Xie, XM; Devereaux, TP; Crommie, MF; Mo, SK; Shen, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Shujie; Zhang, Chaofan; Wong, Dillon; Pedramrazi, Zahra; Tsai, Hsin-Zon; Jia, Chunjing; Moritz, Brian; Claassen, Martin; Ryu, Hyejin; Kahn, Salman; Jiang, Juan; Yan, Hao; Hashimoto, Makoto; Lu, Donghui; Moore, Robert G.; Hwang, Chan-Cuk; Hwang, Choongyu; Hussain, Zahid; Chen, Yulin; Ugeda, Miguel M.; Liu, Zhi; Xie, Xiaoming; Devereaux, Thomas P.; Crommie, Michael F.; Mo, Sung-Kwan; Shen, Zhi-Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum spin Hall state in monolayer 1T′-WTe2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A quantum spin Hall (QSH) insulator is a novel two-dimensional quantum state of matter that features quantized Hall conductance in the absence of a magnetic field, resulting from topologically protected dissipationless edge states that bridge the energy gap opened by band inversion and strong spin-orbit coupling(1,2). By investigating the electronic structure of epitaxially grown monolayer 1T'-WTe2 using angle-resolved photoemission (ARPES) and first-principles calculations, we observe clear signatures of topological band inversion and bandgap opening, which are the hallmarks of a QSH state. Scanning tunnelling microscopy measurements further confirm the correct crystal structure and the existence of a bulk bandgap, and provide evidence for a modified electronic structure near the edge that is consistent with the expectations for a QSH insulator. Our results establish monolayer 1T'-WTe2 as a new class of QSH insulator with large bandgap in a robust two-dimensional materials family of transition metal dichalcogenides (TMDCs).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 734, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 683, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS4174", "DOI Link": "http://dx.doi.org/10.1038/NPHYS4174", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404629900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Danilovic, N; Subbaraman, R; Chang, KC; Chang, SH; Kang, YJ; Snyder, J; Paulikas, AP; Strmcnik, D; Kim, YT; Myers, D; Stamenkovic, VR; Markovic, NM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Danilovic, Nemanja; Subbaraman, Ramachandran; Chang, Kee Chul; Chang, Seo Hyoung; Kang, Yijin; Snyder, Joshua; Paulikas, Arvydas Paul; Strmcnik, Dusan; Kim, Yong Tae; Myers, Deborah; Stamenkovic, Vojislav R.; Markovic, Nenad M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Using Surface Segregation To Design Stable Ru-Ir Oxides for the Oxygen Evolution Reaction in Acidic Environments", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The methods used to improve catalytic activity are well-established, however elucidating the factors that simultaneously control activity and stability is still lacking, especially for oxygen evolution reaction (OER) catalysts. Here, by studying fundamental links between the activity and stability of well-characterized monometallic and bimetallic oxides, we found that there is generally an inverse relationship between activity and stability. To overcome this limitation, we developed a new synthesis strategy that is based on tuning the near-surface composition of Ru and Ir elements by surface segregation, thereby resulting in the formation of a nullosegregated domain that balances the stability and activity of surface atoms. We demonstrate that a Ru0.5Ir0.5 alloy synthesized by using this method exhibits four-times higher stability than the best Ru-Ir oxygen evolution reaction materials, while still preserving the same activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2014, "Volume": 53, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14016, "End Page": 14021, "Article Number": null, "DOI": "10.1002/anie.201406455", "DOI Link": "http://dx.doi.org/10.1002/anie.201406455", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346484400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SE; Zhang, L; Ma, K; Riegman, M; Chen, F; Ingold, I; Conrad, M; Turker, MZ; Gao, MH; Jiang, XJ; Monette, S; Pauliah, M; Gonen, M; Zanzonico, P; Quinn, T; Wiesner, U; Bradbury, MS; Overholtzer, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sung Eun; Zhang, Li; Ma, Kai; Riegman, Michelle; Chen, Feng; Ingold, Irina; Conrad, Marcus; Turker, Melik Ziya; Gao, Minghui; Jiang, Xuejun; Monette, Sebastien; Pauliah, Mohan; Gonen, Mithat; Zanzonico, Pat; Quinn, Thomas; Wiesner, Ulrich; Bradbury, Michelle S.; Overholtzer, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasmall nulloparticles induce ferroptosis in nutrient-deprived cancer cells and suppress tumour growth", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of cancer-targeting particles with precisely tuned physicochemical properties may enhance the delivery of therapeutics and access to pharmacological targets. However, a molecular-level understanding of the interactions driving the fate of nullomedicine in biological systems remains elusive. Here, we show that ultrasmall (<10 nm in diameter) poly (ethylene glycol)-coated silica nulloparticles, functionalized with melanoma-targeting peptides, can induce a form of programmed cell death known as ferroptosis in starved cancer cells and cancer-bearing mice. Tumour xenografts in mice intravenously injected with nulloparticles using a high-dose multiple injection scheme exhibit reduced growth or regression, in a manner that is reversed by the pharmacological inhibitor of ferroptosis, liproxstatin-1. These data demonstrate that ferroptosis can be targeted by ultrasmall silica nulloparticles and may have therapeutic potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 548, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 11, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 977, "End Page": 985, "Article Number": null, "DOI": "10.1038/nnullo.2016.164", "DOI Link": "http://dx.doi.org/10.1038/nnullo.2016.164", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387530100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, GJ; Cheng, HY; Jones, RB; Feng, YQ; Gong, KD; Li, KJ; Fang, XZ; Tahir, MA; Valev, VK; Zhang, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Guanjun; Cheng, Hanyun; Jones, Robin; Feng, Yiqing; Gong, Kedong; Li, Kejian; Fang, Xiaozhong; Tahir, Muhammad Ali; Valev, Ventsislav Kolev; Zhang, Liwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface-Enhanced Raman Spectroscopy Facilitates the Detection of Microplastics <1 μm in the Environment", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Micro- and nulloplastics are considered one of the top pollutants that threaten the environment, aquatic life, and mammalian (including human) health. Unfortunately, the development of uncomplicated but reliable analytical methods that are sensitive to individual microplastic particles, with sizes smaller than 1 mu m, remains incomplete. Here, we demonstrate the detection and identification of (single) micro- and nulloplastics by using surface-enhanced Raman spectroscopy (SERS) with Klarite substrates. Klarite is an exceptional SERS substrate; it is shaped as a dense grid of inverted pyramidal cavities made of gold. Numerical simulations demonstrate that these cavities (or pits) strongly focus incident light into intense hotspots. We show that Klarite has the potential to facilitate the detection and identification of synthesized and atmospheric/aquatic microplastic (single) particles, with sizes down to 360 nm. We find enhancement factors of up to 2 orders of magnitude for polystyrene analytes. In addition, we detect and identify microplastics with sizes down to 450 nm on Klarite, with samples extracted from ambient, airborne particles. Moreover, we demonstrate Raman mapping as a fast detection technique for submicron microplastic particles. The results show that SERS with Klarite is a facile technique that has the potential to detect and systematically measure nulloplastics in the environment. This research is an important step toward detecting nulloscale plastic particles that may cause toxic effects to mammalian and aquatic life when present in high concentrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2020, "Volume": 54, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15594, "End Page": 15603, "Article Number": null, "DOI": "10.1021/acs.est.0c02317", "DOI Link": "http://dx.doi.org/10.1021/acs.est.0c02317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600100400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wong, A; Lin, Q; Griffin, S; Nicholls, A; Regalbuto, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wong, A.; Lin, Q.; Griffin, S.; Nicholls, A.; Regalbuto, J. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of ultrasmall, homogeneously alloyed, bimetallic nulloparticles on silica supports", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supported nulloparticles containing more than one metal have a variety of applications in sensing, catalysis, and biomedicine. Common synthesis techniques for this type of material often result in large, unalloyed nulloparticles that lack the interactions between the two metals that give the particles their desired characteristics. We demonstrate a relatively simple, effective, generalizable method to produce highly dispersed, well-alloyed bimetallic nulloparticles. Ten permutations of noble and base metals (platinum, palladium, copper, nickel, and cobalt) were synthesized with average particle sizes from 0.9 to 1.4 nullometers, with tight size distributions. High-resolution imaging and x-ray analysis confirmed the homogeneity of alloying in these ultrasmall nulloparticles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2017, "Volume": 358, "Issue": 6369, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1427, "End Page": 1430, "Article Number": null, "DOI": "10.1126/science.aao6538", "DOI Link": "http://dx.doi.org/10.1126/science.aao6538", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417918500040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, LH; Hu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Long-Hua; Hu, Xiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scheme for Achieving a Topological Photonic Crystal by Using Dielectric Material", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We derive in the present work topological photonic states purely based on conventional dielectric material by deforming a honeycomb lattice of cylinders into a triangular lattice of cylinder hexagons. The photonic topology is associated with a pseudo-time-reversal (TR) symmetry constituted by the TR symmetry supported in general by Maxwell equations and the C-6 crystal symmetry upon design, which renders the Kramers doubling in the present photonic system. It is shown explicitly for the transverse magnetic mode that the role of pseudospin is played by the angular momentum of the wave function of the out-of-plane electric field. We solve Maxwell equations and demonstrate the new photonic topology by revealing pseudospin-resolved Berry curvatures of photonic bands and helical edge states characterized by Poynting vectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1271, "Times Cited, All Databases": 1355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2015, "Volume": 114, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 223901, "DOI": "10.1103/PhysRevLett.114.223901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.223901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355563000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, G; Chen, J; Zhang, TJ; Jing, QS; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Guang; Chen, Jun; Zhang, Tiejun; Jing, Qingshen; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Radial-arrayed rotary electrification for high performance triboelectric generator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting mechanical energy is an important route in obtaining cost-effective, clean and sustainable electric energy. Here we report a two-dimensional planar-structured triboelectric generator on the basis of contact electrification. The radial arrays of micro-sized sectors on the contact surfaces enable a high output power of 1.5W (area power density of 19mWcm(-2)) at an efficiency of 24%. The triboelectric generator can effectively harness various ambient motions, including light wind, tap water flow and normal body movement. Through a power management circuit, a triboelectric-generator-based power-supplying system can provide a constant direct-current source for sustainably driving and charging commercial electronics, immediately demonstrating the feasibility of the triboelectric generator as a practical power source. Given exceptional power density, extremely low cost and unique applicability resulting from distinctive mechanism and structure, the triboelectric generator can be applied not only to self-powered electronics but also possibly to power generation at a large scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 771, "Times Cited, All Databases": 802, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3426, "DOI": "10.1038/ncomms4426", "DOI Link": "http://dx.doi.org/10.1038/ncomms4426", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334300400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Christensen, PR; Scheuermann, AM; Loeffler, KE; Helms, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Christensen, Peter R.; Scheuermann, Angelique M.; Loeffler, Kathryn E.; Helms, Brett A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Closed-loop recycling of plastics enabled by dynamic covalent diketoenamine bonds", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recycled plastics are low-value commodities due to residual impurities and the degradation of polymer properties with each cycle of re-use. Plastics that undergo reversible polymerization allow high-value monomers to be recovered and re-manufactured into pristine materials, which should incentivize recycling in closed-loop life cycles. However, monomer recovery is often costly, incompatible with complex mixtures and energy-intensive. Here, we show that next-generation plastics-polymerized using dynamic covalent diketoenamine bonds-allow the recovery of monomers from common additives, even in mixed waste streams. Poly(diketoenamine)s 'click' together from a wide variety of triketones and aromatic or aliphatic amines, yielding only water as a by-product. Recovered monomers can be re-manufactured into the same polymer formulation, without loss of performance, as well as other polymer formulations with differentiated properties. The ease with which poly(diketoenamine) s can be manufactured, used, recycled and re-used-without losing value-points to new directions in designing sustainable polymers with minimal environmental impact.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 470, "Times Cited, All Databases": 507, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 11, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 442, "End Page": 448, "Article Number": null, "DOI": "10.1038/s41557-019-0249-2", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0249-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465518600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, Z; Giraudon, JM; Nuns, N; Simon, P; De Geyter, N; Morent, R; Lamonier, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Z.; Giraudon, J. -M.; Nuns, N.; Simon, P.; De Geyter, N.; Morent, R.; Lamonier, J. -F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of the preparation method on the activity of copper-manganese oxides for toluene total oxidation", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper manganese oxides were prepared either by a co-precipitation method using metal nitrates as precursors, tetramethylammonium hydroxide (TMAH) as precipitant or by a redox-precipitation method using manganese acetate and copper nitrate as precursors, permanganate of potassium as oxidant. Copper manganese oxides synthesized by the redox method and calcined at 300 degrees C were also doped with Pt and Pd (0.5 wt%). The materials were characterized by ICP-OES, X-ray powder diffraction, N-2 adsorption/desorption analysis, temperature-programmed reduction, X-ray photoelectron spectroscopy and time-of-flight secondary-ion mass spectrometry. The catalyst properties were assessed in total oxidation of toluene and compared with those of the corresponding single oxides and of a commercial Hopcalite catalyst. Copper manganese oxides were proved to be more active than the single oxides whatever the method of preparation used. CuMnOx prepared via redox method were more active than the catalyst prepared by co-precipitation and compared favorably with the commercial Hopcalite. The overall characterization results revealed that the redox method can ensure a good dispersion of copper in close interaction with manganese preserving more active sites at the outermost layers of the catalyst in comparison with the catalyst obtained via co-precipitation. However all the catalysts deactivate to some extent at the earlier stages of the reaction before to reach a steady-state. For redox catalysts calcined at 300 degrees C, although the dispersion of trace amount of noble metals does not ensure a better activity, adding Pt allows to get a better resistance to deactivation. Additionally it is to be noticeable that the catalyst using redox-precipitation method calcined at 200 degrees C outperforms the commercial hopcalite overtime on stream. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 223, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 154, "End Page": 166, "Article Number": null, "DOI": "10.1016/j.apcatb.2017.06.072", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2017.06.072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419411800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Qu, MY; Wang, CR; Xue, YM; Huang, H; Chen, QM; Sun, WJ; Zhou, XW; Xu, GH; Jiang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jing; Qu, Moyuan; Wang, Canran; Xue, Yumeng; Huang, Hui; Chen, Qianming; Sun, Wujin; Zhou, Xingwu; Xu, Guihua; Jiang, Xing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Dual-Cross-Linked Hydrogel Patch for Promoting Diabetic Wound Healing", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diabetic wound treatment faces significant challenges in clinical settings. Alternative treatment approaches are needed. Continuous bleeding, disordered inflammatory regulation, obstruction of cell proliferation, and disturbance of tissue remodeling are the main characteristics of diabetic wound healing. Hydrogels made of either naturally derived or synthetic materials can potentially be designed with a variety of functions for managing the healing process of chronic wounds. Here, a hemostatic and anti-inflammatory hydrogel patch is designed for promoting diabetic wound healing. The hydrogel patch is derived from dual-cross-linked methacryloyl-substituted Bletilla Striata polysaccharide (B) and gelatin (G) via ultraviolet (UV) light. It is demonstrated that the B-G hydrogel can effectively regulate the M1/M2 phenotype of macrophages, significantly promote the proliferation and migration of fibroblasts in vitro, and accelerate angiogenesis. It can boost wound closure by normalizing epidermal tissue regeneration and depositing collagen appropriately in vivo without exogenous cytokine supplementation. Overall, the B-G bioactive hydrogel can promote diabetic wound healing in a simple, economical, effective, and safe manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 18, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2106172, "DOI": "10.1002/smll.202106172", "DOI Link": "http://dx.doi.org/10.1002/smll.202106172", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771921700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XG; Wei, JW; Zhang, YK; Qian, BB; Jia, Q; Liu, J; Zhao, XJ; Shao, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xiaogu; Wei, Jiawen; Zhang, Yunke; Qian, BinBin; Jia, Qi; Liu, Jun; Zhao, Xiaojia; Shao, Gaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralight Magnetic and Dielectric Aerogels Achieved by Metal-Organic Framework Initiated Gelation of Graphene Oxide for Enhanced Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of a convenient methodology for synthesizing the hierarchically porous aerogels comprising metal-organic frameworks (MOFs) and graphene oxide (GO) building blocks that exhibit an ultralow density and uniformly distributed MOFs on GO sheets is important for various applications. Herein, we report a facile route for synthesizing MOF/reduced GO (rGO) aerogels based on the gelation of GO, which is directly initiated using MOF crystals. Free metal ions exposed on the surface of MIL-88A nullorods act as linkers that bind GO nullosheets to a three-dimensional porous network via metal-oxygen covalent or electrostatic interactions. The MOF/rGO-derived magnetic and dielectric aerogels Fe3O4@C/rGO and Ni-doped Fe3O4@C/rGO show notable microwave absorption (MA) performance, simultaneously achieving strong absorption and broad bandwidth at low thickness of 2.5 (-58.1 dB and 6.48 GHz) and 2.8 mm (-46.2 dB and 7.92 GHz) with ultralow filling contents of 0.7 and 0.6 wt%, respectively. The microwave attenuation ability of the prepared aerogels is further confirmed via a radar cross-sectional simulation, which is attributed to the synergistic effects of their hierarchically porous structures and heterointerface engineering. This work provides an effective pathway for fabricating hierarchically porous MOF/rGO hybrid aerogels and offers magnetic and dielectric aerogels for ultralight MA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107, "DOI": "10.1007/s40820-022-00851-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00851-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784977100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Culp, TE; Khara, B; Brickey, KP; Geitner, M; Zimudzi, TJ; Wilbur, JD; Jons, SD; Roy, A; Paul, M; Ganapathysubramanian, B; Zydney, AL; Kumar, M; Gomez, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Culp, Tyler E.; Khara, Biswajit; Brickey, Kaitlyn P.; Geitner, Michael; Zimudzi, Tawanda J.; Wilbur, Jeffrey D.; Jons, Steven D.; Roy, Abhishek; Paul, Mou; Ganapathysubramanian, Baskar; Zydney, Andrew L.; Kumar, Manish; Gomez, Enrique D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale control of internal inhomogeneity enhances water transport in desalination membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biological membranes can achieve remarkably high permeabilities, while maintaining ideal selectivities, by relying on well-defined internal nulloscale structures in the form of membrane proteins. Here, we apply such design strategies to desalination membranes. A series of polyamide desalination membranes-which were synthesized in an industrial-scale manufacturing line and varied in processing conditions but retained similar chemical compositions-show increasing water permeability and active layer thickness with constant sodium chloride selectivity. Transmission electron microscopy measurements enabled us to determine nulloscale three-dimensional polyamide density maps and predict water permeability with zero adjustable parameters. Density fluctuations are detrimental to water transport, which makes systematic control over nulloscale polyamide inhomogeneity a key route to maximizing water permeability without sacrificing salt selectivity in desalination membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 371, "Issue": 6524, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": 75, "Article Number": null, "DOI": "10.1126/science.abb8518", "DOI Link": "http://dx.doi.org/10.1126/science.abb8518", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604963800043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Ren, X; Sun, SN; Liu, Z; Xi, SB; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yuanmiao; Ren, Xiao; Sun, Shengnull; Liu, Zheng; Xi, Shibo; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering High-Spin State Cobalt Cations in Spinel Zinc Cobalt Oxide for Spin Channel Propagation and Active Site Enhancement in Water Oxidation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spinel zinc cobalt oxide (ZnCo2O4) is not considered as a superior catalyst for the electrochemical oxygen evolution reaction (OER), which is the bottleneck reaction in water-electrolysis. Herein, taking advantage of density functional theory (DFT) calculations, we find that the existence of low-spin (LS) state cobalt cations hinders the OER activity of spinel zinc cobalt oxide, as the t(2g)(6)e(g)(0) configuration gives rise to purely localized electronic structure and exhibits poor binding affinity to the key reaction intermediate. Increasing the spin state of cobalt cations in spinel ZnCo2O4 is found to propagate a spin channel to promote spin-selected charge transport during OER and generate better active sites for intermediates adsorption. The experiments find increasing the calcination temperature a facile approach to engineer high-spin (HS) state cobalt cations in ZnCo2O4, while not working for Co3O4. The activity of the best spin-state-engineered ZnCo2O4 outperforms other typical Co-based oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2021, "Volume": 60, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14536, "End Page": 14544, "Article Number": null, "DOI": "10.1002/anie.202102452", "DOI Link": "http://dx.doi.org/10.1002/anie.202102452", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000651092100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, SF; Wei, QW; Huang, K; Cheng, HM; Ren, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, Songfeng; Wei, Qinwei; Huang, Kun; Cheng, Hui-Ming; Ren, Wencai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene oxide is highly desired for printing electronics, catalysis, energy storage, separation membranes, biomedicine, and composites. However, the present synthesis methods depend on the reactions of graphite with mixed strong oxidants, which suffer from explosion risk, serious environmental pollution, and long-reaction time up to hundreds of hours. Here, we report a scalable, safe and green method to synthesize graphene oxide with a high yield based on water electrolytic oxidation of graphite. The graphite lattice is fully oxidized within a few seconds in our electrochemical oxidation reaction, and the graphene oxide obtained is similar to those achieved by the present methods. We also discuss the synthesis mechanism and demonstrate continuous and controlled synthesis of graphene oxide and its use for transparent conductive films, strong papers, and ultra-light elastic aerogels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 538, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 145, "DOI": "10.1038/s41467-017-02479-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02479-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419676700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hope, MA; Forse, AC; Griffith, KJ; Lukatskaya, MR; Ghidiu, M; Gogotsi, Y; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hope, Michael A.; Forse, Alexander C.; Griffith, Kent J.; Lukatskaya, Maria R.; Ghidiu, Michael; Gogotsi, Yury; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NMR reveals the surface functionalisation of Ti3C2 MXene", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "H-1 and F-19 NMR experiments have identified and quantified the internal surface terminations of Ti3C2Tx MXene. -F and -OH terminations are shown to be intimately mixed and there are found to be significantly fewer -OH terminations than -F and -O, with the proportions highly dependent on the synthesis method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 740, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2016, "Volume": 18, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5099, "End Page": 5102, "Article Number": null, "DOI": "10.1039/c6cp00330c", "DOI Link": "http://dx.doi.org/10.1039/c6cp00330c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370421500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaolei; Zhu, Yuntian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterogeneous materials: a new class of materials with unprecedented mechanical properties", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we present a perspective on heterogeneous materials, a new class of materials possessing superior combinations of strength and ductility that are not accessible to their homogeneous counterparts. Heterogeneous materials consist of domains with dramatic strength differences. The domain sizes may vary in the range of micrometers to millimeters. Large strain gradients near domain interfaces are produced during deformation, which produces a significant back-stress to strengthen the material and to produce high back-stress work hardening for good ductility. High interface density is required to maximize the back-stress, which is a new strengthening mechanism for improving mechanical properties. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1048, "Times Cited, All Databases": 1104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 527, "End Page": 532, "Article Number": null, "DOI": "10.1080/21663831.2017.1343208", "DOI Link": "http://dx.doi.org/10.1080/21663831.2017.1343208", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428140600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roldán-Carmona, C; Malinkiewicz, O; Soriano, A; Espallargas, GM; Garcia, A; Reinecke, P; Kroyer, T; Dar, MI; Nazeeruddin, MK; Bolink, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roldan-Carmona, Cristina; Malinkiewicz, Olga; Soriano, Alejandra; Minguez Espallargas, Guillermo; Garcia, Ana; Reinecke, Patrick; Kroyer, Thomas; Dar, M. Ibrahim; Nazeeruddin, Mohammad Khaja; Bolink, Henk J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible high efficiency perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible perovskite based solar cells with power conversion efficiencies of 7% have been prepared on PET based conductive substrates. Extended bending of the devices does not deteriorate their performance demonstrating their suitability for roll to roll processing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 994, "End Page": 997, "Article Number": null, "DOI": "10.1039/c3ee43619e", "DOI Link": "http://dx.doi.org/10.1039/c3ee43619e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333203900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trevisanello, E; Ruess, R; Conforto, G; Richter, FH; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trevisanello, Enrico; Ruess, Raffael; Conforto, Gioele; Richter, Felix H.; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polycrystalline and Single Crystalline NCM Cathode Materials-Quantifying Particle Cracking, Active Surface Area, and Lithium Diffusion", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Representatives of the LixNi1-y-zCoyMnzO2 (NCM) family of cathode active materials (CAMs) with high nickel content are becoming the CAM of choice for high performance lithium-ion batteries. In addition to high specific capacities, these layered oxides offer high specific energy, power, and long cycle life. Recently, the development of single crystalline particles of NCM has enabled even longer lifetimes due to achieving higher Coulomb efficiencies. In this work, the performance of NCM materials with different particle size and morphology is explored in terms of key parameters such as the charge-transfer resistance and the chemical diffusion coefficient of lithium. Cracking of secondary particles leads to liquid electrolyte infiltration in the CAM, lowering the charge-transfer resistance and increasing the apparent diffusion coefficient by more than one order of magnitude. In contrast, these effects are not observed with single-crystalline NCM, which is mostly free of cracks after cycling. Consequently, severe kinetic limitations are observed when cycling large uncracked secondary particles at low potential and capacity. These results demonstrate that cracking of polycrystalline particles of NCM is not solely detrimental but helps to achieve high reversible capacities and rate capability. Thus, optimization of CAMs size and morphology is decisive to achieve good rate capability with high-nickel NCMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 11, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003400, "DOI": "10.1002/aenm.202003400", "DOI Link": "http://dx.doi.org/10.1002/aenm.202003400", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631881600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XR; Zhou, XC; Jing, Y; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xiaorong; Zhou, Xiaocheng; Jing, Yu; Li, Yafei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical synthesis of urea on MBenes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Urea is an important raw material in the chemical industry and is widely used as a nitrogen source in chemical fertilizers. The current industrial urea synthesis not only requires harsh reaction conditions, but also consumes most of the NH3 obtained through artificial synthesis. The conversion of N-2 and CO2 into urea through electrochemical reactions under ambient conditions represents a novel green urea synthesis method. However, the large-scale promotion of this method is limited by the lack of suitable electrocatalysts. Here, by means of density functional theory computations, we systematically study the catalytic activity of three experimentally available two-dimensional metal borides (MBenes), Mo2B2, Ti2B2, and Cr2B2 toward simultaneous electrocatalytic coupling of N-2 and CO2 to produce urea under ambient conditions. According to our results, these three MBenes not only have superior intrinsic basal activity for urea formation, with limiting potentials ranging from -0.49 to -0.65eV, but also can significantly suppress the competitive reaction of N-2 reduction to NH3. In particular, 2D Mo2B2 and Cr2B2 possess superior capacity to suppress surface oxidation and self-corrosion under electrochemical reaction conditions, rendering them relatively promising electrocatalysts for urea production. Our work paves the way for the electrochemical synthesis of urea. The conversion of N-2 and CO2 into urea through electrochemical reactions under ambient conditions represents a novel green urea synthesis method. Here, the authors demonstrate that two-dimensional transition metal borides can serve as effective catalysts for electrochemical urea synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4080, "DOI": "10.1038/s41467-021-24400-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24400-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672163900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, CX; Dong, ZG; Li, YH; Zhao, HG; Huang, XY; Zhou, ZC; Jiang, JW; Long, YZ; Jiang, PK; Zhang, TY; Sun, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Cenxiao; Dong, Zhigang; Li, Yehua; Zhao, Haiguang; Huang, Xingyi; Zhou, Zhaocai; Jiang, Jin-Wu; Long, Yun-Ze; Jiang, Pingkai; Zhang, Tong-Yi; Sun, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high performance wearable strain sensor with advanced thermal management for motion monitoring", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Resistance change under mechanical stimuli arouses mass operational heat, damaging the performance, lifetime, and reliability of stretchable electronic devices, therefore rapid thermal heat dissipating is necessary. Here we report a stretchable strain sensor with outstanding thermal management. Besides a high stretchability and sensitivity testified by human motion monitoring, as well as long-term durability, an enhanced thermal conductivity from the casted thermoplastic polyurethane-boron nitride nullosheets layer helps rapid heat transmission to the environments, while the porous electrospun fibrous thermoplastic polyurethane membrane leads to thermal insulation. A 32% drop of the real time saturated temperature is achieved. For the first time we in-situ investigated the dynamic operational temperature fluctuation of stretchable electronics under repeating stretching-releasing processes. Finally, cytotoxicity test confirms that the nullofillers are tightly restricted in the nullocomposites, making it harmless to human health. All the results prove it an excellent candidate for the next-generation of wearable devices. Though stretchable strain sensors are attractive for next-generation applications due to their high sensitivity, heat generated in these devices limits their reliability. Here, the authors report boron nitride nullosheet-based stretchable strain sensors with enhanced thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3530, "DOI": "10.1038/s41467-020-17301-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17301-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000554533700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SL; Xu, M; Peng, TY; Zhang, CX; Li, T; Hussain, I; Wang, JY; Tan, BE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shaolei; Xu, Min; Peng, Tianyou; Zhang, Chengxin; Li, Tao; Hussain, Irshad; Wang, Jingyu; Tan, Bien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous hypercrosslinked polymer-TiO2-graphene composite photocatalysts for visible-light-driven CO2 conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Significant efforts have been devoted to develop efficient visible-light-driven photocatalysts for the conversion of CO2 to chemical fuels. The photocatalytic efficiency for this transformation largely depends on CO2 adsorption and diffusion. However, the CO2 adsorption on the surface of photocatalysts is generally low due to their low specific surface area and the lack of matched pores. Here we report a well-defined porous hypercrosslinked polymer-TiO2-graphene composite structure with relatively high surface area i.e., 988 m(2) g(-1) and CO2 uptake capacity i.e., 12.87 wt%. This composite shows high photocatalytic performance especially for CH4 production, i.e., 27.62 mu mol g(-1) h(-1), under mild reaction conditions without the use of sacrificial reagents or precious metal co-catalysts. The enhanced CO2 reactivity can be ascribed to their improved CO2 adsorption and diffusion, visible-light absorption, and photo-generated charge separation efficiency. This strategy provides new insights into the combination of microporous organic polymers with photocatalysts for solar-to-fuel conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 676, "DOI": "10.1038/s41467-019-08651-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08651-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458175700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, LQ; Wan, CJ; Guo, LQ; Shi, Y; Wan, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Li Qiang; Wan, Chang Jin; Guo, Li Qiang; Shi, Yi; Wan, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial synapse network on inorganic proton conductor for neuromorphic systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The basic units in our brain are neurons, and each neuron has more than 1,000 synapse connections. Synapse is the basic structure for information transfer in an ever-changing manner, and short-term plasticity allows synapses to perform critical computational functions in neural circuits. Therefore, the major challenge for the hardware implementation of neuromorphic computation is to develop artificial synapse network. Here in-plane lateral-coupled oxide-based artificial synapse network coupled by proton neurotransmitters are selfassembled on glass substrates at room-temperature. A strong lateral modulation is observed due to the proton-related electrical-double-layer effect. Short-term plasticity behaviours, including paired-pulse facilitation, dynamic filtering and spatiotemporally correlated signal processing are mimicked. Such laterally coupled oxide-based protonic/electronic hybrid artificial synapse network proposed here is interesting for building future neuromorphic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 730, "Times Cited, All Databases": 760, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3158, "DOI": "10.1038/ncomms4158", "DOI Link": "http://dx.doi.org/10.1038/ncomms4158", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331103400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tofa, TS; Kunjali, KL; Paul, S; Dutta, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tofa, Tajkia Syeed; Kunjali, Karthik Laxman; Paul, Swaraj; Dutta, Joydeep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible light photocatalytic degradation of microplastic residues with zinc oxide nullorods", "Source Title": "ENVIRONMENTAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastics have recently become a major environmental issue due to their ubiquitous distribution, uncontrolled environmental occurrences, small sizes and long lifetimes. Actual remediation methods include filtration, incineration and advanced oxidation processes such as ozonation, but those methods require high energy or generate unwanted by-products. Here we tested the degradation of fragmented, low-density polyethylene (LDPE) microplastic residues, by visible light-induced heterogeneous photocatalysis activated by zinc oxide nullorods. The reaction was monitored using Fourier-transform infrared spectroscopy, dynamic mechanical analyser and optical imaging. Results show a 30% increase of the carbonyl index of residues, and an increase of brittleness accompanied by a large number of wrinkles, cracks and cavities on the surface. The degree of oxidation was directly proportional to the catalyst surface area. A mechanism for polyethylene degradation is proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1341, "End Page": 1346, "Article Number": null, "DOI": "10.1007/s10311-019-00859-z", "DOI Link": "http://dx.doi.org/10.1007/s10311-019-00859-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481434000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HW; Bukas, VJ; Park, H; Park, S; Diederichsen, KM; Lim, J; Cho, YH; Kim, J; Kim, W; Han, TH; Voss, J; Luntz, AC; McCloskey, BD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyo Won; Bukas, Vanessa J.; Park, Hun; Park, Sojung; Diederichsen, Kyle M.; Lim, Jinkyu; Cho, Young Hoon; Kim, Juyoung; Kim, Wooyul; Han, Tae Hee; Voss, Johannes; Luntz, Alan C.; McCloskey, Bryan D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanisms of Two-Electron and Four-Electron Electrochemical Oxygen Reduction Reactions at Nitrogen-Doped Reduced Graphene Oxide", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Doped carbon-based systems have been extensively studied over the past decade as active electrocatalysts for both the two-electron (2e(-)) and four-electron (4e(-)) oxygen reduction reactions (ORRs). However, the mechanisms for ORR are generally poorly understood. Here, we report an extensive experimental and first-principles theoretical study of the ORR at nitrogen-doped reduced graphene oxide (NrGO). We synthesize three distinct NrGO catalysts and investigate their chemical and structural properties in detail via X-ray photoelectron spectroscopy, infrared and Raman spectroscopies, high-resolution transmission electron microscopy, and thin-film electrical conductivity. ORR experiments include the pH dependences of 2e(-) versus 4e(-) ORR selectivity, ORR onset potentials, Tafel slopes, and H/D kinetic isotope effects. These experiments show very different ORR behavior for the three catalysts, in terms of both selectivity and the underlying mechanism, which proceeds either via coupled proton-electron transfers (CPETs) or non-CPETs. Reasonable structural models developed from density functional theory rationalize this behavior. The key determinullt between CPET vs non-CPET mechanisms is the electron density at the Fermi level under operating ORR conditions. Regardless of the reaction mechanism or electrolyte pH, however, we identify the ORR active sites as sp(2) carbons that are located next to oxide regions. This assignment highlights the importance of oxygen functional groups, while details of (modest) N-doping may still affect the overall catalytic activity, and likely also the selectivity, by modifying the general chemical environment around the active site.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 852, "End Page": "+", "Article Number": null, "DOI": "10.1021/acscatal.9b04106", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b04106", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506725100093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, BJ; Fabbri, E; Abbott, DF; Cheng, X; Clark, AH; Nachtegaal, M; Borlaf, M; Castelli, IE; Graule, T; Schmidt, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Bae-Jung; Fabbri, Emiliana; Abbott, Daniel F.; Cheng, Xi; Clark, Adam H.; Nachtegaal, Maarten; Borlaf, Mario; Castelli, Ivano E.; Graule, Thomas; Schmidt, Thomas J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional Role of Fe-Doping in Co-Based Perovskite Oxide Catalysts for Oxygen Evolution Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite oxides have been at the forefront among catalysts for the oxygen evolution reaction (OER) in alkaline media offering a higher degree of freedom in cation arrangement. Several highly OER active Co-based perovskites have been known to show extraordinary activities and stabilities when the B-site is partially occupied by Fe. At the current stage, the role of Fe in enhancing the OER activity and stability is still unclear. In order to elucidate the roles of Co and Fe in the OER mechanism of cubic perovskites, two prospective perovskite oxides, La0.2Sr0.8Co1-xFexO3-delta and Ba0.5Sr0.3Co1-xFexO3-delta with x = 0 and 0.2, were prepared by flame spray synthesis as nulloparticles. This study highlights the importance of Fe in order to achieve high OER activity and stability by drawing relations between their physicochemical and electrochemical properties. Ex situ and operando X-ray absorption spectroscopy (XAS) was used to study the local electronic and geometric structure under oxygen evolving conditions. In parallel, density function theory computational studies were conducted to provide theoretical insights into our findings. Our findings show that the incorporation of Fe into Co-based perovskite oxides alters intrinsic properties rendering efficient OER activity and prolonged stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2019, "Volume": 141, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5231, "End Page": 5240, "Article Number": null, "DOI": "10.1021/jacs.8b12101", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b12101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463843700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumaravel, V; Bartlett, J; Pillai, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumaravel, Vignesh; Bartlett, John; Pillai, Suresh C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoelectrochemical Conversion of Carbon Dioxide (CO2) into Fuels and Value-Added Products", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of carbon dioxide (CO2) into fuels and value-added products is one of the most significant inventions to address the global warming and energy needs. Photoelectrochemical (PEC) CO2 conversion can be considered as an artificial photosynthesis technique that produces formate, formaldehyde, formic acid, methane, methanol, ethanol, etc. Recent advances in electrode materials, mechanisms, kinetics, thermodynamics, and reactor designs of PEC CO2 conversion have been comprehensively reviewed in this article. The adsorption and activation of CO2/intermediates at the electrode surface are the key steps for improving the kinetics of CO2 conversion. PEC efficiency could be upgraded through the utilization of 2D/3D materials, plasmonic metals, carbon-based catalysts, porous nullostructures, metal-organic frameworks, molecular catalysts, and biological molecules. The defect engineered (by cation/anion vacancy, crystal distortion, pits, and creation of oxygen vacancies) 2D/3D materials, Z-scheme heterojunctions, bioelectrodes, and tandem photovoltaic-PEC reactors are suitable options to enhance the efficiency at low external bias.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 486, "End Page": 519, "Article Number": null, "DOI": "10.1021/acsenergylett.9b02585", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02585", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514258200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, HL; Simsek, E; Ma, T; Johnson, NS; Qian, SX; Cissé, C; Stasak, D; Al Hasan, N; Zhou, L; Hwang, YH; Radermacher, R; Levitas, VI; Kramer, MJ; Zaeem, MA; Stebner, AP; Ott, RT; Cui, J; Takeuchi, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Huilong; Simsek, Emrah; Ma, Tao; Johnson, Nathan S.; Qian, Suxin; Cisse, Cheikh; Stasak, Drew; Al Hasan, Naila; Zhou, Lin; Hwang, Yunho; Radermacher, Reinhard; Levitas, Valery I.; Kramer, Matthew J.; Zaeem, Mohsen Asle; Stebner, Aaron P.; Ott, Ryan T.; Cui, Jun; Takeuchi, Ichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fatigue-resistant high-performance elastocaloric materials made by additive manufacturing", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elastocaloric cooling, a solid-state cooling technology, exploits the latent heat released and absorbed by stress-induced phase transformations. Hysteresis associated with transformation, however, is detrimental to efficient energy conversion and functional durability. We have created thermodynamically efficient, low-hysteresis elastocaloric cooling materials by means of additive manufacturing of nickel-titanium. The use of a localized molten environment and near-eutectic mixing of elemental powders has led to the formation of nullocomposite microstructures composed of a nickel-rich intermetallic compound interspersed among a binary alloy matrix. The microstructure allowed extremely small hysteresis in quasi-linear stress-strain behaviors-enhancing the materials efficiency by a factor of four to seven-and repeatable elastocaloric performance over 1 million cycles. Implementing additive manufacturing to elastocaloric cooling materials enables distinct microstructure control of high-performance metallic refrigerants with long fatigue life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2019, "Volume": 366, "Issue": 6469, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1116, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax7616", "DOI Link": "http://dx.doi.org/10.1126/science.aax7616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500039200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YG; Dongfang, N; Triana, CA; Huang, C; Erni, R; Wan, WC; Li, JG; Stoian, D; Pan, L; Zhang, P; Lan, JG; Iannuzzi, M; Patzke, GR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yonggui; Dongfang, nullchen; Triana, Carlos A.; Huang, Chong; Erni, Rolf; Wan, Wenchao; Li, Jingguo; Stoian, Dragos; Pan, Long; Zhang, Ping; Lan, Jinggang; Iannuzzi, Marcella; Patzke, Greta R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamics and control of active sites in hierarchically nullostructured cobalt phosphide/chalcogenide-based electrocatalysts for water splitting", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of efficient electrocatalysts for industrial water splitting is essential to generate sustainable hydrogen fuel. However, a comprehensive understanding of the complex catalytic mechanisms under harsh reaction conditions remains a major challenge. We apply a self-templated strategy to introduce hierarchically nullostructured all-surface Fe-doped cobalt phosphide nulloboxes (Co@CoFe-P NBs) as alternative electrocatalysts for industrial-scale applications. Operando Raman spectroscopy and X-ray absorption spectroscopy (XAS) experiments were carried out to track the dynamics of their structural reconstruction and the real catalytically active intermediates during water splitting. Our operando analyses reveal that partial Fe substitution in cobalt phosphides promotes a structural reconstruction into P-Co-O-Fe-P configurations with low-valence metal centers (M-0/M+) during the hydrogen evolution reaction (HER). Results from density functional theory (DFT) demonstrate that these in situ reconstructed configurations significantly enhance the HER performance by lowering the energy barrier for water dissociation and by facilitating the adsorption/desorption of HER intermediates (H*). The competitive activity in the oxygen evolution reaction (OER) arises from the transformation of the reconstructed P-Co-O-Fe-P configurations into oxygen-bridged, high-valence Co-IV-O-Fe-IV moieties as true active intermediates. In sharp contrast, the formation of such Co-III/IV-O-Fe-III/IV moieties in Co-FeOOH is hindered under the same conditions, which outlines the key advantages of phosphide-based electrocatalysts. Ex situ studies of the as-synthesized reference cobalt sulfides (Co-S), Fe doped cobalt selenides (Co@CoFe-Se), and Fe doped cobalt tellurides (Co@CoFe-Te) further corroborate the observed structural transformations. These insights are vital to systematically exploit the intrinsic catalytic mechanisms of non-oxide, low-cost, and robust overall water splitting electrocatalysts for future energy conversion and storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2022, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 727, "End Page": 739, "Article Number": null, "DOI": "10.1039/d1ee02249k", "DOI Link": "http://dx.doi.org/10.1039/d1ee02249k", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739588500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hamad, K; Kaseem, M; Yang, HW; Deri, F; Ko, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hamad, K.; Kaseem, M.; Yang, H. W.; Deri, F.; Ko, Y. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Properties and medical applications of polylactic acid: A review", "Source Title": "EXPRESS POLYMER LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polylactic acid (PLA), one of the well-known biodegradable polyesters, has been studied extensively for tissue engineering and drug delivery systems, and it was also used widely in human medicine. A new method to synthesize PLA (ring-opening polymerization), which allowed the economical production of a high molecular weight PLA polymer, broadened its applications, and this processing would be a potential substitute for petroleum-based products. This review described the principles of the polymerization reactions of PLA and, then, outlined the various materials properties affecting the performance of PLA polymer, such as rheological, mechanical, thermal, and barrier properties as well as the processing technologies which were used to fabricate products based on PLA. In addition, the biodegradation processes of products which were shaped from PLA were discussed and reviewed. The potential applications of PLA in the medical fields, such as tissue engineering, wound management, drugs delivery, and orthopedic devices, were also highlighted.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 508, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 435, "End Page": 455, "Article Number": null, "DOI": "10.3144/expresspolymlett.2015.42", "DOI Link": "http://dx.doi.org/10.3144/expresspolymlett.2015.42", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350698600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HM; Liao, XB; Guan, YP; Xiang, Y; Li, M; Zhang, WF; Zhu, XY; Ming, H; Lu, L; Qiu, JY; Huang, YQ; Cao, GP; Yang, YS; Mai, LQ; Zhao, Y; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huimin; Liao, Xiaobin; Guan, Yuepeng; Xiang, Yu; Li, Meng; Zhang, Wenfeng; Zhu, Xiayu; Ming, Hai; Lu, Lin; Qiu, Jingyi; Huang, Yaqin; Cao, Gaoping; Yang, Yusheng; Mai, Liqiang; Zhao, Yan; Zhang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithiophilic-lithiophobic gradient interfacial layer for a highly stable lithium metal anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The long-standing issue of lithium dendrite growth during repeated deposition or dissolution processes hinders the practical use of lithium-metal anodes for high-energy density batteries. Here, we demonstrate a promising lithiophilic-lithiophobic gradient interfacial layer strategy in which the bottom lithiophilic zinc oxide/carbon nullotube sublayer tightly anchors the whole layer onto the lithium foil, facilitating the formation of a stable solid electrolyte interphase, and prevents the formation of an intermediate mossy lithium corrosion layer. Together with the top lithiophobic carbon nullotube sublayer, this gradient interfacial layer can effectively suppress dendrite growth and ensure ultralong-term stable lithium stripping/plating. This strategy is further demonstrated to provide substantially improved cycle performance in copper current collector, 10 cm(2) pouch cell and lithium-sulfur batteries, which, coupled with a simple fabrication process and wide applicability in various materials for lithium-metal protection, makes the lithiophilic-lithiophobic gradient interfacial layer a favored strategy for next-generation lithium-metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 585, "Times Cited, All Databases": 636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3729, "DOI": "10.1038/s41467-018-06126-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06126-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444494800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HL; Li, JR; Wang, KK; Han, TT; Tong, MM; Li, LS; Xie, YB; Yang, QY; Liu, DH; Zhong, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Hongliang; Li, Jian-Rong; Wang, Keke; Han, Tongtong; Tong, Minman; Li, Liangsha; Xie, Yabo; Yang, Qingyuan; Liu, Dahuan; Zhong, Chongli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) have recently emerged as a new type of nulloporous materials with tailorable structures and functions. Usually, MOFs have uniform pores smaller than 2 nm in size, limiting their practical applications in some cases. Although a few approaches have been adopted to prepare MOFs with larger pores, it is still challenging to synthesize hierarchical-pore MOFs (H-MOFs) with high structural controllability and good stability. Here we demonstrate a facile and versatile method, an in situ self-assembly template strategy for fabricating stable H-MOFs, in which multi-scale soluble and/or acid-sensitive metal-organic assembly (MOA) fragments form during the reactions between metal ions and organic ligands (to construct MOFs), and act as removable dynamic chemical templates. This general strategy was successfully used to prepare various H-MOFs that show rich porous properties and potential applications, such as in large molecule adsorption. Notably, the mesopore sizes of the H-MOFs can be tuned by varying the amount of templates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8847, "DOI": "10.1038/ncomms9847", "DOI Link": "http://dx.doi.org/10.1038/ncomms9847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366295800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Toh, CT; Zhang, HJ; Lin, JH; Mayorov, AS; Wang, YP; Orofeo, CM; Ferry, DB; Andersen, H; Kakenov, N; Guo, ZL; Abidi, IH; Sims, H; Suenaga, K; Pantelides, ST; Ozyilmaz, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Toh, Chee-Tat; Zhang, Hongji; Lin, Junhao; Mayorov, Alexander S.; Wang, Yun-Peng; Orofeo, Carlo M.; Ferry, Darim Badur; Andersen, Henrik; Kakenov, Nurbek; Guo, Zenglong; Abidi, Irfan Haider; Sims, Hunter; Suenaga, Kazu; Pantelides, Sokrates T.; Ozyilmaz, Barbaros", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and properties of free-standing monolayer amorphous carbon", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bulk amorphous materials have been studied extensively and are widely used, yet their atomic arrangement remains an open issue. Although they are generally believed to be Zachariasen continuous random networks(1), recent experimental evidence favours the competing crystallite model in the case of amorphous silicon(2-4). In two-dimensional materials, however, the corresponding questions remain unullswered. Here we report the synthesis, by laser-assisted chemical vapour deposition(5), of centimetre-scale, free-standing, continuous and stable monolayer amorphous carbon, topologically distinct from disordered graphene. Unlike in bulk materials, the structure of monolayer amorphous carbon can be determined by atomic-resolution imaging. Extensive characterization by Raman and X-ray spectroscopy and transmission electron microscopy reveals the complete absence of long-range periodicity and a threefold-coordinated structure with a wide distribution of bond lengths, bond angles, and five-, six-, seven- and eight-member rings. The ring distribution is not a Zachariasen continuous random network, but resembles the competing (nullo)crystallite model(6). We construct a corresponding model that enables density-functional-theory calculations of the properties of monolayer amorphous carbon, in accordance with observations. Direct measurements confirm that it is insulating, with resistivity values similar to those of boron nitride grown by chemical vapour deposition. Free-standing monolayer amorphous carbon is surprisingly stable and deforms to a high breaking strength, without crack propagation from the point of fracture. The excellent physical properties of this stable, free-standing monolayer amorphous carbon could prove useful for permeation and diffusion barriers in applications such as magnetic recording devices and flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2020, "Volume": 577, "Issue": 7789, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 199, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1871-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1871-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506682500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hui, L; Xue, YR; Huang, BL; Yu, HD; Zhang, C; Zhang, DY; Jia, DZ; Zhao, YJ; Li, YJ; Liu, HB; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hui, Lan; Xue, Yurui; Huang, Bolong; Yu, Huidi; Zhang, Chao; Zhang, Danyan; Jia, Dianzeng; Zhao, Yingjie; Li, Yongjun; Liu, Huibiao; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overall water splitting by graphdiyne-exfoliated and -sandwiched layered double-hydroxide nullosheet arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of great urgency to develop efficient, cost-effective, stable and industrially applicable electrocatalysts for renewable energy systems. But there are still few candidate materials. Here we show a bifunctional electrocatalyst, comprising graphdiyne-exfoliated and -sandwiched iron/cobalt layered double-hydroxide nullosheet arrays grown on nickel foam, for the oxygen and hydrogen evolution reactions. Theoretical and experimental data revealed that the charge transport kinetics of the structure were superior to iron/cobalt layered doublehydroxide, a prerequisite for improved electrocatalytic performance. The incorporation with graphdiyne increased the number of catalytically active sites and prevented corrosion, leading to greatly enhanced electrocatalytic activity and stability for oxygen evolution reaction, hydrogen evolution reaction, as well as overall water splitting. Our results suggest that the use of graphdiyne might open up new pathways for the design and fabrication of earth-abundant, efficient, functional, and smart electrode materials with practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5309, "DOI": "10.1038/s41467-018-07790-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07790-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453244200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Casalongue, HGS; Ng, ML; Kaya, S; Friebel, D; Ogasawara, H; Nilsson, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Casalongue, Hernull G. Sanchez; Ng, May Ling; Kaya, Sarp; Friebel, Daniel; Ogasawara, Hirohito; Nilsson, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Observation of Surface Species on Iridium Oxide nulloparticles during the Oxygen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An iridium oxide nulloparticle electrocatalyst under oxygen evolution reaction conditions was probed in situ by ambient-pressure X-ray photoelectron spectroscopy. Under OER conditions, iridium undergoes a change in oxidation state from Ir-IV to Ir-V that takes place predominulltly at the surface of the catalyst. The chemical change in iridium is coupled to a decrease in surface hydroxide, providing experimental evidence which strongly suggests that the oxygen evolution reaction on iridium oxide occurs through an OOH-mediated deprotonation mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 53, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7169, "End Page": 7172, "Article Number": null, "DOI": "10.1002/anie.201402311", "DOI Link": "http://dx.doi.org/10.1002/anie.201402311", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338989500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, J; Wu, Y; Ye, W; Jacobs, DA; Shen, H; Fu, X; Wan, Y; Duong, T; Wu, N; Barugkin, C; Nguyen, HT; Zhong, D; Li, J; Lu, T; Liu, Y; Lockrey, MN; Weber, KJ; Catchpolea, KR; White, TP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jun; Wu, Yiliang; Ye, Wang; Jacobs, Daniel A.; Shen, Heping; Fu, Xiao; Wan, Yimao; Duong, The; Wu, nulldi; Barugkin, Chog; Nguyen, Hieu T.; Zhong, Dingyong; Li, Juntao; Lu, Teng; Liu, Yun; Lockrey, Mark N.; Weber, Klaus J.; Catchpolea, Kylie R.; White, Thomas P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface passivation using ultrathin polymer-fullerene films for high-efficiency perovskite solar cells with negligible hysteresis", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfacial carrier recombination is one of the dominullt loss mechanisms in high efficiency perovskite solar cells, and has also been linked to hysteresis and slow transient responses in these cells. Here we demonstrate an ultrathin passivation layer consisting of a PMMA: PCBM mixture that can effectively passivate defects at or near to the perovskite/TiO2 interface, significantly suppressing interfacial recombination. The passivation layer increases the open circuit voltage of mixed-cation perovskite cells by as much as 80 mV, with champion cells achieving V-oc similar to 1.18 V. As a result, we obtain efficient and stable perovskite solar cells with a steady-state PCE of 20.4% and negligible hysteresis over a large range of scan rates. In addition, we show that the passivated cells exhibit very fast current and voltage response times of less than 3 s under cyclic illumination. This new passivation approach addresses one of the key limitations of current perovskite cells, and paves the way to further efficiency gains through interface engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1792, "End Page": 1800, "Article Number": null, "DOI": "10.1039/c7ee01096f", "DOI Link": "http://dx.doi.org/10.1039/c7ee01096f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407211200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YJ; Oka, T; Suzuki, R; Ye, JT; Iwasa, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Y. J.; Oka, T.; Suzuki, R.; Ye, J. T.; Iwasa, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically Switchable Chiral Light-Emitting Transistor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tungsten diselenide (WSe2) and related transition metal dichalcogenides exhibit interesting optoelectronic properties owing to their peculiar band structures originating from the valley degree of freedom. Although the optical generation and detection of valley polarization has been demonstrated, it has been difficult to realize active valley-dependent functions suitable for device applications. We report an electrically switchable, circularly polarized light source based on the material's valley degree of freedom. Our WSe2-based ambipolar transistors emit circularly polarized electroluminescence from p-i-n junctions electrostatically formed in transistor channels. This phenomenon can be explained qualitatively by the electron-hole overlap controlled by the in-plane electric field. Our device demonstrates a route to exploit the valley degree of freedom and the possibility to develop a valley-optoelectronics technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 667, "Times Cited, All Databases": 724, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2014, "Volume": 344, "Issue": 6185, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 725, "End Page": 728, "Article Number": null, "DOI": "10.1126/science.1251329", "DOI Link": "http://dx.doi.org/10.1126/science.1251329", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335912900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ai, D; Li, H; Zhou, Y; Ren, LL; Han, ZB; Yao, B; Zhou, W; Zhao, L; Xu, JM; Wang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ai, Ding; Li, He; Zhou, Yao; Ren, Lulu; Han, Zhubing; Yao, Bin; Zhou, Wei; Zhao, Ling; Xu, Jianmei; Wang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning nullofillers in In Situ Prepared Polyimide nullocomposites for High-Temperature Capacitive Energy Storage", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modern electronics and electrical systems demand efficient operation of dielectric polymer-based capacitors at high electric fields and elevated temperatures. Here, polyimide (PI) dielectric composites prepared from in situ polymerization in the presence of inorganic nullofillers are reported. The systematic manipulation of the dielectric constant and bandgap of the inorganic fillers, including Al2O3, HfO2, TiO2, and boron nitride nullosheets, reveals the dominullt role of the bandgap of the fillers in determining and improving the high-temperature capacitive performance of the polymer composites, which is very different from the design principle of the dielectric polymer composites operating at ambient temperature. The Al2O3- and HfO2-based PI composites with concomitantly large bandgap and moderate dielectric constants exhibit substantial improvement in the breakdown strength, discharged energy density, and charge-discharge efficiency when compared to the state-of-the-art dielectric polymers. The work provides a design paradigm for high-performance dielectric polymer nullocomposites for electrical energy storage at elevated temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 10, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903881, "DOI": "10.1002/aenm.201903881", "DOI Link": "http://dx.doi.org/10.1002/aenm.201903881", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530329400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Protesescu, L; Yakunin, S; Kumar, S; Bär, J; Bertolotti, F; Masciocchi, N; Guagliardi, A; Grotevent, M; Shorubalko, I; Bodnarchuk, MI; Shih, CJ; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Protesescu, Loredana; Yakunin, Sergii; Kumar, Sudhir; Bar, Janine; Bertolotti, Federica; Masciocchi, Norberto; Guagliardi, Antonietta; Grotevent, Matthias; Shorubalko, Ivan; Bodnarchuk, Maryna I.; Shih, Chih-Jen; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dismantling the Red Wall of Colloidal Perovskites: Highly Luminescent Formamidinium and Formamidinium-Cesium Lead Iodide nullocrystals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal nullocrystals (NCs) of APbX3-type lead halide perovskites [A = Cs+, CH3NH3+ (methylammonium or MA(+) or CH(NH2)(2)(+) (formamidinium or FAl; X = Cl-, Br-, I-] have recently emerged as highly versatile photonic sources for applications ranging from simple photoluminescence down-conversion (e.g., for display backlighting) to light-emitting diodes. From the perspective of spectral coverage, a formidable challenge facing the use of these materials is how to obtain stable emissions in the red and infrared spectral regions covered by the iodide based compositions. So far, red-emissive CsPbI3 NCs have been shown to suffer from a delayed phase transformation into a nonluminescent, wide-band-gap 1D polymorph, and MAPbI(3) exhibits very limited chemical durability. In this work, we report a facile colloidal synthesis method for obtaining FAPbI(3) and FA-doped CsPbI3 NCs that are uniform in size (10-15 nm) and nearly cubic in shape and exhibit drastically higher robustness than their MA- or Cs-only cousins with similar sizes and morphologies. Detailed structural analysis indicated that the FAPbI(3) NCs had a cubic crystal structure, while the FA(0.1)Cs(0.9)PbI(3) NCs had a 3D orthorhombic structure that was isostructural to the structure of CsPbBr3 NCs. Bright photoluminescence (PL) with high quantum yield (QY > 70%) spanning red (690 run, FA(0.1)Cs(0.9)PbI(3) NCs) and near-infrared (near-IR, ca. 780 mn, FAPbI(3) NCs) regions was sustained for several months or more in both the colloidal state and in films. The peak PL wavelengths can be fine-tuned by using postsynthetic cation- and anion-exchange reactions. Amplified spontaneous emissions with low thresholds of 28 and 7.5 mu J cm(-2) were obtained from the films deposited from FA(0.1)Cs(0.9)PbI(3) and FAPbI(3) NCs, respectively. Furthermore, light emitting diodes with a high external quantum efficiency of 2.3% were obtained by using FAPbI(3) NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 423, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3119, "End Page": 3134, "Article Number": null, "DOI": "10.1021/acsnullo.7b00116", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b00116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398014900078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Zou, WK; Luo, YW; Xie, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qian; Zou, Weike; Luo, Yingwu; Xie, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape memory polymer network with thermally distinct elasticity and plasticity", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stimuli-responsive materials with sophisticated yet controllable shape-changing behaviors are highly desirable for real-world device applications. Among various shape-changing materials, the elastic nature of shape memory polymers allows fixation of temporary shapes that can recover on demand, whereas polymers with exchangeable bonds can undergo permanent shape change via plasticity. We integrate the elasticity and plasticity into a single polymer network. Rational molecular design allows these two opposite behaviors to be realized at different temperature ranges without any overlap. By exploring the cumulative nature of the plasticity, we demonstrate easy manipulation of highly complex shapes that is otherwise extremely challenging. The dynamic shape-changing behavior paves a new way for fabricating geometrically complex multifunctional devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501297", "DOI": "10.1126/sciadv.1501297", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501297", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376972900028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sing, SL; Wiria, FE; Yeong, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sing, Swee Leong; Wiria, Florencia Edith; Yeong, Wai Yee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective laser melting of lattice structures: A statistical approach to manufacturability and mechanical behavior", "Source Title": "ROBOTICS AND COMPUTER-INTEGRATED MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper investigates the effect of processing parameters on the dimensional accuracy and mechanical properties of cellular lattice structures fabricated by additive manufacturing, also known as 3D printing. The samples are fabricated by selective laser melting (SLM) using novel titanium-tantalum alloy. The titanium-tantalum alloy has the potential to replace commercially pure titanium and Ti6Al4V as biomedical material. In this study, the unit cell used is specially designed to carry out the analysis using regression method and analysis of variance (ANOVA). Due to the effect of the SLM process parameters, the elastic constant of the cellular lattice structures ranged from 1.36 +/- 0.11 to 6.82 +/- 0.15 GPa using the same unit cell design. The elastic constant range, while showing the versatility of titanium-tantalum as biomedical material, is rather wide despite using the same lattice structure designed. This shows that there is a need to carefully control the processing parameters during the lattice structures fabrication so as to obtain the desired mechanical properties. Based on the statistical analysis, it is found that the dimensional accuracy and mechanical properties such as elastic constant and yield strength of the cellular lattice structures are most sensitive to laser power as compared to other parameters such as laser scanning speed and powder layer thickness. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 49, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 170, "End Page": 180, "Article Number": null, "DOI": "10.1016/j.rcim.2017.06.006", "DOI Link": "http://dx.doi.org/10.1016/j.rcim.2017.06.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412957500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Shen, YT; Sun, LT; Li, JC; Liu, C; Ren, WC; Li, F; Gao, LB; Chen, J; Liu, FC; Sun, YY; Tang, NJ; Cheng, HM; Du, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuan; Shen, Yuting; Sun, Litao; Li, Jincheng; Liu, Chang; Ren, Wencai; Li, Feng; Gao, Libo; Chen, Jie; Liu, Fuchi; Sun, Yuanyuan; Tang, Nujiang; Cheng, Hui-Ming; Du, Youwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elemental superdoping of graphene and carbon nullotubes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Doping of low-dimensional graphitic materials, including graphene, graphene quantum dots and single-wall carbon nullotubes with nitrogen, sulfur or boron can significantly change their properties. We report that simple fluorination followed by annealing in a dopant source can superdope low-dimensional graphitic materials with a high level of N, S or B. The superdoping results in the following doping levels: (i) for graphene, 29.82, 17.55 and 10.79 at% for N-, S-and B-doping, respectively; (ii) for graphene quantum dots, 36.38 at% for N-doping; and (iii) for single-wall carbon nullotubes, 7.79 and 10.66 at% for N- and S-doping, respectively. As an example, the N-superdoping of graphene can greatly increase the capacitive energy storage, increase the efficiency of the oxygen reduction reaction and induce ferromagnetism. Furthermore, by changing the degree of fluorination, the doping level can be tuned over a wide range, which is important for optimizing the performance of doped low-dimensional graphitic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10921, "DOI": "10.1038/ncomms10921", "DOI Link": "http://dx.doi.org/10.1038/ncomms10921", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371715800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, Q; Xu, SY; Shen, HT; MacNeill, D; Fatemi, V; Chang, TR; Valdivia, AMM; Wu, SF; Du, ZZ; Hsu, CH; Fang, S; Gibson, QD; Watanabe, K; Taniguchi, T; Cava, RJ; Kaxiras, E; Lu, HZ; Lin, H; Fu, L; Gedik, N; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Qiong; Xu, Su-Yang; Shen, Huitao; MacNeill, David; Fatemi, Valla; Chang, Tay-Rong; Valdivia, Andres M. Mier; Wu, Sanfeng; Du, Zongzheng; Hsu, Chuang-Han; Fang, Shiang; Gibson, Quinn D.; Watanabe, Kenji; Taniguchi, Takashi; Cava, Robert J.; Kaxiras, Efthimios; Lu, Hai-Zhou; Lin, Hsin; Fu, Liang; Gedik, Nuh; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the nonlinear Hall effect under time-reversal-symmetric conditions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrical Hall effect is the production, upon the application of an electric field, of a transverse voltage under an out-of-plane magnetic field. Studies of the Hall effect have led to important breakthroughs, including the discoveries of Berry curvature and topological Chern invariants(1,2). The internal magnetization of magnets means that the electrical Hall effect can occur in the absence of an external magnetic field(2); this 'anomalous' Hall effect is important for the study of quantum magnets(2-7). The electrical Hall effect has rarely been studied in non-magnetic materials without external magnetic fields, owing to the constraint of timer-eversal symmetry. However, only in the linear response regime-when the Hall voltage is linearly proportional to the external electric field-does the Hall effect identically vanish as a result of time-reversal symmetry; the Hall effect in the nonlinear response regime is not subject to such symmetry constraints(8-10). Here we report observations of the nonlinear Hall effect(10) in electrical transport in bilayers of the non-magnetic quantum material WTe2 under time-reversal-symmetric conditions. We show that an electric current in bilayer WTe2 leads to a nonlinear Hall voltage in the absence of a magnetic field. The properties of this nonlinear Hall effect are distinct from those of the anomalous Hall effect in metals: the nonlinear Hall effect results in a quadratic, rather than linear, current-voltage characteristic and, in contrast to the anomalous Hall effect, the nonlinear Hall effect results in a much larger transverse than longitudinal voltage response, leading to a nonlinear Hall angle (the angle between the total voltage response and the applied electric field) of nearly 90 degrees. We further show that the nonlinear Hall effect provides a direct measure of the dipole moment(10) of the Berry curvature, which arises from layer-polarized Dirac fermions in bilayer WTe2. Our results demonstrate a new type of Hall effect and provide a way of detecting Berry curvature in nonmagnetic quantum materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 565, "Issue": 7739, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0807-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0807-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455781600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, RS; Nolan, AM; Lu, JZ; Wang, JY; Yu, XQ; Mo, YF; Chen, LQ; Huang, XJ; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Rusong; Nolan, Adelaide M.; Lu, Jiaze; Wang, Junyang; Yu, Xiqian; Mo, Yifei; Chen, Liquan; Huang, Xuejie; Li, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Thermal Stability of Lithium Solid Electrolytes with Metallic Lithium", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state lithium-metal batteries are regarded as promising next-generation battery systems. While thermal runaway in conventional Li-ion batteries is known to cause safety hazards, the thermal issues posed by highly reactive metallic lithium (Li) with non-flammable ceramic solid electrolytes (SEs) have been less studied but are critical for the safety of all-solid-state Li-metal batteries. Here, we quantify the thermal stability of four prevalent oxide SEs with metallic Li using the accelerating rate calorimeter (ARC). Thermal runaway is observed during ARC tests for four widely used SEs when contacting with Li, while no obvious heat releases from garnet with Li. The oxygen generation from SEs at elevated temperatures is found to be responsible for the thermal runaway with Li. Our results indicate potential safety issues in all solid-state batteries (ASSBs) brought by highly reactive metallic Li and oxygen from SEs at increased temperatures, emphasizing the need for investigating thermal safety issues in ASSBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 812, "End Page": 821, "Article Number": null, "DOI": "10.1016/j.joule.2020.03.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.03.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527264500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, CJ; Gao, MY; Yu, XX; Zhang, JY; Cheng, YH; Zhu, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Chengjian; Gao, Mengyue; Yu, Xiaoxiao; Zhang, Junyan; Cheng, Yanhua; Zhu, Meifang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fibrous Aerogels with Tunable Superwettability for High-Performance Solar-Driven Interfacial Evaporation", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven interfacial evaporation is an emerging technology for water desalination. Generally, double-layered structure with separate surface wettability properties is usually employed for evaporator construction. However, creating materials with tunable properties is a great challenge because the wettability of existing materials is usually monotonous. Herein, we report vinyltrimethoxysilane as a single molecular unit to hybrid with bacterial cellulose (BC) fibrous network, which can be built into robust aerogel with entirely distinct wettability through controlling assembly pathways. Siloxane groups or carbon atoms are exposed on the surface of BC nullofibers, resulting in either superhydrophilic or superhydrophobic aerogels. With this special property, single component-modified aerogels could be integrated into a double-layered evaporator for water desalination. Under 1 sun, our evaporator achieves high water evaporation rates of 1.91 and 4.20 kg m(-2) h(-1) under laboratory and outdoor solar conditions, respectively. Moreover, this aerogel evaporator shows unprecedented lightweight, structural robustness, long-term stability under extreme conditions, and excellent salt-resistance, highlighting the advantages in synthesis of aerogel materials from the single molecular unit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64, "DOI": "10.1007/s40820-023-01034-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01034-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948771900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YQ; Xu, K; Wei, ZX; Li, HL; Zhang, T; Li, XY; Cai, WP; Ma, JM; Fan, HJ; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yiqiang; Xu, Kun; Wei, Zengxi; Li, Huilin; Zhang, Tao; Li, Xinyang; Cai, Weiping; Ma, Jianmin; Fan, Hong Jin; Li, Yue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Electronic Interaction in Dual-Cation-Incorporated NiSe2 nullosheets with Lattice Distortion for Highly Efficient Overall Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring highly efficient and low-cost electrocatalysts for electrochemical water splitting is of importance for the conversion of intermediate energy. Herein, the synthesis of dual-cation (Fe, Co)-incorporated NiSe2 nullosheets (Fe, Co-NiSe2) and systematical investigation of their electrocatalytic performance for water splitting as a function of the composition are reported. The dual-cation incorporation can distort the lattice and induce stronger electronic interaction, leading to increased active site exposure and optimized adsorption energy of reaction intermediates compared to single-cation-doped or pure NiSe2. As a result, the obtained Fe0.09Co0.13-NiSe2 porous nullosheet electrode shows an optimized catalytic activity with a low overpotential of 251 mV for oxygen evolution reaction and 92 mV for hydrogen evolution reaction (both at 10 mA cm(-2) in 1 m KOH). When used as bifunctional electrodes for overall water splitting, the current density of 10 mA cm(-2) is achieved at a low cell voltage of 1.52 V. This work highlights the importance of dual-cation doping in enhancing the electrocatalyst performance of transition metal dichalcogenides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2018, "Volume": 30, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802121, "DOI": "10.1002/adma.201802121", "DOI Link": "http://dx.doi.org/10.1002/adma.201802121", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442732400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, TZ; Ren, X; Sun, YM; Sun, SN; Xian, GY; Scherer, GG; Fisher, AC; Mandler, D; Ager, JW; Grimaud, A; Wang, JL; Shen, CM; Yang, HT; Gracia, J; Gao, HJ; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Tianze; Ren, Xiao; Sun, Yuanmiao; Sun, Shengnull; Xian, Guoyu; Scherer, Guenther G.; Fisher, Adrian C.; Mandler, Daniel; Ager, Joel W.; Grimaud, Alexis; Wang, Junling; Shen, Chengmin; Yang, Haitao; Gracia, Jose; Gao, Hong-Jun; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Producing hydrogen by water electrolysis suffers from the kinetic barriers in the oxygen evolution reaction (OER) that limits the overall efficiency. With spin-dependent kinetics in OER, to manipulate the spin ordering of ferromagnetic OER catalysts (e.g., by magnetization) can reduce the kinetic barrier. However, most active OER catalysts are not ferromagnetic, which makes the spin manipulation challenging. In this work, we report a strategy with spin pinning effect to make the spins in paramagnetic oxyhydroxides more aligned for higher intrinsic OER activity. The spin pinning effect is established in oxide(FM)/oxyhydroxide interface which is realized by a controlled surface reconstruction of ferromagnetic oxides. Under spin pinning, simple magnetization further increases the spin alignment and thus the OER activity, which validates the spin effect in rate-limiting OER step. The spin polarization in OER highly relies on oxyl radicals (O.) created by 1(st) dehydrogenation to reduce the barrier for subsequent O-O coupling. Water oxidation to triplet oxygen requires a spin polarization process for faster kinetics. Here, the authors show an interface spin pinning effect between ferromagnetic oxides and reconstructed oxyhydroxide surface layer, where the spin ordering in paramagnetic oxyhydroxide catalyst layer can be tuned to improve the intrinsic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3634, "DOI": "10.1038/s41467-021-23896-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23896-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665021800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shekhar, C; Nayak, AK; Sun, Y; Schmidt, M; Nicklas, M; Leermakers, I; Zeitler, U; Skourski, Y; Wosnitza, J; Liu, ZK; Chen, YL; Schnelle, W; Borrmann, H; Grin, Y; Felser, C; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shekhar, Chandra; Nayak, Ajaya K.; Sun, Yan; Schmidt, Marcus; Nicklas, Michael; Leermakers, Inge; Zeitler, Uli; Skourski, Yurii; Wosnitza, Jochen; Liu, Zhongkai; Chen, Yulin; Schnelle, Walter; Borrmann, Horst; Grin, Yuri; Felser, Claudia; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely large magnetoresistance and ultrahigh mobility in the topological Weyl semimetal candidate NbP", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent experiments have revealed spectacular transport properties in semimetals, such as the large, non-saturating magnetoresistance exhibited by WTe2 (ref.1). Topological semimetals with massless relativistic electrons have also been predicted(2) as three-dimensional analogues of graphene(3). These systems are known as Weyl semimetals, and are predicted to have a range of exotic transport properties and surface states(4-7), distinct from those of topological insulators(8,9). Here we examine the magneto-transport properties of NbP, a material the band structure of which has been predicted to combine the hallmarks of a Weyl semimetal(10,11) with those of a normal semimetal. We observe an extremely large magnetoresistance of 850,000% at 1.85 K (250% at room temperature) in a magnetic field of up to 9 T, without any signs of saturation, and an ultra-high carrier mobility of 5 x 10(6) cm(2) V-1 s(-1) that accompanied by strong Shubnikov-de Haas (SdH) oscillations. NbP therefore presents a unique example of a material combining topological and conventional electronic phases, with intriguing physical properties resulting from their interplay.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 958, "Times Cited, All Databases": 1020, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 645, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3372", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3372", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358851900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, Y; Zhao, XH; Xia, C; Wu, ZY; Zhu, P; Kim, JYT; Bai, XW; Gao, GH; Hu, YF; Zhong, J; Liu, YY; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Yang; Zhao, Xunhua; Xia, Chuan; Wu, Zhen-Yu; Zhu, Peng; Kim, Jung Yoon Timothy; Bai, Xiaowan; Gao, Guanhui; Hu, Yongfeng; Zhong, Jun; Liu, Yuanyue; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active and selective oxygen reduction to H2O2 on boron-doped carbon for high production rates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen reduction reaction towards hydrogen peroxide (H2O2) provides a green alternative route for H2O2 production, but it lacks efficient catalysts to achieve high selectivity and activity simultaneously under industrial-relevant production rates. Here we report a boron-doped carbon (B-C) catalyst which can overcome this activity-selectivity dilemma. Compared to the state-of-the-art oxidized carbon catalyst, B-C catalyst presents enhanced activity (saving more than 210mV overpotential) under industrial-relevant currents (up to 300mAcm(-2)) while maintaining high H2O2 selectivity (85-90%). Density-functional theory calculations reveal that the boron dopant site is responsible for high H2O2 activity and selectivity due to low thermodynamic and kinetic barriers. Employed in our porous solid electrolyte reactor, the B-C catalyst demonstrates a direct and continuous generation of pure H2O2 solutions with high selectivity (up to 95%) and high H2O2 partial currents (up to similar to 400mAcm(-2)), illustrating the catalyst's great potential for practical applications in the future. Oxygen reduction reaction provides an environmentally-benign route for hydrogen peroxide production but lacks efficient catalysts to achieve high selectivity and activity simultaneously. Here, the authors report a boron-doped carbon catalyst which shows great promise with outstanding performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4225, "DOI": "10.1038/s41467-021-24329-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24329-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000674487100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chun-Ho", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Multi-Criteria Decision-Making Model for Building Material Supplier Selection Based on Entropy-AHP Weighted TOPSIS", "Source Title": "ENTROPY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The type of criterion weight can be distinguished according to different decision methods. Subjective weights are given by decision makers based on their knowledge, experience, expertise, and other factors. Objective weights are obtained through multi-step calculations of the evaluation matrix constructed from the actual information about the evaluation criteria of the alternatives. A single consideration of these two types of weights often results in biased results. In addition, in order to build an effective supply chain source, buyers must find suitable quality products and/or service providers in the process of supplier selection. Based on the above reasons, it is difficult to accurately select the appropriate alternative. The main contribution of this paper is to combine entropy weight, analytic hierarchy process (AHP) weight, and the technique for order preference by similarity to an ideal solution (TOPSIS) method into a suitable multi-criteria decision making (MCDM) solution. The TOPSIS method is extended with entropy-AHP weights, and entropy-AHP weights are used instead of subjective weights. A novel decision-making model of TOPSIS integrated entropy-AHP weights is proposed to select the appropriate supplier. Finally, we take the selection of building material suppliers as an example and use sensitivity analysis to show that the combination of the TOPSIS method based on entropy-AHP weights can effectively select the appropriate supplier.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 22, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 259, "DOI": "10.3390/e22020259", "DOI Link": "http://dx.doi.org/10.3390/e22020259", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521371400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, SQ; Zhou, AG; Wu, MZ; Hu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Shangqing; Zhou, Aiguo; Wu, Mingzai; Hu, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kirigami Patterning of MXene/Bacterial Cellulose Composite Paper for All-Solid-State Stretchable Micro-Supercapacitor Arrays", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable micropower sources with high energy density and stability under repeated tensile deformation are key components of flexible/wearable microelectronics. Herein, through the combination of strain engineering and modulation of the interlayer spacing, freestanding and lightweight MXene/bacterial cellulose (BC) composite papers with excellent mechanical stability and a high electrochemical performance are first designed and prepared via a facile all-solution-based paper-making process. Following a simple laser-cutting kirigami patterning process, bendable, twistable, and stretchable all-solid-state micro-supercapacitor arrays (MSCAs) are further fabricated. As expected, benefiting from the high-performance MXene/BC composite electrodes and rational sectional structural design, the resulting kirigami MSCAs exhibit a high areal capacitance of 111.5 mF cm(-2), and are stable upon stretching of up to 100% elongation, and in bent or twisted states. The demonstrated combination of an all-solution-based MXene/BC composite paper-making method and an easily manipulated laser-cutting kirigami patterning technique enables the fabrication of MXene-based deformable all-solid-state planar MSCAs in a simple and efficient manner while achieving excellent areal performance metrics and high stretchability, making them promising micropower sources that are compatible with flexible/wearable microelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900529, "DOI": "10.1002/advs.201900529", "DOI Link": "http://dx.doi.org/10.1002/advs.201900529", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477708000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schubert, C; van Langeveld, MC; Donoso, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schubert, Carl; van Langeveld, Mark C.; Donoso, Larry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Innovations in 3D printing: a 3D overview from optics to organs", "Source Title": "BRITISH JOURNAL OF OPHTHALMOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D printing is a method of manufacturing in which materials, such as plastic or metal, are deposited onto one another in layers to produce a three dimensional object, such as a pair of eye glasses or other 3D objects. This process contrasts with traditional ink-based printers which produce a two dimensional object (ink on paper). To date, 3D printing has primarily been used in engineering to create engineering prototypes. However, recent advances in printing materials have now enabled 3D printers to make objects that are comparable with traditionally manufactured items. In contrast with conventional printers, 3D printing has the potential to enable mass customisation of goods on a large scale and has relevance in medicine including ophthalmology. 3D printing has already been proved viable in several medical applications including the manufacture of eyeglasses, custom prosthetic devices and dental implants. In this review, we discuss the potential for 3D printing to revolutionise manufacturing in the same way as the printing press revolutionised conventional printing. The applications and limitations of 3D printing are discussed; the production process is demonstrated by producing a set of eyeglass frames from 3D blueprints.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 98, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 159, "End Page": 161, "Article Number": null, "DOI": "10.1136/bjophthalmol-2013-304446", "DOI Link": "http://dx.doi.org/10.1136/bjophthalmol-2013-304446", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Ophthalmology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330069300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, JM; Zheliuk, O; Leermakers, I; Yuan, NFQ; Zeitler, U; Law, KT; Ye, JT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, J. M.; Zheliuk, O.; Leermakers, I.; Yuan, N. F. Q.; Zeitler, U.; Law, K. T.; Ye, J. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for two-dimensional Ising superconductivity in gated MoS2", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Zeeman effect, which is usually detrimental to superconductivity, can be strongly protective when an effective Zeeman field from intrinsic spin-orbit coupling locks the spins of Cooper pairs in a direction orthogonal to an external magnetic field. We performed magnetotransport experiments with ionic-gated molybdenum disulfide transistors, in which gating prepared individual superconducting states with different carrier dopings, and measured an in-plane critical field B-c2 far beyond the Pauli paramagnetic limit, consistent with Zeeman-protected superconductivity. The gating-enhanced B-c2 is more than an order of magnitude larger than it is in the bulk superconducting phases, where the effective Zeeman field is weakened by interlayer coupling. Our study provides experimental evidence of an Ising superconductor, in which spins of the pairing electrons are strongly pinned by an effective Zeeman field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 721, "Times Cited, All Databases": 782, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2015, "Volume": 350, "Issue": 6266, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1353, "End Page": 1357, "Article Number": null, "DOI": "10.1126/science.aab2277", "DOI Link": "http://dx.doi.org/10.1126/science.aab2277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366162400037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cho, B; Hahm, MG; Choi, M; Yoon, J; Kim, AR; Lee, YJ; Park, SG; Kwon, JD; Kim, CS; Song, M; Jeong, Y; Nam, KS; Lee, S; Yoo, TJ; Kang, CG; Lee, BH; Ko, HC; Ajayan, PM; Kim, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cho, Byungjin; Hahm, Myung Gwan; Choi, Minseok; Yoon, Jongwon; Kim, Ah Ra; Lee, Young-Joo; Park, Sung-Gyu; Kwon, Jung-Dae; Kim, Chang Su; Song, Myungkwan; Jeong, Yongsoo; Nam, Kee-Seok; Lee, Sangchul; Yoo, Tae Jin; Kang, Chang Goo; Lee, Byoung Hun; Ko, Heung Cho; Ajayan, Pulickel M.; Kim, Dong-Ho", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-transfer-based Gas Sensing Using Atomic-layer MoS2", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) molybdenum disulphide (MoS2) atomic layers have a strong potential to be used as 2D electronic sensor components. However, intrinsic synthesis challenges have made this task difficult. In addition, the detection mechanisms for gas molecules are not fully understood. Here, we report a high-performance gas sensor constructed using atomic-layered MoS2 synthesised by chemical vapour deposition (CVD). A highly sensitive and selective gas sensor based on the CVD-synthesised MoS2 was developed. In situ photoluminescence characterisation revealed the charge transfer mechanism between the gas molecules and MoS2, which was validated by theoretical calculations. First-principles density functional theory calculations indicated that NO2 and NH3 molecules have negative adsorption energies (i.e., the adsorption processes are exothermic). Thus, NO2 and NH3 molecules are likely to adsorb onto the surface of the MoS2. The in situ PL characterisation of the changes in the peaks corresponding to charged trions and neutral excitons via gas adsorption processes was used to elucidate the mechanisms of charge transfer between the MoS2 and the gas molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 512, "Times Cited, All Databases": 552, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8052, "DOI": "10.1038/srep08052", "DOI Link": "http://dx.doi.org/10.1038/srep08052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348351800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CJ; Liu, GQ; Sun, N; Zhang, X; Wang, GZ; Zhang, YX; Zhang, HM; Zhao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Cuijiao; Liu, Guoqiang; Sun, Na; Zhang, Xian; Wang, Guozhong; Zhang, Yunxia; Zhang, Haimin; Zhao, Huijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-derived N-doped porous carbon as electrode materials for Zn-air battery powered capacitive deionization", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Capacitive deionization (CDI) has been a promising technique to obtain fresh water by electrosorption of charged ionic species in seawater/brackish water. Its performance is highly dependent on the physical and chemical properties of CDI electrode materials. Herein, N-doped porous carbon (NPC) with a N content of 1.66 at.% was fabricated using soybean shell as starting material by a facile pyrolysis approach with the assistance of KHCO3 in N-2 atmosphere. The as-prepared NPC with porous structure and high surface area (1036.2m(2) g(-1)) was further functionalized with sulfonic groups in an aryl diazonium salt solution to obtain sulfonyl functionalized NPC (S-NPC) with a surface area of 844.0m(2) g(-1). S-NPC as cathode material was assembled into an asymmetric CDI device with aminated activated carbon (A-AC) as anode material, exhibiting superior CDI performance with an adsorption capacity of 15.5 mg g(-1) and an average adsorption rate of 0.44 mg g(-1) min(-1) in 40 mg L-1 NaCl solution at an applied voltage of 1.2 V. As a proof of concept study, such configured CDI device was also powered for the first time by a Zn-air battery made from NPC with an opencircuit voltage of 1.28 V owing to N doping in soybean shell derived porous carbon with superior oxygen reduction reaction (ORR) activity, delivering an impressive CDI performance with an adsorption capacity of 15.8 mg g(-1) and an average adsorption rate of 0.37 mg g(-1) min(-1) in 40 mg L-1 NaCl solution. This superior CDI performance can be due to S-NPC with high surface area, porous structure and surface rich negative charges resulted from sulfonyl functionalization, favourable for adsorption active sites exposure and mass transport of Na+ ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2018, "Volume": 334, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1270, "End Page": 1280, "Article Number": null, "DOI": "10.1016/j.cej.2017.11.069", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.11.069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418533400127", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, DX; Zhu, QG; Chen, CJ; Liu, HZ; Liu, ZM; Zhao, ZJ; Zhang, XY; Liu, SJ; Han, BX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dexin; Zhu, Qinggong; Chen, Chunjun; Liu, Huizhen; Liu, Zhimin; Zhao, Zhijuan; Zhang, Xiaoyu; Liu, Shoujie; Han, Buxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective electroreduction of carbon dioxide to methanol on copper selenide nullocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Production of methanol from electrochemical reduction of carbon dioxide is very attractive. However, achieving high Faradaic efficiency with high current density using facile prepared catalysts remains to be a challenge. Herein we report that copper selenide nullocatalysts have outstanding performance for electrochemical reduction of carbon dioxide to methanol, and the current density can be as high as 41.5 mA cm(-2) with a Faradaic efficiency of 77.6% at a low overpotential of 285 mV. The copper and selenium in the catalysts cooperate very well for the formation of methanol. The current density is higher than those reported up to date with very high Faradaic efficiency for producing methanol. As far as we know, this is the first work for electrochemical reduction of carbon dioxide using copper selenide as the catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 677, "DOI": "10.1038/s41467-019-08653-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08653-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458175700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kondori, A; Esmaeilirad, M; Harzandi, AM; Amine, R; Saray, MT; Yu, L; Liu, TC; Wen, JG; Shan, NN; Wang, HH; Ngo, AT; Redfern, PC; Johnson, CS; Amine, K; Shahbazian-Yassar, R; Curtiss, LA; Asadi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kondori, Alireza; Esmaeilirad, Mohammadreza; Harzandi, Ahmad Mosen; Amine, Rachid; Saray, Mahmoud Tamadoni; Yu, Lei; Liu, Tongchao; Wen, Jianguo; Shan, nullnull; Wang, Hsien-Hau; Ngo, Anh T.; Redfern, Paul C.; Johnson, Christopher S.; Amine, Khalil; Shahbazian-Yassar, Reza; Curtiss, Larry A.; Asadi, Mohammad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A room temperature rechargeable Li2O-based lithium-air battery enabled by a solid electrolyte", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A lithium-air battery based on lithium oxide (Li2O) formation can theoretically deliver an energy density that is comparable to that of gasoline. Lithium oxide formation involves a four-electron reaction that is more difficult to achieve than the one-and two-electron reaction processes that result in lithium superoxide (LiO2) and lithium peroxide (Li2O2), respectively. By using a composite polymer electrolyte based on Li10GeP2S12 nulloparticles embedded in a modified polyethylene oxide polymer matrix, we found that Li2O is the main product in a room temperature solid-state lithium-air battery. The battery is rechargeable for 1000 cycles with a low polarization gap and can operate at high rates. The four-electron reaction is enabled by a mixed ion-electron-conducting discharge product and its interface with air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 379, "Issue": 6631, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 499, "End Page": 504, "Article Number": null, "DOI": "10.1126/science.abq1347", "DOI Link": "http://dx.doi.org/10.1126/science.abq1347", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000934127700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chuang, HJ; Tan, XB; Ghimire, NJ; Perera, MM; Chamlagain, B; Cheng, MMC; Yan, JQ; Mandrus, D; Tománek, D; Zhou, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chuang, Hsun-Jen; Tan, Xuebin; Ghimire, Nirmal Jeevi; Perera, Meeghage Madusanka; Chamlagain, Bhim; Cheng, Mark Ming-Cheng; Yan, Jiaqiang; Mandrus, David; Tomanek, David; Zhou, Zhixian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Mobility WSe2 p- and n-Type Field-Effect Transistors Contacted by Highly Doped Graphene for Low-Resistance Contacts", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the fabrication of both n-type and p-type WSe2 field-effect transistors with hexagonal boron nitride passivated channels and ionic-liquid (IL)-gated graphene contacts. Our transport measurements reveal intrinsic channel properties including a metal-insulator transition at a characteristic conductivity close to the quantum conductance e(2)/h, a high ON/OFF ratio of >10(7) at 170 K, and large electron and hole mobility of mu approximate to 200 cm(2) V-1 s(-1) at 160 K. Decreasing the temperature to 77 K increases mobility of electrons to similar to 330 cm(2) V-1 s(-1) and that of holes to similar to 270 cm(2) V-1 s(-1). We attribute our ability to observe the intrinsic, phonon-limited conduction in both the electron and hole channels to the drastic reduction of the Schottky barriers between the channel and the graphene contact electrodes using IL gating. We elucidate this process by studying a Schottky diode consisting of a single graphene/WSe2 Schottky junction. Our results indicate the possibility to utilize chemically or electrostatically highly doped graphene for versatile, flexible, and transparent low-resistance ohmic contacts to a wide range of quasi-2D semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 486, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3594, "End Page": 3601, "Article Number": null, "DOI": "10.1021/nl501275p", "DOI Link": "http://dx.doi.org/10.1021/nl501275p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100096", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, CC; Zhang, QH; Liu, Y; Luo, W; Guo, X; Huang, ZR; Ting, H; Sun, WH; Zhong, XR; Wei, SY; Wang, SF; Chen, ZJ; Xiao, LX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Cuncun; Zhang, Qiaohui; Liu, Yang; Luo, Wei; Guo, Xuan; Huang, Ziru; Ting, Hungkit; Sun, Weihai; Zhong, Xinrui; Wei, Shiyuan; Wang, Shufeng; Chen, Zhijian; Xiao, Lixin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Dawn of Lead-Free Perovskite Solar Cell: Highly Stable Double Perovskite Cs2AgBiBr6 Film", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, lead-free double perovskites have emerged as a promising environmentally friendly photovoltaic material for their intrinsic thermodynamic stability, appropriate bandgaps, small carrier effective masses, and low exciton binding energies. However, currently no solar cell based on these double perovskites has been reported, due to the challenge in film processing. Herein, a first lead-free double perovskite planar heterojunction solar cell with a high quality Cs2AgBiBr6 film, fabricated by low-pressure assisted solution processing under ambient conditions, is reported. The device presents a best power conversion efficiency of 1.44%. The preliminary efficiency and the high stability under ambient condition without encapsulation, together with the high film quality with simple processing, demonstrate promise for lead-free perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700759, "DOI": "10.1002/advs.201700759", "DOI Link": "http://dx.doi.org/10.1002/advs.201700759", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428310500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoon, M; Dong, YH; Hwang, J; Sung, J; Cha, H; Ahn, K; Huang, YM; Kang, SJ; Li, J; Cho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoon, Moonsu; Dong, Yanhao; Hwang, Jaeseong; Sung, Jaekyung; Cha, Hyungyeon; Ahn, Kihong; Huang, Yimeng; Kang, Seok Ju; Li, Ju; Cho, Jaephil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reactive boride infusion stabilizes Ni-rich cathodes for lithium-ion batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineered polycrystalline electrodes are critical to the cycling stability and safety of lithium-ion batteries, yet it is challenging to construct high-quality coatings at both the primary- and secondary-particle levels. Here we present a room-temperature synthesis route to achieve a full surface coverage of secondary particles and facile infusion into grain boundaries, and thus offer a complete 'coating-plus-infusion' strategy. Cobalt boride metallic glass was successfully applied to a Ni-rich layered cathode LiNi0.8Co0.1Mn0.1O2. It dramatically improved the rate capability and cycling stability, including under high-discharge-rate and elevated-temperature conditions and in pouch full-cells. The superior performance originates from a simultaneous suppression of the microstructural degradation of the intergranular cracking and of side reactions with the electrolyte. Atomistic simulations identified the critical role of strong selective interfacial bonding, which offers not only a large chemical driving force to ensure uniform reactive wetting and facile infusion, but also lowers the surface/interface oxygen activity, which contributes to the exceptional mechanical and electrochemical stabilities of the infused electrode. Coating is commonly used to improve electrode performance in batteries, but it is challenging to achieve and maintain complete coverage of electrode particles during cycling. Here the authors present a coating-and-infusion approach on Ni-rich cathodes that effectively retards stress corrosion cracking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 362, "End Page": 371, "Article Number": null, "DOI": "10.1038/s41560-021-00782-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00782-0", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623725900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwak, H; Han, D; Lyoo, J; Park, J; Jung, SH; Han, Y; Kwon, G; Kim, H; Hong, ST; Nam, KW; Jung, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwak, Hiram; Han, Daseul; Lyoo, Jeyne; Park, Juhyoun; Jung, Sung Hoo; Han, Yoonjae; Kwon, Gihan; Kim, Hansu; Hong, Seung-Tae; Nam, Kyung-Wan; Jung, Yoon Seok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Cost-Effective Halide Solid Electrolytes for All-Solid-State Batteries: Mechanochemically Prepared Fe3+-Substituted Li2ZrCl6", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the combined advantages of sulfide and oxide solid electrolytes (SEs), that is, mechanical sinterability and excellent (electro)chemical stability, recently emerging halide SEs such as Li3YCl6 are considered to be a game changer for the development of all-solid-state batteries. However, the use of expensive central metals hinders their practical applicability. Herein, a new halide superionic conductors are reported that are free of rare-earth metals: hexagonal close-packed (hcp) Li2ZrCl6 and Fe3+-substituted Li2ZrCl6, derived via a mechanochemical method. Conventional heat treatment yields cubic close-packed monoclinic Li2ZrCl6 with a low Li+ conductivity of 5.7 x 10(-6) S cm(-1) at 30 degrees C. In contrast, hcp Li2ZrCl6 with a high Li+ conductivity of 4.0 x 10(-4) S cm(-1) is derived via ball-milling. More importantly, the aliovalent substitution of Li2ZrCl6 with Fe3+, which is probed by complementary analyses using X-ray diffraction, pair distribution function, X-ray absorption spectroscopy, and Raman spectroscopy measurements, drastically enhances the Li+ conductivity up to approximate to 1 mS cm(-1) for Li2.25Zr0.75Fe0.25Cl6. The superior interfacial stability when using Li2+xZr1-xFexCl6, as compared to that when using conventional Li6PS5Cl, is proved. Furthermore, an excellent electrochemical performance of the all-solid-state batteries is achieved via the combination of Li2ZrCl6 and single-crystalline LiNi0.88Co0.11Al0.01O2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003190, "DOI": "10.1002/aenm.202003190", "DOI Link": "http://dx.doi.org/10.1002/aenm.202003190", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000608225900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WL; Zhao, WL; Zhang, HC; Dou, XC; Shi, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wenliang; Zhao, Wenli; Zhang, Haochun; Dou, Xincheng; Shi, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D/2D step-scheme α-Fe2O3/Bi2WO6 photocatalyst with efficient charge transfer for enhanced photo-Fenton catalytic activity", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the traditional Fenton reaction is considered an effective strategy for solving problems caused by environmental pollution, construction of an efficient photocatalytic system by coordinating the Fenton reaction is challenging. In this study, 2D/2D step-scheme alpha-Fe2O3/Bi2WO6 (FO/BWO) heterostructure photo-Fenton catalysts were successfully fabricated by a facile hydrothermal method. The as-prepared materials were characterized by XRD, FT-IR, TEM, XPS, UV-vis DRS, PL, I-t, EIS, and BET analyses. Under visible light irradiation, FO/BWO exhibited remarkably high and stable photo-Fenton catalytic activity for the degradation of methyl blue (MB) at low concentrations of H2O2. It was noted that FO/BWO (0.5) displayed a significantly enhanced photo-Fenton catalytic activity, which was 11.06 and 3.29 times those of FO nullosheets and BWO nullosheets, respectively. The notably improved photo-Fenton catalytic activity of FO/BWO was mainly due to the combination of H2O2 and FO under light illumination and the presence of the 2D/2D S-scheme heterostructure, with the large contact surface, abundant active sites, and efficient separation rate of photogenerated carriers playing contributory roles. Additionally, a possible catalytic mechanism for the FO/BWO composite was preliminarily proposed via active species trapping experiments. In summary, this study provided new insights into the synthesis of an effectively heterogeneous 2D/2D S-scheme photo-Fenton catalyst for degradation of organic pollutants in wastewater. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 97, "End Page": 106, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63602-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63602-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ali, A; Chiang, YW; Santos, RM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ali, Asif; Chiang, Yi Wai; Santos, Rafael M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "X-ray Diffraction Techniques for Mineral Characterization: A Review for Engineers of the Fundamentals, Applications, and Research Directions", "Source Title": "MINERALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray diffraction (XRD) is an important and widely used material characterization technique. With the recent development in material science technology and understanding, various new materials are being developed, which requires upgrading the existing analytical techniques such that emerging intricate problems can be solved. Although XRD is a well-established non-destructive technique, it still requires further improvements in its characterization capabilities, especially when dealing with complex mineral structures. The present review conducts comprehensive discussions on atomic crystal structure, XRD principle, its applications, uncertainty during XRD analysis, and required safety precautions. The future research directions, especially the use of artificial intelligence and machine learning tools, for improving the effectiveness and accuracy of the XRD technique, are discussed for mineral characterization. The topics covered include how XRD patterns can be utilized for a thorough understanding of the crystalline structure, size, and orientation, dislocation density, phase identification, quantification, and transformation, information about lattice parameters, residual stress, and strain, and thermal expansion coefficient of materials. All these important discussions on XRD analysis for mineral characterization are compiled in this comprehensive review, so that it can benefit specialists and engineers in the chemical, mining, iron, metallurgy, and steel industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205, "DOI": "10.3390/min12020205", "DOI Link": "http://dx.doi.org/10.3390/min12020205", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771006000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Li, XY; Qin, YX; Fang, YT; Liu, GL; Wang, ZY; Matz, J; Dong, P; Shen, JF; Ye, MX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yang; Li, Xuanyang; Qin, Yixiu; Fang, Yuting; Liu, Guanglei; Wang, Zengyao; Matz, John; Dong, Pei; Shen, Jianfeng; Ye, Mingxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically porous polyimide/Ti3C2Tx film with stable electromagnetic interference shielding after resisting harsh conditions", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-based conductive nullocomposites are promising for electromagnetic interference (EMI) shielding to ensure stable operations of electronic devices and protect humans from electromagnetic radiation. Although MXenes have shown high EMI shielding performances, it remains a great challenge to construct highly efficient EMI shielding polymer/MXene composite films with minimal MXene content and high durability to harsh conditions. Here, hierarchically porous polyimide (PI)/Ti3C2Tx films with consecutively conductive pathways have been constructed via a unidirectional PI aerogel-assisted immersion and hot-pressing strategy. Contributed by special architectures and high conductivities, PI/Ti3C2Tx films with 2.0 volume % Ti3C2Tx have high absolute EMI shielding effectiveness up to 15,527 dB cm(2) g(-1) at the thickness of 90 mu m. Superior EMI shielding performance can be retained even after being subjected to hygrothermal or combustion environments, cryogenic (-196 degrees C) or high (250 degrees C) temperatures, and rapid thermal shock (Delta T = 446 degrees C), demonstrating high potential as high-performance EMI shielding materials resisting harsh conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 7, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabj1663", "DOI": "10.1126/sciadv.abj1663", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abj1663", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000699973200029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, N; Li, JL; Wang, Y; Fang, C; Li, XQ; Wang, YX; Zhou, L; Zhu, B; Wu, Z; Zhu, SN; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ning; Li, Jinlei; Wang, Yang; Fang, Chang; Li, Xiuqiang; Wang, Yuxi; Zhou, Lin; Zhu, Bin; Wu, Zhen; Zhu, Shining; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A water lily-inspired hierarchical design for stable and efficient solar evaporation of high-salinity brine", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, interfacial solar vapor generation has shown great potential in realizing desalination and wastewater treatment with high energy conversion efficiency. However, high evaporation rate cannot be maintained because of the seemingly unavoidable fouling or salt accumulation on the solar absorbers. The degradation accelerates as the solute concentration increases. Here, we demonstrate a water lily-inspired hierarchical structure that enables efficient evaporation (similar to 80% solar-to-vapor efficiency) out of high-salinity brine [10 weight % (wt %)] and waste-water containing heavy metal ions (30 wt %). More notably, neither decrease in evaporation rate nor fouling on absorbers was observed during the entire evaporation process until water and solute were completely separated. With the capabilities of stable and high-rate evaporation out of high-salinity brine and the effective separation of solute from water, it is expected that this technology can have direct implications in various fields such as wastewater treatment, sea-salt production, and metal recycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw7013", "DOI": "10.1126/sciadv.aaw7013", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw7013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478770400095", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YP; Yin, J; Zheng, XL; Emwas, AH; Lei, YJ; Mohammed, OF; Cui, Y; Alshareef, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yunpei; Yin, Jun; Zheng, Xueli; Emwas, Abdul-Hamid; Lei, Yongjiu; Mohammed, Omar F.; Cui, Yi; Alshareef, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Concentrated dual-cation electrolyte strategy for aqueous zinc-ion batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable Zn-ion batteries are highly promising for stationary energy storage because of their low cost and intrinsic safety. However, due to the poor reversibility of Zn anodes and dissolution of oxide cathodes, aqueous Zn-ion batteries encounter rapid performance degradation when operating in conventional low-concentration electrolytes. Herein, we demonstrate that an aqueous Zn2+ electrolyte using a supporting Na salt at a high concentration is efficient to address these issues without sacrificing the power densities, cycling stability, and safety of zinc-ion batteries. We show that the high-concentration solute minimizes the number of free water molecules and the changes in the electronic state of the electrolyte. A combination of experimental and theoretical investigations reveals that a unique interphase, formed on the Zn anode, enables reversible and uniform Zn plating. Utilizing a cathode of sodium vanadate synthesized through a scalable strategy, the Zn-sodium vanadate battery with the concentrated bi-cation electrolyte shows improved cycling stability, decent rate performance, and low self-discharge. This work provides new insights on electrolyte engineering to achieve high-performance aqueous batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2021, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4463, "End Page": 4473, "Article Number": null, "DOI": "10.1039/d1ee01472b", "DOI Link": "http://dx.doi.org/10.1039/d1ee01472b", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677442500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, YL; Xu, XM; Zhong, YJ; Ge, L; Chen, YB; Veder, JPM; Guan, DQ; O'Hayre, R; Li, MR; Wang, GX; Wang, H; Zhou, W; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Yangli; Xu, Xiaomin; Zhong, Yijun; Ge, Lei; Chen, Yubo; Veder, Jean-Pierre Marcel; Guan, Daqin; O'Hayre, Ryan; Li, Mengran; Wang, Guoxiong; Wang, Hao; Zhou, Wei; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of oxygen evolution reaction (OER) electrocatalysts remains a major challenge that requires significant advances in both mechanistic understanding and material design. Recent studies show that oxygen from the perovskite oxide lattice could participate in the OER via a lattice oxygen-mediated mechanism, providing possibilities for the development of alternative electrocatalysts that could overcome the scaling relations-induced limitations found in conventional catalysts utilizing the adsorbate evolution mechanism. Here we distinguish the extent to which the participation of lattice oxygen can contribute to the OER through the rational design of a model system of silicon-incorporated strontium cobaltite perovskite electrocatalysts with similar surface transition metal properties yet different oxygen diffusion rates. The as-derived silicon-incorporated perovskite exhibits a 12.8-fold increase in oxygen diffusivity, which matches well with the 10-fold improvement of intrinsic OER activity, suggesting that the observed activity increase is dominulltly a result of the enhanced lattice oxygen participation. While water splitting provides a renewable means to store energy, the sluggish O-2 evolution half-reaction limits applications. Here, authors examine a silicon-incorporated strontium cobaltite perovskite and correlate lattice oxygen participation in O-2 evolution to the oxygen ion diffusivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002, "DOI": "10.1038/s41467-020-15873-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15873-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558820800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Yin, W; Gao, SW; Sun, YN; Xu, PL; Wu, SH; Kong, H; Yang, GZ; Wei, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tao; Yin, Wen; Gao, Shouwu; Sun, Yaning; Xu, Peilong; Wu, Shaohua; Kong, Hao; Yang, Guozheng; Wei, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Combination of Two-Dimensional nullomaterials with Metal Oxide nulloparticles for Gas Sensors: A Review", "Source Title": "nullOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal oxide nulloparticles have been widely utilized for the fabrication of functional gas sensors to determine various flammable, explosive, toxic, and harmful gases due to their advantages of low cost, fast response, and high sensitivity. However, metal oxide-based gas sensors reveal the shortcomings of high operating temperature, high power requirement, and low selectivity, which limited their rapid development in the fabrication of high-performance gas sensors. The combination of metal oxides with two-dimensional (2D) nullomaterials to construct a heterostructure can hybridize the advantages of each other and overcome their respective shortcomings, thereby improving the sensing performance of the fabricated gas sensors. In this review, we present recent advances in the fabrication of metal oxide-, 2D nullomaterials-, as well as 2D material/metal oxide composite-based gas sensors with highly sensitive and selective functions. To achieve this aim, we firstly introduce the working principles of various gas sensors, and then discuss the factors that could affect the sensitivity of gas sensors. After that, a lot of cases on the fabrication of gas sensors by using metal oxides, 2D materials, and 2D material/metal oxide composites are demonstrated. Finally, we summarize the current development and discuss potential research directions in this promising topic. We believe in this work is helpful for the readers in multidiscipline research fields like materials science, nullotechnology, chemical engineering, environmental science, and other related aspects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 982, "DOI": "10.3390/nullo12060982", "DOI Link": "http://dx.doi.org/10.3390/nullo12060982", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000774488900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Liu, S; Li, Y; Yan, MJ; Lin, HJ; Chen, JR; Liu, SJ; Wang, SB; Duan, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xi-Lin; Liu, Shiang; Li, Yu; Yan, Minjia; Lin, Hongjun; Chen, Jianrong; Liu, Shoujie; Wang, Shaobin; Duan, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directional and Ultrafast Charge Transfer in Oxygen-Vacancy-Rich ZnO@Single-Atom Cobalt Core-Shell Junction for Photo-Fenton-Like Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In photosynthesis, solar energy is harvested by photosensitizers, and then, the excited electrons transfer via a Z-Scheme mode to enzymatic catalytic centers to trigger redox reactions. Herein, we constructed a core-shell Z-scheme heterojunction of semiconductor@single-atom catalysts (SACs). The oxygen-vacancy-rich ZnO core and single-atom Co-N-4 sites supported on nitrogen-rich carbon shell (SA-Co-CN) act as the photosensitizer and the enzyme-mimicking active centers, respectively. Driven by built-in electric field across the heterojunction, photoexcited electrons could rapidly (2 ps) transfer from the n-type ZnO core to the p-type SA-Co-CN shell, finally boosting the catalytic performance of the surface-exposed single-atom Co-N-4 sites for peroxymonosulfate (PMS) activation under light irradiation. The synergies between photocatalysis and heterogeneous Fenton-like reaction lead to phenomenally enhanced production of various reactive oxygen species for rapid degradation of various microcontaminullts in water. Experimental and theoretical results validate that the interfacial coupling of SA-Co-CN with ZnO greatly facilitates PMS adsorption and activation by reducing the adsorption energy and enhancing the cascade electron transfer processes for the photo-Fenton-like reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2023, "Volume": 62, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202305639", "DOI Link": "http://dx.doi.org/10.1002/anie.202305639", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011077300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HS; Yu, Z; Kong, X; Huang, WL; Zhang, ZW; Mackanic, DG; Huang, XY; Qin, J; Bao, ZN; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hansen; Yu, Zhiao; Kong, Xian; Huang, William; Zhang, Zewen; Mackanic, David G.; Huang, Xinyi; Qin, Jian; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-Solvent Li-Ion Solvation Enables High-Performance Li-Metal Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel electrolyte designs to further enhance the lithium (Li) metal battery cyclability are highly desirable. Here, fluorinated 1,6-dimethoxyhexane (FDMH) is designed and synthesized as the solvent molecule to promote electrolyte stability with its prolonged -CF2- backbone. Meanwhile, 1,2-dimethoxyethane is used as a co-solvent to enable higher ionic conductivity and much reduced interfacial resistance. Combining the dual-solvent system with 1 m lithium bis(fluorosulfonyl)imide (LiFSI), high Li-metal Coulombic efficiency (99.5%) and oxidative stability (6 V) are achieved. Using this electrolyte, 20 mu m Li||NMC batteries are able to retain approximate to 80% capacity after 250 cycles and Cu||NMC anode-free pouch cells last 120 cycles with 75% capacity retention under approximate to 2.1 mu L mAh(-1) lean electrolyte conditions. Such high performances are attributed to the anion-derived solid-electrolyte interphase, originating from the coordination of Li-ions to the highly stable FDMH and multiple anions in their solvation environments. This work demonstrates a new electrolyte design strategy that enables high-performance Li-metal batteries with multisolvent Li-ion solvation with rationally optimized molecular structure and ratio.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 33, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2008619, "DOI": "10.1002/adma.202008619", "DOI Link": "http://dx.doi.org/10.1002/adma.202008619", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648495100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, WD; Li, YT; Xin, S; Goodenough, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Weidong; Li, Yutao; Xin, Sen; Goodenough, John B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rechargeable Sodium All-Solid-State Battery", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A reversible plating/stripping of a dendrite-free metallic-sodium anode with a reduced anode/ceramic interfacial resistance is created by a thin interfacial interlayer formed in situ or by the introduction of a dry polymer film. Wetting of the sodium on the interfacial interlayer suppresses dendrite formation and growth at different discharge/charge C-rates. All-solid-state batteries were obtained with a high cycling stability and Coulombic efficiency at 65 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 52, "End Page": 57, "Article Number": null, "DOI": "10.1021/acscentsci.6b00321", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.6b00321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392499900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Liu, JX; Allard, LF; Lee, S; Liu, JL; Li, H; Wang, JQ; Wang, J; Oh, S; Li, W; Flytzani-Stephanopoulos, M; Shen, MQ; Goldsmith, BR; Yang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hui; Liu, Jin-Xun; Allard, Lawrence F.; Lee, Sungsik; Liu, Jilei; Li, Hang; Wang, Jianqiang; Wang, Jun; Oh, Se H.; Li, Wei; Flytzani-Stephanopoulos, Maria; Shen, Meiqing; Goldsmith, Bryan R.; Yang, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt1 atoms", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the maximized metal dispersion offered by single-atom catalysts, further improvement of intrinsic activity can be hindered by the lack of neighboring metal atoms in these systems. Here we report the use of isolated Pt-1 atoms on ceria as seeds to develop a Pt-O-Pt ensemble, which is well-represented by a Pt8O14 model cluster that retains 100% metal dispersion. The Pt atom in the ensemble is 100-1000 times more active than their single-atom Pt-1/CeO2 parent in catalyzing the low-temperature CO oxidation under oxygen-rich conditions. Rather than the Pt-O-Ce interfacial catalysis, the stable catalytic unit is the Pt-O-Pt site itself without participation of oxygen from the 10-30 nm-size ceria support. Similar Pt-O-Pt sites can be built on various ceria and even alumina, distinguishable by facile activation of oxygen through the paired Pt-O-Pt atoms. Extending this design to other reaction systems is a likely outcome of the findings reported here.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3808, "DOI": "10.1038/s41467-019-11856-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11856-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482398900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sivadas, N; Okamoto, S; Xu, XD; Fennie, CJ; Xiao, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sivadas, Nikhil; Okamoto, Satoshi; Xu, Xiaodong; Fennie, Craig J.; Xiao, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking-Dependent Magnetism in Bilayer CrI3", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the connection between the stacking order and magnetic properties of bilayer CrI3 using first principles calculations. We show that the stacking order defines the magnetic ground state. By changing the interlayer stacking order, one can tune the interlayer exchange interaction between antiferromagnetic and ferromagnetic. To measure the predicted stacking-dependent magnetism, we propose using linear magnetoelectric effect. Our results not only gives a possible explanation for the observed anti-ferromagnetism in bilayer CrI3 but also have direct implications in heterostructures made of two-dimensional magnets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 532, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 18, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7658, "End Page": 7664, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b03321", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b03321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453488800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, QJ; Zhou, M; Yang, MY; Yang, QF; Zhang, ZX; Shi, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qijun; Zhou, Ming; Yang, Mingyang; Yang, Qingfeng; Zhang, Zhixun; Shi, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Induction of long-lived room temperature phosphorescence of carbon dots by water in hydrogen-bonded matrices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorescence shows great potential for application in bioimaging and ion detection because of its long-lived luminescence and high signal-to-noise ratio, but establishing phosphorescence emission in aqueous environments remains a challenge. Herein, we present a general design strategy that effectively promotes phosphorescence by utilising water molecules to construct hydrogen-bonded networks between carbon dots (CDs) and cyanuric acid (CA). Interestingly, water molecules not only cause no phosphorescence quenching but also greatly enhance the phosphorescence emission. This enhancement behaviour can be explained by the fact that the highly ordered bound water on the CA particle surface can construct robust bridge-like hydrogen-bonded networks between the CDs and CA, which not only effectively rigidifies the C=O bonds of the CDs but also greatly enhances the rigidity of the entire system. In addition, the CD-CA suspension exhibits a high phosphorescence lifetime (687 ms) and is successfully applied in ion detection based on its visible phosphorescence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 734, "DOI": "10.1038/s41467-018-03144-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03144-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425593800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Volonakis, G; Haghighirad, AA; Milot, RL; Sio, WH; Filip, MR; Wenger, B; Johnston, MB; Herz, LM; Snaith, HJ; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Volonakis, George; Haghighirad, Amir Abbas; Milot, Rebecca L.; Sio, Weng H.; Filip, Marina R.; Wenger, Bernard; Johnston, Michael B.; Herz, Laura M.; Snaith, Henry J.; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cs2InAgCl6: A New Lead-Free Halide Double Perovskite with Direct Band Gap", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A(2)BB'X-6 halide double perovskites based on bismuth and silver have recently been proposed as potential environmentally friendly alternatives to lead-based hybrid halide perovskites. In particular, Cs2BiAgX6 (X = Cl, Br) have been synthesized and found to exhibit band gaps in the visible range. However, the band gaps of these compounds are indirect, which is not ideal for applications in thin film photovoltaics. Here, we propose a new class of halide double perovskites, where the B3+ and B+ cations are In3+ and Ag+, respectively. Our first-principles calculations indicate that the hypothetical compounds Cs2InAgX6 (X = Cl, Br, I) should exhibit direct band gaps between the visible (I) and the ultraviolet (Cl). Based on these predictions, we attempt to synthesize Cs2InAgCl6 and Cs2InAgBr6, and we succeed to form the hitherto unknown double perovskite Cs2InAgCl6. X-ray diffraction yields a double perovskite structure with space group Fm3m. The measured band gap is 3.3 eV, and the compound is found to be photosensitive and turns reversibly from white to orange under ultraviolet illumination. We also perform an empirical analysis of the stability of Cs2InAgX6 and their mixed halides based on Goldschmidts rules, and we find that it should also be possible to form Cs2InAg(Cl1xBrx)(6) for x < 1. The synthesis of mixed halides will open the way to the development of lead-free double perovskites with direct and tunable band gaps.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 839, "Times Cited, All Databases": 887, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2017, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 772, "End Page": 778, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b02682", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b02682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394484100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Adamovich, I; Agarwal, S; Ahedo, E; Alves, LL; Baalrud, S; Babaeva, N; Bogaerts, A; Bourdon, A; Bruggeman, PJ; Canal, C; Choi, EH; Coulombe, S; Donkó, Z; Graves, DB; Hamaguchi, S; Hegemann, D; Hori, M; Kim, HH; Kroesen, GMW; Kushner, MJ; Laricchiuta, A; Li, X; Magin, TE; Thagard, SM; Miller, V; Murphy, AB; Oehrlein, GS; Puac, N; Sankaran, RM; Samukawa, S; Shiratani, M; Simek, M; Tarasenko, N; Terashima, K; Thomas, E; Trieschmann, J; Tsikata, S; Turner, MM; van der Walt, IJ; van de Sanden, MCM; von Woedtke, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Adamovich, I; Agarwal, S.; Ahedo, E.; Alves, L. L.; Baalrud, S.; Babaeva, N.; Bogaerts, A.; Bourdon, A.; Bruggeman, P. J.; Canal, C.; Choi, E. H.; Coulombe, S.; Donko, Z.; Graves, D. B.; Hamaguchi, S.; Hegemann, D.; Hori, M.; Kim, H-H; Kroesen, G. M. W.; Kushner, M. J.; Laricchiuta, A.; Li, X.; Magin, T. E.; Thagard, S. Mededovic; Miller, V; Murphy, A. B.; Oehrlein, G. S.; Puac, N.; Sankaran, R. M.; Samukawa, S.; Shiratani, M.; Simek, M.; Tarasenko, N.; Terashima, K.; Thomas, E., Jr.; Trieschmann, J.; Tsikata, S.; Turner, M. M.; van der Walt, I. J.; van de Sanden, M. C. M.; von Woedtke, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The 2022 Plasma Roadmap: low temperature plasma science and technology", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The 2022 Roadmap is the next update in the series of Plasma Roadmaps published by Journal of Physics D with the intent to identify important outstanding challenges in the field of low-temperature plasma (LTP) physics and technology. The format of the Roadmap is the same as the previous Roadmaps representing the visions of 41 leading experts representing 21 countries and five continents in the various sub-fields of LTP science and technology. In recognition of the evolution in the field, several new topics have been introduced or given more prominence. These new topics and emphasis highlight increased interests in plasma-enabled additive manufacturing, soft materials, electrification of chemical conversions, plasma propulsion, extreme plasma regimes, plasmas in hypersonics, data-driven plasma science and technology and the contribution of LTP to combat COVID-19. In the last few decades, LTP science and technology has made a tremendously positive impact on our society. It is our hope that this roadmap will help continue this excellent track record over the next 5-10 years.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2022, "Volume": 55, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 373001, "DOI": "10.1088/1361-6463/ac5e1c", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/ac5e1c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821410400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, HN; Zhao, ZG; Cai, YD; Zhou, JJ; Hua, WD; Chen, L; Wang, L; Zhang, JQ; Han, D; Liu, MJ; Jiang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Hainull; Zhao, Ziguang; Cai, Yudong; Zhou, Jiajia; Hua, Wenda; Chen, Lie; Wang, Li; Zhang, Jianqi; Han, Dong; Liu, Mingjie; Jiang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adaptive and freeze-tolerant heteronetwork organohydrogels with enhanced mechanical stability over a wide temperature range", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many biological organisms with exceptional freezing tolerance can resist the damages to cells from extra-/intracellular ice crystals and thus maintain their mechanical stability at subzero temperatures. Inspired by the freezing tolerance mechanisms found in nature, here we report a strategy of combining hydrophilic/oleophilic heteronetworks to produce self-adaptive, freeze-tolerant and mechanically stable organohydrogels. The organohydrogels can simultaneously use water and oil as a dispersion medium, and quickly switch between hydrogel-and organogel-like behaviours in response to the nature of the surrounding phase. Accordingly, their surfaces display unusual adaptive dual superlyophobic in oil/water system (that is, they are superhydrophobic under oil and superoleophobic under water). Moreover, the organogel component can inhibit the ice crystallization of the hydrogel component, thus enhancing the mechanical stability of organohydrogel over a wide temperature range (-78 to 80 degrees C). The organohydrogels may have promising applications in complex and harsh environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15911, "DOI": "10.1038/ncomms15911", "DOI Link": "http://dx.doi.org/10.1038/ncomms15911", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403877400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muravev, V; Parastaev, A; van den Bosch, Y; Ligt, B; Claes, N; Bals, S; Kosinov, N; Hensen, EJM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muravev, Valery; Parastaev, Alexander; van den Bosch, Yannis; Ligt, Bianca; Claes, Nathalie; Bals, Sara; Kosinov, Nikolay; Hensen, Emiel J. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size of cerium dioxide support nullocrystals dictates reactivity of highly dispersed palladium catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic performance of heterogeneous catalysts can be tuned by modulation of the size and structure of supported transition metals, which are typically regarded as the active sites. In single-atom metal catalysts, the support itself can strongly affect the catalytic properties. Here, we demonstrate that the size of cerium dioxide (CeO2) support governs the reactivity of atomically dispersed palladium (Pd) in carbon monoxide (CO) oxidation. Catalysts with small CeO2 nullocrystals (similar to 4 nullometers) exhibit unusually high activity in a CO-rich reaction feed, whereas catalysts with medium-size CeO2 (similar to 8 nullometers) are preferred for lean conditions. Detailed spectroscopic investigations reveal support size-dependent redox properties of the Pd-CeO2 interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2023, "Volume": 380, "Issue": 6650, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1174, "End Page": 1178, "Article Number": null, "DOI": "10.1126/science.adf9082", "DOI Link": "http://dx.doi.org/10.1126/science.adf9082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001010846100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, AZ; Ma, XQ; Huang, SY; Wu, YS; Jia, MJ; Shi, YM; Liu, Y; Wangyang, PH; He, L; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Aizhao; Ma, Xiaoqin; Huang, Shengying; Wu, Youshen; Jia, Mengjun; Shi, Yeming; Liu, Ya; Wangyang, Peihua; He, Ling; Liu, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CsPbBr3 Perovskite nullocrystal Grown on MXene nullosheets for Enhanced Photoelectric Detection and Photocatalytic CO2 Reduction", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic CsPbX3 (X = Cl, Br or I) perovskite nullocrystals have attracted extensive interest recently due to their exceptional optoelectronic properties. In an effort to improve the charge separation and transfer following efficient exciton generation in such nullocrystals, novel functional nullocomposites were synthesized by the in situ growth of CsPbBr3 perovskite nullocrystals on two-dimensional MXene nullosheets. Efficient excited state charge transfer occurs between CsPbBr3 NCs and MXene nullosheets, as indicated by significant photoluminescence (PL) quenching and much shorter PL decay lifetimes compared with pure CsPbBr3NCs. The as-obtained CsPbBr3/MXene nullocomposites demonstrated increased photocurrent generation in response to visible light and X-ray illumination, attesting to the potential application of these heterostructure nullocomposites for photoelectric detection. The efficient charge transfer also renders the CsPbBr3/MXene nullocomposite an active photocatalyst for the reduction of CO2 to CO and CH4. This work provides a guide for exploration of perovskite materials in next-generation optoelectronics, such as photoelectric detectors or photocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2019, "Volume": 10, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6590, "End Page": 6597, "Article Number": null, "DOI": "10.1021/acs.jpclett.9b02605", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.9b02605", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495805100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lázaro, IA; Wells, CJR; Forgan, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lazaro, Isabel; Wells, Connor J. R.; Forgan, Ross S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multivariate Modulation of the Zr MOF UiO-66 for Defect-Controlled Combination Anticancer Drug Delivery", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are emerging as leading candidates for nulloscale drug delivery, as a consequence of their high drug capacities, ease of functionality, and the ability to carefully engineer key physical properties. Despite many anticancer treatment regimens consisting of a cocktail of different drugs, examples of delivery of multiple drugs from one MOF are rare, potentially hampered by difficulties in postsynthetic loading of more than one cargo molecule. Herein, we report a new strategy, multivariate modulation, which allows incorporation of up to three drugs in the Zr MOF UiO-66 by defect-loading. The drugs are added to one-pot solvothermal synthesis and are distributed throughout the MOF at defect sites by coordination to the metal clusters. This tight binding comes with retention of crystallinity and porosity, allowing a fourth drug to be postsynthetically loaded into the MOFs to yield nulloparticles loaded with cocktails of drugs that show enhancements in selective anticancer cytotoxicity against MCF-7 breast cancer cells in vitro. We believe that multivariate modulation is a significant advance in the application of MOFs in biomedicine, and anticipate the protocol will also be adopted in other areas of MOF chemistry, to easily produce defective MOFs with arrays of highly functionalised pores for potential application in gas separations and catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 59, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5211, "End Page": 5217, "Article Number": null, "DOI": "10.1002/anie.201915848", "DOI Link": "http://dx.doi.org/10.1002/anie.201915848", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510801400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QL; Luo, M; Han, JH; Peng, W; Zhao, Y; Chen, DC; Peng, M; Liu, J; de Groot, FMF; Tan, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qiuli; Luo, Min; Han, Jiuhui; Peng, Wei; Zhao, Yang; Chen, Dechao; Peng, Ming; Liu, Ji; de Groot, Frank M. F.; Tan, Yongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying Electrocatalytic Sites of the nulloporous Copper-Ruthenium Alloy for Hydrogen Evolution Reaction in Alkaline Electrolyte", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen production from electrochemical water splitting is a promising route to pursue clean and sustainable energy sources. Here, a three-dimensional nulloporous Cu-Ru alloy is prepared as a high-performance platinum-free catalyst for hydrogen evolution reaction (HER) by a dealloying process. Significantly, the optimized nulloporous alloy Cu53Ru47 exhibits remarkable catalytic activity for HER with nearly zero onset overpotential and ultralow Tafel slopes (similar to 30 and similar to 35 mV dec(-1)) in both alkaline and neutral electrolytes, achieving a catalytic current density of 10 mA cm(-2) at low overpotentials of similar to 15 and similar to 41 mV, respectively. Operando X-ray absorption spectroscopy experiments, in conjunction with DFT simulations, reveal that the incorporation of Ru atoms into the Cu matrix not only accelerates the reaction step rates of water adsorption and activation but also optimizes the hydrogen bonding energy on Cu and Ru active sites, improving the intrinsic activity for HER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 192, "End Page": 199, "Article Number": null, "DOI": "10.1021/acsenergylett.9b02374", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02374", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507145900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TF; Feng, DW; Chen, YP; Zou, LF; Bosch, M; Yuan, S; Wei, ZW; Fordham, S; Wang, KC; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tian-Fu; Feng, Dawei; Chen, Ying-Pin; Zou, Lanfang; Bosch, Mathieu; Yuan, Shuai; Wei, Zhangwen; Fordham, Stephen; Wang, Kecheng; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal-Organic Frameworks with High Surface Area", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Through a topology-guided strategy, a series of Zr-6-containing isoreticular porphyrinic metalorganic frameworks (MOFs), PCN-228, PCN-229, and PCN-230, with ftw-a topology were synthesized using the extended porphyrinic linkers. The bulky porphyrin ring ligand effectively prevents the network interpenetration which often appears in MOFs with increased linker length. The pore apertures of the structures range from 2.5 to 3.8 nm, and PCN-229 demonstrates the highest porosity and BET surface area among the previously reported Zr-MOFs. Additionally, by changing the relative direction of the terminal phenyl rings, this series replaces a Zr-8 cluster with a smaller Zr-6 cluster in a topologically identical framework. The high connectivity of the Zr-6 cluster yields frameworks with enhanced stability despite high porosity and ultralarge linker. As a representative example, PCN-230, constructed with the most extended porphyrinic linker, shows excellent stability in aqueous solutions with pH values ranging from 0 to 12 and demonstrates one of the highest pH tolerances among all porphyrinic MOFs. This work not only presents a successful example of rational design of MOFs with desired topology, but also provides a strategy for construction of stable mesoporous MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 137, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 413, "End Page": 419, "Article Number": null, "DOI": "10.1021/ja5111317", "DOI Link": "http://dx.doi.org/10.1021/ja5111317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348483500070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, F; Yu, DJ; Ma, WB; Xu, XB; Cai, B; Yang, YM; Liu, SN; He, LH; Ke, YB; Lan, S; Choy, KL; Zeng, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Fei; Yu, Dejian; Ma, Wenbo; Xu, Xiaobao; Cai, Bo; Yang, Yang Michael; Liu, Sinull; He, Lunhua; Ke, Yubin; Lan, Si; Choy, Kwang-Leong; Zeng, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shining Emitter in a Stable Host: Design of Halide Perovskite Scintillators for X-ray Imaging from Commercial Concept", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskite (HP) nullocrystals (NCs) have recently shown great potential for X-ray detection and imaging. However, the practical application still has a long way to go with many technical requirements waiting to be fulfilled, including structure optimization, stability enhancement, and cost reduction. A design principle in this beginning stage is urgently needed but still lacking. Herein, with an emitter-in-matrix principle refined from commercial scintillators, CsPbBr3@Cs4PbBr6 with emissive CsPbBr3 NCs embedded inside a solid-state Cs4PbBr6 host is subjected to X-ray sensing and imaging. The Cs4PbBr6 matrix not only enhances the attenuation of X-rays but also dramatically improves the stability of CsPbBr3 NCs. A favorable optical design with the Cs4PbBr6 matrix being transparent to the emission from CsPbBr3 NCs enables efficient light output. As a result, stable and sensitive scintillation response to X-ray signals is demonstrated with superior linearity and ultrahigh time resolution. In order to show the huge potential for practical applications, X-ray imaging using a large-area film (360 mm x 240 mm) by the blade-coating technique is carried out to obtain a high-quality image of interior structures invisible to the human eye. In addition to the above advantages in optics, CsPbBr3@Cs4PbBr6 also enjoys facile solution synthesis with large scalability, excellent repeatability, and low cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2020, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5183, "End Page": 5193, "Article Number": null, "DOI": "10.1021/acsnullo.9b06114", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b06114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537682300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, XX; Lin, YH; Zeng, J; Ren, ZH; Lin, ZJ; Mu, YB; Qiu, YJ; Yu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Xixi; Lin, Yanhong; Zeng, Jie; Ren, Zhonghua; Lin, Zijia; Mu, Yongbiao; Qiu, Yejun; Yu, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene/MoS2/FeCoNi(OH)x and Graphene/MoS2/FeCoNiPx multilayer-stacked vertical nullosheets on carbon fibers for highly efficient overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of excellent and cheap electrocatalysts for water electrolysis is of great significance for application of hydrogen energy. Here, we show a highly efficient and stable oxygen evolution reaction (OER) catalyst with multilayer-stacked hybrid structure, in which vertical graphene nullosheets (VGSs), MoS2 nullosheets, and layered FeCoNi hydroxides (FeCoNi(OH)(x)) are successively grown on carbon fibers (CF/VGSs/MoS2/FeCoNi(OH)(x)). The catalyst exhibits excellent OER performance with a low overpotential of 225 and 241mV to attain 500 and 1000mAcm(-2) and small Tafel slope of 29.2mV dec(-1). Theoretical calculation indicates that compositing of FeCoNi(OH)(x) with MoS2 could generate favorable electronic structure and decrease the OER overpotential, promoting the electrocatalytic activity. An alkaline water electrolyzer is established using CF/VGSs/MoS2/FeCoNi(OH)(x) anode for overall water splitting, which generates a current density of 100mAcm(-2) at 1.59V with excellent stability over 100h. Our highly efficient catalysts have great prospect for water electrolysis. While water-splitting electrocatalysis offers a renewable means for carbon-neutral energy production, it is a challenge to design efficient, active, and stable catalysts. Here, authors prepare multilayer composite nullosheet materials as bifunctional water-splitting electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1380, "DOI": "10.1038/s41467-021-21742-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21742-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626586400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, CS; Yuan, YF; Zhang, B; Tang, LB; Xiao, B; He, ZJ; Zheng, JC; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Changsheng; Yuan, Yifei; Zhang, Bao; Tang, Linbo; Xiao, Bin; He, Zhenjiang; Zheng, Junchao; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene Wrapped FeSe2 nullo-Microspheres with High Pseudocapacitive Contribution for Enhanced Na-Ion Storage", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pseudocapacitance is a Faradaic process that involves surface or near surface redox reactions. Increasing the pseudocapacitive contribution is one of the most effective means to improve the rate performance of electrode materials. In this study, graphene oxide is used as a template to in situ synthesize burr globule-like FeSe2/graphene hybrid (B-FeSe2/G) using a facile one-step hydrothermal method. Structural characterization demonstrates that graphene layers not only wrap the surfaces of FeSe2 particles, but also stretch into the interior of these particles, as a result of which the unique nullo-microsphere structure is successfully established. When serving as anode material for Na-ion batteries, B-FeSe2/G hybrid displays high electrochemical performance in the voltage range of 0.5-2.9 V. The B-FeSe2/G hybrid has high reversible capacity of 521.6 mAh center dot g(-1) at 1.0 A g(-1). Meanwhile, after 400 cycles, high discharge capacity of 496.3 mAh g(-1) is obtained at a rate of 2.5 A g(-1), with a high columbic efficiency of 96.6% and less than 1.0% loss of discharge capacity. Even at the ultrahigh rate of 10 A g(-1), a specific capacity of 316.8 mAh g(-1) can be achieved. Kinetic analyses reveal that the excellent performance of the B-FeSe2/G hybrid is largely attributed to the high pseudocapacitive contribution induced by the special nullo-micro structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2019, "Volume": 9, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900356, "DOI": "10.1002/aenm.201900356", "DOI Link": "http://dx.doi.org/10.1002/aenm.201900356", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468778800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, LH; Chen, QM; Zhang, ZX; Wu, D; Yuan, HY; Li, YY; Qarony, W; Lau, SP; Luo, LB; Tsang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Long-Hui; Chen, Qing-Ming; Zhang, Zhi-Xiang; Wu, Di; Yuan, Huiyu; Li, Yan-Yong; Qarony, Wayesh; Lau, Shu Ping; Luo, Lin-Bao; Tsang, Yuen Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multilayered PdSe2/Perovskite Schottky Junction for Fast, Self-Powered, Polarization-Sensitive, Broadband Photodetectors, and Image Sensor Application", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Group-10 transition metal dichalcogenides (TMDs) with distinct optical and tunable electrical properties have exhibited great potential for various optoelectronic applications. Herein, a self-powered photodetector is developed with broadband response ranging from deep ultraviolet to near-infrared by combining FA(1-x)Cs(x)PbI(3) perovskite with PdSe2 layer, a newly discovered TMDs material. Optoelectronic characterization reveals that the as-assembled PdSe2/perovskite Schottky junction is sensitive to light illumination ranging from 200 to 1550 nm, with the highest sensitivity centered at approximate to 800 nm. The device also shows a large on/off ratio of approximate to 10(4), a high responsivity (R) of 313 mA W-1, a decent specific detectivity (D*) of approximate to 10(13) Jones, and a rapid response speed of 3.5/4 mu s. These figures of merit are comparable with or much better than most of the previously reported perovskite detectors. In addition, the PdSe2/perovskite device exhibits obvious sensitivity to polarized light, with a polarization sensitivity of 6.04. Finally, the PdSe2/perovskite detector can readily record five P, O, L, Y, and U images sequentially produced by 808 nm. These results suggest that the present PdSe2/perovskite Schottky junction photodetectors may be useful for assembly of optoelectronic system applications in near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 6, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901134, "DOI": "10.1002/advs.201901134", "DOI Link": "http://dx.doi.org/10.1002/advs.201901134", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479248500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Liu, X; Wang, L; Feng, XN; Ren, DS; Wu, Y; Xu, GL; Lu, LG; Hou, JX; Zhang, WF; Wang, YL; Xu, WQ; Ren, Y; Wang, ZF; Huang, JY; Meng, XF; Han, XB; Wang, HW; He, XM; Chen, ZH; Amine, K; Ouyang, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yan; Liu, Xiang; Wang, Li; Feng, Xuning; Ren, Dongsheng; Wu, Yu; Xu, Guiliang; Lu, Languang; Hou, Junxian; Zhang, Weifeng; Wang, Yongling; Xu, Wenqian; Ren, Yang; Wang, Zaifa; Huang, Jianyu; Meng, Xiangfeng; Han, Xuebing; Wang, Hewu; He, Xiangming; Chen, Zonghai; Amine, Khalil; Ouyang, Minggao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal runaway mechanism of lithium-ion battery with LiNi0.8Mn0.1Co0.1O2 cathode materials", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Battery safety is critical to the application of lithium-ion batteries, especially for high energy density battery applied in electric vehicles. In this paper, the thermal runaway mechanism of LiNi0.8Co0.1Mn0.1O2 based lithium-ion battery is illustrated. And the reaction between cathode and flammable electrolyte is proved as the trigger of the thermal runaway accident. In detail, with differential scanning calorimeter tests for battery components, the material combination contributing to thermal runaway was decoupled. Characterization with synchrotron X-ray diffraction and transmission electron microscopy with in-situ heating proved that the vigorous exothermic reaction is initiated by the liberated oxygen species. The pulse of highly active oxygen species reacted quickly with the electrolyte, accompanied with tremendous heat release, which accelerated the phase transformation of charged cathode. Also, the mechanism is verified by a confirmatory experiment when the highly active oxygen species were trapped by anion receptor, the phase transformation of the charged cathode was inhibited. Clarifying the thermal runaway mechanism of LiNi0.8Co0.1Mn0.1 based lithium-ion battery may light the way to battery chemistries of both high energy density and high safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 85, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105878, "DOI": "10.1016/j.nulloen.2021.105878", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2021.105878", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663441600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YP; Liang, X; Gu, L; Zhang, Y; Li, GD; Zou, XX; Chen, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yipu; Liang, Xiao; Gu, Lin; Zhang, Yu; Li, Guo-Dong; Zou, Xiaoxin; Chen, Jie-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion engineering towards efficient oxygen evolution electrodes with stable catalytic activity for over 6000 hours", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although a number of nonprecious materials can exhibit catalytic activity approaching (sometimes even outperforming) that of iridium oxide catalysts for the oxygen evolution reaction, their catalytic lifetimes rarely exceed more than several hundred hours under operating conditions. Here we develop an energy-efficient, cost-effective, scaled-up corrosion engineering method for transforming inexpensive iron substrates (e.g., iron plate and iron foam) into highly active and ultrastable electrodes for oxygen evolution reaction. This synthetic method is achieved via a desired corrosion reaction of iron substrates with oxygen in aqueous solutions containing divalent cations (e.g., nickel) at ambient temperature. This process results in the growth on iron substrates of thin film nullosheet arrays that consist of iron-containing layered double hydroxides, instead of rust. This inexpensive and simple manufacturing technique affords iron-substrate-derived electrodes possessing excellent catalytic activities and activity retention for over 6000 hours at 1000 mA cm(-2) current densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 495, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2609, "DOI": "10.1038/s41467-018-05019-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05019-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437252300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, WL; null, HY; Hong, JH; Chen, YM; Zhu, C; Liang, Z; Ma, XY; Ni, ZH; Jin, CH; Zhang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Wanglin; null, Haiyan; Hong, Jinhua; Chen, Yuming; Zhu, Chen; Liang, Zheng; Ma, Xiangyang; Ni, Zhenhua; Jin, Chuanhong; Zhang, Ze", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There have been continuous efforts to seek novel functional two-dimensional semiconductors with high performance for future applications in nulloelectronics and optoelectronics. In this work, we introduce a successful experimental approach to fabricate monolayer phosphorene by mechanical cleavage and a subsequent Ar+ plasma thinning process. The thickness of phosphorene is unambiguously determined by optical contrast spectra combined with atomic force microscopy (AFM). Raman spectroscopy is used to characterize the pristine and plasma-treated samples. The Raman frequency of the A(2g) mode stiffens, and the intensity ratio of A(2g) to A(1g) modes shows a monotonic discrete increase with the decrease of phosphorene thickness down to a monolayer. All those phenomena can be used to identify the thickness of this novel two-dimensional semiconductor. This work on monolayer phosphorene fabrication and thickness determination will facilitate future research on phosphorene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 613, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 853, "End Page": 859, "Article Number": null, "DOI": "10.1007/s12274-014-0446-7", "DOI Link": "http://dx.doi.org/10.1007/s12274-014-0446-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339892000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, MY; He, MB; Zhang, HG; Jian, J; Pan, Y; Liu, XY; Chen, LF; Meng, XY; Chen, H; Li, ZH; Xiao, X; Yu, SH; Yu, SY; Cai, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Mengyue; He, Mingbo; Zhang, Hongguang; Jian, Jian; Pan, Ying; Liu, Xiaoyue; Chen, Lifeng; Meng, Xiangyu; Chen, Hui; Li, Zhaohui; Xiao, Xi; Yu, Shaohua; Yu, Siyuan; Cai, Xinlun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance coherent optical modulators based on thin-film lithium niobate platform", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The coherent transmission technology using digital signal processing and advanced modulation formats, is bringing networks closer to the theoretical capacity limit of optical fibres, the Shannon limit. The in-phase/quadrature electro-optic modulator that encodes information on both the amplitude and the phase of light, is one of the underpinning devices for the coherent transmission technology. Ideally, such modulator should feature a low loss, low drive voltage, large bandwidth, low chirp and compact footprint. However, these requirements have been only met on separate occasions. Here, we demonstrate integrated thin-film lithium niobate in-phase/quadrature modulators that fulfil these requirements simultaneously. The presented devices exhibit greatly improved overall performance (half-wave voltage, bandwidth and optical loss) over traditional lithium niobate counterparts, and support modulation data rate up to 320 Gbit s(-1). Our devices pave new routes for future high-speed, energy-efficient, and cost-effective communication networks. In-phase/quadrature (IQ) electro-optic modulators are underpinning devices for coherent transmission technology. Here the authors present IQ modulators in the lithium-niobate-on-insulator platform, which provide improved overall performance and advanced modulation formats for future coherent transmission systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3911, "DOI": "10.1038/s41467-020-17806-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17806-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561120500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JS; Heo, JM; Park, GS; Woo, SJ; Cho, C; Yun, HJ; Kim, DH; Park, J; Lee, SC; Park, SH; Yoon, E; Greenham, NC; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Joo Sung; Heo, Jung-Min; Park, Gyeong-Su; Woo, Seung-Je; Cho, Changsoon; Yun, Hyung Joong; Kim, Dong-Hyeok; Park, Jinwoo; Lee, Seung-Chul; Park, Sang-Hwan; Yoon, Eojin; Greenham, Neil C.; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-bright, efficient and stable perovskite light-emitting diodes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites are attracting a lot of attention as next-generation lighte-mitting materials owing to their excellent emission properties, with narrow band emission(1-4). However, perovskite light-emitting diodes (PeLEDs), irrespective of their material type (polycrystals or nullocrystals), have not realized high luminullce, high efficiency and long lifetime simultaneously, as they are influenced by intrinsic limitations related to the trade-off of properties between charge transport and confinement in each type of perovskite material(5-8). Here, we report an ultra-bright, efficient and stable PeLED made of core/shell perovskite nullocrystals with a size of approximately 10 nm, obtained using a simple in situ reaction of benzylphosphonic acid (BPA) additive with three-dimensional (3D) polycrystalline perovskite films, without separate synthesis processes. During the reaction, large 3D crystals are split into nullocrystals and the BPA surroundsthe nullocrystals, achieving strong carrier confinement. The BPA shell passivates the undercoordinated lead atoms by forming covalent bonds, and there by greatly reduces the trap density while maintaining good charge-transport properties for the 3D perovskites. We demonstrate simultaneously efficient, bright and stable PeLEDs that have a maximum brightness of approximately 470,000 cd m(-2), maximum external quantum efficiency of 28.9% (average = 25.2 +/- 1.6% over 40 devices), maximum current efficiency of 151 cd A(-1) and half-lifetime of 520 hat 1,000 cd m(-)(2) (estimated half-lifetime >30,000 h at 100 cd m(-2)). Our work sheds light on the possibility that PeLEDs can be commercialized in the future display industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 594, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2022, "Volume": 611, "Issue": 7937, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 688, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05304-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05304-w", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000880580300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SC; Chen, ZH; Siahrostami, S; Kim, TR; Nordlund, D; Sokaras, D; Nowak, S; To, JWF; Higgins, D; Sinclair, R; Norskov, JK; Jaramillo, TF; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shucheng; Chen, Zhihua; Siahrostami, Samira; Kim, Taeho Roy; Nordlund, Dennis; Sokaras, Dimosthenis; Nowak, Stanislaw; To, John W. F.; Higgins, Drew; Sinclair, Robert; Norskov, Jens K.; Jaramillo, Thomas F.; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defective Carbon-Based Materials for the Electrochemical Synthesis of Hydrogen Peroxide", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2), an important industrial chemical, is currently produced through an energy intensive anthraquinone process that is limited to large-scale facilities. Small-scale decentralized electrochemical production of H2O2 via a two-electron oxygen reduction reaction (ORR) offers unique opportunities for sanitization applications and the purification of drinking water. The development of inexpensive, efficient, and selective catalysts for this reaction remains a challenge. Herein, we examine two different porous carbon-based electrocatalysts and show that they exhibit high selectivity for H2O2 under alkaline conditions. By rationally varying synthetic methods, we explore the effect of pore size on electrocatalytic performance. Furthermore, by means of density functional calculations, we point out the critical role of carbon defects. Our theory results show that the majority of defects in graphene are naturally selective for the two-electron reduction of O-2 to H2O2 and we identify the types of defects with high activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 311, "End Page": 317, "Article Number": null, "DOI": "10.1021/acssuschemeng.7b02517", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.7b02517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419536800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saparov, B; Hong, F; Sun, JP; Duan, HS; Meng, WW; Cameron, S; Hill, IG; Yan, YF; Mitzi, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul; Duan, Hsin-Sheng; Meng, Weiwei; Cameron, Samuel; Hill, Ian G.; Yan, Yanfa; Mitzi, David B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thin-Film Preparation and Characterization of Cs3Sb2I9: A Lead-Free Layered Perovskite Semiconductor", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational, thin-film deposition, and characterization approaches have been used to examine the ternary halide semiconductor Cs3Sb2I9. Cs3Sb2I9 has two known structural modifications, the 0-D dimer form (space group P6(3)/mmc, no. 194) and the 2-D layered form (P (3) over bar m1, no. 164), which can be prepared via solution and solid-state or gas-phase reactions, respectively. Our computational investigations suggest that the layered form, which is a one-third Sb-deficient derivative of the ubiquitous perovskite structure, is a potential candidate for high-band gap photovoltaic (PV) applications. In this work, we describe details of a two-step deposition approach that enables the preparation of large grain (>1 mu m) and continuous thin films of the lead-free layered perovskite derivative Cs3Sb2I9. Depending on the deposition conditions, films that are c-axis oriented or randomly oriented can be obtained. The fabricated thin films show enhanced stability under ambient air, compared to methylammonium lead(II) iodide perovskite films stored under similar conditions, and an optical band gap value of 2.05 eV. Photoelectron spectroscopy study yields an ionization energy of 5.6 eV, with the valence band maximum approximately 0.85 eV below the Fermi level, indicating near-intrinsic, weakly p-type character. Density functional theory (DFT) analysis points to a nearly direct band gap for this material (less than 0.02 eV difference between the direct and indirect band gaps) and a similar high-level of absorption compared to CH3NH3PbI3. The photoluminescence peak intensity of Cs3Sb2I9 is substantially suppressed compared to that of CH3NH3PbI3, likely reflecting the presence of deep level defects that result in nonradiative recombination in the film, with computational results pointing to I-nu I-Sb, and V-I as being likely candidates. A key further finding from this study is that, despite a distinctly layered structure, the electronic transport anisotropy is less pronounced due to the high ionicity of the I atoms and the strong antibonding interactions between the Sb s lone pair states and I p states, which leads to a moderately dispersive valence band.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 662, "Times Cited, All Databases": 694, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2015, "Volume": 27, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5622, "End Page": 5632, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b01989", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b01989", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360323700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hejazi, S; Mohajernia, S; Osuagwu, B; Zoppellaro, G; Andryskova, P; Tomanec, O; Kment, S; Zboril, R; Schmuki, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hejazi, Seyedsina; Mohajernia, Shiva; Osuagwu, Benedict; Zoppellaro, Giorgio; Andryskova, Pavlina; Tomanec, Ondrej; Kment, Stepan; Zboril, Radek; Schmuki, Patrik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the Controlled Loading of Single Platinum Atoms as a Co-Catalyst on TiO2 Anatase for Optimized Photocatalytic H2 Generation", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom (SA) catalysis is a novel frontline in the catalysis field due to the often drastically enhanced specific activity and selectivity of many catalytic reactions. Here, an atomic-scale defect engineering approach to form and control traps for platinum SA sites as co-catalyst for photocatalytic H-2 generation is described. Thin sputtered TiO2 layers are used as a model photocatalyst, and compared to the more frequently used (001) anatase sheets. To form stable SA platinum, the TiO2 layers are reduced in Ar/H-2 under different conditions (leading to different but defined Ti3+-O-v surface defects), followed by immersion in a dilute hexachloroplatinic acid solution. HAADF-STEM results show that only on the thin-film substrate can the density of SA sites be successfully controlled by the degree of reduction by annealing. An optimized SA-Pt decoration can enhance the normalized photocatalytic activity of a TiO2 sputtered sample by 150 times in comparison to a conventional platinum-nulloparticle-decorated TiO2 surface. HAADF-STEM, XPS, and EPR investigation jointly confirm the atomic nature of the decorated Pt on TiO2. Importantly, the density of the relevant surface exposed defect centers-thus the density of Pt-SA sites, which play the key role in photocatalytic activity-can be precisely optimized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 32, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1908505, "DOI": "10.1002/adma.201908505", "DOI Link": "http://dx.doi.org/10.1002/adma.201908505", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517668500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, YT; Kneusels, NJH; Marbella, LE; Castillo-Martínez, E; Magusin, PCMM; Weatherup, RS; Jónsson, E; Liu, T; Paul, S; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Yanting; Kneusels, Nis-Julian H.; Marbella, Lauren E.; Castillo-Martinez, Elizabeth; Magusin, Pieter C. M. M.; Weatherup, Robert S.; Jonsson, Erlendur; Liu, Tao; Paul, Subhradip; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Fluoroethylene Carbonate and Vinylene Carbonate Based Electrolytes for Si Anodes in Lithium Ion Batteries with NMR Spectroscopy", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluoroethylene carbonate (FEC) and vinylene carbonate (VC) are widely used as electrolyte additives in lithium ion batteries. Here we analyze the solid electrolyte interphase (SEI) formed on binder-free silicon nullowire (SiNW) electrodes in pure FEC or VC electrolytes containing 1 M LiPF6 by solid-state NMR with and without dynamic nuclear polarization (DNP) enhancement. We find that the polymeric SEIs formed in pure FEC or VC electrolytes consist mainly of cross-linked poly(ethylene oxide) (PEO) and aliphatic chain functionalities along with additional carbonate and carboxylate species. The formation of branched fragments is further confirmed by C-13-C-13 correlation NMR experiments. The presence of cross-linked PEO-type polymers in FEC and VC correlates with good capacity retention and high Coulombic efficiencies of the SiNVVs. Using Si-29 DNP NMR, we are able to probe the interfacial region between SEI and the Si surface for the first time with NMR spectroscopy. Organosiloxanes form upon cycling, confirming that some of the organic SEI is covalently bonded to the Si surface. We suggest that both the polymeric structure of the SEI and the nature of its adhesion to the redox-active materials are important for electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2018, "Volume": 140, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9854, "End Page": 9867, "Article Number": null, "DOI": "10.1021/jacs.8b03408", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b03408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441475800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WH; Du, XF; Zhao, JW; Chen, Z; Li, JJ; Xie, J; Zhang, YJ; Cui, ZL; Kong, QY; Zhao, ZM; Wang, CG; Zhang, QC; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wuhai; Du, Xiaofan; Zhao, Jingwen; Chen, Zheng; Li, Jiajia; Xie, Jian; Zhang, Yaojian; Cui, Zili; Kong, Qingyu; Zhao, Zhiming; Wang, Cunguo; Zhang, Qichun; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrated Eutectic Electrolytes with Ligand-Oriented Solvation Shells for Long-Cycling Zinc-Organic Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite their intrinsic safety and cost-effectiveness, aqueous zinc (Zn)-organic batteries have been struggling with the rapid performance degradation arising from the poor reversibility of Zn anodes and the dissolution of cathodes. Here, we present a new aqueous eutectic electrolyte by coupling a hydrated Zn salt (Zn(ClO4)(2)center dot 6H(2)O) exclusively with a neutral ligand (succinonitrile) to mitigate these issues. The unique aqua Zn2+ solvates with a succinonitrile-assisted solvation shell enable an unusual Zn/Zn2+ reversibility of 98.4% Coulombic efficiency along with smooth Zn deposition. Moreover, all water molecules contribute to the formation of the eutectic network, resulting in a delayed oxidation and suppressed solvating ability. When a quinone-based polymermaterial (38 wt% sulfur content) is utilized as a cathode, the Zn-organic battery with this aqueous eutectic electrolyte exhibits an unprecedented cyclability with a low capacity decay rate (0.004% per cycle over 3,500 cycles) and superior low-temperature performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 546, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1557, "End Page": 1574, "Article Number": null, "DOI": "10.1016/j.joule.2020.05.018", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.05.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551427400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boonprakob, N; Wetchakun, N; Phanichphant, S; Waxler, D; Sherrell, P; Nattestad, A; Chen, J; Inceesungvorn, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boonprakob, Natkritta; Wetchakun, Natda; Phanichphant, Sukon; Waxler, David; Sherrell, Peter; Nattestad, Andrew; Chen, Jun; Inceesungvorn, Burapat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced visible-light photocatalytic activity of g-C3N4/TiO2 films", "Source Title": "JOURNAL OF COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhanced photocatalytic degradation of methylene blue (MB) using graphitic carbon nitride/titanium dioxide (g-C3N4/TiO2) catalyst films has been demonstrated in this present work. The g-C3N4/TiO2 composites were prepared by directly heating the mixture of melamine and pre-synthesized TiO2 nulloparticles in Ar gas flow. The g-C3N4 contents in the g-C3N4/TiO2 composites were varied as 0, 20, 50 and 70 wt%. It was found that the visible-light-induced photocatalytic degradation of MB was remarkably increased upon coupling TiO2 with g-C3N4 and the best degradation performance of similar to 70% was obtained from 50 wt% g-C3N4 loading content. Results from UV-vis absorption study, Electron microscopy, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy suggest that the improved photoactivity is due to a decrease in band gap energy, an increased light absorption in visible light region and possibly an enhanced electron-hole separation efficiency as a result of effective interfacial electron transfer between TiO2 and g-C3N4 of the g-C3N4/TiO2 composite film. Based on the obtained results, the possible MB degradation mechanism is ascribed mainly to the generation of active species induced by the photogenerated electrons. (C) 2013 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2014, "Volume": 417, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 402, "End Page": 409, "Article Number": null, "DOI": "10.1016/j.jcis.2013.11.072", "DOI Link": "http://dx.doi.org/10.1016/j.jcis.2013.11.072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330090600051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, JC; Su, M; Briega-Martos, V; Li, L; Le, JB; Radjenovic, P; Zhou, XS; Feliu, JM; Tian, ZQ; Li, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Jin-Chao; Su, Min; Briega-Martos, Valentin; Li, Lang; Le, Jia-Bo; Radjenovic, Petar; Zhou, Xiao-Shun; Feliu, Juan Miguel; Tian, Zhong-Qun; Li, Jian-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct In Situ Raman Spectroscopic Evidence of Oxygen Reduction Reaction Intermediates at High-Index Pt(hkl) Surfaces", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The study of the oxygen reduction reaction (ORR) at high-index Pt(hkl) single crystal surfaces has received considerable interest due to their well-ordered, typical atomic structures and superior catalytic activities. However, it is difficult to obtain direct spectral evidence of ORR intermediates during reaction processes, especially at high-index Pt(hkl) surfaces. Herein, in situ Raman spectroscopy has been employed to investigate ORR processes at high-index Pt(hkl) surfaces containing the [01 (1) over bar] crystal zone-i.e., Pt(211) and Pt(311). Through control and isotope substitution experiments, in situ spectroscopic evidence of OH and OOH intermediates at Pt(211) and Pt(311) surfaces was successfully obtained. After detailed analysis based on the Raman spectra and theoretical simulation, it was deduced that the difference in adsorption of OOH at high-index surfaces has a significant effect on the ORR activity. This research illuminates and deepens the understanding of the ORR mechanism on high-index Pt(hkl) surfaces and provides theoretical guidance for the rational design of high activity ORR catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2020, "Volume": 142, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 715, "End Page": 719, "Article Number": null, "DOI": "10.1021/jacs.9b12803", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508475100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jang, KI; Chung, HU; Xu, S; Lee, CH; Luan, HW; Jeong, J; Cheng, HY; Kim, GT; Han, SY; Lee, JW; Kim, J; Cho, M; Miao, FX; Yang, YY; Jung, HN; Flavin, M; Liu, H; Kong, GW; Yu, KJ; Rhee, SI; Chung, J; Kim, B; Kwak, JW; Yun, MH; Kim, JY; Song, YM; Paik, U; Zhang, YH; Huang, Y; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jang, Kyung-In; Chung, Ha Uk; Xu, Sheng; Lee, Chi Hwan; Luan, Haiwen; Jeong, Jaewoong; Cheng, Huanyu; Kim, Gwang-Tae; Han, Sang Youn; Lee, Jung Woo; Kim, Jeonghyun; Cho, Moongee; Miao, Fuxing; Yang, Yiyuan; Jung, Han Na; Flavin, Matthew; Liu, Howard; Kong, Gil Woo; Yu, Ki Jun; Rhee, Sang Il; Chung, Jeahoon; Kim, Byunggik; Kwak, Jean Won; Yun, Myoung Hee; Kim, Jin Young; Song, Young Min; Paik, Ungyu; Zhang, Yihui; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft network composite materials with deterministic and bio-inspired designs", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard and soft structural composites found in biology provide inspiration for the design of advanced synthetic materials. Many examples of bio-inspired hard materials can be found in the literature; far less attention has been devoted to soft systems. Here we introduce deterministic routes to low-modulus thin film materials with stress/strain responses that can be tailored precisely to match the non-linear properties of biological tissues, with application opportunities that range from soft biomedical devices to constructs for tissue engineering. The approach combines a low-modulus matrix with an open, stretchable network as a structural reinforcement that can yield classes of composites with a wide range of desired mechanical responses, including anisotropic, spatially heterogeneous, hierarchical and self-similar designs. Demonstrative application examples in thin, skin-mounted electrophysiological sensors with mechanics precisely matched to the human epidermis and in soft, hydrogel-based vehicles for triggered drug release suggest their broad potential uses in biomedical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6566, "DOI": "10.1038/ncomms7566", "DOI Link": "http://dx.doi.org/10.1038/ncomms7566", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baena, JPC; Steier, L; Tress, W; Saliba, M; Neutzner, S; Matsui, T; Giordano, F; Jacobsson, TJ; Kandada, ARS; Zakeeruddin, SM; Petrozza, A; Abate, A; Nazeeruddin, MK; Grätzel, M; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baena, Juan Pablo Correa; Steier, Ludmilla; Tress, Wolfgang; Saliba, Michael; Neutzner, Stefanie; Matsui, Taisuke; Giordano, Fabrizio; Jacobsson, T. Jesper; Kandada, Ajay Ram Srimath; Zakeeruddin, Shaik M.; Petrozza, Annamaria; Abate, Antonio; Nazeeruddin, Mohammad Khaja; Graetzel, Michael; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient planar perovskite solar cells through band alignment engineering", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The simplification of perovskite solar cells (PSCs), by replacing the mesoporous electron selective layer (ESL) with a planar one, is advantageous for large-scale manufacturing. PSCs with a planar TiO2 ESL have been demonstrated, but these exhibit unstabilized power conversion efficiencies (PCEs). Herein we show that planar PSCs using TiO2 are inherently limited due to conduction band misalignment and demonstrate, with a variety of characterization techniques, for the first time that SnO2 achieves a barrier-free energetic configuration, obtaining almost hysteresis-free PCEs of over 18% with record high voltages of up to 1.19 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1064, "Times Cited, All Databases": 1117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2928, "End Page": 2934, "Article Number": null, "DOI": "10.1039/c5ee02608c", "DOI Link": "http://dx.doi.org/10.1039/c5ee02608c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362351700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Natu, V; Pai, R; Sokol, M; Carey, M; Kalra, V; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Natu, Varun; Pai, Rahul; Sokol, Maxim; Carey, Michael; Kalra, Vibha; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D Ti3C2Tz MXene Synthesized by Water-free Etching of Ti3AlC2 in Polar Organic Solvents", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The first MXene discovered, Ti3C2Tz, was synthesized by etching of the parent MAX phase, Ti3AlC2, in a solution of concentrated hydrofluoric acid. Since then, several other ways of synthesizing MXenes have been reported, such as electrochemical etching in various electrolytes, high-temperature alkali treatment, molten salt synthesis, etc. The majority of these etching methods, however, use water as their main solvent, limiting direct use of MXenes in water-sensitive applications. In this work, we show that it is possible to etch, and delaminate, MXenes in the absence of water, by using organic polar solvents in the presence of ammonium dihydrogen fluoride. We further show that by using this etching method, it is possible to obtain Ti 3C2Tz flakes rich in fluorine terminations. We also demonstrate that electrodes made from Ti3C2Tz etched in propylene carbonate resulted in Na-ion battery anodes with double the capacity to those etched in water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 616, "End Page": 630, "Article Number": null, "DOI": "10.1016/j.chempr.2020.01.019", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.01.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519997200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zekoll, S; Marriner-Edwards, C; Hekselman, AKO; Kasemchainull, J; Kuss, C; Armstrong, DEJ; Cai, DY; Wallace, RJ; Richter, FH; Thijssen, JHJ; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zekoll, Stefanie; Marriner-Edwards, Cassian; Hekselman, A. K. Ola; Kasemchainull, Jitti; Kuss, Christian; Armstrong, David E. J.; Cai, Dongyu; Wallace, Robert J.; Richter, Felix H.; Thijssen, Job H. J.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid electrolytes with 3D bicontinuous ordered ceramic and polymer microchannels for all-solid-state batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid solid electrolytes, composed of 3D ordered bicontinuous conducting ceramic and insulating polymer microchannels are reported. The ceramic channels provide continuous, uninterrupted pathways, maintaining high ionic conductivity between the electrodes, while the polymer channels permit improvement of the mechanical properties from that of the ceramic alone, in particular mitigation of the ceramic brittleness. The conductivity of a ceramic electrolyte is usually limited by resistance at the grain boundaries, necessitating dense ceramics. The conductivity of the 3D ordered hybrid is reduced by only the volume fraction occupied by the ceramic, demonstrating that the ceramic channels can be sintered to high density similar to a dense ceramic disk. The hybrid electrolytes are demonstrated using the ceramic lithium ion conductor Li1.4Al0.4Ge1.6(PO4)(3) (LAGP). Structured LAGP 3D scaffolds with empty channels were prepared by negative replication of a 3D printed polymer template. Filling the empty channels with non-conducting polypropylene (PP) or epoxy polymer (epoxy) creates the structured hybrid electrolytes with 3D bicontinuous ceramic and polymer microchannels. Printed templating permits precise control of the ceramic to polymer ratio and the microarchitecture; as demonstrated by the formation of cubic, gyroidal, diamond and spinodal (bijel) structures. The electrical and mechanical properties depend on the microarchitecture, the gyroid filled with epoxy giving the best combination of conductivity and mechanical properties. An ionic conductivity of 1.6 x 10(-4) S cm(-1) at room temperature was obtained, reduced from the conductivity of a sintered LAGP pellet only by the volume fraction occupied by the ceramic. The mechanical properties of the gyroid LAGP-epoxy electrolyte demonstrate up to 28% higher compressive failure strain and up to five times the flexural failure strain of a LAGP pellet before rupture. Notably, this demonstrates that ordered ceramic and polymer hybrid electrolytes can have superior mechanical properties without significantly compromising ionic conductivity, which addresses one of the key challenges for all-solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 185, "End Page": 201, "Article Number": null, "DOI": "10.1039/c7ee02723k", "DOI Link": "http://dx.doi.org/10.1039/c7ee02723k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423017000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chu, CH; Zhu, QH; Pan, ZH; Gupta, S; Huang, DH; Du, YH; Weon, S; Wu, YA; Muhich, C; Stavitski, E; Domen, K; Kim, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chu, Chiheng; Zhu, Qianhong; Pan, Zhenhua; Gupta, Srishti; Huang, Dahong; Du, Yonghua; Weon, Seunghyun; Wu, Yueshen; Muhich, Christopher; Stavitski, Eli; Domen, Kazunari; Kim, Jae-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spatially separating redox centers on 2D carbon nitride with cobalt single atom for photocatalytic H2O2 production", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Redox cocatalysts play crucial roles in photosynthetic reactions, yet simultaneous loading of oxidative and reductive cocatalysts often leads to enhanced charge recombination that is detrimental to photosynthesis. This study introduces an approach to simultaneously load two redox cocatalysts, atomically dispersed cobalt for improving oxidation activity and anthraquinone for improving reduction selectivity, onto graphitic carbon nitride (C3N4) nullosheets for photocatalytic H2O2 production. Spatial separation of oxidative and reductive cocatalysts was achieved on a two-dimensional (2D) photocatalyst, by coordinating cobalt single atom above the void center of C3N4 and anchoring anthraquinone at the edges of C3N4 nullosheets. Such spatial separation, experimentally confirmed and computationally simulated, was found to be critical for enhancing surface charge separation and achieving efficient H2O2 production. This center/edge strategy for spatial separation of cocatalysts may be applied on other 2D photo-catalysts that are increasingly studied in photosynthetic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2020, "Volume": 117, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6376, "End Page": 6382, "Article Number": null, "DOI": "10.1073/pnas.1913403117", "DOI Link": "http://dx.doi.org/10.1073/pnas.1913403117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521821800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, T; Zhang, T; Ge, BH; Han, LL; Zheng, LR; Lin, F; Xu, ZR; Hu, WB; Du, XW; Davey, K; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Tao; Zhang, Tong; Ge, Binghui; Han, Lili; Zheng, Lirong; Lin, Feng; Xu, Zhengrui; Hu, Wen-Bin; Du, Xi-Wen; Davey, Kenneth; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Well-Dispersed Nickel- and Zinc-Tailored Electronic Structure of a Transition Metal Oxide for Highly Active Alkaline Hydrogen Evolution Reaction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The practical scale-up of renewable energy technologies will require catalysts that are more efficient and durable than present ones. This is, however, a formidable challenge that will demand a new capability to tailor the electronic structure. Here, an original electronic structure tailoring of CoO by Ni and Zn dual doping is reported. This changes it from an inert material into one that is highly active for the hydrogen evolution reaction (HER). Based on combined density functional theory calculations and cutting-edge characterizations, it is shown that dual Ni and Zn doping is responsible for a highly significant increase in HER activity of the host oxide. That is, the Ni dopants cluster around surface oxygen vacancy of the host oxide and provide an ideal electronic surface structure for hydrogen intermediate binding, while the Zn dopants distribute inside the host oxide and modulate the bulk electronic structure to boost electrical conduction. As a result, the dual-doped Ni, Zn CoO nullorods achieve current densities of 10 and 20 mA cm(-2) at overpotentials of, respectively, 53 and 79 mV. This outperforms reported state-of-the-art metal oxide, metal oxide/metal, metal sulfide, and metal phosphide catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2019, "Volume": 31, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1807771, "DOI": "10.1002/adma.201807771", "DOI Link": "http://dx.doi.org/10.1002/adma.201807771", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468005400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dang, PP; Li, GG; Yun, XH; Zhang, QQ; Liu, DJ; Lian, HZ; Shang, MM; Lin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dang, Peipei; Li, Guogang; Yun, Xiaohan; Zhang, Qianqian; Liu, Dongjie; Lian, Hongzhou; Shang, Mengmeng; Lin, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally stable and highly efficient red-emitting Eu3+-doped Cs3GdGe3O9 phosphors for WLEDs: non-concentration quenching and negative thermal expansion", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Red phosphor materials play a key role in improving the lighting and backlit display quality of phosphor-converted white light-emitting diodes (pc-WLEDs). However, the development of a red phosphor with simultaneous high efficiency, excellent thermal stability and high colour purity is still a challenge. In this work, unique non-concentration quenching in solid-solution Cs3Gd1 - xGe3O9:xEu(3+) (CGGO:xEu(3+)) (x = 0.1-1.0) phosphors is successfully developed to achieve a highly efficient red-emitting Cs3EuGe3O9 (CEGO) phosphor. Under the optimal 464 nm blue light excitation, CEGO shows a strong red emission at 611 nm with a high colour purity of 95.07% and a high internal quantum efficiency of 94%. Impressively, this red-emitting CEGO phosphor exhibits a better thermal stability at higher temperatures (175-250 degrees C, >90%) than typical red K2SiF6:Mn4+ and Y2O3:Eu3+ phosphors, and has a remarkable volumetric negative thermal expansion (coefficient of thermal expansion, alpha = -5.06 x 10(-5)/degrees C, 25-250 degrees C). By employing this red CEGO phosphor, a fabricated pc-WLED emits warm white light with colour coordinates (0.364, 0.383), a high colour rendering index (CRI = 89.7), and a low colour coordinate temperature (CCT = 4508 K). These results indicate that this highly efficient red-emitting phosphor has great potential as a red component for pc-WLEDs, opening a new perspective for developing new phosphor materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29, "DOI": "10.1038/s41377-021-00469-x", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00469-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613720200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XX; Feng, JR; Liu, JW; Lu, J; Shi, W; Yang, GM; Wang, GC; Feng, PY; Cheng, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xiuxia; Feng, Jianrui; Liu, Jingwei; Lu, Jia; Shi, Wei; Yang, Guangming; Wang, Guichang; Feng, Pingyun; Cheng, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework-Derived ZnO/ZnS Heteronullostructures for Efficient Visible-Light-Driven Photocatalytic Hydrogen Production", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing highly active, recyclable, and inexpensive photocatalysts for hydrogen evolution reaction (HER) under visible light is significant for the direct conversion of solar energy into chemical fuels for various green energy applications. For such applications, it is very challenging but vitally important for a photocatalyst to simultaneously enhance the visible-light absorption and suppress photogenerated electron-hole recombination, while also to maintain high stability and recyclability. Herein, a metal-organic framework (MOF)-templated strategy has been developed to prepare heterostructured nullocatalysts with superior photocatalytic HER activity. Very uniquely, the synthesized photocatalytic materials can be recycled easily after use to restore the initial photocatalytic activity. It is shown that by controlling the calcination temperature and time with MOF-5 as a host and guest thioacetamide as a sulfur source, the chemical compositions of the formed heterojunctions of ZnO/ZnS can be tuned to further enhance the visible-light absorption and photocatalytic activity. The nulloscale heterojunction ZnO/ZnS structural feature serves to reduce the average free path of charge carriers and improve the charge separation efficiency, thus leading to significantly enhanced HER activity under visible-light irradiation (lambda > 420 nm) with high stability and recyclability without any cocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700590, "DOI": "10.1002/advs.201700590", "DOI Link": "http://dx.doi.org/10.1002/advs.201700590", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430460200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wu, X; Cheong, WC; Chen, WX; Lin, R; Li, J; Zheng, LR; Yan, WS; Gu, L; Chen, C; Peng, Q; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wu, Xi; Cheong, Weng-Chon; Chen, Wenxing; Lin, Rui; Li, Jia; Zheng, Lirong; Yan, Wensheng; Gu, Lin; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cation vacancy stabilization of single-atomic-site Pt1/Ni(OH)x catalyst for diboration of alkynes and alkenes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of single-atomic-site catalysts with high metal loading is highly desirable but proved to be very challenging. Although utilizing defects on supports to stabilize independent metal atoms has become a powerful method to fabricate single-atomic-site catalysts, little attention has been devoted to cation vacancy defects. Here we report a nickel hydroxide nulloboard with abundant Ni2+ vacancy defects serving as the practical support to achieve a single-atomic-site Pt catalyst (Pt-1/Ni(OH)(x)) containing Pt up to 2.3 wt% just by a simple wet impregnation method. The Ni2+ vacancies are found to have strong stabilizing effect of single-atomic Pt species, which is determined by X-ray absorption spectrometry analyses and density functional theory calculations. This Pt-1/Ni(OH)(x) catalyst shows a high catalytic efficiency in diboration of a variety of alkynes and alkenes, yielding an overall turnover frequency value upon reaction completion for phenylacetylene of similar to 3000 h(-1), which is much higher than other reported heterogeneous catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1002, "DOI": "10.1038/s41467-018-03380-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03380-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427007700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JY; Shi, JL; Qi, DC; Chen, L; Zhang, KHL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiaye; Shi, Jueli; Qi, Dong-Chen; Chen, Lang; Zhang, Kelvin H. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress on the electronic structure, defect, and doping properties of Ga2O3", "Source Title": "APL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gallium oxide (Ga2O3) is an emerging wide bandgap semiconductor that has attracted a large amount of interest due to its ultra-large bandgap of 4.8 eV, a high breakdown field of 8 MV/cm, and high thermal stability. These properties enable Ga2O3 a promising material for a large range of applications, such as high power electronic devices and solar-blind ultraviolet (UV) photodetectors. In the past few years, a significant process has been made for the growth of high-quality bulk crystals and thin films and device optimizations for power electronics and solar blind UV detection. However, many challenges remain, including the difficulty in p-type doping, a large density of unintentional electron carriers and defects/impurities, and issues with the device process (contact, dielectrics, and surface passivation), and so on. The purpose of this article is to provide a timely review on the fundamental understanding of the semiconductor physics and chemistry of Ga2O3 in terms of electronic band structures, optical properties, and chemistry of defects and impurity doping. Recent progress and perspectives on epitaxial thin film growth, chemical and physical properties of defects and impurities, p-type doping, and ternary alloys with In2O3 and Al2O3 will be discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2020, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20906, "DOI": "10.1063/1.5142999", "DOI Link": "http://dx.doi.org/10.1063/1.5142999", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517462500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lado, JL; Fernández-Rossier, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lado, J. L.; Fernulldez-Rossier, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the origin of magnetic anisotropy in two dimensional CrI3", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The observation of ferromagnetic order in a monolayer of CrI3 has been recently reported, with a Curie temperature of 45 K and off-plane easy axis. Here we study the origin of magnetic anisotropy, a necessary ingredient to have magnetic order in two dimensions, combining two levels of modeling, density functional calculations and spin model Hamiltonians. We find two different contributions to the magnetic anisotropy of the material, favoring off-plane magnetization and opening a gap in the spin wave spectrum. First, ferromagnetic super-exchange across the. 90 degree Cr-I-Cr bonds, are anisotropic, due to the spin-orbit interaction of the ligand I atoms. Second, a much smaller contribution that comes from the single ion anisotropy of the S = 3/2 Cr atom. Our results permit to establish the XXZ Hamiltonian, with a very small single ion anisotropy, as the adequate spin model for this system. Using spin wave theory we estimate the Curie temperature and we highlight the essential role played by the gap that magnetic anisotropy induces on the magnon spectrum.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 602, "Times Cited, All Databases": 641, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35002, "DOI": "10.1088/2053-1583/aa75ed", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/aa75ed", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403656100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, D; Li, L; Shi, BL; Shi, B; Li, MD; Qiu, Y; Zhao, D; Shen, QD; Zhu, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dun; Li, Lei; Shi, Ben-Long; Shi, Bo; Li, Ming-Ding; Qiu, Yong; Zhao, Di; Shen, Qun-Dong; Zhu, Ze-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-triggered piezocatalytic composite hydrogels for promoting bacterial-infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wound healing has become one of the basic issues faced by the medical community because of the susceptibility of skin wounds to bacterial infection. As such, it is highly desired to design a nullocomposite hydrogel with excellent antibacterial activity to achieve high wound closure effectiveness. Here, based on ultrasound-triggered piezocatalytic therapy, a multifunctional hydrogel is designed to promote bacteria-infected wound healing. Under ultrasonic vibration, the surface of barium titanate (BaTiO3, BT) nulloparticles embedded in the hydrogel rapidly generate reactive oxygen species (ROS) owing to the established strong built-in electric field, endowing the hydrogel with superior antibacterial efficacy. This modality shows intriguing advantages over conventional photodynamic therapy, such as prominent soft tissue penetration ability and the avoidance of serious skin phototoxicity after systemic administration of photosensitizers. Moreover, the hydrogel based on N-[tris (hydroxymethyl)methyl]acrylamide (THM), N-(3-aminopropyl)methacrylamide hydrochloride (APMH) and oxidized hyaluronic acid (OHA) exhibits outstanding self-healing and bioadhesive properties able to accelerate full-thickness skin wound healing. Notably, compared with the widely reported mussel-inspired adhesive hydrogels, OHA/THM-APMH hydrogel due to the multiple hydrogen bonds from unique tri-hydroxyl structure overcomes the shortage that catechol groups are easily oxidized, giving it long-term and repeatable adhesion performance. Importantly, this hybrid hydrogel confines BT nulloparticles to wound area and locally induced piezoelectric catalysis under ultrasound to eradicate bacteria, markedly improving the therapeutic biosafety and exhibits great potential for harmless treatment of bacteria-infected tissues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 24, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 96, "End Page": 111, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.11.023", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.11.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000899697100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Wu, HT; Xu, L; Zhang, HN; Yang, Y; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yang; Wu, Heting; Xu, Lin; Zhang, Hainull; Yang, Ya; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically patterned self-powered sensors for multifunctional tactile sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible sensors are highly desirable for tactile sensing and wearable devices. Previous researches of smart elements have focused on flexible pressure or temperature sensors. However, realizing material identification remains a challenge. Here, we report a multifunctional sensor composed of hydrophobic films and graphene/polydimethylsiloxane sponges. By engineering and optimizing sponges, the fabricated sensor exhibits a high-pressure sensitivity of >15.22 per kilopascal, a fast response time of <74 millisecond, and a high stability over >3000 cycles. In the case of temperature stimulus, the sensor exhibits a temperature-sensing resolution of 1 kelvin via the thermoelectric effect. The sensor can generate output voltage signals after physical contact with different flat materials based on contact-induced electrification. The corresponding signals can be, in turn, used to infer material properties. This multifunctional sensor is excellent in its low cost and material identification, which provides a design concept for meeting the challenges in functional electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 6, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb9083", "DOI": "10.1126/sciadv.abb9083", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb9083", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561426700032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pomerantseva, E; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pomerantseva, Ekaterina; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional heterostructures for energy storage", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials provide slit-shaped ion diffusion channels that enable fast movement of lithium and other ions. However, electronic conductivity, the number of intercalation sites, and stability during extended cycling are also crucial for building high-performance energy storage devices. While individual 2D materials, such as graphene, show some of the required properties, none of them can offer all properties needed to maximize energy density, power density, and cycle life. Here we argue that stacking different 2D materials into heterostructured architectures opens an opportunity to construct electrodes that would combine the advantages of the individual building blocks while eliminating the associated shortcomings. We discuss characteristics of common 2D materials and provide examples of 2D heterostructured electrodes that showed new phenomena leading to superior electrochemical performance. We also consider electrode fabrication approaches and finally outline future steps to create 2D heterostructured electrodes that could greatly expand current energy storage technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 838, "Times Cited, All Databases": 887, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17089, "DOI": "10.1038/nenergy.2017.89", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.89", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406499200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, XY; Xu, BG; Gong, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Xiaoyang; Xu, Bingang; Gong, Jianliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically architected polydopamine modified BaTiO3@P(VDF-TrFE) nullocomposite fiber mats for flexible piezoelectric nullogenerators and self-powered sensors", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible piezoelectric nullogenerators (FPENGs) have attracted a great attention owing to their promising applications in harvesting mechanical energy and driving portable devices. To develop high-performance FPENGs, the significant relationship among material, structure and performance inspired us a rational design of FPENGs from Pdop-BaTiO3@P(VDF-TrFE) nullocomposite fiber mats with a hierarchically architected microstructure. In contrast with previous approaches, the polydopamine (Pdop) modified barium titanate (BaTiO3, BT) nulloparticles have been anchored onto the surface of electrospun poly (vinylidene fluoride-trifluoroethylene) P(VDF-TrFE) fibers to fabricate hierarchical micro-structured membrane in this study, which not only effectively avoids the agglomeration of nullofillers but also enhances the density of interfaces in the nullocomposites. As a result, the as-fabricated FPENGs show a significantly enhanced output of 6 V and 1.5 mu A as compared to the PENG with only P(VDF-TrFE) membrane (1.25 V and 0.6 mu A). Furthermore, output voltage of the new FPENGs is 40%-68% higher than that of composite membranes with nulloparticles at the interior of nullofibers. The improved output of the PENG is attributed to the high density of interfaces in the hierarchical microstructure and the corresponding enhancement of dielectric response. Then, electric performance of FPENGs was investigated in terms of force, frequency and load resistance. Finally, the FPENG was employed to efficiently detect human body movements as self-powered sensors. The hierarchical nullocomposite membrane designed in this study provides an effective approach for developing mechanical energy harvesters, wearable sensor network and self-powered devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 70, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104516, "DOI": "10.1016/j.nulloen.2020.104516", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.104516", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521052900044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, QM; Mu, XP; Alhabeb, M; Shuck, CE; Pang, D; Zhao, X; Chu, XF; Wei, Y; Du, F; Chen, G; Gogotsi, Y; Gao, Y; Dall'Agnese, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Qingmin; Mu, Xinpeng; Alhabeb, Mohamed; Shuck, Christopher E.; Pang, Di; Zhao, Xin; Chu, Xue-Feng; Wei, Yingjin; Du, Fei; Chen, Gang; Gogotsi, Yury; Gao, Yu; Dall'Agnese, Yohan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional vanadium carbide (V2C) MXene as electrode for supercapacitors with aqueous electrolytes", "Source Title": "ELECTROCHEMISTRY COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, a large family of 2D materials called MXenes have attracted much attention in the field of supercapacitors, thanks to the excellent performance demonstrated by Ti3C2 MXene-based electrodes. However, research on MXenes for supercapacitor applications has been primarily focused on Ti3C2, even though there are more than 20 other members of this large family of materials already available. Studies on other MXenes are emerging, with promising results already achieved by Ti2C, Mo2C, and Mo1.33C in aqueous electrolytes. Yet, many other MXenes remain unexplored in aqueous supercapacitor applications. In this work, we report on the electrochemical behavior of a vanadium carbide MXene, V2C, in three aqueous electrolytes. Excellent specific capacitances were achieved, specifically 487 F/g in 1 M H2SO4, 225 F/g in 1 M MgSO4, and 184 F/g in 1 M KOH, which are higher than previously reported values for few micrometer-thick delaminated MXene electrodes. This work shows the promise of V2C MXene for energy storage using aqueous electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": 107, "Article Number": null, "DOI": "10.1016/j.elecom.2018.10.012", "DOI Link": "http://dx.doi.org/10.1016/j.elecom.2018.10.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448403200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pang, YK; Xu, XC; Chen, SE; Fang, YH; Shi, XD; Deng, YM; Wang, ZL; Cao, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pang, Yaokun; Xu, Xianchen; Chen, Shoue; Fang, Yuhui; Shi, Xiaodong; Deng, Yiming; Wang, Zhong-Lin; Cao, Changyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-inspired textile-based tactile sensors enable multifunctional sensing of wearables and soft robots", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional tactile sensors that can mimic the sensory capabilities of human skin to perceive various external static and dynamic stimuli are essential to interact with the environment and humans for wearable electronics and soft intelligent robotics. Here, inspired by human skin, we report a textile-based tactile sensor capable of multifunctional sensing for personalized healthcare monitoring and soft robotic control. The tactile sensor consists of a triboelectric nullogenerator sensing layer to mimic the function of fast adapting (FA) mechanoreceptors and a piezoresistive sensing layer to achieve the functionality of slow adapting (SA) mechanoreceptors. The tactile sensor has been demonstrated to be able to recognize voice and monitor physiological signals and human motions in a real-time manner. Combined with a machine learning framework, the tactile sensor is able to percept surface textures and material types with high accuracy. It is also demonstrated as an effective human machine interface for the control of assistive robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2022, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107137, "DOI": "10.1016/j.nulloen.2022.107137", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2022.107137", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788729100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chattot, R; Le Bacq, O; Beermann, V; Kühl, S; Herranz, J; Henning, S; Kuhn, L; Asset, T; Guétaz, L; Renou, G; Drnec, J; Bordet, P; Pasturel, A; Eychmüller, A; Schmidt, TJ; Strasser, P; Dubau, L; Maillard, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chattot, Raphael; Le Bacq, Olivier; Beermann, Vera; Kuehl, Stefanie; Herranz, Juan; Henning, Sebastian; Kuhn, Laura; Asset, Tristan; Guetaz, Laure; Renou, Gilles; Drnec, Jakub; Bordet, Pierre; Pasturel, Alain; Eychmueller, Alexander; Schmidt, Thomas J.; Strasser, Peter; Dubau, Laetitia; Maillard, Frederic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface distortion as a unifying concept and descriptor in oxygen reduction reaction electrocatalysis", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tuning the surface structure at the atomic level is of primary importance to simultaneously meet the electrocatalytic performance and stability criteria required for the development of low-temperature proton-exchange membrane fuel cells (PEMFCs). However, transposing the knowledge acquired on extended, model surfaces to practical nullomaterials remains highly challenging. Here, we propose 'surface distortion' as a novel structural descriptor, which is able to reconciliate and unify seemingly opposing notions and contradictory experimental observations in regards to the electrocatalytic oxygen reduction reaction (ORR) reactivity. Beyond its unifying character, we show that surface distortion is pivotal to rationalize the electrocatalytic properties of state-of-the-art of PtNi/C nullocatalysts with distinct atomic composition, size, shape and degree of surface defectiveness under a simulated PEMFC cathode environment. Our study brings fundamental and practical insights into the role of surface defects in electrocatalysis and highlights strategies to design more durable ORR nullocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 17, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 827, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-018-0133-2", "DOI Link": "http://dx.doi.org/10.1038/s41563-018-0133-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442526400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Greczynski, G; Hultman, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Greczynski, Grzegorz; Hultman, Lars", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compromising Science by Ignorant Instrument Calibration-Need to Revisit Half a Century of Published XPS Data", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray photoelectron spectroscopy (XPS) is an indispensable technique in modern materials science for the determination of chemical bonding as evidenced by more than 10 000 XPS papers published annually. A literature survey reveals that in the vast majority of cases an incorrect referencing of the binding energy scale is used, neglecting warnings that have been formulated from the early days of the technique. Consequences for the data reliability are disastrous and decades of XPS work require revisiting. The purpose of this Viewpoint is to highlight the existing problems, review the criticism and suggest ways forward.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 704, "Times Cited, All Databases": 714, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 59, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5002, "End Page": 5006, "Article Number": null, "DOI": "10.1002/anie.201916000", "DOI Link": "http://dx.doi.org/10.1002/anie.201916000", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517333000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HS; Park, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hui-Seon; Park, Nam-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Parameters Affecting I-V Hysteresis of CH3NH3PbI3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO2 Layer", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current-voltage (I-V) characteristics of CH3NH3PbI3 perovskite solar cells are studied using a time-dependent current response with stepwise sweeping of the bias voltage. Compared with the crystalline Si solar cell showing time-independent current at a given bias voltage, the perovskite solar cells exhibit time-dependent current response. The current increases with time and becomes steady at forward scan from short-circuit to open-circuit, whereas it is decayed and saturated with time at reverse scan from open-circuit to short-circuit. Time-dependent current response eventually leads to I-V hysteresis depending on the scan direction and the scan rate. Crystal size of CH3NH3PbI3 and the mesoporous TiO2 (mp-TiO2) film are found to influence I-V hysteresis, where the I-V hysteresis is alleviated as crystal size increases and in the presence of mp-TiO2. The capacitance observed at low frequency (0.1 to 1 Hz), associated with dipole polarization, tends to diminish as size of perovskite and mp-TiO2 layer thickness increases, which suggests that the origin of hysteresis correlates to the capacitive characteristic of CH3NH3PbI3 and the degree of hysteresis depends strongly on perovskite crystal size and mesoporous TiO2 layer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 989, "Times Cited, All Databases": 1042, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2014, "Volume": 5, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2927, "End Page": 2934, "Article Number": null, "DOI": "10.1021/jz501392m", "DOI Link": "http://dx.doi.org/10.1021/jz501392m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341337400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wei, XZ; Rukhlenko, ID; Chen, HT; Zhu, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jin; Wei, Xingzhan; Rukhlenko, Ivan D.; Chen, Hou-Tong; Zhu, Weiren", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically Tunable Metasurface with Independent Frequency and Amplitude Modulations", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces with actively tunable features are highly demanded for advanced applications in electronic and electromagnetic systems. However, realizing independent dual-tunability remains challenging and requires more efforts. In this paper, we present an active metasurface where the magnitude and frequency of the resonullt absorption can be continuously and independently tuned through application of voltage biases. Such a dual-tunability is accomplished at microwave frequencies by combining a varactor-loaded high-impedance surface and a graphene-based sandwich structure. By electrically controlling the Fermi energy of graphene and the capacitance of varactor diodes, we experimentally demonstrate the independent shifting of the working frequency from 3.41 to 4.55 GHz and tuning of the reflection amplitude between -3 and -30 dB, which is in excellent agreement with full-wave numerical simulations. We further employed an equivalent lumped circuit model to elucidate the mechanism of the dual-tunability resulting from the graphene-based sandwich structure and the active high-impedance surface. We speculate that such a dual-tunability scheme can be potentially extended to terahertz and optical regimes by employing different active/dynamical tuning methods and materials integration, thereby enabling a variety of practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 271, "Article Number": null, "DOI": "10.1021/acsphotonics.9b01532", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.9b01532", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508475800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, K; Lin, YH; Zhang, M; Oliver, RDJ; Wang, X; Liu, Z; Luo, X; Li, J; Lai, D; Luo, HW; Lin, RX; Xu, J; Hou, Y; Snaith, HJ; Tan, HR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Ke; Lin, Yen-Hung; Zhang, Mei; Oliver, Robert D. J.; Wang, Xi; Liu, Zhou; Luo, Xin; Li, Jia; Lai, Donny; Luo, Haowen; Lin, Renxing; Xu, Jun; Hou, Yi; Snaith, Henry J.; Tan, Hairen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable processing for realizing 21.7%-efficient all-perovskite tandem solar modules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Challenges in fabricating all-perovskite tandem solar cells as modules rather than as single-junction configurations include growing high-quality wide-bandgap perovskites and mitigating irreversible degradation caused by halide and metal interdiffusion at the interconnecting contacts. We demonstrate efficient all-perovskite tandem solar modules using scalable fabrication techniques. By systematically tuning the cesium ratio of a methylammonium-free 1.8-electron volt mixed-halide perovskite, we improve the homogeneity of crystallization for blade-coated films over large areas. An electrically conductive conformal diffusion barrier is introduced between interconnecting subcells to improve the power conversion efficiency (PCE) and stability of all-perovskite tandem solar modules. Our tandem modules achieve a certified PCE of 21.7% with an aperture area of 20 square centimeters and retain 75% of their initial efficiency after 500 hours of continuous operation under simulated 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2022, "Volume": 376, "Issue": 6594, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 762, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn7696", "DOI Link": "http://dx.doi.org/10.1126/science.abn7696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798488100050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Y; Zhou, TH; Ashirov, T; El Kazzi, M; Cancellieri, C; Jeurgens, LPH; Choi, JW; Coskun, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yan; Zhou, Tianhong; Ashirov, Timur; El Kazzi, Mario; Cancellieri, Claudia; Jeurgens, Lars P. H.; Choi, Jang Wook; Coskun, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorinated ether electrolyte with controlled solvation structure for high voltage lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of lithium-metal batteries is limited by the low thermodynamic and/or low voltage stability of conventional electrolytes. Here, the authors combined the high voltage stability of fluorinated ethers with high Li+ solvation ability of ethers in a single molecule and realized highly stable lithium-metal batteries. The development of new solvents is imperative in lithium metal batteries due to the incompatibility of conventional carbonate and narrow electrochemical windows of ether-based electrolytes. Whereas the fluorinated ethers showed improved electrochemical stabilities, they can hardly solvate lithium ions. Thus, the challenge in electrolyte chemistry is to combine the high voltage stability of fluorinated ethers with high lithium ion solvation ability of ethers in a single molecule. Herein, we report a new solvent, 2,2-dimethoxy-4-(trifluoromethyl)-1,3-dioxolane (DTDL), combining a cyclic fluorinated ether with a linear ether segment to simultaneously achieve high voltage stability and tune lithium ion solvation ability and structure. High oxidation stability up to 5.5 V, large lithium ion transference number of 0.75 and stable Coulombic efficiency of 99.2% after 500 cycles proved the potential of DTDL in high-voltage lithium metal batteries. Furthermore, 20 mu m thick lithium paired LiNi0.8Co0.1Mn0.1O2 full cell incorporating 2 M LiFSI-DTDL electrolyte retained 84% of the original capacity after 200 cycles at 0.5 C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2575, "DOI": "10.1038/s41467-022-29199-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29199-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791826000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, J; Zhao, YB; Askerka, M; Quan, LN; Gong, XW; Zhao, WJ; Zhao, JX; Tan, HR; Long, GK; Gao, L; Yang, ZY; Voznyy, O; Tang, J; Lu, ZH; Xiong, QH; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Jun; Zhao, Yongbiao; Askerka, Mikhail; Quan, Li Na; Gong, Xiwen; Zhao, Weijie; Zhao, Jiaxin; Tan, Hairen; Long, Guankui; Gao, Liang; Yang, Zhenyu; Voznyy, Oleksandr; Tang, Jiang; Lu, Zheng-Hong; Xiong, Qihua; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Color-stable highly luminescent sky-blue perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes (PeLEDs) have shown excellent performance in the green and near-infrared spectral regions, with high color purity, efficiency, and brightness. In order to shift the emission wavelength to the blue, compositional engineering (anion mixing) and quantum-confinement engineering (reduced-dimensionality) have been employed. Unfortunately, LED emission profiles shift with increasing driving voltages due to either phase separation or the coexistence of multiple crystal domains. Here we report color-stable sky-blue PeLEDs achieved by enhancing the phase monodispersity of quasi-2D perovskite thin films. We selected cation combinations that modulate the crystallization and layer thickness distribution of the domains. The perovskite films show a record photoluminescence quantum yield of 88% at 477 nm. The corresponding PeLEDs exhibit stable sky-blue emission under high operation voltages. A maximum luminullce of 2480 cd m(-2) at 490 nm is achieved, fully one order of magnitude higher than the previous record for quasi-2D blue PeLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 637, "Times Cited, All Databases": 666, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3541, "DOI": "10.1038/s41467-018-05909-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05909-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443155900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, JY; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Jin Young; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Second Skin Enabled by Advanced Electronics", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic second skin is touted as the next interface to expand applications of electronics for natural and seamless interactions with humans to enable smart health care, the Internet of Things, and even to amplify human sensory abilities. Thus, electronic materials are now being actively investigated to construct second skin. Accordingly, electronic devices are desirable to have skin-like properties such as stretchability, self-healing ability, biocompatibility, and biodegradability. This work reviews recent major progress in the development of both electronic materials and devices toward the second skin. It is concluded with comments on future research directions of the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2019, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900186, "DOI": "10.1002/advs.201900186", "DOI Link": "http://dx.doi.org/10.1002/advs.201900186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470189500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, Y; Qiu, M; Kim, MG; Liu, P; Nam, GT; Zhang, T; Zhuang, XD; Yang, B; Cho, J; Chen, MW; Yuan, C; Lei, LC; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Yang; Qiu, Ming; Kim, Min Gyu; Liu, Pan; Nam, Gyutae; Zhang, Tao; Zhuang, Xiaodong; Yang, Bin; Cho, Jaephil; Chen, Mingwei; Yuan, Chris; Lei, Lecheng; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed nickel-nitrogen-sulfur species anchored on porous carbon nullosheets for efficient water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing low-cost electrocatalysts to replace precious Ir-based materials is key for oxygen evolution reaction (OER). Here, we report atomically dispersed nickel coordinated with nitrogen and sulfur species in porous carbon nullosheets as an electrocatalyst exhibiting excellent activity and durability for OER with a low overpotential of 1.51 V at 10 mA cm(-2) and a small Tafel slope of 45 mV dec(-1) in alkaline media. Such electrocatalyst represents the best among all reported transition metal- and/or heteroatom-doped carbon electrocatalysts and is even superior to benchmark Ir/C. Theoretical and experimental results demonstrate that the well-dispersed molecular S vertical bar NiNx species act as active sites for catalyzing OER. The atomic structure of S vertical bar NiNx centers in the carbon matrix is clearly disclosed by aberration-corrected scanning transmission electron microscopy and synchrotron radiation X-ray absorption spectroscopy together with computational simulations. An integrated photoanode of nullocarbon on a Fe2O3 nullosheet array enables highly active solar-driven oxygen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1392, "DOI": "10.1038/s41467-019-09394-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09394-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462458900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Resasco, J; Chen, LD; Clark, E; Tsai, C; Hahn, C; Jaramillo, TF; Chan, K; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra; Tsai, Charlie; Hahn, Christopher; Jaramillo, Thomas F.; Chan, Karen; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of CO2 is known to be influenced by the identity of the alkali metal cation in the electrolyte; however, a satisfactory explanation for this phenomenon has not been developed. Here we present the results of experimental and theoretical studies aimed at elucidating the effects of electrolyte cation size on the intrinsic activity and selectivity of metal catalysts for the reduction of CO2. Experiments were conducted under conditions where the influence of electrolyte polarization is minimal in order to show that cation size affects the intrinsic rates of formation of certain reaction products, most notably for HCOO-, C2H4, and C2H5OH over Cu(100)- and Cu(111)-oriented thin films, and for CO and HCOO- over polycrystalline Ag and Sn. Interpretation of the findings for CO2 reduction was informed by studies of the reduction of glyoxal and CO, key intermediates along the reaction pathway to final products. Density functional theory calculations show that the alkali metal cations influence the distribution of products formed as a consequence of electrostatic interactions between solvated cations present at the outer Helmholtz plane and adsorbed species having large dipole moments. The observed trends in activity with cation size are attributed to an increase in the concentration of cations at the outer Helmholtz plane with increasing cation size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 774, "Times Cited, All Databases": 849, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 139, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11277, "End Page": 11287, "Article Number": null, "DOI": "10.1021/jacs.7b06765", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408074800054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, D; Seyler, KL; Linpeng, XY; Cheng, R; Sivadas, N; Huang, B; Schmidgall, E; Taniguchi, T; Watanabe, K; McGuire, MA; Yao, W; Xiao, D; Fu, KMC; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Ding; Seyler, Kyle L.; Linpeng, Xiayu; Cheng, Ran; Sivadas, Nikhil; Huang, Bevin; Schmidgall, Emma; Taniguchi, Takashi; Watanabe, Kenji; McGuire, Michael A.; Yao, Wang; Xiao, Di; Fu, Kai-Mei C.; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals engineering of ferromagnetic semiconductor heterostructures for spin and valleytronics", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of magnetic material with semiconductors has been fertile ground for fundamental science as well as of great practical interest toward the seamless integration of information processing and storage. We create van der Waals heterostructures formed by an ultrathin ferromagnetic semiconductor CrI3 and a monolayer of WSe2. We observe unprecedented control of the spin and valley pseudospin in WSe2, where we detect a large magnetic exchange field of nearly 13 T and rapid switching of the WSe2 valley splitting and polarization via flipping of the CrI3 magnetization. The WSe2 photoluminescence intensity strongly depends on the relative alignment between photoexcited spins in WSe2 and the CrI3 magnetization, because of ultrafast spin-dependent charge hopping across the heterostructure interface. The photoluminescence detection of valley pseudospin provides a simple and sensitive method to probe the intriguing domain dynamics in the ultrathin magnet, as well as the rich spin interactions within the heterostructure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 615, "Times Cited, All Databases": 709, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1603113", "DOI": "10.1126/sciadv.1603113", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419752300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marshall-Roth, T; Libretto, NJ; Wrobel, AT; Anderton, KJ; Pegis, ML; Ricke, ND; Van Voorhis, T; Miller, JT; Surendranath, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marshall-Roth, Travis; Libretto, Nicole J.; Wrobel, Alexandra T.; Anderton, Kevin J.; Pegis, Michael L.; Ricke, Nathan D.; Van Voorhis, Troy; Miller, Jeffrey T.; Surendranath, Yogesh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron- and nitrogen-doped carbon (Fe-N-C) materials are leading candidates to replace platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active site structures remain poorly understood. A leading postulate is that the iron-containing active sites exist primarily in a pyridinic Fe-N-4 ligation environment, yet, molecular model catalysts generally feature pyrrolic coordination. Herein, we report a molecular pyridinic hexaazacyclophane macrocycle, (phen(2)N(2))Fe, and compare its spectroscopic, electrochemical, and catalytic properties for ORR to a typical Fe-N-C material and prototypical pyrrolic iron macrocycles. N 1s XPS and XAS signatures for (phen(2)N(2))Fe are remarkably similar to those of Fe-N-C. Electrochemical studies reveal that (phen(2)N(2))Fe has a relatively high Fe(III/II) potential with a correlated ORR onset potential within 150mV of Fe-N-C. Unlike the pyrrolic macrocycles, (phen(2)N(2))Fe displays excellent selectivity for four-electron ORR, comparable to Fe-N-C materials. The aggregate spectroscopic and electrochemical data demonstrate that (phen(2)N(2))Fe is a more effective model of Fe-N-C active sites relative to the pyrrolic iron macrocycles, thereby establishing a new molecular platform that can aid understanding of this important class of catalytic materials. Iron- and nitrogen-doped carbon materials are effective catalysts for the oxygen reduction reaction whose active sites are poorly understood. Here, the authors establish a new pyridinic iron macrocycle complex as a more effective active site model relative to legacy pyrrolic model complexes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5283, "DOI": "10.1038/s41467-020-18969-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18969-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000585919600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shieh, P; Zhang, WX; Husted, KEL; Kristufek, SL; Xiong, BY; Lundberg, DJ; Lem, J; Veysset, D; Sun, YC; Nelson, KA; Plata, DL; Johnson, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shieh, Peyton; Zhang, Wenxu; Husted, Keith E. L.; Kristufek, Samantha L.; Xiong, Boya; Lundberg, David J.; Lem, Jet; Veysset, David; Sun, Yuchen; Nelson, Keith A.; Plata, Desiree L.; Johnson, Jeremiah A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cleavable comonomers enable degradable, recyclable thermoset plastics", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermosets-polymeric materials that adopt a permanent shape upon curing-have a key role in the modern plastics and rubber industries, comprising about 20 per cent of polymeric materials manufactured today, with a worldwide annual production of about 65 million tons(1,2). The high density of crosslinks that gives thermosets their useful properties (for example, chemical and thermal resistance and tensile strength) comes at the expense of degradability and recyclability. Here, using the industrial thermoset polydicyclopentadiene as a model system, we show that when a small number of cleavable bonds are selectively installed within the strands of thermosets using a comonomer additive in otherwise traditional curing workflows, the resulting materials can display the same mechanical properties as the native material, but they can undergo triggered, mild degradation to yield soluble, recyclable products of controlled size and functionality. By contrast, installation of cleavable crosslinks, even at much higher loadings, does not produce degradable materials. These findings reveal that optimization of the cleavable bond location can be used as a design principle to achieve controlled thermoset degradation. Moreover, we introduce a class of recyclable thermosets poised for rapid deployment. A method of endowing thermoset plastics with a degree of recyclability and reprocessability by incorporating cleavable chemical linkages in the strands of the polymer, rather than in the crosslinks, is presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 23", "Publication Year": 2020, "Volume": 583, "Issue": 7817, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 542, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2495-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2495-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551954700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Niu, XX; Fu, YH; Li, NX; Hu, C; Chen, YH; He, X; Na, GR; Liu, PF; Zai, HC; Ge, Y; Lu, Y; Ke, XX; Bai, Y; Yang, SH; Chen, PW; Li, YJ; Sui, ML; Zhang, LJ; Zhou, HP; Chen, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cheng; Niu, Xiuxiu; Fu, Yuhao; Li, Nengxu; Hu, Chen; Chen, Yihua; He, Xin; Na, Guangren; Liu, Pengfei; Zai, Huachao; Ge, Yang; Lu, Yue; Ke, Xiaoxing; Bai, Yang; Yang, Shihe; Chen, Pengwan; Li, Yujing; Sui, Manling; Zhang, Lijun; Zhou, Huanping; Chen, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain engineering in perovskite solar cells and its impacts on carrier dynamics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mixed halide perovskites have emerged as outstanding light absorbers for efficient solar cells. Unfortunately, it reveals inhomogeneity in these polycrystalline films due to composition separation, which leads to local lattice mismatches and emergent residual strains consequently. Thus far, the understanding of these residual strains and their effects on photovoltaic device performance is absent. Herein we study the evolution of residual strain over the films by depth-dependent grazing incident X-ray diffraction measurements. We identify the gradient distribution of in-plane strain component perpendicular to the substrate. Moreover, we reveal its impacts on the carrier dynamics over corresponding solar cells, which is stemmed from the strain induced energy bands bending of the perovskite absorber as indicated by first-principles calculations. Eventually, we modulate the status of residual strains in a controllable manner, which leads to enhanced PCEs up to 20.7% (certified) in devices via rational strain engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 763, "Times Cited, All Databases": 799, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 815, "DOI": "10.1038/s41467-019-08507-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08507-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458864600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JH; Zhang, ZX; Yang, YT; Ren, FG; Li, JP; Zhu, SJ; Ma, F; Wu, RQ; Lv, Y; He, G; Guo, BL; Chu, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Jiahui; Zhang, Zixi; Yang, Yutong; Ren, Fenggang; Li, Jipeng; Zhu, Shaojun; Ma, Feng; Wu, Rongqian; Lv, Yi; He, Gang; Guo, Baolin; Chu, Dake", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Injectable Self-Healing Adhesive pH-Responsive Hydrogels Accelerate Gastric Hemostasis and Wound Healing", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Endoscopic mucosal resection (EMR) and endoscopic submucosal dissection (ESD) are well-established therapeutics for gastrointestinal neoplasias, but complications after EMR/ESD, including bleeding and perforation, result in additional treatment morbidity and even threaten the lives of patients. Thus, designing biomaterials to treat gastric bleeding and wound healing after endoscopic treatment is highly desired and remains a challenge. Herein, a series of injectable pH-responsive self-healing adhesive hydrogels based on acryloyl-6-aminocaproic acid (AA) and AA-g-N-hydroxysuccinimide (AA-NHS) were developed, and their great potential as endoscopic sprayable bioadhesive materials to efficiently stop hemorrhage and promote the wound healing process was further demonstrated in a swine gastric hemorrhage/wound model. The hydrogels showed a suitable gelation time, an autonomous and efficient self-healing capacity, hemostatic properties, and good biocompatibility. With the introduction of AA-NHS as a micro-cross-linker, the hydrogels exhibited enhanced adhesive strength. A swine gastric hemorrhage in vivo model demonstrated that the hydrogels showed good hemostatic performance by stopping acute arterial bleeding and preventing delayed bleeding. A gastric wound model indicated that the hydrogels showed excellent treatment effects with significantly enhanced wound healing with type I collagen deposition, alpha-SMA expression, and blood vessel formation. These injectable self-healing adhesive hydrogels exhibited great potential to treat gastric wounds after endoscopic treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 80, "DOI": "10.1007/s40820-020-00585-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00585-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000622730600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, EQ; Li, J; Geng, KY; Jiang, QH; Xu, H; Xu, Q; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Enquan; Li, Juan; Geng, Keyu; Jiang, Qiuhong; Xu, Hong; Xu, Qing; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designed synthesis of stable light-emitting two-dimensional sp2 carbon-conjugated covalent organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks enable the topological connection of organic chromophores into pi lattices, making them attractive for creating light-emitting polymers that are pre-designable for both the primary- and high-order structures. However, owing to linkages, covalent organic frameworks are either unstable or poor luminescent, leaving the practical synthesis of stable light-emitting frameworks challenging. Here, we report the designed synthesis of sp(2) carbon-conjugated frameworks that combine stability with light-emitting activity. The C=C linkages topologically connect pyrene knots and arylyenevinylene linkers into two-dimensional all sp(2) carbon lattices that are designed to be pi conjugated along both the x and y directions and develop layer structures, creating exceptionally stable frameworks. The resulting frameworks are capable of tuning band gap and emission by the linkers, are highly luminescent under various conditions and can be exfoliated to produce brilliant nullosheets. These results suggest a platform based on sp(2) carbon frameworks for designing robust photofunctional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4143, "DOI": "10.1038/s41467-018-06719-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06719-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446566800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dirin, DN; Protesescu, L; Trummer, D; Kochetygov, IV; Yakunin, S; Krumeich, F; Stadie, NP; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dirin, Dmitry N.; Protesescu, Loredana; Trummer, David; Kochetygov, Ilia V.; Yakunin, Sergii; Krumeich, Frank; Stadie, Nicholas P.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harnessing Defect-Tolerance at the nulloscale: Highly Luminescent Lead Halide Perovskite nullocrystals in Mesoporous Silica Matrixes", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal lead halide perovskite nullocrystals (NCs) have recently emerged as a novel class of bright emitters with pure colors spanning the entire visible spectral range. Contrary to conventional quantum dots, such as CdSe and InP NCs, perovskite NCs feature unusual, defect-tolerant photophysics. Specifically, surface dangling bonds and intrinsic point defects such as vacancies do not form midgap states, known to trap carriers and thereby quench photoluminescence (PL). Accordingly, perovskite NCs need not be electronically surface-passivated (with, for instance, ligands and wider gap materials) and do not noticeably suffer from photo-oxidation. Novel opportunities for their preparation therefore can be envisaged. Herein, we show that the infiltration of perovskite precursor solutions into the pores of mesoporous silica, followed by drying, leads to the template-assisted formation of perovskite NCs. The most striking outcome of this simple methodology is very bright PL with quantum efficiencies exceeding 50%. This facile strategy can be applied to a large variety of perovskite compounds, hybrid and fully inorganic, with the general formula APbX(3), where A is cesium (Cs), methylammonium (MA), or formamidinium (FA), and Xis Cl, Br, I or a mixture thereof. The luminescent properties of the resulting templated NCs can be tuned by both quantum size effects as well as composition. Also exhibiting intrinsic haze due to scattering within the composite, such materials may find applications as replacements for conventional phosphors in liquid-crystal television display technologies and in related luminescence down-conversion-based devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 514, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 16, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5866, "End Page": 5874, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b02688", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b02688", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383412100081", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, YP; Zhu, HM; Schrader, AW; Liang, D; Ding, Q; Joshi, P; Hwang, L; Zhu, XY; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Yongping; Zhu, Haiming; Schrader, Alex W.; Liang, Dong; Ding, Qi; Joshi, Prakriti; Hwang, Leekyoung; Zhu, X-Y.; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The excellent intrinsic optoelectronic properties of methyl ammonium lead halide perovskites (MAPbX(3), X = Br, I), such as high photoluminescence quantum efficiency, long carrier lifetime, and high gain coupled with the facile solution growth of nullowires make them promising new materials for ultralow-threshold nullowire lasers. However, their photo and thermal stabilities need to be improved for practical applications. Herein, we report a low-temperature solution growth of single crystal nullowires of formamidinium lead halide perovskites (FAPbX(3)) that feature red-shifted emission and better thermal stability compared to MAPbX(3). We demonstrate optically pumped room-temperature near-infrared (similar to 820 nm) and green lasing (similar to 560 nm) from FAPbI(3) (and MABr-stabilized FAPM(3)) and FAPbBr(3) nullowires with low lasing thresholds of several microjoules per square centimeter and high quality factors of about 1500-2300. More remarkably, the FAPbI(3) and MABr-stabilized FAPbI(3) nullowires display durable room temperature lasing under similar to 10(8) shots of sustained illumination of 402 nm pulsed laser excitation (150 fs, 250 kHz), substantially exceeding the stability of MAPbI(3) (similar to 10(7) laser shots). We further demonstrate tunable nullowire lasers in wider wavelength region from FA-based lead halide perovskite alloys (FA,MA)PbI3 and (FA,MA)Pb(I,Br)(3) through cation and anion substitutions. The results suggest that formamidinium lead halide perovskite nullostructures could be more promising and stable materials for the development of light-emitting diodes and continuous-wave lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1000, "End Page": 1008, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b04053", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b04053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370215200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarycheva, A; Makaryan, T; Maleski, K; Satheeshkumar, E; Melikyan, A; Minassian, H; Yoshimura, M; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarycheva, Asia; Makaryan, Taron; Maleski, Kathleen; Satheeshkumar, Elumalai; Melikyan, Armen; Minassian, Hayk; Yoshimura, Masahiro; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Titanium Carbide (MXene) as Surface-Enhanced Raman Scattering Substrate", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble metal (gold or silver) nulloparticles or patterned films are typically used as substrates for surface-enhanced Raman spectroscopy (SERS). Two-dimensional (2D) carbides and nitrides (MXenes) exhibit unique electronic and optical properties, including metallic conductivity and plasmon resonullce in the visible or near infrared range, making them promising candidates for a wide variety of applications. Herein, we show that 2D titanium carbide, Ti3C2Tx, enhances Raman signal from organic dyes on a substrate and in solution. As a proof of concept, MXene SERS substrates were manufactured by spray-coating and used to detect several common dyes, with calculated enhancement factors reaching, similar to 10(6). Titanium carbide MXene demonstrates SERS effect in aqueous colloidal solutions, suggesting the potential for or environmental applications, where biomedical MXene can selectively enhance positively charged molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2017, "Volume": 121, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19983, "End Page": 19988, "Article Number": null, "DOI": "10.1021/acs.jpcc.7b08180", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.7b08180", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411171800046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dionigi, F; Zhu, J; Zeng, ZH; Merzdorf, T; Sarodnik, H; Gliech, M; Pan, LJ; Li, WX; Greeley, J; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dionigi, Fabio; Zhu, Jing; Zeng, Zhenhua; Merzdorf, Thomas; Sarodnik, Hannes; Gliech, Manuel; Pan, Lujin; Li, Wei-Xue; Greeley, Jeffrey; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Electrocatalytic Activity for Oxygen Evolution of Crystalline 3d-Transition Metal Layered Double Hydroxides", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered double hydroxides (LDHs) are among the most active and studied catalysts for the oxygen evolution reaction (OER) in alkaline electrolytes. However, previous studies have generally either focused on a small number of LDHs, applied synthetic routes with limited structural control, or used non-intrinsic activity metrics, thus hampering the construction of consistent structure-activity-relations. Herein, by employing new individually developed synthesis strategies with atomic structural control, we obtained a broad series of crystalline alpha-M-A(II)M-B(III) LDH and beta-M-A(OH)(2) electrocatalysts (M-A=Ni, Co, and M-B=Co, Fe, Mn). We further derived their intrinsic activity through electrochemical active surface area normalization, yielding the trend NiFe LDH > CoFe LDH > Fe-free Co-containing catalysts > Fe-Co-free Ni-based catalysts. Our theoretical reactivity analysis revealed that these intrinsic activity trends originate from the dual-metal-site nature of the reaction centers, which lead to composition-dependent synergies and diverse scaling relationships that may be used to design catalysts with improved performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2021, "Volume": 60, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14446, "End Page": 14457, "Article Number": null, "DOI": "10.1002/anie.202100631", "DOI Link": "http://dx.doi.org/10.1002/anie.202100631", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654752300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, XM; Ou, X; Zhao, WG; Liu, Y; Zhang, B; Zhang, JF; Zou, LF; Seidl, L; Li, YZ; Hu, GR; Battaglia, C; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Xinming; Ou, Xing; Zhao, Wengao; Liu, Yun; Zhang, Bao; Zhang, Jiafeng; Zou, Lianfeng; Seidl, Lukas; Li, Yangzhong; Hu, Guorong; Battaglia, Corsin; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ inorganic conductive network formation in high-voltage single-crystal Ni-rich cathodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-crystal Ni-rich cathodes suffer from side reactions with the electrolyte and slow Li-ion transport during high-voltage cycling. Herein, a Li1.4Y0.4Ti1.6(PO4)(3) coating is applied to facilitate the Li-ion transport and improve the cycling life of the cell. High nickel content in LiNixCoyMnzO2 (NCM, x >= 0.8, x + y + z = 1) layered cathode material allows high specific energy density in lithium-ion batteries (LIBs). However, Ni-rich NCM cathodes suffer from performance degradation, mechanical and structural instability upon prolonged cell cycling. Although the use of single-crystal Ni-rich NCM can mitigate these drawbacks, the ion-diffusion in large single-crystal particles hamper its rate capability. Herein, we report a strategy to construct an in situ Li1.4Y0.4Ti1.6(PO4)(3) (LYTP) ion/electron conductive network which interconnects single-crystal LiNi0.88Co0.09Mn0.03O2 (SC-NCM88) particles. The LYTP network facilitates the lithium-ion transport between SC-NCM88 particles, mitigates mechanical instability and prevents detrimental crystalline phase transformation. When used in combination with a Li metal anode, the LYTP-containing SC-NCM88-based cathode enables a coin cell capacity of 130 mAh g(-1) after 500 cycles at 5 C rate in the 2.75-4.4 V range at 25 degrees C. Tests in Li-ion pouch cell configuration (i.e., graphite used as negative electrode active material) demonstrate capacity retention of 85% after 1000 cycles at 0.5 C in the 2.75-4.4 V range at 25 degrees C for the LYTP-containing SC-NCM88-based positive electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5320, "DOI": "10.1038/s41467-021-25611-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25611-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694655700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Esfarjani, K; Luo, TF; Zhou, JW; Tian, ZT; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Sangyeop; Esfarjani, Keivan; Luo, Tengfei; Zhou, Jiawei; Tian, Zhiting; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resonullt bonding leads to low lattice thermal conductivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the lattice dynamics and low thermal conductivities of IV-VI, V-2-VI3 and V materials is critical to the development of better thermoelectric and phase-change materials. Here we provide a link between chemical bonding and low thermal conductivity. Our first-principles calculations reveal that long-ranged interaction along the /100S direction of the rocksalt structure exist in lead chalcogenides, SnTe, Bi2Te3, Bi and Sb due to the resonullt bonding that is common to all of them. This long-ranged interaction in lead chalcogenides and SnTe cause optical phonon softening, strong anharmonic scattering and large phase space for three-phonon scattering processes, which explain why rocksalt IV-VI compounds have much lower thermal conductivities than zincblende III-V compounds. The new insights on the relationship between resonullt bonding and low thermal conductivity will help in the development of better thermoelectric and phase change materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 573, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3525, "DOI": "10.1038/ncomms4525", "DOI Link": "http://dx.doi.org/10.1038/ncomms4525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335218500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Balci, O; Polat, EO; Kakenov, N; Kocabas, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Balci, Osman; Polat, Emre O.; Kakenov, Nurbek; Kocabas, Coskun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-enabled electrically switchable radar-absorbing surfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radar-absorbing materials are used in stealth technologies for concealment of an object from radar detection. Resistive and/or magnetic composite materials are used to reduce the backscattered microwave signals. Inability to control electrical properties of these materials, however, hinders the realization of active camouflage systems. Here, using large-area graphene electrodes, we demonstrate active surfaces that enable electrical control of reflection, transmission and absorption of microwaves. Instead of tuning bulk material property, our strategy relies on electrostatic tuning of the charge density on an atomically thin electrode, which operates as a tunable metal in microwave frequencies. Notably, we report large-area adaptive radar-absorbing surfaces with tunable reflection suppression ratio up to 50 dB with operation voltages <5V. Using the developed surfaces, we demonstrate various device architectures including pixelated and curved surfaces. Our results provide a significant step in realization of active camouflage systems in microwave frequencies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 503, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6628, "DOI": "10.1038/ncomms7628", "DOI Link": "http://dx.doi.org/10.1038/ncomms7628", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353039700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CR; Jiang, X; Kim, HJ; Zhang, SM; Zhou, XW; Chen, Y; Ling, HA; Xue, YM; Chen, ZW; Qu, MY; Ren, L; Zhu, JX; Libanori, A; Zhu, YZ; Kang, H; Ahadian, S; Dokmeci, MR; Servati, P; He, XM; Gu, Z; Sun, WJ; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Canran; Jiang, Xing; Kim, Han-Jun; Zhang, Shiming; Zhou, Xingwu; Chen, Yi; Ling, Haonull; Xue, Yumeng; Chen, Zhaowei; Qu, Moyuan; Ren, Li; Zhu, Jixiang; Libanori, Alberto; Zhu, Yangzhi; Kang, Heemin; Ahadian, Samad; Dokmeci, Mehmet R.; Servati, Peyman; He, Ximin; Gu, Zhen; Sun, Wujin; Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible patch with printable and antibacterial conductive hydrogel electrodes for accelerated wound healing", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrical stimulation can facilitate wound healing with high efficiency and limited side effects. However, current electrical stimulation devices have poor conformability with wounds due to their bulky nature and the rigidity of electrodes utilized. Here, a flexible electrical patch (ePatch) made with conductive hydrogel as electrodes to improve wound management was reported. The conductive hydrogel was synthesized using silver nullowire (AgNW) and methacrylated alginate (MAA), with the former chosen as the electrode material considering its antibacterial properties, and the latter used due to its clinical suitability in wound healing. The composition of the hydrogel was optimized to enable printing on medical-grade patches for personalized wound treatment. The ePatch was shown to promote re-epithelization, enhance angiogenesis, mediate immune response, and prevent infection development in the wound microenvironment. In vitro studies indicated an elevated secretion of growth factors with enhanced cell proliferation and migration ability in response to electrical stimulation. An in vivo study in the Sprague-Dawley rat model revealed a rapid wound closure within 7 days compared to 20 days of usual healing process in rodents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 285, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121479, "DOI": "10.1016/j.biomaterials.2022.121479", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2022.121479", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799393200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZC; Chen, ZM; Yang, YC; Xue, QF; Yip, HL; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhenchao; Chen, Ziming; Yang, Yongchao; Xue, Qifan; Yip, Hin-Lap; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulation of recombination zone position for quasi-two-dimensional blue perovskite light-emitting diodes with efficiency exceeding 5%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, substantial progress has been made in developing perovskite light-emitting diodes with near-infrared, red and green emissions and over 20% external quantum efficiency. However, the development of perovskite light-emitting diodes with blue emission remains a great challenge, which retards further development of full-color displays and white-light illumination based on perovskite emissive materials. Here, firstly, through composition and dimensional engineering, we prepare quasi-two-dimensional perovskite thin films with improved blue emission, taking advantages of reduced trap density and enhanced photoluminescence quantum yield. Secondly, we find a vertically non-uniform distribution of perovskite crystals in the PEDOT:PSS/perovskite hybrid film. Through modulating the position of the recombination zone, we activate the majority of quasi-two-dimensional perovskite crystals, and thus demonstrate the most efficient blue perovskite light-emitting diode to date with emission peak at 480 nm, record luminullce of 3780 cd m(-2) and record external quantum efficiency of 5.7%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1027, "DOI": "10.1038/s41467-019-09011-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09011-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460125400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SJ; Hao, JN; Li, H; Zhang, PF; Yin, ZW; Li, YY; Zhang, BK; Lin, Z; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shao-Jian; Hao, Junnull; Li, Huan; Zhang, Peng-Fang; Yin, Zu-Wei; Li, Yu-Yang; Zhang, Bingkai; Lin, Zhan; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyiodide Confinement by Starch Enables Shuttle-Free Zn-Iodine Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-iodine (Zn-I-2) batteries have been regarded as a promising energy-storage system owing to their high energy/power density, safety, and cost-effectiveness. However, the polyiodide shuttling results in serious active mass loss and Zn corrosion, which limits the cycling life of Zn-I-2 batteries. Inspired by the chromogenic reaction between starch and iodine, a structure confinement strategy is proposed to suppress polyiodide shuttling in Zn-I-2 batteries by hiring starch, due to its unique double-helix structure. In situ Raman spectroscopy demonstrates an I-5(-)-dominated I-/I-2 conversion mechanism when using starch. The I-5(-) presents a much stronger bonding with starch than I-3(-), inhibiting the polyiodide shuttling in Zn-I-2 batteries, which is confirmed by in situ ultraviolet-visible spectra. Consequently, a highly reversible Zn-I-2 battery with high Coulombic efficiency (approximate to 100% at 0.2 A g(-1)) and ultralong cycling stability (>50 000 cycles) is realized. Simultaneously, the Zn corrosion triggered by polyiodide is effectively inhibited owing to the desirable shuttling-suppression by the starch, as evidenced by X-ray photoelectron spectroscopy analysis. This work provides a new understanding of the failure mechanism of Zn-I-2 batteries and proposes a cheap but effective strategy to realize high-cyclability Zn-I-2 batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 34, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201716, "DOI": "10.1002/adma.202201716", "DOI Link": "http://dx.doi.org/10.1002/adma.202201716", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789373200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geng, BJ; Hu, JY; Li, Y; Feng, SN; Pan, DY; Feng, LY; Shen, LX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geng, Bijiang; Hu, Jinyan; Li, Yuan; Feng, Shini; Pan, Dengyu; Feng, Lingyan; Shen, Longxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-infrared phosphorescent carbon dots for sonodynamic precision tumor therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Theranostic sonosensitizers with combined sonodynamic and near infrared (NIR) imaging modes are required for imaging guided sonodynamic therapy (SDT). It is challenging, however, to realize a single material that is simultaneously endowed with both NIR emitting and sonodynamic activities. Herein, we report the design of a class of NIR-emitting sonosensitizers from a NIR phosphorescent carbon dot (CD) material with a narrow bandgap (1.62 eV) and long-lived excited triplet states (11.4 mu s), two of which can enhance SDT as thermodynamically and dynamically favorable factors under low-intensity ultrasound irradiation, respectively. The NIR-phosphorescent CDs are identified as bipolar quantum dots containing both p- and n-type surface functionalization regions that can drive spatial separation of e(-)-h(+) pairs and fast transfer to reaction sites. Importantly, the cancer-specific targeting and high-level intratumor enrichment of the theranostic CDs are achieved by cancer cell membrane encapsulation for precision SDT with complete eradication of solid tumors by single injection and single irradiation. These results will open up a promising approach to engineer phosphorescent materials with long-lived triplet excited states for sonodynamic precision tumor therapy. Combining sonodynamic properties and NIR fluorescence into a single material is desired for deep tissue applications. Here, the authors report on carbon dot sono-sensitizers engineered with a narrow bandgap and coated with cancer cell membrane for targeted NIR guided sonodynamic cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5735, "DOI": "10.1038/s41467-022-33474-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33474-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000862065300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YQ; Liu, HW; Zhao, SY; Xie, C; Huang, ZG; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yiqiong; Liu, Hanwen; Zhao, Siyuan; Xie, Chao; Huang, Zhenguo; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into the Dynamic Evolution of Defects in Electrocatalysts", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This review focuses on the formation and preparation of defects, the dynamic evolution process of defects, and the influence of defect dynamic evolution on catalytic reactions. The summary of the current advances in the dynamic evolution process of defects in oxygen evolution reaction, hydrogen evolution reaction, nitrogen reduction reaction, oxygen reduction reaction, and carbon dioxide reduction reaction, and the given perspectives are expected to provide a more comprehensive understanding of defective electrocatalysts on the structural evolution process during electrocatalysis and the reaction mechanisms, especially for the defect dynamic evolution on the performance in catalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209680", "DOI Link": "http://dx.doi.org/10.1002/adma.202209680", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911837500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DR; Pu, HB; Huang, LJ; Sun, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Daorui; Pu, Hongbin; Huang, Lunjie; Sun, Da-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in flexible surface-enhanced Raman scattering (SERS) substrates for nondestructive food detection: Fundamentals and recent applications", "Source Title": "TRENDS IN FOOD SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Food safety has attracted considerable attention in recent years. As a rapid, fingerprint-type recognition and nondestructive detection technique, surface-enhanced Raman scattering (SERS) has been among the promising techniques to meet the increasing needs for food safety analysis. Currently, emerging flexible SERS substrates as an alternative for colloidal and rigid SERS substrates have received great interest. Flexible SERS substrates possess the advantages of easy sampling by wrapping or swabbing on nonplanar surfaces, which facilitate the detection of contaminullts from food surfaces and shed new lights on the nondestructive and sensitive detection of food analytes. Scope and approach: In this review, the characteristics of different flexible materials such as cellulose, polymer film, cotton fabric, adhesive tape and bio-materials for constructing flexible SERS substrates are introduced, detection strategies including infiltration scheme, swab-sampling and in-situ detection are discussed, and recent applications of flexible SERS substrates in detecting trace pesticides in fruits and vegetables, chemical residues in animal farming including fungicides and antibiotics, illegal food additives and food-borne pathogens are highlighted. Key findings and conclusions: Flexible SERS substrates have been increasingly studied for detecting food contaminullts. In preparing SERS substrates, different properties of the materials should be considered. For the detection strategies, compared with conventional infiltration scheme, swab-sampling is unique for flexible substrates and can collect target molecules directly from the surface, while in-situ detection is the most convenient, facile and nondestructive. Encouraging application results available show that flexible SERS substrates possess enormous potentials for food safety analysis and surveillance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 109, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 701, "Article Number": null, "DOI": "10.1016/j.tifs.2021.01.058", "DOI Link": "http://dx.doi.org/10.1016/j.tifs.2021.01.058", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621184500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Shimeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neuro-Inspired Computing With Emerging Nonvolatile Memory", "Source Title": "PROCEEDINGS OF THE IEEE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This comprehensive review summarizes state of the art, challenges, and prospects of the neuro-inspired computing with emerging nonvolatile memory devices. First, we discuss the demand for developing neuro-inspired architecture beyond today's von-Neumann architecture. Second, we summarize the various approaches to designing the neuromorphic hardware (digital versus analog, spiking versus nonspiking, online training versus offline training) and discuss why emerging nonvolatile memory is attractive for implementing the synapses in the neural network. Then, we discuss the desired device characteristics of the synaptic devices (e.g., multilevel states, weight update nonlinearity/asymmetry, variation/noise), and survey a few representative material systems and device prototypes reported in the literature that show the analog conductance tuning. These candidates include phase change memory, resistive memory, ferroelectric memory, floating-gate transistors, etc.Next, we introduce the crossbar array architecture to accelerate the weighted sum and weight update operations that are commonly used in the neuro-inspired machine learning algorithms, and review the recent progresses of array-level experimental demonstrations for pattern recognition tasks. In addition, we discuss the peripheral neuron circuit design issues and present a device-circuit-algorithm codesign methodology to evaluate the impact of nonideal device effects on the system-level performance (e.g., learning accuracy). Finally, we give an outlook on the customization of the learning algorithms for efficient hardware implementation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 849, "Times Cited, All Databases": 907, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 106, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 260, "End Page": 285, "Article Number": null, "DOI": "10.1109/JPROC.2018.2790840", "DOI Link": "http://dx.doi.org/10.1109/JPROC.2018.2790840", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425055600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parangusan, H; Ponnamma, D; Al-Maadeed, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parangusan, Hemalatha; Ponnamma, Deepalekshmi; Al-Maadeed, Mariam Al Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable Electrospun PVDF-HFP/Co-ZnO nullofibers as Piezoelectric nullogenerators", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we investigate the morphology, structure and piezoelectric performances of neat polyvinylidene fluoride hexafluoropropylene (PVDF-HFP) and PVDF-HFP/Co-ZnO nullofibers, fabricated by electrospinning. An increase in the amount of crystalline beta-phase of PVDF-HFP has been observed with the increase in Co-doped ZnO nullofiller concentration in the PVDF-HFP matrix. The dielectric constants of the neat PVDF-HFP and PVDF-HFP/2 wt.% Co-ZnO nullofibers are derived as 8 and 38 respectively. The flexible nullogenerator manipulated from the polymer nullocomposite (PVDF-HFP/Co-ZnO) exhibits an output voltage as high as 2.8 V compared with the neat PVDF-HFP sample (-120 mV). These results indicate that the investigated nullocomposite is appropriate for fabricating various flexible and wearable self-powered electrical devices and systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 754, "DOI": "10.1038/s41598-017-19082-3", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-19082-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422637200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, WC; Zhao, YG; Wei, SQ; Triana, CA; Li, JG; Arcifa, A; Allen, CS; Cao, R; Patzke, GR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Wenchao; Zhao, Yonggui; Wei, Shiqian; Triana, Carlos A.; Li, Jingguo; Arcifa, Andrea; Allen, Christopher S.; Cao, Rui; Patzke, Greta R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanistic insight into the active centers of single/dual-atom Ni/Fe-based oxygen electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of high performance dual-site single-atom catalysts is a promising research direction. Here, the authors report structural dynamics of dual-site nickel-iron single-atom oxygen electrocatalysts under reaction conditions, and proposes a dual-site pathway for the water oxidation reaction. Single-atom catalysts with maximum metal utilization efficiency show great potential for sustainable catalytic applications and fundamental mechanistic studies. We here provide a convenient molecular tailoring strategy based on graphitic carbon nitride as support for the rational design of single-site and dual-site single-atom catalysts. Catalysts with single Fe sites exhibit impressive oxygen reduction reaction activity with a half-wave potential of 0.89 V vs. RHE. We find that the single Ni sites are favorable to promote the key structural reconstruction into bridging Ni-O-Fe bonds in dual-site NiFe SAC. Meanwhile, the newly formed Ni-O-Fe bonds create spin channels for electron transfer, resulting in a significant improvement of the oxygen evolution reaction activity with an overpotential of 270 mV at 10 mA cm(-2). We further reveal that the water oxidation reaction follows a dual-site pathway through the deprotonation of *OH at both Ni and Fe sites, leading to the formation of bridging O-2 atop the Ni-O-Fe sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5589, "DOI": "10.1038/s41467-021-25811-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25811-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000700360600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JJ; Wang, N; Cui, ZL; Du, HP; Fu, L; Huang, CS; Yang, Z; Shen, XY; Yi, YP; Tu, ZY; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Jianjiang; Wang, Ning; Cui, Zili; Du, Huiping; Fu, Lin; Huang, Changshui; Yang, Ze; Shen, Xiangyan; Yi, Yuanping; Tu, Zeyi; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen substituted graphdiyne as carbon-rich flexible electrode for lithium and sodium ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic electrodes are potential alternatives to current inorganic electrode materials for lithium ion and sodium ion batteries powering portable and wearable electronics, in terms of their mechanical flexibility, function tunability and low cost. However, the low capacity, poor rate performance and rapid capacity degradation impede their practical application. Here, we concentrate on the molecular design for improved conductivity and capacity, and favorable bulk ion transport. Through an in situ cross- coupling reaction of triethynylbenzene on copper foil, the carbon-rich frame hydrogen substituted graphdiyne film is fabricated. The organic film can act as free-standing flexible electrode for both lithium ion and sodium ion batteries, and large reversible capacities of 1050 mAh g(-1) for lithium ion batteries and 650 mAh g(-1) for sodium ion batteries are achieved. The electrode also shows a superior rate and cycle performances owing to the extended pi-conjugated system, and the hierarchical pore bulk with large surface area.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1172, "DOI": "10.1038/s41467-017-01202-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01202-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413833000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leroy, A; Bhatia, B; Kelsall, CC; Castillejo-Cuberos, A; Di Capua, HM; Zhao, L; Zhang, L; Guzman, AM; Wang, EN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leroy, A.; Bhatia, B.; Kelsall, C. C.; Castillejo-Cuberos, A.; Di Capua, M. H.; Zhao, L.; Zhang, L.; Guzman, A. M.; Wang, E. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance subambient radiative cooling enabled by optically selective and thermally insulating polyethylene aerogel", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent progress in passive radiative cooling technologies has substantially improved cooling performance under direct sunlight. Yet, experimental demonstrations of daytime radiative cooling still severely underperform in comparison with the theoretical potential due to considerable solar absorption and poor thermal insulation at the emitter. In this work, we developed polyethylene aerogel (PEA)-a solar-reflecting (92.2% solar weighted reflectance at 6 mm thick), infrared-transparent (79.9% transmittance between 8 and 13 mu m at 6 mm thick), and low-thermal-conductivity (k(PEA) = 28 mW/mK) material that can be integrated with existing emitters to address these challenges. Using an experimental setup that includes the custom-fabricated PEA, we demonstrate a daytime ambient temperature cooling power of 96 W/m(2) and passive cooling up to 13 degrees C below ambient temperature around solar noon. This work could greatly improve the performance of existing passive radiative coolers for air conditioning and portable refrigeration applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat9480", "DOI": "10.1126/sciadv.aat9480", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat9480", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494263000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, J; Jin, J; Zhang, H; Lu, M; Peng, Y; Huang, BL; Xi, PX; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Jie; Jin, Jing; Zhang, Hong; Lu, Min; Peng, Yong; Huang, Bolong; Xi, Pinxian; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Arrangement in Metal-Doped NiS2 Boosts the Hydrogen Evolution Reaction in Alkaline Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a novel modulation strategy by introducing transition metals into NiS2 nullosheets (NSs) to flexibly optimize the electronic configurations and atomic arrangement. The Co-NiS2 NSs exhibit excellent hydrogen evolution reaction (HER) performance with an overpotential of 80 mV at j=10 mA cm(-2) and long-term stability of 90 h in alkaline media. The turnover frequencies (TOFs) of 0.55 and 4.1 s(-1) at an overpotential of 100 and 200 mV also confirm their remarkable performance. DFT calculations reveal that the surface dopants abnormally sensitize surface Ni-3d bands in the long-range order towards higher electron-transfer activity, acting as the electron-depletion center. Meanwhile, the high lying surface S-sites possess substantially high selectivity for splitting the adsorbing H2O that guarantee the high HER performance within alkaline conditions. This work opens opportunities for enhancing water splitting by atomic-arrangement-assisted electronic modulation via a facile doping strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2019, "Volume": 58, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18676, "End Page": 18682, "Article Number": null, "DOI": "10.1002/anie.201911470", "DOI Link": "http://dx.doi.org/10.1002/anie.201911470", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493861200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, XD; Yu, HM; Bui, B; Wang, LY; Xing, C; Wang, SY; Chen, ML; Hu, ZZ; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Xiaodan; Yu, Hongmei; Bui, Brian; Wang, Lingyun; Xing, Christina; Wang, Shaoyan; Chen, Mingli; Hu, Zhizhi; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-doped fluorescence carbon dots as multi-mechanism detection for iodide and curcumin in biological and food samples", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iodine ion is one of the most indispensable anions in living organisms, particularly being an important substance for the synthesis of thyroid hormones. Curcumin is a yellow-orange polyphenol compound derived from the rhizome of Curcuma longa L., which has been commonly used as a spice and natural coloring agent, food additives, cosmetics as well as Chinese medicine. However, excess curcumin may cause DNA inactivation, lead to a decrease in intracellular ATP levels, and trigger the tissue necrosis. Therefore, quantitative detection of iodine and curcumin is of great significance in the fields of food and life sciences. Herein, we develop nitrogen-doped fluorescent carbon dots (NCDs) as a multi-mechanism detection for iodide and curcumin in actual complex biological and food samples, which was prepared by a one-step solid-phase synthesis using tartaric acid and urea as precursors without adding any other reagents. An assembled NCDs-Hg2+ fluorescence-enhanced sensor for the quantitative detection of I was established based on a fluorescence turn-off-on mechanism in a linear range of 0.3-15 mu M with a detection limit of 69.4 nM and successfully quantified trace amounts of I in water samples and urine sample. Meanwhile, the as-synthesized NCDs also can be used as a fluorescent quenched sensor for curcumin detection based on the synergistic internal filtration effect (IFE) and static quenching, achieving a good linear range of 0.1-20 mu M with a satisfactory detection limit of 29.8 nM. These results indicate that carbon dots are potential sensing materials for iodine and curcumin detection for the good of our health.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1541, "End Page": 1554, "Article Number": null, "DOI": "10.1016/j.bioactmat.2020.11.006", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2020.11.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630522400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, R; Yi, ZL; Song, MX; Chen, JP; Wei, XX; Su, FY; Dai, LQ; Sun, GH; Yang, F; Xie, LJ; Chen, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ran; Yi, Zonglin; Song, Mingxin; Chen, Jingpeng; Wei, Xianxian; Su, Fangyuan; Dai, Liqin; Sun, Guohua; Yang, Fan; Xie, Lijing; Chen, Cheng-Meng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting sodium storage performance of hard carbons by regulating oxygen functionalities of the cross-linked asphalt precursor", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pre-oxidation treatment is a key process to produce carbon anodes for sodium ion batteries from pitch because it governs the orientation of carbon layers during subsequent carbonization. However, the relationship between the oxygen functionalities in the oxidized pitch and the evolution of carbon structure during carbonization remains unclear. Herein, cross-linked asphalts with differentiated oxygen functionalities such as C-O and C(O)-O (ester group and anhydride), are synthesized to explore their effects on the evolution of carbon structure. The planar cross-linked structures constructed by thermally stable C-O fail to prevent the sliding of carbon layer, leading the formation of short-range order carbon structures with lager lateral size. In contrast, the three-dimensional cross -linked structures constructed by C(O)-O effectively prevent the rearrangement of asphalt at early pyrolysis. Owing to the gas generated by C(O)-O removal during subsequent carbonization, the as-formed more disorder carbon structures with small microcrystalline sizes can generate more closed pores and ultra-micropores, which enhances the low-voltage plateau capacity from 96.06 to 132.2 mAh g-1. The insights for the differentiated oxygen functionalities in regulating the carbon structural conversion pave the way for further development of pitch-based hard carbons with higher performance and their practical applications in SIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2023, "Volume": 206, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 104, "Article Number": null, "DOI": "10.1016/j.carbon.2023.02.004", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.02.004", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938024300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, FC; Liu, W; Sun, YF; Xu, JQ; Liu, KT; Liang, L; Yao, T; Pan, BC; Wei, SQ; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Fengcai; Liu, Wei; Sun, Yongfu; Xu, Jiaqi; Liu, Katong; Liang, Liang; Yao, Tao; Pan, Bicai; Wei, Shiqiang; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin metal layers can be highly active carbon dioxide electroreduction catalysts, but may also be prone to oxidation. Here we construct a model of graphene confined ultrathin layers of highly reactive metals, taking the synthetic highly reactive tin quantum sheets confined in graphene as an example. The higher electrochemical active area ensures 9 times larger carbon dioxide adsorption capacity relative to bulk tin, while the highly-conductive graphene favours rate-determining electron transfer from carbon dioxide to its radical anion. The lowered tin-tin coordination numbers, revealed by X-ray absorption fine structure spectroscopy, enable tin quantum sheets confined in graphene to efficiently stabilize the carbon dioxide radical anion, verified by 0.13 volts lowered potential of hydroxyl ion adsorption compared with bulk tin. Hence, the tin quantum sheets confined in graphene show enhanced electrocatalytic activity and stability. This work may provide a promising lead for designing efficient and robust catalysts for electrolytic fuel synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12697, "DOI": "10.1038/ncomms12697", "DOI Link": "http://dx.doi.org/10.1038/ncomms12697", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384972700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, N; Guo, HY; Li, L; Dai, J; Wang, L; Mei, WN; Wu, XJ; Zeng, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Ning; Guo, Hongyan; Li, Lei; Dai, Jun; Wang, Lu; Mei, Wai-Ning; Wu, Xiaojun; Zeng, Xiao Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2/MX2 heterobilayers: bandgap engineering via tensile strain or external electrical field", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have performed a comprehensive first-principles study of the electronic and magnetic properties of two-dimensional (2D) transition-metal dichalcogenide (TMD) heterobilayers MX2/MoS2 (M = Mo, Cr, W, Fe, V; X = S, Se). For M = Mo, Cr, W; X = S, Se, all heterobilayers show semiconducting characteristics with an indirect bandgap with the exception of the WSe2/MoS2 heterobilayer which retains the direct-bandgap character of the constituent monolayer. For M = Fe, V; X = S, Se, the MX2/MoS2 heterobilayers exhibit metallic characters. Particular attention of this study has been focused on engineering the bandgap of the TMD heterobilayer materials via application of either a tensile strain or an external electric field. We find that with increasing either the biaxial or uniaxial tensile strain, the MX2/MoS2 (M = Mo, Cr, W; X = S, Se) heterobilayers can undergo a semiconductor-to-metal transition. For the WSe2/MoS2 heterobilayer, a direct-to-indirect bandgap transition may occur beyond a critical biaxial or uniaxial strain. For M (=Fe, V) and X (=S, Se), the magnetic moments of both metal and chalcogen atoms are enhanced when the MX2/MoS2 heterobilayers are under a biaxial tensile strain. Moreover, the bandgap of MX2/MoS2 (M = Mo, Cr, W; X = S, Se) heterobilayers can be reduced by the vertical electric field. For two heterobilayers MSe2/MoS2 (M = Mo, Cr), PBE calculations suggest that the indirect-to-direct bandgap transition may occur under an external electric field. The transition is attributed to the enhanced spontaneous polarization. The tunable bandgaps in general and possible indirect-direct bandgap transitions due to tensile strain or external electric field make the TMD heterobilayer materials a viable candidate for optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2879, "End Page": 2886, "Article Number": null, "DOI": "10.1039/c3nr06072a", "DOI Link": "http://dx.doi.org/10.1039/c3nr06072a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332127200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, B; Chen, G; Fave, C; Chen, LJ; Kuriki, R; Maeda, K; Ishitani, O; Lau, TC; Bonin, J; Robert, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Bing; Chen, Gui; Fave, Claire; Chen, Lingjing; Kuriki, Ryo; Maeda, Kazuhiko; Ishitani, Osamu; Lau, Tai-Chu; Bonin, Julien; Robert, Marc", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Visible-Light-Driven CO2 Reduction by a Cobalt Molecular Catalyst Covalently Linked to Mesoporous Carbon Nitride", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving visible-light-driven carbon dioxide reduction with high selectivity control and durability while using only earth abundant elements requires new strategies. Hybrid catalytic material was prepared upon covalent grafting a Co-quaterpyridine molecular complex to semiconductive mesoporous graphitic carbon nitride (mpg-C3N4) through an amide linkage. The molecular material was characterized by various spectroscopic techniques, including XPS, IR, and impedance spectroscopy. It proved to be a selective catalyst for CO production in acetonitrile using a solar simulator with a high 98% selectivity, while being remarkably robust since no degradation was observed after 4 days of irradiation (ca. 500 catalytic cycles). This unique combination of a selective molecular catalyst with a simple and robust semiconductive material opens new pathways for CO2 catalytic light-driven reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 142, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6188, "End Page": 6195, "Article Number": null, "DOI": "10.1021/jacs.9b13930", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13930", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526393700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, QG; Wang, ZJ; Wang, Y; Minori, A; Tolley, MT; Cai, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Qiguang; Wang, Zhijian; Wang, Yang; Minori, Adriane; Tolley, Michael T.; Cai, Shengqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically controlled liquid crystal elastomer-based soft tubular actuator with multimodal actuation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft tubular actuators can be widely found both in nature and in engineering applications. The benefits of tubular actuators include (i) multiple actuation modes such as contraction, bending, and expansion; (ii) facile fabrication from a planar sheet; and (iii) a large interior space for accommodating additional components or for transporting fluids. Most recently developed soft tubular actuators are driven by pneumatics, hydraulics, or tendons. Each of these actuation modes has limitations including complex fabrication, integration, and nonuniform strain. Here, we design and construct soft tubular actuators using an emerging artificial muscle material that can be easily patterned with programmable strain: liquid crystal elastomer. Controlled by an externally applied electrical potential, the tubular actuator can exhibit multidirectional bending as well as large (similar to 40%) homogenous contraction. Using multiple tubular actuators, we build a multifunctional soft gripper and an untethered soft robot.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax5746", "DOI": "10.1126/sciadv.aax5746", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax5746", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491132700053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XL; Gu, M; Hu, SY; Kennard, R; Yan, PF; Chen, XL; Wang, CM; Sailor, MJ; Zhang, JG; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaolin; Gu, Meng; Hu, Shenyang; Kennard, Rhiannon; Yan, Pengfei; Chen, Xilin; Wang, Chongmin; Sailor, Michael J.; Zhang, Ji-Guang; Liu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous silicon sponge as an anti-pulverization structure for high-performance lithium-ion battery anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured silicon is a promising anode material for high-performance lithium-ion batteries, yet scalable synthesis of such materials, and retaining good cycling stability in high loading electrode remain significant challenges. Here we combine in-situ transmission electron microscopy and continuum media mechanical calculations to demonstrate that large (420 mm) mesoporous silicon sponge prepared by the anodization method can limit the particle volume expansion at full lithiation to similar to 30% and prevent pulverization in bulk silicon particles. The mesoporous silicon sponge can deliver a capacity of up to similar to 750 mAhg(-1) based on the total electrode weight with >80% capacity retention over 1,000 cycles. The first cycle irreversible capacity loss of pre-lithiated electrode is <5%. Bulk electrodes with an area-specific-capacity of similar to 1.5 mAhcm(-2) and similar to 92% capacity retention over 300 cycles are also demonstrated. The insight obtained from this work also provides guidance for the design of other materials that may experience large volume variation during operations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 613, "Times Cited, All Databases": 665, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4105, "DOI": "10.1038/ncomms5105", "DOI Link": "http://dx.doi.org/10.1038/ncomms5105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340615900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, PP; Li, Y; Wang, G; Wang, FX; Yang, S; Zhu, F; Zhuang, XD; Schmidt, OG; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Panpan; Li, Yang; Wang, Gang; Wang, Faxing; Yang, Sheng; Zhu, Feng; Zhuang, Xiaodong; Schmidt, Oliver G.; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zn-Ion Hybrid Micro-Supercapacitors with Ultrahigh Areal Energy Density and Long-Term Durability", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-chip micro-supercapacitors (MSCs), as promising power candidates for microdevices, typically exhibit high power density, large charge/discharge rates, and long cycling lifetimes. However, as for most reported MSCs, the unsatisfactory areal energy density (<10 mu Wh cm(-2)) still hinders their practical applications. Herein, a new-type Zn-ion hybrid MSC with ultrahigh areal energy density and long-term durability is demonstrated. Benefiting from fast ion adsorption/desorption on the capacitor-type activated-carbon cathode and reversible Zn stripping/plating on the battery-type electrodeposited Zn-nullosheet anode, the fabricated Zn-ion hybrid MSCs exhibit remarkable areal capacitance of 1297 mF cm(-2) at 0.16 mA cm(-2) (259.4 F g(-1) at a current density of 0.05 A g(-1)), landmark areal energy density (115.4 mu Wh cm(-2) at 0.16 mW cm(-2)), and a superb cycling stability without noticeable decay after 10 000 cycles. This work will inspire the fabrication and development of new high-performance microenergy devices based on novel device design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2019, "Volume": 31, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806005, "DOI": "10.1002/adma.201806005", "DOI Link": "http://dx.doi.org/10.1002/adma.201806005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459628200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, HS; Shao, LD; Zhang, Y; Zou, GQ; Chen, J; Ji, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Hongshuai; Shao, Lidong; Zhang, Yan; Zou, Guoqiang; Chen, Jun; Ji, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Area Carbon nullosheets Doped with Phosphorus: A High-Performance Anode Material for Sodium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-area phosphorus-doped carbon nullosheets (P-CNSs) are first obtained from carbon dots (CDs) through self-assembly driving from thermal treatment with Na catalysis. This is the first time to realize the conversion from 0D CDs to 2D nullosheets doped with phosphorus. The sodium storage behavior of phosphorus-doped carbon material is also investigated for the first time. As anode material for sodium-ion batteries (SIBs), P-CNSs exhibit superb performances for electrochemical storage of sodium. When cycled at 0.1 A g(-1), the P-CNSs electrode delivers a high reversible capacity of 328 mAh g(-1), even at a high current density of 20 A g(-1), a considerable capacity of 108 mAh g(-1) can still be maintained. Besides, this material also shows excellent cycling stability, at a current density of 5 A g(-1), the reversible capacity can still reach 149 mAh g(-1) after 5000 cycles. This work will provide significant value for the development of both carbon materials and SIBs anode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 514, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600243, "DOI": "10.1002/advs.201600243", "DOI Link": "http://dx.doi.org/10.1002/advs.201600243", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392400200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sultan, S; Mathew, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sultan, Sahar; Mathew, Aji P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printed scaffolds with gradient porosity based on a cellulose nullocrystal hydrogel", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3-Dimensional (3D) printing provides a unique methodology for the customization of biomedical scaffolds with respect to size, shape, pore structure and pore orientation useful for tissue repair and regeneration. 3D printing was used to fabricate fully bio-based porous scaffolds of a double crosslinked interpenetrating polymer network (IPN) from a hydrogel ink of sodium alginate and gelatin (SA/G) reinforced with cellulose nullocrystals (CNCs). CNCs provided favorable rheological properties required for 3D printing. The 3D printed scaffolds were crosslinked sequentially via covalent and ionic reactions resulting in dimensionally stable hydrogel scaffolds with pore sizes of 80-2125 m and nulloscaled pore wall roughness (visible from scanning electron microscopy) favorable for cell interaction. The 2D wide angle X-ray scattering studies showed that the nullocrystals orient preferably in the printing direction; the degree of orientation varied between 61-76%. The 3D printing pathways were optimised successfully to achieve 3-dimensional scaffolds (Z axis up to 20 mm) with uniform as well as gradient pore structures. This study demonstrates the potential of 3D printing in developing bio-based scaffolds with controlled pore sizes, gradient pore structures and alignment of nullocrystals for optimal tissue regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2018, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4421, "End Page": 4431, "Article Number": null, "DOI": "10.1039/c7nr08966j", "DOI Link": "http://dx.doi.org/10.1039/c7nr08966j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426708500032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mefford, JT; Rong, X; Abakumov, AM; Hardin, WG; Dai, S; Kolpak, AM; Johnston, KP; Stevenson, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mefford, J. Tyler; Rong, Xi; Abakumov, Artem M.; Hardin, William G.; Dai, Sheng; Kolpak, Alexie M.; Johnston, Keith P.; Stevenson, Keith J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite oxides are attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and conversion systems. However, the rational design of active catalysts has been hampered by the lack of understanding of the mechanism of water electrolysis on perovskite surfaces. Key parameters that have been overlooked include the role of oxygen vacancies, B-O bond covalency, and redox activity of lattice oxygen species. Here we present a series of cobaltite perovskites where the covalency of the Co-O bond and the concentration of oxygen vacancies are controlled through Sr2+ substitution into La1 - xSrxCoO3 - delta. We attempt to rationalize the high activities of La1 - xSrxCoO3 - delta through the electronic structure and participation of lattice oxygen in the mechanism of water electrolysis as revealed through ab initio modelling. Using this approach, we report a material, SrCoO2.7, with a high, room temperature-specific activity and mass activity towards alkaline water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 919, "Times Cited, All Databases": 966, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11053, "DOI": "10.1038/ncomms11053", "DOI Link": "http://dx.doi.org/10.1038/ncomms11053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372721700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, D; Kley, CS; Li, YF; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Dohyung; Kley, Christopher S.; Li, Yifan; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper nulloparticle ensembles for selective electroreduction of CO2 to C2-C3 products", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct conversion of carbon dioxide to multicarbon products remains as a grand challenge in electrochemical CO2 reduction. Various forms of oxidized copper have been demonstrated as electrocatalysts that still require large overpotentials. Here, we show that an ensemble of Cu nulloparticles (NPs) enables selective formation of C-2-C-3 products at low overpotentials. Densely packed Cu NP ensembles underwent structural transformation during electrolysis into electrocatalytically active cube-like particles intermixed with smaller nulloparticles. Ethylene, ethanol, and n-propanol are the major C-2-C-3 products with onset potential at -0.53 V (vs. reversible hydrogen electrode, RHE) and C-2-C-3 faradaic efficiency (FE) reaching 50% at only -0.75 V. Thus, the catalyst exhibits selective generation of C-2-C-3 hydrocarbons and oxygenates at considerably lowered overpotentials in neutral pH aqueous media. In addition, this approach suggests new opportunities in realizing multicarbon product formation from CO2, where the majority of efforts has been to use oxidized copper-based materials. Robust catalytic performance is demonstrated by 10 h of stable operation with C-2-C-3 current density 10 mA/cm(2) (at -0.75 V), rendering it attractive for solar-to-fuel applications. Tafel analysis suggests reductive CO coupling as a rate determining step for C-2 products, while n-propanol (C-3) production seems to have a discrete pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 515, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2017, "Volume": 114, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10560, "End Page": 10565, "Article Number": null, "DOI": "10.1073/pnas.1711493114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1711493114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412130500043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, XM; Lei, TP; Sun, DH; Lin, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Xiaomei; Lei, Tingping; Sun, Daoheng; Lin, Liwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poly(vinylidene fluoride) (PVDF) has been widely utilized in scientific research and the manufacturing industry for its unique piezoelectric properties. In the past few decades, the vibrational spectra of PVDF polymorphic polymers via FTIR (Fourier transform infrared spectroscopy) have been extensively investigated and documented. However, reports on the analysis of alpha, beta and gamma phases often have conflicting views based on measured data. In this work, we analyze the FTIR vibrational bands of PVDF materials fabricated by different processes with detailed XRD (X-ray diffraction) characterization to identify the structural a, b and g phases. By examining the results in this work and extensively reviewing published research reports in the literature, a universal phase identification procedure using only the FTIR results is proposed and validated. Specifically, this procedure can differentiate the three phases by checking the bands around 763 and/or 614, 1275, and 1234 cm(-1) for the alpha, beta and gamma phases, respectively. The rule for assignment of the 840* and 510* cm(-1) bands is provided for the first time and an integrated quantification methodology for individual beta and gamma phase in mixed systems is also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1157, "Times Cited, All Databases": 1210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15382, "End Page": 15389, "Article Number": null, "DOI": "10.1039/c7ra01267e", "DOI Link": "http://dx.doi.org/10.1039/c7ra01267e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396290400050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, F; Roy, AR; Silvioli, L; Cullen, DA; Zitolo, A; Sougrati, MT; Oguz, IC; Mineva, T; Teschner, D; Wagner, S; Wen, J; Dionigi, F; Kramm, UI; Rossmeisl, J; Jaouen, F; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Fang; Roy, Aaron; Silvioli, Luca; Cullen, David A.; Zitolo, Andrea; Sougrati, Moulay Tahar; Oguz, Ismail Can; Mineva, Tzonka; Teschner, Detre; Wagner, Stephan; Wen, Ju; Dionigi, Fabio; Kramm, Ulrike, I; Rossmeisl, Jan; Jaouen, Frederic; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "P-block single-metal-site tin/nitrogen-doped carbon fuel cell cathode catalyst for oxygen reduction reaction", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This contribution reports the discovery and analysis of ap-block Sn-based catalyst for the electroreduction of molecular oxygen in acidic conditions at fuel cell cathodes; the catalyst is free of platinum-group metals and contains single-metal-atom actives sites coordinated by nitrogen. The prepared SnNC catalysts meet and exceed state-of-the-art FeNC catalysts in terms of intrinsic catalytic turn-over frequency and hydrogen-air fuel cell power density. The SnNC-NH(3)catalysts displayed a 40-50% higher current density than FeNC-NH(3)at cell voltages below 0.7 V. Additional benefits include a highly favourable selectivity for the four-electron reduction pathway and a Fenton-inactive character of Sn. A range of analytical techniques combined with density functional theory calculations indicate that stannic Sn(iv)N(x)single-metal sites with moderate oxygen chemisorption properties and low pyridinic N coordination numbers act as catalytically active moieties. The superior proton-exchange membrane fuel cell performance of SnNC cathode catalysts under realistic, hydrogen-air fuel cell conditions, particularly after NH(3)activation treatment, makes them a promising alternative to today's state-of-the-art Fe-based catalysts. For oxygen reduction and hydrogen oxidation reactions, proton-exchange membrane fuel cells typically rely on precious-metal-based catalysts. Ap-block single-metal-site tin/nitrogen-doped carbon is shown to exhibit promising electrocatalytic and fuel cell performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 19, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1215, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-0717-5", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-0717-5", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548166000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Chen, BG; Meng, C; Fang, W; Xiao, Y; Li, XY; Hu, ZF; Xu, YX; Tong, LM; Wang, HQ; Liu, WT; Bao, JM; Shen, YR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Chen, Bigeng; Meng, Chao; Fang, Wei; Xiao, Yao; Li, Xiyuan; Hu, Zhifang; Xu, Yingxin; Tong, Limin; Wang, Hongqing; Liu, Weitao; Bao, Jiming; Shen, Y. Ron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast All-Optical Graphene Modulator", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is an optical material of unusual characteristics because of its linearly dispersive conduction and valence bands and the strong interband transitions. It allows broadband light-matter interactions with ultrafast responses and can be readily pasted to surfaces of functional structures for photonic and optoelectronic applications. Recently, graphene-based optical modulators have been demonstrated with electrical tuning of the Fermi level of graphene. Their operation bandwidth, however, was limited to about 1 GHz by the response of the driving electrical circuit. Clearly, this can be improved by an all-optical approach. Here, we show that a graphene-clad microfiber all-optical modulator can achieve a modulation depth of 38% and a response time of similar to 2.2 ps, limited only by the intrinsic carrier relaxation time of graphene. This modulator is compatible with current high-speed fiber-optic communication networks and may open the door to meet future demand of ultrafast optical signal processing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 624, "Times Cited, All Databases": 685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 955, "End Page": 959, "Article Number": null, "DOI": "10.1021/nl404356t", "DOI Link": "http://dx.doi.org/10.1021/nl404356t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331343900085", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hagemann, N; Joseph, S; Schmidt, HP; Kammann, CI; Harter, J; Borch, T; Young, RB; Varga, K; Taherymoosavi, S; Elliott, KW; McKenna, A; Albu, M; Mayrhofer, C; Obst, M; Conte, P; Dieguez-Alonso, A; Orsetti, S; Subdiaga, E; Behrens, S; Kappler, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hagemann, Nikolas; Joseph, Stephen; Schmidt, Hans-Peter; Kammann, Claudia I.; Harter, Johannes; Borch, Thomas; Young, Robert B.; Varga, Krisztina; Taherymoosavi, Sarasadat; Elliott, K. Wade; McKenna, Amy; Albu, Mihaela; Mayrhofer, Claudia; Obst, Martin; Conte, Pellegrino; Dieguez-Alonso, Alba; Orsetti, Silvia; Subdiaga, Edisson; Behrens, Sebastian; Kappler, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic coating on biochar explains its nutrient retention and stimulation of soil fertility", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Amending soil with biochar (pyrolized biomass) is suggested as a globally applicable approach to address climate change and soil degradation by carbon sequestration, reducing soil-borne greenhouse-gas emissions and increasing soil nutrient retention. Biochar was shown to promote plant growth, especially when combined with nutrient-rich organic matter, e.g., co-composted biochar. Plant growth promotion was explained by slow release of nutrients, although a mechanistic understanding of nutrient storage in biochar is missing. Here we identify a complex, nutrient-rich organic coating on co-composted biochar that covers the outer and inner (pore) surfaces of biochar particles using high-resolution spectro (micro)scopy and mass spectrometry. Fast field cycling nuclear magnetic resonullce, electrochemical analysis and gas adsorption demonstrated that this coating adds hydrophilicity, redox-active moieties, and additional mesoporosity, which strengthens biochar-water interactions and thus enhances nutrient retention. This implies that the functioning of biochar in soil is determined by the formation of an organic coating, rather than biochar surface oxidation, as previously suggested.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1089, "DOI": "10.1038/s41467-017-01123-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01123-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413353500038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dinh, KN; Zheng, PL; Dai, ZF; Zhang, Y; Dangol, R; Zheng, Y; Li, B; Zong, Y; Yan, QY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khang Ngoc Dinh; Zheng, Penglun; Dai, Zhengfei; Zhang, Yu; Dangol, Raksha; Zheng, Yun; Li, Bing; Zong, Yun; Yan, Qingyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Porous NiFeV Ternary Layer Hydroxide nullosheets as a Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, the hydrothermal synthesis of porous ultrathin ternary NiFeV layer double hydroxides (LDHs) nullosheets grown on Nickel foam (NF) substrate as a highly efficient electrode toward overall water splitting in alkaline media is reported. The lateral size of the nullosheets is about a few hundreds of nullometers with the thickness of approximate to 10 nm. Among all molar ratios investigated, the Ni0.75Fe0.125V0.125-LDHs/NF electrode depicts the optimized performance. It displays an excellent catalytic activity with a modest overpotential of 231 mV for the oxygen evolution reaction (OER) and 125 mV for the hydrogen evolution reaction (HER) in 1.0 m KOH electrolyte. Its exceptional activity is further shown in its small Tafel slope of 39.4 and 62.0 mV dec(-1) for OER and HER, respectively. More importantly, remarkable durability and stability are also observed. When used for overall water splitting, the Ni0.75Fe0.125V0.125-LDHs/NF electrodes require a voltage of only 1.591 V to reach 10 mA cm(-2) in alkaline solution. These outstanding performances are mainly attributed to the synergistic effect of the ternary metal system that boosts the intrinsic catalytic activity and active surface area. This work explores a promising way to achieve the optimal inexpensive Ni-based hydroxide electrocatalyst for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2018, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1703257, "DOI": "10.1002/smll.201703257", "DOI Link": "http://dx.doi.org/10.1002/smll.201703257", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425744600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, L; Yang, WJ; Wan, G; Zhang, R; Zheng, XS; Zhou, H; Yu, SH; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Long; Yang, Weijie; Wan, Gang; Zhang, Rui; Zheng, Xusheng; Zhou, Hua; Yu, Shu-Hong; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Atom Electrocatalysts from Multivariate Metal-Organic Frameworks for Highly Selective Reduction of CO2at Low Pressures", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) are of great interest because of their ultrahigh activity and selectivity. However, it is difficult to construct model SACs according to a general synthetic method, and therefore, discerning differences in activity of diverse single-atom catalysts is not straightforward. Herein, a general strategy for synthesis of single-atom metals implanted in N-doped carbon (M-1-N-C; M=Fe, Co, Ni and Cu) has been developed starting from multivariate metal-organic frameworks (MOFs). The M-1-N-C catalysts, featuring identical chemical environments and supports, provided an ideal platform for differentiating the activity of single-atom metal species. When employed in electrocatalytic CO(2)reduction, Ni-1-N-C exhibited a very high CO Faradaic efficiency (FE) up to 96.8 % that far surpassed Fe-1-, Co-1- and Cu-1-N-C. Remarkably, the best-performer, Ni-1-N-C, even demonstrated excellent CO FE at low CO(2)pressures, thereby representing a promising opportunity for the direct use of dilute CO(2)feedstock.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2020, "Volume": 59, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20589, "End Page": 20595, "Article Number": null, "DOI": "10.1002/anie.202008787", "DOI Link": "http://dx.doi.org/10.1002/anie.202008787", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564424300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, YZ; He, CG; Wen, YF; Ye, YS; Zhou, XP; Xie, XL; Mai, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Yuezhan; He, Chengen; Wen, Yingfeng; Ye, Yunsheng; Zhou, Xingping; Xie, Xiaolin; Mai, Yiu-Wing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior flame retardancy and smoke suppression of epoxy-based composites with phosphorus/nitrogen co-doped graphene", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorus and/or nitrogen doping is an effective method of improving the physical and chemical properties of reduced graphene oxide (rGO). In this work, phosphorus and nitrogen co-doped rGO (PN-rGO), synthesized using a scalable hydrothermal and microwave process, was used as an additive to improve the flame retardancy of epoxy resin (EP) for the first time. Chemical structure and morphology characterization confirmed that the nitrogen and phosphorus atoms were doped into the graphite lattice adopting pyrrolic-N, pyridinic-N, quaternary-N and pyrophosphate and metaphosphate forms. Doping increased the oxidization resistance of rGO and the thermal-oxidative stability of its composites' char, while also improving the catalytic charring ability of polymer. Both effects resulted in the formation of a stable char protective layer during burning and to a significant improvement in flame retardation and smoke suppression in the final composites. The peak heat release rate (PHRR), total heat release (THR) and total smoke production (TSP) for the EP-based composite (containing 5 wt% PN-rGO) decreased by 30.9%, 29.3% and 51.3%, respectively, compared to neat EP. Our work has produced a promising graphene-based flame retardant additive for the mass production of high-performance composites, also expended the application of heteroatom-doped graphene. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 346, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 140, "End Page": 151, "Article Number": null, "DOI": "10.1016/j.jhazmat.2017.12.019", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2017.12.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423641100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Gai, KM; Li, C; Guo, Q; Chen, QJ; He, X; Liu, LS; Zhang, YJ; Lu, YF; Chen, XL; Sun, T; Huang, YZ; Cheng, JJ; Jiang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yu; Gai, Kaimin; Li, Chao; Guo, Qin; Chen, Qinjun; He, Xi; Liu, Lisha; Zhang, Yujie; Lu, Yifei; Chen, Xinli; Sun, Tao; Huang, Yongzhuo; Cheng, Jianjun; Jiang, Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macrophage-Membrane-Coated nulloparticles for Tumor-Targeted Chemotherapy", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various delivery vectors have been integrated within biologically derived membrane systems to extend their residential time and reduce their reticuloendothelial system (RES) clearance during systemic circulation. However, rational design is still needed to further improve the in situ penetration efficiency of chemo-drug-loaded membrane delivery-system formulations and their release profiles at the tumor site. Here, a macrophage membrane-coated nulloparticle is developed for tumor-targeted chemotherapy delivery with a controlled release profile in response to tumor microenvironment stimuli. Upon fulfilling its mission of tumor homing and RES evasion, the macrophage-membrane coating can be shed via morphological changes driven by extracellular microenvironment stimuli. The nulloparticles discharged from the outer membrane coating show penetration efficiency enhanced by their size advantage and surface modifications. After internalization by the tumor cells, the loaded drug is quickly released from the nulloparticles in response to the endosome pH. The designed macrophage-membrane-coated nulloparticle (cskc-PPiP/PTX@Ma) exhibits an enhanced therapeutic effect inherited from both membrane-derived tumor homing and step-by-step controlled drug release. Thus, the combination of a biomimetic cell membrane and a cascade-responsive polymeric nulloparticle embodies an effective drug delivery system tailored to the tumor microenvironment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 18, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1908, "End Page": 1915, "Article Number": null, "DOI": "10.1021/acs.nullolett.7b05263", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.7b05263", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427910600049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, Y; Fan, L; Liu, C; Wen, HQ; Wang, SH; Guan, PF; Chen, DF; Ning, CY; Zhou, L; Tan, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Yian; Fan, Lei; Liu, Can; Wen, Huiquan; Wang, Shihuan; Guan, Pengfei; Chen, Dafu; Ning, Chengyun; Zhou, Lei; Tan, Guoxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An injectable, self-healing, electroconductive extracellular matrix-based hydrogel for enhancing tissue repair after traumatic spinal cord injury", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Injectable biomaterial-based treatment is a promising strategy to enhance tissue repair after traumatic spinal cord injury (SCI) by bridging cavity spaces. However, there are limited reports of injectable, electroconductive hydrogels with self-healing properties being employed for the treatment of traumatic SCI. Hence, a natural extracellular matrix (ECM) biopolymer (chondroitin sulphate and gelatin)-based hydrogel containing polypyrrole, which imparted electroconductive properties, is developed for traumatic SCI repair. The resulting hydrogels showed mechanical (similar to 928 Pa) and conductive properties (4.49 mS/cm) similar to natural spinal cord tissues. Moreover, the hydrogels exhibited shear-thinning and self-healing abilities, which allows it to be effectively injected into the injury site and to fill the lesion cavity to accelerate the tissue repair of traumatic SCI. In vitro, electroconductive ECM hydrogels promoted neuronal differentiation, enhanced axon outgrowth, and inhibited astrocyte differentiation. The electroconductive ECM hydrogel activated endogenous neural stem cell neurogenesis in vivo (n = 6), and induced myelinated axon regeneration into the lesion site via activation of the PI3K/AKT and MEK/ERK pathways, thereby achieving significant locomotor function restoration in rats with spinal cord injury (p < 0.001, compared to SCI group). Overall, the injectable self-healing electroconductive ECM-based hydrogels developed in this study are ideal biomaterials for treatment of traumatic SCI.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 98, "End Page": 111, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.05.039", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.05.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709370300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, PC; Mueller, J; Raney, JR; Zheng, XY; Alavi, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Pengcheng; Mueller, Jochen; Raney, Jordan R.; Zheng, Xiaoyu (Rayne); Alavi, Amir H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical metamaterials and beyond", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanical metamaterials enable the creation of structural materials with unprecedented mechanical properties. However, thus far, research on mechanical metamaterials has focused on passive mechanical metamaterials and the tunability of their mechanical properties. Deep integration of multi-functionality, sensing, electrical actuation, information processing, and advancing data-driven designs are grand challenges in the mechanical meta-materials community that could lead to truly intelligent mechanical meta-materials. In this perspective, we provide an overview of mechanical metamaterialswithin and beyond their classical mechanical functionalities. We discuss various aspects of data-driven approaches for inverse design and optimization of multifunctional mechanical metamaterials. Our aim is to provide new roadmaps for design and discovery of next-generation active and responsive mechanical metamaterials that can interact with the surrounding environment and adapt to various conditions while inheriting all outstanding mechanical features of classical mechanical metamaterials. Next, we deliberate the emergingmechanicalmetamaterials with specific functionalities to design informative and scientific intelligent devices. We highlight open challenges ahead of mechanical metamaterial systems at the component and integration levels and their transition into the domain of application beyond their mechanical capabilities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6004, "DOI": "10.1038/s41467-023-41679-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41679-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001116568300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arbabi, E; Arbabi, A; Kamali, SM; Horie, Y; Faraji-Dana, M; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arbabi, Ehsan; Arbabi, Amir; Kamali, Seyedeh Mahsa; Horie, Yu; Faraji-Dana, MohammadSadegh; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MEMS-tunable dielectric metasurface lens", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Varifocal lenses, conventionally implemented by changing the axial distance between multiple optical elements, have a wide range of applications in imaging and optical beam scanning. The use of conventional bulky refractive elements makes these varifocal lenses large, slow, and limits their tunability. Metasurfaces, a new category of lithographically defined diffractive devices, enable thin and lightweight optical elements with precisely engineered phase profiles. Here we demonstrate tunable metasurface doublets, based on microelectromechanical systems (MEMS), with more than 60 diopters (about 4%) change in the optical power upon a 1-mu m movement of one metasurface, and a scanning frequency that can potentially reach a few kHz. They can also be integrated with a third metasurface to make compact microscopes (similar to 1mm thick) with a large corrected field of view (similar to 500 mu m or 40 degrees) and fast axial scanning for 3D imaging. This paves the way towards MEMS-integrated metasurfaces as a platform for tunable and reconfigurable optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 599, "Times Cited, All Databases": 673, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 812, "DOI": "10.1038/s41467-018-03155-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03155-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425935100025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, ZN; Zhu, CP; Li, Y; Lei, XF; Zhang, W; Xiao, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Zhanull; Zhu, Chengpu; Li, Yan; Lei, Xingfeng; Zhang, Wei; Xiao, Jianliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rehealable, fully recyclable, and malleable electronic skin enabled by dynamic covalent thermoset nullocomposite", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic skin (e-skin) mimicking functionalities and mechanical properties of natural skin can find broad applications. We report the first dynamic covalent thermoset-based e-skin, which is connected through robust covalent bonds, rendering the resulting devices good chemical and thermal stability at service condition. By doping the dynamic covalent thermoset with conductive silver nulloparticles, we demonstrate a robust yet rehealable, fully recyclable, and malleable e-skin. Tactile, temperature, flow, and humidity sensing capabilities are realized. The e-skin can be rehealed when it is damaged and can be fully recycled at room temperature, which has rarely, if at all, been demonstrated for e-skin. After rehealing or recycling, the e-skin regains mechanical and electrical properties comparable to the original e-skin. In addition, malleability enables the e-skin to permanently conform to complex, curved surfaces without introducing excessive interfacial stresses. These properties of the e-skin yield an economical and eco-friendly technology that can find broad applications in robotics, prosthetics, health care, and human-computer interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaq0508", "DOI": "10.1126/sciadv.aaq0508", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaq0508", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426845500055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, SH; King, PJ; Tian, RY; Boland, CS; Coelho, J; Zhang, CF; McBean, P; McEvoy, N; Kremer, MP; Daly, D; Coleman, JN; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Sang-Hoon; King, Paul J.; Tian, Ruiyuan; Boland, Conor S.; Coelho, Joao; Zhang, Chuanfang (John); McBean, Patrick; McEvoy, Niall; Kremer, Matthias P.; Daly, Dermot; Coleman, Jonathan N.; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High areal capacity battery electrodes enabled by segregated nullotube networks", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing the energy storage capability of lithium-ion batteries necessitates maximization of their areal capacity. This requires thick electrodes performing at near-theoretical specific capacity. However, achievable electrode thicknesses are restricted by mechanical instabilities, with high-thickness performance limited by the attainable electrode conductivity. Here we show that forming a segregated network composite of carbon nullotubes with a range of lithium storage materials (for example, silicon, graphite and metal oxide particles) suppresses mechanical instabilities by toughening the composite, allowing the fabrication of high-performance electrodes with thicknesses of up to 800 mu m. Such composite electrodes display conductivities up to 1 x 10(4) S m(-1) and low charge-transfer resistances, allowing fast charge-delivery and enabling near-theoretical specific capacities, even for thick electrodes. The combination of high thickness and specific capacity leads to areal capacities of up to 45 and 30 mAh cm(-2) for anodes and cathodes, respectively. Combining optimized composite anodes and cathodes yields full cells with state-of-the-art areal capacities (29 mAh cm(-2)) and specific/volumetric energies (480 Wh kg(-1) and 1,600 Wh l(-1)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 560, "End Page": 567, "Article Number": null, "DOI": "10.1038/s41560-019-0398-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0398-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474920100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, WL; Li, GR; Luo, D; Zhang, YG; Zhao, Y; Zhou, GF; Shui, LL; Wang, X; Chen, ZW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Weilong; Li, Gaoran; Luo, Dan; Zhang, Yongguang; Zhao, Yan; Zhou, Guofu; Shui, Lingling; Wang, Xin; Chen, Zhongwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Micro-nulloclusters of Bimetallic Layered Hydroxide Polyhedrons as Advanced Sulfur Reservoir for High-Performance Lithium-Sulfur Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational construction of sulfur electrodes is essential in pursuit of practically viable lithium-sulfur (Li-S) batteries. Herein, bimetallic NiCo-layered double hydroxide (NiCo-LDH) with a unique hierarchical micro-nullo architecture is developed as an advanced sulfur reservoir for Li-S batteries. Compared with the monometallic Co-layered double hydroxide (Co-LDH) counterpart, the bimetallic configuration realizes much enriched, miniaturized, and vertically aligned LDH nullosheets assembled in hollow polyhedral nulloarchitecture, which geometrically benefits the interface exposure for host-guest interactions. Beyond that, the introduction of secondary metal intensifies the chemical interactions between layered double hydroxide (LDH) and sulfur species, which implements strong sulfur immobilization and catalyzation for rapid and durable sulfur electrochemistry. Furthermore, the favorable NiCo-LDH is architecturally upgraded into closely packed micro-nullo clusters with facilitated long-range electron/ion conduction and robust structural integrity. Due to these attributes, the corresponding Li-S cells realize excellent cyclability over 800 cycles with a minimum capacity fading of 0.04% per cycle and good rate capability up to 2 C. Moreover, highly reversible areal capacity of 4.3 mAh cm(-2) can be achieved under a raised sulfur loading of 5.5 mg cm(-2). This work provides not only an effective architectural design but also a deepened understanding on bimetallic LDH sulfur reservoir for high-performance Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003400, "DOI": "10.1002/advs.202003400", "DOI Link": "http://dx.doi.org/10.1002/advs.202003400", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612806700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, YC; Komsa, HP; Yeh, CH; Björkman, T; Liang, ZY; Ho, CH; Huang, YS; Chiu, PW; Krasheninnikov, AV; Suenaga, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yung-Chang; Komsa, Hannu-Pekka; Yeh, Chao-Hui; Bjorkman, Torbjorn; Liang, Zheng-Yong; Ho, Ching-Hwa; Huang, Ying-Sheng; Chiu, Po-Wen; Krasheninnikov, Arkady V.; Suenaga, Kazu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Layer ReS2: Two-Dimensional Semiconductor with Tunable In-Plane Anisotropy", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rhenium disulfide (ReS2) and diselenide (ReSe2), the group 7 transition metal dichalcogenides (TMDs), are known to have a layered atomic structure showing an in-plane motif of diamond-shaped-chains (DS-chains) arranged in parallel. Using a combination of transmission electron microscopy and transport measurements, we demonstrate here the direct correlation of electron transport anisotropy in single-layered ReS2 with the atomic orientation of the DS-chains, as also supported by our density functional theory calculations. We further show that the direction of conducting channels in ReS2 and ReSe2 can be controlled by electron beam irradiation at elevated temperatures and follows the strain induced to the sample. Furthermore, high chalcogen deficiency can induce a structural transformation to a nonstoichiometric phase, which is again strongly direction-dependent. This tunable in-plane transport behavior opens up great avenues for creating nulloelectronic circuits in 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11249, "End Page": 11257, "Article Number": null, "DOI": "10.1021/acsnullo.5b04851", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b04851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365464800073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YJ; Luan, DY; Chen, Y; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yongjin; Luan, Deyan; Chen, Ye; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Copper-Substituted CoS2@CuxS Double-Shelled nulloboxes by Sequential Ion Exchange for Efficient Sodium Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The construction of hybrid architectures for electrode materials has been demonstrated as an efficient strategy to boost sodium-storage properties because of the synergetic effect of each component. However, the fabrication of hybrid nullostructures with a rational structure and desired composition for effective sodium storage is still challenging. In this study, an integrated nullostructure composed of copper-substituted CoS2@CuxS double-shelled nulloboxes (denoted as Cu-CoS2@CuxS DSNBs) was synthesized through a rational metal-organic framework (MOF)-based templating strategy. The unique shell configuration and complex composition endow the Cu-CoS2@CuxS DSNBs with enhanced electrochemical performance in terms of superior rate capability and stable cyclability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2020, "Volume": 59, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2644, "End Page": 2648, "Article Number": null, "DOI": "10.1002/anie.201912924", "DOI Link": "http://dx.doi.org/10.1002/anie.201912924", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507629900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, C; Song, G; Gao, MC; Feng, R; Chen, PY; Brechtl, J; Chen, Y; An, K; Guo, W; Poplawsky, JD; Li, S; Samaei, AT; Chen, W; Hu, A; Choo, H; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Chanho; Song, Gian; Gao, Michael C.; Feng, Rui; Chen, Peiyong; Brechtl, Jamieson; Chen, Yan; An, Ke; Guo, Wei; Poplawsky, Jonathan D.; Li, Song; Samaei, A. T.; Chen, Wei; Hu, Alice; Choo, Hahn; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice distortion in a strong and ductile refractory high-entropy alloy", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The maximization of the mixing entropy with the optimal range of enthalpy in high-entropy alloys (HEAs) can promote the formation of a stable single solid-solution phase with the absence of competing intermetallic compounds. The resultant effects, such as lattice distortion, can contribute to excellent mechanical properties, which has motivated numerous efforts to develop and design single-phase HEM. However, challenges still remain, particularly on quantifying the lattice distortion and relating it to materials properties. In this study, we have developed a NbTaTiV refractory HEA with a single body-pcentered-cubic (BCC) structure using an integrated experimental and theoretical approach. The theoretical efforts include thermodynamic modeling, i.e., CALculation of PHAse Diagram (CALPHAD). The microstructural evolutions have been investigated by systematic heat-treatment processes. The typical dendrite microstructure was observed, which is caused by the elemental segregation during the solidification in the as-cast condition. The structural inhomogeneity and chemical segregation were completely eliminated by the proper homogenization treatment at 1200 degrees C for 3 days. The homogeneous elemental distribution was quantitatively verified by the Atom Probe Tomography (APT) technique. Importantly, results indicate that this HEA exhibits the high yield strength and ductility at both room and high temperatures (up to 900 degrees C). Furthermore, the effects of the high mixing entropy on the mechanical properties are discussed and quantified in terms of lattice distortions and interatomic interactions of the NbTaTiV HEA via first-principles calculations. It is found that the local severe lattice distortions are induced, due to the atomic interactions and atomic-size mismatch in the homogenization-treated NbTaTiV refractory HEA. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 447, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 160, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 158, "End Page": 172, "Article Number": null, "DOI": "10.1016/j.actamat.2018.08.053", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.08.053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447576600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Antaris, AL; Chen, H; Diao, S; Ma, ZR; Zhang, Z; Zhu, SJ; Wang, J; Lozano, AX; Fan, QL; Chew, LL; Zhu, M; Cheng, K; Hong, XC; Dai, HJ; Cheng, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Antaris, Alexander L.; Chen, Hao; Diao, Shuo; Ma, Zhuoran; Zhang, Zhe; Zhu, Shoujun; Wang, Joy; Lozano, Alexander X.; Fan, Quli; Chew, Leila; Zhu, Mark; Cheng, Kai; Hong, Xuechuan; Dai, Hongjie; Cheng, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high quantum yield molecule-protein complex fluorophore for near-infrared II imaging", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluorescence imaging in the second near-infrared window (NIR-II) allows visualization of deep anatomical features with an unprecedented degree of clarity. NIR-II fluorophores draw from a broad spectrum of materials spanning semiconducting nullomaterials to organic molecular dyes, yet unfortunately all water-soluble organic molecules with >1,000 nm emission suffer from low quantum yields that have limited temporal resolution and penetration depth. Here, we report tailoring the supramolecular assemblies of protein complexes with a sulfonated NIR-II organic dye (CH-4T) to produce a brilliant 110-fold increase in fluorescence, resulting in the highest quantum yield molecular fluorophore thus far. The bright molecular complex allowed for the fastest video-rate imaging in the second NIR window with similar to 50-fold reduced exposure times at a fast 50 frames-per-second (FPS) capable of resolving mouse cardiac cycles. In addition, we demonstrate that the NIR-II molecular complexes are superior to clinically approved ICG for lymph node imaging deep within the mouse body.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 495, "Times Cited, All Databases": 523, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15269, "DOI": "10.1038/ncomms15269", "DOI Link": "http://dx.doi.org/10.1038/ncomms15269", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401626200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, G; Zheng, XS; Cui, PX; Jiang, HY; Wang, XQ; Qu, YT; Chen, WX; Lin, Y; Li, H; Han, X; Hu, YM; Liu, PG; Zhang, QH; Ge, JJ; Yao, YC; Sun, RB; Wu, Y; Gu, L; Hong, X; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Geng; Zheng, Xusheng; Cui, Peixin; Jiang, Hongyu; Wang, Xiaoqian; Qu, Yunteng; Chen, Wenxing; Lin, Yue; Li, Hai; Han, Xiao; Hu, Yanmin; Liu, Peigen; Zhang, Qinghua; Ge, Jingjie; Yao, Yancai; Sun, Rongbo; Wu, Yuen; Gu, Lin; Hong, Xun; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general synthesis approach for amorphous noble metal nullosheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble metal nullomaterials have been widely used as catalysts. Common techniques for the synthesis of noble metal often result in crystalline nullostructures. The synthesis of amorphous noble metal nullostructures remains a substantial challenge. We present a general route for preparing dozens of different amorphous noble metal nullosheets with thickness less than 10 nm by directly annealing the mixture of metal acetylacetonate and alkali salts. Tuning atom arrangement of the noble metals enables to optimize their catalytic properties. Amorphous Ir nullosheets exhibit a superior performance for oxygen evolution reaction under acidic media, achieving 2.5-fold, 17.6-fold improvement in mass activity (at 1.53 V vs. reversible hydrogen electrode) over crystalline Ir nullosheets and commercial IrO2 catalyst, respectively. In situ X-ray absorption fine structure spectra indicate the valance state of Ir increased to less than + 4 during the oxygen evolution reaction process and recover to its initial state after the reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4855, "DOI": "10.1038/s41467-019-12859-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12859-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492140800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Wang, M; Tang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Heng; Wang, Meng; Tang, Yongbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel zinc-ion hybrid supercapacitor for long-life and low-cost energy storage applications", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of multivalent cation based rechargeable devices have attracted increased interest because that one mole of multivalent ion can contribute double (for M2+) or triple (for M3+) electrons than monovalent ion (M+). Recently, multivalent cation based battery systems (e.g. Mg2+ and Al3+ batteries) have been widely investigated, however, less attention were paid on multivalent cation based supercapacitors and especially hybrid supercapacitors. Herein, we demonstrate a Zn-ion based hybrid supercapacitor (Zn-HSC) through directly designing Zn foil as both anode and current collector, and bio-carbon derived porous material as the cathode. The bivalent nature and high abundance of zinc can enable the Zn-HSC to achieve high energy density with low cost. After optimization, this Zn-HSC demonstrated superior electrochemical performances such as high discharge capacitance (170 F g(-1) at 0.1 A g(-1)), good rate performance (similar to 85% capacitance retention at 2 A g(-1)), high energy density (52.7 Wh kg(-1) at 1725 W kg(-1) based on the weight of active materials), and excellent cycling stability with 91% capacitance retention after 20,000 cycles at 2 A g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 514, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 13, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 7, "Article Number": null, "DOI": "10.1016/j.ensm.2017.12.022", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2017.12.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436924800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jo, WK; Kumar, S; Eslava, S; Tonda, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jo, Wan-Kuen; Kumar, Santosh; Eslava, Salvador; Tonda, Surendar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Bi2WO6/RGO/g-C3N4 2D/2D/2D hybrid Z-scheme heterojunctions with large interfacial contact area for efficient charge separation and high-performance photoreduction of CO2 and H2O into solar fuels", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have rationally constructed a hybrid heterojunction comprising of Bi2WO6, reduced graphene oxide, and g-C3N4 (BWO/RGO/CN) with a 2D/2D/2D configuration for efficient photoreduction to generate solar fuels. These heterojunctions displayed dramatically improved performance towards CO2 reduction to generate CO and CH4 under visible-light irradiation, compared to the base material (CN), P25 as reference, as well as binary BWO/CN and RGO/CN heterojunctions. Particularly, the BWO/RGO/CN heterojunctions with 1 wt. % RGO and 15 wt. % BWO achieved record performance in the yields of carbonaceous products (CO + CH4) compared to other synthesized catalysts, with a selectivity of 92% against H-2. The remarkable photocatalytic performance was mainly attributed to the unique 2D/2D/2D architecture that creates large interfacial contact between the constituent materials for rapid charge transfer, to hinder the direct recombination of photoinduced electrons and holes. Notably, RGO played two significant roles: as a supporter to capture the electrons from CN, and as a redox mediator to promote the Z-scheme charge transfer between CN and BWO. The result is a greater extent of charge separation in the present BWO/RGO/CN heterojunction system, as evidenced by the photoluminescence, photocurrent responses, and electron microscopy findings. More importantly, the heterojunctions displayed excellent stability during recycling tests with no obvious loss in the generation of CO and CH4 from photoreduction of CO2. This interesting interfacial engineering approach presented herein offers a promising route for the rational design of a new class of layered multicomponent heterojunctions with 2D/2D/2D architecture for various applications in environmental protection and solar energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2018, "Volume": 239, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 586, "End Page": 598, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.08.056", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.08.056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446283800059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GQ; Zhang, MY; Liu, SH; Yuan, M; Wu, JJ; Yu, M; Teng, LJ; Xu, ZW; Guo, JH; Li, GL; Liu, ZY; Ma, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guoqiang; Zhang, Mingyang; Liu, Sanhu; Yuan, Man; Wu, Junjie; Yu, Mei; Teng, Lijun; Xu, Zhiwu; Guo, Jinhong; Li, Guanglin; Liu, Zhiyuan; Ma, Xing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional flexible electronics using solidified liquid metal with regulated plasticity", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional liquid metal structures can be created by manipulating ductile gallium-indium alloy wires that are then encapsulated in an elastomer and heated to recover their fluidity, and can remain in a liquid state for a range of temperatures due to a supercooling effect. Liquid metals based on gallium alloy are of potential use in the development of soft and stretchable electronics due to their intrinsic fluidity and high conductivity. However, it is challenging to build three-dimensional circuits using liquid metals, which limits the complexity and integration of the resulting devices. Here we show that a gallium-indium alloy can be used to fabricate flexible electronics with three-dimensional circuits by exploiting the solid-liquid phase transition and plastic deformation of the liquid metal. Solid but plastically deformable alloy wires are shaped into circuits at low temperatures (under 15 degrees C) and encapsulated in an elastomer, before being heated above their melting temperature. Subsequently, the supercooling effect allows the alloy to maintain a liquid state at a wide range of temperatures, including below the melting point. We use the technique to fabricate high-sensitivity strain sensors, three-dimensional interconnect arches for integrating an array of light-emitting diodes, and a three-dimensional wearable sensor and multilayer flexible circuit board for monitoring finger motion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 154, "End Page": 163, "Article Number": null, "DOI": "10.1038/s41928-022-00914-8", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00914-8", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921806400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Altan, A; Aytac, Z; Uyar, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Altan, Aylin; Aytac, Zeynep; Uyar, Tamer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carvacrol loaded electrospun fibrous films from zein and poly(lactic acid) for active food packaging", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The composite fibrous films were developed from zein and poly(lactic acid) (PLA) by incorporating carvacrol at three different concentrations (5, 10 and 20%) using electrospinning. The morphology and size of fibers obtained from both zein and PLA were affected by the level of the incorporated carvacrol. The Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA) results showed that carvacrol was encapsulated in electrospun zein and PLA fibers. The antioxidant activity of carvacrol loaded zein fibers ranged from 62 to 75%, while antioxidant capacity of PLA fibers varied from 53 to 65% for 5-20% carvacrol content. The composite fibrous films showed a sustained diffusion controlled release behavior. Preliminary studies on whole wheat bread samples showed that carvacrol loaded electrospun zein and PLA fibers are able to preserve bread samples, indicating that they are good candidates for active food packaging applications to extend the shelf life of whole wheat bread. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 48, "End Page": 59, "Article Number": null, "DOI": "10.1016/j.foodhyd.2018.02.028", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2018.02.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429962700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, DY; Wu, ZP; Li, PG; An, YH; Liu, H; Guo, XC; Yan, H; Wang, GF; Sun, CL; Li, LH; Tang, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Daoyou; Wu, Zhenping; Li, Peigang; An, Yuehua; Liu, Han; Guo, Xuncai; Yan, Hui; Wang, Guofeng; Sun, Changlong; Li, Linghong; Tang, Weihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabrication of β-Ga2O3 thin films and solar-blind photodetectors by laser MBE technology", "Source Title": "OPTICAL MATERIALS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser molecular beam epitaxy technology has been employed to deposit beta-gallium oxide (beta-Ga2O3) on (0001) sapphire substrates. After optimizing the growth parameters, (2) overbar01)-oriented beta-Ga2O3 thin film was obtained. Ultraviolet-visible absorption spectrum demonstrates that the prepared beta-Ga2O3 thin film shows excellent solar-blind ultraviolet (UV) characteristic with a band gap of 5.02 eV. A prototype photodetector device with a metal-semiconductor-metal structure has been fabricated using high quality beta-Ga2O3 film. The device exhibits obvious photoresponse under 254 nm UV light irradiation, suggesting a potential application in solar-blind photodetectors.(C) 2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2014, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1067, "End Page": 1076, "Article Number": null, "DOI": "10.1364/OME.4.001067", "DOI Link": "http://dx.doi.org/10.1364/OME.4.001067", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335493800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, YY; Chen, BH; Xiang, F; Zhou, JX; Wang, H; Suo, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yuanyuan; Chen, Baohong; Xiang, Feng; Zhou, Jinxiong; Wang, Hong; Suo, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chloride can retain over 70% of its initial water even in environment with relative humidity of only 10% RH. The excellent water retention capacities of these hydrogels will make more applications of hydrogels become possible. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2014, "Volume": 105, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 151903, "DOI": "10.1063/1.4898189", "DOI Link": "http://dx.doi.org/10.1063/1.4898189", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344344700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, RY; Xu, BY; Grundish, NS; Xia, Y; Li, YT; Lu, CW; Liu, YJ; Wu, N; Goodenough, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Ruyi; Xu, Biyi; Grundish, Nicholas S.; Xia, Yang; Li, Yutao; Lu, Chengwei; Liu, Yijie; Wu, null; Goodenough, John B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Li2S6-Integrated PEO-Based Polymer Electrolytes for All-Solid-State Lithium-Metal Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of Li2S6 within a poly(ethylene oxide) (PEO)-based polymer electrolyte is demonstrated to improve the polymer electrolyte's ionic conductivity because the strong interplay between O-(PEO)(2-) and Li+ from Li2S6 reduces the crystalline volume within the PEO. The Li/electrolyte interface is stabilized by the in situ formation of an ultra-thin Li2S/Li2S2 layer via the reaction between Li2S6 and lithium metal, which increases the ionic transport at the interface and suppresses lithium dendrite growth. A symmetric Li/Li cell with the Li2S6-integrated composite electrolyte has excellent cyclability and a high critical current density of 0.9 mA cm(-2) at 40 degrees C. Impressive electrochemical performance is demonstrated with all-solid-state Li/LiFePO4 and high-voltage Li/LiNi0.8Mn0.1Co0.1O2 cells at 40 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2021, "Volume": 60, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17701, "End Page": 17706, "Article Number": null, "DOI": "10.1002/anie.202106039", "DOI Link": "http://dx.doi.org/10.1002/anie.202106039", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000668285900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kibria, MG; Chowdhury, FA; Zhao, S; AlOtaibi, B; Trudeau, ML; Guo, H; Mi, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kibria, M. G.; Chowdhury, F. A.; Zhao, S.; AlOtaibi, B.; Trudeau, M. L.; Guo, H.; Mi, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible light-driven efficient overall water splitting using p-type metal-nitride nullowire arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar water splitting for hydrogen generation can be a potential source of renewable energy for the future. Here we show that efficient and stable stoichiometric dissociation of water into hydrogen and oxygen can be achieved under visible light by eradicating the potential barrier on nonpolar surfaces of indium gallium nitride nullowires through controlled p-type dopant incorporation. An apparent quantum efficiency of similar to 12.3% is achieved for overall neutral (pH similar to 7.0) water splitting under visible light illumination (400-475 nm). Moreover, using a double-band p-type gallium nitride/indium gallium nitride nullowire heterostructure, we show a solar-to-hydrogen conversion efficiency of similar to 1.8% under concentrated sunlight. The dominullt effect of near-surface band structure in transforming the photocatalytic performance is elucidated. The stability and efficiency of this recyclable, wafer-level nulloscale metal-nitride photocatalyst in neutral water demonstrates their potential use for large-scale solar-fuel conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6797, "DOI": "10.1038/ncomms7797", "DOI Link": "http://dx.doi.org/10.1038/ncomms7797", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353702500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YB; Sun, ZZ; Tang, C; Zhou, YX; Zeng, L; Huang, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yabin; Sun, Zongzhao; Tang, Chao; Zhou, Yuxia; Zeng, Lei; Huang, Limin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of photocatalytic hydrogen evolution activity of porous oxygen doped g-C3N4 with nitrogen defects induced by changing electron transition", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous structure, nitrogen defects and oxygen dopants are simultaneously introduced into the framework of graphitic carbon nitride (g-C3N4) by a simple co-pyrolysis of dicyandiamide and ammonium persulphate ((NH4)(2)S2O8). The (NH4)(2)S2O8 plays multi-function roles in the co-pyrolysis process. It not only restrains polycondensation to generate nitrogen defects but also introduces porous structure and oxygen dopants due to its strong oxidative ability. The synergetic effect of the nitrogen defects and oxygen dopants leads to the change of pi band state and LP state (lone pair electrons), causing the change of electron transition in the modified g-C3N4. The transitions from impurity levels play a predominullt role in excitation process while the transition from intrinsic HOMO to LUMO becomes subordinate, which improve the charge separation significantly. The modified g-C3N4 exhibits excellent photocatalytic hydrogen evolution activity under visible light illumination, which is almost 6 times higher than pristine g-C3N4 because of the improved efficiency of charge separation and increased specific surface area. These findings provide a simple and efficient method to improve the photocatalytic activity of g-C3N4 by changing the electron transition through a rational band structure engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 240, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 30, "End Page": 38, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.08.059", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.08.059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461002800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, X; Qiu, M; Li, YW; Zhang, QM; Li, SQ; Yang, Z; Feng, C; Zhang, WD; Dai, JG; Lei, DY; Jin, W; Xu, LJ; Zhang, T; Qin, J; Wang, HQ; Fan, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Xiao; Qiu, Meng; Li, Yanwen; Zhang, Q. M.; Li, Siqi; Yang, Zhuo; Feng, Chi; Zhang, Weidong; Dai, Jian-Guo; Lei, Dangyuan; Jin, Wei; Xu, Lijin; Zhang, Tao; Qin, Jie; Wang, Huiqun; Fan, Shanhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creating an Eco-Friendly Building Coating with Smart Subambient Radiative Cooling", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Subambient daytime radiative cooling (SDRC) provides a promising electricity- and cryogen-free pathway for global energy-efficiency. However, current SDRC systems require stringent surface designs, which are neither cost-effective nor eco-friendly, to selectively emit thermal radiation to outer space and simultaneously maximize solar reflectance. Here, a generic method is developed to upgrade the conventional building-coating materials with a peculiar self-adaptive SDRC effect through combining particle scattering, sunlight-excited fluorescence, and mid-infrared broadband radiation. It is also theoretically proved that heat exchange with the sky can eliminate the use of resonullt microstructures and noble metal mirrors in conventional SDRC, and also leads to enhanced daytime cooling yet suppressed nighttime overcooling. When exposed to direct sunlight, the upgraded coating over an aluminum plate can achieve 6 degrees C (7 degrees C on a scale-model building) below the ambient temperature under a solar intensity of 744 W m(-2)(850 W m(-2)), yielding a cooling power of 84.2 W m(-2). The results pave the way for practical large-scale applications of high-performance SDRC for human thermal comfort in buildings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 32, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906751, "DOI": "10.1002/adma.201906751", "DOI Link": "http://dx.doi.org/10.1002/adma.201906751", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569487400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, Y; Guo, JW; Li, JH; Zhu, KJ; Liao, MH; Liu, XZ; Zhang, QH; Gu, L; Tang, L; Feng, X; Zhang, D; Li, W; Song, CL; Wang, LL; Yu, P; Chen, X; Wang, YY; Yao, H; Duan, WH; Xu, Y; Zhang, SC; Ma, XC; Xue, QK; He, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Yan; Guo, Jingwen; Li, Jiaheng; Zhu, Kejing; Liao, Menghan; Liu, Xiaozhi; Zhang, Qinghua; Gu, Lin; Tang, Lin; Feng, Xiao; Zhang, Ding; Li, Wei; Song, Canli; Wang, Lili; Yu, Pu; Chen, Xi; Wang, Yayu; Yao, Hong; Duan, Wenhui; Xu, Yong; Zhang, Shou-Cheng; Ma, Xucun; Xue, Qi-Kun; He, Ke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Realization of an Intrinsic Magnetic Topological Insulator", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An intrinsic magnetic topological insulator (TI) is a stoichiometric magnetic compound possessing both inherent magnetic order and topological electronic states. Such a material can provide a shortcut to various novel topological quantum effects but remained elusive experimentally for a long time. Here we report the experimental realization of thin films of an intrinsic magnetic TI, MnBi2Te4, by alternate growth of a Bi2Te3 quintuple layer and a MnTe bilayer with molecular beam epitaxy. The material shows the archetypical Dirac surface states in angle-resolved photoemission spectroscopy and is demonstrated to be an antiferromagnetic topological insulator with ferromagnetic surfaces by magnetic and transport measurements as well as first-principles calculations. The unique magnetic and topological electronic structures and their interplays enable the material to embody rich quantum phases such as quantum anomalous Hall insulators and axion insulators at higher temperature and in a well-controlled way.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 554, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 36, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76801, "DOI": "10.1088/0256-307X/36/7/076801", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/36/7/076801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475395200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yilgör, I; Yilgör, E; Wilkes, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yilgor, Iskender; Yilgor, Emel; Wilkes, Garth L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Critical parameters in designing segmented polyurethanes and their effect on morphology and properties: A comprehensive review", "Source Title": "POLYMER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A comprehensive discussion is provided of the critical physical, chemical and structural parameters, such as soft and hard segment structures and their molecular weights, polymer composition, solubility parameters, competitive intermolecular interactions and others, which strongly affect the morphology and bulk and surface properties of segmented thermoplastic polyurethanes, polyureas and poly-urethaneureas (TPUs). Important developments related to the design, synthesis and structure-property behavior of segmented polyurethanes are discussed. Although the main emphasis is placed on linear materials, some brief comments are also given on the effect of chemical crosslinking on the structure property behavior of segmented polyurethanes. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2015, "Volume": 58, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A1", "End Page": "A36", "Article Number": null, "DOI": "10.1016/j.polymer.2014.12.014", "DOI Link": "http://dx.doi.org/10.1016/j.polymer.2014.12.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349591000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SM; Hsu, A; Park, MH; Chae, SH; Yun, SJ; Lee, JS; Cho, DH; Fang, WJ; Lee, C; Palacios, T; Dresselhaus, M; Kim, KK; Lee, YH; Kong, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Soo Min; Hsu, Allen; Park, Min Ho; Chae, Sang Hoon; Yun, Seok Joon; Lee, Joo Song; Cho, Dae-Hyun; Fang, Wenjing; Lee, Changgu; Palacios, Tomas; Dresselhaus, Mildred; Kim, Ki Kang; Lee, Young Hee; Kong, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of large-area multilayer hexagonal boron nitride for high material performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although hexagonal boron nitride (h-BN) is a good candidate for gate-insulating materials by minimizing interaction from substrate, further applications to electronic devices with available two-dimensional semiconductors continue to be limited by flake size. While monolayer h-BN has been synthesized on Pt and Cu foil using chemical vapour deposition (CVD), multilayer h-BN is still absent. Here we use Fe foil and synthesize large-area multilayer h-BN film by CVD with a borazine precursor. These films reveal strong cathodoluminescence and high mechanical strength (Young's modulus: 1.16 +/- 0.1 TPa), reminiscent of formation of high-quality h-BN. The CVD-grown graphene on multilayer h-BN film yields a high carrier mobility of similar to 24,000 cm(2)V(-1) s(-1) at room temperature, higher than that (similar to 13,000(2)V(-1) s(-1)) with exfoliated h-BN. By placing additional h-BN on a SiO2/Si substrate for a MoS2 (WSe2) field-effect transistor, the doping effect from gate oxide is minimized and furthermore the mobility is improved by four (150) times.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/ncomms9662", "DOI Link": "http://dx.doi.org/10.1038/ncomms9662", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364936200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eom, Y; Kim, SM; Lee, M; Jeon, H; Park, J; Lee, ES; Hwang, SY; Park, J; Oh, DX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eom, Youngho; Kim, Seon-Mi; Lee, Minkyung; Jeon, Hyeonyeol; Park, Jaeduk; Lee, Eun Seong; Hwang, Sung Yeon; Park, Jeyoung; Oh, Dongyeop X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechano-responsive hydrogen-bonding array of thermoplastic polyurethane elastomer captures both strength and self-healing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-repairable materials strive to emulate curable and resilient biological tissue; however, their performance is currently insufficient for commercialization purposes because mending and toughening are mutually exclusive. Herein, we report a carbonate-type thermoplastic polyurethane elastomer that self-heals at 35 degrees C and exhibits a tensile strength of 43MPa; this elastomer is as strong as the soles used in footwear. Distinctively, it has abundant carbonyl groups in soft-segments and is fully amorphous with negligible phase separation due to poor hard-segment stacking. It operates in dual mechano-responsive mode through a reversible disorder-to-order transition of its hydrogen-bonding array; it heals when static and toughens when dynamic. In static mode, non-crystalline hard segments promote the dynamic exchange of disordered carbonyl hydrogen-bonds for self-healing. The amorphous phase forms stiff crystals when stretched through a transition that orders inter-chain hydrogen bonding. The phase and strain fully return to the pre-stressed state after release to repeat the healing process. Self-healing materials strive to emulate curable and resilient biological tissue but their performance is often insufficient for commercial applications because self-healing and toughening are mutually exclusive properties. Here, the authors report a tough and strong carbonate-type thermoplastic polyurethane elastomer that self-heals at ambient temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 621, "DOI": "10.1038/s41467-021-20931-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-20931-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614500600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZJ; Xu, Y; Lin, Y; Xiang, J; Feng, TH; Cao, QT; Li, JT; Lan, S; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhuojun; Xu, Yi; Lin, Ye; Xiang, Jin; Feng, Tianhua; Cao, Qitao; Li, Juntao; Lan, Sheng; Liu, Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Q Quasibound States in the Continuum for Nonlinear Metasurfaces", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sharp electromagnetic resonullces play an essential role in physics in general and optics in particular. The last decades have witnessed the successful developments of high-quality (Q) resonullces in microcavities operating below the light line, which however is fundamentally challenging to access from free space. Alternatively, metasurface-based bound states in the continuum (BICs) offer a complementary solution of creating high-Q resonullces in devices operating above the light line, yet the experimentally demonstrated Q factors under normal excitations are still limited. Here, we present the realizations of quasi-BIC under normal excitation with a record Q factor up to 18 511 by engineering the symmetry properties and the number of the unit cells in all-dielectric metasurface platforms. The high-Q quasi-BICs exhibit exceptionally high conversion efficiency for the third harmonic generation and even enable the second harmonic generation in Si metasurfaces. Such ultrasharp resonullces achieved in this work may immediately boost the performances of BICs in a plethora of fundamental research and device applications, e.g., cavity QED, biosensing, nullolasing, and quantum light generations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 613, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2019, "Volume": 123, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 253901, "DOI": "10.1103/PhysRevLett.123.253901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.123.253901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503050000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morales-Guio, CG; Tilley, SD; Vrubel, H; Grätzel, M; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morales-Guio, Carlos G.; Tilley, S. David; Vrubel, Heron; Graetzel, Michael; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concerns over climate change resulting from accumulation of anthropogenic carbon dioxide in the atmosphere and the uncertainty in the amount of recoverable fossil fuel reserves are driving forces for the development of renewable, carbon-neutral energy technologies. A promising clean solution is photoelectrochemical water splitting to produce hydrogen using abundant solar energy. Here we present a simple and scalable technique for the deposition of amorphous molybdenum sulphide films as hydrogen evolution catalyst onto protected copper(I) oxide films. The efficient extraction of excited electrons by the conformal catalyst film leads to photocurrents of up to similar to 5.7 mA cm(-2) at 0 V versus the reversible hydrogen electrode (pH 1.0) under simulated AM 1.5 solar illumination. Furthermore, the photocathode exhibits enhanced stability under acidic environments, whereas photocathodes with platinum nulloparticles as catalyst deactivate more rapidly under identical conditions. The work demonstrates the potential of earth-abundant light-harvesting material and catalysts for solar hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3059, "DOI": "10.1038/ncomms4059", "DOI Link": "http://dx.doi.org/10.1038/ncomms4059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331084200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Shi, YP; Liu, MF; Zhang, A; Hong, YL; Li, RH; Gao, Q; Chen, MX; Ren, WC; Cheng, HM; Li, YY; Chen, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Shi, Yongpeng; Liu, Mingfeng; Zhang, Ao; Hong, Yi-Lun; Li, Ronghan; Gao, Qiang; Chen, Mingxing; Ren, Wencai; Cheng, Hui-Ming; Li, Yiyi; Chen, Xing-Qiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intercalated architecture of MA2Z4 family layered van der Waals materials with emerging topological, magnetic and superconducting properties", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for new two-dimensional monolayers with diverse electronic properties has attracted growing interest in recent years. Here, we present an approach to construct MA(2)Z(4) monolayers with a septuple-atomic-layer structure, that is, intercalating a MoS2-type monolayer MZ(2) into an InSe-type monolayer A(2)Z(2). We illustrate this unique strategy by means of first-principles calculations, which not only reproduce the structures of MoSi2N4 and MnBi2Te4 that were already experimentally synthesized, but also predict 72 compounds that are thermodynamically and dynamically stable. Such an intercalated architecture significantly reconstructs the band structures of the constituents MZ(2) and A(2)Z(2), leading to diverse electronic properties for MA(2)Z(4), which can be classified according to the total number of valence electrons. The systems with 32 and 34 valence electrons are mostly semiconductors. Whereas, those with 33 valence electrons can be nonmagnetic metals or ferromagnetic semiconductors. In particular, we find that, among the predicted compounds, (Ca,Sr)Ga2Te4 are topologically nontrivial by both the standard density functional theory and hybrid functional calculations. While VSi2P4 is a ferromagnetic semiconductor and TaSi2N4 is a type-I Ising superconductor. Moreover, WSi2P4 is a direct gap semiconductor with peculiar spin-valley properties, which are robust against interlayer interactions. Our study thus provides an effective way of designing septuple-atomic-layer MA(2)Z(4) with unusual electronic properties to draw immediate experimental interest. The discovery of a new two-dimensional van der Waals layered MoSi2N4 material inspires many attentions. Here, the authors report intercalation strategies to explore a much wider range of MA(2)Z(4) family and predict amount of materials accessible to experimental verifications with emergent topological, magnetic or Ising superconductivity properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2361, "DOI": "10.1038/s41467-021-22324-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22324-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000644222700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZY; Xu, Z; Xie, F; Jiang, JL; Zheng, KT; Alabidun, S; Crespo-Ribadeneyra, M; Hu, YS; Au, HT; Titirici, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhenyu; Xu, Zhen; Xie, Fei; Jiang, Jinglin; Zheng, Kaitian; Alabidun, Sarat; Crespo-Ribadeneyra, Maria; Hu, Yong-Sheng; Au, Heather; Titirici, Maria-Magdalena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigating the Superior Performance of Hard Carbon Anodes in Sodium-Ion Compared With Lithium- and Potassium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emerging sodium-ion batteries (NIBs) and potassium-ion batteries (KIBs) show promise in complementing lithium-ion battery (LIB) technology and diversifying the battery market. Hard carbon is a potential anode candidate for LIBs, NIBs, and KIBs due to its high capacity, sustainability, wide availability, and stable physicochemical properties. Herein, a series of hard carbons is synthesized by hydrothermal carbonization and subsequent pyrolysis at different temperatures to finely tune their structural properties. When tested as anodes, the hard carbons exhibit differing ion-storage trends for Li, Na, and K, with NIBs achieving the highest reversible capacity. Extensive materials and electrochemical characterizations are carried out to study the correlation of structural features with electrochemical performance and to explain the specific mechanisms of alkali-ion storage in hard carbons. In addition, the best-performing hard carbon is tested against a sodium cathode Na3V2(PO4)3 in a Na-ion pouch cell, displaying a high power density of 2172 W kg-1 at an energy density of 181.5 Wh kg-1 (based on the total weight of active materials in both anode and cathode). The Na-ion pouch cell also shows stable ultralong-term cycling (9000 h or 5142 cycles) and demonstrates the promising potential of such materials as sustainable, scalable anodes for beyond Li-batteries. Hard carbons are fabricated via hydrothermal carbonization and subsequent pyrolysis at different temperatures. The hard carbons, as anodes, exhibit differing ion-storage trends for Li, Na, and K. The best-performing material G1500 is tested against a Na3V2(PO4)3 cathode in a Na-ion pouch cell, displaying excellent energy/power densities and cycling performance.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2023, "Volume": 35, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202304091", "DOI Link": "http://dx.doi.org/10.1002/adma.202304091", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001064838000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, LY; Deng, JH; Huang, GF; Li, K; Cai, KZ; Liu, Y; Huang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Li-Yang; Deng, Jin-Huan; Huang, Guo-Fu; Li, Kai; Cai, Kun-Zheng; Liu, Yan; Huang, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Relative distribution of Cd2+ adsorption mechanisms on biochars derived from rice straw and sewage sludge", "Source Title": "BIORESOURCE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Qualitative and quantitative characterization of Cd2+ adsorption mechanisms was performed with rice-straw and sewage-sludge biochars produced at different temperature (300-700 degrees C), respectively. The pH effect, adsorption kinetics and isotherms were investigated, and chemical analyses of Cd2+-loaded biochars were conducted by SEM-EDS, XRD, FTIR and Boehm titration. This demonstrated that rice-straw biochars (RSBs) have greater adsorption capacities for Cd2+ than sewage-sludge biochars (SSBs), which was mainly due to precipitation and cation exchange mechanisms, with their contribution proportion to total adsorption from 76.1% to 80.8%. While in SSBs, both mechanisms were overshadowed by coordination with p electrons mechanism accounting for 59.2%-62.9% of total adsorption, even the role of cation exchange was negligible in the adsorption mechanisms accounting for 2.3%-6.7%. The relationship of each mechanism with biochar's properties were discussed, which further deepen our understanding of adsorption on biochars. These results suggest RSBs have great potential for removing Cd2+ from aqueous solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 272, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 114, "End Page": 122, "Article Number": null, "DOI": "10.1016/j.biortech.2018.09.138", "DOI Link": "http://dx.doi.org/10.1016/j.biortech.2018.09.138", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451625700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, JJ; Shen, J; Yu, XH; Tang, H; Zulfiqar; Liu, QQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jinjun; Shen, Jun; Yu, Xiaohui; Tang, Hua; Zulfiqar; Liu, Qinqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of LSPR-enhanced 0D/2D CdS/MoO3-x S-scheme heterojunctions for visible-light-driven photocatalytic H2 evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmonic nonmetal semiconductors with localized surface plasmon resonullce (LSPR) effects possess extended light-response ranges and can act as highly efficient H-2 generation photocatalysts. Herein, an LSPR-enhanced 0D/2D CdS/MoO3-x heterojunction has been synthesized by the growth of 0D CdS nulloparticles on 2D plasmonic MoO3-x elliptical nullosheets via a simple coprecipitation method. Taking advantage of the LSPR effect of the MoO3-x elliptical nullosheets, the light absorption of the CdS/MoO3-x heterojunction was extended from 600 nm to the near-infrared region (1400 nm). Furthermore, the introduction of 2D plasmonic MoO3-x elliptical nullosheets not only provided a platform for the growth of CdS nulloparticles, but also contributed to the construction of an LSPR-enhanced S-scheme structure due to the interface between the MoO3-x and CdS, accelerating the separation of light-induced electrons and holes. Therefore, the CdS/MoO3-x heterojunction exhibited higher photocatalytic H-2 generation activity than pristine CdS under visible light irradiation, including under 420, 450, 550, and 650 nm monochromic light, as well as improved photo-corrosion performance. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 87, "End Page": 96, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63595-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63595-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, JC; Jia, XY; Wang, DP; Deng, YB; Zheng, P; Li, CH; Zuo, JL; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Jian-Cheng; Jia, Xiao-Yong; Wang, Da-Peng; Deng, Yi-Bing; Zheng, Peng; Li, Cheng-Hui; Zuo, Jing-Lin; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing. Here we report the design and synthesis of a polymer containing thermodynamically stable whilst kinetically labile coordination complex to address this conundrum. The Zn-Hbimcp (Hbimcp = 2,6-bis((imino) methyl)-4-chlorophenol) coordination bond used in this work has a relatively large association constant (2.2 x 10(11)) but also undergoes fast and reversible intra- and inter-molecular ligand exchange processes. The as-prepared Zn(Hbimcp)(2)-PDMS polymer is highly stretchable (up to 2400% strain) with a high toughness of 29.3 MJ m(-3), and can autonomously self-heal at room temperature. Control experiments showed that the optimal combination of its bond strength and bond dynamics is responsible for the material's mechanical toughness and self-healing property. This molecular design concept points out a promising direction for the preparation of self-healing polymers with excellent mechanical properties. We further show this type of polymer can be potentially used as energy absorbing material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1164, "DOI": "10.1038/s41467-019-09130-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09130-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460759800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, GJ; Qiao, M; Li, WY; Lu, Y; Zhao, TT; Zou, RJ; Li, B; Darr, JA; Hu, JQ; Titirici, MM; Parkin, IP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Guanjie; Qiao, Mo; Li, Wenyao; Lu, Yao; Zhao, Tingting; Zou, Rujia; Li, Bo; Darr, Jawwad A.; Hu, Junqing; Titirici, Maria-Magdalena; Parkin, Ivan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S, N-Co-Doped Graphene-Nickel Cobalt Sulfide Aerogel: Improved Energy Storage and Electrocatalytic Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal sulfides are commonly used in energy storage and electrocatalysts due to their redox centers and active sites. Most literature reports show that their performance decreases significantly caused by oxidation in alkaline electrolyte during electrochemical testing. Herein, S and N co-doped graphene-based nickel cobalt sulfide aerogels are synthesized for use as rechargeable alkaline battery electrodes and oxygen reduction reaction (ORR) catalysts. Notably, this system shows improved cyclability due to the stabilization effect of the S and N co-doped graphene aerogel (SNGA). This reduces the rate of oxidation and the decay of electronic conductivity of the metal sulfides materials in alkaline electrolyte, i.e., the capacity decrease of CoNi2S4/SNGA is 4.2% for 10 000 cycles in a three-electrode test; the current retention of 88.6% for Co-S/SNGA after 12000 s current-time chronoamperometric response in the ORR test is higher than corresponding Co-S/nulloparticles and Co-S/ non-doped graphene aerogels. Importantly, the results here confirm that the Ni-Co-S ternary materials behave as an electrode for rechargeable alkaline batteries rather than supercapacitors electrodes in three-electrode test as commonly described and accepted in the literature. Furthermore, formulas to evaluate the performance of hybrid battery devices are specified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600214, "DOI": "10.1002/advs.201600214", "DOI Link": "http://dx.doi.org/10.1002/advs.201600214", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392400200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SH; Lee, YJ; Kang, H; Park, SK; Kang, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Su Hyun; Lee, Yun Jae; Kang, Heemin; Park, Seung-Keun; Kang, Yun Chan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-Coated Three-Dimensional MXene/Iron Selenide Ball with Core-Shell Structure for High-Performance Potassium-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) MXenes are promising as electrode materials for energy storage, owing to their high electronic conductivity and low diffusion barrier. Unfortunately, similar to most 2D materials, MXene nullosheets easily restack during the electrode preparation, which degrades the electrochemical performance of MXene-based materials. A novel synthetic strategy is proposed for converting MXene into restacking-inhibited three-dimensional (3D) balls coated with iron selenides and carbon. This strategy involves the preparation of Fe2O3@carbon/MXene microspheres via a facile ultrasonic spray pyrolysis and subsequent selenization process. Such 3D structuring effectively prevents interlayer restacking, increases the surface area, and accelerates ion transport, while maintaining the attractive properties of MXene. Furthermore, combining iron selenides and carbon with 3D MXene balls offers many more sites for ion storage and enhances the structural robustness of the composite balls. The resultant 3D structured microspheres exhibit a high reversible capacity of 410 mAh g(-1) after 200 cycles at 0.1 A g(-1) in potassium-ion batteries, corresponding to the capacity retention of 97% as calculated based on 100 cycles. Even at a high current density of 5.0 A g(-1), the composite exhibits a discharge capacity of 169 mAh g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17, "DOI": "10.1007/s40820-021-00741-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00741-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000727334300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chuang, S; Battaglia, C; Azcatl, A; McDonnell, S; Kang, JS; Yin, XT; Tosun, M; Kapadia, R; Fang, H; Wallace, RM; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chuang, Steven; Battaglia, Corsin; Azcatl, Angelica; McDonnell, Stephen; Kang, Jeong Seuk; Yin, Xingtian; Tosun, Mahmut; Kapadia, Rehan; Fang, Hui; Wallace, Robert M.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2 P-type Transistors and Diodes Enabled by High Work Function MoOx Contacts", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-resistance source/drain contacts to transition-metal dichalcogenides (TMDCs) is crucial for the realization of high-performance logic components. In particular, efficient hole contacts are required for the fabrication of p-type transistors with MoS2, a model TMDC. Previous studies have shown that the Fermi level of elemental metals is pinned close to the conduction band of MoS2, thus resulting in large Schottky barrier heights for holes with limited hole injection from the contacts. Here, we show that substoichiometric molybdenum trioxide (MoOx, x < 3), a high work function material, acts as an efficient hole injection layer to MoS2 and WSe2. In particular, we demonstrate MoS2 p-type field-effect transistors and diodes by using MoOx contacts. We also show drastic on-current improvement for p-type WSe2 FETs with MoOx contacts over devices made with Pd contacts, which is the prototypical metal used for hole injection. The work presents an important advance in contact engineering of TMDCs and will enable future exploration of their performance limits and intrinsic transport properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 564, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1337, "End Page": 1342, "Article Number": null, "DOI": "10.1021/nl4043505", "DOI Link": "http://dx.doi.org/10.1021/nl4043505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335720300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sebastian, M; Peters, JA; Stoumpos, CC; Im, J; Kostina, SS; Liu, Z; Kanatzidis, MG; Freeman, AJ; Wessels, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sebastian, M.; Peters, J. A.; Stoumpos, C. C.; Im, J.; Kostina, S. S.; Liu, Z.; Kanatzidis, M. G.; Freeman, A. J.; Wessels, B. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitonic emissions and above-band-gap luminescence in the single-crystal perovskite semiconductors CsPbBr3 and CsPbCl3", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ternary compounds CsPbX3 (X = Br or Cl) have perovskite structures that are being considered for optical and electronic applications such as lasing and gamma-ray detection. An above-band-gap excitonic photoluminescence (PL) band is seen in both CsPbX3 compounds. An excitonic emission peak centered at 2.98 eV, similar to 0.1 eV above the room-temperature band gap, is observed for CsPbCl3. The thermal quenching of the excitonic luminescence is well described by a two-step quenching model, yielding activation energies of 0.057 and 0.0076 eV for high-and low-temperature regimes, respectively. CsPbBr3 exhibits bound excitonic luminescence peaks located at 2.29 and 2.33 eV that are attributed to recombination involving Br vacancy centers. Activation energies for thermal quenching of the excitonic luminescence of 0.017 and 0.0007 eV were calculated for CsPbBr3. Temperature-dependent PL experiments reveal unexpected blueshifts for all excitonic emission peaks in CsPbX3 compounds. A phonon-assisted step-up process leads to the blueshift in CsPbBr3 emission, while there is a contribution from band-gap widening in CsPbCl3. The absence of significant deep level defect luminescence in these compounds makes them attractive candidates for high-resolution, room-temperature radiation detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 29", "Publication Year": 2015, "Volume": 92, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235210, "DOI": "10.1103/PhysRevB.92.235210", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.235210", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367378200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, LL; Peng, YS; Yang, Y; Liu, JJ; Huang, HL; Yu, BH; Zhao, JM; Lu, YL; Huang, ZR; Li, ZY; Lombardi, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Lili; Peng, Yusi; Yang, Yong; Liu, Jianjun; Huang, Haoliang; Yu, Bohan; Zhao, Jimin; Lu, Yalin; Huang, Zhengren; Li, Zhiyuan; Lombardi, John R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Ultra-Sensitive Semiconductor SERS Substrate Boosted by the Coupled Resonullce Effect", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent achievements in semiconductor surface-enhanced Raman scattering (SERS) substrates have greatly expanded the application of SERS technique in various fields. However, exploring novel ultra-sensitive semiconductor SERS materials is a high-priority task. Here, a new semiconductor SERS-active substrate, Ta2O5, is developed and an important strategy, the coupled resonullce effect, is presented, to optimize the SERS performance of semiconductor materials by energy band engineering. The optimized Mo-doped Ta2O5 substrate exhibits a remarkable SERS sensitivity with an enhancement factor of 2.2 x 10(7) and a very low detection limit of 9 x 10(-9) m for methyl violet (MV) molecules, demonstrating one of the highest sensitivities among those reported for semiconductor SERS substrates. This remarkable enhancement can be attributed to the synergistic resonullce enhancement of three components under 532 nm laser excitation: i) MV molecular resonullce, ii) photoinduced charge transfer resonullce between MV molecules and Ta2O5 nullorods, and iii) electromagnetic enhancement around the gap and tip of anisotropic Ta2O5 nullorods. Furthermore, it is discovered that the concomitant photoinduced degradation of the probed molecules in the time-scale of SERS detection is a non-negligible factor that limits the SERS performance of semiconductors with photocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900310, "DOI": "10.1002/advs.201900310", "DOI Link": "http://dx.doi.org/10.1002/advs.201900310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477708000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, H; Lee, J; Ahn, H; Kim, O; Park, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hoon; Lee, Joungphil; Ahn, Hyungmin; Kim, Onnuri; Park, Moon Jeong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of three-dimensionally interconnected sulfur-rich polymers for cathode materials of high-rate lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elemental sulfur is one of the most attractive cathode active materials in lithium batteries because of its high theoretical specific capacity. Despite the positive aspect, lithium-sulfur batteries have suffered from severe capacity fading and limited rate capability. Here we report facile large-scale synthesis of a class of organosulfur compounds that could open a new chapter in designing cathode materials to advance lithium-sulfur battery technologies. Porous trithiocyanuric acid crystals are synthesized for use as a soft template, where the ring-opening polymerization of elemental sulfur takes place along the thiol surfaces to create three-dimensionally interconnected sulfur-rich phases. Our lithium-sulfur cells display discharge capacity of 945mAhg(-1) after 100 cycles at 0.2 C with high-capacity retention of 92%, as well as lifetimes of 450 cycles. Particularly, the organized amine groups in the crystals increase Li+-ion transfer rate, affording a rate performance of 1210 mAhg (-1) at 0.1 C and 730mAhg(-1) at 5 C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7278, "DOI": "10.1038/ncomms8278", "DOI Link": "http://dx.doi.org/10.1038/ncomms8278", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357170800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, BY; Zhang, YM; Ma, DX; Shi, Z; Ma, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Baiyan; Zhang, Yiming; Ma, Dingxuan; Shi, Zhan; Ma, Shengqian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mercury nullo-trap for effective and efficient removal of mercury(II) from aqueous solution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly effective and highly efficient decontamination of mercury from aqueous media remains a serious task for public health and ecosystem protection. Here we report that this task can be addressed by creating a mercury 'nullo-trap' as illustrated by functionalizing a high surface area and robust porous organic polymer with a high density of strong mercury chelating groups. The resultant porous organic polymer-based mercury 'nullo-trap' exhibits a record-high saturation mercury uptake capacity of over 1,000 mg g(-1), and can effectively reduce the mercury(II) concentration from 10 p.p.m. to the extremely low level of smaller than 0.4 p.p.b. well below the acceptable limits in drinking water standards (2 p.p.b.), and can also efficiently remove 499.9% mercury(II) within a few minutes. Our work therefore presents a new benchmark for mercury adsorbent materials and provides a new perspective for removing mercury(II) and also other heavy metal ions from contaminated water for environmental remediation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5537, "DOI": "10.1038/ncomms6537", "DOI Link": "http://dx.doi.org/10.1038/ncomms6537", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345913600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, J; Gao, YY; Shi, L; Yu, W; Sun, ZJ; Zhou, YF; Liu, S; Mao, H; Zhang, DY; Lu, TQ; Chen, Q; Yu, DM; Ding, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jing; Gao, Yiyang; Shi, Lei; Yu, Wei; Sun, Zongjie; Zhou, Yifan; Liu, Shuang; Mao, Heng; Zhang, Dongyang; Lu, Tongqing; Chen, Quan; Yu, Demei; Ding, Shujiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-locked constructing dynamic supra- molecular ionic conductive elastomers with superior toughness, autonomous self-healing and recyclability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable ionic conductors are considerable to be the most attractive candidate for next-generation flexible ionotronic devices. Nevertheless, high ionic conductivity, excellent mechanical properties, good self-healing capacity and recyclability are necessary but can be rarely satisfied in one material. Herein, we propose an ionic conductor design, dynamic supramolecular ionic conductive elastomers (DSICE), via phase-locked strategy, wherein locking soft phase polyether backbone conducts lithium-ion (Li+) transport and the combination of dynamic disulfide metathesis and stronger supramolecular quadruple hydrogen bonds in the hard domains contributes to the self-healing capacity and mechanical versatility. The dual-phase design performs its own functions and the conflict among ionic conductivity, self-healing capability, and mechanical compatibility can be thus defeated. The well-designed DSICE exhibits high ionic conductivity (3.77 x 10(-3) S m(-1) at 30 degrees C), high transparency (92.3%), superior stretchability (2615.17% elongation), strength (27.83 MPa) and toughness (164.36 MJ m(-3)), excellent self-healing capability (similar to 99% at room temperature) and favorable recyclability. This work provides an interesting strategy for designing the advanced ionic conductors and offers promise for flexible ionotronic devices or solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4868, "DOI": "10.1038/s41467-022-32517-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32517-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842231900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, K; Xie, PT; Wang, ZY; Su, TM; Shao, Q; Ryu, JE; Zhang, XH; Guo, J; Shankar, A; Li, JF; Fan, RH; Cao, DP; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Kai; Xie, Peitao; Wang, Zhongyang; Su, Tongming; Shao, Qian; Ryu, JongEun; Zhang, Xihua; Guo, Jiang; Shankar, Akash; Li, Jianfeng; Fan, Runhua; Cao, Dapeng; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible polydimethylsiloxane/multi-walled carbon nullotubes membranous metacomposites with negative permittivity", "Source Title": "POLYMER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metacomposites with negative electromagnetic parameters can be promising substitute for periodic metamaterials. In this paper, we devoted to fabricating flexible metacomposite films, which have great potential applications in the field of wearable cloaks, sensing, perfect absorption and stretchable electronic devices. The conductivity and the complex permittivity were investigated in flexible polydimethylsiloxane (PDMS)/multi-walled carbon nullotubes (MWCNTs) membranous nullocomposites, which were fabricated via in-situ polymerization process. With the increase of conductive onedimension carbon nullotubes concentration, there was a percolation transition observed in conduction due to the formation of continuous networks. The dielectric dispersion behavior was also analyzed in the spectra of complex permittivity. It is indicated that the conduction and polarization make a combined effect on the dielectric loss in flexible PDMS/MWCNTs composites. The negative permittivity with a dielectric resonullce was obtained, and was attributed to the induced electric dipoles. (C) 2017 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2017, "Volume": 125, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 50, "End Page": 57, "Article Number": null, "DOI": "10.1016/j.polymer.2017.07.083", "DOI Link": "http://dx.doi.org/10.1016/j.polymer.2017.07.083", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409511800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, XF; Bohlén, M; Lindblad, C; Hedenqvist, M; Hakonen, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Xin-Feng; Bohlen, Martin; Lindblad, Catrin; Hedenqvist, Mikael; Hakonen, Aron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microplastics generated from a biodegradable plastic in freshwater and seawater", "Source Title": "WATER RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biodegradable polymers have been regarded as a promising solution to tackle the pollutions caused by the wide use of conventional polymers. However, during the biodegradation process, the material fragmentation leads to microplastics. In this work, the formation of microplastics from biodegradable poly (butylene adipate-co-terephthalate) (PBAT) in different aquatic environments was investigated and compared with the common non-biodegradable low-density polyethylene (LDPE). The results showed that a much larger quantity of plastic fragments/particles were formed in all aquatic environments from PBAT than from LDPE. In addition, UV-A pretreatment, simulating the exposure to sunlight, increased the rate of PBAT microplastic formation significantly. The size distribution and shapes of the formed microplastics were systematically studied, along with changes in the polymer physicochemical properties such as molecular weight, thermal stability, crystallinity, and mechanical properties, to reveal the formation process of microplastics. This study shows that the microplastic risk from biodegradable polymers is high and needs to be further evaluated with regards to longer timeframes, the biological fate of intermediate products, and final products in freshwater, estuarine and seawater natural habitats. Especially, considering that these microplastics may have good biodegradability in warmer 20 - 25 degrees water but will most likely be highly persistent in the world's cold deep seas. (c) 2021 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ )", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 198, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 117123, "DOI": "10.1016/j.watres.2021.117123", "DOI Link": "http://dx.doi.org/10.1016/j.watres.2021.117123", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000651349000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "DuChene, JS; Tagliabue, G; Welch, AJ; Cheng, WH; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "DuChene, Joseph S.; Tagliabue, Giulia; Welch, Alex J.; Cheng, Wen-Hui; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hot Hole Collection and Photoelectrochemical CO2 Reduction with Plasmonic Au/p-GaN Photocathodes", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting nonequilibrium hot carriers from plasmonic-metal nullostructures offers unique opportunities for driving photochemical reactions at the nulloscale. Despite numerous examples of hot electron-driven processes, the realization of plasmonic systems capable of harvesting hot holes from metal nullostructures has eluded the nascent field of plasmonic photocatalysis. Here, we fabricate gold/p-type gallium nitride (Au/p-GaN) Schottky junctions tailored for photoelectrochemical studies of plasmon-induced hot-hole capture and conversion. Despite the presence of an interfacial Schottky barrier to hot-hole injection of more than 1 eV across the Au/p-GaN heterojunction, plasmonic Au/p-GaN photocathodes exhibit photoelectrochemical properties consistent with the injection of hot holes from Au nulloparticles into p-GaN upon plasmon excitation. The photocurrent action spectrum of the plasmonic photocathodes faithfully follows the surface plasmon resonullce absorption spectrum of the Au nulloparticles and open-circuit voltage studies demonstrate a sustained photovoltage during plasmon excitation. Comparison with Ohmic Au/p-NiO heterojunctions confirms that the vast majority of hot holes generated via interband transitions in Au are sufficiently hot to inject above the 1.1 eV interfacial Schottky barrier at the Au/p-GaN heterojunction. We further investigated plasmon-driven photoelectrochemical CO2 reduction with the Au/p-GaN photocathodes and observed improved selectivity for CO production over H-2 evolution in aqueous electrolytes. Taken together, our results offer experimental validation of photoexcited hot holes more than 1 eV below the Au Fermi level and demonstrate a photoelectrochemical platform for harvesting hot carriers to drive solar-to-fuel energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 18, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2545, "End Page": 2550, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b00241", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b00241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430155900049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YJ; Xiong, X; Huang, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yijie; Xiong, Xiong; Huang, Gangliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-assisted extraction and analysis of maidenhairtree polysaccharides", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The maidenhairtree polysaccharides (MTPs) have important application prospects. So, the extraction, purification, structure, derivatization and biological activities of polysaccharides from leaves, fruits, and testae of maidenhairtree were disscussed. Polysaccharides were extracted by collaborative extraction methods such as ultrasound-assisted extraction and microwave-assisted extraction. The ultrasound-assisted extraction had higher content and higher efficiency. The structural characteristics and structure-activity relationship of maidenhairtree polysaccharides were studied in order to provide theoretical basis and technical support for the further development and utilization of maidenhairtree polysaccharides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 95, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106395, "DOI": "10.1016/j.ultsonch.2023.106395", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2023.106395", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001013612800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdollahramezani, S; Hemmatyar, O; Taghinejad, M; Taghinejad, H; Krasnok, A; Eftekhar, AA; Teichrib, C; Deshmukh, S; El-Sayed, MA; Pop, E; Wuttig, M; Alù, A; Cai, WS; Adibi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdollahramezani, Sajjad; Hemmatyar, Omid; Taghinejad, Mohammad; Taghinejad, Hossein; Krasnok, Alex; Eftekhar, Ali A.; Teichrib, Christian; Deshmukh, Sanchit; El-Sayed, Mostafa A.; Pop, Eric; Wuttig, Matthias; Alu, Andrea; Cai, Wenshan; Adibi, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically driven reprogrammable phase-change metasurface reaching 80% efficiency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The authors demonstrate an efficient platform for electrically driven reconfigurable metasurfaces by using Ge2Sb2Te5 to realize non-volatile, reversible, multilevel, and fast optical modulation and wavefront engineering in the near-infrared spectral range. Phase-change materials (PCMs) offer a compelling platform for active metaoptics, owing to their large index contrast and fast yet stable phase transition attributes. Despite recent advances in phase-change metasurfaces, a fully integrable solution that combines pronounced tuning measures, i.e., efficiency, dynamic range, speed, and power consumption, is still elusive. Here, we demonstrate an in situ electrically driven tunable metasurface by harnessing the full potential of a PCM alloy, Ge2Sb2Te5 (GST), to realize non-volatile, reversible, multilevel, fast, and remarkable optical modulation in the near-infrared spectral range. Such a reprogrammable platform presents a record eleven-fold change in the reflectance (absolute reflectance contrast reaching 80%), unprecedented quasi-continuous spectral tuning over 250 nm, and switching speed that can potentially reach a few kHz. Our scalable heterostructure architecture capitalizes on the integration of a robust resistive microheater decoupled from an optically smart metasurface enabling good modal overlap with an ultrathin layer of the largest index contrast PCM to sustain high scattering efficiency even after several reversible phase transitions. We further experimentally demonstrate an electrically reconfigurable phase-change gradient metasurface capable of steering an incident light beam into different diffraction orders. This work represents a critical advance towards the development of fully integrable dynamic metasurfaces and their potential for beamforming applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1696, "DOI": "10.1038/s41467-022-29374-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29374-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776282500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "van der Stam, W; Geuchies, JJ; Altantzis, T; van den Bos, KHW; Meeldijk, JD; Van Aert, S; Bals, S; Vanmaekelbergh, D; Donega, CD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "van der Stam, Ward; Geuchies, Jaco J.; Altantzis, Thomas; van den Bos, Karel H. W.; Meeldijk, Johannes D.; Van Aert, Sandra; Bals, Sara; Vanmaekelbergh, Daniel; Donega, Celso de Mello", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Emissive Divalent-Ion-Doped Colloidal CsPb1-xMxBr3 Perovskite nullocrystals through Cation Exchange", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal CsPbX3 (X = Br, Cl, and I) perovskite nullocrystals (NCs) have emerged as promising phosphors and solar cell materials due to their remarkable optoelectronic properties. These properties can be tailored by not only controlling the size and shape of the NCs but also postsynthetic composition tuning through topotactic anion exchange. In contrast, property control by cation exchange is still underdeveloped for colloidal CsPbX3 NCs. Here, we present a method that allows partial cation exchange in colloidal CsPbBr3 NCs, whereby Pb' is exchanged for several isovalent cations, resulting in doped CsPb1-xMxBr3 NCs (M= Sn2+, Cd2+, and Zn2+; 0 < x <= 0.1), with preservation of the original NC shape. The size of the parent NCs is also preserved in the product NCs, apart from a small (few %) contraction of the unit cells upon incorporation of the guest cations. The partial Pb' for M' exchange leads to a blue-shift of the optical spectra, while maintaining the high photoluminescence quantum yields (>50%), sharp absorption features, and narrow emission of the parent CsPbBr3 NCs. The blue-shift in the optical spectra is attributed to the lattice contraction that accompanies the Pb2+ for M2+ cation exchange and is observed to scale linearly with the lattice contraction. This work opens up new possibilities to engineer the properties of halide perovskite NCs, which to date are demonstrated to be the only known system where cation and anion exchange reactions can be sequentially combined while preserving the original NC shape, resulting in compositionally diverse perovskite NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 602, "Times Cited, All Databases": 640, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2017, "Volume": 139, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4087, "End Page": 4097, "Article Number": null, "DOI": "10.1021/jacs.6b13079", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b13079", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397477700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GQ; Zhang, D; Qiao, Q; Yu, YF; Peterson, D; Zafar, A; Kumar, R; Curtarolo, S; Hunte, F; Shannon, S; Zhu, YM; Yang, WT; Cao, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guoqing; Zhang, Du; Qiao, Qiao; Yu, Yifei; Peterson, David; Zafar, Abdullah; Kumar, Raj; Curtarolo, Stefano; Hunte, Frank; Shannon, Steve; Zhu, Yimei; Yang, Weitao; Cao, Linyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All The Catalytic Active Sites of MoS2 for Hydrogen Evolution", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MoS2 presents a promising low-cost catalyst for the hydrogen evolution reaction (HER), but the understanding about its active sites has remained limited. Here we present an unambiguous study of the catalytic activities of all possible reaction sites of MoS2, including edge sites, sulfur vacancies, and grain boundaries. We demonstrate that, in addition to the well-known catalytically active edge sites, sulfur vacancies provide another major active site for the HER, while the catalytic activity of grain boundaries is much weaker. The intrinsic turnover frequencies (Tafel slopes) of the edge sites, sulfur vacancies, and grain boundaries are estimated to be 7.5 s(-1) (65-75 mV/dec), 3.2 s(-1) (65-85 mV/dec), and 0.1 s(-1) (120-160 mV/dec), respectively. We also demonstrate that the catalytic activity of sulfur vacancies strongly depends on the density of the vacancies and the local crystalline structure in proximity to the vacancies. Unlike edge sites, whose catalytic activity linearly depends on the length, sulfur vacancies show optimal catalytic activities when the vacancy density is in the range of 7-10%, and the number of sulfur vacancies in high crystalline quality MoS2 is higher than that in low crystalline quality MoS2, which may be related with the proximity of different local crystalline structures to the vacancies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 707, "Times Cited, All Databases": 745, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2016, "Volume": 138, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16632, "End Page": 16638, "Article Number": null, "DOI": "10.1021/jacs.6b05940", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b05940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391081800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, Y; Seong, WM; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Youngjin; Seong, Won Mo; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt-free, high-nickel layered oxide cathodes for lithium-ion batteries: Progress, challenges, and perspectives", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-nickel layered oxides are enabling extraordinary growth of electric vehicles market due to its high energy density. Nonetheless, leading battery manufacturers are trying to cut down the manufacturing costs further by eliminating the dependency on cobalt in cathode materials. In this perspective, we explore several aspects that need to be considered to develop cobalt-free high-Ni layered oxides by reviewing the fundamental properties of LiNiO2. Furthermore, critical key factors for exploring alternative dopants and substituents are discussed for designing stable and inexpensive Co-free high-Ni layered oxides from a viewpoint of materials science and electrochemistry. Finally, a perspective on the future research direction on Co-free high-Ni layered oxides are highlighted with respect to practical considerations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 34, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 259, "Article Number": null, "DOI": "10.1016/j.ensm.2020.09.020", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2020.09.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599498700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muroyama, H; Tsuda, Y; Asakoshi, T; Masitah, H; Okanishi, T; Matsui, T; Eguchi, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muroyama, Hiroki; Tsuda, Yuji; Asakoshi, Toshiki; Masitah, Hasan; Okanishi, Takeou; Matsui, Toshiaki; Eguchi, Koichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon dioxide methanation over Ni catalysts supported on various metal oxides", "Source Title": "JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide methanation is well known to offer some advantages and be catalyzed by Ru, Rh, Pd, and Ni. In this study, Ni catalysts supported on various metal oxides were fabricated and their catalytic activity for CO2 methanation was evaluated. The CO2 conversion for most of catalysts drastically increased at 225-250 degrees C and reached a maximal value at 300-350 degrees C. The order of CH4 yield at 250 degrees C was as follows: Ni/Y2O3 > Ni/Sm2O3 > Ni/ZrO2 > Ni/CeO2 > Ni/Al2O3 > Ni/La2O3. The catalytic activity could be partly explained by the basic property of the catalysts. Moreover, the chemical species formed on the catalyst surface during CO2 methanation were examined by in situ infrared spectroscopy. From the obtained results, the difference in the activity depending on the support material of Ni catalysts was discussed. (C) 2016 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 343, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 178, "End Page": 184, "Article Number": null, "DOI": "10.1016/j.jcat.2016.07.018", "DOI Link": "http://dx.doi.org/10.1016/j.jcat.2016.07.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387197600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, C; Gu, SC; Zhang, QH; Bai, Y; Li, M; Yuan, YF; Wang, HL; Liu, XY; Yuan, YX; Zhu, N; Wu, F; Li, H; Gu, L; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Chuan; Gu, Sichen; Zhang, Qinghua; Bai, Ying; Li, Matthew; Yuan, Yifei; Wang, Huali; Liu, Xinyu; Yuan, Yanxia; Zhu, Na; Wu, Feng; Li, Hong; Gu, Lin; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically activated spinel manganese oxide for rechargeable aqueous aluminum battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aluminum is a naturally abundant, trivalent charge carrier with high theoretical specific capacity and volumetric energy density, rendering aluminum-ion batteries a technology of choice for future large-scale energy storage. However, the frequent collapse of the host structure of the cathode materials and sluggish kinetics of aluminum ion diffusion have thus far hampered the realization of practical battery devices. Here, we synthesize AlxMnO2 center dot nH(2)O by an in-situ electrochemical transformation reaction to be used as a cathode material for an aluminum-ion battery with a configuration of Al/Al(OTF)(3)-H2O/AlxMnO2 center dot nH(2)O. This cell is not only based on aqueous electrolyte chemistry but also delivers a high specific capacity of 467 mAh g(-1) and a record high energy density of 481 Wh kg(-1). The high safety of aqueous electrolyte, facile cell assembly and the low cost of materials suggest that this aqueous aluminum-ion battery holds promise for large-scale energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 73, "DOI": "10.1038/s41467-018-07980-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07980-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455102900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hasa, I; Mariyappan, S; Saurel, D; Adelhelm, P; Koposov, AY; Masquelier, C; Croguennec, L; Casas-Cabanas, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hasa, Ivana; Mariyappan, Sathiya; Saurel, Damien; Adelhelm, Philipp; Koposov, Alexey Y.; Masquelier, Christian; Croguennec, Laurence; Casas-Cabanas, Montse", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges of today for Na-based batteries of the future: From materials to cell metrics", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Several emerging battery technologies are currently on endeavour to take a share of the dominullt position taken by Li-ion batteries in the field of energy storage. Among them, sodium-based batteries offer a combination of attractive properties i.e., low cost, sustainable precursors and secure raw material supplies. Na-based batteries include related battery concepts, such as Na-ion, all solid-state Na batteries, Na/O-2 and Na/S, that differ in key components and in redox chemistry, and therefore result in separate challenges and metrics. Na-ion batteries represent an attractive solution which is almost ready to challenge Li-ion technology in certain applications; the other cell concepts represent a more disruptive innovation, with a higher performance gain, provided that major hurdles are overcome. The present review aims at highlighting the most promising materials in the field of Na-based batteries and challenges needed to be addressed to make this technology industrially appealing, by providing an in-depth analysis of performance metrics from recent literature. To this end, half-cell reported metrics have been extrapolated to full cell level for the more mature Na-ion technology to provide a fair comparison with existing technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 482, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 228872, "DOI": "10.1016/j.jpowsour.2020.228872", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2020.228872", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597242000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, Y; Zeng, JW; Liu, XC; Li, JL; Wang, Q; Li, H; de Rooij, NF; Wang, Y; Zhou, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Yue; Zeng, Junwei; Liu, Xiangcheng; Li, Jialong; Wang, Quan; Li, Hao; de Rooij, Nicolaas Frans; Wang, Yao; Zhou, Guofu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Photovoltaic Self-Powered Gas Sensor Based on All-Dry Transferred MoS2/GaSe Heterojunction for ppb-Level NO2 Sensing at Room Temperature", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional gas sensors are facing the challenge of low power consumption for future application in smart phones and wireless sensor platforms. To solve this problem, self-powered gas sensors are rapidly developed in recent years. However, all reported self-powered gas sensors are suffering from high limit of detection (LOD) toward NO2 gas. In this work, a photovoltaic self-powered NO2 gas sensor based on n-MoS2/p-GaSe heterojunction is successfully prepared by mechanical exfoliation and all-dry transfer method. Under 405 nm visible light illumination, the fabricated photovoltaic self-powered gas sensors show a significant response toward ppb-level NO2 with short response and recovery time and high selectivity at room temperature (25 degrees C). It is worth mentioning that the LOD toward NO2 of this device is 20 ppb, which is the lowest of the reported self-powered room-temperature gas sensors so far. The discussed devices can be used as building blocks to fabricate more functional Internet of things devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100472, "DOI": "10.1002/advs.202100472", "DOI Link": "http://dx.doi.org/10.1002/advs.202100472", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653223500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, EZ; Wang, WY; Zhang, C; Jin, YB; Zhu, GD; Sun, QQ; Zhang, DW; Zhou, P; Xiu, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Enze; Wang, Weiyi; Zhang, Cheng; Jin, Yibo; Zhu, Guodong; Sun, Qingqing; Zhang, David Wei; Zhou, Peng; Xiu, Faxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Charge-Trap Memory Based on Few-Layer MoS2", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charge-trap memory with high-kappa dielectric materials is considered to be a promising candidate for next-generation memory devices. Ultrathin layered two-dimensional (2D) materials like graphene and MoS2 have been receiving much attention because of their fantastic physical properties and potential applications in electronic devices. Here, we report on a dual-gate charge-trap memory device composed of a few-layer MoS2 channel and a three-dimensional (3D) Al2O3/HfO2/Al2O3 charge-trap gate stack. Because of the extraordinary trapping ability of both electrons and holes in HfO2, the MoS2 memory device exhibits an unprecedented memory window exceeding 20 V. Importantly, with a back gate the window size can be effectively tuned from 15.6 to 21 V; the program/erase current ratio can reach up to 10(4), allowing for multibit information storage. Moreover, the device shows a high endurance of hundreds of cycles and a stable retention of similar to 28% charge loss after 10 years, which is drastically lower than ever reported MoS2 flash memory. The combination of 2D materials with traditional high-kappa charge-trap gate stacks opens up an exciting field of nonvolatile memory devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 455, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 612, "End Page": 619, "Article Number": null, "DOI": "10.1021/nn5059419", "DOI Link": "http://dx.doi.org/10.1021/nn5059419", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348619000065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nikolka, M; Nasrallah, I; Rose, B; Ravva, MK; Broch, K; Sadhanala, A; Harkin, D; Charmet, J; Hurhangee, M; Brown, A; Illig, S; Too, P; Jongman, J; McCulloch, I; Bredas, JL; Sirringhaus, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nikolka, Mark; Nasrallah, Iyad; Rose, Bradley; Ravva, Mahesh Kumar; Broch, Katharina; Sadhanala, Aditya; Harkin, David; Charmet, Jerome; Hurhangee, Michael; Brown, Adam; Illig, Steffen; Too, Patrick; Jongman, Jan; McCulloch, Iain; Bredas, Jean-Luc; Sirringhaus, Henning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High operational and environmental stability of high-mobility conjugated polymer field-effect transistors through the use of molecular additives", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to their low-temperature processing properties and inherent mechanical flexibility, conjugated polymer field- effect transistors (FETs) are promising candidates for enabling flexible electronic circuits and displays. Much progress has been made on materials performance; however, there remain significant concerns about operational and environmental stability, particularly in the context of applications that require a very high level of threshold voltage stability, such as active-matrix addressing of organic light-emitting diode displays. Here, we investigate the physical mechanisms behind operational and environmental degradation of high-mobility, p-type polymer FETs and demonstrate an effective route to improve device stability. We show that water incorporated in nullometre- sized voids within the polymer microstructure is the key factor in charge trapping and device degradation. By inserting molecular additives that displace water from these voids, it is possible to increase the stability as well as uniformity to a high level suffcient for demanding industrial applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 356, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4785", "DOI Link": "http://dx.doi.org/10.1038/NMAT4785", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394601600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arbabi, A; Horie, Y; Ball, AJ; Bagheri, M; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arbabi, Amir; Horie, Yu; Ball, Alexander J.; Bagheri, Mahmood; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subwavelength-thick lenses with high numerical apertures and large efficiency based on high-contrast transmitarrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flat optical devices thinner than a wavelength promise to replace conventional free-space components for wavefront and polarization control. Transmissive flat lenses are particularly interesting for applications in imaging and on-chip optoelectronic integration. Several designs based on plasmonic metasurfaces, high-contrast transmitarrays and gratings have been recently implemented but have not provided a performance comparable to conventional curved lenses. Here we report polarization-insensitive, micron-thick, high-contrast transmitarray micro-lenses with focal spots as small as 0.57 lambda. The measured focusing efficiency is up to 82%. A rigorous method for ultrathin lens design, and the trade-off between high efficiency and small spot size (or large numerical aperture) are discussed. The micro-lenses, composed of silicon nullo-posts on glass, are fabricated in one lithographic step that could be performed with high-throughput photo or nulloimprint lithography, thus enabling widespread adoption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 927, "Times Cited, All Databases": 1091, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7069, "DOI": "10.1038/ncomms8069", "DOI Link": "http://dx.doi.org/10.1038/ncomms8069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355531100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WC; Wang, SH; Rastak, R; Ochiai, Y; Niu, SM; Jiang, YW; Arunachala, PK; Zheng, Y; Xu, J; Matsuhisa, N; Yan, XZ; Kwon, SK; Miyakawa, M; Zhang, ZT; Ning, R; Foudeh, AM; Yun, Y; Linder, C; Tok, JBH; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Weichen; Wang, Sihong; Rastak, Reza; Ochiai, Yuto; Niu, Simiao; Jiang, Yuanwen; Arunachala, Prajwal Kammardi; Zheng, Yu; Xu, Jie; Matsuhisa, Naoji; Yan, Xuzhou; Kwon, Soon-Ki; Miyakawa, Masashi; Zhang, Zhitao; Ning, Rui; Foudeh, Amir M.; Yun, Youngjun; Linder, Christian; Tok, Jeffrey B. -H.; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain-insensitive intrinsically stretchable transistors and circuits", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An all-elastomer strain engineering approach, which uses patterned elastomer layers with tunable stiffnesses, can be used to create intrinsically stretchable transistor arrays with a device density of 340 transistors cm(-2) and strain insensitivity of less than 5% performance variation when stretched to 100% strain. Intrinsically stretchable electronics can form intimate interfaces with the human body, creating devices that could be used to monitor physiological signals without constraining movement. However, mechanical strain invariably leads to the degradation of the electronic properties of the devices. Here we show that strain-insensitive intrinsically stretchable transistor arrays can be created using an all-elastomer strain engineering approach, in which the patterned elastomer layers with tunable stiffnesses are incorporated into the transistor structure. By varying the cross-linking density of the elastomers, areas of increased local stiffness are introduced, reducing strain on the active regions of the devices. This approach can be readily incorporated into existing fabrication processes, and we use it to create arrays with a device density of 340 transistors cm(-2) and a strain insensitivity of less than 5% performance variation when stretched to 100% strain. We also show that it can be used to fabricate strain-insensitive circuit elements, including NOR gates, ring oscillators and high-gain amplifiers for the stable monitoring of electrophysiological signals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 143, "End Page": 150, "Article Number": null, "DOI": "10.1038/s41928-020-00525-1", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-00525-1", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000611472500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suarez, F; Parekh, DP; Ladd, C; Vashaee, D; Dickey, MD; Öztürk, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suarez, Francisco; Parekh, Dishit P.; Ladd, Collin; Vashaee, Daryoosh; Dickey, Michael D.; Oeztuerk, Mehmet C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible thermoelectric generator using bulk legs and liquid metal interconnects for wearable electronics", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interest in wearable electronics for continuous, long-term health and performance monitoring is rapidly increasing. The reduction in power levels consumed by sensors and electronic circuits accompanied by the advances in energy harvesting methods allows for the realization of self-powered monitoring systems that do not have to rely on batteries. For wearable electronics, thermoelectric generators (TEGs) offer the unique ability to continuously convert body heat into usable energy. For body harvesting, it is preferable to have TEGs that are thin, soft and flexible. Unfortunately, the performances of flexible modules reported to date have been far behind those of their rigid counterparts. This is largely due to lower efficiencies of the thermoelectric materials, electrical or thermal parasitic losses and limitations on leg dimensions posed by the synthesis techniques. In this work, we present an entirely new approach and explore the possibility of using standard bulk legs in a flexible package. Bulk thermoelectric legs cut from solid ingots are far superior to thermoelectric materials synthesized using other techniques. A key enabler of the proposed technology is the use of EGaln liquid metal interconnects, which not only provide extremely low interconnect resistance but also stretchability with self-healing, both of which are essential for flexible TE modules. The results suggest that this novel approach can finally produce flexible TEGs that have the potential to challenge the rigid TEGs and provide a pathway for the realization of self-powered wearable electronics. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2017, "Volume": 202, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 736, "End Page": 745, "Article Number": null, "DOI": "10.1016/j.apenergy.2017.05.181", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2017.05.181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407188500059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XY; Chen, NJ; Hu, C; Klok, HA; Lee, YM; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xingyu; Chen, nulljun; Hu, Chuan; Klok, Harm-Anton; Lee, Young Moo; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorinated Poly(aryl piperidinium) Membranes for Anion Exchange Membrane Fuel Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anion-exchange-membrane fuel cells (AEMFCs) are a cost-effective alternative to proton-exchange-membrane fuel cells (PEMFCs). The development of high-performance and durable AEMFCs requires highly conductive and robust anion-exchange membranes (AEMs). However, AEMs generally exhibit a trade-off between conductivity and dimensional stability. Here, a fluorination strategy to create a phase-separated morphological structure in poly(aryl piperidinium) AEMs is reported. The highly hydrophobic perfluoroalkyl side chains augment phase separation to construct interconnected hydrophilic channels for anion transport. As a result, these fluorinated PAP (FPAP) AEMs simultaneously possess high conductivity (>150 mS cm(-1) at 80 degrees C) and high dimensional stability (swelling ratio <20% at 80 degrees C), excellent mechanical properties (tensile strength >80 MPa and elongation at break >40%) and chemical stability (>2000 h in 3 m KOH at 80 degrees C). AEMFCs with a non-precious Co-Mn spinel cathode using the present FPAP AEMs achieve an outstanding peak power density of 1.31 W cm(-2). The AEMs remain stable over 500 h of fuel cell operation at a constant current density of 0.2 A cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202210432", "DOI Link": "http://dx.doi.org/10.1002/adma.202210432", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000985983800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, YJ; Wang, LJ; Wen, YR; Cheng, BY; Wu, QL; Cao, TQ; Xiao, Q; Xue, YF; Sha, G; Wang, YD; Ren, Y; Li, XY; Wang, L; Wang, FC; Cai, HNA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Yao-Jian; Wang, Linjing; Wen, Yuren; Cheng, Baoyuan; Wu, Qinli; Cao, Tangqing; Xiao, Qian; Xue, Yunfei; Sha, Gang; Wang, Yandong; Ren, Yang; Li, Xiaoyan; Wang, Lu; Wang, Fuchi; Cai, Hongnian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-content ductile coherent nulloprecipitates achieve ultrastrong high-entropy alloys", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precipitation-hardening high-entropy alloys (PH-HEAs) with good strength-ductility balances are a promising candidate for advanced structural applications. However, current HEAs emphasize near-equiatomic initial compositions, which limit the increase of intermetallic precipitates that are closely related to the alloy strength. Here we present a strategy to design ultrastrong HEAs with high-content nulloprecipitates by phase separation, which can generate a near-equiatomic matrix in situ while forming strengthening phases, producing a PH-HEA regardless of the initial atomic ratio. Accordingly, we develop a non-equiatomic alloy that utilizes spinodal decomposition to create a low-misfit coherent nullostructure combining a near-equiatomic disordered face-centered-cubic (FCC) matrix with high-content ductile Ni3Al-type ordered nulloprecipitates. We find that this spinodal order-disorder nullostructure contributes to a strength increase of similar to 1.5 GPa (>560%) relative to the HEA without precipitation, achieving one of the highest tensile strength (1.9 GPa) among all bulk HEAs reported previously while retaining good ductility (>9%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 497, "Times Cited, All Databases": 525, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4063, "DOI": "10.1038/s41467-018-06600-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06600-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446333400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, L; Wu, HW; Ma, HL; Ye, WP; Jia, WY; Wang, H; Chen, HZ; Zhang, N; Wang, DD; Qian, C; An, ZF; Huang, W; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Long; Wu, Hongwei; Ma, Huili; Ye, Wenpeng; Jia, Wenyong; Wang, He; Chen, Hongzhong; Zhang, null; Wang, Dongdong; Qian, Cheng; An, Zhongfu; Huang, Wei; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functional materials displaying tunable emission and long-lived luminescence have recently emerged as a powerful tool for applications in information encryption, organic electronics and bioelectronics. Herein, we present a design strategy to achieve color-tunable ultralong organic room temperature phosphorescence (UOP) in polymers through radical multicomponent cross-linked copolymerization. Our experiments reveal that by changing the excitation wavelength from 254 to 370 nm, these polymers display multicolor luminescence spanning from blue to yellow with a long-lived lifetime of 1.2 s and a maximum phosphorescence quantum yield of 37.5% under ambient conditions. Moreover, we explore the application of these polymers in multilevel information encryption based on the color-tunable UOP property. This strategy paves the way for the development of multicolor bio-labels and smart luminescent materials with long-lived emission at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 944, "DOI": "10.1038/s41467-020-14792-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14792-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564270500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, XM; Han, P; Wei, ZX; Huang, LS; Gu, ZX; Peng, SJ; Ma, JM; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Xiaomin; Han, Peng; Wei, Zengxi; Huang, Linsong; Gu, Zhengxiang; Peng, Sijia; Ma, Jianmin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron-Doped Graphene for Electrocatalytic N2 Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical N-2 reduction in aqueous solutions at ambient conditions is extremely challenging and requires rational design of electrocatalytic centers. We demonstrate a boron-doped graphene as an efficient metal-free N-2 reduction electrocatalyst. Boron doping in the graphene framework leads to redistribution of electron density, where the electron-deficient boron sites provide enhanced binding capability to N-2 molecules. Density functional theory calculations reveal the catalytic activities of different boron-doped carbon structures, in which the BC3 structure enables the lowest energy barrier for N-2 electroreduction to NH3. At a doping level of 6.2%, the boron-doped graphene achieves a NH3 production rate of 9.8 mu g.hr(-1).cm(-2) and one of the highest reported faradic efficiencies of 10.8% at -0.5 V versus reversible hydrogen electrode in aqueous solutions at ambient conditions. This work suggests the strong potential of atomic-scale design for efficient electrocatalysts for N-2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 830, "Times Cited, All Databases": 866, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1610, "End Page": 1622, "Article Number": null, "DOI": "10.1016/j.joule.2018.06.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.06.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441627400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JN; Yi, SS; Liu, JW; Sun, SY; Liu, YP; Yang, DW; Xi, K; Gao, GX; Abdelkader, A; Yan, W; Ding, SJ; Kumar, RV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianull; Yi, Shanshan; Liu, Jianwei; Sun, Shiyi; Liu, Yunpeng; Yang, Duowen; Xi, Kai; Gao, Guoxin; Abdelkader, Amr; Yan, Wei; Ding, Shujiang; Kumar, Ramachandran Vasant", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressing the Shuttle Effect and Dendrite Growth in Lithium-Sulfur Batteries", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Practical applications of lithium-sulfur batteries are simultaneously hindered by two serious problems occurring separately in both electrodes, namely, the shuttle effects of lithium polysulfides and the uncontrollable growth of lithium dendrites. Herein, to explore a facile integrated approach to tackle both problems as well as guarantee the efficient charge transfer, we used two-dimension hexagonal VS2 flakes as the building blocks to assemble nullotowers on the separators, forming a symmetrical double-side-modified polypropylene separator without blocking the membrane pores. Benefiting from the sulfiphilic and lithiophilic properties, high interfacial electronic conductivity, and the unique hexagonal tower-form nullostructure, the D-HVS@PP separator not only guarantees the effective suppression of the lithium polysulfide shuttle and the rapid ion/electron transfer but also realizes uniform and stable lithium nucleation and growth during cycling. Hence, just at the expense of an 11% increase in the separator weight (0.14 mg cm(-2)), the D-HVS@PP separator delivers an over 16 times higher initial areal capacity (8.3 mAh cm(-2)) than a conventional PP separator (0.5 mAh cm(-2)) under high sulfur-loading conditions (9.24 mg cm(-2)). Even when used under a low electrolyte/sulfur ratio of 4 mL g(-1) and a practically relevant N/P ratio of 1.7, the D-HVS@PP separator still enabled stable cycling with a high cell-level gravimetric energy density. The potentials in broader applications (Li-S pouch battery and Li- Li-FePO4 battery) and the promising commercial prospect (large-scale production and recyclability) of the developed separator are also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2020, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9819, "End Page": 9831, "Article Number": null, "DOI": "10.1021/acsnullo.0c02241", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c02241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566341000047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XW; Huang, JH; Yang, D; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xianwu; Huang, Jiahui; Yang, Dong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Multi-Scale Structural Engineering Strategy for High-Performance MXene Hydrogel Supercapacitor Electrode", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes as an emerging two-dimensional (2D) material have attracted tremendous interest in electrochemical energy-storage systems such as supercapacitors. Nevertheless, 2D MXene flakes intrinsically tend to lie flat on the substrate when self-assembling as electrodes, leading to the highly tortuous ion pathways orthogonal to the current collector and hindering ion accessibility. Herein, a facile strategy toward multi-scale structural engineering is proposed to fabricate high-performance MXene hydrogel supercapacitor electrodes. By unidirectional freezing of the MXene slurry followed by a designed thawing process in the sulfuric acid electrolyte, the hydrogel electrode is endowed with a three-dimensional (3D) open macrostructure impregnated with sufficient electrolyte and H+-intercalated microstructure, which provide abundant active sites for ion storage. Meanwhile, the ordered channels bring through-electrode ion and electron transportation pathways that facilitate electrolyte infiltration and mass exchange between electrolyte and electrode. Furthermore, this strategy can also be extended to the fabrication of a 3D-printed all-MXene micro-supercapacitor (MSC), delivering an ultrahigh areal capacitance of 2.0 F cm(-2) at 1.2 mA cm(-2) and retaining 1.2 F cm(-2) at 60 mA cm(-2) together with record-high energy density (0.1 mWh cm(-2) at 0.38 mW cm(-2)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 8, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101664, "DOI": "10.1002/advs.202101664", "DOI Link": "http://dx.doi.org/10.1002/advs.202101664", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000679991500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZL; Dong, QF; Liu, Y; Bao, CX; Fang, YJ; Lin, Y; Tang, S; Wang, Q; Xiao, X; Bai, Y; Deng, YH; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhaolai; Dong, Qingfeng; Liu, Ye; Bao, Chunxiong; Fang, Yanjun; Lin, Yun; Tang, Shi; Wang, Qi; Xiao, Xun; Bai, Yang; Deng, Yehao; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thin single crystal perovskite solar cells to harvest below-bandgap light absorption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiency of perovskite solar cells has surged in the past few years, while the bandgaps of current perovskite materials for record efficiencies are much larger than the optimal value, which makes the efficiency far lower than the Shockley-Queisser efficiency limit. Here we show that utilizing the below-bandgap absorption of perovskite single crystals can narrow down their effective optical bandgap without changing the composition. Thin methylammonium lead triiodide single crystals with tuned thickness of tens of micrometers are directly grown on hole-transport-layer covered substrates by a hydrophobic interface confined lateral crystal growth method. The spectral response of the methylammonium lead triiodide single crystal solar cells is extended to 820 nm, 20 nm broader than the corresponding polycrystalline thin-film solar cells. The open-circuit voltage and fill factor are not sacrificed, resulting in an efficiency of 17.8% for single crystal perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 497, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1890, "DOI": "10.1038/s41467-017-02039-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02039-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416933400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Liu, LQ; Deng, GW; Deng, C; Bai, YC; Yang, YQ; Wu, WH; Chen, J; Liu, Y; Wang, YG; Lin, X; Han, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Di; Liu, Linqing; Deng, Guowei; Deng, Cheng; Bai, Yuchao; Yang, Yongqiang; Wu, Weihui; Chen, Jie; Liu, Yang; Wang, Yonggang; Lin, Xin; Han, Changjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress on additive manufacturing of multi-material structures with laser powder bed fusion", "Source Title": "VIRTUAL AND PHYSICAL PROTOTYPING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser powder bed fusion (LPBF) additive manufacturing has been advancing in the fabrication of metallic multi-material structures with intricate structures and refined material layouts. Herein, a comprehensive review of the recent achievements of multi-material structures via LPBF is provided in terms of interface characteristics and strengthening methods, critical technical issues and potential applications. It begins with the introduction of multi-material structures and the scope of the review. The interface characteristics (including representative multi-material types printed by LPBF, interfacial microstructure, defects, etc.) and strengthening methods of multi-material structures are then presented. Thereafter, the critical technical issues in LPBF for multi-material structures are discussed with regard to equipment development, data preparation, thermodynamic calculation and process simulation, and powder cross-contamination and recycling. Moreover, the potential applications (particularly in biomedical, electronic, aerospace) are illustrated and discussed. Finally, the outlook is outlined to provide guidance for future research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2022, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 329, "End Page": 365, "Article Number": null, "DOI": "10.1080/17452759.2022.2028343", "DOI Link": "http://dx.doi.org/10.1080/17452759.2022.2028343", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751562000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ilyas, RA; Aisyah, HA; Nordin, A; Ngadi, N; Zuhri, MYM; Asyraf, MRM; Sapuan, SM; Zainudin, ES; Sharma, S; Abral, H; Asrofi, M; Syafri, E; Sari, NH; Rafidah, M; Zakaria, SZS; Razman, MR; Abd Majid, N; Ramli, Z; Azmi, A; Bangar, SP; Ibrahim, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ilyas, Rushdan Ahmad; Aisyah, Humaira Alias; Nordin, Abu Hassan; Ngadi, Norzita; Zuhri, Mohamed Yusoff Mohd; Asyraf, Muhammad Rizal Muhammad; Sapuan, Salit Mohd; Zainudin, Edi Syams; Sharma, Shubham; Abral, Hairul; Asrofi, Mochamad; Syafri, Edi; Sari, Nasmi Herlina; Rafidah, Mazlan; Zakaria, Sharifah Zarina Syed; Razman, Muhammad Rizal; Abd Majid, Nuriah; Ramli, Zuliskandar; Azmi, Ashraf; Bangar, Sneh Punia; Ibrahim, Rushdan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural-Fiber-Reinforced Chitosan, Chitosan Blends and Their nullocomposites for Various Advanced Applications", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been much effort to provide eco-friendly and biodegradable materials for the next generation of composite products owing to global environmental concerns and increased awareness of renewable green resources. This review article uniquely highlights the use of green composites from natural fiber, particularly with regard to the development and characterization of chitosan, natural-fiber-reinforced chitosan biopolymer, chitosan blends, and chitosan nullocomposites. Natural fiber composites have a number of advantages such as durability, low cost, low weight, high specific strength, non-abrasiveness, equitably good mechanical properties, environmental friendliness, and biodegradability. Findings revealed that chitosan is a natural fiber that falls to the animal fiber category. As it has a biomaterial form, chitosan can be presented as hydrogels, sponges, film, and porous membrane. There are different processing methods in the preparation of chitosan composites such as solution and solvent casting, dipping and spray coating, freeze casting and drying, layer-by-layer preparation, and extrusion. It was also reported that the developed chitosan-based composites possess high thermal stability, as well as good chemical and physical properties. In these regards, chitosan-based green composites have wide applicability and potential in the industry of biomedicine, cosmetology, papermaking, wastewater treatment, agriculture, and pharmaceuticals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 874, "DOI": "10.3390/polym14050874", "DOI Link": "http://dx.doi.org/10.3390/polym14050874", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773392800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, Y; Yao, HF; Zhang, JQ; Zhang, T; Wang, YM; Hong, L; Xian, KH; Xu, BW; Zhang, SQ; Peng, J; Wei, ZX; Gao, F; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Yong; Yao, Huifeng; Zhang, Jianqi; Zhang, Tao; Wang, Yuming; Hong, Ling; Xian, Kaihu; Xu, Bowei; Zhang, Shaoqing; Peng, Jing; Wei, Zhixiang; Gao, Feng; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broadening the optical absorption of organic photovoltaic (OPV) materials by enhancing the intramolecular push-pull effect is a general and effective method to improve the power conversion efficiencies of OPV cells. However, in terms of the electron acceptors, the most common molecular design strategy of halogenation usually results in down-shifted molecular energy levels, thereby leading to decreased open-circuit voltages in the devices. Herein, we report a chlorinated non-fullerene acceptor, which exhibits an extended optical absorption and meanwhile displays a higher voltage than its fluorinated counterpart in the devices. This unexpected phenomenon can be ascribed to the reduced non-radiative energy loss (0.206 eV). Due to the simultaneously improved short-circuit current density and open-circuit voltage, a high efficiency of 16.5% is achieved. This study demonstrates that finely tuning the OPV materials to reduce the bandgap-voltage offset has great potential for boosting the efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 906, "Times Cited, All Databases": 911, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2515, "DOI": "10.1038/s41467-019-10351-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10351-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470656800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, TB; Yokoyama, T; Stoumpos, CC; Logsdon, J; Cao, DH; Wasielewski, MR; Aramaki, S; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Tze-Bin; Yokoyama, Takamichi; Stoumpos, Constantinos C.; Logsdon, Jenna; Cao, Duyen H.; Wasielewski, Michael R.; Aramaki, Shinji; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Importance of Reducing Vapor Atmosphere in the Fabrication of Tin-Based Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin-based halide perovskite-materials have been successfully employed in lead-free perovskite solar cells, but the tendency of these materials to form leakage pathways from p-type defect states, mainly Sn4+ and Sn vacancies, causes poor device reproducibility and limits the overall power conversion efficiencies (PCEs). Here, we present an effective process that-involves a reducing vapor atmosphere during the preparation of Sn-based halide perovskite solar cells to solve this problem, using MASnI(3), CsSnI3, and CsSnBr3 as the representative absorbers. This process enables the fabrication of remarkably improved solar cells with PCEs of 3.89%, 1.83%, and 3.04% for MASnI(3), CsSnI3, and CsSnBr3, respectively. The reducing vapor atmosphere process results in more than 20% reduction of Sn4+/Sn2+ ratios, which leads to greatly suppressed carrier recombination, to a level comparable to their lead-based counterparts. These results mark an important step toward a deeper understanding of the intrinsic Sri-based halide perovskite materials, paving the way to the realization of low-cost and lead-free Sn-based halide perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 509, "Times Cited, All Databases": 530, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2017, "Volume": 139, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 836, "End Page": 842, "Article Number": null, "DOI": "10.1021/jacs.6b10734", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b10734", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392459300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DY; Wei, CY; Lin, MC; Pan, CJ; Chou, HL; Chen, HA; Gong, M; Wu, YP; Yuan, CZ; Angell, M; Hsieh, YJ; Chen, YH; Wen, CY; Chen, CW; Hwang, BJ; Chen, CC; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Di-Yan; Wei, Chuan-Yu; Lin, Meng-Chang; Pan, Chun-Jern; Chou, Hung-Lung; Chen, Hsin-An; Gong, Ming; Wu, Yingpeng; Yuan, Chunze; Angell, Michael; Hsieh, Yu-Ju; Chen, Yu-Hsun; Wen, Cheng-Yen; Chen, Chun-Wei; Hwang, Bing-Joe; Chen, Chia-Chun; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced rechargeable aluminium ion battery with a high-quality natural graphite cathode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, interest in aluminium ion batteries with aluminium anodes, graphite cathodes and ionic liquid electrolytes has increased; however, much remains to be done to increase the cathode capacity and to understand details of the anion-graphite intercalation mechanism. Here, an aluminium ion battery cell made using pristine natural graphite flakes achieves a specific capacity of similar to 110 mAh g(-1) with Coulombic efficiency similar to 98%, at a current density of 99mA g(-1) (0.9 C) with clear discharge voltage plateaus (2.25-2.0 V and 1.9-1.5 V). The cell has a capacity of 60 mAh g(-1) at 6 C, over 6,000 cycles with Coulombic efficiency similar to 99%. Raman spectroscopy shows two different intercalation processes involving chloroaluminate anions at the two discharging plateaus, while C-Cl bonding on the surface, or edges of natural graphite, is found using X-ray absorption spectroscopy. Finally, theoretical calculations are employed to investigate the intercalation behaviour of choloraluminate anions in the graphite electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 515, "Times Cited, All Databases": 545, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14283, "DOI": "10.1038/ncomms14283", "DOI Link": "http://dx.doi.org/10.1038/ncomms14283", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393751900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, WJ; Wang, HT; Zhou, JG; Wang, J; Duchesne, PN; Muir, D; Zhang, P; Han, N; Zhao, FP; Zeng, M; Zhong, J; Jin, CH; Li, YG; Lee, ST; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Wenjing; Wang, Hongtao; Zhou, Jigang; Wang, Jian; Duchesne, Paul N.; Muir, David; Zhang, Peng; Han, Na; Zhao, Feipeng; Zeng, Min; Zhong, Jun; Jin, Chuanhong; Li, Yanguang; Lee, Shuit-Tong; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active and durable methanol oxidation electrocatalyst based on the synergy of platinum-nickel hydroxide-graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active and durable electrocatalysts for methanol oxidation reaction are of critical importance to the commercial viability of direct methanol fuel cell technology. Unfortunately, current methanol oxidation electrocatalysts fall far short of expectations and suffer from rapid activity degradation. Here we report platinum-nickel hydroxide-graphene ternary hybrids as a possible solution to this long-standing issue. The incorporation of highly defective nickel hydroxide nullostructures is believed to play the decisive role in promoting the dissociative adsorption of water molecules and subsequent oxidative removal of carbonaceous poison on neighbouring platinum sites. As a result, the ternary hybrids exhibit exceptional activity and durability towards efficient methanol oxidation reaction. Under periodic reactivations, the hybrids can endure at least 500,000 s with negligible activity loss, which is, to the best of our knowledge, two to three orders of magnitude longer than all available electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10035, "DOI": "10.1038/ncomms10035", "DOI Link": "http://dx.doi.org/10.1038/ncomms10035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366375500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klein, DR; MacNeill, D; Lado, JL; Soriano, D; Navarro-Moratalla, E; Watanabe, K; Taniguchi, T; Manni, S; Canfield, P; Fernández-Rossier, J; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klein, D. R.; MacNeill, D.; Lado, J. L.; Soriano, D.; Navarro-Moratalla, E.; Watanabe, K.; Taniguchi, T.; Manni, S.; Canfield, P.; Fernulldez-Rossier, J.; Jarillo-Herrero, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic insulators are a key resource for next-generation spintronic and topological devices. The family of layered metal halides promises varied magnetic states, including ultrathin insulating multiferroics, spin liquids, and ferromagnets, but device-oriented characterization methods are needed to unlock their potential. Here, we report tunneling through the layered magnetic insulator CrI3 as a function of temperature and applied magnetic field. We electrically detect the magnetic ground state and interlayer coupling and observe a field-induced metamagnetic transition. Themetamagnetic transition results in magnetoresistances of 95, 300, and 550% for bilayer, trilayer, and tetralayer CrI3 barriers, respectively. We further measure inelastic tunneling spectra for our junctions, unveiling a rich spectrum consistent with collective magnetic excitations (magnons) in CrI3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 732, "Times Cited, All Databases": 798, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 360, "Issue": 6394, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1218, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar3617", "DOI Link": "http://dx.doi.org/10.1126/science.aar3617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435360400050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZC; Zhu, DY; Rodrigues, SP; Lee, KT; Cai, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhaocheng; Zhu, Dayu; Rodrigues, Sean P.; Lee, Kyu-Tae; Cai, Wenshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generative Model for the Inverse Design of Metasurfaces", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of metasurfaces in recent years has ushered in a revolutionary means to manipulate the behavior of light on the nulloscale. The design of such structures, to date, has relied on the expertise of an optical scientist to guide a progression of electromagnetic simulations that iteratively solve Maxwell's equations until a locally optimized solution can be attained. In this work, we identify a solution to circumvent this conventional design procedure by means of a deep learning architecture. When fed an input set of customer-defined optical spectra, the constructed generative network generates candidate patterns that match the on-demand spectra with high fidelity. This approach reveals an opportunity to expedite the discovery and design systematic, inverse-design manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 672, "Times Cited, All Databases": 727, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 18, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6570, "End Page": 6576, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b03171", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b03171", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447355400065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LX; Zhang, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Lingxiao; Zhang, Junping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly salt-resistant and all-weather solar-driven interfacial evaporators with photothermal and electrothermal effects based on Janus graphene@silicone sponges", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven interfacial evaporators are very promising for obtaining clean water, but suffer from serious performance degradation due to salt-fouling, low evaporation rate under weak illumination and low clean water collection rate. Here, we report highly salt-resistant and all-weather evaporators with photothermal and electrothermal effects based on the Janus graphene@silicone sponges with opposing wettability. The evaporators achieve a remarkable high evaporation rate of 6.53 kg m(-2) h(-1) for 3.5 wt% NaCl solution under 1 sun illumination with a 5 V solar cell as compensation owing to their high solar absorption, low thermal conductivity, unique Janus structure and synergetic photothermal and electrothermal effects. Even in gloomy and dark environments, the evaporators could still generate vapor (1.51 kg m(-2) h 1). Moreover, the evaporators feature long-term excellent salt-resistance, e.g., > 10 d continuous evaporation in 10 wt% NaCl solution without performance degradation and salt precipitation, because of ultrafast water supply and salt diffusion in the macroporous superhydrophilic shell. Furthermore, the evaporators show high clean water collection rates of 21.92 kg m(-2) d 1 (1 sun(-9) h/0 sun-15 h + 5 V, indoor) and 9.65 kg m(-2) d(-1) (natural sun light + 5 V, outdoor). This study offers a new approach for efficiently obtaining clean water via solar desalination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105682, "DOI": "10.1016/j.nulloen.2020.105682", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620328700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, L; Wang, HJ; Niu, M; Dai, S; Cai, ZX; Yang, BG; Huyan, HX; Pan, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Lei; Wang, Hongjie; Niu, Min; Dai, Sheng; Cai, Zhixin; Yang, Biguo; Huyan, Huaixun; Pan, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic and hierarchical SiC@SiO2 nullowire aerogel with exceptional stiffness and stability for thermal superinsulation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ceramic aerogels are promising lightweight and high-efficient thermal insulators for applications in buildings, industry, and aerospace vehicles but are usually limited by their brittleness and structural collapse at high temperatures. In recent years, fabricating nullostructure-based ultralight materials has been proved to be an effective way to realize the resilience of ceramic aerogels. However, the randomly distributed macroscale pores in these architectures usually lead to low stiffness and reduced thermal insulation performance. Here, to overcome these obstacles, a SiC@SiO2 nullowire aerogel with a nullowire-assembled anisotropic and hierarchical microstructure was prepared by using directional freeze casting and subsequent heat treatment. The aerogel exhibits an ultralow thermal conductivity of similar to 14 mW/m.K, an exceptional high stiffness (a specific modulus of similar to 24.7 kN.m/kg), and excellent thermal and chemical stabilities even under heating at 1200 degrees C by a butane blow torch, which makes it an ideal thermally superinsulating material for applications under extreme conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay6689", "DOI": "10.1126/sciadv.aay6689", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay6689", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543504100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Qian, YM; Li, HJ; Zhang, ZH; Mu, YW; Do, D; Zhou, B; Dong, J; Yan, WJ; Qin, Y; Fang, L; Feng, RF; Zhou, JG; Zhang, P; Dong, JC; Yu, GH; Liu, YY; Zhang, XM; Fan, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yang; Qian, Yumin; Li, Haijing; Zhang, Zhenhua; Mu, Yuewen; Do, David; Zhou, Bo; Dong, Jing; Yan, Wenjun; Qin, Yong; Fang, Li; Feng, Renfei; Zhou, Jigang; Zhang, Peng; Dong, Juncai; Yu, Guihua; Liu, Yuanyue; Zhang, Xianming; Fan, Xiujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing strategy in virtue of the synergistic interaction of neighboring metal atoms, which can further improve the intrinsic HER activity beyond SACs. However, the rational design of these systems remains conceptually challenging and requires in-depth research both experimentally and theoretically. Here, we develop a dual-atom catalyst (DAC) consisting of O-coordinated W-Mo heterodimer embedded in N-doped graphene (WiMoi-NG), which is synthesized by controllable self-assembly and nitridation processes. In W1Mo1-NG, the O-bridged W-Mo atoms are anchored in NG vacancies through oxygen atoms with W-O-Mo-O-C configuration, resulting in stable and finely distribution. The W1Mo1-NG DAC enables Pt-like activity and ultrahigh stability for HER in pH-universal electrolyte. The electron delocalization of W-O-Mo-O-C configuration provides optimal adsorption strength of H and boosts the HER kinetics, thereby notably promoting the intrinsic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba6586", "DOI": "10.1126/sciadv.aba6586", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba6586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540787200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, PX; Feng, Y; Zhou, YQ; Tan, CY; Liu, MX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Puxiang; Feng, Yue; Zhou, Youquan; Tan, Cuiying; Liu, Mingxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gold@Halloysite nullotubes-chitin composite hydrogel with antibacterial and hemostatic activity for wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Infection and healing of wounds after injury has always been an unavoidable problem in daily life, so design of a biomaterial with antibacterial and good wound healing properties is highly needed. Herein, a wound healing hydrogel dressing with halloysite clay and chitin as the main components was prepared, which combines the advantages of the biomacromolecule and clay. Halloysite nullotubes (HNTs) are extremely biocompatible clay materials with a hollow tubular structure, and the inner and outer surfaces of HNTs are composed of SiOx and AlOx layers with different charges. Au nulloparticles with diameter in 5-10 nm were filled into the HNTs' lumen to endow photothermal effect of the clay materials. Au@HNTs was then mixed with chitin solution to prepare flexible composite hydrogel by crosslinking by epichlorohydrin. The antibacterial properties, biocompatibility and hemostatic properties of the hydrogel material were investigated by antibacterial experiments, cell exper-iments, mouse liver and tail hemostatic experiments. After infecting the back wound of mice with Staphylococcus aureus, the hydrogel was applied to the wound to further verify the killing effect on bacteria and wound healing effect of the hydrogel material in vivo. The Au@HNTs-chitin composite hydrogel exhibits high antibacterial and hemostatic activity as well as promoting wound healing function with low cytotoxicity. This study is significant for the development of high-performance wound dressings based on two commonly used biocompatible mate-rials, which shows promising application in wound sterilization and healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 355, "End Page": 367, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.05.035", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.05.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830020000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Teicher, SML; Hu, Y; Zuo, JL; Sarte, PM; Schueller, EC; Abeykoon, AMM; Krogstad, MJ; Rosenkranz, S; Osborn, R; Seshadri, R; Balents, L; He, JF; Wilson, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Teicher, Samuel M. L.; Hu, Yong; Zuo, Julia L.; Sarte, Paul M.; Schueller, Emily C.; Abeykoon, A. M. Milinda; Krogstad, Matthew J.; Rosenkranz, Stephan; Osborn, Raymond; Seshadri, Ram; Balents, Leon; He, Junfeng; Wilson, Stephen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CsV3Sb5: A Z2 Topological Kagome Metal with a Superconducting Ground State", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently discovered alongside its sister compounds KV3Sb5 and RbV3Sb5, CsV3Sb5 crystallizes with an ideal kagome network of vanadium and antimonene layers separated by alkali metal ions. This work presents the electronic properties of CsV3Sb5, demonstrating bulk superconductivity in single crystals with a T-c = 2.5 K. The normal state electronic structure is studied via angle-resolved photoemission spectroscopy and density-functional theory, which categorize CsV3Sb5 as a Z(2) topological metal. Multiple protected Dirac crossings are predicted in close proximity to the Fermi level (E-F), and signatures of normal state correlation effects are also suggested by a high-temperature charge density wavelike instability. The implications for the formation of unconventional superconductivity in this material are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 649, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2020, "Volume": 125, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 247002, "DOI": "10.1103/PhysRevLett.125.247002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.247002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597151900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Upham, DC; Agarwal, V; Khechfe, A; Snodgrass, ZR; Gordon, MJ; Metiu, H; McFarland, EW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Upham, D. Chester; Agarwal, Vishal; Khechfe, Alexander; Snodgrass, Zachary R.; Gordon, Michael J.; Metiu, Horia; McFarland, Eric W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic molten metals for the direct conversion of methane to hydrogen and separable carbon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metals that are active catalysts for methane (Ni, Pt, Pd), when dissolved in inactive low-melting temperature metals (In, Ga, Sn, Pb), produce stable molten metal alloy catalysts for pyrolysis of methane into hydrogen and carbon. All solid catalysts previously used for this reaction have been deactivated by carbon deposition. In the molten alloy system, the insoluble carbon floats to the surface where it can be skimmed off. A 27% Ni-73% Bi alloy achieved 95% methane conversion at 1065 degrees C in a 1.1-meter bubble column and produced pure hydrogen without CO2 or other by-products. Calculations show that the active metals in the molten alloys are atomically dispersed and negatively charged. There is a correlation between the amount of charge on the atoms and their catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2017, "Volume": 358, "Issue": 6365, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 917, "End Page": 920, "Article Number": null, "DOI": "10.1126/science.aao5023", "DOI Link": "http://dx.doi.org/10.1126/science.aao5023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415293000045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ramírez, A; Hillebrand, P; Stellmach, D; May, MM; Bogdanoff, P; Fiechter, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ramirez, Alejandra; Hillebrand, Philipp; Stellmach, Diana; May, Matthias M.; Bogdanoff, Peter; Fiechter, Sebastian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluation of MnOx, Mn2O3, and Mn3O4 Electrodeposited Films for the Oxygen Evolution Reaction of Water", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Different manganese oxide phases were prepared as thin films to elucidate their structure-function relationship with respect to oxygen evolution in the process of water splitting. For this purpose, amorphous MnOx films anodically deposited on F:SnO2/glass and annealed at different temperatures (to improve film adherence and crystallinity) were tested in neutral and alkaline electrolytes. Differential electrochemical mass spectroscopy showed that the anodic current correlated well with the onset of the expected oxygen evolution, where in 1 M KOH, the anodic current of crystalline alpha-Mn2O3 films was determined to onset at an overpotential (eta) of 170 mV(RHE) (at J = 0.1 mA/cm(2)) with current densities of ca. 20 mA/cm(2) at eta = 570 mVRHE. Amorphous MnOx films heated at 573 K (MnOx-573 K) were found to improve their adherence to F:SnO2/glass substrate after heat treatment with a slight crystallization detected by Raman spectroscopy. The onset of water oxidation of MnOx-573 K films was identified at eta = 230 mV(RHE) (at J = 0.1 mA/cm(2)) with current densities of ca. 20 mA/cm(2) at eta = 570 mV(RHE) (1 M KOH). The least active of the investigated manganese oxides was Mn3O4 with an onset at eta = 290 mVRHE (at J = 0.1 mA/cm2) and current densities of ca. 10 niA/cm(2) at eta = 570 mV(RHE) (1 M KOH). In neutral solution (1 M KPi, a similar tendency was observed with the lowest overpotential found for alpha-Mn2O3 followed by MnOx-573 K and Mn3O4. X-ray photoelectron spectroscopy revealed that after electrochemical treatment, the surfaces of the manganese oxide electrodes exhibited oxidation of Mn II and Mn III toward Mn IV under oxygen evolving conditions. In the case of alpha-Mn2O3 and MnOx-573 K, the manganese oxidation was found to be reversible in KPi when switching the potential above and below the oxygen evolution reaction (OER) threshold potential. Furthermore, scanning electron microscopy (SEM) images displayed the presence of an amorphous phase on top of all manganese oxide films here tested after oxygen evolution. The results indicate that structural changes played an important role in the catalytic activity of the manganese oxides, in addition to oxidation states, a large variety of Mn-O bond lengths and a high concentration of oxygen point defects. Thus, compared to Mn3O4, crystalline alpha-Mn2O3 and MnOx-573 K are the most efficient catalyst for water oxidation in the manganese oxygen system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2014, "Volume": 118, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14073, "End Page": 14081, "Article Number": null, "DOI": "10.1021/jp500939d", "DOI Link": "http://dx.doi.org/10.1021/jp500939d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338693600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koscher, BA; Swabeck, JK; Bronstein, ND; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koscher, Brent A.; Swabeck, Joseph K.; Bronstein, Noah D.; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Essentially Trap-Free CsPbBr3 Colloidal nullocrystals by Postsynthetic Thiocyanate Surface Treatment", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate postsynthetic modification of CsPbBr3 nullocrystals by a thiocyanate salt treatment. This treatment improves the quantum yield of both freshly synthesized (PLQY approximate to 90%) and aged nullocrystals (PLQY approximate to 70%) to within measurement error (2-3%) of unity, while simultaneously maintaining the shape, size, and colloidal stability. Additionally, the luminescence decay kinetics transform from multiexponential decays typical of nullocrystalline semiconductors with a distribution of trap sites, to a rnonoexponential decay, typical of single energy level emitters. Thiocyanate only needs to access a limited number of CsPbBr3 nullocrystal surface sites, likely representing under-coordinated lead atoms on the surface, in order to have this effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 139, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6566, "End Page": 6569, "Article Number": null, "DOI": "10.1021/jacs.7b02817", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b02817", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401781900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karlsson, LH; Birch, J; Halim, J; Barsoum, MW; Persson, POÅ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karlsson, Linda H.; Birch, Jens; Halim, Joseph; Barsoum, Michel W.; Persson, Per O. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Resolved Structural and Chemical Investigation of Single MXene Sheets", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The properties of two-dimensional (2D) materials depend strongly on the chemical and electrochemical activity of their surfaces. Name, one of the most recent additions to 2D materials, shows great promise as an energy storage material. In the present investigation, the chemical and structural properties of individual Ti3C2 MXene sheets with associated surface groups are investigated at the atomic level by aberration corrected STEM-EELS. The MXene sheets are shown to exhibit a nonuniform coverage of O-based surface groups which locally affect the chemistry. Additionally, native point defects which are proposed to affect the local surface chemistry, such as oxidized titanium adatoms (TiOx), are identified and found to be mobile.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4955, "End Page": 4960, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b00737", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b00737", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359613700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, HL; Shi, ZP; He, SN; Yu, X; Wang, SN; Gao, QS; Tang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Huanlei; Shi, Zhangping; He, Sina; Yu, Xiang; Wang, Sinong; Gao, Qingsheng; Tang, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heteronullowires of MoC-Mo2C as efficient electrocatalysts for hydrogen evolution reaction", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring efficient noble-metal free electrocatalysts for the hydrogen evolution reaction (HER) is one of the most promising pathways for facing the energy crisis. Herein, MoC-Mo2C heteronullowires composed of well-defined nulloparticles were accomplished via controlled carbonization, showing excellent HER activity, fast kinetic metrics and outstanding stability in both acid and basic electrolytes. In particular, the optimal one consisting of 31.4 wt% MoC displayed a low overpotential (eta(10) = 126 and 120 mV for reaching a current density of -10 mA cm(-2)), a small Tafel slope (43 and 42 mV dec(-1)) and a low onset overpotential (38 and 33 mV) in 0.5 M H2SO4 and 1.0 M KOH, respectively. Such prominent performance, outperforming most of the current noble-metal free electrocatalysts, was ascribed to the carbide surface with an optimized electron density, and the consequently facilitated HER kinetics. This work elucidates a feasible way toward efficient electrocatalysts via heteronullostructure engineering, shedding some light on the exploration and optimization of catalysts in energy chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 533, "Times Cited, All Databases": 538, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3399, "End Page": 3405, "Article Number": null, "DOI": "10.1039/c6sc00077k", "DOI Link": "http://dx.doi.org/10.1039/c6sc00077k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374859300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, K; Xie, L; Zhang, YD; Hanyu, M; Yang, ZM; Nagatsu, K; Suzuki, H; Ouyang, J; Ji, XY; Wei, JJ; Xu, H; Farokhzad, OC; Liang, SH; Wang, L; Tao, W; Zhang, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Kuan; Xie, Lin; Zhang, Yiding; Hanyu, Masayuki; Yang, Zhimin; Nagatsu, Kotaro; Suzuki, Hisashi; Ouyang, Jiang; Ji, Xiaoyuan; Wei, Junjie; Xu, Hao; Farokhzad, Omid C.; Liang, Steven H.; Wang, Lu; Tao, Wei; Zhang, Ming-Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Marriage of black phosphorus and Cu2+ as effective photothermal agents for PET-guided combination cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of photothermal agents (PTAs) in cancer photothermal therapy (PTT) has shown promising results in clinical studies. The rapid degradation of PTAs may address safety concerns but usually limits the photothermal stability required for efficacious treatment. Conversely, PTAs with high photothermal stability usually degrade slowly. The solutions that address the balance between the high photothermal stability and rapid degradation of PTAs are rare. Here, we report that the inherent Cu2+-capturing ability of black phosphorus (BP) can accelerate the degradation of BP, while also enhancing photothermal stability. The incorporation of Cu2+ into BP@Cu nullostructures further enables chemodynamic therapy (CDT)-enhanced PTT. Moreover, by employing Cu-64(2+), positron emission tomography (PET) imaging can be achieved for in vivo real-time and quantitative tracking. Therefore, our study not only introduces an ideal PTA that bypasses the limitations of PTAs, but also provides the proof-of-concept application of BP-based materials in PET-guided, CDT-enhanced combination cancer therapy. A balance between high stability and rapid degradation is required for effective photothermal anti-cancer agents. Here, the authors use Cu2+ to accelerate the degradation of black phosphorus nullosheets while enhancing its photothermal ability and apply this material for PET-guided, CDT-enhanced combination cancer therapy in mice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16513-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16513-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541701900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, RF; Hu, Y; Wu, YF; Gao, W; Ren, BY; Wang, QL; Cai, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Renfeng; Hu, Yan; Wu, Yefei; Gao, Wei; Ren, Biye; Wang, Qinglong; Cai, Yuepeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible-Light-Driven BiOI-Based Janus Micromotor in Pure Water", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-driven synthetic micro-/nullomotors have attracted considerable attention due to their potential applications and unique performances such as remote motion control and adjustable velocity. Utilizing harmless and renewable visible light to supply energy for micro-/nullomotors in water represents a great challenge. In view of the outstanding photocatalytic performance of bismuth oxyiodide visible-light-driven BiOI-based Janus micromotors have been developed, which can be activated by a broad spectrum of light, including blue and green light. Such BiOI-based Janus micromotors can be propelled by photocatalytic reactions in pure water under environmentally friendly visible light without the addition of any other chemical fuels. The remote control of photocatalytic propulsion by modulating the power of visible light is characterized by velocity and mean-square displacement analysis of optical video recordings. In addition, the self-electrophoresis mechanism has been confirmed for such visible-light-driven BiOI-based Janus micromotors by demonstrating the effects of various coated layers (e.g., Al2O3, Pt, and Au) on the velocity of motors. The successful demonstration of visible-light driven Janus micromotors holds a great promise for future biomedical and environmental applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2017, "Volume": 139, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1722, "End Page": 1725, "Article Number": null, "DOI": "10.1021/jacs.6b09863", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b09863", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393848400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, PF; Zheng, JM; Gu, M; Xiao, J; Zhang, JG; Wang, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Pengfei; Zheng, Jianming; Gu, Meng; Xiao, Jie; Zhang, Ji-Guang; Wang, Chong-Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "LiNi1/3Mn1/3Co1/3O2-layered cathode is often fabricated in the form of secondary particles, consisting of densely packed primary particles. This offers advantages for high energy density and alleviation of cathode side reactions/corrosions, but introduces drawbacks such as intergranular cracking. Here, we report unexpected observations on the nucleation and growth of intragranular cracks in a commercial LiNi1/3Mn1/3Co1/3O2 cathode by using advanced scanning transmission electron microscopy. We find the formation of the intragranular cracks is directly associated with high-voltage cycling, an electrochemically driven and diffusion-controlled process. The intragranular cracks are noticed to be characteristically initiated from the grain interior, a consequence of a dislocation-based crack incubation mechanism. This observation is in sharp contrast with general theoretical models, predicting the initiation of intragranular cracks from grain boundaries or particle surfaces. Our study emphasizes that maintaining structural stability is the key step towards high-voltage operation of layered-cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 804, "Times Cited, All Databases": 864, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14101, "DOI": "10.1038/ncomms14101", "DOI Link": "http://dx.doi.org/10.1038/ncomms14101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392095500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, FZ; Li, W; Yang, JQ; Han, GQ; Liao, PL; Sun, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Fuzhan; Li, Wei; Yang, Jiaqi; Han, Guanqun; Liao, Peilin; Sun, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysts of the hydrogen evolution and oxidation reactions (HER and HOR) are of critical importance for the realization of future hydrogen economy. In order to make electrocatalysts economically competitive for large-scale applications, increasing attention has been devoted to developing noble metal-free HER and HOR electrocatalysts especially for alkaline electrolytes due to the promise of emerging hydroxide exchange membrane fuel cells. Herein, we report that interface engineering of Ni3N and Ni results in a unique Ni3N/Ni electrocatalyst which exhibits exceptional HER/HOR activities in aqueous electrolytes. A systematic electro-chemical study was carried out to investigate the superior hydrogen electrochemistry catalyzed by Ni3N/Ni, including nearly zero overpotential of catalytic onset, robust long-term durability, unity Faradaic efficiency, and excellent CO tolerance. Density functional theory computations were performed to aid the understanding of the electrochemical results and suggested that the real active sites are located at the interface between Ni3N and Ni.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4531, "DOI": "10.1038/s41467-018-06728-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06728-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448807000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tai, QD; You, P; Sang, HQ; Liu, ZK; Hu, CL; Chan, HLW; Yan, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tai, Qidong; You, Peng; Sang, Hongqian; Liu, Zhike; Hu, Chenglong; Chan, Helen L. W.; Yan, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable perovskite solar cells prepared in ambient air irrespective of the humidity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poor stability of organic-inorganic halide perovskite materials in humid condition has hindered the success of perovskite solar cells in real applications since controlled atmosphere is required for device fabrication and operation, and there is a lack of effective solutions to this problem until now. Here we report the use of lead (II) thiocyanate (Pb(SCN)(2)) precursor in preparing perovskite solar cells in ambient air. High-quality CH3NH3PbI3-x(SCN)(x) perovskite films can be readily prepared even when the relative humidity exceeds 70%. Under optimized processing conditions, we obtain devices with an average power conversion efficiency of 13.49% and the maximum efficiency over 15%. In comparison with typical CH3NH3PbI3-based devices, these solar cells without encapsulation show greatly improved stability in humid air, which is attributed to the incorporation of thiocyanate ions in the crystal lattice. The findings pave a way for realizing efficient and stable perovskite solar cells in ambient atmosphere.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11105, "DOI": "10.1038/ncomms11105", "DOI Link": "http://dx.doi.org/10.1038/ncomms11105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373476900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Rodan-Legrain, D; Rubies-Bigorda, O; Park, JM; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuan; Rodan-Legrain, Daniel; Rubies-Bigorda, Oriol; Park, Jeong Min; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable correlated states and spin-polarized phases in twisted bilayer-bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of correlated insulator states and superconductivity in magic-angle twisted bilayer graphene(1,2) has enabled the experimental investigation of electronic correlations in tunable flat-band systems realized in twisted van der Waals heterostructures(3-6). This novel twist angle degree of freedom and control should be generalizable to other two-dimensional systems, which may exhibit similar correlated physics behaviour, and could enable techniques to tune and control the strength of electron-electron interactions. Here we report a highly tunable correlated system based on small-angle twisted bilayer-bilayer graphene (TBBG), consisting of two rotated sheets of Bernal-stacked bilayer graphene. We find that TBBG exhibits a rich phase diagram, with tunable correlated insulator states that are highly sensitive to both the twist angle and the application of an electric displacement field, the latter reflecting the inherent polarizability of Bernal-stacked bilayer graphene(7,8). The correlated insulator states can be switched on and off by the displacement field at all integer electron fillings of the moire unit cell. The response of these correlated states to magnetic fields suggests evidence of spin-polarized ground states, in stark contrast to magic-angle twisted bilayer graphene. Furthermore, in the regime of lower twist angles, TBBG shows multiple sets of flat bands near charge neutrality, resulting in numerous correlated states corresponding to half-filling of each of these flat bands, all of which are tunable by the displacement field as well. Our results could enable the exploration of twist-angle- and electric-field-controlled correlated phases of matter in multi-flat-band twisted superlattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2020, "Volume": 583, "Issue": 7815, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 215, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2260-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2260-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623832900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, B; Hu, P; Yang, F; Hua, XJ; Yang, FF; Zhu, F; Sun, RY; Hao, K; Wang, KS; Yin, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Bo; Hu, Ping; Yang, Fan; Hua, Xingjiang; Yang, Fairy Fan; Zhu, Fei; Sun, Ruiyan; Hao, Ke; Wang, Kuaishe; Yin, Zongyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Porousized MoS2 nullo Islands Enhance HER/OER Bifunctional Electrocatalysis", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D molybdenum disulfide (MoS2) is developed as a potential alternative non-precious metal electrocatalyst for energy conversion. It is well known that 2D MoS2 has three main phases 2H, 1T, and 1T '. However, the most stable 2H-phase shows poor electrocatalysis in its basal plane, compared with its edge sites. In this work, a facile one-step hydrothermal-driven in situ porousizing of MoS2 into self-supporting nullo islands to maximally expose the edges of MoS2 grains for efficient utilization of the active stable sites at the edges of MoS2 is reported. The results show that such active, aggregation-free nullo islands greatly enhance MoS2's hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) bifunctional electrocatalytic activities. At a low overpotential of 248 and 300 mV, the porous MoS2 nullo islands can generate a current density of 10 mA cm(-2) in HER and OER, which is much better than typical nullosheet morphology. Surprisingly, the porous MoS2 nullo islands even exhibit better performance than the current commercial RuO2 catalyst in OER. This discovery will be another effective strategy to promote robust 2H-phase, instead of 1T/1T '-phase, MoS2 to achieve efficient endurable bifunctional HER/OER, which is expected to further replace precious metal catalysts in industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 19, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/smll.202207177", "DOI Link": "http://dx.doi.org/10.1002/smll.202207177", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921417600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, HL; Chen, SM; Mao, LB; Song, ZQ; Yao, HB; Cölfen, H; Luo, XS; Zhang, F; Pan, Z; Meng, YF; Ni, Y; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Huai-Ling; Chen, Si-Ming; Mao, Li-Bo; Song, Zhao-Qiang; Yao, Hong-Bin; Coelfen, Helmut; Luo, Xi-Sheng; Zhang, Fu; Pan, Zhao; Meng, Yu-Feng; Ni, Yong; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mass production of bulk artificial nacre with excellent mechanical properties", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various methods have been exploited to replicate nacre features into artificial structural materials with impressive structural and mechanical similarity. However, it is still very challenging to produce nacre-mimetics in three-dimensional bulk form, especially for further scale-up. Herein, we demonstrate that large-sized, three-dimensional bulk artificial nacre with comprehensive mimicry of the hierarchical structures and the toughening mechanisms of natural nacre can be facilely fabricated via a bottom-up assembly process based on laminating pre-fabricated two-dimensional nacre-mimetic films. By optimizing the hierarchical architecture from molecular level to macroscopic level, the mechanical performance of the artificial nacre is superior to that of natural nacre and many engineering materials. This bottom-up strategy has no size restriction or fundamental barrier for further scale-up, and can be easily extended to other material systems, opening an avenue for mass production of high-performance bulk nacre-mimetic structural materials in an efficient and cost-effective way for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 287, "DOI": "10.1038/s41467-017-00392-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00392-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408012500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bergmann, A; Martinez-Moreno, E; Teschner, D; Chernev, P; Gliech, M; de Araújo, JF; Reier, T; Dau, H; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bergmann, Arno; Martinez-Moreno, Elias; Teschner, Detre; Chernev, Petko; Gliech, Manuel; de Araujo, Jorge Ferreira; Reier, Tobias; Dau, Holger; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water splitting catalysed by earth-abundant materials is pivotal for global-scale production of non-fossil fuels, yet our understanding of the active catalyst structure and reactivity is still insufficient. Here we report on the structurally reversible evolution of crystalline Co3O4 electrocatalysts during oxygen evolution reaction identified using advanced in situ X-ray techniques. At electrode potentials facilitating oxygen evolution, a sub-nullometre shell of the Co3O4 is transformed into an X-ray amorphous CoOx(OH)(y) which comprises di-mu-oxo-bridged Co3+/4+ ions. Unlike irreversible amorphizations, here, the formation of the catalytically-active layer is reversed by re-crystallization upon return to non-catalytic electrode conditions. The Co3O4 material thus combines the stability advantages of a controlled, stable crystalline material with high catalytic activity, thanks to the structural flexibility of its active amorphous oxides. We propose that crystalline oxides may be tailored for generating reactive amorphous surface layers at catalytic potentials, just to return to their stable crystalline state under rest conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 730, "Times Cited, All Databases": 761, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8625, "DOI": "10.1038/ncomms9625", "DOI Link": "http://dx.doi.org/10.1038/ncomms9625", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364934200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, M; Xiong, DB; Tan, ZQ; Ji, G; Amin-Ahmadi, B; Guo, Q; Fan, GL; Guo, CP; Li, ZQ; Zhang, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Mu; Xiong, Ding-Bang; Tan, Zhanqiu; Ji, Gang; Amin-Ahmadi, Behnam; Guo, Qiang; Fan, Genlian; Guo, Cuiping; Li, Zhiqiang; Zhang, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aligning graphene in bulk copper: Nacre-inspired nullolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methods used to strengthen metals generally also cause a pronounced decrease in ductility and electrical conductivity. In this work a bioinspired strategy is applied to surmount the dilemma. By assembling copper submicron flakes cladded with in-situ grown graphene, graphene/copper matrix composites with a nullolaminated architecture inspired by a natural nacre have been prepared. Owing to a combined effect-from the bioinspired nullolaminated architecture and improved interfacial bonding, a synergy has been achieved between mechanical strength and ductility as well as electrical conductivity in the graphene/copper matrix composites. With a low volume fraction of only 2.5% of graphene, the composite shows a yield strength and elastic modulus similar to 177% and similar to 25% higher than that of unreinforced copper matrix, respectively, while retains ductility and electrical conductivity comparable to that of pure copper. The bioinspired nullolaminated architecture enhances the efficiencies of two-dimensional (2D) graphene in mechanical strengthening and electrical conducting by aligning graphene to maximize performance for required loading and carrier transporting conditions, and toughens the composites by crack deflection. Meanwhile, in-situ growth of graphene is beneficial for improving interfacial bonding and structural quality of graphene. The strategy sheds light on the development of composites with good combined structural and functional properties. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 117, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 74, "Article Number": null, "DOI": "10.1016/j.carbon.2017.02.089", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2017.02.089", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400212100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Landman, A; Dotan, H; Shter, GE; Wullenkord, M; Houaijia, A; Maljusch, A; Grader, GS; Rothschild, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Landman, Avigail; Dotan, Hen; Shter, Gennady E.; Wullenkord, Michael; Houaijia, Anis; Maljusch, Artjom; Grader, Gideon S.; Rothschild, Avner", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoelectrochemical water splitting in separate oxygen and hydrogen cells", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar water splitting provides a promising path for sustainable hydrogen production and solar energy storage. One of the greatest challenges towards large-scale utilization of this technology is reducing the hydrogen production cost. The conventional electrolyser architecture, where hydrogen and oxygen are co-produced in the same cell, gives rise to critical challenges in photoelectrochemical water splitting cells that directly convert solar energy and water to hydrogen. Here we overcome these challenges by separating the hydrogen and oxygen cells. The ion exchange in our cells is mediated by auxiliary electrodes, and the cells are connected to each other only by metal wires, enabling centralized hydrogen production. We demonstrate hydrogen generation in separate cells with solar-to-hydrogen conversion efficiency of 7.5%, which can readily surpass 10% using standard commercial components. A basic cost comparison shows that our approach is competitive with conventional photoelectrochemical systems, enabling safe and potentially affordable solar hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 646, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4876", "DOI Link": "http://dx.doi.org/10.1038/NMAT4876", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402017000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, KH; Li, HB; Huang, D; Xiao, S; Qiu, WT; Li, MY; Hu, YW; Mai, WJ; Ji, HB; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Kai-Hang; Li, Haibo; Huang, Duan; Xiao, Shuang; Qiu, Weitao; Li, Mingyang; Hu, Yuwen; Mai, Wenjie; Ji, Hongbing; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing photoelectrochemical water splitting by combining work function tuning and heterojunction engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We herein demonstrate the unusual effectiveness of two strategies in combination to enhance photoelectrochemical water splitting. First, the work function adjustment via molybdenum (Mo) doping significantly reduces the interfacial energy loss and increases the open-circuit photovoltage of bismuth vanadate (BiVO4) photoelectrochemical cells. Second, the creation and optimization of the heterojunction of boron (B) doping carbon nitride (C3N4) and Mo doping BiVO4 to enforce directional charge transfer, accomplished by work function adjustment via B doping for C3N4, substantially boost the charge separation of photo-generated electron-hole pairs at the B-C3N4 and Mo-BiVO4 interface. The synergy between the above efforts have significantly reduced the onset potential, and enhanced charge separation and optical properties of the BiVO4-based photoanode, culminating in achieving a record applied bias photon-to-current efficiency of 2.67% at 0.54 V vs. the reversible hydrogen electrode. This work sheds light on designing and fabricating the semiconductor structures for the next-generation photoelectrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3687, "DOI": "10.1038/s41467-019-11586-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11586-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000480684500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, XB; Zhao, MQ; Chen, C; Pentecost, A; Maleski, K; Mathis, T; Zhang, XQ; Zhang, Q; Jiang, JJ; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Xin-Bing; Zhao, Meng-Qiang; Chen, Chi; Pentecost, Amanda; Maleski, Kathleen; Mathis, Tyler; Zhang, Xue-Qiang; Zhang, Qiang; Jiang, Jianjun; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullodiamonds suppress the growth of lithium dendrites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has been regarded as the future anode material for high-energy-density rechargeable batteries due to its favorable combination of negative electrochemical potential and high theoretical capacity. However, uncontrolled lithium deposition during lithium plating/stripping results in low Coulombic efficiency and severe safety hazards. Herein, we report that nullodiamonds work as an electrolyte additive to co-deposit with lithium ions and produce dendrite-free lithium deposits. First-principles calculations indicate that lithium prefers to adsorb onto nullodiamond surfaces with a low diffusion energy barrier, leading to uniformly deposited lithium arrays. The uniform lithium deposition morphology renders enhanced electrochemical cycling performance. The nullodiamond-modified electrolyte can lead to a stable cycling of lithium vertical bar lithium symmetrical cells up to 150 and 200 h at 2.0 and 1.0 mA cm(-2), respectively. The nullodiamond co-deposition can significantly alter the lithium plating behavior, affording a promising route to suppress lithium dendrite growth in lithium metal-based batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 336, "DOI": "10.1038/s41467-017-00519-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00519-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408376600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Dai, CL; Xiao, FY; Yang, QJ; Cai, SN; Xu, MW; Fan, HJ; Bao, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Dai, Chunlong; Xiao, Fangyuan; Yang, Qiuju; Cai, Shinull; Xu, Maowen; Fan, Hong Jin; Bao, Shu-Juan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reunderstanding the Reaction Mechanism of Aqueous Zn-Mn Batteries with Sulfate Electrolytes: Role of the Zinc Sulfate Hydroxide", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous Zn-Mn batteries have garnered extensive attention for next-generation high-safety energy storage. However, the charge-storage chemistry of Zn-Mn batteries remains controversial. Prevailing mechanisms include conversion reaction and cation (de)intercalation in mild acid or neutral electrolytes, and a MnO2/Mn2+ dissolution-deposition reaction in strong acidic electrolytes. Herein, a Zn4SO4 center dot(OH)(6)center dot xH(2)O (ZSH)-assisted deposition-dissolution model is proposed to elucidate the reaction mechanism and capacity origin in Zn-Mn batteries based on mild acidic sulfate electrolytes. In this new model, the reversible capacity originates from a reversible conversion reaction between ZSH and ZnxMnO(OH)(2) nullosheets in which the MnO2 initiates the formation of ZSH but contributes negligibly to the apparent capacity. The role of ZSH in this new model is confirmed by a series of operando characterizations and by constructing Zn batteries using other cathode materials (including ZSH, ZnO, MgO, and CaO). This research may refresh the understanding of the most promising Zn-Mn batteries and guide the design of high-capacity aqueous Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2109092, "DOI": "10.1002/adma.202109092", "DOI Link": "http://dx.doi.org/10.1002/adma.202109092", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000761544500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, X; Sushkov, AB; Suess, RJ; Jadidi, MM; Jenkins, GS; Nyakiti, LO; Myers-Ward, RL; Li, S; Yan, J; Gaskill, DK; Murphy, TE; Drew, HD; Fuhrer, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Xinghan; Sushkov, Andrei B.; Suess, Ryan J.; Jadidi, Mohammad M.; Jenkins, Gregory S.; Nyakiti, Luke O.; Myers-Ward, Rachael L.; Li, Shanshan; Yan, Jun; Gaskill, D. Kurt; Murphy, Thomas E.; Drew, H. Dennis; Fuhrer, Michael S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive room-temperature terahertz detection via the photothermoelectric effect in graphene", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Terahertz radiation has uses in applications ranging from security to medicine(1). However, sensitive room-temperature detection of terahertz radiation is notoriously difficult(2). The hot-electron photothermoelectric effect in graphene is a promising detection mechanism; photoexcited carriers rapidly thermalize due to strong electron-electron interactions(3,4), but lose energy to the lattice more slowly(3,5). The electron temperature gradient drives electron diffusion, and asymmetry due to local gating(6,7) or dissimilar contact metals(8) produces a net current via the thermoelectric effect. Here, we demonstrate a graphene thermoelectric terahertz photodetector with sensitivity exceeding 10 V W-1 (700 V W-1) at room temperature and noise-equivalent power less than 1,100 pW Hz(-1/2) (20 pW Hz(-1/2)), referenced to the incident (absorbed) power. This implies a performance that is competitive with the best room-temperature terahertz detectors(9) for an optimally coupled device, and time-resolved measurements indicate that our graphene detector is eight to nine orders of magnitude faster than those(7,10). A simple model of the response, including contact asymmetries (resistance, work function and Fermi-energy pinning) reproduces the qualitative features of the data, and indicates that orders-of-magnitude sensitivity improvements are possible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 563, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 814, "End Page": 819, "Article Number": null, "DOI": "10.1038/NnullO.2014.182", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2014.182", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343617200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, WJ; Huang, MJ; Li, YT; Zhu, YG; Gao, R; Xiao, XH; Zhang, WX; Li, SP; Xu, GY; Yu, Y; Li, P; Lopez, J; Yu, DW; Dong, YH; Fan, WW; Shi, Z; Xiong, R; Sun, CJ; Hwang, I; Lee, WK; Shao-Horn, Y; Johnson, JA; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Weijiang; Huang, Mingjun; Li, Yutao; Zhu, Yun Guang; Gao, Rui; Xiao, Xianghui; Zhang, Wenxu; Li, Sipei; Xu, Guiyin; Yu, Yang; Li, Peng; Lopez, Jeffrey; Yu, Daiwei; Dong, Yanhao; Fan, Weiwei; Shi, Zhe; Xiong, Rui; Sun, Cheng-Jun; Hwang, Inhui; Lee, Wah-Keat; Shao-Horn, Yang; Johnson, Jeremiah A.; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By increasing the charging voltage, a cell specific energy of >400 W h kg(-1) is achievable with LiNi0.8Mn0.1Co0.1O2 in Li metal batteries. However, stable cycling of high-nickel cathodes at ultra-high voltages is extremely challenging. Here we report that a rationally designed sulfonamide-based electrolyte enables stable cycling of commercial LiNi0.8Co0.1Mn0.1O2 with a cut-off voltage up to 4.7 V in Li metal batteries. In contrast to commercial carbonate electrolytes, the electrolyte not only suppresses side reactions, stress-corrosion cracking, transition-metal dissolution and impedance growth on the cathode side, but also enables highly reversible Li metal stripping and plating leading to a compact morphology and low pulverization. Our lithium-metal battery delivers a specific capacity >230 mA h g(-1) and an average Coulombic efficiency >99.65% over 100 cycles. Even under harsh testing conditions, the 4.7 V lithium-metal battery can retain >88% capacity for 90 cycles, advancing practical lithium-metal batteries. Charging at high voltages in principle makes batteries energy dense, but this is often achieved at the cost of the cycling stability. Here the authors design a sulfonamide-based electrolyte to enable a Li metal battery with a state-of-the-art cathode at an ultra-high voltage of 4.7 V while maintaining cyclability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 505, "Article Number": null, "DOI": "10.1038/s41560-021-00792-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00792-y", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632736300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, LJ; Zhou, Z; Xu, MQ; Yang, SQ; Si, KP; Liu, LX; Wang, XG; Jiang, HN; Li, BX; Qin, PX; Zhang, P; Wang, JL; Liu, ZQ; Tang, PZ; Ye, Y; Zhou, W; Bao, LH; Gao, HJ; Gong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Lingjia; Zhou, Zhang; Xu, Mingquan; Yang, Shiqi; Si, Kunpeng; Liu, Lixuan; Wang, Xingguo; Jiang, Huaning; Li, Bixuan; Qin, Peixin; Zhang, Peng; Wang, Jinliang; Liu, Zhiqi; Tang, Peizhe; Ye, Yu; Zhou, Wu; Bao, Lihong; Gao, Hong-Jun; Gong, Yongji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalous thickness dependence of Curie temperature in air-stable two-dimensional ferromagnetic 1T-CrTe2 grown by chemical vapor deposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of ferromagnetic two-dimensional van der Waals materials has opened up opportunities to explore intriguing physics and to develop innovative spintronic devices. However, controllable synthesis of these 2D ferromagnets and enhancing their stability under ambient conditions remain challenging. Here, we report chemical vapor deposition growth of air-stable 2D metallic 1T-CrTe2 ultrathin crystals with controlled thickness. Their long-range ferromagnetic ordering is confirmed by a robust anomalous Hall effect, which has seldom been observed in other layered 2D materials grown by chemical vapor deposition. With reducing the thickness of 1T-CrTe2 from tens of nullometers to several nullometers, the easy axis changes from in-plane to out-of-plane. Monotonic increase of Curie temperature with the thickness decreasing from similar to 130.0 to similar to 7.6nm is observed. Theoretical calculations indicate that the weakening of the Coulomb screening in the two-dimensional limit plays a crucial role in the change of magnetic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 809, "DOI": "10.1038/s41467-021-21072-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21072-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617499600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, MS; Gao, AY; Wang, P; Xia, H; Ott, C; Pan, C; Fu, YJ; Liu, EF; Chen, XS; Lu, W; Nilges, T; Xu, JB; Wang, XM; Hu, WD; Miao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Mingsheng; Gao, Anyuan; Wang, Peng; Xia, Hui; Ott, Claudia; Pan, Chen; Fu, Yajun; Liu, Erfu; Chen, Xiaoshuang; Lu, Wei; Nilges, Tom; Xu, Jianbin; Wang, Xiaomu; Hu, Weida; Miao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature high-detectivity mid-infrared photodetectors based on black arsenic phosphorus", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mid-infrared (MIR) spectral range, pertaining to important applications, such as molecular fingerprint imaging, remote sensing, free space telecommunication, and optical radar, is of particular scientific interest and technological importance. However, state-of-the-art materials for MIR detection are limited by intrinsic noise and inconvenient fabrication processes, resulting in high-cost photodetectors requiring cryogenic operation. We report black arsenic phosphorus-based long-wavelength IR photodetectors, with room temperature operation up to 8.2 mu m, entering the second MIR atmospheric transmission window. Combined with a van der Waals heterojunction, room temperature-specific detectivity higher than 4.9 x 10(9) Jones was obtained in the 3- to 5-mu m range. The photodetector works in a zero-bias photovoltaic mode, enabling fast photoresponse and low dark noise. Our van der Waals heterojunction photodetectors not only exemplify black arsenic phosphorus as a promising candidate for MIR optoelectronic applications but also pave the way for a general strategy to suppress 1/f noise in photonic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 496, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700589", "DOI": "10.1126/sciadv.1700589", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406370700076", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FS; Hu, PY; Hu, FY; Tian, ZH; Tang, JW; Zhang, PG; Pan, L; Barsoum, MW; Cai, LZ; Sun, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fushuo; Hu, Peiying; Hu, Feiyue; Tian, Zhihua; Tang, Jingwen; Zhang, Peigen; Pan, Long; Barsoum, Michel W.; Cai, Longzhu; Sun, ZhengMing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional MXene/C Aerogels for Enhanced Microwave Absorption and Thermal Insulation", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal carbides and nitrides (MXene) have emerged as promising candidates for microwave absorption (MA) materials. However, they also have some drawbacks, such as poor impedance matching, high self- stacking tendency, and high density. To tackle these challenges, MXene nullosheets were incorporated into polyacrylonitrile (PAN) nullofibers and subsequently assembled into a three-dimensional (3D) network structure through PAN carbonization, yielding MXene/C aerogels. The 3D network effectively extends the path of microcurrent transmission, leading to enhanced conductive loss of electromagnetic (EM) waves. Moreover, the aerogel's rich pore structure significantly improves the impedance matching while effectively reducing the density of the MXenebased absorbers. EM parameter analysis shows that the MXene/C aerogels exhibit a minimum reflection loss ( RLmin) value of - 53.02 dB (f = 4.44 GHz, t = 3.8 mm), and an effective absorption bandwidth (EAB) of 5.3 GHz (t = 2.4 mm, 7.44-12.72 GHz). Radar cross-sectional (RCS) simulations were employed to assess the radar stealth effect of the aerogels, revealing that the maximum RCS reduction value of the perfect electric conductor covered by the MXene/C aerogel reaches 12.02 dB m(2). In addition to the MA performance, the MXene/C aerogel also demonstrates good thermal insulation performance, and a 5- mm-thick aerogel can generate a temperature gradient of over 30 degrees C at 82 degrees C. This study provides a feasible design approach for creating lightweight, efficient, and multifunctional MXene-based MA materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 194, "DOI": "10.1007/s40820-023-01158-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01158-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001044788300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dimiev, AM; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dimiev, Ayrat M.; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of Graphene Oxide Formation", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite intensive research, the mechanism of graphene oxide (GO) formation remains unclear. The role of interfacial interactions between solid graphite and the liquid reaction medium, and transport of the oxidizing agent into the graphite, has not been well-addressed. In this work, we show that formation of GO from graphite constitutes three distinct independent steps. The reaction can be stopped at each step, and the corresponding intermediate products can be isolated, characterized, and stored under appropriate conditions. The first step is conversion of graphite into a stage-1 graphite intercalation compound (GIC). The second step is conversion of the stage-1 GIC into oxidized graphite, which we define as pristine graphite oxide (PGO). This step involves diffusion of the oxidizing agent into the preoccupied graphite galleries. This rate-determining step makes the entire process diffusive-controlled. The third step is conversion of PGO into conventional GO after exposure to water, which involves hydrolysis of covalent sulfates and loss of all interlayer registry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 721, "Times Cited, All Databases": 764, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3060, "End Page": 3068, "Article Number": null, "DOI": "10.1021/nn500606a", "DOI Link": "http://dx.doi.org/10.1021/nn500606a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333539400126", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Hu, XY; Liu, EZ; Fan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bin; Hu, Xiaoyun; Liu, Enzhou; Fan, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel S-scheme 2D/2D BiOBr/g-C3N4 heterojunctions with enhanced photocatalytic activity", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and construction of heterojunction photocatalysts, which possess a staggered energy band structure and appropriate interfacial contact, is an effective way to achieve outstanding photocatalytic performance. In this study, 2D/2D BiOBr/g-C3N4 heterojunctions were successfully obtained by a convenient in situ self-assembly route. Under simulated sunlight irradiation, 99% of RhB (10 mg.L-1, 100 mL) was efficiently degraded by 1.5-BiOBr/g-C3N4 within 30 min, which is better than the performance of both BiOBr and g-C3N4, and it has superior stability. In addition, the composite also exhibits enhanced photocatalytic activity for H-2 production. The enhanced activity can be attributed to the intimate interface contact, the larger surface area, and the highly efficient separation of photoinduced electron-hole pairs. Based on the experimental results, a novel S-scheme model was proposed to illuminate the transfer process of charge carriers. This study presents a simple way to develop novel step-scheme photocatalysts for environmental and related applications. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 42, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1519, "End Page": 1529, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63765-2", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63765-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649097900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "El-Atwani, O; Li, N; Li, M; Devaraj, A; Baldwin, JKS; Schneider, MM; Sobieraj, D; Wróbel, JS; Nguyen-Manh, D; Maloy, SA; Martinez, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "El-Atwani, O.; Li, N.; Li, M.; Devaraj, A.; Baldwin, J. K. S.; Schneider, M. M.; Sobieraj, D.; Wrobel, J. S.; Nguyen-Manh, D.; Maloy, S. A.; Martinez, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Outstanding radiation resistance of tungsten-based high-entropy alloys", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A body-centered cubic W-based refractory high entropy alloy with outstanding radiation resistance has been developed. The alloy was grown as thin films showing a bimodal grain size distribution in the nullocrystalline and ultrafine regimes and a unique 4-nm lamella-like structure revealed by atom probe tomography (APT). Transmission electron microscopy (TEM) and x-ray diffraction show certain black spots appearing after thermal annealing at elevated temperatures. TEM and APT analysis correlated the black spots with second-phase particles rich in Cr and V. No sign of irradiation-created dislocation loops, even after 8 dpa, was observed. Furthermore, nullomechanical testing shows a large hardness of 14 GPa in the as-deposited samples, with near negligible irradiation hardening. Theoretical modeling combining ab initio and Monte Carlo techniques predicts the formation of Cr- and V-rich second-phase particles and points at equal mobilities of point defects as the origin of the exceptional radiation tolerance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav2002", "DOI": "10.1126/sciadv.aav2002", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav2002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462564300053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, WF; Qu, ZB; Kumar, P; Vecchio, D; Wang, YF; Ma, Y; Bahng, JH; Bernardino, K; Gomes, WR; Colombari, FM; Lozada-Blanco, A; Veksler, M; Marino, E; Simon, A; Murray, C; Muniz, SR; de Moura, AF; Kotov, NA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Wenfeng; Qu, Zhi-bei; Kumar, Prashant; Vecchio, Drew; Wang, Yuefei; Ma, Yu; Bahng, Joong Hwan; Bernardino, Kalil; Gomes, Weverson R.; Colombari, Felippe M.; Lozada-Blanco, Asdrubal; Veksler, Michael; Marino, Emanuele; Simon, Alex; Murray, Christopher; Muniz, Sergio Ricardo; de Moura, Andr F.; Kotov, Nicholas A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergence of complexity inhierarchically organized chiral particles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The structural complexity of composite biomaterials and biomineralized particles arises from the hierarchical ordering of inorganic building blocks over multiple scales. Although empirical observations of complex nulloassemblies are abundant, the physicochemical mechanisms leading to their geometrical complexity are still puzzling, especially for nonuniformly sized components. We report the self-assembly of hierarchically organized particles (HOPs) from polydisperse gold thiolate nulloplatelets with cysteine surface ligands. Graph theory methods indicate that these HOPs, which feature twisted spikes and other morphologies, display higher complexity than their biological counterparts. Their intricate organization emerges from competing chirality-dependent assembly restrictions that render assembly pathways primarily dependent on nulloparticle symmetry rather than size. These findings and HOP phase diagrams open a pathway to a large family of colloids with complex architectures and unusual chiroptical and chemical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2020, "Volume": 368, "Issue": 6491, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 642, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz7949", "DOI Link": "http://dx.doi.org/10.1126/science.aaz7949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531182900054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LH; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Lu Hua; Chen, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Thin Boron Nitride: Unique Properties and Applications", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin boron nitride (BN) is an important 2D nullomaterial, with many properties distinct from graphene. In this feature article, these unique properties and associated applications, often not feasible with graphene, are outlined. The article starts with characterization and identification of atomically thin BN. It is followed by demonstrating their strong oxidation resistance at high temperatures and applications in protecting metals from oxidation and corrosion. As flat insulators, BN nullosheets are ideal dielectric substrates for surface enhanced Raman spectroscopy (SERS) and electronic devices based on 2D heterostructures. The light emission of BN nullosheets in the deep ultraviolet (DUV) and ultraviolet (UV) regions is also included for its scientific and technological importance. The last part is dedicated to synthesis, characterization, and optical properties of BN nulloribbons, a special form of nullosheets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2016, "Volume": 26, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2594, "End Page": 2608, "Article Number": null, "DOI": "10.1002/adfm.201504606", "DOI Link": "http://dx.doi.org/10.1002/adfm.201504606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375125300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZX; Yang, J; Zhang, T; Nuli, YN; Wang, JL; Hirano, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zhixin; Yang, Jun; Zhang, Tao; Nuli, Yanna; Wang, Jiulin; Hirano, Shin-ichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silicon Microparticle Anodes with Self-Healing Multiple Network Binder", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Si has been regarded as a promising anode material for Li-ion batteries. However, its dramatic volume change during cycling poses formidable challenges to building stable electrodes. Since Si microparticles (SiMPs) can easily cause the pulverization and loss of electronic contact, many previous works were focused on porous-structured, nullostructured, or hierarchically structured silicon materials to improve the cycle stability. However, their low-cost and mass production is mostly difficult or even impossible. Herein, a water-soluble polymer binder, poly(acrylic acid)-poly(2-hydroxyethyl acrylate-co-dopamine methacrylate), is designed and synthesized. It shows better wettability to liquid electrolyte than poly(acrylic acid). Moreover, its multiple network structure with rigid-soft chains and bonds, and special self-healing capability in situ formed during the electrode preparation, not only provides enough mechanical support but also buffers the strain caused by the volume change of SiMPs. Thus, the cycle stability and rate performance are remarkably improved under high reversible capacity or electrode loading.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 950, "End Page": 961, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, JR; Yang, XX; Gao, GY; Xiong, Y; Wang, YF; Han, J; Chen, YH; Zhang, H; Sun, QJ; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Jinran; Yang, Xixi; Gao, Guoyun; Xiong, Yao; Wang, Yifei; Han, Jing; Chen, Youhui; Zhang, Huai; Sun, Qijun; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired mechano-photonic artificial synapse based on graphene/MoS2 heterostructure", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing multifunctional and diversified artificial neural systems to integrate multimodal plasticity, memory, and supervised learning functions is an important task toward the emulation of neuromorphic computation. Here, we present a bioinspired mechano-photonic artificial synapse with synergistic mechanical and optical plasticity. The artificial synapse is composed of an optoelectronic transistor based on graphene/MoS2 heterostructure and an integrated triboelectric nullogenerator. By controlling the charge transfer/exchange in the heterostructure with triboelectric potential, the optoelectronic synaptic behaviors can be readily modulated, including postsynaptic photocurrents, persistent photoconductivity, and photosensitivity. The photonic synaptic plasticity is elaborately investigated under the synergistic effect of mechanical displacement and the light pulses embodying different spatiotemporal information. Furthermore, artificial neural networks are simulated to demonstrate the improved image recognition accuracy up to 92% assisted with mechanical plasticization. The mechano-photonic artificial synapse is highly promising for implementing mixed-modal interaction, emulating complex biological nervous system, and promoting the development of interactive artificial intelligence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabd9117", "DOI": "10.1126/sciadv.abd9117", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abd9117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000633443000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DQ; Shi, MJ; Zhu, TS; Xing, DY; Zhang, HJ; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dongqin; Shi, Minji; Zhu, Tongshuai; Xing, Dingyu; Zhang, Haijun; Wang, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Axion States in the Magnetic Insulator MnBi2Te4 with the Quantized Magnetoelectric Effect", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological states of quantum matter have attracted great attention in condensed matter physics and materials science. The study of time-reversal-invariant topological states in quantum materials has made tremendous progress. However, the study of magnetic topological states falls much behind due to the complex magnetic structures. Here, we predict the tetradymite-type compound MnBi2Te4 and its related materials host topologically nontrivial magnetic states. The magnetic ground state of MnBi2Te4 is an antiferromagetic topological insulator state with a large topologically nontrivial energy gap (similar to 0.2 eV). It presents the axion state, which has gapped bulk and surface states, and the quantized topological magnetoelectric effect. The ferromagnetic phase of MnBi2Te4 might lead to a minimal ideal Weyl semimetal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 672, "Times Cited, All Databases": 743, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2019, "Volume": 122, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 206401, "DOI": "10.1103/PhysRevLett.122.206401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.206401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469032700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Steele, JA; Jin, HD; Dovgaliuk, I; Berger, RF; Braeckevelt, T; Yuan, HF; Martin, C; Solano, E; Lejaeghere, K; Rogge, SMJ; Notebaert, C; Vandezande, W; Janssen, KPF; Goderis, B; Debroye, E; Wang, YK; Dong, YT; Ma, DX; Saidaminov, M; Tan, HR; Lu, ZH; Dyadkin, V; Chernyshov, D; Van Speybroeck, V; Sargent, EH; Hofkens, J; Roeffaers, MBJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Steele, Julian A.; Jin, Handong; Dovgaliuk, Iurii; Berger, Robert F.; Braeckevelt, Tom; Yuan, Haifeng; Martin, Cristina; Solano, Eduardo; Lejaeghere, Kurt; Rogge, Sven M. J.; Notebaert, Charlotte; Vandezande, Wouter; Janssen, Kris P. F.; Goderis, Bart; Debroye, Elke; Wang, Ya-Kun; Dong, Yitong; Ma, Dongxin; Saidaminov, Makhsud; Tan, Hairen; Lu, Zhenghong; Dyadkin, Vadim; Chernyshov, Dmitry; Van Speybroeck, Veronique; Sargent, Edward H.; Hofkens, Johan; Roeffaers, Maarten B. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal unequilibrium of strained black CsPbI3 thin films", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high-temperature, all-inorganic CsPbI3 perovskite black phase is metastable relative to its yellow, nonperovskite phase at room temperature. Because only the black phase is optically active, this represents an impediment for the use of CsPbI3 in optoelectronic devices. We report the use of substrate clamping and biaxial strain to render black-phase CsPbI3 thin films stable at room temperature. We used synchrotron-based, grazing incidence, wide-angle x-ray scattering to track the introduction of crystal distortions and strain-driven texture formation within black CsPbI3 thin films when they were cooled after annealing at 330 degrees C. The thermal stability of black CsPbI3 thin films is vastly improved by the strained interface, a response verified by ab initio thermodynamic modeling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2019, "Volume": 365, "Issue": 6454, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 679, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax3878", "DOI Link": "http://dx.doi.org/10.1126/science.aax3878", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481688700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palummo, M; Bernardi, M; Grossman, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palummo, Maurizia; Bernardi, Marco; Grossman, Jeffrey C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton Radiative Lifetimes in Two-Dimensional Transition Metal Dichalcogenides", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light emission in two-dimensional (2D) transition metal dichalcogenides (TMDs) changes significantly with the number of layers and stacking sequence. While the electronic structure and optical absorption are well understood in 2D-TMDs, much less is known about exciton dynamics and radiative recombination. Here, we show first-principles calculations of intrinsic exciton radiative lifetimes at low temperature (4 K) and room temperature (300 K) in TMD monolayers with the chemical formula MX2 (X = Mo, W, and X = S, Se), as well as in bilayer and bulk MoS2 and in two MX2 heterobilayers. Our results elucidate the time scale and microscopic origin of light emission in TMDs. We find radiative lifetimes of a few picoseconds at low temperature and a few nulloseconds at room temperature in the monolayers and slower radiative recombination in bulk and bilayer than in monolayer MoS2. The MoS2/WS2 and MoSe2/WSe2 heterobilayers exhibit very long-lived (similar to 20-30 ns at room temperature) interlayer excitons constituted by electrons localized on the Mo-based and holes on the W-based monolayer. The wide radiative lifetime tunability, together with the ability shown here to predict radiative lifetimes from computations, hold unique potential to manipulate excitons in TMDs and their heterostructures for application in optoelectronics and solar energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 582, "Times Cited, All Databases": 662, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2794, "End Page": 2800, "Article Number": null, "DOI": "10.1021/nl503799t", "DOI Link": "http://dx.doi.org/10.1021/nl503799t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354906000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Wan, F; Huang, S; Wang, S; Niu, ZQ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yan; Wan, Fang; Huang, Shuo; Wang, Shuai; Niu, Zhiqiang; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A chemically self-charging aqueous zinc-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-charging power systems integrating energy harvesting technologies and batteries are attracting extensive attention in energy technologies. However, the conventional integrated systems are highly dependent on the availability of the energy sources and generally possess complicated configuration. Herein, we develop chemically self-charging aqueous zinc-ion batteries with a simplified two-electrode configuration based on CaV6O16?3H(2)O electrode. Such system possesses the capability of energy harvesting, conversion and storage simultaneously. It can be chemically self-recharged by the spontaneous redox reaction between the discharged cathode and oxygen from the ambient environment. Chemically self-recharged zinc-ion batteries display an initial open-circuit voltage of about 1.05V and a considerable discharge capacity of about 239mAhg(-1), indicating the excellent self-rechargeability. Impressively, such chemically self-charging zinc-ion batteries can also work well at chemical or/and galvanostatic charging hybrid modes. This work not only provides a route to design chemically self-charging energy storage, but also broadens the horizons of aqueous zinc-ion batteries. Self-charging power systems integrating energy generation and storage are receiving consideration attention. Here the authors report an aqueous Zn-ion battery that can be self-recharged by the spontaneous redox reaction between cathode and oxygen from ambient environment without external power supply.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2199, "DOI": "10.1038/s41467-020-16039-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16039-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533952200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, CX; Du, YP; Wu, HP; Xiang, HJ; Deng, KM; Kan, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Chengxi; Du, Yongping; Wu, Haiping; Xiang, Hongjun; Deng, Kaiming; Kan, Erjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of Intrinsic Ferromagnetic Ferroelectricity in a Transition-Metal Halide Monolayer", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The realization of multiferroics in nullostructures, combined with a large electric dipole and ferromagnetic ordering, could lead to new applications, such as high-density multistate data storage. Although multiferroics have been broadly studied for decades, ferromagnetic ferroelectricity is rarely explored, especially in two-dimensional (2D) systems. Here we report the discovery of 2D ferromagnetic ferroelectricity in layered transition-metal halide systems. On the basis of first-principles calculations, we reveal that a charged CrBr3 monolayer exhibits in-plane multiferroicity, which is ensured by the combination of orbital and charge ordering as realized by the asymmetric Jahn-Teller distortions of octahedral Cr-Br-6 units. As an example, we further show that (CrBr3)(2) Li is a ferromagnetic ferroelectric multiferroic. The explored phenomena and mechanism of multiferroics in this 2D system not only are useful for fundamental research in multiferroics but also enable a wide range of applications in nullodevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2018, "Volume": 120, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147601, "DOI": "10.1103/PhysRevLett.120.147601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.147601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428966400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cassabois, G; Valvin, P; Gil, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cassabois, G.; Valvin, P.; Gil, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hexagonal boron nitride is an indirect bandgap semiconductor", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride is a wide bandgap semiconductor with very high thermal and chemical stability that is used in devices operating under extreme conditions. The growth of high-purity crystals has recently revealed the potential of this material for deep ultraviolet emission, with intense emission around 215 nm. In the last few years, hexagonal boron nitride has been attracting even more attention with the emergence of two-dimensional atomic crystals and van der Waals heterostructures, initiated with the discovery of graphene. Despite this growing interest and a seemingly simple structure, the basic questions of the bandgap nature and value are still controversial. Here, we resolve this long-debated issue by demonstrating evidence for an indirect bandgap at 5.955 eV by means of optical spectroscopy. We demonstrate the existence of phonon-assisted optical transitions and we measure an exciton binding energy of about 130 meV by two-photon spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 262, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.277", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372978900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, QM; Liu, ZL; Yan, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Qiming; Liu, Zeliang; Yan, Jinhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning for metal additive manufacturing: predicting temperature and melt pool fluid dynamics using physics-informed neural networks", "Source Title": "COMPUTATIONAL MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent explosion of machine learning (ML) and artificial intelligence (AI) shows great potential in the breakthrough of metal additive manufacturing (AM) process modeling, which is an indispensable step to derive the process-structure-property relationship. However, the success of conventional machine learning tools in data science is primarily attributed to the unprecedented large amount of labeled data-sets (big data), which can be either obtained by experiments or first-principle simulations. Unfortunately, these labeled data-sets are expensive to obtain in AM due to the high expense of the AM experiments and prohibitive computational cost of high-fidelity simulations, hindering the direct applications of big-data based ML tools to metal AM problems. To fully exploit the power of machine learning for metal AM while alleviating the dependence on big data, we put forth a physics-informed neural network (PINN) framework that fuses both data and first physical principles, including conservation laws of momentum, mass, and energy, into the neural network to inform the learning processes. To the best knowledge of the authors, this is the first application of physics-informed deep learning to three dimensional AM processes modeling. Besides, we propose a hard-type approach for Dirichlet boundary conditions (BCs) based on a Heaviside function, which can not only exactly enforce the BCs but also accelerate the learning process. The PINN framework is applied to two representative metal manufacturing problems, including the 2018 NIST AM-Benchmark test series. We carefully assess the performance of the PINN model by comparing the predictions with available experimental data and high-fidelity simulation results, using finite element based variational multi-scale formulation method. The investigations show that the PINN, owed to the additional physical knowledge, can accurately predict the temperature and melt pool dynamics during metal AM processes with only a moderate amount of labeled data-sets. The foray of PINN to metal AM shows the great potential of physics-informed deep learning for broader applications to advanced manufacturing. All the data-sets and the PINN code will be made open-sourced in https://yan.cee.illinois.edu/ once the paper is published.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 67, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 619, "End Page": 635, "Article Number": null, "DOI": "10.1007/s00466-020-01952-9", "DOI Link": "http://dx.doi.org/10.1007/s00466-020-01952-9", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605530100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YS; Chen, CC; Scott, MC; Ophus, C; Xu, R; Pryor, A; Wu, L; Sun, F; Theis, W; Zhou, JH; Eisenbach, M; Kent, PRC; Sabirianov, RF; Zeng, H; Ercius, P; Miao, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yongsoo; Chen, Chien-Chun; Scott, M. C.; Ophus, Colin; Xu, Rui; Pryor, Alan, Jr.; Wu, Li; Sun, Fan; Theis, Wolfgang; Zhou, Jihan; Eisenbach, Markus; Kent, Paul R. C.; Sabirianov, Renat F.; Zeng, Hao; Ercius, Peter; Miao, Jianwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deciphering chemical order/disorder and material properties at the single-atom level", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perfect crystals are rare in nature. Real materials often contain crystal defects and chemical order/disorder such as grain boundaries, dislocations, interfaces, surface reconstructions and point defects(1-3). Such disruption in periodicity strongly affects material properties and functionality(1-3). Despite rapid development of quantitative material characterization methods(1,4-18), correlating three-dimensional (3D) atomic arrangements of chemical order/disorder and crystal defects with material properties remains a challenge. On a parallel front, quantum mechanics calculations such as density functional theory (DFT) have progressed from the modelling of ideal bulk systems to modelling 'real' materials with dopants, dislocations, grain boundaries and interfaces(19,20); but these calculations rely heavily on average atomic models extracted from crystallography. To improve the predictive power of first-principles calculations, there is a pressing need to use atomic coordinates of real systems beyond average crystallographic measurements. Here we determine the 3D coordinates of 6,569 iron and 16,627 platinum atoms in an iron-platinum nulloparticle, and correlate chemical order/disorder and crystal defects with material properties at the single-atom level. We identify rich structural variety with unprecedented 3D detail including atomic composition, grain boundaries, anti-phase boundaries, anti-site point defects and swap defects. We show that the experimentally measured coordinates and chemical species with 22 picometre precision can be used as direct input for DFT calculations of material properties such as atomic spin and orbital magnetic moments and local magnetocrystalline anisotropy. This work combines 3D atomic structure determination of crystal defects with DFT calculations, which is expected to advance our understanding of structure-property relationships at the fundamental level.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2017, "Volume": 542, "Issue": 7639, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 75, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature21042", "DOI Link": "http://dx.doi.org/10.1038/nature21042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396119300034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, MR; Ju, J; Luo, SQ; Han, YC; Dong, ZC; Wang, YL; Gu, Z; Zhang, LJ; Hao, RR; Jiang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Meirong; Ju, Jie; Luo, Siqi; Han, Yuchun; Dong, Zhichao; Wang, Yilin; Gu, Zhen; Zhang, Lingjuan; Hao, Ruiran; Jiang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling liquid splash on superhydrophobic surfaces by a vesicle surfactant", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deposition of liquid droplets on solid surfaces is of great importance to many fundamental scientific principles and technological applications, such as spraying, coating, and printing. For example, during the process of pesticide spraying, more than 50% of agrochemicals are lost because of the undesired bouncing and splashing behaviors on hydrophobic or superhydrophobic leaves. We show that this kind of splashing on superhydrophobic surfaces can be greatly inhibited by adding a small amount of a vesicular surfactant, Aerosol OT. Rather than reducing splashing by increasing the viscosity via polymer additives, the vesicular surfactant confines the motion of liquid with the help of wettability transition and thus inhibits the splash. Significantly, the vesicular surfactant exhibits a distinguished ability to alter the surface wettability during the first inertial spreading stage of similar to 2 ms because of its dense aggregates at the air/water interface. A comprehensive model proposed by this idea could help in understanding the complex interfacial interactions at the solid/liquid/air interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602188", "DOI": "10.1126/sciadv.1602188", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602188", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397044000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, BB; Pang, X; Li, SN; Wu, H; Shen, JL; Wang, XY; Fan, CY; Cao, L; Zhu, TH; Qiu, M; Yin, ZY; Kong, Y; Liu, YQ; Zhang, MZ; Liu, YW; Pan, F; Jiang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Benbing; Pang, Xiao; Li, Shunning; Wu, Hong; Shen, Jianliang; Wang, Xiaoyao; Fan, Chunyang; Cao, Li; Zhu, Tianhao; Qiu, Ming; Yin, Zhuoyu; Kong, Yan; Liu, Yiqin; Zhang, Mingzheng; Liu, Yawei; Pan, Feng; Jiang, Zhongyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The idea of spatial confinement has gained widespread interest in myriad applications. Especially, the confined short hydrogen-bond (SHB) network could afford an attractive opportunity to enable proton transfer in a nearly barrierless manner, but its practical implementation has been challenging. Herein, we report a SHB network confined on the surface of ionic covalent organic framework (COF) membranes decorated by densely and uniformly distributed hydrophilic ligands. Combined experimental and theoretical evidences have pointed to the confinement of water molecules allocated to each ligand, achieving the local enrichment of hydronium ions and the concomitant formation of SHBs in water-hydronium domains. These overlapped water-hydronium domains create an interconnected SHB network, which yields an unprecedented ultrahigh proton conductivity of 1389 mS cm(-1) at 90 degrees C, 100% relative humidity. When hydronium ions are enriched in confined water, short hydrogen bonds (SHBs) form due to the constrained space of excess protons between pairs of water molecules. Here authors demonstrate a SHB network confined on the surface of ionic COF membranes with tunable -SO3H groups, with proton conductivity of 1389 mS cm(-1) at 90 C-o.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6666, "DOI": "10.1038/s41467-022-33868-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33868-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000879737500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, S; Yang, C; Zhang, WB; Xu, JS; Liu, LM; Wu, DQ; Wang, XC; Han, Y; Liang, QF; Zhang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Shuai; Yang, Can; Zhang, Wenbei; Xu, Junsong; Liu, Lingmei; Wu, Dongqing; Wang, Xinchen; Han, Yu; Liang, Qifeng; Zhang, Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional semiconducting covalent organic frameworks via condensation at arylmethyl carbon atoms", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of organic semiconducting materials with in-plane it-conjugated structures and robustness through carbon-carbon bond linkages, alternatively as organic graphene analogs, is extremely desired for powerfully optoelectrical conversion. However, the poor reversibility for sp(2) carbon bond forming reactions makes them unavailable for building high crystalline well-defined organic structures through a self-healing process, such as covalent organic frameworks (COFs). Here we report a scalable solution-processing approach to synthesize a family of two-dimensional (2D) COFs with trans-disubstituted C = C linkages via condensation reaction at arylmethyl carbon atoms on the basis of 3,5-dicyano-2,4,6-trimethylpyridine and linear/trigonal aldehyde (i.e., 4,4 ''-diformyl-p-terphenyl, 4,4'-diformyl-1,1'-biphenyl, or 1,3,5-tris(4-formylphenyl)benzene) monomers. Such sp(2) carbon-jointedpyridinyl frameworks, featuring crystalline honeycomb-like structures with high surface areas, enable driving two half-reactions of water splitting separately under visible light irradiation, comparable to graphitic carbon nitride (g-C3N4) derivatives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2467, "DOI": "10.1038/s41467-019-10504-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10504-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470248000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XR; Yuan, YF; Liu, J; Liu, B; Chen, X; Ding, J; Han, XP; Deng, YD; Zhong, C; Hu, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaorui; Yuan, Yifei; Liu, Jie; Liu, Bin; Chen, Xu; Ding, Jia; Han, Xiaopeng; Deng, Yida; Zhong, Cheng; Hu, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Utilizing solar energy to improve the oxygen evolution reaction kinetics in zinc-air battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Directly harvesting solar energy for battery charging represents an ultimate solution toward low-cost, green, efficient and sustainable electrochemical energy storage. Here, we design a sunlight promotion strategy into rechargeable zinc-air battery with significantly reduced charging potential below the theoretical cell voltage of zinc-air batteries. The sunlight-promoted zinc-air battery using BiVO4 or alpha-Fe2O3 air photoelectrode achieves a record-low charge potential of similar to 1.20 and similar to 1.43 V, respectively, under illumination, which is lowered by similar to 0.5-0.8 V compared to the typical charge voltage of similar to 2 V in conventional zinc-air battery. The band structure and photoelectrochemical stability of photoelectrodes are found to be key factors determining the charging performance of sunlight-promoted zinc-air batteries. The introduction of photoelectrode as an air electrode opens a facile way for developing integrated single-unit zinc-air batteries that can efficiently use solar energy to overcome the high charging overpotential of conventional zinc-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4767, "DOI": "10.1038/s41467-019-12627-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12627-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490982100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Wu, CS; Dai, YJ; Zhao, ZH; Wang, A; Zhang, TJ; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jie; Wu, Changsheng; Dai, Yejing; Zhao, Zhihao; Wang, Aurelia; Zhang, Tiejun; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving ultrahigh triboelectric charge density for efficient energy harvesting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With its light weight, low cost and high efficiency even at low operation frequency, the triboelectric nullogenerator is considered a potential solution for self-powered sensor networks and large-scale renewable blue energy. As an energy harvester, its output power density and efficiency are dictated by the triboelectric charge density. Here we report a method for increasing the triboelectric charge density by coupling surface polarization from triboelectrification and hysteretic dielectric polarization from ferroelectric material in vacuum (P similar to 10(-6) torr). Without the constraint of air breakdown, a triboelectric charge density of 1003 mu C m(-2), which is close to the limit of dielectric breakdown, is attained. Our findings establish an optimization methodology for triboelectric nullogenerators and enable their more promising usage in applications ranging from powering electronic devices to harvesting large-scale blue energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 88, "DOI": "10.1038/s41467-017-00131-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00131-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405900400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, MX; Pan, Y; Yuan, FP; Zhu, YT; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Muxin; Pan, Yue; Yuan, Fuping; Zhu, Yuntian; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Back stress strengthening and strain hardening in gradient structure", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report significant back stress strengthening and strain hardening in gradient structured (GS) interstitial-free (IF) steel. Back stress is long-range stress caused by the pileup of geometrically necessary dislocations (GNDs). A simple equation and a procedure are developed to calculate back stress basing on its formation physics from the tensile unloading-reloading hysteresis loop. The gradient structure has mechanical incompatibility due to its grain size gradient. This induces strain gradient, which needs to be accommodated by GNDs. Back stress not only raises the yield strength but also significantly enhances strain hardening to increase the ductility. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1013, "Times Cited, All Databases": 1054, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 145, "End Page": 151, "Article Number": null, "DOI": "10.1080/21663831.2016.1153004", "DOI Link": "http://dx.doi.org/10.1080/21663831.2016.1153004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385011000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, J; Sarmah, SP; Murali, B; Dursun, I; Peng, W; Parida, MR; Liu, J; Sinatra, L; Alyami, N; Zhao, C; Alarousu, E; Ng, TK; Ooi, BS; Bakr, OM; Mohammed, OF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Jun; Sarmah, Smritakshi P.; Murali, Banavoth; Dursun, Ibrahim; Peng, Wei; Parida, Manas R.; Liu, Jiakai; Sinatra, Lutfan; Alyami, Noktan; Zhao, Chao; Alarousu, Erkki; Ng, Tien Khee; Ooi, Boon S.; Bakr, Osman M.; Mohammed, Omar F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air-Stable Surface-Passivated Perovskite Quantum Dots for Ultra-Robust, Single- and Two-Photon-Induced Amplified Spontaneous Emission", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate ultra-air- and photostable CsPbBr3 quantum dots (gDs) by using an inorganic-organic hybrid ion pair as the capping ligand. This passivation approach to perovskite QDs yields high photoluminescence quantum yield with unprecedented operational stability in ambient conditions (60 +/- 5% lab humidity) and high pump fluences, thus overcoming one of the greatest challenges impeding the development of perovskite-based applications. Due to the robustness of passivated perovskite QDs, we were able to induce ultrastable amplified spontaneous emission (ASE) in solution processed QD films not only through one photon but also through two-photon absorption processes. The latter has not been observed before in the family of perovskite materials. More importantly, passivated perovskite QD films showed remarkable photostability under continuous pulsed laser excitation in ambient conditions for at least 34 h (corresponds to 1.2 x 10(8) laser shots), substantially exceeding the stability of other colloidal QD systems in which ASE has been observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 503, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2015, "Volume": 6, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5027, "End Page": 5033, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b02460", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b02460", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366886000026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, NB; Wang, WJ; Wang, QT; Ye, YX; Lin, SH; Zhang, L; Guo, QH; Brechtl, J; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Nengbin; Wang, Wenjie; Wang, Qianting; Ye, Youxiong; Lin, Sihan; Zhang, Lei; Guo, Qiaohang; Brechtl, Jamieson; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical, corrosion, and wear properties of biomedical Ti-Zr-Nb-Ta-Mo high entropy alloys", "Source Title": "JOURNAL OF ALLOYS AND COMPOUNDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The microstructures, mechanical, corrosion, and wear behaviors of the TixZrNbTaMo (x = 0.5,1,1.5, and 2, molar ratio) high entropy alloys (HEAs) were studied. It was found that the Ti-Zr-Nb-Ta-Mo HEAs showed a dendrite structure with two body-centered-cubic (BCC) solid solution phases. The Ti0.5ZrNb-TaMo HEA exhibited a high hardness of about 500 HV, high compressive strength approaching 2,600 MPa, and large plastic strain of over 30%. Furthermore, the highly-protective oxide films formed on the surface of Ti-Zr-Nb-Ta-Mo HEAs in the phosphate buffer saline (PBS) solution, which resulted in the high corrosion resistance of the HEAs. The Ti-Zr-Nb-Ta-Mo HEAs exhibited the greater dry- and wet-wear resistance than that of the traditional biomedical Ti6Al4V alloy. The results also indicated that with the decrease in the Ti content, the wear resistance of the Ti-Zr-Nb-Ta-Mo HEAs in the PBS solution improved. Finally, the Ti0.5ZrNbTaMo alloy presented the highest corrosive wear resistance among the four HEAs owing to its combination of good mechanical properties and high chemical stability. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2021, "Volume": 861, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 157997, "DOI": "10.1016/j.jallcom.2020.157997", "DOI Link": "http://dx.doi.org/10.1016/j.jallcom.2020.157997", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619199300058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Shan, WT; Zachman, MJ; Wang, MY; Hwang, S; Tabassum, H; Yang, J; Yang, XX; Karakalos, S; Feng, ZX; Wang, GF; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yi; Shan, Weitao; Zachman, Michael J.; Wang, Maoyu; Hwang, Sooyeon; Tabassum, Hassina; Yang, Juan; Yang, Xiaoxuan; Karakalos, Stavros; Feng, Zhenxing; Wang, Guofeng; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Dispersed Dual-Metal Site Catalysts for Enhanced CO2 Reduction: Mechanistic Insight into Active Site Structures", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-supported nitrogen-coordinated single-metal site catalysts (i.e., M-N-C, M: Fe, Co, or Ni) are active for the electrochemical CO2 reduction reaction (CO2RR) to CO. Further improving their intrinsic activity and selectivity by tuning their N-M bond structures and coordination is limited. Herein, we expand the coordination environments of M-N-C catalysts by designing dual-metal active sites. The Ni-Fe catalyst exhibited the most efficient CO2RR activity and promising stability compared to other combinations. Advanced structural characterization and theoretical prediction suggest that the most active N-coordinated dual-metal site configurations are 2N-bridged (Fe-Ni)N-6, in which FeN4 and NiN4 moieties are shared with two N atoms. Two metals (i.e., Fe and Ni) in the dual-metal site likely generate a synergy to enable more optimal *COOH adsorption and *CO desorption than single-metal sites (FeN4 or NiN4) with improved intrinsic catalytic activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2022, "Volume": 61, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202205632", "DOI": "10.1002/anie.202205632", "DOI Link": "http://dx.doi.org/10.1002/anie.202205632", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000792450300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, JW; Yang, Y; Xia, GL; Chen, JT; Jiang, P; Chen, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Jianwei; Yang, Yang; Xia, Guoliang; Chen, Jitang; Jiang, Peng; Chen, Qianwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ruthenium-cobalt nulloalloys encapsulated in nitrogen-doped graphene as active electrocatalysts for producing hydrogen in alkaline media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scalable production of hydrogen could conveniently be realized by alkaline water electrolysis. Currently, the major challenge confronting hydrogen evolution reaction ( HER) is lacking inexpensive alternatives to platinum-based electrocatalysts. Here we report a high-efficient and stable electrocatalyst composed of ruthenium and cobalt bimetallic nulloalloy encapsulated in nitrogen-doped graphene layers. The catalysts display remarkable performance with low overpotentials of only 28 and 218mV at 10 and 100 mA cm(-2), respectively, and excellent stability of 10,000 cycles. Ruthenium is the cheapest platinum-group metal and its amount in the catalyst is only 3.58 wt.%, showing the catalyst high activity at a very competitive price. Density functional theory calculations reveal that the introduction of ruthenium atoms into cobalt core can improve the efficiency of electron transfer from alloy core to graphene shell, beneficial for enhancing carbon-hydrogen bond, thereby lowing Delta G(H star) of HER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 748, "Times Cited, All Databases": 760, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14969, "DOI": "10.1038/ncomms14969", "DOI Link": "http://dx.doi.org/10.1038/ncomms14969", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400066500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HR; Jiang, Y; Ma, ZW; Shi, YQ; Zhu, YJ; Huang, RZ; Feng, YZ; Wang, ZB; Hong, M; Gao, JF; Tang, LC; Song, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hengrui; Jiang, Yue; Ma, Zhewen; Shi, Yongqian; Zhu, Yanjun; Huang, Ruizhe; Feng, Yuezhan; Wang, Zubin; Hong, Min; Gao, Jiefeng; Tang, Long-Cheng; Song, Pingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperelastic, Robust, Fire-Safe Multifunctional MXene Aerogels with Unprecedented Electromagnetic Interference Shielding Efficiency", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene aerogels have shown great potential for many important functional applications, in particular electromagnetic interference (EMI) shielding. However, it has been a grand challenge to create mechanically hyperelastic, air-stable, and durable MXene aerogels for enabling effective EMI protection at low concentrations due to the difficulties in achieving tailorable porous structures, excellent mechanical elasticity, and desired antioxidation capabilities of MXene in air. Here, a facile strategy for fabricating MXene composite aerogels by co-assembling MXene and cellulose nullofibers during freeze-drying followed by surface encapsulation with fire-retardant thermoplastic polyurethane (TPU) is reported. Because of the maximum utilization of pore structures of MXene, and conductive loss enhanced by multiple internal reflections, as-prepared aerogel with 3.14 wt% of MXene exhibits an exceptionally high EMI shielding effectiveness of 93.5 dB, and an ultra-high MXene utilization efficiency of 2977.71 dB g g-1, tripling the values in previous works. Owing to the presence of multiple hydrogen bonding and the TPU elastomer, the aerogel exhibits a hyperelastic feature with additional strength, excellent stability, superior durability, and high fire safety. This study provides a facile strategy for creating multifunctional aerogels with great potential for applications in EMI protection, wearable devices, thermal management, pressure sensing, and intelligent fire monitoring. Hyperelastic, robust, fire-safe multifunctional MXene aerogels with superior electromagnetic interference (EMI) shielding, thermal insulation, and air/moisture resistance are created by an encapsulation strategy. The MXene aerogel shows high EMI shielding effectiveness of 93.5 dB and ultra-high EMI utilization efficiency of MXene of 2977.71 dB g g-1, resulting from efficient utilization of pore structure and multiple internal reflections.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 33, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202306884", "DOI Link": "http://dx.doi.org/10.1002/adfm.202306884", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058729100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Milot, RL; Eperon, GE; Snaith, HJ; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J.; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-Dependent Charge-Carrier Dynamics in CH3NH3PbI3 Perovskite Thin Films", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photoluminescence, transmittance, charge-carrier recombination dynamics, mobility, and diffusion length of CH3NH3PbI3 are investigated in the temperature range from 8 to 370 K. Profound changes in the optoelectronic properties of this prototypical photovoltaic material are observed across the two structural phase transitions occurring at 160 and 310 K. Drude-like terahertz photoconductivity spectra at all temperatures above 80 K suggest that charge localization effects are absent in this range. The monomolecular charge-carrier recombination rate generally increases with rising temperature, indicating a mechanism dominated by ionized impurity mediated recombination. Deduced activation energies E-a associated with ionization are found to increase markedly from the room-temperature tetragonal (E-a approximate to 20 meV) to the higher-temperature cubic (E-a approximate to 200 meV) phase adopted above 310 K. Conversely, the bimolecular rate constant decreases with rising temperature as charge-carrier mobility declines, while the Auger rate constant is highly phase specific, suggesting a strong dependence on electronic band structure. The charge-carrier diffusion length gradually decreases with rising temperature from about 3 m at -93 degrees C to 1.2 m at 67 degrees C but remains well above the optical absorption depth in the visible spectrum. These results demonstrate that there are no fundamental obstacles to the operation of cells based on CH3NH3PbI3 under typical field conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 805, "Times Cited, All Databases": 880, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2015, "Volume": 25, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6218, "End Page": 6227, "Article Number": null, "DOI": "10.1002/adfm.201502340", "DOI Link": "http://dx.doi.org/10.1002/adfm.201502340", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363207000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parida, K; Thangavel, G; Cai, GF; Zhou, XR; Park, S; Xiong, JQ; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parida, Kaushik; Thangavel, Gurunathan; Cai, Guofa; Zhou, Xinran; Park, Sangbaek; Xiong, Jiaqing; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely stretchable and self-healing conductor based on thermoplastic elastomer for all-three-dimensional printed triboelectric nullogenerator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in next-generation soft electronic devices rely on the development of highly deformable, healable, and printable energy generators to power these electronics. Development of deformable or wearable energy generators that can simultaneously attain extreme stretchability with superior healability remains a daunting challenge. We address this issue by developing a highly conductive, extremely stretchable, and healable composite based on thermoplastic elastomer with liquid metal and silver flakes as the stretchable conductor for triboelectric nullogenerators. The elastomer is used both as the matrix for the conductor and as the triboelectric layer. The nullogenerator showed a stretchability of 2500% and it recovered its energy-harvesting performance after extreme mechanical damage, due to the supramolecular hydrogen bonding of the thermoplastic elastomer. The composite of the thermoplastic elastomer, liquid metal particles, and silver flakes exhibited an initial conductivity of 6250 S cm(-1) and recovered 96.0% of its conductivity after healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2158, "DOI": "10.1038/s41467-019-10061-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10061-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467836900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XM; Zhang, SL; Kulinich, SA; Liu, YL; Zeng, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaoming; Zhang, Shengli; Kulinich, Sergei A.; Liu, Yanli; Zeng, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering surface states of carbon dots to achieve controllable luminescence for solid-luminescent composites and sensitive Be2+ detection", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Luminescent carbon dots (L-CDs) with high quantum yield value (44.7%) and controllable emission wavelengths were prepared via a facile hydrothermal method. Importantly, the surface states of the materials could be engineered so that their photoluminescence was either excitation-dependent or distinctly independent. This was achieved by changing the density of amino-groups on the L-CD surface. The above materials were successfully used to prepare multicolor L-CDs/polymer composites, which exhibited blue, green, and even white luminescence. In addition, the excellent excitation-independent luminescence of L-CDs prepared at low temperature was tested for detecting various metal ions. As an example, the detection limit of toxic Be2+ ions, tested for the first time, was as low as 23 mu M.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 672, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4976, "DOI": "10.1038/srep04976", "DOI Link": "http://dx.doi.org/10.1038/srep04976", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335886800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SR; Zhou, ZJ; Tie, ZX; Wang, B; Ye, M; Du, L; Cui, R; Liu, W; Wan, CH; Liu, QY; Zhao, S; Wang, Q; Zhang, YH; Zhang, S; Zhang, HG; Du, Y; Wei, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Sirong; Zhou, Zijun; Tie, Zuoxiu; Wang, Bing; Ye, Meng; Du, Lei; Cui, Ran; Liu, Wei; Wan, Cuihong; Liu, Quanyi; Zhao, Sheng; Wang, Quan; Zhang, Yihong; Zhang, Shuo; Zhang, Huigang; Du, Yan; Wei, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-informed discovery of hydrolytic nullozymes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullozyme is a collection of nullomaterials with enzyme-like activity but higher environmental tolerance and long-term stability than their natural counterparts. Improving the catalytic activity and expanding the category of nullozymes are prerequisites to complement or even supersede enzymes. However, the development of hydrolytic nullozymes is still challenged by diverse hydrolytic substrates and following complicated mechanisms. Here, two strategies are informed by data to screen and predict catalytic active sites of MOF (metal-organic framework) based hydrolytic nullozymes: (1) to increase the intrinsic activity by finely tuned Lewis acidity of the metal clusters; (2) to improve the density of active sites by shortening the length of ligands. Finally, as-obtained Ce-FMA-MOF-based hydrolytic nullozyme is capable of cleaving phosphate bonds, amide bonds, glycosidic bonds, and even their mixture, biofilms. This work provides a rational methodology to design hydrolytic nullozyme, enriches the diversity of nullozymes, and potentially sheds light on future evolution of enzyme engineering. Developing hydrolytic nullozymes remains challenging. Here the authors present a rational methodology to design hydrolytic nullozyme by developing a data-informed strategy to screen and identify potential scaffold and active sites of hydrolase-like nullozyme.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 827, "DOI": "10.1038/s41467-022-28344-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28344-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754315500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Liu, W; Zhao, XY; Xian, YF; Wu, W; Zhang, X; Zhao, NN; Xu, FJ; Wang, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jin; Liu, Wei; Zhao, Xiaoyi; Xian, Yifan; Wu, Wei; Zhang, Xiao; Zhao, nulla; Xu, Fu-Jian; Wang, Changyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural Melanin/Alginate Hydrogels Achieve Cardiac Repair through ROS Scavenging and Macrophage Polarization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficacy of cardiac regenerative strategies for myocardial infarction (MI) treatment is greatly limited by the cardiac microenvironment. The combination of reactive oxygen species (ROS) scavenging to suppress the oxidative stress damage and macrophage polarization to regenerative M2 phenotype in the MI microenvironment can be desirable for MI treatment. Herein, melanin nulloparticles (MNPs)/alginate (Alg) hydrogels composed of two marine-derived natural biomaterials, MNPs obtained from cuttlefish ink and alginate extracted from ocean algae, are proposed. Taking advantage of the antioxidant property of MNPs and mechanical support from injectable alginate hydrogels, the MNPs/Alg hydrogel is explored for cardiac repair by regulating the MI microenvironment. The MNPs/Alg hydrogel is found to eliminate ROS against oxidative stress injury of cardiomyocytes. More interestingly, the macrophage polarization to regenerative M2 macrophages can be greatly promoted in the presence of MNPs/Alg hydrogel. An MI rat model is utilized to evaluate the feasibility of the as-prepared MNPs/Alg hydrogel for cardiac repair in vivo. The antioxidant, anti-inflammatory, and proangiogenesis effects of the hydrogel are investigated in detail. The present study opens up a new way to utilize natural biomaterials for MI treatment and allows to rerecognize the great value of natural biomaterials in cardiac repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100505, "DOI": "10.1002/advs.202100505", "DOI Link": "http://dx.doi.org/10.1002/advs.202100505", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686387100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blum, AP; Kammeyer, JK; Rush, AM; Callmann, CE; Hahn, ME; Gianneschi, NC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blum, Angela P.; Kammeyer, Jacquelin K.; Rush, Anthony M.; Callmann, Cassandra E.; Hahn, Michael E.; Gianneschi, Nathan C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stimuli-Responsive nullomaterials for Biomedical Applications", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature employs a variety of tactics to precisely time and execute the processes and mechanics of life, relying on sequential sense and response cascades to transduce signaling events over multiple length and time scales. Many of these tactics, such as the activation of a zymogen, involve the direct manipulation of a material by a stimulus. Similarly, effective therapeutics and diagnostics require the selective and efficient homing of material to specific tissues and biomolecular targets with appropriate temporal resolution. These systems must also avoid undesirable or toxic side effects and evade unwanted removal by endogenous clearing mechanisms. nulloscale delivery vehicles have been developed to package materials with the hope of delivering them to select locations with rates of accumulation and clearance governed by an interplay between the carrier and its cargo. Many modern approaches to drug delivery have taken inspiration from natural activatable materials like zymogens, membrane proteins, and metabolites, whereby stimuli initiate transformations that are required for cargo release, prodrug activation, or selective transport. This Perspective describes key advances in the field of stimuli-responsive nullomaterials while highlighting some of the many challenges faced and opportunities for development. Major hurdles include the increasing need for powerful new tools and strategies for characterizing the dynamics, morphology, and behavior of advanced delivery systems in situ and the perennial problem of identifying truly specific and useful physical or molecular biomarkers that allow a material to autonomously distinguish diseased from normal tissue.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2015, "Volume": 137, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2140, "End Page": 2154, "Article Number": null, "DOI": "10.1021/ja510147n", "DOI Link": "http://dx.doi.org/10.1021/ja510147n", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349807000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamiya, K; Kamai, R; Hashimoto, K; Nakanishi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamiya, Kazuhide; Kamai, Ryo; Hashimoto, Kazuhito; Nakanishi, Shuji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum-modified covalent triazine frameworks hybridized with carbon nulloparticles as methanol-tolerant oxygen reduction electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent triazine frameworks, which are crosslinked porous polymers with two-dimensional molecular structures, are promising materials for heterogeneous catalysts. However, the application of the frameworks as electrocatalysts has not been achieved to date because of their poor electrical conductivity. Here we report that platinum-modified covalent triazine frameworks hybridized with conductive carbon nulloparticles are successfully synthesized by introducing carbon nulloparticles during the polymerization process of covalent triazine frameworks. The resulting materials exhibit clear electrocatalytic activity for oxygen reduction reactions in acidic solutions. More interestingly, the platinum-modified covalent triazine frameworks show almost no activity for methanol oxidation, in contrast to commercial carbon-supported platinum. Thus, platinum-modified covalent triazine frameworks hybridized with carbon nulloparticles exhibit selective activity for oxygen reduction reactions even in the presence of high concentrations of methanol, which indicates potential utility as a cathode catalyst in direct methanol fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5040, "DOI": "10.1038/ncomms6040", "DOI Link": "http://dx.doi.org/10.1038/ncomms6040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343028600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fabbri, E; Habereder, A; Waltar, K; Kötz, R; Schmidt, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fabbri, E.; Habereder, A.; Waltar, K.; Koetz, R.; Schmidt, T. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction", "Source Title": "CATALYSIS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growing need to store large amounts of energy produced from renewable sources has recently directed substantial R&D efforts towards water electrolysis technologies. Although the description of the electrochemical reaction of water electrolysis dates back to the late 18th century, improvements in terms of efficiency and stability are foreseen for a widespread market penetration of water electrolysers. Particular advances are required for the electrode materials catalysing the oxygen evolution reaction (OER) at the anode side, which has slow kinetics and thus is one of the major sources of the cell efficiency loss. In recent years, high-level theoretical tools and computational studies have led to significant progress in the atomic-level understanding of the OER and electrocatalyst behaviour. In parallel, several experimental studies have explored new catalytic materials with advanced properties and kinetics on a technical relevant level. This contribution summarises previous and the most recent theoretical predictions and experimental outcomes in the field of oxide-based catalysts for the OER, both operating in acidic and alkaline environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1082, "Times Cited, All Databases": 1169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3800, "End Page": 3821, "Article Number": null, "DOI": "10.1039/c4cy00669k", "DOI Link": "http://dx.doi.org/10.1039/c4cy00669k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343004900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huebsch, N; Lippens, E; Lee, K; Mehta, M; Koshy, ST; Darnell, MC; Desai, RM; Madl, CM; Xu, M; Zhao, XH; Chaudhuri, O; Verbeke, C; Kim, WS; Alim, K; Mammoto, A; Ingber, DE; Duda, GN; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huebsch, Nathaniel; Lippens, Evi; Lee, Kangwon; Mehta, Manav; Koshy, Sandeep T.; Darnell, Max C.; Desai, Rajiv M.; Madl, Christopher M.; Xu, Maria; Zhao, Xuanhe; Chaudhuri, Ovijit; Verbeke, Catia; Kim, Woo Seob; Alim, Karen; Mammoto, Akiko; Ingber, Donald E.; Duda, Georg N.; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Matrix elasticity of void-forming hydrogels controls transplanted-stem-cell-mediated bone formation", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The effectiveness of stem cell therapies has been hampered by cell death and limited control over fate. These problems can be partially circumvented by using macroporous biomaterials that improve the survival of transplanted stem cells and provide molecular cues to direct cell phenotype. Stem cell behaviour can also be controlled in vitro by manipulating the elasticity of both porous and non-porous materials, yet translation to therapeutic processes in vivo remains elusive. Here, by developing injectable, void-forming hydrogels that decouple pore formation from elasticity, we show that mesenchymal stem cell (MSC) osteogenesis in vitro, and cell deployment in vitro and in vivo, can be controlled by modifying, respectively, the hydrogel's elastic modulus or its chemistry. When the hydrogels were used to transplant MSCs, the hydrogel's elasticity regulated bone regeneration, with optimal bone formation at 60 kPa. Our findings show that biophysical cues can be harnessed to direct therapeutic stem cell behaviours in situ.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 14, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1269, "End Page": 1277, "Article Number": null, "DOI": "10.1038/NMAT4407", "DOI Link": "http://dx.doi.org/10.1038/NMAT4407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365839000025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Z; Amani, M; Najmaei, S; Xu, Q; Zou, XL; Zhou, W; Yu, T; Qiu, CY; Birdwell, AG; Crowne, FJ; Vajtai, R; Yakobson, BI; Xia, ZH; Dubey, M; Ajayan, PM; Lou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zheng; Amani, Matin; Najmaei, Sina; Xu, Quan; Zou, Xiaolong; Zhou, Wu; Yu, Ting; Qiu, Caiyu; Birdwell, A. Glen; Crowne, Frank J.; Vajtai, Robert; Yakobson, Boris I.; Xia, Zhenhai; Dubey, Madan; Ajayan, Pulickel M.; Lou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain and structure heterogeneity in MoS2 atomic layers grown by chemical vapour deposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer molybdenum disulfide (MoS2) has attracted tremendous attention due to its promising applications in high-performance field-effect transistors, phototransistors, spintronic devices and nonlinear optics. The enhanced photoluminescence effect in monolayer MoS2 was discovered and, as a strong tool, was employed for strain and defect analysis in MoS2. Recently, large-size monolayer MoS2 has been produced by chemical vapour deposition, but has not yet been fully explored. Here we systematically characterize chemical vapour deposition-grown MoS2 by photoluminescence spectroscopy and mapping and demonstrate non-uniform strain in single-crystalline monolayer MoS2 and strain-induced bandgap engineering. We also evaluate the effective strain transferred from polymer substrates to MoS2 by three-dimensional finite element analysis. Furthermore, our work demonstrates that photoluminescence mapping can be used as a non-contact approach for quick identification of grain boundaries in MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 585, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5246, "DOI": "10.1038/ncomms6246", "DOI Link": "http://dx.doi.org/10.1038/ncomms6246", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345653500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Zheng, XJ; Ouchi, T; Kouznetsova, TB; Beech, HK; Av-Ron, S; Matsuda, T; Bowser, BH; Wang, S; Johnson, JA; Kalow, JA; Olsen, BD; Gong, JP; Rubinstein, M; Craig, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zi; Zheng, Xujun; Ouchi, Tetsu; Kouznetsova, Tatiana B.; Beech, Haley K.; Av-Ron, Sarah; Matsuda, Takahiro; Bowser, Brandon H.; Wang, Shu; Johnson, Jeremiah A.; Kalow, Julia A.; Olsen, Bradley D.; Gong, Jian Ping; Rubinstein, Michael; Craig, Stephen L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The utility and lifetime of materials made from polymer networks, including hydrogels, depend on their capacity to stretch and resist tearing. In gels and elastomers, those mechanical properties are often limited by the covalent chemical structure of the polymer strands between cross-links, which is typically fixed during the material synthesis. We report polymer networks in which the constituent strands lengthen through force-coupled reactions that are triggered as the strands reach their nominal breaking point. In comparison with networks made from analogous control strands, reactive strand extensions of up to 40% lead to hydrogels that stretch 40 to 50% further and exhibit tear energies that are twice as large. The enhancements are synergistic with those provided by double-network architectures and complement other existing toughening strategies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2021, "Volume": 374, "Issue": 6564, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg2689", "DOI Link": "http://dx.doi.org/10.1126/science.abg2689", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000704920400043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Hippalgaonkar, K; Yang, F; Hong, JW; Ko, C; Suh, J; Liu, K; Wang, K; Urban, JJ; Zhang, X; Dames, C; Hartnoll, SA; Delaire, O; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sangwook, Lee; Hippalgaonkar, Kedar; Yang, Fan; Hong, Jiawang; Ko, Changhyun; Suh, Joonki; Liu, Kai; Wang, Kevin; Urban, Jeffrey J.; Zhang, Xiang; Dames, Chris; Hartnoll, Sean A.; Delaire, Olivier; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalously low electronic thermal conductivity in metallic vanadium dioxide", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In electrically conductive solids, the Wiedemann-Franz law requires the electronic contribution to thermal conductivity to be proportional to electrical conductivity. Violations of the Wiedemann-Franz law are typically an indication of unconventional quasiparticle dynamics, such as inelastic scattering, or hydrodynamic collective motion of charge carriers, typically pronounced only at cryogenic temperatures. We report an order-of-magnitude breakdown of the Wiedemann-Franz law at high temperatures ranging from 240 to 340 kelvin in metallic vanadium dioxide in the vicinity of its metal-insulator transition. Different from previously established mechanisms, the unusually low electronic thermal conductivity is a signature of the absence of quasiparticles in a strongly correlated electron fluid where heat and charge diffuse independently.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2017, "Volume": 355, "Issue": 6323, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aag0410", "DOI Link": "http://dx.doi.org/10.1126/science.aag0410", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393172800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Zheng, YJ; Lee, J; Hua, JY; Li, SL; Panchamukhi, A; Yue, JP; Gou, XW; Xia, ZF; Zhu, LY; Wu, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Zheng, Yongjun; Lee, Jimmy; Hua, Jieyu; Li, Shilong; Panchamukhi, Anullth; Yue, Jiping; Gou, Xuewen; Xia, Zhaofan; Zhu, Linyong; Wu, Xiaoyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A pulsatile release platform based on photo-induced imine-crosslinking hydrogel promotes scarless wound healing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Effective healing of skin wounds is essential for our survival. Although skin has strong regenerative potential, dysfunctional and disfiguring scars can result from aberrant wound repair. Skin scarring involves excessive deposition and misalignment of ECM (extracellular matrix), increased cellularity, and chronic inflammation. Transforming growth factor-beta (TGF beta) signaling exerts pleiotropic effects on wound healing by regulating cell proliferation, migration, ECM production, and the immune response. Although blocking TGF beta signaling can reduce tissue fibrosis and scarring, systemic inhibition of TGF beta can lead to significant side effects and inhibit wound re-epithelization. In this study, we develop a wound dressing material based on an integrated photo-crosslinking strategy and a microcapsule platform with pulsatile release of TGF-beta inhibitor to achieve spatiotemporal specificity for skin wounds. The material enhances skin wound closure while effectively suppressing scar formation in murine skin wounds and large animal preclinical models. Our study presents a strategy for scarless wound repair. Dysfunctional and disfiguring scars can result from aberrant wound repair. Here, the authors develop a wound dressing material based on an integrated photo-crosslinking strategy and a microcapsule platform with pulsatile release of TGF-beta inhibitor to achieve spatiotemporal specificity for scarless wound repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1670, "DOI": "10.1038/s41467-021-21964-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21964-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630057500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; Park, SN; Seral-Ascaso, A; Barwich, S; McEyoy, N; Boland, CS; Coleman, JN; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuanfang (John); Park, Sang-Noon; Seral-Ascaso, Andres; Barwich, Sebastian; McEyoy, Niall; Boland, Conor S.; Coleman, Jonathan N.; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High capacity silicon anodes enabled by MXene viscous aqueous ink", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ever-increasing demands for advanced lithium-ion batteries have greatly stimulated the quest for robust electrodes with a high areal capacity. Producing thick electrodes from a high-performance active material would maximize this parameter. However, above a critical thickness, solution-processed films typically encounter electrical/mechanical problems, limiting the achievable areal capacity and rate performance as a result. Herein, we show that two-dimensional titanium carbide or carbonitride nullosheets, known as MXenes, can be used as a conductive binder for silicon electrodes produced by a simple and scalable slurry-casting technique without the need of any other additives. The nullosheets form a continuous metallic network, enable fast charge transport and provide good mechanical reinforcement for the thick electrode (up to 450 mu m). Consequently, very high areal capacity anodes (up to 23.3 mAh cm(-2)) have been demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 849, "DOI": "10.1038/s41467-019-08383-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08383-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459095800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, S; Chen, YP; Qin, JS; Lu, WG; Zou, LF; Zhang, Q; Wang, X; Sun, X; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng; Lu, Weigang; Zou, Lanfang; Zhang, Qiang; Wang, Xuan; Sun, Xing; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precise placement of multiple functional groups in a highly ordered metal-organic framework (MOF) platform allows the tailoring of the pore environment, which is required for advanced applications. To realize this, we present a comprehensive study on the linker installation method, in which a stable MOF with coordinatively unsaturated Zr-6 clusters was employed and linkers bearing different functional groups were postsynthetically installed. A Zr-MOF with inherent missing linker sites, namely, PCN-700, was initially constructed under kinetic control. Twelve linkers with different substituents were then designed to study their effect on MOF formation kinetics and therefore resulting MOF structures. Guided by the geometrical analysis, linkers with different lengths were installed into a parent PCN-700, giving rise to 11 new MOFs and each bearing up to three different functional groups in predefined positions. Systematic variation of the pore volume and decoration of pore environment were realized by linker installation, which resulted in synergistic effects including an enhancement of H-2 adsorption capacities of up to 57%. In addition, a size-selective catalytic system for aerobic alcohol oxidation reaction is built in PCN-700 through linker installation, which shows high activity and tunable size selectivity. Altogether, these results exemplify the capability of the linker installation method in the pore environment engineering of stable MOFs with multiple functional groups, giving an unparalleled level of control.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2016, "Volume": 138, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8912, "End Page": 8919, "Article Number": null, "DOI": "10.1021/jacs.6b04501", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b04501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380295600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, D; Duan, PF; Zhang, L; Liu, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dong; Duan, Pengfei; Zhang, Li; Liu, Minghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chirality and energy transfer amplified circularly polarized luminescence in composite nullohelix", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transfer of both chirality and energy information plays an important role in biological systems. Here we show a chiral donor pi-gelator and assembled it with an achiral pi-acceptor to see how chirality and energy can be transferred in a composite donor-acceptor system. It is found that the individual chiral gelator can self-assemble into nullohelix. In the presence of the achiral acceptor, the self-assembly can also proceed and lead to the formation of the composite nullohelix. In the composite nullohelix, an energy transfer is realized. Interestingly, in the composite nullohelix, the achiral acceptor can both capture the supramolecular chirality and collect the circularly polarized energy from the chiral donor, showing both supramolecular chirality and energy transfer amplified circularly polarized luminescence (ETACPL).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15727, "DOI": "10.1038/ncomms15727", "DOI Link": "http://dx.doi.org/10.1038/ncomms15727", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402752900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WJ; Xu, ZR; Zhao, DT; Pan, XQ; Li, HC; Hu, X; Fan, ZY; Wang, WK; Zhao, GH; Jin, S; Huber, GW; Yu, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wu-Jun; Xu, Zhuoran; Zhao, Dongting; Pan, Xiao-Qiang; Li, Hong-Chao; Hu, Xiao; Fan, Zhi-Yong; Wang, Wei-Kang; Zhao, Guo-Hua; Jin, Song; Huber, George W.; Yu, Han-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient electrochemical production of glucaric acid and H2 via glucose electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glucose electrolysis offers a prospect of value-added glucaric acid synthesis and energy-saving hydrogen production from the biomass-based platform molecules. Here we report that nullostructured NiFe oxide (NiFeOx) and nitride (NiFeNx) catalysts, synthesized from NiFe layered double hydroxide nullosheet arrays on three-dimensional Ni foams, demonstrate a high activity and selectivity towards anodic glucose oxidation. The electrolytic cell assembled with these two catalysts can deliver 100mAcm(-2) at 1.39V. A faradaic efficiency of 87% and glucaric acid yield of 83% are obtained from the glucose electrolysis, which takes place via a guluronic acid pathway evidenced by in-situ infrared spectroscopy. A rigorous process model combined with a techno-economic analysis shows that the electrochemical reduction of glucose produces glucaric acid at a 54% lower cost than the current chemical approach. This work suggests that glucose electrolysis is an energy-saving and cost-effective approach for H-2 production and biomass valorization. Renewable biomass conversion may afford high-value products from common materials, but catalysts usually require expensive metals and exhibit poor selectivities. Here, authors employ nickel-iron oxide and nitride electrocatalysts to produce H-2 and to convert glucose to glucaric acid selectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 476, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 265, "DOI": "10.1038/s41467-019-14157-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14157-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528903400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YX; Yang, JP; Lai, WH; Chou, SL; Gu, QF; Liu, HK; Zhao, DY; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yun-Xiao; Yang, Jianping; Lai, Weihong; Chou, Shu-Lei; Gu, Qin-Fen; Liu, Hua Kun; Zhao, Dongyuan; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving High-Performance Room-Temperature Sodium Sulfur Batteries With S@Interconnected Mesoporous Carbon Hollow nullospheres", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the high theoretical capacity of the sodium-sulfur battery, its application is seriously restrained by the challenges due to its low sulfur electroactivity and accelerated shuttle effect, which lead to low accessible capacity and fast decay. Herein, an elaborate carbon framework, interconnected mesoporous hollow carbon nullospheres, is reported as an effective sulfur host to achieve excellent electrochemical performance. Based on in situ synchrotron X-ray diffraction, the mechanism of the room temperature Na/S battery is proposed to be reversible reactions between S-8 and Na2S4, corresponding to a theoretical capacity of 418 mAh g(-1). The cell is capable of achieving high capacity retention of similar to 88.8% over 200 cycles, and superior rate capability with reversible capacity of similar to 390 and 127 mAh g(-1) at 0.1 and 5 A g(-1), respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2016, "Volume": 138, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16576, "End Page": 16579, "Article Number": null, "DOI": "10.1021/jacs.6b08685", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b08685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391081800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, L; Huang, XY; Wang, P; Ye, L; Peng, M; An, LC; Sun, QD; Zhang, Y; Yang, GM; Li, Z; Zhong, F; Wang, F; Wang, YX; Motlag, M; Wu, WZ; Cheng, GJ; Hu, WD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Lei; Huang, Xinyu; Wang, Peng; Ye, Lei; Peng, Meng; An, Licong; Sun, Qiaodong; Zhang, Yong; Yang, Guoming; Li, Zheng; Zhong, Fang; Wang, Fang; Wang, Yixiu; Motlag, Maithilee; Wu, Wenzhuo; Cheng, Gary J.; Hu, Weida", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable mid-infrared polarization imaging based on quasi-2D tellurium at room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation polarized mid-infrared imaging systems generally requires miniaturization, integration, flexibility, good workability at room temperature and in severe environments, etc. Emerging two-dimensional materials provide another route to meet these demands, due to the ease of integrating on complex structures, their native in-plane anisotropy crystal structure for high polarization photosensitivity, and strong quantum confinement for excellent photodetecting performances at room temperature. However, polarized infrared imaging under scattering based on 2D materials has yet to be realized. Here we report the systematic investigation of polarized infrared imaging for a designed target obscured by scattering media using an anisotropic tellurium photodetector. Broadband sensitive photoresponse is realized at room temperature, with excellent stability without degradation under ambient atmospheric conditions. Significantly, a large anisotropic ratio of tellurium ensures polarized imaging in a scattering environment, with the degree of linear polarization over 0.8, opening up possibilities for developing next-generation polarized mid-infrared imaging technology. Photodetectors operating within scattering environment can be realized with anisotropic materials. Here, the authors report polarization sensitive photodetectors based on thin tellurium nullosheets with high photoresponsivity of 3.54x10(2)A/W, detectivity of similar to 3.01x10(9)Jones in the mid-infrared range and an anisotropic ratio of similar to 8 for 2.3 mu m illumination to ensure polarized imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2308, "DOI": "10.1038/s41467-020-16125-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16125-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533936800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SH; Zhou, J; Wang, Q; Chen, XS; Kawazoe, Y; Jena, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shunhong; Zhou, Jian; Wang, Qian; Chen, Xiaoshuang; Kawazoe, Yoshiyuki; Jena, Puru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Penta-graphene: A new carbon allotrope", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A 2D metastable carbon allotrope, penta-graphene, composed entirely of carbon pentagons and resembling the Cairo pentagonal tiling, is proposed. State-of-the-art theoretical calculations confirm that the new carbon polymorph is not only dynamically and mechanically stable, but also can withstand temperatures as high as 1000 K. Due to its unique atomic configuration, penta-graphene has an unusual negative Poisson's ratio and ultrahigh ideal strength that can even outperform graphene. Furthermore, unlike graphene that needs to be functionalized for opening a band gap, penta-graphene possesses an intrinsic quasi-direct band gap as large as 3.25 eV, close to that of ZnO and GaN. Equally important, penta-graphene can be exfoliated from T12-carbon. When rolled up, it can form pentagon-based nullotubes which are semiconducting, regardless of their chirality. When stacked in different patterns, stable 3D twin structures of T12-carbon are generated with band gaps even larger than that of T12-carbon. The versatility of penta-graphene and its derivatives are expected to have broad applications in nulloelectronics and nullomechanics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1253, "Times Cited, All Databases": 1284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2015, "Volume": 112, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2372, "End Page": 2377, "Article Number": null, "DOI": "10.1073/pnas.1416591112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1416591112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349911700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cliffe, MJ; Wan, W; Zou, XD; Chater, PA; Kleppe, AK; Tucker, MG; Wilhelm, H; Funnell, NP; Coudert, FX; Goodwin, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cliffe, Matthew J.; Wan, Wei; Zou, Xiaodong; Chater, Philip A.; Kleppe, Annette K.; Tucker, Matthew G.; Wilhelm, Heribert; Funnell, Nicholas P.; Coudert, Francois-Xavier; Goodwin, Andrew L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlated defect nulloregions in a metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Throughout much of condensed matter science, correlated disorder is a key to material function. While structural and compositional defects are known to exist within a variety of metal-organic frameworks (MOFs), the prevailing understanding is that these defects are only ever included in a random manner. Here we show-using a combination of diffuse scattering, electron microscopy, anomalous X-ray scattering and pair distribution function measurements-that correlations between defects can in fact be introduced and controlled within a hafnium terephthalate MOF. The nulloscale defect structures that emerge are an analogue of correlated Schottky vacancies in rocksalt-structured transition metal monoxides and have implications for storage, transport, optical and mechanical responses. Our results suggest how the diffraction behaviour of some MOFs might be reinterpreted, and establish a strategy of exploiting correlated nulloscale disorder as a targetable and desirable motif in MOF design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4176, "DOI": "10.1038/ncomms5176", "DOI Link": "http://dx.doi.org/10.1038/ncomms5176", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338838700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akkerman, QA; Gandini, M; Di Stasio, F; Rastogi, P; Palazon, F; Bertoni, G; Ball, JM; Prato, M; Petrozza, A; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akkerman, Quinten A.; Gandini, Marina; Di Stasio, Francesco; Rastogi, Prachi; Palazon, Francisco; Bertoni, Giovanni; Ball, James M.; Prato, Mirko; Petrozza, Annamaria; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly emissive perovskite nullocrystal inks for high-voltage solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite semiconductors have recently gained wide interest following their successful embodiment in solidstate photovoltaic devices with impressive power-conversion efficiencies, while offering a relatively simple and low-cost processability. Although the primary optoelectronic properties of these materials have already met the requirement for high-efficiency optoelectronic technologies, industrial scale-up requires more robust processing methods, as well as solvents that are less toxic than the ones that have been commonly used so successfully on the lab-scale. Here we report a fast, room-temperature synthesis of inks based on CsPbBr3 perovskite nullocrystals using short, low-boiling-point ligands and environmentally friendly solvents. Requiring no lengthy post-synthesis treatments, the inks are directly used to fabricate films of high optoelectronic quality, exhibiting photoluminescence quantum yields higher than 30% and an amplified spontaneous emission threshold as low as 1.5 mu J cm(-2). Finally, we demonstrate the fabrication of perovskite nullocrystal-based solar cells, with open-circuit voltages as high as 1.5V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 609, "Times Cited, All Databases": 635, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16194, "DOI": "10.1038/nenergy.2016.194", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2016.194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396303700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alfieri, ML; Weil, T; Ng, DYW; Ball, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alfieri, Maria Laura; Weil, Tanja; Ng, David Yuen Wah; Ball, Vincent", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine at biological interfaces", "Source Title": "ADVANCES IN COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the last years coating of surfaces in the presence of dopamine or other catecholamines in oxidative conditions to yield polydopamine films has become a popular, easy and versatile coating methodology. Polydopamine(s) offer(s) also a rich chemistry allowing to post-functionalize the obtained coatings with metal nulloparticles with polymers and proteins. However, the interactions either of covalent or non-covalent nature between polydopamine and biomolecules has only been explored more recently. They allow polydopamine to become a material, in the form of nulloparticles, membranes and other assemblies, in its own right not just as a coating. It is the aim of this review to describe the most recent advances in the design of composites between polydopamine and related eumelanin like materials with biomolecules like proteins, nucleotides, oligosaccharides and lipid assemblies. Furthermore, the interactions between polydopamine and living cells will be also reported.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 305, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102689, "DOI": "10.1016/j.cis.2022.102689", "DOI Link": "http://dx.doi.org/10.1016/j.cis.2022.102689", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000797951300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XC; Zhao, LX; Long, YJ; Wang, PP; Chen, D; Yang, ZH; Liang, H; Xue, MQ; Weng, HM; Fang, Z; Dai, X; Chen, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xiaochun; Zhao, Lingxiao; Long, Yujia; Wang, Peipei; Chen, Dong; Yang, Zhanhai; Liang, Hui; Xue, Mianqi; Weng, Hongming; Fang, Zhong; Dai, Xi; Chen, Genfu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the Chiral-Anomaly-Induced Negative Magnetoresistance in 3D Weyl Semimetal TaAs", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetal is the three-dimensional analog of graphene. According to quantum field theory, the appearance of Weyl points near the Fermi level will cause novel transport phenomena related to chiral anomaly. In the present paper, we report the experimental evidence for the long-anticipated negative magnetoresistance generated by the chiral anomaly in a newly predicted time-reversal-invariant Weyl semimetal material TaAs. Clear Shubnikov de Haas (SdH) oscillations have been detected starting from a very weak magnetic field. Analysis of the SdH peaks gives the Berry phase accumulated along the cyclotron orbits as pi, indicating the existence of Weyl points.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1465, "Times Cited, All Databases": 1568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31023, "DOI": "10.1103/PhysRevX.5.031023", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.031023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359947000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, WX; Li, H; Pei, C; Xia, JY; Sun, YF; Zhang, C; Lv, W; Tao, Y; Jiao, Y; Zhang, BS; Qiao, SZ; Wan, Y; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Wuxing; Li, Huan; Pei, Chun; Xia, Jingyi; Sun, Yafei; Zhang, Chen; Lv, Wei; Tao, Ying; Jiao, Yan; Zhang, Bingsen; Qiao, Shi-Zhang; Wan, Ying; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective Catalysis Remedies Polysulfide Shuttling in Lithium-Sulfur Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The shuttling of soluble lithium polysulfides between the electrodes leads to serious capacity fading and excess use of electrolyte, which severely bottlenecks practical use of Li-S batteries. Here, selective catalysis is proposed as a fundamental remedy for the consecutive solid-liquid-solid sulfur redox reactions. The proof-of-concept Indium (In)-based catalyst targetedly decelerates the solid-liquid conversion, dissolution of elemental sulfur to polysulfides, while accelerates the liquid-solid conversion, deposition of polysulfides into insoluble Li2S, which basically reduces accumulation of polysulfides in electrolyte, finally inhibiting the shuttle effect. The selective catalysis is revealed, experimentally and theoretically, by changes of activation energies and kinetic currents, modified reaction pathway together with the probed dynamically changing catalyst (LiInS2 catalyst), and gradual deactivation of the In-based catalyst. The In-based battery works steadily over 1000 cycles at 4.0 C and yields an initial areal capacity up to 9.4 mAh cm(-2) with a sulfur loading of approximate to 9.0 mg cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 33, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101006, "DOI": "10.1002/adma.202101006", "DOI Link": "http://dx.doi.org/10.1002/adma.202101006", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680028500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HY; Hu, JS; Wang, LT; Li, JZ; Ma, X; Zhu, ZC; Li, HQ; Zhao, YJ; Li, YJ; Zhao, JX; Xu, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Hongyu; Hu, Jisong; Wang, Litong; Li, Jianzhu; Ma, Xiang; Zhu, Zhicheng; Li, Heqi; Zhao, Yingjie; Li, Yujie; Zhao, Jingxin; Xu, Bingang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-Component Crosslinked Hydrogel Electrolyte toward Dendrite-Free Aqueous Zn Ion Batteries with High Temperature Adaptability", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous Zn-ion batteries (ZIBs) are always regarded as a promising energy storage device owing to their higher safety and durability. However, two problems have become the main trouble for the practical application of ZIBs such as the dendrite growth of Zn metal anode in electrolyte and the freezing of water solvent at low temperature. Herein, to overcome these challenges, a new strategy, multi-component crosslinked hydrogel electrolyte, is proposed to inhibit Zn dendrites and realize low temperature environmental adaptability for ZIBs. Benefitting from the superior inhibition effect of the polyacrylamide and dimethyl sulfoxide (DMSO) on Zn dendrites, the coulombic efficiency of the symmetric cell of approximate to 99.5% is achieved during the Zn plating/stripping over 1 300 h, and the assembled full-cell demonstrates the large specific capacity of 265.2 mAh g(-1) and high cyclic stability with the capacity retention of 95.27% after 3 000 cycles. In addition, the full-cell delivers stable operation at a wide temperature range, from 60 to -40 degrees C, due to the introduction of additive DMSO. This work provides an inspired strategy and novel opportunities to realize a dendrite-free and wide-temperature rechargeable aqueous Zn-ion energy storage system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 32, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2112540, "DOI": "10.1002/adfm.202112540", "DOI Link": "http://dx.doi.org/10.1002/adfm.202112540", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747600900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, YJ; Li, WX; Cheng, XX; Zhou, YH; Yang, S; Zhang, X; Chen, CX; Yang, TN; Pan, H; Xie, GZ; Chen, GR; Zhao, X; Xiao, X; Li, B; Tai, HL; Jiang, YD; Chen, LQ; Li, F; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yuanjie; Li, Weixiong; Cheng, Xiaoxing; Zhou, Yihao; Yang, Shuai; Zhang, Xu; Chen, Chunxu; Yang, Tiannull; Pan, Hong; Xie, Guangzhong; Chen, Guorui; Zhao, Xun; Xiao, Xiao; Li, Bei; Tai, Huiling; Jiang, Yadong; Chen, Long-Qing; Li, Fei; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance piezoelectric composites via β phase programming", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-ceramic piezoelectric composites, combining high piezoelectricity and mechanical flexibility, have attracted increasing interest in both academia and industry. However, their piezoelectric activity is largely limited by intrinsically low crystallinity and weak spontaneous polarization. Here, we propose a Ti3C2Tx MXene anchoring method to manipulate the intermolecular interactions within the all-trans conformation of a polymer matrix. Employing phase-field simulation and molecular dynamics calculations, we show that OH surface terminations on the Ti3C2Tx nullosheets offer hydrogen bonding with the fluoropolymer matrix, leading to dipole alignment and enhanced net spontaneous polarization of the polymer-ceramic composites. We then translated this interfacial bonding strategy into electrospinning to boost the piezoelectric response of samarium doped Pb (Mg1/3Nb2/3)O-3-PbTiO3/polyvinylidene fluoride composite nullofibers by 160% via Ti3C2Tx nullosheets inclusion. With excellent piezoelectric and mechanical attributes, the as-electrospun piezoelectric nullofibers can be easily integrated into the conventional shoe insoles to form a foot sensor network for all-around gait patterns monitoring, walking habits identification and Metatarsalgi prognosis. This work utilizes the interfacial coupling mechanism of intermolecular anchoring as a strategy to develop high-performance piezoelectric composites for wearable electronics. The piezoelectricity of PVDF composites is mainly determined by the crystalline phases and spontaneous polarization. Here, the authors propose a Ti3C2Tx anchoring method to modulate the molecular interactions and conformation of polymer matrix.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4867, "DOI": "10.1038/s41467-022-32518-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32518-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842231900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, Y; Xu, C; Meng, L; Dong, XF; Qi, M; Jiang, DQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Yue; Xu, Chang; Meng, Lingao; Dong, Xufeng; Qi, Min; Jiang, Daqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exosome-functionalized magnesium-organic framework-based scaffolds with osteogenic, angiogenic and anti-inflammatory properties for accelerated bone regeneration", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exosomes derived from human adipose-derived stem cells (hADSCs-Exos) have shown potential as an effective therapeutic tool for repairing bone defects. Although metal-organic framework (MOF) scaffolds are promising strategies for bone tissue regeneration, their potential use for exosome loading remains unexplored. In this study, motivated by the potential advantages of hADSCs-Exos and Mg-GA MOF, we designed and synthesized an exosome-functionalized cell-free PLGA/Mg-GA MOF (PLGA/Exo-Mg-GA MOF) scaffold, taking using of the benefits of hADSCs-Exos, Mg2+, and gallic acid (GA) to construct unique nullostructural interfaces to enhance osteogenic, angiogenic and anti-inflammatory capabilities simultaneously. Our in vitro work demonstrated the beneficial effects of PLGA/Exo-Mg-GA MOF composite scaffolds on the osteogenic effects in human bone marrow-derived mesenchymal stem cells (hBMSCs) and angiogenic effects in human umbilical endothelial cells (HUVECs). Slowly released hADSCs-Exos from composite scaffolds were phagocytosed by co-cultured cells, stabilized the bone graft environment, ensured blood supply, promoted osteogenic differentiation, and accelerated bone reconstruction. Furthermore, our in vivo experiments with rat calvarial defect model showed that PLGA/Exo-Mg-GA MOF scaffolds promoted new bone formation and satisfactory osseointegration. Overall, we provide valuable new insights for designing exosome-coated nullocomposite scaffolds with enhanced osteogenesis property.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 18, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26, "End Page": 41, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.02.012", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.02.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787543400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YJ; Zhang, JX; Xiao, LF; Ai, XP; Cao, YL; Yang, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yongjin; Zhang, Jiexin; Xiao, Lifen; Ai, Xinping; Cao, Yuliang; Yang, Hanxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphate Framework Electrode Materials for Sodium Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium ion batteries (SIBs) have been considered as a promising alternative for the next generation of electric storage systems due to their similar electro-chemistry to Li-ion batteries and the low cost of sodium resources. Exploring appropriate electrode materials with decent electrochemical performance is the key issue for development of sodium ion batteries. Due to the high structural stability, facile reaction mechanism and rich structural diversity, phosphate framework materials have attracted increasing attention as promising electrode materials for sodium ion batteries. Herein, we review the latest advances and progresses in the exploration of phosphate framework materials especially related to single-phosphates, pyrophosphates and mixed-phosphates. We provide the detailed and comprehensive understanding of structure-composition-performance relationship of materials and try to show the advantages and disadvantages of the materials for use in SIBs. In addition, some new perspectives about phosphate framework materials for SIBs are also discussed. Phosphate framework materials will be a competitive and attractive choice for use as electrodes in the next-generation of energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600392, "DOI": "10.1002/advs.201600392", "DOI Link": "http://dx.doi.org/10.1002/advs.201600392", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402740300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, X; Qin, HC; Qian, XS; Zhu, WY; Li, B; Zhang, B; Lu, WC; Li, RP; Zhang, SH; Zhu, L; Dos Santos, FD; Bernholc, J; Zhang, QM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xin; Qin, Hancheng; Qian, Xiaoshi; Zhu, Wenyi; Li, Bo; Zhang, Bing; Lu, Wenchang; Li, Ruipeng; Zhang, Shihai; Zhu, Lei; Dos Santos, Fabrice Domingues; Bernholc, J.; Zhang, Q. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Relaxor ferroelectric polymer exhibits ultrahigh electromechanical coupling at low electric field", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromechanical (EM) coupling-the conversion of energy between electric and mechanical forms-in ferroelectrics has been used for a broad range of applications. Ferroelectric polymers have weak EM coupling that severely limits their usefulness for applications. We introduced a small amount of fluorinated alkyne (FA) monomers (<2 mol %) in relaxor ferroelectric poly(vinylidene fluoridetrifluoroethylene-chlorofluoroethylene) (PVDF-TrFE-CFE) terpolymer that markedly enhances the polarization change with strong EM coupling while suppressing other polarization changes that do not contribute to it. Under a low-dc bias field of 40 megavolts per meter, the relaxor tetrapolymer has an EM coupling factor (k(33)) of 88% and a piezoelectric coefficient (d(33)) >1000 picometers per volt. These values make this solution-processed polymer competitive with ceramic oxide piezoelectrics, with the potential for use in distinct applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2022, "Volume": 375, "Issue": 6587, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1418, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn0936", "DOI Link": "http://dx.doi.org/10.1126/science.abn0936", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778894800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WS; Jie, Q; Kim, HS; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Weishu; Jie, Qing; Kim, Hee Seok; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current progress and future challenges in thermoelectric power generation: From materials to devices", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric power generation (TEG) represents one of the cleanest methods of energy conversion available today. It can be used in applications ranging from the harvesting of waste heat to conversion of solar energy into useful electricity. Remarkable advances have been achieved in recent years for various thermoelectric (TE) material systems. The introduction of nullostructures is used to tune the transport of phonons, while band structure engineering allows for the tailoring of electron transport. In this overview, top-down approaches to phonon engineering, such as atomic construction of new materials, will be reviewed. Bottom-up approaches to electron engineering, such as the formation of ordered nullostructures, will also be discussed. The assembly of TEG devices is still particularly challenging, and consequently, thermal-to-electric conversion utilizing these devices has been realized only in niche applications. In this review paper, we will discuss some of the challenges that must be overcome to enable widespread use of TE devices. These include thermal stability at the material level, and reliable contact at the device level. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 468, "Times Cited, All Databases": 493, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2015, "Volume": 87, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 357, "End Page": 376, "Article Number": null, "DOI": "10.1016/j.actamat.2014.12.042", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2014.12.042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350517700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ariati, R; Sales, F; Souza, A; Lima, RA; Ribeiro, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ariati, Ronaldo; Sales, Flaminio; Souza, Andrews; Lima, Rui A.; Ribeiro, Joao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydimethylsiloxane Composites Characterization and Its Applications: A Review", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydimethylsiloxane (PDMS) is one of the most promising elastomers due its remarkable proprieties such as good thermal stability, biocompatibility, corrosion resistance, flexibility, low cost, ease of use, chemically inertia, hyperplastic characteristics, and gas permeability. Thus, it can be used in areas such as microfluidic systems, biomedical devices, electronic components, membranes for filtering and pervaporation, sensors, and coatings. Although pure PDMS has low mechanical properties, such as low modulus of elasticity and strength, it can be improved by mixing the PDMS with other polymers and by adding particles or reinforcements. Fiber-reinforced PDMS has proved to be a good alternative to manufacturing flexible displays, batteries, wearable devices, tactile sensors, and energy harvesting systems. PDMS and particulates are often used in the separation of liquids from wastewater by means of porosity followed by hydrophobicity. Waxes such as beeswax and paraffin have proved to be materials capable of improving properties such as the hydrophobic, corrosion-resistant, thermal, and optical properties of PDMS. Finally, when blended with polymers such as poly (vinyl chloride-co-vinyl acetate), PDMS becomes a highly efficient alternative for membrane separation applications. However, to the best of our knowledge there are few works dedicated to the review and comparison of different PDMS composites. Hence, this review will be focused on PDMS composites, their respective applications, and properties. Generally, the combination of elastomer with fibers, particles, waxes, polymers, and others it will be discussed, with the aim of producing a review that demonstrates the wide applications of this material and how tailored characteristics can be reached for custom applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4258, "DOI": "10.3390/polym13234258", "DOI Link": "http://dx.doi.org/10.3390/polym13234258", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000734545600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Yang, J; Xu, RJ; Wang, F; Li, WF; Ghufran, M; Zhang, YW; Yu, ZF; Zhang, G; Qin, QH; Lu, YR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuang; Yang, Jiong; Xu, Renjing; Wang, Fan; Li, Weifeng; Ghufran, Muhammad; Zhang, Yong-Wei; Yu, Zongfu; Zhang, Gang; Qin, Qinghua; Lu, Yuerui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinary Photoluminescence and Strong Temperature/Angle-Dependent Raman Responses in Few-Layer Phosphorene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene is a new family member of two-dimensional materials. We observed strong and highly layer-dependent photoluminescence in few-layer phosphorene (two to five layers). The results confirmed the theoretical prediction that few-layer phosphorene has a direct and layer-sensitive band gap. We also demonstrated that few-layer phosphorene is more sensitive to temperature modulation than graphene and MoS2 in Raman scattering. The anisotropic Raman response in few-layer phosphorene has enabled us to use an optical method to quickly determine the crystalline orientation without tunneling electron microscopy or scanning tunneling microscopy. Our results provide much needed experimental information about the band structures and exciton nature in few-layer phosphorene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 607, "Times Cited, All Databases": 659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9590, "End Page": 9596, "Article Number": null, "DOI": "10.1021/nn503893j", "DOI Link": "http://dx.doi.org/10.1021/nn503893j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342184400092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, DD; Shen, RC; Jiang, ZM; Lu, XY; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Doudou; Shen, Rongchen; Jiang, Zhimin; Lu, Xinyong; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient visible-light photocatalytic H2 evolution over 2D-2D CdS/Cu7S4 layered heterojunctions", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Converting solar energy into clean and sustainable chemical fuels is a promising strategy for exploiting renewable energy. The application of photocatalytic water splitting technology in hydrogen production is important for sustainable energy development and environmental protection. In this study, for the first time, 2D Cu7S4 co-catalysts were coupled on the surface of a CdS nullosheet photocatalyst by a one-step ultrasonic-assisted electrostatic self-assembly method at room temperature. The as-fabricated 2D-2D CdS/Cu7S4 layered heterojunctions were demonstrated to be advanced composite photocatalysts that enhance the water splitting efficiency toward hydrogen production. The highest hydrogen evolution rate of the 2D-2D CdS/2%Cu7S4 binary heterojunction photocatalyst was up to 27.8 mmol g(-1) h(-1) under visible light irradiation, with an apparent quantum efficiency of 14.7% at 420 nm, which was almost 10.69 times and 2.65 times higher than those of pure CdS nullosheets (2.6 mmol g(-1) h(-1)) and CdS-2%CuS (10.5 mmol g(-1) h(-1)), respectively. The establishment of the CdS/Cu7S4 binary-layered heterojunction could not only enhance the separation of photogenerated electron-hole (e(-)-h(+)) pairs, improve the transfer of photo-excited electrons, and prolong the life-span of photo-generated electrons, but also enhance the light absorption and hydrogen-evolution kinetics. All these factors are important for the enhancement of the photocatalytic activity. Expectedly, the 2D-2D interface coupling strategy based on CdS NSs can be extensively exploited to improve the hydrogen-evolution activity over various kinds of conventional semiconductor NSs. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 31, "End Page": 40, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63467-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63467-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495145800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, CC; Ding, BF; Zhang, SZ; Cui, LL; Ostrikov, KK; Huang, ZY; Yang, B; Kim, JH; Zhang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Chenchen; Ding, Baofu; Zhang, Shaoze; Cui, Lele; Ostrikov, Kostya Ken; Huang, Ziyang; Yang, Bo; Kim, Jae-Hong; Zhang, Zhenghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Angstrom-confined catalytic water purification within Co-TiOx laminar membrane nullochannels", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The freshwater scarcity and inadequate access to clean water globally have rallied tremendous efforts in developing robust technologies for water purification and decontamination, and heterogeneous catalysis is a highly-promising solution. Sub-nullometer-confined reaction is the ultimate frontier of catalytic chemistry, yet it is challenging to form the angstrom channels with distributed atomic catalytic centers within, and to match the internal mass transfer and the reactive species' lifetimes. Here, we resolve these issues by applying the concept of the angstrom-confined catalytic water contaminullt degradation to achieve unprecedented reaction rates within 4.6 angstrom channels of two-dimensional laminate membrane assembled from monolayer cobalt-doped titanium oxide nullosheets. The demonstrated degradation rate constant of the target pollutant ranitidine (1.06 ms(-1)) is 5-7 orders of magnitude faster compared with the state-of-the-art, achieving the 100% degradation over 100 h continuous operation. This approach is also similar to 100% effective against diverse water contaminates with a retention time of <30 ms, and the strategy developed can be also extended to other two-dimensional material-assembled membranes. This work paves the way towards the generic angstrom-confined catalysis and unravels the importance of utilizing angstrom-confinement strategy in the design of efficient catalysts for water purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4010, "DOI": "10.1038/s41467-022-31807-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31807-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827534700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XF; Zhu, YZ; Mo, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xingfeng; Zhu, Yizhou; Mo, Yifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of fast ion diffusion in super-ionic conductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Super-ionic conductor materials have great potential to enable novel technologies in energy storage and conversion. However, it is not yet understood why only a few materials can deliver exceptionally higher ionic conductivity than typical solids or how one can design fast ion conductors following simple principles. Using ab initio modelling, here we show that fast diffusion in super-ionic conductors does not occur through isolated ion hopping as is typical in solids, but instead proceeds through concerted migrations of multiple ions with low energy barriers. Furthermore, we elucidate that the low energy barriers of the concerted ionic diffusion are a result of unique mobile ion configurations and strong mobile ion interactions in super-ionic conductors. Our results provide a general framework and universal strategy to design solid materials with fast ionic diffusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 727, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15893, "DOI": "10.1038/ncomms15893", "DOI Link": "http://dx.doi.org/10.1038/ncomms15893", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403770700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bartlett, MD; Kazem, N; Powell-Palm, MJ; Huang, XN; Sun, WH; Malen, JA; Majidi, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bartlett, Michael D.; Kazem, Navid; Powell-Palm, Matthew J.; Huang, Xiaonull; Sun, Wenhuan; Malen, Jonathan A.; Majidi, Carmel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High thermal conductivity in soft elastomers with elongated liquid metal inclusions", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft dielectric materials typically exhibit poor heat transfer properties due to the dynamics of phonon transport, which constrain thermal conductivity (k) to decrease monotonically with decreasing elastic modulus (E). This thermal-mechanical trade-off is limiting for wearable computing, soft robotics, and other emerging applications that require materials with both high thermal conductivity and low mechanical stiffness. Here, we overcome this constraint with an electrically insulating composite that exhibits an unprecedented combination of metal-like thermal conductivity, an elastic compliance similar to soft biological tissue (Young's modulus < 100 kPa), and the capability to undergo extreme deformations (>600% strain). By incorporating liquid metal (LM) microdroplets into a soft elastomer, we achieve a similar to 25x increase in thermal conductivity (4.7 +/- 0.2W.m(-1).K-1) over the base polymer (0.20 +/- 0.01W.m(-1) .K-1) under stress-free conditions and a similar to 50x increase (9.8 +/- 0.8 W.m(-1) K-1) when strained. This exceptional combination of thermal and mechanical properties is enabled by a unique thermal-mechanical coupling that exploits the deformability of the LM inclusions to create thermally conductive pathways in situ. Moreover, these materials offer possibilities for passive heat exchange in stretchable electronics and bioinspired robotics, which we demonstrate through the rapid heat dissipation of an elastomer-mounted extreme high-power LED lamp and a swimming soft robot.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 520, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2017, "Volume": 114, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2143, "End Page": 2148, "Article Number": null, "DOI": "10.1073/pnas.1616377114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1616377114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395101200035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lejaeghere, K; Bihlmayer, G; Björkman, T; Blaha, P; Blügel, S; Blum, V; Caliste, D; Castelli, IE; Clark, SJ; Dal Corso, A; de Gironcoli, S; Deutsch, T; Dewhurst, JK; Di Marco, I; Draxl, C; Dulak, M; Eriksson, O; Flores-Livas, JA; Garrity, KF; Genovese, L; Giannozzi, P; Giantomassi, M; Goedecker, S; Gonze, X; Grånäs, O; Gross, EKU; Gulans, A; Gygi, F; Hamann, DR; Hasnip, PJ; Holzwarth, NAW; Iusan, D; Jochym, DB; Jollet, F; Jones, D; Kresse, G; Koepernik, K; Küçükbenli, E; Kvashnin, YO; Locht, ILM; Lubeck, S; Marsman, M; Marzari, N; Nitzsche, U; Nordström, L; Ozaki, T; Paulatto, L; Pickard, CJ; Poelmans, W; Probert, MIJ; Refson, K; Richter, M; Rignullese, GM; Saha, S; Scheffler, M; Schlipf, M; Schwarz, K; Sharma, S; Tavazza, F; Thunström, P; Tkatchenko, A; Torrent, M; Vanderbilt, D; van Setten, MJ; Van Speybroeck, V; Wills, JM; Yates, JR; Zhang, GX; Cottenier, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lejaeghere, Kurt; Bihlmayer, Gustav; Bjoerkman, Torbjoern; Blaha, Peter; Bluegel, Stefan; Blum, Volker; Caliste, Damien; Castelli, Ivano E.; Clark, Stewart J.; Dal Corso, Andrea; de Gironcoli, Stefano; Deutsch, Thierry; Dewhurst, John Kay; Di Marco, Igor; Draxl, Claudia; Dulak, Marcin; Eriksson, Olle; Flores-Livas, Jose A.; Garrity, Kevin F.; Genovese, Luigi; Giannozzi, Paolo; Giantomassi, Matteo; Goedecker, Stefan; Gonze, Xavier; Granaes, Oscar; Gross, E. K. U.; Gulans, Andris; Gygi, Francois; Hamann, D. R.; Hasnip, Phil J.; Holzwarth, N. A. W.; Iusan, Diana; Jochym, Dominik B.; Jollet, Francois; Jones, Daniel; Kresse, Georg; Koepernik, Klaus; Kuecuekbenli, Emine; Kvashnin, Yaroslav O.; Locht, Inka L. M.; Lubeck, Sven; Marsman, Martijn; Marzari, Nicola; Nitzsche, Ulrike; Nordstrom, Lars; Ozaki, Taisuke; Paulatto, Lorenzo; Pickard, Chris J.; Poelmans, Ward; Probert, Matt I. J.; Refson, Keith; Richter, Manuel; Rignullese, Gian-Marco; Saha, Santanu; Scheffler, Matthias; Schlipf, Martin; Schwarz, Karlheinz; Sharma, Sangeeta; Tavazza, Francesca; Thunstroem, Patrik; Tkatchenko, Alexandre; Torrent, Marc; Vanderbilt, David; van Setten, Michiel J.; Van Speybroeck, Veronique; Wills, John M.; Yates, Jonathan R.; Zhang, Guo-Xu; Cottenier, Stefaan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reproducibility in density functional theory calculations of solids", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widespread popularity of density functional theory has given rise to an extensive range of dedicated codes for predicting molecular and crystalline properties. However, each code implements the formalism in a different way, raising questions about the reproducibility of such predictions. We report the results of a community-wide effort that compared 15 solid-state codes, using 40 different potentials or basis set types, to assess the quality of the Perdew-Burke-Ernzerhof equations of state for 71 elemental crystals. We conclude that predictions from recent codes and pseudopotentials agree very well, with pairwise differences that are comparable to those between different high-precision experiments. Older methods, however, have less precise agreement. Our benchmark provides a framework for users and developers to document the precision of new applications and methodological improvements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1174, "Times Cited, All Databases": 1258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2016, "Volume": 351, "Issue": 6280, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "aad3000", "DOI": "10.1126/science.aad3000", "DOI Link": "http://dx.doi.org/10.1126/science.aad3000", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372756200038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, Y; Liu, K; Lang, JL; Zhuo, D; Huang, ZY; Wang, CA; Wu, H; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Yang; Liu, Kai; Lang, Jialiang; Zhuo, Denys; Huang, Zeya; Wang, Chang-an; Wu, Hui; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An intermediate temperature garnet-type solid electrolyte-based molten lithium battery for grid energy storage", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Batteries are an attractive grid energy storage technology, but a reliable battery system with the functionalities required for a grid such as high power capability, high safety and low cost remains elusive. Here, we report a solid electrolyte-based molten lithium battery constructed with a molten lithium anode, a molten Sn-Pb or Bi-Pb alloy cathode and a garnet-type Li6.4La3Zr1.4Ta0.6O12 (LLZTO) solid electrolyte tube. We show that the assembled Li parallel to LLZTO parallel to Sn-Pb and Li parallel to LLZTO parallel to Bi-Pb cells can stably cycle at an intermediate temperature of 240 degrees C for about one month at current densities of 50 mA cm(-2) and 100 mA cm(-2) respectively, with almost no capacity decay and an average Coulombic efficiency of 99.98%. Furthermore, the cells demonstrate high power capability with current densities up to 300 mA cm(-2) (90 mW cm(-2)) for Li parallel to LLZTO parallel to Sn-Pb and 500 mA cm(-2) (175 mW cm(-2)) for Li parallel to LLZTO parallel to Bi-Pb. Our design offers prospects for grid energy storage with intermediate temperature operations, high safety margin and low capital and maintenullce costs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 732, "End Page": 738, "Article Number": null, "DOI": "10.1038/s41560-018-0198-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0198-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444121800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Croguennec, L; Palacin, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Croguennec, Laurence; Palacin, M. Rosa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Achievements on Inorganic Electrode Materials for Lithium-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lithium-ion battery technology is rooted in the studies of intercalation of guest ions into inorganic host materials developed ca. 40 years ago. It further turned into a commercial product, which will soon blow its 25th candle. Intense research efforts during this time have resulted in the development of a large spectrum of electrode materials together with deep understanding of the underlying structure-property relationships that govern their performance. This has enabled an ever increasing electrochemical yield together with the diversification of the technology into several subfamilies, tailoring materials to application requirements. The present paper aims at providing a global and critical perspective on inorganic electrode materials for lithium-ion batteries categorized by their reaction mechanism and structural dimensionality. Specific emphasis is put on recent research in the field, which beyond the chemistry and microstructure of the materials themselves also involves considering interfacial chemistry concepts alongside progress in characterization techniques. Finally a short personal perspective is provided on some plausible development of the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2015, "Volume": 137, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3140, "End Page": 3156, "Article Number": null, "DOI": "10.1021/ja507828x", "DOI Link": "http://dx.doi.org/10.1021/ja507828x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351187200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, P; Chen, B; Liang, CW; Yao, WT; Cui, YZ; Hu, SY; Zou, PC; Zhang, H; Fan, HJ; Yang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Peng; Chen, Bo; Liang, Caiwu; Yao, Wentao; Cui, Yuanzheng; Hu, Shengyu; Zou, Peichao; Zhang, Hua; Fan, Hong Jin; Yang, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tip-Enhanced Electric Field: A New Mechanism Promoting Mass Transfer in Oxygen Evolution Reactions", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The slow kinetics of oxygen evolution reaction (OER) causes high power consumption for electrochemical water splitting. Various strategies have been attempted to accelerate the OER rate, but there are few studies on regulating the transport of reactants especially under large current densities when the mass transfer factor dominates the evolution reactions. Herein, NixFe1-x alloy nullocones arrays (with approximate to 2 nm surface NiO/NiFe(OH)(2) layer) are adopted to boost the transport of reactants. Finite element analysis suggests that the high-curvature tips can enhance the local electric field, which induces an order of magnitude higher concentration of hydroxide ions (OH-) at the active sites and promotes intrinsic OER activity by 67% at 1.5 V. Experimental results show that a fabricated NiFe nullocone array electrode, with optimized alloy composition, has a small overpotential of 190 mV at 10 mA cm(-2) and 255 mV at 500 mA cm(-2). When calibrated by electrochemical surface area, the nullocones electrode outperforms the state-of-the-art OER electrocatalysts. The positive effect of the tip-enhanced local electric field in promoting mass transfer is also confirmed by comparing samples with different tip curvature radii. It is suggested that this local field enhanced OER kinetics is a generic effect to other OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 33, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007377, "DOI": "10.1002/adma.202007377", "DOI Link": "http://dx.doi.org/10.1002/adma.202007377", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612639600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chai, LL; Hu, ZY; Wang, X; Xu, YW; Zhang, LJ; Li, TT; Hu, Y; Qian, JJ; Huang, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chai, Lulu; Hu, Zhuoyi; Wang, Xian; Xu, Yuwei; Zhang, Linjie; Li, Ting-Ting; Hu, Yue; Qian, Jinjie; Huang, Shaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stringing Bimetallic Metal-Organic Framework-Derived Cobalt Phosphide Composite for High-Efficiency Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water electrolysis is an emerging energy conversion technology, which is significant for efficient hydrogen (H-2) production. Based on the high-activity transition metal ions and metal alloys of ultrastable bifunctional catalyst, the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are the key to achieving the energy conversion method by overall water splitting (OWS). This study reports that the Co-based coordination polymer (ZIF-67) anchoring on an indium-organic framework (InOF-1) composite (InOF-1@ZIF-67) is treated followed by carbonization and phosphorization to successfully obtain CoP nulloparticles-embedded carbon nullotubes and nitrogen-doped carbon materials (CoP-InNC@CNT). As HER and OER electrocatalysts, it is demonstrated that CoP-InNC@CNT simultaneously exhibit high HER performance (overpotential of 153 mV in 0.5 m H2SO4 and 159 mV in 1.0 m KOH) and OER performance (overpotential of 270 mV in 1.0 m KOH) activities to reach the current density of 10 mA cm(-2). In addition, these CoP-InNC@CNT rods, as a cathode and an anode, can display an excellent OWS performance with eta(10) = 1.58 V and better stability, which shows the satisfying electrocatalyst for the OWS compared to control materials. This method ensures the tight and uniform growth of the fast nucleating and stable materials on substrate and can be further applied for practical electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903195, "DOI": "10.1002/advs.201903195", "DOI Link": "http://dx.doi.org/10.1002/advs.201903195", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508741100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YX; Shi, R; Bian, XAN; Zhou, C; Zhao, YF; Zhang, S; Wu, F; Waterhouse, GIN; Wu, LZ; Tung, CH; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yunxuan; Shi, Run; Bian, Xuanullg; Zhou, Chao; Zhao, Yufei; Zhang, Shuai; Wu, Fan; Waterhouse, Geoffrey I. N.; Wu, Li-Zhu; Tung, Chen-Ho; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ammonia Detection Methods in Photocatalytic and Electrocatalytic Experiments: How to Improve the Reliability of NH3 Production Rates?", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The enzyme nitrogenase inspires the development of novel photocatalytic and electrocatalytic systems that can drive nitrogen reduction with water under similar low-temperature and low-pressure conditions. While photocatalytic and electrocatalytic N-2 fixation are emerging as hot new areas of fundamental and applied research, serious concerns exist regarding the accuracy of current methods used for ammonia detection and quantification. In most studies, the ammonia yields are low and little consideration is given to the effect of interferants on NH3 quantification. As a result, NH3 yields reported in many works may be exaggerated and erroneous. Herein, the advantages and limitations of the various methods commonly used for NH3 quantification in solution (Nessler's reagent method, indophenol blue method, and ion chromatography method) are systematically explored, placing particular emphasis on the effect of interferants on each quantification method. Based on the data presented, guidelines are suggested for responsible quantification of ammonia in photocatalysis and electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 493, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802109, "DOI": "10.1002/advs.201802109", "DOI Link": "http://dx.doi.org/10.1002/advs.201802109", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464827300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, XD; Li, WY; Wang, X; Sui, Q; Zhang, TY; Wang, Z; Liu, L; Li, D; Feng, S; Zhong, SY; Wang, HW; Bouchiat, V; Regueiro, MN; Rougemaille, N; Coraux, J; Purbawati, A; Hadj-Azzem, A; Wang, ZH; Dong, BJ; Wu, X; Yang, T; Yu, GQ; Wang, BW; Han, Z; Han, XF; Zhang, ZD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Xingdan; Li, Wanying; Wang, Xiao; Sui, Qi; Zhang, Tongyao; Wang, Zhi; Liu, Long; Li, Da; Feng, Shun; Zhong, Siyu; Wang, Hanwen; Bouchiat, Vincent; Regueiro, Manuel Nunez; Rougemaille, Nicolas; Coraux, Johann; Purbawati, Anike; Hadj-Azzem, Abdellali; Wang, Zhenhua; Dong, Baojuan; Wu, Xing; Yang, Teng; Yu, Guoqiang; Wang, Bingwu; Han, Zheng; Han, Xiufeng; Zhang, Zhidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature ferromagnetism in ultra-thin van der Waals crystals of 1T-CrTe2", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although many emerging new phenomena have been unraveled in two dimensional (2D) materials with long-range spin orderings, the usually low critical temperature in van der Waals (vdW) magnetic material has thus far hindered the related practical applications. Here, we show that ferromagnetism can hold above 300 K in a metallic phase of 1T-CrTe(2)down to the ultra-thin limit. It thus makes CrTe(2)so far the only known exfoliated ultra-thin vdW magnets with intrinsic long-range magnetic ordering above room temperature. An in-plane room-temperature negative anisotropic magnetoresistance (AMR) was obtained in ultra-thin CrTe(2)devices, with a sign change in the AMR at lower temperature, with -0.6% and +5% at 300 and 10 K, respectively. Our findings provide insights into magnetism in ultra-thin CrTe2, expanding the vdW crystals toolbox for future room-temperature spintronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3358, "End Page": 3363, "Article Number": null, "DOI": "10.1007/s12274-020-3021-4", "DOI Link": "http://dx.doi.org/10.1007/s12274-020-3021-4", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563729000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JY; Shabbir, B; Wang, CJ; Wan, T; Ou, QD; Yu, P; Tadich, A; Jiao, XC; Chu, DW; Qi, DC; Li, DB; Kan, RF; Huang, YM; Dong, YM; Jasieniak, J; Zhang, YP; Bao, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jingying; Shabbir, Babar; Wang, Chujie; Wan, Tao; Ou, Qingdong; Yu, Pei; Tadich, Anton; Jiao, Xuechen; Chu, Dewei; Qi, Dongchen; Li, Dabing; Kan, Ruifeng; Huang, Yamin; Dong, Yemin; Jasieniak, Jacek; Zhang, Yupeng; Bao, Qiaoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, Printable Soft-X-Ray Detectors Based on All-Inorganic Perovskite Quantum Dots", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites represent a family of the most promising materials for fascinating photovoltaic and photodetector applications due to their unique optoelectronic properties and much needed simple and low-cost fabrication process. The high atomic number (Z) of their constituents and significantly higher carrier mobility also make perovskite semiconductors suitable for the detection of ionizing radiation. By taking advantage of that, the direct detection of soft-X-ray-induced photocurrent is demonstrated in both rigid and flexible detectors based on all-inorganic halide perovskite quantum dots (QDs) synthesized via a solution process. Utilizing a synchrotron soft-X-ray beamline, high sensitivities of up to 1450 mu C Gy(air)(-1) cm(-2) are achieved under an X-ray dose rate of 0.0172 mGy(air) s(-1) with only 0.1 V bias voltage, which is about 70-fold more sensitive than conventional alpha-Se devices. Furthermore, the perovskite film is printed homogeneously on various substrates by the inexpensive inkjet printing method to demonstrate large-scale fabrication of arrays of multichannel detectors. These results suggest that the perovskite QDs are ideal candidates for the detection of soft X-rays and for large-area flat or flexible panels with tremendous application potential in multidimensional and different architectures imaging technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 31, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901644, "DOI": "10.1002/adma.201901644", "DOI Link": "http://dx.doi.org/10.1002/adma.201901644", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000484138100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, F; Zhou, L; Liu, JX; Liang, YC; Zhang, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fei; Zhou, Lin; Liu, Ji-Xuan; Liang, Yongcheng; Zhang, Guo-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy pyrochlores with low thermal conductivity for thermal barrier coating materials", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy pyrochlore-type structures based on rare-earth zirconates are successfully produced by conventional solid-state reaction method. Six rare-earth oxides (La2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, and Y2O3) and ZrO2 are used as the raw powders. Five out of the six rare-earth oxides with equimolar ratio and ZrO2 are mixed and sintered at different temperatures for investigating the reaction process. The results demonstrate that the high-entropy pyrochlores (5RE(1/5))(2)Zr2O7 have been formed after heated at 1000 degrees C The (5RE(1/5))(2)Zr2O7 are highly sintering resistant and possess excellent thermal stability. The thermal conductivities of the (5RE(1/5))(2)Zr2O7 high-entropy ceramics are below 1 W.m(-1).K-1 in the temperature range of 300-1200 degrees C The (5RE(1/5))(2)Zr2O7 can be potential thermal barrier coating materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 576, "End Page": 582, "Article Number": null, "DOI": "10.1007/s40145-019-0342-4", "DOI Link": "http://dx.doi.org/10.1007/s40145-019-0342-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517128600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thomson, D; Zilkie, A; Bowers, JE; Komljenovic, T; Reed, GT; Vivien, L; Marris-Morini, D; Cassan, E; Virot, L; Fédéli, JM; Hartmann, JM; Schmid, JH; Xu, DX; Boeuf, F; O'Brien, P; Mashanovich, GZ; Nedeljkovic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thomson, David; Zilkie, Aaron; Bowers, John E.; Komljenovic, Tin; Reed, Graham T.; Vivien, Laurent; Marris-Morini, Delphine; Cassan, Eric; Virot, Leopold; Fedeli, Jean-Marc; Hartmann, Jean-Michel; Schmid, Jens H.; Xu, Dan-Xia; Boeuf, Frederic; O'Brien, Peter; Mashanovich, Goran Z.; Nedeljkovic, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roadmap on silicon photonics", "Source Title": "JOURNAL OF OPTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon photonics research can be dated back to the 1980s. However, the previous decade has witnessed an explosive growth in the field. Silicon photonics is a disruptive technology that is poised to revolutionize a number of application areas, for example, data centers, high-performance computing and sensing. The key driving force behind silicon photonics is the ability to use CMOS-like fabrication resulting in high-volume production at low cost. This is a key enabling factor for bringing photonics to a range of technology areas where the costs of implementation using traditional photonic elements such as those used for the telecommunications industry would be prohibitive. Silicon does however have a number of shortcomings as a photonic material. In its basic form it is not an ideal material in which to produce light sources, optical modulators or photodetectors for example. A wealth of research effort from both academia and industry in recent years has fueled the demonstration of multiple solutions to these and other problems, and as time progresses new approaches are increasingly being conceived. It is clear that silicon photonics has a bright future. However, with a growing number of approaches available, what will the silicon photonic integrated circuit of the future look like? This roadmap on silicon photonics delves into the different technology and application areas of the field giving an insight into the state-of-the-art as well as current and future challenges faced by researchers worldwide. Contributions authored by experts from both industry and academia provide an overview and outlook for the silicon waveguide platform, optical sources, optical modulators, photodetectors, integration approaches, packaging, applications of silicon photonics and approaches required to satisfy applications at mid-infrared wavelengths. Advances in science and technology required to meet challenges faced by the field in each of these areas are also addressed together with predictions of where the field is destined to reach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 976, "Times Cited, All Databases": 1092, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 18, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 73003, "DOI": "10.1088/2040-8978/18/7/073003", "DOI Link": "http://dx.doi.org/10.1088/2040-8978/18/7/073003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383908800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Srimuk, P; Kaasik, F; Krüner, B; Tolosa, A; Fleischmann, S; Jäckel, N; Tekeli, MC; Aslan, M; Suss, ME; Presser, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Srimuk, Pattarachai; Kaasik, Friedrich; Kruener, Benjamin; Tolosa, Aura; Fleischmann, Simon; Jaeckel, Nicolas; Tekeli, Mehmet C.; Aslan, Mesut; Suss, Matthew E.; Presser, Volker", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene as a novel intercalation-type pseudocapacitive cathode and anode for capacitive deionization", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this proof-of-concept study, we introduce and demonstrate MXene as a novel type of intercalation electrode for desalination via capacitive deionization (CDI). Traditional CDI cells employ nulloporous carbon electrodes with significant pore volume to achieve a large desalination capacity via ion electrosorption. By contrast, MXene stores charge by ion intercalation between the sheets of its two-dimensional nullo lamellar structure. By this virtue, it behaves as an ideal pseudocapacitor, that is, showing capacitive electric response while intercalating both anions and cations. We synthesized Ti3C2-MXene by the conventional process of etching ternary titanium aluminum carbide i.e., the MAX phase (Ti3AlC2) with hydrofluoric acid. The MXene material was cast directly onto the porous separator of the CDI cell without added binder, and, exhibited very stable performance over 30 CDI cycles with an average salt adsorption capacity of 13 +/- 2 mg g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2016, "Volume": 4, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18265, "End Page": 18271, "Article Number": null, "DOI": "10.1039/c6ta07833h", "DOI Link": "http://dx.doi.org/10.1039/c6ta07833h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390083200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leverett, J; Tran-Phu, T; Yuwono, JA; Kumar, P; Kim, C; Zhai, QF; Han, C; Qu, JT; Cairney, J; Simonov, AN; Hocking, RK; Dai, LM; Daiyan, R; Amal, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leverett, Josh; Thanh Tran-Phu; Yuwono, Jodie A.; Kumar, Priyank; Kim, Changmin; Zhai, Qingfeng; Han, Chen; Qu, Jiangtao; Cairney, Julie; Simonov, Alexandr N.; Hocking, Rosalie K.; Dai, Liming; Daiyan, Rahman; Amal, Rose", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the Coordination Structure of Cu-N-C Single Atom Catalysts for Simultaneous Electrochemical Reduction of CO2 and NO3- to Urea", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Closing both the carbon and nitrogen loops is a critical venture to support the establishment of the circular, net-zero carbon economy. Although single atom catalysts (SACs) have gained interest for the electrochemical reduction reactions of both carbon dioxide (CO2RR) and nitrate (NO3RR), the structure-activity relationship for Cu SAC coordination for these reactions remains unclear and should be explored such that a fundamental understanding is developed. To this end, the role of the Cu coordination structure is investigated in dictating the activity and selectivity for the CO2RR and NO3RR. In agreement with the density functional theory calculations, it is revealed that Cu-N-4 sites exhibit higher intrinsic activity toward the CO2RR, whilst both Cu-N-4 and Cu-N-4-(x)-C-x sites are active toward the NO3RR. Leveraging these findings, CO2RR and NO3RR are coupled for the formation of urea on Cu SACs, revealing the importance of *COOH binding as a critical parameter determining the catalytic activity for urea production. To the best of the authors' knowledge, this is the first report employing SACs for electrochemical urea synthesis from CO2RR and NO3RR, which achieves a Faradaic efficiency of 28% for urea production with a current density of -27 mA cm(-2) at -0.9 V versus the reversible hydrogen electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 12, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201500, "DOI": "10.1002/aenm.202201500", "DOI Link": "http://dx.doi.org/10.1002/aenm.202201500", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000823857400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, MD; Wang, HL; Yang, YY; Liang, CM; Bai, WB; Yan, Z; Li, HB; Xue, YG; Wang, XL; Akar, B; Zhao, HB; Luan, HW; Lim, J; Kandela, I; Ameer, GA; Zhang, YH; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Mengdi; Wang, Heling; Yang, Yiyuan; Liang, Cunman; Bai, Wubin; Yan, Zheng; Li, Haibo; Xue, Yeguang; Wang, Xinlong; Akar, Banu; Zhao, Hangbo; Luan, Haiwen; Lim, Jaeman; Kandela, Irawati; Ameer, Guillermo A.; Zhang, Yihui; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional piezoelectric polymer microsystems for vibrational energy harvesting, robotic interfaces and biomedical implants", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric microsystems are of use in areas such as mechanical sensing, energy conversion and robotics. The systems typically have a planar structure, but transforming them into complex three-dimensional (3D) frameworks could enhance and extend their various modes of operation. Here, we report a controlled, nonlinear buckling process to convert lithographically defined two-dimensional patterns of electrodes and thin films of piezoelectric polymers into sophisticated 3D piezoelectric microsystems. To illustrate the engineering versatility of the approach, we create more than twenty different 3D geometries. With these structures, we then demonstrate applications in energy harvesting with tailored mechanical properties and root-mean-square voltages ranging from 2 mV to 790 mV, in multifunctional sensors for robotic prosthetic interfaces with improved responsivity (for example, anisotropic responses and sensitivity of 60 mV N-1 for normal force), and in bio-integrated devices with in vivo operational capabilities. The 3D geometries, especially those with ultralow stiffnesses or asymmetric layouts, yield unique mechanical attributes and levels of functionality that would be difficult or impossible to achieve with conventional two-dimensional designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26, "End Page": 35, "Article Number": null, "DOI": "10.1038/s41928-018-0189-7", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0189-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455967900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, YW; Zhang, LL; Xing, J; Utama, MIB; Lu, X; Du, KZ; Li, YM; Hu, X; Wang, SJ; Genç, A; Dunin-Borkowski, R; Arbiol, J; Xiong, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Yanwen; Zhang, Lulu; Xing, Jun; Utama, M. Iqbal Bakti; Lu, Xin; Du, Kezhao; Li, Yongmei; Hu, Xiao; Wang, Shijie; Genc, Aziz; Dunin-Borkowski, Rafal; Arbiol, Jordi; Xiong, Qihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-yield synthesis and optical properties of g-C3N4", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphitic carbon nitride (g-C3N4), a metal-free semiconductor with a band gap of 2.7 eV, has received considerable attention owing to its fascinating photocatalytic performances under visible-light. g-C3N4 exhibits high thermal and chemical stability and non-toxicity such that it has been considered as the most promising photocatalyst for environmental improvement and energy conservation. Hence, it is of great importance to obtain high-quality g-C3N4 and gain a clear understanding of its optical properties. Herein, we report a high-yield synthesis of g-C3N4 products via heating of high vacuum-sealed melamine powder in an ampoule at temperatures between 450 and 650 degrees C. Using transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), electron energy loss spectroscopy (EELS), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), the chemical composition and crystallization of the as-produced g-C3N4 are demonstrated. A systematic optical study of g-C3N4 is carried out with several approaches. The optical phonon behavior of g-C3N4 is revealed by infrared and Raman spectroscopy, and the emission properties of g-C3N4 are investigated using photoluminescence (PL) spectroscopy, while the photocatalytic properties are explored by the photodegradation experiment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12343, "End Page": 12350, "Article Number": null, "DOI": "10.1039/c5nr02905h", "DOI Link": "http://dx.doi.org/10.1039/c5nr02905h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358207700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, CC; Wu, XD; Tang, L; Chen, XH; Li, M; Mou, Y; Su, B; Wang, SB; Feng, CY; Liu, JW; Yuan, XZ; Zhao, YL; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Chencheng; Wu, Xiaodong; Tang, Lin; Chen, Xiaohong; Li, Miao; Mou, Yi; Su, Bo; Wang, Sibo; Feng, Chengyang; Liu, Jiawei; Yuan, Xingzhong; Zhao, Yanli; Wang, Hou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual donor-acceptor covalent organic frameworks for hydrogen peroxide photosynthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing photocatalytically active and stable covalent organic frameworks containing both oxidative and reductive reaction centers remain a challenge. In this study, benzotrithiophene-based covalent organic frameworks with spatially separated redox centers are rationally designed for the photocatalytic production of hydrogen peroxide from water and oxygen without sacrificial agents. The triazine-containing framework demonstrates high selectivity for H2O2 photogeneration, with a yield rate of 2111 mu Mh(-1) (21.11 mu mol h(-1) and 1407 mu mol g(-1) h(-1)) and a solar-to-chemical conversion efficiency of 0.296%. Codirectional charge transfer and large energetic differences between linkages and linkers are verified in the double donor-acceptor structures of periodic frameworks. The active sites are mainly concentrated on the electron-acceptor fragments near the imine bond, which regulate the electron distribution of adjacent carbon atoms to optimally reduce the Gibbs free energy of O-2* and OOH* intermediates during the formation of H2O2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5238, "DOI": "10.1038/s41467-023-40991-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40991-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057573200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Adelnia, H; Ensandoost, R; Moonshi, SS; Gavgani, JN; Vasafi, EI; Ta, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Adelnia, Hossein; Ensandoost, Reza; Moonshi, Shehzahdi Shebbrin; Gavgani, Jaber Nasrollah; Vasafi, Emad Izadi; Ta, Hang Thu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Freeze/thawed polyvinyl alcohol hydrogels: Present, past and future", "Source Title": "EUROPEAN POLYMER JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A comprehensive review of polyvinyl alcohol (PVA) hydrogels prepared by the freezing/thawing (F-T) process is presented. We discuss their preparation, gelation mechanisms, handling of physical/mechanical properties, physicochemical characteristics, and various applications. PVA gelation through repeated F-T occurs without an externally added crosslinking agent due to the molecular structure and ability of PVA solutions to crystallize, resulting in ultrapure hydrogels. Gelation factors such as F-T cycle number, maximum and minimum temperature used, cycle duration, as well as molecular characteristics of the employed PVA samples, such as the average molecular weight, and the degree of hydrolysis, enable precise tuning of crystallization, hydrogen bonding as well as the final hydrogel properties. Incorporation of a second polymer and/or nulloparticles, which respectively results in interpenetrating polymer networks and nullocomposites, further facilitates obtaining desirable final properties to customize the gels for variety of applications. Facile customizability of the properties along with biocompatibility of PVA has led to the development of diverse prosthetic materials ranging from vascular stents, cartilages, and even contact lenses. In addition, PVA hydrogels have also been under investigation for drug delivery vehicles, and wound dressings. Furthermore, PVA hydrogels may possess a variety of other interesting features such as autonomous self-healing ability and programmed shape memory characteristic. As such PVA hydrogels can be used as components in actuators. Applications of the F-T PVA hydrogels in ionically conductive and photonic crystal-based sensors are also discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2022, "Volume": 164, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110974, "DOI": "10.1016/j.eurpolymj.2021.110974", "DOI Link": "http://dx.doi.org/10.1016/j.eurpolymj.2021.110974", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742708100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Han, C; Cao, WQ; Cao, MS; Yang, HJ; Yuan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Min; Han, Chen; Cao, Wen-Qiang; Cao, Mao-Sheng; Yang, Hui-Jing; Yuan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A nullo-Micro Engineering nullofiber for Electromagnetic Absorber, Green Shielding and Sensor", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is extremely unattainable for a material to simultaneously obtain efficient electromagnetic (EM) absorption and green shielding performance, which has not been reported due to the competition between conduction loss and reflection. Herein, by tailoring the internal structure through nullo-micro engineering, a NiCo2O4 nullofiber with integrated EM absorbing and green shielding as well as strain sensing functions is obtained. With the improvement of charge transport capability of the nullofiber, the performance can be converted from EM absorption to shielding, or even coexist. Particularly, as the conductivity rising, the reflection loss declines from - 52.72 to - 10.5 dB, while the EM interference shielding effectiveness increases to 13.4 dB, suggesting the coexistence of the two EM functions. Furthermore, based on the high EM absorption, a strain sensor is designed through the resonullce coupling of the patterned NiCo2O4 structure. These strategies for tuning EM performance and constructing devices can be extended to other EM functional materials to promote the development of electromagnetic driven devices. Graphic", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27, "DOI": "10.1007/s40820-020-00552-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00552-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595119300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Zha, XH; Chen, FY; Ye, Q; Eklund, P; Du, SY; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jie; Zha, Xianhu; Chen, Fan Y.; Ye, Qun; Eklund, Per; Du, Shiyu; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Two-Dimensional Zirconium Carbide by Selective Etching of Al3C3 from nullolaminated Zr3Al3C5", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The room-temperature synthesis of a new two-dimensional (2D) zirconium-containing carbide, Zr3C2Tz MXene is presented. In contrast to traditional preparation of MXene, the layered ternary Zr3Al3C5 material instead of MAX phases is used as source under hydrofluoric acid treatment. The structural, mechanical, and electronic properties of the synthesized 2D carbide are investigated, combined with first-principles density functional calculations. A comparative study on the structrual stability of our obtained 2D Zr3C2Tz and Ti3C2Tz MXenes at elevated temperatures is performed. The obtained 2D Zr3C2Tz exhibits relatively better ability to maintain 2D nature and strucural integrity compared to Ti-based Mxene. The difference in structural stability under high temperature condition is explained by a theoretical investigation on binding energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 488, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2016, "Volume": 55, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5008, "End Page": 5013, "Article Number": null, "DOI": "10.1002/anie.201510432", "DOI Link": "http://dx.doi.org/10.1002/anie.201510432", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374496100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YZ; Deak, N; Wang, ZW; Yu, HP; Hameleers, L; Jurak, E; Deuss, PJ; Barta, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yongzhuang; Deak, Noemi; Wang, Zhiwen; Yu, Haipeng; Hameleers, Lisanne; Jurak, Edita; Deuss, Peter J.; Barta, Katalin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable and functional deep eutectic solvents for lignocellulose valorization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilization of reactive intermediates is an enabling concept in biomass fractionation and depolymerization. Deep eutectic solvents (DES) are intriguing green reaction media for biomass processing; however undesired lignin condensation is a typical drawback for most acid-based DES fractionation processes. Here we describe ternary DES systems composed of choline chloride and oxalic acid, additionally incorporating ethylene glycol (or other diols) that provide the desired 'stabilization' function for efficient lignocellulose fractionation, preserving the quality of all lignocellulose constituents. The obtained ethylene-glycol protected lignin displays high beta-O-4 content (up to 53 per 100 aromatic units) and can be readily depolymerized to distinct monophenolic products. The cellulose residues, free from condensed lignin particles, deliver up to 95.9 +/- 2.12% glucose yield upon enzymatic digestion. The DES can be recovered with high yield and purity and re-used with good efficiency. Notably, we have shown that the reactivity of the beta-O-4 linkage in model compounds can be steered towards either cleavage or stabilization, depending on DES composition, demonstrating the advantage of the modular DES composition. Deep eutectic solvents (DES) are intriguing green reaction media for biomass processing, however, undesired lignin condensation is a typical drawback. Here the authors develop a tunable ternary DES system that allows for stabilization of reactive intermediates for efficient lignocellulose fractionation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5424, "DOI": "10.1038/s41467-021-25117-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25117-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696024700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, N; Feng, XB; Rao, DW; Deng, X; Cai, LJ; Qiu, BC; Long, R; Xiong, YJ; Lu, Y; Chai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ning; Feng, Xiaobin; Rao, Dewei; Deng, Xi; Cai, Lejuan; Qiu, Bocheng; Long, Ran; Xiong, Yujie; Lu, Yang; Chai, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anodic oxygen evolution reaction (OER) is recognized as kinetic bottleneck in water electrolysis. Transition metal sites with high valence states can accelerate the reaction kinetics to offer highly intrinsic activity, but suffer from thermodynamic formation barrier. Here, we show subtle engineering of highly oxidized Ni4+ species in surface reconstructed (oxy)hydroxides on multicomponent FeCoCrNi alloy film through interatomically electronic interplay. Our spectroscopic investigations with theoretical studies uncover that Fe component enables the formation of Ni4+ species, which is energetically favored by the multistep evolution of Ni2+-> Ni3+-> Ni4+. The dynamically constructed Ni4+ species drives holes into oxygen ligands to facilitate intramolecular oxygen coupling, triggering lattice oxygen activation to form Fe-Ni dual-sites as ultimate catalytic center with highly intrinsic activity. As a result, the surface reconstructed FeCoCrNi OER catalyst delivers outstanding mass activity and turnover frequency of 3601A g(metal)(-1) and 0.483s(-1) at an overpotential of 300mV in alkaline electrolyte, respectively. Electrocatalytic water oxidation is facilitated by high valence states, but these are challenging to achieve at low applied potentials. Here, authors report a multicomponent FeCoCrNi alloy with dynamically formed Ni4+ species to offer high catalytic activity via lattice oxygen activation mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4066, "DOI": "10.1038/s41467-020-17934-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17934-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564248600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HX; Li, SQ; Wang, WW; Yu, WZ; Zhang, WJ; Ma, C; Jia, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hao-Xin; Li, Shan-Qing; Wang, Wei-Wei; Yu, Wen-Zhu; Zhang, Wu-Jun; Ma, Chao; Jia, Chun-Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Partially sintered copper-ceria as excellent catalyst for the high-temperature reverse water gas shift reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing stable active sites in catalysts for high temperature catalytic reactions remains challenging. Here, the authors manage to make stable copper clusters in the copper-ceria catalyst with high Cu loading (15 wt.%) for the high-temperature reverse water gas shift reaction. For high-temperature catalytic reaction, it is of significant importance and challenge to construct stable active sites in catalysts. Herein, we report the construction of sufficient and stable copper clusters in the copper-ceria catalyst with high Cu loading (15 wt.%) for the high-temperature reverse water gas shift (RWGS) reaction. Under very harsh working conditions, the ceria nullorods suffered a partial sintering, on which the 2D and 3D copper clusters were formed. This partially sintered catalyst exhibits unmatched activity and excellent durability at high temperature. The interaction between the copper and ceria ensures the copper clusters stably anchored on the surface of ceria. Abundant in situ generated and consumed surface oxygen vacancies form synergistic effect with adjacent copper clusters to promote the reaction process. This work investigates the structure-function relation of the catalyst with sintered and inhomogeneous structure and explores the potential application of the sintered catalyst in C1 chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 867, "DOI": "10.1038/s41467-022-28476-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28476-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000755220500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, QH; Qi, RJ; Feng, XC; Wang, J; Li, Y; Yao, ZP; Wang, X; Li, QQ; Lu, XG; Zhang, JJ; Zhao, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Qinhao; Qi, Ruijuan; Feng, Xiaochen; Wang, Jing; Li, Yong; Yao, Zhenpeng; Wang, Xuan; Li, Qianqian; Lu, Xionggang; Zhang, Jiujun; Zhao, Yufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of sodium-based batteries in grid-scale energy storage requires electrode materials that facilitate fast and stable charge storage at various temperatures. However, this goal is not entirely achievable in the case of P2-type layered transition-metal oxides because of the sluggish kinetics and unfavorable electrode|electrolyte interphase formation. To circumvent these issues, we propose a P2-type Na0.78Ni0.31Mn0.67Nb0.02O2 (P2-NaMNNb) cathode active material where the niobium doping enables reduction in the electronic band gap and ionic diffusion energy barrier while favoring the Na-ion mobility. Via physicochemical characterizations and theoretical calculations, we demonstrate that the niobium induces atomic scale surface reorganization, hindering metal dissolution from the cathode into the electrolyte. We also report the testing of the cathode material in coin cell configuration using Na metal or hard carbon as anode active materials and ether-based electrolyte solutions. Interestingly, the Na||P2-NaMNNb cell can be cycled up to 9.2 A g(-1) (50 C), showing a discharge capacity of approximately 65 mAh g(-1) at 25 degrees C. Furthermore, the Na||P2-NaMNNb cell can also be charged/discharged for 1800 cycles at 368 mA g(-1) and -40 degrees C, demonstrating a capacity retention of approximately 76% and a final discharge capacity of approximately 70 mAh g(-1). The practical application of sodium-ion batteries at subzero temperatures is hindered by the slow Na-ion transfer kinetics. Here, the authors reported the niobium doping of P2-type cathode active material capable of efficient battery cycling at low temperatures such as -40 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3205, "DOI": "10.1038/s41467-022-30942-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30942-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, GY; Ding, GQ; Li, J; Yao, KL; Wu, MH; Qian, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Guoying; Ding, Guangqian; Li, Jie; Yao, Kailun; Wu, Menghao; Qian, Meichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolayer MXenes: promising half-metals and spin gapless semiconductors", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Half-metals and spin gapless semiconductors are promising candidates for spintronic applications due to the complete (100%) spin polarization of electrons around the Fermi level. Based on recent experimental and theoretical findings of graphene-like monolayer transition metal carbides and nitrides (also known as MXenes), we demonstrate using first-principles calculations that monolayers Ti2C and Ti2N exhibit nearly half-metallic ferromagnetism with the magnetic moments of 1.91 and 1.00 mu B per formula unit, respectively, while monolayer V2C is a metal with unstable antiferromagnetism, and monolayer V2N is a nonmagnetic metal. Interestingly, under a biaxial strain, there is a phase transition from a nearly half-metal to truly half-metal, spin gapless semiconductor, and metal for monolayer Ti2C. Monolayer Ti2N is still a nearly half-metal under a suitable biaxial strain. Large magnetic moments can be induced by the biaxial tensile and compressive strains for monolayer V2C and V2N, respectively. We also show that the structures of these four monolayer MXenes are stable according to the calculated formation energy and phonon spectrum. Our investigations suggest that, unlike monolayer graphene, monolayer MXenes Ti2C and Ti2N without vacancy, doping or external electric field exhibit intrinsic magnetism, especially the half-metallic ferromagnetism and spin gapless semiconductivity, which will stimulate further studies on possible spintronic applications for new two-dimensional materials of MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8986, "End Page": 8994, "Article Number": null, "DOI": "10.1039/c6nr01333c", "DOI Link": "http://dx.doi.org/10.1039/c6nr01333c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374788800067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, H; Susha, AS; Kershaw, SV; Hung, TF; Rogach, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, He; Susha, Andrei S.; Kershaw, Stephen V.; Hung, Tak Fu; Rogach, Andrey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of Emission Color of High Quantum Yield CH3 NH3 PbBr3 Perovskite Quantum Dots by Precipitation Temperature", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 532, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500194, "DOI": "10.1002/advs.201500194", "DOI Link": "http://dx.doi.org/10.1002/advs.201500194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368998500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XB; Stepanov, P; Yang, W; Xie, M; Aamir, MA; Das, I; Urgell, C; Watanabe, K; Taniguchi, T; Zhang, GY; Bachtold, A; MacDonald, AH; Efetov, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xiaobo; Stepanov, Petr; Yang, Wei; Xie, Ming; Aamir, Mohammed Ali; Das, Ipsita; Urgell, Carles; Watanabe, Kenji; Taniguchi, Takashi; Zhang, Guangyu; Bachtold, Adrian; MacDonald, Allan H.; Efetov, Dmitri K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductors, orbital magnets and correlated states in magic-angle bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductivity can occur under conditions approaching broken-symmetry parent states(1). In bilayer graphene, the twisting of one layer with respect to the other at 'magic' twist angles of around 1 degree leads to the emergence of ultra-flat moire superlattice minibands. Such bands are a rich and highly tunable source of strong-correlation physics(2-5), notably superconductivity, which emerges close to interaction-induced insulating states(6,7). Here we report the fabrication of magic-angle twisted bilayer graphene devices with highly uniform twist angles. The reduction in twist-angle disorder reveals the presence of insulating states at all integer occupancies of the fourfold spin-valley degenerate flat conduction and valence bands-that is, at moire band filling factors nu = 0, +/- 1, +/- 2, +/- 3. At nu approximate to -2, superconductivity is observed below critical temperatures of up to 3 kelvin. We also observe three new superconducting domes at much lower temperatures, close to the nu = 0 and. = +/- 1 insulating states. Notably, at nu = +/- 1 we find states with non-zero Chern numbers. For nu = -1 the insulating state exhibits a sharp hysteretic resistance enhancement when a perpendicular magnetic field greater than 3.6 tesla is applied, which is consistent with a field-driven phase transition. Our study shows that broken-symmetry states, interaction-driven insulators, orbital magnets, states with non-zero Chern numbers and superconducting domes occur frequently across a wide range of moire flat band fillings, including close to charge neutrality. This study provides a more detailed view of the phenomenology of magic-angle twisted bilayer graphene, adding to our evolving understanding of its emergent properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1191, "Times Cited, All Databases": 1283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2019, "Volume": 574, "Issue": 7780, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 653, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1695-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1695-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493807800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XK; Liu, JZ; Li, DD; Huang, SQ; Huang, K; Zhang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xinkai; Liu, Jize; Li, Dongdong; Huang, Shaoquan; Huang, Kai; Zhang, Xinxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired Multi-Stimuli Responsive Actuators with Synergistic Color- and Morphing-Change Abilities", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The combination of complex perception, defense, and camouflage mechanisms is a pivotal instinctive ability that equips organisms with survival advantages. The simulations of such fascinating multi-stimuli responsiveness, including thigmotropism, bioluminescence, color-changing ability, and so on, are of great significance for scientists to develop novel biomimetic smart materials. However, most biomimetic color-changing or luminescence materials can only realize a single stimulus-response, hence the design and fabrication of multi-stimuli responsive materials with synergistic color-changing are still on the way. Here, a bioinspired multi-stimuli responsive actuator with color- and morphing-change abilities is developed by taking advantage of the assembled cellulose nullocrystals-based cholesteric liquid crystal structure and its water/temperature response behaviors. The actuator exhibits superfast, reversible bi-directional humidity and near-infrared (NIR) light actuating ability (humidity: 9 s; NIR light: 16 s), accompanying with synergistic iridescent appearance which provides a visual cue for the movement of actuators. This work paves the way for biomimetic multi-stimuli responsive materials and will have a wide range of applications such as optical anti-counterfeiting devices, information storage materials, and smart soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101295, "DOI": "10.1002/advs.202101295", "DOI Link": "http://dx.doi.org/10.1002/advs.202101295", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659721000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, XY; Zhao, YF; Shi, R; Yin, WJ; Zhao, YX; Waterhouse, GIN; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Xuyang; Zhao, Yufei; Shi, Run; Yin, Wenjin; Zhao, Yunxuan; Waterhouse, Geoffrey I. N.; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective photocatalytic CO2 reduction over Zn-based layered double hydroxides containing tri or tetravalent metals", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic CO2 reduction holds promise as a future technology for the manufacture of fuels and commodity chemicals. However, factors controlling product selectivity remain poorly understood. Herein, we compared the performance of a homologous series of Zn-based layered double hydroxide (ZnM-LDH) photocatalysts for CO2 reduction. By varying the trivalent or tetravalent metal cations in the ZnM-LDH photocatalysts (M = Ti4+, Fe3+, Co3+, Ga3+, Al3+), the product selectivity of the reaction could be precisely controlled. ZnTi-LDH afforded CH4 as the main reduction product; ZnFe-LDH and ZnCo-LDH yielded H2 exclusively from water splitting; whilst ZnGa-LDH and ZnAI-LDH generated CO. In-situ diffuse reflectance infrared measurements, valence band XPS and density function theory calculations were applied to rationalize the CO2 reduction selectivities of the different ZnM-LDH photocatalysts. The analyses revealed that the d-band center (epsilon(d)) position of the M3+ or M4+ cations controlled the adsorption strength of CO2 and thus the selectivity to carbon-containing products or H-2. Cations with d-band centers relatively close to the Fermi level (Ti4+, Ga3+ and Al4+) adsorbed CO2 strongly yielding CH4 or CO, whereas metal cations with d-band centers further from the Fermi level (Fe3+ and Co3+) adsorbed CO2 poorly, thereby yielding H-2 only (from water splitting). Our findings clarify the role of trivalent and tetravalent metal cations in LDH photocatalysts for the selective CO2 reduction, paving new ways for the development of improved LDH photocatalyst with high selectivities to specific products. (C) 2020 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2020, "Volume": 65, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 987, "End Page": 994, "Article Number": null, "DOI": "10.1016/j.scib.2020.03.032", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2020.03.032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533609300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; nullgreave, J; Liu, Y; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fei; nullgreave, Jeanette; Liu, Yan; Yan, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural DNA nullotechnology: State of the Art and Future Perspective", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past three decades DNA has emerged as an exceptional molecular building block for nulloconstruction due to its predictable conformation and programmable intra- and intermolecular Watson Crick base-pairing interactions. A variety of convenient design rules and reliable assembly methods have been developed to engineer DNA nullostructures of increasing complexity. The ability to create designer DNA architectures with accurate spatial control has allowed researchers to explore novel applications in many directions, such as directed material assembly, structural biology, biocatalysis, DNA computing, nullorobotics, disease diagnosis, and drug delivery. This Perspective discusses the state of the art in the field of structural DNA nullotechnology and presents some of the challenges and opportunities that exist in DNA-based molecular design and programming.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 468, "Times Cited, All Databases": 547, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2014, "Volume": 136, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11198, "End Page": 11211, "Article Number": null, "DOI": "10.1021/ja505101a", "DOI Link": "http://dx.doi.org/10.1021/ja505101a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340442700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, H; Wang, MY; Liu, HY; Liu, XS; Situ, A; Wu, B; Ji, ZX; Chang, CH; Nel, AE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Huan; Wang, Meiying; Liu, Huiyu; Liu, Xiangsheng; Situ, Allen; Wu, Bobby; Ji, Zhaoxia; Chang, Chong Hyun; Nel, Andre E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Use of a Lipid-Coated Mesoporous Silica nulloparticle Platform for Synergistic Gemcitabine and Paclitaxel Delivery to Human Pancreatic Cancer in Mice", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, a commercial albumin-bound paclitaxel (PTX) nullocarrier (Abraxane) was approved as the first new drug for pancreatic ductal adenocarcinoma in almost a decade. PTX improves the pharmaceutical efficacy of the first-line pancreatic cancer drug, gemcitabine (GEM), through suppression of the tumor stroma and inhibiting the expression of the GEM-inactivating enzyme, cytidine deaminase (CDA). We asked, therefore, whether it was possible to develop a mesoporous silica nulloparticle (MSNP) carrier for pancreatic cancer to co-deliver a synergistic GEM/PTX combination. High drug loading was achieved by a custom-designed coated lipid film technique to encapsulate a calculated dose of GEM (40 wt %) by using a supported lipid bilayer (LB). The uniform coating of the 65 nm nulloparticles by a lipid membrane allowed incorporation of a sublethal amount of hydrophobic PTX, which could be co-delivered with GEM in pancreatic cells and tumors. We demonstrate that ratiometric PTX incorporation and delivery by our LB-MSNP could suppress CDA expression, contemporaneous with induction of oxidative stress as the operating principle for PTX synergy. To demonstrate the in vivo efficacy, mice carrying subcutaneous PANC-1 xenografts received intravenous (IV) injection of PTX/GEM-loaded LB-MSNP. Drug co-delivery provided more effective tumor shrinkage than GEM-loaded LB-MSNP, free GEM, or free GEM plus Abraxane. Comparable tumor shrinkage required coadministration of 12 times the amount of free Abraxane. High-performance liquid chromatography analysis of tumor-associated GEM metabolites confirmed that, compared to free GEM, MSNP co-delivery increased the phosphorylated DNA-interactive GEM metabolite 13-fold and decreased the inactivated and deaminated metabolite 4-fold. IV injection of MSNP-delivered PTX/GEM in a PANC-1 orthotopic model effectively inhibited primary tumor growth and eliminated metastatic foci. The enhanced in vivo efficacy of the dual delivery carrier could be achieved with no evidence of local or systemic toxicity. In summary, we demonstrate the development of an effective LB-MSNP nullocarrier for synergistic PTX/GEM delivery in pancreatic cancer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3540, "End Page": 3557, "Article Number": null, "DOI": "10.1021/acsnullo.5b00510", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b00510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353867000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, BP; Liu, K; Li, HJW; Liu, CX; Fu, JW; Li, HM; Huang, JE; Ou, PF; Alkayyali, T; Cai, C; Duan, YX; Liu, H; An, PD; Zhang, N; Li, WZ; Qiu, XQ; Jia, CK; Hu, JH; Chai, LY; Lin, Z; Gao, YL; Miyauchi, M; Cortés, E; Maier, SA; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Baopeng; Liu, Kang; Li, HuangJingWei; Liu, Changxu; Fu, Junwei; Li, Hongmei; Huang, Jianull Erick; Ou, Pengfei; Alkayyali, Tartela; Cai, Chao; Duan, Yuxia; Liu, Hui; An, Pengda; Zhang, Ning; Li, Wenzhang; Qiu, Xiaoqing; Jia, Chuankun; Hu, Junhua; Chai, Liyuan; Lin, Zhang; Gao, Yongli; Miyauchi, Masahiro; Cortes, Emiliano; Maier, Stefan A.; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating CO2 Electroreduction to Multicarbon Products via Synergistic Electric-Thermal Field on Copper nulloneedles", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction is a promising way to mitigate CO2 emissions and close the anthropogenic carbon cycle. Among products from CO2RR, multicarbon chemicals, such as ethylene and ethanol with high energy density, are more valuable. However, the selectivity and reaction rate of C-2 production are unsatisfactory due to the sluggish thermodynamics and kinetics of C-C coupling. The electric field and thermal field have been studied and utilized to promote catalytic reactions, as they can regulate the thermodynamic and kinetic barriers of reactions. Either raising the potential or heating the electrolyte can enhance C-C coupling, but these come at the cost of increasing side reactions, such as the hydrogen evolution reaction. Here, we present a generic strategy to enhance the local electric field and temperature simultaneously and dramatically improve the electric-thermal synergy desired in electrocatalysis. A conformal coating of similar to 5 nm of polytetrafluoroethylene significantly improves the catalytic ability of copper nulloneedles (similar to 7-fold electric field and similar to 40 K temperature enhancement at the tips compared with bare copper nulloneedles experimentally), resulting in an improved C-2 Faradaic efficiency of over 86% at a partial current density of more than 250 mA cm(-2) and a record-high C-2 turnover frequency of 11.5 +/- 0.3 s(-1) Cu site(-1). Combined with its low cost and scalability, the electric-thermal strategy for a state-of-the-art catalyst not only offers new insight into improving activity and selectivity of value-added C-2 products as we demonstrated but also inspires advances in efficiency and/or selectivity of other valuable electro-/photocatalysis such as hydrogen evolution, nitrogen reduction, and hydrogen peroxide electrosynthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2022, "Volume": 144, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3039, "End Page": 3049, "Article Number": null, "DOI": "10.1021/jacs.1c11253", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c11253", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765779100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, KL; Xie, J; Luo, XY; Wen, JQ; Ma, S; Li, X; Fang, YP; Zhang, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Kelin; Xie, Jun; Luo, Xingyi; Wen, Jiuqing; Ma, Song; Li, Xin; Fang, Yueping; Zhang, Xiangchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced visible light photocatalytic H2 production over Z-scheme g-C3N4 nullsheets/WO3 nullorods nullocomposites loaded with Ni(OH)x cocatalysts", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel WO(3)g-C3N4Ni(OH)(x) hybrids have been successfully synthesized by a two-step strategy of high temperature calcination and in situ photodeposition. Their photocatalytic performance was investigated using TEOA as a hole scavenger under visible light irradiation. The loading of WO3 and Ni(OH)(x) cocatalysts boosted the photocatalytic H-2 evolution efficiency of g-C3N4. WO3/g-C3N4Ni(OH)(x) with 20 wt%defective WO3 and 4.8 wt%Ni(OH)(x) showed the highest hydrogen production rate of 576 mu mol/(gh), which was 5.7, 10.8 and 230 times higher than those of g-C3N4/4.8 wt%Ni(OH)(x), 20 wt%WO3C3N4 and g-C3N4 photocatalysts, respectively. The remarkably enhanced H2 evolution performance was ascribed to the combination effects of the Z-scheme heterojunction (WO3/g-C3N4) and loaded cocatalysts (Ni(OH)(x)), which effectively inhibited the recombination of the photoexcited electron-hole pairs of g-C3N4 and improved both H-2 evolution and TEOA oxidation kinetics. The electron spin resonullce spectra of O-2(-) and . OH radicals provided evidence for the Z-scheme charge separation mechanism. The loading of easily available Ni(OH)(x) cocatalysts on the Z-scheme WO3/g-C3N4 nullocomposites provided insights into constructing a robust multiple-heterojunction material for photocatalytic applications. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 38, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": 252, "Article Number": null, "DOI": "10.1016/S1872-2067(17)62759-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(17)62759-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396384300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YQ; Wang, H; Guo, J; Cheng, XQ; Han, G; Lau, CH; Lin, HQ; Liu, SM; Ma, J; Shao, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yanqiu; Wang, Hao; Guo, Jing; Cheng, Xiquan; Han, Gang; Lau, Cher Hon; Lin, Haiqing; Liu, Shaomin; Ma, Jun; Shao, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ice-confined synthesis of highly ionized 3D-quasilayered polyamide nullofiltration membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Existing polyamide (PA) membrane synthesis protocols are underpinned by controlling diffusion-dominullt liquid-phase reactions that yield subpar spatial architectures and ionization behavior. We report an ice-confined interfacial polymerization strategy to enable the effective kinetic control of the interfacial reaction and thermodynamic manipulation of the hexagonal polytype (I-h) ice phase containing monomers to rationally synthesize a three-dimensional quasilayered PA membrane for nullofiltration. Experiments and molecular simulations confirmed the underlying membrane formation mechanism. Our ice-confined PA nullofiltration membrane features high-density ionized structure and exceptional transport channels, realizing superior water permeance and excellent ion selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2023, "Volume": 382, "Issue": 6667, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 202, "End Page": 206, "Article Number": null, "DOI": "10.1126/science.adi9531", "DOI Link": "http://dx.doi.org/10.1126/science.adi9531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001112161200031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JJ; Wang, ZM; Xu, L; Wang, AC; Han, K; Jiang, T; Lai, QS; Bai, Y; Tang, W; Fan, FR; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jianjun; Wang, Ziming; Xu, Liang; Wang, Aurelia Chi; Han, Kai; Jiang, Tao; Lai, Qingsong; Bai, Yu; Tang, Wei; Fan, Feng Ru; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible and durable wood-based triboelectric nullogenerators for self-powered sensing in athletic big data analytics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the new era of internet of things, big data collection and analysis based on widely distributed intelligent sensing technology is particularly important. Here, we report a flexible and durable wood-based triboelectric nullogenerator for self-powered sensing in athletic big data analytics. Based on a simple and effective strategy, natural wood can be converted into a high-performance triboelectric material with excellent mechanical properties, such as 7.5-fold enhancement in strength, superior flexibility, wear resistance and processability. The electrical output performance is also enhanced by more than 70% compared with natural wood. A self-powered falling point distribution statistical system and an edge ball judgement system are further developed to provide training guidance and real-time competition assistance for both athletes and referees. This work can not only expand the application area of the self-powered system to smart sport monitoring and assisting, but also promote the development of big data analytics in intelligent sports industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5147, "DOI": "10.1038/s41467-019-13166-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13166-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498693600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Walker, DA; Hedrick, JL; Mirkin, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Walker, David A.; Hedrick, James L.; Mirkin, Chad A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid, large-volume, thermally controlled 3D printing using a mobile liquid interface", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a stereolithographic three-dimensional printing approach for polymeric components that uses a mobile liquid interface (a fluorinated oil) to reduce the adhesive forces between the interface and the printed object, thereby allowing for a continuous and rapid print process, regardless of polymeric precursor. The bed area is not size-restricted by thermal limitations because the flowing oil enables direct cooling across the entire print area. Continuous vertical print rates exceeding 430 millimeters per hour with a volumetric throughput of 100 liters per hour have been demonstrated, and proof-of-concept structures made from hard plastics, ceramic precursors, and elastomers have been printed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2019, "Volume": 366, "Issue": 6463, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 360, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax1562", "DOI Link": "http://dx.doi.org/10.1126/science.aax1562", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491290000050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lynam, JG; Kumar, N; Wong, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lynam, Joan G.; Kumar, Narendra; Wong, Mark J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep eutectic solvents' ability to solubilize lignin, cellulose, and hemicellulose; thermal stability; and density", "Source Title": "BIORESOURCE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An environmentally-friendly method to separate cellulose and hemicelluloses from lignin in recalcitrant biomass for subsequent conversion is desirable to reduce greenhouse gas generation. Easily-prepared, deep eutectic solvents (DESs) have low volatility, wide liquid range, non-flammability, nontoxicity, biocompatibility, and biodegradability. This study shows the DESs (formic acid: choline chloride, lactic acid: choline chloride, acetic acid: choline chloride, lactic acid: betaine, and lactic acid: proline) to be capable of preferentially dissolving lignin at 60 degrees C. Thermogravimetric analysis show DES to be stable at typical biomass processing temperatures. Pretreating loblolly pine in one DES increased glucose yield after enzymatic hydrolysis to more than seven times that of raw or glycerol-pretreated pine. The density of DES-pretreated biomass was found to be 40% higher than the untreated pine's density. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 238, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 684, "End Page": 689, "Article Number": null, "DOI": "10.1016/j.biortech.2017.04.079", "DOI Link": "http://dx.doi.org/10.1016/j.biortech.2017.04.079", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402485500081", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Han, N; Deng, J; Wu, JH; Wang, Y; Hu, YP; Ding, P; Li, YF; Li, YG; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hui; Han, Na; Deng, Jun; Wu, Jinghua; Wang, Yu; Hu, Yongpan; Ding, Pan; Li, Yafei; Li, Yanguang; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective CO2 Reduction on 2D Mesoporous Bi nullosheets", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of CO2 to value-added products using electrical or solar energy represents an attractive means for the capture and utilization of atmospheric CO2. Formate is a popular product from CO2 reduction, but its reaction selectivity is usually unsatisfactory. Tin-based materials have attracted the most attention for formate production at present. Unfortunately, most of them only exhibit moderate selectivity in a narrow and highly cathodic potential window. In this study, it is demonstrated that traditionally under-explored bismuth has a much greater potential for formate production than tin or other materials. Mesoporous bismuth nullosheets are prepared here by the cathodic transformation of atomic-thick bismuth oxycarbonate nullosheets. They enable the selective CO2 reduction to formate with large current density, excellent Faradaic efficiency (approximate to 100%) over a broad potential window and great operation stability. Moreover, Bi nullosheets are integrated with an oxygen evolution reaction electrocatalyst in full cells, and achieve efficient and robust solar conversion of CO2/H2O to formate/O-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 8, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801536, "DOI": "10.1002/aenm.201801536", "DOI Link": "http://dx.doi.org/10.1002/aenm.201801536", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453273200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, GH; Zhao, Y; Yang, F; Zhang, Y; Zhou, M; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Gehuan; Zhao, Yue; Yang, Feng; Zhang, Yi; Zhou, Ming; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Integrated Transparent Film for Efficient Electromagnetic Protection", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silver nullowire (Ag NW) has been considered as the promising building block for the fabrication of transparent electromagnetic interference (EMI) shielding films. However, the practical application of Ag NW-based EMI shielding films has been restricted due to the unsatisfactory stability of Ag NW. Herein, we proposed a reduced graphene oxide (rGO) decorated Ag NW film, which realizes a seamless integration of optical transparency, highly efficient EMI shielding, reliable durability and stability. The Ag NW constructs a highly transparent and conductive network, and the rGO provides additional conductive path, showing a superior EMI shielding effectiveness (SE) of 33.62 dB at transmittance of 81.9%. In addition, the top rGO layer enables the hybrid film with reliable durability and chemical stability, which can maintain 96% and 90% EMI SE after 1000 times bending cycles at radius of 2 mm and exposure in air for 80 days. Furthermore, the rGO/Ag NW films also possess fast thermal response and heating stability, making them highly applicable in wearable devices. The synergy of Ag NW and rGO grants the hybrid EMI shielding film multiple desired functions and meanwhile overcomes the shortcomings of Ag NW. This work provides a reference for preparing multifunctional integrated transparent EMI shielding film.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 65, "DOI": "10.1007/s40820-022-00810-y", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00810-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760258300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, JZ; Xiong, M; Fan, K; Bao, CX; Xin, DY; Pan, ZW; Fei, LF; Huang, HT; Zhou, L; Yao, K; Zheng, XJ; Shen, L; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jizhong; Xiong, Min; Fan, Ke; Bao, Chunxiong; Xin, Deyu; Pan, Zhengwei; Fei, Linfeng; Huang, Haitao; Zhou, Lang; Yao, Kai; Zheng, Xiaojia; Shen, Liang; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic strain engineering of perovskite single crystals for highly stable and sensitive X-ray detectors with low-bias imaging and monitoring", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray detectors based on dual-site-doped perovskite single crystals exhibit excellent sensitivity of 2.6 x 10(4) mu C Gy(air)(-1) cm(-2) under a low field of 1 V cm(-1). The detectable dose rate is as low as 7.09 nGy(air) s(-1). The operational stability is beyond half a year. Although three-dimensional metal halide perovskite (ABX(3)) single crystals are promising next-generation materials for radiation detection, state-of-the-art perovskite X-ray detectors include methylammonium as A-site cations, limiting the operational stability. Previous efforts to improve the stability using formamidinium-caesium-alloyed A-site cations usually sacrifice the detection performance because of high trap densities. Here we successfully solve this trade-off between stability and detection performance by synergistic composition engineering, where we include A-site alloys to decrease the trap density and B-site dopants to release the microstrain induced by A-site alloying. As such, we develop high-performance perovskite X-ray detectors with excellent stability. Our X-ray detectors exhibit high sensitivity of (2.6 +/- 0.1) x 10(4) mu C Gy(air)(-1) cm(-2) under 1 V cm(-1) and ultralow limit of detection of 7.09 nGy(air) s(-1). In addition, they feature long-term operational stability over half a year and impressive thermal stability up to 125 degrees C. We further demonstrate the promise of our perovskite X-ray detectors for low-bias portable applications with high-quality X-ray imaging and monitoring prototypes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 16, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 575, "End Page": 581, "Article Number": null, "DOI": "10.1038/s41566-022-01024-9", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01024-9", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826792400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zi, YL; Niu, SM; Wang, J; Wen, Z; Tang, W; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zi, Yunlong; Niu, Simiao; Wang, Jie; Wen, Zhen; Tang, Wei; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Standards and figure-of-merits for quantifying the performance of triboelectric nullogenerators", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerators have been invented as a highly efficient, cost-effective and easy scalable energy-harvesting technology for converting ambient mechanical energy into electricity. Four basic working modes have been demonstrated, each of which has different designs to accommodate the corresponding mechanical triggering conditions. A common standard is thus required to quantify the performance of the triboelectric nullogenerators so that their outputs can be compared and evaluated. Here we report figure-of-merits for defining the performance of a triboelectric nullogenerator, which is composed of a structural figure-of-merit related to the structure and a material figure of merit that is the square of the surface charge density. The structural figure-of-merit is derived and simulated to compare the triboelectric nullogenerators with different configurations. A standard method is introduced to quantify the material figure-of-merit for a general surface. This study is likely to establish the standards for developing TENGs towards practical applications and industrialization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 694, "Times Cited, All Databases": 723, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8376, "DOI": "10.1038/ncomms9376", "DOI Link": "http://dx.doi.org/10.1038/ncomms9376", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363135500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, S; Zuo, YX; Abu-Odeh, A; Zheng, H; Li, XG; Ding, J; Ong, SP; Asta, M; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Sheng; Zuo, Yunxing; Abu-Odeh, Anas; Zheng, Hui; Li, Xiang-Guo; Ding, Jun; Ong, Shyue Ping; Asta, Mark; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomistic simulations of dislocation mobility in refractory high-entropy alloys and the effect of chemical short-range order", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Refractory high-entropy alloys (RHEAs) are designed for high elevated-temperature strength, with both edge and screw dislocations playing an important role for plastic deformation. However, they can also display a significant energetic driving force for chemical short-range ordering (SRO). Here, we investigate mechanisms underlying the mobilities of screw and edge dislocations in the body-centered cubic MoNbTaW RHEA over a wide temperature range using extensive molecular dynamics simulations based on a highly-accurate machine-learning interatomic potential. Further, we specifically evaluate how these mechanisms are affected by the presence of SRO. The mobility of edge dislocations is found to be enhanced by the presence of SRO, whereas the rate of double-kink nucleation in the motion of screw dislocations is reduced, although this influence of SRO appears to be attenuated at increasing temperature. Independent of the presence of SRO, a cross-slip locking mechanism is observed for the motion of screws, which provides for extra strengthening for refractory high-entropy alloy system. Refractory high entropy alloys hold big promise for elevated-temperature applications. Here the authors investigate the influence of short-range order on the mobility of dislocations in high-entropy alloys by large-scale molecular dynamics simulation based on a machine-learning interatomic potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4873, "DOI": "10.1038/s41467-021-25134-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25134-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684339800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Yin, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qiao; Yin, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Inorganic Metal Halide Perovskite nullocrystals: Opportunities and Challenges", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The past decade has witnessed the growing interest in metal halide perovskites as driven by their promising applications in diverse fields. The low intrinsic stability of the early developed organic versions has however hampered their widespread applications. Very recently, all-inorganic perovskite nullocrystals have emerged as a new class of materials that hold great promise for the practical applications in solar cells, photodetectors, light-emitting diodes, and lasers, among others. In this Outlook, we first discuss the recent developments in the preparation, properties, and applications of all-inorganic metal halide perovskite nullocrystals, with a particular focus on CsPbX3, and then provide our view of current challenges and future directions in this emerging area. Our goal is to introduce the current status of this type of new materials to researchers from different areas and motivate them to explore all the potentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 668, "End Page": 679, "Article Number": null, "DOI": "10.1021/acscentsci.8b00201", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.8b00201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436791600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YH; Sun, RJ; Qi, XY; Fu, KF; Chen, QS; Ding, YC; Xu, LJ; Liu, LM; Han, Y; Malko, AV; Liu, XG; Yang, HH; Bakr, OM; Liu, H; Mohammed, OF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuhai; Sun, Ruijia; Qi, Xiangyu; Fu, Kaifang; Chen, Qiushui; Ding, Yuchong; Xu, Liang-Jin; Liu, Lingmei; Han, Yu; Malko, Anton V.; Liu, Xiaogang; Yang, Huanghao; Bakr, Osman M.; Liu, Hong; Mohammed, Omar F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal Halide Perovskite nullosheet for X-ray High-Resolution Scintillation Imaging Screens", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scintillators, which are capable of converting ionizing radiation into visible photons, are an integral part of medical, security, and commercial diagnostic technologies such as X-ray imaging, nuclear cameras, and computed tomography. Conventional scintillator fabrication typically involves high-temperature sintering, generating agglomerated powders or large bulk crystals, which pose major challenges for device integration and processability. On the other hand, colloidal quantum dot scintillators cannot be cast into compact solid films with the necessary thickness required for most X-ray applications. Here, we report the room-temperature synthesis of a colloidal scintillator comprising CsPbBr3 nullosheets of large concentration (up to 150 mg/mL). The CsPbBr3 colloid exhibits a light yield (similar to 21000 photons/MeV) higher than that of the commercially available Ce:LuAG single-crystal scintillator (similar to 18000 photons/MeV). Scintillators based on these nullosheets display both strong radioluminescence (RL) and long-term stability under X-ray illumination. Importantly, the colloidal scintillator can be readily cast into a uniform crack-free large area film (8.5 x 8.5 cm(2) in area) with the requisite thickness for high-resolution X-ray imaging applications. We showcase prototype applications of these high-quality scintillating films as X-ray imaging screens for a cellphone panel and a standard central processing unit chip. Our radiography prototype combines large-area processability with high resolution and a strong penetration ability to sheath materials, such as resin and silicon. We reveal an energy transfer process inside those stacked nullosheet solids that is responsible for their superb scintillation performance. Our findings demonstrate a large-area solution-processed scintillator of stable and efficient RL as a promising approach for low-cost radiography and X-ray imaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2520, "End Page": 2525, "Article Number": null, "DOI": "10.1021/acsnullo.8b09484", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b09484", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460199400151", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; Dai, J; Yu, ZH; Shao, YC; Zhou, Y; Xiao, X; Zeng, XC; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuang; Dai, Jun; Yu, Zhenhua; Shao, Yuchuan; Zhou, Yu; Xiao, Xun; Zeng, Xiao Cheng; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring Passivation Molecular Structures for Extremely Small Open-Circuit Voltage Loss in Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passivation of electronic defects at the surface and grain boundaries of perovskite materials has become one of the most important strategies to suppress charge recombination in both polycrystalline and single-crystalline perovskite solar cells. Although many passivation molecules have been reported, it remains very unclear regarding the passivation mechanisms of various functional groups. Here, we systematically engineer the structures of passivation molecular functional groups, including carboxyl, amine, isopropyl, phenethyl, and tert-butylphenethyl groups, and study their passivation capability to perovskites. It reveals the carboxyl and amine groups would heal charged defects via electrostatic interactions, and the neutral iodine related defects can be reduced by the aromatic structures. The judicious control of the interaction between perovskite and molecules can further realize grain boundary passivation, including those that are deep toward substrates. Understanding of the underlining mechanisms allows us to design a new passivation molecule, D-4-tert-butylphenylalanine, yielding high-performance p-i-structure solar cells with a stabilized efficiency of 21.4%. The open-circuit voltage (V-OC) of a device with an optical bandgap of 1.57 eV for the perovskite layer reaches 1.23 V, corresponding to a record small V-OC deficit of 0.34 V. Our findings provide a guidance for future design of new passivation molecules to realize multiple facets applications in perovskite electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 644, "Times Cited, All Databases": 674, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2019, "Volume": 141, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5781, "End Page": 5787, "Article Number": null, "DOI": "10.1021/jacs.8b13091", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b13091", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464769000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, J; Fan, XX; Liu, T; Xu, P; Hou, Q; Li, K; Yuan, RM; Zheng, MS; Dong, QF; Chen, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Jie; Fan, Xiao-Xiang; Liu, Ting; Xu, Pan; Hou, Qing; Li, Ke; Yuan, Ru-Ming; Zheng, Ming-Sen; Dong, Quan-Feng; Chen, Jia-Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-dispersed polyoxometalate clusters embedded on multilayer graphene as a bifunctional electrocatalyst for efficient Li-S batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient electrochemical energy storage in Li-S batteries is hindered by sluggish sulfur redox reactions. Here, the authors propose a polyoxometalate/multilayer graphene composite as a bifunctional electrocatalyst for battery performance improvement. The redox reactions occurring in the Li-S battery positive electrode conceal various and critical electrocatalytic processes, which strongly influence the performances of this electrochemical energy storage system. Here, we report the development of a single-dispersed molecular cluster catalyst composite comprising of a polyoxometalate framework ([Co-4(PW9O34)(2)](10-)) and multilayer reduced graphene oxide. Due to the interfacial charge transfer and exposure of unsaturated cobalt sites, the composite demonstrates efficient polysulfides adsorption and reduced activation energy for polysulfides conversion, thus serving as a bifunctional electrocatalyst. When tested in full Li-S coin cell configuration, the composite allows for a long-term Li-S battery cycling with a capacity fading of 0.015% per cycle after 1000 cycles at 2 C (i.e., 3.36 A g(-1)). An areal capacity of 4.55 mAh cm(-2) is also achieved with a sulfur loading of 5.6 mg cm(-)(2) and E/S ratio of 4.5 mu L mg(-1). Moreover, Li-S single-electrode pouch cells tested with the bifunctional electrocatalyst demonstrate a specific capacity of about 800 mAh g(-1) at a sulfur loading of 3.6 mg cm(-2) for 100 cycles at 0.2 C (i.e., 336 mA g(-1)) with E/S ratio of 5 mu L mg(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 202, "DOI": "10.1038/s41467-021-27866-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27866-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741852200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, XM; Sun, N; Nielsen, SO; Stogin, BB; Wang, J; Yang, SK; Wong, TS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Xianming; Sun, null; Nielsen, Steven O.; Stogin, Birgitt Boschitsch; Wang, Jing; Yang, Shikuan; Wong, Tak-Sing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrophilic directional slippery rough surfaces for water harvesting", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional surfaces that are favorable for both droplet nucleation and removal are highly desirable for water harvesting applications but are rare. Inspired by the unique functions of pitcher plants and rice leaves, we present a hydrophilic directional slippery rough surface (SRS) that is capable of rapidly nucleating and removing water droplets. Our surfaces consist of nullotextured directional microgrooves in which the nullotextures alone are infused with hydrophilic liquid lubricant. We have shown through molecular dynamics simulations that the physical origin of the efficient droplet nucleation is attributed to the hydrophilic surface functional groups, whereas the rapid droplet removal is due to the significantly reduced droplet pinning of the directional surface structures and slippery interface. We have further demonstrated that the SRS, owing to its large surface area, hydrophilic slippery interface, and directional liquid repellency, outperforms conventional liquid-repellent surfaces in water harvesting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaq0919", "DOI": "10.1126/sciadv.aaq0919", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaq0919", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431373300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, XH; Zhou, WH; Tang, Z; Wu, H; Liu, YC; Dong, H; Wang, N; Huang, H; Bao, SS; Shi, L; Li, XK; Zheng, YF; Guo, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Xinghui; Zhou, Wenhao; Tang, Zhen; Wu, Hao; Liu, Yichao; Dong, Hui; Wang, Ning; Huang, Hai; Bao, Shusen; Shi, Lei; Li, Xiaokang; Zheng, Yufeng; Guo, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnesium surface-activated 3D printed porous PEEK scaffolds for in vivo osseointegration by promoting angiogenesis and osteogenesis", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyetheretherketone (PEEK) has been an alternative material for titanium in bone defect repair, but its clinical application is limited by its poor osseointegration. In this study, a porous structural design and activated surface modification were used to enhance the osseointegration capacity of PEEK materials. Porous PEEK scaffolds were manufactured via fused deposition modeling and a polydopamine (PDA) coating chelated with magnesium ions (Mg2+) was utilized on the surface. After surface modification, the hydrophilicity of PEEK scaffolds was significantly enhanced, and bioactive Mg2+ could be released. In vitro results showed that the activated surface could promote cell proliferation and adhesion and contribute to osteoblast differentiation and mineralization; the released Mg2+ promoted angiogenesis and might contribute to the formation of osteogenic H-type vessels. Furthermore, porous PEEK scaffolds were implanted in rabbit femoral condyles for in vivo evaluation of osseointegration. The results showed that the customized three-dimensional porous structure facilitated vascular ingrowth and bone ingrowth within the PEEK scaffolds. The PDA coating enhanced the interfacial osseointegration of porous PEEK scaffolds and the released Mg2+ accelerated early bone ingrowth by promoting early angiogenesis during the coating degradation process. This study provides an efficient solution for enhancing the osseointegration of PEEK materials, which has high potential for translational clinical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16, "End Page": 28, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.05.011", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.05.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808182300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ZY; Ouyang, YX; Zhang, H; Xiao, ML; Ge, JJ; Jiang, Z; Wang, JL; Tang, DM; Cao, XZ; Liu, CP; Xing, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhaoyan; Ouyang, Yixin; Zhang, Hao; Xiao, Meiling; Ge, Junjie; Jiang, Zheng; Wang, Jinlan; Tang, Daiming; Cao, Xinzhong; Liu, Changpeng; Xing, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lacking strategies to simultaneously address the intrinsic activity, site density, electrical transport, and stability problems of chalcogels is restricting their application in catalytic hydrogen production. Herein, we resolve these challenges concurrently through chemically activating the molybdenum disulfide (MoS2) surface basal plane by doping with a low content of atomic palladium using a spontaneous interfacial redox technique. Palladium substitution occurs at the molybdenum site, simultaneously introducing sulfur vacancy and converting the 2H into the stabilized 1T structure. Theoretical calculations demonstrate the sulfur atoms next to the palladium sites exhibit low hydrogen adsorption energy at -0.02 eV. The final MoS2 doped with only 1wt% of palladium demonstrates exchange current density of 805 mu A cm(-2) and 78 mV overpotential at 10 mA cm(-2), accompanied by a good stability. The combined advantages of our surface activating technique open the possibility of manipulating the catalytic performance of MoS2 to rival platinum.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 530, "Times Cited, All Databases": 549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2120, "DOI": "10.1038/s41467-018-04501-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04501-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433299000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, SX; Liu, FF; Huang, BL; Li, F; Lin, HP; Wu, T; Sun, MZ; Wu, JB; Shao, Q; Xu, Y; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Shuxing; Liu, Fangfang; Huang, Bolong; Li, Fan; Lin, Haiping; Wu, Tong; Sun, Mingzi; Wu, Jianbo; Shao, Qi; Xu, Yong; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency direct methane conversion to oxygenates on a cerium dioxide nullowires supported rhodium single-atom catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct methane conversion (DMC) to high value-added products is of significant importance for the effective utilization of CH4 to combat the energy crisis. However, there are ongoing challenges in DMC associated with the selective C-H activation of CH4. The quest for high-efficiency catalysts for this process is limited by the current drawbacks including poor activity and low selectivity. Here we show a cerium dioxide (CeO2) nullowires supported rhodium (Rh) single-atom (SAs Rh-CeO2 NWs) that can serve as a high-efficiency catalyst for DMC to oxygenates (i.e., CH3OH and CH3OOH) under mild conditions. Compared to Rh/CeO2 nullowires (Rh clusters) prepared by a conventional wet-impregnation method, CeO2 nullowires supported Rh single-atom exhibits 6.5 times higher of the oxygenates yield (1231.7 vs. 189.4mmolg(Rh)(-1)h(-1)), which largely outperforms that of the reported catalysts in the same class. This work demonstrates a highly efficient DMC process and promotes the research on Rh single-atom catalysts in heterogeneous catalysis. Direct methane conversion to high value-added products is a promising way for highly-efficient utilization of methane. Here, the authors demonstrate that rhodium single-atom supported on cerium dioxide nullowires can selectively convert methane to oxygenates under mild conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 954, "DOI": "10.1038/s41467-020-14742-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14742-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558870300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DD; Yang, YM; Bekenstein, Y; Yu, Y; Gibson, NA; Wong, AB; Eaton, SW; Kornienko, N; Kong, Q; Lai, ML; Alivisatos, AP; Leone, SR; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dandan; Yang, Yiming; Bekenstein, Yehonadav; Yu, Yi; Gibson, Natalie A.; Wong, Andrew B.; Eaton, Samuel W.; Kornienko, Nikolay; Kong, Qiao; Lai, Minliang; Alivisatos, A. Paul; Leone, Stephen R.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide nullowires through Anion-Exchange Reactions", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we demonstrate the successful syn.= thesis of brightly emitting colloidal cesium lead halide (CsPbX3, X = Cl, Br, I) nullowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr3 NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX3 alloy NWs with a wide range of alloy compositions can be achieved with wellpreserved morphology and crystal structure. The NI/Vs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX3 system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX3 NWs as prospective materials for,optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2016, "Volume": 138, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7236, "End Page": 7239, "Article Number": null, "DOI": "10.1021/jacs.6b03134", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b03134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378193300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Breger, JC; Yoon, C; Xiao, R; Kwag, HR; Wang, MO; Fisher, JP; Nguyen, TD; Gracias, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Breger, Joyce C.; Yoon, ChangKyu; Xiao, Rui; Kwag, Hye Rin; Wang, Martha O.; Fisher, John P.; Nguyen, Thao D.; Gracias, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Folding Thermo-Magnetically Responsive Soft Microgrippers", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels such as poly(N-isopropylacrylamide-co-acrylic acid) (pNIPAM-AAc) can be photopatterned to create a wide range of actuatable and self-folding microstructures. Mechanical motion is derived from the large and reversible swelling response of this cross-linked hydrogel in varying thermal or pH environments. This action is facilitated by their network structure and capacity for large strain. However, due to the low modulus of such hydrogels, they have limited gripping ability of relevance to surgical excision or robotic tasks such as pick-and-place. Using experiments and modeling, we design, fabricate, and characterize photopatterned, self-folding functional microgrippers that combine a swellable, photo-cross-linked pNIPAM-AAc soft-hydrogel with a nonswellable and stiff segmented polymer (polypropylene fumarate, PPF). We also show that we can embed iron oxide (Fe2O3) nulloparticles into the porous hydrogel layer, allowing the microgrippers to be responsive and remotely guided using magnetic fields. Using finite element models, we investigate the influence of the thickness and the modulus of both the hydrogel and stiff polymer layers on the self-folding characteristics of the microgrippers. Finally, we illustrate operation and functionality of these polymeric microgrippers for soft robotic and surgical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 507, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2015, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3398, "End Page": 3405, "Article Number": null, "DOI": "10.1021/am508621s", "DOI Link": "http://dx.doi.org/10.1021/am508621s", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349580800048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grindy, SC; Learsch, R; Mozhdehi, D; Cheng, J; Barrett, DG; Guan, ZB; Messersmith, PB; Holten-Andersen, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grindy, Scott C.; Learsch, Robert; Mozhdehi, Davoud; Cheng, Jing; Barrett, Devin G.; Guan, Zhibin; Messersmith, Phillip B.; Holten-Andersen, Niels", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of hierarchical polymer mechanics with bioinspired metal-coordination dynamics", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In conventional polymer materials, mechanical performance is traditionally engineered via material structure, using motifs such as polymer molecular weight, polymer branching, or block copolymer design(1). Here, by means of a model system of 4-arm poly(ethylene glycol) hydrogels crosslinked with multiple, kinetically distinct dynamic metal-ligand coordinate complexes, we show that polymer materials with decoupled spatial structure and mechanical performance can be designed. By tuning the relative concentration of two types of metal-ligand crosslinks, we demonstrate control over the material's mechanical hierarchy of energy-dissipating modes under dynamic mechanical loading, and therefore the ability to engineer a priori the viscoelastic properties of these materials by controlling the types of crosslinks rather than by modifying the polymer itself. This strategy to decouple material mechanics from structure is general and may inform the design of soft materials for use in complex mechanical environments. Three examples that demonstrate this are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 14, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1210, "End Page": 1216, "Article Number": null, "DOI": "10.1038/nmat4401", "DOI Link": "http://dx.doi.org/10.1038/nmat4401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365839000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathis, TS; Kurra, N; Wang, XH; Pinto, D; Simon, P; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathis, Tyler S.; Kurra, Narendra; Wang, Xuehang; Pinto, David; Simon, Patrice; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy Storage Data Reporting in Perspective-Guidelines for Interpreting the Performance of Electrochemical Energy Storage Systems", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the tremendous importance of electrochemical energy storage, numerous new materials and electrode architectures for batteries and supercapacitors have emerged in recent years. Correctly characterizing these systems requires considerable time, effort, and experience to ensure proper metrics are reported. Many new nullomaterials show electrochemical behavior somewhere in between conventional double-layer capacitor and battery electrode materials, making their characterization a non-straightforward task. It is understandable that some researchers may be misinformed about how to rigorously characterize their materials and devices, which can result in inflation of their reported data. This is not uncommon considering the current state of the field nearly requires record breaking performance for publication in high-impact journals. Incorrect characterization and data reporting misleads both the materials and device development communities, and it is the shared responsibility of the community to follow rigorous reporting methodologies to ensure published results are reliable to ensure constructive progress. This tutorial aims to clarify the main causes of inaccurate data reporting and to give examples of how researchers should proceed. The best practices for measuring and reporting metrics such as capacitance, capacity, coulombic and energy efficiencies, electrochemical impedance, and the energy and power densities of capacitive and pseudocapacitive materials are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 991, "Times Cited, All Databases": 1033, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 9, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902007, "DOI": "10.1002/aenm.201902007", "DOI Link": "http://dx.doi.org/10.1002/aenm.201902007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491990100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JK; Walker, KL; Han, HS; Kang, J; Prinz, FB; Waymouth, RM; Nam, HG; Zare, RN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jae Kyoo; Walker, Katherine L.; Han, Hyun Soo; Kang, Jooyoun; Prinz, Fritz B.; Waymouth, Robert M.; Nam, Hong Gil; Zare, Richard N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous generation of hydrogen peroxide from aqueous microdroplets", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show H2O2 is spontaneously produced from pure water by atomizing bulk water into microdroplets (1 mu m to 20 mu m in diameter). Production of H2O2, as assayed by H2O2-sensitve fluorescence dye peroxyfluor-1, increased with decreasing microdroplet size. Cleavage of 4-carboxyphenylboronic acid and conversion of phenylboronic acid to phenols in microdroplets further confirmed the generation of H2O2. The generated H2O2 concentration was similar to 30 mu M (similar to 1 part per million) as determined by titration with potassium titanium oxalate. Changing the spray gas to O-2 or bubbling O-2 decreased the yield of H2O2 in microdroplets, indicating that pure water microdroplets directly generate H2O2 without help from O-2 either in air surrounding the droplet or dissolved in water. We consider various possible mechanisms for H2O2 formation and report a number of different experiments exploring this issue. We suggest that hydroxyl radical (OH) recombination is the most likely source, in which OH is generated by loss of an electron from OH- at or near the surface of the water microdroplet. This catalyst-free and voltage-free H2O2 production method provides innovative opportunities for green production of hydrogen peroxide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2019, "Volume": 116, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19294, "End Page": 19298, "Article Number": null, "DOI": "10.1073/pnas.1911883116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1911883116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487532900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, MH; Tian, PF; Cao, XY; Chen, JC; Pu, TC; Shi, BF; Xu, J; Moon, J; Wu, ZL; Han, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Minghui; Tian, Pengfei; Cao, Xinyu; Chen, Jiacheng; Pu, Tiancheng; Shi, Bianfang; Xu, Jing; Moon, Jisue; Wu, Zili; Han, Yi-Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vacancy engineering of the nickel-based catalysts for enhanced CO2 methanation", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is challenging to elucidate the mechanism of CO2 methanation reaction over nickel-based catalysts and precisely tune the kinetics of rate-determining-step. In this work, we propose a strategy to engineer the oxygen vacancies of nickel-based catalysts for enhanced CO2 methanation. A Y2O3-promoted NiO-CeO2 catalyst is prepared and found to exhibit an outstanding methanation activity that is up to three folds higher than NiO-CeO2 and six folds higher than NiO-Y2O3 at mild reaction temperatures (< 300 degrees C). We demonstrate both theoretically and experimentally that the introduction of Y2O3 to CeO2 greatly facilitates the generation of surface oxygen vacancies during the reaction. Using spectrokinetics analysis, we further revealed that these sites promote the direct dissociation of CO2, which is kinetically more favorable than the associative route. Thus, it dramatically improved the CO2 methanation activity. The vacancy engineering strategy will potentially guide the rational design of a broad range of heterogeneous catalysts for CO2 hydrogenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 282, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119561, "DOI": "10.1016/j.apcatb.2020.119561", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119561", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591695500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rakhi, RB; Nayuk, P; Xia, C; Alshareef, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rakhi, R. B.; Nayuk, Pranati; Xia, Chuan; Alshareef, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel amperometric glucose biosensor based on MXene nullocomposite", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A biosensor platform based on Au/MXene nullocomposite for sensitive enzymatic glucose detection is reported. The biosensor leverages the unique electrocatalytic properties and synergistic effects between Au nulloparticles and MXene sheets. An amperometric glucose biosensor is fabricated by the immobilization of glucose oxidase (GOx) enzyme on Nafion solubilized Au/MXene nullocomposite over glassy carbon electrode (GCE). The biomediated Au nulloparticles play a significant role in facilitating the electron exchange between the electroactive center of GOx and the electrode. The GOx/Au/MXene/Nafion/GCE biosensor electrode displayed a linear amperometric response in the glucose concentration range from 0.1 to 18 mM with a relatively high sensitivity of 4.2 mu AmM-1 cm(-2) and a detection limit of 5.9 mu M (S/N = 3). Furthermore, the biosensor exhibited excellent stability, reproducibility and repeatability. Therefore, the Au/MXene nullocomposite reported in this work is a potential candidate as an electrochemical transducer in electrochemical biosensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36422, "DOI": "10.1038/srep36422", "DOI Link": "http://dx.doi.org/10.1038/srep36422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387368700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MQ; Wu, F; Gong, YT; Li, Y; Li, Y; Feng, X; Li, QJ; Wu, C; Bai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingquan; Wu, Feng; Gong, Yuteng; Li, Yu; Li, Ying; Feng, Xin; Li, Qiaojun; Wu, Chuan; Bai, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial-Catalysis-Enabled Layered and Inorganic-Rich SEI on Hard Carbon Anodes in Ester Electrolytes for Sodium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing a homogenous and inorganic-rich solid electrolyte interface (SEI) can efficiently improve the overall sodium-storage performance of hard carbon (HC) anodes. However, the thick and heterogenous SEI derived from conventional ester electrolytes fails to meet the above requirements. Herein, an innovative interfacial catalysis mechanism is proposed to design a favorable SEI in ester electrolytes by reconstructing the surface functionality of HC, of which abundant C(sic)O (carbonyl) bonds are accurately and homogenously implanted. The C(sic)O (carbonyl) bonds act as active centers that controllably catalyze the preferential reduction of salts and directionally guide SEI growth to form a homogenous, layered, and inorganic-rich SEI. Therefore, excessive solvent decomposition is suppressed, and the interfacial Na+ transfer and structural stability of SEI on HC anodes are greatly promoted, contributing to a comprehensive enhancement in sodium-storage performance. The optimal anodes exhibit an outstanding reversible capacity (379.6 mAh g(-1)), an ultrahigh initial Coulombic efficiency (93.2%), a largely improved rate capability, and an extremely stable cycling performance with a capacity decay rate of 0.0018% for 10 000 cycles at 5 A g(-1). This work provides novel insights into smart regulation of interface chemistry to realize high-performance HC anodes for sodium storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 35, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300002", "DOI Link": "http://dx.doi.org/10.1002/adma.202300002", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000995947700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JH; Li, ZT; Xu, J; Li, J; Yan, K; Cheng, W; Xin, M; Zhu, TS; Du, JH; Chen, SX; An, XM; Zhou, Z; Cheng, LY; Ying, S; Zhang, J; Gao, XX; Zhang, QH; Jia, XD; Shi, Y; Pan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jia-Han; Li, Zhengtong; Xu, Juan; Li, Jiean; Yan, Ke; Cheng, Wen; Xin, Ming; Zhu, Tangsong; Du, Jinhua; Chen, Sixuan; An, Xiaoming; Zhou, Zhou; Cheng, Luyao; Ying, Shu; Zhang, Jing; Gao, Xingxun; Zhang, Qiuhong; Jia, Xudong; Shi, Yi; Pan, Lijia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Versatile self-assembled electrospun micro-pyramid arrays for high-performance on-skin devices with minimal sensory interference", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-skin devices that show both high performance and imperceptibility are desired for physiological information detection, individual protection, and bioenergy conversion with minimal sensory interference. Herein, versatile electrospun micropyramid arrays (EMPAs) combined with ultrathin, ultralight, gas-permeable structures are developed through a self-assembly technology based on wet heterostructured electrified jets to endow various on-skin devices with both superior performance and imperceptibility. The designable self-assembly allows structural and material optimization of EMPAs for on-skin devices applied in daytime radiative cooling, pressure sensing, and bioenergy harvesting. A temperature drop of -4 degrees C is obtained via an EMPA-based radiative cooling fabric under a solar intensity of 1 kW m(-2). Moreover, detection of an ultraweak fingertip pulse for health diagnosis during monitoring of natural finger manipulation over a wide frequency range is realized by an EMPA piezocapacitive-triboelectric hybrid sensor, which has high sensitivity (19 kPa(-1)), ultralow detection limit (0.05 Pa), and ultrafast response (<= 1.8 ms). Additionally, EMPA nullogenerators with high triboelectric and piezoelectric outputs achieve reliable biomechanical energy harvesting. The flexible self-assembly of EMPAs exhibits immense potential in superb individual healthcare and excellent human-machine interaction in an interference-free and comfortable manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5839, "DOI": "10.1038/s41467-022-33454-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33454-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000865250300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Luo, M; Peng, M; Yu, YQ; Lu, YR; Chan, TS; Liu, P; de Groot, FMF; Tan, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kang; Luo, Min; Peng, Ming; Yu, Yaqian; Lu, Ying-Rui; Chan, Ting-Shan; Liu, Pan; de Groot, Frank M. F.; Tan, Yongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic active-site generation of atomic iridium stabilized on nulloporous metal phosphides for water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing efficient single-atom catalysts (SACs) for oxygen evolution reaction (OER) is critical for water-splitting. However, the self-reconstruction of isolated active sites during OER not only influences the catalytic activity, but also limits the understanding of structure-property relationships. Here, we utilize a self-reconstruction strategy to prepare a SAC with isolated iridium anchored on oxyhydroxides, which exhibits high catalytic OER performance with low overpotential and small Tafel slope, superior to the IrO2. Operando X-ray absorption spectroscopy studies in combination with theory calculations indicate that the isolated iridium sites undergo a deprotonation process to form the multiple active sites during OER, promoting the O-O coupling. The isolated iridium sites are revealed to remain dispersed due to the support effect during OER. This work not only affords the rational design strategy of OER SACs at the atomic scale, but also provides the fundamental insights of the operando OER mechanism for highly active OER SACs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2701, "DOI": "10.1038/s41467-020-16558-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16558-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542982400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, PP; Ye, CC; Jiao, ZR; Luo, J; Fang, JK; Schubert, US; McKeown, NB; Liu, TL; Yang, ZJ; Xu, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Peipei; Ye, Chunchun; Jiao, Zhongren; Luo, Jian; Fang, Junkai; Schubert, Ulrich S.; McKeown, Neil B.; Liu, T. Leo; Yang, Zhengjin; Xu, Tongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-frictionless ion transport within triazine framework membranes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The enhancement of separation processes and electrochemical technologies such as water electrolysers(1,2), fuel cells(3,4), redox flow batteries(5,6) and ion-capture electrodialysis(7) depends on the development of low-resistance and high-selectivity ion-transport membranes. The transport of ions through these membranes depends on the overall energy barriers imposed by the collective interplay of pore architecture and poreanalyte interaction(8,9). However, it remains challenging to design efficient, scaleable and low-cost selective ion-transport membranes that provide ion channels for low-energy-barrier transport. Here we pursue a strategy that allows the diffusion limit of ions in water to be approached for large-area, free-standing, synthetic membranes using covalently bonded polymer frameworks with rigidity-confined ion channels. The near-frictionless ion flow is synergistically fulfilled by robust micropore confinement and multi-interaction between ion and membrane, which afford, for instance, a Na+ diffusion coefficient of 1.18 x 10(-9) m(2) s(-1), close to the value in pure water at infinite dilution, and an area-specific membrane resistance as low as 0.17 Omega cm(2). We demonstrate highly efficient membranes in rapidly charging aqueous organic redox flow batteries that deliver both high energy efficiency and high-capacity utilization at extremely high current densities (up to 500 mA cm(-2)), and also that avoid crossover-induced capacity decay. This membrane design concept may be broadly applicable to membranes for a wide range of electrochemical devices and for precise molecular separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2023, "Volume": 617, "Issue": 7960, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 299, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05888-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05888-x", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002447800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Humayun, M; Raziq, F; Khan, A; Luo, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Humayun, M.; Raziq, F.; Khan, A.; Luo, W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modification strategies of TiO2 for potential applications in photocatalysis: acritical review", "Source Title": "GREEN CHEMISTRY LETTERS AND REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TiO2 has received tremendous attention owing to its potential applications in the field of photocatalysis for solar fuel production and environmental remediation. This review mainly describes various modification strategies and potential applications of TiO2 in efficient photocatalysis. In past few years, various strategies have been developed to improve the photocatalytic performance of TiO2, including noble metal deposition, elemental doping, inorganic acids modification, heterojunctions with other semiconductors, dye sensitization and metal ion implantation. The enhanced photocatalytic activities of TiO2-based material for CO2 conversion, water splitting and pollutants degradation are highlighted in this review. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 86, "End Page": 102, "Article Number": null, "DOI": "10.1080/17518253.2018.1440324", "DOI Link": "http://dx.doi.org/10.1080/17518253.2018.1440324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427857800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JU; Lee, S; Ryoo, JH; Kang, S; Kim, TY; Kim, P; Park, CH; Park, JG; Cheong, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jae-Ung; Lee, Sungmin; Ryoo, Ji Hoon; Kang, Soonmin; Kim, Tae Yun; Kim, Pilkwang; Park, Cheol-Hwan; Park, Je-Geun; Cheong, Hyeonsik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ising-Type Magnetic Ordering in Atomically Thin FePS3", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetism in two-dimensional materials is not only of fundamental scientific interest but also a promising candidate for numerous applications. However, studies so far, especially the experimental ones, have been mostly limited to the magnetism arising from defects, vacancies, edges, or chemical dopants which are all extrinsic effects. Here, we report on the observation of intrinsic antiferromagnetic ordering in the two-dimensional limit. By monitoring the Raman peaks that arise from zone folding due to antiferromagnetic ordering at the transition temperature, we demonstrate that FePS3 exhibits an Ising-type antiferromagnetic ordering down to the monolayer limit, in good agreement with the Onsager solution for two-dimensional order disorder transition. The transition temperature remains almost independent of the thickness from bulk to the monolayer limit with T-N similar to 118 K, indicating that the weak interlayer interaction has little effect on the antiferromagnetic ordering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 818, "Times Cited, All Databases": 876, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 16, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7433, "End Page": 7438, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b03052", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b03052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389963200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Otto, F; Dlouhy, A; Pradeep, KG; Kubenová, M; Raabe, D; Eggeler, G; George, EP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Otto, F.; Dlouhy, A.; Pradeep, K. G.; Kubenova, M.; Raabe, D.; Eggeler, G.; George, E. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decomposition of the single-phase high-entropy alloy CrMnFeCoNi after prolonged anneals at intermediate temperatures", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among the vast number of multi-principal-element alloys that are referred to as high-entropy alloys (HEAs) in the literature, only a limited number solidify as single-phase solid solutions. The equiatomic HEA, CrMnFeCoNi, is a face-centered cubic (FCC) prototype of this class and has attracted much attention recently because of its interesting mechanical properties. Here we evaluate its phase stability after very long anneals of 500 days at 500-900 degrees C during which it is reasonable to expect thermodynamic equilibrium to have been established. Microstructural analyses were performed using complementary analysis techniques including scanning and transmission electron microscopy (SEM/TEM/STEM), energy dispersive X-ray (EDX) spectroscopy, selected area electron diffraction (SAD), and atom probe tomography (APT). We show that the alloy is a single-phase solid solution after homogenization for 2 days at 1200 degrees C and remains in this state after a subsequent anneal at 900 degrees C for 500 days. However, it is unstable and forms second-phase precipitates at 700 and 500 degrees C. A Cr-rich sigma phase 'forms at 700 degrees C, whereas three different phases (L1(0)-NiMn, B2-FeCo and a Cr-rich body-centered cubic, BCC, phase) precipitate at 500 degrees C. These precipitates are located mostly at grain boundaries, but also form at intragranular inclusions/pores, indicative of heterogeneous nucleation. Since there is limited entropic stabilization of the solid solution state even in the extensively investigated CrMnFeCoNi alloy, the stability of other HEAs currently thought to be solid solutions should be carefully evaluated, especially if they are being considered for applications in vulnerable temperature ranges. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 718, "Times Cited, All Databases": 760, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2016, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 40, "End Page": 52, "Article Number": null, "DOI": "10.1016/j.actamat.2016.04.005", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.04.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377326400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin, HJ; Gao, L; Zhang, ZG; Yang, YK; Zhang, YD; Zhang, CF; Chen, SS; Xue, LW; Yang, C; Xiao, M; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin, Haijun; Gao, Liang; Zhang, Zhi-Guo; Yang, Yankang; Zhang, Yindong; Zhang, Chunfeng; Chen, Shanshan; Xue, Lingwei; Yang, Changduk; Xiao, Min; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simutaneously high open circuit voltage and high short circuit current density is a big challenge for achieving high efficiency polymer solar cells due to the excitonic nature of organic semdonductors. Herein, we developed a trialkylsilyl substituted 2D-conjugated polymer with the highest occupied molecular orbital level down-shifted by Si-C bond interaction. The polymer solar cells obtained by pairing this polymer with a non-fullerene acceptor demonstrated a high power conversion efficiency of 11.41% with both high open circuit voltage of 0.94 V and high short circuit current density of 17.32 mA cm(-2) benefitted from the complementary absorption of the donor and acceptor, and the high hole transfer efficiency from acceptor to donor although the highest occupied molecular orbital level difference between the donor and acceptor is only 0.11 eV. The results indicate that the alkylsilyl substitution is an effective way in designing high performance conjugated polymer photovoltaic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 935, "Times Cited, All Databases": 970, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13651, "DOI": "10.1038/ncomms13651", "DOI Link": "http://dx.doi.org/10.1038/ncomms13651", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389651800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YT; Zhang, RH; Wang, J; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yangtao; Zhang, Ruihan; Wang, Jun; Wang, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current and future lithium-ion battery manufacturing", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) have become one of the main energy storage solutions in modern society. The application fields and market share of LIBs have increased rapidly and continue to show a steady rising trend. The research on LIB materials has scored tremendous achievements. Many innovative materials have been adopted and commercialized by the industry. However, the research on LIB manufacturing falls behind. Many battery researchers may not know exactly how LIBs are being manufactured and how different steps impact the cost, energy consumption, and throughput, which prevents innovations in battery manufacturing. Here in this perspective paper, we introduce state-of-theart manufacturing technology and analyze the cost, throughput, and energy consumption based on the production processes. We then review the research progress focusing on the high-cost, energy, and time-demand steps of LIB manufacturing. Finally, we share our views of challenges in LIB manufacturing and propose future development directions for manufacturing research in LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 475, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2021, "Volume": 24, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102332, "DOI": "10.1016/j.isci.2021.102332", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2021.102332", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642261700078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, H; Shin, H; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Hai; Shin, Hyeyoung; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergy between Fe and Ni in the optimal performance of (Ni, Fe)OOH catalysts for the oxygen evolution reaction", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction (OER) is critical to solar production of fuels, but the reaction mechanism underlying the performance for a best OER catalyst, Fe-doped NiOOH [(Ni, Fe)OOH], remains highly controversial. We used grand canonical quantum mechanics to predict the OER mechanisms including kinetics and thus overpotentials as a function of Fe content in (Ni, Fe) OOH catalysts. We find that density functional theory (DFT) without exact exchange predicts that addition of Fe does not reduce the overpotential much. However, DFT with exact exchange predicts dramatic improvement in performance for (Ni, Fe) OOH, leading to an overpotential of 0.42 V and a Tafel slope of 23 mV/decade (dec), in good agreement with experiments, 0.3-0.4 V and 30 mV/dec. We reveal that the high spin d(4) Fe(IV) leads to efficient formation of an active O radical intermediate, while the closed shell d(6) Ni(IV) catalyzes the subsequent O-O coupling, and thus it is the synergy between Fe and Ni that delivers the optimal performance for OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2018, "Volume": 115, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5872, "End Page": 5877, "Article Number": null, "DOI": "10.1073/pnas.1722034115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1722034115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434114900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, XB; Zhao, XG; Hu, XB; He, K; Yu, YN; Li, T; Tu, Q; Qian, X; Yue, Q; Wasielewski, MR; Kang, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Xianbiao; Zhao, Xingang; Hu, Xiaobing; He, Kun; Yu, Yanull; Li, Tao; Tu, Qing; Qian, Xin; Yue, Qin; Wasielewski, Michael R.; Kang, Yijin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alternative route for electrochemical ammonia synthesis by reduction of nitrate on copper nullosheets", "Source Title": "APPLIED MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose an efficient and clean avenue for ammonia synthesis, via electroreduction of nitrate which could be obtained from industrial wastewater, domestic sewage, sodium nitrate ore, and nitrification of bacteria and electrochemical oxidation of nitrogen, which addresses the water pollution issues and simultaneously upgrades the nitrate to high-value ammonia. At a low overpotential of -0.15 V versus RHE, Cu nullosheets achieved an ammonia formation rate of 390.1 mu g mg(-1) Cu h(-1) and a Faradaic efficiency of 99.7%, attributed to suppression of the HER activity and apparent improvement of the rate of rate-determining step on Cu (111). Such an ammonia formation rate is more than two orders of magnitude higher than electrochemical nitrogen reduction reaction to ammonia. This work not only develops a powerful strategy to the rational design of robust and efficient catalysts by crystal facet engineering, but also provides an alternative route for electrochemical ammonia synthesis by reduction of nitrate. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100620, "DOI": "10.1016/j.apmt.2020.100620", "DOI Link": "http://dx.doi.org/10.1016/j.apmt.2020.100620", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546200100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XX; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiaoxiao; Chen, Baoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macroscopic and Spectroscopic Investigations of the Adsorption of Nitroaromatic Compounds on Graphene Oxide, Reduced Graphene Oxide, and Graphene nullosheets", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface properties and adsorption mechanisms of graphene materials are important for potential environmental applications. The adsorption of m-dinitrobenzene, nitrobenzene, and p-nitrotoluene onto graphene oxide (GO), reduced graphene oxide (RGO), and graphene (G) nullosheets was investigated using IR spectroscopy to probe the molecular interactions of graphene materials with nitro, aromatic compounds (NACs). The hydrophilic GO displayed the weakest adsorption capability. The adsorption of RGO and G was significantly increased due to the recovery of hydrophobic pi-conjugation carbon atoms as active sites. RGO nullosheets, which had more defect sites than did GO or G nullosheets, resulted in the highest adsorption of NACs which was 10-50 times greater than the reported adsorption of carbon nullotubes. Superior adsorption was dominated by various interaction modes including pi-pi electron donor acceptor interactions between the 7r-electron-deficient phenyls of the NACs and the pi-electron-rich matrix of the graphene nullosheets, and the charge electrostatic and polar interactions between the defect sites of graphene nullosheets and the -NO2 of the NA. The charge transfer was initially proved by FTIR that a blue shift of asymmetric -NO2 stretching was observed with a concomitant red shift of symmetric -NO2 stretching after m-dinitrobenzene was adsorbed. The Multiple interaction mechanisms of the adsorption of NAC molecule onto flat graphene nullosheets favor the adsorption, detection, and transformation of explosives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2015, "Volume": 49, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6181, "End Page": 6189, "Article Number": null, "DOI": "10.1021/es5054946", "DOI Link": "http://dx.doi.org/10.1021/es5054946", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355058300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XF; Pereira, LFC; Wang, Y; Wu, J; Zhang, KW; Zhao, XM; Bae, S; Bui, CT; Xie, RG; Thong, JTL; Hong, BH; Loh, KP; Donadio, D; Li, BW; Özyilmaz, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiangfan; Pereira, Luiz F. C.; Wang, Yu; Wu, Jing; Zhang, Kaiwen; Zhao, Xiangming; Bae, Sukang; Cong Tinh Bui; Xie, Rongguo; Thong, John T. L.; Hong, Byung Hee; Loh, Kian Ping; Donadio, Davide; Li, Baowen; Oezyilmaz, Barbaros", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Length-dependent thermal conductivity in suspended single-layer graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene exhibits extraordinary electronic and mechanical properties, and extremely high thermal conductivity. Being a very stable atomically thick membrane that can be suspended between two leads, graphene provides a perfect test platform for studying thermal conductivity in two-dimensional systems, which is of primary importance for phonon transport in low-dimensional materials. Here we report experimental measurements and nonequilibrium molecular dynamics simulations of thermal conduction in suspended single-layer graphene as a function of both temperature and sample length. Interestingly and in contrast to bulk materials, at 300 K, thermal conductivity keeps increasing and remains logarithmically divergent with sample length even for sample lengths much larger than the average phonon mean free path. This result is a consequence of the two-dimensional nature of phonons in graphene, and provides fundamental understanding of thermal transport in two-dimensional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 842, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3689, "DOI": "10.1038/ncomms4689", "DOI Link": "http://dx.doi.org/10.1038/ncomms4689", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335222000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, C; Niu, SZ; Lv, W; Zhou, GM; Li, J; Fan, SX; Deng, YQ; Pan, ZZ; Li, BH; Kang, FY; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Cheng; Niu, Shuzhang; Lv, Wei; Zhou, Guangmin; Li, Jia; Fan, Shaoxun; Deng, Yaqian; Pan, Zhengze; Li, Baohua; Kang, Feiyu; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Propelling polysulfides transformation for high-rate and long-life lithiumsulfur batteries", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A three-dimensional (3D) hierarchical porous graphene macrostructure coupled with uniformly distributed alpha-Fe2O3 nullo-particles (denoted Fe-PGM) was designed as a sulfur host in a lithium- sulfur battery, and was prepared by a hydrothermal method. In this hybrid structure, the alpha-Fe2O3 nullo-particles are proved to not only strongly interact with the polysulfides, but more importantly, chemically promote their transformation to insoluble species during the charge/discharge process, working as chemical barriers for the shuttling of the lithium polysulfides (LiPSs). Therefore, together with 3D hierarchical porous structure facilitating fast electron/ion transfer, Fe-PGM as a sulfur host in a cathode contributes to a high rate performance (565 mAh g(-1) at a high rate of 5 C relative to 1571 mAh g(-1) at 0.3 C) as well as long cyclic stability (an ultralow capacity fading rate of 0.049% per cycle over 1000 cycles at the high current rate of 5 C).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 306, "End Page": 312, "Article Number": null, "DOI": "10.1016/j.nulloen.2017.01.040", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2017.01.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397314200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chiu, CK; Teo, JCY; Schnyder, AP; Ryu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chiu, Ching-Kai; Teo, Jeffrey C. Y.; Schnyder, Andreas P.; Ryu, Shinsei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Classification of topological quantum matter with symmetries", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological materials have become the focus of intense research in recent years, since they exhibit fundamentally new physical phenomena with potential applications for novel devices and quantum information technology. One of the hallmarks of topological materials is the existence of protected gapless surface states, which arise due to a nontrivial topology of the bulk wave functions. This review provides a pedagogical introduction into the field of topological quantum matter with an emphasis on classification schemes. Both fully gapped and gapless topological materials and their classification in terms of nonspatial symmetries, such as time reversal, as well as spatial symmetries, such as reflection, are considered. Furthermore, the classification of gapless modes localized on topological defects is surveyed. The classification of these systems is discussed by use of homotopy groups, Clifford algebras, K theory, and nonlinear sigma models describing the Anderson (de) localization at the surface or inside a defect of the material. Theoretical model systems and their topological invariants are reviewed together with recent experimental results in order to provide a unified and comprehensive perspective of the field. While the bulk of this article is concerned with the topological properties of noninteracting or mean-field Hamiltonians, a brief overview of recent results and open questions concerning the topological classifications of interacting systems is also provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2137, "Times Cited, All Databases": 2287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 31", "Publication Year": 2016, "Volume": 88, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35005, "DOI": "10.1103/RevModPhys.88.035005", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.88.035005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383053400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XQ; Lu, QS; Liu, WQ; Niu, W; Sun, JB; Cook, J; Vaninger, M; Miceli, PF; Singh, DJ; Lian, SW; Chang, TR; He, XQ; Du, J; He, L; Zhang, R; Bian, G; Xu, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoqian; Lu, Qiangsheng; Liu, Wenqing; Niu, Wei; Sun, Jiabao; Cook, Jacob; Vaninger, Mitchel; Miceli, Paul F.; Singh, David J.; Lian, Shang-Wei; Chang, Tay-Rong; He, Xiaoqing; Du, Jun; He, Liang; Zhang, Rong; Bian, Guang; Xu, Yongbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature intrinsic ferromagnetism in epitaxial CrTe2 ultrathin films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the discovery of two-dimensional (2D) magnets opens the door for fundamental physics and next-generation spintronics, it is technically challenging to achieve the room-temperature ferromagnetic (FM) order in a way compatible with potential device applications. Here, we report the growth and properties of single- and few-layer CrTe2, a van der Waals (vdW) material, on bilayer graphene by molecular beam epitaxy (MBE). Intrinsic ferromagnetism with a Curie temperature (T-C) up to 300 K, an atomic magnetic moment of similar to 0.21 mu(B)/Cr and perpendicular magnetic anisotropy (PMA) constant (K-u) of 4.89 x 10(5) erg/cm(3) at room temperature in these few-monolayer films have been unambiguously evidenced by superconducting quantum interference device and X-ray magnetic circular dichroism. This intrinsic ferromagnetism has also been identified by the splitting of majority and minority band dispersions with similar to 0.2 eV at Gamma point using angle-resolved photoemission spectroscopy. The FM order is preserved with the film thickness down to a monolayer (T-C similar to 200 K), benefiting from the strong PMA and weak interlayer coupling. The successful MBE growth of 2D FM CrTe2 films with room-temperature ferromagnetism opens a new avenue for developing large-scale 2D magnet-based spintronics devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2492, "DOI": "10.1038/s41467-021-22777-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22777-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000656508100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, XX; Wu, YY; Liu, YP; Liu, DP; Li, W; Gu, L; Liu, H; Wang, PW; Sun, L; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Xiaoxin; Wu, Yuanyuan; Liu, Yipu; Liu, Dapeng; Li, Wang; Gu, Lin; Liu, Huan; Wang, Pengwei; Sun, Lei; Zhang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Generation of Bifunctional, Efficient Fe-Based Catalysts from Mackinawite Iron Sulfide for Water Splitting", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water splitting requires nonprecious materials that can catalyze efficiently both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Here, we report the synthesis of mackinawite FeS nullosheets grown on iron foam, which can serve as an efficient pre-electrocatalyst for both HER and OER in alkaline media. During electrochemical HER testing, core@shell iron@iron oxysulfide nulloparticles as the catalytically active phase are generated in situ on FeS nullosheets. During electrochemical OER testing, FeS nullosheets totally transform into porous amorphous FeOx film that can mediate the OER efficiently. When assembled as the cathode and the anode in a single electrolyzer, the resulting Fe-based catalysts can give a good overall water splitting output that outperforms the one obtained from a noble-metal-based Pt/C-lrO(2)-coupled electrolyzer. These results provide new insights on the active sites of Fe-based catalysts as well as an impetus for further research on low-cost, iron-containing water-splitting electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2018, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1139, "End Page": 1152, "Article Number": null, "DOI": "10.1016/j.chempr.2018.02.023", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.02.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432725000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TF; Chu, QL; Yan, C; Zhang, SQ; Lin, Z; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tiefeng; Chu, Qiaoling; Yan, Cheng; Zhang, Shanqing; Lin, Zhan; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interweaving 3D Network Binder for High-Areal-Capacity Si Anode through Combined Hard and Soft Polymers", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Si anodes suffer an inherent volume expansion problem. The consensus is that hydrogen bonds in these anodes are preferentially constructed between the binder and Si powder for enhanced adhesion and thus can improve cycling performance. There has been little research done in the field of understanding the contribution of the binder's mechanical properties to performance. Herein, a simple but effective strategy is proposed, combining hard/soft polymer systems, to exploit a robust binder with a 3D interpenetrating binding network (3D-IBN) via an in situ polymerization. The 3D-IBN structure is constructed by interweaving a hard poly(furfuryl alcohol) as the skeleton with a soft polyvinyl alcohol (PVA) as the filler, buffering the dramatic volume change of the Si anode. The resulting Si anode delivers an areal capacity of >10 mAh cm(-2) and enables an energy density of >300 Wh kg(-1) in a full lithium-ion battery (LIB) cell. The component of the interweaving binder can be switched to other polymers, such as replacing PVA by thermoplastic polyurethane and styrene butadiene styrene. Such a strategy is also effective for other high-capacity electroactive materials, e.g., Fe2O3 and Sn. This finding offers an alternative approach in designing high-areal-capacity electrodes through combined hard and soft polymer binders for high-energy-density LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802645, "DOI": "10.1002/aenm.201802645", "DOI Link": "http://dx.doi.org/10.1002/aenm.201802645", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456215200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, T; Wang, L; Huang, XY; Unruangsri, J; Zhang, HL; Wang, R; Song, QL; Yang, QY; Li, WH; Wang, CC; Takahashi, K; Xu, HX; Guo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Ting; Wang, Lei; Huang, Xingye; Unruangsri, Junjuda; Zhang, Hualei; Wang, Rong; Song, Qingliang; Yang, Qingyuan; Li, Weihua; Wang, Changchun; Takahashi, Kaito; Xu, Hangxun; Guo, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PEG-stabilized coaxial stacking of two-dimensional covalent organic frameworks for enhanced photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional covalent organic frameworks (2D COFs) featuring periodic frameworks, extended -conjugation and layered stacking structures, have emerged as a promising class of materials for photocatalytic hydrogen evolution. Nevertheless, the layer-by-layer assembly in 2D COFs is not stable during the photocatalytic cycling in water, causing disordered stacking and declined activity. Here, we report an innovative strategy to stabilize the ordered arrangement of layered structures in 2D COFs for hydrogen evolution. Polyethylene glycol is filled up in the mesopore channels of a beta -ketoenamine-linked COF containing benzothiadiazole moiety. This unique feature suppresses the dislocation of neighbouring layers and retains the columnar pi -orbital arrays to facilitate free charge transport. The hydrogen evolution rate is therefore remarkably promoted under visible irradiation compared with that of the pristine COF. This study provides a general post-functionalization strategy for 2D COFs to enhance photocatalytic performances.Two-dimensional covalent organic frameworks are expected to boost photocatalytic H-2 evolution from water splitting, but are not stable in photocatalysis. Here, authors demonstrate that photocatalytic performances can be enhanced by stabilizing layered stacking via a polymer-infiltration strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3934, "DOI": "10.1038/s41467-021-24179-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24179-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000669487700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, R; Wang, YS; Liu, ZY; Pang, YQ; Chen, JX; Kong, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Rui; Wang, Yansong; Liu, Ziyu; Pang, Yongqiang; Chen, Jianxin; Kong, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Digital Light Processing 3D-Printed Ceramic Metamaterials for Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining 3D printing with precursor-derived ceramic for fabricating electromagnetic (EM) wave-absorbing metamaterials has attracted great attention. This study presents a novel ultraviolet-curable polysiloxane precursor for digital light processing (DLP) 3D printing to fabricate ceramic parts with complex geometry, no cracks and linear shrinkage. Guiding with the principles of impedance matching, attenuation, and effective-medium theory, we design a cross-helix-array metamaterial model based on the complex permittivity constant of precursor-derived ceramics. The corresponding ceramic metamaterials can be successfully prepared by DLP printing and subsequent pyrolysis process, achieving a low reflection coefficient and a wide effective absorption bandwidth in the X-band even under high temperature. This is a general method that can be extended to other bands, which can be realized by merely adjusting the unit structure of metamaterials. This strategy provides a novel and effective avenue to achieve target-design-fabricating ceramic metamaterials, and it exposes the downstream applications of highly efficient and broad EM wave-absorbing materials and structures with great potential applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 122, "DOI": "10.1007/s40820-022-00865-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00865-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791391000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, G; Biswal, BP; Kandambeth, S; Venkatesh, V; Kaur, G; Addicoat, M; Heine, T; Verma, S; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, Gobinda; Biswal, Bishnu P.; Kandambeth, Sharath; Venkatesh, V.; Kaur, Gagandeep; Addicoat, Matthew; Heine, Thomas; Verma, Sandeep; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical sensing in two dimensional porous covalent organic nullosheets", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two new imide-based crystalline, porous, and chemically stable covalent organic frameworks (COFs) (TpBDH and TfpBDH) have been successfully synthesized employing solvothermal crystallization route. Furthermore, thin layered covalent organic nullosheets (CONs) were derived from these bulk COFs by the simple liquid phase exfoliation method. These 2D CONs showcase increased luminescence intensity compared to their bulk counterparts (COFs). Notably, TfpBDH-CONs showcase good selectivity and prominent, direct visual detection towards different nitroaromatic analytes over TpBDH-CONs. Quite interestingly, TfpBDH-CONs exhibit a superior turn-on detection capability for 2,4,6-trinitrophenol (TNP) in the solid state, but conversely, they also show a turn-off detection in the dispersion state. These findings describe a new approach towards developing an efficient, promising fluorescence chemosensor material for both visual and spectroscopic detection of nitroaromatic compounds with very low [10(-5) (M)] analyte concentrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3931, "End Page": 3939, "Article Number": null, "DOI": "10.1039/c5sc00512d", "DOI Link": "http://dx.doi.org/10.1039/c5sc00512d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356176200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, S; Qin, JS; Lollar, CT; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Shuai; Qin, Jun-Sheng; Lollar, Christina T.; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable Metal-Organic Frameworks with Group 4 Metals: Current Status and Trends", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Group 4 metal-based metal-organic frameworks (MIV-MOFs), including Ti-, Zr-, and Hf-based MOFs, are one of the most attractive classes of MOF materials owing to their superior chemical stability and structural tunability. Despite being a relatively new field, MIV-MOFs have attracted significant research attention in the past few years, leading to exciting advances in syntheses and applications. In this outlook, we start with a brief overview of the history and current status of MIV-MOFs, emphasizing the challenges encountered in their syntheses. The unique properties of MIV-MOFs are discussed, including their high chemical stability and strong tolerance toward defects. Particular emphasis is placed on defect engineering in Zr-MOFs which offers additional routes to tailor their functions. Photocatalysis of MIV-MOF is introduced as a representative example of their emerging applications. Finally, we conclude with the perspective of new opportunities in synthesis and defect engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2018, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 440, "End Page": 450, "Article Number": null, "DOI": "10.1021/acscentsci.8b00073", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.8b00073", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431150500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JJ; Zhao, L; Deng, YH; Xiao, X; Ni, ZY; Xu, S; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jingjing; Zhao, Liang; Deng, Yehao; Xiao, Xun; Ni, Zhenyi; Xu, Shuang; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The soft nature of metal halide perovskites makes them potentially applicable as flexible X-ray detectors. Here we report a structure of perovskite-filled membranes (PFMs) for highly sensitive, flexible and large-area X-ray detectors. PFMs with areas up to 400 cm(2)are formed by infiltrating saturated perovskite solution through porous polymer membranes followed by hot lamination. The good connectivity and crystallization of perovskite crystals in the membranes enable a large mobility-lifetime product. The sensitivity of the X-ray detectors under a field of 0.05 V mu m(-1)reaches 8,696 +/- 228 mu C Gy(air)(-1) cm(-2)and shows no degradation after storage for over six months and exposure to a dose of 376.8 Gy(air), equivalent to 1.88 million chest X-ray scans. The flexible PFMs can be bent at radii down to 2 mm without losing performance. The stand-alone detector array is curved and put inside metal pipes for the detection of material defects with imaging quality superior to flat-panel detectors. Perovskite-filled-membranes enable flexible, sensitive and large-area X-ray detectors. The structures are made by infiltrating perovskite solution into porous polymer membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 612, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-020-0678-x", "DOI Link": "http://dx.doi.org/10.1038/s41566-020-0678-x", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560317300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, TL; Li, J; Zheng, F; Chen, WJ; Wen, XM; Ku, ZL; Peng, Y; Zhong, J; Cheng, YB; Huang, FZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Tongle; Li, Jing; Zheng, Fei; Chen, Weijian; Wen, Xiaoming; Ku, Zhiliang; Peng, Yong; Zhong, Jie; Cheng, Yi-Bing; Huang, Fuzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal passivation strategy to slot-die printed SnO2 for hysteresis-free efficient flexible perovskite solar module", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) have reached an impressive efficiency over 23%. One of its promising characteristics is the low-cost solution printability, especially for flexible solar cells. However, printing large area uniform electron transport layers on rough and soft plastic substrates without hysteresis is still a great challenge. Herein, we demonstrate slot-die printed high quality tin oxide films for high efficiency flexible PSCs. The inherent hysteresis induced by the tin oxide layer is suppressed using a universal potassium interfacial passivation strategy regardless of fabricating methods. Results show that the potassium cations, not the anions, facilitate the growth of perovskite grains, passivate the interface, and contribute to the enhanced efficiency and stability. The small size flexible PSCs achieve a high efficiency of 17.18% and large size (5 x 6 cm(2)) flexible modules obtain an efficiency over 15%. This passivation strategy has shown great promise for pursuing high performance large area flexible PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 673, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4609, "DOI": "10.1038/s41467-018-07099-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07099-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449069700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khan, AI; Chatterjee, K; Wang, B; Drapcho, S; You, L; Serrao, C; Bakaul, SR; Ramesh, R; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khan, Asif Islam; Chatterjee, Korok; Wang, Brian; Drapcho, Steven; You, Long; Serrao, Claudy; Bakaul, Saidur Rahman; Ramesh, Ramamoorthy; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative capacitance in a ferroelectric capacitor", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Boltzmann distribution of electrons poses a fundamental barrier to lowering energy dissipation in conventional electronics, often termed as Boltzmann Tyranny(1-5). Negative capacitance in ferroelectric materials, which stems from the stored energy of a phase transition, could provide a solution, but a direct measurement of negative capacitance has so far been elusive(1-3). Here, we report the observation of negative capacitance in a thin, epitaxial ferroelectric film. When a voltage pulse is applied, the voltage across the ferroelectric capacitor is found to be decreasing with time-in exactly the opposite direction to which voltage for a regular capacitor should change. Analysis of this 'inductance'-like behaviour from a capacitor presents an unprecedented insight into the intrinsic energy profile of the ferroelectric material and could pave the way for completely new applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 653, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 182, "End Page": 186, "Article Number": null, "DOI": "10.1038/NMAT4148", "DOI Link": "http://dx.doi.org/10.1038/NMAT4148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348600200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JW; Song, LR; Pedersen, SH; Yin, H; Hung, LT; Iversen, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiawei; Song, Lirong; Pedersen, Steffen Hindborg; Yin, Hao; Le Thanh Hung; Iversen, Bo Brummerstedt", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of high-performance low-cost n-type Mg3Sb2-based thermoelectric materials with multi-valley conduction bands", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Widespread application of thermoelectric devices for waste heat recovery requires low-cost high-performance materials. The currently available n-type thermoelectric materials are limited either by their low efficiencies or by being based on expensive, scarce or toxic elements. Here we report a low-cost n-type material, Te-doped Mg3Sb1.5Bi0.5, that exhibits a very high figure of merit zT ranging from 0.56 to 1.65 at 300 - 725 K. Using combined theoretical prediction and experimental validation, we show that the high thermoelectric performance originates from the significantly enhanced power factor because of the multivalley band behaviour dominated by a unique near-edge conduction band with a sixfold valley degeneracy. This makes Te-doped Mg3Sb1.5Bi0.5 a promising candidate for the low-and intermediate-temperature thermoelectric applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 514, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13901, "DOI": "10.1038/ncomms13901", "DOI Link": "http://dx.doi.org/10.1038/ncomms13901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391306300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SW; Du, YJ; Alsaid, Y; Wu, D; Hua, MT; Yan, YC; Yao, BW; Ma, YF; Zhu, XY; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuwang; Du, Yingjie; Alsaid, Yousif; Wu, Dong; Hua, Mutian; Yan, Yichen; Yao, Bowen; Ma, Yanfei; Zhu, Xinyuan; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superhydrophobic photothermal icephobic surfaces based on candle soot", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ice accumulation causes various problems in our daily life for human society. The daunting challenges in ice prevention and removal call for novel efficient antiicing strategies. Recently, photothermal materials have gained attention for creating icephobic surfaces owing to their merits of energy conservation and environmental friendliness. However, it is always challenging to get an ideal photothermal material which is cheap, easily fabricating, and highly photothermally efficient. Here, we demonstrate a low-cost, high-efficiency superhydrophobic photothermal surface, uniquely based on inexpensive commonly seen candle soot. It consists of three components: candle soot, silica shell, and poly-dimethylsiloxane (PDMS) brushes. The candle soot provides hierarchical nullo/microstructures and photothermal ability, the silica shell strengthens the hierarchical candle soot, and the grafted low-surface-energy PDMS brushes endow the surface with superhydro-phobicity. Upon illumination under 1 sun, the surface temperature can increase by 53 degrees C, so that no ice can form at an environmental temperature as low as -50 degrees C and it can also rapidly melt the accumulated frost and ice in 300 s. The superhydrophobicity enables the melted water to slide away immediately, leaving a clean and dry surface. The surface can also self-clean, which further enhances its effectiveness by removing dust and other contaminullts which absorb and scatter sunlight. In addition, after oxygen plasma treatment, the surface can restore superhydrophobicity with sunlight illumination. The presented icephobic surface shows great potential and broad impacts owing to its inexpensive component materials, simplicity, ecofriendliness, and high energy efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2020, "Volume": 117, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11240, "End Page": 11246, "Article Number": null, "DOI": "10.1073/pnas.2001972117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2001972117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536797100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YC; Min, XB; Ke, Y; Liu, DG; Tang, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuancheng; Min, Xiaobo; Ke, Yong; Liu, Degang; Tang, Chongjian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of red mud-based geopolymer materials from MSWI fly ash and red mud by mechanical activation", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel method to activate red mud was proposed in this study. Municipal solid waste incineration fly ash (MSWIFA) and red mud were utilized to prepare red mud-based geopolymer materials (RGM). The hydration characteristics of RGM were studied by X-ray diffraction, scanning electronic microscopy, and Fourier transform infrared spectroscopy. The long-term stability and physical properties of RGM were tested by freeze-thaw cycle, European Community Bureau reference (BCR) and unconfined compressive strength (UCS) tests. Results showed that mechanical activation can not only effectively activate red mud, but also effectively improve the reaction of MSWIFA and red mud. When 14% sodium silicate was added to the binder, the UCS reached 12.75 MPa at 28 days. In the RGM, aluminosilicate was effectively activated by mechanical activation and reacted with calcium ion to form complex hydration products. The activator reacts adequately with activated aluminum to form a high-strength geopolymer. The freeze-thaw cycles and BCR test results also showed that the RGM had long-term stability and the characteristics satisfied the requirements of MU10 fly ash bricks. This study demonstrated that RGM may be utilized in cement composites. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 83, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 202, "End Page": 208, "Article Number": null, "DOI": "10.1016/j.wasman.2018.11.019", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2018.11.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454371400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dequilettes, DW; Zhang, W; Burlakov, VM; Graham, DJ; Leijtens, T; Osherov, A; Bulovic, V; Snaith, HJ; Ginger, DS; Stranks, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "deQuilettes, Dane W.; Zhang, Wei; Burlakov, Victor M.; Graham, Daniel J.; Leijtens, Tomas; Osherov, Anna; Bulovic, Vladimir; Snaith, Henry J.; Ginger, David S.; Stranks, Samuel D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photo-induced halide redistribution in organic-inorganic perovskite films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic perovskites such as CH3NH3PbI3 are promising materials for a variety of optoelectronic applications, with certified power conversion efficiencies in solar cells already exceeding 21%. Nevertheless, state-of-the-art films still contain performance-limiting non-radiative recombination sites and exhibit a range of complex dynamic phenomena under illumination that remain poorly understood. Here we use a unique combination of confocal photoluminescence (PL) microscopy and chemical imaging to correlate the local changes in photophysics with composition in CH3NH3PbI3 films under illumination. We demonstrate that the photo-induced 'brightening' of the perovskite PL can be attributed to an order-of-magnitude reduction in trap state density. By imaging the same regions with time-of-flight secondary-ion-mass spectrometry, we correlate this photobrightening with a net migration of iodine. Our work provides visual evidence for photo-induced halide migration in triiodide perovskites and reveals the complex interplay between charge carrier populations, electronic traps and mobile halides that collectively impact optoelectronic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 828, "Times Cited, All Databases": 892, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11683, "DOI": "10.1038/ncomms11683", "DOI Link": "http://dx.doi.org/10.1038/ncomms11683", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376616900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oyedele, AD; Yang, SZ; Liang, LB; Puretzky, AA; Wang, K; Zheng, JJ; Yu, P; Pudasaini, PR; Ghosh, AW; Liu, Z; Rouleau, CM; Sumpter, BG; Chisholm, MF; Zhou, W; Rack, PD; Geohegan, DB; Xiao, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oyedele, Akinola D.; Yang, Shize; Liang, Liangbo; Puretzky, Alexander A.; Wang, Kai; Zheng, Jingjie; Yu, Peng; Pudasaini, Pushpa R.; Ghosh, Avik W.; Liu, Zheng; Rouleau, Christopher M.; Sumpter, Bobby G.; Chisholm, Matthew F.; Zhou, Wu; Rack, Philip D.; Geohegan, David B.; Xiao, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PdSe2: Pentagonal Two-Dimensional Layers with High Air Stability for Electronics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most studied two-dimensional (2D) materials exhibit isotropic behavior due to high lattice symmetry; however, lower-symmetry 2D materials such as phosphorene and other elemental 2D materials exhibit very interesting anisotropic properties. In this work, we report the atomic structure, electronic properties, and vibrational modes of few layered PdSe2 exfoliated from bulk crystals, a pentagonal 2D layered noble transition metal dichalcogenide with a puckered morphology that is air stable. Micro-absorption optical spectroscopy and first-principles calculations reveal a wide band gap variation in, this material from 0 (bulk) to 1.3 eV (monolayer). The Raman-active vibrational modes of PdSe2 were identified using polarized Raman spectroscopy, and a strong interlayer interaction was revealed from large, thickness-dependent Raman peak shifts, agreeing with first-principles Raman simulations. Field-effect transistors made from the few-layer PdSe2 display tunable ambipolar charge carrier conduction with a high electron field-effect mobility of similar to 158 cm(2) V-1 s(-1),indicating the promise of this anisotropic, air-stable, pentagonal 2D material for 2D electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 597, "Times Cited, All Databases": 624, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 139, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14090, "End Page": 14097, "Article Number": null, "DOI": "10.1021/jacs.7b04865", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b04865", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413057100028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Henkensmeier, D; Najibah, M; Harms, C; Zitka, J; Hnát, J; Bouzek, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Henkensmeier, Dirk; Najibah, Malikah; Harms, Corinna; Zitka, Jan; Hnat, Jaromir; Bouzek, Karel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overview: State-of-the Art Commercial Membranes for Anion Exchange Membrane Water Electrolysis", "Source Title": "JOURNAL OF ELECTROCHEMICAL ENERGY CONVERSION AND STORAGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One promising way to store and distribute large amounts of renewable energy is water electrolysis, coupled with transport of hydrogen in the gas grid and storage in tanks and caverns. The intermittent availability of renewal energy makes it difficult to integrate it with established alkaline water electrolysis technology. Proton exchange membrane (PEM) water electrolysis (PEMEC) is promising, but limited by the necessity to use expensive platinum and iridium catalysts. The expected solution is anion exchange membrane (AEM) water electrolysis, which combines the use of cheap and abundant catalyst materials with the advantages of PEM water electrolysis, namely, a low foot print, large operational capacity, and fast response to changing operating conditions. The key component for AEM water electrolysis is a cheap, stable, gas tight and highly hydroxide conductive polymeric AEM. Here, we present target values and technical requirements for AEMs, discuss the chemical structures involved and the related degradation pathways, give an overview over the most prominent and promising commercial AEMs (Fumatech Fumasep(R) FAA3, Tokuyama A201, Ionomr Aemion((TM)), Dioxide materials Sustainion(R), and membranes commercialized by Orion Polymer), and review their properties and performances of water electrolyzers using these membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2021, "Volume": 18, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24001, "DOI": "10.1115/1.4047963", "DOI Link": "http://dx.doi.org/10.1115/1.4047963", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636262700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, GS; Kenney, M; Chen, YS; Zheng, XC; Deng, Y; Chen, Z; Wang, SX; Gambhir, SS; Dai, HJ; Rao, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Guosheng; Kenney, Michael; Chen, Yun-Sheng; Zheng, Xianchuang; Deng, Yong; Chen, Zhuo; Wang, Shan X.; Gambhir, Sanjiv Sam; Dai, Hongjie; Rao, Jianghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-coated FeCo nulloparticles as sensitive magnetic-particle-imaging tracers with photothermal and magnetothermal properties", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "FeCo nulloparticles with a graphitic carbon shell decorated with poly(ethylene glycol) have photothermal and magnetothermal properties and are sensitive tracers for magnetic particle imaging, magnetic resonullce imaging and photoacoustic imaging. The low magnetic saturation of iron oxide nulloparticles, which are developed primarily as contrast agents for magnetic resonullce imaging, limits the sensitivity of their detection using magnetic particle imaging (MPI). Here, we show that FeCo nulloparticles that have a core diameter of 10 nm and bear a graphitic carbon shell decorated with poly(ethylene glycol) provide an MPI signal intensity that is sixfold and fifteenfold higher than the signals from the superparamagnetic iron oxide tracers VivoTrax and Feraheme, respectively, at the same molar concentration of iron. We also show that the nulloparticles have photothermal and magnetothermal properties and can therefore be used for tumour ablation in mice, and that they have high optical absorbance in a broad near-infrared region spectral range (wavelength, 700-1,200 nm), making them suitable as tracers for photoacoustic imaging. As sensitive multifunctional and multimodal imaging tracers, carbon-coated FeCo nulloparticles may confer advantages in cancer imaging and hyperthermia therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 325, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41551-019-0506-0", "DOI Link": "http://dx.doi.org/10.1038/s41551-019-0506-0", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510821600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stolterfoht, M; Wolff, CM; Márquez, JA; Zhang, SS; Hages, CJ; Rothhardt, D; Albrecht, S; Burn, PL; Meredith, P; Unold, T; Neher, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stolterfoht, Martin; Wolff, Christian M.; Marquez, Jose A.; Zhang, Shanshan; Hages, Charles J.; Rothhardt, Daniel; Albrecht, Steve; Burn, Paul L.; Meredith, Paul; Unold, Thomas; Neher, Dieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of perovskite solar cells is predominulltly limited by non-radiative recombination, either through trap-assisted recombination in the absorber layer or via minority carrier recombination at the perovskite/transport layer interfaces. Here, we use transient and absolute photoluminescence imaging to visualize all non-radiative recombination pathways in planar pintype perovskite solar cells with undoped organic charge transport layers. We find significant quasi-Fermi-level splitting losses (135 meV) in the perovskite bulk, whereas interfacial recombination results in an additional free energy loss of 80 meV at each individual interface, which limits the open-circuit voltage (V-oc) of the complete cell to similar to 1.12 V. Inserting ultrathin interlayers between the perovskite and transport layers leads to a substantial reduction of these interfacial losses at both the p and n contacts. Using this knowledge and approach, we demonstrate reproducible dopant-free 1 cm(2) perovskite solar cells surpassing 20% efficiency (19.83% certified) with stabilized power output, a high V-oc (1.17 V) and record fill factor (>81%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 814, "Times Cited, All Databases": 846, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 847, "End Page": 854, "Article Number": null, "DOI": "10.1038/s41560-018-0219-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0219-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446724600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arcudi, F; Dordevic, L; Prato, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arcudi, Francesca; Dordevic, Luka; Prato, Maurizio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis, Separation, and Characterization of Small and Highly Fluorescent Nitrogen-Doped Carbon nulloDots", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile bottom-up approach to carbon nullodots (CNDs) is reported, using a microwave-assisted procedure under controlled conditions. The as-prepared nitrogen-doped CNDs (NCNDs) show narrow size-distribution, abundant surface traps and functional groups, resulting in tunable fluorescent emission and excellent solubility in water. Moreover, we present a general method for the separation of NCNDs by low-pressure size-exclusion chromatography, leading to an even narrower size distribution, different surface composition, and optical properties. They display among the smallest size and the highest FLQYs reported so far. C-13-enriched starting materials produced N(13)CNDs suitable for thorough NMR studies, which gave useful information on their molecular structure. Moreover, they can be easily functionalized and can be used as water-soluble carriers. This work provides an avenue to size- and surface-controllable and structurally defined NCNDs for applications in areas such as optoelectronics, biomedicine, and bioimaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2016, "Volume": 55, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2107, "End Page": 2112, "Article Number": null, "DOI": "10.1002/anie.201510158", "DOI Link": "http://dx.doi.org/10.1002/anie.201510158", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854700028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, DM; Lu, KD; Poon, C; Lin, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Demin; Lu, Kuangda; Poon, Christopher; Lin, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks as Sensory Materials and Imaging Agents", "Source Title": "INORGANIC CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are a class of hybrid materials self-assembled from organic bridging ligands and metal ion/cluster connecting points. The combination of a variety of organic linkers, metal ions/clusters, and structural motifs can lead to an infinite array of new materials with interesting properties for many applications. In this Forum Article, we discuss the design and applications of MOFs in chemical sensing and biological imaging. The first half of this article focuses on the development of MOFs as chemical sensors by highlighting how unique attributes of MOFs can be utilized to enhance sensitivity and selectivity. We also discuss some of the issues that need to be addressed in order to develop practically useful MOF sensors. The second half of this article focuses on the design and applications of nulloscale MOFs (NMOFs) as imaging contrast agents. NMOFs possess several interesting attributes, such as high cargo loading capacity, ease of postmodification, tunable size and shape, and intrinsic biodegradability, to make them excellent candidates as imaging contrast agents. We discuss the use of representative NMOFs in magnetic resonullce imaging (MRI), X-ray computed tomography (CT), and optical imaging. Although still in their infancy, we believe that the compositional tunability and mild synthetic conditions of NMOF imaging agents should greatly facilitate their further development for clinical translation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2014, "Volume": 53, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1916, "End Page": 1924, "Article Number": null, "DOI": "10.1021/ic402194c", "DOI Link": "http://dx.doi.org/10.1021/ic402194c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332144100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, H; Chen, Y; Shi, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Han; Chen, Yu; Shi, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into 2D MXenes for Versatile Biomedical Applications: Current Advances and Challenges Ahead", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Great and interdisciplinary research efforts have been devoted to the biomedical applications of 2D materials because of their unique planar structure and prominent physiochemical properties. Generally, ceramic-based biomaterials, fabricated by high-temperature solid-phase reactions, are preferred as bone scaffolds in hard tissue engineering because of their controllable biocompatibility and satisfactory mechanical property, but their potential biomedical applications in disease theranostics are paid much less attention, mainly due to their lack of related material functionalities for possibly entering and circulating within the vascular system. The emerging 2D MXenes, a family of ultrathin atomic nullosheet materials derived from MAX phase ceramics, are currently booming as novel inorganic nullosystems for biologic and biomedical applications. The metallic conductivity, hydrophilic nature, and other unique physiochemical performances make it possible for the 2D MXenes to meet the strict requirements of biomedicine. This work introduces the very recent progress and novel paradigms of 2D MXenes for state-of-the-art biomedical applications, focusing on the design/synthesis strategies, therapeutic modalities, diagnostic imaging, biosensing, antimicrobial, and biosafety issues. It is highly expected that the elaborately engineered ultrathin MXenes nullosheets will become one of the most attractive biocompatible inorganic nulloplatforms for multiple and extensive biomedical applications to profit the clinical translation of nullomedicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800518, "DOI": "10.1002/advs.201800518", "DOI Link": "http://dx.doi.org/10.1002/advs.201800518", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Castle, E; Csanádi, T; Grasso, S; Dusza, J; Reece, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Castle, Elinor; Csanadi, Tamas; Grasso, Salvatore; Dusza, Jan; Reece, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Processing and Properties of High-Entropy Ultra-High Temperature Carbides", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bulkequiatomic (Hf-Ta-Zr-Ti)C and (Hf-Ta-Zr-Nb)C high entropy Ultra-High Temperature Ceramic (UHTC) carbide compositions were fabricated by ball milling and Spark Plasma Sintering (SPS). It was found that the lattice parameter mismatch of the component monocarbides is a key factor for predicting single phase solid solution formation.The processing route was further optimised forthe (Hf-Ta-Zr-Nb) C composition to produce a high purity, single phase, homogeneous, bulk high entropy material (99% density); revealing avast new compositional space for the exploration of new UHTCs. One sample was observed to chemically decompose; indicating the presence of a miscibility gap. While this suggests the system is not thermodynamically stable to room temperature, it does reveal further potential for the development of new in situ formed UHTC nullocomposites.The optimised material was subjected to nulloindentation testing and directly compared to the constituent mono/binary carbides, revealing a significantly enhanced hardness (36.1 +/- 1.6 GPa,) compared to the hardest monocarbide (HfC, 31.5 +/- 1.3GPa) and the binary (Hf-Ta)C (32.9 +/- 1.8GPa).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 639, "Times Cited, All Databases": 678, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8609, "DOI": "10.1038/s41598-018-26827-1", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-26827-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434122600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, XC; Wu, L; Yan, HY; Jiang, ZY; Li, SL; Li, W; Bai, YL; Wang, HJ; Cheng, ZJ; Kong, DL; Wang, LY; Zhu, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Xinchen; Wu, Le; Yan, Hongyu; Jiang, Zhuyan; Li, Shilin; Li, Wen; Bai, Yanli; Wang, Hongjun; Cheng, Zhaojun; Kong, Deling; Wang, Lianyong; Zhu, Meifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microchannelled alkylated chitosan sponge to treat noncompressible hemorrhages and facilitate wound healing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing an anti-infective shape-memory hemostatic sponge able to guide in situ tissue regeneration for noncompressible hemorrhages in civilian and battlefield settings remains a challenge. Here we engineer hemostatic chitosan sponges with highly interconnective microchannels by combining 3D printed microfiber leaching, freeze-drying, and superficial active modification. We demonstrate that the microchannelled alkylated chitosan sponge (MACS) exhibits the capacity for water and blood absorption, as well as rapid shape recovery. We show that compared to clinically used gauze, gelatin sponge, CELOX (TM), and CELOX (TM) -gauze, the MACS provides higher pro-coagulant and hemostatic capacities in lethally normal and heparinized rat and pig liver perforation wound models. We demonstrate its anti-infective activity against S. aureus and E. coli and its promotion of liver parenchymal cell infiltration, vascularization, and tissue integration in a rat liver defect model. Overall, the MACS demonstrates promising clinical translational potential in treating lethal noncompressible hemorrhage and facilitating wound healing. Developing effective treatments for noncompressible hemorrhages remains a challenge. Here the authors engineer alkylated chitosan sponges with highly interconnective microchannels and demonstrate anti-infective activity, as well as higher pro-coagulant, hemostatic and wound healing capacities compared to clinically-used materials in rat and pig liver models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4733, "DOI": "10.1038/s41467-021-24972-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24972-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684407600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Li, GD; Pei, A; Li, YZ; Liao, L; Wang, HX; Wan, JY; Liang, Z; Chen, GX; Zhang, H; Wang, JY; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wei; Li, Guodong; Pei, Allen; Li, Yuzhang; Liao, Lei; Wang, Hongxia; Wan, Jiayu; Liang, Zheng; Chen, Guangxu; Zhang, Hao; Wang, Jiangyan; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A manganese-hydrogen battery with potential for grid-scale energy storage", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Batteries including lithium-ion, lead-acid, redox-flow and liquid-metal batteries show promise for grid-scale storage, but they are still far from meeting the grid's storage needs such as low cost, long cycle life, reliable safety and reasonable energy density for cost and footprint reduction. Here, we report a rechargeable manganese-hydrogen battery, where the cathode is cycled between soluble Mn2+ and solid MnO2 with a two-electron reaction, and the anode is cycled between H-2 gas and H2O through well-known catalytic reactions of hydrogen evolution and oxidation. This battery chemistry exhibits a discharge voltage of similar to 1.3 V, a rate capability of 100 mA cm(-2) (36s of discharge) and a lifetime of more than 10,000 cycles without decay. We achieve a gravimetric energy density of similar to 139 Wh kg(-1) (volumetric energy density of similar to 210 Whl(-1)), with the theoretical gravimetric energy density of similar to 174 Wh kg(-1) (volumetric energy density of similar to 263 Whl(-1)) in a 4M MnSO4 electrolyte. The manganese-hydrogen battery involves low-cost abundant materials and has the potential to be scaled up for large-scale energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 428, "End Page": 435, "Article Number": null, "DOI": "10.1038/s41560-018-0147-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0147-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433029700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, YY; Guo, JN; Liu, ZY; Sun, Z; Wu, YQ; Liu, LL; Yang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Yongyuan; Guo, Jiangna; Liu, Ziyang; Sun, Zhe; Wu, Yiqing; Liu, Lili; Yang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic liquid-based click-ionogels", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gels that are freeze-resistant and heat-resistant and have high ultimate tensile strength are desirable in practical applications owing to their potential in designing flexible energy storage devices, actuators, and sensors. Here, a simple method for fabricating ionic liquid (IL)-based click-ionogels using thiol-ene click chemistry under mild condition is reported. These click-ionogels continue to exhibit excellent mechanical properties and resilience after 10,000 fatigue cycles. Moreover, due to several unique properties of ILs, these click-ionogels exhibit high ionic conductivity, transparency, and nonflammability performance over a wide temperature range (-75 degrees to 340 degrees C). Click-ionogel-based triboelectric nullogenerators exhibit excellent mechanical, freeze-thaw, and heat stability. These promising features of click-ionogels will promote innovative applications in flexible and safe device design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax0648", "DOI": "10.1126/sciadv.aax0648", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax0648", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482759500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Zha, X; Zhou, X; Chen, F; Gao, G; Wang, S; Shen, C; Chen, T; Zhi, C; Eklund, P; Du, S; Xue, J; Shi, W; Chai, Z; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jie; Zha, Xianhu; Zhou, Xiaobing; Chen, Fanyan; Gao, Guoliang; Wang, Shuwei; Shen, Cai; Chen, Tao; Zhi, Chunyi; Eklund, Per; Du, Shiyu; Xue, Jianming; Shi, Weiqun; Chai, Zhifang; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and Electrochemical Properties of Two-Dimensional Hafnium Carbide", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate fabrication of a two-dimensional Hf-containing MXene, Hf3C2Tz, by selective etching of a layered parent Hf-3[Al(Si)](4)C-6 compound. A substitutional solution of Si on Al sites effectively weakened the interfacial adhesion between Hf-C and Al(Si)-C sublayers within the unit cell of the parent compound, facilitating the subsequent selective etching. The underlying mechanism of the Si-alloying-facilitated etching process is thoroughly studied by first-principles density functional calculations. The result showed that more valence electrons of Si than Al weaken the adhesive energy of the etching interface. The MXenes were determined to be flexible and conductive. Moreover, this 2D Hf-containing MXene material showed reversible volumetric capacities of 1567 and 504 mAh cm(-3) for lithium and sodium ions batteries, respectively, at a current density of 200 mAg(-1) after 200 cycles. Thus, Hf3C2Tz MXenes with a 2D structure are candidate anode materials for metal-ion intercalation, especially for applications where size matters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3841, "End Page": 3850, "Article Number": null, "DOI": "10.1021/acsnullo.7b00030", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b00030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400233200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Z; Li, BQ; Chu, JY; Zhang, PF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhen; Li, Baoqiang; Chu, Jiayu; Zhang, Peifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silica in situ enhanced PVA/chitosan biodegradable films for food packages", "Source Title": "CARBOHYDRATE POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-degradable plastic food packages threaten the security of environment. The cost-effective and biodegradable polymer films with good mechanical properties and low permeability are very important for food packages. Among of biodegradable polymers, PVA/chitosan (CS) biodegradable films have attracted considerable attention because of feasible film forming ability. However, PVA/CS biodegradable films suffered from poor mechanical properties. To improve mechanical properties of PVA/CS biodegradable films, we developed SiO2 in situ to enhance PVA/CS biodegradable films via hydrolysis of sodium metasilicate in presence of PVA and chitosan solution. The tensile strength of PVA/CS biodegradable films was improved 45% when 0.6 wt.% SiO2 was incorporated into the films. Weight loss of PVA/CS biodegradable films was 60% after 30 days in the soil. The permeability of oxygen and moisture of PVA/CS biodegradable films was reduced by 25.6% and 10.2%, respectively. SiO2 in situ enhanced PVA/CS biodegradable films possessed not only excellent mechanical properties, but also barrier of oxygen and water for food packages to extend the perseveration time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 184, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": 220, "Article Number": null, "DOI": "10.1016/j.carbpol.2017.12.043", "DOI Link": "http://dx.doi.org/10.1016/j.carbpol.2017.12.043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423720500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, LD; Urushihara, M; Chan, KR; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Leanne D.; Urushihara, Makoto; Chan, Karen; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric Field Effects in Electrochemical CO2 Reduction", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 has the potential to reduce greenhouse gas emissions while providing energy storage and producing chemical feedstocks. A mechanistic understanding of the process is crucial to the discovery of efficient catalysts, and an atomistic description of the electrochemical interface is a major challenge due to its complexity. Here, we examine the CO2 -> CO electrocatalytic pathway on Ag(111) using density functional theory (DFT) calculations and an explicit model of the electrochemical interface. We show that the electric field from solvated cations in the double layer and their corresponding image charges on the metal surface significantly stabilizes key intermediates ->*CO2 and *COOH. At the field-stabilized sites, the formation of *CO is rate-determining. We present a microkinetic model that incorporates field effects and electrochemical barriers from ab initio calculations. The computed polarization curves show reasonable agreement with experiment without fitting any parameters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 540, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7133, "End Page": 7139, "Article Number": null, "DOI": "10.1021/acscatal.6b02299", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b02299", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385057900095", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, Y; Sun, SN; Sun, YM; Xi, SB; Chi, X; Zhang, QH; Ren, X; Wang, JX; Ong, SJH; Du, YH; Gu, L; Grimaud, A; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Yan; Sun, Shengnull; Sun, Yuanmiao; Xi, Shibo; Chi, Xiao; Zhang, Qinghua; Ren, Xiao; Wang, Jingxian; Ong, Samuel Jun Hoong; Du, Yonghua; Gu, Lin; Grimaud, Alexis; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mastering Surface Reconstruction of Metastable Spinel Oxides for Better Water Oxidation", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing highly active electrocatalysts for oxygen evolution reaction (OER) is critical for the effectiveness of water splitting. Low-cost spinel oxides have attracted increasing interest as alternatives to noble metal-based OER catalysts. A rational design of spinel catalysts can be guided by studying the structural/elemental properties that determine the reaction mechanism and activity. Here, using density functional theory (DFT) calculations, it is found that the relative position of O p-band and M-Oh (Co and Ni in octahedron) d-band center in ZnCo2-xNixO4 (x = 0-2) correlates with its stability as well as the possibility for lattice oxygen to participate in OER. Therefore, it is testified by synthesizing ZnCo2-xNixO4 spinel oxides, investigating their OER performance and surface evolution. Stable ZnCo2-xNixO4 (x = 0-0.4) follows adsorbate evolving mechanism under OER conditions. Lattice oxygen participates in the OER of metastable ZnCo2-xNixO4 (x = 0.6, 0.8) which gives rise to continuously formed oxyhydroxide as surface-active species and consequently enhances activity. ZnCo1.2Ni0.8O4 exhibits performance superior to the benchmarked IrO2. This work illuminates the design of highly active metastable spinel electrocatalysts through the prediction of the reaction mechanism and OER activity by determining the relative positions of the O p-band and the M-Oh d-band center.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 31, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1807898, "DOI": "10.1002/adma.201807898", "DOI Link": "http://dx.doi.org/10.1002/adma.201807898", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462619000026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, XR; Kuang, X; Roach, DJ; Wang, YQ; Hamel, CM; Lu, CL; Qi, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Xirui; Kuang, Xiao; Roach, Devin J.; Wang, Yaoqing; Hamel, Craig M.; Lu, Chunliang; Qi, H. Jerry", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrating digital light processing with direct ink writing for hybrid 3D printing of functional structures and devices", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As an emerging branch of additive manufacturing, multi-material 3D printing has drawn tremendous attention as it offers more design flexibility that can combine materials with various mechanical, chemical, thermal-mechanical or electrical properties. However, low cost, high-speed, high-resolution, and versatile multimaterial 3D printing methods are still lacking. In this paper, we present a new hybrid multi-material 3D printing system that consists of a top-down digital light processing (DLP) printing and a direct ink writing (DIW) printing to fabricate composite structures and unique devices in a single printing job. The vat photopolymerization-based DLP printing allows for high-speed and high-resolution printing of a material matrix with complex geometry. The material extrusion-based DIW printing enables the printing of functional material, including liquid crystal elastomers (LCEs) and conductive silver inks. With this hybrid 3D printing system, a wide choice of inks and resins can be used to print functional composites with tunable mechanical properties, enhanced interfacial bonding, and multifunctionality. We demonstrate that composites prototype, active soft robots, circuit-embedding architectures, and strain sensors can be successfully printed. This work provides a new and robust approach for 3D printing of multi-functional devices for broad applications in soft robotics, electronics, active metamaterials, and biomedical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 40, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101911, "DOI": "10.1016/j.addma.2021.101911", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.101911", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636557300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maculan, G; Sheikh, AD; Abdelhady, AL; Saidaminov, MI; Hague, MA; Murali, B; Alarousu, E; Mohammed, OF; Wu, T; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maculan, Giacomo; Sheikh, Arif D.; Abdelhady, Ahmed L.; Saidaminov, Makhsud I.; Hague, Md Azimul; Murali, Banavoth; Alarousu, Erkki; Mohammed, Omar F.; Wu, Tom; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CH3NH3PbCl3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals of hybrid perovskites have shown remarkably improved physical properties compared to their polycrystalline film counterparts, underscoring their importance in the further development of advanced semiconductor devices. Here we present a new method of growing sizable CH3NH3PbCl3 single crystals based on the retrograde solubility behavior of hybrid perovskites. We show, for the first time, the energy band structure, charge recombination, and transport properties of CH3NH3PbCl3 single crystals. These crystals exhibit trap-state density, charge carrier concentration, mobility, and diffusion length comparable with the best quality crystals of methylammonium lead iodide or bromide perovskites reported so far. The high quality of the crystal along with its suitable optical band gap enabled us to build an efficient visible-blind UV-photodetector, demonstrating its potential in optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 450, "Times Cited, All Databases": 501, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2015, "Volume": 6, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3781, "End Page": 3786, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b01666", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b01666", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362391000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fracaroli, AM; Furukawa, H; Suzuki, M; Dodd, M; Okajima, S; Gándara, F; Reimer, JA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu; Dodd, Matthew; Okajima, Satoshi; Gandara, Felipe; Reimer, Jeffrey A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The selective capture of carbon dioxide in the presence of water is an outstanding challenge. Here, we show that the interior of IRMOF-74-III can be covalently functionalized with primary amine (IRMOF-74-III-CH2NH2) and used for the selective capture of CO2 in 6596 relative humidity. This study encompasses the synthesis, structural characterization, gas adsorption, and CO2 capture properties of variously functionalized IRMOF-74-III compounds (IRMOF-74-III-CH3, -NH2, -CH(2)NHBoc, -CH(2)NMeBoc, -CH2NH2, and -CH2NHMe). Cross-polarization magic angle spinning C-13 NMR spectra showed that CO2 binds chemically to IRMOF-74-III-CH2NH2 and -CH2NHMe to make carbamic species. Carbon dioxide isotherms and breakthrough experiments show that IRMOF-74-III-CH2NH2 is especially efficient at taking up CO2 (3.2 mmol of CO2 per gram at 800 Torr) and, more significantly, removing CO2 from wet nitrogen gas streams with breakthrough time of 610 +/- 10 s g(-1) and full preservation of the IRMOF structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2014, "Volume": 136, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8863, "End Page": 8866, "Article Number": null, "DOI": "10.1021/ja503296c", "DOI Link": "http://dx.doi.org/10.1021/ja503296c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338184200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Iglesias, D; Giuliani, A; Melchionna, M; Marchesan, S; Criado, A; Nasi, L; Bevilacqua, M; Tavagnacco, C; Vizza, F; Prato, M; Fornasiero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Iglesias, Daniel; Giuliani, Angela; Melchionna, Michele; Marchesan, Silvia; Criado, Alejandro; Nasi, Lucia; Bevilacqua, Manuela; Tavagnacco, Claudio; Vizza, Francesco; Prato, Maurizio; Fornasiero, Paolo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-Doped Graphitized Carbon nullohorns as a Forefront Electrocatalyst in Highly Selective O2 Reduction to H2O2", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical oxygen reduction (ORR) is a challenging approach for the sustainable production of hydrogen peroxide (H2O2) and is also a reaction of relevance in fuel-cell applications. Here, we propose an outstanding metalfree electrocatalyst for the unexpectedly selective ORR to H2O2, consisting of graphitized N-doped single-wall carbon nullohorns (CNHs). The catalyst can operate at acidic pH to a faradic efficiency as high as 98%, but it also shows excellent performance at either physiological or alkaline pH. Moreover, the very positive onset potentials observed at all pH values investigated (+0.40 V, +0.53 V, and +0.71 V at pH 1.0, 7.4, and 13.0, respectively), good stability, and excellent reproducibility make this material a benchmark catalyst for ORR to H2O2. The outstanding activity arises from a combination of several factors, such as CNH-dependent facilitation of electron delivery, suitable porosity, and a favorable distribution of the types of N atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 106, "End Page": 123, "Article Number": null, "DOI": "10.1016/j.chempr.2017.10.013", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.10.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425276100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shahsavan, H; Aghakhani, A; Zeng, H; Guo, YB; Davidson, ZS; Priimagi, A; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shahsavan, Hamed; Aghakhani, Amirreza; Zeng, Hao; Guo, Yubing; Davidson, Zoey S.; Priimagi, Arri; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired underwater locomotion of light-driven liquid crystal gels", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft-bodied aquatic invertebrates, such as sea slugs and snails, are capable of diverse locomotion modes under water. Recapitulation of such multimodal aquatic locomotion in small-scale soft robots is challenging, due to difficulties in precise spatiotemporal control of deformations and inefficient underwater actuation of existing stimuli-responsive materials. Solving this challenge and devising efficient untethered manipulation of soft stimuli-responsive materials in the aquatic environment would significantly broaden their application potential in biomedical devices. We mimic locomotion modes common to sea invertebrates using monolithic liquid crystal gels (LCGs) with inherent light responsiveness and molecular anisotropy. We elicit diverse underwater locomotion modes, such as crawling, walking, jumping, and swimming, by local deformations induced by selective spatiotemporal light illumination. Our results underpin the pivotal role of the physicomechanical properties of LCGs in the realization of diverse modes of light-driven robotic underwater locomotion. We envisage that our results will introduce a toolbox for designing efficient untethered soft robots for fluidic environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2020, "Volume": 117, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5125, "End Page": 5133, "Article Number": null, "DOI": "10.1073/pnas.1917952117", "DOI Link": "http://dx.doi.org/10.1073/pnas.1917952117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519530400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Auvergniot, J; Cassel, A; Ledeuil, JB; Viallet, V; Seznec, V; Dedryvère, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Auvergniot, Jeremie; Cassel, Alice; Ledeuil, Jean-Bernard; Viallet, Virginie; Seznec, Vincent; Dedryvere, Remi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Stability of Argyrodite Li6PS5Cl toward LiCoO2, LiNi1/3Co1/3Mn1/3O2, and LiMn2O4 in Bulk All-Solid-State Batteries", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Argyrodite Li6PS5Cl is a good candidate for being a solid electrolyte for bulk all-solid-state Li-ion batteries because of its high ionic conductivity and its good processability. However, the interface stability of sulfide based electrolytes toward active materials (negative or positive electrodes) is known to be lower than that of oxide-based electrolytes. In this work, we investigate the interface stability of argyrodite toward several positive electrode materials: LiCoO2, LiNi1/3Co1/3Mn1/3O2, and LiMn2O4. All-solid-state half-cells were cycled, and the interface mechanisms were characterized by Auger electron spectroscopy and X-ray photoelectron spectroscopy. We show that Li6PS5Cl is oxidized into elemental sulfur, lithium polysulfides, P2Sx (x >= 5), phosphates, and LiCl at the interface with the positive electrode active materials. In spite of this interface reactivity, good capacity retention was observed over 300 cycles. Li6PS5Cl shows some reversible electrochemical activity (redox processes) that might contribute to the reversible capacity of the battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2017, "Volume": 29, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3883, "End Page": 3890, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b04990", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b04990", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401221700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YS; Zhao, Y; Yoon, SJ; Gambhir, SS; Emelianov, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yun-Sheng; Zhao, Yang; Yoon, Soon Joon; Gambhir, Sanjiv Sam; Emelianov, Stanislav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Miniature gold nullorods for photoacoustic molecular imaging in the second near-infrared optical window", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In photoacoustic imaging, the second near-infrared (NIR-II) window is where tissue generates the least background signal. However, the large size of the few available contrast agents in this spectral range impedes their pharmacokinetics and decreases their thermal stability, leading to unreliable photoacoustic imaging. Here, we report the synthesis of miniaturized gold nullorods absorbing in the NIR-II that are 5-11 times smaller than regular-sized gold nullorods with a similar aspect ratio. Under nullosecond pulsed laser illumination, small nullorods are about 3 times more thermally stable and generate 3.5 times stronger photoacoustic signal than their absorption-matched larger counterparts. These unexpected findings are confirmed using theoretical and numerical analysis, showing that photoacoustic signal is not only proportional to the optical absorption of the nulloparticle solution but also to the surface-to-volume ratio of the nulloparticles. In living tumour-bearing mice, these small targeted nullorods display a 30% improvement in efficiency of agent delivery to tumours and generate 4.5 times greater photoacoustic contrast.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 465, "End Page": 472, "Article Number": null, "DOI": "10.1038/s41565-019-0392-3", "DOI Link": "http://dx.doi.org/10.1038/s41565-019-0392-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467053100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faig, RW; Popp, TMO; Fracaroli, AM; Kapustin, EA; Kalmutzki, MJ; Altamimi, RM; Fathieh, F; Reimer, JA; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faig, Robinson W.; Popp, Thomas M. Osborn; Fracaroli, Alejandro M.; Kapustin, Eugene A.; Kalmutzki, Markus J.; Altamimi, Rashid M.; Fathieh, Farhad; Reimer, Jeffrey A.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Chemistry of CO2 Capture in an Amine-Functionalized Metal-Organic Framework under Dry and Humid Conditions", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of two primary alkylamine functionalities covalently tethered to the linkers of IRMOE-74-III results in a material that can uptake CO2 at low pressures through a chemisorption mechanism. In contrast to other primary amine-functionalized solid adsorbents that uptake CO2 primarily as ammonium carbamates, we observe using solid state NMR that the major chemisorption product for this material is carbamic acid. The equilibrium of reaction products also shifts to ammonium carbamate when water vapor is present; a new finding that has impact on control of the chemistry of CO2 capture in MOF materials and one that highlights the importance of geometric constraints and the mediating role of water within the pores of MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2017, "Volume": 139, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12125, "End Page": 12128, "Article Number": null, "DOI": "10.1021/jacs.7b06382", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06382", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410255600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, P; Ren, YY; Wang, RT; Zhang, P; Ding, MJ; Li, CX; Zhao, DY; Qian, Z; Zhang, ZW; Zhang, LY; Yin, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peng; Ren, Yingying; Wang, Rutao; Zhang, Peng; Ding, Mingjie; Li, Caixia; Zhao, Danyang; Qian, Zhao; Zhang, Zhiwei; Zhang, Luyuan; Yin, Longwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed cobalt catalyst anchored on nitrogen-doped carbon nullosheets for lithium-oxygen batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing single-site catalysts featuring maximum atom utilization efficiency is urgently desired to improve oxidation-reduction efficiency and cycling capability of lithium-oxygen batteries. Here, we report a green method to synthesize isolated cobalt atoms embedded ultrathin nitrogen-rich carbon as a dual-catalyst for lithium-oxygen batteries. The achieved electrode with maximized exposed atomic active sites is beneficial for tailoring formation/decomposition mechanisms of uniformly distributed nullo-sized lithium peroxide during oxygen reduction/evolution reactions due to abundant cobalt-nitrogen coordinate catalytic sites, thus demonstrating greatly enhanced redox kinetics and efficiently ameliorated over-potentials. Critically, theoretical simulations disclose that rich cobalt-nitrogen moieties as the driving force centers can drastically enhance the intrinsic affinity of intermediate species and thus fundamentally tune the evolution mechanism of the size and distribution of final lithium peroxide. In the lithium-oxygen battery, the electrode affords remarkably decreased charge/discharge polarization (0.40V) and long-term cyclability (260 cycles at 400mAg(-1)). The performance of Li-O-2 batteries is largely determined by the oxygen electrocatalytic reactions at the cathode. Here, the authors report cobalt single-atom catalysts anchored on carbon nullosheets. The design improves oxygen redox kinetics and enables good electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1576, "DOI": "10.1038/s41467-020-15416-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15416-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522436700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Flöry, N; Ma, P; Salamin, Y; Emboras, A; Taniguchi, T; Watanabe, K; Leuthold, J; Novotny, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Flory, Nikolaus; Ma, Ping; Salamin, Yannick; Emboras, Alexandros; Taniguchi, Takashi; Watanabe, Kenji; Leuthold, Juerg; Novotny, Lukas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Waveguide-integrated van der Waals heterostructure photodetector at telecom wavelengths with high speed and high responsivity", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intensive efforts have been devoted to the exploration of new optoelectronic devices based on two-dimensional transition-metal dichalcogenides (TMDCs) owing to their strong light-matter interaction and distinctive material properties. In particular, photodetectors featuring both high-speed and high-responsivity performance are of great interest for a vast number of applications such as high-data-rate interconnects operated at standardized telecom wavelengths. Yet, the intrinsically small carrier mobilities of TMDCs become a bottleneck for high-speed application use. Here, we present high-performance vertical van der Waals heterostructure-based photodetectors integrated on a silicon photonics platform. Our vertical MoTe2-graphene heterostructure design minimizes the carrier transit path length in TMDCs and enables a record-high measured bandwidth of at least 24 GHz under a moderate bias voltage of -3 V. Applying a higher bias or employing thinner MoTe2 flakes boosts the bandwidth even to 50 GHz. Simultaneously, our device reaches a high external responsivity of 0.2 A W-1 for incident light at 1,300 nm, benefiting from the integrated waveguide design. Our studies shed light on performance trade-offs and present design guidelines for fast and efficient devices. The combination of two-diemensional heterostructures and integrated guided-wave nullo photonics defines an attractive platform to realize high-performance optoelectronic devices, such as photodetectors, light-emitting devices and electro-optic modulators. The low carrier mobilities of TMDCs pose a challenge for applications in high-speed photodetection. Integrating vertical two-dimensional heterostructures with photonic waveguides allows the intrinsic speed limitations to be overcome and record-high photodetection bandwidths to be achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 118, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-019-0602-z", "DOI Link": "http://dx.doi.org/10.1038/s41565-019-0602-z", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510822100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, LF; Xia, YD; Li, BX; Xing, GC; Chen, YH; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Lingfeng; Xia, Yingdong; Li, Bixin; Xing, Guichuan; Chen, Yonghua; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-Temperature Molten Salt for Facile Fabrication of Efficient and Stable Perovskite Solar Cells in Ambient Air", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we report an alternative environmentally friendly room-temperature molten salt, methylammonium acetate (MAAc), as a novel solvent for facile fabrication of perovskite solar cells (PSCs) in ambient air. MAAc possesses excellent chemical properties along with high viscosity, negligible vapor pressure, and a nonhazardous nature. Complete solubility of both methylammonium and lead salts by hydrogen bonds in MAAc was observed. Dense and pinholefree perovskite films with high reproducibility can be readily prepared by a simple one-step method without an anti-solvent even under a relative humidity of over 80%. Under optimized processing conditions, we achieved an average power conversion efficiency of 18.42% and a maximum efficiency of 20.05% in CH3NH3PbI3-based planar heterojunction structure. In addition, devices without encapsulation remained above 93% of their original efficiency for more than 1,000 h in ambient air. These findings may open up the possibility of developing a new approach for further improving PSC performance with higher reproducibility and reliability in ambient atmosphere.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2019, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 995, "End Page": 1006, "Article Number": null, "DOI": "10.1016/j.chempr.2019.02.025", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.02.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464241700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YX; Yang, ZX; Wang, YL; Bai, ZL; Zheng, T; Dai, X; Liu, ST; Gui, DX; Liu, W; Chen, M; Chen, LH; Diwu, J; Zhu, LY; Zhou, RH; Chai, ZF; Albrecht-Schmitt, TE; Wang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuxiang; Yang, Zaixing; Wang, Yanlong; Bai, Zhuanling; Zheng, Tao; Dai, Xing; Liu, Shengtang; Gui, Daxiang; Liu, Wei; Chen, Meng; Chen, Lanhua; Diwu, Juan; Zhu, Lingyan; Zhou, Ruhong; Chai, Zhifang; Albrecht-Schmitt, Thomas E.; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many environmental pollutants inherently exist in their anionic forms and are therefore highly mobile in natural water systems. Cationic framework materials that can capture those pollutants are highly desirable but scarcely reported. Here we present a mesoporous cationic thorium-based MOF (SCU-8) containing channels with a large inner diameter of 2.2 nm and possessing a high surface area of 1360 m(2) g(-1). The anion-exchange properties of SCU-8 were explored with many anions including small oxo anions like ReO4- and (CrO72-)-O-2 as well as anionic organic dyes like methyl blue and the persistent organic pollutant, perfluorooctane sulfonate (PFOS). Both fast uptake kinetics and great sorption selectivity toward PFOS are observed. The underlying sorption mechanism was probed using quantum mechanical and molecular dynamics simulations. These computational results reveal that PFOS anions are immobilized in SCU-8 by driving forces including electrostatic interactions, hydrogen bonds, hydrophobic interactions, and van der Waals interactions at different adsorption stages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1354, "DOI": "10.1038/s41467-017-01208-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01208-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414534700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YH; Lu, SY; Zhang, SS; Li, Y; Qu, Z; Chen, Y; Lu, BW; Wang, XY; Feng, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yihao; Lu, Siyuan; Zhang, Shasha; Li, Yan; Qu, Zhe; Chen, Ying; Lu, Bingwei; Wang, Xinyan; Feng, Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-like biosensor system via electrochemical channels for noninvasive blood glucose monitoring", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, noninvasive glucose monitoring is not widely appreciated because of its uncertain measurement accuracy, weak blood glucose correlation, and inability to detect hyperglycemia/hypoglycemia during sleep. We present a strategy to design and fabricate a skin-like biosensor system for noninvasive, in situ, and highly accurate intravascular blood glucose monitoring. The system integrates an ultrathin skin-like biosensor with paper battery-powered electrochemical twin channels (ETCs). The designed subcutaneous ETCs drive intravascular blood glucose out of the vessel and transport it to the skin surface. The ultrathin (similar to 3 mu m) nullostructured biosensor, with high sensitivity (130.4 mu A/mM), fully absorbs and measures the glucose, owing to its extreme conformability. We conducted in vivo human clinical trials. The noninvasive measurement results for intravascular blood glucose showed a high correlation (> 0.9) with clinically measured blood glucose levels. The system opens up new prospects for clinical-grade noninvasive continuous glucose monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1701629", "DOI": "10.1126/sciadv.1701629", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1701629", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426690900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, CS; Lv, C; Wang, LG; Cui, W; Zhang, LY; Dinh, KN; Tan, HT; Wu, C; Wu, TP; Ren, Y; Chen, JQ; Liu, Z; Srinivasan, M; Rui, XH; Yan, QY; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Chunshuang; Lv, Chade; Wang, Liguang; Cui, Wei; Zhang, Leyuan; Khang Ngoc Dinh; Tan, Huiteng; Wu, Chen; Wu, Tianpin; Ren, Yang; Chen, Jieqiong; Liu, Zheng; Srinivasan, Madhavi; Rui, Xianhong; Yan, Qingyu; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Architecting a Stable High-Energy Aqueous Al-Ion Battery", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Al-ion batteries (AAIBs) are the subject of great interest due to the inherent safety and high theoretical capacity of aluminum. The high abundancy and easy accessibility of aluminum raw materials further make AAIBs appealing for grid-scale energy storage. However, the passivating oxide film formation and hydrogen side reactions at the aluminum anode as well as limited availability of the cathode lead to low discharge voltage and poor cycling stability. Here, we proposed a new AAIB system consisting of an AlxMnO2 cathode, a zinc substrate-supported Zn-Al alloy anode, and an Al(OTF)(3) aqueous electrolyte. Through the in situ electrochemical activation of MnO, the cathode was synthesized to incorporate a two-electron reaction, thus enabling its high theoretical capacity. The anode was realized by a simple deposition process of Al3+ onto Zn foil substrate. The featured alloy interface layer can effectively alleviate the passivation and suppress the dendrite growth, ensuring ultralong-term stable aluminum stripping/plating. The architected cell delivers a record-high discharge voltage plateau near 1.6 V and specific capacity of 460 mAh g(-1) for over 80 cycles. This work provides new opportunities for the development of high-performance and low-cost AAIBs for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2020, "Volume": 142, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15295, "End Page": 15304, "Article Number": null, "DOI": "10.1021/jacs.0c05054", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c05054", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571437600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, ML; Yan, TT; Shen, JJ; Zhang, JP; Zhang, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Minlin; Yan, Tingting; Shen, Junjie; Zhang, Jianping; Zhang, Dengsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capacitive Removal of Heavy Metal Ions from Wastewater via an Electro-Adsorption and Electro-Reaction Coupling Process", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heavy metals widely exist in wastewater, which is a serious threat to human health or water environment. Highly efficient removal of heavy metal ions from wastewater is a major challenge to wastewater treatment. In this work, capacitive removal of heavy metal ions from wastewater via an electro-adsorption and electro-reaction coupling process was originally demonstrated. The removal efficiency of heavy metal ions in the binary-component solutions containing metal nitrate (10 mg/L) and NaCl (100 mg/L) can reach 99%. Even the removal efficiency of heavy metal ions can be close to 99% in the multi-component solution containing all the seven metal nitrates (10 mg/L for each) and 100 mg/L NaCl. Meanwhile, the electro-adsorption and electro-reaction coupling process maintained excellent regeneration ability even after 20 cycles. Furthermore, the heavy metal ions removal mechanism was proven to be the pseudocapacitive intercalation of heavy metal ions into the layered structure of the employed W18O49/graphene in the electro-adsorption and electro-reaction coupling process. This work demonstrates great potential for general applicability to wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2021, "Volume": 55, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3333, "End Page": 3340, "Article Number": null, "DOI": "10.1021/acs.est.0c07849", "DOI Link": "http://dx.doi.org/10.1021/acs.est.0c07849", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626270400063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, TL; Wang, HL; Li, B; Krishna, R; Wu, H; Zhou, W; Zhao, YF; Han, Y; Wang, X; Zhu, WD; Yao, ZZ; Xiang, SC; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Tong-Liang; Wang, Hailong; Li, Bin; Krishna, Rajamani; Wu, Hui; Zhou, Wei; Zhao, Yunfeng; Han, Yu; Wang, Xue; Zhu, Weidong; Yao, Zizhu; Xiang, Shengchang; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microporous metal-organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technologically very important, but highly challenging task. Current removal approaches include the partial hydrogenation over a noble metal catalyst and the solvent extraction of cracked olefins, both of which are cost and energy consumptive. Here we report a microporous metal-organic framework in which the suitable pore/cage spaces preferentially take up much more acetylene than ethylene while the functional amine groups on the pore/cage surfaces further enforce their interactions with acetylene molecules, leading to its superior performance for this separation. The single X-ray diffraction studies, temperature dependent gas sorption isotherms, simulated and experimental column breakthrough curves and molecular simulation studies collaboratively support the claim, underlying the potential of this material for the industrial usage of the removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene at room temperature through the cost-and energy-efficient adsorption separation process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 785, "Times Cited, All Databases": 834, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7328, "DOI": "10.1038/ncomms8328", "DOI Link": "http://dx.doi.org/10.1038/ncomms8328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357172100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, Q; Bai, GD; Jing, HB; Yang, C; Li, LL; Cui, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Qian; Bai, Guo Dong; Jing, Hong Bo; Yang, Cheng; Li, Lianlin; Cui, Tie Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smart metasurface with self-adaptively reprogrammable functions", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intelligence at either the material or metamaterial level is a goal that researchers have been pursuing. From passive to active, metasurfaces have been developed to be programmable to dynamically and arbitrarily manipulate electromagnetic (EM) wavefields. However, the programmable metasurfaces require manual control to switch among different functionalities. Here, we put forth a smart metasurface that has self-adaptively reprogrammable functionalities without human participation. The smart metasurface is capable of sensing ambient environments by integrating an additional sensor(s) and can adaptively adjust its EM operational functionality through an unmanned sensing feedback system. As an illustrative example, we experimentally develop a motion-sensitive smart metasurface integrated with a three-axis gyroscope, which can adjust self-adaptively the EM radiation beams via different rotations of the metasurface. We develop an online feedback algorithm as the control software to make the smart metasurface achieve single-beam and multibeam steering and other dynamic reactions adaptively. The proposed metasurface is extendable to other physical sensors to detect the humidity, temperature, illuminating light, and so on. Our strategy will open up a new avenue for future unmanned devices that are consistent with the ambient environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 98, "DOI": "10.1038/s41377-019-0205-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0205-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494270900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, HB; Zheng, GY; Hsu, PC; Kong, DS; Cha, JJ; Li, WY; Seh, ZW; McDowell, MT; Yan, K; Liang, Z; Narasimhan, VK; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Hongbin; Zheng, Guangyuan; Hsu, Po-Chun; Kong, Desheng; Cha, Judy J.; Li, Weiyang; Seh, Zhi Wei; McDowell, Matthew T.; Yan, Kai; Liang, Zheng; Narasimhan, Vijay Kris; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving lithium-sulphur batteries through spatial control of sulphur species deposition on a hybrid electrode surface", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulphur batteries are attractive owing to their high theoretical energy density and reasonable kinetics. Despite the success of trapping soluble polysulphides in a matrix with high surface area, spatial control of solid-state sulphur and lithium sulphide species deposition as a critical aspect has not been demonstrated. Herein, we show a clear visual evidence that these solid species deposit preferentially onto tin-doped indium oxide instead of carbon during electrochemical charge/discharge of soluble polysuphides. To incorporate this concept of spatial control into more practical battery electrodes, we further prepare carbon nullofibers with tin-doped indium oxide nulloparticles decorating the surface as hybrid three-dimensional electrodes to maximize the number of deposition sites. With 12.5 mu l of 5 M Li2S8 as the catholyte and a rate of C/5, we can reach the theoretical limit of Li2S8 capacity similar to 1,470 mAhg(-1) (sulphur weight) under the loading of hybrid electrode only at 4.3 mg cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3943, "DOI": "10.1038/ncomms4943", "DOI Link": "http://dx.doi.org/10.1038/ncomms4943", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337505600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, S; Song, JJ; Xi, SB; Du, YH; Wang, J; Huang, ZF; Xu, ZCJ; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Shuo; Song, Jiajia; Xi, Shibo; Du, Yonghua; Wang, Jiong; Huang, Zhen-Feng; Xu, Zhichuan J.; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Electrochemical CO2 Reduction on Metal-Organic Frameworks via Ligand Doping", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction relies on the availability of highly efficient and selective catalysts Herein, we report a general strategy to boost the activity of metal-organic frameworks (MOFs) towards CO2 reduction via ligand doping. A strong electron-donating molecule of 1,10-phenullthroline was doped into Zn-based MOFs of zeolitic imidazolate framework-8 (ZIF-8) as CO2 reduction electrocatalyst. Experimental and theoretical evidences reveal that the electron-donating nature of phenullthroline enables a charge transfer, which induces adjacent active sites at the sp(2) C atoms in the imidazole ligand possessing more electrons, and facilitates the generation of *COOH, hence leading to improved activity and Faradaic efficiency towards CO production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2019, "Volume": 58, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4041, "End Page": 4045, "Article Number": null, "DOI": "10.1002/anie.201814711", "DOI Link": "http://dx.doi.org/10.1002/anie.201814711", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462680700067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, JC; Li, L; Wang, DP; Zhang, MH; Mo, SR; Wang, X; Zeng, KY; Li, CH; Jiang, Q; You, XZ; Zuo, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Jian-Cheng; Li, Lan; Wang, Da-Peng; Zhang, Min-Hao; Mo, Sheng-Ran; Wang, Xue; Zeng, Ke-Yu; Li, Cheng-Hui; Jiang, Qing; You, Xiao-Zeng; Zuo, Jing-Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A rigid and healable polymer cross-linked by weak but abundant Zn(II)-carboxylate interactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving a desirable combination of solid-like properties and fast self-healing is a great challenge due to slow diffusion dynamics. In this work, we describe a design concept that utilizes weak but abundant coordination bonds to achieve this objective. The designed PDMS polymer, crosslinked by abundant Zn(II)-carboxylate interactions, is very strong and rigid at room temperature. As the coordination equilibrium is sensitive to temperature, the mechanical strength of this polymer rapidly and reversibly changes upon heating or cooling. The soft-rigid switching ability sigma, defined as G'(max) / G'(min), can reach 8000 when Delta T = 100 degrees C. Based on these features, this polymer not only exhibits fast thermal-healing properties, but is also advantageous for various applications such as in orthopedic immobilization, conductive composites/adhesives, and 3D printing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2725, "DOI": "10.1038/s41467-018-05285-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05285-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438494900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZB; Qiu, HY; Zhang, HL; Pang, XN; Zhou, LD; Liu, L; Ren, H; Wang, QH; Dong, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zhi-Bin; Qiu, Hao-Yang; Zhang, Han-Le; Pang, Xiao-Ning; Zhou, Li-Dan; Liu, Lin; Ren, Hui; Wang, Qiong-Hua; Dong, Jian-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A broadband achromatic metalens array for integral imaging in the visible", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integral imaging is a promising three-dimensional (3D) imaging technique that captures and reconstructs light field information. Microlens arrays are usually used for the reconstruction process to display 3D scenes to the viewer. However, the inherent chromatic aberration of the microlens array reduces the viewing quality, and thus, broadband achromatic imaging remains a challenge for integral imaging. Here, we realize a silicon nitride metalens array in the visible region that can be used to reconstruct 3D optical scenes in the achromatic integral imaging for white light. The metalens array contains 60 x 60 polarization-insensitive metalenses with nearly diffraction-limited focusing. The nulloposts in each high-efficiency (measured as 47% on average) metalens are delicately designed with zero effective material dispersion and an effective achromatic refractive index distribution from 430 to 780 nm. In addition, such an achromatic metalens array is composed of only a single silicon nitride layer with an ultrathin thickness of 400 nm, making the array suitable for on-chip hybrid-CMOS integration and the parallel manipulation of optoelectronic information. We expect these findings to provide possibilities for full-color and aberration-free integral imaging, and we envision that the proposed approach may be potentially applicable in the fields of high-power microlithography, high-precision wavefront sensors, virtual/augmented reality and 3D imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 67, "DOI": "10.1038/s41377-019-0178-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0178-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477570200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Siahrostami, S; Akey, AJ; Li, YB; Lu, ZY; Lattimer, J; Hu, YF; Stokes, C; Gangishetty, M; Chen, GX; Zhou, YW; Hill, W; Cai, WB; Bell, D; Chan, KR; Norskov, JK; Cui, Y; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kun; Siahrostami, Samira; Akey, Austin J.; Li, Yanbin; Lu, Zhiyi; Lattimer, Judith; Hu, Yongfeng; Stokes, Chris; Gangishetty, Mahesh; Chen, Guangxu; Zhou, Yawei; Hill, Winfield; Cai, Wen-Bin; Bell, David; Chan, Karen; Norskov, Jens K.; Cui, Yi; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition-Metal Single Atoms in a Graphene Shell as Active Centers for Highly Efficient Artificial Photosynthesis", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Utilizing solar energy to fix CO2 with water into chemical fuels and oxygen, a mimic process of photosynthesis in nature, is becoming increasingly important but still challenged by low selectivity and activity, especially in CO2 electrocatalytic reduction. Here, we report transition-metal atoms coordinated in a graphene shell as active centers for aqueous CO2 reduction to CO with high faradic efficiencies over 90% under significant currents up to similar to 60 mA/mg. We employed three-dimensional atom probe tomography to directly identify the single Ni atomic sites in graphene vacancies. Theoretical simulations suggest that compared with metallic Ni, the Ni atomic sites present different electronic structures that facilitate CO2-to-CO conversion and suppress the competing hydrogen evolution reaction dramatically. Coupled with Li+-tuned Co3O4 oxygen evolution catalyst and powered by a triple-junction solar cell, our artificial photosynthesis system achieves a peak solar-to-CO efficiency of 12.7% by using earth-abundant transition-metal electrocatalysts in a pH-equal system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 950, "End Page": 960, "Article Number": null, "DOI": "10.1016/j.chempr.2017.09.014", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.09.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418335800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gopinadhan, K; Hu, S; Esfandiar, A; Lozada-Hidalgo, M; Wang, FC; Yang, Q; Tyurnina, AV; Keerthi, A; Radha, B; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gopinadhan, K.; Hu, S.; Esfandiar, A.; Lozada-Hidalgo, M.; Wang, F. C.; Yang, Q.; Tyurnina, A. V.; Keerthi, A.; Radha, B.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Complete steric exclusion of ions and proton transport through confined monolayer water", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It has long been an aspirational goal to create artificial structures that allow fast permeation of water but reject even the smallest hydrated ions, replicating the feat achieved by nature in protein channels (e.g., aquaporins). Despite recent progress in creating nulloscale pores and capillaries, these structures still remain distinctly larger than protein channels. We report capillaries made by effectively extracting one atomic plane from bulk crystals, which leaves a two-dimensional slit of a few angstroms in height. Water moves through these capillaries with little resistance, whereas no permeation could be detected even for such small ions as Na+ and Cl-. Only protons (H+) can diffuse through monolayer water inside the capillaries. These observations improve our understanding of molecular transport at the atomic scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2019, "Volume": 363, "Issue": 6423, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 145, "End Page": 147, "Article Number": null, "DOI": "10.1126/science.aau6771", "DOI Link": "http://dx.doi.org/10.1126/science.aau6771", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455320600042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Yue, H; Zhang, YY; Gao, XY; Li, XY; Wang, LC; Cao, YF; Hou, M; An, HX; Zhang, L; Li, S; Ma, JY; Lin, H; Fu, YA; Gu, HK; Lou, WY; Wei, W; Zare, RN; Ge, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaoling; Yue, Hua; Zhang, Yuanyu; Gao, Xiaoyong; Li, Xiaoyang; Wang, Licheng; Cao, Yufei; Hou, Miao; An, Haixia; Zhang, Lin; Li, Sai; Ma, Jingyuan; Lin, He; Fu, Yanull; Gu, Hongkai; Lou, Wenyong; Wei, Wei; Zare, Richard N.; Ge, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Packaging and delivering enzymes by amorphous metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymatic catalysis in living cells enables the in-situ detection of cellular metabolites in single cells, which could contribute to early diagnosis of diseases. In this study, enzyme is packaged in amorphous metal-organic frameworks (MOFs) via a one-pot co-precipitation process under ambient conditions, exhibiting 5-20 times higher apparent activity than when the enzyme is encapsulated in corresponding crystalline MOFs. Molecular simulation and cryo-electron tomography (Cryo-ET) combined with other techniques demonstrate that the mesopores generated in this disordered and fuzzy structure endow the packaged enzyme with high enzyme activity. The highly active glucose oxidase delivered by the amorphous MOF nulloparticles allows the noninvasive and facile measurement of glucose in single living cells, which can be used to distinguish between cancerous and normal cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5165, "DOI": "10.1038/s41467-019-13153-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13153-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496409800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fumagalli, L; Esfandiar, A; Fabregas, R; Hu, S; Ares, P; Janardanull, A; Yang, Q; Radha, B; Taniguchi, T; Watanabe, K; Gomila, G; Novoselov, KS; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fumagalli, L.; Esfandiar, A.; Fabregas, R.; Hu, S.; Ares, P.; Janardanull, A.; Yang, Q.; Radha, B.; Taniguchi, T.; Watanabe, K.; Gomila, G.; Novoselov, K. S.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalously low dielectric constant of confined water", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The dielectric constant epsilon of interfacial water has been predicted to be smaller than that of bulk water (epsilon approximate to 80) because the rotational freedom of water dipoles is expected to decrease near surfaces, yet experimental evidence is lacking. We report local capacitance measurements for water confined between two atomically flat walls separated by various distances down to 1 nullometer. Our experiments reveal the presence of an interfacial layer with vanishingly small polarization such that its out-of-plane e is only similar to 2. The electrically dead layer is found to be two to three molecules thick. These results provide much-needed feedback for theories describing water-mediated surface interactions and the behavior of interfacial water, and show a way to investigate the dielectric properties of other fluids and solids under extreme confinement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 758, "Times Cited, All Databases": 812, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2018, "Volume": 360, "Issue": 6395, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1339, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aat4191", "DOI Link": "http://dx.doi.org/10.1126/science.aat4191", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436040600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahmood, J; Lee, EK; Jung, M; Shin, D; Jeon, IY; Jung, SM; Choi, HJ; Seo, JM; Bae, SY; Sohn, SD; Park, N; Oh, JH; Shin, HJ; Baek, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahmood, Javeed; Lee, Eun Kwang; Jung, Minbok; Shin, Dongbin; Jeon, In-Yup; Jung, Sun-Min; Choi, Hyun-Jung; Seo, Jeong-Min; Bae, Seo-Yoon; Sohn, So-Dam; Park, Noejung; Oh, Joon Hak; Shin, Hyung-Joon; Baek, Jong-Beom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogenated holey two-dimensional structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent graphene research has triggered enormous interest in new two-dimensional ordered crystals constructed by the inclusion of elements other than carbon for bandgap opening. The design of new multifunctional two-dimensional materials with proper bandgap has become an important challenge. Here we report a layered two-dimensional network structure that possesses evenly distributed holes and nitrogen atoms and a C2N stoichiometry in its basal plane. The two-dimensional structure can be efficiently synthesized via a simple wet-chemical reaction and confirmed with various characterization techniques, including scanning tunnelling microscopy. Furthermore, a field-effect transistor device fabricated using the material exhibits an on/off ratio of 10(7), with calculated and experimental bandgaps of approximately 1.70 and 1.96 eV, respectively. In view of the simplicity of the production method and the advantages of the solution processability, the C2N-h2D crystal has potential for use in practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 969, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6486, "DOI": "10.1038/ncomms7486", "DOI Link": "http://dx.doi.org/10.1038/ncomms7486", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352635600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, ZY; Wang, HT; Kong, DS; Yan, K; Hsu, PC; Zheng, GY; Yao, HB; Liang, Z; Sun, XM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Zhiyi; Wang, Haotian; Kong, Desheng; Yan, Kai; Hsu, Po-Chun; Zheng, Guangyuan; Yao, Hongbin; Liang, Zheng; Sun, Xiaoming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical tuning of layered lithium transition metal oxides for improvement of oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for low-cost and efficient catalysts for the oxygen evolution reaction has been actively pursued owing to its importance in clean energy generation and storage. While developing new catalysts is important, tuning the electronic structure of existing catalysts over a wide electrochemical potential range can also offer a new direction. Here we demonstrate a method for electrochemical lithium tuning of catalytic materials in organic electrolyte for subsequent enhancement of the catalytic activity in aqueous solution. By continuously extracting lithium ions out of LiCoO2, a popular cathode material in lithium ion batteries, to Li0.5CoO2 in organic electrolyte, the catalytic activity is significantly improved. This enhancement is ascribed to the unique electronic structure after the delithiation process. The general efficacy of this methodology is demonstrated in several mixed metal oxides with similar improvements. The electrochemically delithiated LiCo0.33Ni0.33Fe0.33O2 exhibits a notable performance, better than the benchmark iridium/carbon catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4345, "DOI": "10.1038/ncomms5345", "DOI Link": "http://dx.doi.org/10.1038/ncomms5345", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340615500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, H; Liu, JF; Xu, M; Ji, J; Dai, QL; You, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Hui; Liu, Junfu; Xu, Mei; Ji, Jie; Dai, Qingli; You, Zhanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discussion on molecular dynamics (MD) simulations of the asphalt materials", "Source Title": "ADVANCES IN COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of asphalt materials in pavement engineering has been increasingly widespread and sophisticated over the past several decades. Variations in the properties of asphalt binder during mixing, transportation, and paving can affect the performance of asphalt pavement. However, the asphalt material is a non homogeneous and complex organic substance, consisting of various molecules with widely various molecular weights, elemental compositions, and structures. This complexity leads to difficulties for researchers to clearly and immediately understand the properties of asphalt materials and their variations. The multi-scale research approach combines macroscopic experimental data and microscopic simulation results from a practical engineering perspective. It helps to improve the understanding of asphalt materials. The molecular dynamics (MD) simulation proposes a corresponding molecular model of asphalt material based on experimental data, and the simulation algorithm is able to derive properties similar to those of real asphalt. This paper provides a comprehensive review of the current studies on MD simulation of asphalt materials, including modeling, properties, and multi-scale analysis. As a key part of the computational simulation, this paper discusses the typical asphalt binder and asphalt-aggregate interface models constructed by different groups, and also presents their differences from real samples and their feasibility based on fundamental properties. After the introduction of molecular models, the extensive work made by researchers based on molecular models is categorically reviewed and discussed. The strengths and weaknesses of MD simulation methods in the study of asphalt materials are also summarized in order to provide the reader with a more comprehensive understanding of the relevant contents and to guide subsequent research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 299, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102565, "DOI": "10.1016/j.cis.2021.102565", "DOI Link": "http://dx.doi.org/10.1016/j.cis.2021.102565", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779511700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XL; De Luna, P; de Arquer, FPG; Zhang, B; Becknell, N; Ross, MB; Li, YF; Banis, MN; Li, YZ; Liu, M; Voznyy, O; Dinh, CT; Zhuang, TT; Stadler, P; Cui, Y; Du, XW; Yang, PD; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xueli; De Luna, Phil; de Arquer, F. Pelayo Garcia; Zhang, Bo; Becknell, Nigel; Ross, Michael B.; Li, Yifan; Banis, Mohammad Norouzi; Li, Yuzhang; Liu, Min; Voznyy, Oleksandr; Cao Thang Dinh; Zhuang, Taotao; Stadler, Philipp; Cui, Yi; Du, Xiwen; Yang, Peidong; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of carbon dioxide (CO2RR) to formate provides an avenue to the synthesis of value-added carbon-based fuels and feedstocks powered using renewable electricity. Here, we hypothesized that the presence of sulfur atoms in the catalyst surface could promote undercoordinated sites, and thereby improve the electrochemical reduction of CO2 to formate. We explored, using density functional theory, how the incorporation of sulfur into tin may favor formate generation. We used atomic layer deposition of SnSx followed by a reduction process to synthesize sulfur-modulated tin (Sn(S)) catalysts. X-ray absorption near-edge structure (XANES) studies reveal higher oxidation states in Sn(S) compared with that of tin in Sn nulloparticles. Sn(S)/Au accelerates CO2RR at geometric current densities of 55 mA cm(-2) at -0.75 V versus reversible hydrogen electrode with a Faradaic efficiency of 93%. Furthermore, Sn(S) catalysts show excellent stability without deactivation (<2% productivity change) following more than 40 hours of operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2017, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 794, "End Page": 805, "Article Number": null, "DOI": "10.1016/j.joule.2017.09.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.09.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425302500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Wen, XR; Jia, YM; Huang, M; Wang, FF; Zhang, XH; Bai, YY; Yuan, GL; Wang, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yang; Wen, Xinrong; Jia, Yanmin; Huang, Ming; Wang, Feifei; Zhang, Xuehui; Bai, Yunyang; Yuan, Guoliang; Wang, Yaojin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezo-catalysis for nondestructive tooth whitening", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increasing demand for a whiter smile has resulted in an increased popularity for tooth whitening procedures. The most classic hydrogen peroxide-based whitening agents are effective, but can lead to enamel demineralization, gingival irritation, or cytotoxicity. Furthermore, these techniques are excessively time-consuming. Here, we report a non-destructive, harmless and convenient tooth whitening strategy based on a piezo-catalysis effect realized by replacement of abrasives traditionally used in toothpaste with piezoelectric particles. Degradation of organic dyes via piezo-catalysis of BaTiO3 (BTO) nulloparticles was performed under ultrasonic vibration to simulate daily tooth brushing. Teeth stained with black tea, blueberry juice, wine or a combination thereof can be notably whitened by the poled BTO turbid liquid after vibration for 3 h. A similar treatment using unpoled or cubic BTO show negligible tooth whitening effect. Furthermore, the BTO nulloparticle-based piezo-catalysis tooth whitening procedure exhibits remarkably less damage to both enamel and biological cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1328, "DOI": "10.1038/s41467-020-15015-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15015-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563525700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, HQ; Cheng, Y; Zhang, Z; Zhang, BS; Pei, CC; Fan, FY; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Huanqin; Cheng, Yan; Zhang, Zhu; Zhang, Baoshan; Pei, Chunchuan; Fan, Feiyue; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-derived graphene-like porous carbon nullosheets towards ultralight microwave absorption and excellent thermal infrared properties", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for ultralight microwave absorber with good heat-insulating property is highly desirable to fulfill the technical requirement of modern society. Herein, the two-dimension (2D) graphene-like porous carbon nullosheets (GPCN) derived from the waste pomelo peel were developed. The preparation is performed by a facile hydrothermal process with synergistic usage of HAc and H2O2. Interestingly, the thickness and porosity of GPCN can be readily regulated by adjusting addition amount of the reagents. The related synthetic mechanism is investigated in depth. Compared with traditional graphene, the fabrication strategy of GPCN possesses many advantages, such as low cost, high yield and ease of production. The results show that GPCN presents superior thermal insulation and microwave absorption properties. The heat-insulating property is comparable to commercial products, e.g. polyurethanes (PU), nickel foam (NF), carbon foam (CF). The strong microwave absorption intensity of -56.4 dB and bandwidth of 6.4 GHz is achieved under ultralow filling ratio of 4 wt%. Moreover, the density of assembled 3D macroscopically product is merely 0.01 g/cm(-3). The excellent performance should be attributed to the unique 2D morphology and high porosity of GPCN. Our work paves a new way for developing porous carbon nullosheet from sustainable biomass as heat-insulating ultralight microwave absorber. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 173, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 501, "End Page": 511, "Article Number": null, "DOI": "10.1016/j.carbon.2020.11.035", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2020.11.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625347900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avci, C; Ariñez-Soriano, J; Carné-Sánchez, A; Guillerm, V; Carbonell, C; Imaz, I; Maspoch, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avci, Civan; Arinez-Soriano, Javier; Carne-Sanchez, Arnau; Guillerm, Vincent; Carbonell, Carlos; Imaz, Inhar; Maspoch, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Post-Synthetic Anisotropic Wet-Chemical Etching of Colloidal Sodalite ZIF Crystals", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling the shape of metal-organic framework (MOF) crystals is important for understanding their crystallization and useful for myriad applications. However, despite the many advances in shaping of inorganic nulloparticles, post-synthetic shape control of MOFs and, in general, molecular crystals remains embryonic. Herein, we report using a simple wet-chemistry process at room temperature to control the anisotropic etching of colloidal ZIF-8 and ZIF-67 crystals. Our work enables uniform reshaping of these porous materials into unprecedented morphologies, including cubic and tetrahedral crystals, and even hollow boxes, by an acid-base reaction and subsequent sequestration of leached metal ions. Etching tests on these ZIFs reveal that etching occurs preferentially in the crystallographic directions richer in metal-ligand bonds; that, along these directions, the etching rate tends to be faster on the crystal surfaces of higher dimensionality; and that the etching can be modulated by adjusting the pH of the etchant solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2015, "Volume": 54, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14417, "End Page": 14421, "Article Number": null, "DOI": "10.1002/anie.201507588", "DOI Link": "http://dx.doi.org/10.1002/anie.201507588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367724000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuang, X; Wu, JT; Chen, KJ; Zhao, Z; Ding, Z; Hu, FJY; Fang, DN; Qi, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuang, Xiao; Wu, Jiangtao; Chen, Kaijuan; Zhao, Zeang; Ding, Zhen; Hu, Fengjingyang; Fang, Daining; Qi, H. Jerry", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grayscale digital light processing 3D printing for highly functionally graded materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) printing or additive manufacturing, as a revolutionary technology for future advanced manufacturing, usually prints parts with poor control of complex gradients for functional applications. We present a single-vat grayscale digital light processing (g-DLP) 3D printing method using grayscale light patterns and a two-stage curing ink to obtain functionally graded materials with the mechanical gradient up to three orders of magnitude and high resolution. To demonstrate the g-DLP, we show the direct fabrication of complex 2D/3D lattices with controlled buckling and deformation sequence, negative Poisson's ratio metamaterial, presurgical models with stiffness variations, composites for 4D printing, and anti-counterfeiting 3D printing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav5790", "DOI": "10.1126/sciadv.aav5790", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav5790", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470125000057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paul, S; Zhu, YQ; Romain, C; Brooks, R; Saini, PK; Williams, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paul, Shyeni; Zhu, Yunqing; Romain, Charles; Brooks, Rachel; Saini, Prabhjot K.; Williams, Charlotte K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlled routes to prepare polyesters and polycarbonates are of interest due to the widespread application of these materials and the opportunities provided to prepare new copolymers. Furthermore, ring-opening copolymerization may enable new poly(ester-carbonate) materials to be prepared which are inaccessible using alternative polymerizations. This review highlights recent advances in the ring-opening copolymerization catalysis, using epoxides coupled with anhydrides or CO2, to produce polyesters and polycarbonates. In particular, the structures and performances of various homogeneous catalysts are presented for the epoxide-anhydride copolymerization. The properties of the resultant polyesters and polycarbonates are presented and future opportunities highlighted for developments of both the materials and catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 51, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6459, "End Page": 6479, "Article Number": null, "DOI": "10.1039/c4cc10113h", "DOI Link": "http://dx.doi.org/10.1039/c4cc10113h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352269000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CF; Liu, SH; Shi, CG; Liang, GH; Lu, ZT; Fu, RW; Wu, DC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chuanfa; Liu, Shaohong; Shi, Chenguang; Liang, Ganghao; Lu, Zhitao; Fu, Ruowen; Wu, Dingcai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries have been considerably limited by the problems of uncontrolled dendritic lithium formation and the highly reactive nature of lithium with electrolytes. Herein, we have developed functional porous bilayer composite separators by simply blade-coating polyacrylamide-grafted graphene oxide molecular brushes onto commercial polypropylene separators. Our functional porous bilayer composite separators integrate the lithiophilic feature of hairy polyacrylamide chains and fast electrolyte diffusion pathways with the excellent mechanical strength of graphene oxide nullosheets and thus enable molecular-level homogeneous and fast lithium ionic flux on the surfaces of electrodes. As a result, dendrite-free uniform lithium deposition with a high Coulombic efficiency (98%) and ultralong-term reversible lithium plating/stripping (over 2600 h) at a high current density (2 mA cm(-2)) are achieved for lithium metal anodes. Remarkably, lithium metal anodes with an unprecedented stability of more than 1900 h cycling at an ultrahigh current density of 20 mA cm(-2) are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1363, "DOI": "10.1038/s41467-019-09211-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09211-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462142200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CL; Zhao, Y; Ma, TS; An, YD; He, R; Zhu, JW; Chen, C; Ren, SQ; Fu, F; Zhao, DW; Li, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Changlei; Zhao, Yue; Ma, Tianshu; An, Yidan; He, Rui; Zhu, Jingwei; Chen, Cong; Ren, Shengqiang; Fu, Fan; Zhao, Dewei; Li, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A universal close-space annealing strategy towards high-quality perovskite absorbers enabling efficient all-perovskite tandem solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The broad bandgap tunability of organic-inorganic metal halide perovskites enables the fabrication of multi-junction all-perovskite tandem solar cells with ultra-high power conversion efficiencies (PCEs). Controllable crystallization plays a crucial role in the formation of high-quality perovskites. Here we report a universal close-space annealing strategy that increases grain size, enhances crystallinity and prolongs carrier lifetimes in low-bandgap (low-E-g) and wide-bandgap (wide-E-g) perovskite films. By placing the intermediate-phase perovskite films with their faces towards solvent-permeable covers during the annealing process, high-quality perovskite absorber layers are obtained with a slowed solvent releasing process, enabling fabrication of efficient single-junction perovskite solar cells (PVSCs) and all-perovskite tandem solar cells. As a result, the best PCEs of 21.51% and 18.58% for single-junction low-E-g and wide-E-g PVSCs are achieved and thus ensure the fabrication of 25.15% efficiency 4-terminal and 25.05% efficiency 2-terminal all-perovskite tandem solar cells. Controlling the crystallization of perovskites is not trivial. Here Wang et al. develop a close-space annealing to improve the structural and optoelectronic quality of perovskite films with different chemical compositions, leading to over 25% efficiency in all-perovskite tandem solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 744, "End Page": 753, "Article Number": null, "DOI": "10.1038/s41560-022-01076-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01076-9", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828440800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, WH; Ong, SJH; Shen, YH; Guo, WY; Fang, YT; Ji, GB; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Weihua; Ong, Samuel Jun Hoong; Shen, Yuhong; Guo, Wenyi; Fang, Yiting; Ji, Guangbin; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Lightweight, Elastic, and Thermally Insulating Stealth Foam With High Infrared-Radar Compatibility", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of infrared-radar compatible materials/devices is challenging because the requirements of material properties between infrared and radar stealth are contradictory. Herein, a composite of poly(3, 4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) coated melamine foam is designed to integrate the advantages of the dual materials and the created heterogeneous interface between them. The as-designed PEDOT:PSS@melamine composite shows excellent mechanical properties, outstanding thermal insulation, and improved thermal infrared stealth performance. The relevant superb radar stealth performance including the minimum reflection loss value of -57.57 dB, the optimum ultra-wide bandwidth of 10.52 GHz, and the simulation of radar cross section reduction value of 17.68 dB m(2), can be achieved. The optimal specific electromagnetic wave absorption performance can reach up as high as 3263.02 dB center dot cm(3) g(-1). The average electromagnetic interference shielding effectiveness value can be 30.80 dB. This study provides an approach for the design of high-performance stealth materials with infrared-radar compatibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 9, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202204165", "DOI Link": "http://dx.doi.org/10.1002/advs.202204165", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000871901900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, SA; Zou, LF; Qin, JS; Li, JL; Huang, L; Feng, LA; Wang, XA; Bosch, M; Alsalme, A; Cagin, T; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng; Li, Jialuo; Huang, Lan; Feng, Liang; Wang, Xuan; Bosch, Mathieu; Alsalme, Ali; Cagin, Tahir; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of hierarchically porous metal-organic frameworks through linker labilization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A major goal of metal-organic framework (MOF) research is the expansion of pore size and volume. Although many approaches have been attempted to increase the pore size of MOF materials, it is still a challenge to construct MOFs with precisely customized pore apertures for specific applications. Herein, we present a new method, namely linker labilization, to increase the MOF porosity and pore size, giving rise to hierarchical-pore architectures. Microporous MOFs with robust metal nodes and pro-labile linkers were initially synthesized. The mesopores were subsequently created as crystal defects through the splitting of a pro-labile-linker and the removal of the linker fragments by acid treatment. We demonstrate that linker labilization method can create controllable hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption process of guest molecules to improve the performances of MOFs in adsorption and catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15356, "DOI": "10.1038/ncomms15356", "DOI Link": "http://dx.doi.org/10.1038/ncomms15356", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401964100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XL; Xie, YH; Hao, MJ; Chen, ZS; Yang, H; Waterhouse, GIN; Ma, SQ; Wang, XK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaolu; Xie, Yinghui; Hao, Mengjie; Chen, Zhongshan; Yang, Hui; Waterhouse, Geoffrey I. N.; Ma, Shengqian; Wang, Xiangke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Electrocatalytic Uranium Extraction from Seawater over an Amidoxime-Functionalized In-N-C Catalyst", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater contains uranium at a concentration of approximate to 3.3 ppb, thus representing a rich and sustainable nuclear fuel source. Herein, an adsorption-electrocatalytic platform is developed for uranium extraction from seawater, comprising atomically dispersed indium anchored on hollow nitrogen-doped carbon capsules functionalized with flexible amidoxime moieties (In-N-x-C-R, where R denotes amidoxime groups). In-N-x-C-R exhibits excellent uranyl capture properties, enabling a uranium removal rate of 6.35 mg g(-1) in 24 h, representing one of the best uranium extractants reported to date. Importantly, In-N-x-C-R demonstrates exceptional selectivity for uranium extraction relative to vanadium in seawater (8.75 times more selective for the former). X-ray absorption spectroscopy (XAS) reveals that the amidoxime groups serve as uranyl chelating sites, thus allowing selective adsorption over other ions. XAS and in situ Raman results directly indicate that the absorbed uranyl can be electrocatalytically reduced to an unstable U(V) intermediate, then re-oxidizes to U(VI) in the form of insoluble Na2O(UO3 center dot H2O)(x) for collection, through reversible single electron transfer processes involving InNx sites. These results provide detailed mechanistic understanding of the uranium extraction process at a molecular level. This work provides a roadmap for the adsorption-electrocatalytic extraction of uranium from seawater, adding to the growing suite of technologies for harvesting valuable metals from the earth's oceans.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201735, "DOI": "10.1002/advs.202201735", "DOI Link": "http://dx.doi.org/10.1002/advs.202201735", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000812290400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CW; Zhang, YJ; Jia, YW; Li, BJ; Tang, WJ; Shang, CN; Mo, R; Li, P; Liu, SM; Zhang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Changwei; Zhang, Yanjun; Jia, Yuewen; Li, Bojun; Tang, Wenjing; Shang, Chuning; Mo, Rui; Li, Pei; Liu, Shaomin; Zhang, Sui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyamide membranes with nulloscale ordered structures for fast permeation and highly selective ion-ion separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fast permeation and effective solute-solute separation provide the opportunities for sustainable water treatment, but they are hindered by ineffective membranes. We present here the construction of a nullofiltration membrane with fast permeation, high rejection, and precise Cl-/SO42- separation by spatial and temporal control of interfacial polymerization via graphitic carbon nitride (g-C3N4). The g-C3N4 nullosheet binds preferentially with piperazine and tiles the water-hexane interface as revealed by molecular dynamics studies, thus lowering the diffusion rate of PIP by one order of magnitude and restricting its diffusion pathways towards the hexane phase. As a result, membranes with nulloscale ordered hollow structure are created. Transport mechanism across the structure is clarified using computational fluid dynamics simulation. Increased surface area, lower thickness, and a hollow ordered structure are identified as the key contributors to the water permeance of 105 L m(2)center dot h(-1)center dot bar(-1) with a Na2SO4 rejection of 99.4% and a Cl-/SO42- selectivity of 130, which is superior to state-of-the-art NF membranes. Our approach for tuning the membrane microstructure enables the development of ultra-permeability and excellent selectivity for ion-ion separation, water purification, desalination, and organics removal. Membranes with precise ion-ion separation are critical for sustainable water treatment. Here, authors demonstrated controlled construction of a nullofiltration membrane with fast permeation and high Cl-/SO42- selectivity by simultaneous spatial and temporal control of interfacial polymerization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1112, "DOI": "10.1038/s41467-023-36848-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36848-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942107800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huan, TN; Ranjbar, N; Rousse, G; Sougrati, M; Zitolo, A; Mougel, V; Jaouen, F; Fontecave, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huan, Tran Ngoc; Ranjbar, Nastaran; Rousse, Gwenaelle; Sougrati, Moulay; Zitolo, Andrea; Mougel, Victor; Jaouen, Frederic; Fontecave, Marc", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Reduction of CO2 Catalyzed by Fe-N-C Materials: A Structure-Selectivity Study", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selective electrochemical reduction of CO, into energy-dense organic compounds is a promising strategy for using CO, as a carbon source. Herein, we investigate a series of iron-based catalysts synthesized by pyrolysis of Fe-, N-, and C-containing precursors for the electroreduction of CO, to CO under aqueous conditions and demonstrate that the selectivity of these materials for CO2 reduction over proton reduction is governed by the ratio of isolated FeN4 sites vs Fe-based nulloparticles. This ratio can be synthetically tuned to generate electrocatalysts producing controlled CO/H-2 ratios. It notably allows preparing materials containing only FeN4 sites, which are able to selectively reduce CO, to CO in aqueous solution with Faradaic yields of over 90% and at low overpotential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1520, "End Page": 1525, "Article Number": null, "DOI": "10.1021/acscatal.6b03353", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b03353", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395726500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Liao, HB; Wang, JR; Chen, B; Sun, SN; Ong, SJH; Xi, SB; Diao, CZ; Du, YH; Wang, JO; Breese, MBH; Li, SZ; Zhang, H; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yuanmiao; Liao, Hanbin; Wang, Jiarui; Chen, Bo; Sun, Shengnull; Ong, Samuel Jun Hoong; Xi, Shibo; Diao, Caozheng; Du, Yonghua; Wang, Jia-Ou; Breese, Mark B. H.; Li, Shuzhou; Zhang, Hua; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalency competition dominates the water oxidation structure-activity relationship on spinel oxides", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spinel oxides have attracted growing interest over the years for catalysing the oxygen evolution reaction (OER) due to their efficiency and cost-effectiveness, but fundamental understanding of their structure-property relationships remains elusive. Here we demonstrate that the OER activity on spinel oxides is intrinsically dominated by the covalency competition between tetrahedral and octahedral sites. The competition fabricates an asymmetric M-T-O-M(O)backbone where the bond with weaker metal-oxygen covalency determines the exposure of cation sites and therefore the activity. Driven by this finding, a dataset with more than 300 spinel oxides is computed and used to train a machine-learning model for screening the covalency competition in spinel oxides, with a mean absolute error of 0.05 eV. [Mn](T)[Al0.5Mn1.5](O)O(4)is predicted to be a highly active OER catalyst and subsequent experimental results confirm its superior activity. This work sets mechanistic principles of spinel oxides for water oxidation, which may be extendable to other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 554, "End Page": 563, "Article Number": null, "DOI": "10.1038/s41929-020-0465-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0465-6", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540419200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahmood, N; Zhang, CZ; Yin, H; Hou, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahmood, Nasir; Zhang, Chenzhen; Yin, Han; Hou, Yanglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-based nullocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to their unique properties, together with their ease of synthesis and functionalization, graphene-based materials have been showing great potential in energy storage and conversion. These hybrid structures display excellent material characteristics, including high carrier mobility, faster recombination rate and long-time stability. In this review, after a short introduction to graphene and its derivatives, we summarize the recent advances in the synthesis and applications of graphene and its derivatives in the fields of energy storage (lithium ion, lithium-air, lithium-sulphur batteries and supercapacitors) and conversion (oxygen reduction reaction for fuel cells). This article further highlights the working principles and problems hindering the practical applications of graphene-based materials in lithium batteries, supercapacitors and fuel cells. Future research trends towards new methodologies to the design and the synthesis of graphene-based nullocomposite with unique architectures for electrochemical energy storage and conversion are also proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15, "End Page": 32, "Article Number": null, "DOI": "10.1039/c3ta13033a", "DOI Link": "http://dx.doi.org/10.1039/c3ta13033a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000327618600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YM; Yu, XY; Li, Z; Paik, U; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yu Ming; Yu, Xin Yao; Li, Zhen; Paik, Ungyu; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical MoS2 tubular structures internally wired by carbon nullotubes as a highly stable anode material for lithium-ion batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum disulfide (MoS2), a typical two-dimensional material, is a promising anode material for lithium-ion batteries because it has three times the theoretical capacity of graphite. The main challenges associated with MoS2 anodes are the structural degradation and the low rate capability caused by the low intrinsic electric conductivity and large strain upon cycling. Here, we design hierarchical MoS2 tubular structures internally wired by carbon nullotubes (CNTs) to tackle these problems. These porous MoS2 tubular structures are constructed from building blocks of ultrathin nullosheets, which are believed to benefit the electrochemical reactions. Benefiting from the unique structural and compositional characteristics, these CNT-wired MoS2 tubular structures deliver a very high specific capacity of similar to 1320 mAh g(-1) at a current density of 0.1 A g(-1), exceptional rate capability, and an ultralong cycle life of up to 1000 cycles. This work may inspire new ideas for constructing high-performance electrodes for electrochemical energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1600021", "DOI": "10.1126/sciadv.1600021", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1600021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381805300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, SH; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Sheng-Heng; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bifunctional Separator with a Light-Weight Carbon-Coating for Dynamically and Statically Stable Lithium-Sulfur Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfur is appealing as a high-capacity cathode for rechargeable lithium batteries as it offers a high theoretical capacity of 1672 mA h g(-1) and is abundant. However, the commercialization of Li-S batteries is hampered by fast capacity fade during both dynamic cell cycling and static cell resting. The poor electrochemical stability is due to polysulfide diffusion, leading to a short cycle life and severe self-discharge. Here, we present the design of a bifunctional separator with a light-weight carbon-coating that integrates the two necessary components already inside the cell: the conductive carbon and the separator. With no extra additives, this bifunctional carbon-coated separator allows the use of pure sulfur cathodes involving no complex composite synthesis process, provides a high initial discharge capacity of 1389 mA h g(-1) with excellent dynamic stability, and facilitates a high reversible capacity of 828 mA h g(-1) after 200 cycles. In addition, the static stability is evidenced by low self-discharge and excellent capacity retention after a 3 month rest period.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 507, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 24, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5299, "End Page": 5306, "Article Number": null, "DOI": "10.1002/adfm.201400845", "DOI Link": "http://dx.doi.org/10.1002/adfm.201400845", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341699200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, JW; Park, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jin-Wu; Park, Harold S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative poisson's ratio in single-layer black phosphorus", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Poisson's ratio is a fundamental mechanical property that relates the resulting lateral strain to applied axial strain. Although this value can theoretically be negative, it is positive for nearly all materials, though negative values have been observed in so-called auxetic structures. However, nearly all auxetic materials are bulk materials whose microstructure has been specifically engineered to generate a negative Poisson's ratio. Here we report using first-principles calculations the existence of a negative Poisson's ratio in a single-layer, two-dimensional material, black phosphorus. In contrast to engineered bulk auxetics, this behaviour is intrinsic for single-layer black phosphorus, and originates from its puckered structure, where the pucker can be regarded as a re-entrant structure that is comprised of two coupled orthogonal hinges. As a result of this atomic structure, a negative Poisson's ratio is observed in the out-of-plane direction under uniaxial deformation in the direction parallel to the pucker.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 656, "Times Cited, All Databases": 702, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4727, "DOI": "10.1038/ncomms5727", "DOI Link": "http://dx.doi.org/10.1038/ncomms5727", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341080100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Azeredo, HMC; Rosa, MF; Mattoso, LHC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Azeredo, Henriette M. C.; Rosa, Morsyleide F.; Mattoso, Luiz Henrique C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose in bio-based food packaging applications", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cellulose nullostructures have been widely studied as components of materials for a variety of applications including food packaging. They are usually incorporated as a reinforcement phase in nullocomposites (as cellulose nullocrystals or cellulose nullofibrils). In other cases, cellulose nullostructures have been used as matrices for films-bacterial cellulose (BC) deserving a special attention in this context, since it is produced as naturally nullostructured membranes, which may grow in a medium containing other biopolymers (producing bottom-up built bionullocomposites), be impregnated with other components, or be disintegrated into nullofibribils or even nullocrystals. This review summarizes findings and prospective applications of nullocellulose for bio-based materials to be used in food packaging (including active packaging). (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 350, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 97, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 664, "End Page": 671, "Article Number": null, "DOI": "10.1016/j.indcrop.2016.03.013", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2016.03.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394064600081", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, DH; Liao, Y; Song, YC; Wang, SL; Wan, HY; Zeng, YH; Yin, T; Yang, WH; He, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Dehai; Liao, Yue; Song, Yingchao; Wang, Shilong; Wan, Haoyu; Zeng, Yanhong; Yin, Tao; Yang, Wenhao; He, Zhizhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Super-Stretchable Liquid Metal Foamed Elastomer for Tunable Control of Electromagnetic Waves and Thermal Transport", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is remarkably desirable and challenging to design a stretchable conductive material with tunable electromagnetic-interference (EMI) shielding and heat transfer for applications in flexible electronics. However, the existing materials sustained a severe attenuation of performances when largely stretched. Here, a super-stretchable (800% strain) liquid metal foamed elastomer composite (LMF-EC) is reported, achieving super-high electrical (approximate to 10(4) S cm(-1)) and thermal (17.6 W mK(-1)) conductivities under a large strain of 400%, which also exhibits unexpected stretching-enhanced EMI shielding effectiveness of 85 dB due to the conductive network elongation and reorientation. By varying the liquid and solid states of LMF, the stretching can enable a multifunctional reversible switch that simultaneously regulates the thermal, electrical, and electromagnetic wave transport. Novel flexible temperature control and a thermoelectric system based on LMF-EC is furthermore developed. This work is a significant step toward the development of smart electromagnetic and thermal regulator for stretchable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000177, "DOI": "10.1002/advs.202000177", "DOI Link": "http://dx.doi.org/10.1002/advs.202000177", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529655400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Q; Liang, C; Sun, XQ; Chen, JW; Yang, ZJ; Zhao, H; Feng, LZ; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Qian; Liang, Chao; Sun, Xiaoqi; Chen, Jiawen; Yang, Zhijuan; Zhao, He; Feng, Liangzhu; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "H2O2-responsive liposomal nulloprobe for photoacoustic inflammation imaging and tumor theranostics via in vivo chromogenic assay", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Abnormal H2O2 levels are closely related to many diseases, including inflammation and cancers. Herein, we simultaneously load HRP and its substrate, 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), into liposomal nulloparticles, obtaining a Lipo@ HRP& ABTS optical nulloprobe for in vivo H2O2-responsive chromogenic assay with great specificity and sensitivity. In the presence of H2O2, colorless ABTS would be converted by HRP into the oxidized form with strong near-infrared (NIR) absorbance, enabling photoacoustic detection of H2O2 down to submicromolar concentrations. Using Lipo@ HRP& ABTS as an H2O2-responsive nulloprobe, we could accurately detect the inflammation processes induced by LPS or bacterial infection in which H2O2 is generated. Meanwhile, upon systemic administration of this nulloprobe we realize in vivo photoacoustic imaging of small s. c. tumors (similar to 2 mm in size) as well as orthotopic brain gliomas, by detecting H2O2 produced by tumor cells. Interestingly, local injection of Lipo@ HRP& ABTS further enables differentiation of metastatic lymph nodes from those nonmetastatic ones, based on their difference in H2O2 contents. Moreover, using the H2O2-dependent strong NIR absorbance of Lipo@ HRP& ABTS, tumorspecific photothermal therapy is also achieved. This work thus develops a sensitive H2O2-responsive optical nulloprobe useful not only for in vivo detection of inflammation but also for tumor-specific theranostic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 459, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2017, "Volume": 114, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5343, "End Page": 5348, "Article Number": null, "DOI": "10.1073/pnas.1701976114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1701976114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401797800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koshelev, K; Kruk, S; Melik-Gaykazyan, E; Choi, JH; Bogdanov, A; Park, HG; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koshelev, Kirill; Kruk, Sergey; Melik-Gaykazyan, Elizaveta; Choi, Jae-Hyuck; Bogdanov, Andrey; Park, Hong-Gyu; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subwavelength dielectric resonators for nonlinear nullophotonics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Subwavelength optical resonators made of high-index dielectric materials provide efficient ways to manipulate light at the nulloscale through mode interferences and enhancement of both electric and magnetic fields. Such Mie-resonullt dielectric structures have low absorption, and their functionalities are limited predominulltly by radiative losses. We implement a new physical mechanism for suppressing radiative losses of individual nulloscale resonators to engineer special modes with high quality factors. optical bound states in the continuum (BICs). We demonstrate that an individual subwavelength dielectric resonator hosting a BIC mode can boost nonlinear effects increasing second-harmonic generation efficiency. Our work suggests a route to use subwavelength high-index dielectric resonators for a strong enhancement of light-matter interactions with applications to nonlinear optics, nulloscale lasers, quantum photonics, and sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 744, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2020, "Volume": 367, "Issue": 6475, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 288, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz3985", "DOI Link": "http://dx.doi.org/10.1126/science.aaz3985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509802700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PB; Wang, TS; Jiang, HN; Wan, JY; Wei, Y; Wang, L; Liu, W; Chen, Q; Yang, WW; Cui, Y; Gong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Pengbo; Wang, Tianshuai; Jiang, Huaning; Wan, Jiayu; Wei, Yi; Wang, Lei; Liu, Wei; Chen, Qian; Yang, Weiwei; Cui, Yi; Gong, Yongji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Artificial Solid-Electrolyte Interphase for Lithium Metal Anodes Enabled by Insulator-Metal-Insulator Layered Heterostructures", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite considerable efforts to prevent lithium (Li) dendrite growth, stable cycling of Li metal anodes with various structures remains extremely difficult due to the direct contact of the liquid electrolyte with Li. Rational design of solid-electrolyte interphase (SEI) for 3D electrodes is a promising but still challenging strategy for preventing Li dendrite growth and avoiding lithium-electrolyte side reactions in Li-metal batteries. Here, a 3D architecture is constructed with g-C3N4/graphene/g-C3N4 insulator-metal-insulator sandwiched nullosheets to guide uniform Li plating/stripping in the van der Waals gap between the graphene and the g-C3N4, and the function of which can be regarded as a 3D artificial SEI. Li deposition on the surface of g-C3N4 is suppressed due to its insulating nature. However, its uniform lithiophilic sites and nullopore channels enable homogeneous lithium plating between the graphene and the g-C3N4, prohibiting the direct contact of the electrolyte with the Li metal. The use of the g-C3N4-layer-modified 3D anode enables long-term Li deposition with a high Coulombic efficiency and stable cycling of full cells under high cathode loading, limited Li excess, and lean electrolyte conditions. The concept of a 3D artificial SEI will shed light on developing safe and stable Li-metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 33, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2006247, "DOI": "10.1002/adma.202006247", "DOI Link": "http://dx.doi.org/10.1002/adma.202006247", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621515400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Q; Wu, H; Zheng, XR; Chen, YA; Rogach, AL; Han, XP; Deng, YD; Hu, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Qi; Wu, Han; Zheng, Xuerong; Chen, Yanull; Rogach, Andrey L.; Han, Xiaopeng; Deng, Yida; Hu, Wenbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encapsulating Cobalt nulloparticles in Interconnected N-Doped Hollow Carbon nullofibers with Enriched Co-N-C Moiety for Enhanced Oxygen Electrocatalysis in Zn-Air Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of bifunctional efficient electrocatalysts for both oxygen reduction (ORR) and oxygen evolution reactions (OER) is desirable-while highly challenging-for development of rechargeable metal-air batteries. Herein, an efficient bifunctional electrocatalyst is designed and fabricated by encapsulating Co nulloparticles in interconnected N-doped hollow porous carbon nullofibers (designated as Co@N-C/PCNF) using an ultrafast high-temperature shock technology. Benefiting from the synergistic effect and intrinsic activity of the Co-N-C moiety, as well as porous structure of carbon nullofibers, the Co@N-C/PCNF composite shows high bifunctional electrocatalytic activities for both OER (289 mV at 10 mA cm(-2)) and ORR (half-wave potential of 0.85 V). The Co-N-C moiety in the composite can modulate the local environmental and electrical structure of the catalysts, thus optimizing the adsorption/desorption kinetics and decreasing the reaction barriers for promoting the reversible oxygen electrocatalysis. Co@N-C/PCNF-based aqueous Zn-air batteries (AZAB) provide high power density of 292 mW cm(-2), and the assembled flexible ZAB can power wearable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101438, "DOI": "10.1002/advs.202101438", "DOI Link": "http://dx.doi.org/10.1002/advs.202101438", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000685682500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, J; Zhang, B; Hua, WB; Liang, YR; Zhang, W; Du, YM; Peleckis, G; Indris, S; Gu, QF; Cheng, ZX; Wang, JZ; Liu, HK; Dou, SX; Chou, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jian; Zhang, Bao; Hua, Weibo; Liang, Yaru; Zhang, Wang; Du, Yumeng; Peleckis, Germanas; Indris, Sylvio; Gu, Qinfen; Cheng, Zhenxiang; Wang, Jiazhao; Liu, Huakun; Dou, Shixue; Chou, Shulei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Disordered Rubik's Cube-Inspired Framework for Sodium-Ion Batteries with Ultralong Cycle Lifespan", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) with fast-charge capability and long lifespan could be applied in various sustainable energy storage systems, from personal devices to grid storage. Inspired by the disordered Rubik's cube, here, we report that the high-entropy (HE) concept can lead to a very substantial improvement in the sodium storage properties of hexacyanoferrate (HCF). An example of HE-HCF has been synthesized as a proof of concept, which has achieved impressive cycling stability over 50 000 cycles and an outstanding fast-charging capability up to 75 C. Remarkable air stability and all-climate performance are observed. Its quasi-zero-strain reaction mechanism and high sodium diffusion coefficient have been measured and analyzed by multiple in situ techniques and density functional theory calculations. This strategy provides new insights into the development of advanced electrodes and provides the opportunity to tune electrochemical performance by tailoring the atomic composition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 62, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202215865", "DOI Link": "http://dx.doi.org/10.1002/anie.202215865", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906046000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Seow, JZY; Zhao, HQ; Xu, ZCJ; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yan; Seow, Justin Zhu Yeow; Zhao, Huanqin; Xu, Zhichuan J.; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Flexible and Lightweight Biomass-Reinforced Microwave Absorber", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing a flexible, lightweight and effective electromagnetic (EM) absorber remains challenging despite being on increasing demand as more wearable devices and portable electronics are commercialized. Herein, we report a flexible and lightweight hybrid paper by a facile vacuum-filtration-induced self-assembly process, in which cotton-derived carbon fibers serve as flexible skeletons, compactly surrounded by other microwave-attenuating components (reduced graphene oxide and Fe3O4@C nullowires). Owing to its unique architecture and synergy of the three components, the as-prepared hybrid paper exhibits flexible and lightweight features as well as superb microwave absorption performance. Maximum absorption intensity with reflection loss as low as - 63 dB can be achieved, and its broadest frequency absorption bandwidth of 5.8 GHz almost covers the entire Ku band. Such a hybrid paper is promising to cope with ever-increasing EM interference. The work also paves the way to develop low-cost and flexible EM wave absorber from biomass through a facile method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2020, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125, "DOI": "10.1007/s40820-020-00461-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00461-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540157400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Skorupskii, G; Trump, BA; Kasel, TW; Brown, CM; Hendon, CH; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W.; Brown, Craig M.; Hendon, Christopher H.; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and tunable one-dimensional charge transport in layered lanthanide metal-organic frameworks", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of electrically conductive metal-organic frameworks (MOFs) has led to applications in chemical sensing and electrical energy storage, among others. The most conductive MOFs are made from organic ligands and square-planar transition metal ions connected into two-dimensional (2D) sheets stacked on top of each other. Their electrical properties are thought to depend critically on the covalency of the metal-ligand bond, and less importance is given to out-of-plane charge transport. Here, we report a series of lanthanide-based MOFs that allow fine tuning of the sheet stacking. In these materials, the Ln(3+) ions lie between the planes of the ligands, thus connecting organic layers into a 3D framework through lanthanide-oxygen chains. Here, efficient charge transport is found to occur primarily perpendicular to the 2D sheets. These results demonstrate that high conductivity in layered MOFs does not necessarily require a metal-ligand bond with highly covalent character, and that interactions between organic ligands alone can produce efficient charge transport pathways. High electrical conductivities in metal-organic frameworks-attractive for applications in sensing and energy storage-typically arise in layered MOFs from metal-ligand bonds with strong covalent character. Now, lanthanide-based MOFs have shown high out-of-plane conductivities originating instead from the pi-stacking of organic ligands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 131, "End Page": 136, "Article Number": null, "DOI": "10.1038/s41557-019-0372-0", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0372-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512175500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Gao, HC; Men, S; Shi, ZQ; Lin, Z; Kang, XW; Chen, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jun; Gao, Hongcheng; Men, Shuang; Shi, Zhenqing; Lin, Zhang; Kang, Xiongwu; Chen, Shaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CoSe2 nulloparticles Encapsulated by N-Doped Carbon Framework Intertwined with Carbon nullotubes: High-Performance Dual-Role Anode Materials for Both Li- and Na-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of fundamental and technological significance to develop dual-role anode materials for both lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) with high performance. Here, a composite material based on CoSe2 nulloparticles encapsulated in N-doped carbon framework intertwined with carbon nullotubes (CoSe2@N-CF/CNTs) is prepared successfully from cobalt-based zeolitic imidazolate framework (ZIF-67). As anode materials for LIBs, CoSe2@N-CF/CNTs composites deliver a reversible capacity of 428 mAh g(-1) even after 500 cycles at a current density of 1 A g(-1) with almost 100% Coulombic efficiency. The charge and discharge mechanisms of CoSe2 are characterized using ex situ X-ray diffraction and Raman analysis, from which the lithiation products of CoSe2 are found to be LixCoSe2 and Li2Se, which are further converted to CoSe2 upon delithiation. The CoSe2@N-CF/CNTs composites also demonstrate excellent electrochemical performance as anode materials for SIBs with a carbonate-based electrolyte, with specific capacities of 606 and 501 mAh g(-1) at 0.1 and 1 A g(-1) in the 100th cycle. The electrochemical performance of the anode materials is further studied by pseudocapacitance and galvanostatic intermittent titration technique (GITT) measurements. This work may be exploited for the rational design and development of dual-role anode materials for both Li- and Na-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800763, "DOI": "10.1002/advs.201800763", "DOI Link": "http://dx.doi.org/10.1002/advs.201800763", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453685900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Yang, H; Li, F; Li, LG; Wu, JB; Liu, SH; Cheng, T; Xu, Y; Shao, Q; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Juan; Yang, Hao; Li, Fan; Li, Leigang; Wu, Jianbo; Liu, Shangheng; Cheng, Tao; Xu, Yong; Shao, Qi; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-site Pt-doped RuO2 hollow nullospheres with interstitial C for high-performance acidic overall water splitting", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing stable and efficient overall water splitting is highly desirable for sustainable and efficient hydrogen production yet challenging because of the rapid deactivation of electrocatalysts during the acidic oxygen evolution process. Here, we report that the single-site Pt-doped RuO2 hollow nullospheres (SS Pt-RuO2 HNSs) with interstitial C can serve as highly active and stable electrocatalysts for overall water splitting in 0.5 M H2SO4. The performance toward overall water splitting have surpassed most of the reported catalysts. Impressively, the SS Pt-RuO2 HNSs exhibit promising stability in polymer electrolyte membrane electrolyzer at 100 mA cm(-2) during continuous operation for 100 hours. Detailed experiments reveal that the interstitial C can elongate Ru-O and Pt-O bonds, and the presence of SS Pt can readily vary the electronic properties of RuO2 and improve the OER activity by reducing the energy barriers and enhancing the dissociation energy of *O species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl9271", "DOI": "10.1126/sciadv.abl9271", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl9271", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763326600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YH; Matei, L; Jung, HJ; McCall, KM; Chen, M; Stoumpos, CC; Liu, ZF; Peters, JA; Chung, DY; Wessels, BW; Wasielewski, MR; Dravid, VP; Burger, A; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yihui; Matei, Liviu; Jung, Hee Joon; McCall, Kyle M.; Chen, Michelle; Stoumpos, Constantinos C.; Liu, Zhifu; Peters, John A.; Chung, Duck Young; Wessels, Bruce W.; Wasielewski, Michael R.; Dravid, Vinayak P.; Burger, Arnold; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High spectral resolution of gamma-rays at room temperature by perovskite CsPbBr3 single crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gamma-ray detection and spectroscopy is the quantitative determination of their energy spectra, and is of critical value and critically important in diverse technological and scientific fields. Here we report an improved melt growth method for cesium lead bromide and a special detector design with asymmetrical metal electrode configuration that leads to a high performance at room temperature. As-grown centimeter-sized crystals possess extremely low impurity levels (below 10 p.p.m. for total 69 elements) and detectors achieve 3.9% energy resolution for 122 keV Co-57 gamma-ray and 3.8% for 662 keV Cs-137 gamma-ray. Cesium lead bromide is unique among all gamma-ray detection materials in that its hole transport properties are responsible for the high performance. The superior mobility-lifetime product for holes (1.34 x 10(-3) cm(2) V-1) derives mainly from the record long hole carrier lifetime (over 25 mu s). The easily scalable crystal growth and high-energy resolution, highlight cesium lead bromide as an exceptional next generation material for room temperature radiation detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1609, "DOI": "10.1038/s41467-018-04073-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04073-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430541900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, DZ; Shi, YH; Yang, LM; Xiao, LW; Kehoe, DK; Gun'ko, YK; Boland, JJ; Wang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dunzhu; Shi, Yunhong; Yang, Luming; Xiao, Liwen; Kehoe, Daniel K.; Gun'ko, Yurii K.; Boland, John J.; Wang, Jing Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microplastic release from the degradation of polypropylene feeding bottles during infant formula preparation", "Source Title": "NATURE FOOD", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polypropylene-based products are commonly used for food preparation and storage, but their capacity to release microplastics is poorly understood. We investigated the potential exposure of infants to microplastics from consuming formula prepared in polypropylene (PP) infant feeding bottles (IFBs). Here, we show that PP IFBs release microplastics with values as high as 16,200,000 particles per litre. Scenario studies showed that PP IFB sterilization and exposure to high-temperature water significantly increase microplastic release. A 21-d test of PP IFBs showed periodic fluctuations in microplastic release. To estimate the potential global exposure to infants up to 12months old, we surveyed 48 regions, finding values ranging from 14,600-4,550,000 particles per capita per day, depending on the region. We demonstrate that infant exposure to microplastics is higher than was previously recognized due to the prevalence of PP-based products used in formula preparation and highlight an urgent need to assess whether exposure to microplastics at these levels poses a risk to infant health. Polypropylene-based food containers are utilized widely, but their potential to degrade and produce microplastics is poorly understood. Here, microplastics released from formula preparation procedures in polypropylene feeding bottles are quantified, demonstrating the potential for global infant exposure to microplastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 746, "End Page": "+", "Article Number": null, "DOI": "10.1038/s43016-020-00171-y", "DOI Link": "http://dx.doi.org/10.1038/s43016-020-00171-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607142400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XY; Li, J; Yang, Y; Zhang, S; Zhu, HS; Zhu, XQ; Xing, HH; Zhang, YL; Huang, BL; Guo, SJ; Wang, EK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoyan; Li, Jing; Yang, Yong; Zhang, Shan; Zhu, Haishuang; Zhu, Xiaoqing; Xing, Huanhuan; Zhang, Yelong; Huang, Bolong; Guo, Shaojun; Wang, Erkang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co3O4/Fe0.33Co0.66P Interface nullowire for Enhancing Water Oxidation Catalysis at High Current Density", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing well-defined nullointerfaces is of prime importance to enhance the activity of nulloelectrocatalysts for different catalytic reactions. However, studies on non-noble-metal-interface electrocatalysts with extremely high activity and superior stability at high current density still remains a great challenge. Herein, a class of Co3O4/Fe0.33Co0.66P interface nullowires is rationally designed for boosting oxygen evolution reaction (OER) catalysis at high current density by partial chemical etching of Co(CO3)(0.5)(OH)center dot 0.11H(2)O (Co-CHH) nullowires with Fe(CN)(6)(3-), followed by low-temperature phosphorization treatment. The resulting Co3O4/Fe0.33Co0.66P interface nullowires exhibit very high OER catalytic performance with an overpotential of only 215 mV at a current density of 50 mA cm(-2) and a Tafel slope of 59.8 mV dec(-1) in 1.0 m KOH. In particular, Co3O4/Fe0.33Co0.66P exhibits an obvious advantage in enhancing oxygen evolution at high current density by showing an overpotential of merely 291 mV at 800 mA cm(-2), much lower than that of RuO2 (446 mV). Co3O4/Fe0.33Co0.66P is remarkably stable for the OER with negligible current loss under overpotentials of 200 and 240 mV for 150 h. Theoretical calculations reveal that Co3O4/Fe0.33Co0.66P is more favorable for the OER since the electrochemical catalytic oxygen evolution barrier is optimally lowered by the active Co- and O-sites from the Co3O4/Fe0.33Co0.66P interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 628, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 30, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803551, "DOI": "10.1002/adma.201803551", "DOI Link": "http://dx.doi.org/10.1002/adma.201803551", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449819500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, J; Lunn, DJ; Pusuluri, A; Yoo, JI; O'Malley, MA; Mitragotri, S; Soh, HT; Hawker, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Jia; Lunn, David J.; Pusuluri, Anusha; Yoo, Justin I.; O'Malley, Michelle A.; Mitragotri, Samir; Soh, H. Tom; Hawker, Craig J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering live cell surfaces with functional polymers via cytocompatible controlled radical polymerization", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capability to graft synthetic polymers onto the surfaces of live cells offers the potential to manipulate and control their phenotype and underlying cellular processes. Conventional grafting-to strategies for conjugating preformed polymers to cell surfaces are limited by low polymer grafting efficiency. Here we report an alternative grafting-from strategy for directly engineering the surfaces of live yeast and mammalian cells through cell surface-initiated controlled radical polymerization. By developing cytocompatible PET-RAFT (photoinduced electron transfer-reversible addition-fragmentation chain-transfer polymerization), synthetic polymers with narrow polydispersity (M-w/M-n < 1.3) could be obtained at room temperature in 5 minutes. This polymerization strategy enables chain growth to be initiated directly from chain-transfer agents anchored on the surface of live cells using either covalent attachment or non-covalent insertion, while maintaining high cell viability. Compared with conventional grafting-to approaches, these methods significantly improve the efficiency of grafting polymer chains and enable the active manipulation of cellular phenotypes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 537, "End Page": 545, "Article Number": null, "DOI": "10.1038/NCHEM.2713", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2713", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401894000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yun, GL; Tang, SY; Sun, SS; Yuan, D; Zhao, QB; Deng, L; Yan, S; Du, HP; Dickey, MD; Li, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yun, Guolin; Tang, Shi-Yang; Sun, Shuaishuai; Yuan, Dan; Zhao, Qianbin; Deng, Lei; Yan, Sheng; Du, Haiping; Dickey, Michael D.; Li, Weihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid metal-filled magnetorheological elastomer with positive piezoconductivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive elastic composites have been used widely in soft electronics and soft robotics. These composites are typically a mixture of conductive fillers within elastomeric substrates. They can sense strain via changes in resistance resulting from separation of the fillers during elongation. Thus, most elastic composites exhibit a negative piezoconductive effect, i.e. the conductivity decreases under tensile strain. This property is undesirable for stretchable conductors since such composites may become less conductive during deformation. Here, we report a liquid metal-filled magnetorheological elastomer comprising a hybrid of fillers of liquid metal microdroplets and metallic magnetic microparticles. The composite's resistivity reaches a maximum value in the relaxed state and drops drastically under any deformation, indicating that the composite exhibits an unconventional positive piezoconductive effect. We further investigate the magnetic field-responsive thermal properties of the composite and demonstrate several proof-of-concept applications. This composite has prospective applications in sensors, stretchable conductors, and responsive thermal interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1300, "DOI": "10.1038/s41467-019-09325-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09325-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461881700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miracle, DB; Miller, JD; Senkov, ON; Woodward, C; Uchic, MD; Tiley, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miracle, Daniel B.; Miller, Jonathan D.; Senkov, Oleg N.; Woodward, Christopher; Uchic, Michael D.; Tiley, Jaimie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploration and Development of High Entropy Alloys for Structural Applications", "Source Title": "ENTROPY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a strategy to design and evaluate high-entropy alloys (HEAs) for structural use in the transportation and energy industries. We give HEA goal properties for low (<= 150 degrees C), medium (<= 450 degrees C) and high (>= 1,100 degrees C) use temperatures. A systematic design approach uses palettes of elements chosen to meet target properties of each HEA family and gives methods to build HEAs from these palettes. We show that intermetallic phases are consistent with HEA definitions, and the strategy developed here includes both single-phase, solid solution HEAs and HEAs with intentional addition of a 2nd phase for particulate hardening. A thermodynamic estimate of the effectiveness of configurational entropy to suppress or delay compound formation is given. A 3-stage approach is given to systematically screen and evaluate a vast number of HEAs by integrating high-throughput computations and experiments. CALPHAD methods are used to predict phase equilibria, and high-throughput experiments on materials libraries with controlled composition and microstructure gradients are suggested. Much of this evaluation can be done now, but key components (materials libraries with microstructure gradients and high-throughput tensile testing) are currently missing. Suggestions for future HEA efforts are given.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 738, "Times Cited, All Databases": 805, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 16, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 494, "End Page": 525, "Article Number": null, "DOI": "10.3390/e16010494", "DOI Link": "http://dx.doi.org/10.3390/e16010494", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330340800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Iyengar, P; Kolb, MJ; Pankhurst, JR; Calle-Vallejo, F; Buonsanti, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Iyengar, Pranit; Kolb, Manuel J.; Pankhurst, James R.; Calle-Vallejo, Federico; Buonsanti, Raffaella", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elucidating the Facet-Dependent Selectivity for CO2 Electroreduction to Ethanol of Cu-Ag Tandem Catalysts", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite being desirable high-value products of the electro-chemical CO2 reduction reaction (CO2RR), alcohols are still obtained with lower selectivity compared to hydrocarbons and the reaction pathways leading to their formation are still under debate. In this joint experimental-computational work, we exploit structural sensitivity effects to elucidate the ethanol-producing active sites on Cu-Ag CO2RR tandem catalysts. Specifically, methane-selective Cu nullo-octahedra (Cu-oh), enclosed by (111) facets, and ethylene-selective Cu nullocubes (Cu-cub), enclosed by (100) facets, are mixed with CO-selective Ag nullospheres (Ag-sph) to form Cu-oh-(A)g and Cu-cub-Ag bimetallic catalysts. Ethanol is selectively enhanced via the *CHx-*CO coupling pathway at the terraces of Cuoh-Ag in the CO-enriched environment generated by the Ag-sph. Conversely, on Cu-cub-Ag, ethanol is selectively produced via the same pathway at the edges and corners of Cu-cub, while ethylene continues to be produced at the terraces. The terraces being the predominullt surfaces on the catalysts, such facet dependence explains the higher ethanol-to-ethylene ratio on the Cuoh-Ag. These findings illustrate how tandem catalysis and structure-sensitive effects can be combined to obtain notable changes in the selectivity of electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2021, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4456, "End Page": 4463, "Article Number": null, "DOI": "10.1021/acscatal.1c00420", "DOI Link": "http://dx.doi.org/10.1021/acscatal.1c00420", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641284700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, CJ; Lee, YK; Yu, Y; Byun, S; Luo, ZZ; Lee, H; Ge, BZ; Lee, YL; Chen, XQ; Lee, JY; Cojocaru-Mirédin, O; Chang, H; Im, J; Cho, SP; Wuttig, M; Dravid, VP; Kanatzidis, MG; Chung, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Chongjian; Lee, Yong Kyu; Yu, Yuan; Byun, Sejin; Luo, Zhong-Zhen; Lee, Hyungseok; Ge, Bangzhi; Lee, Yea-Lee; Chen, Xinqi; Lee, Ji Yeong; Cojocaru-Miredin, Oana; Chang, Hyunju; Im, Jino; Cho, Sung-Pyo; Wuttig, Matthias; Dravid, Vinayak P.; Kanatzidis, Mercouri G.; Chung, In", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polycrystalline SnSe with a thermoelectric figure of merit greater than the single crystal", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric materials generate electric energy from waste heat, with conversion efficiency governed by the dimensionless figure of merit, ZT. Single-crystal tin selenide (SnSe) was discovered to exhibit a high ZT of roughly 2.2-2.6 at 913 K, but more practical and deployable polycrystal versions of the same compound suffer from much poorer overall ZT, thereby thwarting prospects for cost-effective lead-free thermoelectrics. The poor polycrystal bulk performance is attributed to traces of tin oxides covering the surface of SnSe powders, which increases thermal conductivity, reduces electrical conductivity and thereby reduces ZT. Here, we report that hole-doped SnSe polycrystalline samples with reagents carefully purified and tin oxides removed exhibit an ZT of roughly 3.1 at 783 K. Its lattice thermal conductivity is ultralow at roughly 0.07 W m(-1) K-1 at 783 K, lower than the single crystals. The path to ultrahigh thermoelectric performance in polycrystalline samples is the proper removal of the deleterious thermally conductive oxides from the surface of SnSe grains. These results could open an era of high-performance practical thermoelectrics from this high-performance material. SnSe has a very high thermoelectric figure of merit ZT, but uncommonly polycrystalline samples have higher lattice thermal conductivity than single crystals. Here, by controlling Sn reagent purity and removing SnOx impurities, a lower thermal conductivity is achieved, enabling ZT of 3.1 at 783 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 20, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1378, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-021-01064-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-021-01064-6", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680338900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZW; Jian, ZZ; Li, W; Chang, YJ; Ge, BH; Hanus, R; Yang, J; Chen, Y; Huang, MX; Snyder, GJ; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhiwei; Jian, Zhengzhong; Li, Wen; Chang, Yunjie; Ge, Binghui; Hanus, Riley; Yang, Jiong; Chen, Yue; Huang, Mingxin; Snyder, Gerald Jeffrey; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice Dislocations Enhancing Thermoelectric PbTe in Addition to Band Convergence", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonon scattering by nullostructures and point defects has become the primary strategy for minimizing the lattice thermal conductivity (kappa(L)) in thermoelectric materials. However, these scatterers are only effective at the extremes of the phonon spectrum. Recently, it has been demonstrated that dislocations are effective at scattering the remaining mid-frequency phonons as well. In this work, by varying the concentration of Na in Pb0.97Eu0.03Te, it has been determined that the dominullt microstructural features are point defects, lattice dislocations, and nullostructure interfaces. This study reveals that dense lattice dislocations (approximate to 4 x 10(12) cm(-2)) are particularly effective at reducing kappa(L). When the dislocation concentration is maximized, one of the lowest kappa(L) values reported for PbTe is achieved. Furthermore, due to the band convergence of the alloyed 3% mol. EuTe the electronic performance is enhanced, and a high thermoelectric figure of merit, zT, of approximate to 2.2 is achieved. This work not only demonstrates the effectiveness of dense lattice dislocations as a means of lowering kappa(L), but also the importance of engineering both thermal and electronic transport simultaneously when designing high-performance thermoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 29, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1606768, "DOI": "10.1002/adma.201606768", "DOI Link": "http://dx.doi.org/10.1002/adma.201606768", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403280600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, DN; He, YB; Huang, HJ; Yuan, YF; Zhong, GM; Zhao, Q; Hao, XG; Zhang, DF; Lai, C; Zhang, SW; Ma, JB; Wei, YP; Yu, QP; Lv, W; Yu, Y; Li, BH; Yang, QH; Yang, Y; Lu, J; Kang, FY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Danni; He, Yan-Bing; Huang, Huijuan; Yuan, Yifei; Zhong, Guiming; Zhao, Qiang; Hao, Xiaoge; Zhang, Danfeng; Lai, Chen; Zhang, Siwei; Ma, Jiabin; Wei, Yinping; Yu, Qipeng; Lv, Wei; Yu, Yan; Li, Baohua; Yang, Quan-Hong; Yang, Yong; Lu, Jun; Kang, Feiyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cross-linked beta alumina nullowires with compact gel polymer electrolyte coating for ultra-stable sodium metal battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium metal batteries have potentially high energy densities, but severe sodium-dendrite growth and side reactions prevent their practical applications, especially at high temperatures. Herein, we design an inorganic ionic conductor/gel polymer electrolyte composite, where uniformly cross-linked beta alumina nullowires are compactly coated by a poly (vinylidene fluoride-co-hexafluoropropylene)-based gel polymer electrolyte through their strong molecular interactions. These beta alumina nullowires combined with the gel polymer layer create dense and homogeneous solid-liquid hybrid sodium-ion transportation channels through and along the nullowires, which promote uniform sodium deposition and formation of a stable and flat solid electrolyte interface on the sodium metal anode. Side reactions between the sodium metal and liquid electrolyte, as well as sodium dendrite formation, are successfully suppressed, especially at 60 degrees C. The sodium vanadium phosphate/sodium full cells with composite electrolyte exhibit 95.3% and 78.8% capacity retention after 1000 cycles at 1C at 25 degrees C and 60 degrees C, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4244, "DOI": "10.1038/s41467-019-11960-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11960-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486374800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, GJ; Shi, FY; Hao, SQ; Chi, H; Bailey, TP; Zhao, LD; Uher, C; Wolverton, C; Dravid, VP; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Gangjian; Shi, Fengyuan; Hao, Shiqiang; Chi, Hang; Bailey, Trevor P.; Zhao, Li-Dong; Uher, Ctirad; Wolverton, Chris; Dravid, Vinayak P.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valence Band Modification and High Thermoelectric Performance in SnTe Heavily Alloyed with MnTe", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate a high solubility limit of >9 mol% for MnTe alloying in SnTe. The electrical conductivity of SnTe decreases gradually while the Seebeck coefficient increases remarkably with increasing MnTe content, leading to enhanced power factors. The room-temperature Seebeck coefficients of Mn-doped SnTe are significantly higher than those predicted by theoretical Pisarenko plots for pure SnTe, indicating a modified band structure. The high-temperature Hall data of Sn1-xMnxTe show strong temperature dependence, suggestive of a two-valence-band conduction behavior. Moreover, the peak temperature of the Hall plot of Sn1-xMnxTe shifts toward lower temperature as MnTe content is increased, which is clear evidence of decreased energy separation (band convergence) between the two valence bands. The first-principles electronic structure calculations based on density functional theory also support this point. The higher doping fraction (>9%) of Mn in comparison with similar to 3% for Cd and Hg in SnTe gives rise to a much better valence band convergence that is responsible for the observed highest Seebeck coefficient of similar to 230 mu V/K at 900 K The high doping fraction of Mn in SnTe also creates stronger point defect scattering, which when combined with ubiquitous endotaxial MnTe nullostructures when the solubility of Mn is exceeded scatters a wide spectrum of phonons for a low lattice thermal conductivity of 0.9 W m(-1) K-1 at 800 K. The synergistic role that Mn plays in regulating the electron and phonon transport of SnTe yields a high thermoelectric figure of merit of 1.3 at 900 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2015, "Volume": 137, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11507, "End Page": 11516, "Article Number": null, "DOI": "10.1021/jacs.5b07284", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b07284", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361251600044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, K; Peng, X; An, J; Wang, AC; Luo, JJ; Sun, BZ; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Kai; Peng, Xiao; An, Jie; Wang, Aurelia Chi; Luo, Jianjun; Sun, Baozhong; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape adaptable and highly resilient 3D braided triboelectric nullogenerators as e-textiles for power and sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining traditional textiles with triboelectric nullogenerators (TENGs) gives birth to self-powered electronic textiles (e-textiles). However, there are two bottlenecks in their widespread application, low power output and poor sensing capability. Herein, by means of the three-dimensional five-directional braided (3DB) structure, a TENG-based e-textile with the features of high flexibility, shape adaptability, structural integrity, cyclic washability, and superior mechanical stability, is designed for power and sensing. Due to the spatial frame-column structure formed between the outer braided yarn and inner axial yarn, the 3DB-TENG is also endowed with high compression resilience, enhanced power output, improved pressure sensitivity, and vibrational energy harvesting ability, which can power miniature wearable electronics and respond to tiny weight variations. Furthermore, an intelligent shoe and an identity recognition carpet are demonstrated to verify its performance. This study hopes to provide a new design concept for high-performance textile-based TENGs and expand their application scope in human-machine interfacing. Low power output and poor sensing ability are bottlenecks for the practical application of fabric-based triboelectric nullogenerators (TENGs). The authors develop a shape adaptable and highly resilient 3D braided TENG, which is endowed with enhanced power output and improved pressure sensitivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16642-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16642-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541703300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, Y; Chen, YJ; Wu, KL; Chen, Z; Liu, SJ; Cao, X; Cheong, WO; Meng, T; Luo, J; Zheng, LR; Liu, CG; Wang, DS; Peng, Q; Li, J; Chen, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Yuan; Chen, Yinjuan; Wu, Konglin; Chen, Zheng; Liu, Shoujie; Cao, Xing; Cheong, Weng-Chon; Meng, Tao; Luo, Jun; Zheng, Lirong; Liu, Chenguang; Wang, Dingsheng; Peng, Qing; Li, Jun; Chen, Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating the coordination structure of single-atom Fe-NxCy catalytic sites for benzene oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed metal-N-C structures are efficient active sites for catalyzing benzene oxidation reaction (BOR). However, the roles of N and C atoms are still unclear. We report a polymerization-regulated pyrolysis strategy for synthesizing single-atom Fe-based catalysts, and present a systematic study on the coordination effect of Fe-NxCy catalytic sites in BOR. The special coordination environment of single-atom Fe sites brings a surprising discovery: Fe atoms anchored by four-coordinating N atoms exhibit the highest BOR performance with benzene conversion of 78.4% and phenol selectivity of 100%. Upon replacing coordinated N atoms by one or two C atoms, the BOR activities decrease gradually. Theoretical calculations demonstrate the coordination pattern influences not only the structure and electronic features, but also the catalytic reaction pathway and the formation of key oxidative species. The increase of Fe-N coordination number facilitates the generation and activation of the crucial intermediate O=Fe=O species, thereby enhancing the BOR activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4290, "DOI": "10.1038/s41467-019-12362-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12362-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486566700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fortman, DJ; Brutman, JP; Cramer, CJ; Hillmyer, MA; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fortman, David J.; Brutman, Jacob P.; Cramer, Christopher J.; Hillmyer, Marc A.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vitrimers are polymer networks whose cross-links undergo associative exchange processes at elevated temperature, usually in the presence of an embedded catalyst. This design feature enables the reshaping of materials with mechanical properties similar to thermoset resins. Here we report a new class of vitrimers consisting of polyhydroxyurethanes (PHUs) derived from six-membered cyclic carbonates and amines. PHU networks relax stress and may be reprocessed at elevated temperature and pressure in the absence of an external catalyst. The as-synthesized networks exhibit tensile properties comparable to those of leading thermosets and recover ca. 75% of their as-synthesized values following reprocessing. Stress relaxation occurs through an associative process involving nudeophilic addition of free hydroxyl groups to the carbamate linkages and exhibits an Arrhenius activation energy of 111 +/- 10 kJ/mol, which is lower than that observed for molecular model compounds (148 +/- 7 kJ/mol). These findings suggest that transcarbamoylation is activated by mechanical stress, which we attribute, on the basis of DFT calculations, to the twisting of N lone pairs out of conjugation with the carbonyl pi orbitals. PHU vitrimers are a promising new class of repairable networks because of their outstanding mechanical properties, avoidance of toxic isocyanate monomers, and catalyst-free repair processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 710, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2015, "Volume": 137, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14019, "End Page": 14022, "Article Number": null, "DOI": "10.1021/jacs.5b08084", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b08084", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364727600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZT; Shang, TX; Deng, YQ; Tao, Y; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhitan; Shang, Tongxin; Deng, Yaqian; Tao, Ying; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Assembly of MXenes from 2D to 3D", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since their discovery in 2011, transition metal carbides or nitrides (MXenes) have attracted a wide range of attention due to their unique properties and promise for use in a variety of applications. However, the low accessible surface area and poor processability of MXene nullosheets caused by their restacking have severely hindered their practical use, and this is expected to be solved by integrating them into macroscopic assemblies. Here, recent progress in the construction of MXene assemblies from 2D to 3D at the macro and/or microlevel is summarized. The mechanisms of their assembly are also discussed to better understand the relationship between performance and assembled structure. The possible uses of MXene assemblies in energy conversion and storage, electromagnetic interference shielding and absorption, and other applications are summarized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903077, "DOI": "10.1002/advs.201903077", "DOI Link": "http://dx.doi.org/10.1002/advs.201903077", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513079200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XY; Fan, KB; Shadrivov, IV; Padilla, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xinyu; Fan, Kebin; Shadrivov, Ilya V.; Padilla, Willie J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental realization of a terahertz all-dielectric metasurface absorber", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterial absorbers consisting of metal, metal-dielectric, or dielectric materials have been realized across much of the electromagnetic spectrum and have demonstrated novel properties and applications. However, most absorbers utilize metals and thus are limited in applicability due to their low melting point, high Ohmic loss and high thermal conductivity. Other approaches rely on large dielectric structures and / or a supporting dielectric substrate as a loss mechanism, thereby realizing large absorption volumes. Here we present a terahertz (THz) all dielectric metasurface absorber based on hybrid dielectric waveguide resonullces. We tune the metasurface geometry in order to overlap electric and magnetic dipole resonullces at the same frequency, thus achieving an experimental absorption of 97.5%. A simulated dielectric metasurface achieves a total absorption coefficient enhancement factor of F-T = 140, with a small absorption volume. Our experimental results are well described by theory and simulations and not limited to the THz range, but may be extended to microwave, infrared and optical frequencies. The concept of an all-dielectric metasurface absorber offers a new route for control of the emission and absorption of electromagnetic radiation from surfaces with potential applications in energy harvesting, imaging, and sensing. (C) 2017 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2017, "Volume": 25, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 191, "End Page": 201, "Article Number": null, "DOI": "10.1364/OE.25.000191", "DOI Link": "http://dx.doi.org/10.1364/OE.25.000191", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396510600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, TY; Chen, W; Lv, WQ; Huang, JW; Zhu, J; Chu, JW; Yan, CY; Wu, CY; Yan, YC; He, WD; Xiong, J; Li, YR; Yan, CL; Goodenough, JB; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Tianyu; Chen, Wei; Lv, Weiqiang; Huang, Jianwen; Zhu, Jian; Chu, Junwei; Yan, Chaoyi; Wu, Chunyang; Yan, Yichao; He, Weidong; Xiong, Jie; Li, Yanrong; Yan, Chenglin; Goodenough, John B.; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inhibiting Polysulfide Shuttling with a Graphene Composite Separator for Highly Robust Lithium-Sulfur Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries are of considerable interest for high-density energy storage. However, the adoption of Li-S batteries to date has been severely plagued by the polysulfide shuttling effect, whereby polysulfide molecules dissolve into the electrolyte and shuttle across the separator to react with the anode materials, leading to a rapidly fading capacity. Herein, by directly coating a thin layer of reduced graphene oxide (rGO)/sodium lignosulfonate (SL) composite on the standard polypropylene (PP) separator, we produce a rGO@SL/PP separator with abundant negatively charged sulfonic groups in the porous lignin network, which effectively suppress the translocation of the negatively charged polysulfide (PS) ions without compromising the transport of positively charged Li+ ions. Using the rGO@SL/PP separator, we demonstrate a highly robust Li-S battery with a capacity retention of 74% over 1,000 cycles. This study defines an effective strategy to inhibit the PS shuttling effect for highly robust Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2018, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2091, "End Page": 2104, "Article Number": null, "DOI": "10.1016/j.joule.2018.07.022", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.07.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447735000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, L; Meng, TT; Zheng, XY; Li, TY; Brozena, AH; Mao, YM; Zhang, Q; Clifford, BC; Rao, JC; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Lin; Meng, Taotao; Zheng, Xueying; Li, Tangyuan; Brozena, Alexandra H. H.; Mao, Yimin; Zhang, Qian; Clifford, Bryson Callie; Rao, Jiancun; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose-Carboxymethylcellulose Electrolyte for Stable, High-Rate Zinc-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn ion batteries (ZIBs) are one of the most promising battery chemistries for grid-scale renewable energy storage. However, their application is limited by issues such as Zn dendrite formation and undesirable side reactions that can occur in the presence of excess free water molecules and ions. In this study, a nullocellulose-carboxymethylcellulose (CMC) hydrogel electrolyte is demonstrated that features stable cycling performance and high Zn2+ conductivity (26 mS cm(-1)), which is attributed to the material's strong mechanical strength (approximate to 70 MPa) and water-bonding ability. With this electrolyte, the Zn-metal anode shows exceptional cycling stability at an ultra-high rate, with the ability to sustain a current density as high as 80 mA cm(-2) for more than 3500 cycles and a cumulative capacity of 17.6 Ah cm(-2) (40 mA cm(-2)). Additionally, side reactions, such as hydrogen evolution and surface passivation, are substantially reduced due to the strong water-bonding capacity of the CMC. Full Zn||MnO2 batteries fabricated with this electrolyte demonstrate excellent high-rate performance and long-term cycling stability (>500 cycles at 8C). These results suggest the cellulose-CMC electrolyte as a promising low-cost, easy-to-fabricate, and sustainable aqueous-based electrolyte for ZIBs with excellent electrochemical performance that can help pave the way toward grid-scale energy storage for renewable energy sources.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 33, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202302098", "DOI Link": "http://dx.doi.org/10.1002/adfm.202302098", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961672800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, B; Liu, H; Zhang, X; Zhang, P; Zhu, QZ; Du, HL; Wang, LL; Zhang, RP; Xu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Bin; Liu, Huan; Zhang, Xin; Zhang, Peng; Zhu, Qizhen; Du, Huiling; Wang, Lianli; Zhang, Rupeng; Xu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-Derived ZnS nullodots/Ti3C2Tx MXene Hybrids Boosting Superior Lithium Storage Performance", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ZnS has great potentials as an anode for lithium storage because of its high theoretical capacity and resource abundance; however, the large volume expansion accompanied with structural collapse and low conductivity of ZnS cause severe capacity fading and inferior rate capability during lithium storage. Herein, 0D-2D ZnS nullodots/Ti3C2Tx MXene hybrids are prepared by anchoring ZnS nullodots on Ti3C2Tx MXene nullosheets through coordination modulation between MXene and MOF precursor (ZIF-8) followed with sulfidation. The MXene substrate coupled with the ZnS nullodots can synergistically accommodate volume variation of ZnS over charge-discharge to realize stable cyclability. As revealed by XPS characterizations and DFT calculations, the strong interfacial interaction between ZnS nullodots and MXene nullosheets can boost fast electron/lithium-ion transfer to achieve excellent electrochemical activity and kinetics for lithium storage. Thereby, the as-prepared ZnS nullodots/MXene hybrid exhibits a high capacity of 726.8 mAh g(-1) at 30 mA g(-1), superior cyclic stability (462.8 mAh g(-1) after 1000 cycles at 0.5 A g(-1)), and excellent rate performance. The present results provide new insights into the understanding of the lithium storage mechanism of ZnS and the revealing of the effects of interfacial interaction on lithium storage performance enhancement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 202, "DOI": "10.1007/s40820-021-00728-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00728-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000699970800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YD; Qiao, JS; Yu, P; Hu, ZX; Lin, ZY; Lau, SP; Liu, Z; Ji, W; Chai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yuda; Qiao, Jingsi; Yu, Peng; Hu, Zhixin; Lin, Ziyuan; Lau, Shu Ping; Liu, Zheng; Ji, Wei; Chai, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinarily Strong Interlayer Interaction in 2D Layered PtS2", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum disulfide (PtS2), a new member of the group-10 transition-metal dichalcogenides, is studied experimentally and theoretically. The indirect bandgap of PtS2 can be drastically tuned from 1.6 eV (monolayer) to 0.25 eV (bulk counterpart), and the interlayer mechanical coupling is almost isotropic. It can be explained by strongly interlayer interaction from the p(z) orbital hybridization of S atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 484, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2016, "Volume": 28, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2399, "End Page": 2407, "Article Number": null, "DOI": "10.1002/adma.201504572", "DOI Link": "http://dx.doi.org/10.1002/adma.201504572", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372459600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Yu, R; Weng, ST; Zhang, QH; Wang, XF; Guo, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhuo; Yu, Rui; Weng, Suting; Zhang, Qinghua; Wang, Xuefeng; Guo, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring polymer electrolyte ionic conductivity for production of low- temperature operating quasi-all-solid-state lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stable operation of lithium-based batteries at low temperatures is critical for applications in cold climates. However, low-temperature operations are plagued by insufficient dynamics in the bulk of the electrolyte and at electrode|electrolyte interfaces. Here, we report a quasi-solid-state polymer electrolyte with an ionic conductivity of 2.2 x 10(-4) S cm(-1) at -20 degrees C. The electrolyte is prepared via in situ polymerization using a 1,3,5-trioxane-based precursor. The polymer-based electrolyte enables a dual-layered solid electrolyte interphase formation on the Li metal electrode and stabilizes the LiNi0.8Co0.1Mn0.1O2-based positive electrode, thus improving interfacial charge-transfer at low temperatures. Consequently, the growth of dendrites at the lithium metal electrode is hindered, thus enabling stable Li||LiNi0.8Co0.1Mn0.1O2 coin and pouch cell operation even at -30 degrees C. In particular, we report a Li||LiNi0.8Co0.1Mn0.1O2 coin cell cycled at -20 degrees C and 20 mA g(-1) capable of retaining more than 75% (i.e., around 151 mAh g(-1)) of its first discharge capacity cycle at 30 degrees C and same specific current. Low-temperature batteries are detrimentally affected by the sluggish kinetics of the electrolyte. Here, the authors propose a quasi-solid-state polymer electrolyte capable of improving interfacial charge transfer and enabling stable Li metal cell operation even at -30 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 482, "DOI": "10.1038/s41467-023-35857-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35857-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955780200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, QH; Chen, Y; Li, J; Jiang, C; Liu, B; Liu, Y; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Qihong; Chen, Yang; Li, Jia; Jiang, Chao; Liu, Bin; Liu, Yong; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing the phase transformation and dislocation evolution in dual-phase high-entropy alloys", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Some high-entropy alloys, which contain two or more component phases with highly different properties, can achieve an outstanding combination of high strength and high ductility, and even break in the strength-ductility trade-off. However, a detailed atomic-scale mechanism of the dynamic continuous microstructural evolution has not hitherto been performed, to limit the achievement of bulk dual-phase high-entropy alloys with the improved strength and toughness. Here we report the deformation and plasticity as well as strength in the dual-phase nullocrystalline high-entropy alloys with a variable volume fraction of face-centered-cube (FCC) and hexagonal closed-packed (HCP) phases using atomistic simulations during the tensile-straining tests. The results show that the amplitudes of additional interaction stresses and strains rely on such factors as the differences in the mechanical property and volume fraction of each phase. Due to the complexity of the phase and phase boundary, the mechanical properties of the dual-phase nullocrystalline high-entropy alloys, in general, cannot be accurately estimated on the basis of the simple mixed laws, which are dependent upon the volume fraction and yielding strength of individual phase. The aim of this study is to describe how the phase volume fractions affect the mechanical properties in the dual-phase high-entropy alloys. The flow stress and work hardening of the dual-phase high-entropy alloys can be explained on the basis of the mobile dislocation density and dislocation-induced phase transformation in the corresponding phases. The HCP-based high-entropy alloys show the good plasticity and high strength, and are unlike traditional alloys with the low ductility, owing to the occurrence of the HCP to FCC phase transformation. The strength of the dual-phase high-entropy alloy with the 16.7% FCC-phase volume fraction exceeds that of HCP-based or FCC-based matrix, due to the stronger interface hardening. We expect that these results would be helpful for designing and selecting dual-phase high-entropy alloys with great strength and good ductility in various engineering applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 114, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 161, "End Page": 173, "Article Number": null, "DOI": "10.1016/j.ijplas.2018.10.014", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2018.10.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460718900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boota, M; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boota, Muhammad; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene-Conducting Polymer Asymmetric Pseudocapacitors", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conducting polymers (CPs) are attractive pseudocapacitive materials which show the highest capacitance under positive potentials in aqueous protic electrolytes. One way to expand their voltage window (thus energy density) in aqueous electrolytes is to manufacture asymmetric supercapacitors using distinctly different anodes. However, CPs lack matching pseudocapacitive anode materials that can perform well in protic electrolytes (e.g., sulfuric acid). 2D titanium carbide (Ti3C2Tx), MXene, as a universal pseudocapacitive anode material for a range of CPs, such as polyaniline, polypyrrole, and poly(3,4-ethylenedioxythiophene) deposited on reduced graphene oxide (rGO) sheets, is reported here. All-pseudocapacitive organic-inorganic asymmetric devices with MXene cathodes and rGO-polymer anodes can operate in voltage windows up to 1.45 V in 3 m H2SO4. Most importantly, these devices show outstanding cycling performance, outperforming many reported asymmetric pseudocapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2019, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802917, "DOI": "10.1002/aenm.201802917", "DOI Link": "http://dx.doi.org/10.1002/aenm.201802917", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458912300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JY; Illeperuma, WBK; Suo, ZG; Vlassak, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianyu; Illeperuma, Widusha B. K.; Suo, Zhigang; Vlassak, Joost J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Hydrogels with Extremely High Stiffness and Toughness", "Source Title": "ACS MACRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of hydrogels for cartilage replacement and soft robotics has highlighted a challenge: load-bearing hydrogels need to be both stiff and tough. Several approaches have been reported to improve the toughness of hydrogels, but simultaneously achieving high stiffness and toughness remains difficult. Here we report that alginate-polyacrylamide hydrogels can simultaneously achieve high stiffiiess and toughness. We combine short-and long-chain alginates to reduce the viscosity of pregel solutions and synthesize homogeneous hydrogels of high ionic cross-link density. The resulting hydrogels can have elastic moduli of similar to 1 MPa and fracture energies of similar to 4 kJ m(-2). Furthermore, this approach breaks the inverse relation between stiffness and toughness: while maintaining constant elastic moduli, these hydrogels can achieve fracture energies up to similar to 16 kJ m(-2). These stiff and tough hydrogels hold promise for further development as load-bearing materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 520, "End Page": 523, "Article Number": null, "DOI": "10.1021/mz5002355", "DOI Link": "http://dx.doi.org/10.1021/mz5002355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337644500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Han, LL; Huang, BL; Shao, Q; Xin, HLL; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Juan; Han, Lili; Huang, Bolong; Shao, Qi; Xin, Huolin L.; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphization activated ruthenium-tellurium nullorods for efficient water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pursuing active and durable water splitting electrocatalysts is of vital significance for solving the sluggish kinetics of the oxygen evolution reaction (OER) process in energy supply. Herein, theoretical calculations identify that the local distortion-strain effect in amorphous RuTe2 system abnormally sensitizes the Te-p pi coupling capability and enhances the electron-transfer of Ru-sites, in which the excellent inter-orbital p-d transfers determine strong electronic activities for boosting OER performance. Thus, a robust electrocatalyst based on amorphous RuTe2 porous nullorods (PNRs) is successfully fabricated. In the acidic water splitting, a-RuTe2 PNRs exhibit a superior performance, which only require a cell voltage of 1.52 V to reach a current density of 10 mA cm(-2). Detailed investigations show that the high density of defects combine with oxygen atoms to form RuOxHy species, which are conducive to the OER. This work offers valuable insights for constructing robust electrocatalysts based on theoretical calculations guided by rational design and amorphous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 12", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5692, "DOI": "10.1038/s41467-019-13519-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13519-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502254500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, GK; Jiang, CY; Sabatini, R; Yang, ZY; Wei, MY; Quan, LN; Liang, QM; Rasmita, A; Askerka, M; Walters, G; Gong, XW; Xing, J; Wen, XL; Quintero-Bermudez, R; Yuan, HF; Xing, GC; Wang, XR; Song, DT; Voznyy, O; Zhang, MT; Hoogland, S; Gao, WB; Xiong, QH; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Guankui; Jiang, Chongyun; Sabatini, Randy; Yang, Zhenyu; Wei, Mingyang; Quan, Li Na; Liang, Qiuming; Rasmita, Abdullah; Askerka, Mikhail; Walters, Grant; Gong, Xiwen; Xing, Jun; Wen, Xinglin; Quintero-Bermudez, Rafael; Yuan, Haifeng; Xing, Guichuan; Wang, X. Renshaw; Song, Datong; Voznyy, Oleksandr; Zhang, Mingtao; Hoogland, Sjoerd; Gao, Weibo; Xiong, Qihua; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin control in reduced-dimensional chiral perovskites", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic perovskites exhibit strong spin-orbit coupling(1), spin-dependent optical selection rules(2,3) and large Rashba splitting(4-8). These characteristics make them promising candidates for spintronic devices(9) with photonic interfaces. Here we report that spin polarization in perovskites can be controlled through chemical design as well as by a magnetic field. We obtain both spin-polarized photon absorption and spin-polarized photoluminescence in reduced-dimensional chiral perovskites through combined strategies of chirality transfer and energy funnelling. A 3% spin-polarized photoluminescence is observed even in the absence of an applied external magnetic field owing to the different emission rates of sigma(+) and sigma(-) polarized photoluminescence. Three-dimensional perovskites achieve a comparable degree of photoluminescence polarization only under an external magnetic field of 5 T. Our findings pave the way for chiral perovskites as powerful spintronic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 528, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-018-0220-6", "DOI Link": "http://dx.doi.org/10.1038/s41566-018-0220-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443022200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YBT; Panwisawas, C; Ghoussoub, JN; Gong, YL; Clark, JWG; Németh, AAN; McCartney, DG; Reed, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yuanbo T.; Panwisawas, Chinnapat; Ghoussoub, Joseph N.; Gong, Yilun; Clark, John W. G.; Nemeth, Andre A. N.; McCartney, D. Graham; Reed, Roger C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloys-by-design: Application to new superalloys for additive manufacturing", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New grades of gamma/gamma' nickel-based superalloy for the additive manufacturing process are designed using computational approaches. Account is taken of the need to avoid defect formation via solidification and solid-state cracking. Processing trials are carried out using powder-based selective laser melting, comparing with the heritage alloys IN939 and CM247LC. Microstructural characterisation, calorimetry and hot tensile testing are used to assess the approach employed. The superior processability and mechanical behaviour of the new alloys are demonstrated. Suggestions are made for refinements to the modelling approach. (C) 2020 Published by Elsevier Ltd on behalf of Acta Materialia Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 202, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 417, "End Page": 436, "Article Number": null, "DOI": "10.1016/j.actamat.2020.09.023", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.09.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599929500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sivadas, N; Daniels, MW; Swendsen, RH; Okamoto, S; Xiao, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sivadas, Nikhil; Daniels, Matthew W.; Swendsen, Robert H.; Okamoto, Satoshi; Xiao, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic ground state of semiconducting transition-metal trichalcogenide monolayers", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered transition-metal trichalcogenides with the chemical formula ABX(3) have attracted recent interest as potential candidates for two-dimensional magnets. Using first-principles calculations within density functional theory, we investigate the magnetic ground states of monolayers of Mn- and Cr-based semiconducting trichalcogenides. We show that the second and third nearest-neighbor exchange interactions (J(2) and J(3)) between magnetic ions, which have been largely overlooked in previous theoretical studies, are crucial in determining the magnetic ground state. Specifically, we find that monolayer CrSiTe3 is an antiferromagnet with a zigzag spin texture due to significant contribution from J3, whereas CrGeTe3 is a ferromagnet with a Curie temperature of 106 K. Monolayers of Mn compounds (MnPS3 and MnPSe3) always show antiferromagnetic Neel order. We identify the physical origin of various exchange interactions, and demonstrate that strain can be an effective knob for tuning the magnetic properties. Possible magnetic ordering in the bulk is also discussed. Our study suggests that ABX(3) can be a promising platform to explore two-dimensional magnetic phenomena.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2015, "Volume": 91, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235425, "DOI": "10.1103/PhysRevB.91.235425", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.235425", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356215700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LY; Li, ZX; Yang, WJ; Huang, YM; Huang, G; Guan, QQ; Dong, YM; Lu, JL; Yu, SH; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Luyan; Li, Zhixin; Yang, Weijie; Huang, Yamin; Huang, Gang; Guan, Qiaoqiao; Dong, Yemin; Lu, Junling; Yu, Shu-Hong; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of Pd nulloparticles with engineered pore walls in MOFs for enhanced catalysis", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Creating free-access active sites and regulating their interaction with substrates are crucial for efficient catalysis, yet remain a grand challenge. Herein, naked Pd nulloparticles (NPs) have been encapsulated in a metal-organic framework (MOF), MIL-101-NH2, to afford Pd@MIL-101-NH2. The hydrophobic perfluoroalkyls were post-synthetically modified onto -NH2 group to yield Pd@MIL-101-Fx (x = 3, 5, 7, 11, 15), which engineer the MOF pore walls to regulate Pd surrounding microenvironment and interaction with substrates. As a result, both the dehydrogenation coupling of organosilane and hydrogenation of halogenated nitrobenzenes show that their activity and selectivity can be greatly promoted upon hydrophobic modification due to the favorable substrate enrichment and regulated interactions between Pd and the modified MOF hosts, far surpassing the traditional supported or surfactant-protected Pd NPs. We envision metal NPs@MOF composites would be an ideal platform integrating the inherent activity of well-accessible metal sites with engineered microenvironment via readily tunable MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 686, "End Page": 698, "Article Number": null, "DOI": "10.1016/j.chempr.2020.11.023", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.11.023", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628786100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, XG; Tan, HY; Cheng, B; Zhu, BC; Zhang, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Xingang; Tan, Haiyan; Cheng, Bei; Zhu, Bicheng; Zhang, Liuyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D/2D Black Phosphorus/g-C3N4 S-Scheme Heterojunction Photocatalysts for CO2 Reduction Investigated using DFT Calculations", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reduction of CO2 to hydrocarbon compounds is a promising method for addressing energy shortages and environmental pollution. Considerable efforts have been devoted to exploring valid strategies to enhance photocatalytic efficiency. Among various modification methods, the hybridization of different photocatalysts is effective for addressing the shortcomings of a single photocatalyst and enhancing its CO2 reduction performance. In addition, metal-free materials such as g-C3N4 and black phosphorus (BP) are attractive because of their unique structures and electronic properties. Many experimental results have verified the superior photocatalytic activity of a BP/g-C3N4 composite. However, theoretical understanding of the intrinsic mechanism of the activity enhancement is still lacking. Herein, the geometric structures, optical absorption, electronic properties, and CO2 reduction reaction processes of 2D/2D BP/g-C3N4 composite models are investigated using density functional theory calculations. The composite model consists of a monolayer of BP and a tri-s-triazine-based monolayer of g-C3N4. Based on the calculated work function, it is inferred that electrons transfer from g-C3N4 to BP owing to the higher Fermi level of g-C3N4 compared with that of BP. Furthermore, the charge density difference suggests the formation of a built-in electric field at the interface, which is conducive to the separation of photogenerated electron-hole pairs. The optical absorption coefficient demonstrates that the light absorption of the composite is significantly higher than that of its singlecomponent counterpart. Integrated analysis of the band edge potential and interfacial electronic interaction indicates that the migration of photogenerated charge carriers in the BP/g-C3N4 hybrid follows the S-scheme photocatalytic mechanism. Under visible-light irradiation, the photogenerated electrons on BP recombine with the photogenerated holes on g-C3N4, leaving photogenerated electrons and holes in the conduction band of g-C3N4 and the valence band of BP, respectively. Compared with pristine g-C3N4, this S-scheme heterojunction allows efficient separation of photogenerated charge carriers while effectively preserving strong redox abilities. Additionally, the possible reaction path for CO2 reduction on g-C3N4 and BP/g-C3N4 is discussed by computing the free energy of each step. It was found that CO2 reduction on the composite occurs most readily on the g-C3N4 side. The reaction path on the composite is different from that on g-C3N4. The heterojunction reduces the maximum energy barrier for CO2 reduction from 1.48 to 1.22 eV, following the optimal reaction path. Consequently, the BP/g-C3N4 heterojunction is theoretically proven to be an excellent CO2 reduction photocatalyst. This work is helpful for understanding the effect of BP modification on the photocatalytic activity of g-C3N4. It also provides a theoretical basis for the design of other high-performance CO2 reduction photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 37, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2010027, "DOI": "10.3866/PKU.WHXB202010027", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202010027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614248900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Z; He, L; Zhu, CC; Qian, YC; Wen, LP; Jiang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhen; He, Li; Zhu, Congcong; Qian, Yongchao; Wen, Liping; Jiang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved osmotic energy conversion in heterogeneous membrane boosted by three-dimensional hydrogel interface", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emerging heterogeneous membranes show unprecedented superiority in harvesting the osmotic energy between ionic solutions of different salinity. However, the power densities are limited by the low interfacial transport efficiency caused by a mismatch of pore alignment and insufficient coupling between channels of different dimensions. Here we demonstrate the use of three-dimensional (3D) gel interface to achieve high-performance osmotic energy conversion through hybridizing polyelectrolyte hydrogel and aramid nullofiber membrane. The ionic diode effect of the heterogeneous membrane facilitates one-way ion diffusion, and the gel layer provides a charged 3D transport network, greatly enhancing the interfacial transport efficiency. When used for harvesting the osmotic energy from the mixing of sea and river water, the heterogeneous membrane outperforms the state-of-the-art membranes, to the best of our knowledge, with power densities of 5.06Wm(-2). The diversity of the polyelectrolyte and gel makes our strategy a potentially universal approach for osmotic energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 875, "DOI": "10.1038/s41467-020-14674-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14674-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514928000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vogt, C; Groeneveld, E; Kamsma, G; Nachtegaal, M; Lu, L; Kiely, CJ; Berben, PH; Meirer, F; Weckhuysen, BM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vogt, Charlotte; Groeneveld, Esther; Kamsma, Gerda; Nachtegaal, Maarten; Lu, Li; Kiely, Christopher J.; Berben, Peter H.; Meirer, Florian; Weckhuysen, Bert M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unravelling structure sensitivity in CO2 hydrogenation over nickel", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous efforts in the field of materials science have allowed us to generate smaller and smaller metal nulloparticles, creating new opportunities to understand catalytic properties that depend on the metal particle size. Structure sensitivity is the phenomenon where not all surface atoms in a supported metal catalyst have the same activity. Understanding structure sensitivity can assist in the rational design of catalysts, allowing control over mechanisms, activity and selectivity, and thus even the viability of a catalytic reaction. Here, using a unique set of well-defined silica-supported Ni nulloclusters (1-7 nm) and advanced characterization methods, we prove how structure sensitivity influences the mechanism of catalytic CO2 reduction, the nature of which has been long debated. These findings bring fundamental new understanding of CO2 hydrogenation over Ni and allow us to control both activity and selectivity, which can be a means for CO2 emission abatement through its valorization as a low-or even negative-cost feedstock on a low-cost transition-metal catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 127, "End Page": 134, "Article Number": null, "DOI": "10.1038/s41929-017-0016-y", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0016-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428621500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, HF; Xu, MY; Shu, MR; An, J; Ding, WB; Liu, XY; Wang, SY; Zhao, C; Yu, HY; Wang, H; Wang, C; Fu, XP; Pan, XX; Xie, GM; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Hongfa; Xu, Minyi; Shu, Mingrui; An, Jie; Ding, Wenbo; Liu, Xiangyu; Wang, Siyuan; Zhao, Cong; Yu, Hongyong; Wang, Hao; Wang, Chuan; Fu, Xianping; Pan, Xinxiang; Xie, Guangming; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Underwater wireless communication via TENG-generated Maxwell's displacement current", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Underwater communication, despite constant development, still remains a challenging technology. Here, authors report an underwater wireless communication approach based on the triboelectric nullogenerator, which provides a self-powered communication system in complex underwater environments. Underwater communication is a critical and challenging issue, on account of the complex underwater environment. This study introduces an underwater wireless communication approach via Maxwell's displacement current generated by a triboelectric nullogenerator. Underwater electric field can be generated through a wire connected to a triboelectric nullogenerator, while current signal can be inducted in an underwater receiver certain distance away. The received current signals are basically immune to disturbances from salinity, turbidity and submerged obstacles. Even after passing through a 100 m long spiral water pipe, the electric signals are not distorted in waveform. By modulating and demodulating the current signals generated by a sound driven triboelectric nullogenerator, texts and images can be transmitted in a water tank at 16 bits/s. An underwater lighting system is operated by the triboelectric nullogenerator-based voice-activated controller wirelessly. This triboelectric nullogenerator-based approach can form the basis for an alternative wireless communication in complex underwater environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3325, "DOI": "10.1038/s41467-022-31042-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31042-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Song, H; Yuan, LY; Li, ZJ; Zhang, YJ; Gibson, JK; Zheng, LR; Chai, ZF; Shi, WQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lin; Song, Huan; Yuan, Liyong; Li, Zijie; Zhang, Yujuan; Gibson, John K.; Zheng, Lirong; Chai, Zhifang; Shi, Weiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient U(VI) Reduction and Sequestration by Ti2CTx MXene", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although reduction of highly mobile U(VI) to less soluble U(IV) has been long considered an effective approach to in situ environmental remediation of uranium, candidate reducing agents are largely limited to Fe-based materials and microbials. The importance of titanium-containing compounds in natural uranium ore deposits suggests a role for titanium in uranium migration. Herein, for the first time, a two-dimensional transition metal carbide, Ti2CTx, is shown to efficiently remove uranium via a sorption reduction strategy. Batch experiments demonstrate that TiC2Tx exhibits excellent U(VI) removal over a wide pH range, with an uptake capacity of 470 mg g(-1) at pH 3.0. The mechanism for U(VI) to U(IV) reduction by Ti2CTx was deciphered by X-ray absorption spectroscopy and diffraction and photoelectron spectroscopy. The reduced U(IV) species at low pH is identified as mononuclear with bidendate binding to the MXene substrate. At near-neutral pH, nulloparticles of the UO2+x phase adsorb to the substrate with some Ti2CTx transformed to amorphous TiO2. A subsequent in-depth study suggests Ti2CTx materials may be potential candidates for permeable reactive barriers in the treatment of wastewaters from uranium mining. This work highlights reduction-induced immobilization of U(VI) by Ti2CTx MXene including a pH-dependent reduction mechanism that might promote applications of titanium-based materials in the elimination of other oxidized contaminullts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2018, "Volume": 52, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10748, "End Page": 10756, "Article Number": null, "DOI": "10.1021/acs.est.8b03711", "DOI Link": "http://dx.doi.org/10.1021/acs.est.8b03711", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445441000057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yaffe, O; Guo, YS; Tan, LZ; Egger, DA; Hull, T; Stoumpos, CC; Zheng, F; Heinz, TF; Kronik, L; Kanatzidis, MG; Owen, JS; Rappe, AM; Pimenta, MA; Brus, LE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z.; Egger, David A.; Hull, Trevor; Stoumpos, Constantinos C.; Zheng, Fan; Heinz, Tony F.; Kronik, Leeor; Kanatzidis, Mercouri G.; Owen, Jonathan S.; Rappe, Andrew M.; Pimenta, Marcos A.; Brus, Louis E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Local Polar Fluctuations in Lead Halide Perovskite Crystals", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid lead-halide perovskites have emerged as an excellent class of photovoltaic materials. Recent reports suggest that the organic molecular cation is responsible for local polar fluctuations that inhibit carrier recombination. We combine low-frequency Raman scattering with first-principles molecular dynamics (MD) to study the fundamental nature of these local polar fluctuations. Our observations of a strong central peak in the cubic phase of both hybrid (CH3NH3PbBr3) and all-inorganic (CsPbBr3) leadhalide perovskites show that anharmonic, local polar fluctuations are intrinsic to the general lead-halide perovskite structure, and not unique to the dipolar organic cation. MD simulations indicate that head-tohead Cs motion coupled to Br face expansion, occurring on a few hundred femtosecond time scale, drives the local polar fluctuations in CsPbBr3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 596, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2017, "Volume": 118, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136001, "DOI": "10.1103/PhysRevLett.118.136001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.136001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397808400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Riegger, LM; Schlem, R; Sann, J; Zeier, WG; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Riegger, Luise M.; Schlem, Roman; Sann, Joachim; Zeier, Wolfgang G.; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium-Metal Anode Instability of the Superionic Halide Solid Electrolytes and the Implications for Solid-State Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to high ionic conductivity and good oxidation stability, halide-based solid electrolytes regain interest for application in solid-state batteries. While stability at the cathode interface seems to be given, the stability against the lithium metal anode has not been explored yet. Herein, the formation of a reaction layer between Li3InCl6 (Li3YCl6) and lithium is studied by sputter deposition of lithium metal and subsequent in situ X-ray photoelectron spectroscopy as well as by impedance spectroscopy. The interface is thermodynamically unstable and results in a continuously growing interphase resistance. Additionally, the interface between Li3InCl6 and Li6PS5Cl is characterized by impedance spectroscopy to discern whether a combined use as cathode electrolyte and separator electrolyte, respectively, might enable long-term stable and low impedance operation. In fact, oxidation stable halide-based lithium superionic conductors cannot be used against Li, but may be promising candidates as cathode electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 60, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6718, "End Page": 6723, "Article Number": null, "DOI": "10.1002/anie.202015238", "DOI Link": "http://dx.doi.org/10.1002/anie.202015238", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613396100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Verdaguer-Casadevall, A; Li, CW; Johansson, TP; Scott, SB; McKeown, JT; Kumar, M; Stephens, IEL; Kanull, MW; Chorkendorff, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P.; Scott, Soren B.; McKeown, Joseph T.; Kumar, Mukul; Stephens, Ifan E. L.; Kanull, Matthew W.; Chorkendorff, Ib", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO electroreduction activity on oxide-derived Cu (OD-Cu) was found to correlate with metastable surface features that bind CO strongly. OD-Cu electrodes prepared by H-2 reduction of Cu2O precursors reduce CO to acetate and ethanol with nearly 50% Faradaic efficiency at moderate overpotential. Temperature-programmed desorption of CO on OD-Cu revealed the presence of surface sites with strong CO binding that are distinct from the terraces and stepped sites found on polycrystalline Cu foil. After annealing at 350 degrees C, the surface-area corrected current density for CO reduction is 44-fold lower and the Faradaic efficiency is less than 5%. These changes are accompanied by a reduction in the proportion of strong CO binding sites. We propose that the active sites for CO reduction on OD-Cu surfaces are strong CO binding sites that are supported by grain boundaries. Uncovering these sites is a first step toward understanding the surface chemistry necessary for efficient CO electroreduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 754, "Times Cited, All Databases": 834, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2015, "Volume": 137, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9808, "End Page": 9811, "Article Number": null, "DOI": "10.1021/jacs.5b06227", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b06227", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359613300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, PS; Bi, JH; Liu, JY; Zhu, QG; Chen, CJ; Sun, XF; Zhang, JL; Han, BX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Pengsong; Bi, Jiahui; Liu, Jiyuan; Zhu, Qinggong; Chen, Chunjun; Sun, Xiaofu; Zhang, Jianling; Han, Buxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ dual doping for constructing efficient CO2-to-methanol electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Production of methanol from CO2 electroreduction is attractive but achieving high selectivity, current density and stability simultaneously remains a grand challenge. Here, the authors present an in situ dual doping strategy to construct efficient CO2-to-methanol electrocatalysts. Methanol is a highly desirable product of CO2 electroreduction due to its wide array of industrial applications. However, the development of CO2-to-methanol electrocatalysts with high performance is still challenging. Here we report an operationally simple in situ dual doping strategy to construct efficient CO2-to-methanol electrocatalysts. In particular, when using Ag,S-Cu2O/Cu as electrocatalyst, the methanol Faradaic efficiency (FE) could reach 67.4% with a current density as high as 122.7 mA cm(-2) in an H-type cell using 1-butyl-3-methylimidazolium tetrafluoroborate/H2O as the electrolyte, while the current density was below 50 mA cm(-2) when the FE was greater than 50% over the reported catalysts. Experimental and theoretical studies suggest that the anion S can effectively adjust the electronic structure and morphology of the catalysts in favor of the methanol pathway, whereas the cation Ag suppresses the hydrogen evolution reaction. Their synergistic interactions with host material enhance the selectivity and current density for methanol formation. This work opens a way for designing efficient catalysts for CO2 electroreduction to methanol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1965, "DOI": "10.1038/s41467-022-29698-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29698-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000782204100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QC; Meng, JK; Yue, XY; Qiu, QQ; Song, Y; Wu, XJ; Fu, ZW; Xia, YY; Shadike, Z; Wu, JP; Yang, XQ; Zhou, YN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qin-Chao; Meng, Jing-Ke; Yue, Xin-Yang; Qiu, Qi-Qi; Song, Yun; Wu, Xiao-Jin; Fu, Zheng-Wen; Xia, Yong-Yao; Shadike, Zulipiya; Wu, Jinpeng; Yang, Xiao-Qing; Zhou, Yong-Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning P2-Structured Cathode Material by Na-Site Mg Substitution for Na-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most P2-type layered oxides suffer from multiple voltage plateaus, due to Na+/vacancy-order superstructures caused by strong interplay between Na-Na electrostatic interactions and charge ordering in the transition metal layers. Here, Mg ions are successfully introduced into Na sites in addition to the conventional transition metal sites in P2-type Na-0.7[Mn0.6Ni0.4]O-2 as new cathode materials for sodium-ion batteries. Mg ions in the Na layer serve as pillars to stabilize the layered structure, especially for high-voltage charging, meanwhile Mg ions in the transition metal layer can destroy charge ordering. More importantly, Mg ion occupation in both sodium and transition metal layers will be able to create Na-O-Mg and Mg-O-Mg configurations in layered structures, resulting in ionic O 2p character, which allocates these O 2p states on top of those interacting with transition metals in the O-valence band, thus promoting reversible oxygen redox. This innovative design contributes smooth voltage profiles and high structural stability. Na0.7Mg0.05[Mn0.6Ni0.2Mg0.15]O-2 exhibits superior electrochemical performance, especially good capacity retention at high current rate under a high cutoff voltage (4.2 V). A new P2 phase is formed after charge, rather than an O2 phase for the unsubstituted material. Besides, multiple intermediate phases are observed during high-rate charging. Na-ion transport kinetics are mainly affected by elemental-related redox couples and structural reorganization. These findings will open new opportunities for designing and optimizing layer-structured cathodes for sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 141, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 840, "End Page": 848, "Article Number": null, "DOI": "10.1021/jacs.8b08638", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b08638", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456350300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Warnull, J; Rodríguez-Jiménez, S; Leung, JJ; Kalathil, S; Andrei, V; Domen, K; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qian; Warnull, Julien; Rodriguez-Jimenez, Santiago; Leung, Jane J.; Kalathil, Shafeer; Andrei, Virgil; Domen, Kazunari; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecularly engineered photocatalyst sheet for scalable solar formate production from carbon dioxide and water", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting solar energy to convert CO(2)into chemical fuels is a promising technology to curtail the growing atmospheric CO(2)levels and alleviate the global dependence on fossil fuels; however, the assembly of efficient and robust systems for the selective photoconversion of CO(2)without sacrificial reagents and external bias remains a challenge. Here we present a photocatalyst sheet that converts CO(2)and H2O into formate and O(2)as a potentially scalable technology for CO(2)utilization. This technology integrates lanthanum- and rhodium-doped SrTiO3(SrTiO3:La,Rh) and molybdenum-doped BiVO4(BiVO4:Mo) light absorbers modified by phosphonated Co(ii) bis(terpyridine) and RuO(2)catalysts onto a gold layer. The monolithic device provides a solar-to-formate conversion efficiency of 0.08 +/- 0.01% with a selectivity for formate of 97 +/- 3%. As the device operates wirelessly and uses water as an electron donor, it offers a versatile strategy toward scalable and sustainable CO(2)reduction using molecular-based hybrid photocatalysts. Selective photocatalytic conversion of CO(2)into fuels without using sacrificial reagents and external bias has proved difficult. Addressing these challenges, Wang and colleagues fabricate wireless photocatalyst sheets comprising a molecular cobalt catalyst and metal oxide semiconductors that convert CO(2)and H2O into formate and O-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 703, "End Page": 710, "Article Number": null, "DOI": "10.1038/s41560-020-0678-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0678-6", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000562777400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Castellanos-Gomez, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Castellanos-Gomez, Andres", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus: Narrow Gap, Wide Applications", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent isolation of atomically thin black phosphorus by mechanical exfoliation of bulk layered crystals has triggered an unprecedented interest, even higher than that raised by the first works on graphene and other two-dimensionals, in the nulloscience and nullotechnology community. In this Perspective, we critically analyze the reasons behind the surge of experimental and theoretical works on this novel two-dimensional material. We believe that the fact that black phosphorus band gap value spans over a wide range of the electromagnetic spectrum (interesting for thermal imaging, thermoelectrics, fiber optics communication, photovoltaics, etc.) that was not covered by any other two-dimensional material isolated to date, its high carrier mobility, its ambipolar field-effect, and its rather unusual in-plane anisotropy drew the attention of the scientific community toward this two-dimensional material. Here, we also review the current advances, the future directions and the challenges in this young research field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 609, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2015, "Volume": 6, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4280, "End Page": 4291, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b01686", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b01686", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364435800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, N; Ou, PF; Hung, SF; Huang, JE; Ozden, A; Abed, J; Grigioni, I; Chen, CR; Miao, RK; Yan, Y; Zhang, JQ; Wang, ZY; Dorakhan, R; Badreldin, A; Abdel-Wahab, A; Sinton, D; Liu, YC; Liang, HY; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ning; Ou, Pengfei; Hung, Sung-Fu; Huang, Jianull Erick; Ozden, Adnull; Abed, Jehad; Grigioni, Ivan; Chen, Clark; Miao, Rui Kai; Yan, Yu; Zhang, Jinqiang; Wang, Ziyun; Dorakhan, Roham; Badreldin, Ahmed; Abdel-Wahab, Ahmed; Sinton, David; Liu, Yongchang; Liang, Hongyan; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong-Proton-Adsorption Co-Based Electrocatalysts Achieve Active and Stable Neutral Seawater Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct electrolysis of pH-neutral seawater to generate hydrogen is an attractive approach for storing renewable energy. However, due to the anodic competition between the chlorine evolution and the oxygen evolution reaction (OER), direct seawater splitting suffers from a low current density and limited operating stability. Exploration of catalysts enabling an OER overpotential below the hypochlorite formation overpotential (approximate to 490 mV) is critical to suppress the chloride evolution and facilitate seawater splitting. Here, a proton-adsorption-promoting strategy to increase the OER rate is reported, resulting in a promoted and more stable neutral seawater splitting. The best catalysts herein are strong-proton-adsorption (SPA) materials such as palladium-doped cobalt oxide (Co3-xPdxO4) catalysts. These achieve an OER overpotential of 370 mV at 10 mA cm(-2) in pH-neutral simulated seawater, outperforming Co3O4 by a margin of 70 mV. Co3-xPdxO4 catalysts provide stable catalytic performance for 450 h at 200 mA cm(-2) and 20 h at 1 A cm(-2) in neutral seawater. Experimental studies and theoretical calculations suggest that the incorporation of SPA cations accelerates the rate-determining water dissociation step in neutral OER pathway, and control studies rule out the provision of additional OER sites as a main factor herein.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202210057", "DOI Link": "http://dx.doi.org/10.1002/adma.202210057", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950303300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, BY; Montgomery, M; Chamberlain, MD; Ogawa, S; Korolj, A; Pahnke, A; Wells, LA; Massé, S; Kim, J; Reis, L; Momen, A; Nunes, SS; Wheeler, AR; nullthakumar, K; Keller, G; Sefton, MV; Radisic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Boyang; Montgomery, Miles; Chamberlain, M. Dean; Ogawa, Shinichiro; Korolj, Anastasia; Pahnke, Aric; Wells, Laura A.; Masse, Stephane; Kim, Jihye; Reis, Lewis; Momen, Abdul; Nunes, Sara S.; Wheeler, Aaron R.; nullthakumar, Kumaraswamy; Keller, Gordon; Sefton, Michael V.; Radisic, Milica", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable scaffold with built-in vasculature for organ-on-a-chip engineering and direct surgical anastomosis", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the fabrication of a scaffold (hereafter referred to as AngioChip) that supports the assembly of parenchymal cells on a mechanically tunable matrix surrounding a perfusable, branched, three-dimensional microchannel network coated with endothelial cells. The design of AngioChip decouples the material choices for the engineered vessel network and for cell seeding in the parenchyma, enabling extensive remodelling while maintaining an open-vessel lumen. The incorporation of nullopores and micro-holes in the vessel walls enhances permeability, and permits intercellular crosstalk and extravasation of monocytes and endothelial cells on biomolecular stimulation. We also show that vascularized hepatic tissues and cardiac tissues engineered by using AngioChips process clinically relevant drugs delivered through the vasculature, and that millimetre-thick cardiac tissues can be engineered in a scalable manner. Moreover, we demonstrate that AngioChip cardiac tissues implanted with direct surgical anastomosis to the femoral vessels of rat hindlimbs establish immediate blood perfusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 669, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4570", "DOI Link": "http://dx.doi.org/10.1038/NMAT4570", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376528000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YH; Shi, QR; Shan, WT; Li, X; Kropf, AJ; Wegener, EC; Wright, J; Karakalos, S; Su, D; Cullen, DA; Wang, GF; Myers, DJ; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yanghua; Shi, Qiurong; Shan, Weitao; Li, Xing; Kropf, A. Jeremy; Wegener, Evan C.; Wright, Joshua; Karakalos, Stavros; Su, Dong; Cullen, David A.; Wang, Guofeng; Myers, Deborah J.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamically Unveiling Metal-Nitrogen Coordination during Thermal Activation to Design High-Efficient Atomically Dispersed CoN4 Active Sites", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We elucidate the structural evolution of CoN4 sites during thermal activation by developing a zeolitic imidazolate framework (ZIF)-8-derived carbon host as an ideal model for Co2+ ion adsorption. Subsequent in situ X-ray absorption spectroscopy analysis can dynamically track the conversion from inactive Co-OH and Co-O species into active CoN4 sites. The critical transition occurs at 700 degrees C and becomes optimal at 900 degrees C, generating the highest intrinsic activity and four-electron selectivity for the oxygen reduction reaction (ORR). DFT calculations elucidate that the ORR is kinetically favored by the thermal-induced compressive strain of Co-N bonds in CoN4 active sites formed at 900 degrees C. Further, we developed a two-step (i.e., Co ion doping and adsorption) Co-N-C catalyst with increased CoN4 site density and optimized porosity for mass transport, and demonstrated its outstanding fuel cell performance and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2021, "Volume": 60, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9516, "End Page": 9526, "Article Number": null, "DOI": "10.1002/anie.202017288", "DOI Link": "http://dx.doi.org/10.1002/anie.202017288", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626964500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kitano, M; Kanbara, S; Inoue, Y; Kuganathan, N; Sushko, PV; Yokoyama, T; Hara, M; Hosono, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kitano, Masaaki; Kanbara, Shinji; Inoue, Yasunori; Kuganathan, Navaratnarajah; Sushko, Peter V.; Yokoyama, Toshiharu; Hara, Michikazu; Hosono, Hideo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel approaches to efficient ammonia synthesis at an ambient pressure are actively sought out so as to reduce the cost of ammonia production and to allow for compact production facilities. It is accepted that the key is the development of a high-performance catalyst that significantly enhances dissociation of the nitrogen-nitrogen triple bond, which is generally considered a rate-determining step. Here we examine kinetics of nitrogen and hydrogen isotope exchange and hydrogen adsorption/desorption reactions for a recently discovered efficient catalyst for ammonia synthesis-ruthenium-loaded 12CaO center dot 7Al(2)O(3) electride (Ru/C12A7:e(-))-and find that the rate controlling step of ammonia synthesis over Ru/C12A7:e(-) is not dissociation of the nitrogen-nitrogen triple bond but the subsequent formation of N-H-n species. A mechanism of ammonia synthesis involving reversible storage and release of hydrogen atoms on the Ru/C12A7:e(-) surface is proposed on the basis of observed hydrogen absorption/desorption kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 550, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6731, "DOI": "10.1038/ncomms7731", "DOI Link": "http://dx.doi.org/10.1038/ncomms7731", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353045100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, ZC; Huang, BL; Wang, X; Lu, L; Lu, QY; Sun, MZ; Wu, T; Ma, TF; Xu, J; Xu, YS; Wang, S; Du, YP; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Zhichao; Huang, Bolong; Wang, Xia; Lu, Lu; Lu, Qiuyang; Sun, Mingzi; Wu, Tong; Ma, Tengfei; Xu, Jun; Xu, Yueshan; Wang, Shuao; Du, Yaping; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multimodal Luminescent Yb3+/Er3+/Bi3+-Doped Perovskite Single Crystals for X-ray Detection and Anti-Counterfeiting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anti-counterfeiting techniques have become a global topic since they is correlated to the information and data safety, in which multimodal luminescence is one of the most desirable candidates for practical applications. However, it is a long-standing challenge to actualize robust multimodal luminescence with high thermal stability and humid resistance. Conventionally, the multimodal luminescence is usually achieved by the combination of upconversion and downshifting luminescence, which only responds to the electromagnetic waves in a limited range. Herein, the Yb3+/Er3+/Bi(3+)co-doped Cs(2)Ag(0.6)Na(0.4)InCl(6)perovskite material is reported as an efficient multimodal luminescence material. Beyond the excitation of ultraviolet light and near-infrared laser (980 nm), this work extends multimodal luminescence to the excitation of X-ray. Besides the flexible excitation sources, this material also shows the exceptional luminescence performance, in which the X-ray detection limit reaches the level of nGy s(-1), indicating a great potential for further application as a colorless pigment in the anti-counterfeiting field. More importantly, the obtained double perovskite features high stability against both humidity and temperature up to 400 degrees C. This integrated multifunctional luminescent material provides a new directional solution for the development of multifunctional optical materials and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2020, "Volume": 32, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004506, "DOI": "10.1002/adma.202004506", "DOI Link": "http://dx.doi.org/10.1002/adma.202004506", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000570221100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, ZL; Da, YM; Wang, M; Dou, XY; Cui, XH; Chen, J; Jiang, R; Xi, SB; Cui, BH; Luo, YN; Yang, HT; Long, Y; Xiao, YK; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Zhangliu; Da, Yumin; Wang, Meng; Dou, Xinyu; Cui, Xinhang; Chen, Jie; Jiang, Rui; Xi, Shibo; Cui, Baihua; Luo, Yani; Yang, Haotian; Long, Yu; Xiao, Yukun; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective photoelectrochemical oxidation of glucose to glucaric acid by single atom Pt decorated defective TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical reaction is emerging as a powerful approach for biomass conversion. However, it has been rarely explored for glucose conversion into value-added chemicals. Here we develop a photoelectrochemical approach for selective oxidation of glucose to high value-added glucaric acid by using single-atom Pt anchored on defective TiO2 nullorod arrays as photoanode. The defective structure induced by the oxygen vacancies can modulate the charge carrier dynamics and band structure, simultaneously. With optimized oxygen vacancies, the defective TiO2 photoanode shows greatly improved charge separation and significantly enhanced selectivity and yield of C-6 products. By decorating single-atom Pt on the defective TiO2 photoanode, selective oxidation of glucose to glucaric acid can be achieved. In this work, defective TiO2 with single-atom Pt achieves a photocurrent density of 1.91mAcm(-2) for glucose oxidation at 0.6V versus reversible hydrogen electrode, leading to an 84.3 % yield of glucaric acid under simulated sunlight irradiation. Photoelectrochemical oxidation provides a promising strategy for glucaric acid production. Here, selective oxidation of glucose to glucaric acid is realized on the photoanode of defective TiO2 decorated with single-atom Pt via a photoelectrochemical strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1038/s41467-023-35875-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35875-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928461700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, LM; Majumdar, K; Liu, H; Du, YC; Wu, H; Hatzistergos, M; Hung, PY; Tieckelmann, R; Tsai, W; Hobbs, C; Ye, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Lingming; Majumdar, Kausik; Liu, Han; Du, Yuchen; Wu, Heng; Hatzistergos, Michael; Hung, P. Y.; Tieckelmann, Robert; Tsai, Wilman; Hobbs, Chris; Ye, Peide D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chloride Molecular Doping Technique on 2D Materials: WS2 and MoS2", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-resistivity metal-semiconductor (M-S) contact is one of the urgent challenges in the research of 2D transition metal dichalcogenides (TMDs). Here, we report a chloride molecular doping technique which greatly reduces the contact resistance (R-c) in the few-layer WS2 and MoS2. After doping, the R-c of WS2 and MoS2 have been decreased to 0.7 k Omega center dot mu m and 0.5 k Omega center dot mu m, respectively. The significant reduction of the R-c is attributed to the achieved high electron-doping density, thus a significant reduction of Schottky barrier width. As a proof-of-concept, high-performance few-layer WS2 field-effect transistors (FETs) are demonstrated, exhibiting a high drain current of 380 mu A/mu m, an on/off ratio of 4 x 10(6), and a peak field-effect mobility of 60 cm(2)/(V.s). This doping technique provides a highly viable route to diminish the Rc in TMDs, paving the way for high-performance 2D nulloelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 724, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6275, "End Page": 6280, "Article Number": null, "DOI": "10.1021/nl502603d", "DOI Link": "http://dx.doi.org/10.1021/nl502603d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345723800039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JJ; Jiang, YY; Hou, S; Upputuri, PK; Wu, D; Li, JC; Wang, P; Zhen, X; Pramanik, M; Pu, KY; Duan, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jiajing; Jiang, Yuyan; Hou, Shuai; Upputuri, Paul Kumar; Wu, Di; Li, Jingchao; Wang, Peng; Zhen, Xu; Pramanik, Manojit; Pu, Kanyi; Duan, Hongwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compact Plasmonic Blackbody for Cancer Theranosis in the Near-Infrared II Window", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have developed a class of blackbody materials, i.e., hyperbranched Au plasmonic blackbodies (AuPBs), of compact sizes (<50 nm). The AuPBs were prepared in a seedless and surfactant-free approach based on the use of mussel-inspired dopamine. Strong intraparticle plasmonic coupling among branches in close proximity leads to intense and uniform broadband absorption across 400-1350 nm. The blackbody absorption imparts the compact AuPB with a superior photothermal efficiency of >80% and closely matched photothermal activity in the first near infrared (NIR-I) and the second near-infrared (NIR-II) spectral windows, making it a rare broadband theranostic probe for integrated photoacoustic imaging and photothermal therapy (PTT). Our comparative study, using the same probe, has demonstrated that the improved PTT outcome of NIR-II over NIR-I primarily results from its higher maximum permission exposure (MPE) rather than the deeper tissue penetration favored by longer wavelengths. The compact plasmonic broadband nulloabsorbers with tailored surface properties hold potential for a wide spectrum of light-mediated applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 12, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2643, "End Page": 2651, "Article Number": null, "DOI": "10.1021/acsnullo.7b08725", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b08725", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428972600058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, BW; Sheng, T; Wang, YX; Chou, SL; Davey, K; Dou, SX; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bin-Wei; Sheng, Tian; Wang, Yun-Xiao; Chou, Shulei; Davey, Kenneth; Dou, Shi-Xue; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-Life Room-Temperature Sodium-Sulfur Batteries by Virtue of Transition-Metal-nullocluster-Sulfur Interactions", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Room-temperature sodium-sulfur (RT-Na/S) batteries hold significant promise for large-scale application because of low cost of both sodium and sulfur. However, the dissolution of polysulfides into the electrolyte limits practical application. Now, the design and testing of a new class of sulfur hosts as transition-metal (Fe, Cu, and Ni) nulloclusters (ca.1.2 nm) wreathed on hollow carbon nullospheres (S@M-HC)for RT-Na/S batteries is reported. A chemical couple between the metal nulloclusters and sulfur is hypothesized to assist in immobilization of sulfur and to enhance conductivity and activity. S@Fe-HC exhibited an unprecedented reversible capacity of 394 mAhg(-1) despite 1000 cycles at 100 mAg(-1), together with a rate capability of 220 mAhg(-1) at a high current density of 5 Ag-1. DFT calculations underscore that these metal nulloclusters serve as electrocatalysts to rapidly reduce Na2S4 into short-chain sulfides and thereby obviate the shuttle effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2019, "Volume": 58, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1484, "End Page": 1488, "Article Number": null, "DOI": "10.1002/anie.201811080", "DOI Link": "http://dx.doi.org/10.1002/anie.201811080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458826100039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, C; Wang, T; Wang, LL; Hu, ZL; Cui, ZL; Li, JD; Dong, SM; Zhou, XH; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chen; Wang, Tao; Wang, Longlong; Hu, Zhenglin; Cui, Zili; Li, Jiedong; Dong, Shanmu; Zhou, Xinhong; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Differentiated Lithium Salt Design for Multilayered PEO Electrolyte Enables a High-Voltage Solid-State Lithium Metal Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low ionic conductivity at room temperature and limited electrochemical window of poly(ethylene oxide) (PEO) are the bottlenecks restricting its further application in high-energy density lithium metal battery. Herein, a differentiated salt designed multilayered PEO-based solid polymer electrolyte (DSM-SPE) is exploited to achieve excellent electrochemical performance toward both the high-voltage LiCoO2 cathode and the lithium metal anode. The LiCoO2/Li metal battery with DSM-SPE displays a capacity retention of 83.3% after 100 cycles at 60 degrees C with challenging voltage range of 2.5 to 4.3 V, which is the best cycling performance for high-voltage (>= 4.3 V) LiCoO2/Li metal battery with PEO-based electrolytes up to now. Moreover, the Li/Li symmetrical cells present stable and low polarization plating/stripping behavior (less than 80 mV over 600 h) at current density of 0.25 mA cm(-2) (0.25 mAh cm(-2)). Even under a high-area capacity of 2 mAh cm(-2), the profiles still maintain stable. The pouch cell with DSM-SPE exhibits no volume expansion, voltage decline, ignition or explosion after being impaled and cut at a fully charged state, proving the excellent safety characteristic of the DSM-SPE-based lithium metal battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2019, "Volume": 6, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901036, "DOI": "10.1002/advs.201901036", "DOI Link": "http://dx.doi.org/10.1002/advs.201901036", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487402700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, WX; Fu, JM; Hu, HB; Ho, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Wenxiang; Fu, Jimin; Hu, Haibo; Ho, Derek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interlayer Structure Engineering of MXene-Based Capacitor-Type Electrode for Hybrid Micro-Supercapacitor toward Battery-Level Energy Density", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Micro-supercapacitors are notorious for their low energy densities compared to micro-batteries. While MXenes have been identified as promising capacitor-type electrode materials for alternative zinc-ion hybrid micro-supercapacitors (ZHMSCs) with higher energy density, their tightly spaced layered structure renders multivalent zinc-ions with large radii intercalation inefficient. Herein, through insertion of 1D core-shell conductive BC@PPy nullofibers between MXene nullosheets, an interlayer structure engineering technique for MXene/BC@PPy capacitor-type electrodes towards ZHMSCs is presented. Owing to simultaneously achieving two objectives: (i) widening the interlayer space and (ii) providing conductive connections between the loose MXene layers, enabled by the conductive BC@PPy nullospacer, the approach effectively enhances both ion and electron transport within the layered MXene structure, significantly increasing the areal capacitance of the MXene/BC@PPy film electrode to 388 mF cm(-2), which is a 10-fold improvement from the pure MXene film electrode. Pairing with CNTs/MnO2 battery-type electrodes, the obtained ZHMSCs exhibit an areal energy density up to 145.4 mu Wh cm(-2) with an outstanding 95.8% capacity retention after 25000 cycles, which is the highest among recently reported MXene-based MSCs and approaches the level of micro-batteries. The interlayer structure engineering demonstrated in the MXene-based capacitor-type electrode provides a rational means to achieve battery-levelenergy density in the ZHMSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100775, "DOI": "10.1002/advs.202100775", "DOI Link": "http://dx.doi.org/10.1002/advs.202100775", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662210600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, JY; Zheng, QZ; Lou, YY; Zhao, KM; Hu, SN; Li, G; Akdim, O; Huang, XY; Sun, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Jia-Yi; Zheng, Qi-Zheng; Lou, Yao-Yin; Zhao, Kuang-Min; Hu, Sheng-null; Li, Guang; Akdim, Ouardia; Huang, Xiao-Yang; Sun, Shi-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ampere-level current density ammonia electrochemical synthesis using CuCo nullosheets simulating nitrite reductase bifunctional nature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of electrocatalysts capable of efficient reduction of nitrate (NO3-) to ammonia (NH3) is drawing increasing interest for the sake of low carbon emission and environmental protection. Herein, we present a CuCo bimetallic catalyst able to imitate the bifunctional nature of copper-type nitrite reductase, which could easily remove NO2- via the collaboration of two active centers. Indeed, Co acts as an electron/proton donating center, while Cu facilitates NOx- adsorption/association. The bio-inspired CuCo nullosheet electrocatalyst delivers a 1001% Faradaic efficiency at an ampere-level current density of 1035mAcm(-2) at -0.2V vs. Reversible Hydrogen Electrode. The NH3 production rate reaches a high activity of 4.8mmolcm(-2) h(-1) (960mmol g(cat)(-1) h(-1)). A mechanistic study, using electrochemical in situ Fourier transform infrared spectroscopy and shell-isolated nulloparticle enhanced Raman spectroscopy, reveals a strong synergy between Cu and Co, with Co sites promoting the hydrogenation of NO3- to NH3 via adsorbed *H species. The well-modulated coverage of adsorbed *H and *NO3 led simultaneously to high NH3 selectivity and yield.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7899, "DOI": "10.1038/s41467-022-35533-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35533-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972743600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HT; Zhang, BW; Bulin, CK; Li, RH; Xing, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Huitao; Zhang, Bangwen; Bulin, Chaoke; Li, Ruihong; Xing, Ruiguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficient Synthesis of Graphene Oxide Based on Improved Hummers Method", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As an important precursor and derivate of graphene, graphene oxide (GO) has received wide attention in recent years. However, the synthesis of GO in an economical and efficient way remains a great challenge. Here we reported an improved nullO3-free Hummers method by partly replacing KMnO4 with K2FeO4 and controlling the amount of concentrated sulfuric acid. As compared to the existing nullO3-free Hummers methods, this improved routine greatly reduces the reactant consumption while keeps a high yield. The obtained GO was characterized by various techniques, and its derived graphene aerogel was demonstrated as high-performance supercapacitor electrodes. This improved synthesis shows good prospects for scalable production and applications of GO and its derivatives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 627, "Times Cited, All Databases": 672, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 3", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36143, "DOI": "10.1038/srep36143", "DOI Link": "http://dx.doi.org/10.1038/srep36143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387216200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Acharjya, A; Pachfule, P; Roeser, J; Schmitt, FJ; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Acharjya, Amitava; Pachfule, Pradip; Roeser, Jerome; Schmitt, Franz-Josef; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vinylene-Linked Covalent Organic Frameworks by Base-Catalyzed Aldol Condensation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two 2D covalent organic frameworks (COFs) linked by vinylene (-CH=CH-) groups (V-COF-1 and V-COF-2) are synthesized by exploiting the electron deficient nature of the aromatic s-triazine unit of C-3-symmetric 2,4,6-trimethyl-s-triazine (TMT). The acidic terminal methyl hydrogens of TMT can easily be abstracted by a base, resulting in a stabilized carbanion, which further undergoes aldol condensation with multitopic aryl aldehydes to be reticulated into extended crystalline frameworks (V-COFs). Both V-COF-1 (with terepthalaldehyde (TA)) and V-COF-2 (with 1,3,5-tris(p-formylphenyl)benzene (TFPB)) are polycrystalline and exhibit permanent porosity and BET surface areas of 1341 m(2) g(-1) and 627 m(2) g(-1), respectively. Owing to the close proximity (3.52 angstrom) of the pre-organized vinylene linkages within adjacent 2D layers stacked in eclipsed fashion, [2+2] photo-cycloadditon in V-COF-1 formed covalent crosslinks between the COF layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2019, "Volume": 58, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14865, "End Page": 14870, "Article Number": null, "DOI": "10.1002/anie.201905886", "DOI Link": "http://dx.doi.org/10.1002/anie.201905886", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485609000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YT; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yuntian; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective on hetero-deformation induced (HDI) hardening and back stress", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterostructured materials have been reported as a new class of materials with superior mechanical properties, which was attributed to the development of back stress. There are numerous reports on back stress theories and measurements with no consensus. Back stress is developed in soft domains to offset the applied stress, making them appear stronger, while forward stress is developed to make hard domains appear weaker. The extra hardening in heterostructured materials is resulted from interactions between back stresses and forward stresses, and should be described as hetero-deformation induced (HDI) hardening and the measured 'back stress' should be renamed HDI stress. [GRAPHICS] . IMPACT STATEMENT The 'back stress' hardening in the literature can be described more accurately as hetero-deformation induced (HDI) hardening and the measured 'back stress' should be renamed HDI stress.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 934, "Times Cited, All Databases": 980, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 393, "End Page": 398, "Article Number": null, "DOI": "10.1080/21663831.2019.1616331", "DOI Link": "http://dx.doi.org/10.1080/21663831.2019.1616331", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474337900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bartel, CJ; Sutton, C; Goldsmith, BR; Ouyang, RH; Musgrave, CB; Ghiringhelli, LM; Scheffler, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bartel, Christopher J.; Sutton, Christopher; Goldsmith, Bryan R.; Ouyang, Runhai; Musgrave, Charles B.; Ghiringhelli, Luca M.; Scheffler, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New tolerance factor to predict the stability of perovskite oxides and halides", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting the stability of the perovskite structure remains a long-standing challenge for the discovery of new functional materials for many applications including photovoltaics and electrocatalysts. We developed an accurate, physically interpretable, and one-dimensional tolerance factor, 'r, that correctly predicts 92% of compounds as perovskite or nonperovskite for an experimental dataset of 576 ABX(3) materials (X = O2-, F-, Cl-, Br-, I-) using a novel data analytics approach based on SISSO (sure independence screening and sparsifying operator). tau is shown to generalize outside the training set for 1034 experimentally realized single and double perovskites (91% accuracy) and is applied to identify 23,314 new double perovskites (A(2)BB'X-6) ranked by their probability of being stable as perovskite. This work guides experimentalists and theorists toward which perovskites are most likely to be successfully synthesized and demonstrates an approach to descriptor identification that can be extended to arbitrary applications beyond perovskite stability predictions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1070, "Times Cited, All Databases": 1158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav0693", "DOI": "10.1126/sciadv.aav0693", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav0693", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, T; Yan, DY; Wang, H; Jiao, Y; Hu, ZP; Zheng, Y; Zheng, LR; Mao, J; Liu, H; Du, XW; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Tao; Yan, Dong-Yang; Wang, Hui; Jiao, Yan; Hu, Zhenpeng; Zheng, Yao; Zheng, Lirong; Mao, Jing; Liu, Hui; Du, Xi-Wen; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating cobalt(II) oxide nullorods for efficient electrocatalysis by strain engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing high-performance and cost-effective electrocatalysts toward oxygen evolution and hydrogen evolution reactions in water-alkali electrolyzers is pivotal for large-scale and sustainable hydrogen production. Earth-abundant transition metal oxide-based catalysts are particularly active for oxygen evolution reaction; however, they are generally considered inactive toward hydrogen evolution reaction. Here, we show that strain engineering of the outermost surface of cobalt(II) oxide nullorods can turn them into efficient electrocatalysts for the hydrogen evolution reaction. They are competitive with the best electrocatalysts for this reaction in alkaline media so far. Our theoretical and experimental results demonstrate that the tensile strain strongly couples the atomic, electronic structure properties and the activity of the cobalt(II) oxide surface, which results in the creation of a large quantity of oxygen vacancies that facilitate water dissociation, and fine tunes the electronic structure to weaken hydrogen adsorption toward the optimum region.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1509, "DOI": "10.1038/s41467-017-01872-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01872-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415262100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ward, L; Agrawal, A; Choudhary, A; Wolverton, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ward, Logan; Agrawal, Ankit; Choudhary, Alok; Wolverton, Christopher", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general-purpose machine learning framework for predicting properties of inorganic materials", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A very active area of materials research is to devise methods that use machine learning to automatically extract predictive models from existing materials data. While prior examples have demonstrated successful models for some applications, many more applications exist where machine learning can make a strong impact. To enable faster development of machine-learning-based models for such applications, we have created a framework capable of being applied to a broad range of materials data. Our method works by using a chemically diverse list of attributes, which we demonstrate are suitable for describing a wide variety of properties, and a novel method for partitioning the data set into groups of similar materials to boost the predictive accuracy. In this manuscript, we demonstrate how this new method can be used to predict diverse properties of crystalline and amorphous materials, such as band gap energy and glass-forming ability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1121, "Times Cited, All Databases": 1266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 2, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16028, "DOI": "10.1038/npjcompumats.2016.28", "DOI Link": "http://dx.doi.org/10.1038/npjcompumats.2016.28", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426821500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Son, SB; Gao, T; Harvey, SP; Steirer, KX; Stokes, A; Norman, A; Wang, CS; Cresce, A; Xu, K; Ban, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Son, Seoung-Bum; Gao, Tao; Harvey, Steve P.; Steirer, K. Xerxes; Stokes, Adam; Norman, Andrew; Wang, Chunsheng; Cresce, Arthur; Xu, Kang; Ban, Chunmei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium-based batteries possess potential advantages over their lithium counterparts. However, reversible Mg chemistry requires a thermodynamically stable electrolyte at low potential, which is usually achieved with corrosive components and at the expense of stability against oxidation. In lithium-ion batteries the conflict between the cathodic and anodic stabilities of the electrolytes is resolved by forming an anode interphase that shields the electrolyte from being reduced. This strategy cannot be applied to Mg batteries because divalent Mg2+ cannot penetrate such interphases. Here, we engineer an artificial Mg2+-conductive interphase on the Mg anode surface, which successfully decouples the anodic and cathodic requirements for electrolytes and demonstrate highly reversible Mg chemistry in oxidation-resistant electrolytes. The artificial interphase enables the reversible cycling of a Mg/V2O5 full-cell in the water-containing, carbonate-based electrolyte. This approach provides a new avenue not only for Mg but also for other multivalent-cation batteries facing the same problems, taking a step towards their use in energy-storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 532, "End Page": 539, "Article Number": null, "DOI": "10.1038/s41557-018-0019-6", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0019-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430639900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Q; Zou, Y; Zhang, YL; Liu, Z; Shi, BJ; Wang, XX; Jin, YM; Ouyang, H; Li, Z; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Qiang; Zou, Yang; Zhang, Yalan; Liu, Zhuo; Shi, Bojing; Wang, Xinxin; Jin, Yiming; Ouyang, Han; Li, Zhou; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable triboelectric nullogenerator as a life-time designed implantable power source", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transient electronics built with degradable organic and inorganic materials is an emerging area and has shown great potential for in vivo sensors and therapeutic devices. However, most of these devices require external power sources to function, which may limit their applications for in vivo cases. We report a biodegradable triboelectric nullogenerator (BD-TENG) for in vivo biomechanical energy harvesting, which can be degraded and resorbed in an animal body after completing its work cycle without any adverse long-term effects. Tunable electrical output capabilities and degradation features were achieved by fabricated BD-TENG using different materials. When applying BD-TENG to power two complementary micrograting electrodes, a DC-pulsed electrical field was generated, and the nerve cell growth was successfully orientated, showing its feasibility for neuron-repairing process. Our work demonstrates the potential of BD-TENG as a power source for transient medical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 535, "Times Cited, All Databases": 562, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501478", "DOI": "10.1126/sciadv.1501478", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501478", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379620200028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bakarich, SE; Gorkin, R; Panhuis, MIH; Spinks, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bakarich, Shannon E.; Gorkin, Robert, III; Panhuis, Marc In Het; Spinks, Geoffrey M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4D Printing with Mechanically Robust, Thermally Actuating Hydrogels", "Source Title": "MACROMOLECULAR RAPID COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 36, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1211, "End Page": 1217, "Article Number": null, "DOI": "10.1002/marc.201500079", "DOI Link": "http://dx.doi.org/10.1002/marc.201500079", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356352600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alven, S; Peter, S; Mbese, Z; Aderibigbe, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alven, Sibusiso; Peter, Sijongesonke; Mbese, Zintle; Aderibigbe, Blessing A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymer-Based Wound Dressing Materials Loaded with Bioactive Agents: Potential Materials for the Treatment of Diabetic Wounds", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diabetic wounds are severe injuries that are common in patients that suffer from diabetes. Most of the presently employed wound dressing scaffolds are inappropriate for treating diabetic wounds. Improper treatment of diabetic wounds usually results in amputations. The shortcomings that are related to the currently used wound dressings include poor antimicrobial properties, inability to provide moisture, weak mechanical features, poor biodegradability, and biocompatibility, etc. To overcome the poor mechanical properties, polymer-based wound dressings have been designed from the combination of biopolymers (natural polymers) (e.g., chitosan, alginate, cellulose, chitin, gelatin, etc.) and synthetic polymers (e.g., poly (vinyl alcohol), poly (lactic-co-glycolic acid), polylactide, poly-glycolic acid, polyurethanes, etc.) to produce effective hybrid scaffolds for wound management. The loading of bioactive agents or drugs into polymer-based wound dressings can result in improved therapeutic outcomes such as good antibacterial or antioxidant activity when used in the treatment of diabetic wounds. Based on the outstanding performance of polymer-based wound dressings on diabetic wounds in the pre-clinical experiments, the in vivo and in vitro therapeutic results of the wound dressing materials on the diabetic wound are hereby reviewed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 724, "DOI": "10.3390/polym14040724", "DOI Link": "http://dx.doi.org/10.3390/polym14040724", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765179300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, X; Jannasch, A; Albrecht, UR; Hahn, K; Miguel-López, A; Schäffer, E; Sánchez, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Xing; Jannasch, Anita; Albrecht, Urban-Raphael; Hahn, Kersten; Miguel-Lopez, Albert; Schaeffer, Erik; Sanchez, Samuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enzyme-Powered Hollow Mesoporous Janus nullomotors", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of synthetic nullomotors for technological applications in particular for life science and nullomedicine is a key focus of current basic research. However, it has been challenging to make active nullosystems based on biocompatible materials consuming nontoxic fuels for providing self-propulsion. Here, we fabricate self-propelled Janus nullomotors based on hollow mesoporous silica nulloparticles (HMSNPs), which are powered by biocatalytic reactions of three different enzymes: catalase, urease, and glucose mddase (GOx). The active motion is characterized by a mean-square displacement (MSD) analysis of optical video recordings and confirmed by dynamic light scattering (DLS) measurements. We found that the apparent diffusion coefficient was enhanced by up to 83%. In addition, using optical tweezers, we directly measured a holding force of 64 +/- 16 fN, which was necessary to counteract the effective self-propulsion force generated by a single nullomotor. The successful demonstration of biocompatible enzyme-powered active nullomotors using biologically benign fuels has a great potential for future biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 15, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7043, "End Page": 7050, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b03100", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b03100", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363003100116", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SC; Wang, JY; Xu, R; Zhang, P; Chen, YL; Huang, ZJ; Yang, YF; Yu, Z; Oyakhire, ST; Zhang, WB; Greenburg, LC; Kim, MS; Boyle, DT; Sayavong, P; Ye, YS; Qin, J; Bao, ZA; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sang Cheol; Wang, Jingyang; Xu, Rong; Zhang, Pu; Chen, Yuelang; Huang, Zhuojun; Yang, Yufei; Yu, Zhiao; Oyakhire, Solomon T.; Zhang, Wenbo; Greenburg, Louisa C.; Kim, Mun Sek; Boyle, David T.; Sayavong, Philaphon; Ye, Yusheng; Qin, Jian; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy electrolytes for practical lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering is crucial for improving battery performance, particularly for lithium metal batteries. Recent advances in electrolytes have greatly improved cyclability by enhancing electrochemical stability at the electrode interfaces, but concurrently achieving high ionic conductivity has remained challenging. Here we report an electrolyte design strategy for enhanced lithium metal batteries by increasing the molecular diversity in electrolytes, which essentially leads to high-entropy electrolytes. We find that, in weakly solvating electrolytes, the entropy effect reduces ion clustering while preserving the characteristic anion-rich solvation structures, which is characterized by synchrotron-based X-ray scattering and molecular dynamics simulations. Electrolytes with smaller-sized clusters exhibit a twofold improvement in ionic conductivity compared with conventional weakly solvating electrolytes, enabling stable cycling at high current densities up to 2C (6.2 mA cm(-2)) in anode-free LiNi0.6Mn0.2Co0.2 (NMC622)||Cu pouch cells. The efficacy of the design strategy is verified by performance improvements in three disparate weakly solvating electrolyte systems. Electrolyte engineering has proven an effective approach to enhance the performance of lithium metal batteries. Here the authors propose a strategy by using multiple solvents in weakly solvating electrolytes-dubbed as high-entropy electrolytes-to improve the ionic conductivity while maintaining electrochemical stability, leading to high-performance batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 814, "End Page": 826, "Article Number": null, "DOI": "10.1038/s41560-023-01280-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01280-1", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001023405800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZH; Cong, S; Gong, WB; Xuan, JN; Li, GH; Lu, WB; Geng, FX; Zhao, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zuhui; Cong, Shan; Gong, Wenbin; Xuan, Jinnull; Li, Guohui; Lu, Weibang; Geng, Fengxia; Zhao, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semiconductor SERS enhancement enabled by oxygen incorporation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor-based surface-enhanced Raman spectroscopy (SERS) substrates represent a new frontier in the field of SERS. However, the application of semiconductor materials as SERS substrates is still seriously impeded by their low SERS enhancement and inferior detection sensitivity, especially for non-metal-oxide semiconductor materials. Herein, we demonstrate a general oxygen incorporation-assisted strategy to magnify the semiconductor substrate-analyte molecule interaction, leading to significant increase in SERS enhancement for non-metal-oxide semiconductor materials. Oxygen incorporation in MoS2 even with trace concentrations can not only increase enhancement factors by up to 100,000-fold compared with oxygen-unincorporated samples but also endow MoS2 with low limit of detection below 10(-7) M. Intriguingly, combined with the findings in previous studies, our present results indicate that both oxygen incorporation and extraction processes can result in SERS enhancement, probably due to the enhanced charge-transfer resonullce as well as exciton resonullce arising from the judicious control of oxygen admission in semiconductor substrate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1993, "DOI": "10.1038/s41467-017-02166-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02166-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417467100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, YH; Guo, L; Dan, M; Doronkin, DE; Han, CQ; Rao, ZQ; Liu, Y; Meng, J; Huang, Z; Zheng, KB; Chen, P; Dong, F; Zhou, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuehan; Guo, Lan; Dan, Meng; Doronkin, Dmitry E.; Han, Chunqiu; Rao, Zhiqiang; Liu, Yang; Meng, Jie; Huang, Zeai; Zheng, Kaibo; Chen, Peng; Dong, Fan; Zhou, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating electron density of vacancy site by single Au atom for effective CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface electron density significantly affects the photocatalytic efficiency, especially the photocatalytic CO2 reduction reaction, which involves multi-electron participation in the conversion process. Herein, we propose a conceptually different mechanism for surface electron density modulation based on the model of Au anchored CdS. We firstly manipulate the direction of electron transfer by regulating the vacancy types of CdS. When electrons accumulate on vacancies instead of single Au atoms, the adsorption types of CO2 change from physical adsorption to chemical adsorption. More importantly, the surface electron density is manipulated by controlling the size of Au nullostructures. When Au nulloclusters downsize to single Au atoms, the strong hybridization of Au 5d and S 2p orbits accelerates the photo-electrons transfer onto the surface, resulting in more electrons available for CO2 reduction. As a result, the product generation rate of Au-SA/Cd1-xS manifests a remarkable at least 113-fold enhancement compared with pristine Cd1-xS. The electron density of reactive sites significantly affects catalytic performances. Here, authors demonstrate the electron density of different reactive sites can be modulated by regulating the type of vacancy and the size of Au, leading to effective CO2 photoreduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1675, "DOI": "10.1038/s41467-021-21925-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21925-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630057500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, K; Xia, JY; Lu, Y; Zhang, BW; Shi, WC; Cao, X; Zhang, XY; Woods, LM; Han, CC; Chen, CJ; Wang, T; Wu, JS; Huang, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Kang; Xia, Jiuyang; Lu, Yu; Zhang, Bowei; Shi, Wencong; Cao, Xun; Zhang, Xinyue; Woods, Lilia M.; Han, Changcun; Chen, Chunjin; Wang, Tian; Wu, Junsheng; Huang, Yizhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Reconstructed Spinel Surface Structure Enabling the Long-Term Stable Hydrogen Evolution Reaction/Oxygen Evolution Reaction Efficiency of FeCoNiRu High-Entropy Alloyed Electrocatalyst", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High catalytic efficiency and long-term stability are two main components for the performance assessment of an electrocatalyst. Previous attention has been paid more to efficiency other than stability. The present work is focused on the study of the stability processed on the FeCoNiRu high-entropy alloy (HEA) in correlation with its catalytic efficiency. This catalyst has demonstrated not only performing the simultaneous hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) with high efficiency but also sustaining long-term stability upon HER and OER. The study reveals that the outstanding stability is attributed to the spinel oxide surface layer developed during evolution reactions. The spinel structure preserves the active sites that are inherited from the HEA's intrinsic structure. This work will provide an insightful direction/pathway for the design and manufacturing activities of other metallic electrocatalysts and a benchmark for the assessment of their efficiency-stability relationship.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300094", "DOI Link": "http://dx.doi.org/10.1002/advs.202300094", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955075000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, D; Yang, J; Fang, MM; Tang, BZ; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dan; Yang, Jie; Fang, Manman; Tang, Ben Zhong; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stimulus-responsive room temperature phosphorescence materials with full-color tunability from pure organic amorphous polymers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving stimulus-responsive ultralong room temperature phosphorescence (RTP) in organic materials especially with full-color tunable emissions is attractive and important but rarely reported. Here, a strategy was reported to realize stimulus-responsive RTP effect with color-tunable emissions by using water as solvent in the preparation process without any organic solvent through covalent linkage of arylboronic acids with different IC conjugations and polymer matrix of polyvinyl alcohol. The yielded polymer films exhibit outstanding RTP performance (2.43 s). Furthermore, an excitation-dependent RTP film was obtained, and the afterglow color changes from blue to green, then to red as the excitation wavelength increases. The RTP property of all the above materials is sensitive to water and heat stimuli, because the rigidity of the system could be broken by water. Last, they were successfully applied in a multilevel information encryption and multicolor paper and ink.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl8392", "DOI": "10.1126/sciadv.abl8392", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl8392", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763313300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, G; Chen, D; Li, CL; Liu, WX; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Gang; Chen, Duo; Li, Chenglong; Liu, Wenxia; Liu, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineered Microstructure Derived Hierarchical Deformation of Flexible Pressure Sensor Induces a Supersensitive Piezoresistive Property in Broad Pressure Range", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fabricating flexible pressure sensors with high sensitivity in a broad pressure range is still a challenge. Herein, a flexible pressure sensor with engineered microstructures on polydimethylsiloxane (PDMS) film is designed. The high performance of the sensor derives from its unique pyramid-wall-grid microstructure (PWGM). A square array of dome-topped pyramids and crossed strengthening walls on the film forms a multiheight hierarchical microstructure. Two pieces of PWGM flexible PDMS film, stacked face-to-face, form a piezoresistive sensor endowed with ultrahigh sensitivity across a very broad pressure range. The sensitivity of the device is as high as 383 665.9 and 269 662.9 kPa(-1)in the pressure ranges 0-1.6 and 1.6-6 kPa, respectively. In the higher pressure range of 6.1-11 kPa, the sensitivity is 48 689.1 kPa(-1), and even in the very high pressure range of 11-56 kPa, it stays at 1266.8 kPa(-1). The pressure sensor possesses excellent bending and torsional strain detection properties, is mechanically durable, and has potential applications in wearable biosensing for healthcare. In addition, 2 x 2 and 4 x 4 sensor arrays are prepared and characterized, suggesting the possibility of manufacturing a flexible tactile sensor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000154, "DOI": "10.1002/advs.202000154", "DOI Link": "http://dx.doi.org/10.1002/advs.202000154", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561888000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, P; Chen, YH; Xu, YY; Valenzuela, C; Zhang, X; Bisoyi, HK; Yang, X; Wang, L; Xu, XH; Li, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Pan; Chen, Yuanhao; Xu, Yiyi; Valenzuela, Cristian; Zhang, Xuan; Bisoyi, Hari Krishna; Yang, Xiao; Wang, Ling; Xu, Xinhua; Li, Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired MXene-Based Soft Actuators Exhibiting Angle-Independent Structural Color", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In nature, many living organisms exhibiting unique structural coloration and soft-bodied actuation have inspired scientists to develop advanced structural colored soft actuators toward biomimetic soft robots. However, it is challenging to simultaneously biomimic the angle-independent structural color and shape-morphing capabilities found in the plum-throated cotinga flying bird. Herein, we report biomimetic MXene-based soft actuators with angle-independent structural color that are fabricated through controlled self-assembly of colloidal SiO2 nullopardcles onto highly aligned MXene films followed by vacuum-assisted infiltration of polyvinylidene fluoride into the interstices. The resulting soft actuators are found to exhibit brilliant, angle-independent structural color, as well as ultrafast actuation and recovery speeds (a maximum curvature of 0.52 mm(-1) can be achieved within 1.16 s, and a recovery time of similar to 0.24 s) in response to acetone vapor. As proof-of-concept illustrations, structural colored soft actuators are applied to demonstrate a blue gripper-like bird's claw that can capture the target, artificial green tendrils that can twine around tree branches, and an artificial multicolored butterfly that can flutter its wings upon cyclic exposure to acetone vapor. The strategy is expected to offer new insights into the development of biomimetic multifunctional soft actuators for somatosensory soft robotics and next-generation intelligent machines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1, "DOI": "10.1007/s40820-022-00977-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00977-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000889558600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, TT; Zhao, S; Chen, WX; Zhai, D; Dong, JC; Wang, Y; Zhang, SL; Han, AJ; Gu, L; Yu, R; Wen, XD; Ren, HL; Xu, LB; Chen, C; Peng, Q; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Tingting; Zhao, Shu; Chen, Wenxing; Zhai, Dong; Dong, Juncai; Wang, Yu; Zhang, Shaolong; Han, Aijuan; Gu, Lin; Yu, Rong; Wen, Xiaodong; Ren, Hanlin; Xu, Lianbin; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring efficient and cost-effective catalysts to replace precious metal catalysts, such as Pt, for electrocatalytic oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) holds great promise for renewable energy technologies. Herein, we prepare a type of Co catalyst with single-atomic Co sites embedded in hierarchically ordered porous N-doped carbon (Co-SAS/HOPNC) through a facile dual-template cooperative pyrolysis approach. The desirable combination of highly dispersed isolated atomic Co-N-4 active sites, large surface area, high porosity, and good conductivity gives rise to an excellent catalytic performance. The catalyst exhibits outstanding performance for ORR in alkaline medium with a half-wave potential (E-1/2) of 0.892 V, which is 53 mV more positive than that of Pt/C, as well as a high tolerance of methanol and great stability. The catalyst also shows a remarkable catalytic performance for HER with distinctly high turnover frequencies of 0.41 and 3.8 s(-1) at an overpotential of 100 and 200 mV, respectively, together with a long-term durability in acidic condition. Experiments and density functional theory (DFT) calculations reveal that the atomically isolated single Co sites and the structural advantages of the unique 3D hierarchical porous architecture synergistically contribute to the high catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2018, "Volume": 115, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12692, "End Page": 12697, "Article Number": null, "DOI": "10.1073/pnas.1813605115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1813605115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452866000062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Provis, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Provis, John L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkali-activated materials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper, which forms part of the UNEP White Papers series on Eco-Efficient Cements, provides a brief discussion of the class of cementing materials known as 'alkali-activated binders', which are identified to have potential for utilization as a key component of a sustainable future global construction materials industry. These cements are not expected to offer a like-for-like replacement of Portland cement across its full range of applications, for reasons related to supply chain limitations, practical challenges in some modes of application, and the need for careful control of formulation and curing. However, when produced using locally-available raw materials, with well-formulated mix designs (including in particular consideration of the environmental footprint of the alkaline activator) and production under adequate levels of quality control, alkali-activated binders are potentially an important and cost-effective component of the future toolkit of sustainable construction materials. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1163, "Times Cited, All Databases": 1215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 114, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 40, "End Page": 48, "Article Number": null, "DOI": "10.1016/j.cemconres.2017.02.009", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2017.02.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454375600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Galkowski, K; Mitioglu, A; Miyata, A; Plochocka, P; Portugall, O; Eperon, GE; Wang, JTW; Stergiopoulos, T; Stranks, SD; Snaith, HJ; Nicholas, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Galkowski, Krzysztof; Mitioglu, Anatolie; Miyata, Atsuhiko; Plochocka, Paulina; Portugall, Oliver; Eperon, Giles E.; Wang, Jacob Tse-Wei; Stergiopoulos, Thomas; Stranks, Samuel D.; Snaith, Henry J.; Nicholas, Robin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of the exciton binding energy and effective masses for methylammonium and formamidinium lead tri-halide perovskite semiconductors", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The family of organic-inorganic halide perovskite materials has generated tremendous interest in the field of photovoltaics due to their high power conversion efficiencies. There has been intensive development of cells based on the archetypal methylammonium (MA) and recently introduced formamidinium (FA) materials, however, there is still considerable controversy over their fundamental electronic properties. Two of the most important parameters are the binding energy of the exciton (R*) and its reduced effective mass mu. Here we present extensive magneto optical studies of Cl assisted grown MAPbI(3) as well as MAPbBr(3) and the FA based materials FAPbI(3) and FAPbBr(3). We fit the excitonic states as a hydrogenic atom in magnetic field and the Landau levels for free carriers to give R* and mu. The values of the exciton binding energy are in the range 14-25 meV in the low temperature phase and fall considerably at higher temperatures for the tri-iodides, consistent with free carrier behaviour in all devices made from these materials. Both R* and mu increase approximately proportionally to the band gap, and the mass values, 0.09-0.117m(0), are consistent with a simple k.p perturbation approach to the band structure which can be generalized to predict values for the effective mass and binding energy for other members of this perovskite family of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 639, "Times Cited, All Databases": 695, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 962, "End Page": 970, "Article Number": null, "DOI": "10.1039/c5ee03435c", "DOI Link": "http://dx.doi.org/10.1039/c5ee03435c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372243600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, JW; Zhou, GJ; Zhou, YY; Zhang, QY; Xia, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Jianwei; Zhou, Guojun; Zhou, Yayun; Zhang, Qinyuan; Xia, Zhiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near-infrared luminescent materials exhibit unique photophysical properties that make them crucial components in photonic, optoelectronic and biological applications. As broadband near infrared phosphors activated by transition metal elements are already widely reported, there is a challenge for next-generation materials discovery by introducing rare earth activators with 4f-5d transition. Here, we report an unprecedented phosphor K3LuSi2O7:Eu2+ that gives an emission band centered at 740 nm with a full-width at half maximum of 160 nm upon 460 nm blue light excitation. Combined structural and spectral characterizations reveal a selective site occupation of divalent europium in LuO6 and K2O6 polyhedrons with small coordination numbers, leading to the unexpected near infrared emission. The fabricated phosphor-converted light-emitting diodes have great potential as a non-visible light source. Our work provides the design principle of near infrared emission in divalent europium-doped inorganic solid-state materials and could inspire future studies to further explore nearinfrared light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 520, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5267, "DOI": "10.1038/s41467-019-13293-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13293-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497695300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XY; Luo, DY; Xiang, YR; Zhao, LC; Anaya, M; Shen, YL; Wu, J; Yang, WQ; Chiang, YH; Tu, YG; Su, R; Hu, Q; Yu, HY; Shao, GS; Huang, W; Russell, TP; Gong, QH; Stranks, SD; Zhang, W; Zhu, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaoyu; Luo, Deying; Xiang, Yuren; Zhao, Lichen; Anaya, Miguel; Shen, Yonglong; Wu, Jiang; Yang, Wenqiang; Chiang, Yu-Hsien; Tu, Yongguang; Su, Rui; Hu, Qin; Yu, Hongyu; Shao, Guosheng; Huang, Wei; Russell, Thomas P.; Gong, Qihuang; Stranks, Samuel D.; Zhang, Wei; Zhu, Rui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Buried Interfaces in Halide Perovskite Photovoltaics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the fundamental properties of buried interfaces in perovskite photovoltaics is of paramount importance to the enhancement of device efficiency and stability. Nevertheless, accessing buried interfaces poses a sizeable challenge because of their non-exposed feature. Herein, the mystery of the buried interface in full device stacks is deciphered by combining advanced in situ spectroscopy techniques with a facile lift-off strategy. By establishing the microstructure-property relations, the basic losses at the contact interfaces are systematically presented, and it is found that the buried interface losses induced by both the sub-microscale extended imperfections and lead-halide inhomogeneities are major roadblocks toward improvement of device performance. The losses can be considerably mitigated by the use of a passivation-molecule-assisted microstructural reconstruction, which unlocks the full potential for improving device performance. The findings open a new avenue to understanding performance losses and thus the design of new passivation strategies to remove imperfections at the top surfaces and buried interfaces of perovskite photovoltaics, resulting in substantial enhancement in device performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 33, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2006435, "DOI": "10.1002/adma.202006435", "DOI Link": "http://dx.doi.org/10.1002/adma.202006435", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604273900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Liu, BY; Luo, M; Ning, SC; Peng, M; Zhao, Y; Lu, YR; Chan, TS; de Groot, FMF; Tan, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kang; Liu, Boyang; Luo, Min; Ning, Shoucong; Peng, Ming; Zhao, Yang; Lu, Ying-Rui; Chan, Ting-Shan; de Groot, Frank M. F.; Tan, Yongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single platinum atoms embedded in nulloporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing efficient electrocatalysts for hydrogen evolution reaction is significant for renewable and sustainable energy conversion. Here, we report single-atom platinum decorated nulloporous Co0.85Se (Pt/np-Co0.85Se) as efficient electrocatalysts for hydrogen evolution. The achieved Pt/np-Co0.85Se shows high catalytic performance with a near-zero onset overpotential, a low Tafel slope of 35 mV dec(-1), and a high turnover frequency of 3.93 s(-1) at -100 mV in neutral media, outperforming commercial Pt/C catalyst and other reported transition-metal-based compounds. Operando X-ray absorption spectroscopy studies combined with density functional theory calculations indicate that single-atom platinum in Pt/np-Co0.85Se not only can optimize surface states of Co0.85Se active centers under realistic working conditions, but also can significantly reduce energy barriers of water dissociation and improve adsorption/desorption behavior of hydrogen, which synergistically promote thermodynamics and kinetics. This work opens up further opportunities for local electronic structures tuning of electrocatalysts to effectively manipulate its catalytic properties by an atomic-level engineering strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 572, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1743, "DOI": "10.1038/s41467-019-09765-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09765-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464494100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarkar, A; Djenadic, R; Wang, D; Hein, C; Kautenburger, R; Clemens, O; Hahn, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarkar, Abhishek; Djenadic, Ruzica; Wang, Di; Hein, Christina; Kautenburger, Ralf; Clemens, Oliver; Hahn, Horst", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rare earth and transition metal based entropy stabilised perovskite type oxides", "Source Title": "JOURNAL OF THE EUROPEAN CERAMIC SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multicomponent oxides with perovskite type of structure containing up to 10 different cations in equiatomic amounts have been synthesised for the first time. Out of eleven systems synthesised, only six systems crystallised as single phase perovskite type compounds with random and homogenous cation distribution on the respective sites. The formation of phase pure 10-cationic system, (Gd0.2La0.2Nd0.2Sm0.2Y0.2)(Co0.2Cr0.2Fe0.2Mn0.2Ni0.2)O-3, in contrast to the multiphase mixtures observed in five of the lower entropy systems (containing 6 cations) indicates a possible role of entropy in the stabilisation of a single phase crystal structure. The entropy driven structural stabilisation effect is further supported by the reversible phase transformation, from single phase to multiple phase upon cyclic heat treatment, observed in the (Gd0.2La0.2Nd0.2Sm0.2Y0.2)MnO3 system. This type of entropic signature has been observed in rocksalt based high entropy oxide systems. However, it has not been reported before for perovskite based compounds, as shown in this study.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 38, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2318, "End Page": 2327, "Article Number": null, "DOI": "10.1016/j.jeurceramsoc.2017.12.058", "DOI Link": "http://dx.doi.org/10.1016/j.jeurceramsoc.2017.12.058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426029700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JZ; Chen, MG; Samad, A; Dong, HC; Ray, A; Zhang, JW; Jiang, XC; Schwingenschlögl, U; Domke, J; Chen, CL; Han, Y; Fritz, T; Ruoff, RS; Tian, B; Zhang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Junzhu; Chen, Mingguang; Samad, Abdus; Dong, Haocong; Ray, Avijeet; Zhang, Junwei; Jiang, Xiaochuan; Schwingenschlogl, Udo; Domke, Jari; Chen, Cailing; Han, Yu; Fritz, Torsten; Ruoff, Rodney S.; Tian, Bo; Zhang, Xixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wafer-scale single-crystal monolayer graphene grown on sapphire substrate", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-quality wafer-scale single-crystal monolayer graphene is achieved on sapphire substrate, by epitaxially growing graphene at the Cu(111)/sapphire interface and then detaching Cu film via immersion in liquid nitrogen and rapid heating. The growth of inch-scale high-quality graphene on insulating substrates is desirable for electronic and optoelectronic applications, but remains challenging due to the lack of metal catalysis. Here we demonstrate the wafer-scale synthesis of adlayer-free ultra-flat single-crystal monolayer graphene on sapphire substrates. We converted polycrystalline Cu foil placed on Al2O3(0001) into single-crystal Cu(111) film via annealing, and then achieved epitaxial growth of graphene at the interface between Cu(111) and Al2O3(0001) by multi-cycle plasma etching-assisted-chemical vapour deposition. Immersion in liquid nitrogen followed by rapid heating causes the Cu(111) film to bulge and peel off easily, while the graphene film remains on the sapphire substrate without degradation. Field-effect transistors fabricated on as-grown graphene exhibited good electronic transport properties with high carrier mobilities. This work breaks a bottleneck of synthesizing wafer-scale single-crystal monolayer graphene on insulating substrates and could contribute to next-generation graphene-based nullodevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 21, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 740, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-021-01174-1", "DOI Link": "http://dx.doi.org/10.1038/s41563-021-01174-1", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744836500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ryder, CR; Wood, JD; Wells, SA; Yang, Y; Jariwala, D; Marks, TJ; Schatz, GC; Hersam, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ryder, Christopher R.; Wood, Joshua D.; Wells, Spencer A.; Yang, Yang; Jariwala, Deep; Marks, Tobin J.; Schatz, George C.; Hersam, Mark C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent functionalization and passivation of exfoliated black phosphorus via aryl diazonium chemistry", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functionalization of atomically thin nullomaterials enables the tailoring of their chemical, optical and electronic properties. Exfoliated black phosphorus (BP)-a layered two-dimensional semiconductor-exhibits favourable charge-carrier mobility, tunable bandgap and highly anisotropic properties, but it is chemically reactive and degrades rapidly in ambient conditions. Here we show that covalent aryl diazonium functionalization suppresses the chemical degradation of exfoliated BP even after three weeks of ambient exposure. This chemical modification scheme spontaneously forms phosphorus-carbon bonds, has a reaction rate sensitive to the aryl diazonium substituent and alters the electronic properties of exfoliated BP, ultimately yielding a strong, tunable p-type doping that simultaneously improves the field-effect transistor mobility and on/off current ratio. This chemical functionalization pathway controllably modifies the properties of exfoliated BP, and thus improves its prospects for nulloelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 767, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 597, "End Page": 602, "Article Number": null, "DOI": "10.1038/NCHEM.2505", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376529000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bian, J; Zhang, ZQ; Feng, JN; Thangamuthu, M; Yang, F; Sun, L; Li, ZJ; Qu, Y; Tang, DY; Lin, ZW; Bai, FQ; Tang, JW; Jing, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bian, Ji; Zhang, Ziqing; Feng, Jiannull; Thangamuthu, Madasamy; Yang, Fan; Sun, Ling; Li, Zhijun; Qu, Yang; Tang, Dongyan; Lin, Zewei; Bai, Fuquan; Tang, Junwang; Jing, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy Platform for Directed Charge Transfer in the Cascade Z-Scheme Heterojunction: CO2 Photoreduction without a Cocatalyst", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A universal strategy is developed to construct a cascade Z-Scheme system, in which an effective energy platform is the core to direct charge transfer and separation, blocking the unexpected type-II charge transfer pathway. The dimension-matched (001)TiO2-g-C3N4/BiVO4 nullosheet heterojunction (T-CN/BVNS) is the first such model. The optimized cascade Z-Scheme exhibits approximate to 19-fold photoactivity improvement for CO2 reduction to CO in the absence of cocatalysts and costly sacrificial agents under visible-light irradiation, compared with BVNS, which is also superior to other reported Z-Scheme systems even with noble metals as mediators. The experimental results and DFT calculations based on van der Waals structural models on the ultrafast timescale reveal that the introduced T as the platform prolongs the lifetimes of spatially separated electrons and holes and does not compromise their reduction and oxidation potentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2021, "Volume": 60, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20906, "End Page": 20914, "Article Number": null, "DOI": "10.1002/anie.202106929", "DOI Link": "http://dx.doi.org/10.1002/anie.202106929", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684748700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Li, BQ; Zhang, XQ; Huang, JQ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng; Li, Bo-Quan; Zhang, Xue-Qiang; Huang, Jia-Qi; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Perspective toward Practical Lithium-Sulfur Batteries", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries have long been expected to be a promising high-energy-density secondary battery system since their first prototype in the 1960s. During the past decade, great progress has been achieved in promoting the performances of Li-S batteries by addressing the challenges at the laboratory-level model systems. With growing attention paid to the application of Li-S batteries, new challenges at practical cell scales emerge as the bottleneck. In this Outlook, the key parameters for practical Li-S batteries to achieve practical high energy density are emphasized regarding high-sulfur-loading cathodes, lean electrolytes, and limited excess anodes. Subsequently, the key scientific problems are redefined in practical Li-S batteries beyond the previous ones under ideal conditions. Finally, viable strategies are proposed to address the above challenges as future research directions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2020, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1095, "End Page": 1104, "Article Number": null, "DOI": "10.1021/acscentsci.0c00449", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c00449", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555422900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WH; Xiao, SM; Song, QH; Liu, YL; Wu, YK; Wang, S; Yu, J; Han, JC; Tsai, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wenhong; Xiao, Shumin; Song, Qinghai; Liu, Yilin; Wu, Yunkai; Wang, Shuai; Yu, Jie; Han, Jiecai; Tsai, Din-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-dielectric metasurface for high-performance structural color", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The achievement of structural color has shown advantages in large-gamut, high-saturation, high-brightness, and high-resolution. While a large number of plasmonic/dielectric nullostructures have been developed for structural color, the previous approaches fail to match all the above criterion simultaneously. Herein we utilize the Si metasurface to demonstrate an all-in-one solution for structural color. Due to the intrinsic material loss, the conventional Si metasurfaces only have a broadband reflection and a small gamut of 78% of sRGB. Once they are combined with a refractive index matching layer, the reflection bandwidth and the background reflection are both reduced, improving the brightness and the color purity significantly. Consequently, the experimentally demonstrated gamut has been increased to around 181.8% of sRGB, 135.6% of Adobe RGB, and 97.2% of Rec.2020. Meanwhile, high refractive index of silicon preserves the distinct color in a pixel with 2x2 array of nullodisks, giving a diffraction-limit resolution. Here, the authors fabricate a metasurface with high brightness and large gamut structured colors by combining a silicon metasurface with a refractive index matching layer. The experimentally demonstrated gamut is 181.8% of sRGB, 135.6% of Adobe RGB, and 97.2% of Rec.2020.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1864, "DOI": "10.1038/s41467-020-15773-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15773-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558826800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, CK; Cen, D; Ren, ZH; Wang, YF; Wu, YJ; Li, X; Han, GR; Cai, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Congkun; Cen, Dong; Ren, Zhaohui; Wang, Yifan; Wu, Yongjun; Li, Xiang; Han, Gaorong; Cai, Xiujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FeS@BSA nulloclusters to Enable H2S-Amplified ROS-Based Therapy with MRI Guidance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Therapeutic systems to induce reactive oxygen species (ROS) have received tremendous success in the research of tumor theranostics, but suffered daunting challenges in limited efficacy originating from low presence of reactants and reaction kinetics within cancer cells. Here, ferrous sulfide-embedded bovine serum albumin (FeS@BSA) nulloclusters, in an amorphous nature, are designed and synthesized via a self-assembly approach. In acidic conditions, the nulloclusters degrade and simultaneously release H2S gas and Fe2+ ions. The in vitro study using Huh7 cancer cells reveals that Fe2+ released from FeS@BSA nulloclusters induces the toxic hydroxyl radical (center dot OH) effectively via the Fenton reaction. More interestingly, H2S gas released intracellularly presents the specific suppression effect to catalase activity of cancer cells, resulting in the promoted presence of H2O2 that facilitates the Fenton reaction of Fe2+ and consequently promotes ROS induction within the cells remarkably. After intravenous administration, the nulloclusters accumulate in the tumors of mice via the enhanced permeability and retention effect and present strong magnetic resonullce imaging (MRI) signals. The findings confirm this therapeutic system can enable superior anti-tumor performance with MRI guidance and negligible side effects. This study, therefore, offers an alternative gas-amplified ROS-based therapeutic platform for synergetic tumor treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903512, "DOI": "10.1002/advs.201903512", "DOI Link": "http://dx.doi.org/10.1002/advs.201903512", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514182200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, QQ; Li, XS; Ma, Q; Zhang, Q; Bai, H; Yi, WC; Liu, JY; Han, J; Xi, GC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qiqi; Li, Xinshi; Ma, Qiang; Zhang, Qing; Bai, Hua; Yi, Wencai; Liu, Jingyao; Han, Jing; Xi, Guangcheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A metallic molybdenum dioxide with high stability for surface enhanced Raman spectroscopy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compared with noble metals, semiconductors with surface plasmon resonullce effect are another type of SERS substrate materials. The main obstacles so far are that the semiconducting materials are often unstable and easy to be further oxidized or decomposed by laser irradiating or contacting with corrosive substances. Here, we report that metallic MoO2 can be used as a SERS substrate to detect trace amounts of highly risk chemicals including bisphenol A (BPA), dichloropheno (DCP), pentachlorophenol (PCP) and so on. The minimum detectable concentration was 10(-7) M and the maximum enhancement factor is up to 3.75 x 10(6). To the best of our knowledge, it may be the best among the metal oxides and even reaches or approaches to Au/Ag. The MoO2 shows an unexpected high oxidation resistance, which can even withstand 300 degrees C in air without further oxidation. The MoO2 material also can resist long etching of strong acid and alkali.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14903, "DOI": "10.1038/ncomms14903", "DOI Link": "http://dx.doi.org/10.1038/ncomms14903", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400140100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HN; Zhang, CJ; Rana, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haining; Zhang, Changjian; Rana, Farhan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast Dynamics of Defect-Assisted Electron Hole Recombination in Mono layer MoS2", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this Letter, we present nondegenerate ultrafast optical pumpprobe studies of the carrier recombination dynamics in MoS2 monolayers. By tuning the probe to wavelengths much longer than the exciton line, we make the probe transmission sensitive to the total population of photoexcited electrons and holes. Our measurement reveals two distinct time scales over which the photoexcited electrons and holes recombine; a fast time scale that lasts similar to 2 ps and a slow time scale that lasts longer than similar to 100 ps. The temperature and the pump fluence dependence of the observed carrier dynamics are consistent with defect-assisted recombination as being the dominullt mechanism for electronhole recombination in which the electrons and holes are captured by defects via Auger processes. Strong Coulomb interactions in two-dimensional atomic materials, together with strong electron and hole correlations in two-dimensional metal dichalcogenides, make Auger processes particularly effective for carrier capture by defects. We present a model for carrier recombination dynamics that quantitatively explains all features of our data for different temperatures and pump fluences. The theoretical estimates for the rate constants for Auger carrier capture are in good agreement with the experimentally determined values. Our results underscore the important role played by Auger processes in two-dimensional atomic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 617, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 339, "End Page": 345, "Article Number": null, "DOI": "10.1021/nl503636c", "DOI Link": "http://dx.doi.org/10.1021/nl503636c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348086100054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, YC; Tian, ZQ; Zhang, LJ; Ma, JY; Jiang, Z; Deibert, BJ; Ge, RX; Chen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yichao; Tian, Ziqi; Zhang, Linjuan; Ma, Jingyuan; Jiang, Zheng; Deibert, Benjamin J.; Ge, Ruixiang; Chen, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of active, acid-stable and low-cost electrocatalysts for oxygen evolution reaction is urgent and challenging. Herein we report an Iridium-free and low ruthenium-content oxide material (Cr0.6Ru0.4O2) derived from metal-organic framework with remarkable oxygen evolution reaction performance in acidic condition. It shows a record low overpotential of 178 mV at 10 mA cm(-2) and maintains the excellent performance throughout the 10 h chronopotentiometry test at a constant current of 10 mA cm(-2) in 0.5M H2SO4 solution. Density functional theory calculations further revealed the intrinsic mechanism for the exceptional oxygen evolution reaction performance, highlighting the influence of chromium promoter on the enhancement in both activity and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 567, "Times Cited, All Databases": 595, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 162, "DOI": "10.1038/s41467-018-08144-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08144-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455474500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Pan, ZH; Yang, Y; Wang, PF; Pei, CY; Chen, W; Huang, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jin; Pan, Zi-Hao; Yang, Ying; Wang, Peng-Fei; Pei, Chen-Yang; Chen, Wei; Huang, Guo-Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting the catalytic activity of a step-scheme In2O3/ZnIn2S4 hybrid system for the photofixation of nitrogen", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, a step-scheme photocatalytic system comprising one-dimensional In2O3 nullorods and two-dimensional ZnIn2S4 nullosheets was developed for the catalytic photofixation of nitrogen. The effects of the combination of In2O3 with ZnIn2S4 on the crystallinity, microstructure, optical absorption, and charge transfer behavior of the In2O3/ZnIn2S4 hybrid photocatalysts were investigated. Benefiting from the synergistic effects of the photogenerated vacancies and a step-scheme charge separation mechanism, the In2O3/ZnIn2S4 hybrid photocatalyst exhibited significantly enhanced catalytic activity compared to those of bare In2O3 and pure ZnIn2S4, and an optimized 50 wt% In2O3/ZnIn2S4 hybrid sample was found to exhibit superior catalytic activity for the photofixation of N-2, fixing 18.1 +/- 0.77 mg.L-1 of ammonia after exposure to simulated sunlight for 2 h. Crucially, the results of trapping experiments and electron paramagnetic resonullce investigation to identify the active species confirmed that the catalytic nitrogen photofixation performance was highly correlated with the presence of center dot CO2- radicals rather than photogenerated electrons, especially when methanol was used as a hole scavenger. In summary, the reported In2O3/ZnIn2S4 hybrid photocatalysts exhibit both stability and high activity for the photofixation of N-2, making them promising catalysts for sunlight-driven artificial N-2 fixation. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 275, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63801-9", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63801-9", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, CY; Yang, CY; Eidson, N; Chen, J; Han, FD; Chen, L; Luo, C; Wang, PF; Fan, XL; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Chunyu; Yang, Chongyin; Eidson, Nico; Chen, Ji; Han, Fudong; Chen, Long; Luo, Chao; Wang, Peng-Fei; Fan, Xiulin; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Reversible, Dendrite-Free Lithium Metal Anode Enabled by a Lithium-Fluoride-Enriched Interphase", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic lithium is the most competitive anode material for next-generation lithium (Li)-ion batteries. However, one of its major issues is Li dendrite growth and detachment, which not only causes safety issues, but also continuously consumes electrolyte and Li, leading to low coulombic efficiency (CE) and short cycle life for Li metal batteries. Herein, the Li dendrite growth of metallic lithium anode is suppressed by forming a lithium fluoride (LiF)-enriched solid electrolyte interphase (SEI) through the lithiation of surface-fluorinated mesocarbon microbeads (MCMB-F) anodes. The robust LiF-enriched SEI with high interfacial energy to Li metal effectively promotes planar growth of Li metal on the Li surface and meanwhile prevents its vertical penetration into the LiF-enriched SEI from forming Li dendrites. At a discharge capacity of 1.2 mAh cm(-2), a high CE of >99.2% for Li plating/stripping in FEC-based electrolyte is achieved within 25 cycles. Coupling the pre-lithiated MCMB-F (Li@MCMB-F) anode with a commercial LiFePO4 cathode at the positive/negative (P/N) capacity ratio of 1:1, the LiFePO4//Li@MCMB-F cells can be charged/discharged at a high areal capacity of 2.4 mAh cm(-2) for 110 times at a negligible capacity decay of 0.01% per cycle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 32, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906427, "DOI": "10.1002/adma.201906427", "DOI Link": "http://dx.doi.org/10.1002/adma.201906427", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513285600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schirinzi, GF; Pérez-Pomeda, I; Sanchís, J; Rossini, C; Farré, M; Barceló, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schirinzi, Gabriella F.; Perez-Pomeda, Ignacio; Sanchis, Josep; Rossini, Cesare; Farre, Marinella; Barcelo, Damia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cytotoxic effects of commonly used nullomaterials and microplastics on cerebral and epithelial human cells", "Source Title": "ENVIRONMENTAL RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic wastes are among the major inputs of detritus into aquatic ecosystems. Also, during recent years the increasing use of new materials such as nullomaterials (NMs) in industrial and household applications has contributed to the complexity of waste mixtures in aquatic systems. The current effects and the synergism and antagonisms of mixtures of microplastics (MPLs), NMs and organic compounds on the environment and in human health have, to date, not been well understood but instead they are a cause for general concern. The aim of this work is to contribute to a better understanding of the cytotoxicity of NMs and microplastics/ nulloplastics (MPLs/NPLs), at cell level in terms of oxidative stress (evaluating Reactive Oxygen Species effect) and cell viability. Firstly, the individual cytotoxicity of metal nulloparticles (NPs) (AgNPs and AuNPs), of metal oxide NPs (ZrO(2)NPs, CeO(2)NPs, TiO(2)NPs, and Al(2)O(3)NPs), carbon nullomaterials (C(50)ofullerene, graphene), and MPLs of polyethylene (PE) and polystyrene (PS) has been evaluated in vitro. Two different cellular lines T98G and HeLa, cerebral and epithelial human cells, respectively, were employed. The cells were exposed during 24-48 h to different levels of contaminullts, from 10 ng/mL to 10 mu g/mL, under the same conditions. Secondly, the synergistic and antagonistic relationships between fullerenes and other organic contaminullts, including an organophosphate insecticide (malathion), a surfactant (sodium dodecylbenzenesulfonate) and a plasticiser (diethyl phthalate) were assessed. The obtained results confirm that oxidative stress is one of the mechanisms of cytotoxicity at cell level, as has been observed for both cell lines and contributes to the current knowledge of the effects of NMs and MPLs-NPLs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 159, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 579, "End Page": 587, "Article Number": null, "DOI": "10.1016/j.envres.2017.08.043", "DOI Link": "http://dx.doi.org/10.1016/j.envres.2017.08.043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Public, Environmental & Occupational Health", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413280500065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, YM; Lee, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Yiming; Lee, Youngsoo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface modification of zein colloidal particles with sodium caseinate to stabilize oil-in-water pickering emulsion", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zein colloidal nulloparticles can adsorb at the oilewater interface to form Pickering emulsion. However, zein Pickering emulsion is usually not stable due to the poor wettability of zein colloidal nulloparticles. The objective of this study was to modify the surface of zein nulloparticles using sodium caseinate (NaCas) and assess the properties of zein/NaCas nullocomplexes and the resultant oil-in-water Pickering emulsions. One percent (w/w) of zein/NaCas colloidal nullocomplexes were formed, with the zein: NaCas ratios (w/w) ranging from 10: 1 to 10: 4 at pH = 3 by an ultrasound treatment. The zeta-potential of the zein/NaCas nullocomplexes showed altered surface charges, indicating that NaCas adsorbed on the surface of the zein colloidal nulloparticles. Three-phase contact angle measurements suggested that the original zein colloidal nulloparticles were preferentially wetted in water. The incorporation of 0.1%-0.2% (w/w) NaCas significantly enhanced its wettability in the oil, and intermediate wettability was achieved at a zein: NaCas ratio of 10:3. Confocal laser scanning microscope (CLSM) images showed that the incorporation of NaCas improved the interfacial coverage of the Pickering emulsions. When the zein:NaCas ratio ranged from 10:1 to 10:3, the interface was composed of zein/NaCas nullocomplexes. At a zein: NaCas ratio of 10:4, NaCas can competitively adsorbed to the interface and formed a hybrid interfacial structure. The Zein/NaCas nullocomplexes stabilized the Pickering emulsions and exhibited greater centrifugal stability than plain zein emulsions at most pHs and ionic strengths. The underlying mechanisms of the improved emulsion stability are discussed in this paper. This study explored a novel approach to stabilizing Pickering emulsions via the surface modification method using a food-grade protein. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 56, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 292, "End Page": 302, "Article Number": null, "DOI": "10.1016/j.foodhyd.2015.12.030", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2015.12.030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369987300032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, B; Zhang, H; Shao, HZ; Xu, YF; Zhang, RJ; Zhua, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Bo; Zhang, Hao; Shao, Hezhu; Xu, Yuanfeng; Zhang, Rongjun; Zhua, Heyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The electronic, optical, and thermodynamic properties of borophene from first-principles calculations", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Borophene (a two-dimensional boron sheet) is a new type of two-dimensional material, which was recently grown successfully on single crystal Ag substrates. In this paper, we investigate the electronic structure and bonding characteristics of borophene by first-principles calculations. The band structure of borophene shows highly anisotropic metallic behaviour. The obtained optical properties of borophene exhibit strong anisotropy as well. Finally, the thermodynamic properties are investigated based on the phonon properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 4, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3592, "End Page": 3598, "Article Number": null, "DOI": "10.1039/c6tc00115g", "DOI Link": "http://dx.doi.org/10.1039/c6tc00115g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374785300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, KJ; Qi, HY; Dong, RH; Shivhare, R; Addicoat, M; Zhang, T; Sahabudeen, H; Heine, T; Mannsfeld, S; Kaiser, U; Zheng, ZK; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kejun; Qi, Haoyuan; Dong, Renhao; Shivhare, Rishi; Addicoat, Matthew; Zhang, Tao; Sahabudeen, Hafeesudeen; Heine, Thomas; Mannsfeld, Stefan; Kaiser, Ute; Zheng, Zhikun; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-water surface synthesis of crystalline, few-layer two-dimensional polymers assisted by surfactant monolayers", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite rapid progress in recent years, it has remained challenging to prepare crystalline two-dimensional polymers. Here, we report the controlled synthesis of few-layer two-dimensional polyimide crystals on the surface of water through reaction between amine and anhydride monomers, assisted by surfactant monolayers. We obtained polymers with high crystallinity, thickness of similar to 2 nm and an average crystal domain size of similar to 3.5 mu m(2). The molecular structure of the materials, their grain boundaries and their edge structures were characterized using X-ray scattering and transmission electron microscopy techniques. These characterizations were supported by computations. The formation of crystalline polymers is attributed to the pre-organization of monomers at the water-surfactant interface. The surfactant, depending on its polar head, promoted the arrangement of the monomers-and in turn their polymerization-either horizontally or vertically with respect to the water surface. The latter was observed with a surfactant bearing a carboxylic acid group, which anchored amine monomers vertically through a condensation reaction. In both instances, micrometre-sized, few-layer two-dimensional polyamide crystals were grown.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 11, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 994, "End Page": 1000, "Article Number": null, "DOI": "10.1038/s41557-019-0327-5", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0327-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493326400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, XD; Zou, LF; Cao, X; Engelhard, MH; Liu, W; Burton, SD; Lee, H; Niu, CJ; Matthews, BE; Zhu, ZH; Wang, CM; Arey, BW; Xiao, J; Liu, J; Zhang, JG; Xu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xiaodi; Zou, Lianfeng; Cao, Xia; Engelhard, Mark H.; Liu, Wen; Burton, Sarah D.; Lee, Hongkyung; Niu, Chaojiang; Matthews, Bethany E.; Zhu, Zihua; Wang, Chongmin; Arey, Bruce W.; Xiao, Jie; Liu, Jun; Zhang, Ji-Guang; Xu, Wu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium (Li)-metal batteries (LMBs) offer a great opportunity for applications needing high-energy-density battery systems. However, rare progress has been demonstrated so far under practical conditions, including high voltage, high-loading cathode, thin Li anode, and lean electrolyte. Here, in opposition to common wisdom, we report an ether-based localized high-concentration electrolyte that can greatly enhance the stability of a Ni-rich LiNi0.8Mn0.1Co0.1O2 (NMC811) cathode under 4.4 and 4.5 V with an effective protection interphase enriched in LiF. This effect, in combination with the superior Li stability in this electrolyte, enables dramatically improved cycling performances of Li parallel to NMC811 batteries under highly challenging conditions. The LMBs can retain over 80% capacity in 150 stable cycles with extremely limited amounts of the Li anode and electrolyte. The findings in this work point out a very promising strategy to develop practical high-energy LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 728, "Times Cited, All Databases": 767, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1662, "End Page": 1676, "Article Number": null, "DOI": "10.1016/j.joule.2019.05.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.05.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476463300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, J; Tymchenko, M; Argyropoulos, C; Chen, PY; Lu, F; Demmerle, F; Boehm, G; Amann, MC; Alù, A; Belkin, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jongwon; Tymchenko, Mykhailo; Argyropoulos, Christos; Chen, Pai-Yen; Lu, Feng; Demmerle, Frederic; Boehm, Gerhard; Amann, Markus-Christian; Alu, Andrea; Belkin, Mikhail A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant nonlinear response from plasmonic metasurfaces coupled to intersubband transitions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intersubband transitions in n-doped multi-quantum-well semiconductor heterostructures make it possible to engineer one of the largest known nonlinear optical responses in condensed matter systems-but this nonlinear response is limited to light with electric field polarized normal to the semiconductor layers(1-7). In a different context, plasmonic metasurfaces (thin conductor-dielectric composite materials) have been proposed as a way of strongly enhancing light-matter interaction and realizing ultrathin planarized devices with exotic wave properties(8-11). Here we propose and experimentally realize metasurfaces with a record-high nonlinear response based on the coupling of electromagnetic modes in plasmonic metasurfaces with quantum-engineered electronic intersubband transitions in semiconductor heterostructures. We show that it is possible to engineer almost any element of the nonlinear susceptibility tensor of these structures, and we experimentally verify this concept by realizing a 400-nm-thick metasurface with nonlinear susceptibility of greater than 5 x 10(4) picometres per volt for second harmonic generation at a wavelength of about 8 micrometres under normal incidence. This susceptibility is many orders of magnitude larger than any second-order nonlinear response in optical metasurfaces measured so far(12-15). The proposed structures can act as ultrathin highly nonlinear optical elements that enable efficient frequency mixing with relaxed phase-matching conditions, ideal for realizing broadband frequency up-and down-conversions, phase conjugation and all-optical control and tunability over a surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 633, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2014, "Volume": 511, "Issue": 7507, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": "U389", "Article Number": null, "DOI": "10.1038/nature13455", "DOI Link": "http://dx.doi.org/10.1038/nature13455", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338199400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Han, JQ; Wang, H; Car, R; Weinull, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linfeng; Han, Jiequn; Wang, Han; Car, Roberto; Weinull, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Potential Molecular Dynamics: A Scalable Model with the Accuracy of Quantum Mechanics", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce a scheme for molecular simulations, the deep potential molecular dynamics (DPMD) method, based on a many-body potential and interatomic forces generated by a carefully crafted deep neural network trained with ab initio data. The neural network model preserves all the natural symmetries in the problem. It is first-principles based in the sense that there are no ad hoc components aside from the network model. We show that the proposed scheme provides an efficient and accurate protocol in a variety of systems, including bulk materials and molecules. In all these cases, DPMD gives results that are essentially indistinguishable from the original data, at a cost that scales linearly with system size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1319, "Times Cited, All Databases": 1452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2018, "Volume": 120, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 143001, "DOI": "10.1103/PhysRevLett.120.143001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.143001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429119100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Falke, SM; Rozzi, CA; Brida, D; Maiuri, M; Amato, M; Sommer, E; De Sio, A; Rubio, A; Cerullo, G; Molinari, E; Lienau, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Falke, Sarah Maria; Rozzi, Carlo Andrea; Brida, Daniele; Maiuri, Margherita; Amato, Michele; Sommer, Ephraim; De Sio, Antonietta; Rubio, Angel; Cerullo, Giulio; Molinari, Elisa; Lienau, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coherent ultrafast charge transfer in an organic photovoltaic blend", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Blends of conjugated polymers and fullerene derivatives are prototype systems for organic photovoltaic devices. The primary charge-generation mechanism involves a light-induced ultrafast electron transfer from the light-absorbing and electron-donating polymer to the fullerene electron acceptor. Here, we elucidate the initial quantum dynamics of this process. Experimentally, we observed coherent vibrational motion of the fullerene moiety after impulsive optical excitation of the polymer donor. Comparison with first-principle theoretical simulations evidences coherent electron transfer between donor and acceptor and oscillations of the transferred charge with a 25-femtosecond period matching that of the observed vibrational modes. Our results show that coherent vibronic coupling between electronic and nuclear degrees of freedom is of key importance in triggering charge delocalization and transfer in a noncovalently bound reference system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 530, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2014, "Volume": 344, "Issue": 6187, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1001, "End Page": 1005, "Article Number": null, "DOI": "10.1126/science.1249771", "DOI Link": "http://dx.doi.org/10.1126/science.1249771", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336495800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HF; Cao, YQ; Chen, L; Hu, YJ; Duan, XZ; Dai, S; Li, CZ; Jiang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Haifeng; Cao, Yueqiang; Chen, Long; Hu, Yanjie; Duan, Xuezhi; Dai, Sheng; Li, Chunzhong; Jiang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Critical barriers to layered Ni-rich cathode commercialisation include their rapid capacity fading and thermal runaway from crystal disintegration and their interfacial instability. Structure combines surface modification is the ultimate choice to overcome these. Here, a synchronous gradient Al-doped and LiAlO2-coated LiNi0.9Co0.1O2 cathode is designed and prepared by using an oxalate-assisted deposition and subsequent thermally driven diffusion method. Theoretical calculations, in situ X-ray diffraction results and finite-element simulation verify that Al3+ moves to the tetrahedral interstices prior to Ni2+ that eliminates the Li/Ni disorder and internal structure stress. The Li+-conductive LiAlO2 skin prevents electrolyte penetration of the boundaries and reduces side reactions. These help the Ni-rich cathode maintain a 97.4% cycle performance after 100 cycles, and a rapid charging ability of 127.7mAhg(-1) at 20C. A 3.5-Ah pouch cell with the cathode and graphite anode showed more than a 500-long cycle life with only a 5.6% capacity loss. The commercialisation of promising Ni-rich cathodes is limited by capacity fading and thermal runaway. Here, the authors design a gradient Al-doped and LiAlO2-coated LiNi0.9Co0.1O2 cathode, which addresses the crystal degradation and interfacial instability and thus improves the cycle and thermal stabilities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4564, "DOI": "10.1038/s41467-021-24893-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24893-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683367300027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, HJ; Du, W; Dong, J; Che, RC; Kong, F; Cheng, WL; Ma, M; Gu, N; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Haijiao; Du, Wei; Dong, Jian; Che, Renchao; Kong, Fei; Cheng, Wenlong; Ma, Ming; Gu, Ning; Zhang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Depletable peroxidase-like activity of Fe3O4 nullozymes accompanied with separate migration of electrons and iron ions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As pioneering Fe3O4 nullozymes, their explicit peroxidase (POD)-like catalytic mechanism remains elusive. Although many studies have proposed surface Fe2+-induced Fenton-like reactions accounting for their POD-like activity, few have focused on the internal atomic changes and their contribution to the catalytic reaction. Here we report that Fe2+ within Fe3O4 can transfer electrons to the surface via the Fe2+-O-Fe3+ chain, regenerating the surface Fe2+ and enabling a sustained POD-like catalytic reaction. This process usually occurs with the outward migration of excess oxidized Fe3+ from the lattice, which is a rate-limiting step. After prolonged catalysis, Fe3O4 nullozymes suffer the phase transformation to gamma-Fe2O3 with depletable POD-like activity. This self-depleting characteristic of nullozymes with internal atoms involved in electron transfer and ion migration is well validated on lithium iron phosphate nulloparticles. We reveal a neglected issue concerning the necessity of considering both surface and internal atoms when designing, modulating, and applying nullozymes. The mechanism of peroxidase-like Fe3O4 nullozymes remains elusive. Here, the authors show the electron transfer mechanism of Fe(II) ions to regenerate surface Fe(II) and the related phase transformation and depletion of activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5365, "DOI": "10.1038/s41467-022-33098-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33098-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853182100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, MH; Chandrasekhar, N; Raghupathy, RKM; Ly, KH; Zhang, HZ; Dmitrieva, E; Liang, CL; Lu, XH; Kühne, TD; Mirhosseini, H; Weidinger, IM; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Minghao; Chandrasekhar, Naisa; Raghupathy, Ramya Kormath Madam; Ly, Khoa Hoang; Zhang, Haozhe; Dmitrieva, Evgenia; Liang, Chaolun; Lu, Xihong; Kuehne, Thomas D.; Mirhosseini, Hossein; Weidinger, Inez M.; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A High-Rate Two-Dimensional Polyarylimide Covalent Organic Framework Anode for Aqueous Zn-Ion Energy Storage Devices", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous Zn-ion energy storage devices are promising candidates for next- generation energy storage technologies. However, the lack of highly reversible Zn2+-storage anode materials with low potential windows remains a primary concern. Here, we report a two-dimensional polyarylimide covalent organic framework (PI-COF) anode with high-kinetics Zn2+-storage capability. The well-organized pore channels of PI-COF allow the high accessibility of the build-in redox-active carbonyl groups and efficient ion diffusion with a low energy barrier. The constructed PI-COF anode exhibits a specific capacity (332 C g(-1) or 92 mAh g(-1) at 0.7 A g(-1)), a high rate capability (79.8% at 7 A g(-1)), and a long cycle life (85% over 4000 cycles). In situ Raman investigation and first-principle calculations clarify the two-step Zn2+-storage mechanism, in which imide carbonyl groups reversibly form negatively charged enolates. Dendrite-free full Zn-ion devices are fabricated by coupling PI-COF anodes with MnO2 cathodes, delivering excellent energy densities (23.9 similar to 66.5 Wh kg(-1)) and supercapacitor-level power densities (133 similar to 4782 W kg(-1)). This study demonstrates the feasibility of covalent organic framework as Zn2+-storage anodes and shows a promising prospect for constructing reliable aqueous energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2020, "Volume": 142, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19570, "End Page": 19578, "Article Number": null, "DOI": "10.1021/jacs.0c07992", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c07992", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592911000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, JC; He, S; Zhou, W; Shen, Z; Li, YY; Chen, MS; Zhang, QH; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Jincan; He, Shun; Zhou, Wei; Shen, Zheng; Li, Yangyang; Chen, Mingshu; Zhang, Qinghong; Wang, Ye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-pass transformation of syngas into ethanol with high selectivity by triple tandem catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthesis of ethanol from non-petroleum carbon resources via syngas (a mixture of H-2 and CO) is an important but challenging research target. The current conversion of syngas to ethanol suffers from low selectivity or multiple processes with high energy consumption. Here, we report a high-selective conversion of syngas into ethanol by a triple tandem catalysis. An efficient trifunctional tandem system composed of potassium-modified ZnO-ZrO2, modified zeolite mordenite and Pt-Sn/SiC working compatibly in syngas stream in one reactor can afford ethanol with a selectivity of 90%. We demonstrate that the K+-ZnO-ZrO2 catalyses syngas conversion to methanol and the mordenite with eight-membered ring channels functions for methanol carbonylation to acetic acid, which is then hydrogenated to ethanol over the Pt-Sn/SiC catalyst. The present work offers an effective methodology leading to high selective conversion by decoupling a single-catalyst-based complicated and uncontrollable reaction into well-controlled multi-steps in tandem in one reactor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 827, "DOI": "10.1038/s41467-020-14672-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14672-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514433900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krishnaraj, C; Jena, HS; Bourda, L; Laemont, A; Pachfule, P; Roeser, J; Chandran, CV; Borgmans, S; Rogge, SMJ; Leus, K; Stevens, CV; Martens, JA; Van Speybroeck, V; Breynaert, E; Thomas, A; Van der Voort, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krishnaraj, Chidharth; Jena, Himanshu Sekhar; Bourda, Laurens; Laemont, Andreas; Pachfule, Pradip; Roeser, Jerome; Chandran, C. Vinod; Borgmans, Sander; Rogge, Sven M. J.; Leus, Karen; Stevens, Christian, V; Martens, Johan A.; Van Speybroeck, Veronique; Breynaert, Eric; Thomas, Arne; Van der Voort, Pascal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H2O2 Generation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reduction of molecular oxygen is a promising route toward sustainable production of hydrogen peroxide (H2O2). This challenging process requires photoactive semiconductors enabling solar energy driven generation and separation of electrons and holes with high charge transfer kinetics. Covalent organic frameworks (COFs) are an emerging class of photoactive semiconductors, tunable at a molecular level for high charge carrier generation and transfer. Herein, we report two newly designed two-dimensional COFs based on a (diarylamino)benzene linker that form a Kagome (kgm) lattice and show strong visible light absorption. Their high crystallinity and large surface areas (up to 1165 m(2)center dot g(-1)) allow efficient charge transfer and diffusion. The diarylamine (donor) unit promotes strong reduction properties, enabling these COFs to efficiently reduce oxygen to form H2O2. Overall, the use of a metal-free, recyclable photocatalytic system allows efficient photocatalytic solar transformations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2020, "Volume": 142, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20107, "End Page": 20116, "Article Number": null, "DOI": "10.1021/jacs.0c09684", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c09684", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595544800043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, Z; Yu, DW; Yang, Y; Su, C; Huang, YM; Dong, YH; Waluyo, I; Wang, BM; Hunt, A; Yao, XH; Lee, J; Xue, WJ; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zhi; Yu, Daiwei; Yang, Yang; Su, Cong; Huang, Yimeng; Dong, Yanhao; Waluyo, Iradwikanari; Wang, Baoming; Hunt, Adrian; Yao, Xiahui; Lee, Jinhyuk; Xue, Weijiang; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-rich transition metal oxide (Li1+xM1-xO2) cathodes have high energy density above 900 Wh kg(-1) due to hybrid anion- and cation-redox (HACR) contributions, but critical issues such as oxygen release and voltage decay during cycling have prevented their application for years. Here we show that a molten molybdate-assisted LiO extraction at 700 degrees C creates lattice-coherent but depth (r)-dependent Li1+x(r)M1-x(r)O2 particles with a Li-rich (X approximate to 0.2) interior, a Li-poor (X approximate to -0.05) surface and a continuous gradient in between. The gradient Li-rich single crystals eliminate the oxygen release to the electrolyte and, importantly, still allow stable oxygen redox contributions within. Both the metal valence states and the crystal structure are well maintained during cycling. The gradient HACR cathode displays a specific density of 843 Wh kg(-1) after 200 cycles at 0.2C and 808 Wh kg(-1) after 100 cycles at 1C, with very little oxygen release and consumption of electrolyte. This high-temperature immunization treatment can be generalized to leach other elements to avoid unexpected surface reactions in batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1049, "End Page": 1058, "Article Number": null, "DOI": "10.1038/s41560-019-0508-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0508-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502574200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kong, LM; Zhang, XY; Li, YG; Wang, HR; Jiang, YZ; Wang, S; You, MQ; Zhang, CX; Zhang, T; Kershaw, SV; Zheng, WT; Yang, YG; Lin, QQ; Yuan, MJ; Rogach, AL; Yang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kong, Lingmei; Zhang, Xiaoyu; Li, Yunguo; Wang, Haoran; Jiang, Yuanzhi; Wang, Sheng; You, Mengqing; Zhang, Chengxi; Zhang, Ting; Kershaw, Stephen V.; Zheng, Weitao; Yang, Yingguo; Lin, Qianqian; Yuan, Mingjian; Rogach, Andrey L.; Yang, Xuyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smoothing the energy transfer pathway in quasi-2D perovskite films using methanesulfonate leads to highly efficient light-emitting devices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quasi-two-dimensional (quasi-2D) Ruddlesden-Popper (RP) perovskites such as BA(2)Cs(n-1)Pb(n)Br(3n+1) (BA=butylammonium, n>1) are promising emitters, but their electroluminescence performance is limited by a severe non-radiative recombination during the energy transfer process. Here, we make use of methanesulfonate (MeS) that can interact with the spacer BA cations via strong hydrogen bonding interaction to reconstruct the quasi-2D perovskite structure, which increases the energy acceptor-to-donor ratio and enhances the energy transfer in perovskite films, thus improving the light emission efficiency. MeS additives also lower the defect density in RP perovskites, which is due to the elimination of uncoordinated Pb2+ by the electron-rich Lewis base MeS and the weakened adsorbate blocking effect. As a result, green light-emitting diodes fabricated using these quasi-2D RP perovskite films reach current efficiency of 63cdA(-1) and 20.5% external quantum efficiency, which are the best reported performance for devices based on quasi-2D perovskites so far. Owing to large exciton binding energy, quasi-2D perovskite is promising for light-emitting application, yet inhomogeneous phases distribution limits the potential. Here, the authors improve the performance by using MeS additive to regulate the phase distribution and to reduce defect density in the films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1246, "DOI": "10.1038/s41467-021-21522-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21522-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623781900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, YX; Ma, ZL; Lin, RB; Krishna, R; Zhou, W; Lin, QJ; Zhang, ZJ; Xiang, SC; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Yingxiang; Ma, Zhenlin; Lin, Rui-Biao; Krishna, Rajamani; Zhou, Wei; Lin, Quanjie; Zhang, Zhangjing; Xiang, Shengchang; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore Space Partition within a Metal-Organic Framework for Highly Efficient C2H2/CO2 Separation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pore space partition (PSP) approach has been employed to realize a novel porous MOF (FJU-90) with dual functionalities for the challenging C2H2/CO2 separation under ambient conditions. By virtue of a triangular ligand (Tripp = 2,4,6-tris(4-pyridyl)pyridine), the cylindrical channels in the original FJU-88 have been partitioned into uniformly interconnected pore cavities, leading to the dramatically reduced pore apertures from 12.0 X 9.4 to 5.4 X 5.1 angstrom(2). Narrowing down the pore sizes, the resulting activated FJU-90a takes up a very large amount of C2H2 (180 cm(3) g(-1)) but much less of CO2 (103 cm(3) g(-1)) at 298 K and 1 bar, demonstrating it to be the best porous MOF material for this C2H2/CO2 (50%:50%) separation in terms of the C2H2 gravimetric productivity. IAST calculations, molecular modeling studies, and simulated and experimental breakthrough experiments comprehensively demonstrate that the pore space partition strategy is a very powerful approach to constructing MOFs with dual functionality for challenging gas separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 141, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4130, "End Page": 4136, "Article Number": null, "DOI": "10.1021/jacs.9b00232", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00232", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460996500052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaspar, C; Ravoo, BJ; van der Wiel, WG; Wegner, SV; Pernice, WHP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kaspar, C.; Ravoo, B. J.; van der Wiel, W. G.; Wegner, S. V.; Pernice, W. H. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The rise of intelligent matter", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial intelligence (AI) is accelerating the development of unconventional computing paradigms inspired by the abilities and energy efficiency of the brain. The human brain excels especially in computationally intensive cognitive tasks, such as pattern recognition and classification. A long-term goal is de-centralized neuromorphic computing, relying on a network of distributed cores to mimic the massive parallelism of the brain, thus rigorously following a nature-inspired approach for information processing. Through the gradual transformation of interconnected computing blocks into continuous computing tissue, the development of advanced forms of matter exhibiting basic features of intelligence can be envisioned, able to learn and process information in a delocalized manner. Such intelligent matter would interact with the environment by receiving and responding to external stimuli, while internally adapting its structure to enable the distribution and storage (as memory) of information. We review progress towards implementations of intelligent matter using molecular systems, soft materials or solid-state materials, with respect to applications in soft robotics, the development of adaptive artificial skins and distributed neuromorphic computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2021, "Volume": 594, "Issue": 7863, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 355, "Article Number": null, "DOI": "10.1038/s41586-021-03453-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03453-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662887700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peters, BK; Rodriguez, KX; Reisberg, SH; Beil, SB; Hickey, DP; Kawamata, Y; Collins, M; Starr, J; Chen, LR; Udyavara, S; Klunder, K; Gorey, TJ; Anderson, SL; Neurock, M; Minteer, SD; Baran, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peters, Byron K.; Rodriguez, Kevin X.; Reisberg, Solomon H.; Beil, Sebastian B.; Hickey, David P.; Kawamata, Yu; Collins, Michael; Starr, Jeremy; Chen, Longrui; Udyavara, Sagar; Klunder, Kevin; Gorey, Timothy J.; Anderson, Scott L.; Neurock, Matthew; Minteer, Shelley D.; Baran, Phil S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistry", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reductive electrosynthesis has faced long-standing challenges in applications to complex organic substrates at scale. Here, we show how decades of research in lithium-ion battery materials, electrolytes, and additives can serve as an inspiration for achieving practically scalable reductive electrosynthetic conditions for the Birch reduction. Specifically, we demonstrate that using a sacrificial anode material (magnesium or aluminum), combined with a cheap, nontoxic, and water-soluble proton source (dimethylurea), and an overcharge protectant inspired by battery technology [tris(pyrrolidino) phosphoramide] can allow for multigram-scale synthesis of pharmaceutically relevant building blocks. We show how these conditions have a very high level of functional-group tolerance relative to classical electrochemical and chemical dissolving-metal reductions. Finally, we demonstrate that the same electrochemical conditions can be applied to other dissolving metal-type reductive transformations, including McMurry couplings, reductive ketone deoxygenations, and epoxide openings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 363, "Issue": 6429, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 838, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav5606", "DOI Link": "http://dx.doi.org/10.1126/science.aav5606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459387100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JH; Huang, W; Zheng, D; Xie, ZQ; Zhuang, XM; Zhao, D; Chen, Y; Su, N; Chen, HM; Pankow, RM; Gao, Z; Yu, JS; Guo, XG; Cheng, YH; Strzalka, J; Yu, XG; Marks, TJ; Facchetti, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jianhua; Huang, Wei; Zheng, Ding; Xie, Zhaoqian; Zhuang, Xinming; Zhao, Dan; Chen, Yao; Su, Ning; Chen, Hongming; Pankow, Robert M.; Gao, Zhan; Yu, Junsheng; Guo, Xugang; Cheng, Yuhua; Strzalka, Joseph; Yu, Xinge; Marks, Tobin J.; Facchetti, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stretchable organic electrochemical transistors with strain-resistant performance", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing fully stretchable electronic materials is central to advancing new types of mechanically agile and skin-integrable optoelectronic device technologies. Here we demonstrate a materials design concept combining an organic semiconductor film with a honeycomb porous structure with biaxially prestretched platform that enables high-performance organic electrochemical transistors with a charge transport stability over 30-140% tensional strain, limited only by metal contact fatigue. The prestretched honeycomb semiconductor channel of donor-acceptor polymer poly(2,5-bis(2-octyldodecyl)-3,6-di(thiophen-2-yl)-2,5-diketo-pyrrolopyrrole-alt-2,5-bis(3-triethyleneglycoloxy-thiophen-2-yl) exhibits high ion uptake and completely stable electrochemical and mechanical properties over 1,500 redox cycles with 10(4) stretching cycles under 30% strain. Invariant electrocardiogram recording cycles and synapse responses under varying strains, along with mechanical finite element analysis, underscore that the present stretchable organic electrochemical transistor design strategy is suitable for diverse applications requiring stable signal output under deformation with low power dissipation and mechanical robustness. Highly stretchable organic electrochemical transistors with stable charge transport under severe tensional strains are demonstrated using a honeycomb semiconducting polymer morphology, thereby enabling controllable signal output for diverse stretchable bioelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 21, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 564, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01239-9", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01239-9", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789755400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, ZL; Gong, H; Gao, M; Zhu, WW; Sun, XQ; Feng, LZ; Fu, TT; Li, YG; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Ziliang; Gong, Hua; Gao, Min; Zhu, Wenwen; Sun, Xiaoqi; Feng, Liangzhu; Fu, Tingting; Li, Yonggang; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine nulloparticles as a Versatile Molecular Loading Platform to Enable Imaging-guided Cancer Combination Therapy", "Source Title": "THERANOSTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cancer combination therapy to treat tumors with different therapeutic approaches can efficiently improve treatment efficacy and reduce side effects. Herein, we develop a theranostic nullo-platform based on polydopamine (PDA) nulloparticles, which then are exploited as a versatile carrier to allow simultaneous loading of indocyanine green (ICG), doxorubicin (DOX) and manganese ions (PDA-ICG-PEG/DOX(Mn)), to enable imaging-guided chemo & photothermal cancer therapy. In this system, ICG acts as a photothermal agent, which shows red-shifted near-infrared (NIR) absorbance and enhanced photostability compared with free ICG. DOX, a model chemotherapy drug, is then loaded onto the surface of PDA-ICG-PEG with high efficiency. With Mn2+ ions intrinsically chelated, PDA-ICG-PEG/DOX(Mn) is able to offer contrast under T1-weighted magnetic resonullce (MR) imaging. In a mouse tumor model, the MR imaging-guided combined chemo- & photothermal therapy achieves a remarkable synergistic therapeutic effect compared with the respective single treatment modality. This work demonstrates that PDA nulloparticles could serve as a versatile molecular loading platform for MR imaging guided combined chemo- & photothermal therapy with minimal side effects, showing great potential for cancer theranostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1031, "End Page": 1042, "Article Number": null, "DOI": "10.7150/thno.14431", "DOI Link": "http://dx.doi.org/10.7150/thno.14431", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377799600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bisbey, RP; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bisbey, Ryan P.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent Organic Frameworks as a Platform for Multidimensional Polymerization", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The simultaneous polymerization and crystallization of monomers featuring directional bonding designs provides covalent organic frameworks (COFs), which are periodic polymer networks with robust covalent bonds arranged in two or three-dimensional topologies. The range of properties characterized in COFs has rapidly expanded to include those of interest for heterogeneous catalysis, energy storage and photovoltaic devices, and proton-conducting membranes. Yet many of these applications will require materials quality, morphological control, and synthetic efficiency exceeding the capabilities of contemporary synthetic methods. This level of control will emerge from an improved fundamental understanding of COF nucleation and growth processes. More powerful characterization of structure and defects, improved syntheses guided by mechanistic understanding, and accessing diverse isolated forms, ranging from single crystals to thin films to colloidal suspensions, remain important frontier problems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 533, "End Page": 543, "Article Number": null, "DOI": "10.1021/acscentsci.7b00127", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00127", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404825000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YJ; Li, P; Zhou, JW; Buru, CT; Dordevic, L; Li, PH; Zhang, X; Cetin, MM; Stoddart, JF; Stupp, SI; Wasielewski, MR; Farha, OK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yijing; Li, Peng; Zhou, Jiawang; Buru, Cassandra T.; Dordevic, Luka; Li, Penghao; Zhang, Xuan; Cetin, M. Mustafa; Stoddart, J. Fraser; Stupp, Samuel I.; Wasielewski, Michael R.; Farha, Omar K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of Enzymes and Photosensitizers in a Hierarchical Mesoporous Metal-Organic Framework for Light-Driven CO2 Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Protection of enzymes with synthetic materials is a viable strategy to stabilize, and hence to retain, the reactivity of these highly active biomolecules in non-native environments. Active synthetic supports, coupled to encapsulated enzymes, can enable efficient cascade reactions which are necessary for processes like light-driven CO2 reduction, providing a promising pathway for alternative energy generation. Herein, a semi-artificial system-containing an immobilized enzyme, formate dehydrogenase, in a light harvesting scaffold-is reported for the conversion of CO2 to formic acid using white light. The electron-mediator Cp*Rh(2,2'-bipyridyl-5,5'-dicarboxylic acid)Cl was anchored to the nodes of the metal-organic framework NU-1006 to facilitate ultrafast photoinduced electron transfer when irradiated, leading to the reduction of the coenzyme nicotinamide adenine dinucleotide at a rate of about 28 mM.h(-1). Most importantly, the immobilized enzyme utilizes the reduced coenzyme to generate formic acid selectively from CO2 at a high turnover frequency of about 865 h(-1) in 24 h. The outcome of this research is the demonstration of a feasible pathway for solar-driven carbon fixation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2020, "Volume": 142, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1768, "End Page": 1773, "Article Number": null, "DOI": "10.1021/jacs.9b12828", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12828", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510531900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "García, G; Aparicio, S; Ullah, R; Atilhan, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garcia, Gregorio; Aparicio, Santiago; Ullah, Ruh; Atilhan, Mert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications", "Source Title": "ENERGY & FUELS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable technologies applied to energy-related applications should develop a pivotal role in the next decades. In particular, carbon dioxide capture from flue gases emitted by fossil-fueled power plants should play a pivotal role in controlling and reducing the greenhouse effect. Therefore, the development of new materials for carbon capture purposes has merged as central research line, for which many alternatives have been proposed. Ionic liquids (ILs) have emerged as one of the most promising choices for carbon capture, but in spite of their promising properties, some serious drawbacks have also appeared. Deep eutectic solvents (DESs) have recently been considered as alternatives to ILs that maintain most of their relevant properties, such as task-specific character, and at the same time avoid some of their problems, mainly from economic and environmental viewpoints. DES production from low-cost and natural sources, together with their almost null toxicity and total biodegradability, makes these solvents a suitable platform for developing gas separation agents within the green chemistry framework. Therefore, because of the promising characteristics of DESs as CO2 absorbents and in general as gas separating agents, the state of the art on physicochemical properties of DESs in relationship to their influence on gas separation mechanisms and on the studies of gas solubility in DESs are discussed. The objective of this review work is to analyze the current knowledge on gas separation using DESs, comparing the capturing abilities and properties of DESs with those of ILs, inferring the weaknesses and strengths of DESs, and proposing future research directions on this subject.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 812, "Times Cited, All Databases": 866, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 29, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2616, "End Page": 2644, "Article Number": null, "DOI": "10.1021/ef5028873", "DOI Link": "http://dx.doi.org/10.1021/ef5028873", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353251800062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Youssef, KM; Zaddach, AJ; Niu, CN; Irving, DL; Koch, CC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Youssef, Khaled M.; Zaddach, Alexander J.; Niu, Changning; Irving, Douglas L.; Koch, Carl C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Low-Density, High-Hardness, High-entropy Alloy with Close-packed Single-phase nullocrystalline Structures", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A low-density, nullocrystalline high-entropy alloy, Al20Li20Mg10Sc20Ti30 was produced by mechanical alloying. It formed a single-phase fcc structure during ball milling and transformed to single-phase hcp upon annealing. The alloy has an estimated strength-to-weight ratio that is significantly higher than other nullocrystalline alloys and is comparable to ceramics. High hardness is retained after annealing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 496, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 95, "End Page": 99, "Article Number": null, "DOI": "10.1080/21663831.2014.985855", "DOI Link": "http://dx.doi.org/10.1080/21663831.2014.985855", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372218500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Köpf, M; Eckstein, N; Pfister, D; Grotz, C; Krüger, I; Greiwe, M; Hansen, T; Kohlmann, H; Nilges, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koepf, Marianne; Eckstein, Nadine; Pfister, Daniela; Grotz, Carolin; Krueger, Ilona; Greiwe, Magnus; Hansen, Thomas; Kohlmann, Holger; Nilges, Tom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Access and in situ growth of phosphorene-precursor black phosphorus", "Source Title": "JOURNAL OF CRYSTAL GROWTH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals of orthorhombic black phosphorus can be grown by a short way transport reaction from red phosphorus and Sn/SnI4 as mineralization additive. Sizes of several millimeters can be realized with high crystal quality and purity, making a large area preparation of single or multilayer phosphorene possible. An in situ neutron diffraction study was performed addressing the formation of black phosphorus. Black phosphorus is formed directly via gas phase without the occurrence of any other intermediate phase. Crystal growth was initiated after cooling the starting materials down from elevated temperatures at 500 degrees C. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2014, "Volume": 405, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6, "End Page": 10, "Article Number": null, "DOI": "10.1016/j.jcrysgro.2014.07.029", "DOI Link": "http://dx.doi.org/10.1016/j.jcrysgro.2014.07.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Crystallography; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341416200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, ZQ; Zhuang, TT; Seifitokaldani, A; Li, J; Huang, CW; Tan, CS; Li, Y; De Luna, P; Dinh, CT; Hu, YF; Xiao, QF; Hsieh, PL; Wang, YH; Li, FW; Quintero-Bermudez, R; Zhou, YS; Chen, PN; Pang, YJ; Lo, SC; Chen, LJ; Tan, HR; Xu, Z; Zhao, SL; Sinton, D; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Zhi-Qin; Zhuang, Tao-Tao; Seifitokaldani, Ali; Li, Jun; Huang, Chun-Wei; Tan, Chih-Shan; Li, Yi; De Luna, Phil; Dinh, Cao Thang; Hu, Yongfeng; Xiao, Qunfeng; Hsieh, Pei-Lun; Wang, Yuhang; Li, Fengwang; Quintero-Bermudez, Rafael; Zhou, Yansong; Chen, Peining; Pang, Yuanjie; Lo, Shen-Chuan; Chen, Lih-Juann; Tan, Hairen; Xu, Zheng; Zhao, Suling; Sinton, David; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-based materials are promising electrocatalysts for CO2 reduction. Prior studies show that the mixture of copper (I) and copper (0) at the catalyst surface enhances multi-carbon products from CO2 reduction; however, the stable presence of copper (I) remains the subject of debate. Here we report a copper on copper (I) composite that stabilizes copper (I) during CO2 reduction through the use of copper nitride as an underlying copper (I) species. We synthesize a copper-on-nitride catalyst that exhibits a Faradaic efficiency of 64 +/- 2% for C2+ products. We achieve a 40-fold enhancement in the ratio of C2+ to the competing CH4 compared to the case of pure copper. We further show that the copper-on-nitride catalyst performs stable CO2 reduction over 30 h. Mechanistic studies suggest that the use of copper nitride contributes to reducing the CO dimerization energy barrier-a rate-limiting step in CO2 reduction to multi-carbon products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3828, "DOI": "10.1038/s41467-018-06311-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06311-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445063700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PJ; Xie, XS; Xing, ZY; Chen, XH; Fang, GZ; Lu, BA; Zhou, J; Liang, SQ; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pinji; Xie, Xuesong; Xing, Zhenyue; Chen, Xianhong; Fang, Guozhao; Lu, Bingan; Zhou, Jiang; Liang, Shuquan; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanistic Insights of Mg2+-Electrolyte Additive for High-Energy and Long-Life Zinc-Ion Hybrid Capacitors", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An electrolyte cation additive strategy provides a versatile route for developing high-energy and long-life aqueous zinc-ion hybrid capacitors. However, the mechanisms of energy storage and Zn anode protection are still unclear in Zn-based systems with dual-ion electrolytes. Here, a dual charge storage mechanism for zinc-ion hybrid capacitors with both cations and anions adsorption/desorption and the reversible formation of Zn4SO4(OH)(6)center dot xH(2)O enabled by the Mg2+ additive in the common aqueous ZnSO4 electrolyte are proposed. Theoretical calculations verify that the self-healing electrostatic shield effect and the solvation-sheath structure regulation rendered by the Mg2+ additive account for the observed uniform Zn deposition and dendrite suppression. As a result, an additional energy storage capacity of approximate to 50% compared to that in a pure 2 m ZnSO4 electrolyte and an extended cycle life with capacity retention of 98.7% after 10 000 cycles are achieved. This work highlights the effectiveness of electrolyte design for dual-ion carrier storage mechanism in aqueous devices toward high energy density and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 11, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101158, "DOI": "10.1002/aenm.202101158", "DOI Link": "http://dx.doi.org/10.1002/aenm.202101158", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663276800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dang, VD; Annadurai, T; Khedulkar, AP; Lin, JY; Adorna, A; Yu, WJ; Pandit, B; Huynh, TV; Doong, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dang, Van Dien; Annadurai, Thamilselvan; Khedulkar, Akhil Pradiprao; Lin, Jui-Yen; Adorna Jr, Joemer; Yu, Wan-Ju; Pandit, Bidhan; Huynh, Trung Viet; Doong, Ruey-An", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-scheme N-doped carbon dots anchored g-C3N4/Fe2O3 shell/core composite for photoelectrocatalytic trimethoprim degradation and water splitting", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrocatalysis is a promising technique for energy conversion and environmental treatment. This study describes the photoelectrochemical (PEC) degradation of trimethoprim and hydrogen evolution using a photo-anode prepared by N-doped carbon dots (NCD) incorporated g-C3N4/alpha-Fe2O3 (CNFO) shell/core nullocomposite. The electrochemical analysis reveals that the photocurrent density of NCD@CNFO photoanode reached 3.07 mA cm(-2) at 1.6 V vs. NHE, which is 4 and 15 times greater than that of CNFO and intact alpha-Fe2O3, respectively. In the presence of peroxymonosulfate (PMS), the NCD@CNFO photoanode enabled 95 % and 90 % of trimethoprim (TMP) degradation in aqueous solution and lake water, respectively. Hydrogen generation coupled with TMP degradation was also observed in the PEC system, where the H-2 generation rate was 550 mu mol cm(-2) h(-1). Both superoxide (O-center dot(2)-) and hydroxyl ((OH)-O-center dot) radicals played a significant role in the degradation of TMP. The achievements could be assigned to the excellent photoabsorption and electron transfer properties of NCD, which enhanced the PEC activity of CNFO by enabling the S-scheme heterojunction to reduce electron-hole recombination. Moreover, PMS served as a cathodic electron acceptor to improve the catalytic properties of NCD@CNFO photoanode, demonstrating its contribution to both water treatment and hydrogen production. Such superior efficiency offers great potential to develop a PEC system using carbon dots/semiconductor hybrid catalysts for antibiotic degradation and synchronous photocatalytic H-2 evolution from wastewater, providing an alternative solution to environmental pollution and energy crisis issues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 320, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121928, "DOI": "10.1016/j.apcatb.2022.121928", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2022.121928", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000865432900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Lu, LL; Zhu, HL; Chen, YG; Huang, Y; Li, YD; Wang, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Lin; Lu, Lilin; Zhu, Hengli; Chen, Yueguang; Huang, Yu; Li, Yadong; Wang, Leyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved ethanol electrooxidation performance by shortening Pd-Ni active site distance in Pd-Ni-P nullocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Incorporating oxophilic metals into noble metal-based catalysts represents an emerging strategy to improve the catalytic performance of electrocatalysts in fuel cells. However, effects of the distance between the noble metal and oxophilic metal active sites on the catalytic performance have rarely been investigated. Herein, we report on ultrasmall (similar to 5 nm) Pd-Ni-P ternary nulloparticles for ethanol electrooxidation. The activity is improved up to 4.95A per mg(Pd), which is 6.88 times higher than commercial Pd/C (0.72A per mgPd), by shortening the distance between Pd and Ni active sites, achieved through shape transformation from Pd/Ni-P heterodimers into Pd-Ni-P nulloparticles and tuning the Ni/Pd atomic ratio to 1:1. Density functional theory calculations reveal that the improved activity and stability stems from the promoted production of free OH radicals (on Ni active sites) which facilitate the oxidative removal of carbonaceous poison and combination with CH3CO radicals on adjacent Pd active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14136, "DOI": "10.1038/ncomms14136", "DOI Link": "http://dx.doi.org/10.1038/ncomms14136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392120400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, BL; Köpf, M; Abbas, AN; Wang, XM; Guo, QS; Jia, YC; Xia, FN; Weihrich, R; Bachhuber, F; Pielnhofer, F; Wang, H; Dhall, R; Cronin, SB; Ge, MY; Fang, X; Nilges, T; Zhou, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Bilu; Koepf, Marianne; Abbas, Ahmad N.; Wang, Xiaomu; Guo, Qiushi; Jia, Yichen; Xia, Fengnian; Weihrich, Richard; Bachhuber, Frederik; Pielnhofer, Florian; Wang, Han; Dhall, Rohan; Cronin, Stephen B.; Ge, Mingyuan; Fang, Xin; Nilges, Tom; Zhou, Chongwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Arsenic-Phosphorus: Layered Anisotropic Infrared Semiconductors with Highly Tunable Compositions and Properties", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New layered anisotropic infrared semiconductors, black arsenic-phosphorus (b-AsP), with highly tunable chemical compositions and electronic and optical properties are introduced. Transport and infrared absorption studies demonstrate the semiconducting nature of b-AsP with tunable bandgaps, ranging from 0.3 to 0.15 eV. These bandgaps fall into the long-wavelength infrared regime and cannot be readily reached by other layered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2015, "Volume": 27, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4423, "End Page": 4429, "Article Number": null, "DOI": "10.1002/adma.201501758", "DOI Link": "http://dx.doi.org/10.1002/adma.201501758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359347300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, T; Zhao, YL; Li, WP; Yu, CY; Luan, JH; Lin, DY; Fan, L; Jiao, ZB; Liu, WH; Liu, XJ; Kai, JJ; Huang, JC; Liu, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, T.; Zhao, Y. L.; Li, W. P.; Yu, C. Y.; Luan, J. H.; Lin, D. Y.; Fan, L.; Jiao, Z. B.; Liu, W. H.; Liu, X. J.; Kai, J. J.; Huang, J. C.; Liu, C. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-strength and ductile superlattice alloys with nulloscale disordered interfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alloys that have high strengths at high temperatures are crucial for a variety of important industries including aerospace. Alloys with ordered superlattice structures are attractive for this purpose but generally suffer from poor ductility and rapid grain coarsening. We discovered that nulloscale disordered interfaces can effectively overcome these problems. Interfacial disordering is driven by multielement cosegregation that creates a distinctive nullolayer between adjacent micrometer-scale superlattice grains. This nullolayer acts as a sustainable ductilizing source, which prevents brittle intergranular fractures by enhancing dislocation mobilities. Our superlattice materials have ultrahigh strengths of 1.6 gigapascals with tensile ductilities of 25% at ambient temperature. Simultaneously, we achieved negligible grain coarsening with exceptional softening resistance at elevated temperatures. Designing similar nullolayers may open a pathway for further optimization of alloy properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2020, "Volume": 369, "Issue": 6502, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 427, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb6830", "DOI Link": "http://dx.doi.org/10.1126/science.abb6830", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556265800042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, YT; Tang, L; Khan, U; Yu, QM; Cheng, HM; Zou, XL; Liu, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Yuting; Tang, Lei; Khan, Usman; Yu, Qiangmin; Cheng, Hui-Ming; Zou, Xiaolong; Liu, Bilu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphology and surface chemistry engineering toward pH-universal catalysts for hydrogen evolution at high current density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale implementation of electrochemical hydrogen production requires several fundamental issues to be solved, including understanding the mechanism and developing inexpensive electrocatalysts that work well at high current densities. Here we address these challenges by exploring the roles of morphology and surface chemistry, and develop inexpensive and efficient electrocatalysts for hydrogen evolution. Three model electrocatalysts are flat platinum foil, molybdenum disulfide microspheres, and molybdenum disulfide microspheres modified by molybdenum carbide nulloparticles. The last catalyst is highly active for hydrogen evolution independent of pH, with low overpotentials of 227 mV in acidic medium and 220 mV in alkaline medium at a high current density of 1000 mA cm(-2), because of enhanced transfer of mass (reactants and hydrogen bubbles) and fast reaction kinetics due to surface oxygen groups formed on molybdenum carbide during hydrogen evolution. Our work may guide rational design of electrocatalysts that work well at high current densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 576, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 269, "DOI": "10.1038/s41467-018-07792-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07792-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455953600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aubin, CA; Gorissen, B; Milana, E; Buskohl, PR; Lazarus, N; Slipher, GA; Keplinger, C; Bongard, J; Iida, F; Lewis, JA; Shepherd, RF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aubin, Cameron A.; Gorissen, Benjamin; Milana, Edoardo; Buskohl, Philip R.; Lazarus, Nathan; Slipher, Geoffrey A.; Keplinger, Christoph; Bongard, Josh; Iida, Fumiya; Lewis, Jennifer A.; Shepherd, Robert F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards enduring autonomous robots via embodied energy", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Autonomous robots comprise actuation, energy, sensory and control systems built from materials and structures that are not necessarily designed and integrated for multifunctionality. Yet, animals and other organisms that robots strive to emulate contain highly sophisticated and interconnected systems at all organizational levels, which allow multiple functions to be performed simultaneously. Herein, we examine how system integration and multifunctionality in nature inspires a new paradigm for autonomous robots that we call Embodied Energy. Whereas most untethered robots use batteries to store energy and power their operation, recent advancements in energy-storage techniques enable chemical or electrical energy sources to be embodied directly within the structures and materials used to create robots, rather than requiring separate battery packs. This perspective highlights emerging examples of Embodied Energy in the context of developing autonomous robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2022, "Volume": 602, "Issue": 7897, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 393, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04138-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04138-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756892700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, C; Zhang, M; Stern, B; Lipson, M; Loncar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Cheng; Zhang, Mian; Stern, Brian; Lipson, Michal; Loncar, Marko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullophotonic lithium niobate electro-optic modulators", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the emergence of optical fiber communications, lithium niobate (LN) has been the material of choice for electro-optic modulators, featuring high data bandwidth and excellent signal fidelity. Conventional LN modulators however are bulky, expensive and power hungry, and cannot meet the growing demand in modern optical data links. Chip-scale, highly integrated, LN modulators could offer solutions to this problem, yet the fabrication of low-loss devices in LN thin films has been challenging. Here we overcome this hurdle and demonstrate monolithically integrated LN electro-optic modulators that are significantly smaller and more efficient than traditional bulk LN devices, while preserving LN's excellent material properties. Our compact LN electro-optic platform consists of low-loss nulloscale LN waveguides, micro-ring resonators and miniaturized Mach-Zehnder interferometers, fabricated by directly shaping LN thin films into sub-wavelength structures. The efficient confinement of both optical and microwave fields at the nulloscale dramatically improves the device performances featuring a half-wave electro-optic modulation efficiency of 1.8 V center dot cm while operating at data rates up to 40 Gbps. Our monolithic LN nullophotonic platform enables dense integration of high-performance active components, opening new avenues for future high-speed, low power and cost-effective communication networks. (c) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 564, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2018, "Volume": 26, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1547, "End Page": 1555, "Article Number": null, "DOI": "10.1364/OE.26.001547", "DOI Link": "http://dx.doi.org/10.1364/OE.26.001547", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422935900106", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Langdon, J; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Langdon, Jayse; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A perspective on single-crystal layered oxide cathodes for lithium-ion batteries", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-vehicle and grid-storage markets, the need for higher energy density and longer cycle life becomes more apparent. Increasing the nickel content in the layered-oxide cathodes has been a dominullt strategy to increase energy density, but this has exacerbated the surface reactivity concerns. Furthermore, the high states of charge associated with increased capacity lead to cracking of the polycrystalline cathode particles, which exposes fresh surfaces and accelerates capacity fade. Single-crystal cathode particles with low susceptibility to cracking have recently taken on intense interest due to their remarkable cyclability. Many different approaches to single-crystal synthesis have been explored, but there has been no systematic analysis of the different techniques to date. Furthermore, many reports have taken on a trial-and-error approach, ignoring well established literature on grain growth outside the battery field. This perspective reviews the literature on single-crystal cathode synthesis through the lens of classic grain growth theories, providing insight and hopefully accelerating the adoption of the promising single-crystal cathode morphology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 37, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 143, "End Page": 160, "Article Number": null, "DOI": "10.1016/j.ensm.2021.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2021.02.003", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632779100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LS; Zhou, AG; Sun, BR; Chen, KS; Yu, HZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lishen; Zhou, Alvin G.; Sun, Brigitta R.; Chen, Kennedy S.; Yu, Hua-Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional and versatile superhydrophobic coatings via stoichiometric silanization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superhydrophobic coatings have tremendous potential for applications in different fields and have been achieved commonly by increasing nulloscale roughness and lowering surface tension. Limited by the availability of either ideal nullo-structural templates or simple fabrication procedures, the search of superhydrophobic coatings that are easy to manufacture and are robust in real-life applications remains challenging for both academia and industry. Herein, we report an unconventional protocol based on a single-step, stoichiometrically controlled reaction of long-chain organosilanes with water, which creates micro- to nullo-scale hierarchical siloxane aggregates dispersible in industrial solvents (as the coating mixture). Excellent superhydrophobicity (ultrahigh water contact angle >170 degrees and ultralow sliding angle <1) has been attained on solid materials of various compositions and dimensions, by simply dipping into or spraying with the coating mixture. It has been demonstrated that these complete waterproof coatings hold excellent properties in terms of cost, scalability, robustness, and particularly the capability of encapsulating other functional materials (e.g. luminescent dyes). Artificial superhydrophobic coatings that are simple to prepare and practical to use are sought after. Here, the authors create versatile, complete-waterproof coatings based on a single-step, stoichiometrically controlled reaction of organosilanes with water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 982, "DOI": "10.1038/s41467-021-21219-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21219-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620683400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, MJ; Li, Z; Reese, MO; Reid, OG; Kim, DH; Siol, S; Klein, TR; Yan, Y; Berry, JJ; van Hest, MFAM; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Mengjin; Li, Zhen; Reese, Matthew O.; Reid, Obadiah G.; Kim, Dong Hoe; Siol, Sebastian; Klein, Talysa R.; Yan, Yanfa; Berry, Joseph J.; van Hest, Maikel F. A. M.; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite ink with wide processing window for scalable high-efficiency solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells have made tremendous progress using laboratory-scale spin-coating methods in the past few years owing to advances in controls of perovskite film deposition. However, devices made via scalable methods are still lagging behind state-of-the-art spin-coated devices because of the complicated nature of perovskite crystallization from a precursor state. Here we demonstrate a chlorine-containing methylammonium lead iodide precursor formulation along with solvent tuning to enable a wide precursor-processing window (up to similar to 8 min) and a rapid grain growth rate (as short as similar to 1 min). Coupled with antisolvent extraction, this precursor ink delivers high-quality perovskite films with large-scale uniformity. The ink can be used by both spin-coating and blade-coating methods with indistinguishable film morphology and device performance. Using a blade-coated absorber, devices with 0.12-cm(2) and 1.2-cm(2) areas yield average efficiencies of 18.55% and 17.33%, respectively. We further demonstrate a 12.6-cm(2) four-cell module (88% geometric fill factor) with 13.3% stabilized active-area efficiency output.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 513, "Times Cited, All Databases": 560, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17038, "DOI": "10.1038/nenergy.2017.38", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.38", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404895300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, CL; Li, HM; Sheng, Y; Zhou, M; Wang, W; Gong, MX; Wang, KL; Jiang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Chenglong; Li, Haomiao; Sheng, Yi; Zhou, Min; Wang, Wei; Gong, Mingxing; Wang, Kangli; Jiang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Spatial Combination of CN Vacancy-Mediated NiFe-PBA with N-Doped Carbon nullofibers Network Toward Free-Standing Bifunctional Electrode for Zn-Air Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing flexible free-standing electrodes with efficient bifunctional performance is significant for improving the performance of flexible Zinc-air batteries. Herein, a flexible free-standing bifunctional electrode (N-2-NiFe-PBA/NCF/CC-60) is constructed by the 3D spatial combination of CN vacancy-mediated NiFe Prussian Blue Analogue (NiFe-PBA) and N-doped carbon nullofibers (NCF) rooted on carbon cloth (CC). The in situ formed CN vacancies by N-2-plasma activation tune the local coordination environment and electronic structure of Ni-Fe active sites in NiFe-PBA, thus improving the oxygen evolution reaction (OER) catalytic intrinsic activity, and restraining the loss of Fe element during OER process. The combination of NiFe-PBA and NCF presents a 3D interworking network structure, which exhibits a large specific surface and excellent electrical conductivity, thus guaranteeing sufficient, stable, and efficient oxygen reduction reaction (ORR)/OER active sites. Therefore, the N-2-NiFe-PBA/NCF/CC-60 electrode delivers high-efficiency OER activity with a low overpotential (270 mV at 50 mA cm(-2)) and excellent ORR performance with a positive potential of 0.89 V at 5 mA cm(-2). The N-2-NiFe-PBA/NCF/CC-60 based Zn-air batteries display outstanding discharge/charge stability for 2000 cycles. Meanwhile, the corresponding flexible Zn-air batteries with satisfactory mechanical properties exhibit a low voltage gap of 0.52 V at 1.0 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105925, "DOI": "10.1002/advs.202105925", "DOI Link": "http://dx.doi.org/10.1002/advs.202105925", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758844500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hernulldez, E; Nowack, B; Mitrano, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hernulldez, Edgar; Nowack, Bernd; Mitrano, Denise M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyester Textiles as a Source of Microplastics from Households: A Mechanistic Study to Understand Microfiber Release During Washing", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastic fibers make up a large proportion of microplastics found in the environment, especially in urban areas. There is good reason to consider synthetic textiles a major source of microplastic fibers, and it will not diminish since the use of synthetic fabrics, especially polyester, continues to increase. In this study we provide quantitative data regarding the size and mass of microplastic fibers released from synthetic (polyester) textiles during simulated home washing under controlled laboratory conditions. Consideration of fabric structure and washing conditions (use of detergents, temperature, wash duration, and sequential washings) allowed us to study the propensity of fiber shedding in a mechanistic way. Thousands of individual fibers were measured (number, length) from each wash solution to provide a robust data set on which to draw conclusions. Among all the variables tested, the use of detergent appeared to affect the total mass of fibers released the most, yet the detergent composition (liquid or powder) or overdosing of detergent did not significantly influence microplastic release. Despite different release quantities due to the addition of a surfactant (approximately 0.025 and 0.1 mg fibers/g textile washed, without and with detergent, respectively), the overall microplastic fiber length profile remained similar regardless of wash condition or fabric structure, with the vast majority of fibers ranging between 100 and 800 ym in length irrespective of wash cycle number. This indicates that the fiber staple length and/or debris encapsulated inside the fabric from the yarn spinning could be directly responsible for releasing stray fibers. This study serves as a first look toward understanding the physical properties of the textile itself to better understand the mechanisms of fiber shedding in the context of microplastic fiber release into laundry wash water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 528, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 51, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7036, "End Page": 7046, "Article Number": null, "DOI": "10.1021/acs.est.7b01750", "DOI Link": "http://dx.doi.org/10.1021/acs.est.7b01750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404087400045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martin, DJ; Qiu, KP; Shevlin, SA; Handoko, AD; Chen, XW; Guo, ZX; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martin, David James; Qiu, Kaipei; Shevlin, Stephen Andrew; Handoko, Albertus Denny; Chen, Xiaowei; Guo, Zhengxiao; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Photocatalytic H2 Evolution from Water using Visible Light and Structure-Controlled Graphitic Carbon Nitride", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The major challenge of photocatalytic water splitting, the prototypical reaction for the direct production of hydrogen by using solar energy, is to develop low-cost yet highly efficient and stable semiconductor photocatalysts. Herein, an effective strategy for synthesizing extremely active graphitic carbon nitride (g-C3N4) from a low-cost precursor, urea, is reported. The g-C3N4 exhibits an extraordinary hydrogen-evolution rate (ca. 20 000 mu molh(-1)g(-1) under full arc), which leads to a high turnover number (TON) of over 641 after 6 h. The reaction proceeds for more than 30 h without activity loss and results in an internal quantum yield of 26.5% under visible light, which is nearly an order of magnitude higher than that observed for any other existing g-C3N4 photocatalysts. Furthermore, it was found by experimental analysis and DFT calculations that as the degree of polymerization increases and the proton concentration decreases, the hydrogen-evolution rate is significantly enhanced.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1033, "Times Cited, All Databases": 1064, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2014, "Volume": 53, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9240, "End Page": 9245, "Article Number": null, "DOI": "10.1002/anie.201403375", "DOI Link": "http://dx.doi.org/10.1002/anie.201403375", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342676100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kokkinis, D; Schaffner, M; Studart, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kokkinis, Dimitri; Schaffner, Manuel; Studart, Andre R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multimaterial magnetically assisted 3D printing of composite materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D printing has become commonplace for the manufacturing of objects with unusual geometries. Recent developments that enabled printing of multiple materials indicate that the technology can potentially offer a much wider design space beyond unusual shaping. Here we show that a new dimension in this design space can be exploited through the control of the orientation of anisotropic particles used as building blocks during a direct ink-writing process. Particle orientation control is demonstrated by applying low magnetic fields on deposited inks pre-loaded with magnetized stiff platelets. Multimaterial dispensers and a two-component mixing unit provide additional control over the local composition of the printed material. The five-dimensional design space covered by the proposed multimaterial magnetically assisted 3D printing platform (MM-3D printing) opens the way towards the manufacturing of functional heterogeneous materials with exquisite microstructural features thus far only accessible by biological materials grown in nature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 670, "Times Cited, All Databases": 762, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8643, "DOI": "10.1038/ncomms9643", "DOI Link": "http://dx.doi.org/10.1038/ncomms9643", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364941500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dubbeldam, D; Calero, S; Ellis, DE; Snurr, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dubbeldam, David; Calero, Sofia; Ellis, Donald E.; Snurr, Randall Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RASPA: molecular simulation software for adsorption and diffusion in flexible nulloporous materials", "Source Title": "MOLECULAR SIMULATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new software package, RASPA, for simulating adsorption and diffusion of molecules in flexible nulloporous materials is presented. The code implements the latest state-of-the-art algorithms for molecular dynamics and Monte Carlo (MC) in various ensembles including symplectic/measure-preserving integrators, Ewald summation, configurational-bias MC, continuous fractional component MC, reactive MC and Baker's minimisation. We show example applications of RASPA in computing coexistence properties, adsorption isotherms for single and multiple components, self- and collective diffusivities, reaction systems and visualisation. The software is released under the GNU General Public License.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1435, "Times Cited, All Databases": 1532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2016, "Volume": 42, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": 101, "Article Number": null, "DOI": "10.1080/08927022.2015.1010082", "DOI Link": "http://dx.doi.org/10.1080/08927022.2015.1010082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362190200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, HY; Lu, N; Dai, J; Wu, XJ; Zeng, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Hongyan; Lu, Ning; Dai, Jun; Wu, Xiaojun; Zeng, Xiao Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene nulloribbons, Phosphorus nullotubes, and van der Waals Multilayers", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We perform a comprehensive first-principles study of the electronic properties of phosphorene nulloribbons, phosphorus nullotubes, multilayer phosphorene sheets, and heterobilayers of phosphorene and two-dimensional (2D) transition-metal dichalcogenide (TMDC) monolayer. The tensile strain and electric-field effects on electronic properties of low-dimensional phosphorene nullostructures are also investigated. Our calculations show that the bare zigzag phosphorene nulloribbons (z-PNRs) are metals regardless of the ribbon width, whereas the bare armchair phosphorene nulloribbons (a-PNRs) are semiconductors with indirect bandgaps and the bandgaps decrease with increasing ribbon width. We find that compressive (or tensile) strains can reduce (or enlarge) the bandgap of the bare a-PNRs while an in-plane electric field can significantly reduce the bandgap of the bare a-PNRs, leading to the semiconductor-to-metal transition beyond certain electric field. For edge-passivated PNR by hydrogen, z-PNRs become semiconductor with nearly direct bandgaps and a-PNRs are still semiconductor but with direct bandgaps. The response to tensile strain and electric field for the edge-passivated PNRs is similar to that for the edge-unpassivated (bare) a-PNRs. For single-walled phosphorus nullotubes, both armchair and zigzag nullotubes are semiconductors with direct bandgaps. With either tensile strains or transverse electric field, behavior of bandgap modulation similar to that for a-PNRs can arise. It is known that multilayer phosphorene sheets are semiconductors whose bandgaps decrease with an increase in the number of multilayers. In the presence of a vertical electric field, the bandgaps of multilayer phosphorene sheets decrease with increasing electric field and the bandgap modulation is more significant with more layers. Lastly, heterobilayers of phosphorene (p-type) with an n-type TMDC (MoS2 or WS2) monolayer are still semiconductors while their bandgaps can be reduced by applying a vertical electric field as well. We also show that the combined phosphorene/MoS2 heterolayers can be an effective solar cell material. Our estimated power conversion efficiency for the phosphorene/MoS2 heterobilayer has a theoretical maximum value of 17.5%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 583, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2014, "Volume": 118, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14051, "End Page": 14059, "Article Number": null, "DOI": "10.1021/jp505257g", "DOI Link": "http://dx.doi.org/10.1021/jp505257g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338184300087", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dagdeviren, C; Yang, BD; Su, YW; Tran, PL; Joe, P; Anderson, E; Xia, J; Doraiswamy, V; Dehdashti, B; Feng, X; Lu, BW; Poston, R; Khalpey, Z; Ghaffari, R; Huang, YG; Slepian, MJ; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dagdeviren, Canull; Yang, Byung Duk; Su, Yewang; Tran, Phat L.; Joe, Pauline; Anderson, Eric; Xia, Jing; Doraiswamy, Vijay; Dehdashti, Behrooz; Feng, Xue; Lu, Bingwei; Poston, Robert; Khalpey, Zain; Ghaffari, Roozbeh; Huang, Yonggang; Slepian, Marvin J.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformal piezoelectric energy harvesting and storage from motions of the heart, lung, and diaphragm", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we report advanced materials and devices that enable high-efficiency mechanical-to-electrical energy conversion from the natural contractile and relaxation motions of the heart, lung, and diaphragm, demonstrated in several different animal models, each of which has organs with sizes that approach human scales. A cointegrated collection of such energy-harvesting elements with rectifiers and microbatteries provides an entire flexible system, capable of viable integration with the beating heart via medical sutures and operation with efficiencies of similar to 2%. Additional experiments, computational models, and results in multilayer configurations capture the key behaviors, illuminate essential design aspects, and offer sufficient power outputs for operation of pacemakers, with or without battery assist.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 717, "Times Cited, All Databases": 832, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2014, "Volume": 111, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1927, "End Page": 1932, "Article Number": null, "DOI": "10.1073/pnas.1317233111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1317233111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330587600066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, WJ; He, ZK; Lam, JWY; Peng, Q; Ma, HL; Shuai, ZG; Bai, GX; Hao, JH; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Weijun; He, Zikai; Lam, Jacky W. Y.; Peng, Qian; Ma, Huili; Shuai, Zhigang; Bai, Gongxun; Hao, Jianhua; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational Molecular Design for Achieving Persistent and Efficient Pure Organic Room-Temperature Phosphorescence", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manipulation of the emission properties of pure organic room-temperature phosphors through molecular design is attractive but challenging. Tremendous efforts have been made to modulate their aggregation behaviors to suppress nonradiative decay in order to achieve efficient light emission and long lifetimes. However, success has been limited. To attain such a goal, here we present a rational design principle based on intrinsic molecular-structure engineering. Comprehensive investigations on the molecular orbitals revealed that an excited state with hybrid (n,pi*) and (pi,pi*) configurations in appreciable proportion is desired. Tailoring the aromatic subunits in arylphenones can effectively tune the energy level and the orbital feature of the triplet exciton. Our experimental data reveal that a series of full-color pure organic phosphors with a balanced lifetime (up to 0.23 s) and efficiency (up to 36.0%) can be realized under ambient conditions, demonstrating the validity of our instructive design principle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 642, "Times Cited, All Databases": 654, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2016, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 592, "End Page": 602, "Article Number": null, "DOI": "10.1016/j.chempr.2016.08.010", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2016.08.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387035000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, LM; Shen, C; Wu, Q; Shellikeri, A; Zheng, JS; Zhang, CM; Zheng, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Liming; Shen, Chao; Wu, Qiang; Shellikeri, Annadanesh; Zheng, Junsheng; Zhang, Cunman; Zheng, Jim P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pre-Lithiation Strategies for Next-Generation Practical Lithium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation Li-ion batteries (LIBs) with higher energy density adopt some novel anode materials, which generally have the potential to exhibit higher capacity, superior rate performance as well as better cycling durability than conventional graphite anode, while on the other hand always suffer from larger active lithium loss (ALL) in the first several cycles. During the last two decades, various pre-lithiation strategies are developed to mitigate the initial ALL by presetting the extra Li sources to effectively improve the first Coulombic efficiency and thus achieve higher energy density as well as better cyclability. In this progress report, the origin of the huge initial ALL of the anode and its effect on the performance of full cells are first illustrated in theory. Then, various pre-lithiation strategies to resolve these issues are summarized, classified, and compared in detail. Moreover, the research progress of pre-lithiation strategies for the representative electrochemical systems are carefully reviewed. Finally, the current challenges and future perspectives are particularly analyzed and outlooked. This progress report aims to bring up new insights to reassess the significance of pre-lithiation strategies and offer a guideline for the research directions tailored for different applications based on the proposed pre-lithiation strategies summaries and comparisons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2005031, "DOI": "10.1002/advs.202005031", "DOI Link": "http://dx.doi.org/10.1002/advs.202005031", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628862100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, JX; Shen, RC; Jiang, ZM; Zhang, P; Li, YJ; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Junxian; Shen, Rongchen; Jiang, Zhimin; Zhang, Peng; Li, Youji; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of 2D layered CdS/WO3 S-scheme heterojunctions and metallic Ti3C2 MXene-based Ohmic junctions for effective photocatalytic H2 generation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid recombination of photo-generated electron-hole pairs, insufficient active sites, and strong photocorrosion have considerably restricted the practical application of CdS in photocatalytic fields. Herein, we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces. Experiments using electron spin resonullce spectroscopy, ultraviolet photoelectron spectroscopy, and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO3 step-scheme (S-scheme) heterojunctions and CdS/MX ohmic junctions. Impressively, it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO3 nullosheets. In addition, 2D Ti3C2 MXene nullosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with CdS nullosheets, thus providing a greater number of electron transfer pathways and hydrogen evolution sites. Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-CdS/WO3 layered multi-heterostructures could reach as high as 27.5 mmol/g/h, which was 11.0 times higher than that of pure CdS nullosheets. Notably, the apparent quantum efficiency reached 12.0% at 450 nm. It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 359, "End Page": 369, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63883-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63883-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MH; Zhu, WJ; Li, X; Xu, HL; Fan, XM; Wu, HJ; Ye, F; Xue, JM; Li, XQ; Cheng, LF; Zhang, LT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Minghang; Zhu, Wenjie; Li, Xin; Xu, Hailong; Fan, Xiaomeng; Wu, Hongjing; Ye, Fang; Xue, Jimei; Li, Xiaoqiang; Cheng, Laifei; Zhang, Litong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti3C2Tx/MoS2 Self-Rolling Rod-Based Foam Boosts Interfacial Polarization for Electromagnetic Wave Absorption", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous interface design to boost interfacial polarization has become a feasible way to realize high electromagnetic wave absorbing (EMA) performance of dielectric materials. However, interfacial polarization in simple structures such as particles, rods, and flakes is weak and usually plays a secondary role. In order to enhance the interfacial polarization and simultaneously reduce the electronic conductivity to avoid reflection of electromagnetic wave, a more rational geometric structure for dielectric materials is desired. Herein, a Ti3C2Tx/MoS2 self-rolling rod-based foam is proposed to realize excellent interfacial polarization and achieve high EMA performance at ultralow density. Different surface tensions of Ti3C2Tx and ammonium tetrathiomolybdate are utilized to induce the self-rolling of Ti3C2Tx sheets. The rods with a high aspect ratio not only remarkably improve the polarization loss but also are beneficial to the construction of Ti3C2Tx/MoS2 foam, leading to enhanced EMA capability. As a result, the effective absorption bandwidth of Ti3C2Tx/MoS2 foam covers the whole X band (8.2-12.4 GHz) with a density of only 0.009 g cm(-3), at a thickness of 3.3 mm. The advantages of rod structures are verified through simulations in the CST microwave studio. This work inspires the rational geometric design of micro/nullostructures for new-generation EMA materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201118, "DOI": "10.1002/advs.202201118", "DOI Link": "http://dx.doi.org/10.1002/advs.202201118", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000794210400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YF; Gao, L; Zheng, X; Wang, ZH; Yang, CL; Tang, HL; Qu, LJ; Li, YB; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yongfeng; Gao, Liang; Zheng, Xian; Wang, Zhonghao; Yang, Chaolong; Tang, Hailong; Qu, Lunjun; Li, Youbing; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultraviolet irradiation-responsive dynamic ultralong organic phosphorescence in polymeric systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Room temperature phosphorescence (RTP) has drawn extensive attention in recent years. Efficient stimulus-responsive phosphorescent organic materials are attractive, but are extremely rare because of unclear design principles and intrinsically spin-forbidden intersystem crossing. Herein, we present a feasible and facile strategy to achieve ultraviolet irradiation-responsive ultralong RTP (IRRTP) of some simple organic phosphors by doping into amorphous poly(vinyl alcohol) matrix. In addition to the observed green and yellow afterglow emission with distinct irradiation-enhanced phosphorescence, the phosphorescence lifetime can be tuned by varying the irradiation period of 254nm light. Significantly, the dynamic phosphorescence lifetime could be increased 14.3 folds from 58.03ms to 828.81ms in one of the obtained hybrid films after irradiation for 45min under ambient conditions. As such, the application in polychromatic screen printing and multilevel information encryption is demonstrated. The extraordinary IRRTP in the amorphous state endows these systems with a highly promising potential for smart flexible luminescent materials and sensors with dynamically controlled phosphorescence. Efficient stimulus-responsive phosphorescence organic materials are attractive, but are extremely rare because of unclear design principles and intrinsically spin-forbidden intersystem crossing. Here, the authors present a facile strategy to achieve ultraviolet irradiation-responsive ultralong room-temperature phosphorescence in several simple amorphous polymer materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2297, "DOI": "10.1038/s41467-021-22609-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22609-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641850500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lanza, M; Wong, HSP; Pop, E; Ielmini, D; Strukov, D; Regan, BC; Larcher, L; Villena, MA; Yang, JJ; Goux, L; Belmonte, A; Yang, YC; Puglisi, FM; Kang, JF; Magyari-Köpe, B; Yalon, E; Kenyon, A; Buckwell, M; Mehonic, A; Shluger, A; Li, HT; Hou, TH; Hudec, B; Akinwande, D; Ge, RJ; Ambrogio, S; Roldan, JB; Miranda, E; Sune, J; Pey, KL; Wu, X; Raghavan, N; Wu, E; Lu, WD; Navarro, G; Zhang, WD; Wu, HQ; Li, RW; Holleitner, A; Wurstbauer, U; Lemme, MC; Liu, M; Long, SB; Liu, Q; Lv, HB; Padovani, A; Pavan, P; Valov, I; Jing, X; Han, TT; Zhu, KC; Chen, SC; Hui, F; Shi, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lanza, Mario; Wong, H-S Philip; Pop, Eric; Ielmini, Daniele; Strukov, Dimitri; Regan, Brian C.; Larcher, Luca; Villena, Marco A.; Yang, J. Joshua; Goux, Ludovic; Belmonte, Attilio; Yang, Yuchao; Puglisi, Francesco M.; Kang, Jinfeng; Magyari-Kope, Blanka; Yalon, Eilam; Kenyon, Anthony; Buckwell, Mark; Mehonic, Adnull; Shluger, Alexander; Li, Haitong; Hou, Tuo-Hung; Hudec, Boris; Akinwande, Deji; Ge, Ruijing; Ambrogio, Stefano; Roldan, Juan B.; Miranda, Enrique; Sune, Jordi; Pey, Kin Leong; Wu, Xing; Raghavan, Nagarajan; Wu, Ernest; Lu, Wei D.; Navarro, Gabriele; Zhang, Weidong; Wu, Huaqiang; Li, Runwei; Holleitner, Alexander; Wurstbauer, Ursula; Lemme, Max C.; Liu, Ming; Long, Shibing; Liu, Qi; Lv, Hangbing; Padovani, Andrea; Pavan, Paolo; Valov, Ilia; Jing, Xu; Han, Tingting; Zhu, Kaichen; Chen, Shaochuan; Hui, Fei; Shi, Yuanyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recommended Methods to Study Resistive Switching Devices", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Resistive switching (RS) is an interesting property shown by some materials systems that, especially during the last decade, has gained a lot of interest for the fabrication of electronic devices, with electronic nonvolatile memories being those that have received the most attention. The presence and quality of the RS phenomenon in a materials system can be studied using different prototype cells, performing different experiments, displaying different figures of merit, and developing different computational analyses. Therefore, the real usefulness and impact of the findings presented in each study for the RS technology will be also different. This manuscript describes the most recommendable methodologies for the fabrication, characterization, and simulation of RS devices, as well as the proper methods to display the data obtained. The idea is to help the scientific community to evaluate the real usefulness and impact of an RS study for the development of RS technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 512, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800143, "DOI": "10.1002/aelm.201800143", "DOI Link": "http://dx.doi.org/10.1002/aelm.201800143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455220900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Edri, E; Kirmayer, S; Mukhopadhyay, S; Gartsman, K; Hodes, G; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Edri, Eran; Kirmayer, Saar; Mukhopadhyay, Sabyasachi; Gartsman, Konstantin; Hodes, Gary; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elucidating the charge carrier separation and working mechanism of CH3NH3PbI3-xClx perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developments in organic-inorganic lead halide-based perovskite solar cells have been meteoric over the last 2 years, with small-area efficiencies surpassing 15%. We address the fundamental issue of how these cells work by applying a scanning electron microscopy-based technique to cell cross-sections. By mapping the variation in efficiency of charge separation and collection in the cross-sections, we show the presence of two prime high efficiency locations, one at/near the absorber/hole-blocking-layer, and the second at/near the absorber/electron-blocking-layer interfaces, with the former more pronounced. This 'twin-peaks' profile is characteristic of a p-i-n solar cell, with a layer of low-doped, high electronic quality semiconductor, between a p-and an n-layer. If the electron blocker is replaced by a gold contact, only a heterojunction at the absorber/hole-blocking interface remains.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 507, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3461, "DOI": "10.1038/ncomms4461", "DOI Link": "http://dx.doi.org/10.1038/ncomms4461", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334300400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HC; Fu, HL; Sun, LN; Lee, C; Yeatman, EM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huicong; Fu, Hailing; Sun, Lining; Lee, Chengkuo; Yeatman, Eric M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid energy harvesting technology: From materials, structural design, system integration to applications", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The last decade has witnessed significant advances in energy harvesting technology for the realization of self-charging electronics and self-powered wireless sensor nodes (WSNs). To conquer the energy-insufficiency issue of a single energy harvester, hybrid energy harvesting systems have been proposed in recent years. Hybrid harvesting includes not only scavenging energy from multiple sources, but also converting energy into electricity by multiple types of transduction mechanisms. A reasonable hybridization of multiple energy conversion mechanisms not only improves the space utilization efficiency but can also boost the power output significantly. Given the continuously growing trend of hybrid energy harvesting technology, herein we present a comprehensive review of recent progress and representative works, especially focusing on vibrational and thermal energy harvesters which play the dominullt role in hybrid energy harvesting. The working principles and typical configurations for piezoelectric, electromagnetic, triboelectric, thermoelectric and pyroelectric transduction effects are briefly introduced. On this basis, a variety of hybrid energy harvesting systems, including mechanisms, configurations, output performance and advantages, are elaborated. Comparisons and perspectives on the effectiveness of hybrid vibrational and thermal harvesters are provided. A variety of potential application prospects of the hybrid systems are discussed, including infrastructure health monitoring, industry condition monitoring, smart transportation, human healthcare monitoring, marine monitoring systems, and aerospace engineering, towards the future Internet-of-Things (IoT) era.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110473, "DOI": "10.1016/j.rser.2020.110473", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2020.110473", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625292500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZP; Zhang, L; Yang, YH; Vitorica-Yrezabal, IJ; Wang, HL; Tan, FL; Gong, L; Li, YY; Chen, PH; Dong, X; Liang, ZH; Yang, J; Wang, C; Hong, YX; Qiu, Y; Gölzhäuser, A; Chen, XD; Qi, HY; Yang, SH; Liu, W; Sun, JL; Zheng, ZK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhipeng; Zhang, Lei; Yang, Yonghang; Vitorica-Yrezabal, Inigo J.; Wang, Honglei; Tan, Fanglin; Gong, Li; Li, Yuyao; Chen, Pohua; Dong, Xin; Liang, Zihao; Yang, Jing; Wang, Chao; Hong, Yuexian; Qiu, Yi; Goelzhaeuser, Armin; Chen, Xudong; Qi, Haoyuan; Yang, Sihai; Liu, Wei; Sun, Junliang; Zheng, Zhikun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Growth of single-crystal imine-linked covalent organic frameworks using amphiphilic amino-acid derivatives in water", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A core feature of covalent organic frameworks (COFs) is crystallinity, but current crystallization processes rely substantially on trial and error, chemical intuition and large-scale screening, which typically require harsh conditions and low levels of supersaturation, hampering the controlled synthesis of single-crystal COFs, particularly on large scales. Here we report a strategy to produce single-crystal imine-linked COFs in aqueous solutions under ambient conditions using amphiphilic amino-acid derivatives with long hydrophobic chains. We propose that these amphiphilic molecules self-assemble into micelles that serve as dynamic barriers to separate monomers in aqueous solution (nodes) and hydrophobic compartments of the micelles (linkers), thereby regulating the polymerization and crystallization processes. Disordered polyimines were obtained in the micelle, which were then converted into crystals in a step-by-step fashion. Five different three-dimensional COFs and a two-dimensional COF were obtained as single crystals on the gram scale, with yields of 92% and above.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 841, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-023-01181-6", "DOI Link": "http://dx.doi.org/10.1038/s41557-023-01181-6", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967661100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vatankhah-Varnosfaderani, M; Keith, AN; Cong, YD; Liang, HY; Rosenthal, M; Sztucki, M; Clair, C; Magonov, S; Ivanov, DA; Dobrynin, AV; Sheiko, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vatankhah-Varnosfaderani, Mohammad; Keith, Andrew N.; Cong, Yidan; Liang, Heyi; Rosenthal, Martin; Sztucki, Michael; Clair, Charles; Magonov, Sergei; Ivanov, Dimitri A.; Dobrynin, Andrey V.; Sheiko, Sergei S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chameleon-like elastomers with molecularly encoded strain-adaptive stiffening and coloration", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active camouflage is widely recognized as a soft-tissue feature, and yet the ability to integrate adaptive coloration and tissuelike mechanical properties into synthetic materials remains elusive. We provide a solution to this problem by uniting these functions in moldable elastomers through the self-assembly of linear-bottlebrush-linear triblock copolymers. Microphase separation of the architecturally distinct blocks results in physically cross-linked networks that display vibrant color, extreme softness, and intense strain stiffening on par with that of skin tissue. Each of these functional properties is regulated by the structure of one macromolecule, without the need for chemical cross-linking or additives. These materials remain stable under conditions characteristic of internal bodily environments and under ambient conditions, neither swelling in bodily fluids nor drying when exposed to air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2018, "Volume": 359, "Issue": 6383, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1509, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar5308", "DOI Link": "http://dx.doi.org/10.1126/science.aar5308", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428657000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shalaginov, MY; An, S; Zhang, YF; Yang, F; Su, P; Liberman, V; Chou, JB; Roberts, CM; Kang, M; Rios, C; Du, QY; Fowler, C; Agarwal, A; Richardson, KA; Rivero-Baleine, C; Zhang, HL; Hu, JJ; Gu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shalaginov, Mikhail Y.; An, Sensong; Zhang, Yifei; Yang, Fan; Su, Peter; Liberman, Vladimir; Chou, Jeffrey B.; Roberts, Christopher M.; Kang, Myungkoo; Rios, Carlos; Du, Qingyang; Fowler, Clayton; Agarwal, Anuradha; Richardson, Kathleen A.; Rivero-Baleine, Clara; Zhang, Hualiang; Hu, Juejun; Gu, Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconfigurable all-dielectric metalens with diffraction-limited performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active metasurfaces, whose optical properties can be modulated post-fabrication, have emerged as an intensively explored field in recent years. The efforts to date, however, still face major performance limitations in tuning range, optical quality, and efficiency, especially for non-mechanical actuation mechanisms. In this paper, we introduce an active metasurface platform combining phase tuning in the full 2 range and diffraction-limited performance using an all-dielectric, low-loss architecture based on optical phase change materials (O-PCMs). We present a generic design principle enabling binary switching of metasurfaces between arbitrary phase profiles and propose a new figure-of-merit (FOM) tailored for reconfigurable meta-optics. We implement the approach to realize a high-performance varifocal metalens operating at 5.2 mu m wavelength. The reconfigurable metalens features a record large switching contrast ratio of 29.5dB. We further validate aberration-free and multi-depth imaging using the metalens, which represents a key experimental demonstration of a non-mechanical tunable metalens with diffraction-limited performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1225, "DOI": "10.1038/s41467-021-21440-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21440-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621931000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, A; Zhu, HH; Bai, S; Reo, YJ; Zou, TY; Kim, MG; Noh, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ao; Zhu, Huihui; Bai, Sai; Reo, Youjin; Zou, Taoyu; Kim, Myung-Gil; Noh, Yong-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance inorganic metal halide perovskite transistors", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The p-type characteristic of solution-processed metal halide perovskite transistors means that they could be used in combination with their n-type counterparts, such as indium-gallium-zinc-oxide transistors, to create complementary metal-oxide-semiconductor-like circuits. However, the performance and stability of perovskite-based transistors do not yet match their n-type counterparts, which limit their broader application. Here we report high-performance p-channel perovskite thin-film transistors based on inorganic caesium tin triiodide semiconducting layers that have moderate hole concentrations and high Hall mobilities. The perovskite channels are formed by engineering the film composition and crystallization process using a tin-fluoride-modified caesium-iodide-rich precursor with lead substitution. The optimized transistors exhibit field-effect hole mobilities of over 50 cm(2) V-1 s(-1) and on/off current ratios exceeding 10(8), as well as high operational stability and reproducibility. By optimizing the doping and crystallization behaviour of solution-processed metal halide perovskite thin films, p-channel transistors with mobilities of 50 cm(2) V-1 s(-1) and on/off ratios of 10(8) can be fabricated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 83, "Article Number": null, "DOI": "10.1038/s41928-022-00712-2", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00712-2", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757244000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, S; Shadike, Z; Li, JZ; Wang, XL; Yang, Y; Lin, RQ; Cresce, A; Hu, JT; Hunt, A; Waluyo, I; Ma, L; Monaco, F; Cloetens, P; Xiao, J; Liu, YJ; Yang, XQ; Xu, K; Hu, EY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Sha; Shadike, Zulipiya; Li, Jizhou; Wang, Xuelong; Yang, Yang; Lin, Ruoqian; Cresce, Arthur; Hu, Jiangtao; Hunt, Adrian; Waluyo, Iradwikanari; Ma, Lu; Monaco, Federico; Cloetens, Peter; Xiao, Jie; Liu, Yijin; Yang, Xiao-Qing; Xu, Kang; Hu, Enyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive engineering for robust interphases to stabilize high-Ni layered structures at ultra-high voltage of 4.8 V", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel-rich layered cathode materials promise high energy density for next-generation batteries when coupled with lithium metal anodes. However, the practical capacities accessible are far less than the theoretical values due to their structural instability during cycling, especially when charged at high voltages. Here we demonstrate that stable cycling with an ultra-high cut-off voltage of 4.8 V can be realized by using an appropriate amount of lithium difluorophosphate in a common commercial electrolyte. The Li||LiNi0.76Mn0.14Co0.10O2 cell retains 97% of the initial capacity (235 mAh g(-1)) after 200 cycles. The cycling stability is ascribed to the robust interphase on the cathode. It is formed by lithium difluorophosphate decomposition, which is facilitated by the catalytic effect of transition metals. The decomposition products (Li3PO4 and LiF) form a protective interphase. This suppresses transition metal dissolution and cathode surface reconstruction. It also facilitates uniform Li distribution within the cathode, effectively mitigating the strain and crack formation. Severe capacity decay at high voltages prevents the application of Ni-rich layered oxide cathodes. Here the authors report an electrolyte additive in a common commercial electrolyte that enables stable cycling at an ultra-high voltage of 4.8 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 484, "End Page": 494, "Article Number": null, "DOI": "10.1038/s41560-022-01020-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01020-x", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000792547700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HT; Park, TJ; Islam, ANMN; Tran, DSJ; Manna, S; Wang, Q; Mondal, S; Yu, HM; Banik, S; Cheng, SB; Zhou, H; Gamage, S; Mahapatra, S; Zhu, YM; Abate, Y; Jiang, N; Sankaranarayanull, SKRS; Sengupta, A; Teuscher, C; Ramanathan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hai-Tian; Park, Tae Joon; Islam, A. N. M. Nafiul; Tran, Dat S. J.; Manna, Sukriti; Wang, Qi; Mondal, Sandip; Yu, Haoming; Banik, Suvo; Cheng, Shaobo; Zhou, Hua; Gamage, Sampath; Mahapatra, Sayantan; Zhu, Yimei; Abate, Yohannes; Jiang, null; Sankaranarayanull, Subramanian K. R. S.; Sengupta, Abhronil; Teuscher, Christof; Ramanathan, Shriram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconfigurable perovskite nickelate electronics for artificial intelligence", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reconfigurable devices offer the ability to program electronic circuits on demand. In this work, we demonstrated on-demand creation of artificial neurons, synapses, and memory capacitors in post-fabricated perovskite NdNiO3 devices that can be simply reconfigured for a specific purpose by single-shot electric pulses. The sensitivity of electronic properties of perovskite nickelates to the local distribution of hydrogen ions enabled these results. With experimental data from our memory capacitors, simulation results of a reservoir computing framework showed excellent performance for tasks such as digit recognition and classification of electrocardiogram heartbeat activity. Using our reconfigurable artificial neurons and synapses, simulated dynamic networks outperformed static networks for incremental learning scenarios. The ability to fashion the building blocks of brain-inspired computers on demand opens up new directions in adaptive networks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2022, "Volume": 375, "Issue": 6580, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 533, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj7943", "DOI Link": "http://dx.doi.org/10.1126/science.abj7943", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753965100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, RY; Shi, Y; Alsaedi, M; Wu, MC; Shi, L; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Renyuan; Shi, Yusuf; Alsaedi, Mossab; Wu, Mengchun; Shi, Le; Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Hydrogel with High Water Vapor Harvesting Capacity for Deployable Solar-Driven Atmospheric Water Generator", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Earth's atmosphere holds approximately 12 900 billion tons of fresh water distributed all over the world with fast replenishment. Atmospheric water harvesting is emerging as a promising strategy for clean water production in arid regions, land-locked areas, and remote communities. The water vapor sorbent is the key component for atmospheric water harvesting devices based on absorbing-releasing process. In this work, a flexible hybrid photothermal water sorbent composed of deliquescent salt and hydrogel was rationally fabricated. It possesses superior water sorption capacity even in low humidity air thanks to the deliquescent salt and maintains a solid form after it sorbs a large amount of water owing to the hydrogel platform. The harvested water could be easily released under regular sunlight via the photothermal effect, and it can be directly reused without noticeable capacity fading. An easy-to-assemble-at-household prototype device with 35 g of the dry hydrogel was tested outdoors under field conditions and delivered 20 g of fresh water within 2.5 h under natural sunlight. It is estimated that the material cost of making such a device to supply minimum daily water consumption for an adult (i.e., 3 kg) is only $3.20 (USD). This type of atmospheric water generator (AWG) is cheap and affordable, works perfectly with a broad range of humidity, does not need any electricity, and thus is especially suitable for clean water production in remote areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2018, "Volume": 52, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11367, "End Page": 11377, "Article Number": null, "DOI": "10.1021/acs.est.8b02852", "DOI Link": "http://dx.doi.org/10.1021/acs.est.8b02852", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446542100051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubota, K; Pang, YD; Miura, A; Ito, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubota, Koji; Pang, Yadong; Miura, Akira; Ito, Hajime", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox reactions of small organic molecules using ball milling and piezoelectric materials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past decade, photoredox catalysis has harnessed light energy to accelerate bond-forming reactions. We postulated that a complementary method for the redox-activation of small organic molecules in response to applied mechanical energy could be developed through the piezoelectric effect. Here, we report that agitation of piezoelectric materials via ball milling reduces aryl diazonium salts. This mechanoredox system can be applied to arylation and borylation reactions under mechanochemical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2019, "Volume": 366, "Issue": 6472, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1500, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay8224", "DOI Link": "http://dx.doi.org/10.1126/science.aay8224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503861000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, EJ; Siegelman, RL; Jiang, HZH; Forse, AC; Lee, JH; Martell, JD; Milner, PJ; Falkowski, JM; Neaton, JB; Reimer, JA; Weston, SC; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Eugene J.; Siegelman, Rebecca L.; Jiang, Henry Z. H.; Forse, Alexander C.; Lee, Jung-Hoon; Martell, Jeffrey D.; Milner, Phillip J.; Falkowski, Joseph M.; Neaton, Jeffrey B.; Reimer, Jeffrey A.; Weston, Simon C.; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cooperative carbon capture and steam regeneration with tetraamine-appended metal-organic frameworks", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural gas has become the dominullt source of electricity in the United States, and technologies capable of efficiently removing carbon dioxide (CO2) from the flue emissions of natural gas-fired power plants could reduce their carbon intensity. However, given the low partial pressure of CO2 in the flue stream, separation of CO2 is particularly challenging. Taking inspiration from the crystal structures of diamine-appended metal-organic frameworks exhibiting two-step cooperative CO2 adsorption, we report a family of robust tetraamine-functionalized frameworks that retain cooperativity, leading to the potential for exceptional efficiency in capturing CO2 under the extreme conditions relevant to natural gas flue emissions. The ordered, multimetal coordination of the tetraamines imparts the materials with extraordinary stability to adsorption-desorption cycling with simulated humid flue gas and enables regeneration using low-temperature steam in lieu of costly pressure or temperature swings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2020, "Volume": 369, "Issue": 6502, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 392, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb3976", "DOI Link": "http://dx.doi.org/10.1126/science.abb3976", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556265800037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kulbak, M; Cahen, D; Hodes, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kulbak, Michael; Cahen, David; Hodes, Gary", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr3 Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic lead halide perovskite photovoltaic cells have already surpassed 20% conversion efficiency in the few years that they have been seriously studied. However, many fundamental questions still remain unullswered as to why they are so good. One of these is Is the organic cation really necessary to obtain high quality cells? In this study, we show that an all-inorganic version of the lead bromide perovslcite material works equally well as the organic one, in particular generating the high open circuit voltages that are an important feature of these cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 984, "Times Cited, All Databases": 1063, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2015, "Volume": 6, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2452, "End Page": 2456, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b00968", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b00968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357626700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CC; Liu, LJ; Zhao, S; Liu, YC; Yang, YB; Yu, HJ; Lee, SW; Lee, YO; Kang, YMO; Liu, R; Li, FJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenchen; Liu, Luojia; Zhao, Shuo; Liu, Yanchen; Yang, Yubo; Yu, Haijun; Lee, Suwon; Lee, Gi-Hyeok; Kang, Yong-Mook; Liu, Rong; Li, Fujun; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning local chemistry of P2 layered-oxide cathode for high energy and long cycles of sodium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered transition-metal oxides have attracted intensive interest for cathode materials of sodium-ion batteries. However, they are hindered by the limited capacity and inferior phase transition due to the gliding of transition-metal layers upon Na+ extraction and insertion in the cathode materials. Here, we report that the large-sized K+ is riveted in the prismatic Na+ sites of P2-Na0.612K0.056MnO2 to enable more thermodynamically favorable Na+ vacancies. The Mn-O bonds are reinforced to reduce phase transition during charge and discharge. 0.901 Na+ per formula are reversibly extracted and inserted, in which only the two-phase transition of P2 <-> P'2 occurs at low voltages. It exhibits the highest specific capacity of 240.5 mAh g(-1) and energy density of 654 Wh kg(-1) based on the redox of Mn3+/Mn4+, and a capacity retention of 98.2% after 100 cycles. This investigation will shed lights on the tuneable chemical environments of transition-metal oxides for advanced cathode materials and promote the development of sodium-ion batteries. High-capacity and structural stable cathode materials are challenges for sodium-ion batteries. Here, the authors report a layered P2-Na0.612K0.056MnO2 with large-sized K+ riveted in the Na-layers to enable 0.9 Na+ (de)insertion with a reversible phase transition of P2-P'2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2256, "DOI": "10.1038/s41467-021-22523-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22523-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641850800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, SM; Lou, ZR; Zhang, L; Guo, HT; Wang, ZT; Guo, CF; Fukuda, K; Ma, SH; Wang, GQ; Someya, T; Cheng, HM; Xu, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Simin; Lou, Zirui; Zhang, Lan; Guo, Haotian; Wang, Zitian; Guo, Chuanfei; Fukuda, Kenjiro; Ma, Shaohua; Wang, Guoqing; Someya, Takao; Cheng, Hui-Ming; Xu, Xiaomin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Hydrogel Films toward Breathable Skin-Integrated Electronics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-skin electronics that offer revolutionary capabilities in personalized diagnosis, therapeutics, and human-machine interfaces require seamless integration between the skin and electronics. A common question remains whether an ideal interface can be introduced to directly bridge thin-film electronics with the soft skin, allowing the skin to breathe freely and the skin-integrated electronics to function stably. Here, an ever-thinnest hydrogel is reported that is compliant to the glyphic lines and subtle minutiae on the skin without forming air gaps, produced by a facile cold-lamination method. The hydrogels exhibit high water-vapor permeability, allowing nearly unimpeded transepidermal water loss and free breathing of the skin underneath. Hydrogel-interfaced flexible (opto)electronics without causing skin irritation or accelerated device performance deterioration are demonstrated. The long-term applicability is recorded for over one week. With combined features of extreme mechanical compliance, high permeability, and biocompatibility, the ultrathin hydrogel interface promotes the general applicability of skin-integrated electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 35, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202206793", "DOI Link": "http://dx.doi.org/10.1002/adma.202206793", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888665600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YM; Li, XY; Park, K; Lu, W; Wang, C; Xue, WJ; Yang, F; Zhou, J; Suo, LM; Lin, TQ; Huang, HT; Li, J; Goodenough, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuming; Li, Xiaoyan; Park, Kyusung; Lu, Wei; Wang, Chao; Xue, Weijiang; Yang, Fei; Zhou, Jiang; Suo, Liumin; Lin, Tianquan; Huang, Haitao; Li, Ju; Goodenough, John B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Doped Carbon for Sodium-Ion Battery Anode by Self-Etching and Graphitization of Bimetallic MOF-Based Composite", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The greater availability of sodium (Na) over lithium (Li) motivates development of a Na-ion battery that can compete with a Li-ion battery. In these batteries, both electrodes consist of hosts intowhich Li+ or Na+ can be inserted reversibly. Graphite has been the anode host for Li-ion batteries, but the Na+ ion is too large to be inserted easily between the flat graphene layers of common graphite. We report the synthesis and electrochemical performance of N-doped carbon nullofibers and tubules with an organic-liquid electrolyte and a large fraction of graphitic carbon and larger spacing (0.38-0.44 nm) between carbon sheets; the carbon hollow tubules yield ultrastable (10,000 cycles), high-rate capabilities of Na+ intercalation and deintercalation with reversible capacities up to 346 mAh g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 152, "End Page": 163, "Article Number": null, "DOI": "10.1016/j.chempr.2017.05.021", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.05.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408622000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YJ; Chen, QM; Yang, WH; Ji, ZH; Jin, LM; Ma, X; Song, QH; Boltasseva, A; Han, JC; Shalaev, VM; Xiao, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yujie; Chen, Qinmiao; Yang, Wenhong; Ji, Ziheng; Jin, Limin; Ma, Xing; Song, Qinghai; Boltasseva, Alexandra; Han, Jiecai; Shalaev, Vladimir M.; Xiao, Shumin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency broadband achromatic metalens for near-IR biological imaging window", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past years, broadband achromatic metalenses have been intensively studied due to their great potential for applications in consumer and industry products. Even though significant progress has been made, the efficiency of technologically relevant silicon metalenses is limited by the intrinsic material loss above the bandgap. In turn, the recently proposed achromatic metalens utilizing transparent, high-index materials such as titanium dioxide has been restricted by the small thickness and showed relatively low focusing efficiency at longer wavelengths. Consequently, metalens-based optical imaging in the biological transparency window has so far been severely limited. Herein, we experimentally demonstrate a polarization-insensitive, broadband titanium dioxide achromatic metalens for applications in the near-infrared biological imaging. A large-scale fabrication technology has been developed to produce titanium dioxide nullopillars with record-high aspect ratios featuring pillar heights of 1.5 mu m and similar to 90 degrees vertical sidewalls. The demonstrated metalens exhibits dramatically increased group delay range, and the spectral range of achromatism is substantially extended to the wavelength range of 650-1000 nm with an average efficiency of 77.1%-88.5% and a numerical aperture of 0.24-0.1. This research paves a solid step towards practical applications of flat photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5560, "DOI": "10.1038/s41467-021-25797-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25797-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698490300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Do, JL; Friscic, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Do, Jean-Louis; Friscic, Tomislav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanochemistry: A Force of Synthesis", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The past decade has seen a reawakening of solid-state approaches to chemical synthesis, driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, i.e., chemical transformations initiated or sustained by mechanical force, has been advancing particularly rapidly, from a laboratory curiosity to a widely applicable technique that not only enables a cleaner route to chemical transformations but offers completely new opportunities in making and screening for molecules and materials. This Outlook provides a brief overview of the recent achievements and opportunities created by mechanochemistry, including access to materials, molecular targets, and synthetic strategies that are hard or even impossible to access by conventional means.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 1017, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13, "End Page": 19, "Article Number": null, "DOI": "10.1021/acscentsci.6b00277", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.6b00277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392499900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, QR; Tan, X; Bedford, NM; Han, ZJ; Thomsen, L; Smith, S; Amal, R; Lu, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qingran; Tan, Xin; Bedford, Nicholas M.; Han, Zhaojun; Thomsen, Lars; Smith, Sean; Amal, Rose; Lu, Xunyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct insights into the role of epoxy groups on cobalt sites for acidic H2O2 production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide produced by electrochemical oxygen reduction reaction provides a potentially cost effective and energy efficient alternative to the industrial anthraquinone process. In this study, we demonstrate that by modulating the oxygen functional groups near the atomically dispersed cobalt sites with proper electrochemical/chemical treatments, a highly active and selective oxygen reduction process for hydrogen peroxide production can be obtained in acidic electrolyte, showing a negligible amount of onset overpotential and nearly 100% selectivity within a wide range of applied potentials. Combined spectroscopic results reveal that the exceptionally enhanced performance of hydrogen peroxide generation originates from the presence of epoxy groups near the Co-N-4 centers, which has resulted in the modification of the electronic structure of the cobalt atoms. Computational modeling demonstrates these electronically modified cobalt atoms will enhance the hydrogen peroxide productivity during oxygen reduction reaction in acid, providing insights into the design of electroactive materials for effective peroxide production. The production of hydrogen peroxide by electrochemical oxygen reduction is an attractive alternative to the industrial process, but catalysts should be optimized. Here, the authors enhance hydrogen peroxide production in acidic media with epoxy groups near cobalt centers on carbon nullotubes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4181, "DOI": "10.1038/s41467-020-17782-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17782-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569766000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, J; Zhou, QY; Wang, HF; Xiao, Q; Qiang, Z; Li, XP; Wen, J; Ye, CH; Zhu, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Jiayu; Zhou, Qingya; Wang, Haifeng; Xiao, Qi; Qiang, Zhe; Li, Xiaopeng; Wen, Jin; Ye, Changhuai; Zhu, Meifang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically Strong, Freeze-Resistant, and Ionically Conductive Organohydrogels for Flexible Strain Sensors and Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive hydrogels as promising material candidates for soft electronics have been rapidly developed in recent years. However, the low ionic conductivity, limited mechanical properties, and insufficient freeze-resistance greatly limit their applications for flexible and wearable electronics. Herein, aramid nullofiber (ANF)-reinforced poly(vinyl alcohol) (PVA) organohydrogels containing dimethyl sulfoxide (DMSO)/H2O mixed solvents with outstanding freeze-resistance are fabricated through solution casting and 3D printing methods. The organohydrogels show both high tensile strength and toughness due to the synergistic effect of ANFs and DMSO in the system, which promotes PVA crystallization and intermolecular hydrogen bonding interactions between PVA molecules as well as ANFs and PVA, confirmed by a suite of characterization and molecular dynamics simulations. The organohydrogels also exhibit ultrahigh ionic conductivity, ranging from 1.1 to 34.3 S m(-1) at -50 to 60 degrees C. Building on these excellent material properties, the organohydrogel-based strain sensors and solid-state zinc-air batteries (ZABs) are fabricated, which have a broad working temperature range. Particularly, the ZABs not only exhibit high specific capacity (262 mAh g(-1)) with ultra-long cycling life (355 cycles, 118 h) even at -30 degrees C, but also can work properly under various deformation states, manifesting their great potential applications in soft robotics and wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206591", "DOI Link": "http://dx.doi.org/10.1002/advs.202206591", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913838700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Wang, KL; Jiang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Wang, Kangli; Jiang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Low Cost Aqueous Zn-S Battery Realizing Ultrahigh Energy Density", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc ion batteries are enabled by the (de)intercalation chemistry, but bottlenecked by the limited energy density due to the low capacity of cathodes. In this work, carbon nullotubes supported 50 wt% sulfur (denoted as S@CNTs-50), as a conversional cathode, is employed and a high energy density aqueous zinc-sulfur (Zn-S) battery is constructed . In the electrolyte of 1mZn(CH3COO)(2)(pH = 6.5) with 0.05 wt% I(2)additive where I(2)can serve as medium of Zn(2+)ions to reduce the voltage hysteresis of S@CNTs-50 and stabilize Zn stripping/plating, S@CNTs-50 delivers a high capacity of 1105 mAh g(-1)with a flat discharge voltage of 0.5 V, realizing an energy density of 502 Wh kg(-1)based on sulfur, which is one of the highest values reported in aqueous Zn-based batteries that use mild electrolyte. Moreover, the chemical materials cost of this aqueous Zn-S battery can be lowered to be $45 kWh(-1)due to the cheap raw materials, reaching to the level of pumped energy storage. Ex situ X-ray diffraction, Raman spectra, X-ray photoelectron spectrum, and transmission electron microscopy measurements reveal that sulfur cathode undergoes a conversion reaction between S and ZnS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 7, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000761, "DOI": "10.1002/advs.202000761", "DOI Link": "http://dx.doi.org/10.1002/advs.202000761", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579558800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Serlin, M; Tschirhart, CL; Polshyn, H; Zhang, Y; Zhu, J; Watanabe, K; Taniguchi, T; Balents, L; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Serlin, M.; Tschirhart, C. L.; Polshyn, H.; Zhang, Y.; Zhu, J.; Watanabe, K.; Taniguchi, T.; Balents, L.; Young, A. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic quantized anomalous Hall effect in a moire heterostructure", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantum anomalous Hall (QAH) effect combines topology and magnetism to produce precisely quantized Hall resistance at zero magnetic field. We report the observation of a QAH effect in twisted bilayer graphene aligned to hexagonal boron nitride. The effect is driven by intrinsic strong interactions, which polarize the electrons into a single spin- and valley-resolved moire miniband with Chern number C = 1. In contrast to magnetically doped systems, the measured transport energy gap is larger than the Curie temperature for magnetic ordering, and quantization to within 0.1% of the von Klitzing constant persists to temperatures of several kelvin at zero magnetic field. Electrical currents as small as 1 nulloampere controllably switch the magnetic order between states of opposite polarization, forming an electrically rewritable magnetic memory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1084, "Times Cited, All Databases": 1189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 367, "Issue": 6480, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 900, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay5533", "DOI Link": "http://dx.doi.org/10.1126/science.aay5533", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515235800041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, WZ; Geng, P; Li, GW; Zhao, D; Zhang, HB; Zhao, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Wenzheng; Geng, Peng; Li, Guiwei; Zhao, Di; Zhang, Haibo; Zhao, Ji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of Layer Thickness and Raster Angle on the Mechanical Properties of 3D-Printed PEEK and a Comparative Mechanical Study between PEEK and ABS", "Source Title": "MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused deposition modeling (FDM) is a rapidly growing 3D printing technology. However, printing materials are restricted to acrylonitrile butadiene styrene (ABS) or poly (lactic acid) (PLA) in most Fused deposition modeling (FDM) equipment. Here, we report on a new high-performance printing material, polyether-ether-ketone (PEEK), which could surmount these shortcomings. This paper is devoted to studying the influence of layer thickness and raster angle on the mechanical properties of 3D-printed PEEK. Samples with three different layer thicknesses (200, 300 and 400 mu m) and raster angles (0 degrees, 30 degrees and 45 degrees) were built using a polyether-ether-ketone (PEEK) 3D printing system and their tensile, compressive and bending strengths were tested. The optimal mechanical properties of polyether-ether-ketone (PEEK) samples were found at a layer thickness of 300 mu m and a raster angle of 0 degrees. To evaluate the printing performance of polyether-ether-ketone (PEEK) samples, a comparison was made between the mechanical properties of 3D-printed polyether-ether-ketone (PEEK) and acrylonitrile butadiene styrene (ABS) parts. The results suggest that the average tensile strengths of polyether-ether-ketone (PEEK) parts were 108% higher than those for acrylonitrile butadiene styrene (ABS), and compressive strengths were 114% and bending strengths were 115%. However, the modulus of elasticity for both materials was similar. These results indicate that the mechanical properties of 3D-printed polyether-ether-ketone (PEEK) are superior to 3D-printed ABS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 618, "Times Cited, All Databases": 682, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5834, "End Page": 5846, "Article Number": null, "DOI": "10.3390/ma8095271", "DOI Link": "http://dx.doi.org/10.3390/ma8095271", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362639200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, D; Zheng, L; Zhang, Z; Li, M; Chen, ZW; Cui, RG; Shen, YB; Li, GR; Feng, RF; Zhang, SJ; Jiang, GP; Chen, LW; Yu, AP; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Dan; Zheng, Lei; Zhang, Zhen; Li, Matthew; Chen, Zhongwei; Cui, Ruiguang; Shen, Yanbin; Li, Gaoran; Feng, Renfei; Zhang, Shaojian; Jiang, Gaopeng; Chen, Liwei; Yu, Aiping; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing multifunctional solid electrolyte interface via in-situ polymerization for dendrite-free and low N/P ratio lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stable solid electrolyte interface (SEI) is highly sought after for lithium metal batteries (LMB) owing to its efficient electrolyte consumption suppression and Li dendrite growth inhibition. However, current design strategies can hardly endow a multifunctional SEI formation due to the non-uniform, low flexible film formation and limited capability to alter Li nucleation/growth orientation, which results in unconstrained dendrite growth and short cycling stability. Herein, we present a novel strategy to employ electrolyte additives containing catechol and acrylic groups to construct a stable multifunctional SEI by in-situ anionic polymerization. This self-smoothing and robust SEI offers multiple sites for Li adsorption and steric repulsion to constrain nucleation/growth process, leading to homogenized Li nullosphere formation. This isotropic nullosphere offers non-preferred Li growth orientation, rendering uniform Li deposition to achieve a dendrite-free anode. Attributed to these superiorities, a remarkable cycling performance can be obtained, i.e., high current density up to 10mAcm(-2), ultra-long cycle life over 8500 hrs operation, high cumulative capacity over 4.25 Ah cm(-2) and stable cycling under 60 degrees C. A prolonged lifespan can also be achieved in Li-S and Li-LiFePO4 cells under lean electrolyte content, low N/P ratio or high temperature conditions. This facile strategy also promotes the practical application of LMB and enlightens the SEI design in related fields. Stable solid electrolyte interface (SEI) is heavily investigated due to its role in improving lithium metal batteries. Here, the authors present a new strategy by employing electrolyte additives to construct stable multifunctional SEI via in situ anionic polymerization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 186, "DOI": "10.1038/s41467-020-20339-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20339-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626605200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, HY; Geng, K; Wu, L; Liu, JJ; Chen, ZQ; You, W; Yan, F; Guiver, MD; Li, NW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Hongying; Geng, Kang; Wu, Lei; Liu, Junjie; Chen, Zhiquan; You, Wei; Yan, Feng; Guiver, Michael D.; Li, nullwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fuel cells with an operational range of-20 °C to 200 °C enabled by phosphoric acid-doped intrinsically ultramicroporous membranes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional proton exchange membrane fuel cells (PEMFCs) operate within narrow temperature ranges. Typically, they are run at either 80-90 degrees C using fully humidified perfluorosulfonic acid membranes, or at 140-180 degrees C using non-humidified phosphoric acid (PA)-doped membranes, to avoid water condensation-induced PA leaching. However, the ability to function over a broader range of temperature and humidity could simplify heat and water management, thus reducing costs. Here we present PA-doped intrinsically ultramicroporous membranes constructed from rigid, high free volume, Troger's base-derived polymers, which allow operation from -20 to 200 degrees C. Membranes with an average ultramicropore radius of 3.3 angstrom show a syphoning effect that allows high retention of PA even under highly humidified conditions and present more than three orders of magnitude higher proton conductivity retention than conventional dense PA-doped polybenzimidazole membranes. The resulting PA-doped PEMFCs display 95% peak power density retention after 150 start-up/shut-down cycles at 15 degrees C and can accomplish over 100 cycles, even at -20 degrees C. Most proton exchange membrane fuel cells are designed to operate within a temperature range of a few tens of degrees, but functioning in a broader range of conditions could be advantageous. Here the authors use ultramicroporous, phosphoric acid-doped membranes that allow fuel cell operation from -20 degrees C to 200 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 153, "End Page": 162, "Article Number": null, "DOI": "10.1038/s41560-021-00956-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00956-w", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737783400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QD; Zhao, CL; Wang, JL; Yao, ZP; Wang, SW; Kumar, SGH; Ganapathy, S; Eustace, S; Bai, XD; Li, BH; Wagemaker, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qidi; Zhao, Chenglong; Wang, Jianlin; Yao, Zhenpeng; Wang, Shuwei; Kumar, Sai Govind Hari; Ganapathy, Swapna; Eustace, Stephen; Bai, Xuedong; Li, Baohua; Wagemaker, Marnix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High entropy liquid electrolytes for lithium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys/compounds have large configurational entropy by introducing multiple components, showing improved functional properties that exceed those of conventional materials. However, how increasing entropy impacts the thermodynamic/kinetic properties in liquids that are ambiguous. Here we show this strategy in liquid electrolytes for rechargeable lithium batteries, demonstrating the substantial impact of raising the entropy of electrolytes by introducing multiple salts. Unlike all liquid electrolytes so far reported, the participation of several anionic groups in this electrolyte induces a larger diversity in solvation structures, unexpectedly decreasing solvation strengths between lithium ions and solvents/anions, facilitating lithium-ion diffusivity and the formation of stable interphase passivation layers. In comparison to the single-salt electrolytes, a low-concentration dimethyl ether electrolyte with four salts shows an enhanced cycling stability and rate capability. These findings, rationalized by the fundamental relationship between entropy-dominated solvation structures and ion transport, bring forward high-entropy electrolytes as a composition-rich and unexplored space for lithium batteries and beyond. Electrolytes, function as an ion conducting membrane between battery electrodes, are essential for rechargeable batteries. Here, the authors report high-entropy liquid electrolytes and reveal substantial impact of the increasing entropy on lithium-ion solvation structures for highly reversible lithium batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 440, "DOI": "10.1038/s41467-023-36075-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36075-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953273200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YL; Gibbs, ZM; Agapito, LA; Li, G; Kim, HS; Nardelli, MB; Curtarolo, S; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yinglu; Gibbs, Zachary M.; Agapito, Luis A.; Li, Guodong; Kim, Hyun-Sik; Nardelli, Marco Buongiorno; Curtarolo, Stefano; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Convergence of multi-valley bands as the electronic origin of high thermoelectric performance in CoSb3 skutterudites", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Filled skutterudites RxCo4Sb12 are excellent n-type thermoelectric materials owing to their high electronic mobility and high effective mass, combined with low thermal conductivity associated with the addition of filler atoms into the void site. The favourable electronic band structure in n-type CoSb3 is typically attributed to threefold degeneracy at the conduction band minimum accompanied by linear band behaviour at higher carrier concentrations, which is thought to be related to the increase in effective mass as the doping level increases. Using combined experimental and computational studies, we show instead that a secondary conduction band with 12 conducting carrier pockets (which converges with the primary band at high temperatures) is responsible for the extraordinary thermoelectric performance of n-type CoSb3 skutterudites. A theoretical explanation is also provided as to why the linear (or Kane-type) band feature is not beneficial for thermoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 512, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 14, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1223, "End Page": 1228, "Article Number": null, "DOI": "10.1038/nmat4430", "DOI Link": "http://dx.doi.org/10.1038/nmat4430", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365839000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Birkl, CR; Roberts, MR; McTurk, E; Bruce, PG; Howey, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Birkl, Christoph R.; Roberts, Matthew R.; McTurk, Euan; Bruce, Peter G.; Howey, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Degradation diagnostics for lithium ion cells", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Degradation in lithium ion (Li-ion) battery cells is the result of a complex interplay of a host of different physical and chemical mechanisms. The measurable, physical effects of these degradation mechanisms on the cell can be summarised in terms of three degradation modes, namely loss of lithium inventory, loss of active positive electrode material and loss of active negative electrode material. The different degradation modes are assumed to have unique and measurable effects on the open circuit voltage (OCV) of Li-ion cells and electrodes. The presumptive nature and extent of these effects has so far been based on logical arguments rather than experimental proof. This work presents, for the first time, experimental evidence supporting the widely reported degradation modes by means of tests conducted on coin cells, engineered to include different, known amounts of lithium inventory and active electrode material. Moreover, the general theory behind the effects of degradation modes on the OCV of cells and electrodes is refined and a diagnostic algorithm is devised, which allows the identification and quantification of the nature and extent of each degradation mode in Li-ion cells at any point in their service lives, by fitting the cells' OCV. (C) 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1116, "Times Cited, All Databases": 1220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2017, "Volume": 341, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 373, "End Page": 386, "Article Number": null, "DOI": "10.1016/j.jpowsour.2016.12.011", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2016.12.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393003400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chortos, A; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chortos, Alex; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-inspired electronic devices", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic devices that mimic the properties of skin have potential important applications in advanced robotics, prosthetics, and health monitoring technologies. Methods for measuring tactile and temperature signals have progressed rapidly due to innovations in materials and processing methods. Imparting skin-like stretchability to electronic devices can be accomplished by patterning traditional electronic materials or developing new materials that are intrinsically stretchable. The incorporation of sensing methods with transistors facilitates large-area sensor arrays. While sensor arrays have surpassed the properties of human skin in terms of sensitivity, time response, and device density, many opportunities remain for future development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 17, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 321, "End Page": 331, "Article Number": null, "DOI": "10.1016/j.mattod.2014.05.006", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.05.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342360600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HY; Sun, XB; Yang, SH; Zhao, PY; Zhang, XJ; Wang, GS; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hui-Ya; Sun, Xiao-Bo; Yang, Shu-Hao; Zhao, Pei-Yan; Zhang, Xiao-Juan; Wang, Guang-Sheng; Huang, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Ultralight Hollow NiCo Compound@MXene Composites for Tunable and High-Efficient Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The 3D hollow hierarchical architectures tend to be designed for inhibiting stack of MXene flakes to obtain satisfactory lightweight, high-efficient and broadband absorbers. Herein, the hollow NiCo compound@MXene networks were prepared by etching the ZIF 67 template and subsequently anchoring the Ti3C2Tx nullosheets through electrostatic self-assembly. The electromagnetic parameters and microwave absorption property can be distinctly or slightly regulated by adjusting the filler loading and decoration of Ti3C2Tx nulloflakes. Based on the synergistic effects of multi-components and special well-constructed structure, NiCo layered double hydroxides@Ti3C2Tx (LDHT-9) absorber remarkably achieves unexpected effective absorption bandwidth (EAB) of 6.72 GHz with a thickness of 2.10 mm, covering the entire Ku-band. After calcination, transition metal oxide@Ti3C2Tx (TMOT-21) absorber near the percolation threshold possesses minimum reflection loss (RLmin) value of - 67.22 dB at 1.70 mm within a filler loading of only 5 wt%. This work enlightens a simple strategy for constructing MXene-based composites to achieve high-efficient microwave absorbents with lightweight and tunable EAB.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 206, "DOI": "10.1007/s40820-021-00727-y", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00727-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000706174800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, ZC; Lu, JQ; Zhang, TW; Liang, HF; Yuan, H; Su, DH; Ding, W; Lian, RX; Ge, YX; Liang, B; Dong, J; Zhou, XG; Jiang, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zhi-Chao; Lu, Jia-Qi; Zhang, Tai-Wei; Liang, Hai-Feng; Yuan, Hao; Su, Di-Han; Ding, Wang; Lian, Rui-Xian; Ge, Yu-Xiang; Liang, Bing; Dong, Jian; Zhou, Xiao-Gang; Jiang, Li-Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezoresistive MXene/Silk fibroin nullocomposite hydrogel for accelerating bone regeneration by Re-establishing electrical microenvironment", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrical microenvironment plays an important role in bone repair. However, the underlying mechanism by which electrical stimulation (ES) promotes bone regeneration remains unclear, limiting the design of bone microenvironment-specific electroactive materials. Herein, by simple co-incubation in aqueous suspensions at physiological temperatures, biocompatible regenerated silk fibroin (RSF) is found to assemble into nullofibrils with a beta-sheet structure on MXene nullosheets, which has been reported to inhibit the restacking and oxidation of MXene. An electroactive hydrogel based on RSF and bioencapsulated MXene is thus prepared to promote effi-cient bone regeneration. This MXene/RSF hydrogel also acts as a piezoresistive pressure transducer, which can potentially be utilized to monitor the electrophysiological microenvironment. RNA sequencing is performed to explore the underlying mechanisms, which can activate Ca2+/CALM signaling in favor of the direct osteogenesis process. ES is found to facilitate indirect osteogenesis by promoting the polarization of M2 macrophages, as well as stimulating the neogenesis and migration of endotheliocytes. Consistent improvements in bone regeneration and angiogenesis are observed with MXene/RSF hydrogels under ES in vivo. Collectively, the MXene/RSF hydrogel provides a distinctive and promising strategy for promoting direct osteogenesis, regulating immune microenvironment and neovascularization under ES, leading to re-establish electrical microenvironment for bone regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 17, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.08.025", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.08.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888578900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HJ; Wang, DW; Huang, JQ; Cheng, XB; Yuan, Z; Wei, F; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Hong-Jie; Wang, Dai-Wei; Huang, Jia-Qi; Cheng, Xin-Bing; Yuan, Zhe; Wei, Fei; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Janus Separator of Polypropylene-Supported Cellular Graphene Framework for Sulfur Cathodes with High Utilization in Lithium-Sulfur Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the conversion chemistry of the sulfur cathode, the lithium-sulfur (Li-S) batteries exhibit high theoretical energy density. However, the intrinsic mobile redox centers during the sulfur/Li2S-to-lithium polysulfides solid-to-liquid phase transition induce low sulfur utilization and poor cycling life. Herein, the Janus separator of mesoporous cellular graphene framework (CGF)/polypropylene membrane to promote the utilization of sulfur cathode is introduced. The porous polypropylene membrane serves as an insulating substrate in contact with lithium anode while CGFs that possess high electrical conductivity of 100 S cm(-1), a large mesopore volume of 3.1 cm(3) g(-1), and a huge surface area of 2120 m(2) g(-1) are adhered on cathode side to reactivate the shuttling-back polysulfides and to preserve the ion channels. Therefore, the Li-S cell with the two-face CGF Janus separator exhibit a high initial capacity of 1109 mAh g(-1) and superior capacity preserved upon 800 mAh g(-1) after 250 cycles at 0.2 C, which is 40% higher on sulfur utilization efficiency than the corresponding results with routine polypropylene separators. There are significant improvements on capacity as well as electrochemical kinetics. A very high areal capacity of 5.5 mAh cm(-2) combined with high sulfur content of 80% and areal loading amount of 5.3 mg cm(-2) is achieved for such advanced configuration. The negative impact of shuttle mechanism on lowering the utilization of sulfur and overall energy density of a Li-S battery is well eliminated by applying CGF separators. Consequently, employing carbonaceous materials as Janus face of separators enlightens new opportunities for improving the utilization of active materials and energy density of devices that involve complex phase evolution and conversion electrochemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500268, "DOI": "10.1002/advs.201500268", "DOI Link": "http://dx.doi.org/10.1002/advs.201500268", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369004800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JG; Wang, YX; Huang, Y; Gopaluni, RB; Cao, YK; Heere, M; Mühlbauer, MJ; Mereacre, L; Dai, HF; Liu, XH; Senyshyn, A; Wei, XZ; Knapp, M; Ehrenberg, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jiangong; Wang, Yixiu; Huang, Yuan; Gopaluni, R. Bhushan; Cao, Yankai; Heere, Michael; Muhlbauer, Martin J.; Mereacre, Liuda; Dai, Haifeng; Liu, Xinhua; Senyshyn, Anatoliy; Wei, Xuezhe; Knapp, Michael; Ehrenberg, Helmut", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-driven capacity estimation of commercial lithium-ion batteries from voltage relaxation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate capacity estimation is crucial for lithium-ion batteries' reliable and safe operation. Here, the authors propose an approach exploiting features from the relaxation voltage curve for battery capacity estimation without requiring other previous cycling information. Accurate capacity estimation is crucial for the reliable and safe operation of lithium-ion batteries. In particular, exploiting the relaxation voltage curve features could enable battery capacity estimation without additional cycling information. Here, we report the study of three datasets comprising 130 commercial lithium-ion cells cycled under various conditions to evaluate the capacity estimation approach. One dataset is collected for model building from batteries with LiNi0.86Co0.11Al0.03O2-based positive electrodes. The other two datasets, used for validation, are obtained from batteries with LiNi0.83Co0.11Mn0.07O2-based positive electrodes and batteries with the blend of Li(NiCoMn)O-2 - Li(NiCoAl)O-2 positive electrodes. Base models that use machine learning methods are employed to estimate the battery capacity using features derived from the relaxation voltage profiles. The best model achieves a root-mean-square error of 1.1% for the dataset used for the model building. A transfer learning model is then developed by adding a featured linear transformation to the base model. This extended model achieves a root-mean-square error of less than 1.7% on the datasets used for the model validation, indicating the successful applicability of the capacity estimation approach utilizing cell voltage relaxation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2261, "DOI": "10.1038/s41467-022-29837-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29837-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788592600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, K; Wan, GL; Deng, P; Zhang, KN; Ding, SJ; Wang, EY; Yan, MZ; Huang, HQ; Zhang, HY; Xu, ZL; Denlinger, J; Fedorov, A; Yang, HT; Duan, WH; Yao, H; Wu, Y; Fan, SS; Zhang, HJ; Chen, X; Zhou, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Ke; Wan, Guoliang; Deng, Peng; Zhang, Kenull; Ding, Shijie; Wang, Eryin; Yan, Mingzhe; Huang, Huaqing; Zhang, Hongyun; Xu, Zhilin; Denlinger, Jonathan; Fedorov, Alexei; Yang, Haitao; Duan, Wenhui; Yao, Hong; Wu, Yang; Fan, Shoushan; Zhang, Haijun; Chen, Xi; Zhou, Shuyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental observation of topological Fermi arcs in type-II Weyl semimetal MoTe2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetal is a new quantum state of matter(1-12) hosting the condensed matter physics counterpart of the relativistic Weyl fermions(13) originally introduced in high-energy physics. The Weyl semimetal phase realized in the TaAs class of materials features multiple Fermi arcs arising from topological surface states(10,11,14-16) and exhibits novel quantum phenomena, such as a chiral anomaly-induced negative magnetoresistance(17-19) and possibly emergent supersymmetry(20). Recently it was proposed theoretically that a new type (type-II) of Weyl fermion(21,22) that arises due to the breaking of Lorentz invariance, which does not have a counterpart in high-energy physics, can emerge as topologically protected touching between electron and hole pockets. Here, we report direct experimental evidence of topological Fermi arcs in the predicted type-II Weyl semimetal MoTe2 (refs 23-25). The topological surface states are confirmed by directly observing the surface states using bulk-and surface-sensitive angle-resolved photoemission spectroscopy, and the quasi-particle interference pattern between the putative topological Fermi arcs in scanning tunnelling microscopy. By establishing MoTe2 as an experimental realization of a type-II Weyl semimetal, our work opens up opportunities for probing the physical properties of this exciting new state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 679, "Times Cited, All Databases": 736, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1105, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3871", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3871", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389133800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HZ; Firby, CJ; Elezzabi, AY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Haizeng; Firby, Curtis J.; Elezzabi, Abdulhakem Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rechargeable Aqueous Hybrid Zn2+/Al3+ Electrochromic Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochromic batteries are a newly born technology for next-generation transparent electronics. As electrochromic materials are typically bottlenecked by limited capacity and strict selection of triggered ions, the design of high-performance electrochromic batteries remains an elusive goal. Here, we present an aqueous hybrid Zn2+/Al3+ electrochromic battery system utilizing an electrolyte with both Zn2+ and Al3+. This unique architecture yields remarkable electrochemical performance, including rapid self-coloration time (0.5 s) and switching times (3.9 and 5.1 s for the coloration and bleaching processes), a high optical contrast (88%), and a large areal capacity (185.6 mAh/m(2) at 0.5 mA/cm(2)). Consequently, these properties, which are the highest of any reported electrochromic battery presented to date, mark our hybrid electrolyte architecture as the most promising candidate for future device integration. Furthermore, with the outstanding performance of this safe aqueous electrolyte, our hybrid Zn2+/Al3+ electrochromic battery platform is expected to be a significant catalyst for accelerating the development of electrochromic devices in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2019, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2268, "End Page": 2278, "Article Number": null, "DOI": "10.1016/j.joule.2019.06.021", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.06.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486444700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CX; Liu, JN; Wang, J; Wang, CD; Guo, X; Li, XY; Chen, X; Song, L; Li, BQ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chang-Xin; Liu, Jia-Ning; Wang, Juan; Wang, Changda; Guo, Xin; Li, Xi-Yao; Chen, Xiao; Song, Li; Li, Bo-Quan; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A clicking confinement strategy to fabricate transition metal single-atom sites for bifunctional oxygen electrocatalysis", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable zinc-air batteries call for high-performance bifunctional oxygen electrocatalysts. Transition metal single-atom catalysts constitute a promising candidate considering their maximum atom efficiency and high intrinsic activity. However, the fabrication of atomically dispersed transition metal sites is highly challenging, creating a need for for new design strategies and synthesis methods. Here, a clicking confinement strategy is proposed to efficiently predisperse transitional metal atoms in a precursor directed by click chemistry and ensure successful construction of abundant single-atom sites. Concretely, cobalt-coordinated porphyrin units are covalently clicked on the substrate for the confinement of the cobalt atoms and affording a Co-N-C electrocatalyst. The Co-N-C electrocatalyst exhibits impressive bifunctional oxygen electrocatalytic performances with an activity indicator Delta E of 0.79 V. This work extends the approach to prepare transition metal single-atom sites for efficient bifunctional oxygen electrocatalysis and inspires the methodology on precise synthesis of catalytic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabn5091", "DOI": "10.1126/sciadv.abn5091", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abn5091", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770280500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bertassoni, LE; Cardoso, JC; Manoharan, V; Cristino, AL; Bhise, NS; Araujo, WA; Zorlutuna, P; Vrana, NE; Ghaemmaghami, AM; Dokmeci, MR; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bertassoni, Luiz E.; Cardoso, Juliana C.; Manoharan, Vijayan; Cristino, Ana L.; Bhise, Nupura S.; Araujo, Wesleyan A.; Zorlutuna, Pinar; Vrana, Nihal E.; Ghaemmaghami, Amir M.; Dokmeci, Mehmet R.; Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct-write bioprinting of cell-laden methacrylated gelatin hydrogels", "Source Title": "BIOFABRICATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fabrication of three dimensional (3D) organoids with controlled microarchitectures has been shown to enhance tissue functionality. Bioprinting can be used to precisely position cells and cell-laden materials to generate controlled tissue architecture. Therefore, it represents an exciting alternative for organ fabrication. Despite the rapid progress in the field, the development of printing processes that can be used to fabricate macroscale tissue constructs from ECM-derived hydrogels has remained a challenge. Here we report a strategy for bioprinting of photolabile cell-laden methacrylated gelatin (GelMA) hydrogels. We bioprinted cell-laden GelMA at concentrations ranging from 7 to 15% with varying cell densities and found a direct correlation between printability and the hydrogel mechanical properties. Furthermore, encapsulated HepG2 cells preserved cell viability for at least eight days following the bioprinting process. In summary, this work presents a strategy for direct-write bioprinting of a cell-laden photolabile ECM-derived hydrogel, which may find widespread application for tissue engineering, organ printing and the development of 3D drug discovery platforms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 463, "Times Cited, All Databases": 546, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24105, "DOI": "10.1088/1758-5082/6/2/024105", "DOI Link": "http://dx.doi.org/10.1088/1758-5082/6/2/024105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337705000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, GS; Zou, YP; Antaris, AL; Diao, S; Wu, D; Cheng, K; Zhang, XD; Chen, CX; Liu, B; He, YH; Wu, JZ; Yuan, J; Zhang, B; Tao, ZM; Fukunaga, C; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Guosong; Zou, Yingping; Antaris, Alexander L.; Diao, Shuo; Wu, Di; Cheng, Kai; Zhang, Xiaodong; Chen, Changxin; Liu, Bo; He, Yuehui; Wu, Justin Z.; Yuan, Jun; Zhang, Bo; Tao, Zhimin; Fukunaga, Chihiro; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast fluorescence imaging in vivo with conjugated polymer fluorophores in the second near-infrared window", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In vivo fluorescence imaging in the second near-infrared window (1.0-1.7 mu m) can afford deep tissue penetration and high spatial resolution, owing to the reduced scattering of long-wavelength photons. Here we synthesize a series of low-bandgap donor/acceptor copolymers with tunable emission wavelengths of 1,050-1,350 nm in this window. Non-covalent functionalization with phospholipid-polyethylene glycol results in water-soluble and biocompatible polymeric nulloparticles, allowing for live cell molecular imaging at >1,000 nm with polymer fluorophores for the first time. Importantly, the high quantum yield of the polymer allows for in vivo, deep-tissue and ultrafast imaging of mouse arterial blood flow with an unprecedented frame rate of >25 frames per second. The high time-resolution results in spatially and time resolved imaging of the blood flow pattern in cardiogram waveform over a single cardiac cycle (similar to 200 ms) of a mouse, which has not been observed with fluorescence imaging in this window before.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4206, "DOI": "10.1038/ncomms5206", "DOI Link": "http://dx.doi.org/10.1038/ncomms5206", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338839100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, DW; Wang, KC; Wei, ZW; Chen, YP; Simon, CM; Arvapally, RK; Martin, RL; Bosch, M; Liu, TF; Fordham, S; Yuan, DQ; Omary, MA; Haranczyk, M; Smit, B; Zhou, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Dawei; Wang, Kecheng; Wei, Zhangwen; Chen, Ying-Pin; Simon, Cory M.; Arvapally, Ravi K.; Martin, Richard L.; Bosch, Mathieu; Liu, Tian-Fu; Fordham, Stephen; Yuan, Daqiang; Omary, Mohammad A.; Haranczyk, Maciej; Smit, Berend; Zhou, Hong-Cai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal-organic frameworks in the form of crystalline solids, especially as single crystals. Here we present a kinetically tuned dimensional augmentation synthetic route for the preparation of highly crystalline and extremely robust metal-organic frameworks with a preserved metal cluster core. Through this versatile synthetic route, we obtain large single crystals of 34 different iron-containing metal-organic frameworks. Among them, PCN-250(Fe2Co) exhibits high volumetric uptake of hydrogen and methane, and is also stable in water and aqueous solutions with a wide range of pH values.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5723, "DOI": "10.1038/ncomms6723", "DOI Link": "http://dx.doi.org/10.1038/ncomms6723", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347229600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wirthl, D; Pichler, R; Drack, M; Kettlguber, G; Moser, R; Gerstmayr, R; Hartmann, F; Bradt, E; Kaltseis, R; Siket, CM; Schausberger, SE; Hild, S; Bauer, S; Kaltenbrunner, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wirthl, Daniela; Pichler, Robert; Drack, Michael; Kettlguber, Gerald; Moser, Richard; Gerstmayr, Robert; Hartmann, Florian; Bradt, Elke; Kaltseis, Rainer; Siket, Christian M.; Schausberger, Stefan E.; Hild, Sabine; Bauer, Siegfried; Kaltenbrunner, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Instant tough bonding of hydrogels for soft machines and electronics", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Introducing methods for instant tough bonding between hydrogels and antagonistic materials-from soft to hard-allows us to demonstrate elastic yet tough biomimetic devices and machines with a high level of complexity. Tough hydrogels strongly attach, within seconds, to plastics, elastomers, leather, bone, and metals, reaching unprecedented interfacial toughness exceeding 2000 J/m(2). Healing of severed ionic hydrogel conductors becomes feasible and restores function instantly. Soft, transparent multilayered hybrids of elastomers and ionic hydrogels endure biaxial strain with more than 2000% increase in area, facilitating soft transducers, generators, and adaptive lenses. We demonstrate soft electronic devices, from stretchable batteries, self-powered compliant circuits, and autonomous electronic skin for triggered drug delivery. Our approach is applicable in rapid prototyping and in delicate environments inaccessible for extended curing and cross-linking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700053", "DOI": "10.1126/sciadv.1700053", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406370700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seh, ZW; Sun, J; Sun, YM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seh, Zhi Wei; Sun, Jie; Sun, Yongming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Reversible Room-Temperature Sodium Metal Anode", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to its low cost and high natural abundance, sodium metal is among the most promising anode materials for energy storage technologies beyond lithium ion batteries. However, room-temperature sodium metal anodes suffer from poor reversibility during long-term plating and stripping, mainly due to formation of nonuniform solid electrolyte interphase as well as dendritic growth of sodium metal. Herein we report for the first time that a simple liquid electrolyte, sodium hexafluorophosphate in glymes (mono-, di-, and tetraglyme), can enable highly reversible and nondendritic plating-stripping of sodium metal anodes at room temperature. High average Coulombic efficiencies of 99.9% were achieved over 300 plating-stripping cycles at 0.5 mA cm(-2). The long-term reversibility was found to arise from the formation of a uniform, inorganic solid electrolyte interphase made of sodium oxide and sodium fluoride, which is highly impermeable to electrolyte solvent and conducive to nondendritic growth. As a proof of concept, we also demonstrate a room-temperature sodium-sulfur battery using this class of electrolytes, paving the way for the development of next-generation, sodium-based energy storage technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 787, "Times Cited, All Databases": 841, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2015, "Volume": 1, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 449, "End Page": 455, "Article Number": null, "DOI": "10.1021/acscentsci.5b00328", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.5b00328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365969600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Yu, L; Hu, L; Chen, G; Xin, HL; Feng, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jun; Yu, Liang; Hu, Lin; Chen, Gang; Xin, Hongliang; Feng, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of N-2 to NH3 provides an alternative to the Haber-Bosch process for sustainable, distributed production of NH3 when powered by renewable electricity. However, the development of such process has been impeded by the lack of efficient electrocatalysts for N-2 reduction. Here we report efficient electroreduction of N-2 to NH3 on palladium nulloparticles in phosphate buffer solution under ambient conditions, which exhibits high activity and selectivity with an NH3 yield rate of similar to 4.5 mu g mg(Pd)(-1) h(-1) and a Faradaic efficiency of 8.2% at 0.1 V vs. the reversible hydrogen electrode ( corresponding to a low overpotential of 56 mV), outperforming other catalysts including gold and platinum. Density functional theory calculations suggest that the unique activity of palladium originates from its balanced hydrogen evolution activity and the Grotthuss-like hydride transfer mechanism on a-palladium hydride that lowers the free energy barrier of N-2 hydrogenation to *N2H, the rate-limiting step for NH3 electrosynthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 670, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1795, "DOI": "10.1038/s41467-018-04213-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04213-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432114900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, TT; Zhou, BY; Zheng, Q; Wang, LJ; Jiang, W; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Tingting; Zhou, Beiying; Zheng, Qi; Wang, Lianjun; Jiang, Wan; Snyder, Gerald Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable fabric generates electric power from woven thermoelectric fibers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Assembling thermoelectric modules into fabric to harvest energy from body heat could one day power multitudinous wearable electronics. However, the invalid 2D architecture of fabric limits the application in thermoelectrics. Here, we make the valid thermoelectric fabric woven out of thermoelectric fibers producing an unobtrusive working thermoelectric module. Alternately doped carbon nullotube fibers wrapped with acrylic fibers are woven into p-type thermoelectric modules. Utilizing elasticity originating from interlocked thermoelectric modules, stretchable 3D thermoelectric generators without substrate can be made to enable sufficient alignment with the heat flow direction. The textile generator shows a peak power density of 70mWm(-2) for a temperature difference of 44 K and excellent stretchability (similar to 80% strain) with no output degradation. The compatibility between body movement and sustained power supply is further displayed. The generators described here are true textiles, proving active thermoelectrics can be woven into various fabric architectures for sensing, energy harvesting, or thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 572, "DOI": "10.1038/s41467-020-14399-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14399-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563511900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wyatt, BC; Rosenkranz, A; Anasori, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wyatt, Brian C.; Rosenkranz, Andreas; Anasori, Babak", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D MXenes: Tunable Mechanical and Tribological Properties", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition metal carbides, nitrides, and carbonitrides, known as MXenes, were discovered in 2011 and have grown to prominence in energy storage, catalysis, electromagnetic interference shielding, wireless communications, electronic, sensors, and environmental and biomedical applications. In addition to their high electrical conductivity and electrochemically active behavior, MXenes' mechanical properties, flexibility, and strong adhesion properties play crucial roles in almost all of these growing applications. Although these properties prove to be critical in MXenes' impressive performance, the mechanical and tribological understanding of MXenes, as well as their relation to the synthesis process, is yet to be fully explored. Here, a fundamental overview of MXenes' mechanical and tribological properties is provided and the effects of MXenes' compositions, synthesis, and processing steps on these properties are discussed. Additionally, a critical perspective of the compositional control of MXenes for innovative structural, low-friction, and low-wear performance in current and upcoming applications of MXenes is provided. It is established here that the fundamental understanding of MXenes' mechanical and tribological behavior is essential for their quickly growing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 33, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007973, "DOI": "10.1002/adma.202007973", "DOI Link": "http://dx.doi.org/10.1002/adma.202007973", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630225400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, C; Luo, G; Zhang, JB; Chen, MH; Wang, ZQ; Sham, TK; Zhang, LJ; Li, YF; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Chen; Luo, Gan; Zhang, Junbo; Chen, Menghuan; Wang, Zhiqiang; Sham, Tsun-Kong; Zhang, Lijuan; Li, Yafei; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double sulfur vacancies by lithium tuning enhance CO2 electroreduction to n-propanol", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction can produce valuable products with high energy densities but the process is plagued by poor selectivities and low yields. Propanol represents a challenging product to obtain due to the complicated C-3 forming mechanism that requires both stabilization of *C-2 intermediates and subsequent C-1-C-2 coupling. Herein, density function theory calculations revealed that double sulfur vacancies formed on hexagonal copper sulfide can feature as efficient electrocatalytic centers for stabilizing both CO* and OCCO* dimer, and further CO-OCCO coupling to form C-3 species, which cannot be realized on CuS with single or no sulfur vacancies. The double sulfur vacancies were then experimentally synthesized by an electrochemical lithium tuning strategy, during which the density of sulfur vacancies was well-tuned by the charge/discharge cycle number. The double sulfur vacancy-rich CuS catalyst exhibited a Faradaic efficiency toward n-propanol of 15.41% at -1.05V versus reversible hydrogen electrode in H-cells, and a high partial current density of 9.9mAcm(-2) at -0.85V in flow-cells, comparable to the best reported electrochemical CO2 reduction toward n-propanol. Our work suggests an attractive approach to create anion vacancy pairs as catalytic centers for multi-carbon-products. Electrochemical CO2 reduction to the valuable n-propanol is challenging due to the complicated C-3 forming mechanism. Here, authors demonstrate double sulfur vacancies formed on hexagonal copper sulfide can serve as efficient electrocatalytic centers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1580, "DOI": "10.1038/s41467-021-21901-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21901-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629597700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Luan, JY; Seth, A; Liu, L; You, ML; Gupta, P; Rathi, P; Wang, YX; Cao, SS; Jiang, QS; Zhang, X; Gupta, R; Zhou, QJ; Morrissey, JJ; Scheller, EL; Rudra, JS; Singamaneni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zheyu; Luan, Jingyi; Seth, Anushree; Liu, Lin; You, Minli; Gupta, Prashant; Rathi, Priya; Wang, Yixuan; Cao, Sisi; Jiang, Qisheng; Zhang, Xiao; Gupta, Rohit; Zhou, Qingjun; Morrissey, Jeremiah J.; Scheller, Erica L.; Rudra, Jai S.; Singamaneni, Srikanth", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microneedle patch for the ultrasensitive quantification of protein biomarkers in interstitial fluid", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A microneedle patch that samples and quantifies target protein biomarkers in interstitial fluid allows for longitudinal monitoring of the levels of a range of disease-relevant biomarkers, as shown in live mice. The detection and quantification of protein biomarkers in interstitial fluid is hampered by challenges in its sampling and analysis. Here we report the use of a microneedle patch for fast in vivo sampling and on-needle quantification of target protein biomarkers in interstitial fluid. We used plasmonic fluor-an ultrabright fluorescent label-to improve the limit of detection of various interstitial fluid protein biomarkers by nearly 800-fold compared with conventional fluorophores, and a magnetic backing layer to implement conventional immunoassay procedures on the patch and thus improve measurement consistency. We used the microneedle patch in mice for minimally invasive evaluation of the efficiency of a cocaine vaccine, for longitudinal monitoring of the levels of inflammatory biomarkers, and for efficient sampling of the calvarial periosteum-a challenging site for biomarker detection-and the quantification of its levels of the matricellular protein periostin, which cannot be accurately inferred from blood or other systemic biofluids. Microneedle patches for the minimally invasive collection and analysis of biomarkers in interstitial fluid might facilitate point-of-care diagnostics and longitudinal monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 64, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41551-020-00672-y", "DOI Link": "http://dx.doi.org/10.1038/s41551-020-00672-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000610199900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, LL; Maccari, F; Souza, IR; Peter, NJ; Wei, Y; Gault, B; Gutfleisch, O; Li, ZM; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Liuliu; Maccari, Fernulldo; Souza Filho, Isnaldi R.; Peter, Nicolas J.; Wei, Ye; Gault, Baptiste; Gutfleisch, Oliver; Li, Zhiming; Raabe, Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mechanically strong and ductile soft magnet with extremely low coercivity", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft magnetic materials (SMMs) serve in electrical applications and sustainable energy supply, allowing magnetic flux variation in response to changes in applied magnetic field, at low energy loss(1). The electrification of transport, households and manufacturing leads to an increase in energy consumption owing to hysteresis losses(2). Therefore, minimizing coercivity, which scales these losses, is crucial(3). Yet meeting this target alone is not enough: SMMs in electrical engines must withstand severe mechanical loads; that is, the alloys need high strength and ductility(4). This is a fundamental design challenge, as most methods that enhance strength introduce stress fields that can pin magnetic domains, thus increasing coercivity and hysteresis losses(5). Here we introduce an approach to overcome this dilemma. We have designed a Fe-Co-Ni-Ta-Al multicomponent alloy (MCA) with ferromagnetic matrix and paramagnetic coherent nulloparticles (about 91 nm in size and around 55% volume fraction). They impede dislocation motion, enhancing strength and ductility. Their small size, low coherency stress and small magnetostatic energy create an interaction volume below the magnetic domain wall width, leading to minimal domain wall pinning, thus maintaining the soft magnetic properties. The alloy has a tensile strength of 1,336 MPa at 54% tensile elongation, extremely low coercivity of 78 A m(-1) (less than 1 Oe), moderate saturation magnetization of 100 A m(2) kg(-1) and high electrical resistivity of 103 mu Omega cm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2022, "Volume": 608, "Issue": 7922, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 310, "End Page": 316, "Article Number": null, "DOI": "10.1038/s41586-022-04935-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04935-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000838658900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hulva, J; Meier, M; Bliem, R; Jakub, Z; Kraushofer, F; Schmid, M; Diebold, U; Franchini, C; Parkinson, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hulva, Jan; Meier, Matthias; Bliem, Roland; Jakub, Zdenek; Kraushofer, Florian; Schmid, Michael; Diebold, Ulrike; Franchini, Cesare; Parkinson, Gareth S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling CO adsorption on model single-atom catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding how the local environment of a single-atom catalyst affects stability and reactivity remains a challenge. We present an in-depth study of copper(1), silver(1), gold(1), nickel(1), palladium(1), platinum(1), rhodium(1), and iridium(1) species on Fe3O4(001), a model support in which all metals occupy the same twofold-coordinated adsorption site upon deposition at room temperature. Surface science techniques revealed that CO adsorption strength at single metal sites differs from the respective metal surfaces and supported clusters. Charge transfer into the support modifies the d-states of the metal atom and the strength of the metal-CO bond. These effects could strengthen the bond (as for Ag-1-CO) or weaken it (as for Ni-1-CO), but CO-induced structural distortions reduce adsorption energies from those expected on the basis of electronic structure alone. The extent of the relaxations depends on the local geometry and could be predicted by analogy to coordination chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2021, "Volume": 371, "Issue": 6527, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 375, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abe5757", "DOI Link": "http://dx.doi.org/10.1126/science.abe5757", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609884600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, FS; Day, BM; Chen, YC; Tong, ML; Mansikkamäki, A; Layfield, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong; Tong, Ming-Liang; Mansikkamaki, Akseli; Layfield, Richard A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current drawback is that all SMMs require liquid-helium cooling to show magnetic memory effects. We now report a chemical strategy to access the dysprosium metallocene cation [(Cp-iPr5)Dy(Cp*)](+) (Cp-iPr5, penta-iso-propylcyclopentadienyl; Cp*, pentamethylcyclopentadienyl), which displays magnetic hysteresis above liquid-nitrogen temperatures. An effective energy barrier to reversal of the magnetization of U-eff = 1541 wave number is also measured. The magnetic blocking temperature of T-B = 80 kelvin for this cation overcomes an essential barrier toward the development of nullomagnet devices that function at practical temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1491, "Times Cited, All Databases": 1549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2018, "Volume": 362, "Issue": 6421, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1400, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav0652", "DOI Link": "http://dx.doi.org/10.1126/science.aav0652", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453845000058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JP; Wang, MX; Liu, ZL; Ge, JF; Yang, XJ; Liu, CH; Xu, ZA; Guan, DD; Gao, CL; Qian, D; Liu, Y; Wang, QH; Zhang, FC; Xue, QK; Jia, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jin-Peng; Wang, Mei-Xiao; Liu, Zhi Long; Ge, Jian-Feng; Yang, Xiaojun; Liu, Canhua; Xu, Zhu An; Guan, Dandan; Gao, Chun Lei; Qian, Dong; Liu, Ying; Wang, Qiang-Hua; Zhang, Fu-Chun; Xue, Qi-Kun; Jia, Jin-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Detection of a Majorana Mode in the core of a Magnetic Vortex inside a Topological Insulator-Superconductor Bi2Te3/NbSe2 Heterostructure", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Majorana fermions have been intensively studied in recent years for their importance to both fundamental science and potential applications in topological quantum computing. They are predicted to exist in a vortex core of superconducting topological insulators. However, it is extremely difficult to distinguish them experimentally from other quasiparticle states for the tiny energy difference between Majorana fermions and these states, which is beyond the energy resolution of most available techniques. Here, we circumvent the problem by systematically investigating the spatial profile of the Majorana mode and the bound quasiparticle states within a vortex in Bi2Te3 films grown on a superconductor NbSe2. While the zero bias peak in local conductance splits right off the vortex center in conventional superconductors, it splits off at a finite distance similar to 20 nm away from the vortex center in Bi2Te3. This unusual splitting behavior has never been observed before and could be possibly due to the Majorana fermion zero mode. While the Majorana mode is destroyed by the interaction between vortices, the zero bias peak splits as a conventional superconductor again. This work provides self-consistent evidences of Majorana fermions and also suggests a possible route to manipulating them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2015, "Volume": 114, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17001, "DOI": "10.1103/PhysRevLett.114.017001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.017001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348572200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortazavian, S; An, H; Chun, D; Moon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortazavian, Soroosh; An, Hyeunhwan; Chun, Dongwon; Moon, Jaeyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activated carbon impregnated by zero-valent iron nulloparticles (AC/nZVI) optimized for simultaneous adsorption and reduction of aqueous hexavalent chromium: Material characterizations and kinetic studies", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullo-scale zero valent iron (nZVI) particles are one of the efficient materials for water treatment. However, their tendency for agglomeration is one of the major reported drawbacks. In this study, nZVI particles were immobilized onto activated carbon (AC/nZVI) using a two-step synthesis procedure and were applied for simultaneous adsorption and reduction of hexavalent chromium (Cr(VI)) from aqueous solutions. Synthesized AC/nZVI was characterized by SEM, EDS, XRD, XPS, and the Tafel corrosion test. The effects of varying annealing temperatures and times in the first synthesis step were investigated by examining crystal structure changes in the final AC/nZVI samples using XRD, and by running Cr(VI) removal batch experiments. Consequently, the best annealing conditions that provided the AC/nZVI composite with the greatest amount of Cr(VI) removal was determined. The Cr(VI) removal experiments showed that the optimized AC/nZVI was significantly superior than virgin AC applied under the same conditions. A pseudo-second-order model was found to be a good fit for both the AC and AC/nZVI data, showing that Cr(VI) removal rate was 2.2 times faster when using AC/nZVI compared to AC (k'(2AC/nZVI)= 0.363 g mg(-1) h(-1) vs. k'(2AC)= 0.164 g mg(-1) h(-1)). Weber and Boyd kinetics models were used to study adsorbate diffusion in AC and AC/nZVI. Isotherm studies revealed that both Freundlich and Langmuir isotherms could describe the AC data, while the Freundlich model was well suited for AC/nZVI. Comparing the constants of the Freundlich models, AC/nZVI showed 33-times higher adsorption capacity and a greater affinity for Cr(VI) than did AC. Reusability of AC/nZVI for Cr(VI) treatment was assessed by regenerating the adsorbent and indicated that the material maintained a 68% removal efficiency after five cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2018, "Volume": 353, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 781, "End Page": 795, "Article Number": null, "DOI": "10.1016/j.cej.2018.07.170", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.07.170", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441527900077", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Basile, A; Bhatt, AI; O'Mullane, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Basile, A.; Bhatt, A. I.; O'Mullane, A. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing lithium metal using ionic liquids for long-lived batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Suppressing dendrite formation at lithium metal anodes during cycling is critical for the implementation of future lithium metal-based battery technology. Here we report that it can be achieved via the facile process of immersing the electrodes in ionic liquid electrolytes for a period of time before battery assembly. This creates a durable and lithium ion-permeable solid-electrolyte interphase that allows safe charge-discharge cycling of commercially applicable Li vertical bar electrolyte vertical bar LiFePO4 batteries for 1,000 cycles with Coulombic efficiencies 499.5%. The tailored solid-electrolyte interphase is prepared using a variety of electrolytes based on the N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide room temperature ionic liquid containing lithium salts. The formation is both time-and lithium salt-dependant, showing dynamic morphology changes, which when optimized prevent dendrite formation and consumption of electrolyte during cycling. This work illustrates that a simple, effective and industrially applicable lithium metal pretreatment process results in a commercially viable cycle life for a lithium metal battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11794, "DOI": "10.1038/ncomms11794", "DOI Link": "http://dx.doi.org/10.1038/ncomms11794", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378386900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Ashouri, A; Magomedov, A; Ross, M; Jost, M; Talaikis, M; Chistiakova, G; Bertram, T; Márquez, JA; Köhnen, E; Kasparavicius, E; Levcenco, S; Gil-Escrig, L; Hages, CJ; Schlatmann, R; Rech, B; Malinauskas, T; Unold, T; Kaufmann, CA; Korte, L; Niaura, G; Getautis, V; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Ashouri, Amran; Magomedov, Artiom; Ross, Marcel; Jost, Marko; Talaikis, Martynas; Chistiakova, Ganna; Bertram, Tobias; Marquez, Jose A.; Kohnen, Eike; Kasparavicius, Ernestas; Levcenco, Sergiu; Gil-Escrig, Lidon; Hages, Charles J.; Schlatmann, Rutger; Rech, Bernd; Malinauskas, Tadas; Unold, Thomas; Kaufmann, Christian A.; Korte, Lars; Niaura, Gediminas; Getautis, Vytautas; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid rise of perovskite solar cells (PSCs) is increasingly limited by the available charge-selective contacts. This work introduces two new hole-selective contacts for p-i-n PSCs that outperform all typical p-contacts in versatility, scalability and PSC power-conversion efficiency (PCE). The molecules are based on carbazole bodies with phosphonic acid anchoring groups and can form self-assembled monolayers (SAMs) on various oxides. Besides minimal material consumption and parasitic absorption, the self-assembly process enables conformal coverage of arbitrarily formed oxide surfaces with simple process control. The SAMs are designed to create an energetically aligned interface to the perovskite absorber without non-radiative losses. For three different perovskite compositions, one of which is prepared by co-evaporation, we show dopant-, additive- and interlayer-free PSCs with stabilized PCEs of up to 21.1%. Further, the conformal coverage allows to realize a monolithic CIGSe/perovskite tandem solar cell with as-deposited, rough CIGSe surface and certified efficiency of 23.26% on an active area of 1 cm(2). The simplicity and diverse substrate compatibility of the SAMs might help to further progress perovskite photovoltaics towards a low-cost, widely adopted solar technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 793, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2019, "Volume": 12, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3356, "End Page": 3369, "Article Number": null, "DOI": "10.1039/c9ee02268f", "DOI Link": "http://dx.doi.org/10.1039/c9ee02268f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494816300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krishnamoorthy, T; Ding, H; Yan, C; Leong, WL; Baikie, T; Zhang, ZY; Sherburne, M; Li, S; Asta, M; Mathews, N; Mhaisalkar, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krishnamoorthy, Thirumal; Ding, Hong; Yan, Chen; Leong, Wei Lin; Baikie, Tom; Zhang, Ziyi; Sherburne, Matthew; Li, Shuzhou; Asta, Mark; Mathews, Nripan; Mhaisalkar, Subodh G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-free germanium iodide perovskite materials for photovoltaic applications", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational screening based on density-functional-theory calculations reveals Ge as a candidate element for replacing Pb in halide perovskite compounds suitable for light harvesting. Experimentally, three AGeI(3) (A = Cs, CH3NH3 or HC(NH2)(2)) halide perovskite materials have been synthesized. These compounds are stable up to 150 degrees C, and have bandgaps correlated with the A-site cation size. CsGeI3-based solar cells display higher photocurrents, of about 6 mA cm(-2), but are limited by poor film forming abilities and oxidising tendencies. The present results demonstrate the utility of combining computational screening and experimental efforts to develop lead-free halide perovskite compounds for photovoltaic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 897, "Times Cited, All Databases": 942, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23829, "End Page": 23832, "Article Number": null, "DOI": "10.1039/c5ta05741h", "DOI Link": "http://dx.doi.org/10.1039/c5ta05741h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365205000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, G; Xie, DG; Zhong, H; Zhang, ZY; Fu, XK; Zhou, QL; Li, Q; Ni, H; Wang, JO; Guo, EJ; He, M; Wang, C; Yang, GZ; Jin, KJ; Ge, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ge; Xie, Donggang; Zhong, Hai; Zhang, Ziye; Fu, Xingke; Zhou, Qingli; Li, Qiang; Ni, Hao; Wang, Jiaou; Guo, Er-jia; He, Meng; Wang, Can; Yang, Guozhen; Jin, Kuijuan; Ge, Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photo-induced non-volatile VO2 phase transition for neuromorphic ultraviolet sensors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the quest for emerging in-sensor computing, materials that respond to optical stimuli in conjunction with non-volatile phase transition are highly desired for realizing bioinspired neuromorphic vision components. Here, we report a non-volatile multi-level control of VO2 films by oxygen stoichiometry engineering under ultraviolet irradiation. Based on the reversible regulation of VO2 films using ultraviolet irradiation and electrolyte gating, we demonstrate a proof-of-principle neuromorphic ultraviolet sensor with integrated sensing, memory, and processing functions at room temperature, and also prove its silicon compatible potential through the wafer-scale integration of a neuromorphic sensor array. The device displays linear weight update with optical writing because its metallic phase proportion increases almost linearly with the light dosage. Moreover, the artificial neural network consisting of this neuromorphic sensor can extract ultraviolet information from the surrounding environment, and significantly improve the recognition accuracy from 24% to 93%. This work provides a path to design neuromorphic sensors and will facilitate the potential applications in artificial vision systems. Bioinspired neuromorphic vision components are highly desired for the emerging in-sensor computing technology. Here, Ge et al. develop an array of optoelectronic synapses capable of memorizing and processing ultraviolet images facilitated by photo-induced non-volatile phase transition in VO2 films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1729, "DOI": "10.1038/s41467-022-29456-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29456-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777408600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, WY; Duan, ZG; Zhao, J; Fu, RZ; Zhu, CH; Fan, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Wanyi; Duan, Zhiguang; Zhao, Jing; Fu, Rongzhan; Zhu, Chenhui; Fan, Daidi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Glucose and MMP-9 dual-responsive hydrogel with temperature sensitive self-adaptive shape and controlled drug release accelerates diabetic wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chronic diabetic wounds are an important healthcare challenge. High concentration glucose, high level of matrix metalloproteinase-9 (MMP-9), and long-term inflammation constitute the special wound environment of diabetic wounds. Tissue necrosis aggravates the formation of irregular wounds. All the above factors hinder the healing of chronic diabetic wounds. To solve these issues, a glucose and MMP-9 dual-response temperature-sensitive shape self-adaptive hydrogel (CBP/GMs@Cel&INS) was designed and constructed with polyvinyl alcohol (PVA) and chitosan grafted with phenylboric acid (CS-BA) by encapsulating insulin (INS) and gelatin microspheres containing celecoxib (GMs@Cel). Temperature-sensitive self-adaptive CBP/GMs@Cel&INS provides a new way to balance the fluid-like mobility (self-adapt to deep wounds quickly, approximately 37 degrees C) and solid-like elasticity (protect wounds against external forces, approximately 25 degrees C) of self-adaptive hydrogels, while simultaneously releasing insulin and celecoxib on-demand in the environment of high-level glucose and MMP-9. Moreover, CBP/ GMs@Cel&INS exhibits remodeling and self-healing properties, enhanced adhesion strength (39.65 +/- 6.58 kPa), down-regulates MMP-9, and promotes cell proliferation, migration, and glucose consumption. In diabetic full-thickness skin defect models, CBP/GMs@Cel&INS significantly alleviates inflammation and regulates the local high-level glucose and MMP-9 in the wounds, and promotes wound healing effectively through the synergistic effect of temperature-sensitive shape-adaptive character and the dual-responsive system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 17, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 17, "Article Number": null, "DOI": "10.1016/j.bioactmat.2024.01.004", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2024.01.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788639300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, YZ; Yang, B; Xie, X; Brechtl, J; Dahmen, KA; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yunzhu; Yang, Bin; Xie, Xie; Brechtl, Jamieson; Dahmen, Karin A.; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion of AlxCoCrFeNi high-entropy alloys: Al-content and potential scan-rate dependent pitting behavior", "Source Title": "CORROSION SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present work investigates the influence of Al-content and potential-scan-rate on stable/metastable pitting of AlxCoCrFeNi high-entropy alloys in a 3.5 wt.% NaCI solution. The increased Al content causes the volume fraction of the Cr-depleted phase to increase, resulting in thicker/dispersive passive films that degrade the localized corrosion resistance. The varied stable/metastable pitting behavior under different potential scan rates indicates that pit generation is influenced by the properties of passive films and the interactions between chloride ions and the active sites. Furthermore, a mean-field theory is employed to predict the scan-rate dependent, power-law distribution of current fluctuations. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 651, "Times Cited, All Databases": 691, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 33, "End Page": 45, "Article Number": null, "DOI": "10.1016/j.corsci.2017.02.019", "DOI Link": "http://dx.doi.org/10.1016/j.corsci.2017.02.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401390100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Clough, AJ; Skelton, JM; Downes, CA; de la Rosa, AA; Yoo, JW; Walsh, A; Melot, BC; Marinescu, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Clough, Andrew J.; Skelton, Jonathan M.; Downes, Courtney A.; de la Rosa, Ashley A.; Yoo, Joseph W.; Walsh, Aron; Melot, Brent C.; Marinescu, Smaranda C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) metal-organic frameworks (MOFs) have received a great deal of attention due to their relatively high charge carrier mobility and low resistivity. Here we report on the temperature-dependent charge transport properties of a 2D cobalt 2,3,6,7,10,11-triphenylenehexathiolate framework. Variable temperature resistivity studies reveal a transition from a semiconducting to a metallic phase with decreasing temperature, which is unprecedented in MOFs. We find this transition to be highly dependent on the film thickness and the amount of solvent trapped in the pores, with density functional theory calculations of the electronic-structure supporting the complex metallic conductivity of the material. These results identify the first experimentally observed MOF that exhibits band-like metallic conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2017, "Volume": 139, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10863, "End Page": 10867, "Article Number": null, "DOI": "10.1021/jacs.7b05742", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b05742", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407540200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, Z; Hu, L; Ripatti, DS; Hu, X; Feng, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Zhuo; Hu, Lin; Ripatti, Donald S.; Hu, Xun; Feng, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of carbon dioxide (CO2) over copper-based catalysts provides an attractive approach for sustainable fuel production. While efforts are focused on developing catalytic materials, it is also critical to understand and control the microenvironment around catalytic sites, which can mediate the transport of reaction species and influence reaction pathways. Here, we show that a hydrophobic microenvironment can significantly enhance CO2 gas-diffusion electrolysis. For proof-of-concept, we use commercial copper nulloparticles and disperse hydrophobic polytetrafluoroethylene (PTFE) nulloparticles inside the catalyst layer. Consequently, the PTFE-added electrode achieves a greatly improved activity and Faradaic efficiency for CO2 reduction, with a partial current density >250 mA cm(-2) and a single-pass conversion of 14% at moderate potentials, which are around twice that of a regular electrode without added PTFE. The improvement is attributed to a balanced gas/liquid microenvironment that reduces the diffusion layer thickness, accelerates CO2 mass transport, and increases CO2 local concentration for the electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136, "DOI": "10.1038/s41467-020-20397-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20397-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626604800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, Y; Rong, XH; Gao, A; Liu, Y; Li, JW; Mao, ML; Qi, XG; Chai, GL; Zhang, QH; Suo, LM; Gu, L; Li, H; Huang, XJ; Chen, LQ; Liu, BY; Hu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yun; Rong, Xiaohui; Gao, Ang; Liu, Yuan; Li, Jianwei; Mao, Minglei; Qi, Xingguo; Chai, Guoliang; Zhang, Qinghua; Suo, Liumin; Gu, Lin; Li, Hong; Huang, Xuejie; Chen, Liquan; Liu, Binyuan; Hu, Yong-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of a topological polymeric solid electrolyte for high-performance all-solid-state alkali metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poly(ethylene oxide)-based solid-state electrolytes are widely considered promising candidates for the next generation of lithium and sodium metal batteries. However, several challenges, including low oxidation resistance and low cation transference number, hinder poly(ethylene oxide)-based electrolytes for broad applications. To circumvent these issues, here, we propose the design, synthesis and application of a fluoropolymer, i.e., poly(2,2,2-trifluoroethyl methacrylate). This polymer, when introduced into a poly(ethylene oxide)-based solid electrolyte, improves the electrochemical window stability and transference number. Via multiple physicochemical and theoretical characterizations, we identify the presence of tailored supramolecular bonds and peculiar morphological structures as the main factors responsible for the improved electrochemical performances. The polymeric solid electrolyte is also investigated in full lithium and sodium metal lab-scale cells. Interestingly, when tested in a single-layer pouch cell configuration in combination with a Li metal negative electrode and a LiMn0.6Fe0.4PO4-based positive electrode, the polymeric solid-state electrolyte enables 200 cycles at 42 mA center dot g(-1) and 70 degrees C with a stable discharge capacity of approximately 2.5 mAh when an external pressure of 0.28 MPa is applied. Solid-state polymer electrolytes are crucial for developing future rechargeable batteries, but they are still limited in performance. Here, the authors designed a topological polymeric solid electrolyte, enabling an all-solid-state high-voltage lithium metal pouch cell to cycle 200 times efficiently.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4181, "DOI": "10.1038/s41467-022-31792-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31792-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827790500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QL; Xu, CQ; Liu, W; Hung, SF; Yang, HB; Gao, JJ; Cai, WZ; Chen, HM; Li, J; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qilun; Xu, Cong-Qiao; Liu, Wei; Hung, Sung-Fu; Yang, Hong Bin; Gao, Jiajian; Cai, Weizheng; Chen, Hao Ming; Li, Jun; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination engineering of iridium nullocluster bifunctional electrocatalyst for highly efficient and pH-universal overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water electrolysis offers a promising energy conversion and storage technology for mitigating the global energy and environmental crisis, but there still lack highly efficient and pH-universal electrocatalysts to boost the sluggish kinetics for both cathodic hydrogen evolution reaction (HER) and anodic oxygen evolution reaction (OER). Herein, we report uniformly dispersed iridium nulloclusters embedded on nitrogen and sulfur co-doped graphene as an efficient and robust electrocatalyst for both HER and OER at all pH conditions, reaching a current density of 10mA cm(-2) with only 300, 190 and 220mV overpotential for overall water splitting in neutral, acidic and alkaline electrolyte, respectively. Based on probing experiments, operando X-ray absorption spectroscopy and theoretical calculations, we attribute the high catalytic activities to the optimum bindings to hydrogen (for HER) and oxygenated intermediate species (for OER) derived from the tunable and favorable electronic state of the iridium sites coordinated with both nitrogen and sulfur.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4246, "DOI": "10.1038/s41467-020-18064-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18064-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567537300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, YC; Liu, W; Chen, W; Chen, W; Zhou, GM; Hsu, PC; Zhang, RF; Liang, Z; Fan, SS; Zhang, YG; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Yongcai; Liu, Wei; Chen, Wei; Chen, Wei; Zhou, Guangmin; Hsu, Po-Chun; Zhang, Rufan; Liang, Zheng; Fan, Shoushan; Zhang, Yuegang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient solar-driven water splitting by nullocone BiVO4-perovskite tandem cells", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bismuth vanadate (BiVO4) has been widely regarded as a promising photoanode material for photoelectrochemical (PEC) water splitting because of its low cost, its high stability against photocorrosion, and its relatively narrow band gap of 2.4 eV. However, the achieved performance of the BiVO4 photoanode remains unsatisfactory to date because its short carrier diffusion length restricts the total thickness of the BiVO4 film required for sufficient light absorption. We addressed the issue by deposition of nulloporous Mo-doped BiVO4 (Mo:BiVO4) on an engineered cone-shaped nullostructure, in which the Mo: BiVO4 layer with a larger effective thickness maintains highly efficient charge separation and high light absorption capability, which can be further enhanced by multiple light scattering in the nullocone structure. As a result, the nullocone/Mo:BiVO4/Fe(Ni)OOH photoanode exhibits a high water-splitting photocurrent of 5.82 +/- 0.36 mA cm(-2) at 1.23 V versus the reversible hydrogen electrode under 1-sun illumination. We also demonstrate that the PEC cell in tandem with a single perovskite solar cell exhibits unassisted water splitting with a solar-to-hydrogen conversion efficiency of up to 6.2%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501764", "DOI": "10.1126/sciadv.1501764", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501764", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380073800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SY; Ai, ZW; Niu, XW; Yang, WJ; Kang, R; Lin, ZY; Waseem, A; Jiao, L; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Siyuan; Ai, Zhiwen; Niu, Xinwei; Yang, Weijie; Kang, Rong; Lin, Zhongyuan; Waseem, Amir; Jiao, Long; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Linker Engineering of Sandwich-Structured Metal-Organic Framework Composites for Optimized Photocatalytic H2 Production", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the microenvironment around catalytic sites is recognized to be crucial in thermocatalysis, its roles in photocatalysis remain subtle. In this work, a series of sandwich-structured metal-organic framework (MOF) composites, UiO-66-NH2@Pt@UiO-66-X (X means functional groups), is rationally constructed for visible-light photocatalytic H-2 production. By varying the X groups of the UiO-66-X shell, the microenvironment of the Pt sites and photosensitive UiO-66-NH2 core can be simultaneously modulated. Significantly, the MOF composites with identical light absorption and Pt loading present distinctly different photocatalytic H-2 production rates, following the X group sequence of H > Br > NA (naphthalene) > OCH3 > Cl > NO2. UiO-66-NH2@Pt@UiO-66-H demonstrates H-2 production rate up to 2708.2 & mu;mol g(-1) h(-1), & AP;222 times that of UiO-66-NH2@Pt@UiO-66-NO2. Mechanism investigations suggest that the variation of the X group can balance the charge separation of the UiO-66-NH2 core and the proton reduction ability of Pt, leading to an optimal activity of UiO-66-NH2@Pt@UiO-66-H at the equilibrium point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 35, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202302512", "DOI Link": "http://dx.doi.org/10.1002/adma.202302512", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042352700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, PF; Ding, J; Yao, ZH; Pu, TC; Zhang, P; Huang, ZN; Wang, CH; Zhang, JL; Zecher-Freeman, N; Zong, H; Yuan, DS; Deng, SW; Shahbazian-Yassar, R; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Pengfei; Ding, Jing; Yao, Zihao; Pu, Tiancheng; Zhang, Peng; Huang, Zhennull; Wang, Canhui; Zhang, Junlei; Zecher-Freeman, Noah; Zong, Han; Yuan, Dashui; Deng, Shengwei; Shahbazian-Yassar, Reza; Wang, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxo dicopper anchored on carbon nitride for selective oxidation of methane", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selective conversion of methane into value-added chemicals is a promising approach for utilization of hydrocarbon sources. Here the authors develop dimeric copper centers supported on graphitic carbon nitride (denoted as Cu-2@C3N4) with >10% conversion and >98% selectivity toward methyl oxygenates in both thermo- and photo- catalytic reactions. Selective conversion of methane (CH4) into value-added chemicals represents a grand challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric copper centers supported on graphitic carbon nitride (denoted as Cu-2@C3N4) as advanced catalysts for CH4 partial oxidation. The copper-dimer catalysts demonstrate high selectivity for partial oxidation of methane under both thermo- and photocatalytic reaction conditions, with hydrogen peroxide (H2O2) and oxygen (O-2) being used as the oxidizer, respectively. In particular, the photocatalytic oxidation of CH4 with O-2 achieves >10% conversion, and >98% selectivity toward methyl oxygenates and a mass-specific activity of 1399.3 mmol g Cu(-1)h(-1). Mechanistic studies reveal that the high reactivity of Cu-2@C3N4 can be ascribed to symphonic mechanisms among the bridging oxygen, the two copper sites and the semiconducting C3N4 substrate, which do not only facilitate the heterolytic scission of C-H bond, but also promotes H2O2 and O-2 activation in thermo- and photocatalysis, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1375, "DOI": "10.1038/s41467-022-28987-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28987-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770096400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Wang, H; Wang, HT; Chan, JYE; Liu, HL; Zhang, BA; Zhang, YF; Agarwal, K; Yang, XL; Ranganath, AS; Low, HY; Ge, Q; Yang, JKW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wang; Wang, Hao; Wang, Hongtao; Chan, John You En; Liu, Hailong; Zhang, Biao; Zhang, Yuan-Fang; Agarwal, Komal; Yang, Xiaolong; Ranganath, Anupama Sargur; Low, Hong Yee; Ge, Qi; Yang, Joel K. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural multi-colour invisible inks with submicron 4D printing of shape memory polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Four-dimensional (4D) printing of shape memory polymer (SMP) imparts time responsive properties to 3D structures. Here, we explore 4D printing of a SMP in the submicron length scale, extending its applications to nullophononics. We report a new SMP photoresist based on Vero Clear achieving print features at a resolution of similar to 300nm half pitch using two-photon polymerization lithography (TPL). Prints consisting of grids with size-tunable multi-colours enabled the study of shape memory effects to achieve large visual shifts through nulloscale structure deformation. As the nullostructures are flattened, the colours and printed information become invisible. Remarkably, the shape memory effect recovers the original surface morphology of the nullostructures along with its structural colour within seconds of heating above its glass transition temperature. The high-resolution printing and excellent reversibility in both microtopography and optical properties promises a platform for temperature-sensitive labels, information hiding for anti-counterfeiting, and tunable photonic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112, "DOI": "10.1038/s41467-020-20300-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20300-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665639800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, DT; Peng, L; Reeder, WS; Moosavi, SM; Tiana, D; Britt, DK; Oveisi, E; Queen, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Daniel T.; Peng, Li; Reeder, Washington S.; Moosavi, Seyed Mohamad; Tiana, Davide; Britt, David K.; Oveisi, Emad; Queen, Wendy L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid, Selective Heavy Metal Removal from Water by a Metal-Organic Framework/Polydopamine Composite", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Drinking water contamination with heavy metals, particularly lead, is a persistent problem worldwide with grave public health consequences. Existing purification methods often cannot address this problem quickly and economically. Here we report a cheap, water stable metal-organic framework/polymer composite, Fe-BTC/PDA, that exhibits rapid, selective removal of large quantities of heavy metals, such as Pb2+ and Hg2+, from real world water samples. In this work, Fe-BTC is treated with dopamine, which undergoes a spontaneous polymerization to polydopamine (PDA) within its pores via the Fe3+ open metal sites. The PDA, pinned on the internal MOF surface, gains extrinsic porosity, resulting in a composite that binds up to 1634 mg of Hg2+ and 394 mg of Pb2+ per gram of composite and removes more than 99.8% of these ions from a 1 ppm solution, yielding drinkable levels in seconds. Further, the composite properties are well-maintained in river and seawater samples spiked with only trace amounts of lead, illustrating unprecedented selectivity. Remarkably, no significant uptake of competing metal ions is observed even when interferents, such as Na+, are present at concentrations up to 14 000 times that of Pb2+. The material is further shown to be resistant to fouling when tested in high concentrations of common organic interferents, like humic acid, and is fully regenerable over many cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 349, "End Page": 356, "Article Number": null, "DOI": "10.1021/acscentsci.7b00605", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00605", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428801200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Haase, F; Troschke, E; Savasci, G; Banerjee, T; Duppel, V; Dörfler, S; Grundei, MMJ; Burow, AM; Ochsenfeld, C; Kaskel, S; Lotsch, BV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Haase, Frederik; Troschke, Erik; Savasci, Goekcen; Banerjee, Tanmay; Duppel, Viola; Doerfler, Susanne; Grundei, Martin M. J.; Burow, Asbjoern M.; Ochsenfeld, Christian; Kaskel, Stefan; Lotsch, Bettina V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topochemical conversion of an imine-into a thiazole-linked covalent organic framework enabling real structure analysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilization of covalent organic frameworks (COFs) by post-synthetic locking strategies is a powerful tool to push the limits of COF utilization, which are imposed by the reversible COF linkage. Here we introduce a sulfur-assisted chemical conversion of a two-dimensional imine-linked COF into a thiazole-linked COF, with full retention of crystallinity and porosity. This post-synthetic modification entails significantly enhanced chemical and electron beam stability, enabling investigation of the real framework structure at a high level of detail. An in-depth study by electron diffraction and transmission electron microscopy reveals a myriad of previously unknown or unverified structural features such as grain boundaries and edge dislocations, which are likely generic to the in-plane structure of 2D COFs. The visualization of such real structural features is key to understand, design and control structure-property relationships in COFs, which can have major implications for adsorption, catalytic, and transport properties of such crystalline porous polymers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2600, "DOI": "10.1038/s41467-018-04979-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04979-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437102500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vinikoor, T; Dzidotor, GK; Le, TT; Liu, Y; Kan, HM; Barui, S; Chorsi, MT; Curry, EJ; Reinhardt, E; Wang, HZ; Singh, P; Merriman, MA; D'Orio, E; Park, J; Xiao, SY; Chapman, JH; Lin, F; Truong, CS; Prasadh, S; Chuba, L; Killoh, S; Lee, SW; Wu, Q; Chidambaram, RM; Lo, KWH; Laurencin, CT; Nguyen, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vinikoor, Tra; Dzidotor, Godwin K.; Le, Thinh T.; Liu, Yang; Kan, Ho-Man; Barui, Srimanta; Chorsi, Meysam T.; Curry, Eli J.; Reinhardt, Emily; Wang, Hanzhang; Singh, Parbeen; Merriman, Marc A.; D'Orio, Ethan; Park, Jinyoung; Xiao, Shuyang; Chapman, James H.; Lin, Feng; Truong, Cao-Sang; Prasadh, Somasundaram; Chuba, Lisa; Killoh, Shaelyn; Lee, Seok-Woo; Wu, Qian; Chidambaram, Ramaswamy M.; Lo, Kevin W. H.; Laurencin, Cato T.; Nguyen, Thanh D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Injectable and biodegradable piezoelectric hydrogel for osteoarthritis treatment", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Osteoarthritis affects millions of people worldwide but current treatments using analgesics or anti-inflammatory drugs only alleviate symptoms of this disease. Here, we present an injectable, biodegradable piezoelectric hydrogel, made of short electrospun poly-L-lactic acid nullofibers embedded inside a collagen matrix, which can be injected into the joints and self-produce localized electrical cues under ultrasound activation to drive cartilage healing. In vitro, data shows that the piezoelectric hydrogel with ultrasound can enhance cell migration and induce stem cells to secrete TGF-beta 1, which promotes chondrogenesis. In vivo, the rabbits with osteochondral critical-size defects receiving the ultrasound-activated piezoelectric hydrogel show increased subchondral bone formation, improved hyaline-cartilage structure, and good mechanical properties, close to healthy native cartilage. This piezoelectric hydrogel is not only useful for cartilage healing but also potentially applicable to other tissue regeneration, offering a significant impact on the field of regenerative tissue engineering. The use of biomaterial scaffolds-based cartilage grafts could potentially innovate the Osteoarthritis (OA) treatment, but has been limited by toxicity concerns and invasive surgical procedures. Here, the authors report an injectable and biodegradable piezoelectric hydrogel with ultrasound activation to offer a minimally invasive approach for OA treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6257, "DOI": "10.1038/s41467-023-41594-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41594-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001083908100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, XJ; Choi, Y; Zhang, K; Kwon, J; Kim, DY; Lee, JK; Oh, SH; Kim, JK; Park, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xinjian; Choi, Yong; Zhang, Kan; Kwon, Jeong; Kim, Dong Yeong; Lee, Ja Kyung; Oh, Sang Ho; Kim, Jong Kyu; Park, Jong Hyeok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient photoelectrochemical hydrogen production from bismuth vanadate-decorated tungsten trioxide helix nullostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tungsten trioxide/bismuth vanadate heterojunction is one of the best pairs for solar water splitting, but its photocurrent densities are insufficient. Here we investigate the advantages of using helical nullostructures in photoelectrochemical solar water splitting. A helical tungsten trioxide array is fabricated on a fluorine-doped tin oxide substrate, followed by subsequent coating with bismuth vanadate/catalyst. A maximum photocurrent density of similar to 5.35 +/- 0.15 mA cm(-2) is achieved at 1.23V versus the reversible hydrogen electrode, and related hydrogen and oxygen evolution is also observed from this heterojunction. Theoretical simulations and analyses are performed to verify the advantages of this helical structure. The combination of effective light scattering, improved charge separation and transportation, and an enlarged contact surface area with electrolytes due to the use of the bismuth vanadate-decorated tungsten trioxide helical nullostructures leads to the highest reported photocurrent density to date at 1.23V versus the reversible hydrogen electrode, to the best of our knowledge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4775, "DOI": "10.1038/ncomms5775", "DOI Link": "http://dx.doi.org/10.1038/ncomms5775", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342841300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YS; Xuan, C; Qian, XS; Alsaid, Y; Hua, MT; Jin, LH; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yusen; Xuan, Chen; Qian, Xiaoshi; Alsaid, Yousif; Hua, Mutian; Jin, Lihua; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft phototactic swimmer based on self-sustained hydrogel oscillator", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oscillations are widely found in living organisms to generate propulsion-based locomotion often driven by constant ambient conditions, such as phototactic movements. Such environment-powered and environment-directed locomotions may advance fully autonomous remotely steered robots. However, most man-made oscillations require nonconstant energy input and cannot perform environment-dictated movement. Here, we report a self-sustained soft oscillator that exhibits perpetual and untethered locomotion as a phototactic soft swimming robot, remotely fueled and steered by constant visible light. This particular out-of-equilibrium actuation arises from a self-shadowing-enabled negative feedback loop inherent in the dynamic light-material interactions, promoted by the fast and substantial volume change of the photoresponsive hydrogel. Our analytical model and governing equation unveil the oscillation mechanism and design principle with key parameters identified to tune the dynamics. On this autonomous oscillator platform, we establish a broadly applicable principle for converting a continuous input into a discontinuous output. The modular design can be customized to accommodate various forms of input energy and to generate diverse oscillatory behaviors. The hydrogel oscillator showcases agile life-like omnidirectional motion in the entire three-dimensional space with near-infinite degrees of freedom. The large force generated by the powerful and long-lasting oscillation can sufficiently overcome water damping and effectively self-propel away from a light source. Such a hydrogel oscillator-based all-soft swimming robot, named OsciBot, demonstrated high-speed and controllable phototactic locomotion. This autonomous robot is battery free, deployable, scalable, and integratable. Artificial phototaxis opens broad opportunities in maneuverable marine automated systems, miniaturized transportation, and solar sails.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2019, "Volume": 4, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax7112", "DOI": "10.1126/scirobotics.aax7112", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.aax7112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482205800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahrens, A; Bonde, A; Sun, HW; Wittig, NK; Hammershoj, HCD; Batista, GMF; Sommerfeldt, A; Frolich, S; Birkedal, H; Skrydstrup, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahrens, Alexander; Bonde, Andreas; Sun, Hongwei; Wittig, Nina Kolln; Hammershoj, Hans Christian D.; Batista, Gabriel Martins Ferreira; Sommerfeldt, Andreas; Frolich, Simon; Birkedal, Henrik; Skrydstrup, Troels", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic disconnection of C-O bonds in epoxy resins and composites", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fibre-reinforced epoxy composites are well established in regard to load-bearing applications in the aerospace, automotive and wind power industries, owing to their light weight and high durability. These composites are based on thermoset resins embedding glass or carbon fibres(1). In lieu of viable recycling strategies, end-of-use composite-based structures such as wind turbine blades are commonly landfilled(1-4). Because of the negative environmental impact of plastic waste(5,6), the need for circular economies of plastics has become more pressing(7,8). However, recycling thermoset plastics is no trivial matter(1-4). Here we report a transition-metal-catalysed protocol for recovery of the polymer building block bisphenol A and intact fibres from epoxy composites. A Ru-catalysed, dehydrogenation/bond, cleavage/reduction cascade disconnects the C(alkyl)-O bonds of the most common linkages of the polymer. We showcase the application of this methodology to relevant unmodified amine-cured epoxy resins as well as commercial composites, including the shell of a wind turbine blade. Our results demonstrate that chemical recycling approaches for thermoset epoxy resins and composites are achievable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2023, "Volume": 617, "Issue": 7962, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-023-05944-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05944-6", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002447800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, SS; Zhu, B; Jiang, X; Han, G; Li, SW; Lau, CH; Wu, YD; Zhang, YQ; Shao, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Shanshan; Zhu, Bin; Jiang, Xu; Han, Gang; Li, Songwei; Lau, Cher Hon; Wu, Yadong; Zhang, Yanqiu; Shao, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symbiosis-inspired de novo synthesis of ultrahigh MOF growth mixed matrix membranes for sustainable carbon capture", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixed matrix membranes (MMMs) are one of the most promising solutions for energy-efficient gas separation. However, conventional MMM synthesis methods inevitably lead to poor filler-polymer interfacial compatibility, filler agglomeration, and limited loading. Herein, inspired by symbiotic relationships in nature, we designed a universal bottom-up method for in situ nullosized metal organic framework (MOF) assembly within polymer matrices. Consequently, our method eliminating the traditional postsynthetic step significantly enhanced MOF dispersion, interfacial compatibility, and loading to an unprecedented 67.2 wt % in synthesized MMMs. Utilizing experimental techniques and complementary density functional theory (DFT) simulation, we validated that these enhancements synergistically ameliorated CO2 solubility, which was significantly different from other works where MOF typically promoted gas diffusion. Our approach simultaneously improves CO2 permeability and selectivity, and superior carbon capture performance is maintained even during long-term tests; the mechanical strength is retained even with ultrahigh MOF loadings. This symbiosis-inspired de novo strategy can potentially pave the way for next-generation MMMs that can fully exploit the unique characteristics of both MOFs and matrices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2022, "Volume": 119, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2114964119", "DOI": "10.1073/pnas.2114964119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2114964119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784689000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, B; Kawakita, Y; Ohira-Kawamura, S; Sugahara, T; Wang, H; Wang, JF; Chen, YN; Kawaguchi, SI; Kawaguchi, S; Ohara, K; Li, K; Yu, DH; Mole, R; Hattori, T; Kikuchi, T; Yano, S; Zhang, Z; Zhang, Z; Ren, WJ; Lin, SC; Sakata, O; Nakajima, K; Zhang, ZD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Bing; Kawakita, Yukinobu; Ohira-Kawamura, Seiko; Sugahara, Takeshi; Wang, Hui; Wang, Jingfan; Chen, Yanna; Kawaguchi, Saori I.; Kawaguchi, Shogo; Ohara, Koji; Li, Kuo; Yu, Dehong; Mole, Richard; Hattori, Takanori; Kikuchi, Tatsuya; Yano, Shin-ichiro; Zhang, Zhao; Zhang, Zhe; Ren, Weijun; Lin, Shangchao; Sakata, Osami; Nakajima, Kenji; Zhang, Zhidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colossal barocaloric effects in plastic crystals", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Refrigeration is of vital importance for modern society-for example, for food storage and air conditioning-and 25 to 30 per cent of the world's electricity is consumed for refrigeration(1). Current refrigeration technology mostly involves the conventional vapour compression cycle, but the materials used in this technology are of growing environmental concern because of their large global warming potential(2). As a promising alternative, refrigeration technologies based on solid-state caloric effects have been attracting attention in recent decades(3-5). However, their application is restricted by the limited performance of current caloric materials, owing to small isothermal entropy changes and large driving magnetic fields. Here we report colossal barocaloric effects (CBCEs) (barocaloric effects are cooling effects of pressure-induced phase transitions) in a class of disordered solids called plastic crystals. The obtained entropy changes in a representative plastic crystal, neopentylglycol, are about 389 joules per kilogram per kelvin near room temperature. Pressure-dependent neutron scattering measurements reveal that CBCEs in plastic crystals can be attributed to the combination of extensive molecular orientational disorder, giant compressibility and highly anharmonic lattice dynamics of these materials. Our study establishes the microscopic mechanism of CBCEs in plastic crystals and paves the way to next-generation solid-state refrigeration technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2019, "Volume": 567, "Issue": 7749, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 506, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1042-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1042-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462655800046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, XY; Xu, BG; Wu, MJ; Jing, TT; Yang, YJ; Gao, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Xiaoyang; Xu, Bingang; Wu, Mengjie; Jing, Titao; Yang, Yujue; Gao, Yuanyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breathable, washable and wearable woven-structured triboelectric nullogenerators utilizing electrospun nullofibers for biomechanical energy harvesting and self-powered sensing", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapid advancement in wearable electronics, energy harvesting devices based on triboelectric nullo generators (TENGs) have been intensively investigated for providing sustainable power supply for them. However, the fabrication of wearable TENGs still remains great challenges, such as flexibility, breathability and washability. Here, a route to develop a new kind of woven-structured triboelectric nullogenerator (WS-TENG) with a facile, low-cost, and scalable electrospinning technique is reported. The WS-TENG is fabricated with commercial stainless-steel yarns wrapped by electrospun polyamide 66 nullofiber and poly(vinylidenefluorideco-trifluoroethylene) nullofiber, respectively. Triggered by diversified friction materials under a working principle of freestanding mode, the open-circuit voltage, short-circuit current and maximum instantaneous power density from the WS-TENG can reach up to 166 V, 8.5 mu A and 93 mW/m(2), respectively. By virtue of high flexibility, desirable breathability, washability and excellent durability, the fabricated WS-TENG is demonstrated to be a reliable power textile to light up 58 light-emitting diodes (LED) connected serially, charge commercial capacitors and drive portable electronics. A smart glove with stitched WS-TENGs is made to detect finger motion in different circumstances. The work presents a new approach for self-powered textiles with potential applications in biomechanical energy harvesting, wearable electronics and human motion monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 80, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105549, "DOI": "10.1016/j.nulloen.2020.105549", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105549", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618009300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Backes, C; Smith, RJ; McEvoy, N; Berner, NC; McCloskey, D; Nerl, HC; O'Neill, A; King, PJ; Higgins, T; Hanlon, D; Scheuschner, N; Maultzsch, J; Houben, L; Duesberg, GS; Donegan, JF; Nicolosi, V; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Backes, Claudia; Smith, Ronull J.; McEvoy, Niall; Berner, Nina C.; McCloskey, David; Nerl, Hannah C.; O'Neill, Arlene; King, Paul J.; Higgins, Tom; Hanlon, Damien; Scheuschner, Nils; Maultzsch, Janina; Houben, Lothar; Duesberg, Georg S.; Donegan, John F.; Nicolosi, Valeria; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edge and confinement effects allow in situ measurement of size and thickness of liquid-exfoliated nullosheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional nullomaterials such as MoS2 are of great interest both because of their novel physical properties and their applications potential. Liquid exfoliation, an important production method, is limited by our inability to quickly and easily measure nullosheet size, thickness or concentration. Here we demonstrate a method to simultaneously determine mean values of these properties from an optical extinction spectrum measured on a liquid dispersion of MoS2 nullosheets. The concentration measurement is based on the size-independence of the low-wavelength extinction coefficient, while the size and thickness measurements rely on the effect of edges and quantum confinement on the optical spectra. The resultant controllability of concentration, size and thickness facilitates the preparation of dispersions with pre-determined properties such as high monolayer-content, leading to first measurement of A-exciton MoS2 luminescence in liquid suspensions. These techniques are general and can be applied to a range of two-dimensional materials including WS2, MoSe2 and WSe2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4576, "DOI": "10.1038/ncomms5576", "DOI Link": "http://dx.doi.org/10.1038/ncomms5576", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341052900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mori, K; Hashimoto, N; Kamiuchi, N; Yoshida, H; Kobayashi, H; Yamashita, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mori, Kohsuke; Hashimoto, Naoki; Kamiuchi, Naoto; Yoshida, Hideto; Kobayashi, Hisayoshi; Yamashita, Hiromi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen spillover-driven synthesis of high-entropy alloy nulloparticles as a robust catalyst for CO2 hydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) have been intensively pursued as potentially advanced materials because of their exceptional properties. However, the facile fabrication of nullometer-sized HEAs over conventional catalyst supports remains challenging, and the design of rational synthetic protocols would permit the development of innovative catalysts with a wide range of potential compositions. Herein, we demonstrate that titanium dioxide (TiO2) is a promising platform for the low-temperature synthesis of supported CoNiCuRuPd HEA nulloparticles (NPs) at 400 degrees C. This process is driven by the pronounced hydrogen spillover effect on TiO2 in conjunction with coupled proton/electron transfer. The CoNiCuRuPd HEA NPs on TiO2 produced in this work were found to be both active and extremely durable during the CO2 hydrogenation reaction. Characterization by means of various in situ techniques and theoretical calculations elucidated that cocktail effect and sluggish diffusion originating from the synergistic effect obtained by this combination of elements. Facile fabrication of high-entropy alloys (HEAs) nulloparticles (NPs) on conventional catalyst supports remains challenging. Here the authors show TiO2 is a promising platform for the low-temperature synthesis of supported CoNiCuRuPd HEA NPs with excellent activity and durability in CO2 hydrogenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3884, "DOI": "10.1038/s41467-021-24228-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24228-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000668764900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Y; Liao, JF; Chen, HY; Zhang, HH; Li, JY; Wang, XD; Kuang, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yong; Liao, Jin-Feng; Chen, Hong-Yan; Zhang, Hong-Hong; Li, Jun-Yan; Wang, Xu-Dong; Kuang, Dai-Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Solid-State Z-Scheme α-Fe2O3/Amine-RGO/CsPbBr3 Hybrids for Visible-Light-Driven Photocatalytic CO2 Reduction", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite (PVK) has been deemed as a promising photocatalyst alternative because of its remarkable photoelectrical properties; however, the severe charge recombination has limited its catalytic activity. Herein, we report a PVK-based Z-scheme heterojunction, alpha-Fe2O3/Amine-RGO/CsPbBr3, for high-efficiency CO2 reduction in the presence of H2O. By delicately controlling the interfacial interaction, effective Z-scheme electron transfer from alpha-Fe2O3 to CsPbBr3 is built, leading to boosted charge separation and prolonged carrier lifetime, as confirmed by electron spin resonullce (ESR), transient absorption (TA) spectra, etc. The impactful spatial separation of photo-generated carriers in Z-scheme system finally enables an 8.3-fold enhancement in photocatalytic performance as compared to CsPbBr3. A stable product yield of 469.16 mu mol g(-1) and an electron consumption yield of 3,132.46 mu mol g(-1) are achieved. This work is expected to provide deep insights into boosting the photocatalytic performance of PVK by modulating the charge carrier dynamics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 766, "End Page": 780, "Article Number": null, "DOI": "10.1016/j.chempr.2020.01.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.01.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519997200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Varvenne, C; Luque, A; Curtin, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Varvenne, Celine; Luque, Aitor; Curtin, William A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of strengthening in fcc high entropy alloys", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High Entropy Alloys (HEAs) are a new class of random alloys having impressive strength and toughness. Here, a mechanistic, parameter-free, and predictive theory for the temperature-, composition-, and strain-rate-dependence of the plastic yield strength of fcc HEAs is presented, validated, and applied to understand recent experiments. To first order, each elemental component in the HEA is considered as a solute embedded in the effective matrix of the surrounding alloy. Strengthening is then mainly achieved due to dislocation interactions with the random local concentration fluctuations around the average composition. The theory is validated against molecular simulations on model Fe-Ni-Cr alloys. Hall-Petch-corrected yield strengths in Ni-Co-Fe-Cr-Mn fcc HEM are then predicted using only available experimental information, and good quantitative agreement is achieved. The theory demonstrates the origins of the high strength and detailed trends with composition, materials parameters, temperature, thus identifying the key measurable/calculable material properties needed for design and optimization of fcc HEAs, and is a general model for fcc random alloys. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2016, "Volume": 118, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 164, "End Page": 176, "Article Number": null, "DOI": "10.1016/j.actamat.2016.07.040", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.07.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383935800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LF; Ding, QQ; Zhong, Y; Zou, J; Wu, J; Chiu, YL; Li, JX; Zhang, Z; Yu, Q; Shen, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Leifeng; Ding, Qingqing; Zhong, Yuan; Zou, Ji; Wu, Jing; Chiu, Yu-Lung; Li, Jixue; Zhang, Ze; Yu, Qian; Shen, Zhijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dislocation network in additive manufactured steel breaks strength-ductility trade-off", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most mechanisms used for strengthening crystalline materials, e.g. introducing crystalline interfaces, lead to the reduction of ductility. An additive manufacturing process - selective laser melting breaks this trade-off by introducing dislocation network, which produces a stainless steel with both significantly enhanced strength and ductility. Systematic electron microscopy characterization reveals that the pre-existing dislocation network, which maintains its configuration during the entire plastic deformation, is an ideal modulator that is able to slow down but not entirely block the dislocation motion. It also promotes the formation of a high density of nullo-twins during plastic deformation. This finding paves the way for developing high performance metals by tailoring the microstructure through additive manufacturing processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 777, "Times Cited, All Databases": 822, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 21, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 354, "End Page": 361, "Article Number": null, "DOI": "10.1016/j.mattod.2017.11.004", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2017.11.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433264200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, X; Ke, MK; Huang, GX; Chen, C; Chen, WX; Liang, K; Qu, YT; Yang, J; Wang, Y; Li, FT; Yu, HQ; Wu, YE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xiao; Ke, Ming-Kun; Huang, Gui-Xiang; Chen, Cai; Chen, Wenxing; Liang, Kuang; Qu, Yunteng; Yang, Jia; Wang, Ying; Li, Fengting; Yu, Han-Qing; Wu, Yuen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing heterogeneous catalysts with atomically dispersed active sites is vital to boost peroxymonosulfate (PMS) activation for Fenton-like activity, but how to controllably adjust the electronic configuration of metal centers to further improve the activation kinetics still remains a great challenge. Herein, we report a systematic investigation into heteroatom-doped engineering for tuning the electronic structure of Cu-N-4 sites by integrating electron-deficient boron (B) or electron-rich phosphorus (P) heteroatoms into carbon substrate for PMS activation. The electron-depleted Cu-N-4/C-B is found to exhibit the most active oxidation capacity among the prepared Cu-N-4 single-atom catalysts, which is at the top rankings of the Cu-based catalysts and is superior to most of the state-of-the-art heterogeneous Fenton-like catalysts. Conversely, the electron-enriched Cu-N-4/C-P induces a decrease in PMS activation. Both experimental results and theoretical simulations unravel that the long-range interaction with B atoms decreases the electronic density of Cu active sites and down-shifts the d-band center, and thereby optimizes the adsorption energy for PMS activation. This study provides an approach to finely control the electronic structure of Cu-N-4 sites at the atomic level and is expected to guide the design of smart Fenton-like catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2022, "Volume": 119, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2119492119", "DOI": "10.1073/pnas.2119492119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2119492119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766924200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hotchkiss, KM; Reddy, GB; Hyzy, SL; Schwartz, Z; Boyan, BD; Olivares-Navarrete, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hotchkiss, Kelly M.; Reddy, Gireesh B.; Hyzy, Sharon L.; Schwartz, Zvi; Boyan, Barbara D.; Olivares-Navarrete, Rene", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Titanium surface characteristics, including topography and wettability, alter macrophage activation", "Source Title": "ACTA BIOMATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomaterial surface properties including chemistry, topography, and wettability regulate cell response. Previous studies have shown that increasing surface roughness of metallic orthopaedic and dental implants improved bone formation around the implant. Little is known about how implant surface properties can affect immune cells that generate a wound healing microenvironment. The aim of our study was to examine the effect of surface modifications on macrophage activation and cytokine production. Macrophages were cultured on seven surfaces: tissue culture polystyrene (TCPS) control; hydrophobic and hydrophilic smooth Ti (PT and oxygen-plasma-treated (plasma) PT); hydrophobic and hydrophilic microrough Ti (SLA and plasma SLA), and hydrophobic and hydrophilic nullo-and micro-rough Ti (aged modSLA and modSLA). Smooth Ti induced inflammatory macrophage (M1-like) activation, as indicated by increased levels of interleukins IL-1 beta, IL-6, and TNF alpha. In contrast, hydrophilic rough titanium induced macrophage activation similar to the anti-inflammatory M2-like state, increasing levels of interleukins IL-4 and IL-10. These results demonstrate that macrophages cultured on high surface wettability materials produce an anti-inflammatory microenvironment, and this property may be used to improve the healing response to biomaterials. Statement of significance Metals like titanium (Ti) are common in orthopaedics and dentistry due to their ability to integrate with surrounding tissue and good biocompatibility. Roughness- and wettability-increasing surface modifications promote osteogenic differentiation of stem cells on Ti. While these modifications increase production of osteoblastic factors and bone formation, little is known about their effect on immune cells. The initial host response to a biomaterial is controlled primarily by macrophages and the factors they secrete in response to the injury caused by surgery and the material cues. Here we demonstrate the effect of surface roughness and wettability on the activation and production of inflammatory factors by macrophages. Control of inflammation will inform the design of surface modification procedures to direct the immune response and enhance the success of implanted materials. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 31, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 425, "End Page": 434, "Article Number": null, "DOI": "10.1016/j.actbio.2015.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.actbio.2015.12.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370086100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, J; Huang, BL; Zhang, CX; Wang, ZL; An, YM; Zhou, D; Lin, H; Leung, MKH; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Jue; Huang, Bolong; Zhang, Chengxu; Wang, Zilong; An, Yiming; Zhou, Dan; Lin, He; Leung, Michael K. H.; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering stepped edge surface structures of MoS2 sheet stacks to accelerate the hydrogen evolution reaction", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional molybdenum sulfide is an attractive noble-metal-free electrocatalyst for the hydrogen evolution reaction (HER). Significant efforts have been made to increase the number of exposed edge sites. However, little attention has been paid to devising edge surface structures of MoS2 sheet stacks to promote the HER kinetics. Herein we report the first demonstration of significantly enhanced HER kinetics by controllably fabricating a stepped MoS2 surface structure. Vertical arrays of MoS2 sheets terminated with such a stepped surface structure have proved to be an outstanding HER electrocatalyst with an overpotential of 104 mV at 10 mA cm(-2), an exchange current density of 0.2 mA cm(-2) and high stability. Experimental and theoretical results indicate that the enhanced electrocatalytic activity of the vertical MoS2 arrays is associated with the unique vertically terminated, highly exposed, stepped surface structure with a nearly thermoneutral H-adsorption energy. This work opens a new avenue to designing and developing layered materials for electrochemical energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 593, "End Page": 603, "Article Number": null, "DOI": "10.1039/c6ee03629e", "DOI Link": "http://dx.doi.org/10.1039/c6ee03629e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395679100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, MS; Hu, JP; Lu, QQ; Dong, HY; Karnaushenko, DD; Becker, C; Karnaushenko, D; Li, Y; Tang, HM; Qu, Z; Ge, J; Schmidt, OG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Minshen; Hu, Junping; Lu, Qiongqiong; Dong, Haiyun; Karnaushenko, Dmitriy D.; Becker, Christian; Karnaushenko, Daniil; Li, Yang; Tang, Hongmei; Qu, Zhe; Ge, Jin; Schmidt, Oliver G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Patternable and In Situ Formed Polymeric Zinc Blanket for a Reversible Zinc Anode in a Skin-Mountable Microbattery", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to their high safety and reversibility, aqueous microbatteries using zinc anodes and an acid electrolyte have emerged as promising candidates for wearable electronics. However, a critical limitation that prevents implementing zinc chemistry at the microscale lies in its spontaneous corrosion in an acidic electrolyte that causes a capacity loss of 40% after a ten-hour rest. Widespread anti-corrosion techniques, such as polymer coating, often retard the kinetics of zinc plating/stripping and lack spatial control at the microscale. Here, a polyimide coating that resolves this dilemma is reported. The coating prevents corrosion and hence reduces the capacity loss of a standby microbattery to 10%. The coordination of carbonyl oxygen in the polyimide with zinc ions builds up over cycling, creating a zinc blanket that minimizes the concentration gradient through the electrode/electrolyte interface and thus allows for fast kinetics and low plating/stripping overpotential. The polyimide's patternable feature energizes microbatteries in both aqueous and hydrogel electrolytes, delivering a supercapacitor-level rate performance and 400 stable cycles in the hydrogel electrolyte. Moreover, the microbattery is able to be attached to human skin and offers strong resistance to deformations, splashing, and external shock. The skin-mountable microbattery demonstrates an excellent combination of anti-corrosion, reversibility, and durability in wearables.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 33, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007497, "DOI": "10.1002/adma.202007497", "DOI Link": "http://dx.doi.org/10.1002/adma.202007497", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607519500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, C; Jiao, Y; Zhao, BT; Chen, DC; Zou, RQ; Walton, KS; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Chong; Jiao, Yang; Zhao, Bote; Chen, Dongchang; Zou, Ruqiang; Walton, Krista S.; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel-based pillared MOFs for high-performance supercapacitors: Design, synthesis and stability study", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have successfully synthesized novel, nickel-based, pillared DABCO-MOFs (DMOFs) of similar topologies - [Ni(L)(DABCO)(0.5)], where L is the functionalized BDC (1,4-benzenedicarboxylic acid) linker and DABCO is 1,4-diazabicyclo[2.2.2]-octane. The stability of DMOF-ADC ([Ni(9,10-anthracenedicarboxylic acid)(DABCO)(0.5)]) and DMOF-TM ([Ni(2,3,5,6-tetramethyl-1,4-benzenedicarboxylic acid)(DABC0)05]) in a humid environment was confirmed by surface area analysis on the water-exposed samples. When used as electrode materials, these DMOF capacitors exhibited excellent electrochemical performance. For example, a Ni-DMOF-ADC electrode showed specific capacitances of 552 and 438 F g(-1) at current densities of 1 and 20 A g(-1), respectively, while maintaining outstanding cycling stability (capacitance retention of > 98% after 16,000 cycles at current density of 10 A g(-1)) for MOF-derived materials based supercapacitors. The excellent electrochemical performance is attributed to the conversion of DMOFs to highly functionalized nickel hydroxide which inherited the high stability of DMOF-ADC and remained intact during charge-discharge process. Further, this work provides a general approach for the application of nickel-based pillared MOFs as relatively stable electrode in electrical energy storage. (C) 2016 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 66, "End Page": 73, "Article Number": null, "DOI": "10.1016/j.nulloen.2016.04.003", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2016.04.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384908700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Harrison, NJ; Todd, I; Mumtaz, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Harrison, Neil J.; Todd, Iain; Mumtaz, Kamran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduction of micro-cracking in nickel superalloys processed by Selective Laser Melting: A fundamental alloy design approach", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Selective Laser Melting (SLM) process generates large thermal gradients during rapid melting of metallic powdered feedstock. During solidification certain alloys suffer from thermally induced micro-cracking which cannot be eliminated by process optimisation. An alloy's crack susceptibility may reduce by increasing its Thermal Shock Resistance (TSR), potentially achieved through an increase in tensile strength. This hypothesis is investigated with Hastelloy X, a common nickel-base superalloy of known high crack susceptibility when processing SLM. It is demonstrated that through consideration of the imposed rapid solidification conditions, Hastelloy X can be made to form a supersaturated solid solution in the as deposited state. The fundamental solid solution strengthening (SSS) effect is exploited to generate an increase in lattice stress, by increasing the most potent SSS elements present within the alloy, whilst maintaining specification composition. The modified alloy displayed a 65% reduction in cracking and an increase in elevated temperature tensile strength, lending support to the initial hypothesis and identifying a possible approach for developing further SLM crack resistant versions of well-known alloy compositions. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/license.s/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 528, "Times Cited, All Databases": 572, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2015, "Volume": 94, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": 68, "Article Number": null, "DOI": "10.1016/j.actamat.2015.04.035", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.04.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357143500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marronnier, A; Roma, G; Boyer-Richard, S; Pedesseau, L; Jancu, JM; Bonnassieux, Y; Katan, C; Stoumpos, CC; Kanatzidis, MG; Even, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marronnier, Arthur; Roma, Guido; Boyer-Richard, Soline; Pedesseau, Laurent; Jancu, Jean-Marc; Bonnassieux, Yvan; Katan, Claudine; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.; Even, Jacky", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anharmonicity and Disorder in the Black Phases of Cesium Lead Iodide Used for Stable Inorganic Perovskite Solar Cells", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic inorganic perovskites emerged as a new generation of absorber materials for high-efficiency low-cost solar cells in 2009. Very recently, fully inorganic perovskite quantum dots also led to promising efficiencies, making them a potentially stable and efficient alternative to their hybrid cousins. Currently, the record efficiency is obtained with CsPbI3, whose crystallographical characterization is still limited. Here, we show through high-resolution in situ synchrotron XRD measurements that CsPbI3 can be undercooled below its transition temperature and temporarily maintained in its perovskite temperature, stabilizing a metastable perovskite polytype (black gamma-phase) crucial for photovoltaic applications. Our analysis of the structural phase transitions reveals a highly anisotropic evolution of the individual lattice parameters versus temperature. Structural, vibrational, and electronic properties of all the experimentally observed black phases are further inspected based on several theoretical approaches. Whereas the black gamma-phase is shown to behave harmonically around equilibrium, for the tetragonal phase, density functional theory reveals the same anharmonic behavior, with a Brillouin zone-centered double-well instability, as for the cubic phase. Using total energy and vibrational entropy calculations, we highlight the competition between all the low-temperature phases of CsPbI3 (gamma, delta, beta) and show that avoiding the order-disorder entropy term arising from double-well instabilities is key to preventing the formation of the yellow perovskitoid phase. A symmetry-based tight-binding model, validated by self-consistent GW calculations including spin-orbit coupling, affords further insight into their electronic properties, with evidence of Rashba effect for both cubic and tetragonal phases when using the symmetry-breaking structures obtained through frozen phonon calculations. structure down to room", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 605, "Times Cited, All Databases": 638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 12, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3477, "End Page": 3486, "Article Number": null, "DOI": "10.1021/acsnullo.8b00267", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b00267", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431088200045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin, D; Huo, WC; Yuan, YB; Huang, JH; Liu, Y; Zhang, YX; Dong, F; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin, Duan; Huo, Wangchen; Yuan, Yingbo; Huang, Jianhang; Liu, Yao; Zhang, Yuxin; Dong, Fan; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic-Inorganic-Induced Polymer Intercalation into Layered Composites for Aqueous Zinc-Ion Battery", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-based batteries are very attractive alternative devices for current energy storage by virtue of their low cost and high security. However, the performance of vanadium oxide cathode strongly relies on the distance of interlayer spacing. Here, we employ layered PEDOT-NH4V3O8 (PEDOT-NVO) as a cathode material, which produces an enlarged interlayer spacing of 10.8 angstrom (against 7.8 angstrom for the single NVO) by effectively conducting polymer intercalation. This cathode material exhibits an improved capacity of 356.8 mAh g(-1) at 0.05 A g(-1) and 163.6 mAh g(-1), even at the highest current density of 10 A g(-1) (with a high retention from 0.05 to 10 A g(-1)), and features an ultra-long lifetime of over 5,000 charge-discharge cycles with a capacity retention of 94.1%. A combination of mechanism analyses and theoretical calculations suggest that the oxygen vacancies and larger interlayer spacing through polymer assistance account for the improved electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2020, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 968, "End Page": 984, "Article Number": null, "DOI": "10.1016/j.chempr.2020.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.02.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526099500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Velasco-Velez, JJ; Wu, CH; Pascal, TA; Wan, LWF; Guo, JH; Prendergast, D; Salmeron, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Velasco-Velez, Juan-Jesus; Wu, Cheng Hao; Pascal, Tod A.; Wan, Liwen F.; Guo, Jinghua; Prendergast, David; Salmeron, Miquel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The structure of interfacial water on gold electrodes studied by x-ray absorption spectroscopy", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The molecular structure of the electrical double layer determines the chemistry in all electrochemical processes. Using x-ray absorption spectroscopy (XAS), we probed the structure of water near gold electrodes and its bias dependence. Electron yield XAS detected at the gold electrode revealed that the interfacial water molecules have a different structure from those in the bulk. First principles calculations revealed that similar to 50% of the molecules lie flat on the surface with saturated hydrogen bonds and another substantial fraction with broken hydrogen bonds that do not contribute to the XAS spectrum because their core-excited states are delocalized by coupling with the gold substrate. At negative bias, the population of flat-lying molecules with broken hydrogen bonds increases, producing a spectrum similar to that of bulk water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2014, "Volume": 346, "Issue": 6211, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 831, "End Page": 834, "Article Number": null, "DOI": "10.1126/science.1259437", "DOI Link": "http://dx.doi.org/10.1126/science.1259437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344659900039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZL; Lin, SH; Onofrio, N; Zhou, LM; Shi, FY; Lu, W; Kang, K; Zhang, Q; Lau, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zheng-Long; Lin, Shenghuang; Onofrio, Nicolas; Zhou, Limin; Shi, Fangyi; Lu, Wei; Kang, Kisuk; Zhang, Qiang; Lau, Shu Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional catalytic effects of black phosphorus quantum dots in shuttling-free lithium sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium sulfur batteries with high energy densities are promising next-generation energy storage systems. However, shuttling and sluggish conversion of polysulfides to solid lithium sulfides limit the full utilization of active materials. Physical/chemical confinement is useful for anchoring polysulfides, but not effective for utilizing the blocked intermediates. Here, we employ black phosphorus quantum dots as electrocatalysts to overcome these issues. Both the experimental and theoretical results reveal that black phosphorus quantum dots effectively adsorb and catalyze polysulfide conversion. The activity is attributed to the numerous catalytically active sites on the edges of the quantum dots. In the presence of a small amount of black phosphorus quantum dots, the porous carbon/sulfur cathodes exhibit rapid reaction kinetics and no shuttling of polysulfides, enabling a low capacity fading rate (0.027% per cycle over 1000 cycles) and high areal capacities. Our findings demonstrate application of a metal-free quantum dot catalyst for high energy rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4164, "DOI": "10.1038/s41467-018-06629-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06629-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446800200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, XH; Qiao, Y; Do, C; Bras, W; He, CY; Ke, YB; Russell, TP; Qiu, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Xiaohui; Qiao, Yan; Do, Changwoo; Bras, Wim; He, Chunyong; Ke, Yubin; Russell, Thomas P.; Qiu, Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hysteresis-Free nulloparticle-Reinforced Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The elastic storage and release of mechanical energy has been key to many developments throughout the history of mankind. Resilience, absent hysteresis, has been an elusive goal to achieve, particularly at large deformations. Using a low-crosslink-density polyacrylamide hydrogel at 96% water content having hyperbranched silica nulloparticles (HBSPs) as the major junction points, a hysteresis-free material is realized. The fatigue-free characteristic of these composite hydrogels is evidenced by the invariance of the stress-strain curves at strain ratios of 4, even after 5000 cycles. At a strain ratio of 7, only a 1.3% hysteresis is observed. A markedly increased strain-ratio-at-break of 11.5 is observed. The unique attributes of these resilient hydrogels are manifested in the high-fidelity detection of dynamic deformations under cyclic loading over a broad range of frequencies, difficult to achieve with other materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 34, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2108243, "DOI": "10.1002/adma.202108243", "DOI Link": "http://dx.doi.org/10.1002/adma.202108243", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737076400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YC; Yang, H; Xiong, TZ; Adekoya, D; Qiu, WT; Wang, ZM; Zhang, SQ; Balogun, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yongchao; Yang, Hao; Xiong, Tuzhi; Adekoya, David; Qiu, Weitao; Wang, Zhongmin; Zhang, Shanqing; Balogun (Jie Tang), M-Sadeeq", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption energy engineering of nickel oxide hybrid nullosheets for high areal capacity flexible lithium-ion batteries", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enriching electrode materials with definite functions is of great influence but highly challenging towards achieving high areal capacity lithium ion batteries (LIBs). Taking transition metal oxides (TMOs) as a case study, several attempts have been employed to demonstrate the large variations in lithium storage performance of TMOs, but explanation of the adsorption capability is rarely reported. Herein, the Li-ion storage chemistry of NiO nullosheets is successfully enhanced by modulating the position of the p-orbital energy level via engineering with porous N-doped carbon fiber and carbon quantum dots (CDs). The as-prepared monolithic NiO hybrid nullosheets (denoted CF/ECF/NiO/CD) exhibit high reversible areal capacity of 3.97 mA h cm(-2) at 0.25 mA cm(-2), excellent cyclic stability with capacity of 2.91 mA h cm(-2) at 3.0 mA cm(-2), as well as attractive rate capacity of 2.61 mA h cm(-2) at 6.0 mA cm(-2). In situ Raman analyses, XPS, and DFT calculations reveal that performance enhancement is related to the electronic modulations between NiO, porous carbon fiber and CDs that triggers the shift of the pband towards accommodating interfacial electron transfer that helps in promoting the Li storage activity. In addition, an all-flexible lithium ion battery based on CF/ECF/NiO/CD anode is assembled and a volumetric energy density of 619.9 Wh L-1 is achieved (equivalent to an energy density of 201.7 Wh kg(-1)). This work opens an achievable approach for high-areal-capacity LIBs and provides relevant understanding into designing other LIB electrodes and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 25, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 41, "End Page": 51, "Article Number": null, "DOI": "10.1016/j.ensm.2019.11.001", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2019.11.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508681700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benz, F; Schmidt, MK; Dreismann, A; Chikkaraddy, R; Zhang, Y; Demetriadou, A; Carnegie, C; Ohadi, H; de Nijs, B; Esteban, R; Aizpurua, J; Baumberg, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benz, Felix; Schmidt, Mikolaj K.; Dreismann, Alexander; Chikkaraddy, Rohit; Zhang, Yao; Demetriadou, Angela; Carnegie, Cloudy; Ohadi, Hamid; de Nijs, Bart; Esteban, Ruben; Aizpurua, Javier; Baumberg, Jeremy J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-molecule optomechanics in picocavities", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Trapping light with noble metal nullostructures overcomes the diffraction limit and can confine light to volumes typically on the order of 30 cubic nullometers. We found that individual atomic features inside the gap of a plasmonic nulloassembly can localize light to volumes well below 1 cubic nullometer (picocavities), enabling optical experiments on the atomic scale. These atomic features are dynamically formed and disassembled by laser irradiation. Although unstable at room temperature, picocavities can be stabilized at cryogenic temperatures, allowing single atomic cavities to be probed for many minutes. Unlike traditional optomechanical resonators, such extreme optical confinement yields a factor of 10(6) enhancement of optomechanical coupling between the picocavity field and vibrations of individualmolecular bonds. This work sets the basis for developing nulloscale nonlinear quantum optics on the single-molecule level.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 669, "Times Cited, All Databases": 718, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2016, "Volume": 354, "Issue": 6313, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 726, "End Page": 729, "Article Number": null, "DOI": "10.1126/science.aah5243", "DOI Link": "http://dx.doi.org/10.1126/science.aah5243", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387326300031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, ML; Ji, X; Wang, QY; Lin, ZJ; Li, MY; Liu, T; Wang, CL; Hu, YS; Li, H; Huang, XJ; Chen, LQ; Suo, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Minglei; Ji, Xiao; Wang, Qiyu; Lin, Zejing; Li, Meiying; Liu, Tao; Wang, Chengliang; Hu, Yong-Sheng; Li, Hong; Huang, Xuejie; Chen, Liquan; Suo, Liumin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion-enrichment interface enables high-voltage anode-free lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aggressive chemistry involving Li metal anode (LMA) and high-voltage LiNi0.8Mn0.1Co0.1O2 (NCM811) cathode is deemed as a pragmatic approach to pursue the desperate 400 Wh kg(-1). Yet, their implementation is plagued by low Coulombic efficiency and inferior cycling stability. Herein, we propose an optimally fluorinated linear carboxylic ester (ethyl 3,3,3-trifluoropropanoate, FEP) paired with weakly solvating fluoroethylene carbonate and dissociated lithium salts (LiBF4 and LiDFOB) to prepare a weakly solvating and dissociated electrolyte. An anion-enrichment interface prompts more anions' decomposition in the inner Helmholtz plane and higher reduction potential of anions. Consequently, the anion-derived interface chemistry contributes to the compact and columnar-structure Li deposits with a high CE of 98.7% and stable cycling of 4.6 V NCM811 and LiCoO2 cathode. Accordingly, industrial anode-free pouch cells under harsh testing conditions deliver a high energy of 442.5 Wh kg(-1) with 80% capacity retention after 100 cycles. The implementation of Li metal anode with high-voltage Ni/Co rich cathode is plagued by low coulombic efficiency and inferior cycling stability. Here authors propose an anion-enriched interface to facilitate the columnar-structure of Li deposits to solve this issue.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1082, "DOI": "10.1038/s41467-023-36853-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36853-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002656000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZH; Bottari, G; Afanasenko, A; Stuart, MCA; Deuss, PJ; Fridrich, B; Barta, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zhuohua; Bottari, Giovanni; Afanasenko, Anastasiia; Stuart, Marc C. A.; Deuss, Peter J.; Fridrich, Balint; Barta, Katalin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Complete lignocellulose conversion with integrated catalyst recycling yielding valuable aromatics and fuels", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignocellulose, the main component of agricultural and forestry waste, harbours tremendous potential as a renewable starting material for future biorefinery practices. However, this potential remains largely unexploited due to the lack of strategies that derive substantial value from its main constituents. Here, we present a catalytic strategy that is able to transform lignocellulose to a range of attractive products. At the centre of our approach is the flexible use of a non-precious metal catalyst in two distinct stages of a lignocellulose conversion process that enables integrated catalyst recycling through full conversion of all process residues. From the lignin, pharmaceutical and polymer building blocks are obtained. Notably, among these pathways are systematic chemo-catalytic methodologies to yield amines from lignin. The (hemi) cellulose-derived aliphatic alcohols are transformed to alkanes, achieving excellent total carbon utilization. This work will inspire the development of fully sustainable and economically viable biorefineries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 82, "End Page": 92, "Article Number": null, "DOI": "10.1038/s41929-017-0007-z", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0007-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428619500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Q; Pillai, HS; Huang, Y; Liu, SK; Mu, QM; Han, X; Yan, ZH; Zhou, H; He, Q; Xin, HL; Zhu, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Qiang; Pillai, Hemanth Somarajan; Huang, Yang; Liu, Shikai; Mu, Qingmin; Han, Xue; Yan, Zihao; Zhou, Hua; He, Qian; Xin, Hongliang; Zhu, Huiyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking adsorption-energy scaling limitations of electrocatalytic nitrate reduction on intermetallic CuPd nullocubes by machine-learned insights", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning is a powerful tool for screening electrocatalytic materials. Here, the authors reported a seamless integration of machine-learned physical insights with the controlled synthesis of structurally ordered intermetallic nullocrystals and well-defined catalytic sites for efficient nitrate reduction to ammonia. The electrochemical nitrate reduction reaction (NO3RR) to ammonia is an essential step toward restoring the globally disrupted nitrogen cycle. In search of highly efficient electrocatalysts, tailoring catalytic sites with ligand and strain effects in random alloys is a common approach but remains limited due to the ubiquitous energy-scaling relations. With interpretable machine learning, we unravel a mechanism of breaking adsorption-energy scaling relations through the site-specific Pauli repulsion interactions of the metal d-states with adsorbate frontier orbitals. The non-scaling behavior can be realized on (100)-type sites of ordered B2 intermetallics, in which the orbital overlap between the hollow *N and subsurface metal atoms is significant while the bridge-bidentate *NO3 is not directly affected. Among those intermetallics predicted, we synthesize monodisperse ordered B2 CuPd nullocubes that demonstrate high performance for NO3RR to ammonia with a Faradaic efficiency of 92.5% at -0.5 V-RHE and a yield rate of 6.25 mol h(-1) g(-1) at -0.6 V-RHE. This study provides machine-learned design rules besides the d-band center metrics, paving the path toward data-driven discovery of catalytic materials beyond linear scaling limitations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2338, "DOI": "10.1038/s41467-022-29926-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29926-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789018200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, HL; Wang, C; Shaw, JC; Cheng, R; Chen, Y; Huang, XQ; Liu, Y; Weiss, NO; Lin, ZY; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Hailong; Wang, Chen; Shaw, Jonathan C.; Cheng, Rui; Chen, Yu; Huang, Xiaoqing; Liu, Yuan; Weiss, Nathan O.; Lin, Zhaoyang; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large Area Growth and Electrical Properties of p-Type WSe2 Atomic Layers", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dichacogenides represent a unique class of two-dimensional layered materials that can be exfoliated into single or few atomic layers. Tungsten diselenide (WSe2) is one typical example with p-type semiconductor characteristics. Bulk WSe2 has an indirect band gap (similar to 1.2 eV), which transits into a direct band gap (similar to 1.65 eV) in monolayers. Monolayer WSe2, therefore, is of considerable interest as a new electronic material for functional electronics and optoelectronics. However, the controllable synthesis of large-area WSe2 atomic layers remains a challenge. The studies on WSe2 are largely limited by relatively small lateral size of exfoliated flakes and poor yield, which has significantly restricted the large-scale applications of the WSe2 atomic layers. Here, we report a systematic study of chemical vapor deposition approach for large area growth of atomically thin WSe2 film with the lateral dimensions up to similar to 1 cm(2). Microphotoluminescence mapping indicates distinct layer dependent efficiency. The monolayer area exhibits much stronger light emission than bilayer or multilayers, consistent with the expected transition to direct band gap in the monolayer limit. The transmission electron microscopy studies demonstrate excellent crystalline quality of the atomically thin WSe2. Electrical transport studies further show that the p-type WSe2 field-effect transistors exhibit excellent electronic characteristics with effective hole carrier mobility up to 100 cm(2) V-1 s(-1) for monolayer and up to 350 cm(2) V-1 s(-1) for few-layer materials at room temperature, comparable or well above that of previously reported mobility values for the synthetic WSe2 and comparable to the best exfoliated materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 709, "End Page": 713, "Article Number": null, "DOI": "10.1021/nl504256y", "DOI Link": "http://dx.doi.org/10.1021/nl504256y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348086100110", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, JQ; Cui, P; Chen, XL; Wang, JX; Parida, K; Lin, MF; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Jiaqing; Cui, Peng; Chen, Xiaoliang; Wang, Jiangxin; Parida, Kaushik; Lin, Meng-Fang; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-touch-actuated textile-based triboelectric nullogenerator with black phosphorus for durable biomechanical energy harvesting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Textiles that are capable of harvesting biomechanical energy via triboelectric effects are of interest for self-powered wearable electronics. Fabrication of conformable and durable textiles with high triboelectric outputs remains challenging. Here we propose a washable skintouch- actuated textile-based triboelectric nullogenerator for harvesting mechanical energy from both voluntary and involuntary body motions. Black phosphorus encapsulated with hydrophobic cellulose oleoyl ester nulloparticles serves as a synergetic electron-trapping coating, rendering a textile nullogenerator with long-term reliability and high triboelectricity regardless of various extreme deformations, severe washing, and extended environmental exposure. Considerably high output (similar to 250-880 V, similar to 0.48-1.1 mu A cm(-2)) can be attained upon touching by hand with a small force (similar to 5 N) and low frequency (similar to 4 Hz), which can power lightemitting diodes and a digital watch. This conformable all-textile-nullogenerator is incorporable onto cloths/skin to capture the low output of 60 V from subtle involuntary friction with skin, well suited for users' motion or daily operations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 463, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4280, "DOI": "10.1038/s41467-018-06759-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06759-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447298900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, JJ; Wang, R; Chen, XH; Yao, CL; Jin, XY; Wang, KL; Huang, WC; Huang, TY; Zhao, YP; Zhai, YX; Meng, D; Tan, S; Liu, RZ; Wang, ZK; Zhu, CH; Zhu, K; Beard, MC; Yan, YF; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Jingjing; Wang, Rui; Chen, Xihan; Yao, Canglang; Jin, Xiaoyun; Wang, Kai-Li; Huang, Wenchao; Huang, Tianyi; Zhao, Yepin; Zhai, Yaxin; Meng, Dong; Tan, Shaun; Liu, Ruzhang; Wang, Zhao-Kui; Zhu, Chenhui; Zhu, Kai; Beard, Matthew C.; Yan, Yanfa; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconfiguring the band-edge states of photovoltaic perovskites by conjugated organic cations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The band edges of metal-halide perovskites with a general chemical structure of ABX(3) (A, usually a monovalent organic cation; B, a divalent cation; and X, a halide anion) are constructed mainly of the orbitals from B and X sites. Hence, the structural and compositional varieties of the inorganic B-X framework are primarily responsible for regulating their electronic properties, whereas A-site cations are thought to only help stabilize the lattice and not to directly contribute to near-edge states. We report a pi-conjugation-induced extension of electronic states of A-site cations that affects perovskite frontier orbitals. The pi-conjugated pyrene-containing A-site cations electronically contribute to the surface band edges and influence the carrier dynamics, with a properly tailored intercalation distance between layers of the inorganic framework. The ethylammonium pyrene increased hole mobilities, improved power conversion efficiencies relative to that of a reference perovskite, and enhanced device stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2021, "Volume": 371, "Issue": 6529, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 636, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd4860", "DOI Link": "http://dx.doi.org/10.1126/science.abd4860", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615715300055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YH; Qiao, JS; Gao, S; Hu, FR; He, DW; Wu, B; Yang, ZY; Xu, BC; Li, Y; Shi, Y; Ji, W; Wang, P; Wang, XY; Xiao, M; Xu, HX; Xu, JB; Wang, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuhan; Qiao, Jingsi; Gao, Si; Hu, Fengrui; He, Daowei; Wu, Bing; Yang, Ziyi; Xu, Bingchen; Li, Yun; Shi, Yi; Ji, Wei; Wang, Peng; Wang, Xiaoyong; Xiao, Min; Xu, Hangxun; Xu, Jian-Bin; Wang, Xinran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing Carrier Transport and Structure-Property Relationship of Highly Ordered Organic Semiconductors at the Two-Dimensional Limit", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the basic assumptions in organic field-effect transistors, the most fundamental device unit in organic electronics, is that charge transport occurs two dimensionally in the first few molecular layers near the dielectric interface. Although the mobility of bulk organic semiconductors has increased dramatically, direct probing of intrinsic charge transport in the two-dimensional limit has not been possible due to excessive disorders and traps in ultrathin organic thin films. Here, highly ordered single-crystalline mono- to tetralayer pentacene crystals are realized by van derWaals (vdW) epitaxy on hexagonal BN. We find that the charge transport is dominated by hopping in the first conductive layer, but transforms to bandlike in subsequent layers. Such an abrupt phase transition is attributed to strong modulation of the molecular packing by interfacial vdW interactions, as corroborated by quantitative structural characterization and density functional theory calculations. The structural modulation becomes negligible beyond the second conductive layer, leading to a mobility saturation thickness of only similar to 3 nm. Highly ordered organic ultrathin films provide a platform for new physics and device structures (such as heterostructures and quantum wells) that are not possible in conventional bulk crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2016, "Volume": 116, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16602, "DOI": "10.1103/PhysRevLett.116.016602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.016602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367677300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gharibzadeh, S; Fassl, P; Hossain, IM; Rohrbeck, P; Frericks, M; Schmidt, M; Duong, T; Khan, MR; Abzieher, T; Nejand, BA; Schackmar, F; Almora, O; Feeney, T; Singh, R; Fuchs, D; Lemmer, U; Hofmann, JP; Weber, SAL; Paetzold, UW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gharibzadeh, Saba; Fassl, Paul; Hossain, Ihteaz M.; Rohrbeck, Pascal; Frericks, Markus; Schmidt, Moritz; Duong, The; Khan, Motiur Rahman; Abzieher, Tobias; Nejand, Bahram Abdollahi; Schackmar, Fabian; Almora, Osbel; Feeney, Thomas; Singh, Roja; Fuchs, Dirk; Lemmer, Uli; Hofmann, Jan P.; Weber, Stefan A. L.; Paetzold, Ulrich W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two birds with one stone: dual grain-boundary and interface passivation enables >22% efficient inverted methylammonium-free perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advancing inverted (p-i-n) perovskite solar cells (PSCs) is key to further enhance the power conversion efficiency (PCE) and stability of flexible and perovskite-based tandem photovoltaics. Yet, the presence of defects at grain boundaries and in particular interfacial recombination at the perovskite/electron transporting layer interface induce severe non-radiative recombination losses, limiting the open-circuit voltage (V-OC) and fill factor (FF) of PSCs in this architecture. In this work, we introduce a dual passivation strategy using the long chain alkylammonium salt phenethylammonium chloride (PEACl) both as an additive and for surface treatment to simultaneously passivate the grain boundaries and the perovskite/C-60 interface. Using [2-(9H-carbazol-9-yl)ethyl]phosphonic acid (2PACz) as a hole transporting layer and a methylammonium (MA)-free Cs(0.18)FA(0.82)PbI(3) perovskite absorber with a bandgap of similar to 1.57 eV, prolonged charge carrier lifetime and an on average 63 meV enhanced internal quasi-Fermi level splitting are achieved upon dual passivation compared to reference p-i-n PSCs. Thereby, we achieve one of the highest PCEs for p-i-n PSCs of 22.7% (stabilized at 22.3%) by advancing simultaneously the V-OC and FF up to 1.162 V and 83.2%, respectively. Using a variety of experimental techniques, we attribute the positive effects to the formation of a heterogeneous 2D Ruddlesden-Popper (PEA)(2)(Cs(1-x)FA(x))(n-1)Pb-n(I1-yCly)(3n+1) phase at the grain boundaries and surface of the perovskite films. At the same time, the activation energy for ion migration is significantly increased, resulting in enhanced stability of the PSCs under light, humidity, and thermal stress. The presented dual passivation strategy highlights the importance of defect management both in the grain boundaries and the surface of the perovskite absorber layer using a proper passivation material to achieve both highly efficient and stable inverted p-i-n PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2021, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5875, "End Page": 5893, "Article Number": null, "DOI": "10.1039/d1ee01508g", "DOI Link": "http://dx.doi.org/10.1039/d1ee01508g", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686707500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Farag, A; Feeney, T; Hossain, IM; Schackmar, F; Fassl, P; Küster, K; Bäuerle, R; Ruiz-Preciado, MA; Hentschel, M; Ritzer, DB; Diercks, A; Li, Y; Nejand, BA; Laufer, F; Singh, R; Starke, U; Paetzold, UW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Farag, Ahmed; Feeney, Thomas; Hossain, Ihteaz M.; Schackmar, Fabian; Fassl, Paul; Kuester, Kathrin; Baeuerle, Rainer; Ruiz-Preciado, Marco A.; Hentschel, Mario; Ritzer, David B.; Diercks, Alexander; Li, Yang; Nejand, Bahram Abdollahi; Laufer, Felix; Singh, Roja; Starke, Ulrich; Paetzold, Ulrich W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaporated Self-Assembled Monolayer Hole Transport Layers: Lossless Interfaces in p-i-n Perovskite Solar Cells", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering of the interface between perovskite absorber thin films and charge transport layers has fueled the development of perovskite solar cells (PSCs) over the past decade. For p-i-n PSCs, the development and adoption of hole transport layers utilizing self-assembled monolayers (SAM-HTLs) based on carbazole functional groups with phosphonic acid anchoring groups has enabled almost lossless contacts, minimizing interfacial recombination to advance power conversion efficiency in single-junction and tandem solar cells. However, so far these materials have been deposited exclusively via solution-based methods. Here, for the first time, vacuum-based evaporation of the most common carbazole-based SAM-HTLs (2PACz, MeO-2PACz, and Me-4PACz) is reported. X-ray photoelectron spectroscopy and infrared spectroscopy demonstrate no observable chemical differences in the evaporated SAMs compared to solution-processed counterparts. Consequently, the near lossless interfacial properties are either preserved or even slightly improved as demonstrated via photoluminescence measurements and an enhancement in open-circuit voltage. Strikingly, applying evaporated SAM-HTLs to complete PSCs demonstrates comparable performance to their solution-processed counterparts. Furthermore, vacuum deposition is found to improve perovskite wetting and fabrication yield on previously non-ideal materials (namely Me-4PACz) and to display conformal and high-quality coating of micrometer-sized textured surfaces, improving the versatility of these materials without sacrificing their beneficial properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 13, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202203982", "DOI Link": "http://dx.doi.org/10.1002/aenm.202203982", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000907484900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, CZ; Hao, L; Hussein, A; Young, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Chunze; Hao, Liang; Hussein, Ahmed; Young, Philippe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti-6Al-4V triply periodic minimal surface structures for bone implants fabricated via selective laser melting", "Source Title": "JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triply periodic minimal surface (TPMS) structures have already been shown to be a versatile source of biomorphic scaffold designs. Therefore, in this work, Ti-6Al-4V Gyroid and Diamond TPMS lattices having an interconnected high porosity of 80-95% and pore sizes in the range of 560-1600 mu m and 480-1450 mu m respectively were manufactured by selective laser melting (SLM) for bone implants. The manufacturability, microstructure and mechanical properties of the Ti-6Al-4V TPMS lattices were evaluated. Comparison between 3D micro-CT reconstructed models and original CAD models of the Ti-6Al-4V TPMS lattices shows excellent reproduction of the designs. The as-built Ti-6Al-4V struts exhibit the microstructure of columnar grains filled with very fine and orthogonally oriented alpha' martensitic laths with the width of 100-300 nm and have the microhardness of 4.01 +/- 0.34 GPa. After heat treatment at 680 degrees C for 4 h, the alpha' martensite was converted to a mixture of alpha and beta, in which the alpha phase being the dominullt fraction is present as fine laths with the width of 500-800 nm and separated by a small amount of narrow, interphase regions of dark beta phase. Also, the microhardness is decreased to 3.71 +/- 0.35 GPa due to the coarsening of the microstructure. The 80-95% porosity TPMS lattices exhibit a comparable porosity with trabecular bone, and the modulus is in the range of 0.12-1.25 GPa and thus can be adjusted to the modulus of trabecular bone. At the same range of porosity of 5-10%, the moduli of cortical bone and of the Ti-6Al-4V TPMS lattices are in a similar range. Therefore, the modulus and porosity of Ti-6Al-4V TPMS lattices can be tailored to the levels of human bones and thus reduce or avoid stress shielding and increase longevity of implants. Due to the biomorphic designs, and high interconnected porosity and stiffness comparable to human bones, SLM-made Ti-6Al-4V TPMS lattices can be a promising material for load bearing bone implants. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 518, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 61, "End Page": 73, "Article Number": null, "DOI": "10.1016/j.jmbbm.2015.06.024", "DOI Link": "http://dx.doi.org/10.1016/j.jmbbm.2015.06.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362603900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, CH; Liu, C; Su, D; Xin, HLL; Fang, HT; Erens, B; Zhang, S; Murray, CB; Salmeron, MB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Cheng Hao; Liu, Chang; Su, Dong; Xin, Huolin L.; Fang, Hai-Tao; Erens, Baran; Zhang, Sen; Murray, Christopher B.; Salmeron, Miguel B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimetallic synergy in cobalt-palladium nullocatalysts for CO oxidation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bimetallic and multi-component catalysts typically exhibit composition-dependent activity and selectivity, and when optimized often outperform single-component catalysts. Here we used ambient-pressure X-ray photoelectron spectroscopy (AP-XPS) and in situ and ex situ transmission electron microscopy (TEM) to elucidate the origin of composition dependence observed in the catalytic activities of monodisperse CoPd bimetallic nullocatalysts for CO oxidation. We found that the catalysis process induced a reconstruction of the catalysts, leaving CoOx on the nulloparticle surface. The synergy between Pd and CoOx coexisting on the surface promotes the catalytic activity of the bimetallic catalysts. This synergistic effect can be optimized by tuning the Co/Pd ratios in the nulloparticle synthesis, and it reaches a maximum at compositions near Co0.24Pd0.76, which achieves complete CO conversion at the lowest temperature. Our combined AP-XPS and TEM studies provide direct observation of the surface evolution of the bimetallic nulloparticles under catalytic conditions and show how this evolution correlates with catalytic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 85, "Article Number": null, "DOI": "10.1038/s41929-018-0190-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0190-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455845400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YX; Zeng, YX; Chen, Y; Luan, DY; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yunxiang; Zeng, Yinxiang; Chen, Ye; Luan, Deyan; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous N-rich Carbon with Single-Ni Atoms as a Multifunctional Sulfur Host for Li-S Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Physicochemical confinement and catalytic conversion of lithium polysulfides (LiPSs) are crucial to suppress the shuttle effect and enhance the redox kinetics of lithium-sulfur (Li-S) batteries. In this study, a NH4Cl-assisted pyrolysis strategy is developed to fabricate highly mesoporous N-rich carbon (designed as NC(p)) featuring thin outer shells and porous inner networks, on which single-Ni atoms are anchored to form an excellent sulfur host (designed as Ni-NC(p)) for Li-S batteries. During pyrolysis, the pyrolytic HCl from confined NH4Cl within ZIF-8 will in situ etch ZIF-8 to produce rich mesoporous in the carbonized product NC(p). The mesoporous Ni-NC(p) enables favorable electron/ion transfer, high sulfur loading, and effective confinement of LiPSs, while the catalytic effect of single-Ni species enhances the redox kinetics of LiPSs. As a result, the sulfur cathode based on the Ni-NC(p) host delivers obviously improved Li-S battery performance with high specific capacity, good rate capability, and cycling stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2022, "Volume": 61, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212680", "DOI Link": "http://dx.doi.org/10.1002/anie.202212680", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870421800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geng, J; Ji, SH; Jin, M; Zhang, C; Xu, M; Wang, GZ; Liang, CH; Zhang, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geng, Jing; Ji, Sihan; Jin, Meng; Zhang, Chao; Xu, Min; Wang, Guozhong; Liang, Changhao; Zhang, Haimin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambient Electrosynthesis of Urea with Nitrate and Carbon Dioxide over Iron-Based Dual-Sites", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient electrocatalysts to generate key *NH2 and *CO intermediates is crucial for ambient urea electrosynthesis with nitrate (NO3-) and carbon dioxide (CO2). Here we report a liquid-phase laser irradiation method to fabricate symbiotic graphitic carbon encapsulated amorphous iron and iron oxide nulloparticles on carbon nullotubes (Fe(a)@C-Fe3O4/CNTs). Fe(a)@C-Fe3O4/CNTs exhibits superior electrocatalytic activity toward urea synthesis using NO3- and CO2, affording a urea yield of 1341.3 +/- 112.6 mu g h(-1) mg(cat)(-1) and a faradic efficiency of 16.5 +/- 6.1 % at ambient conditions. Both experimental and theoretical results indicate that the formed Fe(a)@C and Fe3O4 on CNTs provide dual active sites for the adsorption and activation of NO3- and CO2, thus generating key *NH2 and *CO intermediates with lower energy barriers for urea formation. This work would be helpful for design and development of high-efficiency dual-site electrocatalysts for ambient urea synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 62, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202210958", "DOI Link": "http://dx.doi.org/10.1002/anie.202210958", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909401900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, X; Qiu, Y; Jiang, B; Chen, ZY; Zhao, CH; Zhou, H; Yang, L; Fan, LS; Zhang, Y; Zhang, NQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Xun; Qiu, Yue; Jiang, Bo; Chen, Zhaoyu; Zhao, Chenghao; Zhou, Hao; Yang, Li; Fan, Lishuang; Zhang, Yu; Zhang, Naiqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated Fe-Co heteronuclear diatomic sites as efficient bifunctional catalysts for high-performance lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The slow redox kinetics of polysulfides and the difficulties in decomposition of Li2S are two serious obstacles to lithium-sulfur batteries. Here, the authors report an isolated Fe-Co heteronuclear diatomic catalyst to achieve high efficiency bifunctional catalysis for lithium-sulfur batteries. The slow redox kinetics of polysulfides and the difficulties in decomposition of Li2S during the charge and discharge processes are two serious obstacles to the practical application of lithium-sulfur batteries. Herein, we construct the Fe-Co diatomic catalytic materials supported by hollow carbon spheres to achieve high-efficiency catalysis for the conversion of polysulfides and the decomposition of Li2S simultaneously. The Fe atom center is beneficial to accelerate the discharge reaction process, and the Co atom center is favorable for charging process. Theoretical calculations combined with experiments reveal that this excellent bifunctional catalytic activity originates from the diatomic synergy between Fe and Co atom. As a result, the assembled cells exhibit the high rate performance (the discharge specific capacity achieves 688 mAh g(-1) at 5 C) and the excellent cycle stability (the capacity decay rate is 0.018% for 1000 cycles at 1 C).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 291, "DOI": "10.1038/s41467-022-35736-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35736-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001006189100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zang, LL; Sun, LG; Zhang, SC; Finnerty, C; Kim, A; Ma, J; Mi, BX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zang, Linlin; Sun, Liguo; Zhang, Shaochun; Finnerty, Casey; Kim, Albert; Ma, Jun; Mi, Baoxia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullofibrous hydrogel-reduced graphene oxide membranes for effective solar-driven interfacial evaporation and desalination", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfacial evaporation from light-absorbing, porous materials have offered an exciting opportunity to utilize sustainable renewable solar energy for desalination. However, the efforts to understand the fundamental mechanisms governing the interfacial evaporation have greatly lagged behind performance studies. Herein, a hybrid nullofibrous hydrogel-reduced graphene oxide (NHrG) membrane is demonstrated in this work. We experimentally characterized the state of water in the NHrG membrane and proved the presence of intermediate water in the porous membrane. By monitoring the vaporization enthalpy as a function of membrane saturation, we demonstrated that the vaporization of intermediate water dominates the interfacial evaporation process, thus playing a key role in lowering the vaporization enthalpy. The lowered enthalpy value together with other factors, such as the high light absorption efficiency enabled by reduced graphene oxide (rGO) and the porous hydrophilic network induced by electrospun hydrogel nullofibers, led to a highly efficient solar-driven interfacial evaporator. The NHrG membrane had an evaporation rate of up to 1.85 kg m-2h-1 with a high energy conversion efficiency of 95.4% under one sun irradiation. In addition, the evaporator exhibited excellent desalination performance in treating fresh seawater and achieved high removal of salt as well as heavy metal ions. Our study provides important knowledge for performance optimization and process design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2021, "Volume": 422, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 129998, "DOI": "10.1016/j.cej.2021.129998", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.129998", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672588200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LX; Chen, J; Fan, LL; Diéguez, O; Cao, JL; Pan, Z; Wang, YL; Wang, JG; Kim, M; Deng, SQ; Wang, JO; Wang, HH; Deng, JX; Yu, RB; Scott, JF; Xing, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linxing; Chen, Jun; Fan, Longlong; Dieguez, Oswaldo; Cao, Jiangli; Pan, Zhao; Wang, Yilin; Wang, Jinguo; Kim, Moon; Deng, Shiqing; Wang, Jiaou; Wang, Huanhua; Deng, Jinxia; Yu, Ranbo; Scott, James F.; Xing, Xianran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant polarization in super-tetragonal thin films through interphase strain", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strain engineering has emerged as a powerful tool to enhance the performance of known functional materials. Here we demonstrate a general and practical method to obtain supertetragonality and giant polarization using interphase strain. We use this method to create an out-of-plane-to-in-plane lattice parameter ratio of 1.238 in epitaxial composite thin films of tetragonal lead titanate (PbTiO3), compared to 1.065 in bulk. These thin films with super-tetragonal structure possess a giant remanent polarization, 236.3 microcoulombs per square centimeter, which is almost twice the value of known ferroelectrics. The supertetragonal phase is stable up to 725 degrees C, compared to the bulk transition temperature of 490 degrees C. The interphase-strain approach could enhance the physical properties of other functional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2018, "Volume": 361, "Issue": 6401, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 494, "End Page": 497, "Article Number": null, "DOI": "10.1126/science.aan2433", "DOI Link": "http://dx.doi.org/10.1126/science.aan2433", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440627300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Welin, ER; Le, C; Arias-Rotondo, DM; McCusker, JK; MacMillan, DWC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Welin, Eric R.; Le, Chip; Arias-Rotondo, Daniela M.; McCusker, James K.; MacMillan, David W. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PHOTOCHEMISTRY Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal catalysis has traditionally relied on organometallic complexes that can cycle through a series of ground-state oxidation levels to achieve a series of discrete yet fundamental fragment-coupling steps. The viability of excited-state organometallic catalysis via direct photoexcitation has been demonstrated. Although the utility of triplet sensitization by energy transfer has long been known as a powerful activation mode in organic photochemistry, it is surprising to recognize that photosensitization mechanisms to access excited-state organometallic catalysts have lagged far behind. Here, we demonstrate excited-state organometallic catalysis via such an activation pathway: Energy transfer from an iridium sensitizer produces an excited-state nickel complex that couples aryl halides with carboxylic acids. Detailed mechanistic studies confirm the role of photosensitization via energy transfer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2017, "Volume": 355, "Issue": 6323, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 380, "End Page": 384, "Article Number": null, "DOI": "10.1126/science.aal2490", "DOI Link": "http://dx.doi.org/10.1126/science.aal2490", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393172800035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, YJ; Feng, JB; Huo, SQ; Song, PA; Yu, B; Liu, L; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Yijiao; Feng, Jiabing; Huo, Siqi; Song, Pingan; Yu, Bin; Liu, Lei; Wang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyphosphoramide-intercalated MXene for simultaneously enhancing thermal stability, flame retardancy and mechanical properties of polylactide", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The creation of thermostable, flame-retardant, mechanically robust bioplastics is highly desirable in the industry as one sustainable alternative to traditional petroleum-based plastics. Unfortunately, to date there lacks an effective strategy to endow commercial bioplastics, such as polylactide (PLA) with such desired integrated performances. Herein, we have demonstrated the fabrication of a novel MXene-phenyl phosphonic diaminohexane (MXene-PPDA) nullohybrid via the intercalation of PPDA into the MXene interlayer. The interlayer spacing of MXene nullosheets is enlarged and as-prepared MXene-PPDA is homogeneously dispersed in the PLA matrix. Incorporating 1.0 wt% MXene-PPDA enables PLA to achieve a UL-94 V-0 rating, with a similar to 22.2% reduction in peak heat release rate, indicating a significantly improved flame retardancy. Meanwhile, the 1.0 wt% MXene-PPDA also increases the initial decomposition temperature of PLA composite, giving rise to a similar to 25-fold enhancement in char yield relative to pure PLA. Additionally, the MXene-PPDA enhances the toughness while retains the mechanical strength for PLA. This work offers an innovative strategy for the design of multifunctional additives and the creation of high-performance polymers with high thermal stability, mechanical robustness and low flammability, expecting to find many practical applications in the industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2020, "Volume": 397, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125336, "DOI": "10.1016/j.cej.2020.125336", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.125336", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552025300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fortman, DJ; Brutman, JP; De Hoe, GX; Snyder, RL; Dichtel, WR; Hillmyer, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fortman, David J.; Brutman, Jacob P.; De Hoe, Guilhem X.; Snyder, Rachel L.; Dichtel, William R.; Hillmyer, Marc A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaches to Sustainable and Continually Recyclable Cross-Linked Polymers", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cross-linked polymers are ubiquitous in daily life, finding applications as tires, insulation, adhesives, automotive parts, and countless other products. The covalent cross links in these materials render them mechanically robust, chemically resistant, and thermally stable, but they also prevent recycling of these materials into similar-value goods. Furthermore, cross-linked polymers are typically produced from petroleum based feedstocks, and their hydrocarbon backbones render them nondegradable, making them unsustainable in the long term. In recent years, much effort has focused on the development of recycling strategies for cross-linked polymeric materials. In the following Perspective, we discuss many of these approaches, and highlight efforts to sustainably produce recyclable cross linked polymers. We present our thoughts on future challenges that must be overcome to enable widespread, viable, and more sustainable and practical implementation of these materials, including the sustainable sourcing of feedstocks, long-term environmental stability of inherently dynamic polymers, and moving toward industrially viable synthesis and reprocessing methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11145, "End Page": 11159, "Article Number": null, "DOI": "10.1021/acssuschemeng.8b02355", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.8b02355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443924100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Katoh, Y; Snead, LL; Henager, CH; Nozawa, T; Hinoki, T; Ivekovic, A; Novak, S; de Vicente, SMG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Katoh, Y.; Snead, L. L.; Henager, C. H., Jr.; Nozawa, T.; Hinoki, T.; Ivekovic, A.; Novak, S.; de Vicente, S. M. Gonzalez", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current status and recent research achievements in SiC/SiC composites", "Source Title": "JOURNAL OF NUCLEAR MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The silicon carbide fiber-reinforced silicon carbide matrix (SiC/SiC) composite system for fusion applications has seen a continual evolution from development a fundamental understanding of the material system and its behavior in a hostile irradiation environment to the current effort which is directed at a broad-based program of technology maturation program. In essence, over the past few decades this material system has steadily moved from a laboratory curiosity to an engineering material, both for fusion structural applications and other high performance application such as aerospace. This paper outlines the recent international scientific and technological achievements towards the development of SiC/SiC composite material technologies for fusion application and discusses future research directions. It also reviews the materials system in the larger context of progress to maturity as an engineering material for both the larger nuclear community and broader engineering applications. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 455, "Issue": "1-3", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 387, "End Page": 397, "Article Number": null, "DOI": "10.1016/j.jnucmat.2014.06.003", "DOI Link": "http://dx.doi.org/10.1016/j.jnucmat.2014.06.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348003600073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Zhang, Y; Su, Y; Liu, X; Zhang, PX; Lin, RB; Chen, SX; Deng, Q; Zeng, ZL; Deng, SG; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jun; Zhang, Yan; Su, Yun; Liu, Xing; Zhang, Peixin; Lin, Rui-Biao; Chen, Shixia; Deng, Qiang; Zeng, Zheling; Deng, Shuguang; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The separation of acetylene and carbon dioxide by porous materials requires delicate control over the pore size. Herein, the authors fine-tune the pore size at sub-nullometer scale in a series of isoreticular metal-organic frameworks to control the acetylene/carbon dioxide separation performance; subtle structural differences lead to remarkable performance enhancement. The separation of C2H2/CO2 is not only industrially important for acetylene purification but also scientifically challenging owing to their high similarities in physical properties and molecular sizes. Ultramicroporous metal-organic frameworks (MOFs) can exhibit a pore confinement effect to differentiate gas molecules of similar size. Herein, we report the fine-tuning of pore sizes in sub-nullometer scale on a series of isoreticular MOFs that can realize highly efficient C2H2/CO2 separation. The subtle structural differences lead to remarkable adsorption performances enhancement. Among four MOF analogs, by integrating appropriate pore size and specific binding sites, [Cu(dps)(2)(SiF6)] (SIFSIX-dps-Cu, SIFSIX = SiF62-, dps = 4.4'-dipyridylsulfide, also termed as NCU-100) exhibits the highest C2H2 uptake capacity and C2H2/CO2 selectivity. At room temperature, the pore space of SIFSIX-dps-Cu significantly inhibits CO2 molecules but takes up a large amount of C2H2 (4.57 mmol g(-1)), resulting in a high IAST selectivity of 1787 for C2H2/CO2 separation. The multiple host-guest interactions for C2H2 in both inter- and intralayer cavities are further revealed by dispersion-corrected density functional theory and grand canonical Monte Carlo simulations. Dynamic breakthrough experiments show a clean C2H2/CO2 separation with a high C2H2 working capacity of 2.48 mmol g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 200, "DOI": "10.1038/s41467-021-27929-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27929-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741852200057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XF; Zhou, D; Qin, XY; Lin, K; Kang, FY; Li, BH; Shanmukaraj, D; Rojo, T; Armand, M; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiaofu; Zhou, Dong; Qin, Xianying; Lin, Kui; Kang, Feiyu; Li, Baohua; Shanmukaraj, Devaraj; Rojo, Teofilo; Armand, Michel; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A room-temperature sodium-sulfur battery with high capacity and stable cycling performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-temperature sodium-sulfur batteries operating at 300-350 degrees C have been commercially applied for large-scale energy storage and conversion. However, the safety concerns greatly inhibit their widespread adoption. Herein, we report a room-temperature sodium-sulfur battery with high electrochemical performances and enhanced safety by employing a cocktail optimized electrolyte system, containing propylene carbonate and fluoroethylene carbonate as co-solvents, highly concentrated sodium salt, and indium triiodide as an additive. As verified by first-principle calculation and experimental characterization, the fluoroethylene carbonate solvent and high salt concentration not only dramatically reduce the solubility of sodium polysulfides, but also construct a robust solid-electrolyte interface on the sodium anode upon cycling. Indium triiodide as redox mediator simultaneously increases the kinetic transformation of sodium sulfide on the cathode and forms a passivating indium layer on the anode to prevent it from polysulfide corrosion. The as-developed sodium-sulfur batteries deliver high capacity and long cycling stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3870, "DOI": "10.1038/s41467-018-06443-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06443-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445329000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, ZM; Chen, QL; Zhang, JW; Li, HQ; Jiang, YQ; Shen, SY; Fu, G; Lu, BA; Xie, ZX; Zheng, LS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Zhenming; Chen, Qiaoli; Zhang, Jiawei; Li, Huiqi; Jiang, Yaqi; Shen, Shouyu; Fu, Gang; Lu, Bang-an; Xie, Zhaoxiong; Zheng, Lansun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum-nickel alloy excavated nullo-multipods with hexagonal close-packed structure and superior activity towards hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystal phase regulations may endow materials with enhanced or new functionalities. However, syntheses of noble metal-based allomorphic nullomaterials are extremely difficult, and only a few successful examples have been found. Herein, we report the discovery of hexagonal close-packed Pt-Ni alloy, despite the fact that Pt-Ni alloys are typically crystallized in face-centred cubic structures. The hexagonal close-packed Pt-Ni alloy nullo-multipods are synthesized via a facile one-pot solvothermal route, where the branches of nullo-multipods take the shape of excavated hexagonal prisms assembled by six nullosheets of 2.5 nm thickness. The hexagonal close-packed Pt-Ni excavated nullo-multipods exhibit superior catalytic property towards the hydrogen evolution reaction in alkaline electrolyte. The overpotential is only 65mV versus reversible hydrogen electrode at a current density of 10 mA cm(-2), and the mass current density reaches 3.03 mA mu gPt(-1) at -70 mV versus reversible hydrogen electrode, which outperforms currently reported catalysts to the best of our knowledge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15131, "DOI": "10.1038/ncomms15131", "DOI Link": "http://dx.doi.org/10.1038/ncomms15131", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400113300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-phonon interactions from first principles", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article reviews the theory of electron-phonon interactions in solids from the point of view of ab initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive nonempirical calculations have become feasible only during the past two decades. Today it is possible to calculate from first principles many materials properties related to the electron-phonon interaction, including the critical temperature of conventional superconductors, the carrier mobility in semiconductors, the temperature dependence of optical spectra in direct and indirect-gap semiconductors, the relaxation rates of photoexcited carriers, the electron mass renormalization in angle-resolved photoelectron spectra, and the nonadiabatic corrections to phonon dispersion relations. In this article a review of the theoretical and computational framework underlying modern electron-phonon calculations from first principles as well as landmark investigations of the electron-phonon interaction in real materials is given. The first part of the article summarizes the elementary theory of electron-phonon interactions and their calculations based on density-functional theory. The second part discusses a general field-theoretic formulation of the electron-phonon problem and establishes the connection with practical first-principles calculations. The third part reviews a number of recent investigations of electron-phonon interactions in the areas of vibrational spectroscopy, photoelectron spectroscopy, optical spectroscopy, transport, and superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1086, "Times Cited, All Databases": 1175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2017, "Volume": 89, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15003, "DOI": "10.1103/RevModPhys.89.015003", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.89.015003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394106600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, RG; Su, XL; Hao, SQ; Zheng, Z; Zhang, M; Xie, HY; Liu, W; Yan, YG; Wolverton, C; Uher, C; Kanatzidis, MG; Tang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Rigui; Su, Xianli; Hao, Shiqiang; Zheng, Zheng; Zhang, Min; Xie, Hongyao; Liu, Wei; Yan, Yonggao; Wolverton, Chris; Uher, Ctirad; Kanatzidis, Mercouri G.; Tang, Xinfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High thermoelectric performance in Bi0.46Sb1.54Te3 nullostructured with ZnTe", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defect engineering and nullo-structuring are the core stratagems for improving thermoelectric properties. In bismuth telluride alloys nullosizing individual crystallites has been extensively studied in efforts to reduce the thermal conductivity, but nullostructuring with second phases has been more challenging. In this study, we demonstrate a thermoelectric figure of merit ZT of 1.4 at 400 K, realized in Zn-containing BiSbTe alloys (specifically Bi0.46Sb1.54Te3) by integrating defect complexity with nullostructuring. We have succeeded in creating nullostructured BiSbTe alloys containing ZnTe nulloprecipitates. We present a melt-spinning-based synthesis that forms in situ ZnTe nulloprecipitates to produce an extremely low lattice thermal conductivity of approximate to 0.35 W m(-1) K-1 at 400 K, approaching the amorphous limit in the Bi2-xSbxTe3 system, while preserving the high power factor of Bi0.46Sb1.54Te3. These samples show excellent repeatability and thermal stability at temperatures up to 523 K. DFT calculations and experimental results show that Zn is inclined to form dual site defects, including two substitutional defects Zn-Bi/Sb and a Te vacancy, to achieve full charge compensation, which was further explicitly corroborated by Positron annihilation measurement. The strong enhancement of thermoelectric properties was validated in a thermoelectric module fabricated with the melt-spun p-legs (ZnTe-nullostructured BiSbTe) and zone-melt n-legs (conventional BiTeSe) which achieved a thermoelectric conversion efficiency of 5.0% when subjected to a temperature gradient of 250 K, representing about 40% improvement compared with a commercial zone-melt-based module. The results presented here represent a significant step forward for applications in thermoelectric power generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2018, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1520, "End Page": 1535, "Article Number": null, "DOI": "10.1039/c8ee00290h", "DOI Link": "http://dx.doi.org/10.1039/c8ee00290h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435351000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, DF; Zhao, ZJ; Zhang, G; Yang, PP; Li, LL; Gao, H; Liu, SH; Chang, X; Chen, S; Wang, T; Ozin, GA; Liu, ZP; Gong, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Dongfang; Zhao, Zhi-Jian; Zhang, Gong; Yang, Piaoping; Li, Lulu; Gao, Hui; Liu, Sihang; Chang, Xin; Chen, Sai; Wang, Tuo; Ozin, Geoffrey A.; Liu, Zhipan; Gong, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The nature of active sites for carbon dioxide electroreduction over oxide-derived copper catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The active sites for CO2 electroreduction (CO2R) to multi-carbon (C2+) products over oxide-derived copper (OD-Cu) catalysts are under long-term intense debate. This paper describes the atomic structure motifs for product-specific active sites on OD-Cu catalysts in CO2R. Herein, we describe realistic OD-Cu surface models by simulating the oxide-derived process via the molecular dynamic simulation with neural network (NN) potential. After the analysis of over 150 surface sites through NN potential based high-throughput testing, coupled with density functional theory calculations, three square-like sites for C-C coupling are identified. Among them, Sigma 3 grain boundary like planar-square sites and convex-square sites are responsible for ethylene production while step-square sites, i.e. n(111)x(100), favor alcohols generation, due to the geometric effect for stabilizing acetaldehyde intermediates and destabilizing Cu-O interactions, which are quantitatively demonstrated by combined theoretical and experimental results. This finding provides fundamental insights into the origin of activity and selectivity over Cu-based catalysts and illustrates the value of our research framework in identifying active sites for complex heterogeneous catalysts. The active sites over oxide-derived copper (OD-Cu) catalysts for CO2 electroreduction are unclear. Here, the authors show atom-level product-specific active sites on OD-Cu surface models, where planar and convex square sites are responsible for ethylene while the step square site favours alcohols generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 395, "DOI": "10.1038/s41467-020-20615-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20615-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609615100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, J; Fan, R; Wu, HQ; Yao, HH; Yan, YJ; Liu, JM; Ran, L; Sun, ZF; Yi, LZ; Dang, L; Gan, PP; Zheng, P; Yang, TL; Zhang, Y; Tang, T; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jun; Fan, Rong; Wu, Huiqiong; Yao, Honghui; Yan, Yujie; Liu, Jiamiao; Ran, Lu; Sun, Zhifang; Yi, Lunzhao; Dang, Li; Gan, Pingping; Zheng, Piao; Yang, Tilong; Zhang, Yi; Tang, Tao; Wang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directed self-assembly of herbal small molecules into sustained release hydrogels for treating neural inflammation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-assembling natural drug hydrogels formed without structural modification and able to act as carriers are of interest for biomedical applications. A lack of knowledge about natural drug gels limits there current application. Here, we report on rhein, a herbal natural product, which is directly self-assembled into hydrogels through noncovalent interactions. This hydrogel shows excellent stability, sustained release and reversible stimuli-responses. The hydrogel consists of a three-dimensional nullofiber network that prevents premature degradation. Moreover, it easily enters cells and binds to toll-like receptor 4. This enables rhein hydrogels to significantly dephosphorylate I kappa B alpha, inhibiting the nuclear translocation of p65 at the NF kappa B signalling pathway in lipopolysaccharide-induced BV2 microglia. Subsequently, rhein hydrogels alleviate neuroinflammation with a long-lasting effect and little cytotoxicity compared to the equivalent free-drug in vitro. This study highlights a direct self-assembly hydrogel from natural small molecule as a promising neuroinflammatory therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604, "DOI": "10.1038/s41467-019-09601-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09601-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463695400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jang, JW; Du, C; Ye, YF; Lin, YJ; Yao, XH; Thorne, J; Liu, E; McMahon, G; Zhu, JF; Javey, A; Guo, JH; Wang, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jang, Ji-Wook; Du, Chun; Ye, Yifan; Lin, Yongjing; Yao, Xiahui; Thorne, James; Liu, Erik; McMahon, Gregory; Zhu, Junfa; Javey, Ali; Guo, Jinghua; Wang, Dunwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling unassisted solar water splitting by iron oxide and silicon", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical (PEC) water splitting promises a solution to the problem of large-scale solar energy storage. However, its development has been impeded by the poor performance of photoanodes, particularly in their capability for photovoltage generation. Many examples employing photovoltaic modules to correct the deficiency for unassisted solar water splitting have been reported to-date. Here we show that, by using the prototypical photoanode material of haematite as a study tool, structural disorders on or near the surfaces are important causes of the low photovoltages. We develop a facile re-growth strategy to reduce surface disorders and as a consequence, a turn-on voltage of 0.45V (versus reversible hydrogen electrode) is achieved. This result permits us to construct a photoelectrochemical device with a haematite photoanode and Si photocathode to split water at an overall efficiency of 0.91%, with NiFeOx and TiO2/Pt overlayers, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 481, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7447, "DOI": "10.1038/ncomms8447", "DOI Link": "http://dx.doi.org/10.1038/ncomms8447", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357176800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sopaj, F; Rodrigo, MA; Oturan, N; Podvorica, FI; Pinson, J; Oturan, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sopaj, Flamur; Rodrigo, Manuel A.; Oturan, Nihal; Podvorica, Fetah I.; Pinson, Jean; Oturan, Mehmet A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of the anode materials on the electrochemical oxidation efficiency. Application to oxidative degradation of the pharmaceutical amoxicillin", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the electro-oxidation capacities of several electrode materials such as carbon-felt, carbon-fiber, carbon-graphite, platinum, lead dioxide, dimensionally stable anode (DSA), (Ti/RuO2-IrO2), and BDD (Boron-Doped Diamond) were tested for the destruction of the antibiotic amoxicillin (AMX) in aqueous medium. BDD anode was more efficient than DSA to oxidize and mineralize totally AMX in water. Moreover, for BDD electrode we obtained very high electrolysis efficiency for the initial stage of the process even for high current densities, which is an indirect indicator that mediated oxidation is involved in, the whole degradation of AMX. Considering the oxidation reactions under mass transfer control, the apparent rate constants for oxidation of AMX by hydroxyl radicals were determined for all anode materials tested. The data obtained shows that in all cases, the oxidation rate constants depended mainly on applied current densities for each material. Platinum showed a relatively good oxidation behavior compared to carbon-fiber and carbon-graphite. DSA was found to be the less efficient electrode for oxidation of AMX. BDD was evidenced as the best anode material at high current densities due to the formation of large amounts of hydroxyl radicals and of other different oxidants such as hydrogen peroxide, ozone and persulfates that contribute to the enhancement of oxidation and mineralization of AMX via mediated oxidation. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2015, "Volume": 262, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 286, "End Page": 294, "Article Number": null, "DOI": "10.1016/j.cej.2014.09.100", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2014.09.100", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347577700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, T; Zheng, Y; Li, LH; Cowie, BCC; Gunzelmann, D; Qiao, SZ; Huang, SM; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Tan; Zheng, Yao; Li, Lu Hua; Cowie, Bruce C. C.; Gunzelmann, Daniel; Qiao, Shi Zhang; Huang, Shaoming; Chen, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Active Sites for Oxygen Reduction Reaction on Nitrogen-Doped Multilayer Graphene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active sites and the catalytic mechanism of nitrogen-doped graphene in an oxygen reduction reaction (ORR) have been extensively studied but are still inconclusive, partly due to the lack of an experimental method that can detect the active sites. It is proposed in this report that the active sites on nitrogen-doped graphene can be determined via the examination of its chemical composition change before and after ORR. Synchrotron-based X-ray photoelectron spectroscopy analyses of three nitrogen-doped multilayer graphene samples reveal that oxygen reduction intermediate OH(ads), which should chemically attach to the active sites, remains on the carbon atoms neighboring pyridinic nitrogen after ORR. In addition, a high amount of the OH(ads) attachment after ORR corresponds to a high catalytic efficiency and vice versa. These pinpoint that the carbon atoms dose to pyridinic nitrogen are the main active sites among the different nitrogen doping configurations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6856, "End Page": 6862, "Article Number": null, "DOI": "10.1021/nn501506p", "DOI Link": "http://dx.doi.org/10.1021/nn501506p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339463100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Q; Occhialini, CA; Ergeçen, E; Ilyas, B; Amoroso, D; Barone, P; Kapeghian, J; Watanabe, K; Taniguchi, T; Botana, AS; Picozzi, S; Gedik, N; Comin, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Qian; Occhialini, Connor A.; Ergecen, Emre; Ilyas, Batyr; Amoroso, Danila; Barone, Paolo; Kapeghian, Jesse; Watanabe, Kenji; Taniguchi, Takashi; Botana, Antia S.; Picozzi, Silvia; Gedik, Nuh; Comin, Riccardo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for a single-layer van der Waals multiferroic", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiferroic materials have attracted wide interest because of their exceptional static(1-3) and dynamical(4-6) magnetoelectric properties. In particular, type-II multiferroics exhibit an inversion-symmetry-breaking magnetic order that directly induces ferroelectric polarization through various mechanisms, such as the spin-current or the inverse Dzyaloshinskii-Moriya effect(3,7). This intrinsic coupling between the magnetic and dipolar order parameters results in high-strength magnetoelectric effects(3,8). Two-dimensional materials possessing such intrinsic multiferroic properties have been long sought for to enable the harnessing of magnetoelectric coupling in nulloelectronic devices(1,9,10). Here we report the discovery of type-II multiferroic order in a single atomic layer of the transition-metal-based van der Waals material NiI2. The multiferroic state of NiI2 is characterized by a proper-screw spin helix with given handedness, which couples to the charge degrees of freedom to produce a chirality-controlled electrical polarization. We use circular dichroic Raman measurements to directly probe the magneto-chiral ground state and its electromagnon modes originating from dynamic magnetoelectric coupling. Combining birefringence and second-harmonic-generation measurements with theoretical modelling and simulations, we detect a highly anisotropic electronic state that simultaneously breaks three-fold rotational and inversion symmetry, and supports polar order. The evolution of the optical signatures as a function of temperature and layer number surprisingly reveals an ordered magnetic polar state that persists down to the ultrathin limit of monolayer NiI2. These observations establish NiI2 and transition metal dihalides as a new platform for studying emergent multiferroic phenomena, chiral magnetic textures and ferroelectricity in the two-dimensional limit. Multiple complementary optical signatures confirm the persistence of ferroelectricity and inversion-symmetry-breaking magnetic order down to monolayer NiI2, introducing the physics of type-II multiferroics into the area of van der Waals materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2022, "Volume": 602, "Issue": 7898, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 601, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04337-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04337-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760423100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SF; Ji, X; Yue, J; Hou, S; Wang, PF; Cui, CY; Chen, J; Shao, BW; Li, JR; Han, FD; Tu, JP; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Sufu; Ji, Xiao; Yue, Jie; Hou, Singyuk; Wang, Pengfei; Cui, Chunyu; Chen, Ji; Shao, Bowen; Li, Jingru; Han, Fudong; Tu, Jiangping; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Interfacial-Energy Interphase Promoting Safe Lithium Metal Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering a stable solid electrolyte interphase (SEI) is critical for suppression of lithium dendrites. However, the formation of a desired SEI by formulating electrolyte composition is very difficult due to complex electrochemical reduction reactions. Here, instead of trial-and-error of electrolyte composition, we design a Li-11 wt % Sr alloy anode to form a SrF2-rich SEI in fluorinated electrolytes. Density functional theory (DFT) calculation and experimental characterization demonstrate that a SrF2-rich SEI has a large interfacial energy with Li metal and a high mechanical strength, which can effectively suppress the Li dendrite growth by simultaneously promoting the lateral growth of deposited Li metal and the SEI stability. The Li-Sr/Cu cells in 2 M LiFSI-DME show an outstanding Li plating/stripping Coulombic efficiency of 99.42% at 1 mA cm(-2) with a capacity of 1 mAh cm(-2) and 98.95% at 3 mA cm(-2) with a capacity of 2 mAh cm(-2), respectively. The symmetric Li-Sr/Li-Sr cells also achieve a stable electrochemical performance of 180 cycles at an extremely high current density of 30 mA cm(-2) with a capacity of 1 mAh cm(-2). When paired with LiFePO4 (LFP) and LiNi0.8Co0.1Mn0.1O2 (NCM811) cathodes, Li-Sr/LFP cells in 2 M LiFSI-DME electrolytes and Li-Sr/NMC811 cells in 1 M LiPF6 in FEC:FEMC:HFE electrolytes also maintain excellent capacity retention. Designing SEIs by regulating Li-metal anode composition opens up a new and rational avenue to suppress Li dendrites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2020, "Volume": 142, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2438, "End Page": 2447, "Article Number": null, "DOI": "10.1021/jacs.9b11750", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b11750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512222700050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lum, Y; Ager, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lum, Yanwei; Ager, Joel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for product-specific active sites on oxide-derived Cu catalysts for electrochemical CO2 reduction", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide electroreduction in aqueous media using Cu catalysts can generate many different C-2 and C-3 products, which leads to the question whether all products are generated from the same types of active sites or if product-specific active sites are responsible for certain products. Here, by reducing mixtures of (CO)-C-13 and (CO2)-C-12, we show that oxide-derived Cu catalysts have three different types of active sites for C-C coupled products, one that produces ethanol and acetate, another that produces ethylene and yet another that produces 1-propanol. In contrast, we do not find evidence of product-specific sites on polycrystalline Cu and oriented (100) and (111) Cu surfaces. Analysis of the isotopic composition of the products leads to the prediction that the adsorption energy of *COOH (the product of the first step of CO2 reduction) may be a descriptor for the product selectivity of a given active site. These new insights should enable highly selective catalysts to be developed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 86, "End Page": 93, "Article Number": null, "DOI": "10.1038/s41929-018-0201-7", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0201-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455845400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SM; Shi, WX; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Simin; Shi, Wenxiong; Wang, Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Locking volatile organic molecules by subnullometer inorganic nullowire-based organogels", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The intermolecular forces among volatile organic molecules are usually weaker than water, making them more difficult to absorb. We prepared alkaline earth cations-bridged polyoxometalate nulloclusters subnullometer nullowires through a facile room-temperature reaction. The nullowires can form three-dimensional networks, trapping more than 10 kinds of volatile organic liquids effectively with the mass fraction of nullowires as low as 0.53%. A series of freestanding, elastic, and stable organogels were obtained. We prepared gels that encapsulate organic liquids at the kilogram scale. Through removing solvents in gels by means of distillation and centrifugation, the nullowires can be recycled more than 10 times. This method could be applied to the effective trapping and recovery of organic liquids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 377, "Issue": 6601, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 100, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm7574", "DOI Link": "http://dx.doi.org/10.1126/science.abm7574", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822009800050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gillett, AJ; Privitera, A; Dilmurat, R; Karki, A; Qian, DP; Pershin, A; Londi, G; Myers, WK; Lee, J; Yuan, J; Ko, SJ; Riede, MK; Gao, F; Bazan, GC; Rao, A; Nguyen, TQ; Beljonne, D; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gillett, Alexander J.; Privitera, Alberto; Dilmurat, Rishat; Karki, Akchheta; Qian, Deping; Pershin, Anton; Londi, Giacomo; Myers, William K.; Lee, Jaewon; Yuan, Jun; Ko, Seo-Jin; Riede, Moritz K.; Gao, Feng; Bazan, Guillermo C.; Rao, Akshay; Thuc-Quyen Nguyen; Beljonne, David; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of charge recombination to triplet excitons in organic solar cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of non-fullerene acceptors (NFAs) in organic solar cells has led to power conversion efficiencies as high as 18%(1). However, organic solar cells are still less efficient than inorganic solar cells, which typically have power conversion efficiencies of more than 20%(2). A key reason for this difference is that organic solar cells have low open-circuit voltages relative to their optical bandgaps(3), owing to non-radiative recombination(4). For organic solar cells to compete with inorganic solar cells in terms of efficiency, non-radiative loss pathways must be identified and suppressed. Here we show that in most organic solar cells that use NFAs, the majority of charge recombination under open-circuit conditions proceeds via the formation of non-emissive NFA triplet excitons; in the benchmark PM6:Y6 blend(5), this fraction reaches 90%, reducing the open-circuit voltage by 60 mV. We prevent recombination via this non-radiative channel by engineering substantial hybridization between the NFA triplet excitons and the spin-triplet charge-transfer excitons. Modelling suggests that the rate of back charge transfer from spin-triplet charge-transfer excitons to molecular triplet excitons may be reduced by an order of magnitude, enabling re-dissociation of the spin-triplet charge-transfer exciton. We demonstrate NFA systems in which the formation of triplet excitons is suppressed. This work thus provides a design pathway for organic solar cells with power conversion efficiencies of 20% or more. A substantial pathway for energy loss in organic solar cells may be suppressed by engineering hybridization between non-fullerene acceptor triplet excitons and spin-triplet charge transfer excitons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2021, "Volume": 597, "Issue": 7878, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 666, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03840-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03840-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701996800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, ZL; Zhang, XY; Wang, HL; Huang, C; Sun, HD; Dong, MY; Ji, L; An, ZF; Yu, T; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Zongliang; Zhang, Xiayu; Wang, Hailan; Huang, Cheng; Sun, Haodong; Dong, Mengyang; Ji, Lei; An, Zhongfu; Yu, Tao; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wide-range lifetime-tunable and responsive ultralong organic phosphorescent multi-host/guest system", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational lifetime-tuning strategy of ultralong organic phosphorescence is extraordinarily important but seldom reported. Herein, a series of multi-host/guest ultralong organic phosphorescence materials with dynamic lifetime-tuning properties were reported. By doping a non-room-temperature phosphorescence emitter into various solid host matrices with continuously reduced triplet energy levels, a wide-range lifetime (from 3.9ms gradually to 376.9ms) phosphorescence with unchangeable afterglow colors were realized. Further studies revealed that the host matrices were employed to afford rigid environment and proper energy levels to generate and stabilize the long-live triplet excitons. Meanwhile, these multi-host/guest ultralong organic phosphorescence materials also exhibited excitation-dependent phosphorescence and temperature-controlled afterglow on/off switching properties, according to the virtue of various photophysical and thermal properties of the host matrices. This work provides a guiding strategy to realize lifetime-tuning ultralong organic phosphorescence with lifetime-order encoding characteristic towards widespread applications in time-resolved information displaying, higher-level security protection, and dynamic multi-dimensional anti-counterfeiting. Though high efficiency has been realized for ultralong organic phosphorescence (UOP) materials, realizing wide ranging and tunable lifetime in these materials remains a challenge. Here, the authors report a multi-host/guest UOP system with wide-ranging tunable lifetime via changing the host matrix.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3522, "DOI": "10.1038/s41467-021-23742-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23742-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663747800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, H; Zhao, Y; Bai, YM; Li, FM; Zhang, Y; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Hao; Zhao, Yue; Bai, Yimin; Li, Fumin; Zhang, Ying; Chen, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive Metal-Organic Frameworks with Extra Metallic Sites as an Efficient Electrocatalyst for the Hydrogen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The 2D conductive metal-organic frameworks (MOFs) are expected to be an ideal electrocatalyst due to their high utilization of metal atoms. Exploring a new conjugated ligand with extra active metallic center can further boost the structural advantages of conductive MOFs. In this work, hexaiminohexaazatrinaphthalene (HAHATN) is employed as a conjugated ligand to construct bimetallic sited conductive MOFs (M2(3)(M1(3)center dot HAHATN)(2)) with an extra M-N-2 moiety. Density functional theory (DFT) calculations demonstrate that the 2D conjugated framework renders M2(3)(M1(3)center dot HAHATN)(2) a high electric conductivity with narrow bandgap (0.19 eV) for electron transfer and a favorable in-plane porous structure (2.7 nm) for mass transfer. Moreover, the metal atom at the extra M-N-2 moiety has a higher unsaturation degree than that at M-N-4 linkage, resulting in a stronger ability to donate electrons for enhancing electroactivity. These characteristics endow the new conductive MOFs with an enhanced electroactivity for hydrogen evolution reaction (HER) electrocatalysis. Among the series of M2(3)(M1(3)center dot HAHATN)(2) MOF, Ni-3(Ni-3 center dot HAHATN)(2) nullosheets with the optimal structure exhibit a small overpotential of 115 mV at 10 mA cm(-2), low Tafel slope of (45.6 mV dec(-1)), and promising electrocatalytic stability for HER. This work provides an effective strategy for designing conductive MOFs with a favorable structure for electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000012, "DOI": "10.1002/advs.202000012", "DOI Link": "http://dx.doi.org/10.1002/advs.202000012", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519634900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Sun, LY; Zou, MH; Gao, W; Liu, CH; Shang, LR; Gu, ZZ; Zhao, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jie; Sun, Lingyu; Zou, Minhan; Gao, Wei; Liu, Cihui; Shang, Luoran; Gu, Zhongze; Zhao, Yuanjin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired shape-memory graphene film with tunable wettability", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functional materials with specific surface wettability play an important role in a wide variety of areas. Inspired by nature's Nepenthes pitcher plant, we present a novel slippery film with tunable wettability based on a shapememory graphene sponge. The porous graphene sponge coated with shape-memory polymer was used to lock in inert lubricants and construct slippery surfaces to repel different liquids. The superelasticity and high strength, together with good electrical conductivity, of the graphene sponge imparted the graphene/polymer hybrid films with fast recoverable shape-memory properties. Various droplets could slip on the compressed film with a lubricant-covered surface, but the droplets would be pinned when the shape-memory graphene film rebounded due to electrical stimulation, which caused the penetration of the infused lubricant into the pores and the exposure of rough topography film surfaces. The electrothermally dynamic tuning approach was stable and reversible; thus, the shape-memory graphene film was imparted with controlled slippery properties and functions that would be amenable to a variety of applications, such as liquid handling for microplates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700004", "DOI": "10.1126/sciadv.1700004", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406370700043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MX; Zhou, X; Li, YH; Dong, YQ; Meng, JS; Zhang, S; Xia, LB; He, ZZ; Ren, L; Chen, ZW; Zhang, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Muxue; Zhou, Xi; Li, Yunhong; Dong, Yuqing; Meng, Jiashen; Zhang, Shuai; Xia, Linbo; He, Zhaozhi; Ren, Lei; Chen, Zhiwei; Zhang, Xingcai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triple-synergistic MOF-nullozyme for efficient antibacterial treatment", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The abuse of antibiotics makes bacterial infection an increasingly serious global health threat. Reactive oxygen species (ROS) are the ideal alternative antibacterial approach for quick and effective sterilization. Although various antibacterial strategies based on ROS have been developed, many of them are still limited by insufficient antibacterial efficiency. Here, we have developed an acid-enhanced dual-modal antibacterial strategy based on zeolitic imidazolate frameworks-8 (ZIF8) -derived nullozyme. ZIF8, which can release Zn2+, is chosen as the carrier to integrate glucose oxidase (GOx) and gold nulloparticles (Au NPs) which can produce ROS via a cascade catalytic reaction. Thus, the bactericidal capability of ROS and Zn2+ have been integrated. More importantly, gluconic acid, a by-product of the catalytic reaction, can generate an acidic environment to promote both the ROS-producing and Zn2+-releasing, enhancing the overall antibacterial performance further. This triple-synergistic strategy exhibits extraordinary bactericidal ability at a low dosage of 4 mu g/mL (for S. aureus) and 8 mu g/mL (for E. coli), which shows a great potential of MOF-derived nullozyme for efficient bacterial eradication and diverse biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 17, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 289, "End Page": 299, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.01.036", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.01.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788675800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, DW; Zhang, YA; Wu, QS; Xu, R; null, HY; Liu, JF; Yao, JJ; Wang, ZL; Yuan, SJ; Li, Y; Shi, Y; Wang, JL; Ni, ZH; He, L; Miao, F; Song, FQ; Xu, HX; Watanabe, K; Taniguchi, T; Xu, JB; Wang, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Daowei; Zhang, Yuhan; Wu, Qisheng; Xu, Rui; null, Haiyan; Liu, Junfang; Yao, Jianjun; Wang, Zilu; Yuan, Shijun; Li, Yun; Shi, Yi; Wang, Jinlan; Ni, Zhenhua; He, Lin; Miao, Feng; Song, Fengqi; Xu, Hangxun; Watanabe, K.; Taniguchi, T.; Xu, Jian-Bin; Wang, Xinran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional quasi-freestanding molecular crystals for high-performance organic field-effect transistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional atomic crystals are extensively studied in recent years due to their exciting physics and device applications. However, a molecular counterpart, with scalable processability and competitive device performance, is still challenging. Here, we demonstrate that high-quality few-layer dioctylbenzothienobenzothiophene molecular crystals can be grown on graphene or boron nitride substrate via van der Waals epitaxy, with precisely controlled thickness down to monolayer, large-area single crystal, low process temperature and patterning capability. The crystalline layers are atomically smooth and effectively decoupled from the substrate due to weak van der Waals interactions, affording a pristine interface for high-performance organic transistors. As a result, monolayer dioctylbenzothienobenzothiophene molecular crystal field-effect transistors on boron nitride show record-high carrier mobility up to 10 cm(2)V(-1) s(-1) and aggressively scaled saturation voltage similar to 1V. Our work unveils an exciting new class of two-dimensional molecular materials for electronic and optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5162, "DOI": "10.1038/ncomms6162", "DOI Link": "http://dx.doi.org/10.1038/ncomms6162", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343981200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, JW; Sapnik, AF; Bennett, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Jingwei; Sapnik, Adam F.; Bennett, Thomas D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework gels and monoliths", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of metal-organic frameworks (MOFs) has, to date, largely been in the form of crystalline powders. However, interest in different physical morphologies of this class of materials is growing. In this perspective, we provide an overview of the structure, properties and applications of MOF monoliths. In particular, we explore the complex synthetic landscapes associated with MOF crystallization and discuss the synthetic factors leading to the formation of MOF gels, i.e. the precursor to sol-gel MOF monoliths. Finally, we provide our thoughts on the future development of this field, and attempt to highlight the importance of the MOF gel state in the discovery of new functional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2020, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 310, "End Page": 323, "Article Number": null, "DOI": "10.1039/c9sc04961d", "DOI Link": "http://dx.doi.org/10.1039/c9sc04961d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000505529100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, QZ; Dahlqvist, M; Lu, J; Kota, S; Meshkian, R; Halim, J; Palisaitis, J; Hultman, L; Barsoum, MW; Persson, POÅ; Rosen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Quanzheng; Dahlqvist, Martin; Lu, Jun; Kota, Sankalp; Meshkian, Rahele; Halim, Joseph; Palisaitis, Justinas; Hultman, Lars; Barsoum, Michel W.; Persson, Per O. A.; Rosen, Johanna", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of two-dimensional solids is an active area of materials discovery. Research in this area has given us structures spanning graphene to dichalcogenides, and more recently 2D transition metal carbides (MXenes). One of the challenges now is to master ordering within the atomic sheets. Herein, we present a top-down, high-yield, facile route for the controlled introduction of ordered divacancies in MXenes. By designing a parent 3D atomic laminate, (Mo2/3Sc1/3)(2)AlC, with in-plane chemical ordering, and by selectively etching the Al and Sc atoms, we show evidence for 2D Mo1.33C sheets with ordered metal divacancies and high electrical conductivities. At similar to 1,100 F cm(-3), this 2D material exhibits a 65% higher volumetric capacitance than its counterpart, Mo2C, with no vacancies, and one of the highest volumetric capacitance values ever reported, to the best of our knowledge. This structural design on the atomic scale may alter and expand the concept of property-tailoring of 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 601, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14949, "DOI": "10.1038/ncomms14949", "DOI Link": "http://dx.doi.org/10.1038/ncomms14949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400065800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, XC; Liu, Z; Tan, PC; Wang, C; Liu, Y; Feng, HQ; Luo, D; Li, Z; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Xuecheng; Liu, Zhuo; Tan, Puchuan; Wang, Chan; Liu, Ying; Feng, Hongqing; Luo, Dan; Li, Zhou; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial tactile perception smart finger for material identification based on triboelectric sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tactile perception includes the direct response of tactile corpuscles to environmental stimuli and psychological parameters associated with brain recognition. To date, several artificial haptic-based sensing techniques can accurately measure physical stimuli. However, quantifying the psychological parameters of tactile perception to achieve texture and roughness identification remains challenging. Here, we developed a smart finger with surpassed human tactile perception, which enabled accurate identification of material type and roughness through the integration of triboelectric sensing and machine learning. In principle, as each material has different capabilities to gain or lose electrons, a unique triboelectric fingerprint output will be generated when the triboelectric sensor is in contact with the measured object. The construction of a triboelectric sensor array could further eliminate interference from the environment, and the accuracy rate of material identification was as high as 96.8%. The proposed smart finger provides the possibility to impart artificial tactile perception to manipulators or prosthetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2022, "Volume": 8, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabq2521", "DOI": "10.1126/sciadv.abq2521", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abq2521", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836990600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, DD; Yang, HP; Hu, Q; Chen, YQ; Chen, HP; Williams, PT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Dingding; Yang, Haiping; Hu, Qiang; Chen, Yingquan; Chen, Hanping; Williams, Paul T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon nullotubes from post-consumer waste plastics: Investigations into catalyst metal and support material characteristics", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nullotubes were produced from post-consumer mixed waste plastics using a pyrolysis-catalysis process. The catalysts used were Ni-Fe bimetals supported over four different porous materials. The Ni-Fe/MCM41 catalyst displayed the highest catalytic activity for the pyrolysis-catalysis of the waste plastics in terms of carbon material yield at 55.60 wt.%. The order of catalytic activity was Ni-Fe/MCM41> Ni-Fe/ZSM5> Ni-Fe/Beta > Ni-Fe/NKF5, which was closely related to their differences in catalyst pore volume and catalyst reducibility. Formation of Ni-Fe alloy with fine particle dispersion over the Ni-Fe/MCM41 catalyst is suggested to be crucial for the promotion of the decomposition of the carbon precursors and subsequent precipitation to form carbon nullotubes. Whereas, the large catalyst particle size for the Ni-Fe/Beta catalyst led to irregular carbon shapes with a simultaneous decrease in purity and graphitization of the nullotubes. By-product production of hydrogen in large quantities (38.10 mmol H-2 g(plastic)(-1)) could be used as process fuel.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 280, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119413, "DOI": "10.1016/j.apcatb.2020.119413", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119413", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572833100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meloni, S; Moehl, T; Tress, W; Franckevicius, M; Saliba, M; Lee, YH; Gao, P; Nazeeruddin, MK; Zakeeruddin, SM; Rothlisberger, U; Graetzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meloni, Simone; Moehl, Thomas; Tress, Wolfgang; Franckevicius, Marius; Saliba, Michael; Lee, Yong Hui; Gao, Peng; Nazeeruddin, Mohammad Khaja; Zakeeruddin, Shaik Mohammed; Rothlisberger, Ursula; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic polarization-induced current-voltage hysteresis in CH3NH3PbX3 perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CH3NH3PbX3 (MAPbX(3)) perovskites have attracted considerable attention as absorber materials for solar light harvesting, reaching solar to power conversion efficiencies above 20%. In spite of the rapid evolution of the efficiencies, the understanding of basic properties of these semiconductors is still ongoing. One phenomenon with so far unclear origin is the so-called hysteresis in the current-voltage characteristics of these solar cells. Here we investigate the origin of this phenomenon with a combined experimental and computational approach. Experimentally the activation energy for the hysteretic process is determined and compared with the computational results. First-principles simulations show that the timescale for MA(+) rotation excludes a MA-related ferroelectric effect as possible origin for the observed hysteresis. On the other hand, the computationally determined activation energies for halide ion (vacancy) migration are in excellent agreement with the experimentally determined values, suggesting that the migration of this species causes the observed hysteretic behaviour of these solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 630, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10334, "DOI": "10.1038/ncomms10334", "DOI Link": "http://dx.doi.org/10.1038/ncomms10334", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371130800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, SJ; Hao, SY; Huang, ZN; Yuan, YF; Han, S; Lei, LC; Zhang, XW; Shahbazian-Yassar, R; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Shaojie; Hao, Shaoyun; Huang, Zhennull; Yuan, Yifei; Han, Song; Lei, Lecheng; Zhang, Xingwang; Shahbazian-Yassar, Reza; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of high-entropy alloy nulloparticles on supports by the fast moving bed pyrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloy nulloparticles (HEA-NPs) are important class of materials with significant technological potential. However, the strategies for synthesizing uniformly dispersed HEA-NPs on granular supports such as carbon materials, gamma -Al2O3, and zeolite, which is vital to their practical applications, are largely unexplored. Herein, we present a fast moving bed pyrolysis strategy to immobilize HEA-NPs on granular supports with a narrow size distribution of 2nm up to denary (MnCoNiCuRhPdSnIrPtAu) HEA-NPs at 923K. Fast moving bed pyrolysis strategy ensures the mixed metal precursors rapidly and simultaneously pyrolyzed at high temperatures, resulting in nuclei with a small size. The representative quinary (FeCoPdIrPt) HEA-NPs exhibit high stability (150h) toward hydrogen evolution reaction with high mass activity, which is 26 times higher than the commercial Pt/C at an overpotential of 100mV. Our strategy provides an improved methodology for synthesizing HEA-NPs on various supports. The large-scale application of extremely small, high-entropy alloy nulloparticles is limited by the phase separation and immobilization. Here, the authors develop a general method of fast-moving bed pyrolysis, uniformly dispersing high-entropy alloy nulloparticles on various granular supports.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2016, "DOI": "10.1038/s41467-020-15934-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15934-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558822900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Braun, JL; Rost, CM; Lim, M; Giri, A; Olson, DH; Kotsonis, GN; Stan, G; Brenner, DW; Maria, JP; Hopkins, PE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Braun, Jeffrey L.; Rost, Christina M.; Lim, Mina; Giri, Ashutosh; Olson, David H.; Kotsonis, George N.; Stan, Gheorghe; Brenner, Donald W.; Maria, Jon-Paul; Hopkins, Patrick E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Induced Disorder Controls the Thermal Conductivity of Entropy-Stabilized Oxides", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manipulating a crystalline material's configurational entropy through the introduction of unique atomic species can produce novel materials with desirable mechanical and electrical properties. From a thermal transport perspective, large differences between elemental properties such as mass and interatomic force can reduce the rate at which phonons carry heat and thus reduce the thermal conductivity. Recent advances in materials synthesis are enabling the fabrication of entropy-stabilized ceramics, opening the door for understanding the implications of extreme disorder on thermal transport. Measuring the structural, mechanical, and thermal properties of single-crystal entropy-stabilized oxides, it is shown that local ionic charge disorder can effectively reduce thermal conductivity without compromising mechanical stiffness. These materials demonstrate similar thermal conductivities to their amorphous counterparts, in agreement with the theoretical minimum limit, resulting in this class of material possessing the highest ratio of elastic modulus to thermal conductivity of any isotropic crystal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 30, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805004, "DOI": "10.1002/adma.201805004", "DOI Link": "http://dx.doi.org/10.1002/adma.201805004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453926000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Shen, W; Jin, HY; Xu, J; Xi, PX; Dong, JC; Zheng, Y; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hao; Shen, Wei; Jin, Huanyu; Xu, Jun; Xi, Pinxian; Dong, Juncai; Zheng, Yao; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Alkaline Seawater Electrolysis with Anomalous Chloride Promoted Oxygen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A highly selective and durable oxygen evolution reaction (OER) electrocatalyst is the bottleneck for direct seawater splitting because of side reactions primarily caused by chloride ions (Cl-). Most studies about OER catalysts in seawater focus on the repulsion of the Cl- to reduce its negative effects. Herein, we demonstrate that the absorption of Cl- on the specific site of a popular OER electrocatalyst, nickel-iron layered double hydroxide (NiFe LDH), does not have a significant negative impact; rather, it is beneficial for its activity and stability enhancement in natural seawater. A set of in situ characterization techniques reveals that the adsorption of Cl- on the desired Fe site suppresses Fe leaching, and creates more OER-active Ni sites, improving the catalyst's long-term stability and activity simultaneously. Therefore, we achieve direct alkaline seawater electrolysis for the very first time on a commercial-scale alkaline electrolyser (AE, 120 cm2 electrode area) using the NiFe LDH anode. The new alkaline seawater electrolyser exhibits a reduction in electricity consumption by 20.7 % compared to the alkaline purified water-based AE using commercial Ni catalyst, achieving excellent durability for 100 h at 200 mA cm-2. An anomalous Cl--promoted oxygen evolution reaction (OER) mechanism with a typical catalyst, nickel-iron layered double hydroxide (NiFe-LDH), is proposed. First, both Fe leaching and active lattice oxygen are suppressed by the adsorption of Cl- on desired Fe sites, which improves the catalyst's long-term stability. Second, more high-valency OER-active Ni sites are created, thus increasing the activity.+image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 13", "Publication Year": 2023, "Volume": 62, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202311674", "DOI Link": "http://dx.doi.org/10.1002/anie.202311674", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078952100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, R; Guo, JH; Zhang, XR; Waterhouse, GIN; Han, ZJ; Zhao, YX; Shang, L; Zhou, C; Jiang, L; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Run; Guo, Jiahao; Zhang, Xuerui; Waterhouse, Geoffrey I. N.; Han, Zhaojun; Zhao, Yunxuan; Shang, Lu; Zhou, Chao; Jiang, Lei; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient wettability-controlled electroreduction of CO2 to CO at Au/C interfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical CO2 reduction reaction (CO2RR) represents a very promising future strategy for synthesizing carbon-containing chemicals in a more sustainable way. In spite of great progress in electrocatalyst design over the last decade, the critical role of wettability-controlled interfacial structures for CO2RR remains largely unexplored. Here, we systematically modify the structure of gas-liquid-solid interfaces over a typical Au/C gas diffusion electrode through wettability modification to reveal its contribution to interfacial CO2 transportation and electroreduction. Based on confocal laser scanning microscopy measurements, the Cassie-Wenzel coexistence state is demonstrated to be the ideal three phase structure for continuous CO2 supply from gas phase to Au active sites at high current densities. The pivotal role of interfacial structure for the stabilization of the interfacial CO2 concentration during CO2RR is quantitatively analysed through a newly-developed in-situ fluorescence electrochemical spectroscopic method, pinpointing the necessary CO2 mass transfer conditions for CO2RR operation at high current densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3028, "DOI": "10.1038/s41467-020-16847-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16847-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558685500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, YP; Dong, Y; Jiang, H; Wang, ZJ; Cao, ZQ; Guo, S; Wang, TM; Li, TJ; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yiping; Dong, Yong; Jiang, Hui; Wang, Zhijun; Cao, Zhiqiang; Guo, Sheng; Wang, Tongmin; Li, Tingju; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promising properties and future trend of eutectic high entropy alloys", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Eutectic high-entropy alloys (EHEAs), as a sub-group of high-entropy alloys (HEAs), are becoming a new research hotspot in the metallic materials community because of their excellent castability, fine and uniform microstructures even in the as-cast state, high strength, and good ductility. Some of the EHEAs have shown promising potentials for industrial applications. Here, the history, interesting solidification microstructure and mechanical properties, and the design strategy of EHEAs are reviewed, and their future prospects are outlined. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 187, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 202, "End Page": 209, "Article Number": null, "DOI": "10.1016/j.scriptamat.2020.06.022", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2020.06.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551272900036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ulissi, ZW; Tang, MT; Xiao, JP; Liu, XY; Torelli, DA; Karamad, M; Cummins, K; Hahn, C; Lewis, NS; Jaramillo, TF; Chan, KR; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ulissi, Zachary W.; Tang, Michael T.; Xiao, Jianping; Liu, Xinyan; Torelli, Daniel A.; Karamad, Mohammadreza; Cummins, Kyle; Hahn, Christopher; Lewis, Nathan S.; Jaramillo, Thomas F.; Chan, Karen; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-Learning Methods Enable Exhaustive Searches for Active Bimetallic Facets and Reveal Active Site Motifs for CO2 Reduction", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bimetallic catalysts are promising for the most difficult thermal and electrochemical reactions, but modeling the many diverse active sites on polycrystalline samples is an open challenge. We present a general framework for addressing this complexity in a systematic and predictive fashion. Active sites for every stable low-index facet of a bimetallic crystal are enumerated and cataloged, yielding hundreds of possible active sites. The activity of these sites is explored in parallel using a neural-network-based surrogate model to share information between the many density functional theory (DFT) relaxations, resulting in activity estimates with an order of magnitude fewer explicit DFT calculations. Sites with interesting activity were found and provide targets for follow-up calculations. This process was applied to the electrochemical reduction of CO2 on nickel gallium bimetallics and indicated that most facets had similar activity to Ni surfaces, but a few exposed Ni sites with a very favorable on-top CO configuration. This motif emerged naturally from the predictive modeling and represents a class of intermetallic CO2 reduction catalysts. These sites rationalize recent experimental reports of nickel gallium activity and why previous materials screens missed this exciting material. Most importantly these methods suggest that bimetallic catalysts will be discovered by studying facet reactivity and diversity of active sites more systematically.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6600, "End Page": 6608, "Article Number": null, "DOI": "10.1021/acscatal.7b01648", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b01648", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412795700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheikh, S; Shafeie, S; Hu, Q; Ahlström, J; Persson, C; Vesely, J; Zyka, J; Klement, U; Guo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheikh, Saad; Shafeie, Samrand; Hu, Qiang; Ahlstrom, Johan; Persson, Christer; Vesely, Jaroslav; Zyka, Jiri; Klement, Uta; Guo, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloy design for intrinsically ductile refractory high-entropy alloys", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Refractory high-entropy alloys (RHEAs), comprising group IV (Ti, Zr, Hf), V (V, Nb, Ta), and VI (Cr, Mo, W) refractory elements, can be potentially new generation high-temperature materials. However, most existing RHEAs lack room-temperature ductility, similar to conventional refractory metals and alloys. Here, we propose an alloy design strategy to intrinsically ductilize RHEAs based on the electron theory and more specifically to decrease the number of valence electrons through controlled alloying. A new ductile RHEA, Hf0.5Nb0.5Ta0.5Ti1.5Zr, was developed as a proof of concept, with a fracture stress of close to 1 GPa and an elongation of near 20%. The findings here will shed light on the development of ductile RHEAs for ultrahigh-temperature applications in aerospace and power-generation industries. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2016, "Volume": 120, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 164902, "DOI": "10.1063/1.4966659", "DOI Link": "http://dx.doi.org/10.1063/1.4966659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387580600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weidman, MC; Seitz, M; Stranks, SD; Tisdale, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weidman, Mark C.; Seitz, Michael; Stranks, Samuel D.; Tisdale, William A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Tunable Colloidal Perovskite nulloplatelets through Variable Cation, Metal, and Halide Composition", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal perovskite nulloplatelets are a promising class of semiconductor nullomaterials-exhibiting bright luminescence, tunable and spectrally narrow absorption and emission features, strongly confined excitonic states, and facile colloidal synthesis. Here, we demonstrate the high degree of spectral tunability achievable through variation of the cation, metal, and halide composition as well as nulloplatelet thickness. We synthesize nulloplatelets of the form L-2[ABX(3)](n-1)BX4, where L is an organic ligand (octylammonium, butylammonium), A is a monovalent metal or organic molecular cation (cesium, methylammonium, formamidinium), B is a divalent metal cation (lead, tin), X is a halide anion (chloride, bromide, iodide), and n-1 is the number of unit cells in thickness. We show that variation of n, B, and X leads to large changes in the absorption and emission energy, while variation of the A cation leads to only subtle changes but can significantly impact the nulloplatelet stability and photoluminescence quantum yield (with values over 20%). Furthermore, mixed halide nulloplatelets exhibit continuous spectral tunability over a 1.5 eV spectral range, from 2.2 to 3.7 eV. The nulloplatelets have relatively large lateral dimensions (100 nm to 1 pm), which promote self-assembly into stacked superlattice structures the periodicity of which can be adjusted based on the nulloplatelet surface ligand length. These results demonstrate the versatility of colloidal perovskite nulloplatelets as a material platform, with tunability extending from the deep-UV, across the visible, into the near-IR. In particular, the tin-containing nulloplatelets represent a significant addition to the small but increasingly important family of lead- and cadmium-free colloidal semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 539, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7830, "End Page": 7839, "Article Number": null, "DOI": "10.1021/acsnullo.6b03496", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b03496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381959100066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cira, NJ; Benusiglio, A; Prakash, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cira, N. J.; Benusiglio, A.; Prakash, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapour-mediated sensing and motility in two-component droplets", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling the wetting behaviour of liquids on surfaces is important for a variety of industrial applications such as water-repellent coatings(1) and lubrication(2). Liquid behaviour on a surface can range from complete spreading, as in the 'tears of wine' effect(3,4), tominimal wetting as observed on a superhydrophobic lotus leaf(5). Controlling droplet movement is important in microfluidic liquid handling(6), on self-cleaning surfaces(7) and in heat transfer(8). Droplet motion can be achieved by gradients of surface energy(9-13). However, existing techniques require either a large gradient or a carefully prepared surface(9) to overcome the effects of contact line pinning, which usually limit dropletmotion(14). Here we show that two-component droplets of well-chosen miscible liquids such as propylene glycol and water depositedon clean glass are not subject to pinning and cause the motion of neighbouring droplets over a distance. Unlike the canonical predictions for these liquids on a high-energy surface, these droplets do not spread completely but exhibit an apparent contact angle. We demonstrate experimentally and analytically that these droplets are stabilized by evaporation-induced surface tension gradients and that they move in response to the vapour emitted by neighbouring droplets. Our fundamental understanding of this robust system enabled us to construct a wide variety of autonomous fluidic machines out of everyday materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 26", "Publication Year": 2015, "Volume": 519, "Issue": 7544, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 446, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature14272", "DOI Link": "http://dx.doi.org/10.1038/nature14272", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351602800051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JL; Qian, JM; Peng, XB; Xia, BR; Gao, DQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jinli; Qian, Jinmei; Peng, Xuebing; Xia, Baori; Gao, Daqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Etching-Induced Surface Reconstruction of NiMoO4 for Oxygen Evolution Reaction", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational reconstruction of oxygen evolution reaction (OER) pre-catalysts and performance index of OER catalysts are crucial but still challenging for universal water electrolysis. Herein, we develop a double-cation etching strategy to tailor the electronic structure of NiMoO4, where the prepared NiMoO4 nullorods etched by H2O2 reconstruct their surface with abundant cation deficiencies and lattice distortion. Calculation results reveal that the double cation deficiencies can make the upshift of d-band center for Ni atoms and the active sites with better oxygen adsorption capacity. As a result, the optimized sample (NMO-30M) possesses an overpotential of 260 mV at 10 mA cm(-2) and excellent long-term durability of 162 h. Importantly, in situ Raman test reveals the rapid formation of high-oxidation-state transition metal hydroxide species, which can further help to improve the catalytic activity of NiMoO4 in OER. This work highlights the influence of surface remodification and shed some light on activating catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 30, "DOI": "10.1007/s40820-022-01011-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-01011-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911314100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Yu, HF; Wu, J; Deng, SQ; Liu, H; Zhu, LF; Qi, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Liang; Yu, Huifen; Wu, Jie; Deng, Shiqing; Liu, Hui; Zhu, Lifeng; Qi, He; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large Energy Capacitive High-Entropy Lead-Free Ferroelectrics", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced lead-free energy storage ceramics play an indispensable role in next-generation pulse power capacitors market. Here, an ultrahigh energy storage density of similar to 13.8 J cm(-3) and a large efficiency of similar to 82.4% are achieved in high-entropy lead-free relaxor ferroelectrics by increasing configuration entropy, named high-entropy strategy, realizing nearly ten times growth of energy storage density compared with low-entropy material. Evolution of energy storage performance and domain structure with increasing configuration entropy is systematically revealed for the first time. The achievement of excellent energy storage properties should be attributed to the enhanced random field, decreased nullodomain size, strong multiple local distortions, and improved breakdown field. Furthermore, the excellent frequency and fatigue stability as well as charge/discharge properties with superior thermal stability are also realized. The significantly enhanced comprehensive energy storage performance by increasing configuration entropy demonstrates that high entropy is an effective but convenient strategy to design new high-performance dielectrics, promoting the development of advanced capacitors .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 65, "DOI": "10.1007/s40820-023-01036-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01036-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948771900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vance, ME; Kuiken, T; Vejerano, EP; McGinnis, SP; Hochella, MF; Rejeski, D; Hull, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vance, Marina E.; Kuiken, Todd; Vejerano, Eric P.; McGinnis, Sean P.; Hochella, Michael F., Jr.; Rejeski, David; Hull, Matthew S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullotechnology in the real world: Redeveloping the nullomaterial consumer products inventory", "Source Title": "BEILSTEIN JOURNAL OF nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To document the marketing and distribution of nullo-enabled products into the commercial marketplace, the Woodrow Wilson International Center for Scholars and the Project on Emerging nullotechnologies created the nullotechnology Consumer Products Inventory (CPI) in 2005. The objective of this present work is to redevelop the CPI by leading a research effort to increase the usefulness and reliability of this inventory. We created eight new descriptors for consumer products, including information pertaining to the nullomaterials contained in each product. The project was motivated by the recognition that a diverse group of stakeholders from academia, industry, and state/ federal government had become highly dependent on the inventory as an important resource and bellweather of the pervasiveness of nullotechnology in society. We interviewed 68 nullotechnology experts to assess key information needs. Their answers guided inventory modifications by providing a clear conceptual framework best suited for user expectations. The revised inventory was released in October 2013. It currently lists 1814 consumer products from 622 companies in 32 countries. The Health and Fitness category contains the most products (762, or 42% of the total). Silver is the most frequently used nullomaterial (435 products, or 24%); however, 49% of the products (889) included in the CPI do not provide the composition of the nullomaterial used in them. About 29% of the CPI (528 products) contain nullomaterials suspended in a variety of liquid media and dermal contact is the most likely exposure scenario from their use. The majority (1288 products, or 71%) of the products do not present enough supporting information to corroborate the claim that nullomaterials are used. The modified CPI has enabled crowdsourcing capabilities, which allow users to suggest edits to any entry and permits researchers to upload new findings ranging from human and environmental exposure data to complete life cycle assessments. There are inherent limitations to this type of database, but these modifications to the inventory addressed the majority of criticisms raised in published literature and in surveys of nullotechnology stakeholders and experts. The development of standardized methods and metrics for nullomaterial characterization and labelling in consumer products can lead to greater understanding between the key stakeholders in nullotechnology, especially consumers, researchers, regulators, and industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1345, "Times Cited, All Databases": 1533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1769, "End Page": 1780, "Article Number": null, "DOI": "10.3762/bjnullo.6.181", "DOI Link": "http://dx.doi.org/10.3762/bjnullo.6.181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359834400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SJ; Zhang, X; Tang, YX; Hao, SY; Zheng, SA; Qiao, J; Wang, Z; Wu, LL; Liu, JR; Wang, FL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shijie; Zhang, Xue; Tang, Yunxiang; Hao, Shuyan; Zheng, Sinull; Qiao, Jing; Wang, Zhou; Wu, Lili; Liu, Jiurong; Wang, Fenglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile fabrication of biomass chitosan-derived magnetic carbon aerogels as multifunctional and high-efficiency electromagnetic wave absorption materials", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomass chitosan-derived porous carbon-based materials take the advantage of light weight, adjustable intrinsic conductivity, and environmental friendliness, attracting more attention in the field of electromagnetic compatibility. However, exploring a facile fabrication method to achieve rational structure design and electrical-magnetic coupling for electromagnetic absorption performance enhancement still remains challenging. Here, a unique honeycomb-like porous cobalt/carbon aerogel is fabricated through the directional freezing-drying and carbonization process, and abundant and even-distributed cobalt particles in-situ grow on the carbon skeletons. The aerogel exhibits an impressive electromagnetic wave absorption performance of a-75.8-dB absorption intensity and a-256.9-dB mm-1 specific reflection loss at a low filling content (10%), as well as an 8.53-GHz effective absorption bandwidth. Besides, the aerogel also demonstrates classy radar stealth and thermal insu-lation performance. The eco-friendly, easily fabricated, and high-performance cobalt/carbon aerogel suggests broad application prospects for electromagnetic compatibility and protection, thermal management, and multifarious electron devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2024, "Volume": 216, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118528, "DOI": "10.1016/j.carbon.2023.118528", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.118528", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001092870600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Z; Liao, XB; Sun, CL; Zhao, KN; Ye, DX; Li, JT; Wu, G; Fang, JH; Zhao, HB; Zhang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhe; Liao, Xiaobin; Sun, Congli; Zhao, Kangning; Ye, Daixin; Li, Jiantao; Wu, Gang; Fang, Jianhui; Zhao, Hongbin; Zhang, Jiujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced performance of atomically dispersed dual-site Fe-Mn electrocatalysts through cascade reaction mechanism", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing and excavating single atom catalysts with high-density active sites and long-life durability for energy storage and conversion devices still remain bestially challenges. In this paper, a novel dual-site electro-catalyst with atomically dispersed Fe/Mn-N-x-C dual metal sites embedded in N-doped carbon matrix is successfully designed and synthesized, which exhibits a state-of-the-art oxygen reduction reaction (ORR) activity with a half-wave potential (E-1/2) of 0.88 V (vs. RHE) as well as a superior stability. Besides, the Fe/Mn-N-x-C catalyst reaches a high power density of 208.6 mW cm(-2) and a specific energy density of 825.5 W h kg(-1) when this catalyst is employed in Zn-air battery, which is superior to most of the reported non-precious catalysts. Furthermore, theoretical DFT calculations reveal the excellent performance is induced through a synergic dual-site cascade mechanism, which overcomes the issue of low adsorption energy (E-ads) of *OH on Fe-N-x site, followed by transfer of the *OH to adjacent Mn-N-x sites. As a result, the first three steps during ORR more favored occur on the Fe-N-x sites instead of the Mn sites to generate *OOH and *O intermediates due to the lower energy barriers. This mechanism is further approved by addition of methanol to verify the preferred adsorption of *OH on the Mn-N-x site.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2021, "Volume": 288, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120021, "DOI": "10.1016/j.apcatb.2021.120021", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2021.120021", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632994500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ou, X; Liu, TC; Zhong, WT; Fan, XM; Guo, XY; Huang, XJ; Cao, L; Hu, JH; Zhang, B; Chu, YS; Hu, GR; Lin, Z; Dahbi, M; Alami, J; Amine, K; Yang, CH; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ou, Xing; Liu, Tongchao; Zhong, Wentao; Fan, Xinming; Guo, Xueyi; Huang, Xiaojing; Cao, Liang; Hu, Junhua; Zhang, Bao; Chu, Yong S.; Hu, Guorong; Lin, Zhang; Dahbi, Mouad; Alami, Jones; Amine, Khalil; Yang, Chenghao; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-capacity Ni-rich layered oxides are promising cathode materials for secondary lithium-based battery systems. However, their structural instability detrimentally affects the battery performance during cell cycling. Here, we report an Al/Zr co-doped single-crystalline LiNi0.88Co0.09Mn0.03O2 (SNCM) cathode material to circumvent the instability issue. We found that soluble Al ions are adequately incorporated in the SNCM lattice while the less soluble Zr ions are prone to aggregate in the outer SNCM surface layer. The synergistic effect of Al/Zr co-doping in SNCM lattice improve the Li-ion mobility, relief the internal strain, and suppress the Li/Ni cation mixing upon cycling at high cut-off voltage. These features improve the cathode rate capability and structural stabilization during prolonged cell cycling. In particular, the Zr-rich surface enables the formation of stable cathode-electrolyte interphase, which prevent SNCM from unwanted reactions with the non-aqueous fluorinated liquid electrolyte solution and avoid Ni dissolution. To prove the practical application of the Al/Zr co-doped SNCM, we assembled a 10.8 Ah pouch cell (using a 100 mu m thick Li metal anode) capable of delivering initial specific energy of 504.5 Wh kg(-1) at 0.1 C and 25 degrees C. Li-ion cathode active materials are transitioning from poly- to single-crystal structures. However, the performance of high Ni-content single-crystal cathodes remains below expectations. Here, via Al/Zr co-doping, the authors propose a strategy to mitigate structural degradation in this class of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2319, "DOI": "10.1038/s41467-022-30020-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30020-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788852000035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gándara, F; Furukawa, H; Lee, S; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gandara, Felipe; Furukawa, Hiroyasu; Lee, Seungkyu; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Methane Storage Capacity in Aluminum Metal-Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of porous materials to store natural gas in vehicles requires large amounts of methane per unit of volume. Here we report the synthesis, crystal structure and methane adsorption properties of two new aluminum metal-organic frameworks, MOF-519 and MOF-520. Both materials exhibit permanent porosity and high methane volumetric storage capacity: MOF-519 has a volumetric capacity of 200 and 279 cm(3) cm(-3) at 298 K and 35 and 80 bar, respectively, and MOF-520 has a volumetric capacity of 162 and 231 cm(3) cm(-3) under the same conditions. Furthermore, MOF-519 exhibits an exceptional working capacity, being able to deliver a large amount of methane at pressures between 5 and 35 bar, 151 cm(3) cm(-3), and between 5 and 80 bar, 230 cm(3) cm(-3).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2014, "Volume": 136, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5271, "End Page": 5274, "Article Number": null, "DOI": "10.1021/ja501606h", "DOI Link": "http://dx.doi.org/10.1021/ja501606h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334572200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mandal, J; Jia, MX; Overvig, A; Fu, YK; Che, E; Yu, NF; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mandal, Jyotirmoy; Jia, Mingxin; Overvig, Adam; Fu, Yanke; Che, Eric; Yu, nullfang; Yang, Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Polymers with Switchable Optical Transmittance for Optical and Thermal Regulation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adaptive control of broadband light is essential for diverse applications including building energy management and light modulation. Here, we present porous polymer coatings (PPCs), whose optical transmittance changes upon reversible wetting with common liquids, as a platform for optical management from solar to thermal wavelengths. In the solar wavelengths, reduction in optical scattering upon wetting changes PPCs from reflective to transparent. For poly(vinylidene fluoride-co-hexafluoropropene) PPCs, this corresponds to solar and visible transmittance changes of up to 0.74 and 0.80, respectively. For infrared (IR) transparent polyethylene PPCs, wetting causes an icehouse-to-greenhouse transition where solar transparency rises but thermal IR transparency falls. These performances are either unprecedented or rival or surpass those of notable optical switching (e.g., electrochromic and thermochromic) paradigms, making PPCs promising for large-scale optical and thermal management. Specifically, switchable sub-ambient radiative cooling (by 3.2 degrees C) and above-ambient solar heating (by 21.4 degrees C), color-neutral daylighting, and thermal camouflage are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3088, "End Page": 3099, "Article Number": null, "DOI": "10.1016/j.joule.2019.09.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.09.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503428000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, MT; Kang, SJ; Wang, L; Lee, HW; Zheng, GW; Cui, Y; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Mintao; Kang, Sujin; Wang, Li; Lee, Hyun-Wook; Zheng, Guangyuan Wesley; Cui, Yi; Sun, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve good rate capability of lithium metal anodes for high-energy-density batteries, one fundamental challenge is the slow lithium diffusion at the interface. Here we report an interpenetrated, three-dimensional lithium metal/lithium tin alloy nullocomposite foil realized by a simple calendering and folding process of lithium and tin foils, and spontaneous alloying reactions. The strong affinity between the metallic lithium and lithium tin alloy as mixed electronic and ionic conducting networks, and their abundant interfaces enable ultrafast charger diffusion across the entire electrode. We demonstrate that a lithium/lithium tin alloy foil electrode sustains stable lithium stripping/plating under 30mAcm(-2) and 5mAhcm(-2) with a very low overpotential of 20mV for 200 cycles in a commercial carbonate electrolyte. Cycled under 6C (6.6mAcm(-2)), a 1.0mAhcm(-2) LiNi0.6Co0.2Mn0.2O2 electrode maintains a substantial 74% of its capacity by pairing with such anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 829, "DOI": "10.1038/s41467-020-14550-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14550-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514434800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, PH; Kuang, YD; Wei, Y; Li, F; Ou, HJ; Jiang, F; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Penghui; Kuang, Yudi; Wei, Yuan; Li, Fang; Ou, Huajie; Jiang, Feng; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatic self-assembly enabled flexible paper-based humidity sensor with high sensitivity and superior durability", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Humidity sensors have been widely used for humidity monitoring in industrial fields. However, the application of conventional sensors is limited due to the structural rigidity, high cost, and time-consuming integration process. Owing to the good hydrophilicity, biodegradability, and low cost of cellulose, the sensors built on cellulose bulk materials are considered a feasible method to overcome these drawbacks while providing reasonable performance. Herein, we design a flexible paper-based humidity sensor based on conductive 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized cellulose fibers/carbon nullotubes (TOCFs/CNTs) conformal fibers network. The CNTs are dispersed by cationic cetyl trimethyl ammonium bromide (CTAB), which introduces positive charges on the CNTs surface. The conductive fibers are achieved by an electrostatic self-assembly process that positively charged CNTs are adsorbed to the surface of negatively charged TOCFs. The vast number of hydrophilic hydroxyl groups on the surface of TOCFs provide more water molecules adsorption sites and facilitate the electron transfer from water molecules to CNTs, endowing the sensor with an excellent humidity responsive property. Besides, the swelling of the TOCFs greatly damages the conductive CNTs network and further promotes the humidity sensitive performance of the sensor. Benefiting from the unique structure, the obtained sensor exhibits a maximum response value of 87.0% (Delta I/I-0, and the response limit is 100%), outstanding linearity (R-2 = 0.995) between 11 and 95% relative humidity (RH), superior bending (with a curvature of 2.1 cm-1) and folding (up to 50 times) durability, and good long-time stability (more than 3 months). Finally, as a proof of concept, the sensor demonstrates an excellent responsive property to human breath, fingertip humidity, and the change of air humidity, indicating a great potential towards practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 404, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127105, "DOI": "10.1016/j.cej.2020.127105", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.127105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000601344700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zitolo, A; Ranjbar-Sahraie, N; Mineva, T; Li, JK; Jia, QY; Stamatin, S; Harrington, GF; Lyth, SM; Krtil, P; Mukerjee, S; Fonda, E; Jaouen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zitolo, Andrea; Ranjbar-Sahraie, Nastaran; Mineva, Tzonka; Li, Jingkun; Jia, Qingying; Stamatin, Serban; Harrington, George F.; Lyth, Stephen Mathew; Krtil, Petr; Mukerjee, Sanjeev; Fonda, Emiliano; Jaouen, Frederic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts with full utilization of metal centers can bridge the gap between molecular and solid-state catalysis. Metal-nitrogen-carbon materials prepared via pyrolysis are promising single-atom catalysts but often also comprise metallic particles. Here, we pyrolytically synthesize a Co-N-C material only comprising atomically dispersed cobalt ions and identify with X-ray absorption spectroscopy, magnetic susceptibility measurements and density functional theory the structure and electronic state of three porphyrinic moieties, CoN4C12, CoN3C10,(porp) and CoN2C5. The O-2 electro-reduction and operando X-ray absorption response are measured in acidic medium on Co-N-C and compared to those of a Fe-N-C catalyst prepared similarly. We show that cobalt moieties are unmodified from 0.0 to 1.0 V versus a reversible hydrogen electrode, while Fe-based moieties experience structural and electronic-state changes. On the basis of density functional theory analysis and established relationships between redox potential and O-2-adsorption strength, we conclude that cobaltbased moieties bind O-2 too weakly for efficient O-2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 483, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 957, "DOI": "10.1038/s41467-017-01100-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01100-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412999700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, F; Geng, W; Zhou, Y; Fang, HH; Tong, CJ; Loi, MA; Liu, LM; Zhao, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Feng; Geng, Wei; Zhou, Yang; Fang, Hong-Hua; Tong, Chuan-Jia; Loi, Maria Antonietta; Liu, Li-Min; Zhao, Ni", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phenylalkylamine Passivation of Organolead Halide Perovskites Enabling High-Efficiency and Air-Stable Photovoltaic Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Benzylamine is introduced as a surface passivation molecule that improves the moisture-resistance of the perovskites while simultaneously enhancing their electronic properties. Solar cells based on benzylamine-modified formamidinium lead iodide perovskite films exhibit a champion efficiency of 19.2% and an open-circuit voltage of 1.12 V. The modified FAPbI(3) films exhibit no degradation after >2800 h air exposure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 557, "Times Cited, All Databases": 595, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2016, "Volume": 28, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9986, "End Page": 9992, "Article Number": null, "DOI": "10.1002/adma.201603062", "DOI Link": "http://dx.doi.org/10.1002/adma.201603062", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392725200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Tang, J; Xia, XX; He, CL; Zhang, JW; Liu, YZ; Wan, CH; Fang, C; Guo, CY; Yang, WL; Guang, Y; Zhang, XM; Xu, HJ; Wei, JW; Liao, MZ; Lu, XB; Feng, JF; Li, XX; Peng, Y; Wei, HX; Yang, R; Shi, DX; Zhang, X; Han, Z; Zhang, ZD; Zhang, GY; Yu, G; Han, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiao; Tang, Jian; Xia, Xiuxin; He, Congli; Zhang, Junwei; Liu, Yizhou; Wan, Caihua; Fang, Chi; Guo, Chenyang; Yang, Wenlong; Guang, Yao; Zhang, Xiaomin; Xu, Hongjun; Wei, Jinwu; Liao, Mengzhou; Lu, Xiaobo; Feng, Jiafeng; Li, Xiaoxi; Peng, Yong; Wei, Hongxiang; Yang, Rong; Shi, Dongxia; Zhang, Xixiang; Han, Zheng; Zhang, Zhidong; Zhang, Guangyu; Yu, Guoqiang; Han, Xiufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current-driven magnetization switching in a van der Waals ferromagnet Fe3GeTe2", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of ferromagnetism in two-dimensional (2D) van der Waals (vdW) materials holds promises for spintronic devices with exceptional properties. However, to use 2D vdW magnets for building spintronic nullodevices such as magnetic memories, key challenges remain in terms of effectively switching the magnetization from one state to the other electrically. Here, we devise a bilayer structure of Fe3GeTe2/Pt, in which the magnetization of few-layered Fe3GeTe2 can be effectively switched by the spin-orbit torques (SOTs) originated from the current flowing in the Pt layer. The effective magnetic fields corresponding to the SOTs are further quantitatively characterized using harmonic measurements. Our demonstration of the SOT-driven magnetization switching in a 2D vdW magnet could pave the way for implementing low-dimensional materials in the next-generation spintronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw8904", "DOI": "10.1126/sciadv.aaw8904", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw8904", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482759500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Li, LQ; Su, K; Liu, XM; Zhang, TJ; Liang, YQ; Jing, DD; Yang, XJ; Zheng, D; Cui, ZD; Li, ZY; Zhu, SL; Yeung, KWK; Zheng, YF; Wang, XB; Wu, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mu; Li, Liqian; Su, Kun; Liu, Xiangmei; Zhang, Tianjin; Liang, Yanqin; Jing, Doudou; Yang, Xianjin; Zheng, Dong; Cui, Zhenduo; Li, Zhaoyang; Zhu, Shengli; Yeung, Kelvin Wai Kwok; Zheng, Yufeng; Wang, Xianbao; Wu, Shuilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Effective and Noninvasive Near-Infrared Eradication of a Staphylococcus aureus Biofilm on Implants by a Photoresponsive Coating within 20 Min", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biofilms have been related to the persistence of infections on medical implants, and these cannot be eradicated because of the resistance of biofilm structures. Therefore, a biocompatible phototherapeutic system is developed composed of MoS2, IR780 photosensitizer, and arginine-glycine-aspartic acid-cysteine (RGDC) to safely eradicate biofilms on titanium implants within 20 min. The magnetron-sputtered MoS2 film possesses excellent photothermal properties, and IR780 can produce reactive oxygen species (ROS) with the irradiation of near-infrared (NIR, lambda = 700-1100 nm) light. Consequently, the combination of photothermal therapy (PTT) and photodynamic therapy (PDT), assisted by glutathione oxidation accelerated by NIR light, can provide synergistic and rapid killing of bacteria, i.e., 98.99 +/- 0.42% eradication ratio against a Staphylococcus aureus biofilm in vivo within 20 min, which is much greater than that of PTT or PDT alone. With the assistance of ROS, the permeability of damaged bacterial membranes increases, and the damaged bacterial membranes become more sensitive to heat, thus accelerating the leakage of proteins from the bacteria. In addition, RGDC can provide excellent biosafety and osteoconductivity, which is confirmed by in vivo animal experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 6, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900599, "DOI": "10.1002/advs.201900599", "DOI Link": "http://dx.doi.org/10.1002/advs.201900599", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476527600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mehmood, A; Gong, MJ; Jaouen, F; Roy, A; Zitolo, A; Khan, A; Sougrati, MT; Primbs, M; Bonastres, AM; Fongalland, D; Drazic, G; Strasser, P; Kucernak, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mehmood, Asad; Gong, Mengjun; Jaouen, Frederic; Roy, Aaron; Zitolo, Andrea; Khan, Anastassiya; Sougrati, Moulay-Tahar; Primbs, Mathias; Bonastres, Alex Martinez; Fongalland, Dash; Drazic, Goran; Strasser, Peter; Kucernak, Anthony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High loading of single atomic iron sites in Fe-NC oxygen reduction catalysts for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-precious iron-based catalysts (Fe-NCs) require high active site density to meet the performance targets as cathode catalysts in proton exchange membrane fuel cells. Site density is generally limited to that achieved at a 1-3 wt%(Fe) loading due to the undesired formation of iron-containing nulloparticles at higher loadings. Here we show that by preforming a carbon-nitrogen matrix using a sacrificial metal (Zn) in the initial synthesis step and then exchanging iron into this preformed matrix we achieve 7 wt% iron coordinated solely as single-atom Fe-N-4 sites, as identified by Fe-57 cryogenic Mossbauer spectroscopy and X-ray absorption spectroscopy. Site density values measured by in situ nitrite stripping and ex situ CO chemisorption methods are 4.7 x 10(19) and 7.8 x 10(19) sites g(-1), with a turnover frequency of 5.4 electrons sites(-1) s(-1) at 0.80 V in a 0.5 M H2SO4 electrolyte. The catalyst delivers an excellent proton exchange membrane fuel cell performance with current densities of 41.3 mA cm(-2) at 0.90 ViR-free using H-2-O-2 and 145 mA cm(-2) at 0.80 V (199 mA cm(-2) at 0.80 ViR-free) using H-2-air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 311, "End Page": 323, "Article Number": null, "DOI": "10.1038/s41929-022-00772-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00772-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787831800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, HL; Hanikel, N; Lyle, SJ; Zhu, CH; Proserpio, DM; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, Ha L.; Hanikel, Nikita; Lyle, Steven J.; Zhu, Chenhui; Proserpio, Davide M.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Porous Covalent Organic Framework with Voided Square Grid Topology for Atmospheric Water Harvesting", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atmospheric moisture is a ubiquitous water resource available at any time and any place, making it attractive to develop materials for harvesting water from air to address the imminent water shortage crisis. In this context, we have been exploring the applicability of covalent organic frameworks (COFs) for water harvesting and report here a new porous, two-dimensional imine-linked COF with a voided square grid topology, termed COF-432. Unlike other reported COFs, COF-432 meets the requirements desired for water harvesting from air in that it exhibits an S-shaped water sorption isotherm with a steep pore-filling step at low relative humidity and without hysteretic behavior-properties essential for energy-efficient uptake and release of water. Further, it can be regenerated at ultra-low temperatures and displays exceptional hydrolytic stability, as demonstrated by the retention of its working capacity after 300 water adsorption-desorption cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2020, "Volume": 142, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2218, "End Page": 2221, "Article Number": null, "DOI": "10.1021/jacs.9b13094", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512222700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reis, F; Li, G; Dudy, L; Bauernfeind, M; Glass, S; Hanke, W; Thomale, R; Schafer, J; Claessen, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reis, F.; Li, G.; Dudy, L.; Bauernfeind, M.; Glass, S.; Hanke, W.; Thomale, R.; Schafer, J.; Claessen, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuthene on a SiC substrate: A candidate for a high-temperature quantum spin Hall material", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin Hall materials hold the promise of revolutionary devices with dissipationless spin currents but have required cryogenic temperatures owing to small energy gaps. Here we show theoretically that a room-temperature regime with a large energy gap may be achievable within a paradigm that exploits the atomic spin-orbit coupling. The concept is based on a substrate-supported monolayer of a high-atomic number element and is experimentally realized as a bismuth honeycomb lattice on top of the insulating silicon carbide substrate SiC(0001). Using scanning tunneling spectroscopy, we detect a gap of similar to 0.8 electron volt and conductive edge states consistent with theory. Our combined theoretical and experimental results demonstrate a concept for a quantum spin Hall wide-gap scenario, where the chemical potential resides in the global system gap, ensuring robust edge conductance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 801, "Times Cited, All Databases": 842, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2017, "Volume": 357, "Issue": 6348, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/science.aai8142", "DOI Link": "http://dx.doi.org/10.1126/science.aai8142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405901600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Long, J; Li, B; Li, XL; Zhang, SL; Yang, FH; Zeng, XH; Yang, ZH; Pang, WK; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Long, Jun; Li, Bo; Li, Xiaolong; Zhang, Shilin; Yang, Fuhua; Zeng, Xiaohui; Yang, Zhanhong; Pang, Wei Kong; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward High-Performance Hybrid Zn-Based Batteries via Deeply Understanding Their Mechanism and Using Electrolyte Additive", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous hybrid Zn-based batteries (ZIBs), as a highly promising alternative to lithium-ion batteries for grid application, have made considerable progress recently. However, few studies have been reported that investigate their working mechanism in detail. Here, the operando synchrotron X-ray diffraction is employed to thoroughly investigate the operational mechanism of a hybrid LiFePO4(LFP)/Zn battery, which indicates only Li+ extraction/insertion from/into cathode during cycling. Based on this system, a cheap electrolyte additive, sodium dodecyl benzene sulfonate, is proposed to effectively enhance its electrochemical properties. The influence of the additive on the Zn anode and LFP cathode is comprehensively studied, respectively. The results show that the additive modifies the intrinsic deposit pattern of Zn2+ ions, rendering Zn plating/stripping highly reversible in an aqueous medium. On the other hand, the wettability of the LFP electrode is visibly a meliorated by introducing the surfactant additive, accelerating the Li-ion diffusion at the LFP electrode/electrolyte interface, as indicated by the overpotential measurements. Benefiting from these effects, the Zn/LFP batteries deliver high rate capability and cycling stability in both coin cells and pouch cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 29, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903605, "DOI": "10.1002/adfm.201903605", "DOI Link": "http://dx.doi.org/10.1002/adfm.201903605", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481931200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, LJ; Yuan, YH; Yan, BJ; Feng, TT; Jian, YP; Zhang, JC; Sun, WY; Lin, K; Luo, GS; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Lijuan; Yuan, Yihui; Yan, Bingjie; Feng, Tiantian; Jian, Yaping; Zhang, Jiacheng; Sun, Wenyan; Lin, Ke; Luo, Guangsheng; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halogen hydrogen-bonded organic framework (XHOF) constructed by singlet open-shell diradical for efficient photoreduction of U(VI)", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While hydrogen bonded organic frameworks are well covered in the scientific literature, halogen hydrogen-bonded organic framework (XHOF) remain less explored. Here, the authors demonstrate a highly stable diradical-based XHOF and demonstrate photoreduction of uranyl ions and high capacity of uranyl immobilization. Synthesis of framework materials possessing specific spatial structures or containing functional ligands has attracted tremendous attention. Herein, a halogen hydrogen-bonded organic framework (XHOF) is fabricated by using Cl- ions as central connection nodes to connect organic ligands, 7,7,8,8-tetraaminoquinodimethane (TAQ), by forming a Cl-center dot center dot center dot H-3 hydrogen bond structure. Unlike metallic node-linked MOFs, covalent bond-linked COFs, and intermolecular hydrogen bond-linked HOFs, XHOFs represent a different kind of crystalline framework. The electron-withdrawing effect of Cl- combined with the electron-rich property of the organic ligand TAQ strengthens the hydrogen bonds and endows XHOF-TAQ with high stability. Due to the production of excited electrons by TAQ under light irradiation, XHOF-TAQ can efficiently catalyze the reduction of soluble U(VI) to insoluble U(IV) with a capacity of 1708 mg-U g(-1)-material. This study fabricates a material for uranium immobilization for the sustainability of the environment and opens up a new direction for synthesizing crystalline framework materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1389, "DOI": "10.1038/s41467-022-29107-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29107-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770096400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, BA; Ghimbeu, CM; Laberty, C; Vix-Guterl, C; Tarascon, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Biao; Ghimbeu, Camelia Matei; Laberty, Christel; Vix-Guterl, Cathie; Tarascon, Jean-Marie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlation Between Microstructure and Na Storage Behavior in Hard Carbon", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard carbons are considered among the most promising anode materials for Na-ion batteries. Understanding their structure is of great importance for optimizing their Na storage capabilities and therefore achieving high performance. Herein, carbon nullofibers (CNFs) are prepared by electrospinning and their microstructure, texture, and surface functionality are tailored through carbonization at various temperatures ranging from 650 to 2800 degrees C. Stepwise carbonization gradually removes the heteroatoms and increases the graphitization degree, enabling us to monitor the corresponding electrochemical performance for establishing a correlation between the CNFs characteristics and Na storage behavior. Outstandingly, it is found that for CNFs carbonized at above 2000 degrees C, a single voltage Na uptake plateau at similar or equal to 0.1 V with a capacity of similar or equal to 200 mAh g(-1). This specific performance may be nested in the higher degree of graphitization, lower active surface area, and different porous texture of the CNFs at such temperatures. It is demonstrated via the assembly of a CNF/Na2Fe2(SO4)(3) cell the benefit of such CNFs electrode for enhancing the energy density of full Na-ion cells. This finding sheds new insights in the quest for high performance carbon based anode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 475, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2016, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501588, "DOI": "10.1002/aenm.201501588", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367901700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Woomer, AH; Farnsworth, TW; Hu, J; Wells, RA; Donley, CL; Warren, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Woomer, Adam H.; Farnsworth, Tyler W.; Hu, Jun; Wells, Rebekah A.; Donley, Carrie L.; Warren, Scott C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here, we systematically survey conditions for liquid exfoliation to achieve the first large-scale production of monolayer, bilayer, and few-layer phosphorus, with exfoliation demonstrated at the 10 g scale. We describe a rapid approach for quantifying the thickness of 20 phosphorus and show that monolayer and few-layer flakes produced by our approach are crystalline and unoxidized, while air exposure leads to rapid oxidation and the production of acid. With large quantities of 2D phosphorus now available, we perform the first quantitative measurements of the material's absorption edge which is nearly identical to the material's band gap under our experimental conditions as a function of flake thickness. Our interpretation of the absorbance spectrum relies on an analytical method introduced in this work, allowing the accurate determination of the absorption edge in polydisperse samples of quantum-confined semiconductors. Using this method, we found that the band gap of black phosphorus increased from 0.33 +/- 0.02 eV in bulk to 1.88 +/- 0.24 eV in bilayers, a range that is larger than that of any other 2D material. In addition, we quantified a higher-energy optical transition (VB-1 to CB), which changes from 2.0 eV in bulk to 3.23 eV in bilayers. This work describes several methods for producing and analyzing 2D phosphorus while also yielding a class of 2D materials with unprecedented optoelectronic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8869, "End Page": 8884, "Article Number": null, "DOI": "10.1021/acsnullo.5b02599", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b02599", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361935800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, JH; Liu, W; Sarkar, D; Jena, D; Banerjee, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Jiahao; Liu, Wei; Sarkar, Deblina; Jena, Debdeep; Banerjee, Kaustav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computational Study of Metal Contacts to Monolayer Transition-Metal Dichalcogenide Semiconductors", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among various 2D materials, monolayer transition-metal dichalcogenide (mTMD) semiconductors with intrinsic band gaps (1-2 eV) are considered promising candidates for channel materials in next-generation transistors. Low-resistance metal contacts to mTMDs are crucial because currently they limit mTMD device performances. Hence, a comprehensive understanding of the atomistic nature of metal contacts to these 2D crystals is a fundamental challenge, which is not adequately addressed at present. In this paper, we report a systematic study of metal-mTMD contacts with different geometries (top contacts and edge contacts) by ab initio density-functional theory calculations, integrated with Mulliken population analysis and a semiempirical van der Waals dispersion potential model (which is critical for 2D materials and not well treated before). Particularly, In, Ti, Au, and Pd, contacts to monolayer MoS2 and WSe2 as well as Mo-MoS2 and W-WSe2 contacts are evaluated and categorized, based on their tunnel barriers, Schottky barriers, and orbital overlaps. Moreover, going beyond Schottky theory, new physics in such contact interfaces is revealed, such as the metallization of mTMDs and abnormal Fermi level pinning. Among the top contacts to MoS2, Ti and Mo show great potential to form favorable top contacts, which are both n-type contacts, while for top contacts to WSe2, W or Pd exhibits the most advantages as an n- or p-type contact, respectively. Moreover, we find that edge contacts can be highly advantageous compared to top contacts in terms of electron injection efficiency. Our formalism and the results provide guidelines that would be invaluable for designing novel 2D semiconductor devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 818, "Times Cited, All Databases": 897, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2014, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31005, "DOI": "10.1103/PhysRevX.4.031005", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.4.031005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341246700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Q; Tong, JH; Scheidt, RA; Wang, XM; Louks, AE; Xian, YM; Tirawat, R; Palmstrom, AF; Hautzinger, MP; Harvey, SP; Johnston, S; Schelhas, LT; Larson, BW; Warren, EL; Beard, MC; Berry, JJ; Yan, YF; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Qi; Tong, Jinhui; Scheidt, Rebecca A.; Wang, Xiaoming; Louks, Amy E.; Xian, Yeming; Tirawat, Robert; Palmstrom, Axel F.; Hautzinger, Matthew P.; Harvey, Steven P.; Johnston, Steve; Schelhas, Laura T.; Larson, Bryon W.; Warren, Emily L.; Beard, Matthew C.; Berry, Joseph J.; Yan, Yanfa; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compositional texture engineering for highly stable wide-bandgap perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly stable and efficient wide-bandgap (WBG) perovskite solar cells (PSCs) based on bromine-iodine (Br-I) mixed-halide perovskite (with Br greater than 20%) is critical to create tandem solar cells. However, issues with Br-I phase segregation under solar cell operational conditions (such as light and heat) limit the device voltage and operational stability. This challenge is often exacerbated by the ready defect formation associated with the rapid crystallization of Br-rich perovskite chemistry with antisolvent processes. We combined the rapid Br crystallization with a gentle gas-quench method to prepare highly textured columnar 1.75-electron volt Br-I mixed WBG perovskite films with reduced defect density. With this approach, we obtained 1.75-electron volt WBG PSCs with greater than 20% power conversion efficiency, approximately 1.33-volt open-circuit voltage (Voc), and excellent operational stability (less than 5% degradation over 1100 hours of operation under 1.2 sun at 65 degrees C). When further integrated with 1.25-electron volt narrow-bandgap PSC, we obtained a 27.1% efficient, all-perovskite, two-terminal tandem device with a high Voc of 2.2 volts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2022, "Volume": 378, "Issue": 6626, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1295, "End Page": 1300, "Article Number": null, "DOI": "10.1126/science.adf0194", "DOI Link": "http://dx.doi.org/10.1126/science.adf0194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905457800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bolan, S; Hou, DY; Wang, LW; Hale, L; Egamberdieva, D; Tammeorg, P; Li, R; Wang, B; Xu, JP; Wang, T; Sun, HW; Padhye, LP; Wang, HL; Siddique, KHM; Rinklebe, J; Kirkham, MB; Bolan, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bolan, Shiv; Hou, Deyi; Wang, Liuwei; Hale, Lauren; Egamberdieva, Dilfuza; Tammeorg, Priit; Li, Rui; Wang, Bing; Xu, Jiaping; Wang, Ting; Sun, Hongwen; Padhye, Lokesh P.; Wang, Hailong; Siddique, Kadambot H. M.; Rinklebe, Joerg; Kirkham, M. B.; Bolan, nullthi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The potential of biochar as a microbial carrier for agricultural and environmental applications", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biochar can be an effective carrier for microbial inoculants because of its favourable properties promoting microbial life. In this review, we assess the effectiveness of biochar as a microbial carrier for agricultural and environmental applications. Biochar is enriched with organic carbon, contains nitrogen, phosphorus, and potassium as nutrients, and has a high porosity and moisture-holding capacity. The large number of active hydroxyl, carboxyl, sulfonic acid group, amino, imino, and acylamino hydroxyl and carboxyl functional groups are effective for microbial cell adhesion and proliferation. The use of biochar as a carrier of microbial inoculum has been shown to enhance the persistence, survival and colonization of inoculated microbes in soil and plant roots, which play a crucial role in soil biochemical processes, nutrient and carbon cycling, and soil contamination remediation. Moreover, biochar-based microbial inoc-ulants including probiotics effectively promote plant growth and remediate soil contaminated with organic pollutants. These findings suggest that biochar can serve as a promising substitute for non-renewable substrates, such as peat, to formulate and deliver microbial inoculants. The future research directions in relation to improving the carrier material performance and expanding the potential applications of this emerging biochar-based microbial immobilization tech-nology have been proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2023, "Volume": 886, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 163968, "DOI": "10.1016/j.scitotenv.2023.163968", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2023.163968", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004464400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Deng, YX; Luo, HX; Shi, CY; Geise, GM; Feringa, BL; Tian, H; Qu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qi; Deng, Yuan-Xin; Luo, Hong-Xi; Shi, Chen-Yu; Geise, Geoffrey M.; Feringa, Ben L.; Tian, He; Qu, Da-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assembling a Natural Small Molecule into a Supramolecular Network with High Structural Order and Dynamic Functions", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Programming the hierarchical self-assembly of small molecules has been a fundamental topic of great significance in biological systems and artificial supramolecular systems. Precise and highly programmed self-assembly can produce supramolecular architectures with distinct structural features. However, it still remains a challenge how to precisely control the self-assembly pathway in a desirable way by introducing abundant structural information into a limited molecular backbone. Here we disclose a strategy that directs the hierarchical self-assembly of sodium thioctate, a small molecule of biological origin, into a highly ordered supramolecular layered network. By combining the unique dynamic covalent ring-opening-polymerization of sodium thioctate and an evaporation-induced interfacial confinement effect, we precisely direct the dynamic supramolecular self-assembly of this simple small molecule in a scheduled hierarchical pathway, resulting in a layered structure with long-range order at both macroscopic and molecular scales, which is revealed by small-angle and wide-angle X-ray scattering technologies. The resulting supramolecular layers are found to be able to bind water molecules as structural water, which works as an interlayer lubricant to modulate the material properties, such as mechanical performance, self-healing capability, and actuating function. Analogous to many reversibly self-assembled biological systems, the highly dynamic polymeric network can be degraded into monomers and reformed by a water-mediated route, exhibiting full recyclability in a facile, mild, and environmentally friendly way. This approach for assembling commercial small molecules into structurally complex materials paves the way for low-cost functional supramolecular materials based on synthetically simple procedures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 14", "Publication Year": 2019, "Volume": 141, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12804, "End Page": 12814, "Article Number": null, "DOI": "10.1021/jacs.9b05740", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b05740", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481563500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCall, KM; Stoumpos, CC; Kostina, SS; Kanatzidis, MG; Wessels, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCall, Kyle M.; Stoumpos, Constantinos C.; Kostina, Svetlana S.; Kanatzidis, Mercouri G.; Wessels, Bruce W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Electron-Phonon Coupling and Self-Trapped Excitons in the Defect Halide Perovskites A3M2I9 (A = Cs, Rb; M = Bi, Sb)", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The optical and electronic properties of Bridgman grown single crystals of the wide-bandgap semiconducting defect halide perovskites A(3)M(2)I(9) (A = Cs, Rb; M = Bi, Sb) have been investigated. Intense Raman scattering was observed at room temperature for each compound, indicating high polarizability and strong electron-phonon coupling. Both low-temperature and room-temperature photoluminescence (PL) were measured for each compound. Cs3Sb2I9 and Rb3Sb2I9 have broad PL emission bands between 1.75 and 2.05 eV with peaks at 1.96 and 1.92 eV, respectively. The Cs3Bi2I9, PL spectra showed broad emission consisting of several overlapping bands in the 1.65-2.2 eV range. Evidence of strong electron-phonon coupling comparable to that of the alkali halides was observed in phonon broadening of the PL emission. Effective phonon energies obtained from temperature-dependent PL measurements were in agreement with the Raman peak energies. A model is proposed whereby electron phonon interactions in Cs3Sb2I9, Rb3Sb2I9, and Cs3Bi2I9. induce small polarons, resulting in trapping of excitons by the lattice. The recombination of these self-trapped excitons is responsible for the broad PL emission. Rb3Bi2I9, Rb3Sb2I9, and Cs3Bi2I9 exhibit high resistivity and photoconductivity response under laser photoexcitation, indicating that these compounds possess potential as semiconductor hard radiation detector materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2017, "Volume": 29, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4129, "End Page": 4145, "Article Number": null, "DOI": "10.1021/acs.chemmater.7b01184", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.7b01184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401221700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, N; Wang, Y; Ma, L; Wen, JG; Li, J; Zheng, HC; Nie, KQ; Wang, XX; Zhao, FP; Li, YF; Fan, J; Zhong, J; Wu, TP; Miller, DJ; Lu, J; Lee, ST; Li, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Na; Wang, Yu; Ma, Lu; Wen, Jianguo; Li, Jing; Zheng, Hechuang; Nie, Kaiqi; Wang, Xinxia; Zhao, Feipeng; Li, Yafei; Fan, Jian; Zhong, Jun; Wu, Tianpin; Miller, Dean J.; Lu, Jun; Lee, Shuit-Tong; Li, Yanguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supported Cobalt Polyphthalocyanine for High-Performance Electrocatalytic CO2 Reduction", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 represents a possible solution for transforming atmospheric CO2 to value-added chemicals such as CO or hydrocarbons, but so far it has been hampered by the lack of suitable electrocatalysts. In this work, we design a type of organic-inorganic hybrid material by template-directed polymerization of cobalt phthalocyanine on carbon nullotubes for a high-performance CO2 reduction reaction. Compared with molecular phthalocyanines, the polymeric form of phthalocyanines supported on the conductive scaffold exhibits an enlarged electrochemically active surface area and improved physical and chemical robustness. Experimental results show that our hybrid electrocatalyst can selectively reduce CO2 to CO with a large faradic efficiency (similar to 90%), exceptional turnover frequency (4,900 hr(-1) at eta = 0.5 V), and excellent long-term durability. These metrics are superior to those of most of its organic or inorganic competitors. Its high electrocatalytic activity is also supported by density functional theory calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 652, "End Page": 664, "Article Number": null, "DOI": "10.1016/j.chempr.2017.08.002", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.08.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416366900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, B; Zhang, YA; Fu, L; Yu, T; Zhou, SJ; Zhang, LY; Yin, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Bo; Zhang, Yanull; Fu, Lin; Yu, Tong; Zhou, Shujie; Zhang, Luyuan; Yin, Longwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface passivation engineering strategy to fully-inorganic cubic CsPbI3 perovskites for high-performance solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to inevitable thermal/moisture instability for organic-inorganic hybrid perovskites, pure inorganic perovskite cesium lead halides with both inherent stability and prominent photovoltaic performance have become research hotspots as a promising candidate for commercial perovskite solar cells. However, it is still a serious challenge to synthesize desired cubic cesium lead iodides (CsPbI3) with superior photovoltaic performance for its thermodynamically metastable characteristics. Herein, polymer poly-vinylpyrrolidone (PVP)-induced surface passivation engineering is reported to synthesize extra-long-term stable cubic CsPbI3. It is revealed that acylamino groups of PVP induce electron cloud density enhancement on the surface of CsPbI3, thus lowering surface energy, conducive to stabilize cubic CsPbI3 even in micrometer scale. The cubic-CsPbI3 PSCs exhibit extra-long carrier diffusion length (over 1.5 mu m), highest power conversion efficiency of 10.74% and excellent thermal/moisture stability. This result provides important progress towards understanding of phase stability in realization of large-scale preparations of efficient and stable inorganic PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 656, "Times Cited, All Databases": 710, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1076, "DOI": "10.1038/s41467-018-03169-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03169-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427377800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, HK; Koh, CSL; Lee, YH; Liu, C; Phang, IY; Han, XM; Tsung, CK; Ling, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hiang Kwee; Koh, Charlynn Sher Lin; Lee, Yih Hong; Liu, Chong; Phang, In Yee; Han, Xuemei; Tsung, Chia-Kuang; Ling, Xing Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Favoring the unfavored: Selective electrochemical nitrogen fixation using a reticular chemistry approach", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical nitrogen-to-ammonia fixation is emerging as a sustainable strategy to tackle the hydrogen-and energy-intensive operations by Haber-Bosch process for ammonia production. However, current electro-chemical nitrogen reduction reaction (NRR) progress is impeded by overwhelming competition from the hydrogen evolution reaction (HER) across all traditional NRR catalysts and the requirement for elevated temperature/pressure. We achieve both excellent NRR selectivity (similar to 90%) and a significant boost to Faradic efficiency by 10 percentage points even at ambient operations by coating a superhydrophobic metal-organic framework (MOF) layer over the NRR electrocatalyst. Our reticular chemistry approach exploits MOF's water-repelling and molecular-concentrating effects to overcome HER-imposed bottlenecks, uncovering the unprecedented electrochemical features of NRR critical for future theoretical studies. By favoring the originally unfavored NRR, we envisage our electrocatalytic design as a starting point for high-performance nitrogen-to-ammonia electro-conversion directly from water vapor-abundant air to address increasing global demand of ammonia in (bio) chemical and energy industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar3208", "DOI": "10.1126/sciadv.aar3208", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar3208", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427892700038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schroder, K; Avarado, J; Yersak, TA; Li, JC; Dudney, N; Webb, LJ; Meng, YS; Stevenson, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schroder, Kjell; Avarado, Judith; Yersak, Thomas A.; Li, Juchuan; Dudney, nullcy; Webb, Lauren J.; Meng, Ying Shirley; Stevenson, Keith J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Effect of Fluoroethylene Carbonate as an Additive on the Solid Electrolyte Interphase on Silicon Lithium-Ion Electrodes", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluoroethylene carbonate (FEC) has become a standard electrolyte additive for use with silicon negative electrodes, but how FEC affects solid electrolyte interphase (SET) formation on the silicon anode's surface is still not well understood. Herein, SET formed from LiPF6-based carbonate electrolytes, with and without FEC, were investigated on 50 nm thick amorphous silicon thin film electrodes to understand the role of FEC on silicon electrode surface reactions. In contrast to previous work, anhydrous and anoxic techniques were used to prevent air and moisture contamination of prepared SET films. This allowed for accurate characterization of the SEI structure and composition by X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry depth profiling. These results show that FEC reduction leads to fluoride ion and LiF formation, consistent with previous computational and experimental results. Surprisingly, we also find that these species decrease lithium-ion solubility and increase the reactivity of the silicon surface. We conclude that the effectiveness of FEC at improving the Coulombic efficiency and capacity retention is due to fluoride ion formation from reduction of the electrolyte, which leads to the chemical attack of any silicon-oxide surface passivation layers and the formation of a kinetically stable SET comprising predominately lithium fluoride and lithium oxide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2015, "Volume": 27, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5531, "End Page": 5542, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b01627", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b01627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360323700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, MM; Wei, ZJ; Li, JJ; Guo, ZC; Yan, ZJ; Sun, X; Yu, QY; Wu, XJ; Yu, CJ; Yao, FL; Feng, SQ; Zhang, H; Li, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Mengmeng; Wei, Zhijian; Li, Junjin; Guo, Zhicheng; Yan, Zhuojun; Sun, Xia; Yu, Qingyu; Wu, Xiaojun; Yu, Chaojie; Yao, Fanglian; Feng, Shiqing; Zhang, Hong; Li, Junjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microgel reinforced zwitterionic hydrogel coating for blood-contacting biomedical devices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zwitterionic hydrogels are nonfouling and hemocompatibility but several key challenges such as weak mechanical strength and low adhesion hamper their application as coating materials for devices. Here, the authors report a microgel reinforced zwitterionic hydrogel with excellent mechanical robustness and anti-swelling properties. Zwitterionic hydrogels exhibit eminent nonfouling and hemocompatibility. Several key challenges hinder their application as coating materials for blood-contacting biomedical devices, including weak mechanical strength and low adhesion to the substrate. Here, we report a poly(carboxybetaine) microgel reinforced poly(sulfobetaine) (pCBM/pSB) pure zwitterionic hydrogel with excellent mechanical robustness and anti-swelling properties. The pCBM/pSB hydrogel coating was bonded to the PVC substrate via the entanglement network between the pSB and PVC chain. Moreover, the pCBM/pSB hydrogel coating can maintain favorable stability even after 21 d PBS shearing, 0.5 h strong water flushing, 1000 underwater bends, and 100 sandpaper abrasions. Notably, the pCBM/pSB hydrogel coated PVC tubing can not only mitigate the foreign body response but also prevent thrombus formation ex vivo in rats and rabbits blood circulation without anticoagulants. This work provides new insights to guide the design of pure zwitterionic hydrogel coatings for biomedical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5339, "DOI": "10.1038/s41467-022-33081-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33081-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853182100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Fu, J; Mao, XY; Chen, C; Liu, H; Gong, M; Zeng, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yue; Fu, Jun; Mao, Xiaoyu; Chen, Chen; Liu, Heng; Gong, Ming; Zeng, Hualing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced bulk photovoltaic effect in two-dimensional ferroelectric CuInP2S6", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While magnetism, hyperferroelectricity, and topological phases in the two-dimensional limit have been widely explored, the direct experimental study on bulk photovoltaic effect in 2D materials remains unimplemented. Here, the authors find bulk photovoltaic effect in 2D ferroelectric CuInP2S6. The photocurrent generation in photovoltaics relies essentially on the interface of p-n junction or Schottky barrier with the photoelectric efficiency constrained by the Shockley-Queisser limit. The recent progress has shown a promising route to surpass this limit via the bulk photovoltaic effect for crystals without inversion symmetry. Here we report the bulk photovoltaic effect in two-dimensional ferroelectric CuInP2S6 with enhanced photocurrent density by two orders of magnitude higher than conventional bulk ferroelectric perovskite oxides. The bulk photovoltaic effect is inherently associated to the room-temperature polar ordering in two-dimensional CuInP2S6. We also demonstrate a crossover from two-dimensional to three-dimensional bulk photovoltaic effect with the observation of a dramatic decrease in photocurrent density when the thickness of the two-dimensional material exceeds the free path length at around 40 nm. This work spotlights the potential application of ultrathin two-dimensional ferroelectric materials for the third-generation photovoltaic cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5896, "DOI": "10.1038/s41467-021-26200-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26200-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000705238300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chu, CH; Tseng, ML; Chen, J; Wu, PC; Chen, YH; Wang, HC; Chen, TY; Hsieh, WT; Wu, HJ; Sun, G; Tsai, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chu, Cheng Hung; Tseng, Ming Lun; Chen, Jie; Wu, Pin Chieh; Chen, Yi-Hao; Wang, Hsiang-Chu; Chen, Ting-Yu; Hsieh, Wen Ting; Wu, Hui Jun; Sun, Greg; Tsai, Din Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active dielectric metasurface based on phase-change medium", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose all-dielectric metasurfaces that can be actively re-configured using the phase-change material Ge2Sb2Te5 (GST) alloy. With selectively controlled phase transitions on the composing GST elements, metasurfaces can be tailored to exhibit varied functionalities. Using phase-change GST rod as the basic building block, we have modelled metamolecules with tunable optical response when phase change occurs on select constituent GST rods. Tunable gradient metasurfaces can be realized with variable supercell period consisting of different patterns of the GST rods in their amorphous and crystalline states. Simulation results indicate a range of functions can be delivered, including multilevel signal modulating, near-field coupling of GST rods, and anomalous reflection angle controlling. This work opens up a new space in exploring active meta-devices with broader applications that cannot be achieved in their passive counterparts with permanent properties once fabricated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 986, "End Page": 994, "Article Number": null, "DOI": "10.1002/lpor.201600106", "DOI Link": "http://dx.doi.org/10.1002/lpor.201600106", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393051500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, WH; Qiu, JM; Liu, XS; Ren, FC; Liu, HD; He, HJ; Luo, C; Li, JL; Ortiz, GF; Duan, HN; Liu, JP; Wang, MS; Li, YX; Fu, RQ; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Wenhua; Qiu, Jimin; Liu, Xiangsi; Ren, Fucheng; Liu, Haodong; He, Huajin; Luo, Chong; Li, Jialin; Ortiz, Gregorio F.; Duan, Huanull; Liu, Jinping; Wang, Ming-Sheng; Li, Yangxing; Fu, Riqiang; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The stability of P2-layered sodium transition metal oxides in ambient atmospheres", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Air-stability is one of the most important considerations for the practical application of electrode materials in energy-harvesting/storage devices, ranging from solar cells to rechargeable batteries. The promising P2-layered sodium transition metal oxides (P2-NaxTmO2) often suffer from structural/chemical transformations when contacted with moist air. However, these elaborate transitions and the evaluation rules towards air-stable P2-NaxTmO2 have not yet been clearly elucidated. Herein, taking P2-Na0.67MnO2 and P2-Na0.67Ni0.33Mn0.67O2 as key examples, we unveil the comprehensive structural/chemical degradation mechanisms of P2-NaxTmO2 in different ambient atmospheres by using various microscopic/spectroscopic characterizations and first-principle calculations. The extent of bulk structural/chemical transformation of P2-NaxTmO2 is determined by the amount of extracted Na+, which is mainly compensated by Na+/H+ exchange. By expanding our study to a series of Mn-based oxides, we reveal that the air-stability of P2-NaxTmO2 is highly related to their oxidation features in the first charge process and further propose a practical evaluating rule associated with redox couples for air-stable NaxTmO2 cathodes. Air-stability is a critical challenge faced by layered sodium transition metal oxide cathodes. Here, the authors depict a general and in-depth model of the structural/chemical evolution of P2-type layered oxides in air and propose an evaluation rule for the air-stability of layered sodium cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3544, "DOI": "10.1038/s41467-020-17290-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17290-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000554533700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, G; Yang, WQ; Zhang, TJ; Jing, QS; Chen, J; Zhou, YS; Bai, P; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Guang; Yang, Wei Qing; Zhang, Tiejun; Jing, Qingshen; Chen, Jun; Zhou, Yu Sheng; Bai, Peng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Powered, Ultrasensitive, Flexible Tactile Sensors Based on Contact Electrification", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tactile/touch sensing is essential in developing human-machine interfacing and electronic skins for areas such as automation, security, and medical care. Here, we report a self-powered triboelectric sensor based on flexible thin-film materials. It relies on contact electrification to generate a voltage signal in response to a physical contact without using an external power supply. Enabled by the unique sensing mechanism and surface modification by polymer-nullowires, the triboelectric sensor shows an exceptional pressure sensitivity of 44 mV/Pa (0.09% Pa-1) and a maximum touch sensitivity of 1.1 V/Pa (2.3% Pa-1) in the extremely low-pressure region (<0.15 KPa). Through integration of the sensor with a signal-processing circuit, a complete tactile sensing system is further developed. Diverse applications of the system are demonstrated, explicitly indicating a variety of immediate uses in human-electronics interface, automatic control, surveillance, remote operation, and security systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3208, "End Page": 3213, "Article Number": null, "DOI": "10.1021/nl5005652", "DOI Link": "http://dx.doi.org/10.1021/nl5005652", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Kong, TY; Xiong, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jun; Kong, Taoyi; Xiong, Huan-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mulberry-Leaves-Derived Red-Emissive Carbon Dots for Feeding Silkworms to Produce Brightly Fluorescent Silk", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluorescent silk has promising applications in dazzling textiles, biological engineering, and medical products, but the natural Bombyx mori silk has almost no fluorescence. Here carbon dots (CDs) made from mulberry leaves are reported, which have a strong near-infrared fluorescence with absolute quantum yield of 73% and a full width at half maximum of 20 nm. After feeding with such CDs, silkworms exhibit bright red fluorescence, grow healthily, cocoon normally, and turn to moths finally. The cocoons are pink in daylight and show bright red fluorescence under ultraviolet light. After breaking out of such cocoons, the red-emissive moths can mate and lay fluorescent eggs which would hatch normally. The growth cycle of the second generation of the test silkworm is the same as that of the control group, which means such CDs have excellent biocompatiblility. Dissection and analyses on both the test silkworms and cocoons disclose the metabolic route of the CDs, that is, the fluorescent CDs are absorbed by silkworms from alimentary canals, then transferred to silk glands, and finally to cocoons, while those unabsorbed CDs are excreted with the feces. All experimental results confirm the excellent biocompatibility and fluorescence stability of such CDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200152, "DOI": "10.1002/adma.202200152", "DOI Link": "http://dx.doi.org/10.1002/adma.202200152", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768880000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, Y; Ma, H; Spolenak, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Yu; Ma, Huan; Spolenak, Ralph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastrong ductile and stable high-entropy alloys at small scales", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Refractory high-entropy alloys (HEAs) are a class of emerging multi-component alloys, showing superior mechanical properties at elevated temperatures and being technologically interesting. However, they are generally brittle at room temperature, fail by cracking at low compressive strains and suffer from limited formability. Here we report a strategy for the fabrication of refractory HEA thin films and small-sized pillars that consist of strongly textured, columnar and nullometre-sized grains. Such HEA pillars exhibit extraordinarily high yield strengths of similar to 10 GPa-among the highest reported strengths in micro-/nullo-pillar compression and one order of magnitude higher than that of its bulk form-and their ductility is considerably improved (compressive plastic strains over 30%). Additionally, we demonstrate that such HEA films show substantially enhanced stability for high-temperature, long-duration conditions (at 1,100 degrees C for 3 days). Small-scale HEAs combining these properties represent a new class of materials in small-dimension devices potentially for high-stress and high-temperature applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7748, "DOI": "10.1038/ncomms8748", "DOI Link": "http://dx.doi.org/10.1038/ncomms8748", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858500054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kretinin, AV; Cao, Y; Tu, JS; Yu, GL; Jalil, R; Novoselov, KS; Haigh, SJ; Gholinia, A; Mishchenko, A; Lozada, M; Georgiou, T; Woods, CR; Withers, F; Blake, P; Eda, G; Wirsig, A; Hucho, C; Watanabe, K; Taniguchi, T; Geim, AK; Gorbachev, RV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kretinin, A. V.; Cao, Y.; Tu, J. S.; Yu, G. L.; Jalil, R.; Novoselov, K. S.; Haigh, S. J.; Gholinia, A.; Mishchenko, A.; Lozada, M.; Georgiou, T.; Woods, C. R.; Withers, F.; Blake, P.; Eda, G.; Wirsig, A.; Hucho, C.; Watanabe, K.; Taniguchi, T.; Geim, A. K.; Gorbachev, R. V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Properties of Graphene Encapsulated with Different Two-Dimensional Atomic Crystals", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride is the only substrate that has so far allowed graphene devices exhibiting micrometer-scale ballistic transport. Can other atomically flat crystals be used as substrates for making quality graphene heterostructures? Here we report on our search for alternative substrates. The devices fabricated by encapsulating graphene with molybdenum or tungsten disulfides and hBN are found to exhibit consistently high carrier mobilities of about 60 000 cm(2) V-1 s(-1). In contrast, encapsulation with atomically flat layered oxides such as mica, bismuth strontium calcium copper oxide, and vanadium pentoxide results in exceptionally low quality of graphene devices with mobilities of similar to 1000 cm(2) V-1 s(-1). We attribute the difference mainly to self-cleansing that takes place at interfaces between graphene, hBN, and transition metal dichalcogenides. Surface contamination assembles into large pockets allowing the rest of the interface to become atomically clean. The cleansing process does not occur for graphene on atomically flat oxide substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 435, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3270, "End Page": 3276, "Article Number": null, "DOI": "10.1021/nl5006542", "DOI Link": "http://dx.doi.org/10.1021/nl5006542", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337337100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YZ; Yang, L; Hou, Y; Zhang, ZZ; Chen, M; Wang, MX; Liu, J; Wang, J; Zhao, ZH; Xie, CM; Lu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yazhen; Yang, Lu; Hou, Yue; Zhang, Zhenzhen; Chen, Miao; Wang, Maoxia; Liu, Jin; Wang, Jun; Zhao, Zhihe; Xie, Chaoming; Lu, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine-mediated graphene oxide and nullohydroxyapatite-incorporated conductive scaffold with an immunomodulatory ability accelerates periodontal bone regeneration in diabetes", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Regenerating periodontal bone tissues in the aggravated inflammatory periodontal microenvironment under diabetic conditions is a great challenge. Here, a polydopamine-mediated graphene oxide (PGO) and hydroxyapatite nulloparticle (PHA)-incorporated conductive alginate/gelatin (AG) scaffold is developed to accelerate periodontal bone regeneration by modulating the diabetic inflammatory microenvironment. PHA confers the scaffold with osteoinductivity and PGO provides a conductive pathway for the scaffold. The conductive scaffold promotes bone regeneration by transferring endogenous electrical signals to cells and activating Ca2+ channels. Moreover, the scaffold with polydopamine-mediated nullomaterials has a reactive oxygen species (ROS)-scavenging ability and anti-inflammatory activity. It also exhibits an immunomodulatory ability that suppresses M1 macrophage polarization and activates M2 macrophages to secrete osteogenesis-related cytokines by mediating glycolytic and RhoA/ROCK pathways in macrophages. The scaffold induces excellent bone regeneration in periodontal bone defects of diabetic rats because of the synergistic effects of good conductive, ROS-scavenging, anti-inflammatory, and immunomodulatory abilities. This study provides fundamental insights into the synergistical effects of conductivity, osteoinductivity, and immunomodulatory abilities on bone regeneration and offers a novel strategy to design immunomodulatory biomaterials for treatment of immune-related diseases and tissue regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 18, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 213, "End Page": 227, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.03.021", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.03.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791151500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZY; Butun, S; Aydin, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhongyang; Butun, Serkan; Aydin, Koray", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Area, Lithography-Free Super Absorbers and Color Filters at Visible Frequencies Using Ultrathin Metallic Films", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured photonic materials enable control and manipulation of light,at subwavelength scales and exhibit unique optical functionalities. In particular, plasmonic materials and metamaterials have been widely utilized to achieve spectral transmission, reflection, and absorption filters based on localized or delocalized resonullces arising from the interaction of photons with nullostructured materials. Realization of visible-frequency, high-performance, large area, optical filters based on nulloplasmonic materials is rather challenging due to nullofabrication related problems (cost, fabrication imperfection, surface roughness) and optical losses of metals. Here, we propose and demonstrate large-area perfect absorbers and transmission filters that overcome difficulties associated with the nullofabrication using a lithography-free approach. We also utilize and benefit from the optical losses in metals in our optical filter designs. Our resonullt optical filter design is based on a modified, asymmetric metal-insufator-metal (MIM) based Fabry-Perot cavity with plasmonic, lossy ultrathin (similar to 30 nm) metallic films used as the top metallic layer. We demonstrated a narrow bandwidth (similar to 17 nm) super absorber with 97% maximum absorption with a performance comparable to nullostructure/nulloparticle-based super absorbers. We also investigated transmission (color) filters using ultrathin metallic films, in which different colors can be obtained by controlling the dielectric spacer thickness. With performance parameters of transmittance peak intensity reaching 60% and a narrow band of 40 nm, our color filters exceed the perfomance of widely studied plasmonic nullohole array based color filters. Proposed asymmetric Fabry-Perot cavities using ultrathin metallic films could find applications in spectrally selective optical (color and absorber) filters, optoelectronic devices with controlled bandwidth such as narrow band photodetectors, and light emitting devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 468, "Times Cited, All Databases": 505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 183, "End Page": 188, "Article Number": null, "DOI": "10.1021/ph500410u", "DOI Link": "http://dx.doi.org/10.1021/ph500410u", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349814400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Feng, HS; Yang, YS; Niu, YM; Wang, L; Yin, P; Hong, S; Zhang, BS; Zhang, X; Wei, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Feng, Haisong; Yang, Yusen; Niu, Yiming; Wang, Lei; Yin, Pan; Hong, Song; Zhang, Bingsen; Zhang, Xin; Wei, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly-efficient RuNi single-atom alloy catalysts toward chemoselective hydrogenation of nitroarenes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and exploitation of high-performance catalysts have gained considerable attention in selective hydrogenation reactions, but remain a huge challenge. Herein, we report a RuNi single atom alloy (SAA) in which Ru single atoms are anchored onto Ni nulloparticle surface via Ru-Ni coordination accompanied with electron transfer from sub-surface Ni to Ru. The optimal catalyst 0.4% RuNi SAA exhibits simultaneously improved activity (TOF value: 4293 h(-1)) and chemoselectivity toward selective hydrogenation of 4-nitrostyrene to 4-aminostyrene (yield: >99%), which is, to the best of our knowledge, the highest level compared with reported heterogeneous catalysts. In situ experiments and theoretical calculations reveal that the Ru-Ni interfacial sites as intrinsic active centers facilitate the preferential cleavage of N-O bond with a decreased energy barrier by 0.28 eV. In addition, the Ru-Ni synergistic catalysis promotes the formation of intermediates (C8H7NO* and C8H7NOH*) and accelerates the rate-determining step (hydrogenation of C8H7NOH*). Catalytic hydrogenation of available nitroarenes is an environmentally benign and recyclable approach to synthesize value-added amines. Here, the authors design a RuNi single atom alloy with host-dopant synergistic effect, which exhibits outstanding performance toward nitroarenes hydrogenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3188, "DOI": "10.1038/s41467-022-30536-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30536-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809119000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YG; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yanguang; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal Air Batteries: Will They Be the Future Electrochemical Energy Storage Device of Choice?", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal air batteries have a theoretical energy density that is much higher than that of lithium-ion batteries and are frequently advocated as a solution toward next-generation electro-chemical energy storage for applications including electric vehicles or grid energy storage. However, they have not fulfilled their full potential because of challenges associated with the metal anode, air cathode, and electrolyte. These challenges will have to be properly resolved before metal air batteries can become a practical reality and be deployed on a large scale. Here we survey the current status and latest advances in metal air battery research for both aqueous (e.g., Zn-air) and nonaqueous (e.g., Li-air) systems. An overview of the general technical issues confronting their development is presented, and our perspective on possible solutions is offered.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 760, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1370, "End Page": 1377, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00119", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403303500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huo, SD; Zhao, PK; Shi, ZY; Zou, MC; Yang, XT; Warszawik, E; Loznik, M; Göstl, R; Herrmann, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huo, Shuaidong; Zhao, Pengkun; Shi, Zhiyuan; Zou, Miancheng; Yang, Xintong; Warszawik, Eliza; Loznik, Mark; Goestl, Robert; Herrmann, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanochemical bond scission for the activation of drugs", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pharmaceutical drug therapy is often hindered by issues caused by poor drug selectivity, including unwanted side effects and drug resistance. Spatial and temporal control over drug activation in response to stimuli is a promising strategy to attenuate and circumvent these problems. Here we use ultrasound to activate drugs from inactive macromolecules or nullo-assemblies through the controlled scission of mechanochemically labile covalent bonds and weak non-covalent bonds. We show that a polymer with a disulfide motif at the centre of the main chain releases an alkaloid-based anticancer drug from its beta-carbonate linker by a force-induced intramolecular 5-exo-trig cyclization. Second, aminoglycoside antibiotics complexed by a multi-aptamer RNA structure are activated by the mechanochemical opening and scission of the nucleic acid backbone. Lastly, nulloparticle-polymer and nulloparticle-nulloparticle assemblies held together by hydrogen bonds between the peptide antibiotic vancomycin and its complementary peptide target are activated by force-induced scission of hydrogen bonds. This work demonstrates the potential of ultrasound to activate mechanoresponsive prodrug systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41557-020-00624-8", "DOI Link": "http://dx.doi.org/10.1038/s41557-020-00624-8", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612903100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SC; He, TW; Chen, P; Du, AJ; Ostrikov, K; Huang, W; Wang, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Songcan; He, Tianwei; Chen, Peng; Du, Aijun; Ostrikov, Kostya (Ken); Huang, Wei; Wang, Lianzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Formation of Oxygen Vacancies Achieving Near-Complete Charge Separation in Planar BiVO4 Photoanodes", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite a suitable bandgap of bismuth vanadate (BiVO4) for visible light absorption, most of the photogenerated holes in BiVO4 photoanodes are vanished before reaching the surfaces for oxygen evolution reaction due to the poor charge separation efficiency in the bulk. Herein, a new sulfur oxidation strategy is developed to prepare planar BiVO4 photoanodes with in situ formed oxygen vacancies, which increases the majority charge carrier density and photovoltage, leading to a record charge separation efficiency of 98.2% among the reported BiVO4 photoanodes. Upon loading NiFeOx as an oxygen evolution cocatalyst, a stable photocurrent density of 5.54 mA cm(-2) is achieved at 1.23 V versus the reversible hydrogen electrode (RHE) under AM 1.5 G illumination. Remarkably, a dual-photoanode configuration further enhances the photocurrent density up to 6.24 mA cm(-2), achieving an excellent applied bias photon-to-current efficiency of 2.76%. This work demonstrates a simple thermal treatment approach to generate oxygen vacancies for the design of efficient planar photoanodes for solar hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 32, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001385, "DOI": "10.1002/adma.202001385", "DOI Link": "http://dx.doi.org/10.1002/adma.202001385", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000532552000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DC; Zhang, LC; Gu, YH; Mehmood, MQ; Gong, YD; Srivastava, A; Jian, LK; Venkatesan, T; Qiu, CW; Hong, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dacheng; Zhang, Lingchao; Gu, Yinghong; Mehmood, M. Q.; Gong, Yandong; Srivastava, Amar; Jian, Linke; Venkatesan, T.; Qiu, Cheng-Wei; Hong, Minghui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switchable Ultrathin Quarter-wave Plate in Terahertz Using Active Phase-change Metasurface", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterials open up various exotic means to control electromagnetic waves and among them polarization manipulations with metamaterials have attracted intense attention. As of today, static responses of resonators in metamaterials lead to a narrow-band and single-function operation. Extension of the working frequency relies on multilayer metamaterials or different unit cells, which hinder the development of ultra-compact optical systems. In this work, we demonstrate a switchable ultrathin terahertz quarter-wave plate by hybridizing a phase change material, vanadium dioxide (VO2), with a metasurface. Before the phase transition, VO2 behaves as a semiconductor and the metasurface operates as a quarter-wave plate at 0.468 THz. After the transition to metal phase, the quarter-wave plate operates at 0.502 THz. At the corresponding operating frequencies, the metasurface converts a linearly polarized light into a circularly polarized light. This work reveals the feasibility to realize tunable/active and extremely low-profile polarization manipulation devices in the terahertz regime through the incorporation of such phase-change metasurfaces, enabling novel applications of ultrathin terahertz meta-devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15020, "DOI": "10.1038/srep15020", "DOI Link": "http://dx.doi.org/10.1038/srep15020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362347400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, Z; Wang, CY; Li, CZ; Zeng, YC; Hwang, S; Li, BY; Karakalos, S; Park, J; Kropf, AJ; Wegener, EC; Gong, Q; Xu, H; Wang, GF; Myers, DJ; Xie, J; Spendelow, JS; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Zhi; Wang, Chenyu; Li, Chenzhao; Zeng, Yachao; Hwang, Sooyeon; Li, Boyang; Karakalos, Stavros; Park, Jaehyung; Kropf, A. Jeremy; Wegener, Evan C.; Gong, Qing; Xu, Hui; Wang, Guofeng; Myers, Deborah J.; Xie, Jian; Spendelow, Jacob S.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed single iron sites for promoting Pt and Pt3Co fuel cell catalysts: performance and durability improvements", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Significantly reducing platinum group metal (PGM) loading while improving catalytic performance and durability is critical to accelerating proton-exchange membrane fuel cells (PEMFCs) for transportation. Here we report an effective strategy to boost PGM catalysts through integrating PGM-free atomically-dispersed single metal active sites in the carbon support toward the cathode oxygen reduction reaction (ORR). We achieved uniform and fine Pt nulloparticle (NP) (similar to 2 nm) dispersion on an already highly ORR-active FeN4 site-rich carbon (FeN4-C). Furthermore, we developed an effective approach to preparing a well-dispersed and highly ordered L1(2) Pt3Co intermetallic nulloparticle catalyst on the FeN4-C support. DFT calculations predicted a synergistic interaction between Pt clusters and surrounding FeN4 sites through weakening O-2 adsorption by 0.15 eV on Pt sites and reducing activation energy to break O-O bonds, thereby enhancing the intrinsic activity of Pt. Experimentally, we verified the synergistic effect between Pt or Pt3Co NPs and FeN4 sites, leading to significantly enhanced ORR activity and stability. Especially in a membrane electrode assembly (MEA) with a low cathode Pt loading (0.1 mg(Pt) cm(-2)), the Pt/FeN4-C catalyst achieved a mass activity of 0.451 A mg(Pt)(-1) and retained 80% of the initial values after 30 000 voltage cycles (0.60 to 0.95 V), exceeding DOE 2020 targets. Furthermore, the Pt3Co/FeN4 catalyst achieved significantly enhanced performance and durability concerning initial mass activity (0.72 A mg(Pt)(-1)), power density (824 mW cm(-2) at 0.67 V), and stability (23 mV loss at 1.0 A cm(-2)). The approach to exploring the synergy between PGM and PGM-free Fe-N-C catalysts provides a new direction to design advanced catalysts for hydrogen fuel cells and various electrocatalysis processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2021, "Volume": 14, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4948, "End Page": 4960, "Article Number": null, "DOI": "10.1039/d1ee01675j", "DOI Link": "http://dx.doi.org/10.1039/d1ee01675j", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680105800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, Y; Zhang, YF; Wang, ZH; Gao, WC; Jia, P; Zhang, D; Yang, CL; Li, YB; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yan; Zhang, Yongfeng; Wang, Zhonghao; Gao, Weichen; Jia, Peng; Zhang, Dan; Yang, Chaolong; Li, Youbing; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitation-Dependent Long-Life Luminescent Polymeric Systems under Ambient Conditions", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic room temperature luminescent materials present a unique phosphorescence emission with a long lifetime. However, many of these materials only emit single blue or green color in spite of external stimulation, and their color tunability is limited. Herein, we report a rational design to extend the emission color range from blue to red by controlling the doping of simple pyrene derivatives into a robust polymer matrix. The integration of these pyrene molecules into the polymer films enhances the intersystem crossing pathway, decreases the first triplet level of the system, and ensures the films show a sensitive response to excitation energy, finally yielding excitation-dependent long-life luminescent polymeric systems under ambient conditions. These materials were used to construct anti-counterfeiting patterns with multicolor interconversion, presenting a promising application potential in the field of information security.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2020, "Volume": 59, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9967, "End Page": 9971, "Article Number": null, "DOI": "10.1002/anie.201912102", "DOI Link": "http://dx.doi.org/10.1002/anie.201912102", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493875800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CY; Xia, JL; Cui, CY; Pollard, TP; Vatamanu, J; Faraone, A; Dura, JA; Tyagi, M; Kattan, A; Thimsen, E; Xu, JJ; Song, WT; Hu, EY; Ji, X; Hou, SY; Zhang, XY; Ding, MS; Hwang, S; Su, D; Ren, Y; Yang, XQ; Wang, H; Borodin, O; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chongyin; Xia, Jiale; Cui, Chunyu; Pollard, Travis P.; Vatamanu, Jenel; Faraone, Antonio; Dura, Joseph A.; Tyagi, Madhusudan; Kattan, Alex; Thimsen, Elijah; Xu, Jijian; Song, Wentao; Hu, Enyuan; Ji, Xiao; Hou, Singyuk; Zhang, Xiyue; Ding, Michael S. S.; Hwang, Sooyeon; Su, Dong; Ren, Yang; Yang, Xiao-Qing; Wang, Howard; Borodin, Oleg; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-temperature zinc batteries with high-entropy aqueous electrolyte", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrification of transportation and rising demand for grid energy storage continue to build momentum around batteries across the globe. However, the supply chain of Li-ion batteries is exposed to the increasing challenges of resourcing essential and scarce materials. Therefore, incentives to develop more sustainable battery chemistries are growing. Here we show an aqueous ZnCl2 electrolyte with introduced LiCl as supporting salt. Once the electrolyte is optimized to Li2ZnCl4.9H(2)O, the assembled Zn-air battery can sustain stable cycling over the course of 800 hours at a current density of 0.4 mA cm-2 between -60 degrees C and +80 degrees C, with 100% Coulombic efficiency for Zn stripping/plating. Even at -60 degrees C, > 80% of room-temperature power density can be retained. Advanced characterization and theoretical calculations reveal a high-entropy solvation structure that is responsible for the excellent performance. The strong acidity allows ZnCl2 to accept donated Cl- ions to form ZnCl42- anions, while water molecules remain within the free solvent network at low salt concentration or coordinate with Li ions. Our work suggests an effective strategy for the rational design of electrolytes that could enable next-generation Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 325, "End Page": 335, "Article Number": null, "DOI": "10.1038/s41893-022-01028-x", "DOI Link": "http://dx.doi.org/10.1038/s41893-022-01028-x", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913832800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Darago, LE; Aubrey, ML; Yu, CJ; Gonzalez, MI; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Darago, Lucy E.; Aubrey, Michael L.; Yu, Chung Jui; Gonzalez, Miguel I.; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A three-dimensional network solid composed of Fe-III centers and paramagnetic semiquinoid linkers, (NBu4)(2)-Fe-2(III)(dhbq)(3) (dhbq(2-/3-) = 2,5-dioxidobenzoquinone/1,2-dioxido-4,5-semiquinone), is shown to exhibit a conductivity of 0.16 +/- 0.01 S/cm at 298 K, one of the highest values yet observed for a metal organic framework (MOF). The origin of this electronic conductivity is determined to be ligand mixed-valency, which is characterized using a suite of spectroscopic techniques, slow-scan cyclic voltammetry, and variable-temperature conductivity and magnetic susceptibility measurements. Importantly, UV-vis-NIR diffuse reflectance measurements reveal the first observation of Robin-Day Class II/III mixed valency in a MOP. Pursuit of stoichiometric control over the ligand redox states resulted in synthesis of the reduced framework material Na-0.9(NBu4)(1.8)Fe-2(III)(dhbq)(3). Differences in electronic conductivity and magnetic ordering temperature between the two compounds are investigated and correlated to the relative ratio of the two different ligand redox states. Overall, the transition metal semiquinoid system is established as a particularly promising scaffold for achieving tunable long-range electronic communication in MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2015, "Volume": 137, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15703, "End Page": 15711, "Article Number": null, "DOI": "10.1021/jacs.5b10385", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b10385", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367562800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Yu, GT; Ai, X; Yan, WS; Duan, HL; Chen, W; Li, XT; Wang, T; Zhang, CH; Huang, XR; Chen, JS; Zou, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Lan; Yu, Guangtao; Ai, Xuan; Yan, Wensheng; Duan, Hengli; Chen, Wei; Li, Xiaotian; Wang, Ting; Zhang, Chenghui; Huang, Xuri; Chen, Jie-Sheng; Zou, Xiaoxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widespread use of proton exchange membrane water electrolysis requires the development of more efficient electrocatalysts containing reduced amounts of expensive iridium for the oxygen evolution reaction (OER). Here we present the identification of 6H-phase SrIrO3 perovskite (6H-SrIrO3) as a highly active electrocatalyst with good structural and catalytic stability for OER in acid. 6H-SrIrO3 contains 27.1 wt% less iridium than IrO2, but its iridium mass activity is about 7 times higher than IrO2, a benchmark electrocatalyst for the acidic OER. 6H-SrIrO3 is the most active catalytic material for OER among the iridium-based oxides reported recently, based on its highest iridium mass activity. Theoretical calculations indicate that the existence of face-sharing octahedral dimers is mainly responsible for the superior activity of 6H-SrIrO3 thanks to the weakened surface Ir-O binding that facilitates the potential-determining step involved in the OER (i.e., O* + H2O -> HOO* + H+ + e(-)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5236, "DOI": "10.1038/s41467-018-07678-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07678-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452633000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, MQ; Yun, JH; Cai, ML; Jiao, YL; Bernhardt, PV; Zhang, M; Wang, Q; Du, AJ; Wang, HX; Liu, G; Wang, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Miaoqiang; Yun, Jung-Ho; Cai, Molang; Jiao, Yalong; Bernhardt, Paul V.; Zhang, Meng; Wang, Qiong; Du, Aijun; Wang, Hongxia; Liu, Gang; Wang, Lianzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic-inorganic bismuth (III)-based material: A lead-free, air-stable and solution-processable light-absorber beyond organolead perovskites", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methylammonium bismuth (III) iodide single crystals and films have been developed and investigated. We have further presented the first demonstration of using this organic-inorganic bismuth-based material to replace lead/tin-based perovskite materials in solution-processable solar cells. The organic-inorganic bismuth-based material has advantages of non-toxicity, ambient stability, and low-temperature solution-processability, which provides a promising solution to address the toxicity and stability challenges in organolead- and organotin-based perovskite solar cells. We also demonstrated that trivalent metal cation-based organic-inorganic hybrid materials can exhibit photovoltaic effect, which may inspire more research work on developing and applying organic-inorganic hybrid materials beyond divalent metal cations (Pb (II) and Sn (II)) for solar energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 692, "End Page": 702, "Article Number": null, "DOI": "10.1007/s12274-015-0948-y", "DOI Link": "http://dx.doi.org/10.1007/s12274-015-0948-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371797000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, QH; Guo, QB; Chen, Q; Zhao, XX; Pennycook, SJ; Chen, HR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qiuhong; Guo, Qiangbing; Chen, Qian; Zhao, Xiaoxu; Pennycook, Stephen J.; Chen, Hangrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient 2D NIR-II Photothermal Agent with Fenton Catalytic Activity for Cancer Synergistic Photothermal-Chemodynamic Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) has emerged as a promising cancer therapeutic modality with high therapeutic specificity, however, its therapeutic effectiveness is limited by available high-efficiency photothermal agents (PTAs), especially in the second near-infrared (NIR-II) biowindow. Here, based on facile liquid-exfoliated FePS3 nullosheets, a highly efficient NIR-II PTA with its photothermal conversion efficiency of up to 43.3% is demonstrated, which is among the highest reported levels in typical PTAs. More importantly, such Fe-based 2D nullosheets also show superior Fenton catalytic activity facilitated by their ultrahigh specific surface area, simultaneously enabling cancer chemodynamic therapy (CDT). Impressively, the efficiency of CDT could be further remarkably enhanced by its photothermal effect, leading to cancer synergistic PTT/CDT. Both in vitro and in vivo studies reveal a highly efficient tumor ablation under NIR-II light irradiation. This work provides a paradigm for cancer CDT and PTT in the NIR-II biowindow via a single 2D nulloplatform with desired therapeutic effect. Furthermore, with additional possibilities for magnetic resonullce imaging, photoacoustic tomography, as well as drug loading, this Fe-based 2D material could potentially serve as a 2D all-in-one theranostic nulloplatform.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902576, "DOI": "10.1002/advs.201902576", "DOI Link": "http://dx.doi.org/10.1002/advs.201902576", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514485100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sidhik, S; Wang, YF; De Siena, M; Asadpour, R; Torma, AJ; Terlier, T; Ho, K; Li, WB; Puthirath, AB; Shuai, XT; Agrawal, A; Traore, B; Jones, M; Giridharagopal, R; Ajayan, PM; Strzalka, J; Ginger, DS; Katan, C; Alam, MA; Even, J; Kanatzidis, MG; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sidhik, Siraj; Wang, Yafei; De Siena, Michael; Asadpour, Reza; Torma, Andrew J.; Terlier, Tanguy; Ho, Kevin; Li, Wenbin; Puthirath, Anulld B.; Shuai, Xinting; Agrawal, Ayush; Traore, Boubacar; Jones, Matthew; Giridharagopal, Rajiv; Ajayan, Pulickel M.; Strzalka, Joseph; Ginger, David S.; Katan, Claudine; Alam, Muhammad Ashraful; Even, Jacky; Kanatzidis, Mercouri G.; Mohite, Aditya D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deterministic fabrication of 3D/2D perovskite bilayer stacks for durable and efficient solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing solution-processed heterostructures is a long-enduring challenge in halide perovskites because of solvent incompatibilities that disrupt the underlying layer. By leveraging the solvent dielectric constant and Gutmann donor number, we could grow phase-pure two-dimensional (2D) halide perovskite stacks of the desired composition, thickness, and bandgap onto 3D perovskites without dissolving the underlying substrate. Characterization reveals a 3D-2D transition region of 20 nullometers mainly determined by the roughness of the bottom 3D layer. Thickness dependence of the 2D perovskite layer reveals the anticipated trends for n-i-p and p-i-n architectures, which is consistent with band alignment and carrier transport limits for 2D perovskites. We measured a photovoltaic efficiency of 24.5%, with exceptional stability of T-99 (time required to preserve 99% of initial photovoltaic efficiency) of >2000 hours, implying that the 3D/2D bilayer inherits the intrinsic durability of 2D perovskite without compromising efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 377, "Issue": 6613, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1425, "End Page": 1430, "Article Number": null, "DOI": "10.1126/science.abq7652", "DOI Link": "http://dx.doi.org/10.1126/science.abq7652", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000887934300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, LM; Li, JH; Cai, B; Song, JZ; Zhang, FJ; Fang, T; Zeng, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Leimeng; Li, Jianhai; Cai, Bo; Song, Jizhong; Zhang, Fengjuan; Fang, Tao; Zeng, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A bilateral interfacial passivation strategy promoting efficiency and stability of perovskite quantum dot light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite quantum-dot-based light-emitting diodes (QLEDs) possess the features of wide gamut and real color expression, which have been considered as candidates for high-quality lightings and displays. However, massive defects are prone to be reproduced during the quantum dot (QD) film assembly, which would sorely affect carrier injection, transportation and recombination, and finally degrade QLED performances. Here, we propose a bilateral passivation strategy through passivating both top and bottom interfaces of QD film with organic molecules, which has drastically enhanced the efficiency and stability of perovskite QLEDs. Various molecules were applied, and comparison experiments were conducted to verify the necessity of passivation on both interfaces. Eventually, the passivated device achieves a maximum external quantum efficiency (EQE) of 18.7% and current efficiency of 75cdA(-1). Moreover, the operational lifetime of QLEDs is enhanced by 20-fold, reaching 15.8h. These findings highlight the importance of interface passivation for efficient and stable QD-based optoelectronic devices. Perovskite quantum-dots are promising candidates for light-emitting diodes but the defects limit the device performance. Here Xu et al. show a passivation strategy to reduce the defect density at both interfaces, which increases the external quantum efficiency (EQE) and lifetime by more than 2-fold and 20-fold, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3902, "DOI": "10.1038/s41467-020-17633-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17633-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561120500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SQ; Xu, L; Wang, AC; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Shiquan; Xu, Liang; Chi Wang, Aurelia; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying electron-transfer in liquid-solid contact electrification and the formation of electric double-layer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Contact electrification (CE) has been known for more than 2600 years but the nature of charge carriers and their transfer mechanisms still remain poorly understood, especially for the cases of liquid-solid CE. Here, we study the CE between liquids and solids and investigate the decay of CE charges on the solid surfaces after liquid-solid CE at different thermal conditions. The contribution of electron transfer is distinguished from that of ion transfer on the charged surfaces by using the theory of electron thermionic emission. Our study shows that there are both electron transfer and ion transfer in the liquid-solid CE. We reveal that solutes in the solution, pH value of the solution and the hydrophilicity of the solid affect the ratio of electron transfers to ion transfers. Further, we propose a two-step model of electron or/and ion transfer and demonstrate the formation of electric double-layer in liquid-solid CE.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 554, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 399, "DOI": "10.1038/s41467-019-14278-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14278-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511940400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, JQ; Guo, CX; Zhu, YH; Chen, SM; Song, L; Jaroniec, M; Zheng, Y; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Jieqiong; Guo, Chunxian; Zhu, Yihan; Chen, Shuangming; Song, Li; Jaroniec, Mietek; Zheng, Yao; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Redistribution-Enhanced nullocrystalline Ru@IrOx Electrocatalysts for Oxygen Evolution in Acidic Media", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving high activity and long-term stability is a major challenge in the design of catalysts. In particular, the oxygen evolution reaction (OER) in acidic media, which plays a key role in proton exchange membrane electrolyzers for fast hydrogen fuel generation, seriously suffers from rapid degradation of catalysts as a result of the harsh acidic and oxidative conditions. Here, we report a rational design strategy for the fabrication of a heterostructured OER electrocatalyst (Ru@IrOx) that has unique physicochemical properties and in which a strong charge redistribution exists between a highly strained ruthenium core and a partially oxidized iridium shell across the metal-metal oxide heterojunction. The increased valence of the iridium shell and the decreased valence of the ruthenium core activate a synergistic electronic and structural interaction, which results in the enhanced activity and stability of the catalyst compared with the majority of the state-of-the-art ruthenium- and iridium-based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 445, "End Page": 459, "Article Number": null, "DOI": "10.1016/j.chempr.2018.11.010", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.11.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458660100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sassi, S; Candolfi, C; Vaney, JB; Ohorodniichuk, V; Masschelein, P; Dauscher, A; Lenoir, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sassi, S.; Candolfi, C.; Vaney, J. -B.; Ohorodniichuk, V.; Masschelein, P.; Dauscher, A.; Lenoir, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assessment of the thermoelectric performance of polycrystalline p-type SnSe", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the evaluation of the thermoelectric performance of polycrystalline p-type SnSe, a material in which unprecedented values of the thermoelectric figure of merit ZT have been recently discovered in single crystals. Besides anisotropic transport properties, our results confirm that this compound exhibits intrinsically very low thermal conductivity values. The electrical properties show trends typical of lightly doped, intrinsic semiconductors with thermopower values reaching 500 mu V K-1 in a broad temperature range. An orthorhombic-to-orthorhombic transition sets in at 823 K, a temperature at which the power factor reaches its maximum value. A maximum ZT of 0.5 was obtained at 823 K, suggesting that proper optimization of the transport properties of SnSe might lead to higher ZT values. These findings indicate that this system represents an interesting experimental platform for the search of highly efficient thermoelectric materials. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2014, "Volume": 104, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 212105, "DOI": "10.1063/1.4880817", "DOI Link": "http://dx.doi.org/10.1063/1.4880817", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337143000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tutusaus, O; Mohtadi, R; Arthur, TS; Mizuno, F; Nelson, EG; Sevryugina, YV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tutusaus, Oscar; Mohtadi, Rana; Arthur, Timothy S.; Mizuno, Fuminori; Nelson, Emily G.; Sevryugina, Yulia V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Efficient Halogen-Free Electrolyte for Use in Rechargeable Magnesium Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unlocking the full potential of rechargeable magnesium batteries has been partially hindered by the reliance on chloride-based complex systems. Despite the high anodic stability of these electrolytes, they are corrosive toward metallic battery components, which reduce their practical electrochemical window. Following on our new design concept involving boron cluster anions, monocarborane CB11H12- produced the first halogen-free, simple-type Mg salt that is compatible with Mg metal and displays an oxidative stability surpassing that of ether solvents. Owing to its inertness and non-corrosive nature, the Mg(CB11H12)(2)/tetraglyme (MMC/G4) electrolyte system permits standardized methods of high-voltage cathode testing that uses a typical coin cell. This achievement is a turning point in the research and development of Mg electrolytes that has deep implications on realizing practical rechargeable Mg batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2015, "Volume": 54, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7900, "End Page": 7904, "Article Number": null, "DOI": "10.1002/anie.201412202", "DOI Link": "http://dx.doi.org/10.1002/anie.201412202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356886600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hanikel, N; Prévot, MS; Fathieh, F; Kapustin, EA; Lyu, H; Wang, HZ; Diercks, NJ; Glover, TG; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hanikel, Nikita; Prevot, Mathieu S.; Fathieh, Farhad; Kapustin, Eugene A.; Lyu, Hao; Wang, Haoze; Diercks, Nicolas J.; Glover, T. Grant; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid Cycling and Exceptional Yield in a Metal-Organic Framework Water Harvester", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sorbent-assisted water harvesting from air represents an attractive way to address water scarcity in arid climates. Hitherto, sorbents developed for this technology have exclusively been designed to perform one water harvesting cycle (WHC) per day, but the productivities attained with this approach cannot reasonably meet the rising demand for drinking water. This work shows that a microporous aluminum-based metal-organic framework, MOF-303, can perform an adsorption- desorption cycle within minutes under a mild temperature swing, which opens the way for high-productivity water harvesting through rapid, continuous WHCs. Additionally, the favorable dynamic water sorption properties of MOF-303 allow it to outperform other commercial sorbents displaying excellent steady-state characteristics under similar experimental conditions. Finally, these findings are implemented in a new water harvester capable of generating 1.3 L kg(MOF)(-1 )day(-1) in an indoor arid environment (32% relative humidity, 27 degrees C) and 0.7 L kg(MOF)(-1 )day(-1) in the Mojave Desert (in conditions as extreme as 10% RH, 27 degrees C), representing an improvement by 1 order of magnitude over previously reported devices. This study demonstrates that creating sorbents capable of rapid water sorption dynamics, rather than merely focusing on high water capacities, is crucial to reach water production on a scale matching human consumption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1699, "End Page": 1706, "Article Number": null, "DOI": "10.1021/acscentsci.9b00745", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00745", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492698300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cangialosi, A; Yoon, C; Liu, J; Huang, Q; Guo, JK; Nguyen, TD; Gracias, DH; Schulman, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cangialosi, Angelo; Yoon, ChangKyu; Liu, Jiayu; Huang, Qi; Guo, Jingkai; Nguyen, Thao D.; Gracias, David H.; Schulman, Rebecca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DNA sequence-directed shape change of photopatterned hydrogels via high-degree swelling", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape-changing hydrogels that can bend, twist, or actuate in response to external stimuli are critical to soft robots, programmable matter, and smart medicine. Shape change in hydrogels has been induced by global cues, including temperature, light, or pH. Here we demonstrate that specific DNA molecules can induce 100-fold volumetric hydrogel expansion by successive extension of cross-links. We photopattern up to centimeter-sized gels containing multiple domains that undergo different shape changes in response to different DNA sequences. Experiments and simulations suggest a simple design rule for controlled shape change. Because DNA molecules can be coupled to molecular sensors, amplifiers, and logic circuits, this strategy introduces the possibility of building soft devices that respond to diverse biochemical inputs and autonomously implement chemical control programs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2017, "Volume": 357, "Issue": 6356, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1126, "End Page": 1129, "Article Number": null, "DOI": "10.1126/science.aan3925", "DOI Link": "http://dx.doi.org/10.1126/science.aan3925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410639800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, LL; Lu, YY; Zhu, ZX; Shao, JX; Yao, HB; Wang, SG; Zhang, TW; Ni, Y; Wang, XX; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Lei-Lei; Lu, Yu-Yang; Zhu, Zheng-Xin; Shao, Jia-Xin; Yao, Hong-Bin; Wang, Shaogang; Zhang, Tian-Wen; Ni, Yong; Wang, Xiu-Xia; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely fast-charging lithium ion battery enabled by dual-gradient structure design", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extremely fast-charging lithium-ion batteries are highly desirable to shorten the recharging time for electric vehicles, but it is hampered by the poor rate capability of graphite anodes. Here, we present a previously unreported particle size and electrode porosity dual-gradient structure design in the graphite anode for achieving extremely fast-charging lithium ion battery under strict electrode conditions. We develop a polymer binder-free slurry route to construct this previously unreported type particle size-porosity dual-gradient structure in the practical graphite anode showing the extremely fast-charging capability with 60% of recharge in 10 min. On the basis of dual-gradient graphite anode, we demonstrate extremely fast-charging lithium ion battery realizing 60% recharge in 6 min and high volumetric energy density of 701 Wh liter(-1) at the high charging rate of 6 C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 8, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm6624", "DOI": "10.1126/sciadv.abm6624", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm6624", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790076700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, HB; Gao, Y; Boott, CE; Gould, OEC; Harniman, RL; Miles, MJ; Webb, SED; Winnik, MA; Manners, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Huibin; Gao, Yang; Boott, Charlotte E.; Gould, Oliver E. C.; Harniman, Robert L.; Miles, Mervyn J.; Webb, Stephen E. D.; Winnik, Mitchell A.; Manners, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uniform patchy and hollow rectangular platelet micelles from crystallizable polymer blends", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The preparation of colloidally stable, self-assembled materials with tailorable solid or hollow two-dimensional (2D) structures represents a major challenge. We describe the formation of uniform, monodisperse rectangular platelet micelles of controlled size by means of seeded-growth methods that involve the addition of blends of crystalline-coil block copolymers and the corresponding crystalline homopolymer to cylindrical micelle seeds. Sequential addition of different blends yields solid platelet block comicelles with concentric rectangular patches with distinct coronal chemistries. These complex nullo-objects can be subject to spatially selective processing that allows their disassembly to form perforated platelets, such as well-defined hollow rectangular rings. The solid and hollow 2D micelles provide a tunable platform for further functionalization and potential for a variety of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2016, "Volume": 352, "Issue": 6286, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 697, "End Page": 701, "Article Number": null, "DOI": "10.1126/science.aad9521", "DOI Link": "http://dx.doi.org/10.1126/science.aad9521", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375417100035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, MQ; Xu, YJ; Lu, WH; Zeng, KY; Zhu, H; Xu, QH; Ho, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Min-Quan; Xu, Yi-Jun; Lu, Wanheng; Zeng, Kaiyang; Zhu, Hai; Xu, Qing-Hua; Ho, Ghim Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-surface charge exfoliation and electrostatically coordinated 2D hetero-layered hybrids", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At present, the technological groundwork of atomically thin two-dimensional (2D) hetero-layered structures realized by successive thin film epitaxial growth is in principle constrained by lattice matching prerequisite as well as low yield and expensive production. Here, we artificially coordinate ultrathin 2D hetero-layered metal chalcogenides via a highly scalable self-surface charge exfoliation and electrostatic coupling approach. Specifically, bulk metal chalcogenides are spontaneously exfoliated into ultrathin layers in a surfactant/intercalator-free medium, followed by unconstrained electrostatic coupling with a dissimilar transition metal dichalcogenide, MoSe2, into scalable hetero-layered hybrids. Accordingly, surface and interfacial-dominated photocatalysis reactivity is used as an ideal testbed to verify the reliability of diverse 2D ultrathin hetero-layered materials that reveal high visible-light photoreactivity, efficient charge transfer and intimate contact interface for stable cycling and storage purposes. Such a synthetic approach renders independent thickness and composition control anticipated to advance the development of 'design-and-build' 2D layered heterojunctions for large-scale exploration and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14224, "DOI": "10.1038/ncomms14224", "DOI Link": "http://dx.doi.org/10.1038/ncomms14224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393073800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Z; Su, XL; Deng, RG; Stoumpos, C; Xie, HY; Liu, W; Yan, YG; Hao, SQ; Uher, C; Wolverton, C; Kanatzidis, MG; Tang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zheng; Su, Xianli; Deng, Rigui; Stoumpos, Constantinos; Xie, Hongyao; Liu, Wei; Yan, Yonggao; Hao, Shiqiang; Uher, Ctirad; Wolverton, Chris; Kanatzidis, Mercouri G.; Tang, Xinfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rhombohedral to Cubic Conversion of GeTe via MnTe Alloying Leads to Ultralow Thermal Conductivity, Electronic Band Convergence, and High Thermoelectric Performance", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, a series of Ge1-xMnxTe (x = 0-0.21) compounds were prepared by a melting-quenching- annealing process combined with spark plasma sintering (SPS). The effect of alloying MnTe into GeTe on the structure and thermoelectric properties of Ge1-xMnxTe is profound. With increasing content of MnTe, the structure of the Ge1-xMnxTe compounds gradually changes from rhombohedral to cubic, and the known R3m to Fm-3m phase transition temperature of GeTe moves from 700 K closer to room temperature. First-principles density functional theory calculations show that alloying MnTe into GeTe decreases the energy difference between the light and heavy valence bands in both the R3m and Fm-3m structures, enhancing a multiband character of the valence band edge that increases the hole carrier effective mass. The effect of this band convergence is a significant enhancement in the carrier effective mass from 1.44 m(0) (GeTe) to 6.15 m(0) (Ge0.85Mn0.15Te). In addition, alloying with MnTe decreases the phonon relaxation time by enhancing alloy scattering, reduces the phonon velocity, and increases Ge vacancies all of which result in an ultralow lattice thermal conductivity of 0.13 W m(-1) K-1 at 823 K. Subsequent doping of the Ge0.9Mn0.1Te compositions with Sb lowers the typical very high hole carrier concentration and brings it closer to its optimal value enhancing the power factor, which combined with the ultralow thermal conductivity yields a maximum ZT value of 1.61 at 823 K (for Ge0.86Mn0.10Sb0.04Te). The average ZT value of the compound over the temperature range 400-800 K is 1.09, making it the best GeTe-based thermoelectric material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 140, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2673, "End Page": 2686, "Article Number": null, "DOI": "10.1021/jacs.7b13611", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b13611", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426143800040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, B; Li, ZF; Xu, GZ; Li, H; Hou, ZP; Liu, EK; Xi, XK; Xu, F; Yao, Y; Wang, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Bei; Li, Zefang; Xu, Guizhou; Li, Hang; Hou, Zhipeng; Liu, Enke; Xi, Xuekui; Xu, Feng; Yao, Yuan; Wang, Wenhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Magnetic Skyrmion Bubbles in a van der Waals Ferromagnet Fe3GeTe2", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) van der Waals (vdW) magnetic materials have recently been introduced as a new horizon in materials science, and they enable potential applications for next-generation spintronic devices. Here, in this communication, the observations of stable Bloch-type magnetic skyrmions in single crystals of 2D vdW Fe3GeTe2 (FGT) are reported by using in situ Lorentz transmission electron microscopy (TEM). We find the ground-state magnetic stripe domains in FGT transform into skyrmion bubbles when an external magnetic field is applied perpendicularly to the (001) thin plate with temperatures below the Curie temperature T-c. Most interestingly, a hexagonal lattice of skyrmion bubbles is obtained via field-cooling manipulation with magnetic field applied along the [001] direction. Owing to their topological stability, the skyrmion bubble lattices are stable to large field-cooling tilted angles and further reproduced by utilizing the micromagnetic simulations. These observations directly demonstrate that the 2D vdW FGT possesses a rich variety of topological spin textures, being of great promise for future applications in the field of spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 868, "End Page": 873, "Article Number": null, "DOI": "10.1021/acs.nullolett.9b03453", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.9b03453", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514255400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, CM; Yu, HS; Lee, S; Peng, RM; Takeuchi, I; Li, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Changming; Yu, Heshan; Lee, Seokhyeong; Peng, Ruoming; Takeuchi, Ichiro; Li, Mo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programmable phase-change metasurfaces on waveguides for multimode photonic convolutional neural network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neuromorphic photonics has recently emerged as a promising hardware accelerator, with significant potential speed and energy advantages over digital electronics for machine learning algorithms, such as neural networks of various types. Integrated photonic networks are particularly powerful in performing analog computing of matrix-vector multiplication (MVM) as they afford unparalleled speed and bandwidth density for data transmission. Incorporating nonvolatile phase-change materials in integrated photonic devices enables indispensable programming and in-memory computing capabilities for on-chip optical computing. Here, we demonstrate a multimode photonic computing core consisting of an array of programable mode converters based on on-waveguide metasurfaces made of phase-change materials. The programmable converters utilize the refractive index change of the phase-change material Ge2Sb2Te5 during phase transition to control the waveguide spatial modes with a very high precision of up to 64 levels in modal contrast. This contrast is used to represent the matrix elements, with 6-bit resolution and both positive and negative values, to perform MVM computation in neural network algorithms. We demonstrate a prototypical optical convolutional neural network that can perform image processing and recognition tasks with high accuracy. With a broad operation bandwidth and a compact device footprint, the demonstrated multimode photonic core is promising toward large-scale photonic neural networks with ultrahigh computation throughputs. Integrated optical computing requires programmable photonic and nonlinear elements. The authors demonstrate a phase-change metasurface mode converter, which can be programmed to control the waveguide mode contrast, and build an optical convolutional neural network to perform image processing tasks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 96, "DOI": "10.1038/s41467-020-20365-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20365-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665636000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasmussen, M; Abdellaoui, S; Minteer, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasmussen, Michelle; Abdellaoui, Sofiene; Minteer, Shelley D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enzymatic biofuel cells: 30 years of critical advancements", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymatic biofiiel cells are bioelectronic devices that utilize oxidoreductase enzymes to catalyze the conversion of chemical energy into electrical energy. This review details the advancements in the field of enzymatic biofuel cells over the last 30 years. These advancements include strategies for improving operational stability and electrochemical performance, as well as device fabrication for a variety of applications, including implantable biofuel cells and self-powered sensors. It also discusses the current scientific and engineering challenges in the field that will need to be addressed in the future for commercial viability of the technology. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2016, "Volume": 76, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 91, "End Page": 102, "Article Number": null, "DOI": "10.1016/j.bios.2015.06.029", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2015.06.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364895000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HC; Fu, X; Tang, Y; Wang, H; Zhang, CF; Yu, WW; Wang, XY; Zhang, Y; Xiao, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huichao; Fu, Xu; Tang, Ying; Wang, Hua; Zhang, Chunfeng; Yu, William W.; Wang, Xiaoyong; Zhang, Yu; Xiao, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase segregation due to ion migration in all-inorganic mixed-halide perovskite nullocrystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor mixed-halide perovskites featured with a tunable energy bandgap are ideal candidates for light absorbers in tandem solar cells as well as fluorescent materials in light-emitting diodes and nulloscale lasers. These device advancements are currently hindered by the light-induced phase segregation effect, whereby ion migration would yield smaller-bandgap domains with red-shifted photoluminescence. Here we show that upon laser excitation all-inorganic mixed-halide nullocrystals unexpectedly exhibit a blue shift in the photoluminescence peak that can revert back in the dark, thus depicting the processes of ion migration out of and back to the originally excited nullocrystals. Interestingly, this reversible photoluminescence shift can also be induced by electrical biasing of mixed-halide nullocrystals without the injection of charge carriers. The above findings suggest that it is the local electric field that breaks the ionic bonds in mixed-halide nullocrystals, which could be a universal origin for light-induced phase segregation observed in other mixed-halide perovskite materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1088, "DOI": "10.1038/s41467-019-09047-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09047-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460410300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XY; Chen, WC; Qian, QR; Huang, HT; Chen, YM; Wang, ZQ; Chen, QH; Yang, J; Li, J; Mai, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaoyan; Chen, Weichen; Qian, Qingrong; Huang, Haitao; Chen, Yuming; Wang, Ziqiang; Chen, Qinghua; Yang, Jing; Li, Ju; Mai, Yiu-Wing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrospinning-Based Strategies for Battery Materials", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrospinning is a popular technique to prepare 1D tubular/fibrous nullomaterials that assemble into 2D/3D architectures. When combined with other material processing techniques such as chemical vapor deposition and hydrothermal treatment, electrospinning enables powerful synthesis strategies that can tailor structural and compositional features of energy storage materials. Herein, a simple description is given of the basic electrospinning technique and its combination with other synthetic approaches. Then its employment in the preparation of frameworks and scaffolds with various functions is introduced, e.g., a graphitic tubular network to enhance the electronic conductivity and structural integrity of the electrodes. Current developments in 3D scaffold structures as a host for Li metal anodes, sulfur cathodes, membrane separators, or as a 3D matrix for polymeric solid-state electrolytes for rechargeable batteries are presented. The use of 1D electrospun nullomaterials as a nulloreactor for in situ transmission electron microscopy (TEM) observations of the mechanisms of materials synthesis and electrochemical reactions is summarized, which has gained popularity due to easy mechanical manipulation, electron transparency, electronic conductivity, and the easy prepositioning of complex chemical ingredients by liquid-solution processing. Finally, an outlook on industrial production and future challenges for energy storage materials is given.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000845, "DOI": "10.1002/aenm.202000845", "DOI Link": "http://dx.doi.org/10.1002/aenm.202000845", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542185500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SY; Dong, RJ; Musteata, VE; Kim, J; Rangnekar, ND; Johnson, JR; Marshall, BD; Chisca, S; Xu, J; Hoy, S; McCool, BA; Nunes, SP; Jiang, ZW; Livingston, AG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Siyao; Dong, Ruijiao; Musteata, Valentina-Elena; Kim, Jihoon; Rangnekar, Neel D.; Johnson, J. R.; Marshall, Bennett D.; Chisca, Stefan; Xu, Jia; Hoy, Scott; McCool, Benjamin A.; Nunes, Suzana P.; Jiang, Zhiwei; Livingston, Andrew G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrophobic polyamide nullofilms provide rapid transport for crude oil separation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrocarbon separation relies on energy-intensive distillation. Membrane technology can offer an energy-efficient alternative but requires selective differentiation of crude oil molecules with rapid liquid transport. We synthesized multiblock oligomer amines, which comprised a central amine segment with two hydrophobic oligomer blocks, and used them to fabricate hydrophobic polyamide nullofilms by interfacial polymerization from self-assembled vesicles. These polyamide nullofilms provide transport of hydrophobic liquids more than 100 times faster than that of conventional hydrophilic counterparts. In the fractionation of light crude oil, manipulation of the film thickness down to similar to 10 nullometers achieves permeance one order of magnitude higher than that of current state-of-the-art hydrophobic membranes while retaining comparable size- and class-based separation. This high permeance can markedly reduce plant footprint, which expands the potential for using membranes made of ultrathin nullofilms in crude oil fractionation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 377, "Issue": 6614, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1555, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abq0598", "DOI Link": "http://dx.doi.org/10.1126/science.abq0598", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891713300031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Cheng, YH; You, JX; Zhang, JM; Yin, CC; Zhang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xin; Cheng, Yaohui; You, Jingxuan; Zhang, Jinming; Yin, Chunchun; Zhang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong phosphorescence cellulose with excellent anti-bacterial, water-resistant and ease-to-process performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we present a phosphorescent cationized cellulose derivative by simply introducing ionic structures, including cyanomethylimidazolium cations and chloride anions, into cellulose chains. The imidazolium cations with the cyano group and nitrogen element promote intersystem crossing. The cyano-containing cations, chloride anions and hydroxyl groups of cellulose form multiple hydrogen bonding interactions and electrostatic attraction interactions, effectively inhibiting the non-radiative transitions. The resultant cellulose-based RTP material is easily processed into phosphorescent films, fibers, coatings and patterns by using eco-friendly aqueous solution processing strategies. Furthermore, after we construct a cross-linking structure by adding a small amount of glutaraldehyde as the cross-linking agent, the as-fabricated phosphorescent patterns exhibit excellent antibacterial properties and water resistance. Therefore, considering the outstanding biodegradability and sustainability of cellulose materials, cellulose-based easy-to-process RTP materials can act as antibacterial, water-resistant, and eco-friendly phosphorescent patterns, coatings and bulk materials, which have enormous potential in advanced anti-counterfeiting, information encryption, disposable smart labels, etc. Organic room-temperature phosphorescence (RTP) materials often suffer from poor processability because of their crystalline or cross-linked nature. Here, the authors demonstrate phosphorescence in a processable cellulose derivative by introducing cationic groups such as imidazolium cations which are able to promote intersystem crossing and to form hydrogen bonds, inhibiting non-radiative transitions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1117, "DOI": "10.1038/s41467-022-28759-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28759-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763605200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, F; Ding, C; Zhang, YH; Ripolles, TS; Kamisaka, T; Toyoda, T; Hayase, S; Minemoto, T; Yoshino, K; Dai, SY; Yanagida, M; Noguchi, H; Shen, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Feng; Ding, Chao; Zhang, Yaohong; Ripolles, Teresa S.; Kamisaka, Taichi; Toyoda, Taro; Hayase, Shuzi; Minemoto, Takashi; Yoshino, Kenji; Dai, Songyuan; Yanagida, Masatoshi; Noguchi, Hidenori; Shen, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloidal Synthesis of Air-Stable Alloyed CsSn1-xPxI3 Perovskite nullocrystals for Use in Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskite solar cells have demonstrated unprecedented high power conversion efficiencies in the past few years. Now, the universal instability of the perovskites has become the main barrier for this kind of solar cells to realize commercialization. This situation can be even worse for those tin-based perovskites, especially for CsSnI3, because upon exposure to ambient atmosphere the desired black orthorhombic phase CsSnI3 would promptly lose single crystallinity and degrade to the inactive yellow phase, followed by irreversible oxidation into metallic Cs2SnI6. By alloying CsSnI3 with CsPbI3, we herein report the synthesis of alloyed perovskite quantum dot (QD), CsSn1-xPbxI3, which not only can be phase-stable for months in purified colloidal solution but also remains intact even directly exposed to ambient air, far superior to both of its parent CsSnI3 and CsPbI3 QDs. Ultrafast transient absorption spectroscopy studies reveal that the photoexcited electrons in the alloyed QDs can be injected into TiO2 nullocrystals at a fast rate of 1.12 X 10(11) S-1 which enables a high photocurrent generation in solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2017, "Volume": 139, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16708, "End Page": 16719, "Article Number": null, "DOI": "10.1021/jacs.7b08628", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b08628", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416496400043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, Q; Alexandrov, E; Si, DH; Huang, QQ; Fang, ZB; Zhang, Y; Zhang, AA; Qin, WK; Li, YL; Liu, TF; Proserpio, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Qi; Alexandrov, Eugeny, V; Si, Duan-Hui; Huang, Qian-Qian; Fang, Zhi-Bin; Zhang, Yuan; Zhang, An-An; Qin, Wei-Kang; Li, Yu-Lin; Liu, Tian-Fu; Proserpio, Davide M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallization-Prompted Robust Porphyrin-Based Hydrogen-Bonded Organic Frameworks for Photocatalytic CO2 Reduction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Under topological guidance, the self-assembly process based on a tetratopic porphyrin synthon results in a hydrogen-bonded organic framework (HOF) with the predicted square layers topology (sql) but unsatisfied stability. Strikingly, simply introducing a transition metal in the porphyrin center does not change the network topology but drastically causes noticeable change on noncovalent interaction, orbital overlap, and molecular geometry, therefore ultimately giving rise to a series of metalloporphyrinic HOFs with high surface area, and excellent stability (intact after being soaked in boiling water, concentrated HCl, and heated to 270 degrees C). On integrating both photosensitizers and catalytic sites into robust backbones, this series of HOFs can effectively catalyze the photoreduction of CO2 to CO, and their catalytic performances greatly depend on the chelated metal species in the porphyrin centers. This work enriches the library of stable functional HOFs and expands their applications in photocatalytic CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2022, "Volume": 61, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202115854", "DOI": "10.1002/anie.202115854", "DOI Link": "http://dx.doi.org/10.1002/anie.202115854", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773480000048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rajaeifar, MA; Ghadimi, P; Raugei, M; Wu, YF; Heidrich, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rajaeifar, Mohammad Ali; Ghadimi, Pezhman; Raugei, Marco; Wu, Yufeng; Heidrich, Oliver", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and recent developments in supply and value chains of electric vehicle batteries: A sustainability perspective", "Source Title": "RESOURCES CONSERVATION AND RECYCLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) play a key role in advancing electromobility. With an increasing trend in the demand for LIBs, the sustainability prospect of LIBs lifecycle faces many challenges that require proactive approaches. There are various sustainability challenges and risks across the supply and value chains of LIBs from mining, material supplies to Original Equipment Manufacturers (OEMs), users to final disposal. Risks are for example the increased raw material demands as well as some economic risks due to price increment or political instabilities in some countries within the raw material supply chain. Despite the promising research efforts on the performance metrics of LIBs and advancing the technology, the research on the various aspects of sustainability of LIBs and its life cycle are still in its infancy and require closer attention. As the editorial of the Special Issue on sustainable supply and value chains of EV batteries, this article presents some of the most pressing challenges of EV LIBs across the different stages of its life cycle. It covers issues from supply and demand of the battery raw materials, battery manufacturing, use, and end-of-life treatments. Within this context the reported findings of some 20 different research teams from across the globe, the state-of-the-art, technical or policy gaps in EV LIBs research and development are presented, as well as market instruments such as innovative business models, and governmental interventions like subsidies or regulations. We grouped the materials presented into five main themes (1) EV and LIB materials demand projections (2) EV LIBs international trade risk (3) EV battery regulation and adoption (4) EV LIBs life cycle assessment (5) and EV LIBs reverse logistics. We conclude by discussing some future research challenges such as the need for more reliable and applicable prediction models that use accurate data on EV stock and end-of-life EVs. Finally, we argue that more collaboration between academia, manufactures, OEMs and the battery recycling industry is needed to implement successful circular economy strategies to achieve environmentally friendly, flexible and cost-efficient battery supplies, use and recycling processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 180, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106144, "DOI": "10.1016/j.resconrec.2021.106144", "DOI Link": "http://dx.doi.org/10.1016/j.resconrec.2021.106144", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781488300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, XL; Ji, X; Han, FD; Yue, J; Chen, J; Chen, L; Deng, T; Jiang, JJ; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Xiulin; Ji, Xiao; Han, Fudong; Yue, Jie; Chen, Ji; Chen, Long; Deng, Tao; Jiang, Jianjun; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state electrolytes (SSEs) are receiving great interest because their high mechanical strength and transference number could potentially suppress Li dendrites and their high electrochemical stability allows the use of high-voltage cathodes, which enhances the energy density and safety of batteries. However, the much lower critical current density and easier Li dendrite propagation in SSEs than in nonaqueous liquid electrolytes hindered their possible applications. Herein, we successfully suppressed Li dendrite growth in SSEs by in situ forming an LiF-rich solid electrolyte interphase (SEI) between the SSEs and the Li metal. The LiF-rich SEI successfully suppresses the penetration of Li dendrites into SSEs, while the low electronic conductivity and the intrinsic electrochemical stability of LiF block side reactions between the SSEs and Li. The LiF-rich SEI enhances the room temperature critical current density of Li3PS4 to a record-high value of >2 mA cm(-2). Moreover, the Li plating/stripping Coulombic efficiency was escalated from 88% of pristine Li3PS4 to more than 98% for LiF-coated Li3PS4. In situ formation of electronic insulating LiF-rich SEI provides an effective way to prevent Li dendrites in the SSEs, constituting a substantial leap toward the practical applications of next-generation high-energy solid-state Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 635, "Times Cited, All Databases": 684, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau9245", "DOI": "10.1126/sciadv.aau9245", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau9245", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454369600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Su, H; Cui, PX; Cao, YY; Teng, ZY; Zhang, QT; Wang, Y; Feng, YB; Feng, R; Hou, JX; Zhou, XY; Ma, PJ; Hu, HW; Wang, KW; Wang, C; Gan, LY; Zhao, YX; Liu, QH; Zhang, TR; Zheng, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xu; Su, Hui; Cui, Peixin; Cao, Yongyong; Teng, Zhenyuan; Zhang, Qitao; Wang, Yang; Feng, Yibo; Feng, Ran; Hou, Jixiang; Zhou, Xiyuan; Ma, Peijie; Hu, Hanwen; Wang, Kaiwen; Wang, Cong; Gan, Liyong; Zhao, Yunxuan; Liu, Qinghua; Zhang, Tierui; Zheng, Kun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developing Ni single-atom sites in carbon nitride for efficient photocatalytic H2O2 production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic two-electron oxygen reduction to produce high-value hydrogen peroxide (H2O2) is gaining popularity as a promising avenue of research. However, structural evolution mechanisms of catalytically active sites in the entire photosynthetic H2O2 system remains unclear and seriously hinders the development of highly-active and stable H2O2 photocatalysts. Herein, we report a high-loading Ni single-atom photocatalyst for efficient H2O2 synthesis in pure water, achieving an apparent quantum yield of 10.9% at 420nm and a solar-to-chemical conversion efficiency of 0.82%. Importantly, using in situ synchrotron X-ray absorption spectroscopy and Raman spectroscopy we directly observe that initial Ni-N-3 sites dynamically transform into high-valent O-1-Ni-N-2 sites after O-2 adsorption and further evolve to form a key *OOH intermediate before finally forming HOO-Ni-N-2. Theoretical calculations and experiments further reveal that the evolution of the active sites structure reduces the formation energy barrier of *OOH and suppresses the O=O bond dissociation, leading to improved H2O2 production activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7115, "DOI": "10.1038/s41467-023-42887-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42887-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142811000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, KH; Wang, XL; Qiu, JL; Wang, Y; Yang, Q; Xu, JJ; Yu, XQ; Li, H; Huang, XJ; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Kaihui; Wang, Xuelong; Qiu, Jiliang; Wang, Yi; Yang, Qi; Xu, Jingjing; Yu, Xiqian; Li, Hong; Huang, Xuejie; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Increasing Poly(ethylene oxide) Stability to 4.5 V by Surface Coating of the Cathode", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Successfully commercialized poly(ethylene oxide) (PEO)-based solid polymer batteries (SPBs) are expected to continuously play a key role in the next generation of high-energy density lithium-ion battery technologies. However, the introduction of high-voltage cathodes, accompanied by safety concerns such as PEO decomposition and the associated gas release, is worthy of more attention. This study employs in situ DEMS to study the gassing behavior of LiCoO2 vertical bar PEO-LiTFSI vertical bar Li SPBs. The experiments, together with theory calculations, reveal that a surface catalytic effect of LiCoO2 is the root cause of the unexpected H-2 gas release of PEO-based SPBs at 4.2 V. The surface coating of LiCoO2 with a stable solid electrolyte Li1.4Al0.4Ti1.6(PO4)(3) (LATP) can mitigate such a surface catalytic effect and therefore extend the stable working voltage to >4.5 V. The crossover effect of HTFSI, which is generated at the cathode side due to oxidation/dehydration of PEO and reacts with lithium at the anode side, is proposed to explain the H-2 generation behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2020, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 826, "End Page": 832, "Article Number": null, "DOI": "10.1021/acsenergylett.9b02739", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02739", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526311000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZT; Klein, T; Murray, RZ; Crawford, R; Chang, J; Wu, CT; Xiao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zetao; Klein, Travis; Murray, Rachael Z.; Crawford, Ross; Chang, Jiang; Wu, Chengtie; Xiao, Yin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Osteoimmunomodulation for the development of advanced bone biomaterials", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As direct effector cells for osteogenesis, osteoblastic cells are commonly used for evaluating the in vitro osteogenic capacity of bone biomaterials, and the traditional biological principle for developing bone biomaterials is to directly stimulate osteogenic differentiation. With this principle, most efforts are currently spent on optimizing the bio-mechanical and physicochemical properties to induce osteogenic differentiation of mesenchymal stem cells. This strategy has achieved certain success in the development of bone biomaterials; however, inconsistencies between in vitro and in vivo studies are not uncommon, implying the mechanisms that govern the material's capacity to mediate osteogenesis is not well-understood. Osteoimmunology has revealed the vital role of immune cells in regulating bone dynamics. Neglecting the importance of the immune response is a major shortcoming of the traditional strategy, and may explain inconsistencies between in vitro and in vivo conditions. Here, we proposed osteoimmunomodulation (OIM) in recognition of the importance of the immune response during biomaterial-mediated osteogenesis. Accordingly, we proposed the paradigm shift of bone biomaterials to an osteoimmunomodulatory material and discussed the evaluation strategy for the osteoimmunomodulation property of bone biomaterials. It is the ambition of authors that this review will change traditional methods for bone biomaterials assessment and assist in developing new bone biomaterials with the osteoimmunomodulatory property for orthopedic and dental applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 562, "Times Cited, All Databases": 584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2016, "Volume": 19, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 304, "End Page": 321, "Article Number": null, "DOI": "10.1016/j.mattod.2015.11.004", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.11.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380759200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TY; Yao, YG; Huang, ZN; Xie, PF; Liu, ZY; Yang, MH; Gao, JL; Zeng, KZ; Brozena, AH; Pastel, G; Jiao, ML; Dong, Q; Dai, JQ; Li, SK; Zong, H; Chi, MF; Luo, J; Mo, YF; Wang, GF; Wang, C; Shahbazian-Yassar, R; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tangyuan; Yao, Yonggang; Huang, Zhennull; Xie, Pengfei; Liu, Zhenyu; Yang, Menghao; Gao, Jinlong; Zeng, Kaizhu; Brozena, Alexandra H.; Pastel, Glenn; Jiao, Miaolun; Dong, Qi; Dai, Jiaqi; Li, Shuke; Zong, Han; Chi, Miaofang; Luo, Jian; Mo, Yifei; Wang, Guofeng; Wang, Chao; Shahbazian-Yassar, Reza; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Denary oxide nulloparticles as highly stable catalysts for methane combustion", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxide nulloparticles with elemental and structural diversity are widely studied for catalysis and energy applications. While compositional control holds great promise for materials discovery, current oxide nulloparticles are typically limited to a few cations due to the intrinsic complexity in nulloscale multi-element mixing. Here we report the rational design and synthesis of single-phase multi-element oxide nulloparticles with tunable composition, size and structure. We have identified temperature-, oxidation- and entropy-driven synthesis strategies to mix a range of elements with largely dissimilar oxidation potentials (including palladium), thus greatly expanding the compositional space. Through rapid synthesis and screening, we obtained a denary multi-element oxide catalyst showing high performance and superior stability for catalytic methane combustion over 100 hours due to the high-entropy design and stabilization. Our work therefore provides a viable synthesis route with clear guidelines for multi-element oxide nulloparticles and enables materials design in the multi-element space towards highly stable catalysts. Multi-element oxide catalysts can feature superior properties compared with their single-element analogues but obtaining such complex structures remains a challenge. Here, a method is reported to access single-phase denary nulloparticles as stable and efficient catalysts for the combustion of methane.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41929-020-00554-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00554-1", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607025500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, YZ; Wei, LS; Wu, XY; Jiang, CM; Yao, Y; Peng, B; Chen, H; Huangfu, JT; Ying, YB; Zhang, CAFO; Ping, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Yuzhou; Wei, Lusong; Wu, Xinyue; Jiang, Chengmei; Yao, Yao; Peng, Bo; Chen, Han; Huangfu, Jiangtao; Ying, Yibin; Zhang, Chuanfang John; Ping, Jianfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature high-precision printing of flexible wireless electronics based on MXene inks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wireless technologies-supported printed flexible electronics are crucial for the Internet of Things (IoTs), human-machine interaction, wearable and biomedical applications. However, the challenges to existing printing approaches remain, such as low printing precision, difficulty in conformal printing, complex ink formulations and processes. Here we present a room-temperature direct printing strategy for flexible wireless electronics, where distinct high-performance functional modules (e.g., antennas, micro-supercapacitors, and sensors) can be fabricated with high resolution and further integrated on various flat/curved substrates. The additive-free titanium carbide (Ti3C2Tx) MXene aqueous inks are regulated with large single-layer ratio (>90%) and narrow flake size distribution, offering metallic conductivity (similar to 6, 900 S cm(-1)) in the ultrafine-printed tracks (3 mu m line gap and 0.43% spatial uniformity) without annealing. In particular, we build an all-MXene-printed integrated system capable of wireless communication, energy harvesting, and smart sensing. This work opens a door for high-precision additive manufacturing of printed wireless electronics at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3223, "DOI": "10.1038/s41467-022-30648-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30648-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XF; Zhang, SL; Shangguan, EB; Zhang, P; Gao, SY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xue Feng; Zhang, Song Lin; Shangguan, Enbo; Zhang, Peng; Gao, Shuyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Doped Cobalt Pyrite Yolk-Shell Hollow Spheres for Long-Life Rechargeable Zn-Air Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Limited by the sluggish four-electron transfer process, designing high-performance nonprecious electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is urgently desired for efficient rechargeable Zn-air batteries (ZABs). Herein, the successful synthesis of porous nitrogen-doped cobalt pyrite yolk-shell nullospheres (N-CoS2 YSSs) is reported. Benefiting from the abundant porosity of the porous yolk-shell structure and unique electronic properties by nitrogen doping, the as-prepared N-CoS2 YSSs possess more exposed active surface, thus giving rise to superior activity for reversible oxygen electrocatalysis and outstanding cycling stability (more than 165 h at 10 mA cm(-2)) in ZABs, exceeding the commercial Pt/C and RuO2 hybrid catalysts. Moreover, the assembled ZABs, delivering a specific capacity of 640 mAh g(Zn)(-1), can be used for practical devices. This work provides a novel tactic to engineer sulfides as high efficiency and promising bifunctional oxygen electrocatalysts for advanced metal-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 7, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001178, "DOI": "10.1002/advs.202001178", "DOI Link": "http://dx.doi.org/10.1002/advs.202001178", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000585358000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Y; Qiu, LB; Juarez-Perez, EJ; Ono, LK; Hu, ZH; Liu, ZH; Wu, ZF; Meng, LQ; Wang, QJ; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yan; Qiu, Longbin; Juarez-Perez, Emilio J.; Ono, Luis K.; Hu, Zhanhao; Liu, Zonghao; Wu, Zhifang; Meng, Lingqiang; Wang, Qijing; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the major factors that determine commercialization of perovskite photovoltaic technology have been shifting from solar cell performance to stability, reproducibility, device upscaling and the prevention of lead (Pb) leakage from the module over the device service life. Here we simulate a realistic scenario in which perovskite modules with different encapsulation methods are mechanically damaged by a hail impact (modified FM 44787 standard) and quantitatively measure the Pb leakage rates under a variety of weather conditions. We demonstrate that the encapsulation method based on an epoxy resin reduces the Pb leakage rate by a factor of 375 compared with the encapsulation method based on a glass cover with an ultraviolet-cured resin at the module edges. The greater Pb leakage reduction of the epoxy resin encapsulation is associated with its optimal self-healing characteristics under the operating conditions and with its increased mechanical strength. These findings strongly suggest that perovskite photovoltaic products can be deployed with minimal Pb leakage if appropriate encapsulation is employed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 585, "End Page": 593, "Article Number": null, "DOI": "10.1038/s41560-019-0406-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0406-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474920100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, XT; Yang, D; Yang, CC; Spintzyk, S; Scheideler, L; Li, P; Li, DC; Geis-Gerstorfer, J; Rupp, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Xingting; Yang, Dong; Yang, Chuncheng; Spintzyk, Sebastian; Scheideler, Lutz; Li, Ping; Li, Dichen; Geis-Gerstorfer, Juergen; Rupp, Frank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Fiber Reinforced PEEK Composites Based on 3D-Printing Technology for Orthopedic and Dental Applications", "Source Title": "JOURNAL OF CLINICAL MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused deposition modeling (FDM) is a rapidly growing three-dimensional (3D) printing technology and has great potential in medicine. Polyether-ether-ketone (PEEK) is a biocompatible high-performance polymer, which is suitable to be used as an orthopedic/dental implant material. However, the mechanical properties and biocompatibility of FDM-printed PEEK and its composites are still not clear. In this study, FDM-printed pure PEEK and carbon fiber reinforced PEEK (CFR-PEEK) composite were successfully fabricated by FDM and characterized by mechanical tests. Moreover, the sample surfaces were modified with polishing and sandblasting methods to analyze the influence of surface roughness and topography on general biocompatibility (cytotoxicity) and cell adhesion. The results indicated that the printed CFR-PEEK samples had significantly higher general mechanical strengths than the printed pure PEEK (even though there was no statistical difference in compressive strength). Both PEEK and CFR-PEEK materials showed good biocompatibility with and without surface modification. Cell densities on the as-printed PEEK and the CFR-PEEK sample surfaces were significantly higher than on the corresponding polished and sandblasted samples. Therefore, the FDM-printed CFR-PEEK composite with proper mechanical strengths has potential as a biomaterial for bone grafting and tissue engineering applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 240, "DOI": "10.3390/jcm8020240", "DOI Link": "http://dx.doi.org/10.3390/jcm8020240", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "General & Internal Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460295400113", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JJ; Raidongia, K; Koltonow, AR; Huang, JX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jiao-Jing; Raidongia, Kalyan; Koltonow, Andrew R.; Huang, Jiaxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembled two-dimensional nullofluidic proton channels with high thermal stability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exfoliated two-dimensional (2D) sheets can readily stack to form flexible, free-standing films with lamellar microstructure. The interlayer spaces in such lamellar films form a percolated network of molecularly sized, 2D nullochannels that could be used to regulate molecular transport. Here we report self-assembled clay-based 2D nullofluidic channels with surface charge-governed proton conductivity. Proton conductivity of these 2D channels exceeds that of acid solution for concentrations up to 0.1 M, and remains stable as the reservoir concentration is varied by orders of magnitude. Proton transport occurs through a Grotthuss mechanism, with activation energy and mobility of 0.19 eV and 1.2 x 10(-3) cm(2)V(-1) s(-1), respectively. Vermiculite nullochannels exhibit extraordinary thermal stability, maintaining their proton conduction functions even after annealing at 500 degrees C in air. The ease of constructing massive arrays of stable 2D nullochannels without lithography should prove useful to the study of confined ionic transport, and will enable new ionic device designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7602, "DOI": "10.1038/ncomms8602", "DOI Link": "http://dx.doi.org/10.1038/ncomms8602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358856400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xin, WW; Zhang, Z; Huang, XD; Hu, YH; Zhou, T; Zhu, CC; Kong, XY; Jiang, L; Wen, LP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xin, Weiwen; Zhang, Zhen; Huang, Xiaodong; Hu, Yuhao; Zhou, Teng; Zhu, Congcong; Kong, Xiang-Yu; Jiang, Lei; Wen, Liping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance silk-based hybrid membranes employed for osmotic energy conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The salinity gradient between seawater and river water is a clean energy source and an alternative solution for the increasing energy demands. A membrane-based reverse electrodialysis technique is a promising strategy to convert osmotic energy to electricity. To overcome the limits of traditional membranes with low efficiency and high resistance, nullofluidic is an emerging technique to promote osmotic energy harvesting. Here, we engineer a high-performance nullofluidic device with a hybrid membrane composed of a silk nullofibril membrane and an anodic aluminum oxide membrane. The silk nullofibril membrane, as a screening layer with condensed negative surface and nullochannels, dominates the ion transport; the anodic aluminum oxide membrane, as a supporting substrate, offers tunable channels and amphoteric groups. Thus, a nullofluidic membrane with asymmetric geometry and charge polarity is established, showing low resistance, high-performance energy conversion, and long-term stability. The system paves avenues for sustainable power generation, water purification, and desalination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3876, "DOI": "10.1038/s41467-019-11792-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11792-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482889400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cerrón-Calle, GA; Fajardo, AS; Sánchez-Sánchez, CM; Garcia-Segura, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cerron-Calle, Gabriel Antonio; Fajardo, Ana S.; Sanchez-Sanchez, Carlos M.; Garcia-Segura, Sergi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly reactive Cu-Pt bimetallic 3D-electrocatalyst for selective nitrate reduction to ammonia", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identifying electrocatalytic materials that generate fossil-free ammonia through N-recycling from polluted water sources is required. Bimetallic Cu-Pt foam electrodes were synthesized to enhance electrochemical reduction of nitrate (ERN) by the introduction of bimetallic catalytic sites. Electrodes were benchmarked against Cu foam using engineering figures of merit. Cu-Pt (180 s) electrode achieved 94% conversion of NO3--N in 120 min yielding 194.4 mg NH3- N L-1 g(cat)(-1), with a selectivity towards ammonia (S-NH3) of 84% and an electrical energy per order decrease by similar to 70% respect pristine Cu foam. Bimetallic electrodes with low Pt loadings (<0.50 wt%) demonstrated that synergistic effects of Cu-Pt nullointerfaces enabled hybridized mechanisms of catalytic electrochemical and hydrogenation reduction processes. These encouraging outcomes emphasize the potential of Cu-Pt foam electrodes to treat contaminated water sources with nitrate, while allowing a sustainable decentralized ammonia recovery. Enriched water for crops irrigation can therefore be a prospect use for this added value product.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 302, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120844, "DOI": "10.1016/j.apcatb.2021.120844", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2021.120844", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720480100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duong, AT; Nguyen, VQ; Duvjir, G; Duong, VT; Kwon, S; Song, JY; Lee, JK; Lee, JE; Park, S; Min, T; Lee, J; Kim, J; Cho, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anh Tuan Duong; Van Quang Nguyen; Duvjir, Ganbat; Van Thiet Duong; Kwon, Suyong; Song, Jae Yong; Lee, Jae Ki; Lee, Ji Eun; Park, SuDong; Min, Taewon; Lee, Jaekwang; Kim, Jungdae; Cho, Sunglae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving ZT=2.2 with Bi-doped n-type SnSe single crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently SnSe, a layered chalcogenide material, has attracted a great deal of attention for its excellent p-type thermoelectric property showing a remarkable ZT value of 2.6 at 923 K. For thermoelectric device applications, it is necessary to have n-type materials with comparable ZT value. Here, we report that n-type SnSe single crystals were successfully synthesized by substituting Bi at Sn sites. In addition, it was found that the carrier concentration increases with Bi content, which has a great influence on the thermoelectric properties of n-type SnSe single crystals. Indeed, we achieved the maximum ZT value of 2.2 along b axis at 733 K in the most highly doped n-type SnSe with a carrier density of -2.1 x 10(19) cm(-3) at 773 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 12", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13713, "DOI": "10.1038/ncomms13713", "DOI Link": "http://dx.doi.org/10.1038/ncomms13713", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389585500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PF; Yao, HR; Liu, XY; Yin, YX; Zhang, JN; Wen, YR; Yu, XQ; Gu, L; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peng-Fei; Yao, Hu-Rong; Liu, Xin-Yu; Yin, Ya-Xia; Zhang, Jie-null; Wen, Yuren; Yu, Xiqian; Gu, Lin; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Na+/vacancy disordering promises high-rate Na-ion batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As one of the most fascinating cathode candidates for Na-ion batteries (NIBs), P2-type Na layered oxides usually exhibit various single-phase domains accompanied by different Na+/vacancy-ordered superstructures, depending on the Na concentration when explored in a limited electrochemical window. Therefore, their Na+ kinetics and cycling stability at high rates are subjected to these superstructures, incurring obvious voltage plateaus in the electrochemical profiles and insufficient battery performance as cathode materials for NIBs. We show that this problem can be effectively diminished by reasonable structure modulation to construct a completely disordered arrangement of Na-vacancy within Na layers. The combined analysis of scanning transmission electron microscopy, ex situ x-ray absorption spectroscopy, and operando x-ray diffraction experiments, coupled with density functional theory calculations, reveals that Na+/vacancy disordering between the transition metal oxide slabs ensures both fast Na mobility (10(-10) to 10(-9) cm(2) s(-1)) and a low Na diffusion barrier (170 meV) in P2-type compounds. As a consequence, the designed P2-Na2/3Ni1/3Mn1/3Ti1/3 O-2 displays extra-long cycle life (83.9% capacity retention after 500 cycles at 1 C) and unprecedented rate capability (77.5% of the initial capacity at a high rate of 20 C). These findings open up a new route to precisely design high-rate cathode materials for rechargeable NIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 470, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar6018", "DOI": "10.1126/sciadv.aar6018", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar6018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427892700043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lambert, CH; Mangin, S; Varaprasad, BSDCS; Takahashi, YK; Hehn, M; Cinchetti, M; Malinowski, G; Hono, K; Fainman, Y; Aeschlimann, M; Fullerton, EE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lambert, C-H; Mangin, S.; Varaprasad, B. S. D. Ch S.; Takahashi, Y. K.; Hehn, M.; Cinchetti, M.; Malinowski, G.; Hono, K.; Fainman, Y.; Aeschlimann, M.; Fullerton, E. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-optical control of ferromagnetic thin films and nullostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interplay of light and magnetism allowed light to be used as a probe of magnetic materials. Now the focus has shifted to use polarized light to alter or manipulate magnetism. Here, we demonstrate optical control of ferromagnetic materials ranging from magnetic thin films to multilayers and even granular films being explored for ultra-high-density magnetic recording. Our finding shows that optical control of magnetic materials is a much more general phenomenon than previously assumed and may have a major impact on data memory and storage industries through the integration of optical control of ferromagnetic bits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 569, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2014, "Volume": 345, "Issue": 6202, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1337, "End Page": 1340, "Article Number": null, "DOI": "10.1126/science.1253493", "DOI Link": "http://dx.doi.org/10.1126/science.1253493", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341483800062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, D; Zheng, M; Zhang, LG; Zhao, HF; Xie, ZG; Jing, XB; Haddad, RE; Fan, HY; Sun, ZC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Dan; Zheng, Min; Zhang, Ligong; Zhao, Haifeng; Xie, Zhigang; Jing, Xiabin; Haddad, Raid E.; Fan, Hongyou; Sun, Zaicheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation mechanism and optimization of highly luminescent N-doped graphene quantum dots", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoluminescent graphene quantum dots (GQDs) have received enormous attention because of their unique chemical, electronic and optical properties. Here a series of GQDs were synthesized under hydrothermal processes in order to investigate the formation process and optical properties of N-doped GQDs. Citric acid (CA) was used as a carbon precursor and self-assembled into sheet structure in a basic condition and formed N-free GQD graphite framework through intermolecular dehydrolysis reaction. N-doped GQDs were prepared using a series of N-containing bases such as urea. Detailed structural and property studies demonstrated the formation mechanism of N-doped GQDs for tunable optical emissions. Hydrothermal conditions promote formation of amide between -NH2 and -COOH with the presence of amine in the reaction. The intramoleculur dehydrolysis between neighbour amide and COOH groups led to formation of pyrrolic N in the graphene framework. Further, the pyrrolic N transformed to graphite N under hydrothermal conditions. N-doping results in a great improvement of PL quantum yield (QY) of GQDs. By optimized reaction conditions, the highest PL QY (94%) of N-doped GQDs was obtained using CA as a carbon source and ethylene diamine as a N source. The obtained N-doped GQDs exhibit an excitation-independent blue emission with single exponential lifetime decay.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 805, "Times Cited, All Databases": 835, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5294, "DOI": "10.1038/srep05294", "DOI Link": "http://dx.doi.org/10.1038/srep05294", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337342700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, HJ; Zhao, LD; Zheng, FS; Wu, D; Pei, YL; Tong, X; Kanatzidis, MG; He, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, H. J.; Zhao, L-D; Zheng, F. S.; Wu, D.; Pei, Y. L.; Tong, X.; Kanatzidis, M. G.; He, J. Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broad temperature plateau for thermoelectric figure of merit ZT > 2 in phase-separated PbTe0.7S0.3", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectrics interconvert heat to electricity and are of great interest in waste heat recovery, solid-state cooling and so on. The efficiency of thermoelectric materials depends directly on the average ZT (dimensionless figure of merit) over a certain temperature range, which historically has been challenging to increase. Here we report that 2.5% K-doped PbTe0.7S0.3 achieves a ZT of > 2 for a very wide temperature range from 673 to 923 K and has a record high average ZT of 1.56 (corresponding to a theoretical energy conversion efficiency of similar to 20.7% at the temperature gradient from 300 to 900 K). The PbTe0.7S0.3 composition shows spinodal decomposition with large PbTe-rich and PbS-rich regions where each region exhibits dissimilar types of nullostructures. Such high average ZT is obtained by synergistically optimized electrical- and thermal-transport properties via carrier concentration tuning, band structure engineering and hierarchical architecturing, and highlights a realistic prospect of wide applications of thermoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 540, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4515, "DOI": "10.1038/ncomms5515", "DOI Link": "http://dx.doi.org/10.1038/ncomms5515", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340625100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, SW; Hu, SY; Xia, J; Anderson, T; Dinh, XQ; Meng, XM; Coquet, P; Yong, KT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Shuwen; Hu, Siyi; Xia, Jing; Anderson, Tommy; Dinh, Xuan-Quyen; Meng, Xiang-Min; Coquet, Philippe; Yong, Ken-Tye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-MoS2 hybrid nullostructures enhanced surface plasmon resonullce biosensors", "Source Title": "SENSORS AND ACTUATORS B-CHEMICAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we propose a new configuration of surface plasmon resonullce (SPR) sensor based on graphene-MoS2 hybrid structures for ultrasensitive detection of molecules. The proposed system displays a phase-sensitivity enhancement factor of more than 500-fold when compared to the SPR sensing scheme without the graphene-MoS2 coating or with only graphene coating. Our hypothesis is that themono layer MoS2 has a much higher optical absorption efficiency (similar to 5%) than that of the graphene layer(similar to 2.3%). Based on our findings, the electron energy loss of MoS2 layer is comparable to that of graphene and this will allow a successful (similar to 100%) of light energy transfer to the graphene-MoS2 coated sensing substrate. Such process will lead to a significant enhancement of SPR signals. Our simulation shows that aquasi dark point of the reflected light can be achieved under this condition and this has resulted in a steep phase jump at the resonullce angle of our newly proposed SPR system. More importantly, we found that phase interrogation detection approach of the graphene-MoS2 hybrid structures-based sensing system is more sensitive than that of using the regularly angular interrogation method and our theoretical analysis indicates that 45 nm of Au film thickness and 3 coating layers of MoS2 nullosheet are the optimized parameters needed for the proposed SPR system to achieve the highest detection sensitivity range. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 207, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 801, "End Page": 810, "Article Number": null, "DOI": "10.1016/j.snb.2014.10.124", "DOI Link": "http://dx.doi.org/10.1016/j.snb.2014.10.124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345895200098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Merryweather, AJ; Schnedermann, C; Jacquet, Q; Grey, CP; Rao, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Merryweather, Alice J.; Schnedermann, Christoph; Jacquet, Quentin; Grey, Clare P.; Rao, Akshay", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando optical tracking of single-particle ion dynamics in batteries", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The key to advancing lithium-ion battery technology-in particular, fast charging-is the ability to follow and understand the dynamic processes occurring in functioning materials under realistic conditions, in real time and on the nullo- to mesoscale. Imaging of lithium-ion dynamics during battery operation (operando imaging) at present requires sophisticated synchrotron X-ray(1-7) or electron microscopy(8,9) techniques, which do not lend themselves to high-throughput material screening. This limits rapid and rational materials improvements. Here we introduce a simple laboratory-based, optical interferometric scattering microscope(10-13) to resolve nulloscopic lithium-ion dynamics in battery materials, and apply it to follow cycling of individual particles of the archetypal cathode material(14,15), LixCoO2, within an electrode matrix. We visualize the insulator-to-metal, solid solution and lithium ordering phase transitions directly and determine rates of lithium diffusion at the single-particle level, identifying different mechanisms on charge and discharge. Finally, we capture the dynamic formation of domain boundaries between different crystal orientations associated with the monoclinic lattice distortion at the Li0.5CoO2 composition(16). The high-throughput nature of our methodology allows many particles to be sampled across the entire electrode and in future will enable exploration of the role of dislocations, morphologies and cycling rate on battery degradation. The generality of our imaging concept means that it can be applied to study any battery electrode, and more broadly, systems where the transport of ions is associated with electronic or structural changes. Such systems include nulloionic films, ionic conducting polymers, photocatalytic materials and memristors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2021, "Volume": 594, "Issue": 7864, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 522, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03584-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03584-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665247800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PY; Fan, Y; Lu, LF; Liu, L; Fan, LL; Zhao, MY; Xie, Y; Xu, CJ; Zhang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peiyuan; Fan, Yong; Lu, Lingfei; Liu, Lu; Fan, Lingling; Zhao, Mengyao; Xie, Yang; Xu, Congjian; Zhang, Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NIR-II nulloprobes in-vivo assembly to improve image-guided surgery for metastatic ovarian cancer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Local recurrence is a common cause of treatment failure for patients with solid tumors. Tumor-specific intraoperative fluorescence imaging may improve staging and debulking efforts in cytoreductive surgery and, thereby improve prognosis. Here, we report in vivo assembly of the second near-infrared window (NIR-II) emitting downconversion nulloparticles (DCNPs) modified with DNA and targeting peptides to improve the image-guided surgery for metastatic ovarian cancer. The NIR-II imaging quality with DCNPs is superior to that of clinically approved ICG with good photostability and deep tissue penetration (8 mm). Stable tumor retention period experienced 6 h by in vivo assembly of nulloprobes can be used for precise tumor resection. Superior tumor-to-normal tissue ratio is successfully achieved to facilitate the abdominal ovarian metastases surgical delineation. Metastases with <= 1 mm can be completely excised under NIR-II bioimaging guidance. This novel technology provides a general new basis for the future design of nullomaterials for medical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2898, "DOI": "10.1038/s41467-018-05113-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05113-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439557800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JY; Huang, W; Pei, A; Li, YZ; Shi, FF; Yu, XY; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiangyan; Huang, William; Pei, Allen; Li, Yuzhang; Shi, Feifei; Yu, Xiaoyun; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Operations of lithium-ion batteries have long been limited to a narrow temperature range close to room temperature. At elevated temperatures, cycling degradation speeds up due to enhanced side reactions, especially when high-reactivity lithium metal is used as the anode. Here, we demonstrate enhanced performance in lithium metal batteries operated at elevated temperatures. In an ether-based electrolyte at 60 degrees C, an average Coulombic efficiency of 99.3% is obtained and more than 300 stable cycles are realized, but, at 20 degrees C, the Coulombic efficiency drops dramatically within 75 cycles, corresponding to an average Coulombic efficiency of 90.2%. Cryo-electron microscopy reveals a drastically different solid electrolyte interface nullostructure emerging at 60 degrees C, which maintains mechanical stability, inhibits continuous side reactions and guarantees good cycling stability and low electrochemical impedance. Furthermore, larger lithium particles grown at the elevated temperature reduce the electrolyte/electrode interfacial area, which decreases the per-cycle lithium loss and enables higher Coulombic efficiencies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 664, "End Page": 670, "Article Number": null, "DOI": "10.1038/s41560-019-0413-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0413-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481484400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, CC; Meijerink, A; Liu, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Chun Che; Meijerink, Andries; Liu, Ru-Shi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Critical Red Components for Next-Generation White LEDs", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Warm white LEDs with a high color rendering index and a low correlated color temperature have undergone rapid development. In this regard, red-emitting materials-such as fluoride phosphors, namely, A(2)MF(6):Mn4+ (A = K, Na, and Cs; M = Si, Ge, Zr, Sn, and Ti) and XSiF6:Mn4+ (X = Ba or Zn), nitridoaluminate phosphor (Sr[LiAl3N4]:Eu2+), and nullocrystals of cesium lead iodide perovskite (CsPbI3)-have been extensively investigated recently. These compounds generate narrow emissions in the visible red spectral region that are highly perceived by the human eye and lead to excellent chromatic saturation of the red spectra. This paper describes the structure, luminescence properties, morphologies, thermal features, and moisture resistance of critical red components, as well as their limitations for practical applications. This Perspective also provides a basis for future development and scientific challenges in optical research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2016, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 503, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b02433", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b02433", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369774400021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kattel, S; Yu, WT; Yang, XF; Yan, BH; Huang, YQ; Wan, WM; Liu, P; Chen, JGG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kattel, Shyam; Yu, Weiting; Yang, Xiaofang; Yan, Binhang; Huang, Yanqiang; Wan, Weiming; Liu, Ping; Chen, Jingguang G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO2 Hydrogenation over Oxide-Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By simply changing the oxide support, the selectivity of a metal-oxide catalysts can be tuned. For the CO2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO2, ZrO2, and TiO2), replacing a TiO2 support by CeO2 or ZrO2 selectively strengthens the binding of C, O-bound and O-bound species at the PtCo-oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal-oxide catalysts can be fine-tuned.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2016, "Volume": 55, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7968, "End Page": 7973, "Article Number": null, "DOI": "10.1002/anie.201601661", "DOI Link": "http://dx.doi.org/10.1002/anie.201601661", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383253100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khan, S; Lorenzelli, L; Dahiya, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khan, Saleem; Lorenzelli, Leandro; Dahiya, Ravinder S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Technologies for Printing Sensors and Electronics Over Large Flexible Substrates: A Review", "Source Title": "IEEE SENSORS JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Printing sensors and electronics over flexible substrates are an area of significant interest due to low-cost fabrication and possibility of obtaining multifunctional electronics over large areas. Over the years, a number of printing technologies have been developed to pattern a wide range of electronic materials on diverse substrates. As further expansion of printed technologies is expected in future for sensors and electronics, it is opportune to review the common features, the complementarities, and the challenges associated with various printing technologies. This paper presents a comprehensive review of various printing technologies, commonly used substrates and electronic materials. Various solution/dry printing and contact/noncontact printing technologies have been assessed on the basis of technological, materials, and process-related developments in the field. Critical challenges in various printing techniques and potential research directions have been highlighted. Possibilities of merging various printing methodologies have been explored to extend the lab developed standalone systems to high-speed roll-to-roll production lines for system level integration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 861, "Times Cited, All Databases": 972, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3164, "End Page": 3185, "Article Number": null, "DOI": "10.1109/JSEN.2014.2375203", "DOI Link": "http://dx.doi.org/10.1109/JSEN.2014.2375203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353149800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HJ; Zhang, M; Yang, YY; Huang, Q; Fukuda, T; Wang, ZK; Shen, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Haojian; Zhang, Mei; Yang, Yuanyuan; Huang, Qiang; Fukuda, Toshio; Wang, Zuankai; Shen, Yajing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A bioinspired multilegged soft millirobot that functions in both dry and wet conditions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing untethered millirobots that can adapt to harsh environments with high locomotion efficiency is of interest for emerging applications in various industrial and biomedical settings. Despite recent success in exploiting soft materials to impart sophisticated functions which are not available in conventional rigid robotics, it remains challenging to achieve superior performances in both wet and dry conditions. Inspired by the flexible, soft, and elastic leg/foot structures of many living organisms, here we report an untethered soft millirobot decorated with multiple tapered soft feet architecture. Such robot design yields superior adaptivity to various harsh environments with ultrafast locomotion speed (>40 limb length/s), ultra-strong carrying capacity (>100 own weight), and excellent obstacle-crossing ability (stand up 90 degrees and across obstacle >10 body height). Our work represents an important advance in the emerging area of bio-inspired robotics and will find a wide spectrum of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 466, "Times Cited, All Databases": 493, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3944, "DOI": "10.1038/s41467-018-06491-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06491-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445607500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jawad, A; Lang, J; Liao, ZW; Khan, A; Ifthikar, J; Lv, ZN; Long, SJ; Chen, ZL; Chen, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jawad, Ali; Lang, Jie; Liao, Zhuwei; Khan, Aimal; Ifthikar, Jerosha; Lv, Zhanao; Long, Sijie; Chen, Zhulei; Chen, Zhuqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activation of persulfate by CuOx@Co-LDH: A novel heterogeneous system for contaminullt degradation with broad pH window and controlled leaching", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To meet the current challenges of waste water, an efficient, environment friendly and economical treatment process is always desirable for the degradation of toxic organic compounds. Herein, we reported a stable and active bimetallic CuOx@Co-LDH catalyst for the degradation of phenol using persulfate (PS) under mild conditions. The system of PS/CuOx@Co-LDH completely degraded 0.1 mM of phenol in less than 40 min while at the same time, all the other tested catalysts including catalyst precursors remained sluggish. In view of the practical application, CuOx@Co-LDH/PS-system demonstrated consistent performance over a broad pH range (pH 5.0-12.0), during which minimum leaching could be detected. Moreover, good resistance to various inorganic anions was demonstrated in CuOx@CoLDH/PS system. The consistent performance of CuOx@Co-LDH/PS system may originate from the constant buffer pH of catalyst (9.5 +/- 0.8), minimum leaching and the generation of diverse free radicals (center dot SO4-, center dot OH or (-)center dot O-2) under different pH conditions. Additionally, LDH structure offered strong synergetic interactions among active components which might also help in minimum leaching and good reactivity of CuOx@Co-LDH catalyst. The results of radical scavengers, EPR and XPS studies collectively proved the mechanism of diverse free radicals, which was accounted to the redox cyclic reactions of active sites (Cu-(III)-Cu-(II)-Cu-(III) and Co-(III)-Co-(II)-Co-(III)) during degradation of phenol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 335, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 548, "End Page": 559, "Article Number": null, "DOI": "10.1016/j.cej.2017.10.097", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.10.097", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430700500060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, YQ; Pan, TT; Lei, Q; Chen, CL; Dong, XL; Yuan, YY; Al Maksoud, W; Zhao, L; Cavallo, L; Pinnau, I; Han, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yaqiang; Pan, Tingting; Lei, Qiong; Chen, Cailing; Dong, Xinglong; Yuan, Youyou; Al Maksoud, Walid; Zhao, Long; Cavallo, Luigi; Pinnau, Ingo; Han, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and simultaneous capture of iodine and methyl iodide achieved by a covalent organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radioactive molecular iodine (I-2) and methyl iodide (CH3I) coexist in the off-gas stream of nuclear power plants at low concentrations and only few adsorbents can effectively adsorb low-concentration I-2 and CH3I simultaneously. Here, the authors demonstrate simultaneous capture of I-2 and CH3I at low concentrations by exploiting different adsorptive sites in a covalent organic framework. Radioactive molecular iodine (I-2) and organic iodides, mainly methyl iodide (CH3I), coexist in the off-gas stream of nuclear power plants at low concentrations, whereas few adsorbents can effectively adsorb low-concentration I-2 and CH3I simultaneously. Here we demonstrate that the I-2 adsorption can occur on various adsorptive sites and be promoted through intermolecular interactions. The CH3I adsorption capacity is positively correlated with the content of strong binding sites but is unrelated to the textural properties of the adsorbent. These insights allow us to design a covalent organic framework to simultaneously capture I-2 and CH3I at low concentrations. The developed material, COF-TAPT, combines high crystallinity, a large surface area, and abundant nucleophilic groups and exhibits a record-high static CH3I adsorption capacity (1.53 g center dot g(-1) at 25 degrees C). In the dynamic mixed-gas adsorption with 150 ppm of I-2 and 50 ppm of CH3I, COF-TAPT presents an excellent total iodine capture capacity (1.51 g center dot g(-1)), surpassing various benchmark adsorbents. This work deepens the understanding of I-2/CH3I adsorption mechanisms, providing guidance for the development of novel adsorbents for related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2878, "DOI": "10.1038/s41467-022-30663-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30663-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000801198000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QH; Zhang, XW; Abdalla, LB; Fazzio, A; Zunger, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qihang; Zhang, Xiuwen; Abdalla, L. B.; Fazzio, Adalberto; Zunger, Alex", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switching a Normal Insulator into a Topological Insulator via Electric Field with Application to Phosphorene", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The study of topological insulators has generally involved search of materials that have this property as an innate quality, distinct from normal insulators. Here we focus on the possibility of converting a normal insulator into a topological one by application of an external electric field that shifts different bands by different energies and induces a specific band inversion, which leads to a topological state. Phosphorene is a two-dimensional (2D) material that can be isolated through mechanical exfoliation from layered black phosphorus, but unlike graphene and silicene, single-layer phosphorene has a large band gap (1.52.2 eV). Thus, it was unsuspected to exhibit band inversion and the ensuing topological insulator behavior. Using first-principles calculations with applied perpendicular electric field F-perpendicular to on few-layer phosphorene we predict a continuous transition from the normal insulator to a topological insulator and eventually to a metal as a function of F-perpendicular to. The tuning of topological behavior with electric field would lead to spin-separated, gapless edge states, that is, quantum spin Hall effect. This finding opens the possibility of converting normal insulating materials into topological ones via electric field and making a multifunctional field effect topological transistor that could manipulate simultaneously both spin and charge carrier. We use our results to formulate some design principles for looking for other 2D materials that could have such an electrical-induced topological transition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1222, "End Page": 1228, "Article Number": null, "DOI": "10.1021/nl5043769", "DOI Link": "http://dx.doi.org/10.1021/nl5043769", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349578000066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, WF; Mu, Z; He, Y; Kong, KR; Jiang, K; Tang, RK; Liu, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Weifeng; Mu, Zhao; He, Yan; Kong, Kangren; Jiang, Kai; Tang, Ruikang; Liu, Zhaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic-inorganic covalent-ionic molecules for elastic ceramic plastic", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although organic-inorganic hybrid materials have played indispensable roles as mechanical1-4, optical5,6, electronic7,8 and biomedical materials9-11, isolated organicinorganic hybrid molecules (at present limited to covalent compounds12,13) are seldom used to prepare hybrid materials, owing to the distinct behaviours of organic covalent bonds14 and inorganic ionic bonds15 in molecular construction. Here we integrate typical covalent and ionic bonds within one molecule to create an organic-inorganic hybrid molecule, which can be used for bottom-up syntheses of hybrid materials. A combination of the organic covalent thioctic acid (TA) and the inorganic ionic calcium carbonate oligomer (CCO) through an acid-base reaction provides a TA-CCO hybrid molecule with the representative molecular formula TA(2)Ca(CaCO3)(2). Its dual reactivity involving copolymerization of the organic TA segment and inorganic CCO segment generates the respective covalent and ionic networks. The two networks are interconnected through TA-CCO complexes to form a covalent-ionic bicontinuous structure within the resulting hybrid material, poly(TA-CCO), which unifies paradoxical mechanical properties. The reversible binding of Ca2+-CO32- bonds in the ionic network and S-S bonds in the covalent network ensures material reprocessability with plastic-like mouldability while preserving thermal stability. The coexistence of ceramic-like, rubber-like and plastic-like behaviours within poly(TA-CCO) goes beyond current classifications of materials to generate an `elastic ceramic plastic'. The bottom-up creation of organic-inorganic hybrid molecules provides a feasible pathway for the molecular engineering of hybrid materials, thereby supplementing the classical methodology used for the manufacture of organic-inorganic hybrid materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2023, "Volume": 619, "Issue": 7969, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 293, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06117-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06117-1", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001005804900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, BY; Yu, JK; Sui, LZ; Zhu, SJ; Tang, ZY; Yang, B; Lu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Boyang; Yu, Jingkun; Sui, Laizhi; Zhu, Shoujun; Tang, Zhiyong; Yang, Bai; Lu, Siyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational Design of Multi-Color-Emissive Carbon Dots in a Single Reaction System by Hydrothermal", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As an emerging building unit, carbon dots (CDs) have been igniting the revolutionaries in the fields of optoelectronics, biomedicine, and bioimaging. However, the difficulty of synthesizing CDs in aqueous solution with full-spectrum emission severely hinders further investigation of their emission mechanism and their extensive applications in white light emitting diodes (LEDs). Here, the full-color-emission CDs with a unique structure consisting of sp(3)-hybridized carbon cores with small domains of partially sp(2)-hybridized carbon atoms are reported. First-principle calculations are initially used to predict that the transformation from sp(3) to sp(2) hybridization redshifts the emission of CDs. Guided by the theoretical predictions, a simple, convenient, and controllable route to hydrothermally prepare CDs in a single reaction system is developed. The prepared CDs have full-spectrum emission with an unprecedented two-photon emission across the whole visible color range. These full-color-emission CDs can be further nurtured by slight modifications of the reaction conditions (e.g., temperature, pH) to generate the emission color from blue to red. Finally a flexible LEDs with full-color emission by using epoxy CDs films is developed, indicating that the strategy affords an industry translational potential over traditional fluorophores.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001453, "DOI": "10.1002/advs.202001453", "DOI Link": "http://dx.doi.org/10.1002/advs.202001453", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591341500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, L; Liang, J; Luo, YS; Zheng, DD; Sun, SJ; Liu, Q; Hamdy, MS; Sun, XP; Ying, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Ling; Liang, Jie; Luo, Yongsong; Zheng, Dongdong; Sun, Shengjun; Liu, Qian; Hamdy, Mohamed S.; Sun, Xuping; Ying, Binwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances in electrocatalytic ammonia synthesis", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial electrocatalytic ammonia (NH3) synthesis is recently becoming a research hotspot. It can couple with clean renewable electricity, which is considered an energy-efficient and sustainable approach for regulating the recirculation of nitrogen species and meanwhile promoting the growth of a circular nitrogen economy. In this Account, we review recent advances in electrocatalytic ammonia synthesis. Firstly, we briefly introduce the research background and significance of three electrochemical NH3 synthesis routes: electrocatalytic nitrogen reduction, nitric oxide reduction, and nitrate/nitrite reduction. And then we give a detailed discussion of the latest research advances in electrocatalysts for ambient NH3 synthesis, mainly involving catalytic mechanisms, theoretical advances, and electrochemical performance. Finally, the existing challenges and future research needs for artificial electrosynthesis of NH3 are also highlighted. & COPY; 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6, "End Page": 44, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64464-X", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64464-X", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001063123500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, YJ; Meng, FB; Zhang, SW; Ping, B; Li, H; Yin, BS; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Yujin; Meng, Fanbo; Zhang, Siwen; Ping, Bu; Li, Hui; Yin, Bosi; Ma, Tianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CNT@MnO2 composite ink toward a flexible 3D printed micro-zinc-ion battery", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible energy storage devices have played a significant role in multiscenario applications, while flexible zinc-ion batteries (ZIBs), as an essential branch, have developed rapidly in recent years. Three-dimensional (3D) printing is an extremely advanced technology to design and modify the structure of batteries and provides unlimited possibilities for the diversified development of energy storage equipment. Herein, by utilizing 3D printing technology, carbon nullotube (CNT) is coated by MnO2 to form a flexible CNT@MnO2 ink as a cathode for flexible aqueous micro-ZIBs for the first time and zinc powder ink is used as an anode due to its high flexibility and bendability. The Zn//CNT@MnO2 flexible battery shows a stable capacity of 63 mu Ah cm(-2) at 0.4 mA cm(-2). When the battery is bent in different states, the maximum capacity loss compared with the initial value is only 2.72%, indicating its stability. This study shows the potential of 3D printing technology in the development of flexible manganese-based ZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 446, "End Page": 457, "Article Number": null, "DOI": "10.1002/cey2.177", "DOI Link": "http://dx.doi.org/10.1002/cey2.177", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749460900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheema, SS; Shanker, N; Wang, LC; Hsu, CH; Hsu, SL; Liao, YH; San Jose, M; Gomez, J; Chakraborty, W; Li, WS; Bae, JH; Volkman, SK; Kwon, D; Rho, Y; Pinelli, G; Rastogi, R; Pipitone, D; Stull, C; Cook, M; Tyrrell, B; Stoica, VA; Zhang, Z; Freeland, JW; Tassone, CJ; Mehta, A; Saheli, G; Thompson, D; Suh, DI; Koo, WT; Nam, KJ; Jung, DJ; Song, WB; Lin, CH; Nam, S; Heo, J; Parihar, N; Grigoropoulos, CP; Shafer, P; Fay, P; Ramesh, R; Mahapatra, S; Ciston, J; Datta, S; Mohamed, M; Hu, CM; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheema, Suraj S.; Shanker, Nirmaan; Wang, Li-Chen; Hsu, Cheng-Hsiang; Hsu, Shang-Lin; Liao, Yu-Hung; San Jose, Matthew; Gomez, Jorge; Chakraborty, Wriddhi; Li, Wenshen; Bae, Jong-Ho; Volkman, Steve K.; Kwon, Daewoong; Rho, Yoonsoo; Pinelli, Gianni; Rastogi, Ravi; Pipitone, Dominick; Stull, Corey; Cook, Matthew; Tyrrell, Brian; Stoica, Vladimir A.; Zhang, Zhan; Freeland, John W.; Tassone, Christopher J.; Mehta, Apurva; Saheli, Ghazal; Thompson, David; Suh, Dong Ik; Koo, Won-Tae; Nam, Kab-Jin; Jung, Dong Jin; Song, Woo-Bin; Lin, Chung-Hsun; Nam, Seunggeol; Heo, Jinseong; Parihar, Narendra; Grigoropoulos, Costas P.; Shafer, Padraic; Fay, Patrick; Ramesh, Ramamoorthy; Mahapatra, Souvik; Ciston, Jim; Datta, Suman; Mohamed, Mohamed; Hu, Chenming; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin ferroic HfO2-ZrO2 superlattice gate stack for advanced transistors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the scaling of lateral dimensions in advanced transistors, an increased gate capacitance is desirable both to retain the control of the gate electrode over the channel and to reduce the operating voltage'. This led to a fundamental change in the gate stack in 2008, the incorporation of high-dielectric-constant HfO2 (ref. 2 ), which remains the material of choice to date. Here we report HfO2-ZrO2 superlattice heterostructures as a gate stack, stabilized with mixed ferroelectric-antiferroelectric order, directly integrated onto Si transistors, and scaled down to approximately 20 angstroms, the same gate oxide thickness required for high-performance transistors. The overall equivalent oxide thickness in metal-oxide-semiconductor capacitors is equivalent to an effective SiO2 thickness of approximately 6.5 angstroms. Such a low effective oxide thickness and the resulting large capacitance cannot be achieved in conventional HfO2-based high-dielectric-constant gate stacks without scavenging the interfacial SiO2, which has adverse effects on the electron transport and gate leakage current'. Accordingly, our gate stacks, which do not require such scavenging, provide substantially lower leakage current and no mobility degradation. This work demonstrates that ultrathin ferroic HfO2-ZrO2 multilayers, stabilized with competing ferroelectric-antiferroelectric order in the two-nullometre-thickness regime, provide a path towards advanced gate oxide stacks in electronic devices beyond conventional HfO2-based high-dielectric-constant materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2022, "Volume": 604, "Issue": 7904, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04425-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04425-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779100400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, Y; Chen, L; Liu, P; Yu, T; Lin, CC; Yan, CC; Hu, YQ; Zhou, W; Sun, Y; Panayi, AC; Cao, FQ; Xue, H; Hu, LC; Lin, Z; Xie, XD; Xiao, XF; Feng, Q; Mi, BB; Liu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Yuan; Chen, Lang; Liu, Pei; Yu, Tao; Lin, Chuanchuan; Yan, Chenchen; Hu, Yiqiang; Zhou, Wu; Sun, Yun; Panayi, Adriana C.; Cao, Faqi; Xue, Hang; Hu, Liangcong; Lin, Ze; Xie, Xudong; Xiao, Xiufeng; Feng, Qian; Mi, Bobin; Liu, Guohui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-in-One: Multifunctional Hydrogel Accelerates Oxidative Diabetic Wound Healing through Timed-Release of Exosome and Fibroblast Growth Factor", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The treatment of diabetic wounds remains a major challenge in clinical practice, with chronic wounds characterized by multiple drug-resistant bacterial infections, angiopathy, and oxidative damage to the microenvironment. Herein, a novel in situ injectable HA@MnO2/FGF-2/Exos hydrogel is introduced for improving diabetic wound healing. Through a simple local injection, this hydrogel is able to form a protective barrier covering the wound, providing rapid hemostasis and long-term antibacterial protection. The MnO2/epsilon-PL nullosheet is able to catalyze the excess H2O2 produced in the wound, converting it to O-2, thus not only eliminating the harmful effects of H2O2 but also providing O-2 for wound healing. Moreover, the release of M2-derived Exosomes (M2 Exos) and FGF-2 growth factor stimulates angiogenesis and epithelization, respectively. These in vivo and in vitro results demonstrate accelerated healing of diabetic wounds with the use of the HA@MnO2/FGF-2/Exos hydrogel, presenting a viable strategy for chronic diabetic wound repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104229, "DOI": "10.1002/smll.202104229", "DOI Link": "http://dx.doi.org/10.1002/smll.202104229", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719615100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, AL; Zhou, XF; Wang, XJ; Liu, S; Xiong, QH; Zhang, QH; Gu, L; Zhuang, ZC; Zhang, WJ; Li, FX; Wang, DS; Li, LJ; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Ali; Zhou, Xiaofeng; Wang, Xijun; Liu, Sheng; Xiong, Qihua; Zhang, Qinghua; Gu, Lin; Zhuang, Zechao; Zhang, Wenjing; Li, Fanxing; Wang, Dingsheng; Li, Lain-Jong; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-step synthesis of single-site vanadium substitution in 1T-WS2 monolayers for enhanced hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic tungsten disulfide (WS2) monolayers have been demonstrated as promising electrocatalysts for hydrogen evolution reaction (HER) induced by the high intrinsic conductivity, however, the key challenges to maximize the catalytic activity are achieving the metallic WS2 with high concentration and increasing the density of the active sites. In this work, single-atom-V catalysts (V SACs) substitutions in 1T-WS2 monolayers (91% phase purity) are fabricated to significantly enhance the HER performance via a one-step chemical vapor deposition strategy. Atomic-resolution scanning transmission electron microscopy (STEM) imaging together with Raman spectroscopy confirm the atomic dispersion of V species on the 1T-WS2 monolayers instead of energetically favorable 2H-WS2 monolayers. The growth mechanism of V SACs@1T-WS2 monolayers is experimentally and theoretically demonstrated. Density functional theory (DFT) calculations demonstrate that the activated V-atom sites play vital important role in enhancing the HER activity. In this work, it opens a novel path to directly synthesize atomically dispersed single-metal catalysts on metastable materials as efficient and robust electrocatalysts. Ru is one of the most active metals for oxygen evolution reaction, but it quickly dissolves in acidic electrolyte particularly in nullosized form. Here the authors show that coral-like solid-solution RuIr consisting of 3nm-thick sheets with only 6at% Ir is a long-lived catalyst with high activity", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 709, "DOI": "10.1038/s41467-021-20951-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-20951-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684846200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Jiang, XF; Zhao, YY; Carné-Sánchez, A; Malgras, V; Kim, J; Kim, JH; Wang, SB; Liu, J; Jiang, JS; Yamauchi, Y; Hu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Jiang, Xiangfen; Zhao, Yanyi; Carne-Sanchez, Arnau; Malgras, Victor; Kim, Jeonghun; Kim, Jung Ho; Wang, Shaobin; Liu, Jian; Jiang, Ji-Sen; Yamauchi, Yusuke; Hu, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow carbon nullobubbles: monocrystalline MOF nullobubbles and their pyrolysis", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nulloarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nullobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate framework (ZIF-8) nullobubbles with a uniform size of less than 100 nm. Interestingly, the ZIF-8 nullobubbles possess a monocrystalline nulloshell with a thickness of around 10 nm. Under optimal pyrolytic conditions, the ZIF-8 nullobubbles can be converted into hollow carbon nullobubbles while keeping their original shapes. The structure of the nullobubble enhances the fast Na+/K+ ion intercalation performance. Such remarkable improvement cannot be realized by conventional MOFs or their derived carbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3538, "End Page": 3546, "Article Number": null, "DOI": "10.1039/c6sc04903f", "DOI Link": "http://dx.doi.org/10.1039/c6sc04903f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400553000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jeon, S; Heo, T; Hwang, SY; Ciston, J; Bustillo, KC; Reed, BW; Ham, JM; Kang, SS; Kim, SG; Lim, J; Lim, K; Kim, JS; Kang, MH; Bloom, RS; Hong, S; Kim, K; Zettl, A; Kim, WY; Ercius, P; Park, J; Lee, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jeon, Sungho; Heo, Taeyeong; Hwang, Sang-Yeon; Ciston, Jim; Bustillo, Karen C.; Reed, Bryan W.; Ham, Jimin; Kang, Sungsu; Kim, Sungin; Lim, Joowon; Lim, Kitaek; Kim, Ji Soo; Kang, Min-Ho; Bloom, Ruth S.; Hong, Sukjoon; Kim, Kwanpyo; Zettl, Alex; Kim, Woo Youn; Ercius, Peter; Park, Jungwon; Lee, Won Chul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible disorder-order transitions in atomic crystal nucleation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nucleation in atomic crystallization remains poorly understood, despite advances in classical nucleation theory. The nucleation process has been described to involve a nonclassical mechanism that includes a spontaneous transition from disordered to crystalline states, but a detailed understanding of dynamics requires further investigation. In situ electron microscopy of heterogeneous nucleation of individual gold nullocrystals with millisecond temporal resolution shows that the early stage of atomic crystallization proceeds through dynamic structural fluctuations between disordered and crystalline states, rather than through a single irreversible transition. Our experimental and theoretical analyses support the idea that structural fluctuations originate from size-dependent thermodynamic stability of the two states in atomic dusters. These findings, based on dynamics in a real atomic system, reshape and improve our understanding of nucleation mechanisms in atomic crystallization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 371, "Issue": 6528, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 498, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz7555", "DOI Link": "http://dx.doi.org/10.1126/science.aaz7555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612983100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZY; Zhang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Zhengyong; Zhang, Jiahe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving broadband absorption and polarization conversion with a vanadium dioxide metasurface in the same terahertz frequencies", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the bifunctional design of a broadband absorber and a broadband polarization converter based on a switchable metasurface through the insulator-to-metal phase transition of vanadium dioxide. When vanadium dioxide is metal, the designed switchable metasurface behaves as a broadband absorber. This absorber is composed of a vanadium dioxide square, silica spacer, and vanadium dioxide film. Calculated results show that in the frequency range of 0.52-1.2 THz, the designed system can absorb more than 90% of the energy, and the bandwidth ratio is 79%. It is insensitive to polarization due to the symmetry, and can still work well even at large incident angles. When vanadium dioxide is an insulator, a terahertz polarizer is realized by a simple anisotropic metasurface. Numerical calculation shows that efficient conversion between two orthogonal linear polarizations can be achieved. Reflectance of a cross-polarized wave can reach 90% from 0.42 THz to 1.04 THz, and the corresponding bandwidth ratio is 85%. This cross-polarized converter has the advantages of wide angle, broad bandwidth, and high efficiency. So our design can realize bifunctionality of broadband absorption and polarization conversion between 0.52 THz and 1.04 THz. This architecture could provide one new way to develop switchable photonic devices and functional components in phase change materials. (C) 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2020, "Volume": 28, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12487, "End Page": 12497, "Article Number": null, "DOI": "10.1364/OE.391066", "DOI Link": "http://dx.doi.org/10.1364/OE.391066", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526518300150", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Yang, SK; Zhang, JW; Chen, Z; Zhu, B; Li, J; Liang, SJ; Bai, YX; Xu, JH; Rao, DW; Dong, LL; Zhang, CF; Yang, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yangyang; Yang, Shaokang; Zhang, Jingwei; Chen, Zhuo; Zhu, Bo; Li, Jian; Liang, Shijing; Bai, Yunxiang; Xu, Jianhong; Rao, Dewei; Dong, Liangliang; Zhang, Chunfang; Yang, Xiaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable and switchable CO2-responsive membranes with high wettability for separation of various oil/water systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Smart membranes with responsive wettability show promise for controllably separating oil/water mixtures, including immiscible oil-water mixtures and surfactant-stabilized oil/water emulsions. However, the membranes are challenged by unsatisfactory external stimuli, inadequate wettability responsiveness, difficulty in scalability and poor self-cleaning performance. Here, we develop a capillary force-driven confinement self-assembling strategy to construct a scalable and stable CO2-responsive membrane for the smart separation of various oil/water systems. In this process, the CO2-responsive copolymer can homogeneously adhere to the membrane surface by manipulating the capillary force, generating a membrane with a large area up to 3600 cm(2) and excellent switching wettability between high hydrophobicity/underwater superoleophilicity and superhydrophilicity/underwater superoleophobicity under CO2/N-2 stimulation. The membrane can be applied to various oil/water systems, including immiscible mixtures, surfactant-stabilized emulsions, multiphase emulsions and pollutant-containing emulsions, demonstrating high separation efficiency (>99.9%), recyclability, and self-cleaning performance. Due to robust separation properties coupled with the excellent scalability, the membrane shows great implications for smart liquid separation. Smart membranes with responsive wettability show promise for controllably separating oil/water mixtures but it remains challenging to fabricate responsive and stable scalable membranes. Here, the authors develop a capillary force-driven self-assembling strategy to construct a scalable and stable CO2-responsive membrane for the smart separation of various oil/water systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1108, "DOI": "10.1038/s41467-023-36685-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36685-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942107800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, JW; Chueh, CC; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Jae Woong; Chueh, Chu-Chen; Jen, Alex K. -Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Low-Temperature, Solution-Processable, Cu-Doped Nickel Oxide Hole-Transporting Layer via the Combustion Method for High-Performance Thin-Film Perovskite Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-temperature, solution-processable Cu-doped NiOX (Cu:NiOx), prepared via combustion chemistry, is demonstrated as an excellent hole-transporting layer (HTL) for thin-film perovskite solar cells (PVSCs). Its good crystallinity, conductivity, and hole-extraction properties enable the derived PVSC to have a high power conversion efficiency (PCE) of 17.74%. Its general applicability for various elecrode materials is also revealed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2015, "Volume": 27, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7874, "End Page": 7880, "Article Number": null, "DOI": "10.1002/adma.201503298", "DOI Link": "http://dx.doi.org/10.1002/adma.201503298", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367837900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, Y; Wang, L; Xia, N; Yang, ZX; Zhang, C; Pan, CF; Jin, DD; Zhang, JC; Majidi, C; Zhang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Yue; Wang, Lu; Xia, Neng; Yang, Zhengxin; Zhang, Chong; Pan, Chengfeng; Jin, Dongdong; Zhang, Jiachen; Majidi, Carmel; Zhang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Untethered small-scale magnetic soft robot with programmable magnetization and integrated multifunctional modules", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intelligent magnetic soft robots capable of programmable structural changes and multifunctionality modalities depend on material architectures and methods for controlling magnetization profiles. While some efforts have been made, there are still key challenges in achieving programmable magnetization profile and creating heterogeneous architectures. Here, we directly embed programmed magnetization patterns (magnetization modules) into the adhesive sticker layers to construct soft robots with programmable magnetization profiles and geometries and then integrate spatially distributed functional modules. Functional modules including temperature and ultraviolet light sensing particles, pH sensing sheets, oil sensing foams, positioning electronic component, circuit foils, and therapy patch films are integrated into soft robots. These test beds are used to explore multimodal robot locomotion and various applications related to environmental sensing and detection, circuit repairing, and gastric ulcer coating, respectively. This proposed approach to engineering modular soft material systems has the potential to expand the functionality, versatility, and adaptability of soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2022, "Volume": 8, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabn8932", "DOI": "10.1126/sciadv.abn8932", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abn8932", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000814518800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, PN; Dolado, I; Alfaro-Mozaz, FJ; Casanova, F; Hueso, LE; Liu, S; Edgar, JH; Nikitin, AY; Vélez, S; Hillenbrand, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Peining; Dolado, Irene; Javier Alfaro-Mozaz, Francisco; Casanova, Felix; Hueso, Luis E.; Liu, Song; Edgar, James H.; Nikitin, Alexey Y.; Velez, Saul; Hillenbrand, Rainer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared hyperbolic metasurface based on nullostructured van der Waals materials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces with strongly anisotropic optical properties can support deep subwavelength-scale confined electromagnetic waves (polaritons), which promise opportunities for controlling light in photonic and optoelectronic applications. We developed a mid-infrared hyperbolic metasurface by nullostructuring a thin layer of hexagonal boron nitride that supports deep subwavelength-scale phonon polaritons that propagate with in-plane hyperbolic dispersion. By applying an infrared nulloimaging technique, we visualize the concave (anomalous) wavefronts of a diverging polariton beam, which represent a landmark feature of hyperbolic polaritons. The results illustrate how near-field microscopy can be applied to reveal the exotic wavefronts of polaritons in anisotropic materials and demonstrate that nullostructured van der Waals materials can form a highly variable and compact platform for hyperbolic infrared metasurface devices and circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2018, "Volume": 359, "Issue": 6378, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 892, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaq1704", "DOI Link": "http://dx.doi.org/10.1126/science.aaq1704", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425752600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schnaider, L; Brahmachari, S; Schmidt, NW; Mensa, B; Shaham-Niv, S; Bychenko, D; Adler-Abramovich, L; Shimon, LJW; Kolusheva, S; DeGrado, WF; Gazit, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schnaider, Lee; Brahmachari, Sayanti; Schmidt, Nathan W.; Mensa, Bruk; Shaham-Niv, Shira; Bychenko, Darya; Adler-Abramovich, Lihi; Shimon, Linda J. W.; Kolusheva, Sofiya; DeGrado, William F.; Gazit, Ehud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembling dipeptide antibacterial nullostructures with membrane disrupting activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peptide-based supramolecular assemblies are a promising class of nullomaterials with important biomedical applications, specifically in drug delivery and tissue regeneration. However, the intrinsic antibacterial capabilities of these assemblies have been largely overlooked. The recent identification of common characteristics shared by antibacterial and self-assembling peptides provides a paradigm shift towards development of antibacterial agents. Here we present the antibacterial activity of self-assembled diphenylalanine, which emerges as the minimal model for antibacterial supramolecular polymers. The diphenylalanine nullo-assemblies completely inhibit bacterial growth, trigger upregulation of stress-response regulons, induce substantial disruption to bacterial morphology, and cause membrane permeation and depolarization. We demonstrate the specificity of these membrane interactions and the development of antibacterial materials by integration of the peptide assemblies into tissue scaffolds. This study provides important insights into the significance of the interplay between self-assembly and antimicrobial activity and establishes innovative design principles toward the development of antimicrobial agents and materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1365, "DOI": "10.1038/s41467-017-01447-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01447-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414662500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MJ; Li, QQ; Shi, CZ; Lv, J; Xu, YD; Yang, JJ; Chua, SL; Jia, LR; Chen, HW; Liu, Q; Huang, CJ; Huang, YC; Chen, JM; Fang, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mengjing; Li, Qianqian; Shi, Changzhi; Lv, Jia; Xu, Youdong; Yang, Junjie; Chua, Shae Linn; Jia, Linran; Chen, Huaiwen; Liu, Qian; Huang, Changjin; Huang, Yichao; Chen, Jianmin; Fang, Mingliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oligomer nulloparticle release from polylactic acid plastics catalysed by gut enzymes triggers acute inflammation", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The health risks of exposure to 'eco-friendly' biodegradable plastics of anthropogenic origin and their effects on the gastrointestinal tract are largely unknown. Here we demonstrate that the enzymatic hydrolysis of polylactic acid microplastics generated nulloplastic particles by competing for triglyceride-degrading lipase during gastrointestinal processes. nulloparticle oligomers were formed by hydrophobically driven self-aggregation. In a mouse model, polylactic acid oligomers and their nulloparticles bioaccumulated in the liver, intestine and brain. Hydrolysed oligomers caused intestinal damage and acute inflammation. A large-scale pharmacophore model revealed that oligomers interacted with matrix metallopeptidase 12. Mechanistically, high binding affinity (K-d = 13.3 mu mol l(-)(1)) of oligomers to the catalytic zinc-ion finger domain led to matrix metallopeptidase 12 inactivation, which might mediate the adverse bowel inflammatory effects after exposure to polylactic acid oligomers. Biodegradable plastics are considered to be a solution to address environmental plastic pollution. Thus, understanding the gastrointestinal fates and toxicities of bioplastics will provide insights into potential health risks. A large-scale pharmacophore model supported by in vitro ligand-binding studies suggests polylactic acid oligomer toxicity in a mouse model is due to the inhibition of matrix metallopeptidase 12.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 18, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41565-023-01329-y", "DOI Link": "http://dx.doi.org/10.1038/s41565-023-01329-y", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942665400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Simonelli, M; Tse, YY; Tuck, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Simonelli, M.; Tse, Y. Y.; Tuck, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of the build orientation on the mechanical properties and fracture modes of SLM Ti-6A1-4V", "Source Title": "MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent research on the additive manufacturing (AM) of Ti alloys has shown that the mechanical properties of the parts are affected by the characteristic microstructure that originates from the AM process. To understand the effect of the microstructure on the tensile properties, selective laser melted (SLM) Ti-6Al-4V samples built in three different orientations were tensile tested. The investigated samples were near fully dense, in two distinct conditions, as-built and stress relieved. It was found that the build orientation affects the tensile properties, and in particular the ductility of the samples. The mechanical anisotropy of the parts was discussed in relation to the crystallographic texture, phase composition and the predominullt fracture mechanisms. Fractography and electron backscatter diffraction (EBSD) results indicate that the predominullt fracture mechanism is intergranular fracture present along the grain boundaries and thus provide and explain the typical fracture surface features observed in fracture AM Ti-6Al-4V. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 755, "Times Cited, All Databases": 806, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2014, "Volume": 616, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 11, "Article Number": null, "DOI": "10.1016/j.msea.2014.07.086", "DOI Link": "http://dx.doi.org/10.1016/j.msea.2014.07.086", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343352400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ha, MR; Kim, DY; Umer, M; Gladkikh, V; Myung, CW; Kim, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ha, Miran; Kim, Dong Yeon; Umer, Muhammad; Gladkikh, Vladislav; Myung, Chang Woo; Kim, Kwang S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning metal single atoms embedded in NxCy moieties toward high-performance electrocatalysis", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble nulloparticle (NP)-sized electrocatalysts have been exploited for diverse electrochemical reactions, in particular, for an eco-friendly hydrogen economy such as water splitting. Recently, minimal amounts of single atoms (SAs) are exploited to maximize the active surface area and to tune the catalytic activity by coordinating the SAs in defect sites of N-doped graphene (G(N)). For the hydrogen evolution reaction (HER) and oxygen evolution/reduction reactions (OER/ORR), we show high-performance 3d-5d transition metal (TM) SA catalysts using density functional theory (DFT) along with machine learning (ML)-based descriptors. We explore the stability and activity of TM-G(N) from the view of structure/coordination, formation energy, structural/electrochemical stability, electronic properties, electrical conductivity, and reaction mechanism, which have not been seriously explored yet. Among various -NnCm moieties, the -N2C2 moieties tend to be more easily formed and show higher electrochemical catalytic performance and longer durability (without aggregation/dissolution) compared with the widely studied pure -C-4/C-3 and -N-4/N-3 moieties. We found that some TM(SA)s favor a new OER/ORR mechanism, completely different from any known mechanism. The ML-based descriptors showing super HER/OER/ORR performances better than those of bench-mark noble metal catalysts are assessed. In the N2C2 templates, Ni/Ru/Rh/Pt show low HER overpotentials. Here, the H adsorption sites are shared by both the metal and C (not N), which was undiscussed in most of the previous literature where the H is attached on top of a metal atom. Low OER overpotentials are found for Pt/Ni-N2C2, Ni/Pd-C-4, and Rh-N-4, while low ORR overpotentials are found for Ir/Rh-N-4, Pd-C-4, Ru-N3C1 and Ni/Pd/Pt-N1C3. The present findings should help in designing high-performance SA catalysts for other various electrocatalytic reactions such as the ammonia evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2021, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3455, "End Page": 3468, "Article Number": null, "DOI": "10.1039/d1ee00154j", "DOI Link": "http://dx.doi.org/10.1039/d1ee00154j", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652643400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kelly, AG; Hallam, T; Backes, C; Harvey, A; Esmaeily, AS; Godwin, I; Coelho, J; Nicolosi, V; Lauth, J; Kulkarni, A; Kinge, S; Siebbeles, LDA; Duesberg, GS; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kelly, Adam G.; Hallam, Toby; Backes, Claudia; Harvey, Andrew; Esmaeily, Amir Sajad; Godwin, Ian; Coelho, Joao; Nicolosi, Valeria; Lauth, Jannika; Kulkarni, Aditya; Kinge, Sachin; Siebbeles, Laurens D. A.; Duesberg, Georg S.; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-printed thin-film transistors from networks of liquid-exfoliated nullosheets", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-printed transistors consisting of interconnected networks of various types of two-dimensional nullosheets are an important goal in nulloscience. Using electrolytic gating, we demonstrate all-printed, vertically stacked transistors with graphene source, drain, and gate electrodes, a transition metal dichalcogenide channel, and a boron nitride (BN) separator, all formed from nullosheet networks. The BN network contains an ionic liquid within its porous interior that allows electrolytic gating in a solid-like structure. nullosheet network channels display on: off ratios of up to 600, transconductances exceeding 5 millisiemens, and mobilities of > 0.1 square centimeters per volt per second. Unusually, the on-currents scaled with network thickness and volumetric capacitance. In contrast to other devices with comparable mobility, large capacitances, while hindering switching speeds, allow these devices to carry higher currents at relatively low drive voltages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2017, "Volume": 356, "Issue": 6333, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 69, "End Page": 72, "Article Number": null, "DOI": "10.1126/science.aal4062", "DOI Link": "http://dx.doi.org/10.1126/science.aal4062", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398689100039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oliveira, JP; LaLonde, AD; Ma, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oliveira, J. P.; LaLonde, A. D.; Ma, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Processing parameters in laser powder bed fusion metal additive manufacturing", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As metallic additive manufacturing grew in sophistication, users have requested greater control over the systems, namely the ability to fully change the process parameters. The goal of this manuscript is to review the effects of major process parameters on build quality (porosity, residual stress, and composition changes) and materials properties (microstructure and microsegregation), and to serve as a guide on how these parameters may be modified to achieve specific design goals for a given part. The focus of this paper is on laser powder bed fusion, but elements can be applied to electron beam powder bed fusion or direct energy deposition techniques. (C) 2020 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 552, "Times Cited, All Databases": 596, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 193, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108762, "DOI": "10.1016/j.matdes.2020.108762", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2020.108762", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567367500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, ZQ; Jiang, Y; Yang, TY; Li, L; Wu, F; Chen, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Zhengqing; Jiang, Ying; Yang, Tianyu; Li, Li; Wu, Feng; Chen, Renjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Catalytic CoSe-ZnSe Heterojunctions Anchored on Graphene Aerogels for Bidirectional Sulfur Conversion Reactions", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sluggish sulfur reduction and lithium sulfide (Li2S) oxidation prevent the widespread use of lithium-sulfur (Li-S) batteries, which are attractive alternatives to Li-ion batteries. The authors propose that a transition metal selenide heterojunction (CoSe-ZnSe) catalytically accelerates bidirectional sulfur conversion reactions. A combination of synchrotron X-ray absorption spectroscopy and density functional theory calculations show that a highly active heterointerface with charge redistribution and structure distortion effectively immobilizes sulfur species, facilitates Li ion diffusion, and decreases the sulfur reduction and Li2S oxidation energy barriers. The CoSe-ZnSe catalytic cathode exhibits high areal capacities, good rate capability, and superior cycling stability with capacity fading rate of 0.027% per cycle over 1700 cycles. Furthermore, CoSe-ZnSe heterojunctions anchored on graphene aerogels (CoSe-ZnSe@G) enhance ionic transport and catalytic activity under high sulfur loading and lean electrolyte conditions. A high areal capacity of 8.0 mAh cm(-2) is achieved at an electrolyte/sulfur ratio of 3 mu L mg(-1). This study demonstrates the importance of bidirectional catalytic heterojunctions and structure engineering in boosting Li-S battery performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103456, "DOI": "10.1002/advs.202103456", "DOI Link": "http://dx.doi.org/10.1002/advs.202103456", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000711739100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JR; Zhu, SJ; Liu, HW; Song, YB; Tao, SY; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jieren; Zhu, Shoujun; Liu, Huiwen; Song, Yubin; Tao, Songyuan; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-Color Emission Polymer Carbon Dots with Quench-Resistant Solid-State Fluorescence", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer carbon dots (PCDs) represent a new class of carbon dots (CDs) possessing sub-fluorophores and unique polymer-like structures. However, like small molecule dyes and traditional CDs, PCDs often suffer from self-quenching effect in solid state, limiting their potential applications. Moreover, it is hard to prepare PCDs that have the same chemical structure, exhibiting full-color emission under one fixed excitation wavelength by only modulating the concentration of the PCDs. Herein, self-quenching-resistant solid-state fluorescent polymer carbon dots (SSFPCDs) are prepared, which exhibit strong red SSF without any other additional solid matrices, while having a large production yield (approximate to 89%) and a considerable quantum yield of 8.50%. When dispersed in water or solid matrices in gradient concentrations, they can exhibit yellow, green, and blue fluorescence, realizing the first SSFPCDs with the same chemical structure emitting in full-color range by changing the ratio of SSFPCDs to the solid matrices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700395, "DOI": "10.1002/advs.201700395", "DOI Link": "http://dx.doi.org/10.1002/advs.201700395", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418385800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, TK; Wang, F; Kim, HB; Choi, IW; Wang, CF; Cho, E; Konefal, R; Puttisong, Y; Terado, K; Kobera, L; Chen, MY; Yang, M; Bai, S; Yang, BW; Suo, JJ; Yang, SC; Liu, XJ; Fu, F; Yoshida, H; Chen, WMM; Brus, J; Coropceanu, V; Hagfeldt, A; Brédas, JL; Fahlman, M; Kim, DS; Hu, ZJ; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Tiankai; Wang, Feng; Kim, Hak-Beom; Choi, In-Woo; Wang, Chuanfei; Cho, Eunkyung; Konefal, Rafal; Puttisong, Yuttapoom; Terado, Kosuke; Kobera, Libor; Chen, Mengyun; Yang, Mei; Bai, Sai; Yang, Bowen; Suo, Jiajia; Yang, Shih-Chi; Liu, Xianjie; Fu, Fan; Yoshida, Hiroyuki; Chen, Weimin M.; Brus, Jiri; Coropceanu, Veaceslav; Hagfeldt, Anders; Bredas, Jean-Luc; Fahlman, Mats; Kim, Dong Suk; Hu, Zhangjun; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion-modulated radical doping of spiro-OMeTAD for more efficient and stable perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Record power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) have been obtained with the organic hole transporter 2,2',7,7'-tetrakis(N,N-di-p-methoxyphenyl-amine)9,9'-spirobifluorene (spiro-OMeTAD). Conventional doping of spiro-OMeTAD with hygroscopic lithium salts and volatile 4-tert-butylpyridine is a time-consuming process and also leads to poor device stability. We developed a new doping strategy for spiro-OMeTAD that avoids post-oxidation by using stable organic radicals as the dopant and ionic salts as the doping modulator (referred to as ion-modulated radical doping). We achieved PCEs of >25% and much-improved device stability under harsh conditions. The radicals provide hole polarons that instantly increase the conductivity and work function (WF), and ionic salts further modulate the WF by affecting the energetics of the hole polarons. This organic semiconductor doping strategy, which decouples conductivity and WF tunability, could inspire further optimization in other optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2022, "Volume": 377, "Issue": 6605, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 501, "Article Number": "eabo2757", "DOI": "10.1126/science.abo2757", "DOI Link": "http://dx.doi.org/10.1126/science.abo2757", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836647500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, Z; Yuan, C; Peng, XR; Wang, TJ; Qi, HJ; Dunn, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Zhen; Yuan, Chao; Peng, Xirui; Wang, Tiejun; Qi, H. Jerry; Dunn, Martin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct 4D printing via active composite materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We describe an approach to print composite polymers in high-resolution three-dimensional (3D) architectures that can be rapidly transformed to a new permanent configuration directly by heating. The permanent shape of a component results from the programmed time evolution of the printed shape upon heating via the design of the architecture and process parameters of a composite consisting of a glassy shape memory polymer and an elastomer that is programmed with a built-in compressive strain during photopolymerization. Upon heating, the shape memory polymer softens, releases the constraint on the strained elastomer, and allows the object to transform into a new permanent shape, which can then be reprogrammed into multiple subsequent shapes. Our key advance, the markedly simplified creation of high-resolution complex 3D reprogrammable structures, promises to enable myriad applications across domains, including medical technology, aerospace, and consumer products, and even suggests a new paradigm in product design, where components are simultaneously designed to inhabit multiple configurations during service.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 535, "Times Cited, All Databases": 583, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602890", "DOI": "10.1126/sciadv.1602890", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602890", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YS; Liu, XJ; Han, DD; Song, XY; Shi, L; Song, Y; Niu, SW; Xie, YF; Cai, JY; Wu, SY; Kang, J; Zhou, JB; Chen, ZY; Zheng, XS; Xiao, XH; Wang, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yishang; Liu, Xiaojing; Han, Dongdong; Song, Xianyin; Shi, Lei; Song, Yao; Niu, Shuwen; Xie, Yufang; Cai, Jinyan; Wu, Shaoyang; Kang, Jian; Zhou, Jianbin; Chen, Zhiyan; Zheng, Xusheng; Xiao, Xiangheng; Wang, Gongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron density modulation of NiCo2S4 nullowires by nitrogen incorporation for highly efficient hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal sulfides for hydrogen evolution catalysis typically suffer from unfavorable hydrogen desorption properties due to the strong interaction between the adsorbed H and the intensely electronegative sulfur. Here, we demonstrate a general strategy to improve the hydrogen evolution catalysis of metal sulfides by modulating the surface electron densities. The N modulated NiCo2S4 nullowire arrays exhibit an overpotential of 41 mV at 10 mA cm(-2) and a Tafel slope of 37 mV dec(-1), which are very close to the performance of the benchmark Pt/C in alkaline condition. X-ray photoelectron spectroscopy, synchrotron-based X-ray absorption spectroscopy, and density functional theory studies consistently confirm the surface electron densities of NiCo2S4 have been effectively manipulated by N doping. The capability to modulate the electron densities of the catalytic sites could provide valuable insights for the rational design of highly efficient catalysts for hydrogen evolution and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1425, "DOI": "10.1038/s41467-018-03858-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03858-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429794300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, T; Kim, JH; Kang, TE; Lee, C; Kang, H; Shin, M; Wang, C; Ma, BW; Jeong, U; Kim, TS; Kim, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Taesu; Kim, Jae-Han; Kang, Tae Eui; Lee, Changyeon; Kang, Hyunbum; Shin, Minkwan; Wang, Cheng; Ma, Biwu; Jeong, Unyong; Kim, Taek-Soo; Kim, Bumjoon J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, highly efficient all-polymer solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-polymer solar cells have shown great potential as flexible and portable power generators. These devices should offer good mechanical endurance with high power-conversion efficiency for viability in commercial applications. In this work, we develop highly efficient and mechanically robust all-polymer solar cells that are based on the PBDTTTPD polymer donor and the P(NDI2HD-T) polymer acceptor. These systems exhibit high power-conversion efficiency of 6.64%. Also, the proposed all-polymer solar cells have even better performance than the control polymer-fullerene devices with phenyl-C-61-butyric acid methyl ester (PCBM) as the electron acceptor (6.12%). More importantly, our all-polymer solar cells exhibit dramatically enhanced strength and flexibility compared with polymer/PCBM devices, with 60- and 470-fold improvements in elongation at break and toughness, respectively. The superior mechanical properties of all-polymer solar cells afford greater tolerance to severe deformations than conventional polymer-fullerene solar cells, making them much better candidates for applications in flexible and portable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 719, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8547, "DOI": "10.1038/ncomms9547", "DOI Link": "http://dx.doi.org/10.1038/ncomms9547", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364930800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, H; Yang, M; Ru, XN; Wang, GS; Yin, S; Peng, FG; Hong, CJ; Qu, MH; Lu, JX; Fang, L; Han, C; Procel, P; Isabella, O; Gao, PQ; Li, ZG; Xu, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Hao; Yang, Miao; Ru, Xiaoning; Wang, Genshun; Yin, Shi; Peng, Fuguo; Hong, Chengjian; Qu, Minghao; Lu, Junxiong; Fang, Liang; Han, Can; Procel, Paul; Isabella, Olindo; Gao, Pingqi; Li, Zhenguo; Xu, Xixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silicon heterojunction solar cells with up to 26.81% efficiency achieved by electrically optimized nullocrystalline-silicon hole contact layers", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improvements in the power conversion efficiency of silicon heterojunction solar cells would consolidate their potential for commercialization. Now, Lin et al. demonstrate 26.81% efficiency devices using a p-doped nullocrystalline silicon and low-sheet-resistance transparent conductive oxide contact layer. Silicon heterojunction (SHJ) solar cells have reached high power conversion efficiency owing to their effective passivating contact structures. Improvements in the optoelectronic properties of these contacts can enable higher device efficiency, thus further consolidating the commercial potential of SHJ technology. Here we increase the efficiency of back junction SHJ solar cells with improved back contacts consisting of p-type doped nullocrystalline silicon and a transparent conductive oxide with a low sheet resistance. The electrical properties of the hole-selective contact are analysed and compared with a p-type doped amorphous silicon contact. We demonstrate improvement in the charge carrier transport and a low contact resistivity (<5 m ohm cm(2)). Eventually, we report a series of certified power conversion efficiencies of up to 26.81% and fill factors up to 86.59% on industry-grade silicon wafers (274 cm(2), M6 size).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 789, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01255-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01255-2", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984178200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, L; Ma, ZW; Zhu, MH; Liu, LN; Dai, JF; Shi, YQ; Gao, JF; Dinh, T; Nguyen, T; Tang, LC; Song, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Lei; Ma, Zhewen; Zhu, Menghe; Liu, Lina; Dai, Jinfeng; Shi, Yongqian; Gao, Jiefeng; Dinh, Toan; Thanh Nguyen; Tang, Long-Cheng; Song, Pingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superhydrophobic self-extinguishing cotton fabrics for electromagnetic interference shielding and human motion detection", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional intelligent fire-safe cotton fabric promises next-generation fire-fighting uniform and sensor applications. However, cotton fabrics' hygroscopicity and intrinsic flammability significantly impede their potential applications in industries. Herein, we report a superhydrophobic fireproof cotton fabric (PEI-APP-PEI-MXene) generated via sequential layer-by-layer deposition of polyethyleneimine (PEI), ammonium polyphosphate (APP), and titanium carbide (MXene), followed by hydrophobic treatment with silicone elastomer. Compared to untreated cotton, the treated cotton fabric with 10 polymolecular layers exhibits -43% and -42% reductions in the peak heat release rate and total heat release, respectively, a desired UL-94 V-0 rating, and a high limiting oxygen index (LOI) value of 39.5 vol.%. In addition to that, the treated fabrics displayed improved electromagnetic interference (EMI) shielding and motion-sensing abilities. The presented work provides a facile and effective surface modification approach to generate multifunctional cotton fabrics with promising practical applications. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2023, "Volume": 132, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": 68, "Article Number": null, "DOI": "10.1016/j.jmst.2022.05.036", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2022.05.036", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827663600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Chakraborty, P; Ponge, D; Hickel, T; Sun, BH; Wu, CH; Gault, B; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Huan; Chakraborty, Poulami; Ponge, Dirk; Hickel, Tilmann; Sun, Binhan; Wu, Chun-Hung; Gault, Baptiste; Raabe, Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen trapping and embrittlement in high-strength Al alloys", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ever more stringent regulations on greenhouse gas emissions from transportation motivate effortsto revisit materials used for vehicles(1). High-strength aluminium alloys often used in aircrafts could help reduce the weight of automobiles, but are susceptible to environmental degradation(2,3). Hydrogen 'embrittlement' is often indicated as the main culprit(4): however, the exact mechanisms underpinning failure are not precisely known: atomic-scale analysis of H inside an alloy remains a challenge, and this prevents deploying alloy design strategiesto enhance the durability of the materials. Here we performed near-atomic-scale analysis of H trapped in second-phase particles and at grain boundaries in a high-strength 7xxx Al alloy. We used these observations to guide atomistic ab initio calculations, which showthat the co-segregation of alloying elements and H favours grain boundary decohesion, and the strong partitioning of H into the second-phase particles removes solute H from the matrix, hence preventing H embrittlement. Our insights further advance the mechanistic understanding of H-assisted embrittlement in Al alloys, emphasizing the role of H traps in minimizing cracking and guiding new alloy design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2022, "Volume": 602, "Issue": 7897, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 437, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04343-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04343-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756892700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, RX; Kang, W; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Ruixiang; Kang, Wei; Yang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectricity and Phase Transitions in Monolayer Group-IV Monochalcogenides", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectricity usually fades away as materials are thinned down below a critical value. We reveal that the unique ionic-potential anharmonicity can induce spontaneous in-plane electrical polarization and ferroelectricity in monolayer group-IV monochalcogenides MX (M = Ge, Sn; X = S, Se). An effective Hamiltonian has been successfully extracted from the parametrized energy space, making it possible to study the ferroelectric phase transitions in a single-atom layer. The ferroelectricity in these materials is found to be robust and the corresponding Curie temperatures are higher than room temperature, making them promising for realizing ultrathin ferroelectric devices of broad interest. We further provide the phase diagram and predict other potentially two-dimensional ferroelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 552, "Times Cited, All Databases": 595, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2016, "Volume": 117, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 97601, "DOI": "10.1103/PhysRevLett.117.097601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.097601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382007600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, N; Wu, YJ; Xu, W; Lyu, JK; Wang, Y; Zi, L; Shao, L; Sun, R; Wang, N; Liu, S; Zhou, DL; Bai, X; Zhou, J; Song, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, null; Wu, Yanjie; Xu, Wen; Lyu, Jiekai; Wang, Yue; Zi, Lu; Shao, Long; Sun, Rui; Wang, null; Liu, Sen; Zhou, Donglei; Bai, Xue; Zhou, Ji; Song, Hongwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel approach for designing efficient broadband photodetectors expanding from deep ultraviolet to near infrared", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broadband photodetection (PD) covering the deep ultraviolet to near-infrared (200-1000 nm) range is significant and desirable for various optoelectronic designs. Herein, we employ ultraviolet (UV) luminescent concentrators (LC), iodine-based perovskite quantum dots (PQDs), and organic bulk heterojunction (BHJ) as the UV, visible, and near-infrared (NIR) photosensitive layers, respectively, to construct a broadband heterojunction PD. Firstly, experimental and theoretical results reveal that optoelectronic properties and stability of CsPbI3 PQDs are significantly improved through Er3+ doping, owing to the reduced defect density, improved charge mobility, increased formation energy, tolerance factor, etc. The narrow bandgap of CsPbI3:Er3+ PQDs serves as a visible photosensitive layer of PD. Secondly, considering the matchable energy bandgap, the BHJ (BTP-4Cl: PBDB-TF) is selected as to NIR absorption layer to fabricate the hybrid structure with CsPbI3:Er3+ PQDs. Thirdly, UV LC converts the UV light (200-400 nm) to visible light (400-700 nm), which is further absorbed by CsPbI3:Er3+ PQDs. In contrast with other perovskites PDs and commercial Si PDs, our PD presents a relatively wide response range and high detectivity especially in UV and NIR regions (two orders of magnitude increase that of commercial Si PDs). Furthermore, the PD also demonstrates significantly enhanced air- and UV- stability, and the photocurrent of the device maintains 81.5% of the original one after 5000 cycles. This work highlights a new attempt for designing broadband PDs, which has application potential in optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 91, "DOI": "10.1038/s41377-022-00777-w", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00777-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780931600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tai, QD; Guo, XY; Tang, GQ; You, P; Ng, TW; Shen, D; Cao, JP; Liu, CK; Wang, NX; Zhu, Y; Lee, CS; Yan, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tai, Qidong; Guo, Xuyun; Tang, Guanqi; You, Peng; Ng, Tsz-Wai; Shen, Dong; Cao, Jiupeng; Liu, Chun-Ki; Wang, Naixiang; Zhu, Ye; Lee, Chun-Sing; Yan, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antioxidant Grain Passivation for Air-Stable Tin-Based Perovskite Solar Cells", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin-based perovskites with excellent optoelectronic properties and suitable band gaps are promising candidates for the preparation of efficient lead-free perovskite solar cells (PSCs). However, it is challenging to prepare highly stable and efficient tin-based PSCs because Sn2+ in perovskites can be easily oxidized to Sn4+ upon air exposure. Here we report the fabrication of air-stable FASnI(3) solar cells by introducing hydroxybenzene sulfonic acid or its salt as an antioxidant additive into the perovskite precursor solution along with excess SnCl2. The interaction between the sulfonate group and the Sn2+ ion enables the in situ encapsulation of the perovskite grains with a SnCl2-additive complex layer, which results in greatly enhanced oxidation stability of the perovskite film. The corresponding PSCs are able to maintain 80 % of the efficiency over 500 h upon air exposure without encapsulation, which is over ten times longer than the best result reported previously. Our results suggest a possible strategy for the future design of efficient and stable tin-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2019, "Volume": 58, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 806, "End Page": 810, "Article Number": null, "DOI": "10.1002/anie.201811539", "DOI Link": "http://dx.doi.org/10.1002/anie.201811539", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455033700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, KH; Kaup, K; Assoud, A; Zhang, Q; Wu, XH; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Kern-Ho; Kaup, Kavish; Assoud, Abdeljalil; Zhang, Qiang; Wu, Xiaohan; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Voltage Superionic Halide Solid Electrolytes for All-Solid-State Li-Ion Batteries", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state Li-ion batteries (ASSBs), considered to be potential next-generation energy storage devices, require solid electrolytes (SEs). Thiophosphate-based materials are popular, but these sulfides exhibit poor anodic stability and require specialty coatings on lithium metal oxide cathodes. Moreover, electrode designs aimed at high energy density are limited by their narrow electrochemical stability window. Here, we report new mixed-metal halide Li3-xM1-xZrxCl6(M = Y, Er) SEs with high ionic conductivity-up to 1.4 mS cm(-1) at 25 degrees C that are stable to high voltage. Substitution of M = Y, Er) by Zr is accompanied by a trigonalto-orthorhombic phase transition, and structure solution using combined neutron and single-crystal X-ray diffraction methods reveal a new framework. The employment of >4 V-class cathode materials without any protective coating is enabled by the high electrochemical oxidation stability of these halides. An ASSB showcasing their electrolyte properties exhibits very promising cycling stability up to 4.5 V at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 533, "End Page": "+", "Article Number": null, "DOI": "10.1021/acsenergylett.9b02599", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02599", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514258200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YF; Wu, N; Li, B; Liu, W; Pan, F; Zeng, ZH; Liu, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yunfei; Wu, Na; Li, Bin; Liu, Wei; Pan, Fei; Zeng, Zhihui; Liu, Jiurong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic Porous MXene Sediment-Based Hydrogel for High-Performance and Multifunctional Electromagnetic Interference Shielding", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance and functional hydrogels that mimic biological materials in nature is promising yet remains highly challenging. Through a facile, scalable unidirectional freezing followed by a salting-out approach, a type of hydrogels composed of trashed MXene sediment (MS) and biomimetic pores is manufactured. By integrating the honeycomb-like ordered porous structure, highly conductive MS, and water, the electromagnetic interference (EMI) shielding effectiveness is up to 90 dB in the X band and can reach more than 40 dB in the ultrabroadband gigahertz band (8.2-40 GHz) for the highly flexible hydrogel, outperforming previously reported porous EMI shields. Moreover, thanks to the stable framework of the MS-based hydrogel, the influences of water on shielding performance are quantitatively identified. Furthermore, the extremely low content of silver nullowire is embedded into the biomimetic hydrogels, leading to the significantly improved multiple reflection-induced microwave loss and thus EMI shielding performance. Last, the MS-based hydrogels allow sensitive and reliable detection of human motions and smart coding. This work thus not only achieves the control of EMI shielding performance via the interior porous structure of hydrogels, but also demonstrates a waste-free, low-cost, and scalable strategy to prepare multifunctional, high-performance MS-based biomimetic hydrogels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 AUG 19", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acsnullo.2c06164", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c06164", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860598600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takeda, H; Ohashi, K; Sekine, A; Ishitani, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takeda, Hiroyuki; Ohashi, Kenji; Sekine, Akiko; Ishitani, Osamu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic CO2 Reduction Using Cu(I) Photosensitizers with a Fe(II) Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic systems developed from complexes with only abundant metals, i.e., Cu-I(dmp)(P)(2)(+) (dmp = 2,9-dimethyl-1,10-phenullthroline; P = phosphine ligand) as a redox photosensitizer and Fe-II(dmp)(2)(NCS)(2) as a catalyst, produced CO as the main product by visible light irradiation. The best photocatalysis was obtained using a Cu-I complex with a tetradentate dmp ligand tethering two phosphine groups, where the turnover number and quantum yield of CO formation were 273 and 6.7%, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2016, "Volume": 138, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4354, "End Page": 4357, "Article Number": null, "DOI": "10.1021/jacs.6b01970", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b01970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373748000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stolterfoht, M; Caprioglio, P; Wolff, CM; Márquez, JA; Nordmann, J; Zhang, SS; Rothhardt, D; Hörmann, U; Amir, Y; Redinger, A; Kegelmann, L; Zu, FS; Albrecht, S; Koch, N; Kirchartz, T; Saliba, M; Unold, T; Neher, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stolterfoht, Martin; Caprioglio, Pietro; Wolff, Christian M.; Marquez, Jose A.; Nordmann, Joleik; Zhang, Shanshan; Rothhardt, Daniel; Hoermann, Ulrich; Amir, Yohai; Redinger, Alex; Kegelmann, Lukas; Zu, Fengshuo; Albrecht, Steve; Koch, Norbert; Kirchartz, Thomas; Saliba, Michael; Unold, Thomas; Neher, Dieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The impact of energy alignment and interfacial recombination on the internal and external open-circuit voltage of perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V-OC) of the cell. In order to realize the full thermodynamic potential of the perovskite absorber, both the electron and hole transport layer (ETL/HTL) need to be as selective as possible. By measuring the photoluminescence yield of perovskite/CTL heterojunctions, we quantify the non-radiative interfacial recombination currents in pin- and nip-type cells including high efficiency devices (21.4%). Our study comprises a wide range of commonly used CTLs, including various hole-transporting polymers, spiro-OMeTAD, metal oxides and fullerenes. We find that all studied CTLs limit the V-OC by inducing an additional non-radiative recombination current that is in most cases substantially larger than the loss in the neat perovskite and that the least-selective interface sets the upper limit for the V-OC of the device. Importantly, the V-OC equals the internal quasi-Fermi level splitting (QFLS) in the absorber layer only in high efficiency cells, while in poor performing devices, the V-OC is substantially lower than the QFLS. Using ultraviolet photoelectron spectroscopy and differential charging capacitance experiments we show that this is due to an energy level mis-alignment at the p-interface. The findings are corroborated by rigorous device simulations which outline important considerations to maximize the V-OC. This work highlights that the challenge to suppress non-radiative recombination losses in perovskite cells on their way to the radiative limit lies in proper energy level alignment and in suppression of defect recombination at the interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 704, "Times Cited, All Databases": 726, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2778, "End Page": 2788, "Article Number": null, "DOI": "10.1039/c9ee02020a", "DOI Link": "http://dx.doi.org/10.1039/c9ee02020a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486019600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gonzalez, JM; Oleynik, II", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonzalez, Joseph M.; Oleynik, Ivan I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-dependent properties of SnS2 and SnSe2 two-dimensional materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The layer-dependent structural, electronic, and vibrational properties of SnS2 and SnSe2 are investigated using first-principles density functional theory (DFT). The in-plane lattice constants, interlayer distances and binding energies are found to be layer-independent. Bulk SnS2 and SnSe2 are both indirect band gap semiconductors with E-g = 2.18 and 1.07 eV, respectively. Few-layer and monolayer 2D systems also possess an indirect band gap, which is increased to 2.41 and 1.69 eV for single layers of SnS2 and SnSe2. The effective mass theory of 2D excitons, which takes into account the combined effect of the anisotropy, nonlocal 2D screening and layer-dependent 3D screening, predicts strong excitonic effects. The binding energy of indirect excitons in monolayer samples, E-x similar to 0.9 eV, is substantially reduced to E-x = 0.14 eV in bulk SnS2 and E-x = 0.09 eV in bulk SnSe2. The layer-dependent Raman spectra display a strong decrease of intensities of the Raman active A(1g) mode upon decreasing the number of layers down to a monolayer, by a factor of 7 in the case of SnS2 and a factor of 20 in the case of SnSe2, which can be used to identify the number of layers in a 2D sample.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 29", "Publication Year": 2016, "Volume": 94, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125443, "DOI": "10.1103/PhysRevB.94.125443", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.125443", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385047900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seo, S; Jo, SH; Kim, S; Shim, J; Oh, S; Kim, JH; Heo, K; Choi, JW; Choi, C; Oh, S; Kuzum, D; Wong, HSP; Park, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seo, Seunghwan; Jo, Seo-Hyeon; Kim, Sungho; Shim, Jaewoo; Oh, Seyong; Kim, Jeong-Hoon; Heo, Keun; Choi, Jae-Woong; Choi, Changhwan; Oh, Saeroonter; Kuzum, Duygu; Wong, H. -S. Philip; Park, Jin-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial optic-neural synapse for colored and color-mixed pattern recognition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The priority of synaptic device researches has been given to prove the device potential for the emulation of synaptic dynamics and not to functionalize further synaptic devices for more complex learning. Here, we demonstrate an optic-neural synaptic device by implementing synaptic and optical-sensing functions together on h-BN/WSe2 heterostructure. This device mimics the colored and color-mixed pattern recognition capabilities of the human vision system when arranged in an optic-neural network. Our synaptic device demonstrates a close to linear weight update trajectory while providing a large number of stable conduction states with less than 1% variation per state. The device operates with low voltage spikes of 0.3 V and consumes only 66 fJ per spike. This consequently facilitates the demonstration of accurate and energy efficient colored and color-mixed pattern recognition. The work will be an important step toward neural networks that comprise neural sensing and training functions for more complex pattern recognition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 559, "Times Cited, All Databases": 590, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5106, "DOI": "10.1038/s41467-018-07572-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07572-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451742700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McEnulley, JM; Singh, AR; Schwalbe, JA; Kibsgaard, J; Lin, JC; Cargnello, M; Jaramillo, TF; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McEnulley, Joshua M.; Singh, Aayush R.; Schwalbe, Jay A.; Kibsgaard, Jakob; Lin, John C.; Cargnello, Matteo; Jaramillo, Thomas F.; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ammonia synthesis from N2 and H2O using a lithium cycling electrification strategy at atmospheric pressure", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia production is imperative to providing food for a growing world population. However, the primary method of synthetic ammonia production, the Haber Bosch process, is resource demanding and unsustainable. Here we report a novel ammonia production strategy, exemplified in an electrochemical lithium cycling process, which provides a pathway to sustainable ammonia synthesis via the ability to directly couple to renewable sources of electricity and can facilitate localized production. Whereas traditional aqueous electrochemical approaches are typically dominated by the hydrogen evolution reaction (HER), we are able to circumvent the HER by using a stepwise approach which separates the reduction of N-2 from subsequent protonation to NH3, thus our synthesis method is predominulltly selective for ammonia production. Density functional theory calculations for thermodynamic and diffusion energy barrier insights suggest that Li-based materials are well suited to carry out this process, though other materials may also be useful. The three steps of the demonstrated process are LiOH electrolysis, direct nitridation of Li, and the exothermic release of ammonia from Li3N, which reproduces the LiOH, completing the cycle. The process uses N-2 and H2O at atmospheric pressure and reasonable temperatures, and, while approaching industrial level electrolytic current densities, we report an initial current efficiency of 88.5% toward ammonia production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2017, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1621, "End Page": 1630, "Article Number": null, "DOI": "10.1039/c7ee01126a", "DOI Link": "http://dx.doi.org/10.1039/c7ee01126a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405279900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathew, K; Sundararaman, R; Letchworth-Weaver, K; Arias, TA; Hennig, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathew, Kiran; Sundararaman, Ravishankar; Letchworth-Weaver, Kendra; Arias, T. A.; Hennig, Richard G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Implicit solvation model for density-functional study of nullocrystal surfaces and reaction pathways", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-liquid interfaces are at the heart of many modern-day technologies and provide a challenge to many materials simulation methods. A realistic first-principles computational study of such systems entails the inclusion of solvent effects. In this work, we implement an implicit solvation model that has a firm theoretical foundation into the widely used density-functional code Vienna ab initio Software Package. The implicit solvation model follows the framework of joint density functional theory. We describe the framework, our algorithm and implementation, and benchmarks for small molecular systems. We apply the solvation model to study the surface energies of different facets of semiconducting and metallic nullocrystals and the S(N)2 reaction pathway. We find that solvation reduces the surface energies of the nullocrystals, especially for the semiconducting ones and increases the energy barrier of the S(N)2 reaction. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2107, "Times Cited, All Databases": 2217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2014, "Volume": 140, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 84106, "DOI": "10.1063/1.4865107", "DOI Link": "http://dx.doi.org/10.1063/1.4865107", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332485900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, LJ; Wang, K; Wei, W; Wang, LL; Han, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lianjia; Wang, Kang; Wei, Wei; Wang, Lili; Han, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance flexible sensing devices based on polyaniline/MXene nullocomposites", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active two-dimensional (2D) nullocomposites, integrating the unique merits of individual components and synergistic effects of composites, are greatly desired for flexible sensing device applications. Although 2D transition metal carbides and nitrides (MXenes) combined with their high metallic conductivity and versatile surface chemistry have shown its huge potential for sensing reactions, it still remains a major challenge to construct functional materials with intriguing sensing performance at room temperature (RT). Herein, we used an integration of density functional theory (DFT) simulations and bulk electrosensitive measurements to show high electrocatalytic sensitivity of polyaniline/MXene (PANI/Ti3C2Tx) nullocomposites. Thanks to the synergistic properties of nullocomposites and high catalytic/absorption capacity of Ti3C2Tx MXene, PANI nulloparticles are rationally decorated on Ti3C2Tx nullosheet surface via in situ polymerization by low temperature approach to induce remarkable detection sensitivity, rapid response/recovery rate, and mechanical stability at RT. This study offers a versatile platform to use MXenes to fabricate 2D nullocomposites materials for high-performance flexible gas sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 407, "End Page": 416, "Article Number": null, "DOI": "10.1002/inf2.12032", "DOI Link": "http://dx.doi.org/10.1002/inf2.12032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000554897200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Andrei, V; Ucoski, GM; Pornrungroj, C; Uswachoke, C; Wang, Q; Achilleos, DS; Kasap, H; Sokol, KP; Jagt, RA; Lu, HJ; Lawson, T; Wagner, A; Pike, SD; Wright, DS; Hoye, RLZ; MacManus-Driscoll, JL; Joyce, HJ; Friend, RH; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Andrei, Virgil; Ucoski, Geani M.; Pornrungroj, Chanon; Uswachoke, Chawit; Wang, Qian; Achilleos, Demetra S.; Kasap, Hatice; Sokol, Katarzyna P.; Jagt, Robert A.; Lu, Haijiao; Lawson, Takashi; Wagner, Andreas; Pike, Sebastian D.; Wright, Dominic S.; Hoye, Robert L. Z.; MacManus-Driscoll, Judith L.; Joyce, Hannah J.; Friend, Richard H.; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Floating perovskite-BiVO4 devices for scalable solar fuel production", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical (PEC) artificial leaves hold the potential to lower the costs of sustainable solar fuel production by integrating light harvesting and catalysis within one compact device. However, current deposition techniques limit their scalability(1), whereas fragile and heavy bulk materials can affect their transport and deployment. Here we demonstrate the fabrication of lightweight artificial leaves by employing thin, flexible substrates and carbonaceous protection layers. Lead halide perovskite photocathodes deposited onto indium tin oxide-coated polyethylene terephthalate achieved an activity of 4,266 mu mol H-2 g(-1) h(-1) using a platinum catalyst, whereas photocathodes with a molecular Co catalyst for CO2 reduction attained a high CO:H-2 selectivity of 7.2 under lower (0.1 sun) irradiation. The corresponding lightweight perovskite-BiVO4 PEC devices showed unassisted solar-to-fuel efficiencies of 0.58% (H-2) and 0.053% (CO), respectively. Their potential for scalability is demonstrated by 100 cm(2) stand-alone artificial leaves, which sustained a comparable performance and stability (of approximately 24 h) to their 1.7 cm(2) counterparts. Bubbles formed under operation further enabled 30-100 mg cm(-2) devices to float, while lightweight reactors facilitated gas collection during outdoor testing on a river. This leaf-like PEC device bridges the gulf in weight between traditional solar fuel approaches, showcasing activities per gram comparable to those of photocatalytic suspensions and plant leaves. The presented lightweight, floating systems may enable open-water applications, thus avoiding competition with land use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2022, "Volume": 608, "Issue": 7923, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 518, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04978-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04978-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842264100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, W; Zhang, WY; Si, YB; Wang, DH; Fu, YZ; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Wei; Zhang, Wanying; Si, Yubing; Wang, Donghai; Fu, Yongzhu; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial dual solid-electrolyte interfaces based on in situ organothiol transformation in lithium sulfur battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li-S cell with BTT delivers a specific discharge capacity of 1,239mAhg(-1) (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li-S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li-S batteries. Lithium-sulfur batteries suffer from the shuttle effect of lithium polysulfides and interfacial instability of the lithium metal anode. Here, the authors use 1,3,5-benzenetrithiol as an electrolyte additive to protect sulfur cathode and lithium metal anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3031, "DOI": "10.1038/s41467-021-23155-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23155-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659141000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JY; Cui, PX; Zhao, GQ; Rui, K; Lao, MM; Chen, YP; Zheng, XS; Jiang, YZ; Pan, HG; Dou, SX; Sun, WP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jiayi; Cui, Peixin; Zhao, Guoqiang; Rui, Kun; Lao, Mengmeng; Chen, Yaping; Zheng, Xusheng; Jiang, Yinzhu; Pan, Hongge; Dou, Shi Xue; Sun, Wenping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Coordinate Iridium Oxide Confined on Graphitic Carbon Nitride for Highly Efficient Oxygen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active and durable electrocatalysts for the oxygen evolution reaction (OER) is greatly desired. Iridium oxide/graphitic carbon nitride (IrO2/GCN) heterostructures are designed with low-coordinate IrO2 nulloparticles (NPs) confined on superhydrophilic highly stable GCN nullosheets for efficient acidic OER. The GCN nullosheets not only ensure the homogeneous distribution and confinement of IrO2 NPs but also endows the heterostructured catalyst system with a superhydrophilic surface, which can maximize the exposure of active sites and promotes mass diffusion. The coordination number of Ir atoms is decreased owing to the strong interaction between IrO2 and GCN, leading to lattice strain and increment of electron density around Ir sites and hence modulating the attachment between the catalyst and reaction intermediates. The optimized IrO2/GCN heterostructure delivers not only by far the highest mass activity among the reported IrO2-based catalysts but also decent durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2019, "Volume": 58, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12540, "End Page": 12544, "Article Number": null, "DOI": "10.1002/anie.201907017", "DOI Link": "http://dx.doi.org/10.1002/anie.201907017", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481305400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, BT; Zhang, L; Zhen, DX; Yoo, S; Ding, Y; Chen, DC; Chen, Y; Zhang, QB; Doyle, B; Xiong, XH; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Bote; Zhang, Lei; Zhen, Dongxing; Yoo, Seonyoung; Ding, Yong; Chen, Dongchang; Chen, Yu; Zhang, Qiaobao; Doyle, Brian; Xiong, Xunhui; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A tailored double perovskite nullofiber catalyst enables ultrafast oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable metal-air batteries and water splitting are highly competitive options for a sustainable energy future, but their commercialization is hindered by the absence of cost-effective, highly efficient and stable catalysts for the oxygen evolution reaction. Here we report the rational design and synthesis of a double perovskite PrBa0.5Sr0.5Co1.5Fe0.5O5+delta nullofiber as a highly efficient and robust catalyst for the oxygen evolution reaction. Co-doping of strontium and iron into PrBaCo2O5+delta is found to be very effective in enhancing intrinsic activity (normalized by the geometrical surface area, similar to 4.7 times), as validated by electrochemical measurements and first-principles calculations. Further, the nullofiber morphology enhances its mass activity remarkably (by similar to 20 times) as the diameter is reduced to similar to 20 nm, attributed to the increased surface area and an unexpected intrinsic activity enhancement due possibly to a favourable eg electron filling associated with partial surface reduction, as unravelled from chemical titration and electron energy-loss spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14586, "DOI": "10.1038/ncomms14586", "DOI Link": "http://dx.doi.org/10.1038/ncomms14586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394796900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vyatskikh, A; Delalande, S; Kudo, A; Zhang, X; Portela, CM; Greer, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vyatskikh, Andrey; Delalande, Stephane; Kudo, Akira; Zhang, Xuan; Portela, Carlos M.; Greer, Julia R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of 3D nullo-architected metals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most existing methods for additive manufacturing (AM) of metals are inherently limited to similar to 20-50 mu m resolution, which makes them untenable for generating complex 3D-printed metallic structures with smaller features. We developed a lithography-based process to create complex 3D nullo-architected metals with similar to 100 nm resolution. We first synthesize hybrid organic-inorganic materials that contain Ni clusters to produce a metal-rich photoresist, then use two-photon lithography to sculpt 3D polymer scaffolds, and pyrolyze them to volatilize the organics, which produces a > 90 wt% Ni-containing architecture. We demonstrate nullolattices with octet geometries, 2 mu m unit cells and 300-400-nm diameter beams made of 20-nm grained nullocrystalline, nulloporous Ni. nullomechanical experiments reveal their specific strength to be 2.1-7.2 MPa g(-1) cm(3), which is comparable to lattice architectures fabricated using existing metal AM processes. This work demonstrates an efficient pathway to 3D-print micro-architected and nullo-architected metals with sub-micron resolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 483, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 593, "DOI": "10.1038/s41467-018-03071-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03071-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424636700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, HLL; Kent, PRC; Hennig, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Houlong L.; Kent, P. R. C.; Hennig, Richard G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong anisotropy and magnetostriction in the two-dimensional Stoner ferromagnet Fe3GeTe2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computationally characterizing magnetic properies of novel two-dimensional (2D) materials serves as an important first step of exploring possible applications. Using density-functional theory, we show that single-layer Fe3GeTe2 is a potential 2D material with sufficiently low formation energy to be synthesized by mechanical exfoliation from the bulk phase with a van der Waals layered structure. In addition, we calculated the phonon dispersion demonstrating that single-layer Fe3GeTe2 is dynamically stable. Furthermore, we find that similar to the bulk phase, 2D Fe3GeTe2 exhibits amagnetic moment that originates from a Stoner instability. In contrast to other 2D materials, we find that single-layer Fe3GeTe2 exhibits a significant uniaxial magnetocrystalline anisotropy energy of 920 mu eV per Fe atom originating from spin-orbit coupling. Finally, we show that applying biaxial tensile strains enhances the anisotropy energy, which reveals strong magnetostriction in single-layer Fe3GeTe2 with a sizable magneostrictive coefficient. Our results indicate that single-layer Fe3GeTe2 is potentially useful for magnetic storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2016, "Volume": 93, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134407, "DOI": "10.1103/PhysRevB.93.134407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.134407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373566000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jana, A; Cho, S; Patil, SA; Meena, A; Jo, Y; Sree, VG; Park, Y; Kim, H; Im, H; Taylor, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jana, Atanu; Cho, Sangeun; Patil, Supriya A.; Meena, Abhishek; Jo, Yongcheol; Sree, Vijaya Gopalan; Park, Youngsin; Kim, Hyungsang; Im, Hyunsik; Taylor, Robert A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite: Scintillators, direct detectors, and X-ray imagers", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskites (HPs) are used in various applications, including solar cells, light-emitting diodes, lasers, and photodetectors. These materials have recently received a great deal of attention as highenergy radiation detectors and scintillators due to their excellent light yield, mobility-lifetime product (ms), and X-ray sensitivity. In addition, due to their solution-processability and low cost, perovskite materials could be used to produce thick perovskite films across wide areas, allowing for low-dose X-ray imaging. Perovskite-based scintillators and detectors could eventually replace commercialized products like thallium-doped cesium iodide (CsI:Tl) and amorphous silicon (Si). Here, we review all of the key properties of HPs, the relevant terminology necessary for radiation detection and scintillation, the physical mechanisms underlying their operation, the fabrication process, and perovskite crystals and thin-films of varying dimensionality used for high-energy radiation detection. We also cover the critical issues and solutions that HPs as detectors, scintillators, and imagers face.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 55, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 110, "End Page": 136, "Article Number": null, "DOI": "10.1016/j.mattod.2022.04.009", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2022.04.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000829229000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LY; Wu, YC; Huang, L; Liu, KS; Duployer, B; Rozier, P; Taberna, PL; Simon, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Liyuan; Wu, Yih-Chyng; Huang, Liang; Liu, Kaisi; Duployer, Benjamin; Rozier, Patrick; Taberna, Pierre-Louis; Simon, Patrice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkali Ions Pre-Intercalated Layered MnO2 nullosheet for Zinc-Ions Storage", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, rechargeable zinc-ion batteries in mild acidic electrolytes have attracted considerable research interest as a result of their high sustainability, safety, and low cost. However, the use of conventional Zn-ion storage materials is hindered by insufficient specific capacity, sluggish reaction kinetics, or poor cycle life. Here, these limitations are addressed by pre-intercalating alkali ions and water crystals into layered delta-MnO2 (birnessite) to prepare K0.27MnO2 center dot 0.54H(2)O (KMO) and Na0.55Mn2O4 center dot 1.5H(2)O with ultrathin nullosheet morphology via a rapid molten salt method. In these materials, alkali ions and water crystals act as pillars to stabilize the layered structures, which can enable rapid diffusion of cations in the KMO structure, resulting in high power capability (90 mAh g(-1) at 10 C) and good cycling stability. Furthermore, electrochemical quartz crystal microbalance measurements shed light on the charge storage mechanism of KMO in an aqueous Zn-ion battery which, combined together with in-operando X-ray diffraction techniques, suggests that the charge storage process is dominated by the (de)intercalation of H3O+ with further dissolution-precipitation of Zn-4(OH)(6)(SO4)center dot 5H(2)O solid product on the KMO surface during cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 11, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101287, "DOI": "10.1002/aenm.202101287", "DOI Link": "http://dx.doi.org/10.1002/aenm.202101287", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000666592500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, E; Zhu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Evan; Zhu, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards strength-ductility synergy through the design of heterogeneous nullostructures in metals", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metals can be processed to reach ultra-high strength, but usually at a drastic loss of ductility. Here, we review recent advances in overcoming this tradeoff, by purposely deploying heterogeneous nullostructures in an otherwise single-phase metal. Several structural designs are being explored, including bimodal, harmonic, lamellar, gradient, domain-dispersed, and hierarchical nullostructures. These seemingly distinct tactics share a unifying design principle in that the intentional structural heterogeneities induce non-homogeneous plastic deformation, and the nullometer-scale features dictate steep strain gradients, thereby enhancing strain hardening and consequently uniform tensile ductility at high flow stresses. Moreover, these heterogeneous nullostructures in metals play a role similar to multiple phases in complex alloys, functionally graded materials and composites, sharing common material design and mechanics principles. Our review advocates this broad vision to help guide future innovations towards a synergy between high strength and high ductility, through highlighting several recent designs as well as identifying outstanding challenges and opportunities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 827, "Times Cited, All Databases": 870, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2017, "Volume": 20, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 323, "End Page": 331, "Article Number": null, "DOI": "10.1016/j.mattod.2017.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2017.02.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408367200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CB; Kopold, P; Li, WH; van Aken, PA; Maier, J; Yu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Changbao; Kopold, Peter; Li, Weihan; van Aken, Peter A.; Maier, Joachim; Yu, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A General Strategy to Fabricate Carbon-Coated 3D Porous Interconnected Metal Sulfides: Case Study of SnS/C nullocomposite for High-Performance Lithium and Sodium Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal sulfides have a great potential for energy storage due to the pronouncedly higher capacity (owing to conversion to metal or even alloy) than traditional insertion electrode materials. However, the poor cycling stability still limits the development and application in lithium and sodium ion batteries. Here, taking SnS as a model material, a novel general strategy is proposed to fabricate a 3D porous interconnected metal sulfide/carbon nullocomposite by the electrostatic spray deposition technique without adding any expensive carbonaceous materials such as graphene or carbon nullotube. In this way, small nullorods of SnS are generated with sizes of approximate to 10-20 nm embedded in amorphous carbon and self-assembled into a 3D porous interconnected nullocomposite. The SnS:C is directly deposited on the Ti foil as a current collector and neither conductive additives nor binder are needed for battery assembly. Such electrodes exhibit a high reversible capacity, high rate capability, and long cycling stability for both lithium and sodium storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500200, "DOI": "10.1002/advs.201500200", "DOI Link": "http://dx.doi.org/10.1002/advs.201500200", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369003500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, ZC; Lustig, WP; Zhang, JM; Zheng, C; Wang, H; Teat, SJ; Gong, QH; Rudd, ND; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zhichao; Lustig, William P.; Zhang, Jingming; Zheng, Chong; Wang, Hao; Teat, Simon J.; Gong, Qihan; Rudd, Nathan D.; Li, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective Detection of Mycotoxins by a Highly Luminescent Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We designed and synthesized a new luminescent metal organic framework (LMOF). LMOF-241 is highly porous and emits strong blue light with high efficiency. We demonstrate for the first time that very fast and extremely sensitive optical detection can be achieved, making use of the fluorescence quenching of an LMOF material. The compound is responsive to Aflatoxin B-1 at parts per billion level, which makes it the best performing luminescence-based chemical sensor to date. We studied the electronic properties of LMOF-241 and selected mycotoxins, as well as the extent of mycotoxin-LMOF interactions, employing theoretical methods. Possible electron and energy transfer mechanisms are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2015, "Volume": 137, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16209, "End Page": 16215, "Article Number": null, "DOI": "10.1021/jacs.5b10308", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b10308", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367636600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, HY; Liu, KW; Hu, LF; Al-Ghamdi, AA; Fang, XS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hongyu; Liu, Kewei; Hu, Linfeng; Al-Ghamdi, Ahmed A.; Fang, Xiaosheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New concept ultraviolet photodetectors", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Benefitting from the continuous innovations in semiconductor materials and device fabricating techniques, ultraviolet (UV) photodetectors have been successfully used in advanced communications, flame detection, air purification, ozone sensing and leak detection, among others, in the past few decades. Nowadays, nulloscience, nullofabrication technologies and versatile materials have sparked a new vision of UV photodetectors, which move toward higher precision, lower energy consumption and greater miniaturization. This paper is thus mainly focused on the perspective of molding devices through exploring new materials and novel architectures inspired by state-of-the-art UV photodetectors, predicting the direction of next-generation photodetectors. It is expected that new concept UV photodetectors with smart, intelligent and multifunctional design will benefit daily life and the wellbeing of society in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 761, "Times Cited, All Databases": 799, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 18, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 493, "End Page": 502, "Article Number": null, "DOI": "10.1016/j.mattod.2015.06.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.06.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363533300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, XL; Fan, XQ; Zhu, YB; Liu, Y; Wu, PQ; Jiang, RH; Wu, B; Wu, HA; Zheng, H; Wang, JB; Ji, XY; Chen, YS; Liang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xinlei; Fan, Xiangqian; Zhu, Yinbo; Liu, Yang; Wu, Peiqi; Jiang, Renhui; Wu, Bao; Wu, Heng-An; Zheng, He; Wang, Jianbo; Ji, Xinyi; Chen, Yongsheng; Liang, Jiajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pushing detectability and sensitivity for subtle force to new limits with shrinkable nullochannel structured aerogel", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is an urgent need for developing electromechanical sensor with both ultralow detection limits and ultrahigh sensitivity to promote the progress of intelligent technology. Here we propose a strategy for fabricating a soft polysiloxane crosslinked MXene aerogel with multilevel nullochannels inside its cellular walls for ultrasensitive pressure detection. The easily shrinkable nullochannels and optimized material synergism endow the piezoresistive aerogel with an ultralow Young's modulus (140 Pa), numerous variable conductive pathways, and mechanical robustness. This aerogel can detect extremely subtle pressure signals of 0.0063 Pa, deliver a high pressure sensitivity over 1900 kPa(-1), and exhibit extraordinarily sensing robustness. These sensing properties make the MXene aerogel feasible for monitoring ultra-weak force signals arising from a human's deep-lying internal jugular venous pulses in a non-invasive manner, detecting the dynamic impacts associated with the landing and take-off of a mosquito, and performing static pressure mapping of a hair. The fabrication of pressure sensors with both ultralow detection limits and ultrahigh sensitivity is still challenging. Here, the authors propose a design strategy for fabricating a soft polysiloxane crosslinked MXene aerogel with multilevel nullochannels inside its cellular walls for ultrasensitive pressure detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1119, "DOI": "10.1038/s41467-022-28760-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28760-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763605200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, W; Lv, L; Ma, TF; Wang, XZ; Ying, JF; Yan, QW; Tan, X; Gao, JY; Xue, C; Yu, JH; Yao, YG; Wei, QP; Sun, R; Wang, Y; Liu, TH; Chen, T; Xiang, R; Jiang, N; Xue, QJ; Wong, CP; Maruyama, S; Lin, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Wen; Lv, Le; Ma, Tengfei; Wang, Xiangze; Ying, Junfeng; Yan, Qingwei; Tan, Xue; Gao, Jingyao; Xue, Chen; Yu, Jinhong; Yao, Yagang; Wei, Qiuping; Sun, Rong; Wang, Yan; Liu, Te-Huan; Chen, Tao; Xiang, Rong; Jiang, null; Xue, Qunji; Wong, Ching-Ping; Maruyama, Shigeo; Lin, Cheng-Te", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiscale Structural Modulation of Anisotropic Graphene Framework for Polymer Composites Achieving Highly Efficient Thermal Energy Management", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is usually embedded into polymer matrices for the development of thermally conductive composites, preferably forming an interconnected and anisotropic framework. Currently, the directional self-assembly of exfoliated graphene sheets is demonstrated to be the most effective way to synthesize anisotropic graphene frameworks. However, achieving a thermal conductivity enhancement (TCE) over 1500% with per 1 vol% graphene content in polymer matrices remains challenging, due to the high junction thermal resistance between the adjacent graphene sheets within the self-assembled graphene framework. Here, a multiscale structural modulation strategy for obtaining highly ordered structure of graphene framework and simultaneously reducing the junction thermal resistance is demonstrated. The resultant anisotropic framework contributes to the polymer composites with a record-high thermal conductivity of 56.8-62.4 W m(-1) K-1 at the graphene loading of approximate to 13.3 vol%, giving an ultrahigh TCE per 1 vol% graphene over 2400%. Furthermore, thermal energy management applications of the composites as phase change materials for solar-thermal energy conversion and as thermal interface materials for electronic device cooling are demonstrated. The finding provides valuable guidance for designing high-performance thermally conductive composites and raises their possibility for practical use in thermal energy storage and thermal management of electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003734, "DOI": "10.1002/advs.202003734", "DOI Link": "http://dx.doi.org/10.1002/advs.202003734", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619450900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Z; An, FL; Zhang, YY; Liang, ZY; Liu, WY; Xing, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhuan; An, Faliang; Zhang, Yayun; Liang, Zhiyan; Liu, Wenyuan; Xing, Mingyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single- atom Mo-Co catalyst with low biotoxicity for sustainable degradation of high- ionization- potential organic pollutants", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single -atom catalysts (SACs) are a promising area in environmental catalysis. We report on a bimetallic Co-Mo SAC that shows excellent performance in activating peroxymonosulfate (PMS) for sustainable degradation of organic pollutants with high ionization potential (IP > 8.5 eV). Density Functional Theory (DFT) calculations and experimental tests demonstrate that the Mo sites in Mo-Co SACs play a critical role in conducting electrons from organic pollutants to Co sites, leading to a 19.4 -fold increase in the degradation rate of phenol compared to the CoCl2-PMS group. The bimetallic SACs exhibit excellent catalytic performance even under extreme conditions and show long -term activation in 10-d experiments, efficiently degrading 600 mg/L of phenol. Moreover, the catalyst has negligible toxicity toward MDA- MB- 231, Hela, and MCF- 7 cells, making it an environmentally friendly option for sustainable water treatment. Our findings have important implications for the design of efficient SACs for environmental remediation and other applications in biology and medicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2023, "Volume": 120, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2305933120", "DOI": "10.1073/pnas.2305933120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2305933120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001052025900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Huang, MQ; Yu, XF; You, WB; Zhang, J; Liu, XH; Wang, M; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Huang, Mengqiu; Yu, Xuefeng; You, Wenbin; Zhang, Jie; Liu, Xianhu; Wang, Min; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-Derived Ni1-xCox@Carbon with Tunable nullo-Microstructure as Lightweight and Highly Efficient Electromagnetic Wave Absorber", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsic electric-magnetic property and special nullo-micro architecture of functional materials have a significant effect on its electromagnetic wave energy conversion, especially in the microwave absorption (MA) field. Herein, porous Ni1-xCox@Carbon composites derived from metal-organic framework (MOF) were successfully synthesized via solvothermal reaction and subsequent annealing treatments. Benefiting from the coordination, carbonized bimetallic Ni-Co-MOF maintained its initial skeleton and transformed into magnetic-carbon composites with tunable nullo-micro structure. During the thermal decomposition, generated magnetic particles/clusters acted as a catalyst to promote the carbonsp(2)arrangement, forming special core-shell architecture. Therefore, pure Ni@C microspheres displayed strong MA behaviors than other Ni1-xCox@Carbon composites. Surprisingly, magnetic-dielectric Ni@C composites possessed the strongest reflection loss value - 59.5 dB and the effective absorption frequency covered as wide as 4.7 GHz. Meanwhile, the MA capacity also can be boosted by adjusting the absorber content from 25% to 40%. Magnetic-dielectric synergy effect of MOF-derived Ni1-xCox@Carbon microspheres was confirmed by the off-axis electron holography technology making a thorough inquiry in the MA mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 150, "DOI": "10.1007/s40820-020-00488-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00488-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000553132900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SH; Liu, YY; Hao, YF; Yang, XP; Goddard, WA ; Zhang, XL; Cao, BQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuhua; Liu, Yuanyue; Hao, Yufeng; Yang, Xiaopeng; Goddard, William A., III; Zhang, Xiao Li; Cao, Bingqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen-Vacancy Abundant Ultrafine Co3O4/Graphene Composites for High-Rate Supercapacitor Electrodes", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The metal oxides/graphene composites are one of the most promising supercapacitors (SCs) electrode materials. However, rational synthesis of such electrode materials with controllable conductivity and electrochemical activity is the topical challenge for high-performance SCs. Here, the Co3O4/graphene composite is taken as a typical example and develops a novel/universal one-step laser irradiation method that overcomes all these challenges and obtains the oxygen-vacancy abundant ultrafine Co3O4 nulloparticles/graphene (UCNG) composites with high SCs performance. First-principles calculations show that the surface oxygen vacancies can facilitate the electrochemical charge transfer by creating midgap electronic states. The specific capacitance of the UCNG electrode reaches 978.1 F g(-1) (135.8 mA h g(-1)) at the current densities of 1 A g(-1) and retains a high capacitance retention of 916.5 F g(-1) (127.3 mA h g(-1)) even at current density up to 10 A g(-1), showing remarkable rate capability (more than 93.7% capacitance retention). Additionally, 99.3% of the initial capacitance is maintained after consecutive 20 000 cycles, demonstrating enhanced cycling stability. Moreover, this proposed laser-assisted growth strategy is demonstrated to be universal for other metal oxide/graphene composites with tuned electrical conductivity and electrochemical activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700659, "DOI": "10.1002/advs.201700659", "DOI Link": "http://dx.doi.org/10.1002/advs.201700659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430460200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aristidou, N; Eames, C; Sanchez-Molina, I; Bu, XN; Kosco, J; Islam, MS; Haque, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aristidou, Nicholas; Eames, Christopher; Sanchez-Molina, Irene; Bu, Xiangnull; Kosco, Jan; Islam, M. Saiful; Haque, Saif A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methylammonium lead halide perovskites are attracting intense interest as promising materials for next-generation solar cells, but serious issues related to long-term stability need to be addressed. Perovskite films based on CH3NH3PbI3 undergo rapid degradation when exposed to oxygen and light. Here, we report mechanistic insights into this oxygen-induced photodegradation from a range of experimental and computational techniques. We find fast oxygen diffusion into CH3NH3PbI3 films is accompanied by photo-induced formation of highly reactive superoxide species. Perovskite films composed of small crystallites show higher yields of superoxide and lower stability. Ab initio simulations indicate that iodide vacancies are the preferred sites in mediating the photo-induced formation of superoxide species from oxygen. Thin-film passivation with iodide salts is shown to enhance film and device stability. The understanding of degradation phenomena gained from this study is important for the future design and optimization of stable perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1027, "Times Cited, All Databases": 1090, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15218, "DOI": "10.1038/ncomms15218", "DOI Link": "http://dx.doi.org/10.1038/ncomms15218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400962100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, LM; Hu, YW; Tang, SF; Iljin, A; Wang, JW; Zhang, ZM; Lu, TB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Li-Ming; Hu, Yu-Wen; Tang, Shang-Feng; Iljin, Andrey; Wang, Jia-Wei; Zhang, Zhi-Ming; Lu, Tong-Bu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe-CoP Electrocatalyst Derived from a Bimetallic Prussian Blue Analogue for Large-Current-Density Oxygen Evolution and Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Industrial application of overall water splitting requires developing readily available, highly efficient, and stable oxygen evolution electrocatalysts that can efficiently drive large current density. This study reports a facile and practical method to fabricate a non-noble metal catalyst by directly growing a Co-Fe Prussian blue analogue on a 3D porous conductive substrate, which is further phosphorized into a bifunctional Fe-doped CoP (Fe-CoP) electrocatalyst. The Fe-CoP/NF (nickel foam) catalyst shows efficient electrocatalytic activity for oxygen evolution reaction, requiring low over-potentials of 190, 295, and 428 mV to achieve 10, 500, and 1000 mA cm(-2) current densities in 1.0 m KOH solution. In addition, the Fe-CoP/NF can also function as a highly active electrocatalyst for hydrogen evolution reaction with a low overpotential of 78 mV at 10 mA cm(-2) current density in alkaline solution. Thus, the Fe-CoP/NF electrode with meso/macropores can act as both an anode and a cathode to fabricate an electrolyzer for overall water splitting, only requiring a cell voltage of 1.49 V to afford a 10 mA cm(-2) current density with remarkable stability. This performance appears to be among the best reported values and is much better than that of the IrO2-Pt/C-based electrolyzer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800949, "DOI": "10.1002/advs.201800949", "DOI Link": "http://dx.doi.org/10.1002/advs.201800949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marti, X; Fina, I; Frontera, C; Liu, J; Wadley, P; He, Q; Paull, RJ; Clarkson, JD; Kudrnovsky, J; Turek, I; Kunes, J; Yi, D; Chu, JH; Nelson, CT; You, L; Arenholz, E; Salahuddin, S; Fontcuberta, J; Jungwirth, T; Ramesh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marti, X.; Fina, I.; Frontera, C.; Liu, Jian; Wadley, P.; He, Q.; Paull, R. J.; Clarkson, J. D.; Kudrnovsky, J.; Turek, I.; Kunes, J.; Yi, D.; Chu, J-H.; Nelson, C. T.; You, L.; Arenholz, E.; Salahuddin, S.; Fontcuberta, J.; Jungwirth, T.; Ramesh, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature antiferromagnetic memory resistor", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The bistability of ordered spin states in ferromagnets provides the basis for magnetic memory functionality. The latest generation of magnetic random access memories rely on an efficient approach in which magnetic fields are replaced by electrical means for writing and reading the information in ferromagnets. This concept may eventually reduce the sensitivity of ferromagnets to magnetic field perturbations to being a weakness for data retention and the ferromagnetic stray fields to an obstacle for high-density memory integration. Here we report a room-temperature bistable antiferromagnetic (AFM) memory that produces negligible stray fields and is insensitive to strong magnetic fields. We use a resistor made of a FeRh AFM, which orders ferromagnetically roughly 100 K above room temperature, and therefore allows us to set different collective directions for the Fe moments by applied magnetic field. On cooling to room temperature, AFM order sets in with the direction of the AFM moments predetermined by the field and moment direction in the high-temperature ferromagnetic state. For electrical reading, we use an AFM analogue of the anisotropic magnetoresistance. Our microscopic theory modelling confirms that this archetypical spintronic effect, discovered more than 150 years ago in ferromagnets, is also present in AFMs. Our work demonstrates the feasibility of fabricating room-temperature spintronic memories with AFMs, which in turn expands the base of available magnetic materials for devices with properties that cannot be achieved with ferromagnets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 574, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 367, "End Page": 374, "Article Number": null, "DOI": "10.1038/NMAT3861", "DOI Link": "http://dx.doi.org/10.1038/NMAT3861", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333397100021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zumstein, MT; Schintlmeister, A; Nelson, TF; Baumgartner, R; Woebken, D; Wagner, M; Kohler, HPE; McNeill, K; Sander, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zumstein, Michael Thomas; Schintlmeister, Arno; Nelson, Taylor Frederick; Baumgartner, Rebekka; Woebken, Dagmar; Wagner, Michael; Kohler, Hans-Peter E.; McNeill, Kristopher; Sander, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradation of synthetic polymers in soils: Tracking carbon into CO2 and microbial biomass", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic materials are widely used in agricultural applications to achieve food security for the growing world population. The use of biodegradable instead of nonbiodegradable polymers in single-use agricultural applications, including plastic mulching, promises to reduce plastic accumulation in the environment. We present a novel approach that allows tracking of carbon from biodegradable polymers into CO2 and microbial biomass. The approach is based on C-13-labeled polymers and on isotope-specific analytical methods, including nulloscale secondary ion mass spectrometry (nulloSIMS). Our results unequivocally demonstrate the biodegradability of poly(butylene adipate-co-terephthalate) (PBAT), an important polyester used in agriculture, in soil. Carbon from each monomer unit of PBAT was used by soil microorganisms, including filamentous fungi, to gain energy and to form biomass. This work advances both our conceptual understanding of polymer biodegradation and the methodological capabilities to assess this process in natural and engineered environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaas9024", "DOI": "10.1126/sciadv.aas9024", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aas9024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, XY; Wang, F; Wei, Q; Li, HS; Shang, YQ; Zhou, WJ; Wang, C; Cheng, PH; Chen, Q; Chen, LW; Ning, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Xianyuan; Wang, Fei; Wei, Qi; Li, Hansheng; Shang, Yuequn; Zhou, Wenjia; Wang, Cheng; Cheng, Peihong; Chen, Qi; Chen, Liwei; Ning, Zhijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin perovskite is rising as a promising candidate to address the toxicity and theoretical efficiency limitation of lead perovskite. However, the voltage and efficiency of tin perovskite solar cells are much lower than lead counterparts. Herein, indene-C-60 bisadduct with higher energy level is utilized as an electron transporting material for tin perovskite solar cells. It suppresses carrier concentration increase caused by remote doping, which significantly reduces interface carriers recombination. Moreover, indene-C-60 bisadduct increases the maximum attainable photovoltage of the device. As a result, the use of indene-C-60 bisadduct brings unprecedentedly high voltage of 0.94 V, which is over 50% higher than that of 0.6 V for device based on [6,6]-phenyl-C61-butyric acid methyl ester. The device shows a record power conversion efficiency of 12.4% reproduced in an accredited independent photovoltaic testing lab.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1245, "DOI": "10.1038/s41467-020-15078-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15078-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549162600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, FM; Gao, HQ; Lei, YX; Dai, WB; Liu, MC; Zheng, XY; Cai, ZX; Huang, XB; Wu, HY; Ding, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Fuming; Gao, Heqi; Lei, Yunxiang; Dai, Wenbo; Liu, Miaochang; Zheng, Xiaoyan; Cai, Zhengxu; Huang, Xiaobo; Wu, Huayue; Ding, Dan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Guest-host doped strategy for constructing ultralong-lifetime near-infrared organic phosphorescence materials for bioimaging", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic near-infrared room temperature phosphorescence materials have unparalleled advantages in bioimaging due to their excellent penetrability. However, limited by the energy gap law, the near-infrared phosphorescence materials (>650 nm) are very rare, moreover, the phosphorescence lifetimes of these materials are very short. In this work, we have obtained organic room temperature phosphorescence materials with long wavelengths (600/657-681/732 nm) and long lifetimes (102-324 ms) for the first time through the guest-host doped strategy. The guest molecule has sufficient conjugation to reduce the lowest triplet energy level and the host assists the guest in exciton transfer and inhibits the non-radiative transition of guest excitons. These materials exhibit good tissue penetration in bioimaging. Thanks to the characteristic of long lifetime and long wavelength emissive phosphorescence materials, the tumor imaging in living mice with a signal to background ratio value as high as 43 is successfully realized. This work provides a practical solution for the construction of organic phosphorescence materials with both long wavelengths and long lifetimes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 186, "DOI": "10.1038/s41467-021-27914-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27914-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849942600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, H; Liu, Z; Li, N; Shi, BJ; Zou, Y; Xie, F; Ma, Y; Li, Z; Li, H; Zheng, Q; Qu, XC; Fan, YB; Wang, ZL; Zhang, H; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Han; Liu, Zhuo; Li, Ning; Shi, Bojing; Zou, Yang; Xie, Feng; Ma, Ye; Li, Zhe; Li, Hu; Zheng, Qiang; Qu, Xuecheng; Fan, Yubo; Wang, Zhong Lin; Zhang, Hao; Li, Zhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symbiotic cardiac pacemaker", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-powered implantable medical electronic devices that harvest biomechanical energy from cardiac motion, respiratory movement and blood flow are part of a paradigm shift that is on the horizon. Here, we demonstrate a fully implanted symbiotic pacemaker based on an implantable triboelectric nullogenerator, which achieves energy harvesting and storage as well as cardiac pacing on a large-animal scale. The symbiotic pacemaker successfully corrects sinus arrhythmia and prevents deterioration. The open circuit voltage of an implantable triboelectric nullogenerator reaches up to 65.2 V. The energy harvested from each cardiac motion cycle is 0.495 mu J, which is higher than the required endocardial pacing threshold energy (0.377 mu J). Implantable triboelectric nullogenerators for implantable medical devices offer advantages of excellent output performance, high power density, and good durability, and are expected to find application in fields of treatment and diagnosis as in vivo symbiotic bioelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1821, "DOI": "10.1038/s41467-019-09851-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09851-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465200000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Runnerstrom, EL; Llordés, A; Lounis, SD; Milliron, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Runnerstrom, Evan L.; Llordes, Anna; Lounis, Sebastien D.; Milliron, Delia J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullostructured electrochromic smart windows: traditional materials and NIR-selective plasmonic nullocrystals", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochromic devices, which dynamically change colour under applied potential, are widely studied for use in energy-efficient smart windows. To improve the viability of smart windows, many researchers are utilizing nullomaterials, which can provide electrochromic devices with improved colouration efficiencies, faster switching times, longer cycle lives, and potentially reduced costs. In an effort to demonstrate a new type of electrochromic device that goes beyond the capabilities of commonly used electrochromic materials, researchers have turned to plasmonic transparent conductive oxide (TCO) nullocrystals. Electrochemical injection of electrons into plasmonic TCO nullocrystal films induces a shift in the plasmon frequency and gives rise to the new functionality of selective optical modulation in the near-infrared region of the solar spectrum. These nullocrystals can be used as building blocks to enable creation of advanced electrochromic devices containing mesoporous electrodes or nullocrystal-in-glass composites. Such devices have been important in advancing the field towards achieving the ideal smart window with independent control over visible and NIR transmittance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 50, "Issue": 73, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10555, "End Page": 10572, "Article Number": null, "DOI": "10.1039/c4cc03109a", "DOI Link": "http://dx.doi.org/10.1039/c4cc03109a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340899500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XH; Liu, C; Feng, SP; Fang, NXL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xin-Hao; Liu, Chang; Feng, Shien-Ping; Fang, Nicholas Xuanlai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Light Management with Thermochromic Hydrogel Microparticles for Smart Windows", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control of solar transmission through windows promises to reduce building energy consumption. However, the ability of current chromogenic technologies to regulate solar gain with the tunable extinction of phase-change materials is still far from optimum. We report a strategy for optimizing the transmittance modulation range of temperature-responsive hydrogel particles by means of tuning the light-scattering behaviors through controlling particle size and internal structure. An emerging thermochromic material, poly(N-isopropylacrylamide)-2-aminoethylmethacrylate hydrochloride (pNIPAm-AEMA) microparticles, was synthesized to demonstrate this strategy. The average size of pNIPAm-AEMA microparticles varies from 1,388 nm at 25 degrees C to 546 nm at 35 degrees C, contributing to an unprecedented infrared transmittance modulation of 75.6%. A high luminous transmittance of 87.2% at 25 degrees C had also been accomplished. An investigation of the tunable scattering behaviors of pNIPAm-AEMA particles provided mechanistic insight into light management by this class of materials, the application field of which is beyond energy-saving smart windows.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 302, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.019", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Dong, QF; Li, T; Gruverman, A; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qi; Dong, Qingfeng; Li, Tao; Gruverman, Alexei; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thin Insulating Tunneling Contacts for Efficient and Water-Resistant Perovskite Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tunneling contacts made of any insulating polymers, a champion technology in silicon solar cells, are shown to increase the stabilized efficiency of perovskite solar cells (PSCs) to 20.3%. The tunneling layers spatially separate photo-generated electrons and holes at the perovskite-cathode interface and reduce charge recombination. The tunneling layers made of hydrophobic polymers also significantly enhance the resistance of PSCs to water-caused damage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 558, "Times Cited, All Databases": 578, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2016, "Volume": 28, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6734, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201600969", "DOI Link": "http://dx.doi.org/10.1002/adma.201600969", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382481200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, KK; Fu, MM; Zhao, YT; Gerhard, E; Li, Y; Yang, J; Guo, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Keke; Fu, Meimei; Zhao, Yitao; Gerhard, Ethan; Li, Yue; Yang, Jian; Guo, Jinshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anti-oxidant anti-inflammatory and antibacterial tannin-crosslinked citrate-based mussel-inspired bioadhesives facilitate scarless wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The revolutionary role of tissue adhesives in wound closure, tissue sealing, and bleeding control necessitates the development of multifunctional materials capable of effective and scarless healing. In contrast to the use of traditionally utilized toxic oxidative crosslinking initiators (exemplified by sodium periodate and silver nitrate), herein, the natural polyphenolic compound tannic acid (TA) was used to achieve near instantaneous (<25s), hydrogen bond mediated gelation of citrate-based mussel-inspired bioadhesives combining anti-oxidant, antiinflammatory, and antimicrobial activities (3A-TCMBAs). The resulting materials were self-healing and possessed low swelling ratios (<60%) as well as considerable mechanical strength (up to similar to 1.0 MPa), elasticity (elongation similar to 2700%), and adhesion (up to 40 kPa). The 3A-TCMBAs showed strong in vitro and in vivo anti-oxidant ability, favorable cytocompatibility and cell migration, as well as photothermal antimicrobial activity against both Staphylococcus aureus and Escherichia coli (>90% bacterial death upon near-infrared (NIR) irradiation). In vivo evaluation in both an infected full-thickness skin wound model and a rat skin incision model demonstrated that 3A-TCMBAs + NIR treatment could promote wound closure and collagen deposition and improve the collagen I/ III ratio on wound sites while simultaneously inhibiting the expression of pro-inflammatory cytokines. Further, phased angiogenesis was observed via promotion in the early wound closure phases followed by inhibition and triggering of degradation & remodeling of the extracellular matrix (ECM) in the late stage (supported by phased CD31 (platelet endothelial cell adhesion molecule-1) PDGF (platelet-derived growth factor) and VEGF (vascular endothelial growth factor) expression as well as elevated matrix metalloprotein-9 (MMP-9) expression on day 21), resulting in scarless wound healing. The significant convergence of material and bioactive properties elucidated above warrant further exploration of 3A-TCMBAs as a significant, new class of bioadhesive.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 93, "End Page": 110, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.05.017", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.05.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808190000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Xiao, H; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuanyue; Xiao, Hai; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Schottky-Barrier-Free Contacts with Two-Dimensional Semiconductors by Surface-Engineered MXenes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) metal carbides and nitrides, called MXenes, have attracted great interest for applications such as energy storage. We demonstrate their potential as Schottky-barrier-free metal contacts to 2D semiconductors, providing a solution to the contact resistance problem in 2D electronics. On the basis of first principles calculations, we find that the surface chemistry strongly affects Fermi level of MXenes: 0 termination always increases the work function with respect to that of bare surface, OH always decreases it, whereas F exhibits either trend depending on the specific material. This phenomenon originates from the effect of surface dipoles, which together with the weak Fermi level pinning, enable Schottky-barrier-free hole (or electron) injection into 2D semiconductors through van der Waals junctions with some of the O-terminated (or all the OH-terminated) MXenes. Furthermore, we suggest synthetic routes to control surface terminations based on calculated formation energies. This study enhances understanding of the correlation between surface chemistry and electronic/transport properties of 2D materials, and also gives predictions for improving 2D electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 500, "Times Cited, All Databases": 514, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 138, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15853, "End Page": 15856, "Article Number": null, "DOI": "10.1021/jacs.6b10834", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b10834", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389962800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, P; Roeser, J; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, Prasenjit; Roeser, Jerome; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar Light Driven H2O2 Production and Selective Oxidations Using a Covalent Organic Framework Photocatalyst Prepared by a Multicomponent Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A chemically stable 2D microporous COF (PMCR-1) was synthesized via the multicomponent Povarov reaction. PMCR-1 exhibits a remarkable and long-term stable photocatalytic H2O2 production rate (60 h) from pure and sea water under visible light. The H2O2 production is markedly enhanced when benzyl alcohol (BA) is added as reductant, which is also due to a strong pi-pi interaction of BA with dangling phenyl moieties in the COF pores introduced by the multicomponent Povarov reaction. Motivated by the concomitant BA oxidation to benzaldehyde during H2O2 formation, the photocatalytic oxidation of various organic substrates such as benzyl amine and methyl sulfide derivatives was investigated. It is shown that the well-defined micropores of PMCR-1 enable size-selective photocatalytic oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2023, "Volume": 62, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202304349", "DOI Link": "http://dx.doi.org/10.1002/anie.202304349", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004583500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singh, R; Cao, W; Al-Naib, I; Cong, LQ; Withayachumnullkul, W; Zhang, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singh, Ranjan; Cao, Wei; Al-Naib, Ibraheem; Cong, Longqing; Withayachumnullkul, Withawat; Zhang, Weili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive terahertz sensing with high-Q Fano resonullces in metasurfaces", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High quality factor resonullces are extremely promising for designing ultra-sensitive refractive index label-free sensors, since it allows intense interaction between electromagnetic waves and the analyte material. Metamaterial and plasmonic sensing have recently attracted a lot of attention due to subwavelength confinement of electromagnetic fields in the resonullt structures. However, the excitation of high quality factor resonullces in these systems has been a challenge. We excite an order of magnitude higher quality factor resonullces in planar terahertz metamaterials that we exploit for ultrasensitive sensing. The low-loss quadrupole and Fano resonullces with extremely narrow linewidths enable us to measure the minute spectral shift caused due to the smallest change in the refractive index of the surrounding media. We achieve sensitivity levels of 7.75 x 10(3) nm/refractive index unit (RIU) with quadrupole and 5.7 x 10(4) nm/RIU with the Fano resonullces which could be further enhanced by using thinner substrates. These findings would facilitate the design of ultrasensitive real time chemical and biomolecular sensors in the fingerprint region of the terahertz regime. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2014, "Volume": 105, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 171101, "DOI": "10.1063/1.4895595", "DOI Link": "http://dx.doi.org/10.1063/1.4895595", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344588600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Wei, QY; Lai, JYL; Peng, ZX; Kim, H; Yuan, J; Ye, L; Ade, H; Zou, YP; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kui; Wei, Qingya; Lai, Joshua Yuk Lin; Peng, Zhengxing; Kim, Ha Kyung; Yuan, Jun; Ye, Long; Ade, Harald; Zou, Yingping; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkyl Chain Tuning of Small Molecule Acceptors for Efficient Organic Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of organic solar cells has seen rapid developments after the report of a high-efficiency (15.7%) small molecule acceptor (SMA) named Y6. In this paper, we design and synthesize a family of SMAs with an aromatic backbone identical to that of Y6 but with different alkyl chains to investigate the influence of alkyl chains on the properties and performance of the SMAs. First, we show that it is beneficial to use branched alkyl chains on the nitrogen atoms of the pyrrole motif of the Y6. In addition, the branching position of the alkyl chains also has a major influence on material and device properties. The SMA with 3rd-position branched alkyl chains (named N3) exhibits optimal solubility and electronic and morphological properties, thus yielding the best performance. Further device optimization using a ternary strategy allows us to achieve a high efficiency of 16.74% (and a certified efficiency of 16.42%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 815, "Times Cited, All Databases": 838, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3020, "End Page": 3033, "Article Number": null, "DOI": "10.1016/j.joule.2019.09.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.09.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503428000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, H; Zhou, YT; Yao, RQ; Wan, WB; Ge, X; Zhang, W; Wen, Z; Lang, XY; Zheng, WT; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Hang; Zhou, Yi-Tong; Yao, Rui-Qi; Wan, Wu-Bin; Ge, Xin; Zhang, Wei; Wen, Zi; Lang, Xing-You; Zheng, Wei-Tao; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneously separated intermetallic Co3Mo from nulloporous copper as versatile electrocatalysts for highly efficient water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing robust nonprecious electrocatalysts towards hydrogen/oxygen evolution reactions is crucial for widespread use of electrochemical water splitting in hydrogen production. Here, we report that intermetallic Co3Mo spontaneously separated from hierarchical nulloporous copper skeleton shows genuine potential as highly efficient electrocatalysts for alkaline hydrogen/oxygen evolution reactions in virtue of in-situ hydroxylation and electro-oxidation, respectively. The hydroxylated intermetallic Co3Mo has an optimal hydrogen-binding energy to facilitate adsorption/desorption of hydrogen intermediates for hydrogen molecules. Associated with high electron/ion transport of bicontinuous nulloporous skeleton, nulloporous copper supported Co3Mo electrodes exhibit impressive hydrogen evolution reaction catalysis, with negligible onset overpotential and low Tafel slope (similar to 40mV dec(-1)) in 1M KOH, realizing current density of -400mAcm(-2) at overpotential of as low as 96mV. When coupled to its electro-oxidized derivative that mediates efficiently oxygen evolution reaction, their alkaline electrolyzer operates with a superior overall water-splitting output, outperforming the one assembled with noble-metal-based catalysts. Electrochemical water splitting is an attractive energy conversion technology, but it usually suffers from low efficiency. Here, the authors report intermetallic Co3Mo integrated on porous Cu as highly efficient electrocatalysts for alkaline HER/OER due to in-situ hydroxylation and electro-oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2940, "DOI": "10.1038/s41467-020-16769-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16769-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543972200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zu, LH; Zhang, W; Qu, LB; Liu, LL; Li, W; Yu, AB; Zhao, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zu, Lianhai; Zhang, Wei; Qu, Longbing; Liu, Liangliang; Li, Wei; Yu, Aibing; Zhao, Dongyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous Materials for Electrochemical Energy Storage and Conversion", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance electrode materials is an urgent requirement for next-generation energy conversion and storage systems. Due to the exceptional features, mesoporous materials have shown great potential to achieve high-performance electrodes with high energy/power density, long lifetime, increased interfacial reaction activity, and enhanced kinetics. In this Essay, applications of mesoporous materials are reviewed in electrochemical energy conversion and storage devices. The synthesis, structure, and properties of mesoporous materials and their performance in rechargeable batteries, supercapacitors, fuel cells, and electrolyzers are discussed, providing practical details and enlightening comments on the construction of high-performance mesoporous electrodes. Lastly, the research challenges and perspectives on mesoporous materials for the future development of energy conversion and storage devices are assessed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2020, "Volume": 10, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002152, "DOI": "10.1002/aenm.202002152", "DOI Link": "http://dx.doi.org/10.1002/aenm.202002152", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000559387300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JJ; Deng, YH; Wei, HT; Zheng, XP; Yu, ZH; Shao, YC; Shield, JE; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jingjing; Deng, Yehao; Wei, Haotong; Zheng, Xiaopeng; Yu, Zhenhua; Shao, Yuchuan; Shield, Jeffrey E.; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskite (OIHP) solar cells have achieved comparable efficiencies to those of commercial solar cells, although their instability hinders their commercialization. Although encapsulation techniques have been developed to protect OIHP solar cells from external stimuli such as moisture, oxygen, and ultraviolet light, understanding of the origin of the intrinsic instability of perovskite films is needed to improve their stability. We show that the OIHP films fabricated by existing methods are strained and that strain is caused by mismatched thermal expansion of perovskite films and substrates during the thermal annealing process. The polycrystalline films have compressive strain in the out-of-plane direction and in-plane tensile strain. The strain accelerates degradation of perovskite films under illumination, which can be explained by increased ion migration in strained OIHP films. This study points out an avenue to enhance the intrinsic stability of perovskite films and solar cells by reducing residual strain in perovskite films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 744, "Times Cited, All Databases": 789, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao5616", "DOI": "10.1126/sciadv.aao5616", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao5616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418002000060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, DY; Cen, KH; Zhuang, XZ; Gan, ZY; Zhou, JB; Zhang, YM; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Dengyu; Cen, Kehui; Zhuang, Xiaozhuang; Gan, Ziyu; Zhou, Jianbin; Zhang, Yimeng; Zhang, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insight into biomass pyrolysis mechanism based on cellulose, hemicellulose, and lignin: Evolution of volatiles and kinetics, elucidation of reaction pathways, and characterization of gas, biochar and bio-oil", "Source Title": "COMBUSTION AND FLAME", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pyrolysis is the first step of gasification and combustion. The pyrolysis process of biomass is complicated, which is generally considered to consist of the pyrolysis of the three major components (i.e., cellulose, hemicellulose, and lignin). Understanding the pyrolysis behavior and product of each component holds a key to understanding the biomass pyrolysis mechanism. In this work, the pyrolysis behavior, pyrolysis kinetics, volatile evolution, and product characterization of the three major components are investigated. Results showed that pyrolysis characteristics and thermal stability of the three components were closely related to their unique chemical structures. During pyrolysis, the main pyrolytic volatiles of hemicellulose appeared first, followed by cellulose and then lignin volatiles in the 3D FTIR spectra. In term of pyrolysis products, gases were generated by the cracking of specific functional groups. Hemicellulose had the highest CO 2 yield, whereas lignin had the highest CH 4 yield due to the aromatic rings and methoxy groups in lignin structure. Whereas cellulose demonstrated the highest CO yield at high temperatures (above 550 degrees C). With increasing temperature, the carbon structures of carboxylic-C and O-alkyl-C in biochar decreased, while aryl-C was enhanced. This was due to the deoxygenation reactions such as dehydroxylation, decarboxylation, decarbonylation, and demethoxylation, resulting in a reduction in the number of oxygen-containing functional groups (such as -OH, -C = O, -COOH, and -OCH 3 ), as well as the polycondensation reactions that formed more polycyclic aromatic hydrocarbon units during pyrolysis. The major components of cellulose bio-oil included anhydrosugars and furans. Whereas the bio-oils derived from hemicellulose and lignin showed the highest relative content of acids and phenols, respectively. Based on this analysis, the thermal decomposition pathways of cellulose, hemicellulose, and lignin were proposed. (c) 2022 The Author(s). Published by Elsevier Inc. on behalf of The Combustion Institute. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ )", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 242, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112142, "DOI": "10.1016/j.combustflame.2022.112142", "DOI Link": "http://dx.doi.org/10.1016/j.combustflame.2022.112142", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799959600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, Y; Koshelev, K; Zhang, FC; Lin, H; Lin, SR; Wu, JY; Jia, BH; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Yao; Koshelev, Kirill; Zhang, Fengchun; Lin, Han; Lin, Shirong; Wu, Jiayang; Jia, Baohua; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bound States in the Continuum in Anisotropic Plasmonic Metasurfaces", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The concept of optical bound states in the continuum (BICs) currently drives the field of dielectric resonullt nullophotonics, providing an important physical mechanism for engineering high-quality (high-Q) optical resonullces in high-index dielectric nulloparticles and structured dielectric metasurfaces. For structured metallic metasurfaces, realization of BICs remains a challenge associated with strong dissipative losses of plasmonic materials. Here, we suggest and realize experimentally anisotropic plasmonic metasurfaces supporting high-Q resonullces governed by quasi-BIC collective resonullt modes. Our metasurfaces are composed of arrays of vertically oriented double-pillar meta-molecules covered by a thin layer of gold. We engineer quasi-BIC modes and observe experimentally sharp resonullces in mid-IR reflectance spectra. Our work suggests a direct route to boost the resonullt field enhancement in plasmonic metasurfaces via combining a small effective mode volume of plasmonic systems with engineered high-Q resonullces provided by the BIC physics, with multiple applications to enhance light-matter interaction for nullo-optics and quantum photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2020, "Volume": 20, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6351, "End Page": 6356, "Article Number": null, "DOI": "10.1021/acs.nullolett.0c01752", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.0c01752", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571442000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, X; Wang, ZL; Xiao, S; An, YM; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Xia; Wang, Zilong; Xiao, Shuang; An, Yiming; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition metal based layered double hydroxides tailored for energy conversion and storage", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered double hydroxides (LDHs) are a class of clays with brucite like layers and intercalated anions. The first (3d) series transition metals based LDHs (TM-LDHs) are attracting increasing interest in the field of energy conversion and storage processes due to their unique physicochemical properties. In this article, we review recent developments in the synthesis and applications of TM-LDH in these areas including water splitting, CO2 conversion, metal-air batteries and supercapacitors and the underlying mechanisms of these processes. In addition, current challenges and possible strategies are discussed from the viewpoint of material design and performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 505, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 19, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 213, "End Page": 226, "Article Number": null, "DOI": "10.1016/j.mattod.2015.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375188500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, J; Kim, J; Kim, SY; Cheong, WH; Jang, J; Park, YG; Na, K; Kim, YT; Heo, JH; Lee, CY; Lee, JH; Bien, F; Park, JU", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jihun; Kim, Joohee; Kim, So-Yun; Cheong, Woon Hyung; Jang, Jiuk; Park, Young-Geun; Na, Kyungmin; Kim, Yun-Tae; Heo, Jun Hyuk; Lee, Chang Young; Lee, Jung Heon; Bien, Franklin; Park, Jang-Ung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft, smart contact lenses with integrations of wireless circuits, glucose sensors, and displays", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in wearable electronics combined with wireless communications are essential to the realization of medical applications through health monitoring technologies. For example, a smart contact lens, which is capable of monitoring the physiological information of the eye and tear fluid, could provide real-time, noninvasive medical diagnostics. However, previous reports concerning the smart contact lens have indicated that opaque and brittle components have been used to enable the operation of the electronic device, and this could block the user's vision and potentially damage the eye. In addition, the use of expensive and bulky equipment to measure signals from the contact lens sensors could interfere with the user's external activities. Thus, we report an unconventional approach for the fabrication of a soft, smart contact lens in which glucose sensors, wireless power transfer circuits, and display pixels to visualize sensing signals in real time are fully integrated using transparent and stretchable nullostructures. The integration of this display into the smart lens eliminates the need for additional, bulky measurement equipment. This soft, smart contact lens can be transparent, providing a clear view by matching the refractive indices of its locally patterned areas. The resulting soft, smart contact lens provides real-time, wireless operation, and there are in vivo tests to monitor the glucose concentration in tears (suitable for determining the fasting glucose level in the tears of diabetic patients) and, simultaneously, to provide sensing results through the contact lens display.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 540, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaap9841", "DOI": "10.1126/sciadv.aap9841", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aap9841", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426694200067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, J; Yang, X; Dai, JY; Cheng, Q; Li, X; Qi, NH; Ke, JC; Bai, GD; Liu, S; Jin, S; Alù, A; Cui, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jie; Yang, Xi; Dai, Jun Yan; Cheng, Qiang; Li, Xiang; Qi, Ning Hua; Ke, Jun Chen; Bai, Guo Dong; Liu, Shuo; Jin, Shi; Alu, Andrea; Cui, Tie Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programmable time-domain digital-coding metasurface for non-linear harmonic manipulation and new wireless communication systems", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical non-linear phenomena are typically observed in natural materials interacting with light at high intensities, and they benefit a diverse range of applications from communication to sensing. However, controlling harmonic conversion with high efficiency and flexibility remains a major issue in modern optical and radio-frequency systems. Here, we introduce a dynamic time-domain digital-coding metasurface that enables efficient manipulation of spectral harmonic distribution. By dynamically modulating the local phase of the surface reflectivity, we achieve accurate control of different harmonics in a highly programmable and dynamic fashion, enabling unusual responses, such as velocity illusion. As a relevant application, we propose and realize a novel architecture for wireless communication systems based on the time-domain digital-coding metasurface, which largely simplifies the architecture of modern communication systems, at the same time yielding excellent performance for real-time signal transmission. The presented work, from new concept to new system, opens new pathways in the application of metamaterials to practical technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 231, "End Page": 238, "Article Number": null, "DOI": "10.1093/nsr/nwy135", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwy135", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467957400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JF; Nghiem, LD; Li, XM; He, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Jian Feng; Nghiem, Long D.; Li, Xue-Mei; He, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium extraction from Chinese salt-lake brines: opportunities, challenges, and future outlook", "Source Title": "ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chinese salt-lake brine is mainly of the magnesium sulfate subtype with a high Mg/Li ratio. Mining lithium from Chinese salt-lake brine has been a decades-long technical challenge. The pros and cons of various technologies are briefly discussed. Chemical extraction has been the most important technology for the recovery of lithium from Chinese salt-lake brine with a high Mg/Li ratio. Several other innovative technologies, including lithium ion sieves, membrane separation, and electro-electrodialysis, have also emerged as potential options.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 593, "End Page": 597, "Article Number": null, "DOI": "10.1039/c7ew00020k", "DOI Link": "http://dx.doi.org/10.1039/c7ew00020k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404718800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alapan, Y; Karacakol, AC; Guzelhan, SN; Isik, I; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alapan, Yunus; Karacakol, Alp C.; Guzelhan, Seyda N.; Isik, Irem; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reprogrammable shape morphing of magnetic soft machines", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape-morphing magnetic soft machines are highly desirable for diverse applications in minimally invasive medicine, wearable devices, and soft robotics. Despite recent progress, current magnetic programming approaches are inherently coupled to sequential fabrication processes, preventing reprogrammability and high-throughput programming. Here, we report a high-throughput magnetic programming strategy based on heating magnetic soft materials above the Curie temperature of the embedded ferromagnetic particles and reorienting their magnetic domains by applying magnetic fields during cooling. We demonstrate discrete, three-dimensional, and reprogrammable magnetization with high spatial resolution (similar to 38 mu m). Using the reprogrammable magnetization capability, reconfigurable mechanical behavior of an auxetic metamaterial structure, tunable locomotion of a surface-walking soft robot, and adaptive grasping of a soft gripper are shown. Our approach further enables high-throughput magnetic programming (up to 10 samples/min) via contact transfer. Heat-assisted magnetic programming strategy described here establishes a rich design space and mass-manufacturing capability for development of multiscale and reprogrammable soft machines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabc6414", "DOI": "10.1126/sciadv.abc6414", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abc6414", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000574597200035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, W; Carraro, F; Solomon, MB; Bell, SG; Amenitsch, H; Sumby, CJ; White, NG; Falcaro, P; Doonull, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Weibin; Carraro, Francesco; Solomon, Marcello B.; Bell, Stephen G.; Amenitsch, Heinz; Sumby, Christopher J.; White, Nicholas G.; Falcaro, Paolo; Doonull, Christian J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enzyme Encapsulation in a Porous Hydrogen-Bonded Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Protection of biological assemblies is critical to applications in biotechnology, increasing the durability of enzymes in biocatalysis or potentially stabilizing biotherapeutics during transport and use. Here we show that a porous hydrogen-bonded organic framework (HOF) constructed from water-soluble tetra-amidinium (1-Cl-4) and tetracarboxylate (2) building blocks can encapsulate and stabilize biomolecules to elevated temperature, proteolytic and denaturing agents, and extend the operable pH range for catalase activity. The HOF, which readily retains water within its framework structure, can also protect and retain the activity of enzymes such as alcohol oxidase, that are inactive when encapsulated within zeolitic imidazolate framework (ZIF) materials. Such HOF coatings could provide valid alternative materials to ZIFs: they are metal free, possess larger pore apertures, and are stable over a wider, more biologically relevant pH range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2019, "Volume": 141, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14298, "End Page": 14305, "Article Number": null, "DOI": "10.1021/jacs.9b06589", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b06589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486361800041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Doganov, RA; O'Farrell, ECT; Koenig, SP; Yeo, YT; Ziletti, A; Carvalho, A; Campbell, DK; Coker, DF; Watanabe, K; Taniguchi, T; Neto, AHC; Özyilmaz, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Doganov, Rostislav A.; O'Farrell, Eoin C. T.; Koenig, Steven P.; Yeo, Yuting; Ziletti, Angelo; Carvalho, Alexandra; Campbell, David K.; Coker, David F.; Watanabe, Kenji; Taniguchi, Takashi; Castro Neto, Antonio H.; Ozyilmaz, Barbaros", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transport properties of pristine few-layer black phosphorus by van der Waals passivation in an inert atmosphere", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin black phosphorus is a two-dimensional semiconductor with a sizeable band gap. Its excellent electronic properties make it attractive for applications in transistor, logic and optoelectronic devices. However, it is also the first widely investigated two-dimensional material to undergo degradation upon exposure to ambient air. Therefore a passivation method is required to study the intrinsic material properties, understand how oxidation affects the physical properties and enable applications of phosphorene. Here we demonstrate that atomically thin graphene and hexagonal boron nitride can be used for passivation of ultrathin black phosphorus. We report that few-layer pristine black phosphorus channels passivated in an inert gas environment, without any prior exposure to air, exhibit greatly improved n-type charge transport resulting in symmetric electron and hole transconductance characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 512, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6647, "DOI": "10.1038/ncomms7647", "DOI Link": "http://dx.doi.org/10.1038/ncomms7647", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353696900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nisar, U; Muralidharan, N; Essehli, R; Amin, R; Belharouak, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nisar, Umair; Muralidharan, Nitin; Essehli, Rachid; Amin, Ruhul; Belharouak, Ilias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valuation of Surface Coatings in High-Energy Density Lithium-ion Battery Cathode Materials", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial barriers, usually with either electrochemically active or inactive coating materials, are deployed on cathode material surfaces to mitigate detrimental side reactions by suppressing direct contact of cathode and electrolyte called surface coatings. These surface coatings are commonly known to increase the wettability of liquid electrolyte and reduce the interfacial charge transfer resistance. An important caveat is the selection of appropriate coating material with appropriate thickness for achieving enhanced electrochemical performance. As modern battery materials are increasingly developed with some type of surface coating, a careful and thorough examination of their role in mitigating the cycle life issues of cathode materials is paramount. This comprehensive review article extensively covers the selection criteria of coating materials based on their chemical and physical properties and electrochemical functionalities. Additionally, the article discusses the concept of critical coating thickness and methods of achieving homogeneous coating architectures that deliver desired performance benefits. Furthermore, this comprehensive article summarizes the recent advancements, effectiveness, necessity of cathode surface coatings and identifies the key aspect of structure-property correlation between coating type/thickness and lithium-ion diffusion through coating layers as the linchpin that validates surface coating approaches especially for high capacity nickel-rich cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 38, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 309, "End Page": 328, "Article Number": null, "DOI": "10.1016/j.ensm.2021.03.015", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2021.03.015", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672723100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YC; Shen, J; Yang, CW; Wan, Y; Tang, HL; Aljarb, AA; Chen, CL; Fu, JH; Wei, X; Huang, KW; Han, Y; Jonas, SJ; Dong, XC; Tung, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yichen; Shen, Jie; Yang, Chi-Wen; Wan, Yi; Tang, Hao-Ling; Aljarb, Areej A.; Chen, Cailing; Fu, Jui-Han; Wei, Xuan; Huang, Kuo-Wei; Han, Yu; Jonas, Steven J.; Dong, Xiaochen; Tung, Vincent", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed-dimensional MXene-hydrogel heterostructures for electronic skin sensors with ultrabroad working range", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin-mountable microelectronics are garnering substantial interest for various promising applications including human-machine interfaces, biointegrated devices, and personalized medicine. However, it remains a critical challenge to develop e-skins to mimic the human somatosensory system in full working range. Here, we present a multifunctional e-skin system with a heterostructured configuration that couples vinyl-hybrid-silica nulloparticle (VSNP)-modified polyacrylamide (PAM) hydrogel with two-dimensional (2D) MXene through nullo-bridging layers of polypyrrole nullowires (PpyNWs) at the interfaces, featuring high toughness and low hysteresis, in tandem with controlled crack generation and distribution. The multidimensional configurations endow the e-skin with an extraordinary working range (2800%), ultrafast responsiveness (90 ms) and resilience (240 ms), good linearity (800%), tunable sensing mechanisms, and excellent reproducibility. In parallel, this e-skin platform is capable of detecting, quantifying, and remotely monitoring stretching motions in multiple dimensions, tactile pressure, proximity sensing, and variations in temperature and light, establishing a promising platform for next-generation smart flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 6, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb5367", "DOI": "10.1126/sciadv.abb5367", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb5367", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595928400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, S; Li, K; Hui, KS; Zhang, JT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Song; Li, Kang; Hui, Kwan San; Zhang, Jintao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulation of Lamellar Structure of Vanadium Oxide via Polyaniline Intercalation for High-Performance Aqueous Zinc-Ion Battery", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "According to the intercalation mechanism, an ordered modulation of channel structures of metal oxides is crucial to reversibly accumulate large zinc ions with high surface charge density for improving zinc-ion battery performance. However, the irreversible structure-transition commonly results in serious performance decay. Herein, polyanilines are in situ intercalated into the layered vanadium oxide in order to enlarge the lamellar spacing for enhancing the battery performance. With enlarged lattice spacing, the polyaniline intercalated vanadium oxide (PIVO) coupled with a Zn electrode exhibit a large specific capacity of 372 mAh g(-1)and good cycling stability. More importantly, in situ characterization results reveal that PIVO allows the accumulation of additional zinc ions without obvious phase transformation and the conjugated polymeric chains enable the structure flexibility in the confined layer space to relieve the intercalation stress for improving cycling stability. Additionally, findings from the in situ infrared spectroscopy measurements elucidate the charge storage mechanism of the battery. Reversible doping processes of polyaniline molecules in vanadium oxide allow the involvement of multiple ions in the charge storage process, improving battery performance. Uncovering the origin of improved charge storage mechanisms is of importance in rationally designing advanced materials with unique organic-inorganic features for high-performance zinc-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 30, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003890, "DOI": "10.1002/adfm.202003890", "DOI Link": "http://dx.doi.org/10.1002/adfm.202003890", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566383500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ming, FW; Zhu, YP; Huang, G; Emwas, AH; Liang, HF; Cui, Y; Alshareef, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ming, Fangwang; Zhu, Yunpei; Huang, Gang; Emwas, Abdul-Hamid; Liang, Hanfeng; Cui, Yi; Alshareef, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co-Solvent Electrolyte Engineering for Stable Anode-Free Zinc Metal Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anode-free metal batteries can in principle offer higher energy density, but this requires them to have extraordinary Coulombic efficiency (>99.7%). Although Zn-based metal batteries are promising for stationary storage, the parasitic side reactions make anode-free batteries difficult to achieve in practice. In this work, a salting-in-effect-induced hybrid electrolyte is proposed as an effective strategy that enables both a highly reversible Zn anode and good stability and compatibility toward various cathodes. The as-prepared electrolyte can also work well under a wide temperature range (i.e., from -20 to 50 degrees C). It is demonstrated that in the presence of propylene carbonate, triflate anions are involved in the Zn2+ solvation sheath structure, even at a low salt concentration (2.14 M). The unique solvation structure results in the reduction of anions, thus forming a hydrophobic solid electrolyte interphase. The waterproof interphase along with the decreased water activity in the hybrid electrolyte effectively prevents side reactions, thus ensuring a stable Zn anode with an unprecedented Coulombic efficiency (99.93% over 500 cycles at 1 mA cm(-2)). More importantly, we design an anode-free Zn metal battery that exhibits excellent cycling stability (80% capacity retention after 275 cycles at 0.5 mA cm(-2)). This work provides a universal strategy to design co-solvent electrolytes for anode-free Zn metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 437, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 144, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7160, "End Page": 7170, "Article Number": null, "DOI": "10.1021/jacs.1c12764", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c12764", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799141600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dhers, S; Vantomme, G; Avérous, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dhers, Sebastien; Vantomme, Ghislaine; Averous, Luc", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fully bio-based polyimine vitrimer derived from fructose", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A bio-based polyimine vitrimer containing 100% renewable carbon content has been synthesised and characterised. This vitrimer material was prepared by combining a bio-based furan dialdehyde obtained from fructose with a bio-based diamine and triamine prepared from fatty acids. Due to the dynamic nature of the imine reversible bonds, the vitrimer properties can be clearly demonstrated. The obtained films exhibit fast stress relaxation around room temperature. To the best of our knowledge, this is the first report of a fully bio-based polyimine vitrimer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2019, "Volume": 21, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1596, "End Page": 1601, "Article Number": null, "DOI": "10.1039/c9gc00540d", "DOI Link": "http://dx.doi.org/10.1039/c9gc00540d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464318800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sadhanala, A; Ahmad, S; Zhao, BD; Giesbrecht, N; Pearce, PM; Deschler, F; Hoye, RLZ; Gödel, KC; Bein, T; Docampo, P; Dutton, SE; De Volder, MFL; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sadhanala, Aditya; Ahmad, Shahab; Zhao, Baodan; Giesbrecht, Nadja; Pearce, Phoebe M.; Deschler, Felix; Hoye, Robert L. Z.; Goedel, Karl C.; Bein, Thomas; Docampo, Pablo; Dutton, Sian E.; De Volder, Michael F. L.; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blue-Green Color Tunable Solution Processable Organolead Chloride-Bromide Mixed Halide Perovskites for Optoelectronic Applications", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed organo-lead halide perovskites are produced with sharp, color-pure electroluminescence that can be tuned from blue to green region of visible spectrum (425-570 nm). This was accomplished by controlling the halide composition of CH3NH3Pb(BrxCl1-x)(3) [0 <= x <= 1] perovskites. The bandgap and lattice parameters change monotonically with composition. The films possess remarkably sharp band edges and a clean bandgap, with a single optically active phase. These chloride-bromide perovskites can potentially be used in optoelectronic devices like solar cells and light emitting diodes (LEDs). Here we demonstrate high color-purity, tunable LEDs with narrow emission full width at half maxima (FWHM) and low turn on voltages using thin-films of these perovskite materials, including a blue CH3NH3PbCl3 perovskite LED with a narrow emission FWHM of 5 nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 15, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6095, "End Page": 6101, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b02369", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b02369", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361252700067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, F; Li, J; Long, Y; Zhang, ZY; Wang, LF; Sui, JJ; Dong, YT; Wang, YZ; Taylor, R; Ni, DL; Cai, WB; Wang, P; Hacker, T; Wang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Fan; Li, Jun; Long, Yin; Zhang, Ziyi; Wang, Linfeng; Sui, Jiajie; Dong, Yutao; Wang, Yizhan; Taylor, Rachel; Ni, Dalong; Cai, Weibo; Wang, Ping; Hacker, Timothy; Wang, Xudong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wafer-scale heterostructured piezoelectric bio-organic thin films", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric biomaterials are intrinsically suitable for coupling mechanical and electrical energy in biological systems to achieve in vivo real-time sensing, actuation, and electricity generation. However, the inability to synthesize and align the piezoelectric phase at a large scale remains a roadblock toward practical applications. We present a wafer-scale approach to creating piezoelectric biomaterial thin films based on g-glycine crystals. The thin film has a sandwich structure, where a crystalline glycine layer self-assembles and automatically aligns between two polyvinyl alcohol (PVA) thin films. The heterostructured glycine-PVA films exhibit piezoelectric coefficients of 5.3 picocoulombs per newton or 157.5 x 10(-3) volt meters per newton and nearly an order of magnitude enhancement of the mechanical flexibility compared with pure glycine crystals. With its natural compatibility and degradability in physiological environments, glycine-PVA films may enable the development of transient implantable electromechanical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2021, "Volume": 373, "Issue": 6552, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf2155", "DOI Link": "http://dx.doi.org/10.1126/science.abf2155", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000679214500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, W; Li, S; He, HC; Li, XN; Cheng, ZX; Yang, Y; Wang, JL; Shen, Q; Wang, XY; Xiong, YJ; Zhou, Y; Zou, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Wa; Li, Shi; He, Huichao; Li, Xiaoning; Cheng, Zhenxiang; Yang, Yong; Wang, Jinlan; Shen, Qing; Wang, Xiaoyong; Xiong, Yujie; Zhou, Yong; Zou, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vacancy-defect modulated pathway of photoreduction of CO2 on single atomically thin AgInP2S6 sheets into olefiant gas", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis, light-driving CO2 conversion into hydrocarbon fuels, is a promising strategy to synchronously overcome global warming and energy-supply issues. The quaternary AgInP2S6 atomic layer with the thickness of similar to 0.70 nm were successfully synthesized through facile ultrasonic exfoliation of the corresponding bulk crystal. The sulfur defect engineering on this atomic layer through a H2O2 etching treatment can excitingly change the CO2 photoreduction reaction pathway to steer dominullt generation of ethene with the yield-based selectivity reaching similar to 73% and the electron-based selectivity as high as similar to 89%. Both DFT calculation and in-situ FTIR spectra demonstrate that as the introduction of S vacancies in AgInP2S6 causes the charge accumulation on the Ag atoms near the S vacancies, the exposed Ag sites can thus effectively capture the forming *CO molecules. It makes the catalyst surface enrich with key reaction intermediates to lower the C-C binding coupling barrier, which facilitates the production of ethene. CO2 conversion driven by light is a promising strategy to synchronously overcome global warming and energy-supply issues. Here the authors show that the sulfur defect engineering on a quaternary AgInP2S6 atomic layer can excitingly change the CO2 photoreduction reaction pathway to the generation of ethene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4747, "DOI": "10.1038/s41467-021-25068-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25068-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684547900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, K; Wang, XH; Li, S; Urbankowski, P; Li, JM; Xu, YX; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ke; Wang, Xuehang; Li, Shuo; Urbankowski, Patrick; Li, Jianmin; Xu, Yuxi; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Ultrafast Conducting Polymer@MXene Positive Electrode with High Volumetric Capacitance for Advanced Asymmetric Supercapacitors", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pseudocapacitors or redox capacitors that synergize the merits of batteries and double-layer capacitors are among the most promising candidates for high-energy and high-power energy storage applications. 2D transition metal carbides (MXenes), an emerging family of pseudocapacitive materials with ultrahigh rate capability and volumetric capacitance, have attracted much interest in recent years. However, MXenes have only been used as negative electrodes as they are easily oxidized at positive (anodic) potential. To construct a high-performance MXene-based asymmetric device, a positive electrode with a compatible performance is highly desired. Herein, an ultrafast polyaniline@MXene cathode prepared by casting a homogenous polyaniline layer onto a 3D porous Ti3C2Tx MXene is reported, which enables the stable operation of MXene at positive potentials because of the enlarged work function after compositing with polyaniline, according to the first-principle calculations. The resulting flexible polyaniline@MXene positive electrode demonstrates a high volumetric capacitance of 1632 F cm(-3) and an ultrahigh rate capability with 827 F cm(-3) at 5000 mV s(-1), surpassing all reported positive electrodes. An asymmetric device is further fabricated with MXene as the anode and polyaniline@MXene as the cathode, which delivers a high energy density of 50.6 Wh L-1 and an ultrahigh power density of 127 kW L-1.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 16, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906851, "DOI": "10.1002/smll.201906851", "DOI Link": "http://dx.doi.org/10.1002/smll.201906851", "Book DOI": null, "Early Access Date": "DEC 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503853600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, RK; Kim, Y; Chester, SA; Sharma, P; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ruike; Kim, Yoonho; Chester, Shawn A.; Sharma, Pradeep; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanics of hard-magnetic soft materials", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft materials that can undergo rapid and large deformation through the remote and wireless action of external stimuli offer a range of tantalizing applications such as soft robots, flexible electronics, and biomedical devices. A natural and simple embodiment of such materials is to embed magnetic particles in soft polymers. Unfortunately, existing magnetically responsive soft materials such as magnetorheological elastomers and ferrogels typically use magnetically-soft particles such as iron and iron oxides, which are characterized by the low coercivity and hence lack the capability to retain remnullt magnetism. Accordingly, their deformation is limited to simple elongation or shortening, rendering these materials substantially unsuited for the complex transformations required in many applications. To introduce shape-programmability, magnetically-hard particles with high coercivity have been incorporated in mechanically soft materials. In addition, recent works aimed at ameliorating this situation have developed fabrication techniques and facile routes to engineer rapid and complex transformations in a programmable manner by introducing intricate patterns of magnetic polarities in soft materials. The resulting structures, when properly designed, have been shown to exhibit a diverse and rich array of actuation behavior. In this work, we develop a suitable theoretical framework to analyze these socalled hard-magnetic soft materials to facilitate the rational design of magnetically activated functional structures and devices based on a quantitative prediction of complex shape changes. We adopt a nonlinear field theory to describe the finite deformation coupled with magnetic fields and argue that the macroscopic behavior of the fabricated materials requires a new constitutive classification ideal hard-magnetic soft material which assumes that (i) the material has a residual magnetic flux density, and (ii) the induced magnetic flux density exhibits a linear relation with the applied actuating magnetic field. We implement the theory and constitutive law in a finite-element framework and find remarkable agreement between the simulation and experimental results on various deformation modes of hard-magnetic soft materials. Using the developed (and validated) model, we present a set of illustrative examples to highlight the use of our model-based simulation to guide the design of experimentally realizable complex shape-morphing structures based on hard-magnetic soft materials. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 244, "End Page": 263, "Article Number": null, "DOI": "10.1016/j.jmps.2018.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2018.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459368300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, Y; Wang, WW; Li, YJ; Wu, QH; Tang, S; Yan, JW; Zheng, MS; Wu, DY; Fan, CH; Hu, WQ; Chen, ZB; Fang, Y; Zhang, QH; Dong, QF; Mao, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Yu; Wang, Wei-Wei; Li, Yi-Juan; Wu, Qi-Hui; Tang, Shuai; Yan, Jia-Wei; Zheng, Ming-Sen; Wu, De-Yin; Fan, Chun-Hai; Hu, Wei-Qiang; Chen, Zhao-Bin; Fang, Yuan; Zhang, Qing-Hong; Dong, Quan-Feng; Mao, Bing-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dendrite growth of alkali metal anodes limited their lifetime for charge/discharge cycling. Here, we report near-perfect anodes of lithium, sodium, and potassium metals achieved by electrochemical polishing, which removes microscopic defects and creates ultra-smooth ultra-thin solid-electrolyte interphase layers at metal surfaces for providing a homogeneous environment. Precise characterizations by AFM force probing with corroborative in-depth XPS profile analysis reveal that the ultra-smooth ultra-thin solid-electrolyte interphase can be designed to have alternating inorganic-rich and organic-rich/mixed multi-layered structure, which offers mechanical property of coupled rigidity and elasticity. The polished metal anodes exhibit significantly enhanced cycling stability, specifically the lithium anodes can cycle for over 200 times at a real current density of 2mA cm(-2) with 100% depth of discharge. Our work illustrates that an ultra-smooth ultra-thin solid-electrolyte interphase may be robust enough to suppress dendrite growth and thus serve as an initial layer for further improved protection of alkali metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1339, "DOI": "10.1038/s41467-018-03466-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03466-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429498100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YR; Huang, Q; He, CT; Chen, YF; Liu, J; Shen, FC; Lan, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yi-Rong; Huang, Qing; He, Chun-Ting; Chen, Yifa; Liu, Jiang; Shen, Feng-Cui; Lan, Ya-Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oriented electron transmission in polyoxometalate-metalloporphyrin organic framework for highly selective electroreduction of CO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of highly stable, selective and efficient electrocatalysts for CO2 reduction reaction is desirable while largely unmet. In this work, a series of precisely designed polyoxometalate-metalloporphyrin organic frameworks are developed. Noted that the integration of {epsilon-pmo(8)(V)Mo(4)(VI)O(40)Zn(4)} cluster and metalloporphyrin endows these polyoxometalate-metalloporphyrin organic frameworks greatly advantages in terms of electron collecting and donating, electron migration and electrocatalytic active component in the CO2 reduction reaction. Thus-obtained catalysts finally present excellent performances and the mechanisms of catalysis processes are discussed and revealed by density functional theory calculations. Most importantly, Co-PMOF exhibits remarkable faradaic efficiency ( > 94%) over a wide potential range (-0.8 to -1.0 V). Its best faradaic efficiency can reach up to 99% (highest in reported metal-organic frameworks) and it exhibits a high turnover frequency of 1656 h(-1) and excellent catalysis stability (> 36 h).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4466, "DOI": "10.1038/s41467-018-06938-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06938-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448414100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ke, WJ; Fang, GJ; Wan, JW; Tao, H; Liu, Q; Xiong, LB; Qin, PL; Wang, J; Lei, HW; Yang, G; Qin, MC; Zhao, XZ; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ke, Weijun; Fang, Guojia; Wan, Jiawei; Tao, Hong; Liu, Qin; Xiong, Liangbin; Qin, Pingli; Wang, Jing; Lei, Hongwei; Yang, Guang; Qin, Minchao; Zhao, Xingzhong; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hole-blocking layer-free planar halide perovskite thin-film solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient lead halide perovskite solar cells use hole-blocking layers to help collection of photogenerated electrons and to achieve high open-circuit voltages. Here, we report the realization of efficient perovskite solar cells grown directly on fluorine-doped tin oxide-coated substrates without using any hole-blocking layers. With ultraviolet-ozone treatment of the substrates, a planar Au/hole-transporting material/CH3NH3PbI3-xClx/substrate cell processed by a solution method has achieved a power conversion efficiency of over 14% and an open-circuit voltage of 1.06V measured under reverse voltage scan. The open-circuit voltage is as high as that of our best reference cell with a TiO2 hole-blocking layer. Besides ultraviolet-ozone treatment, we find that involving Cl in the synthesis is another key for realizing high open-circuit voltage perovskite solar cells without hole-blocking layers. Our results suggest that TiO2 may not be the ultimate interfacial material for achieving high-performance perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6700, "DOI": "10.1038/ncomms7700", "DOI Link": "http://dx.doi.org/10.1038/ncomms7700", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353044000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bharti, B; Kumar, S; Lee, HN; Kumar, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bharti, Bandna; Kumar, Santosh; Lee, Heung-No; Kumar, Rajesh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of oxygen vacancies and Ti3+ state in TiO2 thin film and enhanced optical properties by air plasma treatment", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This is the first time we report that simply air plasma treatment can also enhances the optical absorbance and absorption region of titanium oxide (TiO2) films, while keeping them transparent. TiO2 thin films having moderate doping of Fe and Co exhibit significant enhancement in the aforementioned optical properties upon air plasma treatment. The moderate doping could facilitate the formation of charge trap centers or avoid the formation of charge recombination centers. Variation in surface species viz. Ti3+, Ti4+, O2-, oxygen vacancies, OH group and optical properties was studied using X-ray photon spectroscopy (XPS) and UV-Vis spectroscopy. The air plasma treatment caused enhanced optical absorbance and optical absorption region as revealed by the formation of Ti3+ and oxygen vacancies in the band gap of TiO2 films. The samples were treated in plasma with varying treatment time from 0 to 60 seconds. With the increasing treatment time, Ti3+ and oxygen vacancies increased in the Fe and Co doped TiO2 films leading to increased absorbance; however, the increase in optical absorption region/red shift (from 3.22 to 3.00 eV) was observed in Fe doped TiO2 films, on the contrary Co doped TiO2 films exhibited blue shift (from 3.36 to 3.62 eV) due to Burstein Moss shift.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1122, "Times Cited, All Databases": 1152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 32355, "DOI": "10.1038/srep32355", "DOI Link": "http://dx.doi.org/10.1038/srep32355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382157500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, YJ; Wang, PF; Niu, YB; Zhang, XD; Li, QH; Yu, XQ; Fan, M; Chen, WP; Yu, Y; Liu, XF; Meng, QH; Xin, S; Yin, YX; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Yu-Jie; Wang, Peng-Fei; Niu, Yu-Bin; Zhang, Xu-Dong; Li, Qinghao; Yu, Xiqian; Fan, Min; Chen, Wan-Ping; Yu, Yang; Liu, Xiangfeng; Meng, Qinghai; Xin, Sen; Yin, Ya-Xia; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron-doped sodium layered oxide for reversible oxygen redox reaction in Na-ion battery cathodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The irreversible oxygen redox reaction during charging to the high-voltage region causes cathode structural degradation and Na-ion cell capacity fading. Here, the authors report a B-doped cathode active material to mitigate the irreversible oxygen oxidation and increase the cell capacity. Na-ion cathode materials operating at high voltage with a stable cycling behavior are needed to develop future high-energy Na-ion cells. However, the irreversible oxygen redox reaction at the high-voltage region in sodium layered cathode materials generates structural instability and poor capacity retention upon cycling. Here, we report a doping strategy by incorporating light-weight boron into the cathode active material lattice to decrease the irreversible oxygen oxidation at high voltages (i.e., >4.0 V vs. Na+/Na). The presence of covalent B-O bonds and the negative charges of the oxygen atoms ensures a robust ligand framework for the NaLi1/9Ni2/9Fe2/9Mn4/9O2 cathode material while mitigating the excessive oxidation of oxygen for charge compensation and avoiding irreversible structural changes during cell operation. The B-doped cathode material promotes reversible transition metal redox reaction enabling a room-temperature capacity of 160.5 mAh g(-1) at 25 mA g(-1) and capacity retention of 82.8% after 200 cycles at 250 mA g(-1). A 71.28 mAh single-coated lab-scale Na-ion pouch cell comprising a pre-sodiated hard carbon-based anode and B-doped cathode material is also reported as proof of concept.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5267, "DOI": "10.1038/s41467-021-25610-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25610-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694666900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, J; Zhu, HY; Wang, Y; Feng, W; Hu, YX; Dasgupta, A; Han, YM; Wang, Y; Muller, DA; Martin, LW; Hu, PA; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Jun; Zhu, Hanyu; Wang, Ying; Feng, Wei; Hu, Yunxia; Dasgupta, Arvind; Han, Yimo; Wang, Yuan; Muller, David A.; Martin, Lane W.; Hu, PingAn; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Two-Dimensional Ferroelectricity with Dipole Locking", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Out-of-plane ferroelectricity with a high transition temperature in ultrathin films is important for the exploration of new domain physics and scaling down of memory devices. However, depolarizing electrostatic fields and interfacial chemical bonds can destroy this long-range polar order at twodimensional (2D) limit. Here we report the experimental discovery of the locking between out-of-plane dipoles and in-plane lattice asymmetry in atomically thin In2Se3 crystals, a new stabilization mechanism leading to our observation of intrinsic 2D out-of-plane ferroelectricity. Through second harmonic generation spectroscopy and piezoresponse force microscopy, we found switching of out-of-plane electric polarization requires a flip of nonlinear optical polarization that corresponds to the inversion of in-plane lattice orientation. The polar order shows a very high transition temperature (similar to 700 K) without the assistance of extrinsic screening. This finding of intrinsic 2D ferroelectricity resulting from dipole locking opens up possibilities to explore 2D multiferroic physics and develop ultrahigh density memory devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2018, "Volume": 120, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 227601, "DOI": "10.1103/PhysRevLett.120.227601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.227601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433915100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZK; Bekenstein, Y; Ye, XC; Nguyen, SC; Swabeck, J; Zhang, DD; Lee, ST; Yang, PD; Ma, WL; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zeke; Bekenstein, Yehonadav; Ye, Xingchen; Nguyen, Son C.; Swabeck, Joseph; Zhang, Dandan; Lee, Shuit-Tong; Yang, Peidong; Ma, Wanli; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand Mediated Transformation of Cesium Lead Bromide Perovskite nullocrystals to Lead Depleted Cs4PbBr6 nullocrystals", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite nullocrystals (NCs) have emerged as attractive nullomaterials owing to their excellent optical and optoelectronic properties. Their intrinsic instability and soft nature enable a post-synthetic controlled chemical transformation. We studied a ligand mediated transformation of presynthesized CsPbBr3 NCs to a new type of lead halide depleted perovskite derivative nullocrystal, namely Cs4PbBr6. The transformation is initiated by amine addition, and the use of alkyl-thiol ligands greatly improves the size uniformity and chemical stability of the derived NCs. The thermodynamically driven transformation is governed by a two-step dissolution recrystallization mechanism, which is monitored optically. Our results not only shed light on a decomposition pathway of CsPbBr3 NCs but also present a method to synthesize uniform colloidal Cs4PbBr6 NCs, which may actually be a common product of perovskite NCs degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2017, "Volume": 139, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5309, "End Page": 5312, "Article Number": null, "DOI": "10.1021/jacs.7b01409", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b01409", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399966000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JY; Hu, J; Zhang, MK; Gou, WY; Zhang, S; Chen, Z; Qu, YQ; Ma, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiayuan; Hu, Jun; Zhang, Mingkai; Gou, Wangyan; Zhang, Sai; Chen, Zhong; Qu, Yongquan; Ma, Yuanyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fundamental viewpoint on the hydrogen spillover phenomenon of electrocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen spillover phenomenon of metal-supported electrocatalysts can significantly impact their activity in hydrogen evolution reaction (HER). However, design of active electrocatalysts faces grand challenges due to the insufficient understandings on how to overcome this thermodynamically and kinetically adverse process. Here we theoretically profile that the interfacial charge accumulation induces by the large work function difference between metal and support (Phi) and sequentially strong interfacial proton adsorption construct a high energy barrier for hydrogen transfer. Theoretical simulations and control experiments rationalize that small Phi induces interfacial charge dilution and relocation, thereby weakening interfacial proton adsorption and enabling efficient hydrogen spillover for HER. Experimentally, a series of Pt alloys-CoP catalysts with tailorable Phi show a strong Phi -dependent HER activity, in which PtIr/CoP with the smallest Phi =0.02eV delivers the best HER performance. These findings have conclusively identified Phi as the criterion in guiding the design of hydrogen spillover-based binary HER electrocatalysts. Despite the significance of hydrogen spillover on metal-supported electrocatalysts for hydrogen evolution, fundamental understandings on such a process are insufficient. Here the authors show that small work function difference between metal and support facilitates hydrogen spillover and enhances activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3502, "DOI": "10.1038/s41467-021-23750-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23750-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000664874700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YY; Zhang, L; Wang, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yuanyi; Zhang, Ling; Wang, Wenzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct functionalization of methane into ethanol over copper modified polymeric carbon nitride via photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct valorization of methane to its alcohol derivative remains a great challenge. Photocatalysis arises as a promising green strategy which could exploit hydroxyl radical (center dot OH) to accomplish methane activation. However, both the excessive center dot OH from direct H2O oxidation and the neglect of methane activation on the material would cause deep mineralization. Here we introduce Cu species into polymeric carbon nitride (PCN), accomplishing photocatalytic anaerobic methane conversion for the first time with an ethanol productivity of 106 mu mol g(cat)(-1) h(-1). Cu modified PCN could manage generation and in situ decomposition of H2O2 to produce center dot OH, of which Cu species are also active sites for methane adsorption and activation. These features avoid excess center dot OH for overoxidation and facilitate methane conversion. Moreover, a hypothetic mechanism through a methane-methanol-ethanol pathway is proposed, emphasizing the synergy of Cu species and the adjacent C atom in PCN for obtaining C-2 product.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 506, "DOI": "10.1038/s41467-019-08454-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08454-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457290300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martins, MAR; Pinho, SP; Coutinho, JAP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martins, Monia A. R.; Pinho, Simao P.; Coutinho, Joao A. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into the Nature of Eutectic and Deep Eutectic Mixtures", "Source Title": "JOURNAL OF SOLUTION CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A stricter definition of a deep eutectic solvent (DES) is urgent, so that it may become a sound basis for further developments in this field. This communication aims at contributing to deepening the understanding of eutectic and deep eutectic mixtures concerning their definition, thermodynamic nature and modelling. The glut of literature on DES applications should be followed by a similar effort to address the fundamental questions on their nature. This hopefully would contribute to correct some widespread misconceptions, and help to establish a stringent definition of what a DES is. DES are eutectic mixtures for which the eutectic point temperature should be lower to that of an ideal liquid mixture. To identify and characterize them, their phase diagrams should be known, in order to compare the real temperature depression to that predicted if ideality is assumed, and to define composition ranges for which they are in the liquid state at operating temperatures. It is also shown that hydrogen bonding between the DES components should not be used to define or characterize a DES, since this would describe many ideal mixtures. The future of deep eutectic solvents is quite promising, and we expect that this work will contribute to the efficient design and selection of the best DES for a given application, and to model properties and phase equilibria without which the process design is impractical.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 770, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 48, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 962, "End Page": 982, "Article Number": null, "DOI": "10.1007/s10953-018-0793-1", "DOI Link": "http://dx.doi.org/10.1007/s10953-018-0793-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478750000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Steinrück, HP; Wasserscheid, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Steinrueck, Hans-Peter; Wasserscheid, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic Liquids in Catalysis", "Source Title": "CATALYSIS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ionic liquids (ILs), salts with melting points below 100 A degrees C, represent a fascinating class of liquid materials typically characterized by an extremely low vapor pressure. Besides their application as new solvents or as electrolytes for electrochemical purposes, there are two important concepts of using ILs in catalysis: Liquid-liquid biphasic catalysis and IL thin film catalysis. Liquid-liquid biphasic catalysis enables either a very efficient manner to apply catalytic ILs, e.g. in Friedel-Crafts reactions, or to apply ionic transition metal catalyst solutions. In both cases, phase separation after reaction allows an easy separation of reaction products and catalyst re-use. One problem of liquid-liquid biphasic catalysis is mass transfer limitation. If the chemical reaction is much faster than the liquid-liquid mass transfer the latter limits the overall reaction rate. This problem is overcome in IL thin film catalysis where diffusion pathways and thus the characteristic time of diffusion are short. Here, Supported Ionic Liquid Phase (SILP) and Solid Catalyst with Ionic Liquid Layer (SCILL) are the two most important concepts. In both, a high surface area solid substrate is covered with a thin IL film, which contains either a homogeneously dissolved transition metal complex for SILP, or which modifies catalytically active surface sites at the support for SCILL. In each concept, interface phenomena play a very important role: These may concern the interface of an IL phase with an organic phase in the case of liquid-liquid biphasic catalysis. For IL thin film catalysis, the interfaces of the IL with the gas phase and with catalytic nulloparticles and/or support materials are of critical importance. It has recently been demonstrated that these interfaces and also the bulk of ILs can be investigated in great detail using surface science studies, which greatly contributed to the fundamental understanding of the catalytic properties of ILs and supported IL materials. Exemplary results concerning the IL/vacuum or IL/gas interface, the solubility and surface enrichment of dissolved metal complexes, the IL/support interface and the in situ monitoring of chemical reactions in ILs are presented. Important concepts in catalysis with ionic liquids are reviewed, including Supported Ionic Liquid Phase (SILP) and Solid Catalyst with Ionic Liquid Layer (SCILL), along with the detailed analysis of the relevant interfaces using surface science methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 145, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 380, "End Page": 397, "Article Number": null, "DOI": "10.1007/s10562-014-1435-x", "DOI Link": "http://dx.doi.org/10.1007/s10562-014-1435-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347717000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, X; Liu, QT; Liu, JY; Liu, SY; Liu, XF; Zheng, LR; Shang, JX; Yu, RH; Shui, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Xin; Liu, Qingtao; Liu, Jieyuan; Liu, Shiyuan; Liu, Xiaofang; Zheng, Lirong; Shang, Jiaxiang; Yu, Ronghai; Shui, Jianglan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron atom-cluster interactions increase activity and improve durability in Fe-N-C fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneously increasing the activity and stability of the single-atom active sites of M-N-C catalysts is critical but remains a great challenge. Here, we report an Fe-N-C catalyst with nitrogen-coordinated iron clusters and closely surrounding Fe-N-4 active sites for oxygen reduction reaction in acidic fuel cells. A strong electronic interaction is built between iron clusters and satellite Fe-N-4 due to unblocked electron transfer pathways and very short interacting distances. The iron clusters optimize the adsorption strength of oxygen reduction intermediates on Fe-N-4 and also shorten the bond amplitude of Fe-N-4 with incoherent vibrations. As a result, both the activity and stability of Fe-N-4 sites are increased by about 60% in terms of turnover frequency and demetalation resistance. This work shows the great potential of strong electronic interactions between multiphase metal species for improvements of single-atom catalysts. It is challenging to break the activity-stability trade-off in Fe-N-C fuel cell catalysts. Here, the authors show that interactions between iron atoms and clusters accelerate reaction kinetics and suppress demetalation to improve fuel cell stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2963, "DOI": "10.1038/s41467-022-30702-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30702-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800650200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, YC; Liu, H; Deng, YX; Ye, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Yuchen; Liu, Han; Deng, Yexin; Ye, Peide D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Device Perspective for Black Phosphorus Field-Effect Transistors: Contact Resistance, Ambipolar Behavior, and Scaling", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although monolayer black phosphorus (BP), or phosphorene, has been successfully exfoliated and its optical properties have been explored, most of the electrical performance of the devices is demonstrated on few-layer phosphorene and ultrathin BP films. In this paper, we study the channel length scaling of ultrathin BP field-effect transistors (FETs) and discuss a scheme for using various contact metals to change the transistor characteristics. Through studying transistor behaviors with various channel lengths, the contact resistance can be extracted with the transfer length method (TLM). With different contact metals, we find out that the metal/BP interface has different Schottky barrier heights, leading to a significant difference in contact resistance, which is quite different from previous studies of transition metal dichalcogenides (TMDs), such as MoS2, where the Fermi level is strongly pinned near the conduction band edge at the metal/MoS2 interface. The nature of BP transistors is Schottky barrier FETs, where the on and off states are controlled by tuning the Schottky barriers at the two contacts. We also observe the ambipolar characteristics of BP transistors with enhanced n-type drain current and demonstrate that the p-type carriers can be easily shifted to n-type or vice versa by controlling the gate bias and drain bias, showing the potential to realize BP CMOS logic circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 8, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10035, "End Page": 10042, "Article Number": null, "DOI": "10.1021/nn502553m", "DOI Link": "http://dx.doi.org/10.1021/nn502553m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343952600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Utzat, H; Sun, WW; Kaplan, AEK; Krieg, F; Ginterseder, M; Spokoyny, B; Klein, ND; Shulenberger, KE; Perkinson, CF; Kovalenko, MV; Bawendi, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Utzat, Hendrik; Sun, Weiwei; Kaplan, Alexander E. K.; Krieg, Franziska; Ginterseder, Matthias; Spokoyny, Boris; Klein, Nathan D.; Shulenberger, Katherine E.; Perkinson, Collin F.; Kovalenko, Maksym V.; Bawendi, Moungi G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coherent single-photon emission from colloidal lead halide perovskite quantum dots", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemically made colloidal semiconductor quantum dots have long been proposed as scalable and color-tunable single emitters in quantum optics, but they have typically suffered from prohibitively incoherent emission. We now demonstrate that individual colloidal lead halide perovskite quantum dots (PQDs) display highly efficient single-photon emission with optical coherence times as long as 80 picoseconds, an appreciable fraction of their 210-picosecond radiative lifetimes. These measurements suggest that PQDs should be explored as building blocks in sources of indistinguishable single photons and entangled photon pairs. Our results present a starting point for the rational design of lead halide perovskite-based quantum emitters that have fast emission, wide spectral tunability, and scalable production and that benefit from the hybrid integration with nullophotonic components that has been demonstrated for colloidal materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2019, "Volume": 363, "Issue": 6431, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1068, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau7392", "DOI Link": "http://dx.doi.org/10.1126/science.aau7392", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460750100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, CX; Zheng, Y; Ran, JR; Xie, FX; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Chunxian; Zheng, Yao; Ran, Jingrun; Xie, Fangxi; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering High-Energy Interfacial Structures for High-Performance Oxygen-Involving Electrocatalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering high-energy interfacial structures for high-performance electrocatalysis is achieved by chemical coupling of active CoO nulloclusters and high-index facet Mn3O4 nullo-octahedrons (hi-Mn3O4). A thorough characterization, including synchrotron-based near edge X-ray absorption fine structure, reveals that strong interactions between both components promote the formation of high-energy interfacial Mn-O-Co species and high oxidation state CoO, from which electrons are drawn by MnIII-O present in hi-Mn3O4. The CoO/hi-Mn3O4 demonstrates an excellent catalytic performance over the conventional metal oxide-based electrocatalysts, which is reflected by 1.2 times higher oxygen evolution reaction (OER) activity than that of Ru/C and a comparable oxygen reduction reaction (ORR) activity to that of Pt/C as well as a better stability than that of Ru/C (95% vs. 81% retained OER activity) and Pt/C (92% vs. 78% retained ORR activity after 10 h running) in alkaline electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2017, "Volume": 56, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 8539, "End Page": 8543, "Article Number": null, "DOI": "10.1002/anie.201701531", "DOI Link": "http://dx.doi.org/10.1002/anie.201701531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404739200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, QM; Li, P; Liu, LQ; Yang, H; Fukami, S; Razavi, A; Wu, H; Wang, K; Freimuth, F; Mokrousov, Y; Stiles, MD; Emori, S; Hoffmann, A; Åkerman, J; Roy, K; Wang, JP; Yang, SH; Garello, K; Zhang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Qiming; Li, Peng; Liu, Luqiao; Yang, Hyunsoo; Fukami, Shunsuke; Razavi, Armin; Wu, Hao; Wang, Kang; Freimuth, Frank; Mokrousov, Yuriy; Stiles, Mark D.; Emori, Satoru; Hoffmann, Axel; Akerman, Johan; Roy, Kaushik; Wang, Jian-Ping; Yang, See-Hun; Garello, Kevin; Zhang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roadmap of Spin-Orbit Torques", "Source Title": "IEEE TRANSACTIONS ON MAGNETICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-orbit torque (SOT) is an emerging technology that enables the efficient manipulation of spintronic devices. The initial processes of interest in SOTs involved electric fields, spin-orbit coupling, conduction electron spins, and magnetization. More recently, interest has grown to include a variety of other processes that include phonons, magnons, or heat. Over the past decade, many materials have been explored to achieve a larger SOT efficiency. Recently, holistic design to maximize the performance of SOT devices has extended material research from a nonmagnetic layer to a magnetic layer. The rapid development of SOT has spurred a variety of SOT-based applications. In this article, we first review the theories of SOTs by introducing the various mechanisms thought to generate or control SOTs, such as the spin Hall effect, the Rashba-Edelstein effect, the orbital Hall effect, thermal gradients, magnons, and strain effects. Then, we discuss the materials that enable these effects, including metals, metallic alloys, topological insulators, 2-D materials, and complex oxides. We also discuss the important roles in SOT devices of different types of magnetic layers, such as magnetic insulators, antiferromagnets, and ferrimagnets. Afterward, we discuss device applications utilizing SOTs. We discuss and compare three- and two-terminal SOT-magnetoresistive random access memories (MRAMs); we mention various schemes to eliminate the need for an external field. We provide technological application considerations for SOT-MRAM and give perspectives on SOT-based neuromorphic devices and circuits. In addition to SOT-MRAM, we present SOT-based spintronic terahertz generators, nullo-oscillators, and domain-wall and skyrmion racetrack memories. This article aims to achieve a comprehensive review of SOT theory, materials, and applications, guiding future SOT development in both the academic and industrial sectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 57, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1109/TMAG.2021.3078583", "DOI Link": "http://dx.doi.org/10.1109/TMAG.2021.3078583", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665019800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, LB; Wang, J; Lin, WZ; Sumpter, BG; Meunier, V; Pan, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Liangbo; Wang, Jun; Lin, Wenzhi; Sumpter, Bobby G.; Meunier, Vincent; Pan, Minghu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Bandgap and Edge Reconstruction in Phosphorene Materials", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-layer black phosphorus (BP), or phosphorene, is a highly anisotropic two-dimensional elemental material possessing promising semiconductor properties for flexible electronics. However, the direct bandgap of single-layer black phosphorus predicted theoretically has not been directly measured, and the properties of its edges have not been considered in detail. Here we report atomic scale electronic variation related to strain-induced anisotropic deformation of the puckered honeycomb structure of freshly cleaved black phosphorus using a high-resolution scanning tunneling spectroscopy (STS) survey along the light (x) and heavy (y) effective mass directions. Through a combination of STS measurements and first-principles calculations, a model for edge reconstruction is also determined. The reconstruction is shown to self-passivate most dangling bonds by switching the coordination number of phosphorus from 3 to 5 or 3 to 4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 482, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6400, "End Page": 6406, "Article Number": null, "DOI": "10.1021/nl502892t", "DOI Link": "http://dx.doi.org/10.1021/nl502892t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345723800058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Knebel, A; Geppert, B; Volgmann, K; Kolokolov, DI; Stepanov, AG; Twiefel, J; Heitjans, P; Volkmer, D; Caro, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Knebel, A.; Geppert, B.; Volgmann, K.; Kolokolov, D. I.; Stepanov, A. G.; Twiefel, J.; Heitjans, P.; Volkmer, D.; Caro, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defibrillation of soft porous metal-organic frameworks with electric fields", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gas transport through metal-organic framework membranes (MOFs) was switched in situ by applying an external electric field (E-field). The switching of gas permeation upon E-field polarization could be explained by the structural transformation of the zeolitic imidazolate framework ZIF-8 into polymorphs with more rigid lattices. Permeation measurements under a direct-current E-field poling of 500 volts per millimeter showed reversibly controlled switching of the ZIF-8 into polar polymorphs, which was confirmed by x-ray diffraction and ab initio calculations. The stiffening of the lattice causes a reduction in gas transport through the membrane and sharpens the molecular sieving capability. Dielectric spectroscopy, polarization, and deuterium nuclear magnetic resonullce studies revealed low-frequency resonullces of ZIF-8 that we attribute to lattice flexibility and linker movement. Upon E-field polarization, we observed a defibrillation of the different lattice motions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2017, "Volume": 358, "Issue": 6361, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 347, "End Page": 351, "Article Number": null, "DOI": "10.1126/science.aal2456", "DOI Link": "http://dx.doi.org/10.1126/science.aal2456", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413251000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZP; Li, YF; Torres-Pinto, A; LaGrow, AP; Diaconescu, VM; Simonelli, L; Sampaio, MJ; Bondarchuk, O; Amorim, I; Araujo, A; Silva, AMT; Silva, CG; Faria, JL; Liu, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhipeng; Li, Yifan; Torres-Pinto, Andre; LaGrow, Alec P.; Diaconescu, Vlad Martin; Simonelli, Laura; Sampaio, Maria J.; Bondarchuk, Oleksandr; Amorim, Isilda; Araujo, Ana; Silva, Adrian M. T.; Silva, Claudia G.; Faria, Joaquim L.; Liu, Lifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Ir and Ru anchored on graphitic carbon nitride for efficient and stable electrocatalytic/photocatalytic hydrogen evolution", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Renewable energy-powered water electrolysis and photocatalytic water splitting are two promising approaches to green hydrogen production. Electrocatalysts and photocatalysts are essential components determining the performance of water electrolyzers and photocatalytic reactors, respectively. Currently, there is a pressing need to develop efficient and stable electrocatalysts and photocatalysts for large-scale deployment of these devices to reach carbon neutrality. Herein, we report the synthesis of single-atom Ir and Ru anchored on mesoporous graphitic carbon nitride (Ir-g-CN and Ru-g-CN), which can be used as electrocatalysts and photocatalysts for the hydrogen evolution reaction (HER). Remarkably, Ru-g-CN shows a high turnover frequency (TOF) of 12.9 and 5.1 s- 1 at an overpotential (eta) of 100 mV in 0.5 M H2SO4 and 1.0 M KOH, respectively, outperforming Ir-g-CN, commercial Pt/C benchmark and many other advanced HER catalysts reported recently. Moreover, Ru-g-CN can deliver an exceptionally high mass activity of 24.55 and 8.78 A mg- 1 at eta = 100 mV in acidic and alkaline solutions, meanwhile exhibiting a high apparent current density, which is favorable for practical applications. Additionally, both Ru-g-CN and Ir-g-CN show outstanding catalytic stability, continuously catalyzing the HER in acidic and alkaline conditions for 120 h with minimal degradation. Besides, when used for photocatalytic water splitting, Ru-g-CN can achieve a high hydrogen production rate of 489.7 mmol H2 gRu- 1 h-1, and shows good photocatalytic stability. Our density functional theory (DFT) calculations demonstrate that loading Ir and Ru single-atoms on g-CN alters the electronic structure, resulting in a reduced bandgap and improved electrical conductivity, facilitating electron transfer during the catalysis. Moreover, the Gibbs free energy of hydrogen adsorption on Ru-g-CN and Ir-g-CN is also substantially lowered, enhancing HER performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2022, "Volume": 310, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121318, "DOI": "10.1016/j.apcatb.2022.121318", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2022.121318", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804054800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suo, LM; Oh, D; Lin, YX; Zhuo, ZQ; Borodin, O; Gao, T; Wang, F; Kushima, A; Wang, ZQ; Kim, HC; Qi, Y; Yang, WL; Pan, F; Li, J; Xu, K; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suo, Liumin; Oh, Dahyun; Lin, Yuxiao; Zhuo, Zengqing; Borodin, Oleg; Gao, Tao; Wang, Fei; Kushima, Akihiro; Wang, Ziqing; Kim, Ho-Cheol; Qi, Yue; Yang, Wanli; Pan, Feng; Li, Ju; Xu, Kang; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-electrolyte interphase (SEI) is the key component that enables all advanced electrochemical devices, the best representative of which is Li-ion battery (LIB). It kinetically stabilizes electrolytes at potentials far beyond their thermodynamic stability limits, so that cell reactions could proceed reversibly. Its ad hoc chemistry and formation mechanism has been a topic under intensive investigation since the first commercialization of LIB 25 years ago. Traditionally SEI can only be formed in nonaqueous electrolytes. However, recent efforts successfully transplanted this concept into aqueous media, leading to significant expansion in the electrochemical stability window of aqueous electrolytes from 1.23 V to beyond 4.0 V. This not only made it possible to construct a series of high voltage/energy density aqueous LIBs with unprecedented safety, but also brought high flexibility and even open configurations that have been hitherto unavailable for any LIB chemistries. While this new class of aqueous electrolytes has been successfully demonstrated to support diversified battery chemistries, the chemistry and formation mechanism of the key component, an aqueous SEI, has remained virtually unknown. In this work, combining various spectroscopic, electrochemical and computational techniques, we rigorously examined this new interphase, and comprehensively characterized its chemical composition, microstructure and stability in battery environment. A dynamic picture obtained reveals how a dense and protective interphase forms on anode surface under competitive decompositions of salt anion, dissolved ambient gases and water molecule. By establishing basic laws governing the successful formation of an aqueous SEI, the in-depth understanding presented in this work will assist the efforts in tailor-designing better interphases that enable more energetic chemistries operating farther away from equilibria in aqueous media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2017, "Volume": 139, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18670, "End Page": 18680, "Article Number": null, "DOI": "10.1021/jacs.7b10688", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b10688", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419082100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, CY; Zhang, LZ; Yang, Q; Huang, SX; Shi, HP; Long, Q; Qian, B; Liu, ZH; Guan, QB; Liu, MJ; Yang, RH; Zhao, Q; You, ZW; Ye, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Chenyu; Zhang, Luzhi; Yang, Qi; Huang, Shixing; Shi, Hongpeng; Long, Qiang; Qian, Bei; Liu, Zenghe; Guan, Qingbao; Liu, Mingjian; Yang, Renhao; Zhao, Qiang; You, Zhengwei; Ye, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-healing polyurethane-elastomer with mechanical tunability for multiple biomedical applications in vivo", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The unique properties of self-healing materials hold great potential in the field of biomedical engineering. Although previous studies have focused on the design and synthesis of self-healing materials, their application in in vivo settings remains limited. Here, we design a series of biodegradable and biocompatible self-healing elastomers (SHEs) with tunable mechanical properties, and apply them to various disease models in vivo, in order to test their reparative potential in multiple tissues and at physiological conditions. We validate the effectiveness of SHEs as promising therapies for aortic aneurysm, nerve coaptation and bone immobilization in three animal models. The data presented here support the translation potential of SHEs in diverse settings, and pave the way for the development of self-healing materials in clinical contexts. The unique properties of self-healing materials hold great potential in the field of biomedical engineering. Here, the authors designed a series of biodegradable and biocompatible self-healing elastomers with tunable mechanical properties, and apply them to various disease models in vivo, including aortic aneurism, bone fracture and nerve amputation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4395, "DOI": "10.1038/s41467-021-24680-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24680-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677640700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baars, J; Domenech, T; Bleischwitz, R; Melin, HE; Heidrich, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baars, Joris; Domenech, Teresa; Bleischwitz, Raimund; Melin, Hans Eric; Heidrich, Oliver", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Circular economy strategies for electric vehicle batteries reduce reliance on raw materials", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New battery chemistry can help reduce the reliance on Co for electric vehicles. However, to avoid burden shifting to other resources such as Ni, circular economy strategies with enhanced battery traceability and recycling could contribute substantially to the reduction of primary Co demand from the automotive industry. The wide adoption of lithium-ion batteries used in electric vehicles will require increased natural resources for the automotive industry. The expected rapid increase in batteries could result in new resource challenges and supply-chain risks. To strengthen the resilience and sustainability of automotive supply chains and reduce primary resource requirements, circular economy strategies are needed. Here we illustrate how these strategies can reduce the extraction of primary raw materials, that is, cobalt supplies. Material flow analysis is applied to understand current and future flows of cobalt embedded in electric vehicle batteries across the European Union. A reference scenario is presented and compared with four strategies: technology-driven substitution and technology-driven reduction of cobalt, new business models to stimulate battery reuse/recycling and policy-driven strategy to increase recycling. We find that new technologies provide the most promising strategies to reduce the reliance on cobalt substantially but could result in burden shifting such as an increase in nickel demand. To avoid the latter, technological developments should be combined with an efficient recycling system. We conclude that more-ambitious circular economy strategies, at both government and business levels, are urgently needed to address current and future resource challenges across the supply chain successfully.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 79, "Article Number": null, "DOI": "10.1038/s41893-020-00607-0", "DOI Link": "http://dx.doi.org/10.1038/s41893-020-00607-0", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566879100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, KP; Zhou, JY; Miao, M; Wu, HM; Thaiboonrod, S; Fang, JH; Feng, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Kunpeng; Zhou, Jianyu; Miao, Miao; Wu, Hongmin; Thaiboonrod, Sineenat; Fang, Jianhui; Feng, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Ordered Thermoplastic Polyurethane/Aramid nullofiber Conductive Foams Modulated by Kevlar Polyanion for Piezoresistive Sensing and Electromagnetic Interference Shielding", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly ordered and uniformly porous structure of conductive foams is a vital issue for various functional purposes such as piezoresistive sensing and electromagnetic interference (EMI) shielding. With the aids of Kevlar polyanionic chains, thermoplastic polyurethane (TPU) foams reinforced by aramid nullofibers (ANF) with adjustable pore-size distribution were successfully obtained via a non-solvent-induced phase separation. In this regard, the most outstanding result is the in situ formation of ANF in TPU foams after protonation of Kevlar polyanion during the NIPS process. Furthermore, in situ growth of copper nulloparticles (Cu NPs) on TPU/ANF foams was performed according to the electroless deposition by using the tiny amount of pre-blended Ti3C2Tx MXene as reducing agents. Particularly, the existence of Cu NPs layers significantly promoted the storage modulus in 2,932% increments, and the well-designed TPU/ANF/Ti3C2Tx MXene (PAM-Cu) composite foams showed distinguished compressive cycle stability. Taking virtues of the highly ordered and elastic porous architectures, the PAM-Cu foams were utilized as piezoresistive sensor exhibiting board compressive interval of 0-344.5 kPa (50% strain) with good sensitivity at 0.46 kPa(-1). Meanwhile, the PAM-Cu foams displayed remarkable EMI shielding effectiveness at 79.09 dB in X band. This work provides an ideal strategy to fabricate highly ordered TPU foams with outstanding elastic recovery and excellent EMI shielding performance, which can be used as a promising candidate in integration of satisfactory piezoresistive sensor and EMI shielding applications for human-machine interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 88, "DOI": "10.1007/s40820-023-01062-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01062-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965205100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neupane, M; Xu, SY; Sankar, R; Alidoust, N; Bian, G; Liu, C; Belopolski, I; Chang, TR; Jeng, HT; Lin, H; Bansil, A; Chou, F; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Neupane, Madhab; Xu, Su-Yang; Sankar, Raman; Alidoust, Nasser; Bian, Guang; Liu, Chang; Belopolski, Ilya; Chang, Tay-Rong; Jeng, Horng-Tay; Lin, Hsin; Bansil, Arun; Chou, Fangcheng; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of a three-dimensional topological Dirac semimetal phase in high-mobility Cd3As2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symmetry-broken three-dimensional (3D) topological Dirac semimetal systems with strong spin-orbit coupling can host many exotic Hall-like phenomena and Weyl fermion quantum transport. Here, using high-resolution angle-resolved photoemission spectroscopy, we performed systematic electronic structure studies on Cd3As2, which has been predicted to be the parent material, from which many unusual topological phases can be derived. We observe a highly linear bulk band crossing to form a 3D dispersive Dirac cone projected at the Brillouin zone centre by studying the (001)-cleaved surface. Remarkably, an unusually high in-plane Fermi velocity up to 1.5 x 10(6) ms(-1) is observed in our samples, where the mobility is known up to 40,000 cm(2)V(-1)s(-1), suggesting that Cd3As2 can be a promising candidate as an anisotropic-hypercone (three-dimensional) high spin-orbit analogue of 3D graphene. Our discovery of the Dirac-like bulk topological semimetal phase in Cd3As2 opens the door for exploring higher dimensional spin-orbit Dirac physics in a real material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1203, "Times Cited, All Databases": 1275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3786, "DOI": "10.1038/ncomms4786", "DOI Link": "http://dx.doi.org/10.1038/ncomms4786", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337371600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pulido, A; Chen, LJ; Kaczorowski, T; Holden, D; Little, MA; Chong, SY; Slater, BJ; McMahon, DP; Bonillo, B; Stackhouse, CJ; Stephenson, A; Kane, CM; Clowes, R; Hasell, T; Cooper, AI; Day, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pulido, Angeles; Chen, Linjiang; Kaczorowski, Tomasz; Holden, Daniel; Little, Marc A.; Chong, Samantha Y.; Slater, Benjamin J.; McMahon, David P.; Bonillo, Baltasar; Stackhouse, Chloe J.; Stephenson, Andrew; Kane, Christopher M.; Clowes, Rob; Hasell, Tom; Cooper, Andrew I.; Day, Graeme M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional materials discovery using energy-structure-function maps", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular crystals cannot be designed in the same manner as macroscopic objects, because they do not assemble according to simple, intuitive rules. Their structures result from the balance of many weak interactions, rather than from the strong and predictable bonding patterns found in metal-organic frameworks and covalent organic frameworks. Hence, design strategies that assume a topology or other structural blueprint will often fail. Here we combine computational crystal structure prediction and property prediction to build energy-structure-function maps that describe the possible structures and properties that are available to a candidate molecule. Using these maps, we identify a highly porous solid, which has the lowest density reported for a molecular crystal so far. Both the structure of the crystal and its physical properties, such as methane storage capacity and guest-molecule selectivity, are predicted using the molecular structure as the only input. More generally, energy-structure-function maps could be used to guide the experimental discovery of materials with any target function that can be calculated from predicted crystal structures, such as electronic structure or mechanical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2017, "Volume": 543, "Issue": 7647, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 657, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature21419", "DOI Link": "http://dx.doi.org/10.1038/nature21419", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397619700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, YS; Shi, T; Richards, WD; Li, JC; Kim, JC; Bo, SH; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Yaosen; Shi, Tan; Richards, William D.; Li, Juchuan; Kim, Jae Chul; Bo, Shou-Hang; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compatibility issues between electrodes and electrolytes in solid-state batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Remarkable success has been achieved in the discovery of ceramic alkali superionic conductors as electrolytes in solid-state batteries; however, obtaining a stable interface between these electrolytes and electrodes is difficult. Only limited studies on the compatibility between electrodes and solid electrolytes have been reported, partially because of the need for expensive instrumentation and special cell designs. Without simple yet powerful tools, these compatibility issues cannot be systematically investigated, thus hindering the generalization of design rules for the integration of solid-state battery components. Herein, we present a methodology that combines density functional theory calculations and simple experimental techniques such as X-ray diffraction, simultaneous differential scanning calorimetry and thermal gravimetric analysis, and electrochemistry to efficiently screen the compatibility of numerous electrode/electrolyte pairs. We systemically distinguish between the electrochemical stability of the solid-state conductor, which is relevant wherever the electrolyte contacts an electron pathway, and the electrochemical stability of the electrode/electrolyte interfaces. For the solid electrolyte, we are able to computationally derive an absolute thermodynamic stability voltage window, which is small for Na3PS4 and Na3PSe4, and a larger voltage window which can be kinetically stabilized. The experimental stability, when measured with reliable techniques, falls between these thermodynamic and kinetic limits. Employing a Na solid-state system as an example, we demonstrate the efficiency of our method by finding the most stable system (NaCrO2 vertical bar Na3PS4 vertical bar Na-Sn) within a selected chemical space (more than 20 different combinations of electrodes and electrolytes). Important selection criteria for the cathode, electrolyte, and anode in solid-state batteries are also derived from this study. The current method not only provides an essential guide for integrating all-solid-state battery components but can also significantly accelerate the expansion of the electrolyte/electrode compatibility data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1150, "End Page": 1166, "Article Number": null, "DOI": "10.1039/c7ee00534b", "DOI Link": "http://dx.doi.org/10.1039/c7ee00534b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401408500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZH; Zhu, QQ; Liu, Y; Zhang, Y; Jia, ZR; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zehua; Zhu, Qianqian; Liu, Yue; Zhang, Yan; Jia, Zirui; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Self-Assembly Based Tunable Absorber: Lightweight, Hydrophobic and Self-Cleaning Properties", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although multifunctional aerogels are expected to be used in applications such as portable electronic devices, it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure. Herein, a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties, superhydrophobicity, and self-cleaning by water-induced NiCo-MOF self-assembly. Specifically, the impedance matching of the three-dimensional (3D) structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption. As a result, the prepared NiCo/C aerogels have a broadband width of 6.22 GHz at 1.9 mm. Due to the presence of hydrophobic functional groups, CoNi/C aerogels improve the stability in humid environments and obtain hydrophobicity with large contact angles > 140 degrees. This multifunctional aerogel has promising applications in electromagnetic wave absorption, resistance to water or humid environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137, "DOI": "10.1007/s40820-023-01108-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01108-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000995996100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, W; Blancon, JC; Neukirch, AJ; Appavoo, K; Tsai, H; Chhowalla, M; Alam, MA; Sfeir, MY; Katan, C; Even, J; Tretiak, S; Crochet, JJ; Gupta, G; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Wanyi; Blancon, Jean-Christophe; Neukirch, Amanda J.; Appavoo, Kannatassen; Tsai, Hsinhan; Chhowalla, Manish; Alam, Muhammad A.; Sfeir, Matthew Y.; Katan, Claudine; Even, Jacky; Tretiak, Sergei; Crochet, Jared J.; Gupta, Gautam; Mohite, Aditya D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-activated photocurrent degradation and self-healing in perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed organometallic perovskite solar cells have emerged as one of the most promising thin-film photovoltaic technology. However, a key challenge is their lack of stability over prolonged solar irradiation. Few studies have investigated the effect of light soaking on hybrid perovskites and have attributed the degradation in the optoelectronic properties to photochemical or field-assisted ion migration. Here we show that the slow photocurrent degradation in thin-film photovoltaic devices is due to the formation of light-activated meta-stable deep-level trap states. However, the devices can self-heal completely by resting them in the dark for <1 min or the degradation can be completely prevented by operating the devices at 0 degrees C. We investigate several physical mechanisms to explain the microscopic origin for the formation of these trap states, among which the creation of small polaronic states involving localized cooperative lattice strain and molecular orientations emerges as a credible microscopic mechanism requiring further detailed studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 641, "Times Cited, All Databases": 683, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11574, "DOI": "10.1038/ncomms11574", "DOI Link": "http://dx.doi.org/10.1038/ncomms11574", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375939800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bogaerts, A; Tu, X; Whitehead, JC; Centi, G; Lefferts, L; Guaitella, O; Azzolina-Jury, F; Kim, HH; Murphy, AB; Schneider, WF; Nozaki, T; Hicks, JC; Rousseau, A; Thevenet, F; Khacef, A; Carreon, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bogaerts, Annemie; Tu, Xin; Whitehead, J. Christopher; Centi, Gabriele; Lefferts, Leon; Guaitella, Olivier; Azzolina-Jury, Federico; Kim, Hyun-Ha; Murphy, Anthony B.; Schneider, William F.; Nozaki, Tomohiro; Hicks, Jason C.; Rousseau, Antoine; Thevenet, Frederic; Khacef, Ahmed; Carreon, Maria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The 2020 plasma catalysis roadmap", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO(2)conversion into value-added chemicals and fuels, CH(4)activation into hydrogen, higher hydrocarbons or oxygenates, and NH(3)synthesis. Other applications are already more established, such as for air pollution control, e.g. volatile organic compound remediation, particulate matter and NO(x)removal. In addition, plasma is also very promising for catalyst synthesis and treatment. Plasma catalysis clearly has benefits over 'conventional' catalysis, as outlined in the Introduction. However, a better insight into the underlying physical and chemical processes is crucial. This can be obtained by experiments applying diagnostics, studying both the chemical processes at the catalyst surface and the physicochemical mechanisms of plasma-catalyst interactions, as well as by computer modeling. The key challenge is to design cost-effective, highly active and stable catalysts tailored to the plasma environment. Therefore, insight from thermal catalysis as well as electro- and photocatalysis is crucial. All these aspects are covered in this Roadmap paper, written by specialists in their field, presenting the state-of-the-art, the current and future challenges, as well as the advances in science and technology needed to meet these challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 492, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2020, "Volume": 53, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 443001, "DOI": "10.1088/1361-6463/ab9048", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/ab9048", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563194400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, YJ; Ma, LG; Cai, P; Zhong, RD; Ye, C; Shen, J; Gu, GD; Chen, XH; Zhang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Yijun; Ma, Liguo; Cai, Peng; Zhong, Ruidan; Ye, Cun; Shen, Jian; Gu, G. D.; Chen, Xian Hui; Zhang, Yuanbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-temperature superconductivity in monolayer Bi2Sr2CaCu2O8+δ", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although copper oxide high-temperature superconductors constitute a complex and diverse material family, they all share a layered lattice structure. This curious fact prompts the question of whether high-temperature superconductivity can exist in an isolated monolayer of copper oxide, and if so, whether the two-dimensional superconductivity and various related phenomena differ from those of their three-dimensional counterparts. The answers may provide insights into the role of dimensionality in high-temperature superconductivity. Here we develop a fabrication process that obtains intrinsic monolayer crystals of the high-temperature superconductor Bi2Sr2CaCu2O8+delta (Bi-2212; here, a monolayer refers to a half unit cell that contains two CuO2 planes). The highest superconducting transition temperature of the monolayer is as high as that of optimally doped bulk. The lack of dimensionality effect on the transition temperature defies expectations from the Mermin-Wagner theorem, in contrast to the much-reduced transition temperature in conventional two-dimensional superconductors such as NbSe2. The properties of monolayer Bi-2212 become extremely tunable; our survey of superconductivity, the pseudogap, charge order and the Mott state at various doping concentrations reveals that the phases are indistinguishable from those in the bulk. Monolayer Bi-2212 therefore displays all the fundamental physics of high-temperature superconductivity. Our results establish monolayer copper oxides as a platform for studying high-temperature superconductivity and other strongly correlated phenomena in two dimensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2019, "Volume": 575, "Issue": 7781, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1718-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1718-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496159900054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maschita, J; Banerjee, T; Savasci, G; Haase, F; Ochsenfeld, C; Lotsch, BV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maschita, Johannes; Banerjee, Tanmay; Savasci, Goekcen; Haase, Frederik; Ochsenfeld, Christian; Lotsch, Bettina, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionothermal Synthesis of Imide-Linked Covalent Organic Frameworks", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are an extensively studied class of porous materials, which distinguish themselves from other porous polymers in their crystallinity and high degree of modularity, enabling a wide range of applications. COFs are most commonly synthesized solvothermally, which is often a time-consuming process and restricted to well-soluble precursor molecules. Synthesis of polyimide-linked COFs (PI-COFs) is further complicated by the poor reversibility of the ring-closing reaction under solvothermal conditions. Herein, we report the ionothermal synthesis of crystalline and porous PI-COFs in zinc chloride and eutectic salt mixtures. This synthesis does not require soluble precursors and the reaction time is significantly reduced as compared to standard solvothermal synthesis methods. In addition to applying the synthesis to previously reported imide COFs, a new perylene-based COF was also synthesized, which could not be obtained by the classical solvothermal route. In situ high-temperature XRPD analysis hints to the formation of precursor-salt adducts as crystalline intermediates, which then react with each other to form the COF.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2020, "Volume": 59, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15750, "End Page": 15758, "Article Number": null, "DOI": "10.1002/anie.202007372", "DOI Link": "http://dx.doi.org/10.1002/anie.202007372", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563950900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, BB; Lai, RC; Jiang, SJ; Zhou, LM; Ren, ZX; Lian, YX; Li, PY; Cao, XH; Xing, SY; Wang, YX; Li, WW; Zou, C; Chen, MY; Hong, ZJ; Li, C; Zhao, BD; Di, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Bingbing; Lai, Runchen; Jiang, Sijie; Zhou, Linming; Ren, Zhixiang; Lian, Yaxiao; Li, Puyang; Cao, Xuhui; Xing, Shiyu; Wang, Yaxin; Li, Weiwei; Zou, Chen; Chen, Mengyu; Hong, Zijian; Li, Cheng; Zhao, Baodan; Di, Dawei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastable near-infrared perovskite light-emitting diodes", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes are an emerging light source technology. However, similar to perovskite solar cells, poor operational stability remains an obstacle for commercial applications. Here we demonstrate ultrastable and efficient near-infrared (similar to 800 nm) perovskite light-emitting diodes with record-long operational lifetimes (T-50 extrapolated) of 11,539 h (similar to 1.3 years) and 32,675 h (similar to 3.7 years) for initial radiance (or current densities) of 3.7 W sr(-1) m(-2) (similar to 5.0 mA cm(-2)) and 2.1W sr(-1) m(-2) (similar to 3.2 mA cm(-2)), respectively, with even longer lifetimes forecasted for lower radiance. Key to this stability is the introduction of a dipolar molecular stabilizer, which interacts with the cations and anions at the perovskite grain boundaries. This suppresses ion migration under electric fields, preventing the formation of lead iodide, which mediates the phase transformation and decomposition of alpha-FAPbI(3) perovskite. These results remove the critical concern that halide perovskite devices may be intrinsically unstable, paving the path towards industrial applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 16, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 637, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01046-3", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01046-3", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837534000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, BL; Wen, TQ; Huang, KH; Wang, CZ; Chu, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Beilin; Wen, Tongqi; Huang, Kehan; Wang, Cai-Zhuang; Chu, Yanhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles study, fabrication, and characterization of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramic", "Source Title": "JOURNAL OF THE AMERICAN CERAMIC SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation possibility of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)C high-entropy ceramic (HHC-1) was first analyzed by the first-principles calculations, and then, it was successfully fabricated by hot-pressing sintering technique at 2073K under a pressure of 30MPa. The first-principles calculation results showed that the mixing enthalpy and mixing entropy of HHC-1 were -0.869 +/- 0.290 kJ/mol and 0.805R, respectively. The experimental results showed that the as-prepared HHC-1 not only had an interesting single rock-salt crystal structure of metal carbides but also possessed high compositional uniformity from nulloscale to microscale. By taking advantage of these unique features, it exhibited extremely high nullohardness of 40.6 +/- 0.6GPa and elastic modulus in the range from 514 +/- 10 to 522 +/- 10GPa and relatively high electrical resistivity of 91 +/- 1.3cm, which could be due to the presence of solid solution effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 102, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4344, "End Page": 4352, "Article Number": null, "DOI": "10.1111/jace.16295", "DOI Link": "http://dx.doi.org/10.1111/jace.16295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469290900056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, SM; Wei, MY; Xu, J; Atapattu, HR; Eickemeyer, FT; Darabi, K; Grater, L; Yang, Y; Liu, C; Teale, S; Chen, B; Chen, H; Wang, TH; Zeng, LW; Maxwell, A; Wang, ZW; Rao, KR; Cai, ZY; Zakeeruddin, SM; Pham, JT; Risko, CM; Amassian, A; Kanatzidis, MG; Graham, KR; Grätzel, M; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, So Min; Wei, Mingyang; Xu, Jian; Atapattu, Harindi R.; Eickemeyer, Felix T.; Darabi, Kasra; Grater, Luke; Yang, Yi; Liu, Cheng; Teale, Sam; Chen, Bin; Chen, Hao; Wang, Tonghui; Zeng, Lewei; Maxwell, Aidan; Wang, Zaiwei; Rao, Keerthan R.; Cai, Zhuoyun; Zakeeruddin, Shaik M.; Pham, Jonathan T.; Risko, Chad M.; Amassian, Aram; Kanatzidis, Mercouri G.; Graham, Kenneth R.; Gratzel, Michael; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering ligand reactivity enables high-temperature operation of stable perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) consisting of interfacial two- and three-dimensional heterostructures that incorporate ammonium ligand intercalation have enabled rapid progress toward the goal of uniting performance with stability. However, as the field continues to seek ever-higher durability, additional tools that avoid progressive ligand intercalation are needed to minimize degradation at high temperatures. We used ammonium ligands that are nonreactive with the bulk of perovskites and investigated a library that varies ligand molecular structure systematically. We found that fluorinated aniliniums offer interfacial passivation and simultaneously minimize reactivity with perovskites. Using this approach, we report a certified quasi-steady-state power-conversion efficiency of 24.09% for inverted-structure PSCs. In an encapsulated device operating at 85 degrees C and 50% relative humidity, we document a 1560-hour T-85 at maximum power point under 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2023, "Volume": 381, "Issue": 6654, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 209, "End Page": 215, "Article Number": null, "DOI": "10.1126/science.adi4107", "DOI Link": "http://dx.doi.org/10.1126/science.adi4107", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058656200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, C; Kim, EM; Wang, Y; Lee, G; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Cheng; Kim, Eun Mi; Wang, Yuan; Lee, Geunsik; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiferroicity in atomic van der Waals heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials that are simultaneously ferromagnetic and ferroelectric - multiferroics - promise the control of disparate ferroic orders, leading to technological advances in microwave magnetoelectric applications and next generation of spintronics. Single-phase multiferroics are challenged by the opposite d-orbital occupations imposed by the two ferroics, and heterogeneous nullocomposite multiferroics demand ingredients' structural compatibility with the resultant multiferroicity exclusively at inter-materials boundaries. Here we propose the two-dimensional heterostructure multiferroics by stacking up atomic layers of ferromagnetic Cr2Ge2Te6 and ferroelectric In2Se3, thereby leading to all-atomic multiferroicity. Through first-principles density functional theory calculations, we find as In2Se3 reverses its polarization, the magnetism of Cr2Ge2Te6 is switched, and correspondingly In2Se3 becomes a switchable magnetic semiconductor due to proximity effect. This unprecedented multiferroic duality (i.e., switchable ferromagnet and switchable magnetic semiconductor) enables both layers for logic applications. Van der Waals heterostructure multiferroics open the door for exploring the low-dimensional magnetoelectric physics and spintronic applications based on artificial superlattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2657, "DOI": "10.1038/s41467-019-10693-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10693-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471586800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, LW; Chen, L; Dong, XL; Zhang, ST; Zhang, MX; Dai, X; Liu, XJ; Lin, P; Li, KF; Chen, CL; Pan, TT; Ma, FY; Chen, JC; Yuan, MJ; Zhang, YG; Chen, L; Zhou, RH; Han, Y; Chai, ZF; Wang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Linwei; Chen, Long; Dong, Xinglong; Zhang, Shitong; Zhang, Mingxing; Dai, Xing; Liu, Xiajie; Lin, Peng; Li, Kunfeng; Chen, Cailing; Pan, Tingting; Ma, Fuyin; Chen, Junchang; Yuan, Mengjia; Zhang, Yugang; Chen, Lei; Zhou, Ruhong; Han, Yu; Chai, Zhifang; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capture of radioiodine species during nuclear fuel reprocessing and nuclear accidents is crucial for nuclear safety, environmental protection, and public health. Previously reported emerging materials for iodine uptake cannot outperform commercial zeolites and active carbon under the practical dynamic scenario. Herein, we present a new design philosophy aiming at significantly enhanced specific host-guest interactions and obtain a nitrogen-rich covalent organic framework material by introducing a bipyridine group into the building block for the simultaneous capture of both iodine gas through enhanced electron-pair effect and organic iodide via the methylation reaction. These efforts give rise to not only an ultrahigh uptake capacity of 6.0 g g(-1) for iodine gas and a record-high value of 1.45 g g(-1) for methyl iodide under static sorption conditions but also, more importantly, a record-high iodine loading capability under dynamic conditions demonstrated from the breakthrough experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 699, "End Page": 714, "Article Number": null, "DOI": "10.1016/j.chempr.2020.11.024", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.11.024", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628786100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avsar, A; Vera-Marun, IJ; Tan, JY; Watanabe, K; Taniguchi, T; Neto, AHC; Özyilmaz, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avsar, Ahmet; Vera-Marun, Ivan J.; Tan, Jun You; Watanabe, Kenji; Taniguchi, Takashi; Castro Neto, Antonio H.; Oezyilmaz, Barbaros", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air-Stable Transport in Graphene-Contacted, Fully Encapsulated Ultrathin Black Phosphorus-Based Field-Effect Transistors", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The presence of direct bandgap and high mobility in semiconductor few-layer black phosphorus offers an attractive prospect for using this material in future two-dimensional electronic devices. However, creation of barrier-free contacts which is necessary to achieve high performance in black phosphorus-based devices is challenging and currently limits their potential for applications. Here, we characterize fully encapsulated ultrathin (down to bilayer) black phosphorus field effect transistors fabricated under inert gas conditions by utilizing graphene as source drain electrodes and boron nitride as an encapsulation layer. The observation of a linear I-SD-V-SD behavior with negligible temperature dependence shows that graphene electrodes lead to barrier-free contacts, solving the issue of Schottky barrier limited transport in the technologically relevant two-terminal field-effect-transistor geometry. Such one-atom-thick conformal source-drain electrodes also enable the black phosphorus surface to be sealed, to avoid rapid degradation, with the inert boron nitride encapsulating layer. This architecture, generally applicable for other sensitive two-dimensional crystals, results in air-stable, hysteresis-free transport characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4138, "End Page": 4145, "Article Number": null, "DOI": "10.1021/acsnullo.5b00289", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b00289", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353867000079", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZY; Zhang, LN; Zhao, L; Li, BJ; Bhatia, B; Wang, CX; Wilke, KL; Song, Y; Labban, O; Lienhard, JH; Wang, RZ; Wang, EN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zhenyuan; Zhang, Lenull; Zhao, Lin; Li, Bangjun; Bhatia, Bikram; Wang, Chenxi; Wilke, Kyle L.; Song, Youngsup; Labban, Omar; Lienhard, John H.; Wang, Ruzhu; Wang, Evelyn N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-efficiency desalination via a thermally-localized multistage solar still", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive vapor generation systems with interfacial solar heat localization enable high-efficiency low-cost desalination. In particular, recent progress combining interfacial solar heating and vaporization enthalpy recycling through a capillary-fed multistage architecture, known as the thermally-localized multistage solar still (TMSS), significantly improves the performance of passive solar desalination. Yet, state-of-the-art experimental demonstrations of solar-to-vapor conversion efficiency are still limited since the dominullt factors and the general design principle for TMSS were not well-understood. In this work, we show optimizing the overall heat and mass transport in a multistage configuration plays a key role for further improving the performance. This understanding also increases the flexibility of material choices for the TMSS design. Using a low-cost and free-of-salt accumulation TMSS architecture, we experimentally demonstrated a record-high solar-to-vapor conversion efficiency of 385% with a production rate of 5.78 L m(-2) h(-1) under one-sun illumination, where more than 75% of the total production was collected through condensation. This work not only significantly improves the performance of existing passive solar desalination technologies for portable and affordable drinking water, but also provides a comprehensive physical understanding and optimization principle for TMSS systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2020, "Volume": 13, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 830, "End Page": 839, "Article Number": null, "DOI": "10.1039/c9ee04122b", "DOI Link": "http://dx.doi.org/10.1039/c9ee04122b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000524490200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YM; Wang, WY; Boulesbaa, A; Kravchenko, II; Briggs, DP; Puretzky, A; Geohegan, D; Valentine, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yuanmu; Wang, Wenyi; Boulesbaa, Abdelaziz; Kravchenko, Ivan I.; Briggs, Dayrl P.; Puretzky, Alexander; Geohegan, David; Valentine, Jason", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonlinear Fano-Resonullt Dielectric Metasurfaces", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strong nonlinear light-matter interaction is highly sought-after for a variety of applications including lasing and all-optical light modulation. Recently, resonullt plasmonic structures have been considered promising candidates for enhancing nonlinear optical processes due to their ability to greatly enhance the optical near-field; however, their small mode volumes prevent the inherently large nonlinear susceptibility of the metal from being efficiently exploited. Here, we present an alternative approach that utilizes a Fano-resonullt silicon metasurface. The metasurface results in strong near-field enhancement within the volume of the silicon resonator while minimizing two photon absorption. We measure a third harmonic generation enhancement factor of 1.5 x 10(5) with respect to an unpattemed silicon film and an absolute conversion efficiency of 1.2 x 10(-6) with a peak pump intensity of 3.2 GW cm(-2). The enhanced nonlinearity, combined with a sharp linear transmittance spectrum, results in transmission modulation with a modulation depth of 36%. The modulation mechanism is studied by pump-probe experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 576, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7388, "End Page": 7393, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b02802", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b02802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364725400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, C; Liu, K; Zhu, YM; Li, PC; Wang, QY; Liu, B; Chen, SY; Li, HJW; Zhu, L; Li, HM; Fu, JW; Chen, Y; Pensa, E; Hu, JH; Lu, YR; Chan, TS; Cortés, E; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Chao; Liu, Kang; Zhu, Yuanmin; Li, Pengcheng; Wang, Qiyou; Liu, Bao; Chen, Shanyong; Li, Huangjingwei; Zhu, Li; Li, Hongmei; Fu, Junwei; Chen, Yu; Pensa, Evangelina; Hu, Junhua; Lu, Ying-Rui; Chan, Ting-Shan; Cortes, Emiliano; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimizing Hydrogen Binding on Ru Sites with RuCo Alloy nullosheets for Efficient Alkaline Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ruthenium (Ru)-based catalysts, with considerable performance and desirable cost, are becoming highly interesting candidates to replace platinum (Pt) in the alkaline hydrogen evolution reaction (HER). The hydrogen binding at Ru sites (Ru-H) is an important factor limiting the HER activity. Herein, density functional theory (DFT) simulations show that the essence of Ru-H binding energy is the strong interaction between the 4dz2 orbital of Ru and the 1s orbital of H. The charge transfer between Ru sites and substrates (Co and Ni) causes the appropriate downward shift of the 4dz2 -band center of Ru, which results in a Gibbs free energy of 0.022 eV for H* in the RuCo system, much lower than the 0.133 eV in the pure Ru system. This theoretical prediction has been experimentally confirmed using RuCo alloy-nullosheets (RuCo ANSs). They were prepared via a fast co-precipitation method followed with a mild electrochemical reduction. Structure characterizations reveal that the Ru atoms are embedded into the Co substrate as isolated active sites with a planar symmetric and Z-direction asymmetric coordination structure, obtaining an optimal 4dz2 modulated electronic structure. Hydrogen sensor and temperature program desorption (TPD) tests demonstrate the enhanced Ru-H interactions in RuCo ANSs compared to those in pure Ru nulloparticles. As a result, the RuCo ANSs reach an ultra-low overpotential of 10 mV at 10 mA cm(-2) and a Tafel slope of 20.6 mV dec(-1) in 1 M KOH, outperforming that of the commercial Pt/C. This holistic work provides a new insight to promote alkaline HER by optimizing the metal-H binding energy of active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2022, "Volume": 61, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202113664", "DOI Link": "http://dx.doi.org/10.1002/anie.202113664", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000727437100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Robatjazi, H; Zhao, HQ; Swearer, DF; Hogan, NJ; Zhou, LN; Alabastri, A; McClain, MJ; Nordlander, P; Halas, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Robatjazi, Hossein; Zhao, Hangqi; Swearer, Dayne F.; Hogan, Nathaniel J.; Zhou, Linull; Alabastri, Alessandro; McClain, Michael J.; Nordlander, Peter; Halas, Naomi J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmon-induced selective carbon dioxide conversion on earth-abundant aluminum-cuprous oxide antenna-reactor nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational combination of plasmonic nulloantennas with active transition metal-based catalysts, known as 'antenna-reactor' nullostructures, holds promise to expand the scope of chemical reactions possible with plasmonic photocatalysis. Here, we report earth-abundant embedded aluminum in cuprous oxide antenna-reactor heterostructures that operate more effectively and selectively for the reverse water-gas shift reaction under milder illumination than in conventional thermal conditions. Through rigorous comparison of the spatial temperature profile, optical absorption, and integrated electric field enhancement of the catalyst, we have been able to distinguish between competing photothermal and hot-carrier driven mechanistic pathways. The antenna-reactor geometry efficiently harnesses the plasmon resonullce of aluminum to supply energetic hot-carriers and increases optical absorption in cuprous oxide for selective carbon dioxide conversion to carbon monoxide with visible light. The transition from noble metals to aluminum based antenna-reactor heterostructures in plasmonic photocatalysis provides a sustainable route to high-value chemicals and reaffirms the practical potential of plasmon-mediated chemical transformations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27, "DOI": "10.1038/s41467-017-00055-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00055-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403768500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Seo, DH; Chen, T; Wu, LJ; Topsakal, M; Zhu, YM; Lu, DY; Ceder, G; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Seo, Dong-Hwa; Chen, Tina; Wu, Lijun; Topsakal, Mehmet; Zhu, Yimei; Lu, Deyu; Ceder, Gerbrand; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kinetic pathways of ionic transport in fast-charging lithium titanate", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fast-charging batteries typically use electrodes capable of accommodating lithium continuously by means of solid-solution transformation because they have few kinetic barriers apart from ionic diffusion. One exception is lithium titanate (Li4Ti5O12), an anode exhibiting extraordinary rate capability apparently inconsistent with its two-phase reaction and slow Li diffusion in both phases. Through real-time tracking of Li+ migration using operando electron energy-loss spectroscopy, we reveal that facile transport in Li4+xTi5O12 is enabled by kinetic pathways comprising distorted Li polyhedra in metastable intermediates along two-phase boundaries. Our work demonstrates that high-rate capability may be enabled by accessing the energy landscape above the ground state, which may have fundamentally different kinetic mechanisms from the ground-state macroscopic phases. This insight should present new opportunities in searching for high-rate electrode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2020, "Volume": 367, "Issue": 6481, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1030, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax3520", "DOI Link": "http://dx.doi.org/10.1126/science.aax3520", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517979600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wright, LG; Onodera, T; Stein, MM; Wang, TY; Schachter, DT; Hu, Z; McMahon, PL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wright, Logan G.; Onodera, Tatsuhiro; Stein, Martin M.; Wang, Tianyu; Schachter, Darren T.; Hu, Zoey; McMahon, Peter L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep physical neural networks trained with backpropagation", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep-learning models have become pervasive tools in science and engineering. However, their energy requirements now increasingly limit their scalability(1). Deep-learning accelerators(2-9) aim to perform deep learning energy-efficiently, usually targeting the inference phase and often by exploiting physical substrates beyond conventional electronics. Approaches so far(10-22) have been unable to apply the backpropagation algorithm to train unconventional novel hardware in situ. The advantages of backpropagation have made it the de facto training method for large-scale neural networks, so this deficiency constitutes a major impediment. Here we introduce a hybrid in situ-in silico algorithm, called physics-aware training, that applies backpropagation to train controllable physical systems. Just as deep learning realizes computations with deep neural networks made from layers of mathematical functions, our approach allows us to train deep physical neural networks made from layers of controllable physical systems, even when the physical layers lack any mathematical isomorphism to conventional artificial neural network layers. To demonstrate the universality of our approach, we train diverse physical neural networks based on optics, mechanics and electronics to experimentally perform audio and image classification tasks. Physics-aware training combines the scalability of backpropagation with the automatic mitigation of imperfections and noise achievable with in situ algorithms. Physical neural networks have the potential to perform machine learning faster and more energy-efficiently than conventional electronic processors and, more broadly, can endow physical systems with automatically designed physical functionalities, for example, for robotics(23-26), materials(27-29) and smart sensors(30-32).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2022, "Volume": 601, "Issue": 7894, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 549, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04223-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04223-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749546400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leong, KW; Wang, YF; Ni, M; Pan, WD; Luo, SJ; Leung, DYC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leong, Kee Wah; Wang, Yifei; Ni, Meng; Pan, Wending; Luo, Shijing; Leung, Dennis Y. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rechargeable Zn-air batteries: Recent trends and future perspectives", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently a hot research topic, rechargeable zinc-air batteries are considered one of the most promising post lithium-ion battery technologies for utility-scale energy storage, electric vehicles, and other consumer electronics. Nevertheless, despite a high energy density, low cost, and material abundance, the development of alkaline-based Zn-air batteries has been hampered by parasitic reactions at the Zn anode and sluggish oxygen redox kinetics. This article will review the current status of Zn-air batteries, discuss recent development trends including neutral and hybrid Zn-air batteries, and highlight future research needs. Specifically, an analysis of the latest publications will show that, through redesigning the anode, introducing alternative electrolytes, and engineering high-performing bifunctional oxygen catalysts, researchers have successfully prolonged the battery reversibility to a few thousand cycles and reached unprecedented energy efficiencies over 70%. Although unsolved obstacles remain, these strategies have opened up interesting possibilities in the advancement of rechargeable Zn-air batteries, creating promising prospects for the energy and electronics industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 154, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111771, "DOI": "10.1016/j.rser.2021.111771", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2021.111771", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714449500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MX; Wang, HY; Zhu, WD; Li, WM; Wang, C; Lu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Meixuan; Wang, Huiyuan; Zhu, Wendong; Li, Weimo; Wang, Ce; Lu, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RuNi nulloparticles Embedded in N-Doped Carbon nullofibers as a Robust Bifunctional Catalyst for Efficient Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance, low-cost, and robust bifunctional electrocatalysts for overall water splitting is extremely indispensable and challenging. It is a promising strategy to couple highly active precious metals with transition metals as efficient electrocatalysts, which can not only effectively reduce the cost of the preparation procedure, but also greatly improve the performance of catalysts through a synergistic effect. Herein, Ru and Ni nulloparticles embedded within nitrogen-doped carbon nullofibers (RuNi-NCNFs) are synthesized via a simple electrospinning technology with a subsequent carbonization process. The as-formed RuNi-NCNFs represent excellent Pt-like electrocatalytic activity for the hydrogen evolution reaction (HER) in both alkaline and acidic conditions. Furthermore, the RuNi-NCNFs also exhibit an outstanding oxygen evolution reaction (OER) activity with an overpotential of 290 mV to achieve a current density of 10 mA cm(-2) in alkaline electrolyte. Strikingly, owing to both the HER and OER performance, an electrolyzer with RuNi-NCNFs as both the anode and cathode catalysts requires only a cell voltage of 1.564 V to drive a current density of 10 mA cm(-2) in an alkaline medium, which is lower than the benchmark of Pt/C||RuO2 electrodes. This study opens a novel avenue toward the exploration of high efficient but low-cost electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901833, "DOI": "10.1002/advs.201901833", "DOI Link": "http://dx.doi.org/10.1002/advs.201901833", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496829800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, P; Wu, P; Gao, CD; Yang, YW; Guo, W; Yang, WJ; Shuai, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Pei; Wu, Ping; Gao, Chengde; Yang, Youwen; Guo, Wang; Yang, Wenjing; Shuai, Cijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Multimaterial Scaffold With Tunable Properties: Toward Bone Tissue Repair", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyetheretherketone (PEEK)/-tricalcium phosphate (-TCP) scaffolds are expected to be able to combine the excellent mechanical strength of PEEK and the good bioactivity and biodegradability of -TCP. While PEEK acts as a closed membrane in which -TCP is completely wrapped after the melting/solidifying processing, the PEEK membrane degrades very little, hence the scaffolds cannot display bioactivity and biodegradability. The strategy reported here is to blend a biodegradable polymer with PEEK and -TCP to fabricate multi-material scaffolds via selective laser sintering (SLS). The biodegradable polymer first degrades and leaves caverns on the closed membrane, and then the wrapped -TCP is exposed to body fluid. In this study, poly(l-lactide) (PLLA) is adopted as the biodegradable polymer. The results show that large numbers of caverns form on the membrane with the degradation of PLLA, enabling direct contact between -TCP and body fluid, and allowing for their ion-exchange. As a consequence, the scaffolds display the bioactivity, biodegradability and cytocompatibility. Moreover, bone defect repair studies reveal that new bone tissues grow from the margin towards the center of the scaffolds from the histological analysis. The bone defect region is completely connected to the host bone end after 8 weeks of implantation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700817, "DOI": "10.1002/advs.201700817", "DOI Link": "http://dx.doi.org/10.1002/advs.201700817", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435765900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Shu, RW; Wan, ZL; Shi, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jing; Shu, Ruiwen; Wan, Zongli; Shi, Jianjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of three-dimensional hierarchical porous nitrogen-doped reduced graphene oxide/hollow cobalt ferrite composite aerogels toward highly efficient electromagnetic wave absorption", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of graphene-based composites with low density, robust absorption, wide bandwidth and thin thickness remained a great challenge in the field of electromagnetic (EM) absorption. In this work, nitrogen-doped reduced graphene oxide/hollow cobalt ferrite (NRGO/hollow CoFe2O4) composite aerogels were constructed by a solvothermal and hydrothermal two-step route. Results demonstrated that the as-fabricated composite aerogels had the ultralow density and a unique three-dimensional (3D) network structure, and lots of hollow CoFe2O4 microspheres were almost homogeneously distributed on the wrinkled surfaces of lamellar NRGO. Moreover, superior EM absorbing capacity could be achieved by modulating the ferrite structure, addition amounts of hollow CoFe2O4 and thicknesses. It was noteworthy that the NRGO/hollow CoFe2O4 composite aerogel with the addition amount of ferrite of 15.0 mg possessed the minimum reflection loss of -44.7 dB and maximum absorption bandwidth of 5.2 GHz (from 12.6 to 17.8 GHz) at a very thin thickness of 1.8 mm and filling ratio of 15.0 wt.%. Furthermore, the possible EM attenuation mechanism had been proposed. The results of this work would be helpful for developing RGO-based 3D composites as lightweight, thin and highly efficient EM wave absorbers. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2023, "Volume": 132, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": 200, "Article Number": null, "DOI": "10.1016/j.jmst.2022.05.050", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2022.05.050", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826888900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JJ; Yuk, H; Sarrafian, TL; Guo, CF; Griffiths, LG; Nabzdyk, CS; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jingjing; Yuk, Hyunwoo; Sarrafian, Tiffany L.; Guo, Chuan Fei; Griffiths, Leigh G.; Nabzdyk, Christoph S.; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An off-the-shelf bioadhesive patch for sutureless repair of gastrointestinal defects", "Source Title": "SCIENCE TRANSLATIONAL MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surgical sealing and repair of injured and resected gastrointestinal (GI) organs are critical requirements for successful treatment and tissue healing. Despite being the standard of care, hand-sewn closure of GI defects using sutures faces limitations and challenges. In this work, we introduce an off-the-shelf bioadhesive GI patch capable of atraumatic, rapid, robust, and sutureless repair of GI defects. The GI patch integrates a nonadhesive top layer and a dry, bioadhesive bottom layer, resulting in a thin, flexible, transparent, and ready-to-use patch with tissue-matching mechanical properties. The rapid, robust, and sutureless sealing capability of the GI patch is systematically characterized using ex vivo porcine GI organ models. In vitro and in vivo rat models are used to evaluate the biocompatibility and degradability of the GI patch in comparison to commercially available tissue adhesives (Coseal and Histoacryl). To validate the GI patch's efficacy, we demonstrate successful sutureless in vivo sealing and healing of GI defects in rat colon, stomach, and small intestine as well as in porcine colon injury models. The proposed GI patch provides a promising alternative to suture for repair of GI defects and offers potential clinical opportunities for the repair of other organs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2022, "Volume": 14, "Issue": 630, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabh2857", "DOI": "10.1126/scitranslmed.abh2857", "DOI Link": "http://dx.doi.org/10.1126/scitranslmed.abh2857", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750219600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, ZX; Shen, H; Chen, Z; Yang, YY; Yang, C; Ji, YL; Wang, YH; Zhu, C; Liu, JL; Li, J; Sham, TK; Xu, X; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Zhengxiang; Shen, Hao; Chen, Zheng; Yang, Yaoyue; Yang, Chao; Ji, Yali; Wang, Yuhang; Zhu, Chan; Liu, Junlang; Li, Jun; Sham, Tsun-Kong; Xu, Xin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Electrocatalytic CO2 Reduction to C2+ Alcohols at Defect-Site-Rich Cu Surface", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction is a promising approach for upgrading excessive CO2 into value-added chemicals, while the exquisite control of the catalyst atomic structures to obtain high C2+ alcohol selectivity has remained challenging due to the intrinsically favored ethylene pathways at Cu surface. Herein, we demonstrate a rational strategy to achieve similar to 70% faradaic efficiency toward C2+ alcohols. We utilized a CO-rich environment to construct Cu catalysts with stepped sites that enabled high surface coverages of *CO intermediates and the bridge-bound *CO adsorption, which allowed to trigger CO2 reduction pathways toward the formation alcohols. Using this defect-site-rich Cu catalyst, we achieved C2+ alcohols with partial current densities of > 100 mA.cm(-2) in both a flow-cell electrolyzer and a membrane electrode assembly (MEA) electrolyzer. A stable alcohol faradaic efficiency of similar to 60% was also obtained, with similar to 500 mg C2+ alcohol production per cm(2) catalyst during a continuous 30-h operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 429, "End Page": 440, "Article Number": null, "DOI": "10.1016/j.joule.2020.12.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.12.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629204800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bag, M; Renna, LA; Adhikari, RY; Karak, S; Liu, F; Lahti, PM; Russell, TP; Tuominen, MT; Venkataraman, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bag, Monojit; Renna, Lawrence A.; Adhikari, Ramesh Y.; Karak, Supravat; Liu, Feng; Lahti, Paul M.; Russell, Thomas P.; Tuominen, Mark T.; Venkataraman, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar cells fabricated using alkyl ammonium metal halides as light absorbers have the right combination of high power conversion efficiency and ease of fabrication to realize inexpensive but efficient thin film solar cells. However, they degrade under prolonged exposure to sunlight. Herein, we show that this degradation is quasi-reversible, and that it can be greatly lessened by simple modifications of the solar cell operating conditions. We studied perovskite devices using electrochemical impedance spectroscopy (EIS) with methylammonium (MA)-, formamidinium (FA)-, and MA(x)FA(1-x) lead triiodide as active layers. From variable temperature EIS studies, we found that the diffusion coefficient using MA ions was greater than when using FA ions. Structural studies using powder X-ray diffraction (PXRD) show that for MAPbI(3) a structural change and lattice expansion occurs at device operating temperatures. On the basis of EIS and PXRD studies, we postulate that in MAPbI(3) the predominullt mechanism of accelerated device degradation under sunlight involves thermally activated fast ion transport coupled with a lattice-expanding phase transition, both of which are facilitated by absorption of the infrared component of the solar spectrum. Using these findings, we show that the devices show greatly improved operation lifetimes and stability under white-light emitting diodes, or under a solar simulator with an infrared cutoff filter or with cooling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2015, "Volume": 137, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13130, "End Page": 13137, "Article Number": null, "DOI": "10.1021/jacs.5b08535", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b08535", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363002900057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, T; Zhang, MY; Zeng, QK; Pan, WH; Huang, YJ; Qian, YN; Dong, W; Qi, XL; Shen, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Ting; Zhang, Mengying; Zeng, Qiankun; Pan, Wenhao; Huang, Yijing; Qian, Yuna; Dong, Wei; Qi, Xiaoliang; Shen, Jianliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mussel-inspired agarose hydrogel scaffolds for skin tissue engineering", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polysaccharide hydrogels are widely used in tissue engineering because of their superior biocompatibility and low immunogenicity. However, many of these hydrogels are unrealistic for practical applications as the cost of raw materials is high, and the fabrication steps are tedious. This study focuses on the facile fabrication and optimization of agarose-polydopamine hydrogel (APG) scaffolds for skin wound healing. The first study objective was to evaluate the effects of polydopamine (PDA) on the mechanical properties, water holding capacity and cell adhesiveness of APG. We observed that APG showed decreased rigidity and increased water content with the addition of PDA. Most importantly, decreased rigidity translated into significant increase in cell adhesiveness. Next, the slow biodegradability and high biocompatibility of APG with the highest PDA content (APG3) was confirmed. In addition, APG3 promoted full-thickness skin defect healing by accelerating collagen deposition and promoting angiogenesis. Altogether, we have developed a straightforward and efficient strategy to construct functional APG scaffold for skin tissue engineering, which has translation potentials in clinical practice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 579, "End Page": 588, "Article Number": null, "DOI": "10.1016/j.bioactmat.2020.09.004", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2020.09.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000606983400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, YQ; Chattopadhyay, U; Zhu, BF; Qiang, B; Li, JH; Jin, YH; Li, LH; Davies, AG; Linfield, EH; Zhang, BL; Chong, YD; Wang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Yongquan; Chattopadhyay, Udvas; Zhu, Bofeng; Qiang, Bo; Li, Jinghao; Jin, Yuhao; Li, Lianhe; Davies, Alexander Giles; Linfield, Edmund Harold; Zhang, Baile; Chong, Yidong; Wang, Qi Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically pumped topological laser with valley edge modes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum cascade lasers are compact, electrically pumped light sources in the technologically important mid-infrared and terahertz region of the electromagnetic spectrum(1,2). Recently, the concept of topology(3) has been expanded from condensed matter physics into photonics(4), giving rise to a new type of lasing(5-8) using topologically protected photonic modes that can efficiently bypass corners and defects(4). Previous demonstrations of topological lasers have required an external laser source for optical pumping and have operated in the conventional optical frequency regime(5-8). Here we demonstrate an electrically pumped terahertz quantum cascade laser based on topologically protected valley edge states(9-11). Unlike topological lasers that rely on large-scale features to impart topological protection, our compact design makes use of the valley degree of freedom in photonic crystals(10,11), analogous to two-dimensional gapped valleytronic materials(12). Lasing with regularly spaced emission peaks occurs in a sharp-cornered triangular cavity, even if perturbations are introduced into the underlying structure, owing to the existence of topologically protected valley edge states that circulate around the cavity without experiencing localization. We probe the properties of the topological lasing modes by adding different outcouplers to the topological cavity. The laser based on valley edge states may open routes to the practical use of topological protection in electrically driven laser sources.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 578, "Issue": 7794, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 246, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-1981-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-1981-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513110500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, HH; Zhang, PP; Liu, ZC; Park, S; Lohe, MR; Wu, YP; Nia, AS; Yang, S; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Huanhuan; Zhang, Panpan; Liu, Zaichun; Park, SangWook; Lohe, Martin R.; Wu, Yuping; Shaygan Nia, Ali; Yang, Sheng; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambient-Stable Two-Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene (e.g., Ti3C2) represents an important class of two-dimensional (2D) materials owing to its unique metallic conductivity and tunable surface chemistry. However, the mainstream synthetic methods rely on the chemical etching of MAX powders (e.g., Ti3AlC2) using hazardous HF or alike, leading to MXene sheets with fluorine termination and poor ambient stability in colloidal dispersions. Here, we demonstrate a fluoride-free, iodine (I-2) assisted etching route for preparing 2D MXene (Ti3C2Tx, T=O, OH) with oxygen-rich terminal groups and intact lattice structure. More than 71 % of sheets are thinner than 5 nm with an average size of 1.8 mu m. They present excellent thin-film conductivity of 1250 S cm(-1) and great ambient stability in water for at least 2 weeks. 2D MXene sheets with abundant oxygen surface groups are excellent electrode materials for supercapacitors, delivering a high gravimetric capacitance of 293 F g(-1) at a scan rate of 1 mV s(-1), superior to those made from fluoride-based etchants (<290 F g(-1) at 1 mV s(-1)). Our strategy provides a promising pathway for the facile and sustainable production of highly stable MXene materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2021, "Volume": 60, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8689, "End Page": 8693, "Article Number": null, "DOI": "10.1002/anie.202015627", "DOI Link": "http://dx.doi.org/10.1002/anie.202015627", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626961700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, ZL; Jin, MK; Ye, X; Wang, S; Shi, T; Deng, JH; Mao, NB; Cao, YY; Guan, BO; Alu, A; Li, GX; Li, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Zi-Lan; Jin, Mingke; Ye, Xuan; Wang, Shuai; Shi, Tan; Deng, Junhong; Mao, Ningbin; Cao, Yaoyu; Guan, Bai-Ou; Alu, Andrea; Li, Guixin; Li, Xiangping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-Color Complex-Amplitude Vectorial Holograms Based on Multi-Freedom Metasurfaces", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase, polarization, amplitude, and frequency represent the basic dimensions of light, playing crucial roles for both fundamental light-material interactions and all major optical applications. Metasurfaces have emerged as a compact platform to manipulate these knobs, but previous metasurfaces have limited flexibility to simultaneous control them. A multi-freedom metasurface that can simultaneously and independently modulate phase, polarization, and amplitude in an analytical form is introduced, and frequency multiplexing is further realized by a k-space engineering technique. The multi-freedom metasurface seamlessly combines geometric Pancharatnam-Berry phase and detour phase, both of which are frequency independent. As a result, it allows complex-amplitude vectorial hologram at various frequencies based on the same design strategy, without sophisticated nullostructure searching of massive geometric parameters. Based on this principle, full-color complex-amplitude vectorial meta-holograms in the visible are experimentally demonstrated with a metal-insulator-metal architecture, unlocking the long-sought full potential of advanced light field manipulation through ultrathin metasurfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 30, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1910610, "DOI": "10.1002/adfm.201910610", "DOI Link": "http://dx.doi.org/10.1002/adfm.201910610", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536858100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, JH; Wang, ZM; Ren, ZW; Li, SY; Chen, XY; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Jinhui; Wang, Ziming; Ren, Zewei; Li, Shuyao; Chen, Xiangyu; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Power generation from the interaction of a liquid droplet and a liquid membrane", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerators are an energy harvesting technology that relies on the coupling effects of contact electrification and electrostatic induction between two solids or a liquid and a solid. Here, we present a triboelectric nullogenerator that can work based on the interaction between two pure liquids. A liquid-liquid triboelectric nullogenerator is achieved by passing a liquid droplet through a freely suspended liquid membrane. We investigate two kinds of liquid membranes: a grounded membrane and a pre-charged membrane. The falling of a droplet (about 40 mu L) can generate a peak power of 137.4 nW by passing through a pre-charged membrane. Moreover, this membrane electrode can also remove and collect electrostatic charges from solid objects, indicating a permeable sensor or charge filter for electronic applications. The liquid-liquid triboelectric nullogenerator can harvest mechanical energy without changing the object motion and it can work for many targets, including raindrops, irrigation currents, microfluidics, and tiny particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2264, "DOI": "10.1038/s41467-019-10232-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10232-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468603500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Gao, XJJ; Qin, L; Wang, CD; Song, L; Zhou, YN; Zhu, GY; Cao, W; Lin, SC; Zhou, LQ; Wang, K; Zhang, HG; Jin, Z; Wang, P; Gao, XF; Wei, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoyu; Gao, Xuejiao J.; Qin, Li; Wang, Changda; Song, Li; Zhou, Yong-Ning; Zhu, Guoyin; Cao, Wen; Lin, Shichao; Zhou, Liqi; Wang, Kang; Zhang, Huigang; Jin, Zhong; Wang, Peng; Gao, Xingfa; Wei, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "eg occupancy as an effective descriptor for the catalytic activity of perovskite oxide-based peroxidase mimics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A peroxidase catalyzes the oxidation of a substrate with a peroxide. The search for peroxidase-like and other enzyme-like nullomaterials (called nullozymes) mainly relies on trial-and-error strategies, due to the lack of predictive descriptors. To fill this gap, here we investigate the occupancy of e(g) orbitals as a possible descriptor for the peroxidase-like activity of transition metal oxide (including perovskite oxide) nullozymes. Both experimental measurements and density functional theory calculations reveal a volcano relationship between the e(g) occupancy and nullozymes' activity, with the highest peroxidase-like activities corresponding to e(g) occupancies of similar to 1.2. LaNiO3-delta, optimized based on the e(g) occupancy, exhibits an activity one to two orders of magnitude higher than that of other representative peroxidase-like nullozymes. This study shows that the e(g) occupancy is a predictive descriptor to guide the design of peroxidase-like nullozymes; in addition, it provides detailed insight into the catalytic mechanism of peroxidase-like nullozymes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 704, "DOI": "10.1038/s41467-019-08657-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08657-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458297200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ross, MB; Mirkin, CA; Schatz, GC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ross, Michael B.; Mirkin, Chad A.; Schatz, George C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical Properties of One-, Two-, and Three-Dimensional Arrays of Plasmonic nullostructures", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This Feature Article describes research on the optical properties of arrays of silver and gold nulloparticles, particles that exhibit localized surface plasmon resonullces in the visible and near-infrared. These resonullces lead to strong absorption and scattering of light that is strongly dependent on nulloparticle size and shape. When arranged into multidimensional arrays, the nulloparticles strongly interact such that the collective properties can be rationally designed by changing the dimensions of the array (one-, two-, or three-dimensional), interparticle spacing, and array shape or morphology. Emerging from this work is a large body of literature focusing on one-, two-, and three-dimensional arrays, which provide unique opportunities for realizing materials with interesting and unusual photonic and metamaterial properties. Electrodynamics theory provides an accurate description of the optical properties, often based on simple models such as coupled dipoles, effective medium theory, and anomalous diffraction. In turn, simple models and simulation methods allow for the prediction and explanation of a variety of observed optical properties. In one and two dimensions, these tunable optical properties range from extinction spectra that are red- or blue-shifted compared to the isolated particles to lattice plasmon modes that involve strong interactions between localized plasmon resonullces in the nulloparticles and photonic modes that derive from Bragg diffraction in the crystalline array. Three-dimensional arrays can exhibit unique effective medium properties, such as negative permittivity that leads to metallic optical response even when there is less than 1% metal content in the array. They also can be rationally designed to have photonic scattering modes dictated and controlled by interactions between nulloscale plasmonic nulloparticles and the mesoscale superlattice crystal habit (i.e., the crystalline size, shape, and morphology). This discussion of plasmonic arrays across multiple dimensions provides a comprehensive description of those factors that can be easily tuned for the design of plasmon-based optical materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2016, "Volume": 120, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 816, "End Page": 830, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b10800", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b10800", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368754700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Luan, JY; Huang, XB; Wang, Q; Sun, D; Tang, YG; Ji, XB; Wang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qi; Luan, Jingyi; Huang, Xiaobing; Wang, Qi; Sun, Dan; Tang, Yougen; Ji, Xiaobo; Wang, Haiyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the role of crystal orientation of protective layers for stable zinc anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries are a promising candidate for next-generation energy storage devices. However, their practical application is limited by the severe safety issue caused by uncontrollable dendrite growth on zinc anodes. Here we develop faceted titanium dioxide with relatively low zinc affinity, which can restrict dendrite formation and homogenize zinc deposition when served as the protective layer on zinc anodes. The as-prepared zinc anodes can be stripped and plated steadily for more than 460h with low voltage hysteresis and flat voltage plateau in symmetric cells. This work reveals the key role of crystal orientation in zinc affinity and its internal mechanism is suitable for various crystal materials applied in the surface modification of other metal anodes such as lithium and sodium. Zinc affinity plays a key role in the zinc plating and stripping processes but its internal mechanism is still unclear. Here, the authors report a protective layer with controllable zinc affinity by adjusting the crystal orientation to suppress the dendrite growth on the zinc anode interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 509, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3961, "DOI": "10.1038/s41467-020-17752-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17752-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561098400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, FY; Lang, ZL; Yin, LY; Feng, K; Xia, YJ; Tan, HQ; Zhu, HT; Zhong, J; Kang, ZH; Li, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fei-Yang; Lang, Zhong-Ling; Yin, Li-Ying; Feng, Kun; Xia, Yu-Jian; Tan, Hua-Qiao; Zhu, Hao-Tian; Zhong, Jun; Kang, Zhen-Hui; Li, Yang-Guang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pt-O bond as an active site superior to Pt0 in hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxidized platinum (Pt) can exhibit better electrocatalytic activity than metallic Pt-0 in the hydrogen evolution reaction (HER), which has aroused great interest in exploring the role of oxygen in Pt-based catalysts. Herein, we select two structurally well-defined polyoxometalates Na-5[(H3PtW6O24)-W-(IV)] (PtW6O24) and Na3K5[Pt-2((II))(W5O18)(2)] (Pt-2(W5O18)(2)) as the platinum oxide model to investigate the HER performance. Electrocatalytic experiments show the mass activities of PtW6O24/C and Pt-2(W5O18)(2)/C are 20.175Amg(-1) and 10.976Amg(-1) at 77mV, respectively, which are better than that of commercial 20% Pt/C (0.398Amg(-1)). The in situ synchrotron radiation experiments and DFT calculations suggest that the elongated Pt-O bond acts as the active site during the HER process, which can accelerate the coupling of proton and electron and the rapid release of H-2. This work complements the knowledge boundary of Pt-based electrocatalytic HER, and suggests another way to update the state-of-the-art electrocatalyst. While converting water to H-2 with a catalyst offers a renewable means to produce carbon-neutral fuels, understanding the catalytic active sites has proven challenging. Here, authors show a structurally well-defined model complex with Pt-O bonding to enable efficient H-2 evolution electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 490, "DOI": "10.1038/s41467-019-14274-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14274-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543967000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, F; Wang, Q; Xu, GL; Qin, XP; Hwang, IH; Sun, CJ; Liu, M; Hua, W; Wu, HW; Zhu, SQ; Li, JC; Wang, JG; Zhu, YM; Wu, DJ; Wei, ZD; Gu, M; Amine, K; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Fei; Wang, Qi; Xu, Gui-Liang; Qin, Xueping; Hwang, Inhui; Sun, Cheng-Jun; Liu, Min; Hua, Wei; Wu, Hsi-wen; Zhu, Shangqian; Li, Jin-Cheng; Wang, Jian-Gan; Zhu, Yuanmin; Wu, Duojie; Wei, Zidong; Gu, Meng; Amine, Khalil; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed Pt and Fe sites and Pt-Fe nulloparticles for durable proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton exchange membrane fuel cells convert hydrogen and oxygen into electricity without emissions. The high cost and low durability of Pt-based electrocatalysts for the oxygen reduction reaction hinder their wide application, and the development of non-precious metal electrocatalysts is limited by their low performance. Here we design a hybrid electrocatalyst that consists of atomically dispersed Pt and Fe single atoms and Pt-Fe alloy nulloparticles. Its Pt mass activity is 3.7 times higher than that of commercial Pt/C in a fuel cell. More importantly, the fuel cell with a low Pt loading in the cathode (0.015 mg(P)(t) cm(-2)) shows an excellent durability, with a 97% activity retention after 100,000 cycles and no noticeable current drop at 0.6V for over 200 hours. These results highlight the importance of the synergistic effects among active sites in hybrid electrocatalysts and provide an alternative way to design more active and durable low-Pt electrocatalysts for electrochemical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 503, "End Page": 512, "Article Number": null, "DOI": "10.1038/s41929-022-00796-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00796-1", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805042200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, Q; Li, DG; Li, QT; Cao, XD; Dong, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Qi; Li, Dingguo; Li, Qingtao; Cao, Xiaodong; Dong, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microgel assembly: Fabrication, characteristics and application in tissue engineering and regenerative medicine", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microgel assembly, a macroscopic aggregate formed by bottom-up assembly of micmgels, is now emerging as prospective biomaterials for applications in tissue engineering and regenerative medicine (TERM). This minireview first summarizes the fabrication strategies available for microgel assembly, including chemical reaction, physical reaction, cell-cell interaction and external driving force, then highlights its unique characteristics, such as microporosity, injectability and heterogeneity, and finally itemizes its applications in the fields of cell culture, tissue regeneration and biofabrication, especially 3D printing. The problems to be addressed for further applications of microgel assembly are also discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 105, "End Page": 119, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.07.020", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.07.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000736276600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, M; Zhang, LM; Zhao, XR; Wu, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Ming; Zhang, Limin; Zhao, Xiaoru; Wu, Hongjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect Induced Polarization Loss in Multi-Shelled Spinel Hollow Spheres for Electromagnetic Wave Absorption Application", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defect engineering is an effective approach to manipulate electromagnetic (EM) parameters and enhance absorption ability, but defect induced dielectric loss dominullt mechanism has not been completely clarified. Here the defect induced dielectric loss dominullt mechanism in virtue of multi-shelled spinel hollow sphere for the first time is demonstrated. The unique but identical morphology design as well as suitable composition modulation for serial spinels can exclude the disturbance of EM wave dissipation from dipolar/interfacial polarization and conduction loss. In temperature-regulated defect in NiCo2O4 serial materials, two kinds of defects, defect in spinel structure and oxygen vacancy are detected. Defect in spinel structure played more profound role on determining materials' EM wave dissipation than that of oxygen vacancy. When evaluated serial Co-based materials as absorbers, defect induced polarization loss is responsible for the superior absorption performance of NiCo2O4-based material due to its more defect sites in spinel structure. It is discovered that electron spin resonullce test may be adopted as a novel approach to directly probe EM wave absorption capacities of materials. This work not only provides a strategy to prepare lightweight, efficient EM wave absorber but also illustrates the importance of defect engineering on regulation of materials' dielectric loss capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004640, "DOI": "10.1002/advs.202004640", "DOI Link": "http://dx.doi.org/10.1002/advs.202004640", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615811800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, ZY; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Zhouyue; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly transparent and ultra-stretchable conductor with stable conductivity during large deformation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsically stretchable conductors have undergone rapid development in the past few years and a variety of strategies have been established to improve their electro-mechanical properties. However, ranging from electronically to ionically conductive materials, they are usually vulnerable either to large deformation or at high/low temperatures, mainly due to the fact that conductive domains are generally incompatible with neighboring elastic networks. This is a problem that is usually overlooked and remains challenging to address. Here, we introduce synergistic effect between conductive zwitterionic nullochannels and dynamic hydrogen-bonding networks to break the limitations. The conductor is highly transparent (>90% transmittance), ultra-stretchable (>10,000% strain), high-modulus (>2 MPa Young's modulus), self-healing, and capable of maintaining stable conductivity during large deformation and at different temperatures. Transparent integrated systems are further demonstrated via 3D printing of its precursor and could achieve diverse sensory capabilities towards strain, temperature, humidity, etc., and even recognition of different liquids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3429, "DOI": "10.1038/s41467-019-11364-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11364-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477952600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, H; Xiao, H; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Hyeyoung; Xiao, Hai; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Silico Discovery of New Dopants for Fe-Doped Ni Oxyhydroxide (N1-xFexOOH) Catalysts for Oxygen Evolution Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction (OER) is critical to efficient water splitting to produce the H-2 fuel for sustainable energy production. Currently, the best non noble metal OER electrocatalyst in base conditions is the Fe-doped NiOOH (N1-xFexOOH), with an overpotential of eta = 0.4, but much lower values are desired. We use density functional theory to determine the overall mechanism for the OER of N1-xFexOOH, concluding that promoting radical character on the metal-oxo bond is critical to efficient OER Then we consider replacing Fe with 17 other transition metals of the Fe, Ru, and Os rows, where we find 3 new promising candidates: Co, Rh, and Ir, which we estimate to have eta = 0.27, 0.15, and 0.02, respectively, all very much improved performance compared to Fe, making all three systems excellent candidates for experimental testing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2018, "Volume": 140, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6745, "End Page": 6748, "Article Number": null, "DOI": "10.1021/jacs.8b02225", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b02225", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434895200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, T; Yang, ZX; Gui, DX; Liu, ZY; Wang, XX; Dai, X; Liu, ST; Zhang, LJ; Gao, Y; Chen, LH; Sheng, DP; Wang, YL; Juan, DW; Wang, JQ; Zhou, RH; Chai, ZF; Albrecht-Schmitt, TE; Wang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Tao; Yang, Zaixing; Gui, Daxiang; Liu, Zhiyong; Wang, Xiangxiang; Dai, Xing; Liu, Shengtang; Zhang, Linjuan; Gao, Yang; Chen, Lanhua; Sheng, Daopeng; Wang, Yanlong; Juan Diwu; Wang, Jianqiang; Zhou, Ruhong; Chai, Zhifang; Albrecht-Schmitt, Thomas E.; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) based on zirconium phosphonates exhibit superior chemical stability suitable for applications under harsh conditions. These compounds mostly exist as poorly crystallized precipitates, and precise structural information has therefore remained elusive. Furthermore, a zero-dimensional zirconium phosphonate cluster acting as secondary building unit has been lacking, leading to poor designability in this system. Herein, we overcome these challenges and obtain single crystals of three zirconium phosphonates that are suitable for structural analysis. These compounds are built by previously unknown isolated zirconium phosphonate clusters and exhibit combined high porosity and ultrastability even in fuming acids. SZ-2 possesses the largest void volume recorded in zirconium phosphonates and SZ-3 represents the most porous crystalline zirconium phosphonate and the only porous MOF material reported to survive in aqua regia. SZ-2 and SZ-3 can effectively remove uranyl ions from aqueous solutions over a wide pH range, and we have elucidated the removal mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15369, "DOI": "10.1038/ncomms15369", "DOI Link": "http://dx.doi.org/10.1038/ncomms15369", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402303600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XY; Shi, J; Hao, YN; He, MT; Cai, JX; Qin, XH; Wang, LM; Yu, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xinyang; Shi, Jia; Hao, Yunna; He, Mantang; Cai, Jiaxin; Qin, Xiaohong; Wang, Liming; Yu, Jianyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stretchable, durable, and breathable thermoelectric fabrics for human body energy harvesting and sensing", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable thermoelectrics have recently attracted widespread attention in the field of self-powered wearable electronics due to their unique capability of harvesting body heat. However, it remains challenging to develop thermoelectric materials with excellent stretchability, durable thermoelectric properties, wearable comfort, and multifunctional sensing properties simultaneously. Herein, an advanced preparation strategy combining electrospinning and spraying technology is proposed to prepare carbon nullotube (CNT)/polyvinyl pyrrolidone (PVP)/polyurethane (PU) composite thermoelectric fabrics that have high air permeability and stretchability (similar to 250%) close to those of pure PU nullofiber fabrics. Furthermore, PVP can not only improve the dispersion of CNTs but also act as interfacial binders between the CNT and the elastic PU skeleton. Consequently, both the electrical conductivity and the Seebeck coefficient remain unchanged even after bending 1000 times. In addition, self-powered sensors for the mutual conversion of finger temperature and language and detection of the movement of joints to optimize an athletes movement state were successfully fabricated. This study paves the way for stretchable thermoelectric fabrics with fascinating applications in smart wearable fields such as power generation, health monitoring, and human-computer interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 621, "End Page": 632, "Article Number": null, "DOI": "10.1002/cey2.186", "DOI Link": "http://dx.doi.org/10.1002/cey2.186", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780012700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kosco, J; Gonzalez-Carrero, S; Howells, CT; Fei, T; Dong, YF; Sougrat, R; Harrison, GT; Firdaus, Y; Sheelamanthula, R; Purushothaman, B; Moruzzi, F; Xu, WD; Zhao, LY; Basu, A; De Wolf, S; Anthopoulos, TD; Durrant, JR; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kosco, Jan; Gonzalez-Carrero, Soranyel; Howells, Calvyn T.; Fei, Teng; Dong, Yifan; Sougrat, Rachid; Harrison, George T.; Firdaus, Yuliar; Sheelamanthula, Rajendar; Purushothaman, Balaji; Moruzzi, Floriana; Xu, Weidong; Zhao, Lingyun; Basu, Aniruddha; De Wolf, Stefaan; Anthopoulos, Thomas D.; Durrant, James R.; McCulloch, Iain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generation of long-lived charges in organic semiconductor heterojunction nulloparticles for efficient photocatalytic hydrogen evolution", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic semiconductor heterojunction photocatalysts are promising for synthesis of solar fuels yet a deeper understanding of their underlying photophysics is needed to improve performance. Here, the authors show that such materials can intrinsically generate remarkably long-lived reactive charges, enabling them to efficiently drive hydrogen evolution. Organic semiconductor photocatalysts for the production of solar fuels are attractive as they can be synthetically tuned to absorb visible light while simultaneously retaining suitable energy levels to drive a range of processes. However, a greater understanding of the photophysics that determines the function of organic semiconductor heterojunction nulloparticles is needed to optimize performance. Here, we show that such materials can intrinsically generate remarkably long-lived reactive charges, enabling them to efficiently drive sacrificial hydrogen evolution. Our optimized hetereojunction photocatalysts comprise the conjugated polymer PM6 matched with Y6 or PCBM electron acceptors, and achieve external quantum efficiencies of 1.0% to 5.0% at 400 to 900 nm and 8.7% to 2.6% at 400 to 700 nm, respectively. Employing transient and operando spectroscopies, we find that the heterojunction structure in these nulloparticles greatly enhances the generation of long-lived charges (millisecond to second timescale) even in the absence of electron/hole scavengers or Pt. Such long-lived reactive charges open potential applications in water-splitting Z-schemes and in driving kinetically slow and technologically desirable oxidations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 340, "End Page": 351, "Article Number": null, "DOI": "10.1038/s41560-022-00990-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-00990-2", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768620500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ke, W; Oliveira, JP; Cong, B; Ao, S; Qi, Z; Peng, B; Zeng, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ke, W. C.; Oliveira, J. P.; Cong, B. Q.; Ao, S. S.; Qi, Z. W.; Peng, B.; Zeng, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-layer deposition mechanism in ultra high-frequency pulsed wire arc additive manufacturing (WAAM) of NiTi shape memory alloys", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra high-frequency pulsed gas tungsten arc welding (UHFP-GTAW)-based Wire Arc Additive Manufacturing (WAAM) was used to fabricate thin walls of NiTi shape memory alloys. The transient heat and fluid flow are critical during fusion-based additive manufacturing, since they impact the as-built microstructure. In this work, a three-dimensional numerical model, which includes the force, surface Gauss heat source and periodic droplet transfer models, was developed to simulate the deposition of 5 layers. The gravity, buoyancy, electromagnetic, surface tension, arc pressure and arc shear stress are considered in the developed force model. An improved free surface tracing method using the volume of fluid (VOF) technique was proposed to more effectively track the free surface of the molten pool with the computational fluid dynamics (CFD) software FLUENT. The multiphysics phenomena associated to the process, namely the temperature and velocity fields of the molten pool, were studied. The model was then validated by experiments. It is revealed that the microstructure of the as-built parts is refined by the UHFP current power which induces significant vibration of the molten pool. These findings lay the foundations for optimizing the WAAM process aiming at fabricating high quality and complex NiTi parts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102513, "DOI": "10.1016/j.addma.2021.102513", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.102513", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752143000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, RR; Kolb, MJ; Halck, NB; Pedersen, AF; Mehta, A; You, H; Stoerzinger, KA; Feng, ZX; Hansen, HA; Zhou, H; Giordano, L; Rossmeisl, J; Vegge, T; Chorkendorff, I; Stephens, IEL; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Reshma R.; Kolb, Manuel J.; Halck, Niels Bendtsen; Pedersen, Anders Filsoe; Mehta, Apurva; You, Hoydoo; Stoerzinger, Kelsey A.; Feng, Zhenxing; Hansen, Heine A.; Zhou, Hua; Giordano, Livia; Rossmeisl, Jan; Vegge, Tejs; Chorkendorff, Ib; Stephens, Ifan E. L.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards identifying the active sites on RuO2(110) in catalyzing oxygen evolution", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the surface atomic structure of RuO2 has been well studied in ultra high vacuum, much less is known about the interaction between water and RuO2 in aqueous solution. In this work, in situ surface X-ray scattering measurements combined with density functional theory (DFT) were used to determine the surface structural changes on single-crystal RuO2(110) as a function of potential in acidic electrolyte. The redox peaks at 0.7, 1.1 and 1.4 V vs. reversible hydrogen electrode (RHE) could be attributed to surface transitions associated with the successive deprotonation of -H2O on the coordinatively unsaturated Ru sites (CUS) and hydrogen adsorbed to the bridging oxygen sites. At potentials relevant to the oxygen evolution reaction (OER), an -OO species on the Ru CUS sites was detected, which was stabilized by a neighboring -OH group on the Ru CUS or bridge site. Combining potential-dependent surface structures with their energetics from DFT led to a new OER pathway, where the deprotonation of the -OH group used to stabilize -OO was found to be rate-limiting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 10, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2626, "End Page": 2637, "Article Number": null, "DOI": "10.1039/c7ee02307c", "DOI Link": "http://dx.doi.org/10.1039/c7ee02307c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417255900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elia, GA; Kravchyk, KV; Kovalenko, MV; Chacón, J; Holland, A; Wills, RGA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elia, Giuseppe Antonio; Kravchyk, Kostiantyn V.; Kovalenko, Maksym V.; Chacon, Joaquin; Holland, Alex; Wills, Richard G. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An overview and prospective on Al and Al-ion battery technologies", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aluminum batteries are considered compelling electrochemical energy storage systems because of the natural abundance of aluminum, the high charge storage capacity of aluminum of 2980 mA h g 1/8046 mA h cm(-3), and the sufficiently low redox potential of Al3+/Al. Several electrochemical storage technologies based on aluminum have been proposed so far. This review classifies the types of reported Al-batteries into two main groups: aqueous (Al-ion, and Al-air) and non-aqueous (aluminum graphite dual-ion, Al-organic dual-ion, Al-ion, and Al-sulfur). Specific focus is given to Al electrolyte chemistry based on chloroaluminate melts, deep eutectic solvents, polymers, and chlorine-free formulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 481, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 228870, "DOI": "10.1016/j.jpowsour.2020.228870", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2020.228870", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000593860100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MZ; Zhu, WQ; Huo, PC; Feng, L; Song, MW; Zhang, C; Chen, L; Lezec, HJ; Lu, YQ; Agrawal, A; Xu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingze; Zhu, Wenqi; Huo, Pengcheng; Feng, Lei; Song, Maowen; Zhang, Cheng; Chen, Lu; Lezec, Henri J.; Lu, Yanqing; Agrawal, Amit; Xu, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional metasurfaces enabled by simultaneous and independent control of phase and amplitude for orthogonal polarization states", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monochromatic light can be characterized by its three fundamental properties: amplitude, phase, and polarization. In this work, we propose a versatile, transmission-mode all-dielectric metasurface platform that can independently manipulate the phase and amplitude for two orthogonal states of polarization in the visible frequency range. For proof-of-concept experimental demonstration, various single-layer metasurfaces composed of subwavelength-spaced titanium-dioxide nullopillars are designed, fabricated, and characterized to exhibit the ability of polarization-switchable multidimensional light-field manipulation, including polarization-switchable grayscale nulloprinting, nonuniform cylindrical lensing, and complex-amplitude holography. We envision the metasurface platform demonstrated here to open new possibilities toward creating compact multifunctional optical devices for applications in polarization optics, information encoding, optical data storage, and security.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107, "DOI": "10.1038/s41377-021-00552-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00552-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657801100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, K; Dismukes, AH; Telford, EJ; Wiscons, RA; Wang, J; Xu, XD; Nuckolls, C; Dean, CR; Roy, X; Zhu, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Kihong; Dismukes, Avalon H.; Telford, Evan J.; Wiscons, Ren A.; Wang, Jue; Xu, Xiaodong; Nuckolls, Colin; Dean, Cory R.; Roy, Xavier; Zhu, Xiaoyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic Order and Symmetry in the 2D Semiconductor CrSBr", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of two-dimensional (2D) magnets offers unprecedented control over electrons and spins. A key factor in determining exchange coupling and magnetic order is symmetry. Here, we apply second harmonic generation (SHG) to probe a 2D magnetic semiconductor CrSBr. We find that monolayers are ferromagnetically ordered below 146 K, an observation enabled by the discovery of a large magnetic dipole SHG effect in the centrosymmetric structure. In multilayers, the ferromagnetic monolayers are coupled antiferromagnetically, and in contrast to other 2D magnets, the Neel temperature of CrSBr increases with decreasing layer number. We identify magnetic dipole and magnetic toroidal moments as order parameters of the ferromagnetic monolayer and antiferromagnetic bilayer, respectively. These findings establish CrSBr as an exciting 2D magnetic semiconductor and extend the SHG probe of magnetic symmetry to the monolayer limit, opening the door to exploring the applications of magnetic-electronic coupling and the magnetic toroidal moment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2021, "Volume": 21, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3511, "End Page": 3517, "Article Number": null, "DOI": "10.1021/acs.nullolett.1c00219", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.1c00219", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645560000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XH; Meng, FQ; Zhang, QH; Xue, L; Zhu, H; Lan, S; Liu, Q; Zhao, J; Zhuang, YH; Guo, QB; Liu, B; Gu, L; Lu, X; Ren, Y; Xia, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xiaohui; Meng, Fanqi; Zhang, Qinghua; Xue, Liang; Zhu, He; Lan, Si; Liu, Qi; Zhao, Jing; Zhuang, Yuhang; Guo, Qiubo; Liu, Bo; Gu, Lin; Lu, Xia; Ren, Yang; Xia, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LiMnO2 cathode stabilized by interfacial orbital ordering for sustainable lithium-ion batteries", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Global lithium-ion battery deployments stand poised to grow substantially in the coming years, but it will be necessary to include sustainability considerations in the design of electrode materials. The current cathode chemistry relies heavily on cobalt, which, due to its scarcity and the environmental abuse and violation of human rights during its mining, must be replaced by abundant and environmentally friendly elements such as redox-active manganese. LiMnO2 is a strong contender for sustainable cathodes but cycles poorly because the Jahn-Teller distorted Mn3+ ions destabilize the lattice framework. Here, we report a LiMnO2 cathode design with interwoven spinel and layered domains. At the interface between these two domains, the Mn dz(2) orbitals are oriented perpendicular to each other, giving rise to interfacial orbital ordering, which suppresses the otherwise cooperative Jahn-Teller distortion and Mn dissolution. As a result, the heterostructured cathode delivers enhanced structural and electrochemical cycling stability. This work provides a new strategy for interface engineering, possibly stimulating more research on Mn-rich cathode materials for sustainable lithium-ion batteries. The field of battery chemistry must embrace abundant elements such as Mn for improved sustainability. Here the authors engineer the orientation of Mn 3d orbitals, resulting in excellent performance in LiMnO2 cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 392, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41893-020-00660-9", "DOI Link": "http://dx.doi.org/10.1038/s41893-020-00660-9", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000598708000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, PX; Dai, Q; Li, ZL; Ye, ZY; Xiong, J; Liu, HC; Zheng, GX; Zhang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Peixia; Dai, Qi; Li, Zile; Ye, Zhiyuan; Xiong, Jun; Liu, Hong-Chao; Zheng, Guoxing; Zhang, Shuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metasurface-based key for computational imaging encryption", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical metasurfaces can offer high-quality multichannel displays by modulating different degrees of freedom of light, demonstrating great potential in the next generation of optical encryption and anti-counterfeiting. Different from the direct imaging modality of metasurfaces, single-pixel imaging (SPI) as a typical computational imaging technique obtains the object image from a decryption-like computational process. Here, we propose an optical encryption scheme by introducing metasurface-images (meta-images) into the encoding and decoding processes as the keys of SPI encryption. Different high-quality meta-images generated by a dual-channel Malus metasurface play the role of keys to encode multiple target images and retrieve them following the principle of SPI. Our work eliminates the conventional digital transmission process of keys in SPI encryption, enables the reusability of a single metasurface in different encryption processes, and thereby paves the way toward a high-security optical encryption between direct and indirect imaging methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 7, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg0363", "DOI": "10.1126/sciadv.abg0363", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg0363", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654198900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Galloway, KC; Becker, KP; Phillips, B; Kirby, J; Licht, S; Tchernov, D; Wood, RJ; Gruber, DF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Galloway, Kevin C.; Becker, Kaitlyn P.; Phillips, Brennull; Kirby, Jordan; Licht, Stephen; Tchernov, Dan; Wood, Robert J.; Gruber, David F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft Robotic Grippers for Biological Sampling on Deep Reefs", "Source Title": "SOFT ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article presents the development of an underwater gripper that utilizes soft robotics technology to delicately manipulate and sample fragile species on the deep reef. Existing solutions for deep sea robotic manipulation have historically been driven by the oil industry, resulting in destructive interactions with undersea life. Soft material robotics relies on compliant materials that are inherently impedance matched to natural environments and to soft or fragile organisms. We demonstrate design principles for soft robot end effectors, bench-top characterization of their grasping performance, and conclude by describing in situ testing at mesophotic depths. The result is the first use of soft robotics in the deep sea for the nondestructive sampling of benthic fauna.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 624, "Times Cited, All Databases": 738, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23, "End Page": 33, "Article Number": null, "DOI": "10.1089/soro.2015.0019", "DOI Link": "http://dx.doi.org/10.1089/soro.2015.0019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394585300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, KZ; Lv, WX; Khan, I; Liu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Kezhen; Lv, Wenxiu; Khan, Iltaf; Liu, Shu-yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic H2 generation via CoP quantum-dot-modified g-C3N4 synthesized by electroless plating", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic water splitting is a promising method for hydrogen production. Numerous efficient photocatalysts have been synthesized and utilized. However, photocatalysts without a noble metal as the co-catalyst have been rarely reported. Herein, a CoP co-catalyst-modified graphitic-C3N4 (g-C3N4/CoP) is investigated for photocatalytic water splitting to produce H-2. The g-C3N4/CoP composite is synthesized in two steps. The first step is related to thermal decomposition, and the second step involves an electroless plating technique. The photocatalytic activity for hydrogen evolution reactions of g-C3N4 is distinctly increased by loading the appropriate amount of CoP quantum dots (QDs). Among the as-synthesized samples, the optimized one (g-C3N4/CoP-4%) shows exceptional photocatalytic activity as compared with pristine g-C3N4, generating H-2 at a rate of 936 mu mol g(-1) h(-1)even higher than that of g-C3N4 with 4 wt% Pt (665 mu mol g(-1) h(-1)). The UV-visible and optical absorption behavior confirms that g-C3N4 has an absorption edge at 451 nm, but after being composited with CoP, g-C3N4/CoP-4% has an absorption edge at 497 nm. Furthermore, photoluminescence and photocurrent measurements confirm that loading CoP QDs to pristine g-C(3)N(4 )not only enhances the charge separation, but also improves the transfer of photogenerated e(-)h(+) pairs, thus improving the photocatalytic performance of the catalyst to generate H-2. This work demonstrates a feasible strategy for the synthesis of highly efficient metal phosphide-loaded g-C3N4 for hydrogen generation. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 114, "End Page": 121, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63459-5", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63459-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495145800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Wang, MX; Wu, JX; Fu, HX; Yang, HF; Tian, Z; Tu, T; Peng, H; Sun, Y; Xu, X; Jiang, J; Schröter, NBM; Li, YW; Pei, D; Liu, S; Ekahana, SA; Yuan, HT; Xue, JM; Li, G; Jia, JF; Liu, ZK; Yan, BH; Peng, HL; Chen, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Cheng; Wang, Meixiao; Wu, Jinxiong; Fu, Huixia; Yang, Haifeng; Tian, Zhen; Tu, Teng; Peng, Han; Sun, Yan; Xu, Xiang; Jiang, Juan; Schroter, Niels B. M.; Li, Yiwei; Pei, Ding; Liu, Shuai; Ekahana, Sandy A.; Yuan, Hongtao; Xue, Jiamin; Li, Gang; Jia, Jinfeng; Liu, Zhongkai; Yan, Binghai; Peng, Hailin; Chen, Yulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic structures and unusually robust bandgap in an ultrahigh-mobility layered oxide semiconductor, Bi2O2Se", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductors are essential materials that affect our everyday life in the modern world. Two-dimensional semiconductors with high mobility and moderate bandgap are particularly attractive today because of their potential application in fast, low-power, and ultrasmall/thin electronic devices. We investigate the electronic structures of a new layered air-stable oxide semiconductor, Bi2O2Se, with ultrahigh mobility (similar to 2.8 x 10(5) cm(2)/V.s at 2.0 K) and moderate bandgap (similar to 0.8 eV). Combining angle-resolved photoemission spectroscopy and scanning tunneling microscopy, we mapped out the complete band structures of Bi2O2Se with key parameters (for example, effective mass, Fermi velocity, and bandgap). The unusual spatial uniformity of the bandgap without undesired in-gap states on the sample surface with up to similar to 50% defects makes Bi2O2Se an ideal semiconductor for future electronic applications. In addition, the structural compatibility between Bi2O2Se and interesting perovskite oxides (for example, cuprate high-transition temperature superconductors and commonly used substrate material SrTiO3) further makes heterostructures between Bi2O2Se and these oxides possible platforms for realizing novel physical phenomena, such as topological superconductivity, Josephson junction field-effect transistor, new superconducting optoelectronics, and novel lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat8355", "DOI": "10.1126/sciadv.aat8355", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat8355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449224000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kushima, A; So, KP; Su, C; Bai, P; Kuriyama, N; Maebashi, T; Fujiwara, Y; Bazant, MZ; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kushima, Akihiro; So, Kang Pyo; Su, Cong; Bai, Peng; Kuriyama, Nariaki; Maebashi, Takanori; Fujiwara, Yoshiya; Bazant, Martin Z.; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: Root growth, dead lithium and lithium flotsams", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present in situ environmental transmission electron microscopy (ETEM) observation of metallic lithium nucleation, growth and shrinkage in a liquid confining cell, where protrusions are seen to grow from their roots or surfaces, depending on the overpotential. The rate of solid-electrolyte interface (SEI) formation affects root vs. surface growth mode, with the former akin to intermittent volcanic eruptions, giving kinked segments of nearly constant diameter. Upon delithiation, root-grown whiskers are highly unstable, because the segmental shrinkage rate depends on Li+ transport across SEI, which is the greatest around the latest grown segment with the thinnest SEI, and therefore the near-root segment often dissolves first and the rest of the whisker then loses electrical contact. These electrically isolated dead lithium branches are also easily swept away into the bulk electrolyte to become nullo-lithium flotsam because the hollowed-out SEI tube is very brittle. Our observations are consistent with SEI-obstructed growth by two competing mechanisms; surface growth of dense Eden-like clusters and root growth of whiskers, resulting from the voltage-dependent competition between lithium electrodeposition and SEI formation reactions. Similar phenomena could occur whenever chemical deposition/dissolution competes with irreversible side reactions that form a passivating layer on the evolving surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 32, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 279, "Article Number": null, "DOI": "10.1016/j.nulloen.2016.12.001", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2016.12.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397003700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Andersson, J; Grönkvist, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Andersson, Joakim; Gronkvist, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale storage of hydrogen", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large-scale storage of hydrogen plays a fundamental role in a potential future hydrogen economy. Although the storage of gaseous hydrogen in salt caverns already is used on a full industrial scale, the approach is not applicable in all regions due to varying geological conditions. Therefore, other storage methods are necessary. In this article, options for the large-scale storage of hydrogen are reviewed and compared based on fundamental thermodynamic and engineering aspects. The application of certain storage technologies, such as liquid hydrogen, methanol, ammonia, and dibenzyltoluene, is found to be advantageous in terms of storage density, cost of storage, and safety. The variable costs for these high-density storage technologies are largely associated with a high electricity demand for the storage process or with a high heat demand for the hydrogen release process. If hydrogen is produced via electrolysis and stored during times of low electricity prices in an industrial setting, these variable costs may be tolerable. (C) 2019 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 835, "Times Cited, All Databases": 884, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 44, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11901, "End Page": 11919, "Article Number": null, "DOI": "10.1016/j.ijhydene.2019.03.063", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2019.03.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468710100050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, W; Ji, XY; Zhu, XB; Li, L; Wang, JQ; Zhang, Y; Saw, PE; Li, WL; Kong, N; Islam, MA; Gan, T; Zeng, XW; Zhang, H; Mahmoudi, M; Tearney, GJ; Farokhzad, OC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Wei; Ji, Xiaoyuan; Zhu, Xianbing; Li, Li; Wang, Junqing; Zhang, Ye; Saw, Phei Er; Li, Wenliang; Kong, Na; Islam, Mohammad Ariful; Gan, Tian; Zeng, Xiaowei; Zhang, Han; Mahmoudi, Morteza; Tearney, Guillermo J.; Farokhzad, Omid C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Antimonene-Based Photonic nullomedicine for Cancer Theranostics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimonene (AM) is a recently described two-dimensional (2D) elemental layered material. In this study, a novel photonic drug-delivery platform based on 2D PEGylated AM nullosheets (NSs) is developed. The platform's multiple advantages include: i) excellent photothermal properties, ii) high drug-loading capacity, iii) spatiotemporally controlled drug release triggered by near-infrared (NIR) light and moderate acidic pH, iv) superior accumulation at tumor sites, v) deep tumor penetration by both extrinsic stimuli (i.e., NIR light) and intrinsic stimuli (i.e., pH), vi) excellent multimodal-imaging properties, and vii) significant inhibition of tumor growth with no observable side effects and potential degradability, thus addressing several key limitations of cancer nullomedicines. The intracellular fate of the prepared NSs is also revealed for the first time, providing deep insights that improve cellular-level understanding of the nullo-bio interactions of AM-based NSs and other emerging 2D nullomaterials. To the best of knowledge, this is the first report on 2D AM-based photonic drug-delivery platforms, possibly marking an exciting jumping-off point for research into the application of 2D AM nullomaterials in cancer theranostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2018, "Volume": 30, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802061, "DOI": "10.1002/adma.201802061", "DOI Link": "http://dx.doi.org/10.1002/adma.201802061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444671900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, F; Ma, C; Wang, H; Hu, WJ; Yu, WL; Sheikh, AD; Wu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Feng; Ma, Chun; Wang, Hong; Hu, Weijin; Yu, Weili; Sheikh, Arif D.; Wu, Tom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambipolar solution-processed hybrid perovskite phototransistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organolead halide perovskites have attracted substantial attention because of their excellent physical properties, which enable them to serve as the active material in emerging hybrid solid-state solar cells. Here we investigate the phototransistors based on hybrid perovskite films and provide direct evidence for their superior carrier transport property with ambipolar characteristics. The field-effect mobilities for triiodide perovskites at room temperature are measured as 0.18 (0.17) cm(2)V(-1)s(-1) for holes (electrons), which increase to 1.24 (1.01) cm(2)V(-1)s(-1) for mixed-halide perovskites. The photoresponsivity of our hybrid perovskite devices reaches 320 AW(-1), which is among the largest values reported for phototransistors. Importantly, the phototransistors exhibit an ultrafast photoresponse speed of less than 10 ms. The solution-based process and excellent device performance strongly underscore hybrid perovskites as promising material candidates for photoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8238, "DOI": "10.1038/ncomms9238", "DOI Link": "http://dx.doi.org/10.1038/ncomms9238", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363017500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, LM; Zhou, GH; Wang, QQ; Ang, LK; Ang, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Liemao; Zhou, Guanghui; Wang, Qianqian; Ang, L. K.; Ang, Yee Sin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional van der Waals electrical contact to monolayer MoSi2N4", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A two-dimensional (2D) MoSi2N4 monolayer is an emerging class of air-stable 2D semiconductors possessing exceptional electrical and mechanical properties. Despite intensive recent research effort devoted to uncover the material properties of MoSi2N4, the physics of electrical contacts to MoSi2N4 remains largely unexplored thus far. In this work, we study van der Waals heterostructures composed of MoSi2N4 contacted by graphene and NbS2 monolayers using first-principles density functional theory calculations. We show that the MoSi2N4/NbS2 contact exhibits an ultralow Schottky barrier height (SBH), which is beneficial for nulloelectronics applications. For the MoSi2N4/graphene contact, the SBH can be modulated via the interlayer distance or via external electric fields, thus opening up an opportunity for reconfigurable and tunable nulloelectronic devices. Our findings provide insights into the physics of 2D electrical contacts to MoSi2N4 and shall offer a critical first step toward the design of high-performance electrical contacts to MoSi2N4-based 2D nullodevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 118, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13106, "DOI": "10.1063/5.0033241", "DOI Link": "http://dx.doi.org/10.1063/5.0033241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000608277500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, BZ; Guo, L; Wu, F; Peng, Y; Lu, JE; Smart, TJ; Wang, N; Finfrock, YZ; Morris, D; Zhang, P; Li, N; Gao, P; Ping, Y; Chen, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Bingzhang; Guo, Lin; Wu, Feng; Peng, Yi; Lu, Jia En; Smart, Tyler J.; Wang, null; Finfrock, Y. Zou; Morris, David; Zhang, Peng; Li, Ning; Gao, Peng; Ping, Yuan; Chen, Shaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction is an important process in electrochemical energy technologies. Herein, ruthenium and nitrogen codoped carbon nullowires are prepared as effective hydrogen evolution catalysts. The catalytic performance is markedly better than that of commercial platinum catalyst, with an overpotential of only -12 mV to reach the current density of 10 mV cm(-2) in 1M KOH and -47 mV in 0.1M KOH. Comparisons with control experiments suggest that the remarkable activity is mainly ascribed to individual ruthenium atoms embedded within the carbon matrix, with minimal contributions from ruthenium nulloparticles. Consistent results are obtained in first-principles calculations, where RuCxNy moieties are found to show a much lower hydrogen binding energy than ruthenium nulloparticles, and a lower kinetic barrier for water dissociation than platinum. Among these, RuC2N2 stands out as the most active catalytic center, where both ruthenium and adjacent carbon atoms are the possible active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 631, "DOI": "10.1038/s41467-019-08419-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08419-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458008700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Taylor, AD; Sun, Q; Goetz, KP; An, QZ; Schramm, T; Hofstetter, Y; Litterst, M; Paulus, F; Vaynzof, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Taylor, Alexander D.; Sun, Qing; Goetz, Katelyn P.; An, Qingzhi; Schramm, Tim; Hofstetter, Yvonne; Litterst, Maximillian; Paulus, Fabian; Vaynzof, Yana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general approach to high-efficiency perovskite solar cells by any antisolvent", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deposition of perovskite films by antisolvent engineering is a highly common method employed in perovskite photovoltaics research. Herein, we report on a general method that allows for the fabrication of highly efficient perovskite solar cells by any antisolvent via manipulation of the antisolvent application rate. Through detailed structural, compositional, and microstructural characterization of perovskite layers fabricated by 14 different antisolvents, we identify two key factors that influence the quality of the perovskite layer: the solubility of the organic precursors in the antisolvent and its miscibility with the host solvent(s) of the perovskite precursor solution, which combine to produce rate-dependent behavior during the antisolvent application step. Leveraging this, we produce devices with power conversion efficiencies (PCEs) that exceed 21% using a wide range of antisolvents. Moreover, we demonstrate that employing the optimal antisolvent application procedure allows for highly efficient solar cells to be fabricated from a broad range of precursor stoichiometries. Thin film deposition of perovskites by antisolvent engineering is commonly used, but the effect of processing parameters is not yet fully understood. Here, the authors identify two key factors that influence the film quality through a detailed structural and compositional study of perovskite layers fabricated by 14 different antisolvents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1878, "DOI": "10.1038/s41467-021-22049-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22049-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637990400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stern, MV; Waschitz, Y; Cao, W; Nevo, ; Watanabe, K; Taniguchi, T; Sela, E; Urbakh, M; Hod, O; Ben Shalom, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stern, M. Vizner; Waschitz, Y.; Cao, W.; Nevo, I; Watanabe, K.; Taniguchi, T.; Sela, E.; Urbakh, M.; Hod, O.; Ben Shalom, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial ferroelectricity by van der Waals sliding", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite their partial ionic nature, many-layered diatomic crystals avoid internal electric polarization by forming a centrosymmetric lattice at their optimal van der Waals stacking. Here, we report a stable ferroelectric order emerging at the interface between two naturally grown flakes of hexagonal boron nitride, which are stacked together in a metastable non-centrosymmetric parallel orientation. We observe alternating domains of inverted normal polarization, caused by a lateral shift of one lattice site between the domains. Reversible polarization switching coupled to lateral sliding is achieved by scanning a biased tip above the surface. Our calculations trace the origin of the phenomenon to a subtle interplay between charge redistribution and ionic displacement and provide intuitive insights to explore the interfacial polarization and its distinctive slidetronics switching mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 372, "Issue": 6549, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1462, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abe8177", "DOI Link": "http://dx.doi.org/10.1126/science.abe8177", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665860000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZS; Mao, CL; Meira, DM; Duchesne, PN; Tountas, AA; Li, Z; Qiu, CY; Tang, SL; Song, R; Ding, X; Sun, JC; Yu, JF; Howe, JY; Tu, WG; Wang, L; Ozin, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zeshu; Mao, Chengliang; Meira, Debora Motta; Duchesne, Paul N.; Tountas, Athanasios A.; Li, Zhao; Qiu, Chenyue; Tang, Sanli; Song, Rui; Ding, Xue; Sun, Junchuan; Yu, Jiangfan; Howe, Jane Y.; Tu, Wenguang; Wang, Lu; Ozin, Geoffrey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New black indium oxide-tandem photothermal CO2-H2 methanol selective catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It has long been known that the thermal catalyst Cu/ZnO/Al2O3(CZA) can enable remarkable catalytic performance towards CO2 hydrogenation for the reverse water-gas shift (RWGS) and methanol synthesis reactions. However, owing to the direct competition between these reactions, high pressure and high hydrogen concentration (>= 75%) are required to shift the thermodynamic equilibrium towards methanol synthesis. Herein, a new black indium oxide with photothermal catalytic activity is successfully prepared, and it facilitates a tandem synthesis of methanol at a low hydrogen concentration (50%) and ambient pressure by directly using by-product CO as feedstock. The methanol selectivities achieve 33.24% and 49.23% at low and high hydrogen concentrations, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1512, "DOI": "10.1038/s41467-022-29222-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29222-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771678500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hosseini, ES; Manjakkal, L; Shakthivel, D; Dahiya, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hosseini, Ensieh S.; Manjakkal, Libu; Shakthivel, Dhayalan; Dahiya, Ravinder", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Glycine-Chitosan-Based Flexible Biodegradable Piezoelectric Pressure Sensor", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents flexible pressure sensors based on free-standing and biodegradable glycine-chitosan piezoelectric films. Fabricated by the self-assembly of biological molecules of glycine within a water-based chitosan solution, the piezoelectric films consist of a stable spherulite structure of beta-glycine (size varying from a few millimeters to 1 cm) embedded in an amorphous chitosan polymer. The polymorphic phase of glycine crystals in chitosan, evaluated by X-ray diffraction, confirms formation of a pure ferroelectric phase of glycine (beta-phase). Our results show that a simple solvent-casting method can be used to prepare a biodegradable beta-glycine/chitosan-based piezoelectric film with sensitivity (similar to 2.82 +/- 0.2 mV kPa(-1)) comparable to those of nondegradable commercial piezoelectric materials. The measured capacitance of the beta-glycine/chitosan film is in the range from 0.26 to 0.12 nF at a frequency range from 100 Hz to 1 MHz, and its dielectric constant and loss factor are 7.7 and 0.18, respectively, in the high impedance range under ambient conditions. The results suggest that the glycine-chitosan composite is a promising new biobased piezoelectric material for biodegradable sensors for applications in wearable biomedical diagnostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2020, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9008, "End Page": 9016, "Article Number": null, "DOI": "10.1021/acsami.9b21052", "DOI Link": "http://dx.doi.org/10.1021/acsami.9b21052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517360000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, P; Kannimuthu, K; Zeraati, AS; Roy, S; Wang, X; Wang, XY; Samanta, S; Miller, KA; Molina, M; Trivedi, D; Abed, J; Mata, AC; Al-Mahayni, H; Baltrusaitis, J; Shimizu, G; Wu, YA; Seifitokaldani, A; Sargent, EH; Ajayan, PM; Hu, JG; Kibria, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Pawan; Kannimuthu, Karthick; Zeraati, Ali Shayesteh; Roy, Soumyabrata; Wang, Xiao; Wang, Xiyang; Samanta, Subhajyoti; Miller, Kristen A.; Molina, Maria; Trivedi, Dhwanil; Abed, Jehad; Mata, Astrid Campos; Al-Mahayni, Hasan; Baltrusaitis, Jonas; Shimizu, George; Wu, Yimin A.; Seifitokaldani, Ali; Sargent, Edward H.; Ajayan, Pulickel M.; Hu, Jinguang; Kibria, Md Golam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Density Cobalt Single-Atom Catalysts for Enhanced Oxygen Evolution Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single atom catalysts (SACs) possess unique catalytic properties due to low-coordination and unsaturated active sites. However, the demonstrated performance of SACs is limited by low SAC loading, poor metal-support interactions, and nonstable performance. Herein, we report a macromolecule-assisted SAC synthesis approach that enabled us to demonstrate high-density Co single atoms (10.6 wt % Co SAC) in a pyridinic N-rich graphenic network. The highly porous carbon network (surface area of similar to 186 m(2) g(-1)) with increased conjugation and vicinal Co site decoration in Co SACs significantly enhanced the electrocatalytic oxygen evolution reaction (OER) in 1 M KOH (eta(10) at 351 mV; mass activity of 2209 mA mg(Co)(-1) at 1.65 V) with more than 300 h stability. Operando X-ray absorption near-edge structure demonstrates the formation of electron-deficient Co-O coordination intermediates, accelerating OER kinetics. Density functional theory (DFT) calculations reveal the facile electron transfer from cobalt to oxygen speciesaccelerated OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2023, "Volume": 145, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8052, "End Page": 8063, "Article Number": null, "DOI": "10.1021/jacs.3c00537", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c00537", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967668600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, W; Sun, Y; Zhao, DL; Aili, A; Zhang, S; Shi, CQ; Zhang, JL; Geng, HY; Zhang, J; Zhang, LX; Xiao, JL; Yang, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Wei; Sun, Yan; Zhao, Dongliang; Aili, Ablimit; Zhang, Shun; Shi, Chuanqian; Zhang, Jialun; Geng, Huiyuan; Zhang, Jie; Zhang, Lixia; Xiao, Jianliang; Yang, Ronggui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance wearable thermoelectric generator with self-healing, recycling, and Lego-like reconfiguring capabilities", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric generators (TEGs) are an excellent candidate for powering wearable electronics and the Internet of Things,due to their capability of directly converting heat to electrical energy. Here, we report a high-performance wearable TEG with superior stretchability, self-healability, recyclability, and Lego-like reconfigurability, by combining modular thermoelectric chips, dynamic covalent polyimine, and flowable liquid-metal electrical wiring in a mechanical architecture design of soft motherboard-rigid plugin modules.A record-high open-circuit voltage among flexible TEGs is achieved, reaching 1 V/cm(2) at a temperature difference of 95 K. Furthermore, this TEG is integrated with a wavelength-selective metamaterial film on the cold side, leading to greatly improved device performance under solar irradiation, which is critically important for wearable energy harvesting during outdoor activities. The optimal properties and design concepts of TEGs reported here can pave the way for delivering the next-generation high-performance, adaptable, customizable, durable, economical, and eco-friendly energy-harvesting devices with wide applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe0586", "DOI": "10.1126/sciadv.abe0586", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe0586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617708700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, RP; Li, YY; Xing, LX; Zhong, RY; Qian, ZY; Yin, GP; Wang, YC; Du, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Ruipeng; Li, Yuyang; Xing, Lixin; Zhong, Ruyi; Qian, Zhengyi; Yin, Geping; Wang, Yucheng; Du, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A dynamic Ni(OH)2-NiOOH/NiFeP heterojunction enabling high-performance E-upgrading of hydroxymethylfurfural", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Facilely upgrading 5-Hydroxymethylfurfural (HMF) via controllable oxidation of aldehyde and hydroxymethyl groups has attracted increasing attention since one of the products, 2,5-Furandicarboxylic acid (FDCA), is of great industrial value. Herein, the surface reconstruction of NiFeP and underlying dynamic Ni(OH)2-NiOOH transformation are characterized under electro-anodic HMF oxidation reaction (HMFOR). The Ni(OH)2-NiOOH/ NiFeP heterojunction presents extraordinary HMFOR performance and produces FDCA with a yield over 99% and a Faradaic efficiency over 94%. The reconstructed NiOOH is suggested to chemically (not electrochemically) oxidize HMF while itself is reduced back to Ni(OH)2; The applied anodic potential then drives the oxidation of Ni (OH)2 to NiOOH, to circlize the HMF oxidation process. Meanwhile, the deeper oxidation of NiOOH to NiO(OH)2 or beyond can drive the oxygen evolution reaction (OER). Therefore, a NiOOH-centered dual-circle mechanism is unraveled to understand the entangled and competitive HMFOR and OER, which will be helpful to design better HMFOR electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2022, "Volume": 311, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121357, "DOI": "10.1016/j.apcatb.2022.121357", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2022.121357", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000803622500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HB; An, PF; Zhou, W; Guan, BY; Zhang, P; Dong, JC; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huabin; An, Pengfei; Zhou, Wei; Guan, Bu Yuan; Zhang, Peng; Dong, Juncai; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing atomically dispersed platinum (Pt) electrocatalysts is essential to build high-performance and cost-effective electrochemical water-splitting systems. We present a novel strategy to realize the traction and stabilization of isolated Pt atoms in the nitrogen-containing porous carbon matrix (Pt@PCM). In comparison with the commercial Pt/C catalyst (20 weight %), the as-prepared Pt@PCM catalyst exhibits significantly boosted mass activity (up to 25 times) for hydrogen evolution reaction. Results of extended x-ray absorption fine structure investigation and density functional theory calculation suggest that the active sites are associated with the lattice-confined Pt centers and the activated carbon (C)/nitrogen (N) atoms at the adjacency of the isolated Pt centers. This strategy may provide insights into constructing highly efficient single-atom catalysts for different energy-related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao6657", "DOI": "10.1126/sciadv.aao6657", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao6657", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426694200052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Y; Ruan, PC; Mao, CW; Chang, YX; Wang, L; Dai, L; Zhou, P; Lu, BA; Zhou, J; He, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Yang; Ruan, Pengchao; Mao, Caiwang; Chang, Yuxin; Wang, Ling; Dai, Lei; Zhou, Peng; Lu, Bingan; Zhou, Jiang; He, Zhangxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries (AZIBs) are one of the promising energy storage systems, which consist of electrode materials, electrolyte, and separator. The first two have been significantly received ample development, while the prominent role of the separators in manipulating the stability of the electrode has not attracted sufficient attention. In this work, a separator (UiO-66-GF) modified by Zr-based metal organic framework for robust AZIBs is proposed. UiO-66-GF effectively enhances the transport ability of charge carriers and demonstrates preferential orientation of (002) crystal plane, which is favorable for corrosion resistance and dendrite-free zinc deposition. Consequently, ZnlUiO-66-GF-2.21Zn cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h at 2.0 mA cm(-2) , and Zn1UiO-66-GF-2.21MnO(2) cells show excellent long-term stability with capacity retention of 85% after 1000 cycles. The reasonable design and application of multifunctional metal organic frameworks modified separators provide useful guidance for constructing durable AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 218, "DOI": "10.1007/s40820-022-00960-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00960-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000885744900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, H; Xu, G; Cao, X; Miao, CY; Zhang, HN; Chen, PY; Zhou, Y; Zhang, W; Sun, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Huan; Xu, Gang; Cao, Xin; Miao, Chunyang; Zhang, Hanning; Chen, Pengyu; Zhou, Yang; Zhang, Wei; Sun, ZhengMing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Ion-Conducting Hydrogel Electrolytes Based on Slide-Ring Pseudo-Polyrotaxane for Ultralong-Cycling Flexible Zinc-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible zinc-ion batteries (ZIBs) with high capacity and long cycle stability are essential for wearable electronic devices. Hydrogel electrolytes have been developed to provide ion-transfer channels while maintaining the integrity of ZIBs under mechanical strain. However, hydrogel matrices are typically swollen with aqueous salt solutions to increase ionic conductivity, which can hinder intimate contact with electrodes and reduce mechanical properties. To address this, a single-Zn-ion-conducting hydrogel electrolyte (SIHE) is developed by integrating polyacrylamide network and pseudo-polyrotaxane structure. The SIHE exhibits a high Zn2+ transference number of 0.923 and a high ionic conductivity of 22.4 mS cm(-1) at room temperature. Symmetric batteries with SIHE demonstrate stable Zn plating/stripping performance for over 160 h, with a homogenous and smooth Zn deposition layer. Full cells with La-V2O5 cathodes exhibit a high capacity of 439 mA h g(-1) at 0.1 A g(-1) and excellent capacity retention of 90.2% after 3500 cycles at 5 A g(-1). Moreover, the flexible ZIBs display stable electrochemical performance under harsh conditions, such as bending, cutting, puncturing, and soaking. This work provides a simple design strategy for single-ion-conducting hydrogel electrolytes, which could pave the way for long-life aqueous batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 35, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202301996", "DOI Link": "http://dx.doi.org/10.1002/adma.202301996", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001029759400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "González-Rubio, G; Mosquera, J; Kumar, V; Pedrazo-Tardajos, A; Llombart, P; Solís, DM; Lobato, I; Noya, EG; Guerrero-Martínez, A; Taboada, JM; Obelleiro, F; MacDowell, LG; Bals, S; Liz-Marzán, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonzalez-Rubio, Guillermo; Mosquera, Jesus; Kumar, Vished; Pedrazo-Tardajos, Adrian; Llombart, Pablo; Solis, Diego M.; Lobato, Ivan; Noya, Eva G.; Guerrero-Martinez, Andres; Taboada, Jose M.; Obelleiro, Fernulldo; MacDowell, Luis G.; Bals, Sara; Liz-Marzan, Luis M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Micelle-directed chiral seeded growth on anisotropic gold nullocrystals", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surfactant-assisted seeded growth of metal nulloparticles (NPs) can be engineered to produce anisotropic gold nullocrystals with high chiroptical activity through the templating effect of chiral micelles formed in the presence of dissymmetric cosurfactants. Mixed micelles adsorb on gold nullorods, forming quasihelical patterns that direct seeded growth into NPs with pronounced morphological and optical handedness. Sharp chiral wrinkles lead to chiral plasmon modes with high dissymmetry factors (similar to 0.20). Through variation of the dimensions of chiral wrinkles, the chiroptical properties can be tuned within the visible and near-infrared electromagnetic spectrum. The micelle-directed mechanism allows extension to other systems, such as the seeded growth of chiral platinum shells on gold nullorods. This approach provides a reproducible, simple, and scalable method toward the fabrication of NPs with high chiral optical activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2020, "Volume": 368, "Issue": 6498, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1472, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba0980", "DOI Link": "http://dx.doi.org/10.1126/science.aba0980", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545264600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, SS; Yin, JH; Yu, LD; Zhang, CQ; Zhu, YF; Gao, YS; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Shanshan; Yin, Junhui; Yu, Luodan; Zhang, Changqing; Zhu, Yufang; Gao, Youshui; Chen, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D MXene-Integrated 3D-Printing Scaffolds for Augmented Osteosarcoma Phototherapy and Accelerated Tissue Reconstruction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The residual of malignullt tumor cells and lack of bone-tissue integration are the two critical concerns of bone-tumor recurrence and surgical failure. In this work, the rational integration of 2D Ti3C2 MXene is reported with 3D-printing bioactive glass (BG) scaffolds for achieving concurrent bone-tumor killing by photonic hyperthermia and bone-tissue regeneration by bioactive scaffolds. The designed composite scaffolds take the unique feature of high photothermal conversion of integrated 2D Ti3C2 MXene for inducing bone-tumor ablation by near infrared-triggered photothermal hyperthermia, which has achieved the complete tumor eradication on in vivo bone-tumor xenografts. Importantly, the rational integration of 2D Ti3C2 MXene is demonstrated to efficiently accelerate the in vivo growth of newborn bone tissue of the composite BG scaffolds. The dual functionality of bone-tumor killing and bone-tissue regeneration makes these Ti3C2 MXene-integrated composite scaffolds highly promising for the treatment of bone tumors, which also substantially broadens the biomedical applications of 2D MXenes in tissue engineering, especially on the treatment of bone tumors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901511, "DOI": "10.1002/advs.201901511", "DOI Link": "http://dx.doi.org/10.1002/advs.201901511", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498479000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nayak, PK; Mahesh, S; Snaith, HJ; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nayak, Pabitra K.; Mahesh, Suhas; Snaith, Henry J.; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photovoltaic solar cell technologies: analysing the state of the art", "Source Title": "NATURE REVIEWS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The remarkable development in photovoltaic (PV) technologies over the past 5 years calls for a renewed assessment of their performance and potential for future progress. Here, we analyse the progress in cells and modules based on single-crystalline GaAs, Si, GaInP and InP, multicrystalline Si as well as thin films of polycrystalline CdTe and Culn(x)Ga(1-x),Se-2. In addition, we analyse the PV developments of the more recently emerged lead halide perovskites together with notable improvements in sustainable chalcogenides, organic PVs and quantum dots technologies. In addition to power conversion efficiencies, we consider many of the factors that affect power output for each cell type and note improvements in control over the optoelectronic quality of PV-relevant materials and interfaces and the discovery of new material properties. By comparing PV cell parameters across technologies, we appraise how far each technology may progress in the near future. Although accurate or revolutionary developments cannot be predicted, cross-fertilization between technologies often occurs, making achievements in one cell type an indicator of evolutionary developments in others. This knowledge transfer is timely, as the development of metal halide perovskites is helping to unite previously disparate, technology-focused strands of PV research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 803, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 269, "End Page": 285, "Article Number": null, "DOI": "10.1038/s41578-019-0097-0", "DOI Link": "http://dx.doi.org/10.1038/s41578-019-0097-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463369700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, WH; Liu, XS; Qiu, JM; Zhang, DX; Xiao, ZM; Xie, JS; Ren, FC; Wang, JM; Li, YX; Ortiz, GF; Wen, W; Wu, SQ; Wang, MS; Fu, RQ; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Wenhua; Liu, Xiangsi; Qiu, Jimin; Zhang, Dexin; Xiao, Zhumei; Xie, Jisheng; Ren, Fucheng; Wang, Jinming; Li, Yixiao; Ortiz, Gregorio F.; Wen, Wen; Wu, Shunqing; Wang, Ming-Sheng; Fu, Riqiang; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Na+-layer spacings to stabilize Mn-based layered cathodes for sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Suppressing phase transitions is crucial for the layered lithium/sodium transition metal oxide cathodes in batteries. Here, the authors report a water-mediated strategy to mitigate the phase transitions and boost electrochemical performances of manganese-based layered cathodes for cost-effective Na-ion batteries. Layered transition metal oxides are the most important cathode materials for Li/Na/K ion batteries. Suppressing undesirable phase transformations during charge-discharge processes is a critical and fundamental challenge towards the rational design of high-performance layered oxide cathodes. Here we report a shale-like NaxMnO2 (S-NMO) electrode that is derived from a simple but effective water-mediated strategy. This strategy expands the Na+ layer spacings of P2-type Na0.67MnO2 and transforms the particles into accordion-like morphology. Therefore, the S-NMO electrode exhibits improved Na+ mobility and near-zero-strain property during charge-discharge processes, which leads to outstanding rate capability (100 mAh g(-1) at the operation time of 6 min) and cycling stability (>3000 cycles). In addition, the water-mediated strategy is feasible to other layered sodium oxides and the obtained S-NMO electrode has an excellent tolerance to humidity. This work demonstrates that engineering the spacings of alkali-metal layer is an effective strategy to stabilize the structure of layered transition metal oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4903, "DOI": "10.1038/s41467-021-25074-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25074-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686181800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ono, M; Chen, KF; Li, W; Fan, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ono, Masashi; Chen, Kaifeng; Li, Wei; Fan, Shanhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-adaptive radiative cooling based on phase change materials", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the ability of harvesting the coldness of universe as a thermodynamic resource, radiative cooling technology is important for a broad range of applications such as passive building cooling, refrigeration, and renewable energy harvesting. However, all existing radiative cooling technologises utilize static structures, which lack the ability of self-adaptive tuning based on demand. Here we present the concept of self-adaptive radiative cooling based on phase change materials such as vanadium dioxide. We design a photonic structure that can adaptively turn 'on' and 'off' radiative cooling, depending the ambient temperature, without any extra energy input for switching. Our results here lead to new functionalities of radiative cooling and can potentially be used in a wide range of applications for the thermal managements of buildings, vehicles and textiles. (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2018, "Volume": 26, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A777", "End Page": "A787", "Article Number": null, "DOI": "10.1364/OE.26.00A777", "DOI Link": "http://dx.doi.org/10.1364/OE.26.00A777", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443431400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maitra, U; House, RA; Somerville, J; Tapia-Ruiz, N; Lozano, JG; Guerrini, N; Hao, R; Luo, K; Jin, LY; Pérez-Osorio, MA; Massel, F; Pickup, DM; Ramos, S; Lu, XY; McNally, DE; Chadwick, AV; Giustino, F; Schmitt, T; Duda, LC; Roberts, MR; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maitra, Urmimala; House, Robert A.; Somerville, JamesW.; Tapia-Ruiz, Nuria; Lozano, Juan G.; Guerrini, Niccolo; Hao, Rong; Luo, Kun; Jin, Liyu; Perez-Osorio, Miguel A.; Massel, Felix; Pickup, David M.; Ramos, Silvia; Lu, Xingye; McNally, Daniel E.; Chadwick, Alan V.; Giustino, Feliciano; Schmitt, Thorsten; Duda, Laurent C.; Roberts, Matthew R.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for improved energy-storage materials has revealed Li-and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit capacities in excess of what would be expected from alkali-ion removal/reinsertion and charge compensation by transition-metal (TM) ions. The additional capacity is provided through charge compensation by oxygen redox chemistry and some oxygen loss. It has been reported previously that oxygen redox occurs in O 2p orbitals that interact with alkali ions in the TM and alkali-ion layers (that is, oxygen redox occurs in compounds containing Li+-O(2p)-Li+ interactions). Na-2/3[Mg0.28Mn0.72]O-2 exhibits an excess capacity and here we show that this is caused by oxygen redox, even though Mg2+ resides in the TM layers rather than alkali-metal (AM) ions, which demonstrates that excess AM ions are not required to activate oxygen redox. We also show that, unlike the alkali-rich compounds, Na-2/3[Mg0.28Mn0.72]O-2 does not lose oxygen. The extraction of alkali ions from the alkali and TM layers in the alkalirich compounds results in severely underbonded oxygen, which promotes oxygen loss, whereas Mg2+ remains in Na-2/3[Mg0.28Mn0.72]O-2, which stabilizes oxygen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 496, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 288, "End Page": 295, "Article Number": null, "DOI": "10.1038/NCHEM.2923", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2923", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425589000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, J; Jian, MZ; Huang, L; Sun, ZH; Li, AW; Pan, Y; Yang, JZ; Wen, W; Zhou, W; Lin, Y; Wang, HJ; Liu, XY; Wang, LL; Shi, XX; Huang, XH; Cao, LN; Chen, S; Zheng, XS; Pan, HB; Zhu, JF; Wei, SQ; Li, WX; Lu, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Jian; Jian, Minzhen; Huang, Li; Sun, Zhihu; Li, Aowen; Pan, Yang; Yang, Jiuzhong; Wen, Wu; Zhou, Wu; Lin, Yue; Wang, Hui-Juan; Liu, Xinyu; Wang, Leilei; Shi, Xianxian; Huang, Xiaohui; Cao, Lina; Chen, Si; Zheng, Xusheng; Pan, Haibin; Zhu, Junfa; Wei, Shiqiang; Li, Wei-Xue; Lu, Junling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergizing metal-support interactions and spatial confinement boosts dynamics of atomic nickel for hydrogenations", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synergizing metal-support interactions and spatial confinement through atomic copper grippers boost the dynamics of highly loaded atomic nickel for high activity, high thermal/chemical stability and unprecedented coke inhibition in hydrogenation reactions. Atomically dispersed metal catalysts maximize atom efficiency and display unique catalytic properties compared with regular metal nulloparticles. However, achieving high reactivity while preserving high stability at appreciable loadings remains challenging. Here we solve the challenge by synergizing metal-support interactions and spatial confinement, which enables the fabrication of highly loaded atomic nickel (3.1 wt%) along with dense atomic copper grippers (8.1 wt%) on a graphitic carbon nitride support. For the semi-hydrogenation of acetylene in excess ethylene, the fabricated catalyst shows extraordinary catalytic performance in terms of activity, selectivity and stability-far superior to supported atomic nickel alone in the absence of a synergizing effect. Comprehensive characterization and theoretical calculations reveal that the active nickel site confined in two stable hydroxylated copper grippers dynamically changes by breaking the interfacial nickel-support bonds on reactant adsorption and making these bonds on product desorption. Such a dynamic effect confers high catalytic performance, providing an avenue to rationally design efficient, stable and highly loaded, yet atomically dispersed, catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 16, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1141, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-021-00951-y", "DOI Link": "http://dx.doi.org/10.1038/s41565-021-00951-y", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000679016500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bissett, MA; Kinloch, IA; Dryfe, RAW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bissett, Mark A.; Kinloch, Ian A.; Dryfe, Robert A. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of MoS2-Graphene Composites for High-Performance Coin Cell Supercapacitors", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials, such as graphene and molybdenum disulfide (MoS2), can greatly increase the performance of electrochemical energy storage devices because of the combination of high surface area and electrical conductivity. Here, we have investigated the performance of solution exfoliated MoS2 thin flexible membranes as supercapacitor electrodes in a symmetrical coin cell arrangement using an aqueous electrolyte (Na2SO4). By adding highly conductive graphene to form nullocomposite membranes, it was possible to increase the specific capacitance by reducing the resistivity of the electrode and altering the morphology of the membrane. With continued charge/discharge cycles the performance of the membranes was found to increase significantly (up to 800%), because of partial re-exfoliation of the layered material with continued ion intercalation, as well as increasing the specific capacitance through intercalation pseudocapacitance. These results demonstrate a simple and scalable application of layered 2D materials toward electrochemical energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2015, "Volume": 7, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17388, "End Page": 17398, "Article Number": null, "DOI": "10.1021/acsami.5b04672", "DOI Link": "http://dx.doi.org/10.1021/acsami.5b04672", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359683600059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, XC; Xiao, X; Jeon, S; Kim, D; Park, BJ; Kim, YJ; Rubab, N; Kim, S; Kim, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Xiangchun; Xiao, Xiao; Jeon, Sera; Kim, Dabin; Park, Byung-Joon; Kim, Young-Jun; Rubab, Najaf; Kim, SeongMin; Kim, Sang-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Ultrasound-Driven Bioadhesive Triboelectric nullogenerator for Instant Wound Sealing and Electrically Accelerated Healing in Emergencies", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A bioadhesive triboelectric nullogenerator (BA-TENG), as a first-aid rescue for instant and robust wound sealing and ultrasound-driven accelerated wound healing, is designed. This BA-TENG is fabricated with biocompatible materials, and integrates a flexible TENG as the top layer and bioadhesive as the bottom layer, resulting in effective electricity supply and strong sutureless sealing capability on wet tissues. When driven by ultrasound, the BA-TENG can produce a stable voltage of 1.50 V and current of 24.20 mu A underwater. The ex vivo porcine colon organ models show that the BA-TENG seals defects instantly (approximate to 5 s) with high interfacial toughness (approximate to 150 J m(-2)), while the rat bleeding liver incision model confirms that the BA-TENG performs rapid wound closure and hemostasis, reducing the blood loss by about 82%. When applied in living rats, the BA-TENG not only seals skin injuries immediately but also produces a strong electric field (E-field) of about 0.86 kV m(-1) stimulated by ultrasound to accelerate skin wound healing significantly. The in vitro studies confirm that these effects are attributed to the E-field-accelerated cell migration and proliferation. In addition, these TENG adhesives can be applied to not only wound treatment, nerve stimulation and regeneration, and charging batteries in implanted devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209054", "DOI Link": "http://dx.doi.org/10.1002/adma.202209054", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000929207000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Petrie, JR; Cooper, VR; Freeland, JW; Meyer, TL; Zhang, ZY; Lutterman, DA; Lee, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Petrie, Jonathan R.; Cooper, Valentino R.; Freeland, John W.; Meyer, Tricia L.; Zhang, Zhiyong; Lutterman, Daniel A.; Lee, Ho Nyung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strain is known to greatly influence low temperature oxygen electro catalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and Metal-air batteries. However, its catalytic impact on transition-metal oxide thin films, such as perovskites, is not widely understood. Here, we epitaxially strain the conducting perovskite LaNiO3 to systematically determine its influence on both the oxygen reduction and oxygen evolution reaction. Uniquely, we found that compressive strain could significantly enhance both reactions, yielding a bifunctional catalyst that surpasses the performance of noble metals' such as Pt. We attribute the improved bifunctionality to strain induced splitting of the e(g) Orbitals, which can customize orbital asymmetry at the surface. Analogous to strain induced shifts in the d-band center of noble metals relative to the Fermi level, :such splitting can dramatically affect catalytic activity in this perovskite and other potentially more active Oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2016, "Volume": 138, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2488, "End Page": 2491, "Article Number": null, "DOI": "10.1021/jacs.5b11713", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11713", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371453700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gomes, LC; Carvalho, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gomes, Lidia C.; Carvalho, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorene analogues: Isoelectronic two-dimensional group-IV monochalcogenides with orthorhombic structure", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The group-IV monochalcogenides SnS, SnSe, GeS, and GeSe form a family within the wider group of semiconductor phosphorene analogues. Here, we used first-principles calculations to investigate systematically their structural, electronic, and optical properties, analyzing the changes associated with the reduction of dimensionality, from bulk to monolayer or bilayer form. We show that all those binary phosphorene analogues are semiconducting, with band-gap energies covering part of the infrared and visible range, and in most cases higher than phosphorene. Further, we found that they have multiple valleys in the valence and conduction band, the latter with spin-orbit splitting of the order of 19-86 meV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2015, "Volume": 92, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85406, "DOI": "10.1103/PhysRevB.92.085406", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.085406", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359048700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Retuerto, M; Pascual, L; Calle-Vallejo, F; Ferrer, P; Gianolio, D; Pereira, AG; García, A; Torrero, J; Fernández-Díaz, MT; Bencok, P; Peña, MA; Fierro, JLG; Rojas, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Retuerto, Maria; Pascual, Laura; Calle-Vallejo, Federico; Ferrer, Pilar; Gianolio, Diego; Gonzalez Pereira, Amaru; Garcia, Alvaro; Torrero, Jorge; Fernulldez-Diaz, Maria Teresa; Bencok, Peter; Pena, Miguel A.; Fierro, Jose Luis G.; Rojas, Sergio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Na-doped ruthenium perovskite electrocatalysts with improved oxygen evolution activity and durability in acidic media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of active and durable catalysts for the H2O/O-2 interconversion is one of the major challenges of electrocatalysis for renewable energy. The oxygen evolution reaction (OER) is catalyzed by SrRuO3 with low potentials (ca. 1.35 V-RHE), but the catalyst's durability is insufficient. Here we show that Na doping enhances both activity and durability in acid media. DFT reveals that whereas SrRuO3 binds reaction intermediates too strongly, Na doping of similar to 0.125 leads to nearly optimal OER activity. Na doping increases the oxidation state of Ru, thereby displacing positively O p-band and Ru d-band centers, weakening Ru-adsorbate bonds. The enhanced durability of Na-doped perovskites is concomitant with the stabilization of Ru centers with slightly higher oxidation states, higher dissolution potentials, lower surface energy and less distorted RuO6 octahedra. These results illustrate how high OER activity and durability can be simultaneously engineered by chemical doping of perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2041, "DOI": "10.1038/s41467-019-09791-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09791-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466699900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, C; Sun, YM; Scherer, GG; Fisher, AC; Sherburne, M; Ager, JW; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Chao; Sun, Yuanmiao; Scherer, Guenther G.; Fisher, Adrian C.; Sherburne, Matthew; Ager, Joel W.; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Composition Dependent Ligand Effect in Tuning the Activity of Nickel-Copper Bimetallic Electrocatalysts toward Hydrogen Evolution in Alkaline", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring efficient and low-cost electrocatalysts for hydrogen evolution reaction (HER) in alkaline media is critical for developing anion exchange membrane electrolyzers. The key to a rational catalyst design is understanding the descriptors that govern the alkaline HER activity. Unfortunately, the principles that govern the alkaline HER performance remain unclear and are still under debate. By studying the alkaline HER at a series of NiCu bimetallic surfaces, where the electronic structure is modulated by the ligand effect, we demonstrate that alkaline HER activity can be correlated with either the calculated or the experimental-measured d band center (an indicator of hydrogen binding energy) via a volcano-type relationship. Such correlation indicates the descriptor role of the d band center, and this hypothesis is further supported by the evidence that combining Ni and Cu produces a variety of adsorption sites, which possess near-optimal hydrogen binding energy. Our finding broadens the applicability of d band theory to activity prediction of metal electrocatalysts and may offer an insightful understanding of alkaline HER mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2020, "Volume": 142, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7765, "End Page": 7775, "Article Number": null, "DOI": "10.1021/jacs.9b12005", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529959000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Gao, Q; Wang, JF; Chen, YF; Chen, ZH; Xu, HS; Tang, W; Leng, K; Ning, GH; Wu, JS; Xu, QH; Quek, SY; Lu, YX; Loh, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xing; Gao, Qiang; Wang, Juefan; Chen, Yifeng; Chen, Zhi-Hui; Xu, Hai-Sen; Tang, Wei; Leng, Kai; Ning, Guo-Hong; Wu, Jishan; Xu, Qing-Hua; Quek, Su Ying; Lu, Yixin; Loh, Kian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuneable near white-emissive two-dimensional covalent organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most two-dimensional (2D) covalent organic frameworks (COFs) are non-fluorescent in the solid state even when they are constructed from emissive building blocks. The fluorescence quenching is usually attributed to non-irradiative rotation-related or p-p stacking-caused thermal energy dissipation process. Currently there is a lack of guiding principle on how to design fluorescent, solid-state material made of COF. Herein, we demonstrate that the eclipsed stacking structure of 2D COFs can be used to turn on, and tune, the solid-state photoluminescence from non-emissive building blocks by the restriction of intramolecular bond rotation via intralayer and interlayer hydrogen bonds among highly organized layers in the eclipse-stacked COFs. Our COFs serve as a platform whereby the size of the conjugated linkers and side-chain functionalities can be varied, rendering the emission colour-tuneable from blue to yellow and even white. This work provides a guide to design new solid-state emitters using COFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2335, "DOI": "10.1038/s41467-018-04769-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04769-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435082400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, YT; Pan, ZH; Wang, XS; Yang, J; Qiu, YC; Xu, SY; Lu, YT; Huang, QM; Li, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yaotang; Pan, Zhenghui; Wang, Xianshu; Yang, Jie; Qiu, Yongcai; Xu, Shuyuan; Lu, Yitong; Huang, Qiming; Li, Weishan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Co3O4 nullo-Micro Arrays Featuring Superior Activity as Cathode in a Flexible and Rechargeable Zinc-Air Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state zinc-air batteries are characterized as low cost and have high energy density, providing wearable devices with an ideal power source. However, the sluggish oxygen reduction and evolution reactions in air cathodes are obstacles to its flexible and rechargeable application. Herein, a strategy called MOF-on-MOF (MOF, metal-organic framework) is presented for the structural design of air cathodes, which creatively develops an efficient oxygen catalyst comprising hierarchical Co(3)O(4 )nulloparticles anchored in nitrogen-doped carbon nullo-micro arrays on flexible carbon cloth (Co3O4@N-CNMAs/CC). This hierarchical and free-standing structure design guarantees high catalyst loading on air cathodes with multiple electrocatalytic activity sites, undoubtedly boosting reaction kinetics, and energy density of an all-solid-state zinc-air battery. The integrated Co3O4@N-CNMAs/CC cathode in an all-solid-state zinc-air battery exhibits a high open circuit potential of 1.461 V, a high capacity of 815 mAh g(-1) Zn at 1 mA cm(-2), a high energy density of 1010 Wh kg(-1) Zn, excellent cycling stability as well as outstanding mechanical flexibility, significantly outperforming the Pt/C-based cathode. This work opens a new door for the practical applications of rechargeable zinc-air batteries in wearable electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2019, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802243, "DOI": "10.1002/advs.201802243", "DOI Link": "http://dx.doi.org/10.1002/advs.201802243", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470189500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZL; Zhang, OF; Borgs, C; Chayes, JT; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhiling; Zhang, Oufan; Borgs, Christian; Chayes, Jennifer T.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ChatGPT Chemistry Assistant for Text Mining and the Prediction of MOF Synthesis", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use prompt engineering to guide ChatGPT in the automationoftext mining of metal-organic framework (MOF) synthesis conditionsfrom diverse formats and styles of the scientific literature. Thiseffectively mitigates ChatGPT's tendency to hallucinate information,an issue that previously made the use of large language models (LLMs)in scientific fields challenging. Our approach involves the developmentof a workflow implementing three different processes for text mining,programmed by ChatGPT itself. All of them enable parsing, searching,filtering, classification, summarization, and data unification withdifferent trade-offs among labor, speed, and accuracy. We deploy thissystem to extract 26 257 distinct synthesis parameters pertainingto approximately 800 MOFs sourced from peer-reviewed research articles.This process incorporates our ChemPrompt Engineering strategy to instructChatGPT in text mining, resulting in impressive precision, recall,and F1 scores of 90-99%. Furthermore, with the data set builtby text mining, we constructed a machine-learning model with over87% accuracy in predicting MOF experimental crystallization outcomesand preliminarily identifying important factors in MOF crystallization.We also developed a reliable data-grounded MOF chatbot to answer questionsabout chemical reactions and synthesis procedures. Given that theprocess of using ChatGPT reliably mines and tabulates diverse MOFsynthesis information in a unified format while using only narrativelanguage requiring no coding expertise, we anticipate that our ChatGPTChemistry Assistant will be very useful across various other chemistrysubdisciplines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2023, "Volume": 145, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18048, "End Page": 18062, "Article Number": null, "DOI": "10.1021/jacs.3c05819", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c05819", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001052894400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, W; Song, Q; Luo, Q; Li, LQ; Huo, XB; Chen, SP; Li, JY; Li, YH; Shi, S; Yuan, YH; Du, XW; Zhang, K; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wei; Song, Qun; Luo, Qiang; Li, Linqian; Huo, Xiaobing; Chen, Shipeng; Li, Jinyang; Li, Yunhong; Shi, Se; Yuan, Yihui; Du, Xiwen; Zhang, Kai; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photothermal-enabled single-atom catalysts for high-efficiency hydrogen peroxide photosynthesis from natural seawater", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is a powerful industrial oxidant and potential carbon-neutral liquid energy carrier. Sunlight-driven synthesis of H2O2 from the most earth-abundant O-2 and seawater is highly desirable. However, the solar-to-chemical efficiency of H2O2 synthesis in particulate photocatalysis systems is low. Here, we present a cooperative sunlight-driven photothermalphotocatalytic system based on cobalt single-atomsupported on sulfur doped graphitic carbon nitride/reduced graphene oxide heterostructure (Co-CN@G) to boost H2O2 photosynthesis from natural seawater. By virtue of the photothermal effect and synergy between Co single atoms and the heterostructure, Co-CN@G enables a solar-to-chemical efficiency of more than 0.7% under simulated sunlight irradiation. Theoretical calculations verify that the single atoms combined with heterostructure significantly promote the charge separation, facilitate O-2 absorption and reduce the energy barriers for O-2 reduction and water oxidation, eventually boostingH(2)O(2) photoproduction. The single-atom photothermal-photocatalytic materials may provide possibility of large-scale H2O2 production from inexhaustible seawater in a sustainable way.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2493, "DOI": "10.1038/s41467-023-38211-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38211-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022903400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, YH; Guan, WX; Lei, CX; Lu, HY; Shi, W; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Youhong; Guan, Weixin; Lei, Chuxin; Lu, Hengyi; Shi, Wen; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable super hygroscopic polymer films for sustainable moisture harvesting in arid environments", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extracting atmospheric water is a sustainable strategy to enable decentralized access to safely managed water but remains impractical due to its limited daily water output at low relative humidity. Here, the authors demonstrate a hygroscopic polymer composed of renewable biomass which allows high water uptake at low relative humidity Extracting ubiquitous atmospheric water is a sustainable strategy to enable decentralized access to safely managed water but remains challenging due to its limited daily water output at low relative humidity (<= 30% RH). Here, we report super hygroscopic polymer films (SHPFs) composed of renewable biomasses and hygroscopic salt, exhibiting high water uptake of 0.64-0.96 g g(-1) at 15-30% RH. Konjac glucomannull facilitates the highly porous structures with enlarged air-polymer interfaces for active moisture capture and water vapor transport. Thermoresponsive hydroxypropyl cellulose enables phase transition at a low temperature to assist the release of collected water via hydrophobic interactions. With rapid sorption-desorption kinetics, SHPFs operate 14-24 cycles per day in arid environments, equivalent to a water yield of 5.8-13.3 L kg(-1). Synthesized via a simple casting method using sustainable raw materials, SHPFs highlight the potential for low-cost and scalable atmospheric water harvesting technology to mitigate the global water crisis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2761, "DOI": "10.1038/s41467-022-30505-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30505-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798347800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YC; Sun, YH; Zheng, XL; Aoki, T; Pattengale, B; Huang, JE; He, X; Bian, W; Younull, S; Williams, N; Hu, J; Ge, JX; Pu, N; Yan, XX; Pan, XQ; Zhang, LJ; Wei, YG; Gu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yichao; Sun, Yuanhui; Zheng, Xueli; Aoki, Toshihiro; Pattengale, Brian; Huang, Jier; He, Xin; Bian, Wei; Younull, Sabrina; Williams, Nicholas; Hu, Jun; Ge, Jingxuan; Pu, Ning; Yan, Xingxu; Pan, Xiaoqing; Zhang, Lijun; Wei, Yongge; Gu, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically engineering activation sites onto metallic 1T-MoS2 catalysts for enhanced electrochemical hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering catalytic sites at the atomic level provides an opportunity to understand the catalyst's active sites, which is vital to the development of improved catalysts. Here we show a reliable and tunable polyoxometalate template-based synthetic strategy to atomically engineer metal doping sites onto metallic 1T-MoS2, using Anderson-type polyoxometalates as precursors. Benefiting from engineering nickel and oxygen atoms, the optimized electrocatalyst shows great enhancement in the hydrogen evolution reaction with a positive onset potential of similar to 0 V and a low overpotential of -46 mV in alkaline electrolyte, comparable to platinum-based catalysts. First-principles calculations reveal co-doping nickel and oxygen into 1T-MoS2 assists the process of water dissociation and hydrogen generation from their intermediate states. This research will expand on the ability to improve the activities of various catalysts by precisely engineering atomic activation sites to achieve significant electronic modulations and improve atomic utilization efficiencies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 982, "DOI": "10.1038/s41467-019-08877-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08877-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459899900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, QS; Zhu, C; Chen, M; Jiang, C; Guo, JY; Feng, YL; Dai, ZH; Yadavalli, SK; Hu, MY; Cao, X; Li, YQ; Huang, YZ; Liu, Z; Shi, YT; Wang, LD; Padture, NP; Zhou, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Qingshun; Zhu, Chao; Chen, Min; Jiang, Chen; Guo, Jingya; Feng, Yulin; Dai, Zhenghong; Yadavalli, Srinivas K.; Hu, Mingyu; Cao, Xun; Li, Yuqian; Huang, Yizhong; Liu, Zheng; Shi, Yantao; Wang, Liduo; Padture, Nitin P.; Zhou, Yuanyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interpenetrating interfaces for efficient perovskite solar cells with high operational stability and mechanical robustness", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The perovskite solar cell has emerged rapidly in the field of photovoltaics as it combines the merits of low cost, high efficiency, and excellent mechanical flexibility for versatile applications. However, there are significant concerns regarding its operational stability and mechanical robustness. Most of the previously reported approaches to address these concerns entail separate engineering of perovskite and charge-transporting layers. Herein we present a holistic design of perovskite and charge-transporting layers by synthesizing an interpenetrating perovskite/electron-transporting-layer interface. This interface is reaction-formed between a tin dioxide layer containing excess organic halide and a perovskite layer containing excess lead halide. Perovskite solar cells with such interfaces deliver efficiencies up to 22.2% and 20.1% for rigid and flexible versions, respectively. Long-term (1000h) operational stability is demonstrated and the flexible devices show high endurance against mechanical-bending (2500 cycles) fatigue. Mechanistic insights into the relationship between the interpenetrating interface structure and performance enhancement are provided based on comprehensive, advanced, microscopic characterizations. This study highlights interface integrity as an important factor for designing efficient, operationally-stable, and mechanically-robust solar cells. Operational stability and mechanical robustness remain as engineering bottlenecks in perovskite solar cells technology. Here, Dong et al. introduce an interpenetrating perovskite at the electron-transporting-layer interface that enables a 1000-hour stable operation and high endurance against bending fatigue over 2500 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 973, "DOI": "10.1038/s41467-021-21292-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21292-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620683400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Salishchev, GA; Tikhonovsky, MA; Shaysultanov, DG; Stepanov, ND; Kuznetsov, AV; Kolodiy, IV; Tortika, AS; Senkov, ON", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Salishchev, G. A.; Tikhonovsky, M. A.; Shaysultanov, D. G.; Stepanov, N. D.; Kuznetsov, A. V.; Kolodiy, I. V.; Tortika, A. S.; Senkov, O. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Mn and V on structure and mechanical properties of high-entropy alloys based on CoCrFeNi system", "Source Title": "JOURNAL OF ALLOYS AND COMPOUNDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microstructure and mechanical properties of equimolar composition alloys FeCrCoNi, FeCrCoNiV, FeCrCoNiMn and FeCrCoNiMnV were studied in as-solidified and annealed conditions. The FeCrCoNi and FeCrCoNiMn alloys were single-phase FCC solid-solutions in both conditions. However, the FeCrCoNiV and FeCrCoNiMnV alloys consisted of the intermetallic sigma-phase matrix with a tetragonal crystal lattice and precipitates of a disordered FCC phase. The crystal structures of these alloys were found to be not affected by annealing. A number of criteria were considered to explain phase composition of the studied alloys. It was shown that poor compatibility of V with other alloying elements caused significant distortions of FCC solid solution and thus promoted formation of the sigma phase. Tensile and compressive properties of these alloys together with their microhardness were determined. Significant strengthening accompanied by the loss of ductility due to formation of the sigma phase was demonstrated in the V containing alloys. The characteristics of the microstructure formation in the studied alloys were discussed. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2014, "Volume": 591, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11, "End Page": 21, "Article Number": null, "DOI": "10.1016/j.jallcom.2013.12.210", "DOI Link": "http://dx.doi.org/10.1016/j.jallcom.2013.12.210", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331066900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, K; He, DQ; Harris, C; Wang, YK; Lai, C; Li, HL; Coxon, PR; Ding, SJ; Wang, C; Kumar, RV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Kai; He, Deqing; Harris, Chris; Wang, Yuankun; Lai, Chao; Li, Huanglong; Coxon, Paul R.; Ding, Shujiang; Wang, Chao; Kumar, Ramachandran Vasant", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Sulfur Transformation by Multifunctional FeS2/FeS/S Composites for High-Volumetric Capacity Cathodes in Lithium-Sulfur Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries are currently being explored as promising advanced energy storage systems due to the high theoretical specific capacity of sulfur. However, achieving a scalable synthesis for the sulfur electrode material whilst maintaining a high volumetric energy density remains a serious challenge. Here, a continuous ball-milling route is devised for synthesizing multifunctional FeS2/FeS/S composites for use as high tap density electrodes. These composites demonstrate a maximum reversible capacity of 1044.7 mAh g(-1) and a peak volumetric capacity of 2131.1 Ah L-1 after 30 cycles. The binding direction is also considered here for the first time between dissolved lithium polysulfides (LiPSs) and host materials (FeS2 and FeS in this work) as determined by density functional theory calculations. It is concluded that if only one lithium atom of the polysulfide bonds with the sulfur atoms of FeS2 or FeS, then any chemical interaction between these species is weak or negligible. In addition, FeS2 is shown to have a strong catalytic effect on the reduction reactions of LiPSs. This work demonstrates the limitations of a strategy based on chemical interactions to improve cycling stability and offers new insights into the development of high tap density and high-performance sulfur-based electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800815, "DOI": "10.1002/advs.201800815", "DOI Link": "http://dx.doi.org/10.1002/advs.201800815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462613100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, FQ; Zou, PC; Zhang, YY; Pan, WL; Li, Y; Liang, LM; Chen, C; Liu, H; Zheng, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Fangqing; Zou, Peichao; Zhang, Yangyang; Pan, Wenli; Li, Ying; Liang, Limin; Chen, Cong; Liu, Hui; Zheng, Shijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction is known to be a kinetic bottleneck for water splitting. Triggering the lattice oxygen oxidation mechanism (LOM) can break the theoretical limit of the conventional adsorbate evolution mechanism and enhance the oxygen evolution reaction kinetics, yet the unsatisfied stability remains a grand challenge. Here, we report a high-entropy MnFeCoNiCu layered double hydroxide decorated with Au single atoms and O vacancies (Au-SA-MnFeCoNiCu LDH), which not only displays a low overpotential of 213 mV at 10 mA cm(-2) and high mass activity of 732.925 A g(-1) at 250 mV overpotential in 1.0 M KOH, but also delivers good stability with 700 h of continuous operation at similar to 100 mA cm(-2). Combining the advanced spectroscopic techniques and density functional theory calculations, it is demonstrated that the synergistic interaction between the incorporated Au single atoms and O vacancies leads to an upshift in the O 2p band and weakens the metal-O bond, thus triggering the LOM, reducing the energy barrier, and boosting the intrinsic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6019, "DOI": "10.1038/s41467-023-41706-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41706-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001095471200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZY; Si, Y; Xia, WQ; Wang, F; Liu, HQ; Yang, C; Zhang, WJ; Li, WW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhi-Yan; Si, Yang; Xia, Wen-Qi; Wang, Fan; Liu, Hou-Qi; Yang, Cheng; Zhang, Wen-Jun; Li, Wen-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron delocalization triggers nonradical Fenton-like catalysis over spinel oxides", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonradical Fenton-like catalysis offers opportunities to overcome the low efficiency and secondary pollution limitations of existing advanced oxidation decontamination technologies, but realizing this on transition metal spinel oxide catalysts remains challenging due to insufficient understanding of their catalytic mechanisms. Here, we explore the origins of catalytic selectivity of Fe-Mn spinel oxide and identify electron delocalization of the surface metal active site as the key driver of its nonradical catalysis. Through fine-tuning the crystal geometry to trigger Fe-Mn superexchange interaction at the spinel octahedra, ZnFeMnO4 with high-degree electron delocalization of the Mn-O unit was created to enable near 100% nonradical activation of peroxymonosulfate (PMS) at unprecedented utilization efficiency. The resulting surface-bound PMS* complex can efficiently oxidize electron-rich pollutants with extraordinary degradation activity, selectivity, and good environmental robustness to favor water decontamination applications. Our work provides a molecule-level understanding of the catalytic selectivity and bimetallic interactions of Fe-Mn spinel oxides, which may guide the design of low-cost spinel oxides for more selective and efficient decontamination applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2022, "Volume": 119, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2201607119", "DOI": "10.1073/pnas.2201607119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2201607119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000892124300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mulzer, CR; Shen, LX; Bisbey, RP; McKone, JR; Zhang, N; Abruña, HD; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mulzer, Catherine R.; Shen, Luxi; Bisbey, Ryan P.; McKone, James R.; Zhang, Na; Abruna, Hector D.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior Charge Storage and Power Density of a Conducting Polymer-Modified Covalent Organic Framework", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low conductivity of two-dimensional covalent organic frameworks (2D COFs), and most related coordination polymers, limits their applicability in optoelectronic and electrical energy storage (EES) devices. Although some networks exhibit promising conductivity, these examples generally lack structural versatility, one of the most attractive features of framework materials design. Here we enhance the electrical conductivity of a redox-active 2D COF film by electropolymerizing 3,4-ethylenedioxythiophene (EDOT) within its pores. The resulting poly(3,4-ethylenedioxythiophene) (PEDOT)-infiltrated COF films exhibit dramatically improved electrochemical responses, including quantitative access to their redox-active groups, even for 1 mu m-thick COF films that otherwise provide poor electrochemical performance. PEDOT-modified COF films can accommodate high charging rates (10-1600 C) without compromising performance and exhibit both a 10-fold higher current response relative to unmodified films and stable capacitances for at least 10 000 cycles. This work represents the first time that electroactive COFs or crystalline framework materials have shown volumetric energy and power densities comparable with other porous carbon-based electrodes, thereby demonstrating the promise of redox-active COFs for EES devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2016, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 667, "End Page": 673, "Article Number": null, "DOI": "10.1021/acscentsci.6b00220", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.6b00220", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384750900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, DW; Zhu, Y; Cheng, WK; Xu, GW; Wang, QW; Liu, SX; Li, J; Chen, CJ; Yu, HP; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Dawei; Zhu, Ying; Cheng, Wanke; Xu, Guangwen; Wang, Qingwen; Liu, Shouxin; Li, Jian; Chen, Chaoji; Yu, Haipeng; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Dynamic Gel with Reversible and Tunable Topological Networks and Performances", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design of polymeric networks with unique structural motifs can permit dynamic features, yet most existing material systems exhibit limited operational states or irreversible responsiveness. Here, we use a hydrogen-bond topological network as the design principle to construct an ionic gel material based on cellulose, ionic liquid, and H2O (designated as Cel-IL dynamic gel). The prepared Cel-IL dynamic gels exhibit tunable properties of mechanical strength, ionic conductivity, viscoelasticity, and self-healing. With limited H2O, the Cel-IL dynamic gel exhibits a bramble-like Turing-pattern microstructure with excellent adhesion, rapid self-healing, and moderate ionic conductivity features. By increasing the H2O content to 32 wt %, the microstructure switched to a dense and compact Turing pattern network, giving the gel good stretchability, robust toughness, and a high ionic conductivity. With this material, we demonstrate a flexible, transparent, designable, and biocompatible ion sensor device, which exhibits great potential for use in electronic skins and intelligent devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2020, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 390, "End Page": 403, "Article Number": null, "DOI": "10.1016/j.matt.2019.10.020", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2019.10.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519850300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zandiatashbar, A; Lee, GH; An, SJ; Lee, S; Mathew, N; Terrones, M; Hayashi, T; Picu, CR; Hone, J; Koratkar, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zandiatashbar, Ardavan; Lee, Gwan-Hyoung; An, Sung Joo; Lee, Sunwoo; Mathew, Nithin; Terrones, Mauricio; Hayashi, Takuya; Picu, Catalin R.; Hone, James; Koratkar, Nikhil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of defects on the intrinsic strength and stiffness of graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is important from a fundamental standpoint and for practical applications to understand how the mechanical properties of graphene are influenced by defects. Here we report that the two-dimensional elastic modulus of graphene is maintained even at a high density of sp(3)-type defects. Moreover, the breaking strength of defective graphene is only similar to 14% smaller than its pristine counterpart in the sp(3)-defect regime. By contrast, we report a significant drop in the mechanical properties of graphene in the vacancy-defect regime. We also provide a mapping between the Raman spectra of defective graphene and its mechanical properties. This provides a simple, yet non-destructive methodology to identify graphene samples that are still mechanically functional. By establishing a relationship between the type and density of defects and the mechanical properties of graphene, this work provides important basic information for the rational design of composites and other systems utilizing the high modulus and strength of graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3186, "DOI": "10.1038/ncomms4186", "DOI Link": "http://dx.doi.org/10.1038/ncomms4186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331118200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, JW; Liu, L; Yang, JX; Li, SY; Wang, X; Zhuang, HLL; Lu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Jiawei; Liu, Lei; Yang, Jixiang; Li, Siyuan; Wang, Xiao; Zhuang, Houlong L.; Lu, Yingying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium cobalt oxide, as a popular cathode in portable devices, delivers only half of its theoretical capacity in commercial lithium-ion batteries. When increasing the cut-off voltage to release more capacity, solubilization of cobalt in the electrolyte and structural disorders of lithium cobalt oxide particles are severe, leading to rapid capacity fading and limited cycle life. Here, we show a class of ternary lithium, aluminum, fluorine-modified lithium cobalt oxide with a stable and conductive layer using a facile and scalable hydrothermal-assisted, hybrid surface treatment. Such surface treatment hinders direct contact between liquid electrolytes and lithium cobalt oxide particles, which reduces the loss of active cobalt. It also forms a thin doping layer that consists of a lithium-aluminum-cobalt-oxide-fluorine solid solution, which suppresses the phase transition of lithium cobalt oxide when operated at voltages >4.55 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4918, "DOI": "10.1038/s41467-018-07296-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07296-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450755300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JK; Sougrati, MT; Zitolo, A; Ablett, JM; Oguz, IC; Mineva, T; Matanovic, I; Atanassov, P; Huang, Y; Zenyuk, I; Di Cicco, A; Kumar, K; Dubau, L; Maillard, F; Drazic, G; Jaouen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jingkun; Sougrati, Moulay Tahar; Zitolo, Andrea; Ablett, James M.; Oguz, Ismail Can; Mineva, Tzonka; Matanovic, Ivana; Atanassov, Plamen; Huang, Ying; Zenyuk, Iryna; Di Cicco, Andrea; Kumar, Kavita; Dubau, Laetitia; Maillard, Frederic; Drazic, Goran; Jaouen, Frederic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of durable and non-durable FeNx sites in Fe-N-C materials for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While Fe-N-C materials are a promising alternative to platinum for catalysing the oxygen reduction reaction in acidic polymer fuel cells, limited understanding of their operando degradation restricts rational approaches towards improved durability. Here we show that Fe-N-C catalysts initially comprising two distinct FeNx sites (S1 and S2) degrade via the transformation of S1 into iron oxides while the structure and number of S2 were unmodified. Structure-activity correlations drawn from end-of-test Fe-57 Mossbauer spectroscopy reveal that both sites initially contribute to the oxygen reduction reaction activity but only S2 substantially contributes after 50 h of operation. From in situ Fe-57 Mossbauer spectroscopy in inert gas coupled to calculations of the Mossbauer signature of FeNx moieties in different electronic states, we identify S1 to be a high-spin FeN4C12 moiety and S2 a low- or intermediate-spin FeN4C10 moiety. These insights lay the groundwork for rational approaches towards Fe-N-C cathodes with improved durability in acidic fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41929-020-00545-2", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00545-2", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599021700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Bayram, C; Park, H; Cheng, CW; Dimitrakopoulos, C; Ott, JA; Reuter, KB; Bedell, SW; Sadana, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jeehwan; Bayram, Can; Park, Hongsik; Cheng, Cheng-Wei; Dimitrakopoulos, Christos; Ott, John A.; Reuter, Kathleen B.; Bedell, Stephen W.; Sadana, Devendra K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Principle of direct van der Waals epitaxy of single-crystalline films on epitaxial graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There are numerous studies on the growth of planar films on sp(2)-bonded two-dimensional (2D) layered materials. However, it has been challenging to grow single-crystalline films on 2D materials due to the extremely low surface energy. Recently, buffer-assisted growth of crystalline films on 2D layered materials has been introduced, but the crystalline quality is not comparable with the films grown on sp(3)-bonded three-dimensional materials. Here we demonstrate direct van der Waals epitaxy of high-quality single-crystalline GaN films on epitaxial graphene with low defectivity and surface roughness comparable with that grown on conventional SiC or sapphire substrates. The GaN film is released and transferred onto arbitrary substrates. The post-released graphene/SiC substrate is reused for multiple growth and transfer cycles of GaN films. We demonstrate fully functional blue light-emitting diodes (LEDs) by growing LED stacks on reused graphene/SiC substrates followed by transfer onto plastic tapes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4836, "DOI": "10.1038/ncomms5836", "DOI Link": "http://dx.doi.org/10.1038/ncomms5836", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342983000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, H; Zeng, XD; Li, AG; Zhou, WY; Tang, L; Hu, WB; Fan, QL; Meng, XL; Deng, H; Duan, L; Li, YQ; Deng, ZX; Hong, XC; Xiao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Hui; Zeng, Xiaodong; Li, Anguo; Zhou, Wenyi; Tang, Lin; Hu, Wenbo; Fan, Quli; Meng, Xianli; Deng, Hai; Duan, Lian; Li, Yanqin; Deng, Zixin; Hong, Xuechuan; Xiao, Yuling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upconversion NIR-II fluorophores for mitochondria-targeted cancer imaging and photothermal therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NIR-II fluorophores have shown great promise for biomedical applications with superior in vivo optical properties. To date, few small-molecule NIR-II fluorophores have been discovered with donor-acceptor-donor (D-A-D) or symmetrical structures, and upconversion-mitochondria-targeted NIR-II dyes have not been reported. Herein, we report development of D-A type thiopyrylium-based NIR-II fluorophores with frequency upconversion luminescence (FUCL) at similar to 580nm upon excitation at similar to 850nm. H4-PEG-PT can not only quickly and effectively image mitochondria in live or fixed osteosarcoma cells with subcellular resolution at 1nM, but also efficiently convert optical energy into heat, achieving mitochondria-targeted photothermal cancer therapy without ROS effects. H4-PEG-PT has been further evaluated in vivo and exhibited strong tumor uptake, specific NIR-II signals with high spatial and temporal resolution, and remarkable NIR-II image-guided photothermal therapy. This report presents the first D-A type thiopyrylium NIR-II theranostics for synchronous upconversion-mitochondria-targeted cell imaging, in vivo NIR-II osteosarcoma imaging and excellent photothermal efficiency. Currently available mitochondria-targeted fluorescent dyes emit only one color in the visible or NIR-I and their applications are limited. Here, the authors develop upconversion mitochondria-targeted NIR-II fluorophores for synchronous upconversion-mitochondria-targeted cell imaging, in vivo NIR-II osteosarcoma imaging and photothermal efficiency", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6183, "DOI": "10.1038/s41467-020-19945-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19945-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000608522800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gilbert, C; Tang, TC; Ott, W; Dorr, BA; Shaw, WM; Sun, GL; Lu, TK; Ellis, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gilbert, Charlie; Tang, Tzu-Chieh; Ott, Wolfgang; Dorr, Brandon A.; Shaw, William M.; Sun, George L.; Lu, Timothy K.; Ellis, Tom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Living materials with programmable functionalities grown from engineered microbial co-cultures", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biological systems assemble living materials that are autonomously patterned, can self-repair and can sense and respond to their environment. The field of engineered living materials aims to create novel materials with properties similar to those of natural biomaterials using genetically engineered organisms. Here, we describe an approach to fabricating functional bacterial cellulose-based living materials using a stable co-culture of Saccharomyces cerevisiae yeast and bacterial cellulose-producing Komagataeibacter rhaeticus bacteria. Yeast strains can be engineered to secrete enzymes into bacterial cellulose, generating autonomously grown catalytic materials and enabling DNA-encoded modification of bacterial cellulose bulk properties. Alternatively, engineered yeast can be incorporated within the growing cellulose matrix, creating living materials that can sense and respond to chemical and optical stimuli. This symbiotic culture of bacteria and yeast is a flexible platform for the production of bacterial cellulose-based engineered living materials with potential applications in biosensing and biocatalysis. A symbiotic culture of bacteria and yeast is used to fabricate bacterial cellulose-based living materials that respond to external cues and adapt their structural and functional properties, with implications for sensing and catalytic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 20, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 691, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-00857-5", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-00857-5", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607023400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leung, CLA; Marussi, S; Atwood, RC; Towrie, M; Withers, PJ; Lee, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leung, Chu Lun Alex; Marussi, Sebastian; Atwood, Robert C.; Towrie, Michael; Withers, Philip J.; Lee, Peter D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ X-ray imaging of defect and molten pool dynamics in laser additive manufacturing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The laser-matter interaction and solidification phenomena associated with laser additive manufacturing (LAM) remain unclear, slowing its process development and optimisation. Here, through in situ and operando high-speed synchrotron X-ray imaging, we reveal the underlying physical phenomena during the deposition of the first and second layer melt tracks. We show that the laser-induced gas/vapour jet promotes the formation of melt tracks and denuded zones via spattering (at a velocity of 1 ms(-1)). We also uncover mechanisms of pore migration by Marangoni-driven flow (recirculating at a velocity of 0.4 m s(-1)), pore dissolution and dispersion by laser re-melting. We develop a mechanism map for predicting the evolution of melt features, changes in melt track morphology from a continuous hemi-cylindrical track to disconnected beads with decreasing linear energy density and improved molten pool wetting with increasing laser power. Our results clarify aspects of the physics behind LAM, which are critical for its development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 644, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1355, "DOI": "10.1038/s41467-018-03734-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03734-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429521200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, BQ; He, BW; Zhang, JJ; Li, LQ; Zhang, YZ; Yu, JG; Ran, JR; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Bingquan; He, Bowen; Zhang, Jianjun; Li, Laiquan; Zhang, Yanzhao; Yu, Jiaguo; Ran, Jingrun; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "TiO2/FePS3 S-Scheme Heterojunction for Greatly Raised Photocatalytic Hydrogen Evolution", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aggravating extreme climate changes and natural disasters stimulate the exploration of low-carbon/zero-carbon alternatives to traditional carbon-based fossil fuels. Solar-to-hydrogen (STH) transformation is considered as appealing route to convert renewable solar energy into carbon-free hydrogen. Restricted by the low efficiency and high cost of noble metal cocatalysts, high-performance and cost-effective photocatalysts are required to realize the realistic STH transformation. Herein, the 2D FePS3 (FPS) nullosheets anchored with TiO2 nulloparticles (TiO2/FePS3) are synthesized and tested for the photocatalytic hydrogen evolution reaction. With the integration of FPS, the photocatalytic H-2-evolution rate on TiO2/FePS3 is radically increased by approximate to 1686%, much faster than that of TiO2 alone. The origin of the greatly raised activity is revealed by theoretical calculations and various advanced characterizations, such as transient-state photoluminescence spectroscopy/surface photovoltage spectroscopy, in situ atomic force microscopy combined with Kelvin probe force microscopy (AFM-KPFM), in situ X-ray photoelectron spectroscopy (XPS), and synchrotron-based X-ray absorption near edge structure. Especially, the in situ AFM-KPFM and in situ XPS together confirm the electron transport pathway in TiO2/FePS3 with light illumination, unveiling the efficient separation/transfer of charge carrier in TiO2/FePS3 step-scheme heterojunction. This work sheds light on designing and fabricating novel 2D material-based S-scheme heterojunctions in photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 12, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202201449", "DOI Link": "http://dx.doi.org/10.1002/aenm.202201449", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000864401500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, SS; Yang, WS; Noh, JH; Suk, JH; Jeon, NJ; Park, JH; Kim, JS; Seong, WM; Seok, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Seong Sik; Yang, Woon Seok; Noh, Jun Hong; Suk, Jae Ho; Jeon, Nam Joong; Park, Jong Hoon; Kim, Ju Seong; Seong, Won Mo; Seok, Sang Il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance flexible perovskite solar cells exploiting Zn2SnO4 prepared in solution below 100 °C", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fabricating inorganic-organic hybrid perovskite solar cells (PSCs) on plastic substrates broadens their scope for implementation in real systems by imparting portability, conformability and allowing high-throughput production, which is necessary for lowering costs. Here we report a new route to prepare highly dispersed Zn2SnO4 (ZSO) nulloparticles at low-temperature (<100 degrees C) for the development of high-performance flexible PSCs. The introduction of the ZSO film significantly improves transmittance of flexible polyethylene naphthalate/indium-doped tin oxide (PEN/ITO)-coated substrate from similar to 75 to similar to 90% over the entire range of wavelengths. The best performing flexible PSC, based on the ZSO and CH3NH3PbI3 layer, exhibits steady-state power conversion efficiency (PCE) of 14.85% under AM 1.5G 100 mW . cm(-2) illumination. This renders ZSO a promising candidate as electron-conducting electrode for the highly efficient flexible PSC applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7410, "DOI": "10.1038/ncomms8410", "DOI Link": "http://dx.doi.org/10.1038/ncomms8410", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, YS; Lin, CL; Long, L; Masaki, T; Tang, M; Yang, LL; Liu, JJ; Huang, ZR; Li, ZY; Luo, XY; Lombardi, JR; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Yusi; Lin, Chenglong; Long, Li; Masaki, Tanemura; Tang, Mao; Yang, Lili; Liu, Jianjun; Huang, Zhengren; Li, Zhiyuan; Luo, Xiaoying; Lombardi, John R.; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Transfer Resonullce and Electromagnetic Enhancement Synergistically Enabling MXenes with Excellent SERS Sensitivity for SARS-CoV-2 S Protein Detection", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsNb2C and Ta2C MXenes exhibit remarkable SERS performance with the enhancement factors of 3.0x106 and 1.4x106, which is synergistically enabled by the PICT resonullce enhancement and electromagnetic enhancement.The excellent SERS sensitivity endows Ta2C MXene with the capability to sensitively detect and accurately identify the SARS-CoV-2 spike protein, which is beneficial to achieve real-time monitoring and early warning of novel coronavirus. AbstractThe outbreak of coronavirus disease 2019 has seriously threatened human health. Rapidly and sensitively detecting SARS-CoV-2 viruses can help control the spread of viruses. However, it is an arduous challenge to apply semiconductor-based substrates for virus SERS detection due to their poor sensitivity. Therefore, it is worthwhile to search novel semiconductor-based substrates with excellent SERS sensitivity. Herein we report, for the first time, Nb2C and Ta2C MXenes exhibit a remarkable SERS enhancement, which is synergistically enabled by the charge transfer resonullce enhancement and electromagnetic enhancement. Their SERS sensitivity is optimized to 3.0x10(6) and 1.4x10(6) under the optimal resonullce excitation wavelength of 532 nm. Additionally, remarkable SERS sensitivity endows Ta2C MXenes with capability to sensitively detect and accurately identify the SARS-CoV-2 spike protein. Moreover, its detection limit is as low as 5x10(-9) M, which is beneficial to achieve real-time monitoring and early warning of novel coronavirus. This research not only provides helpful theoretical guidance for exploring other novel SERS-active semiconductor-based materials but also provides a potential candidate for the practical applications of SERS technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 52, "DOI": "10.1007/s40820-020-00565-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00565-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000608047300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Min, JH; Demchyshyn, S; Sempionatto, JR; Song, Y; Hailegnaw, B; Xu, CH; Yang, YR; Solomon, S; Putz, C; Lehner, LE; Schwarz, JF; Schwarzinger, C; Scharber, MC; Sani, ES; Kaltenbrunner, M; Gao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Min, Jihong; Demchyshyn, Stepan; Sempionatto, Juliane R.; Song, Yu; Hailegnaw, Bekele; Xu, Changhao; Yang, Yiran; Solomon, Samuel; Putz, Christoph; Lehner, Lukas E.; Schwarz, Julia Felicitas; Schwarzinger, Clemens; Scharber, Markus Clark; Sani, Ehsan Shirzaei; Kaltenbrunner, Martin; Gao, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An autonomous wearable biosensor powered by a perovskite solar cell", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A wearable sweat sensor powered by a flexible solar cell can continuously collect multimodal physicochemical data-glucose, pH, sodium ion, sweat rate and skin temperature-across indoor and outdoor physical activities for over 12 h. Wearable sweat sensors can potentially be used to continuously and non-invasively monitor physicochemical biomarkers that contain information related to disease diagnostics and fitness tracking. However, the development of such autonomous sensors faces a number of challenges including achieving steady sweat extraction for continuous and prolonged monitoring and addressing the high power demands of multifunctional and complex analysis. Here we report an autonomous wearable biosensor that is powered by a perovskite solar cell and can provide continuous and non-invasive metabolic monitoring. The device uses a flexible quasi-two-dimensional perovskite solar cell module that provides ample power under outdoor and indoor illumination conditions (power conversion efficiency exceeding 31% under indoor light illumination). We show that the wearable device can continuously collect multimodal physicochemical data-glucose, pH, sodium ion, sweat rate and skin temperature-across indoor and outdoor physical activities for over 12 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41928-023-00996-y", "DOI Link": "http://dx.doi.org/10.1038/s41928-023-00996-y", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032822700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HB; Zhang, XC; Yang, P; Zhao, JX; Zhang, W; Feng, NP; Yang, WL; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Haibao; Zhang, Xingcai; Yang, Peng; Zhao, Jiaxu; Zhang, Wei; Feng, Nianping; Yang, Wuli; Tang, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect self-assembly of metal-organic framework triggers ferroptosis to overcome resistance", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of multidrug treatment resistance presents a hurdle for the successful chemotherapy of tumours. Ferroptosis, resulting from the iron-dependent accumulation of lipid peroxides, has the potential to reverse multidrug resistance. However, simultaneous delivery of the iron sources, ferroptosis inducers, drugs, and enhanced circulation carriers within matrices remains a significant challenge. Herein, we designed and fabricated a defect self-assembly of metal-organic framework (MOF)-red blood cell (RBC) membrane-camouflaged multi-drug-delivery nulloplatform for combined ferroptosis-apoptosis treatment of multidrug-resistant cancer. Ferroptosis and chemotherapeutic drugs are embedded in the centre of the iron (III)-based MOF at defect sites by coordination with metal clusters during a one-pot solvothermal synthesis process. The RBC membrane could camouflage the nulloplatform for longer circulation. Our results demonstrate that this defect self-assemblyenabled MOF-membrane-camouflaged nulloplatform could deplete the glutathione, amplify the reactive oxidative species oxidative stress, and enable remarkable anticancer properties. Our work provides an alternative strategy for overcoming multidrug resistance, which could regulate the fluidity and permeability of the cell membrane by ferroptosis to downregulate of P-glycoprotein protein expression by ferroptosis. This defect selfassembly-enabled MOF-membrane-camouflaged multi-drug-delivery nulloplatform has great therapeutic potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 11, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.12.018", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.12.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788642400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YN; He, J; Chen, H; Chen, JS; Zhu, RD; Ma, P; Towers, A; Lin, Y; Gesquiere, AJ; Wu, ST; Dong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yanull; He, Juan; Chen, Hao; Chen, Jiangshan; Zhu, Ruidong; Ma, Pin; Towers, Andrew; Lin, Yuan; Gesquiere, Andre J.; Wu, Shin-Tson; Dong, Yajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastable, Highly Luminescent Organic-Inorganic Perovskite-Polymer Composite Films", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A simple yet general swelling-deswelling microencapsulation strategy has been developed to achieve well dispersed and intimately passivated crystalline organic-inorganic perovskites nulloparticles within polymer matrixes and results in a series of highly luminescent CH3NH3PbBr3 (MAPbBr(3))-polymer composite films with unprecedented water and thermal stabilities and superior color purity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2016, "Volume": 28, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10710, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201603964", "DOI Link": "http://dx.doi.org/10.1002/adma.201603964", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392728200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tu, KK; Puértolas, B; Adobes-Vidal, M; Wang, YR; Sun, JG; Traber, J; Burgert, I; Pérez-Ramírez, J; Keplinger, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tu, Kunkun; Puertolas, Begona; Adobes-Vidal, Maria; Wang, Yaru; Sun, Jianguo; Traber, Jacqueline; Burgert, Ingo; Perez-Ramirez, Javier; Keplinger, Tobias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green Synthesis of Hierarchical Metal-Organic Framework/Wood Functional Composites with Superior Mechanical Properties", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The applicability of advanced composite materials with hierarchical structure that conjugate metal-organic frameworks (MOFs) with macroporous materials is commonly limited by their inferior mechanical properties. Here, a universal green synthesis method for the in situ growth of MOF nullocrystals within wood substrates is introduced. Nucleation sites for different types of MOFs are readily created by a sodium hydroxide treatment, which is demonstrated to be broadly applicable to different wood species. The resulting MOF/wood composite exhibits hierarchical porosity with 130 times larger specific surface area compared to native wood. Assessment of the CO2 adsorption capacity demonstrates the efficient utilization of the MOF loading along with similar adsorption ability to that of pure MOF. Compression and tensile tests reveal superior mechanical properties, which surpass those obtained for polymer substrates. The functionalization strategy offers a stable, sustainable, and scalable platform for the fabrication of multifunctional MOF/wood-derived composites with potential applications in environmental- and energy-related fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902897, "DOI": "10.1002/advs.201902897", "DOI Link": "http://dx.doi.org/10.1002/advs.201902897", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511285400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, J; Kremer, F; Walter, D; Wu, YL; Ji, Y; Xiang, J; Liu, WZ; Duong, T; Shen, HP; Lu, T; Brink, F; Zhong, DY; Li, L; Lem, OLC; Liu, Y; Weber, KJ; White, TP; Catchpole, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jun; Kremer, Felipe; Walter, Daniel; Wu, Yiliang; Ji, Yi; Xiang, Jin; Liu, Wenzhu; Duong, The; Shen, Heping; Lu, Teng; Brink, Frank; Zhong, Dingyong; Li, Li; Lee Cheong Lem, Olivier; Liu, Yun; Weber, Klaus J.; White, Thomas P.; Catchpole, Kylie R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Centimetre-scale perovskite solar cells with fill factors of more than 86 per cent", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to rapid development in their efficiency(1) and stability(2), perovskite solar cells are at the forefront of emerging photovoltaic technologies. State-of-the-art cells exhibit voltage losses(3-8) approaching the theoretical minimum and near-unity internal quantum efficiency(9-13), but conversion efficiencies are limited by the fill factor (<83%, below the Shockley-Queisser limit of approximately 90%). This limitation results from non-ideal charge transport between the perovskite absorber and the cell's electrodes(5,8,13-16). Reducing the electrical series resistance of charge transport layers is therefore crucial for improving efficiency. Here we introduce a reverse-doping process to fabricate nitrogen-doped titanium oxide electron transport layers with outstanding charge transport performance. By incorporating this charge transport material into perovskite solar cells, we demonstrate 1-cm(2) cells with fill factors of >86%, and an average fill factor of 85.3%. We also report a certified steady-state efficiency of 22.6% for a 1-cm(2) cell (23.33% +/- 0.58% from a reverse current-voltage scan).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2022, "Volume": 601, "Issue": 7894, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 573, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04216-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04216-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749546400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Srinivas, G; Krungleviciute, V; Guo, ZX; Yildirim, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Srinivas, Gadipelli; Krungleviciute, Vaiva; Guo, Zheng-Xiao; Yildirim, Taner", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional CO2 capture in a hierarchically porous carbon with simultaneous high surface area and pore volume", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new type of hierarchically porous carbon (HPC) structures of simultaneously high surface area and high pore volume has been synthesised from carefully controlled carbonization of in-house optimised metal-organic frameworks (MOFs). Changes in synthesis conditions lead to millimetre-sized MOF-5 crystals in a high yield. Subsequent carbonization of the MOFs yield HPCs with simultaneously high surface area, up to 2734 m(2) g(-1), and exceptionally high total pore volume, up to 5.53 cm(3) g(-1). In the HPCs, micropores are mostly retained and meso- and macro- pores are generated from defects in the individual crystals, which is made possible by structural inheritance from the MOF precursor. The resulting HPCs show a significant amount of CO2 adsorption, over 27 mmol g(-1) (119 wt%) at 30 bar and 27 degrees C, which is one of the highest values reported in the literature for porous carbons. The findings are comparatively analysed with the literature. The results show great potential for the development of high capacity carbon-based sorbents for effective pre-combustion CO2 capture and other gas and energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 335, "End Page": 342, "Article Number": null, "DOI": "10.1039/c3ee42918k", "DOI Link": "http://dx.doi.org/10.1039/c3ee42918k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329550700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, MR; Chan, MKY; Sun, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Min-Rui; Chan, Maria K. Y.; Sun, Yugang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edge-terminated molybdenum disulfide with a 9.4-Å interlayer spacing for electrochemical hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered molybdenum disulfide has demonstrated great promise as a low-cost alternative to platinum-based catalysts for electrochemical hydrogen production from water. Research effort on this material has focused mainly on synthesizing highly nullostructured molybdenum disulfide that allows the exposure of a large fraction of active edge sites. Here we report a promising microwave-assisted strategy for the synthesis of narrow molybdenum disulfide nullosheets with edge-terminated structure and a significantly expanded interlayer spacing, which exhibit striking kinetic metrics with onset potential of -103mV, Tafel slope of 49mV per decade and exchange current density of 9.62 X 10(-3) mAcm(-2), performing among the best of current molybdenum disulfide catalysts. Besides benefits from the edge-terminated structure, the expanded interlayer distance with modified electronic structure is also responsible for the observed catalytic improvement, which suggests a potential way to design newly advanced molybdenum disulfide catalysts through modulating the interlayer distance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 598, "Times Cited, All Databases": 623, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7493, "DOI": "10.1038/ncomms8493", "DOI Link": "http://dx.doi.org/10.1038/ncomms8493", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358844700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WY; Tagawa, M; Xin, HLL; Wang, T; Emamy, H; Li, HL; Yager, KG; Starr, FW; Tkachenko, AV; Gang, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wenyan; Tagawa, Miho; Xin, Huolin L.; Wang, Tong; Emamy, Hamed; Li, Huilin; Yager, Kevin G.; Starr, Francis W.; Tkachenko, Alexei V.; Gang, Oleg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diamond family of nulloparticle superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diamond lattices formed by atomic or colloidal elements exhibit remarkable functional properties. However, building such structures via self-assembly has proven to be challenging because of the low packing fraction, sensitivity to bond orientation, and local heterogeneity. We report a strategy for creating a diamond superlattice of nullo-objects via self-assembly and demonstrate its experimental realization by assembling two variant diamond lattices, one with and one without atomic analogs. Our approach relies on the association between anisotropic particles with well-defined tetravalent binding topology and isotropic particles. The constrained packing of triangular binding footprints of truncated tetrahedra on a sphere defines a unique three-dimensional lattice. Hence, the diamond self-assembly problem is solved via its mapping onto two-dimensional triangular packing on the surface of isotropic spherical particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2016, "Volume": 351, "Issue": 6273, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 582, "End Page": 586, "Article Number": null, "DOI": "10.1126/science.aad2080", "DOI Link": "http://dx.doi.org/10.1126/science.aad2080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369291600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, H; Zhang, MH; Cheng, Z; Jiang, HY; Yang, JG; Wang, PF; He, P; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Hui; Zhang, Menghang; Cheng, Zhu; Jiang, Heyang; Yang, Jingui; Wang, Pengfei; He, Ping; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-free and binder-free Li-Al alloy anode enabling an all-solid-state Li-S battery with high energy and stability", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Incompatibility of electrolytes with Li anode impedes the application of solid-state batteries. Aluminum with appropriate potential, high-capacity, and electronic conductivity can alloy with Li spontaneously and is proposed herein as a carbon-free and binder-free anode of an all-solid-state Li-S battery (LSB). A biphasic lithiation reaction of Al with modest volume change was revealed by in situ characterization. The Li0.8Al alloy anode showed excellent compatibility toward the Li10GeP2S12 (LGPS) electrolyte, as verified by the steady Li0.8Al-LGPS-Li0.8Al cell operation for over 2500 hours at 0.5 mA cm(-2). An all-solid-state LSB comprising Li0.8Al alloy anode and melting-coated S composite cathode functioned steadily for over 200 cycles with a capacity retention of 93.29%. Furthermore, a Li-S full cell with a low negative-to-positive ratio of 1.125 delivered a specific energy of 541 Wh kg(-1). This work provides an applicable anode selection for all-solid-state LSBs and promotes their practical procedure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabn4372", "DOI": "10.1126/sciadv.abn4372", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abn4372", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786201300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, HL; Wang, JH; Tao, Z; Huang, JC; Rao, P; Kurokawa, T; Gong, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Hailong; Wang, Jiahui; Tao, Zhen; Huang, Junchao; Rao, Ping; Kurokawa, Takayuki; Gong, Jian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adjacent cationic-aromatic sequences yield strong electrostatic adhesion of hydrogels in seawater", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrostatic interaction is strong but usually diminishes in high ionic-strength environments. Biosystems can use this interaction through adjacent cationic-aromatic amino acids sequence of proteins even in a saline medium. Application of such specific sequence to the development of cationic polymer materials adhesive to negatively charged surfaces in saline environments is challenging due to the difficulty in controlling the copolymer sequences. Here, we discover that copolymers with adjacent cation-aromatic sequences can be synthesized through cation-ic complex-aided free-radical polymerization. Sequence controlled hydrogels from diverse cation/aromatic monomers exhibit fast, strong but reversible adhesion to negatively charged surfaces in seawater. Aromatics on copolymers are found to enhance the electrostatic interactions of their adjacent cationic residues to the counter surfaces, even in a high ionic-strength medium that screens the electrostatic interaction for common polyelectrolytes. This work opens a pathway to develop adhesives using saline water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5127, "DOI": "10.1038/s41467-019-13171-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13171-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495858500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Terryn, S; Brancart, J; Lefeber, D; Van Assche, G; Vanderborght, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Terryn, Seppe; Brancart, Joost; Lefeber, Dirk; Van Assche, Guy; Vanderborght, Bram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-healing soft pneumatic robots", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the compliance found in many organisms, soft robots are made almost entirely out of flexible, soft material, making them suitable for applications in uncertain, dynamic task environments, including safe human-robot interactions. Their intrinsic compliance absorbs shocks and protects them against mechanical impacts. However, the soft materials used for their construction are highly susceptible to damage, such as cuts and perforations caused by sharp objects present in the uncontrolled and unpredictable environments they operate in. In this research, we propose to construct soft robotics entirely out of self-healing elastomers. On the basis of healing capacities found in nature, these polymers are given the ability to heal microscopic and macroscopic damage. Diels-Alder polymers, being thermoreversible covalent networks, were used to develop three applications of self-healing soft pneumatic actuators (a soft gripper, a soft hand, and artificial muscles). Soft pneumatic actuators commonly experience perforations and leaks due to excessive pressures or wear during operation. All three prototypes were designed using finite element modeling and mechanically characterized. The manufacturing method of the actuators exploits the self-healing behavior of the materials, which can be recycled. Realistic macroscopic damage could be healed entirely using a mild heat treatment. At the location of the scar, no weak spots were created, and the full performance of the actuators was nearly completely recovered after healing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2017, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaan4268", "DOI": "10.1126/scirobotics.aan4268", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.aan4268", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441523900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WH; Sun, Y; Zhang, JS; Li, FS; Guo, MH; Zhao, YF; Zhang, HM; Peng, JP; Xing, Y; Wang, HC; Fujita, T; Hirata, A; Li, Z; Ding, H; Tang, CJ; Wang, M; Wang, QY; He, K; Ji, SH; Chen, X; Wang, JF; Xia, ZC; Li, L; Wang, YY; Wang, J; Wang, LL; Chen, MW; Xue, QK; Ma, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang Wen-Hao; Sun Yi; Zhang Jin-Song; Li Fang-Sen; Guo Ming-Hua; Zhao Yan-Fei; Zhang Hui-Min; Peng Jun-Ping; Xing Ying; Wang Hui-Chao; Fujita, Takeshi; Hirata, Akihiko; Li Zhi; Ding Hao; Tang Chen-Jia; Wang Meng; Wang Qing-Yan; He Ke; Ji Shuai-Hua; Chen Xi; Wang Jun-Feng; Xia Zheng-Cai; Li Liang; Wang Ya-Yu; Wang Jian; Wang Li-Li; Chen Ming-Wei; Xue Qi-Kun; Ma Xu-Cun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Observation of High-Temperature Superconductivity in One-Unit-Cell FeSe Films", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We prepared one-unit-cell (1-UC) thick FeSe films on insulating SrTiO3 substrates with non-superconducting FeTe protection layers by molecular beam epitaxy for ex situ studies. By direct transport and magnetic measurements, we provide definitive evidence for high temperature superconductivity in the 1-UC FeSe films with an onset T-C above 40K and an extremely large critical current density J(C) similar to 1.7x10(6) A/cm(2) at 2 K, which are much higher than T-C similar to 8K and J(C)similar to 10(4) A/cm(2) for bulk FeSe, respectively. Our work may pave the way to enhancing and tailoring superconductivity by interface engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 31, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17401, "DOI": "10.1088/0256-307X/31/1/017401", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/31/1/017401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330208000040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akkerman, QA; Nguyen, TPT; Boehme, SC; Montanarella, F; Dirin, DN; Wechsler, P; Beiglböck, F; Rainò, G; Erni, R; Katan, C; Even, J; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akkerman, Quinten A.; Nguyen, Tan P. T.; Boehme, Simon C.; Montanarella, Federico; Dirin, Dmitry N.; Wechsler, Philipp; Beiglbock, Finn; Raino, Gabriele; Erni, Rolf; Katan, Claudine; Even, Jacky; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling the nucleation and growth kinetics of lead halide perovskite quantum dots", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal lead halide perovskite nullocrystals are of interest as photoluminescent quantum dots (QDs) whose properties depend on the size and shape. They are normally synthesized on subsecond time scales through hard-to-control ionic metathesis reactions. We report a room-temperature synthesis of monodisperse, isolable, spheroidal APbBr(3) QDs (A indicates cesium, formamidinium, and methylammonium) that are size tunable from 3 to >13 nullometers. The kinetics of both nucleation and growth are temporally separated and substantially slowed down by the intricate equilibrium between the precursor (PbBr2) and the A[PbBr3] solute, with the latter serving as a monomer. QDs of all these compositions exhibit up to four excitonic transitions in their linear absorption spectra, and we demonstrate that the size-dependent confinement energy for all transitions is independent of the A-site cation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 377, "Issue": 6613, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1406, "End Page": 1412, "Article Number": null, "DOI": "10.1126/science.abq3616", "DOI Link": "http://dx.doi.org/10.1126/science.abq3616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000887934300034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Ma, LL; Fan, FF; Zeng, Z; Peng, C; Loya, PE; Liu, Z; Gong, YJ; Zhang, JN; Zhang, XX; Ajayan, PM; Zhu, T; Lou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Ma, Lulu; Fan, Feifei; Zeng, Zhi; Peng, Cheng; Loya, Phillip E.; Liu, Zheng; Gong, Yongji; Zhang, Jiangnull; Zhang, Xingxiang; Ajayan, Pulickel M.; Zhu, Ting; Lou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fracture toughness of graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perfect graphene is believed to be the strongest material. However, the useful strength of large-area graphene with engineering relevance is usually determined by its fracture toughness, rather than the intrinsic strength that governs a uniform breaking of atomic bonds in perfect graphene. To date, the fracture toughness of graphene has not been measured. Here we report an in situ tensile testing of suspended graphene using a nullomechanical device in a scanning electron microscope. During tensile loading, the pre-cracked graphene sample fractures in a brittle manner with sharp edges, at a breaking stress substantially lower than the intrinsic strength of graphene. Our combined experiment and modelling verify the applicability of the classic Griffith theory of brittle fracture to graphene. The fracture toughness of graphene is measured as the critical stress intensity factor of 4.0 +/- 0.6 MPa root m and the equivalent critical strain energy release rate of 15.9 Jm(-2). Our work quantifies the essential fracture properties of graphene and provides mechanistic insights into the mechanical failure of graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 599, "Times Cited, All Databases": 685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3782, "DOI": "10.1038/ncomms4782", "DOI Link": "http://dx.doi.org/10.1038/ncomms4782", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335375400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YG; Hao, JC; Song, H; Zhang, FY; Bai, XH; Meng, XG; Zhang, HY; Wang, SF; Hu, Y; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yaguang; Hao, Jianchao; Song, Hui; Zhang, Fengyu; Bai, Xianhua; Meng, Xianguang; Zhang, Hongyuan; Wang, Shufang; Hu, Yong; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective light absorber-assisted single nickel atom catalysts for ambient sunlight-driven CO2 methanation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient sunlight-driven CO2 methanation cannot be realized due to the temperature being less than 80 degrees C upon irradiation with dispersed solar energy. In this work, a selective light absorber was used to construct a photothermal system to generate a high temperature (up to 288 degrees C) under weak solar irradiation (1 kW m(-2)), and this temperature is three times higher than that in traditional photothermal catalysis systems. Moreover, ultrathin amorphous Y2O3 nullosheets with confined single nickel atoms (SA Ni/Y2O3) were synthesized, and they exhibited superior CO2 methanation activity. As a result, 80% CO2 conversion efficiency and a CH4 production rate of 7.5 L m(-2) h(-1) were achieved through SA Ni/Y2O3 under solar irradiation (from 0.52 to 0.7 kW m(-2)) when assisted by a selective light absorber, demonstrating that this system can serve as a platform for directly harnessing dispersed solar energy to convert CO2 to valuable chemicals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2359, "DOI": "10.1038/s41467-019-10304-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10304-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469320900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miriyev, A; Stack, K; Lipson, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miriyev, Aslan; Stack, Kenneth; Lipson, Hod", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft material for soft actuators", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by natural muscle, a key challenge in soft robotics is to develop self-contained electrically driven soft actuators with high strain density. Various characteristics of existing technologies, such as the high voltages required to trigger electroactive polymers (> 1KV), low strain (< 10%) of shape memory alloys and the need for external compressors and pressure-regulating components for hydraulic or pneumatic fluidicelastomer actuators, limit their practicality for untethered applications. Here we show a single self-contained soft robust composite material that combines the elastic properties of a polymeric matrix and the extreme volume change accompanying liquid-vapor transition. The material combines a high strain (up to 900%) and correspondingly high stress (up to 1.3 MPa) with low density (0.84 g cm(-3)). Along with its extremely low cost (about 3 cent per gram), simplicity of fabrication and environment-friendliness, these properties could enable new kinds of electrically driven entirely soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 615, "Times Cited, All Databases": 688, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 596, "DOI": "10.1038/s41467-017-00685-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00685-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411166900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YK; Liu, WL; Wang, Z; He, WC; Tang, Q; Xi, Y; Wang, X; Guo, HY; Hu, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yike; Liu, Wenlin; Wang, Zhao; He, Wencong; Tang, Qian; Xi, Yi; Wang, Xue; Guo, Hengyu; Hu, Chenguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying contact status and the air-breakdown model of charge-excitation triboelectric nullogenerators to maximize charge density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface charge density is the key factor for developing high performance triboelectric nullogenerators (TENG). The previously invented charge excitation TENG provides a most efficient way to achieve maximum charge output of a TENG device. Herein, criteria to quantitatively evaluate the contact efficiency and air breakdown model on charge excitation TENG are established to enhance and evaluate charge density. The theoretical results are further verified by systematic experiments. A high average charge density up to 2.38 mC m(-2) is achieved using the 4 mu m PEI film and homemade carbon/silicone gel electrode in ambient atmosphere with 5% relative humidity. This work also reveals the actual charge density (over 4.0 mC m(-2)) in a TENG electrode based on quantified surface micro-contact efficiency and provides a prospective technical approach to improve the charge density, which could push the output performance of TENG to a new horizon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1599, "DOI": "10.1038/s41467-020-15368-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15368-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522437900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muller, GA; Cook, JB; Kim, HS; Tolbert, SH; Dunn, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muller, Guillaume A.; Cook, John B.; Kim, Hyung-Seok; Tolbert, Sarah H.; Dunn, Bruce", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Performance Pseudocapacitor Based on 2D Layered Metal Chalcogenide nullocrystals", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-layer and few-layer transition metal dichalcogenides have been extensively studied for their electronic properties, but their energy-storage potential has not been well explored. ThiS:paper describes the structural and electrochemical properties of few-layer TiS2, nullocrystals. The two-dimensional morphology leads to very different behavior, compared to corresponding bulk materials. Only small structural changes occur during lithiation/delithiation and charge: storage characteristic's are consistent with intercalation pseudocapacitance, leading to materials that exhibit both high energYand power density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 554, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1911, "End Page": 1917, "Article Number": null, "DOI": "10.1021/nl504764m", "DOI Link": "http://dx.doi.org/10.1021/nl504764m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351188000071", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, M; Graves, CE; Li, C; Li, YN; Ge, N; Montgomery, E; Davila, N; Jiang, H; Williams, RS; Yang, JJS; Xia, QF; Strachan, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Miao; Graves, Catherine E.; Li, Can; Li, Yunning; Ge, Ning; Montgomery, Eric; Davila, Noraica; Jiang, Hao; Williams, R. Stanley; Yang, J. Joshua; Xia, Qiangfei; Strachan, John Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Memristor-Based Analog Computation and Neural Network Classification with a Dot Product Engine", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using memristor crossbar arrays to accelerate computations is a promising approach to efficiently implement algorithms in deep neural networks. Early demonstrations, however, are limited to simulations or small-scale problems primarily due to materials and device challenges that limit the size of the memristor crossbar arrays that can be reliably programmed to stable and analog values, which is the focus of the current work. High-precision analog tuning and control of memristor cells across a 128 x 64 array is demonstrated, and the resulting vector matrix multiplication (VMM) computing precision is evaluated. Single-layer neural network inference is performed in these arrays, and the performance compared to a digital approach is assessed. Memristor computing system used here reaches a VMM accuracy equivalent of 6 bits, and an 89.9% recognition accuracy is achieved for the 10k MNIST handwritten digit test set. Forecasts show that with integrated (on chip) and scaled memristors, a computational efficiency greater than 100 trillion operations per second per Watt is possible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 590, "Times Cited, All Databases": 638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 30, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705914, "DOI": "10.1002/adma.201705914", "DOI Link": "http://dx.doi.org/10.1002/adma.201705914", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426491600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, LL; Ou, PF; Liu, W; Wang, X; Wang, HT; Zhang, R; Pao, CW; Liu, XJ; Pong, WF; Song, J; Zhuang, ZB; Mirkin, M; Luo, J; Xin, HLL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Lili; Ou, Pengfei; Liu, Wei; Wang, Xiang; Wang, Hsiao-Tsu; Zhang, Rui; Pao, Chih-Wen; Liu, Xijun; Pong, Way-Faung; Song, Jun; Zhuang, Zhongbin; Mirkin, Michael, V; Luo, Jun; Xin, Huolin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Ru-Ni diatomic sites for efficient alkaline hydrogen oxidation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anion exchange membrane fuel cells are limited by the slow kinetics of alkaline hydrogen oxidation reaction (HOR). Here, we establish HOR catalytic activities of single-atom and diatomic sites as a function of *H and *OH binding energies to screen the optimal active sites for the HOR. As a result, the Ru-Ni diatomic one is identified as the best active center. Guided by the theoretical finding, we subsequently synthesize a catalyst with Ru-Ni diatomic sites supported on N-doped porous carbon, which exhibits excellent catalytic activity, CO tolerance, and stability for alkaline HOR and is also superior to single-site counterparts. In situ scanning electrochemical microscopy study validates the HOR activity resulting from the Ru-Ni diatomic sites. Furthermore, in situ x-ray absorption spectroscopy and computational studies unveil a synergistic interaction between Ru and Ni to promote the molecular H-2 dissociation and strengthen OH adsorption at the diatomic sites, and thus enhance the kinetics of HOR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2022, "Volume": 8, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm3779", "DOI": "10.1126/sciadv.abm3779", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm3779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808053900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Wang, GY; van der Wal, LI; Cheng, K; Zhang, QH; de Jong, KP; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuhao; Wang, Genyuan; van der Wal, Lars I.; Cheng, Kang; Zhang, Qinghong; de Jong, Krijn P.; Wang, Ye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualizing Element Migration over Bifunctional Metal-Zeolite Catalysts and its Impact on Catalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic performance of composite catalysts is not only affected by the physicochemical properties of each component, but also the proximity and interaction between them. Herein, we employ four representative oxides (In2O3, ZnO, Cr2O3, and ZrO2) to combine with H-ZSM-5 for the hydrogenation of CO2 to hydrocarbons directed by methanol intermediate and clarify the correlation between metal migration and the catalytic performance. The migration of metals to zeolite driven by the harsh reaction conditions can be visualized by electron microscopy, meanwhile, the change of zeolite acidity is also carefully characterized. The protonic sites of H-ZSM-5 are neutralized by mobile indium and zinc species via a solid ion-exchange mechanism, resulting in a drastic decrease of C2+ hydrocarbon products over In2O3/H-ZSM-5 and ZnO/H-ZSM-5. While, the thermomigration ability of chromium and zirconium species is not significant, endowing Cr2O3/H-ZSM-5 and ZrO2/H-ZSM-5 catalysts with high selectivity of C2+ hydrocarbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2021, "Volume": 60, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17735, "End Page": 17743, "Article Number": null, "DOI": "10.1002/anie.202107264", "DOI Link": "http://dx.doi.org/10.1002/anie.202107264", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000668286600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seyler, KL; Schaibley, JR; Gong, P; Rivera, P; Jones, AM; Wu, SF; Yan, JQ; Mandrus, DG; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seyler, Kyle L.; Schaibley, John R.; Gong, Pu; Rivera, Pasqual; Jones, Aaron M.; Wu, Sanfeng; Yan, Jiaqiang; Mandrus, David G.; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical control of second-harmonic generation in a WSe2 monolayer transistor", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonlinear optical frequency conversion, in which optical fields interact with a nonlinear medium to produce new field frequencies(1), is ubiquitous in modern photonic systems. However, the nonlinear electric susceptibilities that give rise to such phenomena are often challenging to tune in a given material and, so far, dynamical control of optical nonlinearities remains confined to research laboratories as a spectroscopic tool(2). Here, we report a mechanism to electrically control second-order optical nonlinearities in monolayer WSe2, an atomically thin semiconductor. We show that the intensity of second-harmonic generation at the A-exciton resonullce is tunable by over an order of magnitude at low temperature and nearly a factor of four at room temperature through electrostatic doping in a field-effect transistor. Such tunability arises from the strong exciton charging effects in monolayer semiconductors(3,4), which allow for exceptional control over the oscillator strengths at the exciton and trion resonullces. The exciton-enhanced second-harmonic generation is counter-circularly polarized to the excitation laser due to the combination of the two-photon and one-photon valley selection rules(5-8), which have opposite helicity in the monolayer. Our study paves the way towards a new platform for chip-scale, electrically tunable nonlinear optical devices based on two-dimensional semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 407, "End Page": 411, "Article Number": null, "DOI": "10.1038/NnullO.2015.73", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2015.73", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354094900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Downie, LE; Ma, L; Qiu, WD; Dahn, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jing; Downie, Laura E.; Ma, Lin; Qiu, Wenda; Dahn, J. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study of the Failure Mechanisms of LiNi0.8Mn0.1Co0.1O2 Cathode Material for Lithium Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "LiNi0.8Mn0.1Co0.1O2 (NMC811) can deliver a high capacity of similar to 200 mAh/g with an average discharge potential of similar to 3.8 V (vs. Li+/Li), making it a promising positive electrode material for high energy density lithium ion batteries. However, electrochemical tests from half cells and full cells show poor cycling performance when charged to potentials above 4.2 V. The calendar and cycle lifetimes of cells are affected by the structural stability of the active electrode materials as well as the parasitic reactions that occur in lithium ion batteries. In order to explore the major failure mechanisms of the material, half cells (coin cells) with control electrolyte and full cells (pouch cells) with control electrolyte and with selected electrolyte additives were tested over four different potential ranges. Isothermal microcalorimetry was used to explore the parasitic reactions and their potential dependence. In-situ and ex-situ X-ray diffraction and scanning electron microscopy were used to investigate the structural and morphological degradation of the materials over cycling. It was found that the dramatic c-axis change of the active material during charge and discharge may not be the major problem for cells that are cycled to higher potentials. The parasitic reactions that arise from the interactions between the electrolyte and the highly reactive delithiated cathode surface at high potentials are suggested as the main reason for the failure of cells cycled above 4.2 V. It should be possible to further improve the performance of NMC811 at high potentials by modifying the cathode surface and/or identifying and using electrolyte blends which reduce parasitic reactions. (C) The Author(s) 2015. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 162, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A1401", "End Page": "A1408", "Article Number": null, "DOI": "10.1149/2.1011507jes", "DOI Link": "http://dx.doi.org/10.1149/2.1011507jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355643700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SY; Xu, JM; Zou, LY; Luo, SL; Yao, R; Zheng, BN; Liang, GB; Wu, DC; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuyi; Xu, Jianmeng; Zou, Leiyan; Luo, Shulu; Yao, Run; Zheng, Bingna; Liang, Guobin; Wu, Dingcai; Li, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-lasting renewable antibacterial porous polymeric coatings enable titanium biomaterials to prevent and treat peri-implant infection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peri-implant infection is one of the biggest threats to the success of dental implant. Existing coatings on titanium surfaces exhibit rapid decrease in antibacterial efficacy, which is difficult to promisingly prevent peri-implant infection. Herein, we report an N-halamine polymeric coating on titanium surface that simultaneously has long-lasting renewable antibacterial efficacy with good stability and biocompatibility. Our coating is powerfully biocidal against both main pathogenic bacteria of peri-implant infection and complex bacteria from peri-implantitis patients. More importantly, its antibacterial efficacy can persist for a long term (e.g., 12-16 weeks) in vitro, in animal model, and even in human oral cavity, which generally covers the whole formation process of osseointegrated interface. Furthermore, after consumption, it can regain its antibacterial ability by facile rechlorination, highlighting a valuable concept of renewable antibacterial coating in dental implant. These findings indicate an appealing application prospect for prevention and treatment of peri-implant infection. Infection is a major problem for dental implants with current antibacterial coatings losing efficacy quickly. Here, the authors report on the N-halamine polymeric coating of titanium implants to create a long-lasting renewable antibacterial layer and demonstrate application in vivo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3303, "DOI": "10.1038/s41467-021-23069-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23069-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661571900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HR; Zhang, XY; Wu, QQ; Cao, F; Yang, DW; Shang, YQ; Ning, ZJ; Zhang, W; Zheng, WT; Yan, YF; Kershaw, SV; Zhang, LJ; Rogach, AL; Yang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haoran; Zhang, Xiaoyu; Wu, Qianqian; Cao, Fan; Yang, Dongwen; Shang, Yuequn; Ning, Zhijun; Zhang, Wei; Zheng, Weitao; Yan, Yanfa; Kershaw, Stephen V.; Zhang, Lijun; Rogach, Andrey L.; Yang, Xuyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trifluoroacetate induced small-grained CsPbBr3 perovskite films result in efficient and stable light-emitting devices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum efficiencies of organic-inorganic hybrid lead halide perovskite light-emitting devices (LEDs) have increased significantly, but poor device operational stability still impedes their further development and application. All-inorganic perovskites show better stability than the hybrid counterparts, but the performance of their respective films used in LEDs is limited by the large perovskite grain sizes, which lowers the radiative recombination probability and results in grain boundary related trap states. We realize smooth and pinhole-free, small-grained inorganic perovskite films with improved photoluminescence quantum yield by introducing trifluoroacetate anions to effectively passivate surface defects and control the crystal growth. As a result, efficient green LEDs based on inorganic perovskite films achieve a high current efficiency of 32.0 cd A(-1) corresponding to an external quantum efficiency of 10.5%. More importantly, our all-inorganic perovskite LEDs demonstrate a record operational lifetime, with a half-lifetime of over 250 h at an initial luminullce of 100 cd m(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 487, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 665, "DOI": "10.1038/s41467-019-08425-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08425-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458175300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, DC; Liu, YY; Chen, W; Zhou, GM; Liu, K; Dunn, B; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Dingchang; Liu, Yayuan; Chen, Wei; Zhou, Guangmin; Liu, Kai; Dunn, Bruce; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research on lithium (Li) metal-chemistry has been rapidly gaining momentum nowadays not only because of the appealing high theoretical capacity, but also its indispensable role in the nextIeneration Li-S and Li-air batteries. However; two.-root problems of Li metal, namely high reactivity and infinite relative volume change' during cycling. bring about numerous other challenges that impede its practical' applica-e tions. Trl the past, extensive studies have targeted-these two causes' by either improving, interfacial' stability or constructing a stable host. However, efficient surface passivation on three-dimensional (3D) Li is still absent. Here, we develop a conformal LiF coating technique on Li surface with commercial Freon R134a as the reagent. In contrast to solid/liquid reagents, gaseous Freon exhibits not only nontoxicity and well-controlled reactivity, but alsb much better permeability that enables a uniform LiF coating even on 3D Li. By applying a LiF coating onto 3D layered. Li-reduced graphene oxide (Li-rGO) electrodes, highly reduced side reactions and enhanced cycling stability without overpotential.auginent fOr.over 200 cycles were proven in symmetric cells. Furthermore, Li-S cells with LiF protected Li-rGO exhibit-significantly improved cyclability and Coulombic efficiency, while excellent rate capability (similar to 800 mAh g(-1) at 2 C) can still be retained.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3731, "End Page": 3737, "Article Number": null, "DOI": "10.1021/acs.nullolett.7b01020", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.7b01020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403631600060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, QZ; Li, JP; Simon, P; Xu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Qizhen; Li, Jiapeng; Simon, Patrice; Xu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional MXenes for electrochemical capacitor applications: Progress, challenges and perspectives", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes, a family of 2D transition metal carbides/nitrides with a general formula of Mn+1XnTx (n=1 similar to 3), show promising potential for energy storage applications owing to their 2D lamellar structure, impressive density, metallic-like conductivity, tunable terminations and intercalation pseudocapacitance charge storage mechanism. Various combinations of transition metals, C and/or N, as well as different n layers result in a broad range of MXenes, but only about a small number have been prepared and used for capacitive energy storage applications (supercapacitors) so far, with Ti3C2Tx being the most studied one. This review summarizes the recent advances, achievements and challenges of MXenes for supercapacitors. The preparation methods, composition versatility, material and electrode architectures, chemical modification and hybridization with other active materials of MXenes are presented. Moreover, the electrochemical characterizations and energy storage mechanisms of MXenes in aqueous and non-aqueous electrolytes are discussed, as well as the preparation of flexible and printable MXene-based electrodes and devices. Finally, perspective is also given, providing guidance for the future development of MXenes with advanced performances for designing the next generation of supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 35, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 630, "End Page": 660, "Article Number": null, "DOI": "10.1016/j.ensm.2020.11.035", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2020.11.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621384100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lloyd, D; Liu, XH; Christopher, JW; Cantley, L; Wadehra, A; Kim, BL; Goldberg, BB; Swan, AK; Bunch, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lloyd, David; Liu, Xinghui; Christopher, Jason W.; Cantley, Lauren; Wadehra, Anubhav; Kim, Brian L.; Goldberg, Bennett B.; Swan, Anna K.; Bunch, J. Scott", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band Gap Engineering with Ultralarge Biaxial Strains in Suspended Monolayer MoS2", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate the continuous and reversible tuning of the optical band gap of suspended monolayer MoS2 membranes by as much as 500 meV by applying very large biaxial strains. By using chemical vapor deposition (CVD) to grow crystals that are highly impermeable to gas, we are able to apply a pressure difference across suspended membranes to induce biaxial strains. We observe the effect of strain on the energy and intensity Of the peaks in the photoluminescence (PL) spectrum and find a linear tuning rate of the optical band gap of 99 meV/%. This method is then used to study the PL spectra of bilayer and trilayer devices under strain and to find the shift rates and Gruneisen parameters of two Raman modes in monolayer MoS2. Finally, we use this result to show that we can apply biaxial strains as large as 5.6% across micron-sized areas and report evidence for the strain tuning of higher level optical transitions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 558, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 16, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5836, "End Page": 5841, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b02615", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b02615", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383412100076", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, Y; Yu, TT; Deng, SH; Zhou, XY; Lin, DM; Zhang, Q; Jin, ZY; Zhang, DF; He, YB; Qiu, HJ; He, LH; Kang, FY; Li, KK; Zhang, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Yin; Yu, Tingting; Deng, Sihao; Zhou, Xiao-Ye; Lin, Dongmei; Zhang, Qian; Jin, Zeyu; Zhang, Danfeng; He, Yan-Bing; Qiu, Hua-Jun; He, Lunhua; Kang, Feiyu; Li, Kaikai; Zhang, Tong-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While water splitting in acid offers higher operational performances than in alkaline conditions, there are few high-activity, acid-stable oxygen evolution electrocatalysts. Here, authors examine electrochemical Li intercalation to improve the activity and stability of RuO2 for acidic water oxidation. Developing highly active and durable electrocatalysts for acidic oxygen evolution reaction remains a great challenge due to the sluggish kinetics of the four-electron transfer reaction and severe catalyst dissolution. Here we report an electrochemical lithium intercalation method to improve both the activity and stability of RuO2 for acidic oxygen evolution reaction. The lithium intercalates into the lattice interstices of RuO2, donates electrons and distorts the local structure. Therefore, the Ru valence state is lowered with formation of stable Li-O-Ru local structure, and the Ru-O covalency is weakened, which suppresses the dissolution of Ru, resulting in greatly enhanced durability. Meanwhile, the inherent lattice strain results in the surface structural distortion of LixRuO2 and activates the dangling O atom near the Ru active site as a proton acceptor, which stabilizes the OOH* and dramatically enhances the activity. This work provides an effective strategy to develop highly efficient catalyst towards water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3784, "DOI": "10.1038/s41467-022-31468-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31468-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819790100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, S; Zhu, XR; Liu, XK; Gu, J; Liu, W; Wang, DH; Zhang, W; Lin, Y; Lu, JL; Wei, SQ; Li, YF; Yao, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Shi; Zhu, Xiaorong; Liu, Xiaokang; Gu, Jian; Liu, Wei; Wang, Danhao; Zhang, Wei; Lin, Yue; Lu, Junling; Wei, Shiqiang; Li, Yafei; Yao, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uncovering near-free platinum single-atom dynamics during electrochemical hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts offering intriguing activity and selectivity are subject of intense investigation. Understanding the nature of single-atom active site and its dynamics under working state are crucial to improving their catalytic performances. Here, we identify at atomic level a general evolution of single atom into a near-free state under electrocatalytic hydrogen evolution condition, via operando synchrotron X-ray absorption spectroscopy. We uncover that the single Pt atom tends to dynamically release from the nitrogen-carbon substrate, with the geometric structure less coordinated to support and electronic property closer to zero valence, during the reaction. Theoretical simulations support that the Pt sites with weakened Pt-support interaction and more 5d density are the real active centers. The single-atom Pt catalyst exhibits very high hydrogen evolution activity with only 19 mV overpotential in 0.5 M H2SO4 and 46 mV in 1.0 M NaOH at 10 mA cm(-2), and long-term durability in wide-pH electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1029, "DOI": "10.1038/s41467-020-14848-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14848-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564280400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Gomes, LC; Morey, JR; Winiarski, M; Bordelon, M; Mangum, JS; Oswald, LWH; Rodriguez-Rivera, JA; Neilson, JR; Wilson, SD; Ertekin, E; McQueen, TM; Toberer, ES", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Gomes, Lidia C.; Morey, Jennifer R.; Winiarski, Michal; Bordelon, Mitchell; Mangum, John S.; Oswald, Lain W. H.; Rodriguez-Rivera, Jose A.; Neilson, James R.; Wilson, Stephen D.; Ertekin, Elif; McQueen, Tyrel M.; Toberer, Eric S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New kagome prototype materials: discovery of KV3Sb5, RbV3Sb5, and CsV3Sb5", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we present our discovery and characterization of a new kagome prototype structure, KV3Sb5. We also present the discovery of the isostructural compounds RbV3Sb5 and CsV3Sb5. All materials exhibit a structurally perfect two-dimensional kagome net of vanadium. Density-functional theory calculations indicate that the materials are metallic, with the Fermi level in close proximity to several Dirac points. Powder and single-crystal syntheses are presented, with postsynthetic treatments shown to deintercalate potassium from single crystals of KV3Sb5. Considering the proximity to Dirac points, deintercalation provides a convenient means to tune the Fermi level. Magnetization measurements indicate that KV3Sb5 exhibits behavior consistent with a the Curie-Weiss model at high temperatures, although the effective moment is low (0.22 mu(B) per vanadium ion). An anomaly is observed in both magnetization and heat capacity measurements at 80 K, below which the moment is largely quenched. Elastic neutron scattering measurements find no obvious evidence of long-range or short-range magnetic ordering below 80 K. The possibility of an orbital-ordering event is considered. Single-crystal resistivity measurements show the effect of deintercalation on the electron transport and allow estimation of the Kadowaki-Woods ratio in KV3Sb5. We find that A/gamma(2) similar to 61 mu Ohm cm mol(FU)(2) K-2 J(-2), suggesting that correlated electron transport may be possible. KV3Sb5 and its cogeners RbV3Sb5 and CsV3Sb5 represent a new family of kagome metals, and our results demonstrate that they deserve further study as potential model systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 542, "Times Cited, All Databases": 584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2019, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 94407, "DOI": "10.1103/PhysRevMaterials.3.094407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.3.094407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486663000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, G; Li, CF; Estevez, D; Xu, P; Peng, MY; Wei, HJ; Qin, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ge; Li, Changfeng; Estevez, Diana; Xu, Peng; Peng, Mengyue; Wei, Huijie; Qin, Faxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Interfacial Polarization Through Heterointerface Engineering in MXene/Graphene Intercalated-Based Microspheres for Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multi-layer 2D material assemblies provide a great number of interfaces beneficial for electromagnetic wave absorption. However, avoiding agglomeration and achieving layer-by-layer ordered intercalation remain challenging. Here, 3D reduced graphene oxide (rGO)/MXene/TiO2/Fe2C lightweight porous microspheres with periodical intercalated structures and pronounced interfacial effects were constructed by spray-freeze-drying and microwave irradiation based on the Maxwell-Wagner effect. Such approach reinforced interfacial effects via defects introduction, porous skeleton, multi-layer assembly and multi-component system, leading to synergistic loss mechanisms. The abundant 2D/2D/0D/0D intercalated heterojunctions in the microspheres provide a high density of polarization charges while generating abundant polarization sites, resulting in boosted interfacial polarization, which is verified by CST Microwave Studio simulations. By precisely tuning the 2D nullosheets intercalation in the heterostructures, both the polarization loss and impedance matching improve significantly. At a low filler loading of 5 wt%, the polarization loss rate exceeds 70%, and a minimum reflection loss (RLmin) of -67.4 dB can be achieved. Moreover, radar cross-section simulations further confirm the attenuation ability of the optimized porous microspheres. These results not only provide novel insights into understanding and enhancing interfacial effects, but also constitute an attractive platform for implementing heterointerface engineering based on customized 2D hierarchical architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 152, "DOI": "10.1007/s40820-023-01123-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01123-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004417900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gröschel, AH; Müller, AHE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Groschel, Andre H.; Mueller, Axel H. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembly concepts for multicompartment nullostructures", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compartmentalization is ubiquitous to many biological and artificial systems, be it for the separate storage of incompatible matter or to isolate transport processes. Advancements in the synthesis of sequential block copolymers offer a variety of tools to replicate natural design principles with tailor-made soft matter for the precise spatial separation of functionalities on multiple length scales. Here, we review recent trends in the self-assembly of amphiphilic block copolymers to multicompartment nullostructures (MCNs) under (semi-)dilute conditions, with special emphasis on ABC triblock terpolymers. The intrinsic immiscibility of connected blocks induces short-range repulsion into discrete nullo-domains stabilized by a third, soluble block or molecular additive. Polymer blocks can be synthesized from an arsenal of functional monomers directing self-assembly through packing frustration or response to various fields. The mobility in solution further allows the manipulation of self-assembly processes into specific directions by clever choice of environmental conditions. This review focuses on practical concepts that direct self-assembly into predictable nullostructures, while narrowing particle dispersity with respect to size, shape and internal morphology. The growing understanding of underlying self-assembly mechanisms expands the number of experimental concepts providing the means to target and manipulate progressively complex superstructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11841, "End Page": 11876, "Article Number": null, "DOI": "10.1039/c5nr02448j", "DOI Link": "http://dx.doi.org/10.1039/c5nr02448j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357805700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ML; Lu, YP; Lan, JG; Wang, TM; Zhang, C; Cao, ZQ; Li, TJ; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mingliang; Lu, Yiping; Lan, Jinggang; Wang, Tongmin; Zhang, Chuan; Cao, Zhiqiang; Li, Tingju; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, ultrastrong and high thermal-stable eutectic high-entropy alloys for elevated-temperature applications", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Eutectic high-entropy alloys (EHEAs) that combine the advantages of HEAs and eutectic alloys are promising candidates for high-temperature applications. However, currently developed EHEAs still exhibit high densities and low high-temperature strengths, which limit their usage. Here we propose a strategy to design lightweight, strong, and high thermal-stable EHEAs by introducing an extremely stable Heusler-type ordered phase (L21 phase) containing a high-content of low-density elements and constructing a low lattice misfit eutectic-phase interface, which can lead to generate ultrafine and stable lamellar structures and high-density of coherent nulloprecipitates. As a manifestation of this strategy, a novel bulk Al17Ni34Ti17V32 EHEA was designed to consist of L21 and body-centered-cubic (BCC) phases (interlamellar spacing -320 nm) with a lattice misfit only 2.4%. This alloy has one of the lowest densities (-6.2 g/cm3) among all EHEAs reported previously and exhibits much higher high-temperature hardness and specific yield strengths than most reported refractory HEAs (RHEAs), lightweight HEAs (LWHEAs), EHEAs, and conventional superalloys. This work paves the way to develop light EHEAs with excellent high-temperature properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 248, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118806, "DOI": "10.1016/j.actamat.2023.118806", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2023.118806", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952487500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, ZW; Wang, Y; Xu, CQ; Liu, SJ; Chen, C; Peng, Q; Zhuang, ZB; Xiao, H; Pan, Y; Lu, SQ; Yu, R; Cheong, WC; Cao, X; Wu, KL; Sun, KA; Wang, DS; Li, J; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Zewen; Wang, Yu; Xu, Cong-Qiao; Liu, Shoujie; Chen, Chen; Peng, Qing; Zhuang, Zhongbin; Xiao, Hai; Pan, Yuan; Lu, Siqi; Yu, Rong; Cheong, Weng-Chon; Cao, Xing; Wu, Konglin; Sun, Kaian; Wang, Dingsheng; Li, Jun; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional open nullo-netcage electrocatalysts for efficient pH-universal overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-efficiency water electrolysis is the key to sustainable energy. Here we report a highly active and durable RuIrOx (x >= 0) nullo-netcage catalyst formed during electrochemical testing by in-situ etching to remove amphoteric ZnO from RuIrZnOx hollow nullobox. The dispersing-etching-holing strategy endowed the porous nullo-netcage with a high exposure of active sites as well as a three-dimensional accessibility for substrate molecules, thereby drastically boosting the electrochemical surface area (ECSA). The nullo-netcage catalyst achieved not only ultralow overpotentials at 10 mA cm(-2) for hydrogen evolution reaction (HER; 12 mV, pH = 0; 13 mV, pH = 14), but also high-performance overall water electrolysis over a broad pH range (0 similar to 14), with a potential of mere 1.45 V (pH = 0) or 1.47 V (pH = 14) at 10 mA cm(-2). With this universal applicability of our electrocatalyst, a variety of readily available electrolytes (even including waste water and sea water) could potentially be directly used for hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4875, "DOI": "10.1038/s41467-019-12885-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12885-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492835100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, KY; Aitomäki, Y; Berglund, LA; Oksman, K; Bismarck, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Koon-Yang; Aitomaki, Yvonne; Berglund, Lars A.; Oksman, Kristiina; Bismarck, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the use of nullocellulose as reinforcement in polymer matrix composites", "Source Title": "COMPOSITES SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocellulose is often being regarded as the next generation renewable reinforcement for the production of high performance biocomposites. This feature article reviews the various nullocellulose reinforced polymer composites reported in literature and discusses the potential of nullocellulose as reinforcement for the production of renewable high performance polymer nullocomposites. The theoretical and experimentally determined tensile properties of nullocellulose are also reviewed. In addition to this, the reinforcing ability of BC and NFC is juxtaposed. In order to analyse the various cellulose-reinforced polymer nullocomposites reported in literature, Cox-Krenchel and rule-of-mixture models have been used to elucidate the potential of nullocellulose in composite applications. There may be potential for improvement since the tensile modulus and strength of most cellulose nullocomposites reported in literature scale linearly with the tensile modulus and strength of the cellulose nullopaper structures. Better dispersion of individual cellulose nullofibres in the polymer matrix may improve composite properties. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 604, "Times Cited, All Databases": 651, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2014, "Volume": 105, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15, "End Page": 27, "Article Number": null, "DOI": "10.1016/j.compscitech.2014.08.032", "DOI Link": "http://dx.doi.org/10.1016/j.compscitech.2014.08.032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346943400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CG; He, LX; Zhou, LL; Yang, O; Yuan, W; Wei, XL; Liu, YB; Lu, L; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuguo; He, Lixia; Zhou, Linglin; Yang, Ou; Yuan, Wei; Wei, Xuelian; Liu, Yuebo; Lu, Liang; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active resonullce triboelectric nullogenerator for harvesting omnidirectional water-wave energy", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water-wave energy, as one of the important renewable energies, is greatly difficult to efficiently harvest due to its characteristics of low frequency and randomly moving direction. Herein, we report an active resonullce triboelectric nullogenerator (AR-TENG) system fabricated by using simple pendulum, tumbler, and flexible ring TENG, which can harvest omnidirectional and frequency varying water-wave energy through excellent structural design and resonullce effect. Besides, thanks to the high-frequency damped motion of simple pendulum and tumbler, the high-frequency output generated by the AR-TENG system under the driving condition of low-frequency water wave can greatly improve the efficiency of wave energy harvesting. More importantly, based on the low damping coefficient, resonullce effect, and elimination of water screening effect, the output performance of AR-TENG system in the water wave is closest to the simulated test. This work not only can realize the omnidirectional water-wave energy harvesting by TENG but also provide a method for large-scale blue energy harvesting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2021, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1613, "End Page": 1623, "Article Number": null, "DOI": "10.1016/j.joule.2021.04.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.04.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663028600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, SM; Xu, SY; Belopolski, I; Lee, CC; Chang, GQ; Wang, BK; Alidoust, N; Bian, G; Neupane, M; Zhang, CL; Jia, S; Bansil, A; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Shin-Ming; Xu, Su-Yang; Belopolski, Ilya; Lee, Chi-Cheng; Chang, Guoqing; Wang, BaoKai; Alidoust, Nasser; Bian, Guang; Neupane, Madhab; Zhang, Chenglong; Jia, Shuang; Bansil, Arun; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Weyl Fermion semimetal with surface Fermi arcs in the transition metal monopnictide TaAs class", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl fermions are massless chiral fermions that play an important role in quantum field theory but have never been observed as fundamental particles. A Weyl semimetal is an unusual crystal that hosts Weyl fermions as quasiparticle excitations and features Fermi arcs on its surface. Such a semimetal not only provides a condensed matter realization of the anomalies in quantum field theories but also demonstrates the topological classification beyond the gapped topological insulators. Here, we identify a topological Weyl semimetal state in the transition metal monopnictide materials class. Our first-principles calculations on TaAs reveal its bulk Weyl fermion cones and surface Fermi arcs. Our results show that in the TaAs-type materials the Weyl semimetal state does not depend on fine-tuning of chemical composition or magnetic order, which opens the door for the experimental realization of Weyl semimetals and Fermi arc surface states in real materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1327, "Times Cited, All Databases": 1432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7373, "DOI": "10.1038/ncomms8373", "DOI Link": "http://dx.doi.org/10.1038/ncomms8373", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XH; Wang, DH; Qiu, XY; Ma, YJ; Kong, DB; Müllen, K; Li, XL; Zhi, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xinghao; Wang, Denghui; Qiu, Xiongying; Ma, Yingjie; Kong, Debin; Muellen, Klaus; Li, Xianglong; Zhi, Linjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable high-capacity and high-rate silicon-based lithium battery anodes upon two-dimensional covalent encapsulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon is a promising anode material for lithium-ion and post lithium-ion batteries but suffers from a large volume change upon lithiation and delithiation. The resulting instabilities of bulk and interfacial structures severely hamper performance and obstruct practical use. Stability improvements have been achieved, although at the expense of rate capability. Herein, a protocol is developed which we describe as two-dimensional covalent encapsulation. Two-dimensional, covalently bound silicon-carbon hybrids serve as proof-of-concept of a new material design. Their high reversibility, capacity and rate capability furnish a remarkable level of integrated performances when referred to weight, volume and area. Different from existing strategies, the two-dimensional covalent binding creates a robust and efficient contact between the silicon and electrically conductive media, enabling stable and fast electron, as well as ion, transport from and to silicon. As evidenced by interfacial morphology and chemical composition, this design profoundly changes the interface between silicon and the electrolyte, securing the as-created contact to persist upon cycling. Combined with a simple, facile and scalable manufacturing process, this study opens a new avenue to stabilize silicon without sacrificing other device parameters. The results hold great promise for both further rational improvement and mass production of advanced energy storage materials. Stabilizing silicon without sacrificing other device parameters is essential for practical use in lithium and post lithium battery anodes. Here, the authors show the skin-like two-dimensional covalent encapsulation furnishing a remarkable level of integrated lithium storage performances of silicon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3826, "DOI": "10.1038/s41467-020-17686-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17686-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560366500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Frei, MS; Capdevila-Cortada, M; García-Muelas, R; Mondelli, C; López, N; Stewart, JA; Ferré, DC; Pérez-Ramírez, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Frei, M. S.; Capdevila-Cortada, M.; Garcia-Muelas, R.; Mondelli, C.; Lopez, N.; Stewart, J. A.; Ferre, D. Curulla; Perez-Ramirez, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism and microkinetics of methanol synthesis via CO2 hydrogenation on indium oxide", "Source Title": "JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Indium oxide has emerged as a highly effective catalyst for methanol synthesis by direct CO2 hydrogenation. Aiming at gathering a deeper fundamental understanding, mechanistic and (micro)kinetic aspects of this catalytic system were investigated. Steady-state evaluation at 5 MPa and variable temperature indicated a lower apparent activation energy for CO2 hydrogenation than for the reverse watergas shift reaction (103 versus 117 kJ mol(-1)), which is in line with the high methanol selectivity observed. Upon changing the partial pressure of reactants and products, apparent reaction orders of -0.1, 0.5, -0.2, and -0.9 were determined for CO2, H-2, methanol, and water, respectively, which highlight a strong inhibition by the latter. Co-feeding of H2O led to catalyst deactivation by sintering for partial pressures exceeding 0.125 MPa, while addition of the byproduct CO to the gas stream could be favorable at a total pressure below 4 MPa but was detrimental at higher pressures. Density Functional Theory simulations conducted on In2O3(111), which was experimentally and theoretically shown to be the most exposed surface termination, indicated that oxygen vacancies surrounded by three indium atoms enable the activation of CO2 and split hydrogen heterolytically, stabilizing the polarized species formed. The most energetically favored path to methanol comprises three consecutive additions of hydrides and protons and features CH2OOH and CH2(OH)(2) as intermediates. Microkinetic modeling based on the DFT results provided values for temperature and concentration-dependent parameters, which are in good agreement with the empirically obtained data. These results are expected to drive further optimization of In2O3-based materials and serve as a solid basis for reactor and process design, thus fostering advances towards a potential large-scale methanol synthesis from CO2. (C) 2018 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 361, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 313, "End Page": 321, "Article Number": null, "DOI": "10.1016/j.jcat.2018.03.014", "DOI Link": "http://dx.doi.org/10.1016/j.jcat.2018.03.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431164500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, WJ; Duan, ZY; Liu, W; Mehmood, R; Qu, JT; Cao, YC; Guo, XY; Zhong, J; Zhang, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Wenjun; Duan, Zhiyao; Liu, Wei; Mehmood, Rashid; Qu, Jiating; Cao, Yucheng; Guo, Xiangyang; Zhong, Jun; Zhang, Fuxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of heterogenized molecular phthalocyanine hybrid single-atom electrocatalyst towards two-electron oxygen reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts supported on solid substrates have inspired extensive interest, but the rational design of high-efficiency single-atom catalysts is still plagued by ambiguous structure determination of active sites and its local support effect. Here, we report hybrid single-atom catalysts by an axial coordination linkage of molecular cobalt phthalocyanine with carbon nullotubes for selective oxygen reduction reaction by screening from a series of metal phthalocyanines via preferential density-functional theory calculations. Different from conventional heterogeneous single-atom catalysts, the hybrid single-atom catalysts are proven to facilitate rational screening of target catalysts as well as understanding of its underlying oxygen reduction reaction mechanism due to its well-defined active site structure and clear coordination linkage in the hybrid single-atom catalysts. Consequently, the optimized Co hybrid single-atom catalysts exhibit improved 2e(-) oxygen reduction reaction performance compared to the corresponding homogeneous molecular catalyst in terms of activity and selectivity. When prepared as an air cathode in an air-breathing flow cell device, the optimized hybrid catalysts enable the oxygen reduction reaction at 300mAcm(-2) exhibiting a stable Faradaic efficiency exceeding 90% for 25h. Difficulties in elucidating active sites and the role of the support hamper the development of high-efficiency two-electron oxygen reduction electrocatalysts. Here, the authors develop hybrid single-atom catalysts by rational experimental and theoretical screening for hydrogen peroxide production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1426, "DOI": "10.1038/s41467-023-37066-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37066-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055247000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Luo, W; Wang, CW; Li, YJ; Chen, CJ; Song, JW; Dai, JQ; Hitz, EM; Xu, SM; Yang, CP; Wang, YB; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ying; Luo, Wei; Wang, Chengwei; Li, Yiju; Chen, Chaoji; Song, Jianwei; Dai, Jiaqi; Hitz, Emily M.; Xu, Shaomao; Yang, Chunpeng; Wang, Yanbin; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-capacity, low-tortuosity, and channel-guided lithium metal anode", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal anode with the highest capacity and lowest anode potential is extremely attractive to battery technologies, but infinite volume change during the Li stripping/plating process results in cracks and fractures of the solid electrolyte interphase, low Coulombic efficiency, and dendritic growth of Li. Here, we use a carbonized wood (C-wood) as a 3D, highly porous (73% porosity) conductive framework with well-aligned channels as Li host material. We discovered that molten Li metal can infuse into the straight channels of C-wood to form a Li/C-wood electrode after surface treatment. The C-wood channels function as excellent guides in which the Li stripping/plating process can take place and effectively confine the volume change that occurs. Moreover, the local current density can be minimized due to the 3D C-wood framework. Therefore, in symmetric cells, the as-prepared Li/C-wood electrode presents a lower over-potential (90 mV at 3 mA.cm(-2)), more-stable stripping/plating profiles, and better cycling performance (similar to 150 h at 3 mA.cm(-2)) compared with bare Li metal electrode. Our findings may open up a solution for fabricating stable Li metal anode, which further facilitates future application of high-energy-density Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2017, "Volume": 114, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3584, "End Page": 3589, "Article Number": null, "DOI": "10.1073/pnas.1618871114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1618871114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398159000035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jang, KI; Li, K; Chung, HU; Xu, S; Jung, HN; Yang, YY; Kwak, JW; Jung, HH; Song, J; Yang, C; Wang, A; Liu, ZJ; Lee, JY; Kim, BH; Kim, JH; Lee, J; Yu, Y; Kim, BJ; Jang, H; Yu, KJ; Kim, J; Lee, JW; Jeong, JW; Song, YM; Huang, YG; Zhang, YH; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jang, Kyung-In; Li, Kan; Chung, Ha Uk; Xu, Sheng; Jung, Han Na; Yang, Yiyuan; Kwak, Jean Won; Jung, Han Hee; Song, Juwon; Yang, Ce; Wang, Ao; Liu, Zhuangjian; Lee, Jong Yoon; Kim, Bong Hoon; Kim, Jae-Hwan; Lee, Jungyup; Yu, Yongjoon; Kim, Bum Jun; Jang, Hokyung; Yu, Ki Jun; Kim, Jeonghyun; Lee, Jung Woo; Jeong, Jae-Woong; Song, Young Min; Huang, Yonggang; Zhang, Yihui; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembled three dimensional network designs for soft electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low modulus, compliant systems of sensors, circuits and radios designed to intimately interface with the soft tissues of the human body are of growing interest, due to their emerging applications in continuous, clinical-quality health monitors and advanced, bioelectronic therapeutics. Although recent research establishes various materials and mechanics concepts for such technologies, all existing approaches involve simple, two-dimensional (2D) layouts in the constituent micro-components and interconnects. Here we introduce concepts in three-dimensional (3D) architectures that bypass important engineering constraints and performance limitations set by traditional, 2D designs. Specifically, open-mesh, 3D interconnect networks of helical microcoils formed by deterministic compressive buckling establish the basis for systems that can offer exceptional low modulus, elastic mechanics, in compact geometries, with active components and sophisticated levels of functionality. Coupled mechanical and electrical design approaches enable layout optimization, assembly processes and encapsulation schemes to yield 3D configurations that satisfy requirements in demanding, complex systems, such as wireless, skin-compatible electronic sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15894, "DOI": "10.1038/ncomms15894", "DOI Link": "http://dx.doi.org/10.1038/ncomms15894", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403770700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Su, HF; Kwok, RTK; Hu, XL; Zou, H; Luo, QX; Lee, MMS; Xu, WH; Lam, JWY; Tang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dong; Su, Huifang; Kwok, Ryan T. K.; Hu, Xianglong; Zou, Hang; Luo, Qianxin; Lee, Michelle M. S.; Xu, Wenhan; Lam, Jacky W. Y.; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of a water-soluble NIR AIEgen, and its application in ultrafast wash-free cellular imaging and photodynamic cancer cell ablation", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of water-soluble near-infrared (NIR)-emissive fluorescent molecules with aggregation-induced emission (AIE) characteristics and theranostic functions is highly desirable but remains challenging. In this work, we designed and readily prepared for the first time such a molecule with AIE features, good water-solubility and intense emission in the NIR region. This AIE luminogen (AIEgen) is able to specifically light up the cell membrane without the involvement of a washing procedure. Interestingly, the staining process can be performed by simply shaking the culture with cells at room temperature for only a few seconds after the addition of the AIEgen, indicating an ultrafast and easy-to-operate staining protocol. This is the first fluorescent light-up probe for cell-imaging that allows the combination of a short staining period (at the second-level) with a wash-free process. Additionally, the presented AIEgen has also been developed to serve as an excellent phototherapeutic agent for high efficiency generation of reactive oxygen species (ROS) upon visible light irradiation, which allows its effective application in the photodynamic ablation of cancer cells, demonstrating its dual role as an imaging and phototherapeutic agent.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2018, "Volume": 9, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3685, "End Page": 3693, "Article Number": null, "DOI": "10.1039/c7sc04963c", "DOI Link": "http://dx.doi.org/10.1039/c7sc04963c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431389300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, P; Wu, HQ; Gao, B; Eryilmaz, SB; Huang, XY; Zhang, WQ; Zhang, QT; Deng, N; Shi, LP; Wong, HSP; Qian, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Peng; Wu, Huaqiang; Gao, Bin; Eryilmaz, Sukru Burc; Huang, Xueyao; Zhang, Wenqiang; Zhang, Qingtian; Deng, Ning; Shi, Luping; Wong, H. -S. Philip; Qian, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Face classification using electronic synapses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional hardware platforms consume huge amount of energy for cognitive learning due to the data movement between the processor and the off-chip memory. Brain-inspired device technologies using analogue weight storage allow to complete cognitive tasks more efficiently. Here we present an analogue non-volatile resistive memory (an electronic synapse) with foundry friendly materials. The device shows bidirectional continuous weight modulation behaviour. Grey-scale face classification is experimentally demonstrated using an integrated 1024-cell array with parallel online training. The energy consumption within the analogue synapses for each iteration is 1,000x (20x) lower compared to an implementation using Intel Xeon Phi processor with off-chip memory (with hypothetical on-chip digital resistive random access memory). The accuracy on test sets is close to the result using a central processing unit. These experimental results consolidate the feasibility of analogue synaptic array and pave the way toward building an energy efficient and large-scale neuromorphic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 759, "Times Cited, All Databases": 805, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15199, "DOI": "10.1038/ncomms15199", "DOI Link": "http://dx.doi.org/10.1038/ncomms15199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401222500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, GD; Davies, TE; Nasrallah, A; Sainna, MA; Howe, AGR; Lewis, RJ; Quesne, M; Catlow, CRA; Willock, DJ; He, Q; Bethell, D; Howard, MJ; Murrer, BA; Harrison, B; Kiely, CJ; Zhao, XL; Deng, F; Xu, J; Hutchings, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Guodong; Davies, Thomas E.; Nasrallah, Ali; Sainna, Mala A.; Howe, Alexander G. R.; Lewis, Richard J.; Quesne, Matthew; Catlow, C. Richard A.; Willock, David J.; He, Qian; Bethell, Donald; Howard, Mark J.; Murrer, Barry A.; Harrison, Brian; Kiely, Christopher J.; Zhao, Xingling; Deng, Feng; Xu, Jun; Hutchings, Graham J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Au-ZSM-5 catalyses the selective oxidation of CH4 to CH3OH and CH3COOH using O2", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxidation of methane, the main component of natural gas, to selectively form oxygenated chemical feedstocks using molecular oxygen has been a long-standing grand challenge in catalysis. Here, using gold nulloparticles supported on the zeolite ZSM-5, we introduce a method to oxidize methane to methanol and acetic acid in water at temperatures between 120 and 240 degrees C using molecular oxygen in the absence of any added coreductant. Electron microscopy reveals that the catalyst does not contain gold atoms or clusters, but rather gold nulloparticles are the active component, while a mechanism involving surface adsorbed species is proposed in which methanol and acetic acid are formed via parallel pathways.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": 54, "Article Number": null, "DOI": "10.1038/s41929-021-00725-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00725-8", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739774100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chun, SE; Evanko, B; Wang, XF; Vonlanthen, D; Ji, XL; Stucky, GD; Boettcher, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chun, Sang-Eun; Evanko, Brian; Wang, Xingfeng; Vonlanthen, David; Ji, Xiulei; Stucky, Galen D.; Boettcher, Shannon W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of aqueous redox-enhanced electrochemical capacitors with high specific energies and slow self-discharge", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical double-layer capacitors exhibit high power and long cycle life but have low specific energy compared with batteries, limiting applications. Redox-enhanced capacitors increase specific energy by using redox-active electrolytes that are oxidized at the positive electrode and reduced at the negative electrode during charging. Here we report characteristics of several redox electrolytes to illustrate operational/self-discharge mechanisms and the design rules for high performance. We discover a methyl viologen (MV)/bromide electrolyte that delivers a high specific energy of similar to 14 Wh kg(-1) based on the mass of electrodes and electrolyte, without the use of an ion-selective membrane separator. Substituting heptyl viologen for MV increases stability, with no degradation over 20,000 cycles. Self-discharge is low, due to adsorption of the redox couples in the charged state to the activated carbon, and comparable to cells with inert electrolyte. An electrochemical model reproduces experiments and predicts that 30-50 Wh kg(-1) is possible with optimization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7818, "DOI": "10.1038/ncomms8818", "DOI Link": "http://dx.doi.org/10.1038/ncomms8818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360342300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wang, T; Liu, P; Liu, SH; Dong, RH; Zhuang, XD; Chen, MW; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wang, Tao; Liu, Pan; Liu, Shaohua; Dong, Renhao; Zhuang, Xiaodong; Chen, Mingwei; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering water dissociation sites in MoS2 nullosheets for accelerated electrocatalytic hydrogen production", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earth-abundant MoS2 is widely reported as a promising HER electrocatalyst in acidic solutions, but it exhibits extremely poor HER activities in alkaline media due to the slow water dissociation process. Here we present a combined theoretical and experimental approach to improve the sluggish HER kinetics of MoS2 electrocatalysts through engineering the water dissociation sites by doping Ni atoms into MoS2 nullosheets. The Ni sites thus introduced can effectively reduce the kinetic energy barrier of the initial water-dissociation step and facilitate the desorption of the -OH that are formed. As a result, the developed Ni-doped MoS2 nullosheets (Ni-MoS2) show an extremely low HER overpotential of similar to 98 mV at 10 mA cm(-2) in 1 M KOH aqueous solution, which is superior to those (>220 mV at 10 mA cm(-2)) of reported MoS2 electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2789, "End Page": 2793, "Article Number": null, "DOI": "10.1039/c6ee01786j", "DOI Link": "http://dx.doi.org/10.1039/c6ee01786j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382746300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JN; Chen, Y; Huang, HJ; Wang, JJ; Huang, SC; Liao, YF; Fetohi, AE; Hu, F; Chen, HY; Li, LL; Han, XP; El-Khatib, KM; Peng, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Junnull; Chen, Ying; Huang, Hongjiao; Wang, Jiajun; Huang, Shao-Chu; Liao, Yen-Fa; Fetohi, Amani E.; Hu, Feng; Chen, Han-yi; Li, Linlin; Han, Xiaopeng; El-Khatib, K. M.; Peng, Shengjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterointerface Engineering of Hierarchically Assembling Layered Double Hydroxides on Cobalt Selenide as Efficient Trifunctional Electrocatalysts for Water Splitting and Zinc-Air Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering of structure and composition is essential but still challenging for electrocatalytic activity modulation. Herein, hybrid nullostructured arrays (HNA) with branched and aligned structures constructed by cobalt selenide (CoSe2) nullotube arrays vertically oriented on carbon cloth with CoNi layered double hydroxide (CoSe2@CoNi LDH HNA) are synthesized by a hydrothermal-selenization-hybridization strategy. The branched and hollow structure, as well as the heterointerface between CoSe2 and CoNi LDH guarantee structural stability and sufficient exposure of the surface active sites. More importantly, the strong interaction at the interface can effectively modulate the electronic structure of hybrids through the charge transfer and then improves the reaction kinetics. The resulting branched CoSe2@CoNi LDH HNA as trifunctional catalyst exhibits enhanced electrocatalytic performance toward oxygen evolution/reduction and hydrogen evolution reaction. Consequently, the branched CoSe2@CoNi LDH HNA exhibits low overpotential of 1.58 V at 10 mA cm(-2) for water splitting and superior cycling stability (70 h) for rechargeable flexible Zn-air battery. Theoretical calculations reveal that the construction of heterostructure can effectively lower the reaction barrier as well as improve electrical conductivity, consequently favoring the enhanced electrochemical performance. This work concerning engineering heterostructure and topography-performance relationship can provide new guidance for the development of multifunctional electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104522, "DOI": "10.1002/advs.202104522", "DOI Link": "http://dx.doi.org/10.1002/advs.202104522", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741349400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mason, JA; Veenstra, M; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluating metal-organic frameworks for natural gas storage", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks have received significant attention as a new class of adsorbents for natural gas storage; however, inconsistencies in reporting high-pressure adsorption data and a lack of comparative studies have made it challenging to evaluate both new and existing materials. Here, we briefly discuss high-pressure adsorption measurements and review efforts to develop metal-organic frameworks with high methane storage capacities. To illustrate the most important properties for evaluating adsorbents for natural gas storage and for designing a next generation of improved materials, six metal-organic frameworks and an activated carbon, with a range of surface areas, pore structures, and surface chemistries representative of the most promising adsorbents for methane storage, are evaluated in detail. High-pressure methane adsorption isotherms are used to compare gravimetric and volumetric capacities, isosteric heats of adsorption, and usable storage capacities. Additionally, the relative importance of increasing volumetric capacity, rather than gravimetric capacity, for extending the driving range of natural gas vehicles is highlighted. Other important systems-level factors, such as thermal management, mechanical properties, and the effects of impurities, are also considered, and potential materials synthesis contributions to improving performance in a complete adsorbed natural gas system are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1046, "Times Cited, All Databases": 1166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 32, "End Page": 51, "Article Number": null, "DOI": "10.1039/c3sc52633j", "DOI Link": "http://dx.doi.org/10.1039/c3sc52633j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000327601600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kerelsky, A; McGilly, LJ; Kennes, DM; Xian, LD; Yankowitz, M; Chen, SW; Watanabe, K; Taniguchi, T; Hone, J; Dean, C; Rubio, A; Pasupathy, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kerelsky, Alexander; McGilly, Leo J.; Kennes, Dante M.; Xian, Lede; Yankowitz, Matthew; Chen, Shaowen; Watanabe, K.; Taniguchi, T.; Hone, James; Dean, Cory; Rubio, Angel; Pasupathy, Abhay N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Maximized electron interactions at the magic angle in twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic properties of heterostructures of atomically thin van der Waals crystals can be modified substantially by moire superlattice potentials from an interlayer twist between crystals(1,2). Moire tuning of the band structure has led to the recent discovery of superconductivity(3,4) and correlated insulating phases5 in twisted bilayer graphene (TBG) near the 'magic angle' of twist of about 1.1 degrees, with a phase diagram reminiscent of high-transition-temperature superconductors. Here we directly map the atomic-scale structural and electronic properties of TBG near the magic angle using scanning tunnelling microscopy and spectroscopy. We observe two distinct van Hove singularities (VHSs) in the local density of states around the magic angle, with an energy separation of 57 millielectronvolts that drops to 40 millielectronvolts with high electron/hole doping. Unexpectedly, the VHS energy separation continues to decrease with decreasing twist angle, with a lowest value of 7 to 13 millielectronvolts at a magic angle of 0.79 degrees. More crucial to the correlated behaviour of this material, we find that at the magic angle, the ratio of the Coulomb interaction to the bandwidth of each individual VHS (U/t) is maximized, which is optimal for electronic Cooper pairing mechanisms. When doped near the half-moire-band filling, a correlation-induced gap splits the conduction VHS with a maximum size of 6.5 millielectronvolts at 1.15 degrees, dropping to 4 millielectronvolts at 0.79 degrees. We capture the doping-dependent and angle-dependent spectroscopy results using a Hartree-Fock model, which allows us to extract the on-site and nearest-neighbour Coulomb interactions. This analysis yields a U/t of order unity indicating that magic-angle TBG is moderately correlated. In addition, scanning tunnelling spectroscopy maps reveal an energy-and doping-dependent threefold rotational-symmetry breaking of the local density of states in TBG, with the strongest symmetry breaking near the Fermi level and further enhanced when doped to the correlated gap regime. This indicates the presence of a strong electronic nematic susceptibility or even nematic order in TBG in regions of the phase diagram where superconductivity is observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 730, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2019, "Volume": 572, "Issue": 7767, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 95, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1431-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1431-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478017900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, XR; Wang, BB; Wang, KK; Xu, S; Liu, SP; Liu, XH; Jia, ZR; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xuran; Wang, Bingbing; Wang, Kuikui; Xu, Shuang; Liu, Sipeng; Liu, Xuehua; Jia, Zirui; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Ti3C2Tx/TiO2/PANI multi-layer composites for excellent electromagnetic wave absorption performance", "Source Title": "JOURNAL OF COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ti3C2Tx MXene is an excellent electromagnetic wave (EMW) absorber with excellent electrical conductivity and abundant surface functional groups. In this research, Ti3C2Tx/TiO2/PANI multi-layer composites were successfully synthesized by HCl and LiF etching, one-step hydrothermal method and in-situ polymerization. Ti3C2Tx can provide more electron transfer paths due to its unique multilayer structure and high specific surface area. The growth of TiO2 particles on the surface of Ti3C2Tx through hydrothermal reaction enhances the interface polarization, and then polyaniline (PANI) is doped on the surface of Ti3C2Tx where TiO2 particles are grown by in-situ polymerization. Due to the excellent dielectric properties and synergistic effects of the material itself, Ti3C2Tx/TiO2/PANI composites have excellent EMW absorption property. In this study, the Ti3C2Tx/TiO2/PANI composites showed the strong reflection loss (RL) of at 13.92 GHz, which was-65.61 dB, and the thickness was only 2.18 mm. Moreover, the composites also exhibit a wide absorption band, with an effective absorption bandwidth (RL <-10 dB) of 5.92 GHz (11.84 GHz to 17.76 GHz) at 2.10 mm. The results show that the Ti3C2Tx/TiO2/PANI composites are expected to become EMW absorber with thin thickness and high absorption strength. (c) 2020 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 583, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 510, "End Page": 521, "Article Number": null, "DOI": "10.1016/j.jcis.2020.09.094", "DOI Link": "http://dx.doi.org/10.1016/j.jcis.2020.09.094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595128700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YS; Feng, ZM; Cui, PX; Zhu, W; Gong, Y; Girard, MA; Lajoie, G; Trottier, J; Zhang, QH; Gu, L; Wang, Y; Zuo, WH; Yang, Y; Goodenough, JB; Zaghib, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuesheng; Feng, Zimin; Cui, Peixin; Zhu, Wen; Gong, Yue; Girard, Marc-Andre; Lajoie, Gilles; Trottier, Julie; Zhang, Qinghua; Gu, Lin; Wang, Yan; Zuo, Wenhua; Yang, Yong; Goodenough, John B.; Zaghib, Karim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pillar-beam structures prevent layered cathode materials from destructive phase transitions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy storage with high energy density and low cost has been the subject of a decades-long pursuit. Sodium-ion batteries are well expected because they utilize abundant resources. However, the lack of competent cathodes with both large capacities and long cycle lives prevents the commercialization of sodium-ion batteries. Conventional cathodes with hexagonal-P2-type structures suffer from structural degradations when the sodium content falls below 33%, or when the integral anions participate in gas evolution reactions. Here, we show a pillar-beam structure for sodium-ion battery cathodes where a few inert potassium ions uphold the layer-structured framework, while the working sodium ions could diffuse freely. The thus-created unorthodox orthogonal-P2 K-0.4[Ni0.2Mn0.8]O-2 cathode delivers a capacity of 194mAh/g at 0.1C, a rate capacity of 84% at 1C, and an 86% capacity retention after 500 cycles at 1C. The addition of the potassium ions boosts simultaneously the energy density and the cycle life. The specific capacity of P2-type sodium-ion battery cathode is limited because full extraction of Na ions leads to structural degradation. Here authors report pillar-beam structured material to overcome this issue by using K pillar ions to uphold the transition metal layers upon extraction of Na ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13, "DOI": "10.1038/s41467-020-20169-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20169-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665625900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortazavi, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortazavi, Bohayra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra high stiffness and thermal conductivity of graphene like C3N", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, single crystalline carbon nitride 2D material with a C3N stoichiometry has been synthesized. In this investigation, we explored the mechanical response and thermal transport along pristine, freestanding and single-layer C3N. To this aim, we conducted extensive first-principles density functional theory (DFT) calculations as well as molecular dynamics (MD) simulations. DFT results reveal that C3N nullofilms can yield remarkably high elastic modulus of 341 GPa nm and tensile strength of 35 GPa nm, very close to those of defect-free graphene. Classical MD simulations performed at a low temperature, predict accurately the elastic modulus of 2D C3N with less than 3% difference with the first-principles estimation. The deformation process of C3N nullosheets was studied both by the DFT and MD simulations. Ab initio molecular dynamics simulations show that single-layer C3N can withstand high temperatures like 4000 K. Remarkably, the phononic thermal conductivity of free-standing C3N was predicted to be as high as 815 +/- 20 W/mK. Our atomistic modelling results reveal ultra high stiffness and thermal conductivity of C3N nullomembranes and therefore propose them as promising candidates for new application such as the thermal management in nulloelectronics or simultaneously reinforcing the thermal and mechanical properties of polymeric materials. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 118, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 25, "End Page": 34, "Article Number": null, "DOI": "10.1016/j.carbon.2017.03.029", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2017.03.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401120800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SJ; Cai, MJ; Liu, YP; Wang, CC; Lv, KL; Chen, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shijie; Cai, Mingjie; Liu, Yanping; Wang, Chunchun; Lv, Kangle; Chen, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-Scheme photocatalyst TaON/Bi2WO6 nullofibers with oxygen vacancies for efficient abatement of antibiotics and Cr(VI): Intermediate eco-toxicity analysis and mechanistic insights", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enlightened by natural photosynthesis, developing efficient S-scheme heterojunction photocatalysts for deleterious pollutant removal is of prime importance to restore environment. Herein, novel TaON/Bi2WO6 S-scheme heterojunction nullofibers were designed and developed by in-situ growing Bi2WO6 nullosheets with oxygen vacancies (OVs) on TaON nullofibers. Thanks to the efficiently spatial charge disassociation and preserved great redox power by the unique S-scheme mechanism and OVs, as well as firmly interfacial contact by the core-shell 1D/2D fibrous hetero-structure via the in-situ growth, the optimized TaON/Bi2WO6 heterojunction unveils exceptional visible-light photocatalytic property for abatement of tetracycline (TC), levofloxacin (LEV), and Cr(VI), respectively by 2.8-fold, 1.0-fold, and 1.9-fold enhancement compared to the bare Bi2WO6, while maintaining satisfactory stability. Furthermore, the systematic photoreaction tests indicate TaON/Bi2WO6 has the high practicality in the elimination of pollutants in aquatic environment. The degradation pathway of tetracycline and intermediate eco-toxicity were determined based on HPLC-MS combined with QSAR calculation, and a possible photocatalytic mechanism was elucidated. This work provides a guideline for designing high-performance TaON-based S-scheme photocatalysts with defects for environment protection. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 43, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2652, "End Page": 2664, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64106-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64106-8", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884673500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, SS; Sun, Y; Xue, HG; Braunstein, P; Huang, W; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Shasha; Sun, Yan; Xue, Huaiguo; Braunstein, Pierre; Huang, Wei; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nullocrystals for stable electrochemical cycling performance", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most metal-organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous solutions, resulting in insufficient stability, therefore limiting their applications. Thus, the design and synthesis of stable size/morphology-controlled MOF nullocrystals is critical but challenging. In this study, dual-ligand and hard-soft-acid-base strategies were used to fabricate a variety of 3D pillared-layer [Ni(thiophene-2,5-dicarboxylate)(4,4'-bipyridine)](n) MOF nullocrystals (1D nullofibers, 2D nullosheets and 3D aggregates) with controllable morphology by varying the concentration of 4,4'-bipyridine and thus controlling the crystal growth direction. Owing to the shorter ion diffusion length, enhanced electron/ion transfer and strong interactions between thiophene-2,5-dicarboxylate and 4,4'-bipyridine, the 2D nullosheets showed much larger specific capacitance than 1D nullofibers and 3D aggregates. A single device with an output voltage as high as 3.0 V and exceptional cycling performance (95% of retention after 5000 cycles at 3 mA cm(-2)) was realized by configuring two aqueous asymmetric supercapacitive devices in series. The excellent cycling property and charge-discharge mechanism are consistent with the hard-soft-acid-base theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2022, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab197", "DOI": "10.1093/nsr/nwab197", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab197", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837772000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "May, AF; Ovchinnikov, D; Zheng, Q; Hermann, R; Calder, S; Huang, B; Fei, ZY; Liu, YH; Xu, XD; McGuire, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "May, Andrew F.; Ovchinnikov, Dmitry; Zheng, Qiang; Hermann, Raphael; Calder, Stuart; Huang, Bevin; Fei, Zaiyao; Liu, Yaohua; Xu, Xiaodong; McGuire, Michael A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferromagnetism Near Room Temperature in the Cleavable van der Waals Crystal Fe5GeTe2", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials with intrinsic functionality are becoming increasingly important in exploring fundamental condensed matter science and for developing advanced technologies. Bulk crystals that can be exfoliated are particularly relevant to these pursuits as they provide the opportunity to study the role of physical dimensionality and explore device physics in highly crystalline samples and designer heterostructures in a routine manner. Magnetism is a key element in these endeavors; however, relatively few cleavable materials are magnetic and none possess magnetic order at ambient conditions. Here, we introduce Fe5-xGeTe2 as a cleavable material with ferromagnetic behavior at room temperature. We established intrinsic magnetic order at room temperature in bulk crystals (T-C = 310 K) through magnetization measurements and in exfoliated, thin flakes (T-C approximate to 280 K) using the anomalous Hall effect. Our work reveals Fe5GeTe2 as a prime candidate for incorporating intrinsic magnetism into functional van der Waals heterostructures and devices near room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4436, "End Page": 4442, "Article Number": null, "DOI": "10.1021/acsnullo.8b09660", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b09660", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466052900068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, SM; Miao, XB; Zhao, X; Ma, C; Qiu, YH; Hu, ZP; Zhao, JY; Shi, L; Zeng, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Shiming; Miao, Xianbing; Zhao, Xu; Ma, Chao; Qiu, Yuhao; Hu, Zhenpeng; Zhao, Jiyin; Shi, Lei; Zeng, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering electrocatalytic activity in nullosized perovskite cobaltite through surface spin-state transition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The activity of electrocatalysts exhibits a strongly dependence on their electronic structures. Specifically, for perovskite oxides, Shao-Horn and co-workers have reported a correlation between the oxygen evolution reaction activity and the e(g) orbital occupation of transition-metal ions, which provides guidelines for the design of highly active catalysts. Here we demonstrate a facile method to engineer the e(g) filling of perovskite cobaltite LaCoO3 for improving the oxygen evolution reaction activity. By reducing the particle size to similar to 80 nm, the e(g) filling of cobalt ions is successfully increased from unity to near the optimal configuration of 1.2 expected by Shao-Horn's principle. Consequently, the activity is significantly enhanced, comparable to those of recently reported cobalt oxides with e(g) similar to 1.2 configurations. This enhancement is ascribed to the emergence of spin-state transition from low-spin to high-spin states for cobalt ions at the surface of the nulloparticles, leading to more active sites with increased reactivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11510, "DOI": "10.1038/ncomms11510", "DOI Link": "http://dx.doi.org/10.1038/ncomms11510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375930600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, JK; Huang, XP; Boriskina, SV; Loomis, J; Xu, YF; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Jonathan K.; Huang, Xiaopeng; Boriskina, Svetlana V.; Loomis, James; Xu, Yanfei; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared-Transparent Visible-Opaque Fabrics for Wearable Personal Thermal Management", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Personal cooling technologies locally control the temperature of an individual rather than a large space, thus, providing personal thermal comfort while supplementing cooling loads in thermally regulated environments. This can lead to significant energy and cost savings. In this study, a new approach to personal cooling was developed using an infrared-transparent visible-opaque fabric (ITVOF) that provides passive cooling via the transmission of thermal radiation emitted by the human body directly to the environment. Here, we present a conceptual framework to thermally and optically design an ITVOF. Using a heat transfer model, the fabric was found to require a minimum infrared (IR) transmittance of 0.644 and a maximum IR reflectance of 0.2 to ensure thermal comfort at ambient temperatures as high as 26.1 degrees C (79 degrees F). To meet these requirements, an ITVOF design was developed using synthetic polymer fibers with an intrinsically low IR absorptance. These fibers were then structured to minimize IR reflection via weak Rayleigh scattering while maintaining visible opaqueness via strong Mie scattering. For a fabric composed of parallel-aligned polyethylene fibers, numerical finite element simulations predict 1 mu m diameter fibers bundled into 30 mu m yarns can achieve a total hemispherical IR transmittance of 0.972, which is nearly perfectly transparent to mid- and far-IR radiation. The visible wavelength properties of the ITVOF are comparable to conventional textiles ensuring opaqueness to the human eye. By providing personal cooling in a form amenable to everyday use, ITVOF-based clothing offers a simple, low-cost solution to reduce energy consumption in HVAC systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 769, "End Page": 778, "Article Number": null, "DOI": "10.1021/acsphotonics.5b00140", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.5b00140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356757900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Protesescu, L; Yakunin, S; Bodnarchuk, MI; Bertolotti, F; Masciocchi, N; Guagliardi, A; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.; Bertolotti, Federica; Masciocchi, Norberto; Guagliardi, Antonietta; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monodisperse Formamidinium Lead Bromide nullocrystals with Bright and Stable Green Photoluminescence", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bright green emitters with adjustable photoluminescence (PL) maxima in the range of 530-535 nm and full-width at half-maxima (fwhm) of <25 nm are particularly desirable for applications in television displays and related technologies. Toward this goal, we have developed a facile synthesis of highly monodisperse, cubic-shaped formamidinium lead bromide nullocrystals (FAPbBr(3) NCs) with perovskite crystal structure, tunable PL in the range of 470-540 rim by adjusting the nullocrystal-size (5-12 nm), high quantum yield (QY) of up to 85% and PL fwhm of <22 nm. High QYs are also retained in films of FAPbBr(3) NCs. In addition, these films exhibit low thresholds of 14 +/- 2 mu J cm(-2) for amplified spontaneous emission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2016, "Volume": 138, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14202, "End Page": 14205, "Article Number": null, "DOI": "10.1021/jacs.6b08900", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b08900", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387095000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, FM; Davis, SJ; Ciais, P; Crawford-Brown, D; Guan, DB; Pade, C; Shi, TM; Syddall, M; Lv, J; Ji, LZ; Bing, LF; Wang, JY; Wei, W; Yang, KH; Lagerblad, B; Galan, I; Andrade, C; Zhang, Y; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Fengming; Davis, Steven J.; Ciais, Philippe; Crawford-Brown, Douglas; Guan, Dabo; Pade, Claus; Shi, Tiemao; Syddall, Mark; Lv, Jie; Ji, Lanzhu; Bing, Longfei; Wang, Jiaoyue; Wei, Wei; Yang, Keun-Hyeok; Lagerblad, Bjorn; Galan, Isabel; Andrade, Carmen; Zhang, Ying; Liu, Zhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Substantial global carbon uptake by cement carbonation", "Source Title": "NATURE GEOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Calcination of carbonate rocks during the manufacture of cement produced 5% of global CO2 emissions from all industrial process and fossil-fuel combustion in 2013(1,2). Considerable attention has been paid to quantifying these industrial process emissions from cement production(2,3), but the natural reversal of the process-carbonation-has received little attention in carbon cycle studies. Here, we use new and existing data on cement materials during cement service life, demolition, and secondary use of concrete waste to estimate regional and global CO2 uptake between 1930 and 2013 using an analytical model describing carbonation chemistry. We find that carbonation of cement materials over their life cycle represents a large and growing net sink of CO2, increasing from 0.10 GtC yr(-1) in 1998 to 0.25 GtC yr(-1) in 2013. In total, we estimate that a cumulative amount of 4.5 GtC has been sequestered in carbonating cement materials from 1930 to 2013, offsetting 43% of the CO2 emissions from production of cement over the same period, not including emissions associated with fossil use during cement production. We conclude that carbonation of cement products represents a substantial carbon sink that is not currently considered in emissions inventories(1,3,4).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 880, "End Page": "+", "Article Number": null, "DOI": "10.1038/NGEO2840", "DOI Link": "http://dx.doi.org/10.1038/NGEO2840", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390478700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Du, JF; Guo, Z; Yu, J; Gao, Q; Yin, WY; Zhu, S; Gu, ZJ; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao; Du, Jiangfeng; Guo, Zhao; Yu, Jie; Gao, Qin; Yin, Wenyan; Zhu, Shuang; Gu, Zhanjun; Zhao, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Near Infrared Light Triggered Nitric Oxide Release nullocomposites for Sensitizing Mild Photothermal Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mild photothermal therapy (PTT), as a new anticancer therapeutic strategy, faces big challenges of limited therapeutic accuracy and side-effects due to uneven heat distribution. Here, near infrared triggered nitric oxide (NO) release nullocomposites based on bismuth sulfide (Bi2S3) nulloparticles and bis-N-nitroso compounds (BNN) are constructed for NO-enhanced mild photothermal therapy. Upon 808 nm irradiation, the high photothermal conversion efficiency and on-demand NO release are realized simultaneously. Due to the unique properties of NO, enhanced antitumor efficacy of mild PTT based on BNN-Bi2S3 nullocomposites is achieved in vitro and in vivo. Mechanism studies reveal that the exogenous NO from BNN-Bi2S3 could not only impair the autophagic self-repairing ability of tumor cells in situ, but also diffuse to the surrounding cells to enhance the therapeutic effect. This work points out a strategy to overcome the difficulties in mild PTT, and has potentials for further exploitation of NO-sensitized synergistic cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2019, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801122, "DOI": "10.1002/advs.201801122", "DOI Link": "http://dx.doi.org/10.1002/advs.201801122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458118100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tagg, AS; Sapp, M; Harrison, JP; Ojeda, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tagg, Alexander S.; Sapp, Melanie; Harrison, Jesse P.; Ojeda, Jesus J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification and Quantification of Microplastics in Wastewater Using Focal Plane Array-Based Reflectance Micro-FT-IR Imaging", "Source Title": "ANALYTICAL CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastics (<5 mm) have been documented in environmental samples on a global scale. While these pollutants may enter aquatic environments via wastewater treatment facilities, the abundance of microplastics in these matrices has not been investigated. Although efficient methods for the analysis of microplastics in sediment samples and marine organisms have been published, no methods have been developed for detecting these pollutants within organic-rich wastewater samples. In addition, there is no standardized method for analyzing microplastics isolated from environmental samples. In many cases, part of the identification protocol relies on visual selection before analysis, which is open to bias. In order, to address this, a new method for the analysis of microplastics in Wastewater was developed. A pretreatment step using 30% hydrogen peroxide (H2O2) was employed to remove biogenic material, and focal plane array (FPA)-based reflectance Micro-Fourier-transform (FT-IR) imaging was shown to successfully image and identify different microplastic types (polyethylene, polypropylene, nylon-6, polyvinyl chloride, polystyrene). Microplastic-spiked wastewater samples were used to validate the methodology, resulting in a robust protocol which was nonselective and reproducible (the overall success identification rate was 98.33%). The use of FPA-based micro-FT-IR spectroscopy also provides a considerable reduction in analysis time compared with previous methods, since samples that could take several days to be mapped using a single-element detector can now be imaged in less than 9 h (circular filter with a diameter of 47 mm). This method for identifying and quantifying microplastics in wastewater is likely to provide an essential tool for further research into the pathways by which microplastics enter the environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2015, "Volume": 87, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6032, "End Page": 6040, "Article Number": null, "DOI": "10.1021/acs.analchem.5b00495", "DOI Link": "http://dx.doi.org/10.1021/acs.analchem.5b00495", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356755100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, T; Pan, ZH; Vequizo, JJM; Kato, K; Wu, BB; Yamakata, A; Katayama, K; Chen, BL; Chu, CH; Domen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tian; Pan, Zhenhua; Vequizo, Junie Jhon M.; Kato, Kosaku; Wu, Binbin; Yamakata, Akira; Katayama, Kenji; Chen, Baoliang; Chu, Chiheng; Domen, Kazunari", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overall photosynthesis of H2O2 by an inorganic semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis of H2O2 using earth-abundant water and oxygen is a promising approach to achieve scalable and cost-effective solar fuel production. Recent studies on this topic have made significant progress, yet are mainly focused on using organic polymers. This set of photocatalysts is susceptible to potent oxidants (e.g. hydroxyl radical) that are inevitably formed during H2O2 generation. Here, we report an inorganic Mo-doped faceted BiVO4 (Mo:BiVO4) system that is resistant to radical oxidation and exhibits a high overall H2O2 photosynthesis efficiency among inorganic photocatalysts, with an apparent quantum yield of 1.2% and a solar-to-chemical conversion efficiency of 0.29% at full spectrum, as well as an apparent quantum yield of 5.8% at 420 nm. The surface-reaction kinetics and selectivity of Mo:BiVO4 were tuned by precisely loading CoOx and Pd on {110} and {010} facets, respectively. Time-resolved spectroscopic investigations of photocarriers suggest that depositing select cocatalysts on distinct facet tailored the interfacial energetics between {110} and {010} facets and enhanced charge separation in Mo:BiVO4, therefore overcoming a key challenge in developing efficient inorganic photocatalysts. The promising H2O2 generation efficiency achieved by delicate design of catalyst spatial and electronic structures sheds light on applying robust inorganic particulate photocatalysts to artificial photosynthesis of H2O2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1034, "DOI": "10.1038/s41467-022-28686-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28686-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000769633800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Senkov, ON; Miller, JD; Miracle, DB; Woodward, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Senkov, O. N.; Miller, J. D.; Miracle, D. B.; Woodward, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated exploration of multi-principal element alloys with solid solution phases", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent multi-principal element, high entropy alloy (HEA) development strategies vastly expand the number of candidate alloy systems, but also pose a new challenge-how to rapidly screen thousands of candidate alloy systems for targeted properties. Here we develop a new approach to rapidly assess structural metals by combining calculated phase diagrams with simple rules based on the phases present, their transformation temperatures and useful microstructures. We evaluate over 130,000 alloy systems, identifying promising compositions for more time-intensive experimental studies. We find the surprising result that solid solution alloys become less likely as the number of alloy elements increases. This contradicts the major premise of HEAs-that increased configurational entropy increases the stability of disordered solid solution phases. As the number of elements increases, the configurational entropy rises slowly while the probability of at least one pair of elements favouring formation of intermetallic compounds increases more rapidly, explaining this apparent contradiction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 650, "Times Cited, All Databases": 694, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6529, "DOI": "10.1038/ncomms7529", "DOI Link": "http://dx.doi.org/10.1038/ncomms7529", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JL; Wang, XY; Liang, D; Xu, N; Zhu, B; Li, W; Yao, PC; Jiang, Y; Min, XZ; Huang, ZZ; Zhu, SN; Fan, SH; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jinlei; Wang, Xueyang; Liang, Dong; Xu, Ning; Zhu, Bin; Li, Wei; Yao, Pengcheng; Jiang, Yi; Min, Xinzhe; Huang, Zhengzong; Zhu, Shining; Fan, Shanhui; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A tandem radiative/evaporative cooler for weather-insensitive and high-performance daytime passive cooling", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radiative cooling and evaporative cooling with low carbon footprint are regarded as promising passive cooling strategies. However, the intrinsic limits of continuous water supply with complex systems for evaporative cooling, and restricted cooling power as well as the strict requirement of weather conditions for radiative cooling, hinder the scale of their practical applications. Here, we propose a tandem passive cooler composed of bilayer polymer that enables dual-functional passive cooling of radiation and evaporation. Specifically, the high reflectivity to sunlight and mid-infrared emissivity of this polymer film allows excellent radiative cooling performance, and its good atmospheric water harvesting property of underlayer ensures self-supply of water and high evaporative cooling power. Consequently, this tandem passive cooler overcomes the fundamental difficulties of radiative cooling and evaporative cooling and shows the applicability under various conditions of weather/climate. It is expected that this design can expand the practical application domain of passive cooling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2022, "Volume": 8, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabq0411", "DOI": "10.1126/sciadv.abq0411", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abq0411", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000841491100031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, DW; Liang, ZF; Tang, PY; Zhang, CQ; Tang, MX; Li, QZ; Biendicho, JJ; Li, JS; Heggen, M; Dunin-Borkowski, RE; Xu, M; Llorca, J; Arbiol, J; Morante, JR; Chou, SL; Cabot, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dawei; Liang, Zhifu; Tang, Pengyi; Zhang, Chaoqi; Tang, Mingxue; Li, Qizhen; Biendicho, Jordi Jacas; Li, Junshan; Heggen, Marc; Dunin-Borkowski, Rafal E.; Xu, Ming; Llorca, Jordi; Arbiol, Jordi; Morante, Joan Ramon; Chou, Shu-Lei; Cabot, Andreu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A High Conductivity 1D π-d Conjugated Metal-Organic Framework with Efficient Polysulfide Trapping-Diffusion-Catalysis in Lithium-Sulfur Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The shuttling behavior and sluggish conversion kinetics of the intermediate lithium polysulfides (LiPS) represent the main obstructions to the practical application of lithium-sulfur batteries (LSBs). Herein, a 1D pi-d conjugated metal-organic framework (MOF), Ni-MOF-1D, is presented as an efficient sulfur host to overcome these limitations. Experimental results and density functional theory calculations demonstrate that Ni-MOF-1D is characterized by a remarkable binding strength for trapping soluble LiPS species. Ni-MOF-1D also acts as an effective catalyst for S reduction during the discharge process and Li2S oxidation during the charging process. In addition, the delocalization of electrons in the pi-d system of Ni-MOF-1D provides a superior electrical conductivity to improve electron transfer. Thus, cathodes based on Ni-MOF-1D enable LSBs with excellent performance, for example, impressive cycling stability with over 82% capacity retention over 1000 cycles at 3 C, superior rate performance of 575 mAh g(-1) at 8 C, and a high areal capacity of 6.63 mAh cm(-2) under raised sulfur loading of 6.7 mg cm(-2). The strategies and advantages here demonstrated can be extended to a broader range of pi-d conjugated MOFs materials, which the authors believe have a high potential as sulfur hosts in LSBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 34, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2108835, "DOI": "10.1002/adma.202108835", "DOI Link": "http://dx.doi.org/10.1002/adma.202108835", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747786300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, H; Li, WL; Pan, LM; Cullen, CP; Liu, Y; Pakdel, A; Long, DH; Yang, J; McEvoy, N; Duesberg, GS; Nicolosi, V; Zhang, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Huan; Li, Wenlong; Pan, Limei; Cullen, Conor P.; Liu, Yu; Pakdel, Amir; Long, Donghui; Yang, Jian; McEvoy, Niall; Duesberg, Georg S.; Nicolosi, Valeria; Zhang, Chuanfang (John)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Formed Protective Barrier Enabled by Sulfur@Titanium Carbide (MXene) Ink for Achieving High-Capacity, Long Lifetime Li-S Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfur (S) is an attractive cathode material with advantages including high theoretical capacity and low cost. However, issues such as the lithium polysulfide shuttle effect and its insulating properties greatly limit the future applications of lithium-sulfur (Li-S) batteries. Here, a viscous aqueous ink with nulloscale S uniformly decorated on the polar, metallically conductive titanium carbide MXene nullosheets (S@Ti3C2Tx) is reported to address these issues. Importantly, it is observed that the conductive Ti3C2Tx mediator efficiently chemisorbs the soluble polysulfides and converts them into thiosulfate/sulfate. The in situ formed sulfate complex layer acts as a thick protective barrier, which significantly retards the shuttling of polysulfides upon cycling and improves the sulfur utilization. Consequently, the binder-free, robust, highly electrically conductive composite film exhibits outstanding electrochemical performance, including high capacities (1244-1350 mAh g(-1)), excellent rate handling, and impressive cycling stability (0.035-0.048% capacity loss per cycle), surpassing the best MXene-S batteries known. The fabrication of a pouch cell based on the freestanding S@Ti3C2Tx film is also reported. The prototype device showcases high capacities and excellent mechanical flexibility. Considering the broad family of MXenes and their unique roles in immobilizing the polysulfides, various S@MXene composites can be similarly fabricated with promising Li+ storage capability and long lifetime performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800502, "DOI": "10.1002/advs.201800502", "DOI Link": "http://dx.doi.org/10.1002/advs.201800502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444940600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marega, GM; Zhao, YF; Avsar, A; Wang, ZY; Tripathi, M; Radenovic, A; Kis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Migliato Marega, Guilherme; Zhao, Yanfei; Avsar, Ahmet; Wang, Zhenyu; Tripathi, Mukesh; Radenovic, Aleksandra; Kis, Andras", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Logic-in-memory based on an atomically thin semiconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growing importance of applications based on machine learning is driving the need to develop dedicated, energy-efficient electronic hardware. Compared with von Neumann architectures, which have separate processing and storage units, brain-inspired in-memory computing uses the same basic device structure for logic operations and data storage(1-3), thus promising to reduce the energy cost of data-centred computing substantially(4). Although there is ample research focused on exploring new device architectures, the engineering of material platforms suitable for such device designs remains a challenge. Two-dimensional materials(5,6) such as semiconducting molybdenum disulphide, MoS2, could be promising candidates for such platforms thanks to their exceptional electrical and mechanical properties(7-9). Here we report our exploration of large-area MoS2 as an active channel material for developing logic-in-memory devices and circuits based on floating-gate field-effect transistors (FGFETs). The conductance of our FGFETs can be precisely and continuously tuned, allowing us to use them as building blocks for reconfigurable logic circuits in which logic operations can be directly performed using the memory elements. After demonstrating a programmable NOR gate, we show that this design can be simply extended to implement more complex programmable logic and a functionally complete set of operations. Our findings highlight the potential of atomically thin semiconductors for the development of next-generation low-power electronics. Logic operations and reconfigurable circuits are demonstrated that can be directly implemented using memory elements based on floating-gate field-effect transistors with monolayer MoS2 as the active channel material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2020, "Volume": 587, "Issue": 7832, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2861-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2861-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000587009600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Qiu, LB; Ono, LK; He, SS; Hu, ZH; Jiang, MW; Tong, GQ; Wu, ZF; Jiang, Y; Son, DY; Dang, YY; Kazaoui, S; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zonghao; Qiu, Longbin; Ono, Luis K.; He, Sisi; Hu, Zhanhao; Jiang, Maowei; Tong, Guoqing; Wu, Zhifang; Jiang, Yan; Son, Dae-Yong; Dang, Yangyang; Kazaoui, Said; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A holistic approach to interface stabilization for efficient perovskite solar modules with over 2,000-hour operational stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The upscaling of layer treatments and processing that afford high efficiency and stability in small-area perovskite solar cells remains challenging. Liu et al. show how the efficiency and stability of perovskite modules can be improved using an integrated approach to interface and layer engineering. The upscaling of perovskite solar cells to module scale and long-term stability have been recognized as the most important challenges for the commercialization of this emerging photovoltaic technology. In a perovskite solar module, each interface within the device contributes to the efficiency and stability of the module. Here, we employed a holistic interface stabilization strategy by modifying all the relevant layers and interfaces, namely the perovskite layer, charge transporting layers and device encapsulation, to improve the efficiency and stability of perovskite solar modules. The treatments were selected for their compatibility with low-temperature scalable processing and the module scribing steps. Our unencapsulated perovskite solar modules achieved a reverse-scan efficiency of 16.6% for a designated area of 22.4 cm(2). The encapsulated perovskite solar modules, which show efficiencies similar to the unencapsulated one, retained approximately 86% of the initial performance after continuous operation for 2,000 h under AM1.5G light illumination, which translates into aT(90)lifetime (the time over which the device efficiency reduces to 90% of its initial value) of 1,570 h and an estimatedT(80)lifetime (the time over which the device efficiency reduces to 80% of its initial value) of 2,680 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 596, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-020-0653-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0653-2", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000550652600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aytac, Z; Ipek, S; Durgun, E; Tekinay, T; Uyar, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aytac, Zeynep; Ipek, Semran; Durgun, Engin; Tekinay, Turgay; Uyar, Tamer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial electrospun zein nullofibrous web encapsulating thymol/cyclodextrin-inclusion complex for food packaging", "Source Title": "FOOD CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thymol (THY)/gamma-Cyclodextrin(gamma-CD) inclusion complex (IC) encapsulated electrospun zein nullofibrous webs (zein-THY/gamma-CD-IC-NF) were fabricated as a food packaging material. The formation of THY/gamma-CD-IC (1:1 and 2:1) was proved by experimental (X-ray diffraction (XRD), thermal gravimetric analysis (TGA), H-1 NMR) and computational techniques. THY/gamma-CD-IC (2:1) exhibited higher preservation rate and stability than THY/gamma-CD-IC (1:1). It is worth mentioning that zein-THY/gamma-CD-IC-NF (2:1) preserved much more THY as observed in TGA and stability of THY/gamma-CD-IC (2:1) was higher, as shown by a modelling study. Therefore, much more THY was released from zein-THY/gamma-CD-IC-NF (2:1) than zein-THY-NF and zein-THY/gamma-CD-IC-NF (1:1). Similarly, antibacterial activity of zein-THY/gamma-CD-IC-NF (2:1) was higher than zein-THY-NF and zein-THY/gamma-CD-IC-NF (1:1). It was demonstrated that zein-THY/gamma-CD-IC-NF (2:1) was most effective in inhibiting the growth of bacteria on meat samples. These webs show potential application as an antibacterial food packaging material. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2017, "Volume": 233, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 117, "End Page": 124, "Article Number": null, "DOI": "10.1016/j.foodchem.2017.04.095", "DOI Link": "http://dx.doi.org/10.1016/j.foodchem.2017.04.095", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology; Nutrition & Dietetics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402343100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Afroj, S; Tan, SR; Abdelkader, AM; Novoselov, KS; Karim, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Afroj, Shaila; Tan, Sirui; Abdelkader, Amr M.; Novoselov, Kostya S.; Karim, Nazmul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Conductive, Scalable, and Machine Washable Graphene-Based E-Textiles for Multifunctional Wearable Electronic Applications", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene-based textiles show promise for next-generation wearable electronic applications due to their advantages over metal-based technologies. However, current reduced graphene oxide (rGO)-based electronic textiles (e-textiles) suffer from poor electrical conductivity and higher power consumption. Here, highly conductive, ultraflexible, and machine washable graphene-based wearable e-textiles are reported. A simple and scalable pad-dry-cure method with subsequent roller compression and a fine encapsulation of graphene flakes is used. The graphene-based wearable e-textiles thus produced provide lowest sheet resistance (approximate to 11.9 omega sq(-1)) ever reported on graphene e-textiles, and highly conductive even after 10 home laundry washing cycles. Moreover, it exhibits extremely high flexibility, bendability, and compressibility as it shows repeatable response in both forward and backward directions before and after home laundry washing cycles. The scalability and multifunctional applications of such highly conductive graphene-based wearable e-textiles are demonstrated as ultraflexible supercapacitor and skin-mounted strain sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 30, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000293, "DOI": "10.1002/adfm.202000293", "DOI Link": "http://dx.doi.org/10.1002/adfm.202000293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000538154000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YQ; Zhao, HB; Cheng, JB; Liu, BW; Fu, Q; Wang, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yan-Qin; Zhao, Hai-Bo; Cheng, Jin-Bo; Liu, Bo-Wen; Fu, Qiang; Wang, Yu-Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Ti3C2Tx@ZnO Hollow Spheres with Excellent Microwave Absorption Inspired by the Visual Phenomenon of Eyeless Urchins", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ingenious microstructure design and rational composition selection are effective approaches to realize high-performance microwave absorbers, and the advancement of biomimetic manufacturing provides a new strategy. In nature, urchins are the animals without eyes but can see, because their special structure composed of regular spines and spherical photosensitive bodies amplifies the light-receiving ability. Herein, inspired by the above phenomenon, the biomimetic urchin-like Ti3C2Tx@ZnO hollow microspheres are rationally designed and fabricated, in which ZnO nulloarrays (length: similar to 2.3 mu m, diameter: similar to 100 nm) as the urchin spines are evenly grafted onto the surface of the Ti3C2Tx hollow spheres (diameter: similar to 4.2 mu m) as the urchin spherical photosensitive bodies. The construction of gradient impedance and hierarchical hetero- Fraquency (CHzi structures enhance the attenuation of incident electromagnetic waves. And the EMW loss behavior is further revealed by limited integral simulation calculations, which fully highlights the advantages of the urchin-like architecture. As a result, the Ti3C2Tx@ZnO hollow spheres deliver a strong reflection loss of - 57.4 dB and broad effective absorption bandwidth of 6.56 GHz, superior to similar absorbents. This work provides a new biomimetic strategy for the design and manufacturing of advanced microwave absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76, "DOI": "10.1007/s40820-022-00817-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00817-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771472800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nayak, AP; Bhattacharyya, S; Zhu, J; Liu, J; Wu, X; Pandey, T; Jin, CQ; Singh, AK; Akinwande, D; Lin, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nayak, Avinash P.; Bhattacharyya, Swastibrata; Zhu, Jie; Liu, Jin; Wu, Xiang; Pandey, Tribhuwan; Jin, Changqing; Singh, Abhishek K.; Akinwande, Deji; Lin, Jung-Fu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-induced semiconducting to metallic transition in multilayered molybdenum disulphide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum disulphide is a layered transition metal dichalcogenide that has recently raised considerable interest due to its unique semiconducting and opto-electronic properties. Although several theoretical studies have suggested an electronic phase transition in molybdenum disulphide, there has been a lack of experimental evidence. Here we report comprehensive studies on the pressure-dependent electronic, vibrational, optical and structural properties of multilayered molybdenum disulphide up to 35 GPa. Our experimental results reveal a structural lattice distortion followed by an electronic transition from a semiconducting to metallic state at similar to 19 GPa, which is confirmed by ab initio calculations. The metallization arises from the overlap of the valance and conduction bands owing to sulphur-sulphur interactions as the interlayer spacing reduces. The electronic transition affords modulation of the opto-electronic gain in molybdenum disulphide. This pressure-tuned behaviour can enable the development of novel devices with multiple phenomena involving the strong coupling of the mechanical, electrical and optical properties of layered nullomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3731, "DOI": "10.1038/ncomms4731", "DOI Link": "http://dx.doi.org/10.1038/ncomms4731", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337365500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZW; Lv, YW; Ren, LW; Li, J; Kong, LA; Zeng, YJ; Tao, QY; Wu, RX; Ma, HF; Zhao, B; Wang, D; Dang, WQ; Chen, KQ; Liao, L; Duan, XD; Duan, XF; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiwei; Lv, Yawei; Ren, Liwang; Li, Jia; Kong, Lingan; Zeng, Yujia; Tao, Quanyang; Wu, Ruixia; Ma, Huifang; Zhao, Bei; Wang, Di; Dang, Weiqi; Chen, Keqiu; Liao, Lei; Duan, Xidong; Duan, Xiangfeng; Liu, Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient strain modulation of 2D materials via polymer encapsulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strain engineering is a promising method to manipulate the electronic and optical properties of two-dimensional (2D) materials. However, with weak van der Waals interaction, severe slippage between 2D material and substrate could dominate the bending or stretching processes, leading to inefficiency strain transfer. To overcome this limitation, we report a simple strain engineering method by encapsulating the monolayer 2D material in the flexible PVA substrate through spin-coating approach. The strong interaction force between spin-coated PVA and 2D material ensures the mechanical strain can be effectively transferred with negligible slippage or decoupling. By applying uniaxial strain to monolayer MoS2, we observe a higher bandgap modulation up to similar to 300 meV and a highest modulation rate of similar to 136 meV/%, which is approximate two times improvement compared to previous results achieved. Moreover, this simple strategy could be well extended to other 2D materials such as WS2 or WSe2, leading to enhanced bandgap modulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1151, "DOI": "10.1038/s41467-020-15023-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15023-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520939200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; deGlee, B; Tang, Y; Wang, ZY; Zhao, BT; Wei, YC; Zhang, L; Yoo, S; Pei, K; Kim, JH; Ding, Y; Hu, P; Tao, FF; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yu; deGlee, Ben; Tang, Yu; Wang, Ziyun; Zhao, Bote; Wei, Yuechang; Zhang, Lei; Yoo, Seonyoung; Pei, Kai; Kim, Jun Hyuk; Ding, Yong; Hu, P.; Tao, Franklin Feng; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust fuel cell operated on nearly dry methane at 500 °C enabled by synergistic thermal catalysis and electrocatalysis", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid oxide fuel cells (SOFCs) are potentially the most efficient technology for direct conversion of hydrocarbons to electricity. While their commercial viability is greatest at operating temperatures of 300-500 degrees C, it is extremely difficult to run SOFCs on methane at these temperatures, where oxygen reduction and C-H activation are notoriously sluggish. Here we report a robust SOFC that enabled direct utilization of nearly dry methane (with similar to 3.5% H2O) at 500 degrees C (achieving a peak power density of 0.37W cm(-2)) with no evidence of coking after similar to 550 h operation. The cell consists of a PrBa0.5Sr0.5Co1.5Fe0.5O5+delta nullofibre-based cathode and a BaZr0.1Ce0.7Y0.1Yb0.1O3-delta-based multifunctional anode coated with Ce0.90Ni0.05Ru0.05O2 (CNR) catalyst for reforming of CH4 to H-2 and CO. The high activity and coking resistance of the CNR is attributed to a synergistic effect of cationic Ni and Ru sites anchored on the CNR surface, as confirmed by in situ/operando experiments and computations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1042, "End Page": 1050, "Article Number": null, "DOI": "10.1038/s41560-018-0262-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0262-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452650200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, DS; Hadad, M; Riemer, LM; Ignatans, R; Spirito, D; Esposito, ; Tileli, ; Gauquelin, N; Chezganov, D; Jannis, D; Verbeeck, J; Gorfman, S; Pryds, N; Muralt, P; Damjanovic, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, D-S; Hadad, M.; Riemer, L. M.; Ignatans, R.; Spirito, D.; Esposito, V; Tileli, V; Gauquelin, N.; Chezganov, D.; Jannis, D.; Verbeeck, J.; Gorfman, S.; Pryds, N.; Muralt, P.; Damjanovic, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Induced giant piezoelectricity in centrosymmetric oxides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectrics are materials that linearly deform in response to an applied electric field. As a fundamental prerequisite, piezoelectric materials must have a noncentrosymmetric crystal structure. For more than a century, this has remained a major obstacle for finding piezoelectric materials. We circumvented this limitation by breaking the crystallographic symmetry and inducing large and sustainable piezoelectric effects in centrosymmetric materials by the electric field-induced rearrangement of oxygen vacancies. Our results show the generation of extraordinarily large piezoelectric responses [with piezoelectric strain coefficients (d(33)) of similar to 200,000 picometers per volt at millihertz frequencies] in cubic fluorite gadolinium-doped CeO2-x films, which are two orders of magnitude larger than the responses observed in the presently best-known lead-based piezoelectric relaxor-ferroelectric oxide at kilohertz frequencies. These findings provide opportunities to design piezoelectric materials from environmentally friendly centrosymmetric ones.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2022, "Volume": 375, "Issue": 6581, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 653, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm7497", "DOI Link": "http://dx.doi.org/10.1126/science.abm7497", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753975300036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, S; Hong, YY; Zhao, Y; Yin, J; Zhu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuang; Hong, Yaoye; Zhao, Yao; Yin, Jie; Zhu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Caterpillar-inspired soft crawling robot with distributed programmable thermal actuation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many inspirations for soft robotics are from the natural world, such as octopuses, snakes, and caterpillars. Here, we report a caterpillar-inspired, energy-efficient crawling robot with multiple crawling modes, enabled by joule heating of a patterned soft heater consisting of silver nullowire networks in a liquid crystal elastomer (LCE)- based thermal bimorph actuator. With patterned and distributed heaters and programmable heating, different temperature and hence curvature distribution along the body of the robot are achieved, enabling bidirectional locomotion as a result of the friction competition between the front and rear end with the ground. The thermal bimorph behavior is studied to predict and optimize the local curvature of the robot under thermal stimuli. The bidirectional actuation modes with the crawling speeds are investigated. The capability of passing through ob-stacles with limited spacing are demonstrated. The strategy of distributed and programmable heating and ac-tuation with thermal responsive materials offers unprecedented capabilities for smart and multifunctional soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf8014", "DOI": "10.1126/sciadv.adf8014", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf8014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967266700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Q; Liu, XS; Tao, Y; Huang, JX; Zhang, J; Yang, CP; Zhang, YB; Zhang, SW; Jia, YR; Lin, QW; Xiang, YX; Cheng, J; Lv, W; Kang, FY; Yang, Y; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qi; Liu, Xiangsi; Tao, Ying; Huang, Jianxing; Zhang, Jun; Yang, Chunpeng; Zhang, Yibo; Zhang, Siwei; Jia, Yiran; Lin, Qiaowei; Xiang, Yuxuan; Cheng, Jun; Lv, Wei; Kang, Feiyu; Yang, Yong; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sieving carbons promise practical anodes with extensible low-potential plateaus for sodium batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work vividly images an ideal configuration of practical carbon anodes for high-energy sodium-ion batteries, which greatly challenge lithium-ion batteries in the use of large-scale energy storage. Non-graphitic carbons are promising anode candidates for sodium-ion batteries, while their variable and complicated microstructure severely limits the rational design of high-energy carbon anodes that could accelerate the commercialization of sodium-ion batteries, as is the case for graphite in lithium-ion batteries. Here, we propose sieving carbons, featuring highly tunable nullopores with tightened pore entrances, as high-energy anodes with extensible and reversible low-potential plateaus (<0.1 V). It is shown that the tightened pore entrance blocks the formation of the solid electrolyte interphase inside the nullopores and enables sodium clustering to produce the plateau. Theoretical and spectroscopic studies also show that creating a larger area of sodiophilic pore surface leads to an almost linearly increased number of sodium clusters, and controlling the pore body diameter guarantees the reversibility of sodium cluster formation, producing a sieving carbon anode with a record-high plateau capacity of 400 mAh g(-1). More excitingly, this approach to preparing sieving carbons has the potential to be scalable for modifying different commercial porous carbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1093/nsr/nwac084", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac084", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000815273900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JL; Zhu, L; Li, C; Xu, JQ; Wu, HB; Zhang, XN; Zhang, Y; Tang, Z; Liu, F; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Jiali; Zhu, Lei; Li, Chao; Xu, Jinqu; Wu, Hongbo; Zhang, Xuning; Zhang, Yuan; Tang, Zheng; Liu, Feng; Sun, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency organic solar cells with low voltage loss induced by solvent additive strategy", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High voltage loss (V-loss) limits further improvements of organic solar cells (OSCs), and thus developing effective approaches to reduce V-loss is important. Herein, a solvent additive strategy was employed to reduce V-loss in PM6:L8-BO OSCs. The use of diiodomethane (DIM) instead of 1,8-diiodooctane (DIO) led to a reduction in energetic difference between the single excited state of L8-BO and the charge transfer state in PM6:L8-BO blend, and thereby a reduced V-loss. Meanwhile, the morphology, charge transport property, and quantum efficiency are not deteriorated, Consequently, the DIM-processed OSCs showed a high power conversion efficiency (PCE) of 18.60% (certified as 18.20%) with a high V-oc of 0.893 V, higher than those (PCE = 18.23%, V-oc = 0.869 V) of the DIO-processed devices, representing the highest efficiency for binary OSCs thus far. DIM has also been successfully applied in PM6:BTP-eC9 and PM6:3TP3T-4F blends, and high PCEs with reduced V-loss were also achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2021, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2542, "End Page": 2552, "Article Number": null, "DOI": "10.1016/j.matt.2021.06.010", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2021.06.010", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670754300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZL; Yu, L; Gao, M; Chen, XY; Zhou, W; Ma, C; Wu, LH; Zhu, JF; Meng, XY; Hu, JT; Tu, YC; Wu, SS; Mao, J; Tian, ZQ; Deng, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhilong; Yu, Liang; Gao, Meng; Chen, Xiya; Zhou, Wu; Ma, Chao; Wu, Lihui; Zhu, Junfa; Meng, Xiangyu; Hu, Jingting; Tu, Yunchuan; Wu, Sisi; Mao, Jun; Tian, Zhongqun; Deng, Dehui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting hydrogen evolution on MoS2 via co-confining selenium in surface and cobalt in inner layer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lack of highly efficient, inexpensive catalysts severely hinders large-scale application of electrochemical hydrogen evolution reaction (HER) for producing hydrogen. MoS2 as a low-cost candidate suffers from low catalytic performance. Herein, taking advantage of its tri-layer structure, we report a MoS2 nullofoam catalyst co-confining selenium in surface and cobalt in inner layer, exhibiting an ultra-high large-current-density HER activity surpassing all previously reported heteroatom-doped MoS2. At a large current density of 1000mAcm(-2), a much lower overpotential of 382mV than that of 671mV over commercial Pt/C catalyst is achieved and stably maintained for 360hours without decay. First-principles calculations demonstrate that inner layer-confined cobalt atoms stimulate neighbouring sulfur atoms while surface-confined selenium atoms stabilize the structure, which cooperatively enable the massive generation of both in-plane and edge active sites with optimized hydrogen adsorption activity. This strategy provides a viable route for developing MoS2-based catalysts for industrial HER applications. The lack of efficient, inexpensive catalysts hinders large-scale application of hydrogen evolution reaction (HER). Here, the authors report a MoS2 nullofoam catalyst with co-confined Se in the surface and Co in the inner layer, exhibiting high large-current-density HER activity and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17199-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17199-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546623500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, MS; Xia, BY; Li, YW; Yan, Y; Yang, YH; Sun, Q; Chan, SH; Fisher, A; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Ming Shi; Xia, Bao Yu; Li, Yawei; Yan, Ya; Yang, Yanhui; Sun, Qiang; Chan, Siew Hwa; Fisher, Adrian; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amino acid modified copper electrodes for the enhanced selective electroreduction of carbon dioxide towards hydrocarbons", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of carbon dioxide to hydrocarbons has been proposed as a promising way to utilize CO2 and maintain carbon balance in the environment. Copper (Cu) is an effective electrocatalyst for such a purpose. However, the overall selectivity towards hydrocarbons on Cu-based electrodes is still very limited. In this work, we develop a general amino acid modification approach on Cu electrodes for the selective electroreduction of CO2 towards hydrocarbons. A remarkable enhancement in hydrocarbon generation is achieved on these modified copper electrodes, regardless of the morphology of the Cu electrodes. A density functional theory calculation reveals that the key intermediate CHO star is stabilized by interacting with -NH3+ of the adsorbed zwitterionic glycine. Our results suggest that amino acids and their derivatives are promising modifiers in improving the selectivity of hydrocarbons in CO2 electroreduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1687, "End Page": 1695, "Article Number": null, "DOI": "10.1039/c5ee03694a", "DOI Link": "http://dx.doi.org/10.1039/c5ee03694a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375699500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, TT; Yu, JF; Wang, CF; Chen, S; Li, Q; Guo, K; Qing, RK; Wang, GF; Ren, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Tingting; Yu, Jiafei; Wang, Cai-Feng; Chen, Su; Li, Qing; Guo, Kun; Qing, Renkun; Wang, Gefei; Ren, Jianull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Micro-Gel Ensembles for Accelerated Healing of Chronic Wound via pH Regulation", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pH value in the wound milieu plays a key role in cellular processes and cell cycle processes involved in the process of wound healing. Here, a microfluidic assembly technique is employed to fabricate micro-gel ensembles that can precisely tune the pH value of wound surface and accelerate wound healing. The micro-gel ensembles consist of poly (hydroxypropyl acrylate-co-acrylic acid)-magnesium ions (poly-(HPA-co-AA)-Mg2+) gel and carboxymethyl chitosan (CMCS) gel, which can release and absorb hydrogen ion (H+) separately at different stages of healing in response to the evolution of wound microenvironment. By regulating the wound pH to affect the proliferation and migration of cell on the wound and the activity of various biological factors in the wound, the physiological processes are greatly facilitated which results in much accelerated healing of chronic wound. This work presents an effective strategy in designing wound healing materials with vast potentials for chronic wound management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201254, "DOI": "10.1002/advs.202201254", "DOI Link": "http://dx.doi.org/10.1002/advs.202201254", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799729400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suarez, B; Gonzalez-Pedro, V; Ripolles, TS; Sanchez, RS; Otero, L; Mora-Sero, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suarez, Belen; Gonzalez-Pedro, Victoria; Ripolles, Teresa S.; Sanchez, Rafael S.; Otero, Luis; Mora-Sero, Ivan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recombination Study of Combined Halides (Cl, Br, I) Perovskite Solar Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the preparation of a series of solution-processed perovskite solar cells based on methylammonium (MA) lead halide derivatives, MAPbX(3), which show tunable optical properties depending on the nature and ratio of the halides employed (X = Cl, Br, and I). Devices have been prepared with different cell architecture, thin film, and mesoporous scaffold (TiO2, and Al2O3). We have analyzed different sample sets focusing on the characterization of the charge recombination by means of impedance spectroscopy (IS). On the one hand, our study discloses that the insertion of both Cl and Br in the perovskite lattice reduces the charge recombination rates in the light absorber film, thus determining the open circuit voltage (V-oc) of the device. The samples prepared on a mesoporous Al2O3 electrode present lower charge recombination rates than those devices prepared on mesoporous TiO2. Furthermore, the addition of Br in the perovskite structure was demonstrated to improve slightly the lifetime of the devices; in fact, the efficiencies of all devices tested remained at least at the 80% of the initial value 1 month after their preparation. These results highlight the crucial role of the charge-recombination processes on the performance of the perovskite solar cells and pave the way for further progress on this field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2014, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1628, "End Page": 1635, "Article Number": null, "DOI": "10.1021/jz5006797", "DOI Link": "http://dx.doi.org/10.1021/jz5006797", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336199000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, XY; Zhao, CY; Wang, XN; Wang, ZQ; Fu, SC; Lin, Y; Zeng, T; Zhao, XN; Xu, HY; Zhang, XT; Liu, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Xuanyu; Zhao, Chenyi; Wang, Xinnong; Wang, Zhongqiang; Fu, Shencheng; Lin, Ya; Zeng, Tao; Zhao, Xiaoning; Xu, Haiyang; Zhang, Xintong; Liu, Yichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic Optoelectronic Memristor Enabling Fully Light-Modulated Synaptic Plasticity for Neuromorphic Vision", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploration of optoelectronic memristors with the capability to combine sensing and processing functions is required to promote development of efficient neuromorphic vision. In this work, the authors develop a plasmonic optoelectronic memristor that relies on the effects of localized surface plasmon resonullce (LSPR) and optical excitation in an Ag-TiO2 nullocomposite film. Fully light-induced synaptic plasticity (e.g., potentiation and depression) under visible and ultraviolet light stimulations is demonstrated, which enables the functional combination of visual sensing and low-level image pre-processing (including contrast enhancement and noise reduction) in a single device. Furthermore, the light-gated and electrically-driven synaptic plasticity can be performed in the same device, in which the spike-timing-dependent plasticity (STDP) learning functions can be reversibly modulated by visible and ultraviolet light illuminations. Thereby, the high-level image processing function, i.e., image recognition, can also be performed in this memristor, whose recognition rate and accuracy are obviously enhanced as a result of image pre-processing and light-gated STDP enhancement. Experimental analysis shows that the memristive switching mechanism under optical stimulation can be attributed to the oxidation/reduction of Ag nulloparticles due to the effects of LSPR and optical excitation. The authors' work proposes a new type of plasmonic optoelectronic memristor with fully light-modulated capability that may promote the future development of efficient neuromorphic vision.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104632, "DOI": "10.1002/advs.202104632", "DOI Link": "http://dx.doi.org/10.1002/advs.202104632", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000735908800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ju, L; Tan, X; Mao, X; Gu, YT; Smith, S; Du, AJ; Chen, ZF; Chen, CF; Kou, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ju, Lin; Tan, Xin; Mao, Xin; Gu, Yuantong; Smith, Sean; Du, Aijun; Chen, Zhongfang; Chen, Changfeng; Kou, Liangzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controllable CO2 electrocatalytic reduction via ferroelectric switching on single atom anchored In2Se3 monolayer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of CO2 into chemical fuels holds promise for mitigating environmental pollution and energy crisis. This work presents a distinct design of ferroelectric catalysts with high catalytic activity and selectivity for efficient and controllable electrochemical CO2 reduction reaction. Efficient and selective CO2 electroreduction into chemical fuels promises to alleviate environmental pollution and energy crisis, but it relies on catalysts with controllable product selectivity and reaction path. Here, by means of first-principles calculations, we identify six ferroelectric catalysts comprising transition-metal atoms anchored on In2Se3 monolayer, whose catalytic performance can be controlled by ferroelectric switching based on adjusted d-band center and occupation of supported metal atoms. The polarization dependent activation allows effective control of the limiting potential of CO2 reduction on TM@In2Se3 (TM = Ni, Pd, Rh, Nb, and Re) as well as the reaction paths and final products on Nb@In2Se3 and Re@In2Se3. Interestingly, the ferroelectric switching can even reactivate the stuck catalytic CO2 reduction on Zr@In2Se3. The fairly low limiting potential and the unique ferroelectric controllable CO2 catalytic performance on atomically dispersed transition-metals on In2Se3 clearly distinguish them from traditional single atom catalysts, and open an avenue toward improving catalytic activity and selectivity for efficient and controllable electrochemical CO2 reduction reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5128, "DOI": "10.1038/s41467-021-25426-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25426-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000691126200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, HC; Zan, LX; Yuan, PF; Qu, G; Dong, HL; Wei, YF; Yu, Y; Wei, ZY; Yan, WF; Hu, JS; Deng, DH; Zhang, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Huicong; Zan, Lingxing; Yuan, Pengfei; Qu, Gan; Dong, Hongliang; Wei, Yifan; Yu, Yue; Wei, Zeyu; Yan, Wenfu; Hu, Jin-Song; Deng, Dehui; Zhang, Jia-null", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of Stabilized 1T-MoS2 by Atomic-Interface Engineering of 2H-MoS2/Fe-Nx towards Enhanced Sodium Ion Storage", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic conductive 1T phase molybdenum sulfide (MoS2) has been identified as promising anode for sodium ion (Na+) batteries, but its metastable feature makes it difficult to obtain and its restacking during the charge/discharge processing result in part capacity reversibility. Herein, a synergetic effect of atomic-interface engineering is employed for constructing 2H-MoS2 layers assembled on single atomically dispersed Fe N C (SA Fe N C) anode material that boosts its reversible capacity. The work-function-drivenelectron transfer occurs from SA Fe N C to 2H-MoS2 via the Fe S bonds, which enhances the adsorption of Na+ by 2H-MoS2, and lays the foundation for the sodiation process. A phase transfer from 2H to 1T/2H MoS2 with the ferromagnetic spin-polarization of SA Fe-N-C occurs during the sodiation/desodiation process, which significantly enhances the Na+ storage kinetics, and thus the 1T/2H MoS2/SA Fe N C display a high electronic conductivity and a fast Na+ diffusion rate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2023, "Volume": 62, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202218282", "DOI": "10.1002/anie.202218282", "DOI Link": "http://dx.doi.org/10.1002/anie.202218282", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935216600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, KK; Zhang, J; Lin, DM; Wang, DW; Li, BH; Lv, W; Sun, S; He, YB; Kang, FY; Yang, QH; Zhou, LM; Zhang, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Kaikai; Zhang, Jun; Lin, Dongmei; Wang, Da-Wei; Li, Baohua; Lv, Wei; Sun, Sheng; He, Yan-Bing; Kang, Feiyu; Yang, Quan-Hong; Zhou, Limin; Zhang, Tong-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of the electrochemical interface in sodium ion batteries with ether electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ether based electrolytes have surfaced as alternatives to conventional carbonates allowing for enhanced electrochemical performance of sodium-ion batteries; however, the primary source of the improvement remains poorly understood. Here we show that coupling titanium dioxide and other anode materials with diglyme does enable higher efficiency and reversible capacity than those for the combination involving ester electrolytes. Importantly, the electrolyte dependent performance is revealed to be the result of the different structural evolution induced by a varied sodiation depth. A suit of characterizations show that the energy barrier to charge transfer at the interface between electrolyte and electrode is the factor that dominates the interfacial electrochemical characteristics and therefore the energy storage properties. Our study proposes a reliable parameter to assess the intricate sodiation dynamics in sodium-ion batteries and could guide the design of aprotic electrolytes for next generation rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 725, "DOI": "10.1038/s41467-019-08506-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08506-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458567500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Assadi, H; Kreye, H; Gärtner, F; Klassen, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Assadi, H.; Kreye, H.; Gaertner, F.; Klassen, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cold spraying - A materials perspective", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cold spraying is a solid-state powder deposition process with several unique characteristics, allowing production of coatings or bulk components from a wide range of materials. The process has attracted much attention from academia and industry over the past two decades. The technical interest in cold spraying is twofold: first as a coating process for applications in surface technology, and second as a solid-state additive manufacturing process, offering an alternative to selective laser melting or electron beam melting methods. Moreover, cold spraying can be used to study materials behaviour under extremely high strain rates, high pressures and high cooling rates. The cold spraying process is thus considered to be relevant for various industrial applications, as well as for fundamental studies in materials science. This article aims to provide an overview of the cold spray process, the current understanding of the deposition mechanisms, and the related models and experiments, from a materials science perspective. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 671, "Times Cited, All Databases": 759, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2016, "Volume": 116, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 382, "End Page": 407, "Article Number": null, "DOI": "10.1016/j.actamat.2016.06.034", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.06.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382340400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chu, ZM; Zhao, Y; Ma, F; Zhang, CX; Deng, HX; Gao, F; Ye, QF; Meng, JH; Yin, ZG; Zhang, XW; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chu, Zema; Zhao, Yang; Ma, Fei; Zhang, Cai-Xin; Deng, Huixiong; Gao, Feng; Ye, Qiufeng; Meng, Junhua; Yin, Zhigang; Zhang, Xingwang; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large cation ethylammonium incorporated perovskite for efficient and spectra stable blue light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes (PeLEDs) have showed significant progress in recent years; the external quantum efficiency (EQE) of electroluminescence in green and red regions has exceeded 20%, but the efficiency in blue lags far behind. Here, a large cation CH3CH2NH2+ is added in PEA(2)(CsPbBr3)(2)PbBr4 perovskite to decrease the Pb-Br orbit coupling and increase the bandgap for blue emission. X-ray diffraction and nuclear magnetic resonullce results confirmed that the EA has successfully replaced Cs+ cations to form PEA(2)(Cs(1-x)EA(x)PbBr(3))(2)PbBr4. This method modulates the photoluminescence from the green region (508nm) into blue (466nm), and over 70% photoluminescence quantum yield in blue is obtained. In addition, the emission spectra is stable under light and thermal stress. With configuration of PeLEDs with 60% EABr, as high as 12.1% EQE of sky-blue electroluminescence located at 488nm has been demonstrated, which will pave the way for the full color display for the PeLEDs. Blue light-emitting diodes (LEDs) are critical for displays. Employing a large organic cation into a quasi-two dimensional perovskite with green emission, Chu et al. achieve LEDs exhibiting a high external quantum efficiency of 12.1% and stable spectra in the sky-blue region.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4165, "DOI": "10.1038/s41467-020-17943-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17943-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568893000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GQ; Zhong, XY; Wang, XW; Gong, F; Lei, HL; Zhou, YK; Li, CF; Xiao, ZD; Ren, GX; Zhang, L; Dong, ZQ; Liu, Z; Cheng, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guangqiang; Zhong, Xiaoyan; Wang, Xianwen; Gong, Fei; Lei, Huali; Zhou, Yangkai; Li, Chengfei; Xiao, Zhidong; Ren, Guoxi; Zhang, Liang; Dong, Zhiqiang; Liu, Zhuang; Cheng, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Titanium carbide nullosheets with defect structure for photothermal-enhanced sonodynamic therapy", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sonodynamic therapy (SDT) has attracted widespread interest in biomedicine, owing to its novel and nonin-vasive therapeutic method triggered by ultrasound (US). Herein, the Ti3C2 MXene nullosheets (Ti3C2 NSs) are developed as good sonosensitizers via a two-step method of chemical exfoliation and high-temperature treatment. With the high-temperature treatment, the oxygen defect of Ti3C2 MXene nullosheets (H-Ti3C2 NSs) is greatly increased. Therefore, the electron (e(-)) and hole (h(+)) generated by US can be separated faster due to the improved degree of oxidation, and then the recombination of e(-)-h(+) can be prevented with the abundant oxygen defect under US irradiation, which induced the sonodynamic efficiency greatly to improve around 3.7-fold compared with Ti3C2 NSs without high-temperature treatment. After PEGylation, the H-Ti3C2-PEG NSs show good stability and biocompatibility. In vitro studies exhibit that the inherent property of mild photothermal effect can promote the endocytosis of H-Ti3C2-PEG NSs, which can improve the SDT efficacy. In vivo studies further display that the increased blood supply by the mild photothermal effect can significantly relieve hypoxia in the tumor microenvimnment, showing photothermal therapy (PTT) enhanced SDT. Most importantly, the H-Ti3C2-PEG NSs can be biodegraded and excreted out of the body, showing no significant long-term toxicity. Our work develops the defective H-Ti3C2-NSs as high-efficiency and safe sonosensitizers for photothermal-enhanced SDT of cancer, extending the biomedical application of MXene-based nulloplatforms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 409, "End Page": 419, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.06.021", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.06.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751867500029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Low, T; Roldán, R; Wang, H; Xia, FN; Avouris, P; Moreno, LM; Guinea, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Low, Tony; Roldan, Rafael; Wang, Han; Xia, Fengnian; Avouris, Phaedon; Martin Moreno, Luis; Guinea, Francisco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmons and Screening in Monolayer and Multilayer Black Phosphorus", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus exhibits a high degree of band anisotropy. However, we find that its in-plane static screening remains relatively isotropic for momenta relevant to elastic long-range scattering processes. On the other hand, the collective electronic excitations in the system exhibit a strong anisotropy. Band nonparabolicity, due to interband couplings, leads to a plasmon frequency which scales as n(beta), where n is the carrier concentration, and beta < 1/2. Screening and charge distribution in the out-of-plane direction are also studied using a nonlinear Thomas-Fermi model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 520, "Times Cited, All Databases": 552, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2014, "Volume": 113, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106802, "DOI": "10.1103/PhysRevLett.113.106802", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.106802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341267800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mukherjee, T; Zhang, W; DebRoy, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mukherjee, T.; Zhang, W.; DebRoy, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An improved prediction of residual stresses and distortion in additive manufacturing", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In laser assisted additive manufacturing (AM) an accurate estimation of residual stresses and distortion is necessary to achieve dimensional accuracy and prevent premature fatigue failure, delamination and buckling of components. Since many process variables affect AM, experimental measurements of residual stresses and distortion are time consuming and expensive. Numerical thermo-mechanical models can be used for their estimation, but the quality of calculations depends critically on the accurate transient temperature field which affects both the residual stresses and distortion. In this study, a well-tested, three-dimensional, transient heat transfer and fluid flow model is used to accurately calculate transient temperature field for the residual stress and distortion modeling. The calculated residual stress distributions are compared with independent experimental results. It is shown that the residual stresses can be significantly minimized by reducing the layer thickness during AM. Inconel 718 components are found to be more susceptible to delamination than Ti-6Al-4V parts because they encounter higher residual stresses compared to their yield strength. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 553, "Times Cited, All Databases": 618, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 126, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 360, "End Page": 372, "Article Number": null, "DOI": "10.1016/j.commatsci.2016.10.003", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2016.10.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389089900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XB; Cui, PX; Qian, YM; Zhao, GQ; Zheng, XS; Xu, X; Cheng, ZX; Liu, YY; Dou, SX; Sun, WP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaobo; Cui, Peixin; Qian, Yumin; Zhao, Guoqiang; Zheng, Xusheng; Xu, Xun; Cheng, Zhenxiang; Liu, Yuanyue; Dou, Shi Xue; Sun, Wenping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Active-Center-Transferable Platinum/Lithium Cobalt Oxide Heterostructured Electrocatalysts towards Superior Water Splitting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing cost-effective and efficient electrocatalysts plays a pivotal role in advancing the development of electrochemical water splitting for hydrogen generation. Herein, multifunctional active-center-transferable heterostructured electrocatalysts, platinum/lithium cobalt oxide (Pt/LiCoO2) composites with Pt nulloparticles (Pt NPs) anchored on LiCoO(2)nullosheets, are designed towards highly efficient water splitting. In this electrocatalyst system, the active center can be alternatively switched between Pt species and LiCoO(2)for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), respectively. Specifically, Pt species are the active centers and LiCoO(2)acts as the co-catalyst for HER, whereas the active center transfers to LiCoO(2)and Pt turns into the co-catalyst for OER. The unique architecture of Pt/LiCoO(2)heterostructure provides abundant interfaces with favorable electronic structure and coordination environment towards optimal adsorption behavior of reaction intermediates. The 30 % Pt/LiCoO(2)heterostructured electrocatalyst delivers low overpotentials of 61 and 285 mV to achieve 10 mA cm(-2)for HER and OER in alkaline medium, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2020, "Volume": 59, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14533, "End Page": 14540, "Article Number": null, "DOI": "10.1002/anie.202005241", "DOI Link": "http://dx.doi.org/10.1002/anie.202005241", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544736400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, BW; Sheng, T; Liu, YD; Wang, YX; Zhang, L; Lai, WH; Wang, L; Yang, JP; Gu, QF; Chou, SL; Liu, HK; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bin-Wei; Sheng, Tian; Liu, Yun-Dan; Wang, Yun-Xiao; Zhang, Lei; Lai, Wei-Hong; Wang, Li; Yang, Jianping; Gu, Qin-Fen; Chou, Shu-Lei; Liu, Hua-Kun; Dou, Shi-Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic cobalt as an efficient electrocatalyst in sulfur cathodes for superior room-temperature sodium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low-cost room-temperature sodium-sulfur battery system is arousing extensive interest owing to its promise for large-scale applications. Although significant efforts have been made, resolving low sulfur reaction activity and severe polysulfide dissolution remains challenging. Here, a sulfur host comprised of atomic cobalt-decorated hollow carbon nullospheres is synthesized to enhance sulfur reactivity and to electrocatalytically reduce polysulfide into the final product, sodium sulfide. The constructed sulfur cathode delivers an initial reversible capacity of 1081 mA h g(-1) with 64.7% sulfur utilization rate; significantly, the cell retained a high reversible capacity of 508 mA h g(-1) at 100 mA g(-1) after 600 cycles. An excellent rate capability is achieved with an average capacity of 220.3 mA h g(-1) at the high current density of 5 A g(-1). Moreover, the electrocatalytic effects of atomic cobalt are clearly evidenced by operando Raman spectroscopy, synchrotron X-ray diffraction, and density functional theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 4", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4082, "DOI": "10.1038/s41467-018-06144-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06144-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446314600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, X; Yuan, Y; Chen, JQ; Zhang, BH; Li, D; Zhou, D; Jing, PT; Xu, GY; Wang, YL; Holá, K; Shen, DZ; Wu, CF; Song, L; Liu, CB; Zboril, R; Qu, SN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Xin; Yuan, Ye; Chen, Jingqin; Zhang, Bohan; Li, Di; Zhou, Ding; Jing, Pengtao; Xu, Guiying; Wang, Yingli; Hola, Katerina; Shen, Dezhen; Wu, Changfeng; Song, Liang; Liu, Chengbo; Zboril, Radek; Qu, Songnull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In vivo theranostics with near-infrared-emitting carbon dots-highly efficient photothermal therapy based on passive targeting after intravenous administration", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots that exhibit near-infrared fluorescence (NIR CDs) are considered emerging nullomaterials for advanced biomedical applications with low toxicity and superior photostability and targeting compared to currently used photoluminescence agents. Despite progress in the synthesis of NIR CDs, there remains a key obstacle to using them as an in vivo theranostic agent. This work demonstrates that the newly developed sulfur and nitrogen codoped NIR CDs are highly efficient in photothermal therapy (PTT) in mouse models (conversion efficiency of 59%) and can be readily visualized by photoluminescence and photoacoustic imaging. The real theranostic potential of NIR CDs is enhanced by their unique biodistribution and targeting. Contrary to all other nullomaterials that have been tested in biomedicine, they are excreted through the body's renal filtration system. Moreover, after intravenous injection, NIR CDs are accumulated in tumor tissue via passive targeting, without any active species such as antibodies. Due to their accumulation in tumor tissue without the need for intratumor injection, high photothermal conversion, excel lent optical and photoacoustic imaging performance, and renal excretion, the developed CDs are suitable for transfer to clinical biomedical practice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2018, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 91, "DOI": "10.1038/s41377-018-0090-1", "DOI Link": "http://dx.doi.org/10.1038/s41377-018-0090-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450708600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, ZY; Wang, FX; Fang, XM; Gao, XN; Zhang, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Ziye; Wang, Fangxian; Fang, Xiaoming; Gao, Xuenong; Zhang, Zhengguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A hybrid thermal management system for lithium ion batteries combining phase change materials with forced-air cooling", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive thermal management systems using phase change materials (PCMs) provides an effective solution to the overheating of lithium ion batteries. But this study shows heat accumulation in PCMs caused by the inefficient cooling of air natural convection leads to thermal management system failures: The temperature in a battery pack operating continuously outranges the safety limit of 60 degrees C after two cycles with discharge rate of 1.5 C and 2 C. Here a hybrid system that integrates PCMs with forced air convection is presented. This combined system successfully prevents heat accumulation and maintains the maximum temperature under 50 degrees C in all cycles. Study on airspeed effects reveals that thermo-physical properties of PCMs dictate the maximum temperature rise and temperature uniformity in the battery pack, while forced air convection plays a critical role in recovering thermal energy storage capacity of PCMs. A numerical study is also carried out and validated with experiment data, which gives theoretic insights on thermo-physical changes in this hybrid battery thermal management system. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 579, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2015, "Volume": 148, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 403, "End Page": 409, "Article Number": null, "DOI": "10.1016/j.apenergy.2015.03.080", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2015.03.080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355063900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Verma, A; Thakur, S; Mamba, G; Prateek; Gupta, RK; Thakur, P; Thakur, VK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Verma, Ankit; Thakur, Sourbh; Mamba, Gcina; Prateek; Gupta, Raju Kumar; Thakur, Pankaj; Thakur, Vijay Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphite modified sodium alginate hydrogel composite for efficient removal of malachite green dye", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, porous sodium alginate/graphite based hybrid hydrogel was fabricated as an effective adsorbent for organic pollutant. Sodium alginate was modified through graft polymerization of acrylic acid and subsequently loaded with graphite powder to enhance its adsorption capability. The synthesized sodium alginate cross-linked acrylic acid/graphite (NaA-cl-AAc/GP) hydrogel composite was utilized in the removal of malachite green (MG) dye from aqueous solution using batch adsorption experiments. The NaA-cl-AAc/GP hydrogel composite was characterized by infrared spectroscopy, Raman spectroscopy, thermo-gravimetric analysis, scanning electron microscopy, x-ray photoelectron spectroscopy and x-ray diffraction. Under optimized experimental conditions, a maximum adsorption capacity of 628.93 mg g(-1) was attained for malachite green dye. Moreover, the adsorption process could be well described by the Langmuir isotherm model and pseudo-second-order kinetic model. The hydrogel composite also showed 91% adsorption after three consecutive cydes of dye adsorption-desorption. Therefore, the NaA-cl-AAc/GP hydrogel composite is a potentially favourable material towards dye pollution remediation owing to its better swelling rate, environment friendliness, high adsorption potential and regeneration capability. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 148, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1130, "End Page": 1139, "Article Number": null, "DOI": "10.1016/j.ijbiomac.2020.01.142", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2020.01.142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522094600112", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, ZW; Zhang, JZ; Maluk, C; Yu, YM; Seraji, SM; Yu, B; Wang, H; Song, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Zhewen; Zhang, Jianzhong; Maluk, Cristian; Yu, Youming; Seraji, Seyed Mohsen; Yu, Bin; Wang, Hao; Song, Pingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A lava-inspired micro/nullo-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fire-retardant coatings have demonstrated effective fire protection for various materials, ranging from flammable polymeric foam and wood to nonflammable steel. However, the poor cost effectiveness has significantly impeded their real-world applications. In nature, lava is a flowing, noncombustible molten liquid with a low thermal conductivity. We, herein, report a lava-inspired micro/nullo-structured ceramifiable organic-inorganic hybrid coating comprising low-melting glass powders (GPs), such as ceramic precursors; boron nitride (BN) nullosheets as synergists; and a fire-retardant polymer as a coating base. Upon exposure to flame, the coating forms a lava-like noncombustible ceramic char layer that can serve as a robust fire shield for underlying substrates. The hybrid coating treated polyurethane foam exhibits a rapid self-extinguishing behavior and increased compressive strength, outperforming its previous counterparts. Meanwhile, the hybrid coating offers exceptional fire protection for solid wood and steel. This work provides a bioinspired strategy for creating cost-effective fire-retardant coatings for diverse industrial applications and a fire-safe world.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 911, "End Page": 932, "Article Number": null, "DOI": "10.1016/j.matt.2021.12.009", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2021.12.009", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766639300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Santos, VP; Wezendonk, TA; Jaén, JJD; Dugulan, AI; Nasalevich, MA; Islam, HU; Chojecki, A; Sartipi, S; Sun, X; Hakeem, AA; Koeken, ACJ; Ruitenbeek, M; Davidian, T; Meima, GR; Sankar, G; Kapteijn, F; Makkee, M; Gascon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Santos, Vera P.; Wezendonk, Tim A.; Delgado Jaen, Juan Jose; Dugulan, A. Iulian; Nasalevich, Maxim A.; Islam, Husn-Ubayda; Chojecki, Adam; Sartipi, Sina; Sun, Xiaohui; Hakeem, Abrar A.; Koeken, Ard C. J.; Ruitenbeek, Matthijs; Davidian, Thomas; Meima, Garry R.; Sankar, Gopinathan; Kapteijn, Freek; Makkee, Michiel; Gascon, Jorge", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Depletion of crude oil resources and environmental concerns have driven a worldwide research on alternative processes for the production of commodity chemicals. Fischer-Tropsch synthesis is a process for flexible production of key chemicals from synthesis gas originating from non-petroleum-based sources. Although the use of iron-based catalysts would be preferred over the widely used cobalt, manufacturing methods that prevent their fast deactivation because of sintering, carbon deposition and phase changes have proven challenging. Here we present a strategy to produce highly dispersed iron carbides embedded in a matrix of porous carbon. Very high iron loadings (>40 wt %) are achieved while maintaining an optimal dispersion of the active iron carbide phase when a metal organic framework is used as catalyst precursor. The unique iron spatial confinement and the absence of large iron particles in the obtained solids minimize catalyst deactivation, resulting in high active and stable operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6451, "DOI": "10.1038/ncomms7451", "DOI Link": "http://dx.doi.org/10.1038/ncomms7451", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352634600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Osterrieth, JWM; Rampersad, J; Madden, D; Rampal, N; Skoric, L; Connolly, B; Allendorf, MD; Stavila, V; Snider, JL; Ameloot, R; Marreiros, J; Ania, C; Azevedo, D; Vilarrasa-Garcia, E; Santos, BF; Bu, XH; Chang, Z; Bunzen, H; Champness, NR; Griffin, SL; Chen, BL; Lin, RB; Coasne, B; Cohen, S; Moreton, JC; Colón, YJ; Chen, LJ; Clowes, R; Coudert, FX; Cui, Y; Hou, B; D'Alessandro, DM; Doheny, PW; Dinca, M; Sun, CY; Doonull, C; Huxley, MT; Evans, JD; Falcaro, P; Ricco, R; Farha, O; Idrees, KB; Islamoglu, T; Feng, PY; Yang, HJ; Forgan, RS; Bara, D; Furukawa, S; Sanchez, E; Gascon, J; Telalovic, S; Ghosh, SK; Mukherjee, S; Hill, MR; Sadiq, MM; Horcajada, P; Salcedo-Abraira, P; Kaneko, K; Kukobat, R; Kenvin, J; Keskin, S; Kitagawa, S; Otake, KI; Lively, RP; DeWitt, SJA; Llewellyn, P; Lotsch, BV; Emmerling, ST; Putz, AM; Marti-Gastaldo, C; Padial, NM; García-Martínez, J; Linares, N; Maspoch, D; del Pino, JAS; Moghadam, P; Oktavian, R; Morris, RE; Wheatley, PS; Navarro, J; Petit, C; Danaci, D; Rosseinsky, MJ; Katsoulidis, AP; Schröder, M; Han, X; Yang, SH; Serre, C; Mouchaham, G; Sholl, DS; Thyagarajan, R; Siderius, D; Snurr, RQ; Goncalves, RB; Telfer, S; Lee, SJ; Ting, VP; Rowlandson, JL; Uemura, T; Liyuka, T; van derVeen, MA; Rega, D; Van Speybroeck, V; Rogge, SMJ; Lamaire, A; Walton, KS; Bingel, LW; Wuttke, S; Andreo, J; Yaghi, O; Zhang, B; Yavuz, CT; Nguyen, TS; Zamora, F; Montoro, C; Zhou, HC; Kirchon, A; Fairen-Jimenez, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Osterrieth, Johannes W. M.; Rampersad, Jarnes; Madden, David; Rampal, Nakul; Skoric, Luka; Connolly, Bethany; Allendorf, Mark D.; Stavila, Vitalie; Snider, Jonathan L.; Ameloot, Rob; Marreiros, Joao; Ania, Conchi; Azevedo, Diana; Vilarrasa-Garcia, Enrique; Santos, Bianca F.; Bu, Xian-He; Chang, Ze; Bunzen, Hana; Champness, Neil R.; Griffin, Sarah L.; Chen, Banglin; Lin, Rui-Biao; Coasne, Benoit; Cohen, Seth; Moreton, Jessica C.; Colon, Yamil J.; Chen, Linjiang; Clowes, Rob; Coudert, Francois-Xavier; Cui, Yong; Hou, Bang; D'Alessandro, Deanna M.; Doheny, Patrick W.; Dinca, Mircea; Sun, Chenyue; Doonull, Christian; Huxley, Michael Thomas; Evans, Jack D.; Falcaro, Paolo; Ricco, Raffaele; Farha, Omar; Idrees, Karam B.; Islamoglu, Timur; Feng, Pingyun; Yang, Huajun; Forgan, Ross S.; Bara, Dominic; Furukawa, Shuhei; Sanchez, Eli; Gascon, Jorge; Telalovic, Selvedin; Ghosh, Sujit K.; Mukherjee, Soumya; Hill, Matthew R.; Sadiq, Muhammed Munir; Horcajada, Patricia; Salcedo-Abraira, Pablo; Kaneko, Katsumi; Kukobat, Radovan; Kenvin, Jeff; Keskin, Seda; Kitagawa, Susumu; Otake, Ken-ichi; Lively, Ryan P.; DeWitt, Stephen J. A.; Llewellyn, Phillip; Lotsch, Bettina, V; Emmerling, Sebastian T.; Putz, Alexander M.; Marti-Gastaldo, Carlos; Padial, Natalia M.; Garcia-Martinez, Javier; Linares, Noemi; Maspoch, Daniel; del Pino, Jose A. Suarez; Moghadam, Peyman; Oktavian, Rama; Morris, Russel E.; Wheatley, Paul S.; Navarro, Jorge; Petit, Camille; Danaci, David; Rosseinsky, Matthew J.; Katsoulidis, Alexandros P.; Schroder, Martin; Han, Xue; Yang, Sihai; Serre, Christian; Mouchaham, Georges; Sholl, David S.; Thyagarajan, Raghuram; Siderius, Daniel; Snurr, Randall Q.; Goncalves, Rebecca B.; Telfer, Shane; Lee, Seok J.; Ting, Valeska P.; Rowlandson, Jemma L.; Uemura, Takashi; Liyuka, Tomoya; van derVeen, Monique A.; Rega, Davide; Van Speybroeck, Veronique; Rogge, Sven M. J.; Lamaire, Aran; Walton, Krista S.; Bingel, Lukas W.; Wuttke, Stefan; Andreo, Jacopo; Yaghi, Omar; Zhang, Bing; Yavuz, Cafer T.; Nguyen, Thien S.; Zamora, Felix; Montoro, Carmen; Zhou, Hongcai; Kirchon, Angelo; Fairen-Jimenez, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How Reproducible are Surface Areas Calculated from the BET Equation?", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porosity and surface area analysis play a prominent role in modern materials science. At the heart of this sits the Brunauer-Emmett-Teller (BET) theory, which has been a remarkably successful contribution to the field of materials science. The BET method was developed in the 1930s for open surfaces but is now the most widely used metric for the estimation of surface areas of micro- and mesoporous materials. Despite its widespread use, the calculation of BET surface areas causes a spread in reported areas, resulting in reproducibility problems in both academia and industry. To prove this, for this analysis, 18 already-measured raw adsorption isotherms were provided to sixty-one labs, who were asked to calculate the corresponding BET areas. This round-robin exercise resulted in a wide range of values. Here, the reproducibility of BET area determination from identical isotherms is demonstrated to be a largely ignored issue, raising critical concerns over the reliability of reported BET areas. To solve this major issue, a new computational approach to accurately and systematically determine the BET area of nulloporous materials is developed. The software, called BET surface identification (BETSI), expands on the well-known Rouquerol criteria and makes an unambiguous BET area assignment possible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 34, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201502, "DOI": "10.1002/adma.202201502", "DOI Link": "http://dx.doi.org/10.1002/adma.202201502", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798646500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsoi, KM; MacParland, SA; Ma, XZ; Spetzler, VN; Echeverri, J; Ouyang, B; Fadel, SM; Sykes, EA; Goldaracena, N; Kaths, JM; Conneely, JB; Alman, BA; Selzner, M; Ostrowski, MA; Adeyi, OA; Zilman, A; McGilvray, ID; Chan, WCW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsoi, Kim M.; MacParland, Sonya A.; Ma, Xue-Zhong; Spetzler, Vinzent N.; Echeverri, Juan; Ouyang, Ben; Fadel, Saleh M.; Sykes, Edward A.; Goldaracena, Nicolas; Kaths, Johann M.; Conneely, John B.; Alman, Benjamin A.; Selzner, Markus; Ostrowski, Mario A.; Adeyi, Oyedele A.; Zilman, Anton; McGilvray, Ian D.; Chan, Warren C. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of hard-nullomaterial clearance by the liver", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The liver and spleen are major biological barriers to translating nullomedicines because they sequester the majority of administered nullomaterials and prevent delivery to diseased tissue. Here we examined the blood clearance mechanism of administered hard nullomaterials in relation to blood flow dynamics, organ microarchitecture and cellular phenotype. We found that nullomaterial velocity reduces 1,000-fold as they enter and traverse the liver, leading to 7.5 times more nullomaterial interaction with hepatic cells relative to peripheral cells. In the liver, Kupffer cells (84.8 +/- 6.4%), hepatic B cells (81.5 +/- 9.3%) and liver sinusoidal endothelial cells (64.6 +/- 13.7%) interacted with administered PEGylated quantum dots, but splenic macrophages took up less material (25.4 +/- 10.1%) due to differences in phenotype. The uptake patterns were similar for two other nullomaterial types and five different surface chemistries. Potential new strategies to overcome off-target nullomaterial accumulation may involve manipulating intra-organ flow dynamics and modulating the cellular phenotype to alter hepatic cell interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 711, "Times Cited, All Databases": 791, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1212, "End Page": 1221, "Article Number": null, "DOI": "10.1038/NMAT4718", "DOI Link": "http://dx.doi.org/10.1038/NMAT4718", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386377000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mostafaei, A; Zhao, C; He, YN; Ghiaasiaan, SR; Shi, B; Shao, S; Shamsaei, N; Wu, ZH; Kouraytem, N; Sun, T; Pauza, J; Gordon, J; Webler, B; Parab, ND; Asherloo, MD; Guo, QL; Chen, LY; Rollett, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mostafaei, Amir; Zhao, Cang; He, Yining; Ghiaasiaan, Seyed Reza; Shi, Bo; Shao, Shuai; Shamsaei, Nima; Wu, Ziheng; Kouraytem, Nadia; Sun, Tao; Pauza, Joseph; Gordon, Jerard, V; Webler, Bryan; Parab, Niranjan D.; Asherloo, Mohammadreza D.; Guo, Qilin; Chen, Lianyi; Rollett, Anthony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defects and anomalies in powder bed fusion metal additive manufacturing", "Source Title": "CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ABS T R A C T Metal additive manufacturing is a disruptive technology that is revolutionizing the manufacturing industry. Despite its unrivaled capability for directly fabricating metal parts with complex geometries, the wide realization of the technology is currently limited by microstructural defects and anomalies, which could significantly degrade the structural integrity and service performance of the product. Accurate detection, characterization, and prediction of these defects and anomalies have an important and immediate impact in manufacturing fully-dense and defect-free builds. This review seeks to elucidate common defects/anomalies and their formation mechanisms in powder bed fusion additive manufacturing processes. They could arise from raw materials, processing conditions, and post-processing. While defects/anomalies in laser welding have been studied exten-sively, their formation and evolution remain unclear. Additionally, the existence of powder in powder bed fusion techniques may generate new types of defects, e.g., porosity transferring from powder to builds. Practical strategies to mitigate defects are also addressed through fundamental understanding of their formation. Such explorations enable the validation and calibration of models and ease the process qualification without costly trial-and-error experimentation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 26, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100974, "DOI": "10.1016/j.cossms.2021.100974", "DOI Link": "http://dx.doi.org/10.1016/j.cossms.2021.100974", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779607700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SC; Tan, CH; Yan, RP; Zou, XF; Hu, FL; Mi, Y; Yan, C; Zhao, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shucong; Tan, Chunhui; Yan, Ruipeng; Zou, Xifei; Hu, Fei-Long; Mi, Yan; Yan, Cheng; Zhao, Shenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Built-in Electric Field in Heterogeneous nullowire Arrays for Efficient Overall Water Electrolysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient bifunctional electrocatalysts for hydrogen and oxygen evolution reactions are key to water electrolysis. Herein, we report a built-in electric field (BEF) strategy to fabricate heterogeneous nickel phosphide-cobalt nullowire arrays grown on carbon fiber paper (Ni2P-CoCH/CFP) with large work function difference (Delta phi) as bifunctional electrocatalysts for overall water splitting. Impressively, Ni2P-CoCH/CFP exhibits a remarkable catalytic activity for hydrogen and oxygen evolution reactions to obtain 10 mA cm(-2), respectively. Moreover, the assembled lab-scale electrolyzer driven by an AAA battery delivers excellent stability after 50 h electrocatalysis with a 100 % faradic efficiency. Computational calculations combining with experiments reveal the interface-induced electric field effect facilitates asymmetrical charge distributions, thereby regulating the adsorption/desorption of the intermediates during reactions. This work offers an avenue to rationally design high-performance heterogeneous electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2023, "Volume": 62, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202302795", "DOI Link": "http://dx.doi.org/10.1002/anie.202302795", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000989587300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Behler, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Behler, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective: Machine learning potentials for atomistic simulations", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nowadays, computer simulations have become a standard tool in essentially all fields of chemistry, condensed matter physics, and materials science. In order to keep up with state-of-the-art experiments and the ever growing complexity of the investigated problems, there is a constantly increasing need for simulations of more realistic, i.e., larger, model systems with improved accuracy. In many cases, the availability of sufficiently efficient interatomic potentials providing reliable energies and forces has become a serious bottleneck for performing these simulations. To address this problem, currently a paradigm change is taking place in the development of interatomic potentials. Since the early days of computer simulations simplified potentials have been derived using physical approximations whenever the direct application of electronic structure methods has been too demanding. Recent advances in machine learning (ML) now offer an alternative approach for the representation of potential-energy surfaces by fitting large data sets from electronic structure calculations. In this perspective, the central ideas underlying these ML potentials, solved problems and remaining challenges are reviewed along with a discussion of their current applicability and limitations. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1032, "Times Cited, All Databases": 1147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2016, "Volume": 145, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 170901, "DOI": "10.1063/1.4966192", "DOI Link": "http://dx.doi.org/10.1063/1.4966192", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388105100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, Y; Chen, XF; Yang, P; Liang, GJ; Yang, Y; Gu, ZP; Li, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Yuan; Chen, Xiaofeng; Yang, Peng; Liang, Guijie; Yang, Ye; Gu, Zhipeng; Li, Yiwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating the absorption spectrum of polydopamine", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydopamine (PDA) has been increasingly exploited as an advanced functional material, and its emergent light absorption property plays a crucial role in determining various utilizations. However, the rational design and efficient regulation of PDA absorption property remain a challenge due to the complex structure within PDA. In this work, we propose a facile method to regulate the light absorption behaviors of PDA by constructing donor-acceptor pairs within the microstructures through the chemical connections between indoledihydroxy/indolequinone and their oligomers with 2,2,6,6-tetramethylpiperidine-1-oxyl moiety. The detailed structural and spectral analysis, as well as the density functional theory simulation, further confirms the existence of donor-acceptor molecular pair structures, which could decrease the energy bandgap and increase the electron delocalization for enhancing light absorption across a broad spectrum. These rationally designed PDA nulloparticles with tunable absorption properties also show improved total photothermal effect and demonstrate excellent performances in solar desalination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb4696", "DOI": "10.1126/sciadv.abb4696", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb4696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567766700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Milot, RL; Sutton, RJ; Eperon, GE; Haghighirad, AA; Hardigree, JM; Miranda, L; Snaith, HJ; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Milot, Rebecca L.; Sutton, Rebecca J.; Eperon, Giles E.; Haghighirad, Amir Abbas; Hardigree, Josue Martinez; Miranda, Laura; Snaith, Henry J.; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Carrier Dynamics in 2D Hybrid Metal-Halide Perovskites", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid metal-halide perovskites are promising new materials for use in solar cells; however, their chemical stability in the presence of moisture remains a significant drawback. Quasi two-dimensional (2D) perovskites that incorporate hydrophobic organic interlayers offer improved resistance to degradation by moisture, currently still at the cost of overall cell efficiency. To elucidate the factors affecting the optoelectronic properties of these materials, we have investigated the charge transport properties and crystallographic orientation of mixed methylammonium (MA)-phenylethylammonium (PEA) lead iodide thin films as a function of the MA-to-PEA ratio and, thus, the thickness of the encapsulated MA lead halide layers. We find that monomolecular charge-carrier recombination rates first decrease with increasing PEA fraction, most likely as a result of trap passivation, but then increase significantly as excitonic effects begin to dominate for thin confined layers. Bimolecular and Auger recombination rate constants are found to be sensitive to changes in electronic confinement, which alters the density of states for electronic transitions. We demonstrate that effective charge-carrier mobilities remain remarkably high (near 10 cm(2)V-(1)s(-1)) for intermediate PEA content and are enhanced for preferential orientation of the conducting lead iodide layers along the probing electric field. The trade-off between trap reduction, electronic confinement, and layer orientation leads to calculated charge-carrier diffusion lengths reaching a maximum of 2.5 mu m for intermediate PEA content (50%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 445, "Times Cited, All Databases": 490, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 16, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7001, "End Page": 7007, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b03114", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b03114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387625000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YF; Lu, QC; He, J; Huo, ZH; Zhou, RH; Han, X; Jia, MM; Pan, CF; Wang, ZL; Zhai, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yufei; Lu, Qiuchun; He, Jiang; Huo, Zhihao; Zhou, Runhui; Han, Xun; Jia, Mengmeng; Pan, Caofeng; Wang, Zhong Lin; Zhai, Junyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Localizing strain via micro-cage structure for stretchable pressure sensor arrays with ultralow spatial crosstalk", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tactile sensors with high spatial resolution are crucial to manufacture large scale flexible electronics, and low crosstalk sensor array combined with advanced data analysis is beneficial to improve detection accuracy. Here, we demonstrated the photo-reticulated strain localization films (prslPDMS) to prepare the ultralow crosstalk sensor array, which form a micro-cage structure to reduce the pixel deformation overflow by 90.3% compared to that of conventional flexible electronics. It is worth noting that prslPDMS acts as an adhesion layer and provide spacer for pressure sensing. Hence, the sensor achieves the sufficient pressure resolution to detect 1 g weight even in bending condition, and it could monitor human pulse under different states or analyze the grasping postures. Experiments show that the sensor array acquires clear pressure imaging and ultralow crosstalk (33.41 dB) without complicated data processing, indicating that it has a broad application prospect in precise tactile detection. Designing tactile sensors with high spatial resolution are crucial to manufacture large scale flexible electronics. Here, the authors develop a micro-cage structure by exploiting photo-reticulated strain localization films (prslPDMS), which shows the strain local confinement effect and could be used to prepare ultralow crosstalk sensor arrays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1252, "DOI": "10.1038/s41467-023-36885-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36885-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001865400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sundararaman, R; Narang, P; Jermyn, AS; Goddard, WA ; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sundararaman, Ravishankar; Narang, Prineha; Jermyn, Adam S.; Goddard, William A., III; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theoretical predictions for hot-carrier generation from surface plasmon decay", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Decay of surface plasmons to hot carriers finds a wide variety of applications in energy conversion, photocatalysis and photodetection. However, a detailed theoretical description of plasmonic hot-carrier generation in real materials has remained incomplete. Here we report predictions for the prompt distributions of excited 'hot' electrons and holes generated by plasmon decay, before inelastic relaxation, using a quantized plasmon model with detailed electronic structure. We find that carrier energy distributions are sensitive to the electronic band structure of the metal: gold and copper produce holes hotter than electrons by 1-2 eV, while silver and aluminium distribute energies more equitably between electrons and holes. Momentum-direction distributions for hot carriers are anisotropic, dominated by the plasmon polarization for aluminium and by the crystal orientation for noble metals. We show that in thin metallic films intraband transitions can alter the carrier distributions, producing hotter electrons in gold, but interband transitions remain dominullt.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 636, "Times Cited, All Databases": 723, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5788, "DOI": "10.1038/ncomms6788", "DOI Link": "http://dx.doi.org/10.1038/ncomms6788", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347613200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mallick, A; Garai, B; Addicoat, MA; Petkov, PS; Heine, T; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mallick, Arijit; Garai, Bikash; Addicoat, Matthew A.; Petkov, Petko St.; Heine, Thomas; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid state organic amine detection in a photochromic porous metal organic framework", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new Mg(II) based photochromic porous metal-organic framework (MOF) has been synthesized bearing naphthalenediimide (NDI) chromophoric unit. This MOF (Mg-NDI) shows instant and reversible solvatochromic behavior in presence of solvents with different polarity. Mg-NDI also exhibits fast and reversible photochromism via radical formation. Due to the presence of electron deficient NDI moiety, this MOF exhibits selective organic amine (electron rich) sensing in solid state. The organic amine detection has been confirmed by photoluminescence quenching experiment and visual color change.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1420, "End Page": 1425, "Article Number": null, "DOI": "10.1039/c4sc03224a", "DOI Link": "http://dx.doi.org/10.1039/c4sc03224a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348147100072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XY; Zhang, HC; Wang, PY; Hou, J; Lu, J; Easton, CD; Zhang, XW; Hill, MR; Thornton, AW; Liu, JZ; Freeman, BD; Hill, AJ; Jiang, L; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xingya; Zhang, Huacheng; Wang, Peiyao; Hou, Jue; Lu, Jun; Easton, Christopher D.; Zhang, Xiwang; Hill, Matthew R.; Thornton, Aaron W.; Liu, Jefferson Zhe; Freeman, Benny D.; Hill, Anita J.; Jiang, Lei; Wang, Huanting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and selective fluoride ion conduction in sub-1-nullometer metal-organic framework channels", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biological fluoride ion channels are sub-1-nullometer protein pores with ultrahigh F- conductivity and selectivity over other halogen ions. Developing synthetic F- channels with biological-level selectivity is highly desirable for ion separations such as water defluoridation, but it remains a great challenge. Here we report synthetic F- channels fabricated from zirconium-based metal-organic frameworks (MOFs), UiO-66-X (X = H, NH2, and N+(CH3)(3)). These MOFs are comprised of nullometer-sized cavities connected by sub-1-nullometer-sized windows and have specific F- binding sites along the channels, sharing some features of biological F- channels. UiO-66-X channels consistently show ultrahigh F- conductivity up to similar to 10 S m(-1), and ultrahigh F-/Cl- selectivity, from similar to 13 to similar to 240. Molecular dynamics simulations reveal that the ultrahigh F- conductivity and selectivity can be ascribed mainly to the high F- concentration in the UiO-66 channels, arising from specific interactions between F- ions and F- binding sites in the MOF channels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2490, "DOI": "10.1038/s41467-019-10420-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10420-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470968300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, TT; Chen, ZB; Cui, XY; Lu, SL; Chen, HS; Wang, H; Dong, T; Qin, BL; Chan, KC; Brandt, M; Liao, XZ; Ringer, SP; Qian, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Tingting; Chen, Zibin; Cui, Xiangyuan; Lu, Shenglu; Chen, Hansheng; Wang, Hao; Dong, Tony; Qin, Bailiang; Chan, Kang Cheung; Brandt, Milan; Liao, Xiaozhou; Ringer, Simon P. P.; Qian, Ma", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong and ductile titanium-oxygen-iron alloys by additive manufacturing", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Titanium alloys are advanced lightweight materials, indispensable for many critical applications(1,2). The mainstay of the titanium industry is the alpha-beta titanium alloys, which are formulated through alloying additions that stabilize the alpha and beta phases(3-5). Our work focuses on harnessing two of the most powerful stabilizing elements and strengtheners for alpha-beta titanium alloys, oxygen and iron(1-5), which are readily abundant. However, the embrittling effect of oxygen(6,7), described colloquially as 'the kryptonite to titanium'(8), and the microsegregation of iron(9) have hindered their combination for the development of strong and ductile alpha-beta titanium-oxygen-iron alloys. Here we integrate alloy design with additive manufacturing (AM) process design to demonstrate a series of titanium-oxygen-iron compositions that exhibit outstanding tensile properties. We explain the atomic-scale origins of these properties using various characterization techniques. The abundance of oxygen and iron and the process simplicity for net-shape or near-net-shape manufacturing by AM make these alpha-beta titanium-oxygen-iron alloys attractive for a diverse range of applications. Furthermore, they offer promise for industrial-scale use of off-grade sponge titanium or sponge titanium-oxygen-iron(10,11), an industrial waste product at present. The economic and environmental potential to reduce the carbon footprint of the energy-intensive sponge titanium production(12) is substantial.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2023, "Volume": 618, "Issue": 7963, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05952-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05952-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001874500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HJ; Wang, YX; Krishna, R; Jia, XX; Wang, Y; Hong, AN; Dang, C; Castillo, HE; Bu, XH; Feng, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Huajun; Wang, Yanxiang; Krishna, Rajamani; Jia, Xiaoxia; Wang, Yong; Hong, Anh N.; Dang, Candy; Castillo, Henry E.; Bu, Xianhui; Feng, Pingyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore-Space-Partition-Enabled Exceptional Ethane Uptake and Ethane-Selective Ethane-Ethylene Separation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An ideal material for C2H6/C2H4 separation would simultaneously have the highest C2H6 uptake capacity and the highest C2H6/C2H4 selectivity. But such material is elusive. A benchmark material for ethane-selective C2H6/C2H4 separation is peroxo-functionalized MOF-74-Fe that exhibits the best known separation performance due to its high C2H6/C2H4 selectivity (4.4), although its C2H6 uptake capacity is moderate (74.3 cm(3)/g). Here, we report a family of pore-space-partitioned crystalline porous materials (CPMs) with exceptional C2H6 uptake capacity and C2H6/C2H4 separation potential (i.e., C2H4 recovered from the mixture) despite their moderate C2H6/C2H4 selectivity (up to 1.75). The ethane uptake capacity as high as 166.8 cm(3)/g at 1 atm and 298 K, more than twice that of peroxo-MOF-74-Fe, has been achieved even though the isosteric heat of adsorption (21.9-30.4 kJ/mol) for these CPMs is as low as about one-third of that for peroxo-MOF-74-Fe (66.8 kJ/mol). While the overall C2H6/C2H4 separation potentials have not yet surpassed peroxo-MOF-74-Fe, these robust CPMs exhibit outstanding properties including high thermal stability (up to 450 degrees C) and aqueous stability, low regeneration energy, and a high degree of chemical and geometrical tunability within the same isoreticular framework.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2020, "Volume": 142, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2222, "End Page": 2227, "Article Number": null, "DOI": "10.1021/jacs.9b12924", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12924", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512222700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, DL; Wang, ZX; Lu, HT; Li, H; Cui, CJ; Zhang, ZC; Sun, R; Geng, CN; Liang, QH; Guo, XX; Mo, YB; Zhi, X; Kang, FY; Weng, Z; Yang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Daliang; Wang, Zhenxing; Lu, Haotian; Li, Huan; Cui, Changjun; Zhang, Zhicheng; Sun, Rui; Geng, Chuannull; Liang, Qinghua; Guo, Xiaoxia; Mo, Yanbing; Zhi, Xing; Kang, Feiyu; Weng, Zhe; Yang, Quan-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Self-Regulated Interface toward Highly Reversible Aqueous Zinc Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc batteries, that demonstrate high safety and low cost, are considered promising candidates for large-scale energy storage. However, Zn anodes suffer from rapid performance deterioration due to the severe Zn dendrite growth and side reactions. Herein, with a low-cost ammonium acetate (NH4OAc) additive, a self-regulated Zn/electrolyte interface is built to address these problems. The NH4+ induces a dynamic electrostatic shielding layer around the abrupt Zn protuberance to make the Zn deposition uniform, and the OAc- acts as an interfacial pH buffer to suppress the proton-induced side reactions and the precipitation of insoluble by-products. As a result, in the electrolyte with the NH4OAc additive, Zn anodes exhibit a long cycling stability of 3500 h at 1 mA cm(-2), an impressive cumulative areal capacity of 5000 mAh cm(-2) at 10 mA cm(-2), and a high Coulombic efficiency of approximate to 99.7%. A prototype full cell coupled with a NH4V4O10 cathode performs much better in terms of capacity retention than the additive-free case. The findings pave the way for developing practical Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102982, "DOI": "10.1002/aenm.202102982", "DOI Link": "http://dx.doi.org/10.1002/aenm.202102982", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742747000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, C; Zhang, WJ; Deng, CJ; Li, GL; Chang, J; Zhang, ZY; Jiang, XQ; Wu, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Chun; Zhang, Wenjie; Deng, Cuijun; Li, Guanglong; Chang, Jiang; Zhang, Zhiyuan; Jiang, Xinquan; Wu, Chengtie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Lotus Root-Like Biomimetic Materials for Cell Delivery and Tissue Regeneration", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimetic materials have drawn more and more attention in recent years. Regeneration of large bone defects is still a major clinical challenge. In addition, vascularization plays an important role in the process of large bone regeneration and microchannel structure can induce endothelial cells to form rudimentary vasculature. In recent years, 3D printing scaffolds are major materials for large bone defect repair. However, these traditional 3D scaffolds have low porosity and nonchannel structure, which impede angiogenesis and osteogenesis. In this study, inspired by the microstructure of natural plant lotus root, biomimetic materials with lotus root-like structures are successfully prepared via a modified 3D printing strategy. Compared with traditional 3D materials, these biomimetic materials can significantly improve in vitro cell attachment and proliferation as well as promote in vivo osteogenesis, indicating potential application for cell delivery and bone regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700401, "DOI": "10.1002/advs.201700401", "DOI Link": "http://dx.doi.org/10.1002/advs.201700401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418385800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YZ; Tao, XF; Chen, GB; Lu, RH; Wang, D; Chen, MX; Jin, EQ; Yang, J; Liang, HW; Zhao, Y; Feng, XL; Narita, A; Müllen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yazhou; Tao, Xiafang; Chen, Guangbo; Lu, Ruihu; Wang, Ding; Chen, Ming-Xi; Jin, Enquan; Yang, Juan; Liang, Hai-Wei; Zhao, Yan; Feng, Xinliang; Narita, Akimitsu; Muellen, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multilayer stabilization for fabricating high-loading single-atom catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal single-atom catalysts (M-SACs) have emerged as an attractive concept for promoting heterogeneous reactions, but the synthesis of high-loading M-SACs remains a challenge. Here, we report a multilayer stabilization strategy for constructing M-SACs in nitrogen-, sulfur- and fluorine-co-doped graphitized carbons (M=Fe, Co, Ru, Ir and Pt). Metal precursors are embedded into perfluorotetradecanoic acid multilayers and are further coated with polypyrrole prior to pyrolysis. Aggregation of the metals is thus efficiently inhibited to achieve M-SACs with a high metal loading (similar to 16wt%). Fe-SAC serves as an efficient oxygen reduction catalyst with half-wave potentials of 0.91 and 0.82V (versus reversible hydrogen electrode) in alkaline and acid solutions, respectively. Moreover, as an air electrode in zinc-air batteries, Fe-SAC demonstrates a large peak power density of 247.7mWcm(-2) and superior long-term stability(.) Our versatile method paves an effective way to develop high-loading M-SACs for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5892, "DOI": "10.1038/s41467-020-19599-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19599-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595687000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, S; Schmidt, RD; Garcia-Mendez, R; Herbert, E; Dudney, NJ; Wolfenstine, JB; Sakamoto, J; Siegel, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Seungho; Schmidt, Robert D.; Garcia-Mendez, Regina; Herbert, Erik; Dudney, nullcy J.; Wolfenstine, Jeffrey B.; Sakamoto, Jeff; Siegel, Donald J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic Properties of the Solid Electrolyte Li7La3Zr2O12 (LLZO)", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxide known as LLZO, with nominal composition Li7La3Zr2O12, is a promising solid electrolyte for Li-based batteries due to its high Li-ion conductivity and chemical stability with respect to lithium. Solid electrolytes may also enable the use of metallic Li anodes by serving as a physical barrier that suppresses dendrite initiation and propagation during cycling. Prior linear elasticity models of the Li electrode/solid electrolyte interface suggest that the stability of this interface is highly dependent on the elastic properties of the solid separator. For example, dendritic suppression is predicted to be enhanced as the electrolyte's shear modulus increases. In the present study a combination of first-principles calculations, acoustic impulse excitation measurements, and nulloindentation experiments are used to determine the elastic constants and moduli for high-conductivity LLZO compositions based on Al and Ta doping. The calculated and measured isotropic shear moduli are in good agreement and fall within the range of 56-61 GPa. These values are an order of magnitude larger than that for Li metal and far exceed the minimum value (similar to 8.5 GPa) believed to be necessary to suppress dendrite initiation. These data suggest that LLZO exhibits sufficient stiffness to warrant additional development as a solid electrolyte for Li batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 508, "Times Cited, All Databases": 564, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2016, "Volume": 28, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 197, "End Page": 206, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b03854", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b03854", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368322600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Correa-Baena, JP; Luo, YQ; Brenner, TM; Snaider, J; Sun, SJ; Li, XY; Jensen, MA; Hartono, NTP; Nienhaus, L; Wieghold, S; Poindexter, JR; Wang, S; Meng, YS; Wang, T; Lai, B; Holt, MV; Cai, ZH; Bawendi, MG; Huang, LB; Buonassisi, T; Fenning, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Correa-Baena, Juan-Pablo; Luo, Yanqi; Brenner, Thomas M.; Snaider, Jordan; Sun, Shijing; Li, Xueying; Jensen, Mallory A.; Hartono, Noor Titan Putri; Nienhaus, Lea; Wieghold, Sarah; Poindexter, Jeremy R.; Wang, Shen; Meng, Ying Shirley; Wang, Ti; Lai, Barry; Holt, Martin V.; Cai, Zhonghou; Bawendi, Moungi G.; Huang, Libai; Buonassisi, Tonio; Fenning, David P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Homogenized halides and alkali cation segregation in alloyed organic-inorganic perovskites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The role of the alkali metal cations in halide perovskite solar cells is not well understood. Using synchrotron-based nullo-x-ray fluorescence and complementary measurements, we found that the halide distribution becomes homogenized upon addition of cesium iodide, either alone or with rubidium iodide, for substoichiometric, stoichiometric, and overstoichiometric preparations, where the lead halide is varied with respect to organic halide precursors. Halide homogenization coincides with long-lived charge carrier decays, spatially homogeneous carrier dynamics (as visualized by ultrafast microscopy), and improved photovoltaic device performance. We found that rubidium and potassium phase-segregate in highly concentrated clusters. Alkali metals are beneficial at low concentrations, where they homogenize the halide distribution, but at higher concentrations, they form recombination-active second-phase clusters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 363, "Issue": 6427, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 627, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aah5065", "DOI Link": "http://dx.doi.org/10.1126/science.aah5065", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458114200048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, FX; Zhao, SJ; Jin, K; Xue, H; Velisa, G; Bei, H; Huang, R; Ko, JYP; Pagan, DC; Neuefeind, JC; Weber, WJ; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, F. X.; Zhao, Shijun; Jin, Ke; Xue, H.; Velisa, G.; Bei, H.; Huang, R.; Ko, J. Y. P.; Pagan, D. C.; Neuefeind, J. C.; Weber, W. J.; Zhang, Yanwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Local Structure and Short-Range Order in a NiCoCr Solid Solution Alloy", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multielement solid solution alloys are intrinsically disordered on the atomic scale, and many of their advanced properties originate from the local structural characteristics. The local structure of a NiCoCr solid solution alloy is measured with x-ray or neutron total scattering and extended x-ray absorption fine structure (EXAFS) techniques. The atomic pair distribution function analysis does not exhibit an observable structural distortion. However, an EXAFS analysis suggests that the Cr atoms are favorably bonded with Ni and Co in the solid solution alloys. This short-range order (SRO) may make an important contribution to the low values of the electrical and thermal conductivities of the Cr-alloyed solid solutions. In addition, an EXAFS analysis of Ni ion irradiated samples reveals that the degree of SRO in NiCoCr alloys is enhanced after irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2017, "Volume": 118, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205501, "DOI": "10.1103/PhysRevLett.118.205501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.205501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401664000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, BC; Song, ZL; Zhu, RL; Yan, QY; Sun, QD; Grice, CG; Yan, YF; Yin, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Baicheng; Song, Zhilong; Zhu, Rilong; Yan, Qingyu; Sun, Qingde; Grice, Corey G.; Yan, Yanfa; Yin, Wan-Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simple descriptor derived from symbolic regression accelerating the discovery of new perovskite catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symbolic regression (SR) is an approach of interpretable machine learning for building mathematical formulas that best fit certain datasets. In this work, SR is used to guide the design of new oxide perovskite catalysts with improved oxygen evolution reaction (OER) activities. A simple descriptor, mu /t, where mu and t are the octahedral and tolerance factors, respectively, is identified, which accelerates the discovery of a series of new oxide perovskite catalysts with improved OER activity. We successfully synthesise five new oxide perovskites and characterise their OER activities. Remarkably, four of them, Cs0.4La0.6Mn0.25Co0.75O3, Cs0.3La0.7NiO3, SrNi0.75Co0.25O3, and Sr0.25Ba0.75NiO3, are among the oxide perovskite catalysts with the highest intrinsic activities. Our results demonstrate the potential of SR for accelerating the data-driven design and discovery of new materials with improved properties. Symbolic regression holds big promise for guiding materials design, yet its application in materials science is still limited. Here the authors use symbolic regression to introduce an activity descriptor predicting new oxide perovskites with improved oxygen evolution activity as corroborated by experimental validation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17263-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17263-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000550062200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, M; Song, HM; Xu, XY; Shahsafi, A; Qu, YR; Xia, ZY; Ma, ZQ; Kats, MA; Zhu, J; Ooi, BS; Gan, QQ; Yu, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Ming; Song, Haomin; Xu, Xingyu; Shahsafi, Alireza; Qu, Yurui; Xia, Zhenyang; Ma, Zhenqiang; Kats, Mikhail A.; Zhu, Jia; Ooi, Boon S.; Gan, Qiaoqiang; Yu, Zongfu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapor condensation with daytime radiative cooling", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A radiative vapor condenser sheds heat in the form of infrared radiation and cools itself to below the ambient air temperature to produce liquid water from vapor. This effect has been known for centuries, and is exploited by some insects to survive in dry deserts. Humans have also been using radiative condensation for dew collection. However, all existing radiative vapor condensers must operate during the nighttime. Here, we develop daytime radiative condensers that continue to operate 24 h a day. These daytime radiative condensers can produce water from vapor under direct sunlight, without active consumption of energy. Combined with traditional passive cooling via convection and conduction, radiative cooling can substantially increase the performance of passive vapor condensation, which can be used for passive water extraction and purification technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2021, "Volume": 118, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2019292118", "DOI": "10.1073/pnas.2019292118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2019292118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637398300033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, X; Dong, XY; Zou, GJ; Gao, HJ; Zhai, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xiao; Dong, Xinyu; Zou, Guijin; Gao, Huajian; Zhai, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong and tough fibrous hydrogels reinforced by multiscale hierarchical structures with multimechanisms", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tough natural materials such as nacre, bone, and silk exhibit multiscale hierarchical structures where distinct toughening mechanisms occur at each level of the hierarchy, ranging from molecular uncoiling to microscale fibrillar sliding to macroscale crack deflection. An open question is whether and how the multiscale design motifs of natural materials can be translated to the development of next-generation biomimetic hydrogels. To address this challenge, we fabricate strong and tough hydrogel with architected multiscale hierarchical structures using a freeze-casting-assisted solution substitution strategy. The underlying multiscale multimechanisms are attributed to the gel's hierarchical structures, including microscale anisotropic honeycomb-structured fiber walls and matrix, with a modulus of 8.96 and 0.73 MPa, respectively; hydrogen bond- enhanced fibers with nullocrystalline domains; and cross-linked strong polyvinyl alcohol chains with chain-connecting ionic bonds. This study establishes a blueprint of structure-performance mechanisms in tough hierarchically structured hydrogels and can inspire advanced design strategies for other promising hierarchical materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2023, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf7075", "DOI": "10.1126/sciadv.adf7075", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf7075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911464300048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, JH; Jiang, Q; Ferguson, AJ; Palmstrom, AF; Wang, XM; Hao, J; Dunfield, SP; Louks, AE; Harvey, SP; Li, CW; Lu, HP; France, RM; Johnson, SA; Zhang, F; Yang, MJ; Geisz, JF; McGehee, MD; Beard, MC; Yan, YF; Kuciauskas, D; Berry, JJ; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Jinhui; Jiang, Qi; Ferguson, Andrew J.; Palmstrom, Axel F.; Wang, Xiaoming; Hao, Ji; Dunfield, Sean P.; Louks, Amy E.; Harvey, Steven P.; Li, Chongwen; Lu, Haipeng; France, Ryan M.; Johnson, Samuel A.; Zhang, Fei; Yang, Mengjin; Geisz, John F.; McGehee, Michael D.; Beard, Matthew C.; Yan, Yanfa; Kuciauskas, Darius; Berry, Joseph J.; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carrier control in Sn-Pb perovskites via 2D cation engineering for all-perovskite tandem solar cells with improved efficiency and stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-perovskite tandem solar cells are promising for achieving photovoltaics with power conversion efficiencies above the detailed balance limit of single-junction cells, while retaining the low cost, light weight and other advantages associated with metal halide perovskite photovoltaics. However, the efficiency and stability of all-perovskite tandem cells are limited by the Sn-Pb-based narrow-bandgap perovskite cells. Here we show that the formation of quasi-two-dimensional (quasi-2D) structure (PEA)(2)GAPb(2)I(7) from additives based on mixed bulky organic cations phenethylammonium (PEA+) and guanidinium (GA+) provides critical defect control to substantially improve the structural and optoelectronic properties of the narrow-bandgap (1.25 eV) Sn-Pb perovskite thin films. This 2D additive engineering results in Sn-Pb-based absorbers with low dark carrier density (similar to 1.3 x 10(14) cm(-3)), long bulk carrier lifetime (similar to 9.2 mu s) and low surface recombination velocity (similar to 1.4 cm s(-1)), leading to 22.1%-efficient single-junction Sn-Pb perovskite cells and 25.5%-efficient all-perovskite two-terminal tandems with high photovoltage and long operational stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 642, "End Page": 651, "Article Number": null, "DOI": "10.1038/s41560-022-01046-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01046-1", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810334600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZP; Zhang, RJ; Zou, LQ; McClements, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zipei; Zhang, Ruojie; Zou, Liqiang; McClements, David Julian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protein encapsulation in alginate hydrogel beads: Effect of pH on microgel stability, protein retention and protein release", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogel beads (microgels) are promising delivery systems for encapsulation and release of proteins because they can be fabricated from food-grade biopolymers using mild processes. In this study, a model globular protein (whey protein) was encapsulated in calcium-alginate beads (D-43 = 290-520 mm) fabricated using an extrusion device with a vibrating nozzle. Protein-loaded beads were fabricated at three different pH values (pH 3, 5 and 7) to study the influence of protein-alginate electrostatic interactions on protein encapsulation, retention, and release. Protein encapsulation and retention was highest at low pH, while protein release was highest at high pH. Confocal microscopy and spectrophotometry measurements indicated that increasing the pH could trigger protein release from alginate beads formed at pH 3. These results suggest that hydrogel beads are suitable for encapsulation and pH-triggered release of proteins, which may be advantageous for certain food applications. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 58, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 308, "End Page": 315, "Article Number": null, "DOI": "10.1016/j.foodhyd.2016.03.015", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2016.03.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373168200032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XZ; Du, KZ; Liu, YYF; Hu, P; Zhang, J; Zhang, Q; Owen, MHS; Lu, X; Gan, CK; Sengupta, P; Kloc, C; Xiong, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xingzhi; Du, Kezhao; Liu, Yu Yang Fredrik; Hu, Peng; Zhang, Jun; Zhang, Qing; Owen, Man Hon Samuel; Lu, Xin; Gan, Chee Kwan; Sengupta, Pinaki; Kloc, Christian; Xiong, Qihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman spectroscopy of atomically thin two-dimensional magnetic iron phosphorus trisulfide (FePS3) crystals", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal phosphorous trichalcogenide is an important group of layered two-dimensional (2D) materials with potentially diverse applications in low-dimensional magnetic and spintronic devices. Herein we present a comprehensive investigation on the lattice dynamics and spin-phonon interactions of mechanically exfoliated atomically thin 2D magnetic material-iron phosphorus trisulfide (FePS3) by Raman spectroscopy and first principle calculations. Layer-number and temperature dependent Raman spectroscopy suggests a magnetic persistence in FePS3 even down to monolayer regime through the spin-phonon coupling, while the Neel temperature decreases from 117 Kin bulk to 104 K in monolayer sample. Our studies advocate the intriguing magnetic properties in 2D crystals and suggest that FePS3 is a promising candidate material for future magnetic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31009, "DOI": "10.1088/2053-1583/3/3/031009", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/3/3/031009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384071000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, SH; Lin, JC; Farmand, M; Landers, AT; Feaster, JT; Acosta, JEA; Beeman, JW; Ye, YF; Yano, J; Mehta, A; Davis, RC; Jaramillo, TF; Hahn, C; Drisdell, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Soo Hong; Lin, John C.; Farmand, Maryam; Landers, Alan T.; Feaster, Jeremy T.; Acosta, Jaime E. Aviles; Beeman, Jeffrey W.; Ye, Yifan; Yano, Junko; Mehta, Apurva; Davis, Ryan C.; Jaramillo, Thomas F.; Hahn, Christopher; Drisdell, Walter S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxidation State and Surface Reconstruction of Cu under CO2 Reduction Conditions from In Situ X-ray Characterization", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical CO2 reduction reaction (CO2RR) using Cu-based catalysts holds great potential for producing valuable multi-carbon products from renewable energy. However, the chemical and structural state of Cu catalyst surfaces during the CO2RR remains a matter of debate. Here, we show the structural evolution of the near-surface region of polycrystalline Cu electrodes under in situ conditions through a combination of grazing incidence X-ray absorption spectroscopy (GIXAS) and X-ray diffraction (GIXRD). The in situ GIXAS reveals that the surface oxide layer is fully reduced to metallic Cu before the onset potential for CO2RR, and the catalyst maintains the metallic state across the potentials relevant to the CO2RR. We also find a preferential surface reconstruction of the polycrystalline Cu surface toward (100) facets in the presence of CO2. Quantitative analysis of the reconstruction profiles reveals that the degree of reconstruction increases with increasingly negative applied potentials, and it persists when the applied potential returns to more positive values. These findings show that the surface of Cu electrocatalysts is dynamic during the CO2RR, and emphasize the importance of in situ characterization to understand the surface structure and its role in electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2021, "Volume": 143, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 588, "End Page": 592, "Article Number": null, "DOI": "10.1021/jacs.0c10017", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c10017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612557200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sebastian, A; Pendurthi, R; Choudhury, TH; Redwing, JM; Das, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sebastian, Amritanulld; Pendurthi, Rahul; Choudhury, Tanushree H.; Redwing, Joan M.; Das, Saptarshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Benchmarking monolayer MoS2 and WS2 field-effect transistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we benchmark device-to-device variation in field-effect transistors (FETs) based on monolayer MoS2 and WS2 films grown using metal-organic chemical vapor deposition process. Our study involves 230 MoS2 FETs and 160 WS2 FETs with channel lengths ranging from 5 mu m down to 100nm. We use statistical measures to evaluate key FET performance indicators for benchmarking these two-dimensional (2D) transition metal dichalcogenide (TMD) monolayers against existing literature as well as ultra-thin body Si FETs. Our results show consistent performance of 2D FETs across 1x1cm(2) chips owing to high quality and uniform growth of these TMDs followed by clean transfer onto device substrates. We are able to demonstrate record high carrier mobility of 33cm(2)V(-1)s(-1) in WS2 FETs, which is a 1.5X improvement compared to the best reported in the literature. Our experimental demonstrations confirm the technological viability of 2D FETs in future integrated circuits. Here, the authors perform a benchmark study of field-effect transistors (FETs) based on 2D transition metal dichalcogenides, i.e., 230 MoS2 and 160 WS2 FETs, and track device-to-device variations to gauge the technological viability in future integrated circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 693, "DOI": "10.1038/s41467-020-20732-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20732-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684845600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, Q; Ramaswamy, N; Hafiz, H; Tylus, U; Strickland, K; Wu, G; Barbiellini, B; Bansil, A; Holby, EF; Zelenay, P; Mukerjee, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Qingying; Ramaswamy, Nagappan; Hafiz, Hasnain; Tylus, Urszula; Strickland, Kara; Wu, Gang; Barbiellini, Bernardo; Bansil, Arun; Holby, Edward F.; Zelenay, Piotr; Mukerjee, Sanjeev", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Observation of Redox-Induced Fe-N Switching Behavior as a Determinullt Role for Oxygen Reduction Activity", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The commercialization of electrochemical energy conversion and storage devices relies largely upon the development of highly active catalysts based on abundant and inexpensive materials. Despite recent achievements in this respect, further progress is hindered by the poor understanding of the nature of active sites and reaction mechanisms. Herein, by characterizing representative iron-based catalysts under reactive conditions, we identify three Fe-N-4-like catalytic centers with distinctly different Fe-N switching behaviors (Fe moving toward or away from the N-4-plane) during the oxygen reduction reaction (ORR), and show that their ORR activities are essentially governed by the dynamic structure associated with the Fe2+/3+ redox transition, rather than the static structure of the bare sites. Our findings reveal the structural origin of the enhanced catalytic activity of pyrolyzed Fe-based catalysts compared to nonpyrolyzed Fe-macrocycle compounds. More generally, the fundamental insights into the dynamic nature of transition-metal compounds during electron-transfer reactions will potentially guide rational design of these materials for broad applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12496, "End Page": 12505, "Article Number": null, "DOI": "10.1021/acsnullo.5b05984", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b05984", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367280100103", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, QJ; Sheng, H; Ma, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qing-Jie; Sheng, Howard; Ma, Evan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strengthening in multi-principal element alloys with local-chemical-order roughened dislocation pathways", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy and medium-entropy alloys are presumed to have a configurational entropy as high as that of an ideally mixed solid solution (SS) of multiple elements in near-equal proportions. However, enthalpic interactions inevitably render such chemically disordered SSs rare and metastable, except at very high temperatures. Here we highlight the wide variety of local chemical ordering (LCO) that sets these concentrated SSs apart from traditional solvent-solute ones. Using atomistic simulations, we reveal that the LCO of the multiprincipal-element NiCoCr SS changes with alloy processing conditions, producing a wide range of generalized planar fault energies. We show that the LCO heightens the ruggedness of the energy landscape and raises activation barriers governing dislocation activities. This influences the selection of dislocation pathways in slip, faulting, and twinning, and increases the lattice friction to dislocation motion via a nulloscale segment detrapping mechanism. In contrast, severe plastic deformation reduces the LCO towards random SS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 579, "Times Cited, All Databases": 608, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3563, "DOI": "10.1038/s41467-019-11464-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11464-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479188700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, BW; Yao, HL; Yang, JC; Chen, C; Shi, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Bowen; Yao, Heliang; Yang, Jiacai; Chen, Chang; Shi, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of a two-dimensional artificial antioxidase for nullocatalytic rheumatoid arthritis treatment", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing nullomaterials mimicking the coordination environments of natural enzymes may achieve biomimetic catalysis. Here we construct a two-dimensional (2D) metal-organic framework (MOF) nullosheet catalyst as an artificial antioxidase for nullocatalytic rheumatoid arthritis treatment. The 2D MOF periodically assembles numbers of manganese porphyrin molecules, which has a metal coordination geometry analogous to those of two typical antioxidases, human mitochondrial manganese superoxide dismutase (Mn-SOD) and human erythrocyte catalase. The zinc atoms of the 2D MOF regulate the metal-centered redox potential of coordinated manganese porphyrin ligand, endowing the nullosheet with both SOD- and catalase-like activities. Cellular experiments show unique anti-inflammatory and pro-biomineralization performances of the 2D MOF, while in vivo animal model further demonstrates its desirable antiarthritic efficacy. It is expected that such a nullocatalytic antioxidation concept may provide feasible approaches to future anti-inflammatory treatments. Inflammatory diseases such as rheumatoid arthritis are associated with high reactive oxygen species levels. Here, the authors report on 2D metal-organic frameworks as an artificial antioxidase with the same manganese coordination centre as two natural enzymes, and demonstrate their anti-inflammatory effects and anti-arthritic effects in vivo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1988, "DOI": "10.1038/s41467-022-29735-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29735-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783759500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Jiang, X; Li, RQ; Liang, B; Zou, XY; Yin, LL; Cheng, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yong; Jiang, Xue; Li, Rui-qi; Liang, Bin; Zou, Xin-ye; Yin, Lei-lei; Cheng, Jian-chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Realization of Full Control of Reflected Waves with Subwavelength Acoustic Metasurfaces", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces with subwavelength thicknesses have exhibited unconventional phenomena in ways that could not be mimicked by traditional materials. Here we report on the analytical design and experimental realizations of acoustic metasurfaces with hitherto inaccessible functionality of manipulating the reflected waves arbitrarily. By suitably designing the phase-shift profile with a 2 pi span induced by labyrinthine units, the metasurface can reflect acoustic waves in an unusual yet controllable manner. Anomalous reflection and ultrathin planar lenses are both demonstrated with carefully designed metasurfaces. Remarkably, the free manipulation of phase shifts offers great flexibility in the design of nonparaxial acoustic self-accelerating beams with arbitrary trajectories. With extraordinary wave-steering ability, the metasurface should open exciting possibilities for designing compact acoustic components with versatile potential and may find a variety of applications ranging from ultrasound imaging to caustic engineering where designing the shape of a focused trajectory of sound is required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2014, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64002, "DOI": "10.1103/PhysRevApplied.2.064002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.2.064002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349419500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, AW; Du, M; Ni, JX; Liu, DQ; Pan, YH; Liang, XY; Liu, DM; Ma, J; Wang, J; Wang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Aiwen; Du, Meng; Ni, Jiaxin; Liu, Dongqing; Pan, Yunhao; Liang, Xiongying; Liu, Dongmei; Ma, Jun; Wang, Jing; Wang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced and synergistic catalytic activation by photoexcitation driven S-scheme heterojunction hydrogel interface electric field", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The regulation of heterogeneous material properties to enhance the peroxymonosulfate (PMS) activation to degrade emerging organic pollutants remains a challenge. To solve this problem, we synthesize S-scheme heterojunction PBA/MoS2@chitosan hydrogel to achieve photoexcitation synergistic PMS activation. The constructed heterojunction photoexcited carriers undergo redox conversion with PMS through S-scheme transfer pathway driven by the directional interface electric field. Multiple synergistic pathways greatly enhance the reactive oxygen species generation, leading to a significant increase in doxycycline degradation rate. Meanwhile, the 3D polymer chain spatial structure of chitosan hydrogel is conducive to rapid PMS capture and electron transport in advanced oxidation process, reducing the use of transition metal activator and limiting the leaching of metal ions. There is reason to believe that the synergistic activation of PMS by S-scheme heterojunction regulated by photoexcitation will provide a new perspective for future material design and research on enhancing heterologous catalysis oxidation process. The regulation of heterogeneous material properties to enhance the peroxymonosulfate activation remains a challenge. Here, authors synthesize S-scheme heterojunction PBA/MoS2@chitosan hydrogel to achieve photoexcitation synergistic peroxymonosulfate activation driven by interface electric field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6733, "DOI": "10.1038/s41467-023-42542-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42542-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001100643800030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pere, CPP; Economidou, SN; Lall, G; Ziraud, C; Boateng, JS; Alexander, BD; Lamprou, DA; Douroumis, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pere, Cristiane Patricia Pissinato; Economidou, Sophia N.; Lall, Gurprit; Ziraud, Clementine; Boateng, Joshua S.; Alexander, Bruce D.; Lamprou, Dimitrios A.; Douroumis, Dennis", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printed microneedles for insulin skin delivery", "Source Title": "INTERNATIONAL JOURNAL OF PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, polymeric microneedle patches were fabricated by stereolithography, a 3D printing technique, for the transdermal delivery of insulin. A biocompatible resin was photopolymerized to build pyramid and cone microneedle designs followed by inkjet print coating of insulin formulations. Trehalose, mannitol and xylitol were used as drug carriers with the aim to preserve insulin integrity and stability but also to facilitate rapid release rates. Circular dichroism and Raman analysis demonstrated that all carriers maintained the native form of insulin, with xylitol presenting the best performance. Franz cell release studies were used for in vitro determination of insulin release rates in porcine skin. Insulin was released rapidly within 30 min irrespectively of the microneedle design. 3D printing was proved an effective technology for the fabrication of biocompatible and scalable microneedle patches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 544, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 425, "End Page": 432, "Article Number": null, "DOI": "10.1016/j.ijpharm.2018.03.031", "DOI Link": "http://dx.doi.org/10.1016/j.ijpharm.2018.03.031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432874300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging investigator series: the rise of nullo-enabled photothermal materials for water evaporation and clean water production by sunlight", "Source Title": "ENVIRONMENTAL SCIENCE-nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar driven water evaporation and distillation is an ancient technology, but has been rejuvenated by nullo-enabled photothermal materials in the past 4 years. The nullo-enabled state-of-the-art photothermal materials are able to harvest a full solar spectrum and convert it to heat with extremely high efficiency. Moreover, photothermal structures with heat loss management have evolved in parallel. These together have led to the steadily and significantly improved energy efficiency of solar evaporation and distillation in the past 4 years. Some unprecedented clean water production rates have been reported in small-scale and fully solar-driven devices. This frontier presents a timely and systematic review of the impressive developments in photothermal nullomaterial discovery, selection, optimization, and photothermal structural designs along with their applications especially in clean water production. The current challenges and future perspectives are provided. This article helps inspire more research efforts from environmental nullo communities to push forward practical solar-driven clean water production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1078, "End Page": 1089, "Article Number": null, "DOI": "10.1039/c8en00156a", "DOI Link": "http://dx.doi.org/10.1039/c8en00156a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Environmental Sciences & Ecology; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432684200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, N; Zhai, LP; Coupry, DE; Addicoat, MA; Okushita, K; Nishimura, K; Heine, T; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Ning; Zhai, Lipeng; Coupry, Damien E.; Addicoat, Matthew A.; Okushita, Keiko; Nishimura, Katsuyuki; Heine, Thomas; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple-component covalent organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks are a class of crystalline porous polymers that integrate molecular building blocks into periodic structures and are usually synthesized using two-component [1+1] condensation systems comprised of one knot and one linker. Here we report a general strategy based on multiple-component [1+2] and [1+3] condensation systems that enable the use of one knot and two or three linker units for the synthesis of hexagonal and tetragonal multiple-component covalent organic frameworks. Unlike two-component systems, multiple-component covalent organic frameworks feature asymmetric tiling of organic units into anisotropic skeletons and unusually shaped pores. This strategy not only expands the structural complexity of skeletons and pores but also greatly enhances their structural diversity. This synthetic platform is also widely applicable to multiple-component electron donor-acceptor systems, which lead to electronic properties that are not simply linear summations of those of the conventional [1+1] counterparts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12325, "DOI": "10.1038/ncomms12325", "DOI Link": "http://dx.doi.org/10.1038/ncomms12325", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380538600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Otrokov, MM; Rusinov, IP; Blanco-Rey, M; Hoffmann, M; Vyazovskaya, AY; Eremeev, SV; Ernst, A; Echenique, PM; Arnau, A; Chulkov, EV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Otrokov, M. M.; Rusinov, I. P.; Blanco-Rey, M.; Hoffmann, M.; Vyazovskaya, A. Yu; Eremeev, S., V; Ernst, A.; Echenique, P. M.; Arnau, A.; Chulkov, E., V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unique Thickness-Dependent Properties of the van der Waals Interlayer Antiferromagnet MnBi2Te4 Films", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using density functional theory and Monte Carlo calculations, we study the thickness dependence of the magnetic and electronic properties of a van der Waals interlayer antiferromagnet in the two-dimensional limit. Considering MnBi2Te4 as a model material, we find it to demonstrate a remarkable set of thickness-dependent magnetic and topological transitions. While a single septuple layer block of MnBi2Te4 is a topologically trivial ferromagnet, the thicker films made of an odd (even) number of blocks are uncompensated (compensated) interlayer antiferromagnets, which show wide band gap quantum anomalous Hall (zero plateau quantum anomalous Hall) states. Thus, MnBi2Te4 is the first stoichiometric material predicted to realize the zero plateau quantum anomalous Hall state intrinsically. This state has been theoretically shown to host the exotic axion insulator phase.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 542, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2019, "Volume": 122, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107202, "DOI": "10.1103/PhysRevLett.122.107202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.107202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461070200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, XL; Liu, GH; Li, Y; Wang, XR; Liu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Xianglong; Liu, Guhuan; Li, Yang; Wang, Xiaorui; Liu, Shiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cell-Penetrating Hyperbranched Polyprodrug Amphiphiles for Synergistic Reductive Milieu-Triggered Drug Release and Enhanced Magnetic Resonullce Signals", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of theranostic nulloparticles exhibiting synergistic turn-on of therapeutic potency and enhanced diagnostic imaging in response to tumor milieu is critical for efficient personalized cancer chemotherapy. We herein fabricate self-reporting theranostic drug nullocarriers based on hyperbranched polyprodrug amphiphiles (hPAs) consisting of hyperbranched cores conjugated with reduction-activatable camptothecin prodrugs and magnetic resonullce (MR) imaging contrast agent (Gd complex), and hydrophilic coronas functionalized with guanidine residues. Upon cellular internalization, reductive milieu-actuated release of anticancer drug in the active form, activation of therapeutic efficacy (>70-fold enhancement in cytotoxicity), and turn-on of MR imaging (similar to 9.6-fold increase in T-1 relaxivity) were simultaneously achieved in the simulated cytosol milieu. In addition, guanidine-decorated hPAs exhibited extended blood circulation with a half-life up to similar to 9.8 h and excellent tumor cell penetration potency. The hyperbranched chain topology thus provides a novel theranostic polyprodrug platform for synergistic imaging/chemotherapy and enhanced tumor uptake.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 137, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 362, "End Page": 368, "Article Number": null, "DOI": "10.1021/ja5105848", "DOI Link": "http://dx.doi.org/10.1021/ja5105848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348483500064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Imran, M; Caligiuri, V; Wang, MJ; Goldoni, L; Prato, M; Krahne, R; De Trizio, L; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Imran, Muhammad; Caligiuri, Vincenzo; Wang, Mengjiao; Goldoni, Luca; Prato, Mirko; Krahne, Roman; De Trizio, Luca; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Benzoyl Halides as Alternative Precursors for the Colloidal Synthesis of Lead-Based Halide Perovskite nullocrystals", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose here a new colloidal approach for the synthesis of both all-inorganic and hybrid organic-inorganic lead halide perovskite nullocrystals (NCs). The main limitation of the protocols that are currently in use, such as the hot injection and the ligand-assisted reprecipitation routes, is that they employ PbX2 (X = Cl, Br, or I) salts as both lead and halide precursors. This imposes restrictions on being able to precisely tune the amount of reaction species and, consequently, on being able to regulate the composition of the final NCs. In order to overcome this issue, we show here that benzoyl halides can be efficiently used as halide sources to be injected in a solution of metal cations (mainly in the form of metal carboxylates) for the synthesis of APbX(3) NCs (in which A = Cs+, CH3NH3+, or CH(NH2)(2)(+)). In this way, it is possible to independently tune the amount of both cations and halide precursors in the synthesis. The APbX(3) NCs that were prepared with our protocol show excellent optical properties, such as high photoluminescence quantum yields, low amplified spontaneous emission thresholds, and enhanced stability in air. It is noteworthy that CsPbI3 NCs, which crystallize in the cubic a phase, are stable in air for weeks without any postsynthesis treatment. The improved properties of our CsPbX3 perovskite NCs can be ascribed to the formation of lead halide terminated surfaces, in which Cs cations are replaced by alkylammonium ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 524, "Times Cited, All Databases": 546, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 140, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2656, "End Page": 2664, "Article Number": null, "DOI": "10.1021/jacs.7b13477", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b13477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426143800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Edri, E; Kirmayer, S; Kulbak, M; Hodes, G; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Edri, Eran; Kirmayer, Saar; Kulbak, Michael; Hodes, Gary; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chloride Inclusion and Hole Transport Material Doping to Improve Methyl Ammonium Lead Bromide Perovskite-Based High Open-Circuit Voltage Solar Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-cost solar cells with high V-OC, relatively small (E-G - qV(OC)), and high qV(OC)/E-G ratio, where E-G is the absorber band gap, are long sought after, especially for use in tandem cells or other systems with spectral splitting. We report a significant improvement in CH3NH3PbBr3-based cells, using CH(3)NH(3)PbBr(3-)xCl(x), with E-G = 2.3 eV, as the absorber in a mesoporous p-i-n device configuration. By p-doping an organic hole transport material with a deep HOMO level and wide band gap to reduce recombination, the cell's V-OC increased to 1.5 V, a 0.2 V increase from our earlier results with the pristine Br analogue with an identical band gap. At the same time, in the most efficient devices, the current density increased from similar to 1 to 4 mA/cm(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2014, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 429, "End Page": 433, "Article Number": null, "DOI": "10.1021/jz402706q", "DOI Link": "http://dx.doi.org/10.1021/jz402706q", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331153600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, PF; Pu, TC; Nie, AM; Hwang, S; Purdy, SC; Yu, WJ; Su, D; Miller, JT; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Pengfei; Pu, Tiancheng; Nie, Anmin; Hwang, Sooyeon; Purdy, Stephen C.; Yu, Wenjian; Su, Dong; Miller, Jeffrey T.; Wang, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloceria-Supported Single-Atom Platinum Catalysts for Direct Methane Conversion", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloceria-supported atomic Pt catalysts (denoted as Pt-1@CeO2) have been synthesized and demonstrated with advanced catalytic performance for the nonoxidative, direct conversion of methane. These catalysts were synthesized by calcination of Pt-impregnated porous ceria nulloparticles at high temperature (ca. 1000 degrees C), with the atomic dispersion of Pt characterized by combining aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS), and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) analyses. The Pt-1@CeO2 catalysts exhibited much superior catalytic performance to its nulloparticulated counterpart, achieving 14.4% of methane conversion at 975 C and 74.6% selectivity toward C-2 products (ethane, ethylene, and acetylene). Comparative studies of the Pt-1@CeO2 catalysts with different loadings as well as the nulloparticulated counterpart reveal the single-atom Pt to be the active sites for selective conversion of methane into C-2 hydrocarbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4044, "End Page": 4048, "Article Number": null, "DOI": "10.1021/acscatal.8b00004", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b00004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431727300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZK; Chen, BX; Chen, WX; Qu, YT; Zhou, FY; Zhao, CM; Xu, Q; Zhang, QH; Duan, XZ; Wu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zhengkun; Chen, Bingxu; Chen, Wenxing; Qu, Yunteng; Zhou, Fangyao; Zhao, Changming; Xu, Qian; Zhang, Qinghua; Duan, Xuezhi; Wu, Yuen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directly transforming copper (I) oxide bulk into isolated single-atom copper sites catalyst through gas-transport approach", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom metal catalysts have sparked tremendous attention, but direct transformation of cheap and easily obtainable bulk metal oxide into single atoms is still a great challenge. Here we report a facile and versatile gas-transport strategy to synthesize isolated single-atom copper sites (Cu ISAS/NC) catalyst at gram levels. Commercial copper (I) oxide powder is sublimated as mobile vapor at nearly melting temperature (1500 K) and subsequently can be trapped and reduced by the defect-rich nitrogen-doped carbon (NC), forming the isolated copper sites catalyst. Strikingly, this thermally stable Cu ISAS/NC, which is obtained above 1270 K, delivers excellent oxygen reduction performance possessing a recorded half-wave potential of 0.92 V vs RHE among other Cu-based electrocatalysts. By varying metal oxide precursors, we demonstrate the universal synthesis of different metal single atoms anchored on NC materials (M ISAS/NC, where M refers to Mo and Sn). This strategy is readily scalable and the as-prepared sintering-resistant M ISAS/NC catalysts hold great potential in high-temperature applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3734, "DOI": "10.1038/s41467-019-11796-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11796-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481607000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CL; Yao, ZP; Wang, QD; Li, HF; Wang, JL; Liu, M; Ganapathy, S; Lu, YX; Cabana, J; Li, BH; Bai, XD; Aspuru-Guzik, A; Wagemaker, M; Chen, LQ; Hu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chenglong; Yao, Zhenpeng; Wang, Qidi; Li, Haifeng; Wang, Jianlin; Liu, Ming; Ganapathy, Swapna; Lu, Yaxiang; Cabana, Jordi; Li, Baohua; Bai, Xuedong; Aspuru-Guzik, Alan; Wagemaker, Marnix; Chen, Liquan; Hu, Yong-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing High Na-Content P2-Type Layered Oxides as Advanced Sodium-Ion Cathodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered Na-based oxides with the general composition of NaxTMO2 (TM: transition metal) have attracted significant attention for their high compositional diversity that provides tunable electrochemical performance for electrodes in sodium-ion batteries. The various compositions bring forward complex structural chemistry that is decisive for the layered stacking structure, Na-ion conductivity, and the redox activity, potentially promising new avenues in functional material properties. In this work, we have explored the maximum Na content in P2-type layered oxides and discovered that the high-content Na in the host enhances the structural stability; moreover, it promotes the oxidation of low-valent cations to their high oxidation states (in this case Ni2+). This can be rationalized by the increased hybridization of the O(2p)-TM(3d-e(g)*) states, affecting both the local TM environment as well as the interactions between the NaO2 and TMO2 layers. These properties are highly beneficial for the Na storage capabilities as required for cathode materials in sodium-ion batteries. It leads to excellent Na-ion mobility, a large storage capacity (>100 mAh g(-1) between 2.0-4.0 V), yet preventing the detrimental sliding of the TMO2 layers (P2-O2 structural transition), as reflected by the ultralong cycle life (3000 (dis)charge cycles demonstrated). These findings expand the horizons of high Na-content P2-type materials, providing new insights of the electronic and structural chemistry for advanced cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2020, "Volume": 142, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5742, "End Page": 5750, "Article Number": null, "DOI": "10.1021/jacs.9b13572", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13572", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526393100036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Li, LB; Wang, JX; Wen, HM; Krishna, R; Wu, H; Zhou, W; Chen, ZN; Li, B; Qian, GD; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xu; Li, Libo; Wang, Jia-Xin; Wen, Hui-Min; Krishna, Rajamani; Wu, Hui; Zhou, Wei; Chen, Zhong-Ning; Li, Bin; Qian, Guodong; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The separation of ethane (C2H6) from ethylene (C2H4) is of prime importance in the production of polymer-grade C2H4 for industrial manufacturing. It is very challenging and still remains unexploited to fully realize efficient C2H6/C2H4 separation in the emerging hydrogen-bonded organic frameworks (HOFs) due to the weak nature of hydrogen bonds. We herein report the benchmark example of a novel ultrarobust HOF adsorbent (termed as HOF-76a) with a Brunauer-Emmett-Teller surface area exceeding 1100 m(2) g(-1), exhibiting the preferential binding of C2H6 over C2H4 and thus highly selective separation of C2H6/C2H4. Theoretical calculations indicate the key role of the nonpolar surface and the suitable triangular channel-like pores in HOF-76a to sterically match better with the nonplanar C2H6 molecule than the planar C2H4, thus affording overall stronger multipoint van der Waals interactions with C2H6. The exceptional separation performance of HOF-76a for C2H6/C2H4 separation was clearly demonstrated by gas adsorption isotherms, ideal adsorbed solution theory calculations, and simulated and experimental breakthrough curves. Breakthrough experiments on HOF-76a reveal that polymer-grade ethylene gas can be straightforwardly produced from 50/50 (v/v) C2H6/C2H4 mixtures during the first adsorption cycle with a high productivity of 7.2 L/kg at 298 K and 1.01 bar and 18.8 L/kg at 298 K and 5.0 bar, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2020, "Volume": 142, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 633, "End Page": 640, "Article Number": null, "DOI": "10.1021/jacs.9b12428", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b12428", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507144400075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharafi, A; Yu, SH; Naguib, M; Lee, M; Ma, C; Meyer, HM; nullda, J; Chi, MF; Siegel, DJ; Sakamoto, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharafi, Asma; Yu, Seungho; Naguib, Michael; Lee, Marcus; Ma, Cheng; Meyer, Harry M.; nullda, Jagjit; Chi, Maiofang; Siegel, Donald J.; Sakamoto, Jeff", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of air exposure and surface chemistry on Li-Li7La3Zr2O12 interfacial resistance", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li7La3Zr2O12 (LLZO) is a promising solid-state electrolyte that could enable solid-state-batteries (SSB) employing metallic Li anodes. For a SSB to be viable, the stability and charge transfer kinetics at the LiLLZO interface should foster facile plating and stripping of Li. Contrary to these goals, recent studies have reported high Li-LLZO interfacial resistance which was attributed to a contamination layer that forms upon exposure of LLZO to air. This study clarifies the mechanisms and consequences associated with air exposure of LLZO; additionally, strategies to minimize these effects are described. First principles calculations reveal that LLZO readily reacts with humid air; the most favorable reaction pathway involves protonation of LLZO and formation of Li2CO3. X-ray photoelectron spectroscopy, scanning electron microscopy, Raman spectroscopy, and transmission electron microscopy were used to characterize the surface and subsurface chemistry of LLZO as a function of relative humidity and exposure time. Additionally, electrochemical impedance spectroscopy was used to measure the Li-LLZO interfacial resistance as a function of surface contamination. These data indicate that air exposure induced contamination impacts the interfacial resistance significantly, when exposure time exceeds 24 h. The results of this study provide valuable insight into the sensitivity of LLZO to air and how the effects of air contamination can be reversed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2017, "Volume": 5, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13475, "End Page": 13487, "Article Number": null, "DOI": "10.1039/c7ta03162a", "DOI Link": "http://dx.doi.org/10.1039/c7ta03162a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404618200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sahraie, NR; Kramm, UI; Steinberg, J; Zhang, YJ; Thomas, A; Reier, T; Paraknowitsch, JP; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sahraie, Nastaran Ranjbar; Kramm, Ulrike I.; Steinberg, Julian; Zhang, Yuanjian; Thomas, Arne; Reier, Tobias; Paraknowitsch, Jens-Peter; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon materials doped with transition metal and nitrogen are highly active, non-precious metal catalysts for the electrochemical conversion of molecular oxygen in fuel cells, metal air batteries, and electrolytic processes. However, accurate measurement of their intrinsic turn-over frequency and active-site density based on metal centres in bulk and surface has remained difficult to date, which has hampered a more rational catalyst design. Here we report a successful quantification of bulk and surface-based active-site density and associated turn-over frequency values of mono-and bimetallic Fe/N-doped carbons using a combination of chemisorption, desorption and Fe-57 Mossbauer spectroscopy techniques. Our general approach yields an experimental descriptor for the intrinsic activity and the active-site utilization, aiding in the catalyst development process and enabling a previously unachieved level of understanding of reactivity trends owing to a deconvolution of site density and intrinsic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8618, "DOI": "10.1038/ncomms9618", "DOI Link": "http://dx.doi.org/10.1038/ncomms9618", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364934200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Li, XL; Qin, GF; Luo, K; Lu, J; Li, YB; Liang, GJ; Huang, ZD; Zhou, J; Hultman, L; Eklund, P; Persson, POÅ; Du, SY; Chai, ZF; Zhi, CY; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mian; Li, Xinliang; Qin, Guifang; Luo, Kan; Lu, Jun; Li, Youbing; Liang, Guojin; Huang, Zhaodong; Zhou, Jie; Hultman, Lars; Eklund, Per; Persson, Per O. A.; Du, Shiyu; Chai, Zhifang; Zhi, Chunyi; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halogenated Ti3C2 MXenes with Electrochemically Active Terminals for High-Performance Zinc Ion Batteries", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The class of two-dimensional metal carbides and nitrides known as MXenes offer a distinct manner of property tailoring for a wide range of applications. The ability to tune the surface chemistry for expanding the property space of MXenes is thus an important topic, although experimental exploration of surface terminals remains a challenge. Here, we synthesized Ti3C2 MXene with unitary, binary, and ternary halogen terminals, e.g., -Cl, -Br, -I, -BrI, and -ClBrI, to investigate the effect of surface chemistry on the properties of MXenes. The electrochemical activity of Br and I elements results in the extraordinary electrochemical performance of the MXenes as cathodes for aqueous zinc ion batteries. The -Br- and -I-containing MXenes, e.g., Ti3C2Br2 and Ti3C2I2, exhibit distinct discharge platforms with considerable capacities of 97.6 and 135 mA.g(-1). Ti3C2 (BrI) and Ti3C2 (ClBrI) exhibit dual discharge platforms with capacities of 117.2 and 106.7 mAh.g(-1). In contrast, the previously discovered MXenes Ti3C2Cl2 and Ti3C2 (OF) exhibit no discharge platforms and only similar to 50% of capacities and energy densities of Ti3C2Br2. These results emphasize the effectiveness of the Lewis-acidic-melt etching route for tuning the surface chemistry of MXenes and also show promise for expanding the MXene family toward various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2021, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1077, "End Page": 1085, "Article Number": null, "DOI": "10.1021/acsnullo.0c07972", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c07972", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613942700080", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thakur, S; Sharma, B; Verma, A; Chaudhary, J; Tamulevicius, S; Thakur, VK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thakur, Sourbh; Sharma, Bhawna; Verma, Ankit; Chaudhary, Jyoti; Tamulevicius, Sigitas; Thakur, Vijay Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress in sodium alginate based sustainable hydrogels for environmental applications", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, there is a growing research interest in the applications and development of novel sustainable hydrogel materials in waste water treatment because of radically distinctive chemical and physical characteristics of hydrogels such as hydrophilicity, swell ability and modifiability to name a few. Hydrogels have exposed the hypernym functioning in the removal of a wide range of aqueous pollutants containing toxic dyes and heavy metal ions. A large amount of water gets incorporated in the three dimensional networks of hydrophilic structures of hydrogels. The prime objective of this review article is to render a presentation on the recent advances in the modifications of sodium alginate based hydrogels for the adsorptive removal of toxic pollutants. In addition, article also briefly gives the classification and properties of hydrogels and alginate. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2018, "Volume": 198, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 143, "End Page": 159, "Article Number": null, "DOI": "10.1016/j.jclepro.2018.06.259", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2018.06.259", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442973100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, HY; Liu, XY; An, PF; Tang, C; Yu, HM; Zhang, QH; Peng, HJ; Gu, L; Zheng, Y; Song, TS; Davey, K; Paik, U; Dong, JC; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Huanyu; Liu, Xinyan; An, Pengfei; Tang, Cheng; Yu, Huimin; Zhang, Qinghua; Peng, Hong-Jie; Gu, Lin; Zheng, Yao; Song, Taeseup; Davey, Kenneth; Paik, Ungyu; Dong, Juncai; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic rhenium dopant boosts ruthenium oxide for durable oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heteroatom-doping is a practical means to boost RuO2 for acidic oxygen evolution reaction (OER). However, a major drawback is conventional dopants have static electron redistribution. Here, we report that Re dopants in Re0.06Ru0.94O2 undergo a dynamic electron accepting-donating that adaptively boosts activity and stability, which is different from conventional dopants with static dopant electron redistribution. We show Re dopants during OER, (1) accept electrons at the on-site potential to activate Ru site, and (2) donate electrons back at large overpotential and prevent Ru dissolution. We confirm via in situ characterizations and first-principle computation that the dynamic electron-interaction between Re and Ru facilitates the adsorbate evolution mechanism and lowers adsorption energies for oxygen intermediates to boost activity and stability of Re0.06Ru0.94O2. We demonstrate a high mass activity of 500 A g(cata.)(-1) (7811 A g(Re-Ru)(-1)) and a high stability number of S-number = 4.0 x 10(6) n(oxygen) n(Ru)(-1) to outperform most electrocatalysts. We conclude that dynamic dopants can be used to boost activity and stability of active sites and therefore guide the design of adaptive electrocatalysts for clean energy conversions. RuO2 is a promising anode catalyst for proton exchange membrane water electrolyzers but suffers from poor catalytic stability. Here the authors present a rhenium-doped RuO2 with a unique dynamic electron accepting-donating that adaptively boosts activity and stability in acidic water oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 354, "DOI": "10.1038/s41467-023-35913-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35913-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953220800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YF; Guo, Y; Lu, XF; Luan, DY; Gu, XJ; Lou, XWD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yafei; Guo, Yan; Lu, Xue Feng; Luan, Deyan; Gu, Xiaojun; Lou, Xiong Wen David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exposing Single Ni Atoms in Hollow S/N-Doped Carbon Macroporous Fibers for Highly Efficient Electrochemical Oxygen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient and cost-effective electrocatalysts toward the oxygen evolution reaction (OER) is highly desirable for clean energy and fuel conversion. Herein, the facile preparation of Ni single atoms embedded hollow S/N-doped carbon macroporous fibers (Ni SAs@S/N-CMF) as efficient catalysts for OER through pyrolysis of designed CdS-NiSx/polyacrylonitrile composite fibers is reported. Specifically, CdS provides the sulfur source for the doping of polyacrylonitrile-derived carbon matrix and simultaneously creates the hollow macroporous structure, while NiSx is first reduced to nulloparticles and finally evolves into single Ni atoms through the atom migration-trapping strategy. Benefiting from the abundantly exposed single Ni atoms and hollow macroporous structure, the resultant Ni SAs@S/N-CMF electrocatalysts deliver outstanding activity and stability for OER. Specifically, it needs an overpotential of 285 mV to achieve the benchmark current density of 10 mA cm(-2) with a small Tafel slope of 50.8 mV dec(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 34, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203442, "DOI": "10.1002/adma.202203442", "DOI Link": "http://dx.doi.org/10.1002/adma.202203442", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000832660900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Hong, XP; Jin, CH; Shi, SF; Chang, CYS; Chiu, MH; Li, LJ; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jonghwan; Hong, Xiaoping; Jin, Chenhao; Shi, Su-Fei; Chang, Chih-Yuan S.; Chiu, Ming-Hui; Li, Lain-Jong; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast generation of pseudo-magnetic field for valley excitons in WSe2 monolayers", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The valley pseudospin is a degree of freedom that emerges in atomically thin two-dimensional transition metal dichalcogenides (MX2). The capability to manipulate it, in analogy to the control of spin in spintronics, can open up exciting opportunities. Here, we demonstrate that an ultrafast and ultrahigh valley pseudo-magnetic field can be generated by using circularly polarized femtosecond pulses to selectively control the valley degree of freedom in monolayer MX2. Using ultrafast pump-probe spectroscopy, we observed a pure and valley-selective optical Stark effect in WSe2 monolayers from the nonresonullt pump, resulting in an energy splitting of more than 10 milli-electron volts between the K and K' valley exciton transitions. Our study opens up the possibility to coherently manipulate the valley polarization for quantum information applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 346, "Issue": 6214, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1205, "End Page": 1208, "Article Number": null, "DOI": "10.1126/science.1258122", "DOI Link": "http://dx.doi.org/10.1126/science.1258122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346189000051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rothmann, MU; Kim, JS; Borchert, J; Lohmann, KB; O'Leary, CM; Sheader, AA; Clark, L; Snaith, HJ; Johnston, MB; Nellist, PD; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rothmann, Mathias Uller; Kim, Judy S.; Borchert, Juliane; Lohmann, Kilian B.; O'Leary, Colum M.; Sheader, Alex A.; Clark, Laura; Snaith, Henry J.; Johnston, Michael B.; Nellist, Peter D.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-scale microstructure of metal halide perovskite", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic perovskites have high potential as materials for solar energy applications, but their microscopic properties are still not well understood. Atomic-resolution scanning transmission electron microscopy has provided invaluable insights for many crystalline solar cell materials, and we used this method to successfully image formamidinium lead triiodide [CH(NH2)(2)Pbl(3)] thin films with a low dose of electron irradiation. Such images reveal a highly ordered atomic arrangement of sharp grain boundaries and coherent perovskite/Pbl(2) interfaces, with a striking absence of long-range disorder in the crystal. We found that beam-induced degradation of the perovskite leads to an initial loss of formamidinium [CH(NH2)(2)] ions, leaving behind a partially unoccupied perovskite lattice, which explains the unusual regenerative properties of these materials. We further observed aligned point defects and climb-dissociated dislocations. Our findings thus provide an atomic-level understanding of technologically important lead halide perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 30", "Publication Year": 2020, "Volume": 370, "Issue": 6516, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 548, "End Page": "+", "Article Number": "eabb5940", "DOI": "10.1126/science.abb5940", "DOI Link": "http://dx.doi.org/10.1126/science.abb5940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000583031800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Keum, D; Kim, SK; Koo, J; Lee, GH; Jeon, C; Mok, JW; Mun, BH; Lee, KJ; Kamrani, E; Joo, CK; Shin, S; Sim, JY; Myung, D; Yun, SH; Bao, ZN; Hahn, SK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Keum, Do Hee; Kim, Su-Kyoung; Koo, Jahyun; Lee, Geon-Hui; Jeon, Cheonhoo; Mok, Jee Won; Mun, Beom Ho; Lee, Keon Jae; Kamrani, Ehsan; Joo, Choun-Ki; Shin, Sangbaie; Sim, Jae-Yoon; Myung, David; Yun, Seok Hyun; Bao, Zhenull; Hahn, Sei Kwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wireless smart contact lens for diabetic diagnosis and therapy", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A smart contact lens can be used as an excellent interface between the human body and an electronic device for wearable healthcare applications. Despite wide investigations of smart contact lenses for diagnostic applications, there has been no report on electrically controlled drug delivery in combination with real-time biometric analysis. Here, we developed smart contact lenses for both continuous glucose monitoring and treatment of diabetic retinopathy. The smart contact lens device, built on a biocompatible polymer, contains ultrathin, flexible electrical circuits and a microcontroller chip for real-time electrochemical biosensing, on-demand controlled drug delivery, wireless power management, and data communication. In diabetic rabbit models, we could measure tear glucose levels to be validated by the conventional invasive blood glucose tests and trigger drugs to be released from reservoirs for treating diabetic retinopathy. Together, we successfully demonstrated the feasibility of smart contact lenses for noninvasive and continuous diabetic diagnosis and diabetic retinopathy therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba3252", "DOI": "10.1126/sciadv.aba3252", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba3252", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530628100044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, K; Smulders, LCJ; van der Wal, LI; Oenema, J; Meeldijk, JD; Visser, NL; Sunley, G; Roberts, T; Xu, ZR; Doskocil, E; Yoshida, H; Zheng, YP; Zecevic, J; de Jongh, PE; de Jong, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Kang; Smulders, Luc C. J.; van der Wal, Lars, I; Oenema, Jogchum; Meeldijk, Johannes D.; Visser, Nienke L.; Sunley, Glenn; Roberts, Tegan; Xu, Zhuoran; Doskocil, Eric; Yoshida, Hideto; Zheng, Yanping; Zecevic, Jovana; de Jongh, Petra E.; de Jong, Krijn P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Maximizing noble metal utilization in solid catalysts by control of nulloparticle location", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Maximizing the utilization of noble metals is crucial for applications such as catalysis. We found that the minimum loading of platinum for optimal performance in the hydroconversion of n-alkanes for industrially relevant bifunctional catalysts could be reduced by a factor of 10 or more through the rational arranging of functional sites at the nulloscale. Intentionally depositing traces of platinum nulloparticles on the alumina binder or the outer surface of zeolite crystals, instead of inside the zeolite crystals, enhanced isomer selectivity without compromising activity. Separation between platinum and zeolite acid sites preserved the metal and acid functions by limiting micropore blockage by metal clusters and enhancing access to metal sites. Reduced platinum nulloparticles were more active than platinum single atoms strongly bonded to the alumina binder.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 8", "Publication Year": 2022, "Volume": 377, "Issue": 6602, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn8289", "DOI Link": "http://dx.doi.org/10.1126/science.abn8289", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822228900044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, TJ; Li, N; Wang, LL; Ran, WG; Duchesne, PN; Wan, LL; Nguyen, NT; Wang, L; Xia, MK; Ozin, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Tingjiang; Li, Na; Wang, Linlin; Ran, Weiguang; Duchesne, Paul N.; Wan, Lili; Nhat Truong Nguyen; Wang, Lu; Xia, Meikun; Ozin, Geoffrey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuth atom tailoring of indium oxide surface frustrated Lewis pairs boosts heterogeneous CO2 photocatalytic hydrogenation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface frustrated Lewis pairs (SFLPs) on defect-laden metal oxides provide catalytic sites to activate H-2 and CO2 molecules and enable efficient gas-phase CO2 photocatalysis. Lattice engineering of metal oxides provides a useful strategy to tailor the reactivity of SFLPs. Herein, a one-step solvothermal synthesis is developed that enables isomorphic replacement of Lewis acidic site In3+ ions in In2O3 by single-site Bi3+ ions, thereby enhancing the propensity to activate CO2 molecules. The so-formed BixIn2-xO3 materials prove to be three orders of magnitude more photoactive for the reverse water gas shift reaction than In2O3 itself, while also exhibiting notable photoactivity towards methanol production. The increased solar absorption efficiency and efficient charge-separation and transfer of BixIn2-xO3 also contribute to the improved photocatalytic performance. These traits exemplify the opportunities that exist for atom-scale engineering in heterogeneous CO2 photocatalysis, another step towards the vision of the solar CO2 refinery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6095, "DOI": "10.1038/s41467-020-19997-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19997-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617694400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tu, WG; Xu, Y; Wang, JJ; Zhang, BW; Zhou, TH; Yin, SM; Wu, SY; Li, CM; Huang, YZ; Zhou, Y; Zou, ZG; Robertson, J; Kraft, M; Xu, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tu, Wenguang; Xu, You; Wang, Jiajia; Zhang, Bowei; Zhou, Tianhua; Yin, Shengming; Wu, Shuyang; Li, Chunmei; Huang, Yizhong; Zhou, Yong; Zou, Zhigang; Robertson, John; Kraft, Markus; Xu, Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigating the Role of Tunable Nitrogen Vacancies in Graphitic Carbon Nitride nullosheets for Efficient Visible-Light-Driven H2 Evolution and CO2 Reduction", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vacancy engineering, that is, self-doping of vacancy in semiconductors, has become a commonly used strategy to tune the photocatalytic performances. However, there still lacks fundamental understanding of the role of the vacancies in semiconductor materials. Herein, the g-C3N4 nullosheets with tunable nitrogen vacancies are prepared as the photocatalysts for H-2 evolution and CO2 reduction to CO. On the basis of both experimental investigation and DFT calculations, nitrogen vacancies in g-C3N4 induce the formation of midgap states under the conduction band edge, The position of midgap states becomes deeper with the increasing of nitrogen vacancies. The g-C3N4 nullosheets with the optimized density of nitrogen vacancies display about 18 times and 4 times enhancement for H-2 evolution and of CO2 reduction to CO, respectively, as compared to the bulk g-C3N4. This is attributed to the synergistic effects of several factors including (1) nitrogen vacancies cause the excitation of electrons to midgap states below the conduction band edge, which results in extension of the visible light absorption to photons of longer wavelengths (up to 598 nm); (2) the suitable midgap states could trap photogenerated electrons to minimize the recombination loss of photogenerated electron hole pairs; and (3) nitrogen vacancies lead to uniformly anchored small Pt nulloparticles (1-2 nm) on g-C3N4, and facilitate the electron transfer to Pt. However, the overintroduction of nitrogen vacancies generates deeper midgap states as the recombination centers, which results in deterioration of photocatalytic activities. Our work is expected to provide new insights for fabrication of nullomaterials with suitable vacancies for solar fuel generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7260, "End Page": 7268, "Article Number": null, "DOI": "10.1021/acssuschemeng.7b01477", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.7b01477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407410900099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raghavan, N; Dehoff, R; Pannala, S; Simunovic, S; Kirka, M; Turner, J; Carlson, N; Babu, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raghavan, Narendran; Dehoff, Ryan; Pannala, Sreekanth; Simunovic, Srdjan; Kirka, Michael; Turner, John; Carlson, Neil; Babu, Sudarsanam S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical modeling of heat-transfer and the influence of process parameters on tailoring the grain morphology of IN718 in electron beam additive manufacturing", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fabrication of 3-D parts from CAD models by additive manufacturing (AM) is a disruptive technology that is transforming the metal manufacturing industry. The correlation between solidification microstructure and mechanical properties has been well understood in the casting and welding processes over the years. This paper focuses on extending these principles to additive manufacturing to understand the transient phenomena of repeated melting and solidification during electron beam powder melting process to achieve site-specific microstructure control within a fabricated component. In this paper, we have developed a novel melt scan strategy for electron beam melting of nickel-base superalloy (Inconel 718) and also analyzed 3-D heat transfer conditions using a parallel numerical solidification code (Truchas) developed at Los Alamos National Laboratory. The spatial and temporal variations of temperature gradient (G) and growth velocity (R) at the liquid-solid interface of the melt pool were calculated as a function of electron beam parameters. By manipulating the relative number of voxels that lie in the columnar or equiaxed region, the crystallographic texture of the components can be controlled to an extent. The analysis of the parameters provided optimum processing conditions that will result in columnar to equiaxed transition (CET) during the solidification. The results from the numerical simulations were validated by experimental processing and characterization thereby proving the potential of additive manufacturing process to achieve site-specific crystallographic texture control within a fabricated component. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2016, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 303, "End Page": 314, "Article Number": null, "DOI": "10.1016/j.actamat.2016.03.063", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.03.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377326400029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, R; Sun, XY; Yuan, B; Wang, HZ; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Rui; Sun, Xuyang; Yuan, Bo; Wang, Hongzhang; Liu, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic Liquid Metal (Fe-EGaIn) Based Multifunctional Electronics for Remote Self-Healing Materials, Degradable Electronics, and Thermal Transfer Printing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible materials with the ability to be bent, strained, or twisted play a critical role in soft robots and stretchable electronics. Although tremendous efforts are focused on developing new stretchable materials with excellent stability, inevitable mechanical damage due to long term deformation is still an urgent problem to be tackled. Here, a magnetic healing method based on Fe-doped liquid metal (Fe-GaIn) conductive ink via a noncontact way is proposed. Further, multifunctional flexible electronics are designed with combined performances of superior remote self-healing under magnetic field, water-degradable, and thermal transfer printing, which attribute to three parts of the materials including Fe-GaIn conductive ink, degradable PVA substrate, and adhesive fructose. The as-made light emitting diodes (LED) circuit is demonstrated with both structural and functional repairing after single or multipoint damage. The self-healing time from multipoint damage is pretty fast within 10 s. Due to the water-soluble PVA film, the recycling process is simple via immersing into water. Through heating, the electric circuit on fructose can be transferred to other flexible substrate with high efficiency, which broadens the practical applications of the present system. The novel and multifunctional electronics hold great promise for self-healing electronics, transient electronics, and soft robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 6, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901478, "DOI": "10.1002/advs.201901478", "DOI Link": "http://dx.doi.org/10.1002/advs.201901478", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482411800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, T; Wang, PF; Wang, QC; Zhu, KJ; Deng, T; Zhang, JX; Zhang, W; Yang, XQ; Jiao, LF; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Ting; Wang, Peng-Fei; Wang, Qin-Chao; Zhu, Kunjie; Deng, Tao; Zhang, Jiaxun; Zhang, Wei; Yang, Xiao-Qing; Jiao, Lifang; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing Complete Solid-Solution Reaction in High Sodium Content P2-Type Cathode for High-Performance Sodium-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "P2-type layered oxides suffer from an ordered Na+/vacancy arrangement and P2 -> O2/OP4 phase transitions, leading them to exhibit multiple voltage plateaus upon Na(+)extraction/insertion. The deficient sodium in the P2-type cathode easily induces the bad structural stability at deep desodiation states and limited reversible capacity during Na(+)de/insertion. These drawbacks cause poor rate capability and fast capacity decay in most P2-type layered oxides. To address these challenges, a novel high sodium content (0.85) and plateau-free P2-type cathode-Na0.85Li0.12Ni0.22Mn0.66O2(P2-NLNMO) was developed. The complete solid-solution reaction over a wide voltage range ensures both fast Na(+)mobility (10(-11)to 10(-10) cm(2) s(-1)) and small volume variation (1.7 %). The high sodium content P2-NLNMO exhibits a higher reversible capacity of 123.4 mA h g(-1), superior rate capability of 79.3 mA h g(-1)at 20 C, and 85.4 % capacity retention after 500 cycles at 5 C. The sufficient Na and complete solid-solution reaction are critical to realizing high-performance P2-type cathodes for sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2020, "Volume": 59, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14511, "End Page": 14516, "Article Number": null, "DOI": "10.1002/anie.202003972", "DOI Link": "http://dx.doi.org/10.1002/anie.202003972", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546418600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, QF; Yang, HB; Han, ZM; Zhou, LC; Zhu, YB; Ling, ZC; Jiang, HB; Wang, PF; Ma, T; Wu, HA; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Qing-Fang; Yang, Huai-Bin; Han, Zi-Meng; Zhou, Li-Chuan; Zhu, Yin-Bo; Ling, Zhang-Chi; Jiang, He-Bin; Wang, Peng-Fei; Ma, Tao; Wu, Heng-An; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, tough, and sustainable cellulose nullofiber-derived bulk structural materials with low thermal expansion coefficient", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable structural materials with light weight, great thermal dimensional stability, and superb mechanical properties are vitally important for engineering application, but the intrinsic conflict among some material properties (e.g., strength and toughness) makes it challenging to realize these performance indexes at the same time under wide service conditions. Here, we report a robust and feasible strategy to process cellulose nullofiber (CNF) into a high-performance sustainable bulk structural material with low density, excellent strength and toughness, and great thermal dimensional stability. The obtained cellulose nullofiber plate (CNFP) has high specific strength [similar to 198 MPa/(Mg m(-3))], high specific impact toughness [similar to 67 kJ m(-2)/(Mg m(-3))], and low thermal expansion coefficient (<5 x 10(-6) K-1), which shows distinct and superior properties to typical polymers, metals, and ceramics, making it a low-cost, high-performance, and environmental-friendly alternative for engineering requirement, especially for aerospace applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz1114", "DOI": "10.1126/sciadv.aaz1114", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz1114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531089700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qazvini, OT; Babarao, R; Telfer, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qazvini, Omid T.; Babarao, Ravichandar; Telfer, Shane G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective capture of carbon dioxide from hydrocarbons using a metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient and sustainable methods for carbon dioxide capture are highly sought after. Mature technologies involve chemical reactions that absorb CO2, but they have many drawbacks. Energy-efficient alternatives may be realised by porous physisorbents with void spaces that are complementary in size and electrostatic potential to molecular CO2. Here, we present a robust, recyclable and inexpensive adsorbent termed MUF-16. This metal-organic framework captures CO2 with a high affinity in its one-dimensional channels, as determined by adsorption isotherms, X-ray crystallography and density-functional theory calculations. Its low affinity for other competing gases delivers high selectivity for the adsorption of CO2 over methane, acetylene, ethylene, ethane, propylene and propane. For equimolar mixtures of CO2/CH4 and CO2/C2H2, the selectivity is 6690 and 510, respectively. Breakthrough gas separations under dynamic conditions benefit from short time lags in the elution of the weakly-adsorbed component to deliver high-purity hydrocarbon products, including pure methane and acetylene. Metal-organic framework adsorbents are promising materials for gas separation and purification. Herein, the authors present a metal-organic framework that selectively captures CO2 over small hydrocarbons; this separation is relevant for the purification of natural gas and industrial feedstocks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 197, "DOI": "10.1038/s41467-020-20489-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20489-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626605500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, J; Kramer, M; Zhou, L; Liu, F; Gabay, A; Hadjipanayis, G; Balasubramanian, B; Sellmyer, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Jun; Kramer, Matthew; Zhou, Lin; Liu, Fei; Gabay, Alexander; Hadjipanayis, George; Balasubramanian, Balamurugan; Sellmyer, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current progress and future challenges in rare-earth-free permanent magnets", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Permanent magnets (PM) are critical components for electric motors and power generators. Key properties of permanent magnets, especially coercivity and remanent magnetization, are strongly dependent on microstructure. Understanding metallurgical processing, phase stability and microstructural changes are essential for designing and improving permanent magnets. The widely used PM for the traction motor in electric vehicles and for the power generator in wind turbines contain rare earth elements Nd and Dy due to their high maximum energy product. Dy is used to sustain NdFeB's coercivity at higher temperature. Due to the high supply risk of rare earth elements (REE) such as Dy and Nd, these elements are listed as critical materials by the U.S. Department of Energy and other international institutes. Other than Dy, finer grain size is also found to have effect on sustaining coercivity at higher temperature. A proper control of phase stability and microstructures has direct impact on mitigating REE supply risk. Compared to rare earth PMs, non-rare earth (non-RE) PMs typically have lower maximum energy products, however, given their small supply risks and low cost, they are being intensively investigated for less-demanding applications. The general goal for the development of non-RE PMs is to fill in the gap between the most cost-effective but low performing hard ferrite magnet and the most expensive but high performing RE PMs. In the past five years great progress has been made toward improving the microstructure and physical properties of non-RE PMs. Several new candidate materials systems were investigated, and some have showed realistic potential for replacing RE PMs for some applications. In this article, we review the science and technology of various types of non-RE materials for PM applications. These materials systems include Mn based, high magnetocrystalline anisotropy alloys (MnBi and MnAl compounds), spinodally decomposing alloys (Alnico), high-coercivity tetrataenite L1(o) phase (FeNi and FeCo), and nitride/carbide systems (such as alpha '' based, high saturation magnetization Fe16N2 type phase and Co2C/Co3C acicular particle phase). The current status, challenges, potentials as well as the future directions for these candidates non-RE magnet materials are discussed. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2018, "Volume": 158, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 118, "End Page": 137, "Article Number": null, "DOI": "10.1016/j.actamat.2018.07.049", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.07.049", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444667600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YB; Li, Q; Hong, H; Yang, S; Zhang, R; Wang, XQ; Jin, X; Xiong, B; Bai, SC; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yanbo; Li, Qing; Hong, Hu; Yang, Shuo; Zhang, Rong; Wang, Xiaoqi; Jin, Xu; Xiong, Bo; Bai, Shengchi; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lean-water hydrogel electrolyte for zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid polymer electrolytes (SPEs) and hydrogel electrolytes were developed as electrolytes for zinc ion batteries (ZIBs). Hydrogels can retain water molecules and provide high ionic conductivities; however, they contain many free water molecules, inevitably causing side reactions on the zinc anode. SPEs can enhance the stability of anodes, but they typically possess low ionic conductivities and result in high impedance. Here, we develop a lean water hydrogel electrolyte, aiming to balance ion transfer, anode stability, electrochemical stability window and resistance. This hydrogel is equipped with a molecular lubrication mechanism to ensure fast ion transportation. Additionally, this design leads to a widened electrochemical stability window and highly reversible zinc plating/ stripping. The full cell shows excellent cycling stability and capacity retentions at high and low current rates, respectively. Moreover, superior adhesion ability can be achieved, meeting the needs of flexible devices. Excess water in hydrogel-based zinc ion batteries causes side reactions, but reduced water content results in low conductivities. Here, authors develop a lean-water hydrogel based on molecular lubrication mechanism for fast ion transportation, extended stability, and reversible Zinc plating/stripping.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3890, "DOI": "10.1038/s41467-023-39634-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39634-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022536900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, YC; Yuan, YB; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Yuchuan; Yuan, Yongbo; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlation of energy disorder and open-circuit voltage in hybrid perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometal trihalide perovskites have been demonstrated as excellent light absorbers for high-effciency photovoltaic applications. Previous approaches to increasing the solar cell efficiency have focused on optimization of the grain morphology of perovskite thin films. Here, we show that the structural order of the electron transport layers also has a significant impact on solar cell performance. We demonstrate that the power conversion efficiency of CH3NH3PbI3 planar heterojunction photovoltaic cells increases from 17.1 to 19.4% when the energy disorder in the fullerene electron transport layer is reduced by a simple solvent annealing process. The increase in efficiency is the result of the enhancement in open-circuit voltage from 1.04 to 1.13V without sacrificing the short-circuit current and fill factor. These results shed light on the origin of open-circuit voltage in perovskite solar cells, and provide a path to further increase their efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 566, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15001, "DOI": "10.1038/NENERGY.2015.1", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2015.1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394094100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Y; Peng, R; Hensley, DK; Bonnesen, PV; Liang, LB; Wu, ZL; Meyer, HM; Chi, MF; Ma, C; Sumpter, BG; Rondinone, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Yang; Peng, Rui; Hensley, Dale K.; Bonnesen, Peter V.; Liang, Liangbo; Wu, Zili; Meyer, Harry M., III; Chi, Miaofang; Ma, Cheng; Sumpter, Bobby G.; Rondinone, Adam J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper nulloparticle/N-Doped Graphene Electrode", "Source Title": "CHEMISTRYSELECT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though carbon dioxide is a waste product of combustion, it can also be a potential feedstock for the production of fine and commodity organic chemicals provided that an efficient means to convert it to useful organic synthons can be developed. Herein we report a common element, nullostructured catalyst for the direct electrochemical conversion of CO2 to ethanol with high Faradaic efficiency (63% at 1.2 V vs RHE) and high selectivity (84%) that operates in water and at ambient temperature and pressure. Lacking noble metals or other rare or expensive materials, the catalyst is comprised of Cu nulloparticles on a highly textured, N-doped carbon nullospike film. Electro-chemical analysis and density functional theory (DFT) calculations suggest a preliminary mechanism in which active sites on the Cu nulloparticles and the carbon nullospikes work in tandem to control the electrochemical reduction of carbon monoxide dimer to alcohol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2016, "Volume": 1, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6055, "End Page": 6061, "Article Number": null, "DOI": "10.1002/slct.201601169", "DOI Link": "http://dx.doi.org/10.1002/slct.201601169", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395432100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JX; Zhang, Q; Sheng, JZ; Liang, Z; Ma, J; Chen, YM; Zhou, GM; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Junxiong; Zhang, Qi; Sheng, Jinzhi; Liang, Zheng; Ma, Jun; Chen, Yuanmao; Zhou, Guangmin; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct and green repairing of degraded LiCoO2 for reuse in lithium-ion batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work provides a novel direct recycling method based on a sustainable lithium-containing deep eutectic solvent to regenerate degraded cathode materials of spent lithium-ion batteries. Traditional recycling processes of LiCoO2 rely on destructive decomposition, requiring high-temperature roasting or acid leaching to extract valuable Li and Co, which have significant environmental and economic concerns. Herein, a direct repairing method for degraded LiCoO2 using a LiCl-CH4N2O deep eutectic solvent (DES) was established. The DES is not used to dissolve LiCoO2 but directly serves as a carrier for the selective replenishment of lithium and cobalt. Replenishment of lithium restores LiCoO2 at different states of charge to a capacity of 130 mAh/g (at 0.1 C rate), while replenishing the cobalt increases the capacity retention rate of 90% after 100 cycles, which is comparable to pristine LiCoO2. The DES is collected and reused multiple times with a high repair efficiency. This process reduces energy consumption by 37.1% and greenhouse gas emissions by 34.8% compared with the current production process of LiCoO2, demonstrating excellent environmental and economic viability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1093/nsr/nwac097", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac097", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000825807200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Li, LH; Sun, HW; Xu, Y; Wang, XW; Luo, H; Liu, Z; Zhang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tie; Li, Lianhui; Sun, Hongwei; Xu, Yan; Wang, Xuewen; Luo, Hui; Liu, Zheng; Zhang, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Ionic Membrane Based Flexible Humidity Sensor and its Multifunctional Applications", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A highly flexible porous ionic membrane (PIM) is fabricated from a polyvinyl alcohol/KOH polymer gel electrolyte, showing well-defined 3D porous structure. The conductance of the PIM changes more than 70 times as the relative humidity (RH) increases from 10.89% to 81.75% with fast and reversible response at room temperature. In addition, the PIM-based sensor is insensitive to temperature (0-95 degrees C) and pressure (0-6.8 kPa) change, which indicates that it can be used as highly selective flexible humidity sensor. A noncontact switch system containing PIM-based sensor is assembled, and results show that the switch responds favorably to RH change caused by an approaching finger. Moreover, an attachable smart label using PIM-based sensor is explored to measure the water contents of human skin, which shows a great linear relationship between the sensitivity of the sensor and the facial water contents measured by a commercial reference device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600404, "DOI": "10.1002/advs.201600404", "DOI Link": "http://dx.doi.org/10.1002/advs.201600404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402740300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, J; Al-Salihy, A; Wang, J; Li, X; Fu, YF; Li, ZH; Han, XJ; Song, B; Xu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Jing; Al-Salihy, Adel; Wang, Jing; Li, Xue; Fu, Yanfei; Li, Zhonghua; Han, Xijiang; Song, Bo; Xu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved Interface Charge Transfer and Redistribution in CuO-CoOOH p-n Heterojunction nulloarray Electrocatalyst for Enhanced Oxygen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron density modulation is of great importance in an attempt to achieve highly active electrocatalysts for the oxygen evolution reaction (OER). Here, the successful construction of CuO@CoOOH p-n heterojunction (i.e., p-type CuO and n-type CoOOH) nulloarray electrocatalyst through an in situ anodic oxidation of CuO@CoSx on copper foam is reported. The p-n heterojunction can remarkably modify the electronic properties of the space-charge region and facilitate the electron transfer. Moreover, in situ Raman study reveals the generation of SO42- from CoSx oxidation, and electron cloud density distribution and density functional theory calculation suggest that surface-adsorbed SO42- can facilitate the OER process by enhancing the adsorption of OH-. The positively charged CoOOH in the space-charge region can significantly enhance the OER activity. As a result, the CuO@CoOOH p-n heterojunction shows significantly enhanced OER performance with a low overpotential of 186 mV to afford a current density of 10 mA cm(-2). The successful preparation of a large scale (14 x 25 cm(2)) sample demonstrates the possibility of promoting the catalyst to industrial-scale production. This study offers new insights into the design and fabrication of non-noble metal-based p-n heterojunction electrocatalysts as effective catalytic materials for energy storage and conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 8, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103314, "DOI": "10.1002/advs.202103314", "DOI Link": "http://dx.doi.org/10.1002/advs.202103314", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000706548700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schaffner, M; Faber, JA; Pianegonda, L; Rühs, PA; Coulter, F; Studart, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schaffner, Manuel; Faber, Jakob A.; Pianegonda, Lucas; Ruhs, Patrick A.; Coulter, Fergal; Studart, Andre R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of robotic soft actuators with programmable bioinspired architectures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft actuation allows robots to interact safely with humans, other machines, and their surroundings. Full exploitation of the potential of soft actuators has, however, been hindered by the lack of simple manufacturing routes to generate multimaterial parts with intricate shapes and architectures. Here, we report a 3D printing platform for the seamless digital fabrication of pneumatic silicone actuators exhibiting programmable bioinspired architectures and motions. The actuators comprise an elastomeric body whose surface is decorated with reinforcing stripes at a well-defined lead angle. Similar to the fibrous architectures found in muscular hydrostats, the lead angle can be altered to achieve elongation, contraction, or twisting motions. Using a quantitative model based on lamination theory, we establish design principles for the digital fabrication of silicone-based soft actuators whose functional response is programmed within the material's properties and architecture. Exploring such programmability enables 3D printing of a broad range of soft morphing structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 878, "DOI": "10.1038/s41467-018-03216-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03216-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426275300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bell, EL; Smithson, R; Kilbride, S; Foster, J; Hardy, FJ; Ramachandran, S; Tedstone, AA; Haigh, SJ; Garforth, AA; Day, PJR; Levy, C; Shaver, MP; Green, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bell, Elizabeth L.; Smithson, Ross; Kilbride, Siobhan; Foster, Jake; Hardy, Florence J.; Ramachandran, Saranarayanull; Tedstone, Aleksander A.; Haigh, Sarah J.; Garforth, Arthur A.; Day, Philip J. R.; Levy, Colin; Shaver, Michael P.; Green, Anthony P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directed evolution of an efficient and thermostable PET depolymerase", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of IsPETase, a hydrolytic enzyme that can deconstruct polyethylene terephthalate) (PET), has sparked great interest in biocatalytic approaches to recycle plastics. Realization of commercial use will require the development of robust engineered enzymes that meet the demands of industrial processes. Although rationally engineered PETases have been described, enzymes that have been experimentally optimized via directed evolution have not previously been reported. Here, we describe an automated, high-throughput directed evolution platform for engineering polymer degrading enzymes. Applying catalytic activity at elevated temperatures as a primary selection pressure, a thermostable IsPETase variant (HotPETase, T-m = 82.5 degrees C) was engineered that can operate at the glass transition temperature of PET. HotPETase can depolymerize semicrystalline PET more rapidly than previously reported PETases and can selectively deconstruct the PET component of a laminated multimaterial. Structural analysis of HotPETase reveals interesting features that have emerged to improve thermotolerance and catalytic performance. Our study establishes laboratory evolution as a platform for engineering useful plastic degrading enzymes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 673, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41929-022-00821-3", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00821-3", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000840817400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XG; Yang, DW; Sun, YH; Li, TS; Zhang, LJ; Yu, LP; Zunger, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin-Gang; Yang, Dongwen; Sun, Yuanhui; Li, Tianshu; Zhang, Lijun; Yu, Liping; Zunger, Alex", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu-In Halide Perovskite Solar Absorbers", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The long-term chemical instability and the presence of toxic Pb in otherwise stellar solar absorber APbX(3) made of organic molecules on the A site and halogens for X have hindered their large-scale commercialization. Previously explored ways to achieve Pb-free halide perovskites involved replacing Pb2+ with other similar M2+ cations in ns(2) electron configuration, e.g., Sn2+ or by Bi3+ (plus Ag+), but unfortunately this showed either poor stability (M = Sn) or weakly absorbing oversized indirect gaps (M = Bi), prompting concerns that perhaps stability and good optoelectronic properties might be contraindicated. Herein, we exploit the electronic structure underpinning of classic Cu[In,Ga]Se-2 (CIGS) chalcopyrite solar absorbers to design Pb-free halide perovskites by transmuting 2Pb to the pair [B-IB + C-III] such as [Cu + Ga] or [Ag + In] and combinations thereof. The resulting group of double perovskites with formula A(2)BCX(6) (A = K, Rb, Cs; B = Cu, Ag; C = Ga, In; X = Cl, Br, I) benefits from the ionic, yet narrow-gap character of halide perovskites, and at the same time borrows the advantage of the strong Cu(d)/Se(p) -> Ga/In(s/p) valence-to-conduction-band absorption spectra known from CIGS. This constitutes a new group of CuIn-based Halide Perovskite (CIHP). Our first principles calculations guided by such design principles indicate that the CIHPs class has members with clear thermodynamic stability, showing direct band gaps, and manifesting a wide-range of tunable gap values (from zero to about 2.5 eV) and combination of light electron and heavy-light hole effective masses. Materials screening of candidate CIHPs then identifies the best-of-class Rb-2[CuIn]Cl-6, Rb-2[AgIn]Br-6, and Cs-2[AgIn]Br-6, having direct band gaps of 1.36, 1.46, and 1.50 eV, and theoretical spectroscopic limited maximal efficiency comparable to chalcopyrites and CH3NH3PbI3. Our finding offers a new routine for designing new-type Pb-free halide perovskite solar absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 139, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6718, "End Page": 6725, "Article Number": null, "DOI": "10.1021/jacs.7b02120", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b02120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401781900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Hu, EY; Jiang, H; Xiang, YJ; Weng, Z; Li, M; Fan, Q; Yu, XQ; Altman, EI; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wen; Hu, Enyuan; Jiang, Hong; Xiang, Yingjie; Weng, Zhe; Li, Min; Fan, Qi; Yu, Xiqian; Altman, Eric I.; Wang, Hailiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly active and stable hydrogen evolution catalyst based on pyrite-structured cobalt phosphosulfide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design and controlled synthesis of hybrid structures comprising multiple components with distinctive functionalities are an intriguing and challenging approach to materials development for important energy applications like electrocatalytic hydrogen production, where there is a great need for cost effective, active and durable catalyst materials to replace the precious platinum. Here we report a structure design and sequential synthesis of a highly active and stable hydrogen evolution electrocatalyst material based on pyrite-structured cobalt phosphosulfide nulloparticles grown on carbon nullotubes. The three synthetic steps in turn render electrical conductivity, catalytic activity and stability to the material. The hybrid material exhibits superior activity for hydrogen evolution, achieving current densities of 10 mA cm(-2) and 100 mA cm(-2) at overpotentials of 48 mV and 109 mV, respectively. Phosphorus substitution is crucial for the chemical stability and catalytic durability of the material, the molecular origins of which are uncovered by X-ray absorption spectroscopy and computational simulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10771, "DOI": "10.1038/ncomms10771", "DOI Link": "http://dx.doi.org/10.1038/ncomms10771", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371039900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Myndrul, V; Coy, E; Babayevska, N; Zahorodna, V; Balitskyi, V; Baginskiy, I; Gogotsi, O; Bechelany, M; Giardi, MT; Iatsunskyi, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Myndrul, Valerii; Coy, Emerson; Babayevska, Nataliya; Zahorodna, Veronika; Balitskyi, Vitalii; Baginskiy, Ivan; Gogotsi, Oleksiy; Bechelany, Mikhael; Giardi, Maria Teresa; Iatsunskyi, Igor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene nulloflakes decorating ZnO tetrapods for enhanced performance of skin-attachable stretchable enzymatic electrochemical glucose sensor", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous painless glucose monitoring is the greatest desire of more than 422 million diabetics worldwide. Therefore, new non-invasive and convenient approaches to glucose monitoring are more in demand than other tests for microanalytical diagnostic tools. Besides, blood glucose detection can be replaced by continuous glucose monitoring of other human biological fluids (e.g. sweat) collected non-invasively. In this study, a skin-attachable and stretchable electrochemical enzymatic sensor based on ZnO tetrapods (TPs) and a new class of 2D materials -transition metal carbides, known as MXene, was developed and their electroanalytical behavior was tailored for continuous detection glucose in sweat. The high specific area of ZnO TPs and superior electrical conductivity of MXene (Ti3C2Tx) nulloflakes enabled to produce enzymatic electrochemical glucose biosensor with enhanced sensitivity in sweat sample (29 mu A mM(-1) cm(-2)), low limit of detection (LOD asymptotic to 17 mu M), broad linear detection range (LDR = 0.05-0.7 mM) that satisfices glucose detection application in human sweat, and advanced mechanical stability (up to 30% stretching) of the template. The developed skin-attachable stretchable electro-chemical electrodes allowed to monitor the level of glucose in sweat while sugar uptake and during physical activity. Continuous in vivo monitoring of glucose in sweat obtained during 60 min correlated well with data collected by a conventional amperometric blood glucometer in vitro mode. Our findings demonstrate the high potential of developed ZnO/MXene skin-attachable stretchable sensors for biomedical applications on a daily basis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 207, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114141, "DOI": "10.1016/j.bios.2022.114141", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2022.114141", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779151400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HW; Sakar, MS; Petruska, AJ; Pané, S; Nelson, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Hen-Wei; Sakar, Mahmut Selman; Petruska, Andrew J.; Pane, Salvador; Nelson, Bradley J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft micromachines with programmable motility and morphology", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature provides a wide range of inspiration for building mobile micromachines that can navigate through confined heterogenous environments and perform minimally invasive environmental and biomedical operations. For example, microstructures fabricated in the form of bacterial or eukaryotic flagella can act as artificial microswimmers. Due to limitations in their design and material properties, these simple micromachines lack multifunctionality, effective addressability and manoeuvrability in complex environments. Here we develop an origami-inspired rapid prototyping process for building self-folding, magnetically powered micromachines with complex body plans, reconfigurable shape and controllable motility. Selective reprogramming of the mechanical design and magnetic anisotropy of body parts dynamically modulates the swimming characteristics of the micromachines. We find that tail and body morphologies together determine swimming efficiency and, unlike for rigid swimmers, the choice of magnetic field can subtly change the motility of soft microswimmers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 587, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12263, "DOI": "10.1038/ncomms12263", "DOI Link": "http://dx.doi.org/10.1038/ncomms12263", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380841900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, Y; Tian, Y; Yang, ZG; Shi, JF; Kwak, KJ; Tong, YH; Estania, AP; Cao, JH; Hsu, WH; Liu, YT; Chiang, CL; Schrank, BR; Huntoon, K; Lee, DY; Li, ZW; Zhao, YR; Zhang, H; Gallup, TD; Ha, J; Dong, SY; Li, XF; Wang, YF; Lu, WJ; Bahrani, E; Lee, LJ; Teng, LS; Jiang, W; Lan, F; Kim, BYS; Lee, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Yi; Tian, Yu; Yang, Zhaogang; Shi, Junfeng; Kwak, Kwang Joo; Tong, Yuhao; Estania, Andreanne Poppy; Cao, Jianhong; Hsu, Wei-Hsiang; Liu, Yutong; Chiang, Chi-Ling; Schrank, Benjamin R.; Huntoon, Kristin; Lee, DaeYong; Li, Ziwei; Zhao, Yarong; Zhang, Huan; Gallup, Thomas D.; Ha, JongHoon; Dong, Shiyan; Li, Xuefeng; Wang, Yifan; Lu, Wen-Jing; Bahrani, Eman; Lee, Ly James; Teng, Lesheng; Jiang, Wen; Lan, Feng; Kim, Betty Y. S.; Lee, Andrew S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intradermally delivered mRNA-encapsulating extracellular vesicles for collagen-replacement therapy", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The success of messenger RNA therapeutics largely depends on the availability of delivery systems that enable the safe, effective and stable translation of genetic material into functional proteins. Here we show that extracellular vesicles (EVs) produced via cellular nulloporation from human dermal fibroblasts, and encapsulating mRNA encoding for extracellular-matrix alpha 1 type-I collagen (COL1A1) induced the formation of collagen-protein grafts and reduced wrinkle formation in the collagen-depleted dermal tissue of mice with photoaged skin. We also show that the intradermal delivery of the mRNA-loaded EVs via a microneedle array led to the prolonged and more uniform synthesis and replacement of collagen in the dermis of the animals. The intradermal delivery of EV-based COL1A1 mRNA may make for an effective protein-replacement therapy for the treatment of photoaged skin.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 887, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41551-022-00989-w", "DOI Link": "http://dx.doi.org/10.1038/s41551-022-00989-w", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913091100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, J; Qiu, BB; Zhang, ZG; Xue, LW; Wang, R; Zhang, CF; Chen, SS; Zhou, QJ; Sun, CK; Yang, C; Xiao, M; Meng, L; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Jia; Qiu, Beibei; Zhang, Zhi-Guo; Xue, Lingwei; Wang, Rui; Zhang, Chunfeng; Chen, Shanshan; Zhou, Qiuju; Sun, Chenkai; Yang, Changduk; Xiao, Min; Meng, Lei; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cathode engineering with perylene-diimide interlayer enabling over 17% efficiency single-junction organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In organic solar cells (OSCs), cathode interfacial materials are generally designed with highly polar groups to increase the capability of lowering the work function of cathode. However, the strong polar group could result in a high surface energy and poor physical contact at the active layer surface, posing a challenge for interlayer engineering to address the trade-off between device stability and efficiency. Herein, we report a hydrogen-bonding interfacial material, aliphatic amine-functionalized perylene-diimide (PDINN), which simultaneously down-shifts the work function of the air stable cathodes (silver and copper), and maintains good interfacial contact with the active layer. The OSCs based on PDINN engineered silver-cathode demonstrate a high power conversion efficiency of 17.23% (certified value 16.77% by NREL) and high stability. Our results indicate that PDINN is an effective cathode interfacial material and interlayer engineering via suitable intermolecular interactions is a feasible approach to improve device performance of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2726, "DOI": "10.1038/s41467-020-16509-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16509-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542983000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, GW; Xu, FY; Cheng, B; Li, YJ; Yu, JG; Zhang, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Gaowei; Xu, Feiyan; Cheng, Bei; Li, Youji; Yu, Jiaguo; Zhang, Liuyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Photocatalytic H2O2 Production over Inverse Opal ZnO@ Polydopamine S-Scheme Heterojunctions", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic H2O2 production is a sustainable and inexpensive process that requires water and gaseous O-2 as raw materials and sunlight as the energy source. However, the slow kinetics of current photocatalysts limits its practical application. ZnO is commonly used as a photocatalytic material in the solar-to-chemical conversion, owing to its high electron mobility, nontoxicity, and relatively low cost. The adsorption capacity of H2O2 on the ZnO surface is low, which leads to the continuous production of H2O2. However, its photoresponse is limited to the ultraviolet (UV) region due to its wide bandgap (3.2 eV). Polydopamine (PDA) has emerged as an effective surface functionalization material in the field of photocatalysis due to its abundant functional groups. PDA can be strongly anchored onto the surface of a semiconducting photocatalyst through covalent and noncovalent bonds. The superior properties of PDA served as a motivation for this study. Herein, we prepare an inverse opal-structured porous PDA-modified ZnO (ZnO@PDA) photocatalyst by in situ self-polymerization of dopamine hydrochloride. The crystal structure, morphology, valency, stability, and energy band structure of photocatalysts are characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), field-emission scanning electron microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS), UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), electrochemical impedance spectroscopy (EIS), Mott-Schottky curve (MS), and electron paramagnetic resonullce (EPR). The experimental results showed that electrons in PDA are transferred to ZnO upon contact, which results in an electric field at their interface in the direction from PDA to ZnO. The photoexcited electrons in the ZnO conduction bands flow into PDA, driven by the electric field and bent bands, and are recombined with the holes of the highest occupied molecular orbital of PDA, thereby exhibiting an S-scheme charge transfer. This unique S-scheme mechanism ensures effective electron/hole separation and preserves the strong redox ability of used photocarriers. In addition, the inverse opal structure of ZnO@PDA promotes light- harvesting due to the supposed slow photon effect, as well as Bragg diffraction and scattering. Moreover, the enhanced surface area provides a high adsorption capacity and increased active sites for photocatalytic reactions. Therefore, the resulting ZnO@PDA (0.03% (atomic fraction) PDA) exhibits the optimal H2O2 production performance (1011.4 mu mol.L-1.h(-1)), which is 4.4 and 8.9 times higher than pristine ZnO and PDA, respectively. The enhanced performance is ascribed to the improved light absorption, efficient charge separation, and strong redox capability of photocarriers in the S-scheme heterojunction. Therefore, this study provides a novel strategy for the design of inorganic/organic S-scheme heterojunctions for efficient photocatalytic H2O2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 38, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2112037, "DOI": "10.3866/PKU.WHXB202112037", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202112037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760791100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, YH; Xu, L; Li, M; Yuan, D; Liu, XH; Qian, JC; Dou, YH; Qiu, JX; Zhang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Yuhui; Xu, Li; Li, Meng; Yuan, Ding; Liu, Xianhu; Qian, Junchao; Dou, Yuhai; Qiu, Jingxia; Zhang, Shanqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of CoS/CoO@N-Doped Graphene nullocomposite for High-Performance Rechargeable Zn-Air Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsInterface engineering of heterogeneous CoS/CoO nullocrystals and N-doped graphene composite facilitates high-performance oxygen reduction reaction and oxygen evolution reaction.Density functional theory calculations and experimental results confirm the enhanced electrocatalytic performances via the proposed interface engineering.The bifunctional oxygen electrocatalyst exhibits excellent performances in rechargeable Zn-air batteries. AbstractLow cost and green fabrication of high-performance electrocatalysts with earth-abundant resources for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are crucial for the large-scale application of rechargeable Zn-air batteries (ZABs). In this work, our density functional theory calculations on the electrocatalyst suggest that the rational construction of interfacial structure can induce local charge redistribution, improve the electronic conductivity and enhance the catalyst stability. In order to realize such a structure, we spatially immobilize heterogeneous CoS/CoO nullocrystals onto N-doped graphene to synthesize a bifunctional electrocatalyst (CoS/CoO@NGNs). The optimization of the composition, interfacial structure and conductivity of the electrocatalyst is conducted to achieve bifunctional catalytic activity and deliver outstanding efficiency and stability for both ORR and OER. The aqueous ZAB with the as-prepared CoS/CoO@NGNs cathode displays a high maximum power density of 137.8 mW cm(-2), a specific capacity of 723.9 mAh g(-1) and excellent cycling stability (continuous operating for 100 h) with a high round-trip efficiency. In addition, the assembled quasi-solid-state ZAB also exhibits outstanding mechanical flexibility besides high battery performances, showing great potential for applications in flexible and wearable electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3, "DOI": "10.1007/s40820-020-00526-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00526-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591376600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SB; Hu, QK; Zhang, YX; Guo, HY; Wu, YF; Sun, MZ; Zhu, XS; Zhang, JA; Gong, SY; Liu, P; Niu, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shengbo; Hu, Qikun; Zhang, Yu-Xiao; Guo, Haoyue; Wu, Yanfen; Sun, Mingze; Zhu, Xingsong; Zhang, Jiangang; Gong, Shuyan; Liu, Ping; Niu, Zhiqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Depolymerization of polyesters by a binuclear catalyst for plastic recycling", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics play an essential role in modern society; however, the relentless growth of their production is threatening both human health and ecosystems. As a result, there are intensive efforts in developing recycling technologies to repurpose waste plastics into the building blocks for valuable materials. Here we show a binuclear complex that can catalyse the degradation of poly(ethylene terephthalate) (PET)-the most widely used polyester globally-and a wide spectrum of other plastics including polylactic acid, polybutylene adipate terephthalate, polycaprolactone, polyurethane and Nylon 66. Inspired by hydrolases, the group of enzymes that catalyse bond cleavages with water, the present catalyst design features biomimetic Zn-Zn sites that activate the plastic, stabilize the key intermediate and enable intramolecular hydrolysis. This synthetic catalyst delivers an activity of 36 mg(PET) d(-1) g(catal)(-1) toward PET depolymerization at pH 8 and 40 degrees C and an activity of 577 g(PET) d(-1) g(catal)(-1) at pH 13 and 90 degrees C for scalable PET recycling. We further demonstrate a closed-loop production of bottle-grade PET. This work presents a practical and viable solution for the sustainable management of plastics waste. Plastic pollution forms a major global challenge to the ecosystem. Here the authors show a binuclear catalyst that could degrade various polyesters in an effective and scalable way, providing a promising technological solution to the challenge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 965, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41893-023-01118-4", "DOI Link": "http://dx.doi.org/10.1038/s41893-023-01118-4", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979959800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, FY; Meng, K; Cao, S; Jiang, CH; Chen, T; Xu, JS; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Feiyan; Meng, Kai; Cao, Shuang; Jiang, Chenhui; Chen, Tao; Xu, Jingsan; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Step-by-Step Mechanism Insights into the TiO2/Ce2S3 S-Scheme Photocatalyst for Enhanced Aniline Production with Water as a Proton Source", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring heterostructured photocatalysts for the photocatalytic hydrogenation reaction with water as a proton source and investigating the corresponding intrinsic step-by-step mechanism are of great interest. Here, we develop an S-scheme heterojunction through theoretical design and carried out solvothermal growth of Ce2S3 nulloparticles (NPs) onto electrospun TiO2 nullofibers. The low-dimensional (0D/1D) heterostructure unveils enhanced photocatalytic activity for aniline production by nitrobenzene hydrogenation with water as a proton source. Density functional theory (DFT) calculations indicate the electrons transfer from Ce2S3 to TiO2 upon hybridization due to their Fermi level difference and creates an internal electric field at the interface, driving the separation of the photoexcited charge carriers, which is authenticated by in situ X-ray photoelectron spectroscopy along with femtosecond transient absorption spectroscopy. The step-by-step reaction mechanism of the photocatalytic nitrobenzene hydrogenation to yield aniline is revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy, associated with DFT computational prediction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 164, "End Page": 172, "Article Number": null, "DOI": "10.1021/acscatal.1c04903", "DOI Link": "http://dx.doi.org/10.1021/acscatal.1c04903", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731980100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Menezes, PW; Yao, SL; Beltrán-Suito, R; Hausmann, JN; Menezes, PV; Driess, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Menezes, Prashanth W.; Yao, Shenglai; Beltran-Suito, Rodrigo; Hausmann, J. Niklas; Menezes, Pramod V.; Driess, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile Access to an Active γ-NiOOH Electrocatalyst for Durable Water Oxidation Derived From an Intermetallic Nickel Germanide Precursor", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identifying novel classes of precatalysts for the oxygen evolution reaction (OER by water oxidation) with enhanced catalytic activity and stability is a key strategy to enable chemical energy conversion. The vast chemical space of intermetallic phases offers plenty of opportunities to discover OER electrocatalysts with improved performance. Herein we report intermetallic nickel germanide (NiGe) acting as a superior activity and durable Ni-based electro(pre)catalyst for OER. It is produced from a molecular bis(germylene)-Ni precursor. The ultra-small NiGe nullocrystals deposited on both nickel foam and fluorinated tin oxide (FTO) electrodes showed lower overpotentials and a durability of over three weeks (505 h) in comparison to the state-of-the-art Ni-, Co-, Fe-, and benchmark NiFe-based electrocatalysts under identical alkaline OER conditions. In contrast to other Ni-based intermetallic precatalysts under alkaline OER conditions, an unexpected electroconversion of NiGe into gamma-(NiOOH)-O-III with intercalated OH-/CO32- transpired that served as a highly active structure as shown by various ex situ methods and quasi in situ Raman spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2021, "Volume": 60, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4640, "End Page": 4647, "Article Number": null, "DOI": "10.1002/anie.202014331", "DOI Link": "http://dx.doi.org/10.1002/anie.202014331", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613823700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, M; Scudiero, L; Espinal, J; McEwen, JS; Garcia-Perez, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Matthew; Scudiero, Louis; Espinal, Juan; McEwen, Jean-Sabin; Garcia-Perez, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving the deconvolution and interpretation of XPS spectra from chars by ab initio calculations", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interpretation of C1s XPS spectra from disordered oxygenated carbons remains uncertain despite a variety of schemes reported in the literature. Here, a thermoseries of cellulose chars was studied to evaluate six published deconvolution schemes; however, none were capable of correctly identifying the oxygen content determined by the O1s spectrum. To improve the self-consistency of the XPS interpretation a method is proposed based on a 7 peak C1s deconvolution, 3 C-C peaks, 3 oxygenated peaks, and pi-pi* transition peak. Deconvolution of the O1s by 4 peaks is used to determine O-C and O=C contributions which provide upper and lower bounds for the related C1s peaks: C-O, C=O and COO. To improve assignments, various functional groups and carbon structures have been examined via DFT using an initial state approximation. DFT calculations of model compounds (pyrene, cellobiose and peryelene tetracarboxylic dianhydride (PTCDA)) were compared with experimental results to confirm the validity of the calculation method used. The DFT calculations identified several defect structures that justify the use of 3 peaks for deconvolution of the C-C region of C1s XPS spectra. The deconvolution method proposed provides C:O ratios in good agreement (within 5%) of those obtained from total C1s and O1s peaks. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 155, "End Page": 171, "Article Number": null, "DOI": "10.1016/j.carbon.2016.09.012", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2016.09.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386402700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, Z; Hwang, S; Li, X; Wang, CY; Samarakoon, W; Karakalos, S; Li, DG; Chen, MJ; He, YH; Wang, MY; Liu, ZY; Wang, GF; Zhou, H; Feng, ZX; Su, D; Spendelow, JS; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Zhi; Hwang, Sooyeon; Li, Xing; Wang, Chenyu; Samarakoon, Widitha; Karakalos, Stavros; Li, Dongguo; Chen, Mengjie; He, Yanghua; Wang, Maoyu; Liu, Zhenyu; Wang, Guofeng; Zhou, Hua; Feng, Zhenxing; Su, Dong; Spendelow, Jacob S.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D porous graphitic nullocarbon for enhancing the performance and durability of Pt catalysts: a balance between graphitization and hierarchical porosity", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon supports used in oxygen-reduction cathode catalysts for proton exchange membrane fuel cells (PEMFCs) are vulnerable to corrosion under harsh operating conditions, leading to poor performance durability. To address this issue, we have developed highly stable porous graphitic carbon (PGC) produced through pyrolysis of a 3D polymer hydrogel in combination with Mn. The resulting PGC features multilayer carbon sheets assembled in porous and flower-like morphologies. In situ high-temperature electron microscopy was employed to dynamically monitor the carbonization process up to 1100 degrees C, suggesting that the 3D polymer hydrogel provides high porosity at multiple scales, and that Mn catalyzes the graphitization process more effectively than other metals. Compared to conventional carbon supports such as Vulcan, Ketjenblack, and graphitized carbon, PGC provides an improved balance between high graphitization and hierarchical porosity, which is favorable for uniform Pt nulloparticle dispersion and enhanced corrosion resistance. As a result, Pt supported on PGC exhibits remarkably enhanced stability. In addition to thorough testing in aqueous electrolytes, we also conducted fuel cell testing using durability protocols recommended by the U.S. Department of Energy (DOE). After 5000 voltage cycles from 1.0 to 1.5 V, the Pt/PGC catalyst only lost 9 mV at a current density of 1.5 A cm(-2), dramatically exceeding the DOE support durability target (<30 mV), and surpassing commercial Pt/C catalysts. Along with the enhanced carbon corrosion resistance of the PGC support, the enhanced catalyst-support interactions are beneficial for stability improvement, likely due to nitrogen doping into carbon, which was further elucidated through X-ray absorption spectroscopy and density functional theory (DFT) calculations. Thus, the high stability and activity of PGC-based Pt catalysts are attributed to the combination of high graphitization degree, favorable surface area and porosity, and nitrogen doping, which effectively stabilize highly dispersed Pt nulloparticles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2830, "End Page": 2841, "Article Number": null, "DOI": "10.1039/c9ee01899a", "DOI Link": "http://dx.doi.org/10.1039/c9ee01899a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486019600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brown, AM; Sundararaman, R; Narang, P; Goddard, WA ; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brown, Ana M.; Sundararaman, Ravishankar; Narang, Prineha; Goddard, William A., III; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonradiative Plasmon Decay and Hot Carrier Dynamics: Effects of Phonons, Surfaces, and Geometry", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The behavior of metals across a broad frequency range from microwave to ultraviolet frequencies is of interest in plasmonics, nullophotonics, and metamaterials. Depending on the frequency, losses of collective excitations in metals can be predominulltly classical resistive effects or Landau damping. In this context, we present first principles calculations that capture all of the significant microscopic mechanisms underlying surface plasmon decay and predict the initial excited carrier distributions so generated. Specifically, we include ab initio predictions of phonon-assisted optical excitations in metals, which are critical to bridging the frequency range between resistive losses at low frequencies and direct interband transitions at high frequencies. In the commonly used plasmonic materials, gold, silver, copper, and aluminum, we find that resistive losses compete with phonon-assisted carrier generation below the interband threshold, but hot carrier generation via direct transitions dominates above threshold. Finally, we predict energy-dependent lifetimes and mean free paths of hot carriers, accounting for electron electron and electron-phonon scattering, to provide insight toward transport of plasmonically generated carriers at the nulloscale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 582, "Times Cited, All Databases": 649, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 957, "End Page": 966, "Article Number": null, "DOI": "10.1021/acsnullo.5b06199", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b06199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369115800104", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zi, YL; Wang, J; Wang, SH; Li, SM; Wen, Z; Guo, HY; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zi, Yunlong; Wang, Jie; Wang, Sihong; Li, Shengming; Wen, Zhen; Guo, Hengyu; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective energy storage from a triboelectric nullogenerator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To sustainably power electronics by harvesting mechanical energy using nullogenerators, energy storage is essential to supply a regulated and stable electric output, which is traditionally realized by a direct connection between the two components through a rectifier. However, this may lead to low energy-storage efficiency. Here, we rationally design a charging cycle to maximize energy-storage efficiency by modulating the charge flow in the system, which is demonstrated on a triboelectric nullogenerator by adding a motion-triggered switch. Both theoretical and experimental comparisons show that the designed charging cycle can enhance the charging rate, improve the maximum energy-storage efficiency by up to 50% and promote the saturation voltage by at least a factor of two. This represents a progress to effectively store the energy harvested by nullogenerators with the aim to utilize ambient mechanical energy to drive portable/wearable/implantable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10987, "DOI": "10.1038/ncomms10987", "DOI Link": "http://dx.doi.org/10.1038/ncomms10987", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372020100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, SY; Li, Y; Li, W; Mao, XY; Zhu, WG; Zeng, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Siyuan; Li, Yue; Li, Wei; Mao, Xiaoyu; Zhu, Wenguang; Zeng, Hualing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature ferroelectricity and a switchable diode effect in two-dimensional α-In2Se3 thin layers", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale room-temperature ferroelectricity is ideal for developing advanced non-volatile high-density memories. However, reaching the thin film limit in conventional ferroelectrics is a long-standing challenge due to the presence of the critical thickness effect. van der Waals materials, thanks to their stable layered structure, saturated interfacial bonding and weak interlayer couplings, are promising for exploring ultra-thin two-dimensional (2D) ferroelectrics and device applications. Here, we demonstrate a switchable room-temperature ferroelectric diode built upon a 2D ferroelectric alpha-In2Se3 layer as thin as 5 nm in the form of a graphene/alpha-In2Se3 heterojunction. The intrinsic out-of-plane ferroelectricity of the alpha-In2Se3 thin layers is evidenced by the observation of reversible spontaneous electric polarization with a relatively low coercive electric field of similar to 2 x 10(5) V cm(-1) and a typical ferroelectric domain size of around tens mu m(2). Owing to the out-of-plane ferroelectricity of the alpha-In2Se3 layer, the Schottky barrier at the graphene/alpha-In2Se3 interface can be effectively tuned by switching the electric polarization with an applied voltage, leading to a pronounced switchable double diode effect with an on/off ratio of similar to 10(5). Our results offer a new way for developing novel nulloelectronic devices based on 2D ferroelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2018, "Volume": 10, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14885, "End Page": 14892, "Article Number": null, "DOI": "10.1039/c8nr04422h", "DOI Link": "http://dx.doi.org/10.1039/c8nr04422h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445709600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, J; Ji, GB; Fan, XL; Chen, J; Li, Q; Wang, HY; Yang, Y; DeMella, KC; Raghavan, SR; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jing; Ji, Guangbin; Fan, Xiulin; Chen, Ji; Li, Qin; Wang, Haiyang; Yang, Yong; DeMella, Kerry C.; Raghavan, Srinivasa R.; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Fluorinated Electrolytes for Li-S Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable Li-S batteries are regarded as one of the most promising next-generation energy-storage systems. However, the inevitable formation of Li dendrites and the shuttle effect of lithium polysulfides significantly weakens electrochemical performance, preventing its practical application. Herein, a new class of localized high-concentration electrolyte (LHCE) enabled by adding inert fluoroalkyl ether of 1H, 1H, 5H-octafluoropentyl-1,1,2,2- tetrafluoroethyl ether into highly-concentrated electrolytes (HCE) lithium bis(fluorosulfonyl) imide/dimethoxyether (DME) system is reported to suppress Li dendrite formation and minimize the solubility of the high-order polysulfides in electrolytes, thus reducing the amount of electrolyte in cells. Such a unique LHCE can achieve a high coulombic efficiency of Li plating/ stripping up to 99.3% and completely suppressing the shuttling effect, thus maintaining a S cathode capacity of 775 mAh g(-1) for 150 cycles with a lean electrolyte of 4.56 g A(-1) h(-1). The LHCE reduces the solubility of lithium polysulfides, allowing the Li/S cell to achieve super performance in a lean electrolyte. This conception of using inert diluents in a highly concentrated electrolyte can accelerate commercialization of Li-S battery technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2019, "Volume": 9, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803774, "DOI": "10.1002/aenm.201803774", "DOI Link": "http://dx.doi.org/10.1002/aenm.201803774", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467988900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JW; Liu, C; Hsu, PC; Zhao, J; Wu, T; Tang, J; Liu, K; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jinwei; Liu, Chong; Hsu, Po-Chun; Zhao, Jie; Wu, Tong; Tang, Jing; Liu, Kai; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Remediation of heavy metal contaminated soil by asymmetrical alternating current electrochemistry", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soil contamination by heavy metals constitutes an important environmental problem, whereas field applicability of existing remediation technologies has encountered numerous obstacles, such as long operation time, high chemical cost, large energy consumption, secondary pollution, and soil degradation. Here we report the design and demonstration of a remediation method based on a concept of asymmetrical alternating current electrochemistry that achieves high degrees of contaminullt removal for different heavy metals (copper, lead, cadmium) at different initial concentrations (from 100 to 10,000 ppm), all reaching corresponding regulation levels for residential scenario after rational treatment time (from 30 min to 6 h). No excessive nutrient loss in treated soil is observed and no secondary toxic product is produced. Long-term experiment and plant assay show the high sustainability of the method and its feasibility for agricultural use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 4", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2440, "DOI": "10.1038/s41467-019-10472-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10472-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470082100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QD; Yao, ZP; Zhao, CL; Verhallen, T; Tabor, DP; Liu, M; Ooms, F; Kang, FY; Aspuru-Guzik, A; Hu, YS; Wagemaker, M; Li, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qidi; Yao, Zhenpeng; Zhao, Chenglong; Verhallen, Tomas; Tabor, Daniel P.; Liu, Ming; Ooms, Frans; Kang, Feiyu; Aspuru-Guzik, Alan; Hu, Yong-Sheng; Wagemaker, Marnix; Li, Baohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface chemistry of an amide electrolyte for highly reversible lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic lithium is a promising anode to increase the energy density of rechargeable lithium batteries. Despite extensive efforts, detrimental reactivity of lithium metal with electrolytes and uncontrolled dendrite growth remain challenging interconnected issues hindering highly reversible Li-metal batteries. Herein, we report a rationally designed amide-based electrolyte based on the desired interface products. This amide electrolyte achieves a high average Coulombic efficiency during cycling, resulting in an outstanding capacity retention with a 3.5 mAh cm(-2) high-mass-loaded LiNi0.8Co0.1Mn0.1O2 cathode. The interface reactions with the amide electrolyte lead to the predicted solid electrolyte interface species, having favorable properties such as high ionic conductivity and high stability. Operando monitoring the lithium spatial distribution reveals that the highly reversible behavior is related to denser deposition as well as top-down stripping, which decreases the formation of porous deposits and inactive lithium, providing new insights for the development of interface chemistries for metal batteries. Interface chemistry is essential for highly reversible lithium-metal batteries. Here the authors investigate amide-based electrolyte that lead to desirable interface species, resulting in dense Li-metal plating and top-down Li-metal stripping, responsible for the highly reversible cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4188, "DOI": "10.1038/s41467-020-17976-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17976-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569766000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharpe, AL; Fox, EJ; Barnard, AW; Finney, J; Watanabe, K; Taniguchi, T; Kastner, MA; Goldhaber-Gordon, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharpe, Aaron L.; Fox, Eli J.; Barnard, Arthur W.; Finney, Joe; Watanabe, Kenji; Taniguchi, Takashi; Kastner, M. A.; Goldhaber-Gordon, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When two sheets of graphene are stacked at a small twist angle, the resulting flat superlattice minibands are expected to strongly enhance electron-electron interactions. Here, we present evidence that near three-quarters (3/4) filling of the conduction miniband, these enhanced interactions drive the twisted bilayer graphene into a ferromagnetic state. In a narrow density range around an apparent insulating state at 3/4, we observe emergent ferromagnetic hysteresis, with a giant anomalous Hall (AH) effect as large as 10.4 kilohms and indications of chiral edge states. Notably, the magnetization of the sample can be reversed by applying a small direct current. Although the AH resistance is not quantized, and dissipation is present, our measurements suggest that the system may be an incipient Chern insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1346, "Times Cited, All Databases": 1481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2019, "Volume": 365, "Issue": 6453, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 605, "End Page": 608, "Article Number": null, "DOI": "10.1126/science.aaw3780", "DOI Link": "http://dx.doi.org/10.1126/science.aaw3780", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483195200043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, HJ; Zhu, X; Wang, CH; Zhang, L; Li, XS; Lee, S; Huang, ZL; Chen, RM; Chen, ZY; Wang, CF; Gu, Y; Chen, YM; Lei, YS; Zhang, TJ; Kim, N; Guo, YX; Teng, Y; Zhou, WB; Li, Y; Nomoto, A; Sternini, S; Zhou, QF; Pharr, M; di Scalea, FL; Xu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Hongjie; Zhu, Xuan; Wang, Chonghe; Zhang, Lin; Li, Xiaoshi; Lee, Seunghyun; Huang, Zhenlong; Chen, Ruimin; Chen, Zeyu; Wang, Chunfeng; Gu, Yue; Chen, Yimu; Lei, Yusheng; Zhang, Tianjiao; Kim, NamHeon; Guo, Yuxuan; Teng, Yue; Zhou, Wenbo; Li, Yang; Nomoto, Akihiro; Sternini, Simone; Zhou, Qifa; Pharr, Matt; di Scalea, Francesco Lanza; Xu, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable ultrasonic transducer arrays for three-dimensional imaging on complex surfaces", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrasonic imaging has been implemented as a powerful tool for noninvasive subsurface inspections of both structural and biological media. Current ultrasound probes are rigid and bulky and cannot readily image through nonplanar three-dimensional (3D) surfaces. However, imaging through these complicated surfaces is vital because stress concentrations at geometrical discontinuities render these surfaces highly prone to defects. This study reports a stretchable ultrasound probe that can conform to and detect nonplanar complex surfaces. The probe consists of a 10 x 10 array of piezoelectric transducers that exploit an island-bridge layout with multilayer electrodes, encapsulated by thin and compliant silicone elastomers. The stretchable probe shows excellent electromechanical coupling, minimal cross-talk, and more than 50% stretchability. Its performance is demonstrated by reconstructing defects in 3D space with high spatial resolution through flat, concave, and convex surfaces. The results hold great implications for applications of ultrasound that require imaging through complex surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar3979", "DOI": "10.1126/sciadv.aar3979", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar3979", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431373300033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Freeman, R; Han, M; Alvarez, Z; Lewis, JA; Wester, JR; Stephanopoulos, N; McClendon, MT; Lynsky, C; Godbe, JM; Sangji, H; Luijten, E; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Freeman, Ronit; Han, Ming; Alvarez, Zaida; Lewis, Jacob A.; Wester, James R.; Stephanopoulos, Nicholas; McClendon, Mark T.; Lynsky, Cheyenne; Godbe, Jacqueline M.; Sangji, Hussain; Luijten, Erik; Stupp, Samuel I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible self-assembly of superstructured networks", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft structures in nature, such as protein assemblies, can organize reversibly into functional and often hierarchical architectures through noncovalent interactions. Molecularly encoding this dynamic capability in synthetic materials has remained an elusive goal. We report on hydrogels of peptide-DNA conjugates and peptides that organize into superstructures of intertwined filaments that disassemble upon the addition of molecules or changes in charge density. Experiments and simulations demonstrate that this response requires large-scale spatial redistribution of molecules directed by strong noncovalent interactions among them. Simulations also suggest that the chemically reversible structures can only occur within a limited range of supramolecular cohesive energies. Storage moduli of the hydrogels change reversibly as superstructures form and disappear, as does the phenotype of neural cells in contact with these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2018, "Volume": 362, "Issue": 6416, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 808, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aat6141", "DOI Link": "http://dx.doi.org/10.1126/science.aat6141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450488500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Traore, M; Gong, AJ; Wang, YW; Qiu, LA; Bai, YZ; Zhao, WY; Liu, Y; Chen, Y; Liu, Y; Wu, HL; Li, SL; You, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Traore, Mory; Gong, Aijun; Wang, Yiwen; Qiu, Lina; Bai, Yuzhen; Zhao, Weiyu; Liu, Yang; Chen, Yi; Liu, Ying; Wu, Huilin; Li, Shuli; You, Yueyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research progress of rare earth separation methods and technologies", "Source Title": "JOURNAL OF RARE EARTHS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strategical elements, such as rare earth elements, play a crucial role in the industry, especially in pro-ducing high-tech materials. Major global industries have developed a strong dependence on rare earth materials. Every year, there are innovations in industries such as modern technology, green energy, or communications technology, which need more strategic metals to improve investment profitability. This article reviews advances in rare earth separation methods and techniques to guide and recommend the best extractants, depending on leaching conditions and the final target product. Each method for separating and extracting agents is individually revised in terms of the mechanism and interaction of providing rare earth elements. This paper also evaluates past and current trends of these methods and technical extractants and identifies their strengths and weaknesses. (c) 2022 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 41, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 182, "End Page": 189, "Article Number": null, "DOI": "10.1016/j.jre.2022.04.009", "DOI Link": "http://dx.doi.org/10.1016/j.jre.2022.04.009", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931163800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luczak, J; Kroczewska, M; Baluk, M; Sowik, J; Mazierski, P; Zaleska-Medynska, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luczak, Justyna; Kroczewska, Malwina; Baluk, Mateusz; Sowik, Jakub; Mazierski, Pawel; Zaleska-Medynska, Adriana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphology control through the synthesis of metal-organic frameworks", "Source Title": "ADVANCES IN COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal -organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under-standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi-vidual synthesis factors, such as pH of reaction mixture, including acidic or basic character of modulators, temperature, solvents types, surfactants type and content and ionic liquids on the morphology of growing MOFs. We identified main mechanisms of MOFs' growth leading to different morphology of final particles and next systematically discuss the effect of miscellaneous parameters on MOFs morphology based on the main mecha-nisms related to the nucleation, growth and formation of final MOFs structure, including coordination modu-lation, protonation/deprotonation acting and modulation by surfactants or capping agents. The effect of microwaves and ultrasound employment during synthesis is also considered due to their affecting especially nucleation and particles growing steps during MOFs formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 314, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102864, "DOI": "10.1016/j.cis.2023.102864", "DOI Link": "http://dx.doi.org/10.1016/j.cis.2023.102864", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968888700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, Z; Hou, YD; Yuan, RS; Ding, ZX; Ong, WJ; Wang, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Zhuang; Hou, Yidong; Yuan, Rusheng; Ding, Zhengxin; Ong, Wee-Jun; Wang, Sibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow NiCo2S4 nullospheres as a Cocatalyst to Support ZnIn2S4 nullosheets for Visible-Light-Driven Hydrogen Production", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational interface tailoring of nullosheets on hollow spheres is a promising strategy to develop efficient photocatalysts for hydrogen production with solar energy. Among the various photocatalyst materials, metal sulfides have been extensively researched because of their relatively narrow band gap and superior visible-light response. ZnIn2S4 is a layered ternary chalcogenide semiconductor photocatalyst with a tunable band gap energy (approximately 2.4 eV). Among various metal sulfide photocatalysts, ZnIn2S4 has gained considerable attention. However, intrinsic ZnIn2S4 only exhibits a relatively moderate photocatalytic activity, which is mainly owing to the high recombination and low migration rate of photocarriers. Loading cocatalysts onto semiconductor photocatalysts is an effective way to improve the performance of photocatalysts, because it can not only facilitate the separation of electron-hole pairs, but also reduce the activation energy for proton reduction. As a ternary transition metal sulfide, NiCo2S4 features a high electrical conductivity, low electronegativity, excellent redox properties, and outstanding electrocatalytic activity. Such favorable characteristics suggest that NiCo2S4 can expedite charge separation and transfer, thereby promoting photocatalytic H-2 production by serving as a cocatalyst. Moreover, both NiCo2S4 and ZnIn2S4 possess the ternary spinel crystal structure, which may facilitate the construction of NiCo2S4/ZnIn2S4 hybrids with tight interfacial contact for an enhanced photocatalytic performance. Herein, ultrathin ZnIn2S4 nullosheets were grown in situ on a non-noble-metal cocatalyst, namely NiCo2S4 hollow spheres, to form hierarchical NiCo2S4@ZnIn2S4 hollow heterostructured photocatalysts with an intimately coupled interface and strong visible light absorption extending to ca. 583 nm. The optimized NiCo2S4@ZnIn2S4 hybrid with a NiCo2S4 content of ca. 3.1% exhibited a high hydrogen evolution rate of 78 mu mol.h(-1), which was approximately 9 times higher than that of bare ZnIn2S4 and 3 times higher than that of 1% (w, mass fraction) Pt/ZnIn2S4. Additionally, the hybrid photocatalysts displayed good stability in the reaction. Photoluminescence and electrochemical analysis results indicated that NiCo2S4 hollow spheres served as an efficient cocatalyst for facilitating the separation and transport of light-induced charge carriers as well as reducing the hydrogen evolution reaction barrier. Finally, a possible reaction mechanism for the photocatalytic hydrogen evolution was proposed. In the NiCo2S4@ZnIn2S4 composite photocatalyst, the NiCo2S4 cocatalyst with high electrical conductivity favorably accepts the photoinduced electrons transferred from ZnIn2S4 and then employs the electrons to reduce protons for H-2 production on the reactive sites. Concurrently, the photogenerated holes are trapped by TEOA that acts as a hole scavenger to accomplish the photoredox cycle. This study provides guidance for the fabrication of hierarchical hollow heterostructures based on nullosheet semiconductor subunits as remarkable photocatalysts for hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 38, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2111021, "DOI": "10.3866/PKU.WHXB202111021", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202111021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760791100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DC; Liu, ZB; Wu, YW; Ji, SM; Yuan, ZX; Liu, J; Zhu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dechao; Liu, Zhengbo; Wu, Yiwen; Ji, Shaomin; Yuan, Zhanxiang; Liu, Jun; Zhu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Construction a Stable Protective Layer in Polymer Electrolyte for Ultralong Lifespan Solid-State Lithium Metal Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state lithium metal batteries (SLMBs) are attracting enormous attention due to their enhanced safety and high theoretical energy density. However, the alkali lithium with high reducibility can react with the solid-state electrolytes resulting in the inferior cycle lifespan. Herein, inspired by the idea of interface design, the 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide as an initiator to generate an artificial protective layer in polymer electrolyte is selected. Time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy reveal the stable solid electrolyte interface (SEI) is in situ formed between the electrolyte/Li interface. Scanning electron microscopy (SEM) images demonstrate that the constructed SEI can promote homogeneous Li deposition. As a result, the Li/Li symmetrical cells enable stable cycle ultralong-term for over 4500 h. Moreover, the as-prepared LiFePO4/Li SLMBs exhibit an impressive ultra-long cycle lifespan over 1300 cycles at 1 C, as well as 1600 cycles at 0.5 C with a capacity retention ratio over 80%. This work offers an effective strategy for the construction of the stable electrolyte/Li interface, paving the way for the rapid development of long lifespan SLMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104277, "DOI": "10.1002/advs.202104277", "DOI Link": "http://dx.doi.org/10.1002/advs.202104277", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758779200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, K; Feng, JD; Kis, A; Radenovic, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ke; Feng, Jiandong; Kis, Andras; Radenovic, Aleksandra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Thin Molybdenum Disulfide nullopores with High Sensitivity for DNA Trans location", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin nullopore membranes are considered to be a promising approach to achieve single base resolution with the ultimate aim of rapid and cheap DNA sequencing. Molybdenum disulfide (MoS2) is newly emerging as a material complementary to graphene due to its semiconductive nature and other interesting physical properties that can enable a wide range of potential sensing and nulloelectronics applications. Here, we demonstrate that monolayer or few-layer thick exfoliated MoS2 with subnullometer thickness can be transferred and suspended on a predesigned location on the 20 nm thick SiNx. membranes. nullopores in MoS2 are further sculpted with variable sizes using a transmission electron microscope (TEM) to drill through suspended portions of the MoS2 membrane. Various types of double-stranded (ds) DNA with different lengths and conformations are translocated through such a novel architecture, showing improved sensitivity (signal-to-noise ratio >10) compared to the conventional silicon nitride (SiNx) nullopores with tens of nullometers thickness. Unlike graphene nullopores, no special surface treatment is needed to avoid hydrophobic interaction between DNA and the surface. Our results imply that MoS2 membranes with nullopore can complement graphene nullopore membranes and offer potentially better performance in transverse detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2504, "End Page": 2511, "Article Number": null, "DOI": "10.1021/nn406102h", "DOI Link": "http://dx.doi.org/10.1021/nn406102h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333539400063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XF; Liu, CD; Yu, J; Li, Z; Liu, L; Li, CH; Xu, SC; Li, WF; Man, BY; Zhang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xiaofei; Liu, Chundong; Yu, Jing; Li, Zhen; Liu, Lu; Li, Chonghui; Xu, Shicai; Li, Weifeng; Man, Baoyuan; Zhang, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrophobic multiscale cavities for high-performance and self-cleaning surface-enhanced Raman spectroscopy (SERS) sensing", "Source Title": "nullOPHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cavity array, with excellent optical capture capability, has received increasing attention for the surface-enhanced Raman spectroscopy (SERS)-active substrates. Here, we proposed molybdenum disulfide (MoS2) nullocavities growing on pyramid Si (PSi) composed of in situ reduced Au nulloparticles (AuNPs), which can form the multiscale cavities (MSCs), and is facile for the couple of the plasmon. We demonstrated that the PSi/MoS2/Au MSCs can serve as highly sensitive, uniform, and stable SERS substrates for rhodamine 6G (R6G), crystal violet, and adenosine triphosphate detection, benefiting from the synergistic effect of the enhanced light trapping and the effective plasmonic couple. The couple of the plasmon in the MSCs is evidently proved by finitedifference time domain simulation, showing the strong electromagnetic field is located around the cavity wall. Moreover, the excellent hydrophobicity of the PSi/MoS2/AuNPs substrate endows it with the ability for the directional monitoring of organic pollutant in a mixture of oil and water. Finally, we demonstrated the MSCs with outstanding photocatalytic performance could achieve the renewable utilization by self-cleaning, which was attributed to the fast electron transfer and effective light absorption. The proposed PSi/MoS2/AuNPs MSC represents a robust mean using the plasmonic metal/semiconductor heterostructure for high-performance SERS sensors and photodegradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 9, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4761, "End Page": 4773, "Article Number": null, "DOI": "10.1515/nulloph-2020-0454", "DOI Link": "http://dx.doi.org/10.1515/nulloph-2020-0454", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000589660000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwon, MS; Yu, Y; Coburn, C; Phillips, AW; Chung, K; Shanker, A; Jung, J; Kim, G; Pipe, K; Forrest, SR; Youk, JH; Gierschner, J; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwon, Min Sang; Yu, Youngchang; Coburn, Caleb; Phillips, Andrew W.; Chung, Kyeongwoon; Shanker, Apoorv; Jung, Jaehun; Kim, Gunho; Pipe, Kevin; Forrest, Stephen R.; Youk, Ji Ho; Gierschner, Johannes; Kim, Jinsang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressing molecular motions for enhanced room-temperature phosphorescence of metal-free organic materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-free organic phosphorescent materials are attractive alternatives to the predominulltly used organometallic phosphors but are generally dimmer and are relatively rare, as, without heavy-metal atoms, spin-orbit coupling is less efficient and phosphorescence usually cannot compete with radiationless relaxation processes. Here we present a general design rule and a method to effectively reduce radiationless transitions and hence greatly enhance phosphorescence efficiency of metal-free organic materials in a variety of amorphous polymer matrices, based on the restriction of molecular motions in the proximity of embedded phosphors. Covalent cross-linking between phosphors and polymer matrices via Diels-Alder click chemistry is devised as a method. A sharp increase in phosphorescence quantum efficiency is observed in a variety of polymer matrices with this method, which is ca. two to five times higher than that of phosphor-doped polymer systems having no such covalent linkage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8947, "DOI": "10.1038/ncomms9947", "DOI Link": "http://dx.doi.org/10.1038/ncomms9947", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367587400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, ZW; Meng, WW; Wang, JB; Mitzi, DB; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Zewen; Meng, Weiwei; Wang, Jianbo; Mitzi, David B.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality", "Source Title": "MATERIALS HORIZONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for promising nontoxic and air-stable perovskite absorbers for solar cell applications has drawn extensive attention. Here, we show that a promising perovskite absorber should exhibit a high electronic dimensionality. Semiconductors that exhibit a high structural dimensionality, but a low electronic dimensionality have less promise as an absorber, because of barriers to isotropic current flow, enhanced electron/hole effective masses and fundamentally deeper defect states (more effective at causing recombination). Our concept accounts for the device performance of the perovskitebased solar cells reported in literature so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 601, "Times Cited, All Databases": 623, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 206, "End Page": 216, "Article Number": null, "DOI": "10.1039/c6mh00519e", "DOI Link": "http://dx.doi.org/10.1039/c6mh00519e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396098200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YH; Yan, Z; null, KW; Xiao, DQ; Liu, YH; Luan, HW; Fu, HR; Wang, XZ; Yang, QL; Wang, JC; Ren, W; Si, HZ; Liu, F; Yang, LH; Li, HJ; Wang, JT; Guo, XL; Luo, HY; Wang, L; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yihui; Yan, Zheng; null, Kewang; Xiao, Dongqing; Liu, Yuhao; Luan, Haiwen; Fu, Haoran; Wang, Xizhu; Yang, Qinglin; Wang, Jiechen; Ren, Wen; Si, Hongzhi; Liu, Fei; Yang, Lihen; Li, Hejun; Wang, Juntong; Guo, Xuelin; Luo, Hongying; Wang, Liang; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mechanically driven form of Kirigami as a route to 3D mesostructures in micro/nullomembranes", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Assembly of 3D micro/nullostructures in advanced functional materials has important implications across broad areas of technology. Existing approaches are compatible, however, only with narrow classes of materials and/or 3D geometries. This paper introduces ideas for a form of Kirigami that allows precise, mechanically driven assembly of 3D mesostructures of diverse materials from 2D micro/nullomembranes with strategically designed geometries and patterns of cuts. Theoretical and experimental studies demonstrate applicability of the methods across length scales from macro to nullo, in materials ranging from monocrystalline silicon to plastic, with levels of topographical complexity that significantly exceed those that can be achieved using other approaches. A broad set of examples includes 3D silicon mesostructures and hybrid nullomembrane-nulloribbon systems, including heterogeneous combinations with polymers and metals, with critical dimensions that range from 100 nm to 30 mm. A 3D mechanically tunable optical transmission window provides an application example of this Kirigami process, enabled by theoretically guided design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 22", "Publication Year": 2015, "Volume": 112, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11757, "End Page": 11764, "Article Number": null, "DOI": "10.1073/pnas.1515602112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1515602112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361525100031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, M; Liu, K; Jiang, T; Li, SB; Chen, J; Wu, ZH; Li, WQ; Tan, RZ; Wei, WY; Yang, XF; Dai, HL; Chen, ZB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Meng; Liu, Kun; Jiang, Tao; Li, Shengbo; Chen, Jing; Wu, Zihan; Li, Wenqing; Tan, Rongzhi; Wei, Wenying; Yang, Xiaofan; Dai, Honglian; Chen, Zhenbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "GelMA/PEGDA microneedles patch loaded with HUVECs-derived exosomes and Tazarotene promote diabetic wound healing", "Source Title": "JOURNAL OF nullOBIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Clinical work and research on diabetic wound repair remain challenging globally. Although various conventional wound dressings have been continuously developed, the efficacy is unsatisfactory. The effect of drug delivery is limited by the depth of penetration. The sustained release of biomolecules from biological wound dressings is a promising treatment approach to wound healing. An assortment of cell-derived exosomes (exos) have been proved to be instrumental in tissue regeneration, and researchers are dedicated to developing biomolecules carriers with unique properties. Herein, we reported a methacrylate gelatin (GeIMA) microneedles (MNs) patch to achieve transdermal and controlled release of exos and tazarotene. Our MNs patch comprising GeIMA/PEGDA hydrogel has distinctive biological features that maintain the biological activity of exos and drugs in vitro. Additionally, its unique physical structure prevents it from being tightly attached to the skin of the wound, it promotes cell migration, angiogenesis by slowly releasing exos and tazarotene in the deep layer of the skin. The full-thickness cutaneous wound on a diabetic mouse model was carried out to demonstrate the therapeutic effects of GelMA/PEGDA@T+ exos MNs patch. As a result, our GelMA/PEGDA@T+ exos MNs patch presents a potentially valuable method for repairing diabetic wound in clinical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2022, "Volume": 20, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147, "DOI": "10.1186/s12951-022-01354-4", "DOI Link": "http://dx.doi.org/10.1186/s12951-022-01354-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780299100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WJ; Yang, J; Byun, JJ; Moissinac, FP; Xu, JQ; Haigh, SJ; Domingos, M; Bissett, MA; Dryfe, RAW; Barg, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wenji; Yang, Jie; Byun, Jae Jong; Moissinac, Francis P.; Xu, Jiaqi; Haigh, Sarah J.; Domingos, Marco; Bissett, Mark A.; Dryfe, Robert A. W.; Barg, Suelen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Freestanding MXene Architectures for Current-Collector-Free Supercapacitors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) technologies appear as a paradigm for scalable manufacture of electrochemical energy storage (EES) devices, where complex 3D architectures are typically required but are hard to achieve using conventional techniques. The combination of these technologies and innovative material formulations that maximize surface area accessibility and ion transport within electrodes while minimizing space are of growing interest. Herein, aqueous inks composed of atomically thin (1-3 nm) 2D Ti3C2Tx with large lateral size of about 8 mu m possessing ideal viscoelastic properties are formulated for extrusion-based 3D printing of freestanding, high specific surface area architectures to determine the viability of manufacturing energy storage devices. The 3D-printed device achieves a high areal capacitance of 2.1 F cm(-2) at 1.7 mA cm(-2) and a gravimetric capacitance of 242.5 F g(-1) at 0.2 A g(-1) with a retention of above 90% capacitance for 10 000 cycles. It also exhibits a high energy density of 0.0244 mWh cm(-2) and a power density of 0.64 mW cm(-2) at 4.3 mA cm(-2). It is anticipated that the sustainable printing and design approach developed in this work can be applied to fabricate high-performance bespoke multiscale and multidimensional architectures of functional and structural materials for integrated devices in various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 31, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902725, "DOI": "10.1002/adma.201902725", "DOI Link": "http://dx.doi.org/10.1002/adma.201902725", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479337000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YH; Liang, Y; Yao, J; Chen, MK; Lin, SR; Wang, Z; Zhang, JC; Huang, XG; Yu, CY; Tsai, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yuhu; Liang, Yao; Yao, Jin; Chen, Mu Ku; Lin, Shirong; Wang, Zhuo; Zhang, Jingcheng; Huang, Xu Guang; Yu, Changyuan; Tsai, Din Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral Bound States in the Continuum in Plasmonic Metasurfaces", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bound states in the continuum (BICs) offer novel mechanisms to boost the quality factor (Q-factor) of resonullces. Unfortunately, current studies on chiral BICs metasurfaces suffer from a fundamental trade-off between Q-factor and circular dichroism (CD), presenting a significant hurdle that severely limits the independent control between CD and Q-factors. Here, 3D plasmonic metasurfaces are numerically demonstrated that overcome the trade-off and offer high-Q quasi-BIC resonullces (Q approximate to 938) with strong CD (approximate to 0.67) in the mid-infrared. These metasurfaces are made of integrated-resonullce units consisting of a twisted vertical split-ring resonator (VSRR) and a wall. Importantly, this dissimilar dimer configuration unlocks a new degree of freedom to decouple the Q-factor and CD, that is, the Q-factor and CD can be relatively independently manipulated by the height of the wall and the twisted angle of the VSRR, respectively. These results provide novel paradigms to manipulate advanced chiroptical responses, with various applications that require strong CD with enhanced light-matter interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 17, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200597, "DOI": "10.1002/lpor.202200597", "DOI Link": "http://dx.doi.org/10.1002/lpor.202200597", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921400900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, XL; Guo, ZW; Guo, ZY; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Xiaoli; Guo, Zhaowei; Guo, Ziyang; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic Batteries Operated at -70°C", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-temperature operation is a great challenge facing rechargeable batteries, and insufficient ionic conductivity and freezing of electrolyte are generally considered as the main reasons for this issue. Herein, an ethyl acetate-based electrolyte with a sufficient ionic conductivity of 0.2 mS cm(-1) at the ultra-low temperature of -70 degrees C is first used to fabricate intercalation compounds-based Li-ion batteries (LIBs) and an organic electrodes-based rechargeable battery, respectively, to clarify their low-temperature behavior- It is demonstrated that the LIBs cannot work at -70 degrees C because of the sluggish desolvation of Li+. However, the rechargeable battery using organic electrodes can work well at such low temperature and retains similar to 70% of capacity at room temperature, owing to the fast kinetics of charge storage on the surface groups or in the large interstitial space of organic solids. These results indicate a new way for developing low-temperature batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 902, "End Page": 913, "Article Number": null, "DOI": "10.1016/j.joule.2018.01.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.01.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, WC; Hu, TT; Liu, XY; Zha, JJ; Meng, FQ; Wu, ZK; Cui, ZL; Yang, Y; Li, H; Zhang, QH; Gu, L; Liang, RZ; Tan, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Weicheng; Hu, Tingting; Liu, Xueyan; Zha, Jiajia; Meng, Fanqi; Wu, Zhikang; Cui, Zhuolin; Yang, Yu; Li, Hai; Zhang, Qinghua; Gu, Lin; Liang, Ruizheng; Tan, Chaoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect engineering of layered double hydroxide nullosheets as inorganic photosensitizers for NIR-III photodynamic cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although two-dimensional (2D) layered double hydroxides (LDHs) have been widely used as efficient nulloagents for biological diagnosis and treatment, they have been found to be inert as photosensitizers (PSs) for photodynamic therapy (PDT). Herein, we report the defect engineering of ultrathin 2D CoMo-LDH and NiMo-LDH nullosheets as highly active inorganic PSs for PDT in the third near-infrared (NIR-III) window. Hydrothermal-synthesized 2D CoMo-LDH and NiMo-LDH nullosheets are etched via a simple acid treatment to obtain defect-rich CoMo-LDH and NiMo-LDH nullosheets. Importantly, the defect-rich CoMo-LDH nullosheets exhibit much higher activity (similar to 97 times) for generation of reactive oxygen species than that of the pristine CoMo-LDH nullosheets under a NIR-III 1567 nm laser irradiation. Therefore, after modification with polyethylene glycol, the defect-rich CoMo-LDH nullosheets can be used as an efficient inorganic PS for PDT to efficiently induce cancer cells apoptosis in vitro and eradicate tumors in vivo under 1567 nm laser irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3384, "DOI": "10.1038/s41467-022-31106-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31106-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810727500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hisaki, I; Suzuki, Y; Gomez, E; Ji, Q; Tohnai, N; Nakamura, T; Douhal, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hisaki, Ichiro; Suzuki, Yuto; Gomez, Eduardo; Ji, Qin; Tohnai, Norimitsu; Nakamura, Takayoshi; Douhal, Abderrazzak", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acid Responsive Hydrogen-Bonded Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A porous hydrogen-bonded organic framework (HOF) responsive to acid was constructed from a hexaazatrinaphthylene derivative with carboxyphenyl groups (CPHATN). Precise structures of both 1,2,4-trichlorobenzene solvate [CPHATN-1(TCB)] and activated HOF with permanent porosity (CPHATN-1a) were successfully determined by single-crystalline X-ray diffraction analysis. Permanent porosity of CPHATN-1a was evaluated by gas sorption experiments at low temperature. CPHATN-1a also shows significant thermal stability up to 633 K. Its crystals exhibit a rich photochemistry thanks to intramolecular charge-transfer and interunit proton-transfer reactions. Femtosecond (fs) experiments on crystals demonstrate that these events occur in <= 200 fs and 1.2 ps, respectively. Moreover, single-crystal fluorescence microscopy reveals a shift of the emission spectra most probably as a result of defects and a high anisotropic behavior, reflecting an ordered crystalline structure with a preferential orientation of the molecular dipole moments. Remarkably, CPHATN-1a, as a result of the protonation of pyradyl nitrogen atoms embedded in its it-conjugated core, shows reversible vapor acid-induced color changes from yellow to reddish-brown, which can be also followed by an ON/OFF of its emission. To the best of our knowledge, this is the first HOF that exhibits acid-responsive color changes. The present work provides new findings for developing stimuli responsive HOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2019, "Volume": 141, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2111, "End Page": 2121, "Article Number": null, "DOI": "10.1021/jacs.8b12124", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b12124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458348300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, XW; Chen, YH; Johnson, LR; Jovanov, ZP; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xiangwen; Chen, Yuhui; Johnson, Lee R.; Jovanov, Zarko P.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A rechargeable lithium-oxygen battery with dual mediators stabilizing the carbon cathode", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At the cathode of a Li-O-2 battery, O-2 is reduced to Li2O2 on discharge, the process being reversed on charge. Li2O2 is an insulating and insoluble solid, leading ultimately to low rates, low capacities and early cell death if formed on the cathode surface. Here we show that when using dual mediators, 2,5-Di-tert-butyl-1,4-benzoquinone [DBBQ] on discharge and 2,2,6,6-tetramethyl-1-piperidinyloxy [TEMPO] on charge, the electrochemistry at the cathode surface is decoupled from Li2O2 formation/decomposition in solution. Capacities of 2 mAh cm(areal)(-2) at 1 mA cm(areal)(-2) with low polarization on charge/discharge are demonstrated, and up to 40 mAh cm(areal)(-2) at rates >> 1 mA cm(areal)(-2) are anticipated if suitable gas diffusion electrodes can be devised. One of the major barriers to the progress of Li-O-2 cells is decomposition of the carbon cathode. By forming/decomposing Li2O2 in solution and avoiding high charge potentials, the carbon instability is significantly mitigated (<0.008% decomposition per cycle compared with 0.12% without mediators).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17118, "DOI": "10.1038/nenergy.2017.118", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415189100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, XL; Zhang, W; Wang, KM; Gu, YF; An, YW; Zhang, XQ; Gu, JQ; Luo, D; Han, JG; Zhang, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Xiaolin; Zhang, Wei; Wang, Kemeng; Gu, Yangfan; An, Youwen; Zhang, Xueqian; Gu, Jianqiang; Luo, Dan; Han, Jiaguang; Zhang, Weili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active terahertz beam steering based on mechanical deformation of liquid crystal elastomer metasurface", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active metasurfaces are emerging as the core of next-generation optical devices with their tunable optical responses and flat-compact topography. Especially for the terahertz band, active metasurfaces have been developed as fascinating devices for optical chopping and compressive sensing imaging. However, performance regulation by changing the dielectric parameters of the integrated functional materials exhibits severe limitations and parasitic losses. Here, we introduce a C-shape-split-ring-based phase discontinuity metasurface with liquid crystal elastomer as the substrate for infrared modulation of terahertz wavefront. Line-focused infrared light is applied to manipulate the deflection of the liquid crystal elastomer substrate, enabling controllable and broadband wavefront steering with a maximum output angle change of 22 degrees at 0.68 THz. Heating as another control method is also investigated and compared with infrared control. We further demonstrate the performance of liquid crystal elastomer metasurface as a beam steerer, frequency modulator, and tunable beam splitter, which are highly desired in terahertz wireless communication and imaging systems. The proposed scheme demonstrates the promising prospects of mechanically deformable metasurfaces, thereby paving the path for the development of reconfigurable metasurfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14, "DOI": "10.1038/s41377-022-01046-6", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-01046-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000907111500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Gao, ZR; Lin, QF; Liu, CX; Gao, FX; Lin, C; Zhang, SY; Deng, H; Mayoral, A; Fan, W; Luo, S; Chen, XB; He, H; Camblor, MA; Chen, FJ; Yu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jian; Gao, Zihao Rei; Lin, Qing-Fang; Liu, Chenxu; Gao, Fangxin; Lin, Cong; Zhang, Siyao; Deng, Hua; Mayoral, Alvaro; Fan, Wei; Luo, Song; Chen, Xiaobo; He, Hong; Camblor, Miguel A.; Chen, Fei-Jian; Yu, Jihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 3D extra-large-pore zeolite enabled by 1D-to-3D topotactic condensation of a chain silicate", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zeolites are microporous silicates with a large variety of applications as catalysts, adsorbents, and cation exchangers. Stable silica-based zeolites with increased porosity are in demand to allow adsorption and processing of large molecules but challenge our synthetic ability. We report a new, highly stable pure silica zeolite called ZEO-3, which has a multidimensional, interconnected system of extra-large pores open through windows made by 16 and 14 silicate tetrahedra, the least dense polymorph of silica known so far. This zeolite was formed by an unprecedented one-dimensional to three-dimensional (1D-to-3D) topotactic condensation of a chain silicate. With a specific surface area of more than 1000 square meters per gram, ZEO-3 showed a high performance for volatile organic compound abatement and recovery compared with other zeolites and metal-organic frameworks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2023, "Volume": 379, "Issue": 6629, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 283, "End Page": 287, "Article Number": null, "DOI": "10.1126/science.ade1771", "DOI Link": "http://dx.doi.org/10.1126/science.ade1771", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928329800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Luo, Y; Hisatomi, T; Vequizo, JJM; Suzuki, S; Chen, SS; Nakabayashi, M; Lin, LH; Pan, ZH; Kariya, N; Yamakata, A; Shibata, N; Takata, T; Teshima, K; Domen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zheng; Luo, Ying; Hisatomi, Takashi; Vequizo, Junie Jhon M.; Suzuki, Sayaka; Chen, Shanshan; Nakabayashi, Mamiko; Lin, Lihua; Pan, Zhenhua; Kariya, Nobuko; Yamakata, Akira; Shibata, Naoya; Takata, Tsuyoshi; Teshima, Katsuya; Domen, Kazunari", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sequential cocatalyst decoration on BaTaO2N towards highly-active Z-scheme water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxynitride photocatalysts hold promise for renewable solar hydrogen production via water splitting owing to their intense visible light absorption. Cocatalyst loading is essential for activation of such oxynitride photocatalysts. However, cocatalyst nulloparticles form aggregates and exhibit weak interaction with photocatalysts, which prevents eliciting their intrinsic photocatalytic performance. Here, we demonstrate efficient utilization of photoexcited electrons in a single-crystalline particulate BaTaO2N photocatalyst prepared with the assistance of RbCl flux for H-2 evolution reactions via sequential decoration of Pt cocatalyst by impregnation-reduction followed by site-selective photodeposition. The Pt-loaded BaTaO2N photocatalyst evolves H-2 over 100 times more efficiently than before, with an apparent quantum yield of 6.8% at the wavelength of 420nm, from a methanol aqueous solution, and a solar-to-hydrogen energy conversion efficiency of 0.24% in Z-scheme water splitting. Enabling uniform dispersion and intimate contact of cocatalyst nulloparticles on single-crystalline narrow-bandgap particulate photocatalysts is a key to efficient solar-to-chemical energy conversion. Activation of narrow-bandgap photocatalysts holds key to applicable solar-to-hydrogen energy conversion. Here, the authors demonstrate effective sequential cocatalyst decoration for such narrow-bandgap photocatalysts to realise highly-efficient hydrogen evolution and Z-scheme water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1005, "DOI": "10.1038/s41467-021-21284-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21284-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620682300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, GF; Li, F; Zou, W; Karamad, M; Jeon, JP; Kim, SW; Kim, SJ; Bu, YF; Fu, ZP; Lu, YL; Siahrostami, S; Baek, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Gao-Feng; Li, Feng; Zou, Wei; Karamad, Mohammadreza; Jeon, Jong-Pil; Kim, Seong-Wook; Kim, Seok-Jin; Bu, Yunfei; Fu, Zhengping; Lu, Yalin; Siahrostami, Samira; Baek, Jong-Beom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building and identifying highly active oxygenated groups in carbon materials for oxygen reduction to H2O2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The one-step electrochemical synthesis of H2O2 is an on-site method that reduces dependence on the energy-intensive anthraquinone process. Oxidized carbon materials have proven to be promising catalysts due to their low cost and facile synthetic procedures. However, the nature of the active sites is still controversial, and direct experimental evidence is presently lacking. Here, we activate a carbon material with dangling edge sites and then decorate them with targeted functional groups. We show that quinone-enriched samples exhibit high selectivity and activity with a H2O2 yield ratio of up to 97.8 % at 0.75V vs. RHE. Using density functional theory calculations, we identify the activity trends of different possible quinone functional groups in the edge and basal plane of the carbon nullostructure and determine the most active motif. Our findings provide guidelines for designing carbon-based catalysts, which have simultaneous high selectivity and activity for H2O2 synthesis. The identity of catalytic sites for H2O2 generation in carbon-based materials remains controversial with limited experimental evidence to date. Here, the authors decorate various target functional groups on carbon materials and quinone-enriched samples exhibit the highest activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2209, "DOI": "10.1038/s41467-020-15782-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15782-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000532362000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Chen, HM; Ding, XH; Lorestani, F; Huang, CL; Zhang, BW; Zheng, B; Wang, J; Cheng, HY; Xu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Cheng; Chen, Huamin; Ding, Xiaohong; Lorestani, Farnaz; Huang, Chunlei; Zhang, Bingwen; Zheng, Biao; Wang, Jun; Cheng, Huanyu; Xu, Yun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Human motion-driven self-powered stretchable sensing platform based on laser-induced graphene foams", "Source Title": "APPLIED PHYSICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Practical applications of next-generation stretchable electronics hinge on the development of sustained power supplies to drive highly sensitive on-skin sensors and wireless transmission modules. Although the manufacture of stretchable self-charging power units has been demonstrated by integrating stretchable energy harvesters and power management circuits with energy storage units, they often suffer from low and unstable output power especially under mechanical deformation and human movements, as well as complex and expensive fabrication processes. This work presents a low-cost, scalable, and facile manufacturing approach based on laser-induced graphene foams to yield a self-powered wireless sensing platform. 3D porous foams with high specific surface area and excellent charge transport provide an efficient flow of triboelectric electrons in triboelectric nullogenerators. The surface coating or doping with second laser irradiation on these foams can also form a 3D composite to provide high energy density in micro-supercapacitor arrays. The integration of a triboelectric nullogenerator and power management circuits with micro-supercapacitor arrays can efficiently harvest intermittent mechanical energy from body movements into stable power output. 3D foams and their composites patterned into various geometries conveniently create various deformable sensors on large scale at low cost. The generated stable, yet high, power with adjustable voltage and current outputs drives various stretchable sensors and wireless transmission modules to wirelessly measure pulse, strain, temperature, electrocardiogram, blood pressure, and blood oxygen. The self-powered, wireless, wearable sensing platform paves the way to wirelessly detect clinically relevant biophysical and biochemical signals for early disease diagnostics and healthy aging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11413, "DOI": "10.1063/5.0077667", "DOI Link": "http://dx.doi.org/10.1063/5.0077667", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749876500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kundu, D; Oberholzer, P; Glaros, C; Bouzid, A; Tervoort, E; Pasquarello, A; Niederberger, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kundu, Dipan; Oberholzer, Pascal; Glaros, Christos; Bouzid, Assil; Tervoort, Elena; Pasquarello, Alfredo; Niederberger, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic Cathode for Aqueous Zn-Ion Batteries: Taming a Unique Phase Evolution toward Stable Electrochemical Cycling", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc ion batteries are highly attractive for large-scale storage applications because of their inherent safety, low cost, and durability. Yet, their advancement is hindered by a dearth of positive host materials (cathode) due to sluggish diffusion of Zn(2+)inside solid inorganic frameworks. Here, we report on a novel organic host, tetrachloro-1,4-benzoquinone (also called: p-chloranil), which due to its inherently soft crystal structure can provide reversible and efficient Zn(2+)storage. It delivers a high capacity of >= 200 mAh g(-1)with a very small voltage polarization of 50 mV in a flat plateau around 1.1 V, which equate to an attractive specific energy of >200 Wh kg(-1)at an unparalleled energy efficiency (similar to 95%). As unraveled by density functional theory (DFT) calculations, the molecular columns in p-chloranil undergo a twisted rotation to accommodate Zn2+, thus restricting the volume change (-2.7%) during cycling. In-depth characterizations using operando X-ray diffraction, electron microscopy, and impedance analysis reveal a unique phase evolution, driven by a phase transfer mechanism occurring at the boundary of solid and liquid phase, which leads to unrestricted growth of discharged/charged phases. By confining the p-chloranil inside nullochannels of mesoporous carbon CMK-3, we can tame the phase evolution process, and thus stabilize the electrochemical cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2018, "Volume": 30, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3874, "End Page": 3881, "Article Number": null, "DOI": "10.1021/acs.chemmater.8b01317", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.8b01317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435416600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ziletti, A; Carvalho, A; Campbell, DK; Coker, DF; Neto, AHC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ziletti, A.; Carvalho, A.; Campbell, D. K.; Coker, D. F.; Neto, A. H. Castro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen Defects in Phosphorene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface reactions with oxygen are a fundamental cause of the degradation of phosphorene. Using first-principles calculations, we show that for each oxygen atom adsorbed onto phosphorene there is an energy release of about 2 eV. Although the most stable oxygen adsorbed forms are electrically inactive and lead only to minor distortions of the lattice, there are low energy metastable forms which introduce deep donor and/or acceptor levels in the gap. We also propose a mechanism for phosphorene oxidation involving reactive dangling oxygen atoms and we suggest that dangling oxygen atoms increase the hydrophilicity of phosphorene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2015, "Volume": 114, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 46801, "DOI": "10.1103/PhysRevLett.114.046801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.046801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349871400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YZ; Qin, CC; Cui, MH; He, TW; Liu, KK; Huang, YM; Luo, MH; Zhang, L; Xu, HY; Li, SS; Wei, JL; Liu, ZY; Wang, HH; Kim, W; Yuan, MJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuanzhi; Qin, Chaochao; Cui, Minghuan; He, Tingwei; Liu, Kaikai; Huang, Yanmin; Luo, Menghui; Zhang, Li; Xu, Hongyu; Li, Saisai; Wei, Junli; Liu, Zhiyong; Wang, Huanhua; Kim, Gi-Hwan; Yuan, Mingjian; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spectra stable blue perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Device performance and in particular device stability for blue perovskite light-emitting diodes (PeLEDs) remain considerable challenges for the whole community. In this manuscript, we conceive an approach by tuning the 'A-site' cation composition of perovskites to develop blue-emitters. We herein report a Rubidium-Cesium alloyed, quasi-two-dimensional perovskite and demonstrate its great potential for pure-blue PeLED applications. Composition engineering and in-situ passivation are conducted to further improve the material's emission property and stabilities. Consequently, we get a prominent film photoluminescence quantum yield of around 82% under low excitation density. Encouraged by these findings, we finally achieve a spectra-stable blue PeLED with the peak external quantum efficiency of 1.35% and a half-lifetime of 14.5 min, representing the most efficient and stable pure-blue PeLEDs reported so far. The strategy is also demonstrated to be able to generate efficient perovskite blue emitters and PeLEDs in the whole blue spectral region (from 454 to 492 nm).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1868, "DOI": "10.1038/s41467-019-09794-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09794-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465201500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koshy, DM; Chen, SC; Lee, DU; Stevens, MB; Abdellah, AM; Dull, SM; Chen, G; Nordlund, D; Gallo, A; Hahn, C; Higgins, DC; Bao, ZN; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koshy, David M.; Chen, Shucheng; Lee, Dong Un; Stevens, Michaela Burke; Abdellah, Ahmed M.; Dull, Samuel M.; Chen, Gan; Nordlund, Dennis; Gallo, Alessandro; Hahn, Christopher; Higgins, Drew C.; Bao, Zhenull; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the Origin of Highly Selective CO2 Electroreduction to CO on Ni,N-doped Carbon Catalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni,N-doped carbon catalysts have shown promising catalytic performance for CO2 electroreduction (CO2R) to CO; this activity has often been attributed to the presence of nitrogen-coordinated, single Ni atom active sites. However, experimentally confirming Ni-N bonding and correlating CO2 reduction (CO2R) activity to these species has remained a fundamental challenge. We synthesized polyacrylonitrile-derived Ni,N-doped carbon electrocatalysts (Ni-PACN) with a range of pyrolysis temperatures and Ni loadings and correlated their electrochemical activity with extensive physiochemical characterization to rigorously address the origin of activity in these materials. We found that the CO2R to CO partial current density increased with increased Ni content before plateauing at 2 wt % which suggests a dispersed Ni active site. These dispersed active sites were investigated by hard and soft X-ray spectroscopy, which revealed that pyrrolic nitrogen ligands selectively bind Ni atoms in a distorted square-planar geometry that strongly resembles the active sites of molecular metal-porphyrin catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2020, "Volume": 59, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4043, "End Page": 4050, "Article Number": null, "DOI": "10.1002/anie.201912857", "DOI Link": "http://dx.doi.org/10.1002/anie.201912857", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509624500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Wu, XY; Wang, YJ; Zhao, WY; Zhao, Y; Zhou, M; Wu, Y; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jing; Wu, Xinyu; Wang, Yajing; Zhao, Weiying; Zhao, Yue; Zhou, Ming; Wu, Yan; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green, Sustainable Architectural Bamboo with High Light Transmission and Excellent Electromagnetic Shielding as a Candidate for Energy-Saving Buildings", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, light-transmitting, energy-saving, and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment. Here, we developed a cellulose composite with excellent optical transmittance that retained the natural shape and fiber structure of bamboo. The modified whole bamboo possessed an impressive optical transmittance of approximately 60% at 6.23 mm, illuminullce of 1000 luminullce (lux), water absorption stability (mass change rate less than 4%), longitudinal tensile strength (46.40 MPa), and surface properties (80.2 HD). These were attributed to not only the retention of the natural circular hollow structure of the bamboo rod on the macro, but also the complete bamboo fiber skeleton template impregnated with UV resin on the micro. Moreover, a multilayered device consisting of translucent whole bamboo, transparent bamboo sheets, and electromagnetic shielding film exhibited remarkable heat insulation and heat preservation performance as well as an electromagnetic shielding performance of 46.3 dB. The impressive optical transmittance, mechanical properties, thermal performance, and electromagnetic shielding abilities combined with the renewable and sustainable nature, as well as the fast and efficient manufacturing process, make this bamboo composite material suitable for effective application in transparent, energy-saving, and electromagnetic shielding buildings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11, "DOI": "10.1007/s40820-022-00982-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00982-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000895977300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, HB; Chen, ZW; Wang, ZL; Singh, CV; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Haibin; Chen, Zhiwen; Wang, Zhili; Singh, Chandra Veer; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of Co/CoMoN/NF Heterostructures for High-Performance Electrochemical Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-cost and high-efficiency catalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in alkaline electrolyte is still challenging. Herein, interfacial Co/CoMoN heterostructures supported on Ni foam (Co/CoMoN/NF) are constructed by thermal ammonolysis of CoMoOx. In 1.0 m KOH solution, Co/CoMoN/NF heterostructures exhibit excellent HER activity with an overpotential of 173 mV at 100 mA cm(-2) and a Tafel slope of 68.9 mV dec(-1). Density functional theory calculations indicate that the low valence state Co site acts as efficient water-dissociation promoter, while CoMoN substrate has favorable hydrogen adsorption energy, leading to an enhanced HER activity. The Co/CoMoN/NF heterostructures also achieve high OER activity with an overpotential of 303 mV at 100 mA cm(-2) and a Tafel slope of 56 mV dec(-1). Using Co/CoMoN/NF heterostructures as the cathode and anode, the alkaline electrolyzer requires a low voltage of 1.56 V to reach the current density of 100 mA cm(-2) along with superior long-term durability. This study provides a new design strategy toward low-cost and excellent catalysts for water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105313, "DOI": "10.1002/advs.202105313", "DOI Link": "http://dx.doi.org/10.1002/advs.202105313", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753878700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miao, YL; Chen, YH; Luo, JS; Liu, X; Yang, Q; Shi, XT; Wang, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miao, Yali; Chen, Yunhua; Luo, Jinshui; Liu, Xiao; Yang, Qian; Shi, Xuetao; Wang, Yingjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black phosphorus nullosheets-enabled DNA hydrogel integrating 3D-printed scaffold for promoting vascularized bone regeneration", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The classical 3D-printed scaffolds have attracted enormous interests in bone regeneration due to the customized structural and mechanical adaptability to bone defects. However, the pristine scaffolds still suffer from the absence of dynamic and bioactive microenvironment that is analogous to natural extracellular matrix (ECM) to regulate cell behaviour and promote tissue regeneration. To address this challenge, we develop a black phos-phorus nullosheets-enabled dynamic DNA hydrogel to integrate with 3D-printed scaffold to build a bioactive gel -scaffold construct to achieve enhanced angiogenesis and bone regeneration. The black phosphorus nullosheets reinforce the mechanical strength of dynamic self-healable hydrogel and endow the gel-scaffold construct with preserved protein binding to achieve sustainable delivery of growth factor. We further explore the effects of this activated construct on both human umbilical vein endothelial cells (HUVECs) and mesenchymal stem cells (MSCs) as well as in a critical-sized rat cranial defect model. The results confirm that the gel-scaffold construct is able to promote the growth of mature blood vessels as well as induce osteogenesis to promote new bone for-mation, indicating that the strategy of nullo-enabled dynamic hydrogel integrated with 3D-printed scaffold holds great promise for bone tissue engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 97, "End Page": 109, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.08.005", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.08.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000844438500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, D; Han, D; Qu, SN; Liu, L; Jing, PT; Zhou, D; Ji, WY; Wang, XY; Zhang, TF; Shen, DZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Di; Han, Dong; Qu, Song-null; Liu, Lei; Jing, Peng-Tao; Zhou, Ding; Ji, Wen-Yu; Wang, Xiao-Yun; Zhang, Tong-Fei; Shen, De-Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supra-(carbon nullodots) with a strong visible to near-infrared absorption band and efficient photothermal conversion", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel concept and approach to engineering carbon nullodots (CNDs) were explored to overcome the limited light absorption of CNDs in low-energy spectral regions. In this work, we constructed a novel type of supra-CND by the assembly of surface charge-confined CNDs through possible electrostatic interactions and hydrogen bonding. The resulting supra-CNDs are the first to feature a strong, well-defined absorption band in the visible to near-infrared (NIR) range and to exhibit effective NIR photothermal conversion performance with high photothermal conversion efficiency in excess of 50%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e16120", "DOI": "10.1038/lsa.2016.120", "DOI Link": "http://dx.doi.org/10.1038/lsa.2016.120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380772100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Iscen, A; Sai, H; Sato, K; Sather, NA; Chin, SM; Alvarez, Z; Palmer, LC; Schatz, GC; Stupp, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chuang; Iscen, Aysenur; Sai, Hiroaki; Sato, Kohei; Sather, Nicholas A.; Chin, Stacey M.; Alvarez, Zaida; Palmer, Liam C.; Schatz, George C.; Stupp, Samuel, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular-covalent hybrid polymers for light-activated mechanical actuation", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peptide amphiphile supramolecular polymers with a crosslinked spiropyran network respond to light by expelling water, enabling the fabrication of soft actuators or light-driven crawlers. The development of synthetic structures that mimic mechanical actuation in living matter such as autonomous translation and shape changes remains a grand challenge for materials science. In living systems the integration of supramolecular structures and covalent polymers contributes to the responsive behaviour of membranes, muscles and tendons, among others. Here we describe hybrid light-responsive soft materials composed of peptide amphiphile supramolecular polymers chemically bonded to spiropyran-based networks that expel water in response to visible light. The supramolecular polymers form a reversibly deformable and water-draining skeleton that mechanically reinforces the hybrid and can also be aligned by printing methods. The noncovalent skeleton embedded in the network thus enables faster bending and flattening actuation of objects, as well as longer steps during the light-driven crawling motion of macroscopic films. Our work suggests that hybrid bonding polymers, which integrate supramolecular assemblies and covalent networks, offer strategies for the bottom-up design of soft matter that mimics living organisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 19, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 900, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-0707-7", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-0707-7", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542122300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, Z; Zhou, CK; Tian, Y; Shu, Y; Messier, J; Wang, JC; van de Burgt, LJ; Kountouriotis, K; Xin, Y; Holt, E; Schanze, K; Clark, R; Siegrist, T; Ma, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Zhao; Zhou, Chenkun; Tian, Yu; Shu, Yu; Messier, Joshua; Wang, Jamie C.; van de Burgt, Lambertus J.; Kountouriotis, Konstantinos; Xin, Yan; Holt, Ethan; Schanze, Kirk; Clark, Ronald; Siegrist, Theo; Ma, Biwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-dimensional organic lead halide perovskites with efficient bluish white-light emission", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid metal halide perovskites, an emerging class of solution processable photoactive materials, welcome a new member with a one-dimensional structure. Herein we report the synthesis, crystal structure and photophysical properties of one-dimensional organic lead bromide perovskites, C4N2H14 PbBr4, in which the edge sharing octahedral lead bromide chains [PbBr42-](infinity) are surrounded by the organic cations C4N2H142+ to form the bulk assembly of core-shell quantum wires. This unique one-dimensional structure enables strong quantum confinement with the formation of self-trapped excited states that give efficient bluish white-light emissions with photoluminescence quantum efficiencies of approximately 20% for the bulk single crystals and 12% for the microscale crystals. This work verifies once again that one-dimensional systems are favourable for exciton self-trapping to produce highly efficient below-gap broadband luminescence, and opens up a new route towards superior light emitters based on bulk quantum materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 691, "Times Cited, All Databases": 726, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14051, "DOI": "10.1038/ncomms14051", "DOI Link": "http://dx.doi.org/10.1038/ncomms14051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391195500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, D; Yu, Q; Kabra, S; Jiang, M; Forna-Kreutzer, P; Zhang, RP; Payne, M; Walsh, F; Gludovatz, B; Asta, M; Minor, AM; George, EP; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dong; Yu, Qin; Kabra, Saurabh; Jiang, Ming; Forna-Kreutzer, Paul; Zhang, Ruopeng; Payne, Madelyn; Walsh, Flynn; Gludovatz, Bernd; Asta, Mark; Minor, Andrew M.; George, Easo P.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional fracture toughness of CrCoNi-based medium- and high-entropy alloys at 20 kelvin", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CrCoNi-based medium- and high-entropy alloys display outstanding damage tolerance, especially at cryogenic temperatures. In this study, we examined the fracture toughness values of the equiatomic CrCoNi and CrMnFeCoNi alloys at 20 kelvin (K). We found exceptionally high crack-initiation fracture toughnesses of 262 and 459 megapascal-meters(1/2) (MPa center dot m(1/2)) for CrMnFeCoNi and CrCoNi, respectively; CrCoNi displayed a crackgrowth toughness exceeding 540 MPa center dot m(1/2) after 2.25 millimeters of stable cracking. Crack-tip deformation structures at 20 K are quite distinct from those at higher temperatures. They involve nucleation and restricted growth of stacking faults, fine nullotwins, and transformed epsilon martensite, with coherent interfaces that can promote both arrest and transmission of dislocations to generate strength and ductility. We believe that these alloys develop fracture resistance through a progressive synergy of deformation mechanisms, dislocation glide, stacking-fault formation, nullotwinning, and phase transformation, which act in concert to prolong strain hardening that simultaneously elevates strength and ductility, leading to exceptional toughness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2022, "Volume": 378, "Issue": 6623, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 978, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abp8070", "DOI Link": "http://dx.doi.org/10.1126/science.abp8070", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909873400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YM; Chen, ZJ; Yu, BC; Tan, S; Cui, YQ; Wu, HJ; Luo, YH; Shi, JJ; Li, DM; Meng, QB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yiming; Chen, Zijing; Yu, Bingcheng; Tan, Shan; Cui, Yuqi; Wu, Huijue; Luo, Yanhong; Shi, Jiangjian; Li, Dongmei; Meng, Qingbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient, stable formamidinium-cesium perovskite solar cells and minimodules enabled by crystallization regulation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formamidinium-cesium (FA-Cs) lead halide has attracted wide interest for enhancing the stability of perovskite solar cells; however, the crystallization of FA-Cs perovskite usually suffers from more complicated intermediate phase transition processes. Herein, we have developed a dual-functional additive consisting of organic ammonium cation and dithiocarbamate anion to regulate the crystallization and defects of the FA-Cs perovskite film. With a synergistic contribution of the cationic and anionic groups, 24.25% efficiency has been achieved in a single cell with excellent operational stability. Under steady-state light illumination and bias voltage, 90% power output of its initial state can still be obtained after 500 h of continuous operation. After enlarging the device from single cell to module, >20.5% efficiency has been realized from a 10.4 cm(2) minimodule by using only an ultralow-cost laser scribing technology. Briefly, this exploitation of cation-anion synergistic effect from dual-functional additives provides more opportunities for promoting the development of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 676, "End Page": 689, "Article Number": null, "DOI": "10.1016/j.joule.2022.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.02.003", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773205200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, D; Tian, XX; Doronkin, DE; Han, SL; Kondratenko, VA; Grunwaldt, JD; Perechodjuk, A; Vuong, TH; Rabeah, J; Eckelt, R; Rodemerck, U; Linke, D; Jiang, GY; Jiao, HJ; Kondratenko, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Dan; Tian, Xinxin; Doronkin, Dmitry E.; Han, Shanlei; Kondratenko, Vita A.; Grunwaldt, Jan-Dierk; Perechodjuk, Anna; Thanh Huyen Vuong; Rabeah, Jabor; Eckelt, Reinhard; Rodemerck, Uwe; Linke, David; Jiang, Guiyuan; Jiao, Haijun; Kondratenko, Evgenii, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ formation of ZnOx species for efficient propane dehydrogenation", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Propane dehydrogenation (PDH) to propene is an important alternative to oil-based cracking processes, to produce this industrially important platform chemical(1,2). The commercial PDH technologies utilizing Cr-containing (refs. (3,4)) or Pt-containing (refs. (5-8)) catalysts suffer from the toxicity of Cr(vi) compounds or the need to use ecologically harmful chlorine for catalyst regeneration(9). Here, we introduce a method for preparation of environmentally compatible supported catalysts based on commercial ZnO. This metal oxide and a support (zeolite or common metal oxide) are used as a physical mixture or in the form of two layers with ZnO as the upstream layer. Supported ZnOx species are in situ formed through a reaction of support OH groups with Zn atoms generated from ZnO upon reductive treatment above 550 degrees C. Using different complementary characterization methods, we identify the decisive role of defective OH groups for the formation of active ZnOx species. For benchmarking purposes, the developed ZnO-silicalite-1 and an analogue of commercial K-CrOx/Al2O3 were tested in the same setup under industrially relevant conditions at close propane conversion over about 400 h on propane stream. The developed catalyst reveals about three times higher propene productivity at similar propene selectivity. Propene is obtained through propane dehydrogenation using catalysts that are toxic, expensive or demanding to regenerate with ecologically harmful compounds, but the ZnO-based alternative reported here is cheap, clean and scalable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2021, "Volume": 599, "Issue": 7884, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 234, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03923-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03923-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722157200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, KZ; Meng, WW; Wang, XM; Yan, YF; Mitzi, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Ke-zhao; Meng, Weiwei; Wang, Xiaoming; Yan, Yanfa; Mitzi, David B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bandgap Engineering of Lead-Free Double Perovskite Cs2AgBiBr6 through Trivalent Metal Alloying", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The double perovskite family, A(2)M(I)M(III)X(6), is a promising route to overcome the lead toxicity issue confronting the current photovoltaic (PV) standout, CH3NH3PbI3. Given the generally large indirect band gap within most known double perovskites, band-gap engineering provides an important approach for targeting outstanding PV performance within this family. Using Cs2AgBiBr6 as host, band-gap engineering through alloying of In-III/Sb-III has been demonstrated in the current work. Cs2Ag(Bi1-xMx)Br-6 (M=In, Sb) accommodates up to 75% In-III with increased band gap, and up to 37.5% Sb-III with reduced band gap; that is, enabling ca. 0.41 eV band gap modulation through introduction of the two metals, with smallest value of 1.86 eV for Cs2Ag(Bi0.625Sb0.375)Br-6. Band structure calculations indicate that opposite band gap shift directions associated with Sb/In substitution arise from different atomic configurations for these atoms. Associated photoluminescence and environmental stability of the three-metal systems are also assessed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2017, "Volume": 56, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8158, "End Page": 8162, "Article Number": null, "DOI": "10.1002/anie.201703970", "DOI Link": "http://dx.doi.org/10.1002/anie.201703970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404140900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Hu, L; Zhang, YC; Wang, XZ; Wang, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ya; Hu, Lang; Zhang, Yongcai; Wang, Xiaozhi; Wang, Honggui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Snowflake-Like Cu2S/MoS2/Pt heterostructure with near infrared photothermal-enhanced electrocatalytic and photoelectrocatalytic hydrogen production", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Snowflake-like Cu2S/MoS2 heterostructures with varied compositions were constructed via a two-step hydro thermal method. The 45-Cu2S/MoS2 with 45 wt% Cu2S was found as the optimum catalyst, which displayed photothermal enhanced hydrogen evolution reaction (HER) performance under near infrared (NIR) irradiation. After electrochemical deposition of a tiny amount of Pt (45-Cu2S/MoS2/Pt-100s), Schottky barrier was formed between Pt nulloparticles and MoS2 nullosheets. Using 45-Cu2S/MoS2/Pt-100s as an electrocatalyst, low over potential of 78 mV (@10 mV cm(-2)) and Tafel slope of 48 mV dec(-1) were achieved with the assistance of NIR irradiation. The photoelectrochemical (PEC) hydrogen production performance of 45-Cu2S/MoS2/Pt-100s was also investigated. The optimal conversion efficiency of 45-Cu2S/MoS2/Pt-100s could reach 0.78% at 0.57 V (vs. reversible hydrogen electrode (RHE)). The control of the internal geometric and electronic structure of the catalysts and the aid of photothermal effect in this work provide new ideas for designing high-efficiency hydrogen evolution catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2022, "Volume": 315, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121540, "DOI": "10.1016/j.apcatb.2022.121540", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2022.121540", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000812258000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Min, SW; Kim, DH; Joe, DJ; Kim, BW; Jung, YH; Lee, JH; Lee, BY; Doh, I; An, JH; Youn, YN; Joung, B; Yoo, CD; Ahn, HS; Lee, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Min, Seongwook; Kim, Dong Hyun; Joe, Daniel J.; Kim, Byung Woo; Jung, Young Hoon; Lee, Jae Hee; Lee, Bo-Yeon; Doh, Il; An, Jaehun; Youn, Young-Nam; Joung, Boyoung; Yoo, Chang D.; Ahn, Hyo-Suk; Lee, Keon Jae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Clinical Validation of a Wearable Piezoelectric Blood-Pressure Sensor for Continuous Health Monitoring", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable blood-pressure sensors have recently attracted attention as healthcare devices for continuous non-invasive arterial pressure (CNAP) monitoring. However, the accuracy of wearable blood-pressure (BP) monitoring devices has been controversial due to the low signal quality of sensors, the absence of an accurate transfer function to convert the sensor signals into BP values, and the lack of clinical validation regarding measurement precision. Here, a wearable piezoelectric blood-pressure sensor (WPBPS) is reported, which achieves a high normalized sensitivity (0.062 kPa(-1)), and fast response time (23 ms) for CNAP monitoring. The transfer function of a linear regression model is designed, offering a simple solution to convert the flexible piezoelectric sensor signals into BP values. In order to verify the measurement accuracy of WPBPS, clinical trials are performed on 35 subjects aged from 20 to 80 s after screening. The mean difference between the WPBPS and a commercial sphygmomanometer of 175 BP data pairs is -0.89 +/- 6.19 and -0.32 +/- 5.28 mmHg for systolic blood pressure (SBP) and diastolic blood pressure (DBP), respectively. By building a WPBPS-embedded wristwatch, the potentially promising use of a convenient, portable, continuous BP monitoring system for cardiovascular disease diagnosis is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202301627", "DOI Link": "http://dx.doi.org/10.1002/adma.202301627", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000985780600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, YF; Wang, XL; Tang, M; Qiu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Yuanfei; Wang, Xueliang; Tang, Miao; Qiu, Huibin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailored Fabrication of Carbon Dot Composites with Full-Color Ultralong Room-Temperature Phosphorescence for Multidimensional Encryption", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultralong room-temperature phosphorescence (RTP) is highly useful for information encryption, organic electronics, bioelectronics, etc. However, the preparation of related metal-free materials with multiple colors across the full spectrum remains a major challenge. Herein, a facile method is developed to fabricate boron-doped carbon dot (B-CD) composites with full-color long lifetime RTP continuously tailorable in the range of 466-638 nm simply by pyrolysis of the citric acid and boric acid precursors with various mass ratios at different temperatures. This leads to the formation of luminescent B-CD centers in a rigid polycrystalline B2O3 matrix, which effectively stabilizes the triplet excited states of B-CDs. Thus, the composites become phosphorescent over a relatively long period (5-12 s) after the removal of the irradiation source. Meanwhile, the increased particle size and oxidation degree of B-CDs obtained at larger citric acid feeding or higher pyrolysis temperature continuously shift the phosphorescence from blue to red. Due to the formation of multiple luminescence centers, the RTP can also be finely modulated by the excitation wavelength. The resulting B-CD composites with highly tunable long lifetime RTP further allow a variety of distinctive applications in multidimensional encryption handily utilizing space, time, and color variations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103833, "DOI": "10.1002/advs.202103833", "DOI Link": "http://dx.doi.org/10.1002/advs.202103833", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720621700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Xu, YX; Wang, MC; Liu, EZ; Zhao, NQ; Shi, CS; Lin, D; Zhu, FL; He, CN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiang; Xu, Yixin; Wang, Miaocao; Liu, Enzuo; Zhao, Naiqin; Shi, Chunsheng; Lin, Dong; Zhu, Fulong; He, Chunnian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A powder-metallurgy-based strategy toward three-dimensional graphene-like network for reinforcing copper matrix composites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional graphene network is a promising structure for improving both the mechanical properties and functional capabilities of reinforced polymer and ceramic matrix composites. However, direct application in a metal matrix remains difficult due to the reason that wetting is usually unfavorable in the carbon/metal system. Here we report a powder-metallurgy based strategy to construct a three-dimensional continuous graphene network architecture in a copper matrix through thermal-stress-induced welding between graphene-like nullosheets grown on the surface of copper powders. The interpenetrating structural feature of the as-obtained composites not only promotes the interfacial shear stress to a high level and thus results in significantly enhanced load transfer strengthening and crack-bridging toughening simultaneously, but also constructs additional three-dimensional hyperchannels for electrical and thermal conductivity. Our approach offers a general way for manufacturing metal matrix composites with high overall performance. Graphene networks have been used to reinforce polymer and ceramic composites, but connecting graphene into a three dimensional network in a metal matrix is challenging. Here the authors use a powder-metallurgy-based strategy to construct a three-dimensional graphene network reinforced copper matrix composite.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2775, "DOI": "10.1038/s41467-020-16490-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16490-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543974800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, HL; Feng, X; Li, J; Li, M; Xia, YZ; Yuan, YF; Yang, C; Dai, B; Lin, ZQ; Wang, JC; Lu, J; Wang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Huile; Feng, Xin; Li, Jun; Li, Matthew; Xia, Yuanzhi; Yuan, Yifei; Yang, Chao; Dai, Bin; Lin, Zhiqun; Wang, Jichang; Lu, Jun; Wang, Shun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heteroatom-Doped Porous Carbon Materials with Unprecedented High Volumetric Capacitive Performance", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of carbon-based materials with a high mass density and large porosity has always been a challenging goal, since they fulfill the demands of next-generation supercapacitors and other electrochemical devices. We report a new class of high-density heteroatom-doped porous carbon that can be used as an aqueous-based supercapacitor material. The material was synthesized by an in situ dehalogenation reaction between a halogenated conjugated diene and nitrogen-containing nucleophiles. Under the given conditions, pyridinium salts can only continue to perform the dehalogenation if there is residue water remaining from the starting materials. The obtained carbon materials are highly doped by various heteroatoms, leading to high densities, abundant multimodal pores, and an excellent volumetric capacitive performance. Porous carbon tri-doped with nitrogen, phosphorous, and oxygen exhibits a high packing density (2.13 g cm(-3)) and an exceptional volumetric energy density (36.8 Wh L-1) in alkaline electrolytes, making it competitive to even some Ni-MH cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2019, "Volume": 58, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2397, "End Page": 2401, "Article Number": null, "DOI": "10.1002/anie.201813686", "DOI Link": "http://dx.doi.org/10.1002/anie.201813686", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458417700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, CK; Pan, F; Bin, HJ; Zhang, JQ; Xue, LW; Qiu, BB; Wei, ZX; Zhang, ZG; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Chenkai; Pan, Fei; Bin, Haijun; Zhang, Jianqi; Xue, Lingwei; Qiu, Beibei; Wei, Zhixiang; Zhang, Zhi-Guo; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A low cost and high performance polymer donor material for polymer solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of polymer solar cells requires the realization of high efficiency, high stability, and low cost devices. Here we demonstrate a low-cost polymer donor poly[(thiophene)-alt(6,7-difluoro-2-(2-hexyldecyloxy)quinoxaline)] (PTQ10), which is synthesized with high overall yield of 87.4% via only two-step reactions from cheap raw materials. More importantly, an impressive efficiency of 12.70% is obtained for the devices with PTQ10 as donor, and the efficiency of the inverted structured PTQ10-based device also reaches 12.13% (certificated to be 12.0%). Furthermore, the as-cast devices also demonstrate a high efficiency of 10.41% and the devices exhibit insensitivity of active layer thickness from 100 nm to 300 nm, which is conductive to the large area fabrication of the devices. In considering the advantages of low cost and high efficiency with thickness insensitivity, we believe that PTQ10 will be a promising polymer donor for commercial application of polymer solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 734, "Times Cited, All Databases": 773, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 743, "DOI": "10.1038/s41467-018-03207-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03207-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425594200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, K; Xiao, ZY; Lu, SR; Zajaczkowski, W; Pisula, W; Hanssen, E; White, JM; Williamson, RM; Subbiah, J; Ouyang, JY; Holmes, AB; Wong, WWH; Jones, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Kuan; Xiao, Zeyun; Lu, Shirong; Zajaczkowski, Wojciech; Pisula, Wojciech; Hanssen, Eric; White, Jonathan M.; Williamson, Rachel M.; Subbiah, Jegadesan; Ouyang, Jianyong; Holmes, Andrew B.; Wong, Wallace W. H.; Jones, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A molecular nematic liquid crystalline material for high-performance organic photovoltaics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed organic photovoltaic cells (OPVs) hold great promise to enable roll-to-roll printing of environmentally friendly, mechanically flexible and cost-effective photovoltaic devices. Nevertheless, many high-performing systems show best power conversion efficiencies (PCEs) with a thin active layer (thickness is similar to 100 nm) that is difficult to translate to roll-to-roll processing with high reproducibility. Here we report a new molecular donor, benzodithiophene terthiophene rhodanine (BTR), which exhibits good processability, nematic liquid crystalline behaviour and excellent optoelectronic properties. A maximum PCE of 9.3% is achieved under AM 1.5G solar irradiation, with fill factor reaching 77%, rarely achieved in solution-processed OPVs. Particularly promising is the fact that BTR-based devices with active layer thicknesses up to 400 nm can still afford high fill factor of similar to 70% and high PCE of similar to 8%. Together, the results suggest, with better device architectures for longer device lifetime, BTR is an ideal candidate for mass production of OPVs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6013, "DOI": "10.1038/ncomms7013", "DOI Link": "http://dx.doi.org/10.1038/ncomms7013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348812400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LL; Ma, J; Wang, C; Yu, XR; Liu, R; Jiang, F; Sun, XW; Du, AB; Zhou, XH; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Longlong; Ma, Jun; Wang, Chen; Yu, Xinrun; Liu, Ru; Jiang, Feng; Sun, Xingwei; Du, Aobing; Zhou, Xinhong; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Bifunctional Self-Stabilized Strategy Enabling 4.6 V LiCoO2 with Excellent Long-Term Cyclability and High-Rate Capability", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the theoretical specific capacity of LiCoO2 is as high as 274 mAh g(-1), the superior electrochemical performances of LiCoO2 can be barely achieved due to the issues of severe structure destruction and LiCoO2/electrolyte interface side reactions when the upper cutoff voltage exceeds 4.5 V. Here, a bifunctional self-stabilized strategy involving Al+Ti bulk codoping and gradient surface Mg doping is first proposed to synchronously enhance the high-voltage (4.6 V) performances of LiCoO2. The comodified LiCoO2 (CMLCO) shows an initial discharge capacity of 224.9 mAh g(-1) and 78% capacity retention after 200 cycles between 3.0 and 4.6 V. Excitingly, the CMLCO also exhibits a specific capacity of up to 142 mAh g(-1) even at 10 C. Moreover, the long-term cyclability of CMLCO/mesocarbon microbeads full cells is also enhanced significantly even at high temperature of 60 degrees C. The synergistic effects of this bifunctional self-stabilized strategy on structural reversibility and interfacial stability are demonstrated by investigating the phase transitions and interface characteristics of cycled LiCoO2. This work will be a milestone breakthrough in the development of high-voltage LiCoO2. It will also present an instructive contribution for resolving the big structural and interfacial challenges in other high-energy-density rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900355, "DOI": "10.1002/advs.201900355", "DOI Link": "http://dx.doi.org/10.1002/advs.201900355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477708000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, DY; Wang, J; Agosta, L; Zang, Z; Zhao, B; Kong, LM; Lu, HZ; Mosquera-Lois, I; Carnevali, V; Dong, JC; Zhou, JH; Ji, HY; Pfeifer, L; Zakeeruddin, SM; Yang, YG; Wu, B; Rothlisberger, U; Yang, XY; Grätzel, M; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Dongyuan; Wang, Jie; Agosta, Lorenzo; Zang, Ziang; Zhao, Bin; Kong, Lingmei; Lu, Haizhou; Mosquera-Lois, Irea; Carnevali, Virginia; Dong, Jianchao; Zhou, Jianheng; Ji, Huiyu; Pfeifer, Lukas; Zakeeruddin, Shaik M.; Yang, Yingguo; Wu, Bo; Rothlisberger, Ursula; Yang, Xuyong; Gratzel, Michael; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tautomeric mixture coordination enables efficient lead-free perovskite LEDs", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite light-emitting diodes (PeLEDs) have demonstrated remarkable optoelectronic performance1-3. However, there are potential toxicity issues with lead4,5 and removing lead from the best-performing PeLEDs-without compromising their high external quantum efficiencies-remains a challenge. Here we report a tautomeric-mixture-coordination-induced electron localization strategy to stabilize the lead-free tin perovskite TEA2SnI4 (TEAI is 2-thiopheneethylammonium iodide) by incorporating cyanuric acid. We demonstrate that a crucial function of the coordination is to amplify the electronic effects, even for those Sn atoms that aren't strongly bonded with cyanuric acid owing to the formation of hydrogen-bonded tautomeric dimer and trimer superstructures on the perovskite surface. This electron localization weakens adverse effects from Anderson localization and improves ordering in the crystal structure of TEA2SnI4. These factors result in a two-orders-of-magnitude reduction in the non-radiative recombination capture coefficient and an approximately twofold enhancement in the exciton binding energy. Our lead-free PeLED has an external quantum efficiency of up to 20.29%, representing a performance comparable to that of state-of-the-art lead-containing PeLEDs6-12. We anticipate that these findings will provide insights into the stabilization of Sn(II) perovskites and further the development of lead-free perovskite applications. Lead-free perovskite light-emitting diodes (LEDs) prepared using tautomeric mixture coordination provide improved ordering in the crystal structure, reduced recombination and enhanced exciton binding energy compared with lead-containing perovskite-based LEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2023, "Volume": 622, "Issue": 7983, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 493, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06514-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06514-6", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001079363600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, NN; Zhang, X; Ju, ZY; Yu, XW; Wang, YX; Du, Y; Bai, ZC; Dou, SX; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, nulla; Zhang, Xiao; Ju, Zhengyu; Yu, Xingwen; Wang, Yunxiao; Du, Yi; Bai, Zhongchao; Dou, Shixue; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thickness-independent scalable high-performance Li-S batteries with high areal sulfur loading via electron-enriched carbon framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing the energy density of lithium-sulfur batteries necessitates the maximization of their areal capacity, calling for thick electrodes with high sulfur loading and content. However, traditional thick electrodes often lead to sluggish ion transfer kinetics as well as decreased electronic conductivity and mechanical stability, leading to their thickness-dependent electrochemical performance. Here, free-standing and low-tortuosity N, O co-doped wood-like carbon frameworks decorated with carbon nullotubes forest (WLC-CNTs) are synthesized and used as host for enabling scalable high-performance Li-sulfur batteries. EIS-symmetric cell examinations demonstrate that the ionic resistance and charge-transfer resistance per unit electro-active surface area of S@WLC-CNTs do not change with the variation of thickness, allowing the thickness-independent electrochemical performance of Li-S batteries. With a thickness of up to 1200 mu m and sulfur loading of 52.4mgcm(-2), the electrode displays a capacity of 692 mAh g(-1) after 100 cycles at 0.1C with a low E/S ratio of 6. Moreover, the WLC-CNTs framework can also be used as a host for lithium to suppress dendrite growth. With these specific lithiophilic and sulfiphilic features, Li-S full cells were assembled and exhibited long cycling stability. Improving the energy density of lithium-sulfur batteries is necessary for their practical application. Here, the authors report free-standing and low-tortuosity carbon frameworks as host for sulfur and lithium, enabling scalable thickness independent electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4519, "DOI": "10.1038/s41467-021-24873-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24873-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678710800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Channei, D; Inceesungvorn, B; Wetchakun, N; Ukritnukun, S; Nattestad, A; Chen, J; Phanichphant, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Channei, D.; Inceesungvorn, B.; Wetchakun, N.; Ukritnukun, S.; Nattestad, A.; Chen, J.; Phanichphant, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic Degradation of Methyl Orange by CeO2 and Fe-doped CeO2 Films under Visible Light Irradiation", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Undoped CeO2 and 0.50-5.00 mol% Fe-doped CeO2 nulloparticles were prepared by a homogeneous precipitation combined with homogeneous/impreganation method, and applied as photocatalyst films prepared by a doctor blade technique. The superior photocatalytic performances of the Fe-doped CeO2/films, compared with undoped CeO2 films, was ascribed mainly to a decrease in band gap energy and an increase in specific surface area of the material. The presence of Fe3+ as found from XPS analysis, may act as electron acceptor and/or hole donor, facilitating longer lived charge carrier separation in Fe-doped CeO2 films as confirmed by photoluminescence spectroscopy. The 1.50 mol% Fe-doped CeO2 film was found to be the optimal iron doping concentration for MO degradation in this study.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5757, "DOI": "10.1038/srep05757", "DOI Link": "http://dx.doi.org/10.1038/srep05757", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341022700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SS; Wang, SF; Tang, DM; Zhao, WJ; Xu, HL; Chu, LQ; Bando, Y; Golberg, D; Eda, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shisheng; Wang, Shunfeng; Tang, Dai-Ming; Zhao, Weijie; Xu, Huilong; Chu, Leiqiang; Bando, Yoshio; Golberg, Dmitri; Eda, Goki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halide-assisted atmospheric pressure growth of large WSe2 and WS2 monolayer crystals", "Source Title": "APPLIED MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical vapor deposition (CVD) of two-dimensional (2D) tungsten dichalcogenide crystals requires steady flow of tungsten source in the vapor phase. This often requires high temperature and low pressure due to the high sublimation point of tungsten oxide precursors. We demonstrate atmospheric pressure CVD of WSe2 and WS2 monolayers at moderate temperatures (700-850 degrees C) using alkali metal halides (MX where M = Na or K and X = Cl, Br or I) as the growth promoters. We attribute the facilitated growth to the formation of volatile tungsten oxyhalide species during growth, which leads to efficient delivery of the precursor to the growth substrates. The monolayer crystals were found to be free of unintentional doping with alkali metal and halogen atoms. Good field-effect transistor (FET) performances with high current on/off ratio similar to 10(7), hole and electron mobilities up to 102 and 26 cm(2) V-1 s(-1) for WSe2 and electron mobility of 14 cm(2) V-1 s(-1) for WS2 devices were achieved. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 60, "End Page": 66, "Article Number": null, "DOI": "10.1016/j.apmt.2015.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.apmt.2015.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000218476800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pham, TH; Zhang, J; Li, M; Shen, TH; Ko, Y; Tileli, V; Luo, W; Züttel, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pham, Thi Ha My; Zhang, Jie; Li, Mo; Shen, Tzu-Hsien; Ko, Youngdon; Tileli, Vasiliki; Luo, Wen; Zuttel, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Electrocatalytic CO2 Reduction to C2+ Products by Adjusting the Local Reaction Environment with Polymer Binders", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The activity and selectivity of the electrochemical CO2 reduction reaction (CO2RR) are often hindered by the limited access of CO2 to the catalyst surface and overtaken by the competing hydrogen evolution reaction. Herein, it is revealed that polymers used as catalyst binders can effectively modulate the accessibility of CO2 relative to H2O at the vicinity of the catalyst and thus the performance of CO2RR. Three polymers with different hydrophilicities (i.e., polyacrylic acid (PAA), Nafion, and fluorinated ethylene propylene (FEP)) are selected as binders for Cu catalysts. At a thickness of only approximate to 1.2 nm, these binders strongly affect the activity and selectivity toward multi-carbon (C2+) products. The FEP coated catalyst exhibits a C2+ partial current density of over 600 mA cm(-2) with approximate to 77% faradaic efficiency at -0.76 V versus RHE. This high performance is attributed to the hydrophobic (aerophilic) properties of FEP, which reduces the local concentration of H2O and enhances that of the reactant (i.e., CO2) and the reaction intermediates (i.e., CO). These findings suggest that tuning the hydrophobicity of electrocatalysts with polymer binders can be a promising way to regulate the performance of electrochemical reactions involving gas-solid-liquid interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103663, "DOI": "10.1002/aenm.202103663", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103663", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000738965700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, Y; Bohn, BJ; Bladt, E; Wang, K; Müller-Buschbaum, P; Bals, S; Urban, AS; Polavarapu, L; Feldmann, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Yu; Bohn, Bernhard J.; Bladt, Eva; Wang, Kun; Mueller-Buschbaum, Peter; Bals, Sara; Urban, Alexander S.; Polavarapu, Lakshminarayana; Feldmann, Jochen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From Precursor Powders to CsPbX3 Perovskite nullowires: One-Pot Synthesis, Growth Mechanism, and Oriented Self-Assembly", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The colloidal synthesis and assembly of semiconductor nullowires continues to attract a great deal of interest. Herein, we describe the single-step ligand-mediated synthesis of single-crystalline CsPbBr3 perovskite nullowires (NWs) directly from the precursor powders. Studies of the reaction process and the morphological evolution revealed that the initially formed CsPbBr3 nullocubes are transformed into NWs through an oriented-attachment mechanism. The optical properties of the NWs can be tuned across the entire visible range by varying the halide (Cl, Br, and I) composition through subsequent halide ion exchange. Single-particle studies showed that these NWs exhibit strongly polarized emission with a polarization anisotropy of 0.36. More importantly, the NWs can self-assemble in a quasi-oriented fashion at an air/liquid interface. This process should also be easily applicable to perovskite nullocrystals of different morphologies for their integration into nulloscale optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2017, "Volume": 56, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13887, "End Page": 13892, "Article Number": null, "DOI": "10.1002/anie.201707224", "DOI Link": "http://dx.doi.org/10.1002/anie.201707224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413314800065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Slota, M; Keerthi, A; Myers, WK; Tretyakov, E; Baumgarten, M; Ardavan, A; Sadeghi, H; Lambert, CJ; Narita, A; Müllen, K; Bogani, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Slota, Michael; Keerthi, Ashok; Myers, William K.; Tretyakov, Evgeny; Baumgarten, Martin; Ardavan, Arzhang; Sadeghi, Hatef; Lambert, Colin J.; Narita, Akimitsu; Muellen, Klaus; Bogani, Lapo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic edge states and coherent manipulation of graphene nulloribbons", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene, a single-layer network of carbon atoms, has outstanding electrical and mechanical properties(1). Graphene ribbons with nullometre-scale widths(2,3) (nulloribbons) should exhibit half-metallicity(4) and quantum confinement. Magnetic edges in graphene nulloribbons(5,6) have been studied extensively from a theoretical standpoint because their coherent manipulation would be a milestone for spintronic(7) and quantum computing devices(8). However, experimental investigations have been hampered because nulloribbon edges cannot be produced with atomic precision and the graphene terminations that have been proposed are chemically unstable(9). Here we address both of these problems, by using molecular graphene nulloribbons functionalized with stable spin-bearing radical groups. We observe the predicted delocalized magnetic edge states and test theoretical models of the spin dynamics and spin-environment interactions. Comparison with a non-graphitized reference material enables us to clearly identify the characteristic behaviour of the radical-functionalized graphene nulloribbons. We quantify the parameters of spin-orbit coupling, define the interaction patterns and determine the spin decoherence channels. Even without any optimization, the spin coherence time is in the range of microseconds at room temperature, and we perform quantum inversion operations between edge and radical spins. Our approach provides a way of testing the theory of magnetism in graphene nulloribbons experimentally. The coherence times that we observe open up encouraging prospects for the use of magnetic nulloribbons in quantum spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2018, "Volume": 557, "Issue": 7707, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 691, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0154-7", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0154-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433412900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; Bi, DQ; Pellet, N; Xiao, CX; Li, Z; Berry, JJ; Zakeeruddin, SM; Zhu, K; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fei; Bi, Dongqin; Pellet, Norman; Xiao, Chuanxiao; Li, Zhen; Berry, Joseph J.; Zakeeruddin, Shaik Mohammed; Zhu, Kai; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressing defects through the synergistic effect of a Lewis base and a Lewis acid for highly efficient and stable perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving long-term operational stability at a high efficiency level for perovskite solar cells is the most challenging issue toward commercialization of this emerging photovoltaic technology. Here, we investigated the cooperation of a Lewis base and a Lewis acid by combining commercial bis-PCBM mixed isomers as the Lewis acid in the antisolvent and N-(4-bromophenyl)thiourea (BrPh-ThR) as the Lewis base in the perovskite solution precursor. The combination of the Lewis base and the Lewis acid synergistically passivates Pb2+ and PbX3- antisite defects, enlarges the perovskite grain size, and improves charge-carrier separation and transport, leading to improved device efficiency from 19.3% to 21.7%. In addition, this Lewis base and acid combination also suppresses moisture incursion and passivates pinholes generated in the hole-transporting layer. The unsealed devices remained at 93% of the initial efficiency value in ambient air (10-20% relative humidity) after 3600 h at 20-25 degrees C and dropped by 10% after 1500 h under continuous operation at 1-sun illumination and 55 degrees C in nitrogen with maximum power-point tracking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2018, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3480, "End Page": 3490, "Article Number": null, "DOI": "10.1039/c8ee02252f", "DOI Link": "http://dx.doi.org/10.1039/c8ee02252f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452317700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kondrakov, AO; Gesswein, H; Galdina, K; de Biasi, L; Meded, V; Filatova, EO; Schumacher, G; Wenzel, W; Hartmann, P; Brezesinski, T; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kondrakov, Aleksandr O.; Gesswein, Holger; Galdina, Kristina; de Biasi, Lea; Meded, Velimir; Filatova, Elena O.; Schumacher, Gerhard; Wenzel, Wolfgang; Hartmann, Pascal; Brezesinski, Torsten; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Transfer-Induced Lattice Collapse in Ni-Rich NCM Cathode Materials during Delithiation", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-rich LiNixCoyMnzO2 (NCM) cathode materials have great potential for application in next-generation lithium-ion batteries owing to their high specific capacity. However, they are subjected to severe structural changes upon (de)lithiation, which adversely affects the cycling stability. Herein, we investigate changes in crystal and electronic structure of NCM811 (80% Ni) at high states of charge by a combination of operando X-ray diffraction (XRD), operando hard X-ray absorption spectroscopy (hXAS), ex situ soft X-ray absorption spectroscopy (sXAS), and density functional theory (DFT) calculations and correlate the results with data from galvanostatic cycling in coin cells. XRD reveals a large decrease in unit cell volume from 101.38(1) to 94.26(2) angstrom(3) due to collapse of the interlayer spacing when x(Li) < 0.5 (decrease in c-axis from 14.469(1) angstrom at x(Li) = 0.6 to 13.732(2) angstrom at x(Li) = 0.25). hXAS shows that the shrinkage of the transition metal oxygen layer mainly originates from nickel oxidation. sXAS, together with DFT-based Bader charge analysis, indicates that the shrinkage of the interlayer, which is occupied by lithium, is induced by charge transfer between O 2p and partially filled Ni e(g) orbitals (resulting in decrease of oxygen-oxygen repulsion). Overall, the results demonstrate that high voltage operation of NCM811 cathodes is inevitably accompanied by charge-transfer-induced lattice collapse.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2017, "Volume": 121, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24381, "End Page": 24388, "Article Number": null, "DOI": "10.1021/acs.jpcc.7b06598", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.7b06598", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415140400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Q; Jia, Y; Wei, FF; Zhuang, LZ; Yang, DJ; Liu, JZ; Wang, X; Lin, S; Yuan, P; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Qin; Jia, Yi; Wei, Fenfei; Zhuang, Linzhou; Yang, Dongjiang; Liu, Jizi; Wang, Xin; Lin, Sen; Yuan, Pei; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the Activity of Co-N4-xCx in Atomic Metal Catalysts for Oxygen Reduction Catalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic metal catalysis (AMC) provides an effective way to enhance activity for the oxygen reduction reaction (ORR). Cobalt anchored on nitrogen-doped carbon materials have been extensively reported. The carbon-hosted Co-N-4 structure was widely considered as the active site; however, it is very rare to investigate the activity of Co partially coordinated with N, for example, Co-N4-xCx. Herein, the activity of Co-N4-xCx with tunable coordination environment is investigated as the active sites for ORR catalysis. The defect (di-vacancies) on carbon is essential for the formation of Co-N4-xCx. N species play two important roles in promoting the intrinsic activity of atomic metal catalyst: N coordinated with Co to manipulate the reactivity by modification of electronic distribution and N helped to trap more Co to increase the number of active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2020, "Volume": 59, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6122, "End Page": 6127, "Article Number": null, "DOI": "10.1002/anie.202000324", "DOI Link": "http://dx.doi.org/10.1002/anie.202000324", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512809100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, MM; Huang, JW; Liang, SQ; Shan, LT; Xie, XS; Yi, ZY; Wang, YR; Guo, S; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Mingming; Huang, Jiwu; Liang, Shuquan; Shan, Lutong; Xie, Xuesong; Yi, Zhenyu; Wang, Yiren; Guo, Shan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen Defects in β-MnO2 Enabling High-Performance Rechargeable Aqueous Zinc/Manganese Dioxide Battery", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous Zn/manganese dioxide (Zn/MnO2) batteries are attractive energy storage technology owing to their merits of low cost, high safety, and environmental friendliness. However, the beta-MnO2 cathode is still plagued by the sluggish ion insertion kinetics due to the relatively narrow tunneled pathway. Furthermore, the energy storage mechanism is under debate as well. Here, beta-MnO2 cathode with enhanced ion insertion kinetics is introduced by the efficient oxygen defect engineering strategy. Density functional theory computations show that the beta-MnO2 host structure is more likely for H+ insertion rather than Zn2+, and the introduction of oxygen defects will facilitate the insertion of H+ into beta-MnO2. This theoretical conjecture is confirmed by the capacity of 302 mA h g(-1) and capacity retention of 94% after 300 cydes in the assembled aqueous Zn/beta-MnO2 cell. These results highlight the potentials of defect engineering as a strategy of improving the electrochemical performance of beta-MnO2 in aqueous rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2020, "Volume": 23, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100797, "DOI": "10.1016/j.isci.2019.100797", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2019.100797", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508685200060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, LF; Liu, CP; Jiang, FL; Chen, QH; Zhang, LJ; Xue, H; Jiang, HL; Qian, JJ; Yuan, DQ; Hong, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Linfeng; Liu, Caiping; Jiang, Feilong; Chen, Qihui; Zhang, Linjie; Xue, Hui; Jiang, Hai-Long; Qian, Jinjie; Yuan, Daqiang; Hong, Maochun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Considering the rapid increase of CO2 emission, especially from power plants, there is a constant need for materials which can effectively eliminate post-combustion CO2 (the main component: CO2/N-2 = 15/85). Here, we show the design and synthesis of a Cu(II) metalorganic framework (FJI-H14) with a high density of active sites, which displays unusual acid and base stability and high volumetric uptake (171 cm(3) cm(-3)) of CO2 under ambient conditions (298 K, 1 atm), making it a potential adsorbing agent for post-combustion CO2. Moreover, CO2 from simulated post-combustion flue gas can be smoothly converted into corresponding cyclic carbonates by the FJI-H14 catalyst. Such high CO2 adsorption capacity and moderate catalytic activity may result from the synergistic effect of multiple active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1233, "DOI": "10.1038/s41467-017-01166-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01166-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414228800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, C; Li, YJ; Yang, Z; Chen, G; Yao, YG; Jiang, F; Kuang, YD; Pastel, G; Xie, H; Yang, B; Das, S; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Chao; Li, Yiju; Yang, Zhi; Chen, Guang; Yao, Yonggang; Jiang, Feng; Kuang, Yudi; Pastel, Glenn; Xie, Hua; Yang, Bao; Das, Siddhartha; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rich Mesostructures Derived from Natural Woods for Solar Steam Generation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A tree is a living energy-water system. Intensive study of tree-derived natural wood is of great significance for the sustainable development of human civilization and reduced dependence on nonrenewable resources. Here, we report on the mesostructures of several natural wood materials as well as their thermal conductivities and mechanical properties. We found that natural wood, including hardwood and softwood, possesses excellent hydrophilicity, an interconnected pore network, low thermal conductivity, and various mechanical properties. Inspired by the critical ecological energy-water nexus, high-efficiency solar steam generation based on natural wood is demonstrated in this work. The variation in multiple natural wood microstructures results in significantly different solar steam generation performances, with the more porous wood showing higher evaporation efficiency based on our results. The inherent rich mesostructures, aligned microchannels, and favorable hydrophilicity enable natural wood materials to be applied in many other fields of the energy-water nexus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 588, "End Page": 599, "Article Number": null, "DOI": "10.1016/j.joule.2017.09.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.09.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425301500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CY; Lin, HY; Chiang, KM; Tsai, WL; Huang, YC; Tsao, CS; Lin, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chien-Yu; Lin, Hung-Yu; Chiang, Kai-Ming; Tsai, Wei-Lun; Huang, Yu-Ching; Tsao, Cheng-Si; Lin, Hao-Wu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Vacuum-Deposited Stoichiometrically Balanced Inorganic Cesium Lead Halide Perovskite Solar Cells with Stabilized Efficiency Exceeding 11%", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vacuum-sublimed inorganic cesium lead halide perovskite thin films are prepared and integrated in all-vacuum-deposited solar cells. Special care is taken to determine the stoichiometric balance of the sublimation precursors, which has great influence on the device performance. The mixed halide devices exhibit exceptional stabilized power conversion efficiency (11.8%) and promising thermal and long-term stabilities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2017, "Volume": 29, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605290, "DOI": "10.1002/adma.201605290", "DOI Link": "http://dx.doi.org/10.1002/adma.201605290", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396998800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peto, J; Ollár, T; Vancsó, P; Popov, ZI; Magda, GZ; Dobrik, G; Hwang, CY; Sorokin, PB; Tapasztó, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peto, Janos; Ollar, Tamas; Vancso, Peter; Popov, Zakhar I.; Magda, Gabor Zsolt; Dobrik, Gergely; Hwang, Chanyong; Sorokin, Pavel B.; Tapaszto, Levente", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous doping of the basal plane of MoS2 single layers through oxygen substitution under ambient conditions", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The chemical inertness of the defect-free basal plane confers environmental stability to MoS2 single layers, but it also limits their chemical versatility and catalytic activity. The stability of pristine MoS2 basal plane against oxidation under ambient conditions is a widely accepted assumption however, here we report single-atom-level structural investigations that reveal that oxygen atoms spontaneously incorporate into the basal plane of MoS2 single layers during ambient exposure. The use of scanning tunnelling microscopy reveals a slow oxygen-substitution reaction, during which individual sulfur atoms are replaced one by one by oxygen, giving rise to solid-solution-type 2D MoS2-xOx crystals. Oxygen substitution sites present all over the basal plane act as single-atom reaction centres, substantially increasing the catalytic activity of the entire MoS2 basal plane for the electrochemical H-2 evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 10, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1246, "End Page": 1251, "Article Number": null, "DOI": "10.1038/s41557-018-0136-2", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0136-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450790300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, SS; Fowler, C; Zheng, BW; Shalaginov, MY; Tang, H; Li, H; Zhou, L; Ding, J; Agarwal, AM; Rivero-Baleine, C; Richardson, KA; Gu, T; Hu, JJ; Zhang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Sensong; Fowler, Clayton; Zheng, Bowen; Shalaginov, Mikhail Y.; Tang, Hong; Li, Hang; Zhou, Li; Ding, Jun; Agarwal, Anuradha Murthy; Rivero-Baleine, Clara; Richardson, Kathleen A.; Gu, Tian; Hu, Juejun; Zhang, Hualiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Deep Learning Approach for Objective-Driven All-Dielectric Metasurface Design", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces have become a promising means for manipulating optical wavefronts in flat and high-performance optical devices. Conventional metasurface device design relies on trial-and-error methods to obtain target electromagnetic (EM) responses, an approach that demands significant efforts to investigate the enormous number of possible meta-atom structures. In this paper, a deep learning modeling approach is introduced that significantly improves on both speed and accuracy compared to techniques currently used to characterize the subwavelength optical structures. Our neural network approach overcomes two key challenges that have limited previous neural-network-based design schemes: input/output vector dimensional mismatch and accurate EM-wave phase prediction. Additionally, this is the first neural network to characterize 3-D dielectric structures. By combining with optimization algorithms or neural networks, this approach can be generically applied to a wide variety of metasurface device designs across the entire electromagnetic spectrum. Using this new methodology, examples of neural networks capable of producing on-demand designs for meta-atoms, metasurface filters, and phase-change reconfigurable metasurfaces are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3196, "End Page": 3207, "Article Number": null, "DOI": "10.1021/acsphotonics.9b00966", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.9b00966", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503918700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Novelino, LS; Ze, QJ; Wu, S; Paulino, GH; Zhao, RK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Novelino, Larissa S.; Ze, Qiji; Wu, Shuai; Paulino, Glaucio H.; Zhao, Ruike", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Untethered control of functional origami microrobots with distributed actuation", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deployability, multifunctionality, and tunability are features that can be explored in the design space of origami engineering solutions. These features arise from the shape-changing capabilities of origami assemblies, which require effective actuation for full functionality. Current actuation strategies rely on either slow or tethered or bulky actuators (or a combination). To broaden applications of origami designs, we introduce an origami system with magnetic control. We couple the geometrical and mechanical properties of the bistable Kresling pattern with a magnetically responsive material to achieve untethered and local/distributed actuation with controllable speed, which can be as fast as a tenth of a second with instantaneous shape locking. We show how this strategy facilitates multimodal actuation of the multicell assemblies, in which any unit cell can be independently folded and deployed, allowing for on-the-fly programmability. In addition, we demonstrate how the Kresling assembly can serve as a basis for tunable physical properties and for digital computing. The magnetic origami systems are applicable to origami-inspired robots, morphing structures and devices, metamaterials, and multifunctional devices with multiphysics responses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 29", "Publication Year": 2020, "Volume": 117, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24096, "End Page": 24101, "Article Number": null, "DOI": "10.1073/pnas.2013292117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2013292117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000576664200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YB; Zhang, P; Yang, ZC; Li, LN; Gao, JY; Chen, S; Xie, TF; Diao, CZ; Xi, SB; Xiao, BB; Hu, C; Choi, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yubao; Zhang, Peng; Yang, Zhenchun; Li, Lina; Gao, Jingyu; Chen, Sheng; Xie, Tengfeng; Diao, Caozheng; Xi, Shibo; Xiao, Beibei; Hu, Chun; Choi, Wonyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanistic analysis of multiple processes controlling solar-driven H2O2 synthesis using engineered polymeric carbon nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven hydrogen peroxide (H2O2) production presents unique merits of sustainability and environmental friendliness. Herein, efficient solar-driven H2O2 production through dioxygen reduction is achieved by employing polymeric carbon nitride framework with sodium cyanaminate moiety, affording a H2O2 production rate of 18.7 mu mol h (-1) mg(-1) and an apparent quantum yield of 27.6% at 380nm. The overall photocatalytic transformation process is systematically analyzed, and some previously unknown structural features and interactions are substantiated via experimental and theoretical methods. The structural features of cyanamino group and pyridinic nitrogen-coordinated soidum in the framework promote photon absorption, alter the energy landscape of the framework and improve charge separation efficiency, enhance surface adsorption of dioxygen, and create selective 2e(-) oxygen reduction reaction surface-active sites. Particularly, an electronic coupling interaction between O-2 and surface, which boosts the population and prolongs the lifetime of the active shallow-trapped electrons, is experimentally substantiated. Solar-driven H2O2 production presents a renewable approach to chemical synthesis. Here, authors perform a mechanistic analysis on the contribution of the sodium cyanaminate moiety to the 2-electron oxygen reduction reaction performance of polymeric carbon nitride frameworks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3701, "DOI": "10.1038/s41467-021-24048-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24048-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665032700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Zhang, JH; Li, YP; Qian, QZ; Li, ZY; Zhu, Y; Zhang, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yi; Zhang, Jihua; Li, Yapeng; Qian, Qizhu; Li, Ziyun; Zhu, Yin; Zhang, Genqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulating dehydrogenation kinetics through dual-doping Co3N electrode enables highly efficient hydrazine oxidation assisting self-powered H2 production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Replacing sluggish oxygen evolution reaction (OER) with hydrazine oxidation reaction (HzOR) to produce hydrogen has been considered as a more energy-efficient strategy than water splitting. However, the relatively high cell voltage in two-electrode system and the required external electric power hinder its scalable applications, especially in mobile devices. Herein, we report a bifunctional P, W co-doped Co3N nullowire array electrode with remarkable catalytic activity towards both HzOR (-55 mV at 10 mA cm(-2)) and hydrogen evolution reaction (HER, -41 mV at 10 mA cm(-2)). Inspiringly, a record low cell voltage of 28 mV is required to achieve 10 mA cm(-2) in two-electrode system. DFT calculations decipher that the doping optimized H* adsorption/desorption and dehydrogenation kinetics could be the underlying mechanism. Importantly, a self-powered H-2 production system by integrating a direct hydrazine fuel cell with a hydrazine splitting electrolyzer can achieve a decent rate of 1.25 mmol h(-1) at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1853, "DOI": "10.1038/s41467-020-15563-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15563-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564285200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mittal, N; Ansari, F; Gowda, VK; Brouzet, C; Chen, P; Larsson, PT; Roth, SV; Lundell, F; Wågberg, L; Kotov, NA; Söderberg, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mittal, Nitesh; Ansari, Farhan; Gowda, Krishne, V; Brouzet, Christophe; Chen, Pan; Larsson, Per Tomas; Roth, Stephan V.; Lundell, Fredrik; Wagberg, Lars; Kotov, Nicholas A.; Soderberg, L. Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiscale Control of nullocellulose Assembly: Transferring Remarkable nulloscale Fibril Mechanics to Macroscale Fibers", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale building blocks of many materials exhibit extraordinary mechanical properties due to their defect-free molecular structure. Translation of these high mechanical properties to macroscopic materials represents a difficult materials engineering challenge due to the necessity to organize these building blocks into multiscale patterns and mitigate defects emerging at larger scales. Cellulose nullofibrils (CNFs), the most abundant structural element in living systems, has impressively high strength and stiffness, but natural or artificial cellulose composites are 3-15 times weaker than the CNFs. Here, we report the flow-assisted organization of CNFs into macroscale fibers with nearly perfect unidirectional alignment. Efficient stress transfer from macroscale to individual CNF due to cross-linking and high degree of order enables their Young's modulus to reach up to 86 GPa and a tensile strength of 1.57 GPa, exceeding the mechanical properties of known natural or synthetic biopolymeric materials. The specific strength of our CNF fibers engineered at multiscale also exceeds that of metals, alloys, and glass fibers, enhancing the potential of sustainable lightweight high-performance materials with multiscale self-organization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 12, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6378, "End Page": 6388, "Article Number": null, "DOI": "10.1021/acsnullo.8b01084", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b01084", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440505000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YC; Chi, YD; Sun, JF; Huang, ZH; Maghsoudi, OH; Spence, A; Zhao, JG; Su, H; Yin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yichao; Chi, Yinding; Sun, Jiefeng; Huang, Tzu-Hao; Maghsoudi, Omid H.; Spence, Andrew; Zhao, Jianguo; Su, Hao; Yin, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Leveraging elastic instabilities for amplified performance: Spine-inspired high-speed and high-force soft robots", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft machines typically exhibit slow locomotion speed and low manipulation strength because of intrinsic limitations of soft materials. Here, we present a generic design principle that harnesses mechanical instability for a variety of spine-inspired fast and strong soft machines. Unlike most current soft robots that are designed as inherently and unimodally stable, our design leverages tunable snap-through bistability to fully explore the ability of soft robots to rapidly store and release energy within tens of milliseconds. We demonstrate this generic design principle with three high-performance soft machines: High-speed cheetah-like galloping crawlers with locomotion speeds of 2.68 body length/s, high-speed underwater swimmers (0.78 body length/s), and tunable low-to-high-force soft grippers with over 1 to 10(3 )stiffness modulation (maximum load capacity is 11.4 kg). Our study establishes a new generic design paradigm of next-generation high-performance soft robots that are applicable for multifunctionality, different actuation methods, and materials at multiscales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 6, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz6912", "DOI": "10.1126/sciadv.aaz6912", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz6912", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531171100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, LJ; Sun, DW; Pu, HB; Zhang, CY; Zhang, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Lunjie; Sun, Da-Wen; Pu, Hongbin; Zhang, Cuiyun; Zhang, Daorui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose-based polymeric nullozyme as bioinspired spray coating for fruit preservation", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growing concerns about microbial food safety and environmental contamination call for sustainable food active packaging materials and practices with high performance. This contribution proposed a biocatalytic spraying coating for fruit preservation using carboxymethyl cellulose nullofibers grafting enzyme-like metal-organic frameworks (CNF@Ce-MOF) with banulla and mango as model fruits. The well-characterized biohybrid nullofibers were verified to simultaneously mimic good oxidase-like and apyrase-like activities, enabling effective enzyme-like sterilization against three typical foodborne pathogens, i.e. Escherichia coli O157: H7, Staphylococcus aureus, and methicillin-resistant Staphylococcus aureus, reaching killing rates as high as 90.46%. The biocidal center dot O-2(-) generation and adenosine triphosphate depletion were the possible mechanisms causing the nonspecific bacteria death. Such antibacterial performance, as well as additional protective properties of CNF@Ce-MOF, facilitated the quality preservation during the 12-day storage of banullas and mangos by spray coating with the biomimetic CNF@Ce-MOF. It is expected that this work walks out the first step of nullozyme toward active packaging engineering for the fields of food, agriculture, and biomedicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108138, "DOI": "10.1016/j.foodhyd.2022.108138", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2022.108138", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870463200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, K; Li, LS; Lai, TQ; Xiao, LG; Huang, Y; Huang, F; Peng, JB; Cao, Y; Liu, F; Russell, TP; Janssen, RAJ; Peng, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Ke; Li, Lisheng; Lai, Tianqi; Xiao, Liangang; Huang, Yuan; Huang, Fei; Peng, Junbiao; Cao, Yong; Liu, Feng; Russell, Thomas P.; Janssen, Rene A. J.; Peng, Xiaobin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Absorbing Porphyrin Small Molecule for High-Performance Organic Solar Cells with Very Low Energy Losses", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We designed and synthesized the DPPEZnP-TEH molecule, With a porphyrin ring linked to two diketopyrrolopyrrole units by ethynylene bridges. The resulting material exhibits a very low energy band gap of 1.37 eV and a broad light absorption to 907 nth. An open-circuit voltage of 0:78 V was obtained in bulk heterojunction (BHJ) organic solar cells, showing a low energy loss of only 0.59 eV,. Which is the first report that small molecule solar cells show energy losses <0.6 eV. The optimized solar cells show remarkable external quantum efficiency, short circuit current, and power conversion efficiency up to 65%, 16.76 mA/cm(2), and 8.08%, respectively, which are the best values for BHJ solar cells with very low energy losses. Additionally, the morphology of DPPEZnP-TEH neat and blend films with PC61BM was studied thoroughly by grazing incidence X-ray diffraction, resonullt soft X-ray scattering, and transmission electron microscopy under different fabrication conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 435, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2015, "Volume": 137, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7282, "End Page": 7285, "Article Number": null, "DOI": "10.1021/jacs.5b03740", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b03740", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356753700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, J; Yu, Q; Asta, M; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Jun; Yu, Qin; Asta, Mark; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable stacking fault energies by tailoring local chemical order in CrCoNi medium-entropy alloys", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) are an intriguing new class of metallic materials due to their unique mechanical behavior. Achieving a detailed understanding of structure-property relationships in these materials has been challenged by the compositional disorder that underlies their unique mechanical behavior. Accordingly, in this work, we employ first-principles calculations to investigate the nature of local chemical order and establish its relationship to the intrinsic and extrinsic stacking fault energy (SFE) in CrCoNi medium-entropy solid-solution alloys, whose combination of strength, ductility, and toughness properties approaches the best on record. We find that the average intrinsic and extrinsic SFE are both highly tunable, with values ranging from -43 to 30 mJ.m(-2) and from -28 to 66 mJ.m(-2), respectively, as the degree of local chemical order increases. The state of local ordering also strongly correlates with the energy difference between the face-centered cubic (fcc) and hexagonal close-packed (hcp) phases, which affects the occurrence of transformation-induced plasticity. This theoretical study demonstrates that chemical short-range order is thermodynamically favored in HEAs and can be tuned to affect the mechanical behavior of these alloys. It thus addresses the pressing need to establish robust processing-structure-property relationships to guide the science-based design of new HEAs with targeted mechanical behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 634, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2018, "Volume": 115, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8919, "End Page": 8924, "Article Number": null, "DOI": "10.1073/pnas.1808660115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1808660115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443555000047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sha, WEI; Ren, XG; Chen, LZ; Choy, WCH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sha, Wei E. I.; Ren, Xingang; Chen, Luzhou; Choy, Wallace C. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The efficiency limit of CH3NH3PbI3 perovskite solar cells", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the consideration of photon recycling effect, the efficiency limit of methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells is predicted by a detailed balance model. To obtain convincing predictions, both AM 1.5 spectrum of Sun and experimentally measured complex refractive index of perovskite material are employed in the detailed balance model. The roles of light trapping and angular restriction in improving the maximal output power of thin-film perovskite solar cells are also clarified. The efficiency limit of perovskite cells (without the angular restriction) is about 31%, which approaches to Shockley-Queisser limit (33%) achievable by gallium arsenide (GaAs) cells. Moreover, the Shockley-Queisser limit could be reached with a 200 nm-thick perovskite solar cell, through integrating a wavelength-dependent angular-restriction design with a textured light-trapping structure. Additionally, the influence of the trap-assisted nonradiative recombination on the device efficiency is investigated. The work is fundamentally important to high-performance perovskite photovoltaics. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 512, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2015, "Volume": 106, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 221104, "DOI": "10.1063/1.4922150", "DOI Link": "http://dx.doi.org/10.1063/1.4922150", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355924700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, J; Huang, X; Liu, LZ; Wang, M; Wang, L; Huang, B; Zhu, DD; Li, JJ; Gu, CZ; Meng, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Jing; Huang, Xing; Liu, Ling-Zhi; Wang, Meng; Wang, Lei; Huang, Ben; Zhu, Dan-Dan; Li, Jun-Jie; Gu, Chang-Zhi; Meng, Xiang-Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CVD synthesis of large-area, highly crystalline MoSe2 atomic layers on diverse substrates and application to photodetectors", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthesis of large-area, atomically thin transition metal dichalcogenides (TMDs) on diverse substrates is of central importance for the large-scale fabrication of flexible devices and heterojunction-based devices. In this work, we successfully synthesized a large area of highly-crystalline MoSe2 atomic layers on SiO2/Si, mica and Si substrates using a simple chemical vapour deposition (CVD) method at atmospheric pressure. Atomic force microscopy (AFM) and Raman spectroscopy reveal that the as-grown ultrathin MoSe2 layers change from a single layer to a few layers. Photoluminescence (PL) spectroscopy demonstrates that white the multi-layer MoSe2 shows weak emission peaks, the monolayer has a much stronger emission peak at similar to 1.56 eV, indicating the transition from an indirect to a direct bandgap. Transmission electron microscopy (TEM) analysis confirms the single-crystallinity of MoSe2 layers with a hexagonal structure. In addition, the photoresponse performance of photodetectors based on MoSe2 monolayer was studied for the first time. The devices exhibit a rapid response of similar to 60 ms and a good photoresponsivity of similar to 13 mA/W (using a 532 nm laser at an intensity of 1 mW mm(-2) and a bias of 10 V), suggesting that MoSe2 monolayer is a promising material for photodetection applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2014, "Volume": 6, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8949, "End Page": 8955, "Article Number": null, "DOI": "10.1039/c4nr02311k", "DOI Link": "http://dx.doi.org/10.1039/c4nr02311k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339861500071", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Haldar, S; Wang, MC; Bhauriyal, P; Hazra, A; Khan, AH; Bon, V; Isaacs, MA; De, A; Shupletsov, L; Boenke, T; Grothe, J; Heine, T; Brunner, E; Feng, XL; Dong, RH; Schneemann, A; Kaskel, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Haldar, Sattwick; Wang, Mingchao; Bhauriyal, Preeti; Hazra, Arpan; Khan, Arafat H.; Bon, Volodymyr; Isaacs, Mark A.; De, Ankita; Shupletsov, Leonid; Boenke, Tom; Grothe, Julia; Heine, Thomas; Brunner, Eike; Feng, Xinliang; Dong, Renhao; Schneemann, Andreas; Kaskel, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Dithiine-Linked Covalent Organic Framework as a Dynamic Platform for Covalent Polysulfide Anchoring in Lithium-Sulfur Battery Cathodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dithiine linkage formation via a dynamic and self-correctingnucleophilic aromatic substitution reaction enables the de novo synthesis of aporous thianthrene-based two-dimensional covalent organic framework(COF). For thefirst time, this organo-sulfur moiety is integrated as astructural building block into a crystalline layered COF. The structure of thenew material deviates from the typical planar interlayer pi-stacking of the COFto form undulated layers caused by bending along the C-S-C bridge,without loss of aromaticity and crystallinity of the overall COF structure.Comprehensive experimental and theoretical investigations of the COF and amodel compound, featuring the thianthrene moiety, suggest partialdelocalization of sulfur lone pair electrons over the aromatic backbone ofthe COF decreasing the band gap and promoting redox activity. Postsynthetic sulfurization allows for direct covalent attachment ofpolysulfides to the carbon backbone of the framework to afford a molecular-designed cathode material for lithium-sulfur (Li-S)batteries with a minimized polysulfide shuttle. The fabricated coin cell delivers nearly 77% of the initial capacity even after 500charge-discharge cycles at 500 mA/g current density. This novel sulfur linkage in COF chemistry is an ideal structural motif fordesigning model materials for studying advanced electrode materials for Li-S batteries on a molecular level", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2022, "Volume": 144, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9101, "End Page": 9112, "Article Number": null, "DOI": "10.1021/jacs.2c02346", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c02346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805981500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MY; Zhao, N; Yu, Q; Liu, ZQ; Qu, RT; Zhang, J; Li, SJ; Ren, DC; Berto, F; Zhang, ZF; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mingyang; Zhao, Ning; Yu, Qin; Liu, Zengqian; Qu, Ruitao; Zhang, Jian; Li, Shujun; Ren, Dechun; Berto, Filippo; Zhang, Zhefeng; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the damage tolerance of 3-D printed Mg-Ti interpenetrating-phase composites with bioinspired architectures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioinspired architectures are desired to achieve improved mechanical properties, but challenging to achieve in metallic systems. Here the authors fabricate a Mg-Ti interpenetrating phase composite with brick-and-mortar, Bouligand, and crossed-lamellar architectures by pressureless infiltrating method. Bioinspired architectures are effective in enhancing the mechanical properties of materials, yet are difficult to construct in metallic systems. The structure-property relationships of bioinspired metallic composites also remain unclear. Here, Mg-Ti composites were fabricated by pressureless infiltrating pure Mg melt into three-dimensional (3-D) printed Ti-6Al-4V scaffolds. The result was composite materials where the constituents are continuous, mutually interpenetrated in 3-D space and exhibit specific spatial arrangements with bioinspired brick-and-mortar, Bouligand, and crossed-lamellar architectures. These architectures promote effective stress transfer, delocalize damage and arrest cracking, thereby bestowing improved strength and ductility than composites with discrete reinforcements. Additionally, they activate a series of extrinsic toughening mechanisms, including crack deflection/twist and uncracked-ligament bridging, which enable crack-tip shielding from the applied stress and lead to Gamma-shaped rising fracture resistance R-curves. Quantitative relationships were established for the stiffness and strengths of the composites by adapting classical laminate theory to incorporate their architectural characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3247, "DOI": "10.1038/s41467-022-30873-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30873-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808000200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Soe, CMM; Stoumpos, CC; Kepenekian, M; Traoré, B; Tsai, H; Nie, WY; Wang, BH; Katan, C; Seshadri, R; Mohite, AD; Eyen, J; Marks, TJ; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Kepenekian, Mikael; Traore, Boubacar; Tsai, Hsinhan; Nie, Wanyi; Wang, Binghao; Katan, Claudine; Seshadri, Ram; Mohite, Aditya D.; Eyen, Jacky; Marks, Tobin J.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, Properties, and Photovoltaic Performance", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the new homologous series (C(NH2)(3))-(CH3NH3)(n)PbnI3n+1 (n = 1, 2, 3) of layered 2D perovskites. Structural characterization by single-crystal X-ray diffraction reveals that these compounds adopt an unprecedented structure type, which is stabilized by the alternating ordering of the guanidinium and methylammonium cations in the interlayer space (ACI). Compared to the more common Ruddlesden-Popper (RP) 2D perovskites, the ACI perovskites have a different stacking motif and adopt a higher crystal symmetry. The higher symmetry of the ACI perovskites is expressed in their physical properties, which show a characteristic decrease of the bandgap with respect to their RP perovskite counterparts with the same perovskite layer thickness (n). The compounds show a monotonic decrease in the optical gap as n increases: E-g = 2.27 eV for n = 1 to E-g = 1.99 eV for n = 2 and E-g = 1.73 eV for n = 3, which show slightly narrower gaps compared to the corresponding RP perovskites. First principles theoretical electronic structure calculations confirm the experimental optical gap trends suggesting that the ACI perovskites are direct bandgap semiconductors with wide valence and conduction bandwidths. To assess the potential of the ACI perovskites toward solar cell applications, we studied the (C(NH2)(3))-(CH3NH3)(3)Pb3I10 (n = 3) compound. Compact thin films from the (C(NH2)(3))(CH3NH3)(3)Pb3I10 compound with excellent surface coverage can be obtained from the antisolvent dripping method. Planar photovoltaic devices from optimized ACI perovskite films yield a power-conversion-efficiency of 7.26% with a high open-circuit voltage of similar to 1 V and a striking fill factor of similar to 80%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 139, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16297, "End Page": 16309, "Article Number": null, "DOI": "10.1021/jacs.7b09096", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b09096", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415785900045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, H; Chen, BK; Wang, ZG; Hung, TF; Susha, AS; Zhong, HZ; Rogach, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, He; Chen, Bingkun; Wang, Zhenguang; Hung, Tak Fu; Susha, Andrei S.; Zhong, Haizheng; Rogach, Andrey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water resistant CsPbX3 nullocrystals coated with polyhedral oligomeric silsesquioxane and their use as solid state luminophores in all-perovskite white light-emitting devices", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an approach towards stable solid-state perovskite based luminophores with different emission colors via surface protection of CsPbX3 (X = Br or I) with a polyhedral oligomeric silsesquioxane (POSS). This treatment results in water resistant perovskite nullocrystal powders, and prevents otherwise easy anion exchange between perovskite nullocrystals of different compositions mixed together in the solid state, which allows us to preserve their distinct emission spectra. We subsequently used mixtures of green-emitting POSS-CsPbBr3 and red-emitting POSS-CsPb(Br/I)(3) nullocrystal powders to fabricate single layer all-perovskite down conversion white light-emitting devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5699, "End Page": 5703, "Article Number": null, "DOI": "10.1039/c6sc01758d", "DOI Link": "http://dx.doi.org/10.1039/c6sc01758d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382488500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZD; Zhu, ML; Zhang, ZX; Chen, ZC; Shi, QF; Shan, XC; Yeow, RCH; Lee, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zhongda; Zhu, Minglu; Zhang, Zixuan; Chen, Zhaocong; Shi, Qiongfeng; Shan, Xuechuan; Yeow, Raye Chen Hua; Lee, Chengkuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial Intelligence of Things (AIoT) Enabled Virtual Shop Applications Using Self-Powered Sensor Enhanced Soft Robotic Manipulator", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid advancements of artificial intelligence of things (AIoT) technology pave the way for developing a digital-twin-based remote interactive system for advanced robotic-enabled industrial automation and virtual shopping. The embedded multifunctional perception system is urged for better interaction and user experience. To realize such a system, a smart soft robotic manipulator is presented that consists of a triboelectric nullogenerator tactile (T-TENG) and length (L-TENG) sensor, as well as a poly(vinylidene fluoride) (PVDF) pyroelectric temperature sensor. With the aid of machine learning (ML) for data processing, the fusion of the T-TENG and L-TENG sensors can realize the automatic recognition of the grasped objects with the accuracy of 97.143% for 28 different shapes of objects, while the temperature distribution can also be obtained through the pyroelectric sensor. By leveraging the IoT and artificial intelligence (AI) analytics, a digital-twin-based virtual shop is successfully implemented to provide the users with real-time feedback about the details of the product. In general, by offering a more immersive experience in human-machine interactions, the proposed remote interactive system shows the great potential of being the advanced human-machine interface for the applications of the unmanned working space.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100230, "DOI": "10.1002/advs.202100230", "DOI Link": "http://dx.doi.org/10.1002/advs.202100230", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654319800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HM; Li, YB; Li, M; Chen, K; Liang, K; Chen, GX; Lu, J; Palisaitis, J; Persson, POA; Eklund, P; Hultman, L; Du, SY; Chai, ZF; Gogotsi, Y; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Haoming; Li, Youbing; Li, Mian; Chen, Ke; Liang, Kun; Chen, Guoxin; Lu, Jun; Palisaitis, Justinas; Persson, Per O. A.; Eklund, Per; Hultman, Lars; Du, Shiyu; Chai, Zhifang; Gogotsi, Yury; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical scissor-mediated structural editing of layered transition metal carbides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intercalated layered materials offer distinctive properties and serve as precursors for important two-dimensional (2D) materials. However, intercalation of non-van der Waals structures, which can expand the family of 2D materials, is difficult. We report a structural editing protocol for layered carbides (MAX phases) and their 2D derivatives (MXenes). Gap-opening and species-intercalating stages were respectively mediated by chemical scissors and intercalants, which created a large family of MAX phases with unconventional elements and structures, as well as MXenes with versatile terminals. The removal of terminals in MXenes with metal scissors and then the stitching of 2D carbide nullosheets with atom intercalation leads to the reconstruction of MAX phases and a family of metal-intercalated 2D carbides, both of which may drive advances in fields ranging from energy to printed electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2023, "Volume": 379, "Issue": 6637, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1130, "End Page": 1135, "Article Number": null, "DOI": "10.1126/science.add5901", "DOI Link": "http://dx.doi.org/10.1126/science.add5901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959028800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, YX; Chen, DR; Chen, WJ; Zhang, WX; Su, X; Deng, RR; An, ZF; Chen, HM; Xie, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Yixi; Chen, Dunrong; Chen, Wenjing; Zhang, Wenxing; Su, Xin; Deng, Renren; An, Zhongfu; Chen, Hongmin; Xie, Rong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "X-ray-charged bright persistent luminescence in NaYF4:Ln3+@NaYF4 nulloparticles for multidimensional optical information storage", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NaYF4:Ln(3+), due to its outstanding upconversion characteristics, has become one of the most important luminescent nullomaterials in biological imaging, optical information storage, and anticounterfeiting applications. However, the large specific surface area of NaYF4:Ln(3+) nulloparticles generally leads to serious nonradiative transitions, which may greatly hinder the discovery of new optical functionality with promising applications. In this paper, we report that monodispersed nulloscale NaYF4:Ln(3+), unexpectedly, can also be an excellent persistent luminescent (PersL) material. The NaYF4:Ln(3+) nulloparticles with surface-passivated core-shell structures exhibit intense X-ray-charged PersL and narrow-band emissions tunable from 480 to 1060 nm. A mechanism for PersL in NaYF4:Ln(3+) is proposed by means of thermoluminescence measurements and host-referred binding energy (HRBE) scheme, which suggests that some lanthanide ions (such as Tb) may also act as effective electron traps to achieve intense PersL. The uniform and spherical NaYF4:Ln(3+) nulloparticles are dispersible in solvents, thus enabling many applications that are not accessible for traditional PersL phosphors. A new 3-dimensional (2 dimensions of planar space and 1 dimension of wavelength) optical information-storage application is demonstrated by inkjet-printing multicolor PersL nulloparticles. The multicolor persistent luminescence, as an emerging and promising emissive mode in NaYF4:Ln(3+), will provide great opportunities for nullomaterials to be applied to a wider range of fields. Core-shelled nulloparticles NaYF4:Ln(3+)@NaYF4 with multicolor narrow-band persistent luminescence enable a new multidimensional optical information-storage technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 132, "DOI": "10.1038/s41377-021-00575-w", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00575-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000664990900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, QH; Odeh, M; Zúñiga-Pérez, J; Kanté, B; Genevet, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Qinghua; Odeh, Mutasem; Zuniga-Perez, Jesus; Kante, Boubacar; Genevet, Patrice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic topological metasurface by encircling an exceptional point", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Resonullt scattering, guided mode propagation phase, and/or orientation-dependent phase retardations are the three main mechanisms used to date to conceive optical metasurfaces. Here, we introduce an additional degree of freedom to address optical phase engineering by exploiting the topological features of non-Hermitian matrices operating near their singular points. Choosing metasurface building blocks to encircle a singularity following an arbitrarily closed trajectory in parameter space, we engineered a topologically protected full 2p-phase on a specific reflected polarization channel. The ease of implementation together with its compatibility with other phase-addressing mechanisms bring topological properties into the realm of industrial applications at optical frequencies and prove that metasurface technology represents a convenient test bench to study and validate topological photonic concepts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2021, "Volume": 373, "Issue": 6559, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1133, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj3179", "DOI Link": "http://dx.doi.org/10.1126/science.abj3179", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692910300046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, LJ; Guo, HX; deQuilettes, DW; Jariwala, S; De Marco, N; Dong, SQ; DeBlock, R; Ginger, DS; Dunn, B; Wang, MK; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Lijian; Guo, Hexia; deQuilettes, Dane W.; Jariwala, Sarthak; De Marco, Nicholas; Dong, Shiqi; DeBlock, Ryan; Ginger, David S.; Dunn, Bruce; Wang, Mingkui; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The solution processing of polycrystalline perovskite films introduces trap states that can adversely affect their optoelectronic properties. Motivated by the use of small-molecule surfactants to improve the optoelectronic performance of perovskites, we demonstrate the use of polymers with coordinating groups to improve the performance of solution-processed semiconductor films. The use of these polymer modifiers results in a marked change in the electronic properties of the films, as measured by both carrier dynamics and overall device performance. The devices grown with the polymer poly(4-vinylpyridine) (PVP) show significantly enhanced power conversion efficiency from 16.9 +/- 0.7% to 18.8 +/- 0.8% (champion efficiency, 20.2%) from a reverse scan and stabilized champion efficiency from 17.5 to 19.1% [under a bias of 0.94 V and AM (air mass) 1.5-G, 1-sun illumination over 30 min] compared to controls without any passivation. Treating the perovskite film with PVP enables a VOC of up to 1.16 V, which is among the best reported for a CH3NH3PbI3 perovskite solar cell and one of the lowest voltage deficits reported for any perovskite to date. In addition, perovskite solar cells treated with PVP show a long shelf lifetime of up to 90 days (retaining 85% of the initial efficiency) and increased by a factor of more than 20 compared to those without any polymer (degrading to 85% after similar to 4 days). Our work opens up a new class of chemical additives for improving perovskite performance and should pave the way toward improving perovskite solar cells for high efficiency and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 664, "Times Cited, All Databases": 708, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700106", "DOI": "10.1126/sciadv.1700106", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700106", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411589900058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JW; Dai, ZH; Han, TH; Choi, C; Chang, SY; Lee, SJ; De Marco, N; Zhao, HX; Sun, PY; Huang, Y; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jin-Wook; Dai, Zhenghong; Han, Tae-Hee; Choi, Chungseok; Chang, Sheng-Yung; Lee, Sung-Joon; De Marco, Nicholas; Zhao, Hongxiang; Sun, Pengyu; Huang, Yu; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D perovskite stabilized phase-pure formamidinium perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compositional engineering has been used to overcome difficulties in fabricating high-quality phase-pure formamidinium perovskite films together with its ambient instability. However, this comes alongside an undesirable increase in bandgap that sacrifices the device photo-current. Here we report the fabrication of phase-pure formamidinium-lead tri-iodide perovskite films with excellent optoelectronic quality and stability. Incorporation of 1.67 mol% of 2D phenylethylammonium lead iodide into the precursor solution enables the formation of phase-pure formamidinium perovskite with an order of magnitude enhanced photoluminescence lifetime. The 2D perovskite spontaneously forms at grain boundaries to protect the formamidinium perovskite from moisture and suppress ion migration. A stabilized power conversion efficiency (PCE) of 20.64% (certified stabilized PCE of 19.77%) is achieved with a short-circuit current density exceeding 24 mA cm(-2) and an open-circuit voltage of 1.130 V, corresponding to a loss-in-potential of 0.35 V, and significantly enhanced operational stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 578, "Times Cited, All Databases": 617, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3021, "DOI": "10.1038/s41467-018-05454-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05454-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440413800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oien, S; Wragg, D; Reinsch, H; Svelle, S; Bordiga, S; Lamberti, C; Lillerud, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oien, Sigurd; Wragg, David; Reinsch, Helge; Svelle, Stian; Bordiga, Silvia; Lamberti, Carlo; Lillerud, Karl Petter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal-Organic Frameworks", "Source Title": "CRYSTAL GROWTH & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the structure of the Zr metalorganic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5370, "End Page": 5372, "Article Number": null, "DOI": "10.1021/cg501386j", "DOI Link": "http://dx.doi.org/10.1021/cg501386j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Crystallography; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344516800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, JY; Huang, C; Zhan, YN; Han, SM; Wang, J; Meng, XZ; Yoo, CG; Fang, GG; Ragauskas, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Jinyuan; Huang, Chen; Zhan, Yunni; Han, Shanming; Wang, Jia; Meng, Xianzhi; Yoo, Chang Geun; Fang, Guigan; Ragauskas, Arthur J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective biomass fractionation and lignin stabilization using a diol DES system", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A sustainable and renewable biorefinery will increase the economic viability of lignocellulose-derived products. In this study, a diol-based deep eutectic solvent (DES) was developed to reduce the recalcitrance of bamboo, facilitate saccharification and valorize the lignin fraction. The DES pretreatment dramatically enhanced glucan digestibility by the effective removal of lignin (as high as 85.45%) and xylan (91.12%). Notably, the recovered lignin from DES pretreatment was protected during the fractionation, showing well-preserved 8-O-4 structures (31.82%-59.06%). The mechanism of lignin protection was analyzed to be accomplished by incorporating the diol hydroxyl functional groups into the alpha position of the lignin 8-O-4 structure via etherification. This study highlighted that diol DES is a promising pretreatment solvent to valorize both cellulose and lignin fractions with high enzymatic hydrolysis yield and high-quality lignin co-product.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2022, "Volume": 443, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136395, "DOI": "10.1016/j.cej.2022.136395", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.136395", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800002000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, CF; Wen, YP; Ma, J; Dong, DD; Shen, YF; Liu, SQ; Ma, HB; Zhang, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Chaofeng; Wen, Yaping; Ma, Jin; Dong, Dandan; Shen, Yanfei; Liu, Songqin; Ma, Haibo; Zhang, Yuanjian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling fundamental active units in carbon nitride for photocatalytic oxidation reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalently bonded carbon nitride (CN) has stimulated extensive attention as a metal-free semiconductor. However, because of the complexity of polymeric structures, the acquisition of critical roles of each molecular constituent in CN for photocatalysis remains elusive. Herein, we clarify the fundamental active units of CN in photocatalysis by synthesizing CN with more detailed molecular structures. Enabled by microwave synthesis, the as-prepared CN consists of distinguishable melem (M1) and its incomplete condensed form (M2). We disclose rather than the traditional opinion of being involved in the whole photocatalytic processes, M1 and M2 make primary contributions in light absorption and charge separation, respectively. Meanwhile, oxygen molecules are unusually observed to be activated by participating in the photoexcited processes via electronic coupling mainly to M2. As a result, such CN has a higher activity, which was up to 8 times that of traditional bulk CN for photocatalytic oxidation of tetracycline in water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 320, "DOI": "10.1038/s41467-020-20521-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20521-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662810100024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huo, SD; Sheng, L; Xue, WD; Wang, L; Xu, H; Zhang, H; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huo, Sida; Sheng, Li; Xue, Wendong; Wang, Li; Xu, Hong; Zhang, Hao; He, Xiangming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges of polymer electrolyte with wide electrochemical window for high energy solid-state lithium batteries", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapid development of energy storage technology, solid-state lithium batteries with high energy density, power density, and safety are considered as the ideal choice for the next generation of energy storage devices. Solid electrolytes have attracted considerable attention as key components of solid-state batteries. Compared with inorganic solid electrolytes, solid polymer electrolytes have better flexibility, machinability, and more importantly, better contact with the electrode, and low interfacial impedance. However, its low ionic conductivity, narrow electrochemical stability window (ESW), and poor mechanical properties at room temperature limit its development and practical applications. In recent years, many studies have focused on improving the ionic conductivity of polymer electrolytes; however, few systematic studies and reviews have been conducted on their ESWs. A polymer electrolyte with wide electrochemical window will aid battery operation at a high voltage, which can effectively improve their energy density. Moreover, their stability toward lithium metal anode is also important. Therefore, this review summarizes the recent progress of solid polymer electrolytes on the ESW, discusses the factors affecting ESW of polymer electrolytes, and analyzes a strategy to broaden the window from the perspective of molecular interaction, polymer structural design, and interfacial tuning. The development trends of polymer electrolytes with wide electrochemical windows are also presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/inf2.12394", "DOI Link": "http://dx.doi.org/10.1002/inf2.12394", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914396400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JN; Zhang, WL; Sun, ZN; Pan, MY; Tian, F; Li, XH; Ye, M; Deng, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Jianing; Zhang, Wenluan; Sun, Zhengnull; Pan, Mengyao; Tian, Feng; Li, Xiuhong; Ye, Ming; Deng, Xu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Durable radiative cooling against environmental aging", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To fight against global warming, subambient daytime radiative cooling technology provides a promising path to meet sustainable development goals. To achieve subambient daytime radiative cooling, the reflection of most sunlight is the essential prerequisite. However, the desired high solar reflectance is easily dampened by environmental aging, mainly natural soiling and ultraviolet irradiation from sunlight causing yellowish color for most polymers, making the cooling ineffective. We demonstrate a simple strategy to use titanium dioxide nulloparticles, with ultraviolet resistance, forming hierarchical porous morphology via evaporation-driven assembly, which guarantees a balanced anti-soiling and high solar reflectance, rendering anti-aging cooling paint based coatings. We challenge the cooling coatings in an accelerated weathering test against simulated 3 years of natural soiling and simulated 1 year of natural sunshine, and find that the solar reflectance only declined by 0.4% and 0.5% compared with the un-aged ones. We further show over 6 months of aging under real-world conditions with barely no degradation to the cooling performance. Our anti-aging cooling paint is scalable and can be spray coated on desired outdoor architecture and container, presenting durable radiative cooling, promising for real-world applications. The high solar reflectance needed by radiative cooling is easily dampened by environmental aging. Here, authors describe durable cooling performance against heavy soiling and long-term ultraviolet exposure of paint-based coatings, enhancing the potential of radiative cooling for real-world applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4805, "DOI": "10.1038/s41467-022-32409-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32409-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000841396400030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, XH; Zhang, YQ; Chao, DL; Guan, C; Zhang, YJ; Li, L; Ge, X; Bacho, IM; Tu, JP; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Xinhui; Zhang, Yongqi; Chao, Dongliang; Guan, Cao; Zhang, Yijun; Li, Lu; Ge, Xiang; Bacho, Ignacio Minguez; Tu, Jiangping; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution synthesis of metal oxides for electrochemical energy storage applications", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article provides an overview of solution-based methods for the controllable synthesis of metal oxides and their applications for electrochemical energy storage. Typical solution synthesis strategies are summarized and the detailed chemical reactions are elaborated for several common nullostructured transition metal oxides and their composites. The merits and demerits of these synthesis methods and some important considerations are discussed in association with their electrochemical performance. We also propose the basic guideline for designing advanced nullostructure electrode materials, and the future research trend in the development of high power and energy density electrochemical energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5008, "End Page": 5048, "Article Number": null, "DOI": "10.1039/c4nr00024b", "DOI Link": "http://dx.doi.org/10.1039/c4nr00024b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335148800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SF; Fan, Y; Li, DD; Sun, CX; Lei, ZH; Lu, LF; Wang, T; Zhang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shangfeng; Fan, Yong; Li, Dandan; Sun, Caixia; Lei, Zuhai; Lu, Lingfei; Wang, Ting; Zhang, Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anti-quenching NIR-II molecular fluorophores for in vivo high-contrast imaging and pH sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The contrast and sensitivity of in vivo fluorescence imaging has been revolutionized by molecular fluorophores operating in the second near-infrared window (NIR-II; 1000-1700 nm), but an ongoing challenge is the solvatochromism-caused quenching in aqueous solution for the long-wavelength absorbing fluorophores. Herein, we develop a series of antiquenching pentamethine cyanine fluorophores that significantly overcome the severe solvatochromism, thus affording stable absorption/ emission beyond 1000 nm with up to similar to 44-fold enhanced brightness and superior photostability in aqueous solution. These advantages allow for deep optical penetration (8 mm) as well as high-contrast and highly-stable lymphatic imaging superior to clinical-approved indocyanine green. Additionally, these fluorophores exhibit pH-responsive fluorescence, allowing for noninvasive ratiometric fluorescence imaging and quantification of gastric pH in vivo. The results demonstrate reliable accuracy in tissue as deep as 4 mm, comparable to standard pH electrode method. This work unlocks the potential of anti-quenching pentamethine cyanines for NIR-II biological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1058, "DOI": "10.1038/s41467-019-09043-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09043-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460402300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choudhury, S; Wei, SY; Ozhabes, Y; Gunceler, D; Zachman, MJ; Tu, ZY; Shin, JH; Nath, P; Agrawal, A; Kourkoutis, LF; Arias, TA; Archer, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choudhury, Snehashis; Wei, Shuya; Ozhabes, Yalcin; Gunceler, Deniz; Zachman, Michael J.; Tu, Zhengyuan; Shin, Jung Hwan; Nath, Pooja; Agrawal, Akanksha; Kourkoutis, Lena F.; Arias, Tomas A.; Archer, Lynden A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing solid-liquid interphases for sodium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Secondary batteries based on earth-abundant sodium metal anodes are desirable for both stationary and portable electrical energy storage. Room-temperature sodium metal batteries are impractical today because morphological instability during recharge drives rough, dendritic electrodeposition. Chemical instability of liquid electrolytes also leads to premature cell failure as a result of parasitic reactions with the anode. Here we use joint density-functional theoretical analysis to show that the surface diffusion barrier for sodium ion transport is a sensitive function of the chemistry of solid-electrolyte interphase. In particular, we find that a sodium bromide interphase presents an exceptionally low energy barrier to ion transport, comparable to that of metallic magnesium. We evaluate this prediction by means of electrochemical measurements and direct visualization studies. These experiments reveal an approximately three-fold reduction in activation energy for ion transport at a sodium bromide interphase. Direct visualization of sodium electrodeposition confirms large improvements in stability of sodium deposition at sodium bromide-rich interphases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 898, "DOI": "10.1038/s41467-017-00742-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00742-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412860000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, TM; Kantzos, CA; Zarkevich, NA; Harder, BJ; Heczko, M; Gradl, PR; Thompson, AC; Mills, MJ; Gabb, TP; Lawson, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Timothy M.; Kantzos, Christopher A.; Zarkevich, Nikolai A.; Harder, Bryan J.; Heczko, Milan; Gradl, Paul R.; Thompson, Aaron C.; Mills, Michael J.; Gabb, Timothy P.; Lawson, John W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 3D printable alloy designed for extreme environments", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiprincipal-element alloys are an enabling class of materials owing to their impressive mechanical and oxidation-resistant properties, especially in extreme environments(1,2). Here we develop a new oxide-dispersion-strengthened NiCoCr-based alloy using a model-driven alloy design approach and laser-based additive manufacturing. This oxide-dispersion-strengthened alloy, called GRX-810, uses laser powder bed fusion to disperse nulloscale Y2O3 particles throughout the microstructure without the use of resource-intensive processing steps such as mechanical or in situ alloying(3,4). We show the successful incorporation and dispersion of nulloscale oxides throughout the GRX-810 build volume via high-resolution characterization of its microstructure. The mechanical results of GRX-810 show a twofold improvement in strength, over 1,000-fold better creep performance and twofold improvement in oxidation resistance compared with the traditional polycrystalline wrought Ni-based alloys used extensively in additive manufacturing at 1,093 ?(5,6). The success of this alloy highlights how model-driven alloy designs can provide superior compositions using far fewer resources compared with the 'trial-and-error' methods of the past. These results showcase how future alloy development that leverages dispersion strengthening combined with additive manufacturing processing can accelerate the discovery of revolutionary materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2023, "Volume": 617, "Issue": 7961, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 513, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05893-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05893-0", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000975071100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Li, SM; Yi, F; Zi, YL; Lin, J; Wang, XF; Xu, YL; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jie; Li, Shengming; Yi, Fang; Zi, Yunlong; Lin, Jun; Wang, Xiaofeng; Xu, Youlong; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainably powering wearable electronics solely by biomechanical energy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting biomechanical energy is an important route for providing electricity to sustainably drive wearable electronics, which currently still use batteries and therefore need to be charged or replaced/disposed frequently. Here we report an approach that can continuously power wearable electronics only by human motion, realized through a triboelectric nullogenerator (TENG) with optimized materials and structural design. Fabricated by elastomeric materials and a helix inner electrode sticking on a tube with the dielectric layer and outer electrode, the TENG has desirable features including flexibility, stretchability, isotropy, weavability, water-resistance and a high surface charge density of 250 mu Cm-2. With only the energy extracted from walking or jogging by the TENG that is built in outsoles, wearable electronics such as an electronic watch and fitness tracker can be immediately and continuously powered.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 519, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12744, "DOI": "10.1038/ncomms12744", "DOI Link": "http://dx.doi.org/10.1038/ncomms12744", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385285800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Li, W; Li, JY; Hu, WH; Li, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ming; Li, Wei; Li, Junying; Hu, Weihua; Li, Chang Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Electronic Interaction Enhanced Electrocatalysis of Metal Sulfide Clusters Embedded Metal-Organic Framework Ultrathin nullosheets toward Highly Efficient Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unique metal sulfide (MS) clusters embedded ultrathin nullosheets of Fe/Ni metal-organic framework (MOF) are grown on nickel foam (NiFe-MS/MOF@NF) as a highly efficient bifunctional electrocatalyst for overall water splitting. It exhibits remarkable catalytic activity and stability toward both the oxygen evolution reaction (OER,n= 230 mV at 50 mA cm(-2)) and hydrogen evolution reaction (HER,n= 156 mV at 50 mA cm(-2)) in alkaline media, and bi-functionally catalyzes overall alkaline water splitting at a current density of 50 mA cm(-2)by 1.74 V cell voltage withoutiRcompensation. The enhancement mechanism is ascribed to the impregnated metal sulfide clusters in the nullosheets, which not only promote the formation of ultrathin nullosheet to greatly enlarge the reaction surface area while offering high electric conductivity, but more importantly, efficiently modulate the electronic structure of the catalytically active atom sites to an electron-rich state via strong electronic interaction and strengthen the adsorption of oxygenate intermediate to facilitate fast electrochemical reactions. This work reports a highly efficient HER/OER bifunctional electrocatalyst and may shed light on the rational design and synthesis of uniquely structured MOF-derived catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 7, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001965, "DOI": "10.1002/advs.202001965", "DOI Link": "http://dx.doi.org/10.1002/advs.202001965", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571438300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geng, Y; Kizhakidathazhath, R; Lagerwall, JPF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geng, Yong; Kizhakidathazhath, Rijeesh; Lagerwall, Jan P. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust cholesteric liquid crystal elastomer fibres for mechanochromic textiles", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanically responsive textiles have transformative potential in many areas from fashion to healthcare. Cholesteric liquid crystal elastomers have strong mechanochromic responses that offer attractive opportunities for such applications. Nonetheless, making liquid crystalline elastomer fibres suitable for textiles is challenging since the Plateau-Rayleigh instability tends to break up precursor solutions into droplets. Here, we report a simple approach that balances the viscoelastic properties of the precursor solution to avoid this outcome and achieve long and mechanically robust cholesteric liquid crystal elastomer filaments. These filaments have fast, progressive and reversible mechanochromic responses, from red to blue (wavelength shift of 155 nm), when stretched up to 200%. Moreover, the fibres can be sewed into garments and withstand repeated stretching and regular machine washing. This approach and resulting fibres may be useful for applications in wearable technology and other areas benefiting from autonomous strain sensing or detection of critically strong deformations. Robust cholesteric liquid crystal elastomer fibres with rapid and reversible mechanochromic responses are woven and sewn into garments to create smart clothing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 21, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1441, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01355-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01355-6", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863150100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ali-Löytty, H; Louie, MW; Singh, MR; Li, L; Casalongue, HGS; Ogasawara, H; Crumlin, EJ; Liu, Z; Bell, AT; Nilsson, A; Friebel, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ali-Loeytty, Harri; Louie, Mary W.; Singh, Meenesh R.; Li, Lin; Casalongue, Hernull G. Sanchez; Ogasawara, Hirohito; Crumlin, Ethan J.; Liu, Zhi; Bell, Alexis T.; Nilsson, Anders; Friebel, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambient-Pressure XPS Study of a Ni-Fe Electrocatalyst for the Oxygen Evolution Reaction", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical analysis of solid liquid interfaces under electrochemical conditions has recently become feasible due to the development of new synchrotron radiation techniques. Here we report the use of tender X-ray ambient-pressure X-ray photoelectron spectroscopy (APXPS) to characterize a thin film of Ni-Fe oxyhydroxide electro-deposited on Au as the working electrode at different applied potentials in 0.1 M KOH as the electrolyte. Our results show that the as-prepared 7 urn thick Ni-Fe (50% Fe) film contains Fe and Ni in both their metallic as well as oxidized states, and undergoes further oxidation when the sample is subjected to electrochemical oxidation reduction cycles. Metallic Fe is oxidized to Fe3+ and metallic Ni to Ni2+/3+. This work shows that it is possible to monitor the chemical nature of the Ni Fe catalyst as a function of potential when the corresponding current densities are small. This allows for operando measurements just above the onset of OER; however, current densities as they are desired in photoelectrochemical devices (similar to 1-10 mA cm(-2)) could not be achieved in this work, due to ohmic losses in the thin electrolyte film. We use a two-dimensional model to describe the spatial distribution of the electrochemical potential, current density, and pH as a function of the position above the electrolyte meniscus, to provide guidance toward enabling the acquisition of operando APXPS at high current density. The shifts in binding energy of water with applied potential predicted by the model are in good agreement with the experimental values.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 120, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2247, "End Page": 2253, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b10931", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b10931", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369772900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, DF; Liu, YX; Tian, FB; Li, D; Huang, XL; Zhao, ZL; Yu, HY; Liu, BB; Tian, WJ; Cui, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Defang; Liu, Yunxian; Tian, Fubo; Li, Da; Huang, Xiaoli; Zhao, Zhonglong; Yu, Hongyu; Liu, Bingbing; Tian, Wenjing; Cui, Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-induced metallization of dense (H2S)2H2 with high-Tc superconductivity", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high pressure structures, metallization, and superconductivity of recently synthesized H-2-containing compounds (H2S)(2)H-2 are elucidated by ab initio calculations. The ordered crystal structure with P1 symmetry is determined, supported by the good agreement between theoretical and experimental X-ray diffraction data, equation of states, and Raman spectra. The Cccm structure is favorable with partial hydrogen bond symmetrization above 37 GPa. Upon further compression, H-2 molecules disappear and two intriguing metallic structures with R3m and Im-3m symmetries are reconstructive above 111 and 180 GPa, respectively. The predicted metallization pressure is 111 GPa, which is approximately one-third of the currently suggested metallization pressure of bulk molecular hydrogen. Application of the Allen-Dynes-modified McMillan equation for the Im-3m structure yields high T-c values of 191 K to 204 K at 200 GPa, which is among the highest values reported for H-2-rich van der Waals compounds and MH3 type hydride thus far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 783, "Times Cited, All Databases": 846, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6968, "DOI": "10.1038/srep06968", "DOI Link": "http://dx.doi.org/10.1038/srep06968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344759000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sucharitakul, S; Goble, NJ; Kumar, UR; Sankar, R; Bogorad, ZA; Chou, FC; Chen, YT; Gao, XPA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sucharitakul, Sukrit; Goble, Nicholas J.; Kumar, U. Rajesh; Sankar, Raman; Bogorad, Zachary A.; Chou, Fang-Cheng; Chen, Yit-Tsong; Gao, Xuan P. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Electron Mobility Exceeding 103 cm2/(V s) in Multilayer InSe FETs", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene-like two-dimensional (2D) materials not only are interesting for their exotic electronic structure and fundamental electronic transport or optical properties but also hold promises for device miniaturization down to atomic thickness. As one material belonging to this category, InSe, a III-VI semiconductor, not only is a promising candidate for optoelectronic devices but also has potential for ultrathin field effect transistor (FET) with high mobility transport. In this work, various substrates such as PMMA, bare silicon oxide, passivated silicon oxide, and silicon nitride were used to fabricate multilayer InSe FET devices. Through back gating and Hall measurement in four-probe configuration, the device's field effect mobility and intrinsic Hall mobility were extracted at various temperatures to study the material's intrinsic transport behavior and the effect of dielectric substrate. The sample's field effect and Hall mobilities over the range of 20-300 K fall in the range of 0.1-2.0 x 10(3) cm(2)/(V s), which are comparable or better than the state of the art FETs made of widely studied 2D transition metal dichalcogenides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3815, "End Page": 3819, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b00493", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b00493", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356316900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, CY; Niu, LL; Chen, NJ; Jin, K; Yang, TN; Xiu, PY; Zhang, YW; Gao, F; Bei, HB; Shi, S; He, MR; Robertson, IM; Weber, WJ; Wang, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Chenyang; Niu, Liangliang; Chen, nulljun; Jin, Ke; Yang, Taini; Xiu, Pengyuan; Zhang, Yanwen; Gao, Fei; Bei, Hongbin; Shi, Shi; He, Mo-Rigen; Robertson, Ian M.; Weber, William J.; Wang, Lumin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing radiation tolerance by controlling defect mobility and migration pathways in multicomponent single-phase alloys", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A grand challenge in material science is to understand the correlation between intrinsic properties and defect dynamics. Radiation tolerant materials are in great demand for safe operation and advancement of nuclear and aerospace systems. Unlike traditional approaches that rely on microstructural and nulloscale features to mitigate radiation damage, this study demonstrates enhancement of radiation tolerance with the suppression of void formation by two orders magnitude at elevated temperatures in equiatomic single-phase concentrated solid solution alloys, and more importantly, reveals its controlling mechanism through a detailed analysis of the depth distribution of defect clusters and an atomistic computer simulation. The enhanced swelling resistance is attributed to the tailored interstitial defect cluster motion in the alloys from a long-range one-dimensional mode to a short-range three-dimensional mode, which leads to enhanced point defect recombination. The results suggest design criteria for next generation radiation tolerant structural alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 668, "Times Cited, All Databases": 716, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13564, "DOI": "10.1038/ncomms13564", "DOI Link": "http://dx.doi.org/10.1038/ncomms13564", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390282200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, W; Chen, SM; Lin, Y; Yang, L; Chen, SJ; Zheng, XS; Qi, ZM; Wang, CM; Long, R; Chen, M; Zhu, JF; Gao, P; Song, L; Jiang, J; Xiong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Wei; Chen, Shuangming; Lin, Yue; Yang, Li; Chen, Sijia; Zheng, Xusheng; Qi, Zeming; Wang, Chengming; Long, Ran; Chen, Meng; Zhu, Junfa; Gao, Peng; Song, Li; Jiang, Jun; Xiong, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precisely Tuning the Number of Fe Atoms in Clusters on N-Doped Carbon toward Acidic Oxygen Reduction Reaction", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed transition metals anchored on N-doped carbon are identified as a class of promising candidates alternatively to Pt-based catalysts for oxygen reduction reaction but still restricted by the low activity and durability in acidic media. Herein, we report a new strategy for precisely tuning the number of Fe atoms in clusters anchored on N-doped carbon. Such a tunability offers the capabilities of altering O-2 adsorption from superoxo-like to peroxo-like configuration as well as tailoring N species in carbon matrix during pyrolytic catalyst synthesis. As a result, Fe-2 clusters on N-doped carbon display excellent acidic ORR activity with a half-wave potential of 0.78 V versus reversible hydrogen electrode (RHE) as well as remarkable durability with only a -20 mV shift after 20,000 cycles in 0.5 M H2SO4 solution. This work provides insights into non-noble-metal electrocatalyst design at the atomic level from the angle of both active sites and catalyst supports.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2019, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2865, "End Page": 2878, "Article Number": null, "DOI": "10.1016/j.chempr.2019.07.020", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.07.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496957600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Zeng, ZD; Liu, L; Chen, JW; Zhou, HT; Huang, LL; Huang, J; Xu, H; Xu, YY; Chen, ZR; Wu, Y; Guo, WL; Wang, JH; Wang, J; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, He; Zeng, Zhandong; Liu, Lin; Chen, Jiawen; Zhou, Huiting; Huang, Lili; Huang, Jie; Xu, Hua; Xu, Yunyun; Chen, Zhengrong; Wu, Yi; Guo, Wanliang; Wang, Jiang Huai; Wang, Jian; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polydopamine nulloparticles for the treatment of acute inflammation-induced injury", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullotechnology-mediated anti-inflammatory therapy is emerging as a novel strategy for the treatment of inflammation-induced injury. However, one of the main hurdles for these anti-inflammatory nullo-drugs is their potential toxic side effects in vivo. Herein, we uncovered that polydopamine (PDA) nulloparticles with their structure and chemical properties similar to melanin, a natural bio-polymer, displayed a significant anti-inflammation therapeutic effect on acute inflammation-induced injury. PDA with enriched phenol groups functioned as a radical scavenger to eliminate reactive oxygen species (ROS) generated during inflammatory responses. As revealed by in vivo photoacoustic imaging with a H2O2-specific nulloprobe, PDA nulloparticles remarkably reduced intracellular ROS levels in murine macrophages challenged with either H2O2 or lipopolysaccharide (LPS). The anti-inflammatory capacity of PDA nulloparticles was further demonstrated in murine models of both acute peritonitis and acute lung injury (ALI), where diminished ROS generation, reduced proinflammatory cytokines, attenuated neutrophil infiltration, and alleviated lung tissue damage were observed in PDA-treated mice after a single dose of PDA treatment. Our work therefore presents the great promise of PDA nulloparticles as a biocompatible nullo-drug for anti-inflammation therapy to treat acute inflammation-induced injury.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2018, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6981, "End Page": 6991, "Article Number": null, "DOI": "10.1039/c8nr00838h", "DOI Link": "http://dx.doi.org/10.1039/c8nr00838h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430537200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, X; Oganov, AR; Goncharov, AF; Stavrou, E; Lobanov, S; Saleh, G; Qian, GR; Zhu, Q; Gatti, C; Deringer, VL; Dronskowski, R; Zhou, XF; Prakapenka, VB; Konôpková, Z; Popov, IA; Boldyrev, AI; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Xiao; Oganov, Artem R.; Goncharov, Alexander F.; Stavrou, Elissaios; Lobanov, Sergey; Saleh, Gabriele; Qian, Guang-Rui; Zhu, Qiang; Gatti, Carlo; Deringer, Volker L.; Dronskowski, Richard; Zhou, Xiang-Feng; Prakapenka, Vitali B.; Konopkova, Zuzana; Popov, Ivan A.; Boldyrev, Alexander I.; Wang, Hui-Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stable compound of helium and sodium at high pressure", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Helium is generally understood to be chemically inert and this is due to its extremely stable closed-shell electronic configuration, zero electron affinity and an unsurpassed ionization potential. It is not known to form thermodynamically stable compounds, except a few inclusion compounds. Here, using the ab initio evolutionary algorithm USPEX and subsequent high-pressure synthesis in a diamond anvil cell, we report the discovery of a thermodynamically stable compound of helium and sodium, Na2He, which has a fluorite-type structure and is stable at pressures >113 GPa. We show that the presence of He atoms causes strong electron localization and makes this material insulating. This phase is an electride, with electron pairs localized in interstices, forming eight-centre two-electron bonds within empty Na-8 cubes. We also predict the existence of Na2HeO with a similar structure at pressures above 15 GPa.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 440, "End Page": 445, "Article Number": null, "DOI": "10.1038/NCHEM.2716", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2716", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399785500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, L; Zhang, Y; Zhao, ZL; Zhang, QH; Huang, LB; Gu, L; Lu, G; Hu, JS; Wan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lu; Zhang, Yun; Zhao, Zhonglong; Zhang, Qing-Hua; Huang, Lin-Bo; Gu, Lin; Lu, Gang; Hu, Jin-Song; Wan, Li-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steering elementary steps towards efficient alkaline hydrogen evolution via size-dependent Ni/NiO nulloscale heterosurfaces", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkaline hydrogen evolution reaction (HER), consisting of Volmer and Heyrovsky/Tafel steps, requires extra energy for water dissociation, leading to more sluggish kinetics than acidic HER. Despite the advances in electrocatalysts, how to combine active sites to synergistically promote both steps and understand the underlying mechanism remain largely unexplored. Here, Density Functional Theory (DFT) calculations predict that NiO accelerates the Volmer step while metallic Ni facilitates the Heyrovsky/Tafel step. A facile strategy is thus developed to control Ni/NiO heterosurfaces in uniform and well-dispersed Ni-based nullocrystals, targeting both reaction steps synergistically. By systematically modulating the surface composition, we find that steering the elementary steps through tuning the Ni/NiO ratio can significantly enhance alkaline HER activity, and Ni/NiO nullocrystals with a Ni/NiO ratio of 23.7% deliver the best activity, outperforming other state-of-the-art analogues. The results suggest that integrating bicomponent active sites for elementary steps is effective for promoting alkaline HER, but they have to be balanced.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 27, "End Page": 36, "Article Number": null, "DOI": "10.1093/nsr/nwz145", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwz145", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519816200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blok, LG; Longana, ML; Yu, H; Woods, BKS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blok, L. G.; Longana, M. L.; Yu, H.; Woods, B. K. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An investigation into 3D printing of fibre reinforced thermoplastic composites", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused filament fabrication (FFF) is a 3D printing technique which allows layer-by-layer build-up of a part by the deposition of thermoplastic material through a nozzle. The technique allows for complex shapes to be made with a degree of design freedom unachievable with traditional manufacturing methods. However, the mechanical properties of the thermoplastic materials used are low compared to common engineering materials. In this work, composite 3D printing feedstocks for FFF are investigated, wherein carbon fibres are embedded into a thermoplastic matrix to increase strength and stiffness. First, the key processing parameters for FFF are reviewed, showing how fibres alter the printing dynamics by changing the viscosity and the thermal profile of the printed material. The state-of-the-art in composite 3D printing is presented, showing a distinction between short fibre feedstocks versus continuous fibre feedstocks. An experimental study was performed to benchmark these two methods. It is found that printing of continuous carbon fibres using the MarkOne printer gives significant increases in performance over unreinforced thermoplastics, with mechanical properties in the same order of magnitude of typical unidirectional epoxy matrix composites. The method, however, is limited in design freedom as the brittle continuous carbon fibres cannot be deposited freely through small steering radii and sharp angles. Filaments with embedded short carbon microfibres (similar to 100 mu m) show better print capabilities and are suitable for use with standard printing methods, but only offer a slight increase in mechanical properties over the pure thermoplastic properties. It is hypothesized that increasing the fibre length in short fibre filament is expected to lead to increased mechanical properties, potentially approaching those of continuous fibre composites, whilst keeping the high degree of design freedom of the FFF process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 663, "Times Cited, All Databases": 714, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 176, "End Page": 186, "Article Number": null, "DOI": "10.1016/j.addma.2018.04.039", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2018.04.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442170000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZQ; Liu, JP; Wang, J; Wang, Q; Wang, YH; Wang, K; Wang, Z; Gu, M; Tang, ZH; Lim, J; Zhao, TS; Ciucci, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhiqi; Liu, Jiapeng; Wang, Jian; Wang, Qi; Wang, Yuhao; Wang, Kai; Wang, Zheng; Gu, Meng; Tang, Zhenghua; Lim, Jongwoo; Zhao, Tianshou; Ciucci, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom catalyst for high-performance methanol oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is still challenging to engineer single-atom catalysts for electrocatalytic methanol oxidation. Here, the authors design Pt single atom supported on RuO2 for highly active methanol oxidation in contrast to the inert Pt single atom supported on carbon. Single-atom catalysts have been widely investigated for several electrocatalytic reactions except electrochemical alcohol oxidation. Herein, we synthesize atomically dispersed platinum on ruthenium oxide (Pt-1/RuO2) using a simple impregnation-adsorption method. We find that Pt-1/RuO2 has good electrocatalytic activity towards methanol oxidation in an alkaline media with a mass activity that is 15.3-times higher than that of commercial Pt/C (6766 vs. 441 mA mg(Pt)(-1)). In contrast, single atom Pt on carbon black is inert. Further, the mass activity of Pt-1/RuO2 is superior to that of most Pt-based catalysts previously developed. Moreover, Pt-1/RuO2 has a high tolerance towards CO poisoning, resulting in excellent catalytic stability. Ab initio simulations and experiments reveal that the presence of Pt-O-3f (3-fold coordinatively bonded O)-Ru-cus (coordinatively unsaturated Ru) bonds with the undercoordinated bridging O in Pt-1/RuO2 favors the electrochemical dehydrogenation of methanol with lower energy barriers and onset potential than those encountered for Pt-C and Pt-Ru.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5235, "DOI": "10.1038/s41467-021-25562-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25562-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000695649500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Y; Chen, Z; Hang, YM; Deb, P; Gao, H; Xie, SE; Purohit, P; Tate, MW; Park, J; Gruner, SM; Elser, V; Muller, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yi; Chen, Zhen; Hang, Yimo; Deb, Pratiti; Gao, Hui; Xie, Saien; Purohit, Prafull; Tate, Mark W.; Park, Jiwoong; Gruner, Sol M.; Elser, Veit; Muller, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron ptychography of 2D materials to deep sub-angstrom resolution", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aberration-corrected optics have made electron microscopy at atomic resolution a widespread and often essential tool for characterizing nulloscale structures. Image resolution has traditionally been improved by increasing the numerical aperture of the lens (alpha) and the beam energy, with the state-of-the-art at 300 kiloelectronvolts just entering the deep sub-angstrom (that is, less than 0.5 angstrom) regime. Two-dimensional (2D) materials are imaged at lower beam energies to avoid displacement damage from large momenta transfers, limiting spatial resolution to about 1 angstrom. Here, by combining an electron microscope pixel-array detector with the dynamic range necessary to record the complete distribution of transmitted electrons and full-field ptychography to recover phase information from the full phase space, we increase the spatial resolution well beyond the traditional numerical-aperture-limited resolution. At a beam energy of 80 kiloelectronvolts, our ptychographic reconstruction improves the image contrast of single-atom defects in MoS2 substantially, reaching an information limit close to 5 alpha, which corresponds to an Abbe diffraction-limited resolution of 0.39 angstrom, at the electron dose and imaging conditions for which conventional imaging methods reach only 0.98 angstrom.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2018, "Volume": 559, "Issue": 7714, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 343, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0298-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0298-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439059800046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, N; Chae, S; Ma, J; Ko, M; Cho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Namhyung; Chae, Sujong; Ma, Jiyoung; Ko, Minseong; Cho, Jaephil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast-charging high-energy lithium-ion batteries via implantation of amorphous silicon nullolayer in edge-plane activated graphite anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As fast-charging lithium-ion batteries turn into increasingly important components in forthcoming applications, various strategies have been devoted to the development of high-rate anodes. However, despite vigorous efforts, the low initial Coulombic efficiency and poor volumetric energy density with insufficient electrode conditions remain critical challenges that have to be addressed. Herein, we demonstrate a hybrid anode via incorporation of a uniformly implanted amorphous silicon nullolayer and edge-site-activated graphite. This architecture succeeds in improving lithium ion transport and minimizing initial capacity losses even with increase in energy density. As a result, the hybrid anode exhibits an exceptional initial Coulombic efficiency (93.8%) and predominullt fast-charging behavior with industrial electrode conditions. As a result, a full-cell demonstrates a higher energy density (>= 1060 Wh l(-1)) without any trace of lithium plating at a harsh charging current density (10.2 mA cm(-2)) and 1.5 times faster charging than that of conventional graphite.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 812, "DOI": "10.1038/s41467-017-00973-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00973-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412518300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Ma, ZL; Zhang, YL; Qiu, H; Ruan, KP; Gu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Ma, Zhonglei; Zhang, Yali; Qiu, Hua; Ruan, Kunpeng; Gu, Junwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically strong and folding-endurance Ti3C2Tx MXene/PBO nullofiber films for efficient electromagnetic interference shielding and thermal management", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic interference (EMI) shielding materials with excellent flexibility and mechanical properties and outstanding thermal conductivity have become a hot topic of research in functional composites. In this study, the sol-gel-film conversion technique is used to assemble polyetherimide-functionalized Ti3C2Tx nullosheets (f-Ti3C2Tx) with poly(p-phenylene-2,6-benzobisoxazole) (PBO) nullofibers (PNFs), followed by dialysis and vacuum drying to prepare f-Ti3C2Tx/PNF films with lamellar structures. When the loading of f-Ti3C2Tx is 70 wt%, the f-Ti3C2Tx/PNF film presents optimal comprehensive properties, with an EMI shielding effectiveness (SE) of 35 dB and a specific SE/thickness ((SSE, SE/density)/t) of 8211 dB cm(2)/g, a tensile strength of 125.1 MPa, an in-plane thermal conductivity coefficient (lambda) of 5.82 W/(m K), and electrical conductivity of 1943 S/m. After repeated folding for 10,000 cycles, the EMI SE and the tensile strength of f-Ti3C2Tx/PNFs films still remain 33.4 dB and 116.1 MPa, respectively. Additionally, the f-Ti3C2Tx/PNF film also shows excellent thermal stability, flame retardancy, and structural stability. This would provide a novel method for the design and fabrication of multifunctional composite films and considerably expand the applications of MXene- and PNF-based composites in the fields of EMI shielding and thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 200, "End Page": 210, "Article Number": null, "DOI": "10.1002/cey2.174", "DOI Link": "http://dx.doi.org/10.1002/cey2.174", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740762600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, M; Cheng, JJ; Wang, XF; Hong, XK; Fan, JJ; Yu, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Min; Cheng, Jingjing; Wang, Xuefei; Hong, Xuekun; Fan, Jiajie; Yu, Huogen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-mediated photodeposition synthesis of NiS cocatalyst for boosting H2-evolution performance of g-C3N4 photocatalyst", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modification of nickel sulfide cocatalysts is considered to be a promising approach for efficient enhancement of the photocatalytic hydrogen production performance of g-C3N4. Providing more NiS cocatalyst to function as active sites of g-C3N4 is still highly desirable. To realize this goal, in this work, a facile sulfur-mediated photodeposition approach was developed. Specifically, photogenerated electrons excited by visible light reduce the S molecules absorbed on g-C3N4 surface to S2-, and subsequently NiS cocatalyst is formed in situ on the g-C3N4 surface by a combination of Ni2+ and S2- due to their small solubility product constant (K-sp = 3.2 x 10(-19)). This approach has several advantages. The NiS cocatalyst is clearly in situ deposited on the photogenerated electron transfer sites of g-C3N4, and thus provides more active sites for H-2 production. In addition, this method utilizes solar energy with mild reaction conditions at room temperature. Consequently, the synthesized NiS/g-C3N4 photocatalyst achieves excellent hydrogen generation performance with the performance of the optimal sample (244 mu mol h(-1) g(-1)) close to that of 1 wt% Pt/g-C3N4 (316 mu mol h(-1) g(-1), a well-known excellent photocatalyst). More importantly, the present sulfur-mediated photodeposition route is versatile and facile and can be used to deposit various metal sulfides such as CoSx, CuSx and AgSx on the g-C3N4 surface, and all the resulting metal sulfide-modified g-C3N4 photocatalysts exhibit improved H-2-production performance. Our study offers a novel insight for the synthesis of high-efficiency photocatalysts. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 37, "End Page": 45, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63633-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63633-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, XZ; Suvarna, M; Low, S; Dissanayake, PD; Lee, KB; Li, J; Wang, XN; Ok, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Xiangzhou; Suvarna, Manu; Low, Sean; Dissanayake, Pavani Dulanja; Lee, Ki Bong; Li, Jie; Wang, Xiaonull; Ok, Yong Sik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Applied Machine Learning for Prediction of CO2 Adsorption on Biomass Waste-Derived Porous Carbons", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomass waste-derived porous carbons (BWDPCs) are a class of complex materials that are widely used in sustainable waste management and carbon capture. However, their diverse textural properties, the presence of various functional groups, and the varied temperatures and pressures to which they are subjected during CO2 adsorption make it challenging to understand the underlying mechanism of CO2 adsorption. Here, we compiled a data set including 527 data points collected from peer-reviewed publications and applied machine learning to systematically map CO2 adsorption as a function of the textural and compositional properties of BWDPCs and adsorption parameters. Various tree-based models were devised, where the gradient boosting decision trees (GBDTs) had the best predictive performance with R-2 of 0.98 and 0.84 on the training and test data, respectively. Further, the BWDPCs in the compiled data set were classified into regular porous carbons (RPCs) and heteroatom-doped porous carbons (HDPCs), where again the GBDT model had R-2 of 0.99 and 0.98 on the training and 0.86 and 0.79 on the test data for the RPCs and HDPCs, respectively. Feature importance revealed the significance of adsorption parameters, textural properties, and compositional properties in the order of precedence for BWDPC-based CO2 adsorption, effectively guiding the synthesis of porous carbons for CO2 adsorption applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2021, "Volume": 55, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11925, "End Page": 11936, "Article Number": null, "DOI": "10.1021/acs.est.1c01849", "DOI Link": "http://dx.doi.org/10.1021/acs.est.1c01849", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000695530700047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, XQ; Jiang, ZQ; Zhang, BA; Tian, XN; Song, CS; Wang, LK; Maiyalagan, T; Hao, XG; Jiang, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Xiaoqiong; Jiang, Zhongqing; Zhang, Baoan; Tian, Xiaoning; Song, Changsheng; Wang, Likui; Maiyalagan, Thandavarayan; Hao, Xiaogang; Jiang, Zhong-Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-Doped Carbon nullotubes Derived from Graphene Oxide with Embedment of FeCo nulloparticles as Bifunctional Air Electrode for Rechargeable Liquid and Flexible All-Solid-State Zinc-Air Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work reports a novel approach for the synthesis of FeCo alloy nulloparticles (NPs) embedded in the N,P-codoped carbon coated nitrogen-doped carbon nullotubes (NPC/FeCo@NCNTs). Specifically, the synthesis of NCNT is achieved by the calcination of graphene oxide-coated polystyrene spheres with Fe3+, Co2+ and melamine adsorbed, during which graphene oxide is transformed into carbon nullotubes and simultaneously nitrogen is doped into the graphitic structure. The NPC/FeCo@NCNT is demonstrated to be an efficient and durable bifunctional catalyst for oxygen evolution (OER) and oxygen reduction reaction (ORR). It only needs an overpotential of 339.5 mV to deliver 10 mA cm(-2) for OER and an onset potential of 0.92 V to drive ORR. Its bifunctional catalytic activities outperform those of the composite catalyst Pt/C + RuO2 and most bifunctional catalysts reported. The experimental results and density functional theory calculations have demonstrated that the interplay between FeCo NPs and NCNT and the presence of N,P-codoped carbon structure play important roles in increasing the catalytic activities of the NPC/FeCo@NCNT. More impressively, the NPC/FeCo@NCNT can be used as the air-electrode catalyst, improving the performance of rechargeable liquid and flexible all-solid-state zinc-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 8, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004572, "DOI": "10.1002/advs.202004572", "DOI Link": "http://dx.doi.org/10.1002/advs.202004572", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629229500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, JS; Wang, MH; Lin, FL; Han, Z; Fu, BA; Tu, DT; Chen, XY; Qiu, B; Wen, HR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Jinsheng; Wang, Minghua; Lin, Fulin; Han, Zhuo; Fu, Biao; Tu, Datao; Chen, Xueyuan; Qiu, Bao; Wen, He-Rui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally boosted upconversion and downshifting luminescence in Sc2(MoO4)3:Yb/Er with two-dimensional negative thermal expansion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rare earth (RE3+)-doped phosphors generally suffer from thermal quenching, in which their photoluminescence (PL) intensities decrease at high temperatures. Herein, we report a class of unique two-dimensional negative-thermal-expansion phosphor of Sc-2(MoO4)(3):Yb/Er. By virtue of the reduced distances between sensitizers and emitters as well as confined energy migration with increasing the temperature, a 45-fold enhancement of green upconversion (UC) luminescence and a 450-fold enhancement of near-infrared downshifting (DS) luminescence of Er3+ are achieved upon raising the temperature from 298 to 773 K. The thermally boosted UC and DS luminescence mechanism is systematically investigated through in situ temperature-dependent Raman spectroscopy, synchrotron X-ray diffraction and PL dynamics. Moreover, the luminescence lifetime of I-4(13/2) of Er3+ in Sc-2(MoO4)(3):Yb/Er displays a strong temperature dependence, enabling luminescence thermometry with the highest relative sensitivity of 12.3%/K at 298 K and low temperature uncertainty of 0.11 K at 623 K. These findings may gain a vital insight into the design of negative-thermal-expansion RE3+-doped phosphors for versatile applications. Rare-earth doped phosphors with negative thermal expansion (NTE) may display thermally-enhanced emission, but their performance is generally limited. Here the authors report thermally-boosted green upconversion luminescence and near-infrared downshifting luminescence in Sc-2(MoO4)(3):Yb/Er phosphors with two-dimensional NTE, and their application in temperature sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2090, "DOI": "10.1038/s41467-022-29784-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29784-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784997300113", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Zhang, Q; Zhang, QW; Li, X; Zhao, CX; Xu, TY; Qu, DH; Tian, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qian; Zhang, Qi; Zhang, Qi-Wei; Li, Xin; Zhao, Cai-Xin; Xu, Tian-Yi; Qu, Da-Hui; Tian, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Color-tunable single-fluorophore supramolecular system with assembly-encoded emission", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Regulating the fluorescent properties of organic small molecules in a controlled and dynamic manner has been a fundamental research goal. Although several strategies have been exploited, realizing multi-color molecular emission from a single fluorophore remains challenging. Herein, we demonstrate an emissive system by combining pyrene fluorophore and acylhydrazone units, which can generate multi-color switchable fluorescent emissions at different assembled states. Two kinds of supramolecular tools, amphiphilic self-assembly and gamma-cyclodextrin mediated host-guest recognition, are used to manipulate the intermolecular aromatic stacking distances, resulting in the tunable fluorescent emission ranging from blue to yellow, including a pure white-light emission. Moreover, an external chemical signal, amylase, is introduced to control the assembly states of the system on a time scale, generating a distinct dynamic emission system. The dynamic properties of this multi-color fluorescent system can be also enabled in a hydrogel network, exhibiting a promising potential for intelligent fluorescent materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 158, "DOI": "10.1038/s41467-019-13994-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13994-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511898900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, F; Xu, JC; Liu, B; Yang, NL; Cheng, L; Huang, P; Wang, CJ; Chen, Q; Ni, CF; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Fei; Xu, Jiachen; Liu, Bo; Yang, Nailin; Cheng, Liang; Huang, Peng; Wang, Chunjie; Chen, Qian; Ni, Caifang; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale CaH2 materials for synergistic hydrogen-immune cancer therapy", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we prepared CaH2 nulloparticles through liquid-phase exfoliation and first applied them as an antitumor therapeutic agent. Being dispersed in low-molecular-weight polyethylene glycol (PEG) and injected into the tumor, nullo-CaH2 would react with water to generate abundant hydrogen gas (H-2), calcium ions (Ca2+), and hydroxyl ions (OH-), enabling hydrogen therapy, tumor calcification, and neutralization of acidic tumor microenvironment (TME), respectively. The injectable nullo-CaH2 dispersion could lead to significant tumor growth inhibition. In addition, the local nullo-CaH2-induced tumor cell apoptosis and TME modulation would activate the immune system and promote tumor infiltration of immune cells, which, working together with immune checkpoint blockade, could elicit robust immune responses to inhibit abscopal distant tumors without direct nullo-CaH2 injection. Furthermore, nullo-CaH2 could be dispersed in lipiodol to obtain CaH2-lipiodol dispersion for interventional transarterial embolization (TAE) therapy, and they showed obviously improved TAE therapeutic outcome on orthotopic rabbit liver cancer model compared with lipiodol alone.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": "+", "Article Number": null, "DOI": "10.1016/j.chempr.2021.11.020", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2021.11.020", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746890600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, Q; Wang, X; Clowes, R; Cui, P; Chen, LJ; Little, MA; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Qiang; Wang, Xue; Clowes, Rob; Cui, Peng; Chen, Linjiang; Little, Marc A.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Cage COFs: A Dynamic Three-Dimensional Covalent Organic Framework with High-Connectivity Organic Cage Nodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) covalent organic frameworks (COFs) are rare because there is a limited choice of organic building blocks that offer multiple reactive sites in a polyhedral geometry. Here, we synthesized an organic cage molecule ( Cage-6-NH2) that was used as a triangular prism node to yield the first cage-based 3D COF, 3D-CageCOF-1. This COF adopts an unreported 2-fold interpenetrated acs topology and exhibits reversible dynamic behavior, switching between a small-pore (sp) structure and a large-pore (lp) structure. It also shows high CO2 uptake and captures water at low humidity (<40%). This demonstrates the potential for expanding the structural complexity of 3D COFs by using organic cages as the building units.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2020, "Volume": 142, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16842, "End Page": 16848, "Article Number": null, "DOI": "10.1021/jacs.0c07732", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c07732", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577115100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, J; Yin, J; Liu, HB; Huang, BL; Hu, Y; Zhang, H; Sun, MZ; Peng, Y; Xi, PX; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Jing; Yin, Jie; Liu, Hongbo; Huang, Bolong; Hu, Yang; Zhang, Hong; Sun, Mingzi; Peng, Yong; Xi, Pinxian; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Sulfur Filling Oxygen Vacancies Optimizes H Absorption and Boosts the Hydrogen Evolution Reaction in Alkaline Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hydrogen evolution reaction (HER) usually has sluggish kinetics in alkaline solution due to the difficulty in forming binding protons. Herein we report an electrocatalyst in which sulfur atoms are doping in the oxygen vacancies (V-O) of inverse spinel NiFe2O4 (S-NiFe2O4) to create active sites with enhanced electron transfer capability. This electrocatalyst has an ultralow overpotential of 61 mV at the current density of 10 mA cm(-2) and long-term stability of 60 h at 1.0 Acm(-2) in 1.0 M KOH media. In situ Raman spectroscopy revealed that S sites adsorb hydrogen adatom (H*) and in situ form S-H*, which favor the production of hydrogen and boosts HER in alkaline solution. DFT calculations further verified that S introduction lowered the energy barrier of H2O dissociation. Both experimental and theoretical investigations confirmed S atoms are active sites of the S-NiFe2O4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2021, "Volume": 60, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14117, "End Page": 14123, "Article Number": null, "DOI": "10.1002/anie.202104055", "DOI Link": "http://dx.doi.org/10.1002/anie.202104055", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648080900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, YH; Chen, X; Sun, KA; Zhang, JQ; Lai, WH; Liu, H; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yuhan; Chen, Xin; Sun, Kaian; Zhang, Jinqiang; Lai, Wei-Hong; Liu, Hao; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Oxygen-Oxygen Cleavage through Optimizing Interatomic Distances in Dual Single-atom Electrocatalysts for Efficient Oxygen Reduction Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen reduction reaction (ORR) on transition single-atom catalysts (SACs) is sustainable in energy-conversion devices. However, the atomically controllable fabrication of single-atom sites and the sluggish kinetics of ORR have remained challenging. Here, we accelerate the kinetics of acid ORR through a direct O-O cleavage pathway through using a bi-functional ligand-assisted strategy to pre-control the distance of hetero-metal atoms. Concretely, the as-synthesized Fe-Zn diatomic pairs on carbon substrates exhibited an outstanding ORR performance with the ultrahigh half-wave potential of 0.86 V vs. RHE in acid electrolyte. Experimental evidence and density functional theory calculations confirmed that the Fe-Zn diatomic pairs with a specific distance range of around 3 angstrom, which is the key to their ultrahigh activity, average the interaction between hetero-diatomic active sites and oxygen molecules. This work offers new insight into atomically controllable SACs synthesis and addresses the limitations of the ORR dissociative mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2023, "Volume": 62, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202301833", "DOI Link": "http://dx.doi.org/10.1002/anie.202301833", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953704600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, C; Ni, X; Ge, H; Sun, XC; Chen, YB; Lu, MH; Liu, XP; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Cheng; Ni, Xu; Ge, Hao; Sun, Xiao-Chen; Chen, Yan-Bin; Lu, Ming-Hui; Liu, Xiao-Ping; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acoustic topological insulator and robust one-way sound transport", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological design of materials enables topological symmetries and facilitates unique backscattering-immune wave transport(1-26). In airborne acoustics, however, the intrinsic longitudinal nature of sound polarization makes the use of the conventional spin-orbital interaction mechanism impossible for achieving band inversion. The topological gauge flux is then typically introduced with a moving background in theoretical models(19-22). Its practical implementation is a serious challenge, though, due to inherent dynamic instabilities and noise. Here we realize the inversion of acoustic energy bands at a double Dirac cone(15,27,28) and provide an experimental demonstration of an acoustic topological insulator. By manipulating the hopping interaction of neighbouring 'atoms' in this new topological material, we successfully demonstrate the acoustic quantum spin Hall effect, characterized by robust pseudospin-dependent one-way edge sound transport. Our results are promising for the exploration of new routes for experimentally studying topological phenomena and related applications, for example, sound-noise reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 989, "Times Cited, All Databases": 1056, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1124, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3867", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3867", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389133800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, J; Zhu, YL; Chen, Y; Wen, X; Long, MC; Wu, XH; Hu, ZW; Guan, DQ; Wang, XX; Zhou, C; Lin, Q; Sun, YF; Weng, SC; Wang, HT; Zhou, W; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Jie; Zhu, Yinlong; Chen, Yu; Wen, Xue; Long, Mingce; Wu, Xinhao; Hu, Zhiwei; Guan, Daqin; Wang, Xixi; Zhou, Chuan; Lin, Qian; Sun, Yifei; Weng, Shih-Chang; Wang, Huanting; Zhou, Wei; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While renewable H-2 production offers a promising route for clean energy production, there is an urgent need to improve catalyst performances. Here, authors design a Pt-containing complex oxide that utilizes atomic-scale hydrogen spillover to promote H-2 evolution electrocatalysis in acidic media. Improving the catalytic efficiency of platinum for the hydrogen evolution reaction is valuable for water splitting technologies. Hydrogen spillover has emerged as a new strategy in designing binary-component Pt/support electrocatalysts. However, such binary catalysts often suffer from a long reaction pathway, undesirable interfacial barrier, and complicated synthetic processes. Here we report a single-phase complex oxide La2Sr2PtO7+delta as a high-performance hydrogen evolution electrocatalyst in acidic media utilizing an atomic-scale hydrogen spillover effect between multifunctional catalytic sites. With insights from comprehensive experiments and theoretical calculations, the overall hydrogen evolution pathway proceeds along three steps: fast proton adsorption on O site, facile hydrogen migration from O site to Pt site via thermoneutral La-Pt bridge site serving as the mediator, and favorable H-2 desorption on Pt site. Benefiting from this catalytic process, the resulting La2Sr2PtO7+delta exhibits a low overpotential of 13 mV at 10 mA cm(-2), a small Tafel slope of 22 mV dec(-1), an enhanced intrinsic activity, and a greater durability than commercial Pt black catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1189, "DOI": "10.1038/s41467-022-28843-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28843-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764895600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, B; Zhang, X; Xie, Y; Lin, RB; Krishna, R; Cui, H; Li, ZQ; Shi, YS; Wu, H; Zhou, W; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Bin; Zhang, Xin; Xie, Yi; Lin, Rui-Biao; Krishna, Rajamani; Cui, Hui; Li, Zhiqiang; Shi, Yanshu; Wu, Hui; Zhou, Wei; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Ultramicroporous Metal-Organic Framework for High Sieving Separation of Propylene from Propane", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly selective adsorptive separation of olefin/paraffin through porous materials can produce high purity olefins in a much more energy-efficient way than the traditional cryogenic distillation. Here we report an ultramicroporous cobalt gallate metal-organic framework (Co-gallate) for the highly selective sieving separation of propylene/propane at ambient conditions. This material possesses optimal pore structure for the exact confinement of propylene molecules while excluding the slightly large propane molecules, as clearly demonstrated in the neutron diffraction crystal structure of Co-gallateD0.38C(3)D(6). Its high separation performance has been confirmed by the gas sorption isotherms and column breakthrough experiments to produce the high purity of propylene (97.7%) with a high dynamic separation productivity of 36.4 cm(3) cm(-3) under ambient conditions. The gas adsorption measurement, pore size distribution, and crystallographic and modeling studies comprehensively support the high sieving C3H6/C3H8 separation in this MOF material. It is stable under different environments, providing its potential for the industrial propylene purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2020, "Volume": 142, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17795, "End Page": 17801, "Article Number": null, "DOI": "10.1021/jacs.0c09466", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c09466", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579400400067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZM; Berbille, A; Feng, YW; Li, S; Zhu, LP; Tang, W; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ziming; Berbille, Andy; Feng, Yawei; Li, Site; Zhu, Laipan; Tang, Wei; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contact-electro-catalysis for the degradation of organic pollutants using pristine dielectric powders", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanochemistry has been studied for some time, but research on the reactivity of charges exchanged by contact-electrification (CE) during mechanical stimulation remains scarce. Here, we demonstrate that electrons transferred during the CE between pristine dielectric powders and water can be utilized to directly catalyze reactions without the use of conventional catalysts. Specifically, frequent CE at Fluorinated Ethylene Propylene (FEP) - water interface induces electron-exchanges, thus forming reactive oxygen species for the degradation of an aqueous methyl orange solution. Contact-electro-catalysis, by conjunction of CE, mechanochemistry and catalysis, has been proposed as a general mechanism, which has been demonstrated to be effective for various dielectric materials, such as Teflon, Nylon-6,6 and rubber. This original catalytic principle not only expands the range of catalytic materials, but also enables us to envisage catalytic processes through mechano-induced contact-electrification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 130, "DOI": "10.1038/s41467-021-27789-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27789-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028310300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZC; Zhang, WJ; Wu, SH; Zhu, HM; Liu, ZH; Liu, ZY; Jiang, ZY; Chen, R; Zhou, J; Lu, Q; Xiao, ZW; Shi, L; Chen, H; Ono, L; Zhang, SS; Zhang, YQ; Qi, YB; Han, LY; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zhichun; Zhang, Wenjun; Wu, Shaohang; Zhu, Hongmei; Liu, Zonghao; Liu, Zhiyang; Jiang, Zhaoyi; Chen, Rui; Zhou, Jing; Lu, Qian; Xiao, Zewen; Shi, Lei; Chen, Han; Ono, Luis K.; Zhang, Shasha; Zhang, Yiqiang; Qi, Yabing; Han, Liyuan; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Slot-die coating large-area formamidinium-cesium perovskite film for efficient and stable parallel solar module", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells have emerged as one of the most promising thin-film photovoltaic (PV) technologies and have made a strong debut in the PV field. However, they still face difficulties with up-scaling to module-level devices and long-term stability issue. Here, we report the use of a room-temperature nonvolatile Lewis base additive, diphenyl sulfoxide(DPSO), in formamidinium-cesium (FACs) perovskite precursor solution to enhance the nucleation barrier and stabilize the wet precursor film for the scalable fabrication of uniform, large-area FACs perovskite films. With a parallel-interconnected module design, the resultant solar module realized a certified quasi-stabilized efficiency of 16.63% with an active area of 20.77 cm(2). The encapsulated modules maintained 97 and 95% of their initial efficiencies after 10,000 and 1187 hours under day/night cycling and 1-sun equivalent white-light light-emitting diode array illumination with maximum power point tracking at 50 degrees C, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg3749", "DOI": "10.1126/sciadv.abg3749", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg3749", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677572600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, CJ; Yan, X; Jin, DF; Ma, Y; Hsiao, HW; Lin, YL; Bretz-Sullivan, TM; Zhou, XJ; Pearson, J; Fisher, B; Jiang, JS; Han, W; Zuo, JM; Wen, JG; Fong, DD; Sun, JR; Zhou, H; Bhattacharya, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Changjiang; Yan, Xi; Jin, Dafei; Ma, Yang; Hsiao, Haw-Wen; Lin, Yulin; Bretz-Sullivan, Terence M.; Zhou, Xianjing; Pearson, John; Fisher, Brandon; Jiang, J. Samuel; Han, Wei; Zuo, Jian-Min; Wen, Jianguo; Fong, Dillon D.; Sun, Jirong; Zhou, Hua; Bhattacharya, Anulld", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional superconductivity and anisotropic transport at KTaO3 (111) interfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The distinctive electronic structure found at interfaces between materials can allow unconventional quantum states to emerge. Here we report on the discovery of superconductivity in electron gases formed at interfaces between (111)-oriented KTaO3 and insulating overlayers of either EuO or LaAlO3. The superconducting transition temperature, as high as 2.2 kelvin, is about one order of magnitude higher than that of the LaAlO3/SrTiO3 system. Notably, similar electron gases at KTaO3 (001) interfaces remain normal down to 25 millikelvin. The critical field and current-voltage measurements indicate that the superconductivity is two-dimensional. In EuO/KTaO3 (111) samples, a spontaneous in-plane transport anisotropy is observed before the onset of superconductivity, suggesting the emergence of a distinct stripe-like phase, which is also revealed near the critical field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 371, "Issue": 6530, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 716, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba5511", "DOI Link": "http://dx.doi.org/10.1126/science.aba5511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617551600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JL; Wang, XY; Lin, ZH; Xu, N; Li, XQ; Liang, J; Zhao, W; Lin, RX; Zhu, B; Liu, GL; Zhou, L; Zhu, SN; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jinlei; Wang, Xueyang; Lin, Zhenhui; Xu, Ning; Li, Xiuqiang; Liang, Jie; Zhao, Wei; Lin, Renxing; Zhu, Bin; Liu, Guoliang; Zhou, Lin; Zhu, Shining; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 10 kg m-2 h-1 Evaporation Rate Enabled by a 3D Interconnected Porous Carbon Foam", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent advancements in evaporating water using renewable energy provide one of the promising pathways for treating water with minimized carbon footprint. Pursuing a high evaporation rate of water has been the central focus of this field, as it is directly related to the throughput of evaporative water treatment. However, in conventional designs of evaporators, diffusion of vapor into the atmospheric environment has been the limiting step for evaporation. In this work, we demonstrate that a carbon foam with a three-dimensional interconnected porous structure enables sufficient diffusion of vapor with a convective flow and therefore realizes an evaporation rate as high as 10.9 kg m(-2) h(-1) and outdoor evaporation of 42.0 kg m(-2) for continuous 13 h. With such a high evaporation rate achieved, it shows great promise toward a high-throughput, around-the-clock, and eco-friendly technology of evaporative wastewater disposal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 928, "End Page": 937, "Article Number": null, "DOI": "10.1016/j.joule.2020.02.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.02.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527264500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aivazian, G; Gong, ZR; Jones, AM; Chu, RL; Yan, J; Mandrus, DG; Zhang, CW; Cobden, D; Yao, W; Xu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aivazian, G.; Gong, Zhirui; Jones, Aaron M.; Chu, Rui-Lin; Yan, J.; Mandrus, D. G.; Zhang, Chuanwei; Cobden, David; Yao, Wang; Xu, X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic control of valley pseudospin in monolayer WSe2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Local energy extrema of the bands in momentum space, or valleys, can endow electrons in solids with pseudospin in addition to real spies. In transition metal dichalcogenides this valley pseudospin, like real spin, is associated with a magnetic moment(1,6) that underlies the valley-dependent circular dichroism(6) that allows optical generation of valley polarization(7-9), intervalley quantum coherence(10) and the valley Hall effect(11). However, magnetic manipulation of valley pseudospin via this magnetic momentlz(12,13), analogous to what is possible with real spin, has not been shown before. Here we report observation of the valley Zeeman splitting and magnetic tuning of polarization and coherence of the excitonic valley pseudospin, by performing polarization-resolved magneto-photoluminescence on monolayer WSe2. Our measurements reveal both the atomic orbital and lattice contributions to the valley orbital magnetic moment; demonstrate the deviation of the band edges in the valleys from an exact massive Dirac fermion model; and reveal a striking difference between the magnetic responses of neutral and charged valley excitons that is explained by renormalization of the excitonic spectrum due to strong exchange interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 767, "Times Cited, All Databases": 842, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 148, "End Page": 152, "Article Number": null, "DOI": "10.1038/NPHYS3201", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349934700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jose, V; Hu, HM; Edison, E; Manalastas, W; Ren, H; Kidkhunthod, P; Sreejith, S; Jayakumar, A; Nsanzimana, JMV; Srinivasan, M; Choi, JH; Lee, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jose, Vishal; Hu, Huimin; Edison, Eldho; Manalastas, William, Jr.; Ren, Hao; Kidkhunthod, Pinit; Sreejith, Sivaramapanicker; Jayakumar, Anjali; Nsanzimana, Jean Marie Vianney; Srinivasan, Madhavi; Choi, Jinho; Lee, Jong-Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulation of Single Atomic Co and Fe Sites on Hollow Carbon nullospheres as Oxygen Electrodes for Rechargeable Zn-Air Batteries", "Source Title": "SMALL METHODS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient bifunctional electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are required for metal air batteries, to replace costly metals, such as Pt and Ir/Ru based compounds, which are typically used as benchmarks for ORR and OER, respectively. Isolated single atomic sites coordinated with nitrogen on carbon supports (M-N-C) have promising performance for replacement of precious metal catalysts. However, most of monometallic M-N-C catalysts demonstrate unsatisfactory bifunctional performance. Herein, a facile way of preparing bimetallic Fe and Co sites entrapped in nitrogen-doped hollow carbon nullospheres (Fe,Co-SA/CS) is explored, drawing on the unique structure and pore characteristics of Zeolitic imidazole frameworks and molecular size of Ferrocene, an Fe containing species. Fe,Co-SA/CS showed an ORR onset potential and half wave potential of 0.96 and 0.86 V, respectively. For OER, (Fe,Co)-SA/CS attained its anodic current density of 10 mA cm(-2)at an overpotential of 360 mV. Interestingly, the oxygen electrode activity (Delta E) for (Fe,Co)-SA/CS and commercial Pt/C-RuO(2)is calculated to be 0.73 V, exhibiting the bifunctional catalytic activity of (Fe,Co)-SA/CS. (Fe,Co)-SA/CS evidenced desirable specific capacity and cyclic stability than Pt/C-RuO2 mixture when utilized as an air cathode in a homemade Zinc-air battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000751, "DOI": "10.1002/smtd.202000751", "DOI Link": "http://dx.doi.org/10.1002/smtd.202000751", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000576256500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Macino, M; Barnes, AJ; Qu, RY; Gibson, EK; Morgan, DJ; Freakley, SJ; Dimitratos, N; Kiely, CJ; Gao, X; Beale, AM; Bethell, D; He, Q; Sankar, M; Hutchings, GJ; Althahban, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Macino, Margherita; Barnes, Alexandra J.; Qu, Ruiyang; Gibson, Emma K.; Morgan, David J.; Freakley, Simon J.; Dimitratos, Nikolaos; Kiely, Christopher J.; Gao, Xiang; Beale, Andrew M.; Bethell, Donald; He, Qian; Sankar, Meenakshisundaram; Hutchings, Graham J.; Althahban, Sultan M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning of catalytic sites in Pt/TiO2 catalysts for the chemoselective hydrogenation of 3-nitrostyrene", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic activities of supported metal nulloparticles can be tuned by appropriate design of synthesis strategies. Each step in a catalyst synthesis method can play an important role in preparing the most efficient catalyst. Here we report the careful manipulation of the post-synthetic heat treatment procedure-together with control over the metal loading-to prepare a highly efficient 0.2 wt% Pt/TiO2 catalyst for the chemoselective hydrogenation of 3-nitrostyrene. For Pt/TiO2 catalysts with 0.2 and 0.5 wt% loading levels, reduction at 450 degrees C induces the coverage of TiOx over Pt nulloparticles through a strong metal-support interaction, which is detrimental to their catalytic activities. However, this can be avoided by following calcination treatment with reduction (both at 450 degrees C), allowing us to prepare an exceptionally active catalyst. Detailed characterization has revealed that the peripheral sites at the Pt/TiO2 interface are the most likely active sites for this hydrogenation reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 873, "End Page": 881, "Article Number": null, "DOI": "10.1038/s41929-019-0334-3", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0334-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489769600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ML; Lu, YP; Wang, TM; Zhang, CA; Cao, ZQ; Li, TJ; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mingliang; Lu, Yiping; Wang, Tongmin; Zhang, Chuan; Cao, Zhiqiang; Li, Tingju; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel bulk eutectic high-entropy alloy with outstanding as-cast specific yield strengths at elevated temperatures", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to their excellent properties and great potential for industrial application, eutectic high-entropy alloys (EHEAs) have been a hot topic of study over the past few years. The current study reports a novel AlCr1.3TiNi2 EHEA with a low density and outstanding mechanical properties at elevated temperatures. A kilogram-scale EHEA ingot with uniform and ultrafine L2(1) and BCC lamellar structures (interlamellar spacing similar to 400 nm) was firstly prepared by a direct solidification method. The as-cast AlCr1.3TiNi2 EHEA exhibits much higher room- and high-temperature hardness and specific yield strength values than most reported refractory high-entropy alloys (RHEAS), EHEAs, and conventional Ni- and Ti-based alloys. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 204, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114132, "DOI": "10.1016/j.scriptamat.2021.114132", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2021.114132", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000690402200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, CX; Jiang, X; Shen, XJ; Hu, JG; Tang, W; Wu, XX; Ragauskas, A; Jameel, H; Meng, XZ; Yong, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Caoxing; Jiang, Xiao; Shen, Xiaojun; Hu, Jinguang; Tang, Wei; Wu, Xinxing; Ragauskas, Arthur; Jameel, Hasan; Meng, Xianzhi; Yong, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lignin-enzyme interaction: A roadblock for efficient enzymatic hydrolysis of lignocellulosics", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficiently producing second-generation biofuels from biomass is of strategic significance and meets sustainability targets, but it remains a long-term challenge due to the existence of biomass recalcitrance. Lignin contributes significantly to biomass recalcitrance by physically limiting the access of enzymes to carbohydrates, and this could be partially overcome by applying a pretreatment step to directly target lignin. However, lignin typically cannot be completely removed, and its structure is also significantly altered during the pretreatment. As a result, lignin residue in the pretreated materials still significantly hindered a complete conversion of carbohydrate to its monosugars by interacting with cellulase enzymes. The non-productive adsorption driven by hydrophobic, electrostatic, and/or hydrogen bonding interactions is widely considered as the major mechanism of action governing the unfavored lignin-enzyme interaction. One could argue this type of interaction between lignin residue and the activated enzymes is the major roadblock for efficient enzymatic hydrolysis of pretreated lignocellulosics. To alleviate the negative effects of lignin on enzyme performance, a deep understanding of lignin structural transformation upon different types of pretreatments as well as how and where does lignin bind to enzymes are prerequisites. In the last decade, the progress toward a fundamental understanding of ligninenzyme interaction, structural characterization of lignin during pretreatment and/or conformation change of enzyme during hydrolysis is resulting in advances in the development of methodologies to mitigate the negative effect of lignin. Here in this review, the lignin structural transformation upon different types of pretreatments and the inhibition mechanism of lignin in the bioconversion of lignocellulose to bioethanol are summarized. Some technologies to minimize the adverse impact of lignin on the enzymatic hydrolysis, including chemical modification of lignin, adding blocking additives, and post-treatment to remove lignin were also introduced. The production of liquid biofuels from lignocellulosic biomass has shown great environmental benefits such as reducing greenhouse gas emissions and mitigate climate change. By addressing the root causes of lignin-enzyme interaction and how to retard this interaction, it is our hope that this comprehensive review will pave the way for significantly reducing the high cost associated with the enzymatic hydrolysis process, and ultimately achieving a cost-effective and sustainable biorefinery system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 154, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111822, "DOI": "10.1016/j.rser.2021.111822", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2021.111822", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000717972200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, SJ; Dong, XY; Zhao, P; Luo, ZC; Sun, ZH; Yang, XX; Li, QH; Wang, L; Zhang, YG; Zhou, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Shijie; Dong, Xinyue; Zhao, Peng; Luo, Zhicheng; Sun, Zhuohua; Yang, Xiaoxiao; Li, Qinghai; Wang, Lei; Zhang, Yanguo; Zhou, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decoupled temperature and pressure hydrothermal synthesis of carbon sub-micron spheres from cellulose", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Temperature and pressure are typically dependent parameters in hydrothermal processes. Here, authors devise a hydrothermal system that allows independent control of these parameters and realize low-temperature fast synthesis of carbon sub-micron spheres directly from cellulose at higher pressure. The temperature and pressure of the hydrothermal process occurring in a batch reactor are typically coupled. Herein, we develop a decoupled temperature and pressure hydrothermal system that can heat the cellulose at a constant pressure, thus lowering the degradation temperature of cellulose significantly and enabling the fast production of carbon sub-micron spheres. Carbon sub-micron spheres can be produced without any isothermal time, much faster compared to the conventional hydrothermal process. High-pressure water can help to cleave the hydrogen bonds in cellulose and facilitate dehydration reactions, thus promoting cellulose carbonization at low temperatures. A life cycle assessment based on a conceptual biorefinery design reveals that this technology leads to a substantial reduction in carbon emissions when hydrochar replacing fuel or used for soil amendment. Overall, the decoupled temperature and pressure hydrothermal treatment in this study provides a promising method to produce sustainable carbon materials from cellulose with a carbon-negative effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3616, "DOI": "10.1038/s41467-022-31352-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31352-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000815536300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Q; Kharzeev, DE; Zhang, C; Huang, Y; Pletikosic, I; Fedorov, AV; Zhong, RD; Schneeloch, JA; Gu, GD; Valla, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qiang; Kharzeev, Dmitri E.; Zhang, Cheng; Huang, Yuan; Pletikosic, I.; Fedorov, A. V.; Zhong, R. D.; Schneeloch, J. A.; Gu, G. D.; Valla, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral magnetic effect in ZrTe5", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "current induced by chirality imbalance in the presence of a magnetic field. It is a macroscopic manifestation of the quantumanomaly(1,2) in relativistic field theory of chiral fermions (massless spin 1/2 particles with a definite projection of spin on momentum)-a remarkable phenomenon arising from a collective motion of particles and antiparticles in the Dirac sea. The recent discovery(3-6) of Dirac semimetals with chiral quasiparticles opens a fascinating possibility to study this phenomenon in condensed matter experiments. Here we report on the measurement of magnetotransport in zirconium pentatelluride, ZrTe5, that provides strong evidence for the chiral magnetic effect. Our angle-resolved photoemission spectroscopy experiments show that this material's electronic structure is consistent with a three-dimensional Dirac semimetal. We observe a large negative magnetoresistance when the magnetic field is parallel with the current. The measured quadratic field dependence of the magnetoconductance is a clear indication of the chiral magnetic effect. The observed phenomenon stems fromthe effective transmutation of a Dirac semimetal into a Weyl semimetal induced by parallel electric and magnetic fields that represent a topologically non-trivial gauge field background. We expect that the chiral magnetic effect may emerge in a wide class of materials that are near the transition between the trivial and topological insulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 823, "Times Cited, All Databases": 878, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 12, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 550, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3648", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3648", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377475700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Xi, JB; Zhou, EZ; Peng, L; Chen, ZC; Gao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chen; Xi, Jiabin; Zhou, Erzhen; Peng, Li; Chen, Zichen; Gao, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Graphene Microflowers for High-Performance Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene has shown great potential in microwave absorption (MA) owing to its high surface area, low density, tunable electrical conductivity and good chemical stability. To fully realize graphene' s MA ability, the microstructure of graphene should be carefully addressed. Here we prepared graphene microflowers (Gmfs) with highly porous structure for high-performance MA filler material. The efficient absorption bandwidth (reflection loss <= -10 dB) reaches 5.59 GHz and the minimum reflection loss is up to -42.9 dB, showing significant increment compared with stacked graphene. Such performance is higher than most graphene-based materials in the literature. Besides, the low filling content (10 wt%) and low density (40-50 mg cm(-3)) are beneficial for the practical applications. Without compounding with magnetic materials or conductive polymers, Gmfs show outstanding MA performance with the aid of rational microstructure design. Furthermore, Gmfs exhibit advantages in facile processibility and large-scale production compared with other porous graphene materials including aerogels and foams. [GRAPHICS]", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26, "DOI": "10.1007/s40820-017-0179-8", "DOI Link": "http://dx.doi.org/10.1007/s40820-017-0179-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425093800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, P; Xie, QY; Ma, CF; Zhang, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Peng; Xie, Qingyi; Ma, Chunfeng; Zhang, Guangzhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silicone-Based Fouling-Release Coatings for Marine Antifouling", "Source Title": "LANGMUIR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Marine biofouling profoundly influences marine industries and activities. It slows the speed and increases the fuel consumption of ships, corrodes offshore platforms, and blocks seawater pipelines. The most effective and economical antifouling approach uses coatings. Fouling-release coatings (FRCs) with low surface free energy and high elasticity weakly adhere to marine organisms, so they can be readily removed by the water shear force. FRCs have attracted increasing interest because they are biocide-free and hence ecofriendly. However, traditional silicone-based FRCs have weak adhesion to substrates, low mechanical strength, and low fouling resistance, limiting their applications. In recent years, many attempts have been made to improve their mechanical properties and fouling resistance. This review deals with the progress in the construction of high-performance silicone-based fouling-release surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2020, "Volume": 36, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2170, "End Page": 2183, "Article Number": null, "DOI": "10.1021/acs.langmuir.9b03926", "DOI Link": "http://dx.doi.org/10.1021/acs.langmuir.9b03926", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519337400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MJ; Bhaumik, S; Goh, TW; Kumar, MS; Yantara, N; Grätzel, M; Mhaisalkar, S; Mathews, N; Sum, TC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mingjie; Bhaumik, Saikat; Goh, Teck Wee; Kumar, Muduli Subas; Yantara, Natalia; Graetzel, Michael; Mhaisalkar, Subodh; Mathews, Nripan; Sum, Tze Chien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Slow cooling and highly efficient extraction of hot carriers in colloidal perovskite nullocrystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hot-carrier solar cells can overcome the Schottky-Queisser limit by harvesting excess energy from hot carriers. Inorganic semiconductor nullocrystals are considered prime candidates. However, hot-carrier harvesting is compromised by competitive relaxation pathways (for example, intraband Auger process and defects) that overwhelm their phonon bottlenecks. Here we show colloidal halide perovskite nullocrystals transcend these limitations and exhibit around two orders slower hot-carrier cooling times and around four times larger hot-carrier temperatures than their bulk-film counterparts. Under low pump excitation, hot-carrier cooling mediated by a phonon bottleneck is surprisingly slower in smaller nullocrystals (contrasting with conventional nullocrystals). At high pump fluence, Auger heating dominates hot-carrier cooling, which is slower in larger nullocrystals (hitherto unobserved in conventional nullocrystals). Importantly, we demonstrate efficient room temperature hot-electrons extraction (up to similar to 83%) by an energy-selective electron acceptor layer within 1 ps from surface-treated perovskite NCs thin films. These insights enable fresh approaches for extremely thin absorber and concentrator-type hot-carrier solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14350, "DOI": "10.1038/ncomms14350", "DOI Link": "http://dx.doi.org/10.1038/ncomms14350", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393518000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martin, AA; Calta, NP; Khairallah, SA; Wang, J; Depond, PJ; Fong, AY; Thampy, V; Guss, GM; Kiss, AM; Stone, KH; Tassone, CJ; Weker, JN; Toney, MF; van Buuren, T; Matthews, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martin, Aiden A.; Calta, Nicholas P.; Khairallah, Saad A.; Wang, Jenny; Depond, Phillip J.; Fong, Anthony Y.; Thampy, Vivek; Guss, Gabe M.; Kiss, Andrew M.; Stone, Kevin H.; Tassone, Christopher J.; Weker, Johanna Nelson; Toney, Michael F.; van Buuren, Tony; Matthews, Manyalibo J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamics of pore formation during laser powder bed fusion additive manufacturing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser powder bed fusion additive manufacturing is an emerging 3D printing technique for the fabrication of advanced metal components. Widespread adoption of it and similar additive technologies is hampered by poor understanding of laser-metal interactions under such extreme thermal regimes. Here, we elucidate the mechanism of pore formation and liquid-solid interface dynamics during typical laser powder bed fusion conditions using in situ X-ray imaging and multi-physics simulations. Pores are revealed to form during changes in laser scan velocity due to the rapid formation then collapse of deep keyhole depressions in the surface which traps inert shielding gas in the solidifying metal. We develop a universal mitigation strategy which eliminates this pore formation process and improves the geometric quality of melt tracks. Our results provide insight into the physics of laser-metal interaction and demonstrate the potential for science-based approaches to improve confidence in components produced by laser powder bed fusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1987, "DOI": "10.1038/s41467-019-10009-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10009-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466333500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, Z; Nomoto, K; Wang, Q; Kong, C; Sun, LG; Zhang, LC; Liang, SX; Lu, J; Kruzic, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Zhe; Nomoto, Keita; Wang, Qing; Kong, Charlie; Sun, Ligang; Zhang, Lai-Chang; Liang, Shun-Xing; Lu, Jian; Kruzic, Jamie J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Self-Supported High-Entropy Metallic Glass with a nullosponge Architecture for Efficient Hydrogen Evolution under Alkaline and Acidic Conditions", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing highly efficient and durable electrocatalysts for hydrogen evolution reaction (HER) under both alkaline and acidic media is crucial for the future development of a hydrogen economy. However, state-of-the-art high-performance electrocatalysts recently developed are based on carbon carriers mediated by binding noble elements and their complicated processing methods are a major impediment to commercialization. Here, inspired by the high-entropy alloy concept with its inherent multinary nature and using a glassy alloy design with its chemical homogeneity and tunability, we present a scalable strategy to alloy five equiatomic elements, PdPtCuNiP, into a high-entropy metallic glass (HEMG) for HER in both alkaline and acidic conditions. Surface dealloying of the HEMG creates a nullosponge-like architecture with nullopores and embedded nullocrystals that provides abundant active sites to achieve outstanding HER activity. The obtained overpotentials at a current density of 10 mA cm(-2) are 32 and 62 mV in 1.0 m KOH and 0.5 m H2SO4 solutions, respectively, outperforming most currently available electrocatalysts. Density functional theory reveals that a lattice distortion and the chemical complexity of the nullocrystals lead to a strong synergistic effect on the electronic structure that further stabilizes hydrogen proton adsorption/desorption. This HEMG strategy establishes a new paradigm for designing compositionally complex alloys for electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 31, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101586, "DOI": "10.1002/adfm.202101586", "DOI Link": "http://dx.doi.org/10.1002/adfm.202101586", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000656109500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, YW; Baek, SHC; Kim, YM; Lee, HY; Lee, KD; Yang, CG; Park, ES; Lee, KS; Kim, KW; Go, G; Jeong, JR; Min, BC; Lee, HW; Lee, KJ; Park, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Young-Wan; Baek, Seung-Heon Chris; Kim, Y. M.; Lee, Hae Yeon; Lee, Kyeong-Dong; Yang, Chang-Geun; Park, Eun-Sang; Lee, Ki-Seung; Kim, Kyoung-Whan; Go, Gyungchoon; Jeong, Jong-Ryul; Min, Byoung-Chul; Lee, Hyun-Woo; Lee, Kyung-Jin; Park, Byong-Guk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-free switching of perpendicular magnetization through spin-orbit torque in antiferromagnet/ferromagnet/oxide structures", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-orbit torques arising from the spin-orbit coupling of non-magnetic heavy metals allow electrical switching of perpendicular magnetization. However, the switching is not purely electrical in laterally homogeneous structures. An extra in-plane magnetic field is indeed required to achieve deterministic switching, and this is detrimental for device applications. On the other hand, if antiferromagnets can generate spin-orbit torques, they may enable all-electrical deterministic switching because the desired magnetic field may be replaced by their exchange bias. Here we report sizeable spin-orbit torques in IrMn/CoFeB/MgO structures. The antiferromagnetic IrMn layer also supplies an in-plane exchange bias field, which enables all-electrical deterministic switching of perpendicular magnetization without any assistance from an external magnetic field. Together with sizeable spin-orbit torques, these features make antiferromagnets a promising candidate for future spintronic devices. We also show that the signs of the spin-orbit torques in various IrMn-based structures cannot be explained by existing theories and thus significant theoretical progress is required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 11, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 878, "End Page": "+", "Article Number": null, "DOI": "10.1038/NnullO.2016.109", "DOI Link": "http://dx.doi.org/10.1038/NnullO.2016.109", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385802900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZR; Ma, Q; Bi, Z; de la Barrera, S; Liu, MH; Mao, NN; Zhang, Y; Kiper, N; Watanabe, K; Taniguchi, T; Kong, J; Tisdale, WA; Ashoori, R; Gedik, N; Fu, L; Xu, SY; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhiren; Ma, Qiong; Bi, Zhen; de la Barrera, Sergio; Liu, Ming-Hao; Mao, nullnull; Zhang, Yang; Kiper, Natasha; Watanabe, Kenji; Taniguchi, Takashi; Kong, Jing; Tisdale, William A.; Ashoori, Ray; Gedik, Nuh; Fu, Liang; Xu, Su-Yang; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional ferroelectricity in moire heterostructures", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The constituent particles of matter can arrange themselves in various ways, giving rise to emergent phenomena that can be surprisingly rich and often cannot be understood by studying only the individual constituents. Discovering and understanding the emergence of such phenomena in quantum materials-especially those in which multiple degrees of freedom or energy scales are delicately balanced-is of fundamental interest to condensed-matter research(1,2). Here we report on the surprising observation of emergent ferroelectricity in graphene-based moire heterostructures. Ferroelectric materials show electrically switchable electric dipoles, which are usually formed by spatial separation between the average centres of positive and negative charge within the unit cell. On this basis, it is difficult to imagine graphene-a material composed of only carbon atoms-exhibiting ferroelectricity(3). However, in this work we realize switchable ferroelectricity in Bernal-stacked bilayer graphene sandwiched between two hexagonal boron nitride layers. By introducing a moire superlattice potential (via aligning bilayer graphene with the top and/or bottom boron nitride crystals), we observe prominent and robust hysteretic behaviour of the graphene resistance with an externally applied out-of-plane displacement field. Our systematic transport measurements reveal a rich and striking response as a function of displacement field and electron filling, and beyond the framework of conventional ferroelectrics. We further directly probe the ferroelectric polarization through a non-local monolayer graphene sensor. Our results suggest an unconventional, odd-parity electronic ordering in the bilayer graphene/boron nitride moire system. This emergent moire ferroelectricity may enable ultrafast, programmable and atomically thin carbon-based memory devices. Electronic ferroelectricity is observed in a graphene-based moire heterostructure, which is explained using a spontaneous interlayer charge-transfer model driven by layer-specific on-site Coulomb repulsion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2020, "Volume": 588, "Issue": 7836, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2970-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2970-9", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592032100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, HL; Gong, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Hailong; Gong, Jian Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabrication of Bioinspired Hydrogels: Challenges and Opportunities", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the birth of synthetic hydrogel 60 years ago, hydrogels possessing various useful properties and functions have been developed. The research directions of hydrogels have expanded to diverse application fields as well. However, in contrast to natural hydrogels found in biological soft tissues, which have elaborate structures from molecular to macroscopic scales and sophisticated functions, synthetic hydrogels only have very simple structures and naive functions. We have great opportunities to develop hydrogel materials through learning from nature. This Perspective discusses the opportunities and challenges in the fabrication of hydrogels with excellent physical functions by mimicking biological structures at different length scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2020, "Volume": 53, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2769, "End Page": 2782, "Article Number": null, "DOI": "10.1021/acs.macromol.0c00238", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.0c00238", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529885700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Somayazulu, M; Ahart, M; Mishra, AK; Geballe, ZM; Baldini, M; Meng, Y; Struzhkin, VV; Hemley, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Somayazulu, Maddury; Ahart, Muhtar; Mishra, Ajay K.; Geballe, Zachary M.; Baldini, Maria; Meng, Yue; Struzhkin, Viktor V.; Hemley, Russell J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for Superconductivity above 260 K in Lanthanum Superhydride at Megabar Pressures", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent predictions and experimental observations of high T-c superconductivity in hydrogen-rich materials at very high pressures are driving the search for superconductivity in the vicinity of room temperature. We have developed a novel preparation technique that is optimally suited for megabar pressure syntheses of superhydrides using modulated laser heating while maintaining the integrity of sample-probe contacts for electrical transport measurements to 200 GPa. We detail the synthesis and characterization of lanthanum superhydride samples, including four-probe electrical transport measurements that display significant drops in resistivity on cooling up to 260 K and 180-200 GPa, and resistivity transitions at both lower and higher temperatures in other experiments. Additional current-voltage measurements, critical current estimates, and low-temperature x-ray diffraction are also obtained. We suggest that the transitions represent signatures of superconductivity to near room temperature in phases of lanthanum superhydride, in good agreement with density functional structure search and BCS theory calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 955, "Times Cited, All Databases": 1036, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2019, "Volume": 122, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27001, "DOI": "10.1103/PhysRevLett.122.027001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.027001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455687700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XJ; Zhang, HZ; Zhao, XY; Zhang, P; Chen, MH; Zheng, ZK; Han, ZJ; Zhu, TS; Tong, YX; Lu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xinjun; Zhang, Haozhe; Zhao, Xingyu; Zhang, Peng; Chen, Minghua; Zheng, Zhikun; Han, Zhiji; Zhu, Tingshun; Tong, Yexiang; Lu, Xihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized Molybdenum Trioxide nullowires as Novel Ultrahigh-Capacity Cathode for Rechargeable Zinc Ion Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploration of high-performance cathode materials for rechargeable aqueous Zn ion batteries (ZIBs) is highly desirable. The potential of molybdenum trioxide (MoO3) in other electrochemical energy storage devices has been revealed but held understudied in ZIBs. Herein, a demonstration of orthorhombic MoO3 as an ultrahigh-capacity cathode material in ZIBs is presented. The energy storage mechanism of the MoO3 nullowires based on Zn2+ intercalation/deintercalation and its electrochemical instability mechanism are particularly investigated and elucidated. The severe capacity decay of the MoO3 nullowires during charging/discharging cycles arises from the dissolution and the structural collapse of MoO3 in aqueous electrolyte. To this end, an effective strategy to stabilize MoO3 nullowires by using a quasi-solid-state poly(vinyl alcohol)(PVA)/ZnCl2 gel electrolyte to replace the aqueous electrolyte is developed. The capacity retention of the assembled ZIBs after 400 charge/discharge cycles at 6.0 A g(-1) is significantly boosted, from 27.1% (in aqueous electrolyte) to 70.4% (in gel electrolyte). More remarkably, the stabilized quasi-solid-state ZIBs achieve an attracting areal capacity of 2.65 mAh cm(-2) and a gravimetric capacity of 241.3 mAh g(-1) at 0.4 A g(-1), outperforming most of recently reported ZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900151, "DOI": "10.1002/advs.201900151", "DOI Link": "http://dx.doi.org/10.1002/advs.201900151", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477711600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, J; Hinckley, AC; Huang, ZH; Feng, DW; Yakoyenko, AA; Lee, M; Chen, SC; Zou, X; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jihye; Hinckley, Allison C.; Huang, Zhehao; Feng, Dawei; Yakoyenko, Andrey A.; Lee, Minah; Chen, Shucheng; Zou, Xiaodong; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic Routes for a 2D Semiconductive Copper Hexahydroxybenzene Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conductive metal-organic frameworks (c-MOFs) have shown outstanding performance in energy storage and electrocatalysis. Varying the bridging metal species and the coordinating atom are versatile approaches to tune their intrinsic electronic properties in c-MOFs. Herein we report the first synthesis of the oxygen analog of M-3(C6X6)(2) (X = NH, S) family using Cu(II) and hexahydroxybenzene (HHB), namely Cu-HHB [Cu-3(C6O6)(2)], through a kinetically controlled approach with a competing coordination reagent. We also successfully demonstrate an economical synthetic approach using tetrahydroxyquinone as the starting material. Cu-HHB was found to have a partially eclipsed packing between adjacent 2D layers and a bandgap of approximately 1 eV. The addition of Cu-HHB to the family of synthetically realized M-3(C6X6)(2) c-MOFs will enable greater understanding of the influence of the organic linkers and metals, and further broadens the range of applications for these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2018, "Volume": 140, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14533, "End Page": 14537, "Article Number": null, "DOI": "10.1021/jacs.8b06666", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b06666", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449887800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WQ; Fu, CF; Low, JX; Duan, DL; Ma, J; Jiang, WB; Chen, YH; Liu, HJ; Qi, ZM; Long, R; Yao, YF; Li, XB; Zhang, H; Liu, Z; Yang, JL; Zou, ZG; Xiong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenqing; Fu, Cenfeng; Low, Jingxiang; Duan, Delong; Ma, Jun; Jiang, Wenbin; Chen, Yihong; Liu, Hengjie; Qi, Zeming; Long, Ran; Yao, Yingfang; Li, Xiaobao; Zhang, Hui; Liu, Zhi; Yang, Jinlong; Zou, Zhigang; Xiong, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance photocatalytic nonoxidative conversion of methane to ethane and hydrogen by heteroatoms-engineered TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic nonoxidative coupling of methane (NOCM) emerges as an appealing approach for the production of value-added C2 + hydrocarbons and hydrogen. Here the authors propose a heteroatom engineering strategy to prepare Pd single atoms loaded TiO2 for active and selective photocatalytic NOCM. Nonoxidative coupling of methane (NOCM) is a highly important process to simultaneously produce multicarbons and hydrogen. Although oxide-based photocatalysis opens opportunities for NOCM at mild condition, it suffers from unsatisfying selectivity and durability, due to overoxidation of CH4 with lattice oxygen. Here, we propose a heteroatom engineering strategy for highly active, selective and durable photocatalytic NOCM. Demonstrated by commonly used TiO2 photocatalyst, construction of Pd-O-4 in surface reduces contribution of O sites to valence band, overcoming the limitations. In contrast to state of the art, 94.3% selectivity is achieved for C2H6 production at 0.91 mmol g(-1) h(-1) along with stoichiometric H-2 production, approaching the level of thermocatalysis at relatively mild condition. As a benchmark, apparent quantum efficiency reaches 3.05% at 350 nm. Further elemental doping can elevate durability over 24 h by stabilizing lattice oxygen. This work provides new insights for high-performance photocatalytic NOCM by atomic engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2806, "DOI": "10.1038/s41467-022-30532-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30532-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798347800054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, F; Qin, JS; Wang, ZY; Yu, MZ; Wu, XH; Sun, XM; Qiu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Fu; Qin, Jingshan; Wang, Zhiyu; Yu, Mengzhou; Wu, Xianhong; Sun, Xiaoming; Qiu, Jieshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater electrolysis represents a potential solution to grid-scale production of carbon-neutral hydrogen energy without reliance on freshwater. However, it is challenged by high energy costs and detrimental chlorine chemistry in complex chemical environments. Here we demonstrate chlorine-free hydrogen production by hybrid seawater splitting coupling hydrazine degradation. It yields hydrogen at a rate of 9.2 mol h(-1) g(cat)(-1) on NiCo/MXene-based electrodes with a low electricity expense of 2.75 kWh per m(3) H-2 at 500 mA cm(-2) and 48% lower energy equivalent input relative to commercial alkaline water electrolysis. Chlorine electrochemistry is avoided by low cell voltages without anode protection regardless Cl- crossover. This electrolyzer meanwhile enables fast hydrazine degradation to similar to 3 ppb residual. Self-powered hybrid seawater electrolysis is realized by integrating low-voltage direct hydrazine fuel cells or solar cells. These findings enable further opportunities for efficient conversion of ocean resources to hydrogen fuel while removing harmful pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4182, "DOI": "10.1038/s41467-021-24529-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24529-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687325900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, WW; Yu, MA; Chen, T; Liu, YQ; Yi, YF; Huang, CY; Tang, J; Li, HY; Ou, MT; Wang, TQ; Wu, MY; Mei, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Weiwei; Yu, Mian; Chen, Ting; Liu, Yuanqi; Yi, Yunfei; Huang, Chenyi; Tang, Jia; Li, Hanyue; Ou, Meitong; Wang, Tianqi; Wu, Meiying; Mei, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polypyrrole nulloenzymes as Tumor Microenvironment Modulators to Reprogram Macrophage and Potentiate Immunotherapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullozyme-based tumor catalytic therapy has attracted widespread attention in recent years, but its therapeutic outcome is drastically diminished by species of nullozyme, concentration of substrate, pH value, and reaction temperature, etc. Herein, a novel Cu-doped polypyrrole nullozyme (CuP) with trienzyme-like activities, including catalase (CAT), glutathione peroxidase (GPx), and peroxidase (POD), is first proposed by a straightforward one-step procedure, which can specifically promote O-2 and center dot OH elevation but glutathione (GSH) reduction in tumor microenvironment (TME), causing irreversible oxidative stress damage to tumor cells and reversing the redox balance. The PEGylated CuP nullozyme (CuPP) has been demonstrated to efficiently reverse immunosuppressive TME by overcoming tumor hypoxia and re-educating macrophage from pro-tumoral M2 to anti-tumoral M1 phenotype. More importantly, CuPP exhibits hyperthermia-enhanced enzyme-mimic catalytic and immunoregulatory activities, which results in intense immune responses and almost complete tumor inhibition by further combining with alpha PD-L1. This work opens intriguing perspectives not only in enzyme-catalytic nullomedicine but also in macrophage-based tumor immunotherapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201703, "DOI": "10.1002/advs.202201703", "DOI Link": "http://dx.doi.org/10.1002/advs.202201703", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000807952700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Man, Z; Meng, Y; Lin, XC; Dai, XR; Wang, LP; Liu, DZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Man, Zun; Meng, Yang; Lin, Xiaochang; Dai, Xiaorong; Wang, Leiping; Liu, Dezhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assembling UiO-66@TiO2 nullocomposites for efficient photocatalytic degradation of dimethyl sulfide", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photocatalytic activity of titanium dioxide (TiO2) for the purification of odour pollutants, containing reduced sulfur compounds (RSCs), could be largely improved by the coupling of porous materials. Herein, UiO-66@TiO2 nullocomposites with different blending ratios were synthesized via a readily solvothermal method and characterized experimentally by XRD (X-ray diffraction), SEM (scanning electron microscope), FTIR (Fourier transform infrared spectrum), N2 isotherms, and UV-vis DRS (diffuse reflectance spectra). The photodegradation performance of dimethyl sulfide (DMS) by synthesized UiO-66@TiO2 was investigated under various photodegradation conditions, including photocatalyst dosage, DMS concentrations and relative humidity. The results showed that the U1T3 (UiO-66:TiO2 = 1:3) composites exhibited the highest photocatalytic activity, which was about 17.8 and 7.1 times higher than that of pristine UiO-66 and TiO2, respectively. This indicates that the intimate contact interfaces between UiO-66 and TiO2 could promote the separation and migration efficiency of photogenerated electron-hole pairs. When relative humidity increased from 0% to 60%, the photocatalytic activity was enhanced because the moisture could assist to produce more hydroxyl radicals. However, when the relative humidity was further increased to 90%, the excessive water would compete with DMS on the surface of UiO-66 and subsequently weaken the photocatalytic effects. During the cycling experiments, U1T3 showed a stable photocatalytic performance, and the plausible photocatalytic reaction mechanism and reaction pathways of DMS were proposed. With a significant enhancement of photocatalytic performance, UiO-66@TiO2 nullocomposites could promote the practical applications of MOF-based photocatalysts for the degradation of DMS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 431, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 133952, "DOI": "10.1016/j.cej.2021.133952", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.133952", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772781000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Godin, R; Wang, Y; Zwijnenburg, MA; Tang, JW; Durrant, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Godin, Robert; Wang, Yiou; Zwijnenburg, Martijn A.; Tang, Junwang; Durrant, James R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-Resolved Spectroscopic Investigation of Charge Trapping in Carbon Nitrides Photocatalysts for Hydrogen Generation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nitride (g-C3N4) as a benchmark polymer photocatalyst is attracting significant research interest because of its visible light photocatalytic performance combined with good stability and facile synthesis. However, little is known about the fundamental photophysical processes of g-C3N4, which are key to explain and promote photoactivity. Using time-resolved absorption and photoluminescence spectroscopies, we have investigated the photophysics of a series of carbon nitrides on time scales ranging from femtoseconds to seconds. Free charge carriers form within a 200 fs excitation pulse, trap on the picosecond time scale with trap states in a range of energies, and then recombine with power law decays that are indicative of charge trapping-detrapping processes. Delayed photoluminescence is assigned to thermal excitation of trapped carriers back up to the conduction/valence bands. We develop a simple, quantitative model for the charge carrier dynamics in these photocatalysts, which includes carrier relaxation into an exponential tail of trap states extending up to 1.5 eV into the bandgap. This trapping reduces the efficiency of surface photocatalytic reactions. Deep trapped electrons observed on micro- to millisecond time scales are unable to reduce electron acceptors on the surface or in solution. Within a series of g-C3N4, the yield of these unreactive trapped electrons correlates inversely with H-2 evolution rates. We conclude by arguing that the photophysics of these carbon nitride materials show closer parallels with inorganic semiconductors than conjugated polymers, and that the key challenge to optimize photocatalytic activity of these materials is to prevent electron trapping into deep, and photocatalytically inactive, electron trap states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 445, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2017, "Volume": 139, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5216, "End Page": 5224, "Article Number": null, "DOI": "10.1021/jacs.7b01547", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b01547", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399353800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neagu, D; Oh, TS; Miller, DN; Ménard, H; Bukhari, SM; Gamble, SR; Gorte, RJ; Vohs, JM; Irvine, JTS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Neagu, Dragos; Oh, Tae-Sik; Miller, David N.; Menard, Herve; Bukhari, Syed M.; Gamble, Stephen R.; Gorte, Raymond J.; Vohs, John M.; Irvine, John T. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal particles supported on oxide surfaces are used as catalysts for a wide variety of processes in the chemical and energy conversion industries. For catalytic applications, metal particles are generally formed on an oxide support by physical or chemical deposition, or less commonly by exsolution from it. Although fundamentally different, both methods might be assumed to produce morphologically and functionally similar particles. Here we show that unlike nickel particles deposited on perovskite oxides, exsolved analogues are socketed into the parent perovskite, leading to enhanced stability and a significant decrease in the propensity for hydrocarbon coking, indicative of a stronger metal-oxide interface. In addition, we reveal key surface effects and defect interactions critical for future design of exsolution-based perovskite materials for catalytic and other functionalities. This study provides a new dimension for tailoring particle-substrate interactions in the context of increasing interest for emergent interfacial phenomena.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 703, "Times Cited, All Databases": 751, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8120, "DOI": "10.1038/ncomms9120", "DOI Link": "http://dx.doi.org/10.1038/ncomms9120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362949100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, F; Liu, X; Fu, XG; Chen, HW; Huang, L; Fan, JJ; Le, JB; Wang, QX; Yang, WH; Ren, Y; Amine, K; Sun, SG; Xu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Fang; Liu, Xiang; Fu, Xiaoguang; Chen, Hongwei; Huang, Ling; Fan, Jingjing; Le, Jiabo; Wang, Qiuxiang; Yang, Weihua; Ren, Yang; Amine, Khalil; Sun, Shi-Gang; Xu, Gui-Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy and crystal-facet modulation of P2-type layered cathodes for long-lasting sodium-based batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of Mn-rich layered cathodes in Na-based batteries is hindered by inadequate cycling reversibility and sluggish anionic redox kinetics. Here, the authors report a strategy to stabilize the structure and promote anionic redox via configurational entropy and ion-diffusion structural tuning. P2-type sodium manganese-rich layered oxides are promising cathode candidates for sodium-based batteries because of their appealing cost-effective and capacity features. However, the structural distortion and cationic rearrangement induced by irreversible phase transition and anionic redox reaction at high cell voltage (i.e., >4.0 V) cause sluggish Na-ion kinetics and severe capacity decay. To circumvent these issues, here, we report a strategy to develop P2-type layered cathodes via configurational entropy and ion-diffusion structural tuning. In situ synchrotron X-ray diffraction combined with electrochemical kinetic tests and microstructural characterizations reveal that the entropy-tuned Na0.62Mn0.67Ni0.23Cu0.05Mg0.07Ti0.01O2 (CuMgTi-571) cathode possesses more {010} active facet, improved structural and thermal stability and faster anionic redox kinetics compared to Na0.62Mn0.67Ni0.37O2. When tested in combination with a Na metal anode and a non-aqueous NaClO4-based electrolyte solution in coin cell configuration, the CuMgTi-571-based positive electrode enables an 87% capacity retention after 500 cycles at 120 mA g(-1) and about 75% capacity retention after 2000 cycles at 1.2 A g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2826, "DOI": "10.1038/s41467-022-30113-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30113-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799632400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LQ; Hao, YX; Deng, LM; Hu, F; Zhao, S; Li, LL; Peng, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Luqi; Hao, Yixin; Deng, Liming; Hu, Feng; Zhao, Sheng; Li, Linlin; Peng, Shengjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid complete reconfiguration induced actual active species for industrial hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational regulation of electrochemical reconfiguration and exploration of activity origin are important foundations for realizing the optimization of electrocatalyst activity, but rather challenging. Herein, we potentially develop a rapid complete reconfiguration strategy for the heterostructures of CoC2O4 coated by MXene nullosheets (CoC2O4@MXene) during the hydrogen evolution reaction (HER) process. The self-assembled CoC2O4@MXene nullotubular structure has high electronic accessibility and abundant electrolyte diffusion channels, which favor the rapid complete reconfiguration. Such rapid reconfiguration creates new actual catalytic active species of Co(OH)(2) transformed from CoC2O4, which is coupled with MXene to facilitate charge transfer and decrease the free energy of the Volmer step toward fast HER kinetics. The reconfigured components require low overpotentials of 28 and 216 mV at 10 and 1000 mA cm(-2) in alkaline conditions and decent activity and stability in natural seawater. This work gives new insights for understanding the actual active species formation during HER and opens up a new way toward high-performance electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5785, "DOI": "10.1038/s41467-022-33590-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33590-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000864344500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Wu, ZH; Shao, WJ; Gao, Y; Wang, WW; Ma, T; Ma, L; Li, S; Cheng, C; Zhao, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ben; Wu, Zihe; Shao, Wenjie; Gao, Yun; Wang, Weiwen; Ma, Tian; Ma, Lang; Li, Shuang; Cheng, Chong; Zhao, Changsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Atom-Substitution Engineered Transition-Metal Hydroxide nullofibers with High-Valence Fe for Efficient Electrochemical Water Oxidation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing low-cost electrocatalysts for efficient and robust oxygen evolution reaction (OER) is the key for scalable water electrolysis, for instance, NiFe-based materials. Decorating NiFe catalysts with other transition metals offers a new path to boost their catalytic activities but often suffers from the low controllability of the electronic structures of the NiFe catalytic centers. Here, we report an interfacial atom-substitution strategy to synthesize an electrocatalytic oxygen-evolving NiFeV nullofiber to boost the activity of NiFe centers. The electronic structure analyses suggest that the NiFeV nullofiber exhibits abundant high-valence Fe via a charge transfer from Fe to V. The NiFeV nullofiber supported on a carbon cloth shows a low overpotential of 181 mV at 10 mA cm(-2), along with long-term stability (>20 h) at 100 mA cm(-2). The reported substitutional growth strategy offers an effective and new pathway for the design of efficient and durable non-noble metal-based OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2022, "Volume": 61, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202115331", "DOI": "10.1002/anie.202115331", "DOI Link": "http://dx.doi.org/10.1002/anie.202115331", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748150500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smiglak, M; Pringle, JM; Lu, X; Han, L; Zhang, S; Gao, H; MacFarlane, DR; Rogers, RD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smiglak, M.; Pringle, J. M.; Lu, X.; Han, L.; Zhang, S.; Gao, H.; MacFarlane, D. R.; Rogers, R. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic liquids for energy, materials, and medicine", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As highlighted by the recent ChemComm web themed issue on ionic liquids, this field continues to develop beyond the concept of interesting new solvents for application in the greening of the chemical industry. Here some current research trends in the field will be discussed which show that ionic liquids research is still aimed squarely at solving major societal issues by taking advantage of new fundamental understanding of the nature of these salts in their low temperature liquid state. This article discusses current research trends in applications of ionic liquids to energy, materials, and medicines to provide some insight into the directions, motivations, challenges, and successes being achieved with ionic liquids today.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2014, "Volume": 50, "Issue": 66, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9228, "End Page": 9250, "Article Number": null, "DOI": "10.1039/c4cc02021a", "DOI Link": "http://dx.doi.org/10.1039/c4cc02021a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340353300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, J; Li, H; Song, X; Fu, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, J.; Li, H.; Song, X.; Fu, M. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-scale defects in powder-based additively manufactured metals and alloys", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defect formation is a critical challenge for powder-based metal additive manufacturing (AM). Current understanding on the three important issues including formation mechanism, influence and control method of metal AM defects should be updated. In this review paper, multi-scale defects in AMed metals and alloys are identified and for the first time classified into three categories, including geometry related, surface integrity related and microstructural defects. In particular, the microstructural defects are further divided into internal cracks and pores, textured columnar grains, compositional defects and dislocation cells. The root causes of the multi-scale defects are discussed. The key factors that affect the defect formation are identified and analyzed. The detection methods and modeling of the multi-scale defects are briefly introduced. The effects of the multi-scale defects on the mechanical properties especially for tensile properties and fatigue performance of AMed metallic components are reviewed. Various control and mitigation methods for the corresponding defects, include process parameter control, post processing, alloy design and hybrid AM techniques, are summarized and discussed. From research aspect, current research gaps and future prospects from three important aspects of the multi-scale AM defects are identified and delineated. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2022, "Volume": 122, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 165, "End Page": 199, "Article Number": null, "DOI": "10.1016/j.jmst.2022.02.015", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2022.02.015", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788142500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, YY; Li, Y; Wu, XY; Wang, JL; Zhang, GK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Yuyu; Li, Yuan; Wu, Xiaoyong; Wang, Jinlong; Zhang, Gaoke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-scheme Sb2WO6/g-C3N4 photocatalysts with enhanced visible-light-induced photocatalytic NO oxidation performance", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Normal photocatalysts cannot effectively remove low-concentration NO because of the high recombination rate of the photogenerated carriers. To overcome this problem, S-scheme composites have been developed to fabricate photocatalysts. Herein, a novel S-scheme Sb2WO6/g-C3N4 nullocomposite was fabricated by an ultrasound-assisted method, which exhibited excellent performance for photocatalytic ppb-level NO removal. Compared with the pure constituents of the nullocomposite, the as-prepared 15%-Sb2WO6/g-C3N4 photocatalyst could remove more than 68% continuous-flowing NO (initial concentration: 400 ppb) under visible-light irradiation in 30 min. The findings of the trapping experiments confirmed that center dot O-2(-) and h(+) were the important active species in the NO oxidation reaction. Meanwhile, the transient photocurrent response and PL spectroscopy analyses proved that the unique S-scheme structure of the samples could enhance the charge separation efficiency. In situ DRIFTS revealed that the photocatalytic reaction pathway of NO removal over the Sb2WO6/g-C3N4 nullocomposite occurred via an oxygen-induced route. The present work proposes a new concept for fabricating efficient photocatalysts for photocatalytic ppb-level NO oxidation and provides deeper insights into the mechanism of photocatalytic NO oxidation. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 69, "End Page": 77, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63631-2", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63631-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mikolajick, T; Slesazeck, S; Mulaosmanovic, H; Park, MH; Fichtner, S; Lomenzo, PD; Hoffmann, M; Schroeder, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mikolajick, T.; Slesazeck, S.; Mulaosmanovic, H.; Park, M. H.; Fichtner, S.; Lomenzo, P. D.; Hoffmann, M.; Schroeder, U.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Next generation ferroelectric materials for semiconductor process integration and their applications", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectrics are a class of materials that possess a variety of interactions between electrical, mechanical, and thermal properties that have enabled a wealth of functionalities. To realize integrated systems, the integration of these functionalities into semiconductor processes is necessary. To this end, the complexity of well-known ferroelectric materials, e.g., the perovskite class, causes severe issues that limit its applications in integrated systems. The discovery of ferroelectricity in hafnium oxide-based materials brought a renewed interest into this field during the last decade. Very recently, ferroelectricity was also verified in aluminum scandium nitride extending the potential of seeing a wealth of ferroelectric functions in integrated electronics in the future. This paper discusses the prospects of both material systems in various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2021, "Volume": 129, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100901, "DOI": "10.1063/5.0037617", "DOI Link": "http://dx.doi.org/10.1063/5.0037617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628795200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Gadinski, MR; Huang, YQ; Ren, LL; Zhou, Y; Ai, D; Han, ZB; Yao, B; Wang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, He; Gadinski, Matthew R.; Huang, Yuqi; Ren, Lulu; Zhou, Yao; Ai, Ding; Han, Zhubing; Yao, Bin; Wang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crosslinked fluoropolymers exhibiting superior high-temperature energy density and charge-discharge efficiency", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrification of transport requires dielectric materials capable of operating efficiently at high temperatures to meet the increasing demand of electrical energy storage at extreme conditions. Current high-temperature dielectric polymers rely on the incorporation of wide bandgap inorganic fillers to restrain electrical conduction and achieve high efficiencies at elevated temperatures. Here, we report a new class of all-polymer based high-temperature dielectric materials prepared from crosslinking of melt-processable fluoropolymers. The crosslinked polymers exhibit larger discharged energy densities and greater charge-discharge efficiencies along with excellent breakdown strength and cyclic stability at elevated temperatures when compared to the current dielectric polymers. The origins of the marked improvement in the high-temperature capacitive performance are traced to efficient charge-trapping by a range of the molecular trapping centers resulting from the crosslinked structures. In addition, the implementation of melt-extrudable polymers would enable scalable processing that is compatible with the current fabrication techniques used for polymer dielectrics, which is in sharp contrast to the dielectric polymer composites with inorganic fillers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1279, "End Page": 1286, "Article Number": null, "DOI": "10.1039/c9ee03603b", "DOI Link": "http://dx.doi.org/10.1039/c9ee03603b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528728700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, Y; Yi, J; Wu, SC; Liu, Y; Yang, SX; He, P; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Yu; Yi, Jin; Wu, Shichao; Liu, Yang; Yang, Sixie; He, Ping; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Li-CO2 Electrochemistry: A New Strategy for CO2 Fixation and Energy Storage", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large energy is required for traditional CO2 fixation, leading to more CO2 emission and additional pollutants. Recently, integrating renewable energy with CO2 fixation has attracted increasing attention as a sustainable strategy. Here, based on a systematic investigation on aprotic Li-CO2 electrochemistry, we first provide an alternative strategy for either CO2 fixation or energy storage. Both strategies share the same CO2 reduction process with the formation of Li2CO3 and carbon. Subsequently, CO2 fixation is achieved through a rechargeable/irreversible oxidation process, during which Li2CO3 is decomposed, while the carbon obtained remains fixed. Moreover, a reversible Li-CO2 battery system has been realized based on co-oxidization of the resulting carbon and Li2CO3 using a Ru catalyst. Consequently, by shedding light on the fundamental reaction mechanism of aprotic Li-CO2 electrochemistry, the proof of concept presented here provides strong theoretical underpinning for developing flexible routes for both CO2 fixation and Li-CO2 energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 359, "End Page": 370, "Article Number": null, "DOI": "10.1016/j.joule.2017.07.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.07.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425180300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, C; Wu, SX; Fan, JZ; Luo, CJ; Fan, MH; Li, M; He, LP; Yang, YJ; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Cheng; Wu, Shuangxiang; Fan, Jinze; Luo, Chaojie; Fan, Minghui; Li, Ming; He, Lanping; Yang, Yuanjun; Zhang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectrically Modulated and Enhanced Photoresponse in a Self-Powered α-In2Se3/Si Heterojunction Photodetector", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photodetectors have been applied to pivotal optoelectronic components of modern optical communication, sensing, and imaging systems. As a room-temperature ferroelectric van der Waals semiconductor, 2D alpha-In2Se3 is a promising candidate for a next-generation optoelectronic material because of its thickness-dependent direct bandgap and excellent optoelectronic performance. Previous studies of photodetectors based on alpha-In2Se3 have been rarely focused on the modulated relationship between the alpha-In(2)Se(3)3 intrinsic ferroelectricity and photoresponsivity. Herein, a simple integrated process and high-performance photodetector based on an alpha-In2Se3/Si vertical hybrid-dimensional heterojunction was constructed. Our photodetector in the ferroelectric polarization up state accomplishes a self-powered, highly sensitive photoresponse with an on/off ratio of 4.5 x 10(5) and detectivity of 1.6 x 10(13) Jones, and it also shows a fast response time with 43 mu s. The depolarization field generated by the remanent polarization of ferroelectrics in alpha-In2Se3 provides a strategy for enhancement and modulation of photodetection. The negative correlation was discovered because the enhancement photoresponsivity factor of ferroelectric modulation competes with the photovoltaic behavior within the alpha-In2Se3/Si heterojunction. Our research highlights the great potential of the high-efficiency heterojunction photodetector for future object recognition and photoelectric imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2023, "Volume": 17, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6534, "End Page": 6544, "Article Number": null, "DOI": "10.1021/acsnullo.2c11925", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c11925", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959610300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Zhang, XY; Chen, ZW; Lin, SQ; Li, W; Shen, JH; Witting, IT; Faghaninia, A; Chen, Y; Jain, A; Chen, LD; Snyder, GJ; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Juan; Zhang, Xinyue; Chen, Zhiwei; Lin, Siqi; Li, Wen; Shen, Jiahong; Witting, Ian T.; Faghaninia, Alireza; Chen, Yue; Jain, Anubhav; Chen, Lidong; Snyder, G. Jeffrey; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Symmetry Rhombohedral GeTe Thermoelectrics", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-symmetry thermoelectric materials usually have the advantage of very high band degeneracy, while low-symmetry thermoelectrics have the advantage of very low lattice thermal conductivity. If the symmetry breaking of band degeneracy is small, both effects may be realized simultaneously. Here we demonstrate this principle in rhombohedral GeTe alloys, having a slightly reduced symmetry from its cubic structure, to realize a record figure of merit (zT similar to 2.4) at 600 K. This is enabled by the control of rhombohedral distortion in crystal structure for engineering the split low-symmetry bands to be converged and the resultant compositional complexity for simultaneously reducing the lattice thermal conductivity. Device ZT as high as 1.3 in the rhombohedral phase and 1.5 over the entire working temperature range of GeTe alloys make this material the most efficient thermoelectric to date. This work paves the way for exploring low-symmetry materials as efficient thermoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 976, "End Page": 987, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pathak, R; Chen, K; Gurung, A; Reza, KM; Bahrami, B; Pokharel, J; Baniya, A; He, W; Wu, F; Zhou, Y; Xu, K; Qiao, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pathak, Rajesh; Chen, Ke; Gurung, Ashim; Reza, Khan Mamun; Bahrami, Behzad; Pokharel, Jyotshna; Baniya, Abiral; He, Wei; Wu, Fan; Zhou, Yue; Xu, Kang; (Quinn) Qiao, Qiquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal anodes have attracted extensive attention owing to their high theoretical specific capacity. However, the notorious reactivity of lithium prevents their practical applications, as evidenced by the undesired lithium dendrite growth and unstable solid electrolyte interphase formation. Here, we develop a facile, cost-effective and one-step approach to create an artificial lithium metal/electrolyte interphase by treating the lithium anode with a tin-containing electrolyte. As a result, an artificial solid electrolyte interphase composed of lithium fluoride, tin, and the tin-lithium alloy is formed, which not only ensures fast lithium-ion diffusion and suppresses lithium dendrite growth but also brings a synergistic effect of storing lithium via a reversible tin-lithium alloy formation and enabling lithium plating underneath it. With such an artificial solid electrolyte interphase, lithium symmetrical cells show outstanding plating/stripping cycles, and the full cell exhibits remarkably better cycling stability and capacity retention as well as capacity utilization at high rates compared to bare lithium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 93, "DOI": "10.1038/s41467-019-13774-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13774-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551408700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, B; Lu, KQ; Tang, ZC; Chen, HM; Xu, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Bo; Lu, Kang-Qiang; Tang, Zichao; Chen, Hao Ming; Xu, Yi-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing ultrasmall Au clusters for enhanced photoredox catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, loading ligand-protected gold (Au) clusters as visible light photosensitizers onto various supports for photoredox catalysis has attracted considerable attention. However, the efficient control of long-term photostability of Au clusters on the metal-support interface remains challenging. Herein, we report a simple and efficient method for enhancing the photostability of glutathione-protected Au clusters (Au GSH clusters) loaded on the surface of SiO2 sphere by utilizing multifunctional branched poly-ethylenimine (BPEI) as a surface charge modifying, reducing and stabilizing agent. The sequential coating of thickness controlled TiO2 shells can further significantly improve the photocatalytic efficiency, while such structurally designed core-shell SiO2-Au GSH clusters-BPEI@TiO2 composites maintain high photostability during longtime light illumination conditions. This joint strategy via interfacial modification and composition engineering provides a facile guideline for stabilizing ultrasmall Au clusters and rational design of Au clusters-based composites with improved activity toward targeting applications in photoredox catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1543, "DOI": "10.1038/s41467-018-04020-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04020-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430286800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, XL; Lyu, SZ; Xu, XQ; Chen, WB; Shang, PN; Yang, ZF; Zhang, G; Chen, WH; Wang, YP; Chen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Xiaoli; Lyu, Shanzhi; Xu, Xiao-Qi; Chen, Weiben; Shang, Pengna; Yang, Zongfan; Zhang, Guang; Chen, Weihua; Wang, Yapei; Chen, Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superhydrophilic 2D Covalent Organic Frameworks as Broadband Absorbers for Efficient Solar Steam Generation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The intrinsic hydrophobicity and limited light absorption especially in the near-infrared (NIR) region of porous organic polymers are two bottlenecks impeding their applications in solar steam generation (SSG). Herein, we develop a 1,4,5,8-tetrakis(phenylamino)anthracene-9,10-dione (TPAD)-based covalent organic framework (COF) (TPAD-COF) featuring both superhydrophilicity and broad light absorption covering from the entire UV/Vis to NIR regions for SSG. TPAD-COF serving as a highly efficient photothermal conversion material without any additives displays an excellent water evaporation of 1.42 kg m(-2) h(-1) and achieves a high energy conversion efficiency of 94 % under 1 sun irradiation. Further extension of the light absorption range of the TPAD-based COF is realized through post-synthetic modification by chelating BF2 moieties. Systematic control experiments and analysis confirm that the hydrophilicity of photothermal conversion materials plays a more dominullt role in the current TPAD-based COFs for SSG.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2022, "Volume": 61, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202201900", "DOI": "10.1002/anie.202201900", "DOI Link": "http://dx.doi.org/10.1002/anie.202201900", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822495300056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giustino, F; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giustino, Feliciano; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward Lead-Free Perovskite Solar Cells", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the first reports of solar cells with power conversion efficiencies around 10% in 2012, the science and technology of perovskite photovoltaics has been progressing at an unprecedented rate. The current certified record efficiency of 22.1% makes perovskites the first solution-processable technology to outperform multicrystalline and thin-film silicon. For this technology to be deployed on a large scale, the two main challenges that need to be addressed are the material stability and the toxicity of lead. In particular, while lead is allowed in photovoltaic modules, it would be desirable to find alternatives which retain the unique optoelectronic properties of lead halide perovskites. Here we offer our perspective on the most exciting developments in the materials science of new halide perovskites, with an emphasis on alternatives to lead. After surveying recent developments of new perovskites and perovskite-related materials, we highlight the potential of halide double perovskites. This new family of compounds constitutes uncharted territory and may offer a broad materials library for solar energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 891, "Times Cited, All Databases": 937, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 1, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1233, "End Page": 1240, "Article Number": null, "DOI": "10.1021/acsenergylett.6b00499", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.6b00499", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390086400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, P; Chen, H; Chao, YG; Zhang, QH; Zhang, WY; Lv, F; Gu, L; Zhao, Q; Wang, N; Wang, JS; Guo, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Peng; Chen, Hui; Chao, Yuguang; Zhang, Qinghua; Zhang, Weiyu; Lv, Fan; Gu, Lin; Zhao, Qiang; Wang, Ning; Wang, Jinshu; Guo, Shaojun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Pt-I3 sites on all-inorganic Cs2SnI6 perovskite for efficient photocatalytic hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic lead halide perovskites are a new class of semiconductor materials with great potential in photocatalytic hydrogen production, however, their development is greatly plagued by their low photocatalytic activity, instability of organic component and lead toxicity in particular. Herein, we report an anti-dissolution environmentally friendly Cs2SnI6 perovskite anchored with a new class of atomically dispersed Pt-I-3 species (PtSA/Cs2SnI6) for achieving the highly efficient photocatalytic hydrogen production in HI aqueous solution at room temperature. Particularly, we discover that Cs2SnI6 in PtSA/Cs2SnI6 has a greatly enhanced tolerance towards HI aqueous solution, which is very important for achieving excellent photocatalytic stability in perovskite-based HI splitting system. Remarkably, the PtSA/Cs2SnI6 catalyst shows a superb photocatalytic activity for hydrogen production with a record turnover frequency of 70.6 h(-1)per Pt, about 176.5 times greater than that of Pt nulloparticles supported Cs2SnI6 perovskite, along with superior cycling durability. Charge-carrier dynamics studies in combination with theory calculations reveal that the dramatically boosted photocatalytic performance on PtSA/Cs2SnI6 originates from both unique coordination structure and electronic property of Pt-I-3 sites, and strong metal-support interaction effect that can not only greatly promote the charge separation and transfer, but also substantially reduce the energy barrier for hydrogen production. This work opens a new way for stimulating more research on perovskite composite materials for efficient hydrogen production. Organic-inorganic lead halide perovskites are a new class of photocatalysts, however, instability and toxicity pose challenges. Here, the authors report a non-toxic all-inorganic Cs2SnI6 perovskite anchored with atomically dispersed Pt-I-3 for efficient photocatalytic hydrogen production in hydrogen iodide solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4412, "DOI": "10.1038/s41467-021-24702-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24702-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677641700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Almeida, G; Goldoni, L; Akkerman, Q; Dang, ZY; Khan, AH; Marras, S; Moreels, I; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Almeida, Guilherme; Goldoni, Luca; Akkerman, Quinten; Dang, Zhiya; Khan, Ali Hossain; Marras, Sergio; Moreels, Iwan; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of Acid-Base Equilibria in the Size, Shape, and Phase Control of Cesium Lead Bromide nullocrystals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A binary ligand system composed of aliphatic carboxylic acids and primary amines of various chain lengths is commonly employed in diverse synthesis methods for CsPbBr3 nullocrystals (NCs). In this work, we have carried out a systematic study examining how the concentration of ligands (oleylamine and oleic acid) and the resulting acidity (or basicity) affects the hot injection synthesis of CsPbBr3 NCs. We devise a general synthesis scheme for cesium lead bromide NCs which allows control over size, size distribution, shape, and phase (CsPbBr3 or Cs4PbBr6) by combining key insights on the acid base interactions that rule this ligand system. Furthermore, our findings shed light upon the solubility of PbBr2 in this binary ligand system, and plausible mechanisms are suggested in order to understand the ligand-mediated phase control and structural stability of CsPbBr3 NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1704, "End Page": "+", "Article Number": null, "DOI": "10.1021/acsnullo.7b08357", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b08357", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426615600081", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schipper, F; Erickson, EM; Erk, C; Shin, JY; Chesneau, FF; Aurbach, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schipper, Florian; Erickson, Evan M.; Erk, Christoph; Shin, Ji-Yong; Chesneau, Frederick Francois; Aurbach, Doron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Review-Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium ion batteries have become an integral part of our daily lives. Among a number of different cathode materials nickel-rich LiNixCoyMnzO2 is particularly interesting. The material can deliver high capacities of similar to 195 mAh g(-1) putting it on the map for electric vehicles. With an increasing nickel content, a number of issues arise in the material limiting its performance. The Li/Ni mixing, highly reactive surface and formation of micro cracks are the most pressing ones. An overview of recent literature exploring these phenomena is herein summarized and were applicable solutions will be highlighted. (C) The Author(s) 2016. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 671, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 164, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A6220", "End Page": "A6228", "Article Number": null, "DOI": "10.1149/2.0351701jes", "DOI Link": "http://dx.doi.org/10.1149/2.0351701jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394508400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, M; Torbensen, K; Salvatore, D; Ren, SX; Joulié, D; Dumoulin, F; Mendoza, D; Lassalle-Kaiser, B; Isci, U; Berlinguette, CP; Robert, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Min; Torbensen, Kristian; Salvatore, Danielle; Ren, Shaoxuan; Joulie, Dorian; Dumoulin, Fabienne; Mendoza, Daniela; Lassalle-Kaiser, Benedikt; Isci, Umit; Berlinguette, Curtis P.; Robert, Marc", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular catalysts that combine high product selectivity and high current density for CO2 electrochemical reduction to CO or other chemical feedstocks are urgently needed. While earth-abundant metal-based molecular electrocatalysts with high selectivity for CO2 to CO conversion are known, they are characterized by current densities that are significantly lower than those obtained with solid-state metal materials. Here, we report that a cobalt phthalocyanine bearing a trimethyl ammonium group appended to the phthalocyanine macrocycle is capable of reducing CO2 to CO in water with high activity over a broad pH range from 4 to 14. In a flow cell configuration operating in basic conditions, CO production occurs with excellent selectivity (ca. 95%), and good stability with a maximum partial current density of 165 mA cm(-2) (at -0.92 V vs. RHE), matching the most active noble metal-based nullocatalysts. These results represent state-of-the-art performance for electrolytic carbon dioxide reduction by a molecular catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3602, "DOI": "10.1038/s41467-019-11542-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11542-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000480234500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sahabudeen, H; Qi, HY; Glatz, BA; Tranca, D; Dong, RH; Hou, Y; Zhang, T; Kuttner, C; Lehnert, T; Seifert, G; Kaiser, U; Fery, A; Zheng, ZK; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sahabudeen, Hafeesudeen; Qi, Haoyuan; Glatz, Bernhard Alexander; Tranca, Diana; Dong, Renhao; Hou, Yang; Zhang, Tao; Kuttner, Christian; Lehnert, Tibor; Seifert, Gotthard; Kaiser, Ute; Fery, Andreas; Zheng, Zhikun; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wafer-sized multifunctional polyimine-based two-dimensional conjugated polymers with high mechanical stiffness", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the key challenges in two-dimensional (2D) materials is to go beyond graphene, a prototype 2D polymer (2DP), and to synthesize its organic analogues with structural control at the atomic- or molecular-level. Here we show the successful preparation of porphyrin-containing monolayer and multilayer 2DPs through Schiff-base polycondensation reaction at an air-water and liquid-liquid interface, respectively. Both the monolayer and multilayer 2DPs have crystalline structures as indicated by selected area electron diffraction. The monolayer 2DP has a thickness of similar to 0.7 nm with a lateral size of 4-inch wafer, and it has a Young's modulus of 267 +/- 30 GPa. Notably, the monolayer 2DP functions as an active semiconducting layer in a thin film transistor, while the multilayer 2DP from cobalt-porphyrin monomer efficiently catalyses hydrogen generation from water. This work presents an advance in the synthesis of novel 2D materials for electronics and energy-related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13461, "DOI": "10.1038/ncomms13461", "DOI Link": "http://dx.doi.org/10.1038/ncomms13461", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387854900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, CC; Chen, CI; Liao, YT; Wu, KCW; Chueh, CC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Chia-Chen; Chen, Chih-I; Liao, Yu-Te; Wu, Kevin C. -W.; Chueh, Chu-Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing Efficiency and Stability of Photovoltaic Cells by Using Perovskite/Zr-MOF Heterojunction Including Bilayer and Hybrid Structures", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the effectiveness of using a perovskite/Zr-metal-organic frameworks (MOFs) heterojunction in realizing efficient and stable inverted p-i-n perovskite solar cells (PVSCs) is demonstrated. Two types of Zr-MOFs, UiO-66 and MOF-808, are investigated owing to their respectable moisture and chemical stabilities. The MOFs while serving as an interlayer in conjunction with the perovskite film are shown to possess the advantages of UV-filtering capability and enhancing perovskite crystallinity. Consequently, the UiO-66/MOF-808-modified PVSCs yield enhanced power conversion efficiencies (PCEs) of 17.01% and 16.55%, outperforming the control device (15.79%). While further utilizing a perovskite/Zr-MOF hybrid heterojunction to fabricate the devices, the hybrid MOFs are found to possibly distribute over the perovskite grain boundary providing a grain-locking effect to simultaneously passivate the defects and to reinforce the film's robustness against moisture invasion. As a result, the PCEs of the UiO-66/MOF-808-hybrid PVSCs are further enhanced to 18.01% and 17.81%, respectively. Besides, over 70% of the initial PCE is retained after being stored in air (25 degrees C and relative humidity of 60 +/- 5%) for over 2 weeks, in contrast to the quick degradation observed for the control device. This study demonstrates the promising potential of using perovskite/MOF heterojunctions to fabricate efficient and stable PVSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801715, "DOI": "10.1002/advs.201801715", "DOI Link": "http://dx.doi.org/10.1002/advs.201801715", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460374300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Belianinov, A; He, Q; Dziaugys, A; Maksymovych, P; Eliseev, E; Borisevich, A; Morozovska, A; Banys, J; Vysochanskii, Y; Kalinin, SV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Belianinov, A.; He, Q.; Dziaugys, A.; Maksymovych, P.; Eliseev, E.; Borisevich, A.; Morozovska, A.; Banys, J.; Vysochanskii, Y.; Kalinin, S. V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CuInP2S6 Room Temperature Layered Ferroelectric", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We explore ferroelectric properties of cleaved 2-D flakes of copper indium thiophosphate, CuInP2S6 (CITP), and probe size effects along with limits of ferroelectric phase stability, by ambient and ultra high vacuum scanning probe microscopy. CITP belongs to the only material family known to display ferroelectric polarization in a van der Waals, layered crystal at room temperature and above. Our measurements directly reveal stable, ferroelectric polarization as evidenced by domain structures, switchable polarization, and hysteresis loops. We found that at room temperature the domain structure of flakes thicker than 100 nm is similar to the cleaved bulk surfaces, whereas below 50 nm polarization disappears. We ascribe this behavior to a well-known instability of polarization due to depolarization field. Furthermore, polarization switching at high bias is also associated with ionic mobility, as evidenced both by macroscopic measurements and by formation of surface damage under the tip at a bias of 4 V-likely due to copper reduction. Mobile Cu ions may therefore also contribute to internal screening mechanisms. The existence of stable polarization in a van-der-Waals crystal naturally points toward new strategies for ultimate scaling of polar materials, quasi-2D, and single-layer materials with advanced and nonlinear dielectric properties that are presently not found in any members of the growing graphene family.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3808, "End Page": 3814, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b00491", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b00491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356316900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaji, H; Suzuki, H; Fukushima, T; Shizu, K; Suzuki, K; Kubo, S; Komino, T; Oiwa, H; Suzuki, F; Wakamiya, A; Murata, Y; Adachi, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kaji, Hironori; Suzuki, Hajime; Fukushima, Tatsuya; Shizu, Katsuyuki; Suzuki, Katsuaki; Kubo, Shosei; Komino, Takeshi; Oiwa, Hajime; Suzuki, Furitsu; Wakamiya, Atsushi; Murata, Yasujiro; Adachi, Chihaya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Purely organic electroluminescent material realizing 100% conversion from electricity to light", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient organic light-emitting diodes have been developed using emitters containing rare metals, such as platinum and iridium complexes. However, there is an urgent need to develop emitters composed of more abundant materials. Here we show a thermally activated delayed fluorescence material for organic light-emitting diodes, which realizes both approximately 100% photoluminescence quantum yield and approximately 100% up-conversion of the triplet to singlet excited state. The material contains electron-donating diphenylamin-ocarbazole and electron-accepting triphenyltriazine moieties. The typical trade-off between effective emission and triplet-to-singlet up-conversion is overcome by fine-tuning the highest occupied molecular orbital and lowest unoccupied molecular orbital distributions. The nearly zero singlet-triplet energy gap, smaller than the thermal energy at room temperature, results in an organic light-emitting diode with external quantum efficiency of 29.6%. An external quantum efficiency of 41.5% is obtained when using an out-coupling sheet. The external quantum efficiency is 30.7% even at a high luminullce of 3,000 cdm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 829, "Times Cited, All Databases": 846, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8476, "DOI": "10.1038/ncomms9476", "DOI Link": "http://dx.doi.org/10.1038/ncomms9476", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364926700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XM; Hu, JP; Cheng, YC; Yang, HY; Yao, YG; Yang, SYA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoming; Hu, Junping; Cheng, Yingchun; Yang, Hui Ying; Yao, Yugui; Yang, Shengyuan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Borophene as an extremely high capacity electrode material for Li-ion and Na-ion batteries", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials as electrodes is believed to be the trend for future Li-ion and Na-ion battery technologies. Here, by using first-principles methods, we predict that the recently reported borophene (2D boron sheets) can serve as an ideal electrode material with high electrochemical performance for both Li-ion and Na-ion batteries. The calculations are performed on two experimentally stable borophene structures, namely beta(12) and chi(3) structures. The optimized Li and Na adsorption sites are identified, and the host materials are found to maintain good electric conductivity before and after adsorption. Besides advantages including small diffusion barriers and low average open-circuit voltages, most remarkably, the storage capacity can be as high as 1984 mA h g(-1) in beta(12) borophene and 1240 mA h g(-1) in chi(3) borophene for both Li and Na, which are several times higher than the commercial graphite electrode and are the highest among all the 2D materials discovered to date. Our results highly support that borophenes can be appealing anode materials for both Li-ion and Na-ion batteries with extremely high power density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15340, "End Page": 15347, "Article Number": null, "DOI": "10.1039/c6nr04186h", "DOI Link": "http://dx.doi.org/10.1039/c6nr04186h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382068000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, R; Diederichs, C; Wang, J; Liew, TCH; Zhao, JX; Liu, S; Xu, WG; Chen, ZH; Xiong, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Rui; Diederichs, Carole; Wang, Jun; Liew, Timothy C. H.; Zhao, Jiaxin; Liu, Sheng; Xu, Weigao; Chen, Zhanghai; Xiong, Qihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-Temperature Polariton Lasing in All-Inorganic Perovskite nulloplatelets", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polariton lasing is the coherent emission arising from a macroscopic polariton condensate first proposed in 1996. Over the past two decades,. polariton lasing has been demonstrated in a few inorganic and organic semiconductors in both low and room temperatures. Polariton lasing in inorganic materials significantly relies on sophisticated epitaxial growth of crystalline gain medium layers sandwiched by two distributed Bragg reflectors in which combating the built-in strain and mismatched thermal properties is nontrivial. On the other hand, organic active media usually suffer from large threshold density and weak nonlinearity due to the Frenkel exciton nature. Further development of polariton lasing toward technologically significant applications demand more accessible materials, ease of device fabrication, and broadly tunable emission at room temperature. Herein, we report the experimental realization of room-temperature polariton lasing based on an epitaxy-free all-inorganic cesium lead chloride perovskite nulloplatelet microcavity. Polariton lasing is unambiguously evidenced by a superlinear power dependence, macroscopic ground-state occupation, blueshift of the ground-state emission, narrowing of the line width and the buildup of long-range spatial coherence. Our work suggests considerable promise of lead halide perovskites toward large-area, low-cost, high-performance room-temperature polariton devices and coherent light sources extending from the ultraviolet to near-infrared range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3982, "End Page": 3988, "Article Number": null, "DOI": "10.1021/acs.nullolett.7b01956", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.7b01956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403631600096", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, WY; Feng, LJ; Zhang, JC; Lin, K; Wang, H; Yan, BJ; Feng, TT; Cao, M; Liu, T; Yuan, YH; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Wenyan; Feng, Lijuan; Zhang, Jiacheng; Lin, Ke; Wang, Hui; Yan, Bingjie; Feng, Tiantian; Cao, Meng; Liu, Tao; Yuan, Yihui; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amidoxime Group-Anchored Single Cobalt Atoms for Anti-Biofouling during Uranium Extraction from Seawater", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Marine biofouling is one of the most significant challenges hindering practical uranium extraction from seawater. Single atoms have been widely used in catalytic applications because of their remarkable redox property, implying that the single atom is highly capable of catalyzing the generation of reactive oxygen species (ROS) and acts as an anti-biofouling substance for controlling biofouling. In this study, the Co single atom loaded polyacrylamidoxime (PAO) material, PAO-Co, is fabricated based on the binding ability of the amidoxime group to uranyl and cobalt ions. Nitrogen and oxygen atoms from the amidoxime group stabilize the Co single atom. The fabricated PAO-Co exhibits a broad range of antimicrobial activity against diverse marine microorganisms by producing ROS, with an inhibition rate up to 93.4%. The present study is the first to apply the single atom for controlling biofouling. The adsorbent achieves an ultrahigh uranium adsorption capacity of 9.7 mg g(-1) in biofouling-containing natural seawater, which decreased only by 11% compared with that in biofouling-removed natural seawater. These findings indicate that applying single atoms would be a promising strategy for designing biofouling-resistant adsorbents for uranium extraction from seawater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105008, "DOI": "10.1002/advs.202105008", "DOI Link": "http://dx.doi.org/10.1002/advs.202105008", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745461900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, XW; Li, YT; Qian, T; Liu, J; Zhou, JQ; Yan, CL; Goodenough, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Xiaowei; Li, Yutao; Qian, Tao; Liu, Jie; Zhou, Jinqiu; Yan, Chenglin; Goodenough, John B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium anode stable in air for low-cost fabrication of a dendrite-free lithium battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal, the ideal anode material for rechargeable batteries, suffers from the inherent limitations of sensitivity to the humid atmosphere and dendrite growth. Herein, low-cost fabrication of a metallic-lithium anode that is stable in air and plated dendrite-free from an organic-liquid electrolyte solves four key problems that have plagued the development of large-scale Li-ion batteries for storage of electric power. Replacing the low-capacity carbon anode with a safe, dendrite-free lithium anode provides a fast charge while reducing the cost of fabrication of a lithium battery, and increasing the cycle life of a rechargeable cell by eliminating the liquid-electrolyte ethylene-carbonate additive used to form a solid-electrolyte interphase passivation layer on the anode that is unstable during cycling. This solution is accomplished by formation of a hydrophobic solid-electrolyte interphase on a metallic-lithium anode that allows for handling of the treated lithium anode membrane in a standard dry room during cell fabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 900, "DOI": "10.1038/s41467-019-08767-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08767-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459403800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Wang, SC; Peng, JQ; Tan, YT; Li, CC; Boey, FYC; Long, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yang; Wang, Shancheng; Peng, Jinqing; Tan, Yutong; Li, Chuanchang; Boey, Freddy Yin Chiang; Long, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid Thermo-Responsive Smart Window Derived from Hydrogel", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Buildings account for 40% of global energy consumption, while windows are the least energy-efficient part of buildings. Conventional smart windows only regulate solar transmission. For the first time, we developed high thermal energy storage thermo-responsive smart window (HTEST smart window) by trapping the hydrogel-derived liquid within glasses. The excellent thermoresponsive optical property (90% of luminous transmittance and 68.1% solar modulation) together with outstanding specific heat capacity of liquid gives the HTEST smart window excellent energy conservation performance. Simulations suggested that HTEST window can cut off 44.6% heating, ventilation, and air-conditioning (HVAC) energy consumption compared with the normal glass in Singapore In outdoor demonstrations, the HTEST smart window showed promising energy-saving performance in summer daytime. Compared with conventional energy-saving glasses, which need expensive equipment, the thermo-responsive liquid-trapped structure offers a disruptive strategy of easy fabrication, good uniformity, and scalability, together with soundproof functionality that opens an avenue for energy-saving buildings and greenhouses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2020, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2458, "End Page": 2474, "Article Number": null, "DOI": "10.1016/j.joule.2020.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592226000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, M; Zhang, SN; van Eck, ERH; Wang, C; Ganapathy, S; Wagemaker, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ming; Zhang, Shengnull; van Eck, Ernst R. H.; Wang, Chao; Ganapathy, Swapna; Wagemaker, Marnix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving Li-ion interfacial transport in hybrid solid electrolytes", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of commercial solid-state batteries has to date been hindered by the individual limitations of inorganic and organic solid electrolytes, motivating hybrid concepts. However, the room-temperature conductivity of hybrid solid electrolytes is still insufficient to support the required battery performance. A key challenge is to assess the Li-ion transport over the inorganic and organic interfaces and relate this to surface chemistry. Here we study the interphase structure and the Li-ion transport across the interface of hybrid solid electrolytes using solid-state nuclear magnetic resonullce spectroscopy. In a hybrid solid polyethylene oxide polymer-inorganic electrolyte, we introduce two representative types of ionic liquid that have different miscibilities with the polymer. The poorly miscible ionic liquid wets the polymer-inorganic interface and increases the local polarizability. This lowers the diffusional barrier, resulting in an overall room-temperature conductivity of 2.47 x 10(-4) S cm(-1). A critical current density of 0.25 mA cm(-2) versus a Li-metal anode shows improved stability, allowing cycling of a LiFePO4-Li-metal solid-state cell at room temperature with a Coulombic efficiency of 99.9%. Tailoring the local interface environment between the inorganic and organic solid electrolyte components in hybrid solid electrolytes seems to be a viable route towards designing highly conducting hybrid solid electrolytes. NMR measurements show that the interface between the inorganic and organic components can be tailored to design a highly conducting hybrid solid electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 17, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 959, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-022-01162-9", "DOI Link": "http://dx.doi.org/10.1038/s41565-022-01162-9", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828445200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Chen, ZY; Song, X; Zhang, ZF; Zhang, J; Shung, KK; Zhou, QF; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yang; Chen, Zeyu; Song, Xuan; Zhang, Zhuofeng; Zhang, Jun; Shung, K. Kirk; Zhou, Qifa; Chen, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic Anisotropic Reinforcement Architectures by Electrically Assisted nullocomposite 3D Printing", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimetic architectures with Bouligand-type carbon nullotubes are fabricated by an electrically assisted 3D-printing method. The enhanced impact resistance is attributed to the energy dissipation by the rotating anisotropic layers. This approach is used to mimic the collagenfiber alignment in the human meniscus to create a reinforced artificial meniscus with circumferentially and radially aligned carbon nullotubes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2017, "Volume": 29, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605750, "DOI": "10.1002/adma.201605750", "DOI Link": "http://dx.doi.org/10.1002/adma.201605750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396375100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin-Alam, MS; Reshef, O; Mamchur, Y; Alam, MZ; Carlow, G; Upham, J; Sullivan, BT; Ménard, JM; Huttunen, MJ; Boyd, RW; Dolgaleva, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin-Alam, M. Saad; Reshef, Orad; Mamchur, Yaryna; Alam, M. Zahirul; Carlow, Graham; Upham, Jeremy; Sullivan, Brian T.; Menard, Jean-Michel; Huttunen, Mikko J.; Boyd, Robert W.; Dolgaleva, Ksenia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high-Q resonullces in plasmonic metasurfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmonic nullostructures hold promise for the realization of ultra-thin sub-wavelength devices, reducing power operating thresholds and enabling nonlinear optical functionality in metasurfaces. However, this promise is substantially undercut by absorption introduced by resistive losses, causing the metasurface community to turn away from plasmonics in favour of alternative material platforms (e.g., dielectrics) that provide weaker field enhancement, but more tolerable losses. Here, we report a plasmonic metasurface with a quality-factor (Q-factor) of 2340 in the telecommunication C band by exploiting surface lattice resonullces (SLRs), exceeding the record by an order of magnitude. Additionally, we show that SLRs retain many of the same benefits as localized plasmonic resonullces, such as field enhancement and strong confinement of light along the metal surface. Our results demonstrate that SLRs provide an exciting and unexplored method to tailor incident light fields, and could pave the way to flexible wavelength-scale devices for any optical resonating application. Metallic nullostructures are useful in many optical devices due to their nonlinear properties and responses to interaction with light. Here the authors demonstrate a metasurface of gold nulloparticle arrays with ultra-narrow surface lattice resonullces of high quality-factor that operates in the telecommunication band.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 974, "DOI": "10.1038/s41467-021-21196-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21196-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620683400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Sun, JH; Huang, HH; Bai, LL; Zhao, XM; Qu, BH; Xiong, LQ; Bai, FQ; Tang, JW; Jing, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yang; Sun, Jianhui; Huang, Houhou; Bai, Linlu; Zhao, Xiaomeng; Qu, Binhong; Xiong, Lunqiao; Bai, Fuquan; Tang, Junwang; Jing, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving CO2 photoconversion with ionic liquid and Co single atoms", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic CO2 conversion promises an ideal route to store solar energy into chemical bonds. However, sluggish electron kinetics and unfavorable product selectivity remain unresolved challenges. Here, an ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate, and borate-anchored Co single atoms were separately loaded on ultrathin g-C3N4 nullosheets. The optimized nullocomposite photocatalyst produces CO and CH4 from CO2 and water under UV-vis light irradiation, exhibiting a 42-fold photoactivity enhancement compared with g-C3N4 and nearly 100% selectivity towards CO2 reduction. Experimental and theoretical results reveal that the ionic liquid extracts electrons and facilitates CO2 reduction, whereas Co single atoms trap holes and catalyze water oxidation. More importantly, the maximum electron transfer efficiency for CO2 photoreduction, as measured with in-situ mu s-transient absorption spectroscopy, is found to be 35.3%, owing to the combined effect of the ionic liquid and Co single atoms. This work offers a feasible strategy for efficiently converting CO2 to valuable chemicals. There is growing interest in designing photocatalysts for CO2 conversion. Here, the authors combine an ionic liquid with Co single atoms as dual-cocatalysts for g-C3N4, accelerating electron kinetics and improving CO2 reduction selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1457, "DOI": "10.1038/s41467-023-36980-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36980-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002567600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, BH; Wen, GB; Gao, R; Luo, D; Zhang, Z; Qiu, WB; Ma, QY; Wang, X; Cui, Y; Ricardez-Sandoval, L; Yu, AP; Chen, ZW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Bohua; Wen, Guobin; Gao, Rui; Luo, Dan; Zhang, Zhen; Qiu, Weibin; Ma, Qianyi; Wang, Xin; Cui, Yi; Ricardez-Sandoval, Luis; Yu, Aiping; Chen, Zhongwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 electroreduction reaction offers an attractive approach to global carbon neutrality. Industrial CO2 electrolysis towards formate requires stepped-up current densities, which is limited by the difficulty of precisely reconciling the competing intermediates (COOH* and HCOO*). Herein, nullo-crumples induced Sn-Bi bimetallic interface-rich materials are in situ designed by tailored electrodeposition under CO2 electrolysis conditions, significantly expediting formate production. Compared with Sn-Bi bulk alloy and pure Sn, this Sn-Bi interface pattern delivers optimum upshift of Sn p-band center, accordingly the moderate valence electron depletion, which leads to weakened Sn-C hybridization of competing COOH* and suitable Sn-O hybridization of HCOO*. Superior partial current density up to 140 mA/cm(2) for formate is achieved. High Faradaic efficiency (>90%) is maintained at a wide potential window with a durability of 160 h. In this work, we elevate the interface design of highly active and stable materials for efficient CO2 electroreduction. It is of high interests to design catalysts for CO2 electroreduction with enhanced selectivity and activity. Here, the authors report Sn-Bi bimetallic interface-rich material with enhanced performance for CO2 reduction to formate comparing to that of Sn-Bi bulk alloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2486, "DOI": "10.1038/s41467-022-29861-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29861-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791508600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "von Colbe, JB; Ares, JR; Barale, J; Baricco, M; Buckley, C; Capurso, G; Gallandat, N; Grant, DM; Guzik, MN; Jacob, I; Jensen, EH; Jensen, T; Jepsen, J; Klassen, T; Lototskyy, MV; Manickam, K; Montone, A; Puszkiel, J; Sartori, S; Sheppard, DA; Stuart, A; Walker, G; Webb, CJ; Yang, H; Yartys, V; Züttel, A; Dornheim, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "von Colbe, Jose Bellosta; Ares, Jose-Ramon; Barale, Jussara; Baricco, Marcello; Buckley, Craig; Capurso, Giovanni; Gallandat, Noris; Grant, David M.; Guzik, Matylda N.; Jacob, Isaac; Jensen, Emil H.; Jensen, Torben; Jepsen, Julian; Klassen, Thomas; Lototskyy, Mykhaylol V.; Manickam, Kandavel; Montone, Amelia; Puszkiel, Julian; Sartori, Sabrina; Sheppard, Drew A.; Stuart, Alastair; Walker, Gavin; Webb, Colin J.; Yang, Heena; Yartys, Volodymyr; Zuttel, Andreas; Dornheim, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application of hydrides in hydrogen storage and compression: Achievements, outlook and perspectives", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal hydrides are known as a potential efficient, low-risk option for high-density hydrogen storage since the late 1970s. In this paper, the present status and the future perspectives of the use of metal hydrides for hydrogen storage are discussed. Since the early 1990s, interstitial metal hydrides are known as base materials for Ni - metal hydride rechargeable batteries. For hydrogen storage, metal hydride systems have been developed in the 2010s [1] for use in emergency or backup power units, i.e. for stationary applications. With the development and completion of the first submarines of the U212 A series by HDW (now Thyssen Krupp Marine Systems) in 2003 and its export class U214 in 2004, the use of metal hydrides for hydrogen storage in mobile applications has been established, with new application fields coming into focus. In the last decades, a huge number of new intermetallic and partially covalent hydrogen absorbing compounds has been identified and partly more, partly less extensively characterized. In addition, based on the thermodynamic properties of metal hydrides, this class of materials gives the opportunity to develop a new hydrogen compression technology. They allow the direct conversion from thermal energy into the compression of hydrogen gas without the need of any moving parts. Such compressors have been developed and are nowadays commercially available for pressures up to 200 bar. Metal hydride based compressors for higher pressures are under development. Moreover, storage systems consisting of the combination of metal hydrides and high-pressure vessels have been proposed as a realistic solution for on-board hydrogen storage on fuel cell vehicles. In the frame of the Hydrogen Storage Systems for Mobile and Stationary Applications Group in the International Energy Agency (IEA) Hydrogen Task 32 Hydrogen-based energy storage, different compounds have been and will be scaled-up in the near future and tested in the range of 500 g to several hundred kg for use in hydrogen storage applications. (C) 2019 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 558, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 44, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 7780, "End Page": 7808, "Article Number": null, "DOI": "10.1016/j.ijhydene.2019.01.104", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2019.01.104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463306900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, XX; Chen, DY; Zhao, B; Yang, BR; Jin, ZK; Fan, MJ; Tao, GR; Qin, SC; Yang, WL; He, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Xianxian; Chen, Danyang; Zhao, Bin; Yang, Binru; Jin, Zhaokui; Fan, Mingjian; Tao, Geru; Qin, Shucun; Yang, Wuli; He, Qianjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acid-Degradable Hydrogen-Generating Metal-Organic Framework for Overcoming Cancer Resistance/Metastasis and Off-Target Side Effects", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of stimuli-responsively degradable porous carriers for both controlled drug release and high biosafety is vitally important to their clinical translation, but still challenging at present. A new type of porphyrin-iron metal organic framework (Fe-MOF) nullocrystals is engineered here as acid-degradable drug carrier and hydrogen donor by the coordination between porphyrin and zero-valence Fe atom. Fe-MOF nullocrystals exhibit excellent acid-responsive degradation for H-2 generation and simultaneous release of the loaded drug for combined hydrogen-chemotherapy of cancer multidrug resistance (MDR) and metastasis and for local hydrogen eradication of the off-target induced toxic side effects of the drug to normal cells/tissues. Mechanistically, released H-2 assists chemotherapeutic drug to efficiently inhibit cancer metastasis by immunoactivating intratumoral M1-phenotype macrophages and consequently downregulating the expression of metastasis-related matrix metalloproteinase-2 (MMP-2) and can also downregulate the expressions of both P-glycoprotein (P-gp) protein and adenosine triphosphate (ATP) in MDR cancer cells to sensitize chemotherapeutic drug for enhanced damage to mitochondria and DNA. High anti-MDR/antimetastasis efficacies and high biocompatibility endow Fe-MOF nullocrystals and the Fe-MOF-based nullomedicine with high potential for clinical translation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101965, "DOI": "10.1002/advs.202101965", "DOI Link": "http://dx.doi.org/10.1002/advs.202101965", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748513800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, ZC; Zhang, Y; Zhang, LY; Cheng, B; Wang, LX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Zicong; Zhang, Yong; Zhang, Liuyang; Cheng, Bei; Wang, Linxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of calcination temperatures on photocatalytic H2O2-production activity of ZnO nullorods", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic hydrogen peroxide (H2O2) production from O-2 and H2O is an ideal process for solar-to-chemical energy conversion. Herein, ZnO nullorods are prepared via a simple hydrothermal method for photocatalytic H2O2 production. The ZnO nullorods exhibit varied performance with different calcination temperatures. Benefiting from calcination, the separation efficiency of photo-induced carriers is significantly improved, leading to the superior photocatalytic activity for H2O2 production. The H2O2 produced by ZnO calcined at 300 degrees C is 285 umol L-1, which is over 5 times larger than that produced by untreated ZnO. This work provides an insight into photocatalytic H2O2 production mechanism by ZnO nullorods, and presents a promising strategy to H2O2 production. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 226, "End Page": 233, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63832-9", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63832-9", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Gu, J; Wang, ZJ; Wang, J; He, F; Li, P; Tao, Y; Li, HH; Xie, GZ; Huang, W; Zheng, C; Chen, RF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hui; Gu, Jie; Wang, Zijie; Wang, Juan; He, Fei; Li, Ping; Tao, Ye; Li, Huanhuan; Xie, Gaozhan; Huang, Wei; Zheng, Chao; Chen, Runfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-component color-tunable circularly polarized organic afterglow through chiral clusterization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Circularly polarized organic afterglow (CPOA) with both long-lived room-temperature phosphorescence and circularly polarized luminescence is attracting great interest, but the development of multicolor-tunable CPOA in a single-component material remains challenging. Here, the authors report a strategy to achieve multicolor CPOA through chiral clusterization by inserting a chirality center into a non-conjugated organic cluster. Circularly polarized organic afterglow (CPOA) with both long-lived room-temperature phosphorescence (RTP) and circularly polarized luminescence (CPL) is currently attracting great interest, but the development of multicolor-tunable CPOA in a single-component material remains a formidable challenge. Here, we report an efficient strategy to achieve multicolor CPOA molecules through chiral clusterization by implanting chirality center into non-conjugated organic cluster. Owing to excitation-dependent emission of clusters, highly efficient and significantly tuned CPOA emissions from blue to yellowish-green with dissymmetry factor over 2.3 x 10(-3) and lifetime up to 587 ms are observed under different excitation wavelengths. With the distinguished color-tunable CPOA, the multicolor CPL displays and visual RTP detection of ultraviolent light wavelength are successfully constructed. These results not only provide a new paradigm for realization of multicolor-tunable CPOA materials in single-component molecular systems, but also offer new opportunities for expanding the applicability of CPL and RTP materials for diversified applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 429, "DOI": "10.1038/s41467-022-28070-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28070-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745469500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, YR; Wu, P; Gao, MR; Zhang, XL; Gao, FY; Ju, HX; Wu, R; Gao, Q; You, R; Huang, WX; Liu, SJ; Hu, SW; Zhu, JF; Li, ZY; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Ya-Rong; Wu, Ping; Gao, Min-Rui; Zhang, Xiao-Long; Gao, Fei-Yue; Ju, Huan-Xin; Wu, Rui; Gao, Qiang; You, Rui; Huang, Wei-Xin; Liu, Shou-Jie; Hu, Shan-Wei; Zhu, Junfa; Li, Zhenyu; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping-induced structural phase transition in cobalt diselenide enables enhanced hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dichalcogenide materials have been explored extensively as catalysts to negotiate the hydrogen evolution reaction, but they often run at a large excess thermodynamic cost. Although activating strategies, such as defects and composition engineering, have led to remarkable activity gains, there remains the requirement for better performance that aims for real device applications. We report here a phosphorus-doping-induced phase transition from cubic to orthorhombic phases in CoSe2. It has been found that the achieved orthorhombic CoSe2 with appropriate phosphorus dopant (8 wt%) needs the lowest over-potential of 104 mV at 10 mA cm(-2) in 1M KOH, with onset potential as small as -31 mV. This catalyst demonstrates negligible activity decay after 20 h of operation. The striking catalysis performance can be attributed to the favorable electronic structure and local coordination environment created by this doping-induced structural phase transition strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2533, "DOI": "10.1038/s41467-018-04954-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04954-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436549100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, QW; Paskevicius, M; Sheppard, DA; Buckley, CE; Thornton, AW; Hill, MR; Gu, QF; Mao, JF; Huang, ZG; Liu, HK; Guo, ZP; Banerjee, A; Chakraborty, S; Ahuja, R; Aguey-Zinsou, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Qiwen; Paskevicius, Mark; Sheppard, Drew A.; Buckley, Craig E.; Thornton, Aaron W.; Hill, Matthew R.; Gu, Qinfen; Mao, Jianfeng; Huang, Zhenguo; Liu, Hua Kun; Guo, Zaiping; Banerjee, Amitava; Chakraborty, Sudip; Ahuja, Rajeev; Aguey-Zinsou, Kondo-Francois", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art", "Source Title": "CHEMSUSCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the limitations to the widespread use of hydrogen as an energy carrier is its storage in a safe and compact form. Herein, recent developments in effective high-capacity hydrogen storage materials are reviewed, with a special emphasis on light compounds, including those based on organic porous structures, boron, nitrogen, and aluminum. These elements and their related compounds hold the promise of high, reversible, and practical hydrogen storage capacity for mobile applications, including vehicles and portable power equipment, but also for the large scale and distributed storage of energy for stationary applications. Current understanding of the fundamental principles that govern the interaction of hydrogen with these light compounds is summarized, as well as basic strategies to meet practical targets of hydrogen uptake and release. The limitation of these strategies and current understanding is also discussed and new directions proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 8, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 2789, "End Page": 2825, "Article Number": null, "DOI": "10.1002/cssc.201500231", "DOI Link": "http://dx.doi.org/10.1002/cssc.201500231", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360915800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Wu, H; Cheng, HC; Yang, S; Zhu, EB; He, QY; Ding, MN; Li, DH; Guo, J; Weiss, NO; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuan; Wu, Hao; Cheng, Hung-Chieh; Yang, Sen; Zhu, Enbo; He, Qiyuan; Ding, Mengning; Li, Dehui; Guo, Jian; Weiss, Nathan O.; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward Barrier Free Contact to Molybdenum Disulfide Using Graphene Electrodes", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional layered semiconductors such as molybdenum disulfide (MoS2) have attracted tremendous interest as a new class of electronic materials. However, there are considerable challenges in making reliable contacts to these atomically thin materials. Here we present a new strategy by using graphene as the back electrodes to achieve ohmic contact to MoS2. With a finite density of states, the Fermi level of graphene can be readily tuned by a gate potential to enable a nearly perfect band alignment with MoS2. We demonstrate for the first time a transparent contact to MoS2 with zero contact barrier and linear output behavior at cryogenic temperatures (down to 1.9 K) for both monolayer and multilayer MoS2. Benefiting from the barrier-free transparent contacts, we show that a metalinsulator transition can be observed in a two-terminal MoS2 device, a phenomenon that could be easily masked by Schottky barriers found in conventional metal-contacted MoS2 devices. With further passivation by boron nitride (BN) encapsulation, we demonstrate a record-high extrinsic (two-terminal) field effect mobility up to 1300 cm(2)/(V s) in MoS2 at low temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3030, "End Page": 3034, "Article Number": null, "DOI": "10.1021/nl504957p", "DOI Link": "http://dx.doi.org/10.1021/nl504957p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354906000039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, H; Goddard, WA ; Cheng, T; Liu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Hai; Goddard, William A., III; Cheng, Tao; Liu, Yuanyue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu metal embedded in oxidized matrix catalyst to promote CO2 activation and CO dimerization for electrochemical reduction of CO2", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose and validate with quantum mechanics methods a unique catalyst for electrochemical reduction of CO2 (CO2RR) in which selectivity and activity of CO and C-2 products are both enhanced at the borders of oxidized and metallic surface regions. This Cu metal embedded in oxidized matrix (MEOM) catalyst is consistent with observations that Cu2O-based electrodes improve performance. However, we show that a fully oxidized matrix (FOM) model would not explain the experimentally observed performance boost, and we show that the FOM is not stable under CO2 reduction conditions. This electrostatic tension between the Cu+ and Cu-0 surface sites responsible for the MEOM mechanism suggests a unique strategy for designing more efficient and selective electrocatalysts for CO2RR to valuable chemicals (HCOx), a critical need for practical environmental and energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2017, "Volume": 114, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6685, "End Page": 6688, "Article Number": null, "DOI": "10.1073/pnas.1702405114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1702405114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404108400041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, J; Zhang, X; Liu, C; Lyu, LF; Yang, YF; Wang, Z; Wu, LL; Liu, W; Wang, FL; Liu, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Jing; Zhang, Xue; Liu, Chang; Lyu, Longfei; Yang, Yunfei; Wang, Zhou; Wu, Lili; Liu, Wei; Wang, Fenglong; Liu, Jiurong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modern communication technologies put forward higher requirements for electromagnetic wave (EMW) absorption materials. Metal-organic framework (MOF) derivatives have been widely concerned with its diverse advantages. To break the mindset of magnetic-derivative design, and make up the shortage of monometallic non-magnetic derivatives, we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption. The porous carbon-wrapped TiO2/ZrTiO4 composites derived from PCN-415 (TiZr-MOFs) are qualified with a minimum reflection loss of - 67.8 dB (2.16 mm, 13.0 GHz), and a maximum effective absorption bandwidth of 5.9 GHz (2.70 mm). Through in-depth discussions, the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed. Therefore, this work confirms the huge potentials of non-magnetic bimetallic MOFs derivatives in EMW absorption applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75, "DOI": "10.1007/s40820-021-00606-6", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00606-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620676500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, K; Jo, SB; Shi, XL; Nian, L; Zhang, M; Kan, YY; Lin, F; Kan, B; Xu, B; Rong, QK; Shui, LL; Liu, F; Peng, XB; Zhou, GF; Cao, Y; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Ke; Jo, Sae Byeok; Shi, Xueliang; Nian, Li; Zhang, Ming; Kan, Yuanyuan; Lin, Francis; Kan, Bin; Xu, Bo; Rong, Qikun; Shui, Lingling; Liu, Feng; Peng, Xiaobin; Zhou, Guofu; Cao, Yong; Jen, Alex K. -Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 12% Efficiency Nonfullerene All-Small-Molecule Organic Solar Cells with Sequentially Evolved Multilength Scale Morphologies", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, two near-infrared absorbing molecules are successfully incorporated into nonfullerene-based small-molecule organic solar cells (NFSM-OSCs) to achieve a very high power conversion efficiency (PCE) of 12.08%. This is achieved by tuning the sequentially evolved crystalline morphology through combined solvent additive and solvent vapor annealing, which mainly work on ZnP-TBO and 6TIC, respectively. It not only helps improve the crystallinity of the ZnP-TBO and 6TIC blend, but also forms multilength scale morphology to enhance charge mobility and charge extraction. Moreover, it simultaneously reduces the nongeminate recombination by effective charge delocalization. The resultant device performance shows remarkably enhanced fill factor and J(sc). These result in a very respectable PCE, which is the highest among all NFSM-OSCs and all small-molecule binary solar cells reported so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 31, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1807842, "DOI": "10.1002/adma.201807842", "DOI Link": "http://dx.doi.org/10.1002/adma.201807842", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462619000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cannizzaro, F; Hensen, EJM; Filot, IAW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cannizzaro, Francesco; Hensen, Emiel J. M.; Filot, Ivo A. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Promoting Role of Ni on In2O3 for CO2 Hydrogenation to Methanol", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-promoted indium oxide (In2O3) is a promising catalyst for the selective hydrogenation of CO2 to CH3OH, but the nature of the active Ni sites remains unknown. By employing density functional theory and microkinetic modeling, we elucidate the promoting role of Ni in In2O3-catalyzed CO2 hydrogenation. Three representative models have been investigated: (i) a single Ni atom doped in the In2O3(111) surface, (ii) a Ni atom adsorbed on In2O3(111), and (iii) a small cluster of eight Ni atoms adsorbed on In2O3(111). Genetic algorithms (GAs) are used to identify the optimum structure of the Ni8 clusters on the In2O3 surface. Compared to the pristine In2O3(111) surface, the Ni8-cluster model offers a lower overall barrier to oxygen vacancy formation, whereas, on both single-atom models, higher overall barriers are found. Microkinetic simulations reveal that only the supported Ni8 cluster can lead to high methanol selectivity, whereas single Ni atoms either doped in or adsorbed on the In2O3 surface mainly catalyze CO formation. Hydride species obtained by facile H2 dissociation on the Ni8 cluster are involved in the hydrogenation of adsorbed CO2 to formate intermediates and methanol. At higher temperatures, the decreasing hydride coverage shifts the selectivity to CO. On the Ni8-cluster model, the formation of methane is inhibited by high barriers associated with either direct or H-assisted CO activation. A comparison with a smaller Ni6 cluster also obtained with GAs exhibits similar barriers for key rate-limiting steps for the formation of CO, CH4, and CH3OH. Further microkinetic simulations show that this model also has appreciable selectivity to methanol at low temperatures. The formation of CO over single Ni atoms either doped in or adsorbed on the In2O3 surface takes place via a redox pathway involving the formation of oxygen vacancies and direct CO2 dissociation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 18", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1875, "End Page": 1892, "Article Number": null, "DOI": "10.1021/acscatal.2c04872", "DOI Link": "http://dx.doi.org/10.1021/acscatal.2c04872", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922755700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Xue, JJ; Meng, L; Lee, JW; Zhao, ZP; Sun, PY; Cai, L; Huang, TY; Wang, ZX; Wang, ZK; Duan, Y; Yang, JL; Tan, S; Yuan, Y; Huang, Y; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Xue, Jingjing; Meng, Lei; Lee, Jin-Wook; Zhao, Zipeng; Sun, Pengyu; Cai, Le; Huang, Tianyi; Wang, Zhengxu; Wang, Zhao-Kui; Duan, Yu; Yang, Jonathan Lee; Tan, Shaun; Yuan, Yonghai; Huang, Yu; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Caffeine Improves the Performance and Thermal Stability of Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To increase the commercial prospects of metal halide perovskite solar cells, there is a need for simple, cost-effective, and generalized approaches that mitigate their intrinsic thermal instability. Here we show that 1,3,7-trimethylxanthine, a commodity chemical with two conjugated carboxyl groups better known by its common name caffeine, improves the performance and thermal stability of perovskite solar cells based on both MAPbI(3) and CsFAMAPbI(3) active layers. The strong interaction between caffeine and Pb2+ ions serves as a molecular lock'' that increases the activation energy during film crystallization, delivering a perovskite film with preferred orientation, improved electronic properties, reduced ion migration, and greatly enhanced thermal stability. Planar n-i-p solar cells based on caffeine-incorporated pure MAPbI(3) perovskites, which are notoriously unstable, exhibit a champion-stabilized efficiency of 19.8% and retain over 85% of their efficiency under continuous annealing at 85 degrees C in nitrogen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 512, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1464, "End Page": 1477, "Article Number": null, "DOI": "10.1016/j.joule.2019.04.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.04.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472067900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parlak, O; Keene, ST; Marais, A; Curto, VF; Salleo, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parlak, Onur; Keene, Scott Tom; Marais, Andrew; Curto, Vincenzo F.; Salleo, Alberto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecularly selective nulloporous membrane-based wearable organic electrochemical device for noninvasive cortisol sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable biosensors have emerged as an alternative evolutionary development in the field of healthcare technology due to their potential to change conventional medical diagnostics and health monitoring. However, a number of critical technological challenges including selectivity, stability of (bio)recognition, efficient sample handling, invasiveness, and mechanical compliance to increase user comfort must still be overcome to successfully bring devices closer to commercial applications. We introduce the integration of an electrochemical transistor and a tailor-made synthetic and biomimetic polymeric membrane, which acts as a molecular memory layer facilitating the stable and selective molecular recognition of the human stress hormone cortisol. The sensor and a laser-patterned micro capillary channel array are integrated in a wearable sweat diagnostics platform, providing accurate sweat acquisition and precise sample delivery to the sensor interface. The integrated devices were successfully used with both ex situ methods using skin-like microfluidics and on human subjects with on-body real-sample analysis using a wearable sensor assembly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar2904", "DOI": "10.1126/sciadv.aar2904", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar2904", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deysher, G; Shuck, CE; Hantanasirisakul, K; Frey, NC; Foucher, AC; Maleski, K; Sarycheva, A; Shenoy, VB; Stach, EA; Anasori, B; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit; Frey, Nathan C.; Foucher, Alexandre C.; Maleski, Kathleen; Sarycheva, Asia; Shenoy, Vivek B.; Stach, Eric A.; Anasori, Babak; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Mo4VAlC4 MAX Phase and Two-Dimensional Mo4VC4 MXene with Five Atomic Layers of Transition Metals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a family of two-dimensional (2D) transition metal carbides, nitrides, and carbonitrides with a general formula of Mn+1XnTx, in which two, three, or four atomic layers of a transition metal (M: Ti, Nb, V, Cr, Mo, Ta, etc.) are interleaved with layers of C and/or N (shown as X), and T-x represents surface termination groups such as -OH, =O, and -F. Here, we report the scalable synthesis and characterization of a MXene with five atomic layers of transition metals (Mo4VC4Tx), by synthesizing its Mo4VAlC4 MAX phase precursor that contains no other MAX phase impurities. These phases display twinning at their central M layers which is not present in any other known MAX phases or MXenes. Transmission electron microscopy and X-ray diffraction were used to examine the structure of both phases. Energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and high- resolution scanning transmission electron microscopy with energy-dispersive X-ray spectroscopy were used to study the composition of these materials. Density functional theory calculations indicate that other five transition metal-layer MAX phases (M'M-4 '' AlC4) may be possible, where M' and M '' are two different transition metals. The predicted existence of additional Al-containing MAX phases suggests that more M5C4Tx MXenes can be synthesized. Additionally, we characterized the optical, electronic, and thermal properties of Mo4VC4Tx. This study demonstrates the existence of an additional subfamily of M5X4Tx MXenes as well as a twinned structure, allowing for a wider range of 2D structures and compositions for more control over properties, which could lead to many different applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 506, "Times Cited, All Databases": 532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 217, "Article Number": null, "DOI": "10.1021/acsnullo.9b07708", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b07708", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510531500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, ND; Lin, HW; Song, H; Yang, LX; Tang, DM; Deng, F; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Ningdong; Lin, Huiwen; Song, Hui; Yang, Longxiao; Tang, Daiming; Deng, Feng; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and selective photocatalytic CH4 conversion to CH3OH with O2 by controlling overoxidation on TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of photocatalytic methane into methanol in high yield with selectivity remains a huge challenge due to unavoidable overoxidation. Here, the photocatalytic oxidation of CH4 into CH3OH by O-2 is carried out on Ag-decorated facet-dominated TiO2. The {001}-dominated TiO2 shows a durable CH3OH yield of 4.8mmolg(-1)h(-1) and a selectivity of approximately 80%, which represent much higher values than those reported in recent studies and are better than those obtained for {101}-dominated TiO2. Operando Fourier transform infrared spectroscopy, electron spin resonullce, and nuclear magnetic resonullce techniques are used to comprehensively clarify the underlying mechanism. The straightforward generation of oxygen vacancies on {001} by photoinduced holes plays a key role in avoiding the formation of center dot CH3 and center dot OH, which are the main factors leading to overoxidation and are generally formed on the {101} facet. The generation of oxygen vacancies on {001} results in distinct intermediates and reaction pathways (oxygen vacancy -> Ti-O-2(center dot)-> Ti-OO-Ti and Ti-(OO)-> Ti-O-center dot pairs), thus achieving high selectivity and yield for CH4 photooxidation into CH3OH. The photocatalytic conversion of CH4 into CH3OH with high activity and selectivity must avoid product overoxidation. Here, authors minimize overoxidation by using a (001)-dominated TiO2 nullosheet to circumvent CH4 overoxidation intermediates plus reaction pathways that occur on (101) facets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4652, "DOI": "10.1038/s41467-021-24912-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24912-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683428500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoffman, JB; Schleper, AL; Kamat, PV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hoffman, Jacob B.; Schleper, A. Lennart; Kamat, Prashant V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transformation of Sintered CsPbBr3 nullocrystals to Cubic CsPbI3 and Gradient CsPbBrxI3-x through Halide Exchange", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic cesium lead halide (CsPbX3, X = Br-,I-) perovskites could potentially provide comparable photovoltaic performance with enhanced stability compared to organic inorganic lead halide species. However, small-bandgap cubic CsPbI3 has been difficult to study due to challenges forming CsPbI3 in the cubic phase. Here, a low-temperature procedure to form cubic CsPbI3 has been developed through a halide exchange reaction using films of sintered CsPbBr3 nullocrystals. The reaction was found to be strongly dependent upon temperature, featuring an Arrhenius relationship. Additionally, film thickness played a significant role in determining internal film structure at intermediate reaction times. Thin films (50 nm) showed only a small distribution of CsPbBrxI3-x species, while thicker films (350 nm) exhibited much broader distributions. Furthermore, internal film structure was ordered, featuring a compositional gradient within film. Transient absorption spectroscopy showed the influence of halide exchange on the excited state of the material. In thicker films, charge carriers were rapidly transferred to iodide-rich regions near the film surface within the first several picoseconds after excitation. This ultrafast vectorial charge-transfer process illustrates the potential of utilizing compositional gradients to direct charge flow in perovskite-based photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2016, "Volume": 138, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8603, "End Page": 8611, "Article Number": null, "DOI": "10.1021/jacs.6b04661", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b04661", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379794400046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, XH; Yang, YP; Wang, L; Fu, XZ; Luo, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Xiaohui; Yang, Yongpeng; Wang, Lei; Fu, Xian-Zhu; Luo, Jing-Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic Co nulloarray Catalyzes Selective NH3 Production from Electrochemical Nitrate Reduction at Current Densities Exceeding 2 A cm-2", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical nitrate reduction (NITRR) offers a promising alternative toward nitrogen recycling and ammonia production under ambient conditions, for which highly active and selective electrocatalyst is desired. In this study, metallic cobalt nulloarrays as facilely prepared from the electrochemical reduction of Co(OH)(2) nulloarrays (NAs) are demonstrated to exhibit unprecedented NH3 producing capability from catalyzing NITRR. Benefitting from the high intrinsic activity of Co-0, intimate contact between active species and conductive substrate and the nullostructure which exposes large number of active sites, the Co-NAs electrode exhibits current density of -2.2 A cm(-2) and NH3 production rate of 10.4 mmol h(-1) cm(-2) at -0.24 V versus RHE under alkaline condition and significantly surpasses reported counterparts. Moreover, the close-to-unity (>= 96%) Faradaic efficiency (FE) toward NH3 is achieved over wide application range (potential, NO3- concentration and pH). Density function theory calculation reveals the optimized adsorption energy of NITRR intermediates on Co surface over Co(OH)(2). Furthermore, it is proposed that despite the sluggish kinetics of Volmer step (H2O -> *H + *OH) which provides protons in conventional hydrogenation mechanism, the proton-supplying water dissociation process on Co surface is drastically facilitated following a concerted water dissociation-hydrogenation pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004523, "DOI": "10.1002/advs.202004523", "DOI Link": "http://dx.doi.org/10.1002/advs.202004523", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613231000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JJ; Yang, JL; Tang, YJ; Liu, J; Zhang, Y; Liang, GX; Gauthier, M; Chen-Wiegart, YCK; Banis, MN; Li, XF; Li, RY; Wang, J; Sham, TK; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiajun; Yang, Jinli; Tang, Yongji; Liu, Jian; Zhang, Yong; Liang, Guoxian; Gauthier, Michel; Chen-Wiegart, Yu-chen Karen; Banis, Mohammad Norouzi; Li, Xifei; Li, Ruying; Wang, Jun; Sham, T. K.; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size-dependent surface phase change of lithium iron phosphate during carbon coating", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon coating is a simple, effective and common technique for improving the conductivity of active materials in lithium ion batteries. However, carbon coating provides a strong reducing atmosphere and many factors remain unclear concerning the interface nature and underlying interaction mechanism that occurs between carbon and the active materials. Here, we present a size-dependent surface phase change occurring in lithium iron phosphate during the carbon coating process. Intriguingly, nulloscale particles exhibit an extremely high stability during the carbon coating process, whereas microscale particles display a direct visualization of surface phase changes occurring at the interface at elevated temperatures. Our findings provide a comprehensive understanding of the effect of particle size during carbon coating and the interface interaction that occurs on carbon-coated battery material-allowing for further improvement in materials synthesis and manufacturing processes for advanced battery materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 554, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3415, "DOI": "10.1038/ncomms4415", "DOI Link": "http://dx.doi.org/10.1038/ncomms4415", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334300000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SJ; Wahiduzzaman, M; Davis, L; Tissot, A; Shepard, W; Marrot, J; Martineau-Corcos, C; Hamdane, D; Maurin, G; Devautour-Vinot, S; Serre, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sujing; Wahiduzzaman, Mohammad; Davis, Louisa; Tissot, Antoine; Shepard, William; Marrot, Jerome; Martineau-Corcos, Charlotte; Hamdane, Djemel; Maurin, Guillaume; Devautour-Vinot, Sabine; Serre, Christian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust zirconium amino acid metal-organic framework for proton conduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton conductive materials are of significant importance and highly desired for clean energyrelated applications. Discovery of practical metal-organic frameworks (MOFs) with high proton conduction remains a challenge due to the use of toxic chemicals, inconvenient ligand preparation and complication of production at scale for the state-of-the-art candidates. Herein, we report a zirconium-MOF, MIP-202(Zr), constructed from natural alpha-amino acid showing a high and steady proton conductivity of 0.011 S cm(-1) at 363 K and under 95% relative humidity. This MOF features a cost-effective, green and scalable preparation with a very high space-time yield above 7000 kgm(-3) day(-1). It exhibits a good chemical stability under various conditions, including solutions of wide pH range and boiling water. Finally, a comprehensive molecular simulation was carried out to shed light on the proton conduction mechanism. All together these features make MIP-202(Zr) one of the most promising candidates to approach the commercial benchmark Nafion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4937, "DOI": "10.1038/s41467-018-07414-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07414-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450923800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Higo, T; Man, HY; Gopman, DB; Wu, L; Koretsune, T; van't Erve, OMJ; Kabanov, YP; Rees, D; Li, YF; Suzuki, MT; Patankar, S; Ikhlas, M; Chien, CL; Arita, R; Shull, RD; Orenstein, J; Nakatsuji, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Higo, Tomoya; Man, Huiyuan; Gopman, Daniel B.; Wu, Liang; Koretsune, Takashi; van't Erve, Olaf M. J.; Kabanov, Yury P.; Rees, Dylan; Li, Yufan; Suzuki, Michi-To; Patankar, Shreyas; Ikhlas, Muhammad; Chien, C. L.; Arita, Ryotaro; Shull, Robert D.; Orenstein, Joseph; Nakatsuji, Satoru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large magneto-optical Kerr effect and imaging of magnetic octupole domains in an antiferromagnetic metal", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The magneto-optical Kerr effect (MOKE) has been intensively studied in a variety of ferro-and ferrimagnetic materials as a powerful probe for electronic and magnetic properties(1-3) and for magneto-optical technologies(4). The MOKE can be additionally useful for the investigation of the antiferromagnetic (AF) state, although thus far limited to insulators(5-9). Here, we report the first observation of the MOKE in an AF metal. In particular, we find that the non-collinear AF metal Mn3Sn (ref. 10) exhibits a large zero-field Kerr rotation angle of 20 mdeg at room temperature, comparable to ferromagnetic metals. Our first-principles calculations clarify that ferroic ordering of magnetic octupoles(11) produces a large MOKE even in its fully compensated AF state. This large MOKE further allows imaging of the magnetic octupole domains and their reversal. The observation of a large MOKE in an AF metal will open new avenues for the study of domain dynamics as well as spintronics using antiferromagnets(12-16)", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 73, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-017-0086-z", "DOI Link": "http://dx.doi.org/10.1038/s41566-017-0086-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423445500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Veiseh, O; Doloff, JC; Ma, ML; Vegas, AJ; Tam, HH; Bader, AR; Li, J; Langan, E; Wyckoff, J; Loo, WS; Jhunjhunwala, S; Chiu, A; Siebert, S; Tang, K; Hollister-Lock, J; Aresta-Dasilva, S; Bochenek, M; Mendoza-Elias, J; Wang, Y; Qi, M; Lavin, DM; Chen, M; Dholakia, N; Thakrar, R; Lacík, I; Weir, GC; Oberholzer, J; Greiner, DL; Langer, R; Anderson, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Veiseh, Omid; Doloff, Joshua C.; Ma, Minglin; Vegas, Arturo J.; Tam, Hok Hei; Bader, Andrew R.; Li, Jie; Langan, Erin; Wyckoff, Jeffrey; Loo, Whitney S.; Jhunjhunwala, Siddharth; Chiu, Alan; Siebert, Sean; Tang, Katherine; Hollister-Lock, Jennifer; Aresta-Dasilva, Stephanie; Bochenek, Matthew; Mendoza-Elias, Joshua; Wang, Yong; Qi, Merigeng; Lavin, Danya M.; Chen, Michael; Dholakia, Nimit; Thakrar, Raj; Lacik, Igor; Weir, Gordon C.; Oberholzer, Jose; Greiner, Dale L.; Langer, Robert; Anderson, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size- and shape-dependent foreign body immune response to materials implanted in rodents and non-human primates", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficacy of implanted biomedical devices is often compromised by host recognition and subsequent foreign body responses. Here, we demonstrate the role of the geometry of implanted materials on their biocompatibility in vivo. In rodent and non-human primate animal models, implanted spheres 1.5 mm and above in diameter across a broad spectrum of materials, including hydrogels, ceramics, metals and plastics, significantly abrogated foreign body reactions and fibrosis when compared with smaller spheres. We also show that for encapsulated rat pancreatic islet cells transplanted into streptozotocin-treated diabetic C57BL/6 mice, islets prepared in 1.5-mm alginate capsules were able to restore blood-glucose control for up to 180 days, a period more than five times longer than for transplanted grafts encapsulated within conventionally sized 0.5-mm alginate capsules. Our findings suggest that the in vivo biocompatibility of biomedical devices can be significantly improved simply by tuning their spherical dimensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 671, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 643, "End Page": "U125", "Article Number": null, "DOI": "10.1038/NMAT4290", "DOI Link": "http://dx.doi.org/10.1038/NMAT4290", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354801500029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, M; Tan, SJ; Wang, JW; Wu, Y; Liang, LL; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Ming; Tan, Shujuan; Wang, Jingwen; Wu, Yue; Liang, Leilei; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-in-One Multi-Scale Structural Design of Carbon Fiber-Based Composites for Personal Electromagnetic Protection and Thermal Management", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable devices with efficient thermal management and electromagnetic interference (EMI) shielding are highly desirable for improving human comfort and safety. Herein, a multifunctional wearable carbon fibers (CF) @ polyaniline (PANI) / silver nullowires (Ag NWs) composites with a branch-trunk interlocked micro/nullostructure were achieved through three-in-one multi-scale design. The reasonable assembly of the three kinds of one-dimensional (1D) materials can fully exert their excellent properties i.e., the superior flexibility of CF, the robustness of PANI, and the splendid conductivity of AgNWs. Consequently, the constructed flexible composite demonstrates enhanced mechanical properties with a tensile stress of 1.2 MPa, which was almost 6 times that of the original material. This is mainly attributed to the fact that the PNAI (branch) was firmly attached to the CF (trunk) through polydopamine (PDA), forming a robust interlocked structure. Meanwhile, the composite possesses excellent thermal insulation and heat preservation capacity owing to the synergistically low thermal conductivity and emissivity. More importantly, the conductive path of the composite established by the three 1D materials greatly improved its EMI shielding property and Joule heating performance at low applied voltage. This work paves the way for rational utilization of the intrinsic properties of 1D materials, as well as provides a promising strategy for designing wearable electromagnetic protection and thermal energy management devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 176, "DOI": "10.1007/s40820-023-01144-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01144-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026883900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, W; Zhang, JC; Luo, JW; Zeng, CH; Su, H; Zhang, JF; Liu, R; Hu, EY; Liu, YS; Liu, WD; Chen, YA; Hu, WB; Xu, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Wei; Zhang, Jingchao; Luo, Jiawei; Zeng, Cuihua; Su, Hai; Zhang, Jinfeng; Liu, Rui; Hu, Enyuan; Liu, Yuansheng; Liu, Wei-Di; Chen, Yanull; Hu, Wenbin; Xu, Yunhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast Non-Equilibrium Synthesis of Cathode Materials for Li-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of cathode materials plays an important role in determining the production efficiency, cost, and performance of lithium-ion batteries. However, conventional synthesis methods always experience a slow heating rate and involve a complicated multistep reaction process and sluggish reaction dynamics, leading to high energy and long time consumption. Herein, a high-temperature shock (HTS) strategy is reported for the ultrafast synthesis of cathode materials in seconds. The HTS process experiences an ultrahigh heating rate, leading to a non-equilibrium reaction and fast reaction kinetics, and avoids high energy and long time consumption. Mainstream cathode materials (such as LiMn2O4, LiCoO2, LiFePO4, and Li-rich layered oxide/NiO heterostructured material) are successfully synthesized with pure phases, oxygen vacancies, ultrasmall particle sizes, and good electrochemical performance. The HTS process not only provides an efficient synthesis approach for cathode materials, but also can be extended beyond lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 35, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2208974, "DOI": "10.1002/adma.202208974", "DOI Link": "http://dx.doi.org/10.1002/adma.202208974", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928272500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, XH; Li, WP; Chang, HT; Yang, T; Duan, GS; Wu, BL; Huang, JC; Chen, FR; Liu, CT; Chuang, WS; Lu, Y; Sui, ML; Huang, EW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, X. H.; Li, W. P.; Chang, H. T.; Yang, T.; Duan, G. S.; Wu, B. L.; Huang, J. C.; Chen, F. R.; Liu, C. T.; Chuang, W. S.; Lu, Y.; Sui, M. L.; Huang, E. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual heterogeneous structures lead to ultrahigh strength and uniform ductility in a Co-Cr-Ni medium-entropy alloy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alloys with ultra-high strength and sufficient ductility are highly desired for modern engineering applications but difficult to develop. Here we report that, by a careful controlling alloy composition, thermomechanical process, and microstructural feature, a Co-Cr-Ni-based medium-entropy alloy (MEA) with a dual heterogeneous structure of both matrix and precipitates can be designed to provide an ultra-high tensile strength of 2.2GPa and uniform elongation of 13% at ambient temperature, properties that are much improved over their counterparts without the heterogeneous structure. Electron microscopy characterizations reveal that the dual heterogeneous structures are composed of a heterogeneous matrix with both coarse grains (10 similar to 30 mu m) and ultra-fine grains (0.5 similar to 2 mu m), together with heterogeneous L1(2)-structured nulloprecipitates ranging from several to hundreds of nullometers. The heterogeneous L1(2) nulloprecipitates are fully coherent with the matrix, minimizing the elastic misfit strain of interfaces, relieving the stress concentration during deformation, and playing an active role in enhanced ductility. Improving both strength and ductility simultaneously in structural metals and alloys remains a challenge. Here, the authors design a heterogeneous structure in a Co-Cr-Ni alloy that results in ultrahigh strength and significant uniform elongation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2390, "DOI": "10.1038/s41467-020-16085-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16085-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536301900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, L; Yang, YP; Wang, HL; Zheng, YL; Hao, HC; Song, WP; Shi, J; Huang, MH; Mitlin, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Lin; Yang, Yunpeng; Wang, Huanlei; Zheng, Yulong; Hao, Hongchang; Song, Wenping; Shi, Jing; Huang, Minghua; Mitlin, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-nitrogen rich carbon as stable high capacity potassium ion battery anode: Performance and storage mechanisms", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combined sulfur and nitrogen (S = 12.9 at.%, N = 9.9 at.%) rich carbons are synthesized for potassium ion anode applications. The low-surface-area carbons (56 m(2) g(-1)) have sulfur covalently bonded to the structure, with minimum unbound free sulfur. This allows for exceptional rate capability and stability: Capacities of 437, 234 and 72 mAh g(-1) are achieved at 0.1, 1 and 10 A g(-1), with 75% retention at 2 A g(-1) after 3000 cycles. These are among the most favorable capacity-cyclability combinations reported in potassium ion battery carbon literature. As a proof of principle, the carbons are incorporated into a potassium ion capacitor with state-of-the-art energy and power (e.g. 110 W h kg(-1) at 244 W kg(-1)). According to XPS analysis, the reaction of nitrogen with Kthorn is distinct from that of Kthorn with sulfur. The N and N-O moieties undergo a series of complex multi-voltage reactions that result in both reversible and irreversible changes to their structure. The K-S reactions involve a combination of reversible adsorption and reversible formation of sulfides, thiosulfate and sulfate. GITT and EIS analysis indicate that incorporation of S into the N-rich carbon increases the Kthorn solid-state diffusion coefficient by factors ranging from -3 to 8, depending on the voltage. The diffusivities are asymmetric with charging vs. discharging, signifying distinct reaction pathways. The covalently bound sulfur also has a positive influence on the solid electrolyte interphase (SEI) formation, at early and at prolonged cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 27, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 225, "Article Number": null, "DOI": "10.1016/j.ensm.2020.02.004", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2020.02.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521992800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XP; Deng, YH; Chen, B; Wei, HT; Xiao, X; Fang, YJ; Lin, YZ; Yu, ZH; Liu, Y; Wang, Q; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaopeng; Deng, Yehao; Chen, Bo; Wei, Haotong; Xiao, Xun; Fang, Yanjun; Lin, Yuze; Yu, Zhenhua; Liu, Ye; Wang, Qi; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual Functions of Crystallization Control and Defect Passivation Enabled by Sulfonic Zwitterions for Stable and Efficient Perovskite Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uniform and high-electronic-quality perovskite thin films are essential for high-performance perovskite devices. Here, it is shown that the 3-(decyldimethylammonio)-propane-sulfonate inner salt (DPSI), which is a sulfonic zwitterion, plays dual roles in tuning the crystallization behavior and passivating the defects of perovskites. The synergistic effect of crystallization control and defect passivation remarkably suppresses pinhole formation, reduces the charge trap density, and lengthens the carrier recombination lifetime, and thereafter boosts the small-area (0.08 cm(2)) planar perovskite device efficiency to 21.1% and enables a high efficiency of 18.3% for blade-coating large-area (1 cm(2)) devices. The device also shows good light stability, which remains at 88% of the initial efficiency under continuous unfiltered AM 1.5G light illumination for 480 h. These findings provide an avenue for simultaneous crystallization control and defect passivation to further improve the performance of perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2018, "Volume": 30, "Issue": 52, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803428, "DOI": "10.1002/adma.201803428", "DOI Link": "http://dx.doi.org/10.1002/adma.201803428", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454124800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoo, HD; Liang, YL; Dong, H; Lin, JH; Wang, H; Liu, YS; Ma, L; Wu, TP; Li, YF; Ru, Q; Jing, Y; An, QY; Zhou, W; Guo, JH; Lu, J; Pantelides, ST; Qian, XF; Yao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoo, Hyun Deog; Liang, Yanliang; Dong, Hui; Lin, Junhao; Wang, Hua; Liu, Yisheng; Ma, Lu; Wu, Tianpin; Li, Yifei; Ru, Qiang; Jing, Yan; An, Qinyou; Zhou, Wu; Guo, Jinghua; Lu, Jun; Pantelides, Sokrates T.; Qian, Xiaofeng; Yao, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium rechargeable batteries potentially offer high-energy density, safety, and low cost due to the ability to employ divalent, dendrite-free, and earth-abundant magnesium metal anode. Despite recent progress, further development remains stagnated mainly due to the sluggish scission of magnesium-chloride bond and slow diffusion of divalent magnesium cations in cathodes. Here we report a battery chemistry that utilizes magnesium monochloride cations in expanded titanium disulfide. Combined theoretical modeling, spectroscopic analysis, and electrochemical study reveal fast diffusion kinetics of magnesium monochloride cations without scission of magnesium-chloride bond. The battery demonstrates the reversible intercalation of 1 and 1.7 magnesium monochloride cations per titanium at 25 and 60 degrees C, respectively, corresponding to up to 400 mAh g(-1) capacity based on the mass of titanium disulfide. The large capacity accompanies with excellent rate and cycling performances even at room temperature, opening up possibilities for a variety of effective intercalation hosts for multivalent-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 339, "DOI": "10.1038/s41467-017-00431-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00431-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408375700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, TZ; Zhu, ZX; He, YX; Balogun, MS; Huang, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Tuzhi; Zhu, Zhixiao; He, Yanxiang; Balogun, M. -Sadeeq; Huang, Yongchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Evolution on the Hydrogen Adsorption Kinetics of NiFe-Based Heterogeneous Catalysts for Efficient Water Electrolysis", "Source Title": "SMALL METHODS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal layered double hydroxides, especially nickel-iron layered double hydroxide (NiFe-LDH) shows significant advancement as efficient oxygen evolution reaction (OER) electrocatalyst but also plays a momentous role as a precursor for NiFe-based hydrogen evolution reaction (HER) catalysts. Herein, a simple strategy for developing Ni-Fe-derivative electrocatalysts via phase evolution of NiFe-LDH under controllable annealing temperatures in an argon atmosphere is reported. The optimized catalyst annealed at 340 C-o (denoted NiO/FeNi3) exhibits superior HER properties with an ultralow overpotential of 16 mV@10 mA cm(-2). Density functional theory simulation and in situ Raman analyses reveal that the excellent HER properties of the NiO/FeNi3 can be attributed to the strong electronic interaction at the interface of the metallic FeNi3 and semiconducting NiO, which optimizes the H2O and H adsorption energies for efficient HER and OER catalytic processes. This work will provide rational insights into the subsequent development of related HER electrocatalysts and other corresponding compounds via LDH-based precursors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/smtd.202201472", "DOI Link": "http://dx.doi.org/10.1002/smtd.202201472", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935081300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, M; Zhou, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Mei; Zhou, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Breakthroughs in Supercapacitors Boosted by Nitrogen-Rich Porous Carbon Materials", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Featured with unique mechanical, electronic and chemical properties, nitrogen-doped carbon materials have become the research hotspot of energy storage. As electrode materials in supercapacitors (SCs), N-doped carbons have demonstrated intriguing flexibility and superb performances in a wide electrochemical window, equipped with versatile properties as both cathodes and anodes for constructing high voltage devices. Compared with limited doping level, N-rich and porous carbon materials (NPCs) are of great desire to release the restricted properties of N species and obtain high specific capacitances (>600 F g(-1)), pushing the energy density towards the battery level without scarifying the capacitor-level power ability. In this Research News we firstly discuss the key factors influencing the performance of NPC electrodes to disclose related charge storage mechanisms. In addition, the trade-off among N-content, porous structure and electrical conductivity is involved as well as electrochemical behaviors in different electrolytes. Also, various progressive developments are highlighted systematically ranging from asymmetric to symmetric and hybrid configurations, covering both aqueous and non-aqueous systems. Finally, some stubborn and unsolved problems are summarized, with prospective research guidelines on NPC-based SCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600408, "DOI": "10.1002/advs.201600408", "DOI Link": "http://dx.doi.org/10.1002/advs.201600408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408105000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, EA; Banerjee, S; Tang, HM; Richardson, PM; Doux, JM; Qi, J; Zhu, ZY; Grenier, A; Li, YX; Zhao, EY; Deysher, G; Sebti, E; Nguyen, H; Stephens, R; Verbist, G; Chapman, KW; Clément, RJ; Banerjee, A; Meng, YS; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Erik A.; Banerjee, Swastika; Tang, Hanmei; Richardson, Peter M.; Doux, Jean-Marie; Qi, Ji; Zhu, Zhuoying; Grenier, Antonin; Li, Yixuan; Zhao, Enyue; Deysher, Grayson; Sebti, Elias; Nguyen, Han; Stephens, Ryan; Verbist, Guy; Chapman, Karena W.; Clement, Raphaele J.; Banerjee, Abhik; Meng, Ying Shirley; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report the discovery of the ion conductor Na3-xY1-xZrxCl6 (NYZC) that is both electrochemically stable (up to 3.8V vs. Na/Na+) and chemically compatible with oxide cathodes. Its high ionic conductivity of 6.6 x 10(-5)Scm(-1) at ambient temperature, several orders of magnitude higher than oxide coatings, is attributed to abundant Na vacancies and cooperative MCl6 rotation, resulting in an extremely low interfacial impedance. A SSSB comprising a NaCrO2+NYZC composite cathode, Na3PS4 electrolyte, and Na-Sn anode exhibits an exceptional first-cycle Coulombic efficiency of 97.1% at room temperature and can cycle over 1000 cycles with 89.3% capacity retention at 40 degrees C. These findings highlight the immense potential of halides for SSSB applications. Rechargeable solid-state sodium-ion batteries hold great promise for safer and more energy-dense energy storage. Here, the authors show a new sodium-based halide, Na3-xY1-xZrxCl6, for sodium-all-solid-state batteries with enhanced ionic conductivity and long-term cycling stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1256, "DOI": "10.1038/s41467-021-21488-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21488-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623781900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, XQ; Gu, XY; Dai, SP; Chen, JB; Cui, YJ; Chen, Q; Yu, M; Chen, CY; Liu, SL; Mu, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Xueqin; Gu, Xiangyao; Dai, Shipeng; Chen, Jiabing; Cui, Yujia; Chen, Qu; Yu, Min; Chen, Changyun; Liu, Suli; Mu, Shichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking the symmetry of single-atom catalysts enables an extremely low energy barrier and high stability for large-current-density water splitting", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The instability and low large-current-density efficiency for a single atomic metal species system have aroused widespread concern. Herein, the Ru single-atom system constructed on an iron-cobalt layered double hydroxide (Ru(x)SACs@FeCo-LDH) exhibits extremely low oxygen evolution reaction (OER) overpotentials of 194 and 246 mV at current densities of 10 and 1000 mA cm(-2), respectively, and a high stability greater than 1000 h at 1000 mA cm(-2), all of which far surpass the values obtained for commercial RuO2. Moreover, its mass activity is similar to 2 and 6 times higher than those of Ru and FeCo-LDH, respectively. Extraordinarily, it only needs 1.52 V to achieve a 1000 mA cm(-2) current density for water splitting, and it is almost unchanged after 1000 h, as the highest performance reported so far. Experimental and theoretical calculation results show that, after an activation process, an in situ Ru-O-TM (Fe, Co, and Ni)-like nullocompound is formed on the atom-scale symmetry breaking interfaces of the FeCo-LDH surface, promoting O-O coupling at the Ru-O active sites for OER and beneficial for suppressing multiple heteroatomic interface instability for large-current-density water splitting. Our strategy opens up opportunities for boosting the single-atom stability in industrial-scale hydrogen production from water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2022, "Volume": 15, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4048, "End Page": 4057, "Article Number": null, "DOI": "10.1039/d2ee01337a", "DOI Link": "http://dx.doi.org/10.1039/d2ee01337a", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000847701900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, B; Liu, JZ; Huang, X; Qiu, XY; Yang, X; Shao, H; Tang, CY; Zhang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Bo; Liu, Jize; Huang, Xin; Qiu, Xiaoyan; Yang, Xin; Shao, Hong; Tang, Changyu; Zhang, Xinxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanoluminescent-Triboelectric Bimodal Sensors for Self-Powered Sensing and Intelligent Control", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-powered flexible devices with skin-like multiple sensing ability have attracted great attentions due to their broad applications in the Internet of Things (IoT). Various methods have been proposed to enhance mechano-optic or electric performance of the flexible devices; however, it remains challenging to realize the display and accurate recognition of motion trajectories for intelligent control. Here, we present a fully self-powered mechanoluminescent-triboelectric bimodal sensor based on micro-nullostructured mechanoluminescent elastomer, which can patterned-display the force trajectories. The deformable liquid metals used as stretchable electrode make the stress transfer stable through overall device to achieve outstanding mechanoluminescence (with a gray value of 107 under a stimulus force as low as 0.3 N and more than 2000 cycles reproducibility). Moreover, a microstructured surface is constructed which endows the resulted composite with significantly improved triboelectric performances (voltage increases from 8 to 24 V). Based on the excellent bimodal sensing performances and durability of the obtained composite, a highly reliable intelligent control system by machine learning has been developed for controlling trolley, providing an approach for advanced visual interaction devices and smart wearable electronics in the future IoT era.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 72, "DOI": "10.1007/s40820-023-01054-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01054-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959483800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, SM; Watanabe, M; Wu, J; An, Q; Ishihara, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Songmei; Watanabe, Motonori; Wu, Ji; An, Qi; Ishihara, Tatsumi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin WO3•0.33H2O nullotubes for CO2 Photoreduction to Acetate with High Selectivity", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis from CO2 reduction is severely hampered by the kinetically challenging multi-electron reaction process. Oxygen vacancies (Vo) with abundant localized electrons have great potential to overcome this limitation. However, surface Vo usually have low concentrations and are easily oxidized, causing them to lose their activities. For practical application of CO2 photoreduction, fabricating and enhancing the stability of Vo on semiconductors is indispensable. Here we report the first synthesis of ultrathin WO3 center dot 0.33H(2)O nullotubes with a large amount of exposed surface Vo sites, which can realize excellent and stable CO2 photoreduction to CH3COOH in pure water under solar light. The selectivity for acetum generation is up to 85%, with an average productivity of about 9.4 mu mol g(-1) h(-1). More importantly, Vo in the catalyst are sustainable, and their concentration was not decreased even after 60 h of reaction. Quantum chemical calculations and in situ DRIFT studies revealed that the main reaction pathway might be CO2 -> (COOH)-C-center dot -> (COOH)(2) -> CH3COOH.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2018, "Volume": 140, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6474, "End Page": 6482, "Article Number": null, "DOI": "10.1021/jacs.8b03316", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b03316", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433404000040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Li, M; Wang, YC; Han, F; Shen, K; Luo, L; Li, Y; Jia, YH; Zhang, J; Cai, WX; Wang, KJ; Zhao, M; Wang, J; Gao, XW; Tian, CY; Guo, BL; Hu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yue; Li, Meng; Wang, Yunchuan; Han, Fei; Shen, Kuo; Luo, Liang; Li, Yan; Jia, Yanhui; Zhang, Jian; Cai, Weixia; Wang, Kejia; Zhao, Ming; Wang, Jing; Gao, Xiaowen; Tian, Chenyang; Guo, Baolin; Hu, Dahai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exosome/metformin-loaded self-healing conductive hydrogel rescues microvascular dysfunction and promotes chronic diabetic wound healing by inhibiting mitochondrial fission", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chronic diabetic wounds remain a globally recognized clinical challenge. They occur due to high concentrations of reactive oxygen species and vascular function disorders. A promising strategy for diabetic wound healing is the delivery of exosomes, comprising bioactive dressings. Metformin activates the vascular endothelial growth factor pathway, thereby improving angiogenesis in hyperglycemic states. However, multifunctional hydrogels loaded with drugs and bioactive substances synergistically promote wound repair has been rarely reported, and the mechanism of their combinatorial effect of exosome and metformin in wound healing remains unclear. Here, we engineered dual-loaded hydrogels possessing tissue adhesive, antioxidant, self-healing and electrical conduc-tivity properties, wherein 4-armed SH-PEG cross-links with Ag+, which minimizes damage to the loaded goods and investigated their mechanism of promotion effect for wound repair. Multiwalled carbon nullotubes exhib-iting good conductivity were also incorporated into the hydrogels to generate hydrogen bonds with the thiol group, creating a stable three-dimensional structure for exosome and metformin loading. The diabetic wound model of the present study suggests that the PEG/Ag/CNT-M + E hydrogel promotes wound healing by triggering cell proliferation and angiogenesis and relieving peritraumatic inflammation and vascular injury. The mecha-nism of the dual-loaded hydrogel involves reducing the level of reactive oxygen species by interfering with mitochondrial fission, thereby protecting F-actin homeostasis and alleviating microvascular dysfunction. Hence, we propose a drug-bioactive substance combination therapy and provide a potential mechanism for developing vascular function-associated strategies for treating chronic diabetic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 323, "End Page": 336, "Article Number": null, "DOI": "10.1016/j.bioactmat.2023.01.020", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2023.01.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955051400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WW; Liao, XB; Xu, WN; Zhao, KN; Yao, G; Wu, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Wangwang; Liao, Xiaobin; Xu, Weina; Zhao, Kangning; Yao, Guang; Wu, Qinglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion Selective and Water Resistant Cellulose nullofiber/MXene Membrane Enabled Cycling Zn Anode at High Currents", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous rechargeable zinc ion batteries (ZIBs) are regarded as a promising candidates for next-generation energy storage devices but strongly hindered by the limited utilization of the zinc metal anode (below 5%) due to the active water/anion corrosion. Herein, an ion selective and water-resistant cellulose nullofiber (CNF)/MXene composite membrane has been developed through molecular sieving to restrict active water and anions from the electrode/electrolyte interface through dehydration of zinc ions, avoiding the water/anion-induced corrosion/decomposition. In this way, the CNF/MXene@Zn anode exhibits significantly enhanced coulombic efficiency (99.5 % at 10 mA cm(-2)) and low voltage hysteresis. Moreover, coated with CNF/MXene composite membrane, zinc symmetric batteries can be operated at the extremely high current of 100 mA cm(-2) and ultra-high Zn utilization of 88.2% to achieve record-high cumulative plating capacity of 12 Ah cm(-2). Furthermore, the full vanadium dioxide (VO2) |CNF/MXene@Zn batteries exhibit a high capacity of 357 mAh g(-1) at 2 A g(-1) and retain 93.3% of the capacity after 500 cycles. Moreover, at negative/ positive capacity (N/P) ratio of 2.8, the CNF/MXene membrane coated zinc is able to stably cycle for 100 cycles, demonstrating the potential for high energy zinc battery. This designed CNF/MXene membrane enables ZIBs as viable energy storage devices for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 13, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202300283", "DOI Link": "http://dx.doi.org/10.1002/aenm.202300283", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939424300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, T; Zhang, W; Arcelus, O; Kim, JG; Carrasco, J; Yoo, SJ; Zheng, WT; Wang, JF; Tian, HW; Zhang, HB; Cui, XQ; Rojo, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Ting; Zhang, Wei; Arcelus, Oier; Kim, Jin-Gyu; Carrasco, Javier; Yoo, Seung Jo; Zheng, Weitao; Wang, Jiafu; Tian, Hongwei; Zhang, Hengbin; Cui, Xiaoqiang; Rojo, Teofilo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-level energy storage mechanism of cobalt hydroxide electrode for pseudocapacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt hydroxide is a promising electrode material for supercapacitors due to the high capacitance and long cyclability. However, the energy storage/conversion mechanism of cobalt hydroxide is still vague at the atomic level. Here we shed light on how cobalt hydroxide functions as a supercapacitor electrode at operando conditions. We find that the high specific capacitance and long cycling life of cobalt hydroxide involve a complete modification of the electrode morphology, which is usually believed to be unfavourable but in fact has little influence on the performance. The conversion during the charge/discharge process is free of any massive structural evolution, but with some tiny shuffling or adjustments of atom/ion species. The results not only unravel that the potential of supercapacitors could heavily rely on the underlying structural similarities of switching phases but also pave the way for future material design for supercapacitors, batteries and hybrid devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15194, "DOI": "10.1038/ncomms15194", "DOI Link": "http://dx.doi.org/10.1038/ncomms15194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400860900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, ZY; Xiao, CX; Liu, C; Goh, TW; Zhou, L; Maligal-Ganesh, R; Pei, YC; Li, XL; Curtiss, LA; Huang, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Zhiyuan; Xiao, Chaoxian; Liu, Cong; Goh, Tian Wei; Zhou, Lin; Maligal-Ganesh, Raghu; Pei, Yuchen; Li, Xinle; Curtiss, Larry A.; Huang, Wenyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-4 nm PtZn Intermetallic nulloparticles for Enhanced Mass and Specific Activities in Catalytic Electrooxidation Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically ordered intermetallic nulloparticles (iNPs) have sparked considerable interest in fuel cell applications by virtue of their exceptional electronic and structural properties. However, the synthesis of small iNPs in a controllable manner remains a formidable challenge because of the high temperature generally required in the formation of intermetallic phases. Here we report a general method for the synthesis of PtZn. iNPs (3.2 +/- 0.4 nm) on multiwalled carbon nullotubes (MWNT) via a facile and capping agent free strategy using a sacrificial mesoporous silica (mSiO(2)) shell. The as-prepared PtZn iNPs exhibited ca. 10 times higher mass activity in both acidic and basic solution toward the methanol oxidation reaction (MOR) compared to larger PtZn iNPs synthesized on MWNT without the mSiO2 shell. Density functional theory (DFT) calculations predict that PtZn systems go through a non-CO pathway for MOR because of the stabilization of the OH* intermediate by Zn atoms, while a pure Pt system forms highly stable COH* and CO* intermediates, leading to catalyst deactivation. Experimental studies on the origin of the backward oxidation peak of MOR coincide well with DFT predictions. Moreover, the calculations demonstrate that MOR on smaller PtZn iNPs is energetically more favorable than larger iNPs, due to their high density of corner sites and lower-lying energetic pathway. Therefore, smaller PtZn iNPs not only increase the number but also enhance the activity of the active sites in MOR compared with larger ones. This work opens a new avenue for the synthesis of small iNPs with more undercoordinated and enhanced active sites for fuel cell applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2017, "Volume": 139, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4762, "End Page": 4768, "Article Number": null, "DOI": "10.1021/jacs.6b12780", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b12780", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398764000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Qian, J; Ye, YF; Zhou, H; Sun, CJ; Sheehan, C; Zhang, ZY; Wan, G; Liu, YS; Guo, JH; Li, S; Shin, H; Hwang, S; Gunnoe, TB; Goddard, WA ; Zhang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chang; Qian, Jin; Ye, Yifan; Zhou, Hua; Sun, Cheng-Jun; Sheehan, Colton; Zhang, Zhiyong; Wan, Gang; Liu, Yi-Sheng; Guo, Jinghua; Li, Shuang; Shin, Hyeyoung; Hwang, Sooyeon; Gunnoe, T. Brent; Goddard, William A., III; Zhang, Sen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nullorod surface", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient electrocatalysts for the oxygen evolution reaction (OER) are paramount to the development of electrochemical devices for clean energy and fuel conversion. However, the structural complexity of heterogeneous electrocatalysts makes it a great challenge to elucidate the surface catalytic sites and OER mechanisms. Here, we report that catalytic single-site Co in a well-defined brookite TiO2 nullorod (210) surface (Co-TiO2) presents turnover frequencies that are among the highest for Co-based heterogeneous catalysts reported to date, reaching 6.6 +/- 1.2 and 181.4 +/- 28 s(-1) at 300 and 400 mV overpotentials, respectively. Based on grand canonical quantum mechanics calculations and the single-site Co atomic structure validated by in situ and ex situ spectroscopic probes, we have established a full description of the catalytic reaction kinetics for Co-TiO2 as a function of applied potential, revealing an adsorbate evolution mechanism for the OER. The computationally predicted Tafel slope and turnover frequencies exhibit exceedingly good agreement with experiment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 36, "End Page": 45, "Article Number": null, "DOI": "10.1038/s41929-020-00550-5", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00550-5", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000598704500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eperon, GE; Habisreutinger, SN; Leijtens, T; Bruijnaers, BJ; van Franeker, JJ; Dequilettes, DW; Pathak, S; Sutton, RJ; Grancini, G; Ginger, DS; Janssen, RAJ; Petrozza, A; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eperon, Giles E.; Habisreutinger, Severin N.; Leijtens, Tomas; Bruijnaers, Bardo J.; van Franeker, Jacobus J.; dequilettes, Dane W.; Pathak, Sandeep; Sutton, Rebecca J.; Grancini, Giulia; Ginger, David S.; Janssen, Rene A. J.; Petrozza, Annamaria; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Importance of Moisture in Hybrid Lead Halide Perovskite Thin Film Fabrication", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moisture, in the form of ambient humidity, has a significant impact on methylammonium lead halide perovskite films. In particular, due to the hygroscopic nature of the methylammonium component, moisture plays a significant role during film formation. This issue has so far not been well understood and neither has the impact of moisture on the physical properties of resultant films. Herein, we carry out a comprehensive and well-controlled study of the effect of moisture exposure on methylammonium lead halide perovskite film formation and properties. We find that films formed in higher humidity atmospheres have a less continuous morphology but significantly improved photoluminescence, and that film formation is faster. In photovoltaic devices, we find that exposure to moisture, either in the precursor solution or in the atmosphere during formation, results in significantly improved open-circuit voltages and hence overall device performance. We then find that by post-treating dry films with moisture exposure, we can enhance photovoltaic performance and photoluminescence in a similar way. The enhanced photoluminescence and open-circuit voltage imply that the material quality is improved in films that have been exposed to moisture. We determine that this improvement stems from a reduction in trap density in the films, which we postulate to be due to the partial salvation of the methylammonium component and self-healing of the perovskite lattice. This work highlights the importance of controlled moisture exposure when fabricating high-performance perovskite devices and provides guidelines for the optimum environment for fabrication. Moreover, we note that often an unintentional water exposure is likely responsible for the high performance of solar cells produced in some laboratories, whereas careful synthesis and fabrication in a dry environment will lead to lower-performing devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9380, "End Page": 9393, "Article Number": null, "DOI": "10.1021/acsnullo.5b03626", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b03626", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361935800078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SF; Fatemi, V; Gibson, QD; Watanabe, K; Taniguchi, T; Cava, RJ; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Sanfeng; Fatemi, Valla; Gibson, Quinn D.; Watanabe, Kenji; Taniguchi, Takashi; Cava, Robert J.; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the quantum spin Hall effect up to 100 kelvin in a monolayer crystal", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of monolayer crystals have been proposed to be two-dimensional topological insulators exhibiting the quantum spin Hall effect (QSHE), possibly even at high temperatures. Here we report the observation of the QSHE in monolayer tungsten ditelluride (WTe2) at temperatures up to 100 kelvin. In the short-edge limit, the monolayer exhibits the hallmark transport conductance, similar to e(2)/h per edge, where e is the electron charge and h is Planck's constant. Moreover, a magnetic field suppresses the conductance, and the observed Zeeman-type gap indicates the existence of a Kramers degenerate point and the importance of time-reversal symmetry for protection from elastic backscattering. Our results establish the QSHE at temperatures much higher than in semiconductor heterostructures and allow for exploring topological phases in atomically thin crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 667, "Times Cited, All Databases": 746, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 359, "Issue": 6371, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": 79, "Article Number": null, "DOI": "10.1126/science.aan6003", "DOI Link": "http://dx.doi.org/10.1126/science.aan6003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419324700070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, S; Oguchi, H; Toyama, N; Sato, T; Takagi, S; Otomo, T; Arunkumar, D; Kuwata, N; Kawamura, J; Orimo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sangryun; Oguchi, Hiroyuki; Toyama, Naoki; Sato, Toyoto; Takagi, Shigeyuki; Otomo, Toshiya; Arunkumar, Dorai; Kuwata, Naoaki; Kawamura, Junichi; Orimo, Shin-ichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A complex hydride lithium superionic conductor for high-energy-density all-solid-state lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state batteries incorporating lithium metal anode have the potential to address the energy density issues of conventional lithium-ion batteries that use flammable organic liquid electrolytes and low-capacity carbonaceous anodes. However, they suffer from high lithium ion transfer resistance, mainly due to the instability of the solid electrolytes against lithium metal, limiting their use in practical cells. Here, we report a complex hydride lithium superionic conductor, 0.7Li(CB9H10)-0.3Li(CB11H12), with excellent stability against lithium metal and a high conductivity of 6.7 x 10(-3) S cm(-1) at 25 degrees C. This complex hydride exhibits stable lithium plating/stripping reaction with negligible interfacial resistance (< 1 Omega cm(2)) at 0.2 mA cm(-2), enabling all-solid-state lithium-sulfur batteries with high energy density (>2500 Wh kg(-1)) at a high current density of 5016 mA g(-1). The present study opens up an unexplored research area in the field of solid electrolyte materials, contributing to the development of high-energy-density batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1081, "DOI": "10.1038/s41467-019-09061-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09061-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460410300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Zhang, HX; Zou, SZ; Cai, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kun; Zhang, Han-Xuan; Zou, Shouzhong; Cai, Wen-Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrocatalysis of formic acid on palladium and platinum surfaces: from fundamental mechanisms to fuel cell applications", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formic acid as a natural biomass and a CO2 reduction product has attracted considerable interest in renewable energy exploitation, serving as both a promising candidate for chemical hydrogen storage material and a direct fuel for low temperature liquid fed fuel cells. In addition to its chemical dehydrogenation, formic acid oxidation (FAO) is a model reaction in the study of electrocatalysis of C1 molecules and the anode reaction in direct formic acid fuel cells (DFAFCs). Thanks to a deeper mechanistic understanding of FAO on Pt and Pd surfaces brought about by recent advances in the fundamental investigations, the synthesis-by-design'' concept has become a mainstream idea to attain high-performance Pt-and Pd-based nullocatalysts. As a result, a large number of efficient nullocatalysts have been obtained through different synthesis strategies by tailoring geometric and electronic structures of the two primary catalytic metals. In this paper, we provide a brief overview of recent progress in the mechanistic studies of FAO, the synthesis of novel Pd-and Pt-based nullocatalysts as well as their practical applications in DFAFCs with a focus on discussing studies significantly contributing to these areas in the past five years.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 16, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20360, "End Page": 20376, "Article Number": null, "DOI": "10.1039/c4cp03151b", "DOI Link": "http://dx.doi.org/10.1039/c4cp03151b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342072300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, Y; Askounis, E; Plamthottam, R; Libby, T; Peng, ZH; Youssef, K; Pu, JH; Pelrine, R; Pei, QB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Ye; Askounis, Erin; Plamthottam, Roshan; Libby, Tom; Peng, Zihang; Youssef, Kareem; Pu, Junhong; Pelrine, Ron; Pei, Qibing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A processable, high-performance dielectric elastomer and multilayering process", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric elastomers (DEs) can act as deformable capacitors that generate mechanical work in response to an electric field. DEs are often based on commercial acrylic and silicone elastomers. Acrylics require prestretching to achieve high actuation strains and lack processing flexibility. Silicones allow for processability and rapid response but produce much lower strains. In this work, a processable, high-performance dielectric elastomer (PHDE) with a bimodal network structure is synthesized, and its electromechanical properties are tailored by adjusting cross-linkers and hydrogen bonding within the elastomer network. The PHDE exhibits a maximum areal strain of 190% and maintains strains higher than 110% at 2 hertz without prestretching. A dry stacking process with high efficiency, scalability, and yield enables multilayer actuators that maintain the high actuation performance of single-layer films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 8", "Publication Year": 2022, "Volume": 377, "Issue": 6602, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn0099", "DOI Link": "http://dx.doi.org/10.1126/science.abn0099", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822228900049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Conk, RJ; Hanna, S; Shi, JX; Yang, J; Ciccia, NR; Qi, L; Bloomer, BJ; Heuvel, S; Wills, T; Su, J; Bell, AT; Hartwig, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Conk, Richard J.; Hanna, Steven; Shi, Jake X.; Yang, Ji; Ciccia, Nicodemo R.; Qi, Liang; Bloomer, Brandon J.; Heuvel, Steffen; Wills, Tyler; Su, Ji; Bell, Alexis T.; Hartwig, John F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic deconstruction of waste polyethylene with ethylene to form propylene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of polyolefins to monomers would create a valuable carbon feedstock from the largest fraction of waste plastic. However, breakdown of the main chains in these polymers requires the cleavage of carbon-carbon bonds that tend to resist selective chemical transformations. Here, we report the production of propylene by partial dehydrogenation of polyethylene and tandem isomerizing ethenolysis of the desaturated chain. Dehydrogenation of high-density polyethylene with either an iridium-pincer complex or platinum/zinc supported on silica as catalysts yielded dehydrogenated material containing up to 3.2% internal olefins; the combination of a second-generation Hoveyda-Grubbs metathesis catalyst and [PdP(tBu)(3)(mu-Br)](2) as an isomerization catalyst selectively degraded this unsaturated polymer to propylene in yields exceeding 80%. These results show promise for the application of mild catalysis to deconstruct otherwise stable polyolefins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 377, "Issue": 6614, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1561, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.add1088", "DOI Link": "http://dx.doi.org/10.1126/science.add1088", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891713300032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YY; Cai, ZC; Liu, SJ; Zhang, HK; Wong, STH; Lam, JWY; Kwok, RTK; Qian, J; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuanyuan; Cai, Zhaochong; Liu, Shunjie; Zhang, Haoke; Wong, Sherman T. H.; Lam, Jacky W. Y.; Kwok, Ryan T. K.; Qian, Jun; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of AIEgens for near-infrared IIb imaging through structural modulation at molecular and morphological levels", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluorescence imaging in near-infrared IIb (NIR-IIb, 1500-1700 nm) spectrum holds a great promise for tissue imaging. While few inorganic NIR-IIb fluorescent probes have been reported, their organic counterparts are still rarely developed, possibly due to the shortage of efficient materials with long emission wavelength. Herein, we propose a molecular design philosophy to explore pure organic NIR-IIb fluorophores by manipulation of the effects of twisted intramolecular charge transfer and aggregation-induced emission at the molecular and morphological levels. An organic fluorescent dye emitting up to 1600 nm with a quantum yield of 11.5% in the NIR-II region is developed. NIR-IIb fluorescence imaging of blood vessels and deeply-located intestinal tract of live mice based on organic dyes is achieved with high clarity and enhanced signal-to-background ratio. We hope this study will inspire further development on the evolution of pure organic NIR-IIb dyes for bio-imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 445, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1255, "DOI": "10.1038/s41467-020-15095-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15095-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549164300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZQ; Liu, X; Wang, GN; Li, B; Chen, HZ; Li, HR; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiqiang; Liu, Xiao; Wang, Guannull; Li, Bin; Chen, Hongzhong; Li, Huanrong; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoresponsive supramolecular coordination polyelectrolyte as smart anticounterfeiting inks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While photoluminescence printing is a widely applied anticounterfeiting technique, there are still challenges in developing new generation anticounterfeiting materials with high security. Here we report the construction of a photoresponsive supramolecular coordination polyelectrolyte (SCP) through hierarchical self-assembly of lanthanide ion, bis-ligand and diarylethene unit, driven by metal-ligand coordination and ionic interaction. Owing to the conformation-dependent photochromic fluorescence resonullce energy transfer between the lanthanide donor and diarylethene acceptor, the ring-closure/ring-opening isomerization of the diarylethene unit leads to a photoreversible luminescence on/off switch in the SCP. The SCP is then utilized as security ink to print various patterns, through which photoreversible multiple information patterns with visible/invisible transformations are realized by simply alternating the irradiation with UV and visible light. This work demonstrates the possibility of developing a new class of smart anticounterfeiting materials, which could be operated in a noninvasive manner with a higher level of security. Photoluminescence printing is a widely applied anticounterfeiting technique but there are still challenges in developing new generation anticounterfeiting materials providing a high security level. Here, the authors demonstrate coordination dependent photochromic luminescence in a supramolecular coordination polyelectrolyte for multiple information authentication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1363, "DOI": "10.1038/s41467-021-21677-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21677-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626168500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Zhu, RL; Ma, LY; Fu, HY; Lin, XJ; Parker, SC; Molinari, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jing; Zhu, Runliang; Ma, Lingya; Fu, Haoyang; Lin, Xiaoju; Parker, Stephen C.; Molinari, Marco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of phosphate and cadmium on iron (oxyhydr)oxides: A comparative study on ferrihydrite, goethite, and hematite", "Source Title": "GEODERMA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron (oxyhydr)oxides participate in a variety of geochemical processes, and hence control the cycling of elements and quality of soils. The present work provides information about the macroscopic adsorption behaviors and microscopic mechanisms of typical cations and oxyanions (i.e., cadmium and phosphate) on three omnipresent iron (oxyhydr)oxides (i.e., ferrihydrite (Fh), goethite (Gt), and hematite (Hm)) in single- and double-solute systems, which can not only help in understanding the different adsorption behaviors of iron (oxyhydr)oxides, but also be important in developing robust and accurate surface complexation models. In both adsorption systems, Fh exhibited the strongest capacity in the uptake of phosphate and cadmium, followed by Gt and Hm; specifically, the adsorbed amounts of ions by Fh were similar to 6 times higher than those by Gt and Hm. Phosphate and cadmium can be synergistically adsorbed by the minerals. In situ attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra combining with the two-dimensional correlation spectroscopic (2D-COS) analysis were employed to unravel the bonding modes of phosphate on minerals. In the single-solute adsorption systems, although the primary species on Hm and Gt were similar, i.e., protonated and non-protonated bidentate phosphate complexes, more protonated complexes were found on Hm than on Gt; whereas the complexation modes of phosphate on Fh were diversified due to the complex nature of the surfaces, including monoprotonated bidentate, non-protonated bidentate, and outer-sphere complexes. The synergistic adsorption mechanisms of phosphate and cadmium on the three minerals were analogous, including electrostatic interaction, as well as the formation of phosphate-bridged ternary complexes and surface precipitation; nevertheless, the relative contributions of the mechanisms on the minerals were distinct: electrostatic attraction was the predominullt coadsorption mechanism for ions on Gt, while surface precipitation was the most significant on Fh among the three minerals. This study can be enlightening to understand the interaction between the soil constituents, which is crucial to evaluate the fate and transport of the environmentally important substances in different geological settings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 383, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114799, "DOI": "10.1016/j.geoderma.2020.114799", "DOI Link": "http://dx.doi.org/10.1016/j.geoderma.2020.114799", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000590747800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, XY; Wang, Y; Li, RX; Cao, HL; Li, YF; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Xue-Yu; Wang, Yu; Li, Rong-Xin; Cao, Hai-Lei; Li, Ya-Feng; Lu, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impacts of temperatures and phosphoric-acid modification to the physicochemical properties of biochar for excellent sulfadiazine adsorption", "Source Title": "BIOCHAR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The textural properties and surface chemistry of phosphoric acid-modified biochars (PABCs) prepared at different pyrolysis temperatures (500-700 degrees C) were studied based on the results obtained from XRD, SEM, BET, FT-IR, Raman, XPS and elements analyses. PABCs prepared at higher temperatures tended to possess a bigger proportion of microporous structure. The adsorption capacity and initial rate of PABCs for sulfadiazine (SDZ) were notably improved to 139.2 mg/g and 9.66 mg/(g min) as calculated from the Langmuir model. The adsorption equilibrium time was only one quarter of that without modification. The H3PO4 modification was advantageous to produce phosphate and break functional groups to form disordered carbon structure abundant of micropores. The enhancement in the adsorption of SDZ was due to the confinement effect of hydrophobic cavities from the mircoporous structure and the pi-pi electron-donor-acceptor interaction. Specially, PABCs exhibited stable adsorption capacities at a wide pH range (3.0-9.0) or relatively high concentrations of coexisting ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14, "DOI": "10.1007/s42773-022-00143-4", "DOI Link": "http://dx.doi.org/10.1007/s42773-022-00143-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758824000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trantidou, T; Elani, Y; Parsons, E; Ces, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trantidou, Tatiana; Elani, Yuval; Parsons, Edward; Ces, Oscar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrophilic surface modification of PDMS for droplet microfluidics using a simple, quick, and robust method via PVA deposition", "Source Title": "MICROSYSTEMS & nullOENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydimethylsiloxane (PDMS) is a dominullt material in the fabrication of microfluidic devices to generate water-in-oil droplets, particularly lipid-stabilized droplets, because of its highly hydrophobic nature. However, its key property of hydrophobicity has hindered its use in the microfluidic generation of oil-in-water droplets, which requires channels to have hydrophilic surface properties. In this article, we developed, optimized, and characterized a method to produce PDMS with a hydrophilic surface via the deposition of polyvinyl alcohol following plasma treatment and demonstrated its suitability for droplet generation. The proposed method is simple, quick, effective, and low cost and is versatile with respect to surfactants, with droplets being successfully generated using both anionic surfactants and more biologically relevant phospholipids. This method also allows the device to be selectively patterned with both hydrophilic and hydrophobic regions, leading to the generation of double emulsions and inverted double emulsions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2017, "Volume": 3, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16091, "DOI": "10.1038/micronullo.2016.91", "DOI Link": "http://dx.doi.org/10.1038/micronullo.2016.91", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400384500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brivio, F; Frost, JM; Skelton, JM; Jackson, AJ; Weber, OJ; Weller, MT; Goñi, AR; Leguy, AMA; Barnes, PRF; Walsh, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brivio, Federico; Frost, Jarvist M.; Skelton, Jonathan M.; Jackson, Adam J.; Weber, Oliver J.; Weller, Mark T.; Goni, Alejandro R.; Leguy, Aurelien M. A.; Barnes, Piers R. F.; Walsh, Aron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hybrid halide perovskite CH3NH3PbI3 exhibits a complex structural behavior, with successive transitions between orthorhombic, tetragonal, and cubic polymorphs around 165 and 327 K. Herein we report first-principles lattice dynamics (phonon spectrum) for each phase of CH3NH3PbI3. The equilibrium structures compare well to solutions of temperature-dependent powder neutron diffraction. By following the normal modes, we calculate infrared and Raman intensities of the vibrations, and compare them to the measurement of a single crystal where the Raman laser is controlled to avoid degradation of the sample. Despite a clear separation in energy between low-frequency modes associated with the inorganic (PbI3-)(n) network and high-frequency modes of the organic CH3NH3+ cation, significant coupling between them is found, which emphasizes the interplay between molecular orientation and the corner-sharing octahedral networks in the structural transformations. Soft modes are found at the boundary of the Brillouin zone of the cubic phase, consistent with displacive instabilities and anharmonicity involving tilting of the PbI6 octahedra around room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 465, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2015, "Volume": 92, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144308, "DOI": "10.1103/PhysRevB.92.144308", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.144308", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362896700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, Q; Li, WD; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Qiang; Li, Wangda; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Mg-Doped High-Nickel Layered Oxide Cathode Enabling Safer, High-Energy-Density Li-Ion Batteries", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-nickel layered oxide cathodes with a Ni content of >90% show substantial potential for next-generation lithium-ion batteries (LIBs) due to their high capacity and lower cost. However, they are plagued by rapid capacity decay and poor thermal stability, which hamper their practical viability. We present here Li0.98Mg0.02Ni0.94Co0.06O2 (NC-Mg) with 2% Mg doping, aiming to provide a strategic guideline for solving the issues. The Mg2+ ions occupy the lithium layer and are proposed to act as pillar ions, which substantially enhance the structural reversibility and reduce the anisotropic lattice distortion upon cycling, thereby greatly improving the electrochemical and thermal stability of NC-Mg compared to the undoped LiNi0.94Co0.06O2 (NC). Specifically, NC-Mg delivers 214 mA h g(-1) with a capacity retention of 80.1% after 500 cycles in pouch-type full cells, much higher than the retention of NC (56.3%). A discharge capacity of 158 mA h g(-1) at 10C rate demonstrates its remarkable rate capability. Additionally, the Mg doping significantly elevates the exothermic peak temperature of NC-Mg to 211 degrees C, in sharp contrast to 177 degrees C for NC, highlighting the improved thermal stability of NC-Mg. Collectively, the superior performance of NC-Mg demonstrates a feasible alternative strategy for developing safer, high-energy-density LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2019, "Volume": 31, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 938, "End Page": 946, "Article Number": null, "DOI": "10.1021/acs.chemmater.8b03900", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.8b03900", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458937800035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, VP; Park, JS; Shim, HC; Yuk, JM; Kim, JH; Kim, D; Lee, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, Viet Phuong; Park, Ji Su; Shim, Hyung Cheoul; Yuk, Jong Min; Kim, Jae-Hyun; Kim, Duckjong; Lee, Seung-Mo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Sulfur Evolution Reactions by TiS2/TiO2@MXene Host for High-Volumetric-Energy-Density Lithium-Sulfur Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor cycling stability and low volumetric energy density of lithium-sulfur batteries compared with lithium-ion batteries are hindering their practical applications. Here, it is demonstrated that a dense sulfur electrode containing heavy TiS2/TiO2@MXene heterostructures can tackle these issues. It is observed that the TiO2 part functionally anchors the lithium polysulfides through the strong chemical affinity, and the TiS2 part serves as an efficient electrocatalyst to enhance the kinetics of sulfur evolution reactions. Benefitting from these synergistic effects, the TiS2/TiO2@MXene heterostructures effectively suppress the shuttle effects, leading to superior cyclability of the sulfur cathode with a low capacity decay of 0.038% per cycle for 500 cycles at a current rate of 1 C. More encouragingly, a highly dense S/TiS2/TiO2@MXene cathode exhibits a high volumetric energy density of 2476 Wh L-1 (based on the volume of the composite) at a high sulfur mass loading of 7.5 mg cm(-2) and lean electrolyte of 5 mu L mg(-1). The electrochemical performance is comparable to or even superior to the lithium-ion and lithium-sulfur batteries reported in the literature. This study provides an effective strategy to design stable and high-volumetric-energy-density lithium-sulfur batteries for practical energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 33, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202303503", "DOI Link": "http://dx.doi.org/10.1002/adfm.202303503", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984978000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, RC; Ding, YN; Li, SB; Zhang, P; Xiang, QJ; Ng, YH; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Rongchen; Ding, Yingna; Li, Shibang; Zhang, Peng; Xiang, Quanjun; Ng, Yun Hau; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing low-cost Ni3C/twin-crystal Zn0.5Cd0.5S heterojunction/homojunction nullohybrids for efficient photocatalytic H2 evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-cost semiconductor photocatalysts for highly efficient and durable photocatalytic H-2 evolution under visible light is very challenging. In this study, we combine low-cost metallic Ni3C cocatalysts with twin nullocrystal Zn0.5Cd0.5S (ZCS) solid solution homojunctions for an efficient visible-light-driven H-2 production by a simple approach. As-synthesized Zn0.5Cd0.5S-1% Ni3C (ZCS-1) heterojunction/homojunction nullohybrid exhibited the highest photocatalytic H-2-evolution rate of 783 mu mol h(-1) under visible light, which is 2.88 times higher than that of pristine twin nullocrystal ZCS solid solution. The apparent quantum efficiencies of ZCS and ZCS-1 are measured to be 6.13% and 19.25% at 420 nm, respectively. Specifically, the homojunctions between the zinc blende and wurtzite segments in twin nullocrystal ZCS solid solution can significantly improve the light absorption and separation of photogenerated electron-hole pairs. Furthermore, the heterojunction between ZCS and metallic Ni3C NP cocatalysts can efficiently trap excited electrons from ZCS solid solution and enhance the H-2-evolution kinetics at the surface for improving catalytic activity. This study demonstrates a unique one-step strategy for constructing heterojunction/homojunction hybrid nullostructures for a more efficient photocatalytic H-2 evolution compared to other noble metal photocatalytic systems. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 25, "End Page": 36, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63600-2", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63600-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mangolim, CS; Moriwaki, C; Nogueira, AC; Sato, F; Baesso, ML; Neto, AM; Matioli, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mangolim, Camila Sampaio; Moriwaki, Cristiane; Nogueira, Ana Claudia; Sato, Francielle; Baesso, Mauro Luciano; Neto, Antonio Medina; Matioli, Graciette", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Curcumin-β-cyclodextrin inclusion complex: Stability, solubility, characterisation by FT-IR, FT-Raman, X-ray diffraction and photoacoustic spectroscopy, and food application", "Source Title": "FOOD CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Curcumin was complexed with beta-CD using co-precipitation, freeze-drying and solvent evaporation methods. Co-precipitation enabled complex formation, as indicated by the FT-IR and FT-Raman techniques via the shifts in the peaks that were assigned to the aromatic rings of curcumin. In addition, photoacoustic spectroscopy and X-ray diffraction, with the disappearance of the band related to aromatic rings, by Gaussian fitting, and modifications in the spectral lines, respectively, also suggested complex formation. The possible complexation had an efficiency of 74% and increased the solubility of the pure colourant 31-fold. Curcumin-beta-CD complex exhibited a sunlight stability 18% higher than the pure colourant. This material was stable to pH variations and storage at -15 and 4 degrees C. With an isothermal heating at 100 and 150 degrees C for 2 h, the material exhibited a colour retention of approximately 99%. The application of curcumin-beta-CD complex in vanilla ice creams intensified the colour of the products and produced a great sensorial acceptance. (C) 2013 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2014, "Volume": 153, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 361, "End Page": 370, "Article Number": null, "DOI": "10.1016/j.foodchem.2013.12.067", "DOI Link": "http://dx.doi.org/10.1016/j.foodchem.2013.12.067", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology; Nutrition & Dietetics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331990800050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PT; Yang, H; Tang, C; Wu, Y; Zheng, Y; Cheng, T; Davey, K; Huang, XQ; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengtang; Yang, Hao; Tang, Cheng; Wu, Yu; Zheng, Yao; Cheng, Tao; Davey, Kenneth; Huang, Xiaoqing; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting electrocatalytic CO2-to-ethanol production via asymmetric C-C coupling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of high interest to convert CO2 into valuable ethanol product. Here the authors demonstrate the asymmetric C-C coupling triggered on Ag-modified oxide-derived Cu sites can accelerate and steer the reaction pathway for ethanol production with high faradaic efficiency and current density. Electroreduction of carbon dioxide (CO2) into multicarbon products provides possibility of large-scale chemicals production and is therefore of significant research and commercial interest. However, the production efficiency for ethanol (EtOH), a significant chemical feedstock, is impractically low because of limited selectivity, especially under high current operation. Here we report a new silver-modified copper-oxide catalyst (dCu(2)O/Ag-2.3%) that exhibits a significant Faradaic efficiency of 40.8% and energy efficiency of 22.3% for boosted EtOH production. Importantly, it achieves CO2-to-ethanol conversion under high current operation with partial current density of 326.4 mA cm(-2) at -0.87 V vs reversible hydrogen electrode to rank highly significantly amongst reported Cu-based catalysts. Based on in situ spectra studies we show that significantly boosted production results from tailored introduction of Ag to optimize the coordinated number and oxide state of surface Cu sites, in which the *CO adsorption is steered as both atop and bridge configuration to trigger asymmetric C-C coupling for stablization of EtOH intermediates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3754, "DOI": "10.1038/s41467-022-31427-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31427-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830675000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Resasco, J; DeRita, L; Dai, S; Chada, JP; Xu, MJ; Yan, XX; Finzel, J; Hanukovich, S; Hoffman, AS; Graham, GW; Bare, SR; Pan, XQ; Christopher, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Resasco, Joaquin; DeRita, Leo; Dai, Sheng; Chada, Joseph P.; Xu, Mingjie; Yan, Xingxu; Finzel, Jordan; Hanukovich, Sergei; Hoffman, Adam S.; Graham, George W.; Bare, Simon R.; Pan, Xiaoqing; Christopher, Phillip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uniformity Is Key in Defining Structure-Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Catalysts consisting of atomically dispersed Pt (Pt-iso) species on CeO2 supports have received recent interest due to their potential for efficient metal utilization in catalytic convertors. However, discrepancies exist between the behavior (reducibility, interaction strength with adsorbates) of high surface area Pt-iso/CeO2 systems and of well-defined surface science and computational model systems, suggesting differences in Pt local coordination in the two classes of materials. Here, we reconcile these differences by demonstrating that high surface area Pt-iso/CeO2 synthesized at low Pt loadings (<0.1% weight) exhibit resistance to reduction and sintering up to 500 degrees C in 0.05 bar H-2 and minimal interactions with CO-properties previously seen only for model system studies. Alternatively, Pt loadings >0.1 weight % produce a distribution of sub-nullometer Pt structures, which are difficult to distinguish using common characterization techniques, and exhibit strong interactions with CO and weak resistance to sintering, even in 0.05 bar H-2 at 50 degrees C-properties previously seen for high surface area materials. This work demonstrates that low metal loadings can be used to selectively populate the most thermodynamically stable adsorption sites on high surface area supports with atomically dispersed metals. Further, the site uniformity afforded by this synthetic approach is critical for the development of relationships between atomic scale local coordination and functional properties. Comparisons to recent studies of Pt-iso/TiO2 suggest a general compromise between the stability of atomically dispersed metal catalysts and their ability to interact with and activate molecular species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2020, "Volume": 142, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 169, "End Page": 184, "Article Number": null, "DOI": "10.1021/jacs.9b09156", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b09156", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507144400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, Y; Yu, ZY; Yang, L; Zheng, LR; Zhang, CT; Yang, XT; Gao, FY; Zhang, XL; Yu, XX; Liu, R; Ding, HH; Gu, C; Zheng, XS; Shi, L; Jiang, J; Zhu, JF; Gao, MR; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Yu; Yu, Zi-You; Yang, Li; Zheng, Li-Rong; Zhang, Chu-Tian; Yang, Xiao-Tu; Gao, Fei-Yue; Zhang, Xiao-Long; Yu, Xingxing; Liu, Ren; Ding, Hong-He; Gu, Chao; Zheng, Xu-Sheng; Shi, Lei; Jiang, Jun; Zhu, Jun-Fa; Gao, Min-Rui; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimetallic nickel-molybdenum/tungsten nulloalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydroxide exchange membrane fuel cells offer possibility of adopting platinum-group-metal-free catalysts to negotiate sluggish oxygen reduction reaction. Unfortunately, the ultrafast hydrogen oxidation reaction (HOR) on platinum decreases at least two orders of magnitude by switching the electrolytes from acid to base, causing high platinum-group-metal loadings. Here we show that a nickel-molybdenum nulloalloy with tetragonal MoNi4 phase can catalyze the HOR efficiently in alkaline electrolytes. The catalyst exhibits a high apparent exchange current density of 3.41 milliamperes per square centimeter and operates very stable, which is 1.4 times higher than that of state-of-the-art Pt/C catalyst. With this catalyst, we further demonstrate the capability to tolerate carbon monoxide poisoning. Marked HOR activity was also observed on similarly designed WNi4 catalyst. We attribute this remarkable HOR reactivity to an alloy effect that enables optimum adsorption of hydrogen on nickel and hydroxyl on molybdenum (tungsten), which synergistically promotes the Volmer reaction. The lack of efficient and cost-effective catalysts for hydrogen oxidation reaction (HOR) hampers the application of hydroxide exchange membrane fuel cells. Here, authors reported bimetallic MoNi4 and WNi4 nulloalloys with marked HOR activity in alkali, among which MoNi4 outperforms the Pt/C catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 22", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4789, "DOI": "10.1038/s41467-020-18585-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18585-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573750800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lewis, RJ; Ueura, K; Liu, X; Fukuta, Y; Davies, TE; Morgan, DJ; Chen, LW; Qi, JZ; Singleton, J; Edwards, JK; Freakley, SJ; Kiely, CJ; Yamamoto, Y; Hutchings, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lewis, Richard J.; Ueura, Kenji; Liu, Xi; Fukuta, Yukimasa; Davies, Thomas E.; Morgan, David J.; Chen, Liwei; Qi, Jizhen; Singleton, James; Edwards, Jennifer K.; Freakley, Simon J.; Kiely, Christopher J.; Yamamoto, Yasushi; Hutchings, Graham J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient catalytic production of oximes from ketones using in situ-generated H2O2", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ammoximation of cyclohexanone using preformed hydrogen peroxide (H2O2) is currently applied commercially to produce cyclohexanone oxime, an important feedstock in nylon-6 production. We demonstrate that by using supported gold-palladium (AuPd) alloyed nulloparticles in conjunction with a titanium silicate-1 (TS-1) catalyst, H2O2 can be generated in situ as needed, producing cyclohexanone oxime with >95% selectivity, comparable to the current industrial route. The ammoximation of several additional simple ketones is also demonstrated. Our approach eliminates the need to transport and store highly concentrated, stabilized H2O2, potentially achieving substantial environmental and economic savings. This approach could form the basis of an alternative route to numerous chemical transformations that are currently dependent on a combination of preformed H2O2 and TS-1, while allowing for considerable process intensification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2022, "Volume": 376, "Issue": 6593, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 615, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abl4822", "DOI Link": "http://dx.doi.org/10.1126/science.abl4822", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796932700040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TF; Lv, YJ; Su, JH; Wang, Y; Yang, Q; Zhang, YW; Zhou, JC; Xu, L; Sun, DM; Tang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tongfei; Lv, Yinjie; Su, Jiahui; Wang, Yi; Yang, Qian; Zhang, Yiwei; Zhou, Jiancheng; Xu, Lin; Sun, Dongmei; Tang, Yawen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anchoring CoFe2O4 nulloparticles on N-Doped Carbon nullofibers for High-Performance Oxygen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of earth-abundant and high-efficiency electrocatalysts for the oxygen evolution reaction (OER) is of great significant for sustainable energy conversion and storage applications. Although spinel-type binary transition metal oxides (AB(2)O(4), A, B = metal) represent a class of promising candidates for water oxidation catalysis, their intrinsically inferior electrical conductivity exert remarkably negative impacts on their electrochemical performances. Herein, we demonstrates a feasible electrospinning approach to concurrently synthesize CoFe2O4 nulloparticles homogeneously embedded in 1D N-doped carbon nullofibers (denoted as CoFe2O4@N-CNFs). By integrating the catalytically active CoFe2O4 nulloparticles with the N-doped carbon nullofibers, the as-synthesized CoFe2O4@N-CNF nullohybrid manifests superior OER performance with a low overpotential, a large current density, a small Tafel slope, and long-term durability in alkaline solution, outperforming the single component counterparts (pure CoFe2O4 and N-doped carbon nullofibers) and the commercial RuO2 catalyst. Impressively, the overpotential of CoFe2O4@N-CNFs at the current density of 30.0 mA cm(-2) negatively shifts 186 mV as compared with the commercial RuO2 catalyst and the current density of the CoFe2O4@N-CNFs at 1.8 V is almost 3.4 times of that on RuO2 benchmark. The present work would open a new avenue for the exploration of cost-effective and efficient OER electrocatalysts to substitute noble metals for various renewable energy conversion/storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700226, "DOI": "10.1002/advs.201700226", "DOI Link": "http://dx.doi.org/10.1002/advs.201700226", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416155900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, PQ; Zhang, WX; Zhang, JP; Chen, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Pei-Qin; Zhang, Wei-Xiong; Zhang, Jie-Peng; Chen, Xiao-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient purification of ethene by an ethane-trapping metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Separating ethene (C2H4) from ethane (C2H6) is of paramount importance and difficulty. Here we show that C2H4 can be efficiently purified by trapping the inert C2H6 in a judiciously designed metal-organic framework. Under ambient conditions, passing a typical cracked gas mixture (15: 1 C2H4/C2H6) through 1 litre of this C2H6 selective adsorbent directly produces 56 litres of C2H4 with 99.95% + purity (required by the C2H4 polymerization reactor) at the outlet, with a single breakthrough operation, while other C2H6 selective materials can only produce ca. <= 1 litre, and conventional C2H4 selective adsorbents require at least four adsorption-desorption cycles to achieve the same C2H4 purity. Single-crystal X-ray diffraction and computational simulation studies showed that the exceptional C2H6 selectivity arises from the proper positioning of multiple electronegative and electropositive functional groups on the ultramicroporous pore surface, which form multiple C-H center dot center dot center dot N hydrogen bonds with C2H6 instead of the more polar competitor C2H4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 536, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8697, "DOI": "10.1038/ncomms9697", "DOI Link": "http://dx.doi.org/10.1038/ncomms9697", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364937800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Devlin, RC; Khorasaninejad, M; Chen, WT; Oh, J; Capasso, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Devlin, Robert C.; Khorasaninejad, Mohammadreza; Chen, Wei Ting; Oh, Jaewon; Capasso, Federico", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband high-efficiency dielectric metasurfaces for the visible spectrum", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces are planar optical elements that hold promise for overcoming the limitations of refractive and conventional diffractive optics. Original dielectric metasurfaces are limited to transparency windows at infrared wavelengths because of significant optical absorption and loss at visible wavelengths. Thus, it is critical that new materials and nullofabrication techniques be developed to extend dielectric metasurfaces across the visible spectrum and to enable applications such as high numerical aperture lenses, color holograms, and wearable optics. Here, we demonstrate high performance dielectric metasurfaces in the form of holograms for red, green, and blue wavelengths with record absolute efficiency (> 78%). We use atomic layer deposition of amorphous titanium dioxide with surface roughness less than 1 nm and negligible optical loss. We use a process for fabricating dielectric metasurfaces that allows us to produce anisotropic, subwavelength-spaced dielectric nullostructures with shape birefringence. This process is capable of realizing any high-efficiency metasurface optical element, e.g., metalenses and axicons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 538, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2016, "Volume": 113, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10473, "End Page": 10478, "Article Number": null, "DOI": "10.1073/pnas.1611740113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1611740113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383622600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, HC; Qin, GW; Huang, YM; Ren, YP; Sha, XC; Han, XD; Liu, ZQ; Li, CF; Wu, XL; Chen, HW; He, C; Chai, LJ; Wang, YZ; Nie, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Hucheng; Qin, Gaowu; Huang, Yunmiao; Ren, Yuping; Sha, Xuechao; Han, Xiaodong; Liu, Zhi-Quan; Li, Caifu; Wu, Xiaolei; Chen, Houwen; He, Cong; Chai, Linjiang; Wang, Yunzhi; Nie, Jian-feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of low-alloyed and rare-earth-free magnesium alloys having ultra-high strength", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing ultra-high strength in rare-earth-free Mg alloys using conventional extrusion process is a great challenge. What is even more difficult is to achieve such a goal at a lower processing cost. In this work, we report a novel low-alloyed Mg-2Sn-2Ca alloy (in wt. %) that exhibits tunable ultra-high tensile yield strength (360-440 MPa) depending on extrusion parameters. More importantly, there is little drop in mechanical properties of this alloy even when it is extruded at a speed several times higher than those used in the reported high strength Mg alloys. Examination of as-extruded microstructures of this Ca-containing Mg alloy reveals that the ultra-high strength is mainly associated with the presence of surprisingly submicron matrix grains (down to similar to 0.32 mu m). The results suggest that the Ca addition promotes accumulations of the pyramidal dislocations, which eventually transform into the low angular grain boundaries (LAGBs). The high number density of LAGBs separate the alpha-Mg matrix via either discontinuous dynamic recrystallization (DDRX) mechanism in the early stage or the continuous dynamic recrystallization (CDRX) mechanism in the later stage of extrusion, which effectively enhances the nucleation rates of the DRXed grains. More importantly, large amount of Ca segregation along LAGBs, accompanied with dynamically precipitated Mg2Ca nullo-phases, are detected in the present non-severely deformed samples. It is the combination of solute segregations and numerous Mg2Ca nullo-precipitates that contributes to the formation of the ultra-fine grains via pinning mechanism. The ultrafine grains size, Ca enrichment in most LAGBs, and residual Mg2Ca nullo-precipitates would in turn contribute significantly to the enhancement of the yield strength of the as-extruded Mg-2Sn-2Ca (wt.%) alloy. The low content of alloying elements and the fast one-step extrusion process render the present alloys low-cost and thus have great potential in large-scale industry applications. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2018, "Volume": 149, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 350, "End Page": 363, "Article Number": null, "DOI": "10.1016/j.actamat.2018.03.002", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.03.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430895000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, RR; Wang, HF; Du, HR; Yang, Y; Gao, ZH; Qie, L; Huang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ruirui; Wang, Haifeng; Du, Haoran; Yang, Ying; Gao, Zhonghui; Qie, Long; Huang, Yunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc batteries are appealing devices for cost-effective and environmentally sustainable energy storage. However, the zinc metal deposition at the anode strongly influences the battery cycle life and performance. To circumvent this issue, here we propose the use of lanthanum nitrate (La(NO3)(3)) as supporting salt for aqueous zinc sulfate (ZnSO4) electrolyte solutions. Via physicochemical and electrochemical characterizations, we demonstrate that this peculiar electrolyte formulation weakens the electric double layer repulsive force, thus, favouring dense metallic zinc deposits and regulating the charge distribution at the zinc metal|electrolyte interface. When tested in Zn||VS2 full coin cell configuration (with cathode mass loading of 16 mg cm(-2)), the electrolyte solution containing the lanthanum ions enables almost 1000 cycles at 1 A g(-1) (after 5 activation cycles at 0.05 A g(-1)) with a stable discharge capacity of about 90 mAh g(-1) and an average cell discharge voltage of similar to 0.54 V. Zinc metal is a promising anode material for aqueous secondary batteries. However, the unfavourable morphologies formed on the electrode surface during cycling limit its application. Here, the authors report the tailoring of the surface morphology using a lanthanum nitrate aqueous electrolyte additive.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3252, "DOI": "10.1038/s41467-022-30939-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30939-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808000200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, GJ; Shi, FY; Hao, SQ; Zhao, LD; Chi, H; Zhang, XM; Uher, C; Wolverton, C; Dravid, VP; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Gangjian; Shi, Fengyuan; Hao, Shiqiang; Zhao, Li-Dong; Chi, Hang; Zhang, Xiaomi; Uher, Ctirad; Wolverton, Chris; Dravid, Vinayak P.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-equilibrium processing leads to record high thermoelectric figure of merit in PbTe-SrTe", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The broad-based implementation of thermoelectric materials in converting heat to electricity hinges on the achievement of high conversion efficiency. Here we demonstrate a thermoelectric figure of merit ZT of 2.5 at 923 K by the cumulative integration of several performance-enhancing concepts in a single material system. Using non-equilibrium processing we show that hole-doped samples of PbTe can be heavily alloyed with SrTe well beyond its thermodynamic solubility limit of <1 mol%. The much higher levels of Sr alloyed into the PbTe matrix widen the bandgap and create convergence of the two valence bands of PbTe, greatly boosting the power factors with maximal values over 30 mu Wcm (-1) K (-2). Exceeding the 5 mol% solubility limit leads to endotaxial SrTe nullostructures which produce extremely low lattice thermal conductivity of 0.5 Wm (-1) K (-1) but preserve high hole mobilities because of the matrix/precipitate valence band alignment. The best composition is hole-doped PbTe-8% SrTe.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12167, "DOI": "10.1038/ncomms12167", "DOI Link": "http://dx.doi.org/10.1038/ncomms12167", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380196100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xian, JJ; Wang, C; Nie, JH; Li, R; Han, MJ; Lin, JH; Zhang, WH; Liu, ZY; Zhang, ZM; Miao, MP; Yi, YF; Wu, SW; Chen, XD; Han, JB; Xia, ZC; Ji, W; Fu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xian, Jing-Jing; Wang, Cong; Nie, Jin-Hua; Li, Rui; Han, Mengjiao; Lin, Junhao; Zhang, Wen-Hao; Liu, Zhen-Yu; Zhang, Zhi-Mo; Miao, Mao-Peng; Yi, Yangfan; Wu, Shiwei; Chen, Xiaodie; Han, Junbo; Xia, Zhengcai; Ji, Wei; Fu, Ying-Shuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin mapping of intralayer antiferromagnetism and field-induced spin reorientation in monolayer CrTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In two dimensions magnetic order without magnetic anisotropy is forbidden, making 2D magnetic systems a rich playground for interesting physics. Here, Xian et al. fabricate monolayers of CrTe2, and demonstrate antiferromagnetic ordering, with spin reorientation at finite magnetic fields. Intrinsic antiferromagnetism in van der Waals (vdW) monolayer (ML) crystals enriches our understanding of two-dimensional (2D) magnetic orders and presents several advantages over ferromagnetism in spintronic applications. However, studies of 2D intrinsic antiferromagnetism are sparse, owing to the lack of net magnetisation. Here, by combining spin-polarised scanning tunnelling microscopy and first-principles calculations, we investigate the magnetism of vdW ML CrTe2, which has been successfully grown through molecular-beam epitaxy. We observe a stable antiferromagnetic (AFM) order at the atomic scale in the ML crystal, whose bulk is ferromagnetic, and correlate its imaged zigzag spin texture with the atomic lattice structure. The AFM order exhibits an intriguing noncollinear spin reorientation under magnetic fields, consistent with its calculated moderate magnetic anisotropy. The findings of this study demonstrate the intricacy of 2D vdW magnetic materials and pave the way for their in-depth analysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 257, "DOI": "10.1038/s41467-021-27834-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27834-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741852200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, SY; Liu, M; Pan, JJ; Liu, XN; Tan, XL; Xu, N; He, Y; Lei, LC; Zhang, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Shaoyun; Liu, Min; Pan, Junjie; Liu, Xiangnull; Tan, Xiaoli; Xu, null; He, Yi; Lei, Lecheng; Zhang, Xingwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dopants fixation of Ruthenium for boosting acidic oxygen evolution stability and activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing highly durable and active electrocatalysts applied in polymer electrolyte membrane (PEM) electrolyzer for the oxygen evolution reaction remains a grand challenge due to the high dissolution of catalysts in acidic electrolyte. Hindering formation of oxygen vacancies by tuning the electronic structure of catalysts to improve the durability and activity in acidic electrolyte was theoretically effective but rarely reported. Herein we demonstrated rationally tuning electronic structure of RuO2 with introducing W and Er, which significantly increased oxygen vacancy formation energy. The representative W0.2Er0.1Ru0.7O2-delta required a super-low overpotential of 168mV (10mA cm(-)(2)) accompanied with a record stability of 500h in acidic electrolyte. More remarkably, it could operate steadily for 120h (100mA cm(-)(2)) in PEM device. Density functional theory calculations revealed co-doping of W and Er tuned electronic structure of RuO2 by charge redistribution, which significantly prohibited formation of soluble Ru-x>4 and lowered adsorption energies for oxygen intermediates. There is an increasing interest in understanding how defect chemistry can alter material reactivity. Here, authors tune the electronic structure of RuO2 by introducing W and Er dopants that boost acidic oxygen evolution performances by limiting oxygen vacancy formation during catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5368, "DOI": "10.1038/s41467-020-19212-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19212-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000586507600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, LN; Zhang, W; Wang, Y; Ge, X; Zou, LC; Wang, HF; Wang, XX; Liu, QC; Li, F; Xu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Li-Na; Zhang, Wei; Wang, Ying; Ge, Xin; Zou, Lian-Chun; Wang, Huan-Feng; Wang, Xiao-Xue; Liu, Qing-Chao; Li, Fei; Xu, Ji-Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning lithium-peroxide formation and decomposition routes with single-atom catalysts for lithium-oxygen batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-oxygen batteries with ultrahigh energy density have received considerable attention as of the future energy storage technologies. The development of effective electrocatalysts and a corresponding working mechanism during cycling are critically important for lithium-oxygen batteries. Here, a single cobalt atom electrocatalyst is synthesized for lithium-oxygen batteries by a polymer encapsulation strategy. The isolated moieties of single atom catalysts can effectively regulate the distribution of active sites to form micrometre-sized flower-like lithium peroxide and promote the decomposition of lithium peroxide by a one-electron pathway. The battery with single cobalt atoms can operate with high round-trip efficiency (86.2%) and long-term stability (218 days), which is superior to a commercial 5wt% platinum/carbon catalyst. We reveal that the synergy between a single atom and the support endows the catalyst with excellent stability and durability. The promising results provide insights into the design of highly efficient catalysts for lithium-oxygen batteries and greatly expand the scope of future investigation. Li-O-2 batteries represent one of the promising paths toward high energy density battery systems. Here the authors synthesize single atom Co electrocatalysts to regulate the formation and decomposition of the major discharge product Li2O2, realizing high round-trip efficiency and stability in a Li-O-2 cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2191, "DOI": "10.1038/s41467-020-15712-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15712-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533952200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WC; Pang, WK; Sencadas, V; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenchao; Pang, Wei Kong; Sencadas, Vitor; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding High-Energy-Density Sn4P3 Anodes for Potassium-Ion Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorus-based anodes for alkali metal-ion batteries are attractive due to their high theoretical-specific capacity. However, their poor electrochemical performance caused by relatively large volume variations during cycling, low electrical conductivity, and severe electrolyte decomposition due to highly reactive phosphide surface hinder their potential applications. Herein, we confine Sn4P3 in N-doped carbon fibers as anode for potassium-ion batteries with enhanced cycling stability and high rate capability (160.7 mA hr g(-1) after 1,000 cycles at 500 mA g(-1)). The Sn4P3 anodes undergo a sequential conversion (P to K3P11, K3P) and alloying (Sn to KSn) reactions with synergistic K-storage mechanisms. Also, the electrolyte with potassium bis(fluorosulfonyl) imide salt can effectively suppress the dendrite growth in K stripping/plating, stabilize the solid-electrolyte interphase (SEI) layer, and avoid excessive side reactions, thus enhancing the electrode stability. This work provides a feasible approach to overcome the durability bottlenecks of K-ion batteries through regulating dendrite growth and SEI formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 486, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1534, "End Page": 1547, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.022", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441627400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pappas, DK; Borfecchia, E; Dyballa, M; Pankin, IA; Lomachenko, KA; Martini, A; Signorile, M; Teketel, S; Arstad, B; Berlier, G; Lamberti, C; Bordiga, S; Olsbye, U; Lillerud, KP; Svelle, S; Beato, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pappas, Dimitrios K.; Borfecchia, Elisa; Dyballa, Michael; Pankin, Ilia A.; Lomachenko, Kirin A.; Martini, Andrea; Signorile, Matteo; Teketel, Shewangizaw; Arstad, Bjornar; Berlier, Gloria; Lamberti, Carlo; Bordiga, Silvia; Olsbye, Unni; Lillerud, Karl Petter; Svelle, Stian; Beato, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Methane to Methanol: Structure Activity Relationships for Cu-CHA", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu-exchanged zeolites possess active sites that are able to cleave the C-H bond of methane at temperatures <= 200 degrees C, enabling its selective partial oxidation to methanol. Herein we explore this process over Cu-SSZ-13 materials. We combine activity tests and X-ray absorption spectroscopy (XAS) to thoroughly investigate the influence of reaction parameters and material elemental composition on the productivity and Cu speciation during the key process steps. We find that the Cu-II moieties responsible for the conversion are formed in the presence of O-2 and that high temperature together with prolonged activation time increases the population of such active sites. We evidence a linear correlation between the reducibility of the materials and their methanol productivity. By optimizing the process conditions and material composition, we are able to reach a methanol productivity as high as 0.2 mol CH3OH/mol Cu (125 mu mol/g), the highest value reported to date for Cu-SSZ-13. Our results clearly demonstrate that high populations of 2Al Z(2)Cu(II) sites in 6r, favored at low values of both Si:Al and Cu:Al ratios, inhibit the material performance by being inactive for the conversion. Z[(CuOH)-O-II] complexes, although shown to be inactive, are identified as the precursors to the methane-converting active sites. By critical examination of the reported catalytic and spectroscopic evidence, we propose different possible routes for active-site formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 139, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14961, "End Page": 14975, "Article Number": null, "DOI": "10.1021/jacs.7b06472", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06472", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414115800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kan, SBJ; Lewis, RD; Chen, K; Arnold, FH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kan, S. B. Jennifer; Lewis, Russell D.; Chen, Kai; Arnold, Frances H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directed evolution of cytochrome c for carbon-silicon bond formation: Bringing silicon to life", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymes that catalyze carbon-silicon bond formation are unknown in nature, despite the natural abundance of both elements. Such enzymes would expand the catalytic repertoire of biology, enabling living systems to access chemical space previously only open to synthetic chemistry. We have discovered that heme proteins catalyze the formation of organosilicon compounds under physiological conditions via carbene insertion into silicon-hydrogen bonds. The reaction proceeds both in vitro and in vivo, accommodating a broad range of substrates with high chemo-and enulltioselectivity. Using directed evolution, we enhanced the catalytic function of cytochrome c from Rhodothermus marinus to achieve more than 15-fold higher turnover than state-of-the-art synthetic catalysts. This carbon-silicon bond-forming biocatalyst offers an environmentally friendly and highly efficient route to producing enulltiopure organosilicon molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2016, "Volume": 354, "Issue": 6315, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1048, "End Page": 1051, "Article Number": null, "DOI": "10.1126/science.aah6219", "DOI Link": "http://dx.doi.org/10.1126/science.aah6219", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388531800048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, JP; Fu, L; Gao, K; Duan, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Jinping; Fu, Ling; Gao, Kai; Duan, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating radical generation from peroxymonosulfate by confined variable Co species toward ciprofloxacin mineralization: ROS quantification and mechanisms elucidation", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt and oxides are the most recognized catalysts for peroxymonosulfate (PMS)-based advanced oxidation processes. However, the valence states - catalysis relations remain ambiguous. Herein, Co0/CoO/Co3O4 @K, N, O-doped carbons (Co-K-N-O-C) were synthesized via low-temperature pyrolysis. The cobalt species resulted in defective and doped carbons, and KOH facilitated the formation of low-valent Co species and carbon porosity. The synergy between Co and K facilitated peroxymonosulfate (PMS) activation and ciprofloxacin (CIP) mineralization due to enhanced electron transfer. Kinetics analysis was coupled with quenching experiments, electron paramagnetic resonullce (EPR) detection and chemical probe identification to elucidate the contributions of each reactive oxygen species. As a result, hydroxyl radical (HO center dot) dominated the degradation (-64.8 +/- 1.2%), followed by sulfate radicals (SO4 center dot , -34.2 +/- 1.1%) and singlet oxygen (1O2, <2.0%). The low-valent Co species, especially Co0, greatly promoted radical generation. This study dedicates to in-depth elucidation of PMS activation mechanisms over metal/oxides@carbon composites for purifying recalcitrant contaminullts in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2022, "Volume": 315, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121542, "DOI": "10.1016/j.apcatb.2022.121542", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2022.121542", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809949300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdel-Karim, A; Leaper, S; Alberto, M; Vijayaraghavan, A; Fan, XL; Holmes, SM; Souaya, ER; Badawy, MI; Gorgojo, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdel-Karim, Ahmed; Leaper, Sebastian; Alberto, Monica; Vijayaraghavan, Aravind; Fan, Xiaolei; Holmes, Stuart M.; Souaya, Eglal R.; Badawy, Mohamed I.; Gorgojo, Patricia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High flux and fouling resistant flat sheet polyethersulfone membranes incorporated with graphene oxide for ultrafiltration applications", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, graphene oxide (GO) was combined with polyethersulfone (PES) to form mixed matrix membranes (MMMs) for ultrafiltration of aqueous solutions. Also, the effect of adding various pore formers (poly(vinylpyrrolidinone (PVP), reverse triblock Pluronic (P31R1), and poloxamine Tetronic (T904)) to the dope solution was investigated. The prepared MMMs were characterised using various techniques, including Fourier-transform infrared spectroscopy, scanning electron microscopy and atomic force microscopy. It was found that the incorporation of 0.5 wt% of GO increased the flux from 2 to 13 L m(-2) h(-1) (LMH) and the rejection of bovine serum albumin (BSA) from 89.2 to 97% compared to benchmark PES membranes. SEM analysis revealed the increased pore size and porosity of the GO modified membranes, which contributed to the increased flux. The addition of pore formers further increased the flux compared to pure PES and also displayed synergistic effects with GO. The combination of T904 with 0.3 wt% GO increased the water flux significantly from 2 to 245 LMH and increased the rejection of acridine orange (from 40.5 to 48.4%) and BSA (from 89.6 to 93.3%), respectively. Also, fouling properties of the membranes were investigated with the parameters: flux recovery ratio (FRR), total flux decline ratio (R-t), reversible flux decline ratio (R-r), and irreversible flux decline ratio (R-ir), and improved anti-fouling properties were obtained with the addition of GO. This work shows the promise of GO as a performance- enhancing additive in MMMs for wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2018, "Volume": 334, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 789, "End Page": 799, "Article Number": null, "DOI": "10.1016/j.cej.2017.10.069", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.10.069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418533400076", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Keller, AA; Lazareva, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Keller, Arturo A.; Lazareva, Anastasiya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Predicted Releases of Engineered nullomaterials: From Global to Regional to Local", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A key question for industry, regulators, toxicologists, and risk assessors working with nullomaterials is what relevant environmental engineered nullomaterial (ENM) concentrations should be considered. Answering this question requires ENM material flow estimates at the local level. Using a life-cycle approach, global ENM production and application data were used to estimate releases at global, regional, national, and local levels. Local level emissions were then used to estimate releases to water (direct and from wastewater treatment effluent), soils (direct and from runoff and biosolids), and air (direct and from incineration of ENM-containing products). Waste management data for dozens of countries were used to estimate the flow of 10 major ENMs through eight world regions. A national and local release example was conducted with data from the United States, providing predicted wastewater effluent concentrations for the San Francisco Bay area, ranging from low nullograms per liter to micrograms per liter depending on the ENM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 651, "Times Cited, All Databases": 733, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 70, "Article Number": null, "DOI": "10.1021/ez400106t", "DOI Link": "http://dx.doi.org/10.1021/ez400106t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350830700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, C; Ma, HC; Yuan, RC; Wang, KY; Liu, K; Long, YZ; Xu, F; Li, L; Zhang, HT; Zhang, YC; Li, XY; Wu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Cheng; Ma, Huachun; Yuan, Ruichuan; Wang, Kuangyu; Liu, Kai; Long, Yuanzheng; Xu, Fei; Li, Lei; Zhang, Haitian; Zhang, Yingchuan; Li, Xiaoyan; Wu, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roll-to-roll prelithiation of lithium-ion battery anodes by transfer printing", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prelithiation can boost the performance of lithium-ion batteries (LIBs). A cost-effective prelithiation strategy with high quality and high industrial compatibility is urgently required. Herein we developed a roll-to-roll electrodeposition and transfer-printing system for continuous prelithiation of LIB anodes. By roll-to-roll calendering, pre-manufactured anodes could be fully transfer-printed onto electrodeposited lithium metal. The interface separation and adhesion during transfer printing were related to interfacial shear and compressive stress, respectively. With the facile transfer-printing prelithiation, high initial Coulombic efficiencies of 99.99% and 99.05% were achieved in graphite and silicon/carbon composite electrode half cells, respectively. The initial Coulombic efficiencies and energy densities in full cells were observed to be significantly improved with the prelithiated electrodes. The roll-to-roll transfer printing provides a high-performance, controllable, scalable and industry-adaptable prelithiation in LIBs. Prelithiation can be used to address the issue of active lithium loss during lithium-ion battery operation, but its cost effectiveness needs to be improved. Here the researchers develop a roll-to-roll electrodeposition and transfer-printing system for the production of prelithiated battery anodes with high electrochemical performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 703, "End Page": 713, "Article Number": null, "DOI": "10.1038/s41560-023-01272-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01272-1", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002480000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, TY; Bui, JC; Li, ZY; Bell, AT; Weber, AZ; Wu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Tianyu; Bui, Justin C.; Li, Zhengyuan; Bell, Alexis T.; Weber, Adam Z.; Wu, Jingjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective and productive reduction of carbon dioxide to multicarbon products via in situ CO management using segmented tandem electrodes", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction provides a promising route to the sustainable generation of valuable chemicals and fuels. Tandem catalysts enable sequential CO2-to-CO and CO-to-multicarbon (C2+) product conversions on complementary active sites, to produce high C2+ Faradaic efficiency (FE). Unfortunately, previous tandem catalysts exhibit poor management of CO intermediates, which diminishes C2+ FE. Here, we design segmented gas-diffusion electrodes (s-GDEs) in which a CO-selective catalyst layer (CL) segment at the inlet prolongs CO residence time in the subsequent C2+-selective segment, enhancing conversion. This phenomenon enables increases in both the CO utilization and C2+ current density for a Cu/Ag s-GDE compared to pure Cu, by increasing the *CO coverage within the Cu CL. Lastly, we develop a Cu/Fe-N-C s-GDE with 90% C2+ FE at C2+ partial current density (j(c2+)) exceeding 1 A cm(-2). These results prove the importance of transport and establish design principles to improve C2+ FE and j(c2+) in tandem CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 202, "End Page": 211, "Article Number": null, "DOI": "10.1038/s41929-022-00751-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00751-0", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763879400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, WJ; Peng, K; Xu, W; Liu, X; Zhang, HQ; Liang, X; Ye, BJ; Zhang, HJ; Yang, ZJ; Wu, L; Ge, XL; Xu, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Wanjie; Peng, Kang; Xu, Wei; Liu, Xiang; Zhang, Huaqing; Liang, Xian; Ye, Bangjiao; Zhang, Hongjun; Yang, Zhengjin; Wu, Liang; Ge, Xiaolin; Xu, Tongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upscaled production of an ultramicroporous anion-exchange membrane enables long-term operation in electrochemical energy devices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of highly selective yet robust anion exchange membranes remains a challenge. Here, the authors prepare a stable polymer membrane composed of terphenyl isomers, demonstrate roll-to-roll manufacturing, and assess its properties in redox flow batteries, water electrolyzers and fuel cells. The lack of high-performance and substantial supply of anion-exchange membranes is a major obstacle to future deployment of relevant electrochemical energy devices. Here, we select two isomers (m-terphenyl and p-terphenyl) and balance their ratio to prepare anion-exchange membranes with well-connected and uniformly-distributed ultramicropores based on robust chemical structures. The anion-exchange membranes display high ion-conducting, excellent barrier properties, and stability exceeding 8000 h at 80 degrees C in alkali. The assembled anion-exchange membranes present a desirable combination of performance and durability in several electrochemical energy storage devices: neutral aqueous organic redox flow batteries (energy efficiency of 77.2% at 100 mA cm(-2), with negligible permeation of redox-active molecules over 1100 h), water electrolysis (current density of 5.4 A cm(-2) at 1.8 V, 90 degrees C, with durability over 3000 h), and fuel cells (power density of 1.61 W cm(-2) under a catalyst loading of 0.2 mg cm(-2), with open-circuit voltage durability test over 1000 h). As a demonstration of upscaled production, the anion-exchange membranes achieve roll-to-roll manufacturing with a width greater than 1000 mm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2732, "DOI": "10.1038/s41467-023-38350-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38350-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000986282800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, LY; Xing, ZP; Zou, JL; Li, Z; Wu, XY; Zhang, YC; Zhu, Q; Yang, SL; Zhou, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Liyan; Xing, Zipeng; Zou, Jinlong; Li, Zhenzi; Wu, Xiaoyan; Zhang, Yuchi; Zhu, Qi; Yang, Shilin; Zhou, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black TiO2 nullobelts/g-C3N4 nullosheets Laminated Heterojunctions with Efficient Visible-Light-Driven Photocatalytic Performance", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black TiO2 nullobelts/g-C3N4 nullosheets laminated heterojunctions (b-TiO2/g-C3N4) as visible-light-driven photocatalysts are fabricated through a simple hydrothermal-calcination process and an in-situ solid-state chemical reduction approach, followed by the mild thermal treatment (350 degrees C) in argon atmosphere. The prepared samples are evidently investigated by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, N-2 adsorption, and UV-visible diffuse reflectance spectroscopy, respectively. The results show that special laminated heterojunctions are formed between black TiO2 nullobelts and g-C3N4 nullosheets, which favor the separation of photogenerated electron-hole pairs. Furthermore, the presence of Ti3+ and g-C3N4 greatly enhance the absorption of visible light. The resultant b-TiO2/g-C3N4 materials exhibit higher photocatalytic activity than that of g-C3N4, TiO2, b-TiO2 and TiO2/g-C3N4 for degradation of methyl orange (95%) and hydrogen evolution (555.8 mu mol h(-1) g(-1)) under visible light irradiation. The apparent reaction rate constant (k) of b-TiO2/g-C3N4 is similar to 9 times higher than that of pristine TiO2. Therefore, the high-efficient laminated heterojunction composites will have potential applications in fields of environment and energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41978, "DOI": "10.1038/srep41978", "DOI Link": "http://dx.doi.org/10.1038/srep41978", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393372300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XM; Liu, N; Schmuki, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xuemei; Liu, Ning; Schmuki, Patrik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalysis with TiO2 nullotubes: Colorful Reactivity and Designing Site-Specific Photocatalytic Centers into TiO2 nullotubes", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reactions on TiO2 have recently gained an enormous resurgence because of various new strategies and findings that promise to drastically increase efficiency and specificity of such reactions by modifications of the titania scaffold and chemistry. In view of geometry, in particular, anodic TiO2 nullotubes have attracted wide interest, as they allow a high degree of control over the separation of photogenerated charge carriers not only in photocatalytic reactions but also in photoelectrochemical reactions. A key advantage of ordered nullotube arrays is that nullotube modifications can be embedded site specifically into the tube wall; that is, cocatalysts, doping species, or junctions can be placed at highly defined desired locations (or with a desired regular geometry or pattern) along the tube wall. This allows an unprecedented level of engineering of energetics of reaction sites for catalytic and photocatalytic reactions, which target not only higher efficiencies but also the selectivity of reactions. Many recent tube alterations are of a morphologic nature (mesoporous structures, designed faceted crystallites, hybrids, or 1D structures), but a number of color-coded (namely, black, blue, red, green, gray) modifications have attracted wide interest because of the extension of the light absorption spectrum of titania in the visible range and because unique catalytic activity can be induced. The present Perspective gives an overview of TiO2 nullotubes in photocatalysis with an emphasis on the most recent advances in the use of nullotube arrays and discusses the underlying concepts in tailoring their photocatalytic reactivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3210, "End Page": 3235, "Article Number": null, "DOI": "10.1021/acscatal.6b03709", "DOI Link": "http://dx.doi.org/10.1021/acscatal.6b03709", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401054300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YH; Akin, S; Hinderhofer, A; Eickemeyer, FT; Zhu, HW; Seo, JY; Zhang, JH; Schreiber, F; Zhang, H; Zakeeruddin, SM; Hagfeldt, A; Dar, MI; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuhang; Akin, Seckin; Hinderhofer, Alexander; Eickemeyer, Felix T.; Zhu, Hongwei; Seo, Ji-Youn; Zhang, Jiahuan; Schreiber, Frank; Zhang, Hong; Zakeeruddin, Shaik M.; Hagfeldt, Anders; Dar, M. Ibrahim; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilization of Highly Efficient and Stable Phase-Pure FAPbI3Perovskite Solar Cells by Molecularly Tailored 2D-Overlayers", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a result of their attractive optoelectronic properties, metal halide APbI(3)perovskites employing formamidinium (FA(+)) as the A cation are the focus of research. The superior chemical and thermal stability of FA(+)cations makes alpha-FAPbI(3)more suitable for solar-cell applications than methylammonium lead iodide (MAPbI(3)). However, its spontaneous conversion into the yellow non-perovskite phase (delta-FAPbI(3)) under ambient conditions poses a serious challenge for practical applications. Herein, we report on the stabilization of the desired alpha-FAPbI(3)perovskite phase by protecting it with a two-dimensional (2D) IBA(2)FAPb(2)I(7)(IBA=iso-butylammonium overlayer, formed via stepwise annealing. The alpha-FAPbI(3)/IBA(2)FAPb(2)I(7)based perovskite solar cell (PSC) reached a high power conversion efficiency (PCE) of close to 23 %. In addition, it showed excellent operational stability, retaining around 85 % of its initial efficiency under severe combined heat and light stress, that is, simultaneous exposure with maximum power tracking to full simulated sunlight at 80 degrees C over 500 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2020, "Volume": 59, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15688, "End Page": 15694, "Article Number": null, "DOI": "10.1002/anie.202005211", "DOI Link": "http://dx.doi.org/10.1002/anie.202005211", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541488400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WJ; Pan, YY; Yao, L; Liu, HC; Zhang, ST; Wang, C; Shen, FZ; Lu, P; Yang, B; Ma, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Weijun; Pan, Yuyu; Yao, Liang; Liu, Haichao; Zhang, Shitong; Wang, Chu; Shen, Fangzhong; Lu, Ping; Yang, Bing; Ma, Yuguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Hybridized Local and Charge-Transfer Excited State for Highly Efficient Fluorescent OLEDs: Molecular Design, Spectral Character, and Full Exciton Utilization", "Source Title": "ADVANCED OPTICAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For a donor-acceptor (D-A) molecule, there are three possible cases for its low-lying excited state (S-1): a pi-pi* state (a localized electronic state), a charge-transfer (CT) state (a delocalized electronic state), and a mixed or hybridized state of pi-pi* and CT (named here as the hybridized local and charge transfer (HLCT) state). The HLCT state is an important excited state for the design of next-generation organic light-emitting diode (OLED) materials with both high photoluminescence (PL) efficiency and a large fraction of singlet exciton generation in electroluminescence (EL). According to the principle of state mixing in quantum chemistry, a series of twisting D-A molecules are designed and synthesized, and their HLCT state characters are verified by both fluorescent solvatochromic experiments and quantum chemical calculations. The CT components in the HLCT state, which greatly affect the molecular optical properties, are found to be enhanced with a decrease of the twist angle of the D-A segment or an increase of the D-A intensity in these twisting D-A molecules. In OLEDs, using these HLCT compounds as the emitting layer, the maximum exciton utilization efficiency is harvested up to 93%. Surprisingly, an exception of Kasha's rule is revealed in some HLCT compounds: restricted internal-conversion (IC) from the high-lying triplet state (T-2) to the low-lying triplet T-1, and a reopened path of reverse intersystem crossing (RISC) from T-2 to S-1 or S-2, based on the analysis of the excited-state energy levels and the measurement of the low-temperature spectrum. RISC from T-2 to S-1 (S-2) as a hot exciton channel is believed to contribute to the large proportion of the radiative singlet excitons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 892, "End Page": 901, "Article Number": null, "DOI": "10.1002/adom.201400154", "DOI Link": "http://dx.doi.org/10.1002/adom.201400154", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344171800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, QH; Gao, Y; Pu, J; Zhao, X; Wang, YX; Chen, JP; Guan, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Qinghe; Gao, Yong; Pu, Jie; Zhao, Xin; Wang, Yuxuan; Chen, Jipeng; Guan, Cao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient design of imprinted anode for stable Zn-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc metal anodes suffer from electrolyte corrosion and dendrite growth issues during electrochemical cycling. Here, the authors propose a gradient design to imprint the zinc anode, which both prohibits side reactions and alleviates zinc deposition behaviour. Achieving long-term stable zinc anodes at high currents/capacities remains a great challenge for practical rechargeable zinc-ion batteries. Herein, we report an imprinted gradient zinc electrode that integrates gradient conductivity and hydrophilicity for long-term dendrite-free zinc-ion batteries. The gradient design not only effectively prohibits side reactions between the electrolyte and the zinc anode, but also synergistically optimizes electric field distribution, zinc ion flux and local current density, which induces preferentially deposited zinc in the bottom of the microchannels and suppresses dendrite growth even under high current densities/capacities. As a result, the imprinted gradient zinc anode can be stably cycled for 200 h at a high current density/capacity of 10 mA cm(-2)/10 mAh cm(-2), with a high cumulative capacity of 1000 mAh cm(-2), which outperforms the none-gradient counterparts and bare zinc. The imprinted gradient design can be easily scaled up, and a high-performance large-area pouch cell (4*5 cm(2)) is also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-36386-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36386-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954587000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, Z; Maassen, J; Deng, YX; Du, YC; Garrelts, RP; Lundstrom, MS; Ye, PD; Xu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhe; Maassen, Jesse; Deng, Yexin; Du, Yuchen; Garrelts, Richard P.; Lundstrom, Mark S.; Ye, Peide D.; Xu, Xianfan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic in-plane thermal conductivity observed in few-layer black phosphorus", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus has been revisited recently as a new two-dimensional material showing potential applications in electronics and optoelectronics. Here we report the anisotropic in-plane thermal conductivity of suspended few-layer black phosphorus measured by micro-Raman spectroscopy. The armchair and zigzag thermal conductivities are similar to 20 and similar to 40 Wm(-1) K-1 for black phosphorus films thicker than 15 nm, respectively, and decrease to similar to 10 and similar to 20 W m(-1) K-1 as the film thickness is reduced, exhibiting significant anisotropy. The thermal conductivity anisotropic ratio is found to be similar to 2 for thick black phosphorus films and drops to similar to 1.5 for the thinnest 9.5-nm-thick film. Theoretical modelling reveals that the observed anisotropy is primarily related to the anisotropic phonon dispersion, whereas the intrinsic phonon scattering rates are found to be similar along the armchair and zigzag directions. Surface scattering in the black phosphorus films is shown to strongly suppress the contribution of long mean-free-path acoustic phonons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8572, "DOI": "10.1038/ncomms9572", "DOI Link": "http://dx.doi.org/10.1038/ncomms9572", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364932600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sánchez-Díez, E; Ventosa, E; Guarnieri, M; Trovò, A; Flox, C; Marcilla, R; Soavi, F; Mazur, P; Aranzabe, E; Ferret, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sanchez-Diez, Eduardo; Ventosa, Edgar; Guarnieri, Massimo; Trovo, Andrea; Flox, Cristina; Marcilla, Rebeca; Soavi, Francesca; Mazur, Petr; Aranzabe, Estibaliz; Ferret, Raquel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox flow batteries: Status and perspective towards sustainable stationary energy storage", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Redox-flow batteries, based on their particular ability to decouple power and energy, stand as prime candidates for cost-effective stationary storage, particularly in the case of long discharges and long storage times. Integration of renewables and subsequent need for energy storage is promoting effort on the development of mature and emerging redox-flow technologies. This review aims at providing a critical analysis of redox-flow technologies that can potentially fulfill cost requirements and enable large scale storage, mainly aqueous based systems. A comprehensive overview of the status of those technologies, including advantages and weaknesses, is presented. Compiled data on the market permeability, performance and cost should serve, together with the perspective included, to understand the different strategies to reach the successful implementation, from component development to innovative designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 481, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 228804, "DOI": "10.1016/j.jpowsour.2020.228804", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2020.228804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000593860600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jaramillo-Fernulldez, J; Yang, H; Schertel, L; Whitworth, GL; Garcia, PD; Vignolini, S; Sotomayor-Torres, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jaramillo-Fernulldez, Juliana; Yang, Han; Schertel, Lukas; Whitworth, Guy L.; Garcia, Pedro D.; Vignolini, Silvia; Sotomayor-Torres, Clivia M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly-Scattering Cellulose-Based Films for Radiative Cooling", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive radiative cooling (RC) enables the cooling of objects below ambient temperature during daytime without consuming energy, promising to be a game changer in terms of energy savings and CO2 reduction. However, so far most RC surfaces are obtained by energy-intensive nullofabrication processes or make use of unsustainable materials. These limitations are overcome by developing cellulose films with unprecedentedly low absorption of solar irradiance and strong mid-infrared (mid-IR) emittance. In particular, a cellulose-derivative (cellulose acetate) is exploited to produce porous scattering films of two different thicknesses, L approximate to 30 mu m (thin) and L approximate to 300 mu m (thick), making them adaptable to above and below-ambient cooling applications. The thin and thick films absorb only approximate to 5%${\\approx}5\\%$ of the solar irradiance, which represents a net cooling power gain of at least 17 W m(-2), compared to state-of-the-art cellulose-based radiative-cooling materials. Field tests show that the films can reach up to approximate to 5 degrees C below ambient temperature, when solar absorption and conductive/convective losses are minimized. Under dryer conditions (water column = 1 mm), it is estimated that the films can reach average minimum temperatures of approximate to 7-8 degrees C below the ambient. The work presents an alternative cellulose-based material for efficient radiative cooling that is simple to fabricate, cost-efficient and avoids the use of polluting materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104758, "DOI": "10.1002/advs.202104758", "DOI Link": "http://dx.doi.org/10.1002/advs.202104758", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000743189200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, J; Hu, F; Liu, Y; Witherell, P; Wang, CCL; Rosen, DW; Simpson, TW; Lu, Y; Tang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Jian; Hu, Fu; Liu, Ying; Witherell, Paul; Wang, Charlie C. L.; Rosen, David W.; Simpson, Timothy W.; Lu, Yan; Tang, Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research and application of machine learning for additive manufacturing", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) is poised to bring a revolution due to its unique production paradigm. It offers the prospect of mass customization, flexible production, on-demand and decentralized manufacturing. However, a number of challenges stem from not only the complexity of manufacturing systems but the demand for increasingly complex and high-quality products, in terms of design principles, standardization and quality control. These challenges build up barriers to the widespread adoption of AM in the industry and the in-depth research of AM in academia. To tackle the challenges, machine learning (ML) technologies rise to play a critical role as they are able to provide effective ways to quality control, process optimization, modelling of complex systems, and energy management. Hence, this paper employs a systematic literature review method as it is a defined and methodical way of identifying, assessing, and analysing published literature. Then, a keyword co occurrence and cluster analysis are employed for analysing relevant literature. Several aspects of AM, including Design for AM (DfAM), material analytics, in situ monitoring and defect detection, property prediction and sustainability, have been clustered and summarized to present state-of-the-art research in the scope of ML for AM. Finally, the challenges and opportunities of ML for AM are uncovered and discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 52, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102691, "DOI": "10.1016/j.addma.2022.102691", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2022.102691", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798159500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, MJ; Xiao, P; Lang, JW; Yan, C; Yan, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Minjie; Xiao, Peng; Lang, Junwei; Yan, Chao; Yan, Xingbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous g-C3N4 and MXene Dual-Confined FeOOH Quantum Dots for Superior Energy Storage in an Ionic Liquid", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to their unique nullosize effect and surface effect, pseudocapacitive quantum dots (QDs) hold considerable potential for high-efficiency supercapacitors (SCs). However, their pseudocapacitive behavior is exploited in aqueous electrolytes with narrow potential windows, thereby leading to a low energy density of the SCs. Here, a film electrode based on dual-confined FeOOH QDs (FQDs) with superior pseudocapacitive behavior in a high-voltage ionic liquid (IL) electrolyte is put forward. In such a film electrode, FQDs are steadily dual-confined in a 2D heterogeneous nullospace supported by graphite carbon nitride (g-C3N4) and Ti-MXene (Ti3C2). Probing of potential-driven ion accumulation elucidates that strong adsorption occurs between the IL cation and the electrode surface with abundant active sites, providing sufficient redox reaction of FQDs in the film electrode. Furthermore, porous g-C3N4 and conductive Ti3C2 act as ion-accessible channels and charge-transfer pathways, respectively, endowing the FQDs-based film electrode with favorable electrochemical kinetics in the IL electrolyte. A high-voltage flexible SC (FSC) based on an ionogel electrolyte is fabricated, exhibiting a high energy density (77.12 mWh cm(-3)), a high power density, a remarkable rate capability, and long-term durability. Such an FSC can also be charged by harvesting sustainable energy and can effectively power various wearable and portable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901975, "DOI": "10.1002/advs.201901975", "DOI Link": "http://dx.doi.org/10.1002/advs.201901975", "Book DOI": null, "Early Access Date": "NOV 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498628900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZL; Yoon, G; Park, KY; Park, H; Tamwattana, O; Kim, SJ; Seong, WM; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zheng-Long; Yoon, Gabin; Park, Kyu-Young; Park, Hyeokjun; Tamwattana, Orapa; Kim, Sung Joo; Seong, Won Mo; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring sodium intercalation in graphite for high energy and power sodium ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Co-intercalation reactions make graphite as promising anodes for sodium ion batteries, however, the high redox potentials significantly lower the energy density. Herein, we investigate the factors that influence the co-intercalation potential of graphite and find that the tuning of the voltage as large as 0.38 V is achievable by adjusting the relative stability of ternary graphite intercalation compounds and the solvent activity in electrolytes. The feasibility of graphite anode in sodium ion batteries is confirmed in conjunction with Na1.5V-PO4.8F0.7 cathodes by using the optimal electrolyte. The sodium ion battery delivers an improved voltage of 3.1 V, a high power density of 3863 W kg(-1) (both electrodes), negligible temperature dependency of energy/power densities and an extremely low capacity fading rate of 0.007% per cycle over 1000 cycles, which are among the best thus far reported for sodium ion full cells, making it a competitive choice in large-scale energy storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2598, "DOI": "10.1038/s41467-019-10551-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10551-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471227300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HY; Hu, JS; Wei, XJ; Zhang, KQ; Xiao, X; Zhao, JX; Hu, Q; Yu, J; Zhou, GM; Xu, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Hongyu; Hu, Jisong; Wei, Xijun; Zhang, Kaiqi; Xiao, Xiao; Zhao, Jingxin; Hu, Qiang; Yu, Jing; Zhou, Guangmin; Xu, Bingang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A recyclable biomass electrolyte towards green zinc-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The operation of traditional aqueous-electrolyte zinc-ion batteries is adversely affected by the uncontrollable growth of zinc dendrites and the occurrence of side reactions. These problems can be avoided by the development of functional hydrogel electrolytes as replacements for aqueous electrolytes. However, the mechanism by which most hydrogel electrolytes inhibit the growth of zinc dendrites on a zinc anode has not been investigated in detail, and there is a lack of a large-scale recovery method for mainstream hydrogel electrolytes. In this paper, we describe the development of a recyclable and biodegradable hydrogel electrolyte based on natural biomaterials, namely chitosan and polyaspartic acid. The distinctive adsorptivity and inducibility of chitosan and polyaspartic acid in the hydrogel electrolyte triggers a double coupling network and an associated synergistic inhibition mechanism, thereby effectively inhibiting the side reactions on the zinc anode. In addition, this hydrogel electrolyte played a crucial role in an aqueous acid-based Zinc/MnO2 battery, by maintaining its interior two-electron redox reaction and inhibiting the formation of zinc dendrites. Furthermore, the sustainable biomass-based hydrogel electrolyte is biodegradable, and could be recovered from the Zinc/MnO2 battery for subsequent recycling. Functional hydrogel electrolytes show promising potential for enhancing the sustainability of aqueous zinc-ion batteries. Here, the authors introduce a biomass-based hydrogel electrolyte that not only prevents side reactions on the zinc anode but also enables easy retrieval from the zinc batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4435, "DOI": "10.1038/s41467-023-40178-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40178-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001090909700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YC; Zhang, Y; Wu, HD; Wen, J; Zhang, S; Xing, WQ; Zhang, HC; Xue, HG; Gao, JF; Mai, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yongchuan; Zhang, Ya; Wu, Haidi; Wen, Jing; Zhang, Shu; Xing, Wenqian; Zhang, Hechuan; Xue, Huaiguo; Gao, Jiefeng; Mai, Yiuwing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent-Exchange-Assisted Wet Annealing: A New Strategy for Superstrong, Tough, Stretchable, and Anti-Fatigue Hydrogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are widely used in tissue engineering, soft robots, wearable electronics, etc. However, it remains a great challenge to develop hydrogels possessing simultaneously high strength, large stretchability, great fracture energy, and good fatigue threshold to suit different applications. Herein, a novel solvent-exchange-assisted wet-annealing strategy is proposed to prepare high performance poly(vinyl alcohol) hydrogels by extensively tuning the macromolecular chain movement and optimizing the polymer network. The reinforcing and toughening mechanisms are found to be macromolecule crystallization and entanglement. These hydrogels have large tensile strengths up to 11.19 +/- 0.27 MPa and extremely high fracture strains of 1879 +/- 10%. In addition, the fracture energy and fatigue threshold can reach as high as 25.39 +/- 6.64 kJ m(-2) and approximate to 1233 J m(-2), respectively. These superb mechanical properties compare favorably to those of other tough hydrogels, organogels, and even natural tendons and synthetic rubbers. This work provides a new and effective method to fabricate superstrong, tough, stretchable, and anti-fatigue hydrogels with potential applications in artificial tendons and ligaments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202210624", "DOI Link": "http://dx.doi.org/10.1002/adma.202210624", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000943749400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palmstrom, AF; Eperon, GE; Leijtens, T; Prasanna, R; Habisreutinger, SN; Nemeth, W; Gaulding, EA; Dunfield, SP; Reese, M; nullayakkara, S; Moot, T; Werner, J; Liu, J; To, B; Christensen, ST; McGehee, MD; van Hest, MFAM; Luther, JM; Berry, JJ; Moore, DT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palmstrom, Axel F.; Eperon, Giles E.; Leijtens, Tomas; Prasanna, Rohit; Habisreutinger, Severin N.; Nemeth, William; Gaulding, E. Ashley; Dunfield, Sean P.; Reese, Matthew; nullayakkara, Sanjini; Moot, Taylor; Werner, Jeremie; Liu, Jun; To, Bobby; Christensen, Steven T.; McGehee, Michael D.; van Hest, Maikel F. A. M.; Luther, Joseph M.; Berry, Joseph J.; Moore, David T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling Flexible All-Perovskite Tandem Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multijunction all-perovskite solar cells offer a route toward efficiencies of III-V materials at low cost by combining the advantages of low thermalization loss in multijunction architectures with the beneficial properties of perovskitesnamely, low processing cost, high-throughput fabrication, and compatibility with flexible substrates. However, there are two main challenges for enabling high-efficiency tandems: (1) design of a recombination layer to efficiently combine two perovskite subcells while also preventing bottom cell damage during top cell processing and (2) achieving high open-circuit voltage of the widegap subcell. Herein, we overcome both of these challenges. First, we demonstrate a nucleation layer consisting of an ultra-thin polymer with nucleophilic hydroxyl and amine functional groups for nucleating a conformal, low-conductivity aluminum zinc oxide layer by atomic layer deposition (ALD). This method enables ALD-grown recombination layers that reduce shunting as well as solvent degradation from solution processing on top of existing perovskite active layers. Next, we demonstrate a band-gap tuning strategy based on A-site cations of mismatched size (dimethylammonium and cesium) to enable a 1.7 eV perovskite with high, stable voltages. By combining these advances, we fabricate two-terminal all-perovskite tandem solar cells with 23.1% power conversion efficiency on rigid substrates and 21.3% on flexible plastic substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2019, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2193, "End Page": 2204, "Article Number": null, "DOI": "10.1016/j.joule.2019.05.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.05.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486444700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YR; Katayama, Y; Tatara, R; Giordano, L; Yu, Y; Fraggedakis, D; Sun, JGW; Maglia, F; Jung, R; Bazant, MZ; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yirui; Katayama, Yu; Tatara, Ryoichi; Giordano, Livia; Yu, Yang; Fraggedakis, Dimitrios; Sun, Jame Guangwen; Maglia, Filippo; Jung, Roland; Bazant, Martin Z.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding (electro-)chemical reactions at the electrode-electrolyte interface (EEI) is crucial to promote the cycle life of lithium-ion batteries. In this study, we developed an in situ Fourier-transform infrared spectroscopy (FT-IR) method, which provided unprecedented information on the oxidation of carbonate solvents via dehydrogenation on LiNixMnyCo1-x-yO2 (NMC). While ethylene carbonate (EC) was stable against oxidation on Pt up to 4.8 V-Li, unique evidence for dehydrogenation of EC on LiNi0.8Co0.1Mn0.1O2 (NMC811) at voltages as low as 3.8 V-Li was revealed by in situ FT-IR measurements, which was supported by density functional theory (DFT) results. Unique dehydrogenated species from EC were observed on NMC811 surface, including dehydrogenated EC anchored on oxides, vinylene carbonate (VC) and dehydrogenated oligomers which could diffuse away from the surface. Similar dehydrogenation on NMC811 was noted for EMC-based and LP57 (1 M LiPF6 in 3 : 7 EC/EMC) electrolytes. In contrast, no dehydrogenation was found for NMC111 or surface-modified NMC by coatings such as Al2O3. In addition, while the dehydrogenation of solvents was observed in 1 M electrolytes with different anions, they were not observed on NMC811 in the concentrated electrolyte (EC/EMC with 3.1 M LiPF6), indicating lithium coordination could suppress dehydrogenation. Dehydrogenation of carbonates on NMC811 accompanied with rapid growth of interfacial impedance with increasing voltage revealed by electrochemical impedance spectroscopy (EIS), while the electrode-electrolyte combinations without dehydrogenation did not show significant impedance growth. Therefore, minimizing carbonate dehydrogenation on the NMC surface by tuning electrode reactivity and electrolyte reactivity is critical to develop high-energy Li-ion batteries with long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 183, "End Page": 199, "Article Number": null, "DOI": "10.1039/c9ee02543j", "DOI Link": "http://dx.doi.org/10.1039/c9ee02543j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508857600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JQ; Wu, BH; Wei, P; Sun, ST; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiqiang; Wu, Baohu; Wei, Peng; Sun, Shengtong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fatigue-free artificial ionic skin toughened by self-healable elastic nullomesh", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing robust skin-like sensing materials is essential for soft electronics and robotics with extended service life. Here, inspired by the repairable nullofibrous structure of human skin, the authors engineer a fatigue-resistant artificial ionic skin toughened by self-healable elastic nullomesh. Robust ionic sensing materials that are both fatigue-resistant and self-healable like human skin are essential for soft electronics and robotics with extended service life. However, most existing self-healable artificial ionic skins produced on the basis of network reconfiguration suffer from a low fatigue threshold due to the easy fracture of low-energy amorphous polymer chains with susceptible crack propagation. Here we engineer a fatigue-free yet fully healable hybrid ionic skin toughened by a high-energy, self-healable elastic nullomesh, resembling the repairable nullofibrous interwoven structure of human skin. Such a design affords a superhigh fatigue threshold of 2950 J m(-2) while maintaining skin-like compliance, stretchability, and strain-adaptive stiffening response. Moreover, nullofiber tension-induced moisture breathing of ionic matrix leads to a record-high strain-sensing gauge factor of 66.8, far exceeding previous intrinsically stretchable ionic conductors. This concept creates opportunities for designing durable ion-conducting materials that replicate the unparalleled combinatory properties of natural skins more precisely.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4411, "DOI": "10.1038/s41467-022-32140-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32140-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000840832000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Chu, XY; Zhang, HY; Zhang, R; Liu, YH; Zhang, FM; Lu, M; Yang, ZD; Lan, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yan; Chu, Xiaoyu; Zhang, Hong-Yu; Zhang, Rui; Liu, Yu-Han; Zhang, Feng-Ming; Lu, Meng; Yang, Zhao-Di; Lan, Ya-Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering β-ketoamine covalent organic frameworks for photocatalytic overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are an emerging type of crystalline and porous photocatalysts for hydrogen evolution. Here, the authors report a beta-ketoamine COF by systematically engineering N-sites, architecture, and morphology for improved water splitting activity. Covalent organic frameworks (COFs) are an emerging type of crystalline and porous photocatalysts for hydrogen evolution, however, the overall water splitting activity of COFs is rarely known. In this work, we firstly realized overall water splitting activity of beta-ketoamine COFs by systematically engineering N-sites, architecture, and morphology. By in situ incorporating sub-nullometer platinum (Pt) nulloparticles co-catalyst into the pores of COFs nullosheets, both Pt@TpBpy-NS and Pt@TpBpy-2-NS show visible-light-driven overall water splitting activity, with the optimal H-2 and O-2 evolution activities of 9.9 and 4.8 mu mol in 5 h for Pt@TpBpy-NS, respectively, and a maximum solar-to-hydrogen efficiency of 0.23%. The crucial factors affecting the activity including N-sites position, nullo morphology, and co-catalyst distribution were systematically explored. Further mechanism investigation reveals the tiny diversity of N sites in COFs that induces great differences in electron transfer as well as reaction potential barriers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 593, "DOI": "10.1038/s41467-023-36338-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36338-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, R; Mei, X; Yan, DP; Liang, RZ; Wei, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Rui; Mei, Xuan; Yan, Dongpeng; Liang, Ruizheng; Wei, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-photosensitizer based on layered double hydroxide and isophthalic acid for singlet oxygenation and photodynamic therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Singlet oxygen has won a great deal of attention to catalysis and biological studies due to its strong oxidizing properties. However, the photosensitizers which require for the generation of singlet oxygen remain inadequate because of their lack of long-wavelength absorption, weak hydrophilicity, and poor biocompatibility. Here, we develop near-infrared laser activated supramolecular photosensitizers (isophthalic acid/layered double hydroxide nullohybrids) for efficient two-photon photodynamic therapy. The singlet oxygen quantum yield of nullohybrid is up to 0.74. Critically, in vitro tests verify the superior anti-cancer properties of nullohybrid with an IC50 determine to be 0.153 mu gmL(-1). The nullohybrids take advantage of the superior tissue penetration of 808 nm laser irradiation and exhibit a dramatically strong ability to ablate tumors in vivo, with extremely low toxicity. This work provides the proof of concept that ultralong-lived triplet excitons can function as two-photon-activated photosensitizers for an effective singlet oxygen generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2798, "DOI": "10.1038/s41467-018-05223-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05223-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439030100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, XY; Ge, LL; Liu, C; Tang, ZM; Xiao, YF; Chen, W; Lei, ZY; Gao, W; Blake, S; De, DB; Shi, BY; Zeng, XB; Kong, N; Zhang, XC; Tao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Xiaoyuan; Ge, Lanlan; Liu, Chuang; Tang, Zhongmin; Xiao, Yufen; Chen, Wei; Lei, Zhouyue; Gao, Wei; Blake, Sara; De, Diba; Shi, Bingyang; Zeng, Xiaobing; Kong, Na; Zhang, Xingcai; Tao, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capturing functional two-dimensional nullosheets from sandwich-structure vermiculite for cancer theranostics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Clay-based nullomaterials, especially 2:1 aluminosilicates such as vermiculite, biotite, and illite, have demonstrated great potential in various fields. However, their characteristic sandwiched structures and the lack of effective methods to exfoliate two-dimensional (2D) functional core layers (FCLs) greatly limit their future applications. Herein, we present a universal wet-chemical exfoliation method based on alkali etching that can intelligently capture the ultrathin and biocompatible FCLs (MgO and Fe2O3) sandwiched between two identical tetrahedral layers (SiO2 and Al2O3) from vermiculite. Without the sandwich structures that shielded their active sites, the obtained FCL nullosheets (NSs) exhibit a tunable and appropriate electron band structure (with the bandgap decreased from 2.0eV to 1.4eV), a conductive band that increased from -0.4eV to -0.6eV, and excellent light response characteristics. The great properties of 2D FCL NSs endow them with exciting potential in diverse applications including energy, photocatalysis, and biomedical engineering. This study specifically highlights their application in cancer theranostics as an example, potentially serving as a prelude to future extensive studies of 2D FCL NSs. Clay-based nullomaterials are of wide interest but problems extracting the 2D functional core layers have limited potential applications. Here, the authors report on the wet exfoliation of vermiculite by alkali etching to obtain the core layers and explore the application of the materials in cancer theranostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1124, "DOI": "10.1038/s41467-021-21436-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21436-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621425100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CT; Gu, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chun-Teh; Gu, Grace X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generative Deep Neural Networks for Inverse Materials Design Using Backpropagation and Active Learning", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, machine learning (ML) techniques are seen to be promising tools to discover and design novel materials. However, the lack of robust inverse design approaches to identify promising candidate materials without exploring the entire design space causes a fundamental bottleneck. A general-purpose inverse design approach is presented using generative inverse design networks. This ML-based inverse design approach uses backpropagation to calculate the analytical gradients of an objective function with respect to design variables. This inverse design approach is capable of overcoming local minima traps by using backpropagation to provide rapid calculations of gradient information and running millions of optimizations with different initial values. Furthermore, an active learning strategy is adopted in the inverse design approach to improve the performance of candidate materials and reduce the amount of training data needed to do so. Compared to passive learning, the active learning strategy is capable of generating better designs and reducing the amount of training data by at least an order-of-magnitude in the case study on composite materials. The inverse design approach is compared with conventional gradient-based topology optimization and gradient-free genetic algorithms and the pros and cons of each method are discussed when applied to materials discovery and design problems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902607, "DOI": "10.1002/advs.201902607", "DOI Link": "http://dx.doi.org/10.1002/advs.201902607", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506258900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, BH; Wang, XY; Ye, ZQ; Zhang, JY; Chen, X; Zhou, NL; Zhang, M; Yao, C; Wu, F; Shen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Baohong; Wang, Xinye; Ye, Ziqiu; Zhang, Juyang; Chen, Xiong; Zhou, Ninglin; Zhang, Ming; Yao, Cheng; Wu, Fan; Shen, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Single-Atom Active Sites on sp2-Carbon Linked Covalent Organic Frameworks to Induce Bacterial Ferroptosis-Like for Robust Anti-Infection Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the threat posed by drug-resistant pathogenic bacteria, developing non-antibiotic strategies for eradicating clinically prevalent superbugs remains challenging. Ferroptosis is a newly discovered form of regulated cell death that can overcome drug resistance. Emerging evidence shows the potential of triggering ferroptosis-like for antibacterial therapy, but the direct delivery of iron species is inefficient and may cause detrimental effects. Herein, an effective strategy to induce bacterial nonferrous ferroptosis-like by coordinating single-atom metal sites (e.g., Ir and Ru) into the sp(2)-carbon-linked covalent organic framework (sp(2)c-COF-Ir-ppy(2) and sp(2)c-COF-Ru-bpy(2)) is reported. Upon activating by light irradiation or hydrogen peroxide, the as-constructed Ir and Ru single-atom catalysts (SACs) can significantly expedite intracellular reactive oxygen species burst, enhance glutathione depletion-related glutathione peroxidase 4 deactivation, and disturb the nitrogen and respiratory metabolisms, leading to lipid peroxidation-driven ferroptotic damage. Both SAC inducers show potent antibacterial activity against Gram-positive bacteria, Gram-negative bacteria, clinically isolated methicillin-resistant Staphylococcus aureus (MRSA), and biofilms, as well as excellent biocompatibility and strong therapeutic and preventive potential in MRSA-infected wounds and abscesses. This delicate nonferrous ferroptosis-like strategy may open up new insights into the therapy of drug-resistant pathogen infection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207507", "DOI Link": "http://dx.doi.org/10.1002/advs.202207507", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939689700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, XC; Chen, XL; Liu, HM; Feng, YQ; Wei, ZX; Zhou, YH; Chi, ZH; Pi, L; Yen, F; Song, FQ; Wan, XG; Yang, ZR; Wang, BG; Wang, GH; Zhang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Xing-Chen; Chen, Xuliang; Liu, Huimei; Feng, Yanqing; Wei, Zhongxia; Zhou, Yonghui; Chi, Zhenhua; Pi, Li; Yen, Fei; Song, Fengqi; Wan, Xiangang; Yang, Zhaorong; Wang, Baigeng; Wang, Guanghou; Zhang, Yuheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-driven dome-shaped superconductivity and electronic structural evolution in tungsten ditelluride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tungsten ditelluride has attracted intense research interest due to the recent discovery of its large unsaturated magnetoresistance up to 60 T. Motivated by the presence of a small, sensitive Fermi surface of 5d electronic orbitals, we boost the electronic properties by applying a high pressure, and introduce superconductivity successfully. Superconductivity sharply appears at a pressure of 2.5 GPa, rapidly reaching a maximum critical temperature (T-c) of 7 K at around 16.8 GPa, followed by a monotonic decrease in T-c with increasing pressure, thereby exhibiting the typical dome-shaped superconducting phase. From theoretical calculations, we interpret the low-pressure region of the superconducting dome to an enrichment of the density of states at the Fermi level and attribute the high-pressure decrease in T-c to possible structural instability. Thus, tungsten ditelluride may provide a new platform for our understanding of superconductivity phenomena in transition metal dichalcogenides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7805, "DOI": "10.1038/ncomms8805", "DOI Link": "http://dx.doi.org/10.1038/ncomms8805", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358860100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YW; Stocks, GM; Jin, K; Lu, CY; Bei, HB; Sales, BC; Wang, LM; Béland, LK; Stoller, RE; Samolyuk, GD; Caro, M; Caro, A; Weber, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yanwen; Stocks, G. Malcolm; Jin, Ke; Lu, Chenyang; Bei, Hongbin; Sales, Brian C.; Wang, Lumin; Beland, Laurent K.; Stoller, Roger E.; Samolyuk, German D.; Caro, Magdalena; Caro, Alfredo; Weber, William J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A grand challenge in materials research is to understand complex electronic correlation and non-equilibrium atomic interactions, and how such intrinsic properties and dynamic processes affect energy transfer and defect evolution in irradiated materials. Here we report that chemical disorder, with an increasing number of principal elements and/or altered concentrations of specific elements, in single-phase concentrated solid solution alloys can lead to substantial reduction in electron mean free path and orders of magnitude decrease in electrical and thermal conductivity. The subsequently slow energy dissipation affects defect dynamics at the early stages, and consequentially may result in less deleterious defects. Suppressed damage accumulation with increasing chemical disorder from pure nickel to binary and to more complex quaternary solid solutions is observed. Understanding and controlling energy dissipation and defect dynamics by altering alloy complexity may pave the way for new design principles of radiation-tolerant structural alloys for energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8736, "DOI": "10.1038/ncomms9736", "DOI Link": "http://dx.doi.org/10.1038/ncomms9736", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364939200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, Y; Lee, JY; Xi, SB; Sun, YM; Ge, JJ; Ong, SJH; Chen, YB; Dou, S; Meng, FX; Diao, CZ; Fisher, AC; Wang, X; Scherer, GG; Grimaud, A; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Yan; Lee, Jun Yan; Xi, Shibo; Sun, Yuanmiao; Ge, Jingjie; Ong, Samuel Jun Hoong; Chen, Yubo; Dou, Shuo; Meng, Fanxu; Diao, Caozheng; Fisher, Adrian C.; Wang, Xin; Scherer, Gunther G.; Grimaud, Alexis; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anodic Oxidation Enabled Cation Leaching for Promoting Surface Reconstruction in Water Oxidation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A rational design for oxygen evolution reaction (OER) catalysts is pivotal to the overall efficiency of water electrolysis. Much work has been devoted to understanding cation leaching and surface reconstruction of very active electrocatalysts, but little on intentionally promoting the surface in a controlled fashion. We now report controllable anodic leaching of Cr in CoCr2O4 by activating the pristine material at high potential, which enables the transformation of inactive spinel CoCr2O4 into a highly active catalyst. The depletion of Cr and consumption of lattice oxygen facilitate surface defects and oxygen vacancies, exposing Co species to reconstruct into active Co oxyhydroxides differ from CoOOH. A novel mechanism with the evolution of tetrahedrally coordinated surface cation into octahedral configuration via non-concerted proton-electron transfer is proposed. This work shows the importance of controlled anodic potential in modifying the surface chemistry of electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2021, "Volume": 60, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7418, "End Page": 7425, "Article Number": null, "DOI": "10.1002/anie.202015060", "DOI Link": "http://dx.doi.org/10.1002/anie.202015060", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618970400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, ZM; Han, H; Wang, FQ; Yan, YY; Shi, XH; Liang, HX; Zhang, XP; Shuai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Ziming; Han, Han; Wang, Fuqiang; Yan, Yuying; Shi, Xuhang; Liang, Huaxu; Zhang, Xinping; Shuai, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient radiative cooling coating with biomimetic human skin wrinkle structure", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Daytime radiative cooling is an energy-free pathway to achieve cooling performance. Current radiative cooling materials with periodic photonic structures are facing a huge challenge in terms of scale expansion owing to complex preparation technology and high cost. Herein, we proposed the idea of using biomimetic wrinkle structure combined with optimized particles to achieve the efficient optical property regulation of both the solar band and atmospheric window band. On this basis, a large-scale radiative cooling coating with the biomimetic structure of human skin natural wrinkle, comprising high concentrations of BaSO4 and SiO2 particles, was demonstrated. The coating with a thickness of similar to 100 mu m reflected similar to 95% of solar irradiance, and the emissivity in the atmospheric window band was similar to 96%. At noontime (11:00-13:00), in a populous area located at sea level, the average effective cooling power of similar to 89.6 W/m(2) was recorded, and the maximum sub-ambient temperature drop can reach 8.1 degrees C. An outdoor-building test conducted over a year showed that the maximum average indoor air temperature of the building painted with the coating was reduced by 6.2 degrees C and the maximum power-saving rate of air-conditioning exceeded 50%. Our work provided a new idea for designing, fabrication, and application of high-performance radiative cooling materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 89, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106377, "DOI": "10.1016/j.nulloen.2021.106377", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2021.106377", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709608600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Long, YW; Xu, SM; Liu, XH; Chen, L; Wang, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xu; Long, Yuwei; Xu, Shimei; Liu, Xuehui; Chen, Li; Wang, Yu-Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recovery of epoxy thermosets and their composites", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the currently predominullt thermoset plastic, epoxy thermoset is widely used in composite materials, electronic packaging materials, coatings and adhesives. The rapid rise in epoxy thermoset composite materials used for wind turbine blades is largely driven by increasing consumer demands for new energy sources such as wind power in the world. The recovery of the thermosetting polymers is among the most pressing contemporary challenges with the massive decommissioning of the materials. The review summarizes the recent advances on the recovery of epoxy thermosets from two different strategies including source-based recovery strategy (SRS, rational design of recyclable thermosets) and end-based recovery strategy (ERS, recovery approaches of existing thermosets). The recovery methods based on ERS are thoroughly discussed towards physcycling and chemcycling. We highlight important but easily neglected issues during the chemcycling, including mass transfer and heat transfer, solvent effects, full use of both reinforced materials and epoxy thermosets, as well as upcycling. It was pointed out that application-oriented chemcycling should be developed based on selective degradation and effective reconstruction. Finally, this review presents the forthcoming challenges and the prospects for future development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 64, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": 97, "Article Number": null, "DOI": "10.1016/j.mattod.2022.12.005", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2022.12.005", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001819600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, GZ; Qin, ZZ; Fang, WZ; Zhang, LC; Yue, SY; Yan, QB; Hu, M; Su, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Guangzhao; Qin, Zhenzhen; Fang, Wu-Zhang; Zhang, Li-Chuan; Yue, Sheng-Ying; Yan, Qing-Bo; Hu, Ming; Su, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diverse anisotropy of phonon transport in two-dimensional group IV-VI compounds: A comparative study", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New classes of two-dimensional (2D) materials beyond graphene, including layered and non-layered, and their heterostructures, are currently attracting increasing interest due to their promising applications in nulloelectronics, optoelectronics and clean energy, where thermal transport is a fundamental physical parameter. In this paper, we systematically investigated the phonon transport properties of the 2D orthorhombic group IV-VI compounds of GeS, GeSe, SnS and SnSe by solving the Boltzmann transport equation (BTE) based on first-principles calculations. Despite their similar puckered (hinge-like) structure along the armchair direction as phosphorene, the four monolayer compounds possess diverse anisotropic properties in many aspects, such as phonon group velocity, Young's modulus and lattice thermal conductivity (kappa), etc. Especially, the. along the zigzag and armchair directions of monolayer GeS shows the strongest anisotropy while monolayer SnS and SnSe show almost isotropy in phonon transport. The origin of the diverse anisotropy is fully studied and the underlying mechanism is discussed in details. With limited size, the kappa could be effectively lowered, and the anisotropy could be effectively modulated by nullostructuring, which would extend the applications to nulloscale thermoelectrics and thermal management. Our study offers fundamental understanding of the anisotropic phonon transport properties of 2D materials, and would be of significance for further study, modulation and applications in emerging technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11306, "End Page": 11319, "Article Number": null, "DOI": "10.1039/c6nr01349j", "DOI Link": "http://dx.doi.org/10.1039/c6nr01349j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380888200054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Panda, B; Paul, SC; Mohamed, null; Tay, YWD; Tan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Panda, Biranchi; Paul, Suvash Chandra; Mohamed, Nisar Ahamed Noor; Tay, Yi Wei Daniel; Tan, Ming Jen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Measurement of tensile bond strength of 3D printed geopolymer mortar", "Source Title": "MEASUREMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The structural capacity of construction joints in concrete bridges, deck and pavements mainly depends on the bond strength between the old substrate and new overlaid concrete. Sometimes, a mismatch in the properties of old and new concrete may lead to early age failure and shortened service life. Since in 3D concrete printing (3DCP), the whole object is made by layer by layer, bond strength is considered as one of the key parameters to ensure stability in the structure. For understanding bond mechanism, it is essential to measure bond strength at the interface between new and old layer and investigate significant parameters affecting this property. In this direction, our current work targets to analyse tensile bond strength of 3D printed geopolymer mortar with respect to printing time gap between layers, nozzle speed and nozzle standoff distance. A novel formulation of fly ash based geopolymer was made and printed using four- axis automated gantry system. Experimental findings reveal that the bond strength is a function of state of interface material between two nearby layers which can be influenced by material strength development rate and 3D printing parameters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 113, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 108, "End Page": 116, "Article Number": null, "DOI": "10.1016/j.measurement.2017.08.051", "DOI Link": "http://dx.doi.org/10.1016/j.measurement.2017.08.051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411767300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CM; Wang, Y; Li, ZJ; Chen, WX; Xu, Q; He, DS; Xi, DS; Zhang, QH; Yuan, TW; Qu, YT; Yang, J; Zhou, FY; Yang, ZK; Wang, XQ; Wang, J; Luo, J; Li, YF; Duan, HH; Wu, Y; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Changming; Wang, Yu; Li, Zhijun; Chen, Wenxing; Xu, Qian; He, Dongsheng; Xi, Desheng; Zhang, Qinghua; Yuan, Tongwei; Qu, Yunteng; Yang, Jian; Zhou, Fangyao; Yang, Zhengkun; Wang, Xiaoqian; Wang, Jing; Luo, Jun; Li, Yafei; Duan, Haohong; Wu, Yuen; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid-Diffusion Synthesis of Single-Atom Catalysts Directly from Bulk Metal for Efficient CO2 Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of CO2 into value-added products is an effective approach to remit the environmental and energy issues. However, the development of an effective, accessible, and simple method for mass production of electrocatalyst is challenging. Herein, we demonstrate the solid-state diffusion between the N-doped carbon phase and bulk Ni metal can be utilized to synthesize hierarchical, self-supported, and atomistic catalyst. Strikingly, this hierarchical catalyst is programmable and scalable to meet the industrial demand and can be directly used as a binder-free electrode toward the CO2 electroreduction, delivering a state-of-the-art current density of 48.66 mA cm(-2) at -1.0 V versus reversible hydrogen electrode (RHE) and high faradic efficiency of 97% to CO. The selectivity can be retained over 90% in a wide range of working potential of -0.7 to -1.2 V versus RHE. This solid-state diffusion strategy presents great potential to produce hierarchical and atomistic catalysts at industrial levels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 584, "End Page": 594, "Article Number": null, "DOI": "10.1016/j.joule.2018.11.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.11.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460076100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jouny, M; Lv, JJ; Cheng, T; Ko, BH; Zhu, JJ; Goddard, WA ; Jiao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jouny, Matthew; Lv, Jing-Jing; Cheng, Tao; Ko, Byung Hee; Zhu, Jun-Jie; Goddard, William A., III; Jiao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of carbon-nitrogen bonds in carbon monoxide electrolysis", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electroreduction of CO2 is a promising technology for carbon utilization. Although electrolysis of CO2 or CO2-derived CO can generate important industrial multicarbon feedstocks such as ethylene, ethanol, n-propanol and acetate, most efforts have been devoted to promoting C-C bond formation. Here, we demonstrate that C-N bonds can be formed through co-electrolysis of CO and NH3 with acetamide selectivity of nearly 40% at industrially relevant reaction rates. Full-solvent quantum mechanical calculations show that acetamide forms through nucleophilic addition of NH3 to a surface-bound ketene intermediate, a step that is in competition with OH- addition, which leads to acetate. The C-N formation mechanism was successfully extended to a series of amide products through amine nucleophilic attack on the ketene intermediate. This strategy enables us to form carbon-heteroatom bonds through the electroreduction of CO2 expanding the scope of products available from CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 11, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 846, "End Page": 851, "Article Number": null, "DOI": "10.1038/s41557-019-0312-z", "DOI Link": "http://dx.doi.org/10.1038/s41557-019-0312-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483307000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WD; Asl, HY; Xie, Q; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wangda; Asl, Hooman Yaghoobnejad; Xie, Qiang; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Collapse of LiNi1-x-yCoxMnyO2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Volume variation and the associated mechanical fracture of electrode materials upon Li extraction/insertion are a main cause limiting lifetime performance of lithium-ion batteries. For LiNi1-x-yCoxMnyO2 (NCM) cathodes, abrupt anisotropic collapse of the layered lattice structure at deep charge is generally considered characteristic to high Ni content and can be effectively suppressed by elemental substitution. Herein, we demonstrate the lattice collapse is a universal phenomenon almost entirely dependent on Li utilization, and not Ni content, of NCM cathodes upon delithiation. With Li removal nearing 80 mol %, very similar c-axis lattice shrinkage of around 5% occurs concurrently for NCMs synthesized in-house regardless of nickel content (90, 70, 50, or 33 mol %); meanwhile, the a-axis lattice contracts for high-Ni NCM, but it expands for low-Ni NCM. We further reveal Co-Mn cosubstitution in NCM barely, if at all, affects several key structural aspects governing the lattice distortion upon delithiation. Our results highlight the importance of evaluating true implications of compositional tuning on high-Ni layered oxide cathode materials to maximize their charge-storage capacities for next-generation high-energy Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2019, "Volume": 141, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5097, "End Page": 5101, "Article Number": null, "DOI": "10.1021/jacs.8b13798", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b13798", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463843700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, D; Yin, X; Guo, HY; Zhou, LL; Li, XY; Zhang, CL; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Di; Yin, Xing; Guo, Hengyu; Zhou, Linglin; Li, Xinyuan; Zhang, Chunlei; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A constant current triboelectric nullogenerator arising from electrostatic breakdown", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In situ conversion of mechanical energy into electricity is a feasible solution to satisfy the increasing power demand of the Internet of Things (IoTs). A triboelectric nullogenerator (TENG) is considered as a potential solution via building self-powered systems. Based on the triboelectrification effect and electrostatic induction, a conventional TENG with pulsed AC output characteristics always needs rectification and energy storage units to obtain a constant DC output to drive electronic devices. Here, we report a next-generation TENG, which realizes constant current (crest factor, similar to 1) output by coupling the triboelectrification effect and electrostatic breakdown. Meanwhile, a triboelectric charge density of 430 mu C m(-2) is attained, which is much higher than that of a conventional TENG limited by electrostatic breakdown. The novel DC-TENG is demonstrated to power electronics directly. Our findings not only promote the miniaturization of self-powered systems used in IoTs but also provide a paradigm-shifting technique to harvest mechanical energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav6437", "DOI": "10.1126/sciadv.aav6437", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav6437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466398400070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Senullayak, SP; Yang, BY; Thomas, TH; Giesbrecht, N; Huang, WC; Gann, E; Nair, B; Goedel, K; Guha, S; Moya, X; McNeill, CR; Docampo, P; Sadhanala, A; Friend, RH; Sirringhaus, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Senullayak, Satyaprasad P.; Yang, Bingyan; Thomas, Tudor H.; Giesbrecht, Nadja; Huang, Wenchao; Gann, Eliot; Nair, Bhaskaran; Goedel, Karl; Guha, Suchi; Moya, Xavier; McNeill, Christopher R.; Docampo, Pablo; Sadhanala, Aditya; Friend, Richard H.; Sirringhaus, Henning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding charge transport in lead iodide perovskite thin-film field-effect transistors", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fundamental understanding of the charge transport physics of hybrid lead halide perovskite semiconductors is important for advancing their use in high-performance optoelectronics. We use field-effect transistors (FETs) to probe the charge transport mechanism in thin films of methylammonium lead iodide (MAPbI(3)). We show that through optimization of thin-film microstructure and source-drain contact modifications, it is possible to significantly minimize instability and hysteresis in FET characteristics and demonstrate an electron field-effect mobility (mu(FET)) of 0.5 cm(2)/Vs at room temperature. Temperature-dependent transport studies revealed a negative coefficient of mobility with three different temperature regimes. On the basis of electrical and spectroscopic studies, we attribute the three different regimes to transport limited by ion migration due to point defects associated with grain boundaries, polarization disorder of the MA(+) cations, and thermal vibrations of the lead halide inorganic cages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601935", "DOI": "10.1126/sciadv.1601935", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393789900031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wolfs, RJM; Bos, FP; Salet, TAM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wolfs, R. J. M.; Bos, F. P.; Salet, T. A. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Early age mechanical behaviour of 3D printed concrete: Numerical modelling and experimental testing", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A numerical model was developed to analyse the mechanical behaviour of fresh, 3D printed concrete, in the range of 0 to 90 min after material deposition. The model was based on a time-dependent Mohr-Coulomb failure criterion and linear stress-strain behaviour up to failure. An experimental program, consisting of unconfined uniaxial compression tests and direct shear tests, was set-up and performed to obtain the required material properties. The material tests showed that the Young's modulus and cohesion linearly increase with fresh concrete age, as do the compressive and shear strength. The Poisson's ratio and angle of internal friction, on the other hand, remain constant. Subsequently, the model was validated by comparison to printing experiments. Modelling of the printed samples reproduced the experimental results qualitatively, but the quantitative agreement with the print experiments could be improved. However, the deviations can well be explained and the type of failure-deformation mode was predicted accurately.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 106, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": 116, "Article Number": null, "DOI": "10.1016/j.cemconres.2018.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2018.02.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429762800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, TR; Tan, GJ; Zhang, XM; Wu, CF; Li, JF; Dravid, VP; Snyder, GJ; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Tian-Ran; Tan, Gangjian; Zhang, Xiaomi; Wu, Chao-Feng; Li, Jing-Feng; Dravid, Vinayak P.; Snyder, G. Jeffrey; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Distinct Impact of Alkali-Ion Doping on Electrical Transport Properties of Thermoelectric p-Type Polycrystalline SnSe", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent findings about ultrahigh thermoelectric performance in SnSe single crystals have stimulated related research on this simple binary compound, which is focused mostly on its polycrystalline counterparts, and particularly on electrical property enhancement by effective doping. This work systematically investigated the thermoelectric properties of polycrystalline SnSe doped with three alkali metals (Li, Na, and K). It is found that Na has the best doping efficiency, leading to an increase in hole concentration from 3.2 X 10(17) to 4.4 X 10(19) cm(-3) at room temperature, accompanied by a drop in Seebeck coefficient from 480 to 142 mu V/K. An equivalent single parabolic band model was found adequate to capture the variation tendency of Seebeck coefficient with doping levels within a wide range. A mixed scattering of carriers by acoustic phonons and grain boundaries is suitable for numerically understanding the temperature-dependence of carrier mobility. A maximum ZT of similar to 0.8 was achieved in 1% Na- or K-doped SnSe at 800 K. Possible strategies to improve the mobility and ZT of polycrystals were also proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2016, "Volume": 138, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8875, "End Page": 8882, "Article Number": null, "DOI": "10.1021/jacs.6b04181", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b04181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380295600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Levine, I; Al-Ashouri, A; Musiienko, A; Hempel, H; Magomedov, A; Drevilkauskaite, A; Getautis, V; Menzel, D; Hinrichs, K; Unold, T; Albrecht, S; Dittrich, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Levine, Igal; Al-Ashouri, Amran; Musiienko, Artem; Hempel, Hannes; Magomedov, Artiom; Drevilkauskaite, Aida; Getautis, Vytautas; Menzel, Dorothee; Hinrichs, Karsten; Unold, Thomas; Albrecht, Steve; Dittrich, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge transfer rates and electron trapping at buried interfaces of perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identification of electronic processes at buried interfaces of charge selective contacts is crucial for photovoltaic and photocatalysis research. Here, transient surface photovoltage (SPV) is used to study the passivation of different hole-selective carbazole-based SAMs. It is shown that transient SPV and transient photoluminescence provide complementary information on charge transfer kinetics and trapping/de-trapping mechanisms, and that trap-assisted non-radiative recombination losses originate from electron trapping at the SAM-modified ITO/perovskite interface. The hole transfer rates and the density of interface electron traps, obtained by fitting SPV transients with a minimalistic kinetic model, depended strongly on the SAM's chemical structure, and densities of interface traps as low as 10(9) cm(-2), on par with highly passivated c-Si surfaces, were reached for Me-4PACz, previously used in record perovskite/silicon tandem solar cells. The extracted hole transfer rate constants and interface trap densities correlated well with the corresponding fill factors and open-circuit voltages of high-efficiency solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2021, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2915, "End Page": 2933, "Article Number": null, "DOI": "10.1016/j.joule.2021.07.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.07.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000723010700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XH; Liu, ZC; Sun, JF; Luo, RH; Xu, K; Si, MY; Kang, J; Yuan, Y; Liu, S; Ahmad, T; Jiang, TL; Chen, N; Wang, MM; Xu, Y; Chuai, M; Zhu, ZX; Peng, Q; Meng, YH; Zhang, K; Wang, WP; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xinhua; Liu, Zaichun; Sun, Jifei; Luo, Ruihao; Xu, Kui; Si, Mingyu; Kang, Ju; Yuan, Yuan; Liu, Shuang; Ahmad, Touqeer; Jiang, Taoli; Chen, Na; Wang, Mingming; Xu, Yan; Chuai, Mingyan; Zhu, Zhengxin; Peng, Qia; Meng, Yahan; Zhang, Kai; Wang, Weiping; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of Zn-free anodes to inhibit Zn dendrite formation and modulate high-capacity Zn batteries is highly applauded yet very challenging. Here, we design a robust two-dimensional antimony/antimony-zinc alloy heterostructured interface to regulate Zn plating. Benefiting from the stronger adsorption and homogeneous electric field distribution of the Sb/Sb2Zn3-heterostructured interface in Zn plating, the Zn anode enables an ultrahigh areal capacity of 200 mAh cm(-2) with an overpotential of 112 mV and a Coulombic efficiency of 98.5%. An anode-free Zn-Br-2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg(-1) with a practical pouch cell energy density of 62 Wh kg(-1). The scaled-up Zn-Br-2 battery in a capacity of 500 mAh exhibits over 400 stable cycles. Further, the Zn-Br-2 battery module in an energy of 9 Wh (6 V, 1.5 Ah) is integrated with a photovoltaic panel to demonstrate the practical renewable energy storage capabilities. Our superior anode-free Zn batteries enabled by the heterostructured interface enlighten an arena towards large-scale energy storage applications. The development of dendrite-free, Zn-free anodes is challenging. Here, the authors design a two-dimensional antimony/antimony-zinc alloy heterostructured interface to achieve dendrite-free Zn deposition with areal capacity of 200 mAh cm(-2), and energy density of around 270 Wh kg(-1) for anode-free zinc-bromine battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76, "DOI": "10.1038/s41467-022-35630-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35630-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940650100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YM; Yang, ZZ; Xu, SY; Mu, LQ; Gu, L; Hu, YS; Li, H; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yunming; Yang, Zhenzhong; Xu, Shuyin; Mu, Linqin; Gu, Lin; Hu, Yong-Sheng; Li, Hong; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air-Stable Copper-Based P2-Na7/9Cu2/9Fe1/9Mn2/3O2 as a New Positive Electrode Material for Sodium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500031, "DOI": "10.1002/advs.201500031", "DOI Link": "http://dx.doi.org/10.1002/advs.201500031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368944600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, CC; Lu, BY; Pawar, G; Zhang, MH; Cheng, DY; Chen, SR; Ceja, M; Doux, JM; Musrock, H; Cai, M; Liaw, B; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Chengcheng; Lu, Bingyu; Pawar, Gorakh; Zhang, Minghao; Cheng, Diyi; Chen, Shuru; Ceja, Miguel; Doux, Jean-Marie; Musrock, Henry; Cai, Mei; Liaw, Boryann; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-tailored lithium deposition and dissolution in lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unregulated lithium (Li) growth is the major cause of low Coulombic efficiency, short cycle life and safety hazards for rechargeable Li metal batteries. Strategies that aim to achieve large granular Li deposits have been extensively explored, and yet it remains a challenge to achieve the ideal Li deposits, which consist of large Li particles that are seamlessly packed on the electrode and can be reversibly deposited and stripped. Here we report a dense Li deposition (99.49% electrode density) with an ideal columnar structure that is achieved by controlling the uniaxial stack pressure during battery operation. Using multiscale characterization and simulation, we elucidate the critical role of stack pressure on Li nucleation, growth and dissolution processes and propose a Li-reservoir-testing protocol to maintain the ideal Li morphology during extended cycling. The precise manipulation of Li deposition and dissolution is a critical step to enable fast charging and a low-temperature operation for Li metal batteries. Li electrodeposition is a fundamental process in Li metal batteries and its reversibility is crucial for battery operation. The authors investigate the effects of stack pressure on Li deposition and associated processes and discuss strategies for achieving dense Li deposits and practical Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 987, "End Page": 994, "Article Number": null, "DOI": "10.1038/s41560-021-00917-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00917-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709367700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, A; Li, HZ; Li, Z; Zhao, ZP; Li, KX; Li, MZ; Song, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, An; Li, Huizeng; Li, Zheng; Zhao, Zhipeng; Li, Kaixuan; Li, Mingzhu; Song, Yanlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programmable droplet manipulation by a magnetic-actuated robot", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Droplet manipulations are fundamental to numerous applications, such as water collection, medical diagnostics, and drug delivery. Structure-based liquid operations have been widely used both in nature and in artificial materials. However, current strategies depend mainly on fixed structures to realize unidirectional water movement, while multiple manipulation of droplets is still challenging. Here, we propose a magnetic-actuated robot with adjustable structures to achieve programmable multiple manipulations of droplets. The adjustable structure redistributes the resisting forces from the front and rear ends of the droplets, which determine the droplet behaviors. We can transport, split, release, and rotate the droplets using the robot. This robot is universally applicable for manipulation of various fluids in rough environments. These findings offer an efficient strategy for automated manipulation of droplets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay5808", "DOI": "10.1126/sciadv.aay5808", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay5808", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518996500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, B; Cui, JH; Xiang, ZJ; Shang, C; Wang, NZ; Ye, GJ; Luo, XG; Wu, T; Sun, Z; Chen, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, B.; Cui, J. H.; Xiang, Z. J.; Shang, C.; Wang, N. Z.; Ye, G. J.; Luo, X. G.; Wu, T.; Sun, Z.; Chen, X. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of High-Temperature Superconductivity from a Low-Tc Phase Tuned by Carrier Concentration in FeSe Thin Flakes", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the evolution of superconductivity in an FeSe thin flake with systematically regulated carrier concentrations by the liquid-gating technique. With electron doping tuned by the gate voltage, high-temperature superconductivity with an onset at 48 K can be achieved in an FeSe thin flake with T-c less than 10 K. This is the first time such high temperature superconductivity in FeSe is achieved without either an epitaxial interface or external pressure, and it definitely proves that the simple electron-doping process is able to induce high-temperature superconductivity with T-c(onset) as high as 48 K in bulk FeSe. Intriguingly, our data also indicate that the superconductivity is suddenly changed from a low-T-c phase to a high-T-c phase with a Lifshitz transition at a certain carrier concentration. These results help to build a unified picture to understand the high-temperature superconductivity among all FeSe-derived superconductors and shed light on the further pursuit of a higher T-c in these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2016, "Volume": 116, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77002, "DOI": "10.1103/PhysRevLett.116.077002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.077002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370621200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, GF; Ciou, JH; Liu, YZ; Jiang, Y; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Guofa; Ciou, Jing-Hao; Liu, Yizhi; Jiang, Yi; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Leaf-inspired multiresponsive MXene-based actuator for programmable smart devices", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural leaves, with elaborate architectures and functional components, harvest and convert solar energy into chemical fuels that can be converted into energy based on photosynthesis. The energy produced leads to work done that inspired many autonomous systems such as light-triggered motion. On the basis of this nature-inspired phenomenon, we report an unprecedented bilayer-structured actuator based on MXene (Ti3C2Tx)-cellulose composites (MXCC) and polycarbonate membrane, which mimic not only the sophisticated leaf structure but also the energy-harvesting and conversion capabilities. The bilayer actuator features multiresponsiveness, low-power actuation, fast actuation speed, large-shape deformation, programmable adaptability, robust stability, and low-cost facile fabrication, which are highly desirable for modern soft actuator systems. We believe that these adaptive soft systems are attractive in a wide range of revolutionary technologies such as soft robots, smart switch, information encryption, infrared dynamic display, camouflage, and temperature regulation, as well as human-machine interface such as haptics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw7956", "DOI": "10.1126/sciadv.aaw7956", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw7956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478770400099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, J; Zhang, CX; Jiang, L; Lin, H; An, YM; Zhou, D; Leung, MKH; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Jue; Zhang, Chengxu; Jiang, Lin; Lin, He; An, Yiming; Zhou, Dan; Leung, Michael K. H.; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullohybridization of MoS2 with Layered Double Hydroxides Efficiently Synergizes the Hydrogen Evolution in Alkaline Media", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction (HER) on earth-abundant molybdenum disulfide (MoS2) in acidic media is a robust process, but is kinetically retarded in alkaline media. Thus, improving the sluggish kinetics for HER in alkaline media is crucial for advancing the performance of water-alkali electrolyzers. Here, we demonstrate a dramatic enhancement of HER kinetics in base by judiciously hybridizing vertical MoS2 sheets with another earth-abundant material, layered double hydroxide (LDH). The resultant MoS2/NiCo-LDH hybrid exhibits an extremely low HER overpotential of 78 mV at 10 mA/cm(2) and a low Tafel slope of 76.6 mV/dec in 1 M KOH solution. At the current density of 20 mA/cm(2) or even higher, the MoS2/NiCo-LDH composite can operate without degradation for 48 hr. This work not only brought forth a cost-effective and robust electrocatalyst, but more generally opened up new vistas for developing high-performance electrocatalysts in unfavorable media recalcitrant to conventional catalyst design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 383, "End Page": 393, "Article Number": null, "DOI": "10.1016/j.joule.2017.07.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.07.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425180300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Obadia, MM; Mudraboyina, BP; Serghei, A; Montarnal, D; Drockenmuller, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Obadia, Mona M.; Mudraboyina, Bhanu P.; Serghei, Anatoli; Montarnal, Damien; Drockenmuller, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reprocessing and Recycling of Highly Cross-Linked Ion-Conducting Networks through Transalkylation Exchanges of C-N Bonds", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploiting exchangeable covalent bonds as dynamo cross-links recently afforded a new class of polymer materials coined as vitrimers. These permanent networks are insoluble and infusible, but the network topology can be, reshuffled at high ternperatures, thus enabling glasslike :plastic, deformation and reprocessing without depolymerization. We disclose herein the development of funaional and high-value ion-conducting vitrimers that take inspiration from poly(ionic liquid)s. Tunable networks with high ionic content are obtained, 17 the solvent and catalyst-free polyaddition of an alpha-azide-omega-alkyne monomer and simultaneous alkylation of the resulting poly(1,2,3-triazole)s with a series' of difunctional cross-linking agents. Temperature-nduced transalkylation exchanges of C-N bonds between 1,2,3-triazolium cross links and halide-functionalized dangling chains enable, recycling and reprocessing of these highly, cross linked permanent net-Works. They can also be recycled by depolymerization with specific solvents able to displace the transalkylation equilibrium, and they display a,great potential for applications that require solid electrolytes with excellent mechanical performances and facile processing such as supercapacitors, batteries, fuel cells:, and separation membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2015, "Volume": 137, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6078, "End Page": 6083, "Article Number": null, "DOI": "10.1021/jacs.5b02653", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b02653", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354910500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, R; Wang, ZP; Zhu, LN; Pan, Y; Zhang, DW; Wen, H; Luo, ZD; Li, LL; Li, FT; Wu, M; He, LQ; Sharma, P; Seidel, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Ran; Wang, Zhipeng; Zhu, Lina; Pan, Ying; Zhang, Dawei; Wen, Hui; Luo, Zheng-Dong; Li, Linglong; Li, Fa-tang; Wu, Ming; He, Liqiang; Sharma, Pankaj; Seidel, Jan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain-Engineered nullo-Ferroelectrics for High-Efficiency Piezocatalytic Overall Water Splitting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing nullo-ferroelectric materials with excellent piezoelectric performance for piezocatalysts used in water splitting is highly desired but also challenging, especially with respect to reaching large piezo-potentials that fully align with required redox levels. Herein, heteroepitaxial strain in BaTiO3 nulloparticles with a designed porous structure is successfully induced by engineering their surface reconstruction to dramatically enhance their piezoelectricity. The strain coherence can be maintained throughout the nulloparticle bulk, resulting in a significant increase of the BaTiO3 tetragonality and thus its piezoelectricity. Benefiting from high piezoelectricity, the as-synthesized blue-colored BaTiO3 nulloparticles possess a superb overall water-splitting activity, with H-2 production rates of 159 mu mol g(-1) h(-1), which is almost 130 times higher than that of the pristine BaTiO3 nulloparticles. Thus, this work provides a generic approach for designing highly efficient piezoelectric nullomaterials by strain engineering that can be further extended to various other perovskite oxides, including SrTiO3, thereby enhancing their potential for piezoelectric catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2021, "Volume": 60, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16019, "End Page": 16026, "Article Number": null, "DOI": "10.1002/anie.202103112", "DOI Link": "http://dx.doi.org/10.1002/anie.202103112", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659243100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Puigdollers, AR; Schlexer, P; Tosoni, S; Pacchioni, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Puigdollers, Antonio Ruiz; Schlexer, Philomena; Tosoni, Sergio; Pacchioni, Gianfranco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Increasing Oxide Reducibility: The Role of Metal/Oxide Interfaces in the Formation of Oxygen Vacancies", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducibility is an essential characteristic of oxide catalysts in oxidation reactions following the Mars van Krevelen mechanism. A typical descriptor of the reducibility of an oxide is the cost of formation of an oxygen vacancy, which measures the tendency of the oxide to lose oxygen or to donate it to an adsorbed species with consequent change in the surface composition, from MnOm to MnOm-x. The oxide reducibility, however, can be modified in various ways: for instance, by doping and/or nullostructuring. In this review we consider an additional aspect, related to the formation of a metal/oxide interface. This can be realized when small metal nulloparticles are deposited on the surface of an oxide support or when a nullostructured oxide, either a nulloparticle or a thin film, is grown on a metal. In the past decade, both theory and experiment indicate a particularly high reactivity of the oxygen atoms at the boundary region between a metal and an oxide. Oxygen atoms can be removed from interface sites at much lower cost than in other regions of the surface. This can alter completely the reactivity of a solid catalyst. In this respect, reducibility of the bulk material may differ completely from that of the metal/oxide surface. The atomistic study of CO oxidation and water-gas shift reactions are used as examples to provide compelling evidence that the oxidation occurs at specific interface sites, the actual active sites in the complex catalyst. Combining oxide nullostructuring with metal/oxide interfaces opens promising perspectives to turn hardly reducible oxides into reactive materials in oxidation reactions based on the Mars van Krevelen mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 692, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6493, "End Page": 6513, "Article Number": null, "DOI": "10.1021/acscatal.7b01913", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b01913", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412795700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, K; Duan, XC; Jiang, ZY; Ding, D; Chen, YC; Zhang, GQ; Liu, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Kang; Duan, Xingchen; Jiang, Zhiyong; Ding, Dan; Chen, Yuncong; Zhang, Guo-Qiang; Liu, Zhipeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "J-aggregates of meso-[2.2]paracyclophanyl-BODIPY dye for NIR-II imaging", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "J-aggregation is an efficient strategy for the development of fluorescent imaging agents in the second near-infrared window. However, the design of the second near-infrared fluorescent J-aggregates is challenging due to the lack of suitable J-aggregation dyes. Herein, we report meso-[2.2]paracyclophanyl-3,5-bis-N,N-dimethylaminostyrl BODIPY (PCP-BDP2) as an example of BODIPY dye with J-aggregation induced the second near-infrared fluorescence. PCP-BDP2 shows an emission maximum at 1010 nm in the J-aggregation state. Mechanism studies reveal that the steric and conjugation effect of the PCP group on the BODIPY play key roles in the J-aggregation behavior and photophysical properties tuning. Notably, PCP-BDP2 J-aggregates can be utilized for lymph node imaging and fluorescence-guided surgery in the nude mouse, which demonstrates their potential clinical application. This study demonstrates BODIPY dye as an alternate J-aggregation platform for developing the second near-infrared imaging agents. J-aggregation has been proved to be an efficient strategy for the development of fluorescent imaging agents in the NIR-II spectral region but the design of appropriate J-aggregates is challenging. Here, the authors demonstrate J-aggregation of a BODIPY dye with NIR-II emission and demonstrate lymph node imaging for fluorescence guided surgery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2376, "DOI": "10.1038/s41467-021-22686-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22686-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642744500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, H; Tutusaus, O; Liang, YL; Zhang, Y; Lebens-Higgins, Z; Yang, WL; Mohtadi, R; Yao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Hui; Tutusaus, Oscar; Liang, Yanliang; Zhang, Ye; Lebens-Higgins, Zachary; Yang, Wanli; Mohtadi, Rana; Yao, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to sluggish Mg-ion dissociation and diffusion, Mg-based batteries have low power densities. Here the authors carry out rational designs for both the cathode and the electrolyte to enable ultrafast kinetics of a Mg metal battery. Magnesium batteries have long been pursued as potentially low-cost, high-energy and safe alternatives to Li-ion batteries. However, Mg2+ interacts strongly with electrolyte solutions and cathode materials, leading to sluggish ion dissociation and diffusion, and consequently low power output. Here we report a heterogeneous enolization chemistry involving carbonyl reduction (C=O <-> C-O-), which bypasses the dissociation and diffusion difficulties, enabling fast and reversible redox processes. This kinetically favoured cathode is coupled with a tailored, weakly coordinating boron cluster-based electrolyte that allows for dendrite-free Mg plating/stripping at a current density of 20 mA cm(-2). The combination affords a Mg battery that delivers a specific power of up to 30.4 kW kg(-1), nearly two orders of magnitude higher than that of state-of-the-art Mg batteries. The cathode and electrolyte chemistries elucidated here propel the development of magnesium batteries and would accelerate the adoption of this low-cost and safe battery technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1043, "End Page": 1050, "Article Number": null, "DOI": "10.1038/s41560-020-00734-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-00734-0", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595285900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, Z; Cong, BQ; Oliveira, JP; Ke, WC; Schell, N; Peng, B; Qi, ZW; Ge, FG; Zhang, W; Ao, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Z.; Cong, B. Q.; Oliveira, J. P.; Ke, W. C.; Schell, N.; Peng, B.; Qi, Z. W.; Ge, F. G.; Zhang, W.; Ao, S. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire and arc additive manufacturing of a Ni-rich NiTi shape memory alloy: Microstructure and mechanical properties", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wire and Arc Additive Manufacturing (WAAM) was used for fabrication of NiTi parts using a commercialy available Ni-rich NiTi wire as the feedstock material. The as-built parts are near fully austenitic at room temperature as confirmed by differential scanning calorimetry, X-ray diffraction and superelastic cycling. The asbuilt microstructure changed from collumnar, in the first deposited layers, to equiaxed in the last deposited ones as a result of the different thermal cycle conditions. This is the first work where WAAM NiTi parts exhibit superelastic behavior under tensile conditions, highlighting the potential use of the technique for the creation of parts shaped in a complex manner based on this material and process. The potential to use WAAM for deposition of advanced functional materials is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 32, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101051, "DOI": "10.1016/j.addma.2020.101051", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2020.101051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522928600093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, TH; Lee, JW; Choi, C; Tan, S; Lee, C; Zhao, YP; Dai, ZH; De Marco, N; Lee, SJ; Bae, SH; Yuan, YH; Lee, HM; Huang, Y; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Tae-Hee; Lee, Jin-Wook; Choi, Chungseok; Tan, Shaun; Lee, Changsoo; Zhao, Yepin; Dai, Zhenghong; De Marco, Nicholas; Lee, Sung-Joon; Bae, Sang-Hoon; Yuan, Yonghai; Lee, Hyuck Mo; Huang, Yu; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manipulation of grain boundaries in polycrystalline perovskite is an essential consideration for both the optoelectronic properties and environmental stability of solar cells as the solution-processing of perovskite films inevitably introduces many defects at grain boundaries. Though small molecule-based additives have proven to be effective defect passivating agents, their high volatility and diffusivity cannot render perovskite films robust enough against harsh environments. Here we suggest design rules for effective molecules by considering their molecular structure. From these, we introduce a strategy to form macromolecular intermediate phases using long chain polymers, which leads to the formation of a polymer-perovskite composite cross-linker. The cross-linker functions to bridge the perovskite grains, minimizing grain-to-grain electrical decoupling and yielding excellent environmental stability against moisture, light, and heat, which has not been attainable with small molecule defect passivating agents. Consequently, all photovoltaic parameters are significantly enhanced in the solar cells and the devices also show excellent stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 477, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 520, "DOI": "10.1038/s41467-019-08455-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08455-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457291300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kezilebieke, S; Huda, N; Vano, V; Aapro, M; Ganguli, SC; Silveira, OJ; Glodzik, S; Foster, AS; Ojanen, T; Liljeroth, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kezilebieke, Shawulienu; Huda, Nurul; Vano, Viliam; Aapro, Markus; Ganguli, Somesh C.; Silveira, Orlando J.; Glodzik, Szczepan; Foster, Adam S.; Ojanen, Teemu; Liljeroth, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological superconductivity in a van der Waals heterostructure", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exotic states such as topological insulators, superconductors and quantum spin liquids are often challenging or impossible to create in a single material(1-3). For example, it is unclear whether topological superconductivity, which has been suggested to be a key ingredient for topological quantum computing, exists in any naturally occurring material(4-9). The problem can be circumvented by deliberately selecting the combination of materials in heterostructures so that the desired physics emerges from interactions between the different components(1,10-15). Here we use this designer approach to fabricate van der Waals heterostructures that combine a two-dimensional (2D) ferromagnet with a superconductor, and we observe 2D topological superconductivity in the system. We use molecular-beam epitaxy to grow 2D islands of ferromagnetic chromium tribromide(16) on superconducting niobium diselenide. We then use low-temperature scanning tunnelling microscopy and spectroscopy to reveal the signatures of one-dimensional Majorana edge modes. The fabricated 2D van der Waals heterostructure provides a high-quality, tunable system that can be readily integrated into device structures that use topological superconductivity. The layered heterostructures can be readily accessed by various external stimuli, potentially allowing external control of 2D topological superconductivity through electrical(17), mechanical(18), chemical(19) or optical means(20).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2020, "Volume": 588, "Issue": 7838, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 424, "End Page": 428, "Article Number": null, "DOI": "10.1038/s41586-020-2989-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2989-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613070500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rong, XH; Liu, J; Hu, EY; Liu, YJ; Wang, Y; Wu, JP; Yu, XQ; Page, K; Hu, YS; Yang, WL; Li, H; Yang, XQ; Chen, LQ; Huang, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rong, Xiaohui; Liu, Jue; Hu, Enyuan; Liu, Yijin; Wang, Yi; Wu, Jinpeng; Yu, Xiqian; Page, Katharine; Hu, Yong-Sheng; Yang, Wanli; Li, Hong; Yang, Xiao-Qing; Chen, Liquan; Huang, Xuejie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure-Induced Reversible Anionic Redox Activity in Na Layered Oxide Cathode", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anionic redox reaction (ARR) in lithium-and sodium-ion batteries is under hot discussion, mainly regarding how oxygen anion participates and to what extent oxygen can be reversibly oxidized and reduced. Here, a P3-type Na-0.6[Li0.2Mn0.8]O-2 with reversible capacity from pure ARR was studied. The interlayer O-O distance (peroxo-like O-O dimer, 2.506(3)angstrom), associated with oxidization of oxygen anions, was directly detected by using a neutron total scattering technique. Different from Li2RuO3 or Li2IrO3 with strong metal-oxygen (M-O) bonding, for P3-type Na-0.6[Li0.2Mn0.8]O-2 with relatively weak Mn-O covalent bonding, crystal structure factors might play an even more important role in stabilizing the oxidized species, as both Li and Mn ions are immobile in the structure and thus may inhibit the irreversible transformation of the oxidized species to O-2 gas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2018, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 125, "End Page": 140, "Article Number": null, "DOI": "10.1016/j.joule.2017.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425303800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Constant, S; Wienk, HLJ; Frissen, AE; de Peinder, P; Boelens, R; van Es, DS; Grisel, RJH; Weckhuysen, BM; Huijgen, WJJ; Gosselink, RJA; Bruijnincx, PCA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Constant, Sandra; Wienk, Hans L. J.; Frissen, Augustinus E.; de Peinder, Peter; Boelens, Rolf; van Es, Daan S.; Grisel, Ruud J. H.; Weckhuysen, Bert M.; Huijgen, Wouter J. J.; Gosselink, Richard J. A.; Bruijnincx, Pieter C. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New insights into the structure and composition of technical lignins: a comparative characterisation study", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detailed insight into the structure and composition of industrial (technical) lignins is needed to devise efficient thermal, bio- or chemocatalytic valorisation strategies. Six such technical lignins covering three main industrial pulping methods (Indulin AT Kraft, Protobind 1000 soda lignin and Alcell, poplar, spruce and wheat straw organosolv lignins) were comprehensively characterised by lignin composition analysis, FT-IR, pyrolysis-GC-MS, quantitative P-31 and 2D HSQC NMR analysis and molar mass distribution by Size Exclusion Chromatography (SEC). A comparison of nine SEC methods, including the first analysis of lignins with commercial alkaline SEC columns, showed molar masses to vary considerably, allowing some recommendations to be made. The lignin molar mass decreased in the order: Indulin Kraft > soda P1000 > Alcell > OS-W similar to OS-P similar to OS-S, regardless of the SEC method chosen. Structural identification and quantification of aromatic units and inter-unit linkages indicated that all technical lignins, including the organosolv ones, have considerably been degraded and condensed by the pulping process. Importantly, low amounts of beta- ether linkages were found compared to literature values for protolignin and lignins obtained by other, milder isolation processes. Stilbenes and ether furfural units could also be identified in some of the lignins. Taken together, the insights gained in the structure of the technical lignins, in particular, the low beta-O-4 contents, carry implications for the design of lignin valorisation strategies including (catalytic) depolymerisation and material applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 671, "Times Cited, All Databases": 711, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 18, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2651, "End Page": 2665, "Article Number": null, "DOI": "10.1039/c5gc03043a", "DOI Link": "http://dx.doi.org/10.1039/c5gc03043a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375291100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZQ; Chen, HZ; Li, B; Xie, YM; Gong, XL; Liu, X; Li, HR; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiqiang; Chen, Hongzhong; Li, Bin; Xie, Yanmiao; Gong, Xiaoli; Liu, Xiao; Li, Huanrong; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoresponsive Luminescent Polymeric Hydrogels for Reversible Information Encryption and Decryption", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional luminescent information is usually visible under either ambient or UV light, hampering their potential application in smart confidential information protection. In order to address this challenge, herein, light-triggered luminescence ON-OFF switchable hybrid hydrogels are successfully constructed through in situ copolymerization of acrylamide, lanthanide complex, and diarylethene photochromic unit. The open-close behavior of the diarylethene ring in the polymer could be controlled by UV and visible light irradiation, where the close form of the ring features fluorescence resonullce energy transfer with the lanthanide complex. The hydrogel-based blocks with tunable emission colors are then employed to construct 3D information codes, which can be read out under a 254 nm UV lamp. The exposure to 300 nm UV light leads to the luminescence quenching of the hydrogels, thus erasing the encoded information. Under visible light (>450 nm) irradiation, the luminescence is recovered to make the confidential information readable again. Thus, by simply alternating the exposure to UV and visible lights, the luminescence signals could become invisible and visible reversibly, allowing for reversible multiple information encryption and decryption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 6, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901529, "DOI": "10.1002/advs.201901529", "DOI Link": "http://dx.doi.org/10.1002/advs.201901529", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485379100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ozturk, B; Argin, S; Ozilgen, M; McClements, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozturk, Bengu; Argin, Sanem; Ozilgen, Mustafa; McClements, David Julian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation and stabilization of nulloemulsion-based vitamin E delivery systems using natural biopolymers: Whey protein isolate and gum arabic", "Source Title": "FOOD CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural biopolymers, whey protein isolate (WPI) and gum arabic (GA), were used to fabricate emulsion-based delivery systems for vitamin E-acetate. Stable delivery systems could be formed when vitamin E-acetate was mixed with sufficient orange oil prior to high pressure homogenization. WPI (d(32) = 0.11 mu m, 1% emulsifier) was better than GA (d(32) = 0.38 mu m, 10% emulsifier) at producing small droplets at low emulsifier concentrations. However, WPI-stabilized nulloemulsions were unstable to flocculation near the protein isoelectric point (pH 5.0), at high ionic strength (>100 mM), and at elevated temperatures (>60 degrees C), whereas GA-gtabilized emulsions were stable. This difference was attributed to differences in emulsifier stabilization mechanisms: WPI by electrostatic repulsion; GA by steric repulsion. These results provide useful information about the emulsifying and stabilizing capacities of natural biopolymers for forming food-grade vitamin-enriched delivery systems. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2015, "Volume": 188, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 256, "End Page": 263, "Article Number": null, "DOI": "10.1016/j.foodchem.2015.05.005", "DOI Link": "http://dx.doi.org/10.1016/j.foodchem.2015.05.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology; Nutrition & Dietetics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356548900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Iino, H; Usui, T; Hanna, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Iino, Hiroaki; Usui, Takayuki; Hanna, Jun-ichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid crystals for organic thin-film transistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystalline thin films of organic semiconductors are a good candidate for field effect transistor (FET) materials in printed electronics. However, there are currently two main problems, which are associated with inhomogeneity and poor thermal durability of these films. Here we report that liquid crystalline materials exhibiting a highly ordered liquid crystal phase of smectic E (SmE) can solve both these problems. We design a SmE liquid crystalline material, 2-decyl-7-phenyl-[1] benzothieno[3,2-b][1] benzothiophene (Ph-BTBT-10), for FETs and synthesize it. This material provides uniform and molecularly flat polycrystalline thin films reproducibly when SmE precursor thin films are crystallized, and also exhibits high durability of films up to 200 degrees C. In addition, the mobility of FETs is dramatically enhanced by about one order of magnitude (over 10 cm(2)V(-1) s(-1)) after thermal annealing at 120 degrees C in bottom-gate-bottom-contact FETs. We anticipate the use of SmE liquid crystals in solution-processed FETs may help overcome upcoming difficulties with novel technologies for printed electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6828, "DOI": "10.1038/ncomms7828", "DOI Link": "http://dx.doi.org/10.1038/ncomms7828", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353703200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, YT; Lin, JH; Xu, TX; Liu, BS; Huang, KK; Qiao, L; Liu, SD; Cao, J; Jun, SC; Yamauchi, Y; Qi, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Yaotian; Lin, Jinghuang; Xu, Tianxiong; Liu, Baishen; Huang, Keke; Qiao, Liang; Liu, Shude; Cao, Jian; Jun, Seong Chan; Yamauchi, Yusuke; Qi, Junlei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-Level Platinum Filling into Ni-Vacancies of Dual-Deficient NiO for Boosting Electrocatalytic Hydrogen Evolution", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing low-cost and high-efficiency catalysts for sustainable hydrogen production through electrocatalytic hydrogen evolution reaction (HER) is crucial yet remains challenging. Here, a strategy is proposed to fill Ni-vacancy (Ni-v) sites of dual-deficient NiO (D-NiO-Pt) deliberately created by Ar plasma with homogeneously distributed Pt atoms driven by oxygen vacancies (O-v). The incorporated Pt atoms filling the Ni-v reduce the formation energy to increase crystal stability, and subsequently combine with additional O-v to tune the electronic structure of the surrounding Ni sites. Thus, a more ideal hydrogen adsorption free energy (Delta G(H*)) closer to 0 of Ni sites and Pt sites can be achieved. As a result, the D-NiO-Pt electrode achieves superior mass activity of approximate to 1600 mA mg(-1) (normalized by platinum) and nearly negligible loss of activity during long-term operation, which is much better than as-prepared Pt-containing NiO catalysts without plasma treatment. A low overpotential of 20 mV is required for the D-NiO-Pt at 10 mA cm(-2) in alkaline HER, outperforming that of the commercial Pt/C. In addition, the universal access to the other Ni-based compounds including nickel phosphide (Ni2P), nickel sulfide (Ni0.96S), and nickel selenide (NiSe2) is also demonstrated by employing a vacancy-driven Pt filling mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 12, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200434, "DOI": "10.1002/aenm.202200434", "DOI Link": "http://dx.doi.org/10.1002/aenm.202200434", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785582000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, MQ; Wu, FF; Zhang, Y; Yao, YH; Zhu, GP; Li, XY; Chen, L; Jia, G; Wu, XH; Huang, YJ; Gao, P; Ye, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Mengqiu; Wu, Fangfang; Zhang, Ye; Yao, Yuanhui; Zhu, Genping; Li, Xiaoyu; Chen, Liang; Jia, Gan; Wu, Xiaohong; Huang, Youju; Gao, Peng; Ye, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kinetically matched C-N coupling toward efficient urea electrosynthesis enabled on copper single-atom alloy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical C-N coupling from CO2 and NO3-, driven by renewable electricity, toward urea synthesis is an appealing alternative for Bosch-Meiser urea production. However, the unmatched kinetics in CO2 and NO3- reduction reactions and the complexity of C- and N-species involved in the co-reduction render the challenge of C-N coupling, leading to the low urea yield rate and Faradaic efficiency. Here, we report a single-atom copper-alloyed Pd catalyst (Pd4Cu1) that can achieve highly efficient C-N coupling toward urea electrosynthesis. The reduction kinetics of CO2 and NO3- is regulated and matched by steering Cu doping level and Pd4Cu1/FeNi(OH)2 interface. Charge-polarized Pd delta--Cu delta+ dual-sites stabilize the key *CO and *NH2 intermediates to promote C-N coupling. The synthesized Pd4Cu1-FeNi(OH)2 composite catalyst achieves a urea yield rate of 436.9 mmol gcat.-1 h-1 and Faradaic efficiency of 66.4%, as well as a long cycling stability of 1000 h. In-situ spectroscopic results and theoretical calculation reveal that atomically dispersed Cu in Pd lattice promotes the deep reduction of NO3- to *NH2, and the Pd-Cu dual-sites lower the energy barrier of the pivotal C-N coupling between *NH2 and *CO. The synthesis of urea by electrochemically converting the waste of nitrate and carbon dioxide is an interesting approach, but currently still restricted to low urea yield rate and Faradaic efficiency. Here, the authors report an efficient copper single-atom alloy electrocatalyst toward urea electrosynthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6994, "DOI": "10.1038/s41467-023-42794-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42794-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001127178400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, WH; Sankar, M; Beale, AM; He, Q; Kiely, CJ; Bruijnincx, PCA; Weckhuysen, BM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Wenhao; Sankar, Meenakshisundaram; Beale, Andrew M.; He, Qian; Kiely, Christopher J.; Bruijnincx, Pieter C. A.; Weckhuysen, Bert M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performing and stable supported nullo-alloys for the catalytic hydrogenation of levulinic acid to γ-valerolactone", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic hydrogenation of levulinic acid, a key platform molecule in many biorefinery schemes, into gamma-valerolactone is considered as one of the pivotal reactions to convert lignocellulose-based biomass into renewable fuels and chemicals. Here we report on the development of highly active, selective and stable supported metal catalysts for this reaction and on the beneficial effects of metal nullo-alloying. Bimetallic random alloys of gold-palladium and ruthenium-palladium supported on titanium dioxide are prepared with a modified metal impregnation method. Gold-palladium/titanium dioxide shows a marked, similar to 27-fold increase in activity (that is, turnover frequency of 0.1 s(-1)) compared with its monometallic counterparts. Although ruthenium-palladium/titanium dioxide is not only exceptionally active (that is, turnover frequency of 0.6 s(-1)), it shows excellent, sustained selectivity to g-valerolactone (99%). The dilution and isolation of ruthenium by palladium is thought to be responsible for this superior catalytic performance. Alloying, furthermore, greatly improves the stability of both supported nullo-alloy catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6540, "DOI": "10.1038/ncomms7540", "DOI Link": "http://dx.doi.org/10.1038/ncomms7540", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, C; Reeves, PJ; Jacquet, Q; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Chao; Reeves, Philip J.; Jacquet, Quentin; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Behavior during Electrochemical Cycling of Ni-Rich Cathode Materials for Li-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although layered lithium nickel-rich oxides have become the state-of-the-art cathode materials for lithium-ion batteries in electric vehicle (EV) applications, they can suffer from rapid performance failure-particularly when operated under conditions of stress (temperature, high voltage)-the underlying mechanisms of which are not fully understood. This essay aims to connect electrochemical performance with changes in structure during cycling. First, structural properties of LiNiO2 are compared to the substituted Ni-rich compounds NMCs (LiNixMnyCo1-x-yO2) and NCAs (LiNixCoyAl1-x-yO2). Particular emphasis is placed on decoupling intrinsic behavior and extrinsic two-phase reactions observed during initial cycles, as well as after extensive cycling for NMC and NCA cathodes. The need to revisit the various high-voltage structural changes that occur in LiNiO2 with modern characterization tools is highlighted to aid the understanding of the accelerated degradation for Ni-rich cathodes at high voltages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003404, "DOI": "10.1002/aenm.202003404", "DOI Link": "http://dx.doi.org/10.1002/aenm.202003404", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600496800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Tan, P; Ma, X; Wang, DY; Jin, XY; Liu, Y; Xu, B; Qiao, L; Qiu, CR; Wang, B; Zhao, WG; Wei, CJ; Song, KX; Guo, HS; Li, XD; Li, SA; Wei, XY; Chen, LQ; Xu, Z; Li, F; Tian, H; Zhang, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xin; Tan, Peng; Ma, Xue; Wang, Danyang; Jin, Xinyu; Liu, Yao; Xu, Bin; Qiao, Liao; Qiu, Chaorui; Wang, Bo; Zhao, Weigang; Wei, Chaojie; Song, Kexin; Guo, Haisheng; Li, Xudong; Li, Sean; Wei, Xiaoyong; Chen, Long-Qing; Xu, Zhuo; Li, Fei; Tian, Hao; Zhang, Shujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric crystals with giant electro-optic property enabling ultracompact Q-switches", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Relaxor-lead titanate (PbTiO3) crystals, which exhibit extremely high piezoelectricity, are believed to possess high electro-optic (EO) coefficients. However, the optical transparency of relaxor-PbTiO3 crystals is severely reduced as a result of light scattering and reflection by domain walls, limiting electro-optic applications. Through synergistic design of a ferroelectric phase, crystal orientation, and poling technique, we successfully removed all light-scattering domain walls and achieved an extremely high transmittance of 99.6% in antireflection film-coated crystals, with an ultrahigh EO coefficient r(33) of 900 picometers per volt (pm V-1), >30 times as high as that of conventionally used EO crystals. Using these crystals, we fabricated ultracompact EO Q-switches that require very low driving voltages, with superior performance to that of commercial Q-switches. Development of these materials is important for the portability and low driving voltage of EO devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2022, "Volume": 376, "Issue": 6591, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn7711", "DOI Link": "http://dx.doi.org/10.1126/science.abn7711", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788553700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, PF; Zou, XL; Zhang, ZP; Hong, M; Shi, JP; Chen, SL; Shu, JP; Zhao, LY; Jiang, SL; Zhou, XB; Huan, YH; Xie, CY; Gao, P; Chen, Q; Zhang, Q; Liu, ZF; Zhang, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Pengfei; Zou, Xiaolong; Zhang, Zhepeng; Hong, Min; Shi, Jianping; Chen, Shulin; Shu, Jiapei; Zhao, Liyun; Jiang, Shaolong; Zhou, Xiebo; Huan, Yahuan; Xie, Chunyu; Gao, Peng; Chen, Qing; Zhang, Qing; Liu, Zhongfan; Zhang, Yanfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Batch production of 6-inch uniform monolayer molybdenum disulfide catalyzed by sodium in glass", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer transition metal dichalcogenides (TMDs) have become essential two-dimensional materials for their perspectives in engineering next-generation electronics. For related applications, the controlled growth of large-area uniform monolayer TMDs is crucial, while it remains challenging. Herein, we report the direct synthesis of 6-inch uniform monolayer molybdenum disulfide on the solid soda-lime glass, through a designed face-to-face metalprecursor supply route in a facile chemical vapor deposition process. We find that the highly uniform monolayer film, with the composite domains possessing an edge length larger than 400 mu m, can be achieved within a quite short time of 8 min. This highly efficient growth is proven to be facilitated by sodium catalysts that are homogenously distributed in glass, according to our experimental facts and density functional theory calculations. This work provides insights into the batch production of highly uniform TMD films on the functional glass substrate with the advantages of low cost, easily transferrable, and compatible with direct applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 979, "DOI": "10.1038/s41467-018-03388-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03388-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426899300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JW; Yuan, CQ; Jiao, TF; Xing, RR; Yang, MY; Adams, DJ; Yan, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Jingwen; Yuan, Chengqian; Jiao, Tifeng; Xing, Ruirui; Yang, Mengyao; Adams, Dave J.; Yan, Xuehai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Antimicrobial Biometallohydrogels Based on Amino Acid Coordinated Self-Assembly", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is a real need for new antibiotics against self-evolving bacteria. One option is to use biofriendly broad-spectrum and mechanically tunable antimicrobial hydrogels that can combat multidrug-resistant microbes. Whilst appealing, there are currently limited options. Herein, broad-spectrum antimicrobial biometallohydrogels based on the self-assembly and local mineralization of Ag+-coordinated Fmoc-amino acids are reported. Such biometallohydrogels have the advantages of localized delivery and sustained release, reduced drug dosage and toxicity yet improved bioavailability, prolonged drug effect, and tunable mechanical strength. Furthermore, they can directly interact with the cell walls and membrane, resulting in the detachment of the plasma membrane and leakage of the cytoplasm. This leads to cell death, triggering a significant antibacterial effect against both Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) bacteria in cells and mice. This study paves the way for developing a multifunctional integration platform based on simple biomolecules coordinated self-assembly toward a broad range of biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 16, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1907309, "DOI": "10.1002/smll.201907309", "DOI Link": "http://dx.doi.org/10.1002/smll.201907309", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511243900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, YS; Zhang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Y. S.; Zhang, W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling of heat transfer, fluid flow and solidification microstructure of nickel-base superalloy fabricated by laser powder bed fusion", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser-Powder Bed Fusion (L-PBF), an additive manufacturing process, produces a distinctive microstructure that closely resembles the weld metal microstructure but at a much finer scale. The solidification parameters, particularly temperature gradient and solidification rate, are important to study the as-built microstructure. In the present study, a computational framework with meso-scale resolution is developed for L-PBF of Inconel (R) 718 (IN718), a Ni-base superalloy. The framework combines a powder packing model based on Discrete Element Method and a 3-D transient heat and fluid flow simulation. The latter, i.e., the molten pool model, captures the interaction between laser beam and individual powder particles including free surface evolution, surface tension and evaporation. The solidification parameters, calculated from the temperature fields, are used to assess the solidification morphology and grain size using existing theoretical models. The IN718 coupon built by L-PBF are characterized using optical and scanning electron microscopies. The experimental data of molten pool size and solidification microstructure are compared to the corresponding simulation results. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 350, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 12, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 178, "End Page": 188, "Article Number": null, "DOI": "10.1016/j.addma.2016.05.003", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2016.05.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suo, LM; Xue, WJ; Gobet, M; Greenbaum, SG; Wang, C; Chen, YM; Yang, WL; Li, YX; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suo, Liumin; Xue, Weijiang; Gobet, Mallory; Greenbaum, Steve G.; Wang, Chao; Chen, Yuming; Yang, Wanlu; Li, Yangxing; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has gravimetric capacity similar to 10x that of graphite which incentivizes rechargeable Li metal batteries (RLMB) development. A key factor that limits practical use of RLMB is morphological instability of Li metal anode upon electrodeposition, reflected by the uncontrolled area growth of solid-electrolyte interphase that traps cyclable Li, quantified by the Coulombic in-efficiency (CI). Here we show that CI decreases approximately exponentially with increasing donatable fluorine concentration of the electrolyte. By using up to 7 m of Li bis(fluorosulfonyl) imide in fluoroethylene carbonate, where both the solvent and the salt donate F, we can significantly suppress anode porosity and improve the Coulombic efficiency to 99.64%. The electrolyte demonstrates excellent compatibility with 5-V LiNi0.5Mn1.5O4 cathode and Al current collector beyond 5 V. As a result, an RLMB full cell with only 1.4x excess lithium as the anode was demonstrated to cycle above 130 times, at industrially significant loading of 1.83 mAh/cm(2) and 0.36 C. This is attributed to the formation of a protective LiF nullolayer, which has a wide bandgap, high surface energy, and small Burgers vector, making it ductile at room temperature and less likely to rupture in electrodeposition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2018, "Volume": 115, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1156, "End Page": 1161, "Article Number": null, "DOI": "10.1073/pnas.1712895115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1712895115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424191300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Teng, J; Liu, P; Hirata, A; Ma, E; Zhang, Z; Chen, MW; Han, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lihua; Teng, Jiao; Liu, Pan; Hirata, Akihiko; Ma, En; Zhang, Ze; Chen, Mingwei; Han, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain rotation mediated by grain boundary dislocations in nullocrystalline platinum", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Grain rotation is a well-known phenomenon during high (homologous) temperature deformation and recrystallization of polycrystalline materials. In recent years, grain rotation has also been proposed as a plasticity mechanism at low temperatures (for example, room temperature for metals), especially for nullocrystalline grains with diameter d less than similar to 15 nm. Here, in tensile-loaded Pt thin films under a high-resolution transmission electron microscope, we show that the plasticity mechanism transitions from cross-grain dislocation glide in larger grains (d> 6 nm) to a mode of coordinated rotation of multiple grains for grains with d< 6 nm. The mechanism underlying the grain rotation is dislocation climb at the grain boundary, rather than grain boundary sliding or diffusional creep. Our atomic-scale images demonstrate directly that the evolution of the misorientation angle between neighbouring grains can be quantitatively accounted for by the change of the Frank-Bilby dislocation content in the grain boundary.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 632, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4402, "DOI": "10.1038/ncomms5402", "DOI Link": "http://dx.doi.org/10.1038/ncomms5402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340618900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, P; Jiang, L; Wang, F; Deng, KJ; Lv, KL; Zhang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Peng; Jiang, Liang; Wang, Fan; Deng, Kejian; Lv, Kangle; Zhang, Zehui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performance of a cobalt-nitrogen complex for the reduction and reductive coupling of nitro compounds into amines and their derivatives", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Replacement of precious noble metal catalysts with low-cost, non-noble heterogeneous catalysts for chemoselective reduction and reductive coupling of nitro compounds holds tremendous promise for the clean synthesis of nitrogencontaining chemicals. We report a robust cobalt-nitrogen/carbon (Co-N-x/C-800-AT) catalyst for the reduction and reductive coupling of nitro compounds into amines and their derivates. The Co-N-x/C-800-AT catalyst was prepared by the pyrolysis of cobalt phthalocyanine-silica colloid composites and the subsequent removal of silica template and cobalt nulloparticles. The Co-N-x/C-800-AT catalyst showed extremely high activity, chemoselectivity, and stability toward the reduction of nitro compounds with H2, affording full conversion and > 97% selectivity in water after 1.5 hours at 110 degrees C and under a H2 pressure of 3.5 bar for all cases. The hydrogenation of nitrobenzene over the Co-N-x/C-800-AT catalyst can even be smoothly performed under very mild conditions (40 degrees C and a H2 pressure of 1 bar) with an aniline yield of 98.7%. Moreover, the Co-N-x/C-800-AT catalyst has high activity toward the transfer hydrogenation of nitrobenzene into aniline and the reductive coupling of nitrobenzene into other derivates with high yields. These processes were carried out in an environmentally friendly manner without base and ligands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601945", "DOI": "10.1126/sciadv.1601945", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601945", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397039500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZH; Shi, CC; Chen, AT; Li, YK; Chen, S; Sun, D; Wang, CS; Liu, ZF; Wang, Q; Huang, JY; Yue, YM; Zhang, SF; Liu, ZC; Xu, YZ; Su, J; Zhou, Y; Wen, SF; Yan, CZ; Shi, YS; Deng, X; Jiang, L; Su, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhenhua; Shi, Congcan; Chen, Aotian; Li, Yike; Chen, Shuang; Sun, Dong; Wang, Changshun; Liu, Zhufeng; Wang, Qi; Huang, Jianyu; Yue, Yamei; Zhang, Shanfei; Liu, Zichuan; Xu, Yizhuo; Su, Jin; Zhou, Yan; Wen, Shifeng; Yan, Chunze; Shi, Yusheng; Deng, Xu; Jiang, Lei; Su, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Scale, Abrasion-Resistant, and Solvent-Free Superhydrophobic Objects Fabricated by a Selective Laser Sintering 3D Printing Strategy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manufacturing abrasion-resistant superhydrophobic matters is challenging due to the fragile feature of the introduced micro-/nulloscale surface roughness. Besides the long-term durability, large scale at meter level, and 3D complex structures are of great importance for the superhydrophobic objects used across diverse industries. Here it is shown that abrasion-resistant, half-a-meter scaled superhydrophobic objects can be one-step realized by the selective laser sintering (SLS) 3D printing technology using hydrophobic-fumed-silica (HFS)/polymer composite grains. The HFS grains serve as the hydrophobic guests while the sintered polymeric network provides the mechanical strength, leading to low-adhesion, intrinsic superhydrophobic objects with desired 3D structures. It is found that as-printed structures remained anti-wetting capabilities even after undergoing different abrasion tests, including knife cutting test, rude file grinding test, 1000 cycles of sandpaper friction test, tape test and quicksand impacting test, illustrating their abrasion-resistant superhydrophobic stability. This strategy is applied to manufacture a shell of the unmanned aerial vehicle and an abrasion-resistant superhydrophobic shoe, showing the industrial customization of large-scale superhydrophobic objects. The findings thus provide insight for designing intrinsic superhydrophobic objects via the SLS 3D printing strategy that might find use in drag-reduce, anti-fouling, or other industrial fields in harsh operating environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207183", "DOI Link": "http://dx.doi.org/10.1002/advs.202207183", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000915409400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aleid, S; Wu, MC; Li, RY; Wang, WB; Zhang, CL; Zhang, LB; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aleid, Sara; Wu, Mengchun; Li, Renyuan; Wang, Wenbin; Zhang, Chenlin; Zhang, Lianbin; Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Salting-in Effect of Zwitterionic Polymer Hydrogel Facilitates Atmospheric Water Harvesting", "Source Title": "ACS MATERIALS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hygroscopic salt-hydrogel composite sorbents have attracted increasing attention for atmospheric water harvesting (AWH) applications but suffer from the salting-out effect. To this end, this work, for the first time, discovers that the salting-in effect possessed by a zwitterionic hydrogel is able to facilitate water vapor sorption by the hygroscopic salt under otherwise the same conditions. For demonstration, zwitterionic hydrogel of poly-[2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (PDMAPS) was synthesized, and the hygroscopic salt of LiCl was embedded into PDMAPS to produce the salt-hydrogel composite. LiCl salt not only endows the sorbent with high water vapor sorption capacity but also facilitates the dissociation of self-association between cationic and anionic groups of PDMAPS. This salting-in effect was evaluated and confirmed experimentally and via density functional theory (DFT) calculation. The salting-in effect renders the zwitterionic hydrogel matrix with enhanced swelling capacity, leading to the sorbent's high AWH performance. With a photothermal component of CNT integrated into the sorbent, a fully solar energy-driven AWH process was demonstrated outdoors. This study provides important guidance to the design of hydrogel-based AWH sorbents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2022, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": 520, "Article Number": null, "DOI": "10.1021/acsmaterialslett.1c00723", "DOI Link": "http://dx.doi.org/10.1021/acsmaterialslett.1c00723", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766647000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZH; Yang, ZB; Ni, ZY; Shao, YC; Chen, B; Lin, YZ; Wei, HT; Yu, ZSJ; Holman, Z; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhenhua; Yang, Zhibin; Ni, Zhenyi; Shao, Yuchuan; Chen, Bo; Lin, Yuze; Wei, Haotong; Yu, Zhengshan J.; Holman, Zachary; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simplified interconnection structure based on C60/SnO2-xfor all-perovskite tandem solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiencies of all-perovskite tandem devices are improving quickly. However, their complex interconnection layer (ICL) structures-with typically four or more layers deposited by different processes-limit their prospects for applications. Here, we report an ICL in all-perovskite tandem cells consisting merely of a fullerene layer and a SnO2-x(0 < x < 1) layer. The C(60)layer is unintentionally n-doped by iodine ions from the perovskite and thus acts as an effective electron collecting layer. The SnO(2-x)layer, formed by the incomplete oxidization of tin (x = 1.76), has ambipolar carrier transport property enabled by the presence of a large density of Sn2+. The C-60/SnO1.76ICL forms Ohmic contacts with both wide and narrow bandgap perovskite subcells with low contact resistivity. The ICL boosts the efficiencies of small-area tandem cells (5.9 mm(2)) and large-area tandem cells (1.15 cm(2)) to 24.4% and 22.2%, respectively. The tandem cells remain 94% of its initial efficiency after continues 1-sun illumination for 1,000 h. Interconnecting layers are critical to the efficiency of tandem solar cells and a high number of layers is typically needed to ensure good electrical properties. Yu et. al show that a fullerene/tin-oxide interconnecting layer enables 24.4% efficiency and improved stability in all-perovskite tandem solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 657, "End Page": 665, "Article Number": null, "DOI": "10.1038/s41560-020-0657-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0657-y", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000550652600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, H; Huang, ZP; Lee, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Hee; Huang, Zhipeng; Lee, Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-assisted chemical etching of silicon and nullotechnology applications", "Source Title": "nullO TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon nullostructures exhibit promising application potentials in many fields in comparison with their bulk counterpart or other semiconductor nullostructures. Therefore, the exploiting of controllable fabrication methods of silicon nullostructures, and the exploring of further applications of silicon nullostructures gain extensive attentions. In this review, recent advances in metal-assisted chemical etching of silicon, a low-cost and versatile method enabling fine control over morphology feature of silicon nullostructures, are summarized. The overview concerning the applications of silicon nullostructures in the field of energy conversion and storage, and sensors are also presented. (C) 2014 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 304, "Article Number": null, "DOI": "10.1016/j.nulltod.2014.04.013", "DOI Link": "http://dx.doi.org/10.1016/j.nulltod.2014.04.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341481000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, R; Yang, LL; Zhang, Y; Wang, X; Lee, S; Zhang, T; Li, LX; Liang, ZF; Chen, JW; Li, JS; Moghaddam, AO; Llorca, J; Ib, M; Arbiol, J; Xu, Y; Cabot, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Ren; Yang, Linlin; Zhang, Yu; Wang, Xiang; Lee, Seungho; Zhang, Ting; Li, Lingxiao; Liang, Zhifu; Chen, Jingwei; Li, Junshan; Moghaddam, Ahmad Ostovari; Llorca, Jordi; Ib, Maria; Arbiol, Jordi; Xu, Ying; Cabot, Andreu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A CrMnFeCoNi high entropy alloy boosting oxygen evolution/reduction reactions and zinc-air battery performance", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of cost-effective, high-activity and stable bifunctional catalysts for the oxygen reduction and evolution reactions (ORR/OER) is essential for zinc-air batteries (ZABs) to reach the market. Such catalysts must contain multiple adsorption/reaction sites to cope with the high demands of reversible oxygen electrodes. Herein, we propose a high entropy alloy (HEA) based on relatively abundant elements as a bifunctional ORR/ OER catalyst. More specifically, we detail the synthesis of a CrMnFeCoNi HEA through a low-temperature solution-based approach. Such HEA displays superior OER performance with an overpotential of 265 mV at a current density of 10 mA/cm2, and a 37.9 mV/dec Tafel slope, well above the properties of a standard commercial catalyst based on RuO2. This high performance is partially explained by the presence of twinned defects, the incidence of large lattice distortions, and the electronic synergy between the different components, being Cr key to decreasing the energy barrier of the OER rate-determining step. CrMnFeCoNi also displays superior ORR performance with a half-potential of 0.78 V and an onset potential of 0.88 V, comparable with commercial Pt/C. The potential gap (Egap) between the OER overpotential and the ORR half-potential of CrMnFeCoNi is just 0.734 V. Taking advantage of these outstanding properties, ZABs are assembled using the CrMnFeCoNi HEA as air cathode and a zinc foil as the anode. The assembled cells provide an open-circuit voltage of 1.489 V, i.e. 90% of its theoretical limit (1.66 V), a peak power density of 116.5 mW/cm2, and a specific capacity of 836 mAh/g that stays stable for more than 10 days of continuous cycling, i.e. 720 cycles @ 8 mA/cm2 and 16.6 days of continuous cycling, i.e. 1200 cycles @ 5 mA/cm2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 58, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 287, "End Page": 298, "Article Number": null, "DOI": "10.1016/j.ensm.2023.03.022", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2023.03.022", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967601700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, HB; Li, YQ; Kim, J; Takei, T; Wang, ZL; Xu, XT; Wang, J; Bando, Y; Kang, YM; Tang, J; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Haibo; Li, Yunqi; Kim, Jeonghun; Takei, Toshiaki; Wang, Zhongli; Xu, Xingtao; Wang, Jie; Bando, Yoshio; Kang, Yong-Mook; Tang, Jing; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-50 nm Iron-Nitrogen-Doped Hollow Carbon Sphere-Encapsulated Iron Carbide nulloparticles as Efficient Oxygen Reduction Catalysts", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sub-50 nm iron-nitrogen-doped hollow carbon sphere-encapsulated iron carbide nulloparticles (Fe3C-Fe,N/C) are synthesized by using a triblock copolymer of poly(styrene-b-2-vinylpyridine-b-ethylene oxide) as a soft template. Their typical features, including a large surface area (879.5 m(2) g(-1)), small hollow size (approximate to 16 nm), and nitrogen-doped mesoporous carbon shell, and encapsulated Fe3C nulloparticles generate a highly active oxygen reduction reaction (ORR) performance. Fe3C-Fe,N/C hollow spheres exhibit an ORR performance comparable to that of commercially available 20 wt% Pt/C in alkaline electrolyte, with a similar half-wave potential, an electron transfer number close to 4, and lower H2O2 yield of less than 5%. It also shows noticeable ORR catalytic activity under acidic conditions, with a high half-wave potential of 0.714 V, which is only 59 mV lower than that of 20 wt% Pt/C. Moreover, Fe3C-Fe,N/C has remarkable long-term durability and tolerance to methanol poisoning, exceeding Pt/C regardless of the electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800120, "DOI": "10.1002/advs.201800120", "DOI Link": "http://dx.doi.org/10.1002/advs.201800120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439842100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XP; Li, Z; Zhang, Y; Chen, M; Liu, T; Xiao, CX; Gao, DP; Patel, JB; Kuciauskas, D; Magomedov, A; Scheidt, RA; Wang, XM; Harvey, SP; Dai, ZH; Zhang, CL; Morales, D; Pruett, H; Wieliczka, BM; Kirmani, AR; Padture, NP; Graham, KR; Yan, YF; Nazeeruddin, MK; McGehee, MD; Zhu, ZL; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaopeng; Li, Zhen; Zhang, Yi; Chen, Min; Liu, Tuo; Xiao, Chuanxiao; Gao, Danpeng; Patel, Jay B.; Kuciauskas, Darius; Magomedov, Artiom; Scheidt, Rebecca A.; Wang, Xiaoming; Harvey, Steven P.; Dai, Zhenghong; Zhang, Chunlei; Morales, Daniel; Pruett, Henry; Wieliczka, Brian M.; Kirmani, Ahmad R.; Padture, Nitin P.; Graham, Kenneth R.; Yan, Yanfa; Nazeeruddin, Mohammad Khaja; McGehee, Michael D.; Zhu, Zonglong; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co-deposition of hole-selective contact and absorber for improving the processability of perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simplifying the manufacturing processes of renewable energy technologies is crucial to lowering the barriers to commercialization. In this context, to improve the manufacturability of perovskite solar cells (PSCs), we have developed a one-step solution-coating procedure in which the hole-selective contact and perovskite light absorber spontaneously form, resulting in efficient inverted PSCs. We observed that phosphonic or carboxylic acids, incorporated into perovskite precursor solutions, self-assemble on the indium tin oxide substrate during perovskite film processing. They form a robust self-assembled monolayer as an excellent hole-selective contact while the perovskite crystallizes. Our approach solves wettability issues and simplifies device fabrication, advancing the manufacturability of PSCs. Our PSC devices with positive-intrinsic-negative (p-i-n) geometry show a power conversion efficiency of 24.5% and retain >90% of their initial efficiency after 1,200 h of operating at the maximum power point under continuous illumination. The approach shows good generality as it is compatible with different self-assembled monolayer molecular systems, perovskites, solvents and processing methods. Improving the manufacturability of perovskite solar cells is key to their deployment. Zheng et al. report a one-step deposition of the hole-selective and absorber layers that addresses wettability issues and simplifies the fabrication process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 462, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01227-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01227-6", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950511100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, PK; Quan, X; Nie, XW; Zhao, K; Liu, YM; Chen, S; Yu, HT; Chen, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Peike; Quan, Xie; Nie, Xiaowa; Zhao, Kun; Liu, Yanming; Chen, Shuo; Yu, Hongtao; Chen, Jingguang G. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal single-site catalyst design for electrocatalytic production of hydrogen peroxide at industrial-relevant currents", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct hydrogen peroxide electrosynthesis offers a sustainable alternative to the traditional energy-intensive anthraquinone technology. Here, the authors report a scalable cobalt single-site catalyst for hydrogen peroxide synthesis at industrial-relevant currents in acidic, neutral or alkaline electrolyte. Direct hydrogen peroxide (H2O2) electrosynthesis via the two-electron oxygen reduction reaction is a sustainable alternative to the traditional energy-intensive anthraquinone technology. However, high-performance and scalable electrocatalysts with industrial-relevant production rates remain to be challenging, partially due to insufficient atomic level understanding in catalyst design. Here we utilize theoretical approaches to identify transition-metal single-site catalysts for two-electron oxygen reduction using the *OOH binding energy as a descriptor. The theoretical predictions are then used as guidance to synthesize the desired cobalt single-site catalyst with a O-modified Co-(pyrrolic N)(4) configuration that can achieve industrial-relevant current densities up to 300 mA cm(-)(2) with 96-100% Faradaic efficiencies for H2O2 production at a record rate of 11,527 mmol h(-)(1) g(cat)(-)(1). Here, we show the feasibility and versatility of metal single-site catalyst design using various commercial carbon and cobalt phthalocyanine as starting materials and the high applicability for H2O2 electrosynthesis in acidic, neutral and alkaline electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 172, "DOI": "10.1038/s41467-023-35839-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35839-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955726400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, C; Sun, J; Li, B; Feng, Y; Sun, Y; Xiang, L; Wu, BH; Xiao, LL; Liu, BM; Petrovskii, VS; Liu, B; Zhang, JR; Wang, ZL; Li, HY; Zhang, L; Li, JJ; Wang, F; Goestl, R; Potemkin, II; Chen, D; Zeng, HB; Zhang, HJ; Liu, K; Herrmann, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Chao; Sun, Jing; Li, Bo; Feng, Yang; Sun, Yao; Xiang, Li; Wu, Baiheng; Xiao, Lingling; Liu, Baimei; Petrovskii, Vladislav S.; Liu, Bin; Zhang, Jinrui; Wang, Zili; Li, Hongyan; Zhang, Lei; Li, Jingjing; Wang, Fan; Goestl, Robert; Potemkin, Igor I.; Chen, Dong; Zeng, Hongbo; Zhang, Hongjie; Liu, Kai; Herrmann, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-strong bio-glue from genetically engineered polypeptides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomedical glues often face a challenge in providing strong adhesion and providing remodelling capabilities. Here the authors report on the development of a biocompatible and biodegradable protein-based coacervate adhesive and demonstrate application in haemostasis and wound healing using pig models. The development of biomedical glues is an important, yet challenging task as seemingly mutually exclusive properties need to be combined in one material, i.e. strong adhesion and adaption to remodeling processes in healing tissue. Here, we report a biocompatible and biodegradable protein-based adhesive with high adhesion strengths. The maximum strength reaches 16.5 +/- 2.2 MPa on hard substrates, which is comparable to that of commercial cyanoacrylate superglue and higher than other protein-based adhesives by at least one order of magnitude. Moreover, the strong adhesion on soft tissues qualifies the adhesive as biomedical glue outperforming some commercial products. Robust mechanical properties are realized without covalent bond formation during the adhesion process. A complex consisting of cationic supercharged polypeptides and anionic aromatic surfactants with lysine to surfactant molar ratio of 1:0.9 is driven by multiple supramolecular interactions enabling such strong adhesion. We demonstrate the glue's robust performance in vitro and in vivo for cosmetic and hemostasis applications and accelerated wound healing by comparison to surgical wound closures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3613, "DOI": "10.1038/s41467-021-23117-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23117-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687325400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lum, GZ; Ye, Z; Dong, XG; Marvi, H; Erin, O; Hu, WQ; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lum, Guo Zhan; Ye, Zhou; Dong, Xiaoguang; Marvi, Hamid; Erin, Onder; Hu, Wenqi; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape-programmable magnetic soft matter", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape-programmable matter is a class of active materials whose geometry can be controlled to potentially achieve mechanical functionalities beyond those of traditional machines. Among these materials, magnetically actuated matter is particularly promising for achieving complex time-varying shapes at small scale (overall dimensions smaller than 1 cm). However, previous work can only program these materials for limited applications, as they rely solely on human intuition to approximate the required magnetization profile and actuating magnetic fields for their materials. Here, we propose a universal programming methodology that can automatically generate the required magnetization profile and actuating fields for soft matter to achieve new time-varying shapes. The universality of the proposed method can therefore inspire a vast number of miniature soft devices that are critical in robotics, smart engineering surfaces and materials, and biomedical devices. Our proposed method includes theoretical formulations, computational strategies, and fabrication procedures for programming magnetic soft matter. The presented theory and computational method are universal for programming 2D or 3D time-varying shapes, whereas the fabrication technique is generic only for creating planar beams. Based on the proposed programming method, we created a jellyfish-like robot, a spermatozoid-like undulating swimmer, and an artificial cilium that couldmimic the complex beating patterns of its biological counterpart.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 538, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2016, "Volume": 113, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "E6007", "End Page": "E6015", "Article Number": null, "DOI": "10.1073/pnas.1608193113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1608193113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384886900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, HL; Yao, YX; Li, SC; Wu, GL; Zhao, B; Zhou, XD; Dupont, RL; Kara, UI; Zhou, YM; Xi, SB; Liu, B; Che, RC; Zhang, JC; Xu, HB; Adera, S; Wu, RB; Wang, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Hualiang; Yao, Yuxing; Li, Shucong; Wu, Guanglei; Zhao, Biao; Zhou, Xiaodi; Dupont, Robert L.; Kara, Ufuoma I.; Zhou, Yimin; Xi, Shibo; Liu, Bo; Che, Renchao; Zhang, Jincang; Xu, Hongbin; Adera, Solomon; Wu, Renbing; Wang, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Staggered circular nulloporous graphene converts electromagnetic waves into electricity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electromagnetic (EM) energy released by electronic devices in the environment is largely wasted and contributes to EM pollution. Here, the authors report the synthesis of staggered circular nulloporous graphene enabling the absorption and conversion of EM waves into electricity via the thermoelectric effect. Harvesting largely ignored and wasted electromagnetic (EM) energy released by electronic devices and converting it into direct current (DC) electricity is an attractive strategy not only to reduce EM pollution but also address the ever-increasing energy crisis. Here we report the synthesis of nulloparticle-templated graphene with monodisperse and staggered circular nullopores enabling an EM-heat-DC conversion pathway. We experimentally and theoretically demonstrate that this staggered nulloporous structure alters graphene's electronic and phononic properties by synergistically manipulating its intralayer nullostructures and interlayer interactions. The staggered circular nulloporous graphene exhibits an anomalous combination of properties, which lead to an efficient absorption and conversion of EM waves into heat and in turn an output of DC electricity through the thermoelectric effect. Overall, our results advance the fundamental understanding of the structure-property relationships of ordered nulloporous graphene, providing an effective strategy to reduce EM pollution and generate electric energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1982, "DOI": "10.1038/s41467-023-37436-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37436-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980800100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "King, NP; Bale, JB; Sheffler, W; McNamara, DE; Gonen, S; Gonen, T; Yeates, TO; Baker, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "King, Neil P.; Bale, Jacob B.; Sheffler, William; McNamara, Dan E.; Gonen, Shane; Gonen, Tamir; Yeates, Todd O.; Baker, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accurate design of co-assembling multi-component protein nullomaterials", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The self-assembly of proteins into highly ordered nulloscale architectures is a hallmark of biological systems. The sophisticated functions of these molecular machines have inspired the development of methods to engineer self-assembling protein nullostructures; however, the design of multi-component protein nullomaterials with high accuracy remains an outstanding challenge. Here we report a computational method for designing protein nullomaterials in which multiple copies of two distinct subunits co-assemble into a specific architecture. We use the method to design five 24-subunit cage-like protein nullomaterials in two distinct symmetric architectures and experimentally demonstrate that their structures are in close agreement with the computational design models. The accuracy of the method and the number and variety of two-component materials that it makes accessible suggest a route to the construction of functional protein nullomaterials tailored to specific applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2014, "Volume": 510, "Issue": 7503, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature13404", "DOI Link": "http://dx.doi.org/10.1038/nature13404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336768900037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XH; Liu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xunhua; Liu, Yuanyue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of Selective Production of Hydrogen Peroxide by Electrochemical Oxygen Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen reduction reaction (ORR) is one of the most important electrochemical reactions. Starting from a common reaction intermediate *-O-OH, the ORR splits into two pathways, either producing hydrogen peroxide (H2O2) by breaking the *-O bond or leading to water formation by breaking the O-OH bond. However, it is puzzling why many catalysts, despite the strong thermodynamic preference for the O-OH breaking, exhibit high selectivity for hydrogen peroxide. Moreover, the selectivity is dependent on the potential and pH, which remain not understood. Here we develop an advanced first-principles model for effective calculation of the electrochemical reaction kinetics at the solid-water interface, which were not accessible by conventional models. Using this model to study representative catalysts for H2O2 production, we find that breaking the O-OH bond can have a higher energy barrier than breaking *-O, due to the rigidity of the O-OH bond. Importantly, we reveal that the selectivity dependence on potential and pH is rooted into the proton affinity to the former/later O in *-O-OH. For single cobalt atom catalyst, decreasing potential promotes proton adsorption to the former O, thereby increasing the H2O2 selectivity. In contrast, for the carbon catalyst, the proton prefers the latter O, resulting in a lower H2O2 selectivity in acid condition. These findings explain the experiments and highlight the kinetic origins of the selectivity. Our work improves the understanding of ORR by uncovering the proton affinity as a new factor and provides a new model to effectively simulate the atomic-level kinetics of heterogeneous electrochemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2021, "Volume": 143, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9423, "End Page": 9428, "Article Number": null, "DOI": "10.1021/jacs.1c02186", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c02186", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670429000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JY; Guo, P; Guo, ZY; Li, L; Sun, TR; Liu, DP; Tian, L; Zu, GQ; Xiong, LZ; Zhang, JH; Huang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Junyao; Guo, Pu; Guo, Ziyi; Li, Li; Sun, Tongrui; Liu, Dapeng; Tian, Li; Zu, Guoqing; Xiong, Lize; Zhang, Jianhua; Huang, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Retina-Inspired Artificial Synapses with Ultraviolet to Near-Infrared Broadband Responses for Energy-Efficient Neuromorphic Visual Systems", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neuromorphic visual system with image perception, memory, and preprocessing functions is expected to simulate basic features of the human retina. Organic optoelectronic synaptic transistors emulating biological synapses may be promising candidates for constructing neural morphological visual system. However, the sensing wavelength range of organic optoelectronic synaptic transistors usually limits their potential in artificial multispectral visual perception. Here, retina-inspired optoelectronic synaptic transistors that present broadband responses covering ultraviolet, visible, and near-infrared regions are demonstrated, which leverage the wide-range photoresponsive charge trapping layer and the heterostructure formed between PbS quantum dots and organic semiconductor. Simplified neuromorphic visual arrays are developed to simulate comprehensive image perception, memory, and preprocessing functions. Benefitting from the flexibility of the charge trapping and organic semiconductor layers, a flexible neuromorphic visual array can be fabricated, having an ultralow power consumption of 0.55 fJ per event under a low operating voltage of -0.01 V. More significantly, an accelerating image preprocessing effect can be observed in a wide wavelength range even beyond the perception range of the human visual system, due to the gate-adjustable synaptic plasticity. These devices are highly promising for implementing neuromorphic visual systems with broadband perception, increasing image processing efficiency, and promoting the development of artificial vision.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 33, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202302885", "DOI Link": "http://dx.doi.org/10.1002/adfm.202302885", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973185300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, JB; Zhao, B; Xiang, HM; Dai, FZ; Liu, Y; Zhang, R; Zhou, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Jiabin; Zhao, Biao; Xiang, Huimin; Dai, Fu-Zhi; Liu, Yi; Zhang, Rui; Zhou, Yanchun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy spinel ferrites MFe2O4 (M = Mg, Mn, Fe, Co, Ni, Cu, Zn) with tunable electromagnetic properties and strong microwave absorption", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferrites are the most widely used microwave absorbing materials to deal with the threat of electromagnetic (EM) pollution. However, the lack of sufficient dielectric loss capacity is the main challenge that limits their applications. To cope with this challenge, three high-entropy (HE) spinel-type ferrite ceramics including (Mg0.2Mn0.2Fe0.2Co0.2Ni0.2)Fe2O4, (Mg0.2Fe0.2Co0.2Ni0.2Cu0.2)Fe2O4, and (Mg0.2Fe0.2Co0.2Ni0.2Zn0.2)Fe2O4 were designed and successfully prepared through solid state synthesis. The results show that all three HE MFe2O4 samples exhibit synergetic dielectric loss and magnetic loss. The good magnetic loss ability is due to the presence of magnetic components; while the enhanced dielectric properties are attributed to nullo-domain, hopping mechanism of resonullce effect and HE effect. Among three HE spinels, (Mg0.2Mn0.2Fe0.2Co0.2Ni0.2)Fe2O4 shows the best EM wave absorption performance, e.g., its minimum reflection loss (RLmin) reaches -35.10 dB at 6.78 GHz with a thickness of 3.5 mm, and the optimized effective absorption bandwidth (EAB) is 7.48 GHz from 8.48 to 15.96 GHz at the thickness of 2.4 mm. Due to the easy preparation and strong EM dissipation ability, HE MFe2O4 are promising as a new type of EM absorption materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 11, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 754, "End Page": 768, "Article Number": null, "DOI": "10.1007/s40145-022-0569-3", "DOI Link": "http://dx.doi.org/10.1007/s40145-022-0569-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783826800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ringe, S; Clark, EL; Resasco, J; Walton, A; Seger, B; Bell, AT; Chan, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ringe, Stefan; Clark, Ezra L.; Resasco, Joaquin; Walton, Amber; Seger, Brian; Bell, Alexis T.; Chan, Karen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding cation effects in electrochemical CO2 reduction", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-liquid interface engineering has recently emerged as a promising technique to optimize the activity and product selectivity of the electrochemical reduction of CO2. In particular, the cation identity and the interfacial electric field have been shown to have a particularly significant impact on the activity of desired products. Using a combination of theoretical and experimental investigations, we show the cation size and its resultant impact on the interfacial electric field to be the critical factor behind the ion specificity of electrochemical CO2 reduction. We present a multi-scale modeling approach that combines size-modified Poisson-Boltzmann theory with ab initio simulations of field effects on critical reaction intermediates. The model shows an unprecedented quantitative agreement with experimental trends in cation effects on CO production on Ag, C2 production on Cu, CO vibrational signatures on Pt and Cu as well as Au(111) single crystal experimental double layer capacitances. The insights obtained represent quantitative evidence for the impact of cations on the interfacial electric field. Finally, we present design principles to increase the activity and selectivity of any field-sensitive electrochemical process based on the surface charging properties: the potential of zero charge, the ion size, and the double layer capacitance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 12, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3001, "End Page": 3014, "Article Number": null, "DOI": "10.1039/c9ee01341e", "DOI Link": "http://dx.doi.org/10.1039/c9ee01341e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489897600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ferreira, RTL; Amatte, IC; Dutra, TA; Bürger, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luiz Ferreira, Rafael Thiago; Amatte, Igor Cardoso; Dutra, Thiago Assis; Burger, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental characterization and micrography of 3D printed PLA and PLA reinforced with short carbon fibers", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this work is the mechanical characterization of materials produced by 3D printing based on fused filament fabrication (FFF, analogous to FDM (R)). The materials chosen are a polylactic acid (PLA) and a PLA reinforced with short carbon fibers in a weight fraction of 15% (PLA+CF). In view of the FFF nature, which produces specimens layer by layer and following predefined orientations, the main assumption considered is that the materials behave like laminates formed by orthotropic layers. If the 3D printing is made in the 1 - 2 plane, where 1 is the deposition direction and 2 is a direction perpendicular to 1, the mechanical properties obtained are the tensile moduli E-1 and E-2, the Poisson ratios v(12) and v(21), the shear modulus G(12) and related strength properties. For this purpose, only unidirectional or specially oriented specimens are used. After tests up to material failure, scanning electron microscopy (SEM) is employed to observe fracture surfaces. It was noticed that, in the microstructure of the PLA+CF, the short carbon fibers stay highly oriented with the material deposition direction in the FFF specimens. This fact, and the also observed length of the fibers, explains differences in material properties encountered among the performed experiments. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2017, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 88, "End Page": 100, "Article Number": null, "DOI": "10.1016/j.compositesb.2017.05.013", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2017.05.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407539100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miao, J; Slone, CE; Smith, TM; Niu, C; Bei, H; Ghazisaeidi, M; Pharr, GM; Mills, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miao, J.; Slone, C. E.; Smith, T. M.; Niu, C.; Bei, H.; Ghazisaeidi, M.; Pharr, G. M.; Mills, M. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The equiatomic NiCoCr alloy exhibits an excellent combination of strength and ductility, even greater than the FeNiCrCoMn high entropy alloy, and also displays a simultaneous increase in strength and ductility with decreasing the testing temperature. To systemically investigate the origin of the exceptional properties of NiCoCr alloy, which are related to the evolution of the deformation substructure with strain, interrupted tensile testing was conducted on the equiatomic NiCoCr single-phase solid solution alloy at both cryogenic and room temperatures at five different plastic strain levels of 1.5%, 6.5%, 29%, 50% and 76%. The evolution of deformation substructure was examined using electron backscatter diffraction (EBSD), transmission Kikuchi diffraction (TKD), conventional transmission electron microscopy (CTEM), diffraction contrast imaging using STEM (DCI-STEM) and atomic resolution scanning transmission electron microscopy. While the deformation substructure mainly consisted of planar dislocation slip and the dissociation of dislocations into stacking faults at small strain levels (<= 6.5%), at larger strain levels, additional substructures including nullotwins and a new phase with hexagonal close packed (HCP) lamellae also appeared. The volume fraction of the HCP lamellae increases with increasing deformation, especially at cryogenic temperature. First principles calculations at 0 K indicate that the HCP phase is indeed energetically favorable relative to FCC for this composition. The effects of the nullotwin and HCP lamellar structures on hardening rate and ductility at both cryogenic and room temperature are qualitatively discussed. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2017, "Volume": 132, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 35, "End Page": 48, "Article Number": null, "DOI": "10.1016/j.actamat.2017.04.033", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.04.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405881500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Merchant, A; Batzner, S; Schoenholz, SS; Aykol, M; Cheon, G; Cubuk, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Merchant, Amil; Batzner, Simon; Schoenholz, Samuel S.; Aykol, Muratahan; Cheon, Gowoon; Cubuk, Ekin Dogus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling deep learning for materials discovery", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel functional materials enable fundamental breakthroughs across technological applications from clean energy to information processing1-11. From microchips to batteries and photovoltaics, discovery of inorganic crystals has been bottlenecked by expensive trial-and-error approaches. Concurrently, deep- learning models for language, vision and biology have showcased emergent predictive capabilities with increasing data and computation12-14. Here we show that graph networks trained at scale can reach unprecedented levels of generalization, improving the efficiency of materials discovery by an order of magnitude. Building on 48,000 stable crystals identified in continuing studies15-17, improved efficiency enables the discovery of 2.2 million structures below the current convex hull, many of which escaped previous human chemical intuition. Our work represents an order-of-magnitude expansion in stable materials known to humanity. Stable discoveries that are on the final convex hull will be made available to screen for technological applications, as we demonstrate for layered materials and solid-electrolyte candidates. Of the stable structures, 736 have already been independently experimentally realized. The scale and diversity of hundreds of millions of first-principles calculations also unlock modelling capabilities for downstream applications, leading in particular to highly accurate and robust learned interatomic potentials that can be used in condensed-phase molecular-dynamics simulations and high-fidelity zero-shot prediction of ionic conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2023, "Volume": 624, "Issue": 7990, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 80, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06735-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06735-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169148800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, YZ; Liu, C; Huang, R; Zhang, H; Li, XB; de Arquer, FPG; Liu, Z; Li, YY; Zhang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Yunzhou; Liu, Cheng; Huang, Rui; Zhang, Hui; Li, Xiaobao; Garcia de Arquer, F. Pelayo; Liu, Zhi; Li, Youyong; Zhang, Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Introducing Bronsted acid sites to accelerate the bridging-oxygen-assisted deprotonation in acidic water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While water electrolysis devices represent a technology for renewable energy, there are few stable catalysts that survive the acidic conditions. Here, authors enhance acidic oxygen evolution by introducing strong Bronsted acid sites into RuO2 to accelerate bridging-oxygen-assisted deprotonation. Oxygen evolution reaction (OER) consists of four sequential proton-coupled electron transfer steps, which suffer from sluggish kinetics even on state-of-the-art ruthenium dioxide (RuO2) catalysts. Understanding and controlling the proton transfer process could be an effective strategy to improve OER performances. Herein, we present a strategy to accelerate the deprotonation of OER intermediates by introducing strong Bronsted acid sites (e.g. tungsten oxides, WOx) into the RuO2. The Ru-W binary oxide is reported as a stable and active iridium-free acidic OER catalyst that exhibits a low overpotential (235 mV at 10 mA cm(-2)) and low degradation rate (0.014 mV h(-1)) over a 550-hour stability test. Electrochemical studies, in-situ near-ambient pressure X-ray photoelectron spectroscopy and density functional theory show that the W-O-Ru Bronsted acid sites are instrumental to facilitate proton transfer from the oxo-intermediate to the neighboring bridging oxygen sites, thus accelerating bridging-oxygen-assisted deprotonation OER steps in acidic electrolytes. The universality of the strategy is demonstrated for other Ru-M binary metal oxides (M = Cr, Mo, Nb, Ta, and Ti).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4871, "DOI": "10.1038/s41467-022-32581-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32581-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842231900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, YR; Li, X; Li, HB; Zhang, WK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Yurui; Li, Xun; Li, Hongbin; Zhang, Wenke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying thiol-gold interactions towards the efficient strength control", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The strength of the thiol-gold interactions provides the basis to fabricate robust self-assembled monolayers for diverse applications. Investigation on the stability of thiol-gold interactions has thus become a hot topic. Here we use atomic force microscopy to quantify the stability of individual thiol-gold contacts formed both by isolated single thiols and in self-assembled monolayers on gold surface. Our results show that the oxidized gold surface can enhance greatly the stability of gold-thiol contacts. In addition, the shift of binding modes from a coordinate bond to a covalent bond with the change in environmental pH and interaction time has been observed experimentally. Furthermore, isolated thiol-gold contact is found to be more stable than that in self-assembled monolayers. Our findings revealed mechanisms to control the strength of thiol-gold contacts and will help guide the design of thiol-gold contacts for a variety of practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 513, "Times Cited, All Databases": 586, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4348, "DOI": "10.1038/ncomms5348", "DOI Link": "http://dx.doi.org/10.1038/ncomms5348", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340615500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Setvin, M; Franchini, C; Hao, XF; Schmid, M; Janotti, A; Kaltak, M; Van de Walle, CG; Kresse, G; Diebold, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Setvin, Martin; Franchini, Cesare; Hao, Xianfeng; Schmid, Michael; Janotti, Anderson; Kaltak, Merzuk; Van de Walle, Chris G.; Kresse, Georg; Diebold, Ulrike", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct View at Excess Electrons in TiO2 Rutile and Anatase", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A combination of scanning tunneling microscopy and spectroscopy and density functional theory is used to characterize excess electrons in TiO2 rutile and anatase, two prototypical materials with identical chemical composition but different crystal lattices. In rutile, excess electrons can localize at any lattice Ti atom, forming a small polaron, which can easily hop to neighboring sites. In contrast, electrons in anatase prefer a free-carrier state, and can only be trapped near oxygen vacancies or form shallow donor states bound to Nb dopants. The present study conclusively explains the differences between the two polymorphs and indicates that even small structural variations in the crystal lattice can lead to a very different behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2014, "Volume": 113, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86402, "DOI": "10.1103/PhysRevLett.113.086402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.086402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341292300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, MM; Wang, ZM; Sun, K; Wang, A; Zhao, YY; Yuan, QX; Wang, RB; Raj, J; Wu, JJ; Jiang, JC; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Mengmeng; Wang, Zeming; Sun, Kang; Wang, Ao; Zhao, Yuying; Yuan, Qixin; Wang, Ruibin; Raj, Jithu; Wu, Jingjie; Jiang, Jianchun; Wang, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-B-OH Site-Activated Graphene Quantum Dots for Boosting Electrochemical Hydrogen Peroxide Production", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon materials are considered promising 2/4 e(-) oxygen reduction reaction (ORR) electrocatalysts for synthesizing H2O2/H2O via regulating heteroatom dopants and functionalization. Here, various doped and functionalized graphene quantum dots (GQDs) are designed to reveal the crucial active sites of carbon materials for ORR to produce H2O2. Density functional theory (DFT) calculations predict that the edge structure involving edge N, B dopant pairs and further -OH functionalization to the B (N-B-OH) is an active center for 2e(-) ORR. To verify the above predication, GQDs with an enriched density of N-B-OH (NBO-GQDs) are designed and synthesized by the hydrothermal reaction of -NH2 edge-functionalized GQDs with H3BO3 forming six-member heterocycle containing the N-B-OH structure. When dispersed on conductive carbon substrates, the NBO-GQDs show H2O2 selectivity of over 90% at 0.7 -0.8 V versus reversible hydrogen electrode in the alkaline solution in a rotating ring-disk electrode setup. The selectivity retains 90% of the initial value after 12 h stability test. In a flow cell setup, the H2O2 production rate is up to 709 mmol g(catalyst)(-1) h(-1), superior to most reported carbon- and metal-based electrocatalysts. This work provides molecular insight into the design and formulation of highly efficient carbon-based catalysts for sustainable H2O2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209086", "DOI Link": "http://dx.doi.org/10.1002/adma.202209086", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952075600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZW; Shang, JZ; Jiang, CY; Rasmita, A; Gao, WB; Yu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhaowei; Shang, Jingzhi; Jiang, Chongyun; Rasmita, Abdullah; Gao, Weibo; Yu, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Photoluminescence Probing of Ferromagnetism in Monolayer Two-Dimensional CrBr3", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin magnets are the key element to build up spintronics based on two-dimensional materials. The surface nature of two-dimensional ferromagnet opens up opportunities to improve the device performance efficiently. Here, we report the intrinsic ferromagnetism in atomically thin monolayer CrBr3, directly probed by polarization resolved magneto-photoluminescence. The spontaneous magnetization persists in monolayer CrBr3 with a Curie temperature of 34 K. The development of magnons by the thermal excitation is in line with the spin-wave theory. We attribute the layer-number-dependent hysteresis loops in thick layers to the magnetic domain structures. As a stable monolayer material in air, CrBr3 provides a convenient platform for fundamental physics and pushes the potential applications of the two-dimensional ferromagnetism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 19, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3138, "End Page": 3142, "Article Number": null, "DOI": "10.1021/acs.nullolett.9b00553", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.9b00553", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467781900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tapia-Ruiz, N; Armstrong, AR; Alptekin, H; Amores, MA; Au, HT; Barker, J; Boston, R; Brant, WR; Brittain, JM; Chen, Y; Chhowalla, M; Choi, YS; Costa, SIR; Ribadeneyra, MC; Cussen, SA; Cussen, EJ; David, WIF; Desai, A; Dickson, SAM; Eweka, E; Forero-Saboya, JD; Grey, CP; Griffin, JM; Gross, P; Hua, X; Irvine, JTS; Johansson, P; Jones, MO; Karlsmo, M; Kendrick, E; Kim, E; Kolosov, O; Li, ZN; Mertens, SFL; Mogensen, R; Monconduit, L; Morris, RE; Naylor, AJ; Nikman, S; O'Keefe, CA; Ould, DMC; Palgrave, RG; Poizot, P; Ponrouch, A; Renault, S; Reynolds, EM; Rudola, A; Sayers, R; Scanlon, DO; Sen, S; Seymour, VR; Silván, B; Sougrati, MT; Stievano, L; Stone, GS; Thomas, C; Titirici, MM; Tong, JC; Wood, TJ; Wright, DS; Younesi, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tapia-Ruiz, Nuria; Armstrong, A. Robert; Alptekin, Hande; Amores, Marco A.; Au, Heather; Barker, Jerry; Boston, Rebecca; Brant, William R.; Brittain, Jake M.; Chen, Yue; Chhowalla, Manish; Choi, Yong-Seok; Costa, Sara I. R.; Crespo Ribadeneyra, Maria; Cussen, Serena A.; Cussen, Edmund J.; David, William I. F.; Desai, Aamod, V; Dickson, Stewart A. M.; Eweka, Emmanuel, I; Forero-Saboya, Juan D.; Grey, Clare P.; Griffin, John M.; Gross, Peter; Hua, Xiao; Irvine, John T. S.; Johansson, Patrik; Jones, Martin O.; Karlsmo, Martin; Kendrick, Emma; Kim, Eunjeong; Kolosov, Oleg, V; Li, Zhuangnull; Mertens, Stijn F. L.; Mogensen, Ronnie; Monconduit, Laure; Morris, Russell E.; Naylor, Andrew J.; Nikman, Shahin; O'Keefe, Christopher A.; Ould, Darren M. C.; Palgrave, R. G.; Poizot, Philippe; Ponrouch, Alexandre; Renault, Steven; Reynolds, Emily M.; Rudola, Ashish; Sayers, Ruth; Scanlon, David O.; Sen, S.; Seymour, Valerie R.; Silvan, Begona; Sougrati, Moulay Tahar; Stievano, Lorenzo; Stone, Grant S.; Thomas, Chris, I; Titirici, Maria-Magdalena; Tong, Jincheng; Wood, Thomas J.; Wright, Dominic S.; Younesi, Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2021 roadmap for sodium-ion batteries", "Source Title": "JOURNAL OF PHYSICS-ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing concerns regarding the sustainability of lithium sources, due to their limited availability and consequent expected price increase, have raised awareness of the importance of developing alternative energy-storage candidates that can sustain the ever-growing energy demand. Furthermore, limitations on the availability of the transition metals used in the manufacturing of cathode materials, together with questionable mining practices, are driving development towards more sustainable elements. Given the uniformly high abundance and cost-effectiveness of sodium, as well as its very suitable redox potential (close to that of lithium), sodium-ion battery technology offers tremendous potential to be a counterpart to lithium-ion batteries (LIBs) in different application scenarios, such as stationary energy storage and low-cost vehicles. This potential is reflected by the major investments that are being made by industry in a wide variety of markets and in diverse material combinations. Despite the associated advantages of being a drop-in replacement for LIBs, there are remarkable differences in the physicochemical properties between sodium and lithium that give rise to different behaviours, for example, different coordination preferences in compounds, desolvation energies, or solubility of the solid-electrolyte interphase inorganic salt components. This demands a more detailed study of the underlying physical and chemical processes occurring in sodium-ion batteries and allows great scope for groundbreaking advances in the field, from lab-scale to scale-up. This roadmap provides an extensive review by experts in academia and industry of the current state of the art in 2021 and the different research directions and strategies currently underway to improve the performance of sodium-ion batteries. The aim is to provide an opinion with respect to the current challenges and opportunities, from the fundamental properties to the practical applications of this technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31503, "DOI": "10.1088/2515-7655/ac01ef", "DOI Link": "http://dx.doi.org/10.1088/2515-7655/ac01ef", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677849300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XY; Qin, JQ; Xue, YN; Yu, PF; Zhang, B; Wang, LM; Liu, RP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xinyu; Qin, Jiaqian; Xue, Yanull; Yu, Pengfei; Zhang, Bing; Wang, Limin; Liu, Riping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of aspect ratio and surface defects on the photocatalytic activity of ZnO nullorods", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ZnO, aside from TiO2, has been considered as a promising material for purification and disinfection of water and air, and remediation of hazardous waste, owing to its high activity, environment-friendly feature and lower cost. However, their poor visible light utilization greatly limited their practical applications. Herein, we demonstrate the fabrication of different aspect ratios of the ZnO nullorods with surface defects by mechanical-assisted thermal decomposition method. The experiments revealed that ZnO nullorods with higher aspect ratio and surface defects show significantly higher photocatalytic performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 878, "Times Cited, All Databases": 918, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4596, "DOI": "10.1038/srep04596", "DOI Link": "http://dx.doi.org/10.1038/srep04596", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333798100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rahman, MT; Rahman, MS; Kumar, H; Kim, K; Kim, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rahman, Muhammad Toyabur; Rahman, Md Sazzadur; Kumar, Hitendra; Kim, Keekyoung; Kim, Seonghwan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Reinforced Highly Stretchable and Durable Conductive Hydrogel-Based Triboelectric nullogenerator for Biomotion Sensing and Wearable Human-Machine Interfaces", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible triboelectric nullogenerators (TENGs) with multifunctional sensing capabilities offer an elegant solution to address the growing energy supply challenges for wearable smart electronics. Herein, a highly stretchable and durable electrode for wearable TENG is developed using ZIF-8 as a reinforcing nullofiller in a hydrogel with LiCl electrolyte. ZIF-8 nullocrystals improve the hydrogel's mechanical properties by forming hydrogen bonds with copolymer chains, resulting in 2.7 times greater stretchability than pure hydrogel. The hydrogel electrode is encapsulated by microstructured silicone layers that act as triboelectric materials and prevent water loss from the hydrogel. Optimized ZIF-8-based hydrogel electrodes enhance the output performance of TENG through the dynamic balance of electric double layers (EDLs) during contact electrification. Thus, the as-fabricated TENG delivers an excellent power density of 3.47 Wm(-2), which is 3.2 times higher than pure hydrogel-based TENG. The developed TENG can scavenge biomechanical energy even at subzero temperatures to power small electronics and serve as excellent self-powered pressure sensors for human-machine interfaces (HMIs). The nullocomposite hydrogel-based TENG can also function as a wearable biomotion sensor, detecting body movements with high sensitivity. This study demonstrates the significant potential of utilizing ZIF-8 reinforced hydrogel as an electrode for wearable TENGs in energy harvesting and sensor technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 33, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202303471", "DOI Link": "http://dx.doi.org/10.1002/adfm.202303471", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001031831800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZW; Ge, BH; Li, W; Lin, SQ; Shen, JW; Chang, YJ; Hanus, R; Snyder, GJ; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhiwei; Ge, Binghui; Li, Wen; Lin, Siqi; Shen, Jiawen; Chang, Yunjie; Hanus, Riley; Snyder, G. Jeffrey; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To minimize the lattice thermal conductivity in thermoelectrics, strategies typically focus on the scattering of low-frequency phonons by interfaces and high-frequency phonons by point defects. In addition, scattering of mid-frequency phonons by dense dislocations, localized at the grain boundaries, has been shown to reduce the lattice thermal conductivity and improve the thermoelectric performance. Here we propose a vacancy engineering strategy to create dense dislocations in the grains. In Pb(1-x)Sb2(x/3)Se solid solutions, cation vacancies are intentionally introduced, where after thermal annealing the vacancies can annihilate through a number of mechanisms creating the desired dislocations homogeneously distributed within the grains. This leads to a lattice thermal conductivity as low as 0.4 Wm(-1) K-1 and a high thermoelectric figure of merit, which can be explained by a dislocation scattering model. The vacancy engineering strategy used here should be equally applicable for solid solution thermoelectrics and provides a strategy for improving zT.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13828, "DOI": "10.1038/ncomms13828", "DOI Link": "http://dx.doi.org/10.1038/ncomms13828", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391095300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, FS; Liu, GM; Zhan, JY; Jia, YT; Feng, ZH; Shen, BX; Shiju, NR; Zhang, LH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fengshou; Liu, Guomeng; Zhan, Jiayu; Jia, Yangting; Feng, Zhihao; Shen, Boxiong; Shiju, N. Raveendran; Zhang, Lu-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-driven electron enrichment of ultrafine PdAu nulloparticles for electrochemical CO2 reduction: High applicability of work function as an activity descriptor", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly coupled metal/dopant-incorporated carbon dyads provide a possibility to modulate the electron density of metallic materials by forming a rectifying interface, thus showing an enhanced activity in electrochemical CO2 reduction reaction (ECRR). However, understanding the promotion effects of dopants for ECRR is limited to the prediction by theoretical interpretation and case-by-case studies. Herein, we report the direct experimental evidence that the work function, regulated by single structural factor-dopant contents, is significantly correlated to the ECRR reaction activity and kinetics. We prepared a series of PdAu/NxC electrocatalysts composed of ultrafine (similar to 5.7 nm) PdAu bimetallic nulloparticles and tailorable N-doped carbon supports. The wide range of the amount of N dopants allowed the modification of the band gap of the carbon easily. Using ultraviolet photoelectron spectroscopy (UPS) measurements, we demonstrate that the reactivity and kinetics trends of the PdAu/NxC in the ECRR can be intrinsically correlated with the work function of the catalysts. PdAu/N7.50C electrocatalyst with the highest N contents displays a 100% CO2-to-CO conversion and high conversion efficiency over a wide potential window, superior over other reported PdAu catalysts. This work provides a novel way to boost ECRR performance by deliberately lowering the work function of the metal/carbon electrocatalysts through the enhancement by dopants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2023, "Volume": 338, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 122931, "DOI": "10.1016/j.apcatb.2023.122931", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2023.122931", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001144325700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rustomji, CS; Yang, Y; Kim, TK; Mac, J; Kim, YJ; Caldwell, E; Chung, H; Meng, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rustomji, Cyrus S.; Yang, Yangyuchen; Kim, Tae Kyoung; Mac, Jimmy; Kim, Young Jin; Caldwell, Elizabeth; Chung, Hyeseung; Meng, Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquefied gas electrolytes for electrochemical energy storage devices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical capacitors and lithium-ion batteries have seen little change in their electrolyte chemistry since their commercialization, which has limited improvements in device performance. Combining superior physical and chemical properties and a high dielectric-fluidity factor, the use of electrolytes based on solvent systems that exclusively use components that are typically gaseous under standard conditions show a wide potential window of stability and excellent performance over an extended temperature range. Electrochemical capacitors using difluoromethane show outstanding performance from -78 degrees to + 65 degrees C, with an increased operation voltage. The use of fluoromethane shows a high coulombic efficiency of similar to 97% for cycling lithium metal anodes, together with good cyclability of a 4-volt lithium cobalt oxide cathode and operation as low as -60 degrees C, with excellent capacity retention.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2017, "Volume": 356, "Issue": 6345, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaal4263", "DOI": "10.1126/science.aal4263", "DOI Link": "http://dx.doi.org/10.1126/science.aal4263", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404351500029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalaj, M; Cohen, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalaj, Mark; Cohen, Seth M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Postsynthetic Modification: An Enabling Technology for the Advancement of Metal-Organic Frameworks", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are a class of porous materials with immense chemical tunability derived from their organic and inorganic building blocks. Presynthetic approaches have been used to construct tailor-made MOFs, but with a rather restricted functional group scope limited by the typical MOF solvothermal synthesis conditions. Postsynthetic modification (PSM) of MOFs has matured into an alternative strategy to broaden the functional group scope of MOFs. PSM has many incarnations, but two main avenues include (1) covalent PSM, in which the organic linkers of the MOF are modified with a reagent resulting in new functional groups, and (2) coordinative PSM, where organic molecules containing metal ligating groups are introduced onto the inorganic secondary building units (SBUs) of the MOF. These methods have evolved from simple efforts to modifying MOFs to demonstrate proof-of-concept, to becoming key synthetic tools for advancing MOFs for a range of emerging applications, including selective gas sorption, catalysis, and drug delivery. Moreover, both covalent and coordinative PSM have been used to create hierarchal MOFs, MOF-based porous liquids, and other unusual MOF materials. This Outlook highlights recent reports that have extended the scope of PSM in MOFs, some seminal reports that have contributed to the advancement of PSM in MOFs, and our view on future directions of the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2020, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1046, "End Page": 1057, "Article Number": null, "DOI": "10.1021/acscentsci.0c00690", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c00690", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555422900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Filip, MR; Eperon, GE; Snaith, HJ; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filip, Marina R.; Eperon, Giles E.; Snaith, Henry J.; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steric engineering of metal-halide perovskites with tunable optical band gaps", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to their high energy-conversion efficiency and inexpensive fabrication routes, solar cells based on metal-organic halide perovskites have rapidly gained prominence as a disruptive technology. An attractive feature of perovskite absorbers is the possibility of tailoring their properties by changing the elemental composition through the chemical precursors. In this context, rational in silico design represents a powerful tool for mapping the vast materials landscape and accelerating discovery. Here we show that the optical band gap of metal-halide perovskites, a key design parameter for solar cells, strongly correlates with a simple structural feature, the largest metal-halide-metal bond angle. Using this descriptor we suggest continuous tunability of the optical gap from the mid-infrared to the visible. Precise band gap engineering is achieved by controlling the bond angles through the steric size of the molecular cation. On the basis of these design principles we predict novel low-gap perovskites for optimum photovoltaic efficiency, and we demonstrate the concept of band gap modulation by synthesising and characterising novel mixed-cation perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 851, "Times Cited, All Databases": 924, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5757, "DOI": "10.1038/ncomms6757", "DOI Link": "http://dx.doi.org/10.1038/ncomms6757", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347611700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LC; Liang, J; Yue, LC; Xu, ZQ; Dong, K; Liu, Q; Luo, YL; Li, TS; Cheng, XH; Cui, GW; Tang, B; Alshehri, AA; Alzahrani, KA; Guo, XD; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Longcheng; Liang, Jie; Yue, Luchao; Xu, Zhaoquan; Dong, Kai; Liu, Qian; Luo, Yonglan; Li, Tingshuai; Cheng, Xiaohong; Cui, Guanwei; Tang, Bo; Alshehri, Abdulmohsen Ali; Alzahrani, Khalid Ahmed; Guo, Xiaodong; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-doped carbon nullotubes supported CoSe2 nulloparticles: A highly efficient and stable catalyst for H2O2 electrosynthesis in acidic media", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic oxygen reduction reaction (ORR) provides an attractive alternative to anthraquinone process for H2O2 synthesis. Rational design of earth-abundant electrocatalysts for H2O2 synthesis via a two-electron ORR process in acids is attractive but still very challenging. In this work, we report that nitrogen-doped carbon nullotubes as a multi-functional support for CoSe2 nulloparticles not only keep CoSe2 nulloparticles well dispersed but alter the crystal structure, which in turn improves the overall catalytic behaviors and thereby renders high O-2-to-H2O2 conversion efficiency. In 0.1 M HClO4, such CoSe2@NCNTs hybrid delivers a high H2O2 selectivity of 93.2% and a large H2O2 yield rate of 172 ppm center dot h(-1) with excellent durability up to 24 h. Moreover, CoSe2@NCNTs performs effectively for organic dye degradation via electro-Fenton process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 304, "End Page": 309, "Article Number": null, "DOI": "10.1007/s12274-021-3474-0", "DOI Link": "http://dx.doi.org/10.1007/s12274-021-3474-0", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000644310800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YY; Hu, GK; Huang, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yangyang; Hu, Gengkai; Huang, Guoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A hybrid elastic metamaterial with negative mass density and tunable bending stiffness", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving vibration and/or wave attenuation with locally resonullt metamaterials has attracted a great deal of attention due to their frequency dependent negative effective mass density. Moreover, adaptive phononic crystals with shunted piezoelectric patches have also demonstrated a tunable wave attenuation mechanism by controlling electric circuits to achieve a negative effective stiffness. In this paper, we propose an adaptive hybrid meta-material that possesses both a negative mass density as well as an extremely tunable stiffness by properly utilizing both the mechanical and electric elements. A multi-physical analytical model is first developed to investigate and reveal the tunable wave manipulation abilities in terms of both the effective negative mass density and/or bending stiffness of the hybrid metamaterial. The programmed flexural wave manipulations, broad-band negative refraction and waveguiding are then illustrated through three-dimensional (3D) multi-physical numerical simulations in hybrid metamaterial plates. Our numerical results demonstrate that the flexural wave propagation can essentially be switched between ON/OFF states by connecting different shunting circuits. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 105, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 179, "End Page": 198, "Article Number": null, "DOI": "10.1016/j.jmps.2017.05.009", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2017.05.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404698800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YW; Wang, XY; Duan, DL; He, CH; Ma, J; Zhang, WQ; Liu, HJ; Long, R; Li, ZB; Kong, TT; Loh, XJ; Song, L; Ye, EN; Xiong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yawen; Wang, Xinyu; Duan, Delong; He, Chaohua; Ma, Jun; Zhang, Wenqing; Liu, Hengjie; Long, Ran; Li, Zibiao; Kong, Tingting; Loh, Xian Jun; Song, Li; Ye, Enyi; Xiong, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural Reconstruction of Cu2O Superparticles toward Electrocatalytic CO2 Reduction with High C2+ Products Selectivity", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structural reconstruction is a process commonly observed for Cu-based catalysts in electrochemical CO2 reduction. The Cu-based precatalysts with structural complexity often undergo sophisticated structural reconstruction processes, which may offer opportunities for enhancing the electrosynthesis of multicarbon products (C2+ products) but remain largely uncertain due to various new structural features possibly arising during the processes. In this work, the Cu2O superparticles with an assembly structure are demonstrated to undergo complicated structure evolution under electrochemical reduction condition, enabling highly selective CO2-to-C2+ products conversion in electrocatalysis. As revealed by electron microscopic characterization together with in situ X-ray absorption spectroscopy and Raman spectroscopy, the building blocks inside the superparticle fuse to generate numerous grain boundaries while those in the outer shell detach to form nullogap structures that can efficiently confine OH- to induce high local pH. Such a combination of unique structural features with local reaction environment offers two important factors for facilitating C-C coupling. Consequently, the Cu2O superparticle-derived catalyst achieves high faradaic efficiencies of 53.2% for C2H4 and 74.2% for C2+ products, surpassing the performance of geometrically simpler Cu2O cube-derived catalyst and most reported Cu electrocatalysts under comparable conditions. This work provides insights for rationally designing highly selective CO2 reduction electrocatalysts by controlling structural reconstruction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105292, "DOI": "10.1002/advs.202105292", "DOI Link": "http://dx.doi.org/10.1002/advs.202105292", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776638800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XM; Tan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaoming; Tan, Xiaoli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant Strains in Non-Textured (Bi1/2Na1/2)TiO3-Based Lead-Free Ceramics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Giant electric-field-induced strain of 0.70%, corresponding to a d(33)* value of 1400 pm V-1, is observed in a lead-free (Bi1/2Na1/2) TiO3-based polycrystalline ceramic. This is comparable to the properties of single crystals. An in situ transmission electron microscopy study indicates that the excellent performance originates from phase transitions under the applied electric fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 526, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2016, "Volume": 28, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 574, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201503768", "DOI Link": "http://dx.doi.org/10.1002/adma.201503768", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368712900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YL; Tahini, HA; Hu, ZW; Dai, J; Chen, YB; Sun, HN; Zhou, W; Liu, ML; Smith, SC; Wang, HT; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yinlong; Tahini, Hassan A.; Hu, Zhiwei; Dai, Jie; Chen, Yubo; Sun, Hainull; Zhou, Wei; Liu, Meilin; Smith, Sean C.; Wang, Huanting; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unusual synergistic effect in layered Ruddlesden - Popper oxide enables ultrafast hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient electrocatalysts for hydrogen evolution reaction are key to realize clean hydrogen production through water splitting. As an important family of functional materials, transition metal oxides are generally believed inactive towards hydrogen evolution reaction, although many of them show high activity for oxygen evolution reaction. Here we report the remarkable electrocatalytic activity for hydrogen evolution reaction of a layered metal oxide, Ruddlesden-Popper-type Sr2RuO4 with alternative perovskite layer and rock-salt SrO layer, in an alkaline solution, which is comparable to those of the best electrocatalysts ever reported. By theoretical calculations, such excellent activity is attributed mainly to an unusual synergistic effect in the layered structure, whereby the (001) SrO-terminated surface cleaved in rock-salt layer facilitates a barrier-free water dissociation while the active apical oxygen site in perovskite layer promotes favorable hydrogen adsorption and evolution. Moreover, the activity of such layered oxide can be further improved by electrochemistry-induced activation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 149, "DOI": "10.1038/s41467-018-08117-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08117-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455473700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MK; Zhang, P; Qu, ZH; Yan, Y; Lai, C; Liu, TX; Zhang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingkai; Zhang, Peng; Qu, Zehua; Yan, Yan; Lai, Chao; Liu, Tianxi; Zhang, Shanqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive carbon nullofiber interpenetrated graphene architecture for ultra-stable sodium ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term stability and high-rate capability have been the major challenges of sodium-ion batteries. Layered electroactive materials with mechanically robust, chemically stable, electrically and ironically conductive networks can effectively address these issues. Herein we have successfully directed carbon nullofibers to vertically penetrate through graphene sheets, constructing robust carbon nullofiber interpenetrated graphene architecture. Molybdenum disulfide nulloflakes are then grown in situ alongside the entire framework, yielding molybdenum disulfide@carbon nullofiber interpenetrated graphene structure. In such a design, carbon nullofibers prevent the restacking of graphene sheets and provide ample space between graphene sheets, enabling a strong structure that maintains exceptional mechanical integrity and excellent electrical conductivity. The as-prepared sodium ion battery delivers outstanding electrochemical performance and ultrahigh stability, achieving a remarkable specific capacity of 598 mAh g(-1), long-term cycling stability up to 1000 cycles, and an excellent rate performance even at a high current density up to 10 A g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3917, "DOI": "10.1038/s41467-019-11925-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11925-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483305400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, F; Liu, ZC; Deng, BW; Dong, YY; Zhu, XJ; Huang, C; Lu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Fei; Liu, Zhicheng; Deng, Baiwen; Dong, Yanyan; Zhu, Xiaojie; Huang, Chuang; Lu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lotus Leaf-Derived Gradient Hierarchical Porous C/MoS2 Morphology Genetic Composites with Wideband and Tunable Electromagnetic Absorption Performance", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsLotus leaf-derived gradient hierarchical porous C/MoS2 morphology genetic composites nullocomposites were fabricated.Excellent electromagnetic absorption performance was achieved with min of -50.1 dB and EBW of 6.0 GHz.RLA brand-new dielectric sum-quotient model was proposed and corresponded well to the experimental results. AbstractInspired by the nature, lotus leaf-derived gradient hierarchical porous C/MoS2 morphology genetic composites (GHPCM) were successfully fabricated through an in situ strategy. The biological microstructure of lotus leaf was well preserved after treatment. Different pores with gradient pore sizes ranging from 300 to 5 mu m were hierarchically distributed in the composites. In addition, the surface states of lotus leaf resulted in the Janus-like morphologies of MoS2. The GHPCM exhibit excellent electromagnetic wave absorption performance, with the minimum reflection loss of -50.1 dB at a thickness of 2.4 mm and the maximum effective bandwidth of 6.0 GHz at a thickness of 2.2 mm. The outstanding performance could be attributed to the synergy of conductive loss, polarization loss, and impedance matching. In particularly, we provided a brand-new dielectric sum-quotient model to analyze the electromagnetic performance of the non-magnetic material system. It suggests that the specific sum and quotient of permittivity are the key to keep reflection loss below -10 dB within a certain frequency range. Furthermore, based on the concept of material genetic engineering, the dielectric constant could be taken into account to seek for suitable materials with designable electromagnetic absorption performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 43, "DOI": "10.1007/s40820-020-00568-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00568-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607061500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Srivastava, YK; Ako, RT; Gupta, M; Bhaskaran, M; Sriram, S; Singh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Srivastava, Yogesh Kumar; Ako, Rajour Tanyi; Gupta, Manoj; Bhaskaran, Madhu; Sriram, Sharath; Singh, Ranjan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Terahertz sensing of 7 nm dielectric film with bound states in the continuum metasurfaces", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fingerprint spectral response of several materials with terahertz electromagnetic radiation indicates that terahertz technology is an effective tool for sensing applications. However, sensing few nullometer thin-films of dielectrics with much longer terahertz waves (1 THz = 0.3 mm) is challenging. Here, we demonstrate a quasibound state in the continuum (BIC) resonullce for sensing of a nullometer scale thin analyte deposited on a flexible metasurface. The large sensitivity originates from the strong local field confinement of the quasi-BIC Fano resonullce state and extremely low absorption loss of a low-index cyclic olefin copolymer substrate. A minimum thickness of 7 nm thin-film of germanium is sensed on the metasurface, which corresponds to a deep subwavelength scale of lambda/43 000, where lambda is the resonullce wavelength. The low-loss, flexible, and large mechanical strength of the quasi-BIC microstructured metamaterial sensor could be an ideal platform for developing ultrasensitive wearable terahertz sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2019, "Volume": 115, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 151105, "DOI": "10.1063/1.5110383", "DOI Link": "http://dx.doi.org/10.1063/1.5110383", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492035500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thiel, L; Wang, Z; Tschudin, MA; Rohner, D; Gutiérrez-Lezama, I; Ubrig, N; Gibertini, M; Giannini, E; Morpurgo, AF; Maletinsky, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thiel, L.; Wang, Z.; Tschudin, M. A.; Rohner, D.; Gutierrez-Lezama, I.; Ubrig, N.; Gibertini, M.; Giannini, E.; Morpurgo, A. F.; Maletinsky, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing magnetism in 2D materials at the nulloscale with single-spin microscopy", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of ferromagnetism in two-dimensional (2D) van der Waals (vdW) crystals has generated widespread interest. Making further progress in this area requires quantitative knowledge of the magnetic properties of vdW magnets at the nulloscale. We used scanning single-spin magnetometry based on diamond nitrogen-vacancy centers to image the magnetization, localized defects, and magnetic domains of atomically thin crystals of the vdW magnet chromium(III) iodide (CrI3). We determined themagnetization of CrI3 monolayers to be approximate to 16 Bohr magnetons per square nullometer, with comparable values in samples with odd numbers of layers; however, the magnetization vanishes when the number of layers is even. We also found that structural modifications can induce switching between ferromagnetic and antiferromagnetic interlayer ordering. These results demonstrate the benefit of using single-spin scanning magnetometry to study the magnetism of 2D vdW magnets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2019, "Volume": 364, "Issue": 6444, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 973, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav6926", "DOI Link": "http://dx.doi.org/10.1126/science.aav6926", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471079600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fuller, EJ; El Gabaly, F; Léonard, F; Agarwal, S; Plimpton, SJ; Jacobs-Gedrim, RB; James, CD; Marinella, MJ; Talin, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fuller, Elliot J.; El Gabaly, Farid; Leonard, Franois; Agarwal, Sapan; Plimpton, Steven J.; Jacobs-Gedrim, Robin B.; James, Conrad D.; Marinella, Matthew J.; Talin, A. Alec", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Li-Ion Synaptic Transistor for Low Power Analog Computing", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonvolatile redox transistors(NVRTs) based upon Li-ion battery materials are demonstrated as memory elements for neuromorphic computer architectures with multi-level analog states, write linearity, low-voltage switching, and low power dissipation. Simulations of backpropagation using the device properties reach ideal classification accuracy. Physics-based simulations predict energy costs per write operation of < 10 aJ when scaled to 200 nm x 200 nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 476, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 29, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604310, "DOI": "10.1002/adma.201604310", "DOI Link": "http://dx.doi.org/10.1002/adma.201604310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392730500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bruns, OT; Bischof, TS; Harris, DK; Franke, D; Shi, YX; Riedemann, L; Bartelt, A; Jaworski, FB; Carr, JA; Rowlands, CJ; Wilson, MWB; Chen, O; Wei, H; Hwang, GW; Montana, DM; Coropceanu, I; Achorn, OB; Kloepper, J; Heeren, J; So, PTC; Fukumura, D; Jensen, KF; Jain, RK; Bawendi, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bruns, Oliver T.; Bischof, Thomas S.; Harris, Daniel K.; Franke, Daniel; Shi, Yanxiang; Riedemann, Lars; Bartelt, Alexander; Jaworski, Frank B.; Carr, Jessica A.; Rowlands, Christopher J.; Wilson, Mark W. B.; Chen, Ou; Wei, He; Hwang, Gyu Weon; Montana, Daniel M.; Coropceanu, Igor; Achorn, Odin B.; Kloepper, Jonas; Heeren, Joerg; So, Peter T. C.; Fukumura, Dai; Jensen, Klavs F.; Jain, Rakesh K.; Bawendi, Moungi G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Next-generation in vivo optical imaging with short-wave infrared quantum dots", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For in vivo imaging, the short-wavelength infrared region (SWIR; 1,000-2,000 nm) provides several advantages over the visible and near-infrared regions: general lack of autofluorescence, low light absorption by blood and tissue, and reduced scattering. However, the lack of versatile and functional SWIR emitters has prevented the general adoption of SWIR imaging by the biomedical research community. Here, we introduce a class of high-quality SWIR-emissive indium-arsenide-based quantum dots that are readily modifiable for various functional imaging applications, and that exhibit narrow and size-tunable emission and a dramatically higher emission quantum yield than previously described SWIR probes. To demonstrate the unprecedented combination of deep penetration, high spatial resolution, multicolour imaging and fast acquisition speed afforded by the SWIR quantum dots, we quantified, in mice, the metabolic turnover rates of lipoproteins in several organs simultaneously and in real time as well as heartbeat and breathing rates in awake and unrestrained animals, and generated detailed three-dimensional quantitative flow maps of the mouse brain vasculature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 563, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 56, "DOI": "10.1038/s41551-017-0056", "DOI Link": "http://dx.doi.org/10.1038/s41551-017-0056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418855100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, CY; Fan, XL; Zhou, XQ; Chen, J; Wang, QC; Ma, L; Yang, CY; Hu, EY; Yang, XQ; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Chunyu; Fan, Xiulin; Zhou, Xiuquan; Chen, Ji; Wang, Qinchao; Ma, Lu; Yang, Chongyin; Hu, Enyuan; Yang, Xiao-Qing; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure and Interface Design Enable Stable Li-Rich Cathode", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-rich layered-oxide cathodes have the highest theoretical energy density among all the intercalated cathodes, which have attracted intense interests for high-energy Li-ion batteries. However, O3-structured layered-oxide cathodes suffer from a low initial Coulombic efficiency (CE), severe voltage fade, and poor cycling stability because of the continuous oxygen release, structural rearrangements due to irreversible transition-metal migration, and serious side reactions between the delithiated cathode and electrolyte. Herein, we report that these challenges are migrated by using a stable O2-structured Li1.2Ni0.13Co0.13Mn0.54-O-2 (O2-LR-NCM) and all-fluorinated electrolyte. The O2-LR-NCM can restrict the transition metals migrating into the Li layer, and the in situ formed fluorinated cathode-electrolyte interphase (CEI) on the surface of the O2-LR-NCM from the decomposition of all-fluorinated electrolyte during initial cycles effectively restrains the structure transition, suppresses the O-2 release, and thereby safeguards the transition metal redox couples, enabling a highly reversible and stable oxygen redox reaction. O2-LR-NCM in all fluorinated electrolytes achieves a high initial CE of 99.82%, a cycling CE of >99.9%, a high reversible capacity of 278 mAh/g, and high capacity retention of 83.3% after 100 cycles. The synergic design of electrolyte and cathode structure represents a promising direction to stabilize high-energy cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2020, "Volume": 142, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8918, "End Page": 8927, "Article Number": null, "DOI": "10.1021/jacs.0c02302", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c02302", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535252100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mase, K; Yoneda, M; Yamada, Y; Fukuzumi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Seawater usable for production and consumption of hydrogen peroxide as a solar fuel", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O-2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O-2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O-2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11470, "DOI": "10.1038/ncomms11470", "DOI Link": "http://dx.doi.org/10.1038/ncomms11470", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375456000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, C; Lee, J; Jung, SG; Park, T; Albarakati, S; Partridge, J; Field, MR; McCulloch, DG; Wang, L; Lee, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Cheng; Lee, Jinhwan; Jung, Soon-Gil; Park, Tuson; Albarakati, Sultan; Partridge, James; Field, Matthew R.; McCulloch, Dougal G.; Wang, Lan; Lee, Changgu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hard magnetic properties in nulloflake van der Waals Fe3GeTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional van der Waals materials have demonstrated fascinating optical and electrical characteristics. However, reports on magnetic properties and spintronic applications of van der Waals materials are scarce by comparison. Here, we report anomalous Hall effect measurements on single crystalline metallic Fe3GeTe2 nulloflakes with different thicknesses. These nulloflakes exhibit a single hard magnetic phase with a near square-shaped magnetic loop, large coercivity (up to 550 mT at 2 K), a Curie temperature near 200 K and strong perpendicular magnetic anisotropy. Using criticality analysis, the coupling length between van der Waals atomic layers in Fe3GeTe2 is estimated to be similar to 5 van der Waals layers. Furthermore, the hard magnetic behaviour of Fe3GeTe2 can be well described by a proposed model. The magnetic properties of Fe3GeTe2 highlight its potential for integration into van der Waals magnetic heterostructures, paving the way for spintronic research and applications based on these devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1554, "DOI": "10.1038/s41467-018-04018-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04018-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430389100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, CZ; Hao, L; Hussein, A; Young, P; Raymont, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Chunze; Hao, Liang; Hussein, Ahmed; Young, Philippe; Raymont, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced lightweight 316L stainless steel cellular lattice structures fabricated via selective laser melting", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper investigates the manufacturability and performance of advanced and lightweight stainless steel cellular lattice structures fabricated via selective laser melting (SLM). A unique cell type called gyroid is designed to construct periodic lattice structures and utilise its curved cell surface as a self-supported feature which avoids the building of support structures and reduces material waste and production time. The gyroid cellular lattice structures with a wide range of volume fraction were made at different orientations, showing it can reduce the constraints in design for the SLM and provide flexibility in selecting optimal manufacturing parameters. The lattice structures with different volume fraction were well manufactured by the SLM process to exhibit a good geometric agreement with the original CAD models. The strut of the SLM-manufactured lattice structures represents a rough surface and its size is slightly higher than the designed value. When the lattice structure was positioned with half of its struts at an angle of 0 degrees with respect to the building plane, which is considered as the worst building orientation for SLM, it was manufactured with well-defined struts and no defects or broken cells. The compression strength and modulus of the lattice structures increase with the increase in the volume fraction, and two equations based on Gibson-Ashby model have been established to predict their compression properties. (C) 2013 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 55, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 533, "End Page": 541, "Article Number": null, "DOI": "10.1016/j.matdes.2013.10.027", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2013.10.027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329118700063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weiss, C; Carriere, M; Fusco, L; Capua, I; Regla-Nava, JA; Pasquali, M; Scott, AA; Vitale, F; Unal, MA; Mattevi, C; Bedognetti, D; Merkoçi, A; Tasciotti, E; Yilmazer, A; Gogotsi, Y; Stellacci, F; Delogu, LG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weiss, Carsten; Carriere, Marie; Fusco, Laura; Capua, Ilaria; Regla-Nava, Jose Angel; Pasquali, Matteo; Scott, Ames A.; Vitale, Flavia; Unal, Mehmet Altay; Mattevi, Cecilia; Bedognetti, Davide; Merkoci, Arben; Tasciotti, Ennio; Yilmazer, Acelya; Gogotsi, Yury; Stellacci, Francesco; Delogu, Lucia Gemma", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward nullotechnology-Enabled Approaches against the COVID-19 Pandemic", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The COVID-19 outbreak has fueled a global demand for effective diagnosis and treatment as well as mitigation of the spread of infection, all through large-scale approaches such as specific alternative antiviral methods and classical disinfection protocols. Based on an abundance of engineered materials identifiable by their useful physicochemical properties through versatile chemical functionalization, nullotechnology offers a number of approaches to cope with this emergency. Here, through a multidisciplinary Perspective encompassing diverse fields such as virology, biology, medicine, engineering, chemistry, materials science, and computational science, we outline how nullotechnology-based strategies can support the fight against COVID-19, as well as infectious diseases in general, including future pandemics. Considering what we know so far about the life cycle of the virus, we envision key steps where nullotechnology could counter the disease. First, nulloparticles (NPs) can offer alternative methods to classical disinfection protocols used in healthcare settings, thanks to their intrinsic antipathogenic properties and/or their ability to inactivate viruses, bacteria, fungi, or yeasts either photothermally or via photocatalysis-induced reactive oxygen species (ROS) generation. nullotechnology tools to inactivate SARS-CoV-2 in patients could also be explored. In this case, nullomaterials could be used to deliver drugs to the pulmonary system to inhibit interaction between angiotensin-converting enzyme 2 (ACE2) receptors and viral S protein. Moreover, the concept of nulloimmunity by design can help us to design materials for immune modulation, either stimulating or suppressing the immune response, which would find applications in the context of vaccine development for SARS-CoV-2 or in counteracting the cytokine storm, respectively. In addition to disease prevention and therapeutic potential, nullotechnology has important roles in diagnostics, with potential to support the development of simple, fast, and cost-effective nullotechnology-based assays to monitor the presence of SARS-CoV-2 and related biomarkers. In summary, nullotechnology is critical in counteracting COVID-19 and will be vital when preparing for future pandemics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2020, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6383, "End Page": 6406, "Article Number": null, "DOI": "10.1021/acsnullo.0c03697", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c03697", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543744100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gorbachev, RV; Song, JCW; Yu, GL; Kretinin, AV; Withers, F; Cao, Y; Mishchenko, A; Grigorieva, IV; Novoselov, KS; Levitov, LS; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gorbachev, R. V.; Song, J. C. W.; Yu, G. L.; Kretinin, A. V.; Withers, F.; Cao, Y.; Mishchenko, A.; Grigorieva, I. V.; Novoselov, K. S.; Levitov, L. S.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detecting topological currents in graphene superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological materials may exhibit Hall-like currents flowing transversely to the applied electric field even in the absence of a magnetic field. In graphene superlattices, which have broken inversion symmetry, topological currents originating from graphene's two valleys are predicted to flow in opposite directions and combine to produce long-range charge neutral flow. We observed this effect as a nonlocal voltage at zero magnetic field in a narrow energy range near Dirac points at distances as large as several micrometers away from the nominal current path. Locally, topological currents are comparable in strength with the applied current, indicating large valley-Hall angles. The long-range character of topological currents and their transistor-like control by means of gate voltage can be exploited for information processing based on valley degrees of freedom.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2014, "Volume": 346, "Issue": 6208, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 448, "End Page": 451, "Article Number": null, "DOI": "10.1126/science.1254966", "DOI Link": "http://dx.doi.org/10.1126/science.1254966", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343822900037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Demirer, GS; Zhang, H; Matos, JL; Goh, NS; Cunningham, FJ; Sung, Y; Chang, R; Aditham, AJ; Chio, L; Cho, MJ; Staskawicz, B; Landry, MP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Demirer, Gozde S.; Zhang, Huan; Matos, Juliana L.; Goh, Natalie S.; Cunningham, Francis J.; Sung, Younghun; Chang, Roger; Aditham, Abhishek J.; Chio, Linda; Cho, Myeong-Je; Staskawicz, Brian; Landry, Markita P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High aspect ratio nullomaterials enable delivery of functional genetic material without DNA integration in mature plants", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Genetic engineering of plants is at the core of sustainability efforts, natural product synthesis and crop engineering. The plant cell wall is a barrier that limits the ease and throughput of exogenous biomolecule delivery to plants. Current delivery methods either suffer from host-range limitations, low transformation efficiencies, tissue damage or unavoidable DNA integration into the host genome. Here, we demonstrate efficient diffusion-based biomolecule delivery into intact plants of several species with pristine and chemically functionalized high aspect ratio nullomaterials. Efficient DNA delivery and strong protein expression without transgene integration is accomplished in Nicotiana benthamiana (Nb), Eruca sativa (arugula), Triticum aestivum (wheat) and Gossypium hirsutum (cotton) leaves and arugula protoplasts. We find that nullomaterials not only facilitate biomolecule transport into plant cells but also protect polynucleotides from nuclease degradation. Our work provides a tool for species-independent and passive delivery of genetic material, without transgene integration, into plant cells for diverse biotechnology applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 456, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-019-0382-5", "DOI Link": "http://dx.doi.org/10.1038/s41565-019-0382-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467053100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Adli, NM; Shan, WT; Wang, MY; Zachman, MJ; Hwang, S; Tabassum, H; Karakalos, S; Feng, ZX; Wang, GF; Li, YC; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yi; Adli, Nadia Mohd; Shan, Weitao; Wang, Maoyu; Zachman, Michael J.; Hwang, Sooyeon; Tabassum, Hassina; Karakalos, Stavros; Feng, Zhenxing; Wang, Guofeng; Li, Yuguang C.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed single Ni site catalysts for high-efficiency CO2 electroreduction at industrial-level current densities", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed and nitrogen-coordinated single Ni sites (i.e., NiNx moieties) embedded in partially graphitized carbon have emerged as effective catalysts for CO2 electroreduction to CO. However, much mystery remains behind the extrinsic and intrinsic factors that govern the overall catalytic CO2 electrolysis performance. Here, we designed a high-performance single Ni site catalyst through elucidating the structural evolution of NiNx sites during thermal activation and other critical external factors (e.g., carbon particle sizes and Ni content) by using Ni-N-C model catalysts derived from nitrogen-doped carbon carbonized from a zeolitic imidazolate framework (ZIF)-8. The N coordination, metal-N bond length, and thermal wrinkling of carbon planes in Ni-N-C catalysts significantly depend on thermal temperatures. Density functional theory (DFT) calculations reveal that the shortening Ni-N bonds in compressively strained NiN4 sites could intrinsically enhance the CO2RR activity and selectivity of the Ni-N-C catalyst. Notably, the NiN3 active sites with optimal local structures formed at higher temperatures (e.g., 1200 degrees C) are intrinsically more active and CO selective than NiN4, providing a new opportunity to design a highly active catalyst via populating NiN3 sites with increased density. We also studied how morphological factors such as the carbon host particle size and Ni loading alter the final catalyst structure and performance. The implementation of this catalyst in an industrial flow-cell electrolyzer demonstrated an impressive performance for CO generation, achieving a current density of CO up to 726 mA cm(-2) with faradaic efficiency of CO above 90%, representing one of the best catalysts for CO2 reduction to CO.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2022, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2108, "End Page": 2119, "Article Number": null, "DOI": "10.1039/d2ee00318j", "DOI Link": "http://dx.doi.org/10.1039/d2ee00318j", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781904800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QD; Zhao, CL; Yao, ZP; Wang, JL; Wu, FT; Kumar, SGH; Ganapathy, S; Eustace, S; Bai, XD; Li, BH; Lu, J; Wagemaker, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qidi; Zhao, Chenglong; Yao, Zhenpeng; Wang, Jianlin; Wu, Fangting; Kumar, Sai Govind Hari; Ganapathy, Swapna; Eustace, Stephen; Bai, Xuedong; Li, Baohua; Lu, Jun; Wagemaker, Marnix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy-Driven Liquid Electrolytes for Lithium Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing liquid electrolytes with higher kinetics and enhanced interphase stability is one of the key challenges for lithium batteries. However, the poor solubility of lithium salts in solvents sets constraints that compromises the electrolyte properties. Here, it is shown that introducing multiple salts to form a high-entropy solution, alters the solvation structure, which can be used to raise the solubility of specific salts and stabilize electrode-electrolyte interphases. The prepared high-entropy electrolytes significantly enhance the cycling and rate performance of lithium batteries. For lithium-metal anodes the reversibility exceeds 99%, which extends the cycle life of batteries even under aggressive cycling conditions. For commercial batteries, combining a graphite anode with a LiNi0.8Co0.1Mn0.1O2 cathode, more than 1000 charge-discharge cycles are achieved while maintaining a capacity retention of more than 90%. These performance improvements with respect to regular electrolytes are rationalized by the unique features of the solvation structure in high-entropy electrolytes. The weaker solvation interaction induced by the higher disorder results in improved lithium-ion kinetics, and the altered solvation composition leads to stabilized interphases. Finally, the high-entropy, induced by the presence of multiple salts, enables a decrease in melting temperature of the electrolytes and thus enables lower battery operation temperatures without changing the solvents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202210677", "DOI Link": "http://dx.doi.org/10.1002/adma.202210677", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950189000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZH; Provis, JL; Reid, A; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zuhua; Provis, John L.; Reid, Andrew; Wang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical, thermal insulation, thermal resistance and acoustic absorption properties of geopolymer foam concrete", "Source Title": "CEMENT & CONCRETE COMPOSITES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study reports the synthesis and characterization of geopolymer foam concrete (GFC). A Class F fly ash with partial slag substitution was used for GFC synthesis by mechanical mixing of preformed foam. The GFCs exhibited 28 d compressive strengths ranging from 3 to 48 MPa with demolded densities from 720 to 1600 kg/m(3) (105 degrees C oven-dried densities from 585 to 1370 kg/m(3)), with the different densities achieved through alteration of the foam content. The thermal conductivity of GFCs was in the range 0.15-0.48 W/m K, showing better thermal insulation properties than normal Portland cement foam concrete at the same density and/or at the same strength. The GFC derived from alkali activation of fly ash as a sole precursor showed excellent strength retention after heating to temperatures from 100 to 800 degrees C, and the post-cooling compressive strength increased by as much as 100% after exposure at 800 degrees C due to densification and phase transformations. Partial substitution of slag for fly ash increased the strength of GFC at room temperature, but led to notable shrinkage and strength loss at high temperature. Thin GFC panels (20-25 mm) exhibited acoustic absorption coefficients of 0.7-1.0 at 40-150 Hz, and 0.1-0.3 at 800-1600 Hz. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 457, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 97, "End Page": 105, "Article Number": null, "DOI": "10.1016/j.cemconcomp.2015.03.013", "DOI Link": "http://dx.doi.org/10.1016/j.cemconcomp.2015.03.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361577800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sakhatskyi, K; Turedi, B; Matt, GJ; Wu, ER; Sakhatska, A; Bartosh, V; Lintangpradipto, MN; Naphade, R; Shorubalko, I; Mohammed, OF; Yakunin, S; Bakr, OM; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sakhatskyi, Kostiantyn; Turedi, Bekir; Matt, Gebhard J.; Wu, Erfu; Sakhatska, Anastasiia; Bartosh, Vitalii; Lintangpradipto, Muhammad Naufal; Naphade, Rounak; Shorubalko, Ivan; Mohammed, Omar F.; Yakunin, Sergii; Bakr, Osman M.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable perovskite single-crystal X-ray imaging detectors with single-photon sensitivity", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A major thrust of medical X-ray imaging is to minimize the X-ray dose acquired by the patient, down to single-photon sensitivity. Such characteristics have been demonstrated with only a few direct-detection semiconductor materials such as CdTe and Si; nonetheless, their industrial deployment in medical diagnostics is still impeded by elaborate and costly fabrication processes. Hybrid lead halide perovskites can be a viable alternative owing to their facile solution growth. However, hybrid perovskites are unstable under high-field biasing in X-ray detectors, owing to structural lability and mixed electronic-ionic conductivity. Here we show that both single-photon-counting and long-term stable performance of perovskite X-ray detectors are attained in the photovoltaic mode of operation at zero-voltage bias, employing thick and uniform methylammonium lead iodide single-crystal films (up to 300 mu m) and solution directly grown on hole-transporting electrodes. The operational device stability exceeded one year. Detection efficiency of 88% and noise-equivalent dose of 90 pGy(air) are obtained with 18 keV X-rays, allowing single-photon-sensitive, low-dose and energy-resolved X-ray imaging. Array detectors demonstrate high spatial resolution up to 11 lp mm(-1). These findings pave the path for the implementation of hybrid perovskites in low-cost, low-dose commercial detector arrays for X-ray imaging. We show perovskite X-ray detection at zero-voltage bias with operational device stability exceeding one year. Detection efficiency of 88% and noise-equivalent dose of 90 pGyair are obtained with 18 keV X-rays, allowing single-photon-sensitive, low-dose and energy-resolved X-ray imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 510, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01207-y", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01207-y", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983924300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wahl, A; Le Juge, C; Davranche, M; El Hadri, H; Grassl, B; Reynaud, S; Gigault, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wahl, Aurelie; Le Juge, Corentin; Davranche, Melanie; El Hadri, Hind; Grassl, Bruno; Reynaud, Stephanie; Gigault, Julien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloplastic occurrence in a soil amended with plastic debris", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While several studies have investigated the potential impact of nulloplastics, proof of their occurrence in our global environment has not yet been demonstrated. In the present work, by developing an innovative analytical strategy, the presence of nulloplastics in soil was identified for the first time. Our results demonstrate the presence of nulloplastics with a size ranging from 20 to 150 nm and covering three of the most common plastic families: polyethylene, polystyrene and polyvinyl chloride. Given the amount of organic matter in the soil matrix, the discrimination and identification of large nulloplastic aggregates are challenging. However, we provided an innovative methodology to circumvent the organic matter impact on nulloplastic detection by coupling size fractionation to molecular analysis of plastics. While photodegradation has been considered the principal formation pathway of nulloplastics in the environment, this study provides evidence, for the first time, that plastic degradation and nulloplastic production can, however, occur in the soil matrix. Moreover, by providing an innovative and simple extraction/analysis method, this study paves the way to further studies, notably regarding nulloplastic environmental fate and impacts. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 262, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127784, "DOI": "10.1016/j.chemosphere.2020.127784", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2020.127784", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000587290300036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Adewuyi, K; Lotfi, N; Landers, RG; Park, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, J.; Adewuyi, K.; Lotfi, N.; Landers, R. G.; Park, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A single particle model with chemical/mechanical degradation physics for lithium ion battery State of Health (SOH) estimation", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "State of Health (SOH) estimation of lithium ion batteries is critical for Battery Management Systems (BMSs) in Electric Vehicles (EVs). Many estimation techniques utilize a battery model; however, the model must have high accuracy and high computational efficiency. Conventional electrochemical full-order models can accurately capture battery states, but they are too complex and computationally expensive to be used in a BMS. A Single Particle (SP) model is a good alternative that addresses this issue; however, existing SP models do not consider degradation physics. In this work, an SP-based degradation model is developed by including Solid Electrolyte Interface (SEI) layer formation, coupled with crack propagation due to the stress generated by the volume expansion of the particles in the active materials. A model of lithium ion loss from SEI layer formation is integrated with an advanced SP model that includes electrolytic physics. This low-order model quickly predicts capacity fade and voltage profile changes as a function of cycle number and temperature with high accuracy, allowing for the use of online estimation techniques. Lithium ion loss due to SEI layer formation, increase in battery resistance, and changes in the electrodes' open circuit potential operating windows are examined to account for capacity fade and power loss. In addition to the low-order implementation to facilitate on-line estimation, the model proposed in this paper provides quantitative information regarding SEI layer formation and crack propagation, as well as the resulting battery capacity fade and power dissipation, which are essential for SOH estimation in a BMS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2018, "Volume": 212, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1178, "End Page": 1190, "Article Number": null, "DOI": "10.1016/j.apenergy.2018.01.011", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2018.01.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425200700088", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YF; Liu, SD; Xie, XS; Li, ZC; Wang, PJ; Lu, BA; Liang, SQ; Tang, Y; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yanfen; Liu, Shude; Xie, Xuesong; Li, Zhicheng; Wang, Pinji; Lu, Bingan; Liang, Shuquan; Tang, Yan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A functionalized separator enables dendrite-free Zn anode via metal-polydopamine coordination chemistry", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing a multifunctional separator with abundant ion migration paths is crucial for tuning the ion transport in rocking-chair-type batteries. Herein, a polydopamine-functionalized PVDF (PVDF@PDA) nullofibrous membrane is designed to serve as a separator for aqueous zinc-ion batteries (AZIBs). The functional groups (-OH and -NH-) in PDA facilitate the formation of Zn-O and Zn-N coordination bonds with Zn ions, homogenizing the Zn-ion flux and thus enabling dendrite-free Zn deposition. Moreover, the PVDF@PDA separator effectively inhibits the shuttling of V-species through the formation of V-O coordination bonds. As a result, the Zn/NH4V4O10 battery with the PVDF@PDA separator exhibits enhanced cycling stability (92.3% after 1000 cycles at 5 A g(-1)) and rate capability compared to that using a glass fiber separator. This work provides a new avenue to design functionalized separators for high-performance AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/inf2.12374", "DOI Link": "http://dx.doi.org/10.1002/inf2.12374", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863843500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, LL; She, XJ; Zhuang, LC; Li, YY; Ding, R; Guo, XY; Zhang, YQ; Zhu, Y; Xu, K; Fan, HJ; Lau, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Lingling; She, Xiaojie; Zhuang, Lyuchao; Li, Yanyong; Ding, Ran; Guo, Xuyun; Zhang, Yongqi; Zhu, Ye; Xu, Kun; Fan, Hong Jin; Lau, Shu Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating Built-In Electric Field via Variable Oxygen Affinity for Robust Hydrogen Evolution Reaction in Neutral Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Work function strongly impacts the surficial charge distribution, especially for metal-support electro-catalysts when a built-in electric field (BEF) is constructed. Therefore, studying the correlation between work function and BEF is crucial for understanding the intrinsic reaction mechanism. Herein, we present a Pt@CoOx electrocatalyst with a large work function difference (Delta Phi) and strong BEF, which shows outstanding hydrogen evolution activity in a neutral medium with a 4.5-fold mass activity higher than 20 % Pt/C. Both experimental and theoretical results confirm the interfacial charge redistribution induced by the strong BEF, thus subtly optimizing hydrogen and hydroxide adsorption energy. This work not only provides fresh insights into the neutral hydrogen evolution mechanism but also proposes new design principles toward efficient electrocatalysts for hydrogen production in a neutral medium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2022, "Volume": 61, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202116057", "DOI": "10.1002/anie.202116057", "DOI Link": "http://dx.doi.org/10.1002/anie.202116057", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756499400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, HK; Chen, XJ; Ding, Y; Li, B; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Ho-Kwang; Chen, Xiao-Jia; Ding, Yang; Li, Bing; Wang, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solids, liquids, and gases under high pressure", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure has long been recognized as a fundamental thermodynamic variable but its application was previously limited by the available pressure vessels and probes. The development of megabar diamond anvil cells and a battery of associated in-laboratory and synchrotron techniques at the turn of the century have opened a vast new window of opportunities. With the addition of the pressure dimension, we are facing a new world with an order of magnitude more materials to be discovered than all that have been explored at ambient pressure. Pressure drastically and categorically alters all elastic, electronic, magnetic, structural, and chemical properties, and pushes materials across conventional barriers between insulators and superconductors, amorphous and crystalline solids, ionic and covalent compounds, vigorously reactive and inert chemicals, etc. In the process, it reveals surprising high-pressure physics and chemistry and creates novel materials. This reviewdescribes the principles and methodology used to reach ultrahigh static pressure: the in situ probes, the physical phenomena to be investigated, the long-pursued goals, the surprising discoveries, and the vast potential opportunities. Exciting examples include the quest for metallic hydrogen, the record-breaking superconducting temperature of 203 K in HnS, the complication of free-electron gas alkali metals, the magnetic collapse in 3d transition elements, the pressure-induced superconductivity from topological insulators, the novel stoichiometry in simple compounds, the interaction of nulloscience, the accomplishment of 750 GPa pressure, etc. These highlights are the integral results of technological achievements, specific measurements, and theoretical advancement; therefore, the same highlightswill appear in different sections corresponding to these different aspects. Overall, this review demonstrates that high-pressure research is a new dimension in condensed-matter physics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 350, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2018, "Volume": 90, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15007, "DOI": "10.1103/RevModPhys.90.015007", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.015007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427820900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, JT; Liu, YC; Zhao, XD; Liu, H; Deng, SQ; Shen, QY; Hou, Y; Qi, H; Xing, XR; Jiao, LF; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Junteng; Liu, Yongchang; Zhao, Xudong; Liu, Hui; Deng, Shiqing; Shen, Qiuyu; Hou, Ying; Qi, He; Xing, Xianran; Jiao, Lifang; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Annealing in Argon Universally Upgrades the Na-Storage Performance of Mn-Based Layered Oxide Cathodes by Creating Bulk Oxygen Vacancies", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manganese-rich layered oxide cathodes of sodium-ion batteries (SIBs) are extremely promising for large-scale energy storage owing to their high capacities and cost effectiveness, while the Jahn-Teller (J-T) distortion and low operating potential of Mn redox largely hinder their practical applications. Herein, we reveal that annealing in argon rather than conventional air is a universal strategy to comprehensively upgrade the Na-storage performance of Mn-based oxide cathodes. Bulk oxygen vacancies are introduced via this method, leading to reduced Mn valence, lowered Mn 3d-orbital energy level, and formation of the new-concept Mn domains. As a result, the energy density of the model P2-Na0.75Mg0.25Mn0.75O2 cathode increases by approximate to 50 % benefiting from the improved specific capacity and operating potential of Mn redox. The Mn domains can disrupt the cooperative J-T distortion, greatly promoting the cycling stability. This exciting finding opens a new avenue towards high-performance Mn-based oxide cathodes for SIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2023, "Volume": 62, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202219230", "DOI Link": "http://dx.doi.org/10.1002/anie.202219230", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940402300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, X; Yang, FN; Zhang, ZY; Liu, HM; Ge, SY; Hu, SQ; Li, SH; Luo, YT; Yu, QM; Liu, ZB; Wang, Q; Ren, WC; Sun, CH; Cheng, HM; Liu, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Xin; Yang, Fengning; Zhang, Zhiyuan; Liu, Heming; Ge, Shiyu; Hu, Shuqi; Li, Shaohai; Luo, Yuting; Yu, Qiangmin; Liu, Zhibo; Wang, Qiang; Ren, Wencai; Sun, Chenghua; Cheng, Hui-Ming; Liu, Bilu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct seawater electrolysis is promising for sustainable hydrogen production but suffers severe side reactions and corrosion. Here, the authors report a corrosion-resistant electrocatalyst with in situ-formed chloride-ion-repelling cation layer for efficient and long-lasting seawater oxidation. Direct seawater electrolysis is promising for sustainable hydrogen gas (H-2) production. However, the chloride ions in seawater lead to side reactions and corrosion, which result in a low efficiency and poor stability of the electrocatalyst and hinder the use of seawater electrolysis technology. Here we report a corrosion-resistant RuMoNi electrocatalyst, in which the in situ-formed molybdate ions on its surface repel chloride ions. The electrocatalyst works stably for over 3000 h at a high current density of 500 mA cm(-2) in alkaline seawater electrolytes. Using the RuMoNi catalyst in an anion exchange membrane electrolyzer, we report an energy conversion efficiency of 77.9% and a current density of 1000 mA cm(-2) at 1.72 V. The calculated price per gallon of gasoline equivalent (GGE) of the H-2 produced is $ 0.85, which is lower than the 2026 technical target of $ 2.0/GGE set by the United Stated Department of Energy, thus, suggesting practicability of the technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3607, "DOI": "10.1038/s41467-023-39386-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39386-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001009499200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SJ; Chen, X; Zhao, C; Kong, YX; Lin, BJ; Wu, YY; Bi, ZZ; Xuan, ZY; Li, T; Li, YX; Zhang, W; Ma, E; Wang, ZR; Ma, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shijie; Chen, Xi; Zhao, Chao; Kong, Yuxin; Lin, Baojun; Wu, Yongyi; Bi, Zhaozhao; Xuan, Ziyi; Li, Tao; Li, Yuxiang; Zhang, Wei; Ma, En; Wang, Zhongrui; Ma, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An organic electrochemical transistor for multi-modal sensing, memory and processing", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By integrating sensing, memory and processing functionalities, biological nervous systems are energy and area efficient. Emulating such capabilities in artificial systems is, however, challenging and is limited by the device heterogeneity of sensing and processing cores. Here we report an organic electrochemical transistor capable of sensing, memory and processing. The device has a vertical traverse architecture and a crystalline-amorphous channel that can be selectively doped by ions to enable two reconfigurable modes: a volatile receptor and a non-volatile synapse. As a volatile receptor, the device is capable of multi-modal sensing and is responsive to stimuli such as ions and light. As a non-volatile synapse, it is capable of 10-bit analogue states, low switching stochasticity and good state retention. We also show that the homogeneous integration of the devices could provide functions such as conditioned reflexes and could be used for real-time cardiac disease diagnoses via reservoir computing. An organic electrochemical transistor with a vertical traverse architecture and a crystalline-amorphous channel that can be selectively doped by ions can operate as a volatile receptor and a non-volatile synapse.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 281, "End Page": 291, "Article Number": null, "DOI": "10.1038/s41928-023-00950-y", "DOI Link": "http://dx.doi.org/10.1038/s41928-023-00950-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983251900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZZ; Jiang, LS; Wang, K; Li, Y; Zhang, GK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhuangzhuang; Jiang, Lisha; Wang, Kai; Li, Yuan; Zhang, Gaoke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel AgI/BiSbO4 heterojunction for efficient photocatalytic degradation of organic pollutants under visible light: Interfacial electron transfer pathway, DFT calculation and degradation mechanism study", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we constructed a novel AgI/BiSbO4 heterojunction via a hydrothermal-precipitation method. The heterojunction structure boosts the generation of hydroxyl and superoxide radicals for efficient degradation of organic pollutants. The photocatalytic activities of the optimal sample for ARG and TC degradation are 10 and 1.6 times higher than those of bare AgI, respectively. Characterizations and theoretical calculations together confirm a strong interfacial charge transfer exists between the interlayer in AgI and BiSbO4 by the formation of Ag-O bond, making O atoms obtain rich free electrons from Ag atoms of AgI, thus forming an ultrahigh electron transfer tunnel, and ultimately accelerating the separation of photoinduced electrons. More interestingly, low amounts of Ag-0 NPs formed during the photocatalytic process, enhancing the visible light absorption because of its SPR (surface plasmon resonullce) effect and further promoting the separation of photoinduced carriers. Furthermore, photocatalytic degradation pathways were proposed in detail by analyzing intermediates and a reasonable photocatalytic mechanism was unearthed. This work extends the development of AgI-based heterojunction photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2021, "Volume": 410, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124948, "DOI": "10.1016/j.jhazmat.2020.124948", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2020.124948", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000635539300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Figg, CA; Simula, A; Gebre, KA; Tucker, BS; Haddleton, DM; Sumerlin, BS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Figg, C. Adrian; Simula, Alexandre; Gebre, Kalkidan A.; Tucker, Bryan S.; Haddleton, David M.; Sumerlin, Brent S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymerization-induced thermal self-assembly (PITSA)", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymerization-induced self-assembly (PISA) is a versatile technique to achieve a wide range of polymeric nulloparticle morphologies. Most previous examples of self-assembled soft nulloparticle synthesis by PISA rely on a growing solvophobic polymer block that leads to changes in nulloparticle architecture during polymerization in a selective solvent. However, synthesis of block copolymers with a growing stimuli-responsive block to form various nulloparticle shapes has yet to be reported. This new concept using thermoresponsive polymers is termed polymerization-induced thermal self-assembly (PITSA). A reversible addition-fragmentation chain transfer (RAFT) polymerization of N-isopropylacrylamide from a hydrophilic chain transfer agent composed of N, N-dimethylacrylamide and acrylic acid was carried out in water above the known lower critical solution temperature (LCST) of poly(N-isopropylacrylamide) (PNIPAm). After reaching a certain chain length, the growing PNIPAm self-assembled, as induced by the LCST, into block copolymer aggregates within which dispersion polymerization continued. To characterize the nulloparticles at ambient temperatures without their dissolution, the particles were crosslinked immediately following polymerization at elevated temperatures via the reaction of the acid groups with a diamine in the presence of a carbodiimide. Size exclusion chromatography was used to evaluate the unimer molecular weight distributions and reaction kinetics. Dynamic light scattering and transmission electron microscopy provided insight into the size and morphologies of the nulloparticles. The resulting block copolymers formed polymeric nulloparticles with a range of morphologies (e.g., micelles, worms, and vesicles), which were a function of the PNIPAm block length.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1230, "End Page": 1236, "Article Number": null, "DOI": "10.1039/c4sc03334e", "DOI Link": "http://dx.doi.org/10.1039/c4sc03334e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348147100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Z; Liu, Y; Zhang, H; Liu, ZR; Tian, H; Sun, YQ; Zhang, M; Zhou, Y; Sun, JR; Xie, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zheng; Liu, Yuan; Zhang, Hui; Liu, Zhongran; Tian, He; Sun, Yanqiu; Zhang, Meng; Zhou, Yi; Sun, Jirong; Xie, Yanwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric field control of superconductivity at the LaAlO3/KTaO3(111) interface", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxide interface between LaAlO3 and KTaO3(111) can harbor a superconducting state. We report that by applying a gate voltage (V-G) across KTaO3, the interface can be continuously tuned from superconducting into insulating states, yielding a dome-shaped T-c-V-G dependence, where T-c is the transition temperature. The electric gating has only a minor effect on carrier density but a strong one on mobility. We interpret the tuning of mobility in terms of change in the spatial profile of the carriers in the interface and hence, effective disorder. As the temperature is decreased, the resistance saturates at the lowest temperature on both superconducting and insulating sides, suggesting the emergence of a quantum metallic state associated with a failed superconductor and/or fragile insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2021, "Volume": 372, "Issue": 6543, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 721, "End Page": "U444", "Article Number": null, "DOI": "10.1126/science.abb3848", "DOI Link": "http://dx.doi.org/10.1126/science.abb3848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000651125300046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, PF; Lu, HF; Zhou, Y; Zhang, L; Wu, ZL; Yang, SZ; Shi, HL; Zhu, QL; Chen, YF; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Pengfei; Lu, Hanfeng; Zhou, Ying; Zhang, Li; Wu, Zili; Yang, Shize; Shi, Hongliang; Zhu, Qiulian; Chen, Yinfei; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous MnCeOx solid solutions for low temperature and selective oxidation of hydrocarbons", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of noble-metal-free heterogeneous catalysts that can realize the aerobic oxidation of C-H bonds at low temperature is a profound challenge in the catalysis community. Here we report the synthesis of a mesoporous Mn0.5Ce0.5Ox solid solution that is highly active for the selective oxidation of hydrocarbons under mild conditions (100-120 degrees C). Notably, the catalytic performance achieved in the oxidation of cyclohexane to cyclohexanone/ cyclohexanol (100 degrees C, conversion: 17.7%) is superior to those by the state-of-art commercial catalysts (140-160 degrees C, conversion: 3-5%). The high activity can be attributed to the formation of a Mn0.5Ce0.5Ox solid solution with an ultrahigh manganese doping concentration in the CeO2 cubic fluorite lattice, leading to maximum active surface oxygens for the activation of C-H bonds and highly reducible Mn4+ ions for the rapid migration of oxygen vacancies from the bulk to the surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8446, "DOI": "10.1038/ncomms9446", "DOI Link": "http://dx.doi.org/10.1038/ncomms9446", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364925000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, PH; Wang, C; Chen, DC; Zhong, ZC; Yuan, Z; Lu, ZY; Ji, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Peiheng; Wang, Cong; Chen, Dachuan; Zhong, Zhicheng; Yuan, Zhe; Lu, Zhong-Yi; Ji, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking tunable interlayer magnetism in bilayer CrI3", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diverse interlayer tunability of physical properties of two-dimensional layers mostly lies in the covalent-like quasibonding that is significant in electronic structures but rather weak for energetics. Such characteristics result in various stacking orders that are energetically comparable but may significantly differ in terms of electronic structures, e.g., magnetism. Inspired by several recent experiments showing interlayer antiferromagnetically coupled CrI3 bilayers, we carried out first-principles calculations for CrI3 bilayers. We found that the antiferromagnetic coupling results from a different stacking order with the C2/m space group symmetry, rather than the graphene-like one with R (3) over bar as previously believed. Moreover, we demonstrated that the intra- and interlayer couplings in CrI3 bilayer are governed by two different mechanisms, namely ferromagnetic superexchange and direct-exchange interactions, which are largely decoupled because of their significant difference in strength at the strong- and weak-interaction limits. This allows the much weaker interlayer magnetic coupling to be more feasibly tuned by stacking orders solely. Given the fact that interlayer magnetic properties can be altered by changing crystal structure with different stacking orders, our work opens a paradigm for tuning interlayer magnetic properties with the freedom of stacking order in two-dimensional layered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2019, "Volume": 99, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144401, "DOI": "10.1103/PhysRevB.99.144401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.99.144401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462902900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Crawford, D; Casaban, J; Haydon, R; Giri, N; McNally, T; James, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Crawford, Deborah; Casaban, Jose; Haydon, Robert; Giri, Nicola; McNally, Tony; James, Stuart L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Grinding solid reagents under solvent-free or low-solvent conditions (mechanochemistry) is emerging as a general synthetic technique which is an alternative to conventional solvent-intensive methods. However, it is essential to find ways to scale-up this type of synthesis if its promise of cleaner manufacturing is to be realised. Here, we demonstrate the use of twin screw and single screw extruders for the continuous synthesis of various metal complexes, including Ni(salen), Ni(NCS)(2)(PPh3)(2) as well as the commercially important metal organic frameworks (MOFs) Cu-3(BTC)(2) (HKUST-1), Zn(2-methylimidazolate)(2) (ZIF-8, MAF-4) and Al(fumarate)(OH). Notably, Al(fumarate)(OH) has not previously been synthesised mechanochemically. Quantitative conversions occur to give products at kg h(-1) rates which, after activation, exhibit surface areas and pore volumes equivalent to those of materials produced by conventional solvent-based methods. Some reactions can be performed either under completely solvent-free conditions whereas others require the addition of small amounts of solvent (typically 3-4 mol equivalents). Continuous neat melt phase synthesis is also successfully demonstrated by both twin screw and single screw extrusion for ZIF-8. The latter technique provided ZIF-8 at 4 kg h(-1). The space time yields (STYs) for these methods of up to 144 x 10(3) kg per m(3) per day are orders of magnitude greater than STYs for other methods of making MOFs. Extrusion methods clearly enable scaling of mechanochemical and melt phase synthesis under solvent-free or low-solvent conditions, and may also be applied in synthesis more generally.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1645, "End Page": 1649, "Article Number": null, "DOI": "10.1039/c4sc03217a", "DOI Link": "http://dx.doi.org/10.1039/c4sc03217a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349832600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, W; Min, SY; Hwang, H; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Wentao; Min, Sung-Yong; Hwang, Hyunsang; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic core-sheath nullowire artificial synapses with femtojoule energy consumption", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emulation of biological synapses is an important step toward construction of large-scale brain-inspired electronics. Despite remarkable progress in emulating synaptic functions, current synaptic devices still consume energy that is orders of magnitude greater than do biological synapses (similar to 10 fJ per synaptic event). Reduction of energy consumption of artificial synapses remains a difficult challenge. We report organic nullowire (ONW) synaptic transistors (STs) that emulate the important working principles of a biological synapse. The ONWs emulate the morphology of nerve fibers. With a core-sheath-structured ONW active channel and a well-confined 300-nm channel length obtained using ONW lithography, similar to 1.23 fJ per synaptic event for individual ONW was attained, which rivals that of biological synapses. The ONW STs provide a significant step toward realizing low-energy-consuming artificial intelligent electronics and open new approaches to assembling soft neuromorphic systems with nullometer feature size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 500, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501326", "DOI": "10.1126/sciadv.1501326", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501326", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380073800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Florijn, B; Coulais, C; van Hecke, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Florijn, Bastiaan; Coulais, Corentin; van Hecke, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programmable Mechanical Metamaterials", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We create mechanical metamaterials whose response to uniaxial compression can be programmed by lateral confinement, allowing monotonic, nonmonotonic, and hysteretic behavior. These functionalities arise from a broken rotational symmetry which causes highly nonlinear coupling of deformations along the two primary axes of these metamaterials. We introduce a soft mechanism model which captures the programmable mechanics, and outline a general design strategy for confined mechanical metamaterials. Finally, we show how inhomogeneous confinement can be explored to create multistability and giant hysteresis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2014, "Volume": 113, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 175503, "DOI": "10.1103/PhysRevLett.113.175503", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.175503", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344056800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, T; Bilal, OR; Shea, K; Daraio, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Tian; Bilal, Osama R.; Shea, Kristina; Daraio, Chiara", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harnessing bistability for directional propulsion of soft, untethered robots", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In most macroscale robotic systems, propulsion and controls are enabled through a physical tether or complex onboard electronics and batteries. A tether simplifies the design process but limits the range of motion of the robot, while onboard controls and power supplies are heavy and complicate the design process. Here, we present a simple design principle for an untethered, soft swimming robot with preprogrammed, directional propulsion without a battery or onboard electronics. Locomotion is achieved by using actuators that harness the large displacements of bistable elements triggered by surrounding temperature changes. Powered by shape memory polymer (SMP) muscles, the bistable elements in turn actuate the robot's fins. Our robots are fabricated using a commercially available 3D printer in a single print. As a proof of concept, we show the ability to program a vessel, which can autonomously deliver a cargo and navigate back to the deployment point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2018, "Volume": 115, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5698, "End Page": 5702, "Article Number": null, "DOI": "10.1073/pnas.1800386115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1800386115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433283700054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Travis, W; Glover, ENK; Bronstein, H; Scanlon, DO; Palgrave, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Travis, W.; Glover, E. N. K.; Bronstein, H.; Scanlon, D. O.; Palgrave, R. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the application of the tolerance factor to inorganic and hybrid halide perovskites: a revised system", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The tolerance factor is a widely used predictor of perovskite stability. The recent interest in hybrid perovskites for use as solar cell absorbers has lead to application of the tolerance factor to these materials as a way to explain and predict structure. Here we critically assess the suitability of the tolerance factor for halide perovskites. We show that the tolerance factor fails to accurately predict the stability of the 32 known inorganic iodide perovskites, and propose an alternative method. We introduce a revised set of ionic radii for cations that is anion dependent, this revision is necessary due to increased covalency in metal-halide bonds for heavier halides compared with the metal-oxide and fluoride bonds used to calculate Shannon radii. We also employ a 2D structural map to account for the size requirements of the halide anions. Together these measures yield a simple system which may assist in the search for new hybrid and inorganic perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 838, "Times Cited, All Databases": 925, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4548, "End Page": 4556, "Article Number": null, "DOI": "10.1039/c5sc04845a", "DOI Link": "http://dx.doi.org/10.1039/c5sc04845a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378715000071", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reznikov, N; Bilton, M; Lari, L; Stevens, MM; Kroger, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reznikov, Natalie; Bilton, Matthew; Lari, Leonardo; Stevens, Molly M.; Kroger, Roland", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractal-like hierarchical organization of bone begins at the nulloscale", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The components of bone assemble hierarchically to provide stiffness and toughness. However, the organization and relationship between bone's principal components-mineral and collagen-has not been clearly elucidated. Using three-dimensional electron tomography imaging and high-resolution two-dimensional electron microscopy, we demonstrate that bone mineral is hierarchically assembled beginning at the nulloscale: Needle-shaped mineral units merge laterally to form platelets, and these are further organized into stacks of roughly parallel platelets. These stacks coalesce into aggregates that exceed the lateral dimensions of the collagen fibrils and span adjacent fibrils as continuous, cross-fibrillar mineralization. On the basis of these observations, we present a structural model of hierarchy and continuity for the mineral phase, which contributes to the structural integrity of bone.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2018, "Volume": 360, "Issue": 6388, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 507, "End Page": "+", "Article Number": "eaao2189", "DOI": "10.1126/science.aao2189", "DOI Link": "http://dx.doi.org/10.1126/science.aao2189", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431351500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, W; Guo, SR; Lee, I; Ahmed, K; Zhong, JB; Favors, Z; Zaera, F; Ozkan, M; Ozkan, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wei; Guo, Shirui; Lee, Ilkeun; Ahmed, Kazi; Zhong, Jiebin; Favors, Zachary; Zaera, Francisco; Ozkan, Mihrimah; Ozkan, Cengiz S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrous Ruthenium Oxide nulloparticles Anchored to Graphene and Carbon nullotube Hybrid Foam for Supercapacitors", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In real life applications, supercapacitors (SCs) often can only be used as part of a hybrid system together with other high energy storage devices due to their relatively lower energy density in comparison to other types of energy storage devices such as batteries and fuel cells. Increasing the energy density of SCs will have a huge impact on the development of future energy storage devices by broadening the area of application for SCs. Here, we report a simple and scalable way of preparing a three-dimensional (3D) sub-5 nm hydrous ruthenium oxide (RuO2) anchored graphene and CNT hybrid foam (RGM) architecture for high-performance supercapacitor electrodes. This RGM architecture demonstrates a novel graphene foam conformally covered with hybrid networks of RuO2 nulloparticles and anchored CNTs. SCs based on RGM show superior gravimetric and per-area capacitive performance (specific capacitance: 502.78 F g(-1), areal capacitance: 1.11 F cm(-2)) which leads to an exceptionally high energy density of 39.28 Wh kg(-1) and power density of 128.01 kW kg(-1). The electrochemical stability, excellent capacitive performance, and the ease of preparation suggest this RGM system is promising for future energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4452, "DOI": "10.1038/srep04452", "DOI Link": "http://dx.doi.org/10.1038/srep04452", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333327000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Torrejon, J; Riou, M; Araujo, FA; Tsunegi, S; Khalsa, G; Querlioz, D; Bortolotti, P; Cros, V; Yakushiji, K; Fukushima, A; Kubota, H; Uasa, SY; Stiles, MD; Grollier, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Torrejon, Jacob; Riou, Mathieu; Araujo, Flavio Abreu; Tsunegi, Sumito; Khalsa, Guru; Querlioz, Damien; Bortolotti, Paolo; Cros, Vincent; Yakushiji, Kay; Fukushima, Akio; Kubota, Hitoshi; Uasa, Shinji Y.; Stiles, Mark D.; Grollier, Julie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neuromorphic computing with nulloscale spintronic oscillators", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neurons in the brain behave as nonlinear oscillators, which develop rhythmic activity and interact to process information(1). Taking inspiration from this behaviour to realize high-density, low-power neuromorphic computing will require very large numbers of nulloscale nonlinear oscillators. A simple estimation indicates that to fit 10(8) oscillators organized in a two-dimensional array inside a chip the size of a thumb, the lateral dimension of each oscillator must be smaller than one micrometre. However, nulloscale devices tend to be noisy and to lack the stability that is required to process data in a reliable way. For this reason, despite multiple theoretical proposals(2-5) and several candidates, including memristive(6) and superconducting(7) oscillators, a proof of concept of neuromorphic computing using nulloscale oscillators has yet to be demonstrated. Here we show experimentally that a nulloscale spintronic oscillator (a magnetic tunnel junction)(8,9) can be used to achieve spoken-digit recognition with an accuracy similar to that of state-of-the-art neural networks. We also determine the regime of magnetization dynamics that leads to the greatest performance. These results, combined with the ability of the spintronic oscillators to interact with each other, and their long lifetime and low energy consumption, open up a path to fast, parallel, on-chip computation based on networks of oscillators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 983, "Times Cited, All Databases": 1044, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2017, "Volume": 547, "Issue": 7664, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 428, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature23011", "DOI Link": "http://dx.doi.org/10.1038/nature23011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406358300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deubener, J; Allix, M; Davis, MJ; Duran, A; Höche, T; Honma, T; Komatsu, T; Krüger, S; Mitra, I; Müller, R; Nakane, S; Pascual, MJ; Schmelzer, JWP; Zanotto, ED; Zhou, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deubener, J.; Allix, M.; Davis, M. J.; Duran, A.; Hoeche, T.; Honma, T.; Komatsu, T.; Krueger, S.; Mitra, I.; Mueller, R.; Nakane, S.; Pascual, M. J.; Schmelzer, J. W. P.; Zanotto, E. D.; Zhou, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Updated definition of glass-ceramics", "Source Title": "JOURNAL OF NON-CRYSTALLINE SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glass-ceramics are noted for their unusual combination of properties and manifold commercialized products for consumer and specialized markets. Evolution of novel glass and ceramic processing routes, a plethora of new compositions, and unique exotic nullo- and microstructures over the past 60 years led us to review the definition of glass-ceramics. Well-established and emerging processing methods, such as co-firing, additive manufacturing, and laser patterning are analyzed concerning the core requirements of processing glass-ceramics and the performance of the final products. In this communication, we propose a revised, updated definition of glass-ceramics, which reads Glass-ceramics are inorganic, non-metallic materials prepared by controlled crystallization of glasses via different processing methods. They contain at least one type of functional crystalline phase and a residual glass. The volume fraction crystallized may vary from ppm to almost 100%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2018, "Volume": 501, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 3, "End Page": 10, "Article Number": null, "DOI": "10.1016/j.jnoncrysol.2018.01.033", "DOI Link": "http://dx.doi.org/10.1016/j.jnoncrysol.2018.01.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451104400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, M; Zhong, GH; Yin, YM; Miao, JS; Li, K; Wang, CQ; Xu, XR; Shen, C; Meng, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ming; Zhong, Guohua; Yin, Yongming; Miao, Jingsheng; Li, Ke; Wang, Chengqun; Xu, Xiuru; Shen, Clifton; Meng, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aluminum-Doped Cesium Lead Bromide Perovskite nullocrystals with Stable Blue Photoluminescence Used for Display Backlight", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bright and stable blue emitters with narrow full-width at half-maxima are particularly desirable for applications in television displays and related technologies. Here, this study shows that doping aluminum (Al3+) ion into CsPbBr3 nullocrystals (NCs) using AlBr3 can afford lead-halide perovskites NCs with stable blue photoluminescence. First, theoretical and experimental analyses reveal that the extended band gap and quantum confinement effect of elongated shape give rise to the desirable blueshifted emission. Second, the aluminum ion incorporation path is rationalized qualitatively by invoking fundamental considerations about binding relations in AlBr3 and its dimer. Finally, the absence of anion-exchange effect is corroborated when green CsPbBr3 and blue Al:CsPbBr3 NCs are mixed. Combinations of the above two NCs with red-emitting CdSe@ZnS NCs result in UV-pumped white light-emitting diodes (LED) with an National Television System Committee (NTSC) value of 116% and ITU-R Recommendation B.T. 2020 (Rec. 2020) of 87%. The color coordinates of the white LED are optimized at (0.32, 0.34) in CIE 1931. The results suggest that low-cost, earth-abundant, solution-processable Al-doped perovskite NCs can be promising candidate materials for blue down-conversion layer in backlit displays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700335, "DOI": "10.1002/advs.201700335", "DOI Link": "http://dx.doi.org/10.1002/advs.201700335", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416155900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, JL; Dai, Y; Cheng, Y; Xie, S; Li, G; Liu, Y; Wang, JX; Zhang, RR; Bai, NN; Cai, MK; Zhang, Y; Zhan, YF; Zhang, ZY; Yu, CJ; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Junli; Dai, Yuan; Cheng, Yu; Xie, Sai; Li, Gang; Liu, Yuan; Wang, Jingxiao; Zhang, Ruirui; Bai, Ningning; Cai, Minkun; Zhang, Yuan; Zhan, Yifei; Zhang, Zhengyou; Yu, Cunjiang; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Embedment of sensing elements for robust, highly sensitive, and cross-talk-free iontronic skins for robotics applications", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iontronic pressure sensors are promising in robot haptics because they can achieve high sensing performance using nulloscale electric double layers (EDLs) for capacitive signal output. However, it is challenging to achieve both high sensitivity and high mechanical stability in these devices. Iontronic sensors need microstructures that offer subtly changeable EDL interfaces to boost sensitivity, while the microstructured interfaces are mechani-cally weak. Here, we embed isolated microstructured ionic gel (IMIG) in a hole array (28 x 28) of elastomeric matrix and cross-link the IMIGs laterally to achieve enhanced interfacial robustness without sacrificing sensitiv-ity. The embedded configuration toughens and strengthens the skin by pinning cracks and by the elastic dis-sipation of the interhole structures. Furthermore, cross-talk between the sensing elements is suppressed by isolating the ionic materials and by designing a circuit with a compensation algorithm. We have demonstrated that the skin is potentially useful for robotic manipulation tasks and object recognition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2023, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf8831", "DOI": "10.1126/sciadv.adf8831", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf8831", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948527600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Acharya, D; Pathak, I; Dahal, B; Lohani, PC; Bhattarai, RM; Muthurasu, A; Kim, T; Ko, TH; Chhetri, K; Kim, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Acharya, Debendra; Pathak, Ishwor; Dahal, Bipeen; Lohani, Prakash Chandra; Bhattarai, Roshan Mangal; Muthurasu, Alagan; Kim, Taewoo; Ko, Tae Hoon; Chhetri, Kisan; Kim, Hak Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Immoderate nulloarchitectures of bimetallic MOF derived Ni-Fe-O/NPC on porous carbon nullofibers as freestanding electrode for asymmetric supercapacitors", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The logical design and engineering of bimetallic oxide nullomaterials with porous carbon materials have had a significant impact on the development of high-performance electrode materials for energy storage devices in recent years. The vertical and uniform building of porous multimetal nullomaterials on the surface of nulloscale carbon fibers is difficult but not impossible. We present a self-templated metal-organic framework (MOF)-based strategy for the synthesis and assembly of bimetallic oxides/nulloporous carbon nullostructures (Ni-Fe-O/NPC) on porous carbon nullofibers (PCNFs). The vertical alignment of Ni-Fe-O/NPC at PCNFs favors a fast redox reaction by shortening the ion/electrode diffusion path at the electrode-electrolyte interface and helps enhance the overall electrochemical performance. As a freestanding electrode for supercapacitors, it has a high specific capacitance of 1419 F g(-1) at 1 A g(-1) and good cycling life with capacitance retention of approximately 88.5% after 10,000 cycles. The Ni-Fe-O/NPC@PCNFs-400//Fe2O3/NPC@PCNFs asymmetric supercapacitor (ASC) achieves a high energy density of 41.3 Wh kg(-1) at a power density of 892.2 W kg(-1) with a long cycle of life (20,000 cycles) and a high rate capability (78.6%), indicating its potential applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 201, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12, "End Page": 23, "Article Number": null, "DOI": "10.1016/j.carbon.2022.08.091", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2022.08.091", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000861029500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aragaw, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aragaw, Tadele Assefa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surgical face masks as a potential source for microplastic pollution in the COVID-19 scenario", "Source Title": "MARINE POLLUTION BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although there have been enormous reports on the microplastic pollution from different plastic products, impacts, controlling mechanisms in recent years, the surgical face masks, made up of polymeric materials, as a source of microplastic pollution potential in the ecosystem are not fully understood and considered yet. Current studies are mostly stated out that microplastics pollution should be a big deal because of their enormous effect on the aquatic biota, and the entire environment. Due to the complicated conditions of the aquatic bodies, microplastics could have multiple effects, and reports so far are still lacking. In addition to real microplastic pollutions which has been known before, face mask as a potential microplastic source could be also researching out, including the management system, in detail. It is noted that face masks are easily ingested by higher organisms, such as fishes, and microorganisms in the aquatic life which will affect the food chain and finally chronic health problems to humans. As a result, microplastic from the face mask should be a focus worldwide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 159, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111517, "DOI": "10.1016/j.marpolbul.2020.111517", "DOI Link": "http://dx.doi.org/10.1016/j.marpolbul.2020.111517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568698200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Z; Wang, YL; Peng, F; Meng, FQ; Zha, JJ; Ma, L; Du, YH; Peng, N; Ma, LF; Zhang, QH; Gu, L; Yin, WY; Gu, ZJ; Tan, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhan; Wang, Yanlong; Peng, Feng; Meng, Fanqi; Zha, Jiajia; Ma, Lu; Du, Yonghua; Peng, Na; Ma, Lufang; Zhang, Qinghua; Gu, Lin; Yin, Wenyan; Gu, Zhanjun; Tan, Chaoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intercalation-Activated Layered MoO3 nullobelts as Biodegradable nullozymes for Tumor-Specific Photo-Enhanced Catalytic Therapy", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The existence of natural van der Waals gaps in layered materials allows them to be easily intercalated with varying guest species, offering an appealing strategy to optimize their physicochemical properties and application performance. Herein, we report the activation of layered MoO3 nullobelts via aqueous intercalation as an efficient biodegradable nullozyme for tumor-specific photo-enhanced catalytic therapy. The long MoO3 nullobelts are grinded and then intercalated with Na+ and H2O to obtain the short Na+/H2O co-intercalated MoO3-x (NH-MoO3-x) nullobelts. In contrast to the inert MoO3 nullobelts, the NH-MoO3-x nullobelts exhibit excellent enzyme-mimicking catalytic activity for generation of reactive oxygen species, which can be further enhanced by the photothermal effect under a 1064 nm laser irradiation. Thus, after bovine serum albumin modification, the NH-MoO3-x nullobelts can efficiently kill cancer cells in vitro and eliminate tumors in vivo facilitating with 1064 nm laser irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2022, "Volume": 61, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202115939", "DOI": "10.1002/anie.202115939", "DOI Link": "http://dx.doi.org/10.1002/anie.202115939", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753959400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, L; Sun, MZ; Zhou, Y; Luo, MC; Lv, F; Li, MG; Zhang, QH; Gu, L; Huang, BL; Guo, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Lu; Sun, Mingzi; Zhou, Yin; Luo, Mingchuan; Lv, Fan; Li, Menggang; Zhang, Qinghua; Gu, Lin; Huang, Bolong; Guo, Shaojun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A General Synthetic Method for High-Entropy Alloy Subnullometer Ribbons", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) are attracting intensive attention due to their broad compositional tunability and interesting catalytic properties. However, precisely shaping the HEAs into suprathin low-dimensional nullostructures for achieving diverse applications remains an enormous challenge owing to their intrinsic thermodynamic instability. Herein we propose a new and general low-temperature method for incorporating up to eight metallic elements into one single-phase subnullometer ribbon to achieve the thinnest HEA metal materials in the world. We experimentally demonstrate that synthetic processes for suprathin HEA subnullometer ribbons (SNRs) include (1) different metal atom nucleation via galvanic exchange reaction between different metal precursors and Ag nullowire template, (2) co-reduction of different metal precursors on nullowire template, and (3) the removal of the inner Ag core. Density functional theory (DFT) calculations reveal that the crystallization and stabilization of HEA SNRs strongly depend on the highly dynamic Ag from the template, and the crystallization levels of HEA subnullometer ribbons are closely correlated with the concentration of Pt and Pd. We demonstrate that the present synthetic method enables the flexible control of components and concentrations in HEAs SNRs for achieving a library of HEA SNRs and also superior electrocatalytic properties. The well-designed HEA SNRs show great improvement in catalyzing the oxygen reduction reaction of fuel cells and also high discharge capacity, low charge overpotential, and excellent durability for Li-O-2 batteries. DFT calculations reveal the superior electrochemical performances are attributed to the strong reduction capability from high-concentration reductive elements in HEAs, while the other elements guarantee the site-to-site efficient electron transfer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 144, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10582, "End Page": 10590, "Article Number": null, "DOI": "10.1021/jacs.2c03544", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c03544", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000812431000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, YBA; Han, MS; Wu, BK; Wang, YM; Li, ZW; Li, JX; Li, Z; Wang, S; Wan, JY; Zeng, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Yongbiao; Han, Meisheng; Wu, Buke; Wang, Yameng; Li, Zhenwei; Li, Jiaxing; Li, Zheng; Wang, Shuai; Wan, Jiayu; Zeng, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen, Oxygen-Codoped Vertical Graphene Arrays Coated 3D Flexible Carbon nullofibers with High Silicon Content as an Ultrastable Anode for Superior Lithium Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free-standing and foldable electrodes with high energy density and long lifespan have recently elicited attention on the development of lithium-ion batteries (LIBs) for flexible electronic devices. However, both low energy density and slow kinetics in cycling impede their practical applications. In this work, a free-standing and binder-free N, O-codoped 3D vertical graphene carbon nullofibers electrode with ultra-high silicon content (VGAs@Si@CNFs) is developed via electrospinning, subsequent thermal treatment, and chemical vapor deposition processes. The as-prepared VGAs@Si@CNFs electrode exhibits excellent conductivity and flexibility because of the high graphitized carbon nullofiber network and abundant vertical graphene arrays. Such 3D all-carbon architecture can be fabulous for providing a conductive and mechanically robust network, further improving the kinetics and restraining the volume expansion of Si NPs, especially with an ultra-high Si content (>90 wt%). As a result, the VGAs@Si@CNFs composite demonstrates a superior specific capacity (3619.5 mAh g(-1) at 0.05 A g(-1)), ultralong lifespan, and outstanding rate capability (1093.1 mAh g(-1) after 1500 cycles at 8 A g(-1)) as a free-standing anode for LIBs. It is believed that this work offers an exciting method for developing free-standing and high-energy-density electrodes for other energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104685, "DOI": "10.1002/advs.202104685", "DOI Link": "http://dx.doi.org/10.1002/advs.202104685", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739293900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, SB; Hou, ZY; Zou, SJ; Lu, XS; Yang, JM; Hao, TY; Zhou, ZH; Xu, JH; Zeng, YH; Xiao, W; Dong, W; Li, DQ; Wang, X; Hu, ZG; Sun, L; Wu, YN; Liu, XJ; Ding, LM; Sun, ZR; Fahlman, M; Bao, QY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Shaobing; Hou, Zhangyu; Zou, Shijie; Lu, Xiaoshuang; Yang, Jianming; Hao, Tianyu; Zhou, Zihao; Xu, Jianhua; Zeng, Yihan; Xiao, Wei; Dong, Wei; Li, Danqin; Wang, Xiang; Hu, Zhigao; Sun, Lin; Wu, Yuning; Liu, Xianjie; Ding, Liming; Sun, Zhenrong; Fahlman, Mats; Bao, Qinye", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Observation on p- to n-Type Transformation of Perovskite Surface Region during Defect Passivation Driving High Photovoltaic Efficiency", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) suffer from significant nonradiative recombination, limiting their power conversion efficiencies. Here, for the first time, we directly observe a complete transformation of perovskite MAPbI(3) surface region energetics from p- to n-type during defect passivation caused by natural additive capsaicin, attributed to the spontaneous formation of a p-n homojunction in perovskite active layer. We demonstrate that the p-n homojunction locates at similar to 100 nm below perovskite surface. The energetics transformation and defect passivation promote charge transport in bulk perovskite layer and at perovskite/PCBM interface, suppressing both defect-assisted recombination and interface carrier recombination. As a result, an efficiency of 21.88% and a fill factor of 83.81% with excellent device stability are achieved, both values are the highest records for polycrystalline MAPbI(3) based p-i-n PSCs reported to date. The proposed new concept of synergetic defect passivation and energetic modification via additive provides a huge potential for further improvement of PSC performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 467, "End Page": 480, "Article Number": null, "DOI": "10.1016/j.joule.2020.12.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.12.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629204800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mukherjee, R; Thomas, AV; Datta, D; Singh, E; Li, JW; Eksik, O; Shenoy, VB; Koratkar, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mukherjee, Rahul; Thomas, Abhay V.; Datta, Dibakar; Singh, Eklavya; Li, Junwen; Eksik, Osman; Shenoy, Vivek B.; Koratkar, Nikhil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-induced plating of lithium metal within porous graphene networks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is known to possess a very high theoretical capacity of 3,842mAhg(-1) in lithium batteries. However, the use of metallic lithium leads to extensive dendritic growth that poses serious safety hazards. Hence, lithium metal has long been replaced by layered lithium metal oxide and phospho-olivine cathodes that offer safer performance over extended cycling, although significantly compromising on the achievable capacities. Here we report the defect-induced plating of metallic lithium within the interior of a porous graphene network. The network acts as a caged entrapment for lithium metal that prevents dendritic growth, facilitating extended cycling of the electrode. The plating of lithium metal within the interior of the porous graphene structure results in very high specific capacities in excess of 850mAhg(-1). Extended testing for over 1,000 charge/discharge cycles indicates excellent reversibility and coulombic efficiencies above 99%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3710, "DOI": "10.1038/ncomms4710", "DOI Link": "http://dx.doi.org/10.1038/ncomms4710", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335223100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZP; Yuan, J; Zhu, XQ; Wang, H; Huang, W; Wang, YT; Xu, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhenpo; Yuan, Jing; Zhu, Xiaoqing; Wang, Hsin; Huang, Lvwei; Wang, Yituo; Xu, Shiqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overcharge-to-thermal-runaway behavior and safety assessment of commercial lithium-ion cells with different cathode materials: A comparison study", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, overcharge behaviors and thermal runaway (TR) features of large format lithium-ion (Li-ion) cells with different cathode materials (LiFePO4 LFP), Li[Ni1/3Co1/3Mn1/3]O-2 (NCM111), Li [Ni0.6Co0.2Mn0.2]O-2 (NCM622) and Li[Ni0.8Co0.4Mn0.1]O-2 (NCM811)) were investigated. The results showed that, under the same overcharge condition, the TR of LFP Li-ion cell occurred earlier compared with the NCM Li-ion cells, indicating its poor overcharge tolerance and high TR risk. However, when TR occurred, LFP Li-ion cell exhibited lower maximum temperature and mild TR response. All NCM Li-ion cells caught fire or exploded during TR, while the LFP Li-ion cell only released a large amount of smoke without fire. According to the overcharge behaviors and TR features, a safety assessment score system was proposed to evaluate the safety of the cells. In short, NCM Li-ion cells have better performance in energy density and overcharge tolerance (or low TR risk), while LFP Li-ion cell showed less severe response to overcharging (or less TR hazards). For NCM Li-ion cells, as the ratio of nickel in cathode material increases, the thermal stability of the cathode materials becomes poorer, and the TR hazards increase. Such a comparison study on large format Li-ion cells with different cathode materials can provide deeper insights into the overcharge behaviors and TR features, and provide guidance for engineers to reasonably choose battery materials in automotive applications. (C) 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 55, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 484, "End Page": 498, "Article Number": null, "DOI": "10.1016/j.jechem.2020.07.028", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2020.07.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605241400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, K; Zhang, LF; Shan, JQ; Guo, JX; Mao, J; Yang, CC; Wang, CH; Hu, ZP; Ling, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Kun; Zhang, Lifu; Shan, Jieqiong; Guo, Jiaxin; Mao, Jing; Yang, Chueh-Cheng; Wang, Chia-Hsin; Hu, Zhenpeng; Ling, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface engineering breaks both stability and activity limits of RuO2 for sustainable water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing catalytic materials with enhanced stability and activity is crucial for sustainable electrochemical energy technologies. RuO2 is the most active material for oxygen evolution reaction (OER) in electrolysers aiming at producing 'green' hydrogen, however it encounters critical electrochemical oxidation and dissolution issues during reaction. It remains a grand challenge to achieve stable and active RuO2 electrocatalyst as the current strategies usually enhance one of the two properties at the expense of the other. Here, we report breaking the stability and activity limits of RuO2 in neutral and alkaline environments by constructing a RuO2/CoOx interface. We demonstrate that RuO2 can be greatly stabilized on the CoOx substrate to exceed the Pourbaix stability limit of bulk RuO2. This is realized by the preferential oxidation of CoOx during OER and the electron gain of RuO2 through the interface. Besides, a highly active Ru/Co dual-atom site can be generated around the RuO2/CoOx interface to synergistically adsorb the oxygen intermediates, leading to a favourable reaction path. The as-designed RuO2/CoOx catalyst provides an avenue to achieve stable and active materials for sustainable electrochemical energy technologies. RuO2 encounters critical electrochemical dissolution issues during oxygen evolution reaction and it remains a grand challenge to achieve stable and active RuO2 electrocatalyst. Here, the authors report breaking stability and activity limits of RuO2 by constructing a RuO2/CoOx interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5448, "DOI": "10.1038/s41467-022-33150-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33150-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854793700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SF; Zhang, J; Li, Z; Liu, DJ; Qin, MC; Cheung, SH; Lu, XH; Lei, DY; So, SK; Zhu, ZL; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shengfan; Zhang, Jie; Li, Zhen; Liu, Danjun; Qin, Minchao; Cheung, Sin Hang; Lu, Xinhui; Lei, Dangyuan; So, Shu Kong; Zhu, Zonglong; Jen, Alex K-Y", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulation of Defects and Interfaces through Alkylammonium Interlayer for Efficient Inverted Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PVSCs) with p-i-n configuration bear great potential for flexible photovoltaics and all perovskite or Si-perovskite multijunction solar cells because of their low-temperature processability. Nevertheless, the state-of-the-art efficiencies of p-i-n structured PVSCs suffer from non-ideal interfacial recombination and charge-extraction losses. To address these challenges, we employed a large alkylammonium interlayer (LAI) to reduce the energy loss occurred between transport layers and perovskite. The use of LAIs, in contrast with the reported bottom or top surface passivation strategies, can simultaneously suppress the non-radiative energy losses at both top and bottom interfaces of perovskite. As a result, the reduced surface recombination velocity (SRV) and trap state density (N-t) enable a substantially improved photovoltage from 1.12 to 1.21 V for the PVSCs with an optical band gap (Eg) of 1.59 eV, leading to a champion power conversion efficiency (PCE) over 22%, which is among the highest efficiencies reported for inverted PVSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2020, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1248, "End Page": 1262, "Article Number": null, "DOI": "10.1016/j.joule.2020.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542492800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, JJ; Li, PH; Zhang, HR; Song, ZY; Fan, TJ; Zhang, WQ; Tian, J; Huang, T; Qian, YT; Hou, ZG; Shpigel, N; Chen, LF; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Jia-Jia; Li, Pei-Hua; Zhang, Hao-Ran; Song, Zong-Yin; Fan, Tianju; Zhang, Wanqun; Tian, Jie; Huang, Tao; Qian, Yitai; Hou, Zhiguo; Shpigel, Netanel; Chen, Li-Feng; Dou, Shi Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulating Oxygen Vacancies to Spur Ion Kinetics in V2O5 Structures for Superior Aqueous Zinc-Ion Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vanadium-based intercalation materials have attracted considerable attention for aqueous zinc-ion batteries (ZIBs). However, the sluggish interlaminar diffusion of zinc ions due to the strong electrostatic interaction, severely restricts their practical application. Herein, oxygen vacancy-enriched V2O5 structures (Zn0.125V2O5 center dot 0.95H(2)O nulloflowers, Ov-ZVO) with expanded interlamellar space and excellent structural stability are prepared for superior ZIBs. In situ electron paramagnetic resonullce (EPR) and X-ray diffraction (XRD) characterization revealed that numerous oxygen vacancies are generated at a relatively low reaction temperature because of partially escaped lattice water. In situ spectroscopy and density functional theory (DFT) calculations unraveled that the existence of oxygen vacancies lowered Zn2+ diffusion barriers in Ov-ZVO and weakened the interaction between Zn and O atoms, thus contributing to excellent electrochemical performance. The Zn||Ov-ZVO battery displayed a remarkable capacity of 402 mAh g(-1) at 0.1 A g(-1) and impressive energy output of 193 Wh kg(-1) at 2673 W kg(-1). As a proof of concept, the Zn||Ov-ZVO pouch cell can reach a high capacity of 350 mAh g(-1) at 0.5 A g(-1), demonstrating its enormous potential for practical application. This study provides fundamental insights into formation of oxygen-vacant nullostructures and generated oxygen vacancies improving electrochemical performance, directing new pathways toward defect-functionalized advanced materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 33, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2305659, "DOI": "10.1002/adfm.202305659", "DOI Link": "http://dx.doi.org/10.1002/adfm.202305659", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001025505500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, QQ; Wu, DX; Chu, SQ; Chen, ZQ; Lin, Y; Chen, MX; Zhang, J; Wu, XJ; Liang, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Qiang-Qiang; Wu, Dao-Xiong; Chu, Sheng-Qi; Chen, Zhi-Qin; Lin, Yue; Chen, Ming-Xi; Zhang, Jing; Wu, Xiao-Jun; Liang, Hai-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-support interaction is of great significance for catalysis as it can induce charge transfer between metal and support, tame electronic structure of supported metals, impact adsorption energy of reaction intermediates, and eventually change the catalytic performance. Here, we report the metal size-dependent charge transfer reversal, that is, electrons transfer from platinum single atoms to sulfur-doped carbons and the carbon supports conversely donate electrons to Pt when their size is expanded to similar to 1.5 nm cluster. The electron-enriched Pt nulloclusters are far more active than electron-deficient Pt single atoms for catalyzing hydrogen evolution reaction, exhibiting only 11 mV overpotential at 10 mA cm(-2) and a high mass activity of 26.1 A mg(-1) at 20 mV, which is 38 times greater than that of commercial Pt/C. Our work manifests that the manipulation of metal size-dependent charge transfer between metal and support opens new avenues for developing high-active catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4977, "DOI": "10.1038/s41467-019-12851-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12851-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493438700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lázaro, IA; Haddad, S; Sacca, S; Orellana-Tavra, C; Fairen-Jimenez, D; Forgan, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lazaro, Isabel Abanades; Haddad, Salame; Sacca, Sabrina; Orellana-Tavra, Claudia; Fairen-Jimenez, David; Forgan, Ross S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective Surface PEGylation of UiO-66 nulloparticles for Enhanced Stability, Cell Uptake, and pH-Responsive Drug Delivery", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high storage capacities and excellent biocompatibilities of metal-organic frameworks (MOFs) have made them emerging candidates as drug-delivery vectors. Incorporation of surface functionality is a route to enhanced properties, and here we report on a surface-modification procedure-click modulation-that controls their size and surface chemistry. The zirconium terephthalate MOF UiO-66 is (1) synthesized as similar to 200 nm nulloparticles coated with functionalized modulators, (2) loaded with cargo, and (3) covalently surface modified with poly(ethylene glycol) (PEG) chains through mild bioconjugate reactions. At pH 7.4, the PEG chains endow the MOF with enhanced stability toward phosphates and overcome the burst release phenomenon by blocking interaction with the exterior of the nulloparticles, whereas at pH 5.5, stimuli-responsive drug release is achieved. The mode of cellular internalization is also tuned by nulloparticle surface chemistry, such that PEGylated UiO-66 potentially escapes lysosomal degradation through enhanced caveolae-mediated uptake. This makes it a highly promising vector, as demonstrated for dichloroacetic-acid-loaded materials, which exhibit enhanced cytotoxicity. The versatility of the click modulation protocol will allow a wide range of MOFs to be easily surface functionalized for a number of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2017, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": 578, "Article Number": null, "DOI": "10.1016/j.chempr.2017.02.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.02.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408620500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, T; Li, CX; Bao, YP; Fan, J; Liu, EZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Tao; Li, Chenxi; Bao, Yupeng; Fan, Jun; Liu, Enzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-Scheme MnCo2S4/g-C3N4 Heterojunction Photocatalyst for H2 Production", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increased global demand for energy and the enhanced deterioration of the environment are the two urgent challenges of the 21st century on the way to sustainable development for human society. Currently, green and renewable energy conversion technology has received much attention as a substitute for limited and non-renewable fossil fuels. Hydrogen energy is advantageous because of its high energy capacity (142 MJ center dot kg-1) and its production by green conversion technology, consisting of H2 reacting with O2 to generate H2O. It can establish a clean and sustainable hydrogen economic system, as well as reduce the utilization of fossil fuels and carbon dioxide emissions. Water splitting technology is an efficient approach to acquire the featured H2 energy of the green reaction (2H2O -> 2H2 + O2) through electrocatalytic and photocatalytic reactions. Photocatalysis technology, with the advantage of huge solar energy utilization, has been widely regarded as a promising method for the realization of this chemical synthesis. Among photocatalysis technologies, photocatalytic H2 production from water is considered a promising approach to obtain H2 energy due to its environmentally friendly energy conversion. However, the effectiveness of acquiring H2 energy through photocatalytic water splitting is intimately related with photocatalysts. In general, photocatalysts still face the big challenge of their low solar energy utilization efficiency, which restricts the large-scale application of photocatalytic technology to obtain H2 energy. Thus, developing highly efficient photocatalysts for H2 production is critical in promoting this technology moving forward, and obtaining renewable energy. Herein, we successfully construct the S-scheme MnCo2S4/g-C3N4 heterojunction through an expedient physical mixing process at a low temperature, which can be separately obtained via the pyrolysis process and hydrothermal method. The H2 production rate of MnCo2S4/g-C3N4 heterojunction can achieve up to 2979 mu mol center dot g-1 center dot h-1, which is 26.4 and 8.7 times higher than those of g-C3N4 (113 mu mol center dot g-1 center dot h-1) and MnCo2S4 (341 mu mol center dot g-1 center dot h-1), respectively, and presents a superior stability in three continuous cycles during H2 production tests. The high H2 production of MnCo2S4/g-C3N4 heterojunction is mainly ascribed to the following three reasons: i) The light absorption region of the heterojunction is extended to visible light. ii) MnCo2S4/g-C3N4 possesses low impedance during the reaction, high photocurrent density, and more exposed sites in solution. iii) The efficient reservation of active electron-hole pairs greatly enhances the ratio of electrons reacting with H* species to generate H2 over MnCo2S4/g-C3N4 heterojunction. This work provides an efficient approach to constructing advanced g-C3N4-based photocatalysts through hybridization with metal sulfides to form S-scheme heterojunctions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2023, "Volume": 39, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2212009, "DOI": "10.3866/PKU.WHXB202212009", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202212009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942795300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, SM; Wang, XF; Yi, F; Zhou, YS; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Simiao; Wang, Xiaofeng; Yi, Fang; Zhou, Yu Sheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A universal self-charging system driven by random biomechanical energy for sustainable operation of mobile electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Human biomechanical energy is characterized by fluctuating amplitudes and variable low frequency, and an effective utilization of such energy cannot be achieved by classical energy-harvesting technologies. Here we report a high-efficient self-charging power system for sustainable operation of mobile electronics exploiting exclusively human biomechanical energy, which consists of a high-output triboelectric nullogenerator, a power management circuit to convert the random a.c. energy to d.c. electricity at 60% efficiency, and an energy storage device. With palm tapping as the only energy source, this power unit provides a continuous d.c. electricity of 1.044mW (7.34 W m(-3)) in a regulated and managed manner. This self-charging unit can be universally applied as a standard 'infinite-lifetime' power source for continuously driving numerous conventional electronics, such as thermometers, electrocardiograph system, pedometers, wearable watches, scientific calculators and wireless radio-frequency communication system, which indicates the immediate and broad applications in personal sensor systems and internet of things.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 564, "Times Cited, All Databases": 605, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8975, "DOI": "10.1038/ncomms9975", "DOI Link": "http://dx.doi.org/10.1038/ncomms9975", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367588600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Simonov, A; De Baerdemaeker, T; Boström, HLB; Gómez, MLR; Gray, HJ; Chernyshov, D; Bosak, A; Bürgi, HB; Goodwin, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Simonov, Arkadiy; De Baerdemaeker, Trees; Bostrom, Hanna L. B.; Rios Gomez, Maria Laura; Gray, Harry J.; Chernyshov, Dmitry; Bosak, Alexey; Buergi, Hans-Beat; Goodwin, Andrew L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hidden diversity of vacancy networks in Prussian blue analogues", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prussian blue analogues (PBAs) are a diverse family of microporous inorganic solids, known for their gas storage ability(1), metal-ion immobilization(2), proton conduction(3), and stimuli-dependent magnetic(4,5), electronic(6) and optical(7) properties. This family of materials includes the double-metal cyanide catalysts(8,9) and the hexacyanoferrate/ hexacyanomanganate battery materials(10,11). Central to the various physical properties of PBAs is their ability to reversibly transport mass, a process enabled by structural vacancies. Conventionally presumed to be random(12,13), vacancy arrangements are crucial because they control micropore-network characteristics, and hence the diffusivity and adsorption profiles(14,15). The long-standing obstacle to characterizing the vacancy networks of PBAs is the inaccessibility of single crystals(16). Here we report the growth of single crystals of various PBAs and the measurement and interpretation of their X-ray diffuse scattering patterns. We identify a diversity of non-random vacancy arrangements that is hidden from conventional crystallographic powder analysis. Moreover, we explain this unexpected phase complexity in terms of a simple microscopic model that is based on local rules of electroneutrality and centrosymmetry. The hidden phase boundaries that emerge demarcate vacancynetwork polymorphs with very different micropore characteristics. Our results establish a foundation for correlated defect engineering in PBAs as a means of controlling storage capacity, anisotropy and transport efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 578, "Issue": 7794, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 256, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-1980-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-1980-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513110500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, LQ; Qu, JL; Niu, XG; Liu, JZ; Zhang, J; Hong, YR; Feng, MY; Wang, JW; Hu, M; Zeng, L; Zhang, QF; Guo, L; Zhu, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Leqing; Qu, Jiale; Niu, Xiaogang; Liu, Juzhe; Zhang, Juan; Hong, Youran; Feng, Meiying; Wang, Jiangwei; Hu, Miao; Zeng, Liang; Zhang, Qianfan; Guo, Lin; Zhu, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-free potassium manganese hexacyanoferrate cathode material for high-performance potassium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (KIBs) are promising electrochemical energy storage systems because of their low cost and high energy density. However, practical exploitation of KIBs is hampered by the lack of high-performance cathode materials. Here we report a potassium manganese hexacyanoferrate (K2Mn[Fe(CN)(6)]) material, with a negligible content of defects and water, for efficient high-voltage K-ion storage. When tested in combination with a K metal anode, the K2Mn[Fe(CN)(6)]-based electrode enables a cell specific energy of 609.7 Wh kg(-1) and 80% capacity retention after 7800 cycles. Moreover, a K-ion full-cell consisting of graphite and K2Mn[Fe(CN)(6)] as anode and cathode active materials, respectively, demonstrates a specific energy of 331.5 Wh kg(-1), remarkable rate capability, and negligible capacity decay for 300 cycles. The remarkable electrochemical energy storage performances of the K2Mn[Fe(CN)(6)] material are attributed to its stable frameworks that benefit from the defect-free structure. Potassium-ion battery is a promising candidate for post-Li-ion energy storage but the lack of cathode materials hinders practical exploitation. Here the authors investigate defect-free potassium manganese hexacyanoferrate as cathode active material for high energy and long lifespan K-based cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2167, "DOI": "10.1038/s41467-021-22499-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22499-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640906500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, WY; Gong, SJ; Wan, XG; Duan, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Wen-Yi; Gong, Shi-Jing; Wan, Xiangang; Duan, Chun-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Concepts of ferrovalley material and anomalous valley Hall effect", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Valleytronics rooted in the valley degree of freedom is of both theoretical and technological importance as it offers additional opportunities for information storage, as well as electronic, magnetic and optical switches. In analogy to ferroelectric materials with spontaneous charge polarization, or ferromagnetic materials with spontaneous spin polarization, here we introduce a new member of ferroic family, that is, a ferrovalley material with spontaneous valley polarization. Combining a two-band k center dot p model with first-principles calculations, we show that 2H-VSe2 monolayer, where the spin-orbit coupling coexists with the intrinsic exchange interaction of transition-metal d electrons, is such a room-temperature ferrovalley material. We further predict that such system could demonstrate many distinctive properties, for example, chirality-dependent optical band gap and, more interestingly, anomalous valley Hall effect. On account of the latter, functional devices based on ferrovalley materials, such as valley-based nonvolatile random access memory and valley filter, are contemplated for valleytronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13612, "DOI": "10.1038/ncomms13612", "DOI Link": "http://dx.doi.org/10.1038/ncomms13612", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389853200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, SC; Barr, JA; Lyu, Z; Zhang, FY; Wang, MY; Tieu, P; Li, X; Engelhard, MH; Feng, ZX; Beckman, SP; Pan, XQ; Li, JC; Du, D; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Shichao; Barr, Jordan Alysia; Lyu, Zhaoyuan; Zhang, Fangyu; Wang, Maoyu; Tieu, Peter; Li, Xin; Engelhard, Mark H.; Feng, Zhenxing; Beckman, Scott P.; Pan, Xiaoqing; Li, Jin-Cheng; Du, Dan; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Phosphorus Modulation in Iron Single-Atom Catalysts for Peroxidase Mimicking", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fe-N-C single-atom catalysts (SACs) exhibit excellent peroxidase (POD)-like catalytic activity, owing to their well-defined isolated iron active sites on the carbon substrate, which effectively mimic the structure of natural peroxidase's active center. To further meet the requirements of diverse biosensing applications, SAC POD-like activity still needs to be continuously enhanced. Herein, a phosphorus (P) heteroatom is introduced to boost the POD-like activity of Fe-N-C SACs. A 1D carbon nullowire (FeNCP/NW) catalyst with enriched Fe-N-4 active sites is designed and synthesized, and P atoms are doped in the carbon matrix to affect the Fe center through long-range interaction. The experimental results show that the P-doping process can boost the POD-like activity more than the non-P-doped one, with excellent selectivity and stability. The mechanism analysis results show that the introduction of P into SAC can greatly enhance POD-like activity initially, but its effect becomes insignificant with increasing amount of P. As a proof of concept, FeNCP/NW is employed in an enzyme cascade platform for highly sensitive colorimetric detection of the neurotransmitter acetylcholine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2024, "Volume": 36, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209633", "DOI Link": "http://dx.doi.org/10.1002/adma.202209633", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948326900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Troparevsky, MC; Morris, JR; Kent, PRC; Lupini, AR; Stocks, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Troparevsky, M. Claudia; Morris, James R.; Kent, Paul R. C.; Lupini, Andrew R.; Stocks, G. Malcolm", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Criteria for Predicting the Formation of Single-Phase High-Entropy Alloys", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys constitute a new class of materials whose very existence poses fundamental questions regarding the physical principles underlying their unusual phase stability. Originally thought to be stabilized by the large entropy of mixing associated with their large number of components (five or more), these alloys have attracted attention for their potential applications. Yet, no model capable of robustly predicting which combinations of elements will form a single phase currently exists. Here, we propose a model that, through the use of high-throughput computation of the enthalpies of formation of binary compounds, predicts specific combinations of elements most likely to form single-phase, high-entropy alloys. The model correctly identifies all known single-phase alloys while rejecting similar elemental combinations that are known to form an alloy comprising multiple phases. In addition, we predict numerous potential single-phase alloy compositions and provide three tables with the ten most likely five-, six-, and seven-component single-phase alloys to guide experimental searches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11041, "DOI": "10.1103/PhysRevX.5.011041", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.011041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352063800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ares, P; Aguilar-Galindo, F; Rodríguez-San-Miguel, D; Aldave, DA; Díaz-Tendero, S; Alcamí, M; Martín, F; Gómez-Herrero, J; Zamora, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ares, Pablo; Aguilar-Galindo, Fernulldo; Rodriguez-San-Miguel, David; Aldave, Diego A.; Diaz-Tendero, Sergio; Alcami, Manuel; Martin, Fernulldo; Gomez-Herrero, Julio; Zamora, Felix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical Isolation of Highly Stable Antimonene under Ambient Conditions", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimonene fabricated by mechanical exfoliation is highly stable under atmospheric conditions over periods of months and even when immersed in water. Density functional theory confirms the experiments and predicts an electronic gap of approximate to 1 eV. These results highlight the use of antimonene for optoelectronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 467, "Times Cited, All Databases": 481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2016, "Volume": 28, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6332, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201602128", "DOI Link": "http://dx.doi.org/10.1002/adma.201602128", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382480100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vaalma, C; Giffin, GA; Buchholz, D; Passerini, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vaalma, Christoph; Giffin, Guinevere A.; Buchholz, Daniel; Passerini, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-Aqueous K-Ion Battery Based on Layered K0.3MnO2 and Hard Carbon/Carbon Black", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we present the synthesis and characterization of negative (a hard carbon/carbon black composite) and positive (K0.3MnO2) active materials for K-ion batteries as well as their combination in a non-aqueous K-ion cell. The hard carbon/carbon black composite can deliver up to 200 mAh g(-1) while the layered birnessite K0.3MnO2 delivers up to 136 mAh g(-1). The K-ion cell exhibits an interesting and encouraging cycling performance for 100 cycles. These exciting new insights demonstrate the potential of K-ion batteries, which are worth to be further investigated in greater detail. (C) The Author(s) 2016. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 163, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A1295", "End Page": "A1299", "Article Number": null, "DOI": "10.1149/2.0921607jes", "DOI Link": "http://dx.doi.org/10.1149/2.0921607jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377412900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Zhao, XH; Zhu, P; Adler, Z; Wu, ZY; Liu, YY; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao; Zhao, Xunhua; Zhu, Peng; Adler, Zachary; Wu, Zhen-Yu; Liu, Yuanyue; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical oxygen reduction to hydrogen peroxide at practical rates in strong acidic media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical oxygen reduction to hydrogen peroxide (H2O2) in acidic media, especially in proton exchange membrane (PEM) electrode assembly reactors, suffers from low selectivity and the lack of low-cost catalysts. Here we present a cation-regulated interfacial engineering approach to promote the H2O2 selectivity (over 80%) under industrial-relevant generation rates (over 400 mA cm(-2)) in strong acidic media using just carbon black catalyst and a small number of alkali metal cations, representing a 25-fold improvement compared to that without cation additives. Our density functional theory simulation suggests a shielding effect of alkali metal cations which squeeze away the catalyst/electrolyte interfacial protons and thus prevent further reduction of generated H2O2 to water. A double-PEM solid electrolyte reactor was further developed to realize a continuous, selective (similar to 90%) and stable (over 500 hours) generation of H2O2 via implementing this cation effect for practical applications. Electrochemical oxygen reduction to H2O2 in acidic media suffers from low selectivity, especially at high current densities. Here, the authors report a cation-regulated shielding effect to promote the H2O2 selectivity under industrial-relevant current in strong acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2880, "DOI": "10.1038/s41467-022-30337-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30337-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000801198000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XX; Wang, R; Jiao, TF; Zou, GD; Zhan, FK; Yin, JJ; Zhang, LX; Zhou, JX; Peng, QM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xinxin; Wang, Ran; Jiao, Tifeng; Zou, Guodong; Zhan, Fangke; Yin, Juanjuan; Zhang, Lexin; Zhou, Jingxin; Peng, Qiuming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile Preparation of Hierarchical AgNP-Loaded MXene/Fe3O4/Polymer nullocomposites by Electrospinning with Enhanced Catalytic Performance for Wastewater Treatment", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene as a kind of two-dimensional nullomaterial has aroused people's strong research interest because of its excellent properties. In the present study, we introduced a new poly(vinyl alcohol)/poly(acrylic acid)/Fe3O4/MXene@Ag nulloparticle composite film fabricated by electrospinning and heat treatment as well as self-reduction reaction process. The obtained composite films showed high self-reduction ability because of the incorporation of MXene flakes. The intercalated MXene flakes in the composite nullofibers were evenly distributed, which not only solved the aggregation problem from MXene dispersion but also could self-reduce Ag nulloparticles in situ in composite materials. In addition, the composite nullofiber films exhibited good fiber structure, thermal stability, and magnetic properties. Moreover, the composite nullofiber films demonstrated excellent catalytic ability and cycle stability to 4-nitrophenol and 2-nitroaniline.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1897, "End Page": 1906, "Article Number": null, "DOI": "10.1021/acsomega.8b03615", "DOI Link": "http://dx.doi.org/10.1021/acsomega.8b03615", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460214700208", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Xu, XY; Kapitanova, OO; Evdokimov, P; Song, ZX; Matic, A; Xiong, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yangyang; Xu, Xieyu; Kapitanova, Olesya O.; Evdokimov, Pavel, V; Song, Zhongxiao; Matic, Aleksandar; Xiong, Shizhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electro-Chemo-Mechanical Modeling of Artificial Solid Electrolyte Interphase to Enable Uniform Electrodeposition of Lithium Metal Anodes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonuniform electrodeposition of lithium during charging processes is the key issue hindering development of rechargeable Li metal batteries. This deposition process is largely controlled by the solid electrolyte interphase (SEI) on the metal surface and the design of artificial SEIs is an essential pathway to regulate electrodeposition of Li. In this work, an electro-chemo-mechanical model is built and implemented in a phase-field modelling to understand the correlation between the physical properties of artificial SEIs and deposition of Li. The results show that improving ionic conductivity of the SEI above a critical level can mitigate stress concentration and preferred deposition of Li. In addition, the mechanical strength of the SEI is found to also mitigate non-uniform deposition and influence electrochemical kinetics, with a Young's modulus around 4.0 GPa being a threshold value for even deposition of Li. By comparison of the results to experimental results for artificial SEIs it is clear that the most important direction for future work is to improve the ionic conductivity without compromising mechanical strength. In addition, the findings and methodology presented here not only provide detailed guidelines for design of artificial SEI on Li-metal anodes but also pave the way to explore strategies for regulating deposition of other metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103589, "DOI": "10.1002/aenm.202103589", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103589", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742745600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khenkin, MV; Katz, EA; Abate, A; Bardizza, G; Berry, JJ; Brabec, C; Brunetti, F; Bulovic, V; Burlingame, Q; Di Carlo, A; Cheacharoen, R; Cheng, YB; Colsmann, A; Cros, S; Domanski, K; Dusza, M; Fell, CJ; Forrest, SR; Galagan, Y; Di Girolamo, D; Graetzel, M; Hagfeldt, A; von Hauff, E; Hoppe, H; Kettle, J; Koebler, H; Leite, MS; Liu, S; Loo, YL; Luther, JM; Ma, CQ; Madsen, M; Manceau, M; Matheron, M; McGehee, M; Meitzner, R; Nazeeruddin, MK; Nogueira, AF; Odabasi, C; Osherov, A; Park, NG; Reese, MO; De Rossi, F; Saliba, M; Schubert, US; Snaith, HJ; Stranks, SD; Tress, W; Troshin, PA; Turkovic, V; Veenstra, S; Visoly-Fisher, I; Walsh, A; Watson, T; Xie, HB; Yildirim, R; Zakeeruddin, SM; Zhu, K; Lira-Cantu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khenkin, Mark V.; Katz, Eugene A.; Abate, Antonio; Bardizza, Giorgio; Berry, Joseph J.; Brabec, Christoph; Brunetti, Francesca; Bulovic, Vladimir; Burlingame, Quinn; Di Carlo, Aldo; Cheacharoen, Rongrong; Cheng, Yi-Bing; Colsmann, Alexander; Cros, Stephane; Domanski, Konrad; Dusza, Michal; Fell, Christopher J.; Forrest, Stephen R.; Galagan, Yulia; Di Girolamo, Diego; Graetzel, Michael; Hagfeldt, Anders; von Hauff, Elizabeth; Hoppe, Harald; Kettle, Jeff; Koebler, Hans; Leite, Marina S.; Liu, Shengzhong (Frank); Loo, Yueh-Lin; Luther, Joseph M.; Ma, Chang-Qi; Madsen, Morten; Manceau, Matthieu; Matheron, Muriel; McGehee, Michael; Meitzner, Rico; Nazeeruddin, Mohammad Khaja; Nogueira, Ana Flavia; Odabasi, Cagla; Osherov, Anna; Park, Nam-Gyu; Reese, Matthew O.; De Rossi, Francesca; Saliba, Michael; Schubert, Ulrich S.; Snaith, Henry J.; Stranks, Samuel D.; Tress, Wolfgang; Troshin, Pavel A.; Turkovic, Vida; Veenstra, Sjoerd; Visoly-Fisher, Iris; Walsh, Aron; Watson, Trystan; Xie, Haibing; Yildirim, Ramazan; Zakeeruddin, Shaik Mohammed; Zhu, Kai; Lira-Cantu, Monica", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Consensus statement for stability assessment and reporting for perovskite photovoltaics based on ISOS procedures", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis. Reliability of stability data for perovskite solar cells is undermined by a lack of consistency in the test conditions and reporting. This Consensus Statement outlines practices for testing and reporting stability tailoring ISOS protocols for perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1099, "Times Cited, All Databases": 1139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 35, "End Page": 49, "Article Number": null, "DOI": "10.1038/s41560-019-0529-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0529-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509196700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, XJ; Zhou, JH; Wang, PF; Chen, H; Yang, TT; Chen, SY; Miao, L; Mori, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Xiaojiang; Zhou, Jianhua; Wang, Pengfei; Chen, Huan; Yang, Tingting; Chen, Siyi; Miao, Lei; Mori, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust starch-polyacrylamide hydrogel with scavenging energy harvesting capacity for efficient solar thermoelectricity-freshwater cogeneration", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The simultaneous production of clean water and electricity using solar energy has been proposed as a promising solution to water scarcity and electricity shortage. Here, we design a thermoelectricity-freshwater cogenerator based on a thermoelectric generator (TEG) and a starch-polyacrylamide (S-PAM) hydrogel to make the maximum use of solar energy and scavenging energy. A commercial TiNOx blue membrane with high absorptance and low emissivity covers the hot side of the TEG, which is used as the solar absorber for the main energy input. The S-PAM hydrogel underneath the cold side of TEG uses waste heat for evaporation, constituting the multistage utilization of solar energy. The temperature of the evaporation surface drops below the environmental temperature by the optimization of heat transfer channels at the cold side, resulting in a net energy gain from the environment. Simultaneously, the S-PAM hydrogel possessing a hydrophilic and porous 3D network can accommodate much water to absorb heat at the cold side of TEG during the evaporation of water, which creates a large temperature difference between the two sides of TEG and thus in turn, elevates the thermoelectricity performance. The conductive heat loss from the purifier to bulk water is fully eliminated by spraying water and the rapid heat exchange occurs at the cold side of the TEG, which results in further electricity enhancement. Due to the utilization of the scavenging energy, our hybrid cogenerator obtains an evaporation rate of 1.79 kg m(-2) h(-1) and a record maximum output power density of 11.39 W m(-2) during water spraying for 2 minutes under one-sun illumination in reported cogeneration systems based on TEGs. Therefore, ours is a pioneering study on a highly efficient and sustainable way to harvest solar and scavenging energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2022, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3388, "End Page": 3399, "Article Number": null, "DOI": "10.1039/d2ee01394k", "DOI Link": "http://dx.doi.org/10.1039/d2ee01394k", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822867700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, Y; Cao, KW; He, JW; Li, FM; Huang, H; Chen, P; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Yu; Cao, Kai-Wen; He, Jia-Wei; Li, Fu-Min; Huang, Hao; Chen, Pei; Chen, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-doped graphene aerogel-supported ruthenium nullocrystals for pH-universal hydrogen evolution reaction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and synthesis of high-performance and low-cost electrocatalysts for the hydrogen evolution reaction (HER), a key half-reaction in water electrolysis, are essential. Owing to their modest hydrogen adsorption energy, ruthenium (Ru)-based nullomaterials are considered outstanding candidates to replace the expensive platinum (Pt)-based HER electrocatalysts. In this study, we developed an adsorption-pyrolysis method to construct nitrogen (N)-doped graphene aerogel (N-GA)-supported ultrafine Ru nullocrystal (Ru-NC) nullocomposites (Ru-NCs/N-GA). The particle size of the Ru-NCs and the conductivity of the N-GA substrate can be controlled by varying the pyrolysis temperature. Optimal experiments reveal revealed that 10 wt% Ru-NCs/N-GA nullocomposites require overpotentials of only 52 and 36 mV to achieve a current density of 10 mA cm???2 in 1 mol/L HClO4 and 1 mol/L KOH electrolytes for HER, respectively, which is comparable to 20 wt% Pt/C electrocatalyst. Benefiting from the ultrafine size and uniform dispersion of the Ru-NCs, the synergy between Ru and the highly conductive substrate, and the anchoring effect of the N atom, the Ru-NCs/N-GA nullocomposites exhibit excellent activity and durability in the pH-universal HER, thereby opening a new avenue for the production of commercial HER electrocatalysts. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 43, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1535, "End Page": 1543, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63977-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63977-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799204200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Capanema, NSV; Mansur, AAP; de Jesus, AC; Carvalho, SM; de Oliveira, LC; Mansur, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Capanema, Nadia S. V.; Mansur, Alexandra A. P.; de Jesus, Anderson C.; Carvalho, Sandhra M.; de Oliveira, Luiz C.; Mansur, Herman S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superabsorbent crosslinked carboxymethyl cellulose-PEG hydrogels for potential wound dressing applications", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study focused on the synthesis and comprehensive characterization of environmentally friendly hydrogel membranes based on carboxymethyl cellulose (CMC) for wound dressing and skin repair substitutes. These new CMC hydrogels were prepared with two degrees of functionalization (DS = 0.77 and 1.22) and chemically crosslinked with citric acid (CA) for tuning their properties. Additionally, CMC-based hybrids were prepared by blending with polyethylene glycol (PEG, 10 wt.%). The results demonstrated that superabsorbent hydrogels (SAP) were produced with swelling degree typically ranging from 100% to 5000%, which was significantly dependent on the concentration of CA crosslinker and the addition of PEG as network modifier. The spectroscopical characterizations indicated that the mechanism of CA crosslinking was mostly associated with the chemical reaction with CMC hydroxyl groups and that PEG played an important role on the formation of a hybrid polymeric network. These hydrogels presented very distinct morphological features depended on the degree of crosslinking and the surface nullomechanical properties (e.g., elastic moduli) were drastically affected (from approximately 0.08 GPa to 2.0 GPa) due to the formation of CMC-PEG hybrid nullostructures. These CMC-based hydrogels were cytocompatible considering the in vitro cell viability responses of over 95% towards human embryonic kidney cells (HEK293T) used as model cell line. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 106, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1218, "End Page": 1234, "Article Number": null, "DOI": "10.1016/j.ijbiomac.2017.08.124", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2017.08.124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417661600136", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kovtun, A; Jones, D; Dell'Elce, S; Treossi, E; Liscio, A; Palermo, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kovtun, Alessandro; Jones, Derek; Dell'Elce, Simone; Treossi, Emanuele; Liscio, Andrea; Palermo, Vincenzo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accurate chemical analysis of oxygenated graphene-based materials using X-ray photoelectron spectroscopy", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A simple, fast and general protocol for quantitative analysis of X-ray photoelectron spectroscopy (XPS) data provides accurate estimations of chemical species in graphene and related materials (GRMs). XPS data are commonly used to estimate the quality of and defects in graphene and graphene oxide (GO), by comparing carbon and oxygen 1s XPS peaks, obtaining an O/C ratio. This approach, however, cannot be used in the presence of extraneous oxygen contamination. The protocol, based on quantitative line-shape analysis of C 1s signals, uses asymmetric pseudo-Voigt line-shapes (APV), in contrast to Gaussian-based approaches conventionally used in fitting XPS spectra, thus allowing better accuracy in quantifying C 1s contributions from graphitic carbon (sp2), defects (sp3 carbon), carbons bonded to hydroxyl and epoxy groups, and from carbonyl and carboxyl groups. The APV protocol was evaluated on GRMs with O/C ratios ranging from 0.02 to 0.30 with film thicknesses from monolayers to bulk-like (>30 nm) layers and also applied to previously published data, showing better results compared to those from conventional XPS fitting protocols. Based uniquely on C 1s data, the APV protocol can quantify O/C ratio and the presence of specific functional groups in GRMs even on SiOx, substrates, or in samples containing water. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 143, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": 275, "Article Number": null, "DOI": "10.1016/j.carbon.2018.11.012", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2018.11.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456710500030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carey, T; Cacovich, S; Divitini, G; Ren, JS; Mansouri, A; Kim, JM; Wang, CX; Ducati, C; Sordan, R; Torrisi, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carey, Tian; Cacovich, Stefania; Divitini, Giorgio; Ren, Jiesheng; Mansouri, Aida; Kim, Jong M.; Wang, Chaoxia; Ducati, Caterina; Sordan, Roman; Torrisi, Felice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully inkjet-printed two-dimensional material field-effect heterojunctions for wearable and textile electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fully printed wearable electronics based on two-dimensional (2D) material heterojunction structures also known as heterostructures, such as field-effect transistors, require robust and reproducible printed multi-layer stacks consisting of active channel, dielectric and conductive contact layers. Solution processing of graphite and other layered materials provides low-cost inks enabling printed electronic devices, for example by inkjet printing. However, the limited quality of the 2D-material inks, the complexity of the layered arrangement, and the lack of a dielectric 2D-material ink able to operate at room temperature, under strain and after several washing cycles has impeded the fabrication of electronic devices on textile with fully printed 2D heterostructures. Here we demonstrate fully inkjet-printed 2D-material active heterostructures with graphene and hexagonal-boron nitride (h-BN) inks, and use them to fabricate all inkjet-printed flexible and washable field-effect transistors on textile, reaching a field-effect mobility of similar to 91 cm(2) V-1 s(-1), at low voltage (< 5 V). This enables fully inkjet-printed electronic circuits, such as reprogrammable volatile memory cells, complementary inverters and OR logic gates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1202, "DOI": "10.1038/s41467-017-01210-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01210-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414032200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, DHS; Wu, EA; Nguyen, H; Chen, Z; Marple, MAT; Doux, JM; Wang, XF; Yang, HD; Banerjee, A; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Darren H. S.; Wu, Erik A.; Han Nguyen; Chen, Zheng; Marple, Maxwell A. T.; Doux, Jean-Marie; Wang, Xuefeng; Yang, Hedi; Banerjee, Abhik; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elucidating Reversible Electrochemical Redox of Li6PS5CI Solid Electrolyte", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfide-based solid electrolytes are promising candidates for all solid-state batteries (ASSBs) due to their high ionic conductivity and ease of processability. However, their narrow electrochemical stability window causes undesirable electrolyte decomposition. Existing literature on Li-ion ASSBs report an irreversible nature of such decompositions, while Li-S ASSBs show evidence of some reversibility. Here, we explain these observations by investigating the redox mechanism of argyrodite Li6PS5Cl at various chemical potentials. We found that Li-In vertical bar Li6PS5Cl vertical bar Li6PS5Cl-C half-cells can be cycled reversibly, delivering capacities of 965 mAh g(-1) for the electrolyte itself. During charging, Li6PS5Cl forms oxidized products of sulfur (S) and phosphorus pentasulfide (P2S5), while during discharge, these products are first reduced to a Li3PS4 intermediate before forming lithium sulfide (Li2S) and lithium phosphide (Li3P). Finally, we quantified the relative contributions of the products toward cell impedance and proposed a strategy to reduce electrolyte decomposition and increase cell Coulombic efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2418, "End Page": 2427, "Article Number": null, "DOI": "10.1021/acsenergylett.9b01693", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b01693", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490365500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YF; Lu, XF; Wu, ZP; Pei, ZH; Luan, DY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yafei; Lu, Xue Feng; Wu, Zhi-Peng; Pei, Zhihao; Luan, Deyan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supporting Trimetallic Metal-Organic Frameworks on S/N-Doped Carbon Macroporous Fibers for Highly Efficient Electrocatalytic Oxygen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid materials, integrating the merits of individual components, are ideal structures for efficient oxygen evolution reaction (OER). However, the rational construction of hybrid structures with decent physical/electrochemical properties is yet challenging. Herein, a promising OER electrocatalyst composed of trimetallic metal-organic frameworks supported over S/N-doped carbon macroporous fibers (S/N-CMF@FexCoyNi1-x-y-MOF) via a cation-exchange strategy is delicately fabricated. Benefiting from the trimetallic composition with improved intrinsic activity, hollow S/N-CMF matrix facilitating exposure of active sites, as well as their robust integration, the resultant S/N-CMF@FexCoyNi1-x-y-MOF electrocatalyst delivers outstanding activity and stability for alkaline OER. Specifically, it needs an overpotential of 296 mV to reach the benchmark current density of 10 mA cm(-2) with a small Tafel slope of 53.5 mV dec(-1). In combination with X-ray absorption fine structure spectroscopy and density functional theory calculations, the post-formed Fe/Co-doped gamma-NiOOH during the OER operation is revealed to account for the high OER performance of S/N-CMF@FexCoyNi1-x-y-MOF.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 35, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207888", "DOI Link": "http://dx.doi.org/10.1002/adma.202207888", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961595600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xin, TZ; Zhao, YH; Mahjoub, R; Jiang, JX; Yadav, A; Nomoto, K; Niu, RM; Tang, S; Ji, F; Quadir, Z; Miskovic, D; Daniels, J; Xu, WQ; Liao, XZ; Chen, LQ; Hagihara, K; Li, XY; Ringer, S; Ferry, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xin, Tongzheng; Zhao, Yuhong; Mahjoub, Reza; Jiang, Jiaxi; Yadav, Apurv; Nomoto, Keita; Niu, Ranming; Tang, Song; Ji, Fan; Quadir, Zakaria; Miskovic, David; Daniels, John; Xu, Wanqiang; Liao, Xiaozhou; Chen, Long-Qing; Hagihara, Koji; Li, Xiaoyan; Ringer, Simon; Ferry, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh specific strength in a magnesium alloy strengthened by spinodal decomposition", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strengthening of magnesium (Mg) is known to occur through dislocation accumulation, grain refinement, deformation twinning, and texture control or dislocation pinning by solute atoms or nullo-sized precipitates. These modes generate yield strengths comparable to other engineering alloys such as certain grades of aluminum but below that of high-strength aluminum and titanium alloys and steels. Here, we report a spinodal strengthened ultralightweight Mg alloy with specific yield strengths surpassing almost every other engineering alloy. We provide compelling morphological, chemical, structural, and thermodynamic evidence for the spinodal decomposition and show that the lattice mismatch at the diffuse transition region between the spinodal zones and matrix is the dominating factor for enhancing yield strength in this class of alloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 7, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabf3039", "DOI": "10.1126/sciadv.abf3039", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abf3039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658757100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, D; Liu, JC; Cai, WZ; Ma, J; Yang, HB; Xiao, H; Li, J; Xiong, YJ; Huang, YQ; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dong; Liu, Jin-Cheng; Cai, Weizheng; Ma, Jun; Yang, Hong Bin; Xiao, Hai; Li, Jun; Xiong, Yujie; Huang, Yanqiang; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective photoelectrochemical oxidation of glycerol to high value-added dihydroxyacetone", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is highly profitable to transform glycerol - the main by-product from biodiesel production to high value-added chemicals. In this work, we develop a photoelectrochemical system based on nulloporous BiVO4 for selective oxidation of glycerol to 1,3-dihydroxyacetone - one of the most valuable derivatives of glycerol. Under AM 1.5G front illumination (100 mW cm(-2)) in an acidic medium (pH = 2) without adscititious oxidant, the nulloporous BiVO4 photoanode achieves a glycerol oxidation photocurrent density of 3.7 mA cm(-2) at a potential of 1.2 V versus RHE with 51% 1,3-dihydroxyacetone selectivity, equivalent to a production rate of 200 mmol of 1,3-dihydroxyacetone per m(2) of illumination area in one hour.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1779, "DOI": "10.1038/s41467-019-09788-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09788-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464654700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HS; Gibbs, ZM; Tang, YL; Wang, H; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyun-Sik; Gibbs, Zachary M.; Tang, Yinglu; Wang, Heng; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of Lorenz number with Seebeck coefficient measurement", "Source Title": "APL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In analyzing zT improvements due to lattice thermal conductivity (kappa(L)) reduction, electrical conductivity (sigma) and total thermal conductivity (kappa(Total)) are often used to estimate the electronic component of the thermal conductivity (kappa(E)) and in turn kappa(L) from kappa(L) = similar to kappa(Total) - L sigma T. TheWiedemann-Franz law, kappa(E) = L sigma T, where L is Lorenz number, is widely used to estimate kappa(E) from sigma measurements. It is a common practice to treat L as a universal factor with 2.44 x 10(-8) W Omega K-2 (degenerate limit). However, significant deviations from the degenerate limit (approximately 40% or more for Kane bands) are known to occur for non-degenerate semiconductors where L converges to 1.5 x 10(-8) W Omega K-2 for acoustic phonon scattering. The decrease in L is correlated with an increase in thermopower (absolute value of Seebeck coefficient (S)). Thus, a first order correction to the degenerate limit of L can be based on the measured thermopower, vertical bar S vertical bar, independent of temperature or doping. We propose the equation: L = 1.5 + exp [ -vertical bar S vertical bar/116] (where L is in 10(-8) W Omega K-2 and S in mu V/K) as a satisfactory approximation for L. This equation is accurate within 5% for single parabolic band/acoustic phonon scattering assumption and within 20% for PbSe, PbS, PbTe, Si0.8Ge0.2 where more complexity is introduced, such as non-parabolic Kane bands, multiple bands, and/or alternate scattering mechanisms. The use of this equation for L rather than a constant value (when detailed band structure and scattering mechanism is not known) will significantly improve the estimation of lattice thermal conductivity. (C) 2015 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1564, "Times Cited, All Databases": 1632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41506, "DOI": "10.1063/1.4908244", "DOI Link": "http://dx.doi.org/10.1063/1.4908244", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353828400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, YF; Sharpe, R; He, K; Li, CH; Saray, MT; Liu, TC; Yao, WT; Cheng, M; Jin, HL; Wang, S; Amine, K; Shahbazian-Yassar, R; Islam, MS; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Yifei; Sharpe, Ryan; He, Kun; Li, Chenghang; Saray, Mahmoud Tamadoni; Liu, Tongchao; Yao, Wentao; Cheng, Meng; Jin, Huile; Wang, Shun; Amine, Khalil; Shahbazian-Yassar, Reza; Islam, M. Saiful; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding intercalation chemistry for sustainable aqueous zinc-manganese dioxide batteries", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous Zn-MnO2 technology combines one of the oldest battery chemistries with favourable sustainability characteristics, including safety, cost and environmental compatibility. However, the ambiguous charge storage mechanism presents a challenge to fulfil the great potential of this energy technology. Here we leverage on advanced electron microscopy, electrochemical analysis and theoretical calculations to look into the intercalation chemistry within the cathode material, or alpha-MnO2 more specifically. We show that Zn2+ insertion into the cathode is unlikely in the aqueous system; rather, the charge storage process is dominated by proton intercalation to form alpha-HxMnO2. We further reveal anisotropic lattice change as a result of entering protons proceeding from the surface into the bulk of alpha-MnO2, which accounts for the structural failure and capacity decay of the electrode upon cycling. Our work not only advances the fundamental understanding of rechargeable zinc batteries but also suggests the possibility to optimize proton intercalation kinetics for better-performing cell designs. A rechargeable aqueous Zn-MnO2 battery features a combination of favourable sustainability characteristics from safety to cost. The authors deploy advanced characterizations and theoretical calculations to provide fresh insight into the charge storage mechanism, which not only closes an ongoing debate but suggests ways forward.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 890, "End Page": 898, "Article Number": null, "DOI": "10.1038/s41893-022-00919-3", "DOI Link": "http://dx.doi.org/10.1038/s41893-022-00919-3", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837600000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, SG; Luo, X; Chan, HL; Xiao, CC; Dai, YW; Xie, MH; Hao, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Shuoguo; Luo, Xin; Chan, Hung Lit; Xiao, Chengcheng; Dai, Yawei; Xie, Maohai; Hao, Jianhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature ferroelectricity in MoTe2 down to the atomic monolayer limit", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectrics allow for a wide range of intriguing applications. However, maintaining ferroelectricity has been hampered by intrinsic depolarization effects. Here, by combining first-principles calculations and experimental studies, we report on the discovery of robust room-temperature out-of-plane ferroelectricity which is realized in the thinnest monolayer MoTe2 with unexploited distorted 1T (d1T) phase. The origin of the ferroelectricity in d1T-MoTe2 results from the spontaneous symmetry breaking due to the relative atomic displacements of Mo atoms and Te atoms. Furthermore, a large ON/OFF resistance ratio is achieved in ferroelectric devices composed of MoTe2-based van der Waals heterostructure. Our work demonstrates that ferroelectricity can exist in two-dimensional layered material down to the atomic monolayer limit, which can result in new functionalities and achieve unexpected applications in atomic-scale electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1775, "DOI": "10.1038/s41467-019-09669-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09669-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464654700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, JY; Lyu, YH; Qiao, M; Wang, RL; Zhou, YY; Li, H; Chen, C; Li, YF; Zhou, HJ; Jiang, SP; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jianyun; Lyu, Yanhong; Qiao, Man; Wang, Ruilun; Zhou, Yangyang; Li, Hao; Chen, Chen; Li, Yafei; Zhou, Huaijuan; Jiang, San Ping; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoelectrochemical Synthesis of Ammonia on the Aerophilic-Hydrophilic Heterostructure with 37.8% Efficiency", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical nitrogen reduction reaction can provide a useful source of ammonia and transportable carrier of hydrogen, but the process is limited by the photocathodes with poor conversion efficiency and low production rate. Here, we have designed a unique aerophilic-hydrophilic heterostructured Si-based photocathode for nitrogen-to-ammonia fixation in an acid electrolyte under mild conditions, achieving a high ammonia yield rate of similar to 18.9 mu g.cm(-2).hr(-1) and an excellent faradic efficiency of 37.8% at -0.2 V versus a reversible hydrogen electrode The heterostructure based on the Au nulloparticles highly dispersed in poly(tetrafluoroethylene) porous framework enriches nitrogen molecular concentration at the Au active sites while manipulateing the proton activity with suppressed hydrogen evolution reactions. DFT calculation indicates that such heterostructure reduces the energy barrier for the nitrogen reduction reaction. The aerophilic-hydrophilic heterostructure provides a new insight on designing efficient and robust photocathodes for nitrogen fixation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2019, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 617, "End Page": 633, "Article Number": null, "DOI": "10.1016/j.chempr.2018.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.12.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461193300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, SY; Sui, LZ; Liu, Y; Yong, X; Xiao, GJ; Yuan, KJ; Liu, ZY; Liu, BZ; Zou, B; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Siyu; Sui, Laizhi; Liu, Yuan; Yong, Xue; Xiao, Guanjun; Yuan, Kaijun; Liu, Zhongyi; Liu, Baozhong; Zou, Bo; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "White Photoluminescent Ti3C2 MXene Quantum Dots with Two-Photon Fluorescence", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A recently created class of inorganic 2D materials, MXenes, has become a subject of intensive research. Reducing their dimensionality from 2D to 0D quantum dots (QDs) could result in extremely useful properties and functions. However, this type of research is scarce, and the reported Ti3C2 MXene QDs (MQDs) have only shown blue fluorescence emission. This work demonstrates a facile, high-output method for preparing bright white emitting Ti3C2 MQDs. The resulting product is two layers thick with a lateral dimension of 13.1 nm. Importantly, the as prepared Ti3C2 MQDs present strong two-photon white fluorescence. Their fluorescence under high pressure is also investigated and it is found that the white emission is very stable and the pressure makes it possible to change from cool white emission to warm white emission. Hybrid nullocomposites are then fabricated by polymerizing Ti3C2 MQDs in polydimethylsiloxane (PDMS) solution, and the bright white emitting hybrid materials in white light-emitting diodes are used. This work provides a facile and general approach to modulate various nulloscale MXene materials, and could further aid the wide development of applications for MXene materials in various optical-related fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801470, "DOI": "10.1002/advs.201801470", "DOI Link": "http://dx.doi.org/10.1002/advs.201801470", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467524500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Backes, C; Szydlowska, BM; Harvey, A; Yuan, SJ; Vega-Mayoral, V; Davies, BR; Zhao, PL; Hanlon, D; Santos, EJG; Katsnelson, MI; Blau, WJ; Gadermaier, C; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Backes, Claudia; Szydlowska, Beata M.; Harvey, Andrew; Yuan, Shengjun; Vega-Mayoral, Victor; Davies, Ben R.; Zhao, Pei-liang; Hanlon, Damien; Santos, Elton J. G.; Katsnelson, Mikhail I.; Blau, Werner J.; Gadermaier, Christoph; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Production of Highly Monolayer Enriched Dispersions of Liquid-Exfoliated nullosheets by Liquid Cascade Centrifugation", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While liquid exfoliation is a powerful technique to produce defect-free nullosheets in large quantities, its usefulness is limited by broad nullosheet thickness distributions and-Iow monolayer contents. Here we demonstrate liquid processing techniques, based on iterative centrifugation cascades, which can be designed to achieve either highly efficient nullosheet size-selection and/or monolayer enrichment. The resultant size-selected dispersions were used to establish quantitative metrics to determine monolayer volume fraction, as well as mean nullosheet size and thickness, from standard spectroscopic measurements. Such metrics allowed us to design and optimize centrifugation cascades to enrich liquid exfoliated WS2 dispersions up to monolayer contents of 75%. Monolayer-rich dispersions show relatively bright photoluminescence with narrow line widths (<35 meV) indicating the high quality of the nullosheets. The enriched dispersions display extinction spectra with distinct features, which also allow the direct estimation of monolayer contents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1589, "End Page": 1601, "Article Number": null, "DOI": "10.1021/acsnullo.5b07228", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b07228", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369115800178", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roy, T; Tosun, M; Kang, JS; Sachid, AB; Desai, SB; Hettick, M; Hu, CMC; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roy, Tania; Tosun, Mahmut; Kang, Jeong Seuk; Sachid, Angada B.; Desai, Sujay B.; Hettick, Mark; Hu, Chenming C.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-Effect Transistors Built from All Two-Dimensional Material Components", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate field-effect transistors using heterogeneously stacked two-dimensional materials for all of the components, including the semiconductor, insulator, and metal layers. Specifically, MoS2 is used as the active channel material, hexagonal-BN as the top-gate dielectric, and graphene as the source/drain and the top-gate contacts. This transistor exhibits n-type behavior with an ON/OFF current ratio of >10(6), and an electron mobility of similar to 33 cm(2)/V.s. Uniquely, the mobility does not degrade at high gate voltages, presenting an important advantage over conventional Si transistors where enhanced surface roughness scattering severely reduces carrier mobilities at high gate-fields. A WSe2-MoS2 diode with graphene contacts is also demonstrated. The diode exhibits excellent rectification behavior and a low reverse bias current, suggesting high quality interfaces between the stacked layers. In this work, all interfaces are based on van der Waals bonding, presenting a unique device architecture where crystalline, layered materials with atomically uniform thicknesses are stacked on demand, without the lattice parameter constraints. The results demonstrate the promise of using an all-layered material system for future electronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6259, "End Page": 6264, "Article Number": null, "DOI": "10.1021/nn501723y", "DOI Link": "http://dx.doi.org/10.1021/nn501723y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338089200092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, SR; Zihlmann, C; Akbari, M; Assawes, P; Cheung, L; Zhang, KZ; Manoharan, V; Zhang, YS; Yüksekkaya, M; Wan, KT; Nikkhah, M; Dokmeci, MR; Tang, XW; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Su Ryon; Zihlmann, Claudio; Akbari, Mohsen; Assawes, Pribpandao; Cheung, Louis; Zhang, Kaizhen; Manoharan, Vijayan; Zhang, Yu Shrike; Yuksekkaya, Mehmet; Wan, Kai-tak; Nikkhah, Mehdi; Dokmeci, Mehmet R.; Tang, Xiaowu (Shirley); Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced Graphene Oxide-GelMA Hybrid Hydrogels as Scaffolds for Cardiac Tissue Engineering", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomaterials currently used in cardiac tissue engineering have certain limitations, such as lack of electrical conductivity and appropriate mechanical properties, which are two parameters playing a key role in regulating cardiac cell behavior. Here, the myocardial tissue constructs are engineered based on reduced graphene oxide (rGO)-incorporated gelatin methacryloyl (GelMA) hybrid hydrogels. The incorporation of rGO into the GelMA matrix significantly enhances the electrical conductivity and mechanical properties of the material. Moreover, cells cultured on composite rGO-GelMA scaffolds exhibit better biological activities such as cell viability, proliferation, and maturation compared to ones cultured on GelMA hydrogels. Cardiomyocytes show stronger contractility and faster spontaneous beating rate on rGO-GelMA hydrogel sheets compared to those on pristine GelMA hydrogels, as well as GO-GelMA hydrogel sheets with similar mechanical property and particle concentration. Our strategy of integrating rGO within a biocompatible hydrogel is expected to be broadly applicable for future biomaterial designs to improve tissue engineering outcomes. The engineered cardiac tissue constructs using rGO incorporated hybrid hydrogels can potentially provide high-fidelity tissue models for drug studies and the investigations of cardiac tissue development and/or disease processes in vitro.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2016, "Volume": 12, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3677, "End Page": 3689, "Article Number": null, "DOI": "10.1002/smll.201600178", "DOI Link": "http://dx.doi.org/10.1002/smll.201600178", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383374800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, BB; Pu, YC; Lindley, SA; Yang, Y; Lu, LQ; Li, Y; Li, XM; Zhang, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Binbin; Pu, Ying-Chih; Lindley, Sarah A.; Yang, Yi; Lu, Liqiang; Li, Yat; Li, Xueming; Zhang, Jin Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organolead Halide Perovskite nullocrystals: Branched Capping Ligands Control Crystal Size and Stability", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CH3NH3PbBr3 perovskite nullocrystals (PNCs) of different sizes (ca. 2.5-100 nm) with high photoluminescence (PL) quantum yield (QY; ca. 15-55%) and product yield have been synthesized using the branched molecules, APTES and NH2-POSS, as capping ligands. These ligands are sterically hindered, resulting in a uniform size of PNCs. The different capping effects resulting from branched versus straight-chain capping ligands were compared and a possible mechanism proposed to explain the dissolution-precipitation process, which affects the growth and aggregation of PNCs, and thereby their overall stability. Unlike conventional PNCs capped with straight-chain ligands, APTES-capped PNCs show high stability in protic solvents as a result of the strong steric hindrance and propensity for hydrolysis of APTES, which prevent such molecules from reaching and reacting with the core of PNCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2016, "Volume": 55, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8864, "End Page": 8868, "Article Number": null, "DOI": "10.1002/anie.201602236", "DOI Link": "http://dx.doi.org/10.1002/anie.201602236", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383253700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, H; Ran, Q; Dai, TY; Shi, H; Zeng, SP; Zhu, YF; Wen, Z; Zhang, W; Lang, XY; Zheng, WT; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Huan; Ran, Qing; Dai, Tian-Yi; Shi, Hang; Zeng, Shu-Pei; Zhu, Yong-Fu; Wen, Zi; Zhang, Wei; Lang, Xing-You; Zheng, Wei-Tao; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface-Alloyed nulloporous Zinc as Reversible and Stable Anodes for High-Performance Aqueous Zinc-Ion Battery", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic zinc (Zn) is one of the most attractive multivalent-metal anode materials in post-lithium batteries because of its high abundance, low cost and high theoretical capacity. However, it usually suffers from large voltage polarization, low Coulombic efficiency and high propensity for dendritic failure during Zn stripping/plating, hindering the practical application in aqueous rechargeable zinc-metal batteries (AR-ZMBs). Here we demonstrate that anionic surfactant-assisted in situ surface alloying of Cu and Zn remarkably improves Zn reversibility of 3D nulloporous Zn electrodes for potential use as high-performance AR-ZMB anode materials. As a result of the zincophilic ZnxCuy alloy shell guiding uniform Zn deposition with a zero nucleation overpotential and facilitating Zn stripping via the ZnxCuy/Zn galvanic couples, the self-supported nulloporous ZnxCuy/Zn electrodes exhibit superior dendrite-free Zn stripping/plating behaviors in ambient aqueous electrolyte, with ultralow polarizations under current densities up to 50 mA cm(-2), exceptional stability for 1900 h and high Zn utilization. This enables AR-ZMB full cells constructed with nulloporous ZnxCuy/Zn anode and KzMnO2 cathode to achieve specific energy of as high as similar to 430 Wh kg(-1) with similar to 99.8% Coulombic efficiency, and retain similar to 86% after long-term cycles for > 700 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 128, "DOI": "10.1007/s40820-022-00867-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00867-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000811219600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, G; Mandal, K; Haghniaz, R; Li, MC; Xiao, X; Carlson, L; Jucaud, V; Dokmeci, MR; Ho, GW; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Gang; Mandal, Kalpana; Haghniaz, Reihaneh; Li, Mengchen; Xiao, Xiao; Carlson, Larry; Jucaud, Vadim; Dokmeci, Mehmet Remzi; Ho, Ghim Wei; Khademhosseini, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Eutectic Solvents-Based Ionogels with Ultrafast Gelation and High Adhesion in Harsh Environments", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesive materials have recently drawn intensive attention due to their excellent sealing ability, stimulating advances in materials science and industrial usage. However, reported adhesives usually exhibit weak adhesion strength, require high pressure for strong bonding, and display severe adhesion deterioration in various harsh environments. In this study, instead of water or organic solvents, a deep eutectic solvent (DES) is used as the medium for the photopolymerization of zwitterionic and polarized monomers, thus generating a novel ionogel with tunable mechanical properties. Multiple hydrogen bonds and electrostatic interactions between DES and monomers facilitated ultrafast gelation and instant bonding without any external pressure, which has rarely been reported previously. Furthermore, high adhesion in different harsh environments (e.g., water, acidic and basic buffers, and saline solutions) and onto hydrophilic (e.g., glass and tissues) and hydrophobic (e.g., polymethyl methacrylate, polystyrene, and polypropylene) adherends is demonstrated. Also, the high stretchability of the ionogel at extreme temperatures (-80 and 80 degrees C) indicates its widespread applications. Furthermore, the biocompatible ionogel shows high burst pressure onto stomach and intestine tissues to prevent liquid leakage, highlighting its potential as an adhesive patch. This ionogel provides unprecedented opportunities in the packaging industry, marine engineering, medical adhesives, and electronic assembly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 33, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202207388", "DOI Link": "http://dx.doi.org/10.1002/adfm.202207388", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000934384600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Wang, JM; Liu, D; Yang, C; Liu, YC; Ruoff, RS; Lei, WW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Cheng; Wang, Jiemin; Liu, Dan; Yang, Chen; Liu, Yuchen; Ruoff, Rodney S.; Lei, Weiwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functionalized boron nitride membranes with ultrafast solvent transport performance for molecular separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure-driven, superfast organic solvent filtration membranes have significant practical applications. An excellent filtration membrane should exhibit high selectivity and permeation in aqueous and organic solvents to meet increasing industrial demand. Here, we report an amino functionalized boron nitride (FBN) based filtration membrane with a nullochannel network for molecular separation and permeation. This membrane is highly stable in water and in several organic solvents and shows high transport performance for solvents depending on the membranes' thickness. In addition, the FBN membrane is applicable for solute screening in water as well as in organic solvents. More importantly, the FBN membranes are very stable in acidic, alkaline and oxidative media for up to one month. The fast-flow rate and good separation performance of the FBN membranes can be attributed to their stable networks of nullochannels and thin laminar structure, which provide the membranes with beneficial properties for practical separation and purification processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902, "DOI": "10.1038/s41467-018-04294-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04294-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432115300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Wu, M; Li, HZ; Jiang, JL; Zhou, SS; Chen, WZ; Xie, C; Zhen, X; Jiang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xin; Wu, Min; Li, Haoze; Jiang, Jianli; Zhou, Sensen; Chen, Weizhi; Xie, Chen; Zhen, Xu; Jiang, Xiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing Penetration Ability of Semiconducting Polymer nulloparticles for Sonodynamic Therapy of Large Solid Tumor", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sonodynamic therapy (SDT) holds growing promise in deep-seated or large solid tumor treatment owing to its high tissue penetration depth ability; however, its therapeutic efficacy is often compromised due to the hypopermeable and hypoxic characteristics in the tumor milieu. Herein, a semiconducting polymer nulloparticle (SPNC) that synergistically enhances tumor penetration and alleviates tumor hypoxia is reported for sonodynamic therapy of large solid tumors. SPNC comprises a semiconducting polymer nulloparticle core as a sonodynamic converter coated with a poly (ethylene glycol) corona. An oxygen-modulating enzyme, catalase, is efficiently conjugated to the surface of nulloparticles via the coupling reaction. Superior to its counterpart SPNCs (SPNC2 (84 nm) and SPNC3 (134 nm)), SPNC with the smallest size (SPNC1 (35 nm)) can efficiently penetrate throughout the tumor interstitium to alleviate whole tumor hypoxia in a large solid tumor model. Upon ultrasound (US) irradiation, SPNC1 can remotely generate sufficient singlet oxygen to eradicate tumor cells at a deep-tissue depth. Such a single treatment of SPNC1-medicated sonodynamic therapy effectively inhibits tumor growth in a large solid tumor mouse model. Therefore, this study provides a generalized strategy to synergistically overcome both poor penetration and hypoxia of large tumors for enhanced cancer treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104125, "DOI": "10.1002/advs.202104125", "DOI Link": "http://dx.doi.org/10.1002/advs.202104125", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739322400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, B; Xing, T; Zhong, MZ; Huang, L; Lei, N; Zhang, J; Li, JB; Wei, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Bo; Xing, Tao; Zhong, Mianzeng; Huang, Le; Lei, Na; Zhang, Jun; Li, Jingbo; Wei, Zhongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A two-dimensional Fe-doped SnS2 magnetic semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic two-dimensional materials have attracted considerable attention for their significant potential application in spintronics. In this study, we present a high-quality Fe-doped SnS2 monolayer exfoliated using a micromechanical cleavage method. Fe atoms were doped at the Sn atom sites, and the Fe contents are similar to 2.1%, 1.5%, and 1.1%. The field-effect transistors based on the Fe0.021Sn0.979S2 monolayer show n-type behavior and exhibit high optoelectronic performance. Magnetic measurements show that pure SnS2 is diamagnetic, whereas Fe0.021Sn0.979S2 exhibits ferromagnetic behavior with a perpendicular anisotropy at 2 K and a Curie temperature of similar to 31 K. Density functional theory calculations show that long-range ferromagnetic ordering in the Fe-doped SnS2 monolayer is energetically stable, and the estimated Curie temperature agrees well with the results of our experiment. The results suggest that Fe-doped SnS2 has significant potential in future nulloelectronic, magnetic, and optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1958, "DOI": "10.1038/s41467-017-02077-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02077-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417055600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XQ; Yang, F; Xu, W; Zeng, YX; He, JJ; Lu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaoqing; Yang, Fan; Xu, Wei; Zeng, Yinxiang; He, Jinjun; Lu, Xihong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zeolitic Imidazolate Frameworks as Zn2+Modulation Layers to Enable Dendrite-Free Zn Anodes", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc (Zn) holds great promise as a desirable anode material for next-generation rechargeable batteries. However, the uncontrollable dendrite growth and low coulombic efficiency of the Zn plating/stripping process severely impede further practical applications of Zn-based batteries. Here, these roadblocks are removed by using in situ grown zeolitic imidazolate framework-8 (ZIF-8) as the ion modulation layer to tune the diffusion behavior of Zn(2+)ions on Zn anodes. The well-ordered nullochannels and N species of ZIF-8 can effectively homogenize Zn(2+)flux distribution and modulate the plating/stripping rate, ensuring uniform Zn deposition without dendrite growth. The Zn corrosion and hydrogen evolution are also alleviated by the insulating nature of ZIF-8, resulting in high coulombic efficiency. Therefore, the Zn@ZIF anode shows highly reversible, dendrite-free Zn plating/stripping behavior under a broad range of current densities, and a symmetric cell using this anode can work correctly up to 1200 h with a low polarization at 2 mA cm(-2). Moreover, this ultrastable Zn@ZIF anode also enables a full Zn ion battery with outstanding cyclic stability (10 000 cycles).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 7, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002173, "DOI": "10.1002/advs.202002173", "DOI Link": "http://dx.doi.org/10.1002/advs.202002173", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000557657800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alvarez, Z; Kolberg-Edelbrock, AN; Sasselli, IR; Ortega, JA; Qiu, R; Syrgiannis, Z; Mirau, PA; Chen, F; Chin, SM; Weigand, S; Kiskinis, E; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alvarez, Z.; Kolberg-Edelbrock, A. N.; Sasselli, I. R.; Ortega, J. A.; Qiu, R.; Syrgiannis, Z.; Mirau, P. A.; Chen, F.; Chin, S. M.; Weigand, S.; Kiskinis, E.; Stupp, S., I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioactive scaffolds with enhanced supramolecular motion promote recovery from spinal cord injury", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The signaling of cells by scaffolds of synthetic molecules that mimic proteins is known to be effective in the regeneration of tissues. Here, we describe peptide amphiphile supramolecular polymers containing two distinct signals and test them in a mouse model of severe spinal cord injury. One signal activates the transmembrane receptor b1-integrin and a second one activates the basic fibroblast growth factor 2 receptor. By mutating the peptide sequence of the amphiphilic monomers in nonbioactive domains, we intensified the motions of molecules within scaffold fibrils. This resulted in notable differences in vascular growth, axonal regeneration, myelination, survival of motor neurons, reduced gliosis, and functional recovery. We hypothesize that the signaling of cells by ensembles of molecules could be optimized by tuning their internal motions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2021, "Volume": 374, "Issue": 6569, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 848, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh3602", "DOI Link": "http://dx.doi.org/10.1126/science.abh3602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000717915400031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Atkinson, JT; Su, L; Zhang, X; Bennett, GN; Silberg, JJ; Ajo-Franklin, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Atkinson, Joshua T.; Su, Lin; Zhang, Xu; Bennett, George N.; Silberg, Jonathan J.; Ajo-Franklin, Caroline M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Real-time bioelectronic sensing of environmental contaminullts", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Real-time chemical sensing is crucial for applications in environmental and health monitoring(1). Biosensors can detect a variety of molecules through genetic circuits that use these chemicals to trigger the synthesis of a coloured protein, thereby producing an optical signal(2-4). However, the process of protein expression limits the speed of this sensing to approximately half an hour, and optical signals are often difficult to detect in situ(5-8). Here we combine synthetic biology and materials engineering to develop biosensors that produce electrical readouts and have detection times of minutes. We programmed Escherichia coli to produce an electrical current in response to specific chemicals using a modular, eight-component, synthetic electron transport chain. As designed, this strain produced current following exposure to thiosulfate, an anion that causes microbial blooms, within 2 min. This amperometric sensor was then modified to detect an endocrine disruptor. The incorporation of a protein switch into the synthetic pathway and encapsulation of the bacteria with conductive nullomaterials enabled the detection of the endocrine disruptor in urban waterway samples within 3 min. Our results provide design rules to sense various chemicals with mass-transport-limited detection times and a new platform for miniature, low-power bioelectronic sensors that safeguard ecological and human health.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2022, "Volume": 611, "Issue": 7936, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 548, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05356-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05356-y", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000878151700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, X; Gao, PY; Ren, XD; Zou, LF; Engelhard, MH; Matthews, BE; Hu, JT; Niu, CJ; Liu, DY; Arey, BW; Wang, CM; Xiao, J; Liu, J; Xu, W; Zhang, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Xia; Gao, Peiyuan; Ren, Xiaodi; Zou, Lianfeng; Engelhard, Mark H.; Matthews, Bethany E.; Hu, Jiangtao; Niu, Chaojiang; Liu, Dianying; Arey, Bruce W.; Wang, Chongmin; Xiao, Jie; Liu, Jun; Xu, Wu; Zhang, Ji-Guang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of fluorinated solvents on electrolyte solvation structures and electrode/electrolyte interphases for lithium metal batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte is very critical to the performance of the high-voltage lithium (Li) metal battery (LMB), which is one of the most attractive candidates for the next-generation high-density energy-storage systems. Electrolyte formulation and structure determine the physical properties of the electrolytes and their interfacial chemistries on the electrode surfaces. Localized high-concentration electrolytes (LHCEs) outperform state-of-the-art carbonate electrolytes in many aspects in LMBs due to their unique solvation structures. Types of fluorinated cosolvents used in LHCEs are investigated here in searching for the most suitable diluent for high-concentration electrolytes (HCEs). Nonsolvating solvents (including fluorinated ethers, fluorinated borate, and fluorinated orthoformate) added in HCEs enable the formation of LHCEs with high-concentration solvation structures. However, low-solvating fluorinated carbonate will coordinate with Li+ ions and form a second solvation shell or a pseudo-LHCE which diminishes the benefits of LHCE. In addition, it is evident that the diluent has significant influence on the electrode/electrolyte interphases (EEIs) beyond retaining the high-concentration solvation structures. Diluent molecules surrounding the high-concentration clusters could accelerate or decelerate the anion decomposition through coparticipation of diluent decomposition in the EEI formation. The varied interphase features lead to significantly different battery performance. This study points out the importance of diluents and their synergetic effects with the conductive salt and the solvating solvent in designing LHCEs. These systematic comparisons and fundamental insights into LHCEs using different types of fluorinated solvents can guide further development of advanced electrolytes for high-voltage LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2021, "Volume": 118, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2020357118", "DOI": "10.1073/pnas.2020357118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2020357118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625304300048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hui, Y; Yao, Y; Qian, QL; Luo, JH; Chen, HH; Qiao, Z; Yu, YT; Tao, L; Zhou, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hui, Yue; Yao, Yuan; Qian, Qilin; Luo, Jianhua; Chen, Hehao; Qiao, Zheng; Yu, Yetian; Tao, Liang; Zhou, nulljia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional printing of soft hydrogel electronics", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronics based on hydrogels can have inherent similarities to biological tissue and are of potential use in biomedical applications. Ideally, such hydrogel electronics should offer customizable three-dimensional circuits, but making complex three-dimensional circuits encapsulated within a hydrogel matrix is challenging with existing materials and manufacturing methods. Here we report the three-dimensional printing of hydrogel electronics using a curable hydrogel-based supporting matrix and a stretchable silver-hydrogel ink. The supporting matrix has a yield stress fluid behaviour, so the shear force generated by a moving printer nozzle creates a temporary fluid-like state, allowing the accurate placement in the matrix of silver-hydrogel ink circuits and electronic components. After printing, the entire matrix and embedded circuitry can be cured at 60 degrees C to form soft (Young's modulus of less than 5 kPa) and stretchable (elongation of around 18) monolithic hydrogel electronics, whereas the conductive ink exhibits a high conductivity of around 1.4 x 10(3) S cm(-1). We use our three-dimensional printing approach to create strain sensors, inductors and biological electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 DEC 19", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41928-022-00887-8", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00887-8", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000900800000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, L; Liu, C; Chen, XX; Zheng, L; Zou, Y; Wen, HQ; Guan, PF; Lu, F; Luo, YA; Tan, GX; Yu, P; Chen, DF; Deng, CL; Sun, YJ; Zhou, L; Ning, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Lei; Liu, Can; Chen, Xiuxing; Zheng, Lei; Zou, Yan; Wen, Huiquan; Guan, Pengfei; Lu, Fang; Luo, Yian; Tan, Guoxin; Yu, Peng; Chen, Dafu; Deng, Chunlin; Sun, Yongjian; Zhou, Lei; Ning, Chengyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exosomes-Loaded Electroconductive Hydrogel Synergistically Promotes Tissue Repair after Spinal Cord Injury via Immunoregulation and Enhancement of Myelinated Axon Growth", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroconductive hydrogels are very attractive candidates for accelerated spinal cord injury (SCI) repair because they match the electrical and mechanical properties of neural tissue. However, electroconductive hydrogel implantation can potentially aggravate inflammation, and hinder its repair efficacy. Bone marrow stem cell-derived exosomes (BMSC-exosomes) have shown immunomodulatory and tissue regeneration effects, therefore, neural tissue-like electroconductive hydrogels loaded with BMSC-exosomes are developed for the synergistic treatment of SCI. These exosomes-loaded electroconductive hydrogels modulate microglial M2 polarization via the NF-kappa B pathway, and synergistically enhance neuronal and oligodendrocyte differentiation of neural stem cells (NSCs) while inhibiting astrocyte differentiation, and also increase axon outgrowth via the PTEN/PI3K/AKT/mTOR pathway. Furthermore, exosomes combined electroconductive hydrogels significantly decrease the number of CD68-positive microglia, enhance local NSCs recruitment, and promote neuronal and axonal regeneration, resulting in significant functional recovery at the early stage in an SCI mouse model. Hence, the findings of this study demonstrate that the combination of electroconductive hydrogels and BMSC-exosomes is a promising therapeutic strategy for SCI repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105586, "DOI": "10.1002/advs.202105586", "DOI Link": "http://dx.doi.org/10.1002/advs.202105586", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765159600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bennett, TD; Coudert, FX; James, SL; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bennett, Thomas D.; Coudert, Francois-Xavier; James, Stuart L.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The changing state of porous materials", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous materials contain regions of empty space into which guest molecules can be selectively adsorbed and sometimes chemically transformed. This has made them useful in both industrial and domestic applications, ranging from gas separation, energy storage and ion exchange to heterogeneous catalysis and green chemistry. Porous materials are often ordered (crystalline) solids. Order-or uniformity-is frequently held to be advantageous, or even pivotal, to our ability to engineer useful properties in a rational way. Here we highlight the growing evidence that topological disorder can be useful in creating alternative properties in porous materials. In particular, we highlight here several concepts for the creation of novel porous liquids, rationalize routes to porous glasses and provide perspectives on applications for porous liquids and glasses. Highly ordered crystalline porous solids are useful for many applications. This Perspective explores the evolution of these systems from the ordered state to the glassy and liquid states, discusses the different types of porous liquid and considers possible applications of these disordered systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 20, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1179, "End Page": 1187, "Article Number": null, "DOI": "10.1038/s41563-021-00957-w", "DOI Link": "http://dx.doi.org/10.1038/s41563-021-00957-w", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640493800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, BJ; Zhang, L; Yang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Baojie; Zhang, Liang; Yang, Shuangqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymer composites with expanded graphite network with superior thermal conductivity and electromagnetic interference shielding performance", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer composites with high thermal conductivity and excellent electromagnetic interference (EMI) shielding are in high demand in modern microelectronic devices. However, for the most reported EMI shielding composites, high thermal conductivity is not easily achieved and the improvement efficiency is usually low due to the poor control over the heat transfer pathways. Herein, we developed a facile method to fabricate enhanced 3D expanded graphite (EG) network by pre-melt blending of EG with stearic acid and polyethylene wax, followed by powder mixing and thermal molding with linear low-density polyethylene (LLDPE) particles. It was found that micro gaps in EG were significantly reduced due to the introduction of small molecular compounds. The constructed continuous 3D networks and introduction of small molecular compounds in composite showed a much low interface thermal resistance and the thermal conductivity increased to ultrahigh levels which was greater than expected. The maximum thermal conductivity of composites increased from 8.6 Wm(-1) K-1 to 19.6 Wm(-1) K-1 with the presence of 24.89 vol% EG and the corresponding enhancement efficiency exceeded 5927% relative to neat LLDPE. The heat dissipation experiment revealed the high cooling efficiency of composite and the finite element simulation further visually confirmed the excellent heat-transfer capabilities. Moreover, the prepared composite exhibited excellent EMI shielding effectiveness (SE) of 52.4 dB and electrical conductivity up to 4000 Sm-1. This work provides a facile, low-cost, and scalable method to fabricate high thermal conductive and EMI shielding materials by building enhanced 3D filler networks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 404, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126437, "DOI": "10.1016/j.cej.2020.126437", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.126437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613197800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, S; Kondo, Y; Kakimoto, MA; Yang, B; Yamada, H; Kuwajima, I; Lambard, G; Hongo, K; Xu, YB; Shiomi, J; Schick, C; Morikawa, J; Yoshida, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Stephen; Kondo, Yukiko; Kakimoto, Masa-aki; Yang, Bin; Yamada, Hironao; Kuwajima, Isao; Lambard, Guillaume; Hongo, Kenta; Xu, Yibin; Shiomi, Junichiro; Schick, Christoph; Morikawa, Junko; Yoshida, Ryo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-learning-assisted discovery of polymers with high thermal conductivity using a molecular design algorithm", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of machine learning in computational molecular design has great potential to accelerate the discovery of innovative materials. However, its practical benefits still remain unproven in real-world applications, particularly in polymer science. We demonstrate the successful discovery of new polymers with high thermal conductivity, inspired by machine-learning-assisted polymer chemistry. This discovery was made by the interplay between machine intelligence trained on a substantially limited amount of polymeric properties data, expertise from laboratory synthesis and advanced technologies for thermophysical property measurements. Using a molecular design algorithm trained to recognize quantitative structure-property relationships with respect to thermal conductivity and other targeted polymeric properties, we identified thousands of promising hypothetical polymers. From these candidates, three were selected for monomer synthesis and polymerization because of their synthetic accessibility and their potential for ease of processing in further applications. The synthesized polymers reached thermal conductivities of 0.18-0.41 W/mK, which are comparable to those of state-of-the-art polymers in non-composite thermo-plastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2019, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5, "DOI": "10.1038/s41524-019-0203-2", "DOI Link": "http://dx.doi.org/10.1038/s41524-019-0203-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472645100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arrigo, R; Schuster, ME; Xie, ZL; Yi, YM; Wowsnick, G; Sun, LL; Hermann, KE; Friedrich, M; Kast, P; Hävecker, M; Knop-Gericke, A; Schlögl, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arrigo, Rosa; Schuster, Manfred E.; Xie, Zailai; Yi, Youngmi; Wowsnick, Gregor; Sun, Li L.; Hermann, Klaus E.; Friedrich, Matthias; Kast, Patrick; Haevecker, Michael; Knop-Gericke, Axel; Schloegl, Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of the N-Pd Interaction in Nitrogen-Doped Carbon nullotube Catalysts", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, the geometric and electronic structure of N species in N-doped carbon nullotubes (NCNTs) is derived by X-ray photoemission (XPS) and absorption spectroscopy (NEXAFS) of the N Is core excitation. Substitutional N species in pyridine-like configuration and another form of N with higher thermal stability are found in NCNTs. The structural configuration of the high thermally stable N species, in the literature often referred to as graphitic N, is assessed in this work by a combined theoretical and experimental study as a 3-fold substitutional N species in an NCNT basic structural unit (BSU). Furthermore, the nature of the interaction of those N species with a Pd metal center immobilized onto NCNTs is of sigma-type donation from the filled pi-orbital of the N atom to the empty d-orbital of the Pd atom and a pi back-donation from the filled Pd atomic d-orbital to the pi* antibonding orbital of the N atom. We have found that the interaction of pyridine N with Pd is characterized by a charge transfer typical of a covalent chemical bond with partial ionic character, consistent with the chemical shift observed in the Pd 3d core level of divalent Pd. Graphitic N sites interact with Pd by a covalent bond without any charge redistribution. In this case, the electronic state of the Pd corresponds to metallic Pd nulloparticles electronically modified by the interaction with the support. The catalytic reactivity of these samples in hydrogenation, CO oxidation, and oxygen reduction reaction (ORR) allowed clarifying some aspects of the metal carbon support interaction in catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2740, "End Page": 2753, "Article Number": null, "DOI": "10.1021/acscatal.5b00094", "DOI Link": "http://dx.doi.org/10.1021/acscatal.5b00094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354012200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HX; Zhang, CY; Xiang, WJ; Amin, MA; Na, J; Wang, SP; Yu, JX; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Huixi; Zhang, Chenyang; Xiang, Weijun; Amin, Mohammed A.; Na, Jongbeom; Wang, Shengping; Yu, Jingxian; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient electrocatalysis for oxygen evolution: W-doped NiFe nullosheets with oxygen vacancies constructed by facile electrodeposition and corrosion", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting requires efficient electrocatalysts to accelerate the sluggish kinetics of the oxygen evolution reaction (OER). A promising nulloporous W-doped oxygen vacancy-containing NiFe layered double hydroxides (NiFeW-LDHs) electrocatalyst is directly grown on nickel foam via electrodeposition combined with chemical corrosion. With an appropriate amount of W dopant in NiFe-LDHs, the electronic structures of Ni and Fe are modulated by the changes in local environment, and the oxygen vacancy concentration is further optimized, resulting in abundant OER electrocatalytic active centers on the electrocatalyst surface. Due to the excellent electronic conductivity and three-dimensional nulloporous configuration, the representative NiFeW3-LDHs exhibit remarkable OER electrocatalytic activity with a low overpotential (211 mV at 10 mA cm-2), a small Tafel slope (36.44 mV dec-1), and fine stability (more than 120 h at 10 mA cm-2). The oxygen vacancy effectively modifies the intrinsic electronic structure of NiFe-LDHs, optimizes the adsorption energy of intermediates, and accelerates the OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2023, "Volume": 452, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 139104, "DOI": "10.1016/j.cej.2022.139104", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.139104", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863120600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, Y; Lau, SY; Lim, ZW; Chang, SC; Ghadessy, F; Partridge, A; Miserez, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yue; Lau, Sze Yi; Lim, Zhi Wei; Chang, Shi Chieh; Ghadessy, Farid; Partridge, Anthony; Miserez, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-separating peptides for direct cytosolic delivery and redox-activated release of macromolecular therapeutics", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomacromolecules are highly promising therapeutic modalities to treat various diseases. However, they suffer from poor cellular membrane permeability, limiting their access to intracellular targets. Strategies to overcome this challenge often employ nulloscale carriers that can get trapped in endosomal compartments. Here we report conjugated peptides that form pH- and redox-responsive coacervate microdroplets by liquid-liquid phase separation that readily cross the cell membrane. A wide range of macromolecules can be quickly recruited within the microdroplets, including small peptides, enzymes as large as 430 kDa and messenger RNAs (mRNAs). The therapeutic-loaded coacervates bypass classical endocytic pathways to enter the cytosol, where they undergo glutathione-mediated release of payload, the bioactivity of which is retained in the cell, while mRNAs exhibit a high transfection efficiency. These peptide coacervates represent a promising platform for the intracellular delivery of a large palette of macromolecular therapeutics that have potential for treating various pathologies (for example, cancers and metabolic diseases) or as carriers for mRNA-based vaccines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 274, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-021-00854-4", "DOI Link": "http://dx.doi.org/10.1038/s41557-021-00854-4", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750705200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XC; Shi, YA; Xu, J; Ouyang, QY; Zhang, X; Zhu, CL; Zhang, XL; Chen, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xinci; Shi, Yanull; Xu, Jia; Ouyang, Qiuyun; Zhang, Xiao; Zhu, Chunling; Zhang, Xiaoli; Chen, Yujin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of the Intrinsic Dielectric Properties of Metal Single Atoms for Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed metals on N-doped carbon supports (M-NxCs) have great potential applications in various fields. However, a precise understanding of the definitive relationship between the configuration of metal single atoms and the dielectric loss properties of M-NxCs at the atomic-level is still lacking. Herein, we report a general approach to synthesize a series of three-dimensional (3D) honeycomb-like M-NxC (M=Mn, Fe, Co, Cu, or Ni) containing metal single atoms. Experimental results indicate that 3D M-NxCs exhibit a greatly enhanced dielectric loss compared with that of the NC matrix. Theoretical calculations demonstrate that the density of states of the d orbitals near the Fermi level is significantly increased and additional electrical dipoles are induced due to the destruction of the symmetry of the local microstructure, which enhances conductive loss and dipolar polarization loss of 3D M-NxCs, respectively. Consequently, these 3D M-NxCs exhibit excellent electromagnetic wave absorption properties, outperforming the most commonly reported absorbers. This study systematically explains the mechanism of dielectric loss at the atomic level for the first time and is of significance to the rational design of high-efficiency electromagnetic wave absorbing materials containing metal single atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27, "DOI": "10.1007/s40820-021-00773-6", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00773-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000729226800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baker, BM; Trappmann, B; Wang, WY; Sakar, MS; Kim, IL; Shenoy, VB; Burdick, JA; Chen, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baker, Brendon M.; Trappmann, Britta; Wang, William Y.; Sakar, Mahmut S.; Kim, Iris L.; Shenoy, Vivek B.; Burdick, Jason A.; Chen, Christopher S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cell-mediated fibre recruitment drives extracellular matrix mechanosensing in engineered fibrillar microenvironments", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To investigate how cells sense stiffness in settings structurally similar to native extracellular matrices, we designed a synthetic fibrous material with tunable mechanics and user-defined architecture. In contrast to flat hydrogel surfaces, these fibrous materials recapitulated cell-matrix interactions observed with collagen matrices including stellate cell morphologies, cell-mediated realignment of fibres, and bulk contraction of the material. Increasing the stiffness of flat hydrogel surfaces induced mesenchymal stem cell spreading and proliferation; however, increasing fibre stiffness instead suppressed spreading and proliferation for certain network architectures. Lower fibre stiffness permitted active cellular forces to recruit nearby fibres, dynamically increasing ligand density at the cell surface and promoting the formation of focal adhesions and related signalling. These studies demonstrate a departure from the well-described relationship between material stiffness and spreading established with hydrogel surfaces, and introduce fibre recruitment as a previously undescribed mechanism by which cells probe and respond to mechanics in fibrillar matrices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 523, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 14, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1262, "End Page": 1268, "Article Number": null, "DOI": "10.1038/NMAT4444", "DOI Link": "http://dx.doi.org/10.1038/NMAT4444", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365839000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, C; Tan, XP; Tor, SB; Lim, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, C.; Tan, X. P.; Tor, S. B.; Lim, C. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning in additive manufacturing: State-of-the-art and perspectives", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) has emerged as a disruptive digital manufacturing technology. However, its broad adoption in industry is still hindered by high entry barriers of design for additive manufacturing (DfAM), limited materials library, various processing defects, and inconsistent product quality. In recent years, machine learning (ML) has gained increasing attention in AM due to its unprecedented performance in data tasks such as classification, regression and clustering. This article provides a comprehensive review on the state-of-the-art of ML applications in a variety of AM domains. In the DfAM, ML can be leveraged to output new high-performance metamaterials and optimized topological designs. In AM processing, contemporary ML algorithms can help to optimize process parameters, and conduct examination of powder spreading and in-process defect monitoring. On the production of AM, ML is able to assist practitioners in pre-manufacturing planning, and product quality assessment and control. Moreover, there has been an increasing concern about data security in AM as data breaches could occur with the aid of ML techniques. Lastly, it concludes with a section summarizing the main findings from the literature and providing perspectives on some selected interesting applications of ML in research and development of AM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 36, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101538, "DOI": "10.1016/j.addma.2020.101538", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2020.101538", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600807800122", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cong, DY; Xiong, WX; Planes, A; Ren, Y; Mañosa, L; Cao, PY; Nie, ZH; Sun, XM; Yang, Z; Hong, XF; Wang, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cong, Daoyong; Xiong, Wenxin; Planes, Antoni; Ren, Yang; Manosa, Lluis; Cao, Peiyu; Nie, Zhihua; Sun, Xiaoming; Yang, Zhi; Hong, Xiufeng; Wang, Yandong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colossal Elastocaloric Effect in Ferroelastic Ni-Mn-Ti Alloys", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy-efficient and environment-friendly elastocaloric refrigeration, which is a promising replacement of the conventional vapor-compression refrigeration, requires extraordinary elastocaloric properties. Hitherto the largest elastocaloric effect is obtained in small-size films and wires of the prototype NiTi system. Here, we report a colossal elastocaloric effect, well exceeding that of NiTi alloys, in a class of bulk polycrystalline NiMn-based materials designed with the criterion of simultaneously having large volume change across phase transition and good mechanical properties. The reversible adiabatic temperature change reaches a strikingly high value of 31.5 K and the isothermal entropy change is as large as 45 J kg(-1) K-1. The achievement of such a colossal elastocaloric effect in bulk polycrystalline materials should push a significant step forward towards large-scale elastocaloric refrigeration applications. Moreover, our design strategy may inspire the discovery of giant caloric effects in a broad range of ferroelastic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2019, "Volume": 122, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 255703, "DOI": "10.1103/PhysRevLett.122.255703", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.255703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473035400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZL; Cai, XL; Yi, SH; Chen, JL; Dai, YW; Niu, CY; Guo, ZX; Xie, MH; Liu, F; Cho, JH; Jia, Y; Zhang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zhili; Cai, Xiaolin; Yi, Seho; Chen, Jinglei; Dai, Yawei; Niu, Chunyao; Guo, Zhengxiao; Xie, Maohai; Liu, Feng; Cho, Jun-Hyung; Jia, Yu; Zhang, Zhenyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multivalency-Driven Formation of Te-Based Monolayer Materials: A Combined First-Principles and Experimental study", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Contemporary science is witnessing a rapid expansion of the two-dimensional (2D) materials family, each member possessing intriguing emergent properties of fundamental and practical importance. Using the particle-swarm optimization method in combination with first-principles density functional theory calculations, here we predict a new category of 2D monolayers named tellurene, composed of the metalloid element Te, with stable 1T-MoS2-like (alpha-Te), and metastable tetragonal (beta-Te) and 2H-MoS2-like (gamma-Te) structures. The underlying formation mechanism is inherently rooted in the multivalent nature of Te, with the central-layer Te behaving more metal-like (e.g., Mo), and the two outer layers more semiconductorlike (e.g., S). We also show that the alpha-Te phase can be spontaneously obtained from the magic thicknesses divisible by three layers truncated along the [ 001] direction of the trigonal structure of bulk Te, and both the alpha- and alpha-Te phases possess electron and hole mobilities much higher than MoS2. Furthermore, we present preliminary but convincing experimental evidence for the layering behavior of Te on HOPG substrates, and predict the importance of multivalency in the layering behavior of Se. These findings effectively extend the realm of 2D materials to group-VI elements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2017, "Volume": 119, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106101, "DOI": "10.1103/PhysRevLett.119.106101", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.106101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409265000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Florindo, C; Romero, L; Rintoul, I; Branco, LC; Marrucho, IM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Florindo, Catarina; Romero, Leila; Rintoul, Ignacio; Branco, Luis C.; Marrucho, Isabel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From Phase Change Materials to Green Solvents: Hydrophobic Low Viscous Fatty Acid Based Deep Eutectic Solvents", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the use of fatty acids in development of low temperature latent heat storage materials, novel low viscous and hydrophobic deep eutectic solvents (DESs) based exclusively on fatty acids are herein proposed as sustainable solvents. Three DESs were prepared by exclusively combining fatty acids, namely octanoic acid (C-8) nonulloic acid (C-9), decanoic acid (C-10), and dodecanoic acid (C-12), which can simultaneously act as hydrogen bond donors and acceptors. The obtained fatty acid-based DESs were analyzed in order to check their structures, purities, and proportions. Water stability was also carefully evaluated through H-1 NMR Fatty-acid DESs melting point diagrams were determined by visual observation. Good agreement was obtained between the experimental eutectic point and that predicted by considering an ideal system of two individually melting compounds. Important solvent thermophysical properties, such as density and viscosity of the dried and water-saturated DESs, were measured. Finally, the removal of bisphenol A, a persistent micropollutant present in aqueous environments illustrates the potential of binary and ternary fatty acid-based DESs as extraction solvents. All prepared DESs showed good ability to extract bisphenol A from water with extraction efficiencies up to 92%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3888, "End Page": 3895, "Article Number": null, "DOI": "10.1021/acssuschemeng.7b04235", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.7b04235", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427092900117", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, C; Mak, C; Tao, XM; Yan, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Chao; Mak, Chunhin; Tao, Xiaoming; Yan, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photodetectors Based on Two-Dimensional Layered Materials Beyond Graphene", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Following a significant number of graphene studies, other two-dimensional (2D) layered materials have attracted more and more interest for their unique structures and distinct physical properties, which has opened a window for realizing novel electronic or optoelectronic devices. Here, we present a comprehensive review on the applications of 2D-layered semiconductors as photodetectors, including photoconductors, phototransistors, and photodiodes, reported in the past five years. The device designs, mechanisms, and performances of the photodetectors are introduced and discussed systematically. Emerging techniques to improve device performances by enhancing light-matter interactions are addressed as well. Finally, we deliver a summary and outlook to provide a guideline of the future development of this rapidly growing field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 569, "Times Cited, All Databases": 592, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2017, "Volume": 27, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1603886, "DOI": "10.1002/adfm.201603886", "DOI Link": "http://dx.doi.org/10.1002/adfm.201603886", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401319100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharafi, A; Meyer, HM; nullda, J; Wolfenstine, J; Sakamoto, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharafi, Asma; Meyer, Harry M.; nullda, Jagjit; Wolfenstine, Jeff; Sakamoto, Jeff", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterizing the Li-Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stability and kinetics of the Li-Li7La3Zr2O12 (LLZO) interface were characterized as a function of temperature and current density. Polycrystalline LLZO was densified using a rapid hot-pressing technique achieving 97.1 +/- 1% relative density, and <10% grain boundary resistance; effectively consisting of an ensemble of single LLZO crystals. It was determined that by heating to 175 degrees C, the room temperature Li-LIZO interface resistance decreases dramatically from 5822 (as-assembled) to 514 0 cm2; a > 10-fold decrease. In characterizing the maximum sustainable current density (or critical current density - CCD) of the Li-LLZO interface, several signs of degradation were observed. In DC cycling tests, significant deviation from Ohmic behavior was observed. In post-cycling tests, regions of metallic Li were observed; propagating parallel to the ionic current. For the cells cycled at 30, 70, 100, 130 and 160 degrees C, the CCD was determined to be 50, 200, 800, 3500, and 20000 mu A cm(-2), respectively. The relationships and phenomena observed in this work can be used to better understand the Li-LLZO interface stability, enabling the use of batteries employing Li metal anodes. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 551, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2016, "Volume": 302, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 135, "End Page": 139, "Article Number": null, "DOI": "10.1016/j.jpowsour.2015.10.053", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2015.10.053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366068800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JY; Chen, RM; Wang, JL; Zhou, Y; Yang, GD; Dong, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jieyuan; Chen, Ruimin; Wang, Jielin; Zhou, Ying; Yang, Guidong; Dong, Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subnullometric alkaline-earth oxide clusters for sustainable nitrate to ammonia photosynthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reduction of waste nitrate offers an alternative route for ammonia production. Here the authors report BaO clusters on TiO2 for nitrate-ammonia photosynthesis with high ammonia yield. The limitation of inert N-2 molecules with their high dissociation energy has ignited research interests in probing other nitrogen-containing species for ammonia synthesis. Nitrate ions, as an alternative feedstock with high solubility and proton affinity, can be facilely dissociated for sustainable ammonia production. Here we report a nitrate to ammonia photosynthesis route (NO3-RR) catalyzed by subnullometric alkaline-earth oxide clusters. The catalyst exhibits a high ammonia photosynthesis rate of 11.97 mol g(metal)(-1) h(-1) (89.79 mmol g(cat)(-1) h(-1)) with nearly 100% selectivity. A total ammonia yield of 0.78 mmol within 72 h is achieved, which exhibits a significant advantage in the area of photocatalytic NO3-RR. The investigation of the molecular-level reaction mechanism reveals that the unique active interface between the subnullometric clusters and TiO2 substrate is beneficial for the nitrate activation and dissociation, contributing to efficient and selective nitrate reduction for ammonia production with low energy input. The practical application of NO3-RR route in simulated wastewater is developed, which demonstrates great potential for its industrial application. These findings are of general knowledge for the functional development of clusters-based catalysts and could open up a path in the exploitation of advanced ammonia synthesis routes with low energy consumption and carbon emission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1098, "DOI": "10.1038/s41467-022-28740-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28740-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771136200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, CL; Liang, FC; Veeramuthu, L; Cho, CJ; Benas, JS; Tzeng, YR; Tseng, YL; Chen, WC; Rwei, A; Kuo, CC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Cyuan-Lun; Liang, Fang-Cheng; Veeramuthu, Loganathan; Cho, Chia-Jung; Benas, Jean-Sebastien; Tzeng, Yung-Ru; Tseng, Yen-Lin; Chen, Wei-Cheng; Rwei, Alina; Kuo, Chi-Ching", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Super Tough and Spontaneous Water-Assisted Autonomous Self-Healing Elastomer for Underwater Wearable Electronics", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing soft electronic material composition is crucial to sustain the device long-term durability. The fabrication of self-healing soft electronics exposed to high moisture environment is a significant challenge that has yet to be fully achieved. This paper presents the novel concept of a water-assisted room-temperature autonomous self-healing mechanism based on synergistically dynamic covalent Schiff-based imine bonds with hydrogen bonds. The supramolecular water-assisted self-healing polymer (WASHP) films possess rapid self-healing kinetic behavior and high stretchability due to a reversible dissociation-association process. In comparison with the pristine room-temperature self-healing polymer, the WASHP demonstrates favorable mechanical performance at room temperature and a short self-healing time of 1 h; furthermore, it achieves a tensile strain of 9050%, self-healing efficiency of 95%, and toughness of 144.2 MJ m(-3). As a proof of concept, a versatile WASHP-based light-emitting touch-responsive device (WASHP-LETD) and perovskite quantum dot (PeQD)-based white LED backlight are designed. The WASHP-LETD has favorable mechanical deformation performance under pressure, bending, and strain, whereas the WASHP-PeQDs exhibit outstanding long-term stability even over a period exceeding one year in a boiling water environment. This paper provides a mechanically robust approach for producing eco-friendly, economical, and waterproof e-skin device components.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 8, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102275, "DOI": "10.1002/advs.202102275", "DOI Link": "http://dx.doi.org/10.1002/advs.202102275", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000695515200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mi, RY; Chen, CJ; Keplinger, T; Pei, Y; He, SM; Liu, DP; Li, JG; Dai, JQ; Hitz, E; Yang, B; Burgert, I; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mi, Ruiyu; Chen, Chaoji; Keplinger, Tobias; Pei, Yong; He, Shuaiming; Liu, Dapeng; Li, Jianguo; Dai, Jiaqi; Hitz, Emily; Yang, Bao; Burgert, Ingo; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable aesthetic transparent wood for energy efficient buildings", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nowadays, energy-saving building materials are important for reducing indoor energy consumption by enabling better thermal insulation, promoting effective sunlight harvesting and offering comfortable indoor lighting. Here, we demonstrate a novel scalable aesthetic transparent wood (called aesthetic wood hereafter) with combined aesthetic features (e.g. intact wood patterns), excellent optical properties (an average transmittance of similar to 80% and a haze of similar to 93%), good UV-blocking ability, and low thermal conductivity (0.24Wm(-1)K(-1)) based on a process of spatially selective delignification and epoxy infiltration. Moreover, the rapid fabrication process and mechanical robustness (a high longitudinal tensile strength of 91.95MPa and toughness of 2.73 MJ m(-3)) of the aesthetic wood facilitate good scale-up capability (320mm x 170mm x 0.6mm) while saving large amounts of time and energy. The aesthetic wood holds great potential in energy-efficient building applications, such as glass ceilings, rooftops, transparent decorations, and indoor panels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3836, "DOI": "10.1038/s41467-020-17513-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17513-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560366500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, ZY; Chen, JJ; Xu, T; Fang, XM; Gao, XN; Zhang, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Ziye; Chen, Jiajie; Xu, Tao; Fang, Xiaoming; Gao, Xuenong; Zhang, Zhengguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal conductivity of an organic phase change material/expanded graphite composite across the phase change temperature range and a novel thermal conductivity model", "Source Title": "ENERGY CONVERSION AND MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work studies factors that affect the thermal conductivity of an organic phase change material (PCM), RT44HC/expanded graphite (EG) composite, which include: EG mass fraction, composite PCM density and temperature. The increase of EG mass fraction and bulk density will both enhance thermal conductivity of composite PCMs, by up to 60 times. Thermal conductivity of RT44HC/EG composites remains independent on temperature outside the phase change range (40-45 degrees C), but nearly doubles during the phase change. The narrow temperature change during the phase change allows the maximum heat flux or minimum temperature for heat source if attaching PCMs to a first (constant temperature) or second (constant heat flux) thermal boundary. At last, a simple thermal conductivity model for EG-based composites is put forward, based on only two parameters: mass fraction of EG and bulk density of the composite. This model is validated with experiment data presented in this paper and in literature, showing this model has general applicability to any composite of EG and poor thermal conductive materials. (c) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2015, "Volume": 102, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 202, "End Page": 208, "Article Number": null, "DOI": "10.1016/j.enconman.2014.11.040", "DOI Link": "http://dx.doi.org/10.1016/j.enconman.2014.11.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358809400021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Z; Zhang, YY; Song, NN; Li, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Zan; Zhang, Yunya; Song, Ningning; Li, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-derived renewable carbon materials for electrochemical energy storage", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical energy storage devices, such as supercapacitors and batteries, have been proven to be the most effective energy conversion and storage technologies for practical application. However, further development of these energy storage devices is hindered by their poor electrode performance. Carbon materials used in supercapacitors and batteries are often derived from nonrenewable resources under harsh environments. Naturally abundant biomass is a green, alternative carbon source with many desired properties. This review article presents state of the art of renewable carbon materials derived from natural biomasses with an emphasis on their applications in supercapacitors and lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 69, "End Page": 88, "Article Number": null, "DOI": "10.1080/21663831.2016.1250834", "DOI Link": "http://dx.doi.org/10.1080/21663831.2016.1250834", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398625900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Baker, I; Cai, Z; Chen, S; Poplawsky, JD; Guo, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhangwei; Baker, Ian; Cai, Zhonghou; Chen, Si; Poplawsky, Jonathan D.; Guo, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The effect of interstitial carbon on the mechanical properties and dislocation substructure evolution in Fe40.4Ni11.3Mn34.8Al7.5Cr6 high entropy alloys", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A systematic study of the effects of up to 1.1 at. % carbon on the mechanical properties and evolution of the dislocation substructure in a series of a high entropy alloys (HEA) based on Fe40.4Ni11.3Mn34.8Al7.5Cr6 is presented. Transmission electron microscopy (TEM), synchrotron X-ray diffraction (XRD) and atom probe tomography (APT) were used to show that all the alloys are single-phase f.c.c. random solid solutions. The lattice constant, determined from synchrotron XRD measurements, increases linearly with increasing carbon concentration, which leads to a linear relationship between the yield strength and the carbon concentration. The dislocation substructures, as determined by a TEM, show a transition from wavy slip to planar slip and, at higher strains, and from cell-forming structure (dislocations cells, cell blocks and dense dislocation walls) to non-cell forming structure (Taylor lattice, microbands and domain boundaries) with the addition of carbon, features related to the increase in lattice friction stress. The stacking fault energy (measured via weak-beam imaging of the separation of dislocation partials) decreases with increasing carbon content, which also contributes to the transition from wavy slip to planar slip. The formation of non-cell forming structure induced by carbon leads to a high degree of strain hardening and a substantial increase in the ultimate tensile strength. The consequent postponement of necking due to the high strain hardening, along with the plasticity accommodation arising from the formation of microbands and domain boundaries, result in an increase of ductility due to the carbon addition. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 120, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": 239, "Article Number": null, "DOI": "10.1016/j.actamat.2016.08.072", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.08.072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385327200023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LL; Huang, KW; Chen, JT; Zheng, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lulu; Huang, Kuo-Wei; Chen, Jitao; Zheng, Junrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong cycle stability of aqueous zinc-ion batteries with zinc vanadium oxide cathodes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries are promising candidates for large-scale energy storage but are plagued by the lack of cathode materials with both excellent rate capability and adequate cycle life span. We overcome this barrier by designing a novel hierarchically porous structure of Zn-vanadium oxide material. This Zn0.3V2O5 center dot 1.5H(2)O cathode delivers a high specific capacity of 426 mA.h g(-1) at 0.2 A g(-1) and exhibits an unprecedented superlong-term cyclic stability with a capacity retention of 96% over 20,000 cycles at 10 A g(-1). Its electrochemical mechanism is elucidated. The lattice contraction induced by zinc intercalation and the expansion caused by hydronium intercalation cancel each other and allow the lattice to remain constant during charge/discharge, favoring cyclic stability. The hierarchically porous structure provides abundant contact with electrolyte, shortens ion diffusion path, and provides cushion for relieving strain generated during electrochemical processes, facilitating both fast kinetics and long-term stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 513, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax4279", "DOI": "10.1126/sciadv.aax4279", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax4279", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491132700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, D; Huang, D; Wang, HY; Xu, GL; Zhang, XY; Zhang, R; Tang, YG; Abd Ei-Hady, D; Alshitari, W; AL-Bogami, AS; Amine, K; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Dan; Huang, Dan; Wang, Haiyan; Xu, Gui-Liang; Zhang, Xiaoyi; Zhang, Rui; Tang, Yougen; Abd Ei-Hady, Deia; Alshitari, Wael; AL-Bogami, Abdullah Saad; Amine, Khalil; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "1T MoS2 nullosheets with extraordinary sodium storage properties via thermal-driven ion intercalation assisted exfoliation of bulky MoS2", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic phase (1T) MoS2 has attracted enormous attention as an appealing energy storage material for batteries, supercapacitors, and catalysts. However, a facile fabrication method is lacking and the intensive understanding of its sodium storage mechanism is absent. Herein, ultrathin 1T MoS2 nullosheets (1-2 layers) are directly fabricated via and are investigated as an anode material for sodium-ion batteries. Interestingly, the as-prepared 1T MoS2 nullosheets demonstrate a high reversible capacity of 450 mAh g(-1) at 50 mA g(-1) and outstanding cycling stability with a high capacity retention ratio of 94% after 200 cycles at 1 A g(-1), which is far superior to that of the 2H phase counterpart. Density function theory (DFT) calculations show that, in addition to significantly enhanced electronic conductivity, 1T MoS2 also possesses much more sodium philicity and faster Na atom mobility in comparison with the 2H phase. More importantly, as revealed by ex-situ Raman, in-situ X-ray diffraction, and DFT calculations, the 1T MoS2 is more capable of suppressing the dissolution of S species from the material structure compared with the 2H phase, leading to excellent cycling stability. The facile and easily scalable method as well as the deep mechanism analysis will provide a very important reference for the development of high-performance MoS2 anodes and other SIB electrode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 61, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 361, "End Page": 369, "Article Number": null, "DOI": "10.1016/j.nulloen.2019.04.063", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2019.04.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471201800043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, HT; Xin, GQ; Hu, T; Yu, MP; Shao, DL; Sun, X; Lian, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Hongtao; Xin, Guoqing; Hu, Tao; Yu, Mingpeng; Shao, Dali; Sun, Xiang; Lian, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-rate lithiation-induced reactivation of mesoporous hollow spheres for long-lived lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanical and chemical degradations of high-capacity anodes, resulting from lithiation-induced stress accumulation, volume expansion and pulverization, and unstable solid-electrolyte interface formation, represent major mechanisms of capacity fading, limiting the lifetime of electrodes for lithium-ion batteries. Here we report that the mechanical degradation on cycling can be deliberately controlled to finely tune mesoporous structure of the metal oxide sphere and optimize stable solid-electrolyte interface by high-rate lithiation-induced reactivation. The reactivated Co3O4 hollow sphere exhibits a reversible capacity above its theoretical value (924mAhg(-1) at 1.12 C), enhanced rate performance and a cycling stability without capacity fading after 7,000 cycles at a high rate of 5.62 C. In contrast to the conventional approach of mitigating mechanical degradation and capacity fading of anodes using nullostructured materials, high-rate lithiation-induced reactivation offers a new perspective in designing high-performance electrodes for long-lived lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 610, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4526, "DOI": "10.1038/ncomms5526", "DOI Link": "http://dx.doi.org/10.1038/ncomms5526", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340625400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, BY; Wang, X; Zhang, YJ; Xu, LC; Wang, TS; Xiao, X; Wang, SC; Wang, LZ; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Boyan; Wang, Xin; Zhang, Yingjuan; Xu, Liangcheng; Wang, Tingsheng; Xiao, Xiong; Wang, Songcan; Wang, Lianzhou; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A BiVO4 Photoanode with a VOx Layer Bearing Oxygen Vacancies Offers Improved Charge Transfer and Oxygen Evolution Kinetics in Photoelectrochemical Water Splitting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sluggish oxygen evolution kinetics are one of the key limitations of bismuth vanadate (BiVO4) photoanodes for efficient photoelectrochemical (PEC) water splitting. To address this issue, we report a vanadium oxide (VOx) with enriched oxygen vacancies conformally grown on BiVO4 photoanodes by a simple photo-assisted electrodeposition process. The optimized BiVO4/VOx photoanode exhibits a photocurrent density of 6.29 mA cm(-2) at 1.23 V versus the reversible hydrogen electrode under AM 1.5 G illumination, which is ca. 385 % as high as that of its pristine counterpart. A high charge-transfer efficiency of 96 % is achieved and stable PEC water splitting is realized, with a photocurrent retention rate of 88.3 % upon 40 h of testing. The excellent PEC performance is attributed to the presence of oxygen vacancies in VOx that forms undercoordinated sites, which strengthen the adsorption of water molecules onto the active sites and promote charge transfer during the oxygen evolution reaction. This work demonstrates the potential of vanadium-based catalysts for PEC water oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 62, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202217346", "DOI": "10.1002/anie.202217346", "DOI Link": "http://dx.doi.org/10.1002/anie.202217346", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922341300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gaberscek, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gaberscek, Miran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Li-based battery materials via electrochemical impedance spectroscopy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical impedance spectroscopy is a key technique for understanding Li-based battery processes. Here, the authors discuss the current state of the art, advantages and challenges of this technique, also giving an outlook for future developments. Lithium-based batteries are a class of electrochemical energy storage devices where the potentiality of electrochemical impedance spectroscopy (EIS) for understanding the battery charge storage mechanisms is still to be fully exploited. Generally considered as an ancillary technique, the application of EIS should be promoted focusing on improved experimental design of experiments and advanced data analysis using physics-based models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6513, "DOI": "10.1038/s41467-021-26894-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26894-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000717958200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YH; Akin, S; Pan, LF; Uchida, R; Arora, N; Milic, JV; Hinderhofer, A; Schreiber, F; Uhl, AR; Zakeeruddin, SM; Hagfeldt, A; Dar, MI; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuhang; Akin, Seckin; Pan, Linfeng; Uchida, Ryusuke; Arora, Neha; Milic, Jovana V.; Hinderhofer, Alexander; Schreiber, Frank; Uhl, Alexander R.; Zakeeruddin, Shaik M.; Hagfeldt, Anders; Dar, M. Ibrahim; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahydrophobic 3D/2D fluoroarene bilayer-based water-resistant perovskite solar cells with efficiencies exceeding 22%", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Preventing the degradation of metal perovskite solar cells (PSCs) by humid air poses a substantial challenge for their future deployment. We introduce here a two-dimensional (2D) A(2)PbI(4) perovskite layer using pentafluoro-phenylethylammonium (FEA) as a fluoroarene cation inserted between the 3D light-harvesting perovskite film and the hole-transporting material (HTM). The perfluorinated benzene moiety confers an ultrahydrophobic character to the spacer layer, protecting the perovskite light-harvesting material from ambient moisture while mitigating ionic diffusion in the device. Unsealed 3D/2D PSCs retain 90% of their efficiency during photovoltaic operation for 1000 hours in humid air under simulated sunlight. Remarkably, the 2D layer also enhances interfacial hole extraction, suppressing nonradiative carrier recombination and enabling a power conversion efficiency (PCE) > 22%, the highest reported for 3D/2D architectures. Our new approach provides water-and heat-resistant operationally stable PSCs with a record-level PCE.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 572, "Times Cited, All Databases": 591, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw2543", "DOI": "10.1126/sciadv.aaw2543", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw2543", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473798500066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, DJ; Hou, Y; Liu, SC; Wei, MY; Chen, B; Huang, ZR; Li, ZB; Sun, B; Proppe, AH; Dong, YT; Saidaminov, MI; Kelley, SO; Hu, JS; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Ding-Jiang; Hou, Yi; Liu, Shun-Chang; Wei, Mingyang; Chen, Bin; Huang, Ziru; Li, Zongbao; Sun, Bin; Proppe, Andrew H.; Dong, Yitong; Saidaminov, Makhsud I.; Kelley, Shana O.; Hu, Jin-Song; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating strain in perovskite thin films through charge-transport layers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermally-induced tensile strain that remains in perovskite films following annealing results in increased ion migration and is a known factor in the instability of these materials. Previously-reported strain regulation methods for perovskite solar cells (PSCs) have utilized substrates with high thermal expansion coefficients that limits the processing temperature of perovskites and compromises power conversion efficiency. Here we compensate residual tensile strain by introducing an external compressive strain from the hole-transport layer. By using a hole-transport layer with high thermal expansion coefficient, we compensate the tensile strain in PSCs by elevating the processing temperature of hole-transport layer. We find that compressive strain increases the activation energy for ion migration, improving the stability of perovskite films. We achieve an efficiency of 16.4% for compressively-strained PSCs; and these retain 96% of their initial efficiencies after heating at 85 degrees C for 1000 hours-the most stable wide-bandgap perovskites (above 1.75eV) reported so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 480, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1514, "DOI": "10.1038/s41467-020-15338-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15338-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522192500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, SL; Guo, CX; Wang, JN; Li, ZJ; Yang, B; Lei, LC; Wang, LP; Xiao, JP; Zhang, T; Hou, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Siliu; Guo, Chenxi; Wang, Jianing; Li, Zhongjian; Yang, Bin; Lei, Lecheng; Wang, Liping; Xiao, Jianping; Zhang, Tao; Hou, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction (OER) plays a key role in many renewable energy technologies such as water splitting and metal-air batteries. Metal-organic frameworks (MOFs) are appealing to design efficient OER electrocatalysts, however, their intrinsic poor conductivity strongly hinders the activity. Here, we show a strategy to boost the OER activity of poor-conductive MOFs by confining them between graphene multilayers. The resultant NiFe-MOF//G gives a record-low overpotential of 106 mV to reach 10 mA cm(-2) and retains the activity over 150 h, which is in significant contrast to 399 mV of the pristine NiFe-MOF. We use X-ray absorption spectroscopy (XAS) and computations to demonstrate that the nulloconfinement from graphene multilayers not only forms highly reactive NiO6-FeO5 distorted octahedral species in MOF structure but also lowers limiting potential for water oxidation reaction. We also demonstrate that the strategy is applicable to other MOFs of different structures to largely enhance their electrocatalytic activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6171, "DOI": "10.1038/s41467-022-33847-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33847-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870349500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maintz, S; Deringer, VL; Tchougréeff, AL; Dronskowski, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maintz, Stefan; Deringer, Volker L.; Tchougreeff, Andrei L.; Dronskowski, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LOBSTER: A Tool to Extract Chemical Bonding from Plane-Wave Based DFT", "Source Title": "JOURNAL OF COMPUTATIONAL CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The computer program LOBSTER (Local Orbital Basis Suite Towards Electronic-Structure Reconstruction) enables chemical-bonding analysis based on periodic plane-wave (PAW) density-functional theory (DFT) output and is applicable to a wide range of first-principles simulations in solid-state and materials chemistry. LOBSTER incorporates analytic projection routines described previously in this very journal [J. Comput. Chem. 2013, 34, 2557] and offers improved functionality. It calculates, among others, atom-projected densities of states (pDOS), projected crystal orbital Hamilton population (pCOHP) curves, and the recently introduced bond-weighted distribution function (BWDF). The software is offered free-of-charge for noncommercial research. (C) 2016 The Authors. Journal of Computational Chemistry Published by Wiley Periodicals, Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2363, "Times Cited, All Databases": 2467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2016, "Volume": 37, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1030, "End Page": 1035, "Article Number": null, "DOI": "10.1002/jcc.24300", "DOI Link": "http://dx.doi.org/10.1002/jcc.24300", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374023100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XP; Du, LL; Zhao, WJ; Zhao, Z; Xiong, Y; He, XW; Gao, PF; Alam, P; Wang, C; Li, Z; Leng, J; Liu, JX; Zhou, CY; Lam, JWY; Phillips, DL; Zhang, GQ; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xuepeng; Du, Lili; Zhao, Weijun; Zhao, Zheng; Xiong, Yu; He, Xuewen; Gao, Peng Fei; Alam, Parvej; Wang, Can; Li, Zhen; Leng, Jing; Liu, Junxue; Zhou, Chuanyao; Lam, Jacky W. Y.; Phillips, David Lee; Zhang, Guoqing; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralong UV/mechano-excited room temperature phosphorescence from purely organic cluster excitons", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Purely organic room temperature phosphorescence (RTP) has attracted wide attention recently due to its various application potentials. However, ultralong RTP (URTP) with high efficiency is still rarely achieved. Herein, by dissolving 1,8-naphthalic anhydride in certain organic solid hosts, URTP with a lifetime of over 600 ms and overall quantum yield of over 20% is realized. Meanwhile, the URTP can also be achieved by mechanical excitation when the host is mechanoluminescent. Femtosecond transient absorption studies reveal that intersystem crossing of the host is accelerated substantially in the presence of a trace amount of 1,8-naphthalic anhydride. Accordingly, we propose that a cluster exciton spanning the host and guest forms as a transient state before the guest acts as an energy trap for the RTP state. The cluster exciton model proposed here is expected to help expand the varieties of purely organic URTP materials based on an advanced understanding of guest/host combinations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5161, "DOI": "10.1038/s41467-019-13048-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13048-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496409800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PF; Wang, M; Liu, F; Ding, SY; Wang, X; Du, GH; Liu, J; Apel, P; Kluth, P; Trautmann, C; Wang, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengfei; Wang, Mao; Liu, Feng; Ding, Siyuan; Wang, Xue; Du, Guanghua; Liu, Jie; Apel, Pavel; Kluth, Patrick; Trautmann, Christina; Wang, Yugang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast ion sieving using nulloporous polymeric membranes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The great potential of nulloporous membranes for water filtration and chemical separation has been challenged by the trade-off between selectivity and permeability. Here we report on nulloporous polymer membranes with an excellent balance between selectivity and permeability of ions. Our membranes are fabricated by irradiating 2-mu m-thick polyethylene terephthalate Lumirror (R) films with GeV heavy ions followed by ultraviolet exposure. These membranes show a high transport rate of K+ ions of up to 14 mol h(-1)m(-2) and a selectivity of alkali metal ions over heavy metal ions of >500. Combining transport experiments and molecular dynamics simulations with a polymeric nullopore model, we demonstrate that the high permeability is attributable to the presence of nullopores with a radius of similar to 0.5 nm and a density of up to 5 x 10(10) cm(-2), and the selectivity is ascribed to the interaction between the partially dehydrated ions and the negatively charged nullopore wall.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 569, "DOI": "10.1038/s41467-018-02941-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-02941-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424451300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DF; Kong, LY; Fan, P; Chen, H; Zhu, SY; Liu, WY; Cao, L; Sun, YJ; Du, SX; Schneeloch, J; Zhong, RD; Gu, GD; Fu, L; Ding, H; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongfei; Kong, Lingyuan; Fan, Peng; Chen, Hui; Zhu, Shiyu; Liu, Wenyao; Cao, Lu; Sun, Yujie; Du, Shixuan; Schneeloch, John; Zhong, Ruidan; Gu, Genda; Fu, Liang; Ding, Hong; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for Majorana bound states in an iron-based superconductor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for Majorana bound states (MBSs) has been fueled by the prospect of using their non-Abelian statistics for robust quantum computation. Two-dimensional superconducting topological materials have been predicted to host MBSs as zero-energy modes in vortex cores. By using scanning tunneling spectroscopy on the superconducting Dirac surface state of the iron-based superconductor FeTe0.55Se0.45, we observed a sharp zero-bias peak inside a vortex core that does not split when moving away from the vortex center. The evolution of the peak under varying magnetic field, temperature, and tunneling barrier is consistent with the tunneling to a nearly pure MBS, separated from nontopological bound states. This observation offers a potential platform for realizing and manipulating MBSs at a relatively high temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 821, "Times Cited, All Databases": 886, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2018, "Volume": 362, "Issue": 6412, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 333, "End Page": 335, "Article Number": null, "DOI": "10.1126/science.aao1797", "DOI Link": "http://dx.doi.org/10.1126/science.aao1797", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447680100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YZ; Lin, L; Zhang, YG; Liu, L; Sa, B; Lin, J; Wang, LS; Peng, DL; Xie, QS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Youzhang; Lin, Liang; Zhang, Yinggan; Liu, Lie; Sa, Baisheng; Lin, Jie; Wang, Laisen; Peng, Dong-Liang; Xie, Qingshui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-Functional Lithiophilic/Sulfiphilic Binary-Metal Selenide Quantum Dots Toward High-Performance Li-S Full Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The commercial viability of lithium-sulfur batteries is still challenged by the notorious lithium polysulfides (LiPSs) shuttle effect on the sulfur cathode and uncontrollable Li dendrites growth on the Li anode. Herein, a bi-service host with Co-Fe binary-metal selenide quantum dots embedded in three-dimensional inverse opal structured nitrogen-doped carbon skeleton (3DIO FCSe-QDs@NC) is elaborately designed for both sulfur cathode and Li metal anode. The highly dispersed FCSe-QDs with superb adsorptive-catalytic properties can effectively immobilize the soluble LiPSs and improve diffusion-conversion kinetics to mitigate the polysulfide-shutting behaviors. Simultaneously, the 3D-ordered porous networks integrated with abundant lithophilic sites can accomplish uniform Li deposition and homogeneous Li-ion flux for suppressing the growth of dendrites. Taking advantage of these merits, the assembled Li-S full batteries with 3DIO FCSe-QDs@NC host exhibit excellent rate performance and stable cycling ability (a low decay rate of 0.014% over 2,000 cycles at 2C). Remarkably, a promising areal capacity of 8.41 mAh cm(-2) can be achieved at the sulfur loading up to 8.50 mg cm(-2) with an ultra-low electrolyte/sulfur ratio of 4.1 mu L mg(-1). This work paves the bi-serve host design from systematic experimental and theoretical analysis, which provides a viable avenue to solve the challenges of both sulfur and Li electrodes for practical Li-S full batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 67, "DOI": "10.1007/s40820-023-01037-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01037-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953337300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, HQ; Yu, F; Huang, YF; Sun, JY; Zhu, Z; Nielsen, RJ; He, R; Bao, JM; Goddard, WA; Chen, S; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Haiqing; Yu, Fang; Huang, Yufeng; Sun, Jingying; Zhu, Zhuan; Nielsen, Robert J.; He, Ran; Bao, Jiming; Goddard, William A., III; Chen, Shuo; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen evolution by ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the massive consumption of fossil fuels and its detrimental impact on the environment, methods of generating clean power are urgent. Hydrogen is an ideal carrier for renewable energy; however, hydrogen generation is inefficient because of the lack of robust catalysts that are substantially cheaper than platinum. Therefore, robust and durable earth-abundant and cost-effective catalysts are desirable for hydrogen generation from water splitting via hydrogen evolution reaction. Here we report an active and durable earth-abundant transition metal dichalcogenide-based hybrid catalyst that exhibits high hydrogen evolution activity approaching the state-of-the-art platinum catalysts, and superior to those of most transition metal dichalcogenides (molybdenum sulfide, cobalt diselenide and so on). Our material is fabricated by growing ternary molybdenum sulfoselenide particles on self-standing porous nickel diselenide foam. This advance provides a different pathway to design cheap, efficient and sizable hydrogen-evolving electrode by simultaneously tuning the number of catalytic edge sites, porosity, heteroatom doping and electrical conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12765, "DOI": "10.1038/ncomms12765", "DOI Link": "http://dx.doi.org/10.1038/ncomms12765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385362400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, JW; Liu, K; Jiang, KX; Li, HJW; An, PD; Li, WZ; Zhang, N; Li, HM; Xu, XW; Zhou, HQ; Tang, DS; Wang, XM; Qiu, XQ; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Junwei; Liu, Kang; Jiang, Kexin; Li, Huangjingwei; An, Pengda; Li, Wenzhang; Zhang, Ning; Li, Hongmei; Xu, Xiaowen; Zhou, Haiqing; Tang, Dongsheng; Wang, Xiaoming; Qiu, Xiaoqing; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphitic Carbon Nitride with Dopant Induced Charge Localization for Enhanced Photoreduction of CO2 to CH4", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photoreduction of CO2 to hydrocarbon products has attracted much attention because it provides an avenue to directly synthesize value-added carbon-based fuels and feedstocks using solar energy. Among various photocatalysts, graphitic carbon nitride (g-C3N4) has emerged as an attractive metal-free visible-light photocatalyst due to its advantages of earth-abundance, nontoxicity, and stability. Unfortunately, its photocatalytic efficiency is seriously limited by charge carriers ' ready recombination and their low reaction dynamics. Modifying the local electronic structure of g-C3N4 is predicted to be an efficient way to improve the charge transfer and reaction efficiency. Here, boron (B) is doped into the large cavity between adjacent tri-s-triazine units via coordination with two-coordinated N atoms. Theoretical calculations prove that the new electron excitation from N (2p(x), 2p(y)) to B (2p(x), 2p(y)) with the same orbital direction in B-doped g-C3N4 is much easier than N (2p(x), 2p(y)) to C 2p(z) in pure g-C3N4, and improves the charge transfer and localization, and thus the reaction dynamics. Moreover, B atoms doping changes the adsorption of CO (intermediate), and can act as active sites for CH4 production. As a result, the optimal sample of 1%B/g-C3N4 exhibits better selectivity for CH4 with approximate to 32 times higher yield than that of pure g-C3N4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 6, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900796, "DOI": "10.1002/advs.201900796", "DOI Link": "http://dx.doi.org/10.1002/advs.201900796", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477576400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, QY; Ning, D; Wong, D; An, K; Tang, YX; Zhou, D; Schuck, G; Chen, ZH; Zhang, NA; Liu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qingyuan; Ning, De; Wong, Deniz; An, Ke; Tang, Yuxin; Zhou, Dong; Schuck, Goetz; Chen, Zhenhua; Zhang, Nian; Liu, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving the oxygen redox reversibility of Li-rich battery cathode materials via Coulombic repulsive interactions strategy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen redox reaction in lithium-rich layered oxide battery cathode materials generates extra capacity at high cell voltages (i.e., >4.5 V). However, the irreversible oxygen release causes transition metal (TM) dissolution, migration and cell voltage decay. To circumvent these issues, we introduce a strategy for tuning the Coulombic interactions in a model Li-rich positive electrode active material, i.e., Li1.2Mn0.6Ni0.2O2. In particular, we tune the Coulombic repulsive interactions to obtain an adaptable crystal structure that enables the reversible distortion of TMO6 octahedron and mitigates TM dissolution and migration. Moreover, this strategy hinders the irreversible release of oxygen and other parasitic reactions (e.g., electrolyte decomposition) commonly occurring at high voltages. When tested in non-aqueous coin cell configuration, the modified Li-rich cathode material, combined with a Li metal anode, enables a stable cell discharge capacity of about 240 mAh g(-1) for 120 cycles at 50 mA g(-1) and a slower voltage decay compared to the unmodified Li1.2Mn0.6Ni0.2O2. Tailoring the oxygen redox reactivity in Li-rich cathode is crucial for developing high-energy batteries. Here, the authors report a strategy to obtain a flexible crystal structure and enhance the oxygen redox reversibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1123, "DOI": "10.1038/s41467-022-28793-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28793-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763605200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HW; Gu, XK; Zheng, XS; Pan, HB; Zhu, JF; Chen, S; Cao, LN; Li, WX; Lu, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hengwei; Gu, Xiang-Kui; Zheng, Xusheng; Pan, Haibin; Zhu, Junfa; Chen, Si; Cao, Lina; Li, Wei-Xue; Lu, Junling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Disentangling the size-dependent geometric and electronic effects of palladium nullocatalysts beyond selectivity", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The prominent size effect of metal nulloparticles shapes decisively nullocatalysis, but entanglement of the corresponding geometric and electronic effects prevents exploiting their distinct functionalities. In this work, we demonstrate that in palladium (Pd)-catalyzed aerobic oxidation of benzyl alcohol, the geometric and electronic effects interplay and compete so intensively that both activity and selectivity showed in volcano trends on the Pd particle size unprecedentedly. By developing a strategy of site-selective blocking via atomic layer deposition along with first principles calculations, we disentangle these two effects and unveil that the geometric effect dominates the right side of the volcano with larger-size Pd particles, whereas the electronic effect directs the left of the volcano with smaller-size Pd particles substantially. Selective blocking of the low-coordination sites prevents formation of the undesired by-product beyond the volcano relationship, achieving a remarkable benzaldehyde selectivity and activity at the same time for 4-nm Pd. Disentangling the geometric and electronic effects of metal nulloparticles opens a new dimension for rational design of catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat6413", "DOI": "10.1126/sciadv.aat6413", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat6413", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457547900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Huang, YC; Xu, KQ; Zhong, YY; He, CH; Jiang, LP; Sun, JK; Rao, Z; Zhu, JN; Huang, J; Xiao, F; Liu, HF; Xia, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhengyun; Huang, Yuchen; Xu, Kunqi; Zhong, Yanyu; He, Chaohui; Jiang, Lipei; Sun, Jiankang; Rao, Zhuang; Zhu, Jiannull; Huang, Jing; Xiao, Fei; Liu, Hongfang; Xia, Bao Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural oxidase-mimicking copper-organic frameworks for targeted identification of ascorbate in sensitive sweat sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sweat sensors play a significant role in personalized healthcare by dynamically monitoring biochemical markers to detect individual physiological status. The specific response to the target biomolecules usually depends on natural oxidase, but it is susceptible to external interference. In this work, we report tryptophan- and histidine-treated copper metal-organic frameworks (Cu-MOFs). This amino-functionalized copper-organic framework shows highly selective activity for ascorbate oxidation and can serve as an efficient ascorbate oxidase-mimicking material in sensitive sweat sensors. Experiments and calculation results elucidate that the introduced tryptophan/histidine fundamentally regulates the adsorption behaviors of biomolecules, enabling ascorbate to be selectively captured from complex sweat and further efficiently electrooxidized. This work provides not only a paradigm for specifically sweat sensing but also a significant understanding of natural oxidase-inspired MOF nulloenzymes for sensing technologies and beyond. Sweat sensors are important in personalized healthcare using natural oxidase to target biomolecules but these reactions are susceptible to external interference. Here, the authors report tryptophan- and histidine-treated copper metal-organic frameworks which show highly selective activity for ascorbate oxidation and can serve as an efficient ascorbate oxidase-mimicking material in sensitive sweat sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 69, "DOI": "10.1038/s41467-022-35721-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35721-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940650100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, DZ; Balachandran, PV; Hogden, J; Theiler, J; Xue, DQ; Lookman, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Dezhen; Balachandran, Prasanna V.; Hogden, John; Theiler, James; Xue, Deqing; Lookman, Turab", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated search for materials with targeted properties by adaptive design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Finding new materials with targeted properties has traditionally been guided by intuition, and trial and error. With increasing chemical complexity, the combinatorial possibilities are too large for an Edisonian approach to be practical. Here we show how an adaptive design strategy, tightly coupled with experiments, can accelerate the discovery process by sequentially identifying the next experiments or calculations, to effectively navigate the complex search space. Our strategy uses inference and global optimization to balance the trade-off between exploitation and exploration of the search space. We demonstrate this by finding very low thermal hysteresis (Delta T) NiTi-based shape memory alloys, with Ti50.0Ni46.7Cu0.8Fe2.3Pd0.2 possessing the smallest Delta T (1.84 K). We synthesize and characterize 36 predicted compositions (9 feedback loops) from a potential space of similar to 800,000 compositions. Of these, 14 had smaller Delta T than any of the 22 in the original data set.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 675, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11241, "DOI": "10.1038/ncomms11241", "DOI Link": "http://dx.doi.org/10.1038/ncomms11241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374122300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, ZH; Sun, YQ; Tsang, DCW; Khan, E; Yip, ACK; Ng, YH; Rinklebe, J; Ok, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Zhonghao; Sun, Yuqing; Tsang, Daniel C. W.; Khan, Eakalak; Yip, Alex C. K.; Ng, Yun Hau; Rinklebe, Joerg; Ok, Yong Sik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Customised fabrication of nitrogen-doped biochar for environmental and energy applications", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Global warming, environmental pollution, and energy shortage are causing severe environmental concerns for sustainable development. Conversion of various renewable biowastes into value-added carbon-based materials can be a promising option to alleviate these issues. The emergence of nitrogen (N)-doped biochar provides a versatile electroactive candidate suitable for environmental and energy applications. In this review, we scrutinise and highlight the customised production of N-doped biochars and their up-to-date applications in environmental remediation, energy storage, and biorefinery fields. With a comprehensive overview on the original precursor, the interspecies conversion, and the ultimate deactivation of various N-dopants in biochar-based carbocatalysis, their formation mechanisms, distinct electrochemical characteristics, fate in the environmental and energy applications, and electrochemical behaviour can be thoroughly analysed. Contemporary challenges that require to be addressed and perspectives on improving N-doping technique on biochar are articulated. Overall, this review helps to provide new insights into the customised production of N-doped biochar for its broader applications in sustainable carbocatalysis and green chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2020, "Volume": 401, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126136, "DOI": "10.1016/j.cej.2020.126136", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.126136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569901800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Milina, M; Mitchell, S; Crivelli, P; Cooke, D; Pérez-Ramírez, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Milina, Maria; Mitchell, Sharon; Crivelli, Paolo; Cooke, David; Perez-Ramirez, Javier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesopore quality determines the lifetime of hierarchically structured zeolite catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deactivation due to coking limits the lifetime of zeolite catalysts in the production of chemicals and fuels. Superior performance can be achieved through hierarchically structuring the zeolite porosity, yet no relation has been established between the mesopore architecture and the catalyst lifetime. Here we introduce a top-down demetallation strategy to locate mesopores in different regions of MFI-type crystals with identical bulk porous and acidic properties. In contrast, well-established bottom-up strategies as carbon templating and seed silanization fail to yield materials with matching characteristics. Advanced characterization tools capable of accurately discriminating the mesopore size, distribution and connectivity are applied to corroborate the concept of mesopore quality. Positron annihilation lifetime spectroscopy proves powerful to quantify the global connectivity of the intracrystalline pore network, which, as demonstrated in the conversions of methanol or of propanal to hydrocarbons, is closely linked to the lifetime of zeolite catalysts. The findings emphasize the need to aptly tailor hierarchical materials for maximal catalytic advantage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3922, "DOI": "10.1038/ncomms4922", "DOI Link": "http://dx.doi.org/10.1038/ncomms4922", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337504800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dubouis, N; Grimaud, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dubouis, Nicolas; Grimaud, Alexis", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The hydrogen evolution reaction: from material to interfacial descriptors", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The production of sustainable hydrogen with water electrolyzers is envisaged as one of the most promising ways to match the continuously growing demand for renewable electricity storage. While so far regarded as fast when compared to the oxygen evolution reaction (OER), the hydrogen evolution reaction (HER) regained interest in the last few years owing to its poor kinetics in alkaline electrolytes. Indeed, this slow kinetics not only may hinder the foreseen development of the anionic exchange membrane water electrolyzer (AEMWE), but also raises fundamental questions regarding the parameters governing the reaction. In this perspective, we first briefly review the fundamentals of the HER, emphasizing how studies performed on model electrodes allowed for achieving a good understanding of its mechanism under acidic conditions. Then, we discuss how the use of physical descriptors capturing the sole properties of the catalyst is not sufficient to describe the HER kinetics under alkaline conditions, thus forcing the catalysis community to adopt a more complex picture taking into account the electrolyte structure at the electrochemical interface. This work also outlines new techniques, such as spectroscopies, molecular simulations, or chemical approaches that could be employed to tackle these new fundamental challenges, and potentially guide the future design of practical and cheap catalysts while also being useful to a wider community dealing with electrochemical energy storage devices using aqueous electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 696, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2019, "Volume": 10, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9165, "End Page": 9181, "Article Number": null, "DOI": "10.1039/c9sc03831k", "DOI Link": "http://dx.doi.org/10.1039/c9sc03831k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490984300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Chen, B; Liu, Y; Deng, YH; Bai, Y; Dong, QF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qi; Chen, Bo; Liu, Ye; Deng, Yehao; Bai, Yang; Dong, Qingfeng; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling behavior of moisture-induced grain degradation in polycrystalline hybrid perovskite thin films", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stability of perovskite solar cells has shown a huge variation with respect to the film process and film morphology, while the underlining mechanism for the morphology-dependent degradation of the perovskite filmhas remained elusive. Herein, we report a scaling behavior of moisture-induced grain degradation in polycrystalline CH3NH3PbI3 films. The degradation rates of CH3NH3PbI3 films in moisture were shown to be sensitive to the grain sizes. The duration that was needed for different films to degrade by the same percent showed a linear relationship with the grain size, despite the fact that the films were formed by five different deposition methods. This scaling behavior can be explained by the degradation along the in-plane direction, which is initiated at the grain boundary (GB). The GBs of CH3NH3PbI3 films consist of an amorphous intergranular layer, which allows quick diffusion of moisture into the perovskite films. It was found that thermal annealing induced surface self-passivation plays a critical role in stabilizing the surfaces of thin films and single crystals by reducing the moisture-sensitive methylammonium ions at the surface. The determination of the scaling behavior of grain degradation highlights the importance of stabilizing the GBs to improve the stability of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 776, "Times Cited, All Databases": 815, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 516, "End Page": 522, "Article Number": null, "DOI": "10.1039/c6ee02941h", "DOI Link": "http://dx.doi.org/10.1039/c6ee02941h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395679100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, B; Yoon, CS; Lee, HR; Chung, KY; Cho, BW; Oh, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Boeun; Yoon, Chong Seung; Lee, Hae Ri; Chung, Kyung Yoon; Cho, Byung Won; Oh, Si Hyoung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn-ion batteries are emerging energy storage systems eligible for large-scale applications, such as electric vehicles. These batteries consist of totally environmentally-benign electrode materials and potentially manufactured very economically. Although Zn/alpha-MnO2 systems produce high energy densities of 225 Wh kg(-1), larger than those of conventional Mg-ion batteries, they show significant capacity fading during long-term cycling and suffer from poor performance at high current rates. To solve these problems, the concrete reaction mechanism between alpha-MnO2 and zinc ions that occur on the cathode must be elucidated. Here, we report the intercalation mechanism of zinc ions into alpha-MnO2 during discharge, which involves a reversible phase transition of MnO2 from tunneled to layered polymorphs by electrochemical reactions. This transition is initiated by the dissolution of manganese from alpha-MnO2 during discharge process to form layered Zn-birnessite. The original tunneled structure is recovered by the incorporation of manganese ions back into the layers of Zn-birnessite during charge process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 14", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6066, "DOI": "10.1038/srep06066", "DOI Link": "http://dx.doi.org/10.1038/srep06066", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340675000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CD; Chuu, CP; Ren, XB; Li, MY; Li, LJ; Jin, CH; Chou, MY; Shih, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chendong; Chuu, Chih-Piao; Ren, Xibiao; Li, Ming-Yang; Li, Lain-Jong; Jin, Chuanhong; Chou, Mei-Yin; Shih, Chih-Kang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interlayer couplings, Moire patterns, and 2D electronic superlattices in MoS2/WSe2 hetero-bilayers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By using direct growth, we create a rotationally aligned MoS2/WSe2 hetero-bilayer as a designer van der Waals heterostructure. With rotational alignment, the lattice mismatch leads to a periodic variation of atomic registry between individual van der Waals layers, exhibiting a Moire pattern with a well-defined periodicity. By combining scanning tunneling microscopy/spectroscopy, transmission electronmicroscopy, and first-principles calculations, we investigate interlayer coupling as a function of atomic registry. We quantitatively determine the influence of interlayer coupling on the electronic structure of the hetero-bilayer at different critical points. We show that the direct gap semiconductor concept is retained in the bilayer although the valence and conduction band edges are located at different layers. We further show that the local bandgap is periodically modulated in the X-Y direction with an amplitude of similar to 0.15 eV, leading to the formation of a two-dimensional electronic superlattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601459", "DOI": "10.1126/sciadv.1601459", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601459", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393789900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, WJ; Ma, WB; Su, YR; Chen, Z; Chen, XY; Ma, YG; Bai, LZ; Xiao, WG; Liu, TY; Zhu, HM; Liu, XF; Liu, HF; Liu, X; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Wenjuan; Ma, Wenbo; Su, Yirong; Chen, Zeng; Chen, Xinya; Ma, Yaoguang; Bai, Lizhong; Xiao, Wenge; Liu, Tianyu; Zhu, Haiming; Liu, Xiaofeng; Liu, Huafeng; Liu, Xu; Yang, Yang (Michael)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-dose real-time X-ray imaging with nontoxic double perovskite scintillators", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-rays are widely used in probing inside information nondestructively, enabling broad applications in the medical radiography and electronic industries. X-ray imaging based on emerging lead halide perovskite scintillators has received extensive attention recently. However, the strong self-absorption, relatively low light yield and lead toxicity of these perovskites restrict their practical applications. Here, we report a series of nontoxic double-perovskite scintillators of Cs2Ag0.6Na0.4In1-yBiyCl6. By controlling the content of the heavy atom Bi3+, the X-ray absorption coefficient, radiative emission efficiency, light yield and light decay were manipulated to maximise the scintillator performance. A light yield of up to 39,000 +/- 7000 photons/MeV for Cs(2)Ag(0.6)Na(0.4)In(0.85)Bi(0.15)Cl(6)was obtained, which is much higher than that for the previously reported lead halide perovskite colloidal CsPbBr3(21,000 photons/MeV). The large Stokes shift between the radioluminescence (RL) and absorption spectra benefiting from self-trapped excitons (STEs) led to a negligible self-absorption effect. Given the high light output and fast light decay of this scintillator, static X-ray imaging was attained under an extremely low dose of similar to 1 mu Gy(air), and dynamic X-ray imaging of finger bending without a ghosting effect was demonstrated under a low-dose rate of 47.2 mu Gy(air) s(-1). After thermal treatment at 85 degrees C for 50 h followed by X-ray irradiation for 50 h in ambient air, the scintillator performance in terms of the RL intensity and X-ray image quality remained almost unchanged. Our results shed light on exploring highly competitive scintillators beyond the scope of lead halide perovskites, not only for avoiding toxicity but also for better performance. X-ray imaging: Better crystals to convert X-rays into light Low-dose X-ray imaging, which relies on scintillators to convert X-ray photons into readily detectable photons of light, has been improved using new varieties of scintillators composed of materials known as double perovskites. Yang Yang and colleagues at Zhejiang University in China made their scintillators from nontoxic elements including caesium, silver, sodium, indium, bismuth and chloride ions. They outperform existing lead halide perovskite scintillators due to greatly increased light-yield, heat stability and low toxicity. Unlike many alternatives, they do not contain toxic lead ions. The researchers maximised the light-yielding efficiency by controlling the content of bismuth ions (Bi3+) in the double perovskite crystals. They demonstrated the potential of their material by achieving exceptionally low-dose static X-ray images and real-time dynamic images of finger bending. The researchers see great scope for further improvements by exploring other types of lead-free perovskites and perovskite derivatives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112, "DOI": "10.1038/s41377-020-00353-0", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-00353-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546949700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HX; Zhang, GZ; Wang, Y; Ning, MQ; Ouyang, B; Zhao, Y; Huang, Y; Liu, PB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Hanxiao; Zhang, Guozheng; Wang, Yi; Ning, Mingqiang; Ouyang, Bo; Zhao, Yang; Huang, Ying; Liu, Panbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size-Dependent Oxidation-Induced Phase Engineering for MOFs Derivatives Via Spatial Confinement Strategy Toward Enhanced Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precisely reducing the size of metal-organic frameworks (MOFs) derivatives is an effective strategy to manipulate their phase engineering owing to size-dependent oxidation; however, the underlying relationship between the size of derivatives and phase engineering has not been clarified so far. Herein, a spatial confined growth strategy is proposed to encapsulate small-size MOFs derivatives into hollow carbon nullocages. It realizes that the hollow cavity shows a significant spatial confinement effect on the size of confined MOFs crystals and subsequently affects the dielectric polarization due to the phase hybridization with tunable coherent interfaces and heterojunctions owing to size-dependent oxidation motion, yielding to satisfied microwave attenuation with an optimal reflection loss of -50.6 dB and effective bandwidth of 6.6 GHz. Meanwhile, the effect of phase hybridization on dielectric polarization is deeply visualized, and the simulated calculation and electron holograms demonstrate that dielectric polarization is shown to be dominullt dissipation mechanism in determining microwave absorption. This spatial confined growth strategy provides a versatile methodology for manipulating the size of MOFs derivatives and the understanding of size-dependent oxidation-induced phase hybridization offers a precise inspiration in optimizing dielectric polarization and microwave attenuation in theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102, "DOI": "10.1007/s40820-022-00841-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00841-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781951100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, FY; Liu, LF; Liu, T; Wang, XB; Qi, Q; Hang, ZS; Chen, K; Xu, JH; Fu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, FuYao; Liu, LongFei; Liu, Tong; Wang, XueBin; Qi, Qi; Hang, ZuSheng; Chen, Kai; Xu, JianHua; Fu, JiaJun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vascular smooth muscle-inspired architecture enables soft yet tough self-healing materials for durable capacitive strain-sensor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Catastrophically mechanical failure of soft self-healing materials is unavoidable due to their inherently poor resistance to crack propagation. Here, with a model system, i.e., soft self-healing polyurea, we present a biomimetic strategy of surpassing trade-off between soft self-healing and high fracture toughness, enabling the conversion of soft and weak into soft yet tough self-healing material. Such an achievement is inspired by vascular smooth muscles, where core-shell structured Galinstan micro-droplets are introduced through molecularly interfacial metal-coordinated assembly, resulting in an increased crack resistant strain and fracture toughness of 12.2 and 34.9 times without sacrifi-cing softness. The obtained fracture toughness is up to 111.16 +/- 8.76 kJ/m(2), even higher than that of Al and Zn alloys. Moreover, the resultant composite delivers fast self-healing kinetics (1 min) upon local near-infrared irradiation, and possesses ultra-high dielectric constants (similar to 14.57), thus being able to be fabricated into sensitive and self-healing capacitive strain-sensors tolerant towards cracks potentially evolved in service.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 130, "DOI": "10.1038/s41467-023-35810-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35810-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909978900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, C; Wu, CP; Gu, XX; Wang, C; Wang, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Chuang; Wu, Cuiping; Gu, Xingxing; Wang, Chao; Wang, Qinghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering via Ti3C2Tx MXene Electrolyte Additive toward Dendrite-Free Zinc Deposition", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsWell-dispersed MXene nullosheets in the electrolyte dramatically shorten Zn2+ diffusion pathways and facilitate their migration.MXene interfacial layer with abundant functional groups and good conductivity induces uniform nucleation and enables long-term even deposition.MXene-containing electrolyte realizes dendrite-free Zn plating/striping with high Coulombic efficiency (99.7%) and superior reversibility (stably up to 1180 cycles). AbstractZinc metal batteries have been considered as a promising candidate for next-generation batteries due to their high safety and low cost. However, their practical applications are severely hampered by the poor cyclability that caused by the undesired dendrite growth of metallic Zn. Herein, Ti3C2Tx MXene was first used as electrolyte additive to facilitate the uniform Zn deposition by controlling the nucleation and growth process of Zn. Such MXene additives can not only be absorbed on Zn foil to induce uniform initial Zn deposition via providing abundant zincophilic-O groups and subsequently participate in the formation of robust solid-electrolyte interface film, but also accelerate ion transportation by reducing the Zn2+ concentration gradient at the electrode/electrolyte interface. Consequently, MXene-containing electrolyte realizes dendrite-free Zn plating/striping with high Coulombic efficiency (99.7%) and superior reversibility (stably up to 1180 cycles). When applied in full cell, the Zn-V2O5 cell also delivers significantly improved cycling performances. This work provides a facile yet effective method for developing reversible zinc metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 89, "DOI": "10.1007/s40820-021-00612-8", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00612-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627384600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ügdüler, S; Van Geem, KM; Denolf, R; Roosen, M; Mys, N; Ragaert, K; De Meester, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ugduler, Sibel; Van Geem, Kevin M.; Denolf, Ruben; Roosen, Martijn; Mys, Nicolas; Ragaert, Kim; De Meester, Steven", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards closed-loop recycling of multilayer and coloured PET plastic waste by alkaline hydrolysis", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The vast increase in the generation of post-consumer PET plastic waste, as well as fast increasing pledges of brand owners around the world to include recycled content have resulted in a pressing need for efficient recycling processes, such as chemical depolymerization. Although recycling rates of PET bottles are high, those of PET trays and films are still significantly lower due to the broad range of colours and multilayer structures, as well as due to a much poorer collection. In this study, a two-step aqueous alkaline hydrolysis was carried out on different types of real PET plastic waste under mild conditions (<= 80 degrees C under atmospheric pressure). Reaction conditions such as temperature (50-80 degrees C), ethanol to water ratio (20-100 vol%), NaOH amount (5-15 wt%) and stirring rate (250-500 rpm) have been optimized by using pure PET pellets in order to maximize the product yield. At optimal conditions (60 : 40 vol% EtOH : H2O, 5 wt% NaOH and at 80 degrees C) product yields on a mass basis of approximately 95% have been achieved in less than 20 minutes. The purity of the obtained monomers, ethylene glycol (EG) and terephthalic acid (TPA), was characterized by NMR, UV-VIS and FTIR measurements. The experimental kinetic data are represented adequately using the diffusion model. Experiments performed at optimal conditions with different types of post-consumer plastic waste, revealed that the degradation rate increases inversely proportional to the particle size. Furthermore, the increased thickness of the samples and the presence of multilayers reduce the decomposition yield with a factor two as observed for monolayer (80%)versusmultilayer PET trays (45%). In addition to transparent multilayer PET samples, by using the optimized alkaline hydrolysis with further cleaning processes different types of colours, including carbon black are removed from the hydrolysate successfully. A life cycle assessment (LCA) shows that the key to lower the carbon emissions is keeping the energy consumption low by increasing the solid/liquid (S/L) ratio and avoiding excess water addition during monomer purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2020, "Volume": 22, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5376, "End Page": 5394, "Article Number": null, "DOI": "10.1039/d0gc00894j", "DOI Link": "http://dx.doi.org/10.1039/d0gc00894j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560944400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Lü, XJ; Yang, WG; Wen, T; Yang, LX; Ren, XT; Wang, L; Lin, ZS; Zhao, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yonggang; Lu, Xujie; Yang, Wenge; Wen, Ting; Yang, Liuxiang; Ren, Xiangting; Wang, Lin; Lin, Zheshuai; Zhao, Yusheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-Induced Phase Transformation, Reversible Amorphization, and Anomalous Visible Light Response in Organolead Bromide Perovskite", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrostatic pressure, as an alternative of chemical pressure to tune the crystal structure and physical properties, is a significant technique for novel function material design and fundamental research. In this article, we report the phase stability and visible light response of the organolead bromide perovskite, CH3NH3PbBr3 (MAPbBr(3)), under hydrostatic pressure up to 34 GPa at room temperature: Two phase transformations below 2 GPa (from Pm (3) over barm to Im (3) over bar, then to Pnma) and a reversible amorphization starting from about 2 GPa were observed, which could be attributed to the tilting of PbBr6 octahedra and destroying of long-range ordering of MA cations, respectively. The visible light response of MAPbBr3 to pressure was studied by in situ photoluminescence, electric resistance, photocurrent measurements and first-principle simulations. The anomalous band gap evolution during compression with red-shift followed by blue-shift is explained by the competition between compression effect and pressure-induced amorphization. Along with the amorphization process accomplished around 25 GPa, the resistance increased by 5 orders of magnitude while the system still maintains its semiconductor characteristics and considerable response to the visible light irradiation. Our results not only show that hydrostatic pressure may provide an applicable tool for the organohalide perovskites based photovoltaic device functioning as switcher or controller, but also shed light on the exploration of more amorphous organometal composites as potential light absorber.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2015, "Volume": 137, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11144, "End Page": 11149, "Article Number": null, "DOI": "10.1021/jacs.5b06346", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b06346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360867000045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akkerman, QA; Park, S; Radicchi, E; Nunzi, F; Mosconi, E; De Angelis, F; Brescia, R; Rastogi, P; Prato, M; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akkerman, Quinten A.; Park, Sungwook; Radicchi, Eros; Nunzi, Francesca; Mosconi, Edoardo; De Angelis, Filippo; Brescia, Rosaria; Rastogi, Prachi; Prato, Mirko; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nearly Monodisperse Insulator Cs4PbX6 (X = Cl, Br, I) nullocrystals, Their Mixed Halide Compositions, and Their Transformation into CsPbX3 nullocrystals", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have developed a colloidal synthesis of nearly monodisperse nullocrystals of pure Cs4PbX6 (X = Cl, Br, I) and their mixed halide compositions with sizes ranging from 9 to 37 nm. The optical absorption spectra of these nullocrystals display a sharp, high energy peak due to transitions between states localized in individual PbX64- octahedra. These spectral features are insensitive to the size of the particles and in agreement with the features of the corresponding bulk materials. Samples with mixed halide composition exhibit absorption bands that are intermediate in spectral position between those of the pure halide compounds. Furthermore, the absorption bands of intermediate compositions broaden due to the different possible combinations of halide coordination around the Pb2+ ions. Both observations electronically decoupled in these systems. Because of the large are supportive of the fact are band gap of Cs4PbX6 (>3.2 the that the [PbX6](4-) octahedra eV), no excitonic emission in visible range was observed. The Cs4PbBr6 nullocrystals can be converted into green fluorescent CsPbBr3 nullocrystals by their reaction with an excess of PbBr2 with preservation of size and size distributions. The insertion of PbX2 into Cs4PbX6 provides a means of accessing CsPbX3 nullocrystals in a wide variety of sizes, shapes, and compositions, an important aspect for the development of precisely tuned perovskite nullocrystal inks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 525, "Times Cited, All Databases": 560, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1924, "End Page": 1930, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b05262", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b05262", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396185800087", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, Y; Dong, QF; Shao, YC; Deng, YH; Wang, Q; Shen, L; Wang, D; Wei, W; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yang; Dong, Qingfeng; Shao, Yuchuan; Deng, Yehao; Wang, Qi; Shen, Liang; Wang, Dong; Wei, Wei; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing stability and efficiency of perovskite solar cells with crosslinkable silane-functionalized and doped fullerene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The instability of hybrid perovskite materials due to water and moisture arises as one major challenge to be addressed before any practical application of the demonstrated high efficiency perovskite solar cells. Here we report a facile strategy that can simultaneously enhance the stability and efficiency of p-i-n planar heterojunction-structure perovskite devices. Crosslinkable silane molecules with hydrophobic functional groups are bonded onto fullerene to make the fullerene layer highly water-resistant. Methylammonium iodide is introduced in the fullerene layer for n-doping via anion-induced electron transfer, resulting in dramatically increased conductivity over 100-fold. With crosslinkable silane-functionalized and doped fullerene electron transport layer, the perovskite devices deliver an efficiency of 19.5% with a high fill factor of 80.6%. A crosslinked silane-modified fullerene layer also enhances the water and moisture stability of the non-sealed perovskite devices by retaining nearly 90% of their original efficiencies after 30 days' exposure in an ambient environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12806, "DOI": "10.1038/ncomms12806", "DOI Link": "http://dx.doi.org/10.1038/ncomms12806", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385542000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Zhang, CH; Duan, CH; Li, MM; Hu, ZC; Wang, J; Liu, F; Li, N; Brabec, CJ; Janssen, RAJ; Bazan, GC; Huang, F; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xi; Zhang, Chaohong; Duan, Chunhui; Li, Mengmeng; Hu, Zhicheng; Wang, Jing; Liu, Feng; Li, Ning; Brabec, Christoph J.; Janssen, Rene A. J.; Bazan, Guillermo C.; Huang, Fei; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphology Optimization via Side Chain Engineering Enables All Polymer Solar Cells with Excellent Fill Factor and Stability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-polymer solar cells (all-PSCs) composed of conjugated polymers as both donor and acceptor components in bulk heterojunction photoactive layers have attracted increasing attention. However, it is a big challenge to achieve optimal morphology in polymer:polymer blends. In response, we report herein a new strategy to adjust the nulloscale organization for all-PSCs. Specifically, side chain engineering of the well-known naphthalene diimide (NDI)-based polymer N2200 is modulated by introducing a fraction of linear oligoethylene oxide (OE) side chains to replace branched alkyl chains on the NDI units and by synthesizing a series of NDI-based polymer acceptors NOEx, where x is the percentage of OE chain substituted NDI units relative to total NDI units. Compared to the reference polymer NOE0, OE-chain-containing polymer NOE10 offers a much higher power conversion efficiency (PCE) of 8.1% with a record high fill factor (FF) of 0.75 in all-PSCs. Moreover, the NOE10-based all-PSC exhibits excellent long-term and thermal stabilities with >97% of the initial PCE being maintained after 300 h of aging at 65 degrees C. This work demonstrates an effective morphology optimization strategy to achieve highly efficient and stable all-PSCs and shows the excellent potential of NOE10 as an alternative to commercially available acceptor polymers N2200.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 140, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8934, "End Page": 8943, "Article Number": null, "DOI": "10.1021/jacs.8b05038", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b05038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439532000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, SJ; Li, H; Liu, D; Huang, R; Pan, XL; Ren, D; Li, J; Shakouri, M; Zhang, QX; Wang, MJ; Wei, CC; Mai, LQ; Zhang, B; Zhao, Y; Wang, ZB; Graetzel, M; Zhang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Sanjiang; Li, Hao; Liu, Dan; Huang, Rui; Pan, Xuelei; Ren, Dan; Li, Jun; Shakouri, Mohsen; Zhang, Qixing; Wang, Manjing; Wei, Changchun; Mai, Liqiang; Zhang, Bo; Zhao, Ying; Wang, Zhenbin; Graetzel, Michael; Zhang, Xiaodan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable noble-metal-free catalyst for acidic water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing non-noble catalysts with superior activity and durability for oxygen evolution reaction (OER) in acidic media is paramount for hydrogen production from water. Still, challenges remain due to the inadequate activity and stability of the OER catalyst. Here, we report a cost-effective and stable manganese oxybromide (Mn7.5O10Br3) catalyst exhibiting an excellent OER activity in acidic electrolytes, with an overpotential of as low as 295 +/- 5 mV at a current density of 10 mA cm(-2). Mn7.5O10Br3 maintains good stability under operating conditions for at least 500 h. In situ Raman spectroscopy, X ray absorption near edge spectroscopy, and density functional theory calculations confirm that a self-oxidized surface with enhanced electronic transmission capacity forms on Mn7.5O10Br3 and is responsible for both the high catalytic activity and long-term stability during catalysis. The development of Mn7.5O10Br3 as an OER catalyst provides crucial insights into the design of non-noble metal electrocatalysts for water oxidation. While acidic water splitting offers a renewable means to obtain renewable hydrogen fuel, the catalysts needed to oxidize water often require expensive noble metals. Here, authors show manganese oxyhalides as acidic oxygen evolution electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2294, "DOI": "10.1038/s41467-022-30064-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30064-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788852000034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yarulina, I; De Wispelaere, K; Bailleul, S; Goetze, J; Radersma, M; Abou-Hamad, E; Vollmer, I; Goesten, M; Mezari, B; Hensen, EJM; Martínez-Espín, JS; Morten, M; Mitchell, S; Perez-Ramirez, J; Olsbye, U; Weckhuysen, BM; Van Speybroeck, V; Kapteijn, F; Gascon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yarulina, Irina; De Wispelaere, Kristof; Bailleul, Simon; Goetze, Joris; Radersma, Mike; Abou-Hamad, Edy; Vollmer, Ina; Goesten, Maarten; Mezari, Brahim; Hensen, Emiel J. M.; Martinez-Espin, Juan S.; Morten, Magnus; Mitchell, Sharon; Perez-Ramirez, Javier; Olsbye, Unni; Weckhuysen, Bert M.; Van Speybroeck, Veronique; Kapteijn, Freek; Gascon, Jorge", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure-performance descriptors and the role of Lewis acidity in the methanol-to-propylene process", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The combination of well-defined acid sites, shape-selective properties and outstanding stability places zeolites among the most practically relevant heterogeneous catalysts. The development of structure-performance descriptors for processes that they catalyse has been a matter of intense debate, both in industry and academia, and the direct conversion of methanol to olefins is a prototypical system in which various catalytic functions contribute to the overall performance. Propylene selectivity and resistance to coking are the two most important parameters in developing new methanol-to-olefin catalysts. Here, we present a systematic investigation on the effect of acidity on the performance of the zeolite 'ZSM-5' for the production of propylene. Our results demonstrate that the isolation of Bronsted acid sites is key to the selective formation of propylene. Also, the introduction of Lewis acid sites prevents the formation of coke, hence drastically increasing catalyst lifetime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 804, "End Page": 812, "Article Number": null, "DOI": "10.1038/s41557-018-0081-0", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0081-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439420400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Golubkov, AW; Fuchs, D; Wagner, J; Wiltsche, H; Stangl, C; Fauler, G; Voitic, G; Thaler, A; Hacker, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Golubkov, Andrey W.; Fuchs, David; Wagner, Julian; Wiltsche, Helmar; Stangl, Christoph; Fauler, Gisela; Voitic, Gernot; Thaler, Alexander; Hacker, Viktor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal-runaway experiments on consumer Li-ion batteries with metal-oxide and olivin-type cathodes", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-ion batteries play an ever-increasing role in our daily life. Therefore, it is important to understand the potential risks involved with these devices. In this work we demonstrate the thermal runaway characteristics of three types of commercially available Li-ion batteries with the format 18650. The Li-ion batteries were deliberately driven into thermal runaway by overheating under controlled conditions. Cell temperatures up to 850 degrees C and a gas release of up to 0.27 mol were measured. The main gas components were quantified with gas-chromatography. The safety of Li-ion batteries is determined by their composition, size, energy content, design and quality. This work investigated the influence of different cathode-material chemistry on the safety of commercial graphite-based 18650 cells. The active cathode materials of the three tested cell types were (a) LiFePO4, (b) Li(Ni0.45Mn0.45Co0.10)O-2 and (c) a blend of LiCoO2 and Li(Ni0.50Mn0.25Co0.25)O-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 595, "Times Cited, All Databases": 676, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3633, "End Page": 3642, "Article Number": null, "DOI": "10.1039/c3ra45748f", "DOI Link": "http://dx.doi.org/10.1039/c3ra45748f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329039000068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, YC; Hsiao, YC; Wu, HM; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Ying-Chih; Hsiao, Yung-Chi; Wu, Hsing-Mei; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Waterproof Fabric-Based Multifunctional Triboelectric nullogenerator for Universally Harvesting Energy from Raindrops, Wind, and Human Motions and as Self-Powered Sensors", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing nimble, shape-adaptable, conformable, and widely implementable energy harvesters with the capability to scavenge multiple renewable and ambient energy sources is highly demanded for distributed, remote, and wearable energy uses to meet the needs of internet of things. Here, the first single waterproof and fabric-based multifunctional triboelectric nullogenerator (WPF-MTENG) is presented, which can produce electricity from both natural tiny impacts (rain and wind) and body movements, and can not only serve as a flexible, adaptive, wearable, and universal energy collector but also act as a self-powered, active, fabric-based sensor. The working principle comes from a conjunction of contact triboelectrification and electrostatic induction during contact/separation of internal soft fabrics. The structural/material designs of the WPF-MTENG are systematically studied to optimize its performance, and its outputs under different conditions of rain, wind, and various body movements are comprehensively investigated. Its applicability is practically demonstrated in various objects and working situations to gather ambient energy. Lastly, a WPF-MTENG-based keypad as self-powered human-system interfaces is demonstrated on a garment for remotely controlling a music-player system. This multifunctional WPF-MTENG, which is as flexible as clothes, not only presents a promising step toward democratic collections of alternative energy but also provides a new vision for wearable technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801883, "DOI": "10.1002/advs.201801883", "DOI Link": "http://dx.doi.org/10.1002/advs.201801883", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460374300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gheytani, S; Liang, YL; Wu, FL; Jing, Y; Dong, H; Rao, KK; Chi, XW; Fang, F; Yao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gheytani, Saman; Liang, Yanliang; Wu, Feilong; Jing, Yan; Dong, Hui; Rao, Karun K.; Chi, Xiaowei; Fang, Fang; Yao, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Aqueous Ca-Ion Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multivalent-ion batteries are emerging as low-cost, high energy density, and safe alternatives to Li-ion batteries but are challenged by slow cation diffusion in electrode materials due to the high polarization strength of Mg- and Al-ions. In contrast, Ca-ion has a low polarization strength similar to that of Li-ion, therefore a Ca-ion battery will share the advantages while avoiding the kinetics issues related to multivalent batteries. However, there is no battery known that utilizes the Ca-ion chemistry due to the limited success in Ca-ion storage materials. Here, a safe and low-cost aqueous Ca-ion battery based on a highly reversible polyimide anode and a high-potential open framework copper hexacyanoferrate cathode is demonstrated. The prototype cell shows a stable capacity and high efficiency at both high and low current rates, with an 88% capacity retention and an average 99% coloumbic efficiency after cycling at 10C for 1000 cycles. The Ca-ion storage mechanism for both electrodes as well as the origin of the fast kinetics have been investigated. Additional comparison with a Mg-ion cell with identical electrodes reveals clear kinetics advantages for the Ca-ion system, which is explained by the smaller ionic radii and more facile desolvation of hydrated Ca-ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700465, "DOI": "10.1002/advs.201700465", "DOI Link": "http://dx.doi.org/10.1002/advs.201700465", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418385800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "El-Kady, MF; Ihns, M; Li, MP; Hwang, JY; Mousavi, MF; Chaney, L; Lech, AT; Kaner, RB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "El-Kady, Maher F.; Ihns, Melanie; Li, Mengping; Hwang, Jee Youn; Mousavi, Mir F.; Chaney, Lindsay; Lech, Andrew T.; Kaner, Richard B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-performance integrated energy storage", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supercapacitors now play an important role in the progress of hybrid and electric vehicles, consumer electronics, and military and space applications. There is a growing demand in developing hybrid supercapacitor systems to overcome the energy density limitations of the current generation of carbon-based supercapacitors. Here, we demonstrate 3D high-performance hybrid supercapacitors and microsupercapacitors based on graphene and MnO2 by rationally designing the electrode microstructure and combining active materials with electrolytes that operate at high voltages. This results in hybrid electrodes with ultrahigh volumetric capacitance of over 1,100 F/cm(3). This corresponds to a specific capacitance of the constituent MnO2 of 1,145 F/g, which is close to the theoretical value of 1,380 F/g. The energy density of the full device varies between 22 and 42 Wh/l depending on the device configuration, which is superior to those of commercially available double-layer supercapacitors, pseudocapacitors, lithium-ion capacitors, and hybrid supercapacitors tested under the same conditions and is comparable to that of lead acid batteries. These hybrid supercapacitors use aqueous electrolytes and are assembled in air without the need for expensive dry rooms required for building today's supercapacitors. Furthermore, we demonstrate a simple technique for the fabrication of supercapacitor arrays for high-voltage applications. These arrays can be integrated with solar cells for efficient energy harvesting and storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2015, "Volume": 112, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4233, "End Page": 4238, "Article Number": null, "DOI": "10.1073/pnas.1420398112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1420398112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352287800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fichtner, S; Wolff, N; Lofink, F; Kienle, L; Wagner, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fichtner, Simon; Wolff, Niklas; Lofink, Fabian; Kienle, Lorenz; Wagner, Bernhard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "AlScN: A III-V semiconductor based ferroelectric", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectric switching is unambiguously demonstrated for the first time in a III-V semiconductor based material: Al1-xScxN-A discovery which could help to satisfy the urgent demand for thin film ferroelectrics with high performance and good technological compatibility with generic semiconductor technology which arises from a multitude of memory, micro/nullo-actuator, and emerging applications based on controlling electrical polarization. The appearance of ferroelectricity in Al1-xScxN can be related to the continuous distortion of the original wurtzite-type crystal structure towards a layered-hexagonal structure with increasing Sc content and tensile strain, which is expected to be extendable to other III-nitride based solid solutions. Coercive fields which are systematically adjustable by more than 3 MV/cm, high remnullt polarizations in excess of 100 mu C/cm(2)-which constitute the first experimental estimate of the previously inaccessible spontaneous polarization in a III-nitride based material, an almost ideally square-like hysteresis resulting in excellent piezoelectric linearity over a wide strain interval from -0.3% to + 0.4% and a paraelectric transition temperature in excess of 600 degrees C are confirmed. This intriguing combination of properties is to our knowledge as of now unprecedented in the field of polycrystalline ferroelectric thin films and promises to significantly advance the commencing integration of ferroelectric functionality to micro-and nullotechnology, while at the same time providing substantial insight to one of the central open questions of the III-nitride semiconductors-that of their spontaneous polarization. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2019, "Volume": 125, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114103, "DOI": "10.1063/1.5084945", "DOI Link": "http://dx.doi.org/10.1063/1.5084945", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462014300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jiagang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite lead-free piezoelectric ceramics", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability of piezoelectric devices to convert mechanical energy to electrical energy and vice versa has inspired remarkable growth in research on piezoelectric materials. However, based on the Restriction of Hazardous Substances legislation, it is necessary to eliminate the lead from currently used piezoelectric ceramics. Together with the increasing market share and improved performance of lead-free piezoelectrics, this growing recognition that the use of lead should be limited in piezoelectric materials has promoted the development of lead-free piezoelectric ceramics. Some devices with excellent performance based on lead-free piezoelectric ceramics have been reported, and their applications are expected to increase in the near future. This perspective provides an overview of key advances related to the structures and properties of lead-free piezoelectrics, including (K,Na)NbO3, BaTiO3, Bi0.5Na0.5TiO3, and BiFeO3. Future prospects are also discussed based on the performances of lead-free piezoelectric materials investigated to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2020, "Volume": 127, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 190901, "DOI": "10.1063/5.0006261", "DOI Link": "http://dx.doi.org/10.1063/5.0006261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536191400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HT; Zhang, XL; Luo, MH; Cao, KS; Lu, YH; Xu, BB; Pan, HG; Tao, K; Jiang, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Haotian; Zhang, Xuanlin; Luo, Minghe; Cao, Keshuang; Lu, Yunhao; Xu, Ben Bin; Pan, Hongge; Tao, Kai; Jiang, Yinzhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amino Acid-Induced Interface Charge Engineering Enables Highly Reversible Zn Anode", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the impressive merits of low-cost and high-safety electrochemical energy storage for aqueous zinc ion batteries, researchers have long struggled against the unresolved issues of dendrite growth and the side reactions of zinc metal anodes. Herein, a new strategy of zinc-electrolyte interface charge engineering induced by amino acid additives is demonstrated for highly reversible zinc plating/stripping. Through electrostatic preferential absorption of positively charged arginine molecules on the surface of the zinc metal anode, a self-adaptive zinc-electrolyte interface is established for the inhibition of water adsorption/hydrogen evolution and the guidance of uniform zinc deposition. Consequently, an ultra-long stable cycling up to 2200 h at a high current density of 5 mA cm(-2) is achieved under an areal capacity of 4 mAh cm(-2). Even cycled at an ultra-high current density of 10 mA cm(-2), 900 h-long stable cycling is still demonstrated, demonstrating the reliable self-adaptive feature of the zinc-electrolyte interface. This work provides a new perspective of interface charge engineering in realizing highly reversible bulk zinc anode that can prompt its practical application in aqueous rechargeable zinc batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 31, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103514, "DOI": "10.1002/adfm.202103514", "DOI Link": "http://dx.doi.org/10.1002/adfm.202103514", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000682426800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, CJ; Qu, B; Provis, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Caijun; Qu, Bo; Provis, John L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress in low-carbon binders", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-carbon binders has been recognized as a means of reducing the carbon footprint of the Portland cement industry, in response to growing global concerns over CO2 emissions from the construction sector. This paper reviews recent progress in the three most attractive low-carbon binders: alkali-activated, carbonate, and belite-ye'elimite-based binders. Alkali-activated binders/materials were reviewed at the past two ICCC congresses, so this paper focuses on some key developments of alkali-activated binders/materials since the last keynote paper was published in 2015. Recent progress on carbonate and belite-ye'elimite-based binders are also reviewed and discussed, as they are attracting more and more attention as essential alternative low-carbon cementitious materials. These classes of binders have a clear role to play in providing a sustainable future for global construction, as part of the available toolkit of cements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 122, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 250, "Article Number": null, "DOI": "10.1016/j.cemconres.2019.05.009", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2019.05.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473380700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, ZF; Xi, SB; Song, JJ; Dou, S; Li, XG; Du, YH; Diao, CZ; Xu, ZCJ; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Zhen-Feng; Xi, Shibo; Song, Jiajia; Dou, Shuo; Li, Xiaogang; Du, Yonghua; Diao, Caozheng; Xu, Zhichuan J.; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing efficient and low-cost electrocatalysts for oxygen evolution reaction is crucial in realizing practical energy systems for sustainable fuel production and energy storage from renewable energy sources. However, the inherent linear scaling relation for most catalytic materials imposes a theoretical overpotential ceiling, limiting the development of efficient electrocatalysts. Herein, using modeled NaxMn3O7 materials, we report an effective strategy to construct better oxygen evolution electrocatalyst through tuning both lattice oxygen reactivity and scaling relation via alkali metal ion mediation. Specifically, the number of Na+ is linked with lattice oxygen reactivity, which is determined by the number of oxygen hole in oxygen lone-pair states formed by native Mn vacancies, governing the barrier symmetry between O-H bond cleavage and O-O bond formation. On the other hand, the presence of Na+ could have specific noncovalent interaction with pendant oxygen in *OOH to overcome the limitation from linear scaling relation, reducing the overpotential ceiling. Combining in situ spectroscopy-based characterization with first-principles calculations, we demonstrate that an intermediate level of Na+ mediation (NaMn3O7) exhibits the optimum oxygen evolution activity. This work provides a new rational recipe to develop highly efficient catalyst towards water oxidation or other oxidative reactions through tuning lattice oxygen reactivity and scaling relation. While water-splitting provides a renewable means to generate fuel, the water-oxidation half-reaction is considered a bottleneck process. Here, authors tune lattice oxygen reactivity and scaling relations via alkali metal ion mediation in NaMn3O7 for oxygen evolution electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3992, "DOI": "10.1038/s41467-021-24182-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24182-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000669944900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, JQ; Zhang, Q; Heitmann, T; Huang, ZL; Chen, KY; Cheng, JG; Wu, WD; Vaknin, D; Sales, BC; McQueeney, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, J-Q; Zhang, Q.; Heitmann, T.; Huang, Zengle; Chen, K. Y.; Cheng, J-G; Wu, Weida; Vaknin, D.; Sales, B. C.; McQueeney, R. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal growth and magnetic structure of MnBi2Te4", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Millimeter-sized MnBi2Te4 single crystals are grown out of a Bi-Te flux and characterized using magnetic, transport, scanning tunneling microscopy, and spectroscopy measurements. The magnetic structure of MnBi2Te4 below T-N is determined by powder and single-crystal neutron diffraction measurements. Below T-N = 24 K, Mn2+ moments order ferromagnetically in the ab plane but antiferromagnetically along the crystallographic c axis. The ordered moment is 4.04(13)mu(B)/Mn at 10 K and aligned along the crystallographic c axis in an A-type antiferromagnetic order. Below T-N, the electrical resistivity drops upon cooling or when going across the metamagnetic transition in increasing magnetic fields. A critical scattering effect is observed in the vicinity of T-N in the temperature dependence of thermal conductivity, indicating strong spin-lattice coupling in this compound. However, no anomaly is observed in the temperature dependence of thermopower around T-N. Fine tuning of the magnetism and/or electronic band structure is needed for the proposed topological properties of this compound. The growth protocol reported in this work might be applied to grow high-quality crystals where the electronic band structure and magnetism can be finely tuned by chemical substitutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2019, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64202, "DOI": "10.1103/PhysRevMaterials.3.064202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.3.064202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470903400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zang, Y; Lu, DQ; Wang, K; Li, B; Peng, P; Lan, YQ; Zang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zang, Ying; Lu, Di-Qiu; Wang, Kun; Li, Bo; Peng, Peng; Lan, Ya-Qian; Zang, Shuang-Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A pyrolysis-free Ni/Fe bimetallic electrocatalyst for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A well-defined catalyst with dual Ni/Fe atomic active sites was created using a pyrolysis-free approach. The as-made catalyst was used for overall electrochemical water splitting in both acidic and alkaline electrolytes with low overpotentials. Catalysts capable of electrochemical overall water splitting in acidic, neutral, and alkaline solution are important materials. This work develops bifunctional catalysts with single atom active sites through a pyrolysis-free route. Starting with a conjugated framework containing Fe sites, the addition of Ni atoms is used to weaken the adsorption of electrochemically generated intermediates, thus leading to more optimized energy level sand enhanced catalytic performance. The pyrolysis-free synthesis also ensured the formation of well-defined active sites within the framework structure, providing ideal platforms to understand the catalytic processes. The as-prepared catalyst exhibits efficient catalytic capability for electrochemical water splitting in both acidic and alkaline electrolytes. At a current density of 10 mA cm(-2), the overpotential for hydrogen evolution and oxygen evolution is 23/201 mV and 42/194 mV in 0.5 M H2SO4 and 1 M KOH, respectively. Our work not only develops a route towards efficient catalysts applicable across a wide range of pH values, it also provides a successful showcase of a model catalyst for in-depth mechanistic insight into electrochemical water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1792, "DOI": "10.1038/s41467-023-37530-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37530-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000960672300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, RH; Zhang, ZT; Tranca, DC; Zhou, SQ; Wang, MC; Adler, P; Liao, ZQ; Liu, F; Sun, Y; Shi, WJ; Zhang, Z; Zschech, E; Mannsfeld, SCB; Felser, C; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Renhao; Zhang, Zhitao; Tranca, Diana C.; Zhou, Shengqiang; Wang, Mingchao; Adler, Peter; Liao, Zhongquan; Liu, Feng; Sun, Yan; Shi, Wujun; Zhang, Zhe; Zschech, Ehrenfried; Mannsfeld, Stefan C. B.; Felser, Claudia; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) have so far been highlighted for their potential roles in catalysis, gas storage and separation. However, the realization of high electrical conductivity (> 10(-3) S cm(-1)) and magnetic ordering in MOFs will afford them new functions for spintronics, which remains relatively unexplored. Here, we demonstrate the synthesis of a two-dimensional MOF by solvothermal methods using perthiolated coronene as a ligand and planar iron-bis(dithiolene) as linkages enabling a full pi-d conjugation. This 2D MOF exhibits a high electrical conductivity of similar to 10 S cm(-1) at 300 K, which decreases upon cooling, suggesting a typical semiconductor nature. Magnetization and Fe-57 Mossbauer experiments reveal the evolution of ferromagnetism within nulloscale magnetic clusters below 20 K, thus evidencing exchange interactions between the intermediate spin S = 3/2 iron(III) centers via the delocalized pi electrons. Our results illustrate that conjugated 2D MOFs have potential as ferromagnetic semiconductors for application in spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2637, "DOI": "10.1038/s41467-018-05141-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05141-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437677800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YY; Zhang, SF; Zhang, JW; Wang, W; Zhu, YL; Hu, J; Yin, G; Wong, K; Fang, C; Wan, CH; Han, XF; Shao, QM; Taniguchi, T; Watanabe, K; Zang, JD; Mao, ZQ; Zhang, XX; Wang, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yingying; Zhang, Senfu; Zhang, Junwei; Wang, Wei; Zhu, Yang Lin; Hu, Jin; Yin, Gen; Wong, Kin; Fang, Chi; Wan, Caihua; Han, Xiufeng; Shao, Qiming; Taniguchi, Takashi; Watanabe, Kenji; Zang, Jiadong; Mao, Zhiqiang; Zhang, Xixiang; Wang, Kang L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neel-type skyrmion in WTe2/Fe3GeTe2 van der Waals heterostructure", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The promise of high-density and low-energy-consumption devices motivates the search for layered structures that stabilize chiral spin textures such as topologically protected skyrmions. At the same time, recently discovered long-range intrinsic magnetic orders in the two-dimensional van der Waals materials provide a new platform for the discovery of novel physics and effects. Here we demonstrate the Dzyaloshinskii-Moriya interaction and Neel-type skyrmions are induced at the WTe2/Fe3GeTe2 interface. Transport measurements show the topological Hall effect in this heterostructure for temperatures below 100 K. Furthermore, Lorentz transmission electron microscopy is used to directly image Neel-type skyrmion lattice and the stripe-like magnetic domain structures as well. The interfacial coupling induced Dzyaloshinskii-Moriya interaction is estimated to have a large energy of 1.0 mJm(-2). This work paves a path towards the skyrmionic devices based on van der Waals layered heterostructures. Strong magnetic interfacial coupling in van der Waals heterostructures provides a new platform for discovering novel physics and effects. Here, the authors report the formation of skyrmion lattice in the WTe2/Fe3GeTe2 van der Waals heterostructure and a Dzyaloshinskii-Moriya interaction with a large energy density of 1.0 mJm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3860, "DOI": "10.1038/s41467-020-17566-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17566-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560400500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Lin, DC; Li, YZ; Chen, GX; Pei, A; Nix, O; Li, YB; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yayuan; Lin, Dingchang; Li, Yuzhang; Chen, Guangxu; Pei, Allen; Nix, Oliver; Li, Yanbin; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The physiochemical properties of the solid-electrolyte interphase, primarily governed by electrolyte composition, have a profound impact on the electrochemical cycling of metallic lithium. Herein, we discover that the effect of nitrate anions on regulating lithium deposition previously known in ether-based electrolytes can be extended to carbonate-based systems, which dramatically alters the nuclei from dendritic to spherical, albeit extremely limited solubility. This is attributed to the preferential reduction of nitrate during solid-electrolyte interphase formation, and the mechanisms behind which are investigated based on the structure, ion-transport properties, and charge transfer kinetics of the modified interfacial environment. To overcome the solubility barrier, a solubility-mediated sustained-release methodology is introduced, in which nitrate nulloparticles are encapsulated in porous polymer gel and can be steadily dissolved during battery operation to maintain a high concentration at the electroplating front. As such, effective dendrite suppression and remarkably enhanced cycling stability are achieved in corrosive carbonate electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 461, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3656, "DOI": "10.1038/s41467-018-06077-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06077-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444014100031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, MX; Yan, DS; Yuan, FP; Jiang, P; Ma, E; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Muxin; Yan, Dingshun; Yuan, Fuping; Jiang, Ping; Ma, Evan; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamically reinforced heterogeneous grain structure prolongs ductility in a medium-entropy alloy with gigapascal yield strength", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ductility, i. e., uniform strain achievable in uniaxial tension, diminishes for materials with very high yield strength. Even for the CrCoNi medium-entropy alloy (MEA), which has a simple facecentered cubic (FCC) structure that would bode well for high ductility, the fine grains processed to achieve gigapascal strength exhaust the strain hardening ability such that, after yielding, the uniform tensile strain is as low as similar to 2%. Here we purposely deploy, in this MEA, a three-level heterogeneous grain structure (HGS) with grain sizes spanning the nullometer to micrometer range, imparting a high yield strength well in excess of 1 GPa. This heterogeneity results from this alloy's low stacking fault energy, which facilitates corner twins in recrystallization and stores deformation twins and stacking faults during tensile straining. After yielding, the elastoplastic transition through load transfer and strain partitioning among grains of different sizes leads to an upturn of the strain hardening rate, and, upon further tensile straining at room temperature, corner twins evolve into nullograins. This dynamically reinforced HGS leads to a sustainable strain hardening rate, a record-wide hysteresis loop in load-unload-reload stress-strain curve and hence high back stresses, and, consequently, a uniform tensile strain of 22%. As such, this HGS achieves, in a singlephase FCC alloy, a strength-ductility combination that would normally require heterogeneous microstructures such as in dual-phase steels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2018, "Volume": 115, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7224, "End Page": 7229, "Article Number": null, "DOI": "10.1073/pnas.1807817115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1807817115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438050900050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Divitini, G; Cacovich, S; Matteocci, F; Cinà, L; Di Carlo, A; Ducati, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Divitini, G.; Cacovich, S.; Matteocci, F.; Cina, L.; Di Carlo, A.; Ducati, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ observation of heat-induced degradation of perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lack of thermal stability of perovskite solar cells is hindering the progress of this technology towards adoption in the consumer market. Different pathways of thermal degradation are activated at different temperatures in these complex nullostructured hybrid composites. Thus, it is essential to explore the thermal response of the mesosuperstructured composite device to engineer materials and operating protocols. Here we produce devices according to four well-established recipes, and characterize their photovoltaic performance as they are heated within the operational range. The devices are analysed using transmission electron microscopy as they are further heated in situ, to monitor changes in morphology and chemical composition. We identify mechanisms for structural and chemical changes, such as iodine and lead migration, which appear to be correlated to the synthesis conditions. In particular, we identify a correlation between exposure of the perovskite layer to air during processing and elemental diffusion during thermal treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 654, "Times Cited, All Databases": 701, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15012, "DOI": "10.1038/NENERGY.2015.12", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2015.12", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394095900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, GY; Chen, TY; Wang, MT; Xia, XX; He, CL; Zheng, XJ; Li, YK; Zhou, D; Lu, XH; Zuo, LJ; Xu, ZK; Chen, HZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Guanyu; Chen, Tianyi; Wang, Mengting; Xia, Xinxin; He, Chengliang; Zheng, Xiangjun; Li, Yaokai; Zhou, Di; Lu, Xinhui; Zuo, Lijian; Xu, Zhikang; Chen, Hongzheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid Additive-Assisted Layer-by-Layer Processing for 19% Efficiency Binary Organic Solar Cells", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Morphology is of great significance to the performance of organic solar cells (OSCs), since appropriate morphology could not only promote the exciton dissociation, but also reduce the charge recombination. In this work, we have developed a solid additive-assisted layer-by-layer (SAA-LBL) processing to fabricate high-efficiency OSCs. By adding the solid additive of fatty acid (FA) into polymer donor PM6 solution, controllable pre-phase separation forms between PM6 and FA. This intermixed morphology facilitates the diffusion of acceptor Y6 into the donor PM6 during the LBL processing, due to the good miscibility and fast-solvation of the FA with chloroform solution dripping. Interestingly, this results in the desired morphology with refined phase-separated domain and vertical phase-separation structure to better balance the charge transport /collection and exciton dissociation. Consequently, the binary single junction OSCs based on PM6:Y6 blend reach champion power conversion efficiency (PCE) of 18.16% with SAA-LBL processing, which can be generally applicable to diverse systems, e.g., the PM6:L8-BO-based devices and thick-film devices. The efficacy of SAA-LBL is confirmed in binary OSCs based on PM6:L8-BO, where record PCEs of 19.02% and 16.44% are realized for devices with 100 and 250 nm active layers, respectively. The work provides a simple but effective way to control the morphology for high-efficiency OSCs and demonstrates the SAA-LBL processing a promising methodology for boosting the industrial manufacturing of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 92, "DOI": "10.1007/s40820-023-01057-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01057-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968816500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boyn, S; Grollier, J; Lecerf, G; Xu, B; Locatelli, N; Fusil, S; Girod, S; Carretero, C; Garcia, K; Xavier, S; Tomas, J; Bellaiche, L; Bibes, M; Barthélémy, A; Saïghi, S; Garcia, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boyn, Soeren; Grollier, Julie; Lecerf, Gwendal; Xu, Bin; Locatelli, Nicolas; Fusil, Stephane; Girod, Stephanie; Carretero, Cecile; Garcia, Karin; Xavier, Stephane; Tomas, Jean; Bellaiche, Laurent; Bibes, Manuel; Barthelemy, Agnes; Saighi, Sylvain; Garcia, Vincent", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Learning through ferroelectric domain dynamics in solid-state synapses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the brain, learning is achieved through the ability of synapses to reconfigure the strength by which they connect neurons (synaptic plasticity). In promising solid-state synapses called memristors, conductance can be finely tuned by voltage pulses and set to evolve according to a biological learning rule called spike-timing-dependent plasticity (STDP). Future neuromorphic architectures will comprise billions of such nullosynapses, which require a clear understanding of the physical mechanisms responsible for plasticity. Here we report on synapses based on ferroelectric tunnel junctions and show that STDP can be harnessed from inhomogeneous polarization switching. Through combined scanning probe imaging, electrical transport and atomic-scale molecular dynamics, we demonstrate that conductance variations can be modelled by the nucleation-dominated reversal of domains. Based on this physical model, our simulations show that arrays of ferroelectric nullosynapses can autonomously learn to recognize patterns in a predictable way, opening the path towards unsupervised learning in spiking neural networks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14736, "DOI": "10.1038/ncomms14736", "DOI Link": "http://dx.doi.org/10.1038/ncomms14736", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398035500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SQ; Li, W; Chen, ZW; Shen, JW; Ge, BH; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Siqi; Li, Wen; Chen, Zhiwei; Shen, Jiawen; Ge, Binghui; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tellurium as a high-performance elemental thermoelectric", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-efficiency thermoelectric materials require a high conductivity. It is known that a large number of degenerate band valleys offers many conducting channels for improving the conductivity without detrimental effects on the other properties explicitly, and therefore, increases thermoelectric performance. In addition to the strategy of converging different bands, many semiconductors provide an inherent band nestification, equally enabling a large number of effective band valley degeneracy. Here we show as an example that a simple elemental semiconductor, tellurium, exhibits a high thermoelectric figure of merit of unity, not only demonstrating the concept but also filling up the high performance gap from 300 to 700 K for elemental thermoelectrics. The concept used here should be applicable in general for thermoelectrics with similar band features.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 457, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10287, "DOI": "10.1038/ncomms10287", "DOI Link": "http://dx.doi.org/10.1038/ncomms10287", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369021100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cohen, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cohen, Seth M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Postsynthetic Renaissance in Porous Solids", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal organic frameworks (MOFs) have rapidly grown into a major area of chemical research over the last two decades. MOFs represent the development of covalent chemistry beyond the molecule and into extended structures. MOFs also present an unprecedented scaffold for performing heterogeneous organic transformations in the solid state, allowing for deliberate and precise preparation of new materials. The development of these transformations has given rise to the postsynthetic renaissance, a suite of methods by which these materials can be transformed in a single-crystal-to-single-crystal manner. Postsynthetic modification, postsynthetic deprotection, postsynthetic exchange, postsynthetic insertion, and postsynthetic polymerization have exploited the unique features of both the organic and inorganic components of MOFs to create crystalline, porous solids of unique complexity and functionality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2017, "Volume": 139, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2855, "End Page": 2863, "Article Number": null, "DOI": "10.1021/jacs.6b11259", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b11259", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395493400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YZ; Li, YK; Xin, X; Wang, YJ; Guo, P; Wang, RL; Wang, BL; Huang, WJ; Sobrido, AJ; Li, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Youzi; Li, YuKe; Xin, Xu; Wang, Yijin; Guo, Peng; Wang, Ruiling; Wang, Bilin; Huang, Wenjing; Sobrido, Ana Jorge; Li, Xuanhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Internal quantum efficiency higher than 100% achieved by combining doping and quantum effects for photocatalytic overall water splitting", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiple exciton generation can potentially improve the efficiency of solar-driven devices, but its demonstration for solar fuel production is rare. Here the authors show that quantum efficiencies above 100% are achievable in a water splitting photocatalyst, implying the presence of multiple exciton generation effects. Multiple exciton generation (MEG), where two or more electron-hole pairs are produced from the absorption of one high-energy photon, could increase the efficiency of light absorbing devices. However, demonstrations of the effect are still scarce in photocatalytic hydrogen production. Moreover, many photocatalytic systems for overall water splitting suffer from poor charge carrier separation. Here we show that a CdTe quantum dot/vanadium-doped indium sulphide (CdTe/V-In2S3) photocatalyst has a built-in electric field and cascade energy band structure sufficient to effectively extract excitons and separate carriers, allowing MEG to be exploited for hydrogen production. We achieve a tunable energy band structure through quantum effects in CdTe and doping engineering of V-In2S3, which induces a 14-fold enhancement in the CdTe/V-In2S3 interfacial built-in electric field intensity relative to pristine CdTe/V-In2S3. We report an internal quantum efficiency of 114% at 350 nm for photocatalytic hydrogen production, demonstrating the utilization of MEG effects. The solar-to-hydrogen efficiency is 1.31%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 504, "End Page": 514, "Article Number": null, "DOI": "10.1038/s41560-023-01242-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01242-7", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000966632900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Qin, Z; Liang, ZZ; Meng, DJ; Xu, HY; Smith, DR; Liu, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yu; Qin, Zheng; Liang, Zhongzhu; Meng, Dejia; Xu, Haiyang; Smith, David R.; Liu, Yichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-broadband metamaterial absorbers from long to very long infrared regime", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broadband metamaterials absorbers with high absorption, ultrathin thickness and easy configurations are in great demand for many potential applications. In this paper, we first analyse the coupling resonullces in a Ti/Ge/Ti three-layer absorber, which can realise broadband absorption from 8 to 12 mu m. Then we experimentally demonstrate two types of absorbers based on the Ti/Ge/Si3N4/Ti configuration. By taking advantage of coupling surface plasmon resonullces and intrinsic absorption of lossy material Si3N4, the average absorptions of two types of absorbers achieve almost 95% from 8 to 14 mu m (experiment result: 78% from 6.5 to 13.5 mu m). In order to expand the absorption bandwidth, we further propose two Ti/Si/SiO2/Ti absorbers which can absorb 92% and 87% of ultra-broadband light in the 14-30 mu m and 8-30 mu m spectral range, respectively. Our findings establish general and systematic strategies for guiding the design of metamaterial absorbers with excellent broadband absorption and pave the way for enhancing the optical performance in applications of infrared thermal emitters, imaging and photodetectors. Ultra-broadband metamaterials absorbers with high absorption, ultrathin thickness and easy configurations are designed and demonstrated, which pave the way for enhancing the optical performance in applications of infrared thermal emitters, imaging and photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 138, "DOI": "10.1038/s41377-021-00577-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00577-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672523500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, DZ; Tang, C; Zhi, X; Johannessen, B; Slattery, A; Chern, S; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Dazhi; Tang, Cheng; Zhi, Xing; Johannessen, Bernt; Slattery, Ashley; Chern, Shane; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inter-Metal Interaction with a Threshold Effect in NiCu Dual-Atom Catalysts for CO2 Electroreduction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dual-atom catalysts (DACs) have become an emerging platform to provide more flexible active sites for electrocatalytic reactions with multi-electron/proton transfer, such as the CO2 reduction reaction (CRR). However, the introduction of asymmetric dual-atom sites causes complexity in structure, leaving an incomprehensive understanding of the inter-metal interaction and catalytic mechanism. Taking NiCu DACs as an example, herein, a more rational structural model is proposed, and the distance-dependent inter-metal interaction is investigated by combining theoretical simulations and experiments, including density functional theory computation, aberration-corrected transmission electron microscopy, synchrotron-based X-ray absorption fine structure, and Monte Carlo experiments. A distance threshold around 5.3 angstrom between adjacent Ni-N-4 and Cu-N-4 moieties is revealed to trigger effective electronic regulation and boost CRR performance on both selectivity and activity. A universal macro-descriptor rigorously correlating the inter-metal distance and intrinsic material features (e.g., metal loading and thickness) is established to guide the rational design and synthesis of advanced DACs. This study highlights the significance of identifying the inter-metal interaction in DACs, and helps bridge the gap between theoretical study and experimental synthesis of atomically dispersed catalysts with highly correlated active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209386", "DOI Link": "http://dx.doi.org/10.1002/adma.202209386", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928713500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, J; Nabae, Y; Hayakawa, T; Kakimoto, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jisung; Nabae, Yuta; Hayakawa, Teruaki; Kakimoto, Masa-aki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Selective Two-Electron Oxygen Reduction Catalyzed by Mesoporous Nitrogen-Doped Carbon", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of oxygen molecules can produce H2O2, which is an important chemical for a green and sustainable society; therefore, the development of catalysts for this reaction is necessary. We propose mesoporous nitrogen-doped carbon prepared from (1-methyl-1H-pyrrole-2-yl)methanol in the presence of a mesoporous SiO2 template (KIT-6). The nitrogen content of the resulting carbon can be controlled in the range of 0-10 at. % and all prepared samples have well-ordered mesopores with diameters of 3.4-4.0 nm. Electrochemical studies indicate the present materials have high catalytic activities with high selectivity toward H2O2 over 90%. Such high selectivity toward H2O2 is probably due to good mass transport in the catalyst layer, which is enhanced by the mesoporous structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3749, "End Page": 3754, "Article Number": null, "DOI": "10.1021/cs5008206", "DOI Link": "http://dx.doi.org/10.1021/cs5008206", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345735200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Zhang, XL; Zhang, YY; Wang, DF; Bao, DL; Que, YD; Xiao, WD; Du, SX; Ouyang, M; Pantelides, ST; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hui; Zhang, Xian-Li; Zhang, Yu-Yang; Wang, Dongfei; Bao, De-Liang; Que, Yande; Xiao, Wende; Du, Shixuan; Ouyang, Min; Pantelides, Sokrates T.; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically precise, custom-design origami graphene nullostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The construction of atomically precise carbon nullostructures holds promise for developing materials for scientific study and nullotechnology applications. Here, we show that graphene origami is an efficient way to convert graphene into atomically precise, complex nullostructures. By scanning tunneling microscope manipulation at low temperature, we repeatedly fold and unfold graphene nulloislands (GNIs) along an arbitrarily chosen direction. A bilayer graphene stack featuring a tunable twist angle and a tubular edge connection between the layers is formed. Folding single-crystal GNIs creates tubular edges with specified chirality and one-dimensional electronic features similar to those of carbon nullotubes, whereas folding bicrystal GNIs creates well-defined intramolecular junctions. Both origami structural models and electronic band structures are computed to complement analysis of the experimental results. The present atomically precise graphene origami provides a platform for constructing carbon nullostructures with engineered quantum properties and, ultimately, quantum machines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2019, "Volume": 365, "Issue": 6457, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1036, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax7864", "DOI Link": "http://dx.doi.org/10.1126/science.aax7864", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000484732700049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duduta, M; Hajiesmaili, E; Zhao, H; Wood, RJ; Clarke, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duduta, Mihai; Hajiesmaili, Ehsan; Zhao, Huichan; Wood, Robert J.; Clarke, David R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing the potential of dielectric elastomer artificial muscles", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft robotics represents a new set of technologies aimed at operating in natural environments and near the human body. To interact with their environment, soft robots require artificial muscles to actuate movement. These artificial muscles need to be as strong, fast, and robust as their natural counterparts. Dielectric elastomer actuators (DEAs) are promising soft transducers, but typically exhibit low output forces and low energy densities when used without rigid supports. Here, we report a soft composite DEA made of strain-stiffening elastomers and carbon nullotube electrodes, which demonstrates a peak energy density of 19.8 J/kg. The result is close to the upper limit for natural muscle (0.4-40 J/kg), making these DEAs the highest-performance electrically driven soft artificial muscles demonstrated to date. To obtain high forces and displacements, we used low-density, ultrathin carbon nullotube electrodes which can sustain applied electric fields upward of 100 V/mu m without suffering from dielectric breakdown. Potential applications include prosthetics, surgical robots, and wearable devices, as well as soft robots capable of locomotion and manipulation in natural or human-centric environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2019, "Volume": 116, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2476, "End Page": 2481, "Article Number": null, "DOI": "10.1073/pnas.1815053116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1815053116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458365600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XL; Wu, YY; Wu, ZF; Han, Y; Xu, SG; Wang, L; Ye, WG; Han, TY; He, YH; Cai, Y; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiaolong; Wu, Yingying; Wu, Zefei; Han, Yu; Xu, Shuigang; Wang, Lin; Ye, Weiguang; Han, Tianyi; He, Yuheng; Cai, Yuan; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-quality sandwiched black phosphorus heterostructure and its quantum oscillations", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials such as graphene and transition metal dichalcogenides have attracted great attention because of their rich physics and potential applications in next-generation nulloelectronic devices. The family of two-dimensional materials was recently joined by atomically thin black phosphorus which possesses high theoretical mobility and tunable bandgap structure. However, degradation of properties under atmospheric conditions and high-density charge traps in black phosphorus have largely limited its actual mobility thus hindering its future applications. Here, we report the fabrication of stable sandwiched heterostructures by encapsulating atomically thin black phosphorus between hexagonal boron nitride layers to realize ultra-clean interfaces that allow a high field-effect mobility of similar to 1,350 cm(2)V(-1) s(-1) at room temperature and on-off ratios exceeding 105. At low temperatures, the mobility even reaches similar to 2,700 cm(2)V(-1) s(-1) and quantum oscillations in black phosphorus two-dimensional hole gas are observed at low magnetic fields. Importantly, the sandwiched heterostructures ensure that the quality of black phosphorus remains high under ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7315, "DOI": "10.1038/ncomms8315", "DOI Link": "http://dx.doi.org/10.1038/ncomms8315", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357171600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZJ; Zhang, YW; Wu, X; Huang, L; Li, DS; Fan, W; Han, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhanjun; Zhang, Yuanwei; Wu, Xiang; Huang, Ling; Li, Dongsheng; Fan, Wei; Han, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Aqueous-Phase Synthesis of Sub-10 nm Luminous Pearls with Enhanced in Vivo Renewable Near-Infrared Persistent Luminescence", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near-infrared (NIR) persistent luminescence nulloparticles (PLNPs), possessing unique NIR PL properties, have recently emerged as important materials for a wide variety of applications in chemistry and biology for which they must endure high temperature solid-state annealing reactions and subsequent complicated physical post-treatments, Herein,we report, on a first direct aqueous-phase Chemical synthesis route to NIR PLNPs and present their enhanced it vivo renewable NIR PL. Our method leads to monodisperse PLNPs as small - as ca. 8 nm. Such sub-10 nm nullocrystals are readily dispersed and functionalized, and can form stable colloidal solutions in aqueous solution and cell culture medium for biological applications. Under biotissue-penetrable rearlight excitation, we found that such nullocrystals possess superior renewable PL photoluminescence in vitro and in vivo compared to their larger counterparts currently made by existing methods. We believe that this solid-state-reaction-free chemical approach overcomes the current key, roadblock in regard to PLNP development, and thus will pave the way to broad use of these advanced miniature luminous pearls in photonics and biophotonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2015, "Volume": 137, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5304, "End Page": 5307, "Article Number": null, "DOI": "10.1021/jacs.5b00872", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b00872", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353931500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, DH; Pan, ZX; Cuiuri, D; Li, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Donghong; Pan, Zengxi; Cuiuri, Dominic; Li, Huijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A multi-bead overlapping model for robotic wire and arc additive manufacturing (WAAM)", "Source Title": "ROBOTICS AND COMPUTER-INTEGRATED MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wire and arc additive manufacturing (WAAM) is a promising alternative to traditional subtractive manufacturing for fabricating large aerospace components that feature high buy-to-fly ratio. Since the WAAM process builds up a part with complex geometry through the deposition of weld beads on a layer-by-layer basis, it is important to model the geometry of a single weld bead as well as the multi-bead overlapping process in order to achieve high surface quality and dimensional accuracy of the fabricated parts. This study firstly builds models for a single weld bead through various curve fitting methods. The experimental results show that both parabola and cosine functions accurately represent the bead profile. The overlapping principle is then detailed to model the geometry of multiple beads overlapping together. The tangent overlapping model (TOM) is established and the concept of the critical centre distance for stable multi-bead overlapping processes is presented. The proposed TOM is shown to provide a much better approximation to the experimental measurements when compared with the traditional flat-top overlapping model (FOM). This is critical in process planning to achieve better geometry accuracy and material efficiency in additive manufacturing. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 31, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 110, "Article Number": null, "DOI": "10.1016/j.rcim.2014.08.008", "DOI Link": "http://dx.doi.org/10.1016/j.rcim.2014.08.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343622500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deringer, VL; Csányi, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deringer, Volker L.; Csanyi, Gabor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning based interatomic potential for amorphous carbon", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce a Gaussian approximation potential (GAP) for atomistic simulations of liquid and amorphous elemental carbon. Based on a machine learning representation of the density-functional theory (DFT) potentialenergy surface, such interatomic potentials enable materials simulations with close- to DFT accuracy but at much lower computational cost. We first determine the maximum accuracy that any finite-range potential can achieve in carbon structures; then, using a hierarchical set of two-, three-, and many-body structural descriptors, we construct a GAP model that can indeed reach the target accuracy. The potential yields accurate energetic and structural properties over a wide range of densities; it also correctly captures the structure of the liquid phases, at variance with a state-of-the-art empirical potential. Exemplary applications of the GAP model to surfaces of diamondlike tetrahedral amorphous carbon (ta-C) are presented, including an estimate of the amorphous material's surface energy and simulations of high-temperature surface reconstructions (graphitization). The presented interatomic potential appears to be promising for realistic and accurate simulations of nulloscale amorphous carbon structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 494, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2017, "Volume": 95, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 94203, "DOI": "10.1103/PhysRevB.95.094203", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.094203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395995200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, CB; Li, NX; Wang, MR; Wang, XM; Gu, HY; Chen, B; Zhang, Z; Ni, ZY; Jiao, HY; Xu, WZ; Shi, ZF; Yan, YF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Chengbin; Li, Nengxu; Wang, Mengru; Wang, Xiaoming; Gu, Hangyu; Chen, Bo; Zhang, Zhao; Ni, Zhenyi; Jiao, Haoyang; Xu, Wenzhan; Shi, Zhifang; Yan, Yanfa; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-chelating hole-transport layers for efficient and stable perovskite minimodules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The defective bottom interfaces of perovskites and hole-transport layers (HTLs) limit the performance of p-i-n structure perovskite solar cells. We report that the addition of lead chelation molecules into HTLs can strongly interact with lead(II) ion (Pb2+), resulting in a reduced amorphous region in perovskites near HTLs and a passivated perovskite bottom surface. The minimodule with an aperture area of 26.9 square centimeters has a power conversion efficiency (PCE) of 21.8% (stabilized at 21.1%) that is certified by the National Renewable Energy Laboratory (NREL), which corresponds to a minimal small-cell efficiency of 24.6% (stabilized 24.1%) throughout the module area. Small-area cells and large-area minimodules with lead chelation molecules in HTLs had a light soaking stability of 3010 and 2130 hours, respectively, at an efficiency loss of 10% from the initial value under 1-sun illumination and open-circuit voltage conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2023, "Volume": 380, "Issue": 6647, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 823, "End Page": 829, "Article Number": null, "DOI": "10.1126/science.ade9463", "DOI Link": "http://dx.doi.org/10.1126/science.ade9463", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001476900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuo, JJ; Kang, SD; Imasato, K; Tamaki, H; Ohno, S; Kanno, T; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuo, Jimmy Jiahong; Kang, Stephen Dongmin; Imasato, Kazuki; Tamaki, Hiromasa; Ohno, Saneyuki; Kanno, Tsutomu; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain boundary dominated charge transport in Mg3Sb2-based compounds", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermally activated mobility near room temperature is a signature of detrimental scattering that limits the efficiency and figure-of-merit zT in thermoelectric semiconductors. This effect has been observed dramatically in Mg3Sb2-based compounds, but also to a lesser extent in other thermoelectric compounds. Processing samples differently or adding impurities such that this effect is less noticeable produces materials with a higher zT. Experiments suggest that the behavior is related to grain boundaries, but impurity scattering has also been proposed. However, conventional models using Matthissen's rule are not able to explain the dramatic change in the temperature dependency of conductivity or drift mobility which is observed in Mg3Sb2-based compounds. We find that it is essential to consider the grain boundary region as an effectively separate phase rather than a scattering center, taking into account the weaker screening in semiconductors compared with classical metals. By modeling a grain boundary phase with a band offset, we successfully reproduce the experimentally observed conductivity versus temperature and thermopower versus conductivity relations, which indicate an improved description of transport. The model shows good agreement with measured grain size dependencies of conductivity, opening up avenues for quantitatively engineering materials with similar behavior. Model estimates predict room for 460% improvement in the room temperature zT of Mg3.2Sb1.5Bi0.49Te0.01 if the grain boundary resistance could be eliminated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 429, "End Page": 434, "Article Number": null, "DOI": "10.1039/c7ee03326e", "DOI Link": "http://dx.doi.org/10.1039/c7ee03326e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425283400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YZ; Cui, MH; Li, SS; Sun, CJ; Huang, YM; Wei, JL; Zhang, L; Lv, M; Qin, CC; Liu, YF; Yuan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuanzhi; Cui, Minghuan; Li, Saisai; Sun, Changjiu; Huang, Yanmin; Wei, Junli; Zhang, Li; Lv, Mei; Qin, Chaochao; Liu, Yufang; Yuan, Mingjian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reducing the impact of Auger recombination in quasi-2D perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid Auger recombination represents an important challenge faced by quasi-2D perovskites, which induces resulting perovskite light-emitting diodes' (PeLEDs) efficiency roll-off. In principle, Auger recombination rate is proportional to materials' exciton binding energy (Eb). Thus, Auger recombination can be suppressed by reducing the corresponding materials' Eb. Here, a polar molecule, p-fluorophenethylammonium, is employed to generate quasi-2D perovskites with reduced Eb. Recombination kinetics reveal the Auger recombination rate does decrease to one-order-of magnitude lower compared to its PEA(+) analogues. After effective passivation, nonradiative recombination is greatly suppressed, which enables resulting films to exhibit outstanding photoluminescence quantum yields in a broad range of excitation density. We herein demonstrate the very efficient PeLEDs with a peak external quantum efficiency of 20.36%. More importantly, devices exhibit a record luminullce of 82,480 cd m(-2) due to the suppressed efficiency roll-off, which represent one of the brightest visible PeLEDs yet.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 336, "DOI": "10.1038/s41467-020-20555-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20555-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662812500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HP; Sun, B; Gao, TT; Li, H; Ren, YQ; Zhou, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Huapeng; Sun, Bin; Gao, Tingting; Li, Huan; Ren, Yongqiang; Zhou, Guowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti3C2 MXene co-catalyst assembled with mesoporous TiO2 for boosting photocatalytic activity of methyl orange degradation and hydrogen production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic degradation and hydrogen production using solar energy through semiconductor photocatalysts are deemed to be a powerful approach for solving environmental and energy crisis. However, the biggest challenge in photocatalysis is the efficient separation of photo-induced carriers. To this end, we report that the mesoporous TiO2 nulloparticles are anchored on highly conductive Ti3C2 MXene co-catalyst by electrostatic self-assembly strategy. The constructed mesoporous TiO2/Ti3C2 composites display that the mesoporous TiO2 nulloparticles are uniformly distributed on the surface of layer structured Ti3C2 nullosheets. More importantly, the as-obtained mesoporous TiO2/Ti3C2 composites reveal the significantly enhanced light absorption performance, photo-induced carriers separation and transfer ability, thus boosting the photocatalytic activity. The photocatalytic methyl orange degradation efficiency of mesoporous TiO2/Ti3C2 composite with an optimized Ti3C2 content (3 wt%) can reach 99.6% within 40 min. The capture experiments of active species confirm that the center dot O-2 and center dot OH play major role in photocatalytic degradation process. Furthermore, the optimized mesoporous TiO2/Ti3C2 composite also shows an excellent photocatalytic H-2 production rate of 218.85 mu mol g(-1) h(-1), resulting in a 5.6 times activity as compared with the pristine mesoporous TiO2 nulloparticles. This study demonstrates that the MXene family materials can be applied as highly efficient noble-metal-free co-catalysts in the field of photocatalysis. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 461, "End Page": 471, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63915-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63915-3", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745616200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CL; Hu, H; Yang, MF; Pei, ZY; Zhou, Q; Ren, X; Liu, B; Liu, DW; Zeng, XG; Zhang, GL; Zhang, HB; Liu, JJ; Wang, Q; Deng, XJ; Xiao, CJ; Yao, YG; Xue, DS; Zuo, W; Su, Y; Wen, WB; Ouyang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chunlai; Hu, Hao; Yang, Meng-Fei; Pei, Zhao-Yu; Zhou, Qin; Ren, Xin; Liu, Bin; Liu, Dawei; Zeng, Xingguo; Zhang, Guangliang; Zhang, Hongbo; Liu, Jianjun; Wang, Qiong; Deng, Xiangjin; Xiao, Caijin; Yao, Yonggang; Xue, Dingshuai; Zuo, Wei; Su, Yan; Wen, Weibin; Ouyang, Ziyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characteristics of the lunar samples returned by the Chang'E-5 mission", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The CE-5 sample is consistent with weathered mare basalts in mineralogy and petrochemistry, and is classified as low-Ti/low-Al/low-K type with lower REE (rare earth element) contents than KREEP (potassium, rare earth element, and phosphorus). This new sample characterized by high FeO and low Mg index could represent a new lunar basalt. Forty-five years after the Apollo and Luna missions returned lunar samples, China's Chang'E-5 (CE-5) mission collected new samples from the mid-latitude region in the northeastern Oceanus Procellarum of the Moon. Our study shows that 95% of CE-5 lunar soil sizes are found to be within the range of 1.40-9.35 mu m, while 95% of the soils by mass are within the size range of 4.84-432.27 mu m. The bulk density, true density and specific surface area of CE-5 soils are 1.2387 g/cm(3), 3.1952 g/cm(3) and 0.56 m(2)/g, respectively. Fragments from the CE-5 regolith are classified into igneous clasts (mostly basalt), agglutinate and glass. A few breccias were also found. The minerals and compositions of CE-5 soils are consistent with mare basalts and can be classified as low-Ti/low-Al/low-K type with lower rare-earth-element contents than materials rich in potassium, rare earth element and phosphorus. CE-5 soils have high FeO and low Mg index, which could represent a new class of basalt.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2022, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab188", "DOI": "10.1093/nsr/nwab188", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab188", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753113800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Borfecchia, E; Lomachenko, KA; Giordanino, F; Falsig, H; Beato, P; Soldatov, AV; Bordiga, S; Lamberti, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Borfecchia, E.; Lomachenko, K. A.; Giordanino, F.; Falsig, H.; Beato, P.; Soldatov, A. V.; Bordiga, S.; Lamberti, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revisiting the nature of Cu sites in the activated Cu-SSZ-13 catalyst for SCR reaction", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu-SSZ-13 is a highly active NH3-SCR catalyst for the abatement of harmful nitrogen oxides (NOx, x = 1, 2) from the exhausts of lean-burn engines. The study of Cu-speciation occurring upon thermal dehydration is a key step for the understanding of the enhanced catalytic properties of this material and for identifying the SCR active sites and their redox capability. Herein, we combined FTIR, X-ray absorption (XAS) and emission (XES) spectroscopies with DFT computational analysis to elucidate the nature and location of the most abundant Cu sites in the activated catalyst. Different Cu species have been found to be dominullt as a function of the dehydration temperature and conditions. Data analysis revealed that the dehydration process of Cu cations is essentially completed at 250 degrees C, with the formation of dehydrated [CuOH](+) species hosted in close proximity to 1-Al sites in both d6r and 8r units of the SSZ-13 matrix. These species persist at higher temperatures only if a certain amount of O-2 is present in the gas feed, while under inert conditions they undergo virtually total self-reduction as a consequence of an OH extra-ligand loss, resulting in bi-coordinated bare Cu+ cations. Synchrotron characterization supported by computational analysis allowed an unprecedented quantitative refinement of the local environment and structural parameters of these Cu(II) and Cu(I) species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 548, "End Page": 563, "Article Number": null, "DOI": "10.1039/c4sc02907k", "DOI Link": "http://dx.doi.org/10.1039/c4sc02907k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345901600065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Li, J; Lu, JW; Ding, M; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ying; Li, Jie; Lu, Jiawei; Ding, Meng; Chen, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and properties of Poly(vinyl alcohol) hydrogels with high strength and toughness", "Source Title": "POLYMER TESTING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "PVA hydrogels with high strength and toughness are fabricated by dual physical and chemical cross-linking. The best comprehensive mechanical properties can be achieved by reaction at room temperature followed with freeze-thaw and annealing treatment. Besides, the mechanical properties of PVA hydrogel increased first and then decreased with the increase of molecular weight or mass fraction. By changing the reaction solvent, the mechanical properties of PVA hydrogel could also be effectively adjusted. Therefore, the influences of various factors on the mechanical properties of PVA hydrogel can be obtained.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107516, "DOI": "10.1016/j.polymertesting.2022.107516", "DOI Link": "http://dx.doi.org/10.1016/j.polymertesting.2022.107516", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765513200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, SM; Liu, Y; Chen, XY; Wang, SH; Zhou, YS; Lin, L; Xie, YN; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Simiao; Liu, Ying; Chen, Xiangyu; Wang, Sihong; Zhou, Yu Sheng; Lin, Long; Xie, Yannull; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of freestanding triboelectric-layer-based nullogenerators", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerator technology is emerging as a promising candidate for mechanical energy harvesting from ambient environment. Freestanding triboelectric-layer-based nullogenerators (FTENGs) are one of the fundamental operation modes with many advantages. In this paper, the first theoretical model of FTENGs is proposed with thorough analysis of their operation principle. Both contact-mode and sliding-mode FTENGs are discussed to fully uncover their unique characteristics. Contact-mode FTENGs have superior linearity, which is highly beneficial for both energy-harvesting and self-powered sensing applications. Sliding-mode FTENGs have two subcategories based on the material of their freestanding layer. For both of the two subcategories, the coupling effect of the height of the freestanding layer and the electrode gap on their output characteristics are discussed in detail to obtain the strategy for their structural optimization. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 12, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 760, "End Page": 774, "Article Number": null, "DOI": "10.1016/j.nulloen.2015.01.013", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2015.01.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354767500080", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Au, H; Alptekin, H; Jensen, ACS; Olsson, E; O'Keefe, CA; Smith, T; Crespo-Ribadeneyra, M; Headen, TF; Grey, CP; Cai, Q; Drew, AJ; Titirici, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Au, Heather; Alptekin, Hande; Jensen, Anders C. S.; Olsson, Emilia; O'Keefe, Christopher A.; Smith, Thomas; Crespo-Ribadeneyra, Maria; Headen, Thomas F.; Grey, Clare P.; Cai, Qiong; Drew, Alan J.; Titirici, Maria-Magdalena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A revised mechanistic model for sodium insertion in hard carbons", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hard carbons have shown considerable promise as anodes for emerging sodium-ion battery technologies. Current understanding of sodium-storage behaviour in hard carbons attributes capacity to filling of graphitic interlayers and pores, and adsorption at defects, although there is still considerable debate regarding the voltages at which these mechanisms occur. Here,ex situ(23)Na solid-state NMR and total scattering studies on a systematically tuned series of hard carbons revealed the formation of increasingly metallic sodium clusters in direct correlation to the growing pore size, occurring only in samples which exhibited a low voltage plateau. Combining experimental results with DFT calculations, we propose a revised mechanistic model in which sodium ions store first simultaneously and continuously at defects, within interlayers and on pore surfaces. Once these higher energy binding sites are filled, pore filling occurs during the plateau region, where the densely confined sodium takes on a greater degree of metallicity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2020, "Volume": 13, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3469, "End Page": 3479, "Article Number": null, "DOI": "10.1039/d0ee01363c", "DOI Link": "http://dx.doi.org/10.1039/d0ee01363c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579868500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, GX; Zhu, W; Lou, Y; Ma, J; Yao, WQ; Zong, RL; Zhu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Guoxiang; Zhu, Wei; Lou, Yang; Ma, Jun; Yao, Wenqing; Zong, Ruilong; Zhu, Yongfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encapsulate α-MnO2 nullofiber within graphene layer to tune surface electronic structure for efficient ozone decomposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Major challenges encountered when developing manganese-based materials for ozone decomposition are related to the low stability and water inactivation. To solve these problems, a hierarchical structure consisted of graphene encapsulating alpha -MnO2 nullofiber was developed. The optimized catalyst exhibited a stable ozone conversion efficiency of 80% and excellent stability over 100h under a relative humidity (RH) of 20%. Even though the RH increased to 50%, the ozone conversion also reached 70%, well beyond the performance of alpha -MnO2 nullofiber. Here, surface graphite carbon was activated by capturing the electron from inner unsaturated Mn atoms. The excellent stability originated from the moderate local work function, which compromised the reaction barriers in the adsorption of ozone molecule and the desorption of the intermediate oxygen species. The hydrophobic graphene shells hindered the chemisorption of water vapour, consequently enhanced its water resistance. This work offered insights for catalyst design and would promote the practical application of manganese-based catalysts in ozone decomposition. Ozone is a major air pollutant, but its elimination is challenging. Here the authors encapsulate defective alpha -MnO2 nullofiber within ultrathin graphene shells to construct a hierarchical MnO2@graphene catalyst for ozone decomposition that possesses high activity and stability under humid conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4152, "DOI": "10.1038/s41467-021-24424-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24424-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672715100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, XL; Chen, L; Liu, JY; Haller, S; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Xiaoli; Chen, Long; Liu, Jingyuan; Haller, Servane; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current rechargeable batteries generally display limited cycle life and slow electrode kinetics and contain environmentally unfriendly components. Furthermore, their operation depends on the redox reactions of metal elements. We present an original battery system that depends on the redox of I-/I-3(-) couple in liquid cathode and the reversible enolization in polyimide anode, accompanied by Li+ (or Na+) diffusion between cathode and anode through a Li+/Na+ exchange polymer membrane. There are no metal element-based redox reactions in this battery, and Li+ (or Na+) is only used for charge transfer. Moreover, the components (electrolyte/electrode) of this system are environment-friendly. Both electrodes are demonstrated to have very fast kinetics, which gives the battery a supercapacitor-like high power. It can even be cycled 50,000 times when operated within the electrochemical window of 0 to 1.6 V. Such a system might shed light on the design of high-safety and low-cost batteries for grid-scale energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501038", "DOI": "10.1126/sciadv.1501038", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376972900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leng, Z; Padhan, RK; Sreeram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leng, Zhen; Padhan, Rabindra Kumar; Sreeram, Anulld", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Production of a sustainable paving material through chemical recycling of waste PET into crumb rubber modified asphalt", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic materials such as polyethylene terephthalate (PET) are extensively used in manufacturing drinking bottles, food packaging and many other forms of plastic products. However, the inappropriate disposal of large amount of PET waste may cause severe environmental problems. Using PET derived products as a performance-enhancing additive for asphalt can be one of the alternatives to recycle and reuse this waste material. Similarly, disposal of waste vehicle tyres is also a challenging environmental problem. Research has shown that the use of crumb rubber (CR) from waste tyres in asphalt helps improve some of its rheological properties but is often plagued with other concerns such as low storage stability. The main objective of this study is to investigate the feasibility of using the waste PET additives, derived through an aminolysis process, to improve the storage stability and rheological performance of crumb rubber modified asphalt (CRMA). Both the storage stability, and rheological and chemical properties of the asphalt binders collectively modified with PET additives and CR were investigated. It was found that the incorporation of PET based additives to CRMA improved the storage stability, rutting and fatigue resistances, and increased the rotational viscosity (RV) of the modified binders. Overall, the results indicated that the collective usage of waste PET derived additives and scrap tyre rubber in asphalt not only helps recycle waste plastic and rubber, but also improves the engineering properties of asphalt pavement. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2018, "Volume": 180, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 682, "End Page": 688, "Article Number": null, "DOI": "10.1016/j.jclepro.2018.01.171", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2018.01.171", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427218700060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JQ; Wang, ZC; Dai, HJ; Wang, QQ; Yang, R; Yu, H; Liao, MZ; Zhang, J; Chen, W; Wei, Z; Li, N; Du, LJ; Shi, DX; Wang, WL; Zhang, LX; Jiang, Y; Zhang, GY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jianqi; Wang, Zhi-Chang; Dai, Huijia; Wang, Qinqin; Yang, Rong; Yu, Hua; Liao, Mengzhou; Zhang, Jing; Chen, Wei; Wei, Zheng; Li, Na; Du, Luojun; Shi, Dongxia; Wang, Wenlong; Zhang, Lixin; Jiang, Ying; Zhang, Guangyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boundary activated hydrogen evolution reaction on monolayer MoS2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, monolayer molybdenum disulphide (MoS2) has emerged as a promising and non-precious electrocatalyst for hydrogen evolution reaction. However, its performance is largely limited by the low density and poor reactivity of active sites within its basal plane. Here, we report that domain boundaries in the basal plane of monolayer MoS2 can greatly enhance its hydrogen evolution reaction performance by serving as active sites. Two types of effective domain boundaries, the 2H-2H domain boundaries and the 2H-1T phase boundaries, were investigated. Superior hydrogen evolution reaction catalytic activity, long-term stability and universality in both acidic and alkaline conditions were achieved based on a multi-hierarchy design of these two types of domain boundaries. We further demonstrate that such superior catalysts are feasible at a large scale by applying this multi-hierarchy design of domain boundaries to wafer-scale monolayer MoS2 films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 367, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1348, "DOI": "10.1038/s41467-019-09269-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09269-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461996300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dang, Q; Lin, HP; Fan, ZL; Ma, L; Shao, Q; Ji, YJ; Zheng, FF; Geng, SZ; Yang, SZ; Kong, NN; Zhu, WX; Li, YY; Liao, F; Huang, XQ; Shao, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dang, Qian; Lin, Haiping; Fan, Zhenglong; Ma, Lu; Shao, Qi; Ji, Yujin; Zheng, Fangfang; Geng, Shize; Yang, Shi-Ze; Kong, Ningning; Zhu, Wenxiang; Li, Youyong; Liao, Fan; Huang, Xiaoqing; Shao, Mingwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iridium metallene oxide for acidic oxygen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring new materials is essential in the field of material science. Especially, searching for optimal materials with utmost atomic utilization, ideal activities and desirable stability for catalytic applications requires smart design of materials' structures. Herein, we report iridium metallene oxide: 1 T phase-iridium dioxide (IrO2) by a synthetic strategy combining mechanochemistry and thermal treatment in a strong alkaline medium. This material demonstrates high activity for oxygen evolution reaction with a low overpotential of 197 millivolt in acidic electrolyte at 10 milliamperes per geometric square centimeter (mA cm(geo)(-2)). Together, it achieves high turnover frequencies of 4.2 s(UPD)(-1) (3.0 s(BET)(-1)) at 1.50 V vs. reversible hydrogen electrode. Furthermore, 1T-IrO2 also shows little degradation after 126 hours chronopotentiometry measurement under the high current density of 250 mA cm(geo)(-2) in proton exchange membrane device. Theoretical calculations reveal that the active site of Ir in 1T-IrO2 provides an optimal free energy uphill in *OH formation, leading to the enhanced performance. The discovery of this 1T-metallene oxide material will provide new opportunities for catalysis and other applications. Identifying new, active material phases provides a promising avenue in the development of efficient catalysts. Here, authors demonstrate a metastable 1T-phase IrO2 metallene oxide as an oxygen evolution electrocatalyst in acidic electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6007, "DOI": "10.1038/s41467-021-26336-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26336-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000707430400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, YX; Miao, JS; Hua, T; Huang, ZY; Qi, YY; Zou, Y; Qiu, YT; Xia, H; Liu, H; Cao, XS; Yang, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yu Xuan; Miao, Jingsheng; Hua, Tao; Huang, Zhongyan; Qi, Yanyu; Zou, Yang; Qiu, Yuntao; Xia, Han; Liu, He; Cao, Xiaosong; Yang, Chuluo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient selenium-integrated TADF OLEDs with reduced roll-off", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic light emitters based on multiresonullce-induced thermally activated delayed fluorescent materials have great potential for realizing efficient, narrowband organic light-emitting diodes (OLEDs). However, at high brightness operation, efficiency roll-off attributed to the slow reverse intersystem crossing (RISC) process hinders the use of multiresonullce-induced thermally activated delayed fluorescent materials in practical applications. Here we report a heavy-atom incorporating emitter, BNSeSe, which is based on a selenium-integrated boron-nitrogen skeleton and exhibits 100% photoluminescence quantum yield and a high RISC rate (k(RISC)) of 2.0 x 10(6) s(-1). The corresponding green OLEDs exhibit excellent external quantum efficiencies of up to 36.8% and ultra-low roll-off character at high brightnesses (with very small roll-off values of 2.8% and 14.9% at 1,000 cd m(-2) and 10,000 cd m(-2), respectively). Furthermore, the outstanding capability to harvest triplet excitons also enables BNSeSe to be a superior sensitizer for a hyperfluorescence OLED, which shows state-of-the-art performance with a high excellent external quantum efficiency of 40.5%, power efficiency beyond 200 lm W-1, and luminullce close to 20,0000 cd m(-2). Green OLEDs based on BNSeSe offer high operational efficiency and reduced efficiency roll-off.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 16, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 803, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01083-y", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01083-y", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867521100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, B; Li, K; Yin, Y; Wu, T; Dang, LN; Cabán-Acevedo, M; Han, JC; Gao, TL; Wang, XJ; Zhang, ZH; Schmidt, JR; Xu, P; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Bo; Li, Kai; Yin, Ying; Wu, Tao; Dang, Lianna; Caban-Acevedo, Miguel; Han, Jiecai; Gao, Tangling; Wang, Xianjie; Zhang, Zhihua; Schmidt, J. R.; Xu, Ping; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Mixed Nickel Iron Phosphosulfide nullosheet Electrocatalysts for Enhanced Hydrogen and Oxygen Evolution", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly efficient earth-abundant electrocatalysts for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are of great importance for renewable energy conversion systems. Herein, guided by theoretical calculations, we demonstrate highly efficient water splitting in alkaline solution using quarternary mixed nickel iron phosphosulfide (Ni1-xFexPS3) nullosheets (NSs), even though neither NiPS3 nor FePS3 is a good HER (or OER) electrocatalyst. With tuned electronic structure and improved electrical conductivity induced by mixing appropriate amount of Fe into NiPS3, Ni09Fe0.1PS3 NSs display excellent HER activity (an overpotential of 72 mV vs reversible hydrogen electrode (RHE) at a geometric catalytic current density of -10 mA cm(-2) and a Tafel slope of 73 mV dec(-1)), which is among the best HER catalysts under alkaline conditions. Ni0.9Fe0.1PS3 NSs also show a good apparent OER activity (an overpotential of 329 mV vs RHE at a catalytic current density of 20 mA cm(-2) and a Tafel slope of 69 mV dec(-1)), although structural investigation indicates the formation of Ni(Fe)OOH and Ni(Fe)(OH), layers on the catalyst surface after OER reactions as likely the real active species. These mixed nickel iron phosphosulfide non-precious-metal electrocatalysts with enhanced intrinsic activity and long-term stability and durability should have great potential in overall water-splitting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8549, "End Page": 8557, "Article Number": null, "DOI": "10.1021/acscatal.7b02575", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b02575", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417230500063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, FX; Kemppainen, E; Dorbandt, I; Xi, FX; Bors, R; Maticiuc, N; Wenisch, R; Bagacki, R; Schary, C; Michalczik, U; Bogdanoff, P; Lauermann, I; van de Krol, R; Schlatmann, R; Calnull, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Fuxi; Kemppainen, Erno; Dorbandt, Iris; Xi, Fanxing; Bors, Radu; Maticiuc, Natalia; Wenisch, Robert; Bagacki, Rory; Schary, Christian; Michalczik, Ursula; Bogdanoff, Peter; Lauermann, Iver; van de Krol, Roel; Schlatmann, Rutger; Calnull, Sonya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Host, Suppressor, and Promoter-The Roles of Ni and Fe on Oxygen Evolution Reaction Activity and Stability of NiFe Alloy Thin Films in Alkaline Media", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the oxygen evolution reaction (OER) activity and stability of the NiFe-based materials is important for achieving low-cost and highly efficient electro-catalysts for practical water splitting. Here, we report the roles of Ni and Fe on the OER activity and stability of metallic NiFe and pure Ni thin films in alkaline media. Our results support that Ni(OH)(2)/NiOOH does not contribute to the OER directly, but it serves as an ideal host for Fe incorporation, which is essential for obtaining high OER activity. Furthermore, the availability of Fe in the electrolyte is found to be important and necessary for both NiFe and pure Ni thin films to maintain an enhanced OER performance, while the presence of Ni is detrimental to the OER kinetics. The impacts of Fe and Ni species present in KOH on the OER activity are consistent with the dissolution/re-deposition mechanism we proposed. Stability studies show that the OER activity will degrade under prolonged continuous operation. Satisfactory stability can, however, be achieved with intermittent OER operation, in which the electrocatalyst is cycled between degraded and recovered states. Accordingly, two important ranges, that is, the recovery range and the degradation range, are proposed. Compared to the intermittent OER operation, prolonged continuous OER operation (i.e., in the degradation range) generates a higher NiOOH content in the electrocatalyst, which is likely related to the OER deactivation. If the electrode works in the recovery range for a certain period, that is, at a sufficiently low reduction potential, where Ni3+ is reduced to Ni2+, the OER activity can be maintained and even improved if Fe is also present in the electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2021, "Volume": 11, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10537, "End Page": 10552, "Article Number": null, "DOI": "10.1021/acscatal.1c01190", "DOI Link": "http://dx.doi.org/10.1021/acscatal.1c01190", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687845800046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, S; Zhang, W; Demarteau, M; Hoffmann, A; Dubey, M; Roelofs, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, Saptarshi; Zhang, Wei; Demarteau, Marcel; Hoffmann, Axel; Dubey, Madan; Roelofs, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Transport Gap in Phosphorene", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this article, we experimentally demonstrate that the transport gap of phosphorene can be tuned monotonically from similar to 0.3 to similar to 1.0 eV when the flake thickness is scaled down from bulk to a single layer. As a consequence, the ON current, the OFF current, and the current ON/OFF ratios of phosphorene field effect transistors (FETs) were found to be significantly impacted by the layer thickness. The transport gap was determined from the transfer characteristics of phosphorene FETs using a robust technique that has not been reported before. The detailed mathematical model is also provided. By scaling the thickness of the gate oxide, we were also able to demonstrate enhanced ambipolar conduction in monolayer and few layer phosphorene FETs. The asymmetry of the electron and the hole current was found to be dependent on the layer thickness that can be explained by dynamic changes of the metal Fermi level with the energy band of phosphorene depending on the layer number. We also extracted the Schottky barrier heights for both the electron and the hole injection as a function of the layer thickness. Finally, we discuss the dependence of field effect hole mobility of phosphorene on temperature and carrier concentration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 677, "Times Cited, All Databases": 720, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5733, "End Page": 5739, "Article Number": null, "DOI": "10.1021/nl5025535", "DOI Link": "http://dx.doi.org/10.1021/nl5025535", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343016400040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CY; Wang, ZJ; Liu, MD; Wang, EZ; Wang, BL; Xu, LL; Jiang, KL; Fan, SS; Sun, YH; Li, J; Liu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chenyu; Wang, Zhijie; Liu, Mingda; Wang, Enze; Wang, Bolun; Xu, Longlong; Jiang, Kaili; Fan, Shoushan; Sun, Yinghui; Li, Jia; Liu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast self-heating synthesis of robust heterogeneous nullocarbides for high current density hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Industry-level water splitting requires highly active and stable hydrogen evolution reaction (HER) catalysts. Herein, an ultrafast self-heating synthesis delivers robust Mo2C/MoC/CNT HER catalysts that can work at 1000 mA cm(-2) for 14 days. Designing cost-effective and high-efficiency catalysts to electrolyze water is an effective way of producing hydrogen. Practical applications require highly active and stable hydrogen evolution reaction catalysts working at high current densities (>= 1000 mA cm(-2)). However, it is challenging to simultaneously enhance the catalytic activity and interface stability of these catalysts. Herein, we report a rapid, energy-saving, and self-heating method to synthesize high-efficiency Mo2C/MoC/carbon nullotube hydrogen evolution reaction catalysts by ultrafast heating and cooling. The experiments and density functional theory calculations reveal that numerous Mo2C/MoC hetero-interfaces offer abundant active sites with a moderate hydrogen adsorption free energy Delta G(H*) (0.02 eV), and strong chemical bonding between the Mo2C/MoC catalysts and carbon nullotube heater/electrode significantly enhances the mechanical stability owing to instantaneous high temperature. As a result, the Mo2C/MoC/carbon nullotube catalyst achieves low overpotentials of 233 and 255 mV at 1000 and 1500 mA cm(-2) in 1 M KOH, respectively, and the overpotential shows only a slight change after working at 1000 mA cm(-2) for 14 days, suggesting the excellent activity and stability of the high-current-density hydrogen evolution reaction catalyst. The promising activity, excellent stability, and high productivity of our catalyst can fulfil the demands of hydrogen production in various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3338, "DOI": "10.1038/s41467-022-31077-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31077-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, H; Sun, XY; Liu, Y; Zeng, SP; Zhang, QH; Gu, L; Wang, TH; Han, GF; Wen, Z; Fang, QR; Lang, XY; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Hang; Sun, Xin-Ying; Liu, Yang; Zeng, Shu-Pei; Zhang, Qing-Hua; Gu, Lin; Wang, Tong-Hui; Han, Gao-Feng; Wen, Zi; Fang, Qian-Rong; Lang, Xing-You; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicomponent Intermetallic nulloparticles on Hierarchical Metal Network as Versatile Electrocatalysts for Highly Efficient Water Splitting", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-efficiency and cost-effective alloy catalysts toward hydrogen-evolution reaction (HER) is crucial for large-scale hydrogen production via electrochemical water splitting, but conventional single-principal-element alloy design usually causes insufficient activity and durability of state-of-the-art multimetallic catalysts based on non-precious transition metals. Herein, we report multicomponent intermetallic Mo(NiFeCo)(4) nulloparticles seamlessly integrated on hierarchical nickel network (Mo(NiFeCo)(4)/Ni) as robust hydrogen-evolution electrocatalysts with remarkably improved activity and durability by making use of iron and cobalt atoms partially substituting nickel sites to form high-entropy NiFeCo sublattice in intermetallic MoNi4 matrix, which serve as bifunctional electroactive sites for both water dissociation and adsorption/combination of hydrogen intermediate and improves thermodynamic stability. By virtue of bicontinuous nulloporous nickel skeleton facilitating electron/ion transportation, self-supported nulloporous Mo(NiFeCo)(4)/Ni electrode exhibits exceptional HER electrocatalysis, with low Tafel slope (approximate to 35 mV dec(-1)), high current density (approximate to 2300 mA cm(-2)) at low overpotential (200 mV) and long-term durability in 1 m KOH. When coupled to its electrooxidized and nitrified derivative for oxygen-evolution reaction, their alkaline water electrolyzers operate with a superior overall water-splitting output, outperforming the one constructed with commercially available noble-metal-based catalysts. These electrochemical properties make it an attractive candidate as electrocatalyst in alkaline water electrolysis for large-scale hydrogen generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2023, "Volume": 33, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202214412", "DOI Link": "http://dx.doi.org/10.1002/adfm.202214412", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935078400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boyd, CC; Shallcross, RC; Moot, T; Kerner, R; Bertoluzzi, L; Onno, A; Kavadiya, S; Chosy, C; Wolf, EJ; Werner, J; Raiford, JA; de Paula, C; Palmstrom, AF; Yu, ZSJ; Berry, JJ; Bent, SF; Holman, ZC; Luther, JM; Ratcliff, EL; Armstrong, NR; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boyd, Caleb C.; Shallcross, R. Clayton; Moot, Taylor; Kerner, Ross; Bertoluzzi, Luca; Onno, Arthur; Kavadiya, Shalinee; Chosy, Cullen; Wolf, Eli J.; Werner, Jeremie; Raiford, James A.; de Paula, Camila; Palmstrom, Axel F.; Yu, Zhengshan J.; Berry, Joseph J.; Bent, Stacey F.; Holman, Zachary C.; Luther, Joseph M.; Ratcliff, Erin L.; Armstrong, Neal R.; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overcoming Redox Reactions at Perovskite-Nickel Oxide Interfaces to Boost Voltages in Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel oxide (NiOx) hole transport layers (HTLs) are desirable contacts for perovskite photovoltaics because they are low cost, stable, and readily scalable; however, they deliver lower open-circuit voltages (V(OC)s) compared to organic HTLs. Here, we characterize and mitigate electron transfer-proton transfer reactions between NiOx HTLs and perovskite precursors. Using XPS and UPS characterization, we identify that Ni >= 3+ metal cation sites in NiOx thin films act both as Bronsted proton acceptors and Lewis electron acceptors, deprotonating cationic amines and oxidizing iodide species, forming PbI2-xBrx-rich hole extraction barriers at the perovskite-NiOx. interface. Titrating reactive Ni >= 3+ surface states with excess A-site cation salts during perovskite active layer deposition yielded an increase in V-OC values to 1.15 V and power conversion efficiencies of similar to 20%. This may be a general finding for metal oxide contacts that act as Bronsted and Lewis acid-base reactants toward perovskite precursors, an observation that has also been made recently for TiO2 and SnO2 contacts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2020, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1759, "End Page": 1775, "Article Number": null, "DOI": "10.1016/j.joule.2020.06.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.06.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561454400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, G; Li, M; Taylor, R; Hao, Y; Besagni, G; Markides, CN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, G.; Li, M.; Taylor, R.; Hao, Y.; Besagni, G.; Markides, C. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar energy utilisation: Current status and roll-out potential", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To meet the well-known energy transition challenge, a rapid shift from fossil fuels to the broader exploitation of renewable energy sources is needed; solar energy represents the most abundant and readily available resource amongst the renewable energy sources. This vision paper aims at shedding light on the current knowledge and emerging pathways for solar energy utilisation. Specifically, after a general introduction and a brief overview of the current knowledge, open issues are discussed regarding photovoltaic/thermal (PV/T) collectors, building integrated photovoltaic/thermal (BIPV/T) systems, concentrating solar power plants, solar thermochemistry, solar-driven water distillation, and solar thermal energy storage technologies. Subsequentially, this vision article defines key fundamental challenges that need to be addressed for these technologies to play a significant role in future sustainable energy systems. The identified challenges include developing new materials, enhanced performance, accelerated system installation and improved manufacturing processes, combining solar energy with other clean energy production and storage systems, and integrating solar energy utilisation with local energy utilisation patterns.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2022, "Volume": 209, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118285, "DOI": "10.1016/j.applthermaleng.2022.118285", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2022.118285", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788215700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "MacKenzie, IA; Wang, LF; Onuska, NPR; Williams, OF; Begam, K; Moran, AM; Dunietz, BD; Nicewicz, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "MacKenzie, Ian A.; Wang, Leifeng; Onuska, Nicholas P. R.; Williams, Olivia F.; Begam, Khadiza; Moran, Andrew M.; Dunietz, Barry D.; Nicewicz, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery and characterization of an acridine radical photoreductant", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoinduced electron transfer (PET) is a phenomenon whereby the absorption of light by a chemical species provides an energetic driving force for an electron-transfer reaction(1-4). This mechanism is relevant in many areas of chemistry, including the study of natural and artificial photosynthesis, photovoltaics and photosensitive materials. In recent years, research in the area of photoredox catalysis has enabled the use of PET for the catalytic generation of both neutral and charged organic free-radical species. These technologies have enabled previously inaccessible chemical transformations and have been widely used in both academic and industrial settings. Such reactions are often catalysed by visible-light-absorbing organic molecules or transition-metal complexes of ruthenium, iridium, chromium or copper(5,6). Although various closed-shell organic molecules have been shown to behave as competent electron-transfer catalysts in photoredox reactions, there are only limited reports of PET reactions involving neutral organic radicals as excited-state donors or acceptors. This is unsurprising because the lifetimes of doublet excited states of neutral organic radicals are typically several orders of magnitude shorter than the singlet lifetimes of known transition-metal photoredox catalysts(7-11). Here we document the discovery, characterization and reactivity of a neutral acridine radical with a maximum excited-state oxidation potential of -3.36 volts versus a saturated calomel electrode, which is similarly reducing to elemental lithium, making this radical one of the most potent chemical reductants reported(12). Spectroscopic, computational and chemical studies indicate that the formation of a twisted intramolecular charge-transfer species enables the population of higher-energy doublet excited states, leading to the observed potent photoreducing behaviour. We demonstrate that this catalytically generated PET catalyst facilitates several chemical reactions that typically require alkali metal reductants and can be used in other organic transformations that require dissolving metal reductants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2020, "Volume": 580, "Issue": 7801, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2131-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2131-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543789300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Gao, WH; Oshima, H; Nagase, K; Lee, CH; Mori, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zihang; Gao, Weihong; Oshima, Hironori; Nagase, Kazuo; Lee, Chul-Ho; Mori, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Maximizing the performance of n-type Mg3Bi2 based materials for room-temperature power generation and thermoelectric cooling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the thermoelectric effect was discovered around 200 years ago, the main application in practice is thermoelectric cooling using the traditional Bi2Te3. The related studies of new and efficient room-temperature thermoelectric materials and modules have, however, not come to fruition yet. In this work, the electronic properties of n-type Mg3.2Bi1.5Sb0.5 material are maximized via delicate microstructural design with the aim of eliminating the thermal grain boundary resistance, eventually leading to a high zT above 1 over a broad temperature range from 323 K to 423 K. Importantly, we further demonstrated a great breakthrough in the non-Bi2Te3 thermoelectric module, coupled with the high-performance p-type alpha-MgAgSb, for room-temperature power generation and thermoelectric cooling. A high conversion efficiency of similar to 2.8% at the temperature difference of 95 K and a maximum temperature difference of 56.5 K are experimentally achieved. If the interfacial contact resistance is further reduced, our non-Bi2Te3 module may rival the long-standing champion commercial Bi2Te3 system. Overall, this work represents a substantial step towards the real thermoelectric application using non-Bi2Te3 materials and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1120, "DOI": "10.1038/s41467-022-28798-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28798-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763605200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JF; Wang, Y; Li, ZY; Xia, S; Cai, R; Ma, L; Zhang, TY; Ackley, O; Yang, SZ; Wu, YC; Wu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jianfang; Wang, Yan; Li, Zhengyuan; Xia, Shuai; Cai, Rui; Ma, Lu; Zhang, Tianyu; Ackley, Josh; Yang, Shize; Wu, Yucheng; Wu, Jingjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain Boundary-Derived Cu+/Cu0 Interfaces in CuO nullosheets for Low Overpotential Carbon Dioxide Electroreduction to Ethylene", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction reaction can be used to produce value-added hydrocarbon fuels and chemicals by coupling with clean electrical energy. However, highly active, selective, and energy-efficient CO2 conversion to multicarbon hydrocarbons, such as C2H4, remains challenging because of the lack of efficient catalysts. Herein, an ultrasonication-assisted electrodeposition strategy to synthesize CuO nullosheets for low-overpotential CO2 electroreduction to C2H4 is reported. A high C2H4 Faradaic efficiency of 62.5% is achieved over the CuO nullosheets at a small potential of -0.52 V versus a reversible hydrogen electrode, corresponding to a record high half-cell cathodic energy efficiency of 41%. The selectivity toward C2H4 is maintained for over 60 h of continuous operation. The CuO nullosheets are prone to in situ restructuring during CO2 reduction, forming abundant grain boundaries (GBs). Stable Cu+/Cu-0 interfaces are derived from the low-coordinated Cu atoms in the reconstructed GB regions and act as highly active sites for CO2 reduction at low overpotentials. In situ Raman spectroscopic analysis and density functional theory computation reveal that the Cu+/Cu-0 interfaces offer high *CO surface coverage and lower the activation energy barrier for *CO dimerization, which, in synergy, facilitates CO2 reduction to C2H4 at low overpotentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 9, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200454, "DOI": "10.1002/advs.202200454", "DOI Link": "http://dx.doi.org/10.1002/advs.202200454", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798533900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avery, AD; Zhou, BH; Lee, J; Lee, ES; Miller, EM; Ihly, R; Wesenberg, D; Mistry, KS; Guillot, SL; Zink, BL; Kim, YH; Blackburn, JL; Ferguson, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avery, Azure D.; Zhou, Ben H.; Lee, Jounghee; Lee, Eui-Sup; Miller, Elisa M.; Ihly, Rachelle; Wesenberg, Devin; Mistry, Kevin S.; Guillot, Sarah L.; Zink, Barry L.; Kim, Yong-Hyun; Blackburn, Jeffrey L.; Ferguson, Andrew J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailored semiconducting carbon nullotube networks with enhanced thermoelectric properties", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric power generation, allowing recovery of part of the energy wasted as heat, is emerging as an important component of renewable energy and energy efficiency portfolios. Although inorganic semiconductors have traditionally been employed in thermoelectric applications, organic semiconductors garner increasing attention as versatile thermoelectric materials. Here we present a combined theoretical and experimental study suggesting that semiconducting single-walled carbon nullotubes with carefully controlled chirality distribution and carrier density are capable of large thermoelectric power factors, higher than 340 mu Wm(-1) K-2, comparable to the best-performing conducting polymers and larger than previously observed for carbon nullotube films. Furthermore, we demonstrate that phonons are the dominullt source of thermal conductivity in the networks, and that our carrier doping process significantly reduces the thermal conductivity relative to undoped networks. These findings provide the scientific underpinning for improved functional organic thermoelectric composites with carbon nullotube inclusions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16033, "DOI": "10.1038/NENERGY.2016.33", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.33", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394115900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amann, P; Klötzer, B; Degerman, D; Köpfle, N; Götsch, T; Lömker, P; Rameshan, C; Ploner, K; Bikaljevic, D; Wang, HY; Soldemo, M; Shipilin, M; Goodwin, CM; Gladh, J; Stenlid, JH; Börner, M; Schlueter, C; Nilsson, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amann, Peter; Kloetzer, Bernhard; Degerman, David; Koepfle, Norbert; Goetsch, Thomas; Loemker, Patrick; Rameshan, Christoph; Ploner, Kevin; Bikaljevic, Djuro; Wang, Hsin-Yi; Soldemo, Markus; Shipilin, Mikhail; Goodwin, Christopher M.; Gladh, Joergen; Stenlid, Joakim Halldin; Boerner, Mia; Schlueter, Christoph; Nilsson, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The state of zinc in methanol synthesis over a Zn/ZnO/Cu(211) model catalyst", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The active chemical state of zinc (Zn) in a zinc-copper (Zn-Cu) catalyst during carbon dioxide/carbon monoxide (CO2/CO) hydrogenation has been debated to be Zn oxide (ZnO) nulloparticles, metallic Zn, or a Zn-Cu surface alloy. We used x-ray photoelectron spectroscopy at 180 to 500 millibar to probe the nature of Zn and reaction intermediates during CO2/CO hydrogenation over Zn/ZnO/Cu(211), where the temperature is sufficiently high for the reaction to rapidly turn over, thus creating an almost adsorbate-free surface. Tuning of the grazing incidence angle makes it possible to achieve either surface or bulk sensitivity. Hydrogenation of CO2 gives preference to ZnO in the form of clusters or nulloparticles, whereas in pure CO a surface Zn-Cu alloy becomes more prominent. The results reveal a specific role of CO in the formation of the Zn-Cu surface alloy as an active phase that facilitates efficient CO2 methanol synthesis..", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2022, "Volume": 376, "Issue": 6593, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 603, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj7747", "DOI Link": "http://dx.doi.org/10.1126/science.abj7747", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796932700038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sokol, KP; Robinson, WE; Warnull, J; Kornienko, N; Nowaczyk, MM; Ruff, A; Zhang, JZ; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sokol, Katarzyna P.; Robinson, William E.; Warnull, Julien; Kornienko, Nikolay; Nowaczyk, Marc M.; Ruff, Adrian; Zhang, Jenny Z.; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bias-free photoelectrochemical water splitting with photosystem II on a dye-sensitized photoanode wired to hydrogenase", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural photosynthesis stores sunlight in chemical energy carriers, but it has not evolved for the efficient synthesis of fuels, such as H-2. Semi-artificial photosynthesis combines the strengths of natural photosynthesis with synthetic chemistry and materials science to develop model systems that overcome nature's limitations, such as low-yielding metabolic pathways and non-complementary light absorption by photosystems I and II. Here, we report a bias-free semi-artificial tandem platform that wires photosystem II to hydrogenase for overall water splitting. This photoelectrochemical cell integrated the red and blue light-absorber photosystem II with a green light-absorbing diketopyrrolopyrrole dye-sensitized TiO2 photoanode, and so enabled complementary panchromatic solar light absorption. Effective electronic communication at the enzyme-material interface was engineered using an osmium-complex-modified redox polymer on a hierarchically structured TiO2. This system provides a design protocol for bias-free semi-artificial Z schemes in vitro and provides an extended toolbox of biotic and abiotic components to re-engineer photosynthetic pathways.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 944, "End Page": 951, "Article Number": null, "DOI": "10.1038/s41560-018-0232-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0232-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449518300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weston, A; Castanon, EG; Enaldiev, V; Ferreira, F; Bhattacharjee, S; Xu, SG; Corte-León, H; Wu, ZF; Clark, N; Summerfield, A; Hashimoto, T; Gao, YZ; Wang, WD; Hamer, M; Read, H; Fumagalli, L; Kretinin, A; Haigh, SJ; Kazakova, O; Geim, AK; Fal'ko, V; Gorbachev, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weston, Astrid; Castanon, Eli G.; Enaldiev, Vladimir; Ferreira, Fabio; Bhattacharjee, Shubhadeep; Xu, Shuigang; Corte-Leon, Hector; Wu, Zefei; Clark, Nicholas; Summerfield, Alex; Hashimoto, Teruo; Gao, Yunze; Wang, Wendong; Hamer, Matthew; Read, Harriet; Fumagalli, Laura; Kretinin, Andrey, V; Haigh, Sarah J.; Kazakova, Olga; Geim, A. K.; Fal'ko, Vladimir, I; Gorbachev, Roman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial ferroelectricity in marginally twisted 2D semiconductors", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Marginal twisting of 2D semiconductor crystals enables the emergence of room temperature interfacial ferroelectricity. Twisted heterostructures of two-dimensional crystals offer almost unlimited scope for the design of new metamaterials. Here we demonstrate a room temperature ferroelectric semiconductor that is assembled using mono- or few-layer MoS2. These van der Waals heterostructures feature broken inversion symmetry, which, together with the asymmetry of atomic arrangement at the interface of two 2D crystals, enables ferroelectric domains with alternating out-of-plane polarization arranged into a twist-controlled network. The last can be moved by applying out-of-plane electrical fields, as visualized in situ using channelling contrast electron microscopy. The observed interfacial charge transfer, movement of domain walls and their bending rigidity agree well with theoretical calculations. Furthermore, we demonstrate proof-of-principle field-effect transistors, where the channel resistance exhibits a pronounced hysteresis governed by pinning of ferroelectric domain walls. Our results show a potential avenue towards room temperature electronic and optoelectronic semiconductor devices with built-in ferroelectric memory functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 17, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 390, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-022-01072-w", "DOI Link": "http://dx.doi.org/10.1038/s41565-022-01072-w", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000761842000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasool, K; Mahmoud, KA; Johnson, DJ; Helal, M; Berdiyorov, GR; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasool, Kashif; Mahmoud, Khaled A.; Johnson, Daniel J.; Helal, Mohamed; Berdiyorov, Golibjon R.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Antibacterial Membrane based on Two-Dimensional Ti3C2Tx (MXene) nullosheets", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced membranes that enable ultrafast water flux while demonstrating anti-biofouling characteristics can facilitate sustainable water/wastewater treatment processes. MXenes, twodimensional (2D) metal carbides and nitrides, have attracted attention for applications in water/ wastewater treatment. In this work, we reported the antibacterial properties of micrometer-thick titanium carbide (Ti3C2Tx) MXene membranes prepared by filtration on a polyvinylidene fluoride (PVDF) support. The bactericidal properties of Ti3C2Tx modified membranes were tested against Escherichia coli (E. coli) and Bacillus subtilis (B. subtilis) by bacterial growth on the membrane surface and its exposure to bacterial suspensions. The antibacterial rate of fresh Ti3C2Tx MXene membranes reaches more than 73% against B. subtilis and 67% against E. coli as compared with that of control PVDF, while aged Ti3C2Tx membrane showed over 99% growth inhibition of both bacteria under same conditions. Flow cytometry showed about 70% population of dead and compromised cells after 24 h of exposure of both bacterial strains. The damage of the cell surfaces was also revealed by scanning electron microscopy (SEM) and atomic force microscopy (AFM) analysis, respectively. The demonstrated antibacterial activity of MXene coated membranes against common waterborne bacteria, promotes their potential application as anti-biofouling membrane in water and wastewater treatment processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1598, "DOI": "10.1038/s41598-017-01714-3", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-01714-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400870200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamali, M; Suhas, DP; Costa, ME; Capela, I; Aminabhavi, TM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamali, Mohammadreza; Suhas, D. P.; Costa, Maria Elisabete; Capela, Isabel; Aminabhavi, Tejraj M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainability considerations in membrane-based technologies for industrial effluents treatment", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Treatment of industrial effluents (EFs) from the polluted wastewater sources using membrane technologies is an effective and attractive alternative to overcome the weaknesses of some of the conventional wastewater treatment processes, especially when dealing with EFs loaded with recalcitrant organic pollutants and toxic substances. The application of various polymeric and inorganic membrane based technologies to be used for the treatment of industrial EFs has attracted a considerable attention in the past decades. In this regard, a critical discussion on the sustainability of various aspects of membrane technologies would promote the commercialization of these technologies. In this review, various sustainability criteria in technical, economic, environmental, and social categories have been considered for a critical discussion on the current status and improvement opportunities of membrane technologies for the treatment of industrial EFs. While the application of polymeric membranes has been restricted by some bottlenecks to deal with some industrial effluents, metal oxides fabricated ceramic membranes, and especially those fabricated with nullostructured materials such as nullo-zeolites, those made of metal organic frameworks as well as carbon-based fabricated membranes have shown a promising performance in the rejection of recalcitrant organic pollutants. In addition, the combinations of inorganic membrane technologies with other novel methods such as advanced oxidation processes (e.g., using engineered nullomaterials) can be considered among the best options to deal with such highly polluted effluents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2019, "Volume": 368, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 474, "End Page": 494, "Article Number": null, "DOI": "10.1016/j.cej.2019.02.075", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.02.075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462769600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, WY; Cheng, LF; An, YR; Lv, SL; Wu, H; Fan, XL; Zhang, YN; Guo, XH; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Wenyu; Cheng, Laifei; An, Yurong; Lv, Shilin; Wu, Heng; Fan, Xiaoli; Zhang, Yani; Guo, Xiaohui; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Laminated Hybrid Junction of Sulfur-Doped TiO2 and a Carbon Substrate Derived from Ti3C2 MXenes: Toward Highly Visible Light-Driven Photocatalytic Hydrogen Evolution", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TiO2 is an ideal photocatalyst candidate except for its large bandgap and fast charge recombination. A novel laminated junction composed of defect-controlled and sulfur-doped TiO2 with carbon substrate (LDC-S-TiO2/C) is synthesized using the 2D transition metal carbides (MXenes) as a template to enhance light absorption and improve charge separation. The prepared LDC-S-TiO2/C catalyst delivers a high photocatalytic H-2 evolution rate of 333 mu mol g(-1) h(-1) with a high apparent quantum yield of 7.36% at 400 nm and it is also active even at 600 nm, resulting into a 48 time activity compared with L-TiO2/C under visible light irradiation. Further theoretical modeling calculation indicates that such novel approach also reduces activation energy of hydrogen production apart from broadening the absorption wavelength, facilitating charge separation, and creating a large surface area substrate. This synergic effect can also be applied to other photocatalysts' modification. The study provides a novel approach for synthesis defective metal oxides based hybrids and broaden the applications of MXene family.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700870, "DOI": "10.1002/advs.201700870", "DOI Link": "http://dx.doi.org/10.1002/advs.201700870", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435765900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mashtalir, O; Lukatskaya, MR; Kolesnikov, AI; Raymundo-Piñero, E; Naguib, M; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mashtalir, O.; Lukatskaya, M. R.; Kolesnikov, A. I.; Raymundo-Pinero, E.; Naguib, M.; Barsoum, M. W.; Gogotsi, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The effect of hydrazine intercalation on the structure and capacitance of 2D titanium carbide (MXene)", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein we show that hydrazine intercalation into 2D titanium carbide (Ti3C2-based MXene) results in changes in its surface chemistry by decreasing the amounts of fluorine, OH surface groups and intercalated water. It also creates a pillaring effect between Ti3C2Tx layers pre-opening the structure and improving the accessability to active sites. The hydrazine treated material has demonstrated a greatly improved capacitance of 250 F g(-1) in acidic electrolytes with an excellent cycling ability for electrodes as thick as 75 mu m.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9128, "End Page": 9133, "Article Number": null, "DOI": "10.1039/c6nr01462c", "DOI Link": "http://dx.doi.org/10.1039/c6nr01462c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375285800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, S; Gao, HX; Li, L; Hui, KS; Dinh, DA; Wu, SX; Kumar, S; Chen, FM; Shao, ZP; Hui, KN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shuo; Gao, Haixing; Li, Lei; Hui, Kwan San; Duc Anh Dinh; Wu, Shuxing; Kumar, Sachin; Chen, Fuming; Shao, Zongping; Hui, Kwun Nam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput identification of highly active and selective single-atom catalysts for electrochemical ammonia synthesis through nitrate reduction", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The highly selective and active nitrate-to-ammonia electrochemical conversion (NO3 reduction reaction [NO3RR]) can be an appealing and supplementary alternative to the Haber-Bosch process. It also opens up a new idea for addressing nitrate pollution. Previous study demonstrated that FeN4 single-atom catalyst (SAC) indicates excellent NO3RR performance. Nonetheless, the mechanism that triggers the electrocatalytic NO3RR remains unclear. The feasibility of NO3RR over various SACs is verified in this study via high-throughput density functional theory calculations with the single transition metal (TM) atom coordinated with four nitrogen atoms supported on graphene as the example. We conducted a comprehensive screening of TM SAC candidates for stability, NO3- adsorption strength, catalytic activity, and selectivity. Results reveal that the most promising candidate among the 23 TM SACs is Os SAC with a low limiting potential of - 0.42 V. Os SAC is better than Fe SAC with a limiting potential of -0.53 V because of the strong interaction between the oxygen of NO3- species and Os atom. The origin of high NO3RR activity of Os SAC is explained by its inner electronic structure of the strong hybridization of the Os atom and NO3- caused by the increasing charge transfer from TM atom to NO3-, leading to the suitable NO3- adsorption. This research provides a fundamental insight of discovering novel NO3RR catalysts and may provide a motivating drive for the creation of effective ammonia electrocatalysts for further experimental investigation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107517, "DOI": "10.1016/j.nulloen.2022.107517", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2022.107517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000855539900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Joseph, S; Pandey, S; Sarkar, S; Joseph, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Joseph, Shereena; Pandey, Saurabh; Sarkar, Swagato; Joseph, Joby", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bound states in the continuum in resonullt nullostructures: an overview of engineered materials for tailored applications", "Source Title": "nullOPHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "From theoretical model to experimental realization, the bound state in the continuum (BIC) is an emerging area of research interest in the last decade. In the initial years, well-established theoretical frameworks explained the underlying physics for optical BIC modes excited in various symmetrical configurations. Eventually, in the last couple of years, optical-BICs were exploited as a promising tool for experimental realization with advanced nullofabrication techniques for numerous breakthrough applications. Here, we present a review of the evolution of BIC modes in various symmetry and functioning mediums along with their application. More specifically, depending upon the nature of the interacting medium, the excitations of BIC modes are classified into the pure dielectric and lossy plasmonic BICs. The dielectric constituents are again classified as photonic crystal functioning in the sub wavelength regime, influenced by the diffraction modes and metasurfaces for interactions far from the diffraction regime. More importantly, engineered functional materials evolved with the pure dielectric medium are explored for hybrid-quasi-BIC modes with huge-quality factors, exhibiting a promising approach to trigger the nulloscale phenomena more efficiently. Similarly, hybrid modes instigated by the photonic and plasmonic constituents can replace the high dissipative losses of metallic components, sustaining the high localization of field and high figure of merit. Further, the discussions are based on the applications of the localized BIC modes and high-quality quasi-BIC resonullce traits in the nonlinear harmonic generation, refractometric sensing, imaging, lasing, nullocavities, low loss on-chip communication, and as a photodetector. The topology-controlled beam steering and, chiral sensing has also been briefly discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 10, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 4175, "End Page": 4207, "Article Number": null, "DOI": "10.1515/nulloph-2021-0387", "DOI Link": "http://dx.doi.org/10.1515/nulloph-2021-0387", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000721066500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, K; Sakhatskyi, K; Jin, J; Zhang, QY; Kovalenko, MV; Xia, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Kai; Sakhatskyi, Kostiantyn; Jin, Jiance; Zhang, Qinyuan; Kovalenko, Maksym, V; Xia, Zhiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Seed-Crystal-Induced Cold Sintering Toward Metal Halide Transparent Ceramic Scintillators", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scintillators with high spatial resolution at a low radiation dose rate are desirable for X-ray medical imaging. To challenge the state-of-art technology, it is necessary to design large-area wafers with high light yield, oriented light transport, and reduced light scattering. Here, a seed-crystal-induced cold sintering is adopted and a -textured TPP2MnBr4 (TPP: tetraphenylphosphonium) transparent ceramic is fabricated with a large-area wafer of 5 cm in diameter, exhibiting high optical transparency of above 68% over the 450-600 nm range. The compelling scintillation performance of the TPP2MnBr4 wafer includes a light yield of approximate to 78 000 +/- 2000 photons per MeV, a low detection limit 8.8 nullograys per second, about 625 times lower than the requirement of X-ray diagnostics (5500 nullograys per second), and an energy resolution of 17% for high-energy gamma-rays (662 keV). X-ray imaging demonstrates a high spatial resolution of 15.7 lp mm(-1). Moreover, the designed material exhibits good retention of the radioluminescence intensity and light yield. This work presents a paradigm for achieving light-guiding properties with high transparency and large-area fabrication by grain orientation engineering, and the transparent, textured metal halide ceramic scintillator is expected to provide a route for advancement in the X-ray imaging of tomorrow.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110420, "DOI": "10.1002/adma.202110420", "DOI Link": "http://dx.doi.org/10.1002/adma.202110420", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772903400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Wang, GH; Shao, YC; Wang, J; Zhou, S; Su, YR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jie; Wang, Guohong; Shao, Yanchi; Wang, Juan; Zhou, Shuang; Su, Yaorong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Step-scheme ZnO@ZnS hollow microspheres for improved photocatalytic H2 production performance", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing a step-scheme heterojunction at the interface between two semiconductors is an efficient way to optimize the redox ability and accelerate the charge carrier separation of a photocatalytic system for achieving high photocatalytic performance. In this study, we prepared a hierarchical ZnO@ZnS step-scheme photocatalyst by incorporating ZnS into the outer shell of hollow ZnO microspheres via a simple in situ sulfidation strategy. The ZnO@ZnS step-scheme photocatalysts had a large surface area, high light utilization capacity, and superior separation efficiency for photogenerated charge carriers. In addition, the material simulation revealed that the formation of the step-scheme heterojunction between ZnO and ZnS was due to the presence of the built-in electric field. Our study paves the way for design of high-performance photocatalysts for H-2 production. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 329, "End Page": 338, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63889-5", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63889-5", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hussain, S; Amu-Darko, JNO; Wang, MS; Alothman, AA; Ouladsmane, M; Aldossari, SA; Khan, MS; Qiao, GJ; Liu, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hussain, Shahid; Amu-Darko, Jesse Nii Okai; Wang, Mingsong; Alothman, Asma A.; Ouladsmane, Mohamed; Aldossari, Samar A.; Khan, Muhammad Shahzeb; Qiao, Guanjun; Liu, Guiwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CuO-decorated MOF derived ZnO polyhedral nullostructures for exceptional H2S gas detection", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Considering that H2S is a hazardous gas that poses a significant risk to people's lives, research into H2S gas sensors has garnered a lot of interest. This work reports a CuO/ZnO multifaceted nullostructures(NS) created by heat treating Cu2+/ZIF-8 impregnation precursors, and their microstructure and gas sensing characteristics were examined using various characterization techniques (XRD, XPS, SEM, TEM, and BET). The as-prepared hollow CuO/ZnO multifunctional nullostructures had a high gas response value (425@50 ppm H2S gas), quick response and recovery times (57/191s @20 ppm), a low limit of detection (1.6@500 ppb H2S), good humidity resistance and highly selective towards H2S gas. The hollow CuO/ZnO multifaceted nullostructures possessed enhanced gas sensing capabilities which may be related to their porous hollow nullostructures, the manufactured p-CuO/n-ZnO heterojunctions, and the spillover effect between CuO and H2S.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 317, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137827, "DOI": "10.1016/j.chemosphere.2023.137827", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2023.137827", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992530100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Hua, WB; Huang, XH; Stenzel, D; Wang, JB; Ding, ZM; Cui, YY; Wang, QS; Ehrenberg, H; Breitung, B; Kübel, C; Mu, XK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kai; Hua, Weibo; Huang, Xiaohui; Stenzel, David; Wang, Junbo; Ding, Ziming; Cui, Yanyan; Wang, Qingsong; Ehrenberg, Helmut; Breitung, Ben; Kuebel, Christian; Mu, Xiaoke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergy of cations in high entropy oxide lithium ion battery anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High entropy oxides (HEOs) with chemically disordered multi-cation structure attract intensive interest as negative electrode materials for battery applications. The outstanding electrochemical performance has been attributed to the high-entropy stabilization and the so-called 'cocktail effect'. However, the configurational entropy of the HEO, which is thermodynamically only metastable at room-temperature, is insufficient to drive the structural reversibility during conversion-type battery reaction, and the 'cocktail effect' has not been explained thus far. This work unveils the multi-cations synergy of the HEO Mg0.2Co0.2Ni0.2Cu0.2Zn0.2O at atomic and nulloscale during electrochemical reaction and explains the 'cocktail effect'. The more electronegative elements form an electrochemically inert 3-dimensional metallic nullo-network enabling electron transport. The electrochemical inactive cation stabilizes an oxide nullophase, which is semi-coherent with the metallic phase and accommodates Li+ ions. This self-assembled nullostructure enables stable cycling of micron-sized particles, which bypasses the need for nulloscale pre-modification required for conventional metal oxides in battery applications. This demonstrates elemental diversity is the key for optimizing multi-cation electrode materials. Though high entropy oxides have been explored as possible conversion-type negative electrodes for Li-ion batteries, the roles of the different elements remain unclear. Here the authors determine the behavior of each element during electrochemical cycling and connect it to the nulloscale structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1487, "DOI": "10.1038/s41467-023-37034-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37034-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001040483800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XY; Schlexer, P; Xiao, JP; Ji, YF; Wang, L; Sandberg, RB; Tang, M; Brown, KS; Peng, HJ; Ringe, S; Hahn, C; Jaramillo, TF; Norskov, JK; Chan, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xinyan; Schlexer, Philomena; Xiao, Jianping; Ji, Yongfei; Wang, Lei; Sandberg, Robert B.; Tang, Michael; Brown, Kristopher S.; Peng, Hongjie; Ringe, Stefan; Hahn, Christopher; Jaramillo, Thomas F.; Norskov, Jens K.; Chan, Karen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a microkinetic model for CO(2) reduction (CO(2)R) on Cu(211) towards C-2 products, based on energetics estimated from an explicit solvent model. We show that the differences in both Tafel slopes and pH dependence for C-1 vs C-2 activity arise from differences in their multi-step mechanisms. We find the depletion in C-2 products observed at high overpotential and high pH to arise from the 2nd order dependence of C-C coupling on CO coverage, which decreases due to competition from the C-1 pathway. We further demonstrate that CO(2) reduction at a fixed pH yield similar activities, due to the facile kinetics for CO2 reduction to CO on Cu, which suggests C-2 products to be favored for CO2 R under alkaline conditions. The mechanistic insights of this work elucidate how reaction conditions can lead to significant enhancements in selectivity and activity towards higher value C-2 products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 524, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 32, "DOI": "10.1038/s41467-018-07970-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07970-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Calado, P; Telford, AM; Bryant, D; Li, XE; Nelson, J; O'Regan, BC; Barnes, PRF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Calado, Philip; Telford, Andrew M.; Bryant, Daniel; Li, Xiaoe; Nelson, Jenny; O'Regan, Brian C.; Barnes, Piers R. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for ion migration in hybrid perovskite solar cells with minimal hysteresis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ion migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. A major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial contact materials; however, this is unlikely to significantly influence the behaviour of mobile ionic charge within the perovskite phase. Here, we show that the primary effects of ion migration can be observed regardless of whether the contacts were changed to give devices with or without significant hysteresis. Transient optoelectronic measurements combined with device simulations indicate that electric-field screening, consistent with ion migration, is similar in both high and low hysteresis CH3NH3PbI3 cells. Simulation of the photovoltage and photocurrent transients shows that hysteresis requires the combination of both mobile ionic charge and recombination near the perovskite-contact interfaces. Passivating contact recombination results in higher photogenerated charge concentrations at forward bias which screen the ionic charge, reducing hysteresis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 653, "Times Cited, All Databases": 685, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13831, "DOI": "10.1038/ncomms13831", "DOI Link": "http://dx.doi.org/10.1038/ncomms13831", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390261900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, J; Jin, J; Lin, HH; Yin, ZY; Li, JY; Lu, M; Guo, LC; Xi, PX; Tang, Y; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Jie; Jin, Jing; Lin, Honghong; Yin, Zhouyang; Li, Jianyi; Lu, Min; Guo, Linchuan; Xi, Pinxian; Tang, Yu; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimized Metal Chalcogenides for Boosting Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic water splitting (2H(2)O -> 2H(2) + O-2) is a very promising avenue to effectively and environmentally friendly produce highly pure hydrogen (H-2) and oxygen (O-2) at a large scale. Different materials have been developed to enhance the efficiency for water splitting. Among them, chalcogenides with unique atomic arrangement and high electronic transport show interesting catalytic properties in various electrochemical reactions, such as the hydrogen evolution reaction, oxygen evolution reaction, and overall water splitting, while the control of their morphology and structure is of vital importance to their catalytic performance. Herein, the general synthetic methods are summarized to prepare metal chalcogenides and different strategies are designed to improve their catalytic performance for water splitting. The remaining challenges in the research and development of metal chalcogenides and possible directions for future research are also summarized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903070, "DOI": "10.1002/advs.201903070", "DOI Link": "http://dx.doi.org/10.1002/advs.201903070", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536690400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JM; Wu, CC; Li, J; Dong, BH; Zhao, L; Wang, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jinmao; Wu, Congcong; Li, Jin; Dong, Binghai; Zhao, Li; Wang, Shimin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "1D/2D TiO2/ZnIn2S4 S-scheme heterojunction photocatalyst for efficient hydrogen evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TiO2 is a promising photocatalyst with limited use in practical applications owing to its wide handgap, narrow light response range, and rapid recombination of photoexcited carriers. To address these limitations, a novel 1D/2D TiO2/ZnIn2S4 heterostructure was designed according to the principles of the S-scheme heterojunction. The TiO2/ZnIn2S4 (TZISx) hybrids prepared via a hydrothermal method afforded significant improvement in photocatalytic hydrogen evolution (PHE) in comparison to pristine TiO2 and ZnIn2S4. In particular, the optimal TZIS2 sample (mass ratio of ZnIn2S4 to TiO2 was 0.4) exhibited the highest PHE activity (6.03 mmol/h/g), which was approximately 3.7 and 2.0 times higher than those of pristine TiO2 and ZnIn2S4, respectively. This improvement in the PHE of the TZIS2 sample could be attributed to the formation of an intimate heterojunction interface, high-efficiency separation of charge carriers, abundant reactive sites, and enhanced light absorption capacity. Notably, theoretical and experimental results demonstrated that the S-scheme mechanism of interfacial electron transfer in the TZISx composites facilitated the transfer and separation of photoexcited charge carriers, resulting in more isolated photoexcited electrons for the PHE reaction. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 339, "End Page": 349, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63875-5", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63875-5", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shafique, A; Shin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shafique, Aamir; Shin, Young-Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoelectric and phonon transport properties of two-dimensional IV-VI compounds", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We explore the thermoelectric and phonon transport properties of two-dimensional monochalcogenides (SnSe, SnS, GeSe, and GeS) using density functional theory combined with Boltzmann transport theory. We studied the electronic structures, Seebeck coefficients, electrical conductivities, lattice thermal conductivities, and figures of merit of these two-dimensional materials, which showed that the thermoelectric performance of monolayer of these compounds is improved in comparison compared to their bulk phases. High figures of merit (ZT) are predicted for SnSe (ZT = 2.63, 2.46), SnS (ZT = 1.75, 1.88), GeSe (ZT = 1.99, 1.73), and GeS (ZT = 1.85, 1.29) at 700 K along armchair and zigzag directions, respectively. Phonon dispersion calculations confirm the dynamical stability of these compounds. The calculated lattice thermal conductivities are low while the electrical conductivities and Seebeck coefficients are high. Thus, the properties of the monolayers show high potential toward thermoelectric applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 506, "DOI": "10.1038/s41598-017-00598-7", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-00598-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397811900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, P; Vermeulen, NA; Malliakas, CD; Gómez-Gualdrón, DA; Howarth, AJ; Mehdi, BL; Dohnalkova, A; Browning, ND; O'Keeffe, M; Farha, OK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.; Gomez-Gualdron, Diego A.; Howarth, Ashlee J.; Mehdi, B. Layla; Dohnalkova, Alice; Browning, Nigel D.; O'Keeffe, Michael; Farha, Omar K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bottom-up construction of a superstructure in a porous uranium-organic crystal", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bottom-up construction of highly intricate structures from simple building blocks remains one of the most difficult challenges in chemistry. We report a structurally complex, mesoporous uranium-based metal-organic framework (MOF) made from simple starting components. The structure comprises 10 uranium nodes and seven tricarboxylate ligands (both crystallographically nonequivalent), resulting in a 173.3-angstrom cubic unit cell enclosing 816 uranium nodes and 816 organic linkers-the largest unit cell found to date for any nonbiological material. The cuboctahedra organize into pentagonal and hexagonal prismatic secondary structures, which then form tetrahedral and diamond quaternary topologies with unprecedented complexity. This packing results in the formation of colossal icosidodecahedral and rectified hexakaidecahedral cavities with internal diameters of 5.0 nullometers and 6.2 nullometers, respectively-ultimately giving rise to the lowest-density MOF reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2017, "Volume": 356, "Issue": 6338, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 624, "End Page": 627, "Article Number": null, "DOI": "10.1126/science.aam7851", "DOI Link": "http://dx.doi.org/10.1126/science.aam7851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400975200051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, HW; Wu, JP; Cai, ZJ; Liu, J; Kwon, DH; Kim, H; Urban, A; Papp, JK; Foley, E; Tian, YS; Balasubramanian, M; Kim, H; Clément, RJ; McCloskey, BD; Yang, WL; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Huiwen; Wu, Jinpeng; Cai, Zijian; Liu, Jue; Kwon, Deok-Hwang; Kim, Hyunchul; Urban, Alexander; Papp, Joseph K.; Foley, Emily; Tian, Yaosen; Balasubramanian, Mahalingam; Kim, Haegyeom; Clement, Raphaele J.; McCloskey, Bryan D.; Yang, Wanli; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh power and energy density in partially ordered lithium-ion cathode materials", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is an intensive search for high-performance cathode materials for rechargeable batteries. Here the authors report that oxyfluorides with partial spinel-like cation order, made from earth-abundant elements, display both exceptionally high energy and power. The rapid market growth of rechargeable batteries requires electrode materials that combine high power and energy and are made from earth-abundant elements. Here we show that combining a partial spinel-like cation order and substantial lithium excess enables both dense and fast energy storage. Cation overstoichiometry and the resulting partial order is used to eliminate the phase transitions typical of ordered spinels and enable a larger practical capacity, while lithium excess is synergistically used with fluorine substitution to create a high lithium mobility. With this strategy, we achieved specific energies greater than 1,100 Wh kg(-1) and discharge rates up to 20 A g(-1). Remarkably, the cathode materials thus obtained from inexpensive manganese present a rare case wherein an excellent rate capability coexists with a reversible oxygen redox activity. Our work shows the potential for designing cathode materials in the vast space between fully ordered and disordered compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 213, "End Page": 221, "Article Number": null, "DOI": "10.1038/s41560-020-0573-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0573-1", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518736900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, SZ; Ma, HL; Shi, HF; Wang, H; Wang, X; Xiao, LX; Ye, WP; Huang, KW; Cao, XD; Gan, N; Ma, CQ; Gu, MX; Song, LL; Xu, H; Tao, YT; Zhang, CF; Yao, W; An, ZF; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Suzhi; Ma, Huili; Shi, Huifang; Wang, He; Wang, Xuan; Xiao, Leixin; Ye, Wenpeng; Huang, Kaiwei; Cao, Xudong; Gan, null; Ma, Chaoqun; Gu, Mingxing; Song, Lulu; Xu, Hai; Tao, Youtian; Zhang, Chunfeng; Yao, Wei; An, Zhongfu; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling long-lived organic room temperature phosphorescence in polymers by subunit interlocking", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-lived room temperature phosphorescence (LRTP) is an attractive optical phenomenon in organic electronics and photonics. Despite the rapid advance, it is still a formidable challenge to explore a universal approach to obtain LRTP in amorphous polymers. Based on the traditional polyethylene derivatives, we herein present a facile and concise chemical strategy to achieve ultralong phosphorescence in polymers by ionic bonding cross-linking. Impressively, a record LRTP lifetime of up to 2.1 s in amorphous polymers under ambient conditions is set up. Moreover, multicolor long-lived phosphorescent emission can be procured by tuning the excitation wavelength in single-component polymer materials. These results outline a fundamental principle for the construction of polymer materials with LRTP, endowing traditional polymers with fresh features for potential applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4247, "DOI": "10.1038/s41467-019-11749-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11749-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486375400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Varnell, JA; Tse, ECM; Schulz, CE; Fister, TT; Haasch, RT; Timoshenko, J; Frenkel, AI; Gewirth, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Varnell, Jason A.; Tse, Edmund C. M.; Schulz, Charles E.; Fister, Tim T.; Haasch, Richard T.; Timoshenko, Janis; Frenkel, Anatoly I.; Gewirth, Andrew A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of carbon-encapsulated iron nulloparticles as active species in non-precious metal oxygen reduction catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widespread use of fuel cells is currently limited by the lack of efficient and cost-effective catalysts for the oxygen reduction reaction. Iron-based non-precious metal catalysts exhibit promising activity and stability, as an alternative to state-of-the-art platinum catalysts. However, the identity of the active species in non-precious metal catalysts remains elusive, impeding the development of new catalysts. Here we demonstrate the reversible deactivation and reactivation of an iron-based non-precious metal oxygen reduction catalyst achieved using high-temperature gas-phase chlorine and hydrogen treatments. In addition, we observe a decrease in catalyst heterogeneity following treatment with chlorine and hydrogen, using Mossbauer and X-ray absorption spectroscopy. Our study reveals that protected sites adjacent to iron nulloparticles are responsible for the observed activity and stability of the catalyst. These findings may allow for the design and synthesis of enhanced non-precious metal oxygen reduction catalysts with a higher density of active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12582, "DOI": "10.1038/ncomms12582", "DOI Link": "http://dx.doi.org/10.1038/ncomms12582", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381775300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, Q; Shi, H; Meng, H; Zeng, SP; Wan, WB; Zhang, W; Wen, Z; Lang, XY; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Qing; Shi, Hang; Meng, Huan; Zeng, Shu-Pei; Wan, Wu-Bin; Zhang, Wei; Wen, Zi; Lang, Xing-You; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aluminum-copper alloy anode materials for high-energy aqueous aluminum batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous aluminum batteries are promising post-lithium battery technologies for large-scale energy storage applications because of the raw materials abundance, low costs, safety and high theoretical capacity. However, their development is hindered by the unsatisfactory electrochemical behaviour of the Al metal electrode due to the presence of an oxide layer and hydrogen side reaction. To circumvent these issues, we report aluminum-copper alloy lamellar heterostructures as anode active materials. These alloys improve the Al-ion electrochemical reversibility (e.g., achieving dendrite-free Al deposition during stripping/plating cycles) by using periodic galvanic couplings of alternating anodic alpha-aluminum and cathodic intermetallic Al2Cu nullometric lamellas. In symmetric cell configuration with a low oxygen concentration (i.e., 0.13 mg L-1) aqueous electrolyte solution, the lamella-nullostructured eutectic Al82Cu18 alloy electrode allows Al stripping/plating for 2000 h with an overpotential lower than +/- 53 mV. When the Al82Cu18 anode is tested in combination with an AI(x)MnO(2) cathode material, the aqueous full cell delivers specific energy of similar to 670 Wh kg(-1) at 100 mA g(-1) and an initial discharge capacity of similar to 400 mAh g(-1) at 500 mA g(-1) with a capacity retention of 83% after 400 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 576, "DOI": "10.1038/s41467-022-28238-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28238-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751005700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SH; Wu, MF; Tang, TT; Xing, QJ; Peng, CQ; Li, F; Liu, H; Luo, XB; Zou, JP; Min, XB; Luo, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Si-Hai; Wu, Mei-Feng; Tang, Ting-Ting; Xing, Qiu-Ju; Peng, Cai-Qing; Li, Fei; Liu, Hui; Luo, Xu-Biao; Zou, Jian-Ping; Min, Xiao-Bo; Luo, Jin-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism investigation of anoxic Cr(VI) removal by nullo zero-valent iron based on XPS analysis in time scale", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, nulloscale zero-valent iron (nZVI) with a considerably high surface area (182.97 m(2).g(-1)) and featured morphology of chain structure has been synthesized and well characterized. The as-prepared nZVI on can totally remove Cr(VI) under anoxic condition after 20 min reaction, whereas only 43% of Cr(VI) was removed after 60 min reaction under oxic condition. Noteworthily, the nZVI exhibits excellent removal capacity of Cr(VI) (123.85 mg/g) and fast removal rate (0.017 g.mg(-1).min(-1)), much better than those reported in the literatures except for that reported by Li et al. (2008) [1]. Experimental results have confirmed that only FeCr2O4 with low compactness was generated under anoxic and acidic conditions in the new process. And it is evident that the formation of the passivation layer which contains oxides and hydroxides (or (oxy)hydroxides) of iron and chromium were well hindered. Furthermore, the as-prepared nZVI has shown fast removal of traced Cr(VI) from the Cr-spiked drinking water or actual Cr-contaminated lake water. Accordingly, we proposed a new reaction process of Cr(VI) reduction by nZVI under anoxic condition. And we firstly make clear the detailed process of Cr(VI) removal by the as-prepared nZVI via X-ray photoelectron spectrometer (XPS) analysis in time scale. Meanwhile, the excellent Cr(VI) removal performance of the as-prepared nZVI could be attributed to (i) the high surface area, (ii) large quantity of active sites of nZVI, and (iii) fast electron transfer from the nZVI/FeCr2O4 to Cr (VI). The present work not only provides the potential materials for the application to the rapid and high-efficient removal of Cr(VI) from aqueous solution, but also proposed a new avenue for hindering the passivation of Fe-0. And a detailed mechanism of the Cr(VI) removal by nZVI was proposed for the first time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 335, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 945, "End Page": 953, "Article Number": null, "DOI": "10.1016/j.cej.2017.10.182", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2017.10.182", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430700500097", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, SL; Li, RF; Huang, H; Jiang, NZ; Lin, JD; Wang, SX; Zheng, YH; Chen, XY; Chen, DQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Shilin; Li, Renfu; Huang, Hai; Jiang, Naizhong; Lin, Jidong; Wang, Shaoxiong; Zheng, Yuanhui; Chen, Xueyuan; Chen, Daqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compact ultrabroadband light-emitting diodes based on lanthanide-doped lead-free double perovskites", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Impurity doping is an effective approach to tuning the optoelectronic performance of host materials by imparting extrinsic electronic channels. Herein, a family of lanthanide (Ln(3+)) ions was successfully incorporated into a Bi:Cs2AgInCl6 lead-free double-perovskite (DP) semiconductor, expanding the spectral range from visible (Vis) to near-infrared (NIR) and improving the photoluminescence quantum yield (PLQY). After multidoping with Nd, Yb, Er and Tm, Bi/Ln: Cs(2)AglnCl(6) yielded an ultrabroadband continuous emission spectrum with a full width at half-maximum of similar to 365 nm originating from intrinsic self-trapped exciton recombination and abundant 4f-4f transitions of the Ln(3+) dopants. Steady-state and transient-state spectra were used to ascertain the energy transfer and emissive processes. To avoid adverse energy interactions between the various Ln(3+) ions in a single DP host, a heterogeneous architecture was designed to spatially confine different Ln(3+) dopants via a DP-in-glass composite (DiG) structure. This bottom-up strategy endowed the prepared Ln(3+) -doped DIG with a high PLQY of 40% (nearly three times as high as that of the multidoped DP) and superior long-term stability. Finally, a compact Vis-NIR ultrabroadband (400 similar to 2000 nm) light source was easily fabricated by coupling the DiG with a commercial UV LED chip, and this light source has promising applications in nondestructive spectroscopic analyses and multifunctional lighting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 52, "DOI": "10.1038/s41377-022-00739-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00739-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765794100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, BY; Wei, ZH; Sui, LZ; Yu, JK; Zhang, BW; Wang, XY; Feng, SN; Song, HQ; Yong, X; Tian, YX; Yang, B; Lu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Boyang; Wei, Zhihong; Sui, Laizhi; Yu, Jingkun; Zhang, Baowei; Wang, Xiaoyong; Feng, Shengnull; Song, Haoqiang; Yong, Xue; Tian, Yuxi; Yang, Bai; Lu, Siyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-phonon coupling-assisted universal red luminescence of o-phenylenediamine-based carbon dots", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the complex core-shell structure and variety of surface functional groups, the photoluminescence (PL) mechanism of carbon dots (CDs) remain unclear. o-Phenylenediamine (oPD), as one of the most common precursors for preparing red emissive CDs, has been extensively studied. Interestingly, most of the red emission CDs based on oPD have similar PL emission characteristics. Herein, we prepared six different oPD-based CDs and found that they had almost the same PL emission and absorption spectra after purification. Structural and spectral characterization indicated that they had similar carbon core structures but different surface polymer shells. Furthermore, single-molecule PL spectroscopy confirmed that the multi-modal emission of those CDs originated from the transitions of different vibrational energy levels of the same PL center in the carbon core. In addition, the phenomenon of spectral splitting of single-particle CDs was observed at low temperature, which confirmed these oPD-based CDs were unique materials with properties of both organic molecules and quantum dots. Finally, theoretical calculations revealed their potential polymerization mode and carbon core structure. Moreover, we proposed the PL mechanism of red-emitting CDs based on oPD precursors; that is, the carbon core regulates the PL emission, and the polymer shell regulates the PL intensity. Our work resolves the controversy on the PL mechanism of oPD-based red CDs. These findings provide a general guide for the mechanism exploration and structural analysis of other types of CDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 172, "DOI": "10.1038/s41377-022-00865-x", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00865-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806755400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, XS; Yang, J; Li, SQ; Liu, ZZ; Hu, ZP; Hao, JY; Du, J; Leng, YX; Qin, HY; Lin, X; Lin, Y; Tian, YX; Zhou, M; Xiong, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Xiaosheng; Yang, Jie; Li, Shiqi; Liu, Zhengzheng; Hu, Zhiping; Hao, Jiongyue; Du, Juan; Leng, Yuxin; Qin, Haiyan; Lin, Xing; Lin, Yue; Tian, Yuxi; Zhou, Miao; Xiong, Qihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single Halide Perovskite/Semiconductor Core/Shell Quantum Dots with Ultrastability and Nonblinking Properties", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The further practical applications of halide perovskite quantum dots (QDs) are blocked by problems of instability and nonradiative Auger recombination manifested as photoluminescence blinking. Here, single core/shell structured perovskite semiconductor QDs are successfully fabricated by capping CsPbBr3 QD core with CdS shell. It is demonstrated that CsPbBr3/CdS core/shell QDs exhibit ultrahigh chemical stability and nonblinking photoluminescence with high quantum yield due to the reduced electronic traps within the core/shell structure. Efficiency of amplified spontaneous emission exhibits obvious enhancement compared to that of pure CsPbBr3 QDs, originating from the mitigated competition between stimulated emission and suppressed nonradiative biexciton Auger recombination. Furthermore, low-threshold whispering-gallery-mode lasing with a high-quality factor is achieved by incorporating CsPbBr3/CdS QDs into microtubule resonators. Density functional theory (DFT)-based first-principles calculations are also performed to reveal the atomic interface structure, which supports the existence of CsPbBr3/CdS structure. An interesting feature of spatially separated charge density at CsPbBr3/CdS interface is found, which may greatly contribute to the suppressed Auger recombination. The results provide a practical approach to improve the stability and suppress the blinking of halide perovskite QDs, which may pave the way for future applications for various optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 6, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900412, "DOI": "10.1002/advs.201900412", "DOI Link": "http://dx.doi.org/10.1002/advs.201900412", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473535000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; Lou, SF; Li, S; Yu, ZJ; Liu, QS; Dai, A; Cao, CT; Toney, MF; Ge, MY; Xiao, XH; Lee, WK; Yao, YD; Deng, JJ; Liu, TC; Tang, YP; Yin, GP; Lu, J; Su, D; Wang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fang; Lou, Shuaifeng; Li, Shuang; Yu, Zhenjiang; Liu, Qingsong; Dai, Alvin; Cao, Chuntian; Toney, Michael F.; Ge, Mingyuan; Xiao, Xianghui; Lee, Wah-Keat; Yao, Yudong; Deng, Junjing; Liu, Tongchao; Tang, Yiping; Yin, Geping; Lu, Jun; Su, Dong; Wang, Jiajun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-crystal cathode materials for lithium-ion batteries have attracted increasing interest in providing greater capacity retention than their polycrystalline counterparts. However, after being cycled at high voltages, these single-crystal materials exhibit severe structural instability and capacity fade. Understanding how the surface structural changes determine the performance degradation over cycling is crucial, but remains elusive. Here, we investigate the correlation of the surface structure, internal strain, and capacity deterioration by using operando X-ray spectroscopy imaging and nullo-tomography. We directly observe a close correlation between surface chemistry and phase distribution from homogeneity to heterogeneity, which induces heterogeneous internal strain within the particle and the resulting structural/performance degradation during cycling. We also discover that surface chemistry can significantly enhance the cyclic performance. Our modified process effectively regulates the performance fade issue of single-crystal cathode and provides new insights for improved design of high-capacity battery materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3050, "DOI": "10.1038/s41467-020-16824-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16824-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542988800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amanchukwu, CV; Yu, Z; Kong, X; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amanchukwu, Chibueze, V; Yu, Zhiao; Kong, Xian; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Class of Ionically Conducting Fluorinated Ether Electrolytes with High Electrochemical Stability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing battery energy density is greatly desired for applications such as portable electronics and transportation. However, many next-generation batteries are limited by electrolyte selection because high ionic conductivity and poor electrochemical stability are typically observed in most electrolytes. For example, ether-based electrolytes have high ionic conductivity but are oxidatively unstable above 4 V, which prevents the use of high-voltage cathodes that promise higher energy densities. In contrast, hydrofluoroethers (HFEs) have high oxidative stability but do not dissolve lithium salt. In this work, we synthesize a new class of fluorinated ether electrolytes that combine the oxidative stability of HFEs with the ionic conductivity of ethers in a single compound. We show that conductivities of up to 2.7 x 10(-4) S/cm (at 30 degrees C) can be obtained with oxidative stability up to 5.6 V. The compounds also show higher lithium transference numbers compared to typical ethers. Furthermore, we use nuclear magnetic resonullce (NMR) and molecular dynamics (MD) to study their ionic transport behavior and ion solvation environment, respectively. Finally, we demonstrate that this new class of electrolytes can be used with a Ni-rich layered cathode (NMC 811) to obtain over 100 cycles at a C/5 rate. The design of new molecules with high ionic conductivity and high electrochemical stability is a novel approach for the rational design of next-generation batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2020, "Volume": 142, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7393, "End Page": 7403, "Article Number": null, "DOI": "10.1021/jacs.9b11056", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b11056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529156100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, Q; Liang, F; Li, XB; Gao, YJ; Huang, MY; Wang, Y; Xia, SG; Gao, XY; Gan, QC; Lin, ZS; Tung, CH; Wu, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Qing; Liang, Fei; Li, Xu-Bing; Gao, Yu-Ji; Huang, Mao-Yong; Wang, Yang; Xia, Shu-Guang; Gao, Xiao-Ya; Gan, Qi-Chao; Lin, Zhe-Shuai; Tung, Chen-Ho; Wu, Li-Zhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and Selective CO2 Reduction Integrated with Organic Synthesis by Solar Energy", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven catalytic CO2 reduction is attractive to produce usable fuels and value-added chemicals. However, conventional strategies suffer from low activity and/or expense of sacrificial reagents. Here, we describe the first example of CO2 reduction integrated with the oxidative organic synthesis by solar energy. With visible-light irradiation, CdSe/CdS quantum dots (QDs) enable photocatalytic conversion of CO2 to CO with an exciting rate of similar to 412.8 mmol g(-1) h(-1) and a high selectivity of > 96% in the presence of triethylamine. More importantly, CO2-to-CO conversion proceeds smoothly when integrated with oxidative coupling of 1-Phenylethanol to evolve pinacol. 1-Phenylethanol with electron-donating groups at the p-position of aryl ring, for example, is converted to corresponding pinacols with excellent yields up to 98%. The released protons and electrons of oxidative half-reaction are used for CO2 reduction. Apparently, this strategy provides the exact answer toward cost-effective CO2 photoreduction and opens a new horizon for efficient solar-to-fuel conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2605, "End Page": 2616, "Article Number": null, "DOI": "10.1016/j.chempr.2019.06.019", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.06.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489631400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LQ; Zhang, MJ; Guo, HL; Tian, ZH; Ge, LF; He, GJ; Huang, JJ; Wang, JT; Liu, TX; Parkin, IP; Lai, FL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Leiqian; Zhang, Mingjie; Guo, Hele; Tian, Zhihong; Ge, Lingfeng; He, Guanjie; Huang, Jiajia; Wang, Jingtao; Liu, Tianxi; Parkin, Ivan P.; Lai, Feili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Universal Polyiodide Regulation Using Quaternization Engineering toward High Value-Added and Ultra-Stable Zinc-Iodine Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of aqueous rechargeable zinc-iodine (Zn-I-2) batteries is still plagued by the polyiodide shuttle issue, which frequently causes batteries to have inadequate cycle lifetimes. In this study, quaternization engineering based on the concept of electric double layer is developed on a commercial acrylic fiber skeleton ($1.55-1.7 kg(-1)) to precisely constrain the polyiodide and enhance the cycling durability of Zn-I-2 batteries. Consequently, a high-rate (1 C-146.1 mAh g(-1), 10 C-133.8 mAh g(-1)) as well as, ultra-stable (2000 cycles at 20 C with 97.24% capacity retention) polymer-based Zn-I-2 battery is reported. These traits are derived from the strong electrostatic interaction generated by quaternization engineering, which significantly eliminates the polyiodide shuttle issue and simultaneously realizes peculiar solution-based iodine chemistry (I-/I-3(-)) in Zn-I-2 batteries. The quaternization strategy also presents high practicability, reliability, and extensibility in various complicated environments. In particular, cutting-edge Zn-I-2 batteries based on the concept of derivative material (commercially available quaternized resin) demonstrate approximate to 100% capacity retention over 17 000 cycles at 20 C. This work provides a general and fresh insight into the design and development of large-scale, low-cost, and high-performance zinc-iodine batteries, as well as, other novel iodine storage systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105598, "DOI": "10.1002/advs.202105598", "DOI Link": "http://dx.doi.org/10.1002/advs.202105598", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765253400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ping, Y; Nielsen, RJ; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ping, Yuan; Nielsen, Robert J.; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Reaction Mechanism with Free Energy Barriers at Constant Potentials for the Oxygen Evolution Reaction at the IrO2 (110) Surface", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "How to efficiently oxidize H2O to O-2 (oxygen evolution reaction, OER) in photoelectrochemical cells (PEC) is a great challenge due to its complex charge transfer process, high overpotential, and corrosion. So far no OER mechanism has been fully explained atomistically with both thermodynamic and kinetics. IrO2 is the only known OER catalyst with both high catalytic activity and stability in acidic conditions. This is important because PEC experiments often operate at extreme pH conditions. In this work, we performed first-principles calculations integrated with implicit solvation at constant potentials to examine the detailed atomistic reaction mechanism of OER at the IrO2 (110) surface. We determined the surface phase diagram, explored the possible reaction pathways including kinetic barriers, and computed reaction rates based on the microkinetic models. This allowed us to resolve several long-standing puzzles about the atomistic OER mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2017, "Volume": 139, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 149, "End Page": 155, "Article Number": null, "DOI": "10.1021/jacs.6b07557", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b07557", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392036900031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, RC; Zhang, MQ; Hu, CQ; Xiao, DQ; Wang, M; Ma, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Ruochen; Zhang, Mei-Qi; Hu, Chaoquan; Xiao, Dequan; Wang, Meng; Ma, Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic oxidation of polystyrene to aromatic oxygenates over a graphitic carbon nitride catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The continuous increase in manufacturing coupled with the difficulty of recycling of plastic products has generated huge amounts of waste plastics. Most of the existing chemical recycling and upcycling methods suffer from harsh conditions and poor product selectivity. Here we demonstrate a photocatalytic method to oxidize polystyrene to aromatic oxygenates under visible light irradiation using heterogeneous graphitic carbon nitride catalysts. Benzoic acid, acetophenone, and benzaldehyde are the dominullt products in the liquid phase when the conversion of polystyrene reaches >90% at 150 degrees C. For the transformation of 0.5 g polystyrene plastic waste, 0.36 g of the aromatic oxygenates is obtained. The reaction mechanism is also investigated with various characterization methods and procedes via polystyrene activation to form hydroxyl and carbonyl groups over its backbone via C-H bond oxidation which is followed by oxidative bond breakage via C-C activation and further oxidation processes to aromatic oxygenates. There is a real need to create materials capable of plastic recycling and upcycling. Here, the authors report a heterogeneous carbon nitride photocatalyst which efficiently converts polystyrene plastics into aromatic oxygenates, such as benzoic acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4809, "DOI": "10.1038/s41467-022-32510-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32510-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000841396400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motagamwala, AH; Won, WY; Sener, C; Alonso, DM; Maravelias, CT; Dumesic, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motagamwala, Ali Hussain; Won, Wangyun; Sener, Canull; Alonso, David Martin; Maravelias, Christos T.; Dumesic, James A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward biomass-derived renewable plastics: Production of 2,5-furandicarboxylic acid from fructose", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a process for converting fructose, at a high concentration (15 weight %), to 2,5-furandicarboxylic acid (FDCA), a monomer used in the production of polyethylene furanoate, a renewable plastic. In our process, fructose is dehydrated to hydroxymethylfurfural (HMF) at high yields (70%) using a g-valerolactone (GVL)/H2O solvent system. HMF is subsequently oxidized to FDCA over a Pt/C catalyst with 93% yield. The advantage of our system is the higher solubility of FDCA in GVL/H2O, which allows oxidation at high concentrations using a heterogeneous catalyst that eliminates the need for a homogeneous base. In addition, FDCA can be separated from the GVL/H2O solvent system by crystallization to obtain >99% pure FDCA. Our process eliminates the use of corrosive acids, because FDCA is an effective catalyst for fructose dehydration, leading to improved economic and environmental impact of the process. Our techno-economic model indicates that the overall process is economically competitive with current terephthalic acid processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaap9722", "DOI": "10.1126/sciadv.aap9722", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aap9722", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426694200066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vanapalli, KR; Sharma, HB; Ranjan, VP; Samal, B; Bhattacharya, J; Dubey, BK; Goel, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vanapalli, Kumar Raja; Sharma, Hari Bhakta; Ranjan, Ved Prakash; Samal, Biswajit; Bhattacharya, Jayanta; Dubey, Brajesh K.; Goel, Sudha", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and strategies for effective plastic waste management during and post COVID-19 pandemic", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of the COVID-19 pandemic has enhanced the complexities of plastic waste management. Our improved, hyper-hygienic way of life in the fear of transmission has conveniently shifted our behavioral patterns like the use of PPE (Personal protective equipment), increased demand for plastic-packaged food and groceries, and the use of disposable utensils. The inadequacies and inefficiencies of our current waste management system to deal with the increased dependence on plastic could aggravate its mismanagement and leakage into the environment, thus triggering a new environmental crisis. Mandating scientific sterilization and the use of sealed bags for safe disposal of contaminated plastic wastes should be an immediate priority to reduce the risk of transmission to sanitation workers. Investments in circular technologies like feedstock recycling, improving the infrastructure and environmental viability of existing techniques could be the key to dealing with the plastic waste fluxes during such a crisis. Transition towards environmentally friendly materials like bioplastics and harboring new sustainable technologies would be crucial to fighting future pandemics. Although the rollbacks and relaxation of single-use plastic bans may be temporary, their likely implications on the consumer perception could hinder our long-term goals of transitioning towards a circular economy. Likewise, any delay in building international willingness and participation to curb any form of pollution through summits and agendas may also delay its implementation. Reduction in plastic pollution and at the same time promoting sustainable plastic waste management technologies can be achieved by prioritizing our policies to instill individual behavioral as well as social, institutional changes. Incentivizing measures that encourage circularity and sustainable practices, and public-private investments in research, infrastructure and marketing would help in bringing the aforementioned changes. Individual responsibility, corporate action, and government policy are all necessary to keep us from transitioning from one disaster to another. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 750, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141514, "DOI": "10.1016/j.scitotenv.2020.141514", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2020.141514", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000585694600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, SW; Yang, Y; Lee, HW; Ghasemi, H; Kraemer, D; Chen, G; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Seok Woo; Yang, Yuan; Lee, Hyun-Wook; Ghasemi, Hadi; Kraemer, Daniel; Chen, Gang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An electrochemical system for efficiently harvesting low-grade heat energy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient and low-cost thermal energy-harvesting systems are needed to utilize the tremendous low-grade heat sources. Although thermoelectric devices are attractive, its efficiency is limited by the relatively low figure-of-merit and low-temperature differential. An alternative approach is to explore thermodynamic cycles. Thermogalvanic effect, the dependence of electrode potential on temperature, can construct such cycles. In one cycle, an electrochemical cell is charged at a temperature and then discharged at a different temperature with higher cell voltage, thereby converting heat to electricity. Here we report an electrochemical system using a copper hexacyanoferrate cathode and a Cu/Cu2+ anode to convert heat into electricity. The electrode materials have low polarization, high charge capacity, moderate temperature coefficients and low specific heat. These features lead to a high heat-to-electricity energy conversion efficiency of 5.7% when cycled between 10 and 60 degrees C, opening a promising way to utilize low-grade heat.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3942, "DOI": "10.1038/ncomms4942", "DOI Link": "http://dx.doi.org/10.1038/ncomms4942", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337505600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khazaei, M; Arai, M; Sasaki, T; Ranjbar, A; Liang, YY; Yunoki, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khazaei, Mohammad; Arai, Masao; Sasaki, Taizo; Ranjbar, Ahmad; Liang, Yunye; Yunoki, Seiji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "OH-terminated two-dimensional transition metal carbides and nitrides as ultralow work function materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a set of two-dimensional transition metal carbides and nitrides that offer many potential applications in energy storage and electronic devices. As an important parameter to design new electronic devices, we investigate the work functions of bare MXenes and their functionalized ones with F, OH, and O chemical groups using first-principles calculations. From our calculations, it turns out that the OH-terminated MXenes attain ultralow work functions between 1.6 and 2.8 eV. Moreover, depending on the type of the transition metal, the F or O functionalization affects increasing or decreasing the work functions. We show that the changes in the work functions upon functionalizations are linearly correlated with the changes in the surface dipole moments. It is shown that the work functions of the F- or O-terminated MXenes are controlled by two factors: the induced dipole moments by the charge transfers between F/O and the substrate, and the changes in the total surface dipole moments caused by surface relaxation upon the functionalization. However, in the cases of the OH-terminated MXenes, in addition to these two factors, the intrinsic dipole moments of the OH groups play an important role in determining the total dipole moments and consequently justify their ultralow work functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2015, "Volume": 92, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75411, "DOI": "10.1103/PhysRevB.92.075411", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.075411", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359344100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, K; Luo, JS; Zhou, C; Zhang, T; Arbiol, J; Lu, XH; Mao, BW; Zhang, X; Fransaer, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Kai; Luo, Jiangshui; Zhou, Chen; Zhang, Ting; Arbiol, Jordi; Lu, Xihong; Mao, Bing-Wei; Zhang, Xuan; Fransaer, Jan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Porous Ni3S4 with Enriched High-Valence Ni Sites as a Robust Electrocatalyst for Efficient Oxygen Evolution Reaction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting is a common way to produce hydrogen gas, but the sluggish kinetics of the oxygen evolution reaction (OER) significantly limits the overall energy conversion efficiency of water splitting. In this work, a highly active and stable, meso-macro hierarchical porous Ni3S4 architecture, enriched in Ni3+ is designed as an advanced electrocatalyst for OER. The obtained Ni3S4 architectures exhibit a relatively low overpotential of 257 mV at 10 mA cm(-2) and 300 mV at 50 mA cm(-2). Additionally, this Ni3S4 catalyst has excellent long-term stability (no degradation after 300 h at 50 mA cm(-2)). The outstanding OER performance is due to the high concentration of Ni3+ and the meso-macro hierarchical porous structure. The presence of Ni3+ enhances the chemisorption of OH-, which facilitates electron transfer to the surface during OER. The hierarchical porosity increases the number of exposed active sites, and facilitates mass transport. A water-splitting electrolyzer using the prepared Ni3S4 as the anode catalyst and Pt/C as the cathode catalyst achieves a low cell voltage of 1.51 V at 10 mA cm(-2). Therefore, this work provides a new strategy for the rational design of highly active OER electrocatalysts with high valence Ni3+ and hierarchical porous architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2019, "Volume": 29, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900315, "DOI": "10.1002/adfm.201900315", "DOI Link": "http://dx.doi.org/10.1002/adfm.201900315", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471330500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Sato, N; Gao, WH; Yubuta, K; Kawamoto, N; Mitome, M; Kurashima, K; Owada, Y; Nagase, K; Lee, CH; Yi, J; Tsuchiya, K; Mori, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zihang; Sato, Naoki; Gao, Weihong; Yubuta, Kunio; Kawamoto, Naoyuki; Mitome, Masanori; Kurashima, Keiji; Owada, Yuka; Nagase, Kazuo; Lee, Chul-Ho; Yi, Jangho; Tsuchiya, Koichi; Mori, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Demonstration of ultrahigh thermoelectric efficiency of ∼7.3% in Mg3Sb2/MgAgSb module for low-temperature energy harvesting", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric harvesting of low-temperature waste heat offers great opportunities for sustainable energy production. However, the investigations of related thermoelectric materials and modules remain sluggish. Here, we reported a great advance in the n-type Mg3Sb1.5Bi0.5 system by minor Cu additions. Some Cu atoms preferentially occupy interstitial sites within the Mg3Sb2 lattice and significantly modified phonon modes via filling in the phonon gap and increased anharmonic phonon scattering, thereby leading to the anomalously low thermal conductivity. Simultaneously, the detrimental behavior of thermally activated electrical conductivity was completely eliminated through grain-boundary complexion engineering. These two critical roles contributed to the remarkable improvement of zT Based on this developed high-performance material coupled with p-type alpha-MgAgSb-based material, a fabricated thermoelectric module rivaling long-time champion Bi2Te3, demonstrated a record-high conversion efficiency 7,3% at the hot-side temperature of 593 K. These results pave the way for low-temperature thermoelectric harvesting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2021, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1196, "End Page": 1208, "Article Number": null, "DOI": "10.1016/j.joule.2021.03.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.03.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654225600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Malko, D; Kucernak, A; Lopes, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Malko, Daniel; Kucernak, Anthony; Lopes, Thiago", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ electrochemical quantification of active sites in Fe-N/C non-precious metal catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The economic viability of low temperature fuel cells as clean energy devices is enhanced by the development of inexpensive oxygen reduction reaction catalysts. Heat treated iron and nitrogen containing carbon based materials (Fe-N/C) have shown potential to replace expensive precious metals. Although significant improvements have recently been made, their activity and durability is still unsatisfactory. The further development and a rational design of these materials has stalled due to the lack of an in situ methodology to easily probe and quantify the active site. Here we demonstrate a protocol that allows the quantification of active centres, which operate under acidic conditions, by means of nitrite adsorption followed by reductive stripping, and show direct correlation to the catalytic activity. The method is demonstrated for two differently prepared materials. This approach may allow researchers to easily assess the active site density and turnover frequency of Fe-N/C catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13285, "DOI": "10.1038/ncomms13285", "DOI Link": "http://dx.doi.org/10.1038/ncomms13285", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386455900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cook, JB; Kim, HS; Yan, Y; Ko, JS; Robbennolt, S; Dunn, B; Tolbert, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cook, John B.; Kim, Hyung-Seok; Yan, Yan; Ko, Jesse S.; Robbennolt, Shauna; Dunn, Bruce; Tolbert, Sarah H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous MoS2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na-Ion Charge Storage", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ion insertion properties of MoS2 continue to be of widespread interest for energy storage. While much of the current work on MoS2 has been focused on the high capacity four-electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g(-1) for Li-ions and 118 mAh g(-1) for Na-ions at 1 mV s(-1). Utilizing synchrotron grazing incidence X-ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso-oriented crystal structure. When Li-ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g(-1). Moreover, the nulloscale architecture of mesoporous MoS2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS2 is due to a pseudocapacitive mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2016, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501937, "DOI": "10.1002/aenm.201501937", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501937", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379306400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Comesaña-Gándara, B; Chen, J; Bezzu, CG; Carta, M; Rose, I; Ferrari, MC; Esposito, E; Fuoco, A; Jansen, JC; McKeown, NB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Comesana-Gandara, Bibiana; Chen, Jie; Bezzu, C. Grazia; Carta, Mariolino; Rose, Ian; Ferrari, Maria-Chiara; Esposito, Elisa; Fuoco, Alessio; Jansen, Johannes C.; McKeown, Neil B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redefining the Robeson upper bounds for CO2/CH4 and CO2/N2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membranes composed of Polymers of Intrinsic Microporosity (PIMs) have the potential for energy efficient industrial gas separations. Here we report the synthesis and gas permeability data of a series of ultrapermeable PIMs, of two-dimensional chain conformation and based on benzotriptycene structural units, that demonstrate remarkable ideal selectivity for most gas pairs of importance. In particular, the CO2 ultrapermeability and high selectivity for CO2 over CH4, of key importance for the upgrading of natural gas and biogas, and for CO2 over N2, of importance for cost-effective carbon capture from power plants, exceed the performance of the current state-of-the-art polymers. All of the gas permeability data from this series of benzotriptycene-based PIMs are placed well above the current 2008 Robeson upper bounds for CO2/CH4 and CO2/N2. Indeed, the data for some of these polymers fall into a linear correlation on the benchmark Robeson plots [i.e. log(PCO2/PCH4) versus log PCO2 and log(PCO2/PN2) versus log PCO2], which are parallel to, but significantly above, that of the 2008 CO2/CH4 and CO2/N2 upper bounds, allowing their revision. The redefinition of these upper bounds sets new aspirational targets for polymer chemists to aim for and will result in more attractive parametric estimates of energy and cost efficiencies for carbon capture and natural/bio gas upgrading using state-of-the-art CO2 separation membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 611, "Times Cited, All Databases": 641, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2733, "End Page": 2740, "Article Number": null, "DOI": "10.1039/c9ee01384a", "DOI Link": "http://dx.doi.org/10.1039/c9ee01384a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486019600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krauskopf, T; Dippel, R; Hartmann, H; Peppler, K; Mogwitz, B; Richter, FH; Zeier, WG; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krauskopf, Thorben; Dippel, Rabea; Hartmann, Hannah; Peppler, Klaus; Mogwitz, Boris; Richter, Felix H.; Zeier, Wolfgang G.; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium-Metal Growth Kinetics on LLZO Garnet-Type Solid Electrolytes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li7La3Zr2O12 (LLZO)-based garnet materials are recently being investigated as suitable electrolytes for solid-state batteries with lithium-metal electrodes. Unfortunately, lithium-metal penetration through polycrystalline garnet-type electrolytes limits the electric current density during cell charging. In this study, we introduce an electrochemical operando approach that is well suited to get insights into the early stage of lithium-metal penetration that was yet only accessible with very elaborate neutron measurements. Combined with in situ as well as ex situ electron microscopic techniques, we investigate the morphological instability of the lithium-metal anode on garnet-type solid electrolytes under cathodic load and demonstrate the inter-relationship between microkinetic aspects and lithium-penetration susceptibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2019, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2030, "End Page": 2049, "Article Number": null, "DOI": "10.1016/j.joule.2019.06.013", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.06.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482204600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, F; Xue, YJ; Wang, FL; Guo, DN; He, YJ; Zhao, X; Yan, FY; Xu, YQ; Xia, DD; Liu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Fan; Xue, Yijia; Wang, Feilong; Guo, Danni; He, Yunjiao; Zhao, Xiao; Yan, Fanyu; Xu, Yuqian; Xia, Dandan; Liu, Yunsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustained release of magnesium and zinc ions synergistically accelerates wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin wounds are a major medical challenge that threaten human health. Functional hydrogel dressings demonstrate great potential to promote wound healing. In this study, magnesium (Mg) and zinc (Zn) are introduced into methacrylate gelatin (GelMA) hydrogel via low-temperature magnetic stirring and photocuring, and their effects on skin wounds and the underlying mechanisms are investigated. Degradation testing confirmed that the GelMA/Mg/Zn hydrogel released magnesium ions (Mg2+) and zinc ions (Zn2+) in a sustained manner. The Mg2+ and Zn2+ not only enhanced the migration of human skin fibroblasts (HSFs) and human immortalized keratinocytes (HaCats), but also promoted the transformation of HSFs into myofibroblasts and accelerated the production and remodeling of extracellular matrix. Moreover, the GelMA/Mg/Zn hydrogel enhanced the healing of full-thickness skin defects in rats via accelerated collagen deposition, angiogenesis and skin wound re-epithelialization. We also identified the mechanisms through which GelMA/Mg/Zn hydrogel promoted wound healing: the Mg2+ promoted Zn2+ entry into HSFs and increased the concentration of Zn2+ in HSFs, which effectively induced HSFs to differentiate into myofibroblasts by activating the STAT3 signaling pathway. The synergistic effect of Mg2+ and Zn2+ promoted wound healing. In conclusion, our study provides a promising strategy for skin wounds regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 88, "End Page": 101, "Article Number": null, "DOI": "10.1016/j.bioactmat.2023.02.019", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2023.02.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972604000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jian, WR; Xie, ZC; Xu, SZ; Su, YQ; Yao, XH; Beyerlein, IJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jian, Wu-Rong; Xie, Zhuocheng; Xu, Shuozhi; Su, Yanqing; Yao, Xiaohu; Beyerlein, Irene J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of lattice distortion and chemical short-range order on the mechanisms of deformation in medium entropy alloy CoCrNi", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the numbers of medium- to high-entropy alloys being studied and impressive structural properties they exhibit increase rapidly, questions regarding the role played by their complex chemical fluctuations rise concomitantly. Here, using a combination of large-scale molecular dynamics (MD), a hybrid MD and Monte-Carlo simulation method, and crystal defect analysis, we investigate the role lattice distortion (LD) and chemical short-range order (CSRO) play in the nucleation and evolution of dislocations and nullotwins with straining in single crystal and nullocrystalline CoCrNi, a medium entropy alloy (MEA). LD and CSRO effects are elucidated by comparisons with responses from a hypothetical pure A-atom alloy, which bears the same bulk properties of the nominal MEA but no LD and no CSRO. The analysis reveals that yield strengths are determined by the strain to nucleate Shockley partial dislocations, and LD lowers this strain, while higher degrees of CSRO increase it. We show that while these partials prefer to nucleate in the CoCr clusters, regardless of their size, they find it increasingly difficult to propagate away from these sites as the level of CSRO increases. After yield, nullotwin nucleation occurs via reactions of mobile Shockley partials and is promoted in MEAs, due to the enhanced glide resistance resulting from LD and CSRO. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2020, "Volume": 199, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 352, "End Page": 369, "Article Number": null, "DOI": "10.1016/j.actamat.2020.08.044", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.08.044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577997400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Flynn, JM; Shokrani, A; Newman, ST; Dhokia, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Flynn, Joseph M.; Shokrani, Alborz; Newman, Stephen T.; Dhokia, Vimal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid additive and subtractive machine tools - Research and industrial developments", "Source Title": "INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By synergistically combining additive and subtractive processes within a single workstation, the relative merits of each process may be harnessed. This facilitates the manufacture of internal, overhanging and high aspect ratio features with desirable geometric accuracy and surface characteristics. The ability to work, measure and then rework material enables the reincarnation and repair of damaged, high-value components. These techniques present significant opportunities to improve material utilisation, part complexity and quality management in functional parts. The number of single platform workstations for hybrid additive and subtractive processes (WHASPs) is increasing. Many of these integrate additive directed energy deposition (DED) with subtractive CNC machining within a highly mobile multi-axis machine tool. Advanced numerical control (NC), and computer aided design (CAD), manufacture (CAM) and inspection (CAI) help to govern the process. This research reviews and critically discusses salient published literature relating to the development of WHASPs, and identifies future avenues for research and development. It reports on state-of-the-art WHASP systems, identifying key traits and research gaps. Finally, a future vision for WHASPs and other hybrid machine tools is presented based upon emerging trends and future opportunities within this research area. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 101, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 79, "End Page": 101, "Article Number": null, "DOI": "10.1016/j.ijmachtools.2015.11.007", "DOI Link": "http://dx.doi.org/10.1016/j.ijmachtools.2015.11.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369555500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Zhou, F; Zhang, S; Liang, YY; Wang, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xing; Zhou, Feng; Zhang, Shen; Liang, Yongye; Wang, Ruihu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering MoS2 Basal Planes for Hydrogen Evolution via Synergistic Ruthenium Doping and nullocarbon Hybridization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Promoting the intrinsic activity and accessibility of basal plane sites in 2D layered metal dichalcogenides is desirable to optimize their catalytic performance for energy conversion and storage. Herein, a core/shell structured hybrid catalyst, which features few-layered ruthenium (Ru)-doped molybdenum disulfide (MoS2) nullosheets closely sheathing around multiwalled carbon nullotube (CNT), for highly efficient hydrogen evolution reaction (HER) is reported. With 5 at% (atomic percent) Ru substituting for Mo in MoS2, Ru-MoS2/CNT achieves the optimum HER activity, which displays a small overpotential of 50 mV at -10 mA cm(-2) and a low Tafel slope of 62 mV dec(-1) in 1 M KOH. Theoretical simulations reveal that Ru substituting for Mo in coordination with six S atoms is thermodynamically stable, and the in-plane S atoms neighboring Ru dopants represent new active centers for facilitating water adsorption, dissociation, and hydrogen adsorption/desorption. This work provides a multiscale structural and electronic engineering strategy for synergistically enhancing the HER activity of transition metal dichalcogenides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2019, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900090, "DOI": "10.1002/advs.201900090", "DOI Link": "http://dx.doi.org/10.1002/advs.201900090", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468187200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, H; Park, J; Park, I; Jin, K; Jerng, SE; Kim, SH; Nam, KT; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyunah; Park, Jimin; Park, Inchul; Jin, Kyoungsuk; Jerng, Sung Eun; Kim, Sun Hee; Nam, Ki Tae; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination tuning of cobalt phosphates towards efficient water oxidation catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient and stable water oxidation catalysts is necessary for the realization of practically viable water-splitting systems. Although extensive studies have focused on the metal-oxide catalysts, the effect of metal coordination on the catalytic ability remains still elusive. Here we select four cobalt-based phosphate catalysts with various cobalt-and phosphate-group coordination as a platform to better understand the catalytic activity of cobalt-based materials. Although they exhibit various catalytic activities and stabilities during water oxidation, Na2CoP2O7 with distorted cobalt tetrahedral geometry shows high activity comparable to that of amorphous cobalt phosphate under neutral conditions, along with high structural stability. First-principles calculations suggest that the surface reorganization by the pyrophosphate ligand induces a highly distorted tetrahedral geometry, where water molecules can favourably bind, resulting in a low overpotential (similar to 0.42 eV). Our findings emphasize the importance of local cobalt coordination in the catalysis and suggest the possible effect of polyanions on the water oxidation chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8253, "DOI": "10.1038/ncomms9253", "DOI Link": "http://dx.doi.org/10.1038/ncomms9253", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363017500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, YC; Lee, KB; Song, H; Oh, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Ying Chuan; Lee, Kelvin Berm; Song, Hakhyeon; Oh, Jihun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating Local CO2 Concentration as a General Strategy for Enhancing C-C Coupling in CO2 Electroreduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flow electrolyzers based on gas-diffusion electrodes (GDEs) have been increasingly employed to advance toward industry-relevant electrochemical CO2 reduction reaction (CO2RR) performance, though fundamental understanding of the GDE system is still lacking. Here, we propose that regulating local CO2 concentration on copper (Cu) surfaces is an effective and general strategy to promote C-C coupling in CO2yRR. LocalCO(2) concentration could influence the surface coverage of *CO2, *H, and *CO, which affects the reaction pathways toward multi-carbon (C2+) products. Guided by mass-transport modeling, we have identified three approaches to modulate the local CO2 concentration in GDE-based electrolyzers: (1) catalyst layer structure, (2) feed CO2 concentration, and (3) feed flow rate. Utilizing Cu2O nulloparticles as the model catalysts, modulation of local CO2 concentration enabled an optimized faradaic efficiency toward C2+ products of up to 75.5% at 300 mA cm(-2) and C2+ partial current density of up to 342 mA cm(-2) in 1.0 M KHCO3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2020, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1104, "End Page": 1120, "Article Number": null, "DOI": "10.1016/j.joule.2020.03.013", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.03.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535806100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Li, YB; Lin, DC; Hsu, PC; Liu, BF; Yan, GB; Wu, T; Cui, Y; Chu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chong; Li, Yanbin; Lin, Dingchang; Hsu, Po-Chun; Liu, Bofei; Yan, Gangbin; Wu, Tong; Cui, Yi; Chu, Steven", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium Extraction from Seawater through Pulsed Electrochemical Intercalation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is highly attractive to develop efficient methods to directly extract Li from seawater to secure the supply of Li. However, high concentration of Na in the seawater poses a great challenge in Li extraction. Here, we developed pulsed-rest and pulse-rest-reverse pulse-rest electrochemical intercalation methods with TiO2-coated FePO4 electrodes for Li extraction. The method can lower the intercalation overpotential and successfully boost the Li selectivity. Moreover, the pulse-rest-reverse pulse-rest method can also promote electrode crystal structure stability during the co-intercalation of Li and Na and prolong the lifetime of the electrode. We demonstrated 10 cycles of successful and stable Li extraction with 1:1 of Li to Na recovery from authentic seawater, which is equivalent to the selectivity of similar to 1.8 x 10(4). Also, with lake water of higher initial Li/Na ratio of 1.6 x 10(-3), we achieved Li extraction with more than 50:1 of Li to Na recovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1459, "End Page": 1469, "Article Number": null, "DOI": "10.1016/j.joule.2020.05.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.05.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551427400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arbabi, A; Arbabi, E; Kamali, SM; Horie, Y; Han, S; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arbabi, Amir; Arbabi, Ehsan; Kamali, Seyedeh Mahsa; Horie, Yu; Han, Seunghoon; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Miniature optical planar camera based on a wide-angle metasurface doublet corrected for monochromatic aberrations", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical metasurfaces are two-dimensional arrays of nullo-scatterers that modify optical wavefronts at subwavelength spatial resolution. They are poised to revolutionize optics by enabling complex low-cost systems where multiple metasurfaces are lithographically stacked and integrated with electronics. For imaging applications, metasurface stacks can perform sophisticated image corrections and can be directly integrated with image sensors. Here we demonstrate this concept with a miniature flat camera integrating a monolithic metasurface lens doublet corrected for monochromatic aberrations, and an image sensor. The doublet lens, which acts as a fisheye photographic objective, has a small f-number of 0.9, an angle-of-view larger than 60 degrees x 60 degrees, and operates at 850 nm wavelength with 70% focusing efficiency. The camera exhibits nearly diffraction-limited image quality, which indicates the potential of this technology in the development of optical systems for microscopy, photography, and computer vision.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 589, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13682, "DOI": "10.1038/ncomms13682", "DOI Link": "http://dx.doi.org/10.1038/ncomms13682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388644100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LH; Cervenka, J; Watanabe, K; Taniguchi, T; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Lu Hua; Cervenka, Jiri; Watanabe, Kenji; Taniguchi, Takashi; Chen, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Oxidation Resistance of Atomically Thin Boron Nitride nullosheets", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Investigation of oxidation resistance of two-dimensional (2D) materials is critical for many of their applications because 2D materials could have higher oxidation kinetics than their bulk counterparts due to predominullt surface atoms and structural distortions. In this study, the oxidation behavior of high-quality boron nitride (BN) nullosheets of 1-4 layers thick has been examined by heating in air. Atomic force microscopy and Raman spectroscopy analyses reveal that monolayer BN nullosheets can sustain up to 850 degrees C, and the starting temperature of oxygen doping/oxidation of BN nullosheets only slightly increases with the increase of nullosheet layer and depends on heating conditions. Elongated etch lines are found on the oxidized monolayer BN nullosheets, suggesting that the BN nullosheets are first cut along the chemisorbed oxygen chains and then the oxidative etching grows perpendicularly to these cut lines. The stronger oxidation resistance of BN nullosheets makes them more preferable for high-temperature applications than graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 736, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1457, "End Page": 1462, "Article Number": null, "DOI": "10.1021/nn500059s", "DOI Link": "http://dx.doi.org/10.1021/nn500059s", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332059200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, HY; Gu, QF; Chen, B; Tang, C; Zheng, Y; Zhang, H; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Huanyu; Gu, Qinfen; Chen, Bo; Tang, Cheng; Zheng, Yao; Zhang, Hua; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Facile synthesis of single-crystal 2D layered transition-metal nitrides (TMNs) is of crucial importance for the development of forthcoming technologies, such as superconducting, electromagnetic interference shielding, and energy-related applications. However, the fabrication of TMNs with natural 2D layered structure is thermodynamically difficult, in which stringent synthesis constraints have limited the exploration of this important class of functional materials. Here, we employed alkali molten salts as catalysts to achieve facile and large-scale (over decagram) synthesis of a family of 2D layered TMNs, such as MoN1.2, WN1.5, and Mo0.7W0.3N1.2, under atmospheric pressure. Ex-situ experiments reveal that the molten salt can lower the formation energy of 2D layered TMNs by assuring a liquid-gas synthesis and forming a TMN-salt-TMN superstructure as an intermediate. The resultant 2D layered TMNs show superior performance in hydrogen evolution reaction, demonstrating the immense potential of 2D layered TMNs for energy-related applications and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 10", "Publication Year": 2020, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2382, "End Page": 2394, "Article Number": null, "DOI": "10.1016/j.chempr.2020.06.037", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.06.037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000575403300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, HM; Wang, JQ; Zhao, JH; Shen, BX; Shi, J; Huang, J; Wu, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Hongman; Wang, Jianqiao; Zhao, Jinhui; Shen, Boxiong; Shi, Jeffrey; Huang, Jun; Wu, Chunfei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual functional catalytic materials of Ni over Ce-modified CaO sorbents for integrated CO2 capture and conversion", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Excessive anthropogenic CO2 emission in the atmosphere is considered as one of the main contributions to the serious climate changes. However, with the growth of global economics, more fossil fuels will be consumed to feed the global activity, especially in developing countries. Thus, CO2 needs to be captured for storage or converted to fuels or value-added chemicals. Herein, we propose and demonstrate a one-pot method synthesized dual functional materials (DFMs), which contain a sorbent coupled with a catalyst component, allowing the sorbent regeneration and CO2 conversion to CO are performed simultaneously in a single reactor. This process requires no additional thermal energy for the regeneration of sorbents. In addition, CeO2 is incorporated into the DFMs to largely enhance the stability of the materials for the process, and the influence of different Ce loadings on the performance of integrated CO2 capture and conversion is studied. It is found that the DFMs with a Ca/Ni/Ce molar ratio of 1:0.1:0.033 displays almost 100% CO selectivity and 51.8% CO2 conversion in the reverse water-gas shift (RWGS) reaction and a remarkable cyclic stability after 20 cycles of integrated CO2 capture and conversion. Therefore, the incorporation of Ce into DFMs has two profits, for one thing, the oxygen vacancies generated by CeO2 directly reduces the dissociated CO2 regenerated from the DFMs, demonstrating the high CO yield; for another, the well-dispersed CeO2, which could act as a physical barrier, effectively prevents the growth and agglomeration of CaO crystallite and NiO species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2019, "Volume": 244, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": 75, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.11.040", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.11.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457952600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CH; Kim, J; Tang, J; Na, J; Kang, YM; Kim, M; Lim, H; Bando, Y; Li, JS; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chaohai; Kim, Jeonghun; Tang, Jing; Na, Jongbeom; Kang, Yong-Mook; Kim, Minjun; Lim, Hyunsoo; Bando, Yoshio; Li, Jiansheng; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Scale Synthesis of MOF-Derived Superporous Carbon Aerogels with Extraordinary Adsorption Capacity for Organic Solvents", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon aerogels (CAs) with 3D interconnected networks hold promise for application in areas such as pollutant treatment, energy storage, and electrocatalysis. In spite of this, it remains challenging to synthesize high-performance CAs on a large scale in a simple and sustainable manner. We report an eco-friendly method for the scalable synthesis of ultralight and superporous CAs by using cheap and widely available agarose (AG) biomass as the carbon precursor. Zeolitic imidazolate framework-8 (ZIF-8) with high porosity is introduced into the AG aerogels to increase the specific surface area and enable heteroatom doping. After pyrolysis under inert atmosphere, the ZIF-8/AG-derived nitrogen-doped CAs show a highly interconnected porous mazelike structure with a low density of 24 mg cm(-3), a high specific surface area of 516 m(2) g(-1), and a large pore volume of 0.58 cm(-3) g(-1). The resulting CAs exhibit significant potential for application in the adsorption of organic pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2020, "Volume": 59, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2066, "End Page": 2070, "Article Number": null, "DOI": "10.1002/anie.201913719", "DOI Link": "http://dx.doi.org/10.1002/anie.201913719", "Book DOI": null, "Early Access Date": "DEC 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502903300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, ZY; Wu, XD; Wang, YF; Li, MD; Li, Y; Liu, XL; Zhang, X; Lan, ZY; Wang, JL; Du, YY; Zhang, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Zhenyu; Wu, Xiaodan; Wang, Yifan; Li, Mengdie; Li, Yan; Liu, XuLong; Zhang, Xin; Lan, Ziyang; Wang, Jianglin; Du, Yingying; Zhang, Shengmin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zn/Sr dual ions-collagen co-assembly hydroxyapatite enhances bone regeneration through procedural osteo-immunomodulation and osteogenesis", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The immune microenvironment induced by biomaterials played vital roles in bone regeneration. Hydroxyapatite (HA) and its ion-substituted derivates represent a large class of core inorganic materials for bone tissue engineering. Although ion substitution was proved to be a potent way to grant HA more biological functions, few studies focused on the immunomodulatory properties of ion-doped HA. Herein, to explore the potential osteoimmunomodulatory effects of ion-doped HA, zinc and strontium co-assembled into HA through a collagen template biomimetic way (ZnSr-Col-HA) was successfully achieved. It was found that ZnSr-Col-HA could induce a favorable osteo-immune microenvironment by stimulating macrophages. Furthermore, ZnSr-Col-HA demonstrated a procedural promoting effect on osteogenic differentiation of bone marrow mesenchymal stem cells (BMSCs) in vitro. Specifically, the osteo-immune microenvironment acted as a dominullt factor in promoting osteogenic gene expressions at the early stage through OSM signal pathway. Whereas the direct stimulating effects on BMSCs by Zn2+/Sr2+ were more effectively at the later stage with Nfatc1/Maf and Wnt signals activated. In vivo study confirmed strong promoting effects of ZnSr-Col-HA on critical-sized cranial defect repair. The current study indicated that such a combined biomaterial design philosophy of dual ion-doping and biomimetic molecular co-assembly to endow HA applicable osteoimmunomodulatory characteristics might bring up a new cutting-edge concept for bone regeneration study.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 195, "End Page": 206, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.09.013", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.09.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000743255000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, C; Choi, MK; Liu, SY; Kim, MS; Park, OK; Im, C; Kim, J; Qin, XL; Lee, GJ; Cho, KW; Kim, M; Joh, E; Lee, J; Son, D; Kwon, SH; Jeon, NL; Song, YM; Lu, NS; Kim, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Changsoon; Choi, Moon Kee; Liu, Siyi; Kim, Min Sung; Park, Ok Kyu; Im, Changkyun; Kim, Jaemin; Qin, Xiaoliang; Lee, Gil Ju; Cho, Kyoung Won; Kim, Myungbin; Joh, Eehyung; Lee, Jongha; Son, Donghee; Kwon, Seung-Hae; Jeon, Noo Li; Song, Young Min; Lu, nullshu; Kim, Dae-Hyeong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Human eye-inspired soft optoelectronic device using high-density MoS2-graphene curved image sensor array", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft bioelectronic devices provide new opportunities for next-generation implantable devices owing to their soft mechanical nature that leads to minimal tissue damages and immune responses. However, a soft form of the implantable optoelectronic device for optical sensing and retinal stimulation has not been developed yet because of the bulkiness and rigidity of conventional imaging modules and their composing materials. Here, we describe a high-density and hemispherically curved image sensor array that leverages the atomically thin MoS2-graphene heterostructure and strain-releasing device designs. The hemispherically curved image sensor array exhibits infrared blindness and successfully acquires pixelated optical signals. We corroborate the validity of the proposed soft materials and ultrathin device designs through theoretical modeling and finite element analysis. Then, we propose the ultrathin hemispherically curved image sensor array as a promising imaging element in the soft retinal implant. The CurvIS array is applied as a human eye-inspired soft implantable optoelectronic device that can detect optical signals and apply programmed electrical stimulation to optic nerves with minimum mechanical side effects to the retina.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1664, "DOI": "10.1038/s41467-017-01824-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01824-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416223800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Orellana-Tavra, C; Baxter, EF; Tian, T; Bennett, TD; Slater, NKH; Cheetham, AK; Fairen-Jimenez, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Orellana-Tavra, Claudia; Baxter, Emma F.; Tian, Tian; Bennett, Thomas D.; Slater, Nigel K. H.; Cheetham, Anthony K.; Fairen-Jimenez, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous metal-organic frameworks for drug delivery", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the encapsulation of the hydrophilic model molecule calcein in the Zr-based MOF UiO-66, followed by amorphization of the framework by ball-milling. We show controlled release of calcein over more than 30 days, compared with the 2 day release period from crystalline UiO-66.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 51, "Issue": 73, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13878, "End Page": 13881, "Article Number": null, "DOI": "10.1039/c5cc05237h", "DOI Link": "http://dx.doi.org/10.1039/c5cc05237h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360398900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nagarajan, V; Mohanty, AK; Misratt, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nagarajan, Vidhya; Mohanty, Amar K.; Misratt, Manjusri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective on Polylactic Acid (PLA) based Sustainable Materials for Durable Applications: Focus on Toughness and Heat Resistance", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Evolution of the bioplastics industry has changed directions dramatically since the early 1990s. The latest generation is moving toward durable bioplastics having high biobased content. The main objective is to replace fossil carbon with renewable carbon, a holistic strategy to mitigate climate change by minimizing the environmental impact of a product throughout its life cycle. Durable bioplastics is desired for multiuse long-term application in automotive, electronics and other industries. One necessary requirement for them is to be both tough and strong, yet the two attributes are often mutually exclusive. Does this mean a biobased and biodegradable polymer as polylactic acid (PLA) with its high strength but low toughness cannot be adopted for durable applications? Well, not exactly; this is where the concept of tailoring the properties of PLA to achieve stiffness toughness balance along with acceptable heat resistance comes into play. In this perspective, we summarize the recent research progress in addressing the toughness vs strength and heat resistance conflict inherent in PLA. Blends having super toughness and composites based on the toughened PLA blends formulated to obtain desired material properties are covered. Morphology and crystallinity that individually contribute to toughness and heat resistance have also been elucidated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 683, "Times Cited, All Databases": 725, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2899, "End Page": 2916, "Article Number": null, "DOI": "10.1021/acssuschemeng.6b00321", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.6b00321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377425900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HN; Zeng, L; Luo, D; He, J; Li, XL; Guo, ZP; Zhang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Hanna; Zeng, Li; Luo, Dan; He, Jun; Li, Xiaolong; Guo, Zaiping; Zhang, Chuhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printing of Electron/Ion-Flux Dual-Gradient Anodes for Dendrite-Free Zinc Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D porous Zn-metal anodes have aroused widespread interest for Zn-ion batteries (ZIBs). Nevertheless, the notorious top-growth dendrites caused by the intrinsic top-concentrated ions and randomly distributed electrons may ultimately trigger a cell failure. Herein, an electron/ion-flux dual-gradient 3D porous Zn anode is reported for dendrite-free ZIBs by adopting 3D printing technology. The 3D-printed Zn anode with layer-by-layer bottom-up attenuating Ag nulloparticles (3DP-BU@Zn) establishes dual-gradient electron/ion fluxes, i.e., an internal bottom-up gradient electron flux created by bottom-rich conductive Ag nulloparticles, and a gradient ion flux resulting from zincophilic Ag nulloparticles which pump ions toward the bottom. Meanwhile, the 3D-printing-enabled hierarchical porous structure and continuously conducting network endow unimpeded electron transfer and ion diffusion among the electrode, dominating a bottom-preferential Zn deposition behavior. As a result, the 3DP-BU@Zn symmetrical cell affords highly reversible Zn plating/stripping with an extremely small voltage hysteresis of 17.7 mV and a superior lifespan over 630 h at 1 mA cm(-2) and 1 mAh cm(-2). Meanwhile, the 3DP-BU@Zn//VO2 full cell exhibits remarkable cyclic stability over 500 cycles. This unique dual-gradient strategy sheds light on the roadmap for the next-generation safe and durable Zn-metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202211498", "DOI Link": "http://dx.doi.org/10.1002/adma.202211498", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952641000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuang, PY; Ni, ZR; Zhu, BC; Lin, Y; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuang, Panyong; Ni, Zhenrui; Zhu, Bicheng; Lin, Yue; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating the d-Band Center Enables Ultrafine Pt3Fe Alloy nulloparticles for pH-Universal Hydrogen Evolution Reaction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By providing dual active sites to synergistically accelerate H2O dissociation and H+ reduction, ordered intermetallic alloys usually show extraordinary performance for pH-universal hydrogen evolution reaction (HER). Herein, activated N-doped mesoporous carbon spheres supported intermetallic Pt3Fe alloys (Pt3Fe/NMCS-A), as a highly-efficient electrocatalyst for pH-universal HER, are reported. The Pt3Fe/NMCS-A exhibits low overpotentials (eta(10)) of 13, 29, and 48 mV to deliver 10 mA cm(-2) in 0.5 m H2SO4, 1.0 m KOH, and 1.0 m phosphate buffered solution (PBS), respectively, as well as robust stability to maintain the overall catalytic performances. Theoretical studies reveal that the strong Pt 5d-Fe 3d orbital electronic interactions negatively shift the d-band center (epsilon(d)) of Pt 5d orbital, resulting in reduced H* adsorption energy of Pt sites and enhanced acidic HER activity. With Pt and Fe acting as co-adsorption sites for H* and *OH intermediates, respectively, a low energy barrier is required for Pt3Fe/NMCS-A to dissociate H2O to afford H* intermediates, which greatly promotes the H* adsorption and H-2 formation in alkaline and neutral conditions. The synthetic strategy is further extended to the synthesis of Pt3Co and Pt3Ni alloys with excellent HER activity in pH-universal electrolytes, demonstrating the great potential of these Pt-based alloys for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 35, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2303030, "DOI": "10.1002/adma.202303030", "DOI Link": "http://dx.doi.org/10.1002/adma.202303030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001166720600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, YM; Lu, JL; Mao, CY; Zhu, YZ; Wang, CF; Wu, J; Liu, XM; Wu, SL; Kwan, KYH; Cheung, KMC; Yeung, KWK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Yiming; Lu, Jiali; Mao, Congyang; Zhu, Yizhou; Wang, Chaofeng; Wu, Jun; Liu, Xiangmei; Wu, Shuilin; Kwan, Kenny Y. H.; Cheung, Kenneth M. C.; Yeung, Kelvin W. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-triggered interfacial engineering-based microneedle for bacterial infection acne treatment", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Acne is an inflammatory skin disease mainly caused by Propionibacterium acnes, which can cause local inflammatory reactions and develop into chronic inflammatory diseases in severe cases. To avoid the use of antibiotics and to effectively treat the site of acne, we report a sodium hyaluronate microneedle patch that mediates the transdermal delivery of ultrasound-responsive nulloparticles for the effective treatment of acne. The patch contains nulloparticles formed by zinc porphyrin-based metal-organic framework and zinc oxide (ZnTCPP@ZnO). We demonstrated activated oxygen-mediated killing of P. acnes with an antibacterial efficiency of 99.73% under 15 min of ultrasound irradiation, resulting in a decrease in levels of acne-related factors, including tumor necrosis factor-a, interleukins, and matrix metalloproteinases. The zinc ions up-regulated DNA replication-related genes, promoting the proliferation of fibroblasts and, consequently, skin repair. This research leads to a highly effective strategy for acne treatment through the interface engineering of ultrasound response.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2023, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf0854", "DOI": "10.1126/sciadv.adf0854", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf0854", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000960951400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carter, LN; Martin, C; Withers, PJ; Attallah, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carter, Luke N.; Martin, Christopher; Withers, Philip J.; Attallah, Moataz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The influence of the laser scan strategy on grain structure and cracking behaviour in SLM powder-bed fabricated nickel superalloy", "Source Title": "JOURNAL OF ALLOYS AND COMPOUNDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "During the development of a processing route for the Selective Laser Melting (SLM) powder-bed fabrication of the nickel superalloy CM247LC it has been observed that the 'island' scan-strategy used as standard by the Concept Laser M2 SLM powder-bed system strongly influences the grain structure of the material. Optical and SEM micrographs are presented to show the observed grain structure in the SLM fabricated and Hot Isostatically Pressed (HIPped) material. The repeating pattern shown in the grain structure has been linked to the overlapping of the 'island' pattern used as standard in the Concept Laser M2 powder-bed facility. It is suggested that the formation of this bi-modal grain structure can be linked to the heat transfer away from the solidifying melt pool. The concept of a 'band' heating effect across each 'island' rather than 'moving point' heating has been suggested and has been supported by Electron Back Scattered Diffraction (EBSD) evidence. For comparison an EBSD map from a sample formed using a simple 'back-and-forth' strategy has also been presented and reveals a dramatically different grain structure and crystallographic orientation. MicroCT evidence, supported by SEM microscopy, shows that in the as-fabricated material the bimodal structure caused by the 'island' scan-strategy translates directly into the macroscopic pattern for the regions of extensive weld cracking associated with the SLM fabrication of gamma' hardenable materials. Similar microCT data has shown that HIPping can effectively close the internal cracks to provide a retro-fix solution. (C) 2014 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 568, "Times Cited, All Databases": 643, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 615, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 338, "End Page": 347, "Article Number": null, "DOI": "10.1016/j.jallcom.2014.06.172", "DOI Link": "http://dx.doi.org/10.1016/j.jallcom.2014.06.172", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342245700050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YL; Yu, Z; Rudnicki, P; Gong, HX; Huang, ZJ; Kim, SC; Lai, JC; Kong, X; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuelang; Yu, Zhiao; Rudnicki, Paul; Gong, Huaxin; Huang, Zhuojun; Kim, Sang Cheol; Lai, Jian-Cheng; Kong, Xian; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steric Effect Tuned Ion Solvation Enabling Stable Cycling of High-Voltage Lithium Metal Battery", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "1,2-Dimethoxyethane (DME) is a common electrolyte solvent for lithium metal batteries. Various DME-based electrolyte designs have improved long-term cyclability of high-voltage full cells. However, insufficient Coulombic efficiency at the Li anode and poor high-voltage stability remain a challenge for DME electrolytes. Here, we report a molecular design principle that utilizes a steric hindrance effect to tune the solvation structures of Li+ ions. We hypothesized that by substituting the methoxy groups on DME with larger-sized ethoxy groups, the resulting 1,2-diethoxyethane (DEE) should have a weaker solvation ability and consequently more anion-rich inner solvation shells, both of which enhance interfacial stability at the cathode and anode. Experimental and computational evidence indicates such stericeffect-based design leads to an appreciable improvement in electrochemical stability of lithium bis(fluorosulfonyl)imide (LiFSI)/DEE electrolytes. Under stringent full-cell conditions of 4.8 mAh cm(-2) NMC811, 50 mu m thin Li, and high cutoff voltage at 4.4 V, 4 M LiFSI/DEE enabled 182 cycles until 80% capacity retention while 4 M LiFSI/DME only achieved 94 cycles. This work points out a promising path toward the molecular design of non-fluorinated ether-based electrolyte solvents for practical high-voltage Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2021, "Volume": 143, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18703, "End Page": 18713, "Article Number": null, "DOI": "10.1021/jacs.1c09006", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c09006", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000718279300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, HY; Lu, WJ; Shao, DF; Sun, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, H. Y.; Lu, W. J.; Shao, D. F.; Sun, Y. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced thermoelectric performance of phosphorene by strain-induced band convergence", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The newly emerging monolayer phosphorene was recently predicted to be a promising thermoelectric material. In this work, we propose to further enhance the thermoelectric performance of phosphorene using the strain-induced band convergence. The effect of the uniaxial strain on the thermoelectric properties of phosphorene was investigated by using the first-principles calculations combined with the semiclassical Boltzmann theory. When the zigzag-direction strain is applied, the Seebeck coefficient and electrical conductivity in the zigzag direction can simultaneously be greatly enhanced at the critical strain of 5%, at which the band convergence is achieved. The largest ZT value of 1.65 at 300 K is then conservatively estimated by using the bulk lattice thermal conductivity. When the armchair-direction strain of 8% is applied, the room-temperature ZT value can reach 2.12 in the armchair direction of phosphorene. Our results indicate that strain-induced band convergence could be an effective method to enhance the thermoelectric performance of phosphorene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2014, "Volume": 90, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85433, "DOI": "10.1103/PhysRevB.90.085433", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.085433", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341300000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, MH; Lai, JK; Tumuluri, U; Wu, ZL; Wachs, IE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Minghui; Lai, Jun-Kun; Tumuluri, Uma; Wu, Zili; Wachs, Israel E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of Active Sites and Surface Intermediates during SCR of NO with NH3 by Supported V2O5-WO3/TiO2 Catalysts", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Time-resolved in situ IR was performed during selective catalytic reduction of NO with NH3 on supported V2O5-WO3/TiO2 catalysts to examine the distribution and reactivity of surface ammonia species on Lewis and Bronsted acid sites. While both species were found to participate in the SCR reaction, their relative population depends on the coverage of the surface vanadia and tungsta sites, temperature, and moisture. Although the more abundant surface NH4,ads+ intermediates dominate the overall SCR reaction, especially for hydrothermally aged catalysts, the minority, surface NH3,ads intermediates exhibit a higher specific SCR activity. (TOF). The current study serves to resolve the long-standing controversy about the active sites for SCR of NO with NH3 by supported V2O5-WO3/TiO2 catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2017, "Volume": 139, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15624, "End Page": 15627, "Article Number": null, "DOI": "10.1021/jacs.7b09646", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b09646", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415028200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, CK; Lin, HR; Tian, Y; Yuan, Z; Clark, R; Chen, BH; van de Burgt, LJ; Wang, JC; Zhou, Y; Hanson, K; Meisner, QJ; Neu, J; Besara, T; Siegrist, T; Lambers, E; Djurovich, P; Ma, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Chenkun; Lin, Haoran; Tian, Yu; Yuan, Zhao; Clark, Ronald; Chen, Banghao; van de Burgt, Lambertus J.; Wang, Jamie C.; Zhou, Yan; Hanson, Kenneth; Meisner, Quinton J.; Neu, Jennifer; Besara, Tiglet; Siegrist, Theo; Lambers, Eric; Djurovich, Peter; Ma, Biwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystalline zero-dimensional (0D) organic-inorganic hybrid materials with perfect host-guest structures have been developed as a new generation of highly efficient light emitters. Here we report a series of lead-free organic metal halide hybrids with a 0D structure, (C4N2H14X)(4)SnX6 (X = Br, I) and (C9NH20)(2)SbX5 (X = Cl), in which the individual metal halide octahedra (SnX64-) and quadrangular pyramids (SbX52-) are completely isolated from each other and surrounded by the organic ligands C4N2H14X+ and C9NH20+, respectively. The isolation of the photoactive metal halide species by the wide band gap organic ligands leads to no interaction or electronic band formation between the metal halide species, allowing the bulk materials to exhibit the intrinsic properties of the individual metal halide species. These 0D organic metal halide hybrids can also be considered as perfect host-guest systems, with the metal halide species periodically doped in the wide band gap matrix. Highly luminescent, strongly Stokes shifted broadband emissions with photoluminescence quantum efficiencies (PLQEs) of close to unity were realized, as a result of excited state structural reorganization of the individual metal halide species. Our discovery of highly luminescent single crystalline 0D organic-inorganic hybrid materials as perfect host-guest systems opens up a new paradigm in functional materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 531, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2018, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 586, "End Page": 593, "Article Number": null, "DOI": "10.1039/c7sc04539e", "DOI Link": "http://dx.doi.org/10.1039/c7sc04539e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422947000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Knott, BC; Erickson, E; Allen, MD; Gado, JE; Graham, R; Kearns, FL; Pardo, I; Topuzlu, E; Anderson, JJ; Austin, HP; Dominick, G; Johnson, CW; Rorrer, NA; Szostkiewicz, CJ; Copié, V; Payne, CM; Woodcock, HL; Donohoe, BS; Beckham, GT; McGeehan, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Knott, Brandon C.; Erickson, Erika; Allen, Mark D.; Gado, Japheth E.; Graham, Rosie; Kearns, Fiona L.; Pardo, Isabel; Topuzlu, Ece; Anderson, Jared J.; Austin, Harry P.; Dominick, Graham; Johnson, Christopher W.; Rorrer, Nicholas A.; Szostkiewicz, Caralyn J.; Copie, Valerie; Payne, Christina M.; Woodcock, H. Lee; Donohoe, Bryon S.; Beckham, Gregg T.; McGeehan, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization and engineering of a two-enzyme system for plastics depolymerization", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics pollution represents a global environmental crisis. In response, microbes are evolving the capacity to utilize synthetic polymers as carbon and energy sources. Recently, Ideonella sakaiensis was reported to secrete a two-enzyme system to deconstruct polyethylene terephthalate (PET) to its constituent monomers. Specifically, the I. sakaiensis PETase depolymerizes PET, liberating soluble products, including mono(2-hydroxyethyl) terephthalate (MHET), which is cleaved to terephthalic acid and ethylene glycol by MHETase. Here, we report a 1.6 angstrom resolution MHETase structure, illustrating that the MHETase core domain is similar to PETase, capped by a lid domain. Simulations of the catalytic itinerary predict that MHETase follows the canonical two- step serine hydrolase mechanism. Bioinformatics analysis suggests that MHETase evolved from ferulic acid esterases, and two homologous enzymes are shown to exhibit MHET turnover. Analysis of the two homologous enzymes and the MHETase S131G mutant demonstrates the importance of this residue for accommodation of MHET in the active site. We also demonstrate that the MHETase lid is crucial for hydrolysis of MHET and, furthermore, that MHETase does not turnover mono(2-hydroxyethyl)furanoate or mono(2-hydroxyethyl)-isophthalate. A highly synergistic relationship between PETase and MHETase was observed for the conversion of amorphous PET film to monomers across all nonzero MHETase concentrations tested. Finally, we compare the performance of MHETase:PETase chimeric proteins of varying linker lengths, which all exhibit improved PET and MHET turnover relative to the free enzymes. Together, these results offer insights into the two-enzyme PET depolymerization system and will inform future efforts in the biological deconstruction and upcycling of mixed plastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2020, "Volume": 117, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 25476, "End Page": 25485, "Article Number": null, "DOI": "10.1073/pnas.2006753117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2006753117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642213900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, J; Tang, ZJ; Liu, JY; Liu, X; Zhu, YL; Graf, D; Myhro, K; Tran, S; Lau, CN; Wei, J; Mao, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Jin; Tang, Zhijie; Liu, Jinyu; Liu, Xue; Zhu, Yanglin; Graf, David; Myhro, Kevin; Tran, Son; Lau, Chun Ning; Wei, Jiang; Mao, Zhiqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence of Topological Nodal-Line Fermions in ZrSiSe and ZrSiTe", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Dirac nodal-line semimetal phase, which represents a new quantum state of topological materials, has been experimentally realized only in a few systems, including PbTaSe2, PtSn4, and ZrSiS. In this Letter, we report evidence of nodal-line fermions in ZrSiSe and ZrSiTe probed in de Haas-van Alphen quantum oscillations. Although ZrSiSe and ZrSiTe share a similar layered structure with ZrSiS, our studies show the Fermi surface (FS) enclosing a Dirac nodal line has a 2D character in ZrSiTe, in contrast with 3D-like FS in ZrSiSe and ZrSiS. Another important property revealed in our experiment is that the nodal-line fermion density in this family of materials (similar to 10(20) cm(-3)) is much higher than the Dirac fermion density of other topological materials with discrete nodes. In addition, we have demonstrated ZrSiSe and ZrSiTe single crystals can be thinned down to 2D atomic thin layers through microexfoliation, which offers the first platform to explore exotic properties of topological nodal-line fermions in low dimensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2016, "Volume": 117, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16602, "DOI": "10.1103/PhysRevLett.117.016602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.016602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378881300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Dong, XL; Lin, JZ; Teat, SJ; Jensen, S; Cure, J; Alexandrov, EV; Xia, QB; Tan, K; Wang, QN; Olson, DH; Proserpio, DM; Chabal, YJ; Thonhauser, T; Sun, JL; Han, Y; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hao; Dong, Xinglong; Lin, Junzhong; Teat, Simon J.; Jensen, Stephanie; Cure, Jeremy; Alexandrov, Eugeny V.; Xia, Qibin; Tan, Kui; Wang, Qining; Olson, David H.; Proserpio, Davide M.; Chabal, Yves J.; Thonhauser, Timo; Sun, Junliang; Han, Yu; Li, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As an alternative technology to energy intensive distillations, adsorptive separation by porous solids offers lower energy cost and higher efficiency. Herein we report a topology-directed design and synthesis of a series of Zr-based metal-organic frameworks with optimized pore structure for efficient separation of C6 alkane isomers, a critical step in the petroleum refining process to produce gasoline with high octane rating. Zr6O4(OH)(4)(bptc)(3) adsorbs a large amount of n-hexane but excluding branched isomers. The n-hexane uptake is similar to 70% higher than that of a benchmark adsorbent, zeolite-5A. A derivative structure, Zr6O4(OH)(8)(-H2O)(4)(abtc)(2), is capable of discriminating all three C6 isomers and yielding a high separation factor for 3-methylpentane over 2,3-dimethylbutane. This property is critical for producing gasoline with further improved quality. Multicomponent breakthrough experiments provide a quantitative measure of the capability of these materials for separation of C6 alkane isomers. A detailed structural analysis reveals the unique topology, connectivity and relationship of these compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1745, "DOI": "10.1038/s41467-018-04152-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04152-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431118900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, QY; Wang, L; Dunn, CK; Kuang, X; Duan, F; Zhang, Z; Qi, HJ; Wang, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Quanyi; Wang, Lei; Dunn, Conner K.; Kuang, Xiao; Duan, Feng; Zhang, Zhong; Qi, H. Jerry; Wang, Tiejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Digital light processing 3D printing of conductive complex structures", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D printing has gained significant research interest recently for directly manufacturing 3D components and structures for use in a variety of applications. In this paper, a digital light processing (DLP (R)) based 3D printing technique was explored to manufacture electrically conductive objects of polymer nullocomposites. Here, the ink was made of a mixture of photocurable resin with multi-walled carbon nullotubes (MWCNTs). The concentrations of MWCNT as well as the printing parameters were investigated to yield optimal conductivity and printing quality. We found that 0.3 wt% loading of MWCNT in the resin matrix can provide the maximum electrical conductivity of 0.027S/m under the resin viscosity limit that allows high printing quality. With electric conductivity, the printed MWCNT nullocomposites can be used as smart materials and structures with strain sensitivity and shape memory effect. We demonstrate that the printed conductive complex structures as hollow capacitive sensor, electrically activated shape memory composites, stretchable circuits, showing the versatility of DLP (R) 3D printing for conductive complex structures. In addition, mechanical tests showed that the addition of MWCNT could slightly increase the modulus and ultimate tensile stress while decreasing slightly the ultimate stretch, indicating that the new functionality is not obtained at the price of sacrificing mechanical properties. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 18, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 74, "End Page": 83, "Article Number": null, "DOI": "10.1016/j.addma.2017.08.011", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2017.08.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LL; Xiong, P; Ma, L; Yuan, YF; Zhu, Y; Chen, DH; Luo, XY; Lu, J; Amine, K; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lele; Xiong, Pan; Ma, Lu; Yuan, Yifei; Zhu, Yue; Chen, Dahong; Luo, Xiangyi; Lu, Jun; Amine, Khalil; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Holey two-dimensional transition metal oxide nullosheets for efficient energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxide nullomaterials are promising electrodes for alkali-ion batteries owing to their distinct reaction mechanism, abundant active sites and shortened ion diffusion distance. However, detailed conversion reaction processes in terms of the oxidation state evolution and chemical/mechanical stability of the electrodes are still poorly understood. Herein we explore a general synthetic strategy for versatile synthesis of various holey transition metal oxide nullosheets with adjustable hole sizes that enable greatly enhanced alkali-ion storage properties. We employ in-situ transmission electron microscopy and operando X-ray absorption structures to study the mechanical properties, morphology evolution and oxidation state changes during electrochemical processes. We find that these holey oxide nullosheets exhibit strong mechanical stability inherited from graphene oxide, displaying minimal structural changes during lithiation/delithiation processes. These holey oxide nullosheets represent a promising material platform for in-situ probing the electrochemical processes, and could open up opportunities in many energy storage and conversion systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15139, "DOI": "10.1038/ncomms15139", "DOI Link": "http://dx.doi.org/10.1038/ncomms15139", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400065600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JB; Liu, XJ; Zhu, LQ; Zhou, J; Guan, Y; Chen, L; Niu, SW; Cai, JY; Sun, D; Zhu, YC; Du, J; Wang, GM; Qian, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jianbin; Liu, Xiaojing; Zhu, Linqin; Zhou, Jie; Guan, Yong; Chen, Liang; Niu, Shuwen; Cai, Jinyan; Sun, Da; Zhu, Yongchun; Du, Jin; Wang, Gongming; Qian, Yitai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deciphering the Modulation Essence of p Bands in Co-Based Compounds on Li-S Chemistry", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the fact that metal-based compounds have been extensively used as sulfur cathode additives, large variations in electrochemical performance have been commonly observed from one material to another, which cannot be simply explained by the adsorption capability. Herein, we have systematically studied the kinetic behaviors of Li-S chemistry on Co-based compounds with fixedmetal cation and varied non-metal anions, and deciphered the intrinsic modulation essence of the anions. Among the Co-based compounds, CoP exhibits the lowest overpotential for polysulfide transformation. Even at 40.0 C, S@CoP/rGO still delivers a high capacity of 417.3 mA hr g(-1) and an unprecedented power density of 137.3 kW kg(-1), representing the best rate performance. DFT analysis reveals that the performance variations mainly originate from the shift of p band centers, which modulate the interfacial electron transfer dynamics. This work could unlock the potential of band engineering for Li-S batteries and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 455, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2018, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2681, "End Page": 2693, "Article Number": null, "DOI": "10.1016/j.joule.2018.08.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.08.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453896100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FY; Zhou, P; Hou, YH; Tan, H; Liang, Y; Liang, JL; Zhang, Q; Guo, SJ; Tong, MP; Ni, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fuyang; Zhou, Peng; Hou, Yanghui; Tan, Hao; Liang, Yin; Liang, Jialiang; Zhang, Qing; Guo, Shaojun; Tong, Meiping; Ni, Jinren", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven photosynthesis is a sustainable process for the production of hydrogen peroxide, the efficiency of which is plagued by side reactions. Metal-free covalent organic frameworks (COFs) that can form suitable intermediates and inhibit side reactions show great promise to photo-synthesize H2O2. However, the insufficient formation and separation/transfer of photogenerated charges in such materials restricts the efficiency of H2O2 production. Herein, we provide a strategy for the design of donor-acceptor COFs to greatly boost H2O2 photosynthesis. We demonstrate that the optimal intramolecular polarity of COFs, achieved by using suitable amounts of phenyl groups as electron donors, can maximize the free charge generation, which leads to high H2O2 yield rates (605 & mu;mol g(-1) h(-1)) from water, oxygen and visible light without sacrificial agents. Combining in-situ characterization with computational calculations, we describe how the triazine N-sites with optimal N 2p states play a crucial role in H2O activation and selective oxidation into H2O2. We further experimentally demonstrate that H2O2 can be efficiently produced in tap, river or sea water with natural sunlight and air for water decontamination. Solar-driven photosynthesis is a green and sustainable process for hydrogen peroxide production. Here the authors report that optimizing the intramolecular polarity of COFs can greatly boost H2O2 photosynthesis from water, air, and sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-40007-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40007-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037980500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Assat, G; Foix, D; Delacourt, C; Iadecola, A; Dedryvère, R; Tarascon, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Assat, Gaurav; Foix, Dominique; Delacourt, Charles; Iadecola, Antonella; Dedryvere, Remi; Tarascon, Jean-Marie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reversible anionic redox has rejuvenated the search for high-capacity lithium-ion battery cathodes. Real-world success necessitates the holistic mastering of this electrochemistry's kinetics, thermodynamics, and stability. Here we prove oxygen redox reactivity in the archetypical lithium-and manganese-rich layered cathodes through bulk-sensitive synchrotron-based spectroscopies, and elucidate their complete anionic/cationic charge-compensation mechanism. Furthermore, via various electroanalytical methods, we answer how the anionic/cationic interplay governs application-wise important issues-namely sluggish kinetics, large hysteresis, and voltage fade-that afflict these promising cathodes despite widespread industrial and academic efforts. We find that cationic redox is kinetically fast and without hysteresis unlike sluggish anions, which furthermore show different oxidation vs. reduction potentials. Additionally, more time spent with fully oxidized oxygen promotes voltage fade. These fundamental insights about anionic redox are indispensable for improving lithium-rich cathodes. Moreover, our methodology provides guidelines for assessing the merits of existing and future anionic redox-based high-energy cathodes, which are being discovered rapidly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 547, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2219, "DOI": "10.1038/s41467-017-02291-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02291-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418566800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Wu, JJ; Hackenberg, KP; Zhang, J; Wang, YM; Yang, YC; Keyshar, K; Gu, J; Ogitsu, T; Vajtai, R; Lou, J; Ajayan, PM; Wood, BC; Yakobson, BI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuanyue; Wu, Jingjie; Hackenberg, Ken P.; Zhang, Jing; Wang, Y. Morris; Yang, Yingchao; Keyshar, Kunttal; Gu, Jing; Ogitsu, Tadashi; Vajtai, Robert; Lou, Jun; Ajayan, Pulickel M.; Wood, Brandon C.; Yakobson, Boris I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-optimizing, highly surface-active layered metal dichalcogenide catalysts for hydrogen evolution", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-cost, layered transition-metal dichalcogenides (MX2) based on molybdenum and tungsten have attracted substantial interest as alternative catalysts for the hydrogen evolution reaction (HER). These materials have high intrinsic per-site HER activity; however, a significant challenge is the limited density of active sites, which are concentrated at the layer edges. Here we unravel electronic factors underlying catalytic activity on MX2 surfaces, and leverage the understanding to report group-5 MX2 (H-TaS2 and H-NbS2) electrocatalysts whose performance instead mainly derives from highly active basal-plane sites, as suggested by our first-principles calculations and performance comparisons with edge-active counterparts. Beyond high catalytic activity, they are found to exhibit an unusual ability to optimize their morphology for enhanced charge transfer and accessibility of active sites as the HER proceeds, offering a practical advantage for scalable processing. The catalysts reach 10 mA cm(-2) current density at an overpotential of similar to 50-60 mV with a loading of 10-55 mu g cm(-2), surpassing other reported MX2 candidates without any performance-enhancing additives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17127, "DOI": "10.1038/nenergy.2017.127", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.127", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415189100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rafsanjani, A; Pasini, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rafsanjani, Ahmad; Pasini, Damiano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bistable auxetic mechanical metamaterials inspired by ancient geometric motifs", "Source Title": "EXTREME MECHANICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Auxetic materials become thicker rather than thinner when stretched, exhibiting an unusual negative Poisson's ratio well suited for designing shape transforming metamaterials. Current auxetic designs, however, are often monostable and cannot maintain the transformed shape upon load removal. Here, inspired by ancient geometric motifs arranged in square and triangular grids, we introduce a class of switchable architected materials exhibiting simultaneous auxeticity and structural bistability. The material concept is experimentally realized by perforating various cut motifs into a sheet of rubber, thus creating a network of rotating units connected with compliant hinges. The metamaterial performance is assessed through mechanical testing and accurately predicted by a coherent set of finite element simulations. A discussion on a rich set of mechanical phenomena follows to shed light on the main design principles governing bistable auxetics. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 9, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 291, "End Page": 296, "Article Number": null, "DOI": "10.1016/j.eml.2016.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.eml.2016.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395260300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avayu, O; Almeida, E; Prior, Y; Ellenbogen, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avayu, Ori; Almeida, Euclides; Prior, Yehiam; Ellenbogen, Tal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Composite functional metasurfaces for multispectral achromatic optics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured metasurfaces offer unique capabilities for subwavelength control of optical waves. Based on this potential, a large number of metasurfaces have been proposed recently as alternatives to standard optical elements. In most cases, however, these elements suffer from large chromatic aberrations, thus limiting their usefulness for multiwavelength or broadband applications. Here, in order to alleviate the chromatic aberrations of individual diffractive elements, we introduce dense vertical stacking of independent metasurfaces, where each layer is made from a different material, and is optimally designed for a different spectral band. Using this approach, we demonstrate a triply red, green and blue achromatic metalens in the visible range. We further demonstrate functional beam shaping by a self-aligned integrated element for stimulated emission depletion microscopy and a lens that provides anomalous dispersive focusing. These demonstrations lead the way to the realization of ultra-thin superachromatic optical elements showing multiple functionalities- all in a single nullostructured ultra-thin element.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14992, "DOI": "10.1038/ncomms14992", "DOI Link": "http://dx.doi.org/10.1038/ncomms14992", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398348100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Navarro-Moratalla, E; Island, JO; Mañas-Valero, S; Pinilla-Cienfuegos, E; Castellanos-Gomez, A; Quereda, J; Rubio-Bollinger, G; Chirolli, L; Silva-Guillén, JA; Agraït, N; Steele, GA; Guinea, F; van der Zant, HSJ; Coronado, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Navarro-Moratalla, Efren; Island, Joshua O.; Manas-Valero, Samuel; Pinilla-Cienfuegos, Elena; Castellanos-Gomez, Andres; Quereda, Jorge; Rubio-Bollinger, Gabino; Chirolli, Luca; Angel Silva-Guillen, Jose; Agrait, Nicolas; Steele, Gary A.; Guinea, Francisco; van der Zant, Herre S. J.; Coronado, Eugenio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced superconductivity in atomically thin TaS2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to exfoliate layered materials down to the single layer limit has presented the opportunity to understand how a gradual reduction in dimensionality affects the properties of bulk materials. Here we use this top-down approach to address the problem of superconductivity in the two-dimensional limit. The transport properties of electronic devices based on 2H tantalum disulfide flakes of different thicknesses are presented. We observe that superconductivity persists down to the thinnest layer investigated (3.5 nm), and interestingly, we find a pronounced enhancement in the critical temperature from 0.5 to 2.2 K as the layers are thinned down. In addition, we propose a tight-binding model, which allows us to attribute this phenomenon to an enhancement of the effective electron-phonon coupling constant. This work provides evidence that reducing the dimensionality can strengthen superconductivity as opposed to the weakening effect that has been reported in other 2D materials so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11043, "DOI": "10.1038/ncomms11043", "DOI Link": "http://dx.doi.org/10.1038/ncomms11043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372228200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Liao, HX; Molokeev, MS; Zhou, YY; Zhang, QY; Liu, QL; Xia, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ming; Liao, Hongxu; Molokeev, Maxim S.; Zhou, Yayun; Zhang, Qinyuan; Liu, Quanlin; Xia, Zhiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphor-converted white LEDs rely on combining a blue-emitting InGaN chip with yellow and red-emitting luminescent materials. The discovery of cyan-emitting (470-500 nm) phosphors is a challenge to compensate for the spectral gap and produce full-spectrum white light. Na0.5K0.5Li3SiO4: Eu2+ (NKLSO: Eu2+) phosphor was developed with impressive properties, providing cyan emission at 486 nm with a narrow full width at half maximum (FWHM) of only 20.7 nm, and good thermal stability with an integrated emission loss of only 7% at 150 degrees C. The ultra-narrow-band cyan emission results from the high-symmetry cation sites, leading to almost ideal cubic coordination for UCr4C4-type compounds. NKLSO: Eu2+ phosphor allows the valley between the blue and yellow emission peaks in the white LED device to be filled, and the color-rendering index can be enhanced from 86 to 95.2, suggesting great applications in full-spectrum white LEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 38, "DOI": "10.1038/s41377-019-0148-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0148-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464000500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Terrones, H; Del Corro, E; Feng, S; Poumirol, JM; Rhodes, D; Smirnov, D; Pradhan, NR; Lin, Z; Nguyen, MAT; Elías, AL; Mallouk, TE; Balicas, L; Pimenta, MA; Terrones, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Terrones, H.; Del Corro, E.; Feng, S.; Poumirol, J. M.; Rhodes, D.; Smirnov, D.; Pradhan, N. R.; Lin, Z.; Nguyen, M. A. T.; Elias, A. L.; Mallouk, T. E.; Balicas, L.; Pimenta, M. A.; Terrones, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New First Order Raman-active Modes in Few Layered Transition Metal Dichalcogenides", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the main Raman features of semiconducting transition metal dichalcogenides are well known for the monolayer and bulk, there are important differences exhibited by few layered systems which have not been fully addressed. WSe2 samples were synthesized and ab-initio calculations carried out. We calculated phonon dispersions and Raman-active modes in layered systems: WSe2, MoSe2, WS2 and MoS2 ranging from monolayers to five-layers and the bulk. First, we confirmed that as the number of layers increase, the E', E '' and E-2g modes shift to lower frequencies, and the A(1)' and A(1g) modes shift to higher frequencies. Second, new high frequency first order A(1)' and A(1g) modes appear, explaining recently reported experimental data for WSe2, MoSe2 and MoS2. Third, splitting of modes around A(1)' and A(1g) is found which explains those observed in MoSe2. Finally, exterior and interior layers possess different vibrational frequencies. Therefore, it is now possible to precisely identify few-layered STMD.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4215, "DOI": "10.1038/srep04215", "DOI Link": "http://dx.doi.org/10.1038/srep04215", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331956200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, EH; Chen, MH; Chen, ZT; Zhou, YY; Zhou, WJ; Sun, HT; Yang, XF; Gan, JL; Ye, S; Zhang, QY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Enhai; Chen, Meihua; Chen, Zitao; Zhou, Yayun; Zhou, Weijie; Sun, Hong-Tao; Yang, Xianfeng; Gan, Jiulin; Ye, Shi; Zhang, Qinyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mn2+-activated dual-wavelength emitting materials toward wearable optical fibre temperature sensor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal sensing is crucial for the creation of smart wearable devices. However, the discovery of luminescent materials with suitable dual-wavelength emissions is a great challenge for the construction of stable wearable optical fibre temperature sensors. Benefiting from the Mn2+-Mn2+ superexchange interactions, a dual-wavelength (530/650 nm)-emitting material Li2ZnSiO4:Mn2+ is presented via simple increasing the Mn2+ concentration, wherein the two emission bands have different temperature-dependent emission behaviours, but exhibit quite similar excitation spectra. Density functional theory calculations, coupled with extended X-ray absorption fine structure and electron-diffraction analyses reveal the origins of the two emission bands in this material. A wearable optical temperature sensor is fabricated by incorporating Li2ZnSiO4:Mn2+ in stretchable elastomer-based optical fibres, which can provide thermal-sensitive emissions at dual- wavelengths for stable ratiometric temperature sensing with good precision and repeatability. More importantly, a wearable mask integrated with this stretchable fibre sensor is demonstrated for the detection of physiological thermal changes, showing great potential for use as a wearable health monitor. This study also provides a framework for creating transition-metal-activated luminescence materials. Dual-wavelength emission materials can provide fluorescence intensity ratio technology with self-calibration features; their fabrication however, remains a challenge. Here, authors design a dual-wavelength emitting material Li2ZnSiO4:Mn2+ and present a wearable optical fibre temperature sensor, functioning in both contact and noncontact modes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2166, "DOI": "10.1038/s41467-022-29881-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29881-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784989100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhan, A; Colburn, S; Trivedi, R; Fryett, TK; Dodson, CM; Majumdar, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhan, Alan; Colburn, Shane; Trivedi, Rahul; Fryett, Taylor K.; Dodson, Christopher M.; Majumdar, Arka", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Contrast Dielectric Metasurface Optics", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The miniaturization of current image sensors is largely limited by the volume of the optical elements. Using a subwavelength-patterned quasi-periodic structure, also known as a metasurface, one can build planar optical elements based on the principle of diffraction. Recent demonstrations of high quality metasurface optical elements are mostly based on high refractive-index materials. Here, we present a design of low contrast metasurface-based optical elements. We fabricate and experimentally characterize several silicon nitride-based lenses and vortex beam generators. The fabricated lenses achieved beam spots of less than 1 pm with numerical apertures as high as similar to 0.7S. We observed a transmission efficiency of 90% and focusing efficiency of 40% in the visible regime. Our results pave the way toward building low-loss metasurface-based optical elements at visible frequencies using low-contrast materials and extend the range of prospective material systems for metasurface optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 209, "End Page": 214, "Article Number": null, "DOI": "10.1021/acsphotonics.5b00660", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.5b00660", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370587000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuang, HL; Hennig, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuang, Houlong L.; Hennig, Richard G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stability and magnetism of strongly correlated single-layer VS2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-layer transition metal dichalcogenides exhibit a variety of atomic structures and associated exotic electronic and magnetic properties. Density-functional calculations using the LDA+U approximation show that single-layer VS2 is a strongly correlated material, where the stability, phonon spectra, and magnetic moments of the octahedral (1T) and the trigonal prismatic (2H) structures significantly depend on the effective Hubbard U parameter, U-eff. Comparison with the HSE06 hybrid density functional used as a benchmark indicates that U-eff = 2.5 eV, which consistently shows that the 2H structure is more stable than the 1T structure and a ferromagnetic semiconductor. The magnetic moments are localized on the V atoms and coupled ferromagnetically due to the super exchange interactions mediated by the S atoms. Calculations of the magnetic anisotropy show an easy plane for the magnetic moment. Assuming a classical XY model with nearest neighbor coupling, we determine the critical temperature, T-c, for the Berezinsky-Kosterlitz-Thouless transition of 2H single-layer VS2 to be about 90 K. Applying biaxial tensile strains can increase T-c. Using Wannier interpolation, we evaluate the Berry curvature and anomalous Hall conductivity of 2H single-layer VS2. The coexistence of quasi-long-range ferromagnetic ordering and semiconducting behavior enables 2H single-layer VS2 to be a promising candidate for spintronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2016, "Volume": 93, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 54429, "DOI": "10.1103/PhysRevB.93.054429", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.054429", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370840400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Revilla-León, M; Özcan, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Revilla-Leon, Marta; Ozcan, Mutlu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive Manufacturing Technologies Used for Processing Polymers: Current Status and Potential Application in Prosthetic Dentistry", "Source Title": "JOURNAL OF PROSTHODONTICS-IMPLANT ESTHETIC AND RECONSTRUCTIVE DENTISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There are 7 categories of additive manufacturing (AM) technologies, and a wide variety of materials can be used to build a CAD 3D object. The present article reviews the main AM processes for polymers for dental applications: stereolithography (SLA), digital light processing (DLP), material jetting (MJ), and material extrusion (ME). The manufacturing process, accuracy, and precision of these methods will be reviewed, as well as their prosthodontic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 28, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 146, "End Page": 158, "Article Number": null, "DOI": "10.1111/jopr.12801", "DOI Link": "http://dx.doi.org/10.1111/jopr.12801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Dentistry, Oral Surgery & Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458904300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, Y; Trinh, MT; Chen, RS; Purdum, GE; Khlyabich, PP; Sezen, M; Oh, S; Zhu, HM; Fowler, B; Zhang, BY; Wang, W; Nam, CY; Sfeir, MY; Black, CT; Steigerwald, ML; Loo, YL; Ng, F; Zhu, XY; Nuckolls, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yu; Trinh, M. Tuan; Chen, Rongsheng; Purdum, Geoffrey E.; Khlyabich, Petr P.; Sezen, Melda; Oh, Seokjoon; Zhu, Haiming; Fowler, Brandon; Zhang, Boyuan; Wang, Wei; Nam, Chang-Yong; Sfeir, Matthew Y.; Black, Charles T.; Steigerwald, Michael L.; Loo, Yueh-Lin; Ng, Fay; Zhu, X. -Y.; Nuckolls, Colin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular helices as electron acceptors in high-performance bulk heterojunction solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite numerous organic semiconducting materials synthesized for organic photovoltaics in the past decade, fullerenes are widely used as electron acceptors in highly efficient bulk-heterojunction solar cells. None of the non-fullerene bulk heterojunction solar cells have achieved efficiencies as high as fullerene-based solar cells. Design principles for fullerene-free acceptors remain unclear in the field. Here we report examples of helical molecular semiconductors as electron acceptors that are on par with fullerene derivatives in efficient solar cells. We achieved an 8.3% power conversion efficiency in a solar cell, which is a record high for non-fullerene bulk heterojunctions. Femtosecond transient absorption spectroscopy revealed both electron and hole transfer processes at the donor - acceptor interfaces. Atomic force microscopy reveals a mesh-like network of acceptors with pores that are tens of nullometres in diameter for efficient exciton separation and charge transport. This study describes a new motif for designing highly efficient acceptors for organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8242, "DOI": "10.1038/ncomms9242", "DOI Link": "http://dx.doi.org/10.1038/ncomms9242", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363017500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TX; Patra, J; Chang, JK; Ting, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thi Xuyen Nguyen; Patra, Jagabandhu; Chang, Jeng-Kuei; Ting, Jyh-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High entropy spinel oxide nulloparticles for superior lithiation-delithiation performance", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High entropy spinel oxide (HESO) nulloparticles were synthesizedviaa surfactant-assisted hydrothermal method and used as a novel anode material in a lithium-ion battery. The HESO consists of non-equimolar cations of Cr, Mn, Fe, Co, and Ni dispersed in two Wyckoff sites with various valence states. Due to a strong entropy-induced phase stabilization effect of the HESO, no inactive MgO structural pillars, which are exclusively present in the reported rock salt type high entropy oxides, are required to achieve high electrode cycling stability. A superior charge-discharge capacity of 1235 mA h g(-1), the highest among all known HEOs, is obtained with 90% capacity retention after 200 cycles. The unique HESO is also characterized by plenty of oxygen vacancies and three-dimensional Li(+)transport pathways. Also, great high-rate performance,i.e., 500 mA h g(-1)@ 2000 mA g(-1), of the HESO electrode is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2020, "Volume": 8, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18963, "End Page": 18973, "Article Number": null, "DOI": "10.1039/d0ta04844e", "DOI Link": "http://dx.doi.org/10.1039/d0ta04844e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572173300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, XQ; Li, TY; Yan, LL; Jiao, Y; Zhang, YJ; Wang, K; Cheng, ZJ; Ma, J; Shao, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Xiquan; Li, Tongyu; Yan, Linlin; Jiao, Yang; Zhang, Yingjie; Wang, Kai; Cheng, Zhongjun; Ma, Jun; Shao, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable electrospinning superhydrophilic nullofiber membranes for ultrafast oil-water separation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although membrane technology has attracted considerable attention for oily wastewater treatment, the plastic waste generated from discarded membranes presents an immediate challenge for achieving eco-friendly separation. We designed on-demand biodegradable superhydrophilic membranes composed of polylactic acid nullofibers in conjunction with polyethylene oxide hydrogels using electrospinning technology for ultrafast purification of oily water. Our results showed that the use of the polyethylene oxide hydrogels increased the number of hydrogen bonds formed between the membrane surface and water molecules by 357.6%. This converted hydrophobic membranes into superhydrophilic ones, which prevented membrane fouling and accelerated emulsion penetration through the membranes. The oil-in-water emulsion permeance of our newly designed nullofiber membranes increased by 61.9 times (2.1 x 10(4) liters per square meter per hour per bar) with separation efficiency >99.6%, which was superior to state-of-the-art membranes. Moreover, the formation of hydrogen bonds was found to accelerate polylactic acid biodegradation into lactic acid by over 30%, offering a promising approach for waste membrane treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 9, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadh8195", "DOI": "10.1126/sciadv.adh8195", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adh8195", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053144500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JL; Liang, Y; Li, W; Xu, N; Zhu, B; Wu, Z; Wang, XY; Fan, SH; Wang, MH; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jinlei; Liang, Yuan; Li, Wei; Xu, Ning; Zhu, Bin; Wu, Zhen; Wang, Xueyang; Fan, Shanhui; Wang, Minghuai; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protecting ice from melting under sunlight via radiative cooling", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As ice plays a critical role in various aspects of life, from food preservation to ice sports and ecosystem, it is desirable to protect ice from melting, especially under sunlight. The fundamental reason for ice melt under sunlight is related to the imbalanced energy flows of the incoming sunlight and outgoing thermal radiation. Therefore, radiative cooling, which can balance the energy flows without energy consumption, offers a sustainable approach for ice protection. Here, we demonstrate that a hierarchically designed radiative cooling film based on abundant and eco-friendly cellulose acetate molecules versatilely provides effective and passive protection to various forms/scales of ice under sunlight. This work provides inspiration for developing an effective, scalable, and sustainable route for preserving ice and other critical elements of ecosystems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabj9756", "DOI": "10.1126/sciadv.abj9756", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abj9756", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757383500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Xu, D; Wu, QY; Diao, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yang; Xu, Di; Wu, Qingyong; Diao, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu2O/CuO Bilayered Composite as a High-Efficiency Photocathode for Photoelectrochemical Hydrogen Evolution Reaction", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar powered hydrogen evolution reaction (HER) is one of the key reactions in solar-to-chemical energy conversion. It is desirable to develop photocathodic materials that exhibit high activity toward photoelectrochemical (PEC) HER at more positive potentials because a higher potential means a lower overpotential for HER. In this work, the Cu2O/CuO bilayered composites were prepared by a facile method that involved an electrodeposition and a subsequent thermal oxidation. The resulting Cu2O/CuO bilayered composites exhibited a surprisingly high activity and good stability toward PEC HER, expecially at high potentials in alkaline solution. The photocurrent density for HER was 3.15 mA.cm(-2) at the potential of 0.40 V vs. RHE, which was one of the two highest reported at the same potential on copper-oxide-based photocathode. The high photoactivity of the bilayered composite was ascribed to the following three advantages of the Cu2O/CuO heterojunction: (1) the broadened light absorption band that made more efficient use of solar energy, (2) the large space-charge-region potential that enabled a high efficiency for electron-hole separation, and (3) the high majority carrier density that ensured a faster charge transportation rate. This work reveals the potential of the Cu2O/CuO bilayered composite as a promising photocathodic material for solar water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35158, "DOI": "10.1038/srep35158", "DOI Link": "http://dx.doi.org/10.1038/srep35158", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385352900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, HW; Qiao, JW; Hawk, JA; Zhou, HF; Chen, MW; Gao, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, H. W.; Qiao, J. W.; Hawk, J. A.; Zhou, H. F.; Chen, M. W.; Gao, M. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties of refractory high-entropy alloys: Experiments and modeling", "Source Title": "JOURNAL OF ALLOYS AND COMPOUNDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Refractory high-entropy alloys hold the potential for high-temperature applications beyond the capability of the state-of-the-art Ni-based superalloys, and thus, it is important to study their solid solution formation characteristics and mechanical properties. In this study, designed by CALPHAD method, formation of as-cast arc-melted body-centered cubic MoNbTaTiV was experimentally verified using X-ray diffraction and scanning electron microscopy. The measured density and lattice parameter for MoNbTaTiV are 9: 29 g= cm(3) and 3.224 angstrom, which obey the rule of mixtures (ROM). The alloy exhibits high hardness at 443 Hv, high yield strength at 1.4 GPa, and good compressive fracture strength at 2.45 GPa with a fracture strain of similar to 30% at room temperature. The yield strength and hardness values of this alloy, and other single-phase refractory high-entropy alloys, are estimated using a simple model of solid solution strengthening. Reasonable agreement between modeling prediction and experiments is obtained. In addition, first-principles density functional theory calculations predict an enthalpy of formation of -0.865 kJ/mol for the MoNbTaTiV alloy, with calculated atomic volume and elastic properties (e. g., bulk and elastic moduli) obeying the ROM. (C) 2016 Elsevier B. V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2017, "Volume": 696, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1139, "End Page": 1150, "Article Number": null, "DOI": "10.1016/j.jallcom.2016.11.188", "DOI Link": "http://dx.doi.org/10.1016/j.jallcom.2016.11.188", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391819800148", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MY; Chen, CH; Shi, YM; Li, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ming-Yang; Chen, Chang-Hsiao; Shi, Yumeng; Li, Lain-Jong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterostructures based on two-dimensional layered materials and their potential applications", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of two-dimensional (2D) layered materials is driven by fundamental interest and their potential applications. Atomically thin 2D materials provide a wide range of basic building blocks with unique electrical, optical, and thermal properties which do not exist in their bulk counterparts. The van der Waals interlayer interaction enables the possibility to exfoliate and reassemble different 2D materials into arbitrarily and vertically stacked heterostructures. Recently developed vapor phase growth of 2D materials further paves the way of directly synthesizing vertical and lateral heterojunctions. This review provides insights into the layered 2D heterostructures, with a concise introduction to preparative approaches for 2D materials and heterostructures. These unique 2D heterostructures have abundant implications for many potential applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 494, "Times Cited, All Databases": 540, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2016, "Volume": 19, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 322, "End Page": 335, "Article Number": null, "DOI": "10.1016/j.mattod.2015.11.003", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.11.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380759200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, P; Luo, X; Ma, YF; Chu, SQ; Chen, S; Zheng, XS; Lu, JL; Wu, XJ; Liang, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Peng; Luo, Xiao; Ma, Yanfu; Chu, Sheng-Qi; Chen, Si; Zheng, Xusheng; Lu, Junling; Wu, Xiao-Jun; Liang, Hai-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur stabilizing metal nulloclusters on carbon at high temperatures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supported metal nulloclusters consisting of several dozen atoms are highly attractive for heterogeneous catalysis with unique catalytic properties. However, the metal nullocluster catalysts face the challenges of thermal sintering and consequent deactivation owing to the loss of metal surface areas particularly in the applications of high-temperature reactions. Here, we report that sulfur-a documented poison reagent for metal catalysts-when doped in a carbon matrix can stabilize similar to 1 nullometer metal nulloclusters (Pt, Ru, Rh, Os, and Ir) at high temperatures up to 700 degrees C. We find that the enhanced adhesion strength between metal nulloclusters and the sulfur-doped carbon support, which arises from the interfacial metal-sulfur bonding, greatly retards both metal atom diffusion and nullocluster migration. In catalyzing propane dehydrogenation at 550 degrees C, the sulfur-doped carbon supported Pt nullocluster catalyst with interfacial electronic effects exhibits higher selectivity to propene as well as more stable durability than sulfur-free carbon supported catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3135, "DOI": "10.1038/s41467-021-23426-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23426-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658774600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, C; Yang, JJ; Xie, LH; Cui, GL; Fang, WH; Li, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Chen; Yang, Jia-Jia; Xie, Lin-Hua; Cui, Ganglong; Fang, Wei-Hai; Li, Jian-Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic ozone decomposition and adsorptive VOCs removal in bimetallic metal-organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Warm-season O-3 pollution has been increasingly frequent worldwide in the past few years, exposing a threat to human health as well as the natural environment. Here, the authors showcase a stable MOF which can not only effectively capture various airborne VOCs, but decompose trace O-3 in ambient air. Atmospheric ozone has long been a threat to human health, however, rational design of high-performance O-3-decomposition catalysts remains challenging. Herein, we demonstrate the great potential of a series of isomorphous bimetallic MOFs denoted as PCN-250(Fe2M) (M = Co2+, Ni2+, Mn2+) in catalytic O-3 decomposition. Particularly, PCN-250(Fe2Co) showed 100% O-3 removal efficiency for a continuous air flow containing 1 ppm O-3 over a wide humidity range (0 - 80% RH) at room temperature. Mechanism studies suggested that the high catalytic performance originated from the introduction of open Co(II) sites as well as its porous structure. Additionally, at low pressures around 10 Pa, PCN-250(Fe2Co) exhibited high adsorption capacities (89 - 241 mg g(-1)) for most VOCs, which are not only a class of hazardous air pollutants but also the precursor of O-3. This work opens up a new avenue to develop advanced air purification materials for O-3 and VOCs removal in one.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4991, "DOI": "10.1038/s41467-022-32678-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32678-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000845603400038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, ZM; Li, G; Wang, XM; Gomez-Garcia, CJ; Xin, JJ; Ma, HY; Pang, HJ; Gao, KQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Zemin; Li, Gang; Wang, Xinming; Gomez-Garcia, Carlos J.; Xin, Jianjiao; Ma, Huiyuan; Pang, Haijun; Gao, Keqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FeS2/MoS2@RGO hybrid materials derived from polyoxomolybdate-based metal-organic frameworks as high-performance electrocatalyst for ammonia synthesis under ambient conditions", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrocatalytic nitrogen reduction reaction (NRR) provides a promising way for storage and sustainable utilization of ammonia. In order to reduce the cost of ammonia synthesis and promote large-scale production, it is very important to develop stable and highly active electrocatalysts. In this work, we demonstrate an iron-based metal-organic framework (MIL-100) and molybdenum-based polyoxometalate (PMo12) host-guest-assisted strategy for synthesizing nullostructured bimetallic sulfides through a one-pot hydrothermal synthesis process. FeS2/MoS2 particles are evenly distributed on reduced graphene oxide (RGO) with high conductivity, forming a well-defined nulloflower structure. Benefiting from the synergistic effect of FeS2, MoS2 (with inherent rich catalytically active sites and uniform nulloflower structure) and RGO, the as-synthesized FeS2/MoS2@RGO achieves electrocatalytic activity and stability towards NRR in both basic and acidic solutions. The electrochemical results show a high Faradaic efficiency (FE) of 38.6 % and NH3 yield rate of 41.1 mu g h-1 mgcat -1 at -0.2 V with respect to a reversible hydrogen electrode (RHE) in acidic potassium sulfate, and FE of 9.62 % and NH3 yield rate of 10.35 mu g h-1 mgcat-1 at -0.4 V vs. RHE in alkaline potassium hydroxide solution at room temperature. Density functional theory (DFT) calculation indicates that NRR on FeS2/MoS2 has optimized nitrogen binding and ammonia release which promotes the fast kinetics process through the distal mechanism, and the protonation of N2 to form *N2H species is the rate-determining step (RDS) with the maximum Delta G values (+0.43 eV). This work develop a general and promising method for the design of efficient and low cost pH-universal NRR electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2022, "Volume": 445, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136797, "DOI": "10.1016/j.cej.2022.136797", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.136797", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000801821000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Zhang, K; Li, TH; Maruf, A; Qin, X; Luo, L; Zhong, Y; Qiu, JH; McGinty, S; Pontrelli, G; Liao, XL; Wu, W; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yi; Zhang, Kang; Li, Tianhan; Maruf, Ali; Qin, Xian; Luo, Li; Zhong, Yuan; Qiu, Juhui; McGinty, Sean; Pontrelli, Giuseppe; Liao, Xiaoling; Wu, Wei; Wang, Guixue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macrophage membrane functionalized biomimetic nulloparticles for targeted anti-atherosclerosis applications", "Source Title": "THERANOSTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atherosclerosis (AS), the underlying cause of most cardiovascular events, is one of the most common causes of human morbidity and mortality worldwide due to the lack of an efficient strategy for targeted therapy. In this work, we aimed to develop an ideal biomimetic nulloparticle for targeted AS therapy. Methods: Based on macrophage homing into atherosclerotic lesions and cell membrane coating nullotechnology, biomimetic nulloparticles (MM/RAPNPs) were fabricated with a macrophage membrane (MM) coating on the surface of rapamycin-loaded poly (lactic-co-glycolic acid) copolymer (PLGA) nulloparticles (RAPNPs). Subsequently, the physical properties of the MM/RAPNPs were characterized. The biocompatibility and biological functions of MM/RAPNPs were determined in vitro. Finally, in AS mouse models, the targeting characteristics, therapeutic efficacy and safety of the MM/RAPNPs were examined. Results: The advanced MM/RAPNPs demonstrated good biocompatibility. Due to the MM coating, the nulloparticles effectively inhibited the phagocytosis by macrophages and targeted activated endothelial cells in vitro. In addition, MM-coated nulloparticles effectively targeted and accumulated in atherosclerotic lesions in vivo. After a 4-week treatment program, MM/RAPNPs were shown to significantly delay the progression of AS. Furthermore, MM/RAPNPs displayed favorable safety performance after long-term administration. Conclusion: These results demonstrate that MM/RAPNPs could efficiently and safely inhibit the progression of AS. These biomimetic nulloparticles may be potential drug delivery systems for safe and effective anti-AS applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 164, "End Page": 180, "Article Number": null, "DOI": "10.7150/thno.47841", "DOI Link": "http://dx.doi.org/10.7150/thno.47841", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582957500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Chu, ZM; Yin, ZG; Li, JZ; Yang, YG; Chen, JR; Wu, JL; You, JB; Zhang, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Ji; Chu, Zema; Yin, Zhigang; Li, Jingzhen; Yang, Yingguo; Chen, Jingren; Wu, Jinliang; You, Jingbi; Zhang, Xingwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Red Perovskite Light-Emitting Diodes with Efficiency Exceeding 25% Realized by Co-Spacer Cations", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes (PeLEDs) have received great attention in recent years due to their narrow emission bandwidth and tunable emission spectrum. Efficient red emission is one of most important parts for lighting and displays. Quasi-2D perovskites can deliver high emission efficiency due to the strong carrier confinement, while the external quantum efficiencies (EQE) of red quasi-2D PeLEDs are inefficient at present, which is due to the complex distribution of different n-value phases in quasi-2D perovskite films. In this work, the phase distribution of the quasi-2D perovskite is finely controlled by mixing two different large organic cations, which effectively reduces the amount of smaller n-index phases, meanwhile the passivation of lead and halide defects in perovskite films is realized. Accordingly, the PeLEDs show 25.8% EQE and 1300 cd m(-2) maximum brightness at 680 nm, which exhibits the highest performance for red PeLEDs up to now.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 34, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2204460, "DOI": "10.1002/adma.202204460", "DOI Link": "http://dx.doi.org/10.1002/adma.202204460", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837201800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YQ; Ba, DL; Li, YY; Liu, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuqi; Ba, Deliang; Li, Yuanyuan; Liu, Jinping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Noninterference Revealing of Layered to Layered Zinc Storage Mechanism of δ-MnO2 toward Neutral Zn-Mn Batteries with Superior Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MnO2 is one of the most studied cathodes for aqueous neutral zinc-ion batteries. However, the diverse reported crystal structures of MnO2 compared to delta-MnO2 inevitably suffer a structural phase transition from tunneled to layered Zn-buserite during the initial cycles, which is not as kinetically direct as the conventional intercalation electrochemistry in layered materials and thus poses great challenges to the performance and multifunctionality of devices. Here, a binder-free delta-MnO2 cathode is designed and a favorable layered to layered Zn2+ storage mechanism is revealed systematically using such a noninterferencing electrode platform in combination with ab initio calculation. A flexible quasi-solid-state Zn-Mn battery with an electrodeposited flexible Zn anode is further assembled, exhibiting high energy density (35.11 mWh cm(-3); 432.05 Wh kg(-1)), high power density (676.92 mW cm(-3); 8.33 kW kg(-1)), extremely low self-discharge rate, and ultralong stability up to 10 000 cycles. Even with a relatively high delta-MnO2 mass loading of 5 mg cm(-2), significant energy and power densities are still achieved. The device also works well over a broad temperature range (0-40 degrees C) and can efficiently power different types of small electronics. This work provides an opportunity to develop high-performance multivalent-ion batteries via the design of a kinetically favorable host structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902795, "DOI": "10.1002/advs.201902795", "DOI Link": "http://dx.doi.org/10.1002/advs.201902795", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507549200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palm, GJ; Reisky, L; Böttcher, D; Müller, H; Michels, EAP; Walczak, MC; Berndt, L; Weiss, MS; Bornscheuer, UT; Weber, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palm, Gottfried J.; Reisky, Lukas; Boettcher, Dominique; Mueller, Henrik; Michels, Emil A. P.; Walczak, Miriam C.; Berndt, Leona; Weiss, Manfred S.; Bornscheuer, Uwe T.; Weber, Gert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure of the plastic-degrading Ideonella sakaiensis MHETase bound to a substrate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The extreme durability of polyethylene terephthalate (PET) debris has rendered it a long-term environmental burden. At the same time, current recycling efforts still lack sustainability. Two recently discovered bacterial enzymes that specifically degrade PET represent a promising solution. First, Ideonella sakaiensis PETase, a structurally well-characterized consensus alpha/beta-hydrolase fold enzyme, converts PET to mono-(2-hydroxyethyl) terephthalate (MHET). MHETase, the second key enzyme, hydrolyzes MHET to the PET educts terephthalate and ethylene glycol. Here, we report the crystal structures of active ligand-free MHETase and MHETase bound to a nonhydrolyzable MHET analog. MHETase, which is reminiscent of feruloyl esterases, possesses a classic alpha/beta-hydrolase domain and a lid domain conferring substrate specificity. In the light of structure-based mapping of the active site, activity assays, mutagenesis studies and a first structure-guided alteration of substrate specificity towards bis-(2-hydroxyethyl) terephthalate (BHET) reported here, we anticipate MHETase to be a valuable resource to further advance enzymatic plastic degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1717, "DOI": "10.1038/s41467-019-09326-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09326-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464338100028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "S", "Authors": "Nielsen, AV; Beauchamp, MJ; Nordin, GP; Woolley, AT", "Book Authors": null, "Book Editors": "Bohn, PW; Pemberton, JE", "Book Group Authors": null, "Author Full Names": "Nielsen, Anna V.; Beauchamp, Michael J.; Nordin, Gregory P.; Woolley, Adam T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Microfluidics", "Source Title": "ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 13", "Book Series Title": "Annual Review of Analytical Chemistry", "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Book Chapter", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional microfabrication techniques suffer from several disadvantages, including the inability to create truly three-dimensional (3D) architectures, expensive and time-consuming processes when changing device designs, and difficulty in transitioning from prototyping fabrication to bulk manufacturing. 3D printing is an emerging technique that could overcome these disadvantages. While most 3D printed fluidic devices and features to date have been on the millifluidic size scale, some truly microfluidic devices have been shown. Currently, stereolithography is the most promising approach for routine creation of microfluidic structures, but several approaches under development also have potential. Microfluidic 3D printing is still in an early stage, similar to where polydimethylsiloxane was two decades ago. With additional work to advance printer hardware and software control, expand and improve resin and printing material selections, and realize additional applications for 3D printed devices, we foresee 3D printing becoming the dominullt microfluidic fabrication method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2020, "Volume": 13, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": 65, "Article Number": null, "DOI": "10.1146/annurev-anchem-091619-102649", "DOI Link": "http://dx.doi.org/10.1146/annurev-anchem-091619-102649", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Spectroscopy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591551900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SY; Tang, YQ; Kang, WX; Bisoyi, HK; Guo, JB; Li, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Siyang; Tang, Yuqi; Kang, Wenxin; Bisoyi, Hari Krishna; Guo, Jinbao; Li, Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photo-triggered full-color circularly polarized luminescence based on photonic capsules for multilevel information encryption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with phototunable full-color circularly polarized luminescence (CPL) have a large storage density, high-security level, and enormous prospects in the field of information encryption and decryption. In this work, device-friendly solid films with color tunability are prepared by constructing Forster resonullce energy transfer (FRET) platforms with chiral donors and achiral molecular switches in liquid crystal photonic capsules (LCPCs). These LCPCs exhibit photoswitchable CPL from initial blue emission to RGB trichromatic signals under UV irradiation due to the synergistic effect of energy and chirality transfer and show strong time dependence because of the different FRET efficiencies at each time node. Based on these phototunable CPL and time response characteristics, the concept of multilevel data encryption by using LCPC films is demonstrated. Phototunable full-color circularly polarized luminescence (CPL) features large storage density which is important for the field of information encryption and decryption. Here, the authors present a device-friendly solid film with color-tunability by employing Forster resonullce energy transfer among a chiral donor and achiral molecular switches in a liquid crystal photonic capsules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3005, "DOI": "10.1038/s41467-023-38801-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38801-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001080600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, TY; Chen, MP; Wu, F; Smart, TJ; Wang, SW; Wu, YS; Zhang, Y; Li, ST; Lall, S; Zhang, ZH; Liu, YS; Guo, JH; Wang, GM; Ping, Y; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Tianyi; Chen, Mingpeng; Wu, Feng; Smart, Tyler J.; Wang, Shanwen; Wu, Yishang; Zhang, Ying; Li, Shengtong; Lall, Supriya; Zhang, Zhonghua; Liu, Yi-Sheng; Guo, Jinghua; Wang, Gongming; Ping, Yuan; Li, Yat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon doping switching on the hydrogen adsorption activity of NiO for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction (HER) is more sluggish in alkaline than in acidic media because of the additional energy required for water dissociation. Numerous catalysts, including NiO, that offer active sites for water dissociation have been extensively investigated. Yet, the overall HER performance of NiO is still limited by lacking favorable H adsorption sites. Here we show a strategy to activate NiO through carbon doping, which creates under-coordinated Ni sites favorable for H adsorption. DFT calculations reveal that carbon dopant decreases the energy barrier of Heyrovsky step from 1.17eV to 0.81eV, suggesting the carbon also serves as a hot-spot for the dissociation of water molecules in water-alkali HER. As a result, the carbon doped NiO catalyst achieves an ultralow overpotential of 27mV at 10mAcm(-2), and a low Tafel slope of 36mVdec(-1), representing the best performance among the state-of-the-art NiO catalysts. While H-2 evolution from water may serve as a renewable source of fuel, there are a limited number of catalysts that are stable and active in alkaline media. Here, authors find carbon doping of NiO to increase the number of favorable sites for H-2 evolution and boost electrocatalytic performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-14462-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14462-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543981700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasmussen, FA; Thygesen, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasmussen, Filip A.; Thygesen, Kristian S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computational 2D Materials Database: Electronic Structure of Transition-Metal Dichalcogenides and Oxides", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a comprehensive first-principles study of the electronic structure of 51 semiconducting monolayer transition-metal dichalcogenides and -oxides in the 2H and 1T hexagonal phases. The quasiparticle (QP) band structures with spin-orbit coupling are calculated in the G(0)W(0) approximation, and comparison is made with different density functional theory descriptions. Pitfalls related to the convergence of GW calculations for two-dimensional (2D) materials are discussed together with possible solutions. The monolayer band edge positions relative to vacuum are used to estimate the band alignment at various heterostructure interfaces. The sensitivity of the band structures to the in-plane lattice constant is analyzed and rationalized in terms of the electronic structure. Finally, the q-dependent dielectric functions and effective electron and hole masses are obtained from the QP band structure and used as input to a 2D hydrogenic model to estimate exciton binding energies. Throughout the paper we focus on trends and correlations in the electronic structure rather than detailed analysis of specific materials. All the computed data is available in an open database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 901, "Times Cited, All Databases": 974, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2015, "Volume": 119, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13169, "End Page": 13183, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b02950", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b02950", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356317500044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, LT; Zhang, MY; Huang, P; Guo, GC; Hong, MC; Li, CS; Irvine, JTS; Xie, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Lingting; Zhang, Minyi; Huang, Ping; Guo, Guocong; Hong, Maochun; Li, Chunsen; Irvine, John T. S.; Xie, Kui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing CO2 electrolysis through synergistic control of non-stoichiometry and doping to tune cathode surface structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable future energy scenarios require significant efficiency improvements in both electricity generation and storage. High-temperature solid oxide cells, and in particular carbon dioxide electrolysers, afford chemical storage of available electricity that can both stabilize and extend the utilization of renewables. Here we present a double doping strategy to facilitate CO2 reduction at perovskite titanate cathode surfaces, promoting adsorption/activation by making use of redox active dopants such as Mn linked to oxygen vacancies and dopants such as Ni that afford metal nulloparticle exsolution. Combined experimental characterization and first-principle calculations reveal that the adsorbed and activated CO2 adopts an intermediate chemical state between a carbon dioxide molecule and a carbonate ion. The dual doping strategy provides optimal performance with no degradation being observed after 100 h of high-temperature operation and 10 redox cycles, suggesting a reliable cathode material for CO2 electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14785, "DOI": "10.1038/ncomms14785", "DOI Link": "http://dx.doi.org/10.1038/ncomms14785", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396399300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, TL; Ono, LK; Li, J; Su, J; Tong, GQ; Zhang, W; Liu, YQ; Zhang, JH; Chang, JJ; Kazaoui, S; Huang, FZ; Cheng, YB; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Tongle; Ono, Luis K.; Li, Jing; Su, Jie; Tong, Guoqing; Zhang, Wei; Liu, Yuqiang; Zhang, Jiahao; Chang, Jingjing; Kazaoui, Said; Huang, Fuzhi; Cheng, Yi-Bing; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating crystal growth of formamidinium-caesium perovskites for over 200 cm2 photovoltaic sub-modules", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Upscaling perovskite solar cells requires control of the crystallization of perovskite films over large areas. Here, the authors tailor the composition of the precursor ink and achieve 15.3% efficient solar cells over a 205 cm(2) area without the use of anti-solvent. Upscalable fabrication of efficient and stable perovskite solar modules is urgently needed for commercialization. Here we introduce methylammonium chloride additives in the co-solvent system of N-methyl-2-pyrrolidone/N,N-dimethylformamide to control the formation of intermediate phases during the growth of formamidinium-caesium lead triiodide perovskite films. We achieve high-quality films upon drying without the use of anti-solvent. By implementing bulk and surface passivation, champion efficiencies of 24.02% for a small-sized solar cell and 20.5% for a 5 cm x 5 cm solar mini-module on an aperture area of 22.4 cm(2) (geometric fill factor similar to 96%) are achieved by spin-coating. The fully blade-coated perovskite solar sub-module demonstrates a champion efficiency of 15.3% on an aperture area of 205 cm(2). The solar mini-module exhibits impressive operational stability with a T-80 lifetime of over 1,000 h at maximum power point tracking under continuous light illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 528, "End Page": 536, "Article Number": null, "DOI": "10.1038/s41560-022-01039-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01039-0", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805082400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, W; Zhang, J; Li, M; Züttel, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Wen; Zhang, Jie; Li, Mo; Zuttel, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting CO Production in Electrocatalytic CO2 Reduction on Highly Porous Zn Catalysts", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earth-abundant electrocatalysts are desirable for the efficient and selective reduction of CO2 to value-added chemicals. Here, a low-cost porous Zn electrocatalyst is synthesized using a facile electrodeposition method to boost the performance of CO2 electro-catalytic reaction (CO2RR). In an H-cell reactor, the porous Zn catalyst can convert CO2 to CO at a remarkably high faradaic efficiency (FE, similar to 95%) and current density (27 mA cm(-2)) at -0.95 V versus the reversible hydrogen electrode. Detailed electrokinetic studies demonstrate that instead of the enhanced intrinsic activity, the dramatically increased active sites play a decisive role in improving the catalytic activity. In addition, the high local pH induced by the highly porous structure of Zn results in enhanced CO selectivity because of the suppressed H-2 evolution. Furthermore, we present a straightforward strategy to transform the porous Zn electrode into a gas diffusion electrode. This way, the CO2RR current density can be boosted to 200 mA cm(-2) with similar to 84% FE for CO at -0.64 V in a flow-cell reactor, which is, to date, the best performance observed over non-noble CO2RR catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3783, "End Page": 3791, "Article Number": null, "DOI": "10.1021/acscatal.8b05109", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b05109", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467335600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Auvergniot, J; Cassel, A; Foix, D; Viallet, V; Seznec, V; Dedryvère, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Auvergniot, Jeremie; Cassel, Alice; Foix, Dominique; Viallet, Virgine; Seznec, Vincent; Dedryvere, Remi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study", "Source Title": "SOLID STATE IONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Argyrodite Li6PS5Cl is a good candidate as solid electrolyte for bulk all-solid-state Li-ion batteries due to its high ionic conductivity and its good processability, although it shows some interface reactivity towards electrode active materials. In this work we have cycled LiCoO2/Li6PS5Cl/Li4Ti5O12 full cells and analyzed the interfacial mechanisms by surface-sensitive characterization techniques: Auger Electron Spectroscopy (AES) and X-ray Photoelectron Spectroscopy (XPS). We show that Li6PS5Cl has an electrochemical redox activity in the positive electrode. It is partially oxidized into LiCl, P2S5 and polysulfides Li2Sn upon charge, with some reversibility upon discharge. Li6PS5Cl also reacts with LiCoO2 upon cycling, leading to the formation of phosphates at the interface. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 300, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 85, "Article Number": null, "DOI": "10.1016/j.ssi.2016.11.029", "DOI Link": "http://dx.doi.org/10.1016/j.ssi.2016.11.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393929400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brivio, F; Butler, KT; Walsh, A; van Schilfgaarde, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brivio, Federico; Butler, Keith T.; Walsh, Aron; van Schilfgaarde, Mark", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar cells based on a light absorbing layer of the organometal halide perovskite CH3NH3PbI3 have recently surpassed 15% conversion efficiency, though how these materials work remains largely unknown. We analyze the electronic structure and optical properties within the quasiparticle self-consistent GW approximation. While this compound bears some similarity to conventional sp semiconductors, it also displays unique features. Quasiparticle self-consistency is essential for an accurate description of the band structure: Band gaps are much larger than what is predicted by the local-density approximation (LDA) or GW based on the LDA. Valence band dispersions are modified in a very unusual manner. In addition, spin-orbit coupling strongly modifies the band structure and gives rise to unconventional dispersion relations and a Dresselhaus splitting at the band edges. The average hole mass is small, which partially accounts for the long diffusion lengths observed. The surface ionization potential (work function) is calculated to be 5.7 eV with respect to the vacuum level, explaining efficient carrier transfer to TiO2 and Au electrical contacts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 601, "Times Cited, All Databases": 646, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2014, "Volume": 89, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 155204, "DOI": "10.1103/PhysRevB.89.155204", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.155204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335232700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ebrahimi, A; Withayachumnullkul, W; Al-Sarawi, S; Abbott, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ebrahimi, Amir; Withayachumnullkul, Withawat; Al-Sarawi, Said; Abbott, Derek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Sensitivity Metamaterial-Inspired Sensor for Microfluidic Dielectric Characterization", "Source Title": "IEEE SENSORS JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new metamaterial-inspired microwave microfluidic sensor is proposed in this paper. The main part of the device is a microstrip coupled complementary split-ring resonator (CSRR). At resonullce, a strong electric field will be established along the sides of CSRR producing a very sensitive area to a change in the nearby dielectric material. A micro-channel is positioned over this area for microfluidic sensing. The liquid sample flowing inside the channel modifies the resonullce frequency and peak attenuation of the CSRR resonullce. The dielectric properties of the liquid sample can be estimated by establishing an empirical relation between the resonullce characteristics and the sample complex permittivity. The designed microfluidic sensor requires a very small amount of sample for testing since the cross-sectional area of the sensing channel is over five orders of magnitude smaller than the square of the wavelength. The proposed microfluidic sensing concept is compatible with lab-on-a-chip platforms owing to its compactness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 566, "Times Cited, All Databases": 580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1345, "End Page": 1351, "Article Number": null, "DOI": "10.1109/JSEN.2013.2295312", "DOI Link": "http://dx.doi.org/10.1109/JSEN.2013.2295312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333112300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Caprioli, M; Roppolo, I; Chiappone, A; Larush, L; Pirri, CF; Magdassi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Caprioli, Matteo; Roppolo, Ignazio; Chiappone, Annalisa; Larush, Liraz; Pirri, Candido Fabrizio; Magdassi, Shlomo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D-printed self-healing hydrogels via Digital Light Processing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing hydrogels may mimic the behavior of living tissues, which can autonomously repair minor damages, and therefore have a high potential for application in biomedicine. So far, such hydrogels have been processed only via extrusion-based additive manufacturing technology, limited in freedom of design and resolution. Herein, we present 3D-printed hydrogel with self-healing ability, fabricated using only commercially available materials and a commercial Digital Light Processing printer. These hydrogels are based on a semi-interpenetrated polymeric network, enabling self-repair of the printed objects. The autonomous restoration occurs rapidly, at room temperature, and without any external trigger. After rejoining, the samples can withstand deformation and recovered 72% of their initial strength after 12hours. The proposed approach enables 3D printing of self-healing hydrogels objects with complex architecture, paving the way for future applications in diverse fields, ranging from soft robotics to energy storage. Self-healing hydrogels can mimic the damage repair behaviour of living tissues, but such hydrogels have only been processed via extrusion-based additive manufacturing technology. Here, the authors demonstrate a rapidly self-healing hydrogel which can be processed by DLP printing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2462, "DOI": "10.1038/s41467-021-22802-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22802-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000647110400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, HY; Chen, ZY; Mao, M; Wu, YY; Yang, F; Gong, LX; Zhao, L; Cao, CF; Song, PA; Gao, JF; Zhang, GD; Shi, YQ; Cao, K; Tang, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hai-Yang; Chen, Zuan-Yu; Mao, Min; Wu, Yu-Yue; Yang, Fan; Gong, Li-Xiu; Zhao, Li; Cao, Cheng-Fei; Song, Pingan; Gao, Jie-Feng; Zhang, Guo-Dong; Shi, Yong-Qian; Cao, Kun; Tang, Long-Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Adhesive Polydimethylsiloxane Foam Materials Decorated with MXene/Cellulose nullofiber Interconnected Network for Versatile Functionalities", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydimethylsiloxanes (PDMS) foam as one of next-generation polymer foam materials shows poor surface adhesion and limited functionality, which greatly restricts its potential applications. Fabrication of advanced PDMS foam materials with multiple functionalities remains a critical challenge. In this study, unprecedented self-adhesive PDMS foam materials are reported with worm-like rough structure and reactive groups for fabricating multifunctional PDMS foam nullocomposites decorated with MXene/cellulose nullofiber (MXene/CNF) interconnected network by a facile silicone foaming and dip-coating strategy followed by silane surface modification. Interestingly, such self-adhesive PDMS foam produces strong interfacial adhesion with the hybrid MXene/CNF nullo-coatings. Consequently, the optimized PDMS foam nullocomposites have excellent surface super-hydrophobicity (water contact angle of & AP;159(o)), tunable electrical conductivity (from 10(-8) to 10 S m(-1)), stable compressive cyclic reliability in both wide-temperature range (from -20 to 200 C-o) and complex environments (acid, sodium, and alkali conditions), outstanding flame resistance (LOI value of >27% and low smoke production rate), good thermal insulating performance and reliable strain sensing in various stress modes and complex environmental conditions. It provides a new route for the rational design and development of advanced PDMS foam nullocomposites with versatile multifunctionalities for various promising applications such as intelligent healthcare monitoring and fire-safe thermal insulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 33, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202304927", "DOI Link": "http://dx.doi.org/10.1002/adfm.202304927", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026758600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, RYK; Li, YQ; Han, S; Chen, XX; Chen, JQ; He, J; Gao, HW; Yang, Y; Yang, SL; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Renyikun; Li, Yuqing; Han, Shan; Chen, Xinxin; Chen, Jingqi; He, Jia; Gao, Hongwei; Yang, Yang; Yang, Shilin; Yang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe-Curcumin nullozyme-Mediated Reactive Oxygen Species Scavenging and Anti-Inflammation for Acute Lung Injury", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pneumonia, such as acute lung injury (ALI), has been a type of lethal disease that is generally caused by uncontrolled inflammatory response and excessive generation of reactive oxygen species (ROS). Herein, we report Fe-curcuminbased nulloparticles (Fe-Cur NPs) with nullozyme functionalitYies in guiding the intracellular ROS scavenging and meanwhile exhibiting anti-inflammation efficacy for curing ALI. The nulloparticles are noncytotoxic when directing these biological activities. Mechanism studies for the anti-inflammation aspects of Fe-Cur NPs were systematically carried out, in which the infected cells and tissues were alleviated through downregulating levels of several important inflammatory cytokines (such as TNF-alpha, IL-1 beta, and IL6), decreasing the intracellular Ca2+ release, inhibiting NLRP3 inflammasomes, and suppressing NF-kappa B signaling pathways. In addition, we performed both the intratracheal and intravenous injection of Fe-Cur NPs in mice experiencing ALI and, importantly, found that the accumulation of such nullozymes was enhanced in lung tissue (better than free curcumin drugs), demonstrating its promising therapeutic efficiency in two different administration methods. We showed that the inflammation reduction of Fe-Cur NPs was effective in animal experiments and that ROS scavenging was also effectively achieved in lung tissue. Finally, we revealed that Fe-Cur NPs can decrease the level of macrophage cells (CD11b(lo)F4/80(hi)) and CD3(+)CD45(+) T cells in mice, which could help suppress the inflammation cytokine storm caused by ALI. Overall, this work has developed the strategy of using Fe-Cur NPs as nullozymes to scavenge intracellular ROS and as an antiinflammation nullodrugs to synergistically cure ALI, which may serve as a promising therapeutic agent in the clinical treatment of this deadly disease. Fe-Cur NP nullozymes were designed to attenuate ALI by clearing intracellular ROS and alleviating inflammation synergistically. Relevant cytokines, inflammasomes, and signaling pathways were studied.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10, "End Page": 21, "Article Number": null, "DOI": "10.1021/acscentsci.1c00866", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.1c00866", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748376700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yadollahi, A; Shamsaei, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yadollahi, Aref; Shamsaei, Nima", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of fatigue resistant materials: Challenges and opportunities", "Source Title": "INTERNATIONAL JOURNAL OF FATIGUE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This overview focuses on the current state of knowledge pertaining to the mechanical characteristics of metallic parts fabricated via additive manufacturing (AM), as well as the ongoing challenges and imminent opportunities in fabricating materials with increased fatigue resistance. Current experimental evidence suggests that the mechanical properties of laboratory AM specimens may not be representative of those associated with parts, due primarily to differences in geometry/size which influence the thermal histories experienced during fabrication, and consequently, microstructural features, surface roughness, and more. In addition, standards for mechanical testing methods, specimen design procedures, post manufacturing treatments, etc., may need to be revised for AM parts. Standardizing the AM process may only be accomplished by strengthening the current understanding of the relationships among process parameters, thermal history, solidification, resultant microstructure, and mechanical behavior of the part. Having the ability to predict variations in mechanical behavior based on resultant microstructure, or matching the best conceivable properties of a part in accordance with the loading critical plane, are some possible solutions for making AM a more reliable means for producing functional parts. Developing microstructure-property models is arguably the first necessary step toward design optimization and the more efficient, accurate estimation of the structural integrity of AM parts. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 686, "Times Cited, All Databases": 752, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 98, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14, "End Page": 31, "Article Number": null, "DOI": "10.1016/j.ijfatigue.2017.01.001", "DOI Link": "http://dx.doi.org/10.1016/j.ijfatigue.2017.01.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398008100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, R; Mishra, B; Traxler, M; Roeser, J; Chaoui, N; Kumbhakar, B; Schmidt, J; Li, S; Thomas, A; Pachfule, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Rui; Mishra, Bikash; Traxler, Michael; Roeser, Jerome; Chaoui, Nicolas; Kumbhakar, Bidhan; Schmidt, Johannes; Li, Shuang; Thomas, Arne; Pachfule, Pradip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Thiazole-linked Covalent Organic Framework for Lithium-Sulphur Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulphur (Li-S) batteries are a promising alternative power source, as they can provide a higher energy density than current lithium-ion batteries. Porous materials are often used as cathode materials as they can act as a host for sulphur in such batteries. Recently, covalent organic frameworks (COFs) have also been used, however they typically suffer from stability issues, resulting in limited and thus insufficient durability under practical conditions and applications. Herein, we report the synthesis of a crystalline and porous imine-linked triazine-based dimethoxybenzo-dithiophene functionalized COF (TTT-DMTD) incorporating high-density redox sites. The imine linkages were further post-synthetically transformed to yield a robust thiazole-linked COF (THZ-DMTD) by utilizing a sulphur-assisted chemical conversion method, while maintaining the crystallinity. As a synergistic effect of its high crystallinity, porosity and the presence of redox-active moieties, the thiazole-linked THZ-DMTD exhibited a high capacity and long-term stability (642 mAh g(-1) at 1.0 C; 78.9 % capacity retention after 200 cycles) when applied as a cathode material in a Li-S battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2023, "Volume": 62, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202302276", "DOI Link": "http://dx.doi.org/10.1002/anie.202302276", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001016784800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, LZ; Gutbrod, SR; Bonifas, AP; Su, YW; Sulkin, MS; Lu, NS; Chung, HJ; Jang, KI; Liu, ZJ; Ying, M; Lu, C; Webb, RC; Kim, JS; Laughner, JI; Cheng, HY; Liu, YH; Ameen, A; Jeong, JW; Kim, GT; Huang, YG; Efimov, IR; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Lizhi; Gutbrod, Sarah R.; Bonifas, Andrew P.; Su, Yewang; Sulkin, Matthew S.; Lu, nullshu; Chung, Hyun-Joong; Jang, Kyung-In; Liu, Zhuangjian; Ying, Ming; Lu, Chi; Webb, R. Chad; Kim, Jong-Seon; Laughner, Jacob I.; Cheng, Huanyu; Liu, Yuhao; Ameen, Abid; Jeong, Jae-Woong; Kim, Gwang-Tae; Huang, Yonggang; Efimov, Igor R.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D multifunctional integumentary membranes for spatiotemporal cardiac measurements and stimulation across the entire epicardium", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Means for high-density multiparametric physiological mapping and stimulation are critically important in both basic and clinical cardiology. Current conformal electronic systems are essentially 2D sheets, which cannot cover the full epicardial surface or maintain reliable contact for chronic use without sutures or adhesives. Here we create 3D elastic membranes shaped precisely to match the epicardium of the heart via the use of 3D printing, as a platform for deformable arrays of multifunctional sensors, electronic and optoelectronic components. Such integumentary devices completely envelop the heart, in a form-fitting manner, and possess inherent elasticity, providing a mechanically stable biotic/abiotic interface during normal cardiac cycles. Component examples range from actuators for electrical, thermal and optical stimulation, to sensors for pH, temperature and mechanical strain. The semiconductor materials include silicon, gallium arsenide and gallium nitride, co-integrated with metals, metal oxides and polymers, to provide these and other operational capabilities. Ex vivo physiological experiments demonstrate various functions and methodological possibilities for cardiac research and therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3329, "DOI": "10.1038/ncomms4329", "DOI Link": "http://dx.doi.org/10.1038/ncomms4329", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332668300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; Kim, DH; Lu, HP; Park, JS; Larson, BW; Hu, J; Gao, LG; Xiao, CX; Reid, OG; Chen, XH; Zhao, Q; Ndione, PF; Berry, JJ; You, W; Walsh, A; Beard, MC; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fei; Kim, Dong Hoe; Lu, Haipeng; Park, Ji-Sang; Larson, Bryon W.; Hu, Jun; Gao, Liguo; Xiao, Chuanxiao; Reid, Obadiah G.; Chen, Xihan; Zhao, Qian; Ndione, Paul F.; Berry, Joseph J.; You, Wei; Walsh, Aron; Beard, Matthew C.; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Charge Transport in 2D Perovskites via Fluorination of Organic Cation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic halide perovskites incorporating two-dimensional (2D) structures have shown promise for enhancing the stability of perovskite solar cells (PSCs). However, the bulky spacer cations often limit charge transport. Here, we report on a simple approach based on molecular design of the organic spacer to improve the transport properties of 2D perovskites, and we use phenethylammonium (PEA) as an example. We demonstrate that by fluorine substitution on the para position in PEA to form 4-fluorophenethylammonium (F-PEA), the average phenyl ring centroid-centroid distances in the organic layer become shorter with better aligned stacking of perovskite sheets. The impact is enhanced orbital interactions and charge transport across adjacent inorganic layers as well as increased carrier lifetime and reduced trap density. Using a simple perovskite deposition at room temperature without using any additives, we obtained a power conversion efficiency of >13% for (F-PEA)(2)MA(4)Pb(5)I(16)-based PSCs. In addition, the thermal stability of 2D PSCs based on F-PEA is significantly enhanced compared to those based on PEA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2019, "Volume": 141, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5972, "End Page": 5979, "Article Number": null, "DOI": "10.1021/jacs.9b00972", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00972", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464769000049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, LB; Cheng, L; Ma, TH; Zhang, JJ; Wu, HK; Su, JJ; Song, Y; Zhu, H; Liu, Q; Zhu, MH; Zeng, ZY; He, QY; Tse, MK; Yang, DT; Yakobson, BI; Tang, BZ; Ren, Y; Ye, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Libei; Cheng, Le; Ma, Tinghao; Zhang, Jun-Jie; Wu, Haikun; Su, Jianjun; Song, Yun; Zhu, He; Liu, Qi; Zhu, Minghui; Zeng, Zhiyuan; He, Qiyuan; Tse, Man-Kit; Yang, Deng-tao; Yakobson, Boris I.; Tang, Ben Zhong; Ren, Yang; Ye, Ruquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Synthesis of Ammonia from Nitrate on Amorphous Graphene with Near 100% Efficiency", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia is an indispensable commodity in the agricultural and pharmaceutical industries. Direct nitrate-to-ammonia electroreduction is a decentralized route yet challenged by competing side reactions. Most catalysts are metal-based, and metal-free catalysts with high nitrate-to-ammonia conversion activity are rarely reported. Herein, it is shown that amorphous graphene synthesized by laser induction and comprising strained and disordered pentagons, hexagons, and heptagons can electrocatalyze the eight-electron reduction of NO3- to NH3 with a Faradaic efficiency of approximate to 100% and an ammonia production rate of 2859 mu g cm(-2) h(-1) at -0.93 V versus reversible hydrogen electrode. X-ray pair-distribution function analysis and electron microscopy reveal the unique molecular features of amorphous graphene that facilitate NO3- reduction. In situ Fourier transform infrared spectroscopy and theoretical calculations establish the critical role of these features in stabilizing the reaction intermediates via structural relaxation. The enhanced catalytic activity enables the implementation of flow electrolysis for the on-demand synthesis and release of ammonia with >70% selectivity, resulting in significantly increased yields and survival rates when applied to plant cultivation. The results of this study show significant promise for remediating nitrate-polluted water and completing the NOx cycle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202211856", "DOI Link": "http://dx.doi.org/10.1002/adma.202211856", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000977863800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, D; Wang, YD; Ma, CJ; Han, L; Jiang, BQ; Gan, XT; Hua, SJ; Zhang, WD; Mei, T; Zhao, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Dong; Wang, Yadong; Ma, Chaojie; Han, Lei; Jiang, Biqiang; Gan, Xuetao; Hua, Shijia; Zhang, Wending; Mei, Ting; Zhao, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WS2 mode-locked ultrafast fiber laser", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene-like two dimensional materials, such as WS2 and MoS2, are highly anisotropic layered compounds that have attracted growing interest from basic research to practical applications. Similar with MoS2, few-layer WS2 has remarkable physical properties. Here, we demonstrate for the first time that WS2 nullosheets exhibit ultrafast nonlinear saturable absorption property and high optical damage threshold. Soliton mode-locking operations are achieved separately in an erbium-doped fiber laser using two types of WS2-based saturable absorbers, one of which is fabricated by depositing WS2 nullosheets on a D-shaped fiber, while the other is synthesized by mixing WS2 solution with polyvinyl alcohol, and then evaporating them on a substrate. At the maximum pump power of 600 mW, two saturable absorbers can work stably at mode-locking state without damage, indicating that few-layer WS2 is a promising high-power flexible saturable absorber for ultrafast optics. Numerous applications may benefit from the ultrafast nonlinear features of WS2 nullosheets, such as high-power pulsed laser, materials processing, and frequency comb spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7965, "DOI": "10.1038/srep07965", "DOI Link": "http://dx.doi.org/10.1038/srep07965", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348165500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wickramaratne, D; Zahid, F; Lake, RK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wickramaratne, Darshana; Zahid, Ferdows; Lake, Roger K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic and thermoelectric properties of few-layer transition metal dichalcogenides", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic and thermoelectric properties of one to four monolayers of MoS2, MoSe2, WS2, and WSe2 are calculated. For few layer thicknesses, the near degeneracies of the conduction band K and Sigma valleys and the valence band Gamma and K valleys enhance the n-type and p-type thermoelectric performance. The interlayer hybridization and energy level splitting determine how the number of modes within k(B)T of a valley minimum changes with layer thickness. In all cases, the maximum ZT coincides with the greatest near-degeneracy within k(B)T of the band edge that results in the sharpest turn-on of the density of modes. The thickness at which this maximum occurs is, in general, not a monolayer. The transition from few layers to bulk is discussed. Effective masses, energy gaps, powerfactors, and ZT values are tabulated for all materials and layer thicknesses. (c) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2014, "Volume": 140, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124710, "DOI": "10.1063/1.4869142", "DOI Link": "http://dx.doi.org/10.1063/1.4869142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334169000061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Dang, AL; Li, TH; Sun, YT; Lee, TC; Deng, WB; Wu, SH; Zada, A; Zhao, TK; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xin; Dang, Alei; Li, Tiehu; Sun, Yiting; Lee, Tung-Chun; Deng, Weibin; Wu, Shaoheng; Zada, Amir; Zhao, Tingkai; Li, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic Coupling of Au nulloclusters on a Flexible MXene/ Graphene Oxide Fiber for Ultrasensitive SERS Sensing", "Source Title": "ACS SENSORS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High sensitivity, good signal repeatability, and facile fabrication of flexible surface enhanced Raman scattering (SERS) substrates are common pursuits of researchers for the detection of probe molecules in a complex environment. However, fragile adhesion between the noble-metal nulloparticles and substrate material, low selectivity, and complex fabrication process on a large scale limit SERS technology for wide-ranging applications. Herein, we propose a scalable and cost-effective strategy to a fabricate sensitive and mechanically stable flexible Ti3C2Tx MXene@graphene oxide/Au nulloclusters (MG/AuNCs) fiber SERS substrate from wet spinning and subsequent in situ reduction processes. The use of MG fiber provides good flexibility (114 MPa) and charge transfer enhancement (chemical mechanism, CM) for a SERS sensor and allows further in situ growth of AuNCs on its surface to build highly sensitive hot spots (electromagnetic mechanism, EM), promoting the durability and SERS performance of the substrate in complex environments. Therefore, the formed flexible MG/AuNCs-1 fiber exhibits a low detection limit of 1 x 10-11 M with a 2.01 x 109 enhancement factor (EFexp), signal repeatability (RSD = 9.80%), and time retention (remains 75% after 90 days of storage) for R6G molecules. Furthermore, the L-cysteine-modified MG/AuNCs-1 fiber realized the trace and selective detection of trinitrotoluene (TNT) molecules (0.1 mu M) via Meisenheimer complex formation, even by sampling the TNT molecules at a fingerprint or sample bag. These findings fill the gap in the large-scale fabrication of high-performance 2D materials/precious-metal particle composite SERS substrates, with the expectation of pushing flexible SERS sensors toward wider applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1287, "End Page": 1298, "Article Number": null, "DOI": "10.1021/acssensors.2c02808", "DOI Link": "http://dx.doi.org/10.1021/acssensors.2c02808", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955935100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoang, QT; Ravichandran, V; Cao, TGN; Kang, JH; Ko, YT; Lee, TI; Shim, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Quan Truong Hoang; Ravichandran, Vasanthan; Thuy Giang Nguyen Cao; Kang, Ji Hee; Ko, Young Tag; Lee, Tae Il; Shim, Min Suk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezoelectric Au-decorated ZnO nullorods: Ultrasound-triggered generation of ROS for piezocatalytic cancer therapy", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocatalytic cancer therapy that triggers catalytic reactions to generate cytotoxic reactive oxygen species (ROS) in target cancer cells has recently emerged as an effective therapeutic modality. In this study, piezoelectric, Au-decorated, poly(ethylene glycol)-coated zinc oxide nullorods (Au@P-ZnO NRs), a new class of nulloscale pie-zocatalysts, were developed for efficient cancer treatment via US-triggered piezocatalytic generation of ROS. The detailed piezocatalytic mechanism of Au@P-ZnO NRs was also proposed. Under US exposure, thermally excited electrons and holes that are produced in ZnO NRs are separated and accumulated at the surface by piezoelectric polarization, which subsequently catalyzes the generation of ROS for piezocatalytic cancer therapy. Au NPs, as Fenton-like catalysts, were deposited on the surface of the P-ZnO NRs to enhance the piezocatalytic generation of ROS. A pro-oxidant drug, piperlongumine (PL), was loaded into Au@P-ZnO NRs to enhance their cancer-specificity and anticancer effects. The variation in piezoelectric potential with respect to the size of the ZnO NRs and the pressure applied by US were calculated using COMSOL Multiphysics (R). Under US irradiation, the piezocatalytic Au@P-ZnO NRs considerably amplified intracellular ROS levels in MCF-7 human breast cancer cells. PL-loaded Au@P-ZnO NRs (PL-Au@P-ZnO NRs) revealed efficient and cancer-specific cytotoxicity in MCF-7 cells under US irradiation, thereby confirming effective chemo-piezocatalytic combination cancer therapy. Notably, a single intravenous injection of PL-Au@P-ZnO NRs with US exposure significantly suppressed tumor growth without resulting in systemic toxicity in mice. This study demonstrates the feasibility of PL-Au@P-ZnO NRs as US-triggered piezocatalytic agents that can selectively and effectively eradicate tumors via chemo-piezocatalytic combination therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2022, "Volume": 435, "Issue": null, "Part Number": 3, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 135039, "DOI": "10.1016/j.cej.2022.135039", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.135039", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786675300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, FS; Li, QY; Kimura, H; Xie, XB; Zhang, XY; Wu, NN; Sun, XQ; Bin Xu, B; Algadi, H; Pashameah, RA; Alanazih, AK; Alzahrani, E; Li, HD; Du, W; Guo, ZH; Hou, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fushan; Li, Qiuyu; Kimura, Hideo; Xie, Xiubo; Zhang, Xiaoyu; Wu, nullnull; Sun, Xueqin; Bin Xu, Ben; Algadi, Hassan; Pashameah, Rami Adel; Alanazih, Abdullah K.; Alzahrani, Eman; Li, Handong; Du, Wei; Guo, Zhanhu; Hou, Chuanxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphology controllable urchin-shaped bimetallic nickel-cobalt oxide/carbon composites with enhanced electromagnetic wave absorption performance", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The microscopic morphology of electromagnetic wave absorbers influences the multiple reflections of electromagnetic waves and impedance matching, determining the absorption properties. Herein, the urchin-shaped bimetallic nickel-cobalt oxide/carbon (NiCo2O4/C) composites are prepared via a hy-drothermal route, whose absorption properties are investigated by different morphologies regulated by changing calcination temperature. A minimum reflection loss (RLmin) of-75.26 dB is achieved at a match-ing thickness of 1.5 mm, and the effective absorption bandwidth (EAB) of 8.96 GHz is achieved at 2 mm. Multi-advantages of the synthesized NiCo2O4/C composites contribute to satisfactory absorption proper-ties. First, the interweaving of the needle-like structures increases the opportunities for scattering and multiple reflections of incident electromagnetic waves, and builds up a conductive network to facilitate the enhancement of conductive losses. Second, the carbon component in the NiCo2O4/C composites en-hances the interfacial polarization and reduces the density of the absorber. Besides, generous oxygen va-cancy defects are introduced into the NiCo2O4/C composites, which induces defect polarization and dipole polarization. In summary, the ternary coordination of components, defects and morphology led to out-standing electromagnetic wave absorption, which lightened the path for improving the electromagnetic wave absorption property and enriching the family of NiCo2O4 absorbers with excellent performance.(c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2023, "Volume": 148, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 259, "Article Number": null, "DOI": "10.1016/j.jmst.2022.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2022.12.003", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939824400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, PX; Ji, X; Zhang, JX; Zhang, WR; Hou, S; Su, H; Li, MJ; Deng, T; Cao, LS; Liu, SF; He, XZ; Xu, YH; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Panxing; Ji, Xiao; Zhang, Jiaxun; Zhang, Weiran; Hou, Singyuk; Su, Hai; Li, Mengjie; Deng, Tao; Cao, Longsheng; Liu, Sufu; He, Xinzi; Xu, Yunhua; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of LiF-rich Cathode-Electrolyte Interphase by Electrolyte Reduction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capacity of transition metal oxide cathode for Li-ion batteries can be further enhanced by increasing the charging potential. However, these high voltage cathodes suffer from fast capacity decay because the large volume change of cathode breaks the active materials and cathode-electrolyte interphase (CEI), resulting in electrolyte penetration into broken active materials and continuous side reactions between cathode and electrolytes. Herein, a robust LiF-rich CEI was formed by potentiostatic reduction of fluorinated electrolyte at a low potential of 1.7 V. By taking LiCoO2 as a model cathode, we demonstrate that the LiF-rich CEI maintains the structural integrity and suppresses electrolyte penetration at a high cut-off potential of 4.6 V. The LiCoO2 with LiF-rich CEI exhibited a capacity of 198 mAh g(-1) at 0.5C and an enhanced capacity retention of 63.5 % over 400 cycles as compared to the LiF-free LiCoO2 with only 17.4 % of capacity retention.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2022, "Volume": 61, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202202731", "DOI": "10.1002/anie.202202731", "DOI Link": "http://dx.doi.org/10.1002/anie.202202731", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788369300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, Q; Huang, L; Yin, J; Davaasuren, B; Yuan, YY; Dong, XL; Wu, ZP; Wang, XQ; Yao, KX; Lu, X; Han, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Qiong; Huang, Liang; Yin, Jun; Davaasuren, Bambar; Yuan, Youyou; Dong, Xinglong; Wu, Zhi-Peng; Wang, Xiaoqian; Yao, Ke Xin; Lu, Xu; Han, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural evolution and strain generation of derived-Cu catalysts during CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper (Cu)-based catalysts generally exhibit high C2+ selectivity during the electrochemical CO2 reduction reaction (CO2RR). However, the origin of this selectivity and the influence of catalyst precursors on it are not fully understood. We combine operando X-ray diffraction and operando Raman spectroscopy to monitor the structural and compositional evolution of three Cu precursors during the CO2RR. The results indicate that despite different kinetics, all three precursors are completely reduced to Cu(O) with similar grain sizes (similar to 11 nm), and that oxidized Cu species are not involved in the CO2RR. Furthermore, Cu(OH)(2)- and Cu-2(OH)(2)CO3-derived Cu exhibit considerable tensile strain (0.43%similar to 0.55%), whereas CuO-derived Cu does not. Theoretical calculations suggest that the tensile strain in Cu lattice is conducive to promoting CO2RR, which is consistent with experimental observations. The high CO2RR performance of some derived Cu catalysts is attributed to the combined effect of the small grain size and lattice strain, both originating from the in situ electroreduction of precursors. These findings establish correlations between Cu precursors, lattice strains, and catalytic behaviors, demonstrating the unique ability of operando characterization in studying electrochemical processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4857, "DOI": "10.1038/s41467-022-32601-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32601-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842231900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, R; Pint, CL; Islam, AE; Weatherup, RS; Hofmann, S; Meshot, ER; Wu, FQ; Zhou, CW; Dee, N; Amama, PB; Carpena-Nuñez, J; Shi, WB; Plata, DL; Penev, ES; Yakobson, BI; Balbuena, PB; Bichara, C; Futaba, DN; Noda, S; Shin, HM; Kim, KS; Simard, B; Mirri, F; Pasquali, M; Fornasiero, F; Kauppinen, EI; Arnold, M; Cola, BA; Nikolaev, P; Arepalli, S; Cheng, HM; Zakharov, DN; Stach, EA; Zhang, J; Wei, F; Terrones, M; Geohegan, DB; Maruyama, B; Maruyama, S; Li, Y; Adams, WW; Hart, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Rahul; Pint, Cary L.; Islam, Ahmad E.; Weatherup, Robert S.; Hofmann, Stephan; Meshot, Eric R.; Wu, Fanqi; Zhou, Chongwu; Dee, Nicholas; Amama, Placidus B.; Carpena-Nunez, Jennifer; Shi, Wenbo; Plata, Desiree L.; Penev, Evgeni S.; Yakobson, Boris I.; Balbuena, Perla B.; Bichara, Christophe; Futaba, Don N.; Noda, Suguru; Shin, Homin; Kim, Keun Su; Simard, Benoit; Mirri, Francesca; Pasquali, Matteo; Fornasiero, Francesco; Kauppinen, Esko I.; Arnold, Michael; Cola, Baratunde A.; Nikolaev, Pavel; Arepalli, Sivaram; Cheng, Hui-Ming; Zakharov, Dmitri N.; Stach, Eric A.; Zhang, Jin; Wei, Fei; Terrones, Mauricio; Geohegan, David B.; Maruyama, Benji; Maruyama, Shigeo; Li, Yan; Adams, W. Wade; Hart, A. John", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon nullotubes and Related nullomaterials: Critical Advances and Challenges for Synthesis toward Mainstream Commercial Applications", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in the synthesis and scalable manufacturing of single-walled carbon nullotubes (SWCNTs) remain critical to realizing many important commercial applications. Here we review recent breakthroughs in the synthesis of SWCNTs and highlight key ongoing research areas and challenges. A few key applications that capitalize on the properties of SWCNTs are also reviewed with respect to the recent synthesis breakthroughs and ways in which synthesis science can enable advances in these applications. While the primary focus of this review is on the science framework of SWCNT growth, we draw connections to mechanisms underlying the synthesis of other 1D and 2D materials such as boron nitride nullotubes and graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11756, "End Page": 11784, "Article Number": null, "DOI": "10.1021/acsnullo.8b06511", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b06511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454567500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, HL; Si, HN; Zhang, ZH; Kang, Z; Wu, PW; Zhou, LX; Zhang, SC; Zhang, Z; Liao, QL; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Hualin; Si, Haonull; Zhang, Zihan; Kang, Zhuo; Wu, Pingwei; Zhou, Lixin; Zhang, Suicai; Zhang, Zheng; Liao, Qingliang; Zhang, Yue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Inorganic Perovskite Quantum Dot-Monolayer MoS2 Mixed-Dimensional van der Waals Heterostructure for Ultrasensitive Photodetector", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition metal dichalcogenide (2D-TMD) materials and their van der Waals heterostructures (vdWHs) have inspired worldwide efforts in the fields of electronics and optoelectronics. However, photodetectors based on 2D/2D vdWHs suffer from performance limitations due to the weak optical absorption of their atomically thin nature. In this work, taking advantage of an excellent light absorption coefficient, low-temperature solution-processability, and long charge carrier diffusion length, all-inorganic halides perovskite CsPbI3-xBrx quantum dots are integrated with monolayer MoS2 for high-performance and low-cost photodetectors. A favorable energy band alignment facilitating interfacial photocarrier separation and efficient carrier injection into the MoS2 layer inside the 0D-2D mixed-dimensional vdWHs are confirmed by a series of optical characterizations. Owing to the synergistic effect of the photogating mechanism and the modulation of Schottky barriers, the corresponding phototransistor exhibits a high photoresponsivity of 7.7 x 10(4) A W-1, a specific detectivity of approximate to 5.6 x 10(11) Jones, and an external quantum efficiency exceeding 10(7)%. The demonstration of such 0D-2D mixed-dimensional heterostructures proposed here would open up a wide realm of opportunities for designing low-cost, flexible transparent, and high-performance optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801219, "DOI": "10.1002/advs.201801219", "DOI Link": "http://dx.doi.org/10.1002/advs.201801219", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453685900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JZ; Uzun, S; Seyedin, S; Lynch, PA; Akuzum, B; Wang, ZY; Qin, S; Alhabeb, M; Shuck, CE; Lei, WW; Kumbur, EC; Yang, WR; Wang, XA; Dion, G; Razal, JM; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jizhen; Uzun, Simge; Seyedin, Shayan; Lynch, Peter A.; Akuzum, Bilen; Wang, Zhiyu; Qin, Si; Alhabeb, Mohamed; Shuck, Christopher E.; Lei, Weiwei; Kumbur, E. Caglan; Yang, Wenrong; Wang, Xungai; Dion, Genevieve; Razal, Joselito M.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive-Free MXene Liquid Crystals and Fibers", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of liquid crystalline (LC) phases in dispersions of two-dimensional (2D) materials has enabled the development of macroscopically aligned three-dimensional (3D) macrostructures. Here, we report the first experimental observation of self-assembled LC phases in aqueous Ti3C2Tx MXene inks without using LC additives, binders, or stabilizing agents. We show that the transition concentration from the isotropic to nematic phase is influenced by the aspect ratio of MXene flakes. The formation of the nematic LC phase makes it possible to produce fibers from MXenes using a wet-spinning method. By changing the Ti3C2Tx flake size in the ink formulation, coagulation bath, and spinning parameters, we control the morphology of the MXene fibers. The wet-spun Ti3C2Tx fibers show a high electrical conductivity of similar to 7750 S cm(-1), surpassing existing nullomaterial-based fibers. A high volumetric capacitance of similar to 1265 F cm(-3) makes Ti3C2Tx fibers promising for fiber-shaped supercapacitor devices. We also show that Ti3C2Tx fibers can be used as heaters. Notably, the nematic LC phase can be achieved in other MXenes (Mo2Ti2C3Tx and Ti2CTx) and in various organic solvents, suggesting the widespread LC behavior of MXene inks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2020, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 254, "End Page": 265, "Article Number": null, "DOI": "10.1021/acscentsci.9b01217", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b01217", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517832800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Solomon, G; Landström, A; Mazzaro, R; Jugovac, M; Moras, P; Cattaruzza, E; Morandi, V; Concina, I; Vomiero, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Solomon, Getachew; Landstrom, Anton; Mazzaro, Raffaello; Jugovac, Matteo; Moras, Paolo; Cattaruzza, Elti; Morandi, Vittorio; Concina, Isabella; Vomiero, Alberto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NiMoO4@Co3O4 Core-Shell nullorods: In Situ Catalyst Reconstruction toward High Efficiency Oxygen Evolution Reaction", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sluggish kinetics of the oxygen evolution reaction (OER) is the bottleneck for the practical exploitation of water splitting. Here, the potential of a core-shell structure of hydrous NiMoO4 microrods conformally covered by Co3O4 nulloparticles via atomic layer depositions is demonstrated. In situ Raman and synchrotron-based photoemission spectroscopy analysis confirms the leaching out of Mo facilitates the catalyst reconstruction, and it is one of the centers of active sites responsible for higher catalytic activity. Post OER characterization indicates that the leaching of Mo from the crystal structure, induces the surface of the catalyst to become porous and rougher, hence facilitating the penetration of the electrolyte. The presence of Co3O4 improves the onset potential of the hydrated catalyst due to its higher conductivity, confirmed by the shift in the Fermi level of the heterostructure. In particular NiMoO4@Co3O4 shows a record low overpotential of 120 mV at a current density of 10 mA cm(-2), sustaining a remarkable performance operating at a constant current density of 10, 50, and 100 mA cm(-2) with negligible decay. Presented outcomes can significantly contribute to the practical use of the water-splitting process, by offering a clear and in-depth understanding of the preparation of a robust and efficient catalyst for water-splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 11, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101324, "DOI": "10.1002/aenm.202101324", "DOI Link": "http://dx.doi.org/10.1002/aenm.202101324", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000673277700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, TC; Chang, KC; Tsai, TM; Chu, TJ; Sze, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Ting-Chang; Chang, Kuan-Chang; Tsai, Tsung-Ming; Chu, Tian-Jian; Sze, Simon M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resistance random access memory", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-volatile memory (NVM) will play a decisive role in the development of the next-generation of electronic products. Therefore, the development of next-generation NVM is urgent as widely applied flash memory is facing its physical limit. Among various next-generation NVMs, Resistive Random Access Memory (RRAM) is a promising candidate for future memory due to its high-efficiency, highspeed and energy-saving characteristics. In recent years, continuous improvement and in-depth investigation in both materials and electrical switching mechanisms have not only lead to a breakthrough in the performance of digital NVM, but also lead to other possible memory functionality. This paper describes new findings and perspectives on various RRAM devices with different laminated structures and materials, and classifies RRAM into four categories according to different resistive switching mechanisms, from which the four elements are (1) anion-type RRAM: redox reaction and migration of oxygen ions, (2) cation-type RRAM: redox reaction and migration of cation ions, (3) carbon-based RRAM: the stretch of C-C bond lengths due to oxygen and hydrogen dual ions, (4) oxide-based electrode: oxygen accumulation in oxide-based electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 438, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 19, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 254, "End Page": 264, "Article Number": null, "DOI": "10.1016/j.mattod.2015.11.009", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.11.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377882400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noel, NK; Habisreutinger, SN; Wenger, B; Klug, MT; Hörantner, MT; Johnston, MB; Nicholas, RJ; Moore, DT; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noel, Nakita K.; Habisreutinger, Severin N.; Wenger, Bernard; Klug, Matthew T.; Horantner, Maximilian T.; Johnston, Michael B.; Nicholas, Robin J.; Moore, David T.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite-based photovoltaics have, in recent years, become poised to revolutionise the solar industry. While there have been many approaches taken to the deposition of this material, one-step spin-coating remains the simplest and most widely used method in research laboratories. Although spin-coating is not recognised as the ideal manufacturing methodology, it represents a starting point from which more scalable deposition methods, such as slot-dye coating or ink-jet printing can be developed. Here, we introduce a new, low-boiling point, low viscosity solvent system that enables rapid, room temperature crystallisation of methylammonium lead triiodide perovskite films, without the use of strongly coordinating aprotic solvents. Through the use of this solvent, we produce dense, pinhole free films with uniform coverage, high specularity, and enhanced optoelectronic properties. We fabricate devices and achieve stabilised power conversion efficiencies of over 18% for films which have been annealed at 100 degrees C, and over 17% for films which have been dried under vacuum and have undergone no thermal processing. This deposition technique allows uniform coating on substrate areas of up to 125 cm(2), showing tremendous promise for the fabrication of large area, high efficiency, solution processed devices, and represents a critical step towards industrial upscaling and large area printing of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2017, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 145, "End Page": 152, "Article Number": null, "DOI": "10.1039/c6ee02373h", "DOI Link": "http://dx.doi.org/10.1039/c6ee02373h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395208000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; He, S; Lu, SF; Veder, JP; Johannessen, B; Thomsen, L; Saunders, M; Becker, T; De Marco, R; Li, QF; Yang, SZ; Jiang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yi; He, Shuai; Lu, Shanfu; Veder, Jean-Pierre; Johannessen, Bernt; Thomsen, Lars; Saunders, Martin; Becker, Thomas; De Marco, Roland; Li, Qingfeng; Yang, Shi-ze; Jiang, San Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron single atom catalysts (Fe SACS) are the best-known nonprecious metal (NPM) catalysts for the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), but their practical application has been constrained by the low Fe SACs loading (<2 wt%). Here, a one-pot pyrolysis method is reported for the synthesis of iron single atoms on graphene (FeSA-G) with a high Fe SAC loading of approximate to 7.7 +/- 1.3 wt%. The as-synthesized FeSA-G shows an onset potential of 0.950 V and a half-wave potential of 0.804 V in acid electrolyte for the ORR, similar to that of Pt/C catalysts but with a much higher stability and higher phosphate anion tolerance. High temperature SiO2 nullopartide-doped phosphoric acid/polybenzimidazole (PA/PBI/SiO2) composite membrane cells utilizing a FeSA-G cathode with Fe SAC loading of 0.3 mg cm(-2) delivers a peak power density of 325 mW cm(-2) at 230 degrees C, better than 313 mW cm(-2) obtained on the cell with a Pt/C cathode at a Pt loading of 1 mg cm(-2). The cell with FeSA-G cathode exhibits superior stability at 230 degrees C, as compared to that with Pt/C cathode. Our results provide a new approach to developing practical NPM catalysts to replace Pt-based catalysts for fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2019, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802066, "DOI": "10.1002/advs.201802066", "DOI Link": "http://dx.doi.org/10.1002/advs.201802066", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468187200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, PF; Yin, P; Zou, YT; Li, M; Zhang, NQ; Tan, D; Zhao, HY; Li, QJ; Yang, RS; Zou, B; Liu, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Pengfei; Yin, Pei; Zou, Yongtao; Li, Mu; Zhang, nullqiu; Tan, Dan; Zhao, Haiyang; Li, Quanjun; Yang, Rusen; Zou, Bo; Liu, Bingbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-fast Piezocatalysts Enabled By Interfacial Interaction of Reduced Graphene Oxide/MoS2 Heterostructures", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The catalytic activity has been investigated in 2D materials, and the unique structural and electronic properties contribute to their success in conventional heterogeneous catalysis. Heterojunction-based piezocatalysis has attracted increasing attention due to the band-structure engineering and the enhanced charge carrier separation by prominent piezoelectric effect. However, the piezocatalytic behavior of van der Waals (vdW) heterostructures is still unknown, and the finite active sites, catalyst poisoning, and poor conductivity are challenges for developing good piezocatalysts. Herein, a reduced graphene oxide (rGO)-MoS2 heterostructure is rationally designed to tackle these challenges. The heterostructure shows a record-high piezocatalytic degradation rate of 1.40 x 10(2) L mol(-1) s(-1), which is 7.86 times higher than MoS2 nullosheets. Piezoresponse force microscope measurements and density functional theory calculation reveal that the coupling between semiconductive and piezoelectric properties in the vdW heterojunction is vital to break the metallic state screening effect at the MoS2 edge for keeping the piezoelectric potential. The dynamic charges generated by MoS2 and the fast charge transfer in rGO activate and maintain catalytically active sites for pollutant degradation with an ultra-fast rate and good stability. The working mechanism opens new avenues for developing efficient catalysts significant to wastewater treatments and other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 35, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202212172", "DOI Link": "http://dx.doi.org/10.1002/adma.202212172", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950746400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Highley, CB; Song, KH; Daly, AC; Burdick, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Highley, Christopher B.; Song, Kwang Hoon; Daly, Andrew C.; Burdick, Jason A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Jammed Microgel Inks for 3D Printing Applications", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3D printing involves the development of inks that exhibit the requisite proper- ties for both printing and the intended application. In bioprinting, these inks are often hydrogels with controlled rheological properties that can be stabilized after deposition. Here, an alternate approach is developed where the ink is composed exclusively of jammed microgels, which are designed to incorporate a range of properties through microgel design (e.g., composition, size) and through the mixing of microgels. The jammed microgel inks are shear-thinning to permit flow and rapidly recover upon deposition, including on surfaces or when deposited in 3D within hydrogel supports, and can be further stabilized with secondary cross-linking. This platform allows the use of microgels engineered from various materials (e.g., thiol-ene cross-linked hyaluronic acid (HA), photo-cross-linked poly(ethylene glycol), thermo-sensitive agarose) and that incorporate cells, where the jamming process and printing do not decrease cell viability. The versatility of this particle-based approach opens up numerous potential biomedical applications through the printing of a more diverse set of inks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2019, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801076, "DOI": "10.1002/advs.201801076", "DOI Link": "http://dx.doi.org/10.1002/advs.201801076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455199400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheng, SZ; Wang, JL; Zhao, B; He, Z; Feng, XF; Shang, QG; Chen, C; Pei, G; Zhou, J; Liu, JW; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheng, Si-Zhe; Wang, Jin-Long; Zhao, Bin; He, Zhen; Feng, Xue-Fei; Shang, Qi-Guo; Chen, Cheng; Pei, Gang; Zhou, Jun; Liu, Jian-Wei; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullowire-based smart windows combining electro- and thermochromics for dynamic regulation of solar radiation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Smart windows offer more efficient sunlight modulation and heat management. Here, the authors propose a co-assembly strategy to produce smart windows that combine electrochromic and thermochromic functions with tunable components and ordered structures for dynamic solar radiation regulation. Smart window is an attractive option for efficient heat management to minimize energy consumption and improve indoor living comfort owing to their optical properties of adjusting sunlight. To effectively improve the sunlight modulation and heat management capability of smart windows, here, we propose a co-assembly strategy to fabricate the electrochromic and thermochromic smart windows with tunable components and ordered structures for the dynamic regulation of solar radiation. Firstly, to enhance both illumination and cooling efficiency in electrochromic windows, the aspect ratio and mixed type of Au nullorods are tuned to selectively absorb the near-infrared wavelength range of 760 to 1360 nm. Furthermore, when assembled with electrochromic W18O49 nullowires in the colored state, the Au nullorods exhibit a synergistic effect, resulting in a 90% reduction of near-infrared light and a corresponding 5 degrees C cooling effect under 1-sun irradiation. Secondly, to extend the fixed response temperature value to a wider range of 30-50 degrees C in thermochromic windows, the doping amount and mixed type of W-VO2 nullowires are carefully regulated. Last but not the least, the ordered assembly structure of the nullowires can greatly reduce the level of haze and enhance visibility in the windows.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3231, "DOI": "10.1038/s41467-023-38353-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38353-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002562700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, X; Zhou, YH; Zhao, X; Chen, GR; Liu, ZX; Wang, ZH; Lu, CY; Hu, ML; Nashalian, A; Shen, S; Xie, KD; Yang, WW; Gong, YJ; Ding, WB; Servati, P; Han, C; Dou, SX; Li, WJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Xiao; Zhou, Yihao; Zhao, Xun; Chen, Guorui; Liu, Zixiao; Wang, Zihan; Lu, Chengyue; Hu, Menglei; Nashalian, Ardo; Shen, Sophia; Xie, Kedi; Yang, Weiwei; Gong, Yongji; Ding, Wenbo; Servati, Peyman; Han, Chao; Dou, Shi Xue; Li, Weijie; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An ultrathin rechargeable solid-state zinc ion fiber battery for electronic textiles", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic textiles (e-textiles), having the capability of interacting with the human body and surroundings, are changing our everyday life in fundamental and meaningful ways. Yet, the expansion of the field of e-textiles is still limited by the lack of stable and biocompatible power sources with aesthetic designs. Here, we report a rechargeable solid-state Zn/MnO2 fiber battery with stable cyclic performance exceeding 500 hours while maintaining 98.0% capacity after more than 1000 charging/recharging cycles. The mechanism of the high electrical and mechanical performance due to the graphene oxide-embedded polyvinyl alcohol hydrogel electrolytes was rationalized by Monte Carlo simulation and finite element analysis. With a collection of key features including thin, light weight, economic, and biocompatible as well as high energy density, the Zn/MnO2 fiber battery could seamlessly be integrated into a multifunctional on-body e-textile, which provides a stable power unit for continuous and simultaneous heart rate, temperature, humidity, and altitude monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 7, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl3742", "DOI": "10.1126/sciadv.abl3742", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl3742", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000724702800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YJ; Mandal, J; Li, WX; Smith-Washington, A; Tsai, CC; Huang, WL; Shrestha, S; Yu, NF; Han, RPS; Cao, A; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yijun; Mandal, Jyotirmoy; Li, Wenxi; Smith-Washington, Ajani; Tsai, Cheng-Chia; Huang, Wenlong; Shrestha, Sajan; Yu, nullfang; Han, Ray P. S.; Cao, Anyuan; Yang, Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colored and paintable bilayer coatings with high solar-infrared reflectance for efficient cooling", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar reflective and thermally emissive surfaces offer a sustainable way to cool objects under sunlight. However, white or silvery reflectance of these surfaces does not satisfy the need for color. Here, we present a paintable bilayer coating that simultaneously achieves color and radiative cooling. The bilayer comprises a thin, visibleabsorptive layer atop a nonabsorptive, solar-scattering underlayer. The top layer absorbs appropriate visible wavelengths to show specific colors, while the underlayer maximizes the reflection of near-to-short wavelength infrared (NSWIR) light to reduce solar heating. Consequently, the bilayer attains higher NSWIR reflectance (by 0.1 to 0.51) compared with commercial paint monolayers of the same color and stays cooler by as much as 3.0 degrees to 15.6 degrees C under strong sunlight. High NSWIR reflectance of 0.89 is realized in the blue bilayer. The performances show that the bilayer paint design can achieve both color and efficient radiative cooling in a simple, inexpensive, and scalable manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz5413", "DOI": "10.1126/sciadv.aaz5413", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz5413", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530628100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boriachek, K; Masud, MK; Palma, C; Phan, HP; Yamauchi, Y; Hossain, MSA; Nguyen, NT; Salomon, C; Shiddiky, MJA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boriachek, Kseniia; Masud, Mostafa Kamal; Palma, Carlos; Hoang-Phuong Phan; Yamauchi, Yusuke; Hossain, Md. Shahriar A.; Nam-Trung Nguyen; Salomon, Carlos; Shiddiky, Muhammad J. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Avoiding Pre-Isolation Step in Exosome Analysis: Direct Isolation and Sensitive Detection of Exosomes Using Gold-Loaded nulloporous Ferric Oxide nullozymes", "Source Title": "ANALYTICAL CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most of the current exosome-analysis strategies are time-consuming and largely dependent on commercial extraction kit based preisolation step, which requires extensive sample manipulations, costly isolation kits, reagents, tedious procedures, and sophisticated equipment and is prone to bias/artifacts. Herein we introduce a simple method for direct isolation and subsequent detection of a specific population of exosomes using an engineered superparamagnetic material with multifunctional properties, namely, gold-loaded ferric oxide nullocubes (Au-NPFe2O3NC). In this method, the Au-NPFe2O3NC were initially functionalized with a generic tetraspanin (exosomes-associated) antibody (i.e., CD63) and dispersed in sample fluids where they work as dispersible nullocarriers to capture the bulk population of exosomes. After magnetic collection and purification, Au-NPFe2O3NC-bound exosomes were transferred to the tissue-specific, antibody-modified, screen-printed electrode. As a proof of principle, we used a specific placental marker, placenta alkaline phosphatase (PLAP), to detect exosomes secreted from placental cells. The peroxidase-like activity of Au-NPFe2O3NC was then used to accomplish an enzyme-linked immunosorbent assay (ELISA)based sensing protocol for naked-eye observation along with UV-visible and electrochemical detection of PLAP-specific exosomes present in placental cell-conditioned media. We demonstrated excellent agreement in analytical performance for the detection of placental cell-derived exosomes (i.e., linear dynamic range, 10(3)-10(7) exosomes/mL; limit of detection, 10(3) exosomes/mL; relative standard deviation (%RSD) of <5.5% for n = 3) using with and without commercial total exosome isolation kit-based preisolation step. We envisage that this highly sensitive, rapid, and inexpensive assay could be useful in quantifying specific populations of exosomes for various clinical applications, focusing on pregnullcy complications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2019, "Volume": 91, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3827, "End Page": 3834, "Article Number": null, "DOI": "10.1021/acs.analchem.8b03619", "DOI Link": "http://dx.doi.org/10.1021/acs.analchem.8b03619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462098300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, B; Chandrasekaran, S; Zhang, J; Xiao, W; Qian, F; Zhu, C; Duoss, EB; Spadaccini, CM; Worsley, MA; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Bin; Chandrasekaran, Swetha; Zhang, Jing; Xiao, Wang; Qian, Fang; Zhu, Cheng; Duoss, Eric B.; Spadaccini, Christopher M.; Worsley, Marcus A.; Li, Yat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient 3D Printed Pseudocapacitive Electrodes with Ultrahigh MnO2 Loading", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Retaining sound electrochemical performance of electrodes at high mass loading holds significant importance to energy storage. Pseudocapacitive materials such as manganese oxide (MnO2) deposited on current collectors have achieved outstanding gravimetric capacitances, sometimes even close to their theoretical values. Yet, this is only achievable with very small mass loading of active material typically less than 1 mg cm(-2). Increasing mass loading often leads to drastic decay of capacitive performance due to sluggish ion diffusion in bulk material. Here, we demonstrate a 3D printed graphene aerogel electrode with MnO2 loading of 182.2 mg cm(-2), which achieves a record-high areal capacitance of 44.13 F cm(-2). Most importantly, this 3D printed graphene aerogel/MnO2 electrode can simultaneously achieve excellent capacitance normalized to area, gravimetry, and volume, which is the trade-off for most electrodes. This work successfully validates the feasibility of printing practical pseudocapacitive electrodes, which might revolutionize pseudocapacitor fabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 459, "End Page": 470, "Article Number": null, "DOI": "10.1016/j.joule.2018.09.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.09.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460076100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Helmy, S; Leibfarth, FA; Oh, S; Poelma, JE; Hawker, CJ; de Alaniz, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Helmy, Sameh; Leibfarth, Frank A.; Oh, Saemi; Poelma, Justin E.; Hawker, Craig J.; de Alaniz, Javier Read", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoswitching Using Visible Light: A New Class of Organic Photochromic Molecules", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A versatile new class of organic photochromic molecules that offers an unprecedented combination of physical properties including tunable photoswitching using visible light, excellent fatigue resistance, and large polarity changes is described. These unique features offer significant opportunities in diverse fields ranging from biosensors to targeted delivery systems while also allowing non-experts ready synthetic access to these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2014, "Volume": 136, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8169, "End Page": 8172, "Article Number": null, "DOI": "10.1021/ja503016b", "DOI Link": "http://dx.doi.org/10.1021/ja503016b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337336800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WZ; Liu, YJ; Yang, ZQ; Xu, CQ; Li, XD; Huang, SL; Shi, JH; Du, JL; Han, AJ; Yang, YH; Xu, GN; Yu, J; Ling, JJ; Peng, J; Yu, LP; Ding, B; Gao, Y; Jiang, K; Li, ZF; Yang, YC; Li, ZJ; Lan, SH; Fu, HX; Fan, B; Fu, YY; He, W; Li, FR; Song, X; Zhou, YN; Shi, Q; Wang, GY; Guo, L; Kang, JX; Yang, XB; Li, DD; Wang, ZC; Li, J; Thoroddsen, S; Cai, R; Wei, FH; Xing, GQ; Xie, Y; Liu, XC; Zhang, LP; Meng, FY; Di, ZF; Liu, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wenzhu; Liu, Yujing; Yang, Ziqiang; Xu, Changqing; Li, Xiaodong; Huang, Shenglei; Shi, Jianhua; Du, Junling; Han, Anjun; Yang, Yuhao; Xu, Guoning; Yu, Jian; Ling, Jiajia; Peng, Jun; Yu, Liping; Ding, Bin; Gao, Yuan; Jiang, Kai; Li, Zhenfei; Yang, Yanchu; Li, Zhaojie; Lan, Shihu; Fu, Haoxin; Fan, Bin; Fu, Yanyan; He, Wei; Li, Fengrong; Song, Xin; Zhou, Yinuo; Shi, Qiang; Wang, Guangyuan; Guo, Lan; Kang, Jingxuan; Yang, Xinbo; Li, Dongdong; Wang, Zhechao; Li, Jie; Thoroddsen, Sigurdur; Cai, Rong; Wei, Fuhai; Xing, Guoqiang; Xie, Yi; Liu, Xiaochun; Zhang, Liping; Meng, Fanying; Di, Zengfeng; Liu, Zhengxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible solar cells based on foldable silicon wafers with blunted edges", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible solar cells have a lot of market potential for application in photovoltaics integrated into buildings and wearable electronics because they are lightweight, shockproof and self-powered. Silicon solar cells have been successfully used in large power plants. However, despite the efforts made for more than 50 years, there has been no notable progress in the development of flexible silicon solar cells because of their rigidity1-4. Here we provide a strategy for fabricating large-scale, foldable silicon wafers and manufacturing flexible solar cells. A textured crystalline silicon wafer always starts to crack at the sharp channels between surface pyramids in the marginal region of the wafer. This fact enabled us to improve the flexibility of silicon wafers by blunting the pyramidal structure in the marginal regions. This edge-blunting technique enables commercial production of large-scale (>240 cm(2)), high-effliciency (>24%) silicon solar cells that can be rolled similarly to a sheet of paper. The cells retain 100% of their power conversion efficiency after 1,000 side-to-side bending cycles. After being assembled into large (>10,000 cm(2)) flexible modules, these cells retain 99.62% of their power after thermal cycling between -70 degrees C and 85 degrees C for 120 h. Furthermore, they retain 96.03% of their power after 20 min of exposure to air flow when attached to a soft gasbag, which models wind blowing during a violent storm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2023, "Volume": 617, "Issue": 7962, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 717, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05921-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05921-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000995020000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Guo, CX; Fang, SS; Zhao, XT; Li, L; Jiang, HY; Liu, ZY; Fan, ZQ; Xu, WG; Xiao, JP; Zhong, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jin; Guo, Chenxi; Fang, Susu; Zhao, Xiaotong; Li, Le; Jiang, Haoyang; Liu, Zhaoyang; Fan, Ziqi; Xu, Weigao; Xiao, Jianping; Zhong, Miao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating electrochemical CO2 reduction to multi-carbon products via asymmetric intermediate binding at confined nullointerfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 electroreduction to multi-carbon products in acids remains challenging due to the low efficiency and poor stability of C-C coupling. Here, the authors show that asymmetric CO binding at confined nullointerfaces enhances multi-carbon production, improves CO2 utilization, and limits H-2 evolution. Electrochemical CO2 reduction (CO2R) to ethylene and ethanol enables the long-term storage of renewable electricity in valuable multi-carbon (C2+) chemicals. However, carbon-carbon (C-C) coupling, the rate-determining step in CO2R to C2+ conversion, has low efficiency and poor stability, especially in acid conditions. Here we find that, through alloying strategies, neighbouring binary sites enable asymmetric CO binding energies to promote CO2-to-C2+ electroreduction beyond the scaling-relation-determined activity limits on single-metal surfaces. We fabricate experimentally a series of Zn incorporated Cu catalysts that show increased asymmetric CO* binding and surface CO* coverage for fast C-C coupling and the consequent hydrogenation under electrochemical reduction conditions. Further optimization of the reaction environment at nullointerfaces suppresses hydrogen evolution and improves CO2 utilization under acidic conditions. We achieve, as a result, a high 31 +/- 2% single-pass CO2-to-C2+ yield in a mild-acid pH 4 electrolyte with >80% single-pass CO2 utilization efficiency. In a single CO2R flow cell electrolyzer, we realize a combined performance of 91 +/- 2% C2+ Faradaic efficiency with notable 73 +/- 2% ethylene Faradaic efficiency, 31 +/- 2% full-cell C2+ energy efficiency, and 24 +/- 1% single-pass CO2 conversion at a commercially relevant current density of 150 mA cm(-2) over 150 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1298, "DOI": "10.1038/s41467-023-36926-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36926-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001683700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Matras-Postolek, K; Yang, P; Jiang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao; Matras-Postolek, Katarzyna; Yang, Ping; Jiang, San Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Z-scheme WOx/Cu-g-C3N4 heterojunction nulloarchitectonics with promoted charge separation and transfer towards efficient full solar- spectrum photocatalysis", "Source Title": "JOURNAL OF COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of Z-scheme heterojunctions has been considered one superb method in promoting solar-assisted charge carrier separation of carbon-based materials to achieve efficient utilization of solar energy in hydrogen production and CO2 reduction. One interesting concept in nullofabrication that has become trend recent years is nulloarchitectonics. A heterostructure photocatalyst constructed based on the idea of nulloarchitectonics using the combination of g-C3N4, metal and an additional semiconducting nullocomposite is investigated in this paper. Z-scheme tungsten oxide incorporated copper modified gra-phitic carbon nitride (WOx/Cu-g-C3N4) heterostructures are fabricated via immobilization of WOxon Cu nulloparticles modified superior thin g-C3N4 nullosheets. Mechano-chemical pre-reaction and a two-step high-temperature thermal polymerization process are the keys in attaining homogeneous distribution of Cu nulloparticles in g-C3N4 nullosheets. The horizontal growth of homogeneously distributed WOx nullo-belts on Cu modified g-C3N4 (Cu-g-C3N4) base via solvothermal synthesis is achieved. The photocatalytic performances of the heterostructures are evaluated through water splitting and CO2 photoreduction measurements in full solar spectrum irradiation condition. The presence of Cu nulloparticles in the com-posite system improves charge transport between g-C3N4 and WOx and thus enhances the photocatalytic performances (H2 generation and CO2 photoreduction) of the composite material, while the presence of WOx nullocomposites enhances light absorption of the composite material in the near infrared range. The synthesized heterostructure with optimized WOx to Cu-g-C3N4 ratio and in case of no co-catalyst addition exhibits enhanced photocatalytic H2 evolution (4560 lmolg-1h-1) as well as excellent CO2 reduction rate (5.89 lmolg-1h-1 for CO generation).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 636, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 646, "End Page": 656, "Article Number": null, "DOI": "10.1016/j.jcis.2023.01.052", "DOI Link": "http://dx.doi.org/10.1016/j.jcis.2023.01.052", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964807000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, SG; Gong, PF; Bai, L; Xu, X; Zhang, SQ; Sun, ZH; Lin, ZS; Hong, MC; Chen, CT; Luo, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Sangen; Gong, Pifu; Bai, Lei; Xu, Xiang; Zhang, Shuquan; Sun, Zhihua; Lin, Zheshuai; Hong, Maochun; Chen, Chuangtian; Luo, Junhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonlinear optical (NLO) materials are of great importance in laser science and technology, as they can expand the wavelength range provided by common laser sources. Few NLO materials, except KBe2BO3F2 (KBBF), can practically generate deep-ultraviolet coherent light by direct second-harmonic generation process, limited by the fundamental requirements on the structure-directing optical properties. However, KBBF suffers a strong layering tendency and high toxicity of the containing beryllium, which hinder the commercial availability of KBBF. Here we report a new beryllium-free borate, Li4Sr(BO3)(2), which preserves the structural merits of KBBF, resulting in the desirable optical properties. Furthermore, Li4Sr(BO3)(2) mitigates the layering tendency greatly and enhances the efficiency of second-harmonic generation by more than half that of KBBF. These results suggest that Li4Sr(BO3)(2) is an attractive candidate for the next generation of deep-ultraviolet NLO materials. This beryllium-free borate represents a new research direction in the development of deep-ultraviolet NLO materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4019, "DOI": "10.1038/ncomms5019", "DOI Link": "http://dx.doi.org/10.1038/ncomms5019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337542900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JF; Chen, J; Xiong, XM; Peng, XD; Chen, DL; Pan, FS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Jiangfeng; Chen, Jing; Xiong, Xiaoming; Peng, Xiaodong; Chen, Daolun; Pan, Fusheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research advances of magnesium and magnesium alloys worldwide in 2021", "Source Title": "JOURNAL OF MAGNESIUM AND ALLOYS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "More than 4000 papers in the field of Mg and Mg alloys were published and indexed in Web of Science (WoS) Core Collection database in 2021. The bibliometric analyses indicate that the microstructure, mechanical properties, and corrosion of Mg alloys still are the main research focus. Mg ion batteries and hydrogen storage Mg materials have attracted much attention. Significant contributions to the research and development of magnesium alloys were made by Chongqing University, Shanghai Jiaotong University, and Chinese Academy of Sciences in China, Helmholtz Zentrum Hereon in Germany, Ohio State University in the United States, the University of Queensland in Australia, Kumanto University in Japan, and Seoul National University in Korea, University of Tehran in Iran, etc.. This review is aimed to summarize the progress in the development of structural and functional Mg and Mg alloys in 2021. Based on the issues and challenges identified here, some future research directions are suggested. (C) 2022 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 863, "End Page": 898, "Article Number": null, "DOI": "10.1016/j.jma.2022.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.jma.2022.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799350100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XB; Xiong, J; Xu, Y; Feng, ZJ; Huang, JT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xibao; Xiong, Jie; Xu, Ying; Feng, Zhijun; Huang, Juntong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-assisted surface modification enhances the visible light photocatalytic performance of g-C3N4@C-TiO2 direct Z-scheme heterojunctions", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To increase the number of active sites and defects in TiO2 and promote rapid and efficient transfer of photogenerated charges, a g-C3N4@C-TiO2 composite photocatalyst was prepared via in situ deposition of g-C3N4 on a carbon-doped anatase TiO2 surface. The effects of carbon doping state and surface modification of g-C3N4 on the performance of g-C3N4@C-TiO(2)composite photocatalysts were studied by X-ray diffraction, X-ray photoelectron spectroscopy, UV-visible diffuse-reflectance spectroscopy, transmission electron microscopy, electrochemical impedance spectroscopy, photoluminescence, and electron paramagnetic resonullce. With increasing carbon doping content, the carbon doping state in TiO2 gradually changed from gap to substitution doping. Although the number of oxygen vacancies gradually increased, the degradation efficiency of g-C3N4@C-TiO2 for RhB (phenol) initially increased and subsequently decreased with increasing carbon content. The g-C3Na4@10C-TiO2 sample exhibited the highest apparent reaction rate constant of 0.036 min(-1) (0.039 min(-)1) for RhB (phenol) degradation, which was 150 (139), 6.4 (6.8), 2.3 (3), and 1.7 (2.1) times higher than that of pure TiO2, 10C-TiO2, g-C3N4, and g-C3N4@TiO2, respectively. g-C3N4 was grown in situ on the surface of C-TiO2 by surface carbon hybridization and bonding. The resultant novel g-C3N4@C-TiO2 photocatalyst exhibited direct Z-scheme heterojunctions with non-local impurity levels. The high photocatalytic activity can be attributed to the synergistic effects of the improved visible light response ability, higher photogenerated electron transfer efficiency, and redox ability arising from Z-type heterojunctions. 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 40, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 424, "End Page": 433, "Article Number": null, "DOI": "10.1016/S1872-2067(18)63183-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(18)63183-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466263200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motta, C; El-Mellouhi, F; Kais, S; Tabet, N; Alharbi, F; Sanvito, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motta, Carlo; El-Mellouhi, Fedwa; Kais, Sabre; Tabet, Nouar; Alharbi, Fahhad; Sanvito, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the role of organic cations in hybrid halide perovskite CH3NH3PbI3", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hybrid halide perovskite CH3NH3PbI3 has enabled solar cells to reach an efficiency of about 20%, demonstrating a pace for improvements with no precedents in the solar energy arena. Despite such explosive progress, the microscopic origin behind the success of such material is still debated, with the role played by the organic cations in the light-harvesting process remaining unclear. Here van der Waals-corrected density functional theory calculations reveal that the orientation of the organic molecules plays a fundamental role in determining the material electronic properties. For instance, if CH3NH3 orients along a (011)-like direction, the PbI6 octahedral cage will distort and the bandgap will become indirect. Our results suggest that molecular rotations, with the consequent dynamical change of the band structure, might be at the origin of the slow carrier recombination and the superior conversion efficiency of CH3NH3PbI3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 578, "Times Cited, All Databases": 630, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7026, "DOI": "10.1038/ncomms8026", "DOI Link": "http://dx.doi.org/10.1038/ncomms8026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353707100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Yaji, K; Hashimoto, T; Ota, Y; Kondo, T; Okazaki, K; Wang, ZJ; Wen, JS; Gu, GD; Ding, H; Shin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Yaji, Koichiro; Hashimoto, Takahiro; Ota, Yuichi; Kondo, Takeshi; Okazaki, Kozo; Wang, Zhijun; Wen, Jinsheng; Gu, G. D.; Ding, Hong; Shin, Shik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of topological superconductivity on the surface of an iron-based superconductor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological superconductors are predicted to host exotic Majorana states that obey non-Abelian statistics and can be used to implement a topological quantum computer. Most of the proposed topological superconductors are realized in difficult-to-fabricate heterostructures at very low temperatures. By using high-resolution spin-resolved and angle-resolved photoelectron spectroscopy, we find that the iron-based superconductor FeTe1-xSex (x = 0.45; superconducting transition temperature T-c = 14.5 kelvin) hosts Dirac-cone-type spin-helical surface states at the Fermi level; the surface states exhibit an s-wave superconducting gap below T-c. Our study shows that the surface states of FeTe0.55Se0.45 are topologically superconducting, providing a simple and possibly high-temperature platform for realizing Majorana states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 552, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2018, "Volume": 360, "Issue": 6385, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 182, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aan4596", "DOI Link": "http://dx.doi.org/10.1126/science.aan4596", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429805400041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ju, L; Shang, J; Tang, X; Kou, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ju, Lin; Shang, Jing; Tang, Xiao; Kou, Liangzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Photocatalytic Water Splitting by the Ferroelectric Switch in a 2D AgBiP2Se6 Monolayer", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic water splitting is a promising technology to solve the energy crisis and provide renewable and clean energies. Recently, although numerous 2D materials have been proposed as the photocatalytic candidates, the strategies to effectively modulate photocatalytic reactions and conversion efficiency are still lacking. Herein, based on first-principles calculations, we show that the photocatalytic activities and energy conversion efficiency can be well tuned by ferroelectric-paraelectric phase transition of a AgBiP2Se6 monolayer. It is found that the AgBiP2Se6 monolayer has a higher potential and driving forces of photogenerated holes for water oxidation in the ferroelectric phase, but higher corresponding values of photogenerated electrons for the hydrogen reduction reaction in the paraelectric phase. Besides, the solar-to-hydrogen energy conversion efficiency is also tunable with the phase transition; it is up to 10.04% at the ferroelectric phase due to the better carrier utilization, but only 6.66% at the paraelectric phase. Moreover, the exciton binding energy is always smaller in the paraelectric state than that in the ferroelectric state, indicating that the ferroelectric switch could also make a directional adjustment to the photoexcited carrier separation. Our theoretical investigation not only reveals the importance of ferroelectric polarization on water splitting, but also opens an avenue to modify the photocatalytic properties of 2D ferroelectric materials via a ferroelectric switch.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2020, "Volume": 142, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1492, "End Page": 1500, "Article Number": null, "DOI": "10.1021/jacs.9b11614", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b11614", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509425600047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alqurashi, H; Khurshid, Z; Syed, AU; Habib, SR; Rokaya, D; Zafar, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alqurashi, Hatim; Khurshid, Zohaib; Syed, Azeem Ul Yaqin; Habib, Syed Rashid; Rokaya, Dinesh; Zafar, Muhammad Sohail", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyetherketoneketone (PEKK): An emerging biomaterial for oral implants and dental prostheses", "Source Title": "JOURNAL OF ADVANCED RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: The polyetherketoneketone (PEKK) and polyetheretherketone (PEEK) are the two most well-known of the polyaryletherketone (PAEK) family. PEKK is a new evolving polymeric material. PEKK bio-materials is an elastic material with good shock absorbance and fracture resistance and present ultrahigh performance among all thermoplastic composites for excellent mechanical strength, chemical resistance, and high thermal stability. Aims of Review: The aim of this review is to present a comprehensive overview of PEKK and its various applications in restorative, prosthetic, and implant dentistry highlighting its prospects for clinical applications. Key Scientific Concepts of Review: Available articles on PEKK for dental applications were reviewed from January 1957 to August 2020) using MEDLINE/PubMed, Web of Science, and ScienceDirect resources. PEKK presents suitable physical, mechanical, and chemical properties for applications in prosthodontics and oral implantology. PEKK has good potential for a wide range of dental applications, including tooth restorations, crowns, bridge, endoposts, denture framework, implant-supported fixed prosthesis, and dental implants. PEKK dental implants have shown lesser stress shielding compared to titanium for dental implant applications. Further modifications and improving material properties can result in broader applications in the field of dentistry. Long term evaluations are needed as PEKK is recently applied in dentistry, and there are limited studies published on PEKK. (C) 2021 The Authors. Published by Elsevier B.V. on behalf of Cairo University.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 28, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 87, "End Page": 95, "Article Number": null, "DOI": "10.1016/j.jare.2020.09.004", "DOI Link": "http://dx.doi.org/10.1016/j.jare.2020.09.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648694400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, WH; Bai, T; Wang, L; Cheng, Y; Xia, DD; Yu, S; Zheng, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Wenhao; Bai, Tian; Wang, Lan; Cheng, Yan; Xia, Dandan; Yu, Sen; Zheng, Yufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic AgNPs@antimicrobial peptide/silk fibroin coating for infection-trigger antibacterial capability and enhanced osseointegration", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Endowing implant surfaces with combined antibacterial and osteogenic properties by drug-loaded coatings has made great strides, but how to achieve the combined excellence of infection-triggered bactericidal and in vivo-proven osteogenic activities without causing bacterial resistance still remains a formidable challenge. Herein, antimicrobial peptides (AMPs) with osteogenic fragments were designed and complexed on the surface of silver nulloparticle (AgNP) through hydrogen bonding, and the collagen structure-bionic silk fibroin (SF) was applied to carry AgNPs@ AMPs to achieve infection-triggered antibacterial and osteointegration. As verified by TEM, AMPs contributed to the dispersion and size-regulation of AgNPs, with a particle size of about 20 nm, and a clear protein corona structure was observed on the particle surface. The release curve of silver ion displayed that the SF-based coating owned sensitive pH-responsive properties. In the antibacterial test against S.aureus for up to 21 days, the antibacterial rate had always remained above 99%. Meanwhile, the underlying mechanism was revealed, originating from the destruction of the bacterial cell membranes and ROS generation. The SF-based coating was conducive to the adhesion, diffusion, and proliferation of bone marrow stem cells (BMSCs) on the surface, and promoted the expression of osteogenic genes and collagen secretion. The in vivo implantation results showed that compared with the untreated Ti implants, SF-based coating enhanced osseointegration at week 4 and 8. Overall, the AgNPs@AMPs-loaded SF-based coating presented the ability to synergistically inhibit bacteria and promote osseointegration, possessing tremendous potential application prospects in bone defects and related-infection treatments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 64, "End Page": 80, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.05.015", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.05.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808232900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, ZW; Yuan, CX; Liu, YF; Wang, XJ; Sun, P; Wang, L; Jiang, HC; Jiang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Zhenwei; Yuan, Chenxu; Liu, Yongfu; Wang, Xiao-Jun; Sun, Peng; Wang, Lei; Jiang, Haochuan; Jiang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optics: Visibly powerful near-infrared light-emitting diodes A near-infrared light-emitting (NIR-LED) diode that emits high-power light could pave the way for the development of next-generation monitoring and detecting devices. Although solid-state NIR-LEDs are used in such devices, their narrow emission band limits their range of applications. Broadband NIR-emitting phosphor-converted LEDs offer the best solution. However, creating NIR phosphors that are sufficiently excited by blue light is challenging. Now, a team of Chinese and American researchers, led by Yongfu Liu from the Chinese Academy of Sciences, has created a NIR-LED that emits light in the 700-900 nm with an output of 109.9 mW at 520 mA after excitation with blue light. The device has the highest recorded power rating to date and could be used in applications from bioimaging and night-vision technologies, to monitoring food and medicines. Broadband near-infrared (NIR)-emitting phosphors are key for next-generation smart NIR light sources based on blue LEDs. To achieve excellent NIR phosphors, we propose a strategy of enhancing the crystallinity, modifying the micromorphology, and maintaining the valence state of Cr3+ in Ca3Sc2Si3O12 garnet (CSSG). By adding fluxes and sintering in a reducing atmosphere, the internal quantum efficiency (IQE) is greatly enhanced to 92.3%. The optimized CSSG:6%Cr3+ exhibits excellent thermal stability. At 150 degrees C, 97.4% of the NIR emission at room temperature can be maintained. The fabricated NIR-LED device emits a high optical power of 109.9 mW at 520 mA. The performances of both the achieved phosphor and the NIR-LED are almost the best results until now. The mechanism for the optimization is investigated. An application of the NIR-LED light source is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 587, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86, "DOI": "10.1038/s41377-020-0326-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0326-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533075300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, YG; Camp, J; Haranczyk, M; Sikora, BJ; Bury, W; Krungleviciute, V; Yildirim, T; Farha, OK; Sholl, DS; Snurr, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Yongchul G.; Camp, Jeffrey; Haranczyk, Maciej; Sikora, Benjamin J.; Bury, Wojciech; Krungleviciute, Vaiva; Yildirim, Taner; Farha, Omar K.; Sholl, David S.; Snurr, Randall Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computation-Ready, Experimental Metal-Organic Frameworks: A Tool To Enable High-Throughput Screening of nulloporous Crystals", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Experimentally refined crystal structures for metalorganic frameworks (MOFs) often include solvent molecules and partially occupied or disordered atoms. This creates a major impediment to applying high-throughput computational screening to MOFs. To address this problem, we have constructed a database of MOF structures that are derived from experimental data but are immediately suitable for molecular simulations. The computation-ready, experimental (CoRE) MOF database contains over 4700 porous structures with publically available atomic coordinates. Important physical and chemical properties including the surface area and pore dimensions are reported for these structures. To demonstrate the utility of the database, we performed grand canonical Monte Carlo simulations of methane adsorption on all structures in the CoRE MOF database. We investigated the structural properties of the CoRE MOFs that govern methane storage capacity and found that these relationships agree well with those derived recently from a large database of hypothetical MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 608, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2014, "Volume": 26, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6185, "End Page": 6192, "Article Number": null, "DOI": "10.1021/cm502594j", "DOI Link": "http://dx.doi.org/10.1021/cm502594j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344905600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XJ; Vieru, V; Feng, XW; Liu, JL; Zhang, ZJ; Na, B; Shi, W; Wang, BW; Powell, AK; Chibotaru, LF; Gao, S; Cheng, P; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xuejing; Vieru, Veacheslav; Feng, Xiaowen; Liu, Jun-Liang; Zhang, Zhenjie; Na, Bo; Shi, Wei; Wang, Bing-Wu; Powell, Annie K.; Chibotaru, Liviu F.; Gao, Song; Cheng, Peng; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of Guest Exchange on the Magnetization Dynamics of Dilanthanide Single-Molecule-Magnet Nodes within a Metal-Organic Framework", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multitopic organic linkers can provide a means to organize metal cluster nodes in a regular three-dimensional array. Herein, we show that isonicotinic acid N-oxide (HINO) serves as the linker in the formation of a metal-organic framework featuring Dy-2 single-molecule magnets as nodes. Importantly, guest solvent exchange induces a reversible single-crystal to single-crystal transformation between the phases Dy-2(INO)(4)(NO3)(2)center dot 2 solvent (solvent=DMF (Dy-2-DMF), CH3CN (Dy-2-CH3CN)), thereby switching the effective magnetic relaxation barrier (determined by ac magnetic susceptibility measurements) between a negligible value for Dy-2-DMF and 76 cm(-1) for Dy-2-CH3CN. Ab initio calculations indicate that this difference arises not from a significant change in the intrinsic relaxation barrier of the Dy-2 nodes, but rather from a slowing of the relaxation rate of incoherent quantum tunneling of the magnetization by two orders of magnitude.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2015, "Volume": 54, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9861, "End Page": 9865, "Article Number": null, "DOI": "10.1002/anie.201503636", "DOI Link": "http://dx.doi.org/10.1002/anie.201503636", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360215100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TY; Zhou, ZP; Guo, YC; Guo, D; Liu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tianyu; Zhou, Zhengping; Guo, Yichen; Guo, Dong; Liu, Guoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Block copolymer derived uniform mesopores enable ultrafast electron and ion transport at high mass loadings", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. On conventional carbon supports, high mass loadings inevitably lead to sluggish electron conduction and ion diffusion due to thick pseudocapacitive layers and clogged pores. Here we present a design principle of carbon supports, utilizing self-assembly and microphase-separation of block copolymers. We synthesize porous carbon fibers (PCFs) with uniform mesopores of 11.7 nm, which are partially filled with MnO2 of <2 nm in thickness. The uniform mesopores and ultrathin MnO2 enable fast electron/ion transport comparable to electrical-double-layer-capacitive carbons. At mass loadings approaching 7mg cm(-2), the gravimetric and areal capacitances of MnO2 (similar to 50% of total mass) reach 1148 F g(-1) and 3141 mF cm(-2), respectively. Our MnO2-coated PCFs outperform other MnO2-based electrodes at similar loadings, highlighting the great promise of block copolymers for designing PCF supports for electrochemical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 675, "DOI": "10.1038/s41467-019-08644-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08644-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458175700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XN; Zhao, LM; Li, XJ; Liu, Y; Wang, YS; Yao, QF; Xie, JP; Xue, QZ; Yan, ZF; Yuan, X; Xing, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoning; Zhao, Lianming; Li, Xuejin; Liu, Yong; Wang, Yesheng; Yao, Qiaofeng; Xie, Jianping; Xue, Qingzhong; Yan, Zifeng; Yuan, Xun; Xing, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-precision Pt6 nulloclusters for enhanced hydrogen electro-oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discord between the insufficient abundance and the excellent electrocatalytic activity of Pt urgently requires its atomic-level engineering for minimal Pt dosage yet maximized electrocatalytic performance. Here we report the design of ultrasmall triphenylphosphine-stabilized Pt-6 nulloclusters for electrocatalytic hydrogen oxidation reaction in alkaline solution. Benefiting from the self-optimized ligand effect and atomic-precision structure, the nullocluster electrocatalyst demonstrates a high mass activity, a high stability, and outperforms both Pt single atoms and Pt nulloparticle analogues, uncovering an unexpected size optimization principle for designing Pt electrocatalysts. Moreover, the nullocluster electrocatalyst delivers a high CO-tolerant ability that conventional Pt/C catalyst lacks. Theoretical calculations confirm that the enhanced electrocatalytic performance is attributable to the bifold effects of the triphenylphosphine ligand, which can not only tune the formation of atomically precise platinum nulloclusters, but also shift the d-band center of Pt atoms for favorable adsorption kinetics of *H, *OH, and CO. While Pt is an active fuel cell catalyst, it's low abundance and high cost spurs research into boosting performances from lesser Pt amounts. Here, authors design atomically precise triphenylphosphine-stabilized Pt nulloclusters with high activities and durabilities for electrocatalytic H-2 oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1596, "DOI": "10.1038/s41467-022-29276-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29276-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773001900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Malgras, V; Tominaka, S; Ryan, JW; Henzie, J; Takei, T; Ohara, K; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Malgras, Victor; Tominaka, Satoshi; Ryan, James W.; Henzie, Joel; Takei, Toshiaki; Ohara, Koji; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Quantum Confinement in Monodisperse Methylammonium Lead Halide Perovskite nullocrystals Embedded in Mesoporous Silica", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic metal halide perovskites have fascinating electronic properties and have already been implemented in various devices. Although the behavior of bulk metal halide perovskites has been widely studied, the properties of perovskite nullocrystals are less well-understood because synthesizing them is still very challenging, in part because of stability. Here we demonstrate a simple and versatile method to grow monodisperse CH3NH3PbBrxIx-3 perovskite nullocrystals inside mesoporous silica templates. The size of the nullocrystal is governed by the pore size of the templates (3.3, 3.7, 4.2, 6.2, and 7.1 nm). In-depth structural analysis shows that the nullocrystals maintain the perovskite crystal structure, but it is slightly distorted. Quantum confinement was observed by tuning the size of the particles via the template. This approach provides an additional route to tune the optical bandgap of the nullocrystal. The level of quantum confinement was modeled taking into account the dimensions of the rod-shaped nullocrystals and their close packing inside the channels of the template. Photoluminescence measurements on CH3NH3PbBr clearly show a shift from green to blue as the pore size is decreased. Synthesizing perovskite nullostructures in templates improves their stability and enables tunable electronic properties via quantum confinement. These structures may be useful as reference materials for comparison with other perovskites, or as functional materials in all solid-state light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2016, "Volume": 138, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13874, "End Page": 13881, "Article Number": null, "DOI": "10.1021/jacs.6b05608", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b05608", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386540500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, KC; Pazos, S; Aguirre, F; Shen, YQ; Yuan, Y; Zheng, WW; Alharbi, O; Villena, MA; Fang, B; Li, XY; Milozzi, A; Farronato, M; Muñoz-Rojo, M; Wang, T; Li, R; Fariborzi, H; Roldan, JB; Benstetter, G; Zhang, XX; Alshareef, HN; Grasser, T; Wu, HQ; Ielmini, D; Lanza, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Kaichen; Pazos, Sebastian; Aguirre, Fernulldo; Shen, Yaqing; Yuan, Yue; Zheng, Wenwen; Alharbi, Osamah; Villena, Marco A.; Fang, Bin; Li, Xinyi; Milozzi, Alessandro; Farronato, Matteo; Munoz-Rojo, Miguel; Wang, Tao; Li, Ren; Fariborzi, Hossein; Roldan, Juan B.; Benstetter, Guenther; Zhang, Xixiang; Alshareef, Husam N.; Grasser, Tibor; Wu, Huaqiang; Ielmini, Daniele; Lanza, Mario", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid 2D-CMOS microchips for memristive applications", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploiting the excellent electronic properties of two-dimensional (2D) materials to fabricate advanced electronic circuits is a major goal for the semiconductor industry(1,2). However, most studies in this field have been limited to the fabrication and characterization of isolated large (more than 1 mu m(2)) devices on unfunctional SiO2-Si substrates. Some studies have integrated monolayer graphene on silicon microchips as a large-area (more than 500 mu m(2)) interconnection(3) and as a channel of large transistors (roughly 16.5 mu m(2)) (refs. 4,5), but in all cases the integration density was low, no computation was demonstrated and manipulating monolayer 2D materials was challenging because native pinholes and cracks during transfer increase variability and reduce yield. Here, we present the fabrication of high-integration-density 2D-CMOS hybrid microchips for memristive applications-CMOS stands for complementary metal-oxide-semiconductor. We transfer a sheet of multilayer hexagonal boron nitride onto the back-end-of-line interconnections of silicon microchips containing CMOS transistors of the 180 nm node, and finalize the circuits by patterning the top electrodes and interconnections. The CMOS transistors provide outstanding control over the currents across the hexagonal boron nitride memristors, which allows us to achieve endurances of roughly 5 million cycles in memristors as small as 0.053 mu m(2). We demonstrate in-memory computation by constructing logic gates, and measure spike-timing dependent plasticity signals that are suitable for the implementation of spiking neural networks. The high performance and the relatively-high technology readiness level achieved represent a notable advance towards the integration of 2D materials in microelectronic products and memristive applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2023, "Volume": 618, "Issue": 7963, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 57, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05973-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05973-1", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994587100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Dai, X; Zhu, L; Xu, C; Zhang, D; Silver, MA; Li, P; Chen, LH; Li, YZ; Zuo, DW; Zhang, H; Xiao, CL; Chen, J; Diwu, J; Farha, OK; Albrecht-Schmitt, TE; Chai, ZF; Wang, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jie; Dai, Xing; Zhu, Lin; Xu, Chao; Zhang, Duo; Silver, Mark A.; Li, Peng; Chen, Lanhua; Li, Yongzhong; Zuo, Douwen; Zhang, Hui; Xiao, Chengliang; Chen, Jing; Diwu, Juan; Farha, Omar K.; Albrecht-Schmitt, Thomas E.; Chai, Zhifang; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "99TcO4- remediation by a cationic polymeric network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct removal of (TcO4-)-Tc-99 from the highly acidic solution of used nuclear fuel is highly beneficial for the recovery of uranium and plutonium and more importantly aids in the elimination of Tc-99 discharge into the environment. However, this task represents a huge challenge given the combined extreme conditions of super acidity, high ionic strength, and strong radiation field. Here we overcome this challenge using a cationic polymeric network with significant TcO4- uptake capabilities in four aspects: the fastest sorption kinetics, the highest sorption capacity, the most promising uptake performance from highly acidic solutions, and excellent radiation-resistance and hydrolytic stability among all anion sorbent materials reported. In addition, this material is fully recyclable for multiple sorption/desorption trials, making it extremely attractive for waste partitioning and emergency remediation. The excellent TcO4- uptake capability is elucidated by X-ray absorption spectroscopy, solid-state NMR measurement, and density functional theory analysis on anion coordination and bonding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3007, "DOI": "10.1038/s41467-018-05380-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05380-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440413500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, K; Liu, B; Hu, WT; Dong, X; Wang, YB; Huang, Q; Gao, YF; Sun, L; Zhao, ZS; Wu, YJ; Zhang, Y; Ma, MD; Zhou, XF; He, JL; Yu, DL; Liu, ZY; Xu, B; Tian, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Kun; Liu, Bing; Hu, Wentao; Dong, Xiao; Wang, Yanbin; Huang, Quan; Gao, Yufei; Sun, Lei; Zhao, Zhisheng; Wu, Yingju; Zhang, Yang; Ma, Mengdong; Zhou, Xiang-Feng; He, Julong; Yu, Dongli; Liu, Zhongyuan; Xu, Bo; Tian, Yongjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coherent interfaces govern direct transformation from graphite to diamond", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the direct transformation from graphite to diamond has been a long-standing challenge with great scientific and practical importance. Previously proposed transformation mechanisms(1-3), based on traditional experimental observations that lacked atomistic resolution, cannot account for the complex nullostructures occurring at graphite-diamond interfaces during the transformation(4,5). Here we report the identification of coherent graphite-diamond interfaces, which consist of four basic structural motifs, in partially transformed graphite samples recovered from static compression, using high-angle annular dark-field scanning transmission electron microscopy. These observations provide insight into possible pathways of the transformation. Theoretical calculations confirm that transformation through these coherent interfaces is energetically favoured compared with those through other paths previously proposed(1-3). The graphite-to-diamond transformation is governed by the formation of nulloscale coherent interfaces (diamond nucleation), which, under static compression, advance to consume the remaining graphite (diamond growth). These results may also shed light on transformation mechanisms of other carbon materials and boron nitride under different synthetic conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2022, "Volume": 607, "Issue": 7919, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 486, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04863-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04863-2", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000823195900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sykam, K; Forsth, M; Sas, G; Restás, A; Das, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sykam, Kesavarao; Forsth, Michael; Sas, Gabriel; Restas, Agoston; Das, Oisik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phytic acid: A bio-based flame retardant for cotton and wool fabrics", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phytic acid (PA) is one of the widely used flame retardants (FRs) to treat a variety of fabrics owing to its high phosphorus content of ca. 28 wt% (with respect to its molecular weight), abundance, non-toxicity, and biocompatibility. The current review discusses the state-of-the-art of PA-based FRs for natural fabrics such as cotton and wool. The possibilities of making PA and FR-based multi-functional cotton fabrics having antimicrobial, conductive, hydrophobic properties are reported by virtue of the synergistic benefits associated with chitosan, silicon, nitrogen, and boron-based molecules. The factors influencing the FR behaviour as well as the durability of PA-based cotton and wool fabrics are discussed with respect to the concentration of PA, pH of the coating solution, temperature, and preparation methods. Holistically, PA has been proved to be a potential alternative to halogenated FRs to confer fire retardant property to cotton and wool fabrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 164, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113349, "DOI": "10.1016/j.indcrop.2021.113349", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2021.113349", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000635623200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Daus, A; Vaziri, S; Chen, V; Köroglu, C; Grady, RW; Bailey, CS; Lee, HR; Schauble, K; Brenner, K; Pop, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Daus, Alwin; Vaziri, Sam; Chen, Victoria; Koroglu, Cagil; Grady, Ryan W.; Bailey, Connor S.; Lee, Hye Ryoung; Schauble, Kirstin; Brenner, Kevin; Pop, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance flexible nulloscale transistors based on transition metal dichalcogenides", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) semiconducting transition metal dichalcogenides could be used to build high-performance flexible electronics. However, flexible field-effect transistors (FETs) based on such materials are typically fabricated with channel lengths on the micrometre scale, not benefitting from the short-channel advantages of 2D materials. Here, we report flexible nulloscale FETs based on 2D semiconductors; these are fabricated by transferring chemical-vapour-deposited transition metal dichalcogenides from rigid growth substrates together with nullo-patterned metal contacts, using a polyimide film, which becomes the flexible substrate after release. Transistors based on monolayer molybdenum disulfide (MoS2) are created with channel lengths down to 60 nm and on-state currents up to 470 mu A mu m(-1) at a drain-source voltage of 1 V, which is comparable to the performance of flexible graphene and crystalline silicon FETs. Despite the low thermal conductivity of the flexible substrate, we find that heat spreading through the metal gate and contacts is essential to reach such high current densities. We also show that the approach can be used to create flexible FETs based on molybdenum diselenide (MoSe2) and tungsten diselenide (WSe2). By transferring two-dimensional semiconductors from rigid growth substrates together with nullo-patterned metal contacts, flexible field-effect transistors can be fabricated with channel lengths down to 60 nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 501, "Article Number": null, "DOI": "10.1038/s41928-021-00598-6", "DOI Link": "http://dx.doi.org/10.1038/s41928-021-00598-6", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662845200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WB; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wenbin; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezoelectricity in two-dimensional group-III monochalcogenides", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is found that several layer-phase group-III monochalcogenides, including GaS, GaSe, and InSe, are piezoelectric in their monolayer form. First-principles calculations reveal that the piezoelectric coefficients of monolayer GaS, GaSe, and InSe (2.06, 2.30, and 1.46 pm center dot V-(TM) 1) are of the same order of magnitude as previously discovered two-dimensional (2D) piezoelectric materials such as boron nitride (BN) and MoS2 monolayers. This study therefore indicates that a strong piezoelectric response can be obtained in a wide range of two-dimensional materials with broken inversion symmetry. The co-existence of piezoelectricity and superior photo-sensitivity in these monochalcogenide monolayer semiconductors means they have the potential to allow for the integration of electromechanical and optical sensors on the same material platform.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3796, "End Page": 3802, "Article Number": null, "DOI": "10.1007/s12274-015-0878-8", "DOI Link": "http://dx.doi.org/10.1007/s12274-015-0878-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367003400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuai, CG; Xu, ZR; Xi, C; Hu, AY; Yang, ZJ; Zhang, Y; Sun, CJ; Li, LX; Sokaras, D; Dong, CK; Qiao, SZ; Du, XW; Lin, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuai, Chunguang; Xu, Zhengrui; Xi, Cong; Hu, Anyang; Yang, Zhijie; Zhang, Yan; Sun, Cheng-Jun; Li, Luxi; Sokaras, Dimosthenis; Dong, Cunku; Qiao, Shi-Zhang; Du, Xi-Wen; Lin, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase segregation reversibility in mixed-metal hydroxide water oxidation catalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving stable, low-cost electrocatalysts represents a daunting challenge towards practical water oxidation reactions. Here, we report that a degraded electrocatalyst can be revivified under catalytic operating conditions by manipulating reversible phase segregation. Under the oxygen evolution reaction conditions, Fe segregation develops in the Ni-Fe hydroxide host lattice, with the formation of FeOOH, resulting in an interface between the FeOOH and the host lattice. A dynamic metal dissolution-redeposition process accelerates the Fe segregation and formation of the FeOOH secondary phase, resulting in catalyst deactivation. Operando synchrotron spectroscopic and microscopic analyses suggest that the phase segregation is reversible between the water oxidation potential and the catalyst reduction potential. Therefore, we have developed an intermittent reduction methodology to revivify the catalytic activity under the operating conditions, enhancing catalyst durability. The present study highlights that tailoring phase segregation at the catalyst/electrolyte interface constitutes an important strategy for revivifying and stabilizing catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 743, "End Page": 753, "Article Number": null, "DOI": "10.1038/s41929-020-0496-z", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0496-z", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000562347700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, HF; Ye, L; Hou, JX; Jang, B; Han, GC; Cui, Y; Su, GM; Wang, C; Gao, BW; Yu, RN; Zhang, H; Yi, YP; Woo, HY; Ade, H; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Huifeng; Ye, Long; Hou, Junxian; Jang, Bomee; Han, Guangchao; Cui, Yong; Su, Gregory M.; Wang, Cheng; Gao, Bowei; Yu, Runnull; Zhang, Hao; Yi, Yuanping; Woo, Han Young; Ade, Harald; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Highly Efficient Nonfullerene Organic Solar Cells with Improved Intermolecular Interaction and Open-Circuit Voltage", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new acceptor-donor-acceptor-structured nonfullerene acceptor ITCC (3,9-bis(4-(1,1-dicyanomethylene)-3-methylene-2-oxo-cyclopenta[b]thiophen)-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d': 2,3-d']-s-indaceno[1,2-b: 5,6-b']dithiophene) is designed and synthesized via simple end-group modification. ITCC shows improved electron-transport properties and a high-lying lowest unoccupied molecular orbital level. A power conversion efficiency of 11.4% with an impressive V-OC of over 1 V is recorded in photovoltaic devices, suggesting that ITCC has great potential for applications in tandem organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2017, "Volume": 29, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700254, "DOI": "10.1002/adma.201700254", "DOI Link": "http://dx.doi.org/10.1002/adma.201700254", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402518900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, JQ; Liu, CF; Tian, M; Jia, XX; Jahrman, EP; Seidler, GT; Zhang, SQ; Liu, YY; Zhang, YF; Meng, CG; Cao, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Jiqi; Liu, Chaofeng; Tian, Meng; Jia, Xiaoxiao; Jahrman, Evan P.; Seidler, Gerald T.; Zhang, Shaoqing; Liu, Yanyan; Zhang, Yifu; Meng, Changgong; Cao, Guozhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and reversible zinc ion intercalation in Al-ion modified hydrated vanadate", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-ion batteries (ZIBs) are emerging candidates for safe and eco-friendly large-scale energy storage, but the critical challenge is to develop stable and robust cathode materials for reversible and fast Zn2+ intercalation. In the present work, the drawbacks of pure hydrated vanadium oxides (VOH), including low ion mobility and cycling instability, are mitigated by modifying the local atomic environment and increasing the amount of tetravalent vanadium cations. These effects are achieved by introducing trivalent Al-ions during a one-step hydrothermal synthesis. The expanded lattice spacing and improved conductivity of the synthesized Al-VOH enable rapid Zn2+ diffusion and electron transfer, leading to a high capacity of 380 mAh.g(-1) at 50 mA g(-1), as well as the excellent long-term cycling stability (capacity maintained over 3000 cycles). Further investigations of the reaction kinetics and mechanism reveal the effects of introducing Al-ions, and the role of Zn2+ trapped upon initial charging plays in promoting the subsequent electrochemical process and preventing the structural degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 70, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104519, "DOI": "10.1016/j.nulloen.2020.104519", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.104519", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521052900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "House, RA; Rees, GJ; Pérez-Osorio, MA; Marie, JJ; Boivin, E; Robertson, AW; Nag, A; Garcia-Fernulldez, M; Zhou, KJ; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "House, Robert A.; Rees, Gregory J.; Perez-Osorio, Miguel A.; Marie, John-Joseph; Boivin, Edouard; Robertson, Alex W.; Nag, Abhishek; Garcia-Fernulldez, Mirian; Zhou, Ke-Jin; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-cycle voltage hysteresis in Li-rich 3dcathodes associated with molecular O2trapped in the bulk", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-rich cathode materials are potential candidates for next-generation Li-ion batteries. However, they exhibit a large voltage hysteresis on the first charge/discharge cycle, which involves a substantial (up to 1 V) loss of voltage and therefore energy density. For Na cathodes, for example Na-0.75[Li0.25Mn0.75]O-2, voltage hysteresis can be explained by the formation of molecular O(2)trapped in voids within the particles. Here we show that this is also the case for Li1.2Ni0.13Co0.13Mn0.54O2. Resonullt inelastic X-ray scattering and(17)O magic angle spinning NMR spectroscopy show that molecular O-2, rather than O-2(2-), forms within the particles on the oxidation of O(2-)at 4.6 V versus Li+/Li on charge. These O(2)molecules are reduced back to O(2-)on discharge, but at the lower voltage of 3.75 V, which explains the voltage hysteresis in Li-rich cathodes.O-17 magic angle spinning NMR spectroscopy indicates a quantity of bulk O(2)consistent with the O-redox charge capacity minus the small quantity of O(2)loss from the surface. The implication is that O-2, trapped in the bulk and lost from the surface, can explain O-redox. Understanding the severe voltage hysteresis in the first cycle of Li-rich cathodes is essential to realize their full potential in batteries. P. G. Bruce and colleagues report the formation of molecular O(2)on charging rather than other oxidized O species is the cause for the voltage hysteresis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 777, "End Page": 785, "Article Number": null, "DOI": "10.1038/s41560-020-00697-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-00697-2", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571739400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoo, JJ; Wieghold, S; Sponseller, MC; Chua, MR; Bertram, SN; Hartono, NTP; Tresback, JS; Hansen, EC; Correa-Baena, JP; Bulovic, V; Buonassisi, T; Shin, SS; Bawendi, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoo, Jason J.; Wieghold, Sarah; Sponseller, Melany C.; Chua, Matthew R.; Bertram, Sophie N.; Hartono, Noor Titan Putri; Tresback, Jason S.; Hansen, Eric C.; Correa-Baena, Juan-Pablo; Bulovic, Vladimir; Buonassisi, Tonio; Shin, Seong Sik; Bawendi, Moungi G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An interface stabilized perovskite solar cell with high stabilized efficiency and low voltage loss", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilization of the crystal phase of inorganic/organic lead halide perovskites is critical for their high performance optoelectronic devices. However, due to the highly ionic nature of perovskite crystals, even phase stabilized polycrystalline perovskites can undergo undesirable phase transitions when exposed to a destabilizing environment. While various surface passivating agents have been developed to improve the device performance of perovskite solar cells, conventional deposition methods using a protic polar solvent, mainly isopropyl alcohol (IPA), results in a destabilization of the underlying perovskite layer and an undesirable degradation of device properties. We demonstrate the hidden role of IPA in surface treatments and develop a strategy in which the passivating agent is deposited without destabilizing the high quality perovskite underlayer. This strategy maximizes and stabilizes device performance by suppressing the formation of the perovskite delta-phase and amorphous phase during surface treatment, which is observed using conventional methods. Our strategy also effectively passivates surface and grain boundary defects, minimizing non-radiative recombination sites, and preventing carrier quenching at the perovskite interface. This results in an open-circuit-voltage loss of only similar to 340 mV, a champion device with a power conversion efficiency of 23.4% from a reverse current-voltage scan, a device with a record certified stabilized PCE of 22.6%, and enhanced operational stability. In addition, our perovskite solar cell exhibits an electroluminescence external quantum efficiency up to 8.9%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 583, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2019, "Volume": 12, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2192, "End Page": 2199, "Article Number": null, "DOI": "10.1039/c9ee00751b", "DOI Link": "http://dx.doi.org/10.1039/c9ee00751b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477950000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Dai, YH; Chen, RW; Xu, ZM; Li, JW; Zong, W; Li, HX; Li, Z; Zhang, ZY; Zhu, JX; Guo, F; Gao, X; Du, ZJ; Chen, JT; Wang, TL; He, GJ; Parkin, IP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Dai, Yuhang; Chen, Ruwei; Xu, Zhenming; Li, Jianwei; Zong, Wei; Li, Huangxu; Li, Zheng; Zhang, Zhenyu; Zhu, Jiexin; Guo, Fei; Gao, Xuan; Du, Zijuan; Chen, Jintao; Wang, Tianlei; He, Guanjie; Parkin, Ivan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Reversible Zinc Metal Anode in a Dilute Aqueous Electrolyte Enabled by a pH Buffer Additive", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries have drawn increasing attention due to the intrinsic safety, cost-effectiveness and high energy density. However, parasitic reactions and non-uniform dendrite growth on the Zn anode side impede their application. Herein, a multifunctional additive, ammonium dihydrogen phosphate (NHP), is introduced to regulate uniform zinc deposition and to suppress side reactions. The results show that the NH4+ tends to be preferably absorbed on the Zn surface to form a shielding effect and blocks the direct contact of water with Zn. Moreover, NH4+ and (H2PO4)(-) jointly maintain pH values of the electrode-electrolyte interface. Consequently, the NHP additive enables highly reversible Zn plating/stripping behaviors in Zn//Zn and Zn//Cu cells. Furthermore, the electrochemical performances of Zn//MnO2 full cells and Zn//active carbon (AC) capacitors are improved. This work provides an efficient and general strategy for modifying Zn plating/stripping behaviors and suppressing side reactions in mild aqueous electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 62, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212695", "DOI Link": "http://dx.doi.org/10.1002/anie.202212695", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000894095400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shang, Y; Li, XX; Song, JJ; Huang, SZ; Yang, Z; Xu, ZCJ; Yang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shang, Yang; Li, Xiaoxia; Song, Jiajia; Huang, Shaozhuan; Yang, Zhao; Xu, Zhichuan J.; Yang, Hui Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional Mn Vacancies in Mn-Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mn-Fe Prussian blue analogs (PBAs) cathode materials suffer from poor cycling reversibility and capacity retention during phase transition from cubic to tetragonal phase, which is related to the large structural deformation of Mn-N-6 octahedra caused by Jahn-Teller distortion Herein, we explore a controllable strategy for creating unconventional cation Mn vacancies (V-Mn) on the surface of Mn-Fe PBAs by utilizing a strong chelating agent-ethylenediaminet etraacetic acid disodium. The V-Mn in Mn-Fe PBAs can restrain the movement of Mn-N bonds and thereby mitigate the Jahn-Teller distortion of Mn-N(6 )octahedra, leading to highly reversible phase transitions of Mn-Fe PBAs as well as an outstanding long-term cycling stability and capacity retention for both the half-cell (72.3% after 2,700 cycles at 0.5 A g(-1)) and full cell (75.5% after 550 cycles at 0,1 A g(-1)). This work opens up a universal avenue to explore the relationship between vacancies and electrochemical performances, even in other materials beyond PBAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2020, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1804, "End Page": 1818, "Article Number": null, "DOI": "10.1016/j.chempr.2020.05.004", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.05.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558678900028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mou, NL; Sun, SL; Dong, HX; Dong, SH; He, Q; Zhou, L; Zhang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mou, nullli; Sun, Shulin; Dong, Hongxing; Dong, Shaohua; He, Qiong; Zhou, Lei; Zhang, Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybridization-induced broadband terahertz wave absorption with graphene metasurfaces", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic (EM) wave absorption plays a vital role in photonics. While metasurfaces are proposed to absorb EM waves efficiently, most of them exhibit limited bandwidth and fixed functionalities. Here, we propose a broadband and tunable terahertz (THz) absorber based on a graphene-based metasurface, which is constructed by a single layer of closely patterned graphene concentric double rings and a metallic mirror separated by an ultrathin SiO2 layer. Plasmonic hybridization between two graphene rings significantly enlarges the absorption bandwidth, which can be further tuned by gating the graphene. Moreover, the specific design also makes our device insensitive to the incident angle and polarization state of impinging EM waves. Our results may inspire certain wave-modulation-related applications, such as THz imaging, smart absorber, tunable sensor, etc. (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2018, "Volume": 26, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11728, "End Page": 11736, "Article Number": null, "DOI": "10.1364/OE.26.011728", "DOI Link": "http://dx.doi.org/10.1364/OE.26.011728", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431718300058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, Y; Liang, S; Wang, X; Zhang, MY; Hao, SM; Cui, X; Li, ZW; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Yan; Liang, Shuang; Wang, Xiang; Zhang, Mingyue; Hao, Shu-Meng; Cui, Xun; Li, Zhiwei; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust wrinkled MoS2/N-C bifunctional electrocatalysts interfaced with single Fe atoms for wearable zinc-air batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to create highly efficient and stable bifunctional electrocatalysts, capable of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in the same electrolyte, represents an important endeavor toward high-performance zinc-air batteries (ZABs). Herein, we report a facile strategy for crafting wrinkled MoS2/N-doped carbon core/shell nullospheres interfaced with single Fe atoms (denoted MoS2@Fe-N-C) as superior ORR/OER bifunctional electrocatalysts for robust wearable ZABs with a high capacity and outstanding cycling stability. Specifically, the highly crumpled MoS2 nullosphere core is wrapped with a layer of single-Fe-atom-impregnated, N-doped carbon shell (i.e., Fe-N-C shell with well-dispersed FeN4 sites). Intriguingly, MoS2@Fe-N-C nullospheres manifest an ORR half-wave potential of 0.84 V and an OER overpotential of 360 mV at 10 mA.cm(-2). More importantly, density functional theory calculations reveal the lowered energy barriers for both ORR and OER, accounting for marked enhanced catalytic performance of MoS2@Fe-N-C nullospheres. Remarkably, wearable ZABs assembled by capitalizing on MoS2@Fe-N-C nullospheres as an air electrode with an ultralow area loading (i.e., 0.25 mg.cm(-2)) display excellent stability against deformation, high special capacity (i.e., 442 mAh.g(Zn)(-1)), excellent power density (i.e., 78 mW.cm(-2)) and attractive cycling stability (e.g., 50 cycles at current density of 5 mA.cm(-2)). This study provides a platform to rationally design single-atom-interfaced core/shell bifunctional electrocatalysts for efficient metal-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2021, "Volume": 118, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2110036118", "DOI": "10.1073/pnas.2110036118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2110036118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000710708300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, HY; Jiao, TF; Zhang, QR; Guo, WF; Peng, QM; Yan, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Haiying; Jiao, Tifeng; Zhang, Qingrui; Guo, Wenfeng; Peng, Qiuming; Yan, Xuehai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of Graphene Oxide-Based Hydrogels as Efficient Dye Adsorbents for Wastewater Treatment", "Source Title": "nullOSCALE RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene oxide (GO) sheets exhibit superior adsorption capacity for removing organic dye pollutants from an aqueous environment. In this paper, the facile preparation of GO/polyethylenimine (PEI) hydrogels as efficient dye adsorbents has been reported. The GO/PEI hydrogels were achieved through both hydrogen bonding and electrostatic interactions between amine-rich PEI and GO sheets. For both methylene blue (MB) and rhodamine B (RhB), the as-prepared hydrogels exhibit removal rates within about 4 h in accordance with the pseudo-second-order model. The dye adsorption capacity of the hydrogel is mainly attributed to the GO sheets, whereas the PEI was incorporated to facilitate the gelation process of GO sheets. More importantly, the dye-adsorbed hydrogels can be conveniently separated from an aqueous environment, suggesting potential large-scale applications of the GO-based hydrogels for organic dye removal and wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2015, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 272, "DOI": "10.1186/s11671-015-0931-2", "DOI Link": "http://dx.doi.org/10.1186/s11671-015-0931-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357131400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CW; Song, ZN; Zhao, DW; Xiao, CX; Subedi, B; Shrestha, N; Junda, MM; Wang, CL; Jiang, CS; Al-Jassim, M; Ellingson, RJ; Podraza, NJ; Zhu, K; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chongwen; Song, Zhaoning; Zhao, Dewei; Xiao, Chuanxiao; Subedi, Biwas; Shrestha, Niraj; Junda, Maxwell M.; Wang, Changlei; Jiang, Chun-Sheng; Al-Jassim, Mowafak; Ellingson, Randy J.; Podraza, Nikolas J.; Zhu, Kai; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reducing Saturation-Current Density to Realize High-Efficiency Low-Bandgap Mixed Tin-Lead Halide Perovskite Solar Cells", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The unsatisfactory performance of low-bandgap mixed tin (Sn)-lead (Pb) halide perovskite subcells has been one of the major obstacles hindering the progress of the power conversion efficiencies (PCEs) of all-perovskite tandem solar cells. By analyzing dark-current density and distribution, it is identified that charge recombination at grain boundaries is a key factor limiting the performance of low-bandgap mixed Sn-Pb halide perovskite subcells. It is further found that bromine (Br) incorporation can effectively passivate grain boundaries and lower the dark current density by two-three orders of magnitude. By optimizing the Br concentration, low-bandgap (1.272 eV) mixed Sn-Pb halide perovskite solar cells are fabricated with open-circuit voltage deficits as low as 0.384 V and fill factors as high as 75%. The best-performing device demonstrates a PCE of >19%. The results suggest an important direction for improving the performance of low-bandgap mixed Sn-Pb halide perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803135, "DOI": "10.1002/aenm.201803135", "DOI Link": "http://dx.doi.org/10.1002/aenm.201803135", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456215200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naebe, M; Wang, J; Amini, A; Khayyam, H; Hameed, N; Li, LH; Chen, Y; Fox, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naebe, Minoo; Wang, Jing; Amini, Abbas; Khayyam, Hamid; Hameed, Nishar; Li, Lu Hua; Chen, Ying; Fox, Bronwyn", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical Property and Structure of Covalent Functionalised Graphene/Epoxy nullocomposites", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermally reduced graphene nulloplatelets were covalently functionalised via Bingel reaction to improve their dispersion and interfacial bonding with an epoxy resin. Functionalised graphene were characterized by microscopic, thermal and spectroscopic techniques. Thermal analysis of functionalised graphene revealed a significantly higher thermal stability compared to graphene oxide. Inclusion of only 0.1 wt% of functionalised graphene in an epoxy resin showed 22% increase in flexural strength and 18% improvement in storage modulus. The improved mechanical properties of nullocomposites is due to the uniform dispersion of functionalised graphene and strong interfacial bonding between modified graphene and epoxy resin as confirmed by microscopy observations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 465, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4375, "DOI": "10.1038/srep04375", "DOI Link": "http://dx.doi.org/10.1038/srep04375", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332798000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YC; Zhao, J; Wang, SF; Chen, RR; Ding, J; Tsai, HJ; Zeng, WJ; Hung, SF; Xu, W; Wang, JH; Jaouen, F; Li, XN; Huang, YQ; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yachen; Zhao, Jian; Wang, Shifu; Chen, Ruru; Ding, Jie; Tsai, Hsin-Jung; Zeng, Wen-Jing; Hung, Sung-Fu; Xu, Wei; Wang, Junhu; Jaouen, Frederic; Li, Xuning; Huang, Yanqiang; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando Spectroscopic Analysis of Axial Oxygen-Coordinated Single-Sn-Atom Sites for Electrochemical CO2 Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sn-based materials have been demonstrated as promising catalysts for the selective electrochemical CO2 reduction reaction (CO2RR). However, the detailed structures of catalytic intermediates and the key surface species remain to be identified. In this work, a series of single-Sn-atom catalysts with well-defined structures is developed as model systems to explore their electrochemical reactivity toward CO2RR. The selectivity and activity of CO2 reduction to formic acid on Sn -single-atom sites are shown to be correlated with Sn(IV)-N4 moieties axially coordinated with oxygen (O-Sn-N4), reaching an optimal HCOOH Faradaic efficiency of 89.4% with a partial current density (jHCOOH) of 74.8 mA center dot cm-2 at -1.0 V vs reversible hydrogen electrode (RHE). Employing a combination of operando X-ray absorption spectroscopy, attenuated total reflectance surface-enhanced infrared absorption spectroscopy, Raman spectroscopy, and 119Sn Mo''ssbauer spectroscopy, surface-bound bidentate tin carbonate species are captured during CO2RR. Moreover, the electronic and coordination structures of the single-Sn-atom species under reaction conditions are determined. Density functional theory (DFT) calculations further support the preferred formation of Sn-O-CO2 species over the O-Sn-N4 sites, which effectively modulates the adsorption configuration of the reactive intermediates and lowers the energy barrier for the hydrogenation of *OCHO species, as compared to the preferred formation of *COOH species over the Sn-N4 sites, thereby greatly facilitating CO2-to-HCOOH conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2023, "Volume": 145, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7242, "End Page": 7251, "Article Number": null, "DOI": "10.1021/jacs.2c12952", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c12952", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948442500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XQ; Ji, CC; Meng, QQ; Mi, HY; Yang, Q; Li, ZX; Yang, NJ; Qiu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xiaoqing; Ji, Chenchen; Meng, Qiangqiang; Mi, Hongyu; Yang, Qi; Li, Zixiao; Yang, Nianjun; Qiu, Jieshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Freeze-Tolerant Hydrogel Electrolyte with High Strength for Stable Operation of Flexible Zinc-Ion Hybrid Supercapacitors", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing ionic conductive hydrogels with diversified properties is crucial for portable zinc-ion hybrid supercapacitors (ZHSCs). Herein, a freeze-tolerant hydrogel electrolyte (AF PVA-CMC/Zn(CF3SO3)(2)) is developed by forming a semi-interpenetrating anti-freezing polyvinyl alcohol-carboxymethyl cellulose (AF PVA-CMC) network filled with the ethylene glycol (EG)-containing Zn(CF3SO3)(2) aqueous solution. The semi-interpenetrating AF PVA-CMC/Zn(CF3SO3)(2) possesses enhanced mechanical properties, realizes the uniform zinc deposition, and impedes the dendrite growth. Notably, the interaction between PVA and EG suppresses the ice crystal formation and prevents freezing at -20 degrees C. Due to these advantages, the designed hydrogel owns high ionic conductivity of 1.73/0.75 S m(-1) at 20/-20 degrees C with excellent tensile/compression strength at 20 degrees C. Impressively, the flexible AF quasi-solid-state ZHSC employing the hydrogel electrolyte achieves a superior energy density at 20/-20 degrees C (87.9/60.7 Wh kg(-1)). It maintains nearly 84.8% of the initial capacity after 10 000 cycles and a low self-discharge rate (1.77 mV h(-1)) at 20 degrees C, together with great tolerance to corrosion. Moreover, this device demonstrates a stable electrochemical performance at -20 degrees C under deformation. The obtained results provide valuable insights for constructing durable hydrogel electrolytes in cold environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 18, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200055, "DOI": "10.1002/smll.202200055", "DOI Link": "http://dx.doi.org/10.1002/smll.202200055", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766985900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ajmal, A; Majeed, I; Malik, RN; Idriss, H; Nadeem, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ajmal, Anila; Majeed, Imran; Malik, Riffat Naseem; Idriss, Hicham; Nadeem, Muhammad Amtiaz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Principles and mechanisms of photocatalytic dye degradation on TiO2 based photocatalysts: a comparative overview", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The total annual production of synthetic dye is more than 7 x 10(5) tons. Annually, through only textile waste effluents, around one thousand tons of non-biodegradable textile dyes are discharged into natural streams and water bodies. Therefore, with growing environmental concerns and environmental awareness there is a need for the removal of dyes from local and industrial water effluents with a cost effective technology. In general, these dyes have been found to be resistant to biological as well as physical treatment technologies. In this regard, heterogeneous advanced oxidation processes (AOPs), involving photo-catalyzed degradation of dyes using semiconductor nulloparticles is considered as an efficient cure for dye pollution. In the last two decades TiO2 has received considerable interest because of its high potential as a photocatalyst to degrade a wide range of organic material including dyes. This review starts with (i) a brief overview on dye pollution, dye classification and dye decolourization/degradation strategies; (ii) focuses on the mechanisms involved in comparatively well understood TiO2 photocatalysts and (iii) discusses recent advancements to enhance TiO2 photocatalytic efficiency by (a) doping with metals, non-metals, transition metals, noble metals and lanthanide ions, (b) structural modifications of TiO2 and (c) immobilization of TiO2 by using various supports to make it a flexible and cost-effective commercial dye treatment technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1120, "Times Cited, All Databases": 1162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 4, "Issue": 70, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 37003, "End Page": 37026, "Article Number": null, "DOI": "10.1039/c4ra06658h", "DOI Link": "http://dx.doi.org/10.1039/c4ra06658h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341454000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ba, Y; Zhuang, SA; Zhang, YK; Wang, YT; Gao, Y; Zhou, HA; Chen, MF; Sun, WD; Liu, Q; Chai, GZ; Ma, J; Zhang, Y; Tian, HF; Du, HF; Jiang, WJ; null, CW; Hu, JM; Zhao, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ba, You; Zhuang, Shihao; Zhang, Yike; Wang, Yutong; Gao, Yang; Zhou, Hengan; Chen, Mingfeng; Sun, Weideng; Liu, Quan; Chai, Guozhi; Ma, Jing; Zhang, Ying; Tian, Huanfang; Du, Haifeng; Jiang, Wanjun; null, Cewen; Hu, Jia-Mian; Zhao, Yonggang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric-field control of skyrmions in multiferroic heterostructure via magnetoelectric coupling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Room-temperature skyrmions in magnetic multilayers are considered to be promising candidates for the next-generation spintronic devices. Several approaches have been developed to control skyrmions, but they either cause significant heat dissipation or require ultrahigh electric fields near the breakdown threshold. Here, we demonstrate electric-field control of skyrmions through strain-mediated magnetoelectric coupling in ferromagnetic/ferroelectric multiferroic heterostructures. We show the process of non-volatile creation of multiple skyrmions, reversible deformation and annihilation of a single skyrmion by performing magnetic force microscopy with in situ electric fields. Strain-induced changes in perpendicular magnetic anisotropy and interfacial Dzyaloshinskii-Moriya interaction strength are characterized experimentally. These experimental results, together with micromagnetic simulations, demonstrate that strain-mediated magnetoelectric coupling (via strain-induced changes in both the perpendicular magnetic anisotropy and interfacial Dzyaloshinskii-Moriya interaction is responsible for the observed electric-field control of skyrmions. Our work provides a platform to investigate electric-field control of skyrmions in multiferroic heterostructures and paves the way towards more energy-efficient skyrmion-based spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 322, "DOI": "10.1038/s41467-020-20528-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20528-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662810100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, J; Fang, SM; Zhang, ZH; Yin, J; Li, LX; Wang, X; Guo, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Jin; Fang, Sunmiao; Zhang, Zhuhua; Yin, Jun; Li, Luxian; Wang, Xiang; Guo, Wanlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-sustained electricity generator driven by the compatible integration of ambient moisture adsorption and evaporation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Generating electricity from air opens a promising way for green energy harvesting. Here, authors present a prototype driven by the integration of moisture adsorption with evaporation to generate continuous electricity for a long duration. Generating sustainable electricity from ambient humidity and natural evaporation has attracted tremendous interest recently as it requires no extra mechanical energy input and is deployable across all weather and geography conditions. Here, we present a device prototype for enhanced power generation from ambient humidity. This prototype uses both heterogenous materials assembled from a LiCl-loaded cellulon paper to facilitate moisture adsorption and a carbon-black-loaded cellulon paper to promote water evaporation. Exposing such a centimeter-sized device to ambient humidity can produce voltages of around 0.78 V and a current of around 7.5 mu A, both of which can be sustained for more than 10 days. The enhanced electric output and durability are due to the continuous water flow that is directed by evaporation through numerous, negatively charged channels within the cellulon papers. The voltage and current exhibit an excellent scaling behavior upon device integration to sufficiently power commercial devices including even cell phones. The results open a promising prospect of sustainable electricity generation based on a synergy between spontaneous moisture adsorption and water evaporation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3643, "DOI": "10.1038/s41467-022-31221-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31221-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000815645800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, XH; Song, TC; Wilson, NP; Clark, G; He, MH; Zhang, XO; Taniguchi, T; Watanabe, K; Yao, W; Xiao, D; McGuire, MA; Cobden, DH; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Xinghan; Song, Tiancheng; Wilson, Nathan P.; Clark, Genevieve; He, Minhao; Zhang, Xiaoou; Taniguchi, Takashi; Watanabe, Kenji; Yao, Wang; Xiao, Di; McGuire, Michael A.; Cobden, David H.; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Thin CrCl3: An In-Plane Layered Antiferromagnetic Insulator", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of magnetism in atomically thin layers of van der Waals (vdW) crystals has created new opportunities for exploring magnetic phenomena in the two-dimensional (2D) limit. In most 2D magnets studied to date, the c-axis is an easy axis, so that at zero applied field the polarization of each layer is perpendicular to the plane. Here, we demonstrate that atomically thin CrCl3 is a layered antiferromagnetic insulator with an easy-plane normal to the c-axis, that is, the polarization is in the plane of each layer and has no preferred direction within it. Ligand-field photoluminescence at 870 nm is observed down to the monolayer limit, demonstrating its insulating properties. We investigate the in-plane magnetic order using tunneling magnetoresistance in graphene/CrCl3/graphene tunnel junctions, establishing that the interlayer coupling is antiferromagnetic down to the bilayer. From the temperature dependence of the magnetoresistance, we obtain an effective magnetic phase diagram for the bilayer. Our result shows that CrCl3 should be useful for studying the physics of 2D phase transitions and for making new kinds of vdW spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 19, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3993, "End Page": 3998, "Article Number": null, "DOI": "10.1021/acs.nullolett.9b01317", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.9b01317", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471834900080", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, MZ; Huang, HQ; Zhang, KN; Wang, EY; Yao, W; Deng, K; Wan, GL; Zhang, HY; Arita, M; Yang, HT; Sun, Z; Yao, H; Wu, Y; Fan, SS; Duan, WH; Zhou, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Mingzhe; Huang, Huaqing; Zhang, Kenull; Wang, Eryin; Yao, Wei; Deng, Ke; Wan, Guoliang; Zhang, Hongyun; Arita, Masashi; Yang, Haitao; Sun, Zhe; Yao, Hong; Wu, Yang; Fan, Shoushan; Duan, Wenhui; Zhou, Shuyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lorentz-violating type-II Dirac fermions in transition metal dichalcogenide PtTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological semimetals have recently attracted extensive research interests as host materials to condensed matter physics counterparts of Dirac and Weyl fermions originally proposed in high energy physics. Although Lorentz invariance is required in high energy physics, it is not necessarily obeyed in condensed matter physics, and thus Lorentz-violating type-II Weyl/Dirac fermions could be realized in topological semimetals. The recent realization of type-II Weyl fermions raises the question whether their spin-degenerate counterpart-type-II Dirac fermions-can be experimentally realized too. Here, we report the experimental evidence of type-II Dirac fermions in bulk stoichiometric PtTe2 single crystal. Angle-resolved photoemission spectroscopy measurements and first-principles calculations reveal a pair of strongly tilted Dirac cones along the G-A direction, confirming PtTe2 as a type-II Dirac semimetal. Our results provide opportunities for investigating novel quantum phenomena (e.g., anisotropic magneto-transport) and topological phase transition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 257, "DOI": "10.1038/s41467-017-00280-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00280-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407553800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, H; Tian, HJ; Wang, SJ; Chen, SM; Zhang, F; Song, L; Liu, H; Liu, J; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Hao; Tian, Huajun; Wang, Shijian; Chen, Shuangming; Zhang, Fan; Song, Li; Liu, Hao; Liu, Jian; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-power lithium-selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selenium cathodes have attracted considerable attention due to high electronic conductivity and volumetric capacity comparable to sulphur cathodes. However, practical development of lithium-selenium batteries has been hindered by the low selenium reaction activity with lithium, high volume changes and rapid capacity fading caused by the shuttle effect of polyselenides. Recently, single atom catalysts have attracted extensive interests in electrochemical energy conversion and storage because of unique electronic and structural properties, maximum atom-utilization efficiency, and outstanding catalytic performances. In this work, we developed a facile route to synthesize cobalt single atoms/nitrogen-doped hollow porous carbon (Co-SA-HC). The cobalt single atoms can activate selenium reactivity and immobilize selenium and polyselenides. The as-prepared selenium-carbon (Se@Co-SA-HC) cathodes deliver a high discharge capacity, a superior rate capability, and excellent cycling stability with a Coulombic efficiency of similar to 100%. This work could open an avenue for achieving long cycle life and high-power lithium-selenium batteries. Lithium selenium batteries are attractive energy storage systems, but they are hindered by low selenium reaction activity and rapid capacity fading. Herein, the authors report a selenium host with atomic cobalt electrocatalyst which exhibits superior performances in lithium-selenium batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5025, "DOI": "10.1038/s41467-020-18820-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18820-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000578460200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, JY; Zhou, M; Qian, YX; Cong, ZH; Chen, S; Zhang, WJ; Jiang, WN; Dai, CZ; Shao, N; Ji, ZM; Zou, JC; Xiao, XM; Liu, LQ; Chen, MZ; Li, J; Liu, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Jiayang; Zhou, Min; Qian, Yuxin; Cong, Zihao; Chen, Sheng; Zhang, Wenjing; Jiang, Weinull; Dai, Chengzhi; Shao, Ning; Ji, Zhemin; Zou, Jingcheng; Xiao, Ximian; Liu, Longqiang; Chen, Minzhang; Li, Jin; Liu, Runhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Addressing MRSA infection and antibacterial resistance with peptoid polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antibiotic resistance is a major issue in medicine and new antimicrobials for treating resistant infection are needed. Here, the authors report on antibacterial peptoid polymers, prepared via NNCA ring-opening polymerization, demonstrating antibacterial function against MRSA in vitro and in in vivo infection models. Methicillin-Resistant Staphylococcus aureus (MRSA) induced infection calls for antibacterial agents that are not prone to antimicrobial resistance. We prepare protease-resistant peptoid polymers with variable C-terminal functional groups using a ring-opening polymerization of N-substituted N-carboxyanhydrides (NNCA), which can provide peptoid polymers easily from the one-pot synthesis. We study the optimal polymer that displays effective activity against MRSA planktonic and persister cells, effective eradication of highly antibiotic-resistant MRSA biofilms, and potent anti-infectious performance in vivo using the wound infection model, the mouse keratitis model, and the mouse peritonitis model. Peptoid polymers show insusceptibility to antimicrobial resistance, which is a prominent merit of these antimicrobial agents. The low cost, convenient synthesis and structure diversity of peptoid polymers, the superior antimicrobial performance and therapeutic potential in treating MRSA infection altogether imply great potential of peptoid polymers as promising antibacterial agents in treating MRSA infection and alleviating antibiotic resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5898, "DOI": "10.1038/s41467-021-26221-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26221-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000705238300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, RH; Hua, DW; Van Hoeck, J; Berdecka, D; Léger, L; De Munter, S; Fraire, JC; Raes, L; Harizaj, A; Sauvage, F; Goetgeluk, G; Pille, M; Aalders, J; Belza, J; Van Acker, T; Bolea-Fernulldez, E; Si, T; Vanhaecke, F; De Vos, WH; Vandekerckhove, B; van Hengel, J; Raemdonck, K; Huang, CB; De Smedt, SC; Braeckmans, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Ranhua; Hua, Dawei; Van Hoeck, Jelter; Berdecka, Dominika; Leger, Laurens; De Munter, Stijn; Fraire, Juan C.; Raes, Laurens; Harizaj, Aranit; Sauvage, Felix; Goetgeluk, Glenn; Pille, Melissa; Aalders, Jeffrey; Belza, Joke; Van Acker, Thibaut; Bolea-Fernulldez, Eduardo; Si, Ting; Vanhaecke, Frank; De Vos, Winnok H.; Vandekerckhove, Bart; van Hengel, Jolanda; Raemdonck, Koen; Huang, Chaobo; De Smedt, Stefaan C.; Braeckmans, Kevin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photothermal nullofibres enable safe engineering of therapeutic cells", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloparticle-mediated photoporation is used to temporarily permeabilize cell membranes for intracellular delivery of macromolecules, but cell exposure to nulloparticles might cause cellular damage and hamper application of the technique to therapeutic cell engineering. Here the authors show that, under photothermal heating, nullofibre-embedded iron oxide nulloparticles can be used to deliver effector macromolecules to different types of cells, in a contactless manner, with no cellular toxicity or diminished therapeutic potency. nulloparticle-sensitized photoporation is an upcoming approach for the intracellular delivery of biologics, combining high efficiency and throughput with excellent cell viability. However, as it relies on close contact between nulloparticles and cells, its translation towards clinical applications is hampered by safety and regulatory concerns. Here we show that light-sensitive iron oxide nulloparticles embedded in biocompatible electrospun nullofibres induce membrane permeabilization by photothermal effects without direct cellular contact with the nulloparticles. The photothermal nullofibres have been successfully used to deliver effector molecules, including CRISPR-Cas9 ribonucleoprotein complexes and short interfering RNA, to adherent and suspension cells, including embryonic stem cells and hard-to-transfect T cells, without affecting cell proliferation or phenotype. In vivo experiments furthermore demonstrated successful tumour regression in mice treated with chimeric antibody receptor T cells in which the expression of programmed cell death protein 1 (PD1) is downregulated after nullofibre photoporation with short interfering RNA to PD1. In conclusion, cell membrane permeabilization with photothermal nullofibres is a promising concept towards the safe and more efficient production of engineered cells for therapeutic applications, including stem cell or adoptive T cell therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 16, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1281, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-021-00976-3", "DOI Link": "http://dx.doi.org/10.1038/s41565-021-00976-3", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000710306500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, RC; Cheng, J; Zhang, JB; Zhou, JH; Cen, KF; Murphy, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Richen; Cheng, Jun; Zhang, Jiabei; Zhou, Junhu; Cen, Kefa; Murphy, Jerry D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting biomethane yield and production rate with graphene: The potential of direct interspecies electron transfer in anaerobic digestion", "Source Title": "BIORESOURCE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interspecies electron transfer between bacteria and archaea plays a vital role in enhancing energy efficiency of anaerobic digestion (AD). Conductive carbon materials (i.e. graphene nullomaterial and activated charcoal) were assessed to enhance AD of ethanol (a key intermediate product after acidogenesis of algae). The addition of graphene (1.0 g/L) resulted in the highest biomethane yield (695.0 +/- 9.1 mL/g) and production rate (95.7 +/- 7.6 mL/g/d), corresponding to an enhancement of 25.0% in biomethane yield and 19.5% in production rate. The ethanol degradation constant was accordingly improved by 29.1% in the presence of graphene. Microbial analyses revealed that electrogenic bacteria of Geobacter and Pseudomonas along with archaea Methanobacterium and Methanospirillum might participate in direct interspecies electron transfer (DIET). Theoretical calculations provided evidence that graphene-based DIET can sustained a much higher electron transfer flux than conventional hydrogen transfer. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 239, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 352, "Article Number": null, "DOI": "10.1016/j.biortech.2017.05.017", "DOI Link": "http://dx.doi.org/10.1016/j.biortech.2017.05.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405318100042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Ye, WK; Zuo, YX; Zheng, C; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Ye, Weike; Zuo, Yunxing; Zheng, Chen; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graph Networks as a Universal Machine Learning Framework for Molecules and Crystals", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graph networks are a new machine learning (ML) paradigm that supports both relational reasoning and combinatorial generalization. Here, we develop universal MatErials Graph Network (MEGNet) models for accurate property prediction in both molecules and crystals. We demonstrate that the MEGNet models outperform prior ML models such as the SchNet in 11 out of 13 properties of the QM9 molecule data set. Similarly, we show that MEGNet models trained on similar to 60 000 crystals in the Materials Project substantially outperform prior ML models in the prediction of the formation energies, band gaps, and elastic moduli of crystals, achieving better than density functional theory accuracy over a much larger data set. We present two new strategies to address data limitations common in materials science and chemistry. First, we demonstrate a physically intuitive approach to unify four separate molecular MEGNet models for the internal energy at 0 K and room temperature, enthalpy, and Gibbs free energy into a single free energy MEGNet model by incorporating the temperature, pressure, and entropy as global state inputs. Second, we show that the learned element embeddings in MEGNet models encode periodic chemical trends and can be transfer-learned from a property model trained on a larger data set (formation energies) to improve property models with smaller amounts of data (band gaps and elastic moduli).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 796, "Times Cited, All Databases": 903, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2019, "Volume": 31, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3564, "End Page": 3572, "Article Number": null, "DOI": "10.1021/acs.chemmater.9b01294", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.9b01294", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468242300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Wang, J; Wu, B; Guo, XW; Wang, YJ; Chen, D; Zhang, YC; Du, K; Oguzie, EE; Ma, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, B.; Wang, J.; Wu, B.; Guo, X. W.; Wang, Y. J.; Chen, D.; Zhang, Y. C.; Du, K.; Oguzie, E. E.; Ma, X. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unmasking chloride attack on the passive film of metals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullometer-thick passive films on metals usually impart remarkable resistance to general corrosion but are susceptible to localized attack in certain aggressive media, leading to material failure with pronounced adverse economic and safety consequences. Over the past decades, several classic theories have been proposed and accepted, based on hypotheses and theoretical models, and oftentimes, not sufficiently nor directly corroborated by experimental evidence. Here we show experimental results on the structure of the passive film formed on a FeCr15Ni15 single crystal in chloride-free and chloride-containing media. We use aberration-corrected transmission electron microscopy to directly capture the chloride ion accumulation at the metal/film interface, lattice expansion on the metal side, undulations at the interface, and structural inhomogeneity on the film side, most of which had previously been rejected by existing models. This work unmasks, at the atomic scale, the mechanism of chloride-induced passivity breakdown that is known to occur in various metallic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2559, "DOI": "10.1038/s41467-018-04942-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04942-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436958500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, X; Du, X; Mathis, TS; Zhang, MM; Wang, XH; Shui, JL; Gogotsi, Y; Xu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xiang; Du, Xuan; Mathis, Tyler S.; Zhang, Mengmeng; Wang, Xuehang; Shui, Jianglan; Gogotsi, Yury; Xu, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Maximizing ion accessibility in MXene-knotted carbon nullotube composite electrodes for high-rate electrochemical energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the accessibility of ions in the electrodes of electrochemical energy storage devices is vital for charge storage and rate performance. In particular, the kinetics of ion transport in organic electrolytes is slow, especially at low operating temperatures. Herein, we report a new type of MXene-carbon nullotube (CNT) composite electrode that maximizes ion accessibility resulting in exceptional rate performance at low temperatures. The improved ion transport at low temperatures is made possible by breaking the conventional horizontal alignment of the two-dimensional layers of the MXene Ti3C2 by using specially designed knotted CNTs. The large, knot-like structures in the knotted CNTs prevent the usual restacking of the Ti3C2 flakes and create fast ion transport pathways. The MXene-knotted CNT composite electrodes achieve high capacitance (up to 130Fg(-1) (276Fcm(-3))) in organic electrolytes with high capacitance retention over a wide scan rate range of 10mVs(-1) to 10Vs(-1). This study is also the first report utilizing MXene-based supercapacitors at low temperatures (down to -60 degrees C). Improving the accessibility of ions in the electrodes of electrochemical energy storage devices is vital for charge storage and rate performance. Here, the authors report a new type of MXene-carbon nullotube composite electrode that maximizes ion accessibility, resulting in high rate performance at low temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6160, "DOI": "10.1038/s41467-020-19992-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19992-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000598902200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ko, Y; Kwon, M; Bae, WK; Lee, B; Lee, SW; Cho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ko, Yongmin; Kwon, Minseong; Bae, Wan Ki; Lee, Byeongyong; Lee, Seung Woo; Cho, Jinhan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible supercapacitor electrodes based on real metal-like cellulose papers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The effective implantation of conductive and charge storage materials into flexible frames has been strongly demanded for the development of flexible supercapacitors. Here, we introduce metallic cellulose paper-based supercapacitor electrodes with excellent energy storage performance by minimizing the contact resistance between neighboring metal and/or metal oxide nulloparticles using an assembly approach, called ligand-mediated layer-by-layer assembly. This approach can convert the insulating paper to the highly porous metallic paper with large surface areas that can function as current collectors and nulloparticle reservoirs for supercapacitor electrodes. Moreover, we demonstrate that the alternating structure design of the metal and pseudocapacitive nulloparticles on the metallic papers can remarkably increase the areal capacitance and rate capability with a notable decrease in the internal resistance. The maximum power and energy density of the metallic paper-based supercapacitors are estimated to be 15.1mWcm(-2) and 267.3 mu Wh cm(-2), respectively, substantially outperforming the performance of conventional paper or textile-type supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 536, "DOI": "10.1038/s41467-017-00550-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00550-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410710600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, JW; Zhu, YM; Li, XN; Luo, J; Deng, SX; Zhao, Y; Sun, YP; Wu, DJ; Hu, YF; Li, WH; Sham, TK; Li, RY; Gu, M; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Jianwen; Zhu, Yuanmin; Li, Xiaona; Luo, Jing; Deng, Sixu; Zhao, Yang; Sun, Yipeng; Wu, Duojie; Hu, Yongfeng; Li, Weihan; Sham, Tsun-Kong; Li, Ruying; Gu, Meng; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A gradient oxy-thiophosphate-coated Ni-rich layered oxide cathode for stable all-solid-state Li-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy Ni-rich layered oxide cathode materials such as LiNi0.8Mn0.1Co0.1O2 (NMC811) suffer from detrimental side reactions and interfacial structural instability when coupled with sulfide solid-state electrolytes in all-solid-state lithium-based batteries. To circumvent this issue, here we propose a gradient coating of the NMC811 particles with lithium oxy-thiophosphate (Li3P1+xO4S4x). Via atomic layer deposition of Li3PO4 and subsequent in situ formation of a gradient Li3P1+xO4S4x coating, a precise and conformal covering for NMC811 particles is obtained. The tailored surface structure and chemistry of NMC811 hinder the structural degradation associated with the layered-to-spinel transformation in the grain boundaries and effectively stabilize the cathode|solid electrolyte interface during cycling. Indeed, when tested in combination with an indium metal negative electrode and a Li10GeP2S12 solid electrolyte, the gradient oxy-thiophosphate-coated NCM811-based positive electrode enables the delivery of a specific discharge capacity of 128mAh/g after almost 250 cycles at 0.178mA/cm(2) and 25 degrees C. Layered oxide cathode active materials suffer from interfacial structural instability when coupled with sulfide solid-state electrolytes. Here, the authors propose a gradient coating with a lithium oxythiophosphate layer that can stabilize the cathode|solid-state electrolyte interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 146, "DOI": "10.1038/s41467-022-35667-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35667-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928461700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yabuuchi, N; Takeuchi, M; Nakayama, M; Shiiba, H; Ogawa, M; Nakayama, K; Ohta, T; Endo, D; Ozaki, T; Inamasu, T; Sato, K; Komaba, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yabuuchi, Naoaki; Takeuchi, Mitsue; Nakayama, Masanobu; Shiiba, Hiromasa; Ogawa, Masahiro; Nakayama, Keisuke; Ohta, Toshiaki; Endo, Daisuke; Ozaki, Tetsuya; Inamasu, Tokuo; Sato, Kei; Komaba, Shinichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-capacity electrode materials for rechargeable lithium batteries: Li3NbO4-based system with cation-disordered rocksalt structure", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium batteries have rapidly risen to prominence as fundamental devices for green and sustainable energy development. Lithium batteries are now used as power sources for electric vehicles. However, materials innovations are still needed to satisfy the growing demand for increasing energy density of lithium batteries. In the past decade, lithium-excess compounds, Li2MeO3 (Me = Mn4+, Ru4+, etc.), have been extensively studied as high-capacity positive electrode materials. Although the origin as the high reversible capacity has been a debatable subject for a long time, recently it has been confirmed that charge compensation is partly achieved by solid-state redox of nonmetal anions (i.e., oxide ions), coupled with solid-state redox of transition metals, which is the basic theory used for classic lithium insertion materials, such as LiMeO2 (Me = Co3+, Ni3+, etc.). Herein, as a compound with further excess lithium contents, a cation-ordered rocksalt phase with lithium and pentavalent niobium ions, Li3NbO4, is first examined as the host structure of a new series of high-capacity positive electrode materials for rechargeable lithium batteries. Approximately 300 mAh.g(-1) of high-reversible capacity at 50 degrees C is experimentally observed, which partly originates from charge compensation by solid-state redox of oxide ions. It is proposed that such a charge compensation process by oxide ions is effectively stabilized by the presence of electrochemically inactive niobium ions. These results will contribute to the development of a new class of high-capacity electrode materials, potentially with further lithium enrichment (and fewer transition metals) in the close-packed framework structure with oxide ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2015, "Volume": 112, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7650, "End Page": 7655, "Article Number": null, "DOI": "10.1073/pnas.1504901112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1504901112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356731300051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Joe, YI; Chen, XM; Ghaemi, P; Finkelstein, KD; de la Peña, GA; Gan, Y; Lee, JCT; Yuan, S; Geck, J; MacDougall, GJ; Chiang, TC; Cooper, SL; Fradkin, E; Abbamonte, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Joe, Y. I.; Chen, X. M.; Ghaemi, P.; Finkelstein, K. D.; de la Pena, G. A.; Gan, Y.; Lee, J. C. T.; Yuan, S.; Geck, J.; MacDougall, G. J.; Chiang, T. C.; Cooper, S. L.; Fradkin, E.; Abbamonte, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergence of charge density wave domain walls above the superconducting dome in 1T-TiSe2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductivity in so-called unconventional superconductors is nearly always found in the vicinity of another ordered state, such as antiferromagnetism, charge density wave (CDW), or stripe order. This suggests a fundamental connection between superconductivity and fluctuations in some other order parameter. To better understand this connection, we used high-pressure X-ray scattering to directly study the CDW order in the layered dichalcogenide TiSe2, which was previously shown to exhibit superconductivity when the CDW is suppressed by pressure(1) or intercalation of Cu atoms(2). We succeeded in suppressing the CDW fully to zero temperature, establishing for the first time the existence of aquantum critical point (QCP) at P-c = 5.1 +/- 0.2 GPa, which is more than 1 GPa beyond the end of the superconducting region. Unexpectedly, at P = 3 GPa we observed a reentrant, weakly first order, incommensurate phase, indicating the presence of a Lifshitz tricritical point somewhere above the superconducting dome. Our study suggests that superconductivity in TiSe2 may not be connected to the QCP itself, but to the formation of CDW domain walls.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 421, "End Page": 425, "Article Number": null, "DOI": "10.1038/NPHYS2935", "DOI Link": "http://dx.doi.org/10.1038/NPHYS2935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336969500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, R; Li, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Rui; Li, Weihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Thermal-Stability and High-Thermal-Conductivity Ti3C2Tx MXene/Poly(vinyl alcohol) (PVA) Composites", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes, a new family of two-dimensional materials, have recently attracted increasing attention due to their unique properties for a wide range of potential applications. Herein, we synthesize Ti3C2Tx/poly(vinyl alcohol) (PVA) composites and investigate the effects of the thermal properties of MXene by temperature-dependent Raman spectroscopy and polarized-laser power-dependent Raman spectroscopy. Compared to the Ti3C2Tx MXene, the PVA significantly improves the thermal stability of Ti3C2Tx by reducing the thermal coefficient of the E-g(1) mode from -0.06271 to -0.03357 cm(-1)/K, which is attributed to the strong Ti-O bonds formed between the MXene and PVA polymer confirmed by the X-ray photoelectron spectroscopy results. Meanwhile, the thermal conductivities of Ti3C2Tx and Ti3C2Tx/PVA composites reach as high as about 55.8 and 47.6 W/(m K), respectively. Overall, this work will contribute to extend the MXene applications in terms of polymer-based nullocomposites and improve the reliability of the related devices effectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2609, "End Page": 2617, "Article Number": null, "DOI": "10.1021/acsomega.7b02001", "DOI Link": "http://dx.doi.org/10.1021/acsomega.7b02001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427939400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lehner, AJ; Fabini, DH; Evans, HA; Hébert, CA; Smock, SR; Hu, J; Wang, HB; Zwanziger, JW; Chabinyc, ML; Seshadri, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lehner, Anna J.; Fabini, Douglas H.; Evans, Hayden A.; Hebert, Claire-Alice; Smock, Sara R.; Hu, Jerry; Wang, Hengbin; Zwanziger, Josef W.; Chabinyc, Michael L.; Seshadri, Ram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal and Electronic Structures of Complex Bismuth Iodides A3Bi2I9 (A = K, Rb, Cs) Related to Perovskite: Aiding the Rational Design of Photovoltaics", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ternary bismuth halides form an interesting functional materials class in the context of the closely related Pb halide perovsldte photovoltaics, especially given the significantly reduced toxicity of Bi when compared with Pb. The compounds A(3)Bi(2)I(9) (A = K, Rb, Cs) examined here crystallize in two different structure types: the layered defect-perovskite K3Bi2I9 type, and the Cs3Cr2CI9 type. The latter structure type features isolated Bi2I93- anions. Here, the crystal structures of the ternary iodides are redetermined and a corrected structural model for Rb3Bi2I9, as established by single crystal X-ray diffraction and solid state Rb-87 NMR spectroscopy and supported by density functional theory (DFT) calculations is presented. A variety of facile preparation techniques for single crystals, bulk materials, as well as solution-processed thin films are described. The optical properties and electronic structures are investigated experimentally by optical absorption and ultraviolet photoemission spectroscopy and computationally by DFT calculations. Absolute band positions of the valence and conduction bands of these semiconductors, with excellent agreement of experimental and calculated values, are reported, constituting a useful input for the rational interface design of efficient electronic and optoelectronic devices. The different structural connectivity in the two different structure types, somewhat surprisingly, appears to not impact band positions or band gaps in a significant manner. Computed dielectric properties, including the finding of anomalously large Born effective charge tensors on Bi3+, suggest proximal structural instabilities arising from the Be3+ 6s(2) lone pair. These anomalous Born effective charges are promising for defect screening and effective charge carrier transport. The structural, electronic, and optical properties of the complex bismuth iodides are to some extent similar to the related lead iodide perovskites. The deeper valence band positions in the complex bismuth iodides point to the need for different choices of hole transport materials for Bi-iodide based solar cell architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2015, "Volume": 27, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7137, "End Page": 7148, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b03147", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b03147", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363915000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Finnerty, C; Zhang, L; Sedlak, DL; Nelson, KL; Mi, BX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Finnerty, Casey; Zhang, Lei; Sedlak, David L.; Nelson, Kara L.; Mi, Baoxia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic Graphene Oxide Leaf for Solar Desalination with Zero Liquid Discharge", "Source Title": "ENVIRONMENTAL SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water vapor generation through sunlight harvesting and heat localization by carbon-based porous thin film materials holds great promise for sustainable, energy-efficient desalination and water treatment. However, the applicability of such materials in a high-salinity environment emphasizing zero-liquid-discharge brine disposal has not been studied. This paper reports the characterization and evaporation performance of a nature-inspired synthetic leaf made of graphene oxide (GO) thin film material, which exhibited broadband light absorption and excellent stability in high-salinity water. Under 0.82-sun illumination (825 W/m(2)), a GO leaf floating on water generated steam at a rate of 1.1 L per m(2) per hour (LMH) with a light-to-vapor energy conversion efficiency of 54%, while a GO leaf lifted above water in a tree-like configuration generated steam at a rate of 2.0 LMH with an energy efficiency of 78%. The evaporation rate increased with increasing light intensity and decreased with increasing salinity. During a long-term evaporation experiment with a 15 wt % NaCl solution, the GO leaf demonstrated stable performance despite gradual and eventually severe accumulation of salt crystals on the leaf surface. Furthermore, the GO leaf can be easily restored to its pristine condition by simply scraping off salt crystals from its surface and rinsing with water. Therefore, the robust high performance and relatively low fabrication cost of the synthetic GO leaf could potentially unlock a new generation of desalination technology that can be entirely solar-powered and achieve zero liquid discharge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2017, "Volume": 51, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11701, "End Page": 11709, "Article Number": null, "DOI": "10.1021/acs.est.7b03040", "DOI Link": "http://dx.doi.org/10.1021/acs.est.7b03040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413391800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lü, BZ; Chen, YF; Li, PY; Wang, B; Müllen, K; Yin, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Baozhong; Chen, Yifa; Li, Pengyu; Wang, Bo; Muellen, Klaus; Yin, Meizhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable radical anions generated from a porous perylenediimide metal-organic framework for boosting near-infrared photothermal conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radical anions of electron-deficient systems are widely used, but are easily reoxidized upon exposure to air. Therefore, the stabilization of radical anions under ambient conditions is of great significance, but still remains a scientific challenge. Herein, perylenediimide is employed to prepare a crystalline metal-organic framework for stabilizing radical anions without extensive chemical modification. The porous, three-dimensional framework of perylenediimide can trap electron donors such as amine vapors and produce radical anions in-situ through photo-induced electron transfer. The radical anions are protected against quenching by shielding effect in air and remain unobstructed in air for at least a month. Because of the high yield and stability of the radical anions, which are the basis for near-infrared photothermal conversion, the framework shows high near-infrared photothermal conversion efficiency (eta = 52.3%). The work provides an efficient and simple method towards ambient stable radical anions and affords a promising material for photothermal therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 767, "DOI": "10.1038/s41467-019-08434-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08434-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458754700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tusek, J; Engelbrecht, K; Eriksen, D; Dall'Olio, S; Tusek, J; Pryds, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tusek, Jaka; Engelbrecht, Kurt; Eriksen, Dan; Dall'Olio, Stefano; Tusek, Janez; Pryds, Nini", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A regenerative elastocaloric heat pump", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A large fraction of global energy use is for refrigeration and air-conditioning, which could be decarbonized if efficient renewable energy technologies could be found. Vapour-compression technology remains the most widely used system to move heat up the temperature scale after more than 100 years; however, caloric-based technologies (those using the magnetocaloric, electrocaloric, barocaloric or elastocaloric effect) have recently shown a significant potential as alternatives to replace this technology due to high efficiency and the use of green solid-state refrigerants. Here, we report a regenerative elastocaloric heat pump that exhibits a temperature span of 15.3 K on the water side with a corresponding specific heating power up to 800 W kg(-1) and maximum COP (coefficient-of-performance) values of up to 7. The efficiency and specific heating power of this device exceeds those of other devices based on caloric effects. These results open up the possibility of using the elastocaloric effect in various cooling and heat-pumping applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16134, "DOI": "10.1038/NENERGY.2016.134", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394784400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Voisin, T; Forien, JB; Perron, A; Aubry, S; Bertin, N; Samanta, A; Baker, A; Wang, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Voisin, Thomas; Forien, Jean-Baptiste; Perron, Aurelien; Aubry, Sylvie; Bertin, Nicolas; Samanta, Amit; Baker, Alexander; Wang, Y. Morris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New insights on cellular structures strengthening mechanisms and thermal stability of an austenitic stainless steel fabricated by laser powder-bed-fusion", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid solidification cellular structures are known to play a crucial role in helping achieve high strength and high ductility in 316L austenitic stainless steels fabricated by laser powder-bed-fusion (L-PBF). Despite this, the understanding of their intrinsic characteristics (e.g., crystallographic orientations, dislocations, precipitates, elemental segregations) and the respective impacts on the material's strength and thermal stability remains nebulous. We conduct several dedicated transmission electron microscopy (TEM) studies to investigate these strengthening mechanisms and identified that cell walls follow specific crystallographic orientations. The high density of tangled dislocations inside cell walls are found to have a higher tendency to dissociate, forming wider stacking faults while oxide precipitates are confined inside cell walls. These features act as barriers to moving dislocations upon plastic deformation and contribute to the high strength. Our dislocation dynamic simulations indicate that segregated particles are effective in blocking dislocations locally, helping the formation of dislocation cells and participating to the material strengthening. To study the thermal stability of L-PBF 316L SS, we perform systematic post-processing heat treatments from 400-1200 degrees C. Microstructure characterizations using electron backscatter diffraction, TEM, and synchrotron X-ray diffraction coupled with dislocation dynamics and CALPHAD simulations and tensile testing reveal three heat treatment zones where the structure-property relationship can be tuned. After annealing up to 600 degrees C, the microstructure remains stable; but the work hardening behavior is altered with a material that retains high strength and high ductility. Annealing between 600-1000 degrees C activates elemental diffusion and gradual disappearance of cell walls, leading to a sharp drop in yield strength and a tradeoff between strength and ductility. Low-angle grain boundaries remain stable up to 1000 degrees C while the average grain size defined by high angle grain boundaries is near constant at annealing temperatures up to 800 degrees C. Annealing above 1100 degrees C removes all L-PBF microstructure footprints and renders a conventional-like microstructure. Compared to conventional materials, L-PBF 316LSS displays substantially higher thermal stability and superior performance at elevated temperatures. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 203, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116476, "DOI": "10.1016/j.actamat.2020.11.018", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.11.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600589700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, M; Li, B; Cui, X; Jiang, BB; He, YJ; Chen, YH; O'Neil, D; Szymanski, P; El-Sayed, MA; Huang, JS; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Ming; Li, Bo; Cui, Xun; Jiang, Beibei; He, Yanjie; Chen, Yihuang; O'Neil, Daniel; Szymanski, Paul; El-Sayed, Mostafa A.; Huang, Jinsong; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Meniscus-assisted solution printing of large-grained perovskite films for high-efficiency solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control over morphology and crystallinity of metal halide perovskite films is of key importance to enable high-performance optoelectronics. However, this remains particularly challenging for solution-printed devices due to the complex crystallization kinetics of semiconductor materials within dynamic flow of inks. Here we report a simple yet effective meniscus-assisted solution printing (MASP) strategy to yield large-grained dense perovskite film with good crystallization and preferred orientation. Intriguingly, the outward convective flow triggered by fast solvent evaporation at the edge of the meniscus ink imparts the transport of perovskite solutes, thus facilitating the growth of micrometre-scale perovskite grains. The growth kinetics of perovskite crystals is scrutinized by in situ optical microscopy tracking to understand the crystallization mechanism. The perovskite films produced by MASP exhibit excellent optoelectronic properties with efficiencies approaching 20% in planar perovskite solar cells. This robust MASP strategy may in principle be easily extended to craft other solution-printed perovskite-based optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16045, "DOI": "10.1038/ncomms16045", "DOI Link": "http://dx.doi.org/10.1038/ncomms16045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404976200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shu, CQ; Qin, C; Chen, L; Wang, YF; Shi, Z; Yu, JM; Huang, JM; Zhao, CQ; Huan, ZG; Wu, CT; Zhu, M; Zhu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shu, Chaoqin; Qin, Chen; Chen, Lei; Wang, Yufeng; Shi, Zhe; Yu, Jiangming; Huang, Jimin; Zhao, Chaoqian; Huan, Zhiguang; Wu, Chengtie; Zhu, Min; Zhu, Yufang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Functionalized Bioceramic Scaffolds with Antioxidative Activity for Enhanced Osteochondral Regeneration", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Osteoarthritis (OA) is a degenerative disease that often causes cartilage lesions and even osteochondral damage. Osteochondral defects induced by OA are accompanied by an inflammatory arthrosis microenvironment with overproduced reactive oxygen species (ROS), resulting in the exacerbation of defects and difficulty regenerating osteochondral tissues. Therefore, it is urgently needed to develop osteochondral scaffolds that can not only promote the integrated regeneration of cartilage and subchondral bone, but also possess ROS-scavenging ability to protect tissues from oxidative stress. Herein, zinc-cobalt bimetallic organic framework (Zn/Co-MOF) functionalized bioceramic scaffolds are designed for repairing osteochondral defects under OA environment. By functionalizing Zn/Co-MOF on the 3D-printed beta-tricalcium phosphate (beta-TCP) scaffolds, the Zn/Co-MOF functionalized beta-TCP (MOF-TCP) scaffolds with broad-spectrum ROS-scavenging ability are successfully developed. Benefiting from its catalytic active sites and degradation products, Zn/Co-MOF endows the scaffolds with excellent antioxidative and anti-inflammatory properties to protect cells from ROS invasion, as well as dual-bioactivities of simultaneously inducing osteogenic and chondrogenic differentiation in vitro. Furthermore, in vivo results confirm that MOF-TCP scaffolds accelerate the integrated regeneration of cartilage and subchondral bone in severe osteochondral defects. This study offers a promising strategy for treating defects induced by OA as well as other inflammatory diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206875", "DOI Link": "http://dx.doi.org/10.1002/advs.202206875", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939431600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SQ; Chen, Y; Wang, XD; Jiao, HX; Zhao, QR; Huang, XN; Tai, XC; Zhou, Y; Chen, H; Wang, XJ; Huang, SY; Yan, HG; Lin, T; Shen, H; Hu, WD; Meng, XJ; Chu, JH; Wang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuaiqin; Chen, Yan; Wang, Xudong; Jiao, Hanxue; Zhao, Qianru; Huang, Xinning; Tai, Xiaochi; Zhou, Yong; Chen, Hao; Wang, Xingjun; Huang, Shenyang; Yan, Hugen; Lin, Tie; Shen, Hong; Hu, Weida; Meng, Xiangjian; Chu, Junhao; Wang, Jianlu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-sensitive polarization-resolved black phosphorus homojunction photodetector defined by ferroelectric domains", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the further miniaturization and integration of multi-dimensional optical information detection devices, polarization-sensitive photodetectors based on anisotropic low-dimension materials have attractive potential applications. However, the performance of these devices is restricted by intrinsic property of materials leading to a small polarization ratio of the detectors. Here, we construct a black phosphorus (BP) homojunction photodetector defined by ferroelectric domains with ultra-sensitive polarization photoresponse. With the modulation of ferroelectric field, the BP exhibits anisotropic dispersion changes, leading an increased photothermalelectric (PTE) current in the armchair (AC) direction. Moreover, the PN junction can promote the PTE current and accelerate carrier separation. As a result, the BP photodetector demonstrates an ultrahigh polarization ratio (PR) of 288 at 1450 nm incident light, a large photoresponsivity of 1.06 A/W, and a high detectivity of 1.27 x 10(11) cmHz(1/2)W(-1) at room temperature. This work reveals the great potential of BP in future polarized light detection. Integrated polarization-sensitive photodetectors are important for sensing applications and optical communication. Here, the authors report the realization of 2D black phosphorus homojunction photodetectors defined by ferroelectric substrates, showing polarization ratios up to 288 and high responsivity in the near-infrared.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3198, "DOI": "10.1038/s41467-022-30951-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30951-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZL; Wu, WL; Wang, ML; Wang, YA; Ma, XL; Luo, L; Chen, Y; Fan, KY; Pan, Y; Li, HL; Zeng, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhongling; Wu, Wenlong; Wang, Menglin; Wang, Yanull; Ma, Xinlong; Luo, Lei; Chen, Yue; Fan, Kaiyuan; Pan, Yang; Li, Hongliang; Zeng, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ambient-pressure hydrogenation of CO2 into long-chain olefins", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of CO2 by renewable power-generated hydrogen is a promising approach to a sustainable production of long-chain olefins (C-4+(=)) which are currently produced from petroleum resources. The decentralized small-scale electrolysis for hydrogen generation requires the operation of CO2 hydrogenation in ambient-pressure units to match the manufacturing scales and flexible on-demand production. Herein, we report a Cu-Fe catalyst which is operated under ambient pressure with comparable C-4+(=) selectivity (66.9%) to that of the state-of-the-art catalysts (66.8%) optimized under high pressure (35 bar). The catalyst is composed of copper, iron oxides, and iron carbides. Iron oxides enable reverse-water-gas-shift to produce CO. The synergy of carbide path over iron carbides and CO insertion path over interfacial sites between copper and iron carbides leads to efficient C-C coupling into C-4+(=). This work contributes to the development of small-scale low-pressure devices for CO2 hydrogenation compatible with sustainable hydrogen production. The conversion of CO2 by renewable power-generated hydrogen is a promising approach to a sustainable production of long-chain olefins. Here the authors report a Cu-Fe catalyst which achieves the hydrogenation of CO2 into long-chain olefins under ambient pressure via the synergy of carbide mechanism and CO insertion mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2396, "DOI": "10.1038/s41467-022-29971-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29971-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790385800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, T; Xiao, H; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Tao; Xiao, Hai; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full atomistic reaction mechanism with kinetics for CO reduction on Cu(100) from ab initio molecular dynamics free-energy calculations at 298 K", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NA critical step toward the rational design of new catalysts that achieve selective and efficient reduction of CO2 to specific hydrocarbons and oxygenates is to determine the detailed reaction mechanism including kinetics and product selectivity as a function of pH and applied potential for known systems. To accomplish this, we apply ab initio molecular metadynamics simulations (AIMD) for the water/Cu(100) system with five layers of the explicit solvent under a potential of -0.59 V [ reversible hydrogen electrode (RHE)] at pH 7 and compare with experiment. From these free-energy calculations, we determined the kinetics and pathways for major products (ethylene and methane) and minor products (ethanol, glyoxal, glycolaldehyde, ethylene glycol, acetaldehyde, ethane, and methanol). For an applied potential (U) greater than -0.6 V (RHE) ethylene, the major product, is produced via the Eley-Rideal (ER) mechanism using H2O + e(-). The rate-determining step (RDS) is C-C coupling of two CO, with Delta G not asymptotic to = 0.69 eV. For an applied potential less than -0.60 V (RHE), the rate of ethylene formation decreases, mainly due to the loss of CO surface sites, which are replaced by H*. The reappearance of C2H4 along with CH4 at U less than -0.85 V arises from *CHO formation produced via an ER process of H* with nonadsorbed CO (a unique result). This *CHO is the common intermediate for the formation of both CH4 and C2H4. These results suggest that, to obtain hydrocarbon products selectively and efficiency at pH 7, we need to increase the CO concentration by changing the solvent or alloying the surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 535, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2017, "Volume": 114, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1795, "End Page": 1800, "Article Number": null, "DOI": "10.1073/pnas.1612106114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1612106114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395099500046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, L; Liu, XJ; He, KY; Yu, GD; Yuan, H; Xu, M; Li, FY; Yu, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Lang; Liu, Xiaojun; He, Kunyun; Yu, Guodong; Yuan, Hang; Xu, Ming; Li, Fuyou; Yu, Yanlei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Geminate labels programmed by two-tone microdroplets combining structural and fluorescent color", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Creating a security label that carries entirely distinct information in reflective and fluorescent states would enhance anti-counterfeiting levels to deter counterfeits ranging from currencies to pharmaceuticals, but has proven extremely challenging. Efforts to tune the reflection color of luminescent materials by modifying inherent chemical structures remain outweighed by substantial trade-offs in fluorescence properties, and vice versa, which destroys the information integrity of labels in either reflection or fluorescent color. Here, a strategy is reported to design geminate labels by programming fluorescent cholesteric liquid crystal microdroplets (two-tone inks), where the luminescent material is 'coated' with the structural color from helical superstructures. These structurally defined microdroplets fabricated by a capillary microfluidic technique contribute to different but intact messages of both reflective and fluorescent patterns in the geminate labels. Such two-tone inks have enormous potential to provide a platform for encryption and protection of valuable authentic information in anti-counterfeiting technology. Creating an enhanced-security-level label that carries entirely distinct information in different optical states has proven challenging. Here, the authors design geminate labels by programming fluorescent cholesteric liquid crystal microdroplets to encrypt fluorescent security information behind colorful reflective patterns.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 699, "DOI": "10.1038/s41467-021-20908-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-20908-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684845600027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Linger, JG; Vardon, DR; Guarnieri, MT; Karp, EM; Hunsinger, GB; Franden, MA; Johnson, CW; Chupka, G; Strathmann, TJ; Pienkos, PT; Beckham, GT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Linger, Jeffrey G.; Vardon, Derek R.; Guarnieri, Michael T.; Karp, Eric M.; Hunsinger, Glendon B.; Franden, Mary Ann; Johnson, Christopher W.; Chupka, Gina; Strathmann, Timothy J.; Pienkos, Philip T.; Beckham, Gregg T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lignin valorization through integrated biological funneling and chemical catalysis", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignin is an energy-dense, heterogeneous polymer comprised of phenylpropanoid monomers used by plants for structure, water transport, and defense, and it is the second most abundant biopolymer on Earth after cellulose. In production of fuels and chemicals from biomass, lignin is typically underused as a feed-stock and burned for process heat because its inherent heterogeneity and recalcitrance make it difficult to selectively valorize. In nature, however, some organisms have evolved metabolic pathways that enable the utilization of lignin-derived aromatic molecules as carbon sources. Aromatic catabolism typically occurs via upper pathways that act as a biological funnel to convert heterogeneous substrates to central intermediates, such as protocatechuate or catechol. These intermediates undergo ring cleavage and are further converted via the beta-ketoadipate pathway to central carbon metabolism. Here, we use a natural aromatic-catabolizing organism, Pseudomonas putida KT2440, to demonstrate that these aromatic metabolic pathways can be used to convert both aromatic model compounds and heterogeneous, lignin-enriched streams derived from pilot-scale biomass pretreatment into medium chain-length polyhydroxyalkanoates (mcl-PHAs). mcl-PHAs were then isolated from the cells and demonstrated to be similar in physicochemical properties to conventional carbohydrate-derived mcl-PHAs, which have applications as bioplastics. In a further demonstration of their utility, mcl-PHAs were catalytically converted to both chemical precursors and fuel-range hydrocarbons. Overall, this work demonstrates that the use of aromatic catabolic pathways enables an approach to valorize lignin by overcoming its inherent heterogeneity to produce fuels, chemicals, and materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 619, "Times Cited, All Databases": 697, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2014, "Volume": 111, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12013, "End Page": 12018, "Article Number": null, "DOI": "10.1073/pnas.1410657111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1410657111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340438800039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, AK; Hoang, TB; Dridi, M; Deeb, C; Mikkelsen, MH; Schatz, GC; Odom, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Ankun; Hoang, Thang B.; Dridi, Montacer; Deeb, Claire; Mikkelsen, Maiken H.; Schatz, George C.; Odom, Teri W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Real-time tunable lasing from plasmonic nullocavity arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmon lasers can support ultrasmall mode confinement and ultrafast dynamics with device feature sizes below the diffraction limit. However, most plasmon-based nullolasers rely on solid gain materials (inorganic semiconducting nullowire or organic dye in a solid matrix) that preclude the possibility of dynamic tuning. Here we report an approach to achieve real-time, tunable lattice plasmon lasing based on arrays of gold nulloparticles and liquid gain materials. Optically pumped arrays of gold nulloparticles surrounded by liquid dye molecules exhibit lasing emission that can be tuned as a function of the dielectric environment. Wavelength-dependent time-resolved experiments show distinct lifetime characteristics below and above the lasing threshold. By integrating gold nulloparticle arrays within microfluidic channels and flowing in liquid gain materials with different refractive indices, we achieve dynamic tuning of the plasmon lasing wavelength. Tunable lattice plasmon lasers offer prospects to enhance and detect weak physical and chemical processes on the nulloscale in real time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6939, "DOI": "10.1038/ncomms7939", "DOI Link": "http://dx.doi.org/10.1038/ncomms7939", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, RL; Li, YZ; Zhou, X; Yu, A; Huang, Q; Xu, TT; Zhu, LT; Peng, P; Song, SY; Echegoyen, L; Li, FF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ruiling; Li, Yaozhou; Zhou, Xuan; Yu, Ao; Huang, Qi; Xu, Tingting; Zhu, Longtao; Peng, Ping; Song, Shuyan; Echegoyen, Luis; Li, Fang-Fang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atomic platinum on fullerene C60 surfaces for accelerated alkaline hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of high-loading Pt single-atom catalysts is important but challenging. Here, the authors use fullerene C-60 with electron-deficient C=C bonds to build Pt/C-60 catalysts with abundant Pt single atoms which exhibits high catalytic activity for electrochemical hydrogen evolution reactions The electrocatalytic hydrogen evolution reaction (HER) is one of the most studied and promising processes for hydrogen fuel generation. Single-atom catalysts have been shown to exhibit ultra-high HER catalytic activity, but the harsh preparation conditions and the low single-atom loading hinder their practical applications. Furthermore, promoting hydrogen evolution reaction kinetics, especially in alkaline electrolytes, remains as an important challenge. Herein, Pt/C-60 catalysts with high-loading, high-dispersion single-atomic platinum anchored on C-60 are achieved through a room-temperature synthetic strategy. Pt/C-60-2 exhibits high HER catalytic performance with a low overpotential (eta(10)) of 25 mV at 10 mA cm(-2). Density functional theory calculations reveal that the Pt-C-60 polymeric structures in Pt/C-60-2 favors water adsorption, and the shell-like charge redistribution around the Pt-bonding region induced by the curved surfaces of two adjacent C-60 facilitates the desorption of hydrogen, thus favoring fast reaction kinetics for hydrogen evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-38126-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38126-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983415900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fatemi, V; Wu, SF; Cao, Y; Bretheau, L; Gibson, QD; Watanabe, K; Taniguchi, T; Cava, RJ; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fatemi, Valla; Wu, Sanfeng; Cao, Yuan; Bretheau, Landry; Gibson, Quinn D.; Watanabe, Kenji; Taniguchi, Takashi; Cava, Robert J.; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically tunable low-density superconductivity in a monolayer topological insulator", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Turning on superconductivity in a topologically nontrivial insulator may provide a route to search for non-Abelian topological states. However, existing demonstrations of superconductor-insulator switches have involved only topologically trivial systems. Here we report reversible, in situ electrostatic on-off switching of superconductivity in the recently established quantum spin Hall insulator monolayer tungsten ditelluride (WTe2). Fabricated into a van der Waals field-effect transistor, the monolayer's ground state can be continuously gate-tuned from the topological insulating to the superconducting state, with critical temperatures T-c up to similar to 1 kelvin. Our results establish monolayer WTe2 as a material platform for engineering nullodevices that combine superconducting and topological phases of matter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2018, "Volume": 362, "Issue": 6417, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 926, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar4642", "DOI Link": "http://dx.doi.org/10.1126/science.aar4642", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451124500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, B; Yu, ZSJ; Manzoor, S; Wang, S; Weigand, W; Yu, ZH; Yang, G; Ni, ZY; Dai, XZ; Holman, ZC; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Bo; Yu, Zhengshan J.; Manzoor, Salman; Wang, Shen; Weigand, William; Yu, Zhenhua; Yang, Guang; Ni, Zhenyi; Dai, Xuezeng; Holman, Zachary C.; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blade-Coated Perovskites on Textured Silicon for 26%-Efficient Monolithic Perovskite/Silicon Tandem Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integrating perovskites onto textured silicon provides a pathway to 30% tandem solar cells. However, deposition of 0.5-1 mm thick perovskite layers from solution onto textured silicon with typical pyramid heights of 3-10 mm remains a challenge. We propose a new tandem architecture that enables scalable, solution-based blading of perovskites onto silicon wafers textured with pyramids less than 1 mmin height. These pyramids are rough enough to scatter light within the silicon nearly as efficiently as large pyramids but smooth enough to solutionprocess a perovskite film. A nitrogen-assisted blading process deposits both a conformal hole transport layer and a planarizing perovskite layer that fully covers the textured silicon, at a speed of 1.5 m/min. With a textured light-scattering layer added to the top of the tandem to reduce front-surface reflectance, we achieve a perovskite/silicon tandem cell with an efficiency of 26% on textured silicon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 850, "End Page": 864, "Article Number": null, "DOI": "10.1016/j.joule.2020.01.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.01.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527264500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Costa, CM; Barbosa, JC; Gonçalves, R; Castro, H; Del Campo, FJ; Lanceros-Méndez, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Costa, C. M.; Barbosa, J. C.; Goncalves, R.; Castro, H.; Del Campo, F. J.; Lanceros-Mendez, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling and environmental issues of lithium-ion batteries: Advances, challenges and opportunities", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries, LIBs are ubiquitous through mobile phones, tablets, laptop computers and many other consumer electronic devices. Their increasing demand, mainly driven by the implementation of the electric vehicles, brings several environmental issues related to the mining, extraction and purification of scarce materials such as cobalt, nickel and lithium. This work provides an overview on the relevance of recycling LIBs and their environmental impact. It also analyses the components of LIBs and evaluates their value in the world market. Although there is a strong focus on lithium, other critical metals, such as cobalt and nickel, are also addressed. Different recycling methods for the different battery components are reported together with the main achievements. The advantages and disadvantages of the different used methods are discussed, and their environmental issues are considered. Finally, the main environmental issues associated with the production, use and end of life of LIBs for electric vehicles are described.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 37, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 433, "End Page": 465, "Article Number": null, "DOI": "10.1016/j.ensm.2021.02.032", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2021.02.032", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632780200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, MG; Xu, C; Yan, H; Fan, GH; Nakata, T; Lao, CS; Chen, RS; Kamado, S; Han, EH; Lu, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, M. G.; Xu, C.; Yan, H.; Fan, G. H.; Nakata, T.; Lao, C. S.; Chen, R. S.; Kamado, S.; Han, E. H.; Lu, B. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the formation of basal texture variations based on twinning and dynamic recrystallization in AZ31 magnesium alloy during extrusion", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Commercial Mg extrusions usually develop various types of basal textures, affecting the formability and mechanical properties. The mechanisms for the formation of basal texture variations were systematically investigated for the first time based on the twinning and dynamic recrystallization (DRX) during extrusion using electron back-scatter diffraction (EBSD) characterization. The results indicate that {10 (1) over bar2} extension twins with various variants played a key role in the formation of [10 (1) over bar0] fiber texture, while twin-induced DRX mechanism associated with {10 (1) over bar1} twins made a limited contribution to overall texture evolution. The microstructure developed consecutively as a result of continuous DRX (CDRX) and discontinuous DRX (DDRX) after twinning with different nucleation of new orientations. In the unDRXed region, new DRXed grains with 30 degrees [0001] GBs preferentially nucleated via CDRX, forming preferred selection of [2 (11) over bar0] fiber orientation. Consequently, [10 (1) over bar0] fiber texture became weakened with [2 (11) over bar0] fiber component strengthening, progressively leading to the development of [10 (1) over bar0]-[2 (11) over bar0] double fiber texture. In the DRXed region, DDRX further occurred along the serrated grain boundaries and at the triple junctions of the parent grains by bulging, forming fresh DRXed grains without preferred orientation selection. Thus, the [10 (1) over bar0]-[2 (11) over bar0] double fiber texture became randomized and gradually transformed into non-fiber texture at the late stage of extrusion. Besides, typical nucleation sites for DRX and subsequent grain growth were also discussed in this study. These findings unveil that basal texture variations are attributed to the twinning and DRX mechanisms during extrusion, which leads to new insight to design new wrought Mg alloys with high performance by grain refinement and texture modification. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 447, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2018, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 53, "End Page": 71, "Article Number": null, "DOI": "10.1016/j.actamat.2018.07.014", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.07.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445318800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LY; Guo, LD; Olson, DH; Xian, SK; Zhang, ZG; Yang, QW; Wu, KY; Yang, YW; Bao, ZB; Ren, QL; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Liangying; Guo, Lidong; Olson, David H.; Xian, Shikai; Zhang, Zhiguo; Yang, Qiwei; Wu, Kaiyi; Yang, Yiwen; Bao, Zongbi; Ren, Qilong; Li, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discrimination of xylene isomers in a stacked coordination polymer", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The separation and purification of xylene isomers is an industrially important but challenging process. Developing highly efficient adsorbents is crucial for the implementation of simulated moving bed technology for industrial separation of these isomers. Herein, we report a stacked one-dimensional coordination polymer {[Mn(dhbq)(H2O)(2)], H(2)dhbq = 2,5-dihydroxy-1,4-benzoquinone} that exhibits an ideal molecular recognition and sieving of xylene isomers. Its distinct temperature-adsorbate-dependent adsorption behavior enables full separation of p-, m-, and o-xylene isomers in both vapor and liquid phases. The delicate stimuli-responsive swelling of the structure imparts this porous material with exceptionally high flexibility and stability, well-balanced adsorption capacity, high selectivity, and fast kinetics at conditions mimicking industrial settings. This study may offer an alternative approach for energy-efficient and adsorption-based industrial xylene separation and purification processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 377, "Issue": 6603, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 335, "End Page": 339, "Article Number": null, "DOI": "10.1126/science.abj7659", "DOI Link": "http://dx.doi.org/10.1126/science.abj7659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830834200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, L; Li, XD; Sun, YF; Tan, YL; Jiao, XC; Ju, HX; Qi, ZM; Zhu, JF; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Liang; Li, Xiaodong; Sun, Yongfu; Tan, Yuanlong; Jiao, Xingchen; Ju, Huanxin; Qi, Zeming; Zhu, Junfa; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared Light-Driven CO2 Overall Splitting at Room Temperature", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date, infrared (IR) light constituting almost 50% of the solar energy has never been utilized, owing to an insurmountable contradiction between IR light utilization and CO 2 photoreduction. To break through this limitation, we designed an ultrathin intermediate-band semiconductor, and hence first realized IR-driven CO2 overall splitting on a single material without using any sacrificial reductants. Taking the synthetic ultrathin cubic-WO3 layers as an example, theoretical calculations disclose that the created oxygen vacancies reaching a critical density results in an intermediate band, verified by synchrotron-radiation valence-band spectra, photoluminescence spectra, UV-vis-NIR spectra, and synchrotron-radiation IR reflectance spectra. As a result, the oxygen-deficient WO3 atomic layers display IR-driven CO2 overall splitting to CO and O-2, while their catalytic activity proceeds without deactivation even after 3 days. Also, the higher oxygen vacancy concentration favors CO2 adsorption and activation into COOH* radical, affirmed by CO2 temperature-programmed desorption spectra and in situ MR spectra, hence guaranteeing increased CO and O-2 formation rates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 482, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1004, "End Page": 1016, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.019", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hunge, YM; Yadav, AA; Khan, S; Takagi, K; Suzuki, N; Teshima, K; Terashima, C; Fujishima, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hunge, Y. M.; Yadav, A. A.; Khan, Sovann; Takagi, Kai; Suzuki, Norihiro; Teshima, Katsuya; Terashima, Chiaki; Fujishima, Akira", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic degradation of bisphenol A using titanium dioxide@nullodiamond composites under UV light illumination", "Source Title": "JOURNAL OF COLLOID AND INTERFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Different types of organic impurities such as dyes, acids, and alcohols are discharged into potable water sources. The removal of these hazardous organic pollutants from wastewater is an important task glob-ally. However, the conventional methods used to remove organic impurities suffer from low efficiency and recycling problems. Photocatalysis is a promising advanced oxidation process for the degradation of organic compounds in aqueous solution. Titanium dioxide (TiO2) is commonly used as a photocatalyst. However, the wide bandgap of TiO2 means that it is activated by ultraviolet light, which restrains its ability to harvest solar energy. In this study, a simple water-based precipitation method was used to synthesize TiO2@nullodiamond composites. The ability of the composites to degrade bisphenol A as a model organic pollutant was investigated. It was found that 10 ppm of bisphenol A was completely degraded in 100 min by the TiO2@nullodiamond photocatalyst under ultraviolet illumination. (C) 2020 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 582, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1058, "End Page": 1066, "Article Number": null, "DOI": "10.1016/j.jcis.2020.08.102", "DOI Link": "http://dx.doi.org/10.1016/j.jcis.2020.08.102", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591521100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghanadpour, M; Carosio, F; Larsson, PT; Wågberg, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghanadpour, Maryam; Carosio, Federico; Larsson, Per Tomas; Wagberg, Lars", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorylated Cellulose nullofibrils: A Renewable nullomaterial for the Preparation of Intrinsically Flame-Retardant Materials", "Source Title": "BIOMACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cellulose from wood fibers can be modified for use in flame-retardant composites as an alternative to halogen-based compounds. For this purpose, sulfite dissolving pulp fibers have been chemically modified by phosphorylation, and the resulting material has been used to prepare cellulose nullofibrils (CNF) that have a width of approximately 3 nm. The phosphorylation was achieved using (NH4)(2)HPO4 in the presence of urea, and the degree of substitution by phosphorus was determined by X-ray photoelectron spectroscopy, conductometric titration, and nuclear magnetic resonullce spectroscopy. The presence of phosphate groups in the structure of CNF has been found to noticeably improve the flame retardancy of this material. The nullopaper sheets prepared from phosphorylated CNF showed self-extinguishing properties after consecutive applications of a methane flame for 3 s and did not ignite under a heat flux of 35 kW/m(2), as shown by flammability and cone calorimetry measurements, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 16, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3399, "End Page": 3410, "Article Number": null, "DOI": "10.1021/acs.biomac.5b01117", "DOI Link": "http://dx.doi.org/10.1021/acs.biomac.5b01117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362863500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mei, FF; Li, Z; Dai, K; Zhang, JF; Liang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mei, Feifei; Li, Zhen; Dai, Kai; Zhang, Jinfeng; Liang, Changhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Step-scheme porous g-C3N4/Zn0.2Cd0.8S-DETA composites for efficient and stable photocatalytic H2 production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, environmental pollution and energy crisis have become increasingly serious issues owing to the burning of fossil fuels. Among the many technologies, decomposition of water to produce hydrogen has attracted much attention because of its sustainability and non-polluting characteristic. However, highly efficient decomposition of water that is driven by visible light is still a challenge. Herein, we report the large-scale preparation of step-scheme porous graphite carbon nitride/Zn0.2Cd0.8S-diethylenetriamine (Pg-C3N4/Zn0.2Cd0.8S-DETA) composite by a facile solvothermal method. It was found by UV-vis spectroscopy that 15%Pg-C3N4/Zn0.2Cd0.8S-DETA exhibited suitable visible absorption edge and band gap for water decomposition. The hydrogen production rate of 15%Pg-C3N4/Zn0.2Cd0.8S-DETA composite was 6.69 mmol g(-1) h(-1), which was 16.73, 1.61, and 1.44 times greater than those of Pg-C3N4, CdS-DETA, and Zn0.2Cd0.8S-DETA, respectively. In addition, 15%Pg-C3N4/Zn0.2Cd0.8S-DETA composite displayed excellent photocatalytic stability, which was maintained for seven cycles of photocatalytic water splitting test. We believe that 15%Pg-C3N4/Zn0.2Cd0.8S-DETA composite can be a valuable guide for the development of solar hydrogen production applications in the near future. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 41, "End Page": 49, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63389-9", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63389-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495145800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, YJ; Lin, JY; Wan, T; Luo, YL; Ma, ZW; Zhou, YH; Tuten, BT; Zhang, M; Tao, XY; Song, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Yijiao; Lin, Jinyou; Wan, Tao; Luo, Yanlong; Ma, Zhewen; Zhou, Yonghong; Tuten, Bryan T.; Zhang, Meng; Tao, Xinyong; Song, Pingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable, Ultratough, and Intrinsically Self-Extinguishing Elastomers with Desirable Recyclability", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced elastomers are increasingly used in emerging areas, for example, flexible electronics and devices, and these real-world applications often require elastomers to be stretchable, tough and fire safe. However, to date there are few successes in achieving such a performance portfolio due to their different governing mechanisms. Herein, a stretchable, supertough, and self-extinguishing polyurethane elastomers by introducing dynamic pi-pi stacking motifs and phosphorus-containing moieties are reported. The resultant elastomer shows a large break strain of approximate to 2260% and a record-high toughness (ca. 460 MJ m(-3)), which arises from its dynamic microphase-separated microstructure resulting in increased entropic elasticity, and strain-hardening at large strains. The elastomer also exhibits a self-extinguishing ability thanks to the presence of both phosphorus-containing units and pi-pi stacking interactions. Its promising applications as a reliable yet recyclable substrate for strain sensors are demonstrated. The work will help to expedite next-generation sustainable advanced elastomers for flexible electronics and devices applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2207268, "DOI": "10.1002/advs.202207268", "DOI Link": "http://dx.doi.org/10.1002/advs.202207268", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927876300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SC; Wang, H; Kang, ZX; Jin, S; Zhang, XD; Zheng, XS; Qi, ZM; Zhu, JF; Pan, BC; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shichuan; Wang, Hui; Kang, Zhixiong; Jin, Sen; Zhang, Xiaodong; Zheng, Xusheng; Qi, Zeming; Zhu, Junfa; Pan, Bicai; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen vacancy associated single-electron transfer for photofixation of CO2 to long-chain chemicals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photofixation and utilization of CO2 via single-electron mechanism is considered to be a clean and green way to produce high-value-added commodity chemicals with long carbon chains. However, this topic has not been fully explored for the highly negative reduction potential in the formation of reactive carbonate radical. Herein, by taking Bi2O3 nullosheets as a model system, we illustrate that oxygen vacancies confined in atomic layers can lower the adsorption energy of CO2 on the reactive sites, and thus activate CO2 by single-electron transfer in mild conditions. As demonstrated, Bi2O3 nullosheets with rich oxygen vacancies show enhanced generation of center dot CO2- species during the reaction process and achieve a high conversion yield of dimethyl carbonate (DMC) with nearly 100% selectivity in the presence of methanol. This study establishes a practical way for the photofixation of CO2 to long-chain chemicals via defect engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 788, "DOI": "10.1038/s41467-019-08697-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08697-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458755400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martin, JJ; Fiore, BE; Erb, RM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martin, Joshua J.; Fiore, Brad E.; Erb, Randall M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing bioinspired composite reinforcement architectures via 3D magnetic printing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discontinuous fibre composites represent a class of materials that are strong, lightweight and have remarkable fracture toughness. These advantages partially explain the abundance and variety of discontinuous fibre composites that have evolved in the natural world. Many natural structures out-perform the conventional synthetic counterparts due, in part, to the more elaborate reinforcement architectures that occur in natural composites. Here we present an additive manufacturing approach that combines real-time colloidal assembly with existing additive manufacturing technologies to create highly programmable discontinuous fibre composites. This technology, termed as '3D magnetic printing', has enabled us to recreate complex bioinspired reinforcement architectures that deliver enhanced material performance compared with monolithic structures. Further, we demonstrate that we can now design and evolve elaborate reinforcement architectures that are not found in nature, demonstrating a high level of possible customization in discontinuous fibre composites with arbitrary geometries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86411, "DOI": "10.1038/ncomms9641", "DOI Link": "http://dx.doi.org/10.1038/ncomms9641", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364941500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YC; Chen, T; Jin, ZK; Li, MX; Zhang, DD; Duan, L; Zhao, ZG; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuncong; Chen, Tao; Jin, Zhekai; Li, Mengxue; Zhang, Dongdong; Duan, Lian; Zhao, Zhiguo; Wang, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough, stable and self-healing luminescent perovskite-polymer matrix applicable to all harsh aquatic environments", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gelatinous underwater invertebrates such as jellyfish have organs that are transparent, luminescent and self-healing, which allow the creatures to navigate, camouflage themselves and, indeed, survive in aquatic environments. Artificial luminescent materials that can mimic such functionality can be used to develop aquatic wearable/stretchable displays and water-resistant devices. Here, a luminescent composite that is simultaneously transparent, tough and can autonomously self-heal in both dry and wet conditions is reported. A tough, self-healable fluorine elastomer with dipole-dipole interactions is synthesized as the polymer matrix. It exhibits excellent compatibility with metal halide perovskite quantum dots. The composite possesses a toughness of 19 MJ m(-3), maximum strain of 1300% and capability to autonomously self-heal underwater. Notably, the material can withstand extremely harsh aqueous conditions, such as highly salty, acidic (pH = 1) and basic (pH = 13) environment for more than several months with almost no decay in mechanical performance or optical properties. Fabrication of perovskite-polymer composites that simultaneously possesses strong mechanical strength, high stretchability, high stability towards harsh aqueous environments and self-healing properties is challenging. Here, the authors report a luminescent composite that is simultaneously transparent, tough and can autonomously self-heal in both dry and wet conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1338, "DOI": "10.1038/s41467-022-29084-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29084-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000769063600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, XR; Chen, YH; Wang, ZX; Liu, H; Le, MQ; Lin, CH; Wu, G; Wang, L; Shi, XT; Jia, YG; Zhao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Xueru; Chen, Yunhua; Wang, Zhenxing; Liu, Huan; Le, Mengqi; Lin, Caihong; Wu, Gang; Wang, Lin; Shi, Xuetao; Jia, Yong-Guang; Zhao, Yanli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymerizable rotaxane hydrogels for three-dimensional printing fabrication of wearable sensors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While hydrogels find applications in wearable sensors and electronic skins, they are prone to fatigue fractures upon deformation cycling. Xiong et al. report the synthesis of conductive polymerizable rotaxane hydrogels, exhibiting large fatigue resistance, for 3D printable flexible sensors. While hydrogels enable a variety of applications in wearable sensors and electronic skins, they are susceptible to fatigue fracture during cyclic deformations owing to their inefficient fatigue resistance. Herein, acrylated beta-cyclodextrin with bile acid is self-assembled into a polymerizable pseudorotaxane via precise host-guest recognition, which is photopolymerized with acrylamide to obtain conductive polymerizable rotaxane hydrogels (PR-Gel). The topological networks of PR-Gel enable all desirable properties in this system due to the large conformational freedom of the mobile junctions, including the excellent stretchability along with superior fatigue resistance. PR-Gel based strain sensor can sensitively detect and distinguish large body motions and subtle muscle movements. The three-dimensional printing fabricated sensors of PR-Gel exhibit high resolution and altitude complexity, and real-time human electrocardiogram signals are detected with high repeating stability. PR-Gel can self-heal in air, and has highly repeatable adhesion to human skin, demonstrating its great potential in wearable sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1331, "DOI": "10.1038/s41467-023-36920-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36920-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955761600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XM; Zhuo, Y; Luo, Q; Wu, ZH; Midya, R; Wang, ZR; Song, WH; Wang, R; Upadhyay, NK; Fang, YL; Kiani, F; Rao, MY; Yang, Y; Xia, QF; Liu, Q; Liu, M; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xumeng; Zhuo, Ye; Luo, Qing; Wu, Zuheng; Midya, Rivu; Wang, Zhongrui; Song, Wenhao; Wang, Rui; Upadhyay, Navnidhi K.; Fang, Yilin; Kiani, Fatemeh; Rao, Mingyi; Yang, Yang; Xia, Qiangfei; Liu, Qi; Liu, Ming; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An artificial spiking afferent nerve based on Mott memristors for neurorobotics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neuromorphic computing based on spikes offers great potential in highly efficient computing paradigms. Recently, several hardware implementations of spiking neural networks based on traditional complementary metal-oxide semiconductor technology or memristors have been developed. However, an interface (called an afferent nerve in biology) with the environment, which converts the analog signal from sensors into spikes in spiking neural networks, is yet to be demonstrated. Here we propose and experimentally demonstrate an artificial spiking afferent nerve based on highly reliable NbOx Mott memristors for the first time. The spiking frequency of the afferent nerve is proportional to the stimuli intensity before encountering noxiously high stimuli, and then starts to reduce the spiking frequency at an inflection point. Using this afferent nerve, we further build a power-free spiking mechanoreceptor system with a passive piezoelectric device as the tactile sensor. The experimental results indicate that our afferent nerve is promising for constructing self-aware neurorobotics in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 51, "DOI": "10.1038/s41467-019-13827-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13827-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551396500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mouhat, F; Coudert, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mouhat, Felix; Coudert, Francois-Xavier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Necessary and sufficient elastic stability conditions in various crystal systems", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the Born elastic stability criteria are well known for cubic crystals, there is some confusion in the literature about the form they should take for lower-symmetry crystal classes. Here we present closed form necessary and sufficient conditions for elastic stability in all crystal classes, as a concise and pedagogical reference to stability criteria in noncubic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3238, "Times Cited, All Databases": 3319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 90, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 224104, "DOI": "10.1103/PhysRevB.90.224104", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.224104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346607200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, YX; Zheng, DB; Li, QC; Xiao, WP; Ma, TY; Fu, YL; Wu, ZX; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yuxiao; Zheng, Debo; Li, Qichang; Xiao, Weiping; Ma, Tianyi; Fu, Yunlei; Wu, Zexing; Wang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Co3O4-RuO2 Hollow Spheres with Abundant Interfaces as Advanced Trifunctional Electrocatalyst for Water-Splitting and Flexible Zn-Air Battery", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploiting efficient and stable electrocatalysts with trifunctional catalytic activity toward hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR) act has a crucial role with sustainable energy development. Therefore, this study fabricates Co3O4-RuO2 hollow spheres using a facile and eco-friendly solvothermal and low temperature oxidation procedure followed by ice water treatment (IW-Co3O4-RuO2-HS). The specific hollow nullostructure could provide sufficient active sites and channels in the electrocatalytic procedure. Then, the IW-Co3O4-RuO2-HS presents small overpotentials toward HER (40 mV@ 10 mA cm(-2)) and OER (250 mV@ 10 mA cm(-2)), and high half-wave potential for ORR (E-1/2@ 0.79 V). Remarkably, the IW-Co3O4-RuO2-HS also presents superior catalytic performances toward water-splitting and flexible rechargeable Zn-air batteries. Furthermore, the water electrolysis can be driven by sustainable energy, including solar, wind, thermal energy, and the assembled flexible rechargeable Zn-air battery. This study provides a valid path to synthesize multifunctional electrocatalysts on energy-related devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 32, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203206, "DOI": "10.1002/adfm.202203206", "DOI Link": "http://dx.doi.org/10.1002/adfm.202203206", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000823273400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, KF; Li, HB; Klimov, VI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Kaifeng; Li, Hongbo; Klimov, Victor I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tandem luminescent solar concentrators based on engineered quantum dots", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Luminescent solar concentrators (LSCs) can serve as large-area sunlight collectors for terrestrial and space-based photovoltaics. Due to their high emission efficiencies and readily tunable emission and absorption spectra, colloidal quantum dots have emerged as a new and promising type of LSC fluorophore. Spectral tunability of the quantum dots also facilitates the realization of stacked multilayered LSCs, where enhanced performance is obtained through spectral splitting of incident sunlight, as in multijunction photovoltaics. Here, we demonstrate a large-area (> 230 cm(2)) tandem LSC based on two types of nearly reabsorption-free quantum dots spectrally tuned for optimal solar-spectrum splitting. This prototype device exhibits a high optical quantum efficiency of 6.4% for sunlight illumination and solar-to-electrical power conversion efficiency of 3.1%. The efficiency gains due to the tandem architecture over single-layer devices quickly increase with increasing LSC size and can reach more than 100% in structures with window sizes of more than 2,500 cm(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 105, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-017-0070-7", "DOI Link": "http://dx.doi.org/10.1038/s41566-017-0070-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423445500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, H; Xie, GZ; Cao, Y; Zhang, LY; Yan, X; Zhang, X; Miao, SH; Tao, Y; Li, HH; Zheng, C; Huang, W; Chen, RF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Hao; Xie, Gaozhan; Cao, Yang; Zhang, Longyan; Yan, Xi; Zhang, Xiao; Miao, Shihao; Tao, Ye; Li, Huanhuan; Zheng, Chao; Huang, Wei; Chen, Runfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-demand modulating afterglow color of water-soluble polymers through phosphorescence FRET for multicolor security printing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing full-color organic ultralong room temperature phosphorescence (OURTP) materials with continuously variable afterglow emission is of considerable practical importance in diverse optoelectronic applications but remains a formidable challenge. Here, we present an effective strategy for on-demand engineering of afterglow color in water-soluble polymeric systems via efficient phosphorescence Forster resonullce energy transfer. Using a blue afterglow emitting water-soluble polymer as host and a series of fluorescent emitters with varied emissive colors as guests, afterglow emission is rationally modulated, conferring the full-color afterglow emission ranging from blue to red and even white with ultralong lifetimes up to 4.2 s and photoluminescence quantum yields of 36%.These water-soluble multicolor-emitting polymeric afterglow systems can function as OURTP security inks, and multilevel information encryption was successfully established by RGB-based multicolor security printing. These results present important guidance in developing high-performance afterglow polymers with on-demand color tuning ability for remarkable optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabk2925", "DOI": "10.1126/sciadv.abk2925", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abk2925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786201300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nakajima, Y; Shimada, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nakajima, Y.; Shimada, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrosilylation reaction of olefins: recent advances and perspectives", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This review covers the recent advances in hydrosilylation chemistry mainly published in the last decade. Hydrosilylation of olefins is an important reaction for the production of various organosilicon compounds such as industrially important silicone products. Although the utility of platinum catalysts, Speier's and Karstedt's catalysts, has been widely recognized in this field for decades, development of more efficient, selective, and cheaper catalyst systems are still desired for more economical production of organosilicon materials having superior properties. In these contexts, much progress has been made in recent years. In the platinum catalysis systems, continuous progress has been made to further improve selectivity and activity. Several non-precious metal catalysts, such as Fe and Ni catalysts, with good efficiency and selectivity have been developed. Furthermore, unique chemo-and regioselectivity have been achieved not only by precious metal catalysts but also by non-precious metal catalysts. The utility of non-transition metal catalysts including early main group metals, Lewis acidic alane, borane and phosphonium salts as well as N-heterocyclic carbenes has also been disclosed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 5, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20603, "End Page": 20616, "Article Number": null, "DOI": "10.1039/c4ra17281g", "DOI Link": "http://dx.doi.org/10.1039/c4ra17281g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350220400099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gomez-Martin, A; Reissig, F; Frankenstein, L; Heidbüchel, M; Winter, M; Placke, T; Schmuch, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gomez-Martin, Aurora; Reissig, Friederike; Frankenstein, Lars; Heidbuchel, Marcel; Winter, Martin; Placke, Tobias; Schmuch, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnesium Substitution in Ni-Rich NMC Layered Cathodes for High-Energy Lithium Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ni-rich LiNi1-x-yMnxCoyO2 (NMC) layered oxides are promising cathode materials for high-energy density lithium ion batteries but suffer from severe capacity fading upon cycling. Elemental substitution (= doping) with Mg has repeatedly attracted attention in NMC materials to overcome instability problems at reasonable cost, yet rational compositional tuning is needed to guarantee sufficient cycle life without compromising energy density on the material level. Herein, a series of Mg-substituted NMC materials with 90 mol% Ni are investigated regarding key performance metrics in NMC || graphite full-cells benchmarked against LiNi0.80Mn0.10Co0.10O2 and LiNi0.90Mn0.05Co0.05O2 synthetized using the same co-precipitation route. A linear correlation between cycle life and attainable gravimetric capacities is demonstrated, which are directly influenced by the degree of Mg substitution and the amount of Li+ cycled upon (de-)lithiation processes. A Mg content <2 mol% should be considered to take notable benefit from the increase in Ni content from 80 to 90 mol% to achieve a higher energy density. The present study highlights the importance of evaluating the true implications of elemental substitution on cell performance and is expected to be an insightful guideline for the future development of NMC-type cathode materials in particular with high Ni and low Co content.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103045, "DOI": "10.1002/aenm.202103045", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103045", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000738814800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goodpaster, JD; Bell, AT; Head-Gordon, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goodpaster, Jason D.; Bell, Alexis T.; Head-Gordon, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Possible Pathways for C-C Bond Formation during Electrochemical Reduction of CO2: New Theoretical Insights from an Improved Electrochemical Model", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have carried out a periodic Kohn-Sham density functional theory investigation of the pathways by which carbon-carbon bonds could be formed during the electrochemical reduction of CO2 on Cu(100) using a model that includes the effects of the electrochemical potential, solvent, and electrolyte. The electrochemical potential was set by relating the applied potential to the Fermi energy and then calculating the number of electrons required by the simulation cell for that specific Fermi energy. The solvent was included as a continuum dielectric, and the electrolyte was described using a linearized Poisson-Boltzmann model. The calculated potential of zero charge for a variety of surfaces agrees with experiment to within a mean average error of 0.09 V, thereby validating the assumptions of the model. Analysis of the mechanism for C-C bond formation revealed that at low-applied potential, C-C bond formation occurs through a CO dimer. However, at high applied potentials, a large activation barrier blocks this pathway; therefore, C-C bond formation occurs through reaction of adsorbed CHO and CO. Rate parameters determined from our calculations were used to simulate the kinetics of ethene formation during the electrochemical reduction of CO over a Cu(100) surface. An excellent match was observed between previously reported measurements of the partial current for ethene formation as a function of applied voltage and the variation in the partial current for C-C bond formation predicted by our microkinetic model. The electrochemical model reported here is simple, fairly easy to implement, and involves only a small increase in computational cost over calculations neglecting the effects of the electrolyte and the applied field. Therefore, it can be used to study the effects of applied potential and electrolyte composition on the energetics of surface reactions for a wide variety of electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 553, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2016, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1471, "End Page": 1477, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b00358", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b00358", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374810800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shanmugam, S; Xu, JT; Boyer, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shanmugam, Sivaprakash; Xu, Jiangtao; Boyer, Cyrille", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploiting Metalloporphyrins for Selective Living Radical Polymerization Tunable over Visible Wavelengths", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of metalloporphyrins has :been gaining popularity particularly in the area of medicine concerning sensitizers for the treatment of cancer and dermatological diseases through photodynamic therapy (PDT), and advanced materials for engineering molecular antenna for harvesting solar energy. In line With the myriad functions of metalloporphyrins, we investigated their capability for photoinduced living polymerization under visible light irradiation over a broad range of wavelengths. We discovered that zinc porphyrins.(i.e., zinc tetraphenylporphine (ZnTPP)) were able to Selectively activate photoinduced electron transfer reversible addition fragmentation chain transfer (PET-RAFT) polymerization of trithiocarbonate compounds for the polymerization of styrene, (meth)acrylates and (meth)acrylamides under a broad range of wavelengths (from 435 to 655 nm). Interestingly, other thiocarbonylthio compounds (dithiobenzoate, dithiocarbamite and xanthate) were not effectively activated in the presence of ZnTPP. This selectivity was likely attributed to a specific interaction between ZnTPP and trithiocarbonates, suggesting novel recognition at the molecular level. This interaction between the photoredox catalyst and trithiocarbonate group confers specific properties to this polymerization, such as oxygen tolerance, enabling living radical polymerization in the presence of air and also ability to manipulate the polymerization rates (k(p)(app) from 1.2-2.6 x 10(-2) min(-1)) by varying the visible wavelengths.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2015, "Volume": 137, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9174, "End Page": 9185, "Article Number": null, "DOI": "10.1021/jacs.5b05274", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b05274", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358556200046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, D; Guo, CG; Zeng, LH; Ren, XY; Shi, ZF; Wen, L; Chen, Q; Zhang, M; Li, XJ; Shan, CX; Jie, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Di; Guo, Chenguang; Zeng, Longhui; Ren, Xiaoyan; Shi, Zhifeng; Wen, Long; Chen, Qin; Zhang, Meng; Li, Xin Jian; Shan, Chong-Xin; Jie, Jiansheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-controlled van der Waals growth of wafer-scale 2D MoTe2 layers for integrated high-sensitivity broadband infrared photodetection", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Being capable of sensing broadband infrared (IR) light is vitally important for wide-ranging applications from fundamental science to industrial purposes. Two-dimensional (2D) topological semimetals are being extensively explored for broadband IR detection due to their gapless electronic structure and the linear energy dispersion relation. However, the low charge separation efficiency, high noise level, and on-chip integration difficulty of these semimetals significantly hinder their further technological applications. Here, we demonstrate a facile thermal-assisted tellurization route for the van der Waals (vdW) growth of wafer-scale phase-controlled 2D MoTe2 layers. Importantly, the type-II Weyl semimetal 1T'-MoTe2 features a unique orthorhombic lattice structure with a broken inversion symmetry, which ensures efficient carrier transportation and thus reduces the carrier recombination. This characteristic is a key merit for the well-designed 1T'-MoTe2/Si vertical Schottky junction photodetector to achieve excellent performance with an ultrabroadband detection range of up to 10.6 mu m and a large room temperature specific detectivity of over 10(8) Jones in the mid-infrared (MIR) range. Moreover, the large-area synthesis of 2D MoTe2 layers enables the demonstration of high-resolution uncooled MIR imaging capability by using an integrated device array. This work provides a new approach to assembling uncooled IR photodetectors based on 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41377-022-01047-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-01047-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906375800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HM; Wang, DY; Jin, HY; Wu, P; Wu, X; Chu, DW; Lu, Y; Yang, XF; Xu, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Huimin; Wang, Deyu; Jin, Huanyu; Wu, Pan; Wu, Xuan; Chu, Dewei; Lu, Yi; Yang, Xiaofei; Xu, Haolan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D MoN1.2-rGO Stacked Heterostructures Enabled Water State Modification for Highly Efficient Interfacial Solar Evaporation", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving interfacial solar evaporation performance is crucial for the practical application of this technology in solar-driven seawater desalination. Lowering evaporation enthalpy is one of the most promising and effective strategies to significantly improve solar evaporation rate. In this study, a new pathway to lower vaporization enthalpy by introducing heterogeneous interactions between hydrophilic hybrid materials and water molecules is developed. 2D MoN1.2 nullosheets are synthesized and integrated with rGO nullosheets to form stacked MoN1.2-rGO heterostructures with massive junction interfaces for interfacial solar evaporation. Molecular dynamics simulation confirms that atomic thick 2D MoN1.2 and rGO in the MoN1.2-rGO heterostructures simultaneously interact with water molecules, while the interactions are remarkably different. These heterogeneous interactions cause an imbalanced water state, which easily breaks the hydrogen bonds between water molecules, leading to dramatically lowered vaporization enthalpy and improved solar evaporation rate (2.6 kg m(-2) h(-1)). This study provides a promising strategy for designing 2D-2D heterostructures to regulate evaporation enthalpy to improve solar evaporate rate for clean water production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 33, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202214828", "DOI Link": "http://dx.doi.org/10.1002/adfm.202214828", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948772300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, S; Aitken, ZH; Pattamatta, S; Wu, ZX; Yu, ZG; Srolovitz, DJ; Liaw, PK; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shuai; Aitken, Zachary H.; Pattamatta, Subrahmanyam; Wu, Zhaoxuan; Yu, Zhi Gen; Srolovitz, David J.; Liaw, Peter K.; Zhang, Yong-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneously enhancing the ultimate strength and ductility of high-entropy alloys via short-range ordering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneously enhancing strength and ductility of metals and alloys has been a tremendous challenge. Here, we investigate a CoCuFeNiPd high-entropy alloy (HEA), using a combination of Monte Carlo method, molecular dynamic simulation, and density-functional theory calculation. Our results show that this HEA is energetically favorable to undergo short-range ordering (SRO), and the SRO leads to a pseudo-composite microstructure, which surprisingly enhances both the ultimate strength and ductility. The SRO-induced composite microstructure consists of three categories of clusters: face-center-cubic-preferred (FCCP) clusters, indifferent clusters, and body-center-cubic-preferred (BCCP) clusters, with the indifferent clusters playing the role of the matrix, the FCCP clusters serving as hard fillers to enhance the strength, while the BCCP clusters acting as soft fillers to increase the ductility. Our work highlights the importance of SRO in influencing the mechanical properties of HEAs and presents a fascinating route for designing HEAs to achieve superior mechanical properties. The strength-ductility trade-off has been a long-standing problem for alloy development. Here the authors present a route for designing high-entropy alloys to overcome this trade-off via short-range ordering shown by combined Monte Carlo, molecular dynamic, and density-functional theory simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4953, "DOI": "10.1038/s41467-021-25264-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25264-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686641700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kirchartz, T; Márquez, JA; Stolterfoht, M; Unold, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kirchartz, Thomas; Marquez, Jose A.; Stolterfoht, Martin; Unold, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoluminescence-Based Characterization of Halide Perovskites for Photovoltaics", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoluminescence spectroscopy is a widely applied characterization technique for semiconductor materials in general and halide perovskite solar cell materials in particular. It can give direct information on the recombination kinetics and processes as well as the internal electrochemical potential of free charge carriers in single semiconductor layers, layer stacks with transport layers, and complete solar cells. The correct evaluation and interpretation of photoluminescence requires the consideration of proper excitation conditions, calibration and application of the appropriate approximations to the rather complex theory, which includes radiative recombination, non-radiative recombination, interface recombination, charge transfer, and photon recycling. In this article, an overview is given of the theory and application to specific halide perovskite compositions, illustrating the variables that should be considered when applying photoluminescence analysis in these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 10, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1904134, "DOI": "10.1002/aenm.201904134", "DOI Link": "http://dx.doi.org/10.1002/aenm.201904134", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530496800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, LL; Wu, YL; Stoumpos, CC; Traore, B; Katan, C; Even, J; Wasielewski, MR; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.; Traore, Boubacar; Katan, Claudine; Even, Jacky; Wasielewski, Michael R.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable White-Light Emission in Single-Cation-Templated Three-Layered 2D Perovskites (CH3CH2NH3)4Pb3Br10-xClx", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) hybrid halide perovskites come as a family (B)(2)(A)(n-1)/PbnX3n+1 (B and A= cations; X= halide). These perovskites are promising semiconductors for solar cells and optoelectronic applications. Among the fascinating properties of these materials is white-light emission, which has been mostly observed in single-layered 2D lead bromide or chloride systems (n = 1), where the broad emission comes from the transient photoexcited states generated by self trapped excitons (STEs) from structural distortion. Here we report a multilayered 2D perovskite (n = 3) exhibiting a tunable white-light emission. Ethylammonium (EA(+)) can stabilize the 2D perovskite structure in EA(4)Pb(3)Br(10-x)Cl(x) (x = 0, 2, 4, 6, 8, 9.5, and 10) with EA(+) being both the A and B cations in this system. Because of the larger size of EA, these materials show a high distortion level in their inorganic structures, with EA(4)Pb(3)Cl(10) having a much larger distortion than that of EA(4)Pb(3)Br(10), which results in broadband white-light emission of EA(4)Pb(3)Cl(10) in contrast to narrow blue emission of EA(4)Pb(3)Br(10). The average lifetime of the series decreases gradually from the Cl end to the Br end, indicating that the larger distortion also prolongs the lifetime (more STE states). The band gap of EA(4)Pb(3)Br(10-x)Cl(x) ranges from 3.45 eV (x = 10) to 2.75 eV (x = 0), following Vegard's law. First-principles density functional theory calculations (DFT) show that both EA(4)Pb(3)Cl(10) and EA(4)Pb(3)Br(10) are direct band gap semiconductors. The color rendering index (CRI) of the series improves from 66 (EA(4)Pb(3)Cl(10)) to 83 (EA(4)Pb(3)Br(0.3)Cl(9.5)), displaying high tunability and versatility of the title compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2017, "Volume": 139, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11956, "End Page": 11963, "Article Number": null, "DOI": "10.1021/jacs.7b06143", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409286000048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, CX; Yu, L; Zhu, L; Collins, JL; Kim, D; Lou, YD; Xu, C; Li, M; Wei, Z; Zhang, YP; Edmonds, MT; Li, SQ; Seidel, J; Zhu, Y; Liu, JZ; Tang, WX; Fuhrer, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Changxi; Yu, Lei; Zhu, Lin; Collins, James L.; Kim, Dohyung; Lou, Yaoding; Xu, Chao; Li, Meng; Wei, Zheng; Zhang, Yupeng; Edmonds, Mark T.; Li, Shiqiang; Seidel, Jan; Zhu, Ye; Liu, Jefferson Zhe; Tang, Wen-Xin; Fuhrer, Michael S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature in-plane ferroelectricity in van der Waals In2Se3", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals (vdW) assembly of layered materials is a promising paradigm for creating electronic and optoelectronic devices with novel properties. Ferroelectricity in vdW layered materials could enable nonvolatile memory and low-power electronic and optoelectronic switches, but to date, few vdW ferroelectrics have been reported, and few in-plane vdW ferroelectrics are known. We report the discovery of in-plane ferroelectricity in a widely investigated vdW layered material,VIn2Se3. The in-plane ferroelectricity is strongly tied to the formation of one-dimensional superstructures aligning along one of the threefold rotational symmetric directions of the hexagonal lattice in the c plane. Surprisingly, the superstructures and ferroelectricity are stable to 200 degrees C in both bulk and thin exfoliated layers of In2Se3. Because of the in-plane nature of ferroelectricity, the domains exhibit a strong linear dichroism, enabling novel polarization-dependent optical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar7720", "DOI": "10.1126/sciadv.aar7720", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar7720", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schaffner, M; Rühs, PA; Coulter, F; Kilcher, S; Studart, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schaffner, Manuel; Ruhs, Patrick A.; Coulter, Fergal; Kilcher, Samuel; Studart, Andre R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of bacteria into functional complex materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite recent advances to control the spatial composition and dynamic functionalities of bacteria embedded in materials, bacterial localization into complex three-dimensional (3D) geometries remains a major challenge. We demonstrate a 3D printing approach to create bacteria-derived functional materials by combining the natural diverse metabolism of bacteria with the shape design freedom of additive manufacturing. To achieve this, we embedded bacteria in a biocompatible and functionalized 3D printing ink and printed two types of living materials capable of degrading pollutants and of producing medically relevant bacterial cellulose. With this versatile bacteria-printing platform, complexmaterials displaying spatially specific compositions, geometry, and properties not accessed by standard technologies can be assembled from bottom up for new biotechnological and biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao6804", "DOI": "10.1126/sciadv.aao6804", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao6804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418003100035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gupta, A; Briffa, SM; Swingler, S; Gibson, H; Kannappan, V; Adamus, G; Kowalczuk, M; Martin, C; Radecka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gupta, Abhishek; Briffa, Sophie M.; Swingler, Sam; Gibson, Hazel; Kannappan, Vinodh; Adamus, Grazyna; Kowalczuk, Marek; Martin, Claire; Radecka, Iza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Silver nulloparticles Using Curcumin-Cyclodextrins Loaded into Bacterial Cellulose-Based Hydrogels for Wound Dressing Applications", "Source Title": "BIOMACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chronic wounds are often recalcitrant to treatment because of high microbial bioburden and the problem of microbial resistance. Silver is a broad-spectrum natural antimicrobial agent with wide applications extending to proprietary wound dressings. Recently, silver nulloparticles have attracted attention in wound management. In the current study, the green synthesis of nulloparticles was accomplished using a natural reducing agent, curcumin, which is a natural polyphenolic compound that is wellknown as a wound-healing agent. The hydrophobicity of curcumin was overcome by its microencapsulation in cyclodextrins. This study demonstrates the production, characterization of silver nullopartides using aqueous curcumin:hydroxypropyl-beta-cydodextrin complex and loading them into bacterial cellulose hydrogel with moist wound-healing properties. These silver nulloparticle-loaded bacterial cellulose hydrogels were characterized for wound-management applications. In addition to high cytocompatibility, these novel dressings exhibited antimicrobial activity against three common wound-infecting pathogenic microbes Staphylococcus aureus, Pseudomonas aeruginosa, and Candida auris.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 21, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1802, "End Page": 1811, "Article Number": null, "DOI": "10.1021/acs.biomac.9b01724", "DOI Link": "http://dx.doi.org/10.1021/acs.biomac.9b01724", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535186300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, H; Yang, CY; Zhang, XH; Motta, A; Feng, K; Xia, Y; Shi, YQ; Wu, Z; Yang, K; Chen, JH; Liao, QG; Tang, YM; Sun, HL; Woo, HY; Fabiano, S; Facchetti, A; Guo, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Han; Yang, Chi-Yuan; Zhang, Xianhe; Motta, Alessandro; Feng, Kui; Xia, Yu; Shi, Yongqiang; Wu, Ziang; Yang, Kun; Chen, Jianhua; Liao, Qiaogan; Tang, Yumin; Sun, Huiliang; Woo, Han Young; Fabiano, Simone; Facchetti, Antonio; Guo, Xugang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition metal-catalysed molecular n-doping of organic semiconductors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron doping of organic semiconductors is typically inefficient, but here a precursor molecular dopant is used to deliver higher n-doping efficiency in a much shorter doping time. Chemical doping is a key process for investigating charge transport in organic semiconductors and improving certain (opto)electronic devices(1-9). N(electron)-doping is fundamentally more challenging than p(hole)-doping and typically achieves a very low doping efficiency (eta) of less than 10%(1,10). An efficient molecular n-dopant should simultaneously exhibit a high reducing power and air stability for broad applicability(1,5,6,9,11), which is very challenging. Here we show a general concept of catalysed n-doping of organic semiconductors using air-stable precursor-type molecular dopants. Incorporation of a transition metal (for example, Pt, Au, Pd) as vapour-deposited nulloparticles or solution-processable organometallic complexes (for example, Pd-2(dba)(3)) catalyses the reaction, as assessed by experimental and theoretical evidence, enabling greatly increased eta in a much shorter doping time and high electrical conductivities (above 100 S cm(-1); ref. (12)). This methodology has technological implications for realizing improved semiconductor devices and offers a broad exploration space of ternary systems comprising catalysts, molecular dopants and semiconductors, thus opening new opportunities in n-doping research and applications(12, 13).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2021, "Volume": 599, "Issue": 7883, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 67, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03942-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03942-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714417400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, DS; Kusada, K; Yoshioka, S; Yamamoto, T; Toriyama, T; Matsumura, S; Chen, YN; Seo, O; Kim, J; Song, C; Hiroi, S; Sakata, O; Ina, T; Kawaguchi, S; Kubota, Y; Kobayashi, H; Kitagawa, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Dongshuang; Kusada, Kohei; Yoshioka, Satoru; Yamamoto, Tomokazu; Toriyama, Takaaki; Matsumura, Syo; Chen, Yanna; Seo, Okkyun; Kim, Jaemyung; Song, Chulho; Hiroi, Satoshi; Sakata, Osami; Ina, Toshiaki; Kawaguchi, Shogo; Kubota, Yoshiki; Kobayashi, Hirokazu; Kitagawa, Hiroshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient overall water splitting in acid with anisotropic metal nullosheets", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water is the only available fossil-free source of hydrogen. Splitting water electrochemically is among the most used techniques, however, it accounts for only 4% of global hydrogen production. One of the reasons is the high cost and low performance of catalysts promoting the oxygen evolution reaction (OER). Here, we report a highly efficient catalyst in acid, that is, solid-solution RuIr nullosized-coral (RuIr-NC) consisting of 3 nm-thick sheets with only 6at.% Ir. Among OER catalysts, RuIr-NC shows the highest intrinsic activity and stability. A home-made overall water splitting cell using RuIr-NC as both electrodes can reach 10mAcm(geo)(-2) at 1.485V for 120h without noticeable degradation, which outperforms known cells. Operando spectroscopy and atomic-resolution electron microscopy indicate that the high-performance results from the ability of the preferentially exposed {0001} facets to resist the formation of dissolvable metal oxides and to transform ephemeral Ru into a long-lived catalyst. Ru is one of the most active metals for oxygen evolution reaction, but it quickly dissolves in acidic electrolyte particularly in nullosized form. Here, the authors show that coral-like solid-solution RuIr consisting of 3 nm-thick sheets with only 6 at% Ir is a long-lived catalyst with high activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1145, "DOI": "10.1038/s41467-021-20956-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-20956-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626757600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JT; Mahmood, J; Dou, YH; Dou, SX; Li, F; Dai, LM; Baek, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jiantie; Mahmood, Javeed; Dou, Yuhai; Dou, Shixue; Li, Feng; Dai, Liming; Baek, Jong-Beom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D Frameworks of C2N and C3N as New Anode Materials for Lithium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel layered 2D frameworks (C3N and C2N-450) with well-defined crystal structures are explored for use as anode materials in lithium-ion batteries (LIBs) for the first time. As anode materials for LIBs, C3N and C2N-450 exhibit unusual electrochemical characteristics. For example, C2N-450 (and C3N) display high reversible capacities of 933.2 (383.3) and 40.1 (179.5) mAh g(-1) at 0.1 and 10 C, respectively. Furthermore, C3N shows a low hypothetical voltage (approximate to 0.15 V), efficient operating voltage window with approximate to 85% of full discharge capacity secured at >0.45 V, and excellent cycling stability for more than 500 cycles. The excellent electrochemical performance (especially of C3N) can be attributed to their inherent 2D polyaniline frameworks, which provide large net positive charge densities, excellent structural stability, and enhanced electronic/ionic conductivity. Stable solid state interface films also form on the surfaces of the 2D materials during the charge/discharge process. These 2D materials with promising electrochemical performance should provide insights to guide the design and development of their analogues for future energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2017, "Volume": 29, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702007, "DOI": "10.1002/adma.201702007", "DOI Link": "http://dx.doi.org/10.1002/adma.201702007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409448300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krieg, F; Ochsenbein, ST; Yakunin, S; ten Brinck, S; Aellen, P; Suess, A; Clerc, B; Guggisberg, D; Nazarenko, O; Shynkarenko, Y; Kumar, S; Shih, CJ; Infante, I; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii; ten Brinck, Stephanie; Aellen, Philipp; Suess, Adrian; Clerc, Baptiste; Guggisberg, Dominic; Nazarenko, Olga; Shynkarenko, Yevhen; Kumar, Sudhir; Shih, Chih-Jen; Infante, Ivan; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloidal CsPbX3 (X = CI, Br, I) nullocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal lead halide perovskite nullocrystals (NCs) have recently emerged as versatile photonic sources. Their processing and optoelectronic applications are hampered by the loss of colloidal stability and structural integrity due to the facile desorption of surface capping molecules during isolation and purification. To address this issue, herein, we propose a new ligand capping strategy utilizing common and inexpensive long-chain zwitterionic molecules such as 3-(N,N-dimethyloctadecylammonio)propanesulfonate, resulting in much improved chemical durability. In particular, this class of ligands allows for the isolation of clean NCs with high photoluminescence quantum yields (PL QYs) of above 90% after four rounds of precipitation/redispersion along with much higher overall reaction yields of uniform and colloidal dispersible NCs. Densely packed films of these NCs exhibit high PL QY values and effective charge transport. Consequently, they exhibit photoconductivity and low thresholds for amplified spontaneous emission of 2 mu J cm(-2) under femtosecond optical excitation and are suited for efficient light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 753, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 641, "End Page": 646, "Article Number": null, "DOI": "10.1021/acsenergylett.8b00035", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b00035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427444300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Falin, A; Cai, QR; Santos, EJG; Scullion, D; Qian, D; Zhang, R; Yang, Z; Huang, SM; Watanabe, K; Taniguchi, T; Barnett, MR; Chen, Y; Ruoff, RS; Li, LH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Falin, Aleksey; Cai, Qiran; Santos, Elton J. G.; Scullion, Declan; Qian, Dong; Zhang, Rui; Yang, Zhi; Huang, Shaoming; Watanabe, Kenji; Taniguchi, Takashi; Barnett, Matthew R.; Chen, Ying; Ruoff, Rodney S.; Li, Lu Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties of atomically thin boron nitride and the role of interlayer interactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin boron nitride (BN) nullosheets are important two-dimensional nullomaterials with many unique properties distinct from those of graphene, but investigation into their mechanical properties remains incomplete. Here we report that high-quality single-crystalline mono-and few-layer BN nullosheets are one of the strongest electrically insulating materials. More intriguingly, few-layer BN shows mechanical behaviours quite different from those of few-layer graphene under indentation. In striking contrast to graphene, whose strength decreases by more than 30% when the number of layers increases from 1 to 8, the mechanical strength of BN nullosheets is not sensitive to increasing thickness. We attribute this difference to the distinct interlayer interactions and hence sliding tendencies in these two materials under indentation. The significantly better interlayer integrity of BN nullosheets makes them a more attractive candidate than graphene for several applications, for example, as mechanical reinforcements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 680, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15815, "DOI": "10.1038/ncomms15815", "DOI Link": "http://dx.doi.org/10.1038/ncomms15815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403876200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Cho, DW; Tsang, DCW; Cao, XD; Hou, DY; Shen, ZT; Alessi, DS; Ok, YS; Poon, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Cho, Dong-Wan; Tsang, Daniel C. W.; Cao, Xinde; Hou, Deyi; Shen, Zhengtao; Alessi, Daniel S.; Ok, Yong Sik; Poon, Chi Sun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green remediation of As and Pb contaminated soil using cement-free clay-based stabilization/solidification", "Source Title": "ENVIRONMENT INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilization/solidification (S/S) is a low-cost and high-efficiency remediation method for contaminated soils, however, conventional cement-based S/S method has environmental constraints and sustainability concerns. This study proposes a low-carbon, cement-free, clay-based approach for simultaneous S/S of As and Pb in the contaminated soil, and accordingly elucidates the chemical interactions between alkali-activated clay binders and potentially toxic elements. Quantitative X-ray diffraction and Al-27 nuclear magnetic resonullce analyses indicated that the addition of lime effectively activated the hydration of kaolinite clay, and the presence of limestone further enhanced the polymerization of hydrates. X-ray photoelectron spectroscopy showed that approximately 19% of As-[III] was oxidized to As-[V] in the alkali-activated clay system, which reduced toxicity and facilitated immobilization of As. During the cement-free S/S process, As and Pb consumed Ca(OH)(2) and precipitated as Ca-3(AsO4)(2)center dot 4H(2)O and Pb-3(NO3)(OH)(5), respectively, accounting for the low leachability of As (7.0%) and Pb (5.4%). However, the reduced amount of Ca(OH)(2) decreased the degree of hydration of clay minerals, and the pH buffering capacity of the contaminated soil hindered the pH increase. Sufficient dosage of lime was required for ensuring satisfactory solidification and contaminullt immobilization of the clay-based S/S products. The leachability of As and Pb in high-Ca S/S treated soil samples was reduced by 96.2% and 98.8%, respectively. This is the first study developing a green and cement-free S/S of As- and Pb-contaminated soil using clay minerals as an environmentally compatible binding material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 126, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 336, "End Page": 345, "Article Number": null, "DOI": "10.1016/j.envint.2019.02.057", "DOI Link": "http://dx.doi.org/10.1016/j.envint.2019.02.057", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462597500040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Kingsbury, R; Thind, AS; Shyamsunder, A; Fister, TT; Klie, RF; Persson, KA; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chang; Kingsbury, Ryan; Thind, Arashdeep Singh; Shyamsunder, Abhinulldan; Fister, Timothy T.; Klie, Robert F.; Persson, Kristin A.; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving high-performance aqueous Zn-metal batteries is a challenge. Here, authors report a eutectic electrolyte that concurrently enables selective Zn2+ intercalation at the cathode and highly reversible Zn metal plating/stripping, resulting in a benchmark high-areal capacity Zn anode-free cell. Two major challenges hinder the advance of aqueous zinc metal batteries for sustainable stationary storage: (1) achieving predominullt Zn-ion (de)intercalation at the oxide cathode by suppressing adventitious proton co-intercalation and dissolution, and (2) simultaneously overcoming Zn dendrite growth at the anode that triggers parasitic electrolyte reactions. Here, we reveal the competition between Zn(2+)vs proton intercalation chemistry of a typical oxide cathode using ex-situ/operando techniques, and alleviate side reactions by developing a cost-effective and non-flammable hybrid eutectic electrolyte. A fully hydrated Zn2+ solvation structure facilitates fast charge transfer at the solid/electrolyte interface, enabling dendrite-free Zn plating/stripping with a remarkably high average coulombic efficiency of 99.8% at commercially relevant areal capacities of 4 mAh cm(-2) and function up to 1600 h at 8 mAh cm(-2). By concurrently stabilizing Zn redox at both electrodes, we achieve a new benchmark in Zn-ion battery performance of 4 mAh cm(-2) anode-free cells that retain 85% capacity over 100 cycles at 25 degrees C. Using this eutectic-design electrolyte, Zn | |Iodine full cells are further realized with 86% capacity retention over 2500 cycles. The approach represents a new avenue for long-duration energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3067, "DOI": "10.1038/s41467-023-38460-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38460-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000996589500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XN; Cao, CS; Hung, SF; Lu, YR; Cai, WZ; Rykov, AI; Miao, S; Xi, SB; Yang, HB; Hu, ZH; Wang, JH; Zhao, JY; Alp, EE; Xu, W; Chan, TS; Chen, HM; Xiong, QH; Xiao, H; Huang, YQ; Li, J; Zhang, T; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xuning; Cao, Chang-Su; Hung, Sung-Fu; Lu, Ying-Rui; Cai, Weizheng; Rykov, Alexandre, I; Miao, Shu; Xi, Shibo; Yang, Hongbin; Hu, Zehua; Wang, Junhu; Zhao, Jiyong; Alp, Esen Ercan; Xu, Wei; Chan, Ting-Shan; Chen, Haoming; Xiong, Qihua; Xiao, Hai; Huang, Yanqiang; Li, Jun; Zhang, Tao; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lack of model single-atom catalysts (SACs) and atomic-resolution operando spectroscopic techniques greatly limits our comprehension of the nature of catalysis. Herein, based on the designed model single-Fe-atom catalysts with well-controlled microenvironments, we have explored the exact structure of catalytic centers and provided insights into a spin-crossover-involved mechanism for oxygen reduction reaction (ORR) using operando Raman, X-ray absorption spectroscopies, and the developed operando Fe-57 Mossbauer spectroscopy. In combination with theoretical studies, the N-FeN4C10 moiety is evidenced as a more active site for ORR. Moreover, the potential-relevant dynamic cycles of both geometric structure and electronic configuration of reactive single-Fe-atom moieties are evidenced via capturing the peroxido (*0(2)(-)) and hydroxyl (*OH-) intermediates under in situ ORR conditions. We anticipate that the integration of operando techniques and SACs in this work shall shed some light on the electronic-level insight into the catalytic centers and underlying reaction mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2020, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3440, "End Page": 3454, "Article Number": null, "DOI": "10.1016/j.chempr.2020.10.027", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.10.027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596158700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gibson, QD; Zhao, TQ; Daniels, LM; Walker, HC; Daou, R; Hébert, S; Zanella, M; Dyer, MS; Claridge, JB; Slater, B; Gaultois, MW; Corà, F; Alaria, J; Rosseinsky, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gibson, Quinn D.; Zhao, Tianqi; Daniels, Luke M.; Walker, Helen C.; Daou, Ramzy; Hebert, Sylvie; Zanella, Marco; Dyer, Matthew S.; Claridge, John B.; Slater, Ben; Gaultois, Michael W.; Cora, Furio; Alaria, Jonathan; Rosseinsky, Matthew J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low thermal conductivity in a modular inorganic material with bonding anisotropy and mismatch", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The thermal conductivity of crystalline materials cannot be arbitrarily low, as the intrinsic limit depends on the phonon dispersion. We used complementary strategies to suppress the contribution of the longitudinal and transverse phonons to heat transport in layered materials that contain different types of intrinsic chemical interfaces. BiOCI and Bi2O2Se encapsulate these design principles for longitudinal and transverse modes, respectively, and the bulk superlattice material Bi4O4SeCl2 combines these effects by ordering both interface types within its unit cell to reach an extremely low thermal conductivity of 0.1 watts per kelvin per meter at room temperature along its stacking direction. This value comes within a factor of four of the thermal conductivity of air. We demonstrated that chemical control of the spatial arrangement of distinct interfaces can synergically modify vibrational modes to minimize thermal conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2021, "Volume": 373, "Issue": 6558, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1017, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh1619", "DOI Link": "http://dx.doi.org/10.1126/science.abh1619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000690202600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, T; Yang, T; Ma, RJ; Zhan, LL; Luo, ZH; Zhang, GY; Li, Y; Gao, K; Xiao, YQ; Yu, JW; Zou, XH; Sun, HL; Zhang, MJ; Dela Peña, TA; Xing, ZS; Liu, H; Li, XJ; Li, G; Huang, JH; Duan, CH; Wong, KS; Lu, XH; Guo, XG; Gao, F; Chen, HZ; Huang, F; Li, YF; Li, YL; Cao, Y; Tang, B; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tao; Yang, Tao; Ma, Ruijie; Zhan, Lingling; Luo, Zhenghui; Zhang, Guangye; Li, Yuan; Gao, Ke; Xiao, Yiqun; Yu, Jianwei; Zou, Xinhui; Sun, Huiliang; Zhang, Maojie; Dela Pena, Top Archie; Xing, Zengshan; Liu, Heng; Li, Xiaojun; Li, Gang; Huang, Jianhua; Duan, Chunhui; Wong, Kam Sing; Lu, Xinhui; Guo, Xugang; Gao, Feng; Chen, Hongzheng; Huang, Fei; Li, Yongfang; Li, Yuliang; Cao, Yong; Tang, Bo; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "16% efficiency all-polymer organic solar cells enabled by a finely tuned morphology via the design of ternary blend", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A SUMMARY There is an urgent demand for all-polymer organic solar cells (AP-OSCs) to gain higher efficiency. Here, we successfully improve the performance to 16.09% by introducing a small amount of BN-T, a B <- N-type polymer acceptor, into the PM6:PY-IT blend. It has been found that BN-T makes the active layer, based on the PM6:PY-IT:BN-T ternary blend, more crystalline but meanwhile slightly reduces the phase separation, leading to enhancement of both exciton harvesting and charge transport. From a thermodynamic viewpoint, BN-T prefers to reside between PM6 and PY-IT, and the fraction of this fine-tunes the morphology. Besides, a significantly reduced nonradiative energy loss occurs in the ternary blend, along with the coexistence of energy and charge transfer between the two acceptors. The progressive performance facilitated by these improved properties demonstrates that AP-OSCs can possibly comparably efficient with those based on small molecule acceptors, further enhancing the competitiveness of this device type.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2021, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 914, "End Page": 930, "Article Number": null, "DOI": "10.1016/j.joule.2021.02.002", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.02.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642473100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, TX; Meng, FL; Cheng, Y; Dewangan, N; Ho, GW; Kawi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Tianxi; Meng, Fanlu; Cheng, Yin; Dewangan, Nikita; Ho, Ghim Wei; Kawi, Sibudjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Z-scheme transition metal bridge of Co9S8/Cd/CdS tubular heterostructure for enhanced photocatalytic hydrogen evolution", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Narrow band gap semiconductors heterojunction with superior coupling and composition matching can enhance light absorption, reduce carrier recombination and increase redox activity. Here, we report Co9S8/Cd/CdS Z-scheme type heterojunctions with hierarchical tubular heterostructure and inexpensive transition metallic electronic bridge between two distinct semiconductors by a simultaneous immobilization and in-situ reduction strategy. The designed heterostructure greatly promotes the redox activity owing to high-density catalytic sites, excellent visible light capture by small band gap Co9S8/CdS and hollow framework in conjunction with fast charge separation and smooth transfer through intermediary conductive Cd. The optimized photocatalyst exhibits a hydrogen generation rate up to 10.42 mu mol h(-1) without obvious drop in performance over multiple cycles. The structural design, matching tandem constituent and continuous phase mediator are the pivotal factors to engender an efficient solid-state Z-scheme photocatalysis. The facile synthetic approach and noble metal free tandem structure of this work provide alternative avenues for the development of heterojunction photocatalysts for efficient solar-to-chemical conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2021, "Volume": 286, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119853, "DOI": "10.1016/j.apcatb.2020.119853", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2020.119853", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621624500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chai, SM; Chen, XW; Zhang, XR; Fang, YX; Sprick, RS; Chen, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chai, Shuming; Chen, Xiaowen; Zhang, Xirui; Fang, Yuanxing; Sprick, Reiner Sebastian; Chen, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of covalent organic frameworks for efficient photocatalytic hydrogen peroxide production", "Source Title": "ENVIRONMENTAL SCIENCE-nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is an important chemical for environmental applications and also used in large-scale industrial processes. Recent studies have demonstrated photocatalytic production of H2O2, but the observed production rates are low, making the materials unpractical for applications at scale. Herein, covalent organic frameworks (COFs) have been studied as photocatalysts for H2O2 production. Two related COFs show markedly different performances, which can be explained by the presence of donor-acceptor configurations in the backbone. N-0-COF has increased charge-separation efficiencies and a better band alignment compared to its nitrogen containing analogue N-3-COF. The result is that N-0-COF has a H2O2 production rate of 15.7 mu mol h(-1) for 10 mg, which is ten times higher compared to N-3-COF. In this study, both experimental and theoretical studies have been used to understand the improved performance. This study reveals the importance of the backbone design of metal-free materials for advanced photocatalytic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2022, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2464, "End Page": 2469, "Article Number": null, "DOI": "10.1039/d2en00135g", "DOI Link": "http://dx.doi.org/10.1039/d2en00135g", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Environmental Sciences & Ecology; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000807032400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, TZ; Yang, G; Rajput, NN; Self, J; Park, SW; nullda, J; Persson, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Tingzheng; Yang, Guang; Rajput, Nav Nidhi; Self, Julian; Park, Sang-Won; nullda, Jagjit; Persson, Kristin A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The influence of FEC on the solvation structure and reduction reaction of LiPF6/EC electrolytes and its implication for solid electrolyte interphase formation", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluoroethylene carbonate (FEC) has been proposed as an effective electrolyte additive that enhances the stability and elasticity of the solid electrolyte interphase (SEI) of emerging Si and Li metal anodes. However, uncertainties still remain on the exact mechanism through which FEC alters the electrolyte decomposition and SEI formation process. Herein, the influence of FEC on LiPF6/ethylene carbonate (EC) electrolytes for Si anodes is investigated through classical molecular dynamics, Fourier-transform infrared spectroscopy, and quantum chemical calculations. Albeit a minority species, FEC is found to significantly modify the solvation structure and reduction behavior of the electrolyte while being innocuous to transport properties. Even with limited 10% of FEC, the Li+ solvation structure exhibits a notably higher contact-ion pair ratio (14%) than the parent EC electrolyte (6%). Moreover, FEC itself, as a new fluorine-containing species, appears in 1/5 of the Li+ solvation shells. The Li+-coordinated FEC is found to reduce prior to EC and uncoordinated FEC which will passivate the anode surface at an early onset (ca. 0.3 V higher than EC) by forming LiF. The critical role of FEC in tailoring the Li+ solvation structure and as-formed protective SEI composition provides mechanistic insight that will aid in the rational design of novel electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 64, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103881, "DOI": "10.1016/j.nulloen.2019.103881", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2019.103881", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487931500063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, T; Wei, CW; Simpson, RE; Zhang, L; Cryan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Tun; Wei, Chen-wei; Simpson, Robert E.; Zhang, Lei; Cryan, Martin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Polarization-Independent Perfect Absorber Using a Phase-Change Metamaterial at Visible Frequencies", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a broadband polarization-independent perfect absorber with wide-angle near unity absorbance in the visible regime. Our structure is composed of an array of thin Au squares separated from a continuous Au film by a phase change material (Ge2Sb2Te5) layer. It shows that the near perfect absorbance is flat and broad over a wide-angle incidence up to 80 degrees for either transverse electric or magnetic polarization due to a high imaginary part of the dielectric permittivity of Ge2Sb2Te5. The electric field, magnetic field and current distributions in the absorber are investigated to explain the physical origin of the absorbance. Moreover, we carried out numerical simulations to investigate the temporal variation of temperature in the Ge2Sb2Te5 layer and to show that the temperature of amorphous Ge2Sb2Te5 can be raised from room temperature to > 433 K (amorphous-to-crystalline phase transition temperature) in just 0.37 ns with a low light intensity of 95 nW/mu m(2), owing to the enhanced broadband light absorbance through strong plasmonic resonullces in the absorber. The proposed phase-change metamaterial provides a simple way to realize a broadband perfect absorber in the visible and near-infrared (NIR) regions and is important for a number of applications including thermally controlled photonic devices, solar energy conversion and optical data storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3955, "DOI": "10.1038/srep03955", "DOI Link": "http://dx.doi.org/10.1038/srep03955", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331217400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singer, A; Zhang, M; Hy, S; Cela, D; Fang, C; Wynn, TA; Qiu, B; Xia, Y; Liu, Z; Ulvestad, A; Hua, N; Wingert, J; Liu, H; Sprung, M; Zozulya, AV; Maxey, E; Harder, R; Meng, YS; Shpyrko, OG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singer, A.; Zhang, M.; Hy, S.; Cela, D.; Fang, C.; Wynn, T. A.; Qiu, B.; Xia, Y.; Liu, Z.; Ulvestad, A.; Hua, N.; Wingert, J.; Liu, H.; Sprung, M.; Zozulya, A. V.; Maxey, E.; Harder, R.; Meng, Y. S.; Shpyrko, O. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-rich layered oxides (LRLO) are among the leading candidates for the next-generation cathode material for energy storage, delivering 50% excess capacity over commercially used compounds. Despite excellent prospects, voltage fade has prevented effective use of the excess capacity, and a major challenge has been a lack of understanding of the mechanisms underpinning the voltage fade. Here, using operando three-dimensional Bragg coherent diffractive imaging, we directly observe the nucleation of a mobile dislocation network in LRLO nulloparticles. The dislocations form more readily in LRLO as compared with a classical layered oxide, suggesting a link between the defects and voltage fade. We show microscopically how the formation of partial dislocations contributes to the voltage fade. The insights allow us to design and demonstrate an effective method to recover the original high-voltage functionality. Our findings reveal that the voltage fade in LRLO is reversible and call for new paradigms for improved design of oxygen-redox active materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 641, "End Page": 647, "Article Number": null, "DOI": "10.1038/s41560-018-0184-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0184-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441098100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, MJ; Zhang, LJ; Liu, X; Zhou, YN; Zhang, MY; Wang, YJ; Yang, L; Wei, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Mengjuan; Zhang, Lijuan; Liu, Xu; Zhou, Yaning; Zhang, Maoyi; Wang, Yangjian; Yang, Lu; Wei, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wide linear range and highly sensitive flexible pressure sensor based on multistage sensing process for health monitoring and human-machine interfaces", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible pressure sensors have promising applications in wearable electronic devices. However, fabricating flexible pressure sensors with wide linear range and high sensitivity remain a great challenge. Herein, a micro-nullo hybrid conductive elastomer film based on carbon materials with arched micro-patterns array on surface (P-HCF) is developed to show expected sensing properties through a sustainable route. The 1D carbon fibers (CFs) and 0D carbon nulloparticles (CNPs) were incorporated into polydimethylsiloxane (PDMS) matrix to construct a 3D conductive network consisting of physical contact and tunneling effect among carbon materials to improve the sensing range and sensitivity. The arched micro-patterns of the P-HCF, which is designed mimicking the human fingerprints, influences the pressure distribution inside the material, giving rise to a linear sensitivity over the whole sensing range. Finite element analysis (FEA) method is investigated to simulate and analyze the compression process. The P-HCF sensor exhibits both a high sensitivity of 26.6 kPa(-1) and an exceptionally wide linear range of 20 Pa - 600 kPa. The devices were demonstrated in monitoring artery pulses, assisting in diagnosing Parkinson?s disease, and analyzing gait for healthcare. Furthermore, the sensors are integrated into complex devices to realize pressure distribution detection, controlling manipulator, and operating PC games. The attainment of excellent pressure sensing performance of the P-HCF, potentially initiates vast applications in health monitoring and human-machine interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2021, "Volume": 412, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 128649, "DOI": "10.1016/j.cej.2021.128649", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.128649", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000638221300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lebrun, R; Ross, A; Bender, SA; Qaiumzadeh, A; Baldrati, L; Cramer, J; Brataas, A; Duine, RA; Kläui, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lebrun, R.; Ross, A.; Bender, S. A.; Qaiumzadeh, A.; Baldrati, L.; Cramer, J.; Brataas, A.; Duine, R. A.; Klaeui, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable long-distance spin transport in a crystalline antiferromagnetic iron oxide", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spintronics relies on the transport of spins, the intrinsic angular momentum of electrons, as an alternative to the transport of electron charge as in conventional electronics. The long-term goal of spintronics research is to develop spin-based, low-dissipation computing-technology devices. Recently, long-distance transport of a spin current was demonstrated across ferromagnetic insulators(1). However, antiferromagnetically ordered materials, the most common class of magnetic materials, have several crucial advantages over ferromagnetic systems for spintronics applications(2): antiferromagnets have no net magnetic moment, making them stable and impervious to external fields, and can be operated at terahertz-scale frequencies(3). Although the properties of antiferromagnets are desirable for spin transport(4-7), indirect observations of such transport indicate that spin transmission through antiferromagnets is limited to only a few nullometres(8-10). Here we demonstrate long-distance propagation of spin currents through a single crystal of the antiferromagnetic insulator haematite (alpha-Fe2O3)(11), the most common antiferromagnetic iron oxide, by exploiting the spin Hall effect for spin injection. We control the flow of spin current across a haematite-platinum interface-at which spins accumulate, generating the spin current-by tuning the antiferromagnetic resonullce frequency using an external magnetic field(12). We find that this simple antiferromagnetic insulator conveys spin information parallel to the antiferromagnetic Neel order over distances of more than tens of micrometres. This mechanism transports spins as efficiently as the most promising complex ferromagnets(1). Our results pave the way to electrically tunable, ultrafast, low-power, antiferromagnetic-insulator-based spin-logic devices(6,13) that operate without magnetic fields at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 441, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2018, "Volume": 561, "Issue": 7722, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0490-7", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0490-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444437900039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khayum, MA; Ghosh, M; Vijayakumar, V; Halder, A; Nurhuda, M; Kumar, S; Addicoat, M; Kurungot, S; Banerjee, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khayum, Abdul M.; Ghosh, Meena; Vijayakumar, Vidyanulld; Halder, Arjun; Nurhuda, Maryam; Kumar, Sushil; Addicoat, Matthew; Kurungot, Sreekumar; Banerjee, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc ion interactions in a two-dimensional covalent organic framework based aqueous zinc ion battery", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The two-dimensional structural features of covalent organic frameworks (COFs) can promote the electrochemical storage of cations like H+, Li+, and Na+ through both faradaic and non-faradaic processes. However, the electrochemical storage of cations like Zn2+ ion is still unexplored although it bears a promising divalent charge. Herein, for the first time, we have utilized hydroquinone linked beta-ketoenamine COF acting as a Zn2+ anchor in an aqueous rechargeable zinc ion battery. The charge-storage mechanism comprises of an efficient reversible interlayer interaction of Zn2+ ions with the functional moieties in the adjacent layers of COF (-182.0 kcal mol(-1)). Notably, due to the well-defined nullopores and structural organization, a constructed full cell, displays a discharge capacity as high as 276 mA h g(-1) at a current rate of 125 mA g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2019, "Volume": 10, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8889, "End Page": 8894, "Article Number": null, "DOI": "10.1039/c9sc03052b", "DOI Link": "http://dx.doi.org/10.1039/c9sc03052b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488472900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, G; Shan, Y; Hu, YY; Xu, XY; Long, LY; Zhang, JL; Dai, J; Guo, JH; Shen, JC; Li, S; Liu, LZ; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Gang; Shan, Yun; Hu, Youyou; Xu, Xiaoyong; Long, Liyuan; Zhang, Jinlei; Dai, Jun; Guo, Junhong; Shen, Jiancang; Li, Shuang; Liu, Lizhe; Wu, Xinglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Half-metallic carbon nitride nullosheets with micro grid mode resonullce structure for efficient photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic hydrogen evolution from water has triggered an intensive search for metal-free semiconducting photocatalysts. However, traditional semiconducting materials suffer from limited hydrogen evolution efficiency owing to low intrinsic electron transfer, rapid recombination of photogenerated carriers, and lack of artificial microstructure. Herein, we report a metal-free half-metallic carbon nitride for highly efficient photocatalytic hydrogen evolution. The introduced half-metallic features not only effectively facilitate carrier transfer but also provide more active sites for hydrogen evolution reaction. The nullosheets incorporated into a micro grid mode resonullce structure via in situ pyrolysis of ionic liquid, which show further enhanced photoelectronic coupling and entire solar energy exploitation, boosts the hydrogen evolution rate reach up to 1009 mu mol g(-1) h(-1). Our findings propose a strategy for micro-structural regulations of half-metallic carbon nitride material, and meanwhile the fundamentals provide inspirations for the steering of electron transfer and solar energy absorption in electrocatalysis, photoelectrocatalysis, and photovoltaic cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3366, "DOI": "10.1038/s41467-018-05590-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05590-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442376200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Campos, A; Troc, N; Cottancin, E; Pellarin, M; Weissker, HC; Lermé, J; Kociak, M; Hillenkamp, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Campos, Alfredo; Troc, Nicolas; Cottancin, Emmanuel; Pellarin, Michel; Weissker, Hans-Christian; Lerme, Jean; Kociak, Mathieu; Hillenkamp, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic quantum size effects in silver nulloparticles are dominated by interfaces and local environments", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The physical properties of metals change when their dimensions are reduced to the nullo-scale and new phenomena such as the localized surface-plasmon resonullce (LSPR) appear. This collective electronic excitation can be tuned over a large spectral range by adapting the material, size and shape. The existing literature is as rich as it is controversial-for example, size-dependent spectral shifts of the LSPR in small metal nulloparticles, induced by quantum effects, are reported to the red, to the blue or entirely absent. Here we report how complementary experiments on size-selected small silver nulloparticles embedded in silica can yield inconsistent results on the same system: whereas optical absorption shows no size effect in the range between only a few atoms and similar to 10 nm, a clear spectral shift is observed in single-particle electron spectroscopy. Our quantitative interpretation, based on a mixed classical/quantum model, resolves the apparent contradictions, not only within our experimental data, but also in the literature. Our comprehensive model describes how the local environment is the crucial parameter controlling the manifestation or absence of quantum size effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 275, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-018-0345-z", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0345-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460166500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, L; Zhang, Y; Zhou, S; Chaturvedi, A; Morris, SA; Liu, FC; Chang, L; Ichinose, D; Funakubo, H; Hu, WJ; Wu, T; Liu, Z; Dong, S; Wang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Lu; Zhang, Yang; Zhou, Shuang; Chaturvedi, Apoorva; Morris, Samuel A.; Liu, Fucai; Chang, Lei; Ichinose, Daichi; Funakubo, Hiroshi; Hu, Weijin; Wu, Tom; Liu, Zheng; Dong, Shuai; Wang, Junling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of giant negative piezoelectricity in a layered van der Waals ferroelectric", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent research on piezoelectric materials is predominulltly devoted to enhancing the piezoelectric coefficient, but overlooks its sign, largely because almost all of them exhibit positive longitudinal piezoelectricity. The only experimentally known exception is ferroelectric polymer poly(vinylidene fluoride) and its copolymers, which condense via weak van der Waals (vdW) interaction and show negative piezoelectricity. Here we report quantitative determination of giant intrinsic negative longitudinal piezoelectricity and electrostriction in another class of vdW solids-two-dimensional (2D) layered ferroelectric CuInP2S6. With the help of single crystal x-ray crystallography and density-functional theory calculations, we unravel the atomistic origin of negative piezoelectricity in this system, which arises from the large displacive instability of Cu ions coupled with its reduced lattice dimensionality. Furthermore, the sizable piezoelectric response and negligible substrate clamping effect of the 2D vdW piezoelectric materials warrant their great potential in nulloscale, flexible electromechanical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav3780", "DOI": "10.1126/sciadv.aav3780", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav3780", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466398400050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, F; Liu, WB; Ke, SW; Kurmoo, M; Zuo, JL; Zhang, QC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fei; Liu, Wenbo; Ke, Si-Wen; Kurmoo, Mohamedally; Zuo, Jing-Lin; Zhang, Qichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochromic two-dimensional covalent organic framework with a reversible dark-to-transparent switch", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochromic (EC) materials with a dark-to-transmissive switch have great applications in optical communications, infrared wavelength detectors for spacecraft, and infrared camouflage coatings. However, such electroactive materials with high stability and cyclability are rare. Considering the advantages of the donor-acceptor approach (wide-range tuneable band position) and porous two-dimensional (2D) covalent organic framework (COF, well-ordered crystalline framework with stable structure and high surface area), in this work we constructed an extended delocalised pi-electron layered dark purple EC-COF-1 by reacting the donor N,N,N',N'-tetrakis(p-aminophenyl)-p-benzenediamine (TPBD) with the acceptor 2,1,3-benzothiadiazole-4,7-dicarboxaldehyde (BTDD). A sandwiched device made of EC-COF-1 exhibits the two-band bleaching (370 nm and 574 nm) in the visible region and becomes transparent under the applied potential with an induced absorption centring at 1400 nm. This discovery of a stable dark-to-transmissive switch in COF might open another door for their application in many EC devices for various purposes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5534, "DOI": "10.1038/s41467-020-19315-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19315-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617729600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, Y; Tian, ZH; Heil, T; Meng, AY; Cheng, B; Cao, SW; Yu, JG; Antonietti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Yang; Tian, Zhihong; Heil, Tobias; Meng, Aiyun; Cheng, Bei; Cao, Shaowen; Yu, Jiaguo; Antonietti, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Selective CO2 Capture and Its Direct Photochemical Conversion on Ordered 2D/1D Heterojunctions", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymeric carbon nitrides (CNs) are regarded as the most sustainable materials for solar energy conversion via photocatalytic processes. However, the first-generation CNs suffered from imperfect charge separation and insufficient CO2 adsorption. Herein, the construction of a heterojunction material involving highly crystalline CN-nullorods with ordered alignment on graphene is delineated, which improves light harvesting, CO2 capture, and interface charge transfer. The graphene-supported 1 D nullo-arrays of crystalline CNs show a comparably high selectivity of CO2/N-2 up to 44, with an isosteric heat of adsorption of 55.2 kJ/mol for CO2. The heterojunction material also drives the simple and efficient CO2 photoreduction in the gas phase, without the addition of any cocatalyst or sacrificial agent, even at the more relevant case of low concentrations of CO2. These findings provide a robust way for tailoring the performance of CN materials, with the aim of a practicable technological application for CO2 capture and photoreduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2019, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2792, "End Page": 2805, "Article Number": null, "DOI": "10.1016/j.joule.2019.08.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.08.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497987900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, Y; Wilbraham, L; Slater, BJ; Zwijnenburg, MA; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yang; Wilbraham, Liam; Slater, Benjamin J.; Zwijnenburg, Martijn A.; Sprick, Reiner Sebastian; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Discovery of Organic Polymer Photocatalysts for Hydrogen Evolution from Water through the Integration of Experiment and Theory", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymers are an emerging class of photocatalysts for hydrogen production where the large breadth of potential synthetic diversity presents both an opportunity and a challenge. Here, we integrate robotic experimentation with high-throughput computation to navigate the available structure-property space. A total of 6354 co-polymers was considered computationally, followed by the synthesis and photocatalytic characterization of a sub-library of more than 170 co-polymers. This led to the discovery of new polymers with sacrificial hydrogen evolution rates (HERs) of more than 6 mmol g(-1) h(-1). The variation in HER across the library does not correlate strongly with any single physical property, but a machine-learning model involving four separate properties can successfully describe up to 68% of the variation in the HER data between the different polymers. The four variables used in the model were the predicted electron affinity, the predicted ionization potential, the optical gap, and the dispersibility of the polymer particles in solution, as measured by optical transmittance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2019, "Volume": 141, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9063, "End Page": 9071, "Article Number": null, "DOI": "10.1021/jacs.9b03591", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b03591", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470939200053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Sarte, PM; Kenney, EM; Graf, MJ; Teicher, SML; Seshadri, R; Wilson, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Sarte, Paul M.; Kenney, Eric M.; Graf, Michael J.; Teicher, Samuel M. L.; Seshadri, Ram; Wilson, Stephen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity in the Z2 kagome metal KV3Sb5", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we report the observation of bulk superconductivity in single crystals of the two-dimensional kagome metal KV3Sb5. Magnetic susceptibility, resistivity, and heat capacity measurements reveal superconductivity below T-c = 0.93 K, and density functional theory (DFT) calculations further characterize the normal state as a Z(2) topological metal. Our results demonstrate that the recent observation of superconductivity within the related kagome metal CsV3Sb5 is likely a common feature across the AV(3)Sb(5) (A: K, Rb, Cs) family of compounds and establishes them as a rich arena for studying the interplay between bulk superconductivity, topological surface states, and likely electronic density wave order in an exfoliable kagome lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2021, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34801, "DOI": "10.1103/PhysRevMaterials.5.034801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.5.034801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627741900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ishii, A; Miyasaka, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ishii, A.; Miyasaka, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct detection of circular polarized light in helical 1D perovskite-based photodiode", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detection of circularly polarized light (CPL) has a high potential for development of various optical technologies. Conventional photodetectors require optical polarizers on the device to detect polarized light, and this causes substantial losses of sensitivity and resolution in light detection. Here, we report direct CPL detection by a photodiode using a helical one-dimensional (1D) structure of lead halide perovskites composed of naphthylethylamine-based chiral organic cations. The 1D structure with face-sharing (Pbl(6))(4-) octahedral chains whose helicity is largely affected by chiral cations shows intense circular dichroism (CD) signals over 3000 mdeg at 395 nm with the highly anisotropy factor (g(CD)) of 0.04. This high CD enables photocurrent detection with effective discrimination between left-handed and right-handed CPLs. The CPL detector based on this 1D perovskite achieved the highest polarization discrimination ratio of 25.4, which largely surpasses the direct detecting CPL devices (<4) using chiral plasmonic metamaterials and organic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 6, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabd3274", "DOI": "10.1126/sciadv.abd3274", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abd3274", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592174000040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, YK; Wu, BH; Sun, ST; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yingkun; Wu, Baohu; Sun, Shengtong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous spinning of robust, self-healable, and crack-resistant hydrogel microfibers enabled by hydrogen bond nulloconfinement", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Robust damage-tolerant hydrogel fibers with high strength, crack resistance, and self-healing properties are indispensable for their long-term uses in soft machines and robots as load-bearing and actuating elements. However, current hydrogel fibers with inherent homogeneous structure are generally vulnerable to defects and cracks and thus local mechanical failure readily occurs across fiber normal. Here, inspired by spider spinning, we introduce a facile, energy-efficient aqueous pultrusion spinning process to continuously produce stiff yet extensible hydrogel microfibers at ambient conditions. The resulting microfibers are not only crack-insensitive but also rapidly heal the cracks in 30s by moisture, owing to their structural nulloconfinement with hydrogen bond clusters embedded in an ionically complexed hygroscopic matrix. Moreover, the nulloconfined structure is highly energy-dissipating, moisture-sensitive but stable in water, leading to excellent damping and supercontraction properties. This work creates opportunities for the sustainable spinning of robust hydrogel-based fibrous materials towards diverse intelligent applications. Hydrogels with homogenous structure are vulnerable to defects and cracks, and local mechanical failure occurs consequently. Here, the authors develop a spinning process to produce robust hydrogel microfibers with both crack insensitivity and self-healability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1370, "DOI": "10.1038/s41467-023-37036-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37036-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001029839500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seyler, KL; Zhong, D; Huang, B; Linpeng, XY; Wilson, NP; Taniguchi, T; Watanabe, K; Yao, W; Xiao, D; McGuire, MA; Fu, KMC; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seyler, Kyle L.; Zhong, Ding; Huang, Bevin; Linpeng, Xiayu; Wilson, Nathan P.; Taniguchi, Takashi; Watanabe, Kenji; Yao, Wang; Xiao, Di; McGuire, Michael A.; Fu, Kai-Mei C.; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valley Manipulation by Optically Tuning the Magnetic Proximity Effect in WSe2/CrI3 Heterostructures", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer valley semiconductors, such as tungsten diselenide (WSe2), possess valley pseudospin degrees of freedom that are optically addressable but degenerate in energy. Lifting the energy degeneracy by breaking time-reversal symmetry is vital for valley manipulation. This has been realized by directly applying magnetic fields or via pseudomagnetic fields generated by intense circularly polarized optical pulses. However, sweeping large magnetic fields is impractical for devices, and the pseudomagnetic fields are only effective in the presence of ultrafast laser pulses. The recent rise of two-dimensional (2D) magnets unlocks new approaches to controlling valley physics via van der Waals heterostructure engineering. Here, we demonstrate the wide continuous tuning of the valley polarization and valley Zeeman splitting with small changes in the laser-excitation power in heterostructures formed by monolayer WSe2 and 2D magnetic chromium triiodide (CrI3). The valley manipulation is realized via the optical control of the CrI3 magnetization, which tunes the magnetic exchange field over a range of 20 T. Our results reveal a convenient new path toward the optical control of valley pseudospins and van der Waals magnetic heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 358, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 18, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3823, "End Page": 3828, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b01105", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b01105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435524300072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yi, MJ; Ma, JY; Ren, Y; Wang, H; Xie, L; Zhu, ZY; Zhang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yi, Mingjie; Ma, Jiayu; Ren, Yi; Wang, Hao; Xie, Lin; Zhu, Zhenye; Zhang, Jiaheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic Liquid Meets MOF: A Facile Method to Optimize the Structure of CoSe2-NiSe2 Heterojunctions with N, P, and F Triple-Doped Carbon Using Ionic Liquid for Efficient Hydrogen Evolution and Flexible Supercapacitors", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of catalysts' spatial structure is vitally important to boost catalytic performance by exposing the active sites and increasing specific surface area. Herein, the heteroatom doping and morphology of CoNi metal-organic frameworks(MOF) are modulated by controlling the volume of ionic liquid used in synthesis and generating CoSe2-NiSe2 heterojunction structures wrapped by N, P, F tri-doped carbon(NPFC) after a selenisation process. Notably, the unique cubic porous structure of CoSe2-NiSe2/NPFC results in a specific surface five times that of the sheet-like hollow structure produced without ionic liquid. Moreover, the charge redistribution during heterojunction formation is verified in detail using synchrotron radiation. Density functional theory calculations reveal that the formation of heterojunctions and doping of heteroatoms successfully lower the Delta G(H*) and Delta G(OH*) values. Consequently, CoSe2-NiSe2/NPFC exhibits excellent activity for HER in both acidic and alkaline solutions. Meanwhile, CoSe2-NiSe2/NPFC as a cathode material exhibits excellent performance in a flexible solid-state supercapacitor, with a superior energy density of 55.7 Wh kg(-1) at an extremely high-power density of 15.9 kW kg(-1). This material design provides new ideas for not only using ionic liquids to modulate the morphology of MOFs but also deriving heterojunctions and heteroatom-doped carbon from MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206029", "DOI Link": "http://dx.doi.org/10.1002/advs.202206029", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914015200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, B; Chandrasekaran, S; Zhang, HZ; Ma, A; Kang, JZ; Zhang, L; Lu, XH; Qian, F; Zhu, C; Duoss, EB; Spadaccini, CM; Worsley, MA; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Bin; Chandrasekaran, Swetha; Zhang, Haozhe; Ma, Annie; Kang, Junzhe; Zhang, Lei; Lu, Xihong; Qian, Fang; Zhu, Cheng; Duoss, Eric B.; Spadaccini, Christopher M.; Worsley, Marcus A.; Li, Yat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D-Printed Structure Boosts the Kinetics and Intrinsic Capacitance of Pseudocapacitive Graphene Aerogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of pseudocapacitive electrodes at fast charging rates are typically limited by the slow kinetics of Faradaic reactions and sluggish ion diffusion in the bulk structure. This is particularly problematic for thick electrodes and electrodes highly loaded with active materials. Here, a surface-functionalized 3D-printed graphene aerogel (SF-3D GA) is presented that achieves not only a benchmark areal capacitance of 2195 mF cm(-2) at a high current density of 100 mA cm(-2) but also an ultrahigh intrinsic capacitance of 309.1 mu F cm(-2) even at a high mass loading of 12.8 mg cm(-2). Importantly, the kinetic analysis reveals that the capacitance of SF-3D GA electrode is primarily (93.3%) contributed from fast kinetic processes. This is because the 3D-printed electrode has an open structure that ensures excellent coverage of functional groups on carbon surface and facilitates the ion accessibility of these surface functional groups even at high current densities and large mass loading/electrode thickness. An asymmetric device assembled with SF-3D GA as anode and 3D-printed GA decorated with MnO2 as cathode achieves a remarkable energy density of 0.65 mWh cm(-2) at an ultrahigh power density of 164.5 mW cm(-2), outperforming carbon-based supercapacitors operated at the same power density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 32, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1906652, "DOI": "10.1002/adma.201906652", "DOI Link": "http://dx.doi.org/10.1002/adma.201906652", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507632100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Wang, XY; Cong, S; Chen, J; Sun, HZ; Chen, ZG; Song, G; Geng, FX; Chen, Q; Zhao, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhen; Wang, Xiaoyu; Cong, Shan; Chen, Jian; Sun, Hongzhao; Chen, Zhigang; Song, Ge; Geng, Fengxia; Chen, Qin; Zhao, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards full-colour tunability of inorganic electrochromic devices using ultracompact fabry-perot nullocavities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intercalation-based inorganic materials that change their colours upon ion insertion/extraction lay an important foundation for existing electrochromic technology. However, using only such inorganic electrochromic materials, it is very difficult to achieve the utmost goal of full-colour tunability for future electrochromic technology mainly due to the absence of structural flexibility. Herein, we demonstrate an ultracompact asymmetric Fabry-Perot (F-P) nullocavity-type electrochromic device formed by using partially reflective metal tungsten as the current collector and reflector layer simultaneously; this approach enables fairly close matching of the reflections at both interfaces of the WO3 thin layer in device form, inducing a strong interference. Such an interference-enhanced device that is optically manipulated at the nulloscale displays various structural colours before coloration and, further, can change to other colours including blue, red, and yellow by changing the optical indexes (n, k) of the tungsten oxide layer through ion insertion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 302, "DOI": "10.1038/s41467-019-14194-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14194-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511911600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, LC; Bell, AT; Weber, AZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards membrane-electrode assembly systems for CO2 reduction: a modeling study", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membrane-electrode assemblies (MEAs) are an attractive cell design for the electrochemical reduction of CO2 because they exhibit low ohmic loss and high energy efficiency. We describe here the development and application of a multiphysics model to investigate the fundamental limitations of two MEA designs: one with gaseous feeds at both the anode and cathode (full-MEA), and the other with an aqueous anode feed (KHCO3 or KOH exchange solution) and a gaseous cathode feed (exchange-MEA). The total current density for the three cases follows the order: KOH-MEA > KHCO3-MEA 4 full-MEA. This trend is established by examining the distribution of the applied voltage. We show that the main charge-carrying species are carbonate anions for an MEA that uses an anion-exchange membrane (AEM). The amount of CO2 consumed but not converted to CO decreases with increasing current densities above 100 mA cm(2) for a full-MEA, but converges to 50% for exchange-MEAs. The full-MEA becomes limited by ohmic resistance as the membrane dehydrates with increasing cell temperature, and eventually becomes limited due to water mass transport. The exchange-MEAs can maintain membrane hydration and the local ion concentration at the anode, but are limited by salt precipitation at the cathode, as well as a higher tendency to flood. Finally, we explore the effects of temperature and discuss the possibility of increasing water supply to the full-MEA to improve its performance at elevated temperatures. The MEA model and the understanding of MEA performance for the electrochemical reduction of CO2 presented in this study should help guide the design of next-generation CO2 reduction cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2019, "Volume": 12, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1950, "End Page": 1968, "Article Number": null, "DOI": "10.1039/c9ee00909d", "DOI Link": "http://dx.doi.org/10.1039/c9ee00909d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471283100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lops, C; Ancona, A; Di Cesare, K; Dumontel, B; Garino, N; Canavese, G; Hérnulldez, S; Cauda, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lops, Carmine; Ancona, Andrea; Di Cesare, Katia; Dumontel, Bianca; Garino, Nadia; Canavese, Giancarlo; Hernulldez, Simelys; Cauda, Valentina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sonophotocatalytic degradation mechanisms of Rhodamine B dye via radicals generation by micro- and nullo-particles of ZnO", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENTAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, it is proposed an environmental friendly sonophotocatalytic approach to efficiently treat polluted waters from industrial dyes exploiting ZnO micro- and nullo-materials. For the first time, we deeply investigated the generation of reactive oxygen species (ROS) under ultrasound stimulation of different ZnO structures by Electron Paramagnetic Resonullce Spectroscopy (EPR). Indeed, five zinc oxide (ZnO) micro- and nullo-structures, i.e. Desert Roses (DRs), Multipods (MPs), Microwires (MWs), nulloparticles (NPs) and nullowires (NWs), were studied for the Rhodamine B (RhB) sonodegradation under ultrasonic irradiation. The DRs microparticles demonstrated the best sonocatalytic performance (100% degradation of RhB in 180 min) and the highest OH center dot radicals generation under ultrasonic irradiation. Strikingly, the coupling of ultrasound and sun-light irradiation in a sonophotodegradation approach led to 100% degradation efficiency, i.e. color reduction, of RhB in just 10 min, revealing a great positive synergy between the photocatalytic and sonocatalytic mechanisms. The RhB sonophotocatalytic degradation was also evaluated at different initial dye concentrations and with the presence of anions in solution. It was demonstrated a good stability over repeated cycles of dye treatment, which probe the applicability of this technique with industrial effluents. In conclusion, sonophotocatalytic degradation synergizing sunlight and ultrasound in the presence of DRs microparticles shows a great potential and a starting point to investigate further the efficient treatment of organic dyes in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 436, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 243, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 629, "End Page": 640, "Article Number": null, "DOI": "10.1016/j.apcatb.2018.10.078", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2018.10.078", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453616800065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, T; Wang, J; Qiu, CT; Ling, X; Tian, BB; Chen, W; Su, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Tao; Wang, Jun; Qiu, Chuntian; Ling, Xiang; Tian, Bingbing; Chen, Wei; Su, Chenliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "B, N Codoped and Defect-Rich nullocarbon Material as a Metal-Free Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly active, inexpensive, and stable bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts to replace noble metal Pt and RuO2 catalysts remains a considerable challenge for highly demanded reversible fuel cells and metal-air batteries. Here, a simple approach for the facile construction of a defective nullocarbon material is reported with B and N dopants (B,N-carbon) as a superior bifunctional metal-free catalyst for both ORR and OER. The catalyst is prepared by pyrolyzing the composites of ethyl cellulose and high-boiling point 4-(1-naphthyl)benzeneboronic acid in NH3 atmosphere with an inexpensive Zn-based template. The obtained porous B,N-carbon with rich carbon defects exhibits excellent ORR and OER performances, including high activity and stability. In alkaline medium, B,N-carbon material shows high ORR activity with an onset potential (E-onset) reaching 0.98 V versus reversible hydrogen electrode (RHE), very close to that of Pt/C, a high electron transfer number and excellent stability. This catalyst also presents the admirable ORR activity in acidic medium with a high E-onset of 0.81 V versus RHE and a four-electron process. The OER activity of B,N-carbon is superior to that of the precious metal RuO2 and Pt/C catalysts. A Zn-air battery using B,N-carbon as the air cathode exhibits a low voltage gap between charge and discharge and long-term stability. The excellent electrocatalytic performance of this porous nullocarbon material is attributed to the combined positive effects of the abundant carbon defects and the heteroatom codopants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800036, "DOI": "10.1002/advs.201800036", "DOI Link": "http://dx.doi.org/10.1002/advs.201800036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439842100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, QX; Xu, CX; Hou, JG; Ma, WQ; Jian, TZ; Yan, SS; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Qiuxia; Xu, Caixia; Hou, Jiagang; Ma, Wenqing; Jian, Tianzhen; Yan, Shishen; Liu, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Duplex Interpenetrating-Phase FeNiZn and FeNi3 Heterostructure with Low-Gibbs Free Energy Interface Coupling for Highly Efficient Overall Water Splitting", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sluggish kinetics of both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) generate the large over-potential in water electrolysis and thus high-cost hydrogen production. Here, multidimensional nulloporous interpenetrating-phase FeNiZn alloy and FeNi3 intermetallic heterostructure is in situ constructed on NiFe foam (FeNiZn/FeNi3@NiFe) by dealloying protocol. Coupling with the eminent synergism among specific constituents and the highly efficient mass transport from integrated porous backbone, FeNiZn/ FeNi3@NiFe depicts exceptional bifunctional activities for water splitting with extremely low overpotentials toward OER and HER (eta(1000) = 367/245 mV) as well as the robust durability during the 400 h testing in alkaline solution. The as- built water electrolyzer with FeNiZn/FeNi3@NiFe as both anode and cathode exhibits record-high performances for sustainable hydrogen output in terms of much lower cell voltage of 1.759 and 1.919 V to deliver the current density of 500 and 1000 mA-cm(-2) as well long working lives. Density functional theory calculations disclose that the interface interaction between FeNiZn alloy and -FeNi3 intermetallic generates the modulated electron structure state and optimized intermediate chemisorption, thus diminishing the energy barriers for hydrogen production in water splitting. With the merits of fine performances, scalable fabrication, and low cost, FeNiZn/FeNi3@NiFe holds prospective application potential as the bifunctional electrocatalyst for water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 95, "DOI": "10.1007/s40820-023-01066-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01066-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968816500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bos, F; Wolfs, R; Ahmed, Z; Salet, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bos, Freek; Wolfs, Rob; Ahmed, Zeeshan; Salet, Theo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of concrete in construction: potentials and challenges of 3D concrete printing", "Source Title": "VIRTUAL AND PHYSICAL PROTOTYPING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing is gaining ground in the construction industry. The potential to improve on current construction methods is significant. One of such methods being explored currently, both in academia and in construction practice, is the additive manufacturing of concrete (AMoC). Albeit a steadily growing number of researchers and private enterprises active in this field, AMoC is still in its infancy. Different variants in this family of manufacturing methods are being developed and improved continuously. Fundamental scientific understanding of the relations between design, material, process, and product is being explored. The collective body of work in that area is still very limited. After sketching the potential of AMoC for construction, this paper introduces the variants of AMoC under development around the globe and goes on to describe one of these in detail, the 3D Concrete Printing (3DCP) facility of the Eindhoven University of Technology. It is compared to other AMoC methods as well as to 3D printing in general. Subsequently, the paper will address the characteristics of 3DCP product geometry and structure, and discuss issues on parameter relations and experimental research. Finally, it will present the primary obstacles that stand between the potential of 3DCP and large-scale application in practice, and discuss the expected evolution of AMoC in general.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 717, "Times Cited, All Databases": 787, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 209, "End Page": 225, "Article Number": null, "DOI": "10.1080/17452759.2016.1209867", "DOI Link": "http://dx.doi.org/10.1080/17452759.2016.1209867", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383054100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meneghini, M; De Santi, C; Abid, I; Buffolo, M; Cioni, M; Khadar, RA; Nela, L; Zagni, N; Chini, A; Medjdoub, F; Meneghesso, G; Verzellesi, G; Zanoni, E; Matioli, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meneghini, Matteo; De Santi, Carlo; Abid, Idriss; Buffolo, Matteo; Cioni, Marcello; Khadar, Riyaz Abdul; Nela, Luca; Zagni, Nicolo; Chini, Alessandro; Medjdoub, Farid; Meneghesso, Gaudenzio; Verzellesi, Giovanni; Zanoni, Enrico; Matioli, Elison", "Book Author Full Names": null, "Group Authors": null, "Article Title": "GaN-based power devices: Physics, reliability, and perspectives", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the last decade, gallium nitride (GaN) has emerged as an excellent material for the fabrication of power devices. Among the semiconductors for which power devices are already available in the market, GaN has the widest energy gap, the largest critical field, and the highest saturation velocity, thus representing an excellent material for the fabrication of high-speed/high-voltage components. The presence of spontaneous and piezoelectric polarization allows us to create a two-dimensional electron gas, with high mobility and large channel density, in the absence of any doping, thanks to the use of AlGaN/GaN heterostructures. This contributes to minimize resistive losses; at the same time, for GaN transistors, switching losses are very low, thanks to the small parasitic capacitances and switching charges. Device scaling and monolithic integration enable a high-frequency operation, with consequent advantages in terms of miniaturization. For high power/high-voltage operation, vertical device architectures are being proposed and investigated, and three-dimensional structures-fin-shaped, trench-structured, nullowire-based-are demonstrating great potential. Contrary to Si, GaN is a relatively young material: trapping and degradation processes must be understood and described in detail, with the aim of optimizing device stability and reliability. This Tutorial describes the physics, technology, and reliability of GaN-based power devices: in the first part of the article, starting from a discussion of the main properties of the material, the characteristics of lateral and vertical GaN transistors are discussed in detail to provide guidance in this complex and interesting field. The second part of the paper focuses on trapping and reliability aspects: the physical origin of traps in GaN and the main degradation mechanisms are discussed in detail. The wide set of referenced papers and the insight into the most relevant aspects gives the reader a comprehensive overview on the present and next-generation GaN electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2021, "Volume": 130, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 181101, "DOI": "10.1063/5.0061354", "DOI Link": "http://dx.doi.org/10.1063/5.0061354", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000762647900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amani, M; Tan, CL; Zhang, G; Zhao, CS; Bullock, J; Song, XH; Kim, H; Shrestha, VR; Gao, Y; Crozier, KB; Scott, M; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amani, Matin; Tan, Chaoliang; Zhang, George; Zhao, Chunsong; Bullock, James; Song, Xiaohui; Kim, Hyungjin; Shrestha, Vivek Raj; Gao, Yang; Crozier, Kenneth B.; Scott, Mary; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution-Synthesized High-Mobility Tellurium nulloflakes for Short-Wave Infrared Photodetectors", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials, particularly black phosphorus (bP), have demonstrated themselves to be excellent candidates for high-performance infrared photodetectors and transistors. However, high-quality bP can be obtained only via mechanical exfoliation from high-temperature- and high-pressure-grown bulk crystals and degrades rapidly when exposed to ambient conditions. Here, we report solution-synthesized and air-stable quasi-2D tellurium (Te) nulloflakes for short-wave infrared (SWIR) photodetectors. We perform comprehensive optical characterization via polarization-resolved transmission and reflection measurements and report the absorbance and complex refractive index of Te crystals. It is found that this material is an indirect semiconductor with a band gap of 0.31 eV. From temperature dependent electrical measurements, we confirm this band-gap value and find that 12 nm thick Te nulloflakes show high hole mobilities of 450 and 1430 cm(2) V-1 s(-1) at 300 and 77 K, respectively. Finally, we demonstrate that despite its indirect band gap, Te can be utilized for high-performance SWIR photodetectors by employing optical cavity substrates consisting of Au/Al2O3 to dramatically increase the absorption in the semiconductor. By changing the thickness of the Al2O3 cavity, the peak responsivity of Te photoconductors can be tuned from 1.4 mu m (13 A/W) to 2.4 mu m (8 A/W) with a cutoff wavelength of 3.4 fully capturing the SWIR band. An optimized room-temperature specific detectivity (D*) of 2 X 10(9) cm Hz(1/2) W-1 is obtained at a wavelength of 1.7 mu m.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 12, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7253, "End Page": 7263, "Article Number": null, "DOI": "10.1021/acsnullo.8b03424", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.8b03424", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440505000092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XR; Xu, XM; Yao, SX; Hao, C; Pan, C; Xiang, X; Tian, ZQ; Shen, PK; Shao, ZP; Jiang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoran; Xu, Xiaomin; Yao, Sixian; Hao, Chao; Pan, Can; Xiang, Xue; Tian, Zhi Qun; Shen, Pei Kang; Shao, Zongping; Jiang, San Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Electrocatalytic Activity of Single Atom Catalysts Supported on Nitrogen-Doped Carbon through N Coordination Environment Engineering", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonprecious group metal (NPGM)-based single atom catalysts (SACs) hold a great potential in electrocatalysis and dopant engineering has been extensively exploited to boost their catalytic activity, while the coordination environment of dopant, which also significantly affects the electronic structure of SACs, and consequently their electrocatalytic performance, have been largely ignored. Here, by adopting a precursor modulation strategy, the authors successfully synthesize single cobalt atom catalysts embedded in nitrogen-doped carbon, Co-N/C, with similar overall Co and N concentrations but different N types, that is, pyridinic N (N-P), graphitic N (N-G), and pyrrolic N (N-PY). Co-N/C with the Co-N-4 moieties coordinated with N-G displays far superior activity for oxygen reduction (ORR) and evolution reactions, and superior activity and stability in both zinc-air batteries and proton exchange membrane fuel cells. Density functional theory calculation indicates that coordinated N species in particular N-G functions as electron donors to the Co core of Co-N-4 active sites, leading to the downshift of d-band center of Co-N-4 and weakening the binding energies of the intermediates on Co-N-4 sites, thus, significantly promoting catalytic kinetics and thermodynamics for ORR in a full pH range condition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 18, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105329, "DOI": "10.1002/smll.202105329", "DOI Link": "http://dx.doi.org/10.1002/smll.202105329", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742021800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Wang, L; Xiao, FS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hai; Wang, Liang; Xiao, Feng-Shou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal@Zeolite Hybrid Materials for Catalysis", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fixation of metal nulloparticles into zeolite crystals has emerged as a new series of heterogeneous catalysts, giving performances that steadily outperform the generally supported catalysts in many important reactions. In this outlook, we define different noble metal-in-zeolite structures (metal@zeolite) according to the size of the nulloparticles and their relative location to the micropores. The metal species within the micropores and those larger than the micropores are denoted as encapsulated and fixed structures, respectively. The development in the strategies for the construction of metal@zeolite hybrid materials is briefly summarized in this work, where the rational preparation and improved thermal stability of the metal nullostructures are particularly mentioned. More importantly, these metal@zeolite hybrid materials as catalysts exhibit excellent shape selectivity. Finally, we review the current challenges and future perspectives for these metal@zeolite catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2020, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1685, "End Page": 1697, "Article Number": null, "DOI": "10.1021/acscentsci.0c01130", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c01130", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000586913800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SF; Li, YH; Sun, S; Liu, L; Mu, XY; Liu, SH; Jiao, ML; Chen, XZ; Chen, K; Ma, HZ; Li, T; Liu, XY; Wang, H; Zhang, JN; Yang, J; Zhang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shaofang; Li, Yonghui; Sun, Si; Liu, Ling; Mu, Xiaoyu; Liu, Shuhu; Jiao, Menglu; Chen, Xinzhu; Chen, Ke; Ma, Huizhen; Li, Tuo; Liu, Xiaoyu; Wang, Hao; Zhang, Jianning; Yang, Jiang; Zhang, Xiao-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom nullozymes catalytically surpassing naturally occurring enzymes as sustained stitching for brain trauma", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Regenerable nullozymes with high catalytic stability and sustainability are promising substitutes for naturally-occurring enzymes but are limited by insufficient and non-selective catalytic activities. Herein, we developed single-atom nullozymes of RhN4, VN4, and Fe-Cu-N-6 with catalytic activities surpassing natural enzymes. Notably, Rh/VN4 preferably forms an Rh/V-O-N-4 active center to decrease reaction energy barriers and mediates a two-sided oxygen-linked reaction path, showing 4 and 5-fold higher affinities in peroxidase-like activity than the FeN4 and natural horseradish peroxidase. Furthermore, RhN4 presents a 20-fold improved affinity in the catalase-like activity compared to the natural catalase; Fe-Cu-N-6 displays selectivity towards the superoxide dismutase-like activity; VN4 favors a 7-fold higher glutathione peroxidase-like activity than the natural glutathione peroxidase. Bioactive sutures with Rh/VN4 show recyclable catalytic features without apparent decay in 1 month and accelerate the scalp healing from brain trauma by promoting the vascular endothelial growth factor, regulating the immune cells like macrophages, and diminishing inflammation. The catalytic activity of regenerable nullozymes is currently the bottle neck for their wider employment. Here, the authors report on single-atom nullozymes of RhN4, VN4, and Fe-Cu-N-6 with higher catalytic activities than natural enzymes, and demonstrate the Rh/VN4 recyclability and scalp healing properties in bioactive sutures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4744, "DOI": "10.1038/s41467-022-32411-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32411-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000840114800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Zhang, J; Zhou, YZ; Liu, HB; Xue, QF; Li, XS; Chueh, CC; Yip, HL; Zhu, ZL; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jing; Zhang, Jie; Zhou, Yingzhi; Liu, Hongbin; Xue, Qifan; Li, Xiaosong; Chueh, Chu-Chen; Yip, Hin-Lap; Zhu, Zonglong; Jen, Alex K. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient all-inorganic perovskite solar cells with suppressed non-radiative recombination by a Lewis base", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic perovskite solar cells (PVSCs) have drawn increasing attention because of their outstanding thermal stability. However, their performance is still inferior than the typical organic-inorganic counterparts, especially for the devices with p-i-n configuration. Herein, we successfully employ a Lewis base small molecule to passivate the inorganic perovskite film, and its derived PVSCs achieved a champion efficiency of 16.1% and a certificated efficiency of 15.6% with improved photostability, representing the most efficient inverted all-inorganic PVSCs to date. Our studies reveal that the nitrile (C-N) groups on the small molecule effectively reduce the trap density of the perovskite film and thus significantly suppresses the non-radiative recombination in the derived PVSC by passivating the Pb-exposed surface, resulting in an improved open-circuit voltage from 1.10 V to 1.16 V after passivation. This work provides an insight in the design of functional interlayers for improving efficiencies and stability of all-inorganic PVSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 497, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 177, "DOI": "10.1038/s41467-019-13909-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13909-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551458600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YL; Yang, WJ; Xu, SS; Zhao, SF; Chen, GX; Weidenkaff, A; Hardacre, C; Fan, XL; Huang, J; Tu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yaolin; Yang, Wenjie; Xu, Shanshan; Zhao, Shufang; Chen, Guoxing; Weidenkaff, Anke; Hardacre, Christopher; Fan, Xiaolei; Huang, Jun; Tu, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shielding Protection by Mesoporous Catalysts for Improving Plasma-Catalytic Ambient Ammonia Synthesis", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasma catalysis is a promising technology for decentralized small-scale ammonia (NH3) synthesis under mild conditions using renewable energy, and it shows great potential as an alternative to the conventional Haber-Bosch process. To date, this emerging process still suffers from a low NH3 yield due to a lack of knowledge in the design of highly efficient catalysts and the in situ plasma-induced reverse reaction (i.e., NH3 decomposition). Here, we demonstrate that a bespoke design of supported Ni catalysts using mesoporous MCM-41 could enable efficient plasma-catalytic NH3 production at 35 degrees C and 1 bar with >5% NH3 yield at 60 kJ/L. Specifically, the Ni active sites were deliberately deposited on the external surface of MCM-41 to enhance plasma-catalyst interactions and thus NH3 production. The desorbed NH3 could then diffuse into the ordered mesopores of MCM-41 to be shielded from decomposition due to the absence of plasma discharge in the mesopores of MCM-41, that is, shielding protection, thus driving the reaction forward effectively. This promising strategy sheds light on the importance of a rational design of catalysts specifically for improving plasma-catalytic processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 JUN 22", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c01950", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c01950", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818778100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pena-Francesch, A; Jung, HH; Demirel, MC; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pena-Francesch, Abdon; Jung, Huihun; Demirel, Melik C.; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biosynthetic self-healing materials for soft machines", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing materials are indispensable for soft actuators and robots that operate in dynamic and real-world environments, as these machines are vulnerable to mechanical damage. However, current self-healing materials have shortcomings that limit their practical application, such as low healing strength (below a megapascal) and long healing times (hours). Here, we introduce high-strength synthetic proteins that self-heal micro- and macro-scale mechanical damage within a second by local heating. These materials are optimized systematically to improve their hydrogen-bonded nullostructure and network morphology, with programmable healing properties (2-23 MPa strength after 1 s of healing) that surpass by several orders of magnitude those of other natural and synthetic soft materials. Such healing performance creates new opportunities for bioinspired materials design, and addresses current limitations in self-healing materials for soft robotics and personal protective equipment. Protein-based materials for soft robotics that self-heal within a second while maintaining the high strength of the damaged area are reported.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 19, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1230, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-0736-2", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-0736-2", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552933500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Horstmann, B; Shi, JY; Amine, R; Werres, M; He, X; Jia, H; Hausen, F; Cekic-Laskovic, I; Wiemers-Meyer, S; Lopez, J; Galvez-Aranda, D; Baakes, F; Bresser, D; Su, CC; Xu, YB; Xu, W; Jakes, P; Eichel, RA; Figgemeier, E; Krewer, U; Seminario, JM; Balbuena, PB; Wang, CM; Passerini, S; Shao-Horn, Y; Winter, M; Amine, K; Kostecki, R; Latz, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Horstmann, Birger; Shi, Jiayan; Amine, Rachid; Werres, Martin; He, Xin; Jia, Hao; Hausen, Florian; Cekic-Laskovic, Isidora; Wiemers-Meyer, Simon; Lopez, Jeffrey; Galvez-Aranda, Diego; Baakes, Florian; Bresser, Dominic; Su, Chi-Cheung; Xu, Yaobin; Xu, Wu; Jakes, Peter; Eichel, Ruediger-A; Figgemeier, Egbert; Krewer, Ulrike; Seminario, Jorge M.; Balbuena, Perla B.; Wang, Chongmin; Passerini, Stefano; Shao-Horn, Yang; Winter, Martin; Amine, Khalil; Kostecki, Robert; Latz, Arnulf", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategies towards enabling lithium metal in batteries: interphases and electrodes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the continuous increase in capacity, lithium-ion intercalation batteries are approaching their performance limits. As a result, research is intensifying on next-generation battery technologies. The use of a lithium metal anode promises the highest theoretical energy density and enables use of lithium-free or novel high-energy cathodes. However, the lithium metal anode suffers from poor morphological stability and Coulombic efficiency during cycling, especially in liquid electrolytes. In contrast to solid electrolytes, liquid electrolytes have the advantage of high ionic conductivity and good wetting of the anode, despite the lithium metal volume change during cycling. Rapid capacity fade due to inhomogeneous deposition and dissolution of lithium is the main hindrance to the successful utilization of the lithium metal anode in combination with liquid electrolytes. In this perspective, we discuss how experimental and theoretical insights can provide possible pathways for reversible cycling of two-dimensional lithium metal. Therefore, we discuss improvements in the understanding of lithium metal nucleation, deposition, and stripping on the nulloscale. As the solid-electrolyte interphase (SEI) plays a key role in the lithium morphology, we discuss how the proper SEI design might allow stable cycling. We highlight recent advances in conventional and (localized) highly concentrated electrolytes in view of their respective SEIs. We also discuss artificial interphases and three-dimensional host frameworks, which show prospects of mitigating morphological instabilities and suppressing large shape change on the electrode level.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2021, "Volume": 14, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5289, "End Page": 5314, "Article Number": null, "DOI": "10.1039/d1ee00767j", "DOI Link": "http://dx.doi.org/10.1039/d1ee00767j", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678842700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feurer, T; Reinhard, P; Avancini, E; Bissig, B; Löckinger, J; Fuchs, P; Carron, R; Weiss, TP; Perrenoud, J; Stutterheim, S; Buecheler, S; Tiwari, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feurer, Thomas; Reinhard, Patrick; Avancini, Enrico; Bissig, Benjamin; Lockinger, Johannes; Fuchs, Peter; Carron, Romain; Weiss, Thomas Paul; Perrenoud, Julian; Stutterheim, Stephan; Buecheler, Stephan; Tiwari, Ayodhya N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Progress in thin film CIGS photovoltaics - Research and development, manufacturing, and applications", "Source Title": "PROGRESS IN PHOTOVOLTAICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This review summarizes the current status of Cu(In,Ga) (S,Se)(2) (CIGS) thin film solar cell technology with a focus on recent advancements and emerging concepts intended for higher efficiency and novel applications. The recent developments and trends of research in laboratories and industrial achievements communicated within the last years are reviewed, and the major developments linked to alkali post deposition treatment and composition grading in CIGS, surface passivation, buffer, and transparent contact layers are emphasized. Encouraging results have been achieved for CIGS-based tandem solar cells and for improvement in low light device performance. Challenges of technology transfer of lab's record high efficiency cells to average industrial production are obvious from the reported efficiency values. One section is dedicated to development and opportunities offered by flexible and lightweight CIGS modules. Copyright (C) 2016 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 25, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 645, "End Page": 667, "Article Number": null, "DOI": "10.1002/pip.2811", "DOI Link": "http://dx.doi.org/10.1002/pip.2811", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403783600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, NN; Han, K; Cabral, MJ; Liao, XZ; Zhang, SJ; Liao, CZ; Zhang, GZ; Chen, XY; Feng, Q; Li, JF; Wei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Nengneng; Han, Kai; Cabral, Matthew J.; Liao, Xiaozhou; Zhang, Shujun; Liao, Changzhong; Zhang, Guangzu; Chen, Xiyong; Feng, Qin; Li, Jing-Feng; Wei, Yuezhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing phase boundary in AgNbO3 antiferroelectrics: pathway simultaneously achieving high energy density and efficiency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors with high energy storage density (W-rec) and efficiency (eta) are in great demand for high/pulsed power electronic systems, but the state-of-the-art lead-free dielectric materials are facing the challenge of increasing one parameter at the cost of the other. Herein, we report that high W-rec of 6.3Jcm(-3) with eta of 90% can be simultaneously achieved by constructing a room temperature M2-M3 phase boundary in (1-x)AgNbO3-xAgTaO(3) solid solution system. The designed material exhibits high energy storage stability over a wide temperature range of 20-150 degrees C and excellent cycling reliability up to 10(6) cycles. All these merits achieved in the studied solid solution are attributed to the unique relaxor antiferroelectric features relevant to the local structure heterogeneity and antiferroelectric ordering, being confirmed by scanning transmission electron microscopy and synchrotron X-ray diffraction. This work provides a good paradigm for developing new lead-free dielectrics for high-power energy storage applications. Dielectric capacitors are widely used in electronic systems but they possess inferior energy density in comparison with other electrochemical energy storage. Here, the authors construct a diffused phase boundary to simultaneously achieve high energy storage density and efficiency in AgNbO(3)antiferroelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4824, "DOI": "10.1038/s41467-020-18665-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18665-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573753900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XL; Dai, YQ; Cai, JX; Zhong, NJ; Xiao, H; McClements, DJ; Hu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xulin; Dai, Yuqing; Cai, Jiaxin; Zhong, nulljing; Xiao, Hang; McClements, David Julian; Hu, Kun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resveratrol encapsulation in core-shell biopolymer nulloparticles: Impact on antioxidant and anticancer activities", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zein/pectin core-shell nulloparticles with average diameter of about 235 nm and polydispersity index (PDI) of 0.24 were developed to encapsulate, protect and deliver resveratrol. Biopolymer nulloparticles could be formed containing up to 10.2% (w/w) resveratrol, with a particle yield of 91.7% and a resveratrol loading efficiency of 77.9%. The nulloparticles formed were spherical and had good redispersibility in aqueous solutions. The encapsulated resveratrol had a higher in vitro antioxidant activity than free resveratrol as determined by DPPH center dot, ABTS(center dot+) scavenging ability, and iron (III) reducing power. The encapsulated resveratrol also exhibited higher antiproliferative activity when tested using human hepatocarcinoma Bel-7402 cells than free resveratrol, with IC50 values of 17.6 mu g/mL (77.2 mu M) and 25.6 mu g/mL (112.0 mu M) respectively. The colloidal form of resveratrol developed in this study may be particularly useful for application in functional foods and beverages, as well as in dietary supplements and pharmaceutical products. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 64, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 157, "End Page": 165, "Article Number": null, "DOI": "10.1016/j.foodhyd.2016.10.029", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2016.10.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390721500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XL; Lin, YX; San Martin, J; Sun, Y; Zhu, D; Yan, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xiaolin; Lin, Yixiong; San Martin, Jovan; Sun, Yue; Zhu, Dian; Yan, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead halide perovskites for photocatalytic organic synthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature is capable of storing solar energy in chemical bonds via photosynthesis through a series of C-C, C-O and C-N bond-forming reactions starting from CO2 and light. Direct capture of solar energy for organic synthesis is a promising approach. Lead (Pb)-halide perovskite solar cells reach 24.2% power conversion efficiency, rendering perovskite a unique type material for solar energy capture. We argue that photophysical properties of perovskites already proved for photovoltaics, also should be of interest in photoredox organic synthesis. Because the key aspects of these two applications are both relying on charge separation and transfer. Here we demonstrated that perovskites nullocrystals are exceptional candidates as photocatalysts for fundamental organic reactions, for example C-C, C-N and C-O bond-formations. Stability of CsPbBr3 in organic solvents and ease-of-tuning their bandedges garner perovskite a wider scope of organic substrate activations. Our low-cost, easy-to-process, highly-efficient, air-tolerant and bandedge-tunable perovskites may bring new breakthrough in organic chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2843, "DOI": "10.1038/s41467-019-10634-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10634-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473132200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, CL; Lou, Q; Zang, JH; Liu, KK; Qu, SN; Dong, L; Shan, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Cheng-Long; Lou, Qing; Zang, Jin-Hao; Liu, Kai-Kai; Qu, Song-null; Dong, Lin; Shan, Chong-Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-Infrared Chemiluminescent Carbon nullodots and Their Application in Reactive Oxygen Species Bioimaging", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reactive oxygen species (ROS) are generated in the body and related to many pathophysiological processes. Hence, detection of ROS is indispensable in understanding, diagnosis, and treatment of many diseases. Here, near-infrared (NIR) chemiluminescent (CL) carbon nullodots (CDs) are fabricated for the first time and their CL quantum yield can reach 9.98 x 10(-3) einstein mol(-1), which is the highest value ever reported for CDs until now. nullointegration of NIR CDs and peroxalate (P-CDs) through the bridging effect of amphiphilic triblock copolymer can serve as turn-on probes for the detection and imaging of hydrogen peroxide (H2O2). Considering high efficiency and large penetration depth of NIR photons, the P-CDs are employed in bioimaging H2O2 in vitro and in vivo, and the detection limit can reach 5 x 10(-9) m, among the best reported of CDs-based sensors. Moreover, imaging of inflammatory H2O2 in a mouse model of peritonitis is achieved by employing the P-CDs as sensors. The results may provide a clue for the diagnosis and treatment of inflammation or cancers employing CL CDs as sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903525, "DOI": "10.1002/advs.201903525", "DOI Link": "http://dx.doi.org/10.1002/advs.201903525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529216500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sultana, I; Ramireddy, T; Rahman, MM; Chen, Y; Glushenkov, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sultana, Irin; Ramireddy, Thrinathreddy; Rahman, Md Mokhlesur; Chen, Ying; Glushenkov, Alexey M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tin-based composite anodes for potassium-ion batteries", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical behaviour of a Sn-based anode in a potassium cell is reported for the first time. The material is active at low potentials vs. K/K+, and encouraging capacities of around 150 mA h g(-1) are recorded. Experimental evidence shows that Sn is capable of alloying/de-alloying with potassium in a reversible manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 52, "Issue": 59, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9279, "End Page": 9282, "Article Number": null, "DOI": "10.1039/c6cc03649j", "DOI Link": "http://dx.doi.org/10.1039/c6cc03649j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379899200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, YQ; Yu, K; Isakov, MS; Wu, JT; Dunn, ML; Qi, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Yiqi; Yu, Kai; Isakov, Michael S.; Wu, Jiangtao; Dunn, Martin L.; Qi, H. Jerry", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sequential Self-Folding Structures by 3D Printed Digital Shape Memory Polymers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Folding is ubiquitous in nature with examples ranging from the formation of cellular components to winged insects. It finds technological applications including packaging of solar cells and space structures, deployable biomedical devices, and self-assembling robots and airbags. Here we demonstrate sequential self-folding structures realized by thermal activation of spatially-variable patterns that are 3D printed with digital shape memory polymers, which are digital materials with different shape memory behaviors. The time-dependent behavior of each polymer allows the temporal sequencing of activation when the structure is subjected to a uniform temperature. This is demonstrated via a series of 3D printed structures that respond rapidly to a thermal stimulus, and self-fold to specified shapes in controlled shape changing sequences. Measurements of the spatial and temporal nature of self-folding structures are in good agreement with the companion finite element simulations. A simplified reduced-order model is also developed to rapidly and accurately describe the self-folding physics. An important aspect of self-folding is the management of self-collisions, where different portions of the folding structure contact and then block further folding. A metric is developed to predict collisions and is used together with the reduced-order model to design self-folding structures that lock themselves into stable desired configurations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13616, "DOI": "10.1038/srep13616", "DOI Link": "http://dx.doi.org/10.1038/srep13616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360793200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XY; Chen, NJ; Klok, HA; Lee, YM; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xingyu; Chen, nulljun; Klok, Harm-Anton; Lee, Young Moo; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Branched Poly(Aryl Piperidinium) Membranes for Anion-Exchange Membrane Fuel Cells", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anion-exchange membrane fuel cells (AEMFCs) are a promising, next-generation fuel cell technology. AEMFCs require highly conductive and robust anion-exchange membranes (AEMs), which are challenging to develop due to the tradeoff between conductivity and water uptake. Here we report a method to prepare high-molecular-weight branched poly(aryl piperidinium) AEMs. We show that branching reduces water uptake, leading to improved dimensional stability. The optimized membrane, b-PTP-2.5, exhibits simultaneously high OH- conductivity (>145 mS cm(-1) at 80 degrees C), high mechanical strength and dimensional stability, good processability, and excellent alkaline stability (>1500 h) in 1 M KOH at 80 degrees C. AEMFCs based on b-PTP-2.5 reached peak power densities of 2.3 W cm(-2) in H-2-O-2 and 1.3 W cm(-2) in H-2-air at 80 degrees C. The AEMFCs can run stably under a constant current of 0.2 A cm(-2) over 500 h, during which the b-PTP-2.5 membrane remains stable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2022, "Volume": 61, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202114892", "DOI": "10.1002/anie.202114892", "DOI Link": "http://dx.doi.org/10.1002/anie.202114892", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000734677400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Swierk, JR; Klaus, S; Trotochaud, L; Bell, AT; Tilley, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Swierk, John R.; Klaus, Shannon; Trotochaud, Lena; Bell, Alexis T.; Tilley, T. Don", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron-doped nickel (oxy)hydroxide catalysts (FexNi1-xOOH) exhibit high electrocatalytic behavior for the oxygen evolution reaction in base. Recent findings suggest that the incorporation of Fe3+ into a NiOOH lattice leads to nearly optimal adsorption energies for OER intermediates on active Fe sites. Utilizing electrochemical impedance spectroscopy and activation energy measurements, we find that pure NiOOH and FeOOH catalysts exhibit exceedingly high Faradaic resistances and activation energies 40-50 kJ/mol(-1) higher than those of the most active FexNi1-xOOH catalysts. Furthermore, the most active FexNi1-xOOH catalysts in this study exhibit activation energies that approach those previously reported for IrO2 OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2015, "Volume": 119, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19022, "End Page": 19029, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b05861", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b05861", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360026200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JU; Park, IS; Chan, CY; Tanaka, M; Tsuchiya, Y; Nakanotani, H; Adachi, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jong Uk; Park, In Seob; Chan, Chin-Yiu; Tanaka, Masaki; Tsuchiya, Youichi; Nakanotani, Hajime; Adachi, Chihaya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullosecond-time-scale delayed fluorescence molecule for deep-blue OLEDs with small efficiency rolloff", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aromatic organic deep-blue emitters that exhibit thermally activated delayed fluorescence (TADF) can harvest all excitons in electrically generated singlets and triplets as light emission. However, blue TADF emitters generally have long exciton lifetimes, leading to severe efficiency decrease, i.e., rolloff, at high current density and luminullce by exciton annihilations in organic light-emitting diodes (OLEDs). Here, we report a deep-blue TADF emitter employing simple molecular design, in which an activation energy as well as spin-orbit coupling between excited states with different spin multiplicities, were simultaneously controlled. An extremely fast exciton lifetime of 750ns was realized in a donor-acceptor-type molecular structure without heavy metal elements. An OLED utilizing this TADF emitter displayed deep-blue electroluminescence (EL) with CIE chromaticity coordinates of (0.14, 0.18) and a high maximum EL quantum efficiency of 20.7%. Further, the high maximum efficiency were retained to be 20.2% and 17.4% even at high luminullce. Deep-blue emitting organic materials with low exciton lifetime are required to realize efficient organic light-emitting diodes (OLEDs) at high brightness. Here, the authors report deep-blue OLEDs featuring thermally activated delayed fluorescence molecules with subnullo-second exciton lifetime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-15558-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15558-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528787900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khairallah, SA; Anderson, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khairallah, Saad A.; Anderson, Andy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoscopic simulation model of selective laser melting of stainless steel powder", "Source Title": "JOURNAL OF MATERIALS PROCESSING TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A 3D mesoscopic model is developed to simulate selective laser melting processes using the ALE3D multiphysics code. We study the laser-induced melting of a random bed of stainless steel 316 particles on a solid substrate (1000 mu m x 300 mu m x 50 mu m) and its solidification into either a continuous track or a discontinuous track as a result of Plateau Rayleigh instability. Our approach couples thermal diffusion to hydrodynamics and accounts for temperature dependent material properties and surface tension, as well as the random particle distribution. The simulations give new physical insight that should prove useful for development of continuum models, where the powder is homogenized. We validate our approach against the experiment and find that we match the main laser track characteristics. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 475, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 214, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2627, "End Page": 2636, "Article Number": null, "DOI": "10.1016/j.jmatprotec.2014.06.001", "DOI Link": "http://dx.doi.org/10.1016/j.jmatprotec.2014.06.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340300400046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubicki, DJ; Prochowicz, D; Hofstetter, A; Saski, M; Yadav, P; Bi, DQ; Pellet, N; Lewinski, J; Zakeeruddin, SM; Grätzel, M; Emsley, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubicki, Dominik J.; Prochowicz, Daniel; Hofstetter, Albert; Saski, Marcin; Yadav, Pankaj; Bi, Dongqin; Pellet, Norman; Lewinski, Janusz; Zakeeruddin, Shaik M.; Gratzel, Michael; Emsley, Lyndon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of Stable Mixed Guanidinium-Methylammonium Phases with Exceptionally Long Carrier Lifetimes for High-Efficiency Lead Iodide-Based Perovskite Photovoltaics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methylammonium (MA)- and formamidinium (FA)-based organic inorganic lead halide perovskites provide outstanding performance as photovoltaic materials, due to their versatility of fabrication and their power conversion efficiencies reaching over 22%. The proposition of guanidinium (GUA)-doped perovskite materials generated considerable interest due to their potential to increase carrier lifetimes and open-circuit voltages as compared to pure MAPbI(3). However, simple size considerations based on the Goldschmidt tolerance factor suggest that guanidinium is too big to completely replace methylammonium as an A cation in the APbI(3) perovskite lattice, and its effect was thus ascribed to passivation of surface trap states at grain boundaries. As guanidinium was not thought to incorporate into the MAPbI(3) lattice, interest waned since it appeared unlikely that it could be used to modify the intrinsic perovskite properties. Here, using solid-state NMR, we provide for the first time atomic-level evidence that GUA is directly incorporated into the MAPbI(3) and FAPbI(3) lattices, forming pure GUA(x)MA(1-x)PbI(3) or GUA(x)FAI(1-x)PbI(3) phases, and that it reorients on the picosecond time scale within the perovskite lattice, which explains its superior charge carrier stabilization capacity. Our findings establish a fundamental link between charge carrier lifetimes observed in photovoltaic perovskites and the A cation structure in ABX(3)-type metal halide perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2018, "Volume": 140, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3345, "End Page": 3351, "Article Number": null, "DOI": "10.1021/jacs.7b12860", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b12860", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427203600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, YB; Zhang, Y; Yang, L; Zhao, YH; Zhu, YH; Jiang, HL; Li, CZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Yanbin; Zhang, Yue; Yang, Li; Zhao, Yuhan; Zhu, Yihua; Jiang, Hongliang; Li, Chunzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into the activity of nickel boride/nickel heterostructures for efficient methanol electrooxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the role of active sites in electrooxidation reactions is important yet challenging. Here, the authors use operando spectroscopies to monitor the effect of methanol concentration on Ni3B/Ni heterostructures during formate production. Designing efficient catalysts and understanding the underlying mechanisms for anodic nucleophile electrooxidation are central to the advancement of electrochemically-driven technologies. Here, a heterostructure of nickel boride/nickel catalyst is developed to enable methanol electrooxidation into formate with a Faradaic efficiency of nearly 100%. Operando electrochemical impedance spectroscopy and in situ Raman spectroscopy are applied to understand the influence of methanol concentration in the methanol oxidation reaction. High concentrations of methanol inhibit the phase transition of the electrocatalyst to high-valent electro-oxidation products, and electrophilic oxygen species (O* or OH*) formed on the electrocatalyst are considered to be the catalytically active species. Additional mechanistic investigation with density functional theory calculations reveals that the potential-determining step, the formation of *CH2O, occurs most favorably on the nickel boride/nickel heterostructure rather than on nickel boride and nickel. These results are highly instructive for the study of other nucleophile-based approaches to electrooxidation reactions and organic electrosynthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4602, "DOI": "10.1038/s41467-022-32443-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32443-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836839500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Traxler, M; Gisbertz, S; Pachfule, P; Schmidt, J; Roeser, J; Reischauer, S; Rabeah, J; Pieber, B; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Traxler, Michael; Gisbertz, Sebastian; Pachfule, Pradip; Schmidt, Johannes; Roeser, Jerome; Reischauer, Susanne; Rabeah, Jabor; Pieber, Bartholomaus; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acridine-Functionalized Covalent Organic Frameworks (COFs) as Photocatalysts for Metallaphotocatalytic C-N Cross-Coupling", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are structurally tuneable, porous and crystalline polymers constructed through the covalent attachment of small organic building blocks as elementary units. Using the myriad of such building blocks, a broad spectrum of functionalities has been applied for COF syntheses for broad applications, including heterogeneous catalysis. Herein, we report the synthesis of a new family of porous and crystalline COFs using a novel acridine linker and benzene-1,3,5-tricarbaldehyde derivatives bearing a variable number of hydroxy groups. With the broad absorption in the visible light region, the COFs were applied as photocatalysts in metallaphotocatalytic C-N cross-coupling. The fully beta-ketoenamine linked COF showed the highest activity, due to the increased charge separation upon irradiation. The COF showed good to excellent yields for several aryl bromides, good recyclability and even catalyzed the organic transformation in presence of green light as energy source.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2022, "Volume": 61, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202117738", "DOI": "10.1002/anie.202117738", "DOI Link": "http://dx.doi.org/10.1002/anie.202117738", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772001900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, L; Gong, ZY; Xu, YX; Ma, JN; Liu, HF; Xing, JL; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Lei; Gong, Zhuyu; Xu, Youxun; Ma, Jiani; Liu, Huifen; Xing, Jialiang; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Binary Au-Cu Reaction Sites Decorated ZnO for Selective Methane Oxidation to C1 Oxygenates with Nearly 100% Selectivity at Room Temperature", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct and efficient oxidation of methane to methanol and the related liquid oxygenates provides a promising pathway for sustainable chemical industry, while still remaining an ongoing challenge owing to the dilemma between methane activation and overoxidation. Here, ZnO with highly dispersed dual Au and Cu species as cocatalysts enables efficient and selective photocatalytic conversion of methane to methanol and one-carbon (C1) oxygenates using O-2 as the oxidant operated at ambient temperature. The optimized AuCu-ZnO photocatalyst achieves up to 11225 mu mol.g(-1).h(-1) of primary products (CH3OH and CH3OOH) and HCHO with a nearly 100% selectivity, resulting in a 14.1% apparent quantum yield at 365 nm, much higher than the previous best photocatalysts reported for methane conversion to oxygenates. In situ EPR and XPS disclose that Cu species serve as photoinduced electron mediators to promote O-2 activation to (OOH)-O-center dot, and simultaneously that Au is an efficient hole acceptor to enhance H2O oxidation to (OH)-O-center dot, thus synergistically promoting charge separation and methane transformation. This work highlights the significances of co-modification with suitable dual cocatalysts on simultaneous regulation of activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2022, "Volume": 144, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 740, "End Page": 750, "Article Number": null, "DOI": "10.1021/jacs.1c09141", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c09141", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000734442700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Kelly, S; Guevarra, D; Wang, ZB; Wang, Y; Haber, JA; Anulld, M; Gunasooriya, GTKK; Abraham, CS; Vijay, S; Gregoire, JM; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hao; Kelly, Sara; Guevarra, Dan; Wang, Zhenbin; Wang, Yu; Haber, Joel A.; Anulld, Megha; Gunasooriya, G. T. Kasun Kalhara; Abraham, Christina Susan; Vijay, Sudarshan; Gregoire, John M.; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of the limitations in the oxygen reduction activity of transition metal oxide surfaces", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen reduction reaction (ORR) is the key bottleneck in the performance of fuel cells. So far, the most active and stable electrocatalysts for the reaction are based on Pt group metals. Transition metal oxides (TMOs) constitute an alternative class of materials for achieving operational stability under oxidizing conditions. Unfortunately, TMOs are generally found to be less active than Pt. Here, we identify two reasons why it is difficult to find TMOs with a high ORR activity. The first is that TMO surfaces consistently bind oxygen atoms more weakly than transition metals do. This makes the breaking of the O-O bond rate-determining for the broad range of TMO surfaces investigated here. The second is that electric field effects are stronger at TMO surfaces, which further makes O-O bond breaking difficult. To validate the predictions and ascertain their generalizability for TMOs, we report experimental ORR catalyst screening for 7,798 unique TMO compositions that generally exhibit activity well below that of Pt.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 463, "End Page": 468, "Article Number": null, "DOI": "10.1038/s41929-021-00618-w", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00618-w", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653656500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, S; Gu, Y; Seo, JK; Wang, J; Liu, P; Meng, YS; Xu, S; Chen, RK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Sahngki; Gu, Yue; Seo, Joon Kyo; Wang, Joseph; Liu, Ping; Meng, Y. Shirley; Xu, Sheng; Chen, Renkun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable thermoelectrics for personalized thermoregulation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoregulation has substantial implications for energy consumption and human comfort and health. However, cooling technology has remained largely unchanged for more than a century and still relies on cooling the entire space regardless of the number of occupants. Personalized thermoregulation by thermoelectric devices (TEDs) can markedly reduce the cooling volume and meet individual cooling needs but has yet to be realized because of the lack of flexible TEDs with sustainable high cooling performance. Here, we demonstrate a wearable TED that can deliver more than 10 degrees C cooling effect with a high coefficient of performance (COP > 1.5). Our TED is the first to achieve long-term active cooling with high flexibility, due to a novel design of double elastomer layers and high-ZT rigid TE pillars. Thermoregulation based on these devices may enable a shift from centralized cooling toward personalized cooling with the benefits of substantially lower energy consumption and improved human comfort.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw0536", "DOI": "10.1126/sciadv.aaw0536", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw0536", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470125000089", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pletikosic, I; Ali, MN; Fedorov, AV; Cava, RJ; Valla, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pletikosic, I.; Ali, Mazhar N.; Fedorov, A. V.; Cava, R. J.; Valla, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Structure Basis for the Extraordinary Magnetoresistance in WTe2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic structure basis of the extremely large magnetoresistance in layered nonmagnetic tungsten ditelluride has been investigated by angle-resolved photoelectron spectroscopy. Hole and electron pockets of approximately the same size were found at low temperatures, suggesting that carrier compensation should be considered the primary source of the effect. The material exhibits a highly anisotropic Fermi surface from which the pronounced anisotropy of the magnetoresistance follows. A change in the Fermi surface with temperature was found and a high-density-of-states band that may take over conduction at higher temperatures and cause the observed turn-on behavior of the magnetoresistance in WTe2 was identified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2014, "Volume": 113, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 216601, "DOI": "10.1103/PhysRevLett.113.216601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.216601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345658100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, M; Yang, JT; Li, XG; Eguchi, M; Yamauchi, Y; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Min; Yang, Jietian; Li, Xingang; Eguchi, Miharu; Yamauchi, Yusuke; Wang, Zhong-Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights into alloy/oxide or hydroxide interfaces in Ni-Mo-based electrocatalysts for hydrogen evolution under alkaline conditions", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel-molybdenum (Ni-Mo) alloys are promising non-noble metal electrocatalysts for the hydrogen evolution reaction (HER) in alkaline water; however, the kinetic origins of their catalytic activities still remain under debate. In this perspective, we systematically summarize the structural characteristics of Ni-Mo-based electrocatalysts recently reported and find that highly active catalysts generally have alloy-oxide or alloy-hydroxide interface structures. Based on the two-step reaction mechanism under alkaline conditions, water dissociation to form adsorbed hydrogen and combination of adsorbed hydrogen into molecular hydrogen, we discuss in detail the relationship between the two types of interface structures obtained by different synthesis methods and their HER performance in Ni-Mo based catalysts. For the alloy-oxide interfaces, the Ni4Mo/MoOx composites produced by electrodeposition or hydrothermal combined with thermal reduction exhibit activities close to that of platinum. For only the alloy or oxide, their activities are significantly lower than that of composite structures, indicating the synergistic catalytic effect of binary components. For the alloy-hydroxide interfaces, the activity of the NixMoy alloy with different Ni/Mo ratios is greatly improved by constructing heterostructures with hydroxides such as Ni(OH)(2) or Co(OH)(2). In particular, pure alloys obtained by metallurgy must be activated to produce a layer of mixed Ni(OH)(2) and MoOx on the surface to achieve high activity. Therefore, the activity of Ni-Mo catalysts probably originates from the interfaces of alloy-oxide or alloy-hydroxide, in which the oxide or hydroxide promotes water dissociation and the alloy accelerates hydrogen combination. These new understandings will provide valuable guidance for the further exploration of advanced HER electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2023, "Volume": 14, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3400, "End Page": 3414, "Article Number": null, "DOI": "10.1039/d2sc06298d", "DOI Link": "http://dx.doi.org/10.1039/d2sc06298d", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928384800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Viezbicke, BD; Patel, S; Davis, BE; Birnie, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Viezbicke, Brian D.; Patel, Shane; Davis, Benjamin E.; Birnie, Dunbar P., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluation of the Tauc method for optical absorption edge determination: ZnO thin films as a model system", "Source Title": "PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the most frequently used methods for characterizing thin films is UV-Vis absorption. The near-edge region can be fitted to a simple expression in which the intercept gives the band-gap and the fitting exponent identifies the electronic transition as direct or indirect (see Tauc et al., Phys. Status Solidi 15, 627 (1966); these are often called Tauc plots). While the technique is powerful and simple, the accuracy of the fitted band-gap result is seldom stated or known. We tackle this question by refitting a large number of Tauc plots from the literature and look for trends. Nominally pure zinc oxide (ZnO) was chosen as a material with limited intrinsic deviation from stoichiometry and which has been widely studied. Our examination of the band gap values and their distribution leads to a discussion of some experimental factors that can bias the data and lead to either smaller or larger apparent values than would be expected. Finally, an easily evaluated figure-of-merit is defined that may help guide more accurate Tauc fitting. For samples with relatively sharper Tauc plot shapes, the population yields E-g(ZnO) as 3.276 +/- 0.033 eV, in good agreement with data for single crystalline material. (C) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 888, "Times Cited, All Databases": 940, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 252, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1700, "End Page": 1710, "Article Number": null, "DOI": "10.1002/pssb.201552007", "DOI Link": "http://dx.doi.org/10.1002/pssb.201552007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359085300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SY; Chen, BH; Ouyang, LP; Wang, DH; Tan, J; Qiao, YQ; Ge, SF; Ruan, J; Zhuang, A; Liu, XY; Jia, RB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shaoyun; Chen, Baohui; Ouyang, Liping; Wang, Donghui; Tan, Ji; Qiao, Yuqin; Ge, Shengfang; Ruan, Jing; Zhuang, Ai; Liu, Xuanyong; Jia, Renbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Stimuli-Responsive Injectable Antibacterial Hydrogel to Achieve Synergetic Photothermal/Gene-Targeted Therapy towards Uveal Melanoma", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uveal melanoma (UM) is the most prevalent primary intraocular malignullt tumor with a high lethal rate. Patients who undergo conventional enucleation treatments consistently suffer permanent blindness, facial defects, and mental disorders, therefore, novel therapeutic modalities are urgently required. Herein, an injectable and stimuli-responsive drug delivery antibacterial hydrogel (CP@Au@DC_AC50) is constructed via a facile grinding method that is inspired by the preparation process of traditional Chinese medicine. The incorporation of gold nullorods can enhance the mechanical strength of the hydrogel and realize photothermal therapy (PTT) and thermosensitive gel-sol transformation to release the gene-targeted drug DC_AC50 on demand in response to low-density near-infrared (NIR) light. The orthotopic model of UM is built successfully and indicates the excellent efficiency of CP@Au@DC_AC50 in killing tumors without damage to normal tissue because of its synergistic mild temperature PTT and gene-targeted therapy. Moreover, the eyeball infection model reveals the remarkable antibacterial properties of the hydrogel which can prevent endophthalmitis in the eyeball. There is negligible difference between the CP@Au@DC_AC50+NIR group and normal group. This NIR light-triggered gene-targeted therapy/PTT/antibacterial treatment pattern provides a promising strategy for building multifunctional therapeutic platform against intraocular tumors and exhibits great potential for the clinical treatment of UM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 8, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004721, "DOI": "10.1002/advs.202004721", "DOI Link": "http://dx.doi.org/10.1002/advs.202004721", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000679653100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmad, S; Fu, P; Yu, SW; Yang, Q; Liu, X; Wang, XC; Wang, XL; Guo, X; Li, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmad, Sajjad; Fu, Ping; Yu, Shuwen; Yang, Qing; Liu, Xuan; Wang, Xuchao; Wang, Xiuli; Guo, Xin; Li, Can", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dion-Jacobson Phase 2D Layered Perovskites for Solar Cells with Ultrahigh Stability", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D layered perovskites have emerged as potential alternates to traditional 3D analogs to solve the stability issue of perovskite solar cells (PSCs). However, van der Weals gaps in reported Ruddlesden-Popper (RP) phase 2D perovskites with monoammonium cations provide weak interactions between layers, potentially destabilizing the layered perovskite structure and thus the device. Here we eradicate such gaps by incorporating diammonium cations into MAPbI(3), developing a series of Dion-Jacobson phase 2D perovskites that afford a cell efficiency of 13.3% with ultrahigh device stability. Unencapsulated devices retain over 95% efficiency upon exposure to various harsh stresses including ambient air (40%-70% relative humidity [RH]) for 4,000 hr, damp heat (85 degrees C and 85% RH) for 168 hr, and continuous light illumination for 3,000 hr. The improved device stability over the RP counterpart is attributed to alternating hydrogen bonding interactions between diammonium cations and inorganic slabs, strengthening the 2D layered perovskite structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 484, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 794, "End Page": 806, "Article Number": null, "DOI": "10.1016/j.joule.2018.11.026", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.11.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462010600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pickering, EJ; Muñoz-Moreno, R; Stone, HJ; Jones, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pickering, E. J.; Munoz-Moreno, R.; Stone, H. J.; Jones, N. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precipitation in the equiatomic high-entropy alloy CrMnFeCoNi", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CrMnFeCoNi is widely considered to be an exemplar high-entropy alloy, which is stable as a single solid-solution phase at all temperatures below its melting point. Here, for the first time, the formation of two distinct types of Cr-rich precipitate in coarse-grained CrMnFeCoNi is reported following prolonged exposures at 700 degrees C. The precipitates were identified as M23C6 and the sigma phase, and their formation in unworked material during heat treatments without an applied stress indicated that they are equilibrium phases. Therefore, CrMnFeCoNi can no longer be regarded as thermodynamically stable as a single phase at all temperatures below its solidus. (C) 2015 Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 450, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2016, "Volume": 113, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 106, "End Page": 109, "Article Number": null, "DOI": "10.1016/j.scriptamat.2015.10.025", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2015.10.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367412400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YL; Chernikov, A; Zhang, X; Rigosi, A; Hill, HM; van der Zande, AM; Chenet, DA; Shih, EM; Hone, J; Heinz, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yilei; Chernikov, Alexey; Zhang, Xian; Rigosi, Albert; Hill, Heather M.; van der Zande, Arend M.; Chenet, Daniel A.; Shih, En-Min; Hone, James; Heinz, Tony F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Measurement of the optical dielectric function of monolayer transition-metal dichalcogenides: MoS2, MoSe2, WS2, and WSe2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a determination of the complex in-plane dielectric function of monolayers of four transition-metal dichalcogenides: MoS2, MoSe2, WS2, and WSe2, for photon energies from 1.5 to 3 eV. The results were obtained from reflection spectra using a Kramers-Kronig constrained variational analysis. From the dielectric functions, we obtain the absolute absorbance of the monolayers. We also provide a comparison of the dielectric function for the monolayers with the corresponding bulk materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1095, "Times Cited, All Databases": 1204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2014, "Volume": 90, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205422, "DOI": "10.1103/PhysRevB.90.205422", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.205422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345642000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, J; Liu, SB; Hu, ZH; Zhang, XZ; Yi, N; Tang, KR; Dexheimer, MG; Lian, XJ; Wang, Q; Yang, J; Gray, J; Cheng, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jia; Liu, Shangbin; Hu, Zhihui; Zhang, Xianzhe; Yi, Ning; Tang, Kairui; Dexheimer, Michael Gregory; Lian, Xiaojun; Wang, Qing; Yang, Jian; Gray, Jennifer; Cheng, Huanyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Laser-induced graphene non-enzymatic glucose sensors for on-body measurements", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-enzymatic glucose sensors outperform enzymatic ones in terms of cost, sensitivity, stability, and operating duration. Though highly sensitive, it is still desirable to further improve the sensitivity of non-enzymatic glucose sensors to detect a trace amount of glucose in sweat and other biofluids. Among the demonstrated effective approaches using bimetals or 3D porous structures, the porous laser-induced graphene (LIG) on flexible polymers showcases good conductivity and a simple fabrication process for the integration of sensing materials. The uniform electroless plating of the nickel and gold layer on LIG electrodes demonstrates significantly enhanced sensitivity and a large linear range for glucose sensing. The sensor with the porous LIG foam exhibits a high sensitivity of 1080 mu A mM(-1) cm(-2), whereas a further increased sensitivity of 3500 mu A mM(-1) cm(-2) is obtained with LIG fibers (LIGF). Impressively, a large linear range (0-30 mM) can be achieved by changing the bias voltage from 0.5 to 0.1 V due to the Au coating. Because the existing non-enzymatic glucose sensors are limited to use in basic solutions, their application in wearable electronics is elusive. In addition to the reduced requirement for the basic solution, this work integrates a porous encapsulating reaction cavity containing alkali solutions with a soft, skin-interfaced microfluidic component to provide integrated microfluidic non-enzymatic glucose sensors for sweat sampling and glucose sensing. The accurate glucose measurements from the human sweat and cell culture media showcase the practical utility, which opens up opportunities for the non-enzymatic glucose sensors in wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2021, "Volume": 193, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113606, "DOI": "10.1016/j.bios.2021.113606", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2021.113606", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000700077900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, TC; Tham, E; Liu, XY; Yehl, K; Rovner, AJ; Yuk, H; de la Fuente-Nunez, C; Isaacs, FJ; Zhao, XH; Lu, TK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Tzu-Chieh; Tham, Eleonore; Liu, Xinyue; Yehl, Kevin; Rovner, Alexis J.; Yuk, Hyunwoo; de la Fuente-Nunez, Cesar; Isaacs, Farren J.; Zhao, Xuanhe; Lu, Timothy K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogel-based biocontainment of bacteria for continuous sensing and computation", "Source Title": "NATURE CHEMICAL BIOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Genetically modified microorganisms (GMMs) can enable a wide range of important applications including environmental sensing and responsive engineered living materials. However, containment of GMMs to prevent environmental escape and satisfy regulatory requirements is a bottleneck for real-world use. While current biochemical strategies restrict unwanted growth of GMMs in the environment, there is a need for deployable physical containment technologies to achieve redundant, multi-layered and robust containment. We developed a hydrogel-based encapsulation system that incorporates a biocompatible multilayer tough shell and an alginate-based core. This deployable physical containment strategy (DEPCOS) allows no detectable GMM escape, bacteria to be protected against environmental insults including antibiotics and low pH, controllable lifespan and easy retrieval of genomically recoded bacteria. To highlight the versatility of DEPCOS, we demonstrated that robustly encapsulated cells can execute useful functions, including performing cell-cell communication with other encapsulated bacteria and sensing heavy metals in water samples from the Charles River. A dual-layer encapsulation approach provides physical containment of genetically modified bacteria (especially when combined with chemical containment) while also protecting them from environmental stressors and maintaining their sensing functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 724, "End Page": 731, "Article Number": null, "DOI": "10.1038/s41589-021-00779-6", "DOI Link": "http://dx.doi.org/10.1038/s41589-021-00779-6", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636963200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HP; Yu, QQ; Li, H; Li, J; Si, JJ; Jin, YZ; Wang, NN; Wang, JP; He, JW; Wang, XK; Zhang, Y; Ye, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Haiping; Yu, Qianqian; Li, Hui; Li, Jing; Si, Junjie; Jin, Yizheng; Wang, nulla; Wang, Jianpu; He, Jingwen; Wang, Xinke; Zhang, Yan; Ye, Zhizhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton localization in solution-processed organolead trihalide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organolead trihalide perovskites have attracted great attention due to the stunning advances in both photovoltaic and light-emitting devices. However, the photophysical properties, especially the recombination dynamics of photogenerated carriers, of this class of materials are controversial. Here we report that under an excitation level close to the working regime of solar cells, the recombination of photogenerated carriers in solution-processed methylammonium-lead-halide films is dominated by excitons weakly localized in band tail states. This scenario is evidenced by experiments of spectral-dependent luminescence decay, excitation density-dependent luminescence and frequency-dependent terahertz photoconductivity. The exciton localization effect is found to be general for several solution-processed hybrid perovskite films prepared by different methods. Our results provide insights into the charge transport and recombination mechanism in perovskite films and help to unravel their potential for high-performance optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10896, "DOI": "10.1038/ncomms10896", "DOI Link": "http://dx.doi.org/10.1038/ncomms10896", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372461400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Degani, M; An, QZ; Albaladejo-Siguan, M; Hofstetter, YJ; Cho, C; Paulus, F; Grancini, G; Vaynzof, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Degani, Matteo; An, Qingzhi; Albaladejo-Siguan, Miguel; Hofstetter, Yvonne J.; Cho, Changsoon; Paulus, Fabian; Grancini, Giulia; Vaynzof, Yana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "23.7% Efficient inverted perovskite solar cells by dual interfacial modification", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite remarkable progress, the performance of lead halide perovskite solar cells fabricated in an inverted structure lags behind that of standard architecture devices. Here, we report on a dual interfacial modification approach based on the incorporation of large organic cations at both the bottom and top interfaces of the perovskite active layer. Together, this leads to a simultaneous improvement in both the open-circuit voltage and fill factor of the devices, reaching maximum values of 1.184 V and 85%, respectively, resulting in a champion device efficiency of 23.7%. This dual interfacial modification is fully compatible with a bulk modification of the perovskite active layer by ionic liquids, leading to both efficient and stable inverted architecture devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 7, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabj7930", "DOI": "10.1126/sciadv.abj7930", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abj7930", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000724702800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Saremi, S; Acharya, M; Velarde, G; Parsonnet, E; Donahue, P; Qualls, A; Garcia, D; Martin, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jieun; Saremi, Sahar; Acharya, Megha; Velarde, Gabriel; Parsonnet, Eric; Donahue, Patrick; Qualls, Alexander; Garcia, David; Martin, Lane W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh capacitive energy density in ion-bombarded relaxor ferroelectric films", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors can store and release electric energy at ultrafast rates and are extensively studied for applications in electronics and electric power systems. Among various candidates, thin films based on relaxor ferroelectrics, a special kind of ferroelectric with nullometer-sized domains, have attracted special attention because of their high energy densities and efficiencies. We show that high-energy ion bombardment improves the energy storage performance of relaxor ferroelectric thin films. Intrinsic point defects created by ion bombardment reduce leakage, delay low-field polarization saturation, enhance high-field polarizability, and improve breakdown strength. We demonstrate energy storage densities as high as similar to 133 joules per cubic centimeter with efficiencies exceeding 75%. Deterministic control of defects by means of postsynthesis processing methods such as ion bombardment can be used to overcome the trade-off between high polarizability and breakdown strength.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2020, "Volume": 369, "Issue": 6499, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb0631", "DOI Link": "http://dx.doi.org/10.1126/science.abb0631", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548751700049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ST; Wang, ZY; Li, XL; Liu, XY; Wang, HD; Ma, WG; Zhang, LQ; Zhu, LY; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Shuting; Wang, Zhenyu; Li, Xuelei; Liu, Xinyu; Wang, Haidong; Ma, Weigang; Zhang, Lianqi; Zhu, Lingyun; Zhang, Xing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Growth of lithium-indium dendrites in all-solid-state lithium-based batteries with sulfide electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state lithium-based batteries with inorganic solid electrolytes are considered a viable option for electrochemical energy storage applications. However, the application of lithium metal is hindered by issues associated with the growth of mossy and dendritic Li morphologies upon prolonged cell cycling and undesired reactions at the electrode/solid electrolyte interface. In this context, alloy materials such as lithium-indium (Li-In) alloys are widely used at the laboratory scale because of their (electro)chemical stability, although no in-depth investigations on their morphological stability have been reported yet. In this work, we report the growth of Li-In dendritic structures when the alloy material is used in combination with a Li6PS5Cl solid electrolyte and Li(Ni0.6Co0.2Mn0.2)O-2 positive electrode active material and cycled at high currents (e.g., 3.8 mA cm(-2)) and high cathode loading (e.g., 4 mAh cm(-2)). Via ex situ measurements and simulations, we demonstrate that the irregular growth of Li-In dendrites leads to cell short circuits after room-temperature long-term cycling. Furthermore, the difference between Li and Li-In dendrites is investigated and discussed to demonstrate the distinct type of dendrite morphology. Li-In alloys are widely used as reference materials in the research field of solid-state lithium-based batteries. Here, the authors report and discuss the instability of Li-In electrodes towards sulfide solid electrolytes in all-solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6968, "DOI": "10.1038/s41467-021-27311-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27311-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000723756500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, M; Ju, MG; Garces, HF; Carl, AD; Ono, LK; Hawash, Z; Zhang, Y; Shen, TY; Qi, YB; Grimm, RL; Pacifici, D; Zeng, XC; Zhou, YY; Padture, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Min; Ju, Ming-Gang; Garces, Hector F.; Carl, Alexander D.; Ono, Luis K.; Hawash, Zafer; Zhang, Yi; Shen, Tianyi; Qi, Yabing; Grimm, Ronald L.; Pacifici, Domenico; Zeng, Xiao Cheng; Zhou, Yuanyuan; Padture, Nitin P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stable and efficient all-inorganic lead-free perovskite solar cells with native-oxide passivation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been an urgent need to eliminate toxic lead from the prevailing halide perovskite solar cells (PSCs), but the current lead-free PSCs are still plagued with the critical issues of low efficiency and poor stability. This is primarily due to their inadequate photovoltaic properties and chemical stability. Herein we demonstrate the use of the lead-free, all-inorganic cesium tin-germanium triiodide (CsSn(0.5)Ge(0.5)l(3)) solid-solution perovskite as the light absorber in PSCs, delivering promising efficiency of up to 7.11%. More importantly, these PSCs show very high stability, with less than 10% decay in efficiency after 500 h of continuous operation in N-2 atmosphere under one-sun illumination. The key to this striking performance of these PSCs is the formation of a full-coverage, stable native-oxide layer, which fully encapsulates and passivates the perovskite surfaces. The native-oxide passivation approach reported here represents an alternate avenue for boosting the efficiency and stability of lead-free PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 629, "Times Cited, All Databases": 690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16, "DOI": "10.1038/s41467-018-07951-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07951-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, F; Deng, YC; Chen, YL; Cai, XB; Peng, M; Jia, ZM; Xie, JL; Xiao, DQ; Wen, XD; Wang, N; Jiang, Z; Liu, HY; Ma, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Fei; Deng, Yuchen; Chen, Yunlei; Cai, Xiangbin; Peng, Mi; Jia, Zhimin; Xie, Jinglin; Xiao, Dequan; Wen, Xiaodong; Wang, Ning; Jiang, Zheng; Liu, Hongyang; Ma, Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anchoring Cu1 species over nullodiamond-graphene for semi-hydrogenation of acetylene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of cheap, non-toxic, and earth-abundant transition metal catalysts for selective hydrogenation of alkynes remains a challenge in both industry and academia. Here, we report a new atomically dispersed copper (Cu) catalyst supported on a defective nullodiamond-graphene (ND@G), which exhibits excellent catalytic performance for the selective conversion of acetylene to ethylene, i.e., with high conversion (95%), high selectivity (98%), and good stability (for more than 60 h). The unique structural feature of the Cu atoms anchored over graphene through Cu-C bonds ensures the effective activation of acetylene and easy desorption of ethylene, which is the key for the outstanding activity and selectivity of the catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4431, "DOI": "10.1038/s41467-019-12460-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12460-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488235000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZP; Caracciolo, DT; Maswadeh, Y; Wen, JG; Kong, ZJ; Shan, SY; Vargas, JA; Yan, S; Hopkins, E; Park, K; Sharma, A; Ren, Y; Petkov, V; Wang, LC; Zhong, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhi-Peng; Caracciolo, Dominic T.; Maswadeh, Yazan; Wen, Jianguo; Kong, Zhijie; Shan, Shiyao; Vargas, Jorge A.; Yan, Shan; Hopkins, Emma; Park, Keonwoo; Sharma, Anju; Ren, Yang; Petkov, Valeri; Wang, Lichang; Zhong, Chuan-Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloying-realloying enabled high durability for Pt-Pd-3d-transition metal nulloparticle fuel cell catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alloying noble metals with non-noble metals enables high activity while reducing the cost of electrocatalysts in fuel cells. However, under fuel cell operating conditions, state-of-the-art oxygen reduction reaction alloy catalysts either feature high atomic percentages of noble metals (>70%) with limited durability or show poor durability when lower percentages of noble metals (<50%) are used. Here, we demonstrate a highly-durable alloy catalyst derived by alloying PtPd (<50%) with 3d-transition metals (Cu, Ni or Co) in ternary compositions. The origin of the high durability is probed by in-situ/operando high-energy synchrotron X-ray diffraction coupled with pair distribution function analysis of atomic phase structures and strains, revealing an important role of realloying in the compressively-strained single-phase alloy state despite the occurrence of dealloying. The implication of the finding, a striking departure from previous perceptions of phase-segregated noble metal skin or complete dealloying of non-noble metals, is the fulfilling of the promise of alloy catalysts for mass commercialization of fuel cells. Durability of catalysts under fuel cell reaction conditions is challenging for active nulloalloy electrocatalysts derived from platinum group metals and other transition metals. Here, the authors show that realloying in certain multimetallic nulloalloys plays a major role in enabling the high durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 859, "DOI": "10.1038/s41467-021-21017-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21017-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625204500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Yin, S; Long, C; Dong, BW; He, DP; Cheng, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Cheng; Yin, Sheng; Long, Chang; Dong, Bo Wen; He, Daping; Cheng, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid metamaterial absorber for ultra-low and dual-broadband absorption", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-efficiency microwave absorbers remains challenging in the broad-band range, particularly in the low-frequency range containing the L band and even lower. To overcome this challenge, a hybrid metamaterial absorber comprising a conventional magnetic absorbing material and a multi-layered meta-structure predesigned with graphene films is proposed to realize wideband absorption performance starting from ultra-low frequencies (0.79-20.9 GHz and 25.1-40.0 GHz). The high absorption ability of the proposed device originates from fundamental resonullce modes and their coupling. The experimental results agree well with the simulated ones, proving the effectiveness of our design method. In addition, owing to the use of low-density polymethylacrylimide foam and graphene films with outstanding mechanical properties, our design is lightweight and environmentally adaptable, which reflects its engineering value. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2021, "Volume": 29, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14078, "End Page": 14086, "Article Number": null, "DOI": "10.1364/OE.423245", "DOI Link": "http://dx.doi.org/10.1364/OE.423245", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000643941900107", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, J; Ding, WB; Zi, YL; Lu, YJ; Ji, LH; Liu, F; Wu, CS; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Jia; Ding, Wenbo; Zi, Yunlong; Lu, Yijia; Ji, Linhong; Liu, Fan; Wu, Changsheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triboelectric microplasma powered by mechanical stimuli", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerators (TENGs) naturally have the capability of high voltage output to breakdown gas easily. Here we present a concept of triboelectric microplasma by integrating TENGs with the plasma source so that atmospheric-pressure plasma can be powered only by mechanical stimuli. Four classical atmospheric-pressure microplasma sources are successfully demonstrated, including dielectric barrier discharge (DBD), atmospheric-pressure non-equilibrium plasma jets (APNP-J), corona discharge, and microspark discharge. For these types of microplasma, analysis of electric characteristics, optical emission spectra, COMSOL simulation and equivalent circuit model are carried out to explain transient process of different discharge. The triboelectric microplasma has been applied to patterned luminescence and surface treatment successfully as a first-step evaluation as well as to prove the system feasibility. This work offers a promising, facile, portable and safe supplement to traditional plasma sources, and will enrich the diversity of plasma applications based on the reach of existing technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3733, "DOI": "10.1038/s41467-018-06198-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06198-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444494800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HY; Peng, WX; Liu, JB; Chan, XY; Liu, SK; Lu, L; Le Ferrand, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Hongying; Peng, Weixiang; Liu, Junbo; Chan, Xin Ying; Liu, Shike; Lu, Li; Le Ferrand, Hortense", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructured BN Composites with Internally Designed High Thermal Conductivity Paths for 3D Electronic Packaging", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Miniaturized and high-power-density 3D electronic devices pose new challenges on thermal management. Indeed, prompt heat dissipation in electrically insulating packaging is currently limited by the thermal conductivity achieved by thermal interface materials (TIMs) and by their capability to direct the heat toward heat sinks. Here, high thermal conductivity boron nitride (BN)-based composites that are able to conduct heat intentionally toward specific areas by locally orienting magnetically functionalized BN microplatelets are created using magnetically assisted slip casting. The obtained thermal conductivity along the direction of alignment is unusually high, up to 12.1 W m(-1) K-1, thanks to the high concentration of 62.6 vol% of BN in the composite, the low concentration in polymeric binder, and the high degree of alignment. The BN composites have a low density of 1.3 g cm(-3), a high stiffness of 442.3 MPa, and are electrically insulating. Uniquely, the approach is demonstrated with proof-of-concept composites having locally graded orientations of BN microplatelets to direct the heat away from two vertically stacked heat sources. Rationally designing the microstructure of TIMs to direct heat strategically provides a promising solution for efficient thermal management in 3D integrated electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 34, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2205120, "DOI": "10.1002/adma.202205120", "DOI Link": "http://dx.doi.org/10.1002/adma.202205120", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843376100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JTW; Wang, ZP; Pathak, S; Zhang, W; deQuilettes, DW; Wisnivesky-Rocca-Rivarola, F; Huang, J; Nayak, PK; Patel, JB; Yusof, HAM; Vaynzof, Y; Zhu, R; Ramirez, I; Zhang, J; Ducati, C; Grovenor, C; Johnston, MB; Ginger, DS; Nicholas, RJ; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jacob Tse-Wei; Wang, Zhiping; Pathak, Sandeep; Zhang, Wei; deQuilettes, Dane W.; Wisnivesky-Rocca-Rivarola, Florencia; Huang, Jian; Nayak, Pabitra K.; Patel, Jay B.; Yusof, Hanis A. Mohd; Vaynzof, Yana; Zhu, Rui; Ramirez, Ivan; Zhang, Jin; Ducati, Caterina; Grovenor, Chris; Johnston, Michael B.; Ginger, David S.; Nicholas, Robin J.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient perovskite solar cells by metal ion doping", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing the theoretical limiting power conversion efficiency (PCE) in perovskite solar cells requires a better understanding and control over the fundamental loss processes occurring in the bulk of the perovskite layer and at the internal semiconductor interfaces in devices. One of the main challenges is to eliminate the presence of charge recombination centres throughout the film which have been observed to be most densely located at regions near the grain boundaries. Here, we introduce aluminium acetylacetonate to the perovskite precursor solution, which improves the crystal quality by reducing the microstrain in the polycrystalline film. At the same time, we achieve a reduction in the non-radiative recombination rate, a remarkable improvement in the photoluminescence quantum efficiency (PLQE) and a reduction in the electronic disorder deduced from an Urbach energy of only 12.6 meV in complete devices. As a result, we demonstrate a PCE of 19.1% with negligible hysteresis in planar heterojunction solar cells comprising all organic p and n-type charge collection layers. Our work shows that an additional level of control of perovskite thin film quality is possible via impurity cation doping, and further demonstrates the continuing importance of improving the electronic quality of the perovskite absorber and the nature of the heterojunctions to further improve the solar cell performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2892, "End Page": 2901, "Article Number": null, "DOI": "10.1039/c6ee01969b", "DOI Link": "http://dx.doi.org/10.1039/c6ee01969b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382746300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YJ; Wei, XF; He, XX; Yao, JR; Tan, RY; Chen, P; Yao, BY; Zhou, JT; Yao, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yijie; Wei, Xiangfei; He, Xiaoxuan; Yao, Junru; Tan, Ruiyang; Chen, Ping; Yao, Boyi; Zhou, Jintang; Yao, Zhengjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Shape Memory Composites for Joule Heating, Self-Healing, and Highly Efficient Microwave Absorption", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional microwaves absorption materials (MAMs) are applied in the form of coatings, generally inflexible, with high production costs and poor adaptability to applications in different locations. The diversification of application scenarios requires materials with multifunctionalities, but it is extremely challenging to integrate multifunctionalities within single material at present. Herein, a multifunctional CoNC@GN/PCL/TPU MAMs is synthesized. The CoNC@GN nullo-micro absorber has high-efficiency microwave absorption ability. The electromagnetic microwave absorption performance is ultra-light (4 wt.%), ultra-thin (2.3 mm), and broadband (6.21 GHz), which is better than similar MAMs. Additionally, the samples have highly efficient electro-thermal conversion properties, enabling controlled electrical heating performance and excellent self-healing properties. More remarkably, the sample has an electrically driven shape memory effect that allows the material to target the absorption of multi-angle incident electromagnetic waves. Therefore, CoNC@GN/PCL/TPU absorbers are the key to truly opening up opportunities for flexible, shape memory, and multifunctional absorbers in frontier applications such as wearables, deformable robots, and chip protection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 33, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202211352", "DOI Link": "http://dx.doi.org/10.1002/adfm.202211352", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888941400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JL; Song, GS; Liu, T; Yi, X; Yang, K; Cheng, L; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Jiali; Song, Guosheng; Liu, Teng; Yi, Xuan; Yang, Kai; Cheng, Liang; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Vivo Long-Term Biodistribution, Excretion, and Toxicology of PEGylated Transition-Metal Dichalcogenides MS2 (M = Mo, W, Ti) nullosheets", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With unique 2D structures and intriguing physicochemical properties, various types of transition metal dichalcogenides (TMDCs) have attracted much attention in many fields including nullomedicine. Hence, it is of great importance to carefully study the in vivo biodistribution, excretion, and toxicology profiles of different TMDCs, and hopefully to identify the most promising type of TMDCs with low toxicity and fast excretion for further biomedical applications. Herein, the in vivo behaviors of three representative TMDCs including molybdenum dichalcogenides (MoS2), tungsten dichalcogenides (WS2), and titanium dichalcogenides (TiS2) nullosheets are systematically investigated. Without showing significant in vitro cytotoxicity, all the three types of polyethylene glycol (PEG) functionalized TMDCs show dominate accumulation in reticuloendothelial systems (RES) such as liver and spleen after intravenous injection. In marked contrast to WS2-PEG and TiS2-PEG, which show high levels in the organs for months, MoS2-PEG can be degraded and then excreted almost completely within one month. Further degradation experiments indicate that the distinctive in vivo excretion behaviors of TDMCs can be attributed to their different chemical properties. This work suggests that MoS2, among various TMDCs, may be particularly interesting for further biomedical applications owning to its low toxicity, capability of biodegradation, and rapid excretion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600160, "DOI": "10.1002/advs.201600160", "DOI Link": "http://dx.doi.org/10.1002/advs.201600160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392400200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YX; Ren, XM; Hou, ZS; Wang, NN; Jiang, Y; Luan, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yaxin; Ren, Xiaomeng; Hou, Zhaosheng; Wang, Ningning; Jiang, Yue; Luan, Yuxia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering a photosensitizer nulloplatform for amplified photodynamic immunotherapy via tumor microenvironment modulation", "Source Title": "nullOSCALE HORIZONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photosensitizer-based photodynamic therapy (PDT) can not only kill tumor cells by the generated cytotoxic reactive oxygen species (ROS), but also trigger immunogenic cell death (ICD) and activate an immune response for immunotherapy. However, such photodynamic immunotherapy suffers from major obstacles in the tumor microenvironment. The hypoxic microenvironment greatly weakens PDT, while the immunosuppressive tumor microenvironment caused by aberrant tumor blood vessels and indoleamine 2,3-dioxygenase (IDO) leads to a significant reduction in immunotherapy. To overcome these obstacles, herein, an engineered photosensitizer nulloplatform is designed for amplified photodynamic immunotherapy by integrating chlorin e6 (Ce6, a photosensitizer), axitinib (AXT, a tyrosine kinase inhibitor) and dextro-1-methyl tryptophan (1MT, an IDO inhibitor). In our nulloplatform, AXT improves the tumor microenvironment by normalizing tumor blood vessels, which not only promotes PDT by reducing the level of hypoxia of the tumor microenvironment, but also promotes immunotherapy through facilitating infiltration of immune effector cells into the tumor and reversing the immunosuppressive effect of vascular endothelial growth factor (VEGF). Moreover, 1MT effectively inhibits the activity of IDO, further reducing the immunosuppressive nature of the tumor microenvironment. Therefore, this nulloplatform demonstrates an amplified photodynamic immunotherapy via tumor microenvironment modulation, exhibiting outstanding therapeutic efficacy against tumor growth and metastasis with negligible side toxicity. The current concept of engineering photosensitizer nulloplatforms for overcoming photodynamic immunotherapy obstacles provides a promising strategy against tumors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 120, "End Page": 131, "Article Number": null, "DOI": "10.1039/d0nh00480d", "DOI Link": "http://dx.doi.org/10.1039/d0nh00480d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617006200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HY; Chen, SM; Jia, XF; Xu, B; Lin, HF; Yang, HZ; Song, L; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Haoyi; Chen, Shuangming; Jia, Xiaofan; Xu, Biao; Lin, Haifeng; Yang, Haozhou; Song, Li; Wang, Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active and robust eletcrocatalysts based on earth-abundant elements are desirable to generate hydrogen and oxygen as fuels from water sustainably to replace noble metal materials. Here we report an approach to synthesize porous hybrid nullostructures combining amorphous nickel-cobalt complexes with 1T phase molybdenum disulfide (MoS2) via hydrazine-induced phase transformation for water splitting. The hybrid nullostructures exhibit overpotentials of 70mV for hydrogen evolution and 235mV for oxygen evolution at 10 mA cm(-2) with long-term stability, which have superior kinetics for hydrogen-and oxygen-evolution with Tafel slope values of 38.1 and 45.7 mV dec(-1). Moreover, we achieve 10 mA cm(-2) at a low voltage of 1.44V for 48 h in basic media for overall water splitting. We propose that such performance is likely due to the complete transformation of MoS2 to metallic 1T phase, high porosity and stabilization effect of nickel-cobalt complexes on 1T phase MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15377, "DOI": "10.1038/ncomms15377", "DOI Link": "http://dx.doi.org/10.1038/ncomms15377", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400849800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, QR; Scullion, D; Gan, W; Falin, A; Zhang, SY; Watanabe, K; Taniguchi, T; Chen, Y; Santos, EJG; Li, LH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Qiran; Scullion, Declan; Gan, Wei; Falin, Alexey; Zhang, Shunying; Watanabe, Kenji; Taniguchi, Takashi; Chen, Ying; Santos, Elton J. G.; Li, Lu Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High thermal conductivity of high-quality monolayer boron nitride and its thermal expansion", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heat management has become more and more critical, especially in miniaturized modern devices, so the exploration of highly thermally conductive materials with electrical insulation is of great importance. Here, we report that high-quality one-atom-thin hexagonal boron nitride (BN) has a thermal conductivity (k) of 751 W/mK at room temperature, the second largest k per unit weight among all semiconductors and insulators. The k of atomically thin BN decreases with increased thickness. Our molecular dynamic simulations accurately reproduce this trend, and the density functional theory (DFT) calculations reveal the main scattering mechanism. The thermal expansion coefficients of monolayer to trilayer BN at 300 to 400 K are also experimentally measured for the first time. Owing to its wide bandgap, high thermal conductivity, outstanding strength, good flexibility, and excellent thermal and chemical stability, atomically thin BN is a strong candidate for heat dissipation applications, especially in the next generation of flexible electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav0129", "DOI": "10.1126/sciadv.aav0129", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav0129", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473798500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, H; Neale, AR; Zhu, Q; Bahri, M; Wang, X; Yang, HF; Xu, YJ; Clowes, R; Browning, ND; Little, MA; Hardwick, LJ; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Hui; Neale, Alex R.; Zhu, Qiang; Bahri, Mounib; Wang, Xue; Yang, Haofan; Xu, Yongjie; Clowes, Rob; Browning, Nigel D.; Little, Marc A.; Hardwick, Laurence J.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Pyrene-4,5,9,10-Tetraone-Based Covalent Organic Framework Delivers High Specific Capacity as a Li-Ion Positive Electrode", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemically active covalent organic frameworks (COFs) are promising electrode materials for Li-ion batteries. However, improving the specific capacities of COF-based electrodes requires materials with increased conductivity and a higher concentration of redox-active groups. Here, we designed a series of pyrene-4,5,9,10-tetraone COF (PT-COF) and carbon nullotube (CNT) composites (denoted as PT-COFX, where X = 10, 30, and 50 wt % of CNT) to address these challenges. Among the composites, PT-COF50 achieved a capacity of up to 280 mAh g(-1) as normalized to the active COF material at a current density of 200 mA g(-1), which is the highest capacity reported for a COF-based composite cathode electrode to date. Furthermore, PTCOF-50 exhibited excellent rate performance, delivering a capacity of 229 mAh g(-1) at 5000 mA g(-1) (18.5C). Using operando Raman microscopy the reversible transformation of the redox-active carbonyl groups of PT-COF was determined, which rationalizes an overall 4 e(-)/4 Li+ redox process per pyrene-4,5,9,10-tetraone unit, accounting for its superior performance as a Li-ion battery electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2022, "Volume": 144, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9434, "End Page": 9442, "Article Number": null, "DOI": "10.1021/jacs.2c02196", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c02196", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819300900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, GQ; Gao, GY; Yao, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Guangqian; Gao, Guoying; Yao, Kailun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficient thermoelectric materials: The case of orthorhombic IV-VI compounds", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the thermoelectric efficiency is one of the greatest challenges in materials science. The recent discovery of excellent thermoelectric performance in simple orthorhombic SnSe crystal offers new promise in this prospect [Zhao et al. Nature 508, 373 (2014)]. By calculating the thermoelectric properties of orthorhombic IV-VI compounds GeS, GeSe, SnS, and SnSe based on the first-principles combined with the Boltzmann transport theory, we show that the Seebeck coefficient, electrical conductivity, and thermal conductivity of orthorhombic SnSe are in agreement with the recent experiment. Importantly, GeS, GeSe, and SnS exhibit comparative thermoelectric performance compared to SnSe. Especially, the Seebeck coefficients of GeS, GeSe, and SnS are even larger than that of SnSe under the studied carrier concentration and temperature region. We also use the Cahill's model to estimate the lattice thermal conductivities at the room temperature. The large Seebeck coefficients, high power factors, and low thermal conductivities make these four orthorhombic IV-VI compounds promising candidates for high-efficient thermoelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9567, "DOI": "10.1038/srep09567", "DOI Link": "http://dx.doi.org/10.1038/srep09567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355857700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, JF; Zhang, JJ; Cao, XJ; Huo, JH; Huang, XP; Zhang, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Jinfei; Zhang, Jiaojiao; Cao, Xiaojun; Huo, Jinhui; Huang, Xiaopeng; Zhang, Junping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Durable superhydrophobic coatings for prevention of rain attenuation of 5G/weather radomes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superhydrophobic coatings are expected to solve the rain attenuation issue of 5G radomes. However, it is very challenging to design and construct such superhydrophobic coatings with good impalement resistance, mechanical robustness, and weather resistance, which remains as one of the main bottlenecks hindering their practical applications. Here, we report the design of superhydrophobic coatings with all these merits mentioned above by spray-coating a suspension of adhesive/fluorinated silica core/shell microspheres onto substrates. The core/shell microspheres are formed by phase separation of the adhesive and adhesion between the adhesive and fluorinated silica nulloparticles. The coatings have an approximately isotropic three-tier hierarchical micro-/micro-/nullostructure, a dense but rough surface at the nulloscale, and chemically inert composition with low surface energy. Consequently, the coatings show excellent impalement resistance, mechanical robustness and weather resistance compared with previous studies, and the mechanisms are revealed. Furthermore, we realize large-scale preparation, extension, and practical application of the coatings for efficiently preventing rain attenuation of 5G/weather radomes. By taking these advantages, we believe that the superhydrophobic coatings have great application potential and market prospect. The findings here will boost preparation and real-world applications of superhydrophobic coatings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2862, "DOI": "10.1038/s41467-023-38678-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38678-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058116700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, RZ; Kim, HJ; Achavanullthadith, S; Xiong, Z; Lee, JKW; Kong, YL; Ho, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Rongzhou; Kim, Han-Joon; Achavanullthadith, Sippanat; Xiong, Ze; Lee, Jason K. W.; Kong, Yong Lin; Ho, John S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Digitally-embroidered liquid metal electronic textiles for wearable wireless systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic textiles should maintain performance against repeated mechanical, thermal and chemical stresses during daily activities. Here, authors demonstrate digital embroidery of robust liquid metal-based fibres with wireless functionalities. Electronic textiles capable of sensing, powering, and communication can be used to non-intrusively monitor human health during daily life. However, achieving these functionalities with clothing is challenging because of limitations in the electronic performance, flexibility and robustness of the underlying materials, which must endure repeated mechanical, thermal and chemical stresses during daily use. Here, we demonstrate electronic textile systems with functionalities in near-field powering and communication created by digital embroidery of liquid metal fibers. Owing to the unique electrical and mechanical properties of the liquid metal fibers, these electronic textiles can conform to body surfaces and establish robust wireless connectivity with nearby wearable or implantable devices, even during strenuous exercise. By transferring optimized electromagnetic patterns onto clothing in this way, we demonstrate a washable electronic shirt that can be wirelessly powered by a smartphone and continuously monitor axillary temperature without interfering with daily activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2190, "DOI": "10.1038/s41467-022-29859-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29859-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785003900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XP; Jing, WW; Meng, HF; Guo, YY; Yu, LY; Li, RP; Peng, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiaopeng; Jing, Wenwen; Meng, Huifeng; Guo, Yuanyuan; Yu, Liyang; Li, Ruipeng; Peng, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sequential Deposition of Multicomponent Bulk Heterojunctions Increases Efficiency of Organic Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing tandem and multi-blend organic solar cells (OSCs) is an effective way to overcome the absorption limitations of conventional single-junction devices. However, these methods inevitably require tedious multilayer deposition or complicated morphology-optimization procedures. Herein, sequential deposition is utilized as an effective and simple method to fabricate multicomponent OSCs with a double-bulk heterojunction (BHJ) structure of the active layer to further improve photovoltaic performance. Two efficient donor-acceptor pairs, D18-Cl:BTP-eC9 and PM6:L8-BO, are sequentially deposited to form the D18-Cl:BTP-eC9/PM6:L8-BO double-BHJ active layer. In these double-BHJ OSCs, light absorption is significantly improved, and optimal morphology is also retained without requiring a more complicated morphology optimization involved in quaternary blends. Compared to the quaternary blend devices, energy loss (E-loss) is also reduced by rationally matching each donor with an appropriate acceptor. Consequently, the power conversion efficiency (PCE) is improved from 18.25% for D18-Cl:BTP-eC9 and 18.69% for PM6:L8-BO based binary blend OSCs to 19.61% for the double-BHJ OSCs. In contrast, a D18-Cl:PM6:L8-BO:BTP-eC9 quaternary blend of OSCs exhibited a dramatically reduced PCE of 15.83%. These results demonstrate that a double-BHJ strategy, with a relatively simple processing procedure, can potentially enhance the device performance of OSCs and lead to more widespread use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202208997", "DOI Link": "http://dx.doi.org/10.1002/adma.202208997", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000934629700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SY; Fang, XY; Lu, B; Yan, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shuya; Fang, Xiaoyu; Lu, Bo; Yan, Dongpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wide range zero-thermal-quenching ultralong phosphorescence from zero-dimensional metal halide hybrids", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with ultralong phosphorescence have wide-ranging application prospects in biological imaging, light-emitting devices, and anti-counterfeiting. Usually, molecular phosphorescence is significantly quenched with increasing temperature, rendering it difficult to achieve high-efficiency and ultralong room temperature phosphorescence. Herein, we spearhead this challenging effort to design thermal-quenching resistant phosphorescent materials based on an effective intermediate energy buffer and energy transfer route. Co-crystallized assembly of zero-dimensional metal halide organic-inorganic hybrids enables ultralong room temperature phosphorescence of (Ph4P)(2)Cd2Br6 that maintains luminescent stability across a wide temperature range from 100 to 320K (Delta T=220 degrees C) with the room temperature phosphorescence quantum yield of 62.79% and lifetime of 37.85ms, which exceeds those of other state-of-the-art systems. Therefore, this work not only describes a design for thermal-quenching-resistant luminescent materials with high efficiency, but also demonstrates an effective way to obtain intelligent systems with long-lasting room temperature phosphorescence for optical storage and logic compilation applications. Molecular luminescence is generally significantly quenched at high temperature. Here the authors report a zero-dimensional metal halide hybrid that exhibits zero-thermal-quenching ultralong phosphorescence over a wide temperature range of 220K, and demonstrate use for Morse code encryption and logic gates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4649, "DOI": "10.1038/s41467-020-18482-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18482-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573777500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, L; Yang, T; Zhao, YL; Luan, JH; Zhou, G; Wang, H; Jiao, ZB; Liu, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Lei; Yang, Tao; Zhao, Yilu; Luan, Junhua; Zhou, Gang; Wang, Hao; Jiao, Zengbao; Liu, Chain-Tsuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh strength and ductility in newly developed materials with coherent nullolamellar architectures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullo-lamellar materials with ultrahigh strengths and unusual physical properties are of technological importance for structural applications. However, these materials generally suffer from low tensile ductility, which severely limits their practical utility. Here we show that markedly enhanced tensile ductility can be achieved in coherent nullo-lamellar alloys, which exhibit an unprecedented combination of over 2GPa yield strength and 16% uniform tensile ductility. The ultrahigh strength originates mainly from the lamellar boundary strengthening, whereas the large ductility correlates to a progressive work-hardening mechanism regulated by the unique nullo-lamellar architecture. The coherent lamellar boundaries facilitate the dislocation transmission, which eliminates the stress concentrations at the boundaries. Meanwhile, deformation-induced hierarchical stacking-fault networks and associated high-density Lomer-Cottrell locks enhance the work hardening response, leading to unusually large tensile ductilities. The coherent nullo-lamellar strategy can potentially be applied to many other alloys and open new avenues for designing ultrastrong yet ductile materials for technological applications. nullo-lamellar materials with ultrahigh strengths are highly desirable for technological applications. Here the authors report a nullolamellar architecturing approach by utilizing coherent L12 structures to achieve ultrahigh strength and ductility in Ni-Fe-Co-Cr-Al-Ti multicomponent alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6240, "DOI": "10.1038/s41467-020-20109-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20109-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000598906000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaiser, K; Scriven, LM; Schulz, F; Gawel, P; Gross, L; Anderson, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kaiser, Katharina; Scriven, Lorel M.; Schulz, Fabian; Gawel, Przemyslaw; Gross, Leo; Anderson, Harry L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An sp-hybridized molecular carbon allotrope, cyclo[18]carbon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon allotropes built from rings of two-coordinate atoms, known as cyclo[n] carbons, have fascinated chemists for many years, but until now they could not be isolated or structurally characterized because of their high reactivity. We generated cyclo[18] carbon (C-18) using atom manipulation on bilayer NaCl on Cu(111) at 5 kelvin by eliminating carbon monoxide from a cyclocarbon oxide molecule, C24O6. Characterization of cyclo[18] carbon by high-resolution atomic force microscopy revealed a polyynic structure with defined positions of alternating triple and single bonds. The high reactivity of cyclocarbon and cyclocarbon oxides allows covalent coupling between molecules to be induced by atom manipulation, opening an avenue for the synthesis of other carbon allotropes and carbon-rich materials from the coalescence of cyclocarbon molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2019, "Volume": 365, "Issue": 6459, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1299, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay1914", "DOI Link": "http://dx.doi.org/10.1126/science.aay1914", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487547400045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Islam, S; Alfaruqi, MH; Putro, DY; Park, S; Kim, S; Lee, S; Ahmed, MS; Mathew, V; Sun, YK; Hwang, JY; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Islam, Saiful; Alfaruqi, Muhammad Hilmy; Putro, Dimas Yunianto; Park, Sohyun; Kim, Seokhun; Lee, Seulgi; Ahmed, Mohammad Shamsuddin; Mathew, Vinod; Sun, Yang-Kook; Hwang, Jang-Yeon; Kim, Jaekook", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Oriented Mn Deficient ZnMn2O4@C nulloarchitecture for Durable Rechargeable Aqueous Zinc-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manganese (Mn)-based cathode materials have garnered huge research interest for rechargeable aqueous zinc-ion batteries (AZIBs) due to the abundance and low cost of manganese and the plentiful advantages of manganese oxides including their different structures, wide range of phases, and various stoichiometries. A novel in situ generated Mn-deficient ZnMn2O4@C (Mn-d-ZMO@C) nulloarchitecture cathode material from self-assembly of ZnO-MnO@C for rechargeable AZIBs is reported. Analytical techniques confirm the porous and crystalline structure of ZnO-MnO@C and the in situ growth of Mn deficient ZnMn2O4@C. The Zn/Mn-d-ZMO@C cell displays a promising capacity of 194 mAh g(-1) at a current density of 100 mA g(-1) with 84% of capacity retained after 2000 cycles (at 3000 mA g(-1) rate). The improved performance of this cathode originates from in situ orientation, porosity, and carbon coating. Additionally, first-principles calculations confirm the high electronic conductivity of Mn-d-ZMO@C cathode. Importantly, a good capacity retention (86%) is obtained with a year-old cell (after 150 cycles) at 100 mA g(-1) current density. This study, therefore, indicates that the in situ grown Mn-d-ZMO@C nulloarchitecture cathode is a promising material to prepare a durable AZIB.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002636, "DOI": "10.1002/advs.202002636", "DOI Link": "http://dx.doi.org/10.1002/advs.202002636", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604287100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, WG; Spencer, AP; Mukherjee, S; Alzola, JM; Sangwan, VK; Amsterdam, SH; Swick, SM; Jones, LO; Heiber, MC; Herzing, AA; Li, GP; Stern, CL; DeLongchamp, DM; Kohlstedt, KL; Hersam, MC; Schatz, GC; Wasielewski, MR; Chen, LX; Facchetti, A; Marks, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Weigang; Spencer, Austin P.; Mukherjee, Subhrangsu; Alzola, Joaquin M.; Sangwan, Vinod K.; Amsterdam, Samuel H.; Swick, Steven M.; Jones, Leighton O.; Heiber, Michael C.; Herzing, Andrew A.; Li, Guoping; Stern, Charlotte L.; DeLongchamp, Dean M.; Kohlstedt, Kevin L.; Hersam, Mark C.; Schatz, George C.; Wasielewski, Michael R.; Chen, Lin X.; Facchetti, Antonio; Marks, Tobin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystallography, Morphology, Electronic Structure, and Transport in Non-Fullerene/Non-Indacenodithienothiophene Polymer:Y6 Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emerging nonfullerene acceptors (NFAs) with crystalline domains enable high-performance bulk heterojunction (BHJ) solar cells. Thermal annealing is known to enhance the BHJ photoactive layer morphology and performance. However, the microscopic mechanism of annealing-induced performance enhancement is poorly understood in emerging NFAs, especially regarding competing factors. Here, optimized thermal annealing of model system PBDB-TF:Y6 (Y6 = 2,2'4(2Z,2'Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl-12,13-dihydro- [1,2,5] thiadiazolo [3,4-e] - thieno[2 '',3 '':4',5']thieno[2',3':4,5]pyrrolo[3,2-g]thieno[2',3' :4,5] -thieno [3,2-b] indole-2,10-diyl) bis(methanylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene)) dimalononitrile) decreases the open circuit voltage (V-OC) but increases the short circuit current (J(SC)) and fill factor (FF) such that the resulting power conversion efficiency (PCE) increases from 14 to 15% in the ambient environment. Here we systematically investigate these thermal annealing effects through in-depth characterizations of carrier mobility, film morphology, charge photogeneration, and recombination using SCLC, GIXRD, AFM, XPS, NEXAFS, R-SoXS, TEM, STEM, fs/ns TA spectroscopy, 2DES, and impedance spectroscopy. Surprisingly, thermal annealing does not alter the film crystallinity, R-SoXS characteristic size scale, relative average phase purity, or TEM-imaged phase separation but rather facilitates Y6 migration to the BHJ film top surface, changes the PBDB-TF/Y6 vertical phase separation and intermixing, and reduces the bottom surface roughness. While these morphology changes increase bimolecular recombination (BR) and lower the free charge (FC) yield, they also increase the average electron and hole mobility by at least 2-fold. Importantly, the increased mu(h) dominates and underlies the increased FF and PCE. Single-crystal X-ray diffraction reveals that Y6 molecules cofacially pack via their end groups/cores, with the shortest pi-pi distance as close as 3.34 angstrom, clarifying out-of-plane pi-face-on molecular orientation in the nullocrystalline BHJ domains. DFT analysis of Y6 crystals reveals hole/electron reorganization energies of as low as 160/150 meV, large intermolecular electronic coupling integrals of 12.1-37.9 meV rationalizing the 3D electron transport, and relatively high mu(e) of 10(-4) cm(2) V-1 s(-1). Taken together, this work clarifies the richness of thermal annealing effects in high-efficiency NFA solar cells and tasks for future materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2020, "Volume": 142, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14532, "End Page": 14547, "Article Number": null, "DOI": "10.1021/jacs.0c05560", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c05560", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566667700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moghadam, PZ; Li, A; Wiggin, SB; Tao, A; Maloney, AGP; Wood, PA; Ward, SC; Fairen-Jimenez, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moghadam, Peyman Z.; Li, Aurelia; Wiggin, Seth B.; Tao, Andi; Maloney, Andrew G. P.; Wood, Peter A.; Ward, Suzanna C.; Fairen-Jimenez, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of a Cambridge Structural Database Subset: A Collection of Metal-Organic Frameworks for Past, Present, and Future", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the generation and characterization of the most complete collection of metal organic frameworks (MOFs) maintained and updated, for the first time, by the Cambridge Crystallographic Data Centre (CCDC). To set up this subset, we asked the question what is a MOF? and implemented a number of look-for-MOF criteria embedded within a bespoke Cambridge Structural Database (CSD) Python API workflow to identify and extract information on 69 666 MOF materials. The CSD MOF subset is updated regularly with subsequent MOF additions to the CSD, bringing a unique record for all researchers working in the area of porous materials around the world, whether to perform high-throughput computational screening for materials discovery or to have a global view over the existing structures in a single resource. Using this resource, we then developed and used an array of computational tools to remove residual solvent molecules from the framework pores of all the MOFs identified and went on to analyze geometrical and physical properties of nondisordered structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 780, "Times Cited, All Databases": 847, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2017, "Volume": 29, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2618, "End Page": 2625, "Article Number": null, "DOI": "10.1021/acs.chemmater.7b00441", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.7b00441", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399264100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kormányos, A; Zólyomi, V; Drummond, ND; Burkard, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kormanyos, Andor; Zolyomi, Viktor; Drummond, Neil D.; Burkard, Guido", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-Orbit Coupling, Quantum Dots, and Qubits in Monolayer Transition Metal Dichalcogenides", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We derive an effective Hamiltonian that describes the dynamics of electrons in the conduction band of monolayer transition metal dichalcogenides (TMDC) in the presence of perpendicular electric and magnetic fields. We discuss in detail both the intrinsic and the Bychkov-Rashba spin-orbit coupling induced by an external electric field. We point out interesting differences in the spin-split conduction band between different TMDC compounds. An important consequence of the strong intrinsic spin-orbit coupling is an effective out-of-plane g factor for the electrons that differs from the free-electron g factor g similar or equal to 2. We identify a new term in the Hamiltonian of the Bychkov-Rashba spin-orbit coupling that does not exist in III-V semiconductors. Using first-principles calculations, we give estimates of the various parameters appearing in the theory. Finally, we consider quantum dots formed in TMDC materials and derive an effective Hamiltonian that allows us to calculate the magnetic field dependence of the bound states in the quantum dots. We find that all states are both valley and spin split, which suggests that these quantum dots could be used as valley-spin filters. We explore the possibility of using spin and valley states in TMDCs as quantum bits, and conclude that, due to the relatively strong intrinsic spin-orbit splitting in the conduction band, the most realistic option appears to be a combined spin-valley (Kramers) qubit at low magnetic fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2014, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11034, "DOI": "10.1103/PhysRevX.4.011034", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.4.011034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332762500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kufer, D; Konstantatos, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kufer, Dominik; Konstantatos, Gerasimos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photo-FETs: Phototransistors Enabled by 2D and OD nullomaterials", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large diversity of applications in our daily lives that rely on photodetection technology requires photodetectors with distinct properties. The choice of an adequate photodetecting system depends on its application, where aspects such as spectral selectivity, speed, and sensitivity play a critical role. High-sensitivity photodetection covering a large spectral range from the UV to IR is dominated by photodiodes. To overcome existing limitations in sensitivity and cost of state-of-the-art systems, new device architectures and material systems are needed with low-cost fabrication and high performance. Low-dimensional nullomaterials (0D, 1D, 2D) are promising candidates with many unique electrical and optical properties and additional functionalities such as flexibility and transparency. In this Perspective, the physical mechanism of photo-FETs (field-effect transistors) is described and recent advances in the field of low-dimensional photo-FETs and hybrids thereof are discussed. Several requirements for the channel material are addressed in view of the photon absorption and carrier transport process, and a fundamental trade-off between them is pointed out for single-material-based devices. We further clarify how hybrid devices, consisting of an ultrathin channel sensitized with strongly absorbing semiconductors, can circumvent these limitations and lead to a new generation of highly sensitive photodetectors. Recent advances in the development of sensitized low-dimensional photo-FETs are discussed, and several promising future directions for their application in high-sensitivity photodetection are proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2197, "End Page": 2210, "Article Number": null, "DOI": "10.1021/acsphotonics.6b00391", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.6b00391", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390731700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahon, OR; Browe, DC; Gonzalez-Fernulldez, T; Pitacco, P; Whelan, IT; Von Euw, S; Hobbs, C; Nicolosi, V; Cunningham, KT; Mills, KHG; Kelly, DJ; Dunne, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahon, Olwyn R.; Browe, David C.; Gonzalez-Fernulldez, Tomas; Pitacco, Pierluca; Whelan, Ian T.; Von Euw, Stanislas; Hobbs, Christopher; Nicolosi, Valeria; Cunningham, Kyle T.; Mills, Kingston H. G.; Kelly, Daniel J.; Dunne, Aisling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-particle mediated M2 macrophage polarization enhances bone formation and MSC osteogenesis in an IL-10 dependent manner", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering a pro-regenerative immune response following scaffold implantation is integral to functional tissue regeneration. The immune response to implanted biomaterials is determined by multiple factors, including biophysical cues such as material stiffness, topography and particle size. In this study we developed an immune modulating scaffold for bone defect healing containing bone mimetic nullo hydroxyapatite particles (BMnP). We first demonstrate that, in contrast to commercially available micron-sized hydroxyapatite particles, in-house generated BMnP preferentially polarize human macrophages towards an M2 phenotype, activate the transcription factor cMaf and specifically enhance production of the anti-inflammatory cytokine, IL-10. Furthermore, nullo-particle treated macrophages enhance mesenchymal stem cell (MSC) osteogenesis in vitro and this occurs in an IL-10 dependent manner, demonstrating a direct pro-osteogenic role for this cytokine. BMnPs were also capable of driving pro-angiogenic responses in human macrophages and HUVECs. Characterization of immune cell subsets following incorporation of functionalized scaffolds into a rat femoral defect model revealed a similar profile, with micron-sized hydroxyapatite functionalized scaffolds eliciting pro-inflammatory responses characterized by infiltrating T cells and elevated expression of M1 macrophages markers compared to BMnP functionalized scaffolds which promoted M2 macrophage polarization, tissue vascularization and increased bone volume. Taken together these results demonstrate that nullo -sized Hydroxyapatite has immunomodulatory potential and is capable of directing anti-inflammatory innate immune-mediated responses that are associated with tissue repair and regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 239, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 119833, "DOI": "10.1016/j.biomaterials.2020.119833", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2020.119833", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518868700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, L; Li, LL; Yang, J; Fan, JJ; Xu, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Long; Li, Lingling; Yang, Juan; Fan, Jiajie; Xu, Quanlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabricating covalent organic framework/CdS S-scheme heterojunctions for improved solar hydrogen generation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fabrication of S-scheme heterojunctions has received considerable attention as an effective approach to promote the separation and migration of photoexcited electron/hole pairs and retain strong redox abilities. Herein, an imine-based porous covalent organic framework (COF-LZU1) is integrated with controllably fabricated CdS hollow cubes, resulting in the formation of an S-scheme heterojunction. When the COF content reaches 1.5 wt%, the COF/CdS heterostructure (1.5%COF/CdS) achieves the highest hydrogen generation rate of 8670 mu mol.h(-1).g(-1), which is approximately 2.1 times higher than that of pure CdS. The apparent quantum efficiency (AQE) of 1.5%COF/CdS is approximately 8.9% at 420 nm. Further systematic analysis shows that the intimate contact interface and suitable energy band structures between CdS and COF can induce the formation of an internal electric field at the heterojunction interface, which can effectively drive the spatial separation of photoexcited charge carriers and simultaneously maintain a strong redox ability, thus enhancing the photocatalytic H-2 evolution performance. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 350, "End Page": 358, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63869-X", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63869-X", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, YR; Li, Q; Cai, L; Pan, MY; Ghosh, P; Du, KK; Qiu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Yurui; Li, Qiang; Cai, Lu; Pan, Meiyan; Ghosh, Pintu; Du, Kaikai; Qiu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal camouflage based on the phase-changing material GST", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Camouflage technology has attracted growing interest for many thermal applications. Previous experimental demonstrations of thermal camouflage technology have not adequately explored the ability to continuously camouflage objects either at varying background temperatures or for wide observation angles. In this study, a thermal camouflage device incorporating the phase-changing material Ge2Sb2Te5 (GST) is experimentally demonstrated. It has been shown that near-perfect thermal camouflage can be continuously achieved for background temperatures ranging from 30 degrees C to 50 degrees C by tuning the emissivity of the device, which is attained by controlling the GST phase change. The thermal camouflage is robust when the observation angle is changed from 0 degrees to 60 degrees. This demonstration paves the way toward dynamic thermal emission control both within the scientific field and for practical applications in thermal information.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2018, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26, "DOI": "10.1038/s41377-018-0038-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-018-0038-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437729500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, F; Lin, LL; Fu, A; Mo, SG; Ou, DH; Fang, XL; Zheng, NF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, Fei; Lin, Lele; Fu, Ang; Mo, Shiguang; Ou, Daohui; Fang, Xiaoliang; Zheng, nullfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Two-Dimensional Porous Carbon-Modified Separator for High-Energy-Density Li-S Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries are a promising next-generation energy-storage system due to their high theoretical energy density and low cost However, the rapid capacity fading of high-sulfur-loading cathodes caused by the shuttle of soluble polysulfide intermediates between two electrodes heavily hinders the development of high-energy-density Li-S batteries. We develop in this work a powerful functional separator to suppress the polysulfide shuttle by coating two-dimensional nitrogen-doped porous carbon nullosheets on one surface of a commercial polypropylene separator. The high surface area, high content of nitrogen dopants, and close-packing laminar structure of the two-dimensional porous carbon nullosheets make them ideal to fabricate a lightweight and thin separator for high-energy-density Li-S batteries. The separator reported in this work endows the high-sulfur-loading cathodes made of commercial carbon materials with significantly enhanced performances that are comparable with or even superior to the state-of-the-art sulfur composite cathodes, opening up new opportunities for designing practical high-energy-density Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 323, "End Page": 336, "Article Number": null, "DOI": "10.1016/j.joule.2017.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.12.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435090900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, SY; Liu, J; Portale, G; Fang, HH; Blake, GR; ten Brink, GH; Koster, LJA; Loi, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Shuyan; Liu, Jian; Portale, Giuseppe; Fang, Hong-Hua; Blake, Graeme R.; ten Brink, Gert H.; Koster, L. Jan Anton; Loi, Maria Antonietta", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Reproducible Sn-Based Hybrid Perovskite Solar Cells with 9% Efficiency", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low power conversion efficiency (PCE) of tin-based hybrid perovskite solar cells (HPSCs) is mainly attributed to the high background carrier density due to a high density of intrinsic defects such as Sn vacancies and oxidized species (Sn4+) that characterize Sn-based HPSCs. Herein, this study reports on the successful reduction of the background carrier density by more than one order of magnitude by depositing near-single-crystalline formamidinium tin iodide (FASnI(3)) films with the orthorhombic a-axis in the out-of-plane direction. Using these highly crystalline films, obtained by mixing a very small amount (0.08 m) of layered (2D) Sn perovskite with 0.92 m (3D) FASnI(3), for the first time a PCE as high as 9.0% in a planar p-i-n device structure is achieved. These devices display negligible hysteresis and light soaking, as they benefit from very low trap-assisted recombination, low shunt losses, and more efficient charge collection. This represents a 50% improvement in PCE compared to the best reference cell based on a pure FASnI(3) film using SnF2 as a reducing agent. Moreover, the 2D/3D-based HPSCs show considerable improved stability due to the enhanced robustness of the perovskite film compared to the reference cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 769, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2018, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702019, "DOI": "10.1002/aenm.201702019", "DOI Link": "http://dx.doi.org/10.1002/aenm.201702019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424152200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, PT; Shen, YF; Ge, SF; Chen, ZQ; Yoshikawa, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Peitao; Shen, Yafei; Ge, Shifu; Chen, Zhenqian; Yoshikawa, Kunio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Our society currently faces three challenges, including resource depletion, waste accumulation and environmental degradation, leading to rapidly escalating raw material costs and increasingly expensive and restrictive waste disposal legislation. This work aims to produce clean solid biofuel from high moisture content waste biomass (bio-waste) with high nitrogen (N)/chlorine (Cl) content by mild hydrothermal (HT) conversion processes. The newest results are summarized and discussed in terms of the mechanical dewatering and upgrading, dechlorination, denitrification and coalification resulting from the HT pretreatment. Moreover, both the mono-combustion and co-combustion characteristics of the solid fuel are reviewed by concentrating on the pollutants emission control, especially the NO emission properties. In addition, the feasibility of this HT solid biofuel production process is also discussed in terms of Energy Balance and economic viability. As an alternative to dry combustion/dry pyrolysis/co-combustion, the HT process, combining the dehydration and decarboxylation of a biomass to raise its carbon content aiming to achieve a higher calorific value, opens up the field of potential feedstock for lignite-like solid biofuel production from a wide range of nontraditional renewable and plentiful wet agricultural residues, sludge and municipal wastes. It would contribute to a wider application of HT pretreatment bio-wastes for safe disposal and energy recycling. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 347, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2014, "Volume": 131, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 367, "Article Number": null, "DOI": "10.1016/j.apenergy.2014.06.038", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2014.06.038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341335500032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wood, KN; Teeter, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wood, Kevin N.; Teeter, Glenn", "Book Author Full Names": null, "Group Authors": null, "Article Title": "XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction", "Source Title": "ACS APPLIED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate identification of chemical phases associated with the electrode and solid-electrolyte interphase (SEI) is critical for understanding and controlling interfacial degradation mechanisms in lithium-containing battery systems. To study these critical battery materials and interfaces X-ray photoelectron spectroscopy (XPS) is a widely used technique that provides quantitative chemical insights. However, due to the fact that a majority of chemical phases relevant to battery interfaces are poor electronic conductors, phase identification that relies primarily on absolute XPS core-level binding-energies (BEs) can be problematic. Charging during XPS measurements leads to BE shifts that can be difficult to correct. These difficulties are often exacerbated by the coexistence of multiple Li-containing phases in the SEI with overlapping XPS core levels. To facilitate accurate phase identification of battery-relevant phases (and electronically insulating phases in general), we propose a straightforward approach for removing charging effects from XPS data sets. We apply this approach to XPS data sets acquired from six battery-relevant inorganic phases including lithium metal (Li-0), lithium oxide (Li2O), lithium peroxide (Li2O2), lithium hydroxide (LiOH), lithium carbonate (Li2CO3), and lithium nitride (Li3N). Specifically, we demonstrate that BE separations between core levels present in a particular phase (e.g., BE separation between the O 1s and Li 1s core levels in Li2O) provide an additional constraint that can significantly improve reliability of phase identification. For phases like Li2O2 and LiOH where the Li-to-O ratios and BE separations are nearly identical, X-ray excited valence-band spectra can provide additional clues that facilitate accurate phase identification. To accurately identity the phases in this study, we show that in situ growth of Li2O on Li provides a means for determining absolute core-level positions, where all charging effects can be accurately removed. Finally, as an exemplary case we apply the charge-correction methodology to XPS data acquired from a symmetric cell based on a Li2S-P2S5 solid electrolyte. This analysis demonstrates that accurately accounting for XPS BE shifts as a function of current-bias conditions can provide a direct probe of ionic conductivities associated with battery materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 1, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4493, "End Page": 4504, "Article Number": null, "DOI": "10.1021/acsaem.8b00406", "DOI Link": "http://dx.doi.org/10.1021/acsaem.8b00406", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458706500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chong, JY; Sung, CH; Nam, KS; Kang, TW; Kim, H; Lee, HS; Park, H; Park, S; Kang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chong, Jooyeun; Sung, Changhoon; Nam, Kum Seok; Kang, Taewon; Kim, Hyunjun; Lee, Haeseung; Park, Hyunchang; Park, Seongjun; Kang, Jiheong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly conductive tissue-like hydrogel interface through template-directed assembly", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past decade, conductive hydrogels have received great attention as tissue-interfacing electrodes due to their soft and tissue-like mechanical properties. However, a trade-off between robust tissue-like mechanical properties and good electrical properties has prevented the fabrication of a tough, highly conductive hydrogel and limited its use in bioelectronics. Here, we report a synthetic method for the realization of highly conductive and mechanically tough hydrogels with tissue-like modulus. We employed a template-directed assembly method, enabling the arrangement of a disorder-free, highly-conductive nullofibrous conductive network inside a highly stretchable, hydrated network. The resultant hydrogel exhibits ideal electrical and mechanical properties as a tissue-interfacing material. Furthermore, it can provide tough adhesion (800 J/m(2)) with diverse dynamic wet tissue after chemical activation. This hydrogel enables suture-free and adhesive-free, high-performance hydrogel bioelectronics. We successfully demonstrated ultra-low voltage neuromodulation and high-quality epicardial electrocardiogram (ECG) signal recording based on in vivo animal models. This template-directed assembly method provides a platform for hydrogel interfaces for various bioelectronic applications. Conductive hydrogels have potential as tissue-interfacing electrodes, but it is challenging to achieve both robust mechanical properties and good electrical properties. Here, the authors report a synthetic method for developing highly conductive and mechanically tough hydrogels, with a tissue-like modulus, for electrocardiogram signal recording.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2206, "DOI": "10.1038/s41467-023-37948-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37948-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984481700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, R; Jiang, S; Chen, Y; Liu, Y; Weiss, N; Cheng, HC; Wu, H; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Rui; Jiang, Shan; Chen, Yu; Liu, Yuan; Weiss, Nathan; Cheng, Hung-Chieh; Wu, Hao; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Few-layer molybdenum disulfide transistors and circuits for high-speed flexible electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional layered materials, such as molybdenum disulfide, are emerging as an exciting material system for future electronics due to their unique electronic properties and atomically thin geometry. Here we report a systematic investigation of MoS2 transistors with optimized contact and device geometry, to achieve self-aligned devices with performance including an intrinsic gain over 30, an intrinsic cut-off frequency f(T) up to 42 GHz and a maximum oscillation frequency f(MAX) up to 50 GHz, exceeding the reported values for MoS2 transistors to date (f(T) similar to 0.9 GHz, f(MAX) similar to 1GHz). Our results show that logic inverters or radio frequency amplifiers can be formed by integrating multiple MoS2 transistors on quartz or flexible substrates with voltage gain in the gigahertz regime. This study demonstrates the potential of two-dimensional layered semiconductors for high-speed flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 499, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5143, "DOI": "10.1038/ncomms6143", "DOI Link": "http://dx.doi.org/10.1038/ncomms6143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343980700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "John, RA; Demirag, Y; Shynkarenko, Y; Berezovska, Y; Ohannessian, N; Payvand, M; Zeng, P; Bodnarchuk, M; Krumeich, F; Kara, G; Shorubalko, I; Nair, M; Cooke, GA; Lippert, T; Indiveri, G; Kovalenko, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "John, Rohit Abraham; Demirag, Yigit; Shynkarenko, Yevhen; Berezovska, Yuliia; Ohannessian, Natacha; Payvand, Melika; Zeng, Peng; Bodnarchuk, Maryna, I; Krumeich, Frank; Kara, Goekhan; Shorubalko, Ivan; Nair, Manu, V; Cooke, Graham A.; Lippert, Thomas; Indiveri, Giacomo; Kovalenko, Maksym, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconfigurable halide perovskite nullocrystal memristors for neuromorphic computing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many in-memory computing frameworks demand electronic devices with specific switching characteristics to achieve the desired level of computational complexity. Existing memristive devices cannot be reconfigured to meet the diverse volatile and non-volatile switching requirements, and hence rely on tailored material designs specific to the targeted application, limiting their universality. Reconfigurable memristors that combine both ionic diffusive and drift mechanisms could address these limitations, but they remain elusive. Here we present a reconfigurable halide perovskite nullocrystal memristor that achieves on-demand switching between diffusive/volatile and drift/non-volatile modes by controllable electrochemical reactions. Judicious selection of the perovskite nullocrystals and organic capping ligands enable state-of-the-art endurance performances in both modes - volatile (2 x 10(6) cycles) and non-volatile (5.6 x 10(3) cycles). We demonstrate the relevance of such proof-of-concept perovskite devices on a benchmark reservoir network with volatile recurrent and non-volatile readout layers based on 19,900 measurements across 25 dynamically-configured devices. Existing memristors cannot be reconfigured to meet the diverse switching requirements of various computing frameworks, limiting their universality. Here, the authors present a nullocrystal memristor that can be reconfigured on-demand to address these limitations", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2074, "DOI": "10.1038/s41467-022-29727-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29727-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784997300085", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rosen, AS; Iyer, SM; Ray, D; Yao, ZP; Aspuru-Guzik, A; Gagliardi, L; Notestein, JM; Snurr, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rosen, Andrew S.; Iyer, Shaelyn M.; Ray, Debmalya; Yao, Zhenpeng; Aspuru-Guzik, Alan; Gagliardi, Laura; Notestein, Justin M.; Snurr, Randall Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning the quantum-chemical properties of metal-organic frameworks for accelerated materials discovery", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The modular nature of metal-organic frameworks (MOFs) enables synthetic control over their physical and chemical properties, but it can be difficult to know which MOFs would be optimal for a given application. High-throughput computational screening and machine learning are promising routes to efficiently navigate the vast chemical space of MOFs but have rarely been used for the prediction of properties that need to be calculated by quantum mechanical methods. Here, we introduce the Quantum MOF (QMOF) database, a publicly available database of computed quantum-chemical properties for more than 14,000 experimentally synthesized MOFs. Throughout this study, we demonstrate how machine learning models trained on the QMOF database can be used to rapidly discover MOFs with targeted electronic structure properties, using the prediction of theoretically computed band gaps as a representative example. We conclude by highlighting several MOFs predicted to have low band gaps, a challenging task given the electronically insulating nature of most MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2021, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1578, "End Page": 1597, "Article Number": null, "DOI": "10.1016/j.matt.2021.02.015", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2021.02.015", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649592000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZP; Qian, YM; Zhang, T; Otani, M; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Zhiping; Qian, Yumin; Zhang, Tao; Otani, Minoru; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(benzoquinonyl sulfide) as a High-Energy Organic Cathode for Rechargeable Li and Na Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In concern of resource sustainability and environmental friendliness, organic electrode materials for rechargeable batteries have attracted increasing attentions in recent years. However, for many researchers, the primary impression on organic cathode materials is the poor cycling stability and low energy density, mainly due to the unfavorable dissolution and low redox potential, respectively. Herein, a novel polymer cathode material, namely poly(benzoquinonyl sulfide) (PBQS) is reported, for either rechargeable Li or Na battery. Remarkably, PBQS shows a high energy density of 734 W h kg(-1) (2.67 V x 275 mA h g(-1)) in Li battery, or 557 W h kg(-1) (2.08 V x 268 mA h g(-1)) in Na battery, which exceeds those of most inorganic Li or Na intercalation cathodes. Moreover, PBQS also demonstrates excellent long-term cycling stability (1000 cycles, 86%) and superior rate capability (5000 mA g(-1), 72%) in Li battery. Besides the exciting battery performance, investigations on the structure-property relationship between benzoquinone (BQ) and PBQS, and electrochemical behavior difference between Li-PBQS battery and Na-PBQS battery, also provide significant insights into developing better Li-organic and Na-organic batteries beyond conventional Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500124, "DOI": "10.1002/advs.201500124", "DOI Link": "http://dx.doi.org/10.1002/advs.201500124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368998500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, H; Cheng, T; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Hai; Cheng, Tao; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomistic Mechanisms Underlying Selectivities in C1 and C2 Products from Electrochemical Reduction of CO on Cu(111)", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Practical environmental and energy applications of the electrochemical reduction of CO2 to chemicals and fuels require far more efficient and selective electrocatalysts beyond the only working material Cu, but the wealth of experimental data on Cu can serve to validate any proposed mechanisms. To provide design guidelines, we use quantum mechanics to predict the detailed atomistic mechanisms responsible for C-1 and C-2 products on Cu. Thus, we report the pH dependent routes to the major products, methane and ethylene, and identify the key intermediates where branches to methanol, ketene, ethanol, acetylene, and ethane are kinetically blocked. We discovered that surface water on Cu plays a key role in the selectivity for hydrocarbon products over the oxygen containing alcohol products by serving as a strong proton donor for electrochemical dehydration reductions. We suggest new experiments to validate our predicted mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2017, "Volume": 139, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 130, "End Page": 136, "Article Number": null, "DOI": "10.1021/jacs.6b06846", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b06846", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392036900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cnops, K; Rand, BP; Cheyns, D; Verreet, B; Empl, MA; Heremans, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cnops, Kjell; Rand, Barry P.; Cheyns, David; Verreet, Bregt; Empl, Max A.; Heremans, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "8.4% efficient fullerene-free organic solar cells exploiting long-range exciton energy transfer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to increase the power conversion efficiency of organic solar cells, their absorption spectrum should be broadened while maintaining efficient exciton harvesting. This requires the use of multiple complementary absorbers, usually incorporated in tandem cells or in cascaded exciton-dissociating heterojunctions. Here we present a simple three-layer architecture comprising two non-fullerene acceptors and a donor, in which an energy-relay cascade enables an efficient two-step exciton dissociation process. Excitons generated in the remote wide-bandgap acceptor are transferred by long-range Forster energy transfer to the smaller-bandgap acceptor, and subsequently dissociate at the donor interface. The photocurrent originates from all three complementary absorbing materials, resulting in a quantum efficiency above 75% between 400 and 720 nm. With an open-circuit voltage close to 1V, this leads to a remarkable power conversion efficiency of 8.4%. These results confirm that multilayer cascade structures are a promising alternative to conventional donor-fullerene organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3406, "DOI": "10.1038/ncomms4406", "DOI Link": "http://dx.doi.org/10.1038/ncomms4406", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334299400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, P; Tang, YJ; Li, DW; Wang, Y; Ran, P; Zhou, CY; Yuan, Y; Zhu, WJ; Liu, TY; Liang, K; Kuang, CF; Liu, X; Zhu, BW; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Peng; Tang, Yingjie; Li, Dingwei; Wang, Yan; Ran, Peng; Zhou, Chuanyu; Yuan, Ye; Zhu, Wenjuan; Liu, Tianyu; Liang, Kun; Kuang, Cuifang; Liu, Xu; Zhu, Bowen; Yang, Yang (Michael)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing nearly-zero dark current and ultrahigh signal-to-noise ratio perovskite X-ray detector and image array by dark-current-shunting strategy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although perovskite X-ray detectors have revealed promising properties, their dark currents are usually hundreds of times larger than the practical requirements. Here, we report a detector architecture with a unique shunting electrode working as a blanking unit to suppress dark current, and it theoretically can be reduced to zero. We experimentally fabricate the dark-current-shunting X-ray detector, which exhibits a record-low dark current of 51.1 fA at 5 V mm(-1), a detection limit of 7.84 nGy(air) s(-1), and a sensitivity of 1.3 x 10(4) mu C Gy(air)(-1) cm(-2). The signal-to-noise ratio of our polycrystalline perovskite-based detector is even outperforming many previously reported state-of-the-art single crystal-based X-ray detectors by serval orders of magnitude. Finally, the proof-of-concept X-ray imaging of a 64 x 64 pixels dark-current-shunting detector array is successfully demonstrated. This work provides a device strategy to fundamentally reduce dark current and enhance the signal-to-noise ratio of X-ray detectors and photodetectors in general. The high dark current of perovskite photodetectors hinders the full potential of perovskites as active material for X-ray detectors. Here, Jin et al. provide a strategy to reduce the dark current to zero and massively enhance the signal-to-noise ratio of perovskite X-ray detectors and photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-36313-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36313-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954587000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Min, TT; Sun, XL; Yuan, ZP; Zhou, LP; Jiao, XY; Zha, JW; Zhu, Z; Wen, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Min, Tiantian; Sun, Xiaoli; Yuan, Zhipeng; Zhou, Liping; Jiao, Xiangyu; Zha, Junwei; Zhu, Zhu; Wen, Yongqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel antimicrobial packaging film based on porous poly(lactic acid) nullofiber and polymeric coating for humidity-controlled release of thyme essential oil", "Source Title": "LWT-FOOD SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this work is to explore a new pathway to develop active packaging materials. Currently, controlled release materials have attracted considerable attention in food packaging applications. In this study, the thyme essential oil (TEO) was loaded in electrospinning porous poly(lactic acid) (PLA) nullofibers and coated with poly(vinyl alcohol)/poly(ethylene glycol) (PVA/PEG) blends for humidity-controlled TEO release. The images of scanning electron microscope displayed uniform pores distributed on the surface of PLA nullofibers. Water contact angle measurement indicated that PVA/PEG coating provided the packaging film with excellent hydrophilicity. ATR-FTIR spectral analysis supported the chemical composition of the films. The antibacterial activities of PLA/TEO/PVA/PEG films against Escherichia coli and Staphylococcus aureus reached >99%. Furthermore, the weight loss and firmness of strawberries packaged with this novel film were evaluated. Finally, the in vitro release behaviors of TEO were evaluated and the results demonstrated that the release rate could be controlled by adjusting the humidity (20% RH to 80% RH).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110034, "DOI": "10.1016/j.lwt.2020.110034", "DOI Link": "http://dx.doi.org/10.1016/j.lwt.2020.110034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599531300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YZ; Liang, H; Liu, XM; Wu, J; Yang, C; Wong, TM; Kwan, KYH; Cheung, KMC; Wu, SL; Yeung, KWK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yizhou; Liang, Hang; Liu, Xiangmei; Wu, Jun; Yang, Cao; Wong, Tak Man; Kwan, Kenny Y. H.; Cheung, Kenneth M. C.; Wu, Shuilin; Yeung, Kelvin W. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulation of macrophage polarization through surface topography design to facilitate implant-to-bone osteointegration", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proper immune responses are critical for successful biomaterial implantation. Here, four scales of honeycomb-like TiO2 structures were custom made on titanium (Ti) substrates to investigate cellular behaviors of RAW 264.7 macro-phages and their immunomodulation on osteogenesis. We found that the reduced scale of honeycomb-like TiO2 structures could significantly activate the anti-inflammatory macrophage phenotype (M2), in which the 90-nullometer sample induced the highest expression level of CD206, interleukin-4, and interleukin-10 and released the highest amount of bone morphogenetic protein-2 among other scales. Afterward, the resulting immune microenvironment favorably triggered osteogenic differentiation of murine mesenchymal stem cells in vitro and subsequent implant-to-bone osteointegration in vivo. Furthermore, transcriptomic analysis revealed that the minimal scale of TiO2 honeycomb-like structure (90 nullometers) facilitated macrophage filopodia formation and up-regulated the Rho family of guanosine triphosphatases (RhoA, Rac1, and CDC42), which reinforced the polarization of macrophages through the activation of the RhoA/Rho-associated protein kinase signaling pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabf6654", "DOI": "10.1126/sciadv.abf6654", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abf6654", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636455600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tracy, CL; Park, S; Rittman, DR; Zinkle, SJ; Bei, H; Lang, M; Ewing, RC; Mao, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tracy, Cameron L.; Park, Sulgiye; Rittman, Dylan R.; Zinkle, Steven J.; Bei, Hongbin; Lang, Maik; Ewing, Rodney C.; Mao, Wendy L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High pressure synthesis of a hexagonal close-packed phase of the high-entropy alloy CrMnFeCoNi", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys, near-equiatomic solid solutions of five or more elements, represent a new strategy for the design of materials with properties superior to those of conventional alloys. However, their phase space remains constrained, with transition metal high-entropy alloys exhibiting only face- or body-centered cubic structures. Here, we report the high-pressure synthesis of a hexagonal close-packed phase of the prototypical high-entropy alloy CrMnFeCoNi. This martensitic transformation begins at 14 GPa and is attributed to suppression of the local magnetic moments, destabilizing the initial fcc structure. Similar to fcc-to-hcp transformations in Al and the noble gases, the transformation is sluggish, occurring over a range of >40 GPa. However, the behaviour of CrMnFeCoNi is unique in that the hcp phase is retained following decompression to ambient pressure, yielding metastable fcc-hcp mixtures. This demonstrates a means of tuning the structures and properties of high-entropy alloys in a manner not achievable by conventional processing techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15634, "DOI": "10.1038/ncomms15634", "DOI Link": "http://dx.doi.org/10.1038/ncomms15634", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401966000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, G; Miljkovic, N; Ghasemi, H; Huang, XP; Boriskina, SV; Lin, CT; Wang, JJ; Xu, YF; Rahman, MM; Zhang, TJ; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, George; Miljkovic, Nenad; Ghasemi, Hadi; Huang, Xiaopeng; Boriskina, Svetlana V.; Lin, Cheng-Te; Wang, Jianjian; Xu, Yanfei; Rahman, Md Mahfuzur; Zhang, TieJun; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Volumetric solar heating of nullofluids for direct vapor generation", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional solar-thermal receivers suffer from high surface temperatures, which increase heat losses to the surroundings. To improve performance, volumetric receivers based on nullopartides suspended in liquid (nullofluids) have been studied as an approach to reduce surface losses by localizing high temperatures to the interior of the receiver. Here, we report measured vapor generation efficiencies of 69% at solar concentrations of 10 sun using graphitized carbon black, carbon black, and graphene suspended in water, representing a significant improvement in both transient and steady-state performance over previously reported results. To elucidate the vapor generation mechanism and validate our experimental results, we develop numerical and analytical heat transfer models that suggest that nullofluid heating and vapor generation occur due to classical global heating of the suspension fluid. This work demonstrates high nullofluid-assisted vapor generation efficiencies with potential applications in power generation, distillation, and sterilization. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 17, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 301, "Article Number": null, "DOI": "10.1016/j.nulloen.2015.08.021", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2015.08.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366149000032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, K; Yi, J; Liu, XY; Sun, Y; Cui, J; Xie, YH; Liu, YY; Xia, YY; Zhang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Kai; Yi, Jin; Liu, Xiaoyu; Sun, Yang; Cui, Jin; Xie, Yihua; Liu, Yuyu; Xia, Yongyao; Zhang, Jiujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating Zn Deposition via an Artificial Solid-Electrolyte Interface with Aligned Dipoles for Long Life Zn Anode", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc ion batteries show prospects for next-generation renewable energy storage devices. However, the practical applications have been limited by the issues derived from Zn anode. As one of serious problems, Zn dendrite growth caused from the uncontrollable Zn deposition is unfavorable. Herein, with the aim to regulate Zn deposition, an artificial solid-electrolyte interface is subtly engineered with a perovskite type material, BaTiO3, which can be polarized, and its polarization could be switched under the external electric field. Resulting from the aligned dipole in BaTiO3 layer, zinc ions could move in order during cycling process. Regulated Zn migration at the anode/electrolyte interface contributes to the even Zn stripping/plating and confined Zn dendrite growth. As a result, the reversible Zn plating/stripping processes for over 2000 h have been achieved at 1 mA cm(-2) with capacity of 1 mAh cm(-2). Furthermore, this anode endowing the electric dipoles shows enhanced cycling stability for aqueous Zn-MnO2 batteries. The battery can deliver nearly 100% Coulombic efficiency at 2 A g(-1) after 300 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 79, "DOI": "10.1007/s40820-021-00599-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00599-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620938100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Y; Xue, YR; Qi, L; Xing, CY; Zheng, XC; He, F; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yang; Xue, Yurui; Qi, Lu; Xing, Chengyu; Zheng, Xuchen; He, Feng; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rhodium nullocrystals on porous graphdiyne for electrocatalytic hydrogen evolution from saline water", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The realization of the efficient hydrogen conversion with large current densities at low overpotentials represents the development trend of this field. Here we report the atomic active sites tailoring through a facile synthetic method to yield well-defined Rhodium nullocrystals in aqueous solution using formic acid as the reducing agent and graphdiyne as the stabilizing support. High-resolution high-angle annular dark-field scanning-transmission electron microscopy images show the high-density atomic steps on the faces of hex-ahedral Rh nullocrystals. Experimental results reveal the formation of stable sp-C-Rh bonds can stabilize Rh nullocrystals and further improve charge transfer ability in the system. Experimental and density functional theory calculation results solidly demonstrate the exposed high active stepped surfaces and various metal atomic sites affect the electronic structure of the catalyst to reduce the overpotential resulting in the large-current hydrogen production from saline water. This exciting result demonstrates unmatched electrocatalytic performance and highly stable saline water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5227, "DOI": "10.1038/s41467-022-32937-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32937-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000850348400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CJ; Ang, NWJ; Meyer, TH; Qiu, YA; Ackermann, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cuiju; Ang, Nate W. J.; Meyer, Tjark H.; Qiu, Youai; Ackermann, Lutz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic Electrochemistry: Molecular Syntheses with Potential", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient and selective molecular syntheses are paramount to inter alia biomolecular chemistry and material sciences as well as for practitioners in chemical, agrochemical, and pharmaceutical industries. Organic electrosynthesis has undergone a considerable renaissance and has thus in recent years emerged as an increasingly viable platform for the sustainable molecular assembly. In stark contrast to early strategies by innate reactivity, electrochemistry was recently merged with modern concepts of organic synthesis, such as transition-metal-catalyzed transformations for inter alia C-H functionalization and asymmetric catalysis. Herein, we highlight the unique potential of organic electrosynthesis for sustainable synthesis and catalysis, showcasing key aspects of exceptional selectivities, the synergism with photocatalysis, or dual electrocatalysis, and novel mechanisms in metallaelectrocatalysis until February of 2021.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2021, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 415, "End Page": 431, "Article Number": null, "DOI": "10.1021/acscentsci.0c01532", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c01532", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634764100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, JW; Zhang, S; Zhou, XQ; Chen, WB; Gautier, R; Xia, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Jianwei; Zhang, Shuai; Zhou, Xinquan; Chen, Weibin; Gautier, Romain; Xia, Zhiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-Infrared Light-Emitting Diodes utilizing a Europium-Activated Calcium Oxide Phosphor with External Quantum Efficiency of up to 54.7%", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near-infrared (NIR) luminescence materials with broadband emissions are necessary for the development of light-emitting diodes (LEDs) based light sources. However, most known NIR-emitting materials are limited by their low external quantum efficiency. This work demonstrates how the photoluminescence quantum efficiency of europium-activated calcium oxide (CaO:Eu) NIR phosphor can be significantly improved and stabilized at operating temperatures of LEDs. A carbon paper wrapping technology is innovatively developed and used during the solid-state sintering to promote the reduction of Eu3+ into Eu2+. In parallel, the oxygen vacancies in the CaO lattice are repaired utilizing GeO2 decomposition. Through this process, a record-high external quantum efficiency of 54.7% at 740 nm is obtained with a thermal stability greatly improved from 57% to 90% at 125 degrees C. The as-fabricated NIR-LEDs reach record photoelectric efficiency (100 mA@23.4%) and output power (100 mA @ 319.5 mW). This discovery of high-performance phosphors will open new research avenues for broadband NIR LED light sources in a variety of photonics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 34, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201887, "DOI": "10.1002/adma.202201887", "DOI Link": "http://dx.doi.org/10.1002/adma.202201887", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796359900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TX; Su, YH; Lin, CC; Ruan, J; Ting, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thi Xuyen Nguyen; Su, Yen-Hsun; Lin, Chia-Chun; Ruan, Jrjeng; Ting, Jyh-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New High Entropy Glycerate for High Performance Oxygen Evolution Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, a new high entropy material is reported, i.e., a noble metal-free high entropy glycerate (HEG), synthesized via a simple solvothermal process. The HEG consists of 5 different metals of Fe, Ni, Co, Cr, and Mn. The unique glycerate structure exhibits an excellent oxygen evolution reaction (OER) activity with a low overpotential of 229 and 278 mV at current densities of 10 and 100 mA cm(-2), respectively, in 1 m KOH electrolyte, outperforming its subsystems of binary-, ternary-, and quaternary-metal glycerates. The HEG also shows outstanding stability and durability in the alkaline electrolyte. The result demonstrates the significance of synergistic effect that gives additional freedoms to modify the electronic structure and coordination environment. Moreover, HEG@HEG electrolyzer shows a good overall water splitting performance and durability, requiring a cell voltage of 1.63 V to achieve a current density of 10 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002446, "DOI": "10.1002/advs.202002446", "DOI Link": "http://dx.doi.org/10.1002/advs.202002446", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612037600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naik, MH; Jain, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naik, Mit H.; Jain, Manish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultraflatbands and Shear Solitons in Moire Patterns of Twisted Bilayer Transition Metal Dichalcogenides", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultraflatbands in twisted bilayers of two-dimensional materials have the potential to host strong correlations, including the Mott-insulating phase at half-filling of the band. Using first-principles density functional theory calculations, we show the emergence of ultraflatbands at the valence band edge in twisted bilayer MoS2, a prototypical transition metal dichalcogenide. The computed band widths, 5 and 23 meV for 56.5 degrees and 3.5 degrees twist angles, respectively, are comparable to that of twisted bilayer graphene near magic angles. Large structural transformations in the moire patterns lead to formation of shear solitons at stacking boundaries and strongly influence the electronic structure. We extend our analysis for twisted bilayer MoS2 to show that flatbands can occur at the valence band edge of twisted bilayer WS2, MoSe2, and WSe2 as well.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2018, "Volume": 121, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 266401, "DOI": "10.1103/PhysRevLett.121.266401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.266401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454637100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Comin, R; Frano, A; Yee, MM; Yoshida, Y; Eisaki, H; Schierle, E; Weschke, E; Sutarto, R; He, F; Soumyanarayanull, A; He, Y; Le Tacon, M; Elfimov, IS; Hoffman, JE; Sawatzky, GA; Keimer, B; Damascelli, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Comin, R.; Frano, A.; Yee, M. M.; Yoshida, Y.; Eisaki, H.; Schierle, E.; Weschke, E.; Sutarto, R.; He, F.; Soumyanarayanull, A.; He, Yang; Le Tacon, M.; Elfimov, I. S.; Hoffman, Jennifer E.; Sawatzky, G. A.; Keimer, B.; Damascelli, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge Order Driven by Fermi-Arc Instability in Bi2Sr2-xLaxCuO6+δ", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The understanding of the origin of superconductivity in cuprates has been hindered by the apparent diversity of intertwining electronic orders in these materials. We combined resonullt x-ray scattering (REXS), scanning-tunneling microscopy (STM), and angle-resolved photoemission spectroscopy (ARPES) to observe a charge order that appears consistently in surface and bulk, and in momentum and real space within one cuprate family, Bi2Sr2-xLaxCuO6+delta. The observed wave vectors rule out simple antinodal nesting in the single-particle limit but match well with a phenomenological model of a many-body instability of the Fermi arcs. Combined with earlier observations of electronic order in other cuprate families, these findings suggest the existence of a generic charge-ordered state in underdoped cuprates and uncover its intimate connection to the pseudogap regime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 500, "Times Cited, All Databases": 539, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2014, "Volume": 343, "Issue": 6169, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 390, "End Page": 392, "Article Number": null, "DOI": "10.1126/science.1242996", "DOI Link": "http://dx.doi.org/10.1126/science.1242996", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330039300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, Y; Miao, LC; Ma, GQ; Di, SL; Wang, YY; Wang, LB; Xu, JZ; Zhang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Yang; Miao, Licheng; Ma, Guoqiang; Di, Shengli; Wang, Yuanyuan; Wang, Liubin; Xu, Jianzhong; Zhang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-concentrated aqueous electrolytes with organic solvent additives for stable zinc batteries†‡", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc batteries (RAZBs) are promising for large-scale energy storage because of their superiority in addressing cost and safety concerns. However, their practical realization is hampered by issues including dendrite growth, poor reversibility and low coulombic efficiency (CE) of Zn anodes due to parasitic reactions. Here, we report a non-concentrated aqueous electrolyte composed of 2 m zinc trifluoromethanesulfonate (Zn(OTf)(2)) and the organic dimethyl carbonate (DMC) additive to stabilize the Zn electrochemistry. Unlike the case in conventional aqueous electrolytes featuring typical Zn[H2O](6)(2+) solvation, a solvation sheath of Zn2+ with the co-participation of the DMC solvent and OTf- anion is found in the formulated H2O + DMC electrolyte, which contributes to the formation of a robust ZnF2 and ZnCO3-rich interphase on Zn. The resultant Zn anode exhibits a high average CE of Zn plating/stripping (99.8% at an areal capacity of 2.5 mA h cm(-2)) and dendrite-free cycling over 1000 cycles. Furthermore, the H2O + DMC electrolytes sustain stable operation of RAZBs pairing Zn anodes with diverse cathode materials such as vanadium pentoxide, manganese dioxide, and zinc hexacyanoferrate. Rational electrolyte design with organic solvent additives would promote building better aqueous batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2021, "Volume": 12, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5843, "End Page": 5852, "Article Number": null, "DOI": "10.1039/d0sc06734b", "DOI Link": "http://dx.doi.org/10.1039/d0sc06734b", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631617200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, M; Zhang, YH; Gao, X; Palacios, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Min; Zhang, Yuhao; Gao, Xiang; Palacios, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance GaN Vertical Fin Power Transistors on Bulk GaN Substrates", "Source Title": "IEEE ELECTRON DEVICE LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This letter reports a GaN vertical fin power field-effect-transistor structure with submicron fin-shaped channels on bulk GaN substrates. In this vertical transistor design only n-GaN layers are needed, while no material regrowth or p-GaN layer is required. A combined dry/wet etch was used to get smooth fin vertical sidewalls. The fabricated transistor demonstrated a threshold voltage of 1 V and specific on resistance of 0.36m Omega cm(2). By proper electric field engineering, 800 V blocking voltage was achieved at a gate bias of 0 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 38, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 509, "End Page": 512, "Article Number": null, "DOI": "10.1109/LED.2017.2670925", "DOI Link": "http://dx.doi.org/10.1109/LED.2017.2670925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398905400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, KJ; Kuzum, D; Hwang, SW; Kim, BH; Juul, H; Kim, NH; Won, SM; Chiang, K; Trumpis, M; Richardson, AG; Cheng, HY; Fang, H; Thompson, M; Bink, H; Talos, D; Seo, KJ; Lee, HN; Kang, SK; Kim, JH; Lee, JY; Huang, YG; Jensen, FE; Dichter, MA; Lucas, TH; Viventi, J; Litt, B; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Ki Jun; Kuzum, Duygu; Hwang, Suk-Won; Kim, Bong Hoon; Juul, Halvor; Kim, Nam Heon; Won, Sang Min; Chiang, Ken; Trumpis, Michael; Richardson, Andrew G.; Cheng, Huanyu; Fang, Hui; Thompson, Marissa; Bink, Hank; Talos, Delia; Seo, Kyung Jin; Lee, Hee Nam; Kang, Seung-Kyun; Kim, Jae-Hwan; Lee, Jung Yup; Huang, Younggang; Jensen, Frances E.; Dichter, Marc A.; Lucas, Timothy H.; Viventi, Jonathan; Litt, Brian; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioresorbable silicon electronics for transient spatiotemporal mapping of electrical activity from the cerebral cortex", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioresorbable silicon electronics technology offers unprecedented opportunities to deploy advanced implantable monitoring systems that eliminate risks, cost and discomfort associated with surgical extraction. Applications include postoperative monitoring and transient physiologic recording after percutaneous or minimally invasive placement of vascular, cardiac, orthopaedic, neural or other devices. We present an embodiment of these materials in both passive and actively addressed arrays of bioresorbable silicon electrodes with multiplexing capabilities, which record in vivo electrophysiological signals from the cortical surface and the subgaleal space. The devices detect normal physiologic and epileptiform activity, both in acute and chronic recordings. Comparative studies show sensor performance comparable to standard clinical systems and reduced tissue reactivity relative to conventional clinical electrocorticography (ECoG) electrodes. This technology offers general applicability in neural interfaces, with additional potential utility in treatment of disorders where transient monitoring and modulation of physiologic function, implant integrity and tissue recovery or regeneration are required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 15, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 782, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4624", "DOI Link": "http://dx.doi.org/10.1038/NMAT4624", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378347800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QM; Jackson, JA; Ge, Q; Hopkins, JB; Spadaccini, CM; Fang, NX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qiming; Jackson, Julie A.; Ge, Qi; Hopkins, Jonathan B.; Spadaccini, Christopher M.; Fang, Nicholas X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight Mechanical Metamaterials with Tunable Negative Thermal Expansion", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ice floating on water is a great manifestation of negative thermal expansion (NTE) in nature. The limited examples of natural materials possessing NTE have stimulated research on engineered structures. Previous studies on NTE structures were mostly focused on theoretical design with limited experimental demonstration in two-dimensional planar geometries. In this work, aided with multimaterial projection microstereolithography, we experimentally fabricate lightweight multimaterial lattices that exhibit significant negative thermal expansion in three directions and over a temperature range of 170 degrees. Such NTE is induced by the structural interaction of material components with distinct thermal expansion coefficients. The NTE can be tuned over a large range by varying the thermal expansion coefficient difference between constituent beams and geometrical arrangements. Our experimental results match qualitatively with a simple scaling law and quantitatively with computational models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2016, "Volume": 117, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 175901, "DOI": "10.1103/PhysRevLett.117.175901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.175901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386393300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Senkov, ON; Isheim, D; Seidman, DN; Pilchak, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Senkov, Oleg N.; Isheim, Dieter; Seidman, David N.; Pilchak, Adam L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of a Refractory High Entropy Superalloy", "Source Title": "ENTROPY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microstructure, phase composition and mechanical properties of a refractory high entropy superalloy, AlMo0.5NbTa0.5TiZr, are reported in this work. The alloy consists of a nullo-scale mixture of two phases produced by the decomposition from a high temperature body-centered cubic (BCC) phase. The first phase is present in the form of cuboidal-shaped nullo-precipitates aligned in rows along <100>-type directions, has a disordered BCC crystal structure with the lattice parameter a(1) = 326.9 +/- 0.5 pm and is rich in Mo, Nb and Ta. The second phase is present in the form of channels between the cuboidal nullo-precipitates, has an ordered B2 crystal structure with the lattice parameter a(2) = 330.4 +/- 0.5 pm and is rich in Al, Ti and Zr. Both phases are coherent and have the same crystallographic orientation within the former grains. The formation of this modulated nullo-phase structure is discussed in the framework of nucleation-and-growth and spinodal decomposition mechanisms. The yield strength of this refractory high entropy superalloy is superior to the yield strength of Ni-based superalloys in the temperature range of 20 degrees C to 1200 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 18, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.3390/e18030102", "DOI Link": "http://dx.doi.org/10.3390/e18030102", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373531600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vashishtha, P; Ng, M; Shivarudraiah, SB; Halpert, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vashishtha, Parth; Ng, Michael; Shivarudraiah, Sunil B.; Halpert, Jonathan E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Efficiency Blue and Green Light-Emitting Diodes Using Ruddlesden-Popper Inorganic Mixed Halide Perovskites with Butylammonium Interlayers", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ruddlesden-Popper phase inorganic metal halide perovskites are promising candidates for efficient light-emitting diodes (LEDs) with high brightness and color purity. Here, we demonstrate LEDs made from in situ grown CsPbX3 quasi 2D/3D thin films that are color tunable across the entire visible spectrum. CsPbX3 nullosheets are used to produce RP phase perovskites using butylammonium as a separating ligand to create BA(2)Cs(n-1)Pb(n) (Br/Y)(3n+1) 2D/3D mixed halide thin films, where Y = Cl or I. The number of CsPbBr3 monolayers in these crystals was optimized by changing the butylammonium concentration. We demonstrate a stable perovskite phase with thin emission line widths providing points covering the edge of the CIE triangle and a maximum red/green/blue coverage of similar to 130% of the National Television System Committee color standard. Additionally, we are able to report record efficiencies for blue emitting perovskite nullocrystal LEDs with a maximum external quantum efficiency (EQE) of 2.4% and 6.2% at 465 and 487 nm and a maximum luminullce of 3340 cd/m(2). We also demonstrate efficient green LEDs with a maximum efficiency of 10.1% EQE, 23.3 cd/A and 9.8 lm/W at 16.3 mA/cm(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2019, "Volume": 31, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 83, "End Page": 89, "Article Number": null, "DOI": "10.1021/acs.chemmater.8b02999", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.8b02999", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455558100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, RJ; Huang, JW; Barnard, ES; Hong, SS; Singh, P; Wong, EK; Jansen, T; Harbola, V; Xiao, J; Wang, BY; Crossley, S; Lu, D; Liu, S; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ruijuan; Huang, Jiawei; Barnard, Edward S.; Hong, Seung Sae; Singh, Prastuti; Wong, Ed K.; Jansen, Thies; Harbola, Varun; Xiao, Jun; Wang, Bai Yang; Crossley, Sam; Lu, Di; Liu, Shi; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain-induced room-temperature ferroelectricity in SrTiO3 membranes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in complex oxide heteroepitaxy have highlighted the enormous potential of utilizing strain engineering via lattice mismatch to control ferroelectricity in thin-film heterostructures. This approach, however, lacks the ability to produce large and continuously variable strain states, thus limiting the potential for designing and tuning the desired properties of ferroelectric films. Here, we observe and explore dynamic strain-induced ferroelectricity in SrTiO3 by laminating freestanding oxide films onto a stretchable polymer substrate. Using a combination of scanning probe microscopy, optical second harmonic generation measurements, and atomistic modeling, we demonstrate robust room-temperature ferroelectricity in SrTiO3 with 2.0% uniaxial tensile strain, corroborated by the notable features of 180 degrees ferroelectric domains and an extrapolated transition temperature of 400K. Our work reveals the enormous potential of employing oxide membranes to create and enhance ferroelectricity in environmentally benign lead-free oxides, which hold great promise for applications ranging from non-volatile memories and microwave electronics. Previous approach lacks the ability to produce large and continuously tunable strain states due to the limited number of available substrates. Here, the authors demonstrate strain-induced ferroelectricity in SrTiO3 membranes by laminating freestanding SrTiO3 films onto a stretchable polymer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16912-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16912-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545686200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, S; Feng, QH; Javadpour, F; Hu, QH; Wu, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sen; Feng, Qihong; Javadpour, Farzam; Hu, Qinhong; Wu, Keliu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Competitive adsorption of methane and ethane in montmorillonite nullopores of shale at supercritical conditions: A grand canonical Monte Carlo simulation study", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Because ethane acts apart from methane as a significant component in shale gas, knowledge of the competitive adsorption behavior of methane and ethane in shales, primarily under supercritical conditions, is crucial to understanding the fundamental mechanisms governing fluid storage, transport, and hydrocarbon production. Using grand canonical Monte Carlo simulations, we studied the adsorption behavior of single and binary mixtures of methane and ethane in montmorillonite slits having apertures ranging from 1.1 to 3.0 nm, for pressures up to 40 MPa over a temperature range of 333-393 K. The dependences of adsorption isotherms and selectivity on pore size, pressure, temperature, fluid composition, and water content were examined. With increasing pressure, the selectivity of ethane relative to methane decreases and tends to approach a constant smaller than unity, indicating that the adsorption propensity of ethane fails at higher pressures. The weaker interactions among adsorbate molecules, posterior adsorption saturation, and smaller molecular size of methane lead to its higher adsorption affinity at elevated pressures. Enlarging the pore or increasing the water content suppresses the selectivity of ethane over methane; selectivity decreases more steeply with pressure at lower temperatures. While there is only negligible selectivity variation with fluid composition at low pressures, the preferential adsorption of ethane at high pressures is facilitated by decreasing its mole fraction in the bulk fluid. We also discussed the implications of our work on shale gas exploitation. This study provides better insight into the storage mechanisms of shale gas and sheds light on the reliable estimation of gas-inplace and, more generally, competitive adsorption of mixtures in nulloporous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 355, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": 90, "Article Number": null, "DOI": "10.1016/j.cej.2018.08.067", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.08.067", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445416900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kurumaji, T; Nakajima, T; Hirschberger, M; Kikkawa, A; Yamasaki, Y; Sagayama, H; Nakao, H; Taguchi, Y; Arima, T; Tokura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kurumaji, Takashi; Nakajima, Taro; Hirschberger, Max; Kikkawa, Akiko; Yamasaki, Yuichi; Sagayama, Hajime; Nakao, Hironori; Taguchi, Yasujiro; Arima, Taka-hisa; Tokura, Yoshinori", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skyrmion lattice with a giant topological Hall effect in a frustrated triangular-lattice magnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Geometrically frustrated magnets can host complex spin textures, leading to unconventional electromagnetic responses. Magnetic frustration may also promote topologically nontrivial spin states such as magnetic skyrmions. Experimentally, however, skyrmions have largely been observed in noncentrosymmetric lattice structures or interfacial symmetry-breaking heterostructures. Here, we report the emergence of a Bloch-type skyrmion state in the frustrated centrosymmetric triangular-lattice magnet Gd2PdSi3. We observed a giant topological Hall response, indicating a field-induced skyrmion phase, which is further corroborated by the observation of in-plane spin modulation probed by resonullt x-ray scattering. Our results may lead to further discoveries of emergent electrodynamics in magnetically frustrated centrosymmetric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 512, "Times Cited, All Databases": 527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2019, "Volume": 365, "Issue": 6456, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 914, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau0968", "DOI Link": "http://dx.doi.org/10.1126/science.aau0968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483975800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HZ; Li, Q; Zheng, CQ; Hong, Y; Xu, ZQ; Wang, H; Shen, WD; Kaur, S; Ghosh, P; Qiu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Huanzheng; Li, Qiang; Zheng, Chunqi; Hong, Yu; Xu, Ziquan; Wang, Han; Shen, Weidong; Kaur, Sandeep; Ghosh, Pintu; Qiu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-temperature infrared camouflage with efficient thermal management", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-temperature infrared (IR) camouflage is crucial to the effective concealment of high-temperature objects but remains a challenging issue, as the thermal radiation of an object is proportional to the fourth power of temperature (T-4). Here, we experimentally demonstrate high-temperature IR camouflage with efficient thermal management. By combining a silica aerogel for thermal insulation and a Ge/ZnS multilayer wavelength-selective emitter for simultaneous radiative cooling (high emittance in the 5-8 mu m non-atmospheric window) and IR camouflage (low emittance in the 8-14 mu m atmospheric window), the surface temperature of an object is reduced from 873 to 410 K. The IR camouflage is demonstrated by indoor/outdoor (with/without earthshine) radiation temperatures of 310/248 K for an object at 873/623 K and a 78% reduction in with-earthshine lock-on range. This scheme may introduce opportunities for high-temperature thermal management and infrared signal processing. Thermal camouflage: hiding high-temperature objects The infrared signal from high-temperature structures such as jet engines and ship funnels could be significantly concealed by a composite material that reduces the radiation temperature of internally hot objects. Such infrared camouflaging is especially significant for military and civil applications, to reduce the threat from heat-seeking missiles and evade thermal imaging systems. Researchers in China, led by Qiang Li at Zhejiang University, built their layered thermal camouflage from a silica aerogel and a germanium/zinc sulfide blend. The highly porous aerogel forms effective insulation. The germanium/zinc sulfide layers achieve radiative cooling by emitting energy at wavelengths outside the atmosphere's window. In tests on objects with an internal temperature of 600 degrees C, the camouflage material reduced the surface temperature and the radiation temperature to 137 degrees C and 37 degrees C, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 60, "DOI": "10.1038/s41377-020-0300-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0300-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528683100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feuillastre, S; Pauton, M; Gao, LH; Desmarchelier, A; Riives, AJ; Prim, D; Tondelier, D; Geffroy, B; Muller, G; Clavier, G; Pieters, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feuillastre, Sophie; Pauton, Mathilde; Gao, Longhui; Desmarchelier, Alaric; Riives, Adrian J.; Prim, Damien; Tondelier, Denis; Geffroy, Bernard; Muller, Gilles; Clavier, Gilles; Pieters, Gregory", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work describes the first thermally activated delayed fluorescence material enabling circularly polarized light emission through chiral perturbation. These new molecular architectures obtained through a scalable one-pot sequential synthetic procedure at room temperature (83% yield) display high quantum yield (up to 74%) and circularly polarized luminescence with an.absolute luminescence dissymmetry factor, vertical bar g(lum)vertical bar, of 1.3 X 10(-3). These chiral molecules have been used as an emissive dopant in an organic light emitting diode exhibiting external quantum efficiency as high as 9.1%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2016, "Volume": 138, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3990, "End Page": 3993, "Article Number": null, "DOI": "10.1021/jacs.6b00850", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b00850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373518800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, RF; Qi, H; Ma, Y; Deng, YP; Liu, SN; Jie, YS; Jing, JZ; He, JL; Zhang, X; Wheatley, L; Huang, CX; Sheng, X; Zhang, ML; Yin, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Rongfeng; Qi, Hui; Ma, Yuan; Deng, Yuping; Liu, Shengnull; Jie, Yongsheng; Jing, Jinzhu; He, Jinlong; Zhang, Xu; Wheatley, Laura; Huang, Congxi; Sheng, Xing; Zhang, Milin; Yin, Lan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A flexible and physically transient electrochemical sensor for real-time wireless nitric oxide monitoring", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Real-time sensing of nitric oxide (NO) in physiological environments is critically important in monitoring neurotransmission, inflammatory responses, cardiovascular systems, etc. Conventional approaches for NO detection relying on indirect colorimetric measurement or built with rigid and permanent materials cannot provide continuous monitoring and/or require additional surgical retrieval of the implants, which comes with increased risks and hospital cost. Herein, we report a flexible, biologically degradable and wirelessly operated electrochemical sensor for real-time NO detection with a low detection limit (3.97 nmol), a wide sensing range (0.01-100 mu M), and desirable anti-interference characteristics. The device successfully captures NO evolution in cultured cells and organs, with results comparable to those obtained from the standard Griess assay. Incorporated with a wireless circuit, the sensor platform achieves continuous sensing of NO levels in living mammals for several days. The work may provide essential diagnostic and therapeutic information for health assessment, treatment optimization and postsurgical monitoring. Real-time continuous sensing of biological analytes is of importance in a range of biomedical applications. Here, the authors report on a flexible and physically transient sensor for the detection of nitric oxide and demonstrate applications in nitric oxide sensing in organs ex vivo and in vivo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17008-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17008-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549968400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZX; Wang, Q; Qiu, WN; Lyu, YT; Zhu, ZR; Zhao, XL; Zhu, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhenxing; Wang, Qi; Qiu, Wanshan; Lyu, Yanting; Zhu, Zhirong; Zhao, Xiaolei; Zhu, Wei-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "AIE-active luminogens as highly efficient free-radical ROS photogenerator for image-guided photodynamic therapy", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Image-guided photodynamic therapy (PDT) can realize highly precise and effective therapy via the integration of imaging and therapy, and has created high requirements for photosensitizers. However, the PDT modality usually utilizes conventional type II photosensitizers, resulting in unsatisfactory imaging and therapeutic outcomes due to aggregation-caused quenching (ACQ), always on fluorescence and strong oxygen dependence. Herein, we report the type I-based aggregation-induced emission (AIE) photosensitizer TCM-CPS with low oxygen dependence, near-infrared (NIR) emission and off-on fluorescence; in particular, it produces more reactive oxygen species (ROS) than commercially available Chlorin e6 and Rose Bengal. In the rational design of the AIE-based photosensitizer TCM-CPS, the strongly electron-donating carbazole unit and pi-thiophene bridge distinctly extend the emission wavelength and decrease the autofluorescence interference in bio-imaging, and the hydrophilic pyridinium salt group guarantees good molecular dispersion and maintains the fluorescence-off state in the aqueous system to decrease the initial fluorescence background. Moreover, the strong donor-pi-acceptor (D-pi-A) character in TCM-CPS greatly separates the HOMO-LUMO distribution, enhancing the ROS generation, and TCM-CPS was constructed as a type I photosensitizer with the assistance of strong intramolecular charge transfer in the electron-rich anion-pi(+) structure. Based on its favorable hydrophilicity and photosensitivity, TCM-CPS was found to be a highly efficient free-radical ROS photogenerator for both visualizing cells using light-up NIR fluorescence and efficiently killing cancer cells upon light irradiation. The positively charged TCM-CPS could quickly bind to bacteria via electrostatic interactions to provide a light-up signal and kill bacteria at a low concentration. In the PDT treatment of bacteria-infected mice, the mice exhibited accelerated wound healing with low wound infection. Thus, the AIE-based type I photosensitizer TCM-CPS has great potential to replace commercially available photosensitizers in the image-guided PDT modality for the treatment of cancer and bacterial infection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2022, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3599, "End Page": 3608, "Article Number": null, "DOI": "10.1039/d2sc00067a", "DOI Link": "http://dx.doi.org/10.1039/d2sc00067a", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765899600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, H; Xu, ZW; Hu, ZY; Yin, ZW; Wang, Z; Deng, Z; Wei, P; Feng, SH; Dong, SH; Liu, JF; Luo, SC; Qiu, ZD; Zhou, L; Mai, LQ; Su, BL; Zhao, DY; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Hui; Xu, Zhewei; Hu, Zhi-Yi; Yin, Zhiwen; Wang, Zhao; Deng, Zhao; Wei, Ping; Feng, Shihao; Dong, Shunhong; Liu, Jinfeng; Luo, Sicheng; Qiu, Zhaodong; Zhou, Liang; Mai, Liqiang; Su, Bao-Lian; Zhao, Dongyuan; Liu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesoporous Pt@Pt-skin Pt3Ni core-shell framework nullowire electrocatalyst for efficient oxygen reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of Pt-based nulloarchitectures with controllable compositions and morphologies is necessary to enhance their electrocatalytic activity. Herein, we report a rational design and synthesis of anisotropic mesoporous Pt@Pt-skin Pt3Ni core-shell framework nullowires for high-efficient electrocatalysis. The catalyst has a uniform core-shell structure with an ultrathin atomic-jagged Pt nullowire core and a mesoporous Pt-skin Pt3Ni framework shell, possessing high electrocatalytic activity, stability and Pt utilisation efficiency. For the oxygen reduction reaction, the anisotropic mesoporous Pt@Pt-skin Pt3Ni core-shell framework nullowires demonstrated exceptional mass and specific activities of 6.69 A/mg(pt) and 8.42 mA/cm(2) (at 0.9 V versus reversible hydrogen electrode), and the catalyst exhibited high stability with negligible activity decay after 50,000 cycles. The mesoporous Pt@Pt-skin Pt3Ni core-shell framework nullowire configuration combines the advantages of three-dimensional open mesopore molecular accessibility and compressive Pt-skin surface strains, which results in more catalytically active sites and weakened chemisorption of oxygenated species, thus boosting its catalytic activity and stability towards electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1518, "DOI": "10.1038/s41467-023-37268-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37268-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000957141600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, XX; Chen, RH; null, ZA; Lv, XD; Meng, RQ; Cao, J; Tang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Xiaoxia; Chen, Ruihao; null, Zi-Ang; Lv, Xudong; Meng, Ruiqian; Cao, Jing; Tang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perfection of Perovskite Grain Boundary Passivation by Eu-Porphyrin Complex for Overall-Stable Perovskite Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of defects at surfaces and grain boundaries (GBs) during the fabrication of solution-processed perovskite film are thought to be responsible for its instability. Herein, Eu-porphyrin complex (Eu-pyP) is directly doped into methylammonium lead triiodide (MAPbI(3)) precursor, perfectly fabricating 2D (Eu-pyP)(0.5)MA(n-1)Pb(n)I(3n+1) platelets inlaying the GBs of 3D polycrystalline interstices in this protocol. The device based on Eu-pyP doped perovskite film possesses a champion efficiency of 18.2%. More importantly, the doped perovskite solar cells device shows beyond 85% retention of its pristine efficiency value, whereas the pure MAPbI(3) device has a rapid drop in efficiency down to 10% within 100 h under 45% humidity at 85 degrees C in AM 1.5 G. The above acquired perovskite films reveal an unpredictable thermodynamic self-healing ability. Consequently, the findings provide an avenue for defect passivation to synchronously improve resistibility to moisture, heat, and solar light including UV.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802040, "DOI": "10.1002/advs.201802040", "DOI Link": "http://dx.doi.org/10.1002/advs.201802040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460374300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, K; Tong, GSM; Wan, QY; Cheng, G; Tong, WY; Ang, WH; Kwong, WL; Che, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Kai; Tong, Glenna So Ming; Wan, Qingyun; Cheng, Gang; Tong, Wai-Yip; Ang, Wai-Hung; Kwong, Wai-Lun; Che, Chi-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly phosphorescent platinum(II) emitters: photophysics, materials and biological applications", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years a blossoming interest in the synthesis, photophysics and application of phosphorescent Pt(II) complexes, particularly on their uses in bioimaging, photocatalysis and phosphorescent organic light-emitting diodes (OLEDs), has been witnessed. The superior performance of phosphorescent Pt(II) complexes in these applications is linked to their diverse spectroscopic and photophysical properties, which can be systematically modulated by appropriate choices of auxiliary ligands. Meanwhile, an important criterion for the practical application of phosphorescent metal complexes is their stability which is crucial for biological utilization and industrial OLED applications. Taking both the luminescence properties and stability into consideration, chelating ligands having rigid scaffolds and with strong sigma-donor atoms are advantageous for the construction of highly robust phosphorescent Pt(II) complexes. The square-planar coordination geometry endows Pt(II) complexes with the intriguing spectroscopic and photophysical properties associated with their intermolecular interactions in both the ground and excited states. In this article, we discuss the design and synthesis of phosphorescent Pt(II) complexes with elaboration on the effects of ligands on the structure and luminescence properties. Based on their photophysical and emission properties, we intend to shed light on the great promise of highly robust phosphorescent Pt(II) emitters in an array of applications from molecular materials to biosensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1653, "End Page": 1673, "Article Number": null, "DOI": "10.1039/c5sc03766b", "DOI Link": "http://dx.doi.org/10.1039/c5sc03766b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371021900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sommer, F; Dietze, V; Baum, A; Sauer, J; Gilge, S; Maschowski, C; Gieré, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sommer, Frank; Dietze, Volker; Baum, Anja; Sauer, Jan; Gilge, Stefan; Maschowski, Christoph; Giere, Reto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tire Abrasion as a Major Source of Microplastics in the Environment", "Source Title": "AEROSOL AND AIR QUALITY RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traffic-related non-exhaust particulate matter mainly consists of tire wear, brake wear, and road wear. For this study, passive-samplers were placed near highly frequented roads in industrial, agricultural, and urban environments with the aim of collecting and characterizing super-coarse (> 10 mu m) airborne particles. Single-particle analysis using SEM-EDX was conducted on more than 500 particles with nearly 1500 spectra to determine their size, shape, volume, and chemical composition. The ambient aerosol near all studied roads is dominated by traffic-related abrasion particles, amounting to approximately 90 vol%. The majority of the particles were composites of tire-, road-, and brake-abrasion material. The particle assemblages differed in size distribution, composition, and structure depending on driving speed, traffic flow, and traffic fleet. Our study documents that tire wear significantly contributes to the flux of microplastics into the environment. A decrease in the release of this abrasion material, however, is unlikely in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 18, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2014, "End Page": 2028, "Article Number": null, "DOI": "10.4209/aaqr.2018.03.0099", "DOI Link": "http://dx.doi.org/10.4209/aaqr.2018.03.0099", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440053100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sugiarto, S; Leow, Y; Tan, CL; Wang, G; Kai, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sugiarto, Sigit; Leow, Yihao; Tan, Chong Li; Wang, Guan; Kai, Dan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How far is Lignin from being a biomedical material?", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignin is a versatile biomass that possesses many different desirable properties such as antioxidant, antibacterial, anti-UV, and good biocompatibility. Natural lignin can be processed through several chemical processes. The processed lignin can be modified into functionalized lignin through chemical modifications to develop and enhance biomaterials. Thus, lignin is one of the prime candidate for various biomaterial applications such as drug and gene delivery, biosensors, bioimaging, 3D printing, tissue engineering, and dietary supplement additive. This review presents the potential of developing and utilizing lignin in the outlook of new and sustainable biomaterials. Thereafter, we also discuss on the challenges and outlook of utilizing lignin as a biomaterial.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 94, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.06.023", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.06.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751867500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, JC; Tang, XW; Peng, YD; Fan, CH; Li, L; Zhang, C; Lai, FL; He, GJ; Ma, PM; Wang, ZC; Wei, QF; Yan, XP; Qian, HL; Huang, YP; Liu, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Jiancheng; Tang, Xinwei; Peng, Yidong; Fan, Chonghui; Li, Le; Zhang, Chao; Lai, Feili; He, Guanjie; Ma, Piming; Wang, Zicheng; Wei, Qufu; Yan, Xiu-Ping; Qian, Hai-Long; Huang, Yunpeng; Liu, Tianxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly permeable and ultrastretchable E-textiles with EGaIn-superlyophilicity for on-skin health monitoring, joule heating, and electromagnetic shielding", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The prosperity of wearable and healthcare electronics yearns for the compact integration of multi-functionalities including detectability for various electrophysiological signals, thermal/moisture management, and electro-magnetic wave protection. Herein, highly breathable and ultrastretchable styrene-ethylene-butylene-styrene (SEBS)-Ag-liquid metal (SSLM) nonwoven electronic textiles are fabricated as versatile on-skin bioelectrodes for accurate health monitoring, Joule heating, and electromagnetic interface (EMI) shielding. Taking advantage of the reactive alloying between liquid metal and magnetron sputtered silver nulloparticles, ultra-conductive eutectic gallium-indium (EGaIn) is intimately and uniformly encapsulated on superlyophilic SEBS microfibers after activation via monolithic pre-stretching. Benefiting from the highly deformable, extremely stable, and 3D interconnected conducting networks, the nonwoven E-textiles demonstrate exceptional EMI shielding effec-tiveness (75.3 dB at frequencies of 8.2-12.8 GHz, and still maintain 31.7 dB at 300% elongation), and efficient Joule heating performance also under large-scale deformation (120%). Moreover, the breathable SSLM E-textiles used as skin-attachable bioelectrodes even manifest prominent monitoring performance for biophysical signals (breath, phonation, and joint bending), surface electromyography signals (sEMG), and electroencephalogram signals (EEG). Therefore, the superlyophilicity and superior performance of the liquid metal E-textiles enable a wide range of applications in next-generation skin electronics and protective textiles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108194, "DOI": "10.1016/j.nulloen.2023.108194", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2023.108194", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923182800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ZS; Ye, XY; Zhang, SJ; Xue, SK; Yang, C; Hou, YD; Xing, WD; Yu, R; Sun, J; Yu, ZY; Wang, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhishan; Ye, Xiaoyuan; Zhang, Shijia; Xue, Sikang; Yang, Can; Hou, Yidong; Xing, Wandong; Yu, Rong; Sun, Jie; Yu, Zhiyang; Wang, Xinchen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the charge transfer dynamics steered by built-in electric fields in BiOBr photocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While internal electric fields alter charge-separation dynamics in solar-to-chemical conversions, a greater understanding of such processes is necessary. Here, authors analyze charge transfer dynamics modulated by built-in electric fields and identify carrier drift distances as a critical parameter. Construction of internal electric fields (IEFs) is crucial to realize efficient charge separation for charge-induced redox reactions, such as water splitting and CO2 reduction. However, a quantitative understanding of the charge transfer dynamics modulated by IEFs remains elusive. Here, electron microscopy study unveils that the non-equilibrium photo-excited electrons are collectively steered by two contiguous IEFs within binary (001)/(200) facet junctions of BiOBr platelets, and they exhibit characteristic Gaussian distribution profiles on reduction facets by using metal co-catalysts as probes. An analytical model justifies the Gaussian curve and allows us to measure the diffusion length and drift distance of electrons. The charge separation efficiency, as well as photocatalytic performances, are maximized when the platelet size is about twice the drift distance, either by tailoring particle dimensions or tuning IEF-dependent drift distances. The work offers great flexibility for precisely constructing high-performance particulate photocatalysts by understanding charge transfer dynamics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2230, "DOI": "10.1038/s41467-022-29825-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29825-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787388900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Keber, FC; Loiseau, E; Sanchez, T; DeCamp, SJ; Giomi, L; Bowick, MJ; Marchetti, MC; Dogic, Z; Bausch, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Keber, Felix C.; Loiseau, Etienne; Sanchez, Tim; DeCamp, Stephen J.; Giomi, Luca; Bowick, Mark J.; Marchetti, M. Cristina; Dogic, Zvonimir; Bausch, Andreas R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topology and dynamics of active nematic vesicles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering synthetic materials that mimic the remarkable complexity of living organisms is a fundamental challenge in science and technology. We studied the spatiotemporal patterns that emerge when an active nematic film of microtubules and molecular motors is encapsulated within a shape-changing lipid vesicle. Unlike in equilibrium systems, where defects are largely static structures, in active nematics defects move spontaneously and can be described as self-propelled particles. The combination of activity, topological constraints, and vesicle deformability produces a myriad of dynamical states. We highlight two dynamical modes: a tunable periodic state that oscillates between two defect configurations, and shape-changing vesicles with streaming filopodia-like protrusions. These results demonstrate how biomimetic materials can be obtained when topological constraints are used to control the non-equilibrium dynamics of active matter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 501, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2014, "Volume": 345, "Issue": 6201, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1135, "End Page": 1139, "Article Number": null, "DOI": "10.1126/science.1254784", "DOI Link": "http://dx.doi.org/10.1126/science.1254784", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341179800036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, B; Zhang, Z; Zou, YC; Xu, K; Xu, GY; Wang, H; Meng, H; Deng, YH; Li, J; Gu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Bing; Zhang, Zhen; Zou, Yucheng; Xu, Kang; Xu, Guiyin; Wang, Hong; Meng, Hong; Deng, Yonghong; Li, Ju; Gu, Meng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poor Stability of Li2CO3 in the Solid Electrolyte Interphase of a Lithium-Metal Anode Revealed by Cryo-Electron Microscopy", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The solid electrolyte interphase (SEI) dictates the cycling stability of lithium-metal batteries. Here, direct atomic imaging of the SEI's phase components and their spatial arrangement is achieved, using ultralow-dosage cryogenic transmission electron microscopy. The results show that, surprisingly, a lot of the deposited Li metal has amorphous atomic structure, likely due to carbon and oxygen impurities, and that crystalline lithium carbonate is not stable and readily decomposes when contacting the lithium metal. Lithium carbonate distributed in the outer SEI also continuously reacts with the electrolyte to produce gas, resulting in a dynamically evolving and porous SEI. Sulfur-containing additives cause the SEI to preferentially generate Li2SO4 and overlithiated lithium sulfate and lithium oxide, which encapsulate lithium carbonate in the middle, limiting SEI thickening and enhancing battery life by a factor of ten. The spatial mapping of the SEI gradient amorphous (polymeric -> inorganic -> metallic) and crystalline phase components provides guidance for designing electrolyte additives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 33, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100404, "DOI": "10.1002/adma.202100404", "DOI Link": "http://dx.doi.org/10.1002/adma.202100404", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000643567600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, Y; Zheng, Y; Jin, J; Wang, YT; Peng, Y; Yin, J; Shen, W; Hou, YC; Zhu, L; An, L; Lu, M; Xi, PX; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yang; Zheng, Yao; Jin, Jing; Wang, Yantao; Peng, Yong; Yin, Jie; Shen, Wei; Hou, Yichao; Zhu, Liu; An, Li; Lu, Min; Xi, Pinxian; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the sulphur-oxygen exchange process of metal sulphides prior to oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dynamic reconstruction of metal sulphides during electrocatalytic oxygen evolution reaction is a key aspect of study. Herein, modelling on a series of cobalt-nickel bimetallic sulphides, the authors reveal a dynamic phase evaluation pathway and the S-O substitution process occurring on the catalytic surface at the pre-catalytic stage. Dynamic reconstruction of metal sulphides during electrocatalytic oxygen evolution reaction (OER) has hampered the acquisition of legible evidence for comprehensively understanding the phase-transition mechanism and electrocatalytic activity origin. Herein, modelling on a series of cobalt-nickel bimetallic sulphides, we for the first time establish an explicit and comprehensive picture of their dynamic phase evaluation pathway at the pre-catalytic stage before OER process. By utilizing the in-situ electrochemical transmission electron microscopy and electron energy loss spectroscopy, the lattice sulphur atoms of (NiCo)S-1.33 particles are revealed to be partially substituted by oxygen from electrolyte to form a lattice oxygen-sulphur coexisting shell surface before the generation of reconstituted active species. Such S-O exchange process is benefitted from the subtle modulation of metal-sulphur coordination form caused by the specific Ni and Co occupation. This unique oxygen-substitution behaviour produces an (NiCo)OxS1.33-x surface to reduce the energy barrier of surface reconstruction for converting sulphides into active oxy/hydroxide derivative, therefore significantly increasing the proportion of lattice oxygen-mediated mechanism compared to the pure sulphide surface. We anticipate this direct observation can provide an explicit picture of catalysts' structural and compositional evolution during the electrocatalytic process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1949, "DOI": "10.1038/s41467-023-37751-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37751-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002598300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, ZB; Qu, C; Zhou, WY; Zhao, R; Zhang, H; Zhu, BJ; Guo, WH; Meng, W; Wu, YX; Aftab, W; Wang, Q; Zou, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Zibin; Qu, Chong; Zhou, Wenyang; Zhao, Ruo; Zhang, Hao; Zhu, Bingjun; Guo, Wenhan; Meng, Wei; Wu, Yingxiao; Aftab, Waseem; Wang, Qian; Zou, Ruqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Effect of Co-Ni Hybrid Phosphide nullocages for Ultrahigh Capacity Fast Energy Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of metal compounds in terms of the structure morphology and chemical composition is essential to achieve desirable electrochemical performances for fast energy storage because of the synergistic effect between different elements and the structure effect. Here, an approach is presented to facilely fabricate mixed-metal compounds including hydroxides, phosphides, sulfides, oxides, and selenides with well-defined hollow nullocage structure using metal-organic framework nullocrystals as sacrificial precursors. Among the as-synthesized samples, the porous nullocage structure, synergistic effect of mixed metals, and unique phosphide composition endow nickel cobalt bimetallic phosphide (NiCo-P) nullocages with outstanding performance as a battery-type Faradaic electrode material for fast energy storage, with ultrahigh specific capacity of 894 C g(-1) at 1 A g(-1) and excellent rate capability, surpassing most of the reported metal compounds. Control experiments and theoretical calculations based on density functional theory reveal that the synergistic effect between Ni and Co in NiCo-P can greatly increase the OH- adsorption energy, while the hollow porous structure facilitates the fast mass/electron transport. The presented work not only provides a promising electrode material for fast energy storage, but also opens a new route toward structural and compositional design of electrode materials for energy storage and conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802005, "DOI": "10.1002/advs.201802005", "DOI Link": "http://dx.doi.org/10.1002/advs.201802005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464827300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, L; Cao, H; Xue, C; Zhang, H; Qin, MC; Wang, J; Wen, KC; Fu, ZW; Jiang, T; Xu, L; Zhang, Y; Cao, Y; Tu, C; Zhang, J; Liu, DW; Zhang, GB; Kong, DC; Fan, N; Li, GQ; Yi, C; Peng, QM; Chang, J; Lu, XH; Wang, NN; Huang, W; Wang, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Lin; Cao, Hui; Xue, Chen; Zhang, Hao; Qin, Minchao; Wang, Jie; Wen, Kaichuan; Fu, Zewu; Jiang, Tao; Xu, Lei; Zhang, Ya; Cao, Yu; Tu, Cailing; Zhang, Ju; Liu, Dawei; Zhang, Guangbin; Kong, Decheng; Fan, Ning; Li, Gongqiang; Yi, Chang; Peng, Qiming; Chang, Jin; Lu, Xinhui; Wang, nulla; Huang, Wei; Wang, Jianpu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the additive-assisted oriented growth of perovskite crystallite for high performance light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed metal halide perovskites have been recognized as one of the most promising semiconductors, with applications in light-emitting diodes (LEDs), solar cells and lasers. Various additives have been widely used in perovskite precursor solutions, aiming to improve the formed perovskite film quality through passivating defects and controlling the crystallinity. The additive's role of defect passivation has been intensively investigated, while a deep understanding of how additives influence the crystallization process of perovskites is lacking. Here, we reveal a general additive-assisted crystal formation pathway for FAPbI(3) perovskite with vertical orientation, by tracking the chemical interaction in the precursor solution and crystallographic evolution during the film formation process. The resulting understanding motivates us to use a new additive with multi-functional groups, 2-(2-(2-Aminoethoxy)ethoxy)acetic acid, which can facilitate the orientated growth of perovskite and passivate defects, leading to perovskite layer with high crystallinity and low defect density and thereby record-high performance NIR perovskite LEDs (similar to 800 nm emission peak, a peak external quantum efficiency of 22.2% with enhanced stability).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5081, "DOI": "10.1038/s41467-021-25407-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25407-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687672000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, MM; Huang, JW; Xie, XS; Li, TC; Huang, JT; Liang, SQ; Zhou, J; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Mingming; Huang, Jiwu; Xie, Xuesong; Li, Tian Chen; Huang, Jiangtao; Liang, Shuquan; Zhou, Jiang; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrated Eutectic Electrolyte with Ligand-Oriented Solvation Shell to Boost the Stability of Zinc Battery", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the substantial progress in cathode materials in the past few years, rechargeable zinc batteries (RZBs) are plagued by rapid performance degradation due to dendrite formation and notorious side reactions at the Zn anode side. Here, an optimized hydrated eutectic electrolyte (HEE) system containing methylsulfonylmethane, zinc perchlorate, and water, in which an organic ligand coordinated the solvation shell of Zn ions with water molecules constituting the eutectic network, is proposed. Compared to common aqueous solutions, this HEE system is proven effective in promoting the smooth Zn deposition and plating/stripping reversibility as well as suppressing side reactions. The vanadium-based zinc batteries based on this new HEE exhibit exceptionally high-capacity retention (approximate to 100% retention even after 1600 cycles at a relatively small current density of 1000 mA g(-1)). This study offers a new type of electrolyte for RZBs and a deep understanding of the effect of Zn2+ solvent sheath structure on the cycle reversibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 32, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110957, "DOI": "10.1002/adfm.202110957", "DOI Link": "http://dx.doi.org/10.1002/adfm.202110957", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770784200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trang, TTT; Zhang, JH; Kim, JH; Zargaran, A; Hwang, JH; Suh, BC; Kim, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trang, T. T. T.; Zhang, J. H.; Kim, J. H.; Zargaran, A.; Hwang, J. H.; Suh, B. -C.; Kim, N. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing a magnesium alloy with high strength and high formability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although magnesium alloys, as the lightest structural alloys, offer significant potential for automotive applications, their applications remain limited due to their poor formability at room temperature. Since the strategies used for improving formability usually result in a degradation of strength, there are no high strength magnesium alloys showing good formability. Here we report an alloy design concept that can simultaneously provide high strength and good formability. Such designed alloy when subjected to an appropriate processing technique shows a combination of strength and formability that surpasses those of the existing magnesium alloys reported so far. The alloy design concept used in the present study is based on the utilization of alloying elements that can induce precipitation, as well as maximize the segregation of other texture-controlling alloying elements. Such developed alloy is expected to broaden the application of Mg alloy sheets, which are now starting to gain acceptance by automotive industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2522, "DOI": "10.1038/s41467-018-04981-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04981-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436548700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geiger, S; Kasian, O; Ledendecker, M; Pizzutilo, E; Mingers, AM; Fu, WT; Diaz-Morales, O; Li, ZZ; Oellers, T; Fruchter, L; Ludwig, A; Mayrhofer, KJJ; Koper, MTM; Cherevko, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geiger, Simon; Kasian, Olga; Ledendecker, Marc; Pizzutilo, Enrico; Mingers, Andrea M.; Fu, Wen Tian; Diaz-Morales, Oscar; Li, Zhizhong; Oellers, Tobias; Fruchter, Luc; Ludwig, Alfred; Mayrhofer, Karl J. J.; Koper, Marc T. M.; Cherevko, Serhiy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The stability number as a metric for electrocatalyst stability benchmarking", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing the noble metal loading and increasing the specific activity of the oxygen evolution catalysts are omnipresent challenges in proton-exchange-membrane water electrolysis, which have recently been tackled by utilizing mixed oxides of noble and non-noble elements. However, proper verification of the stability of these materials is still pending. Here we introduce a metric to explore the dissolution processes of various iridium-based oxides, defined as the ratio between the amounts of evolved oxygen and dissolved iridium. The so-called stability number is independent of loading, surface area or involved active sites and provides a reasonable comparison of diverse materials with respect to stability. The case study on iridium-based perovskites shows that leaching of the non-noble elements in mixed oxides leads to the formation of highly active amorphous iridium oxide, the instability of which is explained by the generation of short-lived vacancies that favour dissolution. These insights are meant to guide further research, which should be devoted to increasing the utilization of highly durable pure crystalline iridium oxide and finding solutions to stabilize amorphous iridium oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 678, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 1, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 508, "End Page": 515, "Article Number": null, "DOI": "10.1038/s41929-018-0085-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0085-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446621500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Z; Chen, N; Yi, ZG; Zhong, JW; Zhang, FL; Ji, SB; Liao, R; Wang, Y; Li, HC; Liu, ZH; Wang, Y; Yokota, T; Liu, XG; Fukuda, K; Chen, XD; Someya, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Zhi; Chen, Nuan; Yi, Zhigao; Zhong, Junwen; Zhang, Feilong; Ji, Shaobo; Liao, Rui; Wang, Yan; Li, Haicheng; Liu, Zhihua; Wang, Yang; Yokota, Tomoyuki; Liu, Xiaogang; Fukuda, Kenjiro; Chen, Xiaodong; Someya, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 1.3-micrometre-thick elastic conductor for seamless on-skin and implantable sensors", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydimethylsiloxane-gold conductors that are 1.3 mu m thick and have controlled morphology of microcracks in the gold film can be used to create breathable and water-resistant electrodes for recording electrocardiogram signals, as well as on-skin pressure sensors and implantable nerve electrodes. On-skin and implantable electronics require elastic conductors that are only a few micrometres thick and soft enough to form a seamless contact with three-dimensional structures. However, fabricating thin conductors that are mechanically durable and have consistent electrical properties with stretching is challenging. Here we report polydimethylsiloxane (PDMS)-gold conductors that are around 1.3 mu m thick and have a controlled morphology of microcracks in the gold film. The microcracks are formed by evaporating a 50-nm-thick gold film onto a 1.2-mu m-thick PDMS film that is supported during fabrication by a 100-mu m-thick PDMS film on glass; thermal expansion of the thick PDMS film causes the evaporated gold to form a microcracked structure on the thin PDMS. The resulting conductors can be stretched by up to 300% and remain highly conductive after strain release. We use them to create on-skin electrodes that are breathable and water resistant, and can continuously record electrocardiogram signals. We also use the conductors to create on-skin sensors with less than 3 mu m thickness that can detect small mechanical forces and create implantable nerve electrodes that can provide signal recording and stimulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 784, "End Page": 793, "Article Number": null, "DOI": "10.1038/s41928-022-00868-x", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00868-x", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000886183800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Xiang, L; Zhang, JW; Liu, C; Wang, ZK; Zeng, HB; Xu, ZK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chao; Xiang, Li; Zhang, Jiawen; Liu, Chang; Wang, Zuankai; Zeng, Hongbo; Xu, Zhi-Kang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revisiting the adhesion mechanism of mussel-inspired chemistry", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mussel-inspired chemistry has become an ideal platform to engineer a myriad of functional materials, but fully understanding the underlying adhesion mechanism is still missing. Particularly, one of the most pivotal questions is whether catechol still plays a dominullt role in molecular-scale adhesion like that in mussel adhesive proteins. Herein, for the first time, we reveal an unexplored adhesion mechanism of mussel-inspired chemistry that is strongly dictated by 5,6-dihydroxyindole (DHI) moieties, amending the conventional viewpoint of catechol-dominated adhesion. We demonstrate that polydopamine (PDA) delivers an unprecedented adhesion of 71.62 mN m(-1), which surpasses that of many mussel-inspired derivatives and is even 121-fold higher than that of polycatechol. Such a robust adhesion mainly stems from a high yield of DHI moieties through a delicate synergy of leading oxidation and subsidiary cyclization within self-polymerization, allowing for governing mussel-inspired adhesion by the substituent chemistry and self-polymerization manner. The adhesion mechanisms revealed in this work offer a useful paradigm for the exploitation of functional mussel-inspired materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2022, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1698, "End Page": 1705, "Article Number": null, "DOI": "10.1039/d1sc05512g", "DOI Link": "http://dx.doi.org/10.1039/d1sc05512g", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745041500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, EJ; Sharafi, A; Sakamoto, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte", "Source Title": "ELECTROCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The potential to enable unprecedented performance, durability, and safety has created the impetus to develop bulk-scale all-solid-state batteries employing metallic Li as the negative electrode. Owing to its low density, low electronegativity and high specific capacity, Li metal is the most attractive negative electrode. However, failure caused by the formation of dendrites has limited the widespread use of rechargeable batteries using metallic Li negative electrodes coupled with liquid electrolytes. One approach to mitigate the formation of dendrites involves the use of a solid electrolyte to physically stabilize the Li-electrolyte interface while allowing the facile transport of Li-ions. Though in principle this approach should work, it has been observed that at high Li deposition rates Li metal can propagate through relatively hard ceramic electrolytes and Li dendrite formation causing short circuit has been reported. Why this occurs is poorly understood, erhphasizing the need to close the knowledge gap and facilitate the development of advanced batteries employing solid electrolytes. Here, through precise microstructural control, striking electron microscopy, and high-resolution surface spectroscopy, we directly observed for the first time the propagation of Li metal through a promising polycrystalline solid electrolyte based on the garnet mineral structure (Li6.25Al0.25La3Zr2O12). Moreover, we observed that Li preferentially deposits along grain boundaries (intergranularly). These results offer insight into the electrochemical-mechanical phenomena that govern the stability of the metallic Li-polycrystalline solid electrolyte interface and are essential to the maturation of solid-state batteries. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 571, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2017, "Volume": 223, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 85, "End Page": 91, "Article Number": null, "DOI": "10.1016/j.electacta.2016.12.018", "DOI Link": "http://dx.doi.org/10.1016/j.electacta.2016.12.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392773100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shirayama, M; Kadowaki, H; Miyadera, T; Sugita, T; Tamakoshi, M; Kato, M; Fujiseki, T; Murata, D; Hara, S; Murakami, TN; Fujimoto, S; Chikamatsu, M; Fujiwara, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shirayama, Masaki; Kadowaki, Hideyuki; Miyadera, Tetsuhiko; Sugita, Takeshi; Tamakoshi, Masato; Kato, Masato; Fujiseki, Takemasa; Murata, Daisuke; Hara, Shota; Murakami, Takurou N.; Fujimoto, Shohei; Chikamatsu, Masayuki; Fujiwara, Hiroyuki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical Transitions in Hybrid Perovskite Solar Cells: Ellipsometry, Density Functional Theory, and Quantum Efficiency Analyses for CH3NH3PbI3", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-induced photocarrier generation is an essential process in all solar cells, including organic inorganic hybrid (CH3NH3PbI3) solar cells, which exhibit a high short-circuit current density (J(sc)) of approximately 20 mA/cm(2). Although the high J observed in the hybrid solar cells relies on strong electron-photon interaction, the optical transitions in the perovskite material remain unclear. Here, we report artifact-free CH3NH3PbI3 optical constants extracted from ultrasmooth perovskite layers without air exposure and assign all of the optical transitions in the visible and ultraviolet region unambiguously, based on density-functional theory (DFT) analysis that assumes a simple pseudocubic crystal structure. From the self-consistent spectroscopic ellipsometry analysis of the ultrasmooth CH3NH3PbI3 layers, we find that the absorption coefficients of CH3NH3PbI3 (alpha = 3.8 x 10(4) cm(-1) at 2.0 eV) are comparable to those of CuInGaSe, and CdTe, and high a values reported in earlier studies are overestimated seriously by the extensive surface roughness of CH3NE3PbI3 layers. The polarization-dependent DFT calculations show that CH3NE3 interacts strongly with the PbI3-cage, modifying the CH3NE3PbI3 dielectric function in the visible region rather significantly. In particular, the transition matrix element of CH3NH3Pb11 varies, depending on the position of CH3NH3 within the Pb-1 network. When the effect of CH3NH3 on the optical transition is eliminated in the D1-1 calculation, the CH3NH3PbI3 dielectric function deduced from DFT shows an excellent agreement with the experimental result. As a result, distinct optical transitions observed at E-o(E-g) = 1.61 eV, El = 2.53 eV, and E-2, = 3.24 eV in CH3NH3PbI3 are attributed to the direct semiconductor-type transitions at the R, M, and X points in the pseudocubic Brillouin zone, respectively. We further perform the quantum efficiency (QE) analysis for a standard hybrid-perovskite solar cell incorporating a mesoporous TiO, layer and demonstrate that the QE spectrum can be reproduced almost perfectly when the revised CELNH3PbL optical constants are employed. Depth-resolved QE simulations confirm that J(sc) is limited by the material's longer wavelength response and indicate the importance of optical confinement and long carrier-diffusion lengths in hybrid perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2016, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14012, "DOI": "10.1103/PhysRevApplied.5.014012", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.5.014012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369340400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bondue, CJ; Graf, M; Goyal, A; Koper, MTM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bondue, Christoph J.; Graf, Matthias; Goyal, Akansha; Koper, Marc T. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppression of Hydrogen Evolution in Acidic Electrolytes by Electrochemical CO2 Reduction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this article we investigate the electrochemical reduction of CO2 at gold electrodes under mildly acidic conditions. Differential electrochemical mass spectroscopy (DEMS) is used to quantify the amounts of formed hydrogen and carbon monoxide as well as the consumed amount of CO2. We investigate how the Faradaic efficiency of CO formation is affected by the CO2 partial pressure (0.1-0.5 bar) and the proton concentration (1-0.25 mM). Increasing the former enhances the rate of CO2 reduction and suppresses hydrogen evolution from proton reduction, leading to Faradaic efficiencies close to 100%. Hydrogen evolution is suppressed by CO2 reduction as all protons at the electrode surfaces are used to support the formation of water (CO2 + 2H(+) + 2e(-) -> CO + H2O). Under conditions of slow mass transport, this leaves no protons to support hydrogen evolution. On the basis of our results, we derive a general design principle for acid CO2 electrolyzers to suppress hydrogen evolution from proton reduction: the rate of CO/OH- formation must be high enough to match/compensate the mass transfer of protons to the electrode surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2021, "Volume": 143, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 279, "End Page": 285, "Article Number": null, "DOI": "10.1021/jacs.0c10397", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c10397", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000611083700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, C; Huang, JL; Sun, KW; Johnston, S; Zhang, YF; Sun, H; Pu, AB; He, MR; Liu, FY; Eder, K; Yang, LM; Cairney, JM; Ekins-Daukes, NJ; Hameiri, Z; Stride, JA; Chen, SY; Green, MA; Hao, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Chang; Huang, Jialiang; Sun, Kaiwen; Johnston, Steve; Zhang, Yuanfang; Sun, Heng; Pu, Aobo; He, Mingrui; Liu, Fangyang; Eder, Katja; Yang, Limei; Cairney, Julie M.; Ekins-Daukes, N. J.; Hameiri, Ziv; Stride, John A.; Chen, Shiyou; Green, Martin A.; Hao, Xiaojing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu2ZnSnS4 solar cells with over 10% power conversion efficiency enabled by heterojunction heat treatment", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfide kesterite Cu2ZnSnS4 provides an attractive low-cost, environmentally benign and stable photovoltaic material, yet the record power conversion efficiency for such solar cells has been stagnullt at around 9% for years. Severe non-radiative recombination within the heterojunction region is a major cause limiting voltage output and overall performance. Here we report a certified 11% efficiency Cu2ZnSnS4 solar cell with a high 730 mV open-circuit voltage using heat treatment to reduce heterojunction recombination. This heat treatment facilitates elemental inter-diffusion, directly inducing Cd atoms to occupy Zn or Cu lattice sites, and promotes Na accumulation accompanied by local Cu deficiency within the heterojunction region. Consequently, new phases are formed near the hetero-interface and more favourable conduction band alignment is obtained, contributing to reduced non-radiative recombination. Using this approach, we also demonstrate a certified centimetre-scale (1.11 cm(2)) 10% efficiency Cu2ZnSnS4 photovoltaic device; the first kesterite cell (including selenium-containing) of standard centimetre-size to exceed 10%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 764, "End Page": 772, "Article Number": null, "DOI": "10.1038/s41560-018-0206-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0206-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444121800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Zhang, YR; Huang, BT; Cai, B; Rao, RR; Giordano, L; Sun, SG; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tao; Zhang, Yirui; Huang, Botao; Cai, Bin; Rao, Reshma R.; Giordano, Livia; Sun, Shi-Gang; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing oxygen reduction electrocatalysis by tuning interfacial hydrogen bonds", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton activity at the electrified interface is central to the kinetics of proton-coupled electron transfer (PCET) reactions for making chemicals and fuels. Here we employ a library of protic ionic liquids in an interfacial layer on platinum and gold to alter local proton activity, where the intrinsic oxygen-reduction reaction (ORR) activity is enhanced up to fivefold, exhibiting a volcano-shaped dependence on the pK(a) of the ionic liquid. The enhanced ORR activity is attributed to strengthened hydrogen bonds between ORR products and ionic liquids with comparable pK(a)s, resulting in favourable PCET kinetics. This proposed mechanism is supported by in situ surface-enhanced Fourier-transform infrared spectroscopy and our simulation of PCET kinetics based on computed proton vibrational wavefunctions at the hydrogen-bonding interface. These findings highlight opportunities for using non-covalent interactions between hydrogen-bonded structures and solvation environments at the electrified interface to tune the kinetics of ORR and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 753, "End Page": 762, "Article Number": null, "DOI": "10.1038/s41929-021-00668-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00668-0", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692974900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singh, TI; Maibam, A; Cha, DC; Yoo, S; Babarao, R; Lee, SU; Lee, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singh, Thangjam Ibomcha; Maibam, Ashakiran; Cha, Dun Chan; Yoo, Sunghoon; Babarao, Ravichandar; Lee, Sang Uck; Lee, Seunghyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Alkaline Water-Splitting Activity of Mesoporous 3D Heterostructures: An Amorphous-Shell@Crystalline-Core nullo-Assembly of Co-Ni-Phosphate Ultrathin-nullosheets and V- Doped Cobalt-Nitride nullowires", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Introducing amorphous and ultrathin nullosheets of transition bimetal phosphate arrays that are highly active in the oxygen evolution reaction (OER) as shells over an electronically modulated crystalline core with low hydrogen absorption energy for an excellent hydrogen evolution reaction (HER) can boost the sluggish kinetics of the OER and HER in alkaline electrolytes. Therefore, in this study, ultrathin and amorphous cobalt-nickel-phosphate (CoNiPOx) nullosheet arrays are deposited over vanadium (V)-doped cobalt-nitride (V-3%-Co4N) crystalline core nullowires to obtain amorphous-shell@crystalline-core mesoporous 3D-heterostructures (CoNiPOx@V-Co4N/NF) as bifunctional electrocatalysts. The optimized electrocatalyst shows extremely low HER and OER overpotentials of 53 and 270 mV at 10 mA cm(-2), respectively. The CoNiPOx@V-3%-Co4N/NF (+/-) electrolyzer utilizing the electrocatalyst as both anode and cathode demonstrates remarkable overall water-splitting activity, requiring a cell potential of only 1.52 V at 10 mA cm(-2), 30 mV lower than that of the RuO2/NF (+)/20%-Pt/C/NF (-) electrolyzer. Such impressive bifunctional activities can be attributed to abundant active sites, adjusted electronic structure, lower charge-transfer resistance, enhanced electrochemically active surface area (ECSA), and surface- and volume-confined electrocatalysis resulting from the synergistic effects of the crystalline V-3%-Co4N core and amorphous CoNiPOx shells boosting water splitting in alkaline media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201311, "DOI": "10.1002/advs.202201311", "DOI Link": "http://dx.doi.org/10.1002/advs.202201311", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806254200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, X; Li, H; Yue, WJ; Gao, S; Chen, ZX; Li, Y; Shen, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Xiao; Li, Hao; Yue, Wenjing; Gao, Song; Chen, Zhenxiang; Li, Yang; Shen, Guozhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-accuracy, real-time, intelligent material perception system with a machine-learning-motivated pressure-sensitive electronic skin", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing e-skins that can perceive stimuli with high sensitivity and material recognition functionality at low cost is of great importance to intelligent perception. Here, a hybrid e-skin (PTES) consisting of a triboelectric nullogenerator in tandem with a piezoresistive pressure sensor (PPS) is reported by using an eggshell membrane and infiltration method, which effectively perceives static and dynamic tactile information, such as human physiological information, manipulator tactile sensation, and human walking state. By integrating PTES with a high-speed data collector and machine learning, a material perception system capable of recognizing 12 materials in real time within one touch is established. A PTES array that can detect material property and location further demonstrates the feasibility of simultaneously processing multidimensional information. Additionally, by paralleling with a thin-film resistor, the PPS achieves an ultra-high sensitivity that can also be linearly adjusted. This PTES can open a new avenue for practical intelligent perception and realization of prominent applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2022, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.matt.2022.02.016", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2022.02.016", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000797800700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Slavney, AH; Leppert, L; Bartesaghi, D; Gold-Parker, A; Toney, MF; Savenije, TJ; Neaton, JB; Karunadasa, HI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Slavney, Adam H.; Leppert, Linn; Bartesaghi, Davide; Gold-Parker, Aryeh; Toney, Michael F.; Savenije, Tom J.; Neaton, Jeffrey B.; Karunadasa, Hemamala I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-Induced Band-Edge Reconstruction of a Bismuth-Halide Double Perovskite for Visible-Light Absorption", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide double perovskites have recently been developed as less toxic analogs of the lead perovskite solar-cell absorbers APbX(3) (A = monovalent cation; X = Br or I). However, all known halide double perovskites have large bandgaps that afford weak visible-light absorption. The first halide double perovskite evaluated as an absorber, Cs2AgBiBr6 (1), has a bandgap of 1.95 eV. Here, we show that dilute alloying decreases l's bandgap by ca. 0.5 eV. Importantly, time-resolved photoconductivity measurements reveal long-lived carriers with microsecond lifetimes in the alloyed material, which is very promising for photovoltaic applications. The alloyed perovskite described herein is the first double perovskite to show comparable bandgap energy and carrier lifetime to those of (CH3NH3)PbI3. By describing how energy- and symmetry-matched impurity orbitals, at low concentrations, dramatically alter l's band edges, we open. a potential pathway for the large and diverse family of halide double perovskites to compete with APbX(3) absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2017, "Volume": 139, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5015, "End Page": 5018, "Article Number": null, "DOI": "10.1021/jacs.7b01629", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b01629", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399353800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pearson, RM; Lim, CH; McCarthy, BG; Musgrave, CB; Miyake, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pearson, Ryan M.; Lim, Chern-Hooi; McCarthy, Blaine G.; Musgrave, Charles B.; Miyake, Garret M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "N-Aryl phenoxazines have been synthesized and introduced as strongly reducing metal-free photoredox catalysts in organocatalyzed atom transfer radical polymerization for the synthesis of well-defined polymers. Experiments confirmed quantum chemical predictions that, like their dihydrophenazine analogs, the photoexcited states of phenoxazine photoredox catalysts are strongly reducing and achieve superior performance when they possess charge transfer character. We compare phenoxazines to previously reported dihydrophenazines and phenothiazines as photoredox catalysts to gain insight into the performance of these catalysts and establish principles for catalyst design. A key finding reveals that maintenullce of a planar conformation of the phenoxazine catalyst during the catalytic cycle encourages the synthesis of well-defined macromolecules. Using these principles, we realized a core substituted phenoxazine as a visible light photoredox catalyst that performed superior to UV-absorbing phenoxazines as well as previously reported organic photocatalysts in organocatalyzed atom transfer radical polymerization. Using this catalyst and irradiating with white LEDs resulted in the production of polymers with targeted molecular weights through achieving quantitative initiator efficiencies, which possess dispersities ranging from 1.13 to 1.31.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2016, "Volume": 138, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11399, "End Page": 11407, "Article Number": null, "DOI": "10.1021/jacs.6b08068", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b08068", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382901800054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, Y; Wei, CT; Li, XM; Li, YL; Qiu, SC; Shen, W; Cai, B; Sun, ZG; Yang, DD; Deng, ZT; Zeng, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Ye; Wei, Changting; Li, Xiaoming; Li, Yuelei; Qiu, Shuangchen; Shen, Wei; Cai, Bo; Sun, Zhiguo; Yang, Dandan; Deng, Zhengtao; Zeng, Haibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Passivation of PbBr64- Octahedra toward Blue Luminescent CsPbBr3 nulloplatelets with Near 100% Absolute Quantum Yield", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, the pursuit of high photoluminescence quantum yields (PLQYs) for blue emission in perovskite nullocrystals (NCs) has attracted increased attention because the QY of blue NCs lags behind those of green and red ones severely, which is fatal for three-primary-color displays. Here, we propose an in situ PbBr64- octahedra passivation strategy to achieve a 96% absolute QY for the ultrapure (line width = 12 nm) blue emission from CsPbBr3 nulloplatelets (NPLs), and both values rank first among perovskite NCs with blue emission. From the aspect of constructing intact PbBr64- octahedra, additional Br- was introduced to drive the ionic equilibrium to form intact Pb-Br octahedra. The reduced Br vacancy and inhibited nonradiative recombination processes are well proved by reduced Urbach energy, increased Pb-Br bonds, and slower transient absorption delay. Blue light-emitting diodes (LEDs) using NPLs were fabricated, and a high external quantum efficiency (EQE) of 0.124% with an emission line width of similar to 12 nm was realized. This work will provide good references to break the blue-wall in perovskite NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2030, "End Page": 2037, "Article Number": null, "DOI": "10.1021/acsenergylett.8b01025", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b01025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445052900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, BJ; He, JJ; Mu, YX; Zhu, QZ; Wu, SK; Wang, YF; Zhang, Y; Jin, CJ; Lo, CC; Chi, ZG; Lien, A; Liu, SW; Xu, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Bingjia; He, Jiajun; Mu, Yingxiao; Zhu, Qiangzhong; Wu, Sikai; Wang, Yifan; Zhang, Yi; Jin, Chongjun; Lo, Changcheng; Chi, Zhenguo; Lien, Alan; Liu, Siwei; Xu, Jiarui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Very bright mechanoluminescence and remarkable mechanochromism using a tetraphenylethene derivative with aggregation-induced emission", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic materials exhibiting mechanoluminescence (ML) are promising for usage in displays, lighting and sensing. However, the mechanism for ML generation remains unclear, and the light-emitting performance of organic ML materials in the solid state has been severely limited by an aggregation-caused quenching (ACQ) effect. Herein, we present two strongly photoluminescent polymorphs (i.e., C-g and C-b) with distinctly different ML activities based on a tetraphenylethene derivative P(4)TA. As an aggregation-induced emission (AIE) emitter, P(4)TA perfectly surmounted the ACQ, making the resultant block-like crystals in the C-g phase exhibit brilliant green ML under daylight at room temperature. The ML-inactive prism-like crystals C-b can also have their ML turned on by transitioning toward C-g with the aid of dichloromethane vapor. Moreover, the C-g polymorph shows ML and mechanochromism simultaneously and respectively without and with UV irradiation under a force stimulus, thus suggesting a feasible design direction for the development of efficient and multifunctional ML materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3236, "End Page": 3241, "Article Number": null, "DOI": "10.1039/c5sc00466g", "DOI Link": "http://dx.doi.org/10.1039/c5sc00466g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353223100070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, DW; Yao, JM; Zhang, L; Xu, RN; Wang, SJ; Yan, XL; Yu, C; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Dewu; Yao, Jingming; Zhang, Long; Xu, Ruonull; Wang, Shaojie; Yan, Xinlin; Yu, Chuang; Wang, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting favorable interfacial properties in lithium-based batteries using chlorine-rich sulfide inorganic solid-state electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interfacial stability of lithium metal is a crucial aspect for all-solid-state battery development. Here, authors report argyrodite solid electrolytes containing LiCl framework, where the Cl ions construct a LiCl-rich interphase capable of improving battery performances. The use of inorganic solid-state electrolytes is considered a viable strategy for developing high-energy Li-based metal batteries. However, suppression of parasitic interfacial reactions and growth of unfavorable Li metal depositions upon cycling are challenging aspects and not yet fully addressed. Here, to better understand these phenomena, we investigate various sulfide inorganic solid electrolytes (SEs), i.e., Li7-xPS6-xClx (x = 0.6, 1.0, 1.3, 1.45, and 1.6), via ex situ and in situ physicochemical and electrochemical measurements. We found that the Cl distribution and the cooling process applied during the SE synthesis strongly influence the evolution of the Li|SE interface in terms of microstructure, interphase composition, and morphology. Indeed, for a SE with a moderate chlorine content (i.e., x = 1.3) and obtained via a slow cooling process after sintering, the Cl atoms are located on the surface of the SE grains as interconnected LiCl nulloparticles that form an extended LiCl-based framework. This peculiar microstructure facilitates the migration of the Cl ions to the Li|SE interface during electrochemical cycling, thus, favouring the formation of a LiCl-rich interphase layer capable of improving the battery cycling performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1909, "DOI": "10.1038/s41467-022-29596-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29596-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779784400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ershad, F; Thukral, A; Yue, JP; Comeaux, P; Lu, YT; Shim, H; Sim, K; Kim, NI; Rao, ZY; Guevara, R; Contreras, L; Pan, FJ; Zhang, YC; Guan, YS; Yang, PY; Wang, X; Wang, P; Wu, XY; Yu, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ershad, Faheem; Thukral, Anish; Yue, Jiping; Comeaux, Phillip; Lu, Yuntao; Shim, Hyunseok; Sim, Kyoseung; Kim, Nam-In; Rao, Zhoulyu; Guevara, Ross; Contreras, Luis; Pan, Fengjiao; Zhang, Yongcao; Guan, Ying-Shi; Yang, Pinyi; Wang, Xu; Wang, Peng; Wu, Xiaoyang; Yu, Cunjiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-conformal drawn-on-skin electronics for multifunctional motion artifact-free sensing and point-of-care treatment", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An accurate extraction of physiological and physical signals from human skin is crucial for health monitoring, disease prevention, and treatment. Recent advances in wearable bioelectronics directly embedded to the epidermal surface are a promising solution for future epidermal sensing. However, the existing wearable bioelectronics are susceptible to motion artifacts as they lack proper adhesion and conformal interfacing with the skin during motion. Here, we present ultra-conformal, customizable, and deformable drawn-on-skin electronics, which is robust to motion due to strong adhesion and ultra-conformality of the electronic inks drawn directly on skin. Electronic inks, including conductors, semiconductors, and dielectrics, are drawn on-demand in a freeform manner to develop devices, such as transistors, strain sensors, temperature sensors, heaters, skin hydration sensors, and electrophysiological sensors. Electrophysiological signal monitoring during motion shows drawn-on-skin electronics' immunity to motion artifacts. Additionally, electrical stimulation based on drawn-on-skin electronics demonstrates accelerated healing of skin wounds. Designing efficient wearable bioelectronics for health monitoring, disease prevention, and treatment, remains a challenge. Here, the authors demonstrate an ultra-conformal, customizable and deformable drawn-on-skin electronics which is robust to motion artifacts and resistant to physical damage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3823, "DOI": "10.1038/s41467-020-17619-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17619-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560076500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pérez-Gallent, E; Figueiredo, MC; Calle-Vallejo, F; Koper, MTM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perez-Gallent, Elena; Figueiredo, Marta C.; Calle-Vallejo, Federico; Koper, Marc T. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spectroscopic Observation of a Hydrogenated CODimer Intermediate During CO Reduction on Cu(100) Electrodes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide and carbon monoxide can be electrochemically reduced to useful products such as ethylene and ethanol on copper electrocatalysts. The process is yet to be optimized and the exact mechanism and the corresponding reaction intermediates are under debate or unknown. In particular, it has been hypothesized that the C-C bond formation proceeds via CO dimerization and further hydrogenation. Although computational support for this hypothesis exists, direct experimental evidence has been elusive. In this work, we detect a hydrogenated dimer intermediate (OCCOH) using Fourier transform infrared spectroscopy at low over-potentials in LiOH solutions. Density functional theory calculations support our assignment of the observed vibrational bands. The formation of this intermediate is structure sensitive, as it is observed only during CO reduction on Cu(100) and not on Cu(111), in agreement with previous experimental and computational observations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 484, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2017, "Volume": 56, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3621, "End Page": 3624, "Article Number": null, "DOI": "10.1002/anie.201700580", "DOI Link": "http://dx.doi.org/10.1002/anie.201700580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397339400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XM; Pan, YL; Zhong, J; Shi, CL; Guan, DQ; Ge, L; Hu, ZW; Chin, YY; Lin, HJ; Chen, CT; Wang, H; Jiang, SP; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiaomin; Pan, Yangli; Zhong, Yjun; Shi, Chenliang; Guan, Daqin; Ge, Lei; Hu, Zhiwei; Chin, Yi-Ying; Lin, Hong-Ji; Chen, Chien-Te; Wang, Hao; Jiang, San Ping; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Undisputed Evidence and Strategy for Enhanced Lattice-Oxygen Participation of Perovskite Electrocatalyst through Cation Deficiency Manipulation", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction (OER) is a key half-reaction in many electrochemical transformations, and efficient electrocatalysts are critical to improve its kinetics which is typically sluggish due to its multielectron-transfer nature. Perovskite oxides are a popular category of OER catalysts, while their activity remains insufficient under the conventional adsorbate evolution reaction scheme where scaling relations limit activity enhancement. The lattice oxygen-mediated mechanism (LOM) has been recently reported to overcome such scaling relations and boost the OER catalysis over several doped perovskite catalysts. However, direct evidence supporting the LOM participation is still very little because the doping strategy applied would introduce additional active sites that may mask the real reaction mechanism. Herein, a dopant-free, cation deficiency manipulation strategy to tailor the bulk diffusion properties of perovskites without affecting their surface properties is reported, providing a perfect platform for studying the contribution of LOM to OER catalysis. Further optimizing the A-site deficiency achieves a perovskite candidate with excellent intrinsic OER activity, which also demonstrates outstanding performance in rechargeable Zn-air batteries and water electrolyzers. These findings not only corroborate the key role of LOM in OER electrocatalysis, but also provide an effective way for the rational design of better catalyst materials for clean energy technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200530, "DOI": "10.1002/advs.202200530", "DOI Link": "http://dx.doi.org/10.1002/advs.202200530", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770788400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, K; Conboy, M; Park, HM; Jiang, FG; Kim, HJ; Dewitt, MA; Mackley, VA; Chang, K; Rao, A; Skinner, C; Shobha, T; Mehdipour, M; Liu, H; Huang, WC; Lan, F; Bray, NL; Li, S; Corn, JE; Kataoka, K; Doudna, JA; Conboy, I; Murthy, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Kunwoo; Conboy, Michael; Park, Hyo Min; Jiang, Fuguo; Kim, Hyun Jin; Dewitt, Mark A.; Mackley, Vanessa A.; Chang, Kevin; Rao, Anirudh; Skinner, Colin; Shobha, Tamanna; Mehdipour, Melod; Liu, Hui; Huang, Wen-chin; Lan, Freeman; Bray, Nicolas L.; Li, Song; Corn, Jacob E.; Kataoka, Kazunori; Doudna, Jennifer A.; Conboy, Irina; Murthy, Niren", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticle delivery of Cas9 ribonucleoprotein and donor DNA in vivo induces homology-directed DNA repair", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Clustered regularly interspaced short palindromic repeats (CRISPR)-CRISPR associated protein 9 (Cas9)-based therapeutics, especially those that can correct gene mutations via homology-directed repair, have the potential to revolutionize the treatment of genetic diseases. However, it is challenging to develop homology-directed repair-based therapeutics because they require the simultaneous in vivo delivery of Cas9 protein, guide RNA and donor DNA. Here, we demonstrate that a delivery vehicle composed of gold nulloparticles conjugated to DNA and complexed with cationic endosomal disruptive polymers can deliver Cas9 ribonucleoprotein and donor DNA into a wide variety of cell types and efficiently correct the DNA mutation that causes Duchenne muscular dystrophy in mice via local injection, with minimal off-target DNA damage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 555, "Times Cited, All Databases": 649, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 889, "End Page": 901, "Article Number": null, "DOI": "10.1038/s41551-017-0137-2", "DOI Link": "http://dx.doi.org/10.1038/s41551-017-0137-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418861200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Croteau, JR; Griffiths, S; Rossell, MD; Leinenbach, C; Kenel, C; Jansen, V; Seidman, DN; Dunulld, DC; Vo, NQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Croteau, Joseph R.; Griffiths, Seth; Rossell, Marta D.; Leinenbach, Christian; Kenel, Christoph; Jansen, Vincent; Seidman, David N.; Dunulld, David C.; Vo, Nhon Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure and mechanical properties of Al-Mg-Zr alloys processed by selective laser melting", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gas-atomized powders of two ternary alloys, Al-3.60Mg-1.18Zr and Al-3.66Mg-1.57Zr (wt.%), were densified via laser powder bed fusion. At energy densities ranging from 123 to 247 J/mm(3), as-fabricated components are near-fully densified (relative density 99.2-99.9%) as verified by X-ray tomography. While Mg acts a solid-solution strengthener, Zr creates two types of metastable L1(2) Al3Zr precipitates, each playing dual roles: (a) sub-micrometer Al3Zr particles form in the melt upon solidification and act as grain refining agents, nucleating fine aluminum grains, which (i) prevent hot-tearing during the rapid solidification inherent to laser melting and (ii) enhance tensile strength (Hall-Petch strengthening) and ductility (influence a heterogenous grain structure) after fabrication; (b) Al3Zr nullo-precipitates form in the solid alloy during subsequent aging, which (i) precipitation-strengthen the alloy leading to an increase of >40% in strength over the as-fabricated value, and (ii) promote thermal stability of the fine grain size (and the associated Hall-Petch strengthening) after exposure to high temperature due to the slow kinetics of Al3Zr coarsening (from the sluggish diffusivity of Zr in solid Al-Mg). While the Zr-richer alloy shows higher yield and ultimate tensile strength in the as-fabricated state, both alloys have identical mechanical properties after peak aging. Interconnected bands of fine (similar to 0.8 mu m), equiaxed, isotropic grains and coarser (similar to 1 x 10 mu m), columnar, textured grains - both containing oxide particles and Al3Zr precipitates - provide a combination of high yield strength and high ductility (e.g., similar to 354 MPa, and similar to 20%, respectively) with isotropic values in both as-fabricated and peak-aged samples, unlike Al-Si alloys processed via laser fusion of commercial Al-Si-based powders. The pre-alloyed, gas-atomized Al-Mg-Zr powders do not contain expensive alloying elements such as Sc, nor do they require blending with a second powder to nucleate fine grains, making them excellent candidates for economical, large-scale additive manufacturing applications. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 153, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 35, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.actamat.2018.04.053", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2018.04.053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437391500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Wang, XM; Yang, Z; Zhou, NH; Deng, YH; Zhao, JJ; Xiao, X; Rudd, P; Moran, A; Yan, YF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qi; Wang, Xiaoming; Yang, Zhi; Zhou, Ninghao; Deng, Yehao; Zhao, Jingjing; Xiao, Xun; Rudd, Peter; Moran, Andrew; Yan, Yanfa; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient sky-blue perovskite light-emitting diodes via photoluminescence enhancement", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiencies of green and red perovskite light-emitting diodes (PeLEDs) have been increased close to their theoretical upper limit, while the efficiency of blue PeLEDs is lagging far behind. Here we report enhancing the efficiency of sky-blue PeLEDs by overcoming a major hurdle of low photoluminescence quantum efficiency in wide-bandgap perovskites. Blending phenylethylammonium chloride into cesium lead halide perovskites yields a mixture of two-dimensional and three-dimensional perovskites, which enhances photoluminescence quantum efficiency from 1.1% to 19.8%. Adding yttrium (III) chloride into the mixture further enhances photoluminescence quantum efficiency to 49.7%. Yttrium is found to incorporate into the three-dimensional perovskite grain, while it is still rich at grain boundaries and surfaces. The yttrium on grain surface increases the bandgap of grain shell, which confines the charge carriers inside grains for efficient radiative recombination. Record efficiencies of 11.0% and 4.8% were obtained in sky-blue and blue PeLEDs, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5633, "DOI": "10.1038/s41467-019-13580-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13580-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502089000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XQ; Sun, BW; Sui, CX; nulldi, A; Fang, HM; Peng, YC; Tan, G; Hsu, PC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiuqiang; Sun, Bowen; Sui, Chenxi; nulldi, Ankita; Fang, Haoming; Peng, Yucan; Tan, Gang; Hsu, Po-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of daytime radiative cooling and solar heating for year-round energy saving in buildings", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The heating and cooling energy consumption of buildings accounts for about 15% of national total energy consumption in the United States. In response to this challenge, many promising technologies with minimum carbon footprint have been proposed. However, most of the approaches are static and monofunctional, which can only reduce building energy consumption in certain conditions and climate zones. Here, we demonstrate a dual-mode device with electrostatically-controlled thermal contact conductance, which can achieve up to 71.6 W/m(2) of cooling power density and up to 643.4 W/m(2) of heating power density (over 93% of solar energy utilized) because of the suppression of thermal contact resistance and the engineering of surface morphology and optical property. Building energy simulation shows our dual-mode device, if widely deployed in the United States, can save 19.2% heating and cooling energy, which is 1.7 times higher than cooling-only and 2.2 times higher than heating-only approaches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6101, "DOI": "10.1038/s41467-020-19790-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19790-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617694500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liardet, L; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liardet, Laurent; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous Cobalt Vanadium Oxide as a Highly Active Electrocatalyst for Oxygen Evolution", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The water-splitting reaction provides a promising mechanism to store renewable energies in the form of hydrogen fuel. The oxidation half-reaction, the oxygen evolution reaction (OER), is a complex four-electron process that constitutes an efficiency bottleneck in water splitting. Here we report a highly active OER catalyst, cobalt vanadium oxide. The catalyst is designed on the basis of a volcano plot of metal-OH bond strength and activity. The catalyst can be synthesized by a facile hydrothermal route. The most active pure-phase material (a-CoVOx) is X-ray amorphous and provides a 10 mA cm(-2) current density at an overpotential of 347 mV in 1 M KOH electrolyte when immobilized on a flat substrate. The synthetic method can also be applied to coat a high-surface-area substrate such as nickel foam. On this three-dimensional substrate, the a-CoVOx catalyst is highly active, reaching 10 mA cm(-2) at 254 mV overpotential, with a Tafel slope of only 35 mV dec(-1). This work demonstrates a-CoVOx as a promising electrocatalyst for oxygen evolution and validates M-OH bond strength as a practical descriptor in OER catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 644, "End Page": 650, "Article Number": null, "DOI": "10.1021/acscatal.7b03198", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b03198", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419751100065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, LX; Liu, ZK; Sun, Y; Peng, H; Yang, HF; Zhang, T; Zhou, B; Zhang, Y; Guo, YF; Rahn, M; Prabhakaran, D; Hussain, Z; Mo, SK; Felser, C; Yan, B; Chen, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, L. X.; Liu, Z. K.; Sun, Y.; Peng, H.; Yang, H. F.; Zhang, T.; Zhou, B.; Zhang, Y.; Guo, Y. F.; Rahn, M.; Prabhakaran, D.; Hussain, Z.; Mo, S. -K.; Felser, C.; Yan, B.; Chen, Y. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weyl semimetal phase in the non-centrosymmetric compound TaAs", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) topological Weyl semimetals (TWSs) represent a state of quantum matter with unusual electronic structures that resemble both a '3D graphene' and a topological insulator. Their electronic structure displays pairs of Weyl points (through which the electronic bands disperse linearly along all three momentum directions) connected by topological surface states, forming a unique arc-like Fermi surface (FS). Each Weyl point is chiral and contains half the degrees of freedom of a Dirac point, and can be viewed as a magnetic monopole in momentum space. By performing angle-resolved photoemission spectroscopy on the non-centrosymmetric compound TaAs, here we report its complete band structure, including the unique Fermi-arc FS and linear bulk band dispersion across the Weyl points, in agreement with the theoretical calculations1,2. This discovery not only confirms TaAs as a 3DTWS, but also provides an ideal platform for realizing exotic physical phenomena (for example, negative magnetoresistance, chiral magnetic effects and the quantum anomalous Hall effect) which may also lead to novel future applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 828, "Times Cited, All Databases": 899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 11, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 728, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3425", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3425", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360709200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Azofra, LM; Li, N; MacFarlane, DR; Sun, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Azofra, Luis Miguel; Li, Neng; MacFarlane, Douglas R.; Sun, Chenghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promising prospects for 2D d2-d4 M3C2 transition metal carbides (MXenes) in N2 capture and conversion into ammonia", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Density functional theory investigations of M3C2 transition metal carbides from the d(2), d(3), and d(4) series suggest promising N-2 capture behaviour, displaying spontaneous chemisorption energies that are larger than those for the capture of CO2 and H2O in d(3) and d(4) MXenes. The chemisorbed N-2 becomes activated, promoting its catalytic conversion into NH3. The first proton-electron transfer is found to be the rate-determining step for the whole process, with an activation barrier of only 0.64 eV vs. SHE for V3C2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2545, "End Page": 2549, "Article Number": null, "DOI": "10.1039/c6ee01800a", "DOI Link": "http://dx.doi.org/10.1039/c6ee01800a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384921700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, S; Eickemeyer, FT; Gao, J; Yum, JH; Zheng, X; Ren, D; Xia, M; Guo, R; Rong, YG; Zakeeruddin, SM; Sivula, K; Tang, J; Shen, ZJ; Li, X; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Shuai; Eickemeyer, Felix T.; Gao, Jing; Yum, Jun-Ho; Zheng, Xin; Ren, Dan; Xia, Meng; Guo, Rui; Rong, Yaoguang; Zakeeruddin, Shaik M.; Sivula, Kevin; Tang, Jiang; Shen, Zhongjin; Li, Xiong; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bifunctional hole-shuttle molecule for improved interfacial energy level alignment and defect passivation in perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interface engineering in perovskite solar cells is key to high performance. Now, You et al. design an interlayer that both passivates defects and improves the energy level alignment between the perovskite and hole transport material. Perovskite solar cells have reached a power conversion efficiency over 25%, and the engineering of the interface between the perovskite and hole transport layer (HTL) has been crucial to achieve high performance. Here we design a bifunctional molecule CBz-PAI with carbazole-triphenylamine and phenylammonium iodide units to passivate defects at the perovskite/HTL interface. Owing to a favourable energy level alignment with the perovskite, the CBz-PAI acts as a hole shuttle between the perovskite layer and the HTL. This minimizes the difference between the quasi-Fermi level splitting of the perovskite, or 'internal' V-oc, and the external device V-oc, thus reducing voltage losses. As a result, solar cells incorporating CBz-PAI reach a stabilized power conversion efficiency of 24.7% and maintain 92.3% of the initial efficiency after 1,000 h under damp heat test (85 degrees C and 85% relative humidity) and 94.6% after 1,100 h under maximum power point-tracking conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 515, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01249-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01249-0", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971047200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YQ; Ke, QQ; Zhang, G; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yongqing; Ke, Qingqing; Zhang, Gang; Zhang, Yong-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energetics, Charge Transfer, and Magnetism of Small Molecules Physisorbed on Phosphorene", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations are performed to investigate the interaction of physisorbed small molecules, including CO, H-2, H2O, NH3, NO, NO2, and O-2, with phosphorene, and their energetics, charge transfer, and magnetic moment are evaluated on the basis of dispersion-corrected density functional theory. Our calculations reveal that CO, H-2, H2O, and NH3 molecules act as a weak donor, whereas O-2 and NO2 act as a strong acceptor. While the NO molecule donates electrons to graphene, it receives electrons from phosphorene. Among all the investigated molecules, NO2 has the strongest interaction through hybridizing its frontier orbitals with the 3p orbital of phosphorene. The nontrivial and distinct charge transfer occurring between phosphorene and these physisorbed molecules not only renders phosphorene promising for application as a gas sensor but also provides an effective route for modulating the polarity and density of carriers in phosphorene. In addition, the intermediate binding energy of hydrogen molecules on phosphorene implies stable hydrogen storage at ambient conditions and subsequent facile release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2015, "Volume": 119, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3102, "End Page": 3110, "Article Number": null, "DOI": "10.1021/jp510863p", "DOI Link": "http://dx.doi.org/10.1021/jp510863p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349578400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faid, AY; Barnett, AO; Seland, F; Sunde, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faid, Alaa Y.; Barnett, Alejandro Oyarce; Seland, Frode; Sunde, Svein", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni/NiO nullosheets for alkaline hydrogen evolution reaction: In situ electrochemical-Raman study", "Source Title": "ELECTROCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel/Nickel oxide (Ni/NiO) nullosheets heterostructure is a cheap and active catalyst for hydrogen evolution reaction (HER) in alkaline electrolytes. However, the reason for this activity is still under debate. Herein in-situ Raman electrochemistry has been established as a method to probe interfacial intermediates and correlate the performance of various nickel catalysts (Ni, NiO, and Ni/NiO nullosheets) during HER. In-situ Raman spectroscopy demonstrated that Ni/NiO nullosheet heterostructure maintained beta-Ni(OH)(2) species initially, which may contribute to the superior initial HER activity. Ni/NiO nullosheets lost beta-Ni(OH)(2) species by preserving a high cathodic overpotential (-0.4 V vs. RHE) for 2000 sec. The results confirmed the importance of Ni metal sites in addition to NiO sites and maintaining hydroxide species for superior and durable HER activity. These results can be utilized to design an efficient and durable catalyst for alkaline electrolyzers for the sustainable production of hydrogen. (C) 2020 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2020, "Volume": 361, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137040, "DOI": "10.1016/j.electacta.2020.137040", "DOI Link": "http://dx.doi.org/10.1016/j.electacta.2020.137040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000580627600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, F; Nordlund, D; Li, YY; Quan, MK; Cheng, L; Weng, TC; Liu, YJ; Xin, HL; Doeff, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Feng; Nordlund, Dennis; Li, Yuyi; Quan, Matthew K.; Cheng, Lei; Weng, Tsu-Chien; Liu, Yijin; Xin, Huolin L.; Doeff, Marca M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In technologically important LiNi1-x-yMnxCoyO2 cathode materials, surface reconstruction from a layered to a rock-salt structure is commonly observed under a variety of operating conditions, particularly in Ni-rich compositions. This phenomenon contributes to poor high-voltage cycling performance, impeding attempts to improve the energy density by widening the potential window at which these electrodes operate. Here, using advanced nullo-tomography and transmission electron microscopy techniques, we show that hierarchically structured LiNi0.4Mn0.4Co0.2O2 spherical particles, made by a simple spray pyrolysis method, exhibit local elemental segregation such that surfaces are Ni-poor and Mn-rich. The tailored surfaces result in superior resistance to surface reconstruction compared with those of conventional LiNi0.4Mn0.4Co0.2O2, as shown by soft X-ray absorption spectroscopy experiments. The improved high-voltage cycling behaviour exhibited by cells containing these cathodes demonstrates the importance of controlling LiNi1-x-yMnxCoyO2 surface chemistry for successful development of high-energy lithium ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15004, "DOI": "10.1038/NENERGY.2015.4", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2015.4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394094100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kishore, RA; Nozariasbmarz, A; Poudel, B; Sanghadasa, M; Priya, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kishore, Ravi Anullt; Nozariasbmarz, Amin; Poudel, Bed; Sanghadasa, Mohan; Priya, Shashank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high performance wearable thermoelectric coolers with less materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric coolers are attracting significant attention for replacing age-old cooling and refrigeration devices. Localized cooling by wearable thermoelectric coolers will decrease the usage of traditional systems, thereby reducing global warming and providing savings on energy costs. Since human skin as well as ambient air is a poor conductor of heat, wearable thermoelectric coolers operate under huge thermally resistive environment. The external thermal resistances greatly influence thermoelectric material behavior, device design, and device performance, which presents a fundamental challenge in achieving high efficiency for on-body applications. Here, we examine the combined effect of heat source/sink thermal resistances and thermoelectric material properties on thermoelectric cooler performance. Efficient thermoelectric coolers demonstrated here can cool the human skin up to 8.2 degrees C below the ambient temperature (170% higher cooling than commercial modules). Cost-benefit analysis shows that cooling over material volume for our optimized thermoelectric cooler is 500% higher than that of the commercial modules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1765, "DOI": "10.1038/s41467-019-09707-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09707-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464654700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, L; Li, S; Huang, HX; Tao, KY; Xu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Lei; Li, Shun; Huang, Haixuan; Tao, Keyu; Xu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-broadband absorber from visible to near-infrared using plasmonic metamaterial", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a design of an ultra-broadband absorber based on a thin metamaterial nullostructure composed of a periodic array of titanium-silica (Ti-SiO2) cubes and an aluminum (Al) bottom film. The proposed structure can achieve nearly perfect absorption with an average absorbance of 97% spanning a broad range from visible to near-infrared (i.e., from 354 nm to 1066 nm), showing a 90% absorption bandwidth over 712 nm, and the peak absorption is up to 99.8%. The excitation of superior surface plasmon resonullce combined with the resonullce induced by the metal-insulator-metal Fabry-Perot (FP) cavity leads to this broadband perfect absorption. The polarization and angle insensitivity is demonstrated by analyzing the absorption performance with oblique incidences for both TE- and TM-polarized waves. In addition, we discuss the impact of various metal materials and geometry structure on absorption performance in detail. The proposed broadband metamaterial absorber shows a promising prospect in applications such as solar cell, infrared detection, and imaging. Moreover, the use of a thin titanium cap and an aluminum film instead of noble metals has the potential to reduce production cost in applications. (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2018, "Volume": 26, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5686, "End Page": 5693, "Article Number": null, "DOI": "10.1364/OE.26.005686", "DOI Link": "http://dx.doi.org/10.1364/OE.26.005686", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427147200054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YG; Bai, XH; Yuan, DC; Zhang, FY; Li, B; San, XY; Liang, BL; Wang, SF; Luo, J; Fu, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yaguang; Bai, Xianhua; Yuan, Dachao; Zhang, Fengyu; Li, Bo; San, Xingyuan; Liang, Baolai; Wang, Shufang; Luo, Jun; Fu, Guangsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General heterostructure strategy of photothermal materials for scalable solar-heating hydrogen production without the consumption of artificial energy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-heating catalysis has the potential to realize zero artificial energy consumption, which is restricted by the low ambient solar heating temperatures of photothermal materials. Here, we propose the concept of using heterostructures of black photothermal materials (such as Bi2Te3) and infrared insulating materials (Cu) to elevate solar heating temperatures. Consequently, the heterostructure of Bi2Te3 and Cu (Bi2Te3/Cu) increases the 1 sun-heating temperature of Bi2Te3 from 93 degrees C to 317 degrees C by achieving the synergy of 89% solar absorption and 5% infrared radiation. This strategy is applicable for various black photothermal materials to raise the 1 sun-heating temperatures of Ti2O3, Cu2Se, and Cu2S to 295 degrees C, 271 degrees C, and 248 degrees C, respectively. The Bi2Te3/Cu-based device is able to heat CuOx/ZnO/Al2O3 nullosheets to 305 degrees C under 1 sun irradiation, and this system shows a 1 sun-driven hydrogen production rate of 310 mmol g(-1) h(-1) from methanol and water, at least 6 times greater than that of all solar-driven systems to date, with 30.1% solar-to-hydrogen efficiency and 20-day operating stability. Furthermore, this system is enlarged to 6 m(2) to generate 23.27 m(3)/day of hydrogen under outdoor sunlight irradiation in the spring, revealing its potential for industrial manufacture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 776, "DOI": "10.1038/s41467-022-28364-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28364-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756697400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chmiela, S; Sauceda, HE; Müller, KR; Tkatchenko, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chmiela, Stefan; Sauceda, Huziel E.; Mueller, Klaus-Robert; Tkatchenko, Alexandre", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards exact molecular dynamics simulations with machine-learned force fields", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular dynamics (MD) simulations employing classical force fields constitute the cornerstone of contemporary atomistic modeling in chemistry, biology, and materials science. However, the predictive power of these simulations is only as good as the underlying interatomic potential. Classical potentials often fail to faithfully capture key quantum effects in molecules and materials. Here we enable the direct construction of flexible molecular force fields from high-level ab initio calculations by incorporating spatial and temporal physical symmetries into a gradient-domain machine learning (sGDML) model in an automatic data-driven way. The developed sGDML approach faithfully reproduces global force fields at quantum-chemical CCSD(T) level of accuracy and allows converged molecular dynamics simulations with fully quantized electrons and nuclei. We present MD simulations, for flexible molecules with up to a few dozen atoms and provide insights into the dynamical behavior of these molecules. Our approach provides the key missing ingredient for achieving spectroscopic accuracy in molecular simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 613, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3887, "DOI": "10.1038/s41467-018-06169-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06169-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445329000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Sun, Y; Zhang, Y; Shi, WJ; Parkin, SSP; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hao; Sun, Yan; Zhang, Yang; Shi, Wu-Jun; Parkin, Stuart S. P.; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Weyl semimetals in the chiral antiferromagnetic materials Mn3Ge and Mn3Sn", "Source Title": "NEW JOURNAL OF PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent experiments revealed that Mn3Sn and Mn3Ge exhibit a strong anomalous Hall effect at room temperature, provoking us to explore their electronic structures for topological properties. By ab. initio band structure calculations, we have observed the existence of multiple Weyl points in the bulk and corresponding Fermi arcs on the surface, predicting antiferromagnetic Weyl semimetals in Mn3Ge and Mn3Sn. Here the chiral antiferromagnetism in the Kagome-type lattice structure is essential to determine the positions and numbers of Weyl points. Our work further reveals a new guiding principle to search for magnetic Weyl semimetals among materials that exhibit a strong anomalous Hall effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2017, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15008, "DOI": "10.1088/1367-2630/aa5487", "DOI Link": "http://dx.doi.org/10.1088/1367-2630/aa5487", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394535900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YH; Peng, CK; Hu, HM; Chen, SY; Choi, JH; Lin, YG; Lee, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yinghao; Peng, Chun-Kuo; Hu, Huimin; Chen, San-Yuan; Choi, Jin-Ho; Lin, Yan-Gu; Lee, Jong-Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interstitial boron-triggered electron-deficient Os aerogels for enhanced pH-universal hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance electrocatalysts for hydrogen evolution reaction (HER) is crucial for sustainable hydrogen production, yet still challenging. Here, we report boron-modulated osmium (B-Os) aerogels with rich defects and ultra-fine diameter as a pH-universal HER electrocatalyst. The catalyst shows the small overpotentials of 12, 19, and 33 mV at a current density of 10 mA cm(-2) in acidic, alkaline, and neutral electrolytes, respectively, as well as excellent stability, surpassing commercial Pt/C. Operando X-ray absorption spectroscopy shows that interventional interstitial B atoms can optimize the electron structure of B-Os aerogels and stabilize Os as active sites in an electron-deficient state under realistic working conditions, and simultaneously reveals the HER catalytic mechanisms of B-Os aerogels in pH-universal electrolytes. The density functional theory calculations also indicate introducing B atoms can tailor the electronic structure of Os, resulting in the reduced water dissociation energy and the improved adsorption/desorption behavior of hydrogen, which synergistically accelerate HER. While noble metals can be active electrocatalysts for producing renewable H-2, there are relatively few works examining osmium materials. Here, the authors prepare boron-doped osmium aerogels for H-2 evolution electrocatalysis plus examine the mechanism using computational and in situ characterization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1143, "DOI": "10.1038/s41467-022-28805-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28805-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764258100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mallick, A; El-Zohry, AM; Shekhah, O; Yin, J; Jia, JT; Aggarwal, H; Emwas, AH; Mohammed, OF; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mallick, Arijit; El-Zohry, Ahmed M.; Shekhah, Osama; Yin, Jun; Jia, Jiangtao; Aggarwal, Himanshu; Emwas, Abdul-Hamid; Mohammed, Omar F.; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unprecedented Ultralow Detection Limit of Amines using a Thiadiazole-Functionalized Zr(IV)-Based Metal-Organic Framework", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A luminescent Zr(IV)-based metal-organic framework (MOF), with the underlying fcu topology, encompassing a pi-conjugated organic ligand with a thiadiazole functionality, exhibits an unprecedented low detection limit of 66 nM for amines in aqueous solution. Markedly, this ultralow detection is driven by hydrogen-bonding interactions between the linker and the hosted amines. This observation is supported by density functional theory (DFT) calculations, which clearly corroborate the suppression of the twisting motion of thiadiazole core in the presence of amine, reducing significantly the nonradiative recombination pathways and subsequently enhancing the emission intensity. Credibly, nicotine regarded as a harmful chemical and bearing an amine pending group is also detected with high sensitivity, positioning this MOF as a potential sensor for practical environmental applications. This finding serves also as a benchmark to understand the sensing mechanism in MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2019, "Volume": 141, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7245, "End Page": 7249, "Article Number": null, "DOI": "10.1021/jacs.9b01839", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b01839", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467781600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suresh, SM; Duda, E; Hall, D; Yao, Z; Bagnich, S; Slawin, AMZ; Bässler, H; Beljonne, D; Buck, M; Olivier, Y; Köhler, A; Zysman-Colman, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suresh, Subeesh Madayanad; Duda, Eimantas; Hall, David; Yao, Zhen; Bagnich, Sergey; Slawin, Alexandra M. Z.; Baessler, Heinz; Beljonne, David; Buck, Manfred; Olivier, Yoann; Koehler, Anna; Zysman-Colman, Eli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Deep Blue B,N-Doped Heptacene Emitter That Shows Both Thermally Activated Delayed Fluorescence and Delayed Fluorescence by Triplet-Triplet Annihilation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An easy-to-access, near-UV-emitting linearly extended B,N-doped heptacene with high thermal stability is designed and synthesized in good yields. This compound exhibits thermally activated delayed fluorescence (TADF) at ambient temperature from a multiresonullt (MR) state and represents a rare example of a non-triangulene-based MR-TADF emitter. At lower temperatures triplet-triplet annihilation dominates. The compound simultaneously possesses narrow, deep-blue emission with CIE coordinates of (0.17, 0.01). While delayed fluorescence results mainly from triplet-triplet annihilation at lower temperatures in THF solution, where aggregates form upon cooling, the TADF mechanism takes over around room temperature in solution when the aggregates dissolve or when the compound is well dispersed in a solid matrix. The potential of our molecular design to trigger TADF in larger acenes is demonstrated through the accurate prediction of Delta E-ST using correlated wave-function-based calculations. On the basis of these calculations, we predicted dramatically different optoelectronic behavior in terms of both Delta E-ST and the optical energy gap of two constitutional isomers where only the boron and nitrogen positions change. A comprehensive structural, optoelectronic, and theoretical investigation is presented. In addition, the ability of the achiral molecule to assemble on a Au(111) surface to a highly ordered layer composed of enulltiomorphic domains of racemic entities is demonstrated by scanning tunneling microscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2020, "Volume": 142, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6588, "End Page": 6599, "Article Number": null, "DOI": "10.1021/jacs.9b13704", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13704", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526394200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, NN; Wu, X; Zhang, Y; Yin, YY; Sun, CZ; Mao, YC; Fan, LS; Zhang, NQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, nullnull; Wu, Xian; Zhang, Yu; Yin, Yanyou; Sun, Chengzhi; Mao, Yachun; Fan, Lishuang; Zhang, Naiqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building High Rate Capability and Ultrastable Dendrite-Free Organic Anode for Rechargeable Aqueous Zinc Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries (ZIBs) are an alternative energy storage system for large-scale grid applications compared with lithium-ion batteries, when the low cost, safety, and durability are taken into consideration. However, the reliability of the battery systems always suffers from the serious challenge of the large Zn dendrite formation and dead Zn, thus bringing out the inferior cycling stability, and even cell shorting. Herein, a dendrite-free organic anode, perylene-3,4,9,10-tetracarboxylic diimide (PTCDI) polymerized on the surface of reduced graphene oxide (PTCDI/rGO) utilized in ZIBs is reported. Moreover, the theoretical calculations prove the reason for the low redox potential. Due to the protons and zinc ions coparticipant phase transfer mechanism and the high charge transfer capability, the PTCDI/rGO electrode provides superior rate capability (121 mA h g(-1)at 5000 mA g(-1), retaining the 95% capacity of that compared with 50 mA g(-1)) and a long cycling life span (96% capacity retention after 1500 cycles at 3000 mA g(-1)). In addition, the proton coparticipation energy storage mechanism of active materials is elucidated by various ex-situ methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 7, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000146, "DOI": "10.1002/advs.202000146", "DOI Link": "http://dx.doi.org/10.1002/advs.202000146", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542847500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XQ; Zhang, YL; Li, QK; Zheng, JX; Lu, YM; Juodkazis, S; Chen, QD; Sun, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xue-Qing; Zhang, Yong-Lai; Li, Qian-Kun; Zheng, Jia-Xin; Lu, Yi-Ming; Juodkazis, Saulius; Chen, Qi-Dai; Sun, Hong-Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic sapphire windows enabled by inside-out femtosecond laser deep-scribing", "Source Title": "PHOTONIX", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Femtosecond laser machining of biomimetic micro/nullostructures with high aspect ratio (larger than 10) on ultrahard materials, such as sapphire, is a challenging task, because the uncontrollable surface damage usually results in poor surface structures, especially for deep scribing. Here, we report an inside-out femtosecond laser deep scribing technology in combination with etching process for fabricating bio-inspired micro/nullostructures with high-aspect-ratio on sapphire. To effectively avoid the uncontrollable damage at the solid/air interface, a sacrificial layer of silicon oxide was employed for surface protection. High-quality microstructures with an aspect ratio as high as 80:1 have been fabricated on sapphire surface. As a proof-of-concept application, we produced a moth-eye inspired antireflective window with sub-wavelength pyramid arrays on sapphire surface, by which broadband (3-5 mu m) and high transmittance (98% at 4 mu m, the best results reported so far) have been achieved. The sacrificial layer assisted inside-out femtosecond laser deep scribing technology is effective and universal, holding great promise for producing micro/nullostructured optical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2022, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1, "DOI": "10.1186/s43074-022-00047-3", "DOI Link": "http://dx.doi.org/10.1186/s43074-022-00047-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751321500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Sheng, T; Chen, JF; Wang, HF; Hu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dong; Sheng, Tian; Chen, Jianfu; Wang, Hai-Feng; Hu, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying the key obstacle in photocatalytic oxygen evolution on rutile TiO2", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the bottleneck in photocatalytic water splitting, the oxygen evolution reaction (OER) has drawn huge attention, but its efficiency still falls short of expectations. A widely accepted speculation is that the catalysts' activity is insufficient (high reaction barriers need to be overcome). Here, we develop a first-principles method to investigate the photocatalytic OER at the water/TiO2(110) interface. A full mechanism uncovering the importance of radicals is determined. Kinetic analysis further enables to quantitatively estimate each possible obstacle in the process. We demonstrate unambiguously that the rate-determining factor of the OER varies with the concentration of surface-reaching photoholes (Ch+). Under experimental conditions, the intrinsic catalytic activity of TiO2(110) does not represent the main obstacle, but all steps involving the photoholes are slow due to their low concentrations. This suggests that the key to enhance the OER efficiency is to increase Ch+ before Ch+ reaches the estimated threshold (Ch+ = similar to 10(-4)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 291, "End Page": 299, "Article Number": null, "DOI": "10.1038/s41929-018-0055-z", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0055-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430451900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Yang, W; Yang, W; Wang, ZQ; Rong, JH; Wang, GX; Xu, CJ; Kang, FY; Dong, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yang; Yang, Wang; Yang, Wu; Wang, Ziqi; Rong, Jianhua; Wang, Guoxiu; Xu, Chengjun; Kang, Feiyu; Dong, Liubing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards High-Energy and Anti-Self-Discharge Zn-Ion Hybrid Supercapacitors with New Understanding of the Electrochemistry", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-ion hybrid supercapacitors (ZHSs) are increasingly being studied as a novel electrochemical energy storage system with prominent electrochemical performance, high safety and low cost. Herein, high-energy and anti-self-discharge ZHSs are realized based on the fibrous carbon cathodes with hierarchically porous surface and O/N heteroatom functional groups. Hierarchically porous surface of the fabricated freestanding fibrous carbon cathodes not only provides abundant active sites for divalent ion storage, but also optimizes ion transport kinetics. Consequently, the cathodes show a high gravimetric capacity of 156 mAh g(-1) superior rate capability (79 mAh g(-1) with a very short charge/discharge time of 14 s) and exceptional cycling stability. Meanwhile, hierarchical pore structure and suitable surface functional groups of the cathodes endow ZHSs with a high energy density of 127 Wh kg(-1), a high power density of 15.3 kW kg(-1) and good anti-self-discharge performance. Mechanism investigation reveals that ZHS electrochemistry involves cation adsorption/desorption and Zn4SO4 (OH)(6)center dot 5H(2)O formation/dissolution at low voltage and anion adsorption/desorption at high voltage on carbon cathodes. The roles of these reactions in energy storage of ZHSs are elucidated. This work not only paves a way for high-performance cathode materials of ZHSs, but also provides a deeper understanding of ZHS electrochemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 95, "DOI": "10.1007/s40820-021-00625-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00625-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630369000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JW; Kim, DH; Kim, HS; Seo, SW; Cho, SM; Park, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jin-Wook; Kim, Deok-Hwan; Kim, Hui-Seon; Seo, Seung-Woo; Cho, Sung Min; Park, Nam-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formamidinium and Cesium Hybridization for Photo- and Moisture-Stable Perovskite Solar Cell", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although power conversion efficiency (PCE) of state-of-the-art perovskite solar cells has already exceeded 20%, photo- and/or moisture instability of organolead halide perovskite have prevented further commercialization. In particular, the underlying weak interaction of organic cations with surrounding iodides due to eight equivalent orientations of the organic cation along the body diagonals in unit cell and chemically non-inertness of organic cation result in photo- and moisture instability of organometal halide perovskite. Here, a perovskite light absorber incorporating organic-inorganic hybrid cation in the A-site of 3D APbI(3) structure with enhanced photo- and moisture stability is reported. A partial substitution of Cs+ for HC(NH2)(2)(+) in HC(NH2)(2)PbI3 perovskite is found to substantially improve photo- and moisture stability along with photovoltaic performance. When 10% of HC(NH2)(2)(+) is replaced by Cs+, photo- and moisture stability of perovskite film are significantly improved, which is attributed to the enhanced interaction between HC(NH2)(2)(+) and iodide due to contraction of cubo-octahedral volume. Moreover, trap density is reduced by one order of magnitude upon incorporation of Cs+, which is responsible for the increased open-circuit voltage and fill factor, eventually leading to enhancement of average PCE from 14.9% to 16.5%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1326, "Times Cited, All Databases": 1357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2015, "Volume": 5, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501310, "DOI": "10.1002/aenm.201501310", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363459400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, DJ; Bloch, ED; Mason, JA; Queen, WL; Hudson, MR; Planas, N; Borycz, J; Dzubak, AL; Verma, P; Lee, K; Bonino, F; Crocellà, V; Yano, J; Bordiga, S; Truhlar, DG; Gagliardi, L; Brown, CM; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A.; Queen, Wendy L.; Hudson, Matthew R.; Planas, Nora; Borycz, Joshua; Dzubak, Allison L.; Verma, Pragya; Lee, Kyuho; Bonino, Francesca; Crocella, Valentina; Yano, Junko; Bordiga, Silvia; Truhlar, Donald G.; Gagliardi, Laura; Brown, Craig M.; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxidation of ethane to ethanol by N2O in a metal-organic framework with coordinatively unsaturated iron(II) sites", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymatic haem and non-haem high-valent iron-oxo species are known to activate strong C-H bonds, yet duplicating this reactivity in a synthetic system remains a formidable challenge. Although instability of the terminal iron-oxo moiety is perhaps the foremost obstacle, steric and electronic factors also limit the activity of previously reported mononuclear iron(IV)-oxo compounds. In particular, although nature's non-haem iron(IV)-oxo compounds possess high-spin S = 2 ground states, this electronic configuration has proved difficult to achieve in a molecular species. These challenges may be mitigated within metal-organic frameworks that feature site-isolated iron centres in a constrained, weak-field ligand environment. Here, we show that the metal-organic framework Fe-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate) and its magnesium-diluted analogue, Fe0.1Mg1.9(dobdc), are able to activate the C-H bonds of ethane and convert it into ethanol and acetaldehyde using nitrous oxide as the terminal oxidant. Electronic structure calculations indicate that the active oxidant is likely to be a high-spin S = 2 iron(IV)-oxo species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 590, "End Page": 595, "Article Number": null, "DOI": "10.1038/NCHEM.1956", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.1956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338444600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, CL; Panwisawas, C; Ward, M; Basoalto, HC; Brooks, JW; Attallah, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Chunlei; Panwisawas, Chinnapat; Ward, Mark; Basoalto, Hector C.; Brooks, Jeffery W.; Attallah, Moataz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the role of melt flow into the surface structure and porosity development during selective laser melting", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the development of surface structure and porosity of Ti-6Al-4V samples fabricated by selective laser melting under different laser scanning speeds and powder layer thicknesses has been studied and correlated with the melt flow behaviour through both experimental and modelling approaches. The as-fabricated samples were investigated using optical microscopy (OM) and scanning electron microscopy (SEM). The interaction between laser beam and powder particles was studied by both high speed imaging observation and computational fluid dynamics (CFD) calculation. It was found that at a high laser power and a fixed powder layer thickness (20 mu m), the samples contain particularly low porosity when the laser scanning speeds are below 2700 mm/s. Further increase of scanning speed led to increase of porosity but not significantly. The porosity is even more sensitive to powder layer thickness with the use of thick powder layers (above 40 mu m) leading to significant porosity. The increase of porosity with laser scanning speed and powder layer thickness is not inconsistent with the observed increase in surface roughness complicated by increasingly irregular-shaped laser scanned tracks and an increased number of discontinuity and cave-like pores on the top surfaces. The formation of pores and development of rough surfaces were found by both high speed imaging and modelling, to be strongly associated with unstable melt flow and splashing of molten material. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 764, "Times Cited, All Databases": 844, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2015, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": 79, "Article Number": null, "DOI": "10.1016/j.actamat.2015.06.004", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.06.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358459900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XW; Li, Q; Lu, EJ; Wang, ZQ; Gong, XQ; Yu, ZY; Guo, Y; Wang, L; Guo, YL; Zhan, WC; Zhang, JS; Dai, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xinwei; Li, Qing; Lu, Erjun; Wang, Zhiqiang; Gong, Xueqing; Yu, Zhiyang; Guo, Yun; Wang, Li; Guo, Yanglong; Zhan, Wangcheng; Zhang, Jinshui; Dai, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Taming the stability of Pd active phases through a compartmentalizing strategy toward nullostructured catalyst supports", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and synthesis of robust sintering-resistant nullocatalysts for high-temperature oxidation reactions is ubiquitous in many industrial catalytic processes and still a big challenge in implementing nullostructured metal catalyst systems. Herein, we demonstrate a strategy for designing robust nullocatalysts through a sintering-resistant support via compartmentalization. Ultrafine palladium active phases can be highly dispersed and thermally stabilized by nullosheet-assembled gamma-Al2O3 (NA-Al2O3) architectures. The NA-Al2O3 architectures with unique flowerlike morphologies not only efficiently suppress the lamellar aggregation and irreversible phase transformation of gamma-Al2O3 nullosheets at elevated temperatures to avoid the sintering and encapsulation of metal phases, but also exhibit significant structural advantages for heterogeneous reactions, such as fast mass transport and easy access to active sites. This is a facile stabilization strategy that can be further extended to improve the thermal stability of other Al2O3-supported nullocatalysts for industrial catalytic applications, in particular for those involving high-temperature reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1611, "DOI": "10.1038/s41467-019-09662-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09662-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463695400026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Xu, XY; Sadd, M; Kapitanova, OO; Krivchenko, VA; Ban, J; Wang, JL; Jiao, XX; Song, ZX; Song, JX; Xiong, SZ; Matic, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yangyang; Xu, Xieyu; Sadd, Matthew; Kapitanova, Olesya O.; Krivchenko, Victor A.; Ban, Jun; Wang, Jialin; Jiao, Xingxing; Song, Zhongxiao; Song, Jiangxuan; Xiong, Shizhao; Matic, Aleksandar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insight into the Critical Role of Exchange Current Density on Electrodeposition Behavior of Lithium Metal", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to an ultrahigh theoretical specific capacity of 3860 mAh g(-1), lithium (Li) is regarded as the ultimate anode for high-energy-density batteries. However, the practical application of Li metal anode is hindered by safety concerns and low Coulombic efficiency both of which are resulted fromunavoidable dendrite growth during electrodeposition. This study focuses on a critical parameter for electrodeposition, the exchange current density, which has attracted only little attention in research on Li metal batteries. A phase-field model is presented to show the effect of exchange current density on electrodeposition behavior of Li. The results show that a uniform distribution of cathodic current density, hence uniform electrodeposition, on electrode is obtained with lower exchange current density. Furthermore, it is demonstrated that lower exchange current density contributes to form a larger critical radius of nucleation in the initial electrocrystallization that results in a dense deposition of Li, which is a foundation for improved Coulombic efficiency and dendrite-free morphology. The findings not only pave the way to practical rechargeable Li metal batteries but can also be translated to the design of stable metal anodes, e.g., for sodium (Na), magnesium (Mg), and zinc (Zn) batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003301, "DOI": "10.1002/advs.202003301", "DOI Link": "http://dx.doi.org/10.1002/advs.202003301", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605168800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, XF; Pan, JJ; Guo, HT; Wang, JW; Zhang, CM; Han, JQ; Lou, ZC; Ma, CX; Jiang, SH; Zhang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Xiaofan; Pan, Junjie; Guo, Hongtao; Wang, Jingwen; Zhang, Chunmei; Han, Jingquan; Lou, Zhichao; Ma, Chunxin; Jiang, Shaohua; Zhang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Wood-Derived Conductive Carbon Composite Film for Electromagnetic Shielding and Electric Heating Management", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, wood-based composites have absorbed widespread concern in the field of electromagnetic interference (EMI) shielding due to their sustainability and inherent layered porous structure. The channel structure of wood is often used to load highly conductive materials to improve the EMI shielding performance of wood-based composites. However, there is little research on how to use pure wood to prepare ultrathin EMI shielding materials. Herein, ultrathin veneer is obtained by cutting wood in parallel to the annual rings. Then, carbonized wood film (CWF) is prepared by a simple two-step compressing and carbonization. The specific EMI shielding effectiveness (SSE/t) of CWF-1200 with an ultrathin thickness (140 mu m) and high electrical conductivity (58 S cm(-1)) can reach 9861.41 dB cm(2) g(-1), which is much higher than other reported wood-based materials. In addition, the zeolitie imidazolate framework-8 (ZIF-8) nullocrystals are grown in situ on the surface of the CWF to obtain CWF/ZIF-8. CWF/ZIF-8 exhibits an EMI shielding effectiveness (SE) of up to 46 dB and an ultrahigh SSE/t value of 11 330.04 dB cm(2) g(-1) in X band. In addition, the ultrathin CWF also shows an excellent Joule heating effect. Therefore, the development of ultrathin wood-based film provides a research basis for wood biomass to replace traditional non-renewable and expensive electromagnetic (EM) shielding materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 33, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202213431", "DOI Link": "http://dx.doi.org/10.1002/adfm.202213431", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000919876800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, FS; Wang, JW; Luo, J; Liu, RR; Zhang, ZM; He, CT; Lu, TB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fang-Shuai; Wang, Jia-Wei; Luo, Jun; Liu, Rui-Rui; Zhang, Zhi-Ming; He, Chun-Ting; Lu, Tong-Bu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraction of nickel from NiFe-LDH into Ni2P@NiFe hydroxide as a bifunctional electrocatalyst for efficient overall water splitting", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly efficient, low-cost and stable electrocatalysts for overall water splitting is highly desirable for the storage of intermittent solar energy and wind energy sources. Herein, we show for the first time that nickel can be extracted from NiFe-layered double hydroxide (NiFe-LDH) to generate an Ni2P@FePOx heterostructure. The Ni2P@FePOx heterostructure was converted to an Ni2P@NiFe hydroxide heterostructure (P-NiFe) during water splitting, which displays high electrocatalytic performance for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in 1.0 M KOH solution, with an overpotential of 75 mV at 10 mA cm(-2) for HER, and overpotentials of 205, 230 and 430 mV at 10, 100 and 1000 mA cm(-2) for OER, respectively. Moreover, it could afford a stable current density of 10 mA cm(-2) for overall water splitting at 1.51 V in 1.0 M KOH with long-term durability (100 h). This cell voltage is among the best reported values for bifunctional electrocatalysts. The results of theoretical calculations demonstrate that P-NiFe displays optimized adsorption energies for both HER and OER intermediates at the nickel active sites, thus dramatically enhancing its electrocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2018, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1375, "End Page": 1384, "Article Number": null, "DOI": "10.1039/c7sc04569g", "DOI Link": "http://dx.doi.org/10.1039/c7sc04569g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424010600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, YM; Li, YF; Wu, JX; Meng, LS; Wang, JL; Jia, CL; Liu, T; Yang, XJ; Liu, ZP; Gong, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Yaming; Li, Yefei; Wu, Jianxiang; Meng, Lingshen; Wang, Jinling; Jia, Chenglin; Liu, Tao; Yang, Xuejing; Liu, Zhi-Pan; Gong, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recognition of Surface Oxygen Intermediates on NiFe Oxyhydroxide Oxygen-Evolving Catalysts by Homogeneous Oxidation Reactivity", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NiFe oxyhydroxide is one of the most promising oxygen evolution reaction (OER) catalysts for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen intermediates on its surface is a key challenge but is critical to the catalyst design for improving the energy efficiency. Here, we screened and utilized in situ reactive probes that can selectively target specific oxygen intermediates with high rates to investigate the OER intermediates and pathway on NiFe oxyhydroxide. Most importantly, the oxygen atom transfer (OAT) probes (e.g., 4-(diphenylphosphino) benzoic acid) could efficiently inhibit the OER kinetics by scavenging the OER intermediates, exhibiting lower OER currents, larger Tafel slopes, and larger kinetic isotope effect (KIE) values, while probes with other reactivities demonstrated much smaller effects. Combining the OAT reactivity with electrochemical kinetic and operando Raman spectroscopic techniques, we identified a resting Fe=O intermediate in the Ni-O scaffold and a rate-limiting O-O chemical coupling step between a Fe=O moiety and a vicinal bridging O. DFT calculation further revealed a longer Fe=O bond formed on the surface and a large kinetic energy barrier of the O-O chemical coupling step, corroborating the experimental results. These results point to a new direction of liberating lattice O and expediting O-O coupling for optimizing NiFe-based OER electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2021, "Volume": 143, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1493, "End Page": 1502, "Article Number": null, "DOI": "10.1021/jacs.0c11307", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c11307", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614064400030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GC; Chen, XK; Xiao, JY; Chow, PCY; Ren, MR; Kupgan, G; Jiao, XC; Chan, CCS; Du, XY; Xia, RX; Chen, ZM; Yuan, J; Zhang, YQ; Zhang, SF; Liu, YD; Zou, YP; Yan, H; Wong, KS; Coropceanu, V; Li, N; Brabec, CJ; Bredas, JL; Yip, HL; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guichuan; Chen, Xian-Kai; Xiao, Jingyang; Chow, Philip C. Y.; Ren, Minrun; Kupgan, Grit; Jiao, Xuechen; Chan, Christopher C. S.; Du, Xiaoyan; Xia, Ruoxi; Chen, Ziming; Yuan, Jun; Zhang, Yunqiang; Zhang, Shoufeng; Liu, Yidan; Zou, Yingping; Yan, He; Wong, Kam Sing; Coropceanu, Veaceslav; Li, Ning; Brabec, Christoph J.; Bredas, Jean-Luc; Yip, Hin-Lap; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Delocalization of exciton and electron wavefunction in non-fullerene acceptor molecules enables efficient organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A major challenge for organic solar cell (OSC) research is how to minimize the tradeoff between voltage loss and charge generation. In early 2019, we reported a non-fullerene acceptor (named Y6) that can simultaneously achieve high external quantum efficiency and low voltage loss for OSC. Here, we use a combination of experimental and theoretical modeling to reveal the structure-property-performance relationships of this state-of-the-art OSC system. We find that the distinctive -pi molecular packing of Y6 not only exists in molecular single crystals but also in thin films. Importantly, such molecular packing leads to (i) the formation of delocalized and emissive excitons that enable small non-radiative voltage loss, and (ii) delocalization of electron wavefunctions at donor/acceptor interfaces that significantly reduces the Coulomb attraction between interfacial electron-hole pairs. These properties are critical in enabling highly efficient charge generation in OSC systems with negligible donor-acceptor energy offset. p id=Par Y6, as a non-fullerene acceptor for organic solar cells, has attracted intensive attention because of the low voltage loss and high charge generation efficiency. Here, Zhang et al. find that the delocalization of exciton and electron wavefunction due to strong pi-pi packing of Y6 is the key for the high performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3943, "DOI": "10.1038/s41467-020-17867-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17867-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561093500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortensen, NA; Raza, S; Wubs, M; Sondergaard, T; Bozhevolnyi, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortensen, N. A.; Raza, S.; Wubs, M.; Sondergaard, T.; Bozhevolnyi, S. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A generalized non-local optical response theory for plasmonic nullostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic nullostructures exhibit a multitude of optical resonullces associated with localized surface plasmon excitations. Recent observations of plasmonic phenomena at the sub-nullometre to atomic scale have stimulated the development of various sophisticated theoretical approaches for their description. Here instead we present a comparatively simple semiclassical generalized non-local optical response theory that unifies quantum pressure convection effects and induced charge diffusion kinetics, with a concomitant complex-valued generalized non-local optical response parameter. Our theory explains surprisingly well both the frequency shifts and size-dependent damping in individual metallic nulloparticles as well as the observed broadening of the crossover regime from bonding-dipole plasmons to charge-transfer plasmons in metal nulloparticle dimers, thus unravelling a classical broadening mechanism that even dominates the widely anticipated short circuiting by quantum tunnelling. We anticipate that our theory can be successfully applied in plasmonics to a wide class of conducting media, including doped semiconductors and low-dimensional materials such as graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 461, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3809, "DOI": "10.1038/ncomms4809", "DOI Link": "http://dx.doi.org/10.1038/ncomms4809", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337372200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YL; Chen, YF; Zhang, WJ; Quek, SY; Chen, CH; Li, LJ; Hsu, WT; Chang, WH; Zheng, YJ; Chen, W; Wee, ATS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yu Li; Chen, Yifeng; Zhang, Wenjing; Quek, Su Ying; Chen, Chang-Hsiao; Li, Lain-Jong; Hsu, Wei-Ting; Chang, Wen-Hao; Zheng, Yu Jie; Chen, Wei; Wee, Andrew T. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bandgap tunability at single-layer molybdenum disulphide grain boundaries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal dichalcogenides have emerged as a new class of semiconductor materials with novel electronic and optical properties of interest to future nulloelectronics technology. Single-layer molybdenum disulphide, which represents a prototype two-dimensional transition metal dichalcogenide, has an electronic bandgap that increases with decreasing layer thickness. Using high-resolution scanning tunnelling microscopy and spectroscopy, we measure the apparent quasiparticle energy gap to be 2.40 +/- 0.05 eV for single-layer, 2.10 +/- 0.05 eV for bilayer and 1.75 +/- 0.05 eV for trilayer molybdenum disulphide, which were directly grown on a graphite substrate by chemical vapour deposition method. More interestingly, we report an unexpected bandgap tunability (as large as 0.85 +/- 0.05 eV) with distance from the grain boundary in single-layer molybdenum disulphide, which also depends on the grain misorientation angle. This work opens up new possibilities for flexible electronic and optoelectronic devices with tunable bandgaps that utilize both the control of two-dimensional layer thickness and the grain boundary engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 438, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6298, "DOI": "10.1038/ncomms7298", "DOI Link": "http://dx.doi.org/10.1038/ncomms7298", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358165200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahne, N; Schafzahl, B; Leypold, C; Leypold, M; Grumm, S; Leitgeb, A; Strohmeier, GA; Wilkening, M; Fontaine, O; Kramer, D; Slugovc, C; Borisov, SM; Freunberger, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahne, Nika; Schafzahl, Bettina; Leypold, Christian; Leypold, Mario; Grumm, Sandra; Leitgeb, Anita; Strohmeier, Gernot A.; Wilkening, Martin; Fontaine, Olivier; Kramer, Denis; Slugovc, Christian; Borisov, Sergey M.; Freunberger, Stefan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium-oxygen batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-aqueous metal-oxygen batteries depend critically on the reversible formation/decomposition of metal oxides on cycling. Irreversible parasitic reactions cause poor rechargeability, efficiency, and cycle life, and have predominulltly been ascribed to the reactivity of reduced oxygen species with cell components. These species, however, cannot fully explain the side reactions. Here we show that singlet oxygen forms at the cathode of a lithium-oxygen cell during discharge and from the onset of charge, and accounts for the majority of parasitic reaction products. The amount increases during discharge, early stages of charge, and charging at higher voltages, and is enhanced by the presence of trace water. Superoxide and peroxide appear to be involved in singlet oxygen generation. Singlet oxygen traps and quenchers can reduce parasitic reactions effectively. Awareness of the highly reactive singlet oxygen in non-aqueous metal-oxygen batteries gives a rationale for future research towards achieving highly reversible cell operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17036, "DOI": "10.1038/nenergy.2017.36", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.36", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404895300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Bhaumik, S; Veldhuis, SA; Xing, G; Xu, Q; Gratzel, M; Mhaisalkar, S; Mathews, N; Sum, TC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Weiqiang; Bhaumik, Saikat; Veldhuis, Sjoerd A.; Xing, Guichuan; Xu, Qiang; Gratzel, Michael; Mhaisalkar, Subodh; Mathews, Nripan; Tze Chien Sum", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant five-photon absorption from multidimensional core-shell halide perovskite colloidal nullocrystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiphoton absorption processes enable many technologically important applications, such as in vivo imaging, photodynamic therapy and optical limiting, and so on. Specifically, higher-order nonlinear absorption such as five-photon absorption offers significant advantages of greater spatial confinement, increased penetration depth, reduced autofluorescence, enhanced sensitivity and improved resolution over lower orders in bioimaging. Organic chromophores and conventional semiconductor nullocrystals are leaders in two-/three-photon absorption applications, but face considerable challenges from their small five-photon action cross-sections. Herein, we reveal that the family of halide perovskite colloidal nullocrystals transcend these constraints with highly efficient five-photon-excited upconversion fluorescence-unprecedented for semiconductor nullocrystals. Amazingly, their multidimensional type I (both conduction and valence band edges of core lie within bandgap of shell) core-shell (three-dimensional methylammonium lead bromide/two-dimensional octylammonium lead bromide) perovskite nullocrystals exhibit five-photon action cross-sections that are at least 9 orders larger than state-of-the-art specially designed organic molecules. Importantly, this family of halide perovskite nullocrystals may enable fresh approaches for next-generation multiphoton imaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15198, "DOI": "10.1038/ncomms15198", "DOI Link": "http://dx.doi.org/10.1038/ncomms15198", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401222500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, YR; Vernieres, J; Wang, ZB; Zhang, K; Hochfilzer, D; Krempl, K; Liao, TW; Presel, F; Altantzis, T; Fatermans, J; Scott, SB; Secher, NM; Moon, C; Liu, P; Bals, S; Van Aert, S; Cao, A; Anulld, M; Norskov, JK; Kibsgaard, J; Chorkendorff, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Ya-Rong; Vernieres, Jerome; Wang, Zhenbin; Zhang, Ke; Hochfilzer, Degenhart; Krempl, Kevin; Liao, Ting-Wei; Presel, Francesco; Altantzis, Thomas; Fatermans, Jarmo; Scott, Soren Bertelsen; Secher, Niklas Morch; Moon, Choongman; Liu, Pei; Bals, Sara; Van Aert, Sandra; Cao, Ang; Anulld, Megha; Norskov, Jens K.; Kibsgaard, Jakob; Chorkendorff, Ib", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monitoring oxygen production on mass-selected iridium-tantalum oxide electrocatalysts", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of low-cost and high-performance oxygen evolution reaction catalysts is key to implementing polymer electrolyte membrane water electrolysers for hydrogen production. Iridium-based oxides are the state-of-the-art acidic oxygen evolution reaction catalysts but still suffer from inadequate activity and stability, and iridium's scarcity motivates the discovery of catalysts with lower iridium loadings. Here we report a mass-selected iridium-tantalum oxide catalyst prepared by a magnetron-based cluster source with considerably reduced noble-metal loadings beyond a commercial IrO2 catalyst. A sensitive electrochemistry/mass-spectrometry instrument coupled with isotope labelling was employed to investigate the oxygen production rate under dynamic operating conditions to account for the occurrence of side reactions and quantify the number of surface active sites. Iridium-tantalum oxide nulloparticles smaller than 2 nm exhibit a mass activity of 1.2 +/- 0.5 kA g(Ir)(-1) and a turnover frequency of 2.3 +/- 0.9 s(-1) at 320 mV overpotential, which are two and four times higher than those of mass-selected IrO2, respectively. Density functional theory calculations reveal that special iridium coordinations and the lowered aqueous decomposition free energy might be responsible for the enhanced performance. Low-cost, high-performance oxygen evolution catalysts would facilitate implementation of water electrolysers for hydrogen production. Here the authors report a low-iridium mass-selected iridium-tantalum oxide catalyst with high intrinsic activity in acid and carefully evaluate oxygen production to account for parasitic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 55, "End Page": 64, "Article Number": null, "DOI": "10.1038/s41560-021-00948-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00948-w", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000728458000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Doherty, TAS; Winchester, AJ; Macpherson, S; Johnstone, DN; Pareek, V; Tennyson, EM; Kosar, S; Kosasih, FU; Anaya, M; Abdi-Jalebi, M; Andaji-Garmaroudi, Z; Wong, EL; Madeo, J; Chiang, YH; Park, JS; Jung, YK; Petoukhoff, CE; Divitini, G; Man, MKL; Ducati, C; Walsh, A; Midgley, PA; Dani, KM; Stranks, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Doherty, Tiarnull A. S.; Winchester, Andrew J.; Macpherson, Stuart; Johnstone, Duncan N.; Pareek, Vivek; Tennyson, Elizabeth M.; Kosar, Sofiia; Kosasih, Felix U.; Anaya, Miguel; Abdi-Jalebi, Mojtaba; Andaji-Garmaroudi, Zahra; Wong, E. Laine; Madeo, Julien; Chiang, Yu-Hsien; Park, Ji-Sang; Jung, Young-Kwang; Petoukhoff, Christopher E.; Divitini, Giorgio; Man, Michael K. L.; Ducati, Caterina; Walsh, Aron; Midgley, Paul A.; Dani, Keshav M.; Stranks, Samuel D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance-limiting nulloscale trap clusters at grain junctions in halide perovskites", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskite materials have promising performance characteristics for low-cost optoelectronic applications. Photovoltaic devices fabricated from perovskite absorbers have reached power conversion efficiencies above 25 per cent in single-junction devices and 28 per cent in tandem devices(1,2). This strong performance (albeit below the practical limits of about 30 per cent and 35 per cent, respectively(3)) is surprising in thin films processed from solution at low-temperature, a method that generally produces abundant crystalline defects(4). Although point defects often induce only shallow electronic states in the perovskite bandgap that do not affect performance(5), perovskite devices still have many states deep within the bandgap that trap charge carriers and cause them to recombine non-radiatively. These deep trap states thus induce local variations in photoluminescence and limit the device performance(6). The origin and distribution of these trap states are unknown, but they have been associated with light-induced halide segregation in mixed-halide perovskite compositions(7) and with local strain(8), both of which make devices less stable(9). Here we use photoemission electron microscopy to image the trap distribution in state-of-the-art halide perovskite films. Instead of a relatively uniform distribution within regions of poor photoluminescence efficiency, we observe discrete, nulloscale trap clusters. By correlating microscopy measurements with scanning electron analytical techniques, we find that these trap clusters appear at the interfaces between crystallographically and compositionally distinct entities. Finally, by generating time-resolved photoemission sequences of the photo-excited carrier trapping process(10,11), we reveal a hole-trapping character with the kinetics limited by diffusion of holes to the local trap clusters. Our approach shows that managing structure and composition on the nulloscale will be essential for optimal performance of halide perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2020, "Volume": 580, "Issue": 7803, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 360, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2184-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2184-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530151300027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZF; Liu, Y; Zhen, SJ; Li, XX; Zhang, WG; Sun, X; Xu, BY; Wang, X; Gao, ZH; Meng, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zifei; Liu, Yang; Zhen, Shijie; Li, Xiaoxi; Zhang, Weiguang; Sun, Xun; Xu, Baoyuan; Wang, Xue; Gao, Zhenhua; Meng, Xiangeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gram-Scale Synthesis of 41% Efficient Single-Component White-Light-Emissive Carbonized Polymer Dots with Hybrid Fluorescence/Phosphorescence for White Light-Emitting Diodes", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluorescent carbon dots (CDs) are compelling optical emitters to construct white light-emitting diodes (WLEDs). However, it remains a challenge to achieve large-scale and highly efficient single-component white-light-emissive CDs suitable for WLED applications. Herein, a low cost, fast processable, environmentally friendly, and one-step synthetic approach is developed for the preparation of gram-scale and highly efficient single-component white-light-emissive carbonized polymer dots (SW-CPDs). It is revealed that hybrid fluorescence/phosphorescence components cooperatively contribute to the emergence of white light emission. The SW-CPDs exhibit a record quantum yield (QY) of approximate to 41% for the white light emission observed in solid-state CD systems, while the QY of the phosphorescence is approximate to 23% under ambient conditions. Heavy doping of N and P elements as well as presence of covalently cross-linked polymer frameworks is suggested to account for the emergence of hybrid fluorescence/phosphorescence, which is supported by the experimental results and theoretical calculations. A WLED is fabricated by applying the SW-CPDs on an UV-LED chip, showing favorable white-light-emitting characteristics with a high luminous efficacy of 18.7 lm W-1 that is comparable to that of state-of-the-art WLEDs reported before.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902688, "DOI": "10.1002/advs.201902688", "DOI Link": "http://dx.doi.org/10.1002/advs.201902688", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507436700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, WW; Wang, XM; Xiao, ZW; Wang, JB; Mitzi, DB; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Weiwei; Wang, Xiaoming; Xiao, Zewen; Wang, Jianbo; Mitzi, David B.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Parity-Forbidden Transitions and Their Impact on the Optical Absorption Properties of Lead-Free Metal Halide Perovskites and Double Perovskites", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using density functional theory calculations, we analyze the optical absorption properties of lead (Pb)-free metal halide perovskites (AB(2+)X(3)) and double perovskites (A(2)B(+)B(3+)X(6)) (A = Cs or monovalent organic ion, B2+ = non-Pb divalent metal, B+ = monovalent metal, B3+ = trivalent metal, X = halogen). We show that if B2+ is not Sn or Ge, Pb-free metal halide perovskites exhibit poor optical absorptions because of their indirect band gap nature. Among the nine possible types of Pb-free metal halide double perovskites, six have direct band gaps. Of these six types, four show inversion symmetry-induced parity-forbidden or weak transitions between band edges, making them not ideal for thin-film solar cell applications. Only one type of Pb-free double perovskite shows optical absorption and electronic properties suitable for solar cell applications, namely, those with B+ = In, Tl and B3+ = Sb, Bi. Our results provide important insights for designing new metal halide perovskites and double perovskites for optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 539, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2017, "Volume": 8, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2999, "End Page": 3007, "Article Number": null, "DOI": "10.1021/acs.jpclett.7b01042", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.7b01042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405252600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YCY; Li, XF; Yang, HL; Zhang, P; Wang, PH; Sun, Y; Yang, FZ; Liu, WY; Li, YJ; Tian, Y; Qian, S; Chen, SD; Cheng, HY; Wang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yangchengyi; Li, Xiaofeng; Yang, Hanlin; Zhang, Ping; Wang, Peihe; Sun, Yi; Yang, Fengzhen; Liu, Weiyi; Li, Yujing; Tian, Yao; Qian, Shun; Chen, Shangda; Cheng, Huanyu; Wang, Xiufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-Interfaced Superhydrophobic Insensible Sweat Sensors for Evaluating Body and Skin Barrier Functions", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monitoring sweat rate is vital for estimating sweat loss and accurately measuring biomarkers of interest. Although various optical or electrical sensors have been developed to monitor the sensible sweat rate, the quantification of the insensible sweat rate that is directly related to body thermo-regulation and skin barrier functions still remains a challenge. This work introduces a superhydrophobic sweat sensor based on a polyacrylate sodium/MXene composite sandwiched between two superhydrophobic textile layers to continuously measure sweat vapor from insensible sweat with high sensitivity and rapid response. The superhydrophobic textile on a holey thin substrate with reduced stiffness and excellent breathability allows the permeation of sweat vapor, while preventing the sensor from being affected by the external water droplets and internal sensible sweat. Integrating the insensible sweat sensor with a flexible wireless communication and powering module further yields a standalone sensing system to continuously monitor insensible sweat rates at different body locations for diverse application scenarios. Proof-of-concept demonstrations on human subjects showcase the feasibility to continuously evaluate the body's thermoregulation and skin barrier functions for the assessment of thermal comfort, disease conditions, and nervous system activity. The results presented in this work also provide a low-cost device platform to detect other health-relevant biomarkers in the sweat (vapor) as the next-generation sweat sensor for smart healthcare and personalized medicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2023, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5588, "End Page": 5599, "Article Number": null, "DOI": "10.1021/acsnullo.2c11267", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c11267", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000960130800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwon, O; Sengodan, S; Kim, K; Kim, G; Jeong, HY; Shin, J; Ju, YW; Han, JW; Kim, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwon, Ohhun; Sengodan, Sivaprakash; Kim, Kyeounghak; Kim, Gihyeon; Jeong, Hu Young; Shin, Jeeyoung; Ju, Young-Wan; Han, Jeong Woo; Kim, Guntae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exsolution trends and co-segregation aspects of self-grown catalyst nulloparticles in perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In perovskites, exsolution of transition metals has been proposed as a smart catalyst design for energy applications. Although there exist transition metals with superior catalytic activity, they are limited by their ability to exsolve under a reducing environment. When a doping element is present in the perovskite, it is often observed that the surface segregation of the doping element is changed by oxygen vacancies. However, the mechanism of co-segregation of doping element with oxygen vacancies is still an open question. Here we report trends in the exsolution of transition metal (Mn, Co, Ni and Fe) on the PrBaMn2O5-delta layered perovskite oxide related to the co-segregation energy. Transmission electron microscopic observations show that easily reducible cations (Mn, Co and Ni) are exsolved from the perovskite depending on the transition metal-perovskite reducibility. In addition, using density functional calculations we reveal that co-segregation of B-site dopant and oxygen vacancies plays a central role in the exsolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15967, "DOI": "10.1038/ncomms15967", "DOI Link": "http://dx.doi.org/10.1038/ncomms15967", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404226300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Talebi, H; Silani, M; Bordas, SPA; Kerfriden, P; Rabczuk, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Talebi, Hossein; Silani, Mohammad; Bordas, Stephane P. A.; Kerfriden, Pierre; Rabczuk, Timon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A computational library for multiscale modeling of material failure", "Source Title": "COMPUTATIONAL MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an open-source software framework called PERMIX for multiscale modeling and simulation of fracture in solids. The framework is an object oriented open-source effort written primarily in Fortran 2003 standard with Fortran/C++ interfaces to a number of other libraries such as LAMMPS, ABAQUS, LS-DYNA and GMSH. Fracture on the continuum level is modeled by the extended finite element method (XFEM). Using several novel or state of the art methods, the piece software handles semi-concurrent multiscale methods as well as concurrent multiscale methods for fracture, coupling two continuum domains or atomistic domains to continuum domains, respectively. The efficiency of our open-source software is shown through several simulations including a 3D crack modeling in clay nullocomposites, a semi-concurrent FE-FE coupling, a 3D Arlequin multiscale example and an MD-XFEM coupling for dynamic crack propagation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 505, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 53, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1047, "End Page": 1071, "Article Number": null, "DOI": "10.1007/s00466-013-0948-2", "DOI Link": "http://dx.doi.org/10.1007/s00466-013-0948-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334280600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, XY; Wang, HF; Yang, F; Shen, H; Wang, X; Wu, DC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Xueyu; Wang, Hufei; Yang, Fei; Shen, Hong; Wang, Xing; Wu, Decheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Step Soaking Strategy toward Anti-Swelling Hydrogels with a Stiff Armor", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Double-network (DN) hydrogels consisting of noncovalent interacting networks are highly desired due to their well-controlled compositions and environmental friendliness, but the low water resistance always impairs their mechanical strength. Here, an anti-swelling hydrogel possessing the core/shell architecture through rational regulation of multiple weak noncovalent interactions is prepared. A composite hydrogel consists of chitosan (CS) and poly(N-acryloyl 2-glycine) (PACG), readily forming the shell-structured DN hydrogel after soaking in a FeCl3 solution because of in situ formation of chain entanglements, hydrogen bonds, and ionic coordination. The produced DN hydrogels exhibit excellent anti-swelling behaviors and mechanical durability for over half a year, even in some strict situations. Taking the merits of noncovalent bonds in adjustability and reversibility, the swelling property of these hydrogels can be easily customized through control of the ion species and concentrations. A dynamically reversible transition from super-swelling to anti-swelling is realized by breaking up and rebuilding the metal-coordination complexes. This facile but efficient strategy of turning the noncovalent interactions and consequently the mechanics and anti-swelling properties is imperative to achieve the rational design of high-performance hydrogels with specific usage requirements and expand their applicability to a higher stage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206242", "DOI Link": "http://dx.doi.org/10.1002/advs.202206242", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000916705400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ST; Li, XY; Yu, TL; Wang, J; Fang, H; Nie, F; He, B; Zhao, L; Lu, WM; Yan, SS; Nogaret, A; Liu, G; Zheng, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shu-Ting; Li, Xing-Yu; Yu, Tong-Liang; Wang, Jie; Fang, Hong; Nie, Fang; He, Bin; Zhao, Le; Lu, Wei-Ming; Yan, Shi-Shen; Nogaret, Alain; Liu, Gang; Zheng, Li-Mei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Neuromorphic Computing Based on Ferroelectric Synapses with Excellent Conductance Linearity and Symmetry", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial synapses can boost neuromorphic computing to overcome the inherent limitations of von Neumann architecture. As a promising memristor candidate, ferroelectric tunnel junctions (FTJ) enable the authors to successfully emulate spike-timing-dependent synapses. However, the nonlinear and asymmetric synaptic weight update under repeated presynaptic stimulation hampers neuromorphic computing by favoring the runaway of synaptic weights during learning. Here, the authors demonstrate an FTJ whose conductivity varies linearly and symmetrically by judiciously combining ferroelectric domain switching and oxygen vacancy migration. The artificial neural network based on this FTJ-synapse achieves classification accuracy of 96.7% during supervised learning, which is the closest to the maximum theoretical value of 98% achieved to date. This artificial synapse also demonstrates stable unsupervised learning in a noisy environment for its well-balanced spike-timing-dependent plasticity response. The novel concept of controlling ionic migration in ferroelectric materials paves the way toward highly reliable and reproducible supervised and unsupervised learning strategies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 32, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202366, "DOI": "10.1002/adfm.202202366", "DOI Link": "http://dx.doi.org/10.1002/adfm.202202366", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000814096700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Delaney, M; Zeimpekis, I; Lawson, D; Hewak, DW; Muskens, OL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Delaney, Matthew; Zeimpekis, Ioannis; Lawson, Daniel; Hewak, Daniel W.; Muskens, Otto L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Family of Ultralow Loss Reversible Phase-Change Materials for Photonic Integrated Circuits: Sb2S3 and Sb2Se3", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase-change materials (PCMs) are seeing tremendous interest for their use in reconfigurable photonic devices; however, the most common PCMs exhibit a large absorption loss in one or both states. Here, Sb(2)S(3)and Sb(2)Se(3)are demonstrated as a class of low loss, reversible alternatives to the standard commercially available chalcogenide PCMs. A contrast of refractive index of Delta n = 0.60 for Sb(2)S(3)and Delta n = 0.77 for Sb(2)Se(3)is reported, while maintaining very low losses (k < 10(-5)) in the telecommunications C-band at 1550 nm. With a stronger absorption in the visible spectrum, Sb(2)Se(3)allows for reversible optical switching using conventional visible wavelength lasers. Here, a stable switching endurance of better than 4000 cycles is demonstrated. To deal with the essentially zero intrinsic absorption losses, a new figure of merit (FOM) is introduced taking into account the measured waveguide losses when integrating these materials onto a standard silicon photonics platform. The FOM of 29 rad phase shift per dB of loss for Sb(2)Se(3)outperforms Ge(2)Sb(2)Te(5)by two orders of magnitude and paves the way for on-chip programmable phase control. These truly low-loss switchable materials open up new directions in programmable integrated photonic circuits, switchable metasurfaces, and nullophotonic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 30, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002447, "DOI": "10.1002/adfm.202002447", "DOI Link": "http://dx.doi.org/10.1002/adfm.202002447", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546297500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Ai, D; Ren, LL; Yao, B; Han, ZB; Shen, ZH; Wang, JJ; Chen, LQ; Wang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, He; Ai, Ding; Ren, Lulu; Yao, Bin; Han, Zhubing; Shen, Zhonghui; Wang, Jianjun; Chen, Long-Qing; Wang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable Polymer nullocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed nullostructured Inorganic Fillers", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation microelectronics and electrical power systems call for high-energy-density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution-processable polymer nullocomposites consisting of readily prepared Al2O3 fillers with systematically varied morphologies including nulloparticles, nullowires, and nulloplates are reported. The field-dependent electrical conduction of the polymer nullocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al2O3 nulloplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm(-3) and a charge-discharge efficiency of >90% measured at 450 MV m(-1) and 150 degrees C, significantly outperforming the state-of-the-art dielectric polymers and nullocomposites that are typically prepared via tedious, low-yield approaches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 31, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900875, "DOI": "10.1002/adma.201900875", "DOI Link": "http://dx.doi.org/10.1002/adma.201900875", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474087100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, JH; Wang, ZY; Xu, P; Wang, C; Gao, F; Zhao, DC; Liu, SP; Yang, H; Wang, D; Niu, CM; Zhu, YS; Wu, YT; Liu, X; Wang, ZL; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Jinghui; Wang, Zhenyu; Xu, Peng; Wang, Cong; Gao, Fei; Zhao, Decheng; Liu, Shupei; Yang, Han; Wang, Di; Niu, Chunming; Zhu, Yusong; Wu, Yutong; Liu, Xiang; Wang, Zhoulu; Zhang, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Co2VO4 nullodisk as a High-Energy and Fast-Charging Anode for Lithium-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy-density lithium-ion batteries (LIBs) that can be safely fast-charged are desirable for electric vehicles. However, sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues and low energy density. Here we hypothesize that a cobalt vanadate oxide, Co2VO4, can be attractive anode material for fast-charging LIBs due to its high capacity (similar to 1000 mAh g(-1)) and safe lithiation potential (similar to 0.65 V vs. Li+/Li). The Li+ diffusion coefficient of Co2VO4 is evaluated by theoretical calculation to be as high as 3.15 x 10(-10) cm(2) s(-1), proving (CoVO4)-V-2 a promising anode in fast-charging LIBs. A hexagonal porous (CoVO4)-V-2 nullodisk (PCVO ND) structure is designed accordingly, featuring a high specific surface area of 74.57 m(2) g(-1) and numerous pores with a pore size of 14 nm. This unique structure succeeds in enhancing Li+ and electron transfer, leading to superior fast-charging performance than current commercial anodes. As a result, the PCVO ND shows a high initial reversible capacity of 911.0 mAh g(-1) at 0.4 C, excellent fast-charging capacity (344.3 mAh g(-1) at 10 C for 1000 cycles), outstanding long-term cycling stability (only 0.024% capacity loss per cycle at 10 C for 1000 cycles), confirming the commercial feasibility of PCVO ND in fast-charging LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5, "DOI": "10.1007/s40820-021-00758-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00758-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000725606600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Dong, LZ; Li, S; Huang, X; Chang, JN; Wang, JH; Zhou, J; Li, SL; Lan, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yu; Dong, Long-Zhang; Li, Shan; Huang, Xin; Chang, Jia-null; Wang, Jian-Hui; Zhou, Jie; Li, Shun-Li; Lan, Ya-Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical CO2 reduction to high-value-added chemicals is one of the most promising and challenging research in the energy conversion field. An efficient ECR catalyst based on a Cu-based conductive metal-organic framework (Cu-DBC) is dedicated to producing CH4 with superior activity and selectivity, showing a Faradaic efficiency of CH4 as high as similar to 80% and a large current density of -203 mA cm(-2) at -0.9 V vs. RHE. The further investigation based on theoretical calculations and experimental results indicates the Cu-DBC with oxygen-coordinated Cu sites exhibits higher selectivity and activity over the other two crystalline ECR catalysts with nitrogen-coordinated Cu sites due to the lower energy barriers of Cu-O-4 sites during ECR process. This work unravels the strong dependence of ECR selectivity on the Cu site coordination environment in crystalline porous catalysts, and provides a platform for constructing highly selective ECR catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 176, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6390, "DOI": "10.1038/s41467-021-26724-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26724-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714754400048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HP; Wu, W; Jiang, C; Ding, Y; Bian, WJ; Hu, BX; Singh, P; Orme, CJ; Wang, LC; Zhang, YY; Ding, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Hanping; Wu, Wei; Jiang, Chao; Ding, Yong; Bian, Wenjuan; Hu, Boxun; Singh, Prabhakar; Orme, Christopher J.; Wang, Lucun; Zhang, Yunya; Ding, Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The protonic ceramic electrochemical cell (PCEC) is an emerging and attractive technology that converts energy between power and hydrogen using solid oxide proton conductors at intermediate temperatures. To achieve efficient electrochemical hydrogen and power production with stable operation, highly robust and durable electrodes are urgently desired to facilitate water oxidation and oxygen reduction reactions, which are the critical steps for both electrolysis and fuel cell operation, especially at reduced temperatures. In this study, a triple conducting oxide of PrNi0.5Co0.5O3-delta perovskite is developed as an oxygen electrode, presenting superior electrochemical performance at 400 similar to 600 degrees C. More importantly, the self-sustainable and reversible operation is successfully demonstrated by converting the generated hydrogen in electrolysis mode to electricity without any hydrogen addition. The excellent electrocatalytic activity is attributed to the considerable proton conduction, as confirmed by hydrogen permeation experiment, remarkable hydration behavior and computations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1907, "DOI": "10.1038/s41467-020-15677-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15677-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558828600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QB; Liu, MZ; Zhang, C; Zhu, WQ; Wang, YL; Lin, PC; Yan, F; Chen, L; Lezec, HJ; Lu, YQ; Agrawal, A; Xu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Qingbin; Liu, Mingze; Zhang, Cheng; Zhu, Wenqi; Wang, Yilin; Lin, Peicheng; Yan, Feng; Chen, Lu; Lezec, Henri J.; Lu, Yanqing; Agrawal, Amit; Xu, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Independent Amplitude Control of Arbitrary Orthogonal States of Polarization via Dielectric Metasurfaces", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exquisite polarization control using optical metasurfaces has attracted considerable attention thanks to their ability to manipulate multichannel independent wavefronts with subwavelength resolution. Here we present a new class of metasurface polarization optics, which enables imposition of two arbitrary and independent amplitude profiles on any pair of orthogonal states of polarization. The implementation method involves a polarization-dependent interference mechanism achieved by constructing a metasurface composed of an array of nulloscale birefringent waveplates. Based on this principle, we experimentally demonstrate chiral grayscale metasurface and chiral shadow rendering of structured light. These results illustrate a general approach interlinking amplitude profiles and orthogonal states of polarization and expands the scope of metasurface polarization shaping optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2020, "Volume": 125, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 267402, "DOI": "10.1103/PhysRevLett.125.267402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.267402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000601155900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XH; Liu, DH; Jin, TZ; Chen, WJ; He, Q; Zou, ZP; Zhao, HH; Ye, XQ; Guo, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xinhui; Liu, Donghong; Jin, Tony Z.; Chen, Weijun; He, Qiao; Zou, Zhipeng; Zhao, Huanhuan; Ye, Xingqian; Guo, Mingming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation and characterization of gellan gum-chitosan polyelectrolyte complex films with the incorporation of thyme essential oil nulloemulsion", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimicrobial food packaging with a sustained release of antimicrobial agents plays a key role in maintaining food quality and food safety. In this study, polyelectrolyte gellan gum (GG)-chitosan (CS) multilayer film was fabricated by layer-by-layer assembly technology with the incorporation of thyme essential oil (TEO) coarse emulsion (TEOC) or nulloemulsion (TEON). The microstructure of GG-CS three-layered film was observed by scanning electron microscopy (SEM). The red fluorescent signals in confocal laser scanning microscopy (CLSM) images indicated smaller droplets and more uniform distribution of TEON prepared by ultrasonic treatments, which was consistent with the particle size results and porous structure in SEM images. The film incorporated with 6% TEON exhibited higher antimicrobial activity than that with 6% TEOC, and it significantly reduced E. coli populations in liquid model system. Moreover, films incorporated with TEON showed improved mechanical flexibility (elongation at break) and UV blocking property in comparison to TEOC. This developed GGCS three-layered film loading with TEON was expected to be a potential antimicrobial material with sustained release property for food packaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 114, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106570, "DOI": "10.1016/j.foodhyd.2020.106570", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2020.106570", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612695000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Qiu, T; Zhang, JH; Baldini, E; Lu, J; Rappe, AM; Nelson, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xian; Qiu, Tian; Zhang, Jiahao; Baldini, Edoardo; Lu, Jian; Rappe, Andrew M.; Nelson, Keith A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Terahertz field-induced ferroelectricity in quantum paraelectric SrTiO3", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hidden phases are metastable collective states of matter that are typically not accessible on equilibrium phase diagrams. These phases can host exotic properties in otherwise conventional materials and hence may enable novel functionality and applications, but their discovery and access are still in early stages. Using intense terahertz electric field excitation, we found that an ultrafast phase transition into a hidden ferroelectric phase can be dynamically induced in quantum paraelectric strontium titanate (SrTiO3). The induced lowering in crystal symmetry yields substantial changes in the phonon excitation spectra. Our results demonstrate collective coherent control over material structure, in which a single-cycle field drives ions along the microscopic pathway leading directly to their locations in a new crystalline phase on an ultrafast time scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2019, "Volume": 364, "Issue": 6445, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1079, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw4913", "DOI Link": "http://dx.doi.org/10.1126/science.aaw4913", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471306700043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SS; Wang, MF; Qian, T; Ji, HQ; Liu, J; Yan, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Sisi; Wang, Mengfan; Qian, Tao; Ji, Haoqing; Liu, Jie; Yan, Chenglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facilitating nitrogen accessibility to boron-rich covalent organic frameworks via electrochemical excitation for efficient nitrogen fixation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks with abundant active sites are potential metal-free catalysts for the nitrogen reduction reaction. However, the utilization ratio of active sites is restricted in an actual reaction process due to the limited nitrogen transport. Here, we demonstrate that facilitating the N-2 accessibility to boron-rich covalent organic frameworks through electrochemical excitation can achieve highly efficient nitrogen reduction activity. Simulations show that the boron sites are bonded with nitrogenous species under electrochemical condition and the resultant amorphous phase of covalent organic frameworks has much stronger affinity toward N-2 to enhance the molecule collision. Combined with experimental results, the excitation process is confirmed to be a virtuous cycle of more excited sites and stronger N-2 affinity, which continuously proceed until the whole system reaches the optimum reaction status. As expected, the electrochemically excited catalyst delivers significantly enhanced reaction activity, with a high Faradaic efficiency of 45.43%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3898, "DOI": "10.1038/s41467-019-11846-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11846-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483017900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roy, P; Chen, PC; Periasamy, AP; Chen, YN; Chang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roy, Prathik; Chen, Po-Cheng; Periasamy, Arun Prakash; Chen, Ya-Na; Chang, Huan-Tsung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photoluminescent carbon nullodots: synthesis, physicochemical properties and analytical applications", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nullodots (C-dots) possessing photoluminescence (PL) properties have become interesting materials for sensing and imaging, with the advantages of water-dispersibility, biocompatibility, chemical and photo stability. They can be prepared from organic matter such as tea, grass, coffee, and small organic molecules like glycine and glucose through hydrothermal routes. In this review, we focus on the recent advances in the synthesis and characterization of C-dots along with their optical (absorption, PL, upconverted PL) properties and analytical applications. Having bright PL, biocompatibility, chemical and photo stability, as well as low toxicity, C-dots have been used for the detection of metal ions and for cell imaging. C-dots prepared from organic matter such as used tea and ginger possess a great inhibitory effect on the growth of cancer cells, showing their excellent potential as new drugs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 18, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 447, "End Page": 458, "Article Number": null, "DOI": "10.1016/j.mattod.2015.04.005", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.04.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361834000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ciarrocchi, A; Unuchek, D; Avsar, A; Watanabe, K; Taniguchi, T; Kis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ciarrocchi, Alberto; Unuchek, Dmitrii; Avsar, Ahmet; Watanabe, Kenji; Taniguchi, Takashi; Kis, Andras", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polarization switching and electrical control of interlayer excitons in two-dimensional van der Waals heterostructures", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The long-lived interlayer excitons in van der Waals heterostructures based on transition-metal dichalcogenides, together with unique spin-valley physics, make them promising for next-generation photonic and valleytronic devices. Although the emission characteristics of interlayer excitons have been studied, efficient manipulation of their valley states, a necessary requirement for information encoding, is still lacking. Here, we demonstrate comprehensive electrical control of interlayer excitons in a MoSe2/WSe2 heterostructure. Encapsulation of our well-aligned stack with hexagonal boron nitride (h-BN) allows us to resolve two separate narrow interlayer transitions with opposite helicities under circularly polarized excitation, either preserving or reversing the polarization of incoming light. By electrically controlling their relative intensities, we realize a polarization switch with tunable emission intensity and wavelength. Finally, we observe large g-factors of these two transitions on application of an external magnetic field. These results are interpreted within the picture of moire-induced brightening of forbidden optical transitions. The ability to control the polarization of interlayer excitons is a step towards the manipulation of the valley degree of freedom in realistic device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 131, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-018-0325-y", "DOI Link": "http://dx.doi.org/10.1038/s41566-018-0325-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456652900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, ZT; Xiang, YX; Wang, KJ; Zhu, JP; Jin, YT; Wang, HC; Zheng, BZ; Chen, ZR; Tao, MM; Liu, XS; Wu, YQ; Fu, RQ; Wang, CS; Winter, M; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Ziteng; Xiang, Yuxuan; Wang, Kangjun; Zhu, Jianping; Jin, Yanting; Wang, Hongchun; Zheng, Bizhu; Chen, Zirong; Tao, Mingming; Liu, Xiangsi; Wu, Yuqi; Fu, Riqiang; Wang, Chunsheng; Winter, Martin; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the failure process of sulfide-based all-solid-state lithium batteries via operando nuclear magnetic resonullce spectroscopy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state lithium batteries performance is affected by the solid electrolyte interphase (SEI) and electrically disconnected (dead) Li metal. Here, via operando NMR measurements, the authors quantify the Li metal in the SEI and dead regions using various inorganic solid-state electrolytes. The performance of all-solid-state lithium metal batteries (SSLMBs) is affected by the presence of electrochemically inactive (i.e., electronically and/or ionically disconnected) lithium metal and solid electrolyte interphase (SEI), which are jointly termed inactive lithium. However, the differentiation and quantification of inactive lithium during cycling are challenging, and their lack limits the fundamental understanding of SSLMBs failure mechanisms. To shed some light on these crucial aspects, here, we propose operando nuclear magnetic resonullce (NMR) spectroscopy measurements for real-time quantification and evolution-tracking of inactive lithium formed in SSLMBs. In particular, we examine four different sulfide-based solid electrolytes, namely, Li10GeP2S12, Li9.54Si1.74P1.44S11.7Cl0.3, Li6PS5Cl and Li7P3S11. We found that the chemistry of the solid electrolyte influences the activity of lithium. Furthermore, we demonstrate that electronically disconnected lithium metal is mainly found in the interior of solid electrolytes, and ionically disconnected lithium metal is found at the negative electrode surface. Moreover, by monitoring the Li NMR signal during cell calendar ageing, we prove the faster corrosion rate of mossy/dendritic lithium than flat/homogeneous lithium in SSLMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-35920-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35920-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001003645200035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LP; Guo, LF; Zhang, KQ; Xia, YG; Hao, JC; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Luping; Guo, Longfei; Zhang, Kaiqiang; Xia, Yuguo; Hao, Jingcheng; Wang, Xu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of Tough Thermoplastic Elastomers by Leveraging Rigid-Flexible Supramolecular Segment Interplays", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supramolecular interactions facilitate the development of tough multifunctional thermoplastic elastomers. However, the fundamental principles that govern supramolecular toughening are barely understood, and the rational design to achieve the desired high toughness remains daunting. Herein, we report a simple and robust method for toughening thermoplastic elastomers by rationally tailoring hard-soft phase separation structures containing rigid and flexible supramolecular segments. The introduced functional segments with distinct structural rigidities provide mismatched supramolecular interactions to efficiently tune the energy dissipation and bear an external load. The optimal supramolecular elastomer containing aromatic amide and acylsemicarbazide moieties demonstrates a record toughness (1.2 GJ m(-3)), extraordinary crack tolerance (fracture energy 282.5 kJ m(-2)), an ultrahigh true stress at break (2.3 GPa), good elasticity, healing ability, recyclability, and impact resistance. The toughening mechanism is validated by testing various elastomers, confirming the potential for designing and developing super-tough supramolecular materials with promising applications in aerospace and electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2023, "Volume": 62, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202301762", "DOI Link": "http://dx.doi.org/10.1002/anie.202301762", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001003392800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Zhu, L; Zhou, GQ; Hao, TY; Qiu, CQ; Zhao, Z; Hu, Q; Larson, BW; Zhu, HM; Ma, ZF; Tang, Z; Feng, W; Zhang, YM; Russell, TP; Liu, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ming; Zhu, Lei; Zhou, Guanqing; Hao, Tianyu; Qiu, Chaoqun; Zhao, Zhe; Hu, Qin; Larson, Bryon W.; Zhu, Haiming; Ma, Zaifei; Tang, Zheng; Feng, Wei; Zhang, Yongming; Russell, Thomas P.; Liu, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-layered organic photovoltaics with double cascading charge transport pathways: 18% efficiencies", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The chemical structure of donors and acceptors limit the power conversion efficiencies achievable with active layers of binary donor-acceptor mixtures. Here, using quaternary blends, double cascading energy level alignment in bulk heterojunction organic photovoltaic active layers are realized, enabling efficient carrier splitting and transport. Numerous avenues to optimize light absorption, carrier transport, and charge-transfer state energy levels are opened by the chemical constitution of the components. Record-breaking PCEs of 18.07% are achieved where, by electronic structure and morphology optimization, simultaneous improvements of the open-circuit voltage, short-circuit current and fill factor occur. The donor and acceptor chemical structures afford control over electronic structure and charge-transfer state energy levels, enabling manipulation of hole-transfer rates, carrier transport, and non-radiative recombination losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 596, "Times Cited, All Databases": 633, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 309, "DOI": "10.1038/s41467-020-20580-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20580-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662810100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, SF; Otsuka, K; Murdey, R; Nakamura, T; Truong, MA; Yamada, T; Handa, T; Matsuda, K; Nakano, K; Sato, A; Marumoto, K; Tajima, K; Kanemitsu, Y; Wakamiya, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Shuaifeng; Otsuka, Kento; Murdey, Richard; Nakamura, Tomoya; Minh Anh Truong; Yamada, Takumi; Handa, Taketo; Matsuda, Kazuhiro; Nakano, Kyohei; Sato, Atsushi; Marumoto, Kazuhiro; Tajima, Keisuke; Kanemitsu, Yoshihiko; Wakamiya, Atsushi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimized carrier extraction at interfaces for 23.6% efficient tin-lead perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carrier extraction in mixed tin-lead perovskite solar cells is improved by modifying the top and bottom perovskite surfaces with ethylenediammonium diiodide and glycine hydrochloride, respectively. Trap densities in perovskite layers are reduced as a result of surface passivation effects and an increase in film crystallinity. In addition, the oriented aggregation of the ethylenediammonium and glycinium cations at the charge collection interfaces results in the formation of surface dipoles, which facilitate charge extraction. As a result, the treated mixed tin-lead perovskite solar cells showed improved performance, with a fill factor of 0.82 and a power conversion efficiency of up to 23.6%. The unencapsulated device also shows improved stability under AM1.5 G, retaining over 80% of the initial efficiency after 200 h continuous operation in an inert atmosphere. Our strategy is also successfully applied to centimeter-scale devices, with efficiencies of up to 21.0%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2022, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2096, "End Page": 2107, "Article Number": null, "DOI": "10.1039/d2ee00288d", "DOI Link": "http://dx.doi.org/10.1039/d2ee00288d", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781499400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XJ; Huang, RJ; Zhong, C; Xie, GH; Ning, WM; Huang, ML; Ni, F; Dias, FB; Yang, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xujun; Huang, Rongjuan; Zhong, Cheng; Xie, Guohua; Ning, Weimin; Huang, Manli; Ni, Fan; Dias, Fernulldo B.; Yang, Chuluo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving 21% External Quantum Efficiency for Nondoped Solution-Processed Sky-Blue Thermally Activated Delayed Fluorescence OLEDs by Means of Multi-(Donor/Acceptor) Emitter with Through-Space/-Bond Charge Transfer", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although numerous thermally activated delayed fluorescence (TADF) organic light-emitting diodes (OLEDs) have been demonstrated, efficient blue or even sky-blue TADF-based nondoped solution-processed devices are still very rare. Herein, through-space charge transfer (TSCT) and through-bond charge transfer (TBCT) effects are skillfully incorporated, as well as the multi-(donor/acceptor) characteristic, into one molecule. The former allows this material to show small singlet-triplet energy splitting (Delta E-ST) and a high transition dipole moment. The latter, on the one hand, further lights up multichannel reverse intersystem crossing (RISC) to increase triplet exciton utilization via degenerating molecular orbitals. On the other hand, the nature of the molecular twisted structure effectively suppresses intermolecular packing to obtain high photoluminescence quantum yield (PLQY) in neat flims. Consequently, using this design strategy, T-CNDF-T-tCz containing three donor and three acceptor units, successfully realizes a small Delta E-ST (approximate to 0.03 eV) and a high PLQY (approximate to 0.76) at the same time; hence the nondoped solution-processed sky-blue TADF-OLED displays record-breaking efficiency among the solution process-based nondoped sky-blue OLEDs, with high brightness over 5200 cd m(-2) and external quantum efficiency up to 21.0%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902087, "DOI": "10.1002/advs.201902087", "DOI Link": "http://dx.doi.org/10.1002/advs.201902087", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511664400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, SQ; Ren, XH; Lin, HW; Song, H; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Shunqin; Ren, Xiaohui; Lin, Huiwen; Song, Hui; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic photothermal catalysis for solar-to-fuel conversion: current status and prospects", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-to-fuel conversion through photocatalytic processes is regarded as promising technology with the potential to reduce reliance on dwindling reserves of fossil fuels and to support the sustainable development of our society. However, conventional semiconductor-based photocatalytic systems suffer from unsatisfactory reaction efficiencies due to limited light harvesting abilities. Recent pioneering work from several groups, including ours, has demonstrated that visible and infrared light can be utilized by plasmonic catalysts not only to induce local heating but also to generate energetic hot carriers for initiating surface catalytic reactions and/or modulating the reaction pathways, resulting in synergistically promoted solar-to-fuel conversion efficiencies. In this perspective, we focus primarily on plasmon-mediated catalysis for thermodynamically uphill reactions converting CO2 and/or H2O into value-added products. We first introduce two types of mechanism and their applications by which reactions on plasmonic nullostructures can be initiated: either by photo-induced hot carriers (plasmonic photocatalysis) or by light-excited phonons (photothermal catalysis). Then, we emphasize examples where the hot carriers and phonon modes act in concert to contribute to the reaction (plasmonic photothermal catalysis), with special attention given to the design concepts and reaction mechanisms of the catalysts. We discuss challenges and future opportunities relating to plasmonic photothermal processes, aiming to promote an understanding of underlying mechanisms and provide guidelines for the rational design and construction of plasmonic catalysts for highly efficient solar-to-fuel conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2021, "Volume": 12, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5701, "End Page": 5719, "Article Number": null, "DOI": "10.1039/d1sc00064k", "DOI Link": "http://dx.doi.org/10.1039/d1sc00064k", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631619400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, GL; Sanjay, ST; Zhou, W; Brekken, RA; Kirken, RA; Li, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Guanglei; Sanjay, Sharma T.; Zhou, Wan; Brekken, Rolf A.; Kirken, Robert A.; Li, XiuJun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploration of nulloparticle-Mediated Photothermal Effect of TMB-H2O2 Colorimetric System and Its Application in a Visual Quantitative Photothermal Immunoassay", "Source Title": "ANALYTICAL CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of new physical and chemical properties of materials and their innovative application in different fields are of great importance to advance analytical chemistry, material science, and other important fields. Herein, we, for the first time, discovered the photothermal effect of an iron oxide nulloparticles (NPs) mediated TMB (3,3',5,5'-tetramethylbenzidine)-H2O2 colorimetric system, and applied it toward the development of a new NP-mediated photothermal immunoassay platform for visual quantitative biomolecule detection using a thermometer as the signal reader. Using a sandwich-type proof-of-concept immunoassay, we found that the charge transfer complex of the iron oxide NPs-mediated one-electron oxidation product of TMB (oxidized TMB) exhibited not only color changes, but also a strong near-infrared (NIR) laser-driven photothermal effect. Hence, oxidized TMB was explored as a new sensitive photothermal probe to convert the immunoassay signal into heat through the near-infrared laser-driven photothermal effect, enabling simple photothermal immunoassay using a thermometer. Based on the new iron oxide NPs mediated TMB-H2O2 photothermal immunoassay platform, prostate-specific antigen (PSA) as a model biomarker can be detected at a concentration as low as 1.0 ng-mL(-1) in normal human serum. The discovered photothermal effect of the colorimetric system and the developed new photothermal immunoassay platform open up a new horizon for affordable detection of disease biomarkers and have great potential for other important material and biomedical applications of interest.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2018, "Volume": 90, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5930, "End Page": 5937, "Article Number": null, "DOI": "10.1021/acs.analchem.8b00842", "DOI Link": "http://dx.doi.org/10.1021/acs.analchem.8b00842", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431464400057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hugar, KM; Kostalik, HA; Coates, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hugar, Kristina M.; Kostalik, Henry A.; Coates, Geoffrey W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure-Stability Relationships", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly base-stable cationic moieties are a critical component of anion exchange membranes (AEMs) in alkaline fuel cells (AFCs); however, the commonly employed organic cations have limited alkaline stability. To address this problem, we synthesized and characterized the stability of a series of imidazolium cations in 1, 2, or 5 M KOH/CD3OH at 80 degrees C, systematically evaluating the impact of substitution on chemical stability. The substituent identity at each position of the imidazolium ring has a dramatic effect on the overall cation stability. We report imidazolium cations that have the highest alkaline stabilities reported to date, >99% cation remaining after 30 days in 5 M KOH/CD3OH at 80 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2015, "Volume": 137, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8730, "End Page": 8737, "Article Number": null, "DOI": "10.1021/jacs.5b02879", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b02879", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358186700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, YN; Tang, JS; Li, XY; Liang, XP; Liu, ZW; Li, YJ; Xi, Y; Yao, P; Hao, ZQ; Gao, B; Qian, H; Wu, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yanull; Tang, Jianshi; Li, Xinyi; Liang, Xiangpeng; Liu, Zhengwu; Li, Yijun; Xi, Yue; Yao, Peng; Hao, Zhenqi; Gao, Bin; Qian, He; Wu, Huaqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A memristor-based analogue reservoir computing system for real-time and power-efficient signal processing", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reservoir computing offers a powerful neuromorphic computing architecture for spatiotemporal signal processing. To boost the power efficiency of the hardware implementations of reservoir computing systems, analogue devices and components-including spintronic oscillators, photonic modules, nullowire networks and memristors-have been used to partially replace the elements of fully digital systems. However, the development of fully analogue reservoir computing systems remains limited. Here we report a fully analogue reservoir computing system that uses dynamic memristors for the reservoir layer and non-volatile memristors for the readout layer. The system can efficiently process spatiotemporal signals in real time with three orders of magnitude lower power consumption than digital hardware. We illustrate the capabilities of the system using temporal arrhythmia detection and spatiotemporal dynamic gesture recognition tasks, achieving accuracies of 96.6% and 97.9%, respectively. Our memristor-based fully analogue reservoir computing system could be of use in edge computing applications that require extremely low power and hardware cost. Dynamic and non-volatile memristors can be used to create hardware-based reservoir and readout layers in artificial neural networks, providing a fully analogue signal processing chain for efficient data classification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 672, "End Page": 681, "Article Number": null, "DOI": "10.1038/s41928-022-00838-3", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00838-3", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000859735000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, YL; Pham, T; Li, PF; Wang, T; Chen, Y; Chen, KJ; Forrest, KA; Space, B; Cheng, P; Zaworotko, MJ; Zhang, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Yun-Lei; Pham, Tony; Li, Pengfei; Wang, Ting; Chen, Yao; Chen, Kai-Jie; Forrest, Katherine A.; Space, Brian; Cheng, Peng; Zaworotko, Michael J.; Zhang, Zhenjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust Ultramicroporous Metal-Organic Frameworks with Benchmark Affinity for Acetylene", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly selective separation and/or purification of acetylene from various gas mixtures is a relevant and difficult challenge that currently requires costly and energy-intensive chemisorption processes. Two ultramicroporous metal-organic framework physisorbents, NKMOF-1-M (M=Cu or Ni), offer high hydrolytic stability and benchmark selectivity towards acetylene versus several gases at ambient temperature. The performance of NKMOF-1-M is attributed to their exceptional acetylene binding affinity as revealed by modelling and several experimental studies: insitu single-crystal X-ray diffraction, FTIR, and gas mixture breakthrough tests. NKMOF-1-M exhibit better low-pressure uptake than existing physisorbents and possesses the highest selectivities yet reported for C2H2/CO2 and C2H2/CH4. The performance of NKMOF-1-M is not driven by the same mechanism as current benchmark physisorbents that rely on pore walls lined by inorganic anions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2018, "Volume": 57, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10971, "End Page": 10975, "Article Number": null, "DOI": "10.1002/anie.201806732", "DOI Link": "http://dx.doi.org/10.1002/anie.201806732", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442863700030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miao, JW; Xiao, FX; Yang, HB; Khoo, SY; Chen, JZ; Fan, ZX; Hsu, YY; Chen, HM; Zhang, H; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miao, Jianwei; Xiao, Fang-Xing; Yang, Hong Bin; Khoo, Si Yun; Chen, Jiazang; Fan, Zhanxi; Hsu, Ying-Ya; Chen, Hao Ming; Zhang, Hua; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Ni-Mo-S nullosheets on carbon fiber cloth: A flexible electrode for efficient hydrogen generation in neutral electrolyte", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A unique functional electrode made of hierarchal Ni-Mo-S nullosheets with abundant exposed edges anchored on conductive and flexible carbon fiber cloth, referred to as Ni-Mo-S/C, has been developed through a facile biomolecule-assisted hydrothermal method. The incorporation of Ni atoms in Mo-S plays a crucial role in tuning its intrinsic catalytic property by creating substantial defect sites as well as modifying the morphology of Ni-Mo-S network at atomic scale, resulting in an impressive enhancement in the catalytic activity. The Ni-Mo-S/C electrode exhibits a large cathodic current and a low onset potential for hydrogen evolution reaction in neutral electrolyte (pH similar to 7), for example, current density of 10 mA/cm(2) at a very small overpotential of 200 mV. Furthermore, the Ni-Mo-S/C electrode has excellent electrocatalytic stability over an extended period, much better than those of MoS2/C and Pt plate electrodes. Scanning and transmission electron microscopy, Raman spectroscopy, x-ray diffraction, x-ray photoelectron spectroscopy, and x-ray absorption spectroscopy were used to understand the formation process and electrocatalytic properties of Ni-Mo-S/C. The intuitive comparison test was designed to reveal the superior gas-evolving profile of Ni-Mo-S/C over that of MoS2/C, and a laboratory-cale hydrogen generator was further assembled to demonstrate its potential application in practical appliances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 437, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 1, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500259", "DOI": "10.1126/sciadv.1500259", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500259", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216596000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Wang, M; Wang, JW; Yang, L; Ren, XY; Song, G; Chen, SS; Yuan, YH; Liu, RQ; Pan, L; Li, Z; Leow, WR; Luo, YF; Ji, SB; Cui, ZQ; He, K; Zhang, FL; Lv, FT; Tian, YY; Cai, KY; Yang, BW; Niu, JY; Zou, HC; Liu, SR; Xu, GL; Fan, X; Hu, BH; Loh, XJ; Wang, LH; Chen, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ting; Wang, Ming; Wang, Jianwu; Yang, Le; Ren, Xueyang; Song, Gang; Chen, Shisheng; Yuan, Yuehui; Liu, Ruiqing; Pan, Liang; Li, Zheng; Leow, Wan Ru; Luo, Yifei; Ji, Shaobo; Cui, Zequn; He, Ke; Zhang, Feilong; Lv, Fengting; Tian, Yuanyuan; Cai, Kaiyu; Yang, Bowen; Niu, Jingyi; Zou, Haochen; Liu, Songrui; Xu, Guoliang; Fan, Xing; Hu, Benhui; Loh, Xian Jun; Wang, Lianhui; Chen, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A chemically mediated artificial neuron", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Brain-machine interfaces typically rely on electrophysiological signals to interpret and transmit neurological information. In biological systems, however, neurotransmitters are chemical-based interneuron messengers. This mismatch can potentially lead to incorrect interpretation of the transmitted neuron information. Here we report a chemically mediated artificial neuron that can receive and release the neurotransmitter dopamine. The artificial neuron detects dopamine using a carbon-based electrochemical sensor and then processes the sensory signals using a memristor with synaptic plasticity, before stimulating dopamine release through a heat-responsive hydrogel. The system responds to dopamine exocytosis from rat pheochromocytoma cells and also releases dopamine to activate pheochromocytoma cells, forming a chemical communication loop similar to interneurons. To illustrate the potential of this approach, we show that the artificial neuron can trigger the controllable movement of a mouse leg and robotic hand. An artificial neuron that detects dopamine using a carbon-based electrochemical sensor and then processes the sensory signals using a memristor with synaptic plasticity, before stimulating dopamine release via a heat-responsive hydrogel, can be used to trigger the controllable movement of a mouse leg and robotic hand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 586, "End Page": 595, "Article Number": null, "DOI": "10.1038/s41928-022-00803-0", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00803-0", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837541300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YG; Bai, XH; Yuan, DC; Yu, CY; San, XY; Guo, YN; Zhang, LQ; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yaguang; Bai, Xianhua; Yuan, Dachao; Yu, Chenyang; San, Xingyuan; Guo, Yunna; Zhang, Liqiang; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu-based high-entropy two-dimensional oxide as stable and active photothermal catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu-based nullocatalysts are the cornerstone of various industrial catalytic processes. Synergistically strengthening the catalytic stability and activity of Cu-based nullocatalysts is an ongoing challenge. Herein, the high-entropy principle is applied to modify the structure of Cu-based nullocatalysts, and a PVP templated method is invented for generally synthesizing six-eleven dissimilar elements as high-entropy two-dimensional (2D) materials. Taking 2D Cu2Zn1Al0.5Ce5Zr0.5Ox as an example, the high-entropy structure not only enhances the sintering resistance from 400 degrees C to 800 degrees C but also improves its CO2 hydrogenation activity to a pure CO production rate of 417.2 mmol g(-1) h(-1) at 500 degrees C, 4 times higher than that of reported advanced catalysts. When 2D Cu2Zn1Al0.5Ce5Zr0.5Ox are applied to the photothermal CO2 hydrogenation, it exhibits a record photochemical energy conversion efficiency of 36.2%, with a CO generation rate of 248.5 mmol g(-1) h(-1) and 571 L of CO yield under ambient sunlight irradiation. The high-entropy 2D materials provide a new route to simultaneously achieve catalytic stability and activity, greatly expanding the application boundaries of photothermal catalysis. Synergistically enhancing catalytic stability and activity of Cu-based nullocatalysts is an ongoing challenge. Here the authors report Cu-based high-entropy two-dimensional oxide as stable and active catalyst for photothermal CO2 hydrogenation under ambient sunlight irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3171, "DOI": "10.1038/s41467-023-38889-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38889-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002233800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ikhlas, M; Tomita, T; Koretsune, T; Suzuki, MT; Nishio-Hamane, D; Arita, R; Otani, Y; Nakatsuji, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ikhlas, Muhammad; Tomita, Takahiro; Koretsune, Takashi; Suzuki, Michi-To; Nishio-Hamane, Daisuke; Arita, Ryotaro; Otani, Yoshichika; Nakatsuji, Satoru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large anomalous Nernst effect at room temperature in a chiral antiferromagnet", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A temperature gradient in a ferromagnetic conductor can generate a transverse voltage drop perpendicular to both the magnetization and heat current. This anomalous Nernst effect has been considered to be proportional to the magnetization(1- 7), and thus observed only in ferromagnets. Theoretically, however, the anomalous Nernst effect provides a measure of the Berry curvature at the Fermi energy(8,9), and so may be seen in magnets with no net magnetization. Here, we report the observation of a large anomalous Nernst effect in the chiral antiferromagnet Mn3Sn (ref. 10). Despite a very small magnetization similar to 0.002 mu(B) per Mn, the transverse Seebeck coeffcient at zero magnetic field is similar to 0.35 mu VK-1 at room temperature and reaches similar to 0.6 mu VK-1 at 200 K, which is comparable to the maximum value known for a ferromagnetic metal. Our first-principles calculations reveal that this arises from a significantly enhanced Berry curvature associated with Weyl points near the Fermi energy(11). As this effect is geometrically convenient for thermoelectric power geceration-it enables a lateral configuration of modules to cover a heat source6-these observations suggest that a new class of thermoelectric materials could be developed that exploit topological magnets to fabricate effcient, densely integrated thermopiles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 13, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1085, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS4181", "DOI Link": "http://dx.doi.org/10.1038/NPHYS4181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414250500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nothling, MD; Fu, Q; Reyhani, A; Allison-Logan, S; Jung, K; Zhu, J; Kamigaito, M; Boyer, C; Qiao, GG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nothling, Mitchell D.; Fu, Qiang; Reyhani, Amin; Allison-Logan, Stephanie; Jung, Kenward; Zhu, Jian; Kamigaito, Masami; Boyer, Cyrille; Qiao, Greg G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Progress and Perspectives Beyond Traditional RAFT Polymerization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of advanced materials based on well-defined polymeric architectures is proving to be a highly prosperous research direction across both industry and academia. Controlled radical polymerization techniques are receiving unprecedented attention, with reversible-deactivation chain growth procedures now routinely leveraged to prepare exquisitely precise polymer products. Reversible addition-fragmentation chain transfer (RAFT) polymerization is a powerful protocol within this domain, where the unique chemistry of thiocarbonylthio (TCT) compounds can be harnessed to control radical chain growth of vinyl polymers. With the intense recent focus on RAFT, new strategies for initiation and external control have emerged that are paving the way for preparing well-defined polymers for demanding applications. In this work, the cutting-edge innovations in RAFT that are opening up this technique to a broader suite of materials researchers are explored. Emerging strategies for activating TCTs are surveyed, which are providing access into traditionally challenging environments for reversible-deactivation radical polymerization. The latest advances and future perspectives in applying RAFT-derived polymers are also shared, with the goal to convey the rich potential of RAFT for an ever-expanding range of high-performance applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 7, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001656, "DOI": "10.1002/advs.202001656", "DOI Link": "http://dx.doi.org/10.1002/advs.202001656", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000562401300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, B; Shin, JH; Ok, J; Park, S; Jung, W; Jeong, C; Choy, S; Jo, YJ; Kim, TI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Byeonghak; Shin, Joo Hwan; Ok, Jehyung; Park, Subin; Jung, Woojin; Jeong, Chanho; Choy, Seunghwan; Jo, Young Jin; Kim, Tae-il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cuticular pad-inspired selective frequency damper for nearly dynamic noise-free bioelectronics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioelectronics needs to continuously monitor mechanical and electrophysiological signals for patients. However, the signals always include artifacts by patients' unexpected movement (such as walking and respiration under approximately 30 hertz). The current method to remove them is a signal process that uses a bandpass filter, which may cause signal loss. We present an unconventional bandpass filter material-viscoelastic gelatin-chitosan hydrogel damper, inspired by the viscoelastic cuticular pad in a spider-to remove dynamic mechanical noise artifacts selectively. The hydrogel exhibits frequency-dependent phase transition that results in a rubbery state that damps low-frequency noise and a glassy state that transmits the desired high-frequency signals. It serves as an adaptable passfilter that enables the acquisition of high-quality signals from patients while minimizing signal process for advanced bioelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2022, "Volume": 376, "Issue": 6593, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 624, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj9912", "DOI Link": "http://dx.doi.org/10.1126/science.abj9912", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796932700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, J; Ji, XY; Zhang, XC; Feng, C; Tang, ZM; Kong, N; Xie, A; Wang, JQ; Sui, XB; Deng, L; Liu, YNA; Kim, JS; Cao, YH; Tao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Jiang; Ji, Xiaoyuan; Zhang, Xingcai; Feng, Chan; Tang, Zhongmin; Kong, Na; Xie, Angel; Wang, Junqing; Sui, Xinbing; Deng, Liu; Liu, Younian; Kim, Jong Seung; Cao, Yihai; Tao, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ sprayed NIR-responsive, analgesic black phosphorus-based gel for diabetic ulcer treatment", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The treatment of diabetic ulcer (DU) remains a major clinical challenge due to the complex wound-healing milieu that features chronic wounds, impaired angiogenesis, persistent pain, bacterial infection, and exacerbated inflammation. A strategy that effectively targets all these issues has proven elusive. Herein, we use a smart black phos-phorus (BP)-based gel with the characteristics of rapid formation and near-infrared light (NIR) responsiveness to address these problems. The in situ sprayed BP-based gel could act as 1) a temporary, biomimetic skin to temporarily shield the tissue from the external environment and accelerate chronic wound healing by promoting the proliferation of endothelial cells, vascularization, and angiogenesis and 2) a drug reservoir to store therapeutic BP and pain-relieving lidocaine hydrochloride (Lid). Within several minutes of NIR laser irradiation, the BP-based gel generates local heat to accelerate micro circulatory blood flow, mediate the release of loaded Lid for on demand pain relief, eliminate bacteria, and reduce inflammation. Therefore, our study not only introduces a concept of in situ sprayed, NIR-responsive pain relief gel targeting the challenging wound-healing milieu in diabetes but also provides a proof-of-concept application of BP-based materials in DU treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2020, "Volume": 117, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 28667, "End Page": 28677, "Article Number": null, "DOI": "10.1073/pnas.2016268117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2016268117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595339600024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Terlouw, T; Bauer, C; McKenna, R; Mazzotti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Terlouw, Tom; Bauer, Christian; McKenna, Russell; Mazzotti, Marco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale hydrogen production via water electrolysis: a techno-economic and environmental assessment", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-carbon (green) hydrogen can be generated via water electrolysis using photovoltaic, wind, hydropower, or decarbonized grid electricity. This work quantifies current and future costs as well as environmental burdens of large-scale hydrogen production systems on geographical islands, which exhibit high renewable energy potentials and could act as hydrogen export hubs. Different hydrogen production configurations are examined, considering a daily hydrogen production rate of 10 tonnes, on hydrogen production costs, life cycle greenhouse gas emissions, material utilization, and land transformation. The results demonstrate that electrolytic hydrogen production costs of 3.7 Euro per kg H-2 are within reach today and that a reduction to 2 Euro per kg H-2 in year 2040 is likely, hence approaching cost parity with hydrogen from natural gas reforming even when applying historical natural gas prices. The recent surge of natural gas prices shows that cost parity between green and grey hydrogen can already be achieved today. Producing hydrogen via water electrolysis with low costs and low GHG emissions is only possible at very specific locations nowadays. Hybrid configurations using different electricity supply options demonstrate the best economic performance in combination with low environmental burdens. Autonomous hydrogen production systems are especially effective to produce low-carbon hydrogen, although the production of larger sized system components can exhibit significant environmental burdens and investments. Some materials (especially iridium) and the availability of land can be limiting factors when scaling up green hydrogen production with polymer electrolyte membrane (PEM) electrolyzers. This implies that decision-makers should consider aspects beyond costs and GHG emissions when designing large-scale hydrogen production systems to avoid risks coming along with the supply of, for example, scarce materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2022, "Volume": 15, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3583, "End Page": 3602, "Article Number": null, "DOI": "10.1039/d2ee01023b", "DOI Link": "http://dx.doi.org/10.1039/d2ee01023b", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000838177400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, DD; Qin, Y; Guo, H; Wen, P; Lin, H; Voshage, M; Schleifenbaum, JH; Cheng, Y; Zheng, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Dandan; Qin, Yu; Guo, Hui; Wen, Peng; Lin, Hong; Voshage, Maximilian; Schleifenbaum, Johannes Henrich; Cheng, Yan; Zheng, Yufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additively manufactured pure zinc porous scaffolds for critical-sized bone defects of rabbit femur", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing has received attention for the fabrication of medical implants that have customized and complicated structures. Biodegradable Zn metals are revolutionary materials for orthopedic implants. In this study, pure Zn porous scaffolds with diamond structures were fabricated using customized laser powder bed fusion (L-PBF) technology. First, the mechanical properties, corrosion behavior, and biocompatibility of the pure Zn porous scaffolds were characterized in vitro. The scaffolds were then implanted into the rabbit femur criticalsize bone defect model for 24 weeks. The results showed that the pure Zn porous scaffolds had compressive strength and rigidity comparable to those of cancellous bone, as well as relatively suitable degradation rates for bone regeneration. A benign host response was observed using hematoxylin and eosin (HE) staining of the heart, liver, spleen, lungs, and kidneys. Moreover, the pure Zn porous scaffold showed good biocompatibility and osteogenic promotion ability in vivo. This study showed that pure Zn porous scaffolds with customized structures fabricated using L-PBF represent a promising biodegradable solution for treating large bone defects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12, "End Page": 23, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.03.010", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.03.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788642400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eren, B; Zherebetskyy, D; Patera, LL; Wu, CH; Bluhm, H; Africh, C; Wang, LW; Somorjai, GA; Salmeron, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eren, Baran; Zherebetskyy, Danylo; Patera, Laerte L.; Wu, Cheng Hao; Bluhm, Hendrik; Africh, Cristina; Wang, Lin-Wang; Somorjai, Gabor A.; Salmeron, Miquel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activation of Cu(111) surface by decomposition into nulloclusters driven by CO adsorption", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The (111) surface of copper (Cu), its most compact and lowest energy surface, became unstable when exposed to carbon monoxide (CO) gas. Scanning tunneling microscopy revealed that at room temperature in the pressure range 0.1 to 100 Torr, the surface decomposed into clusters decorated by CO molecules attached to edge atoms. Between 0.2 and a few Torr CO, the clusters became mobile in the scale of minutes. Density functional theory showed that the energy gain from CO binding to low-coordinated Cu atoms and the weakening of binding of Cu to neighboring atoms help drive this process. Particularly for softer metals, the optimal balance of these two effects occurs near reaction conditions. Cluster formation activated the surface for water dissociation, an important step in the water-gas shift reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2016, "Volume": 351, "Issue": 6272, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 475, "End Page": 478, "Article Number": null, "DOI": "10.1126/science.aad8868", "DOI Link": "http://dx.doi.org/10.1126/science.aad8868", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368858200029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CX; Qi, QL; Mei, YJ; Hu, J; Sun, MZ; Zhang, YJ; Huang, BL; Zhang, LB; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chengxu; Qi, Qianglong; Mei, Yunjie; Hu, Jue; Sun, Minzi; Zhang, Yingjie; Huang, Bolong; Zhang, Libo; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationally Reconstructed Metal-Organic Frameworks as Robust Oxygen Evolution Electrocatalysts", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reconstructing metal-organic framework (MOFs) toward a designed framework structure provides breakthrough opportunities to achieve unprecedented oxygen evolution reaction (OER) electrocatalytic performance, but has rarely, if ever, been proposed and investigated yet. Here, the first successful fabrication of a robust OER electrocatalyst by precision reconstruction of an MOF structure is reported, viz., from MOF-74-Fe to MIL-53(Fe)-2OH with different coordination environments at the active sites. Due to the radically reduced e(g)-t(2g) crystal-field splitting in Fe-3d and the much suppressed electron-hopping barriers through the synergistic effects of the O species the efficient OER of in MIL-53(Fe)-2OH is guaranteed. Benefiting from this desired electronic structure, the designed MIL-53(Fe)-2OH catalyst exhibits high intrinsic OER activity, including a low overpotential of 215 mV at 10 mA cm(-2), low Tafel slope of 45.4 mV dec(-1) and high turnover frequency (TOF) of 1.44 s(-1) at 300 mV overpotential, over 80 times that of the commercial IrO2 catalyst (0.0177 s(-1)).Consistent with the density functional theory (DFT) calculations, the real-time kinetic simulation reveals that the conversion from O* to OOH* is the rate-determining step on the active sites of MIL-53(Fe)-2OH.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 35, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202208904", "DOI Link": "http://dx.doi.org/10.1002/adma.202208904", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000904748800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, S; Zhao, ZJ; Mu, RT; Chang, X; Luo, J; Purdy, SC; Kropf, AJ; Sun, GD; Pei, CL; Miller, JT; Zhou, XH; Vovk, E; Yang, Y; Gong, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Sai; Zhao, Zhi-Jian; Mu, Rentao; Chang, Xin; Luo, Jun; Purdy, Stephen C.; Kropf, A. Jeremy; Sun, Guodong; Pei, Chunlei; Miller, Jeffrey T.; Zhou, Xiaohong; Vovk, Evgeny; Yang, Yong; Gong, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Propane dehydrogenation (PDH) is a commercial propylene production technology that has received much attention, but high reaction temperatures result in a decrease of propylene selectivity and catalyst stability. This paper describes a single-site [PtZn4] catalyst by assembling atomically ordered intermetallic alloy (IMA) as a selective and ultrastable PDH catalyst. The catalyst enables more than 95% of propylene selectivity from 520 degrees C to 620 degrees C. No obvious deactivation is observed within the 160-h test, superior to PtSn/Al2O3 and state-of-the-art Pt-based catalysts. Based on in situ X-ray absorption fine structure, X-ray photoelectron spectroscopy measurements, and density functional theory calculations, we reveal that the surface [PtZn4] ensembles in PtZn IMAs serve as the key active site structures, wherein the geometry-isolated and electron-rich Pt-1 site in [PtZn4] ensembles readily promotes the first and second C-H cleavage of propane but inhibits further dehydrogenation of surface-bounded propylene. This significantly improves the selectivity and stability by prohibiting coke side reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2021, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 387, "End Page": 405, "Article Number": null, "DOI": "10.1016/j.chempr.2020.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.10.008", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628784800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morandeau, A; Thiéry, M; Dangla, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morandeau, A.; Thiery, M.; Dangla, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation of the carbonation mechanism of CH and C-S-H in terms of kinetics, microstructure changes and moisture properties", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The purpose of this article is to investigate the carbonation mechanism of CH and C-S-H within type-I cement-based materials in terms of kinetics, microstructure changes and water released from hydrates during carbonation. Carbonation tests were performed under accelerated conditions (10% CO2, 25 degrees C and 65 +/- 5% RH). Carbonation profiles were assessed by destructive and non-destructive methods such as phenolphthalein spray test, thermogravimetric analysis, and mercury intrusion porosimetry (destructive), as well as gamma-ray attenuation (non-destructive). Carbonation penetration was carried out at different ages from 1 to 16 weeks of CO2 exposure on cement pastes of 0.45 and 0.6 w/c, as well as on mortar specimens (w/c = 0.50 and s/c = 2). Combining experimental results allowed us to improve the understanding of C-S-H and CH carbonation mechanism. The variation of molar volume of C-S-H during carbonation was identified and a quantification of the amount of water released during CH and C-S-H carbonation was performed. (C) 2013 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 761, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 56, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 153, "End Page": 170, "Article Number": null, "DOI": "10.1016/j.cemconres.2013.11.015", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2013.11.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331424500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, R; von Haugwitz, G; Pfaff, L; Mican, J; Badenhorst, CPS; Liu, WD; Weber, G; Austin, HP; Bednar, D; Damborsky, J; Bornscheuer, UT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Ren; von Haugwitz, Gerlis; Pfaff, Lara; Mican, Jan; Badenhorst, Christoffel P. S.; Liu, Weidong; Weber, Gert; Austin, Harry P.; Bednar, David; Damborsky, Jiri; Bornscheuer, Uwe T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism-Based Design of Efficient PET Hydrolases", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyethylene terephthalate (PET) is the most widespread synthetic polyester, having been utilized in textile fibers and packaging materials for beverages and food, contributing considerably to the global solid waste stream and environmental plastic pollution. While enzymatic PET recycling and upcycling have recently emerged as viable disposal methods for a circular plastic economy, only a handful of benchmark enzymes have been thoroughly described and subjected to protein engineering for improved properties over the last 16 years. By analyzing the specific material properties of PET and the reaction mechanisms in the context of interfacial biocatalysis, this Perspective identifies several limitations in current enzymatic PET degradation approaches. Unbalanced enzyme-substrate interactions, limited thermostability, and low catalytic efficiency at elevated reaction temperatures, and inhibition caused by oligomeric degradation intermediates still hamper industrial applications that require high catalytic efficiency. To overcome these limitations, successful protein engineering studies using innovative experimental and computational approaches have been published extensively in recent years in this thriving research field and are summarized and discussed in detail here. The acquired knowledge and experience will be applied in the near future to address plastic waste contributed by other mass-produced polymer types (e.g., polyamides and polyurethanes) that should also be properly disposed by biotechnological approaches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2022, "Volume": 12, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3382, "End Page": 3396, "Article Number": null, "DOI": "10.1021/acscatal.1c05856", "DOI Link": "http://dx.doi.org/10.1021/acscatal.1c05856", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778789200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SH; Sun, F; Du, XF; Zhang, XH; Huang, L; Ma, J; Dong, SM; Hilger, A; Manke, I; Li, LS; Xie, B; Li, JD; Hu, ZW; Komarek, AC; Lin, HJ; Kuo, CY; Chen, CT; Han, PX; Xu, GJ; Cui, ZL; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shenghang; Sun, Fu; Du, Xiaofan; Zhang, Xiaohu; Huang, Lang; Ma, Jun; Dong, Shanmu; Hilger, Andre; Manke, Ingo; Li, Longshan; Xie, Bin; Li, Jiedong; Hu, Zhiwei; Komarek, Alexander C.; Lin, Hong-Ji; Kuo, Chang-Yang; Chen, Chien-Te; Han, Pengxian; Xu, Gaojie; Cui, Zili; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ-polymerized lithium salt as a polymer electrolyte for high-safety lithium metal batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer electrolytes offer advantages of leak-proofing, excellent flexibility, and high compatibility with lithium metal, enabling the highly safe operation of lithium metal batteries (LMBs). However, most current polymer electrolytes do not meet the requirements for the practical applications of LMBs. Herein, to resolve this issue, employing thermal-induced in situ polymerization of lithium perfluoropinacolatoaluminate (LiFPA), we present a novel interface-compatible and safe single-ion conductive 3D polymer electrolyte (3D-SIPE-LiFPA). It is demonstrated that 3D-SIPE-LiFPA with a unique polyanion structure promoted the formation of a protective electrode/electrolyte interface and inhibited the dissolution-migration-deposition of transition metals (TMs). 3D-SIPE-LiFPA endowed LiNi0.8Co0.1Mn0.1O2 (NCM811, 3.7 mA h cm(-2))/Li (50 mu m) LMBs with a long cycle life at both the coin-cell level (80.8% after 236 cycles) and pouch-cell level (437 W h kg(-1), 95.4% after 60 cycles, injected electrolyte 2 g A h(-1)). More importantly, pouch-type NCM811/Li LMBs using 3D-SIPE-LiFPA delivered significantly enhanced onset temperature for heat release (T-onset) and thermal runaway temperature (T-tr) by 34 degrees C and 72 degrees C, respectively. Our strategy of polymerizing lithium salt as a polymer electrolyte opens up a new frontier to simultaneously enhance the cycle life and safety of LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2023, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2591, "End Page": 2602, "Article Number": null, "DOI": "10.1039/d3ee00558e", "DOI Link": "http://dx.doi.org/10.1039/d3ee00558e", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984117700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, ZC; Xu, D; Lin, ZY; Wang, PQ; Cao, BC; Ren, HY; Song, F; Wan, CZ; Wang, LY; Zhou, JX; Zhao, X; Chen, J; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Zhuocheng; Xu, Dong; Lin, Zhaoyang; Wang, Peiqi; Cao, Bocheng; Ren, Huaying; Song, Frank; Wan, Chengzhang; Wang, Laiyuan; Zhou, Jingxuan; Zhao, Xun; Chen, Jun; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stretchable van der Waals thin films for adaptable and breathable electronic membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conformal integration of electronic systems with irregular, soft objects is essential for many emerging technologies. We report the design of van der Waals thin films consisting of staggered two-dimensional nullosheets with bond-free van der Waals interfaces. The films feature sliding and rotation degrees of freedom among the staggered nullosheets to ensure mechanical stretchability and malleability, as well as a percolating network of nullochannels to endow permeability and breathability. With an excellent mechanical match to soft biological tissues, the freestanding films can naturally adapt to local surface topographies and seamlessly merge with living organisms with highly conformal interfaces, rendering living organisms with electronic functions, including leaf-gate and skin-gate transistors. On-skin transistors allow high-fidelity monitoring and local amplification of skin potentials and electrophysiological signals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2022, "Volume": 375, "Issue": 6583, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 852, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abl8941", "DOI Link": "http://dx.doi.org/10.1126/science.abl8941", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764232800040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, F; Busch, MM; Lassalle-Kaiser, B; Hsu, CS; Petkucheva, E; Bensimon, M; Chen, HM; Corminboeuf, C; Hu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Fang; Busch, Michael M.; Lassalle-Kaiser, Benedikt; Hsu, Chia-Shuo; Petkucheva, Elitsa; Bensimon, Michael; Chen, Hao Ming; Corminboeuf, Clemence; Hu, Xile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Unconventional Iron Nickel Catalyst for the Oxygen Evolution Reaction", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction (OER) is a key process that enables the storage of renewable energies in the form of chemical fuels. Here, we describe a catalyst that exhibits turnover frequencies higher than state-of-the-art catalysts that operate in alkaline solutions, including the benchmark nickel iron oxide. This new catalyst is easily prepared from readily available and industrially relevant nickel foam, and it is stable for many hours. Operando X-ray absorption spectroscopic data reveal that the catalyst is made of nulloclusters of gamma-FeOOH covalently linked to gamma-NiOOH support. According to density functional theory (DFT) computations, this structure may allow a reaction path involving iron as the oxygen evolving center and a nearby terrace O site on the gamma-NiOOH support oxide as a hydrogen acceptor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 558, "End Page": 568, "Article Number": null, "DOI": "10.1021/acscentsci.9b00053", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462498900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Golovin, K; Kobaku, SPR; Lee, DH; DiLoreto, ET; Mabry, JM; Tuteja, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Golovin, Kevin; Kobaku, Sai P. R.; Lee, Duck Hyun; DiLoreto, Edward T.; Mabry, Joseph M.; Tuteja, Anish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing durable icephobic surfaces", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ice accretion has a negative impact on critical infrastructure, as well as a range of commercial and residential activities. Icephobic surfaces are defined by an ice adhesion strength tau(ice) < 100 kPa. However, the passive removal of ice requires much lower values of tau(ice), such as on airplane wings or power lines (tau(ice) < 20 kPa). Such low tau(ice) values are scarcely reported, and robust coatings that maintain these low values have not been reported previously. We show that, irrespective of material chemistry, by tailoring the cross-link density of different elastomeric coatings and by enabling interfacial slippage, it is possible to systematically design coatings with extremely low ice adhesion (tau(ice) < 0.2 kPa). These newfound mechanisms allow for the rational design of icephobic coatings with virtually any desired ice adhesion strength. By using these mechanisms, we fabricate extremely durable coatings that maintain tau(ice) < 10 kPa after severe mechanical abrasion, acid/base exposure, 100 icing/deicing cycles, thermal cycling, accelerated corrosion, and exposure to Michigan wintery conditions over several months.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 572, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501496", "DOI": "10.1126/sciadv.1501496", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379620200031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, W; Nyein, HYY; Shahpar, Z; Fahad, HM; Chen, K; Emaminejad, S; Gao, YJ; Tai, LC; Ota, H; Wu, E; Bullock, J; Zeng, YP; Lien, DH; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Wei; Nyein, Hnin Y. Y.; Shahpar, Ziba; Fahad, Hossain M.; Chen, Kevin; Emaminejad, Sam; Gao, Yuji; Tai, Li-Chia; Ota, Hiroki; Wu, Eric; Bullock, James; Zeng, Yuping; Lien, Der-Hsien; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable Microsensor Array for Multiplexed Heavy Metal Monitoring of Body Fluids", "Source Title": "ACS SENSORS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A flexible and wearable microsensor array is described for simultaneous multiplexed monitoring of heavy metals in human body fluids. Zn, Cd, Pb, Cu, and Hg ions are chosen as target analytes for detection via electrochemical square wave anodic stripping voltammetry (SWASV) on Au and Bi microelectrodes. The oxidation peaks of these metals are calibrated and compensated by incorporating a skin temperature sensor. High selectivity, repeatability, and flexibility of the sensor arrays are presented. Human sweat and urine samples are collected for heavy metal analysis, and measured results from the microsensors are validated through inductively coupled plasma mass spectrometry (ICP-MS). Real-time on-body evaluation of heavy metal (e.g., zinc and copper) levels in sweat of human subjects by cycling is performed to examine the change in concentrations with time. This platform is anticipated to provide insightful information about an individual's health state such as heavy metal exposure and aid the related clinical investigations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 1, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 866, "End Page": 874, "Article Number": null, "DOI": "10.1021/acssensors.6b00287", "DOI Link": "http://dx.doi.org/10.1021/acssensors.6b00287", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385464900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, XK; Wei, YJ; Yin, XB; Li, BW; Yang, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Xiaokun; Wei, Yujie; Yin, Xiaobo; Li, Baowen; Yang, Ronggui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloquium: Phononic thermal properties of two-dimensional materials", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Following the emergence of many novel two-dimensional (2D) materials beyond graphene, interest has grown in exploring implications for fundamental physics and practical applications ranging from electronics, photonics, and phononics to thermal management and energy storage. In this Colloquium, a summary and comparison are given of the phonon properties, such as phonon dispersion and relaxation time, of pristine 2D materials with single-layer graphene to understand the role of crystal structure and dimension on thermal conductivity. A comparison is made of the phonon properties, contrasting idealized 2D crystals, realistic 2D crystals, and 3D crystals, and synthesizing this to develop a physical picture of how the sample size of 2D materials affects their thermal conductivity. The effects of geometry such as the number of layers and the nulloribbon width, together with the presence of defects, mechanical strain, and substrate interactions on the thermal properties of 2D materials are discussed. Intercalation affects both the group velocities and phonon relaxation times of layered crystals and thus tunes the thermal conductivity along both the through-plane and basal-plane directions. This Colloquium concludes with a discussion of the challenges in theoretical and experimental studies of thermal transport in 2D materials. The rich and special phonon physics in 2D materials make them promising candidates for exploring novel phenomena such as topological phonon effects and applications such as phononic quantum devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 13", "Publication Year": 2018, "Volume": 90, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41002, "DOI": "10.1103/RevModPhys.90.041002", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.041002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450150200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, ZN; Ruan, JJ; Li, C; Zheng, CY; Wen, Z; Dai, JY; Li, AD; Wu, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Zhongnull; Ruan, Jieji; Li, Chen; Zheng, Chunyan; Wen, Zheng; Dai, Jiyan; Li, Aidong; Wu, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant tunnelling electroresistance in metal/ferroelectric/semiconductor tunnel junctions by engineering the Schottky barrier", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, ferroelectric tunnel junctions have attracted much attention due to their potential applications in non-destructive readout non-volatile memories. Using a semiconductor electrode has been proven effective to enhance the tunnelling electroresistance in ferroelectric tunnel junctions. Here we report a systematic investigation on electroresistance of Pt/BaTiO3/Nb:SrTiO3 metal/ferroelectric/semiconductor tunnel junctions by engineering the Schottky barrier on Nb:SrTiO3 surface via varying BaTiO3 thickness and Nb doping concentration. The optimum ON/OFF ratio as great as 6.0 x 10(6), comparable to that of commercial Flash memories, is achieved in a device with 0.1 wt% Nb concentration and a 4-unit-cell-thick BaTiO3 barrier. With this thinnest BaTiO3 barrier, which shows a negligible resistance to the tunnelling current but is still ferroelectric, the device is reduced to a polarization-modulated metal/semiconductor Schottky junction that exhibits a more efficient control on the tunnelling resistance to produce the giant electroresistance observed. These results may facilitate the design of high performance non-volatile resistive memories.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15217, "DOI": "10.1038/ncomms15217", "DOI Link": "http://dx.doi.org/10.1038/ncomms15217", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401509400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, Y; Zhu, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Ye; Zhu, Guangshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous Aromatic Frameworks as a Platform for Multifunctional Applications", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous aromatic frameworks (PAFs), which are well-known for their large surface areas, associated porosity, diverse structures, and superb stability, have recently attracted broad interest. Taking advantage of widely available building blocks and various coupling strategies, customized porous architectures can be prepared exclusively through covalent bonding to satisfy necessary requirements. In addition, PAFs are composed of phenyl-ring-derived fragments that are easily modified with desired functional groups with the help of established synthetic chemistry techniques. On the basis of material design and preparative chemistry, this review mainly focuses on recent advances in the structural and chemical characteristics of PAFs for potential utilizations, including molecule storage, gas separation, catalysis, and ion extraction. Additionally, a concise outlook on the rational construction of functional PAFs is discussed in terms of developing next-generation porous materials for broader applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 409, "End Page": 418, "Article Number": null, "DOI": "10.1021/acscentsci.9b00047", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00047", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462498900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, S; Yang, B; Gu, G; Joshi, PC; Ivanov, IN; Rouleau, CM; Aytug, T; Geohegan, DB; Xiao, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, Sanjib; Yang, Bin; Gu, Gong; Joshi, Pooran C.; Ivanov, Ilia N.; Rouleau, Christopher M.; Aytug, Tolga; Geohegan, David B.; Xiao, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance Flexible Perovskite Solar Cells by Using a Combination of Ultrasonic Spray-Coating and Low Thermal Budget Photonic Curing", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing the commercialization of high-performance and robust perovskite solar cells urgently requires the development of economically scalable processing techniques. Here we report a high-throughput ultrasonic spray-coating (USC) process capable of fabricating perovskite film-based solar cells on glass substrates with a power conversion efficiency (PCE) as high as 13%. Perovskite films with high uniformity, crystallinity, and surface coverage are obtained in a single step. Moreover, we report USC processing on TiO2/ITO-coated polyethylene terephthalate (PET) substrates to realize flexible perovskite solar cells with a PCE as high as 8.1% that are robust under mechanical stress. In this case, a photonic curing technique was used to achieve a highly conductive TiO2 layer on flexible PET substrates for the first time. The high device performance and reliability obtained by this combination of USC processing with optical curing appear very promising for roll-to-roll manufacturing of high-efficiency, flexible perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 680, "End Page": 686, "Article Number": null, "DOI": "10.1021/acsphotonics.5b00119", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.5b00119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356757900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zang, Y; Li, CZ; Chueh, CC; Williams, ST; Jiang, W; Wang, ZH; Yu, JS; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zang, Yue; Li, Chang-Zhi; Chueh, Chu-Chen; Williams, Spencer T.; Jiang, Wei; Wang, Zhao-Hui; Yu, Jun-Sheng; Jen, Alex K-Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated Molecular, Interfacial, and Device Engineering towards High-Performance Non-Fullerene Based Organic Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance non-fullerene OSCs with PCEs of up to ca. 6.0% are demonstrated based on PBDTT-F-TT polymer and a molecular di-PBI acceptor through comprehensive molecular, interfacial, and device engineering. Impressive PCEs can also be retained in devices with relatively thick BHJ layer and processed through non-halogenated solvents, indicating these high-performance non-fullerene OSCs are promising for large-area printing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2014, "Volume": 26, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5708, "End Page": "+", "Article Number": null, "DOI": "10.1002/adma.201401992", "DOI Link": "http://dx.doi.org/10.1002/adma.201401992", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340900800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, T; Xu, ZY; Wang, R; Dong, XY; Fu, Q; Liu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Tong; Xu, Zhiyuan; Wang, Rui; Dong, Xiyue; Fu, Qiang; Liu, Yongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal Growth Regulation of 2D/3D Perovskite Films for Solar Cells with Both High Efficiency and Stability", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing the electronic defects in perovskite films has become a substantial challenge to further boost the photovoltaic performance of perovskite solar cells. Here, 2D (NpMA)(2)PbI4 perovskite and 1-naphthalenemethylammonium iodide (NpMAI) are separately introduced into the PbI2 precursor solutions to regulate the crystal growth in a 2D/3D perovskite film using a two-step deposition method. The (NpMA)(2)PbI4 modulated perovskite film shows a significantly improved film quality with enlarged grain size from approximate to 500 nm to over 1000 nm, which greatly reduces the grain-boundary defects, improves the charge carrier lifetime, and hinders ionic diffusion. As a result, the best-performing device shows a high power conversion efficiency (PCE) of 24.37% for a small-area (0.10 cm(-2)) device and a superior PCE of 22.26% for a large-area (1.01 cm(-2)) device. Importantly, the unencapsulated device shows a dramatically improved operational stability with maintains over 98% of its initial efficiency after 1500 h by maximum power point (MPP) tracking under continuous light irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200705, "DOI": "10.1002/adma.202200705", "DOI Link": "http://dx.doi.org/10.1002/adma.202200705", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000769937600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roncali, J; Leriche, P; Blanchard, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roncali, Jean; Leriche, Philippe; Blanchard, Philippe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular Materials for Organic Photovoltaics: Small is Beautiful", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An overview of some recent developments of the chemistry of molecular donor materials for organic photovoltaics (OPV) is presented. Although molecular materials have been used for the fabrication of OPV cells from the very beginning of the field, the design of molecular donors specifically designed for OPV is a relatively recent research area. In the past few years, molecular donors have been used in both vacuum-deposited and solution-processed OPV cells and both fields have witnessed impressive progress with power conversion efficiencies crossing the symbolic limit of 10%. However, this progress has been achieved at the price of an increasing complexity of the chemistry of active materials and of the technology of device fabrication. This evolution probably inherent to the progress of research is difficult to reconcile with the necessity for OPV to demonstrate a decisive economic advantage over existing silicon technology. In this short review various classes of molecular donors are discussed with the aim of defining possible basic molecular structures that can combine structural simplicity, low molecular weight, synthetic accessibility, scalability and that can represent possible starting points for the development of simple and cost-effective OPV materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 541, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2014, "Volume": 26, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3821, "End Page": 3838, "Article Number": null, "DOI": "10.1002/adma.201305999", "DOI Link": "http://dx.doi.org/10.1002/adma.201305999", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337618600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, MZ; Wei, Z; Du, LJ; Wang, QQ; Tang, J; Yu, H; Wu, FF; Zhao, JJ; Xu, XZ; Han, B; Liu, KH; Gao, P; Polcar, T; Sun, ZP; Shi, DX; Yang, R; Zhang, GY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Mengzhou; Wei, Zheng; Du, Luojun; Wang, Qinqin; Tang, Jian; Yu, Hua; Wu, Fanfan; Zhao, Jiaojiao; Xu, Xiaozhi; Han, Bo; Liu, Kaihui; Gao, Peng; Polcar, Tomas; Sun, Zhipei; Shi, Dongxia; Yang, Rong; Zhang, Guangyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precise control of the interlayer twist angle in large scale MoS2 homostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Twist angle between adjacent layers of two-dimensional (2D) layered materials provides an exotic degree of freedom to enable various fascinating phenomena, which opens a research direction-twistronics. To realize the practical applications of twistronics, it is of the utmost importance to control the interlayer twist angle on large scales. In this work, we report the precise control of interlayer twist angle in centimeter-scale stacked multilayer MoS2 homostructures via the combination of wafer-scale highly-oriented monolayer MoS2 growth techniques and a water-assisted transfer method. We confirm that the twist angle can continuously change the indirect bandgap of centimeter-scale stacked multilayer MoS2 homostructures, which is indicated by the photoluminescence peak shift. Furthermore, we demonstrate that the stack structure can affect the electrical properties of MoS2 homostructures, where 30 degrees twist angle yields higher electron mobility. Our work provides a firm basis for the development of twistronics. Interlayer twist angle between vertically stacked 2D material layers can trigger exciting fundamental physics. Here, the authors report precise control of interlayer twist angle of stacked centimeter scale multilayer MoS2 homostructures that enables continuous change in their indirect bandgap, Moire phonons and electrical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2153, "DOI": "10.1038/s41467-020-16056-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16056-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531425700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XT; Ke, WJ; Traoré, B; Guo, PJ; Hadar, I; Kepenekian, M; Even, J; Katan, C; Stoumpos, CC; Schaller, RD; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaotong; Ke, Weijun; Traore, Boubacar; Guo, Peijun; Hadar, Ido; Kepenekian, Mikael; Even, Jacky; Katan, Claudine; Stoumpos, Constantinos C.; Schaller, Richard D.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Dion-Jacobson Hybrid Lead Iodide Perovskites with Aromatic Diammonium Cations", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) halide perovskites have extraordinary optoelectronic properties and structural tunability. Among them, the Dion-Jacobson phases with the inorganic layers stacking exactly on top of each other are less explored. Herein, we present the new series of 2D Dion-Jacobson halide perovskites, which adopt the general formula of A'A(n-1)Pb(n)I(3n+1) (A' = 4-(aminomethyl)pyridinium (4AMPY), A = methylammonium (MA), n = 1-4). By modifying the position of the CH2NH3+ group from 4AMPY to 3AMPY (3AMPY = 3-(aminomethyl)pyridinium), the stacking of the inorganic layers changes from exactly eclipsed to slightly offset. The perovskite octahedra tilts are also different between the two series, with the 3AMPY series exhibiting smaller bandgaps than the 4AMPY series. Compared to the aliphatic cation of the same size (AMP = (aminomethyl)piperidinium), the aromatic spacers increase the rigidity of the cation, reduce the interlayer spacing, and decrease the dielectric mismatch between inorganic layer and the organic spacer, showing the indirect but powerful influence of the organic cations on the structure and consequently on the optical properties of the perovskite materials. All A'A(n-1)Pb(n)I(3n+1) compounds exhibit strong photoluminescence (PL) at room temperature. Preliminary solar cell devices based on the n = 4 perovskites as absorbers of both series exhibit promising performances, with a champion power conversion efficiency (PCE) of 9.20% for (3AMPY)(MA)(3)Pb4I13-based devices, which is higher than the (4AMPY)(MA)(3)Pb4I13 and the corresponding aliphatic analogue (3AMP)(MA)(3)Pb4I13-based ones.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 14", "Publication Year": 2019, "Volume": 141, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12880, "End Page": 12890, "Article Number": null, "DOI": "10.1021/jacs.9b06398", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b06398", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481563500057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Hu, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chi; Hu, Xinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-Dimensional Single-Port Labyrinthine Acoustic Metamaterial: Perfect Absorption with Large Bandwidth and Tunability", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "materials. Here, we report on the design, fabrication, and experimental characterization of a three-dimensional single-port labyrinthine acoustic metamaterial. By using curled perforations with one end closed and with appropriate loss inside, the metamaterial can perfectly absorb airborne sounds in a low-frequency band. Both the position and the relative width of the band can be tuned flexibly. A trade-off is uncovered between the relative absorption bandwidth and thickness of the metamaterial. When the relative absorption bandwidth is as high as 51%, the requirement of deep-subwavelength thickness (0.07 lambda) can still be satisfied. We emphasize that the perfect absorption with large tunability in relative bandwidth (from 9% to > 180%) was not attainable previously and may find applications ranging from noise reduction to sound imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 29", "Publication Year": 2016, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64025, "DOI": "10.1103/PhysRevApplied.6.064025", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.6.064025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391066400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XF; Dong, X; Oganov, AR; Zhu, Q; Tian, YJ; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xiang-Feng; Dong, Xiao; Oganov, Artem R.; Zhu, Qiang; Tian, Yongjun; Wang, Hui-Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semimetallic Two-Dimensional Boron Allotrope with Massless Dirac Fermions", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It has been widely accepted that planar boron structures, composed of triangular and hexagonal motifs are the most stable two-dimensional (2D) phases and likely precursors for boron nullostructures. Here we predict, based on an ab initio evolutionary structure search, a novel 2D boron structure with nonzero thickness, which is considerably, by 50 meV/atom, lower in energy than the recently proposed alpha-sheet structure and its analogues. In particular, this phase is identified for the first time to have a distorted Dirac cone, after graphene and silicene the third elemental material with massless Dirac fermions. The buckling and coupling between the two sublattices not only enhance the energetic stability, but also are the key factors for the emergence of the distorted Dirac cone.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 508, "Times Cited, All Databases": 526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2014, "Volume": 112, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85502, "DOI": "10.1103/PhysRevLett.112.085502", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.085502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331958400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SJ; Wang, CC; Dong, KX; Zhang, P; Chen, XB; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shijie; Wang, Chunchun; Dong, Kexin; Zhang, Peng; Chen, Xiaobo; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MIL-101(Fe)/BiOBr S-scheme photocatalyst for promoting photocatalytic abatement of Cr(VI) and enrofloxacin antibiotic: Performance and mechanism", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly active, economical, and robust bifunctional photocatalysts is a priority for sustainable photocatalytic water remediation. Inadequately available reactive sites and sluggish interface photocarrier transfer and separation remain significant challenges in the photoreaction progress. In this study, the Fe-containing metal-organic framework (MOF) MIL-101(Fe) was inte-grated with BiOBr microspheres to form a competent S-scheme heterostructure for the photocatalytic mitigation of Cr(VI) and enrofloxacin (ENR) antibiotics. The optimal MIL-101(Fe)/BiOBr ex-hibited the highest photoactivity, with 99.4% of Cr(VI) and 84.4% of ENR eliminated upon visi-ble-light illumination in a single-pollutant system. The photoactivity of MIL-101(Fe)/BiOBr in the decontamination of the Cr(VI)-ENR co-existence system exhibited a substantial enhancement when compared to that in a single system, owing to the improved utilization of electrons and holes resulting from the synergism between Cr(VI), ENR, and the photocatalyst. The enhanced photoactivity is attributed to two aspects: (1) the incorporation of MIL-101(Fe) results in an increased number of available reactive sites and improved solar harvesting properties; and (2) the S-scheme mechanism enables the effective spatial disassociation of photoexcited carriers and optimization of the pho-to-redox capability of the system. Through scavenging experiments, electron spin resonullce characterization, liquid chromatography-tandem mass spectrometry analysis, and T.E.S.T. theoretical estimation, the catalytic mechanism, antibiotic degradation process, and biotoxicities of the de-graded products were analyzed and confirmed. This study provides a viable strategy for building competent MOF-inorganic semiconductor S-scheme photocatalysts with superior photocatalytic decontamination performance.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 112, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64479-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64479-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001136853100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, S; Kim, J; Won, SM; Ma, YJ; Kang, D; Xie, ZQ; Lee, KT; Chung, HU; Banks, A; Min, S; Heo, SY; Davies, CR; Lee, JW; Lee, CH; Kim, BH; Li, K; Zhou, YD; Wei, C; Feng, X; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Seungyong; Kim, Jeonghyun; Won, Sang Min; Ma, Yinji; Kang, Daeshik; Xie, Zhaoqian; Lee, Kyu-Tae; Chung, Ha Uk; Banks, Anthony; Min, Seunghwan; Heo, Seung Yun; Davies, Charles R.; Lee, Jung Woo; Lee, Chi-Hwan; Kim, Bong Hoon; Li, Kan; Zhou, Yadong; Wei, Chen; Feng, Xue; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Battery-free, wireless sensors for full-body pressure and temperature mapping", "Source Title": "SCIENCE TRANSLATIONAL MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thin, soft, skin-like sensors capable of precise, continuous measurements of physiological health have broad potential relevance to clinical health care. Use of sensors distributed over a wide area for full-body, spatiotemporal mapping of physiological processes would be a considerable advance for this field. We introduce materials, device designs, wireless power delivery and communication strategies, and overall system architectures for skin-like, battery-free sensors of temperature and pressure that can be used across the entire body. Combined experimental and theoretical investigations of the sensor operation and the modes for wireless addressing define the key features of these systems. Studies with human subjects in clinical sleep laboratories and in adjustable hospital beds demonstrate functionality of the sensors, with potential implications for monitoring of circadian cycles and mitigating risks for pressure-induced skin ulcers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2018, "Volume": 10, "Issue": 435, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaan4950", "DOI": "10.1126/scitranslmed.aan4950", "DOI Link": "http://dx.doi.org/10.1126/scitranslmed.aan4950", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429098800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheng, DP; Zhu, L; Dai, X; Xu, C; Li, P; Pearce, CI; Xiao, CL; Chen, J; Zhou, RH; Duan, T; Farha, OK; Chai, ZF; Wang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheng, Daopeng; Zhu, Lin; Dai, Xing; Xu, Chao; Li, Peng; Pearce, Carolyn, I; Xiao, Chengliang; Chen, Jing; Zhou, Ruhong; Duan, Tao; Farha, Omar K.; Chai, Zhifang; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Successful Decontamination of 99TcO4- in Groundwater at Legacy Nuclear Sites by a Cationic Metal-Organic Framework with Hydrophobic Pockets", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tc-99 contamination at legacy nuclear sites is a serious and unsolved environmental issue. The selective remediation of (TcO4-)-Tc-99 in the presence of a large excess of NO3- and SO42- from natural waste systems represents a significant scientific and technical challenge, since anions with a higher charge density are often preferentially sorbed by traditional anion-exchange materials. We present a solution to this challenge based on a stable cationic metal-organic framework, SCU-102 (Ni-2(tipm)(3)(NO3)(4)), which exhibits fast sorption kinetics, a large capacity (291 mg g(-1)), a high distribution coefficient, and, most importantly, a record-high TcO4- uptake selectivity. This material can almost quantitatively remove TcO4- in the presence of a large excess of NO3- and SO42-. Decontamination experiments confirm that SCU-102 represents the optimal Tc scavenger with the highest reported clean-up efficiency, while first-principle simulations reveal that the origin of the selectivity is the recognition of TcO4- by the hydrophobic pockets of the structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2019, "Volume": 58, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4968, "End Page": 4972, "Article Number": null, "DOI": "10.1002/anie.201814640", "DOI Link": "http://dx.doi.org/10.1002/anie.201814640", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463739900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zampardi, G; La Mantia, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zampardi, Giorgia; La Mantia, Fabio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Open challenges and good experimental practices in the research field of aqueous Zn-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries are realistic candidates as stationary storage systems for power-grid applications. However, to accelerate their commercialization, some important challenges must be specifically tackled, and appropriate experimental practices need to be embraced to align the academic research efforts with the realistic industrial working conditions for stationary storage. Within this commentary article, both the open challenges and the good experimental practices are discussed in relation to their impact on the future development of the aqueous Zn-ion technology. Aqueous Zn-based batteries represent a viable and cost-effective technology for electricity grid storage. Here, the authors discuss the most challenging aspects to bridge academic and industrial research and accelerate the adoption of this class of devices on a large scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 687, "DOI": "10.1038/s41467-022-28381-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28381-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752207900034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CQ; Du, X; Jiang, S; Liu, Y; Niu, ZL; Liu, ZY; Yi, SS; Yue, XZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chuan-Qi; Du, Xin; Jiang, Shan; Liu, Yan; Niu, Zhu-Lin; Liu, Zhong-Yi; Yi, Sha-Sha; Yue, Xin-Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Direct Z-Scheme Heterostructure by Enwrapping ZnIn2S4 on CdS Hollow Cube for Efficient Photocatalytic H2 Generation", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design hybrid nullostructure photocatalysts with efficient charge separation and transfer, and good solar light harvesting ability have critical significance for achieving high solar-to-chemical conversion efficiency. Here a highly active and stable composite photocatalyst is reported by integrating ultrathin ZnIn2S4 nullosheets on surface of hollow CdS cube to form the cube-in-cube structure. Experimental results combined with density functional theory calculations confirm that the Z-scheme ZnIn2S4/CdS heterojunction is formed, which highly boosts the charge separation and transfer under the local-electric-field at semiconductor/semiconductor interface, and thus prolongs their lifetimes. Moreover, such a structure affords the highly enhanced light-harvesting property. The optimized ZnIn2S4/CdS nullohybrids exhibit superior H-2 generation rate under visible-light irradiation (lambda >= 420 nm) with excellent photochemical stability during 20 h continuous operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201773, "DOI": "10.1002/advs.202201773", "DOI Link": "http://dx.doi.org/10.1002/advs.202201773", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000815026700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, ZH; Ren, W; Chen, H; Bellaiche, L; Zhang, ZY; MacDonald, AH; Niu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Zhenhua; Ren, Wei; Chen, Hua; Bellaiche, L.; Zhang, Zhenyu; MacDonald, A. H.; Niu, Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum Anomalous Hall Effect in Graphene Proximity Coupled to an Antiferromagnetic Insulator", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose realizing the quantum anomalous Hall effect by proximity coupling graphene to an antiferromagnetic insulator that provides both broken time-reversal symmetry and spin-orbit coupling. We illustrate our idea by performing ab initio calculations for graphene adsorbed on the (111) surface of BiFeO3. In this case, we find that the proximity-induced exchange field in graphene is about 70 meV, and that a topologically nontrivial band gap is opened by Rashba spin-orbit coupling. The size of the gap depends on the separation between the graphene and the thin film substrate, which can be tuned experimentally by applying external pressure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2014, "Volume": 112, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116404, "DOI": "10.1103/PhysRevLett.112.116404", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.116404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332925900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, T; Li, QC; Liao, J; Zhang, Y; Zhu, WK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Ting; Li, Qichen; Liao, Jun; Zhang, Yong; Zhu, Wenkun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly enhanced adsorption performance to uranium(VI) by facile synthesized hydroxyapatite aerogel", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to protect environment and save uranium resources, it was necessary to find a highly efficient adsorbent for uranium recovery from wastewater. In this work, we used a freeze-drying-calcination method to synthesize HAP aerogel to effectively remove uranium. Compared with commercially available nullo-hydroxyapatite, HAP aemgel presented better adsorption performance. This was because the as-prepared HAP aemgel presented continuous porous structure, which could provide more active sites for the adsorption to uranium. The uranium removal efficiency of HAP aerogel arrived 99.4% within 10 min and the maximum adsorption capacity was up to 2087.6 mg g(-1) at pH = 4.0 and 298 K. In addition, the immobilization of uranium on HAP aerogel was chemisorption, which was probably due to adsorption, dissolution-precipitation and ions exchange. These results indicated that the as-prepared HAP aerogel could be widely used as a high efficiency and potential adsorbent for the treatment of uranium-containing wastewater in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2022, "Volume": 423, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127184, "DOI": "10.1016/j.jhazmat.2021.127184", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2021.127184", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000697058500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McGuire, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McGuire, Michael A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides", "Source Title": "CRYSTALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials composed of two dimensional layers bonded to one another through weak van der Waals interactions often exhibit strongly anisotropic behaviors and can be cleaved into very thin specimens and sometimes into monolayer crystals. Interest in such materials is driven by the study of low dimensional physics and the design of functional heterostructures. Binary compounds with the compositions MX2 and MX3 where M is a metal cation and X is a halogen anion often form such structures. Magnetism can be incorporated by choosing a transition metal with a partially filled d-shell for M, enabling ferroic responses for enhanced functionality. Here a brief overview of binary transition metal dihalides and trihalides is given, summarizing their crystallographic properties and long-range-ordered magnetic structures, focusing on those materials with layered crystal structures and partially filled d-shells required for combining low dimensionality and cleavability with magnetism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121, "DOI": "10.3390/cryst7050121", "DOI Link": "http://dx.doi.org/10.3390/cryst7050121", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Crystallography; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402965400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amano, H; Collazo, R; De Santi, C; Einfeldt, S; Funato, M; Glaab, J; Hagedorn, S; Hirano, A; Hirayama, H; Ishii, R; Kashima, Y; Kawakami, Y; Kirste, R; Kneissl, M; Martin, R; Mehnke, F; Meneghini, M; Ougazzaden, A; Parbrook, PJ; Rajan, S; Reddy, P; Römer, F; Ruschel, J; Sarkar, B; Scholz, F; Schowalter, LJ; Shields, P; Sitar, Z; Sulmoni, L; Wang, T; Wernicke, T; Weyers, M; Witzigmann, B; Wu, YR; Wunderer, T; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amano, Hiroshi; Collazo, Ramon; Santi, Carlo De; Einfeldt, Sven; Funato, Mitsuru; Glaab, Johannes; Hagedorn, Sylvia; Hirano, Akira; Hirayama, Hideki; Ishii, Ryota; Kashima, Yukio; Kawakami, Yoichi; Kirste, Ronny; Kneissl, Michael; Martin, Robert; Mehnke, Frank; Meneghini, Matteo; Ougazzaden, Abdallah; Parbrook, Peter J.; Rajan, Siddharth; Reddy, Pramod; Roemer, Friedhard; Ruschel, Jan; Sarkar, Biplab; Scholz, Ferdinulld; Schowalter, Leo J.; Shields, Philip; Sitar, Zlatko; Sulmoni, Luca; Wang, Tao; Wernicke, Tim; Weyers, Markus; Witzigmann, Bernd; Wu, Yuh-Renn; Wunderer, Thomas; Zhang, Yuewei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The 2020 UV emitter roadmap", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid state UV emitters have many advantages over conventional UV sources. The (Al,In,Ga)N material system is best suited to produce LEDs and laser diodes from 400 nm down to 210 nm-due to its large and tuneable direct band gap, n- and p-doping capability up to the largest bandgap material AlN and a growth and fabrication technology compatible with the current visible InGaN-based LED production. However AlGaN based UV-emitters still suffer from numerous challenges compared to their visible counterparts that become most obvious by consideration of their light output power, operation voltage and long term stability. Most of these challenges are related to the large bandgap of the materials. However, the development since the first realization of UV electroluminescence in the 1970s shows that an improvement in understanding and technology allows the performance of UV emitters to be pushed far beyond the current state. One example is the very recent realization of edge emitting laser diodes emitting in the UVC at 271.8 nm and in the UVB spectral range at 298 nm. This roadmap summarizes the current state of the art for the most important aspects of UV emitters, their challenges and provides an outlook for future developments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 9", "Publication Year": 2020, "Volume": 53, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 503001, "DOI": "10.1088/1361-6463/aba64c", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/aba64c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573488200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SD; Xie, ZP; Zhu, D; Fu, S; Wu, YS; Yu, HL; Lu, CY; Zhou, PK; Bonn, M; Wang, HI; Liao, Q; Xu, H; Chen, X; Gu, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shengdong; Xie, Zhipeng; Zhu, Da; Fu, Shuai; Wu, Yishi; Yu, Hongling; Lu, Chuangye; Zhou, Panke; Bonn, Mischa; Wang, Hai I.; Liao, Qing; Xu, Hong; Chen, Xiong; Gu, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient photocatalytic production of hydrogen peroxide using dispersible and photoactive porous polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing efficient artificial photocatalysts for the biomimetic photocatalytic production of molecular materials, including medicines and clean energy carriers, remains a fundamentally and technologically essential challenge. Hydrogen peroxide is widely used in chemical synthesis, medical disinfection, and clean energy. However, the current industrial production, predominulltly by anthraquinone oxidation, suffers from hefty energy penalties and toxic byproducts. Herein, we report the efficient photocatalytic production of hydrogen peroxide by protonation-induced dispersible porous polymers with good charge-carrier transport properties. Significant photocatalytic hydrogen peroxide generation occurs under ambient conditions at an unprecedented rate of 23.7 mmol g-1 h-1 and an apparent quantum efficiency of 11.3% at 450 nm. Combined simulations and spectroscopies indicate that sub-picosecond ultrafast electron localization from both free carriers and exciton states at the catalytic reaction centers underlie the remarkable photocatalytic performance of the dispersible porous polymers. Current industrial production of hydrogen peroxide suffers from hefty energy penalties and toxic byproducts. Here, the authors report efficient photocatalytic production of hydrogen peroxide by protonation-induced dispersible porous polymers with good charge-carrier transport properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6891, "DOI": "10.1038/s41467-023-42720-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42720-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001093326300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maughan, AE; Ganose, AM; Bordelon, MM; Miller, EM; Scanlon, DO; Neilson, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maughan, Annalise E.; Ganose, Alex M.; Bordelon, Mitchell M.; Miller, Elisa M.; Scanlon, David O.; Neilson, James R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect Tolerance to Intolerance in the Vacancy-Ordered Double Perovskite Semiconductors Cs2SnI6 and Cs2TeI6", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vacancy-ordered double perovskites of the general formula A(2)BX(6) are a family of perovskite derivatives composed of a face-centered lattice of nearly isolated [BX6] units with A-site cations occupying the cuboctahedral voids. Despite the presence of isolated octahedral units, the close-packed iodide lattice provides significant electronic dispersion, such that Cs2SnI6 has recently been explored for applications in photovoltaic devices. To elucidate the structure property relationships of these materials, we have synthesized solid-solution Cs2Sn1-xTexI6. However, even though tellurium substitution increases electronic dispersion via closer I-I contact distances, the substitution experimentally yields insulating behavior from a significant decrease in carrier concentration and mobility. Density functional calculations of native defects in Cs2SnI6 reveal that iodine vacancies exhibit a low enthalpy of formation, and that the defect energy level is a shallow donor to the conduction band rendering the material tolerant to these defect states. The increased covalency of Te-I bonding renders the formation of iodine vacancy states unfavorable and is responsible for the reduction in conductivity upon Te substitution. Additionally, Cs2TeI6 is intolerant to the formation of these defects, because the defect level occurs deep within the band gap and thus localizes potential mobile charge carriers. In these vacancy-ordered double perovskites, the close-packed lattice of iodine provides significant electronic dispersion, while the interaction of the B- and X-site ions dictates the properties as they pertain to electronic structure and defect tolerance. This simplified perspective based on extensive experimental and theoretical analysis provides a platform from which to understand structure property relationships in functional perovskite halides", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2016, "Volume": 138, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8453, "End Page": 8464, "Article Number": null, "DOI": "10.1021/jacs.6b03207", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b03207", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379794400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bliem, R; McDermott, E; Ferstl, P; Setvin, M; Gamba, O; Pavelec, J; Schneider, MA; Schmid, M; Diebold, U; Blaha, P; Hammer, L; Parkinson, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bliem, R.; McDermott, E.; Ferstl, P.; Setvin, M.; Gamba, O.; Pavelec, J.; Schneider, M. A.; Schmid, M.; Diebold, U.; Blaha, P.; Hammer, L.; Parkinson, G. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subsurface cation vacancy stabilization of the magnetite (001) surface", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron oxides play an increasingly prominent role in heterogeneous catalysis, hydrogen production, spintronics, and drug delivery. The surface or material interface can be performance-limiting in these applications, so it is vital to determine accurate atomic-scale structures for iron oxides and understand why they form. Using a combination of quantitative low-energy electron diffraction, scanning tunneling microscopy, and density functional theory calculations, we show that an ordered array of subsurface iron vacancies and interstitials underlies the well-known (root 2 x root 2)R45 degrees reconstruction of Fe3O4(001). This hitherto unobserved stabilization mechanism occurs because the iron oxides prefer to redistribute cations in the lattice in response to oxidizing or reducing environments. Many other metal oxides also achieve stoichiometry variation in this way, so such surface structures are likely commonplace.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 346, "Issue": 6214, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1215, "End Page": 1218, "Article Number": null, "DOI": "10.1126/science.1260556", "DOI Link": "http://dx.doi.org/10.1126/science.1260556", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346189000054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, WC; Liu, WL; Chen, J; Wang, Z; Liu, YK; Pu, XJ; Yang, HM; Tang, Q; Yang, HK; Guo, HY; Hu, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Wencong; Liu, Wenlin; Chen, Jie; Wang, Zhao; Liu, Yike; Pu, Xianjie; Yang, Hongmei; Tang, Qian; Yang, Huake; Guo, Hengyu; Hu, Chenguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting output performance of sliding mode triboelectric nullogenerator by charge space-accumulation effect", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sliding mode triboelectric nullogenerator (S-TENG) is an effective technology for in-plane low-frequency mechanical energy harvesting. However, as surface modification of tribo-materials and charge excitation strategies are not well applicable for this mode, output performance promotion of S-TENG has no breakthrough recently. Herein, we propose a new strategy by designing shielding layer and alternative blank-tribo-area enabled charge space-accumulation (CSA) for enormously improving the charge density of S-TENG. It is found that the shielding layer prevents the air breakdown on the interface of tribo-layers effectively and the blank-tribo-area with charge dissipation on its surface of tribo-material promotes charge accumulation. The charge space-accumulation mechanism is analyzed theoretically and verified by experiments. The charge density of CSA-S-TENG achieves a 2.3 fold enhancement (1.63 mC m(-2)) of normal S-TENG in ambient conditions. This work provides a deep understanding of the working mechanism of S-TENG and an effective strategy for promoting its output performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4277, "DOI": "10.1038/s41467-020-18086-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18086-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567553400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, JC; Wang, CW; Zhang, CC; Hu, YL; Yang, L; Lao, ZX; Xu, B; Li, JW; Wu, D; Chu, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Jincheng; Wang, Chaowei; Zhang, Chenchu; Hu, Yanlei; Yang, Liang; Lao, Zhaoxin; Xu, Bing; Li, Jiawen; Wu, Dong; Chu, Jiaru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional chiral microstructures fabricated by structured optical vortices in isotropic material", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical vortices, a type of structured beam with helical phase wavefronts and 'doughnut'-shaped intensity distributions, have been used to fabricate chiral structures in metals and spiral patterns in anisotropic polarization-dependent azobenzene polymers. However, in isotropic polymers, the fabricated microstructures are typically confined to non-chiral cylindrical geometry due to the two-dimensional 'doughnut'-shaped intensity profile of the optical vortices. Here we develop a powerful strategy to realize chiral microstructures in isotropic material by coaxial interference of a vortex beam and a plane wave, which produces threedimensional (3D) spiral optical fields. These coaxial interference beams are generated by designing contrivable holograms consisting of an azimuthal phase and an equiphase loaded on a liquid-crystal spatial light modulator. In isotropic polymers, 3D chiral microstructures are achieved under illumination using coaxial interference femtosecond laser beams with their chirality controlled by the topological charge. Our further investigation reveals that the spiral lobes and chirality are caused by interfering patterns and helical phase wavefronts, respectively. This technique is simple, stable and easy to perform, and it offers broad applications in optical tweezers, optical communications and fast metamaterial fabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2017, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e17011", "DOI": "10.1038/lsa.2017.11", "DOI Link": "http://dx.doi.org/10.1038/lsa.2017.11", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405491800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, SJ; Zhong, Y; Zeng, YX; Wang, YD; Wang, XL; Lu, XH; Xia, XH; Tu, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Shengjue; Zhong, Yu; Zeng, Yinxiang; Wang, Yadong; Wang, Xiuli; Lu, Xihong; Xia, Xinhui; Tu, Jiangping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow TiO2@Co9S8 Core-Branch Arrays as Bifunctional Electrocatalysts for Efficient Oxygen/Hydrogen Production", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing ever more efficient and cost-effective bifunctional electrocatalysts for oxygen/hydrogen evolution reactions (OER/HER) is greatly vital and challenging. Here, a new type of binder-free hollow TiO2@Co9S8 core-branch arrays is developed as highly active OER and HER electrocatalysts for stable overall water splitting. Hollow core-branch arrays of TiO2@Co9S8 are readily realized by the rational combination of crosslinked Co9S8 nulloflakes on TiO2 core via a facile and powerful sulfurization strategy. Arising from larger active surface area, richer/shorter transfer channels for ions/electrons, and reinforced structural stability, the as-obtained TiO2@Co9S8 core-branch arrays show noticeable exceptional electrocatalytic performance, with low overpotentials of 240 and 139 mV at 10 mA cm(-2) as well as low Tafel slopes of 55 and 65 mV Dec(-1) for OER and HER in alkaline medium, respectively. Impressively, the electrolysis cell based on the TiO2@Co9S8 arrays as both cathode and anode exhibits a remarkably low water splitting voltage of 1.56 V at 10 mA cm(-2) and long-term durability with no decay after 10 d. The versatile fabrication protocol and smart branch-core design provide a new way to construct other advanced metal sulfides for energy conversion and storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700772, "DOI": "10.1002/advs.201700772", "DOI Link": "http://dx.doi.org/10.1002/advs.201700772", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428310500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QL; Cheng, K; Hu, X; Ma, XW; Zhang, RP; Yang, M; Lu, XM; Xing, L; Huang, W; Gambhir, SS; Cheng, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Quli; Cheng, Kai; Hu, Xiang; Ma, Xiaowei; Zhang, Ruiping; Yang, Min; Lu, Xiaomei; Xing, Lei; Huang, Wei; Gambhir, Sanjiv Sam; Cheng, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transferring Biomarker into Molecular Probe: Melanin nulloparticle as a Naturally Active Platform for Multimodality Imaging", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing multifunctional and easily prepared nulloplatforms with integrated different modalities is highly challenging for molecular imaging. Here, we report the successful transfer of an important molecular target, melanin, into a novel multimodality imaging nulloplatform. Melanin is abundantly expressed in melanotic melanomas and thus has been actively studied as a target for melanoma imaging. In our work, the multifunctional biopolymer nulloplatform based on ultrasmall (<10 nm) water-soluble melanin nulloparticle (MNP) was developed and showed unique photoacoustic property and natural binding ability with metal ions (for example, Cu-64(2+), Fe3+). Therefore, MNP can serve not only as a photoacoustic contrast agent, but also as a nulloplatform for positron emission tomography (PET) and magnetic resonullce imaging (MRI). Traditional passive nulloplatforms require complicated and time-consuming processes for prebuilding reporting moieties or chemical modifications using active groups to integrate different contrast properties into one entity. In comparison, utilizing functional biomarker melanin can greatly simplify the building process. We further conjugated av beta 3 integrins, cyclic c(RGDfC) peptide, to MNPs to allow for U87MG tumor accumulation due to its targeting property combined with the enhanced permeability and retention (EPR) effect. The multimodal properties of MNPs demonstrate the high potential of endogenous materials with multifunctions as nulloplatforms for molecular theranostics and clinical translation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2014, "Volume": 136, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15185, "End Page": 15194, "Article Number": null, "DOI": "10.1021/ja505412p", "DOI Link": "http://dx.doi.org/10.1021/ja505412p", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344042900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XJ; Li, W; Hu, SS; Akhmedov, NG; Reed, D; Li, XL; Liu, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiujuan; Li, Wei; Hu, Shanshan; Akhmedov, Novruz G.; Reed, David; Li, Xiaolin; Liu, Xingbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyvinyl alcohol coating induced preferred crystallographic orientation in aqueous zinc battery anodes", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of rechargeable aqueous zinc batteries is mainly hindered by the Zn anode, which suffers from dendrite growth, corrosion, hydrogen evolution, and surface passivation. Herein, a thin polyvinyl alcohol (PVA) coating layer on Zn anode has enabled dendrite-free, long-life aqueous Zn batteries by effectively regulating the interfacial ion diffusion and inducing the homogeneous Zn nucleation and deposition of stacked plates with preferentially crystallographic orientation along (002)Zn planes. The PVA@Zn anode achieved an ultralong cycle lifespan of thousands of hours at 0.25 and 1 mA cm(-2). Outstanding durability under a deep cycling capacity (5 mA h cm(-2)), high current density (10 mA cm(-2)), and long duration conditions were achieved. The superior cyclability of PVA@Zn anode was also demonstrated in PVA@Zn//V2O5 full cells. The insights of PVA induced Zn deposition with preferred crystal orientation and interfacial regulation shed light on the future development of stable Zn anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 98, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107269, "DOI": "10.1016/j.nulloen.2022.107269", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2022.107269", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000793654700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, R; Weng, HM; Fang, Z; Dai, X; Hu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Rui; Weng, Hongming; Fang, Zhong; Dai, Xi; Hu, Xiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Node-Line Semimetal and Dirac Semimetal State in Antiperovskite Cu3PdN", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on first-principles calculation and effective model analysis, we propose that the cubic antiperovskite material Cu3PdN can host a three-dimensional (3D) topological node-line semimetal state when spin-orbit coupling (SOC) is ignored, which is protected by the coexistence of time-reversal and inversion symmetry. There are three node-line circles in total due to the cubic symmetry. Drumheadlike surface flat bands are also derived. When SOC is included, each node line evolves into a pair of stable 3D Dirac points as protected by C-4 crystal symmetry. This is remarkably distinguished from the Dirac semimetals known so far, such as Na3Bi and Cd3As2, both having only one pair of Dirac points. Once C-4 symmetry is broken, the Dirac points are gapped and the system becomes a strong topological insulator with (1;111) Z(2) indices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 708, "Times Cited, All Databases": 738, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2015, "Volume": 115, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36807, "DOI": "10.1103/PhysRevLett.115.036807", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.036807", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358034400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, SP; Shi, H; Dai, TY; Liu, Y; Wen, Z; Han, GF; Wang, TH; Zhang, W; Lang, XY; Zheng, WT; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Shu-Pei; Shi, Hang; Dai, Tian-Yi; Liu, Yang; Wen, Zi; Han, Gao-Feng; Wang, Tong-Hui; Zhang, Wei; Lang, Xing-You; Zheng, Wei-Tao; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lamella-heterostructured nulloporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride electrodes as stable catalysts for oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing robust nonprecious-metal electrocatalysts with high activity towards sluggish oxygen-evolution reaction is paramount for large-scale hydrogen production via electrochemical water splitting. Here we report that self-supported laminate composite electrodes composed of alternating nulloporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride (FeCo/CeO2-xNx) heterolamellas hold great promise as highly efficient electrocatalysts for alkaline oxygen-evolution reaction. By virtue of three-dimensional nulloporous architecture to offer abundant and accessible electroactive CoFeOOH/CeO2-xNx heterostructure interfaces through facilitating electron transfer and mass transport, nulloporous FeCo/CeO2-xNx composite electrodes exhibit superior oxygen-evolution electrocatalysis in 1 M KOH, with ultralow Tafel slope of similar to 33 mV dec(-1). At overpotential of as low as 360 mV, they reach >3900 mA cm(-2) and retain exceptional stability at similar to 1900 mA cm(-2) for >1000 h, outperforming commercial RuO2 and some representative oxygen-evolution-reaction catalysts recently reported. These electrochemical properties make them attractive candidates as oxygen-evolution-reaction electrocatalysts in electrolysis of water for large-scale hydrogen generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1811, "DOI": "10.1038/s41467-023-37597-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37597-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980769900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Salvatore, GA; Araki, H; Chiarelli, AM; Xie, ZQ; Banks, A; Sheng, X; Liu, YH; Lee, JW; Jang, KI; Heo, SY; Cho, K; Luo, HY; Zimmerman, B; Kim, J; Yan, LQ; Feng, X; Xu, S; Fabiani, M; Gratton, G; Huang, YG; Paik, U; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jeonghyun; Salvatore, Giovanni A.; Araki, Hitoshi; Chiarelli, Antonio M.; Xie, Zhaoqian; Banks, Anthony; Sheng, Xing; Liu, Yuhao; Lee, Jung Woo; Jang, Kyung-In; Heo, Seung Yun; Cho, Kyoungyeon; Luo, Hongying; Zimmerman, Benjamin; Kim, Joonhee; Yan, Lingqing; Feng, Xue; Xu, Sheng; Fabiani, Monica; Gratton, Gabriele; Huang, Yonggang; Paik, Ungyu; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Battery-free, stretchable optoelectronic systems for wireless optical characterization of the skin", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in materials, mechanics, and electronic device design are rapidly establishing the foundations for health monitoring technologies that have skin-like properties, with options in chronic (weeks) integration with the epidermis. The resulting capabilities in physiological sensing greatly exceed those possible with conventional hard electronic systems, such as those found in wrist-mounted wearables, because of the intimate skin interface. However, most examples of such emerging classes of devices require batteries and/or hard-wired connections to enable operation. The work reported here introduces active optoelectronic systems that function without batteries and in an entirely wireless mode, with examples in thin, stretchable platforms designed for multiwavelength optical characterization of the skin. Magnetic inductive coupling and near-field communication (NFC) schemes deliver power to multicolored light-emitting diodes and extract digital data from integrated photodetectors in ways that are compatible with standard NFC-enabled platforms, such as smartphones and tablet computers. Examples in the monitoring of heart rate and temporal dynamics of arterial blood flow, in quantifying tissue oxygenation and ultraviolet dosimetry, and in performing four-color spectroscopic evaluation of the skin demonstrate the versatility of these concepts. The results have potential relevance in both hospital care and at-home diagnostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1600418", "DOI": "10.1126/sciadv.1600418", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1600418", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383734300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, Y; Xie, C; Chechetka, SA; Miyako, E; Pu, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Yan; Xie, Chen; Chechetka, Svetlana A.; Miyako, Eijiro; Pu, Kanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semiconducting Polymer nullobioconjugates for Targeted Photothermal Activation of Neurons", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optogenetics provides powerful means for precise control of neuronal activity; however, the requirement of transgenesis and the incapability to extend the neuron excitation window into the deep-tissue-penetrating near-infrared (NIR) region partially limit its application. We herein report a potential alternative approach to optogenetics using semiconducting polymer nullobioconjugates (SPNs(bc)) as the photothermal nullomodulator to control the thermosensitive ion channels in neurons. SPNs(bc) are designed to efficiently absorb the NIR light at 808 rim and have a photothermal conversion efficiency higher than that of gold nullorods. By virtue of the fast heating capability in conjunction with the precise targeting to the thermosensitive ion channel, SPNs(bc) can specifically and rapidly activate the intracellular Ca2+ influx of neuronal cells in a reversible and safe manner. Our study provides an organic nulloparticle based strategy that eliminates the need for genetic transfection to remotely regulate cellular machinery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2016, "Volume": 138, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9049, "End Page": 9052, "Article Number": null, "DOI": "10.1021/jacs.6b05192", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b05192", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380730000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Clausen, A; Wang, FW; Jensen, JS; Sigmund, O; Lewis, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Clausen, Anders; Wang, Fengwen; Jensen, Jakob S.; Sigmund, Ole; Lewis, Jennifer A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topology Optimized Architectures with Programmable Poisson's Ratio over Large Deformations", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topology optimized architectures are designed and printed with programmable Poisson's ratios ranging from -0.8 to 0.8 over large deformations of 20% or more.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 425, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2015, "Volume": 27, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5523, "End Page": 5527, "Article Number": null, "DOI": "10.1002/adma.201502485", "DOI Link": "http://dx.doi.org/10.1002/adma.201502485", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362727900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, WY; Fu, PB; Zhang, YY; Xu, H; Wang, HL; Xing, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wenyuan; Fu, Pengbo; Zhang, Yayun; Xu, Hai; Wang, Hualin; Xing, Mingyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen production from wastewater remediation by piezoelectricity coupling advanced oxidation processes", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient H2 harvesting from wastewater instead of pure water can minimize fresh water consumption, which is expected to solve the problem of water shortage in H2 production process and contribute to carbon neutrality in the environmental remediation, but the inevitable electron depletion caused by electron-consuming pollutants will result in an exhausted H2 evolution reaction (HER) performance. In this paper, by coupling piezo-catalysis and advanced oxidation processes (AOPs) by a MoS2/Fe0/peroxymonosulfate (PMS) ternary system, extensive types of wastewater achieved considerable H2 genera-tion, which exceeded the yield in pure water with synchronous advanced degradation of organic pollutants. In addition, profiting from the crucial bridging role of PMS, the H2 yield in nitrobenzene wastewater after the introduction of PMS-based AOPs increased 3.37-fold from 267.7 mu mol center dot g-1 center dot h-1 to 901.0 mu mol center dot g-1 center dot h-1 because the presence of PMS both thermodynamically benefited MoS2 piezocatalytic H2 evolution and eliminated the electron depletion caused by organic pollutants. By this way, the original repressed H2 evolution performance in substrate of wastewater not only was regained but even showed a significant enhancement than that in pure water (505.7 mu mol center dot g-1 center dot h-1). Additionally, the cyclonic piezoelectric reactor was preliminarily designed for future industrialization. This strategy provided a valuable path for the recycling of actual wastewater by fuel production and synchronous advanced treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2023, "Volume": 120, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2218813120", "DOI": "10.1073/pnas.2218813120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2218813120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169167100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, ZL; Shanmugam, M; Liu, Z; Brookfield, A; Bennett, EL; Guan, RP; Herrera, DEV; Lopez-Sanchez, JA; Slater, AG; McInnes, EJL; Qi, XT; Xiao, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Zhiliang; Shanmugam, Muralidharan; Liu, Zhao; Brookfield, Adam; Bennett, Elliot L.; Guan, Renpeng; Herrera, David E. Vega; Lopez-Sanchez, Jose A.; Slater, Anna G.; McInnes, Eric J. L.; Qi, Xiaotian; Xiao, Jianliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical Recycling of Polystyrene to Valuable Chemicals via Selective Acid-Catalyzed Aerobic Oxidation under Visible Light", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical recycling is one of the most promisingtechnologies that could contribute to circular economy targets byproviding solutions to plastic waste; however, it is still at an earlystage of development. In this work, we describe thefirst light-driven, acid-catalyzed protocol for chemical recycling of poly-styrene waste to valuable chemicals under 1 bar of O2. Requiringno photosensitizers and only mild reaction conditions, the protocolis operationally simple and has also been demonstrated in aflowsystem. Electron paramagnetic resonullce (EPR) investigations anddensity functional theory (DFT) calculations indicate that singletoxygen is involved as the reactive oxygen species in thisdegradation process, which abstracts a hydrogen atom from a tertiary C-H bond, leading to hydroperoxidation and subsequentC-C bond cracking events via a radical process. Notably, our study indicates that an adduct of polystyrene and an acid catalystmight be formed in situ, which could act as a photosensitizer to initiate the formation of singlet oxygen. In addition, the oxidizedpolystyrene polymer may play a role in the production of singlet oxygen under light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 176, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2022, "Volume": 144, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6532, "End Page": 6542, "Article Number": null, "DOI": "10.1021/jacs.2c01410", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c01410", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826349900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ZC; Liu, M; Guo, ZN; Jiang, XF; Luo, AP; Zhao, CJ; Yu, XF; Xu, WC; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhi-Chao; Liu, Meng; Guo, Zhi-null; Jiang, Xiao-Fang; Luo, Ai-Ping; Zhao, Chu-Jun; Yu, Xue-Feng; Xu, Wen-Cheng; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microfiber-based few-layer black phosphorus saturable absorber for ultra-fast fiber laser", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer black phosphorus (BP), as the most alluring graphene analogue owing to its similar structure as graphene and thickness dependent direct band-gap, has now triggered a new wave of research on two-dimensional (2D) materials based photonics and optoelectronics. However, a major obstacle of practical applications for few-layer BPs comes from their instabilities of laser-induced optical damage. Herein, we demonstrate that, few-layer BPs, which was fabricated through the liquid exfoliation approach, can be developed as a new and practical saturable absorber (SA) by depositing few-layer BPs with microfiber. The saturable absorption property of few-layer BPs had been verified through an open-aperture z-scan measurement at the telecommunication band. The microfiber-based BP device had been found to show a saturable average power of similar to 4.5 mW and a modulation depth of 10.9%, which is further confirmed through a balanced twin detection measurement. By integrating this optical SA device into an erbium-doped fiber laser, it was found that it can deliver the mode-locked pulse with duration down to 940 fs with central wavelength tunable from 1532 nm to 1570 nm. The prevention of BP from oxidation through the lateral interaction scheme owing to this microfiber-based few-layer BP SA device might partially mitigate the optical damage problem of BP. Our results not only demonstrate that black phosphorus might be another promising SA material for ultrafast photonics, but also provide a practical solution to solve the optical damage problem of black phosphorus by assembling with waveguide structures such as microfiber. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2015, "Volume": 23, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20030, "End Page": 20039, "Article Number": null, "DOI": "10.1364/OE.23.020030", "DOI Link": "http://dx.doi.org/10.1364/OE.23.020030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361035300141", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, Y; Zheng, ZK; Wei, DH; Jiang, X; Lu, HF; Sun, L; Tao, FB; Guo, DL; Liu, Y; Gao, JF; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Yang; Zheng, Zhikun; Wei, Donghui; Jiang, Xin; Lu, Hongfei; Sun, Lei; Tao, Fengbo; Guo, Dongliang; Liu, Yang; Gao, Jinfeng; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detection of Micro-Scale Li Dendrite via H2 Gas Capture for Early Safety Warning", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-ion battery safety issues related to fires and explosions are frequently triggered by Li dendrite growth, which is a predominullt reason for separator piercing and cell shorts and is very difficult to detect in the early state. Here, we developed a sensitive detection method based on H-2 gas capture that could detect trace amounts of Li dendrite formation. H-2 gas was generated due to reaction of metallic Li with polymer binders. Even micron-scale Li dendrite (similar to 2.8 x 10(-4) mg and 50 mu m) growth can trigger H-2 capture. Overcharge experiment with a LiFePO4-graphite battery pack (8.8 kWh) shows that H-2 was captured first among H-2, CO, CO2, HCL, HF, and SO2, and the capture time was 639 s earlier than smoke and 769 s earlier than fire. The Li dendrite growth can be completely prevented once H-2 is captured, with neither smoke nor fire observed, which provides an effective method for early safety warning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2020, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1714, "End Page": 1729, "Article Number": null, "DOI": "10.1016/j.joule.2020.05.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.05.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561454400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumaravel, V; Imam, MD; Badreldin, A; Chava, RK; Do, JY; Kang, M; Abdel-Wahab, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumaravel, Vignesh; Imam, Muhammad Danyal; Badreldin, Ahmed; Chava, Rama Krishna; Do, Jeong Yeon; Kang, Misook; Abdel-Wahab, Ahmed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts", "Source Title": "CATALYSTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic water splitting is a sustainable technology for the production of clean fuel in terms of hydrogen (H-2). In the present study, hydrogen (H-2) production efficiency of three promising photocatalysts (titania (TiO2-P25), graphitic carbon nitride (g-C3N4), and cadmium sulfide (CdS)) was evaluated in detail using various sacrificial agents. The effect of most commonly used sacrificial agents in the recent years, such as methanol, ethanol, isopropanol, ethylene glycol, glycerol, lactic acid, glucose, sodium sulfide, sodium sulfite, sodium sulfide/sodium sulfite mixture, and triethanolamine, were evaluated on TiO2-P25, g-C3N4, and CdS. H-2 production experiments were carried out under simulated solar light irradiation in an immersion type photo-reactor. All the experiments were performed without any noble metal co-catalyst. Moreover, photolysis experiments were executed to study the H-2 generation in the absence of a catalyst. The results were discussed specifically in terms of chemical reactions, pH of the reaction medium, hydroxyl groups, alpha hydrogen, and carbon chain length of sacrificial agents. The results revealed that glucose and glycerol are the most suitable sacrificial agents for an oxide photocatalyst. Triethanolamine is the ideal sacrificial agent for carbon and sulfide photocatalyst. A remarkable amount of H-2 was produced from the photolysis of sodium sulfide and sodium sulfide/sodium sulfite mixture without any photocatalyst. The findings of this study would be highly beneficial for the selection of sacrificial agents for a particular photocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 276, "DOI": "10.3390/catal9030276", "DOI Link": "http://dx.doi.org/10.3390/catal9030276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465012800056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Higashi, S; Lee, SW; Lee, JS; Takechi, K; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Higashi, Shougo; Lee, Seok Woo; Lee, Jang Soo; Takechi, Kensuke; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Avoiding short circuits from zinc metal dendrites in anode by backside-plating configuration", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Portable power sources and grid-scale storage both require batteries combining high energy density and low cost. Zinc metal battery systems are attractive due to the low cost of zinc and its high charge-storage capacity. However, under repeated plating and stripping, zinc metal anodes undergo a well-known problem, zinc dendrite formation, causing internal shorting. Here we show a backside-plating configuration that enables long-term cycling of zinc metal batteries without shorting. We demonstrate 800 stable cycles of nickel-zinc batteries with good power rate (20 mA cm(-2), 20 C rate for our anodes). Such a backside-plating method can be applied to not only zinc metal systems but also other metal-based electrodes suffering from internal short circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11801, "DOI": "10.1038/ncomms11801", "DOI Link": "http://dx.doi.org/10.1038/ncomms11801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377384900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Yang, Y; Jia, SF; Wang, XM; Lyu, KJ; Peng, YQ; Zheng, H; Wei, X; Ren, H; Xiao, L; Wang, JB; Muller, DA; Abruña, HD; Hwang, BOE; Lu, JT; Zhuang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ying; Yang, Yao; Jia, Shuangfeng; Wang, Xiaoming; Lyu, Kangjie; Peng, Yanqiu; Zheng, He; Wei, Xing; Ren, Huan; Xiao, Li; Wang, Jianbo; Muller, David A.; Abruna, Hector D.; Hwang, Bing Joe; Lu, Juntao; Zhuang, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Mn-Co catalyst outperforms Pt on high-rate oxygen reduction for alkaline polymer electrolyte fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkaline polymer electrolyte fuel cells are a class of fuel cells that enable the use of non-precious metal catalysts, particularly for the oxygen reduction reaction at the cathode. While there have been alternative materials exhibiting Pt-comparable activity in alkaline solutions, to the best of our knowledge none have outperformed Pt in fuel-cell tests. Here we report a Mn-Co spinel cathode that can deliver greater power, at high current densities, than a Pt cathode. The power density of the cell employing the Mn-Co cathode reaches 1.1 W cm(-2) at 2.5 A cm(-2) at 60 degrees C. Moreover, this catalyst outperforms Pt at low humidity. In-depth characterization reveals that the remarkable performance originates from synergistic effects where the Mn sites bind O-2 and the Co sites activate H2O, so as to facilitate the proton-coupled electron transfer processes. Such an electrocatalytic synergy is pivotal to the high-rate oxygen reduction, particularly under water depletion/low humidity conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1506, "DOI": "10.1038/s41467-019-09503-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09503-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463170600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jing, Y; Ma, YD; Li, YF; Heine, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jing, Yu; Ma, Yandong; Li, Yafei; Heine, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "GeP3: A Small Indirect Band Gap 2D Crystal with High Carrier Mobility and Strong Interlayer Quantum Confinement", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a two-dimensional crystal that possesses low indirect band gaps of 0.55 eV (monolayer) and 0.43 eV (bilayer) and high carrier mobilities similar to those of phosphorene, GeP3. GeP3 has a stable three-dimensional layered bulk counterpart, which is metallic and known from experiment since 1970. GeP3 monolayer has a calculated cleavage energy of 1.14 J m(-2), which suggests exfoliation of bulk material as viable means for the preparation of mono- and few-layer materials. The material shows strong interlayer quantum confinement effects, resulting in a band gap reduction from mono- to bilayer, and then to a semiconductor-metal transition between bi- and triple layer. Under biaxial strain, the indirect band gap can be turned into a direct one. Pronounced light absorption in the spectral range from similar to 600 to 1400 nm is predicted for monolayer and bilayer and promises applications in photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1833, "End Page": 1838, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b05143", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b05143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396185800075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarycheva, A; Polemi, A; Liu, YL; Dandekar, K; Anasori, B; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarycheva, Asia; Polemi, Alessia; Liu, Yucliao; Dandekar, Kapil; Anasori, Babak; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D titanium carbide (MXene) for wireless communication", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the development of the Internet of Things (IoT), the demand for thin and wearable electronic devices is growing quickly. The essential part of the IoT is communication between devices, which requires radio-frequency (RF) antennas. Metals are widely used for antennas; however, their bulkiness limits the fabrication of thin, lightweight, and flexible antennas. Recently, nullomaterials such as graphene, carbon nullotubes, and conductive polymers came into play. However, poor conductivity limits their use. We show RF devices for wireless communication based on metallic two-dimensional (2D) titaniumcarbide (MXene) prepared by a single-step spray coating. We fabricated a similar to 100-nm-thick translucent MXene antenna with a reflection coefficient of less than -10 dB. By increasing the antenna thickness to 8 mm, we achieved a reflection coefficient of -65 dB. We also fabricated a 1-mu m-thick MXene RF identification device tag reaching a reading distance of 8 m at 860 MHz. Our finding shows that 2D titanium carbide MXene operates below the skin depth of copper or other metals as well as offers an opportunity to produce transparent antennas. Being the most conductive, as well as water-dispersible, among solution-processed 2Dmaterials, MXenes open new avenues for manufacturing various classes of RF and other portable, flexible, and wearable electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau0920", "DOI": "10.1126/sciadv.aau0920", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau0920", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449224000054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, B; Cao, XX; Pan, AQ; Luo, ZG; Dinesh, S; Lin, JD; Tang, Y; Liang, SQ; Cao, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Bo; Cao, Xinxin; Pan, Anqiang; Luo, Zhigao; Dinesh, Selvakumaran; Lin, Jiande; Tang, Yan; Liang, Shuquan; Cao, Guozhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encapsulation of CoSx nullocrystals into N/S Co-Doped Honeycomb-Like 3D Porous Carbon for High-Performance Lithium Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A honeycomb-like 3D N/S co-doped porous carbon-coated cobalt sulfide (CoS, Co9S8, and Co1-xS) composite (CS@PC) is successfully prepared using polyacrylonitrile (PAN) as the nitrogen-containing carbon source through a facile solvothermal method and subsequent in situ conversion. As an anode for lithium-ion batteries (LIBs), the CS@PC composite exhibits excellent electrochemical performance, including high reversible capacity, good rate capability, and cyclic stability. The composite electrode delivers specific capacities of 781.2 and 466.0 mAh g(-1) at 0.1 and 5 A g(-1), respectively. When cycled at a current density of 1 A g(-1), it displays a high reversible capacity of 717.0 mAh g(-1) after 500 cycles. The ability to provide this level of performance is attributed to the unique 3D multi-level porous architecture with large electrode-electrolyte contact area, bicontinuous electron/ion transport pathways, and attractive structure stability. Such micro-/nulloscale design and engineering strategies may also be used to explore other nullocomposites to boost their energy storage performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800829, "DOI": "10.1002/advs.201800829", "DOI Link": "http://dx.doi.org/10.1002/advs.201800829", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444940600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CY; Cai, XY; Qian, Y; Jiang, HF; Zhou, LJ; Li, BS; Lai, LF; Shen, ZX; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chunyan; Cai, Xiaoyi; Qian, Yao; Jiang, Haifeng; Zhou, Lijun; Li, Baosheng; Lai, Linfei; Shen, Zexiang; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically Synthesis of Nickel Cobalt Sulfide for High-Performance Flexible Asymmetric Supercapacitors", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A lightweight, flexible, and highly efficient energy management strategy is highly desirable for flexible electronic devices to meet a rapidly growing demand. Herein, Ni-Co-S nullosheet array is successfully deposited on graphene foam (Ni-Co-S/GF) by a one-step electrochemical method. The Ni-Co-S/GF composed of Ni-Co-S nullosheet array which is vertically aligned to GF and provides a large interfacial area for redox reactions with optimum interstitials facilitates the ions diffusion. The Ni-Co-S/GF electrodes have high specific capacitance values of 2918 and 2364 F g(-1) at current densities of 1 and 20 A g(-1), respectively. Using such hierarchical Ni-Co-S/GF as the cathode, a flexible asymmetric supercapacitor (ASC) is further fabricated with polypyrrple(PPy)/GF as the anode. The flexible asymmetric supercapacitors have maximum operation potential window of 1.65 V, and energy densities of 79.3 and 37.7 Wh kg(-1) when the power densities are 825.0 and 16100 W kg(-1), respectively. It's worth nothing that the ASC cells have robust flexibility with performance well maintained when the devices were bent to different angles from 180 degrees to 15 degrees at a duration of 5 min. The efficient electrochemical deposition method of Ni-Co-S with a preferred orientation of nullosheet arrays is applicable for the flexible energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700375, "DOI": "10.1002/advs.201700375", "DOI Link": "http://dx.doi.org/10.1002/advs.201700375", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426200000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wood, KN; Kazyak, E; Chadwick, AF; Chen, KH; Zhang, JG; Thornton, K; Dasgupta, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wood, Kevin N.; Kazyak, Eric; Chadwick, Alexander F.; Chen, Kuan-Hung; Zhang, Ji-Guang; Thornton, Katsuyo; Dasgupta, Neil P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dendrites and Pits: Untangling the Complex Behavior of Lithium Metal Anodes through Operando Video Microscopy", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enabling ultra-high energy density rechargeable Li batteries would have widespread impact on society. However the critical challenges of Li metal anodes (most notably cycle life and safety) remain unsolved. This is attributed to the evolution of Li metal morphology during cycling, which leads to dendrite growth and surface pitting. Herein, we present a comprehensive understanding of the voltage variations observed during Li metal cycling, which is directly correlated to morphology evolution through the use of operando video microscopy. A custom-designed visualization cell was developed to enable operando synchronized observation of Li metal electrode morphology and electrochemical behavior during cycling. A mechanistic understanding of the complex behavior of these electrodes is gained through correlation with continuum-scale modeling, which provides insight into the dominullt surface kinetics. This work provides a detailed explanation of (1) when dendrite nucleation occurs, (2) how those dendrites evolve as a function of time, (3) when surface pitting occurs during Li electrodissolution, (4) kinetic parameters that dictate overpotential as the electrode morphology evolves, and (5) how this understanding can be applied to evaluate electrode performance in a variety of electrolytes. The results provide detailed insight into the interplay between morphology and the dominullt electrochemical processes occurring on the Li electrode surface through an improved understanding of changes in cell voltage, which represents a powerful new platform for analysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 734, "Times Cited, All Databases": 822, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2016, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 790, "End Page": 801, "Article Number": null, "DOI": "10.1021/acscentsci.6b00260", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.6b00260", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390864600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maher, BA; Ahmed, IAM; Karloukovski, V; MacLaren, DA; Foulds, PG; Allsop, D; Mann, DMA; Torres-Jardón, R; Calderon-Garciduenas, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maher, Barbara A.; Ahmed, Imad A. M.; Karloukovski, Vassil; MacLaren, Donald A.; Foulds, Penelope G.; Allsop, David; Mann, David M. A.; Torres-Jardon, Ricardo; Calderon-Garciduenas, Lilian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetite pollution nulloparticles in the human brain", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biologically formed nulloparticles of the strongly magnetic mineral, magnetite, were first detected in the human brain over 20 y ago [Kirschvink JL, Kobayashi-Kirschvink A, Woodford BJ (1992) Proc Natl Acad Sci USA 89(16):7683-7687]. Magnetite can have potentially large impacts on the brain due to its unique combination of redox activity, surface charge, and strongly magnetic behavior. We used magnetic analyses and electron microscopy to identify the abundant presence in the brain of magnetite nulloparticles that are consistent with high-temperature formation, suggesting, therefore, an external, not internal, source. Comprising a separate nulloparticle population from the euhedral particles ascribed to endogenous sources, these brain magnetites are often found with other transition metal nulloparticles, and they display rounded crystal morphologies and fused surface textures, reflecting crystallization upon cooling from an initially heated, iron-bearing source material. Such high-temperature magnetite nullospheres are ubiquitous and abundant in airborne particulate matter pollution. They arise as combustion-derived, iron-rich particles, often associated with other transition metal particles, which condense and/or oxidize upon airborne release. Those magnetite pollutant particles which are", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 720, "Times Cited, All Databases": 775, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2016, "Volume": 113, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10797, "End Page": 10801, "Article Number": null, "DOI": "10.1073/pnas.1605941113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1605941113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383954700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noh, HJ; Jeong, J; Cho, EJ; Kim, K; Min, BI; Park, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noh, Han-Jin; Jeong, Jinwon; Cho, En-Jin; Kim, Kyoo; Min, B. I.; Park, Byeong-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Realization of Type-II Dirac Fermions in a PdTe2 Superconductor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Dirac fermion in a topological Dirac semimetal is a quadruple-degenerate quasiparticle state with a relativistic linear dispersion. Breaking either time-reversal or inversion symmetry turns this system into a Weyl semimetal that hosts double-degenerate Weyl fermion states with opposite chiralities. These two kinds of quasiparticles, although described by a relativistic Dirac equation, do not necessarily obey Lorentz invariance, allowing the existence of so-called type-II fermions. The recent theoretical discovery of type-II Weyl fermions evokes the prediction of type-II Dirac fermions in PtSe2-type transition metal dichalco-genides, expecting experimental confirmation. Here, we report an experimental realization of type-II Dirac fermions in PdTe2 by angle-resolved photoemission spectroscopy combined with ab initio band calculations. Our experimental finding shows the first example that has both superconductivity and type-II Dirac fermions, which turns the topological material research into a new phase.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2017, "Volume": 119, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16401, "DOI": "10.1103/PhysRevLett.119.016401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.016401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428176300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, L; Patankar, S; Morimoto, T; Nair, NL; Thewalt, E; Little, A; Analytis, JG; Moore, JE; Orenstein, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Liang; Patankar, S.; Morimoto, T.; Nair, N. L.; Thewalt, E.; Little, A.; Analytis, J. G.; Moore, J. E.; Orenstein, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant anisotropic nonlinear optical response in transition metal monopnictideWeyl semimetals", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although Weyl fermions have proven elusive in high-energy physics, their existence as emergent quasiparticles has been predicted in certain crystalline solids in which either inversion or time-reversal symmetry is broken(1-4). Recently they have been observed in transition metal monopnictides (TMMPs) such as TaAs, a class of noncentrosymmetric materials that heretofore received only limited attention(5-7). The question that arises now is whether these materials will exhibit novel, enhanced, or technologically applicable electronic properties. The TMMPs are polar metals, a rare subset of inversion-breaking crystals that would allow spontaneous polarization, were it not screened by conduction electrons(8-10). Despite the absence of spontaneous polarization, polar metals can exhibit other signatures of inversion-symmetry breaking, most notably second-order nonlinear optical polarizability, chi((2)), leading to phenomena such as optical rectification and second-harmonic generation (SHG). Here we report measurements of SHG that reveal a giant, anisotropic chi((2)) in the TMMPs TaAs, TaP and NbAs. With the fundamental and second-harmonic fields oriented parallel to the polar axis, the value of chi((2)) is larger by almost one order of magnitude than its value in the archetypal electro-optic materials GaAs11 and ZnTe12, and in fact larger than reported in any crystal to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 350, "End Page": 355, "Article Number": null, "DOI": "10.1038/NPHYS3969", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3969", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398262900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, JQ; Yang, QG; Oh, J; Chen, SS; Odunmbaku, GO; Ouedraogo, null; Yang, C; Sun, K; Lu, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Jianqiang; Yang, Qianguang; Oh, Jiyeon; Chen, Shanshan; Odunmbaku, George Omololu; Ouedraogo, Nabonswende Aida Nadege; Yang, Changduk; Sun, Kuan; Lu, Shirong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Volatile Solid Additive-Assisted Sequential Deposition Enables 18.42% Efficiency in Organic Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Morphology optimization of active layer plays a critical role in improving the performance of organic solar cells (OSCs). In this work, a volatile solid additive-assisted sequential deposition (SD) strategy is reported to regulate the molecular order and phase separation in solid state. The OSC adopts polymer donor D18-Cl and acceptor N3 as active layer, as well as 1,4-diiodobenzene (DIB) as volatile additive. Compared to the D18-Cl:N3 (one-time deposition of mixture) and D18-Cl/N3 (SD) platforms, the D18-Cl/N3(DIB) device based on DIB-assisted SD method exhibits a finer phase separation with greatly enhanced molecular crystallinity. The optimal morphology delivers superior charge transport and extraction, offering a champion power conversion efficiency of 18.42% with significantly enhanced short-circuit current density (J(sc)) of 27.18 mA cm(-2) and fill factor of 78.8%. This is one of the best performances in binary SD OSCs to date. Angle-dependent grazing-incidence wide-angle X-ray scattering technique effectively reveals the vertical phase separation and molecular crystallinity of the active layer. This work demonstrates the combination of volatile solid additive and sequential deposition is an effective method to develop high-performance OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105347, "DOI": "10.1002/advs.202105347", "DOI Link": "http://dx.doi.org/10.1002/advs.202105347", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745984400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, MY; Tang, H; Wu, JB; Song, WH; Zhang, MX; Yin, WB; Zhuo, Y; Kiani, F; Chen, BJM; Jiang, XQ; Liu, HF; Chen, HY; Midya, R; Ye, F; Jiang, H; Wang, ZR; Wu, MC; Hu, M; Wang, H; Xia, QF; Ge, N; Li, J; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Mingyi; Tang, Hao; Wu, Jiangbin; Song, Wenhao; Zhang, Max; Yin, Wenbo; Zhuo, Ye; Kiani, Fatemeh; Chen, Benjamin; Jiang, Xiangqi; Liu, Hefei; Chen, Hung-Yu; Midya, Rivu; Ye, Fan; Jiang, Hao; Wang, Zhongrui; Wu, Mingche; Hu, Miao; Wang, Han; Xia, Qiangfei; Ge, Ning; Li, Ju; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thousands of conductance levels in memristors integrated on CMOS", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neural networks based on memristive devices(1-3) have the ability to improve throughput and energy efficiency for machine learning(4,5) and artificial intelligence(6), especially in edge applications(7-21). Because training a neural network model from scratch is costly in terms of hardware resources, time and energy, it is impractical to do it individually on billions of memristive neural networks distributed at the edge. A practical approach would be to download the synaptic weights obtained from the cloud training and program them directly into memristors for the commercialization of edge applications. Some post-tuning in memristor conductance could be done afterwards or during applications to adapt to specific situations. Therefore, in neural network applications, memristors require high-precision programmability to guarantee uniform and accurate performance across a large number of memristive networks(22-28). This requires many distinguishable conductance levels on each memristive device, not only laboratory-made devices but also devices fabricated in factories. Analog memristors with many conductance states also benefit other applications, such as neural network training, scientific computing and even `mortal computing'(25,29,30.) Here we report 2,048 conductance levels achieved with memristors in fully integrated chips with 256 x 256 memristor arrays monolithically integrated on complementary metal-oxide-semiconductor (CMOS) circuits in a commercial foundry. We have identified the underlying physics that previously limited the number of conductance levels that could be achieved in memristors and developed electrical operation protocols to avoid such limitations. These results provide insights into the fundamental understanding of the microscopic picture of memristive switching as well as approaches to enable high-precision memristors for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2023, "Volume": 615, "Issue": 7954, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 823, "End Page": 829, "Article Number": null, "DOI": "10.1038/s41586-023-05759-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05759-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961772700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, RJ; Gan, XT; Li, C; Chen, XQ; Hu, SQ; Gu, LP; Van Thourhout, D; Castellanos-Gomez, A; Sun, ZP; Zhao, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Ruijuan; Gan, Xuetao; Li, Chen; Chen, Xiaoqing; Hu, Siqi; Gu, Linpeng; van Thourhout, Dries; Castellanos-Gomez, Andres; Sun, Zhipei; Zhao, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chip-integrated van der Waals PN heterojunction photodetector with low dark current and high responsivity", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials are attractive for constructing high-performance photonic chip-integrated photodetectors because of their remarkable electronic and optical properties and dangling-bond-free surfaces. However, the reported chip-integrated two-dimensional material photodetectors were mainly implemented with the configuration of metal-semiconductor-metal, suffering from high dark currents and low responsivities at high operation speed. Here, we report a van der Waals PN heterojunction photodetector, composed of p-type black phosphorous and n-type molybdenum telluride, integrated on a silicon nitride waveguide. The built-in electric field of the PN heterojunction significantly suppresses the dark current and improves the responsivity. Under a bias of 1 V pointing from n-type molybdenum telluride to p-type black phosphorous, the dark current is lower than 7 nA, which is more than two orders of magnitude lower than those reported in other waveguide-integrated black phosphorus photodetectors. An intrinsic responsivity up to 577 mA W-1 is obtained. Remarkably, the van der Waals PN heterojunction is tunable by the electrostatic doping to further engineer its rectification and improve the photodetection, enabling an increased responsivity of 709 mA W-1. Besides, the heterojunction photodetector exhibits a response bandwidth of similar to 1.0 GHz and a uniform photodetection over a wide spectral range, as experimentally measured from 1500 to 1630 nm. The demonstrated chip-integrated van der Waals PN heterojunction photodetector with low dark current, high responsivity and fast response has great potentials to develop high-performance on-chip photodetectors for various photonic integrated circuits based on silicon, lithium niobate, polymer, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101, "DOI": "10.1038/s41377-022-00784-x", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00784-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784993900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TX; Wang, SD; Fan, WX; Lu, YP; Wang, TM; Li, TJ; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tianxin; Wang, Shudao; Fan, Wenxue; Lu, Yiping; Wang, Tongmin; Li, Tingju; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CALPHAD-aided design for superior thermal stability and mechanical behavior in a TiZrHfNb refractory high-entropy alloy", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TiZrHfNbTa refractory high-entropy alloys (RHEAs) are now at the research frontier of advanced metallic ma-terials due to their exceptional mechanical performance, particularly at high temperatures. However, the TiZrHfNbTa RHEAs exhibit poor phase stability at intermediate temperatures (600 - 1,000 degrees C). The present study aimed to tailor their phase stability and mechanical properties via the calculation of phase diagrams (CALPHAD) approach. We found that Ta and Hf were detrimental to the phase stability of the TiZrHfNbTa RHEAs. Accordingly, a Ta-free and Hf-depleted Ti30Zr30Hf16Nb24 RHEA with outstanding phase stability was designed, which could remain a single-phase body-centered cubic (BCC) structure after annealing at 600 degrees C for 200 h. Furthermore, numerous (Ti, Zr)-rich nullo-precipitates were dispersedly formed in the cold-rolled plus recrystallization-annealed (CR+A) Ti30Zr30Hf16Nb24 RHEA. The nullo-precipitates controlled by the spinodal decomposition mechanism had an identical BCC lattice. The lattice fringes with (110) Miller indices bent from the matrix phase to the nullo-precipitates, causing a strong local strain field near the phase boundaries. The CR+A alloy possessed a yield strength of -800 MPa and tensile fracture elongation of -34.0%, showing a superior strength-ductility combination. The strain measurement by a digital image correlation indicated that the CR+A alloy exhibited a more substantial plastic stability than the as-cast alloy. Detailed observations of deformation microstructures through a transmission electron microscope and electron back-scattered diffraction revealed the origin of strength and ductility. Dislocation cross-slip and kink bands tended to form in the CR+A alloy during deformation and were capable of accommodating dislocation slip against stress concentration. Labusch's model uncovered that solid-solution strengthening contributed the most to yield strength. The present study provides a paradigm for the superior thermostability and controllable nullophase-precipitation behavior in RHEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 246, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118728, "DOI": "10.1016/j.actamat.2023.118728", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2023.118728", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965302100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, W; Li, RZ; Zhang, ST; Liu, YL; Wang, NN; Cao, Y; Miao, YF; Xu, MM; Guo, Q; Di, DW; Zhang, L; Yi, C; Gao, F; Friend, RH; Wang, JP; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Wei; Li, Renzhi; Zhang, Shuting; Liu, Yunlong; Wang, nulla; Cao, Yu; Miao, Yanfeng; Xu, Mengmeng; Guo, Qiang; Di, Dawei; Zhang, Li; Yi, Chang; Gao, Feng; Friend, Richard H.; Wang, Jianpu; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimising efficiency roll-off in high-brightness perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficiency roll-off is a major issue for most types of light-emitting diodes (LEDs), and its origins remain controversial. Here we present investigations of the efficiency roll-off in perovskite LEDs based on two-dimensional layered perovskites. By simultaneously measuring electroluminescence and photoluminescence on a working device, supported by transient photoluminescence decay measurements, we conclude that the efficiency roll-off in perovskite LEDs is mainly due to luminescence quenching which is likely caused by non-radiative Auger recombination. This detrimental effect can be suppressed by increasing the width of quantum wells, which can be easily realized in the layered perovskites by tuning the ratio of large and small organic cations in the precursor solution. This approach leads to the realization of a perovskite LED with a record external quantum efficiency of 12.7%, and the efficiency remains to be high, at approximately 10%, under a high current density of 500 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 608, "DOI": "10.1038/s41467-018-03049-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03049-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424641200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Wang, DD; Zhong, Y; Jiang, F; Zhao, DQ; Sun, SQ; Lu, P; Lu, M; Wang, ZY; Wu, ZN; Gao, YB; Zhang, Y; Yu, WW; Bai, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xin; Wang, Dingdi; Zhong, Yuan; Jiang, Feng; Zhao, Deqiang; Sun, Siqi; Lu, Po; Lu, Min; Wang, Zhenyu; Wu, Zhennull; Gao, Yanbo; Zhang, Yu; Yu, William W. W.; Bai, Xue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halide Double Perovskite nullocrystals Doped with Rare-Earth Ions for Multifunctional Applications", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most lead-free halide double perovskite materials display low photoluminescence quantum yield (PLQY) due to the indirect bandgap or forbidden transition. Doping is an effective strategy to tailor the optical properties of materials. Herein, efficient blue-emitting Sb3+-doped Cs2NaInCl6 nullocrystals (NCs) are selected as host, rare-earth (RE) ions (Sm3+, Eu3+, Tb3+, and Dy3+) are incorporated into the host, and excellent PLQY of 80.1% is obtained. Femtosecond transient absorption measurement found that RE ions not only served as the activator ions but also filled the deep vacancy defects. Anti-counterfeiting, optical thermometry, and white-light-emitting diodes (WLEDs) are exhibited using these RE ions-doped halide double perovskite NCs. For the optical thermometry based on Sm3+-doped Cs2NaInCl6:Sb3+ NCs, the maximum relative sensitivity is 0.753% K-1, which is higher than those of most temperature-sensing materials. Moreover, the WLED fabricated by Sm3+-doped Cs2NaInCl6:Sb3+ NCs@PMMA displays CIE color coordinates of (0.30, 0.28), a luminous efficiency of 37.5 lm W-1, a CCT of 8035 K, and a CRI over 80, which indicate that Sm3+-doped Cs2NaInCl6:Sb3+ NCs are promising single-component white-light-emitting phosphors for next-generation lighting and display technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207571", "DOI Link": "http://dx.doi.org/10.1002/advs.202207571", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000976064800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, K; Wang, JY; Zhao, SQ; Zhou, D; Sun, B; Cui, Y; Wang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Kang; Wang, Jiangyan; Zhao, Shuoqing; Zhou, Dong; Sun, Bing; Cui, Yi; Wang, Guoxiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-dependent Nucleation and Growth of Dendrite-Free Lithium Metal Anodes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is essential to develop a facile and effective method to enhance the electrochemical performance of lithium metal anodes for building high-energy-density Li-metal based batteries. Herein, we explored the temperature-dependent Li nucleation and growth behavior and constructed a dendrite-free Li metal anode by elevating temperature from room temperature (20 degrees C) to 60 degrees C. A series of ex situ and in situ microscopy investigations demonstrate that increasing Li deposition temperature results in large nuclei size, low nucleation density, and compact growth of Li metal. We reveal that the enhanced lithiophilicity and the increased Li-ion diffusion coefficient in aprotic electrolytes at high temperature are essential factors contributing to the dendrite-free Li growth behavior. As anodes in both half cells and full cells, the compact deposited Li with minimized specific surface area delivered high Coulombic efficiencies and long cycling stability at 60 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2019, "Volume": 58, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11364, "End Page": 11368, "Article Number": null, "DOI": "10.1002/anie.201905251", "DOI Link": "http://dx.doi.org/10.1002/anie.201905251", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477333300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, G; Han, X; Cai, JY; Yin, PQ; Cui, PX; Zheng, XS; Li, H; Chen, C; Wang, GM; Hong, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Geng; Han, Xiao; Cai, Jinyan; Yin, Peiqun; Cui, Peixin; Zheng, Xusheng; Li, Hai; Chen, Cai; Wang, Gongming; Hong, Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-plane strain engineering in ultrathin noble metal nullosheets boosts the intrinsic electrocatalytic hydrogen evolution activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While inducing strain to noble metal nullomaterials can modulate catalytic activities, the strain is often spatially dependent. Here, authors manipulate the planar strain in noble metal nullosheets for hydrogen evolution electrocatalysis by constructing amorphous-crystalline phase boundaries. Strain has been shown to modulate the electronic structure of noble metal nullomaterials and alter their catalytic performances. Since strain is spatially dependent, it is challenging to expose the active strained interfaces by structural engineering with atomic precision. Herein, we report a facile method to manipulate the planar strain in ultrathin noble metal nullosheets by constructing amorphous-crystalline phase boundaries that can expose the active strained interfaces. Geometric-phase analysis and electron diffraction profile demonstrate the in-plane amorphous-crystalline boundaries can induce about 4% surface tensile strain in the nullosheets. The strained Ir nullosheets display substantially enhanced intrinsic activity toward the hydrogen evolution reaction electrocatalysis with a turnover frequency value 4.5-fold higher than the benchmark Pt/C catalyst. Density functional theory calculations verify that the tensile strain optimizes the d-band states and hydrogen adsorption properties of the strained Ir nullosheets to improve catalysis. Furthermore, the in-plane strain engineering method is demonstrated to be a general approach to boost the hydrogen evolution performance of Ru and Rh nullosheets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4200, "DOI": "10.1038/s41467-022-31971-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31971-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828281800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, F; Ding, L; Zhang, L; Monticone, F; Chum, CC; Deng, J; Mei, ST; Li, Y; Teng, JH; Hong, MH; Zhang, S; Alu, A; Qiu, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Fei; Ding, Lu; Zhang, Lei; Monticone, Francesco; Chum, Chan Choy; Deng, Jie; Mei, Shengtao; Li, Ying; Teng, Jinghua; Hong, Minghui; Zhang, Shuang; Alu, Andrea; Qiu, Cheng-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid bilayer plasmonic metasurface efficiently manipulates visible light", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces operating in the cross-polarization scheme have shown an interesting degree of control over the wavefront of transmitted light. Nevertheless, their inherently low efficiency in visible light raises certain concerns for practical applications. Without sacrificing the ultrathin flat design, we propose a bilayer plasmonic metasurface operating at visible frequencies, obtained by coupling a nulloantenna-based metasurface with its complementary Babinet-inverted copy. By breaking the radiation symmetry because of the finite, yet small, thickness of the proposed structure and benefitting from properly tailored intra- and interlayer couplings, such coupled bilayer metasurface experimentally yields a conversion efficiency of 17%, significantly larger than that of earlier single-layer designs, as well as an extinction ratio larger than 0 dB, meaning that anomalous refraction dominates the transmission response. Our finding shows that metallic metasurface can counterintuitively manipulate the visible light as efficiently as dielectric metasurface (similar to 20% in conversion efficiency in Lin et al.'s study), although the metal's ohmic loss is much higher than dielectrics. Our hybrid bilayer design, still being ultrathin (similar to lambda/6), is found to obey generalized Snell's law even in the presence of strong couplings. It is capable of efficiently manipulating visible light over a broad bandwidth and can be realized with a facile one-step nullofabrication process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501168", "DOI": "10.1126/sciadv.1501168", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376972900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, JJ; Chen, WX; He, DS; Wan, JW; Pei, JJ; Dong, JC; Wang, Y; An, PF; Jin, Z; Xing, W; Tang, HL; Zhuang, ZB; Liang, X; Huang, Y; Zhou, G; Wang, LY; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Junjie; Chen, Wenxing; He, Dongsheng; Wan, Jiawei; Pei, Jiajing; Dong, Juncai; Wang, Yu; An, Pengfei; Jin, Zhao; Xing, Wei; Tang, Haolin; Zhuang, Zhongbin; Liang, Xin; Huang, Yu; Zhou, Gang; Wang, Leyu; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of ultrathin Pt-Mo-Ni nullowire catalysts for ethanol electrooxidation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing cost-effective, active, and durable electrocatalysts is one of the most important issues for the commercialization of fuel cells. Ultrathin Pt-Mo-Ni nullowires (NWs) with a diameter of similar to 2.5 nm and lengths of up to several micro-meters were synthesized via a H-2-assisted solution route (HASR). This catalyst was designed on the basis of the following three points: (i) ultrathin NWs with high numbers of surface atoms can increase the atomic efficiency of Pt and thus decrease the catalyst cost; (ii) the incorporation of Ni can isolate Pt atoms on the surface and produce surface defects, leading to high catalytic activity (the unique structure and superior activity were confirmed by spherical aberration-corrected electron microscopy measurements and ethanol oxidation tests, respectively); and (iii) the incorporation of Mo can stabilize both Ni and Pt atoms, leading to high catalytic stability, which was confirmed by experiments and density functional theory calculations. Furthermore, the developed HASR strategy can be extended to synthesize a series of Pt-Mo-M (M = Fe, Co, Mn, Ru, etc.) NWs. These multimetallic NWs would open up new opportunities for practical fuel cell applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1603068", "DOI": "10.1126/sciadv.1603068", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603068", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411589900071", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, C; Ma, HS; Wang, ZY; Younis, MR; Liu, CY; Wu, CT; Luo, YX; Huang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chen; Ma, Hongshi; Wang, Zhiyong; Younis, Muhammad Rizwan; Liu, Chunyang; Wu, Chengtie; Luo, Yongxiang; Huang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Wesselsite nullosheets Functionalized Scaffold Facilitates NIR-II Photothermal Therapy and Vascularized Bone Regeneration", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various bifunctional scaffolds have recently been developed to address the reconstruction of tumor-initiated bone defects. Such scaffolds are usually composed of a near-infrared (NIR) photothermal conversion agent and a conventional bone scaffold for photothermal therapy (PTT) and long-term bone regeneration. However, the reported photothermal conversion agents are mainly restricted to the first biological window (NIR-I) with intrinsic poor tissue penetration depth. Also, most of these agents are non-bioactive materials, which induced potential systemic side toxicity after implantation. Herein, a NIR-II photothermal conversion agent (Wesselsite [SrCuSi4O10] nullosheets, SC NSs) with tremendous osteogenic and angiogenic bioactivity, is rationally integrated with polycaprolactone (PCL) via 3D printing. The as-designed 3D composite scaffolds not only trigger osteosarcoma ablation through NIR-II light generated extensive hyperthermia, but also promote in vitro cellular proliferation and osteogenic differentiation of rat bone marrow mesenchymal stem cells (rBMSCs) and human umbilical vein endothelial cells (HUVECs), respectively, and the ultimate enhancement of vascularized bone regeneration in vivo owing to the controlled and sustained release of bioactive ions (Sr, Cu, and Si). The authors' study provides a new avenue to prepare multifunctional bone scaffolds based on therapeutic bioceramics for repairing tumor-induced bone defects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100894, "DOI": "10.1002/advs.202100894", "DOI Link": "http://dx.doi.org/10.1002/advs.202100894", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000685684100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, WJ; Chen, HY; Xu, GY; Xue, RM; Wang, SH; Li, YW; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Weijie; Chen, Haiyang; Xu, Guiying; Xue, Rongming; Wang, Shuhui; Li, Yaowen; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precise Control of Crystal Growth for Highly Efficient CsPbI2Br Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic perovskite solar cells (pero-SCs) are attracting considerable attention due to their promising thermal stability, but their inferior power-conversion efficiency (PCE) and moisture instability are hindering their application. Here, we used a gradient thermal annealing (GTA) method to control the growth of alpha-CsPbI2Br crystals and then utilized a green anti-solvent (ATS) isopropanol to further optimize the morphology of alpha-CsPbI2Br film. Through this GTA-ATS synergetic effect, the growth of alpha-CsPbI2Br crystals could be precisely controlled, leading to a high-quality perovskite film with one-micron average grain size, low root-mean-square of 25.9 nm, and reduced defect density. Pero-SCs based on this CsPbI2Br film achieved a champion scan PCE of 16.07% (stabilized efficiency of 15.75%), which is the highest efficiency reported in all-inorganic pero-SCs. Moreover, the CsPbI2Br pero-SC demonstrates excellent robustness against moisture and oxygen, and maintains 90% of initial PCE after aging 120 hr under 100 mW/cm(2) UV irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 443, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 191, "End Page": 204, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koshelev, K; Tang, YT; Li, KF; Choi, DY; Li, GX; Kivshart, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koshelev, Kirill; Tang, Yutao; Li, Kingfai; Choi, Duk-Yong; Li, Guixin; Kivshart, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonlinear Metasurfaces Governed by Bound States in the Continuum", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonlinear nullostructured surfaces provide a paradigm shift in nonlinear optics with new ways to control and manipulate frequency conversion processes at the nulloscale, also offering novel opportunities for applications in photonics, chemistry, material science, and biosensing. Here, we develop a general approach to employ sharp resonullces in metasurfaces originated from the physics of bound states in the continuum for both engineering and enhancing the nonlinear response. We study experimentally the third-harmonic generation from metasurfaces composed of symmetry-broken silicon meta-atoms and reveal that the harmonic generation intensity depends critically on the asymmetry parameter. We employ the concept of the critical coupling of light to the metasurface resonullces to uncover the effect of radiative and nonradiative losses on the nonlinear conversion efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1639, "End Page": 1644, "Article Number": null, "DOI": "10.1021/acsphotonics.9b00700", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.9b00700", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476684300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, TT; Elbadawi, C; Totonjian, D; Lobo, CJ; Grosso, G; Moon, H; Englund, DR; Ford, MJ; Aharonovich, I; Toth, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Toan Trong Tran; Elbadawi, Christopher; Totonjian, Daniel; Lobo, Charlene J.; Grosso, Gabriele; Moon, Hyowon; Englund, Dirk R.; Ford, Michael J.; Aharonovich, Igor; Toth, Milos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust Multicolor Single Photon Emission from Point Defects in Hexagonal Boron Nitride", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride (hBN) is an emerging two-dimensional material for quantum photonics owing to its large bandgap and hyperbolic properties. Here we report two approaches for engineering quantum emitters in ISBN multilayers using either electron beam irradiation or annealing and characterize their photophysical properties. The defects exhibit a broad range of multicolor room-temperature single photon emissions across the visible and the near-infrared spectral ranges, narrow line widths of sub-10 nm at room temperature, and a short excited-state lifetime, and high brightness. We show that the emitters can be categorized into two general groups, but most likely possess similar crystallographic structure. Remarkably, the emitters are extremely robust and withstand aggressive annealing treatments in oxidizing and reducing environments. Our results constitute a step toward deterministic engineering of single emitters in 2D materials and hold great promise for the use of defects in boron nitride as sources for quantum information processing and nullophotonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 500, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7331, "End Page": 7338, "Article Number": null, "DOI": "10.1021/acsnullo.6b03602", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b03602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381959100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, TQ; Zhu, WY; Zhang, YH; Xue, QF; Jiao, XC; Wang, ZJ; Xie, YM; Li, P; Chen, RF; Huang, F; Li, Y; Yip, L; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Tianqi; Zhu, Weiya; Zhang, Yiheng; Xue, Qifan; Jiao, Xuechen; Wang, Zijie; Xie, Yue-Min; Li, Ping; Chen, Runfeng; Huang, Fei; Li, Yuan; Yip, Hin-Lap; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "D-A-π-A-D-type Dopant-free Hole Transport Material for Low-Cost, Efficient, and Stable Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-cost and efficient hole transport materials (HTMs) is important for the commercialization of perovskite solar cells (PSCs). Comparing with the widely studied D-A-D and D-pi-D linear-type small molecule HTMs, DTB-FL with a D-A-pi-A-D molecular design is proposed, featuring facile synthesis and excellent optoelectronic properties. Moreover, the HTM with efficient surface passivation effects and proper energy level alignment at the hole extraction interface effectively inhibits recombination loss and improves the charge collection property. As a result, the champion efficiencies of 21.5% and 19.6% for active areas of 0.09 and 1.0 cm(2), respectively, with superior operational stability are achieved by using DTB-FL HTM. In addition, DTB-FL can also be used as efficient HTM for all-inorganic PSCs, producing an impressive PCE of 17.0% with a high V-oc of 1.30 V. These results underscore the promising potential of the D-A-pi-A-D molecular design in preparing low-cost dopant-free HTMs toward stable and efficient PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2021, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 249, "End Page": 269, "Article Number": null, "DOI": "10.1016/j.joule.2020.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.12.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000610121200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, C; Huang, HF; Lu, WY; Wei, ZX; Ni, XY; Sun, F; Qing, P; Liu, ZJ; Ma, JM; Wei, WF; Chen, LB; Yan, CL; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Chen; Huang, Haifeng; Lu, Weiyi; Wei, Zengxi; Ni, Xuyan; Sun, Fu; Qing, Piao; Liu, Zhijian; Ma, Jianmin; Wei, Weifeng; Chen, Libao; Yan, Chenglin; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mg Doped Li-LiB Alloy with In Situ Formed Lithiophilic LiB Skeleton for Lithium Metal Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High energy density lithium metal batteries (LMBs) are promising next-generation energy storage devices. However, the uncontrollable dendrite growth and huge volume change limit their practical applications. Here, a new Mg doped Li-LiB alloy with in situ formed lithiophilic 3D LiB skeleton (hereinafter called Li-B-Mg composite) is presented to suppress Li dendrite and mitigate volume change. The LiB skeleton exhibits superior lithiophilic and conductive characteristics, which contributes to the reduction of the local current density and homogenization of incoming Li+ flux. With the introduction of Mg, the composite achieves an ultralong lithium deposition/dissolution lifespan (500 h, at 0.5 mA cm(-2)) without short circuit in the symmetrical battery. In addition, the electrochemical performance is superior in full batteries assembled with LiCoO2 cathode and the manufactured composite. The currently proposed 3D Li-B-Mg composite anode may significantly propel the advancement of LMB technology from laboratory research to industrial commercialization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902643, "DOI": "10.1002/advs.201902643", "DOI Link": "http://dx.doi.org/10.1002/advs.201902643", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506257800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, G; Pandey, R; Karna, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Gaoxue; Pandey, Ravindra; Karna, Shashi P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically Thin Group V Elemental Films: Theoretical Investigations of Antimonene Allotropes", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Group V elemental monolayers including phosphorene are emerging as promising 2D materials with semiconducting electronic properties. Here, we present the results of first-principles calculations on stability, mechanical and electronic properties of 2D antimony (Sb), antimonene. Our calculations show that free-standing alpha and beta allotropes of antimonene are stable and semiconducting. The a-Sb has a puckered structure with two atomic sublayers and beta-Sb has a buckled hexagonal lattice. The calculated Raman spectra and STM images have distinct features thus facilitating characterization of both allotropes. The beta-Sb has nearly isotropic mechanical properties, whereas alpha-Sb shows strongly anisotropic characteristics. An indirect-direct band gap transition is expected with moderate tensile strains applied to the monolayers, which opens up the possibility of their applications in optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2015, "Volume": 7, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11490, "End Page": 11496, "Article Number": null, "DOI": "10.1021/acsami.5b02441", "DOI Link": "http://dx.doi.org/10.1021/acsami.5b02441", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355891700055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Gutiérrez-Lezama, I; Ubrig, N; Kroner, M; Gibertini, M; Taniguchi, T; Watanabe, K; Imamoglu, A; Giannini, E; Morpurgo, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhe; Gutierrez-Lezama, Ignacio; Ubrig, Nicolas; Kroner, Martin; Gibertini, Marco; Taniguchi, Takashi; Watanabe, Kenji; Imamoglu, Atac; Giannini, Enrico; Morpurgo, Alberto F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic layered van der Waals crystals are an emerging class of materials giving access to new physical phenomena, as illustrated by the recent observation of 2D ferromagnetism in Cr2Ge2Te6 and CrI3. Of particular interest in semiconductors is the interplay between magnetism and transport, which has remained unexplored. Here we report magneto-transport measurements on exfoliated CrI3 crystals. We find that tunneling conduction in the direction perpendicular to the crystalline planes exhibits a magnetoresistance as large as 10,000%. The evolution of the magnetoresistance with magnetic field and temperature reveals that the phenomenon originates from multiple transitions to different magnetic states, whose possible microscopic nature is discussed on the basis of all existing experimental observations. This observed dependence of the conductance of a tunnel barrier on its magnetic state is a phenomenon that demonstrates the presence of a strong coupling between transport and magnetism in magnetic van der Waals semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 748, "Times Cited, All Databases": 802, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2516, "DOI": "10.1038/s41467-018-04953-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04953-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436548700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bates, CM; Bates, FS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bates, Christopher M.; Bates, Frank S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "50th Anniversary Perspective: Block Polymers-Pure Potential", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Block polymers have undergone extraordinary evolution since their inception more than 60 years ago, maturing from simple surfactants to an expansive class of macromolecules encoded with exquisite attributes. Contemporary synthetic accessibility coupled with facile characterization and rigorous theoretical advances have conspired to continuously generate fundamental insights and enabling concepts that target applications spanning chemistry, biology, physics, and engineering. Here, we parse the vast literature to examine the forefront of the field and identify exciting themes and challenging opportunities that portend a bracing future trajectory. This Perspective celebrates the visionary role played by Macromolecules in advancing our understanding of this remarkable class of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 638, "Times Cited, All Databases": 709, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2017, "Volume": 50, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3, "End Page": 22, "Article Number": null, "DOI": "10.1021/acs.macromol.6b02355", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.6b02355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391898000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sangroniz, A; Zhu, JB; Tang, XY; Etxeberria, A; Chen, EYX; Sardon, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sangroniz, Ainara; Zhu, Jian-Bo; Tang, Xiaoyan; Etxeberria, Agustin; Chen, Eugene Y. -X.; Sardon, Haritz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Packaging materials with desired mechanical and barrier properties and full chemical recyclability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics have become indispensable in modern life and the material of choice in packaging applications, but they have also caused increasing plastic waste accumulation in oceans and landfills. Although there have been continuous efforts to develop biodegradable plastics, the mechanical and/or transport properties of these materials still need to be significantly improved to be suitable for replacing conventional plastic packaging materials. Here we report a class of biorenewable and degradable plastics, based on copolymers of gamma-butyrolactone and its ring- fused derivative, with competitive permeability and elongation at break compared to commodity polymers and superior mechanical and transport properties to those of most promising biobased plastics. Importantly, these materials are designed with full chemical recyclability built into their performance with desired mechanical and barrier properties, thus representing a circular economy approach to plastic packaging materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3559, "DOI": "10.1038/s41467-019-11525-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11525-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479188700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, HH; Wu, S; Ayvali, T; Zheng, J; Fellowes, J; Ho, PL; Leung, KC; Large, A; Held, G; Kato, R; Suenaga, K; Reyes, YIA; Thang, HV; Chen, HYT; Tsang, SCE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Huihuang; Wu, Simson; Ayvali, Tugce; Zheng, Jianwei; Fellowes, Joshua; Ho, Ping-Luen; Leung, Kwan Chee; Large, Alexander; Held, Georg; Kato, Ryuichi; Suenaga, Kazu; Reyes, Yves Ira A.; Thang, Ho Viet; Chen, Hsin-Yi Tiffany; Tsang, Shik Chi Edman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dispersed surface Ru ensembles on MgO(111) for catalytic ammonia decomposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia is regarded as an energy vector for hydrogen storage, transport and utilization, which links to usage of renewable energies. However, efficient catalysts for ammonia decomposition and their underlying mechanism yet remain obscure. Here we report that atomically-dispersed Ru atoms on MgO support on its polar (111) facets {denoted as MgO(111)} show the highest rate of ammonia decomposition, as far as we are aware, than all catalysts reported in literature due to the strong metal-support interaction and efficient surface coupling reaction. We have carefully investigated the loading effect of Ru from atomic form to cluster/nulloparticle on MgO(111). Progressive increase of surface Ru concentration, correlated with increase in specific activity per metal site, clearly indicates synergistic metal sites in close proximity, akin to those bimetallic N-2 complexes in solution are required for the stepwise dehydrogenation of ammonia to N-2/H-2, as also supported by DFT modelling. Whereas, beyond surface doping, the specific activity drops substantially upon the formation of Ru cluster/nulloparticle, which challenges the classical view of allegorically higher activity of coordinated Ru atoms in cluster form (B-5 sites) than isolated sites. Ruthenium-based materials show promising performance for ammonia decomposition, yet the underlying mechanism remains to be further explored. Here the authors investigate atomically dispersed Ru atoms on polar (111) on MgO facets to show synergistic metal sites in close proximity are required for the stepwise dehydrogenation of ammonia to N2/H2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-36339-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36339-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954587000032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cousins, DS; Suzuki, Y; Murray, RE; Samaniuk, JR; Stebner, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cousins, Dylan S.; Suzuki, Yasuhito; Murray, Robynne E.; Samaniuk, Joseph R.; Stebner, Aaron P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling glass fiber thermoplastic composites from wind turbine blades", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoplastic resin systems have long been discussed for use in large-scale composite parts but have yet to be exploited by the energy industry. The use of these resins versus their thermosetting counterparts can potentially introduce cost savings due to non-heated tooling, shorter manufacturing cycle times, and recovery of raw materials from the retired part. Because composite parts have high embedded energy, recovery of their constituent materials can provide substantial economic benefit. This study determines the feasibility of recycling composite wind turbine blade components that are fabricated with glass fiber reinforced Elium (R) thermoplastic resin. Several experiments are conducted to tabulate important material properties that are relevant to recycling, including thermal degradation, grinding, and dissolution of the polymer matrix to recover the constituent materials. Dissolution, which is a process unique to thermoplastic matrices, allows recovery of both the polymer matrix and full-length glass fibers, which maintain their stiffness (190 N/(mm g)) and strength (160 N/g) through the recovery process. Injection molded regrind material is stiffer (12 GPa compared to 10 GPa) and stronger (150 MPa compared to 84 MPa) than virgin material that had shorter fibers. An economic analysis of the technical data shows that recycling thermoplastic-glass fiber composites via dissolution into their constituent parts is commercially feasible under certain conditions. This analysis concludes that 50% of the glass fiber must be recovered and resold for a price of $0.28/kg. Additionally, 90% of the resin must be recovered and resold at a price of $2.50/kg. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 209, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1252, "End Page": 1263, "Article Number": null, "DOI": "10.1016/j.jclepro.2018.10.286", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2018.10.286", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457351900103", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goyanes, A; Det-Amornrat, U; Wang, J; Basit, AW; Gaisford, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goyanes, Alvaro; Det-Amornrat, Usanee; Wang, Jie; Basit, Abdul W.; Gaisford, Simon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D scanning and 3D printing as innovative technologies for fabricating personalized topical drug delivery systems", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Acne is a multifactorial inflammatory skin disease with high prevalence. In this work, the potential of 3D printing to produce flexible personalised-shape anti-acne drug (salicylic acid) loaded devices was demonstrated by two different 3D printing (3DP) technologies: Fused Deposition Modelling (FDM) and stereolithography (SLA). 3D scanning technology was used to obtain a 3D model of a nose adapted to the morphology of an individual. In FDM 3DP, commercially produced Flex EcoPLA (TM) (FPLA) and polycaprolactone (PCL) filaments were loaded with salicylic acid by hot melt extrusion (HME) (theoretical drug loading 2% w/w) and used as feedstock material for 3D printing. Drug loading in the FPLA-salicylic acid and PCL-salicylic acid 3D printed patches was 0.4% w/ w and 12% w/w respectively, indicating significant thermal degradation of drug during HME and 3D printing. Diffusion testing in Franz cells using a synthetic membrane revealed that the drug loaded printed samples released <187 mu g/cm(2) within 3 h. FPLA-salicylic acid filament was successfully printed as a nose-shape mask by FDM 3DP, but the PCL-salicylic acid filament was not. In the SLA printing process, the drug was dissolved in different mixtures of poly(ethylene glycol) diadylate (PEGDA) and poly(ethylene glycol) (PEG) that were solidified by the action of a laser beam. SLA printing led to 3D printed devices (nose-shape) with higher resolution and higher drug loading (1.9% w/w) than FDM, with no drug degradation. The results of drug diffusion tests revealed that drug diffusion was faster than with the FDM devices, 229 and 291 mu g/cm(2) within 3 h for the two formulations evaluated. In this study, SLA printing was the more appropriate 3D printing technology to manufacture anti-acne devices with salicylic add. The combination of 3D scanning and 3D printing has the potential to offer solutions to produce personalised drug loaded devices, adapted in shape and size to individual patients. kV. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2016, "Volume": 234, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 41, "End Page": 48, "Article Number": null, "DOI": "10.1016/j.jconrel.2016.05.034", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2016.05.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378056800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, K; Jin, BJ; Park, C; Cho, Y; Song, XF; Shi, XJ; Zhang, SL; Kim, W; Zeng, HB; Park, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Kan; Jin, Bingjun; Park, Cheolwoo; Cho, Yoonjun; Song, Xiufeng; Shi, Xinjian; Zhang, Shengli; Kim, Wooyul; Zeng, Haibo; Park, Jong Hyeok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black phosphorene as a hole extraction layer boosting solar water splitting of oxygen evolution catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the development of oxygen evolution co-catalysts (OECs) is being actively undertaken, the tailored integration of those OECs with photoanodes is expected to be a plausible avenue for achieving highly efficient solar-assisted water splitting. Here, we demonstrate that a black phosphorene (BP) layer, inserted between the OEC and BiVO4 can improve the photoelectrochemical performance of pre-optimized OEC/BiVO4 (OEC: NiOOH, MnOx, and CoOOH) systems by 1.21.6-fold, while the OEC overlayer, in turn, can suppress BP self-oxidation to achieve a high durability. A photocurrent density of 4.48 mA.cm(-2) at 1.23 V vs reversible hydrogen electrode (RHE) is achieved by the NiOOH/BP/BiVO4 photoanode. It is found that the intrinsic p-type BP can boost hole extraction from BiVO4 and prolong holes trapping lifetime on BiVO4 surface. This work sheds light on the design of BP-based devices for application in solar to fuel conversion, and also suggests a promising nexus between semiconductor and electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001, "DOI": "10.1038/s41467-019-10034-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10034-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466337500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sui, D; Yao, M; Si, LQ; Yan, K; Shi, JG; Wang, JS; Xu, CC; Zhang, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sui, Dong; Yao, Min; Si, Linqi; Yan, Kun; Shi, Jingge; Wang, Jianshe; Xu, Charles Chunbao; Zhang, Yongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-derived carbon coated SiO2 nullotubes as superior anode for lithium-ion batteries", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silica (SiO2) is regarded as a promising anode for lithium-ion batteries due to the high specific capacity, abundant resources and low cost. However, the inherently poor electrical conductivity and the huge volume variation during charge/discharge process significantly hinder the application of SiO2. Designing nullostructured SiO2 and coating with high conductivity materials are effective methods to solve the above challenges. In this work, advanced SiO2 anodes were prepared by coating hollow SiO2 nullotubes (SNTs) with lignin or phenolated and depolymerized lignin furfural resin (PDLF)-derived carbon. The novel structure of the obtained SNTs greatly promotes the rapid transport for both Li+ and electron, increases the exposed active sites for Li+ insertion and accommodates the volume change of SNTs. Especially, PDLF possesses abundant functional groups, high carbon content and thermosetting property, which are beneficial to the dispersion of SNTs and formation of a cross-linked 3D conductive network. Thereby, SNTs@C-PDLF presents higher specific capacity of 661 mAh g(-1) at 100 mA g(-1), superior rate capability (262 mAh g(-1) at 3000 mA g(-1)) and better cycling stability (549 mAh g(-1) at 1000 mA g(-1) after 800 cycles) compared with SNTs@C-lignin and pristine SNTs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2023, "Volume": 205, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 510, "End Page": 518, "Article Number": null, "DOI": "10.1016/j.carbon.2023.01.039", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.01.039", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931799800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, WL; Lawrence, M; Yang, BA; Liu, F; Fang, FZ; Béri, B; Li, JS; Zhang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Wenlong; Lawrence, Mark; Yang, Biao; Liu, Fu; Fang, Fengzhou; Beri, Benjamin; Li, Jensen; Zhang, Shuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Photonic Phase in Chiral Hyperbolic Metamaterials", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, the possibility of achieving one-way backscatter immune transportation of light by mimicking the topological properties of certain solid state systems, such as topological insulators, has received much attention. Thus far, however, demonstrations of nontrivial topology in photonics have relied on photonic crystals with precisely engineered lattice structures, periodic on the scale of the operational wavelength and composed of finely tuned, complex materials. Here we propose a novel effective medium approach towards achieving topologically protected photonic surface states robust against disorder on all length scales and for a wide range of material parameters. Remarkably, the nontrivial topology of our metamaterial design results from the Berry curvature arising from the transversality of electromagnetic waves in a homogeneous medium. Our investigation therefore acts to bridge the gap between the advancing field of topological band theory and classical optical phenomena such as the spin Hall effect of light. The effective medium route to topological phases will pave the way for highly compact one-way transportation of electromagnetic waves in integrated photonic circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2015, "Volume": 114, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37402, "DOI": "10.1103/PhysRevLett.114.037402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.037402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348576100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, C; Mills, JP; Yohannes, AG; Wei, W; Wang, L; Lu, SY; Lian, JX; Wang, MY; Guo, T; Wang, XY; Zhou, H; Sun, CJ; Wen, JZ; Kendall, B; Couillard, M; Guo, HS; Tan, ZC; Siahrostami, S; Wu, YA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Cheng; Mills, Joel P.; Yohannes, Asfaw G.; Wei, Wei; Wang, Lei; Lu, Siyan; Lian, Jian-Xiang; Wang, Maoyu; Guo, Tao; Wang, Xiyang; Zhou, Hua; Sun, Cheng-Jun; Wen, John Z.; Kendall, Brian; Couillard, Martin; Guo, Hongsheng; Tan, Zhongchao; Siahrostami, Samira; Wu, Yimin A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cascade electrocatalysis via AgCu single-atom alloy and Ag nulloparticles in CO2 electroreduction toward multicarbon products", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic CO2 reduction into value-added multicarbon products offers a means to close the anthropogenic carbon cycle using renewable electricity. However, the unsatisfactory catalytic selectivity for multicarbon products severely hinders the practical application of this technology. In this paper, we report a cascade AgCu single-atom and nulloparticle electrocatalyst, in which Ag nulloparticles produce CO and AgCu single-atom alloys promote C-C coupling kinetics. As a result, a Faradaic efficiency (FE) of 94 +/- 4% toward multicarbon products is achieved with the as-prepared AgCu single-atom and nulloparticle catalyst under similar to 720 mA cm(-2) working current density at -0.65 V in a flow cell with alkaline electrolyte. Density functional theory calculations further demonstrate that the high multicarbon product selectivity results from cooperation between AgCu single-atom alloys and Ag nulloparticles, wherein the Ag single-atom doping of Cu nulloparticles increases the adsorption energy of *CO on Cu sites due to the asymmetric bonding of the Cu atom to the adjacent Ag atom with a compressive strain.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6142, "DOI": "10.1038/s41467-023-41871-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41871-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001084559200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, XY; Kamin, S; Liu, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Xiaoyang; Kamin, Simon; Liu, Na", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic plasmonic colour display", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmonic colour printing based on engineered metasurfaces has revolutionized colour display science due to its unprecedented subwavelength resolution and high-density optical data storage. However, advanced plasmonic displays with novel functionalities including dynamic multicolour printing, animations, and highly secure encryption have remained in their infancy. Here we demonstrate a dynamic plasmonic colour display technique that enables all the aforementioned functionalities using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent magnesium nulloparticles, which serve as dynamic pixels, allow for plasmonic colour printing, tuning, erasing and restoration of colour. Different dynamic pixels feature distinct colour transformation kinetics, enabling plasmonic animations. Through smart material processing, information encoded on selected pixels, which are indiscernible to both optical and scanning electron microscopies, can only be read out using hydrogen as a decoding key, suggesting a new generation of information encryption and anti-counterfeiting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 466, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14606, "DOI": "10.1038/ncomms14606", "DOI Link": "http://dx.doi.org/10.1038/ncomms14606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394654400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Qiao, J; He, K; Bliznakov, S; Sutter, E; Chen, X; Luo, D; Meng, F; Su, D; Decker, J; Ji, W; Ruoff, RS; Sutter, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yuan; Qiao, Jingsi; He, Kai; Bliznakov, Stoyan; Sutter, Eli; Chen, Xianjue; Luo, Da; Meng, Fanke; Su, Dong; Decker, Jeremy; Ji, Wei; Ruoff, Rodney S.; Sutter, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interaction of Black Phosphorus with Oxygen and Water", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus (BP) has attracted significant interest as a monolayer or few-layer material with extraordinary electrical and optoelectronic properties. Chemical reactions with different ambient species, notably oxygen and water, are important as they govern key properties such as stability in air, electronic structure and charge transport, wetting by aqueous solutions, and so on. Here, we report experiments combined with ab initio calculations that address the effects of oxygen and water in contact with BP. Our results show that the reaction with oxygen is primarily responsible for changing properties of BP. Oxidation involving the dissociative chemisorption of O-2 causes the decomposition of BP and continuously lowers the conductance of BP field-effect transistors (FETs). In contrast, BP is stable in contact with deaerated (i.e., O-2 depleted) water and the carrier mobility in BP FETs gated by H2O increases significantly due to efficient dielectric screening of scattering centers by the high-k dielectric. Isotope labeling experiments, contact angle measurements, and calculations show that the pristine BP surface is hydrophobic but is turned progressively hydrophilic by oxidation. Our results open new avenues for exploring applications that require contact of BP with aqueous solutions including solution gating, electrochemistry, and solution-phase approaches for exfoliation, dispersion, and delivery of BP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 458, "Times Cited, All Databases": 484, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2016, "Volume": 28, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8330, "End Page": 8339, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b03592", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b03592", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388914500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ford, S; Despeisse, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ford, Simon; Despeisse, Melanie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing and sustainability: an exploratory study of the advantages and challenges", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of advanced manufacturing technologies, coupled with consumer demands for more customised products and services, are causing shifts in the scale and distribution of manufacturing. In this paper, consideration is given to the role of one such advanced manufacturing process technology: additive manufacturing. The consequences of adopting this novel production technology on industrial sustainability are not well understood and this exploratory study draws on publically available data to provide insights into the impacts of additive manufacturing on sustainability. Benefits are found to exist across the product and material life cycles through product and process redesign, improvements to material input processing, make-to-order component and product manufacturing, and closing the loop. As an immature technology, there are substantial challenges to these benefits being realised at each stage of the life cycle. This paper summarises these advantages and challenges, and discusses the implications of additive manufacturing on sustainability in terms of the sources of innovation, business models, and the configuration of value chains. (C) 2016 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1073, "Times Cited, All Databases": 1196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2016, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1573, "End Page": 1587, "Article Number": null, "DOI": "10.1016/j.jclepro.2016.04.150", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2016.04.150", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391079300141", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benin, BM; Dirin, DN; Morad, V; Wörle, M; Yakunin, S; Rainò, G; Nazarenko, O; Fischer, M; Infante, I; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benin, Bogdan M.; Dirin, Dmitry N.; Morad, Viktoriia; Woerle, Michael; Yakunin, Sergii; Raino, Gabriele; Nazarenko, Olga; Fischer, Markus; Infante, Ivan; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Emissive Self-Trapped Excitons in Fully Inorganic Zero-Dimensional Tin Halides", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spatial localization of charge carriers to promote the formation of bound excitons and concomitantly enhance radiative recombination has long been a goal for luminescent semiconductors. Zero-dimensional materials structurally impose carrier localization and result in the formation of localized Frenkel excitons. Now the fully inorganic, perovskite-derived zero-dimensional Sn-II material Cs4SnBr6 is presented that exhibits room-temperature broad-band photoluminescence centered at 540 nm with a quantum yield (QY) of 15 +/- 5%. A series of analogous compositions following the general formula Cs(4-x)A(x)Sn(Br1-yIy)(6) (A=Rb, K; x <= 1, y <= 1) can be prepared. The emission of these materials ranges from 500 nm to 620 nm with the possibility to compositionally tune the Stokes shift and the self-trapped exciton emission bands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2018, "Volume": 57, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11329, "End Page": 11333, "Article Number": null, "DOI": "10.1002/anie.201806452", "DOI Link": "http://dx.doi.org/10.1002/anie.201806452", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442340000037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carrete, J; Mingo, N; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carrete, Jesus; Mingo, Natalio; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low thermal conductivity and triaxial phononic anisotropy of SnSe", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this theoretical study, we investigate the origins of the very low thermal conductivity of tin selenide (SnSe) using ab-initio calculations. We obtained high-temperature lattice thermal conductivity values that are close to those of amorphous compounds. We also found a strong anisotropy between the three crystallographic axes: one of the in-plane directions conducts heat much more easily than the other. Our results are compatible with most of the experimental literature on SnSe and differ markedly from the more isotropic values reported by a recent study. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2014, "Volume": 105, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101907, "DOI": "10.1063/1.4895770", "DOI Link": "http://dx.doi.org/10.1063/1.4895770", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342758700024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, JX; Lu, LG; Wang, L; Ohma, A; Ren, DS; Feng, XN; Li, Y; Li, YL; Ootani, I; Han, XB; Ren, WN; He, XM; Nitta, Y; Ouyang, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Junxian; Lu, Languang; Wang, Li; Ohma, Atsushi; Ren, Dongsheng; Feng, Xuning; Li, Yan; Li, Yalun; Ootani, Issei; Han, Xuebing; Ren, Weining; He, Xiangming; Nitta, Yoshiaki; Ouyang, Minggao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal runaway of Lithium-ion batteries employing LiN(SO2F)2-based concentrated electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concentrated electrolytes usually demonstrate good electrochemical performance and thermal stability, and are also supposed to be promising when it comes to improving the safety of lithium-ion batteries due to their low flammability. Here, we show that LiN(SO2F)(2)-based concentrated electrolytes are incapable of solving the safety issues of lithium-ion batteries. To illustrate, a mechanism based on battery material and characterizations reveals that the tremendous heat in lithium-ion batteries is released due to the reaction between the lithiated graphite and LiN(SO2F)(2) triggered thermal runaway of batteries, even if the concentrated electrolyte is non-flammable or low-flammable. Generally, the flammability of an electrolyte represents its behaviors when oxidized by oxygen, while it is the electrolyte reduction that triggers the chain of exothermic reactions in a battery. Thus, this study lights the way to a deeper understanding of the thermal runaway mechanism in batteries as well as the design philosophy of electrolytes for safer lithium-ion batteries. Concentrated electrolytes display superior thermal stability due to their non-flammability nature. Here, the authors show that LiN(SO2F)(2)-based concentrated electrolytes are incapable of solving the safety issues due to heat release during reaction between the lithiated graphite and electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5100, "DOI": "10.1038/s41467-020-18868-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18868-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000581916500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, YX; Wang, F; Tian, JW; Li, SY; Fu, EG; Nie, JH; Lei, R; Ding, YF; Chen, XY; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yuxiang; Wang, Fan; Tian, Jingwen; Li, Shuyao; Fu, Engang; Nie, Jinhui; Lei, Rui; Ding, Yafei; Chen, Xiangyu; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-powered electro-tactile system for virtual tactile experiences", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tactile sensation plays important roles in virtual reality and augmented reality systems. Here, a self-powered, painless, and highly sensitive electro-tactile (ET) system for achieving virtual tactile experiences is proposed on the basis of triboelectric nullogenerator (TENG) and ET interface formed of ball-shaped electrode array. Electrostatic discharge triggered by TENG can induce notable ET stimulation, while controlled distance between the ET electrodes and human skin can regulate the induced discharge current. The ion bombardment technique has been used to enhance the electrification capability of triboelectric polymer. Accordingly, TENG with a contact area of 4 cm(2) is capable of triggering discharge, leading to a compact system. In this skin-integrated ET interface, touching position and motion trace on the TENG surface can be precisely reproduced on skin. This TENG-based ET system can work for many fields, including virtual tactile displays, Braille instruction, intelligent protective suits, or even nerve stimulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe2943", "DOI": "10.1126/sciadv.abe2943", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe2943", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615369000026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tancogne-Dejean, T; Diamantopoulou, M; Gorji, MB; Bonatti, C; Mohr, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tancogne-Dejean, Thomas; Diamantopoulou, Marianna; Gorji, Maysam B.; Bonatti, Colin; Mohr, Dirk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Plate-Lattices: An Emerging Class of Low-Density Metamaterial Exhibiting Optimal Isotropic Stiffness", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In lightweight engineering, there is a constant quest for low-density materials featuring high mass-specific stiffness and strength. Additively-manufactured metamaterials are particularly promising candidates as the controlled introduction of porosity allows for tailoring their density while activating strengthening size-effects at the nullo- and microstructural level. Here, plate-lattices are conceived by placing plates along the closest-packed planes of crystal structures. Based on theoretical analysis, a general design map is developed for elastically isotropic plate-lattices of cubic symmetry. In addition to validating the design map, detailed computational analysis reveals that there even exist plate-lattice compositions that provide nearly isotropic yield strength together with elastic isotropy. The most striking feature of plate-lattices is that their stiffness and yield strength are within a few percent of the theoretical limits for isotropic porous solids. This implies that the stiffness of isotropic plate-lattices is up to three times higher than that of the stiffest truss-lattices of equal mass. This stiffness advantage is also confirmed by experiments on truss- and plate-lattice specimens fabricated through direct laser writing. Due to their porous internal structure, the potential impact of the new metamaterials reported here goes beyond lightweight engineering, including applications for heat-exchange, thermal insulation, acoustics, and biomedical engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 30, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803334, "DOI": "10.1002/adma.201803334", "DOI Link": "http://dx.doi.org/10.1002/adma.201803334", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449819500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, ZJ; Mahammed, SAR; Liu, TF; Cao, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Zu-Jin; Mahammed, Shaheer A. R.; Liu, Tian-Fu; Cao, Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional Porous Hydrogen-Bonded Organic Frameworks: Current Status and Future Perspectives", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen-bonded organic frameworks (HOFs), self-assembled from organic or metalated organic building blocks (also termed as tectons) by hydrogen bonding, pi-pi stacking, and other intermolecular interactions, have become an emerging class of multifunctional porous materials. So far, a library of HOFs with high porosity has been synthesized based on versatile tectons and supramolecular synthons. Benefiting from the flexibility and reversibility of H-bonds, HOFs feature high structural flexibility, mild synthetic reaction, excellent solution processability, facile healing, easy regeneration, and good recyclability. However, the flexible and reversible nature of H-bonds makes most HOFs suffer from poor structural designability and low framework stability. In this Outlook, we first describe the development and structural features of HOFs and summarize the design principles of HOFs and strategies to enhance their stability. Second, we highlight the state-ofthe-art development of HOFs for diverse applications, including gas storage and separation, heterogeneous catalysis, biological applications, sensing, proton conduction, and other applications. Finally, current challenges and future perspectives are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2022, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1589, "End Page": 1608, "Article Number": null, "DOI": "10.1021/acscentsci.2c01196", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.2c01196", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000901517100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZY; Chen, FF; Martinez-Ibañez, M; Feng, WF; Forsyth, M; Zhou, ZB; Armand, M; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Ziyu; Chen, Fangfang; Martinez-Ibanez, Maria; Feng, Wenfang; Forsyth, Maria; Zhou, Zhibin; Armand, Michel; Zhang, Heng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A reflection on polymer electrolytes for solid-state lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer electrolytes are attractive candidates for rechargeable lithium metal batteries. Here, the authors give a personal reflection on the structural design of coupled and decoupled polymer electrolytes and possible routes to further enhance their performance in rechargeable batteries. Before the debut of lithium-ion batteries (LIBs) in the commodity market, solid-state lithium metal batteries (SSLMBs) were considered promising high-energy electrochemical energy storage systems before being almost abandoned in the late 1980s because of safety concerns. However, after three decades of development, LIB technologies are now approaching their energy content and safety limits imposed by the rocking chair chemistry. These aspects are prompting the revival of research activities in SSLMB technologies at both academic and industrial levels. In this perspective article, we present a personal reflection on solid polymer electrolytes (SPEs), spanning from early development to their implementation in SSLMBs, highlighting key milestones. In particular, we discuss the SPEs' characteristics taking into account the concept of coupled and decoupled SPEs proposed by C. Austen Angell in the early 1990s. Possible remedies to improve the physicochemical and electrochemical properties of SPEs are also examined. With this article, we also aim to highlight the missing blocks in building ideal SSLMBs and stimulate research towards innovative electrolyte materials for future rechargeable high-energy batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4884, "DOI": "10.1038/s41467-023-40609-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40609-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001049310000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, AS; Brown, DW; Kumar, M; Gallegos, GF; King, WE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Amanda S.; Brown, Donald W.; Kumar, Mukul; Gallegos, Gilbert F.; King, Wayne E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Experimental Investigation into Additive Manufacturing-Induced Residual Stresses in 316L Stainless Steel", "Source Title": "METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) technology provides unique opportunities for producing net-shape geometries at the macroscale through microscale processing. This level of control presents inherent trade-offs necessitating the establishment of quality controls aimed at minimizing undesirable properties, such as porosity and residual stresses. Here, we perform a parametric study into the effects of laser scanning pattern, power, speed, and build direction in powder bed fusion AM on residual stress. In an effort to better understand the factors influencing macroscale residual stresses, a destructive surface residual stress measurement technique (digital image correlation in conjunction with build plate removal and sectioning) has been coupled with a nondestructive volumetric evaluation method (i.e., neutron diffraction). Good agreement between the two measurement techniques is observed. Furthermore, a reduction in residual stress is obtained by decreasing scan island size, increasing island to wall rotation to 45 deg, and increasing applied energy per unit length (laser power/speed). Neutron diffraction measurements reveal that, while in-plane residual stresses are affected by scan island rotation, axial residual stresses are unchanged. We attribute this in-plane behavior to misalignment between the greatest thermal stresses (scan direction) and largest part dimension.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": "45A", "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6260, "End Page": 6270, "Article Number": null, "DOI": "10.1007/s11661-014-2549-x", "DOI Link": "http://dx.doi.org/10.1007/s11661-014-2549-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344334900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, JR; Zhang, HP; Fu, SJ; Jaroniec, M; Shan, JQ; Xia, BQ; Qu, Y; Qu, JT; Chen, SM; Song, L; Cairney, JM; Jing, LQ; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Jingrun; Zhang, Hongping; Fu, Sijia; Jaroniec, Mietek; Shan, Jieqiong; Xia, Bingquan; Qu, Yang; Qu, Jiangtao; Chen, Shuangming; Song, Li; Cairney, Julie M.; Jing, Liqiang; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NiPS3 ultrathin nullosheets as versatile platform advancing highly active photocatalytic H2 production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance and low-cost photocatalysts play the key role in achieving the large-scale solar hydrogen production. In this work, we report a liquid-exfoliation approach to prepare NiPS3 ultrathin nullosheets as a versatile platform to greatly improve the light-induced hydrogen production on various photocatalysts, including TiO2, CdS, In2ZnS4 and C3N4. The superb visible-light-induced hydrogen production rate (13,600 mu mol h(-1) g(-1)) is achieved on NiPS3/CdS hetero-junction with the highest improvement factor (similar to 1,667%) compared with that of pure CdS. This significantly better performance is attributed to the strongly correlated NiPS3/CdS interface assuring efficient electron-hole dissociation/transport, as well as abundant atomic-level edge P/S sites and activated basal S sites on NiPS3 ultrathin nullosheets advancing hydrogen evolution. These findings are revealed by the state-of-art characterizations and theoretical computations. Our work for the first time demonstrates the great potential of metal phosphorous chalcogenide as a general platform to tremendously raise the performance of different photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4600, "DOI": "10.1038/s41467-022-32256-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32256-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836839500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZZ; Xiong, XH; Xiong, JB; Krishna, R; Li, LB; Fan, YL; Luo, F; Chen, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Zhenzhen; Xiong, Xiaohong; Xiong, Jianbo; Krishna, Rajamani; Li, Libo; Fan, Yaling; Luo, Feng; Chen, Banglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Separation of C2H4 from C2H4/C2H2/C2H6 mixture with high working capacity is still a challenging task. Herein, we deliberately design a Th-metal-organic framework (MOF) for highly efficient separation of C2H4 from a binary C2H6/C2H4 and ternary C2H4/C2H2/C2H6 mixture. The synthesized MOF Azole-Th-1 shows a UiO-66-type structure with fcu topology built on a Th-6 secondary building unit and a tetrazole-based linker. Such noticeable structure, is connected by a N,O-donor ligand with high chemical stability. At 100 kPa and 298K Azole-Th-1 performs excellent separation of C2H4 (purity > 99.9%) from not only a binary C2H6/C2H4 (1:9, v/v) mixture but also a ternary mixture of C2H6/C2H2/C2H4 (9:1:90, v/v/v), and the corresponding working capacity can reach up to 1.13 and 1.34mmolg(-1), respectively. The separation mechanism, as unveiled by the density functional theory calculation, is due to a stronger van der Waals interaction between ethane and the MOF skeleton. Separation of ethylene from C2 ternary mixture with high working capacity is a challenging task. Here, the authors report a Th-azole framework (Azole-Th-1) for highly efficient purification of ethylene from C2H4/C2H6 and C2H4/C2H2/C2H6 mixtures, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-16960-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16960-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544742300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chi, JG; Liu, CR; Che, LF; Li, DJ; Fan, K; Li, Q; Yang, WH; Dong, LX; Wang, GF; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chi, Jingu; Liu, Chaoran; Che, Lufeng; Li, Dujuan; Fan, Kai; Li, Qing; Yang, Weihuang; Dong, Linxi; Wang, Gaofeng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harvesting Water-Evaporation-Induced Electricity Based on Liquid-Solid Triboelectric nullogenerator", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting energy from natural water evaporation has been proposed as a promising alternative to supply power for self-powered and low-power devices and systems, owing to its spontaneous, ubiquitous, and sustainability. Herein, an approach is presented for harvesting water-evaporation-induced electricity based on liquid-solid triboelectric nullogenerators (LS-TENGs), which has various advantages of easy preparation, substrate needless, and robustness. This developed harvester with porous Al2O3 ceramic sheet can generate a continuous and stable direct current of approximate to 0.3 mu A and voltage of approximate to 0.7 V by optimizing the sheet physical dimensions and ambient parameters such as relative humidity, temperature, wind velocity, and ion concentration. The output power also can be improved significantly by series or parallel connection the harvesters, which has superior electrical compatibility and environmental suitability. The development of the water-evaporation-induced electricity harvesting shows many application prospects including power supply for digital calculator and charging capacitor. This research provides an in-depth experimental study on water-evaporation-induced electricity harvesting based on LS-TENGs and an efficient approach to supply electricity for low-power devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 9, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201586, "DOI": "10.1002/advs.202201586", "DOI Link": "http://dx.doi.org/10.1002/advs.202201586", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783013400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Wu, YL; Xu, ZM; Li, HX; Xu, M; Li, JW; Dai, YH; Zong, W; Chen, RW; He, L; Zhang, Z; Brett, DJL; He, GJ; Lai, YQ; Parkin, IP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Wu, Yulun; Xu, Zhenming; Li, Huangxu; Xu, Ming; Li, Jianwei; Dai, Yuhang; Zong, Wei; Chen, Ruwei; He, Liang; Zhang, Zhian; Brett, Dan J. L.; He, Guanjie; Lai, Yanqing; Parkin, Ivan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationally Designed Sodium Chromium Vanadium Phosphate Cathodes with Multi-Electron Reaction for Fast-Charging Sodium-Ion Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium super-ionic conductor (NASICON)-structured phosphates are emerging as rising stars as cathodes for sodium-ion batteries. However, they usually suffer from a relatively low capacity due to the limited activated redox couples and low intrinsic electronic conductivity. Herein, a reduced graphene oxide supported NASICON Na3Cr0.5V1.5(PO4)(3) cathode (VC/C-G) is designed, which displays ultrafast (up to 50 C) and ultrastable (1 000 cycles at 20 C) Na+ storage properties. The VC/C-G can reach a high energy density of approximate to 470 W h kg(-1) at 0.2 C with a specific capacity of 176 mAh g(-1) (equivalent to the theoretical value); this corresponds to a three-electron transfer reaction based on fully activated V5+/V4+, V4+/V3+, V3+/V2+ couples. In situ X-ray diffraction (XRD) results disclose a combination of solid-solution reaction and biphasic reaction mechanisms upon cycling. Density functional theory calculations reveal a narrow forbidden-band gap of 1.41 eV and a low Na+ diffusion energy barrier of 0.194 eV. Furthermore, VC/C-G shows excellent fast-charging performance by only taking approximate to 11 min to reach 80% state of charge. The work provides a widely applicable strategy for realizing multi-electron cathode design for high-performance SIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 12, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201065, "DOI": "10.1002/aenm.202201065", "DOI Link": "http://dx.doi.org/10.1002/aenm.202201065", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000792055400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, ZY; Jiao, HY; Fei, CB; Gu, HY; Xu, S; Yu, ZH; Yang, G; Deng, YA; Jiang, Q; Liu, Y; Yan, YF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Zhenyi; Jiao, Haoyang; Fei, Chengbin; Gu, Hangyu; Xu, Shuang; Yu, Zhenhua; Yang, Guang; Deng, Yehao; Jiang, Qi; Liu, Ye; Yan, Yanfa; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of defects during the degradation of metal halide perovskite solar cells under reverse bias and illumination", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiency and stability of perovskite solar cells are essentially determined by defects in the perovskite layer, yet their chemical nature and linking with the degradation mechanism of devices remain unclear. Here we uncover where degradation occurs and the underlying mechanisms and defects involved in the performance degradation of p-i-n perovskite solar cells under illumination or reverse bias. Light-induced degradation starts with the generation of iodide interstitials at the interfacial region between the perovskite and both charge transport layers. While we observe trap annihilation of two types of iodide defect at the anode side, we find negatively charged iodide interstitials near the cathode side, which we show to be more detrimental to the solar cell efficiency. The reverse-bias degradation is initialized by the interaction between iodide interstitials and injected holes at the interface between the electron transport layer and the perovskite. Introducing a hole-blocking layer between the layers suppresses this interaction, improving the reverse-bias stability. The efficiency of perovskite solar cells decreases over time, yet the underlying mechanisms are unclear. Ni et al. observe charged iodide interstitial defects within the device layers and how they contribute to the efficiency degradation when the cell is operated under illumination or reverse bias.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 73, "Article Number": null, "DOI": "10.1038/s41560-021-00949-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00949-9", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733869600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Richards, WD; Tsujimura, T; Miara, LJ; Wang, Y; Kim, JC; Ong, SP; Uechi, I; Suzuki, N; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Richards, William D.; Tsujimura, Tomoyuki; Miara, Lincoln J.; Wang, Yan; Kim, Jae Chul; Ong, Shyue Ping; Uechi, Ichiro; Suzuki, Naoki; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and synthesis of the superionic conductor Na10SnP2S12", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are emerging as candidates for large-scale energy storage due to their low cost and the wide variety of cathode materials available. As battery size and adoption in critical applications increases, safety concerns are resurfacing due to the inherent flammability of organic electrolytes currently in use in both lithium and sodium battery chemistries. Development of solid-state batteries with ionic electrolytes eliminates this concern, while also allowing novel device architectures and potentially improving cycle life. Here we report the computation-assisted discovery and synthesis of a high-performance solid-state electrolyte material: Na10SnP2S12, with room temperature ionic conductivity of 0.4 mScm(-1) rivalling the conductivity of the best sodium sulfide solid electrolytes to date. We also computationally investigate the variants of this compound where tin is substituted by germanium or silicon and find that the latter may achieve even higher conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11009, "DOI": "10.1038/ncomms11009", "DOI Link": "http://dx.doi.org/10.1038/ncomms11009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372226600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, J; Shuai, J; Song, SW; Wu, YX; Dally, R; Zhou, JW; Liu, ZH; Sun, JF; Zhang, QY; dela Cruz, C; Wilson, S; Pei, YZ; Singh, DJ; Chen, G; Chu, CW; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Jun; Shuai, Jing; Song, Shaowei; Wu, Yixuan; Dally, Rebecca; Zhou, Jiawei; Liu, Zihang; Sun, Jifeng; Zhang, Qinyong; dela Cruz, Clarina; Wilson, Stephen; Pei, Yanzhong; Singh, David J.; Chen, Gang; Chu, Ching-Wu; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulation of ionized impurity scattering for achieving high thermoelectric performance in n-type Mg3Sb2-based materials", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving higher carrier mobility plays a pivotal role for obtaining potentially high thermoelectric performance. In principle, the carrier mobility is governed by the band structure as well as by the carrier scattering mechanism. Here, we demonstrate that by manipulating the carrier scattering mechanism in n-type Mg3Sb2-based materials, a substantial improvement in carrier mobility, and hence the power factor, can be achieved. In this work, Fe, Co, Hf, and Ta are doped on the Mg site of Mg3.2Sb1.5Bi0.49Te0.01, where the ionized impurity scattering crosses over to mixed ionized impurity and acoustic phonon scattering. A significant improvement in Hallmobility from similar to 16 to similar to 81 cm(2).V-1.s(-1) is obtained, thus leading to a notably enhanced power factor of similar to 13 mu W.cm(-1).K-2 from similar to 5 mu W.cm(-1).K-2. A simultaneous reduction in thermal conductivity is also achieved. Collectively, a figure of merit (ZT) of similar to 1.7 is obtained at 773 K in Mg3.1Co0.1Sb1.5Bi0.49Te0.01. The concept of manipulating the carrier scattering mechanism to improve the mobility should also be applicable to other material systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2017, "Volume": 114, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10548, "End Page": 10553, "Article Number": null, "DOI": "10.1073/pnas.1711725114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1711725114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412130500041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, S; Li, ZD; Wang, CL; Tao, WW; Huang, MX; Zuo, M; Yang, Y; Yang, K; Zhang, LJ; Chen, S; Xu, PP; Chen, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shuai; Li, Zedong; Wang, Changlai; Tao, Weiwei; Huang, Minxue; Zuo, Ming; Yang, Yang; Yang, Kang; Zhang, Lijuan; Chen, Shi; Xu, Pengping; Chen, Qianwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Turning main-group element magnesium into a highly active electrocatalyst for oxygen reduction reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is known that the main-group metals and their related materials show poor catalytic activity due to a broadened single resonullce derived from the interaction of valence orbitals of adsorbates with the broad sp-band of main-group metals. However, Mg cofactors existing in enzymes are extremely active in biochemical reactions. Our density function theory calculations reveal that the catalytic activity of the main-group metals (Mg, Al and Ca) in oxygen reduction reaction is severely hampered by the tight-bonding of active centers with hydroxyl group intermediate, while the Mg atom coordinated to two nitrogen atoms has the near-optimal adsorption strength with intermediate oxygen species by the rise of p-band center position compared to other coordination environments. We experimentally demonstrate that the atomically dispersed Mg cofactors incorporated within graphene framework exhibits a strikingly high half-wave potential of 910 mV in alkaline media, turning a s/p-band metal into a highly active electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 938, "DOI": "10.1038/s41467-020-14565-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14565-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564269900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Pan, Z; Guo, FF; Liu, WC; Ning, HP; Chen, YB; Lu, MH; Yang, B; Chen, J; Zhang, ST; Xing, XR; Rödel, J; Cao, WW; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ji; Pan, Zhao; Guo, Fei-Fei; Liu, Wen-Chao; Ning, Huanpo; Chen, Y. B.; Lu, Ming-Hui; Yang, Bin; Chen, Jun; Zhang, Shan-Tao; Xing, Xianran; Roedel, Juergen; Cao, Wenwu; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semiconductor/relaxor 0-3 type composites without thermal depolarization in Bi0.5Na0.5TiO3-based lead-free piezoceramics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Commercial lead-based piezoelectric materials raised worldwide environmental concerns in the past decade. Bi0.5Na0.5TiO3-based solid solution is among the most promising lead-free piezoelectric candidates; however, depolarization of these solid solutions is a longstanding obstacle for their practical applications. Here we use a strategy to defer the thermal depolarization, even render depolarization-free Bi0.5Na0.5TiO3-based 0-3-type composites. This is achieved by introducing semiconducting ZnO particles into the relaxor ferroelectric 0.94Bi(0.5)Na(0.5)TiO(3)-0.06BaTiO(3) matrix. The depolarization temperature increases with increasing ZnO concentration until depolarization disappears at 30 mol% ZnO. The semiconducting nature of ZnO provides charges to partially compensate the ferroelectric depolarization field. These results not only pave the way for applications of Bi0.5Na0.5TiO3-based piezoceramics, but also have great impact on the understanding of the mechanism of depolarization so as to provide a new design to optimize the performance of lead-free piezoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6615, "DOI": "10.1038/ncomms7615", "DOI Link": "http://dx.doi.org/10.1038/ncomms7615", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353041100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, XT; Meng, XC; Zhang, L; Zhang, YY; Cai, ZR; Huang, ZQ; Su, M; Wang, Y; Li, MZ; Li, FY; Yao, X; Wang, FY; Ma, W; Chen, YW; Song, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Xiaotian; Meng, Xiangchuan; Zhang, Lin; Zhang, Yanyan; Cai, Zheren; Huang, Zengqi; Su, Meng; Wang, Yang; Li, Mingzhu; Li, Fengyu; Yao, Xi; Wang, Fuyi; Ma, Wei; Chen, Yiwang; Song, Yanlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Mechanically Robust Conducting Polymer Network Electrode for Efficient Flexible Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lightweight and mechanically flexible photovoltaics enable roll-to-roll processing, which improves their potential for low-cost mass production. However, the lack of highly conductive and transparent flexible electrodes still causes reduced efficiency relative to solar cells formed on rigid substrates. Here, we demonstrate an electrode that reduces this performance gap in perovskite solar cells (PSCs) by regulating the phase separation of a conducting polymer network using a fluorosurfactant dopant. This network electrode simultaneously offers high conductivity (> 4,000 S/cm), improved transmittance (over 80% from 400 to 900 nm), and high mechanical endurance. PSCs with this electrode achieve stabilized power conversion efficiencies of 19.0% and 10.9% at aperture areas of 0.1 cm 2 and 25 cm(2), respectively, which is comparable to control devices on rigid substrates. This electrode further shows promise as the top electrode in semi-transparent PSCs, which show a stabilized efficiency of 12.5% at 30.6% average visible transmittance. Each of these cells exhibits strong mechanical stability, retaining 80% at 25 cm(2), 85% at 0.1 cm(2), and 90% for semi-transparent devices of their original efficiency after 5,000 bending cycles at a curvature radius of 3 mm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2019, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2205, "End Page": 2218, "Article Number": null, "DOI": "10.1016/j.joule.2019.06.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.06.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486444700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, EB; Chen, H; Xie, FX; Wu, YZ; Chen, W; Su, YJ; Islam, A; Grätzel, M; Yang, XD; Han, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Enbing; Chen, Han; Xie, Fengxian; Wu, Yongzhen; Chen, Wei; Su, Yanjie; Islam, Ashraful; Gratzel, Michael; Yang, Xudong; Han, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diffusion engineering of ions and charge carriers for stable efficient perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term stability is crucial for the future application of perovskite solar cells, a promising low-cost photovoltaic technology that has rapidly advanced in the recent years. Here, we designed a nullostructured carbon layer to suppress the diffusion of ions/molecules within perovskite solar cells, an important degradation process in the device. Furthermore, this nullocarbon layer benefited the diffusion of electron charge carriers to enable a high-energy conversion efficiency. Finally, the efficiency on a perovskite solar cell with an aperture area of 1.02 cm(2), after a thermal aging test at 85 degrees C for over 500 h, or light soaking for 1,000 h, was stable of over 15% during the entire test. The present diffusion engineering of ions/molecules and photo generated charges paves a way to realizing long-term stable and highly efficient perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15330, "DOI": "10.1038/ncomms15330", "DOI Link": "http://dx.doi.org/10.1038/ncomms15330", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403063500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, CY; Liu, PB; Wu, ZC; Zhang, HB; Zhang, RX; Zhang, C; Wang, L; Wang, LY; Yang, BT; Yang, ZQ; You, WB; Che, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Chunyang; Liu, Panbo; Wu, Zhengchen; Zhang, Huibin; Zhang, Ruixuan; Zhang, Chang; Wang, Lei; Wang, Longyuan; Yang, Bingtong; Yang, Ziqi; You, Wenbin; Che, Renchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Customizing Heterointerfaces in Multilevel Hollow Architecture Constructed by Magnetic Spindle Arrays Using the Polymerizing-Etching Strategy for Boosting Microwave Absorption", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterointerface engineering is evolving as an effective approach to tune electromagnetic functional materials, but the mechanisms of heterointerfaces on microwave absorption (MA) remain unclear. In this work, abundant electromagnetic heterointerfaces are customized in multilevel hollow architecture via a one-step synergistic polymerizing-etching strategy. Fe/Fe3O4@C spindle-on-tube structures are transformed from FeOOH@polydopamine precursors by a controllable reduction process. The impressive electromagnetic heterostructures are realized on the Fe/Fe3O4@C hollow spindle arrays and induce strong interfacial polarization. The highly dispersive Fe/Fe3O4 nulloparticles within spindles build multi-dimension magnetic networks, which enhance the interaction with incident microwaves and reinforce magnetic loss capacity. Moreover, the hierarchically hollow structure and electromagnetic synergistic components are conducive to the impedance matching between absorbing materials and air medium. Furthermore, the mechanisms of electromagnetic heterointerfaces on the MA are systematically investigated. Accordingly, the as-prepared hierarchical Fe/Fe3O4@C microtubes exhibit remarkable MA performance with a maximum refection loss of -55.4 dB and an absorption bandwidth of 4.2 GHz. Therefore, in this study, the authors not only demonstrate a synergistic strategy to design multilevel hollow architecture, but also provide a fundamental guide in heterointerface engineering of highly efficient electromagnetic functional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 9, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200804, "DOI": "10.1002/advs.202200804", "DOI Link": "http://dx.doi.org/10.1002/advs.202200804", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781277400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Zhang, W; Lin, YC; Cao, J; Zhou, Y; Jiang, W; Du, H; Tang, B; Shi, J; Jiang, B; Cao, X; Lin, B; Fu, Q; Zhu, C; Guo, W; Huang, Y; Yao, Y; Parkin, SSP; Zhou, J; Gao, Y; Wang, Y; Hou, Y; Yao, Y; Suenaga, K; Wu, X; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jiadong; Zhang, Wenjie; Lin, Yung-Chang; Cao, Jin; Zhou, Yao; Jiang, Wei; Du, Huifang; Tang, Bijun; Shi, Jia; Jiang, Bingyan; Cao, Xun; Lin, Bo; Fu, Qundong; Zhu, Chao; Guo, Wei; Huang, Yizhong; Yao, Yuan; Parkin, Stuart S. P.; Zhou, Jianhui; Gao, Yanfeng; Wang, Yeliang; Hou, Yanglong; Yao, Yugui; Suenaga, Kazu; Wu, Xiaosong; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterodimensional superlattice with in-plane anomalous Hall effect", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superlattices-a periodic stacking of two-dimensional layers of two or more materials-provide a versatile scheme for engineering materials with tailored properties(1,2). Here we report an intrinsic heterodimensional superlattice consisting of alternating layers of two-dimensional vanadium disulfide (VS2) and a one-dimensional vanadium sulfide (VS) chain array, deposited directly by chemical vapour deposition. This unique superlattice features an unconventional 1T stacking with a monoclinic unit cell of VS2/VS layers identified by scanning transmission electron microscopy. An unexpected Hall effect, persisting up to 380 kelvin, is observed when the magnetic field is in-plane, a condition under which the Hall effect usually vanishes. The observation of this effect is supported bytheoretical calculations, and can be attributed to an unconventional anomalous Hall effect owing to an out-of-plane Berry curvature induced by an in-plane magnetic field, which is related to the one-dimensional VS chain. Our work expandsthe conventional understanding of superlattices and will stimulate the synthesis of more extraordinary superstructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2022, "Volume": 609, "Issue": 7925, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 46, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05031-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05031-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000848739300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ZQ; Wu, DD; Xu, B; Xu, HY; Cai, ZP; Peng, J; Weng, J; Xu, S; Zhu, CH; Wang, FQ; Sun, ZP; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhengqian; Wu, Duanduan; Xu, Bin; Xu, Huiying; Cai, Zhiping; Peng, Jian; Weng, Jian; Xu, Shuo; Zhu, Chunhui; Wang, Fengqiu; Sun, Zhipei; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional material-based saturable absorbers: towards compact visible-wavelength all-fiber pulsed lasers", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive Q-switching or mode-locking by placing a saturable absorber inside the laser cavity is one of the most effective and popular techniques for pulse generation. However, most of the current saturable absorbers cannot work well in the visible spectral region, which seriously impedes the progress of passively Q-switched/mode-locked visible pulsed fibre lasers. Here, we report a kind of visible saturable absorber-two-dimensional transition-metal dichalcogenides (TMDs, e.g. WS2, MoS2, MoSe2), and successfully demonstrate compact red-light Q-switched praseodymium (Pr3+)-doped all-fibre lasers. The passive Q-switching operation at 635 nm generates stable laser pulses with similar to 200 ns pulse duration, 28.7 nJ pulse energy and repetition rate from 232 to 512 kHz. This achievement is attributed to the ultrafast saturable absorption of these layered TMDs in the visible region, as well as the compact and all-fibre laser-cavity design by coating a dielectric mirror on the fibre end facet. This work may open a new route for next-generation high-performance pulsed laser sources in the visible (even ultraviolet) range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1066, "End Page": 1072, "Article Number": null, "DOI": "10.1039/c5nr06981e", "DOI Link": "http://dx.doi.org/10.1039/c5nr06981e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367258500045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abraham, E; Cherpak, V; Senyuk, B; ten Hove, JB; Lee, TW; Liu, QK; Smalyukh, II", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abraham, Eldho; Cherpak, Vladyslav; Senyuk, Bohdan; ten Hove, Jan Bart; Lee, Taewoo; Liu, Qingkun; Smalyukh, Ivan I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly transparent silanized cellulose aerogels for boosting energy efficiency of glazing in buildings", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To maintain comfortable indoor conditions, buildings consume similar to 40% of the energy generated globally. In terms of passively isolating building interiors from cold or hot outdoors, windows and skylights are the least-efficient parts of the building envelope because achieving simultaneously high transparency and thermal insulation of glazing remains a challenge. Here we describe highly transparent aerogels fabricated from cellulose, an Earth-abundant biopolymer, by utilizing approaches such as colloidal self assembly and procedures compatible with roll-to-roll processing. The aerogels have visible-range light transmission of 97-99% (better than glass), haze of similar to 1% and thermal conductivity lower than that of still air. These lightweight materials can be used as panes inside multi-pane insulating glass units and to retrofit existing windows. We demonstrate how aerogels boost energy efficiency and may enable advanced technical solutions for insulating glass units, skylights, daylighting and facade glazing, potentially increasing the role of glazing in building envelopes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 381, "End Page": 396, "Article Number": null, "DOI": "10.1038/s41560-023-01226-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01226-7", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950511100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naghdi, S; Cherevan, A; Giesriegl, A; Guillet-Nicolas, R; Biswas, S; Gupta, T; Wang, J; Haunold, T; Bayer, BC; Rupprechter, G; Toroker, MC; Kleitz, F; Eder, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naghdi, Shaghayegh; Cherevan, Alexey; Giesriegl, Ariane; Guillet-Nicolas, Remy; Biswas, Santu; Gupta, Tushar; Wang, Jia; Haunold, Thomas; Bayer, Bernhard Christian; Rupprechter, Gunther; Toroker, Maytal Caspary; Kleitz, Freddy; Eder, Dominik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective ligand removal to improve accessibility of active sites in hierarchical MOFs for heterogeneous photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While metal organic frameworks offer highly tunable materials for photocatalytic applications, catalytic site accessibility is a crucial parameter. Here, authors demonstrate selective ligand removal to introduce new active sites and mesopores and to enhance photocatalytic H-2 evolution. Metal-organic frameworks (MOFs) are commended as photocatalysts for H-2 evolution and CO2 reduction as they combine light-harvesting and catalytic functions with excellent reactant adsorption capabilities. For dynamic processes in liquid phase, the accessibility of active sites becomes a critical parameter as reactant diffusion is limited by the inherently small micropores. Our strategy is to introduce additional mesopores by selectively removing one ligand in mixed-ligand MOFs via thermolysis. Here we report photoactive MOFs of the MIL-125-Ti family with two distinct mesopore architectures resembling either large cavities or branching fractures. The ligand removal is highly selective and follows a 2-step process tunable by temperature and time. The introduction of mesopores and the associated formation of new active sites have improved the HER rates of the MOFs by up to 500%. We envision that this strategy will allow the purposeful engineering of hierarchical MOFs and advance their applicability in environmental and energy technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 282, "DOI": "10.1038/s41467-021-27775-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27775-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742155000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, XT; Xu, HY; Li, WT; Liu, YY; Shi, YX; Li, Q; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xiaotian; Xu, Hengyue; Li, Wenting; Liu, Yangyi; Shi, Yuxin; Li, Qing; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Embedding Atomically Dispersed Iron Sites in Nitrogen-Doped Carbon Frameworks-Wrapped Silicon Suboxide for Superior Lithium Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon suboxide (SiOx) has attracted widespread interest as Li-ion battery (LIB) anodes. However, its undesirable electronic conductivity and apparent volume effect during cycling impede its practical applications. Herein, sustainable rice husks (RHs)-derived SiO2 are chosen as a feedstock to design SiOx/iron-nitrogen co-doped carbon (Fe-N-C) materials. Using a facile electrospray-carbonization strategy, SiOx nulloparticles (NPs) are encapsulated in the nitrogen-doped carbon (N-C) frameworks decorating atomically dispersed iron sites. Systematic characterizations including high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and X-ray absorption fine structure (XAFS) verify the existence of Fe single atoms and typical coordination environment. Benefiting from its structural and compositional merits, the SiOx/Fe-N-C anode delivers significantly improved discharge capacity of 799.1 mAh g(-1), rate capability, and exceptional durability, compared with pure SiO2 and SiOx/N-C, which has been revealed by the density functional theory (DFT) calculations. Additionally, the electrochemical tests and in situ X-ray diffraction (XRD) analysis reveal the oxidation of LixSi phase and the storage mechanism. The synthetic strategy is universal for the design and synthesis of metal single atoms/clusters dispersed N-C frameworks encapsulated SiOx NPs. Meanwhile, this work provides impressive insights into developing various LIB anode materials suffering from inferior conductivity and huge volume fluctuations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206084", "DOI Link": "http://dx.doi.org/10.1002/advs.202206084", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000895718100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, JM; Zheng, JM; Zhou, ZW; Suo, H; Zhao, Q; Zhou, XJ; Zhang, NM; Molokeev, MS; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Jinmeng; Zheng, Jiming; Zhou, Ziwei; Suo, Hao; Zhao, Xiaoqi; Zhou, Xianju; Zhang, Niumiao; Molokeev, Maxim S.; Guo, Chongfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of red emission and site analysis in Eu2+ doped new-type structure Ba3CaK(PO4)3 for plant growth white LEDs", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel compound Ba3CaK(PO4)(3) (BCKP) with new-type structure was synthesized and its structure was determined by X-ray diffraction Rietveld refinement, in which crystal structure consists of Ba1O(9), Ba2O(12), Ba3O(9), CaO8 and KO10 polyhedra, that's five cationic sites. As a phosphor host, Eu2+ doped BCKP emits cold white light with about 90% quantum efficiency (QE) through entering different cationic sites. Based on the results of refinement, three Eu2+ luminescence centers in sites Ca, Ba2 and K were clearly assigned in Eu2+ solely doped BCKP by the time-resolved emission spectra (TRES), Van Uitert equation, but the emissions of Eu2+ at Ba1 and Ba3 sites are not easy to be determined for the same coordination number (CN). According to their different spatial distribution of the coordinated atoms, the first-principles calculation was used to compute the d orbital splitting energy of Eu2+ ions in Ba1 and Ba3 sites to accurately distinguish the ambiguous luminescence centers. In order to meet the requirement of plant growth spectra, Mn2+ was introduced into BCKP: Eu2+ to enhance the red component of spectra, which not only perfectly match with the absorption spectra of carotenoid and chlorophyll-b, but also LEDs fabricated through combining 365 nm near ultraviolet (n-UV) chip with BCKP: Eu2+, Mn2+ phosphor exhibit excellent parameters including high color rendering index (Ra) (92), excellent correlated color temperature (CCT) (4486 K) and outstanding QE up to 65%. Results confirmed that BCKP: Eu2+/Mn2+ phosphor with great potential applications in white LEDs and plant growth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2019, "Volume": 356, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 236, "End Page": 244, "Article Number": null, "DOI": "10.1016/j.cej.2018.09.036", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2018.09.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447004100025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huebsch, N; Kearney, CJ; Zhao, XH; Kim, J; Cezar, CA; Suo, ZG; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huebsch, Nathaniel; Kearney, Cathal J.; Zhao, Xuanhe; Kim, Jaeyun; Cezar, Christine A.; Suo, Zhigang; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-triggered disruption and self-healing of reversibly cross-linked hydrogels for drug delivery and enhanced chemotherapy", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biological systems are exquisitely sensitive to the location and timing of physiologic cues and drugs. This spatiotemporal sensitivity presents opportunities for developing new therapeutic approaches. Polymer-based delivery systems are used extensively for attaining localized, sustained release of bioactive molecules. However, these devices typically are designed to achieve a constant rate of release. We hypothesized that it would be possible to create digital drug release, which could be accelerated and then switched back off, on demand, by applying ultrasound to disrupt ionically cross-linked hydrogels. We demonstrated that ultrasound does not permanently damage these materials but enables nearly digital release of small molecules, proteins, and condensed oligonucleotides. Parallel in vitro studies demonstrated that the concept of applying temporally short, high-dose bursts of drug exposure could be applied to enhance the toxicity of mitoxantrone toward breast cancer cells. We thus used the hydrogel system in vivo to treat xenograft tumors with mitoxantrone, and found that daily ultrasound-stimulated drug release substantially reduced tumor growth compared with sustained drug release alone. This approach of digital drug release likely will be applicable to a broad variety of polymers and bioactive molecules, and is a potentially useful tool for studying how the timing of factor delivery controls cell fate in vivo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 8", "Publication Year": 2014, "Volume": 111, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9762, "End Page": 9767, "Article Number": null, "DOI": "10.1073/pnas.1405469111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1405469111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338514800026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Li, MY; Lim, JH; Weng, YW; Tay, YWD; Pham, H; Pham, QC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xu; Li, Mingyang; Lim, Jian Hui; Weng, Yiwei; Tay, Yi Wei Daniel; Pham, Hung; Pham, Quang-Cuong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale 3D printing by a team of mobile robots", "Source Title": "AUTOMATION IN CONSTRUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalability is a problem common to most existing 3D printing processes, where the size of the design is strictly constrained by the chamber volume of the 3D printer. This issue is more pronounced in the building and construction industry, where it is impractical to have printers that are larger than actual buildings. One workaround consists in printing smaller pieces, which can then be assembled on-site. This workaround generates however additional design and process complexities, as well as creates potential weaknesses at the assembly interfaces. In this paper, we propose a 3D printing system that employs multiple mobile robots printing concurrently a large, single-piece, structure. We present our system in detail, and report simulation and experimental results. To our knowledge, this is the first physical demonstration of large-scale, concurrent, 3D printing of a concrete structure by multiple mobile robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 95, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 98, "End Page": 106, "Article Number": null, "DOI": "10.1016/j.autcon.2018.08.004", "DOI Link": "http://dx.doi.org/10.1016/j.autcon.2018.08.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446286800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rui, N; Zhang, F; Sun, KH; Liu, ZY; Xu, WQ; Stavitski, E; Senullayake, SD; Rodriguez, JA; Liu, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rui, Ning; Zhang, Feng; Sun, Kaihang; Liu, Zongyuan; Xu, Wenqian; Stavitski, Eli; Senullayake, Sanjaya D.; Rodriguez, Jose A.; Liu, Chang-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogenation of CO2 to Methanol on a Auδ+-In2O3-x Catalyst", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 hydrogenation to methanol has attracted increasing attention with the development of renewable hydrogen. A big challenge is to identify catalysts able to achieve high conversion and selectivity. Here, we report an In2O3-supported Au catalyst that exhibits excellent performance for hydrogenation of CO2 selectively to methanol. In situ characterizations using time-resolved X-ray diffraction, ambient-pressure X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy confirm that a strong metal-support interaction leads to a reactive Au delta+-In2O3-x interface for activation and hydrogenation of CO2 to methanol. An effective gold-indium oxide bonding favors the dispersion of the noble metal and prevents its sintering under reaction conditions. The methanol selectivity reaches 100% at temperatures below 225 degrees C and is more than 70% at 275 degrees C over the Au delta+-In2O3-x catalyst. It is even 67.8% with a space time yield of methanol of 0.47 gMeOH/(h.g(cat)) at 300 degrees C, 5 MPa, and 21,000 cm(3) h(-1) g(cat)(-1). The results obtained here represent the highest selectivity and activity ever reported for CO2 hydrogenation over supported gold catalysts. Our study shows that the strong Au/In2O3 interaction and the intrinsic chemical activity of In2O3 can be used to significantly improve the catalytic performance of Au catalysts, providing promising routes for the rational design and application of Au catalysts beyond CO2 hydrogenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2020, "Volume": 10, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11307, "End Page": 11317, "Article Number": null, "DOI": "10.1021/acscatal.0c02120", "DOI Link": "http://dx.doi.org/10.1021/acscatal.0c02120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577156300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miao, L; Lin, JQ; Huang, YX; Li, LX; Delcassian, D; Ge, YF; Shi, YH; Anderson, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miao, Lei; Lin, Jiaqi; Huang, Yuxuan; Li, Linxian; Delcassian, Derfogail; Ge, Yifan; Shi, Yunhua; Anderson, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic lipid compositions for albumin receptor mediated delivery of mRNA to the liver", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lipid-like nulloparticles (LNPs) have potential as non-viral delivery systems for mRNA therapies. However, repeated administrations of LNPs may lead to accumulation of delivery materials and associated toxicity. To address this challenge, we have developed biodegradable lipids which improve LNPs clearance and reduce toxicity. We modify the backbone structure of Dlin-MC3-DMA by introducing alkyne and ester groups into the lipid tails. We evaluate the performance of these lipids when co-formulated with other amine containing lipid-like materials. We demonstrate that these formulations synergistically facilitate robust mRNA delivery with improved tolerability after single and repeated administrations. We further identify albumin-associated macropinocytosis and endocytosis as an ApoE-independent LNP cellular uptake pathway in the liver. Separately, the inclusion of alkyne lipids significantly increases membrane fusion to enhance mRNA release, leading to synergistic improvement of mRNA delivery. We believe that the rational design of LNPs with multiple amine-lipids increases the material space for mRNA delivery. Lipid-like nulloparticles have applications as non-viral delivery systems for mRNA. Here, the authors develop biodegradable lipids with improved clearance and reduced toxicity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2424, "DOI": "10.1038/s41467-020-16248-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16248-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Duerloo, KAN; Wauson, K; Reed, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yao; Duerloo, Karel-Alexander N.; Wauson, Kerry; Reed, Evan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural semiconductor-to-semimetal phase transition in two-dimensional materials induced by electrostatic gating", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dynamic control of conductivity and optical properties via atomic structure changes is of technological importance in information storage. Energy consumption considerations provide a driving force towards employing thin materials in devices. Monolayer transition metal dichalcogenides are nearly atomically thin materials that can exist in multiple crystal structures, each with distinct electrical properties. By developing new density functional-based methods, we discover that electrostatic gating device configurations have the potential to drive structural semiconductor-to-semimetal phase transitions in some monolayer transition metal dichalcogenides. Here we show that the semiconductor-to-semimetal phase transition in monolayer MoTe2 can be driven by a gate voltage of several volts with appropriate choice of dielectric. We find that the transition gate voltage can be reduced arbitrarily by alloying, for example, for MoxW1-xTe2 monolayers. Our findings identify a new physical mechanism, not existing in bulk materials, to dynamically control structural phase transitions in two-dimensional materials, enabling potential applications in phase-change electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10671, "DOI": "10.1038/ncomms10671", "DOI Link": "http://dx.doi.org/10.1038/ncomms10671", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371021000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yue, O; Wang, XC; Liu, XH; Hou, MD; Zheng, MH; Wang, YY; Cui, BQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yue, Ouyang; Wang, Xuechuan; Liu, Xinhua; Hou, Mengdi; Zheng, Manhui; Wang, Youyou; Cui, Boqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spider-Web and Ant-Tentacle Doubly Bio-Inspired Multifunctional Self-Powered Electronic Skin with Hierarchical nullostructure", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For the practical applications of wearable electronic skin (e-skin), the multifunctional, self-powered, biodegradable, biocompatible, and breathable materials are needed to be assessed and tailored simultaneously. Integration of these features in flexible e-skin is highly desirable; however, it is challenging to construct an e-skin to meet the requirements of practical applications. Herein, a bio-inspired multifunctional e-skin with a multilayer nullostructure based on spider web and ant tentacle is constructed, which can collect biological energy through a triboelectric nullogenerator for the simultaneous detection of pressure, humidity, and temperature. Owing to the poly(vinyl alcohol)/poly(vinylidene fluoride) nullofibers spider web structure, internal bead-chain structure, and the collagen aggregate nullofibers based positive friction material, e-skin exhibits the highest pressure sensitivity (0.48 V kPa(-1)) and high detection range (0-135 kPa). Synchronously, the nullofibers imitating the antennae of ants provide e-skin with short response and recovery time (16 and 25 s, respectively) to a wide humidity range (25-85% RH). The e-skin is demonstrated to exhibit temperature coefficient of resistance (TCR = 0.0075 degrees C-1) in a range of the surrounding temperature (27-55 degrees C). Moreover, the natural collagen aggregate and the all-nullofibers structure ensure the biodegradability, biocompatibility, and breathability of the e-skin, showing great promise for practicability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004377, "DOI": "10.1002/advs.202004377", "DOI Link": "http://dx.doi.org/10.1002/advs.202004377", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000656798700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Toombs, JT; Luitz, M; Cook, CC; Jenne, S; Li, CC; Rapp, BE; Kotz-Helmer, F; Taylor, HK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Toombs, Joseph T.; Luitz, Manuel; Cook, Caitlyn C.; Jenne, Sophie; Li, Chi Chung; Rapp, Bastian E.; Kotz-Helmer, Frederik; Taylor, Hayden K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Volumetric additive manufacturing of silica glass with microscale computed axial lithography", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glass is increasingly desired as a material for manufacturing complex microscopic geometries, from the micro-optics in compact consumer products to microfluidic systems for chemical synthesis and biological analyses. As the size, geometric, surface roughness, and mechanical strength requirements of glass evolve, conventional processing methods are challenged. We introduce microscale computed axial lithography (micro-CAL) of fused silica components, by tomographically illuminating a photopolymersilica nullocomposite that is then sintered. We fabricated three-dimensional microfluidics with internal diameters of 150 micrometers, free-form micro-optical elements with a surface roughness of 6 nullometers, and complex high-strength trusses and lattice structures with minimum feature sizes of 50 micrometers. As a high-speed, layer-free digital light manufacturing process, micro-CAL can process nullocomposites with high solids content and high geometric freedom, enabling new device structures and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2022, "Volume": 376, "Issue": 6590, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 308, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm6459", "DOI Link": "http://dx.doi.org/10.1126/science.abm6459", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783317900051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, Z; Yang, HJ; Zhu, XY; He, P; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Zhi; Yang, Huijun; Zhu, Xingyu; He, Ping; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloconfined/sub-nulloconfined solvent molecules tend to undergo dramatic changes in their properties and behaviours. In this work, we find that unlike typical bulk liquid electrolytes, electrolytes confined in a sub-nulloscale environment (inside channels of a 6.5 angstrom metal-organic framework, defined as a quasi-solid electrolyte) exhibits unusual properties and behaviours: higher boiling points, highly aggregated configurations, decent lithium-ion conductivities, extended electrochemical voltage windows (approximately 5.4 volts versus Li/Li+) and nonflammability at high temperatures. We incorporate this interesting electrolyte into lithium-metal batteries (LMBs) and find that LMBs cycled in the quasi-solid electrolyte demonstrate an electrolyte interphase-free (CEI-free) cathode and dendrite-free Li-metal surface. Moreover, high-voltage LiNi0.8Co0.1Mn0.1O2//Li (NCM-811//Li with a high NCM-811 mass loading of 20 mg cm(-2)) pouch cells assemble with the quasi-solid electrolyte deliver highly stable electrochemical performances even at a high working temperature of 90 degrees C (171 mAh g(-1)after 300 cycles, 89% capacity retention; 164 mAh g -1 after 100 cycles even after being damaged). This strategy for fabricating nonflammable and ultrastable quasi-solid electrolytes is promising for the development of safe and high-energy-density LIBs/LMBs for powering electronic devices under various practical working conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1510, "DOI": "10.1038/s41467-022-29118-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29118-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771678500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Zhao, SL; Pan, CF; Zi, YL; Wang, FC; Yang, C; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chaojie; Zhao, Shilong; Pan, Caofeng; Zi, Yunlong; Wang, Fangcheng; Yang, Cheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A method for quantitatively separating the piezoelectric component from the as-received Piezoelectric signal", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer-based piezoelectric devices are promising for developing future wearable force sensors, nullogenerators, and implantable electronics, etc. The electric signals generated by them are often assumed as solely coming from the piezoelectric effect. However, triboelectric signals originated from contact electrification between the piezoelectric devices and the contacted objects can produce non-negligible interfacial electron transfer, which is often combined with the piezoelectric signal to give a triboelectric-piezoelectric hybrid output, leading to an exaggerated measured piezoelectric signal. Herein, a simple and effective method is proposed for quantitatively identifying and extracting the piezoelectric charge from the hybrid signal. The triboelectric and piezoelectric parts in the hybrid signal generated by a poly(vinylidene fluoride)-based device are clearly differentiated, and their force and charge characteristics in the time domain are identified. This work presents an effective method to elucidate the true piezoelectric performance in practical measurement, which is crucial for evaluating piezoelectric materials fairly and correctly. Difficulties in separating tribo and piezoelectric hybrid signals can lead to an overestimated contribution of the latter. Here, authors propose a method to separate these hybrid signals in the time domain, precisely extracting piezoelectric charge transfer for performance evaluation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1391, "DOI": "10.1038/s41467-022-29087-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29087-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770096400031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abtab, SMT; Alezi, D; Bhatt, PM; Shkurenko, A; Belmabkhout, Y; Aggarwal, H; Weselinski, LJ; Alsadun, N; Samin, U; Hedhili, MN; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abtab, Sk Md Towsif; Alezi, Dalal; Bhatt, Prashant M.; Shkurenko, Aleksander; Belmabkhout, Youssef; Aggarwal, Himanshu; Weselinski, Lukasz J.; Alsadun, Norah; Samin, Umer; Hedhili, Mohamed Nejib; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reticular Chemistry in Action: A Hydrolytically Stable MOF Capturing Twice Its Weight in Adsorbed Water", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrolytically stable adsorbents, with notable water uptake, are of prime importance and offer great potential for many water-adsorption-related applications. Nevertheless, deliberate construction of tunable porous solids with high porosity and high stability remains challenging. Here, we present the successful deployment of reticular chemistry to address this demand: we constructed Cr-soc-MOF-1, a chemically and hydrolytically stable chromium-based metal-organic framework (MOF) with underlying soc topology. Prominently, Cr-soc-MOF-1 offers the requisite thermal and chemical stability concomitant with unique adsorption properties, namely extraordinary high porosity (apparent surface area of 4,549 m(2)/g) affording a water vapor uptake of 1.95 g/g at 70% relative humidity. This exceptional water uptake is maintained over more than 100 adsorption-desorption cycles. Markedly, the adsorbed water can be fully desorbed by just the simple reduction of the relative humidity at 25 degrees C. Cr-soc-MOF-1 offers great potential for use in applications pertaining to water vapor control in enclosed and confined spaces and dehumidification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 105, "Article Number": null, "DOI": "10.1016/j.chempr.2017.11.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.11.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425276100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GW; Huang, SY; Chaves, A; Song, CY; Özçelik, VO; Low, T; Yan, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guowei; Huang, Shenyang; Chaves, Andrey; Song, Chaoyu; Ozcelik, V. Ongun; Low, Tony; Yan, Hugen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared fingerprints of few-layer black phosphorus", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Although highly desirable, a comprehensive infrared characterization is still lacking. Here we report a systematic infrared study of mechanically exfoliated few-layer black phosphorus, with thickness ranging from 2 to 15 layers and photon energy spanning from 0.25 to 1.36 eV. Each few-layer black phosphorus exhibits a thickness-dependent unique infrared spectrum with a series of absorption resonullces, which reveals the underlying electronic structure evolution and serves as its infrared fingerprints. Surprisingly, unexpected absorption features, which are associated with the forbidden optical transitions, have been observed. Furthermore, we unambiguously demonstrate that controllable uniaxial strain can be used as a convenient and effective approach to tune the electronic structure of few-layer black phosphorus. Our study paves the way for black phosphorus applications in infrared photonics and optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14071, "DOI": "10.1038/ncomms14071", "DOI Link": "http://dx.doi.org/10.1038/ncomms14071", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391266200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JH; Xu, K; Liu, N; Reed, D; Li, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Junhua; Xu, Kang; Liu, Nian; Reed, David; Li, Xiaolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crossroads in the renaissance of rechargeable aqueous zinc batteries", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc batteries dominate the primary battery market with alkaline chemistries and recently have been rejuvenated as rechargeable devices to compete for grid-scale energy storage applications. Tremendous effort has been made in the past few years and improved cyclability has been demonstrated in both alkaline, neutral, and mild acidic systems. In this review/perspective, we will elucidate the merits of rechargeable aqueous zinc batteries through side-by-side comparison to Li-ion batteries, examine the challenges and progress made in the pursuit of highly rechargeable alkaline and mild acidic batteries, and finally provide a holistic forward look at the technology. The focus is placed on static closed cell designs, while flow batteries and open systems like zinc-air batteries will not be included due to space constraint.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 45, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 191, "End Page": 212, "Article Number": null, "DOI": "10.1016/j.mattod.2020.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2020.12.003", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000660079700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, ZB; Huyan, WJ; Yang, F; Yao, JR; Tan, RY; Chen, P; Tao, XW; Yao, ZJ; Zhou, JT; Liu, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Zibao; Huyan, Wenjun; Yang, Feng; Yao, Junru; Tan, Ruiyang; Chen, Ping; Tao, Xuewei; Yao, Zhengjun; Zhou, Jintang; Liu, Peijiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Ultra-Wideband and Elevated Temperature Electromagnetic Wave Absorption via Constructing Lightweight Porous Rigid Structure", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing ultra-wideband absorption, desirable attenuation capability at high temperature and mechanical requirements for real-life applications remains a great challenge for microwave absorbing materials. Herein, we have constructed a porous carbon fiber/polymethacrylimide (CP) structure for acquiring promising microwave absorption performance and withstanding both elevated temperature and high strength in a low density. Given the ability of porous structure to induce desirable impedance matching and multiple reflection, the absorption bandwidth of CP composite can reach ultra-wideband absorption of 14 GHz at room temperature and even cover the whole X-band at 473 K. Additionally, the presence of imide ring group in polymethacrylimide and hard bubble wall endows the composite with excellent heat and compressive behaviors. Besides, the lightweight of the CP composite with a density of only 110 mg cm(-3) coupled with high compressive strength of 1.05 MPa even at 453 K also satisfies the requirements in engineering applications. Compared with soft and compressible aerogel materials, we envision that the rigid porous foam absorbing material is particularly suitable for environmental extremes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 173, "DOI": "10.1007/s40820-022-00904-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00904-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843529500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CW; Gordon, KN; Liu, PF; Liu, JY; Zhou, XQ; Hao, PP; Narayan, D; Emmanouilidou, E; Sun, HY; Liu, YT; Brawer, H; Ramirez, AP; Ding, L; Cao, HB; Liu, QH; Dessau, D; Ni, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Chaowei; Gordon, Kyle N.; Liu, Pengfei; Liu, Jinyu; Zhou, Xiaoqing; Hao, Peipei; Narayan, Dushyant; Emmanouilidou, Eve; Sun, Hongyi; Liu, Yuntian; Brawer, Harlan; Ramirez, Arthur P.; Ding, Lei; Cao, Huibo; Liu, Qihang; Dessau, Dan; Ni, Ni", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A van der Waals antiferromagnetic topological insulator with weak interlayer magnetic coupling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic topological insulators (TI) provide an important material platform to explore quantum phenomena such as quantized anomalous Hall effect and Majorana modes, etc. Their successful material realization is thus essential for our fundamental understanding and potential technical revolutions. By realizing a bulk van der Waals material MnBi4Te7 with alternating septuple [MnBi2Te4] and quintuple [Bi2Te3] layers, we show that it is ferromagnetic in plane but antiferromagnetic along the c axis with an out-of-plane saturation field of similar to 0.22T at 2 K. Our angle-resolved photoemission spectroscopy measurements and first-principles calculations further demonstrate that MnBi4Te7 is a Z(2) antiferromagnetic TI with two types of surface states associated with the [MnBi2Te4] or [Bi2Te3] termination, respectively. Additionally, its superlattice nature may make various heterostructures of [MnBi2Te4] and [Bi2Te3] layers possible by exfoliation. Therefore, the low saturation field and the superlattice nature of MnBi4Te7 make it an ideal system to investigate rich emergent phenomena.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 97, "DOI": "10.1038/s41467-019-13814-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13814-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511967900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, W; Cong, H; Huang, W; Huang, Y; Chen, LJ; Pan, AL; Xue, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Wei; Cong, Hui; Huang, Wei; Huang, Yu; Chen, Lijuan; Pan, Anlian; Xue, Chunlai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Germanium/perovskite heterostructure for high-performance and broadband photodetector from visible to infrared telecommunication band", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-performance and broadband heterojunction photodetector has been successfully fabricated. The heterostructure device is based on a uniform and pinhole-free perovskite film constructed on top of a single-crystal germanium layer. The perovskite/germanium photodetector shows enhanced performance and a broad spectrum compared with the single-material-based device. The photon response properties are characterized in detail from the visible to near-infrared spectrum. At an optical fibre communication wavelength of 1550 nm, the heterojunction device exhibits the highest responsivity of 1.4 A/W. The performance is promoted because of an antireflection perovskite coating, the thickness of which is optimized to 150 nm at the telecommunication band. At a visible light wavelength of 680 nm, the device shows outstanding responsivity and detectivity of 228 A/W and 1.6 x 10(10) Jones, respectively. These excellent properties arise from the photoconductive gain boost in the heterostructure device. The presented heterojunction photodetector provides a competitive approach for wide-spectrum photodetection from visible to optical communication areas. Based on the distinguished capacity of light detection and harvesting from the visible to near-infrared spectrum, the designed germanium/perovskite heterostructure configuration is believed to provide new building blocks for novel optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106, "DOI": "10.1038/s41377-019-0218-y", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0218-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497764400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, Y; Guo, YQ; Chen, PZ; Liu, HF; Zhang, MX; Zhang, LD; Yan, WS; Chu, WS; Wu, CZ; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Yun; Guo, Yuqiao; Chen, Pengzuo; Liu, Haifeng; Zhang, Mengxing; Zhang, Lidong; Yan, Wensheng; Chu, Wangsheng; Wu, Changzheng; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-State Regulation of Perovskite Cobaltite to Realize Enhanced Oxygen Evolution Activity", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite electrocatalysts strongly rely on electronic structure regulation, especially for electron configuration (e(g)) and conductivity. However, current regulation strategies inevitably involve ambiguous entanglement of crystals, electrons, and spin degrees of freedom. Here, we developed a spin-state regulation method to optimize oxygen evolution reaction (OER) activity by lattice orientation control of LaCoO3 epitaxial films. The different lattice-oriented LaCoO3 films bring different degrees of distortion of the CoO6 octahedron, successfully inducing a spin-state transition of cobalt from a low spin state (LS t(2g)(6) e(g)(0)) to an intermediate spin state (IS t(2g)(5) e(g)(1)). X-ray absorption spectroscopy of Co L-edge and O K-edge provides experimental support of spin-state transition in different lattice-oriented LaCoO3 films. As expected, LaCoO3 (100) film possesses optimal e(g) electron filling, lower adsorption free energy, and higher conductivity, exhibiting better OER performance than the other two films. Our findings demonstrate that electronic state regulation will be a new avenue for the rational design of high-activity perovskite electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 812, "End Page": 821, "Article Number": null, "DOI": "10.1016/j.chempr.2017.09.003", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.09.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416368000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vegas, AJ; Veiseh, O; Doloff, JC; Ma, ML; Tam, HH; Bratlie, K; Li, J; Bader, AR; Langan, E; Olejnik, K; Fenton, P; Kang, JW; Hollister-Locke, J; Bochenek, MA; Chiu, A; Siebert, S; Tang, K; Jhunjhunwala, S; Aresta-Dasilva, S; Dholakia, N; Thakrar, R; Vietti, T; Chen, M; Cohen, J; Siniakowicz, K; Qi, MRG; McGarrigle, J; Lyle, S; Harlan, DM; Greiner, DL; Oberholzer, J; Weir, GC; Langer, R; Anderson, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vegas, Arturo J.; Veiseh, Omid; Doloff, Joshua C.; Ma, Minglin; Tam, Hok Hei; Bratlie, Kaitlin; Li, Jie; Bader, Andrew R.; Langan, Erin; Olejnik, Karsten; Fenton, Patrick; Kang, Jeon Woong; Hollister-Locke, Jennifer; Bochenek, Matthew A.; Chiu, Alan; Siebert, Sean; Tang, Katherine; Jhunjhunwala, Siddharth; Aresta-Dasilva, Stephanie; Dholakia, Nimit; Thakrar, Raj; Vietti, Thema; Chen, Michael; Cohen, Josh; Siniakowicz, Karolina; Qi, Meirigeng; McGarrigle, James; Lyle, Stephen; Harlan, David M.; Greiner, Dale L.; Oberholzer, Jose; Weir, Gordon C.; Langer, Robert; Anderson, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combinatorial hydrogel library enables identification of materials that mitigate the foreign body response in primates", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The foreign body response is an immune-mediated reaction that can lead to the failure of implanted medical devices and discomfort for the recipient(1-6). There is a critical need for biomaterials that overcome this key challenge in the development of medical devices. Here we use a combinatorial approach for covalent chemical modification to generate a large library of variants of one of the most widely used hydrogel biomaterials, alginate. We evaluated the materials in vivo and identified three triazole-containing analogs that substantially reduce foreign body reactions in both rodents and, for at least 6 months, in non-human primates. The distribution of the triazole modification creates a unique hydrogel surface that inhibits recognition by macrophages and fibrous deposition. In addition to the utility of the compounds reported here, our approach may enable the discovery of other materials that mitigate the foreign body response.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 34, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": "+", "Article Number": null, "DOI": "10.1038/nbt.3462", "DOI Link": "http://dx.doi.org/10.1038/nbt.3462", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371802600033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, YT; Zhang, ZY; Yang, FN; Li, J; Liu, ZB; Ren, WC; Zhang, S; Liu, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Yuting; Zhang, Zhiyuan; Yang, Fengning; Li, Jiong; Liu, Zhibo; Ren, Wencai; Zhang, Shuo; Liu, Bilu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized hydroxide-mediated nickel-based electrocatalysts for high-current-density hydrogen evolution in alkaline media", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale production of green hydrogen by electrochemical water splitting is considered as a promising technology to address critical energy challenges caused by the extensive use of fossil fuels. Although nonprecious nickel-based catalysts work well at low current densities, they need large overpotentials at high current densities, which hinders their wide applications in practical industry. Here we report a hydroxide-mediated nickel-based electrocatalyst for high-current-density hydrogen evolution, which delivers a current density of 1000 mA cm(-2) at an ultralow overpotential of 97 mV. Combined X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) results show charge redistribution of Ni sites caused by Mo and surface Fe, which can stabilize the surface nickel hydroxide at high current densities for promoting the water dissociation step. Combined in situ XAS, quasi in situ XPS, and density functional theory calculations indicate that Fe plays an important role in the improved catalytic activity. Such a catalyst is synthesized at the metre-size scale and delivers a current density of 500 mA cm(-2) at 1.56 V in overall water splitting, demonstrating its potential for practical use. This work highlights a charge engineering strategy to design efficient catalysts for high current density electrochemical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2021, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4610, "End Page": 4619, "Article Number": null, "DOI": "10.1039/d1ee01487k", "DOI Link": "http://dx.doi.org/10.1039/d1ee01487k", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678047600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, CZ; Wang, S; San Hui, K; Wang, KX; Li, JF; Gao, HX; Zha, CY; Zhang, XM; Dinh, DA; Wu, XL; Tang, ZK; Wan, JW; Shao, ZP; Hui, KN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Cheng-Zong; Wang, Shuo; San Hui, Kwan; Wang, Kaixi; Li, Junfeng; Gao, Haixing; Zha, Chenyang; Zhang, Xiaomeng; Dinh, Duc Anh; Wu, Xi-Lin; Tang, Zikang; Wan, Jiawei; Shao, Zongping; Hui, Kwun Nam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Immobilizing Atomically Dispersed Ru on Oxygen-Defective Co3O4 for Efficient Oxygen Evolution", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synergistic regulation of the electronic structures of transition-metal oxide-based catalysts via oxygen vacancy defects and single -atom doping is efficient to boost their oxygen evolution reaction (OER) performance, which remains challenging due to complex synthetic procedures. Herein, a facile defect-induced in situ single-atom deposition strategy is developed to anchor atomically dispersed Ru single-atom onto oxygen vacancy-rich cobalt oxides (Ru/Co3O4-x) based on the spontaneous redox reaction between Ru3+ ions and nonstoichiometric Co3O4-x. Accordingly, the as-prepared Ru/Co3O4-x electrocatalyst with the coex-istence of oxygen vacancies and Ru atoms exhibits excellent performances toward OER with a low overpotential of 280 mV at 10 mA cm(-2), a small Tafel slope value of 86.9 mV dec(-1), and good long-term stability in alkaline media. Furthermore, density functional theory calculations uncover that oxygen vacancy and atomically dispersed Ru could synergistically tailor electron decentralization and d-band center of Co atoms, further optimizing the adsorption of oxygen-based intermediates (*OH, *O, and *OOH) and reducing the reaction barriers of OER. This work proposes an available strategy for constructing electrocatalysts with abundant oxygen vacancies and atomically dispersed noble metal and presents a deep understanding of synergistic electronic engineering of transition-metal-based catalysts to boost oxygen evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2023, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2462, "End Page": 2471, "Article Number": null, "DOI": "10.1021/acscatal.2c04946", "DOI Link": "http://dx.doi.org/10.1021/acscatal.2c04946", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927354200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Wang, HL; Yuan, WJ; Li, YH; Gao, P; Tiwari, N; Chen, X; Wang, ZH; Niu, GY; Cheng, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Li; Wang, Hongli; Yuan, Wenjing; Li, Yuhang; Gao, Peng; Tiwari, Naveen; Chen, Xue; Wang, Zihan; Niu, Guangyu; Cheng, Huanyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable Pressure Sensors Based on MXene/Tissue Papers for Wireless Human Health Monitoring", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though the widely available, low-cost, and disposable papers have been explored in flexible paper-based pressure sensors, it is still difficult for them to simultaneously achieve ultrahigh sensitivity, low limit and broad range of detection, and high-pressure resolution. Herein, we demonstrate a novel flexible paper-based pressure sensing platform that features the MXene-coated tissue paper (MTP) sandwiched between a polyimide encapsulation layer and a printing paper with interdigital electrodes. After replacing the polyimide with weighing paper in the MTP pressure sensor, the silver interdigital electrodes can be recycled through incineration. The resulting pressure sensor with polyimide or paper encapsulation exhibits a high sensitivity of 509.5 or 344.0 kPa(-1), a low limit (similar to 1 Pa) and a broad range (100 kPa) of detection, and outstanding stability over 10 000 loading/unloading cycles. With ultrahigh sensitivity over a wide pressure range, the flexible pressure sensor can monitor various physiological signals and human movements. Configuring the pressure sensors into an array layout results in a smart artificial electronic skin to recognize the spatial pressure distribution. The flexible pressure sensor can also be integrated with signal processing and wireless communication modules on a face mask as a remote respiration monitoring system to wirelessly detect various respiration conditions and respiratory abnormalities for early self-identification of opioid overdose, pulmonary fibrosis, and other cardiopulmonary diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2021, "Volume": 13, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 60531, "End Page": 60543, "Article Number": null, "DOI": "10.1021/acsami.1c22001", "DOI Link": "http://dx.doi.org/10.1021/acsami.1c22001", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731624700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fallahi, A; Guldentops, G; Tao, MJ; Granados-Focil, S; Van Dessel, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fallahi, Ali; Guldentops, Gert; Tao, Mingjiang; Granados-Focil, Sergio; Van Dessel, Steven", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Review on solid-solid phase change materials for thermal energy storage: Molecular structure and thermal properties", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-solid phase change materials (SS-PCMs) for thermal energy storage have received increasing interest because of their high energy-storage density and inherent advantages over solid-liquid counterparts (e.g., leakage free, no need for encapsulation, less phase segregation and smaller volume variation). Four main SS-PCMs for thermal energy storage are reviewed, with a focus on their thermal properties and the relationship between molecular structure, processes involved during phase transition, and thermal properties. This review aims to provide guidance for selecting appropriate SS-PCMs for various applications and tailoring the synthesis of SS-PCMs with desired thermal, physical and mechanical properties. Challenges and opportunities to use of SS-PCMs for thermal storage and other applications are also discussed. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 25", "Publication Year": 2017, "Volume": 127, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1427, "End Page": 1441, "Article Number": null, "DOI": "10.1016/j.applthermaleng.2017.08.161", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2017.08.161", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413608400136", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XT; Liang, ET; Yuan, JJ; Qiu, HY; Chen, XD; Zhao, FL; Dong, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xin-Tao; Liang, En-Tao; Yuan, Jia-Jun; Qiu, Hao-Yang; Chen, Xiao-Dong; Zhao, Fu-Li; Dong, Jian-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A silicon-on-insulator slab for topological valley transport", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Backscattering suppression in silicon-on-insulator (SOI) is one of the central issues to reduce energy loss and signal distortion, enabling for capability improvement of modern information processing systems. Valley physics provides an intriguing way for robust information transfer and unidirectional coupling in topological nullophotonics. Here we realize topological transport in a SOI valley photonic crystal slab. Localized Berry curvature near zone corners guarantees the existence of valley-dependent edge states below light cone, maintaining in-plane robustness and light confinement simultaneously. Topologically robust transport at telecommunication is observed along two sharp-bend interfaces in subwavelength scale, showing flat-top high transmission of similar to 10% bandwidth. Topological photonic routing is achieved in a bearded-stack interface, due to unidirectional excitation of valley-chirality-locked edge state from the phase vortex of a nulloscale microdisk. These findings show the prototype of robustly integrated devices, and open a new door towards the observation of non-trivial states even in non-Hermitian systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 702, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 872, "DOI": "10.1038/s41467-019-08881-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08881-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459097100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, X; Wen, JH; Cheng, L; Yu, DL; Zhang, HJ; Gumbsch, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Xin; Wen, Jihong; Cheng, Li; Yu, Dianlong; Zhang, Hongjia; Gumbsch, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programmable gear-based mechanical metamaterials", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A design paradigm to create robust robotic metamaterials using versatile gear clusters is demonstrated. It enables intriguing programmability of elastic properties and shape while preserving stability for intelligent machines. Elastic properties of classical bulk materials can hardly be changed or adjusted in operando, while such tunable elasticity is highly desired for robots and smart machinery. Although possible in reconfigurable metamaterials, continuous tunability in existing designs is plagued by issues such as structural instability, weak robustness, plastic failure and slow response. Here we report a metamaterial design paradigm using gears with encoded stiffness gradients as the constituent elements and organizing gear clusters for versatile functionalities. The design enables continuously tunable elastic properties while preserving stability and robust manoeuvrability, even under a heavy load. Such gear-based metamaterials enable excellent properties such as continuous modulation of Young's modulus by two orders of magnitude, shape morphing between ultrasoft and solid states, and fast response. This allows for metamaterial customization and brings fully programmable materials and adaptive robots within reach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 21, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 869, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01269-3", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01269-3", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808423100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ratautaite, V; Boguzaite, R; Brazys, E; Ramanaviciene, A; Ciplys, E; Juozapaitis, M; Slibinskas, R; Bechelany, M; Ramanavicius, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ratautaite, Vilma; Boguzaite, Raimonda; Brazys, Ernestas; Ramanaviciene, Almira; Ciplys, Evaldas; Juozapaitis, Mindaugas; Slibinskas, Rimantas; Bechelany, Mikhael; Ramanavicius, Arunas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecularly imprinted polypyrrole based sensor for the detection of SARS-CoV-2 spike glycoprotein", "Source Title": "ELECTROCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study describes the application of a polypyrrole-based sensor for the determination of SARS-CoV-2-S spike glycoprotein. The SARS-CoV-2-S spike glycoprotein is a spike protein of the coronavirus SARS-CoV-2 that recently caused the worldwide spread of COVID-19 disease. This study is dedicated to the devel-opment of an electrochemical determination method based on the application of molecularly imprinted polymer technology. The electrochemical sensor was designed by molecular imprinting of polypyrrole (Ppy) with SARS-CoV-2-S spike glycoprotein (MIP-Ppy). The electrochemical sensors with MIP-Ppy and with polypyrrole without imprints (NIP-Ppy) layers were electrochemically deposited on a platinum elec-trode surface by a sequence of potential pulses. The performance of polymer layers was evaluated by pulsed amperometric detection. According to the obtained results, a sensor based on MIP-Ppy is more sensitive to the SARS-CoV-2-S spike glycoprotein than a sensor based on NIP-Ppy. Also, the results demon-strate that the MIP-Ppy layer is more selectively interacting with SARS-CoV-2-S glycoprotein than with bovine serum albumin. This proves that molecularly imprinted MIP-Ppy-based sensors can be applied for the detection of SARS-CoV-2 virus proteins.(c) 2021 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2022, "Volume": 403, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 139581, "DOI": "10.1016/j.electacta.2021.139581", "DOI Link": "http://dx.doi.org/10.1016/j.electacta.2021.139581", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000775936900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dargusch, M; Liu, WD; Chen, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dargusch, Matthew; Liu, Wei-Di; Chen, Zhi-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoelectric Generators: Alternative Power Supply for Wearable Electrocardiographic Systems", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research interest in the development of real-time monitoring of personal health indicators using wearable electrocardiographic systems has intensified in recent years. New advanced thermoelectrics are potentially a key enabling technology that can be used to transform human body heat into power for use in wearable electrographic monitoring devices. This work provides a systematic review of the potential application of thermoelectric generators for use as power sources in wearable electrocardiographic monitoring systems. New strategies on miniaturized rigid thermoelectric modules combined with batteries or supercapacitors can provide adequate power supply for wearable electrocardiographic systems. Flexible thermoelectric generators can also support wearable electrocardiographic systems directly when a heat sink is incorporated into the design in order to enlarge and stabilize the temperature gradient. Recent advances in enhancing the performance of novel fiber/fabric based flexible thermoelectrics has opened up an exciting direction for the development of wearable electrocardiographic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001362, "DOI": "10.1002/advs.202001362", "DOI Link": "http://dx.doi.org/10.1002/advs.202001362", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558190700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YH; Liu, PF; Pan, LF; Wang, HF; Yang, ZZ; Zheng, LR; Hu, P; Zhao, HJ; Gu, L; Yang, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yu Hang; Liu, Peng Fei; Pan, Lin Feng; Wang, Hai Feng; Yang, Zhen Zhong; Zheng, Li Rong; Hu, P.; Zhao, Hui Jun; Gu, Lin; Yang, Hua Gui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Local atomic structure modulations activate metal oxide as electrocatalyst for hydrogen evolution in acidic water", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modifications of local structure at atomic level could precisely and effectively tune the capacity of materials, enabling enhancement in the catalytic activity. Here we modulate the local atomic structure of a classical but inert transition metal oxide, tungsten trioxide, to be an efficient electrocatalyst for hydrogen evolution in acidic water, which has shown promise as an alternative to platinum. Structural analyses and theoretical calculations together indicate that the origin of the enhanced activity could be attributed to the tailored electronic structure by means of the local atomic structure modulations. We anticipate that suitable structure modulations might be applied on other transition metal oxides to meet the optimal thermodynamic and kinetic requirements, which may pave the way to unlock the potential of other promising candidates as cost-effective electrocatalysts for hydrogen evolution in industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8064, "DOI": "10.1038/ncomms9064", "DOI Link": "http://dx.doi.org/10.1038/ncomms9064", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360353000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Li, JH; Cheng, MQ; Wang, QJ; Yeung, KWK; Chu, PK; Zhang, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Li, Jinhua; Cheng, Mengqi; Wang, Qiaojie; Yeung, Kelvin W. K.; Chu, Paul K.; Zhang, Xianlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc-Modified Sulfonated Polyetheretherketone Surface with Immunomodulatory Function for Guiding Cell Fate and Bone Regeneration", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The cytokines released by immune cells are considered important factors to induce bone tissue regeneration. However, the pathway of those bone-targeting macrophage cytokines induced by biomaterial surface under tissue microenvironment is rarely reported. In this study, the immunomodulatory capability of zinc ions on macrophage polarization and its effects on osteogenic differentiation are investigated. Hence, a layer of zinc ions are incorporated on sulfonated polyetheretherketone (SPEEK) biomaterials by using a customized magnetron sputtering technique. The results reveal that the microenvironment on Zn-coated SPEEK can modulate nonactivated macrophage polarization to an anti-inflammatory phenotype and induce the secretion of anti-inflammatory and osteogenic cytokines. The osteogenic differentiation capability of bone marrow stromal cells (BMSCs) is therefore enhanced, leading to improved osteointegration between the zinc-coated SPEEK and bone tissue. This study verifies that zinc ion is a promising additive in the osteoimmunomodulation process and provides knowledge that may pave the way to develop the next generation of immunomodulatory biomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800749, "DOI": "10.1002/advs.201800749", "DOI Link": "http://dx.doi.org/10.1002/advs.201800749", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, Z; Wang, JD; Lu, ZH; Zhan, RM; Ou, YT; Wang, L; Dahbi, M; Alami, J; Lu, J; Amine, K; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Zhao; Wang, Jindi; Lu, Ziheng; Zhan, Renming; Ou, Yangtao; Wang, Li; Dahbi, Mouad; Alami, Jones; Lu, Jun; Amine, Khalil; Sun, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast Metal Electrodeposition Revealed by In Situ Optical Imaging and Theoretical Modeling towards Fast-Charging Zn Battery Chemistry", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic Zn is a preferred anode material for rechargeable aqueous batteries towards a smart grid and renewable energy storage. Understanding how the metal nucleates and grows at the aqueous Zn anode is a critical and challenging step to achieve full reversibility of Zn battery chemistry, especially under fast-charging conditions. Here, by combining in situ optical imaging and theoretical modeling, we uncover the critical parameters governing the electrodeposition stability of the metallic Zn electrode, that is, the competition among crystallographic thermodynamics, kinetics, and Zn2+-ion diffusion. Moreover, steady-state Zn metal plating/ stripping with Coulombic efficiency above 99 % is achieved at 10-100 mA cm(-2) in a reasonably high concentration (3 M) ZnSO4 electrolyte. Significantly, a long-term cycling-stable Zn metal electrode is realized with a depth of discharge of 66.7 % under 50 mA cm(-2) in both Zn parallel to Zn symmetrical cells and MnO2 parallel to Zn full cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2022, "Volume": 61, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202116560", "DOI": "10.1002/anie.202116560", "DOI Link": "http://dx.doi.org/10.1002/anie.202116560", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753680400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, L; Lu, T; Xu, GJ; Zhang, XH; Jiang, ZX; Zhang, ZQ; Wang, YT; Han, PX; Cui, GL; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Lang; Lu, Tao; Xu, Gaojie; Zhang, Xiaohu; Jiang, Zhaoxuan; Zhang, Zengqi; Wang, Yantao; Han, Pengxian; Cui, Guanglei; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal runaway routes of large-format lithium-sulfur pouch cell batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries emerge as one of the most attractive energy storage systems due to their ultra-high theoretical energy densities, but the pace of their thermal safety assessment is obviously lagging behind. Herein, by investigating the thermal runaway behavior of Li-S pouch cells from the materials level, we unprecedentedly revealed that the thermal runaway route starts from cathode-induced reactions and then gets accelerated by reactions from the anode. Besides, the solvent vaporization is verified to dominate pressure building up during thermal runaway. Moreover, Li-S batteries employing varied electrolytes with different thermal stabilities, even inorganic all solid-state electrolytes, all undergo rapid thermal runaway at a narrow temperature range due to the intrinsic thermal features of the sulfur cathode and Li metal anode sublimating, melting, and cross-reacting at high temperatures. The in-depth depicted thermal runaway routes will deliver great inspiration for mitigating the safety issues of next generation batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 906, "End Page": 922, "Article Number": null, "DOI": "10.1016/j.joule.2022.02.015", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.02.015", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798521700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, ZM; Xu, L; Xie, C; Guo, LR; Zhang, LB; Guo, SH; Peng, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Zhimeng; Xu, Lei; Xie, Cheng; Guo, Lirong; Zhang, Libo; Guo, Shenghui; Peng, Jinhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of CuCo2S4@Expanded Graphite with crystal/amorphous heterointerface and defects for electromagnetic wave absorption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The remarkable advantages of heterointerface and defect engineering and their unique electromagnetic characteristics inject infinite vitality into the design of advanced carbon-matrix electromagnetic wave absorbers. However, understanding the interface and dipole effects based on microscopic and macroscopic perspectives, rather than semi-empirical rules, can facilitate the design of heterointerfaces and defects to adjust the impedance matching and electromagnetic wave absorption of the material, which is currently lacking. Herein, CuCo2S4@Expanded Graphite heterostructure with multiple heterointerfaces and cation defects are reported, and the morphology, interfaces and defects of component are regulated by varying the concentration of metal ions. The results show that the 3D flower-honeycomb morphology, the crystal-crystal/amorphous heterointerfaces and the abundant cation defects can effectively adjust the conductive and polarization losses, achieve the impedance matching balance of carbon materials, and improve the absorption of electromagnetic wave. For the sample CEG-6, the effective absorption of Ku band with RLmin of -72.28 dB and effective absorption bandwidth of 4.14 GHz is realized at 1.4 mm, while the filler loading is only 7.0 wt. %. This article reports on the establishment of potential relationship between crystal-crystal/amorphous heterointerfaces, cation defects, and the impedance matching of carbon materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5951, "DOI": "10.1038/s41467-023-41697-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41697-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001074590000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, MD; Chen, L; Aras, K; Liang, CM; Chen, XX; Zhao, HB; Li, K; Faye, NR; Sun, BH; Kim, JH; Bai, WB; Yang, QS; Ma, YH; Lu, W; Song, EM; Baek, JM; Lee, YJ; Liu, C; Model, JB; Yang, GJ; Ghaffari, R; Huang, YG; Efimov, IR; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Mengdi; Chen, Lin; Aras, Kedar; Liang, Cunman; Chen, Xuexian; Zhao, Hangbo; Li, Kan; Faye, Ndeye Rokhaya; Sun, Bohan; Kim, Jae-Hwan; Bai, Wubin; Yang, Quansan; Ma, Yuhang; Lu, Wei; Song, Enming; Baek, Janice Mihyun; Lee, Yujin; Liu, Clifford; Model, Jeffrey B.; Yang, Guanjun; Ghaffari, Roozbeh; Huang, Yonggang; Efimov, Igor R.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catheter-integrated soft multilayer electronic arrays for multiplexed sensing and actuation during cardiac surgery", "Source Title": "NATURE BIOMEDICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft multilayer electronic arrays on endocardial balloon catheters allow for multiplexed high-density spatiotemporal sensing and actuation, as shown in perfused ex vivo hearts. The rigidity and relatively primitive modes of operation of catheters equipped with sensing or actuation elements impede their conformal contact with soft-tissue surfaces, limit the scope of their uses, lengthen surgical times and increase the need for advanced surgical skills. Here, we report materials, device designs and fabrication approaches for integrating advanced electronic functionality with catheters for minimally invasive forms of cardiac surgery. By using multiphysics modelling, plastic heart models and Langendorff animal and human hearts, we show that soft electronic arrays in multilayer configurations on endocardial balloon catheters can establish conformal contact with curved tissue surfaces, support high-density spatiotemporal mapping of temperature, pressure and electrophysiological parameters and allow for programmable electrical stimulation, radiofrequency ablation and irreversible electroporation. Integrating multimodal and multiplexing capabilities into minimally invasive surgical instruments may improve surgical performance and patient outcomes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 997, "End Page": 1009, "Article Number": null, "DOI": "10.1038/s41551-020-00604-w", "DOI Link": "http://dx.doi.org/10.1038/s41551-020-00604-w", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568441600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hannull, MA; Hoque, MM; Hussain, A; Yusof, Y; Ker, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hannull, Mahammad A.; Hoque, Md. Murshadul; Hussain, Aini; Yusof, Yushaizad; Ker, Pin Jern", "Book Author Full Names": null, "Group Authors": null, "Article Title": "State-of-the-Art and Energy Management System of Lithium-Ion Batteries in Electric Vehicle Applications:Issues and Recommendations", "Source Title": "IEEE ACCESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of rechargeable batteries are now available in world markets for powering electric vehicles (EVs). The lithium-ion (Li-ion) battery is considered the best among all battery types and cells because of its superior characteristics and performance. The positive environmental impacts and recycling potential of lithium batteries have influenced the development of new research for improving Li-ion battery technologies. However, the cost reduction, safe operation, and mitigation of negative ecological impacts are now a common concern for advancement. This paper provides a comprehensive study on the state of the art of Li-ion batteries including the fundamentals, structures, and overall performance evaluations of different types of lithium batteries. A study on a battery management system for Li-ion battery storage in EV applications is demonstrated, which includes a cell condition monitoring, charge, and discharge control, states estimation, protection and equalization, temperature control and heat management, battery fault diagnosis, and assessment aimed at enhancing the overall performance of the system. It is observed that the Li-ion batteries are becoming very popular in vehicle applications due to price reductions and lightweight with high power density. However, the management of the charging and discharging processes, CO2 and greenhouse gases emissions, health effects, and recycling and refurbishing processes have still not been resolved satisfactorily. Consequently, this review focuses on the many factors, challenges, and problems and provides recommendations for sustainable battery manufacturing for future EVs. This review will hopefully lead to increasing efforts toward the development of an advanced Li-ion battery in terms of economics, longevity, specific power, energy density, safety, and performance in vehicle applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 533, "Times Cited, All Databases": 581, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19362, "End Page": 19378, "Article Number": null, "DOI": "10.1109/ACCESS.2018.2817655", "DOI Link": "http://dx.doi.org/10.1109/ACCESS.2018.2817655", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430817400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shimazaki, Y; Schwartz, I; Watanabe, K; Taniguchi, T; Kroner, M; Imamoglu, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shimazaki, Yuya; Schwartz, Ido; Watanabe, Kenji; Taniguchi, Takashi; Kroner, Martin; Imamoglu, Atac", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly correlated electrons and hybrid excitons in a moire heterostructure", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials and their heterostructures constitute a promising platform to study correlated electronic states, as well as the many-body physics of excitons. Transport measurements on twisted graphene bilayers have revealed a plethora of intertwined electronic phases, including Mott insulators, strange metals and superconductors(1-5). However, signatures of such strong electronic correlations in optical spectroscopy have hitherto remained unexplored. Here we present experiments showing how excitons that are dynamically screened by itinerant electrons to form exciton-polarons(6,7) can be used as a spectroscopic tool to investigate interaction-induced incompressible states of electrons. We study a molybdenum diselenide/hexagonal boron nitride/molybdenum diselenide heterostructure that exhibits a long-period moire superlattice, as evidenced by coherent hole-tunnelling-mediated avoided crossings of an intralayer exciton with three interlayer exciton resonullces separated by about five millielectronvolts. For electron densities corresponding to half-filling of the lowest moire subband, we observe strong layer pseudospin paramagnetism, demonstrated by an abrupt transfer of all the (roughly 1,500) electrons from one molybdenum diselenide layer to the other on application of a small perpendicular electric field. Remarkably, the electronic state at half-filling of each molybdenum diselenide layer is resilient towards charge redistribution by the applied electric field, demonstrating an incompressible Mott-like state of electrons. Our experiments demonstrate that optical spectroscopy provides a powerful tool for investigating strongly correlated electron physics in the bulk and paves the way for investigating Bose-Fermi mixtures of degenerate electrons and dipolar excitons. Optical spectroscopy is used to probe correlated electronic states in a moire heterostructure, showing many-body effects such as strong layer paramagnetism and an incompressible Mott-like state of electrons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 580, "Issue": 7804, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 472, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2191-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2191-2", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526290100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, JH; Sun, L; Ge, YC; Li, W; Hendon, CH; Li, J; Gul, S; Yano, JK; Stach, EA; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Jin-Hu; Sun, Lei; Ge, Yicong; Li, Wenbin; Hendon, Christopher H.; Li, Ju; Gul, Sheraz; Yano, Junko; Stach, Eric A.; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Signature of Metallic Behavior in the Metal-Organic Frameworks M3(hexaiminobenzene)2 (M = Ni, Cu)", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The two-dimensionally connected metal organic frameworks (MOFs) Ni-3(HIB)(2) and Cu-3(HIB)(2) (HIB = hexaiminobenzene) are bulk electrical conductors and exhibit ultraviolet-photoelectron spectroscopy (UPS) signatures expected of metallic solids. Electronic band structure calculations confirm that in both materials the Fermi energy lies in a partially filled delocalized band. Together with additional structural characterization and microscopy data, these results represent the first report of metallic behavior and permanent porosity coexisting within a metal organic framework.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 4", "Publication Year": 2017, "Volume": 139, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13608, "End Page": 13611, "Article Number": null, "DOI": "10.1021/jacs.7b07234", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b07234", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412716900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yagi, S; Yamada, I; Tsukasaki, H; Seno, A; Murakami, M; Fujii, H; Chen, H; Umezawa, N; Abe, H; Nishiyama, N; Mori, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yagi, Shunsuke; Yamada, Ikuya; Tsukasaki, Hirofumi; Seno, Akihiro; Murakami, Makoto; Fujii, Hiroshi; Chen, Hungru; Umezawa, Naoto; Abe, Hideki; Nishiyama, Norimasa; Mori, Shigeo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalency-reinforced oxygen evolution reaction catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction that occurs during water oxidation is of considerable importance as an essential energy conversion reaction for rechargeable metal-air batteries and direct solar water splitting. Cost-efficient ABO(3) perovskites have been studied extensively because of their high activity for the oxygen evolution reaction; however, they lack stability, and an effective solution to this problem has not yet been demonstrated. Here we report that the Fe4+-based quadruple perovskite CaCu3Fe4O12 has high activity, which is comparable to or exceeding those of state-of-the-art catalysts such as Ba0.5Sr0.5Co0.8Fe0.2O3 - delta and the gold standard RuO2. The covalent bonding network incorporating multiple Cu2+ and Fe4+ transition metal ions significantly enhances the structural stability of CaCu3Fe4O12, which is key to achieving highly active long-life catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 424, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8249, "DOI": "10.1038/ncomms9249", "DOI Link": "http://dx.doi.org/10.1038/ncomms9249", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363017500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Musso, YS; Salgado, PR; Mauri, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Musso, Yanina S.; Salgado, Pablo R.; Mauri, Adriana N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smart edible films based on gelatin and curcumin", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work studied the preparation of edible smart films based on gelatin and curcumin. Films were prepared by casting using water and an ethanol-water mixture as solvents. The addition of curcumin, besides affecting the physicochemical properties of gelatin films, colored them depending on the pH of the film-forming dispersion (yellow at pH = 6 and red at pH = 11). It also provided films with important antioxidant properties, but no antimicrobial activity. The response of these materials against pH changes was evaluated simulating their contact with liquid and semisolid foods, and with a container headspace at acid and alkaline pH. In all tests, gelatin films with curcumin added could modify their color after being in contact with media of different pH. The use of an ethanol-water mixture as solvent was a good alternative to intensify film color and the visualization of their response capacity against pH changes, as well as to increase the antioxidant properties and hydrophobicity of films. These edible films could be used as smart food packaging, since they could inform consumers if the product was suitable for consumption through their capacity to sense pH changes. (C) 2016 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 66, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8, "End Page": 15, "Article Number": null, "DOI": "10.1016/j.foodhyd.2016.11.007", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2016.11.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392779100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, YS; Yin, RT; Pfenniger, A; Koo, J; Avila, R; Lee, KB; Chen, SW; Lee, G; Li, G; Qiao, Y; Murillo-Berlioz, A; Kiss, A; Han, SL; Lee, SM; Li, CH; Xie, ZQ; Chen, YY; Burrell, A; Geist, B; Jeong, H; Kim, J; Yoon, HJ; Banks, A; Kang, SK; Zhang, ZJ; Haney, CR; Sahakian, AV; Johnson, D; Efimova, T; Huang, YG; Trachiotis, GD; Knight, BP; Arora, RK; Efimov, IR; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Yeon Sik; Yin, Rose T.; Pfenniger, Anna; Koo, Jahyun; Avila, Raudel; Benjamin Lee, K.; Chen, Sheena W.; Lee, Geumbee; Li, Gang; Qiao, Yun; Murillo-Berlioz, Alejandro; Kiss, Alexi; Han, Shuling; Lee, Seung Min; Li, Chenhang; Xie, Zhaoqian; Chen, Yu-Yu; Burrell, Amy; Geist, Beth; Jeong, Hyoyoung; Kim, Joohee; Yoon, Hong-Joon; Banks, Anthony; Kang, Seung-Kyun; Zhang, Zheng Jenny; Haney, Chad R.; Sahakian, Alan Varteres; Johnson, David; Efimova, Tatiana; Huang, Yonggang; Trachiotis, Gregory D.; Knight, Bradley P.; Arora, Rishi K.; Efimov, Igor R.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully implantable and bioresorbable cardiac pacemakers without leads or batteries", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A biodegradable pacemaker without external leads improves the safety of temporary cardiac pacing. Temporary cardiac pacemakers used in periods of need during surgical recovery involve percutaneous leads and externalized hardware that carry risks of infection, constrain patient mobility and may damage the heart during lead removal. Here we report a leadless, battery-free, fully implantable cardiac pacemaker for postoperative control of cardiac rate and rhythm that undergoes complete dissolution and clearance by natural biological processes after a defined operating timeframe. We show that these devices provide effective pacing of hearts of various sizes in mouse, rat, rabbit, canine and human cardiac models, with tailored geometries and operation timescales, powered by wireless energy transfer. This approach overcomes key disadvantages of traditional temporary pacing devices and may serve as the basis for the next generation of postoperative temporary pacing technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 39, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1228, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41587-021-00948-x", "DOI Link": "http://dx.doi.org/10.1038/s41587-021-00948-x", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667605500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, D; Zhang, YJ; Zhang, JQ; Wang, ZY; Zhu, LY; Fang, J; Xia, BZ; Wang, Z; Lu, K; Ma, W; Wei, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Dan; Zhang, Yajie; Zhang, Jianqi; Wang, Zaiyu; Zhu, Lingyun; Fang, Jin; Xia, Benzheng; Wang, Zhen; Lu, Kun; Ma, Wei; Wei, Zhixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorination-enabled optimal morphology leads to over 11% efficiency for inverted small-molecule organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processable small molecules for organic solar cells have attracted intense attention for their advantages of definite molecular structures compared with their polymer counterparts. However, the device efficiencies based on small molecules are still lower than those of polymers, especially for inverted devices, the highest efficiency of which is <9%. Here we report three novel solution-processable small molecules, which contain pi-bridges with gradient-decreased electron density and end acceptors substituted with various fluorine atoms (0F, 1F and 2F, respectively). Fluorination leads to an optimal active layer morphology, including an enhanced domain purity, the formation of hierarchical domain size and a directional vertical phase gradation. The optimal morphology balances charge separation and transfer, and facilitates charge collection. As a consequence, fluorinated molecules exhibit excellent inverted device performance, and an average power conversion efficiency of 11.08% is achieved for a two-fluorine atom substituted molecule.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13740, "DOI": "10.1038/ncomms13740", "DOI Link": "http://dx.doi.org/10.1038/ncomms13740", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389879000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, YL; Chen, Z; Wei, RL; Yang, C; Wang, YH; Xu, J; Zhang, H; Guan, AX; Chen, JT; Sham, TK; Luo, J; Yang, YY; Xu, X; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Yali; Chen, Zheng; Wei, Ruilin; Yang, Chao; Wang, Yuhang; Xu, Jie; Zhang, Hao; Guan, Anxiang; Chen, Jiatang; Sham, Tsun-Kong; Luo, Jun; Yang, Yaoyue; Xu, Xin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective CO-to-acetate electroreduction via intermediate adsorption tuning on ordered Cu-Pd sites", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of carbon monoxide (CO) has recently emerged as a potential approach for obtaining high-value, multicarbon products such as acetate, while the activity and selectivity for prodution of acetate have remained low. Herein, we develop an atomically ordered copper-palladium intermetallic compound (CuPd) composed of a high density of Cu-Pd pairs that feature as catalytic sites to enrich surface *CO coverage, stabilize ethenone as a key acetate path intermediate and inhibit the hydrogen evolution reaction, thus substantially promoting acetate formation. The CuPd electrocatalyst enables a high Faradaic efficiency of 70 +/- 5% for CO-to-acetate electroreduction and a high acetate partial current density of 425 mA cm(-2). Under membrane electrode assembly conditions, the CuPd electrocatalyst demonstrated a 500 h CO-to-acetate conversion at 500 mA cm(-2) with a stable acetate Faradaic efficiency of similar to 50%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 251, "End Page": 258, "Article Number": null, "DOI": "10.1038/s41929-022-00757-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00757-8", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773966900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "House, RA; Marie, JJ; Pérez-Osorio, MA; Rees, GJ; Boivin, E; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "House, Robert A.; Marie, John-Joseph; Perez-Osorio, Miguel A.; Rees, Gregory J.; Boivin, Edouard; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of O2 in O-redox cathodes for Li-ion batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energy density of Li-ion batteries can be improved by storing charge at high voltages through the oxidation of oxide ions in the cathode material. However, oxidation of O2- triggers irreversible structural rearrangements in the bulk and an associated loss of the high voltage plateau, which is replaced by a lower discharge voltage, and a loss of O-2 accompanied by densification at the surface. Here we consider various models for oxygen redox that are proposed in the literature and then describe a single unified model involving O2- oxidation to form O-2, most of which is trapped in the bulk and the remainder of which evolves from the surface. The model extends the O-2 formation and evolution at the surface, which is well known and well characterized, into the electrode particle bulk as caged O-2 that can be reversibly reduced and oxidized. This converged understanding enables us to propose practical strategies to avoid oxygen-redox-induced instability and provide potential routes towards more reversible, high energy density Li-ion cathodes. Oxygen redox in Li-rich oxide cathodes is of both fundamental and practical interest in Li-ion battery development. Bruce and team examine the current understanding of oxygen-redox processes, especially those concerning O-2 formation, and discuss strategies that can harness oxygen redox with suppressed side effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 781, "End Page": 789, "Article Number": null, "DOI": "10.1038/s41560-021-00780-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00780-2", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623725900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Lu, XF; Nai, JW; Zang, SQ; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Lu, Xue Feng; Nai, Jianwei; Zang, Shuang-Quan; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Hierarchical Co-Fe Oxyphosphide Microtubes for Electrocatalytic Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of efficient electrocatalysts is a crucial requirement to build water splitting systems for the production of clean and sustainable fuels. This goal could be achieved by fine-tuning the composition and structure of the electrocatalytic materials. Here, a facile self-templated synthetic strategy is developed for the fabrication of hierarchical Co-Fe oxyphosphide microtubes (MTs). Fe-based metal-organic compound microrods are first synthesized as the self-sacrificing template. Afterward, the Fe-based precursors are converted into hierarchical Co-Fe layered double hydroxide MTs through a hydrothermal approach, which are then transformed into the hierarchical Co-Fe oxyphosphide MTs by a phosphidation treatment. Benefiting from the synergistic effect of the compositions and the advantages of the hierarchical hollow structure, the obtained electrocatalyst exhibits enhanced performance for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 6, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900576, "DOI": "10.1002/advs.201900576", "DOI Link": "http://dx.doi.org/10.1002/advs.201900576", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475847500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, S; Lee, CS; Lee, MH; Lee, Y; Ma, KY; Kim, G; Yoon, SI; Ihm, K; Kim, KJ; Shin, TJ; Kim, SW; Jeon, EC; Jeon, H; Kim, JY; Lee, HI; Lee, Z; Antidormi, A; Roche, S; Chhowalla, M; Shin, HJ; Shin, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Seokmo; Lee, Chang-Seok; Lee, Min-Hyun; Lee, Yeongdong; Ma, Kyung Yeol; Kim, Gwangwoo; Yoon, Seong In; Ihm, Kyuwook; Kim, Ki-Jeong; Shin, Tae Joo; Kim, Sang Won; Jeon, Eun-chae; Jeon, Hansol; Kim, Ju-Young; Lee, Hyung-Ik; Lee, Zonghoon; Antidormi, Aleandro; Roche, Stephan; Chhowalla, Manish; Shin, Hyeon-Jin; Shin, Hyeon Suk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralow-dielectric-constant amorphous boron nitride", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Decrease in processing speed due to increased resistance and capacitance delay is a major obstacle for the down-scaling of electronics(1-3). Minimizing the dimensions of interconnects (metal wires that connect different electronic components on a chip) is crucial for the miniaturization of devices. Interconnects are isolated from each other by non-conducting (dielectric) layers. So far, research has mostly focused on decreasing the resistance of scaled interconnects because integration of dielectrics using low-temperature deposition processes compatible with complementary metal-oxide-semiconductors is technically challenging. Interconnect isolation materials must have low relative dielectric constants (kappa values), serve as diffusion barriers against the migration of metal into semiconductors, and be thermally, chemically and mechanically stable. Specifically, the International Roadmap for Devices and Systems recommends(4) the development of dielectrics with kappa values of less than 2 by 2028. Existing low-kappa materials (such as silicon oxide derivatives, organic compounds and aerogels) have kappa values greater than 2 and poor thermo-mechanical properties(5). Here we report three-nullometre-thick amorphous boron nitride films with ultralow kappa values of 1.78 and 1.16 (close to that of air, kappa = 1) at operation frequencies of 100 kilohertz and 1 megahertz, respectively. The films are mechanically and electrically robust, with a breakdown strength of 7.3 megavolts per centimetre, which exceeds requirements. Cross-sectional imaging reveals that amorphous boron nitride prevents the diffusion of cobalt atoms into silicon under very harsh conditions, in contrast to reference barriers. Our results demonstrate that amorphous boron nitride has excellent low-kappa dielectric characteristics for high-performance electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2020, "Volume": 582, "Issue": 7813, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "S11", "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2375-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2375-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623816400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, HJ; Li, Z; Feng, GX; Yang, ZZ; Fox, D; Wang, MY; Zhou, H; Zhai, L; Kushima, A; Du, YG; Feng, ZX; Shan, XN; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Huajun; Li, Zhao; Feng, Guangxia; Yang, Zhenzhong; Fox, David; Wang, Maoyu; Zhou, Hua; Zhai, Lei; Kushima, Akihiro; Du, Yingge; Feng, Zhenxing; Shan, Xiaonull; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable, high-performance, dendrite-free, seawater-based aqueous batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal anode instability, including dendrite growth, metal corrosion, and hetero-ions interference, occurring at the electrolyte/electrode interface of aqueous batteries, are among the most critical issues hindering their widespread use in energy storage. Herein, a universal strategy is proposed to overcome the anode instability issues by rationally designing alloyed materials, using Zn-M alloys as model systems (M = Mn and other transition metals). An insitu optical visualization coupled with finite element analysis is utilized to mimic actual electrochemical environments analogous to the actual aqueous batteries and analyze the complex electrochemical behaviors. The Zn-Mn alloy anodes achieved stability over thousands of cycles even under harsh electrochemical conditions, including testing in seawaterbased aqueous electrolytes and using a high current density of 80 mA cm(-2). The proposed design strategy and the in-situ visualization protocol for the observation of dendrite growth set up a new milestone in developing durable electrodes for aqueous batteries and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 237, "DOI": "10.1038/s41467-020-20334-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20334-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630190600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, JR; Xu, XT; Hill, JP; Wang, LP; Dang, JJ; Kang, YQ; Li, YL; Guan, WS; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Jingru; Xu, Xingtao; Hill, Jonathan P.; Wang, Liping; Dang, Jingjing; Kang, Yunqing; Li, Yuliang; Guan, Weisheng; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-carbon 2D heterostructures with hierarchically-porous P,N-doped layered architecture for capacitive deionization", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring a new-family of carbon-based desalinators to optimize their performances beyond the current commercial benchmark is of significance for the development of practically useful capacitive deionization (CDI) materials. Here, we have fabricated a hierarchically porous N,P-doped carbon-graphene 2D heterostructure (denoted NPC/rGO) by using metal-organic framework (MOF)-nulloparticle-driven assembly on graphene oxide (GO) nullosheets followed by stepwise pyrolysis and phosphorization procedures. The resulting NPC/rGO-based CDI desalinator exhibits ultrahigh deionization performance with a salt adsorption capacity of 39.34 mg g(-1) in a 1000 mg L-1 NaCl solution at 1.2 V over 30 min with good cycling stability over 50 cycles. The excellent performance is attributed to the high specific surface area, high conductivity, favorable meso-/microporous structure together with nitrogen and phosphorus heteroatom co-doping, all of which are beneficial for the accommodation of ions and charge transport during the CDI process. More importantly, NPC/rGO exhibits a state-of-the-art CDI performance compared to the commercial benchmark and most of the previously reported carbon materials, highlighting the significance of the MOF nulloparticle-driven assembly strategy and graphene-carbon 2D heterostructures for CDI applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 14", "Publication Year": 2021, "Volume": 12, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10334, "End Page": 10340, "Article Number": null, "DOI": "10.1039/d1sc00915j", "DOI Link": "http://dx.doi.org/10.1039/d1sc00915j", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670331700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sunku, SS; Ni, GX; Jiang, BY; Yoo, H; Sternbach, A; McLeod, AS; Stauber, T; Xiong, L; Taniguchi, T; Watanabe, K; Kim, P; Fogler, MM; Basov, DN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sunku, S. S.; Ni, G. X.; Jiang, B. Y.; Yoo, H.; Sternbach, A.; McLeod, A. S.; Stauber, T.; Xiong, L.; Taniguchi, T.; Watanabe, K.; Kim, P.; Fogler, M. M.; Basov, D. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "\\ Photonic crystals for nullo-light in moire graphene superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is an atomically thin plasmonic medium that supports highly confined plasmon polaritons, or nullo-light, with very low loss. Electronic properties of graphene can be drastically altered when it is laid upon another graphene layer, resulting in a moire superlattice. The relative twist angle between the two layers is a key tuning parameter of the interlayer coupling in thus-obtained twisted bilayer graphene (TBG). We studied the propagation of plasmon polaritons in TBG by infrared nullo-imaging. We discovered that the atomic reconstruction occurring at small twist angles transforms the TBG into a natural plasmon photonic crystal for propagating nullo-light. This discovery points to a pathway for controlling nullo-light by exploiting quantum properties of graphene and other atomically layered van der Waals materials, eliminating the need for arduous top-down nullofabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2018, "Volume": 362, "Issue": 6419, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1153, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau5144", "DOI Link": "http://dx.doi.org/10.1126/science.aau5144", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452506300056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, J; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Jie; Yang, Lan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical whispering-gallery mode barcodes for high-precision and wide-range temperature measurements", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Temperature measurement: optical barcodes from whispering-gallery sensors Extremely precise measurement of temperature using devices known as whispering-gallery mode (WGM) sensors can be greatly improved using a technique that simultaneously monitors different modes, or patterns, of the optical signals. WGM sensors rely on the sustained circulation of light within closed concave microstructures-discs, rings, or spheres-similar to the movement of sound waves in whispering galleries such as the dome of St. Paul's Cathedral in London. Jie Liao and Lan Yang at Washington University in St. Louis, Missouri, USA, developed procedures to analyse the effect of temperature on the collective patterns of light signals in WGM sensors. The results are converted into optical barcodes which indicate the temperature directly. This multimode system overcomes significant limitations imposed by the restricted range and less direct monitoring methods of existing single-mode sensors. Temperature is one of the most fundamental physical properties to characterize various physical, chemical, and biological processes. Even a slight change in temperature could have an impact on the status or dynamics of a system. Thus, there is a great need for high-precision and large-dynamic-range temperature measurements. Conventional temperature sensors encounter difficulties in high-precision thermal sensing on the submicron scale. Recently, optical whispering-gallery mode (WGM) sensors have shown promise for many sensing applications, such as thermal sensing, magnetic detection, and biosensing. However, despite their superior sensitivity, the conventional sensing method for WGM resonators relies on tracking the changes in a single mode, which limits the dynamic range constrained by the laser source that has to be fine-tuned in a timely manner to follow the selected mode during the measurement. Moreover, we cannot derive the actual temperature from the spectrum directly but rather derive a relative temperature change. Here, we demonstrate an optical WGM barcode technique involving simultaneous monitoring of the patterns of multiple modes that can provide a direct temperature readout from the spectrum. The measurement relies on the patterns of multiple modes in the WGM spectrum instead of the changes of a particular mode. It can provide us with more information than the single-mode spectrum, such as the precise measurement of actual temperatures. Leveraging the high sensitivity of WGMs and eliminating the need to monitor particular modes, this work lays the foundation for developing a high-performance temperature sensor with not only superior sensitivity but also a broad dynamic range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 32, "DOI": "10.1038/s41377-021-00472-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00472-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615240900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Tan, H; Liu, DB; Liu, XB; Xin, JP; Xie, JF; Zhao, MW; Song, L; Dai, LM; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhihe; Tan, Hua; Liu, Daobin; Liu, Xiaobiao; Xin, Jianping; Xie, Junfeng; Zhao, Mingwen; Song, Li; Dai, Liming; Liu, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promotion of Overall Water Splitting Activity Over a Wide pH Range by Interfacial Electrical Effects of Metallic NiCo-nitrides nulloparticle/NiCo2O4 nulloflake/graphite Fibers", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many efforts have been made to develop bifunctional electrocatalysts to facilitate overall water splitting. Here, a fibrous bifunctional 3D electrocatalyst is reported for both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) with high performance. The remarkable electrochemical performance is attributed of the catalysts to a number of factors: the metallic character of the three components (i.e., Ni3N, CoN, and NiCo2O4); the electronic structure, nulloflake-nullosphere network with abundant electroactive sites, and the electric field effect at the interfaces between different components. The oxide-nitride/graphite fibers have the lowest overpotential requirements of 71 and 183 mV at 10 mA cm(-2) for HER and OER in alkaline medium, respectively. These values are comparable to those of commercial Pt/C (20 wt%) and RuO2. The electrodes also show a response to HER and OER in both neutral and acid media. Furthermore, the 3D structure can be highlighted by all-round electrodes for overall water splitting. The calculations on the changes in electrons transfer and the Femi level from oxides to oxides/nitrides reveal that the observed superb electrocatalytic performance can be attributed to the presence of Ni3N and CoN derived from the in situ nitridation of NiCo2O4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2019, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801829, "DOI": "10.1002/advs.201801829", "DOI Link": "http://dx.doi.org/10.1002/advs.201801829", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460374300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YL; Zuo, XJ; He, YY; Qian, F; Zuo, SN; Zhang, YL; Liang, L; Chen, ZQ; Zhao, K; Liu, ZK; Gou, J; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yali; Zuo, Xuejiao; He, Yiyang; Qian, Fang; Zuo, Shengnull; Zhang, Yalan; Liang, Lei; Chen, Zuqin; Zhao, Kui; Liu, Zhike; Gou, Jing; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual Passivation of Perovskite and SnO2 for High-Efficiency MAPbI3 Perovskite Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "So far, most techniques for modifying perovskite solar cells (PSCs) focus on either the perovskite or electron transport layer (ETL). For the sake of comprehensively improving device performance, a dual-functional method of simultaneously passivating trap defects in both the perovskite and ETL films is proposed that utilizes guidable transfer of Eu3+ in SnO2 to perovskite. Europium ions are distributed throughout the SnO2 film during the formation process of SnO2, and they can diffuse directionally through the SnO2/perovskite interface into the perovskite, while most of the europium ions remain at the interface. Under the synergistic effect of distributed Eu3+ in the SnO2 and aggregated Eu3+ at the interface, the electron mobilities of ETLs are evidently improved. Meanwhile, diffused Eu3+ ions passivate the perovskite to reduce trap densities at the grain boundaries, which can dramatically elevate the open-circuit voltage (V-oc) of PSCs. Finally, the mainly PSCs coated on SnO2:Eu3+ ETL achieve a power conversion efficiency of 20.14%. Moreover, an unsealed device degrades by only 13% after exposure to ambient atmosphere for 84 days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001466, "DOI": "10.1002/advs.202001466", "DOI Link": "http://dx.doi.org/10.1002/advs.202001466", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612809100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Usov, I; Nyström, G; Adamcik, J; Handschin, S; Schütz, C; Fall, A; Bergström, L; Mezzenga, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Usov, Ivan; Nystroem, Gustav; Adamcik, Jozef; Handschin, Stephan; Schutz, Christina; Fall, Andreas; Bergstrom, Lennart; Mezzenga, Raffaele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding nullocellulose chirality and structure-properties relationship at the single fibril level", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocellulose fibrils are ubiquitous in nature and nullotechnologies but their mesoscopic structural assembly is not yet fully understood. Here we study the structural features of rod-like cellulose nulloparticles on a single particle level, by applying statistical polymer physics concepts on electron and atomic force microscopy images, and we assess their physical properties via quantitative nullomechanical mapping. We show evidence of right-handed chirality, observed on both bundles and on single fibrils. Statistical analysis of contours from microscopy images shows a non-Gaussian kink angle distribution. This is inconsistent with a structure consisting of alternating amorphous and crystalline domains along the contour and supports process-induced kink formation. The intrinsic mechanical properties of nullocellulose are extracted from nulloindentation and persistence length method for transversal and longitudinal directions, respectively. The structural analysis is pushed to the level of single cellulose polymer chains, and their smallest associated unit with a proposed 2 x 2 chain-packing arrangement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7564, "DOI": "10.1038/ncomms8564", "DOI Link": "http://dx.doi.org/10.1038/ncomms8564", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357180800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sridharan, R; Cameron, AR; Kelly, DJ; Kearney, CJ; O'Brien, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sridharan, Rukmani; Cameron, Andrew R.; Kelly, Daniel J.; Kearney, Cathal J.; O'Brien, Fergal J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomaterial based modulation of macrophage polarization: a review and suggested design principles", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Macrophages have long been known for their phagocytic capabilities and immune defence; however, their role in healing is being increasingly recognized in recent years due to their ability to polarize into pro-inflammatory and anti-inflammatory phenotypes. Historically, biomaterials were designed to be inert to minimize the host response. More recently, the emergence of tissue engineering and regenerative medicine has led to the design of biomaterials that interact with the host through tailored mechanical, chemical and temporal characteristics. Due to such advances in biomaterial functionality and an improved understanding of macrophage responses to implanted materials, it is now possible to identify biomaterial design characteristics that dictate the host response and contribute to successful tissue integration. Herein, we begin by briefly reviewing macrophage cell origin and the key cytokine/chemokine markers of macrophage polarization and then describe which responses are favorable for both replacement and regenerative biomaterials. The body of the review focuses on macrophage polarization in response to inherent cues directly provided by biomaterials and the consequent cues that result from events related to biomaterial implantation. To conclude, a section on potential design principles for both replacement and regenerative biomaterials is presented. An in depth understanding of biomaterial cues to selectively polarize macrophages may prove beneficial in the design of a new generation of immuno-informed' biomaterials that can positively interact with the immune system to dictate a favorable macrophage response following implantation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 671, "Times Cited, All Databases": 743, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2015, "Volume": 18, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 313, "End Page": 325, "Article Number": null, "DOI": "10.1016/j.mattod.2015.01.019", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.01.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356184700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kibria, MG; Zhao, S; Chowdhury, FA; Wang, Q; Nguyen, HPT; Trudeau, ML; Guo, H; Mi, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kibria, M. G.; Zhao, S.; Chowdhury, F. A.; Wang, Q.; Nguyen, H. P. T.; Trudeau, M. L.; Guo, H.; Mi, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the surface Fermi level on p-type gallium nitride nullowires for efficient overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar water splitting is one of the key steps in artificial photosynthesis for future carbonneutral, storable and sustainable source of energy. Here we show that one of the major obstacles for achieving efficient and stable overall water splitting over the emerging nullostructured photocatalyst is directly related to the uncontrolled surface charge properties. By tuning the Fermi level on the nonpolar surfaces of gallium nitride nullowire arrays, we demonstrate that the quantum efficiency can be enhanced by more than two orders of magnitude. The internal quantum efficiency and activity on p-type gallium nitride nullowires can reach similar to 51% and similar to 4.0 mol hydrogen h(-1) g(-1), respectively. The nullowires remain virtually unchanged after over 50,000 mu mol gas (hydrogen and oxygen) is produced, which is more than 10,000 times the amount of photocatalyst itself (similar to 4.6 mmol). The essential role of Fermi-level tuning in balancing redox reactions and in enhancing the efficiency and stability is also elucidated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3825, "DOI": "10.1038/ncomms4825", "DOI Link": "http://dx.doi.org/10.1038/ncomms4825", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335376500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de la Barrera, SC; Sinko, MR; Gopalan, DP; Sivadas, N; Seyler, KL; Watanabe, K; Taniguchi, T; Tsen, AW; Xu, XD; Xiao, D; Hunt, BM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de la Barrera, Sergio C.; Sinko, Michael R.; Gopalan, Devashish P.; Sivadas, Nikhil; Seyler, Kyle L.; Watanabe, Kenji; Taniguchi, Takashi; Tsen, Adam W.; Xu, Xiaodong; Xiao, Di; Hunt, Benjamin M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Ising superconductivity with layer and spin-orbit coupling in two-dimensional transition-metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Systems simultaneously exhibiting superconductivity and spin-orbit coupling are predicted to provide a route toward topological superconductivity and unconventional electron pairing, driving significant contemporary interest in these materials. Monolayer transition-metal dichalcogenide (TMD) superconductors in particular lack inversion symmetry, yielding an antisymmetric form of spin-orbit coupling that admits both spin-singlet and spin-triplet components of the superconducting wavefunction. Here, we present an experimental and theoretical study of two intrinsic TMD superconductors with large spin-orbit coupling in the atomic layer limit, metallic 2H-TaS2 and 2H-NbSe2. We investigate the superconducting properties as the material is reduced to monolayer thickness and show that high-field measurements point to the largest upper critical field thus reported for an intrinsic TMD superconductor. In few-layer samples, we find the enhancement of the upper critical field is sustained by the dominullce of spin-orbit coupling over weak interlayer coupling, providing additional candidate systems for supporting unconventional superconducting states in two dimensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1427, "DOI": "10.1038/s41467-018-03888-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03888-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429794300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, HJ; Cai, L; Pan, F; Shi, YY; Cheng, J; Yang, Y; Shi, Z; Chai, XL; Wu, HJ; Lu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Haojie; Cai, Lei; Pan, Fei; Shi, Yuyang; Cheng, Jie; Yang, Yang; Shi, Zhong; Chai, Xiaoli; Wu, Hongjing; Lu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ordered Heterostructured Aerogel with Broadband Electromagnetic Wave Absorption Based on Mesoscopic Magnetic Superposition Enhancement", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Demand for lightweight and efficient electromagnetic wave (EW) absorbers continues to increase with technological advances in highly integrated electronics and military applications. Although MXene-based EW absorbers have been extensively developed, more efficient electromagnetic coupling and thinner thickness are still essential. Recently, ordered heterogeneous materials have emerged as a novel design concept to address the bottleneck faced by current material development. Herein, an ordered heterostructured engineering to assemble Ti3CNTx MXenes/Aramid nullofibers/FeCo@SiO2 nullobundles (FS) aerogel (AMFS-O) is proposed, where the commonly disordered magnetic composition is transformed to ordered FS arrays that provide more powerful magnetic loss capacity. Experiments and simulations reveal that the anisotropy magnetic networks enhance the response to the magnetic field vector of EW, which effectively improves the impedance matching and makes the reflection loss (RL) peaks shift to lower frequencies, leading to the thinner matching thickness. Furthermore, the temperature stability and excellent compressibility of AMFS-O expand functionalized applications. The synthesized AMFS-O achieves full-wave absorption in X and Ku-band (8.2-18.0 GHz) at 3.0 mm with a RLmin of -41 dB and a low density of 0.008 g cm(-3). These results suggest that ordered heterostructured engineering is an effective strategy for designing high-performance multifunctional EW absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202301599", "DOI Link": "http://dx.doi.org/10.1002/advs.202301599", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982363800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, HF; Chen, GF; Savateev, O; Xue, J; Ding, LX; Liang, ZX; Antonietti, M; Wang, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Haifeng; Chen, Gao-Feng; Savateev, Oleksandr; Xue, Jian; Ding, Liang-Xin; Liang, Zhenxing; Antonietti, Markus; Wang, Haihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabled Efficient Ammonia Synthesis and Energy Supply in a Zinc-Nitrate Battery System by Separating Nitrate Reduction Process into Two Stages", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aqueous electrocatalytic reduction of NO3- into NH3 (NitrRR) presents a sustainable route applicable to NH3 production and potentially energy storage. However, the NitrRR involves a directly eight-electron transfer process generally required a large overpotential (<-0.2 V versus reversible hydrogen electrode (vs. RHE)) to reach optimal efficiency. Here, inspired by biological nitrate respiration, the NitrRR was separated into two stages along a [2+6]-electron pathway to alleviate the kinetic barrier. The system employed a Cu nullowire catalyst produces NO2- and NH3 with current efficiencies of 91.5 % and 100 %, respectively at lower overpotentials (>+0.1 vs. RHE). The high efficiency for such a reduction process was further explored in a zinc-nitrate battery. This battery could be specified by a high output voltage of 0.70 V, an average energy density of 566.7 Wh L-1 at 10 mA cm(-2) and a power density of 14.1 mW cm(-2), which is well beyond all previously reported similar concepts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2023, "Volume": 62, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202218717", "DOI Link": "http://dx.doi.org/10.1002/anie.202218717", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937292300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, J; Jin, J; Yin, ZY; Zhu, L; Du, X; Peng, Y; Xi, PX; Yan, CH; Sun, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Jie; Jin, Jing; Yin, Zhouyang; Zhu, Liu; Du, Xin; Peng, Yong; Xi, Pinxian; Yan, Chun-Hua; Sun, Shouheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding and controlling chemical environment of metal-N-catalysts is of great importance. In this work, the authors reveal FeN/Fe3N interface with Fe-N-4 and Fe-N-2 coordination sites for enhanced electrochemical CO2 reduction to CO. nullostructured metal-nitrides have attracted tremendous interest as a new generation of catalysts for electroreduction of CO2, but these structures have limited activity and stability in the reduction condition. Herein, we report a method of fabricating FeN/Fe3N nulloparticles with FeN/Fe3N interface exposed on the NP surface for efficient electrochemical CO2 reduction reaction (CO2RR). The FeN/Fe3N interface is populated with Fe-N-4 and Fe-N-2 coordination sites respectively that show the desired catalysis synergy to enhance the reduction of CO2 to CO. The CO Faraday efficiency reaches 98% at -0.4 V vs. reversible hydrogen electrode, and the FE stays stable from -0.4 to -0.9 V during the 100 h electrolysis time period. This FeN/Fe3N synergy arises from electron transfer from Fe3N to FeN and the preferred CO2 adsorption and reduction to *COOH on FeN. Our study demonstrates a reliable interface control strategy to improve catalytic efficiency of the Fe-N structure for CO2RR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1724, "DOI": "10.1038/s41467-023-37360-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37360-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000962607600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, F; Feurer, T; Weiss, TP; Pisoni, S; Avancini, E; Andres, C; Buecheler, S; Tiwari, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Fan; Feurer, Thomas; Weiss, Thomas Paul; Pisoni, Stefano; Avancini, Enrico; Andres, Christian; Buecheler, Stephan; Tiwari, Ayodhya N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-effciency inverted semi-transparent planar perovskite solar cells in substrate configuration", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to grow perovskite solar cells in substrate configuration, where light enters the devices from the film side, allows the use of non-transparent flexible polymer and metal substrates. Furthermore, this configuration could facilitate processing directly on Cu(In, Ga) Se-2 solar cells to realize ultrahigh-effciency polycrystalline all-thin-film tandem devices. However, the inversion of conventional superstrate architecture imposes severe constraints on device processing and limits the electronic quality of the absorber and charge selective contacts. Here we report a device architecture that allows inverted semitransparent planar perovskite solar cells with a high open-circuit voltage of 1.116V and substantially improved effciency of 16.1%. The substrate configuration perovskite devices show a temperature coeffcient of -0.18% degrees C-1 and promising thermal and photo-stability. Importantly, the device exhibits a high average transmittance of 80.4% between 800 and 1,200 nm, which allows us to demonstrate polycrystalline all-thin-film tandem devices with effciencies of 22.1% and 20.9% for Cu(In, Ga) Se-2 and CuInSe2 bottom cells, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16190, "DOI": "10.1038/nenergy.2016.190", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2016.190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396303000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, Z; Huang, XJ; Yang, ZW; Qiu, JB; Song, ZG; Zhang, JY; Dong, GP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zhen; Huang, Xiongjian; Yang, Zhengwen; Qiu, Jianbei; Song, Zhiguo; Zhang, Junying; Dong, Guoping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible 3D optical data storage and information encryption in photo-modulated transparent glass medium", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transparent glass has been identified as a vital medium for three-dimensional (3D) optical information storage and multi-level encryption. However, it has remained a challenge for directly writing 3D patterning inside a transparent glass using semiconductor blue laser instead of high-cost femtosecond laser. Here, we demonstrate that rare earth ions doped transparent glass can be used as 3D optical information storage and data encryption medium based on their reversible transmittance and photoluminescence manipulation. The color of tungsten phosphate glass doped with rare earth ions change reversibly from light yellow to blue upon alternating 473 nm laser illumination and temperature stimulation, resulting in the reversible luminescence modulation. The information data could be repeatedly written and erased in arbitrary 3D space of transparent glass, not only showing the ability of the excellent reproducibility and storage capacity, but also opening opportunities in information security. The present work expands the application fields of luminescent glass, and it is conducive to develop a novel 3D data storage and information encryption media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 140, "DOI": "10.1038/s41377-021-00581-y", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00581-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672403300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gautier, R; Zhang, XW; Hu, LH; Yu, LP; Lin, YY; Sunde, TOL; Chon, D; Poeppelmeier, KR; Zunger, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gautier, Romain; Zhang, Xiuwen; Hu, Linhua; Yu, Liping; Lin, Yuyuan; Sunde, Tor O. L.; Chon, Danbee; Poeppelmeier, Kenneth R.; Zunger, Alex", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction and accelerated laboratory discovery of previously unknown 18-electron ABX compounds", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemists and material scientists have often focused on the properties of previously reported compounds, but neglect numerous unreported but chemically plausible compounds that could have interesting properties. For example, the 18-valence electron ABX family of compounds features examples of topological insulators, thermoelectrics and piezoelectrics, but only 83 out of 483 of these possible compounds have been made. Using first-principles thermodynamics we examined the theoretical stability of the 400 unreported members and predict that 54 should be stable. Of those previously unreported `missing' materials now predicted to be stable, 15 were grown in this study; X-ray studies agreed with the predicted crystal structure in all 15 cases. Among the predicted and characterized properties of the missing compounds are potential transparent conductors, thermoelectric materials and topological semimetals. This integrated process-prediction of functionality in unreported compounds followed by laboratory synthesis and characterization-could be a route to the systematic discovery of hitherto missing, realizable functional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 308, "End Page": 316, "Article Number": null, "DOI": "10.1038/NCHEM.2207", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2207", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351756200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ascherl, L; Evans, EW; Gorman, J; Orsborne, S; Bessinger, D; Bein, T; Friend, RH; Auras, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ascherl, Laura; Evans, Emrys W.; Gorman, Jeffrey; Orsborne, Sarah; Bessinger, Derya; Bein, Thomas; Friend, Richard H.; Auras, Florian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perylene-Based Covalent Organic Frameworks for Acid Vapor Sensing", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditionally, the properties and functions of covalent organic frameworks (COFs) are defined by their constituting building blocks, while the chemical bonds that connect the individual subunits have not attracted much attention as functional components of the final material. We have developed a new series of dual-pore perylene-based COFs and demonstrated that their imine bonds can be protonated reversibly, causing significant protonation-induced color shifts toward the near-infrared, while the structure and crystallinity of the frameworks are fully retained. Thin films of these COFs are highly sensitive colorimetric acid vapor sensors with a detection limit as low as 35 mu g L-1 and a response range of at least 4 orders of magnitude. Since the acidochromism in our COFs is a cooperative phenomenon based on electronically coupled imines, the COFs can be used to determine simultaneously the concentration and protonation strength of nonaqueous acid solutions, in which pH electrodes are not applicable, and to distinguish between different acids. Including the imine bonds as function-determining constituents of the framework provides an additional handle for constructing multifunctional COFs and extending the range of their possible applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2019, "Volume": 141, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15693, "End Page": 15699, "Article Number": null, "DOI": "10.1021/jacs.9b08079", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b08079", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489001500031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, S; Cao, WR; Liu, TL; Tsang, SW; Yang, YX; Yan, XL; Qian, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Song; Cao, Weiran; Liu, Taili; Tsang, Sai-Wing; Yang, Yixing; Yan, Xiaolin; Qian, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the degradation mechanisms of quantum-dot light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The operating lifetime of blue quantum-dot light-emitting diodes (QLED) is currently a short slab for this emerging display technology. To pinpoint the origin of device degradation, here we apply multiple techniques to monitor the electric-field distribution and space-charge accumulation across the multilayered structure before and after lifetime tests. Evident by charge-modulated electro-absorption and capacitance-voltage characteristics, the excited electrons in blue quantum dots (QD) are prone to cross the type II junction between the QD emission layer and the electron-transporting layer (ETL) due to the offset of conduction band minimum, leading to space-charge accumulation and operating-voltage rise in the ETL. Therefore, unlike those very stable red devices, of which the lifetime is primarily limited by the slow degradation of hole-transporting layer, the poor lifetime of blue QLED originates from the fast degradation at the QD-ETL junction. Materials engineering for efficient electron injection is prerequisite for the boost of operating lifetime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 765, "DOI": "10.1038/s41467-019-08749-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08749-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458754700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XF; Vashisth, A; Prehn, E; Sun, WM; Shah, S; Habib, T; Chen, YX; Tan, ZY; Lutkenhaus, J; Radovic, M; Green, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xiaofei; Vashisth, Aniruddh; Prehn, Evan; Sun, Wanmei; Shah, Smit; Habib, Touseef; Chen, Yexiao; Tan, Zeyi; Lutkenhaus, Jodie; Radovic, Miladin; Green, Micah J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antioxidants Unlock Shelf-Stable Ti3C2Tx (MXene) nullosheet Dispersions", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although MXene nullosheets have attracted significant scientific and industrial attention, these materials are highly susceptible to oxidation, which leads to their chemical degradation and loss of functional properties in a matter of days. Here we demonstrate an effective method to prevent the oxidation of colloidal Ti3C2Tx MXene nullosheets by using sodium L-ascorbate as an antioxidant. The success of the method is evident in the stable morphology, structure, and colloidal stability of Ti3C2Tx. Even in the presence of water and oxygen, the electrical conductivity of Ti3C2Tx nullosheets treated with sodium L-ascorbate was orders of magnitude higher as compared with untreated ones after 21 days. This resistance to oxidation also persists in the dried state. We propose that the sodium L-ascorbate protects the edges of the nullosheets, restricting water molecules from otherwise reactive sites; this is supported by molecular dynamics simulations that show association of the ascorbate anion with the nullosheet edge.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 528, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2019, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 513, "End Page": 526, "Article Number": null, "DOI": "10.1016/j.matt.2019.05.020", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2019.05.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519688200021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, FB; Gu, YQ; O'Brien, JP; Yi, SM; Yalcin, SE; Srikanth, V; Shen, C; Vu, D; Ing, NL; Hochbaum, AI; Egelman, EH; Malvankar, NS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Fengbin; Gu, Yangqi; O'Brien, J. Patrick; Yi, Sophia M.; Yalcin, Sibel Ebru; Srikanth, Vishok; Shen, Cong; Vu, Dennis; Ing, Nicole L.; Hochbaum, Allon, I; Egelman, Edward H.; Malvankar, Nikhil S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure of Microbial nullowires Reveals Stacked Hemes that Transport Electrons over Micrometers", "Source Title": "CELL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-range (>10 mu m) transport of electrons along networks of Geobacter sulfurreducens protein filaments, known as microbial nullowires, has been invoked to explain a wide range of globally important redox phenomena. These nullowires were previously thought to be type IV pili composed of PilA protein. Here, we report a 3.7 angstrom resolution cryoelectron microscopy structure, which surprisingly reveals that, rather than PilA, G. sulfurreducens nullowires are assembled by micrometer-long polymerization of the hexaheme cytochrome OmcS, with hemes packed within similar to 3.5-6 angstrom of each other. The inter-subunit interfaces show unique structural elements such as inter-subunit parallel-stacked homes and axial coordination of heme by histidines from neighboring subunits. Wild-type OmcS filaments show 100-fold greater conductivity than other filaments from a Delta omcS strain, highlighting the importance of OmcS to conductivity in these nullowires. This structure explains the remarkable capacity of soil bacteria to transport electrons to remote electron acceptors for respiration and energy sharing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2019, "Volume": 177, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 361, "End Page": "+", "Article Number": null, "DOI": "10.1016/j.cell.2019.03.029", "DOI Link": "http://dx.doi.org/10.1016/j.cell.2019.03.029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Cell Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463346200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, BY; Su, GX; Wang, HF; Su, H; Shen, XP; Zhan, P; Lu, MH; Wang, ZL; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Bi-Ye; Su, Guang-Xu; Wang, Hong-Fei; Su, Hai; Shen, Xiao-Peng; Zhan, Peng; Lu, Ming-Hui; Wang, Zhen-Lin; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization of Higher-Order Topological Insulating Phases in Two-Dimensional Dielectric Photonic Crystals", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The studies of topological phases of matter have been developed from condensed matter physics to photonic systems, resulting in fascinating designs of robust photonic devices. Recently, higher-order topological insulators have been investigated as a novel topological phase of matter beyond the conventional bulk-boundary correspondence. Previous studies of higher-order topological insulators have been mainly focused on the topological multipole systems with negative coupling between lattice sites. Here we experimentally demonstrate that second-order topological insulating phases without negative coupling can be realized in two-dimensional dielectric photonic crystals. We visualize both one-dimensional topological edge states and zero-dimensional topological corner states by using the nearfield scanning technique. Our findings open new research frontiers for photonic topological phases and provide a new mechanism for light manipulating in a hierarchical way.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 483, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2019, "Volume": 122, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 233903, "DOI": "10.1103/PhysRevLett.122.233903", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.233903", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471988900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Panda, B; Paul, SC; Hui, LJ; Tay, YWD; Tan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Panda, Biranchi; Paul, Suvash Chandra; Hui, Lim Jian; Tay, Yi Wei Daniel; Tan, Ming Jen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of geopolymer for sustainable built environment", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper evaluates the potential of fly ash based geopolymer cement for large scale additive manufacturing (AM) of construction elements. Geopolymer is considered as a green construction material and its use in AM may contribute towards sustainable environment since in AM process material is only deposited whereby it is necessary. As part of this research, an industrial robot was employed to print geopolymer mortar in layer-by-layer manner directly from 3D computer-aided design (CAD) model. The characteristic of raw materials and fresh properties were examined by rheology, x-ray diffraction (XRD), and scanning electron microscopy (SEM). Mechanical tests such as compression, flexural and tensile bond strength were conducted on the printed geopolymer in different printing directions and their performance was compared with casted samples. It was found, from the experimental results, that the mechanical properties of 3D printed geopolymer are mostly dependent of loading directions due to anisotropic nature of the printing process and retains intrinsic performance of the material. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2017, "Volume": 167, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 281, "End Page": 288, "Article Number": null, "DOI": "10.1016/j.jclepro.2017.08.165", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2017.08.165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413128100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schultz, T; Frey, NC; Hantanasirisakul, K; Park, S; May, SJ; Shenoy, VB; Gogotsi, Y; Koch, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schultz, Thorsten; Frey, Nathan C.; Hantanasirisakul, Kanit; Park, Soohyung; May, Steven J.; Shenoy, Vivek B.; Gogotsi, Yury; Koch, Norbert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Termination Dependent Work Function and Electronic Properties of Ti3C2Tx MXene", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes, an emerging family of 2D transition metal carbides and nitrides, have shown promise in various applications, such as energy storage, electromagnetic interference shielding, conductive thin films, photonics, and photothermal therapy. Their metallic nature, wide range of optical absorption, and tunable surface chemistry are the key to their success in those applications. The physical properties of MXenes are known to be strongly dependent on their surface terminations. In this study, we investigated the electronic properties of Ti3C2Tx for different surface terminations, as achieved by different annealing temperatures, with the help of photoelectron spectroscopy, inverse photoelectron spectroscopy, and density functional theory calculations. We find that fluorine occupies solely the face-centered cubic adsorption site, whereas oxygen initially occupies at least two different adsorption sites, followed by a rearrangement after fluorine desorption at high annealing temperatures. The measured electronic structure of Ti3C2Tx showed strong dispersion of more than 1 eV, which we conclude to stem from Ti-O bonds by comparing it to calculated band structures. We further measured the work function of Ti3C2Tx as a function of annealing temperature and found that it is in the range of 3.9-4.8 eV, depending on the surface composition. A comparison of the experimental work function to detailed density functional theory calculations shows that the measured value is not simply an average of the work function values of uniformly terminated Ti3C2 surfaces but that the interplay between the different surface moieties and their local dipoles plays a crucial role.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 10", "Publication Year": 2019, "Volume": 31, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6590, "End Page": 6597, "Article Number": null, "DOI": "10.1021/acs.chemmater.9b00414", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.9b00414", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485830300026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YY; Xu, GY; Xi, JC; Shen, YX; Wu, XX; Tang, XH; Ding, JY; Yang, HY; Cheng, QR; Chen, ZY; Li, YW; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yeyong; Xu, Guiying; Xi, Jiachen; Shen, Yunxiu; Wu, Xiaoxiao; Tang, Xiaohua; Ding, Junyuan; Yang, Heyi; Cheng, Qinrong; Chen, Ziyuan; Li, Yaowen; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ crosslinking-assisted perovskite grain growth for mechanically robust flexible perovskite solar cells with 23.4% efficiency", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible perovskite solar cells (pero-SCs) are the best candidates to complement silicon solar cells in the photovoltaic market. However, their power conversion efficiencies (PCEs) and mechanical stability are far behind the industry standards because of the uncontrollable growth of perovskites on plastic substrates and intrinsically high Young's modulus. We explored an in situ crosslinking bis((3-methyl-oxetan-3-yl) methyl) thiophene-2,5-dicarboxylate along with perovskite growth, and its coordination ability and crosslinking tem-perature enabled the fine regulation of the quality of perovskite in real time. The resultant perovskite film exhibits an enlarged grain size, compact stacking, and a preferential crystal orientation. More-over, the crosslinked elastomer polymer gathered at the perovskite grain boundaries can effectively release the mechanical stress. As a result, the flexible pero-SC based on this perovskite film achieved a record PCE of 23.4% (certified 22.9%), which is comparable with that of the rigid device. Importantly, the flexible pero-SCs also display a robust bending durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.joule.2022.12.013", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.12.013", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939839300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Xia, ZG; Molokeev, MS; Zhang, XW; Peng, DS; Liu, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jun; Xia, Zhiguo; Molokeev, Maxim S.; Zhang, Xiuwen; Peng, Dongsheng; Liu, Quanlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Composition design, optical gap and stability investigations of lead-free halide double perovskite Cs2AgInCl6", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of lead-free double perovskites provides a feasible way of searching for air-stable and environmentally benign solar cell absorbers. Herein we report the design and hydrothermal crystal growth of double perovskite Cs2AgInCl6. The crystal structure, morphology related to the crystal growth habit, band structure, optical properties, and stability are investigated in detail. This perovskite crystallized in a cubic unit cell with the space group Fm3(-)m and is composed of [AgCl6] and [InCl6] octahedra alternating in a ordered rock-salt structure, and the as-obtained crystal size is dependent on the hydrothermal reaction time. Cs2AgInCl6 is a direct gap semiconductor with a wide band gap of 3.23 eV obtained experimentally and 3.33 eV obtained by DFT calculation. This theoretically predicted and experimentally confirmed optical gap is a prototype of the band gaps that are direct and optically allowed except at the single high-symmetry k-point, which didn't raise interest before but have potential applications in future technologies. Cs2AgInCl6 material with excellent moisture, light and heat stability shows great potential for photovoltaic and other optoelectronic applications via further band gap engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2017, "Volume": 5, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15031, "End Page": 15037, "Article Number": null, "DOI": "10.1039/c7ta04690a", "DOI Link": "http://dx.doi.org/10.1039/c7ta04690a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406187800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mellor, S; Hao, L; Zhang, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mellor, Stephen; Hao, Liang; Zhang, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing: A framework for implementation", "Source Title": "INTERNATIONAL JOURNAL OF PRODUCTION ECONOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As mass production has migrated to developing countries, European and US companies are forced to rapidly switch towards low volume production of more innovative, customised and sustainable products with high added value. To compete in this turbulent environment, manufacturers have sought new fabrication techniques to provide the necessary tools to support the need for increased flexibility and enable economic low volume production. One such emerging technique is Additive Manufacturing (AM). AM is a method of manufacture which involves the joining of materials, usually layer-upon-layer, to create objects from 3D model data. The benefits of this methodology include new design freedom, removal of tooling requirements, and economic low volumes. AM consists of various technologies to process versatile materials, and for many years its dominullt application has been the manufacture of prototypes, or Rapid Prototyping. However, the recent growth in applications for direct part manufacture, or Rapid Manufacturing, has resulted in much research effort focusing on development of new processes and materials. This study focuses on the implementation process of AM and is motivated by the lack of socio-technical studies in this area. It addresses the need for existing and potential future AM project managers to have an implementation framework to guide their efforts in adopting this new and potentially disruptive technology class to produce high value products and generate new business opportunities. Based on a review of prior works and through qualitative case study analysis, we construct and test a normative structural model of implementation factors related to AM technology, supply chain, organisation, operations and strategy. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 149, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 194, "End Page": 201, "Article Number": null, "DOI": "10.1016/j.ijpe.2013.07.008", "DOI Link": "http://dx.doi.org/10.1016/j.ijpe.2013.07.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Operations Research & Management Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332439600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Zhang, YM; Fan, GZ; Song, LZ; Jia, G; Huang, HT; Ouyang, SX; Ye, JH; Li, ZS; Zou, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yong; Zhang, Yuanming; Fan, Guozheng; Song, Lizhu; Jia, Gan; Huang, Huiting; Ouyang, Shuxin; Ye, Jinhua; Li, Zhaosheng; Zou, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cooperative catalysis coupling photo-/photothermal effect to drive Sabatier reaction with unprecedented conversion and selectivity", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly efficient catalysts to drive the Sabatier reactions under mild conditions remains a great challenge. Here, we report a 0.35%Ru@Ni2V2O7 catalyst exhibited an unprecedented solar-driven CO2 methanation rate of 114.9 mmol g(cat)(-1)h(-1) (32.8 mol gRu(-1) h(-1) as normalized to the mass of the Ru catalyst), which was approximately 40 and 460 times larger than the rates obtained over the bare Ni2V2O7 and Ru@SiO2 catalysts, respectively. Moreover, the 0.35%Ru@Ni2V2O7 catalyst exhibited 93.5% CO2 conversion efficiency and 99% selectivity for CH4 production, approaching the thermodynamic equilibrium limit of thermocatalytic CO2 methanation. Further investigations revealed a cooperative mechanism coupling photocatalysis and photothermal catalysis between the Ru and Ni2V2O7. When illuminated, Ru clusters acted as a nulloheater'' and raised the local temperature to activate H-2 and desorb H2O molecules. The spilled H adatoms reacted with adsorbed CO2 on the surface of O-vacancy-rich Ni2V2O7 to achieve cooperative catalysis for CO2 methanation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2021, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3235, "End Page": 3251, "Article Number": null, "DOI": "10.1016/j.joule.2021.11.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.11.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000732713600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, ZM; Chen, Q; Zheng, QQ; Shen, RC; Zhang, P; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Zhimin; Chen, Qing; Zheng, Qiaoqing; Shen, Rongchen; Zhang, Peng; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing 1D/2D Schottky-Based Heterojunctions between Mn0.2Cd0.8S nullorods and Ti3C2 nullosheets for Boosted Photocatalytic H2 Evolution", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable photocatalytic H-2 evolution has attracted extensive attention in recent years because it can address both energy shortage and environmental pollution issues. In particular, metal sulfide solid-solution photocatalysts have been widely applied in photocatalytic hydrogen generation owing to their excellent light harvesting properties, narrow enough band gap, and suitable redox potentials of conduction and valance bands. However, it is still challenging to develop low-cost and high-efficiency sulfide solid-solution photocatalysts for practical photocatalytic hydrogen evolution. Recently, 1D MnxCd1-xS nullostructures have shown superior light absorption, charge separation, and H-2-evolution activity owing to their shortened diffusion pathway of carriers and high length-to-diameter ratios. Thus, 1D MnxCd1-xS nullostructures have been applied in photocatalytic H-2 evolution. However, a single MnxCd1-xS photocatalyst still has some disadvantages for photocatalytic H-2 evolution, such as the rapid recombination of photogenerated electron-hole pairs and low quantum efficiency. Herein, to further boost the separation of photogenerated charge carriers and H-2-evolution kinetics, an in situ solvothermal method was used to synthesize the 10/20 Schottky-based heterojunctions between the Mn0.2Cd0.8S nullorods (MCS NRs) and Ti3C2 MXene nullosheets (NSs). Furthermore, various characterization methods have been used to investigate the crucial roles and underlying mechanisms of metallic Ti3C2 MXene NSs in boosting the photocatalytic H-2 evolution over the Mn0.2Cd0.8S nullorods. X-ray Diffraction (XRD), Transmission Electron Microscope (TEM), High Resolution Transmission Electron Microscopy (HRTEM), element mapping images, and X-ray Photoelectron Spectroscopy (XPS) results clearly demonstrate that hybrid low-cost Schottky-based heterojunctions have been successfully constructed for practical applications in photocatalytic H(2 )evolution. Additionally, the photocatalytic hydrogen evolution reaction (HER) was also carried out in a mixed solution of Na2SO3 and Na2S using as the sacrificial agents. The highest hydrogen evolution rate of the optimized 1D/2D Schottky-based heterojunction is 15.73 mmol.g(-1).h(-1), which is 6.72 times higher than that of pure MCS NRs (2.34 mmol.g(-1).h(-1)). An apparent quantum efficiency of 19.6% was achieved at 420 nm. The stability measurements of the binary photocatalysts confirmed their excellent photocatalytic stability for practical applications. More interestingly, the UV-Vis diffuse reflection spectra, photoluminescence (PL) spectrum, transient photocurrent responses, and Electrochemical Impedance Spectroscopy (EIS) Nyquist plots clearly confirmed the promoted charge separation between the MCS NRs and Ti3C2 MXene NSs. The linear sweep voltammetry also showed that the loading of MXene cocatalysts could greatly decrease the overpotential of pure MCS NRs, suggesting that the 2D Ti3C2 NSs could act as an electronic conductive bridge to improve the H-2-evolution kinetics. In summary, these results show that the 2D/1D hybrid Schottky-based heterojunctions between metallic Ti3C2 MXene NSs and MCS NRs can not only improve the separation of photogenerated electrons and holes but also decrease the H-2-evolution overpotential, thus resulting in significantly enhanced photocatalytic H-2 generation. We believe that this study will inspire new ideas for constructing low-cost Schottky-based heterojunctions for practical applications in photocatalytic H-2 evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2021, "Volume": 37, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2010059, "DOI": "10.3866/PKU.WHXB202010059", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202010059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614248900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YM; Liu, LR; Zhu, C; Guo, SS; Golani, P; Koo, B; Tang, PY; Zhao, ZQ; Xu, MZ; Yu, P; Zhou, X; Gao, CT; Wang, XW; Shi, ZD; Zheng, L; Yang, JF; Shin, B; Arbiol, J; Duan, HG; Du, YH; Heggen, M; Dunin-Borkowski, RE; Guo, WL; Wang, QJ; Zhang, ZH; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yongmin; Liu, Liren; Zhu, Chao; Guo, Shasha; Golani, Prafful; Koo, Bonhyeong; Tang, Pengyi; Zhao, Zhiqiang; Xu, Manzhang; Yu, Peng; Zhou, Xin; Gao, Caitian; Wang, Xuewen; Shi, Zude; Zheng, Lu; Yang, Jiefu; Shin, Byungha; Arbiol, Jordi; Duan, Huigao; Du, Yonghua; Heggen, Marc; Dunin-Borkowski, Rafal E.; Guo, Wanlin; Wang, Qi Jie; Zhang, Zhuhua; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of noble metal catalysts with the potential to leverage efficiency is vital for industrial applications. Such an ultimate atom-utilization efficiency can be achieved when all noble metal atoms exclusively contribute to catalysis. Here, we demonstrate the fabrication of a wafer-size amorphous PtSex film on a SiO2 substate via a low-temperature amorphization strategy, which offers single-atom-layer Pt catalysts with high atom-utilization efficiency (similar to 26 wt%). This amorphous PtSex (1.2 < x < 1.3) relative to a pure Pt surface and reliable production of sustained high-flux hydrogen over a 2 inch wafer as a proof-of-concept. Furthermore, an electrolyser is demonstrated to generate a high current density of 1,000 mA cm(-2). Such an amorphization strategy is potentially extendable to other noble metals, including the Pd, Ir, Os, Rh and Ru elements, demonstrating the universality of single-atom-layer catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 221, "Article Number": null, "DOI": "10.1038/s41929-022-00753-y", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00753-y", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766418700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stroppa, A; Di Sante, D; Barone, P; Bokdam, M; Kresse, G; Franchini, C; Whangbo, MH; Picozzi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stroppa, Alessandro; Di Sante, Domenico; Barone, Paolo; Bokdam, Menno; Kresse, Georg; Franchini, Cesare; Whangbo, Myung-Hwan; Picozzi, Silvia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable ferroelectric polarization and its interplay with spin-orbit coupling in tin iodide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectricity is a potentially crucial issue in halide perovskites, breakthrough materials in photovoltaic research. Using density functional theory simulations and symmetry analysis, we show that the lead-free perovskite iodide (FA) SnI3, containing the planar formamidinium cation FA, (NH2CHNH2)(+), is ferroelectric. In fact, the perpendicular arrangement of FA planes, leading to a 'weak' polarization, is energetically more stable than parallel arrangements of FA planes, being either antiferroelectric or 'strong' ferroelectric. Moreover, we show that the 'weak' and 'strong' ferroelectric states with the polar axis along different crystallographic directions are energetically competing. Therefore, at least at low temperatures, an electric field could stabilize different states with the polarization rotated by pi/4, resulting in a highly tunable ferroelectricity appealing for multistate logic. Intriguingly, the relatively strong spin-orbit coupling in noncentrosymmetric (FA)SnI3 gives rise to a co-existence of Rashba and Dresselhaus effects and to a spin texture that can be induced, tuned and switched by an electric field controlling the ferroelectric state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5900, "DOI": "10.1038/ncomms6900", "DOI Link": "http://dx.doi.org/10.1038/ncomms6900", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347176500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "López-Valdeolivas, M; Liu, DQ; Broer, DJ; Sánchez-Somolinos, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lopez-Valdeolivas, Maria; Liu, Danqing; Broer, Dick Jan; Sanchez-Somolinos, Carlos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4D Printed Actuators with Soft-Robotic Functions", "Source Title": "MACROMOLECULAR RAPID COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft matter elements undergoing programed, reversible shape change can contribute to fundamental advance in areas such as optics, medicine, microfluidics, and robotics. Crosslinked liquid crystalline polymers have demonstrated huge potential to implement soft responsive elements; however, the complexity and size of the actuators are limited by the current dominullt thin-film geometry processing toolbox. Using 3D printing, stimuli-responsive liquid crystalline elastomeric structures are created here. The printing process prescribes a reversible shape-morphing behavior, offering a new paradigm for active polymer system preparation. The additive character of this technology also leads to unprecedented geometries, complex functions, and sizes beyond those of typical thin-films. The fundamental concepts and devices presented therefore overcome the current limitations of actuation energy available from thin-films, thereby narrowing the gap between materials and practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 39, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700710, "DOI": "10.1002/marc.201700710", "DOI Link": "http://dx.doi.org/10.1002/marc.201700710", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426647000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Li, YB; Zhao, B; Liu, SS; Zhang, HB; Chen, K; Li, M; Du, SY; Xiu, FX; Che, RC; Chai, ZF; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Lu; Li, Youbing; Zhao, Biao; Liu, Shanshan; Zhang, Huibin; Chen, Ke; Li, Mian; Du, Shiyu; Xiu, Faxian; Che, Renchao; Chai, Zhifang; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiprincipal Element M2FeC (M = Ti,V,Nb,Ta,Zr) MAX Phases with Synergistic Effect of Dielectric and Magnetic Loss", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic (EM) wave pollution is harmful to human health and environment, thus it is absolutely important to develop new electromagnetic wave absorbing materials. MAX phases have been attracted more attention as a potential candidate for electromagnetic wave absorbing materials due to their high conductivity and nullolaminated structure. Herein, two new magnetic MAX phases with multiprincipal elements ((Ti1/3Nb1/3Ta1/3)(2)FeC and (Ti0.2V0.2Nb0.2Ta0.2Zr0.2)(2)FeC) in which Fe atoms replace Al atoms in the A sites are successfully synthesized by an isomorphous replacement reaction of multiprincipal (Ti1/3Nb1/3Ta1/3)(2)AlC and (Ti0.2V0.2Nb0.2Ta0.2Zr0.2)(2)AlC MAX phases with Lewis acid salt (FeCl2). (Ti1/3Nb1/3Ta1/3)(2)FeC and (Ti0.2V0.2Nb0.2Ta0.2Zr0.2)(2)FeC exhibit ferromagnetic behavior, and the Curie temperature (T-c) are 302 and 235 K, respectively. The dual electromagnetic absorption mechanisms that include dielectric and magnetic loss, which is realized in these multiprincipal MAX phases. The minimum reflection loss (RL) of (Ti1/3Nb1/3Ta1/3)(2)FeC is -44.4 dB at 6.56 GHz with 3 mm thickness, and the effective bandwidth is 2.48 GHz. Additionally, the electromagnetic wave absorption properties of the magnetic MAX phases indicate that magnetic loss also plays an important role besides dielectric loss. This work shows a promising composition-design strategy to develop MAX phases with good EM wave absorption performance via simultaneously regulating dielectric and magnetic loss together.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206877", "DOI Link": "http://dx.doi.org/10.1002/advs.202206877", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000924115800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Razaq, R; Din, MMU; Småbråten, DR; Eyupoglu, V; Janakiram, S; Sunde, TO; Allahgoli, N; Rettenwander, D; Deng, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Razaq, Rameez; Din, Mir Mehraj Ud; Smabraten, Didrik Rene; Eyupoglu, Volkan; Janakiram, Saravanull; Sunde, Tor Olav; Allahgoli, Nima; Rettenwander, Daniel; Deng, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Effect of Bimetallic MOF Modified Separator for Long Cycle Life Lithium-Sulfur Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Severe polysulfide dissolution and shuttling are the main challenges that plague the long cycle life and capacity retention of lithium-sulfur (Li-S) batteries. To address these challenges, efficient separators are designed and modified with a dual functional bimetallic metal-organic framework (MOF). Flower-shaped bimetallic MOFs (i.e., Fe-ZIF-8) with nullostructured pores are synthesized at 35 degrees C in water by introducing dopant metal sites (Fe), which are then coated on a polypropylene (PP) separator to provide selective channels, thereby effectively inhibiting the migration of lithium polysulfides while allowing homogeneous transport of Li-ions. The active sites of the Fe-ZIF-8 enable electrocatalytic conversion, facilitating the conversion of lithium polysulfides. Moreover, the developed separator can prevent dendrite formation due to the uniform pore size and hence the even Li-ion transport and deposition. A coin cell using a Fe-ZIF-8/PP separator with S-loaded carbon cathode displayed a high cycle life of 1000 cycles with a high initial discharge capacity of 863 mAh g-1 at 0.5 C and a discharge capacity of 746 mAh g-1 at a high rate of 3 C. Promising specific capacity has been documented even under high sulfur loading of 5.0 mg cm-2 and electrolyte to the sulfur ratio (E/S) of 5 mu L mg-1. A multifunctional bimetallic MOF-based separator is designed specifically for lithium-sulfur batteries that can selectively block and convert polysulfides while providing even transport of lithium ions. Remarkably higher catalytic activity is found for the conversion of polysulfides by the Fe-doped MOF (ZIF-8) compared to the parent ZIF-8. Meanwhile, the incorporation of Fe (II) centers into the ZIF framework dramatically improves the specific capacity and rate capability.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202302897", "DOI Link": "http://dx.doi.org/10.1002/aenm.202302897", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001105691300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, GR; Dai, ZH; Wang, YL; Tan, PH; Liu, LQ; Xu, ZP; Wei, YG; Huang, R; Zhang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Guorui; Dai, Zhaohe; Wang, Yanlei; Tan, PingHeng; Liu, Luqi; Xu, Zhiping; Wei, Yueguang; Huang, Rui; Zhang, Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "\\Measuring Interlayer Shear Stress in Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer two-dimensional (2D) crystals exhibit a host of intriguing properties, but the most exciting applications may come from stacking them into multilayer structures. Interlayer and interfacial shear interactions could play a crucial role in the performance and reliability of these applications, but little is known about the key parameters controlling shear deformation across the layers and interfaces between 2D materials. Herein, we report the first measurement of the interlayer shear stress of bilayer graphene based on pressurized microscale bubble loading devices. We demonstrate continuous growth of an interlayer shear zone outside the bubble edge and extract an interlayer shear stress of 40 kPa based on a membrane analysis for bilayer graphene bubbles. Meanwhile, a much higher interfacial shear stress of 1.64 MPa was determined for monolayer graphene on a silicon oxide substrate. Our results not only provide insights into the interfacial shear responses of the thinnest structures possible, but also establish an experimental method for characterizing the fundamental interlayer shear properties of the emerging 2D materials for potential applications in multilayer systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2017, "Volume": 119, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36101, "DOI": "10.1103/PhysRevLett.119.036101", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.036101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405718000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YS; Cao, XX; Luo, ZG; Fang, GZ; Liu, F; Zhou, J; Pan, AQ; Liang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yangsheng; Cao, Xinxin; Luo, Zhigao; Fang, Guozhao; Liu, Fei; Zhou, Jiang; Pan, Anqiang; Liang, Shuquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Caging Na3V2(PO4)2F3 Microcubes in Cross-Linked Graphene Enabling Ultrafast Sodium Storage and Long-Term Cycling", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are widely regarded as a promising supplement for lithium-ion battery technology. However, it still suffers from some challenges, including low energy/power density and unsatisfactory cycling stability. Here, a cross-linked graphene-caged Na3V2(PO4)(2)F-3 microcubes (NVPF@rGO) composite via a one-pot hydrothermal strategy followed by freeze drying and heat treatment is reported. As a cathode for a sodium-ion half-cell, the NVPF@rGO delivers excellent cycling stability and rate capability, as well as good low temperature adaptability. The structural evolution during the repeated Na+ extraction/insertion and Na ions diffusion kinetics in the NVPF@rGO electrode are investigated. Importantly, a practicable sodium-ion full-cell is constructed using a NVPF@rGO cathode and a N-doped carbon anode, which delivers outstanding cycling stability (95.1% capacity retention over 400 cycles at 10 C), as well as an exceptionally high energy density (291 Wh kg(-1) at power density of 192 W kg(-1)). Such micro-/nulloscale design and engineering strategies, as well as deeper understanding of the ion diffusion kinetics, may also be used to explore other micro-/nullostructure materials to boost the performance of energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800680, "DOI": "10.1002/advs.201800680", "DOI Link": "http://dx.doi.org/10.1002/advs.201800680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444940600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, XJ; Li, D; Jiang, W; Gu, ZM; Wang, XJ; Zhang, ZX; Sun, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Xiaojun; Li, Dong; Jiang, Wei; Gu, Zheming; Wang, Xiaojuan; Zhang, Zengxing; Sun, Zhengzong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printable Graphene Composite", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In human being's history, both the Iron Age and Silicon Age thrived after a matured massive processing technology was developed. Graphene is the most recent superior material which could potentially initialize another new material Age. However, while being exploited to its full extent, conventional processing methods fail to provide a link to today's personalization tide. New technology should be ushered in. Three-dimensional (3D) printing fills the missing linkage between graphene materials and the digital mainstream. Their alliance could generate additional stream to push the graphene revolution into a new phase. Here we demonstrate for the first time, a graphene composite, with a graphene loading up to 5.6 wt%, can be 3D printable into computer-designed models. The composite's linear thermal coefficient is below 75 ppm.degrees C-1 from room temperature to its glass transition temperature (T-g), which is crucial to build minute thermal stress during the printing process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 8", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11181, "DOI": "10.1038/srep11181", "DOI Link": "http://dx.doi.org/10.1038/srep11181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357571400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, ZY; Choi, JH; Zhang, Q; Qin, W; Yi, SH; Wang, PD; Li, L; Wang, YF; Zhang, H; Sun, Z; Wei, LM; Zhang, SB; Guo, TF; Lu, QY; Cho, JH; Zeng, CG; Zhang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Zhiyong; Choi, Jin-Ho; Zhang, Qiang; Qin, Wei; Yi, Seho; Wang, Pengdong; Li, Lin; Wang, Yifan; Zhang, Hui; Sun, Zhe; Wei, Laiming; Zhang, Shengbai; Guo, Tengfei; Lu, Qingyou; Cho, Jun-Hyung; Zeng, Changgan; Zhang, Zhenyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flatbands and Emergent Ferromagnetic Ordering in Fe3Sn2 Kagome Lattices", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A flatband representing a highly degenerate and dispersionless manifold state of electrons may offer unique opportunities for the emergence of exotic quantum phases. To date, definitive experimental demonstrations of flatbands remain to be accomplished in realistic materials. Here, we present the first experimental observation of a striking flatband near the Fermi level in the layered Fe3Sn2 crystal consisting of two Fe kagome lattices separated by a Sn spacing layer. The band flatness is attributed to the local destructive interferences of Bloch wave functions within the kagome lattices, as confirmed through theoretical calculations and modelings. We also establish high-temperature ferromagnetic ordering in the system and interpret the observed collective phenomenon as a consequence of the synergetic effect of electron correlation and the peculiar lattice geometry. Specifically, local spin moments formed by intramolecular exchange interaction are ferromagnetically coupled through a unique network of the hexagonal units in the kagome lattice. Our findings have important implications to exploit emergent flatband physics in special lattice geometries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2018, "Volume": 121, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 96401, "DOI": "10.1103/PhysRevLett.121.096401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.096401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442816500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YW; Hao, J; Liu, HY; Li, YL; Ma, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yinwei; Hao, Jian; Liu, Hanyu; Li, Yanling; Ma, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The metallization and superconductivity of dense hydrogen sulfide", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water (H2O). The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the pressure-induced weakening of S-H bond and larger atomic core difference between H and S. Metallization is yet achieved for H2O, but it was observed for H2S above 96 GPa. However, the metallic structure of H2S remains elusive, greatly impeding the understanding of its metallicity and the potential superconductivity. We have performed an extensive structural study on solid H2S at pressure ranges of 10-200 GPa through an unbiased structure prediction method based on particle swarm optimization algorithm. Besides the findings of candidate structures for nonmetallic phases IV and V, we are able to establish stable metallic structures violating an earlier proposal of elemental decomposition into sulfur and hydrogen [R. Rousseau, M. Boero, M. Bernasconi, M. Parrinello, and K. Terakura, Phys. Rev. Lett. 85, 1254 (2000)]. Our study unravels a superconductive potential of metallic H2S with an estimated maximal transition temperature of similar to 80 K at 160 GPa, higher than those predicted for most archetypal hydrogen-containing compounds (e.g., SiH4, GeH4, etc.). (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2014, "Volume": 140, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 174712, "DOI": "10.1063/1.4874158", "DOI Link": "http://dx.doi.org/10.1063/1.4874158", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336048000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YP; Lei, JH; Wang, G; Zhang, ZM; Wu, J; Zhang, BH; Zhang, HQ; Liu, ES; Wang, LM; Liu, TM; Xing, GC; Ouyang, DF; Deng, CX; Tang, ZK; Qu, SN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yupeng; Lei, Josh Haipeng; Wang, Gang; Zhang, Zhiming; Wu, Jun; Zhang, Bohan; Zhang, Huiqi; Liu, Enshan; Wang, Liming; Liu, Tzu-Ming; Xing, Guichuan; Ouyang, Defang; Deng, Chu-Xia; Tang, Zikang; Qu, Songnull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward Strong Near-Infrared Absorption/Emission from Carbon Dots in Aqueous Media through Solvothermal Fusion of Large Conjugated Perylene Derivatives with Post-Surface Engineering", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots (CDs) have attracted significant interest as one of the most emerging photoluminescence (PL) nullomaterials. However, the realization of CDs with dominullt near-infrared (NIR) absorption/emission peaks in aqueous solution remains a great challenge. Herein, CDs with both main NIR absorption bands at 720 nm and NIR emission bands at 745 nm in an aqueous solution are fabricated for the first time by fusing large conjugated perylene derivatives under solvothermal treatment. With post-surface engineering, the polyethyleneimine modified CDs (PEI-CDs) exhibit enhanced PL quantum yields (PLQY) up to 8.3% and 18.8% in bovine serum albumin aqueous and DMF solutions, which is the highest PLQY of CDs in NIR region under NIR excitation. Density functional theory calculations support the strategy of fusing large conjugated perylene derivatives to achieve NIR emissions from CDs. Compared to the commercial NIR dye Indocyanine green, PEI-CDs exhibit excellent photostability and much lower cost. Furthermore, the obtained PEI-CDs illustrate the advantages of remarkable two-photon NIR angiography and in vivo NIR fluorescence bioimaging. This work demonstrates a promising strategy of fusing large conjugated molecules for preparing CDs with strong NIR absorption/emission to promote their bioimaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 9, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202283, "DOI": "10.1002/advs.202202283", "DOI Link": "http://dx.doi.org/10.1002/advs.202202283", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804578400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kasap, H; Caputo, CA; Martindale, BCM; Godin, R; Lau, VWH; Lotsch, BV; Durrant, JR; Reisner, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kasap, Hatice; Caputo, Christine A.; Martindale, Benjamin C. M.; Godin, Robert; Lau, Vincent Wing-hei; Lotsch, Bettina V.; Durrant, James R.; Reisner, Erwin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar-Driven Reduction of Aqueous Protons Coupled to Selective Alcohol Oxidation with a Carbon Nitride-Molecular Ni Catalyst System", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar water-splitting represents an important strategy toward production of the storable and renewable fuel hydrogen. The water oxidation half-reaction typically proceeds with poor efficiency and produces the unprofitable and often damaging product, O-2. Herein, we demonstrate an alternative approach and couple solar H-2 generation with value-added organic substrate oxidation. Solar irradiation of a cyanamide surface-functionalized melon-type carbon nitride ((CNx)-C-NCN) and a molecular nickel(II) bis(diphosphine) H-2-evolution catalyst (NiP) enabled the production of H-2 with concomitant selective oxidation of benzylic alcohols to aldehydes in high yield under purely aqueous conditions, at room temperature and ambient pressure. This one-pot system maintained its activity over 24 h, generating products in 1:1 stoichiometry, separated in the gas and solution phases. The (CNx)-C-NCN-NiP system showed an activity of 763 mu mol (g CNx)(-1) h(-1) toward H-2 and aldehyde production, a Ni-based turnover frequency of 76 h(-1), and an external quantum efficiency of 15% (lambda = 360 +/- 10 nm). This precious metal-free and nontoxic photocatalytic system displays better performance than an analogous system containing platinum instead of NiP. Transient absorption spectroscopy revealed that the photoactivity of (CNx)-C-NCN is due to efficient substrate oxidation of the material, which outweighs possible charge recombination compared to the nonfunctionalized melon type carbon nitride. Photoexcited (CNx)-C-NCN in the presence of an organic substrate can accumulate ultralong-lived trapped electrons, which allow for fuel generation in the dark. The artificial photosynthetic system thereby catalyzes a closed redox cycle showing 100% atom economy and generates two value-added products, a solar chemical, and solar fuel.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2016, "Volume": 138, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9183, "End Page": 9192, "Article Number": null, "DOI": "10.1021/jacs.6b04325", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b04325", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380730000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lao, J; Yan, MG; Tian, BB; Jiang, CL; Luo, CH; Xie, ZZ; Zhu, QX; Bao, ZQ; Zhong, N; Tang, XD; Sun, LF; Wu, GJ; Wang, JL; Peng, H; Chu, JH; Duan, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lao, Jie; Yan, Mengge; Tian, Bobo; Jiang, Chunli; Luo, Chunhua; Xie, Zhuozhuang; Zhu, Qiuxiang; Bao, Zhiqiang; Zhong, Ni; Tang, Xiaodong; Sun, Linfeng; Wu, Guangjian; Wang, Jianlu; Peng, Hui; Chu, Junhao; Duan, Chungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralow-Power Machine Vision with Self-Powered Sensor Reservoir", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A neuromorphic visual system integrating optoelectronic synapses to perform the in-sensor computing is triggering a revolution due to the reduction of latency and energy consumption. Here it is demonstrated that the dwell time of photon-generated carriers in the space-charge region can be effectively extended by embedding a potential well on the shoulder of Schottky energy barrier. It permits the nonlinear interaction of photocurrents stimulated by spatiotemporal optical signals, which is necessary for in-sensor reservoir computing (RC). The machine vision with the sensor reservoir constituted by designed self-powered Au/P(VDF-TrFE)/Cs2AgBiBr6/ITO devices is competent for both static and dynamic vision tasks. It shows an accuracy of 99.97% for face classification and 100% for dynamic vehicle flow recognition. The in-sensor RC system takes advantage of near-zero energy consumption in the reservoir, resulting in decades-time lower training costs than a conventional neural network. This work paves the way for ultralow-power machine vision using photonic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2106092, "DOI": "10.1002/advs.202106092", "DOI Link": "http://dx.doi.org/10.1002/advs.202106092", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768413400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, RP; Ma, LX; Hong, XL; Reina, TR; Luo, WH; Kang, LQ; Feng, G; Zhang, RB; Fan, MH; Zhang, RG; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Runping; Ma, Lixuan; Hong, Xiaoling; Reina, Tomas Ramirez; Luo, Wenhao; Kang, Liqun; Feng, Gang; Zhang, Rongbin; Fan, Maohong; Zhang, Riguang; Liu, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Low-Temperature CO2 Hydrogenation over Ni-based Catalysts by Tuning Strong Metal-Support Interactions", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of low-cost and efficient transition-metal catalysts for low-temperature CO2 activation is significant and poses great challenges. Herein, a strategy via regulating the local electron density of active sites is developed to boost CO2 methanation that normally requires >350 degrees C for commercial Ni catalysts. An optimal Ni/ZrO2 catalyst affords an excellent low-temperature performance hitherto, with a CO2 conversion of 84.0 %, CH4 selectivity of 98.6 % even at 230 degrees C and GHSV of 12,000 mL g(-1) h(-1) for 106 h, reflecting one of the best CO2 methanation performance to date on Ni-based catalysts. Combined a series of in situ spectroscopic characterization studies reveal that re-constructing monoclinic-ZrO2 supported Ni species with abundant oxygen vacancies can facilitate CO2 activation, owing to the enhanced local electron density of Ni induced by the strong metal-support interactions. These findings might be of great aid for construction of robust catalysts with an enhanced performance for CO2 emission abatement and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2024, "Volume": 63, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202317669", "DOI Link": "http://dx.doi.org/10.1002/anie.202317669", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001117638400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, H; Xue, K; Zhang, YX; Xiao, MH; Wu, KY; Shi, LQ; Zhu, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Hao; Xue, Ke; Zhang, Yongxin; Xiao, Minghui; Wu, Kaiyu; Shi, Linqi; Zhu, Chunlei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoresponsive Hydrogel-Enabled Thermostatic Photothermal Therapy for Enhanced Healing of Bacteria-Infected Wounds", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) has emerged as an attractive technique for the treatment of bacterial infections. However, the uncontrolled heat generation in conventional PTT inevitably causes thermal damages to healthy tissues and/or organs. It is thus essential to develop a smart and universal strategy to regulate the photothermal equilibrium temperature to a preset safe threshold. Herein, a thermoresponsive hydrogel-enabled thermostatic PTT system for enhanced healing of bacteria-infected wounds is reported. In this system, the near-infrared (NIR)-triggered heat generation by photothermal nullomaterials is spontaneously transferred to a thermoresponsive hydrogel with a lower critical solution temperature (LCST), leading to its rapid phase transition by forming considerable light-scattering centers to block NIR penetration. Such a dynamic and reversible process automatically regulates the photothermal equilibrium temperature to the phase-transition point of the LCST-type hydrogel. In contrast to temperature-uncontrolled conventional PTT with severe thermal damages, the thermoresponsive hydrogel-enabled thermostatic PTT provides effective protection on healthy tissues and/or organs, which remarkably accelerates wound healing by efficient bacterial eradication. This study establishes a smart, simple and universal PTT platform, holding great promise in the safe and efficient treatment of bacterial skin infections.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 10, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206865", "DOI Link": "http://dx.doi.org/10.1002/advs.202206865", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930012500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Liu, XH; Jia, CY; Sun, ZS; Jiang, HW; Jia, ZR; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuo; Liu, Xuehua; Jia, Chenyu; Sun, Zhengshuo; Jiang, Haowen; Jia, Zirui; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of Multiple Heterointerfaces in a Hierarchical 0D@2D@1D Structure for Lightweight, Flexible, and Hydrophobic Multifunctional Electromagnetic Protective Fabrics", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of wearable multifunctional electromagnetic protective fabrics with multifunctional, low cost, and high efficiency remains a challenge. Here, inspired by the unique flower branch shape of Thunberg's meadowsweet in nature, a nullofibrous composite membrane with hierarchical structure was constructed. Integrating sophisticated 0D@2D@1D hierarchical structures with multiple heterointerfaces can fully unleash the multifunctional application potential of composite membrane. The targeted induction method was used to precisely regulate the formation site and morphology of the metal-organic framework precursor, and intelligently integrate multiple heterostructures to enhance dielectric polarization, which improves the impedance matching and loss mechanisms of the electromagnetic wave absorbing materials. Due to the synergistic enhancement of electrospinning-derived carbon nullofiber stems, MOF-derived carbon nullosheet petals and transition metal selenide nullo-particle stamens, the CoxSey/ NiSe@CNSs@CNFs (CNCC) composite membrane obtains a minimum reflection loss value (RLmin) of-68.40 dB at 2.6 mm and a maximum effective absorption bandwidth (EAB) of 8.88 GHz at a thin thickness of 2.0 mm with a filling amount of only 5 wt%. In addition, the multi-component and hierarchical hetero-structure endow the fibrous membrane with excellent flexibility, water resistance, thermal management, and other multifunctional properties. This work provides unique perspectives for the precise design and rational application of multifunctional fabrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 204, "DOI": "10.1007/s40820-023-01179-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01179-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001093856000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, LS; Li, D; Soto, FA; Ponce, V; Zhang, B; Ma, L; Deng, T; Seminario, JM; Hu, EY; Yang, XQ; Balbuena, PB; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Longsheng; Li, Dan; Soto, Fernulldo A.; Ponce, Victor; Zhang, Bao; Ma, Lu; Deng, Tao; Seminario, Jorge M.; Hu, Enyuan; Yang, Xiao-Qing; Balbuena, Perla B.; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Reversible Aqueous Zinc Batteries enabled by Zincophilic-Zincophobic Interfacial Layers and Interrupted Hydrogen-Bond Electrolytes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn batteries promise high energy density but suffer from Zn dendritic growth and poor low-temperature performance. Here, we overcome both challenges by using an eutectic 7.6 m ZnCl2 aqueous electrolyte with 0.05 m SnCl2 additive, which in situ forms a zincophilic/zincophobic Sn/Zn-5(OH)(8)Cl-2 center dot H2O bilayer interphase and enables low temperature operation. Zincophilic Sn decreases Zn plating/stripping overpotential and promotes uniform Zn plating, while zincophobic Zn-5(OH)(8)Cl-2 center dot H2O top-layer suppresses Zn dendrite growth. The eutectic electrolyte has a high ionic conductivity of approximate to 0.8 mS cm(-1) even at -70 degrees C due to the distortion of hydrogen bond network by solvated Zn2+ and Cl-. The eutectic electrolyte enables Zn parallel to Ti half-cell a high Coulombic efficiency (CE) of >99.7 % for 200 cycles and Zn parallel to Zn cell steady charge/discharge for 500 h with a low overpotential of 8 mV at 3 mA cm(-2). Practically, Zn parallel to VOPO4 batteries maintain >95 % capacity with a CE of >99.9 % for 200 cycles at -50 degrees C, and retain approximate to 30 % capacity at -70 degrees C of that at 20 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2021, "Volume": 60, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18845, "End Page": 18851, "Article Number": null, "DOI": "10.1002/anie.202107378", "DOI Link": "http://dx.doi.org/10.1002/anie.202107378", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000673145600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Kowsari, K; Serjouei, A; Dunn, ML; Ge, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Biao; Kowsari, Kavin; Serjouei, Ahmad; Dunn, Martin L.; Ge, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reprocessable thermosets for sustainable three-dimensional printing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among all three-dimensional (3D) printing materials, thermosetting photopolymers claim almost half of the market, and have been widely used in various fields owing to their superior mechanical stability at high temperatures, excellent chemical resistance as well as good compatibility with high-resolution 3D printing technologies. However, once these thermosetting photopolymers form 3D parts through photopolymerization, the covalent networks are permanent and cannot be reprocessed, i.e., reshaped, repaired, or recycled. Here, we report a two-step polymerization strategy to develop 3D printing reprocessable thermosets (3DPRTs) that allow users to reform a printed 3D structure into a new arbitrary shape, repair a broken part by simply 3D printing new material on the damaged site, and recycle unwanted printed parts so the material can be reused for other applications. These 3DPRTs provide a practical solution to address environmental challenges associated with the rapid increase in consumption of 3D printing materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1831, "DOI": "10.1038/s41467-018-04292-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04292-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431630400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dufferwiel, S; Schwarz, S; Withers, F; Trichet, AAP; Li, F; Sich, M; Del Pozo-Zamudio, O; Clark, C; Nalitov, A; Solnyshkov, DD; Malpuech, G; Novoselov, KS; Smith, JM; Skolnick, MS; Krizhanovskii, DN; Tartakovskii, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dufferwiel, S.; Schwarz, S.; Withers, F.; Trichet, A. A. P.; Li, F.; Sich, M.; Del Pozo-Zamudio, O.; Clark, C.; Nalitov, A.; Solnyshkov, D. D.; Malpuech, G.; Novoselov, K. S.; Smith, J. M.; Skolnick, M. S.; Krizhanovskii, D. N.; Tartakovskii, A. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton-polaritons in van der Waals heterostructures embedded in tunable microcavities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered materials can be assembled vertically to fabricate a new class of van der Waals heterostructures a few atomic layers thick, compatible with a wide range of substrates and optoelectronic device geometries, enabling new strategies for control of light-matter coupling. Here, we incorporate molybdenum diselenide/hexagonal boron nitride (MoSe2/hBN) quantum wells in a tunable optical microcavity. Part-light-part-matter polariton eigenstates are observed as a result of the strong coupling between MoSe2 excitons and cavity photons, evidenced from a clear anticrossing between the neutral exciton and the cavity modes with a splitting of 20 meV for a single MoSe2 monolayer, enhanced to 29 meV in MoSe2/hBN/MoSe2 double-quantum wells. The splitting at resonullce provides an estimate of the exciton radiative lifetime of 0.4 ps. Our results pave the way for room-temperature polaritonic devices based on multiple-quantum-well van der Waals heterostructures, where polariton condensation and electrical polariton injection through the incorporation of graphene contacts may be realized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8579, "DOI": "10.1038/ncomms9579", "DOI Link": "http://dx.doi.org/10.1038/ncomms9579", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364932600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JC; Chen, GB; Liu, QC; Fan, C; Sun, DM; Tang, YW; Sun, HJ; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiachen; Chen, Guangbo; Liu, Qicheng; Fan, Chuang; Sun, Dongmei; Tang, Yawen; Sun, Hanjun; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Competitive Adsorption: Reducing the Poisoning Effect of Adsorbed Hydroxyl on Ru Single-Atom Site with SnO2 for Efficient Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ruthenium (Ru) has been theoretically considered a viable alkaline hydrogen evolution reaction electrocatalyst due to its fast water dissociation kinetics. However, its strong affinity to the adsorbed hydroxyl (OHad) blocks the active sites, resulting in unsatisfactory performance during the practical HER process. Here, we first reported a competitive adsorption strategy for the construction of SnO2 nulloparticles doped with Ru single-atoms supported on carbon (Ru SAs-SnO2/C) via atomic galvanic replacement. SnO2 was introduced to regulate the strong interaction between Ru and OHad by the competitive adsorption of OHad between Ru and SnO2, which alleviated the poisoning of Ru sites. As a consequence, the Ru SAs-SnO2/C exhibited a low overpotential at 10 mA cm(-2) (10 mV) and a low Tafel slope of 25 mV dec(-1). This approach provides a new avenue to modulate the adsorption strength of active sites and intermediates, which paves the way for the development of highly active electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2022, "Volume": 61, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202209486", "DOI": "10.1002/anie.202209486", "DOI Link": "http://dx.doi.org/10.1002/anie.202209486", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843764200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, HX; Xiong, WQ; Lv, PF; Yu, J; Yuan, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Hongxia; Xiong, Wenqi; Lv, Pengfei; Yu, Jin; Yuan, Shengjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain-induced semiconductor to metal transition in MA2Z4 bilayers (M = Ti, Cr, Mo; A = Si; Z = N, P)", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Very recently, a new type of two-dimensional layered material, MoSi2N4, was fabricated that is semiconducting with weak interlayer interaction, high strength, and excellent stability. We systematically investigate the effect of vertical strain on the electronic structure of MA(2)Z(4) (M = Ti/Cr/Mo, A = Si, Z = N/P) bilayers. Taking bilayer MoSi2N4 as an example, our first-principles calculations show that its indirect band gap decreases monotonically as the vertical compressive strain increases. Under a critical strain around 22%, it undergoes a transition from semiconductor to metal. We attribute this to the opposite energy shift of states in different layers, which originates from the built-in electric field induced by the asymmetric charge transfer between two inner sublayers near the interface. Similar semiconductor to metal transitions are observed in other strained MA(2)Z(4) bilayers, and the estimated critical pressures to realize such transitions are within the same order as semiconducting transition metal dichalcogenides. The semiconductor to metal transitions in the family of MA(2)Z(4) bilayers present interesting possibilities for strain-induced engineering of their electronic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 103, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85124, "DOI": "10.1103/PhysRevB.103.085124", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.103.085124", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619134100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Z; Wang, T; Zhang, HX; Liu, YH; Xing, BS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhen; Wang, Tao; Zhang, Huixue; Liu, Yonghong; Xing, Baoshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of Pb(II) and Cd(II) by magnetic activated carbon and its mechanism", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetized activated carbons (MAC) were prepared by activating rape straw powder, and pyrolyzing at different temperatures, then magnetizing activated carbon by hydrothermal method. MAC-300 had the largest adsorption capacity of Pb(II) (253.2 mg/g) and Cd(II) (733 mg/g). The adsorption isotherms and kinetics could conform to the Freundlich model and pseudo-second-order kinetic model, respectively, indicating that the adsorptive behavior of the adsorbent mainly depends on the non-uniform active points on the surface of the material. Meanwhile, the thermodynamic parameters showed that the adsorption of Pb(II) and Cd(II) by MAC-300 was a spontaneous and endothermic reaction.The adsorption capacity of MAC-300 could be improved by properly increasing the pH of the original solution. There was competitive adsorption when high-valent ions were present in solution. In combination with various characterizations and comparison tests of samples after adsorption, the adsorption mechanisms include surface electrostatic attraction, surface complexation, and co-precipitation. The results indicated that the MAC material was a potential material to remove heavy metal ions from the aqueous solution. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2021, "Volume": 757, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 143910, "DOI": "10.1016/j.scitotenv.2020.143910", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2020.143910", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604432900111", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, R; Linsenmann, F; Thomas, R; Wandt, J; Solchenbach, S; Maglia, F; Stinner, C; Tromp, M; Gasteiger, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Roland; Linsenmann, Fabian; Thomas, Rowena; Wandt, Johannes; Solchenbach, Sophie; Maglia, Filippo; Stinner, Christoph; Tromp, Moniek; Gasteiger, Hubert A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel, Manganese, and Cobalt Dissolution from Ni-Rich NMC and Their Effects on NMC622-Graphite Cell", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dissolution from the cathode active material and its deposition on the anode causes significant cell aging, studied most intensively for manganese. Owing to their higher specific energy, the current focus is shifting towards nickel-rich layered LiNixMnyCozO2 (NMC, x + y + z = 1) with x > 0.5, so that the effect of Ni dissolution on cell degradation needs to be understood. This study investigates the dissolution of transition metals from a NMC622 cathode and their subsequent deposition on a graphite anode using operando X-ray absorption spectroscopy. We show that in NMC622-graphite cells transition metals dissolve nearly stoichiometrically at potentials > 4.6 V, highlighting the significance of investigating Ni dissolution/deposition. Using NMC622-graphite full-cells with electrolyte containing the bis(trifluoromethane) sulfonimide (TFSI) salts of either Ni, Mn, or Co, we compare the detrimental impact of these metals on cell performance. Using in-situ and ex-situ XRD, we show that the aging mechanism induced by all three metals is the loss of cycleable lithium in the solid electrolyte interface (SEI) of the graphite. This loss is larger in magnitude when Mn is present in the electrolyte compared to Ni and Co, which we ascribe to a higher activity of deposited Mn towards SEI decomposition in comparison to Ni and Co. (C) The Author(s) 2019. Published by ECS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 166, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A378", "End Page": "A389", "Article Number": null, "DOI": "10.1149/2.1151902jes", "DOI Link": "http://dx.doi.org/10.1149/2.1151902jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462063700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Glenn, DR; Bucher, DB; Lee, J; Lukin, MD; Park, H; Walsworth, RL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Glenn, David R.; Bucher, Dominik B.; Lee, Junghyun; Lukin, Mikhail D.; Park, Hongkun; Walsworth, Ronald L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-resolution magnetic resonullce spectroscopy using a solid-state spin sensor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum systems that consist of solid-state electronic spins can be sensitive detectors of nuclear magnetic resonullce (NMR) signals, particularly from very small samples. For example, nitrogen-vacancy centres in diamond have been used to record NMR signals from nullometre-scale samples(1-3), with sensitivity sufficient to detect the magnetic field produced by a single protein(4). However, the best reported spectral resolution for NMR of molecules using nitrogen-vacancy centres is about 100 hertz(5). This is insufficient to resolve the key spectral identifiers of molecular structure that are critical to NMR applications in chemistry, structural biology and materials research, such as scalar couplings (which require a resolution of less than ten hertz(6)) and small chemical shifts (which require a resolution of around one part per million of the nuclear Larmor frequency). Conventional, inductively detected NMR can provide the necessary high spectral resolution, but its limited sensitivity typically requires millimetre-scale samples, precluding applications that involve smaller samples, such as picolitre-volume chemical analysis or correlated optical and NMR microscopy. Here we demonstrate a measurement technique that uses a solid-state spin sensor (a magnetometer) consisting of an ensemble of nitrogen-vacancy centres in combination with a narrowband synchronized readout protocol(7-9) to obtain NMR spectral resolution of about one hertz. We use this technique to observe NMR scalar couplings in a micrometre-scale sample volume of approximately ten picolitres. We also use the ensemble of nitrogen-vacancy centres to apply NMR to thermally polarized nuclear spins and resolve chemicalshift spectra from small molecules. Our technique enables analytical NMR spectroscopy at the scale of single cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 555, "Issue": 7696, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 351, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature25781", "DOI Link": "http://dx.doi.org/10.1038/nature25781", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427477100032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arppe, R; Hyppänen, I; Perälä, N; Peltomaa, R; Kaiser, M; Würth, C; Christ, S; Resch-Genger, U; Schäferling, M; Soukka, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arppe, Riikka; Hyppanen, Iko; Perala, Niina; Peltomaa, Riikka; Kaiser, Martin; Wuerth, Christian; Christ, Simon; Resch-Genger, Ute; Schaferling, Michael; Soukka, Tero", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quenching of the upconversion luminescence of NaYF4:Yb3+,Er3+ and NaYF4:Yb3+,Tm3+ nullophosphors by water: the role of the sensitizer Yb3+ in non-radiative relaxation", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have studied the mechanisms of water-based quenching of the upconversion photoluminescence of upconverting nullophosphors (UCNPs) via luminescence decay measurements for a better understanding of the non-radiative deactivation pathways responsible for the relatively low upconversion luminescence efficiency in aqueous solutions. This included both upconversion luminescence measurements and the direct excitation of emissive energy states of Er3+ and Yb3+ dopants in NaYF4:Yb3+, Er3+ UCNPs by measuring the decays at 550 and 655 nm upon 380 nm excitation and at 980 nm upon 930 nm excitation, respectively. The luminescence intensities and decays were measured from both bare and silanized NaYF4:Yb3+, Er3+ and NaYF4:Yb3+, Tm3+ UCNPs in H2O and D2O. The measurements revealed up to 99.9% quenching of the upconversion photoluminescence intensity of both Er3+ and Tm3+ doped bare nullophosphors by water. Instead of the multiphonon relaxation of excited energy levels of the activators, the main mechanism of quenching was found to be the multiphonon deactivation of the Yb3+ sensitizer ion caused by OH-vibrations on the surface of the nullophosphor. Due to the nonlinear nature of upconversion, the quenching of Yb3+ has a higher order effect on the upconversion emission intensity with the efficient Yb-Yb energy migration in the similar to 35 nm nullocrystals making the whole nullophosphor volume susceptible to surface quenching effects. The study underlines the need of efficient surface passivation for the use of UCNPs as labels in bioanalytical applications performed in aqueous solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11746, "End Page": 11757, "Article Number": null, "DOI": "10.1039/c5nr02100f", "DOI Link": "http://dx.doi.org/10.1039/c5nr02100f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357399600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YD; Wu, X; Wu, P; Zhao, JY; Yang, XF; Owens, G; Xu, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yida; Wu, Xuan; Wu, Pan; Zhao, Jingyuan; Yang, Xiaofei; Owens, Gary; Xu, Haolan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing solar steam generation using a highly thermally conductive evaporator support", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfacial solar steam generation is an efficient water evaporation technology which has promising applications in desalination, sterilization, water purification and treatment. A common component of evaporator design is a thermal-insulation support placed between the photothermal evaporation surface and bulk water. This configuration, common in 2-dimensional (2D) evaporation systems, minimizes heat loss from evaporation surface to bulk water, thus localizing the heat on the evaporation surface for efficient evaporation. This design is subsequently directly adopted for 3-dimensional (3D) evaporators without any consideration if it is appropriate. However, unlike 2D solar evaporators, the 3D evaporators can also harvest additional energy (other than solar light) from the air and bulk water to enhance evaporation rate. In this scenario, the use of thermal insulator support is not proper since it will hinder energy extraction from water. Here, the traditional 3D evaporator configuration was completely redesigned by using highly thermally conductive material, instead of a thermal insulator, to connect evaporation surfaces and the bulk water. Much higher evaporation rates were achieved by this strategy, owing to the rapid heat transfer from the bulk water to the evaporation surfaces. Indoor and outdoor tests both confirmed that evaporation performance could be significantly improved by substituting a thermal insulator with thermally conductive support. These findings will redirect the future design of 3D photothermal evaporators. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2021, "Volume": 66, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2479, "End Page": 2488, "Article Number": null, "DOI": "10.1016/j.scib.2021.09.018", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2021.09.018", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000726409800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, F; Fan, XL; Gao, T; Sun, W; Ma, ZH; Yang, CY; Han, F; Xu, K; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Fei; Fan, Xiulin; Gao, Tao; Sun, Wei; Ma, Zhaohui; Yang, Chongyin; Han, Fudong; Xu, Kang; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Voltage Aqueous Magnesium Ion Batteries", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonaqueous rechargeable magnesium (Mg) batteries suffer from the complicated and moisture-sensitive electrolyte chemistry. Besides electrolytes, the practicality of a Mg battery is also confined by the absence of high-performance electrode materials due to the intrinsically slow Mg2+ diffusion in the solids. In this work, we demonstrated a rechargeable aqueous magnesium ion battery (AMIB) concept of high energy density, fast kinetics, and reversibility. Using a superconcentration approach we expanded the electrochemical stability window of the aqueous electrolyte to 2.0 V. More importantly, two new Mg ion host materials, Li superconcentration approach we expanded the electrochemical stability window of the aqueous electrolyte to 2.0 V. More importantly, two new Mg ion host materials, Li3V2(PO4)(3) and poly pyromellitic dianhydride, were developed and employed as cathode and anode electrodes, respectively. Based on comparisons of the aqueous and nonaqueous systems, the role of water is identified to be critical in the Mg ion mobility in the intercalation host but remaining little detrimental to its non-diffusion controlled process. Compared with the previously reported Mg ion cell delivers an unprecedented high power density of 6400 W kg ion cell delivers an unprecedented high power density of 6400 W kg while retaining 92% of the initial capacity after 6000 cycles, pushing the Mg ion cell to a brand new stage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1121, "End Page": 1128, "Article Number": null, "DOI": "10.1021/acscentsci.7b00361", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00361", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413697100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SL; Nie, YY; Zhu, HY; Xu, YR; Cao, ST; Zhang, JX; Li, YY; Wang, JH; Ning, XH; Kong, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shaolei; Nie, Yuanyuan; Zhu, Hangyu; Xu, Yurui; Cao, Shitai; Zhang, Jiaxue; Li, Yanyan; Wang, Jianhui; Ning, Xinghai; Kong, Desheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsically stretchable electronics with ultrahigh deformability to monitor dynamically moving organs", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsically stretchable electronics represent an attractive platform for next-generation implantable devices by reducing the mechanical mismatch and the immune responses with biological tissues. Despite extensive efforts, soft implantable electronic devices often exhibit an obvious trade-off between electronic performances and mechanical deformability because of limitations of commonly used compliant electronic materials. Here, we introduce a scalable approach to create intrinsically stretchable and implantable electronic devices featuring the deployment of liquid metal components for ultrahigh stretchability up to 400% tensile strain and excellent durability against repetitive deformations. The device architecture further shows long-term stability under physiological conditions, conformal attachments to internal organs, and low interfacial impedance. Successful electrophysiological mapping on rapidly beating hearts demonstrates the potential of intrinsically stretchable electronics for widespread applications in health monitoring, disease diagnosis, and medical therapies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 8, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl5511", "DOI": "10.1126/sciadv.abl5511", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl5511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778886800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, WX; Johnston-Peck, AC; Wolter, T; Yang, WCD; Xu, L; Oh, J; Reeves, BA; Zhou, CS; Holtz, ME; Herzing, AA; Lindenberg, AM; Mavrikakis, M; Cargnello, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Weixin; Johnston-Peck, Aaron C.; Wolter, Trenton; Yang, Wei-Chang D.; Xu, Lang; Oh, Jinwon; Reeves, Benjamin A.; Zhou, Chengshuang; Holtz, Megan E.; Herzing, Andrew A.; Lindenberg, Aaron M.; Mavrikakis, Manos; Cargnello, Matteo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steam-created grain boundaries for methane C-H activation in palladium catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects may display high reactivity because the specific arrangement of atoms differs from crystalline surfaces. We demonstrate that high-temperature steam pretreatment of palladium catalysts provides a 12-fold increase in the mass-specific reaction rate for carbon-hydrogen (C-H) activation in methane oxidation compared with conventional pretreatments. Through a combination of experimental and theoretical methods, we demonstrate that an increase in the grain boundary density through crystal twinning is achieved during the steam pretreatment and oxidation and is responsible for the increased reactivity. The grain boundaries are highly stable during reaction and show specific rates at least two orders of magnitude higher than other sites on the palladium on alumina (Pd/Al2O3) catalysts. Theoretical calculations show that strain introduced by the defective structure can enhance C-H bond activation. Introduction of grain boundaries through laser ablation led to further rate increases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2021, "Volume": 373, "Issue": 6562, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1518, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj5291", "DOI Link": "http://dx.doi.org/10.1126/science.abj5291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698977800052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Selvi, S; Vishvaksenull, A; Rajasekar, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Selvi, S.; Vishvaksenull, A.; Rajasekar, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cold metal transfer (CMT) technology - An overview", "Source Title": "DEFENCE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cold Metal Transfer technology has revolutionized the welding of dissimilar metals and thicker materials by producing improved weld bead aesthetics with controlled metal deposition and low heat-input. In this study, the process, weld combinations, laser-CMT hybrid welding and applications of CMT welding are critically reviewed. Microstructure and other weld characteristics have been discussed at length for various base metal combinations. Particularly, the welding of aluminium and steel with better results has been possible with CMT Welding. The results reviewed in this article indicate that the CMT-Laser hybrid welding is more preferable to Laser or Laser hybrid welding. CMT welding has found applications in automobile industries, defence sectors and power plants as a method of additive manufacturing. (C) 2018 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 28, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.dt.2017.08.002", "DOI Link": "http://dx.doi.org/10.1016/j.dt.2017.08.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426445200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YQ; Zhang, G; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yongqing; Zhang, Gang; Zhang, Yong-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Properties of Phosphorene/Graphene and Phosphorene/Hexagonal Boron Nitride Heterostructures", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vertical integration of two-dimensional materials has recently emerged as an exciting method for the design of novel electronic and optoelectronic devices. Using density functional theory, we investigate the structural and electronic properties of two heterostructures, graphene/phosphorene (G/BP) and hexagonal boron nitride/phosphorene (BN/BP). We found that the interlayer distance, binding energy, and charge transfer in G/BP and BN/BP are similar. Inter layer noncovalent bonding is predicted due to the weak coupling between the p(z) orbital of BP and the pi orbital of graphene and BN. A small amount of electron transfer from graphene and BN, scaling with the vertical strain, renders BP slightly n-doped for both heterostructures. Several attractive characteristics of BP, including direct band gap and linear dichroism, are preserved. However, a large redistribution of electrostatic potential across the interface is observed, which may significantly renormalize the carrier dynamics and affect the excitonic behavior of BP. Our work suggests that graphene and BN can be used not only as an effective capping layer to protect BP from its structural and chemical degradation while still maintaining its major electronic characteristics but also as an active layer to tune the carrier dynamics and optical properties of BP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2015, "Volume": 119, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13929, "End Page": 13936, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b02634", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b02634", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356754900065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Piñeros-Hernulldez, D; Medina-Jaramillo, C; López-Córdoba, A; Goyanes, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pineros-Hernulldez, Danyxa; Medina-Jaramillo, Carolina; Lopez-Cordoba, Alex; Goyanes, Silvia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edible cassava starch films carrying rosemary antioxidant extracts for potential use as active food packaging", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyphenols-rich rosemary extracts (RE) were successfully incorporated within cassava starch films in order to produce active food packaging with antioxidant properties. Films with similar thicknesses (about 200 pm) and water content (15-20%) were obtained (p > 0.05). The polyphenols content of the active films ranged between 4.4 and 13.6 mg of gallic acid equivalents per gram. As the polyphenols content increased, the films showed an increase in their antioxidant activity. Moreover, the films containing the greater extract concentration showed better barrier properties against UV light. Surface hydrophobicity of the films was affected by the extract presence; the active films showed about 40% higher contact angle values (about 51) than the control ones (about 37). Fourier transform infrared spectroscopy and thermogravimetric analysis suggested that RE presence inhibited the bonding between glycerol and starch molecules and as a result the water vapor permeability and mechanical properties of the active films were affected. Migration tests were carried out using water and ethanol 95% as food simulants for aqueous and fatty foods, respectively. After 7 days of film exposition, the total polyphenols content loaded in the films was migrated within the aqueous food simulant, while, only a negligible polyphenol amount was detected in the fatty food one. Finally, the bio-disintegration of the films was tested finding that as the RE content increased the integrity of the RE-containing films was better preserved along the composting. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 63, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 488, "End Page": 495, "Article Number": null, "DOI": "10.1016/j.foodhyd.2016.09.034", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2016.09.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389091600053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghaemi, N; Madaeni, SS; Daraei, P; Rajabi, H; Zinadini, S; Alizadeh, A; Heydari, R; Beygzadeh, M; Ghouzivand, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghaemi, Negin; Madaeni, Sayed S.; Daraei, Parisa; Rajabi, Hamid; Zinadini, Sirus; Alizadeh, Abdolhamid; Heydari, Rouhollah; Beygzadeh, Mojtaba; Ghouzivand, Sohrab", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyethersulfone membrane enhanced with iron oxide nulloparticles for copper removal from water: Application of new functionalized Fe3O4 nulloparticles", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface modification of Fe3O4 nulloparticles was performed by immobilizing silica, metformine, and amine. Mixed matrix PES nullofiltration membrane was prepared by embedding various concentrations of the modified Fe3O4 based nulloparticles. The membranes were characterized in terms of morphology and performance including investigation of SEM and AFM microphotographs, water contact angle, mean pore size and porosity measurements and determination of pure water flux as well as copper ion removal. Embedding iron oxide nulloparticles resulted in a significant rise in the pure water flux as a result of changes in the mean pore radius, porosity and hydrophilicity of the membranes. Moreover, the copper removal capability of prepared membranes remarkably increased because of improved hydrophilicity and also presence of nucleophilic functional groups on nulloparticles. The membrane fabricated with 0.1 wt.% metformine-modified silica coated Fe3O4 nulloparticles showed the highest copper removal (about 92%) due to high affinity in copper adsorption. Moreover, acceptable reusability was found for the membrane with the best performance after several times of usage/regeneration cycles using EDTA as eluting agent. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2015, "Volume": 263, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 112, "Article Number": null, "DOI": "10.1016/j.cej.2014.10.103", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2014.10.103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349062900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ariga, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ariga, Katsuhiko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloarchitectonics: what's coming next after nullotechnology?", "Source Title": "nullOSCALE HORIZONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In science and technology today, the crucial importance of the regulation of nulloscale objects and structures is well recognized. The production of functional material systems using nulloscale units can be achieved via the fusion of nullotechnology with the other research disciplines. This task is a part of the emerging concept of nulloarchitectonics, which is a concept moving beyond the area of nullotechnology. The concept of nulloarchitectonics is supposed to involve the architecting of functional materials using nulloscale units based on the principles of nullotechnology. In this focus article, the essences of nullotechnology and nulloarchitectonics are first explained, together with their historical backgrounds. Then, several examples of material production based on the concept of nulloarchitectonics are introduced via several approaches: (i) from atomic switches to neuromorphic networks; (ii) from atomic nullostructure control to environmental and energy applications; (iii) from interfacial processes to devices; and (iv) from biomolecular assemblies to life science. Finally, perspectives relating to the final goals of the nulloarchitectonics approach are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2021, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 364, "End Page": 378, "Article Number": null, "DOI": "10.1039/d0nh00680g", "DOI Link": "http://dx.doi.org/10.1039/d0nh00680g", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632523700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hunge, YM; Yadav, AA; Kang, SW; Lim, SJ; Kim, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hunge, Y. M.; Yadav, A. A.; Kang, Seok-Won; Lim, Sung Jun; Kim, Hyunmin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible light activated MoS2/ZnO composites for photocatalytic degradation of ciprofloxacin antibiotic and hydrogen production", "Source Title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the photocatalysis process, photon energy is mainly converted into chemical energy with the help of both light and catalyst. This process can be used in different applications like photocatalytic degradation of hazardous compounds, fixation of nitrogen, hydrogen production, air purification, water splitting, carbon dioxide reduction etc. In this research work, multiplicative ZnO and MoS2/ZnO (MZ) composites were synthesized using green chemical methods like the hydrothermal process and used in two different applications i) photocatalytic degradation of ciprofloxacin (CIP) antibiotic and ii) hydrogen production. CIP is not easily biodegradable and is mainly used in various antibacterial treatments. The photocatalytic activity was tested for ZnO and different MoS2/ZnO composites along with this the effect of different amounts of catalysts doses was studied. MoS2/ZnO composites exhibit superior photocatalytic performance than ZnO for photocatalytic degradation of CIP. Using the LC-MS technique possible degradation pathways are proposed. The same photocatalyst materials were used to test the photocatalytic H2 production activity. H2 production rates were found to be 22, 39 and 235 mu mol/g/h for ZnO, MoS2 and MZ-30 composite respectively. Superior photocatalytic activity of MZ-30 composite than ZnO is chiefly attributed to the extended light absorption capacity, effective charge transfer, suitable band alignment between the ZnO and MoS2, minimum recombination of charge carriers etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2023, "Volume": 434, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114250, "DOI": "10.1016/j.jphotochem.2022.114250", "DOI Link": "http://dx.doi.org/10.1016/j.jphotochem.2022.114250", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870209300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, KF; Wei, SQ; Shou, HW; Shen, FR; Chen, SM; Zhang, PJ; Wang, CD; Cao, YY; Guo, X; Luo, M; Zhang, HJ; Ye, BJ; Wu, XJ; He, LH; Song, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Kefu; Wei, Shiqiang; Shou, Hongwei; Shen, Feiran; Chen, Shuangming; Zhang, Pengjun; Wang, Changda; Cao, Yuyang; Guo, Xin; Luo, Mi; Zhang, Hongjun; Ye, Bangjiao; Wu, Xiaojun; He, Lunhua; Song, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defect engineering is a strategy that is attracting widespread attention for the possibility of modifying battery active materials in order to improve the cycling stability of the electrodes. However, accurate investigation and quantification of the effect of the defects on the electrochemical energy storage performance of the cell are not trivial tasks. Herein, we report the quantification of vanadium-defective clusters (i.e., up to 5.7%) in the V2O3 lattice via neutron and X-ray powder diffraction measurements, positron annihilation lifetime spectroscopy, and synchrotron-based X-ray analysis. When the vanadium-defective V2O3 is employed as cathode active material in an aqueous Zn coin cell configuration, capacity retention of about 81% after 30,000 cycles at 5 A g(-1) is achieved. Density functional theory calculations indicate that the vanadium-defective clusters can provide favorable sites for reversible Zn-ion storage. Moreover, the vanadium-defective clusters allow the storage of Zn ions in V2O3, which reduces the electrostatic interaction between the host material and the multivalent ions. Aqueous Zn metal batteries are a promising system for high-power electrochemical energy storage. Here, the authors investigate a defective V2O3 cathode via neutron and X-ray techniques and test the material in Zn metal cell configuration for 30k cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6878, "DOI": "10.1038/s41467-021-27203-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27203-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722866700058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Garrido-Barros, P; Derosa, J; Chalkley, MJ; Peters, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garrido-Barros, Pablo; Derosa, Joseph; Chalkley, Matthew J.; Peters, Jonas C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tandem electrocatalytic N2 fixation via proton-coupled electron transfer", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New electrochemical ammonia (NH3) synthesis technologies are of interest as a complementary route to the Haber-Bosch process for distributed fertilizer generation, and towards exploiting ammonia as a zero-carbon fuel produced via renewably sourced electricity(1). Apropos of these goals is a surge of fundamental research targeting heterogeneous materials as electrocatalysts for the nitrogen reduction reaction (N2RR)(2). These systems generally suffer from poor stability and NH3 selectivity; the hydrogen evolution reaction (HER) outcompetes N2RR3. Molecular catalyst systems can be exquisitely tuned and offer an alternative strategy(4), but progress has been thwarted by the same selectivity issue; HER dominates. Here we describe a tandem catalysis strategy that offers a solution to this puzzle. A molecular complex that can mediate an N-2 reduction cycle is partnered with a co-catalyst that interfaces the electrode and an acid to mediate proton-coupled electron transfer steps, facilitating N-H bond formation at a favourable applied potential (-1.2 V versus Fc(+/0)) and overall thermodynamic efficiency. Certain intermediates of the N2RR cycle would be otherwise unreactive via uncoupled electron transfer or proton transfer steps. Structurally diverse complexes of several metals (W, Mo, Os, Fe) also mediate N2RR electrocatalysis at the same potential in the presence of the mediator, pointing to the generality of this tandem approach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2022, "Volume": 609, "Issue": 7925, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05011-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05011-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849436200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Yang, HT; Hu, B; Zhao, Z; Yuan, J; Xing, YQ; Qian, GJ; Huang, ZH; Li, G; Ye, YH; Ma, S; Ni, SL; Zhang, H; Yin, QW; Gong, CS; Tu, ZJ; Lei, HC; Tan, HX; Zhou, S; Shen, CM; Dong, XL; Yan, BH; Wang, ZQ; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hui; Yang, Haitao; Hu, Bin; Zhao, Zhen; Yuan, Jie; Xing, Yuqing; Qian, Guojian; Huang, Zihao; Li, Geng; Ye, Yuhan; Ma, Sheng; Ni, Shunli; Zhang, Hua; Yin, Qiangwei; Gong, Chunsheng; Tu, Zhijun; Lei, Hechang; Tan, Hengxin; Zhou, Sen; Shen, Chengmin; Dong, Xiaoli; Yan, Binghai; Wang, Ziqiang; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roton pair density wave in a strong-coupling kagome superconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The transition metal kagome lattice materials host frustrated, correlated and topological quantum states of matter(1-9). Recently, a new family of vanadium-based kagome metals, AV(3)Sb(5) (A = K, Rb or Cs), with topological band structures has been discovered(10,11). These layered compounds are nonmagnetic and undergo charge density wave transitions before developing superconductivity at low temperatures(11-19). Here we report the observation of unconventional superconductivity and a pair density wave (PDW) in CsV3Sb5 using scanning tunnelling microscope/spectroscopy and Josephson scanning tunnelling spectroscopy. We find that CsV3Sb5 exhibits a V-shaped pairing gap Delta similar to 0.5 meV and is a strong-coupling superconductor (2 Delta/k(B)T(c) - 5) that coexists with 4a(0) unidirectional and 2a(0) x 2a(0) charge order. Remarkably, we discover a 3Q PDW accompanied by bidirectional 4a(0)/3 spatial modulations of the superconducting gap, coherence peak and gap depth in the tunnelling conductance. We term this novel quantum state a roton PDW associated with an underlying vortex-antivortex lattice that can account for the observed conductance modulations. Probing the electronic states in the vortex halo in an applied magnetic field, in strong field that suppresses superconductivity and in zero field above T-c, reveals that the PDW is a primary state responsible for an emergent pseudogap and intertwined electronic order. Our findings show striking analogies and distinctions to the phenomenology of high-T-c cuprate superconductors, and provide groundwork for understanding the microscopic origin of correlated electronic states and superconductivity in vanadium-based kagome metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2021, "Volume": 599, "Issue": 7884, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": 228, "Article Number": null, "DOI": "10.1038/s41586-021-03983-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03983-5", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714336200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wilkerson, CG; Mansfield, SD; Lu, F; Withers, S; Park, JY; Karlen, SD; Gonzales-Vigil, E; Padmakshan, D; Unda, F; Rencoret, J; Ralph, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wilkerson, C. G.; Mansfield, S. D.; Lu, F.; Withers, S.; Park, J. -Y.; Karlen, S. D.; Gonzales-Vigil, E.; Padmakshan, D.; Unda, F.; Rencoret, J.; Ralph, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolignol Ferulate Transferase Introduces Chemically Labile Linkages into the Lignin Backbone", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Redesigning lignin, the aromatic polymer fortifying plant cell walls, to be more amenable to chemical depolymerization can lower the energy required for industrial processing. We have engineered poplar trees to introduce ester linkages into the lignin polymer backbone by augmenting the monomer pool with monolignol ferulate conjugates. Herein, we describe the isolation of a transferase gene capable of forming these conjugates and its xylem-specific introduction into poplar. Enzyme kinetics, in planta expression, lignin structural analysis, and improved cell wall digestibility after mild alkaline pretreatment demonstrate that these trees produce the monolignol ferulate conjugates, export them to the wall, and use them during lignification. Tailoring plants to use such conjugates during cell wall biosynthesis is a promising way to produce plants that are designed for deconstruction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2014, "Volume": 344, "Issue": 6179, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 90, "End Page": 93, "Article Number": null, "DOI": "10.1126/science.1250161", "DOI Link": "http://dx.doi.org/10.1126/science.1250161", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333746100059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Day, RW; Bediako, DK; Rezaee, M; Parent, LR; Skorupskii, G; Arguilla, MQ; Hendon, CH; Stassen, I; Gianneschi, NC; Kim, P; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Day, Robert W.; Bediako, D. Kwabena; Rezaee, Mehdi; Parent, Lucas R.; Skorupskii, Grigorii; Arguilla, Maxx Q.; Hendon, Christopher H.; Stassen, Ivo; Gianneschi, Nathan C.; Kim, Philip; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single Crystals of Electrically Conductive Two-Dimensional Metal-Organic Frameworks: Structural and Electrical Transport Properties", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystalline, electrically conductive, and intrinsically porous materials are rare. Layered two-dimensional (2D) metal-organic frameworks (MOFs) break this trend. They are porous crystals that exhibit high electrical conductivity and are novel platforms for studying fundamentals of electricity and magnetism in two dimensions. Despite demonstrated applications, electrical transport in these remains poorly understood because of a lack of single crystal studies. Here, studies of single crystals of two 2D MOFs, Ni-3(HITP)(2) and Cu-3(HHTP)(2), uncover critical insights into their structure and transport. Conductivity measurements down to 0.3 K suggest metallicity for mesoscopic single crystals of Ni-3(HITP)(2), which contrasts with apparent activated conductivity for polycrystalline films. Microscopy studies further reveal that these MOFs are not isostructural as previously reported. Notably, single rods exhibit conductivities up to 150 S/cm, which persist even after prolonged exposure to ambient conditions. These single crystal studies confirm that 2D MOFs hold promise as molecularly tunable platforms for fundamental science and applications where porosity and conductivity are critical.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 26", "Publication Year": 2019, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1959, "End Page": 1964, "Article Number": null, "DOI": "10.1021/acscentsci.9b01006", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b01006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000504673000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Song, I; Ahn, J; Han, M; Linares, M; Surin, M; Zhang, HJ; Oh, JH; Lin, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Li; Song, Inho; Ahn, Jaeyong; Han, Myeonggeun; Linares, Mathieu; Surin, Mathieu; Zhang, Hui-Jun; Oh, Joon Hak; Lin, Jianbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "π-Extended perylene diimide double-heterohelicenes as ambipolar organic semiconductors for broadband circularly polarized light detection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite great challenges, the development of new molecular structures with multiple and even conflicting characteristics are eagerly pursued for exploring advanced applications. To develop high-performance chiral organic semiconducting molecules, a distorted -system is required for strong coupling with circularly polarized light (CPL), whereas planar pi -stacking systems are necessary for high charge-carrier mobility. To address this dilemma, in this work, we introduce a skeleton merging approach through distortion of a perylene diimide (PDI) core with four fused heteroaromatics to form an ortho-pi -extended PDI double-[7]heterohelicene. PDI double helicene inherits a high dissymmetry factor from the helicene skeleton, and the extended pi -planar system concurrently maintains a high level of charge transport properties. In addition, ortho-pi -extension of the PDI skeleton brings about near-infrared (NIR) light absorption and ambipolar charge transport abilities, endowing the corresponding organic phototransistors with high photoresponsivity of 450 and 120mAW(-1) in p- and n-type modes respectively, along with a high external quantum efficiency (89%) under NIR light irradiations. Remarkably, these multiple characteristics enable high-performance broadband CPL detections up to NIR spectral region with chiral organic semiconductors. In organic semiconducting molecules materials, distorted pi -systems enable strong coupling with circular polarized light while planar pi -stacking systems are necessary for high charge-carrier mobility. Here, the authors address this dilemma by introducing a skeleton merging approach through distortion of a perylene diimide core with four fused heteroaromatics to form a pi -extended double helicene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1038/s41467-020-20390-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20390-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626604800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Y; Asokan, C; Xu, MJ; Graham, GW; Pan, XQ; Christopher, P; Li, J; Sautet, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yan; Asokan, Chithra; Xu, Mingjie; Graham, George W.; Pan, Xiaoqing; Christopher, Phillip; Li, Jun; Sautet, Philippe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rh single atoms on TiO2 dynamically respond to reaction conditions by adapting their site", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts are widely investigated heterogeneous catalysts; however, the identification of the local environment of single atoms under experimental conditions, as well as operando characterization of their structural changes during catalytic reactions are still challenging. Here, the preferred local coordination of Rh single atoms is investigated on TiO2 during calcination in O-2, reduction in H-2, CO adsorption, and reverse water gas shift (RWGS) reaction conditions. Theoretical and experimental studies clearly demonstrate that Rh single atoms adapt their local coordination and reactivity in response to various redox conditions. Single-atom catalysts hence do not have static local coordinations, but can switch from inactive to active structure under reaction conditions, hence explaining some conflicting literature accounts. The combination of approaches also elucidates the structure of the catalytic active site during reverse water gas shift. This insight on the real nature of the active site is key for the design of high-performance catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4488, "DOI": "10.1038/s41467-019-12461-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12461-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488774200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, CJ; Xin, YC; Chen, XB; Xu, DK; Chu, PK; Liu, CQ; Guan, B; Huang, XX; Liu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Changjian; Xin, Yunchang; Chen, Xiao-Bo; Xu, Daokui; Chu, Paul K.; Liu, Chaoqiang; Guan, Bo; Huang, Xiaoxu; Liu, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evading strength-corrosion tradeoff in Mg alloys via dense ultrafine twins", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional ultrafine-grains can generate high strength in Mg alloys, but significant tradeoff of corrosion resistance due to inclusion of a large number of non-equilibrium grain boundaries. Herein, an ultrafine-grain structure consisting of dense ultrafine twins is prepared, yielding a high strength up to 469MPa and decreasing the corrosion rate by one order of magnitude. Generally, the formation of dense ultrafine twins in Mg alloys is rather difficult, but a carefully designed multi-directional compression treatment effectively stimulates twinning nucleation within twins and refines grain size down to 300nm after 12-passes compressions. Grain-refinement by low-energy twins not only circumvents the detrimental effects of non-equilibrium grain boundaries on corrosion resistance, but also alters both the morphology and distribution of precipitates. Consequently, micro-galvanic corrosion tendency decreases, and severe localized corrosion is suppressed completely. This technique has a high commercial viability as it can be readily implemented in industrial production. Conventional ultrafine grains can generate high-strength Mg alloys, but non-equilibrium grain boundaries deteriorates their corrosion resistance. Here, the authors present ultrafine grained Mg alloys with dense twins that display high strength and reduced corrosion rate by one order of magnitude.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4616, "DOI": "10.1038/s41467-021-24939-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24939-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000681059800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Andres, J; Hersch, RD; Moser, JE; Chauvin, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Andres, Julien; Hersch, Roger D.; Moser, Jacques-Edouard; Chauvin, Anne-Sophie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Anti-Counterfeiting Feature Relying on Invisible Luminescent Full Color Images Printed with Lanthanide-Based Inks", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Europium and terbium trisdipicolinate complexes are inkjet printed onto paper with commercially available desktop inkjet printers. Together with a commercial blue luminescent ink, the red-emitting luminescent ink containing europium and the green-emitting luminescent ink containing terbium are used to reproduce accurate full color images that are invisible under white light and appear under a 254 nm UV light. Such invisible luminescent images are attractive anti-counterfeiting security features. The luminescent prints have a color range (gamut) nearly as wide as the gamut of a standard sRGB display. The gamut of the luminescent prints is determined by relying on a simple model predicting the relative spectral radiant emittances of any printed luminescent color halftone. The model is also used to establish the correspondence between the surface coverages of the printed luminescent inks and the emitted color of these luminescent halftones. The accuracy of the spectral prediction model is very good and can be rationalized by the absence of quenching when the luminescent lanthanide complexes are printed in superposition with the other luminescent materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2014, "Volume": 24, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5029, "End Page": 5036, "Article Number": null, "DOI": "10.1002/adfm.201400298", "DOI Link": "http://dx.doi.org/10.1002/adfm.201400298", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341142100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Schutter, G; Lesage, K; Mechtcherine, V; Nerella, VN; Habert, G; Agusti-Juan, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Schutter, Geert; Lesage, Karel; Mechtcherine, Viktor; Nerella, Venkatesh Naidu; Habert, Guillaume; Agusti-Juan, Isolda", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vision of 3D printing with concrete - Technical, economic and environmental potentials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A vision is presented on 3D printing with concrete, considering technical, economic and environmental aspects. Although several showcases of 3D printed concrete structures are available worldwide, many challenges remain at the technical and processing level. Currently available high-performance cement-based materials cannot be directly 3D printed, because of inadequate rheological and stiffening properties. Active rheology control (ARC) and active stiffening control (ASC) will provide new ways of extending the material palette for 3D printing applications. From an economic point of view, digitally manufactured concrete (DFC) will induce changes in the stakeholders as well as in the cost structure. Although it is currently too ambitious to quantitatively present the cost structure, DFC presents many potential opportunities to increase cost-effectiveness of construction processes. The environmental impact of 3D printing with concrete has to be seen in relation to the shape complexity of the structure. Implementing structural optimization as well as functional hybridization as design strategies allows the use of material only where is structurally or functionally needed. This design optimization increases shape complexity, but also reduces material use in DFC. As a result, it is expected that for structures with the same functionality, DFC will environmentally perform better over the entire service life in comparison with conventionally produced concrete structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 25, "End Page": 36, "Article Number": null, "DOI": "10.1016/j.cemconres.2018.06.001", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2018.06.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444357300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, S; Zhou, HY; Dong, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Shuo; Zhou, Huiyu; Dong, Hongbiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Using deep neural network with small dataset to predict material defects", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep neural network (DNN) exhibits state-of-the-art performance in many fields including microstructure recognition where big dataset is used in training. However, DNN trained by conventional methods with small datasets commonly shows worse performance than traditional machine learning methods, e.g. shallow neural network and support vector machine. This inherent limitation prevented the wide adoption of DNN in material study because collecting and assembling big dataset in material science is a challenge. In this study, we attempted to predict solidification defects by DNN regression with a small dataset that contains 487 data points. It is found that a pre-trained and fine-tuned DNN shows better generalization performance over shallow neural network, support vector machine, and DNN trained by conventional methods. The trained DNN transforms scattered experimental data points into a map of high accuracy in high-dimensional chemistry and processing parameters space. Though DNN with big datasets is the optimal solution, DNN with small datasets and pre-training can be a reasonable choice when big datasets are unavailable in material study. (C) 2018 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2019, "Volume": 162, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 300, "End Page": 310, "Article Number": null, "DOI": "10.1016/j.matdes.2018.11.060", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2018.11.060", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454128400031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QC; Feng, QG; Lei, YP; Tang, SH; Xu, L; Xiong, Y; Fang, GZ; Wang, YC; Yang, PY; Liu, JJ; Liu, W; Xiong, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qichen; Feng, Qingguo; Lei, Yongpeng; Tang, Shuaihao; Xu, Liang; Xiong, Yu; Fang, Guozhao; Wang, Yuchao; Yang, Peiyao; Liu, Jingjing; Liu, Wei; Xiong, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quasi-solid-state Zn-air batteries with an atomically dispersed cobalt electrocatalyst and organohydrogel electrolyte", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quasi-solid-state Zn-air batteries are usually limited to relatively low-rate ability (<10 mA cm(-2)), which is caused in part by sluggish oxygen electrocatalysis and unstable electrochemical interfaces. Here we present a high-rate and robust quasi-solid-state Zn-air battery enabled by atomically dispersed cobalt sites anchored on wrinkled nitrogen doped graphene as the air cathode and a polyacrylamide organohydrogel electrolyte with its hydrogen-bond network modified by the addition of dimethyl sulfoxide. This design enables a cycling current density of 100 mA cm(-2) over 50 h at 25 degrees C. A low-temperature cycling stability of over 300 h (at 0.5 mA cm(-2)) with over 90% capacity retention at -60 degrees C and a broad temperature adaptability (-60 to 60 degrees C) are also demonstrated. Quasi-solid-state Zn-air batteries are limited by sluggish kinetics and low temperature incompatibility. Here, the authors use a single-atom catalyst and an organohydrogel electrolyte to enable a 100 mA cm(-2) cycling current density at 25 degrees C and a -60 to 60 degrees C operational window.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3689, "DOI": "10.1038/s41467-022-31383-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31383-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818961600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nsanzimana, JMV; Peng, YC; Xu, YY; Thia, L; Wang, C; Xia, BY; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nsanzimana, Jean Marie Vianney; Peng, Yuecheng; Xu, Yang Yang; Thia, Larissa; Wang, Cheng; Xia, Bao Yu; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Efficient and Earth-Abundant Oxygen-Evolving Electrocatalyst Based on Amorphous Metal Borides", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cost-effective and efficient oxygen-evolving electrocatalysts are urgently required for energy storage and conversion technologies. In this work, an amorphous trimetallic boride nullocatalyst (Fe-Co-2.3Ni-B) prepared by a simple approach is reported as a highly efficient oxygen evolution reaction electrocatalyst. It exhibits an overpotential () of 274 mV to deliver a geometric current density (j(geo)) of 10 mA cm(-2), a small Tafel slope of 38 mV dec(-1), and excellent long-term durability at a mass loading of 0.3 mg cm(-2). The impressive electrocatalytic performance originates from the unique amorphous multimetal-metalloid complex nullostructure. From application's point of view, this work holds great promise as this process is simple and allows for large-scale production of cheap, yet efficient, material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701475, "DOI": "10.1002/aenm.201701475", "DOI Link": "http://dx.doi.org/10.1002/aenm.201701475", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419327200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HL; Li, YH; Sun, S; Xin, Q; Liu, SH; Mu, XY; Yuan, X; Chen, K; Wang, H; Varga, K; Mi, WB; Yang, J; Zhang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Haile; Li, Yonghui; Sun, Si; Xin, Qi; Liu, Shuhu; Mu, Xiaoyu; Yuan, Xun; Chen, Ke; Wang, Hao; Varga, Kalman; Mi, Wenbo; Yang, Jiang; Zhang, Xiao-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytically potent and selective clusterzymes for modulation of neuroinflammation through single-atom substitutions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emerging artificial enzymes with reprogrammed and augmented catalytic activity and substrate selectivity have long been pursued with sustained efforts. The majority of current candidates have rather poor catalytic activity compared with natural molecules. To tackle this limitation, we design artificial enzymes based on a structurally well-defined Au-25 cluster, namely clusterzymes, which are endowed with intrinsic high catalytic activity and selectivity driven by single-atom substitutions with modulated bond lengths. Au24Cu1 and Au24Cd1 clusterzymes exhibit 137 and 160 times higher antioxidant capacities than natural trolox, respectively. Meanwhile, the clusterzymes demonstrate preferential enzyme-mimicking catalytic activities, with Au-25, Au24Cu1 and Au24Cd1 displaying compelling selectivity in glutathione peroxidase-like (GPx-like), catalase-like (CAT-like) and superoxide dismutase-like (SOD-like) activities, respectively. Au24Cu1 decreases peroxide in injured brain via catalytic reactions, while Au24Cd1 preferentially uses superoxide and nitrogenous signal molecules as substrates, and significantly decreases inflammation factors, indicative of an important role in mitigating neuroinflammation. Artificial enzymes with reprogrammed and augmented catalytic activity and substrate selectivity have emerged to tackle limitations of noble metals or transition metal oxides. Here, the authors report Au-25 clusterzymes which are endowed with high catalytic activity and selectivity in a range of enzyme-mimicking reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114, "DOI": "10.1038/s41467-020-20275-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20275-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684636800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sa, BS; Li, YL; Qi, JS; Ahuja, R; Sun, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sa, Baisheng; Li, Yan-Ling; Qi, Jingshan; Ahuja, Rajeev; Sun, Zhimei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain Engineering for Phosphorene: The Potential Application as a Photocatalyst", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2014, "Volume": 118, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26560, "End Page": 26568, "Article Number": null, "DOI": "10.1021/jp508618t", "DOI Link": "http://dx.doi.org/10.1021/jp508618t", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345474000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JB; Munir, R; Fan, YY; Niu, TQ; Liu, YC; Zhong, YF; Yang, Z; Tian, YS; Liu, B; Sun, J; Smilgies, DM; Thoroddsen, S; Amassian, A; Zhao, K; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianbo; Munir, Rahim; Fan, Yuanyuan; Niu, Tianqi; Liu, Yucheng; Zhong, Yufei; Yang, Zhou; Tian, Yuansi; Liu, Bo; Sun, Jie; Smilgies, Detlef-M.; Thoroddsen, Sigurdur; Amassian, Aram; Zhao, Kui; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Transition Control for High-Performance Blade-Coated Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we have identified that the key issue for rational transitioning from spin-coating to blade-coating processes of perovskite films arises from whether intermediate phases participate in the phase transition. In situ characterizations were carried out to provide a comprehensive picture of structural evolution and crystal growth mechanisms. These findings present opportunities for designing an effective process for blade-coating perovskite film: a large-grained dense perovskite film with high crystal quality and photophysical properties can be obtained only via direct crystallization for both spin-coating and blade-coating processes. As a result, the blade-coated MAPbI(3) films deliver excellent charge-collection efficiency at both short circuit and open circuit, and photovoltaic properties with efficiencies of 18.74% (0.09 cm(2)) and 17.06% (1 cm(2)) in planar solar cells. The significant advances in understanding how the phase transition links spin-coating and blade-coating processes should provide a path toward high-performance printed perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1313, "End Page": 1330, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439698900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, QY; Jiang, B; Hu, J; Lao, CY; Gao, YZ; Li, PH; Liu, ZW; Suo, GQ; He, DL; Wang, W; Yin, GP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Qiyao; Jiang, Bo; Hu, Jun; Lao, Cheng-Yen; Gao, Yunzhi; Li, Peihao; Liu, Zhiwei; Suo, Guoquan; He, Donglin; Wang, Wei (Alex); Yin, Geping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic Octahedral CoSe2 Threaded by N-Doped Carbon nullotubes: A Flexible Framework for High-Performance Potassium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the abundant and low-cost K resources, the exploration of suitable materials for potassium-ion batteries (KIBs) is advancing as a promising alternative to lithium-ion batteries. However, the large-sized and sluggish-kinetic K ions cause poor battery behavior. This work reports a metallic octahedral CoSe2 threaded by N-doped carbon nullotubes as a flexible framework for a high-performance KIBs anode. The metallic property of CoSe2 together with the highly conductive N-doped carbon nullotubes greatly accelerates the electron transfer and improves the rate performance. The carbon nullotube framework serves as a backbone to inhibit the agglomeration, anchor the active materials, and stabilize the integral structure. Every octahedral CoSe2 particle arranges along the carbon nullotubes in sequence, and the zigzag void space can accommodate the volume expansion during cycling, therefore boosting the cycling stability. Density functional theory is also employed to study the K-ion intercalation/deintercalation process. This unique structure delivers a high capacity (253 mAh g(-1) at 0.2 A g(-1) over 100 cycles) and enhanced rate performance (173 mAh g(-1) at 2.0 A g(-1) over 600 cycles) as an advanced anode material for KIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800782, "DOI": "10.1002/advs.201800782", "DOI Link": "http://dx.doi.org/10.1002/advs.201800782", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447632000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, BQ; Feng, ZL; Xu, QN; Gao, X; Ma, JZ; Kong, LY; Richard, P; Huang, YB; Strocov, VN; Fang, C; Weng, HM; Shi, YG; Qian, T; Ding, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, B. Q.; Feng, Z-L.; Xu, Q. -N.; Gao, X.; Ma, J. -Z.; Kong, L. -Y.; Richard, P.; Huang, Y. -B.; Strocov, V. N.; Fang, C.; Weng, H. -M.; Shi, Y. -G.; Qian, T.; Ding, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of three-component fermions in the topological semimetal molybdenum phosphide", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In quantum field theory, Lorentz invariance leads to three types of fermion-Dirac, Weyl and Majorana. Although the existence of Weyl and Majorana fermions as elementary particles in high-energy physics is debated, all three types of fermion have been proposed to exist as low-energy, long-wavelength quasiparticle excitations in condensed-matter systems(1-12). The existence of Dirac and Weyl fermions in condensed-matter systems has been confirmed experimentally(13-18), and that of Majorana fermions is supported by various experiments(19,20). However, in condensed-matter systems, fermions in crystals are constrained by the symmetries of the 230 crystal space groups rather than by Lorentz invariance, giving rise to the possibility of finding other types of fermionic excitation that have no counterparts in high-energy physics(21-29). Here we use angle-resolved photoemission spectroscopy to demonstrate the existence of a triply degenerate point in the electronic structure of crystalline molybdenum phosphide. Quasiparticle excitations near a triply degenerate point are three-component fermions, beyond the conventional Dirac-Weyl-Majorana classification, which attributes Dirac and Weyl fermions to four-and two-fold degenerate points, respectively. We also observe pairs of Weyl points in the bulk electronic structure of the crystal that coexist with the three-component fermions. This material thus represents a platform for studying the interplay between different types of fermions. Our experimental discovery opens up a way of exploring the new physics of unconventional fermions in condensed-matter systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2017, "Volume": 546, "Issue": 7660, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 627, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature22390", "DOI Link": "http://dx.doi.org/10.1038/nature22390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404332000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tasan, CC; Hoefnagels, JPM; Diehl, M; Yan, D; Roters, F; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tasan, C. C.; Hoefnagels, J. P. M.; Diehl, M.; Yan, D.; Roters, F.; Raabe, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain localization and damage in dual phase steels investigated by coupled in-situ deformation experiments and crystal plasticity simulations", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferritic-martensitic dual phase (DP) steels deform spatially in a highly heterogeneous manner, i.e. with strong strain and stress partitioning at the micro-scale. Such heterogeneity in local strain evolution leads in turn to a spatially heterogeneous damage distribution, and thus, plays an important role in the process of damage inheritance and fracture. To understand and improve DP steels, it is important to identify connections between the observed strain and damage heterogeneity and the underlying microstructural parameters, e.g. ferrite grain size, martensite distribution, martensite fraction, etc. In this work we pursue this aim by conducting in-situ deformation experiments on two different DP steel grades, employing two different microscopic-digital image correlation (mu DIC) techniques to achieve microstructural strain maps of representative statistics and high-resolution. The resulting local strain maps are analyzed in connection to the observed damage incidents (identified by image post-processing) and to local stress maps (obtained from crystal plasticity (CP) simulations of the same microstructural area). The results reveal that plasticity is typically initiated within hot zones with larger ferritic grains and lower local martensite fraction. With increasing global deformation, damage incidents are most often observed in the boundary of such highly plastified zones. High-resolution mu DIC and the corresponding CP simulations reveal the importance of martensite dispersion: zones with bulky martensite are more susceptible to macroscopic localization before the full strain hardening capacity of the material is consumed. Overall, the presented joint analysis establishes an integrated computational materials engineering (ICME) approach for designing advanced DP steels. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 63, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 198, "End Page": 210, "Article Number": null, "DOI": "10.1016/j.ijplas.2014.06.004", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2014.06.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342873100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LC; Meira, DM; Arenal, R; Concepcion, P; Puga, AV; Corma, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Lichen; Meira, Debora M.; Arenal, Raul; Concepcion, Patricia; Puga, Alberto V.; Corma, Avelino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of the Evolution of Heterogeneous Single Metal Atoms and nulloclusters under Reaction Conditions: Which Are the Working Catalytic Sites?", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identification of active sites in heterogeneous metal catalysts is critical for understanding the reaction mechanism at the molecular level and for designing more efficient catalysts. Because of their structural flexibility, subnullometric metal catalysts, including single atoms and clusters with a few atoms, can exhibit dynamic structural evolution when interacting with substrate molecules, making it difficult to determine the catalytically active sites. In this work, Pt catalysts containing selected types of Pt entities (from single atoms to clusters and nulloparticles) have been prepared, and their evolution has been followed, while they were reacting in a variety of heterogeneous catalytic reactions, including selective hydrogenation reactions, CO oxidation, dehydrogenation of propane, and photocatalytic H-2 evolution reaction. By in situ X-ray absorption spectroscopy, in situ IR spectroscopy, and high-resolution electron microscopy techniques, we will show that some characterization techniques carried out in an inadequate way can introduce confusion on the interpretation of coordination environment of highly dispersed Pt species. Finally, the combination of catalytic reactivity and in situ characterization techniques shows that, depending on the catalyst-reactant interaction and metal-support interaction, singly dispersed metal atoms can rapidly evolve into metal clusters or nulloparticles, being the working active sites for those abovementioned heterogeneous reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10626, "End Page": 10639, "Article Number": null, "DOI": "10.1021/acscatal.9b04214", "DOI Link": "http://dx.doi.org/10.1021/acscatal.9b04214", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502169900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, JS; Pan, YH; Yang, F; Wang, C; Chai, Y; Ji, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Jingsi; Pan, Yuhao; Yang, Feng; Wang, Cong; Chai, Yang; Ji, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Few-layer Tellurium: one-dimensional-like layered elementary semiconductor with striking physical properties", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer Tellurium, an elementary semiconductor, succeeds most of striking physical properties that black phosphorus (BP) offers and could be feasibly synthesized by simple solution-based methods. It is comprised of non-covalently bound parallel Te chains, among which covalent-like feature appears. This feature is, we believe, another demonstration of the previously found covalent-like quasi-bonding (CLQB) where wavefunction hybridization does occur. The strength of this inter-chain CLQB is comparable with that of intra-chain covalent bonding, leading to closed stability of several Te allotropes. It also introduces a tunable bandgap varying from nearly direct 0.31 eV (bulk) to indirect 1.17 eV (2L) and four (two) complex, highly anisotropic and layer-dependent hole (electron) pockets in the first Brillouin zone. It also exhibits an extraordinarily high hole mobility (similar to 10(5) cm(2)/Vs) and strong optical absorption along the non-covalently bound direction, nearly isotropic and layer-dependent optical properties, large ideal strength over 20%, better environmental stability than BP and unusual crossover of force constants for interlayer shear and breathing modes. All these results manifest that the few-layer Te is an extraordinary-high-mobility, high optical absorption, intrinsic-anisotropy, low-cost-fabrication, tunable bandgap, better environmental stability and nearly direct bandgap semiconductor. This one-dimen sion-like few-layer Te, together with other geometrically similar layered materials, may promote the emergence of a new family of layered materials. (C) 2018 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2018, "Volume": 63, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 159, "End Page": 168, "Article Number": null, "DOI": "10.1016/j.scib.2018.01.010", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2018.01.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425946400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, LC; Bell, AT; Weber, AZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling gas-diffusion electrodes for CO2 reduction", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 reduction conducted in electrochemical cells with planar electrodes immersed in an aqueous electrolyte is severely limited by mass transport across the hydrodynamic boundary layer. This limitation can be minimized by use of vapor-fed, gas-diffusion electrodes (GDEs), enabling current densities that are almost two orders of magnitude greater at the same applied cathode overpotential than what is achievable with planar electrodes in an aqueous electrolyte. The addition of porous cathode layers, however, introduces a number of parameters that need to be tuned in order to optimize the performance of the GDE cell. In this work, we develop a multiphysics model for gas diffusion electrodes for CO2 reduction and used it to investigate the interplay between species transport and electrochemical reaction kinetics. The model demonstrates how the local environment near the catalyst layer, which is a function of the operating conditions, affects cell performance. We also examine the effects of catalyst layer hydrophobicity, loading, porosity, and electrolyte flowrate to help guide experimental design of vapor-fed CO2 reduction cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2018, "Volume": 20, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16973, "End Page": 16984, "Article Number": null, "DOI": "10.1039/c8cp01319e", "DOI Link": "http://dx.doi.org/10.1039/c8cp01319e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436571800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, Z; Li, D; Ushakova, EV; Maslov, VG; Zhou, D; Jing, PT; Shen, DZ; Qu, SN; Rogach, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Zhen; Li, Di; Ushakova, Elena V.; Maslov, Vladimir G.; Zhou, Ding; Jing, Pengtao; Shen, Dezhen; Qu, Songnull; Rogach, Andrey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multilevel Data Encryption Using Thermal-Treatment Controlled Room Temperature Phosphorescence of Carbon Dot/Polyvinylalcohol Composites", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal-treatment controlled room temperature phosphorescence is realized by embedding either originally synthesized carbon dots (CDs) or 200 degrees C thermal-treated CDs into a polyvinylalcohol (PVA) matrix through post-synthetic thermal annealing at 200 or 150 degrees C. The thermal-treatment controlled phosphorescence is attributed to the transfer of photoexcitation from the excited singlet state to the triplet state through intersystem crossing, followed by radiative transition to the ground state, which is due to decrease of quenchers (oxygen) in the CDs and suppression of the vibrational dissipations through the chemical bonding of CDs in the PVA matrix. Multilevel fluorescence/phosphorescence data encryption is demonstrated based on the thermal-treatment controlled phosphorescence from CD@PVA composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800795, "DOI": "10.1002/advs.201800795", "DOI Link": "http://dx.doi.org/10.1002/advs.201800795", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444940600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, KH; Lee, AS; Atanasov, V; Kerres, J; Park, EJ; Adhikari, S; Maurya, S; Manriquez, LD; Jung, J; Fujimoto, C; Matanovic, I; Jankovic, J; Hu, ZD; Jia, HF; Kim, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Katie H.; Lee, Albert S.; Atanasov, Vladimir; Kerres, Jochen; Park, Eun Joo; Adhikari, Santosh; Maurya, Sandip; Manriquez, Luis Delfin; Jung, Jiyoon; Fujimoto, Cy; Matanovic, Ivana; Jankovic, Jasna; Hu, Zhendong; Jia, Hongfei; Kim, Yu Seung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protonated phosphonic acid electrodes for high power heavy-duty vehicle fuel cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-temperature polymer electrolyte membrane fuel cells are promising for heavy-duty vehicle applications, but strides in performance are needed to improve their commercial viability. Here it is demonstrated that protonating phosphonic acid electrodes greatly enhances power density and durability. State-of-the-art automotive fuel cells that operate at about 80 degrees C require large radiators and air intakes to avoid overheating. High-temperature fuel cells that operate above 100 degrees C under anhydrous conditions provide an ideal solution for heat rejection in heavy-duty vehicle applications. Here we report protonated phosphonic acid electrodes that remarkably improve the performance of high-temperature polymer electrolyte membrane fuel cells. The protonated phosphonic acids comprise tetrafluorostyrene-phosphonic acid and perfluorosulfonic acid polymers, where a perfluorosulfonic acid proton is transferred to the phosphonic acid to enhance the anhydrous proton conduction of fuel cell electrodes. By using this material in fuel cell electrodes, we obtained a fuel cell exhibiting a rated power density of 780 mW cm(-)(2) at 160 degrees C, with minimal degradation during 2,500 h of operation and 700 thermal cycles from 40 to 160 degrees C under load.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 248, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-021-00971-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00971-x", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750299200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uchida, K; Adachi, H; Kikkawa, T; Kirihara, A; Ishida, M; Yorozu, S; Maekawa, S; Saitoh, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uchida, Ken-ichi; Adachi, Hiroto; Kikkawa, Takashi; Kirihara, Akihiro; Ishida, Masahiko; Yorozu, Shinichi; Maekawa, Sadamichi; Saitoh, Eiji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermoelectric Generation Based on Spin Seebeck Effects", "Source Title": "PROCEEDINGS OF THE IEEE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin Seebeck effect (SSE) refers to the generation of a spin current as a result of a temperature gradient in magnetic materials including insulators. The SSE is applicable to thermoelectric generation because the thermally generated spin current can be converted into a charge current via spin-orbit interaction in conductive materials adjacent to the magnets. The insulator-based SSE device exhibits unconventional characteristics potentially useful for thermoelectric applications, such as simple structure, device-design flexibility, and convenient scaling capability. In this article, we review recent studies on the SSE from the viewpoint of thermoelectric applications. Firstly, we introduce the thermoelectric generation process and measurement configuration of the SSE, followed by showing fundamental characteristics of the SSE device. Secondly, a theory of the thermoelectric conversion efficiency of the SSE device is presented, which clarifies the difference between the SSE and conventional thermoelectric effects and the efficiency limit of the SSE device. Finally, we show preliminary demonstrations of the SSE in various device structures for future thermoelectric applications and discuss prospects of the SSE-based thermoelectric technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 104, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1946, "End Page": 1973, "Article Number": null, "DOI": "10.1109/JPROC.2016.2535167", "DOI Link": "http://dx.doi.org/10.1109/JPROC.2016.2535167", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385371800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gent, WE; Lim, K; Liang, YF; Li, QH; Barnes, T; Ahn, SJ; Stone, KH; McIntire, M; Hong, JY; Song, JH; Li, YY; Mehta, A; Ermon, S; Tyliszczak, T; Kilcoyne, D; Vine, D; Park, JH; Doo, SK; Toney, MF; Yang, WL; Prendergast, D; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gent, William E.; Lim, Kipil; Liang, Yufeng; Li, Qinghao; Barnes, Taylor; Ahn, Sung-Jin; Stone, Kevin H.; McIntire, Mitchell; Hong, Jihyun; Song, Jay Hyok; Li, Yiyang; Mehta, Apurva; Ermon, Stefano; Tyliszczak, Tolek; Kilcoyne, David; Vine, David; Park, Jin-Hwan; Doo, Seok-Kwang; Toney, Michael F.; Yang, Wanli; Prendergast, David; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-rich layered transition metal oxide positive electrodes offer access to anion redox at high potentials, thereby promising high energy densities for lithium-ion batteries. However, anion redox is also associated with several unfavorable electrochemical properties, such as open-circuit voltage hysteresis. Here we reveal that in Li1.17-xNi0.21Co0.08Mn0.54O2, these properties arise from a strong coupling between anion redox and cation migration. We combine various X-ray spectroscopic, microscopic, and structural probes to show that partially reversible transition metal migration decreases the potential of the bulk oxygen redox couple by > 1 V, leading to a reordering in the anionic and cationic redox potentials during cycling. First principles calculations show that this is due to the drastic change in the local oxygen coordination environments associated with the transition metal migration. We propose that this mechanism is involved in stabilizing the oxygen redox couple, which we observe spectroscopically to persist for 500 charge/discharge cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 569, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2091, "DOI": "10.1038/s41467-017-02041-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02041-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417702300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mitra, S; Chakraborty, AJ; Tareq, A; Bin Emran, T; Nainu, F; Khusro, A; Idris, AM; Khandaker, MU; Osman, H; Alhumaydhi, FA; Simal-Gandara, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mitra, Saikat; Chakraborty, Arka Jyoti; Tareq, Abu Montakim; Bin Emran, Talha; Nainu, Firzan; Khusro, Ameer; Idris, Abubakr M.; Khandaker, Mayeen Uddin; Osman, Hamid; Alhumaydhi, Fahad A.; Simal-Gandara, Jesus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of heavy metals on the environment and human health: Novel therapeutic insights to counter the toxicity", "Source Title": "JOURNAL OF KING SAUD UNIVERSITY SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heavy metals are well-known environmental pollutants owing to their toxicity, longevity in the atmosphere, and ability to accumulate in the human body via bioaccumulation. The pollution of terrestrial and aquatic ecosystems with toxic heavy metals is a major environmental concern that has consequences for public health. Most heavy metals occur naturally, but a few are derived from anthropogenic sources. Heavy metals are characterized by their high atomic mass and toxicity to living organisms. Most heavy metals cause environmental and atmospheric pollution, and may be lethal to humans. Heavy metals can become strongly toxic by mixing with different environmental elements, such as water, soil, and air, and humans and other living organisms can be exposed to them through the food chain. Plenty of experimental studies were performed to appraise the promising treatment options from natural products. Additionally, nullotechnology based treatment options are being constantly developed. As an emerging field, nullotechnology is making substantial advances in the analysis and removal of heavy metals from complicated matrices. Removal of heavy metal has been accomplished by the use of a variety of nullomaterials, including graphene and its derivatives, magnetic nulloparticles, metal oxide nulloparticles, and carbon nullotubes, to name a few. Using nullotechnology for heavy metal analysis and removal from food and water resources provides many benefits over traditional methods. These advantages include a broad linear range, low detection and quantification limits, a high sensitivity, and high selectivity. Therefore this review aimed to explore the environmental consequences of the heavy metals, toxicity to the human health, as well as novel therapeutics development from the natural resources. Additionally, nullotechnological and nullomedicinal applications to treat heavy metal toxicity are also highlighted in this review. (c) 2022 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 814, "Times Cited, All Databases": 853, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101865, "DOI": "10.1016/j.jksus.2022.101865", "DOI Link": "http://dx.doi.org/10.1016/j.jksus.2022.101865", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758190800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, JW; Ryu, H; Bai, WB; Xie, ZQ; Vazquez-Guardado, A; nulldoliya, K; Avila, R; Lee, G; Song, Z; Kim, J; Lee, MK; Liu, YG; Kim, M; Wang, HF; Wu, YX; Yoon, HJ; Kwak, SS; Shin, J; Kwon, K; Lu, W; Chen, XX; Huang, YG; Ameer, GA; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Joseph W.; Ryu, Hanjun; Bai, Wubin; Xie, Zhaoqian; Vazquez-Guardado, Abraham; nulldoliya, Khizar; Avila, Raudel; Lee, Geumbee; Song, Zhen; Kim, Jihye; Lee, Min-Kyu; Liu, Yugang; Kim, Mirae; Wang, Huifeng; Wu, Yixin; Yoon, Hong-Joon; Kwak, Sung Soo; Shin, Jaeho; Kwon, Kyeongha; Lu, Wei; Chen, Xuexian; Huang, Yonggang; Ameer, Guillermo A.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioresorbable, wireless, and battery-free system for electrotherapy and impedance sensing at wound sites", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chronic wounds, particularly those associated with diabetes mellitus, represent a growing threat to public health, with additional notable economic impacts. Inflammation associated with these wounds leads to abnormalities in endogenous electrical signals that impede the migration of keratinocytes needed to support the healing process. This observation motivates the treatment of chronic wounds with electrical stimulation therapy, but practical engineering challenges, difficulties in removing stimulation hardware from the wound site, and absence of means to monitor the healing process create barriers to widespread clinical use. Here, we demonstrate a miniaturized wireless, battery-free bioresorbable electrotherapy system that overcomes these challenges. Studies based on a splinted diabetic mouse wound model confirm the efficacy for accelerated wound closure by guiding epithelial migration, modulating inflammation, and promoting vasculogenesis. Changes in the impedance provide means for tracking the healing process. The results demonstrate a simple and effective platform for wound site electrotherapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2023, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eade4687", "DOI": "10.1126/sciadv.ade4687", "DOI Link": "http://dx.doi.org/10.1126/sciadv.ade4687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000949019100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YH; Xu, S; Chen, SS; Xiao, X; Zhao, JJ; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yehao; Xu, Shuang; Chen, Shangshang; Xiao, Xun; Zhao, Jingjing; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect compensation in formamidinium-caesium perovskites for highly efficient solar mini-modules with improved photostability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formamidinium-caesium mixed-cation perovskites have shown better thermal stability than their methylammonium-containing counterparts but they suffer from photoinstability induced by iodide migration and phase segregation. Here we improve their photostability by adding slightly excessive AX (at a molar percentage of 0.25% to Pb2+ ions), where A is formamidinium or caesium and X is iodine. The excessive AX does not improve the initial solar cell efficiency. It compensates iodide vacancies and suppresses ion migration and defects generation during long-term illumination by around tenfold compared with AX-deficient devices. Consequently, generation of hole traps and phase segregation is impeded, with the former limiting solar cell efficiency after degradation. The perovskite mini-modules reached a certified stabilized efficiency of 18.6% with an aperture area of similar to 30 cm(2), corresponding to an active area efficiency of 20.2%. The mini-module maintains 93.6% of the initial efficiency after continuous operation under 1 sun illumination for >1,000 h at 50 +/- 5 degrees C in air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 633, "End Page": 641, "Article Number": null, "DOI": "10.1038/s41560-021-00831-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00831-8", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652456000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CW; Song, ZN; Chen, C; Xiao, CX; Subedi, B; Harvey, SP; Shrestha, N; Subedi, KK; Chen, L; Liu, DC; Li, Y; Kim, YW; Jiang, CS; Heben, MJ; Zhao, DW; Ellingson, RJ; Podraza, NJ; Al-Jassim, M; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chongwen; Song, Zhaoning; Chen, Cong; Xiao, Chuanxiao; Subedi, Biwas; Harvey, Steven P.; Shrestha, Niraj; Subedi, Kamala Khanal; Chen, Lei; Liu, Dachang; Li, You; Kim, Yong-Wah; Jiang, Chun-sheng; Heben, Michael J.; Zhao, Dewei; Ellingson, Randy J.; Podraza, Nikolas J.; Al-Jassim, Mowafak; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-bandgap mixed tin-lead iodide perovskites with reduced methylammonium for simultaneous enhancement of solar cell efficiency and stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance perovskite/perovskite tandem solar cells require high-efficiency and stable low-bandgap perovskite subcells. State-of-the-art low-bandgap mixed tin-lead iodide perovskite solar cells exhibit either a high power-conversion efficiency or improved stability, but not both. Here we report a two-step bilayer interdiffusion growth process to simultaneously meet both requirements for formamidinium-based low-bandgap mixed tin-lead iodide perovskite solar cells. The bilayer interdiffusion growth process allows for the formation of high-quality and large-grained perovskite films with only 10 mol% volatile methylammonium. Additionally, one-dimensional pyrrolidinium perovskite was applied to passivate the perovskite film and improve the junction quality, which resulted in a carrier lifetime of 1.1 mu s and an open circuit voltage of 0.865 V for our perovskite film and device with a bandgap of 1.28 eV. Our strategies enabled a power-conversion efficiency of 20.4% for low-bandgap perovskite solar cells under AM 1.5G illumination. More importantly, an encapsulated device can retain 92% of its initial efficiency after 450 h of continuous 1 sun illumination. Low-bandgap tin-lead perovskites are key to all-perovskite tandem solar cells but simultaneous improvement in efficiency and stability has proven challenging. Now, Li et al. fabricate tin-lead perovskite cells with reduced methylammonium content that are 20.4% efficient and stable under illumination for 450 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 768, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-020-00692-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-00692-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000578091500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YM; Wang, JA; Koketsu, T; Kroschel, M; Chen, JM; Hsu, SY; Henkelman, G; Hu, ZW; Strasser, P; Ma, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yiming; Wang, Jiaao; Koketsu, Toshinari; Kroschel, Matthias; Chen, Jin-Ming; Hsu, Su-Yang; Henkelman, Graeme; Hu, Zhiwei; Strasser, Peter; Ma, Jiwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iridium single atoms incorporated in Co3O4 efficiently catalyze the oxygen evolution in acidic conditions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing active and stable electrocatalysts with economic efficiency for acidic oxygen evolution reaction is essential for developing proton exchange membrane water electrolyzers. Herein, we report on a cobalt oxide incorporated with iridium single atoms (Ir-Co3O4), prepared by a mechanochemical approach. Operando X-ray absorption spectroscopy reveals that Ir atoms are partially oxidized to active Ir>4+ during the reaction, meanwhile Ir and Co atoms with their bridged electrophilic O ligands acting as active sites, are jointly responsible for the enhanced performance. Theoretical calculations further disclose the isolated Ir atoms can effectively boost the electronic conductivity and optimize the energy barrier. As a result, Ir-Co3O4 exhibits significantly higher mass activity and turnover frequency than those of benchmark IrO2 in acidic conditions. Moreover, the catalyst preparation can be easily scaled up to gram-level per batch. The present approach highlights the concept of constructing single noble metal atoms incorporated cost-effective metal oxides catalysts for practical applications. Designing active, stable and cost-effective catalysts for the acidic oxygen evolution reaction remains a challenge. Here, the authors report iridium single atoms incorporated cobalt oxides, showing distinctly enhanced performance in the acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7754, "DOI": "10.1038/s41467-022-35426-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35426-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028135800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, YY; Zhou, XE; Gao, X; He, YZ; Liu, W; Ishchenko, A; Barty, A; Sathish, D; Yefanov, O; Han, GW; Xu, QP; de Waal, PW; Ke, JY; Tan, MHE; Zhang, CH; Moeller, A; West, GM; Pascal, BD; Van Eps, N; Caro, LN; Vishnivetskiy, SA; Lee, RJ; Suino-Powell, KM; Gu, X; Pal, K; Ma, JM; Zhi, XY; Boutet, S; Williams, GJ; Messerschmidt, M; Gati, C; Zatsepin, NA; Wang, DJ; James, D; Basu, S; Roy-Chowdhury, S; Conrad, CE; Coe, J; Liu, HG; Lisova, S; Kupitz, C; Grotjohann, I; Fromme, R; Jiang, Y; Tan, MJ; Yang, HY; Li, J; Wang, MT; Zheng, Z; Li, DF; Howe, N; Zhao, YM; Standfuss, J; Diederichs, K; Dong, YH; Potter, CS; Carragher, B; Caffrey, M; Jiang, HL; Chapman, HN; Spence, JCH; Fromme, P; Weierstall, U; Ernst, OP; Katritch, V; Gurevich, VV; Griffin, PR; Hubbell, WL; Stevens, RC; Cherezov, V; Melcher, K; Xu, HE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Yanyong; Zhou, X. Edward; Gao, Xiang; He, Yuanzheng; Liu, Wei; Ishchenko, Andrii; Barty, Anton; Sathish, D.; Yefanov, Oleksandr; Han, Gye Won; Xu, Qingping; de Waal, Parker W.; Ke, Jiyuan; Tan, M. H. Eileen; Zhang, Chenghai; Moeller, Arne; West, Graham M.; Pascal, Bruce D.; Van Eps, Ned; Caro, Lydia N.; Vishnivetskiy, Sergey A.; Lee, Regina J.; Suino-Powell, Kelly M.; Gu, Xin; Pal, Kuntal; Ma, Jinming; Zhi, Xiaoyong; Boutet, Sebastien; Williams, Garth J.; Messerschmidt, Marc; Gati, Cornelius; Zatsepin, Nadia A.; Wang, Dingjie; James, Daniel; Basu, Shibom; Roy-Chowdhury, Shatabdi; Conrad, Chelsie E.; Coe, Jesse; Liu, Haiguang; Lisova, Stella; Kupitz, Christopher; Grotjohann, Ingo; Fromme, Raimund; Jiang, Yi; Tan, Minjia; Yang, Huaiyu; Li, Jun; Wang, Meitian; Zheng, Zhong; Li, Dianfan; Howe, Nicole; Zhao, Yingming; Standfuss, Joerg; Diederichs, Kay; Dong, Yuhui; Potter, Clinton S.; Carragher, Bridget; Caffrey, Martin; Jiang, Hualiang; Chapman, Henry N.; Spence, John C. H.; Fromme, Petra; Weierstall, Uwe; Ernst, Oliver P.; Katritch, Vsevolod; Gurevich, Vsevolod V.; Griffin, Patrick R.; Hubbell, Wayne L.; Stevens, Raymond C.; Cherezov, Vadim; Melcher, Karsten; Xu, H. Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal structure of rhodopsin bound to arrestin by femtosecond X-ray laser", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "G-protein-coupled receptors (GPCRs) signal primarily through G proteins or arrestins. Arrestin binding to GPCRs blocks G protein interaction and redirects signalling to numerous G-protein-independent pathways. Here we report the crystal structure of a constitutively active form of human rhodopsin bound to a pre-activated form of the mouse visual arrestin, determined by serial femtosecond X-ray laser crystallography. Together with extensive biochemical and mutagenesis data, the structure reveals an overall architecture of the rhodopsin-arrestin assembly in which rhodopsin uses distinct structural elements, including transmembrane helix 7 and helix 8, to recruit arrestin. Correspondingly, arrestin adopts the pre-activated conformation, with a similar to 20 degrees rotation between the amino and carboxy domains, which opens up a cleft in arrestin to accommodate a short helix formed by the second intracellular loop of rhodopsin. This structure provides a basis for understanding GPCR-mediated arrestin-biased signalling and demonstrates the power of X-ray lasers for advancing the frontiers of structural biology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 616, "Times Cited, All Databases": 691, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2015, "Volume": 523, "Issue": 7562, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature14656", "DOI Link": "http://dx.doi.org/10.1038/nature14656", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358655200038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tai, ZX; Zhang, Q; Liu, YJ; Liu, HK; Dou, SX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tai, Zhixin; Zhang, Qing; Liu, Yajie; Liu, Huakun; Dou, Shixue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activated carbon from the graphite with increased rate capability for the potassium ion battery", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Activated carbon has been synthesized by a high-temperature annealing route using graphite as carbon source and potassium hydroxide as the etching agent. Many nullosized carbon sheets formed on the particles could be of benefit for rapid intercalation/de-intercalation of potassium ions. Moreover, the d-spacing in the (100) crystal planes of the as-prepared active carbon is enlarged to 0.335 nm, even some formed carbon nullosheets can reach 0.358 nm, and the diffusion coefficient of K ion is also improved by 7 times as well. The as-prepared activated carbon electrode can deliver a high reversible capacity of 100 mAh g(-1) after 100 cycles (at a high current density of 0.2 A g(-1)), and exhibits increased rate performance. The results demonstrate that the as-prepared active carbon is a promising anode material for the potassium ion battery, with high capacity, excellent rate performance, and great cycling stability. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 123, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 54, "End Page": 61, "Article Number": null, "DOI": "10.1016/j.carbon.2017.07.041", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2017.07.041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410369600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, Y; Celio, H; Li, JY; Dolocan, A; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Ya; Celio, Hugo; Li, Jianyu; Dolocan, Andrei; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modified High-Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-Ni layered oxides are promising next-generation cathodes for lithium-ion batteries owing to their high capacity and lower cost. However, as the Ni content increases over 70%, they have a high dynamic affinity towards moisture and CO, in ambient air, primarily reacting to form LiOH, Li2CO3, and LiHCO3 on the surface, which is commonly termed residual lithium. Air exposure occurs after synthesis as it is common practice to handle and store them under ambient conditions. The air exposure leads 10 significant performance losses, and hampers the electrode fabrication, impeding their practical viability. Herein, we show that substituting a small amount of Al for Ni in the crystal lattice notably improves the chemical stability against air by limiting the formation of LiOH, Li2CO3, LiHCO3, and NiO in the near-surface region. The Al doped high-Ni oxides display a high capacity retention with excellent rate capability and cycling stability after being exposed to air for 30 days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2018, "Volume": 57, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6480, "End Page": 6485, "Article Number": null, "DOI": "10.1002/anie.201801533", "DOI Link": "http://dx.doi.org/10.1002/anie.201801533", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434041700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XF; Tian, YH; Luo, J; Jin, B; Wu, ZJ; Ning, XM; Zhan, L; Fan, XL; Zhou, T; Zhang, SQ; Zhou, XS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xunfu; Tian, Yuhui; Luo, Jin; Jin, Bei; Wu, Zhijun; Ning, Xiaomei; Zhan, Liang; Fan, Xuliang; Zhou, Tao; Zhang, Shanqing; Zhou, Xiaosong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoC Quantum Dots@N-Doped-Carbon for Low-Cost and Efficient Hydrogen Evolution Reaction: From Electrocatalysis to Photocatalysis", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable and highly efficient non-noble metal catalysts could facilitate the realization of closed-loop and carbon-neutral hydrogen (H-2) economy via low-cost electrocatalytic (EC) or photocatalytic (PC) H-2 evolution reaction (HER) from water. Herein, molybdenum carbide (MoC) quantum dots onto N-doped porous carbon are in situ synthesized and immobilized, resulting in a bifunctional catalyst MoC@NC. Density functional theory calculation suggests that the targeted catalyst has a suitable Gibbs free-energy (Delta G(H*)) for the adsorption of atomic hydrogen, which is beneficial to both EC and PC HERs. For EC HER, the as-prepared MoC@NC catalyst delivers a low overpotential of 160 mV at -10 mA cm(-2) and a remarkable H-2 evolution rate in alkaline electrolytes. For PC HER, MoC@NC couple with 2D graphitic carbon nitride (g-C3N4), which significantly reduces the PC HER energy barrier and enhances the separation efficiency of photogenerated carriers, and consequently, achieves an outstanding photocatalytic H-2 evolution rate of 1709 mu mol h(-1) g(-1), which is 213-fold of that of pure g-C3N4. This work paves a new avenue for developing sustainable non-noble metal catalysts for both EC and PC HERs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 32, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201518, "DOI": "10.1002/adfm.202201518", "DOI Link": "http://dx.doi.org/10.1002/adfm.202201518", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779847000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JB; Bie, Z; Cai, XX; Jiao, ZY; Wang, ZT; Tao, JC; Song, WX; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Junbo; Bie, Zhe; Cai, Xinxin; Jiao, Zhaoyang; Wang, Ziting; Tao, Jingchen; Song, Weixing; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Molecular-Sieve Electrolyte Membrane enables Separator-Free Zinc Batteries with Ultralong Cycle Life", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor stability of the zinc-metal anode is a main bottleneck for practical application of aqueous zinc-ion batteries. Herein, a series of molecular sieves with various channel sizes are investigated as an electrolyte host to regulate the ionic environment of Zn2+ on the surface of the zinc anode and to realize separator-free batteries. Based on the ZSM-5 molecular sieve, a solid-liquid mixed electrolyte membrane is constructed to uniformize the transport of zinc ions and foster dendrite-free Zn deposition. Side reactions can also be suppressed through tailoring the solvation sheath and restraining the activity of water molecules in electrolyte. A V2O5||ZSM-5||Zn full cell shows significantly enhanced performance compared to cells using glass fiber separator. Specifically, it exhibits a high specific capacity of 300 mAh g(-1), and a capacity retention of 98.67% after 1000 cycles and 82.67% after 3000 cycles at 1 A g(-1). It is attested that zeolites (ZSM-5, H-beta, and Bate) with channel sizes of 5-7 angstrom result in best cycle stability. Given the low cost and recyclability of the ZSM and its potent function, this work may further lower the cost and boost the industrial application of AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 34, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2207209, "DOI": "10.1002/adma.202207209", "DOI Link": "http://dx.doi.org/10.1002/adma.202207209", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000859054000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bennett, TD; Yue, YZ; Li, P; Qiao, A; Tao, HZ; Greaves, NG; Richards, T; Lampronti, GI; Redfern, SAT; Blanc, F; Farha, OK; Hupp, JT; Cheetharm, AK; Keen, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bennett, Thomas D.; Yue, Yuanzheng; Li, Peng; Qiao, Ang; Tao, Haizheng; Greaves, Neville G.; Richards, Tom; Lampronti, Giulio I.; Redfern, Simon A. T.; Blanc, Frederic; Farha, Omar K.; Hupp, Joseph T.; Cheetharm, Anthony K.; Keen, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Melt-Quenched Glasses of Metal-Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystalline solids dominate the field of metal organic frameworks (MOFs), with access to the liquid and glass states of matter usually prohibited by relatively low temperatures of thermal decomposition. In this work, we give due consideration to framework chemistry and topology to expand the phenomenon of the melting of 3D MOFs, linking crystal chemistry to framework melting temperature and kinetic fragility of the glass-forming liquids. Here we show that melting temperatures can be lowered by altering the chemistry of the crystalline MOF state, which provides a route to facilitate the melting of other MOFs. The glasses formed upon vitrification are chemically and structurally distinct from the three other existing categories of melt-quenched glasses (inorganic nonmetallic, organic, and metallic), and retain the basic metal ligand connectivity of crystalline MOFs, which connects their mechanical properties to their starting chemical composition. The transfer of functionality from crystal to glass points toward new routes to tunable, functional hybrid glasses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2016, "Volume": 138, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3484, "End Page": 3492, "Article Number": null, "DOI": "10.1021/jacs.5b13220", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b13220", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372477700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Wu, HB; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lei; Wu, Hao Bin; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron-Oxide- Based Advanced Anode Materials for LithiumIon Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron oxides, such as Fe2O3 and Fe3O4, have recently received increased attention as very promising anode materials for rechargeable lithium-ion batteries (LIBs) because of their high theoretical capacity, non-toxicity, low cost, and improved safety. nullostructure engineering has been demonstrated as an effective approach to improve the electrochemical performance of electrode materials. Here, recent research progress in the rational design and synthesis of diverse iron oxide-based nullomaterials and their lithium storage performance for LIBs, including 1D nullowires/rods, 2D nullosheets/flakes, 3D porous/hierarchical architectures, various hollow structures, and hybrid nullostructures of iron oxides and carbon (including amorphous carbon, carbon nullotubes, and graphene). By focusing on synthesis strategies for various iron-oxide-based nullostructures and the impacts of nullostructuring on their electrochemical performance, novel approaches to the construction of iron-oxide-based nullostructures are highlighted and the importance of proper structural and compositional engineering that leads to improved physical/chemical properties of iron oxides for efficient electrochemical energy storage is stressed. Iron-oxide-based nullomaterials stand a good chance as negative electrodes for next generation LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 560, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1300958, "DOI": "10.1002/aenm.201300958", "DOI Link": "http://dx.doi.org/10.1002/aenm.201300958", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332924700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, WH; Tan, X; Qu, JT; Li, SS; Li, JT; Liu, X; Ringer, SP; Cairney, JM; Wang, KX; Smith, SC; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Wenhao; Tan, Xin; Qu, Jiangtao; Li, Sesi; Li, Jiantao; Liu, Xin; Ringer, Simon P.; Cairney, Julie M.; Wang, Kaixue; Smith, Sean C.; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated copper-tin atomic interfaces tuning electrocatalytic CO2 conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct experimental observations of the interface structure can provide vital insights into heterogeneous catalysis. Examples of interface design based on single atom and surface science are, however, extremely rare. Here, we report Cu-Sn single-atom surface alloys, where isolated Sn sites with high surface densities (up to 8%) are anchored on the Cu host, for efficient electrocatalytic CO2 reduction. The unique geometric and electronic structure of the Cu-Sn surface alloys (Cu97Sn3 and Cu99Sn1) enables distinct catalytic selectivity from pure Cu-100 and Cu70Sn30 bulk alloy. The Cu97Sn3 catalyst achieves a CO Faradaic efficiency of 98% at a tiny overpotential of 30mV in an alkaline flow cell, where a high CO current density of 100mAcm(-2) is obtained at an overpotential of 340mV. Density functional theory simulation reveals that it is not only the elemental composition that dictates the electrocatalytic reactivity of Cu-Sn alloys; the local coordination environment of atomically dispersed, isolated Cu-Sn bonding plays the most critical role. The understanding of catalytic reactions at the atomic interface is vital; however, the characterization and mechanism studies of atomically dispersed catalysts remain challenging. Here, the authors demonstrate Cu-Sn surface alloys with isolated Sn atoms on a Cu host to achieve efficient CO2 to CO conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1449, "DOI": "10.1038/s41467-021-21750-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21750-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626131800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tritschler, U; Pearce, S; Gwyther, J; Whittell, GR; Manners, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tritschler, Ulrich; Pearce, Sam; Gwyther, Jessica; Whittell, George R.; Manners, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "50th Anniversary Perspective: Functional nulloparticles from the Solution Self-Assembly of Block Copolymers", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This Perspective outlines recent advances concerning the formation and potential uses of block copolymer micelles, a class of soft-matter-based nulloparticles of growing importance. As a result of rapidly expanding-interest since the mid-1990s, substantial advances have been reported in terms of the development of morphological diversity, structural complexity, control over micelle dimensions, scale-up, and applications in a range of areas from nullocomposites to nullomedicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2017, "Volume": 50, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3439, "End Page": 3463, "Article Number": null, "DOI": "10.1021/acs.macromol.6b02767", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.6b02767", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401221400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Li, WA; Choi, Y; Lewin, SA; Verbeke, CS; Dranoff, G; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jaeyun; Li, Weiwei Aileen; Choi, Youngjin; Lewin, Sarah A.; Verbeke, Catia S.; Dranoff, Glenn; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Injectable, spontaneously assembling, inorganic scaffolds modulate immune cells in vivo and increase vaccine efficacy", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Implanting materials in the body to program host immune cells is a promising alternative to transplantation of cells manipulated ex vivo to direct an immune response, but doing so requires a surgical procedure. Here we demonstrate that high-aspect-ratio, mesoporous silica rods (MSRs) injected with a needle spontaneously assemble in vivo to form macroporous structures that provide a 3D cellular microenvironment for host immune cells. In mice, substantial numbers of dendritic cells are recruited to the pores between the scaffold rods. The recruitment of dendritic cells and their subsequent homing to lymph nodes can be modulated by sustained release of inflammatory signals and adjuvants from the scaffold. Moreover, injection of an MSR-based vaccine formulation enhances systemic helper T cells T(H)1 and T(H)2 serum antibody and cytotoxic T-cell levels compared to bolus controls. These findings suggest that injectable MSRs may serve as a multifunctional vaccine platform to modulate host immune cell function and provoke adaptive immune responses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 433, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 33, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 64, "End Page": "U241", "Article Number": null, "DOI": "10.1038/nbt.3071", "DOI Link": "http://dx.doi.org/10.1038/nbt.3071", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347714200029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, DH; Muzzillo, CP; Tong, JH; Palmstrom, AF; Larson, BW; Choi, C; Harvey, SP; Glynn, S; Whitaker, JB; Zhang, F; Li, Z; Lu, HP; van Hest, MFAM; Berry, JJ; Mansfield, LM; Huang, Y; Yan, YF; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Dong Hoe; Muzzillo, Christopher P.; Tong, Jinhui; Palmstrom, Axel F.; Larson, Bryon W.; Choi, Chungseok; Harvey, Steven P.; Glynn, Stephen; Whitaker, James B.; Zhang, Fei; Li, Zhen; Lu, Haipeng; van Hest, Maikel F. A. M.; Berry, Joseph J.; Mansfield, Lorelle M.; Huang, Yu; Yan, Yanfa; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimolecular Additives Improve Wide-Band-Gap Perovskites for Efficient Tandem Solar Cells with CIGS", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tandem solar cells coupling narrow- and wide-band-gap thin-film polycrystalline absorbers are attractive for achieving ultrahigh efficiency with low manufacturing cost. For established narrow-band-gap CIGS thin-film bottom cells, a challenge is to develop highly efficient polycrystalline wide-band-gap top cells. Here, we demonstrate a 1.68-eV (FA(0.65)MA(0.20)Cs(0.15))Pb(I0.8Br0.2)(3) wide-band-gap perovskite solar cell with an efficiency of similar to 20% enabled by using PEAI and Pb(SCN)(2) complementary additives in the perovskite precursor. The coupling of PEA(+) and SCN- provides a synergistic effect that overcomes growth challenges with either additive individually and improves perovskite film quality with enhanced crystallinity, reduced formation of excess PbI2 (in comparison to using Pb(SCN)(2) additive alone), lower defect density and energetic disorder, and an improved carrier mobility (similar to 47 cm(2)V(-1)s(-1)) and lifetime (similar to 2.9 mu s). When coupling a semi-transparent 1.68-eV perovskite top cell fabricated by this approach with a 1 .1 2-eV CIGS bottom cell, we achieve 25.9%-efficient polycrystalline perovskite/CIGS 4-terminal thin-film tandem solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1734, "End Page": 1745, "Article Number": null, "DOI": "10.1016/j.joule.2019.04.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.04.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476463300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, KY; Li, Y; Wang, X; Zhang, ZJ; Cao, LP; Fan, XY; Wan, B; Liu, FX; Zhang, XB; He, ZG; Zhou, YT; Wang, D; Sun, J; Chen, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kaiyuan; Li, Yang; Wang, Xia; Zhang, Zhijun; Cao, Liping; Fan, Xiaoyuan; Wan, Bin; Liu, Fengxiang; Zhang, Xuanbo; He, Zhonggui; Zhou, Yingtang; Wang, Dong; Sun, Jin; Chen, Xiaoyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gas therapy potentiates aggregation-induced emission luminogen-based photoimmunotherapy of poorly immunogenic tumors through cGAS-STING pathway activation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gas-based therapy is an emerging therapeutic option for cancer treatment. Here the authors design a virus-mimicking hollow mesoporous tetrasulfide-doped organosilica for co-encapsulation of an aggregation-induced emission (AIE)-active luminogen and manganese carbonyl to fabricate a STING activating gas nullo-adjuvant for photo-immunotherapy, promoting anti-tumor immune response in preclinical models. The immunologically cold microenvironment of triple negative breast cancer results in resistance to current immunotherapy. Here, we reveal the immunoadjuvant property of gas therapy with cyclic GMP-AMP synthase-stimulator of interferon genes (cGAS-STING) pathway activation to augment aggregation-induced emission (AIE)-active luminogen (AIEgen)-based photoimmunotherapy. A virus-mimicking hollow mesoporous tetrasulfide-doped organosilica is developed for co-encapsulation of AIEgen and manganese carbonyl to fabricate gas nulloadjuvant. As tetra-sulfide bonds are responsive to intratumoral glutathione, the gas nulloadjuvant achieves tumor-specific drug release, promotes photodynamic therapy, and produces hydrogen sulfide (H2S). Upon near-infrared laser irradiation, the AIEgen-mediated phototherapy triggers the burst of carbon monoxide (CO)/Mn2+. Both H2S and CO can destroy mitochondrial integrity to induce leakage of mitochondrial DNA into the cytoplasm, serving as gas immunoadjuvants to activate cGAS-STING pathway. Meanwhile, Mn2+ can sensitize cGAS to augment STING-mediated type I interferon production. Consequently, the gas nulloadjuvant potentiates photoimmunotherapy of poorly immunogenic breast tumors in female mice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-38601-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38601-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001481100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, ZG; Ríos, C; Pernice, WHP; Wright, CD; Bhaskaran, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Zengguang; Rios, Carlos; Pernice, Wolfram H. P.; Wright, C. David; Bhaskaran, Harish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-chip photonic synapse", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for new neuromorphic computing architectures that mimic the brain's approach to simultaneous processing and storage of information is intense. Because, in real brains, neuronal synapses outnumber neurons by many orders of magnitude, the realization of hardware devices mimicking the functionality of a synapse is a first and essential step in such a search. We report the development of such a hardware synapse, implemented entirely in the optical domain via a photonic integrated-circuit approach. Using purely optical means brings the benefits of ultrafast operation speed, virtually unlimited bandwidth, and no electrical interconnect power losses. Our synapse uses phase-change materials combined with integrated silicon nitride waveguides. Crucially, we can randomly set the synaptic weight simply by varying the number of optical pulses sent down the waveguide, delivering an incredibly simple yet powerful approach that heralds systems with a continuously variable synaptic plasticity resembling the true analog nature of biological synapses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 463, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700160", "DOI": "10.1126/sciadv.1700160", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423949400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mackanic, DG; Yan, XZ; Zhang, QH; Matsuhisa, N; Yu, ZA; Jiang, YW; Manika, T; Lopez, J; Yan, HP; Liu, K; Chen, XD; Cui, Y; Bao, ZA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mackanic, David G.; Yan, Xuzhou; Zhang, Qiuhong; Matsuhisa, Naoji; Yu, Zhiao; Jiang, Yuanwen; Manika, Tuheen; Lopez, Jeffrey; Yan, Hongping; Liu, Kai; Chen, Xiaodong; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decoupling of mechanical properties and ionic conductivity in supramolecular lithium ion conductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of wearable electronics puts batteries closer to the human skin, exacerbating the need for battery materials that are robust, highly ionically conductive, and stretchable. Herein, we introduce a supramolecular design as an effective strategy to overcome the canonical tradeoff between mechanical robustness and ionic conductivity in polymer electrolytes. The supramolecular lithium ion conductor utilizes orthogonally functional H-bonding domains and ion-conducting domains to create a polymer electrolyte with unprecedented toughness (29.3 MJ m(-3)) and high ionic conductivity (1.2 x 10(-4) S cm(-1) at 25 degrees C). Implementation of the supramolecular ion conductor as a binder material allows for the creation of stretchable lithium-ion battery electrodes with strain capability of over 900% via a conventional slurry process. The supramolecular nature of these battery components enables intimate bonding at the electrode-electrolyte interface. Combination of these stretchable components leads to a stretchable battery with a capacity of 1.1 mAh cm(-2) that functions even when stretched to 70% strain. The method reported here of decoupling ionic conductivity from mechanical properties opens a promising route to create high-toughness ion transport materials for energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5384, "DOI": "10.1038/s41467-019-13362-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13362-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498700600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, YY; Zhao, LF; Peng, Q; Fan, D; Yuan, WZ; Zhang, YM; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Yongyang; Zhao, Lifang; Peng, Qian; Fan, Di; Yuan, Wang Zhang; Zhang, Yongming; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystallization-induced dual emission from metal- and heavy atom-free aromatic acids and esters", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pure organic materials exhibiting room temperature phosphorescence (RTP) have significant fundamental importance and promising optoelectronic and biological applications. Exploration of metal-and heavy atom-free pure organic phosphors, however, remains challenging because achieving emissive triplet relaxation that outcompetes the vibrational loss is difficult without metal or heavy atoms. In this contribution, in contrast to aggregation-caused quenching (ACQ) normally observed in conventional chromophores, a unique phenomenon of crystallization-induced dual emission (CIDE), namely, simultaneously boosted fluorescence and phosphorescence upon crystallization, is observed in a group of pure organic aromatic acids and esters at ambient conditions. Moreover, two triplet-involved relaxations of delayed fluorescence (DF) and phosphorescence are activated. Such efficient intrinsic emission from both singlet and triplet states in a single compound without employing metal or heavy atoms is suitable for a variety of fundamental research and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4438, "End Page": 4444, "Article Number": null, "DOI": "10.1039/c5sc00253b", "DOI Link": "http://dx.doi.org/10.1039/c5sc00253b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357931700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, SS; Hontz, ER; Sun, L; Hendon, CH; Walsh, A; Van Voorhis, T; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Sarah S.; Hontz, Eric R.; Sun, Lei; Hendon, Christopher H.; Walsh, Aron; Van Voorhis, Troy; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cation-Dependent Intrinsic Electrical Conductivity in lsostructural Tetrathiafulvalene-Based Microporous Metal-Organic Frameworks", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Isostructural metalorganic frameworks (MOFs) M-2(TTFTB) (M = Mn, Co, Zn, and Cd; H4TTFTB = tetrathiafulvalene tetrabenzoate) exhibit a striking correlation between their single-crystal conductivities and the shortest S center dot center dot center dot S interaction defined by neighboring TTF cores, which inversely correlates with the ionic radius of the metal ions. The larger cations cause a pinching of the S S contact, which is responsible for better orbital overlap between pz orbitals on neighboring S and C atoms. Density functional theory calculations show that these orbitals are critically involved in the valence band of these materials, such that modulation of the S S distance has an important effect on band dispersion and, implicitly, on the conductivity. The Cd analogue, with the largest cation and shortest S center dot center dot center dot S contact, shows the largest electrical conductivity, pi = 2.86 (+/- 0.53) X 10(-4) S/cm, which is also among the highest in microporous MOFs. These results describe the first demonstration of tunable intrinsic electrical conductivity in this class of materials and serve as a blueprint for controlling charge transport in MOFs with pi-stacked motifs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2015, "Volume": 137, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1774, "End Page": 1777, "Article Number": null, "DOI": "10.1021/ja512437u", "DOI Link": "http://dx.doi.org/10.1021/ja512437u", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349575800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rudenko, AN; Katsnelson, MI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rudenko, A. N.; Katsnelson, M. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quasiparticle band structure and tight-binding model for single- and bilayer black phosphorus", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By performing ab initio calculations for one-to four-layer black phosphorus within the GW approximation, we obtain a significant difference in the band gap (similar to 1.5 eV), which is in line with recent experimental data. The results are analyzed in terms of the constructed four-band tight-binding model, which gives accurate descriptions of the mono-and bilayer band structure near the band gap, and reveal an important role of the interlayer hoppings, which are largely responsible for the obtained gap difference.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 631, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 27", "Publication Year": 2014, "Volume": 89, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 201408, "DOI": "10.1103/PhysRevB.89.201408", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.201408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336650700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mancheri, NA; Sprecher, B; Bailey, G; Ge, JP; Tukker, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mancheri, Nabeel A.; Sprecher, Benjamin; Bailey, Gwendolyn; Ge, Jianping; Tukker, Arnold", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Chinese policies on rare earth supply chain resilience", "Source Title": "RESOURCES CONSERVATION AND RECYCLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rare earths elements (REE) are considered as strategic resources because they interact with business and governments' direct policy interventions. Policy interventions can have a major effect on security of rare earth supply (Kooroshy et al., 2015). The purpose of this study is to scrutinize China's REE policies and its impacts on the supply chain resilience. We analyze the supply chain dynamics by specifically targeting a number of Chinese REE policies that have disruptive tendencies. We analyze various policies placing the price at the center as an overarching feedback loop. In other words, we focus on how price responds to various resilience influencing mechanisms such as diversity of supply, regulatory frameworks, and stockpiling. In the process, we investigate Chinese influence on rest of the world (RoW) supply chain and dynamics inside the Chinese supply chain as there are two different layers of supply chain one for China and another one for rest of the world. We show that the supply chain is a complex phenomenon and resilience of a system is not solely dependent on physical disruptions but also on dynamic factors such as societal and geo-political (eg. environmental regulation, speculative market and export ban). We identify links and interdependencies even where data is not readily available and examine how the overall system reacts to various constraints and disruptions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 142, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 112, "Article Number": null, "DOI": "10.1016/j.resconrec.2018.11.017", "DOI Link": "http://dx.doi.org/10.1016/j.resconrec.2018.11.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457659400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, GY; Hong, JY; Hwang, S; Moon, S; Kang, H; Jeon, S; Kim, H; Jeong, JH; Lee, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Gun-Yeal; Hong, Jong-Young; Hwang, SoonHyoung; Moon, Seokil; Kang, Hyeokjung; Jeon, Sohee; Kim, Hwi; Jeong, Jun-Ho; Lee, Byoungho", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metasurface eyepiece for augmented reality", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, metasurfaces composed of artificially fabricated subwavelength structures have shown remarkable potential for the manipulation of light with unprecedented functionality. Here, we first demonstrate a metasurface application to realize a compact near-eye display system for augmented reality with a wide field of view. A key component is a see-through metalens with an anisotropic response, a high numerical aperture with a large aperture, and broadband characteristics. By virtue of these high-performance features, the metalens can overcome the existing bottleneck imposed by the narrow field of view and bulkiness of current systems, which hinders their usability and further development. Experimental demonstrations with a nulloimprinted large-area see-through metalens are reported, showing full-color imaging with a wide field of view and feasibility of mass production. This work on novel metasurface applications shows great potential for the development of optical display systems for future consumer electronics and computer vision applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4562, "DOI": "10.1038/s41467-018-07011-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07011-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448940100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, BY; Yang, K; Ma, JB; Shi, PR; Chen, LK; Chen, CM; Hong, X; Cheng, X; Tang, MC; He, YB; Kang, FY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Boyu; Yang, Ke; Ma, Jiabin; Shi, Peiran; Chen, Likun; Chen, Changmiao; Hong, Xin; Cheng, Xing; Tang, Man-Chung; He, Yan-Bing; Kang, Feiyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicomponent Copper-Zinc Alloy Layer Enabling Ultra-Stable Zinc Metal Anode of Aqueous Zn-ion Battery", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing stable surface modification layer is an effective strategy to suppress dendrite growth and side reactions of Zinc (Zn) metal anode in aqueous Zn-ion battery. Herein, a multicomponent Cu-Zn alloy interlayer with superior Zn affinity, high toughness and effective inhibition effect on lattice distortion is constructed on Zn foil (Cu-Zn@Zn) to fabricate ultra-stable Zn metal anode. Owning to the advantages of high binding energy of Cu-Zn alloy layer with Zn atoms and less contact area between metallic Zn and electrolyte, the as-prepared Cu-Zn@Zn electrode not only restricts the aggregation of Zn atoms, but also suppresses the pernicious hydrogen evolution and corrosion, leading to homogeneous Zn deposition and outstanding electrochemical performances. Accordingly, the symmetric battery with Cu-Zn@Zn electrode exhibits an ultra-long cycle life of 5496 h at 1 mA cm(-2) for 1 mAh cm(-2), and the Cu-Zn@Zn//V2O5 pouch cell demonstrates excellent cycling stability with a capacity retention of 88 % after 600 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2022, "Volume": 61, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212587", "DOI Link": "http://dx.doi.org/10.1002/anie.202212587", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870423800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, S; Davenport, TC; Haile, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Sihyuk; Davenport, Timothy C.; Haile, Sossina M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protonic ceramic electrochemical cells for hydrogen production and electricity generation: exceptional reversibility, stability, and demonstrated faradaic efficiency", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate exceptional performance for steam electrolysis at intermediate temperatures (500-650 degrees C) using protonic ceramic electrolyte cells comprised of the proton-permeable, high-activity mixed conductor PrBa0.5Sr0.5Co1.5Fe0.5O5+ (PBSCF) as the air electrode, the highly proton-conductive and chemically stable perovskite oxide BaZr0.4Ce0.4Y0.1Yb0.1O3 (BZCYYb4411) as the electrolyte, and a composite of Ni-BZCYYb4411 as the fuel electrode. Cells constructed from this material set have been shown previously to function efficiently in fuel cell mode. We demonstrate here reversible operation, enabling hydrogen production when excess electricity is available and immediate electricity generation from stored hydrogen when power demand is high. The cells are stable under cyclic operation and also under prolonged continuous operation in electrolysis mode, undergoing minimal loss in electrochemical characteristics after 500 h at 550 degrees C. Microstructurally optimized cells yield a remarkable current density of -1.80 A cm(-2) at 600 degrees C and an operating voltage of 1.3 V, of which, based on an electrochemically deduced faradaic efficiency of 76%, -1.37 A cm(-2) contributes to useful hydrogen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 206, "End Page": 215, "Article Number": null, "DOI": "10.1039/c8ee02865f", "DOI Link": "http://dx.doi.org/10.1039/c8ee02865f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457194500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, YH; Yang, XF; Lv, CX; Liu, TC; Xia, YZ; Shang, L; Waterhouse, GIN; Yang, DJ; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Yihui; Yang, Xianfeng; Lv, Chunxiao; Liu, Tongchao; Xia, Yanzhi; Shang, Lu; Waterhouse, Geoffrey I. N.; Yang, Dongjiang; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multishelled Ni-Rich Li(NixCoyMnz)O2 Hollow Fibers with Low Cation Mixing as High-Performance Cathode Materials for Li-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600262, "DOI": "10.1002/advs.201600262", "DOI Link": "http://dx.doi.org/10.1002/advs.201600262", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392400200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Hayazawa, N; Kawata, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Hayazawa, Norihiko; Kawata, Satoshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 1.7 nm resolution chemical analysis of carbon nullotubes by tip-enhanced Raman imaging in the ambient", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface morphology of materials is routinely analysed by an atomic force microscope and scanning tunneling microscope (STM) down to subnullometer precision. However, it is still challenging to investigate the surface chemistry simultaneously, which requires specific capability of force or tunneling spectroscopy in ultrahigh vacuum environment and liquid Helium temperature. Here we demonstrate the simultaneous chemical and structural analysis of individual carbon nullotubes (CNTs) by STM-based tip-enhanced Raman spectroscopy (STM-TERS) with 1.7 nm spatial resolution in the ambient. Raman contrast over different types of CNTs, local defects, diameters and bundling effect are all visualized in real space. Disengaging from ultrahigh vacuum and cryogenic environment, our ambient STM-TERS imaging is powerful in analysing local chemistry for CNTs and also suitable for analysing as-made and soft materials, which cannot be seen with general electron microscopy techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3312, "DOI": "10.1038/ncomms4312", "DOI Link": "http://dx.doi.org/10.1038/ncomms4312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332668300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Quilez-Bermejo, J; Garcia-Dali, S; Daouli, A; Zitolo, A; Canevesi, RLS; Emo, M; Izquierdo, MT; Badawi, M; Celzard, A; Fierro, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Quilez-Bermejo, Javier; Garcia-Dali, Sergio; Daouli, Ayoub; Zitolo, Andrea; Canevesi, Rafael L. S.; Emo, Melanie; Izquierdo, Maria T.; Badawi, Michael; Celzard, Alain; Fierro, Vanessa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced Design of Metal nulloclusters and Single Atoms Embedded in C1N1-Derived Carbon Materials for ORR, HER, and OER", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single atoms and nulloclusters of Fe, Ni, Co, Cu, and Mn are systematically designed and embedded in a well-defined C1N1-type material that has internal cavities of approximate to 0.6 nm based on four N atoms. These N atoms serve as perfect anchoring points for the nucleation of small nulloclusters of different metal natures through the creation of metal-nitrogen (TM-N-4) bonds. After pyrolysis at 800 degrees C, TM@CNx-type structures are obtained, where TM is the transition metal and x < 1. Fe@CNx and Co@CNx are the most promising for oxygen reduction reaction and hydrogen evolution reaction, respectively, with a Pt-like performance, and Ni@CNx is the most active for oxygen evolution reaction (OER) with an E-OER of 1.59 V versus RHE, far outperforming the commercial IrO2 (E-OER = 1.72 V). This systematic and benchmarking study can serve as a basis for the future design of advanced multi-functional electrocatalysts by modulating and combining the metallic nature of nulloclusters and single atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 33, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202300405", "DOI Link": "http://dx.doi.org/10.1002/adfm.202300405", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935522000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, ML; Chen, JW; Bai, YL; Liu, ZJ; Zhang, JX; Zhao, TK; Shi, QN; Li, SW; Wang, X; Zhang, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Menglei; Chen, Junwu; Bai, Yiling; Liu, Zhanjun; Zhang, Jingxian; Zhao, Tongkun; Shi, Qiaona; Li, Shuwei; Wang, Xi; Zhang, Guangjin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical C-N coupling with perovskite hybrids toward efficient urea synthesis", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic C-N coupling reaction by co-activation of both N-2 and CO2 molecules under ambient conditions to synthesize valuable urea opens a new avenue for sustainable development, while the actual catalytic activity is limited by poor adsorption and coupling capability of gas molecules on the catalyst surface. Herein, theoretical calculation predicts that the well-developed built-in electric field in perovskite hetero-structured BiFeO3/BiVO4 hybrids can accelerate the local charge redistribution and thus promote the targeted adsorption and activation of inert N-2 and CO2 molecules on the generated local electrophilic and nucleophilic regions. Thus, a BiFeO3/BiVO4 heterojunction is designed and synthesized, which delivers a urea yield rate of 4.94 mmol h(-1) g(-1) with a faradaic efficiency of 17.18% at -0.4 V vs. RHE in 0.1 M KHCO3, outperforming the highest values reported as far. The comprehensive analysis further confirms that the local charge redistribution in the heterojunction effectively suppresses CO poisoning and the formation of the endothermic *NNH intermediate, which thus guarantees the exothermic coupling of *N=N* intermediates with the generated CO via C-N coupling reactions to form the urea precursor *NCON* intermediate. This work opens a new avenue for effective electrocatalytic C-N coupling under ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2021, "Volume": 12, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6048, "End Page": 6058, "Article Number": null, "DOI": "10.1039/d1sc01467f", "DOI Link": "http://dx.doi.org/10.1039/d1sc01467f", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641432600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gibaja, C; Rodriguez-San-Miguel, D; Ares, P; Gómez-Herrero, J; Varela, M; Gillen, R; Maultzsch, J; Hauke, F; Hirsch, A; Abellán, G; Zamora, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gibaja, Carlos; Rodriguez-San-Miguel, David; Ares, Pablo; Gomez-Herrero, Julio; Varela, Maria; Gillen, Roland; Maultzsch, Janina; Hauke, Frank; Hirsch, Andreas; Abellan, Gonzalo; Zamora, Felix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Few-Layer Antimonene by Liquid-Phase Exfoliation", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on a fast and simple method to produce highly stable isopropanol/water (4: 1) suspensions of few-layer antimonene by liquid-phase exfoliation of antimony crystals in a process that is assisted by sonication but does not require the addition of any surfactant. This straightforward method generates dispersions of few-layer antimonene suitable for on-surface isolation. Analysis by atomic force microscopy, scanning transmission electron microscopy, and electron energy loss spectroscopy confirmed the formation of high-quality few-layer antimonene nullosheets with large lateral dimensions. These nullolayers are extremely stable under ambient conditions. Their Raman signals are strongly thickness-dependent, which was rationalized by means of density functional theory calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2016, "Volume": 55, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14343, "End Page": 14347, "Article Number": null, "DOI": "10.1002/anie.201605298", "DOI Link": "http://dx.doi.org/10.1002/anie.201605298", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387028000025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MX; Yue, JY; Cui, R; Ma, ZR; Wan, H; Wang, FF; Zhu, SJ; Zhou, Y; Kuang, Y; Zhong, YT; Pang, DW; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mingxi; Yue, Jingying; Cui, Ran; Ma, Zhuoran; Wan, Hao; Wang, Feifei; Zhu, Shoujun; Zhou, Ying; Kuang, Yun; Zhong, Yeteng; Pang, Dai-Wen; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bright quantum dots emitting at ∼1,600 nm in the NIR-IIb window for deep tissue fluorescence imaging", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With suppressed photon scattering and diminished autofluorescence, in vivo fluorescence imaging in the 1,500- to 1,700-nm range of the near-IR (NIR) spectrum (NIR-Ilb window) can afford high clarity and deep tissue penetration. However, there has been a lack of NIR-Ilb fluorescent probes with sufficient brightness and aqueous stability. Here, we present a bright fluorescent probe emitting at similar to 1,600 nm based on core/shell lead sulfide/cadmium sulfide (CdS) quantum dots (CSQDs) synthesized in organic phase. The CdS shell plays a critical role of protecting the lead sulfide (PbS) core from oxidation and retaining its bright fluorescence through the process of amphiphilic polymer coating and transferring to water needed for imparting aqueous stability and compatibility. The resulting CSQDs with a branched PEG outer layer exhibited a long blood circulation half-life of 7 hours and enabled through-skin, real-time imaging of blood flows in mouse vasculatures at an unprecedented 60 frames per second (fps) speed by detecting similar to 1,600-nm fluorescence under 808-nm excitation. It also allowed through-skin in vivo confocal 3D imaging of tumor vasculatures in mice with an imaging depth of similar to 1.2 mm. The PEG-CSQDs accumulated in tumor effectively through the enhanced permeation and retention effect, affording a high tumor-to-normal tissue ratio up to similar to 32 owing to the bright similar to 1,600-nm emission and nearly zero autofluorescence background resulting from a large similar to 800-nm Stoke's shift. The aqueous-compatible CSQDs are excreted through the biliary pathway without causing obvious toxicity effects, suggesting a useful class of similar to 1,600-nm emitting probes for biomedical research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2018, "Volume": 115, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6590, "End Page": 6595, "Article Number": null, "DOI": "10.1073/pnas.1806153115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1806153115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436245000050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, LJ; Xu, H; Liu, LC; Zheng, YQ; Han, W; Wang, LL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lianjia; Xu, Hao; Liu, Lingchen; Zheng, Yiqiang; Han, Wei; Wang, Lili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene-Induced Flexible, Water-Retention, Semi-Interpenetrating Network Hydrogel for Ultra-Stable Strain Sensors with Real-Time Gesture Recognition", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As water-saturated polymer networks, hydrogels are a growing family of soft materials that have recently become promising candidates for flexible electronics application. However, it remains still difficult for hydrogel-based strain sensors to achieve the organic unity of mechanical properties, electrical conductivity, and water retention. To address this challenge, based on the template, the excellent properties of MXene nulloflakes (rich surface functional groups, high specific surface area, hydrophilicity, and conductivity) are fully utilized in this study to prepare the P(AA-co-AM)/MXene@PDADMAC semi-interpenetrating network (semi-IPN) hydrogel. The proposed hydrogel continues to exhibit excellent strain response and flexibility after 30 days of storage at room temperature, and its performance do not decrease after 1100 cycles. Considering these characteristics, a hydrogel-based device for converting sign language into Chinese characters is successfully developed and optimized using machine learning. Therefore, this study provides novel insight and application directions for hydrogel families. MXene semi-interpenetrating network hydrogels take full advantage of the characteristics of MXene nulloflakes and the interaction between components. The strain sensor based on it has high stability, high sensitivity, and fast response recovery time. And the portable device can convert sign language into Chinese characters.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 10, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202303922", "DOI Link": "http://dx.doi.org/10.1002/advs.202303922", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059266800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yagai, S; Okamura, S; Nakano, Y; Yamauchi, M; Kishikawa, K; Karatsu, T; Kitamura, A; Ueno, A; Kuzuhara, D; Yamada, H; Seki, T; Ito, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yagai, Shiki; Okamura, Satoru; Nakano, Yujiro; Yamauchi, Mitsuaki; Kishikawa, Keiki; Karatsu, Takashi; Kitamura, Akihide; Ueno, Akira; Kuzuhara, Daiki; Yamada, Hiroko; Seki, Tomohiro; Ito, Hajime", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design amphiphilic dipolar π-systems for stimuli-responsive luminescent materials using metastable states", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "pi-Conjugated compounds that exhibit tunable luminescence in the solid state under external mechanical stimuli have potential applications in sensors and imaging devices. However, no rational designs have been proposed that impart these mechano-responsive luminescent properties to pi-conjugated compounds. Here we demonstrate a strategy for mechano-responsive luminescent materials by imparting amphiphilic and dipolar characteristics to a luminescent pi-conjugated system. The oligo(p-phenylenevinylene) luminophore with a didodecylamino group at one end and a tri(ethylene glycol) ester group at the other end yields segregated solid structures by separately aggregating its hydrophobic and hydrophilic moieties. The segregated structures force the molecules to align in the same direction, thereby generating a conflict between the side-chain aggregation and dipolar stabilization of the pi-system. Consequently, these metastable solid structures can be transformed through mechanical stimulation to a more stable structure, from a pi-pi stacked aggregate to a liquid crystal and further to a crystalline phase with variable luminescence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4013, "DOI": "10.1038/ncomms5013", "DOI Link": "http://dx.doi.org/10.1038/ncomms5013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338836500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bauer, J; Meza, LR; Schaedler, TA; Schwaiger, R; Zheng, XY; Valdevit, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bauer, Jens; Meza, Lucas R.; Schaedler, Tobias A.; Schwaiger, Ruth; Zheng, Xiaoyu; Valdevit, Lorenzo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullolattices: An Emerging Class of Mechanical Metamaterials", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In 1903, Alexander Graham Bell developed a design principle to generate lightweight, mechanically robust lattice structures based on triangular cells; this has since found broad application in lightweight design. Over one hundred years later, the same principle is being used in the fabrication of nullolattice materials, namely lattice structures composed of nulloscale constituents. Taking advantage of the size-dependent properties typical of nulloparticles, nullowires, and thin films, nullolattices redefine the limits of the accessible material-property space throughout different disciplines. Herein, the exceptional mechanical performance of nullolattices, including their ultrahigh strength, damage tolerance, and stiffness, are reviewed, and their potential for multifunctional applications beyond mechanics is examined. The efficient integration of architecture and size-affected properties is key to further develop nullolattices. The introduction of a hierarchical architecture is an effective tool in enhancing mechanical properties, and the eventual goal of nullolattice design may be to replicate the intricate hierarchies and functionalities observed in biological materials. Additive manufacturing and self-assembly techniques enable lattice design at the nulloscale; the scaling-up of nullolattice fabrication is currently the major challenge to their widespread use in technological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 461, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 29, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701850, "DOI": "10.1002/adma.201701850", "DOI Link": "http://dx.doi.org/10.1002/adma.201701850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413406200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, PP; Li, C; Zhang, XT; Xu, J; Chen, X; Wang, XL; Jia, Y; Wang, XJ; Liu, YC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Peng-Peng; Li, Cong; Zhang, Xin-Tong; Xu, Jun; Chen, Xi; Wang, Xiu-Li; Jia, Yan; Wang, Xiaojun; Liu, Yi-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A single Eu2+-activated high-color-rendering oxychloride white-light phosphor for white-light-emitting diodes", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-phased, high-color-rendering index (CRI) white-light phosphors are emerging as potential phosphor-converted white-light-emitting diodes (WLEDs) and as an alternative to blends of tricolor phosphors. However, it is a challenge to create a high CRI white light from a single-doped activator. Here, we present a high CRI (Ra =91) white-light phosphor, Sr-5(PO4)(3-x)(BO3)(x)Cl:Eu2+, composed of Sr-5(PO4)(3)Cl as the beginning member and Sr-5(BO3)(3)Cl as the end member. This work utilized the solid-solution method, and tunable Eu2+ emission was achieved. Color-tunable Eu2+ emissions in response to structural variation were observed in Sr-5(PO4)(3-x)(BO3)(x)Cl solid solutions. This was further confirmed using X-ray Rietveld refinement, electron paramagnetic resonullce spectroscopy, and in the photoluminescence spectra. The color-tunable emissions included the white light that originated from the combination of the blue emission of Sr-5(PO4)(3)Cl:Eu2+ and an induced Eu2+ yellow emission at approximately 550 nm in the solid solution. Importantly, the white-light phosphors showed a greater R9 = 90.2 under excitation at 365 nm. This result has rarely been reported in the literature and is greater than that of (R9 = 14.3) commercial Y3Al5O12:Ce3+-based WLEDs. These findings demonstrate the great potential of Sr-5(PO4)(3-x)(BO3)(x)Cl:0.04Eu(2+) as a white-light phosphor for near-UV phosphor-converted WLEDs. These results also provide a shortcut for developing a high CRI white-light phosphor from a single Eu2+-doped compound.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e16024", "DOI": "10.1038/lsa.2016.24", "DOI Link": "http://dx.doi.org/10.1038/lsa.2016.24", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370478500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, H; Cheng, T; Goddard, WA ; Sundararaman, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Hai; Cheng, Tao; Goddard, William A., III; Sundararaman, Ravishankar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanistic Explanation of the pH Dependence and Onset Potentials for Hydrocarbon Products from Electrochemical Reduction of CO on Cu (111)", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy and environmental concerns demand development of more efficient and selective electrodes for electrochemical reduction of CO2 to form fuels and chemicals. Since Cu is the only pure metal exhibiting reduction to form hydrocarbon chemicals, we focus here on the Cu (111) electrode. We present a methodology for density functional theory calculations to obtain accurate onset electrochemical potentials with explicit constant electrochemical potential and pH effects using implicit solvation. We predict the atomistic mechanisms underlying electrochemical reduction of CO, finding that (1) at acidic pH, the C-1 pathway proceeds through COH to CHOH to form CH4 while C-2 (C-3) pathways are kinetically blocked; (2) at neutral pH, the C-1 and C-2 (C-3) pathways share the COH common intermediate, where the branch to C-C coupling is realized by a novel CO-COH pathway; and (3) at high pH, early C-C coupling through adsorbed CO dimerization dominates, suppressing the C-1 pathways by kinetics, thereby boosting selectivity for multi-carbon products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2016, "Volume": 138, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 483, "End Page": 486, "Article Number": null, "DOI": "10.1021/jacs.5b11390", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368562800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Özçelik, VO; Azadani, JG; Yang, C; Koester, SJ; Low, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozcelik, V. Ongun; Azadani, Javad G.; Yang, Ce; Koester, Steven J.; Low, Tony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band alignment of two-dimensional semiconductors for designing heterostructures with momentum space matching", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a comprehensive study of the band alignments of two-dimensional (2D) semiconducting materials and highlight the possibilities of forming momentum-matched type I, II, and III heterostructures, an enticing possibility being atomic heterostructures where the constituent monolayers have band edges at the zone center, i.e., Gamma valley. Our study, which includes the group IV and III-V compound monolayer materials, group V elemental monolayer materials, transition-metal dichalcogenides, and transition-metal trichalcogenides, reveals that almost half of these materials have conduction and/or valence band edges residing at the zone center. Using first-principles density functional calculations, we present the type of the heterostructure for 903 different possible combinations of these 2D materials which establishes a periodic table of heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2016, "Volume": 94, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35125, "DOI": "10.1103/PhysRevB.94.035125", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.035125", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379502200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, FF; Zhai, PB; Wei, Y; Yang, ZL; Chen, Q; Zuo, JH; Gu, XK; Gong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Feifei; Zhai, Pengbo; Wei, Yi; Yang, Zhilin; Chen, Qian; Zuo, Jinghan; Gu, Xiaokang; Gong, Yongji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Artificial SEI Layer on Lithiophilic MXene Surface for High-Performance Lithium Metal Anodes", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene has been found as a good host for lithium (Li) metal anodes because of its high specific surface area, lithiophilicity, good stability with lithium, and the in situ formed LiF protective layer. However, the formation of Li dendrites and dead Li is inevitable during long-term cycle due to the lack of protection at the Li/electrolyte interface. Herein, a stable artificial solid electrolyte interface (SEI) is constructed on the MXene surface by using insulating g-C3N4 layer to regulate homogeneous Li plating/stripping. The 2D/2D MXene/g-C3N4 composite nullosheets can not only guarantee sufficient lithiophilic sites, but also protect the Li metal from continuous corrosion by electrolytes. Thus, the Ti3C2Tx/g-C3N4 electrode enables conformal Li deposition, enhanced average Coulombic efficiency (CE) of 98.4%, and longer cycle lifespan over 400 cycles with an areal capacity of 1.0 mAh cm(-2) at 0.5 mA cm(-2). Full cells paired with LiFePO4 (LFP) cathode also achieve enhanced rate capacity and cycling stability with higher capacity retention of 85.5% after 320 cycles at 0.5C. The advantages of the 2D/2D lithiophilic layer/artificial SEI layer heterostructures provide important insights into the design strategies for high-performance and stable Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103930, "DOI": "10.1002/advs.202103930", "DOI Link": "http://dx.doi.org/10.1002/advs.202103930", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739468400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bian, G; Chang, TR; Sankar, R; Xu, SY; Zheng, H; Neupert, T; Chiu, CK; Huang, SM; Chang, GQ; Belopolski, I; Sanchez, DS; Neupane, M; Alidoust, N; Liu, C; Wang, BK; Lee, CC; Jeng, HT; Zhang, CL; Yuan, ZJ; Jia, S; Bansil, A; Chou, FC; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bian, Guang; Chang, Tay-Rong; Sankar, Raman; Xu, Su-Yang; Zheng, Hao; Neupert, Titus; Chiu, Ching-Kai; Huang, Shin-Ming; Chang, Guoqing; Belopolski, Ilya; Sanchez, Daniel S.; Neupane, Madhab; Alidoust, Nasser; Liu, Chang; Wang, BaoKai; Lee, Chi-Cheng; Jeng, Horng-Tay; Zhang, Chenglong; Yuan, Zhujun; Jia, Shuang; Bansil, Arun; Chou, Fangcheng; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological nodal-line fermions in spin-orbit metal PbTaSe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological semimetals can support one-dimensional Fermi lines or zero-dimensional Weyl points in momentum space, where the valence and conduction bands touch. While the degeneracy points in Weyl semimetals are robust against any perturbation that preserves translational symmetry, nodal lines require protection by additional crystalline symmetries such as mirror reflection. Here we report, based on a systematic theoretical study and a detailed experimental characterization, the existence of topological nodal-line states in the non-centrosymmetric compound PbTaSe2 with strong spin-orbit coupling. Remarkably, the spin-orbit nodal lines in PbTaSe2 are not only protected by the reflection symmetry but also characterized by an integer topological invariant. Our detailed angle-resolved photoemission measurements, first-principles simulations and theoretical topological analysis illustrate the physical mechanism underlying the formation of the topological nodal-line states and associated surface states for the first time, thus paving the way towards exploring the exotic properties of the topological nodal-line fermions in condensed matter systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 729, "Times Cited, All Databases": 773, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10556, "DOI": "10.1038/ncomms10556", "DOI Link": "http://dx.doi.org/10.1038/ncomms10556", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371014300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Gao, Y; Peng, J; Fan, YM; Zhao, LF; Li, L; Xiao, Y; Pang, WK; Wang, JZ; Chou, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hang; Gao, Yun; Peng, Jian; Fan, Yameng; Zhao, Lingfei; Li, Li; Xiao, Yao; Pang, Wei Kong; Wang, Jiazhao; Chou, Shu-Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prussian Blue Analogues with Optimized Crystal Plane Orientation and Low Crystal Defects toward 450 Wh kg-1 Alkali-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Prussian blue analogues (PBAs) have been regarded as promising cathode materials for alkali-ion batteries owing to their high theoretical energy density and low cost. However, the high water and vacancy content of PBAs lower their energy density and bring safety issues, impeding their large-scale application. Herein, a facile potassium-ions assisted strategy is proposed to synthesize highly crystallized PBAs. By manipulating the dominullt crystal plane and suppressing vacancies, the as-prepared PBAs exhibit increased redox potential resulting in high energy density up to approximate to 450 Wh kg(-1), which is at the same level of the well-known LiFePO4 cathodes for lithium-ion batteries. Remarkably, unconventional highly-reversible phase evolution and redox-active pairs were identified by multiple in situ techniques for the first time. The preferred guest-ion storage sites and migration mechanism were systematically analysed through theoretical calculations. We believe these results could inspire the design of safe with high energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 MAY 24", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202303953", "DOI Link": "http://dx.doi.org/10.1002/anie.202303953", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000993478800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, SM; Rao, KM; Zo, SM; Shin, EJ; Han, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Soon Mo; Rao, Kummara Madhusudana; Zo, Sun Mi; Shin, Eun Joo; Han, Sung Soo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bacterial Cellulose and Its Applications", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sharp increase in the use of cellulose seems to be in increasing demand in wood; much more research related to sustainable or alternative materials is necessary as a lot of the arable land and natural resources use is unsustainable. In accordance, attention has focused on bacterial cellulose as a new functional material. It possesses a three-dimensional, gelatinous structure consisting of cellulose with mechanical and thermal properties. Moreover, while a plant-originated cellulose is composed of cellulose, hemi-cellulose, and lignin, bacterial cellulose attributable to the composition of a pure cellulose nullofiber mesh spun is not necessary in the elimination of other components. Moreover, due to its hydrophilic nature caused by binding water, consequently being a hydrogel as well as biocompatibility, it has only not only used in medical fields including artificial skin, cartilage, vessel, and wound dressing, but also in delivery; some products have even been commercialized. In addition, it is widely used in various technologies including food, paper, textile, electronic and electrical applications, and is being considered as a highly versatile green material with tremendous potential. However, many efforts have been conducted for the evolution of novel and sophisticated materials with environmental affinity, which accompany the empowerment and enhancement of specific properties. In this review article, we summarized only industry and research status regarding BC and contemplated its potential in the use of BC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 14, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1080, "DOI": "10.3390/polym14061080", "DOI Link": "http://dx.doi.org/10.3390/polym14061080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776427200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Delacuvellerie, A; Cyriaque, V; Gobert, S; Benali, S; Wattiez, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Delacuvellerie, Alice; Cyriaque, Valentine; Gobert, Sylvie; Benali, Samira; Wattiez, Ruddy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The plastisphere in marine ecosystem hosts potential specific microbial degraders including Alcanivorax borkumensis as a key player for the low-density polyethylene degradation", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most plastics are released to the environment in landfills and around 32% end up in the sea, inducing large ecological and health impacts. The plastics constitute a physical substrate and potential carbon source for microorganisms. The present study compares the structures of bacterial communities from floating plastics, sediment-associated plastics and sediments from the Mediterranean Sea. The 16S rRNA microbiome profiles of surface and sediment plastic-associated microbial biofilms from the same geographic location differ significantly, with the omnipresence of Bacteroidetes and Gammaproteobacteria. Our research confirmed that plastisphere hosts microbial communities were environmental distinct niche. In parallel, this study used environmental samples to investigate the enrichment of potential plastic-degrading bacteria with Low Density PolyEthylene (LDPE), PolyEthylene Terephthalate (PET) and PolyStyrene (PS) plastics as the sole carbon source. In this context, we showed that the bacterial community composition is clearly plastic nature dependent. Hydrocarbon-degrading bacteria such as Alcanivorax, Marinobacter and Arenibacter genera are enriched with LDPE and PET, implying that these bacteria are potential players in plastic degradation. Finally, our data showed for the first time the ability of Alcanivorax borkwnensis to form thick biofilms specifically on LDPE and to degrade this petroleum-based plastic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2019, "Volume": 380, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120899, "DOI": "10.1016/j.jhazmat.2019.120899", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2019.120899", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491683300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aboulkhair, NT; Maskery, I; Tuck, C; Ashcroft, I; Everitt, NM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aboulkhair, Nesma T.; Maskery, Ian; Tuck, Chris; Ashcroft, Ian; Everitt, Nicola M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The microstructure and mechanical properties of selectively laser melted AlSi10Mg: The effect of a conventional T6-like heat treatment", "Source Title": "MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selective laser melting (SLM) of aluminium is of research interest because, of its potential benefits to high value manufacturing applications in the aerospace and automotive industries. In order to demonstrate the credibility of SLM Al parts, their mechanical properties need to be studied. In this paper, the nullo-, micro-, and macro-scale mechanical properties of SLM AlSi10Mg were examined. In addition, the effect of a conventional T6-like heat treatment was investigated and correlated to the generated microstructure. nulloindentation showed uniform hardness within the SLM material. Significant spatial variation was observed after heat treatment due to phase transformation. It was found that the SLM material's micro-hardness exceeded its die-cast counterpart. Heat treatment softened the material, reducing micro-hardness from 125 +/- 1 HV to 100 +/- 1 HV. An ultimate tensile strength (333 MPa), surpassing that of the die cast counterpart was achieved, which was slightly reduced by heat treatment (12%) alongside a significant gain in strain-to-failure (similar to threefold). Significantly high compressive yield strength was recorded for the as-built material with the ability to withstand high compressive strains. The SLM characteristic microstructure yielded enhanced strength under loading, outperforming cast material. The use of a T6-like heat treatment procedure also modified the properties of the material to yield a potentially attractive compromise between the material's strength and ductility making it more suitable for a wider range of applications and opening up further opportunities for the additive manufacturing process and alloy combination. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2016, "Volume": 667, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 139, "End Page": 146, "Article Number": null, "DOI": "10.1016/j.msea.2016.04.092", "DOI Link": "http://dx.doi.org/10.1016/j.msea.2016.04.092", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378183800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CY; Chen, J; Qing, TT; Fan, XL; Sun, W; von Cresce, A; Ding, MS; Borodin, O; Vatamanu, J; Schroeder, MA; Eidson, N; Wang, CS; Xu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chongyin; Chen, Ji; Qing, Tingting; Fan, Xiulin; Sun, Wei; von Cresce, Arthur; Ding, Michael S.; Borodin, Oleg; Vatamanu, Jenel; Schroeder, Marshall A.; Eidson, Nico; Wang, Chunsheng; Xu, Kang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4.0 V Aqueous Li-Ion Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although recent efforts have expanded the stability window of aqueous electrolytes from 1.23 V to > 3 V, intrinsically safe aqueous batteries still deliver lower energy densities (200 Wh/kg) compared with state-of-the-art Li-ion batteries (similar to 400 Wh/ kg). The essential origin for this gap comes from their cathodic stability limit, excluding the use of themost ideal anodematerials (graphite, Limetal). Here, we resolved this ''cathodic challenge'' by adopting an ''inhomogeneous additive'' approach, in which a fluorinated additive immiscible with aqueous electrolyte can be applied on anode surfaces as an interphase precursor coating. The strong hydrophobicity of the precursor minimizes the competitive water reduction during interphase formation, while its own reductive decomposition forms a unique composite interphase consisting of both organic and inorganic fluorides. Such effective protection allows these high-capacity/low-potential anode materials to couple with different cathode materials, leading to 4.0 V aqueous Li-ion batteries with high efficiency and reversibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 496, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2017, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 122, "End Page": 132, "Article Number": null, "DOI": "10.1016/j.joule.2017.08.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.08.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425179500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamali, SM; Arbabi, E; Arbabi, A; Horie, Y; Faraji-Dana, M; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamali, Seyedeh Mahsa; Arbabi, Ehsan; Arbabi, Amir; Horie, Yu; Faraji-Dana, MohammadSadegh; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Angle-Multiplexed Metasurfaces: Encoding Independent Wavefronts in a Single Metasurface under Different Illumination Angles", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The angular response of thin diffractive optical elements is highly correlated. For example, the angles of incidence and diffraction of a grating are locked through the grating momentum determined by the grating period. Other diffractive devices, including conventional metasurfaces, have a similar angular behavior due to the fixed locations of the Fresnel zone boundaries and the weak angular sensitivity of the meta-atoms. To alter this fundamental property, we introduce angle-multiplexed metasurfaces, composed of reflective high-contrast dielectric U-shaped meta-atoms, whose response under illumination from different angles can be controlled independently. This enables flat optical devices that impose different and independent optical transformations when illuminated from different directions, a capability not previously available in diffractive optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 6", "Publication Year": 2017, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41056, "DOI": "10.1103/PhysRevX.7.041056", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.7.041056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417131200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, RC; Xu, B; Dong, HJ; Yang, CC; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Rong Chao; Xu, Bo; Dong, Hou Ji; Yang, Chun Cheng; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N/O Dual-Doped Environment-Friendly Hard Carbon as Advanced Anode for Potassium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries (PIBs) are considered as promising candidates for lithium-ion batteries due to the abundant reserve and lower cost of K resources. However, K+ exhibits a larger radius than that of Li+, which may impede the intercalation of K+ into the electrode, thus resulting in poor cycling stability of PIBs. Here, an N/O dual-doped hard carbon (NOHC) is constructed by carbonizing the renewable piths of sorghum stalks. As a PIB anode, NOHC presents a high reversible capacity (304.6 mAh g(-1) at 0.1 A g(-1) after 100 cycles) and superior cycling stability (189.5 mAh g(-1) at 1 A g(-1) after 5000 cycles). The impressive electrochemical performances can be ascribed to the super-stable porous structure, expanded interlayer space, and N/O dual-doping. More importantly, the NOHC can be prepared in large scale in a concise way, showing great potential for commercialization applications. This work may impel the development of low-cost and sustainable carbon-based materials for PIBs and other advanced energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902547, "DOI": "10.1002/advs.201902547", "DOI Link": "http://dx.doi.org/10.1002/advs.201902547", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506250100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GZ; Chang, J; Wang, LG; Li, JW; Wang, CY; Wang, R; Shi, GL; Yu, K; Huang, W; Zheng, HH; Wu, TP; Deng, YH; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guangzhao; Chang, Jian; Wang, Liguang; Li, Jiawei; Wang, Chaoyang; Wang, Ruo; Shi, Guoli; Yu, Kai; Huang, Wei; Zheng, Honghe; Wu, Tianpin; Deng, Yonghong; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A monofluoride ether-based electrolyte solution for fast-charging and low-temperature non-aqueous lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energy content of non-aqueous lithium batteries is limited by the electrochemical stability window of the electrolyte solution. Here, the authors report a monofluoride ether-based electrolyte to stabilize high-voltage lithium metal batteries at high current rates and low temperatures. The electrochemical stability window of the electrolyte solution limits the energy content of non-aqueous lithium metal batteries. In particular, although electrolytes comprising fluorinated solvents show good oxidation stability against high-voltage positive electrode active materials such as LiNi0.8Co0.1Mn0.1O2 (NCM811), the ionic conductivity is adversely affected and, thus, the battery cycling performance at high current rates and low temperatures. To address these issues, here we report the design and synthesis of a monofluoride ether as an electrolyte solvent with Li-F and Li-O tridentate coordination chemistries. The monofluoro substituent (-CH2F) in the solvent molecule, differently from the difluoro (-CHF2) and trifluoro (-CF3) counterparts, improves the electrolyte ionic conductivity without narrowing the oxidation stability. Indeed, the electrolyte solution with the monofluoride ether solvent demonstrates good compatibility with positive and negative electrodes in a wide range of temperatures (i.e., from -60 degrees C to +60 degrees C) and at high charge/discharge rates (e.g., at 17.5 mA cm(-2)). Using this electrolyte solution, we assemble and test a 320 mAh Li||NCM811 multi-layer pouch cell, which delivers a specific energy of 426 Wh kg(-1) (based on the weight of the entire cell) and capacity retention of 80% after 200 cycles at 0.8/8 mA cm(-2) charge/discharge rate and 30 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1081, "DOI": "10.1038/s41467-023-36793-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36793-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002656000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jones, AM; Yu, HY; Ross, JS; Klement, P; Ghimire, NJ; Yan, JQ; Mandrus, DG; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jones, Aaron M.; Yu, Hongyi; Ross, Jason S.; Klement, Philip; Ghimire, Nirmal J.; Yan, Jiaqiang; Mandrus, David G.; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-layer locking effects in optical orientation of exciton spin in bilayer WSe2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coupling degrees of freedom of distinct nature plays a critical role in numerous physical phenomena(1-10). The recent emergence of layered materials(11-13) provides a laboratory for studying the interplay between internal quantum degrees of freedom of electrons(14,15). Here we report new coupling phenomena connecting real spin with layer pseudospins in bilayer WSe2. In polarization-resolved photoluminescence measurements, we observe large spin orientation of neutral and charged excitons by both circularly and linearly polarized excitation, with the trion spectrum splitting into a doublet at large vertical electrical field. These observations can be explained as a locking of spin and layer pseudospin in a given valley(15), where the doublet implies an electrically induced spin splitting. The observed distinctive behaviour of the trion doublet under polarized excitation further provides spectroscopic evidence of interlayer and intralayer trion species, a promising step towards optical manipulation in van der Waals heterostructures(16) through interlayer excitons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 130, "End Page": 134, "Article Number": null, "DOI": "10.1038/NPHYS2848", "DOI Link": "http://dx.doi.org/10.1038/NPHYS2848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332141800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, T; Zhang, JB; Zhong, WK; Liang, YY; Zhang, K; Dong, S; Ying, L; Liu, F; Wang, XH; Huang, F; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Tao; Zhang, Jiabin; Zhong, Wenkai; Liang, Yuanying; Zhang, Kai; Dong, Sheng; Ying, Lei; Liu, Feng; Wang, Xiaohui; Huang, Fei; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "14.4% efficiency all-polymer solar cell with broad absorption and low energy loss enabled by a novel polymer acceptor", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-polymer solar cells (All-PSCs) offer several distinct merits including superior thermal stability and flexibility. Here, we report a novel polymer acceptor PJ1 that exhibits a narrow band gap around 1.4 eV and a high extinction coefficient about 1.39 x 10(5) cm(-1). When PJ1 is blended with donor polymer PBDB-T, all-PSC with a record power conversion efficiency (PCE) of 14.4% is achieved, which is mainly attributed to the broad absorption, efficient charge separation and collection, and low energy loss. The synergetic effects of molecular weight of PJ1 on the photovoltaic performance are also investigated. It is found that the increase in molecular weight can result in the red-shift of absorption along with slight enhancement of extinction coefficient, which therefore benefits photocurrent. In addition, all-PSC based on PJ1 demonstrate much better thermal stability than the control device based on small molecule acceptor (TTPBT-IC), as evidenced by the insignificant morphology change of PBDB-T:PJ1 versus excessive phase separation of PBDB-T:TTPBT-IC when annealed at 150 degrees C. Of particular interest is that the all-PSCs based on PBDB-T:PJ1 can retain high PCEs even when the thickness of photoactive layer is increased over 300 nm (PCE of 12.1%) or the device area is enlarged to 1 cm(2) (PCE of 13.0%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 72, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104718, "DOI": "10.1016/j.nulloen.2020.104718", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.104718", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000532790600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, D; Yang, YQ; Chen, Z; Tao, Y; Liu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Duan; Yang, Yong-Qiang; Chen, Zheng; Tao, Ye; Liu, Yun-Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress on thin-film encapsulation technologies for organic electronic devices", "Source Title": "OPTICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among the advanced electronic devices, flexible organic electronic devices with rapid development are the most promising technologies to customers and industries. Organic thin films accommodate low-cost fabrication and can exploit diverse molecules in inexpensive plastic light emitting diodes, plastic solar cells, and even plastic lasers. These properties may ultimately enable organic materials for practical applications in industry. However, the stability of organic electronic devices still remains a big challenge, because of the difficulty in fabricating commercial products with flexibility. These organic materials can be protected using substrates and barriers such as glass and metal; however, this results in a rigid device and does not satisfy the applications demanding flexible devices. Plastic substrates and transparent flexible encapsulation barriers are other possible alternatives; however, these offer little protection to oxygen and water, thus rapidly degrading the devices. Thin-film encapsulation (TFE) technology is most effective in preventing water vapor and oxygen permeation into the flexible devices. Because of these (and other) reasons, there has been an intense interest in developing transparent barrier materials with much lower permeabilities, and their market is expected to reach over $550 million by 2025. In this study, the degradation mechanism of organic electronic devices is reviewed. To increase the stability of devices in air, several TFE technologies were applied to provide efficient barrier performance. In this review, the degradation mechanism of organic electronic devices, permeation rate measurement, traditional encapsulation technologies, and TFE technologies are presented. (C) 2015 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2016, "Volume": 362, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 43, "End Page": 49, "Article Number": null, "DOI": "10.1016/j.optcom.2015.08.021", "DOI Link": "http://dx.doi.org/10.1016/j.optcom.2015.08.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369229900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, LX; Ye, C; Zhao, XX; Zhou, XY; Hu, JX; Li, Q; Liu, D; Das, CM; Yang, JF; Hu, DY; Chen, JQ; Cao, X; Zhang, Y; Xu, MZ; Di, J; Tian, D; Song, P; Kutty, G; Zeng, QS; Fu, QD; Deng, Y; Zhou, JD; Ariando, A; Miao, F; Hong, G; Huang, YZ; Pennycook, SJ; Yong, KT; Ji, W; Wang, XRS; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Lixing; Ye, Chen; Zhao, Xiaoxu; Zhou, Xieyu; Hu, Junxiong; Li, Qiao; Liu, Dan; Das, Chandreyee Manas; Yang, Jiefu; Hu, Dianyi; Chen, Jieqiong; Cao, Xun; Zhang, Yong; Xu, Manzhang; Di, Jun; Tian, Dan; Song, Pin; Kutty, Govindan; Zeng, Qingsheng; Fu, Qundong; Deng, Ya; Zhou, Jiadong; Ariando, Ariando; Miao, Feng; Hong, Guo; Huang, Yizhong; Pennycook, Stephen J.; Yong, Ken-Tye; Ji, Wei; Wang, Xiao Renshaw; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-controllable growth of ultrathin 2D magnetic FeTe crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) magnets with intrinsic ferromagnetic/antiferromagnetic (FM/AFM) ordering are highly desirable for future spintronic devices. However, the direct growth of their crystals is in its infancy. Here we report a chemical vapor deposition approach to controllably grow layered tetragonal and non-layered hexagonal FeTe nulloplates with their thicknesses down to 3.6 and 2.8nm, respectively. Moreover, transport measurements reveal these obtained FeTe nulloflakes show a thickness-dependent magnetic transition. Antiferromagnetic tetragonal FeTe with the Neel temperature (T-N) gradually decreases from 70 to 45K as the thickness declines from 32 to 5nm. And ferromagnetic hexagonal FeTe is accompanied by a drop of the Curie temperature (T-C) from 220K (30nm) to 170K (4nm). Theoretical calculations indicate that the ferromagnetic order in hexagonal FeTe is originated from its concomitant lattice distortion and Stoner instability. This study highlights its potential applications in future spintronic devices. Two-dimensional magnets with intrinsic ferromagnetic/antiferromagnetic ordering are highly desirable for future spintronic devices. Here, the authors demonstrate a chemical vapor deposition approach to controllably grow ultrathin FeTe crystals with antiferromagnetic tetragonal and ferromagnetic hexagonal phase, showing a thickness-dependent magnetic transition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3729, "DOI": "10.1038/s41467-020-17253-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17253-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556361600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZB; Zhu, WD; Yi, JH; Liu, N; Cao, YG; Lu, JL; Decker, EA; McClements, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zhenbao; Zhu, Weiduo; Yi, Jianhua; Liu, Ning; Cao, Yungang; Lu, Jiali; Decker, Eric Andrew; McClements, David Julian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of sonication on the physicochemical and functional properties of walnut protein isolate", "Source Title": "FOOD RESEARCH INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this study was to investigate the impact of high -intensity ultrasound treatment (sonication) on the molecular, physicochemical, and functional properties of walnut protein isolate. Aqueous walnut protein suspensions were sonicated at varying power levels (200, 400 or 600 W) and times (15 or 30 min), and then any alternations in protein structure and properties were determined. SDS-PAGE demonstrated that there were no changes in protein electrophoretic patterns, indicating that sonication did not break covalent bonds. Circular dichroism spectroscopy indicated a small change in protein secondary structure after sonication, with a decrease in alpha-helix and increase in beta-sheet, beta-turn, and random coil content. There was an increase in surface free sulfhydryl (SH) groups and a decrease in fluorescence intensity after sonication, indicating that appreciable changes in tertiary structure occurred. Ultrasound reduced the size of the particles in aqueous walnut protein dispersions as confirmed by static light scattering and scanning electron microscopy, suggesting that sonication dissociated protein aggregates. Moreover, the water-solubility ( + 22%), emulsifying activity index ( + 26%), and emulsifying stability index ( + 41%) all increased after sonication. These results suggest that sonication is a valuable tool for improving the functional attributes of walnut proteins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 106, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 853, "End Page": 861, "Article Number": null, "DOI": "10.1016/j.foodres.2018.01.060", "DOI Link": "http://dx.doi.org/10.1016/j.foodres.2018.01.060", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429893100093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KY; Wang, NN; Yin, QW; Gu, YH; Jiang, K; Tu, ZJ; Gong, CS; Uwatoko, Y; Sun, JP; Lei, HC; Hu, JP; Cheng, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, K. Y.; Wang, N. N.; Yin, Q. W.; Gu, Y. H.; Jiang, K.; Tu, Z. J.; Gong, C. S.; Uwatoko, Y.; Sun, J. P.; Lei, H. C.; Hu, J. P.; Cheng, J-G", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double Superconducting Dome and Triple Enhancement of Tc in the Kagome Superconductor CsV3Sb5 under High Pressure", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CsV3Sb5 is a newly discovered Z(2) topological kagome metal showing the coexistence of a charge-density-wave (CDW)-like order at T* = 94 K and superconductivity (SC) at T-c = 2.5 K at ambient pressure. Here, we study the interplay between CDW and SC in CsV3Sb5 via measurements of resistivity, dc and ac magnetic susceptibility under various pressures up to 6.6 GPa. We find that the CDW transition decreases with pressure and experience a subtle modification at P-c1 approximate to 0.6-0.9 GPa before it vanishes completely at P-ct2 approximate to GPa. Correspondingly, T-c(P) displays an unusual M-shaped double dome with two maxima around P-c1 and P(c2 )respectively, leading to a tripled enhancement of T-c to about 8 K at 2 GPa. The obtained temperature-pressure phase diagram resembles those of unconventional superconductors, illustrating an intimated competition between CDW-like order and SC. The competition is found to be particularly strong for the intermediate pressure range P-c1 <= P <= P-c2 as evidenced by the broad superconducting transition and reduced superconducting volume fraction. The modification of CDW order around P-c1 has been discussed based on the band structure calculations. This work not only demonstrates the potential to raise T-c of the V-based kagome superconductors, but also offers more insights into the rich physics related to the electron correlations in this novel family of topological kagomc metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2021, "Volume": 126, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 247001, "DOI": "10.1103/PhysRevLett.126.247001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.247001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663310900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jenkins, J; Mantell, J; Neal, C; Gholinia, A; Verkade, P; Nobbs, AH; Su, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jenkins, J.; Mantell, J.; Neal, C.; Gholinia, A.; Verkade, P.; Nobbs, A. H.; Su, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial effects of nullopillar surfaces are mediated by cell impedance, penetration and induction of oxidative stress", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Some insects, such as dragonflies, have evolved nulloprotrusions on their wings that rupture bacteria on contact. This has inspired the design of antibacterial implant surfaces with insect-wing mimetic nullopillars made of synthetic materials. Here, we characterise the physiological and morphological effects of mimetic titanium nullopillars on bacteria. The nullopillars induce deformation and penetration of the Gram-positive and Gram-negative bacterial cell envelope, but do not rupture or lyse bacteria. They can also inhibit bacterial cell division, and trigger production of reactive oxygen species and increased abundance of oxidative stress proteins. Our results indicate that nullopillars' antibacterial activities may be mediated by oxidative stress, and do not necessarily require bacterial lysis. Synthetic nullopillars resembling the wing surface of certain insects display antibacterial activities. Here, Jenkins et al. show that these activities do not necessarily require bacterial lysis, and may be mediated by oxidative stress induced by deformation of the bacterial cell envelope.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1626, "DOI": "10.1038/s41467-020-15471-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15471-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000525081200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZY; Duan, Y; Liu, JD; Chen, Y; Liu, XK; Liu, W; Ma, T; Li, Y; Zheng, XS; Yao, T; Gao, MR; Zhu, JF; Ye, BJ; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zi-You; Duan, Yu; Liu, Jian-Dang; Chen, Yu; Liu, Xiao-Kang; Liu, Wei; Ma, Tao; Li, Yi; Zheng, Xu-Sheng; Yao, Tao; Gao, Min-Rui; Zhu, Jun-Fa; Ye, Bang-Jiao; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional CN vacancies suppress iron-leaching in Prussian blue analogue pre-catalyst for boosted oxygen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The incorporation of defects, such as vacancies, into functional materials could substantially tailor their intrinsic properties. Progress in vacancy chemistry has enabled advances in many technological applications, but creating new type of vacancies in existing material system remains a big challenge. We show here that ionized nitrogen plasma can break bonds of iron-carbon-nitrogen-nickel units in nickel-iron Prussian blue analogues, forming unconventional carbon-nitrogen vacancies. We study oxygen evolution reaction on the carbon-nitrogen vacancy-mediated Prussian blue analogues, which exhibit a low overpotential of 283 millivolts at 10 milliamperes per square centimeter in alkali, far exceeding that of original Prussian blue analogues and previously reported oxygen evolution catalysts with vacancies. We ascribe this enhancement to the in-situ generated nickel-iron oxy(hydroxide) active layer during oxygen evolution reaction, where the Fe leaching was significantly suppressed by the unconventional carbon-nitrogen vacancies. This work opens up opportunities for producing vacancy defects in nullomaterials for broad applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2799, "DOI": "10.1038/s41467-019-10698-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10698-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472840400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Deng, YX; Shi, CY; Feringa, BL; Tian, H; Qu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qi; Deng, Yuanxin; Shi, Chen-Yu; Feringa, Ben L.; Tian, He; Qu, Da-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual closed-loop chemical recycling of synthetic polymers by intrinsically reconfigurable poly(disulfides)", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The excessive use of plastics has led to severe global problems involving environmental, energy, and health issues and demands for sustainable and recyclable alternatives. Toward circular plastics, the development of efficient chemical recycling methods without loss of properties or allowing reprocessing into new materials offer tremendous opportunities. Here, we report an intrinsically recyclable and reconfigurable poly(disulfide) polymer using a natural small molecule, thioctic acid (TA), as the feedstock Taking advantage of its dynamic covalent ring-opening polymerization, this material enables a dual closed-loop chemical recycling network among TA monomers and two kinds of polymer products, including self-healing elastomers and mechanically robust ionic films. Mild and complete depolymerization into monomers in diluted alkaline aqueous solution is achieved with yields of recovered monomers up to 86%. The polymer materials can be repeatedly recycled and reused with reconfigurable polymer composition and tunable mechanical properties offering prospects for sustainable functional plastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2021, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1352, "End Page": 1364, "Article Number": null, "DOI": "10.1016/j.matt.2021.01.014", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2021.01.014", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637800400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meza, LR; Zelhofer, AJ; Clarke, N; Mateos, AJ; Kochmann, DM; Greer, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meza, Lucas R.; Zelhofer, Alex J.; Clarke, Nigel; Mateos, Arturo J.; Kochmann, Dennis M.; Greer, Julia R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resilient 3D hierarchical architected metamaterials", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hierarchically designed structures with architectural features that span across multiple length scales are found in numerous hard biomaterials, like bone, wood, and glass sponge skeletons, as well as manmade structures, like the Eiffel Tower. It has been hypothesized that their mechanical robustness and damage tolerance stem from sophisticated ordering within the constituents, but the specific role of hierarchy remains to be fully described and understood. We apply the principles of hierarchical design to create structural metamaterials from three material systems: (i) polymer, (ii) hollow ceramic, and (iii) ceramic-polymer composites that are patterned into self-similar unit cells in a fractal-like geometry. In situ nullomechanical experiments revealed (i) a nearly theoretical scaling of structural strength and stiffness with relative density, which outperforms existing nonhierarchical nullolattices; (ii) recoverability, with hollow alumina samples recovering up to 98% of their original height after compression to >= 50% strain; (iii) suppression of brittle failure and structural instabilities in hollow ceramic hierarchical nullolattices; and (iv) a range of deformation mechanisms that can be tuned by changing the slenderness ratios of the beams. Additional levels of hierarchy beyond a second order did not increase the strength or stiffness, which suggests the existence of an optimal degree of hierarchy to amplify resilience. We developed a computational model that captures local stress distributions within the nullolattices under compression and explains some of the underlying deformation mechanisms as well as validates the measured effective stiffness to be interpreted as a metamaterial property.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 612, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2015, "Volume": 112, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11502, "End Page": 11507, "Article Number": null, "DOI": "10.1073/pnas.1509120112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1509120112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361393700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Gregorio, GL; Burdyny, T; Loiudice, A; Iyengar, P; Smith, WA; Buonsanti, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Gregorio, Gian Luca; Burdyny, Tom; Loiudice, Anna; Iyengar, Pranit; Smith, Wilson A.; Buonsanti, Raffaella", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facet-Dependent Selectivity of Cu Catalysts in Electrochemical CO2 Reduction at Commercially Viable Current Densities", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite substantial progress in the electrochemical conversion of CO2 into value-added chemicals, the translation of fundamental studies into commercially relevant conditions requires additional efforts. Here, we study the catalytic properties of tailored Cu nullocatalysts under commercially relevant current densities in a gas-fed flow cell. We demonstrate that their facet-dependent selectivity is retained in this device configuration with the advantage of further suppressing hydrogen production and increasing the faradaic efficiencies toward the CO2 reduction products compared to a conventional H-cell. The combined catalyst and system effects result in stateof-the art product selectivity at high current densities (in the range 100-300 mA/cm(2)) and at relatively low applied potential (as low as -0.65 V vs RHE). Cu cubes reach an ethylene selectivity of up to 57% with a corresponding mass activity of 700 mA/mg, and Cu octahedra reach a methane selectivity of up to 51% with a corresponding mass activity of 1.45 A/mg in 1 M KOH.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2020, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4854, "End Page": 4862, "Article Number": null, "DOI": "10.1021/acscatal.0c00297", "DOI Link": "http://dx.doi.org/10.1021/acscatal.0c00297", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530090800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, BW; Wang, XR; Li, WL; Li, C; Wang, ZS; Guo, HB; Wu, JB; Fan, KB; Zhang, CH; He, YB; Jin, BB; Chen, J; Wu, PH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Benwen; Wang, Xinru; Li, Weili; Li, Chun; Wang, Zhaosong; Guo, Hangbin; Wu, Jingbo; Fan, Kebin; Zhang, Caihong; He, Yunbin; Jin, Biaobing; Chen, Jian; Wu, Peiheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically addressable integrated intelligent terahertz metasurface", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reconfigurable intelligent surfaces (RISs) play an essential role in various applications, such as next-generation communication, uncrewed vehicles, and vital sign recognizers. However, in the terahertz (THz) region, the devel-opment of RISs is limited because of lacking tunable phase shifters and low-cost sensors. Here, we developed an integrated self-adaptive metasurface (SAM) with THz wave detection and modulation capabilities based on the phase change material. By applying various coding sequences, the metasurface could deflect THz beams over an angle range of 42.8 degrees. We established a software-defined sensing reaction system for intelligent THz wave manip-ulation. In the system, the SAM self-adaptively adjusted the THz beam deflection angle and stabilized the reflected power in response to the detected signal without human intervention, showing vast potential in eliminating coverage dead zones and other applications in THz communication. Our programmable controlled SAM creates a platform for intelligent electromagnetic information processing in the THz regime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2022, "Volume": 8, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadd1296", "DOI": "10.1126/sciadv.add1296", "DOI Link": "http://dx.doi.org/10.1126/sciadv.add1296", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000882137600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Loebel, C; Mauck, RL; Burdick, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Loebel, Claudia; Mauck, Robert L.; Burdick, Jason A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Local nascent protein deposition and remodelling guide mesenchymal stromal cell mechanosensing and fate in three-dimensional hydrogels", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels serve as valuable tools for studying cell-extracellular matrix interactions in three-dimensional environments that recapitulate aspects of native extracellular matrix. However, the impact of early protein deposition on cell behaviour within hydrogels has largely been overlooked. Using a bio-orthogonal labelling technique, we visualized nascent proteins within a day of culture across a range of hydrogels. In two engineered hydrogels of interest in three-dimensional mechanobiology studies-proteolytically degradable covalently crosslinked hyaluronic acid and dynamic viscoelastic hyaluronic acid hydrogels-mesenchymal stromal cell spreading, YAP/TAZ nuclear translocation and osteogenic differentiation were observed with culture. However, inhibition of cellular adhesion to nascent proteins or reduction in nascent protein remodelling reduced mesenchymal stromal cell spreading and nuclear translocation of YAP/TAZ, resulting in a shift towards adipogenic differentiation. Our findings emphasize the role of nascent proteins in the cellular perception of engineered materials and have implications for in vitro cell signalling studies and application to tissue repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 18, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 883, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-019-0307-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-019-0307-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476651600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Winne, JM; Leibler, L; Du Prez, FE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Winne, Johan M.; Leibler, Ludwik; Du Prez, Filip E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic covalent chemistry in polymer networks: a mechanistic perspective", "Source Title": "POLYMER CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The incorporation of dynamic covalent linkages within and between polymer chains brings new properties to classical thermosetting polymer formulations, in particular in terms of thermal responses, processing options and intrinsic recycling abilities. Thus, in recent years, there has been a rapidly growing interest in the design and synthesis of monomers and cross-linkers that can be used as robust but at the same time reactive organic building blocks for dynamic polymer networks. In this perspective, a selection of such chemistries is highlighted, with a particular focus on the reaction mechanisms of molecular network rearrangements, and on how various mechanistic profiles can be related to the mechanical and physicochemical properties of polymer materials, in particular in relation with vitrimers, the recently defined third category of polymer materials. The recent advances in this area are not only expected to help direct promising emerging polymer applications, but also point towards the need for a better fundamental understanding of chemical reactivity within a macromolecular context.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 475, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2019, "Volume": 10, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6091, "End Page": 6108, "Article Number": null, "DOI": "10.1039/c9py01260e", "DOI Link": "http://dx.doi.org/10.1039/c9py01260e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498229100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, YH; Wof, C; Kim, YT; Cho, H; Kwon, W; Do, S; Sadhanala, A; Park, CG; Rhee, SW; Im, SH; Friend, RH; Leet, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Young-Hoon; Wof, Christoph; Kim, Young-Tae; Cho, Himchan; Kwon, Woosung; Do, Sungan; Sadhanala, Aditya; Park, Chan Gyung; Rhee, Shi-Woo; Im, Sang Hyuk; Friend, Richard H.; Leet, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Light-Emitting Diodes of Colloidal Metal-Halide Perovskite nullocrystals beyond Quantum Size", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal metal-halide perovskite quantum dots (QDs) with a dimension less than the exciton Bohr diameter D-B (quantum size regime) emerged as promising light emitters due to their spectrally narrow light, facile color tuning, and high photoluminescence quantum efficiency (PLQE). However, their size-sensitive emission wavelength and color purity and low electroluminescence efficiency are still challenging aspects. Here, we demonstrate highly efficient light-emitting diodes (LEDs) based on the colloidal perovskite nullo crystals (NCs) in a dimension > D-B (regime beyond quantum size) by using a multifunctional buffer hole injection layer (Buf-HIL). The perovskite NCs with a dimension greater than D-B show a size-irrespective high color purity and PLQE by managing the recombination of excitons occurring at surface traps and inside the NCs. The Buf-HIL composed of poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS) and per fluorinated ionomer induces uniform perovskite particle films with complete film coverage and prevents exciton quenching at the PEDOT:PSS/perovskite particle film interface. With these strategies, we achieved a very high PLQE (similar to 60.5%) in compact perovskite particle films without any complex post-treatments and multilayers and a high current efficiency of 15.5 cd/A in the LEDs of colloidal perovskite NCs, even in a simplified structure, which is the highest efficiency to date in green LEDs that use colloidal organic-inorganic metal-halide perovskite nulloparticles including perovskite QDs and NCs. These results can help to guide development of various light-emitting optoelectronic applications based on perovskite NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6586, "End Page": 6593, "Article Number": null, "DOI": "10.1021/acsnullo.6b07617", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b07617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406649700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Snyder, GJ; Snyder, AH; Wood, M; Gurunathan, R; Snyder, BH; Niu, CN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Snyder, G. Jeffrey; Snyder, Alemayouh H.; Wood, Maxwell; Gurunathan, Ramya; Snyder, Berhanu H.; Niu, Changning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weighted Mobility", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering semiconductor devices requires an understanding of charge carrier mobility. Typically, mobilities are estimated using Hall effect and electrical resistivity meausrements, which are are routinely performed at room temperature and below, in materials with mobilities greater than 1 cm(2) V-1 s(-1). With the availability of combined Seebeck coefficient and electrical resistivity measurement systems, it is now easy to measure the weighted mobility (electron mobility weighted by the density of electronic states). A simple method to calculate the weighted mobility from Seebeck coefficient and electrical resistivity measurements is introduced, which gives good results at room temperature and above, and for mobilities as low as 10(-3) cm(2) V-1 s(-1), mu w=331cm2Vs(m omega cm rho) (T300 K)-3/2[ exp[ |S|kB/e-2]1+exp[-5(|S|kB/e-1) ]+3 pi 2|S|kB/e1+exp[5(|S|kB/e-1) ] ]Here, mu(w) is the weighted mobility, rho is the electrical resistivity measured in m omega cm, T is the absolute temperature in K, S is the Seebeck coefficient, and k(B)/e = 86.3 mu V K-1. Weighted mobility analysis can elucidate the electronic structure and scattering mechanisms in materials and is particularly helpful in understanding and optimizing thermoelectric systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 656, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 32, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001537, "DOI": "10.1002/adma.202001537", "DOI Link": "http://dx.doi.org/10.1002/adma.202001537", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000532658500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, WY; Yang, ZJ; Sharma, R; Zhang, C; Withers, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Wenyuan; Yang, Zhenjun; Sharma, Rajneesh; Zhang, Ch; Withers, Philip J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional X-ray CT image based meso-scale fracture modelling of concrete", "Source Title": "ENGINEERING FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional meso-scale finite element models with realistic aggregates, cement paste and voids of concrete are developed using microscale X-ray Computed Tomography images. Cohesive elements with traction-separation laws are pre-embedded within cement paste and aggregate-cement interfaces to simulate complex nonlinear fracture. Tension tests using a large number of images were simulated with statistical analysis. The very different load-carrying capacities and crack patterns demonstrate the effects of random distribution of phases. It is found that the tensile strength decreases as the void fraction increases, and the relative strength of cement paste and interfaces dominates the microcracking behaviour, which in turn affects macrocracking and load-carrying capacity. (C) 2014 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 133, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24, "End Page": 39, "Article Number": null, "DOI": "10.1016/j.engfracmech.2014.10.016", "DOI Link": "http://dx.doi.org/10.1016/j.engfracmech.2014.10.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348580000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, Y; Yang, FF; Zhao, HM; Gao, Q; Xia, B; Fu, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yong; Yang, FeiFei; Zhao, HaiMing; Gao, Qing; Xia, Bing; Fu, JianZhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research on the printability of hydrogels in 3D bioprinting", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the biocompatible materials, hydrogels have been widely used in three-dimensional (3D) bioprinting/organ printing to load cell for tissue engineering. It is important to precisely control hydrogels deposition during printing the mimic organ structures. However, the printability of hydrogels about printing parameters is seldom addressed. In this paper, we systemically investigated the printability of hydrogels from printing lines (one dimensional, 1D structures) to printing lattices/films (two dimensional, 2D structures) and printing 3D structures with a special attention to the accurate printing. After a series of experiments, we discovered the relationships between the important factors such as air pressure, feedrate, or even printing distance and the printing quality of the expected structures. Dumbbell shape was observed in the lattice structures printing due to the hydrogel diffuses at the intersection. Collapses and fusion of adjacent layer would result in the error accumulation at Z direction which was an important fact that could cause printing failure. Finally, we successfully demonstrated a 3D printing hydrogel scaffold through harmonize with all the parameters. The cell viability after printing was compared with the casting and the results showed that our bioprinting method almost had no extra damage to the cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 481, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29977, "DOI": "10.1038/srep29977", "DOI Link": "http://dx.doi.org/10.1038/srep29977", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380056100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sagara, Y; Karman, M; Verde-Sesto, E; Matsuo, K; Kim, Y; Tamaoki, N; Weder, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sagara, Yoshimitsu; Karman, Marc; Verde-Sesto, Ester; Matsuo, Kazuya; Kim, Yuna; Tamaoki, Nobuyuki; Weder, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rotaxanes as Mechanochromic Fluorescent Force Transducers in Polymers", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of mechanophores, motifs that transduce mechanical forces into chemical reactions, allows creating materials with stress-dependent properties. Typical mechanophores are activated by cleaving weak covalent bonds, but these reactions can also be triggered by other stimuli, and this renders the behavior unspecific. Here we show that this problem can be overcome by extending the molecular-shuttle function of rotaxanes to mechanical activation. A mechanically interlocked mecha-nophore composed of a fluorophore-carrying macrocycle and a dumbbell-shaped molecule containing a matching quencher was integrated into a polyurethane elastomer. Deformation of this polymer causes a fluorescence turn on, due to the spatial separation of fluorophore and quencher. This process is specific, efficient, instantly reversible, and elicits an easily detectable optical signal that correlates with the applied force.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2018, "Volume": 140, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1584, "End Page": 1587, "Article Number": null, "DOI": "10.1021/jacs.7b12405", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b12405", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424851500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, L; Goh, K; Wang, Y; Lee, J; Huang, YJ; Karahan, HE; Zhou, K; Guiver, MD; Bae, TH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Lina; Goh, Kunli; Wang, Yu; Lee, Jaewoo; Huang, Yinjuan; Karahan, H. Enis; Zhou, Kun; Guiver, Michael D.; Bae, Tae-Hyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing small-flake graphene oxide membranes for ultrafast size-dependent organic solvent nullofiltration", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membranes for organic solvent nullofiltration (OSN) or solvent-resistant nullofiltration (SRNF) offer unprecedented opportunities for highly efficient and cost-competitive solvent recovery in the pharmaceutical industry. Here, we describe small-flake graphene oxide (SFGO) membranes for high-performance OSN applications. Our strategy exploits lateral dimension control to engineer shorter and less tortuous transport pathways for solvent molecules. By using La(3+ )as a cross-linker and spacer for intercalation, the SFGO membrane selective layer was stabilized, and size-dependent ultrafast selective molecular transport was achieved. The methanol permeance was up to 2.9-fold higher than its large-flake GO (LFGO) counterpart, with high selectivity toward three organic dyes. More importantly, the SFGO-La3+ membrane demonstrated robust stability for at least 24 hours under hydrodynamic stresses that are representative of realistic OSN operating conditions. These desirable attributes stem from the La3+ cross-linking, which forms uniquely strong coordination bonds with oxygen-containing functional groups of SFGO. Other cations were found to be ineffective.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz9184", "DOI": "10.1126/sciadv.aaz9184", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz9184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530628100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bertsch, KM; de Bellefon, GM; Kuehl, B; Thoma, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bertsch, K. M.; de Bellefon, G. Meric; Kuehl, B.; Thoma, D. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of dislocation structures in an additively manufactured austenitic stainless steel 316L", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this experiment, the origin of dislocation structures in AM stainless steels was systematically investigated by controlling the effect of thermal stress through geometric constraints for the first time. Stainless steel 316L parts were produced in the form of 1D rods, 2D walls, and 3D rectangular prisms to evaluate the effect of constraints to thermal expansion/shrinkage on the development of defect microstructures and to elucidate the origin of additively manufactured (AM) dislocation microstructures. Dislocation density, organization, chemical micro-segregation, precipitate structures, and misorientations were analyzed as a function of increasing constraints around solidifying material in 1D, 2D, and 3D components built using both directed energy deposition (DED) and powder-bed selective laser melting (SLM). In DED parts, the dislocation density was not dependent on local misorientations or micro-segregation patterns, but evolved from approximately rho(perpendicular to)approximate to 10(12) m(-)(2) in 1D parts to rho(perpendicular to) approximate to 10(14) m(-2) in 3D parts, indicating that it is primarily thermal distortions that produce AM dislocation structures. In DED 3D parts and SLM parts, dislocation densities were highest (rho(perpendicular to) approximate to 10(14) m(-2)) and corresponded to the formation of dislocation cells approximately 300-450 nm in diameter. Dislocation cells overlapped with dendrite micro-segregation in some but not all cases. The results illustrate that dendritic micro-segregation, precipitates, or local misorientations influence how the dislocations organize during processing, but are not responsible for producing the organized cell structures. This work shows that AM dislocation structures originate due to thermal distortions during printing, which are primarily dictated by constraints surrounding the melt pool and thermal cycling. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 497, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2020, "Volume": 199, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19, "End Page": 33, "Article Number": null, "DOI": "10.1016/j.actamat.2020.07.063", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.07.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577994500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Z; Wang, XG; Zhang, X; Xie, ZJ; Chen, YN; Ma, LP; Peng, ZQ; Zhou, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhang; Wang, Xin-Gai; Zhang, Xu; Xie, Zhaojun; Chen, Ya-null; Ma, Lipo; Peng, Zhangquan; Zhou, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Verifying the Rechargeability of Li-CO2 Batteries on Working Cathodes of Ni nulloparticles Highly Dispersed on N-Doped Graphene", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-CO2 batteries could skillfully combine the reduction of greenhouse effect with energy storage systems. However, Li-CO2 batteries still suffer from unsatisfactory electrochemical performances and their rechargeability is challenged. Here, it is reported that a composite of Ni nulloparticles highly dispersed on N-doped graphene (Ni-NG) with 3D porous structure, exhibits a superior discharge capacity of 17 625 mA h g(-1), as the air cathode for Li-CO2 batteries. The batteries with these highly efficient cathodes could sustain 100 cycles at a cutoff capacity of 1000 mA h g(-1) with low overpotentials at the current density of 100 mA g(-1). Particularly, the Ni-NG cathodes allow to observe the appearance/disappearance of agglomerated Li2CO3 particles and carbon thin films directly upon discharge/charge processes. In addition, the recycle of CO2 is detected through in situ differential electrochemical mass spectrometry. This is a critical step to verify the electrochemical rechargeability of Li-CO2 batteries. Also, first-principles computations further prove that Ni nulloparticles are active sites for the reaction of Li and CO2, which could guide to design more advantageous catalysts for rechargeable Li-CO2 batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700567, "DOI": "10.1002/advs.201700567", "DOI Link": "http://dx.doi.org/10.1002/advs.201700567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426200000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kong, Y; Ao, X; Huang, X; Bai, JL; Zhao, SQ; Zhang, JY; Tian, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kong, Yang; Ao, Xin; Huang, Xiao; Bai, Jinglong; Zhao, Shangquan; Zhang, Jinyong; Tian, Bingbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni-CeO2 Heterostructures in Li-S Batteries: A Balancing Act between Adsorption and Catalytic Conversion of Polysulfide", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries have attracted considerable attention over the last two decades because of a high energy density and low cost. However, the wide application of Li-S batteries has been severely impeded due to the poor electrical conductivity of S, shuttling effect of soluble lithium polysulfides (LiPSs), and sluggish redox kinetics of S species, especially under high S loading. To address all these issues, a Ni-CeO2 heterostructure-doped carbon nullofiber (Ni-CeO2-CNF) is developed as an S host that combines the strong adsorption with the high catalytic activity and the good electrical conductivity, where the LiPSs anchored on the heterostructure surface can directly gain electrons from the current collector and realize a fast conversion between S-8 and Li2S. Therefore, Li-S batteries with S@Ni-CeO2-CNF cathodes exhibit superior long-term cycling stability, with a capacity decay of 0.046% per cycle over 1000 cycles, even at 2 C. Noteworthy, under a sulfur loading up to 6 mg cm(-2), a high reversible areal capacity of 5.3 mAh cm(-2) can be achieved after 50 cycles at 0.1 C. The heterostructure-modified S cathode effectively reconciles the thermodynamic and kinetic characteristics of LiPSs for adsorption and conversion, furthering the development of high-performance Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 9, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105538, "DOI": "10.1002/advs.202105538", "DOI Link": "http://dx.doi.org/10.1002/advs.202105538", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781680500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rehman, SRU; Augustine, R; Zahid, AA; Ahmed, R; Tariq, M; Hasan, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rehman, Syed Raza Ur; Augustine, Robin; Zahid, Alap Ali; Ahmed, Rashid; Tariq, Muhammad; Hasan, Anwarul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced Graphene Oxide Incorporated GelMA Hydrogel Promotes Angiogenesis For Wound Healing Applications", "Source Title": "INTERNATIONAL JOURNAL OF nullOMEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Purpose: Non-healing or slow healing chronic wounds are among serious complications of diabetes that eventually result in amputation of limbs and increased morbidities and mortalities. Chronic diabetic wounds show reduced blood vessel formation (lack of angiogenesis), inadequate cell proliferation and poor cell migration near wounds. In this paper, we report the development of a hydrogel-based novel wound dressing material loaded with reduced graphene oxide (rGO) to promote cell proliferation, cell migration and angiogenesis for wound healing applications. Methods: Gelatin-methacryloyl (GelMA) based hydrogels loaded with different concentrations of rGO were fabricated by UV crosslinking. Morphological and physical characterizations (porosity, degradation, and swelling) of rGO incorporated GelMA hydrogel was performed. In vitro cell proliferation, cell viability and cell migration potential of the hydrogels were analyzed by MTT assay, live/dead staining, and wound healing scratch assay respectively. Finally, in vivo chicken embryo angiogenesis (CEO) testing was performed to evaluate the angiogenic potential of the prepared hydrogel. Results: The experimental results showed that the developed hydrogel possessed enough porosity and exudate-absorbing capacity. The biocompatibility of prepared hydrogel on three different cell lines (3T3 fibroblasts, EA.hy926 endothelial cells, and HaCaT keratinocytes) was confirmed by in vitro cell culture studies (live/dead assay). The GelMA hydrogel containing 0.002% w/w rGO considerably increased the proliferation and migration of cells as evident from MTT assay and wound healing scratch assay. Furthermore, rGO impregnated GelMA hydrogel significantly enhanced the angiogenesis in the chick embryo model. Conclusion: The positive effect of 0.002% w/w rGO impregnated GelMA hydrogels on angiogenesis, cell migration and cell proliferation suggests that these formulations could be used as a functional wound healing material for the healing of chronic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": 14, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9603, "End Page": 9617, "Article Number": null, "DOI": "10.2147/IJN.S218120", "DOI Link": "http://dx.doi.org/10.2147/IJN.S218120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500795400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, L; Lv, SS; Xiang, WC; Huan, SQ; McClements, DJL; Rojas, OJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Long; Lv, Shanshan; Xiang, Wenchao; Huan, Siqi; McClements, David Julian; Rojas, Orlando J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oil-in-water Pickering emulsions via microfluidization with cellulose nullocrystals: 1. Formation and stability", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oil-in-water Pickering emulsions were successfully prepared via high-energy microfluidization using cellulose nullocrystals (CNC) as interfacial stabilizers. The influence of microfluidization pressure, CNC concentration, and oil type on droplet size and emulsion stability was determined. Under optimized homogenization conditions, CNC formed and stabilized emulsions based on corn, fish, sunflower, flax, orange, and MCT oils. The droplet size decreased with increasing microfluidization pressure from 9 to 17 kpsi, but then increased slightly at 19 kpsi. The creaming stability of the emulsions increased with CNC concentration, which was mainly attributed to the decrease in droplet size (mean particle diameter < 1 mu m at CNC-to-oil ratios greater than 1:10) and slightly increased viscosity. The Pickering emulsions were stable to droplet coalescence, presumably due to strong electrostatic and steric repulsions between the lipid droplets carrying adsorbed nulloparticles. The Pickering emulsions had good stability over a range of environmental stresses: pH 3 to 10; NaCl < 100 mM; temperature from 30 to 90 degrees C. Droplet flocculation was, however, observed under more acidic conditions (pH 2) and at high ionic strength (200-500 mM NaCl), owing to electrostatic screening. Our results indicate that microfluidization is an effective method for forming CNC-stabilized Pickering emulsions suitable for utilization in the food industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 699, "End Page": 708, "Article Number": null, "DOI": "10.1016/j.foodhyd.2019.04.038", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2019.04.038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474521200073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SY; Ladani, RB; Zhang, J; Bafekrpour, E; Ghorbani, K; Mouritz, AP; Kinloch, AJ; Wang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuying; Ladani, Raj B.; Zhang, Jin; Bafekrpour, Ehsan; Ghorbani, Kamran; Mouritz, Adrian P.; Kinloch, Anthony J.; Wang, Chun H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aligning multilayer graphene flakes with an external electric field to improve multifunctional properties of epoxy nullocomposites", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increasing demand for multifunctional polymer nullocomposites calls for new technologies to simultaneously enhance mechanical, electrical, and thermal properties. This paper presents the use of an alternating-current electric field to align graphene nulloplatelets (GnPs) in an epoxy polymer. Theoretical modeling of the alignment process has identified the key parameters that control the rotation and chain-formation of the GnPs. Experimental results reveal that the resulting nullocomposites exhibit anisotropic properties with significantly improved electrical and thermal conductivities in the alignment direction, and dramatically increased fracture toughness when the GnPs are aligned transverse to the crack growth direction. In particular, compared to the unmodified epoxy polymer, the alignment of the GnPs yields up to about 7-8 orders of magnitude improvement in the electrical conductivity, up to approximately 60% increase in the thermal conductivity, and up to a nearly 900% increase in the mode I fracture toughness. The dramatic improvement in the fracture toughness is attributed to multiple intrinsic and extrinsic toughening mechanisms including microcracking, pinning, deflection and branching of the crack, and rupture and pull-out of the GnPs. Such major improvement in the toughness arises from GnPs being transversely aligned to the crack growth direction exhibiting increased interactions with the advancing crack tip. (C) 2015 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 94, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 607, "End Page": 618, "Article Number": null, "DOI": "10.1016/j.carbon.2015.07.026", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2015.07.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360294900075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XJ; Wu, CC; Jha, SK; Li, Z; Zhu, K; Priya, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaojia; Wu, Congcong; Jha, Shikhar K.; Li, Zhen; Zhu, Kai; Priya, Shashank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved Phase Stability of Formamidinium Lead Triiodide Perovskite by Strain Relaxation", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though formamidinium lead triiodide (FAPbI(3)) possesses a suitable band gap and good thermal stability, the phase transition from the pure black perovskite phase (alpha-phase) to the undesirable yellow nonperovskite polymorph (delta-phase) at room temperature, especially under humid air, hinders its practical application. Here, we investigate the intrinsic instability mechanism of the alpha-phase at ambient temperature and demonstrate the existence of an anisotropic strained lattice in the (111) plane that drives phase transformation into the delta-phase. Methylammonium bromide (MABr) alloying (or FAPbI(3)-MABr) was found to cause lattice contraction, thereby balancing the lattice strain. This led to dramatic improvement in the stability of alpha-FAPbI3. Solar cells fabricated using FAPbI(3)-MABr demonstrated significantly enhanced stability under the humid air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 1, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1014, "End Page": 1020, "Article Number": null, "DOI": "10.1021/acsenergylett.6b00457", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.6b00457", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390085700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, C; Liu, JQ; Guo, J; Chang, L; Wang, RN; Weng, WL; Peters, J; Xie, WQ; Zhang, ZY; Riemensberger, J; Selvidge, J; Kippenberg, TJ; Bowers, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Chao; Liu, Junqiu; Guo, Joel; Chang, Lin; Wang, Rui Ning; Weng, Wenle; Peters, Jonathan; Xie, Weiqiang; Zhang, Zeyu; Riemensberger, Johann; Selvidge, Jennifer; Kippenberg, Tobias J.; Bowers, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Laser soliton microcombs heterogeneously integrated on silicon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon photonics enables wafer-scale integration of optical functionalities on chip. Silicon-based laser frequency combs can provide integrated sources of mutually coherent laser lines for terabit-per-second transceivers, parallel coherent light detection and ranging, or photonics-assisted signal processing. We report heterogeneously integrated laser soliton microcombs combining both indium phospide/silicon (InP/Si) semiconductor lasers and ultralow-loss silicon nitride (Si3N4) microresonators on a monolithic silicon substrate. Thousands of devices can be produced from a single wafer by using complementary metal-oxide-semiconductor-compatible techniques. With on-chip electrical control of the laser-microresonator relative optical phase, these devices can output single-soliton microcombs with a 100-gigahertz repetition rate. Furthermore, we observe laser frequency noise reduction due to self-injection locking of the InP/Si laser to the Si3N4 microresonator. Our approach provides a route for large-volume, low-cost manufacturing of narrow-linewidth, chip-based frequency combs for next-generation high-capacity transceivers, data centers, space and mobile platforms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2021, "Volume": 373, "Issue": 6550, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 99, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh2076", "DOI Link": "http://dx.doi.org/10.1126/science.abh2076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677843100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Håkansson, KMO; Fall, AB; Lundell, F; Yu, S; Krywka, C; Roth, SV; Santoro, G; Kvick, M; Wittberg, LP; Wågberg, L; Söderberg, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hakansson, Karl M. O.; Fall, Andreas B.; Lundell, Fredrik; Yu, Shun; Krywka, Christina; Roth, Stephan V.; Santoro, Gonzalo; Kvick, Mathias; Wittberg, Lisa Prahl; Wagberg, Lars; Soderberg, L. Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrodynamic alignment and assembly of nullofibrils resulting in strong cellulose filaments", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cellulose nullofibrils can be obtained from trees and have considerable potential as a building block for biobased materials. In order to achieve good properties of these materials, the nullostructure must be controlled. Here we present a process combining hydrodynamic alignment with a dispersion-gel transition that produces homogeneous and smooth filaments from a low-concentration dispersion of cellulose nullofibrils in water. The preferential fibril orientation along the filament direction can be controlled by the process parameters. The specific ultimate strength is considerably higher than previously reported filaments made of cellulose nullofibrils. The strength is even in line with the strongest cellulose pulp fibres extracted from wood with the same degree of fibril alignment. Successful nulloscale alignment before gelation demands a proper separation of the timescales involved. Somewhat surprisingly, the device must not be too small if this is to be achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4018, "DOI": "10.1038/ncomms5018", "DOI Link": "http://dx.doi.org/10.1038/ncomms5018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338836700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HX; Thiaville, A; Rohart, S; Fert, A; Chshiev, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hongxin; Thiaville, Andre; Rohart, Stanislas; Fert, Albert; Chshiev, Mairbek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anatomy of Dzyaloshinskii-Moriya Interaction at Co/Pt Interfaces", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Dzyaloshinskii-Moriya interaction (DMI) has been recently recognized to play a crucial role in allowing fast domain wall dynamics driven by spin-orbit torques and the generation of magnetic Skyrmions. Here, we unveil the main features and microscopic mechanisms of DMI in Co/Pt bilayers via first principles calculations. We find that the large DMI of the bilayers has a dominullt contribution from the spins of the interfacial Co layer. This DMI between the interfacical Co spins extends very weakly away from the interface and is associated with a spin-orbit coupling in the adjacent atomic layer of Pt. Furthermore, no direct correlation is found between DMI and proximity induced magnetism in Pt. These results clarify the underlying mechanisms of DMI at interfaces between ferromagnetic and heavy metals and should help optimizing material combinations for domain wall and Skyrmion-based devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 562, "Times Cited, All Databases": 598, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2015, "Volume": 115, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 267210, "DOI": "10.1103/PhysRevLett.115.267210", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.267210", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367385200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SH; Geng, SZ; Li, L; Zhang, Y; Ren, GM; Huang, BL; Hu, ZW; Lee, JF; Lai, YH; Chu, YH; Xu, Y; Shao, Q; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shangheng; Geng, Shize; Li, Ling; Zhang, Ying; Ren, Guomian; Huang, Bolong; Hu, Zhiwei; Lee, Jyh-Fu; Lai, Yu-Hong; Chu, Ying-Hao; Xu, Yong; Shao, Qi; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A top-down strategy for amorphization of hydroxyl compounds for electrocatalytic oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A versatile top-down strategy has been shown to produce amorphous oxides through amorphization of corresponding hydroxides. This approach was used to generate various unitary, binary and ternary amorphous oxides for electrocatalytic oxygen evolution. Amorphous materials have attracted increasing attention in diverse fields due to their unique properties, yet their controllable fabrications still remain great challenges. Here, we demonstrate a top-down strategy for the fabrications of amorphous oxides through the amorphization of hydroxides. The versatility of this strategy has been validated by the amorphizations of unitary, binary and ternary hydroxides. Detailed characterizations indicate that the amorphization process is realized by the variation of coordination environment during thermal treatment, where the M-OH octahedral structure in hydroxides evolves to M-O tetrahedral structure in amorphous oxides with the disappearance of the M-M coordination. The optimal amorphous oxide (FeCoSn(OH)(6)-300) exhibits superior oxygen evolution reaction (OER) activity in alkaline media, where the turnover frequency (TOF) value is 39.4 times higher than that of FeCoSn(OH)(6). Moreover, the enhanced OER performance and the amorphization process are investigated with density functional theory (DFT) and molecule dynamics (MD) simulations. The reported top-down fabrication strategy for fabricating amorphous oxides, may further promote fundamental research into and practical applications of amorphous materials for catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1187, "DOI": "10.1038/s41467-022-28888-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28888-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764895600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, X; Li, Y; Li, TJ; Li, YC; Deng, YR; Xie, X; Wang, Y; Li, G; Bian, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Xin; Li, Yuan; Li, Tianjie; Li, Yucong; Deng, Yingrui; Xie, Xian; Wang, Yi; Li, Gang; Bian, Liming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coacervate-Derived Hydrogel with Effective Water Repulsion and Robust Underwater Bioadhesion Promotes Wound Healing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving robust underwater adhesion by bioadhesives remains a challenge due to interfacial water. Herein a coacervate-to-hydrogel strategy to enhance interfacial water repulsion and bulk adhesion of bioadhesives is reported. The polyethyleneimine/thioctic acid (PEI/TA) coacervate is deposited onto underwater substrates, which can effectively repel interfacial water and completely spread into substrate surface irregularities due to its liquid and water-immiscible nature. The physical interactions between coacervate and substrate can further enhance interfacial adhesion. Furthermore, driven by the spontaneous hydrophobic aggregation of TA molecules and strong electrostatic interaction between PEI and TA, the coacervate can turn into a hydrogel in situ within minutes without additional stimuli to develop enhanced matrix cohesion and robust bulk adhesion on diverse underwater substrates. Molecular dynamics simulations further reveal atomistic details of the formation and wet adhesion of the PEI/TA coacervate via multimode physical interactions. Lastly, it is demonstrated that the PEI/TA coacervate-derived hydrogel can effectively repel blood and therefore efficiently deliver the carried growth factors at wound sites, thereby enhancing wound healing in an animal model. The advantages of the PEI/TA coacervate-derived hydrogel including body fluid-immiscibility, strong underwater adhesion, adaptability to fit irregular target sites, and excellent biocompatibility make it a promising bioadhesive for diverse biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 9, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203890, "DOI": "10.1002/advs.202203890", "DOI Link": "http://dx.doi.org/10.1002/advs.202203890", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853957400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Y; Zhang, H; Wang, YD; Zhu, XR; Xiao, WP; Xu, HL; Li, GR; Li, YF; Fan, DQ; Zeng, HB; Chen, ZP; Yang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yi; Zhang, Hao; Wang, Yida; Zhu, Xiaorong; Xiao, Weiping; Xu, Haolan; Li, Gaoran; Li, Yafei; Fan, Deqi; Zeng, Haibo; Chen, Zupeng; Yang, Xiaofei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar-Driven Interfacial Evaporation Accelerated Electrocatalytic Water Splitting on 2D Perovskite Oxide/MXene Heterostructure", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of economic and high-performance electrocatalytic water-splitting systems is of great significance for energy and environmental sustainability. Developing a sustainable energy conversion-assisted electrocatalytic process provides a promising novel approach to effectively boost its performance. Herein, a self-sustained water-splitting system originated from the heterostructure of perovskite oxide with 2D Ti3C2Tx MXene on Ni foam (La1-xSrxCoO3/Ti3C2Tx MXene/Ni) that shows high activity for solar-powered water evaporation and simultaneous electrocatalytic water splitting is presented. The all-in-one interfacial electrocatalyst exhibits highly improved oxygen evolution reaction (OER) performance with a low overpotential of 279 mV at 10 mA cm(-2) and a small Tafel slope of 74.3 mV dec(-1), superior to previously reported perovskite oxide-based electrocatalysts. Density functional theory calculations reveal that the integration of La0.9Sr0.1CoO3 with Ti3C2Tx MXene can lower the energy barrier for the electron transfer and decrease the OER overpotential, while COMSOL simulations unveil that interfacial solar evaporation could induce OH- enrichment near the catalyst surfaces and enhance the convection flow above the catalysts to remove the generated gas, remarkably accelerating the kinetics of electrocatalytic water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 33, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202215061", "DOI Link": "http://dx.doi.org/10.1002/adfm.202215061", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000945695900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, R; Joanni, E; Sahoo, S; Shim, JJ; Matsuda, A; Tan, WK; Singh, RK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Rajesh; Joanni, Ednull; Sahoo, Sumanta; Shim, Jae-Jin; Matsuda, Atsunori; Tan, Wai Kian; Singh, Rajesh K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An overview of recent progress in nullostructured carbon-based supercapacitor electrodes: From zero to bi-dimensional materials", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lack of higher performance energy storage has been widely acknowledged as a major factor hindering further developments in transportation, portable and wearable electronic devices, among other key applications. Although supercapacitors (SCs) have been known for more than fifty years, only recently these devices have been considered as promising candidates to fulfil this significant technology gap. Developments in nullotechnology and manufacturing techniques applied to high-performance advanced electrode materials have accelerated progress in this fast-moving field. In this comprehensive overview article, we systematically survey the current state of art on fabrication and the corresponding electrochemical performance of electrode materials for SCs. The text covers novel carbon nullomaterials having different dimensions, such as 0D-carbon quantum dots, 1D-carbon nullostructures (carbon nullotubes, carbon nullofibers, carbon nullo yarns and their composites) as well as 2D-carbon materials (graphene, doped-graphene, graphene derivatives and their composites). Emerging fabrication technologies are also addressed, including conventional SCs, as well as asymmetric, flexible, micro, stretchable and wearable devices. Additionally, the drawbacks for each class of electrode material, the major challenges facing the current technologies, and some of the promising research directions in this field have also been discussed. (c) 2022 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2022, "Volume": 193, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 298, "End Page": 338, "Article Number": null, "DOI": "10.1016/j.carbon.2022.03.023", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2022.03.023", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800496400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Matlack, KH; Bauhofer, A; Krödel, S; Palermo, A; Daraio, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Matlack, Kathryn H.; Bauhofer, Anton; Krodel, Sebastian; Palermo, Antonio; Daraio, Chiara", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Composite 3D-printed metastructures for low-frequency and broadband vibration absorption", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Architected materials that control elastic wave propagation are essential in vibration mitigation and sound attenuation. Phononic crystals and acoustic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a material. However, existing solutions are limited in the low-frequency regimes and in their bandwidth of operation because they require impractical sizes and masses. Here, we present a class of materials (labeled elastic metastructures) that supports the formation of wide and low- frequency band gaps, while simultaneously reducing their global mass. To achieve these properties, the metastructures combine local resonullces with structural modes of a periodic architected lattice. Whereas the band gaps in these metastructures are induced by Bragg scattering mechanisms, their key feature is that the band-gap size and frequency range can be controlled and broadened through local resonullces, which are linked to changes in the lattice geometry. We demonstrate these principles experimentally, using advanced additive manufacturing methods, and inform our designs using finite-element simulations. This design strategy has a broad range of applications, including control of structural vibrations, noise, and shock mitigation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2016, "Volume": 113, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8386, "End Page": 8390, "Article Number": null, "DOI": "10.1073/pnas.1600171113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1600171113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380346200035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XQ; Min, XZ; Li, JL; Xu, N; Zhu, PC; Bin Zhu, B; Zhu, SN; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiuqiang; Min, Xinzhe; Li, Jinlei; Xu, Ning; Zhu, Pengchen; Zhu, Bin; Zhu, Shining; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Storage and Recycling of Interfacial Solar Steam Enthalpy", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, it is shown that by storing and recycling steam enthalpy derived from the solar steam process, we can enable simultaneous generation of clean water and electricity. Energy-transfer efficiency of solar to steam can reach 72.2% with extra electricity power (with 1.23% efficiency) generated simultaneously. With advanced thermal management to further elevate the working temperature and exciting progress in the fields of thermoelectrics and desalination, it is expected that the performance of this system can be further improved. This approach with scalable materials and processes, high energy-transfer efficiency, and integrated storage capability will provide an attractive avenue to produce electricity and clean water in an individualized manner, particularly desirable in various off-grid areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2018, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2477, "End Page": 2484, "Article Number": null, "DOI": "10.1016/j.joule.2018.08.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.08.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450940600025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, ZW; Liu, Z; Lu, SY; Wang, LR; Feng, XL; Yang, DW; Wang, K; Xiao, GJ; Zhang, LJ; Redfern, SAT; Zou, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Zhiwei; Liu, Zhun; Lu, Siyu; Wang, Lingrui; Feng, Xiaolei; Yang, Dongwen; Wang, Kai; Xiao, Guanjun; Zhang, Lijun; Redfern, Simon A. T.; Zou, Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-induced emission of cesium lead halide perovskite nullocrystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites (MHPs) are of great interest for optoelectronics because of their high quantum efficiency in solar cells and light-emitting devices. However, exploring an effective strategy to further improve their optical activities remains a considerable challenge. Here, we report that nullocrystals (NCs) of the initially nonfluorescent zero-dimensional (OD) cesium lead halide perovskite Cs4PbBr6 exhibit a distinct emission under a high pressure of 3.01 GPa. Subsequently, the emission intensity of Cs4PbBr6 NCs experiences a significant increase upon further compression. Joint experimental and theoretical analyses indicate that such pressure-induced emission (PIE) may be ascribed to the enhanced optical activity and the increased binding energy of self-trapped excitons upon compression. This phenomenon is a result of the large distortion of [PbBr6](4-) octahedral motifs resulting from a structural phase transition. Our findings demonstrate that high pressure can be a robust tool to boost the photoluminescence efficiency and provide insights into the relationship between the structure and optical properties of OD MHPs under extreme conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4506, "DOI": "10.1038/s41467-018-06840-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06840-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448575700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vaniman, DT; Bish, DL; Ming, DW; Bristow, TF; Morris, RV; Blake, DF; Chipera, SJ; Morrison, SM; Treiman, AH; Rampe, EB; Rice, M; Achilles, CN; Grotzinger, JP; McLennull, SM; Williams, J; Bell, JF; Newsom, HE; Downs, RT; Maurice, S; Sarrazin, P; Yen, AS; Morookian, JM; Farmer, JD; Stack, K; Milliken, RE; Ehlmann, BL; Sumner, DY; Berger, G; Crisp, JA; Hurowitz, JA; Anderson, R; Des Marais, DJ; Stolper, EM; Edgett, KS; Gupta, S; Spanovich, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vaniman, D. T.; Bish, D. L.; Ming, D. W.; Bristow, T. F.; Morris, R. V.; Blake, D. F.; Chipera, S. J.; Morrison, S. M.; Treiman, A. H.; Rampe, E. B.; Rice, M.; Achilles, C. N.; Grotzinger, J. P.; McLennull, S. M.; Williams, J.; Bell, J. F., III; Newsom, H. E.; Downs, R. T.; Maurice, S.; Sarrazin, P.; Yen, A. S.; Morookian, J. M.; Farmer, J. D.; Stack, K.; Milliken, R. E.; Ehlmann, B. L.; Sumner, D. Y.; Berger, G.; Crisp, J. A.; Hurowitz, J. A.; Anderson, R.; Des Marais, D. J.; Stolper, E. M.; Edgett, K. S.; Gupta, S.; Spanovich, N.", "Book Author Full Names": null, "Group Authors": "MSL Sci Team", "Article Title": "Mineralogy of a Mudstone at Yellowknife Bay, Gale Crater, Mars", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sedimentary rocks at Yellowknife Bay (Gale crater) on Mars include mudstone sampled by the Curiosity rover. The samples, John Klein and Cumberland, contain detrital basaltic minerals, calcium sulfates, iron oxide or hydroxides, iron sulfides, amorphous material, and trioctahedral smectites. The John Klein smectite has basal spacing of similar to 10 angstroms, indicating little interlayer hydration. The Cumberland smectite has basal spacing at both similar to 13.2 and similar to 10 angstroms. The larger spacing suggests a partially chloritized interlayer or interlayer magnesium or calcium facilitating H2O retention. Basaltic minerals in the mudstone are similar to those in nearby eolian deposits. However, the mudstone has far less Fe-forsterite, possibly lost with formation of smectite plus magnetite. Late Noachian/Early Hesperian or younger age indicates that clay mineral formation on Mars extended beyond Noachian time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2014, "Volume": 343, "Issue": 6169, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1243480, "DOI": "10.1126/science.1243480", "DOI Link": "http://dx.doi.org/10.1126/science.1243480", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330039300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, QW; Duan, JL; Du, J; Guo, QY; Zhang, QY; Yang, XY; Duan, YY; Tang, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Qingwei; Duan, Jialong; Du, Jian; Guo, Qiyao; Zhang, Qiaoyu; Yang, Xiya; Duan, Yanyan; Tang, Qunwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailored Lattice Tape to Confine Tensile Interface for 11.08%-Efficiency All-Inorganic CsPbBr3 Perovskite Solar Cell with an Ultrahigh Voltage of 1.702 V", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystal distortion such as lattice strain and defect located at the surfaces and grain boundaries induced by soft perovskite lattice highly determines the charge extraction-transfer dynamics and recombination to cause an inferior efficiency of perovskite solar cells (PSCs). Herein, the authors propose a strategy to significantly reduce the superficial lattice tensile strain by means of incorporating an inorganic 2D Cl-terminated Ti3C2 (Ti3C2Clx) MXene into the bulk and surface of CsPbBr3 film. Arising from the strong interaction between Cl atoms in Ti3C2Clx and the under-coordinated Pb2+ in CsPbBr3 lattice, the expanded perovskite lattice is compressed and confined to act as a lattice tape, in which the Pb-Cl bond plays a role of glue and the 2D Ti3C2 immobilizes the lattice. Finally, the defective surface is healed and a champion efficiency as high as 11.08% with an ultrahigh open-circuit voltage up to 1.702 V is achieved on the best all-inorganic CsPbBr3 PSC, which is so far the highest efficiency record for this kind of PSCs. Furthermore, the unencapsulated device demonstrates nearly unchanged performance under 80% relative humidity over 100 days and 85 degrees C over 30 days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101418, "DOI": "10.1002/advs.202101418", "DOI Link": "http://dx.doi.org/10.1002/advs.202101418", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000682866900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZH; Liu, BW; Zeng, FR; Lin, XC; Zhang, JY; Wang, XL; Wang, YZ; Zhao, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zi-Hao; Liu, Bo -Wen; Zeng, Fu-Rong; Lin, Xin-Cen; Zhang, Jia-Yan; Wang, Xiu-Li; Wang, Yu-Zhong; Zhao, Hai -Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully recyclable multifunctional adhesive with high durability, transparency, flame retardancy, and harsh- environment resistance", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recyclable/reversible adhesives have attracted growing attention for sustainability and intelligence but suffer from low adhesion strength and poor durability in complex conditions. Here, we demonstrate an aromatic silox-ane adhesive that exploits stimuli-responsive reversible assembly driven by Tr -Tr stacking, allowing for elimina-tion and activation of interfacial interactions via infiltration-volatilization of ethanol. The robust cohesive energy from water-insensitive siloxane assembly enables durable strong adhesion (3.5 MPa shear strength on glasses) on diverse surfaces. Long-term adhesion performances are realized in underwater, salt, and acid/alkali solutions (pH 1-14) and at low/high temperatures (-10-90 degrees C). With reversible assembly/disassembly, the adhesive is closed-loop recycled (-100%) and reused over 100 times without adhesion loss. Furthermore, the adhesive has unique combinations of high transparency (-98% in the visible light region of 400-800 nm) and flame re-tardancy. The experiments and theoretical calculations reveal the corresponding mechanism at the molecular level. This Tr -Tr stacking-driven siloxane assembly strategy opens up an avenue for high-performance adhesives with circular life and multifunctional integration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2022, "Volume": 8, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadd8527", "DOI": "10.1126/sciadv.add8527", "DOI Link": "http://dx.doi.org/10.1126/sciadv.add8527", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905194200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JC; Ren, ZY; Hu, WQ; Soon, RH; Yasa, IC; Liu, ZM; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiachen; Ren, Ziyu; Hu, Wenqi; Soon, Ren Hao; Yasa, Immihan Ceren; Liu, Zemin; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Voxelated three-dimensional miniature magnetic soft machines via multimaterial heterogeneous assembly", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Small-scale soft-bodied machines that respond to externally applied magnetic field have attracted wide research interest because of their unique capabilities and promising potential in a variety of fields, especially for biomedical applications. When the size of such machines approach the sub-millimeter scale, their designs and functionalities are severely constrained by the available fabrication methods, which only work with limited materials, geometries, and magnetization profiles. To free such constraints, here, we propose a bottom-up assembly-based 3D microfabri-cation approach to create complex 3D miniature wireless magnetic soft machines at the milli-and sub-millimeter scale with arbitrary multimaterial compositions, arbitrary 3D geometries, and arbitrary programmable 3D magne-tization profiles at high spatial resolution. This approach helps us concurrently realize diverse characteristics on the machines, including programmable shape morphing, negative Poisson's ratio, complex stiffness distribution, directional joint bending, and remagnetization for shape reconfiguration. It enlarges the design space and en-ables biomedical device-related functionalities that are previously difficult to achieve, including peristaltic pump -ing of biological fluids and transport of solid objects, active targeted cargo transport and delivery, liquid biopsy, and reversible surface anchoring in tortuous tubular environments withstanding fluid flows, all at the sub-millimeter scale. This work improves the achievable complexity of 3D magnetic soft machines and boosts their future capa-bilities for applications in robotics and biomedical engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2021, "Volume": 6, "Issue": 53, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "abf0112", "DOI": "10.1126/scirobotics.abf0112", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.abf0112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000679970500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YF; Kumar, P; Tan, X; Lu, XX; Zhu, XF; Jiang, JJ; Pan, J; Xi, SB; Yang, HY; Ma, ZP; Wan, T; Chu, DW; Jiang, WJ; Smith, SC; Amal, R; Han, ZJ; Lu, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yufei; Kumar, Priyank, V; Tan, Xin; Lu, Xinxin; Zhu, Xiaofeng; Jiang, Junjie; Pan, Jian; Xi, Shibo; Yang, Hui Ying; Ma, Zhipeng; Wan, Tao; Chu, Dewei; Jiang, Wenjie; Smith, Sean C.; Amal, Rose; Han, Zhaojun; Lu, Xunyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating Pt-O-Pt atomic clusters with isolated cobalt atoms for enhanced hydrogen evolution catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modulating single-metal sites at the atomic level can boost the intrinsic catalytic activity. Here, the authors describe the design of Pt atomic clusters containing Pt-O-Pt units supported on Co single atoms and N co-doped carbon for enhanced hydrogen evolution catalysis. Platinum is the most efficient catalyst for hydrogen evolution reaction in acidic conditions, but its widespread use has been impeded by scarcity and high cost. Herein, Pt atomic clusters (Pt ACs) containing Pt-O-Pt units were prepared using Co/N co-doped carbon (CoNC) as support. Pt ACs are anchored to single Co atoms on CoNC by forming strong interactions. Pt-ACs/CoNC exhibits only 24 mV overpotential at 10 mA cm(-2) and a high mass activity of 28.6 A mg(-1) at 50 mV, which is more than 6 times higher than commercial Pt/C with any Pt loadings. Spectroscopic measurements and computational modeling reveal the enhanced hydrogen generation activity attributes to the charge redistribution between Pt and O atoms in Pt-O-Pt units, making Pt atoms the main active sites and O linkers the assistants, thus optimizing the proton adsorption and hydrogen desorption. This work opens an avenue to fabricate noble-metal-based ACs stabilized by single-atom catalysts with desired properties for electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2430, "DOI": "10.1038/s41467-022-30155-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30155-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790940000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, YJ; Peng, B; Bravic, I; Yu, Y; Dong, YR; Liang, RQ; Ou, QR; Monserrat, B; Zhang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yujun; Peng, Bo; Bravic, Ivona; Yu, Yan; Dong, Yurong; Liang, Rongqing; Ou, Qiongrong; Monserrat, Bartomeu; Zhang, Shuyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Blue-Emitting CsPbBr3Perovskite nullocrystals through Neodymium Doping", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal CsPbX3(X = Br, Cl, and I) perovskite nullocrystals exhibit tunable bandgaps over the entire visible spectrum and high photoluminescence quantum yields in the green and red regions. However, the lack of highly efficient blue-emitting perovskite nullocrystals limits their development for optoelectronic applications. Herein, neodymium (III) (Nd3+) doped CsPbBr(3)nullocrystals are prepared through the ligand-assisted reprecipitation method at room temperature with tunable photoemission from green to deep blue. A blue-emitting nullocrystal with a central wavelength at 459 nm, an exceptionally high photoluminescence quantum yield of 90%, and a spectral width of 19 nm is achieved. First principles calculations reveal that the increase in photoluminescence quantum yield upon doping is driven by an enhancement of the exciton binding energy due to increased electron and hole effective masses and an increase in oscillator strength due to shortening of the Pb-Br bond. Putting these results together, an all-perovskite white light-emitting diode is successfully fabricated, demonstrating that B-site composition engineering is a reliable strategy to further exploit the perovskite family for wider optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 7, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001698, "DOI": "10.1002/advs.202001698", "DOI Link": "http://dx.doi.org/10.1002/advs.202001698", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000565547400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, RH; Curtarolo, S; Ahmetcik, E; Scheffler, M; Ghiringhelli, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Runhai; Curtarolo, Stefano; Ahmetcik, Emre; Scheffler, Matthias; Ghiringhelli, Luca M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "SISSO: A compressed-sensing method for identifying the best low-dimensional descriptor in an immensity of offered candidates", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lack of reliable methods for identifying descriptors-the sets of parameters capturing the underlying mechanisms of a material's property-is one of the key factors hindering efficient materials development. Here, we propose a systematic approach for discovering descriptors for materials' properties, within the framework of compressed-sensing-based dimensionality reduction. The sure independence screening and sparsifying operator (SISSO) tackles immense and correlated features spaces, and converges to the optimal solution from a combination of features relevant to the materials' property of interest. In addition, SISSO gives stable results also with small training sets. The methodology is benchmarked with the quantitative prediction of the ground-state enthalpies of octet binary materials (using ab initio data) and applied to the showcase example of predicting the metal/insulator classification of binaries (with experimental data). Accurate, predictive models are found in both cases. For the metal-insulator classification model, the predictive capability is tested beyond the training data: It rediscovers the available pressure-induced insulator-to-metal transitions and it allows for the prediction of yet unknown transition candidates, ripe for experimental validation. As a step forward with respect to previous model-identification methods, SISSO can become an effective tool for automatic materials development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 578, "Times Cited, All Databases": 640, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 83802, "DOI": "10.1103/PhysRevMaterials.2.083802", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.2.083802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441038500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, X; Hu, XZ; Jin, B; Yu, J; Liu, KL; Li, HQ; Zhai, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xing; Hu, Xiaozong; Jin, Bao; Yu, Jing; Liu, Kailang; Li, Huiqiao; Zhai, Tianyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Anisotropic GeSe nullosheets for Phototransistors with Ultrahigh Photoresponsivity", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D GeSe possesses black phosphorous-analog-layered structure and shows excellent environmental stability, as well as highly anisotropic in-plane properties. Additionally, its high absorption efficiency in the visible range and high charge carrier mobility render it promising for applications in optoelectronics. However, most reported GeSe-based photodetectors show frustrating performance especially in photoresponsivity. Herein, a 2D GeSe-based phototransistor with an ultrahigh photoresponsivity is demonstrated. Its optimized photoresponsivity can be up to approximate to 1.6 x 10(5) A W-1. This high responsivity can be attributed to the highly efficient light absorption and the enhanced photoconductive gain due to the existence of trap states. The exfoliated GeSe nullosheet is confirmed to be along the [001] (armchair direction) and [010] (zigzag direction) using transmission electron microscopy and anisotropic Raman characterizations. The angle-dependent electric and photoresponsive performance is systematically explored. Notably, the GeSe-based phototransistor shows strong polarization-dependent photoresponse with a peak/valley ratio of 1.3. Furthermore, the charge carrier mobility along the armchair direction is measured to be 1.85 times larger than that along the zigzag direction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800478, "DOI": "10.1002/advs.201800478", "DOI Link": "http://dx.doi.org/10.1002/advs.201800478", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441869400031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, HY; Hu, DQ; Yang, QG; Gao, J; Fu, JH; Yang, K; He, H; Chen, SS; Kan, ZP; Duan, TN; Yang, C; Ouyang, JY; Xiao, ZY; Sun, K; Lu, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Haiyan; Hu, Dingqin; Yang, Qianguang; Gao, Jie; Fu, Jiehao; Yang, Ke; He, Hao; Chen, Shanshan; Kan, Zhipeng; Duan, Tainull; Yang, Changduk; Ouyang, Jianyong; Xiao, Zeyun; Sun, Kuan; Lu, Shirong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-Small-Molecule Organic Solar Cells with an Ordered Liquid Crystalline Donor", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystallinity and intermolecular interaction among small molecules are enhanced in order to achieve reasonable phase segregation between the donor and acceptor in all-small-molecule organic solar cells (ASM OSCs). By substituting an alkyl side chain with a chlorine (CI) atom on the original benzodithiophene terthiophene rhodanine (BTR) molecule, the new small molecular donor, namely BTR-CI, processes a more ordered liquid crystalline property, down-shifted molecular energy levels, and higher crystallinity, When blended with a non-fullerene acceptor Y6, which has a complementary absorption profile and well-matched energy levels but no liquid crystalline property, a prominent phase separation and optimal film morphology are obtained. As a result, a record-high power conversion efficiency (PCE) of 13.6% is achieved, taking a large step forward in ASM OSCs. Our results highlight the importance of crystallinity to phase separation, suggesting the great promise of liquid crystalline materials in OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3034, "End Page": 3047, "Article Number": null, "DOI": "10.1016/j.joule.2019.09.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.09.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503428000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Perrot, A; Rangeard, D; Pierre, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perrot, A.; Rangeard, D.; Pierre, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural built-up of cement-based materials used for 3D-printing extrusion techniques", "Source Title": "MATERIALS AND STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing and digital fabrication bring new horizons to concrete and cement-based material construction. 3D printing inspired construction techniques that have recently been developed at laboratory scale for cement-based materials. This study aims to investigate the role of the structural build-up properties of cement-based materials in such a layer by layer construction technique. As construction progresses, the cement-based materials become harder with time. The mechanical strength of the cement-based materials must be sufficient to sustain the weight of the layers subsequently deposited. It follows that the comparison of the mechanical strength, which evolves with time (i.e. structural build-up), with the loading due to layers subsequently deposited, can be expected to provide the optimal rate of layer by layer construction. A theoretical framework has been developed to propose a method of optimization of the building rate, which is experimentally validated in a layer-wise built column.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 601, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 49, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1213, "End Page": 1220, "Article Number": null, "DOI": "10.1617/s11527-015-0571-0", "DOI Link": "http://dx.doi.org/10.1617/s11527-015-0571-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373963700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, F; Rao, YP; Batalu, D; Cai, L; Dong, YY; Zhu, XJ; Shi, YY; Shi, Z; Liu, YW; Lu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Fei; Rao, Yanping; Batalu, Dan; Cai, Lei; Dong, Yanyan; Zhu, Xiaojie; Shi, Yuyang; Shi, Zhong; Liu, Yaowen; Lu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macroscopic Electromagnetic Cooperative Network-Enhanced MXene/Ni Chains Aerogel-Based Microwave Absorber with Ultra-Low Matching Thickness", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic cooperative strategy has been presented as a mainstream approach that can effectively optimize the matching thickness of dielectric loss dominullt system. However, it is still challenging for dielectric-magnetic loss coexisting-type absorber to develop electromagnetic wave (EMW) performance with ultra-low matching thickness (<= 1 mm). Breaking the limitation of traditional electromagnetic response at microscopic/mesoscopic scale, a ficus microcarpa-like magnetic aerogel with macroscopical electromagnetic cooperative effect was fabricated through highly oriented self-assembly engineering. The highly oriented Ni chains with unique macroscopic morphology (similar to 1 cm in length) were achieved via a special magnetic field-induced growth. Strong magnetic coupling was observed in the Ni chains confirmed by the micromagnetic simulation. The deductive calculation validates that maintaining high value of electromagnetic parameters at high frequencies is the prerequisites of ultrathin absorber. The electromagnetic cooperative networks with uninterrupted and dual pathways spread through the entire aerogel skeleton, resulting in the impressive permittivity even at high frequencies. Consequently, the aerogel exhibits a remarkable EMW performance at an ultrathin thickness of 1 mm. Thus, based on the modulation of electromagnetic parameters, this work proposed a macroscopic ordered structure with the electromagnetic cooperative effect useful to develop a suitable strategy for achieving ultrathin EMW absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 140, "DOI": "10.1007/s40820-022-00869-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00869-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821031400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HY; Zhou, WK; Gao, J; Wang, F; Wang, SB; Fang, Y; Gao, Y; Chen, W; Zhang, W; Weng, YX; Wang, ZC; Liu, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Huaying; Zhou, Weikang; Gao, Jing; Wang, Fan; Wang, Shaobing; Fang, Yan; Gao, Yang; Chen, Wei; Zhang, Wen; Weng, Yunxiang; Wang, Zhengchao; Liu, Haiqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient, biosafe and tissue adhesive hemostatic cotton gauze with controlled balance of hydrophilicity and hydrophobicity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cotton gauze is widely used as haemostatic material for bleeding control, but its high blood absorption capacity can to cause extra blood loss. Here, the authors develop a cotton gauze whose surface is modified with a catechol compound featuring a flexible long hydrophobic alkyl chain which demonstrates excellent haemostatic performance. Cotton gauze is a widely used topical hemostatic material for bleeding control, but its high blood absorption capacity tends to cause extra blood loss. Therefore, development of rapid hemostatic cotton gauze with less blood loss is of great significance. Here, we develop an efficient hemostatic cotton gauze whose surface is slightly modified with a catechol compound which features a flexible long hydrophobic alkyl chain terminated with a catechol group. Its hemostatic performance in animal injuries is superior to standard cotton gauze and Combat Gauze(TM). Its biosafety is similar to cotton gauze and rebleeding hardly occurs when the gauze is removed. Here, we show its hemostatic capability is attributable to the rapid formation of big and thick primary erythrocyte clots, due to its effective controlling of blood movement through blocking effect from tissue adhesion by catechol, blood wicking in cotton, and the hydrophobic effect from long alkyl chains.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 552, "DOI": "10.1038/s41467-022-28209-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28209-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749187600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XF; Shen, B; Lyubartsev, A; Zhai, JW; Hedin, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xiaofeng; Shen, Bo; Lyubartsev, Alexander; Zhai, Jiwei; Hedin, Niklas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semiconducting piezoelectric heterostructures for piezo- and piezophotocatalysis", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric semiconductors can be polarized and used in mechanoredox systems and photoredox catalysis. Conventional non-piezoelectric semiconductors have limitations when it comes to charge carrier recombination and slow transport rates in catalytic reactions, which can be overcome by piezoelectric polarization processes in piezoelectric semiconductors. Heterostructures based on semiconducting piezoelectrics often offer enhanced catalytic reactivities that are related to their mechanical, piezoelectric, optical, and electronic characteristics. We review how to use such heterostructures to convert mechanical energy into chemical energy, and how the related piezoelectric polarization tunes the band structures and provides advantages in piezophotocatalysis over regular photocatalysis. We discuss fundamental concepts of piezoelectricity, piezoelectric potential, and examine different piezoelectric heterostructures for piezoand piezophotocatalysis. A review of dynamic investigations of piezoand piezophotocatalytic processes is presented. The complementary developments in the understanding of the piezotronic and piezophototronic effects are described, which include the induced charge-transfer mechanisms for piezoand piezophotocatalytic reactions that can occur with piezoelectric heterostructures. Finally, we derive design principles and suggest future research directions in the emerging field of piezoand piezophotocatalysis employing semiconductive heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107141, "DOI": "10.1016/j.nulloen.2022.107141", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2022.107141", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779310100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Lu, YJ; Huang, R; Chang, JW; Yu, XN; Jiang, RC; Yu, XL; Roskilly, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhi; Lu, Yiji; Huang, Rui; Chang, Jinwei; Yu, Xiaonull; Jiang, Ruicheng; Yu, Xiaoli; Roskilly, Anthony Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Applications and technological challenges for heat recovery, storage and utilisation with latent thermal energy storage", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal energy storage (TES) technology is considered to have the greatest potential to balance the demand and supply overcoming the intermittency and fluctuation nature of real-world heat sources, making a more flexible, highly efficient and reliable thermal energy system. This article provides a comprehensive state-of-the-art review of latent thermal energy storage (LTES) technology with a particular focus on medium-high temperature phase change materials for heat recovery, storage and utilisation. This review aims to identify potential methods to design and optimise LTES heat exchangers for heat recovery and storage, bridging the knowledge gap between the present studies and future technological developments. The key focuses of current work can be described as follows: (1) Insight into moderate-high temperature phase change materials and thermal conductivity enhancement methods. (2) Various configurations of latent thermal energy storage heat exchangers and relevant heat transfer enhancement techniques (3) Applications of latent thermal energy storage heat exchangers with different thermal sources, including solar energy, industrial waste heat and engine waste heat, are discussed in detail.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 283, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116277, "DOI": "10.1016/j.apenergy.2020.116277", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2020.116277", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613289000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schneider, M; George, EP; Manescau, TJ; Zálezák, T; Hunfeld, J; Dlouhy, A; Eggeler, G; Laplanche, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schneider, M.; George, E. P.; Manescau, T. J.; Zalezak, T.; Hunfeld, J.; Dlouhy, A.; Eggeler, G.; Laplanche, G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of strengthening due to grain boundaries and annealing twin boundaries in the CrCoNi medium-entropy alloy", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CrCoNi exhibits the best combination of strength and ductility among all the equiatomic single-phase FCC subsets of the CrMnFeCoNi high-entropy alloy. Here, its yield strength was determined in compression as a function of grain size and temperature. Yield strength was also plotted as a function of crystallite size, which takes into account both annealing twin boundaries and grain boundaries. The resulting Hall-Petch slopes were straight lines but with different slopes that depend on the number of twin boundaries per grain. Scanning transmission electron microscopy of deformed specimens revealed the formation of dislocation pile-ups at grain and annealing twin boundaries indicating that the latter also act as obstacles to slip and contribute to strength. Using a simple pile-up model, the strengths of the grain and twin boundaries were estimated to lie in the range 900-1250 MPa. Assuming that they have the same strength, in the case of twin boundaries this strength corresponds roughly to the stress required to constrict Shockley partials, which suggests that dissociated dislocations have to become compact before they can cross the annealing twin boundaries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 155, "End Page": 169, "Article Number": null, "DOI": "10.1016/j.ijplas.2019.08.009", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2019.08.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502893800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, WK; Chen, C; Wang, ZB; Chu, IH; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Weike; Chen, Chi; Wang, Zhenbin; Chu, Iek-Heng; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep neural networks for accurate predictions of crystal stability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting the stability of crystals is one of the central problems in materials science. Today, density functional theory (DFT) calculations remain comparatively expensive and scale poorly with system size. Here we show that deep neural networks utilizing just two descriptors-the Pauling electronegativity and ionic radii-can predict the DFT formation energies of C(3)A(2)D(3)O(12) garnets and ABO(3) perovskites with low mean absolute errors (MAEs) of 7-10 meV atom(-1) and 20-34 meV atom(-1), respectively, well within the limits of DFT accuracy. Further extension to mixed garnets and perovskites with little loss in accuracy can be achieved using a binary encoding scheme, addressing a critical gap in the extension of machine-learning models from fixed stoichiometry crystals to infinite universe of mixed-species crystals. Finally, we demonstrate the potential of these models to rapidly transverse vast chemical spaces to accurately identify stable compositions, accelerating the discovery of novel materials with potentially superior properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3800, "DOI": "10.1038/s41467-018-06322-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06322-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444796400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, GZ; Yan, QB; Qin, ZZ; Yue, SY; Hu, M; Su, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Guangzhao; Yan, Qing-Bo; Qin, Zhenzhen; Yue, Sheng-Ying; Hu, Ming; Su, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic intrinsic lattice thermal conductivity of phosphorene from first principles", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorene, the single layer counterpart of black phosphorus, is a novel two-dimensional semiconductor with high carrier mobility and a large fundamental direct band gap, which has attracted tremendous interest recently. Its potential applications in nullo-electronics and thermoelectrics call for fundamental study of the phonon transport. Here, we calculate the intrinsic lattice thermal conductivity of phosphorene by solving the phonon Boltzmann transport equation (BTE) based on first-principles calculations. The thermal conductivity of phosphorene at 300 K is 30.15 W m(-1) K-1 (zigzag) and 13.65 W m(-1) K-1 (armchair), showing an obvious anisotropy along different directions. The calculated thermal conductivity fits perfectly to the inverse relationship with temperature when the temperature is higher than Debye temperature (Theta(D) = 278.66 K). In comparison to graphene, the minor contribution around 5% of the ZA mode is responsible for the low thermal conductivity of phosphorene. In addition, the representative mean free path (MFP), a critical size for phonon transport, is also obtained.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 17, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4854, "End Page": 4858, "Article Number": null, "DOI": "10.1039/c4cp04858j", "DOI Link": "http://dx.doi.org/10.1039/c4cp04858j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349616400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ozden, A; Li, J; Kandambeth, S; Li, XY; Liu, SJ; Shekhah, O; Ou, PF; Finfrock, YZ; Wang, YK; Alkayyali, T; de Arquer, FPG; Kale, VS; Bhatt, PM; Ip, AH; Eddaoudi, M; Sargent, EH; Sinton, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozden, Adnull; Li, Jun; Kandambeth, Sharath; Li, Xiao-Yan; Liu, Shijie; Shekhah, Osama; Ou, Pengfei; Zou Finfrock, Y.; Wang, Ya-Kun; Alkayyali, Tartela; Pelayo Garcia de Arquer, F.; Kale, Vinayak S.; Bhatt, Prashant M.; Ip, Alexander H.; Eddaoudi, Mohamed; Sargent, Edward H.; Sinton, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy- and carbon-efficient CO2/CO electrolysis to multicarbon products via asymmetric ion migration-adsorption", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide/monoxide (CO2/CO) electrolysis provides a means to convert emissions into multicarbon products. However, impractical energy and carbon efficiencies limit current systems. Here we show that these inefficiencies originate from uncontrolled gas/ion distributions in the local reaction environment. Understanding of the flows of cations and anions motivated us to seek a route to block cation migration to the catalyst surface-a strategy we instantiate using a covalent organic framework (COF) in bulk heterojunction with a catalyst. The pi-conjugated hydrophobic COFs constrain cation (potassium) diffusion via cation-pi interactions, while promoting anion (hydroxide) and gaseous feedstock adsorption on the catalyst surface. As a result, a COF-mediated catalyst enables electrosynthesis of multicarbon products from CO for 200 h at a single-pass carbon efficiency of 95%, an energy efficiency of 40% and a current density of 240 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 179, "End Page": 190, "Article Number": null, "DOI": "10.1038/s41560-022-01188-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01188-2", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913426300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, G; Xiang, Z; Yu, F; Asaba, T; Lawson, B; Cai, P; Tinsman, C; Berkley, A; Wolgast, S; Eo, YS; Kim, DJ; Kurdak, C; Allen, JW; Sun, K; Chen, XH; Wang, YY; Fisk, Z; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, G.; Xiang, Z.; Yu, F.; Asaba, T.; Lawson, B.; Cai, P.; Tinsman, C.; Berkley, A.; Wolgast, S.; Eo, Y. S.; Kim, Dae-Jeong; Kurdak, C.; Allen, J. W.; Sun, K.; Chen, X. H.; Wang, Y. Y.; Fisk, Z.; Li, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional Fermi surfaces in Kondo insulator SmB6", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the Kondo insulator samarium hexaboride (SmB6), strong correlation and band hybridization lead to an insulating gap and a diverging resistance at low temperature. The resistance divergence ends at about 3 kelvin, a behavior that may arise from surface conductance. We used torque magnetometry to resolve the Fermi surface topology in this material. The observed oscillation patterns reveal two Fermi surfaces on the (100) surface plane and one Fermi surface on the (101) surface plane. The measured Fermi surface cross sections scale as the inverse cosine function of the magnetic field tilt angles, which demonstrates the two-dimensional nature of the conducting electronic states of SmB6.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 346, "Issue": 6214, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1208, "End Page": 1212, "Article Number": null, "DOI": "10.1126/science.1250366", "DOI Link": "http://dx.doi.org/10.1126/science.1250366", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346189000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, I; Kim, WS; Kim, K; Ansari, MA; Mehmood, MQ; Badloe, T; Kim, Y; Gwak, J; Lee, H; Kim, YK; Rho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Inki; Kim, Won-Sik; Kim, Kwan; Ansari, Muhammad Afnull; Mehmood, Muhammad Qasim; Badloe, Trevon; Kim, Yeseul; Gwak, Junho; Lee, Heon; Kim, Young-Ki; Rho, Junsuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Holographic metasurface gas sensors for instantaneous visual alarms", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid detection of biological and chemical substances in real time is particularly important for public health and environmental monitoring and in the military sector. If the process of substance detection to visual reporting can be implemented into a single miniaturized sensor, there could be a profound impact on practical applications. Here, we propose a compact sensor platform that integrates liquid crystals (LCs) and holographic metasurfaces to autonomously sense the existence of a volatile gas and provide an immediate visual holographic alarm. By combining the advantage of the rapid responses to gases realized by LCs with the compactness of holographic metasurfaces, we develop ultracompact gas sensors without additional complex instruments or machinery to report the visual information of gas detection. To prove the applicability of the compact sensors, we demonstrate a metasurface-integrated gas sensor on safety goggles via a one-step nullocasting process that is attachable to flat, curved, and flexible surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 7, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe9943", "DOI": "10.1126/sciadv.abe9943", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe9943", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637819900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouyang, YX; Shi, SL; Bai, XW; Li, Q; Wang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouyang, Yixin; Shi, Li; Bai, Xiaowan; Li, Qiang; Wang, Jinlan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking scaling relations for efficient CO2 electrochemical reduction through dual-atom catalysts", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of CO2 offers an elegant solution to the current energy crisis and carbon emission issues, but the catalytic efficiency for CO2 reduction is seriously restricted by the inherent scaling relations between the adsorption energies of intermediates. Herein, by combining the concept of single-atom catalysts and multiple active sites, we design heteronuclear dual-atom catalysts to break through the stubborn restriction of scaling relations on catalytic activity. Twenty-one kinds of heteronuclear transition-metal dimers are embedded in monolayer C2N as potential dual-atom catalysts. First-principles calculations reveal that by adjusting the components of dimers, the two metal atoms play the role of carbon adsorption sites and oxygen adsorption sites respectively, which results in the decoupling of adsorption energies of key intermediates. Free energy profiles demonstrate that CO2 can be efficiently reduced to CH4 on CuCr/C2N and CuMn/C2N with low limiting potentials of -0.37 V and -0.32 V, respectively. This study suggests that the introduction of multiple active sites into porous two-dimensional materials would provide a great possibility for breaking scaling relations to achieve efficient multi-intermediate electrocatalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1807, "End Page": 1813, "Article Number": null, "DOI": "10.1039/c9sc05236d", "DOI Link": "http://dx.doi.org/10.1039/c9sc05236d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515704400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, R; Liu, XN; Hu, GK; Sun, CT; Huang, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, R.; Liu, X. N.; Hu, G. K.; Sun, C. T.; Huang, G. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative refraction of elastic waves at the deep-subwavelength scale in a single-phase metamaterial", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Negative refraction of elastic waves has been studied and experimentally demonstrated in three- and two-dimensional phononic crystals, but Bragg scattering is impractical for low-frequency wave control because of the need to scale the structures to manageable sizes. Here we present an elastic metamaterial with chiral microstructure made of a single-phase solid material that aims to achieve subwavelength negative refraction of elastic waves. Both negative effective mass density and modulus are observed owing to simultaneous translational and rotational resonullces. We experimentally demonstrate negative refraction of the longitudinal elastic wave at the deep-subwavelength scale in the metamaterial fabricated in a stainless steel plate. The experimental measurements are in good agreement with numerical simulations. Moreover, wave mode conversion related with negative refraction is revealed and discussed. The proposed elastic metamaterial may thus be used as a flat lens for elastic wave focusing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5510, "DOI": "10.1038/ncomms6510", "DOI Link": "http://dx.doi.org/10.1038/ncomms6510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345913000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, RF; Chen, L; Liang, Q; Xi, JQ; Zhao, HQ; Jin, YL; Gao, XF; Yan, XY; Gao, LZ; Fan, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ruofei; Chen, Lei; Liang, Qian; Xi, Juqun; Zhao, Hanqing; Jin, Yiliang; Gao, Xingfa; Yan, Xiyun; Gao, Lizeng; Fan, Kelong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the active sites on ferrihydrite with apparent catalase-like activity for potentiating radiotherapy", "Source Title": "nullO TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of catalase-like nullozymes in relieving tumor hypoxia has been a promising strategy for adjuvant radiotherapy, yet their catalytic mechanism and toxic potential remain elusive. While most studies on catalase-like mechanisms focus on the substrates and products in the catalytic process, little is reported to analyze the dominating surface structure for catalytic activity of nullozymes. Here, we reported the catalase-like activity of ferrihydrite and revealed its structure-activity relationship. Among the ten main forms of iron oxide nullomaterials, ferrihydrite, especially 2-line ferrihydrite, exhibited the highest catalase-like activity. Importantly, the structure-activity fitting and density functional analysis revealed that the abundant surface iron-associated hydroxyl groups dominulltly affect the catalase-like activity of ferrihydrites. In addition, the ferrihydrite exhibited no peroxidase-like and superoxide dismutase-like activities, and constantly catalyzed the decomposition of H2O2 to release O-2 in the pH range of 4.0-8.7. With the help of steady and single catalase-like activity in the physiological environment, ferrihydrite safely and effectively catalyzed the H2O2 in tumor microenvironment to in situ produce O-2 and significantly enhanced the therapeutic effect of radiotherapy. Moreover, ferrihydrite exhibited excellent biosafety and biodegradability. These findings demonstrate the great potential of ferrihydrite as a biocompatible catalase-like nullozyme for relieving hypoxia in cancer therapy. (C) 2021 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 41, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101317, "DOI": "10.1016/j.nulltod.2021.101317", "DOI Link": "http://dx.doi.org/10.1016/j.nulltod.2021.101317", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000717766200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, GF; Chen, JL; Yu, TQ; Luo, L; Yin, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Guangfu; Chen, Jinli; Yu, Tianqi; Luo, Lin; Yin, Shibin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "N-Doped Graphene-Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO nullo-sheet Heterojunction for Enhanced Water Electrolysis Activity at High Current Density", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing highly effective and stable non-noble metal-based bifunctional catalyst working at high current density is an urgent issue for water electrolysis (WE). Herein, we prepare the N-doped graphene-decorated NiCo alloy coupled with mesoporous NiCoMoO nullo-sheet grown on 3D nickel foam (NiCo@C-NiCoMoO/NF) for water splitting. NiCo@C-NiCoMoO/NF exhibits outstanding activity with low overpotentials for hydrogen and oxygen evolution reaction (HER: 39/266 mV; OER: 260/390 mV) at +/- 10 and +/- 1000 mA cm(-2). More importantly, in 6.0 M KOH solution at 60 degrees C for WE, it only requires 1.90 V to reach 1000 mA cm(-2) and shows excellent stability for 43 h, exhibiting the potential for actual application. The good performance can be assigned to N-doped graphene-decorated NiCo alloy and mesoporous NiCoMoO nullo-sheet, which not only increase the intrinsic activity and expose abundant catalytic activity sites, but also enhance its chemical and mechanical stability. This work thus could provide a promising material for industrial hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77, "DOI": "10.1007/s40820-021-00607-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00607-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619826300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YX; Chen, ZW; null, PF; Xiong, F; Lin, SQ; Zhang, XY; Chen, Y; Chen, LD; Ge, BH; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yixuan; Chen, Zhiwei; null, Pengfei; Xiong, Fen; Lin, Siqi; Zhang, Xinyue; Chen, Yue; Chen, Lidong; Ge, Binghui; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice Strain Advances Thermoelectrics", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice vibrations in crystalline materials generate phonons as heat carriers for heat conduction, and the phonon dispersion (energy versus momentum) is fundamentally determined by the mass of lattice vibrators (atoms) and the interaction force between atoms. A significant manipulation of lattice thermal conductivity through a change in atomic mass usually requires a large variation in chemical composition, which is not always valid thermodynamically or may risk the resultant detriment of other functionalities (e.g., carrier mobility). Here we show a strategy of alternatively manipulating the interaction force between atoms through lattice strains without changing the composition, for remarkably reducing the lattice thermal conductivity without reducing carrier mobility, in Na0.03Eu0.03Sn0.02Pb0.92Te with stable lattice dislocations. This successfully leads to an extraordinarily high thermoelectric figure of merit, with the help of valence band convergence. This work offers both insights and solutions on lattice strain engineering for reducing lattice thermal conductivity, thus advancing thermoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1276, "End Page": 1288, "Article Number": null, "DOI": "10.1016/j.joule.2019.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.02.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467969300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, BH; Zhang, XY; Wu, K; Wang, H; Wang, J; Chen, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Bohua; Zhang, Xiaoyan; Wu, Kan; Wang, Hao; Wang, Jun; Chen, Jianping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Q-switched fiber laser based on transition metal dichalcogenides MoS2, MoSe2, WS2, and WSe2", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, we report 4 different saturable absorbers based on 4 transition metal dichalcogenides (MoS2, MoSe2, WS2, WSe2) and utilize them to Q-switch a ring-cavity fiber laser with identical cavity configuration. It is found that MoSe2 exhibits highest modulation depth with similar preparation process among four saturable absorbers. Q-switching operation performance is compared from the aspects of RF spectrum, optical spectrum, repetition rate and pulse duration. WS2 Q-switched fiber laser generates the most stable pulse trains compared to other 3 fiber lasers. These results demonstrate the feasibility of TMDs to Q-switch fiber laser effectively and provide a meaningful reference for further research in nonlinear fiber optics with these TMDs materials. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 503, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2015, "Volume": 23, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26723, "End Page": 26737, "Article Number": null, "DOI": "10.1364/OE.23.026723", "DOI Link": "http://dx.doi.org/10.1364/OE.23.026723", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365077900127", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, WC; Li, WB; Zhang, Y; Xia, YG; Wang, QL; Wang, W; Liu, P; Yu, XQ; He, H; Liang, CH; Ban, YX; Mi, CW; Yang, S; Liu, W; Cui, MM; Deng, X; Wang, ZK; Zhang, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Wancheng; Li, Wanbo; Zhang, Yu; Xia, Yage; Wang, Qiaoling; Wang, Wei; Liu, Ping; Yu, Xinquan; He, Hui; Liang, Caihua; Ban, Youxue; Mi, Changwen; Yang, Sha; Liu, Wei; Cui, Miaomiao; Deng, Xu; Wang, Zuankai; Zhang, Youfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-durable superhydrophobic cellular coatings", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing versatile, scalable, and durable coatings that resist the accretion of matters (liquid, vapor, and solid phases) in various operating environments is important to industrial applications, yet has proven challenging. Here, we report a cellular coating that imparts liquid-repellence, vapor-imperviousness, and solid-shedding capabilities without the need for complicated structures and fabrication processes. The key lies in designing basic cells consisting of rigid microshells and releasable nulloseeds, which together serve as a rigid shield and a bridge that chemically bonds with matrix and substrate. The durability and strong resistance to accretion of different matters of our cellular coating are evidenced by strong anti-abrasion, enhanced anti-corrosion against saltwater over 1000 h, and maintaining dry in complicated phase change conditions. The cells can be impregnated into diverse matrixes for facile mass production through scalable spraying. Our strategy provides a generic design blueprint for engineering ultra-durable coatings for a wide range of applications. The design and scalable fabrication of durable superhydrophobic coatings that prevent accretion of matter is challenging. Here the authors developed a generic cellular design for ultra-durable coatings that provides liquid-repellence, vapor imperviousness, and solid-shedding capabilities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5953, "DOI": "10.1038/s41467-023-41675-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41675-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001074590000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, YH; Jiang, YL; Yang, ZZ; Dong, J; Yang, W; An, QY; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Yuanhao; Jiang, Yalong; Yang, Zhongzhuo; Dong, Jun; Yang, Wei; An, Qinyou; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Structure Modulation in MoO2/MoP Heterostructure to Induce Fast Electronic/Ionic Diffusion Kinetics for Lithium Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxides (TMOs) are considered as the prospective anode materials in lithium-ion batteries (LIBs). Nevertheless, the disadvantages, including large volume variation and poor electrical conductivity, obstruct these materials to meet the needs of practical application. Well-designed mesoporous nullostructures and electronic structure modulation can enhance the electron/Li-ions diffusion kinetics. Herein, a unique mesoporous molybdenum dioxide/molybdenum phosphide heterostructure nullobelts (meso-MoO2/MoP-NBs) composed of uniform nulloparticles is obtained by one-step phosphorization process. The Mott-Schottky tests and density functional theory calculations demonstrated that meso-MoO2/MoP-NBs possesses superior electronic conductivity. The detailed lithium storage mechanism (solid solution reaction for MoP and partial conversion for MoO2), small change ratio of crystal structure and fast electronic/ionic diffusion behavior of meso-MoO2/MoP-NBs are systematically investigated by operando X-ray diffraction, ex situ transmission electron microscopy, and kinetic analysis. Benefiting from the synergistic effects, the meso-MoO2/MoP-NBs displays a remarkable cycling performance (515 mAh g(-1) after 1000 cycles at 1 A g(-1)) and excellent rate capability (291 mAh g(-1) at 8 A g(-1)). These findings can shed light on the behavior of the electron/ion regulation in heterostructures and provide a potential route to develop high-performance lithium-ion storage materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104504, "DOI": "10.1002/advs.202104504", "DOI Link": "http://dx.doi.org/10.1002/advs.202104504", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740626500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lazouski, N; Chung, MJ; Williams, K; Gala, ML; Manthiram, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lazouski, Nikifar; Chung, Minju; Williams, Kindle; Gala, Michal L.; Manthiram, Karthish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-aqueous gas diffusion electrodes for rapid ammonia synthesis from nitrogen and water-splitting-derived hydrogen", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical transformations in non-aqueous solvents are important for synthetic and energy storage applications. Use of non-polar gaseous reactants such as nitrogen and hydrogen in non-aqueous solvents is limited by their low solubility and slow transport. Conventional gas diffusion electrodes improve the transport of gaseous species in aqueous electrolytes by facilitating efficient gas-liquid contacting in the vicinity of the electrode. Their use with non-aqueous solvents is hampered by the absence of hydrophobic repulsion between the liquid phase and carbon fibre support. Herein we report a method to overcome transport limitations in tetrahydrofuran using a stainless steel cloth-based support for ammonia synthesis paired with hydrogen oxidation. An ammonia partial current density of 8.8 +/- 1.4 mA cm(-2) and a Faradaic efficiency of 35 +/- 6% are obtained using a lithium-mediated approach. Hydrogen oxidation current densities of up to 25 mA cm(-2) are obtained in two non-aqueous solvents with near-unity Faradaic efficiency. The approach is then applied to produce ammonia from nitrogen and water-splitting-derived hydrogen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 463, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41929-020-0455-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0455-8", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530181400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Z; Chen, C; Wu, WT; Wang, FF; Du, LL; Zhang, XY; Xiong, Y; He, XW; Cai, YJ; Kwok, RTK; Lam, JWY; Gao, XK; Sun, PC; Phillips, DL; Ding, D; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Zheng; Chen, Chao; Wu, Wenting; Wang, Fenfen; Du, Lili; Zhang, Xiaoyan; Xiong, Yu; He, Xuewen; Cai, Yuanjing; Kwok, Ryan T. K.; Lam, Jacky W. Y.; Gao, Xike; Sun, Pingchuan; Phillips, David Lee; Ding, Dan; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient photothermal nulloagent achieved by harvesting energy via excited-state intramolecular motion within nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exciting applications of molecular motion are still limited and are in urgent pursuit, although some fascinating concepts such as molecular motors and molecular machines have been proposed for years. Utilizing molecular motion in a nulloplatform for practical application has been scarcely explored due to some unconquered challenges such as how to achieve effective molecular motion in the aggregate state within nulloparticles. Here, we introduce a class of near infrared-absorbing organic molecules with intramolecular motion-induced photothermy inside nulloparticles, which enables most absorbed light energy to dissipate as heat. Such a property makes the nulloparticles a superior photoacoustic imaging agent compared to widely used methylene blue and semiconducting polymer nulloparticles and allow them for high-contrast photoacoustic imaging of tumours in live mice. This study not only provides a strategy for developing advanced photothermal/photoacoustic imaging nulloagents, but also enables molecular motion in a nulloplatform to find a way for practical application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 768, "DOI": "10.1038/s41467-019-08722-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08722-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458754700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, GK; Adamo, G; Tian, JY; Klein, M; Krishnamoorthy, HNS; Feltri, E; Wang, HB; Soci, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Guankui; Adamo, Giorgio; Tian, Jingyi; Klein, Maciej; Krishnamoorthy, Harish N. S.; Feltri, Elena; Wang, Hebin; Soci, Cesare", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite metasurfaces with large superstructural chirality", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent attempts to synthesize hybrid perovskites with large chirality have been hampered by large size mismatch and weak interaction between their structure and the wavelength of light. Here we adopt a planar nullostructure design to overcome these limitations and realize all-dielectric perovskite metasurfaces with giant superstructural chirality. We identify a direct spectral correspondence between the near- and the far- field chirality, and tune the electric and magnetic multipole moments of the resonullt chiral metamolecules to obtain large anisotropy factor of 0.49 and circular dichroism of 6350 mdeg. Simulations show that larger area metasurfaces could yield even higher optical activity, approaching the theoretical limits. Our results clearly demonstrate the advantages of nullostructrure engineering for the implementation of perovskite chiral photonic, optoelectronic, and spintronic devices. Though chiral hybrid organic-inorganic perovskites are attractive for next-generation optoelectronics, imparting strong chirality through chemical synthesis has proved challenging. Here, the authors report all-dielectric perovskite metasurfaces with giant superstructural chirality via planar nullostructuring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1551, "DOI": "10.1038/s41467-022-29253-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29253-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772575300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, ZY; Nomoto, K; Li, WS; Tanen, N; Sasaki, K; Kuramata, A; Nakamura, T; Jena, D; Xing, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zongyang; Nomoto, Kazuki; Li, Wenshen; Tanen, Nicholas; Sasaki, Kohei; Kuramata, Akito; Nakamura, Tohru; Jena, Debdeep; Xing, Huili Grace", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement-Mode Ga2O3 Vertical Transistors With Breakdown Voltage > 1 kV", "Source Title": "IEEE ELECTRON DEVICE LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-voltage vertical Ga2O3 MISFETs are developed employing halide vapor phase epitaxial (HVPE) layers on bulk Ga2O3 (001) substrates. The low charge concentration of similar to 10(16) cm(-3) in the n-drift region allows three terminal breakdown voltages to reach up to 1057 V without field plates. The devices operate in the enhancement mode (E-mode) with a threshold voltage of similar to 1.2-2.2V, a current on/off ratio of similar to 108, an on resistance of similar to 13-18m Omega.m(2), and an output current of > 300 A/cm(2). This is the first report of high-voltage vertical Ga2O3 transistors with E-mode operation, a significant milestone toward realizing Ga2O3 based power electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 39, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 869, "End Page": 872, "Article Number": null, "DOI": "10.1109/LED.2018.2830184", "DOI Link": "http://dx.doi.org/10.1109/LED.2018.2830184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437086800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, XL; Zhang, X; Xie, M; Xiong, LK; Sun, H; Lu, YT; Mu, QQ; Rummeli, MH; Xu, JB; Li, S; Zhong, J; Deng, Z; Ma, BY; Cheng, T; Goddard, WA ; Peng, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Xulan; Zhang, Xiang; Xie, Miao; Xiong, Likun; Sun, Hao; Lu, Yongtao; Mu, Qiaoqiao; Rummeli, Mark H.; Xu, Jiabin; Li, Shuo; Zhong, Jun; Deng, Zhao; Ma, Bingyun; Cheng, Tao; Goddard, William A., III; Peng, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks are promising catalysts for CO2 electroreduction, yet limited by their poor conductivity and stability. Here, Au nulloneedles are inserted into the metalloporphyrin framework to activate C-C coupling and stabilize the structure for much enhanced ethylene production. Direct implementation of metal-organic frameworks as the catalyst for CO2 electroreduction has been challenging due to issues such as poor conductivity, stability, and limited > 2e(-) products. In this study, Au nulloneedles are impregnated into a cupric porphyrin-based metal-organic framework by exploiting ligand carboxylates as the Au3+ -reducing agent, simultaneously cleaving the ligand-node linkage. Surprisingly, despite the lack of a coherent structure, the Au-inserted framework affords a superb ethylene selectivity up to 52.5% in Faradaic efficiency, ranking among the best for metal-organic frameworks reported in the literature. Through operando X-ray, infrared spectroscopies and density functional theory calculations, the enhanced ethylene selectivity is attributed to Au-activated nitrogen motifs in coordination with the Cu centers for C-C coupling at the metalloporphyrin sites. Furthermore, the Au-inserted catalyst demonstrates both improved structural and catalytic stability, ascribed to the altered charge conduction path that bypasses the incoherent framework. This study underlines the modulation of reticular metalloporphyrin structure by metal impregnation for steering the CO2 reduction reaction pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 63, "DOI": "10.1038/s41467-021-27768-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27768-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744540800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wen, XX; Chen, C; Lu, SC; Li, KH; Kondrotas, R; Zhao, Y; Chen, WH; Gao, L; Wang, C; Zhang, J; Niu, GD; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wen, Xixing; Chen, Chao; Lu, Shuaicheng; Li, Kanghua; Kondrotas, Rokas; Zhao, Yang; Chen, Wenhao; Gao, Liang; Wang, Chong; Zhang, Jun; Niu, Guangda; Tang, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapor transport deposition of antimony selenide thin film solar cells with 7.6% efficiency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimony selenide is an emerging promising thin film photovoltaic material thanks to its binary composition, suitable bandgap, high absorption coefficient, inert grain boundaries and earth-abundant constituents. However, current devices produced from rapid thermal evaporation strategy suffer from low-quality film and unsatisfactory performance. Herein, we develop a vapor transport deposition technique to fabricate antimony selenide films, a technique that enables continuous and low-cost manufacturing of cadmium telluride solar cells. We improve the crystallinity of antimony selenide films and then successfully produce superstrate cadmium sulfide/antimony selenide solar cells with a certified power conversion efficiency of 7.6%, a net 2% improvement over previous 5.6% record of the same device configuration. We analyze the deep defects in antimony selenide solar cells, and find that the density of the dominullt deep defects is reduced by one order of magnitude using vapor transport deposition process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 473, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2179, "DOI": "10.1038/s41467-018-04634-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04634-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434125100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Lu, D; Wang, JR; Tu, WG; Wu, D; Koh, SW; Gao, PQ; Xu, ZCJ; Deng, SL; Zhou, Y; You, B; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Hu; Lu, Dan; Wang, Jiarui; Tu, Wenguang; Wu, Dan; Koh, See Wee; Gao, Pingqi; Xu, Zhichuan J.; Deng, Sili; Zhou, Yan; You, Bo; Li, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raw biomass electroreforming coupled to green hydrogen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the tremendous progress of coupling organic electrooxidation with hydrogen generation in a hybrid electrolysis, electroreforming of raw biomass coupled to green hydrogen generation has not been reported yet due to the rigid polymeric structures of raw biomass. Herein, we electrooxidize the most abundant natural amino biopolymer chitin to acetate with over 90% yield in hybrid electrolysis. The overall energy consumption of electrolysis can be reduced by 15% due to the thermodynamically and kinetically more favorable chitin oxidation over water oxidation. In obvious contrast to small organics as the anodic reactant, the abundance of chitin endows the new oxidation reaction excellent scalability. A solar-driven electroreforming of chitin and chitin-containing shrimp shell waste is coupled to safe green hydrogen production thanks to the liquid anodic product and suppression of oxygen evolution. Our work thus demonstrates a scalable and safe process for resource upcycling and green hydrogen production for a sustainable energy future. The scale-up of the coupling of water electroreduction (HER) with organic electrooxidation remains challenging. Here the authors address this challenge by coupling HER with electrooxidation of raw biomass chitin, cogenerating acetate and green hydrogen safely at high current density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2008, "DOI": "10.1038/s41467-021-22250-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22250-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636903700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kraft, MA; Ohno, S; Zinkevich, T; Koerver, R; Culver, SP; Fuchs, T; Senyshyn, A; Indris, S; Morgan, BJ; Zeier, WG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kraft, Marvin A.; Ohno, Saneyuki; Zinkevich, Tatiana; Koerver, Raimund; Culver, Sean P.; Fuchs, Till; Senyshyn, Anatoliy; Indris, Sylvio; Morgan, Benjamin J.; Zeier, Wolfgang G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li6+x P1-xGexS5l for All -Solid-State Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state batteries with inorganic solid electrolytes are currently being discussed as a more reliable and safer future alternative to the current lithium-ion battery technology. To compete with state-of-the-art lithium-ion batteries, solid electrolytes with higher ionic conductivities are needed, especially if thick electrode configurations are to be used. In the search for optimized ionic conductors, the lithium argyrodites have attracted a lot of interest. Here, we systematically explore the influence of aliovalent substitution in Li6+xP1-xGexS5I using a combination of X-ray and neutron diffraction, as well as impedance spectroscopy and nuclear magnetic resonullce. With increasing Ge content, an anion site disorder is induced and the activation barrier for ionic motion drops significantly, leading to the fastest lithium argyrodite so far with 5.4 +/- 0.8 mS cm(-1) in a cold-pressed state and 18.4 +/- 2.7 mS cm(-1) upon sintering. These high ionic conductivities allow for successful implementation within a thick-electrode solid-state capacity fade over 150 cycles. The observed changes in the activation barrier and changing site approach toward designing better performing solid electrolytes. battery that shows negligible disorder provide an additional approach toward designing better performing solid electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2018, "Volume": 140, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16330, "End Page": 16339, "Article Number": null, "DOI": "10.1021/jacs.8b10282", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b10282", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451933100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Djellabi, R; Noureen, L; Dao, V; Meroni, D; Falletta, E; Dionysiou, DDD; Bianchi, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Djellabi, Ridha; Noureen, Laila; Dao, Van-Duong; Meroni, Daniela; Falletta, Ermelinda; Dionysiou, Dionysios D. D.; Bianchi, Claudia L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances and challenges of emerging solar-driven steam and the contribution of photocatalytic effect", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, solar-driven steam materials and systems for water desalination and decontamination have received increasing attention from the scientific community. Notwithstanding the fundamental scientific achievements reached on this topic, numerous technological concerns still remain to be addressed, including heat loss, radiation reflection, low degree of purification of condensed water, biofouling, and salt accumulation on the surface. In this report, we critically reviewed the most recent advances in the engineering of solar-driven steam materials and the main technology challenges which may limit their large-scale application. First, different classes of materials, e.g., inorganic semiconductors, carbonaceous materials, polymers, and surface plasmon resonullce metals, are compared in terms of the mechanistic pathways to generate steam vapor and condensed to freshwater on their surface. Then, the main approaches to tackle the technology shortcomings of solar-driven steam systems are discussed in depth. For instance, in terms of salt accumulation, several strategies were proposed such as solar-driven surfaces with ion exchange or/and salt dissolving, an inversion system to remove the salt from the active surface, and salt rejection surfaces. To enhance the photothermal process and limit the reflection of light, thermal insulators, reflective layers, and 3D/pyramidal photoabsorbers were proved to be excellent strategies. The review addresses as well the recent research regarding hybrid systems by incorporating photocatalysis effect in solar-driven water evaporators. Photocatalyst addition endows the surface of evaporators with unique properties, such as the radical oxidation of organic pollutants and microbial inactivation, resulting in reduced fast biofouling and condensed waters with higher purity. Finally, the remaining challenges and prospects for future developments are critically discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 431, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134024, "DOI": "10.1016/j.cej.2021.134024", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.134024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771999300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, HH; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Ho-Hyun; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni0.9Co0.05Mn0.05]O2 Cathode for Lithium-Ion Batteries", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To address the growing demand for energy density, the Ni-rich layered [Ni0.90Co0.05Mn0.05]O-2 cathode has been synthesized and its electrochemical performance in lithium-ion cells has been benchmarked against a lower-Ni content Li[Ni0.6Co0.2Mn0.2]O-2 cathode. Li[Ni0.90Co0.05Mn0.05]O-2 delivers a high discharge capacity of 227 mA h g(-1) compared to a capacity of 189 mA h g(-1) for Li[Ni0.6Co0.2Mn0.2]O-2 when cycled up to a lower cutoff voltage of 4.3 V, making it an appealing candidate for electric vehicles. With an increase in the charge cutoff voltage to 4.5 V, Li[Ni0.90Co0.05Mn0.05]O-2 displays a capacity of 238 mA h g(-1) compared to a capacity of 208 mA. h g(-1) for Li[Ni0.6Co0.2Mn0.2]O-2. Although Li[Ni0.90Co0.05Mn0.05]O-2 suffers during cycling from the usual rapid capacity fade in a manner similar to that of LiNiO2, 87 and 81% of the initial capacity could still be retained after 100 cycles even after cycling to higher cutoff voltages of 4.3 and 4.5 V, respectively. A comparison of Li[Ni0.90Co0.05Mn0.05]O-2 and Li[Ni0.6Co0.2Mn0.2]O-2 reveals that the capacity fade of Li[Ni0.90Co0.05Mn0.05]O-2 originates largely from the anisotropic volume change and subsequent microcrack propagation in the bulk and NiO-like rock salt impurity phase formation on the particle surface, which are exacerbated at 4.5 V. Future work with appropriate doping and surface modification could improve further the performance of Li[Ni0.90Co0.05Mn0.05]O-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2017, "Volume": 29, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8486, "End Page": 8493, "Article Number": null, "DOI": "10.1021/acs.chemmater.7b03268", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.7b03268", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412965800050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, RJ; Wu, XH; Kim, M; Shi, JP; Sonde, S; Tao, L; Zhang, YF; Lee, JC; Akinwande, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Ruijing; Wu, Xiaohan; Kim, Myungsoo; Shi, Jianping; Sonde, Sushant; Tao, Li; Zhang, Yanfeng; Lee, Jack C.; Akinwande, Deji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomristor: Nonvolatile Resistance Switching in Atomic Sheets of Transition Metal Dichalcogenides", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, two-dimensional (2D) atomic sheets have inspired new ideas in nulloscience including topologically protected charge transport,(1'2) spatially separated excitons,(3) and strongly anisotropic heat transport.(4) Here, we report the intriguing observation of stable nonvolatile resistance switching (NVRS) in single-layer atomic sheets sandwiched between metal electrodes. NVRS is observed in the prototypical semiconducting (MX2, M = Mo, W; and X = S, Se) transitional metal dichalcogenides (TMDs),(5) which alludes to the universality of this phenomenon in TMD monolayers and offers forming-free switching. This observation of NVRS phenomenon, widely attributed to ionic diffusion, filament, and interfacial redox in bulk oxides and electrolytes,(6-9) inspires new studies on defects, ion transport, and energetics at the sharp interfaces between atomically thin sheets and conducting electrodes. Our findings overturn the contemporary thinking that nonvolatile switching is not scalable to subnullometre owing to leakage currents.(10) Emerging device concepts in nonvolatile flexible memory fabrics, and brain-inspired (neuromorphic) computing could benefit substantially from the wide 2D materials design space. A new major application, zero-static power radio frequency (RF) switching, is demonstrated with a monolayer switch operating to 50 GHz.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 434, "End Page": 441, "Article Number": null, "DOI": "10.1021/acs.nullolett.7b04342", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.7b04342", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000420000000058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Zheng, XP; Deng, YH; Zhao, JJ; Chen, ZL; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qi; Zheng, Xiaopeng; Deng, Yehao; Zhao, Jingjing; Chen, Zhaolai; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing the α-Phase of CsPbI3 Perovskite by Sulfobetaine Zwitterions in One-Step Spin-Coating Films", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic cesium lead halide perovskites (CsPbI3) are promising materials for efficient wide-bandgap perovskite solar cells, but they suffer from a phase transition from black alpha phase to yellow delta phase at room temperature. Here, we report a facile method to stabilize the alpha-phase CsPbI3 films viaa single-step film deposition process. A small amount (similar to 1.5 wt %) of sulfobetaine zwitterion mixed in CsPbI3 precursor solution could facilitate the formation of black-phase CsPbI3 films that show significantly improved phase stability in air. The black-phase stabilization can be explained by the formation of small CsPbI3 grains with average size of similar to 30 nm, which increased the grain surface area to stabilizes the a phase. The zwitterions were found to impede the crystallization of CsPbI3 perovskite films via electrostatic interaction with the ions and colloids in the CsPbI3 precursor solution. Solar cells using these zwitterion-stabilized perovskite films showed stabilized power conversion efficiency of 11.4% under 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 474, "Times Cited, All Databases": 499, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": 382, "Article Number": null, "DOI": "10.1016/j.joule.2017.07.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.07.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425180300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, M; Chen, W; Lei, Y; Yu, H; Lin, YX; Terrones, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Min; Chen, Wei; Lei, Yu; Yu, Hao; Lin, Yuxiao; Terrones, Mauricio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic Construction of Ferrite Quantum Dot/Graphene Heterostructure for Enhancing Ion/Charge Transfer in Supercapacitors", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spinel ferrites are regarded as promising electrode materials for supercapacitors (SCs) in virtue of their low cost and high theoretical specific capacitances. However, bulk ferrites suffer from limited electrical conductivity, sluggish ion transport, and inadequate active sites. Therefore, rational structural design and composition regulation of the ferrites are approaches to overcome these limitations. Herein, a general biomimetic mineralization synthetic strategy is proposed to synthesize ferrite (XFe2O4, X = Ni, Co, Mn) quantum dot/graphene (QD/G) heterostructures. Anchoring ferrite QD on the graphene sheets not only strengthens the structural stability, but also forms the electrical conductivity network needed to boost the ion diffusion and charge transfer. The optimized NiFe2O4 QD/G heterostructure exhibits specific capacitances of 697.5 F g(-1) at 1 A g(-1), and exceptional cycling performance. Furthermore, the fabricated symmetrical SCs deliver energy densities of 24.4 and 17.4 Wh kg(-1) at power densities of 499.3 and 4304.2 W kg(-1), respectively. Density functional theory calculations indicate the combination of NiFe2O4 QD and graphene facilitates the adsorption of potassium atoms, ensuring rapid ion/charge transfer. This work enriches the application of the biomimetic mineralization synthesis and provides effective strategies for boosting ion/charge transfer, which may offer a new way to develop advanced electrodes for SCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 35, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300940", "DOI Link": "http://dx.doi.org/10.1002/adma.202300940", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961665900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, M; Li, QZ; Yan, XW; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Miao; Li, Qi-Zhi; Yan, Xun-Wang; Wang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of phonon-mediated superconductivity in borophene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductivity in two-dimensional compounds is widely studied, not only because of its application in constructing nullo-superconducting devices, but also for general scientific interest. Very recently, borophene (a two-dimensional boron sheet) has been successfully grown on the Ag(111) surface, through direct evaporation of a pure boron source. The experiment unveiled two types of borophene structures, namely beta(12) and chi(3). Herein, we employed density-functional first-principles calculations to investigate the electron-phonon coupling and superconductivity in both structures of borophene. The band structures of beta(12) and chi(3) borophenes exhibit inherent metallicity. We found that electron-phonon coupling constants in the two compounds are larger than that in MgB2. The superconducting transition temperatures were determined to be 18.7 K and 24.7 K through the McMillian-Allen-Dynes formula. These temperatures are much higher than the theoretically predicted 8.1 K and experimentally observed 7.4 K superconductivity in graphene. Our findings will enrich nullo-superconducting device applications and boron-related materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2017, "Volume": 95, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24505, "DOI": "10.1103/PhysRevB.95.024505", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.024505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391851800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, Y; Gan, ZX; Zhang, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yong; Gan, Zhongxue; Zhang, Shou-Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Thermoelectric Performance and Anomalous Seebeck Effects in Topological Insulators", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the thermoelectric figure of merit zT is one of the greatest challenges in material science. The recent discovery of topological insulators (TIs) offers new promise in this prospect. In this work, we demonstrate theoretically that zT is strongly size dependent in TIs, and the size parameter can be tuned to enhance zT to be significantly greater than 1. Furthermore, we show that the lifetime of the edge states in TIs is strongly energy dependent, leading to large and anomalous Seebeck effects with an opposite sign to the Hall effect. These striking properties make TIs a promising material for thermoelectric science and technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2014, "Volume": 112, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 226801, "DOI": "10.1103/PhysRevLett.112.226801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.226801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337277700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shevchik, SA; Kenel, C; Leinenbach, C; Wasmer, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shevchik, S. A.; Kenel, C.; Leinenbach, C.; Wasmer, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acoustic emission for in situ quality monitoring in additive manufacturing using spectral convolutional neural networks", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing, also known as 3D printing, is a new technology that obliterates the geometrical limits of the produced workpieces and promises low running costs as compared to traditional manufacturing methods. Hence, additive manufacturing technology has high expectations in industry. Unfortunately, the lack of a proper quality monitoring prohibits the penetration of this technology into an extensive practice. This work investigates the feasibility of using acoustic emission for quality monitoring and combines a sensitive acoustic emission sensor with machine learning. The acoustic signals were recorded using a fiber Bragg grating sensor during the powder bed additive manufacturing process in a commercially available selective laser melting machine. The process parameters were intentionally tuned to invoke different processing regimes that lead to the formation of different types and concentrations of pores (1.42 +/- 0.85 %, 0.3 +/- 0.18 % and 0.07 +/- 0.02 %) inside the workpiece. According to this poor, medium and high part qualities were defined. The acoustic signals collected during processing were grouped accordingly and divided into two separate datasets; one for the training and one for the testing. The acoustic features were the relative energies of the narrow frequency bands of the wavelet packet transform, extracted from all the signals. The classifier, based on spectral convolutional neural network, was trained to differentiate the acoustic features of dissimilar quality. The confidence in classifications varies between 83 and 89 %. In view of the narrow range of porosity, the results can be considered as promising and they showed the feasibility of the quality monitoring using acoustic emission with the sub-layer spatial resolution. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 598, "End Page": 604, "Article Number": null, "DOI": "10.1016/j.addma.2017.11.012", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2017.11.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751300060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharma, B; Gatóo, A; Bock, M; Ramage, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharma, Bhavna; Gatoo, Ana; Bock, Maximilian; Ramage, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineered bamboo for structural applications", "Source Title": "CONSTRUCTION AND BUILDING MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bamboo is a rapidly renewable material that has many applications in construction. Engineered bamboo products result from processing the raw bamboo culm into a laminated composite, similar to glue-laminated timber products. These products allow the material to be used in standardised sections and have less inherent variability than the natural material. The present work investigates the mechanical properties of two types of commercially available products - bamboo scrimber and laminated bamboo sheets - and compares these to timber and engineered timber products. It is shown that engineered bamboo products have properties that are comparable to or surpass that of timber and timber-based products. Potential limitations to use in structural design are also discussed. The study contributes to a growing body of research on engineered bamboo and presents areas in which further investigation is needed. (c) 2015 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2015, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 66, "End Page": 73, "Article Number": null, "DOI": "10.1016/j.conbuildmat.2015.01.077", "DOI Link": "http://dx.doi.org/10.1016/j.conbuildmat.2015.01.077", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352672500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gosvami, NN; Bares, JA; Mangolini, F; Konicek, AR; Yablon, DG; Carpick, RW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gosvami, N. N.; Bares, J. A.; Mangolini, F.; Konicek, A. R.; Yablon, D. G.; Carpick, R. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanisms of antiwear tribofilm growth revealed in situ by single-asperity sliding contacts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc dialkyldithiophosphates (ZDDPs) form antiwear tribofilms at sliding interfaces and are widely used as additives in automotive lubricants. The mechanisms governing the tribofilm growth are not well understood, which limits the development of replacements that offer better performance and are less likely to degrade automobile catalytic converters over time. Using atomic force microscopy in ZDDP-containing lubricant base stock at elevated temperatures, we monitored the growth and properties of the tribofilms in situ in well-defined single-asperity sliding nullocontacts. Surface-based nucleation, growth, and thickness saturation of patchy tribofilms were observed. The growth rate increased exponentially with either applied compressive stress or temperature, consistent with a thermally activated, stress-assisted reaction rate model. Although some models rely on the presence of iron to catalyze tribofilm growth, the films grew regardless of the presence of iron on either the tip or substrate, highlighting the critical role of stress and thermal activation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2015, "Volume": 348, "Issue": 6230, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 102, "End Page": 106, "Article Number": null, "DOI": "10.1126/science.1258788", "DOI Link": "http://dx.doi.org/10.1126/science.1258788", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352079500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ross, MB; Dinh, CT; Li, Y; Kim, D; De Luna, P; Sargent, EH; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ross, Michael B.; Cao Thang Dinh; Li, Yifan; Kim, Dohyung; De Luna, Phil; Sargent, Edward H.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Cu Enrichment Enables Designer Syngas Electrosynthesis from CO2", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using renewable energy to recycle CO2 provides an opportunity to both reduce net CO2 emissions and synthesize fuels and chemical feedstocks. It is of central importance to design electrocatalysts that both are efficient and can access a tunable spectrum of products. Syngas, a mixture of carbon monoxide (CO) and hydrogen (H-2), is an important chemical precursor that can be converted downstream into small molecules or larger hydrocarbons by fermentation or thermochemistry. Many processes that utilize syngas require different syngas compositions: we therefore pursued the rational design of a family of electrocatalysts that can be programmed to synthesize different designer syngas ratios. We utilize in situ surface enhanced Raman spectroscopy and first-principles density functional theory calculations to develop a systematic picture of CO* binding on Cu-enriched Au surface model systems. Insights from these model systems are then translated to nullostructured electrocatalysts, whereby controlled Cu enrichment enables tunable syngas production while maintaining current densities greater than 20 mA/cm(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2017, "Volume": 139, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9359, "End Page": 9363, "Article Number": null, "DOI": "10.1021/jacs.7b04892", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b04892", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405642400040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, DY; Gao, AJ; Cen, KH; Zhang, J; Cao, XB; Ma, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Dengyu; Gao, Anjiang; Cen, Kehui; Zhang, Jie; Cao, Xiaobing; Ma, Zhongqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation of biomass torrefaction based on three major components: Hemicellulose, cellulose, and lignin", "Source Title": "ENERGY CONVERSION AND MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, torrefaction of hemicellulose, cellulose, and lignin were studied at a series of torrefaction temperatures (210, 240, 270, and 300 degrees C) based on the properties of their three-phase products, namely solid, liquid (water and tar), and gaseous products. Among the three biomass components, significant difference of torrefaction characteristics was found due to their different molecular structures. For the solid product, hemicellulose presented lowest yield from 85.65% to 41.54% as the temperature increased because of the poor thermostability, thereby showing obvious variations in carbon and oxygen contents. For the gaseous product, CO2, followed by CO, were the dominullt gaseous components in all torrefaction conditions including different feedstock and temperatures; also a small number of other components (H-2 and CH4) were produced during torrefaction of lignin. The liquid product was composed of water and a small amount of tar. For the tar product, acids and ketones were the dominullt components in the torrefaction of hemicellulose, while anhydrosugar in the tonefaction of cellulose, and phenols in the torrefaction of lignin. As the temperature increased from 210 degrees C to 300 degrees C, about 19.76-71.11%, 5.85-33.27%, and 16.28-44.89% of oxygen from hemicellulose, cellulose, and lignin, respectively, was transformed into the liquid and gaseous products. Dehydration reaction and volatilization of the oxygenated gaseous product were the two dominullt deoxygenation pathways, and the water, CO2, and CO were the dominullt carriers of oxygen migration. In contrast to oxygen, only a small amount of carbon was transferred into tar product, followed by gaseous product, consequently the solid samples still retained most of the energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2018, "Volume": 169, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": 237, "Article Number": null, "DOI": "10.1016/j.enconman.2018.05.063", "DOI Link": "http://dx.doi.org/10.1016/j.enconman.2018.05.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436885900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, HYX; Wu, SC; Wu, ZK; Kang, GZ; Peng, X; Withers, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Hongyixi; Wu, Shengchuan; Wu, Zhengkai; Kang, Guozheng; Peng, Xin; Withers, Philip J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A machine-learning fatigue life prediction approach of additively manufactured metals", "Source Title": "ENGINEERING FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The defects retained during laser powder bed fusion determine the poor fatigue performance and pronounced lifetime scatter of the fabricated metallic components. In this work, a machine learning method was adopted to explore the influence of defect location, size, and morphology on the fatigue life of a selective laser melted Ti-6Al-4 V alloy. Both the high cycle fatigue post mortem examination and synchrotron X-ray tomography were combined to acquire the geometric features of the critical defects, which were trained using a support vector machine (SVM). To accelerate the optimization process, the grid search approach with cross validation was selected for fitting the model parameters. It is found that the coefficient of determination between the predicted and experimental fatigue lives can reach up to 0.99, indicating that the SVM model shows strong training ability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 242, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107508, "DOI": "10.1016/j.engfracmech.2020.107508", "DOI Link": "http://dx.doi.org/10.1016/j.engfracmech.2020.107508", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613933000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, C; Fezzaa, K; Cunningham, RW; Wen, HD; De Carlo, F; Chen, LY; Rollett, AD; Sun, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Cang; Fezzaa, Kamel; Cunningham, Ross W.; Wen, Haidan; De Carlo, Francesco; Chen, Lianyi; Rollett, Anthony D.; Sun, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Real-time monitoring of laser powder bed fusion process using high-speed X-ray imaging and diffraction", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We employ the high-speed synchrotron hard X-ray imaging and diffraction techniques to monitor the laser powder bed fusion (LPBF) process of Ti-6Al-4V in situ and in real time. We demonstrate that many scientifically and technologically significant phenomena in LPBF, including melt pool dynamics, powder ejection, rapid solidification, and phase transformation, can be probed with unprecedented spatial and temporal resolutions. In particular, the keyhole pore formation is experimentally revealed with high spatial and temporal resolutions. The solidification rate is quantitatively measured, and the slowly decrease in solidification rate during the relatively steady state could be a manifestation of the recalescence phenomenon. The high-speed diffraction enables a reasonable estimation of the cooling rate and phase transformation rate, and the diffusionless transformation from beta to alpha' phase is evident. The data present here will facilitate the understanding of dynamics and kinetics in metal LPBF process, and the experiment platform established will undoubtedly become a new paradigm for future research and development of metal additive manufacturing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 591, "Times Cited, All Databases": 677, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3602, "DOI": "10.1038/s41598-017-03761-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-03761-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403314500050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Mishchenko, A; Yu, GL; Khestanova, E; Rooney, AP; Prestat, E; Kretinin, AV; Blake, P; Shalom, MB; Woods, C; Chapman, J; Balakrishnull, G; Grigorieva, IV; Novoselov, KS; Piot, BA; Potemski, M; Watanabe, K; Taniguchi, T; Haigh, SJ; Geim, AK; Gorbachev, RV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Y.; Mishchenko, A.; Yu, G. L.; Khestanova, E.; Rooney, A. P.; Prestat, E.; Kretinin, A. V.; Blake, P.; Shalom, M. B.; Woods, C.; Chapman, J.; Balakrishnull, G.; Grigorieva, I. V.; Novoselov, K. S.; Piot, B. A.; Potemski, M.; Watanabe, K.; Taniguchi, T.; Haigh, S. J.; Geim, A. K.; Gorbachev, R. V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quality Heterostructures from Two-Dimensional Crystals Unstable in Air by Their Assembly in Inert Atmosphere", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many layered materials can be cleaved down to individual atomic planes, similar to graphene, but only a small minority of them are stable under ambient conditions. The rest react and decompose in air, which has severely hindered their investigation and potential applications. Here we introduce a remedial approach based on cleavage, transfer, alignment, and encapsulation of air-sensitive crystals, all inside a controlled inert atmosphere. To illustrate the technology, we choose two archetypal two-dimensional crystals that are of intense scientific interest but are unstable in air: black phosphorus and niobium diselenide. Our field-effect devices made from their monolayers are conductive and fully stable under ambient conditions, which is in contrast to the counterparts processed in air. NbSe2 remains superconducting down to the monolayer thickness. Starting with a trilayer, phosphorene devices reach sufficiently high mobilities to exhibit Landau quantization. The approach offers a venue to significantly expand the range of experimentally accessible two-dimensional crystals and their heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4914, "End Page": 4921, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b00648", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b00648", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359613700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, LY; Sinitsyn, NA; Chen, WB; Yuan, JT; Zhang, J; Lou, J; Crooker, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Luyi; Sinitsyn, Nikolai A.; Chen, Weibing; Yuan, Jiangtan; Zhang, Jing; Lou, Jun; Crooker, Scott A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-lived nullosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recently discovered monolayer transition metal dichalcogenides (TMDCs) provide a fertile playground to explore new coupled spin-valley physics(1-3). Although robust spin and valley degrees of freedom are inferred from polarized photoluminescence (PL) experiments(4-8), PL timescales are necessarily constrained by short-lived (3-100 ps) electron-hole recombination(9,10). Direct probes of spin/valley polarization dynamics of resident carriers in electron (or hole)-doped TMDCs, which may persist long after recombination ceases, are at an early stage(11-13). Here we directly measure the coupled spin-valley dynamics in electron-doped MoS2 and WS2 monolayers using optical Kerr spectroscopy, and reveal very long electron spin lifetimes, exceeding 3 ns at 5 K (two to three orders of magnitude longer than typical exciton recombination times). In contrast with conventional III-V or II-VI semiconductors, spin relaxation accelerates rapidly in small transverse magnetic fields. Supported by a model of coupled spin-valley dynamics, these results indicate a novel mechanism of itinerant electron spin dephasing in the rapidly fluctuating internal spin-orbit field in TMDCs, driven by fast inter-valley scattering. Additionally, a long-lived spin coherence is observed at lower energies, commensurate with localized states. These studies provide insight into the physics underpinning spin and valley dynamics of resident electrons in atomically thin TMDCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 11, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 830, "End Page": "U187", "Article Number": null, "DOI": "10.1038/NPHYS3419", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3419", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362188600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Merinov, BV; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuanyue; Merinov, Boris V.; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of low sodium capacity in graphite and generally weak substrate binding of Na and Mg among alkali and alkaline earth metals", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is well known that graphite has a low capacity for Na but a high capacity for other alkali metals. The growing interest in alternative cation batteries beyond Li makes it particularly important to elucidate the origin of this behavior, which is not well understood. In examining this question, we find a quite general phenomenon: among the alkali and alkaline earth metals, Na and Mg generally have the weakest chemical binding to a given substrate, compared with the other elements in the same column of the periodic table. We demonstrate this with quantum mechanics calculations for a wide range of substrate materials (not limited to C) covering a variety of structures and chemical compositions. The phenomenon arises from the competition between trends in the ionization energy and the ion-substrate coupling, down the columns of the periodic table. Consequently, the cathodic voltage for Na and Mg is expected to be lower than those for other metals in the same column. This generality provides a basis for analyzing the binding of alkali and alkaline earth metal atoms over a broad range of systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2016, "Volume": 113, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3735, "End Page": 3739, "Article Number": null, "DOI": "10.1073/pnas.1602473113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1602473113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373354000032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Xu, J; Zhang, YM; Wang, TM; Wang, QH; Li, S; Yang, ZH; Zhang, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoyue; Xu, Jing; Zhang, Yaoming; Wang, Tingmei; Wang, Qihua; Li, Song; Yang, Zenghui; Zhang, Xinrui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A stretchable, mechanically robust polymer exhibiting shape-memory-assisted self-healing and clustering-triggered emission", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing and recyclable polymer materials are being developed through extensive investigations on noncovalent bond interactions. However, they typically exhibit inferior mechanical properties. Therefore, the present study is aimed at synthesizing a polyurethane-urea elastomer with excellent mechanical properties and shape-memory-assisted self-healing behavior. In particular, the introduction of coordination and hydrogen bonds into elastomer leads to the optimal elastomer exhibiting good mechanical properties (strength, 76.37 MPa; elongation at break, 839.10%; toughness, 308.63 MJ m(-3)) owing to the phased energy dissipation mechanism involving various supramolecular interactions. The elastomer also demonstrates shape-memory properties, whereby the shape recovery force that brings damaged surfaces closer and facilitates self-healing. Surprisingly, all specimens exhibite clustering-triggered emission, with cyan fluorescence is observed under ultraviolet light. The strategy reported herein for developing multifunctional materials with good mechanical properties can be leveraged to yield stimulus-responsive polymers and smart seals. Polymers formed with non-covalent bonds are increasingly being developed, but often show inferior mechanical properties. Here, the authors report the development of high performances polyurethane-urea elastomer with shape-memory assisted self-healing behaviour", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4712, "DOI": "10.1038/s41467-023-40340-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40340-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001043364000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Q; Li, YJ; Zhang, H; Yang, JB; Han, J; Xu, T; Wang, SJ; Wang, ZS; Gao, BY; Zhao, JS; Li, XQ; Ma, XY; Zakeeruddin, SM; Sha, WEI; Li, XH; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Qi; Li, Yongjiang; Zhang, Hong; Yang, Jiabao; Han, Jian; Xu, Ting; Wang, Shuangjie; Wang, Zishuai; Gao, Bingyu; Zhao, Junsong; Li, Xiaoqiang; Ma, Xiaoyan; Zakeeruddin, Shaik Mohammed; Sha, Wei E., I; Li, Xuanhua; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable inverted perovskite solar cells with very high fill factors via incorporation of star-shaped polymer", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilizing high-efficiency perovskite solar cells (PSCs) at operating conditions remains an unresolved issue hampering its large-scale commercial deployment. Here, we report a star-shaped polymer to improve charge transport and inhibit ion migration at the perovskite interface. The incorporation of multiple chemical anchor sites in the star-shaped polymer branches strongly controls the crystallization of perovskite film with lower trap density and higher carrier mobility and thus inhibits the nonradiative recombination and reduces the charge-transport loss. Consequently, the modified inverted PSCs show an optimal power conversion efficiency of 22.1% and a very high fill factor (FF) of 0.862, corresponding to 95.4% of the Shockley-Queisser limited FF (0.904) of PSCs with a 1.59-eV bandgap. The modified devices exhibit excellent long-term operational and thermal stability at the maximum power point for 1000 hours at 45 degrees C under continuous one-sun illumination without any significant loss of efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 7, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg0633", "DOI": "10.1126/sciadv.abg0633", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg0633", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670435700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Celik, G; Kennedy, RM; Hackler, RA; Ferrandon, M; Tennakoon, A; Patnaik, S; LaPointe, AM; Ammal, SC; Heyden, A; Perras, FA; Pruski, M; Scott, SL; Poeppelmeier, KR; Sadow, AD; Delferro, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Celik, Gokhan; Kennedy, Robert M.; Hackler, Ryan A.; Ferrandon, Magali; Tennakoon, Akalanka; Patnaik, Smita; LaPointe, Anne M.; Ammal, Salai C.; Heyden, Andreas; Perras, Frederic A.; Pruski, Marek; Scott, Susannah L.; Poeppelmeier, Kenneth R.; Sadow, Aaron D.; Delferro, Massimiliano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upcycling Single-Use Polyethylene into High-Quality Liquid Products", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Our civilization relies on synthetic polymers for all aspects of modern life; yet, inefficient recycling and extremely slow environmental degradation of plastics are causing increasing concern about their widespread use. After a single use, many of these materials are currently treated as waste, underutilizing their inherent chemical and energy value. In this study, energy-rich polyethylene (PE) macromolecules are catalytically transformed into value-added products by hydrogenolysis using well-dispersed Pt nulloparticles (NPs) supported on SrTiO3 perovskite nullocuboids by atomic layer deposition. Pt/SrTiO3 completely converts PE (M-n = 8000-158,000 Da) or a single-use plastic bag (Mn = 31,000 Da) into high-quality liquid products, such as lubricants and waxes, characterized by a narrow distribution of oligomeric chains, at 170 psi H-2 and 300 degrees C under solvent-free conditions for reaction durations up to 96 h. The binding of PE onto the catalyst surface contributes to the number averaged molecular weight (Mn) and the narrow polydispersity (D) of the final liquid product. Solid-state nuclear magnetic resonullce of C-13-enriched PE adsorption studies and density functional theory computations suggest that PE adsorption is more favorable on Pt sites than that on the SrTiO3 support. Smaller Pt NPs with higher concentrations of undercoordinated Pt sites over-hydrogenolyzed PE to undesired light hydrocarbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2019, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1795, "End Page": 1803, "Article Number": null, "DOI": "10.1021/acscentsci.9b00722", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00722", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499482200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MR; Zhao, MW; Li, F; Zhou, W; Peterson, VK; Xu, XY; Shao, ZP; Gentle, I; Zhu, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mengran; Zhao, Mingwen; Li, Feng; Zhou, Wei; Peterson, Vanessa K.; Xu, Xiaoyong; Shao, Zongping; Gentle, Ian; Zhu, Zhonghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A niobium and tantalum co-doped perovskite cathode for solid oxide fuel cells operating below 500 °C", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The slow activity of cathode materials is one of the most significant barriers to realizing the operation of solid oxide fuel cells below 500 degrees C. Here we report a niobium and tantalum co-substituted perovskite SrCo0.8Nb0.1Ta0.1O3 delta as a cathode, which exhibits high electroactivity. This cathode has an area-specific polarization resistance as low as similar to 0.16 and similar to 0.68 Omega cm(2) in a symmetrical cell and peak power densities of 1.2 and 0.7Wcm(-2) in a Gd0.1Ce0.9O1.95-based anode-supported fuel cell at 500 and 450 degrees C, respectively. The high performance is attributed to an optimal balance of oxygen vacancies, ionic mobility and surface electron transfer as promoted by the synergistic effects of the niobium and tantalum. This work also points to an effective strategy in the design of cathodes for low-temperature solid oxide fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13990, "DOI": "10.1038/ncomms13990", "DOI Link": "http://dx.doi.org/10.1038/ncomms13990", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391062500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, HL; Luo, GQ; Ji, ZY; Bo, RH; Xue, ZG; Yan, DJ; Zhang, F; Bai, K; Liu, JX; Cheng, X; Pang, WB; Shen, ZM; Zhang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Honglie; Luo, Guoquan; Ji, Ziyao; Bo, Renheng; Xue, Zhaoguo; Yan, Dongjia; Zhang, Fan; Bai, Ke; Liu, Jianxing; Cheng, Xu; Pang, Wenbo; Shen, Zhangming; Zhang, Yihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly-integrated, miniaturized, stretchable electronic systems based on stacked multilayer network materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elastic stretchability and function density represent two key figures of merits for stretchable inorganic electronics. Various design strategies have been reported to provide both high levels of stretchability and function density, but the function densities are mostly below 80%. While the stacked device layout can overcome this limitation, the soft elastomers used in previous studies could highly restrict the deformation of stretchable interconnects. Here, we introduce stacked multilayer network materials as a general platform to incorporate individual components and stretchable interconnects, without posing any essential constraint to their deformations. Quantitative analyses show a substantial enhancement (e.g., by similar to 7.5 times) of elastic stretchability of serpentine interconnects as compared to that based on stacked soft elastomers. The proposed strategy allows demonstration of a miniaturized electronic system (11 mm by 10 mm), with a moderate elastic stretchability (similar to 20%) and an unprecedented areal coverage (similar to 110%), which can serve as compass display, somatosensory mouse, and physiological-signal monitor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm3785", "DOI": "10.1126/sciadv.abm3785", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm3785", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770280500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ali, M; Zhou, FL; Chen, K; Kotzur, C; Xiao, CL; Bourgeois, L; Zhang, XY; MacFarlane, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ali, Muataz; Zhou, Fengling; Chen, Kun; Kotzur, Christopher; Xiao, Changlong; Bourgeois, Laure; Zhang, Xinyi; MacFarlane, Douglas R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullostructured photoelectrochemical solar cell for nitrogen reduction using plasmon-enhanced black silicon", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia (NH3) is one of the most widely produced chemicals worldwide. It has application in the production of many important chemicals, particularly fertilizers. It is also, potentially, an important energy storage intermediate and clean energy carrier. Ammonia production, however, mostly uses fossil fuels and currently accounts for more than 1.6% of global CO2 emissions (0.57 Gt in 2015). Here we describe a solar-driven nullostructured photoelectrochemical cell based on plasmon-enhanced black silicon for the conversion of atmospheric N-2 to ammonia producing yields of 13.3 mg m(-2) h(-1) under 2 suns illumination. The yield increases with pressure; the highest observed in this work was 60 mg m(-2) h(-1) at 7 atm. In the presence of sulfite as a reactant, the process also offers a direct solar energy route to ammonium sulfate, a fertilizer of economic importance. Although the yields are currently not sufficient for practical application, there is much scope for improvement in the active materials in this cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11335, "DOI": "10.1038/ncomms11335", "DOI Link": "http://dx.doi.org/10.1038/ncomms11335", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374564400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YX; Lavacchi, A; Miller, HA; Bevilacqua, M; Filippi, J; Innocenti, M; Marchionni, A; Oberhauser, W; Wang, L; Vizza, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Y. X.; Lavacchi, A.; Miller, H. A.; Bevilacqua, M.; Filippi, J.; Innocenti, M.; Marchionni, A.; Oberhauser, W.; Wang, L.; Vizza, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullotechnology makes biomass electrolysis more energy efficient than water electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energetic convenience of electrolytic water splitting is limited by thermodynamics. Consequently, significant levels of hydrogen production can only be obtained with an electrical energy consumption exceeding 45 kWh kg(-1) H-2. Electrochemical reforming allows the overcoming of such thermodynamic limitations by replacing oxygen evolution with the oxidation of biomass-derived alcohols. Here we show that the use of an original anode material consisting of palladium nulloparticles deposited on to a three-dimensional architecture of titania nullotubes allows electrical energy savings up to 26.5 kWh kg(-1) H-2 as compared with proton electrolyte membrane water electrolysis. A net energy analysis shows that for bio-ethanol with energy return of the invested energy larger than 5.1 (for example, cellulose), the electrochemical reforming energy balance is advantageous over proton electrolyte membrane water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4036, "DOI": "10.1038/ncomms5036", "DOI Link": "http://dx.doi.org/10.1038/ncomms5036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338837500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubota, K; Asari, T; Komaba, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubota, Kei; Asari, Takuya; Komaba, Shinichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of Ti and Zn Dual-Substitution in P2 Type Na2/3Ni1/3Mn2/3O2 on Ni-Mn and Na-Vacancy Ordering and Electrochemical Properties", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy layered oxide materials containing various metals that exhibit smooth voltage curves and excellent electrochemical performances have attracted attention in the development of positive electrode materials for sodium-ion batteries. However, a smooth voltage curve can be obtained by suppression of the Na+-vacancy ordering, and therefore, transition metal slabs do not need to be more multi-element than necessary. Here, the Na+-vacancy ordering is found to be disturbed by dual substitution of Ti-IV for Mn-IV and Zn-II for Ni-II in P2-Na-2/3[Ni1/3Mn2/3]O-2. Dual-substituted Na-2/3[Ni1/4Mn1/2Ti1/6Zn1/12]O-2 demonstrates almost non-step voltage curves with a reversible capacity of 114 mAh g(-1) and less structural changes with a high crystalline structure maintained during charging and discharging. Synchrotron X-ray, neutron, and electron diffraction measurements reveal that dual-substitution with Ti-IV and Zn-II uniquely promotes in-plane Ni-II-Mn-IV ordering, which is quite different from the disordered mixing in conventional multiple metal substitution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300714", "DOI Link": "http://dx.doi.org/10.1002/adma.202300714", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000986399800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MJ; Li, HY; Zhuang, QX; He, DM; Liu, BB; Chen, C; Zhang, BX; Pauporté, T; Zang, ZG; Chen, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mengjia; Li, Haiyun; Zhuang, Qixin; He, Dongmei; Liu, Baibai; Chen, Cong; Zhang, Boxue; Pauporte, Thierry; Zang, Zhigang; Chen, Jiangzhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing Perovskite Precursor by Synergy of Functional Groups for NiOx-Based Inverted Solar Cells with 23.5 % Efficiency", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells suffer from poor reproducibility due to the degradation of perovskite precursor solution. Herein, we report an effective precursor stabilization strategy via incorporating 3-hydrazinobenzoic acid (3-HBA) containing carboxyl (-COOH) and hydrazine (-NHNH2) functional groups as stabilizer. The oxidation of I-, deprotonation of organic cations and amine-cation reaction are the main causes of the degradation of mixed organic cation perovskite precursor solution. The -NHNH2 can reduce I-2 defects back to I- and thus suppress the oxidation of I-, while the H+ generated by -COOH can inhibit the deprotonation of organic cations and subsequent amine-cation reaction. The above degradation reactions are simultaneously inhibited by the synergy of functional groups. The inverted device achieves an efficiency of 23.5 % (certified efficiency of 23.3 %) with an excellent operational stability, retaining 94 % of the initial efficiency after maximum power point tracking for 601 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2022, "Volume": 61, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202206914", "DOI": "10.1002/anie.202206914", "DOI Link": "http://dx.doi.org/10.1002/anie.202206914", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000823843500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, BB; Yu, Y; Chen, HY; Cui, J; Liu, XX; Xie, L; He, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Binbin; Yu, Yong; Chen, Hongyi; Cui, Juan; Liu, Xixi; Xie, Lin; He, Jiaqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy engineering promotes thermoelectric performance in p-type chalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate that the thermoelectric properties of p-type chalcogenides can be effectively improved by band convergence and hierarchical structure based on a high-entropy-stabilized matrix. The band convergence is due to the decreased light and heavy band energy offsets by alloying Cd for an enhanced Seebeck coefficient and electric transport property. Moreover, the hierarchical structure manipulated by entropy engineering introduces all-scale scattering sources for heat-carrying phonons resulting in a very low lattice thermal conductivity. Consequently, a peak zT of 2.0 at 900K for p-type chalcogenides and a high experimental conversion efficiency of 12% at Delta T=506K for the fabricated segmented modules are achieved. This work provides an entropy strategy to form all-scale hierarchical structures employing high-entropy-stabilized matrix. This work will promote real applications of low-cost thermoelectric materials. The synergism of entropy engineering and the typical optimization mechanisms in high-entropy-stabilized chalcogenide is unknown. Here, the authors find high-entropy-stabilized composition works as a promising matrix of applying synergistic effect to realize high thermoelectric performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3234, "DOI": "10.1038/s41467-021-23569-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23569-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659145000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, TM; Wang, Y; Han, JY; Zhang, QQ; Bai, X; Niu, XD; Wang, ZL; Guan, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Tianmi; Wang, Yin; Han, Jingyi; Zhang, Qiaoqiao; Bai, Xue; Niu, Xiaodi; Wang, Zhenlu; Guan, Jingqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-atom Co-Fe catalysts for oxygen reduction reaction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlled synthesis of dual-atom catalysts (DACs) for heterogeneous catalytic reactions is vital but still demanding. Herein, we construct a novel dual-atom catalyst containing FeN3-CoN3 sites on N-doped graphene nullosheets (CoFe-NG), which exhibits remarkable catalytic performance with a half-wave potential of 0.952 V for oxygen reduction reaction (ORR) and shows higher endurance to methanol/carbon monoxide poisoning and better durability than commercial Pt/C. The assembled Zn-air battery with CoFe-NG as the air electrode delivers a peak power density of 230 mW cm-2 and exhibits negligible change in output voltage at 5 mA cm-2 for 250 h. Theoretical calculations reveal that FeN3-CoN3 sites on N-doped graphene exhibit lower ORR barrier than FeN4 and CoN4 sites, and the rate-limiting step on the former is the transformation of *OH intermediate to H2O, different from the transformation of *O to *OH on the FeN4 site and the transformation of O2 to *OOH on the CoN4 site.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 48, "End Page": 55, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64189-5", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64189-5", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991308800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, J; Zhang, Y; Zhang, M; Yao, BW; Li, YR; Huang, L; Li, C; Shi, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ji; Zhang, Yao; Zhang, Miao; Yao, Bowen; Li, Yingru; Huang, Liang; Li, Chun; Shi, Gaoquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water-enhanced oxidation of graphite to graphene oxide with controlled species of oxygenated groups", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene oxide (GO) sheets with controlled species of oxygen-containing groups are important for fabricating graphene materials with desired structures and properties. Here we report a water-addition modified Hummers method to prepare GO sheets with tunable amounts of hydroxyl and epoxide groups without destroying their structural integrity. This method is simple, effective, and efficient. It can be applied to the mass-production of GO with controlled amounts and species of oxygenated groups, and improve the yields of synthesizing high-quality GO at low temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1874, "End Page": 1881, "Article Number": null, "DOI": "10.1039/c5sc03828f", "DOI Link": "http://dx.doi.org/10.1039/c5sc03828f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371021900028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YM; Liu, LY; Zhao, LL; Hou, CX; Huang, MN; Algadi, H; Li, DY; Xia, Q; Wang, J; Zhou, ZR; Han, X; Long, YX; Li, YB; Zhang, ZD; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yiming; Liu, Liyuan; Zhao, Lanling; Hou, Chuanxin; Huang, Meina; Algadi, Hassan; Li, Deyuan; Xia, Qing; Wang, Jun; Zhou, Zhaorui; Han, Xue; Long, Yuxin; Li, Yebing; Zhang, Zidong; Liu, Yao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sandwich-like CoMoP2/MoP heterostructures coupling N, P co-doped carbon nullosheets as advanced anodes for high-performance lithium-ion batteries", "Source Title": "ADVANCED COMPOSITES AND HYBRID MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal phosphides as ideal anodes have been attracted a large number of interests due to their excellent performance for lithium-ion batteries. Nevertheless, CoMoP2 materials were rarely reported as lithium-ion battery anode materials. Thereupon, to excavate their ability in LIBs, a sandwich-like architecture was employed as anode material, in which heterostructured CoMoP2 and MoP nulloparticles were coated on N, P co-doped carbon matrix. Notably, doped micro-lamellated carbon sheets could not only allow boosted lithium ion and electron transport but also alleviate the volume changes of active material to sustain anode integrity during the discharge/charge processes. More importantly, the combination of CoMoP2 and MoP nulloparticles could synergically strengthen the electrochemical activities of the anodes, and their built-in heterojunction facilitated the reaction kinetics on their interfaces. This research may offer a rational design on both heterostructure and doping engineering of future anodes for lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2601, "End Page": 2610, "Article Number": null, "DOI": "10.1007/s42114-022-00535-x", "DOI Link": "http://dx.doi.org/10.1007/s42114-022-00535-x", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843262500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schindler, F; Cook, AM; Vergniory, MG; Wang, ZJ; Parkin, SSP; Bernevig, BA; Neupert, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schindler, Frank; Cook, Ashley M.; Vergniory, Maia G.; Wang, Zhijun; Parkin, Stuart S. P.; Andrei Bernevig, B.; Neupert, Titus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-order topological insulators", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional topological (crystalline) insulators are materials with an insulating bulk but conducting surface states that are topologically protected by time-reversal (or spatial) symmetries. We extend the notion of three-dimensional topological insulators to systems that host no gapless surface states but exhibit topologically protected gapless hinge states. Their topological character is protected by spatiotemporal symmetries of which we present two cases: (i) Chiral higher-order topological insulators protected by the combination of time-reversal and a fourfold rotation symmetry. Their hinge states are chiral modes, and the bulk topology is Z(2)-classified. (ii) Helical higher-order topological insulators protected by time-reversal and mirror symmetries. Their hinge states come in Kramers pairs, and the bulk topology is Z-classified. We provide the topological invariants for both cases. Furthermore, we show that SnTe as well as surface-modified Bi(2)Tel, BiSe, and BiTe are helical higher-order topological insulators and propose a realistic experimental setup to detect the hinge states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1244, "Times Cited, All Databases": 1324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat0346", "DOI": "10.1126/sciadv.aat0346", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat0346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, N; Bediako, DK; Hadt, RG; Hayes, D; Kempa, TJ; von Cube, F; Bell, DC; Chen, LX; Nocera, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, nullcy; Bediako, D. Kwabena; Hadt, Ryan G.; Hayes, Dugan; Kempa, Thomas J.; von Cube, Felix; Bell, David C.; Chen, Lin X.; Nocera, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron doping of nickel oxide films results in enhanced activity for promoting the oxygen evolution reaction (OER). Whereas this enhanced activity has been ascribed to a unique iron site within the nickel oxide matrix, we show here that Fe doping influences the Ni valency. The percent of Fe3+ doping promotes the formation of formal Ni4+, which in turn directly correlates with an enhanced activity of the catalyst in promoting OER. The role of Fe3+ is consistent with its behavior as a superior Lewis acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 541, "Times Cited, All Databases": 573, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2017, "Volume": 114, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1486, "End Page": 1491, "Article Number": null, "DOI": "10.1073/pnas.1620787114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1620787114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393989300044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QQ; Du, CY; Shen, B; Zuo, PJ; Cheng, XQ; Ma, YL; Yin, GP; Gao, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qianqian; Du, Chunyu; Shen, Bin; Zuo, Pengjian; Cheng, Xinqun; Ma, Yulin; Yin, Geping; Gao, Yunzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding undesirable anode lithium plating issues in lithium-ion batteries", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) are attractive candidates as power sources for various applications, such as electric vehicles and large-scale energy storage devices. However, safety and life issues are still great challenges for the practical applications of LIBs. Metallic lithium plating on the negative electrode under critical charging conditions accelerates performance degradation and poses safety hazards for LIBs. Therefore, anode lithium plating in LIBs has recently drawn increased attention. This article reviews the recent research and progress regarding anode lithium plating of LIBs. Firstly, the adverse effects of anode lithium plating on the electrochemical performance of LIBs are presented. Various in situ and ex situ techniques for characterizing and detecting anode lithium plating are then summarized. Also, this review discusses the influencing factors that induce anode lithium plating and approaches to mitigating or preventing anode lithium plating. Finally, remaining challenges and future developments related to anode lithium plating are proposed in the conclusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": 91, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 88683, "End Page": 88700, "Article Number": null, "DOI": "10.1039/c6ra19482f", "DOI Link": "http://dx.doi.org/10.1039/c6ra19482f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384571800099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hufschmid, R; Arami, H; Ferguson, RM; Gonzales, M; Teeman, E; Brush, LN; Browning, ND; Krishnull, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hufschmid, Ryan; Arami, Hamed; Ferguson, R. Matthew; Gonzales, Marcela; Teeman, Eric; Brush, Lucien N.; Browning, Nigel D.; Krishnull, Kannull M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of phase-pure and monodisperse iron oxide nulloparticles by thermal decomposition", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superparamagnetic iron oxide nulloparticles (SPIONs) are used for a wide range of biomedical applications requiring precise control over their physical and magnetic properties, which are dependent on their size and crystallographic phase. Here we present a comprehensive template for the design and synthesis of iron oxide nulloparticles with control over size, size distribution, phase, and resulting magnetic properties. We investigate critical parameters for synthesis of monodisperse SPIONs by organic thermal decomposition. Three different, commonly used, iron containing precursors (iron oleate, iron pentacarbonyl, and iron oxyhydroxide) are evaluated under a variety of synthetic conditions. We compare the suitability of these three kinetically controlled synthesis protocols, which have in common the use of iron oleate as a starting precursor or reaction intermediate, for producing nulloparticles with specific size and magnetic properties. Monodisperse particles were produced over a tunable range of sizes from approximately 2-30 nm. Reaction parameters such as precursor concentration, addition of surfactant, temperature, ramp rate, and time were adjusted to kinetically control size and size-distribution, phase, and magnetic properties. In particular, large quantities of excess surfactant (up to 25 : 1 molar ratio) alter reaction kinetics and result in larger particles with uniform size; however, there is often a trade-off between large particles and a narrow size distribution. Iron oxide phase, in addition to nulloparticle size and shape, is critical for establishing magnetic properties such as differential susceptibility (dm/dH) and anisotropy. As an example, we show the importance of obtaining the required size and iron oxide phase for application to Magnetic Particle Imaging (MPI), and describe how phase purity can be controlled. These results provide much of the information necessary to determine which iron oxide synthesis protocol is best suited to a particular application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11142, "End Page": 11154, "Article Number": null, "DOI": "10.1039/c5nr01651g", "DOI Link": "http://dx.doi.org/10.1039/c5nr01651g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356515900035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, S; Dong, L; Wang, ZQ; Han, X; Daemen, LL; Li, J; Cheng, YQ; Guo, Y; Liu, XH; Hu, YF; Ramirez-Cuesta, AJ; Yang, SH; Gong, XQ; Wang, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Shuang; Dong, Lin; Wang, Zhi-Qiang; Han, Xue; Daemen, Luke L.; Li, Jiong; Cheng, Yongqiang; Guo, Yong; Liu, Xiaohui; Hu, Yongfeng; Ramirez-Cuesta, Anibal J.; Yang, Sihai; Gong, Xue-Qing; Wang, Yanqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass challenging. Here the authors report a unique core-shell structured Co@CoO catalyst which exhibits excellent performance in the hydrogenolysis of biomass-derived compounds. The development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass remains an important and challenging target. Here, we report the efficient hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran over a unique core-shell structured catalyst, Co@CoO that affords the highest productivity among all catalysts, including noble-metal-based catalysts, reported to date. Surprisingly, we find that the catalytically active sites reside on the shell of CoO with oxygen vacancies rather than the metallic Co. The combination of various spectroscopic experiments and computational modelling reveals that the CoO shell incorporating oxygen vacancies not only drives the heterolytic cleavage, but also the homolytic cleavage of H-2 to yield more active H delta- species, resulting in the exceptional catalytic activity. Co@CoO also exhibits excellent activity toward the direct hydrodeoxygenation of lignin model compounds. This study unlocks, for the first time, the potential of simple metal-oxide-based catalysts for the hydrodeoxygenation of renewable biomass to chemical feedstocks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3657, "DOI": "10.1038/s41467-022-31362-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31362-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818961600036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, XH; Man, ZM; Quan, B; Zheng, J; Gu, WH; Zhang, Z; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Xiaohui; Man, Zengming; Quan, Bin; Zheng, Jing; Gu, Weihua; Zhang, Zhu; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environment-Stable CoxNiy Encapsulation in Stacked Porous Carbon nullosheets for Enhanced Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic/dielectric@porous carbon composites, derived from metal-organic frameworks (MOFs) with adjustable composition ratio, have attracted wide attention due to their unique magnetoelectric properties. In addition, MOFs-derived porous carbon-based materials can meet the needs of lightweight feature. This paper reports a simple process for synthesizing stacked CoxNiy@C nullosheets derived from CoxNiy-MOFs nullosheets with multiple interfaces, which is good to the microwave response. The CoxNiy@C with controllable composition can be obtained by adjusting the ratio of Co2+ and Ni2+. It is supposed that the increased Co content is benefit to the dielectric and magnetic loss. Additionally, the bandwidth of CoNi@C nullosheets can take up almost the whole Ku band. Moreover, this composite has better environmental stability in air, which characteristic provides a sustainable potential for the practical application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2020, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102, "DOI": "10.1007/s40820-020-00432-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00432-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529096800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boyle, DT; Huang, W; Wang, HS; Li, YZ; Chen, H; Yu, Z; Zhang, WB; Bao, ZN; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boyle, David T.; Huang, William; Wang, Hansen; Li, Yuzhang; Chen, Hao; Yu, Zhiao; Zhang, Wenbo; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion of lithium metal anodes during calendar ageing and its microscopic origins", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium (Li) metal batteries must have long cycle life and calendar life (retention of capacity during storage at open circuit). Particular emphasis has been placed on prolonging the cycle life of Li metal anodes, but calendar ageing is less understood. Here, we show that Li metal loses at least 2-3% of its capacity after only 24 hours of ageing, regardless of the electrolyte chemistry. These losses of capacity during calendar ageing also shorten the cycle life of Li metal batteries. Cryogenic transmission electron microscopy shows that chemical corrosion of Li and the continuous growth of the solid electrolyte interphase-a passivation film on Li-cause the loss of capacity. Electrolytes with long cycle life do not necessarily form a solid electrolyte interphase with more resistance to chemical corrosion, so functional electrolytes must simultaneously minimize the rate of solid electrolyte interphase growth and the surface area of electrodeposited Li metal. Batteries keep degrading even when they are not in operation, but their calendar life is rarely studied in advanced batteries that are still in the development stage. Here the authors quantify the calendar ageing of Li metal anodes and report its underlying mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 487, "End Page": 494, "Article Number": null, "DOI": "10.1038/s41560-021-00787-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00787-9", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631480700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, W; Liu, JX; Liu, XQ; Wang, LQ; Yin, LC; Tan, HT; Hou, F; Liang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Wei; Liu, Jiaxin; Liu, Xiaoqing; Wang, Liqun; Yin, Lichang; Tan, Haotian; Hou, Feng; Liang, Ji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facilitating two-electron oxygen reduction with pyrrolic nitrogen sites for electrochemical hydrogen peroxide production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic hydrogen peroxide (H2O2) production via the two-electron oxygen reduction reaction is a promising alternative to the energy-intensive and high-pollution anthraquinone oxidation process. However, developing advanced electrocatalysts with high H2O2 yield, selectivity, and durability is still challenging, because of the limited quantity and easy passivation of active sites on typical metal-containing catalysts, especially for the state-of-the-art single-atom ones. To address this, we report a graphene/mesoporous carbon composite for high-rate and high-efficiency 2e- oxygen reduction catalysis. The coordination of pyrrolic-N sites -modulates the adsorption configuration of the *OOH species to provide a kinetically favorable pathway for H2O2 production. Consequently, the H2O2 yield approaches 30 mol g-1 h-1 with a Faradaic efficiency of 80% and excellent durability, yielding a high H2O2 concentration of 7.2 g L-1. This strategy of manipulating the adsorption configuration of reactants with multiple non-metal active sites provides a strategy to design efficient and durable metal-free electrocatalyst for 2e- oxygen reduction. A graphene/mesoporous carbon composite presents rapid and efficient H2O2 electrosynthesis capability by two-electron oxygen reduction catalysis which is facilitated by the presence of multiple pyrrolic nitrogen dopants within the material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4430, "DOI": "10.1038/s41467-023-40118-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40118-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001111938400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, YH; Li, M; Wu, ZZ; Sun, Q; Yuan, D; Johannessen, B; Xu, L; Wang, Y; Dou, YH; Zhao, HJ; Zhang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Yuhui; Li, Meng; Wu, Zhenzhen; Sun, Qiang; Yuan, Ding; Johannessen, Bernt; Xu, Li; Wang, Yun; Dou, Yuhai; Zhao, Huijun; Zhang, Shanqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edge-hosted Atomic Co-N4 Sites on Hierarchical Porous Carbon for Highly Selective Two-electron Oxygen Reduction Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Not only high efficiency but also high selectivity of the electrocatalysts is crucial for high-performance, low-cost, and sustainable energy storage applications. Herein, we systematically investigate the edge effect of carbon-supported single-atom catalysts (SACs) on oxygen reduction reaction (ORR) pathways (two-electron (2 e(-)) or four-electron (4 e(-))) and conclude that the 2 e(-)-ORR proceeding over the edge-hosted atomic Co-N-4 sites is more favorable than the basal-plane-hosted ones. As such, we have successfully synthesized and tuned Co-SACs with different edge-to-bulk ratios. The as-prepared edge-rich Co-N/HPC catalyst exhibits excellent 2 e(-)-ORR performance with a remarkable selectivity of approximate to 95 % in a wide potential range. Furthermore, we also find that oxygen functional groups could saturate the graphitic carbon edges under the ORR operation and further promote electrocatalytic performance. These findings on the structure-property relationship in SACs offer a promising direction for large-scale and low-cost electrochemical H2O2 production via the 2 e(-)-ORR.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2022, "Volume": 61, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202213296", "DOI Link": "http://dx.doi.org/10.1002/anie.202213296", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888861000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, MH; Tang, SS; Li, Z; Wang, MY; Jin, ZY; Li, PP; Zhan, X; Zhou, H; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Minghao; Tang, Sishuang; Li, Zhao; Wang, Maoyu; Jin, Zhaoyu; Li, Panpan; Zhan, Xun; Zhou, Hua; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intermetallic Single-Atom Alloy In-Pd Bimetallene for Neutral Electrosynthesis of Ammonia from Nitrate", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvestingrecyclable ammonia (NH3) from theelectrocatalyticreduction of nitrate (NO3RR) offers a sustainable strategyto close the ecological nitrogen cycle from nitration contaminationin an energy-efficient and environmentally friendly manner. The emergingintermetallic single-atom alloys (ISAAs) are recognized to achievethe highest site density of single atoms by isolating contiguous metalatoms into single sites stabilized by another metal within the intermetallicstructure, which holds promise to couple the catalytic benefits fromintermetallic nullocrystals and single-atom catalysts for promotingNO(3)RR. Herein, ISAA In-Pd bimetallene, in whichthe Pd single atoms are isolated by surrounding In atoms, is reportedto boost neutral NO3RR with a NH3 Faradaic efficiency(FE) of 87.2%, a yield rate of 28.06 mg h(-1) mg(Pd) (-1), and an exceptional electrocatalyticstability with increased activity/selectivity over 100 h and 20 cycles.The ISAA structure induces substantially diminished overlap of Pdd-orbitals and narrowed p-d hybridization of In-p and Pd-dstates around the Fermi level, resulting in a stronger NO3 (-) adsorption and a depressed energy barrier ofthe potential-determining step for NO3RR. Further integratingthe NO3RR catalyst into a Zn-NO3 (-) flow battery as the cathode delivers a power densityof 12.64 mW cm(-2) and a FE of 93.4% for NH3 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2023, "Volume": 145, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13957, "End Page": 13967, "Article Number": null, "DOI": "10.1021/jacs.3c03432", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c03432", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011497600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, PC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Pengcheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antiferromagnetic order and spin dynamics in iron-based superconductors", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-transition temperature (high-T-c) superconductivity in the iron pnictides or chalcogenides emerges from the suppression of the static antiferromagnetic order in their parent compounds, similar to copper oxide superconductors. This raises a fundamental question concerning the role of magnetism in the superconductivity of these materials. Neutron scattering, a powerful probe to study the magnetic order and spin dynamics, plays an essential role in determining the relationship between magnetism and superconductivity in high-T-c superconductors. The rapid development of modern neutron time-of-flight spectrometers allows a direct determination of the spin dynamical properties of iron-based superconductors throughout the entire Brillouin zone. In this paper, an overview is presented of the neutron scattering results on iron-based superconductors, focusing on the evolution of spin-excitation spectra as a function of electron and hole doping and isoelectronic substitution. Spin dynamical properties of iron-based superconductors are compared with those of copper oxide and heavy fermion superconductors and the common features of spin excitations in these three families of unconventional superconductors and their relationship with superconductivity are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 602, "Times Cited, All Databases": 665, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2015, "Volume": 87, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 855, "End Page": 896, "Article Number": null, "DOI": "10.1103/RevModPhys.87.855", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.87.855", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359906200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, CR; Yang, YL; Hu, XM; Cho, Y; Jang, YY; Ao, YH; Wang, LY; Shen, JY; Park, JH; Zhang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Chaoran; Yang, Yilong; Hu, Xuemin; Cho, Yoonjun; Jang, Gyuyong; Ao, Yanhui; Wang, Luyang; Shen, Jinyou; Park, Jong Hyeok; Zhang, Kan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-cycled photo-Fenton-like system based on an artificial leaf with a solar-to-H2O2 conversion efficiency of 1.46%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Millions of families around the world remain vulnerable to water scarcity and have no access to drinking water. Advanced oxidation processes (AOPs) are an effective way towards water purification with qualified reactive oxygen species (ROSs) while are impeded by the high-cost and tedious process in either input of consumable reagent, production of ROSs, and the pre-treatment of supporting electrolyte. Herein, we couple solar light-assisted H2O2 production from water and photo-Fenton-like reactions into a self-cyclable system by using an artificial leaf, achieving an unassisted H2O2 production rate of 0.77 mu mol/(min center dot cm(2)) under 1 Sun AM 1.5 illumination. Furthermore, a large (70 cm(2)) artificial leaf was used for an unassisted solar-driven bicarbonate-activated hydrogen peroxide (BAP) system with recycled catalysts for real-time wastewater purification with requirements for only water, oxygen and sunlight. This demonstration highlights the feasibility and scalability of photoelectrochemical technology for decentralized environmental governullce applications from laboratory benchtops to industry. Continuous generation of reactive oxygen species is desirable in the advanced oxidation process. Here, the authors report a self-cycled photoFenton-like with a scalable artificial leaf for production of H2O2 from water with solar-to-H2O2 efficiency of 1.46%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4982, "DOI": "10.1038/s41467-022-32410-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32410-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000845603400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stockman, MI; Kneipp, K; Bozhevolnyi, SI; Saha, S; Dutta, A; Ndukaife, J; Kinsey, N; Reddy, H; Guler, U; Shalaev, VM; Boltasseva, A; Gholipour, B; Krishnamoorthy, HNS; MacDonald, KF; Soci, C; Zheludev, NI; Savinov, V; Singh, R; Gross, P; Lienau, C; Vadai, M; Solomon, ML; Barton, DR; Lawrence, M; Dionne, JA; Boriskina, SV; Esteban, R; Aizpurua, J; Zhang, X; Yang, S; Wang, DQ; Wang, WJ; Odom, TW; Accanto, N; de Roque, PM; Hancu, IM; Piatkowski, L; van Hulst, NF; Kling, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stockman, Mark I.; Kneipp, Katrin; Bozhevolnyi, Sergey I.; Saha, Soham; Dutta, Aveek; Ndukaife, Justus; Kinsey, Nathaniel; Reddy, Harsha; Guler, Urcan; Shalaev, Vladimir M.; Boltasseva, Alexandra; Gholipour, Behrad; Krishnamoorthy, Harish N. S.; MacDonald, Kevin F.; Soci, Cesare; Zheludev, Nikolay I.; Savinov, Vassili; Singh, Ranjan; Gross, Petra; Lienau, Christoph; Vadai, Michal; Solomon, Michelle L.; Barton, David R., III; Lawrence, Mark; Dionne, Jennifer A.; Boriskina, Svetlana V.; Esteban, Ruben; Aizpurua, Javier; Zhang, Xiang; Yang, Sui; Wang, Danqing; Wang, Weijia; Odom, Teri W.; Accanto, Nicolo; de Roque, Pablo M.; Hancu, Ion M.; Piatkowski, Lukasz; van Hulst, Niek F.; Kling, Matthias F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roadmap on plasmonics", "Source Title": "JOURNAL OF OPTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasmonics is a rapidly developing field at the boundary of physical optics and condensed matter physics. It studies phenomena induced by and associated with surface plasmons-elementary polar excitations bound to surfaces and interfaces of good nullostructured metals. This Roadmap is written collectively by prominent researchers in the field of plasmonics. It encompasses selected aspects of nulloplasmonics. Among them are fundamental aspects, such as quantum plasmonics based on the quantum-mechanical properties of both the underlying materials and the plasmons themselves (such as their quantum generator, spaser), plasmonics in novel materials, ultrafast (attosecond) nulloplasmonics, etc. Selected applications of nulloplasmonics are also reflected in this Roadmap, in particular, plasmonic waveguiding, practical applications of plasmonics enabled by novel materials, thermo-plasmonics, plasmonic-induced photochemistry and photo-catalysis. This Roadmap is a concise but authoritative overview of modern plasmonics. It will be of interest to a wide audience of both fundamental physicists and chemists, as well as applied scientists and engineers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 20, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 43001, "DOI": "10.1088/2040-8986/aaa114", "DOI Link": "http://dx.doi.org/10.1088/2040-8986/aaa114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447428100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jow, TR; Delp, SA; Allen, JL; Jones, JP; Smart, MC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jow, T. Richard; Delp, Samuel A.; Allen, Jan L.; Jones, John-Paul; Smart, Marshall C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Factors Limiting Li+ Charge Transfer Kinetics in Li-Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the factors limiting Li+ charge transfer kinetics in Li-ion batteries is essential in improving the rate performance, especially at lower temperatures. The Li+ charge transfer process involved in the lithium intercalation of graphite anode includes the step of de-solvation of the solvated Li+ in the liquid electrolyte and the step of transport of Li+ in the preformed solid electrolyte interphase (SEI) on electrodes until the Li+ accepts an electron at the electrode and becomes a Li in the electrode. Whether the de-solvation process or the Li+ transport through the SEI is a limiting step depends on the nature of the interphases at the electrode and electrolyte interfaces. Several examples involving the electrode materials such as graphite, lithium titanate (LTO), lithium iron phosphate (LFP), lithium nickel cobalt aluminum oxide (NCA) and solid Li+ conductor such as lithium lanthanum titanate or Li-Al-Ti-phosphate are reviewed and discussed to clarify the conditions at which either the de-solvation or the transport of Li+ in SEI is dominating and how the electrolyte components affect the activation energy of Li+ charge transfer kinetics. How the electrolyte additives impact the Li+ charge transfer kinetics at both the anode and the cathode has been examined at the same time in 3-electrode full cells. The resulting impact on Li+ charge transfer resistance, R-ct, and activation energy, E-a, at both electrodes are reported and discussed. (C) The Author(s) 2018. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 165, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A361", "End Page": "A367", "Article Number": null, "DOI": "10.1149/2.1221802jes", "DOI Link": "http://dx.doi.org/10.1149/2.1221802jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431786800048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, ZP; Eisner, FD; Jiao, XC; Azzouzi, M; Röhr, JA; Han, Y; Shahid, M; Chesman, ASR; Easton, CD; McNeill, CR; Anthopoulos, TD; Nelson, J; Heeney, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Zhuping; Eisner, Flurin D.; Jiao, Xuechen; Azzouzi, Mohammed; Rohr, Jason A.; Han, Yang; Shahid, Munazza; Chesman, Anthony S. R.; Easton, Christopher D.; McNeill, Christopher R.; Anthopoulos, Thomas D.; Nelson, Jenny; Heeney, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Alkylated Indacenodithieno[3,2-b]thiophene-Based Nonfullerene Acceptor with High Crystallinity Exhibiting Single Junction Solar Cell Efficiencies Greater than 13% with Low Voltage Losses", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new synthetic route, to prepare an alkylated indacenodithieno[3,2-b]thiophene-based nonfullerene acceptor (C8-ITIC), is reported. Compared to the reported ITIC with phenylalkyl side chains, the new acceptor C8-ITIC exhibits a reduction in the optical band gap, higher absorptivity, and an increased propensity to crystallize. Accordingly, blends with the donor polymer PBDB-T exhibit a power conversion efficiency (PCE) up to 12.4%. Further improvements in efficiency are found upon backbone fluorination of the donor polymer to afford the novel material PFBDB-T. The resulting blend with C8-ITIC shows an impressive PCE up to 13.2% as a result of the higher open-circuit voltage. Electroluminescence studies demonstrate that backbone fluorination reduces the energy loss of the blends, with PFBDB-T/C8-ITIC-based cells exhibiting a small energy loss of 0.6 eV combined with a high J(SC) of 19.6 mA cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2018, "Volume": 30, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1705209, "DOI": "10.1002/adma.201705209", "DOI Link": "http://dx.doi.org/10.1002/adma.201705209", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425449300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, JB; Jiang, H; Yang, QQ; Tang, LL; Tao, Y; Li, YY; Chen, RF; Zheng, C; Fan, QL; Zhang, KY; Zhao, Q; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Jibiao; Jiang, He; Yang, Qingqing; Tang, Lele; Tao, Ye; Li, Yuanyuan; Chen, Runfeng; Zheng, Chao; Fan, Quli; Zhang, Kenneth Yin; Zhao, Qiang; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermally activated triplet exciton release for highly efficient tri-mode organic afterglow", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of organic afterglow materials that do not contain heavy metals is of interest for biological applications. Here, the authors report on the development of a thermally activated organic molecule with tri-mode afterglow and an afterglow efficiency of up to 45%. Developing high-efficient afterglow from metal-free organic molecules remains a formidable challenge due to the intrinsically spin-forbidden phosphorescence emission nature of organic afterglow, and only a few examples exhibit afterglow efficiency over 10%. Here, we demonstrate that the organic afterglow can be enhanced dramatically by thermally activated processes to release the excitons on the stabilized triplet state (T-1*) to the lowest triplet state (T-1) and to the singlet excited state (S-1) for spin-allowed emission. Designed in a twisted donor-acceptor architecture with small singlet-triplet splitting energy and shallow exciton trapping depth, the thermally activated organic afterglow shows an efficiency up to 45%. This afterglow is an extraordinary tri-mode emission at room temperature from the radiative decays of S-1, T-1, and T-1*. With the highest afterglow efficiency reported so far, the tri-mode afterglow represents an important concept advance in designing high-efficient organic afterglow materials through facilitating thermally activated release of stabilized triplet excitons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 842, "DOI": "10.1038/s41467-020-14669-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14669-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514609800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shangguan, WC; Liu, Q; Wang, Y; Sun, N; Liu, Y; Zhao, R; Li, YX; Wang, CY; Zhao, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shangguan, Wenchao; Liu, Qing; Wang, Ying; Sun, Ning; Liu, Yu; Zhao, Rui; Li, Yingxuan; Wang, Chuanyi; Zhao, Jincai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular-level insight into photocatalytic CO2 reduction with H2O over Au nulloparticles by interband transitions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving CO2 reduction with H2O on metal photocatalysts and understanding the corresponding mechanisms at the molecular level are challenging. Herein, we report that quantum-sized Au nulloparticles can photocatalytically reduce CO2 to CO with the help of H2O by electron-hole pairs mainly originating from interband transitions. Notably, the Au photocatalyst shows a CO production rate of 4.73 mmol g(-1) h(-1) (similar to 100% selectivity), similar to 2.5 times the rate during CO2 reduction with H-2 under the same experimental conditions, under low-intensity irradiation at 420 nm. Theoretical and experimental studies reveal that the increased activity is induced by surface Au-O species formed from H2O decomposition, which synchronously optimizes the rate-determining steps in the CO2 reduction and H2O oxidation reactions, lowers the energy barriers for the *CO desorption and *OOH formation, and facilitates CO and O-2 production. Our findings provide an in-depth mechanistic understanding for designing active metal photocatalysts for efficient CO2 reduction with H2O.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3894, "DOI": "10.1038/s41467-022-31474-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31474-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821634700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Revia, RA; Zhang, MQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Revia, Richard A.; Zhang, Miqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetite nulloparticles for cancer diagnosis, treatment, and treatment monitoring: recent advances", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of nulloparticles (NPs) for use in all facets of oncological disease detection and therapy has shown great progress over the past two decades. NPs have been tailored for use as contrast enhancement agents for imaging, drug delivery vehicles, and most recently as a therapeutic component in initiating tumor cell death in magnetic and photonic ablation therapies. Of the many possible core constituents of NPs, such as gold, silver, carbon nullotubes, fullerenes, manganese oxide, lipids, micelles, etc., iron oxide (or magnetite) based NPs have been extensively investigated due to their excellent superparamagnetic, biocompatible, and biodegradable properties. This review addresses recent applications of magnetite NPs in diagnosis, treatment, and treatment monitoring of cancer. Finally, some views will be discussed concerning the toxicity and clinical translation of iron oxide NPs and the future outlook of NP development to facilitate multiple therapies in a single formulation for cancer theranostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 514, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 19, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 157, "End Page": 168, "Article Number": null, "DOI": "10.1016/j.mattod.2015.08.022", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2015.08.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373600400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neal, AT; Mou, S; Rafique, S; Zhao, HP; Ahmadi, E; Speck, JS; Stevens, KT; Blevins, JD; Thomson, DB; Moser, N; Chabak, KD; Jessen, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Neal, Adam T.; Mou, Shin; Rafique, Subrina; Zhao, Hongping; Ahmadi, Elaheh; Speck, James S.; Stevens, Kevin T.; Blevins, John D.; Thomson, Darren B.; Moser, Neil; Chabak, Kelson D.; Jessen, Gregg H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Donors and deep acceptors in β-Ga2O3", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have studied the properties of Si, Ge shallow donors and Fe, Mg deep acceptors in beta-Ga2O3 through temperature dependent van der Pauw and Hall effect measurements of samples grown by a variety of methods, including edge-defined film-fed, Czochralski, molecular beam epitaxy, and low pressure chemical vapor deposition. Through simultaneous, self-consistent fitting of the temperature dependent carrier density and mobility, we are able to accurately estimate the donor energy of Si and Ge to be 30meV in beta-Ga2O3. Additionally, we show that our measured Hall effect data are consistent with Si and Ge acting as typical shallow donors, rather than shallow DX centers. The high temperature Hall effect measurement of Fe doped beta-Ga2O3 indicates that the material remains weakly n-type even with the Fe doping, with an acceptor energy of 860meV relative to the conduction band for the Fe deep acceptor. Van der Pauw measurements of Mg doped Ga2O3 indicate an activation energy of 1.1 eV, as determined from the temperature dependent conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2018, "Volume": 113, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 62101, "DOI": "10.1063/1.5034474", "DOI Link": "http://dx.doi.org/10.1063/1.5034474", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441333900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KJ; Madden, DG; Pham, T; Forrest, KA; Kumar, A; Yang, QY; Xue, W; Space, B; Perry, JJ; Zhang, JP; Chen, XM; Zaworotko, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Kai-Jie; Madden, David G.; Pham, Tony; Forrest, Katherine A.; Kumar, Amrit; Yang, Qing-Yuan; Xue, Wei; Space, Brian; Perry, John J.; Zhang, Jie-Peng; Chen, Xiao-Ming; Zaworotko, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Pore Size in Square-Lattice Coordination Networks for Size-Selective Sieving of CO2", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Porous materials capable of selectively capturing CO2 from flue-gases or natural gas are of interest in terms of rising atmospheric CO2 levels and methane purification. Size-exclusive sieving of CO2 over CH4 and N-2 has rarely been achieved. Herein we show that a crystal engineering approach to tuning of pore-size in a coordination network, [Cu(quinoline-5-carboxyate)(2)](n) (Qc-5-Cu) ena+bles ultra-high selectivity for CO2 over N-2 (S-CN approximate to 40 000) and CH4 (S-CM approximate to 3300). Qc-5-Cu-sql-beta, a narrow pore polymorph of the square lattice (sql) coordination network Qc-5-Cu-sql-a, adsorbs CO2 while excluding both CH4 and N-2. Experimental measurements and molecular modeling validate and explain the performance. Qc-5-Cu-sql-beta is stable to moisture and its separation performance is unaffected by humidity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2016, "Volume": 55, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10268, "End Page": 10272, "Article Number": null, "DOI": "10.1002/anie.201603934", "DOI Link": "http://dx.doi.org/10.1002/anie.201603934", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383373700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, C; Hong, YJ; Jung, J; Shin, Y; Sunwoo, SH; Baik, S; Park, OK; Choi, SH; Hyeon, T; Kim, JH; Lee, S; Kim, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Chanhyuk; Hong, Yongseok Joseph; Jung, Jaebong; Shin, Yoonsoo; Sunwoo, Sung-Hyuk; Baik, Seungmin; Park, Ok Kyu; Choi, Sueng Hong; Hyeon, Taeghwan; Kim, Ji Hoon; Lee, Sangkyu; Kim, Dae-Hyeong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tissue-like skin-device interface for wearable bioelectronics by using ultrasoft, mass-permeable, and low-impedance hydrogels", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels consist of a cross-linked porous polymer network and water molecules occupying the interspace between the polymer chains. Therefore, hydrogels are soft and moisturized, with mechanical structures and physical properties similar to those of human tissue. Such hydrogels have a potential to turn the microscale gap between wearable devices and human skin into a tissue-like space. Here, we present material and device strategies to form a tissue-like, quasi-solid interface between wearable bioelectronics and human skin. The key material is an ultrathin type of functionalized hydrogel that shows unusual features of high mass-permeability and low impedance. The functionalized hydrogel acted as a liquid electrolyte on the skin and formed an extremely conformal and low-impedance interface for wearable electrochemical biosensors and electrical stimulators. Furthermore, its porous structure and ultrathin thickness facilitated the efficient transport of target molecules through the interface. Therefore, this functionalized hydrogel can maximize the performance of various wearable bioelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 7, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabd3716", "DOI": "10.1126/sciadv.abd3716", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abd3716", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648332700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YZ; Yuan, J; Ni, YX; Yang, J; Wang, Y; Jiu, TG; Yuan, MJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuanzhi; Yuan, Jin; Ni, Youxuan; Yang, Jien; Wang, Yao; Jiu, Tonggang; Yuan, Mingjian; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced-Dimensional α-CsPbX3 Perovskites for Efficient and Stable Photovoltaics", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic CsPbX3 perovskites have gained great attention owing to their excellent thermal stability and carrier transport properties. However, the power conversion efficiency (PCE) of solution-processed CsPbX3 perovskite solar cells is still far inferior to that of their hybrid analogues. Insufficient film thickness and undesirable phase transition are the two major obstacles limiting their device performance. Here, we show that by adopting a new precursor pair, cesium acetate (CsAc) and hydrogen lead trihalide (HPbX3), we were able to overcome the notorious solubility limitation for Cs precursors to fabricate high-quality CsPbX3 perovskite films with large film thickness (similar to 500 nm). We further introduced a judicious amount of phenylethylammonium iodide (PEAI) into the system to induce reduced-dimensional perovskite formation. Unprecedentedly, the resulting quasi-2D perovskites significantly suppressed undesirable phase transition and thus reduced the film's trap density. Following this approach, we reported a state-of-the-art PCE to date, 12.4%, for reduced-dimensional alpha-CsPbI3 perovskite photovoltaics with greatly improved performance longevity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1356, "End Page": 1368, "Article Number": null, "DOI": "10.1016/j.joule.2018.05.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.05.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439698900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, WM; Jo, YH; Sohn, SS; Lee, S; Lee, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Won-Mi; Jo, Yong Hee; Sohn, Seok Su; Lee, Sunghak; Lee, Byeong-Joo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the physical metallurgy of the CoCrFeMnNi high-entropy alloy: an atomistic simulation study", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although high-entropy alloys (HEAs) are attracting interest, the physical metallurgical mechanisms related to their properties have mostly not been clarified, and this limits wider industrial applications, in addition to the high alloy costs. We clarify the physical metallurgical reasons for the materials phenomena (sluggish diffusion and micro-twining at cryogenic temperatures) and investigate the effect of individual elements on solid solution hardening for the equiatomic CoCrFeMnNi HEA based on atomistic simulations (Monte Carlo, molecular dynamics and molecular statics). A significant number of stable vacant lattice sites with high migration energy barriers exists and is thought to cause the sluggish diffusion. We predict that the hexagonal close-packed (hcp) structure is more stable than the face-centered cubic (fcc) structure at 0 K, which we propose as the fundamental reason for the micro-twinning at cryogenic temperatures. The alloying effect on the critical resolved shear stress (CRSS) is well predicted by the atomistic simulation, used for a design of non-equiatomic fcc HEAs with improved strength, and is experimentally verified. This study demonstrates the applicability of the proposed atomistic approach combined with a thermodynamic calculation technique to a computational design of advanced HEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2018, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1, "DOI": "10.1038/s41524-017-0060-9", "DOI Link": "http://dx.doi.org/10.1038/s41524-017-0060-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426839100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghazaryan, D; Greenaway, MT; Wang, Z; Guarochico-Moreira, VH; Vera-Marun, IJ; Yin, J; Liao, Y; Morozov, SV; Kristanovski, O; Lichtenstein, AI; Katsnelson, MI; Withers, F; Mishchenko, A; Eaves, L; Geim, AK; Novoselov, KS; Misra, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghazaryan, D.; Greenaway, M. T.; Wang, Z.; Guarochico-Moreira, V. H.; Vera-Marun, I. J.; Yin, J.; Liao, Y.; Morozov, S. V.; Kristanovski, O.; Lichtenstein, A. I.; Katsnelson, M. I.; Withers, F.; Mishchenko, A.; Eaves, L.; Geim, A. K.; Novoselov, K. S.; Misra, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnon-assisted tunnelling in van der Waals heterostructures based on CrBr3", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals heterostructures, which are composed of layered two-dimensional materials, offer a platform to investigate a diverse range of physical phenomena and could be of use in a variety of applications. Heterostructures containing two-dimensional ferromagnets, such as chromium triiodide (CrI3), have recently been reported, which could allow two-dimensional spintronic devices to be developed. Here we study tunnelling through thin ferromagnetic chromium tribromide (CrBr3) barriers that are sandwiched between graphene electrodes. In devices with non-magnetic barriers, conservation of momentum can be relaxed by phonon-assisted tunnelling or by tunnelling through localized states. In contrast, in the devices with ferromagnetic barriers, the major tunnelling mechanisms are the emission of magnons at low temperatures and the scattering of electrons on localized magnetic excitations at temperatures above the Curie temperature. Magnetoresistance in the graphene electrodes further suggests induced spin-orbit coupling and proximity exchange via the ferromagnetic barrier. Tunnelling with magnon emission offers the possibility of spin injection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 1, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 344, "End Page": 349, "Article Number": null, "DOI": "10.1038/s41928-018-0087-z", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0087-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444077900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sinhamahapatra, A; Jeon, JP; Yu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sinhamahapatra, Apurba; Jeon, Jong-Pil; Yu, Jong-Sung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new approach to prepare highly active and stable black titania for visible light-assisted hydrogen production", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In spite of their remarkable enhancement in visible light absorption, black TiO2 materials have failed to demonstrate expected photocatalytic activity in visible light due to the presence of a high number of recombination centers. In this report, a new controlled magnesiothermic reduction has been developed to synthesize reduced black TiO2 under a 5% H-2/Ar atmosphere. The material possesses an optimum band gap and band position, oxygen vacancies, surface defects, and charge recombination centers and shows significantly improved optical absorption in the visible and infrared region. The synergistic effects enable the black TiO2 material to show an excellent hydrogen production ability in the methanol-water system in the presence of Pt as a co-catalyst. The maximum hydrogen production rates are 43 mmol h(-1) g(-1) and 440 mu mol h(-1) g(-1), along with remarkable stability under the full solar wavelength range of light and visible light, respectively, and these values are superior to those of previously reported black TiO2 materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3539, "End Page": 3544, "Article Number": null, "DOI": "10.1039/c5ee02443a", "DOI Link": "http://dx.doi.org/10.1039/c5ee02443a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365412300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SZ; McGuirk, CM; Ross, MB; Wang, SY; Chen, PC; Xing, H; Liu, Y; Mirkin, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shunzhi; McGuirk, C. Michael; Ross, Michael B.; Wang, Shuya; Chen, Pengcheng; Xing, Hang; Liu, Yuan; Mirkin, Chad A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General and Direct Method for Preparing Oligonucleotide-Functionalized Metal-Organic Framework nulloparticles", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal organic frameworks (MOFs) are a class of modular, crystalline, and porous materials that hold promise for storage and transport of chemical cargoes. Though MOFs have been studied in bulk forms, ways of deliberately manipulating the external surface functionality of MOF nulloparticles are less developed. A generalizable approach to modify their surfaces would allow one to impart chemical functionality onto the particle surface that is independent of the bulk MOF structure. Moreover, the use of a chemically programmable ligand, such as DNA, would allow for the manipulation of interparticle interactions. Herein, we report a coordination chemistry-based strategy for the surface functionalization of the external metal nodes of MOF nulloparticles with terminal phosphate-modified oligonucleotides. The external surfaces of nine distinct archetypical MOF particles containing four different metal species (Zr, Cr, Fe, and Al) were successfully functionalized with oligonucleotides, illustrating the generality of this strategy. By taking advantage of the programmable and specific interactions of DNA, 11 distinct MOF particle inorganic particle core satellite clusters were synthesized. In these hybrid nulloclusters, the relative stoichiometry, size, shape, and composition of the building blocks can all be independently controlled. This work provides access to a new set of nucleic acid-nulloparticle conjugates, which may be useful as programmable material building blocks and as probes for measuring and manipulating intracellular processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2017, "Volume": 139, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9827, "End Page": 9830, "Article Number": null, "DOI": "10.1021/jacs.7b05633", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b05633", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406649600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, BZ; Xiao, TC; Makgae, OA; Jie, XY; Gonzalez-Cortes, S; Guan, SL; Kirkland, AI; Dilworth, JR; Al-Megren, HA; Alshihri, SM; Dobson, PJ; Owen, GP; Thomas, JM; Edwards, PP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Benzhen; Xiao, Tiancun; Makgae, Ofentse A.; Jie, Xiangyu; Gonzalez-Cortes, Sergio; Guan, Shaoliang; Kirkland, Angus I.; Dilworth, Jonathan R.; Al-Megren, Hamid A.; Alshihri, Saeed M.; Dobson, Peter J.; Owen, Gari P.; Thomas, John M.; Edwards, Peter P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transforming carbon dioxide into jet fuel using an organic combustion-synthesized Fe-Mn-K catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With mounting concerns over climate change, the utilisation or conversion of carbon dioxide into sustainable, synthetic hydrocarbons fuels, most notably for transportation purposes, continues to attract worldwide interest. This is particularly true in the search for sustainable or renewable aviation fuels. These offer considerable potential since, instead of consuming fossil crude oil, the fuels are produced from carbon dioxide using sustainable renewable hydrogen and energy. We report here a synthetic protocol to the fixation of carbon dioxide by converting it directly into aviation jet fuel using novel, inexpensive iron-based catalysts. We prepare the Fe-Mn-K catalyst by the so-called Organic Combustion Method, and the catalyst shows a carbon dioxide conversion through hydrogenation to hydrocarbons in the aviation jet fuel range of 38.2%, with a yield of 17.2%, and a selectivity of 47.8%, and with an attendant low carbon monoxide (5.6%) and methane selectivity (10.4%). The conversion reaction also produces light olefins ethylene, propylene, and butenes, totalling a yield of 8.7%, which are important raw materials for the petrochemical industry and are presently also only obtained from fossil crude oil. As this carbon dioxide is extracted from air, and re-emitted from jet fuels when combusted in flight, the overall effect is a carbon-neutral fuel. This contrasts with jet fuels produced from hydrocarbon fossil sources where the combustion process unlocks the fossil carbon and places it into the atmosphere, in longevity, as aerial carbon - carbon dioxide. Design and discovery of catalysts to make clean energy and mitigate the harmful effect of greenhouse gases remains a massive challenge. Here the authors report a combustion-synthesised iron-based catalyst of high activity and selectivity for directly converting CO2 to aviation jet fuel.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6395, "DOI": "10.1038/s41467-020-20214-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20214-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000603077500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, HF; Xi, QY; Chen, X; Guo, DY; Ding, F; Yang, Z; Wang, S; Li, J; Huang, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Huifang; Xi, Qiaoya; Chen, Xi'an; Guo, Daying; Ding, Feng; Yang, Zhi; Wang, Shun; Li, Juan; Huang, Shaoming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molybdenum Carbide nulloparticles Coated into the Graphene Wrapping N-Doped Porous Carbon Microspheres for Highly Efficient Electrocatalytic Hydrogen Evolution Both in Acidic and Alkaline Media", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum carbide (Mo2C) is recognized as an alternative electrocatalyst to noble metal for the hydrogen evolution reaction (HER). Herein, a facile, low cost, and scalable method is provided for the fabrication of Mo2C-based eletrocatalyst (Mo2C/G-NCS) by a spray-drying, and followed by annealing. As-prepared Mo2C/G-NCS electrocatalyst displays that ultrafine Mo2C nullopartilces are uniformly embedded into graphene wrapping N-doped porous carbon microspheres derived from chitosan. Such designed structure offer several favorable features for hydrogen evolution application: 1) the ultrasmall size of Mo2C affords a large exposed active sites; 2) graphene-wrapping ensures great electrical conductivity; 3) porous structure increases the electrolyte-electrode contact points and lowers the charge transfer resistance; 4) N-dopant interacts with H+ better than C atoms and favorably modifies the electronic structures of adjacent Mo and C atoms. As a result, the Mo2C/G-NCS demonstrates superior HER activity with a very low overpotential of 70 or 66 mV to achieve current density of 10 mA cm(-2), small Tafel slope of 39 or 37 mV dec(-1), respectively, in acidic and alkaline media, and high stability, indicating that it is a great potential candidate as HER electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700733, "DOI": "10.1002/advs.201700733", "DOI Link": "http://dx.doi.org/10.1002/advs.201700733", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428310500029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Banerjee, D; Simon, CM; Plonka, AM; Motkuri, RK; Liu, J; Chen, XY; Smit, B; Parise, JB; Haranczyk, M; Thallapally, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Banerjee, Debasis; Simon, Cory M.; Plonka, Anna M.; Motkuri, Radha K.; Liu, Jian; Chen, Xianyin; Smit, Berend; Parise, John B.; Haranczyk, Maciej; Thallapally, Praveen K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework with optimally selective xenon adsorption and separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nuclear energy is among the most viable alternatives to our current fossil fuel-based energy economy. The mass deployment of nuclear energy as a low-emissions source requires the reprocessing of used nuclear fuel to recover fissile materials and mitigate radioactive waste. A major concern with reprocessing used nuclear fuel is the release of volatile radionuclides such as xenon and krypton that evolve into reprocessing facility off-gas in parts per million concentrations. The existing technology to remove these radioactive noble gases is a costly cryogenic distillation; alternatively, porous materials such as metal-organic frameworks have demonstrated the ability to selectively adsorb xenon and krypton at ambient conditions. Here we carry out a high-throughput computational screening of large databases of metal-organic frameworks and identify SBMOF-1 as the most selective for xenon. We affirm this prediction and report that SBMOF-1 exhibits by far the highest reported xenon adsorption capacity and a remarkable Xe/Kr selectivity under conditions pertinent to nuclear fuel reprocessing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11831, "DOI": "10.1038/ncomms11831", "DOI Link": "http://dx.doi.org/10.1038/ncomms11831", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378387300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, XH; Price, MB; Finnegan, JR; Boott, CE; Richter, JM; Rao, A; Menke, M; Friend, RH; Whittell, GR; Manners, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Xu-Hui; Price, Michael B.; Finnegan, John R.; Boott, Charlotte E.; Richter, Johannes M.; Rao, Akshay; Menke, Matthew; Friend, Richard H.; Whittell, George R.; Manners, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-range exciton transport in conjugated polymer nullofibers prepared by seeded growth", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Easily processed materials with the ability to transport excitons over length scales of more than 100 nullometers are highly desirable for a range of light-harvesting and optoelectronic devices. We describe the preparation of organic semiconducting nullofibers comprising a crystalline poly(di-n-hexylfluorene) core and a solvated, segmented corona consisting of polyethylene glycol in the center and polythiophene at the ends. These nullofibers exhibit exciton transfer from the core to the lower-energy polythiophene coronas in the end blocks, which occurs in the direction of the interchain pi-pi stacking with very long diffusion lengths (>200 nullometers) and a large diffusion coefficient (0.5 square centimeters per second). This is made possible by the uniform exciton energetic landscape created by the well-ordered, crystalline nullofiber core.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2018, "Volume": 360, "Issue": 6391, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 897, "End Page": 900, "Article Number": null, "DOI": "10.1126/science.aar8104", "DOI Link": "http://dx.doi.org/10.1126/science.aar8104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433039800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, S; Zhang, SL; Zhang, TR; Yao, QF; Lee, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Sheng; Zhang, Shengliang; Zhang, Tianran; Yao, Qiaofeng; Lee, Jim Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Visible Light-Near-Infrared Dual-Band Smart Window with Internal Energy Storage", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The integration of electrochromic smart windows with energy storage is an appealing concept for green building development. Herein, we report a dual-band electrochromic energy storage (DEES) window capable of independent control of visible light (VIS) and near-infrared (NIR, solar heat) transmittance with a high internal charge storage. The key design feature is the use of composition-optimized Ta-doped nullo-TiO2 nullocrystals as a multifunctional active material to deliver a high charge-storage capability concurrently with high bistability and long-cycle-life electrochromism in three distinct operating modes: (1) the VIS and NIR transparent bright'' mode; (2) the VIS transparent and NIR opaque cool'' mode; and (3) the completely opaque dark'' mode. The independent control of VIS (sunlight) and NIR (solar heat) modulation was successfully demonstrated in a DEES prototype with a high charge-storage capacity of 466.5 mA hr m(-2) at 150 mA m(-2) of current density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1152, "End Page": 1162, "Article Number": null, "DOI": "10.1016/j.joule.2018.12.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.12.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465149000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, T; Zeng, WW; Tie, CJ; Yu, M; Hao, HS; Deng, Y; Li, QQ; Zheng, HR; Wu, MY; Mei, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ting; Zeng, Weiwei; Tie, Changjun; Yu, Mian; Hao, Huisong; Deng, Yang; Li, Qianqian; Zheng, Hairong; Wu, Meiying; Mei, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineered gold/black phosphorus nulloplatforms with remodeling tumor microenvironment for sonoactivated catalytic tumor theranostics", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The imbalance between oxidants and antioxidants in cancer cells would evoke oxidative stress-induced cell death, which has been demonstrated to be highly effective in treating malignullt tumors. Sonodynamic therapy (SDT) adopts ultrasound (US) as the excitation source to induce the production of reactive oxygen species (ROS), which emerges as a noninvasive therapeutic strategy with deep tissue penetration depth and high clinical safety. Herein, we construct novel sonoactivated oxidative stress amplification nulloplatforms by coating MnO2 on Au nulloparticle-anchored black phosphorus nullosheets and decorating soybean phospholipid subsequently (Au/BP@MS). The Au/BP@MS exhibit increased ROS generation efficiency under US irradiation in tumor tissues due to Au/BP nullosensitizer-induced improvement of electron-hole separation as well as MnO2-mediated O-2 generation and GSH depletion, thus leading to notable inhibition effect on tumor growth. Moreover, tumor microenvironment-responsive biodegradability of Au/BP@MS endows them with enhanced magnetic resonullce imaging guidance and clinical potential for cancer theranostics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 515, "End Page": 525, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.09.016", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.09.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000743380700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, T; Li, ZL; Louie, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Ting; Li, Zhenglu; Louie, Steven G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Magnetism and Half-Metallicity in Hole-Doped Monolayer GaSe", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We find, through first-principles calculations, that hole doping induces a ferromagnetic phase transition in monolayer GaSe. Upon increasing hole density, the average spin magnetic moment per carrier increases and reaches a plateau near 1.0 mu(B) per carrier in a range of 3 x 10(13) x cm(2) -1 x 10(14)/cm(2), with the system in a half-metal state before the moment starts to descend abruptly. The predicted itinerant magnetism originates from an exchange splitting of electronic states at the top of the valence band, where the density of states exhibits a sharp van Hove singularity in this quasi-two-dimensional system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2015, "Volume": 114, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 236602, "DOI": "10.1103/PhysRevLett.114.236602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.236602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355727300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, J; Bin Yang, H; Ma, XL; Liu, S; Liu, W; Mao, Q; Huang, YQ; Li, J; Zhang, T; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Jie; Bin Yang, Hong; Ma, Xue-Lu; Liu, Song; Liu, Wei; Mao, Qing; Huang, Yanqiang; Li, Jun; Zhang, Tao; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A tin-based tandem electrocatalyst for CO2 reduction to ethanol with 80% selectivity", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most catalysts that generate appreciable amounts of multicarbon products from electrochemical CO2 reduction are based on Cu. However, the limited understanding of C-C coupling processes over Cu-based catalysts hinders design of more efficient catalysts. Here we report a Cu-free, Sn-based electrocatalyst that exhibits high catalytic performance for reduction of CO2 to ethanol. Our data suggest the catalyst is largely composed of SnS2 nullosheets and single Sn atoms coordinated with three oxygen atoms on three-dimensional carbon. The catalyst achieves a maximum selectivity of approximately 82.5% at 0.9 V-RHE (reversible hydrogen electrode, RHE) and more than 70% over a wide electrode potential window (-0.6 to -1.1 V-RHE); it also maintains 97% of its initial activity (with a geometric current density of 17.8 mA cm(-2) at 0.9 V-RHE) after 100 hours of reaction. First principles modelling suggests that dual active centres comprising Sn and O atoms can adsorb *CHO and *CO(OH) intermediates, respectively, therefore promoting C-C bond formation through a formyl-bicarbonate coupling pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1386, "End Page": 1394, "Article Number": null, "DOI": "10.1038/s41560-023-01389-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01389-3", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001098234800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vegas, AJ; Veiseh, O; Gürtler, M; Millman, JR; Pagliuca, FW; Bader, AR; Doloff, JC; Li, J; Chen, M; Olejnik, K; Tam, HH; Jhunjhunwala, S; Langan, E; Aresta-Dasilva, S; Gandham, S; McGarrigle, JJ; Bochenek, MA; Hollister-Lock, J; Oberholzer, J; Greiner, DL; Weir, GC; Melton, DA; Langer, R; Anderson, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vegas, Arturo J.; Veiseh, Omid; Guertler, Mads; Millman, Jeffrey R.; Pagliuca, Felicia W.; Bader, Andrew R.; Doloff, Joshua C.; Li, Jie; Chen, Michael; Olejnik, Karsten; Tam, Hok Hei; Jhunjhunwala, Siddharth; Langan, Erin; Aresta-Dasilva, Stephanie; Gandham, Srujan; McGarrigle, James J.; Bochenek, Matthew A.; Hollister-Lock, Jennifer; Oberholzer, Jose; Greiner, Dale L.; Weir, Gordon C.; Melton, Douglas A.; Langer, Robert; Anderson, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-term glycemic control using polymer-encapsulated human stem cell-derived beta cells in immune-competent mice", "Source Title": "NATURE MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The transplantation of glucose-responsive, insulin-producing cells offers the potential for restoring glycemic control in individuals with diabetes'. Pancreas transplantation and the infusion of cadaveric islets are currently implemented clinically(2), but these approaches are limited by the adverse effects of immunosuppressive therapy over the lifetime of the recipient and the limited supply of donor tissue(3). The latter concern may be addressed by recently described glucose-responsive mature beta cells that are derived from human embryonic stem cells (referred to as SC-beta cells), which may represent an unlimited source of human cells for pancreas replacement therapy(4). Strategies to address the immunosuppression concerns include immunoisolation of insulin-producing cells with porous biomaterials that function as an immune barrier(5,6). However, clinical implementation has been challenging because of host immune responses to the implant materials(7). Here we report the first long-term glycemic correction of a diabetic, immunocompetent animal model using human SC-beta cells. SC-beta cells were encapsulated with alginate derivatives capable of mitigating foreign-body responses in vivo and implanted into the intraperitoneal space of C57BL/6J mice treated with streptozotocin, which is an animal model for chemically induced type 1 diabetes. These implants induced glycemic correction without any immunosuppression until their removal at 174 d after implantation. Human C-peptide concentrations and in vivo glucose responsiveness demonstrated therapeutically relevant glycemic control. Implants retrieved after 174 d contained viable insulin-producing cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 22, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 306, "End Page": 311, "Article Number": null, "DOI": "10.1038/nm.4030", "DOI Link": "http://dx.doi.org/10.1038/nm.4030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371445100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Tian, XY; Liu, MJ; Guo, H; Zhou, JD; Fang, QY; Liu, Z; Wu, Q; Lou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jing; Tian, Xiaoyin; Liu, Mingjie; Guo, Hua; Zhou, Jiadong; Fang, Qiyi; Liu, Zheng; Wu, Qin; Lou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt-Modulated Molybdenum-Dinitrogen Interaction in MoS2 for Catalyzing Ammonia Synthesis", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dinitrogen conversion to ammonia via electrochemical reduction with over 10% Faradaic efficiency is demonstrated in this work. Co-doped MoS2-x polycrystalline nullosheets with S vacancies as the catalysts are loaded onto carbon cloth by hydrothermal growth from Mo, Co, and S precursors. A sulfur vacancy on the MoS2-x basal plane mimicking the natural Mo-nitrogenase active site is modified by Co doping and exhibits superior dinitrogen-to-ammonia conversion activity. Density-functional simulation reveals that the free energy barrier, which can be compensated by applied overpotential, is reduced from 1.62 to 0.59 eV after Co doping. Meanwhile, dinitrogen tends to be chemically adsorbed to defective MoS2-x, which effectively activates the dinitrogen molecule for the dissociation of the N N triple bond. This process is further accelerated by Co doping, resulting from the modulation of Mo-N bonding configuration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2019, "Volume": 141, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19269, "End Page": 19275, "Article Number": null, "DOI": "10.1021/jacs.9b02501", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b02501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502687800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, BJ; Wang, XW; Han, MJ; Xu, XD; Zhang, ZW; Zhu, C; Cao, X; Yang, YM; Fu, QD; Yang, JQ; Li, XJ; Gao, WB; Zhou, JD; Lin, JH; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Bijun; Wang, Xiaowei; Han, Mengjiao; Xu, Xiaodong; Zhang, Zhaowei; Zhu, Chao; Cao, Xun; Yang, Yumeng; Fu, Qundong; Yang, Jianqun; Li, Xingji; Gao, Weibo; Zhou, Jiadong; Lin, Junhao; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase engineering of Cr5Te8 with colossal anomalous Hall effect", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials that are intrinsically ferromagnetic are crucial for the development of compact spintronic devices. However, most non-layered 2D magnets with a strong ferromagnetic order are difficult to synthesize. Here we show that the flakes of trigonal and monoclinic Cr5Te8 can be grown via a chemical vapour deposition method. Using magneto-optical and magnetotransport measurements, we show that both phases exhibit robust ferromagnetism with strong perpendicular anisotropy at thicknesses of a few nullometres. A high Curie temperature of up to 200 K can be obtained by manipulating the phase structure and thickness. We also observe a colossal anomalous Hall effect in the more structurally distorted monoclinic Cr5Te8, with an anomalous Hall conductivity of 650 omega(-1) cm(-1) and anomalous Hall angle of 5%. Few-nullometre-thick flakes of trigonal and monoclinic Cr5Te8 can be grown using chemical vapour deposition, with the monoclinic phase exhibiting an anomalous Hall conductivity of 650 omega(-1) cm(-1) and anomalous Hall angle of 5%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 224, "End Page": 232, "Article Number": null, "DOI": "10.1038/s41928-022-00754-6", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00754-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788302100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, RZ; Gucci, F; Zhu, HY; Chen, K; Reece, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Rui-Zhi; Gucci, Francesco; Zhu, Hongyu; Chen, Kan; Reece, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-Driven Design of Ecofriendly Thermoelectric High-Entropy Sulfides", "Source Title": "INORGANIC CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy compounds with compositional complexity can be designed as new thermoelectric materials. Here a data-driven model was developed, which chose suitable elements to reduce the enthalpy of formation and hence to increase the chance of single phase formation. Using this model, two high-entropy sulfides were designed, metallic Cu5SnMgGeZnS9 and semiconducting Cu3SnMgInZnS7. They were then successfully fabricated as single-phase dense ceramics with homogeneously distributed cations, and their phase stability and atomic local structures were investigated using density functional theory calculations. Finally, a zT value of 0.58 at 773 K was obtained for Cu5Sn1.2MgGeZnS9, where additional Sn was used to tune the carrier concentration. This work provides a simple approach to find new high-entropy functional materials in the largely unexplored multielement chemical space.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2018, "Volume": 57, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13027, "End Page": 13033, "Article Number": null, "DOI": "10.1021/acs.inorgchem.8b02379", "DOI Link": "http://dx.doi.org/10.1021/acs.inorgchem.8b02379", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447680400065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, XK; Yang, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Xiaokun; Yang, Ronggui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phonon transport in single-layer transition metal dichalcogenides: A first-principles study", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal dichalcogenides (TMDCs) are finding promising electronic and optical applications due to their unique properties. In this letter, we systematically study the phonon transport and thermal conductivity of eight semiconducting single-layer TMDCs, MX2 (M = Mo, W, Zr, and Hf, X = S and Se), by using the first-principles-driven phonon Boltzmann transport equation approach. The validity of the single-mode relaxation time approximation to predict the thermal conductivity of TMDCs is assessed by comparing the results with the iterative solution of the phonon Boltzmann transport equation. We find that the phononic thermal conductivities of 2H-type TMDCs are above 50 W/mK at room temperature while the thermal conductivity values of the 1T-type TMDCs are much lower, when the size of the sample is 1 mu m. A very high thermal conductivity value of 142 W/mK was found in single-layer WS2. The large atomic weight difference between W and S leads to a very large phonon bandgap which in turn forbids the scattering between acoustic and optical phonon modes and thus resulting in very long phonon relaxation time. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 29", "Publication Year": 2014, "Volume": 105, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 131903, "DOI": "10.1063/1.4896685", "DOI Link": "http://dx.doi.org/10.1063/1.4896685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343031700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hendricks, MP; Sato, K; Palmer, LC; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hendricks, Mark P.; Sato, Kohei; Palmer, Liam C.; Stupp, Samuel I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular Assembly of Peptide Amphiphiles", "Source Title": "ACCOUNTS OF CHEMICAL RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CONSPECTUS: Peptide amphiphiles (PAs) are small molecules that contain hydrophobic components covalently conjugated to peptides. In this Account, we describe recent advances involving PAs that consist of a short peptide sequence linked to an aliphatic tail. The peptide sequence can be designed to form beta-sheets among the amino acids near the alkyl tail, while the residues farthest from the tail are charged to promote solubility and in some cases contain a bioactive sequence. In water, beta-sheet formation and hydrophobic collapse of the aliphatic tails induce assembly of the molecules into supramolecular one-dimensional nullostructures, commonly high-aspect-ratio cylindrical or ribbonlike nullofibers. These nullostructures hold significant promise for biomedical functions due to their ability to display a high density of biological signals on their surface for targeting or to activate pathways, as well as for biocompatibility and biodegradable nature. Recent studies have shown that supramolecular systems, such as PAs, often become kinetically trapped in local minima along their self-assembly reaction coordinate, not unlike the pathways associated with protein folding. Furthermore, the assembly pathway can influence the shape, internal structure, and dimension of nullostructures and thereby affect their bioactivity. We discuss methods to map the energy landscape of a PA structure as a function of thermal energy and ionic strength and vary these parameters to convert between kinetically trapped and thermodynamically favorable states. We also demonstrate that the pathway-dependent morphology of the PA assembly can determine biological cell adhesion and survival rates. The dynamics associated with the nullostructures are also critical to their function, and techniques are now available to probe the internal dynamics of these nullostructures. For example, by conjugating radical electron spin labels to PAs, electron paramagnetic resonullce spectroscopy can be used to study the rotational diffusion rates within the fiber, showing a liquidlike to solidlike transition through the cross section of the nullofiber. PAs can also be labeled with fluorescent dyes, allowing the use of super-resolution microscopy techniques to study the molecular exchange dynamics between PA fibers. For a weak hydrogen-bonding PA, individual PA molecules or clusters exchange between fibers in time scales as short as minutes. The amount of hydrogen bonding within PAs that dictates the dynamics also plays an important role in biological function. In one case, weak hydrogen bonding within a PA resulted in cell death through disruption of lipid membranes, while in another example reduced hydrogen bonding enhanced growth factor signaling by increasing lipid raft mobility. PAs are a promising platform for designing advanced hybrid materials. We discuss a covalent polymer with a rigid aromatic imine backbone and alkylated peptide side chains that simultaneously polymerizes and interacts with a supramolecular PA structure with identical chemistry to that of the side chains. The covalent polymerization can be catalyzed by noncovalent polymerization of supramolecular monomers, taking advantage of the dynamic nature of supramolecular assemblies. These novel hybrid structures have potential in self repairing materials and as reusable scaffolds for delivery of drugs or other chemicals. Finally, we highlight recent biomedical applications of PAs and related structures, ranging from bone regeneration to decreasing blood loss during internal bleeding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 50, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2440, "End Page": 2448, "Article Number": null, "DOI": "10.1021/acs.accounts.7b00297", "DOI Link": "http://dx.doi.org/10.1021/acs.accounts.7b00297", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413392000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YJ; Ding, JN; Zhou, WX; Cao, S; Yang, FY; Sun, YY; Zhang, ST; Xue, HG; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yijian; Ding, Jiani; Zhou, Wenxuan; Cao, Shuai; Yang, Feiyu; Sun, Yangyang; Zhang, Songtao; Xue, Huaiguo; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Uniform Hollow Carbon nulloarchitectures: Different Capacitive Deionization between the Hollow Shell Thickness and Cavity Size", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-based materials with high capacitance ability and fast electrosorption rate are ideal electrode materials in capacitive deionization (CDI). However, traditional carbon materials have structural limitations in electrochemical and desalination performance due to the low capacitance and poor transmission channel of the prepared electrodes. Therefore, reasonable design of electrode material structure is of great importance for achieving excellent CDI properties. Here, uniform hollow carbon materials with different morphologies (hollow carbon nullospheres, hollow carbon nullorods, hollow carbon nullo-pseudoboxes, hollow carbon nullo-ellipsoids, hollow carbon nullo-capsules, and hollow carbon nullo-peanuts) are reasonably designed through multi-step template method and calcination of polymer precursors. Hollow carbon nullospheres and hollow carbon nullo-pseudoboxes exhibit better capacitance and higher salt adsorption capacity (SAC) due to their stable carbonaceous structure during calcination. Moreover, the effects of the thickness of the shell and the size of the cavity on the CDI performance are also studied. HCNSs-0.8 with thicker shell (approximate to 20 nm) and larger cavity (approximate to 320 nm) shows the best SAC value of 23.01 mg g(-1) due to its large specific surface area (1083.20 m(2) g(-1)) and rich pore size distribution. These uniform hollow carbon nulloarchitectures with functional properties have potential applications in electrochemistry related fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206960", "DOI Link": "http://dx.doi.org/10.1002/advs.202206960", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913602000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, Z; Manser, JS; Wan, Y; Kamat, PV; Huang, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhi; Manser, Joseph S.; Wan, Yan; Kamat, Prashant V.; Huang, Libai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spatial and temporal imaging of long-range charge transport in perovskite thin films by ultrafast microscopy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charge carrier diffusion coefficient and length are important physical parameters for semiconducting materials. Long-range carrier diffusion in perovskite thin films has led to remarkable solar cell efficiencies; however, spatial and temporal mechanisms of charge transport remain unclear. Here we present a direct measurement of carrier transport in space and in time by mapping carrier density with simultaneous ultrafast time resolution and similar to 50-nm spatial precision in perovskite thin films using transient absorption microscopy. These results directly visualize long-range carrier transport of similar to 220nm in 2 ns for solution-processed polycrystalline CH3NH3PbI3 thin films. Variations of the carrier diffusion coefficient at the mm length scale have been observed with values ranging between 0.05 and 0.08 cm(2) s(-1). The spatially and temporally resolved measurements reported here underscore the importance of the local morphology and establish an important first step towards discerning the underlying transport properties of perovskite materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 345, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7471, "DOI": "10.1038/ncomms8471", "DOI Link": "http://dx.doi.org/10.1038/ncomms8471", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357177600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schreuders, FKG; Dekkers, BL; Bodnár, I; Erni, P; Boom, RM; van der Goot, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schreuders, Floor K. G.; Dekkers, Birgit L.; Bodnar, Igor; Erni, Philipp; Boom, Remko M.; van der Goot, Atze Jan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparing structuring potential of pea and soy protein with gluten for meat analogue preparation", "Source Title": "JOURNAL OF FOOD ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pea protein isolate can be combined with wheat gluten into materials with a fibrous morphology using shear induced structuring combined with heating. Results are partly in-line with soy protein isolate-wheat gluten blends, but the latter yields anisotropic materials in a much broader temperature range. Both blends also have the ability to include air. Air bubbles were aligned and deformed at process conditions that gave the most pronounce fibrous products. Mechanically, the pea protein-gluten materials processed at 140 degrees C had a similar strength as soy protein blends. At 110 and 120 degrees C, the pea protein blends had a strength that was comparable to a chicken meat reference (50-100 kPa) but weaker than their counterparts with soy (220-300 kPa). Blends of pea protein-gluten show potential for preparing structured plant protein materials, but the application area might be different compared with potential applications of soy protein-gluten blends.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 261, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 32, "End Page": 39, "Article Number": null, "DOI": "10.1016/j.jfoodeng.2019.04.022", "DOI Link": "http://dx.doi.org/10.1016/j.jfoodeng.2019.04.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477785500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WX; Yang, TN; Liu, CS; Huang, YH; Chen, CX; Pan, H; Xie, GZ; Tai, HL; Jiang, YD; Wu, YJ; Kang, Z; Chen, LQ; Su, YJ; Hong, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Weixiong; Yang, Tiannull; Liu, Changshu; Huang, Yuhui; Chen, Chunxu; Pan, Hong; Xie, Guangzhong; Tai, Huiling; Jiang, Yadong; Wu, Yongjun; Kang, Zhao; Chen, Long-Qing; Su, Yuanjie; Hong, Zijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimizing Piezoelectric nullocomposites by High-Throughput Phase-Field Simulation and Machine Learning", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric nullocomposites with oxide fillers in a polymer matrix combine the merit of high piezoelectric response of the oxides and flexibility as well as biocompatibility of the polymers. Understanding the role of the choice of materials and the filler-matrix architecture is critical to achieving desired functionality of a composite towards applications in flexible electronics and energy harvest devices. Herein, a high-throughput phase-field simulation is conducted to systematically reveal the influence of morphology and spatial orientation of an oxide filler on the piezoelectric, mechanical, and dielectric properties of the piezoelectric nullocomposites. It is discovered that with a constant filler volume fraction, a composite composed of vertical pillars exhibits superior piezoelectric response and electromechanical coupling coefficient as compared to the other geometric configurations. An analytical regression is established from a linear regression-based machine learning model, which can be employed to predict the performance of nullocomposites filled with oxides with a given set of piezoelectric coefficient, dielectric permittivity, and stiffness. This work not only sheds light on the fundamental mechanism of piezoelectric nullocomposites, but also offers a promising material design strategy for developing high-performance polymer/inorganic oxide composite-based wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105550, "DOI": "10.1002/advs.202105550", "DOI Link": "http://dx.doi.org/10.1002/advs.202105550", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767506500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carrete, J; Li, W; Mingo, N; Wang, SD; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carrete, Jesus; Li, Wu; Mingo, Natalio; Wang, Shidong; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Finding Unprecedentedly Low-Thermal-Conductivity Half-Heusler Semiconductors via High-Throughput Materials Modeling", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lattice thermal conductivity (kappa(omega)) is a key property for many potential applications of compounds. Discovery of materials with very low or high kappa(omega) remains an experimental challenge due to high costs and time-consuming synthesis procedures. High-throughput computational prescreening is a valuable approach for significantly reducing the set of candidate compounds. In this article, we introduce efficient methods for reliably estimating the bulk kappa(omega) for a large number of compounds. The algorithms are based on a combination of machine-learning algorithms, physical insights, and automatic ab initio calculations. We scanned approximately 79,000 half-Heusler entries in the AFLOWLIB.org database. Among the 450 mechanically stable ordered semiconductors identified, we find that kappa(omega) spans more than 2 orders of magnitude-a much larger range than that previously thought. kappa(omega) is lowest for compounds whose elements in equivalent positions have large atomic radii. We then perform a thorough screening of thermodynamical stability that allows us to reduce the list to 75 systems. We then provide a quantitative estimate of kappa(omega) for this selected range of systems. Three semiconductors having kappa(omega) < 5 Wm(-1) K-1 are proposed for further experimental study.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 484, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2014, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11019, "DOI": "10.1103/PhysRevX.4.011019", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.4.011019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332159300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, J; Tang, QL; Fu, YH; Zhang, YL; Hu, JM; Li, T; Zhong, Q; Fan, MH; Kung, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Jie; Tang, Qingli; Fu, Yanghe; Zhang, Yulong; Hu, Juanmin; Li, Tong; Zhong, Qin; Fan, Maohong; Kung, Harold H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Core-Shell Covalently Linked Graphitic Carbon Nitride-Melamine-Resorcinol-Formaldehyde Microsphere Polymers for Efficient Photocatalytic CO2 Reduction to Methanol", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reduction of CO2 with light and H2O to form CH3OH is a promising route to mitigate carbon emissions and climate changes. Although semiconducting metal oxides are potential photocatalysts for this reaction, low photon efficiency and leaching of environmentally unfriendly toxic metals limit their applicability. Here, we report metal-free, core-shell photocatalysts consisting of graphitic carbon nitride (g-C3N4, CN) covalently linked to melamine-resorcinol-formaldehyde (MRF) microsphere polymers for this reaction. Covalent linkage enabled efficient separation of photogenerated carriers and photocatalysis. Using 100 mg of a photocatalyst containing 15 wt % CN, a CH3OH yield of 0.99 mu mol.h(-1) was achieved at a reaction temperature of 80 degrees C and 0.5 MPa with external quantum efficiencies ranging from 5.5% at 380 nm to 1.7% at 550 nm. The yield was about 20 and 10 times higher than that of its components CN and MRF, respectively. Characterization with X-ray photoelectron spectroscopy, transmission electron microscopy, and bulk and surface elemental analyses supported the formation of a core-shell structure and the charge transfer in the C-N bond at the CN-MRF interface between the methoxy group in the 2,4-dihydroxylmethyl-1,3-diphenol part of MRF and the terminal amino groups in CN. This enhanced ligand-to-ligand charge transfer resulted in 67% of the photo-excited internal charge transferred from CN to the hydroxymethylamino group in MRF, whose amino group was the catalytic site for the CO2 photocatalytic reduction to CH3OH. This study provides a series of new metal-free photocatalyst designs and insights into the molecular-level structure-mediated photocatalytic response.Y", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2022, "Volume": 144, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9576, "End Page": 9585, "Article Number": null, "DOI": "10.1021/jacs.1c13301", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c13301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810004000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, GY; Wan, T; BaQais, A; Mu, YR; Cui, DP; Amin, MA; Li, XD; Xu, BB; Zhu, XH; Algadi, H; Li, HD; Wasnik, P; Lu, N; Guo, ZH; Wei, HG; Cheng, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Guanying; Wan, Tong; BaQais, Amal; Mu, Yirui; Cui, Dapeng; Amin, Mohammed A.; Li, Xiaodong; Xu, Ben Bin; Zhu, Xiaohan; Algadi, Hassan; Li, Handong; Wasnik, Priyanka; Lu, Na; Guo, Zhanhu; Wei, Huige; Cheng, Bowen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron and fluorine Co-doped laser-induced graphene towards high-performance micro-supercapacitors", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser-induced graphene (LIG) has attracted extensive research as an electrode material for micro-supercapacitors (MSC). However, the low capacitive performance of LIG arising from both limited specific surface area and few active sites remains challenging. Herein, in situ doping of fluorine and boron atoms into laser-induced graphene was innovatively achieved via laser direct writing approach using boron-doped fluorinated polyimide (FB-PI) as the precursor. The porous fluorine and boron co-doped laser-induced graphene (FB-LIG) exhibits more active sites and improved wettability and significantly enhanced capacitive performance due to the synergistic effect of fluorine and boron co-doping. By tuning the weight ratio of boron to fluorine, the MSC utilizing FB-LIG as the electrode and poly(vinyl alcohol) (PVA)/H2SO4 as the gel electrolyte delivers a high areal capacitance of 49.81 mF/cm2 at a current density of 0.09 mA/cm2, 23 times higher that of MSC from commercial polyimide (PI)-based LIG, and 3 times that of MSC from fluorinated PI-based LIG. In addition, MSCs from FB-LIG possess excellent mechanical stability and flexibility, rendering them promising for flexible wearable microelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 212, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118101, "DOI": "10.1016/j.carbon.2023.118101", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.118101", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001017850000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DF; Li, MN; Yong, X; Song, HQ; Waterhouse, GIN; Yi, YF; Xue, BJ; Zhang, DL; Liu, BZ; Lu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dafeng; Li, Mengnull; Yong, Xue; Song, Haoqiang; Waterhouse, Geoffrey I. N.; Yi, Yunfei; Xue, Bingjie; Zhang, Dongliang; Liu, Baozhong; Lu, Siyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Zn-doped RuO2 nullowires for efficient and stable water oxidation in acidic media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction catalysts capable of working efficiently in acidic media are highly demanded for the commercialization of proton exchange membrane water electrolysis. Herein, we report a Zn-doped RuO2 nullowire array electrocatalyst with outstanding catalytic performance for the oxygen evolution reaction under acidic conditions. Overpotentials as low as 173, 304, and 373 mV are achieved at 10, 500, and 1000 mA cm(-2), respectively, with robust stability reaching to 1000 h at 10 mA cm(-2). Experimental and theoretical investigations establish a clear synergistic effect of Zn dopants and oxygen vacancies on regulating the binding configurations of oxygenated adsorbates on the active centers, which then enables an alternative Ru-Zn dual-site oxide path of the reaction. Due to the change of reaction pathways, the energy barrier of rate-determining step is reduced, and the over-oxidation of Ru active sites is alleviated. As a result, the catalytic activity and stability are significantly enhanced. Ru-based materials are promising catalysts for oxygen evolution reaction in acidic condition, but their catalytic performance needs to be further improved. Here, the authors report Zn-RuO2 nullowires with a Ru-Zn dual-site oxide reaction pathway with enhanced activity and stability for acidic oxygen evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2517, "DOI": "10.1038/s41467-023-38213-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38213-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980689000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YY; Yang, XB; Cheng, ZJ; Lau, CH; Ma, J; Shao, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yuanyuan; Yang, Xiaobin; Cheng, Zhongjun; Lau, Cher Hon; Ma, Jun; Shao, Lu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface manipulation for prevention of migratory viscous crude oil fouling in superhydrophilic membranes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we present a proactive fouling prevention mechanism that endows superhydrophilic membranes with antifouling capability against migratory viscous crude oil fouling. By simulating the hierarchical architecture/chemical composition of a dahlia leaf, a membrane surface is decorated with wrinkled-pattern microparticles, exhibiting a unique proactive fouling prevention mechanism based on a synergistic hydration layer/steric hindrance. The density functional theory and physicochemical characterizations demonstrate that the main chains of the microparticles are bent towards Fe3+ through coordination interactions to create nulloscale wrinkled patterns on smooth microparticle surfaces. nulloscale wrinkled patterns reduce the surface roughness and increase the contact area between the membrane surface and water molecules, expanding the steric hindrance between the oil molecules and membrane surface. Molecular dynamic simulations reveal that the water-molecule densities and strengths of the hydrogen bonds are higher near the resultant membrane surface. With this concept, we can successfully inhibit the initial adhesion, migration, and deposition of oil, regardless of the viscosity, on the membrane surface and achieve migratory viscous crude oil antifouling. This research on the PFP mechanism opens pathways to realize superwettable materials for diverse applications in fields related to the environment, energy, health, and beyond. Minimizing membrane fouling is critical for their continuous and efficient operation. Here, authors demonstrate a wrinkled-pattern microparticles-decorated membrane surface can increase contact area with water molecules, expand steric hindrance, and inhibit adhesion and deposition of oil, achieving efficient migratory viscous crude oil antifouling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2679, "DOI": "10.1038/s41467-023-38419-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38419-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053796300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Huang, R; Ouyang, ZB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yan; Huang, Rui; Ouyang, Zhengbiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Terahertz absorber with dynamically switchable dual-broadband based on a hybrid metamaterial with vanadium dioxide and graphene", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An absorber based on hybrid metamaterial with vanadium dioxide and graphene has been proposed to achieve dynamically switchable dual-broadband absorption property in the terahertz regime. Due to the phase transition of vanadium dioxide and the electrical tunable property of graphene, the dynamically switchablc dual-broadband absorption property is implemented. When the vanadium dioxide is in the metallic phase, the Fermi energy level of graphene is set as zero simultaneously, the high-frequency broadband from 2.05 THz to 4.30 THz can be achieved with the absorptance more than 90%. The tunable absorptance can be realized through thermal control on the conductivity of the vanadium dioxide. The proposed device acts as a low-frequency broadband absorber if the vanadium dioxide is in the insulating phase, for which the Fermi energy level of graphene varies from to 0.1 eV to 0.7 eV. The low-frequency broadband possesses high absorptance which is maintained above 90% from 1.10 THz to 2.30 THz. The absorption intensity can be continuously adjusted from 5.2% to 99.8% by electrically controlling the Fermi energy level of graphene. The absorption window can be further broadened by adjusting the geometrical parameters. Furthermore, the influence of incidence angle on the absorption spectra has been investigated. The proposed absorber has potential applications in the terahertz regime, such as filtering, sensing, cloaking objects, and switches. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2021, "Volume": 29, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20839, "End Page": 20850, "Article Number": null, "DOI": "10.1364/OE.428790", "DOI Link": "http://dx.doi.org/10.1364/OE.428790", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000664025900129", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, DJ; Li, GG; Dang, PP; Zhang, QQ; Wei, Y; Qiu, L; Molokeev, MS; Lian, HZ; Shang, MM; Lin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dongjie; Li, Guogang; Dang, Peipei; Zhang, Qianqian; Wei, Yi; Qiu, Lei; Molokeev, Maxim S.; Lian, Hongzhou; Shang, Mengmeng; Lin, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near-infrared (NIR)-emitting phosphor-converted light-emitting diodes have attracted widespread attention in various applications based on NIR spectroscopy. Except for typical Cr3+-activated NIR-emitting phosphors, next-generation Cr3+-free NIR-emitting phosphors with high efficiency and tunable optical properties are highly desired to enrich the types of NIR luminescent materials for different application fields. Here, we report the Fe3+-activated Sr2-yCay(InSb)(1-z)Sn2zO6 phosphors that exhibit unprecedented long-wavelength NIR emission. The overall emission tuning from 885 to 1005 nm with broadened full-width at half maximum from 108 to 146 nm was realized through a crystallographic site engineering strategy. The NIR emission was significantly enhanced after complete Ca2+ incorporation owing to the substitution-induced lower symmetry of the Fe3+ sites. The Ca2InSbO6:Fe3+ phosphor peaking at 935 nm showed an ultra-high internal quantum efficiency of 87%. The as-synthesized emission-tunable phosphors demonstrated great potential for NIR spectroscopy detection. This work initiates the development of efficient Fe3+-activated broadband NIR-emitting phosphors and opens up a new avenue for designing NIR-emitting phosphor materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112, "DOI": "10.1038/s41377-022-00803-x", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00803-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788327300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hansen, HA; Viswanathan, V; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hansen, Heine A.; Viswanathan, Venkatasubramanian; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unifying Kinetic and Thermodynamic Analysis of 2 e- and 4 e- Reduction of Oxygen on Metal Surfaces", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen electrochemistry has played a key role in developing the foundational understanding of surface electrocatalysis. In this work, we develop a detailed microkinetic model for the oxygen reduction reaction based on density functional theory calculations and molucular dynamics simulations. The developed microkinetic model has a reaction order of 1 in O-2 and a 59 mV/dec Tafel slope in the potential range where the Pt(111) surface is dominated by OH adsorption. Using calculated scaling and Bronsted-Evans-Polanyi relations, we extend this analysis to calculate the activity on materials with a varying OH binding energy. We demonstrate the existence of a kinetic activity volcano which is in close agreement with the thermodynamic activity volcano derived earlier. Both of these analyses identify an activity optimum around 0.1 eV weaker binding of OH relative to Pt(111). The predictions of the kinetic activity volcano are in close agreement with several RDE experiments on metals and Pt alloys. On the basis of rate control analysis and Sabatier analysis, we demonstrate the close connection between the kinetic and thermodynamic formulations for oxygen reduction. We further examine trends in 2e(-) reduction of O-2 to H2O2 and show a similar correspondence between the thermodynamic and kinetic activity volcano with the activity optimum around 0.3 eV weaker OH binding than Pt(111). On the basis of rate control analysis, we show that many elementary steps play a key role in determining the selectivity. This emphasizes the importance of detailed kinetic analysis for addressing trends in selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2014, "Volume": 118, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6706, "End Page": 6718, "Article Number": null, "DOI": "10.1021/jp4100608", "DOI Link": "http://dx.doi.org/10.1021/jp4100608", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334258600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JJ; Lu, GX; You, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jianjun; Lu, Guoxing; You, Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large deformation and energy absorption of additively manufactured auxetic materials and structures: A review", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Different from conventional materials, materials with negative Poisson's ratios expand laterally when stretched longitudinally. Known as 'auxetic' materials, the effect means they possess particularly fascinating properties, which have recently attracted considerable attention in the literature. A range of auxetic materials has been discovered, theoretically designed and fabricated. Developments in additive manufacturing (AM) techniques enable fabrication of materials with intricate cellular architectures. This paper outlines recent progress in the development of auxetic materials and structures, and their mechanical properties under quasi-static and dynamic loading are analysed and summarised. Limited experimental studies on 3D printed auxetic materials and structures are given more attention, ahead of extensively finite element (FE) simulations. A special focus is dedicated to their large, plastic deformation behaviour and energy absorption performance, which should be stressed in their engineering applications; no review paper has yet been found regarding this. Finally, this paper provides an overview of current study limitations, and some future research is envisaged in terms of auxetic materials and structures, nullo-auxetics and additive manufacturing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2020, "Volume": 201, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108340, "DOI": "10.1016/j.compositesb.2020.108340", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2020.108340", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000581931600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tayyab, M; Liu, YJ; Min, SX; Irfan, RM; Zhu, QH; Zhou, L; Lei, JY; Zhang, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tayyab, Muhammad; Liu, Yujie; Min, Shixiong; Irfan, Rana Muhammad; Zhu, Qiaohong; Zhou, Liang; Lei, Juying; Zhang, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneous hydrogen production with the selective oxidation of benzyl alcohol to benzaldehyde by a noble-metal-free photocatalyst VC/CdS nullowires", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work we used CdS NWs (nullowires) with vanadium carbide (VC) attached via facile electrostatic self-assembly and calcination method. The results showed that compared to pristine CdS NWs, the photocatalytic activity of CdS NWs loaded with the particular amount of VC was dramatically enhanced. Among them, the VC/CS-15 indicated the highest enhancement for simultaneous production of H2 with selective oxidation of benzyl alcohol (BO) into benzaldehyde (BD). The highest hydrogen evolution rate of 20.5 mmol g(-1) h(-1) was obtained with more than 99% selectivity for BD production under visible light (lambda > 420 nm) irradiation for 2 h, which was almost 661 times higher than the pristine CdS NWs. This enhancement of photocatalytic activity is due to the VC, which provides a favorable attraction for BO by lowering the zeta potential, along with the active site for hydrogen production, and retard the recombination of electron-hole pairs by increasing the conductivity of the photocatalyst. Moreover, the apparent quantum efficiency (AQE) of VC/CS-15 for BD and H-2 production at monochromatic 420 nm is about 7.5%. At the end of the hydrogen evolution test, the selective oxidation with more than 99% selectivity was obtained. It hopes this work will prove its future significance and move scientific community toward a more economical way for achieving the commercialization of H-2 by photocatalysis. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 43, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1165, "End Page": 1175, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63997-9", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63997-9", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798562100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YC; Gao, P; Li, LZ; Pan, XQ; Tappertzhofen, S; Choi, S; Waser, R; Valov, I; Lu, WD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yuchao; Gao, Peng; Li, Linze; Pan, Xiaoqing; Tappertzhofen, Stefan; Choi, ShinHyun; Waser, Rainer; Valov, Ilia; Lu, Wei D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical dynamics of nulloscale metallic inclusions in dielectrics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale metal inclusions in or on solid-state dielectrics are an integral part of modern electrocatalysis, optoelectronics, capacitors, metamaterials and memory devices. The properties of these composite systems strongly depend on the size, dispersion of the inclusions and their chemical stability, and are usually considered constant. Here we demonstrate that nulloscale inclusions (for example, clusters) in dielectrics dynamically change their shape, size and position upon applied electric field. Through systematic in situ transmission electron microscopy studies, we show that fundamental electrochemical processes can lead to universally observed nucleation and growth of metal clusters, even for inert metals like platinum. The clusters exhibit diverse dynamic behaviours governed by kinetic factors including ion mobility and redox rates, leading to different filament growth modes and structures in memristive devices. These findings reveal the microscopic origin behind resistive switching, and also provide general guidance for the design of novel devices involving electronics and ionics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 776, "Times Cited, All Databases": 833, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4232, "DOI": "10.1038/ncomms5232", "DOI Link": "http://dx.doi.org/10.1038/ncomms5232", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338840000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Wang, ZJ; Pang, WK; Lie, W; Yuwono, JA; Liang, GM; Liu, SL; D' Angelo, AM; Deng, JJ; Fan, YM; Davey, K; Li, BH; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yanyan; Wang, Zhijie; Pang, Wei Kong; Lie, Wilford; Yuwono, Jodie A.; Liang, Gemeng; Liu, Sailin; D' Angelo, Anita M.; Deng, Jiaojiao; Fan, Yameng; Davey, Kenneth; Li, Baohua; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent control of water O-H bonds for highly reversible zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-ion batteries have attracted increasing research interest; however, the development of these batteries has been hindered by several challenges, including dendrite growth, Zn corrosion, cathode material degradation, limited temperature adaptability and electrochemical stability window, which are associated with water activity and the solvation structure of electrolytes. Here we report that water activity is suppressed by increasing the electron density of the water protons through interactions with highly polar dimethylacetamide and trimethyl phosphate molecules. Meanwhile, the Zn corrosion in the hybrid electrolyte is mitigated, and the electrochemical stability window and the operating temperature of the electrolyte are extended. The dimethylacetamide alters the surface energy of Zn, guiding the (002) plane dominated deposition of Zn. Molecular dynamics simulation evidences Zn2+ ions are solvated with fewer water molecules, resulting in lower lattice strain in the NaV3O8 center dot 1.5H(2)O cathode during the insertion of hydrated Zn2+ ions, boosting the lifespan of Zn|| NaV3O8 center dot 1.5H(2)O cell to 3000 cycles. The electrochemical performance of aqueous zinc ion batteries is limited by water activity. Here, the authors propose a hybrid electrolyte that incorporate strongly polar molecules to strengthen the water O-H bonds, thus reduce water activity and improve the electrochemical performance of the batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2720, "DOI": "10.1038/s41467-023-38384-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38384-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992465700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Bai, X; Yang, TZ; Luo, HL; Qiu, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ying; Bai, Xue; Yang, Tianzhi; Luo, Hailu; Qiu, Cheng-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structured thermal surface for radiative camouflage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal camouflage has been successful in the conductive regime, where thermal meta-materials embedded in a conductive system can manipulate heat conduction inside the bulk. Most reported approaches are background-dependent and not applicable to radiative heat emitted from the surface of the system. A coating with engineered emissivity is one option for radiative camouflage, but only when the background has uniform temperature. Here, we propose a strategy for radiative camouflage of external objects on a given background using a structured thermal surface. The device is non-invasive and restores arbitrary background temperature distributions on its top. For many practical candidates of the background material with similar emissivity as the device, the object can thereby be radiatively concealed without a priori knowledge of the host conductivity and temperature. We expect this strategy to meet the demands of anti-detection and thermal radiation manipulation in complex unknown environments and to inspire developments in phononic and photonic thermotronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 273, "DOI": "10.1038/s41467-017-02678-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02678-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422745800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mousavi, SH; Khanikaev, AB; Wang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mousavi, S. Hossein; Khanikaev, Alexander B.; Wang, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topologically protected elastic waves in phononic metamaterials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface waves in topological states of quantum matter exhibit unique protection from backscattering induced by disorders, making them ideal carriers for both classical and quantum information. Topological matters for electrons and photons are largely limited by the range of bulk properties, and the associated performance trade-offs. In contrast, phononic metamaterials provide access to a much wider range of material properties. Here we demonstrate numerically a phononic topological metamaterial in an elastic-wave analogue of the quantum spin Hall effect. A dual-scale phononic crystal slab is used to support two effective spins for phonons over a broad bandwidth, and strong spin-orbit coupling is realized by breaking spatial mirror symmetry. By preserving the spin polarization with an external load or spatial symmetry, phononic edge states are shown to be robust against scattering from discrete defects as well as disorders in the continuum, demonstrating topological protection for phonons in both static and time-dependent regimes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 675, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8682, "DOI": "10.1038/ncomms9682", "DOI Link": "http://dx.doi.org/10.1038/ncomms9682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366288900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takabatake, T; Suekuni, K; Nakayama, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takabatake, Toshiro; Suekuni, Koichiro; Nakayama, Tsuneyoshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phonon-glass electron-crystal thermoelectric clathrates: Experiments and theory", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Type-I clathrate compounds have attracted a great deal of interest in connection with the search for efficient thermoelectric materials. These compounds constitute networked cages consisting of nulloscale tetrakaidecahedrons (14-hedrons) and dodecahedrons (12-hedrons), in which the group-1 or -2 elements in the periodic table are encaged as so-called rattling guest atoms. It is remarkable that, although these compounds have a crystalline cubic structure, they exhibit glasslike phonon thermal conductivity over the whole temperature range depending on the states of rattling guest atoms in the tetrakaidecahedron. In addition, these compounds show unusual glasslike specific heats and terahertz-frequency phonon dynamics, providing a remarkable broad peak almost identical to those observed in amorphous materials or structural glasses, the so-called boson peak. An efficient thermoelectric effect is realized in compounds showing these glasslike characteristics. In this decade, a number of experimental works dealing with type-I clathrate compounds have been published. These are diffraction, thermal, and spectroscopic experiments in addition to those based on heat and electronic transport. These form the raw materials for this review based on advances from this decade. The subject of this review involves interesting phenomena from the viewpoint not only of physics but also of the practical problem of elaborating efficient thermoelectric materials. This review presents a survey of a wide range of experimental investigations of type-I clathrate compounds, together with a review of theoretical interpretations of the peculiar thermal and dynamic properties observed in these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 4", "Publication Year": 2014, "Volume": 86, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 669, "End Page": 716, "Article Number": null, "DOI": "10.1103/RevModPhys.86.669", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.86.669", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338646300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, C; Yue, KH; Han, JJ; Liu, XZ; Liu, LJ; Liu, QN; Kong, QY; Pao, CW; Hu, ZW; Suenaga, K; Su, D; Zhang, QB; Wang, XY; Tan, YZ; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Chun; Yue, Kaihang; Han, Jiajia; Liu, Xiaozhi; Liu, Lijia; Liu, Qiunull; Kong, Qingyu; Pao, Chih-Wen; Hu, Zhiwei; Suenaga, Kazu; Su, Dong; Zhang, Qiaobao; Wang, Xianying; Tan, Yuanzhi; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Misoriented high-entropy iridium ruthenium oxide for acidic water splitting", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing an efficient catalyst for acidic oxygen evolution reaction (OER) is of critical importance in manipulating proton exchange membrane water electrolyzer (PEMWE) for hydrogen production. Here, we report a fast, nonequilibrium strategy to synthesize quinary high-entropy ruthenium iridium-based oxide (M-RuIrFeCoNiO2) with abundant grain boundaries (GB), which exhibits a low overpotential of 189 millivolts at 10 milliamperes per square centimeter for OER in 0.5 M H2SO4. Microstructural analyses, density functional calculations, and isotope-labeled differential electrochemical mass spectroscopy measurements collectively reveal that the integration of foreign metal elements and GB is responsible for the enhancement of activity and stability of RuO2 toward OER. A PEMWE using M-RuIrFeCoNiO2 catalyst can steadily operate at a large current density of 1 ampere per square centimeter for over 500 hours. This work demonstrates a pathway to design high-performance OER electrocatalysts by integrating the advantages of various components and GB, which breaks the limits of thermodynamic solubility for different metal elements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2023, "Volume": 9, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf9144", "DOI": "10.1126/sciadv.adf9144", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf9144", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001068543100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZY; Sun, QD; Lu, Y; Lu, F; Mu, XL; Wei, SH; Sui, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zeyu; Sun, Qingde; Lu, Yue; Lu, Feng; Mu, Xulin; Wei, Su-Huai; Sui, Manling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogenated Cs2AgBiBr6 for significantly improved efficiency of lead-free inorganic double perovskite solar cell", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though inorganic perovskites are an attractive, non-toxic and stable alternative to organic-inorganic halide perovskite solar cells, realizing efficient devices remains a challenge. Here, the authors report hydrogenated lead-free inorganic perovskite solar cells with enhanced power conversion efficiency. Development of lead-free inorganic perovskite material, such as Cs2AgBiBr6, is of great importance to solve the toxicity and stability issues of traditional lead halide perovskite solar cells. However, due to a wide bandgap of Cs2AgBiBr6 film, its light absorption ability is largely limited and the photoelectronic conversion efficiency is normally lower than 4.23%. In this text, by using a hydrogenation method, the bandgap of Cs2AgBiBr6 films could be tunable from 2.18 eV to 1.64 eV. At the same time, the highest photoelectric conversion efficiency of hydrogenated Cs2AgBiBr6 perovskite solar cell has been improved up to 6.37% with good environmental stability. Further investigations confirmed that the interstitial doping of atomic hydrogen in Cs2AgBiBr6 lattice could not only adjust its valence and conduction band energy levels, but also optimize the carrier mobility and carrier lifetime. All these works provide an insightful strategy to fabricate high performance lead-free inorganic perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3397, "DOI": "10.1038/s41467-022-31016-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31016-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810727500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HD; Xue, YR; Hui, L; Zhang, C; Fang, Y; Liu, YX; Chen, X; Zhang, DY; Huang, BL; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Huidi; Xue, Yurui; Hui, Lan; Zhang, Chao; Fang, Yan; Liu, Yuxin; Chen, Xi; Zhang, Danyan; Huang, Bolong; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphdiyne-based metal atomic catalysts for synthesizing ammonia", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of novel catalysts for nitrogen reduction at ambient pressures and temperatures with ultrahigh ammonia (NH3) yield and selectivity is challenging. In this work, an atomic catalyst with separated Pd atoms on graphdiyne (Pd-GDY) was synthesized, which shows fascinating electrocatalytic properties for nitrogen reduction. The catalyst has the highest average NH3 yield of 4.45 +/- 0.30 mg(NH3) mg(Pd)(-1) h(-1), almost tens of orders larger than for previously reported catalysts, and 100% reaction selectivity in neutral media. Pd-GDY exhibits almost no decreases in NH3 yield and Faradaic efficiency. Density functional theory calculations show that the reaction pathway prefers to perform at the (Pd, C1, C2) active area because of the strongly coupled (Pd, C1, C2), which elevates the selectivity via enhanced electron transfer. By adjusting the p-d coupling accurately, reduction of self-activated nitrogen is promoted by anchoring atom selection, and side effects are minimized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwaa213", "DOI": "10.1093/nsr/nwaa213", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa213", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692594900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bian, H; Bai, DL; Jin, ZW; Wang, K; Liang, L; Wang, HR; Zhang, JR; Wang, Q; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bian, Hui; Bai, Dongliang; Jin, Zhiwen; Wang, Kang; Liang, Lei; Wang, Haoran; Zhang, Jingru; Wang, Qian; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graded Bandgap CsPbI2+xBr1-x Perovskite Solar Cells with a Stabilized Efficiency of 14.4%", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-inorganic perovskite shows great potential for photovoltaic applications due to its excellent solar cell performance and atmospheric stability. Here, a CsPbI2+xBr1-x perovskite solar cell with a graded bandgap is explored using CsPbBrI2 and CsPbI3 quantum dots as component cells. Four strategies were pursued to boost the device performance. First, CsPbI2Br film was fabricated as the main absorber, with the component cell showing remarkable power conversion efficiency (PCE) as high as 13.45%. Second, by Mn2+ substitution, SCN- capping, and [(NH2)(2)CH](+) treatment, stable and high-mobility CsPbI3 quantum dot (QD) film was attained. Third, a halide-ion-profiled heterojunction was designed at the CsPbBrI2/CsPbI3 QD interface to achieve proper band-edge bending as graded bandgap for improved carrier collection. Finally, the CsPbI3 QD layer was optimized in the graded bandgap structure to achieve maximum overall light harvesting. As a result, the device achieved a PCE of 14.45%. This is the highest efficiency ever reported for inorganic perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1500, "End Page": 1510, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441627400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, J; Feng, XY; Wu, YY; Wang, YD; Liu, PC; Shang, K; Jiang, H; Hou, XL; Mitlin, D; Xiang, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Jian; Feng, Xuyong; Wu, Yueyue; Wang, Yueda; Liu, Pengcheng; Shang, Ke; Jiang, Hao; Hou, Xianglong; Mitlin, David; Xiang, Hongfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable sodium anodes for sodium metal batteries (SMBs) enabled by in-situ formed quasi solid-state polymer electrolyte", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-performance quasi-solid polymer electrolyte for sodium metal batteries (SMBs) based on in-situ polymerized poly(1,3-dioxolane) (DOL) with 20% volume ratio of fluoroethylene carbonate (FEC), termed PDFE-20, is proposed in this work. It is demonstrated PDFE-20 possesses a room-temperature ionic con-ductivity of 3.31 x 10-3 S cm-1, an ionic diffusion activation energy of 0.10 eV, and an oxidation potential of 4.4 V. SMBs based on PDFE-20 and Na3V2(PO4)3 (NVP) cathodes were evaluated with an active material mass loading of 6.8 mg cm-2. The cell displayed an initial discharge specific capacity of 104 mA h g-1, and 97.1% capacity retention after 100 cycles at 0.5 C. In-situ polymerization conformally coats the anode/-cathode interfaces, avoiding geometrical gaps and high charge transfer resistance with ex-situ polymer-ization of the same chemistry. FEC acts as a plasticizer during polymerization to suppress crystallization and significantly improves ionic transport. During battery cycling FEC promotes mechanical congruence of electrolyte-electrode interfaces while forming a stable NaF-rich solid electrolyte interphase (SEI) at the anode. Density functional theory (DFT) calculations were also performed to further understand the role FEC in the poly(DOL)-FEC electrolytes. This work broadens the application of in-situ prepared poly(DOL) electrolytes to sodium storage and demonstrates the crucial role of FEC in improving the electrochemical performance.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 77, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 299, "Article Number": null, "DOI": "10.1016/j.jechem.2022.09.040", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2022.09.040", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000917913300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nukala, P; Ahmadi, M; Wei, YF; de Graaf, S; Stylianidis, E; Chakrabortty, T; Matzen, S; Zandbergen, HW; Björling, A; Mannix, D; Carbone, D; Kooi, B; Noheda, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nukala, Pavan; Ahmadi, Majid; Wei, Yingfen; de Graaf, Sytze; Stylianidis, Evgenios; Chakrabortty, Tuhin; Matzen, Sylvia; Zandbergen, Henny W.; Bjorling, Alexander; Mannix, Dan; Carbone, Dina; Kooi, Bart; Noheda, Beatriz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible oxygen migration and phase transitions in hafnia-based ferroelectric devices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unconventional ferroelectricity exhibited by hafnia-based thin films-robust at nulloscale sizes-presents tremendous opportunities in nulloelectronics. However, the exact nature of polarization switching remains controversial. We investigated a La0.67Sr0.33MnO3/Hf0.5Zr0.5O2 capacitor interfaced with various top electrodes while performing in situ electrical biasing using atomic-resolution microscopy with direct oxygen imaging as well as with synchrotron nullobeam diffraction. When the top electrode is oxygen reactive, we observe reversible oxygen vacancy migration with electrodes as the source and sink of oxygen and the dielectric layer acting as a fast conduit at millisecond time scales. With nonreactive top electrodes and at longer time scales (seconds), the dielectric layer also acts as an oxygen source and sink. Our results show that ferroelectricity in hafnia-based thin films is unmistakably intertwined with oxygen voltammetry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2021, "Volume": 372, "Issue": 6542, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 630, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf3789", "DOI Link": "http://dx.doi.org/10.1126/science.abf3789", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649103500046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hung, WY; Fang, GC; Lin, SW; Cheng, SH; Wong, KT; Kuo, TY; Chou, PT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hung, Wen-Yi; Fang, Guan-Cheng; Lin, Shih-Wei; Cheng, Shuo-Hsien; Wong, Ken-Tsung p; Kuo, Ting-Yi; Chou, Pi-Tai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The First Tandem, All-exciplex-based WOLED", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploiting our recently developed bilayer interface methodology, together with a new wide energy-gap, low LUMO acceptor (A) and the designated donor (D) layers, we succeeded in fabricating an exciplex-based organic light-emitting diode (OLED) systematically tuned from blue to red. Further optimization rendered a record-high blue exciplex OLED with eta(ext) of 8%. We then constructed a device structure configured by two parallel blend layers of mCP/PO-T2T and DTAF/PO-T2T, generating blue and yellow exciplex emission, respectively. The resulting device demonstrates for the first time a tandem, all-exciplex-based white-light OLED (WOLED) with excellent efficiencies eta(ext): 11.6%, eta(c): 27.7 cd A(-1), and eta(p): 15.8 ml W-1 with CIE(0.29, 0.35) and CRI 70.6 that are nearly independent of EL intensity. The tandem architecture and blend-layer D/A (151) configuration are two key elements that fully utilize the exciplex delay fluorescence, providing a paragon for the use of low-cost, abundant organic compounds en route to commercial WOLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 4", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5161, "DOI": "10.1038/srep05161", "DOI Link": "http://dx.doi.org/10.1038/srep05161", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336723500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brutman, JP; Delgado, PA; Hillmyer, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brutman, Jacob P.; Delgado, Paula A.; Hillmyer, Marc A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polylactide Vitrimers", "Source Title": "ACS MACRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While much research has been aimed at new approaches to the healing of cross-linked polymers, there is a dearth of effort in the healing of renewable cross-linked polymers. In this study, the healing ability of renewable polylactide-based vitrimers containing Sn(Oct)(2) was investigated. The vitrimers were prepared from hydroxyl-terminated star-shaped poly((+/-)-lactide) samples that were cross-linked with methylenediphenyl diisocyanate. Cross-linked samples were prepared with isocyanate:hydroxyl (IC:OH) ratios of 0.6:1 to 1.1:1 and initial catalyst:hydroxyl (Sn(Oct)(2):OH) ratios ranging from 0.013:1 to 0.050:1. The plateau modulus and T-g values for the cross-linked samples decreased with decreasing IC:OH ratio. The materials were subjected to stress relaxation analyses, which confirmed that the materials not only were vitrimeric in nature but also exhibited remarkably short characteristic relaxation times of less than 50 s at 140 degrees C. Finally, vitrimers fractured in uniaxial tensile testing were healed by compression molding and exhibited up to 67% recovery of ultimate elongation, up to 102% recovery of tensile strength, and up to 133% recovery of tensile modulus values.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 607, "End Page": 610, "Article Number": null, "DOI": "10.1021/mz500269w", "DOI Link": "http://dx.doi.org/10.1021/mz500269w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339226200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vo, TH; Shekhirev, M; Kunkel, DA; Morton, MD; Berglund, E; Kong, LM; Wilson, PM; Dowben, PA; Enders, A; Sinitskii, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vo, Timothy H.; Shekhirev, Mikhail; Kunkel, Donna A.; Morton, Martha D.; Berglund, Eric; Kong, Lingmei; Wilson, Peter M.; Dowben, Peter A.; Enders, Axel; Sinitskii, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale solution synthesis of narrow graphene nulloribbons", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "According to theoretical studies, narrow graphene nulloribbons with atomically precise armchair edges and widths of <2 nm have a bandgap comparable to that in silicon (1.1 eV), which makes them potentially promising for logic applications. Different top-down fabrication approaches typically yield ribbons with width >10nm and have limited control over their edge structure. Here we demonstrate a novel bottom-up approach that yields gram quantities of high-aspect-ratio graphene nulloribbons, which are only similar to 1 nm wide and have atomically smooth armchair edges. These ribbons are shown to have a large electronic bandgap of similar to 1.3 eV, which is significantly higher than any value reported so far in experimental studies of graphene nulloribbons prepared by top-down approaches. These synthetic ribbons could have lengths of 4100 nm and self-assemble in highly ordered few-micrometer-long 'nullobelts' that can be visualized by conventional microscopy techniques, and potentially used for the fabrication of electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3189, "DOI": "10.1038/ncomms4189", "DOI Link": "http://dx.doi.org/10.1038/ncomms4189", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332661800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, SY; Li, Y; Li, X; Zhou, YJ; Dang, ZQ; Rong, JH; Dong, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Shiyin; Li, Yang; Li, Xu; Zhou, Yujun; Dang, Ziqi; Rong, Jianhua; Dong, Liubing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable Zinc Anodes Enabled by Zincophilic Cu nullowire Networks", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn-based electrochemical energy storage (EES) systems have received tremendous attention in recent years, but their zinc anodes are seriously plagued by the issues of zinc dendrite and side reactions (e.g., corrosion and hydrogen evolution). Herein, we report a novel strategy of employing zincophilic Cu nullowire networks to stabilize zinc anodes from multiple aspects. According to experimental results, COMSOL simulation and density functional theory calculations, the Cu nullowire networks covering on zinc anode surface not only homogenize the surface electric field and Zn2+ concentration field, but also inhibit side reactions through their hydrophobic feature. Meanwhile, facets and edge sites of the Cu nullowires, especially the latter ones, are revealed to be highly zincophilic to induce uniform zinc nucleation/deposition. Consequently, the Cu nullowire networks- protected zinc anodes exhibit an ultralong cycle life of over 2800 h and also can continuously operate for hundreds of hours even at very large charge/discharge currents and areal capacities (e.g., 10 mA cm(-2) and 5 mAh cm(-2)), remarkably superior to bare zinc anodes and most of currently reported zinc anodes, thereby enabling Zn-based EES devices to possess high capacity, 16,000-cycle lifespan and rapid charge/discharge ability. This work provides new thoughts to realize long-life and high-rate zinc anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 39, "DOI": "10.1007/s40820-021-00783-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00783-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000734156400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, PC; Zhang, R; Yao, LB; Qin, JY; Kisslinger, K; Zhuang, HL; Xin, HLL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Peichao; Zhang, Rui; Yao, Libing; Qin, Jiayi; Kisslinger, Kim; Zhuang, Houlong; Xin, Huolin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-Rate and Long-Life Zinc-Metal Anodes Enabled by Self-Accelerated Cation Migration", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc ion batteries are receiving unprecedented attention owing to their markedly high safety and sustainability, yet their lifespan particularly at high rates is largely limited by the poor reversibility of zinc metal anodes, due to the random ion diffusion and sluggish ion replenishment at the reaction interface. Here, a tunnel-rich and corona-poled ferroelectric polymer-inorganic-composite thin film coating for Zn metal anodes to tackle above problems, is proposed. It is demonstrated that the poled ferroelectric coating can better deconcentrate and self-accelerate ion migration at coating/Zn interface during the electroplating process than untreated ferroelectric coating and bare Zn, thus enabling a compact and horizontally-aligned Zn morphology even at ultrahigh rates. Notably, a maximal cumulative plating capacity of over 6500 mAh cm(-2) (at 10 mA cm(-2)) is achieved for the surface-modified Zn metal anode, showing extraordinary reversibility of Zn plating/stripping. This work provides new insights in stabilizing Zn metal electrodeposition at the scale of interfacial ion diffusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 11, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100982, "DOI": "10.1002/aenm.202100982", "DOI Link": "http://dx.doi.org/10.1002/aenm.202100982", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000666871700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZY; Zhao, ZQ; Hou, YL; Wang, H; Li, XP; He, G; Zhang, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zeyuan; Zhao, Zhengqing; Hou, Yali; Wang, Heng; Li, Xiaopeng; He, Gang; Zhang, Mingming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous Platinum(II)-Cage-Based Light-Harvesting System for Photocatalytic Cross-Coupling Hydrogen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photosynthesis is a process wherein the chromophores in plants and bacteria absorb light and convert it into chemical energy. To mimic this process, an emissive poly(ethylene glycol)-decorated tetragonal prismatic platinum(II) cage was prepared and used as the donor molecule to construct a light-harvesting system in water. EosinY was chosen as the acceptor because of its good spectral overlap with that of the metallacage, which is essential for the preparation of light-harvesting systems. Such a combination showed enhanced catalytic activity in catalyzing the cross-coupling hydrogen evolution reaction, as compared with eosinY alone. This study offers a pathway for using the output energy from the light-harvesting system to mimic the whole photosynthetic process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2019, "Volume": 58, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8862, "End Page": 8866, "Article Number": null, "DOI": "10.1002/anie.201904407", "DOI Link": "http://dx.doi.org/10.1002/anie.201904407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474806700041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, XS; Su, HZ; He, SF; Song, YA; Wang, YB; Qin, ZZ; Wu, YZ; Yang, XD; Han, QF; Fang, JF; Zhang, YQ; Segawa, H; Grätzel, M; Han, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Xuesong; Su, Hongzhen; He, Sifan; Song, Yenull; Wang, Yanbo; Qin, Zhenzhen; Wu, Yongzhen; Yang, Xudong; Han, Qifeng; Fang, Junfeng; Zhang, Yiqiang; Segawa, Hiroshi; Graetzel, Michael; Han, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ growth of graphene on both sides of a Cu-Ni alloy electrode for perovskite solar cells with improved stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The instability of rear electrodes undermines the long-term operational durability of efficient perovskite solar cells. Here, a composite electrode of copper-nickel (Cu-Ni) alloy stabilized by in situ grown bifacial graphene is designed. The alloying makes the work function of Cu suitable for regular perovskite solar cells. Cu-Ni is the ideal substrate for preparing high-quality graphene via chemical vapour deposition, which simultaneously protects the device from oxygen, water and reactions between internal components. To rivet the composite electrode with the semi-device, a thermoplastic copolymer is applied as an adhesive layer through hot pressing. The resulting devices achieve power conversion efficiencies of 24.34% and 20.76% (certified 20.86%) with aperture areas of 0.09 and 1.02 cm(2), respectively. The devices show improved stability: 97% of their initial efficiency is retained after 1,440 hours of a damp-heat test at 85 degrees C with a relative humidity of 85%; 95% of their initial efficiency is retained after 5,000 hours at maximum power point tracking under continuous 1 sun illumination. The instability of contact layers for perovskite solar cells under operating conditions limits the deployment of the technology. Now, Lin et al. develop a Cu-Ni electrode sandwiched between in situ-grown graphene protective layers, enabling solar cells with improved stability under light, humidity and high temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 520, "End Page": 527, "Article Number": null, "DOI": "10.1038/s41560-022-01038-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01038-1", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000802955400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Eperon, GE; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Eperon, Giles E.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal halide perovskites for energy applications", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring prospective materials for energy production and storage is one of the biggest challenges of this century. Solar energy is one of the most important renewable energy resources, due to its wide availability and low environmental impact. Metal halide perovskites have emerged as a class of semiconductor materials with unique properties, including tunable bandgap, high absorption coefficient, broad absorption spectrum, high charge carrier mobility and long charge diffusion lengths, which enable a broad range of photovoltaic and optoelectronic applications. Since the first embodiment of perovskite solar cells showing a power conversion efficiency of 3.8%, the device performance has been boosted up to a certified 22.1% within a few years. In this Perspective, we discuss differing forms of perovskite materials produced via various deposition procedures. We focus on their energy-related applications and discuss current challenges and possible solutions, with the aim of stimulating potential new applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 888, "Times Cited, All Databases": 941, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16048, "DOI": "10.1038/NENERGY.2016.48", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.48", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394124200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "null, TX; Lin, H; Gao, Y; Matyushov, A; Yu, GL; Chen, HH; Sun, N; Wei, SJ; Wang, ZG; Li, MH; Wang, XJ; Belkessam, A; Guo, RD; Chen, B; Zhou, J; Qian, ZY; Hui, Y; Rinaldi, M; McConney, ME; Howe, BM; Hu, ZQ; Jones, JG; Brown, GJ; Sun, NX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "null, Tianxiang; Lin, Hwaider; Gao, Yuan; Matyushov, Alexei; Yu, Guoliang; Chen, Huaihao; Sun, Neville; Wei, Shengjun; Wang, Zhiguang; Li, Menghui; Wang, Xinjun; Belkessam, Amine; Guo, Rongdi; Chen, Brian; Zhou, James; Qian, Zhenyun; Hui, Yu; Rinaldi, Matteo; McConney, Michael E.; Howe, Brandon M.; Hu, Zhongqiang; Jones, John G.; Brown, Gail J.; Sun, Nian Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acoustically actuated ultra-compact NEMS magnetoelectric antennas", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "State-of-the-art compact antennas rely on electromagnetic wave resonullce, which leads to antenna sizes that are comparable to the electromagnetic wavelength. As a result, antennas typically have a size greater than one-tenth of the wavelength, and further miniaturization of antennas has been an open challenge for decades. Here we report on acoustically actuated nullomechanical magnetoelectric (ME) antennas with a suspended ferromagnetic/ piezoelectric thin-film heterostructure. These ME antennas receive and transmit electromagnetic waves through the ME effect at their acoustic resonullce frequencies. The bulk acoustic waves in ME antennas stimulate magnetization oscillations of the ferromagnetic thin film, which results in the radiation of electromagnetic waves. Vice versa, these antennas sense the magnetic fields of electromagnetic waves, giving a piezoelectric voltage output. The ME antennas (with sizes as small as one-thousandth of a wavelength) demonstrates 1-2 orders of magnitude miniaturization over state-of-the-art compact antennas without performance degradation. These ME antennas have potential implications for portable wireless communication systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 296, "DOI": "10.1038/s41467-017-00343-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00343-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408091000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, JY; Chen, ZY; Pan, DY; Li, HZ; Shen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jiayi; Chen, Zhiyi; Pan, Daoyan; Li, Huaizhi; Shen, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Umbilical Cord-Derived Mesenchymal Stem Cell-Derived Exosomes Combined Pluronic F127 Hydrogel Promote Chronic Diabetic Wound Healing and Complete Skin Regeneration", "Source Title": "INTERNATIONAL JOURNAL OF nullOMEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Purpose: Chronic refractory wounds are a multifactorial comorbidity of diabetes mellitus with the characteristic of impaired vascular networks. Currently, there is a lack of effective treatments for such wounds. Various types of mesenchymal stem cell-derived exosomes (MSC-exos) have been shown to exert multiple therapeutic effects on skin regeneration. We aimed to determine whether a constructed combination of human umbilical cord MSC (hUCMSC)-derived exosomes (hUCMSC-exos) and Pluronic F-127 (PF-127) hydrogel could improve wound healing. Materials and Methods: We topically applied human umbilical cord-derived MSC (hUCMSC)-derived exosomes (hUCMSC-exos) encapsulated in a thermosensitive PF-127 hydrogel to a full-thickness cutaneous wound in a streptozotocin-induced diabetic rat model. The material properties and wound healing ability of the hydrogel and cellular responses were analyzed. Results: Compared with hUCMSC-exos, PF-127-only or control treatment, the combination of PF-127 and hUCMSC-exos resulted in a significantly accelerated wound closure rate, increased expression of CD31 and Ki67, enhanced regeneration of granulation tissue and upregulated expression of vascular endothelial growth factor (VEGF) and factor transforming growth factor beta-1 (TGF beta-1). Conclusion: The efficient delivery of hUCMSC-exos in PF-127 gel and improved exosome ability could promote diabetic wound healing. Thus, this biomaterial-based exosome therapy may represent a new therapeutic approach for cutaneous regeneration of chronic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2020, "Volume": 15, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5911, "End Page": 5926, "Article Number": null, "DOI": "10.2147/IJN.S249129", "DOI Link": "http://dx.doi.org/10.2147/IJN.S249129", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577115800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, HY; Guo, LT; Xue, H; Zhang, Y; Shen, XF; Liu, XT; Wang, PH; He, X; Dai, GZ; Jiang, P; Zheng, HW; Zhang, BB; Xu, C; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Haiyang; Guo, Litong; Xue, Hao; Zhang, Ying; Shen, Xiaofang; Liu, Xiaoting; Wang, Peihong; He, Xu; Dai, Guozhang; Jiang, Peng; Zheng, Haiwu; Zhang, Binbin; Xu, Cheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying and understanding the triboelectric series of inorganic non-metallic materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Contact-electrification is a universal effect for all existing materials, but it still lacks a quantitative materials database to systematically understand its scientific mechanisms. Using an established measurement method, this study quantifies the triboelectric charge densities of nearly 30 inorganic nonmetallic materials. From the matrix of their triboelectric charge densities and band structures, it is found that the triboelectric output is strongly related to the work functions of the materials. Our study verifies that contact-electrification is an electronic quantum transition effect under ambient conditions. The basic driving force for contact-electrification is that electrons seek to fill the lowest available states once two materials are forced to reach atomically close distance so that electron transitions are possible through strongly overlapping electron wave functions. We hope that the quantified series could serve as a textbook standard and a fundamental database for scientific research, practical manufacturing, and engineering. The mechanism of contact electrification remains a topic of debate. Here, the authors present a quantitative database of the triboelectric charge density and band structure of many inorganic materials, verifying that contact electrification between solids is an electron quantum transition effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 626, "Times Cited, All Databases": 647, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2093, "DOI": "10.1038/s41467-020-15926-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15926-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531855500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, HR; Wang, ZB; Yuan, T; Yuan, FL; Li, XH; Li, YC; Tan, ZA; Fan, LZ; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Haoran; Wang, Zhibin; Yuan, Ting; Yuan, Fanglong; Li, Xiaohong; Li, Yunchao; Tan, Zhan'ao; Fan, Louzhen; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electroluminescent Warm White Light-Emitting Diodes Based on Passivation Enabled Bright Red Bandgap Emission Carbon Quantum Dots", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient red bandgap emission carbon quantum dots (CQDs) for realizing high-performance electroluminescent warm white light-emitting diodes (warm-WLEDs) represents a grand challenge. Here, the synthesis of three red-emissive electron-donating group passivated CQDs (R-EGP-CQDs): R-EGP-CQDs-NMe2, -NEt2, and -NPr2 is reported. The R-EGP-CQDs, well soluble in common organic solvents, display bright red bandgap emission at 637, 642, and 645 nm, respectively, reaching the highest photoluminescence quantum yield (QY) up to 86.0% in ethanol. Theoretical investigations reveal that the red bandgap emission originates from the rigid pi-conjugated skeleton structure, and the -NMe2, -NEt2, and -NPr2 passivation plays a key role in inducing charge transfer excited state in the pi-conjugated structure to afford the high QY. Solution-processed electroluminescent warm-WLEDs based on the R-EGP-CQDs-NMe2, -NEt2, and -NPr2 display voltage-stable warm white spectra with a maximum luminullce of 5248-5909 cd m(-2) and a current efficiency of 3.65-3.85 cd A(-1). The warm-WLEDs also show good long-term operational stability (L/L-0 > 80% after 50 h operation, L-0: 1000 cd m(-2)). The electron-donating group passivation strategy opens a new avenue to realizing efficient red bandgap emission CQDs and developing high-performance electroluminescent warm-WLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2019, "Volume": 6, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900397, "DOI": "10.1002/advs.201900397", "DOI Link": "http://dx.doi.org/10.1002/advs.201900397", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477710600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YC; Tan, YR; Lao, JZ; Gao, HJ; Yu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yingchao; Tan, Yurong; Lao, Jiazheng; Gao, Huajian; Yu, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogels for Flexible Electronics", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogelshave emerged as promising materials for flexible electronicsdue to their unique properties, such as high water content, softness,and biocompatibility. In this perspective, we provide an overviewof the development of hydrogels for flexible electronics, with a focuson three key aspects: mechanical properties, interfacial adhesion,and conductivity. We discuss the principles of designing high-performancehydrogels and present representative examples of their potential applicationsin the field of flexible electronics for healthcare. Despite significantprogress, several challenges remain, including improving the antifatiguecapability, enhancing interfacial adhesion, and balancing water contentin wet environments. Additionally, we highlight the importance ofconsidering the hydrogel-cell interactions and the dynamicproperties of hydrogels in future research. Looking ahead, the futureof hydrogels in flexible electronics is promising, with exciting opportunitieson the horizon, but continued investment in research and developmentis necessary to overcome the remaining challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2023, "Volume": 17, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9681, "End Page": 9693, "Article Number": null, "DOI": "10.1021/acsnullo.3c02897", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.3c02897", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001014029600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, ZL; Zhang, XY; Hu, YX; Chen, ZW; Lin, SQ; Li, W; Xiao, C; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Zhonglin; Zhang, Xinyue; Hu, Yixin; Chen, Zhiwei; Lin, Siqi; Li, Wen; Xiao, Chong; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A record thermoelectric efficiency in tellurium-free modules for low-grade waste heat recovery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-grade heat accounts for >50% of the total dissipated heat sources in industries. An efficient recovery of low-grade heat into useful electricity not only reduces the consumption of fossil-fuels but also releases the subsequential environmental-crisis. Thermoelectricity offers an ideal solution, yet low-temperature efficient materials have continuously been limited to Bi2Te3-alloys since the discovery in 1950s. Scarcity of tellurium and the strong property anisotropy cause high-cost in both raw-materials and synthesis/processing. Here we demonstrate cheap polycrystalline antimonides for even more efficient thermoelectric waste-heat recovery within 600 K than conventional tellurides. This is enabled by a design of Ni/Fe/Mg3SbBi and Ni/Sb/CdSb contacts for both a prevention of chemical diffusion and a low interfacial resistivity, realizing a record and stable module efficiency at a temperature difference of 270 K. In addition, the raw-material cost to the output power ratio in this work is reduced to be only 1/15 of that of conventional Bi2Te3-modules. Thermoelectric materials for low-grade heat recovery applications are limited to Bi2Te3-based alloys containing expensive Te for decades. Here, the authors demonstrate on a module level, cheap antimonides could enable an efficiency not inferior to that of expensive tellurides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 237, "DOI": "10.1038/s41467-021-27916-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27916-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741852200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, SQ; Zhu, JY; Uliana, AA; Li, DY; Zhang, YT; Zhang, L; Wang, Y; He, T; Elimelech, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Shuangqiao; Zhu, Junyong; Uliana, Adam A.; Li, Dongyang; Zhang, Yatao; Zhang, Lin; Wang, Yong; He, Tao; Elimelech, Menachem", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microporous organic nullotube assisted design of high performance nullofiltration membranes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microporous organic nullotubes (MONs) hold considerable promise for designing molecular-sieving membranes because of high microporosity, customizable chemical functionalities, and favorable polymer affinity. Here, the authors report the usage of MONs derived from covalent organic frameworks to engineer 15-nm-thick microporous membranes via interfacial polymerization. Microporous organic nullotubes (MONs) hold considerable promise for designing molecular-sieving membranes because of their high microporosity, customizable chemical functionalities, and favorable polymer affinity. Herein, we report the use of MONs derived from covalent organic frameworks to engineer 15-nm-thick microporous membranes via interfacial polymerization (IP). The incorporation of a highly porous and interpenetrated MON layer on the membrane before the IP reaction leads to the formation of polyamide membranes with Turing structure, enhanced microporosity, and reduced thickness. The MON-modified membranes achieve a remarkable water permeability of 41.7 L m(-2) h(-1) bar(-1) and high retention of boron (78.0%) and phosphorus (96.8%) at alkaline conditions (pH 10), surpassing those of reported nullofiltration membranes. Molecular simulations reveal that introducing the MONs not only reduces the amine molecule diffusion toward the organic phase boundary but also increases membrane porosity and the density of water molecules around the membrane pores. This MON-regulated IP strategy provides guidelines for creating high-permeability membranes for precise nullofiltration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7954, "DOI": "10.1038/s41467-022-35681-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35681-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935585400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, L; Babucci, M; Zhang, YF; Lund, A; Liu, LM; Li, JW; Chen, YZ; Hoffman, AS; Bare, SR; Han, Y; Gates, BC; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Liang; Babucci, Melike; Zhang, Yanfei; Lund, Alicia; Liu, Lingmei; Li, Jingwei; Chen, Yizhen; Hoffman, Adam S.; Bare, Simon R.; Han, Yu; Gates, Bruce C.; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Propane Dehydrogenation Catalyzed by Isolated Pt Atoms in SiOZn-OH Nests in Dealuminated Zeolite Beta", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed noble metal catalysts have drawn wide attention as candidates to replace supported metal clusters and metal nulloparticles. Atomic dispersion can offer unique chemical properties as well as maximum utilization of the expensive metals. Addition of a second metal has been found to help reduce the size of Pt ensembles in bimetallic clusters; however, the stabilization of isolated Pt atoms in small nests of nonprecious metal atoms remains challenging. We now report a novel strategy for the design, synthesis, and characterization of a zeolite-supported propane dehydrogenation catalyst that incorporates predominulltly isolated Pt atoms stably bonded within nests of Zn atoms located within the nulloscale pores of dealuminated zeolite Beta. The catalyst is stable in long-term operation and exhibits high activity and high selectivity to propene. Atomic resolution images, bolstered by X-ray absorption spectra, demonstrate predominulltly atomic dispersion of the Pt in the nests and, with complementary infrared and nuclear magnetic resonullce spectra, determine a structural model of the nested Pt.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2021, "Volume": 143, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21364, "End Page": 21378, "Article Number": null, "DOI": "10.1021/jacs.1c10261", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c10261", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731063700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, BY; Cao, JW; Mukherjee, S; Pham, T; Zhang, T; Wang, T; Jiang, X; Forrest, KA; Zaworotko, MJ; Chen, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Baoyong; Cao, Jian-Wei; Mukherjee, Soumya; Pham, Tony; Zhang, Tao; Wang, Teng; Jiang, Xue; Forrest, Katherine A.; Zaworotko, Michael J.; Chen, Kai-Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore Engineering for One-Step Ethylene Purification from a Three-Component Hydrocarbon Mixture", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ethylene production from C2 hydrocarbon mixtures through one separation step is desirable but challenging because of the similar size and physical properties of acetylene, ethylene, and ethane. Herein, we report three new isostructural porous coordination networks (NPU-1, NPU-2, NPU-3; NPU represents Northwestern Polytechnical University) that are sustained by 9-connected nodes based upon a hexanuclear metal cluster of composition [Mn-6(mu(3)-O)(2) (CH3COO)(3)](6+). NPU-1/ 2 / 3 exhibit a dual cage structure that was systematically fine-tuned in terms of cage size to realize selective adsorption of C2H2 and C2H6 over C2H4 . Dynamic breakthrough experiments demonstrated that NPU-1 produces ethylene in >99.9% purity from a three-component gas mixture (1:1:1 C2H2/C2H4/C2H6). Molecular modeling studies revealed that the dual adsorption preference for C2H2 and C2H6 over C2H4 originates from (a) strong hydrogen-bonding interactions between electronegative carboxylate O atoms and C2H2 molecules in one cage and (b) multiple non-covalent interactions between the organic linkers of the host network and C2H6 molecules in the second cage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2021, "Volume": 143, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1485, "End Page": 1492, "Article Number": null, "DOI": "10.1021/jacs.0c11247", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c11247", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614064400029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, J; Fan, ZY; Nakabayashi, M; Ju, HX; Pastukhova, N; Xiao, YQ; Feng, C; Shibata, N; Domen, K; Li, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Jie; Fan, Zeyu; Nakabayashi, Mamiko; Ju, Huanxin; Pastukhova, Nadiia; Xiao, Yequan; Feng, Chao; Shibata, Naoya; Domen, Kazunari; Li, Yanbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface engineering of Ta3N5 thin film photoanode for highly efficient photoelectrochemical water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interface engineering is a proven strategy to improve the efficiency of thin film semiconductor based solar energy conversion devices. Ta3N5 thin film photoanode is a promising candidate for photoelectrochemical (PEC) water splitting. Yet, a concerted effort to engineer both the bottom and top interfaces of Ta3N5 thin film photoanode is still lacking. Here, we employ n-type In:GaN and p-type Mg:GaN to modify the bottom and top interfaces of Ta3N5 thin film photoanode, respectively. The obtained In:GaN/Ta3N5/Mg:GaN heterojunction photoanode shows enhanced bulk carrier separation capability and better injection efficiency at photoanode/electrolyte interface, which lead to a record-high applied bias photon-to-current efficiency of 3.46% for Ta3N5-based photoanode. Furthermore, the roles of the In:GaN and Mg:GaN layers are distinguished through mechanistic studies. While the In:GaN layer contributes mainly to the enhanced bulk charge separation efficiency, the Mg:GaN layer improves the surface charge inject efficiency. This work demonstrates the crucial role of proper interface engineering for thin film-based photoanode in achieving efficient PEC water splitting. Solar-to-fuel energy conversion requires well-designed materials properties to ensure favorable charge carrier movement. Here, authors employ interface engineering of Ta3N5 thin film to enhance bulk carrier separation and interface carrier injection to improve the water-splitting efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 729, "DOI": "10.1038/s41467-022-28415-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28415-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752524300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eum, D; Kim, B; Song, JH; Park, H; Jang, HY; Kim, SJ; Cho, SP; Lee, MH; Heo, JH; Park, J; Ko, Y; Park, SK; Kim, J; Oh, K; Kim, DH; Kang, SJ; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eum, Donggun; Kim, Byunghoon; Song, Jun-Hyuk; Park, Hyeokjun; Jang, Ho-Young; Kim, Sung Joo; Cho, Sung-Pyo; Lee, Myeong Hwan; Heo, Jae Hoon; Park, Jaehyun; Ko, Youngmin; Park, Sung Kwan; Kim, Jinsoo; Oh, Kyungbae; Kim, Do-Hoon; Kang, Seok Ju; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling structural evolution and oxygen-redox electrochemistry in layered transition metal oxides", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice oxygen redox offers an unexplored way to access superior electrochemical properties of transition metal oxides (TMOs) for rechargeable batteries. However, the reaction is often accompanied by unfavourable structural transformations and persistent electrochemical degradation, thereby precluding the practical application of this strategy. Here we explore the close interplay between the local structural change and oxygen electrochemistry during short- and long-term battery operation for layered TMOs. The substantially distinct evolution of the oxygen-redox activity and reversibility are demonstrated to stem from the different cation-migration mechanisms during the dynamic de/intercalation process. We show that the pi stabilization on the oxygen oxidation initially aids in the reversibility of the oxygen redox and is predominullt in the absence of cation migrations; however, the pi-interacting oxygen is gradually replaced by sigma-interacting oxygen that triggers the formation of O-O dimers and structural destabilization as cycling progresses. More importantly, it is revealed that the distinct cation-migration paths available in the layered TMOs govern the conversion kinetics from pi to sigma interactions. These findings constitute a step forward in unravelling the correlation between the local structural evolution and the reversibility of oxygen electrochemistry and provide guidance for further development of oxygen-redox layered electrode materials. Transition metal oxide electrodes are promising for rechargeable batteries but are subject to suffer from structural transformations and electrochemical degradation. The evolution of oxygen-redox activity and reversibility in layered electrodes are shown to arise from cation-migration mechanisms during de/intercalation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 21, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 664, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01209-1", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01209-1", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000770195000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jindal, A; Saha, A; Li, ZZ; Taniguchi, T; Watanabe, K; Hone, JC; Birol, T; Fernulldes, RM; Dean, CR; Pasupathy, AN; Rhodes, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jindal, Apoorv; Saha, Amartyajyoti; Li, Zizhong; Taniguchi, Takashi; Watanabe, Kenji; Hone, James C. C.; Birol, Turan; Fernulldes, Rafael M. M.; Dean, Cory R. R.; Pasupathy, Abhay N. N.; Rhodes, Daniel A. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupled ferroelectricity and superconductivity in bilayer Td-MoTe2", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving electrostatic control of quantum phases is at the frontier of condensed matter research. Recent investigations have revealed superconductivity tunable by electrostatic doping in twisted graphene heterostructures and in two-dimensional semimetals such as WTe2 (refs.(1-5)). Some of these systems have a polar crystal structure that gives rise to ferroelectricity, in which the interlayer polarization exhibits bistability driven by external electric fields(6-8). Here we show that bilayer T-d-MoTe2 simultaneously exhibits ferroelectric switching and superconductivity. Notably, a field-driven, first-order superconductor-to-normal transition is observed at its ferroelectric transition. Bilayer T-d-MoTe2 also has a maximum in its superconducting transition temperature (T-c) as a function of carrier density and temperature, allowing independent control of the superconducting state as a function of both doping and polarization. We find that the maximum T-c is concomitant with compensated electron and hole carrier densities and vanishes when one of the Fermi pockets disappears with doping. We argue that this unusual polarization-sensitive two-dimensional superconductor is driven by an interband pairing interaction associated with nearly nested electron and hole Fermi pockets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 613, "Issue": 7942, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 48, "End Page": 52, "Article Number": null, "DOI": "10.1038/s41586-022-05521-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05521-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909636500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhatia, B; Leroy, A; Shen, YC; Zhao, L; Gianello, M; Li, DH; Gu, T; Hu, JJ; Soljacic, M; Wang, EN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhatia, Bikram; Leroy, Arny; Shen, Yichen; Zhao, Lin; Gianello, Melissa; Li, Duanhui; Gu, Tian; Hu, Juejun; Soljacic, Marin; Wang, Evelyn N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Passive directional sub-ambient daytime radiative cooling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Demonstrations of passive daytime radiative cooling have primarily relied on complex and costly spectrally selective nullophotonic structures with high emissivity in the transparent atmospheric spectral window and high reflectivity in the solar spectrum. Here, we show a directional approach to passive radiative cooling that exploits the angular confinement of solar irradiation in the sky to achieve sub-ambient cooling during the day regardless of the emitter properties in the solar spectrum. We experimentally demonstrate this approach using a setup comprising a polished aluminum disk that reflects direct solar irradiation and a white infrared-transparent polyethylene convection cover that minimizes diffuse solar irradiation. Measurements performed around solar noon show a minimum temperature of 6 degrees C below ambient temperature and maximum cooling power of 45 Wm(-2). Our passive cooling approach, realized using commonly available low-cost materials, could improve the performance of existing cooling systems and enable next-generation thermal management and refrigeration solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5001, "DOI": "10.1038/s41467-018-07293-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07293-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451310400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JW; Zeng, HL; Dong, X; Ding, YM; Hu, SP; Zhang, RH; Dai, YZ; Cui, PX; Xiao, Z; Zhao, DH; Zhou, LJ; Zheng, TT; Xiao, JP; Zeng, J; Xia, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiawei; Zeng, Hongliang; Dong, Xue; Ding, Yimin; Hu, Sunpei; Zhang, Runhao; Dai, Yizhou; Cui, Peixin; Xiao, Zhou; Zhao, Donghao; Zhou, Liujiang; Zheng, Tingting; Xiao, Jianping; Zeng, Jie; Xia, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective CO2 electrolysis to CO using isolated antimony alloyed copper", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Renewable electricity-powered CO evolution from CO2 emissions is a promising first step in the sustainable production of commodity chemicals, but performing electrochemical CO2 reduction economically at scale is challenging since only noble metals, for example, gold and silver, have shown high performance for CO2-to-CO. Cu is a potential catalyst to achieve CO2 reduction to CO at the industrial scale, but the C-C coupling process on Cu significantly depletes CO* intermediates, thus limiting the CO evolution rate and producing many hydrocarbon and oxygenate mixtures. Herein, we tune the CO selectivity of Cu by alloying a second metal Sb into Cu, and report an antimony-copper single-atom alloy catalyst (Sb1Cu) of isolated Sb-Cu interfaces that catalyzes the efficient conversion of CO2-to-CO with a Faradaic efficiency over 95%. The partial current density reaches 452 mA cm(-2) with approximately 91% CO Faradaic efficiency, and negligible C2+ products are observed. In situ spectroscopic measurements and theoretical simulations reason that the atomic Sb-Cu interface in Cu promotes CO2 adsorption/activation and weakens the binding strength of CO*, which ends up with enhanced CO selectivity and production rates. Engineering Cu to achieve high catalytic selectivity towards carbon monoxide at high current density is challenging. Here, the authors report an Cu-Sb single-atom alloy catalyst that catalyzes CO2 reduction at a current density of 500 mA cm(-2) with CO FE of ca. 91%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 340, "DOI": "10.1038/s41467-023-35960-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35960-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002375100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karpatne, A; Atluri, G; Faghmous, JH; Steinbach, M; Banerjee, A; Ganguly, A; Shekhar, S; Samatova, N; Kumar, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karpatne, Anuj; Atluri, Gowtham; Faghmous, James H.; Steinbach, Michael; Banerjee, Arindam; Ganguly, Auroop; Shekhar, Shashi; Samatova, Nagiza; Kumar, Vipin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory-Guided Data Science: A New Paradigm for Scientific Discovery from Data", "Source Title": "IEEE TRANSACTIONS ON KNOWLEDGE AND DATA ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Data science models, although successful in a number of commercial domains, have had limited applicability in scientific problems involving complex physical phenomena. Theory-guided data science (TGDS) is an emerging paradigm that aims to leverage the wealth of scientific knowledge for improving the effectiveness of data science models in enabling scientific discovery. The overarching vision of TGDS is to introduce scientific consistency as an essential component for learning generalizable models. Further, by producing scientifically interpretable models, TGDS aims to advance our scientific understanding by discovering novel domain insights. Indeed, the paradigm of TGDS has started to gain prominence in a number of scientific disciplines such as turbulence modeling, material discovery, quantum chemistry, bio-medical science, bio-marker discovery, climate science, and hydrology. In this paper, we formally conceptualize the paradigm of TGDS and present a taxonomy of research themes in TGDS. We describe several approaches for integrating domain knowledge in different research themes using illustrative examples from different disciplines. We also highlight some of the promising avenues of novel research for realizing the full potential of theory-guided data science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 795, "Times Cited, All Databases": 896, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2017, "Volume": 29, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2318, "End Page": 2331, "Article Number": null, "DOI": "10.1109/TKDE.2017.2720168", "DOI Link": "http://dx.doi.org/10.1109/TKDE.2017.2720168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000410643300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leber, A; Dong, CQ; Chandran, R; Das Gupta, T; Bartolomei, N; Sorin, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leber, Andreas; Dong, Chaoqun; Chandran, Rajasundar; Das Gupta, Tapajyoti; Bartolomei, Nicola; Sorin, Fabien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft and stretchable liquid metal transmission lines as distributed probes of multimodal deformations", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanical sensing is a key functionality in soft electronics intended for applications in health monitoring, human-machine interactions and soft robotics. Current methods typically use intricate networks of sensors specific to one type of deformation and one point in space, which limits their sensing capabilities. An alternative approach to distributed sensing is electrical reflectometry, but it is challenging to build the necessary transmission lines out of soft materials. Here, we report the scalable fabrication of microstructured elastomeric fibres that integrate tens of liquid metal conductors and have the length and cross-sectional integrity necessary to successfully apply time-domain reflectometry. Our soft transmission lines allow the detection of the mode, magnitude and position of multiple simultaneous pressing and stretching events. Furthermore, as a result of the dynamically responsive conductors, the pressure sensitivity is improved by a factor of 200 compared to rigid line probes. By integrating a single soft transmission line with a single interface port into a larger fabric, our technique can be used to create an electronic textile that can decipher convoluted mechanical stimulation. A microstructured liquid metal fibre can be used as a soft transmission line probe for reflectometry, allowing electronic textiles to be created that can decipher convoluted mechanical stimulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 316, "End Page": 326, "Article Number": null, "DOI": "10.1038/s41928-020-0415-y", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-0415-y", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537036000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, IS; Yang, ML; Shibata, H; Amanokura, N; Yasuda, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, In Seob; Yang, Minlang; Shibata, Hiromoto; Amanokura, Natsuki; Yasuda, Takuma", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Ultimate Narrowband and Ultrapure Blue Organic Light-Emitting Diodes Based on Polycyclo-Heteraborin Multi-Resonullce Delayed-Fluorescence Emitters", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve an ultimate wide color gamut for ultrahigh-definition displays, there is great demand for the development of organic light-emitting diodes (OLEDs) enabling monochromatic, ultrapure blue electroluminescence (EL). Herein, high-efficiency and ultrapure blue OLEDs based on polycyclo-heteraborin multi-resonullce thermally activated delayed fluorescence (MR-TADF) materials, BOBO-Z, BOBS-Z, and BSBS-Z, are reported. The key to the design of the present luminophores is the exquisite combination and interplay of multiple boron, nitrogen, oxygen, and sulfur heteroatoms embedded in a fused polycyclic pi-system. Comprehensive photophysical and computational investigations of this family of MR-TADF materials reveal that the systematic implementation of chalcogen (oxygen and sulfur) atoms can finely modulate the emission color while maintaining a narrow bandwidth, as well as the spin-flipping rates between the excited singlet and triplet states. Consequently, OLEDs based on BOBO-Z, BOBS-Z, and BSBS-Z demonstrate narrowband and ultrapure blue EL emission, with peaks at 445-463 nm and full width at half maxima of 18-23 nm, leading to Commission Internationale de l'eclairage-y coordinates in the range of 0.04-0.08. Particularly, for OLEDs incorporating sulfur-doped BOBS-Z and BSBS-Z, notably high maximum external EL quantum efficiencies of 26.9% and 26.8%, respectively, and small efficiency roll-offs are achieved concurrently.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 34, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2107951, "DOI": "10.1002/adma.202107951", "DOI Link": "http://dx.doi.org/10.1002/adma.202107951", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744631600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YC; Xu, Z; Yang, Z; Zhang, YX; Cui, J; He, YH; Ye, HC; Zhao, K; Su, HM; Lu, R; Liu, M; Kanatzidis, MG; Liu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yucheng; Xu, Zhuo; Yang, Zhou; Zhang, Yunxia; Cui, Jian; He, Yihui; Ye, Haochen; Zhao, Kui; Su, Huaming; Lu, Rui; Liu, Ming; Kanatzidis, Mercouri G.; (Frank) Liu, Shengzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inch-Size 0D-Structured Lead-Free Perovskite Single Crystals for Highly Sensitive Stable X-Ray Imaging", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ion migration in perovskite materials accelerates its decomposition-deteriorating device performance, causing baseline drift, and lowering imaging resolution. In particular, in X-ray detectors, the effect of ion migration is more obvious under the necessary high working bias. Here, we report an effective strategy to grow superior inch-sized, high-quality, zero-dimensional (0D)-structured, lead-free (CH3NH3)(3)Bi2I9 perovskite single crystals. These crystals have significantly lower ion migration, reduced dark current, and better environmental stability compared with other perovskites, enabling us to fabricate a type of 0D-structured perovskite X-ray detector. The X-ray detector shows high sensitivity of 1,947 mu C Gy(air)(-1) cm(-2), low detection limit of 83 nGy(air) s(-1), short response time of 23.3 ms, the lowest baseline drift of 5.0 x 10(-10) nA cm(-1) s(-1) V-1, and the best long-term stability among all perovskites reported. The combination of large crystal size and excellent X-ray response allows us to fabricate the first 0D-structured perovskite X-ray imaging system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2020, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 180, "End Page": 196, "Article Number": null, "DOI": "10.1016/j.matt.2020.04.017", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2020.04.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548739400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, CF; Yu, B; Chen, ZY; Qu, YX; Li, YT; Shi, YQ; Ma, ZW; Sun, FN; Pan, QH; Tang, LC; Song, PA; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Cheng-Fei; Yu, Bin; Chen, Zuan-Yu; Qu, Yong-Xiang; Li, Yu-Tong; Shi, Yong-Qian; Ma, Zhe-Wen; Sun, Feng-Na; Pan, Qing-Hua; Tang, Long-Cheng; Song, Pingan; Wang, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fire Intumescent, High-Temperature Resistant, Mechanically Flexible Graphene Oxide Network for Exceptional Fire Shielding and Ultra-Fast Fire Warning", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Smart fire alarm sensor (FAS) materials with mechanically robust, excellent flame retardancy as well as ultra-sensitive temperature-responsive capability are highly attractive platforms for fire safety application. However, most reported FAS materials can hardly provide sensitive, continuous and reliable alarm signal output due to their undesirable temperature-responsive, flame-resistant and mechanical performances. To overcome these hurdles, herein, we utilize the multi-amino molecule, named HCPA, that can serve as triple-roles including cross-linker, fire retardant and reducing agent for decorating graphene oxide (GO) sheets and obtaining the GO/HCPA hybrid networks. Benefiting from the formation of multi-interactions in hybrid network, the optimized GO/HCPA network exhibits significant increment in mechanical strength, e.g., tensile strength and toughness increase of similar to 2.3 and similar to 5.7 times, respectively, compared to the control one. More importantly, based on P and N doping and promoting thermal reduction effect on GO network, the excellent flame retardancy (withstanding similar to 1200 degrees C flame attack), ultra-fast fire alarm response time (similar to 0.6 s) and ultra-long alarming period (> 600 s) are obtained, representing the best comprehensive performance of GO-based FAS counterparts. Furthermore, based on GO/HCPA network, the fireproof coating is constructed and applied in polymer foam and exhibited exceptional fire shielding performance. This work provides a new idea for designing and fabricating desirable FAS materials and fireproof coatings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 92, "DOI": "10.1007/s40820-022-00837-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00837-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778996400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bo, Z; Shuai, XR; Mao, S; Yang, HC; Qian, JJ; Chen, JH; Yan, JH; Cen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bo, Zheng; Shuai, Xiaorui; Mao, Shun; Yang, Huachao; Qian, Jiajing; Chen, Junhong; Yan, Jianhua; Cen, Kefa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green preparation of reduced graphene oxide for sensing and energy storage applications", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Preparation of graphene from chemical reduction of graphene oxide ( GO) is recognized as one of the most promising methods for large-scale and low-cost production of graphene-based materials. This study reports a new, green, and efficient reducing agent ( caffeic acid/CA) for GO reduction. The CA-reduced GO (CA-rGO) shows a high C/O ratio (7.15) that is among the best rGOs prepared with green reducing reagents. Electronic gas sensors and supercapacitors have been fabricated with the CA- rGO and show good performance, which demonstrates the potential of CA- rGO for sensing and energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/srep04684", "DOI Link": "http://dx.doi.org/10.1038/srep04684", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334285700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, P; Luo, YZ; Zhang, GX; Chen, ZS; Ranganathan, H; Sun, SH; Shi, ZC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pan; Luo, Yuanzhi; Zhang, Gaixia; Chen, Zhangsen; Ranganathan, Hariprasad; Sun, Shuhui; Shi, Zhicong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of NixSx@MnOxHy nullorods to Efficiently Enhance Overall-Water-Splitting Activity and Stability", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring highly active and stable transition metal-based bifunctional electrocatalysts has recently attracted extensive research interests for achieving high inherent activity, abundant exposed active sites, rapid mass transfer, and strong structure stability for overall water splitting. Herein, an interface engineering coupled with shell-protection strategy was applied to construct three-dimensional (3D) core-shell NixSy@MnOxHy heterostructure nullorods grown on nickel foam (NixSy@MnOxHy/NF) as a bifunctional electrocatalyst. NixSy@MnOxHy/NF was synthesized via a facile hydrothermal reaction followed by an electrodeposition process. The X-ray absorption fine structure spectra reveal that abundant Mn-S bonds connect the heterostructure interfaces of NixSy@MnOxHy, leading to a strong electronic interaction, which improves the intrinsic activities of hydrogen evolution reaction and oxygen evolution reaction (OER). Besides, as an efficient protective shell, the MnOxHy dramatically inhibits the electrochemical corrosion of the electrocatalyst at high current densities, which remarkably enhances the stability at high potentials. Furthermore, the 3D nullorod structure not only exposes enriched active sites, but also accelerates the electrolyte diffusion and bubble desorption. Therefore, NixSy@MnOxHy/NF exhibits exceptional bifunctional activity and stability for overall water splitting, with low overpotentials of 326 and 356 mV for OER at 100 and 500 mA cm(-2), respectively, along with high stability of 150 h at 100 mA cm(-2). Furthermore, for overall water splitting, it presents a low cell voltage of 1.529 V at 10 mA cm(-2), accompanied by excellent stability at 100 mA cm(-2) for 100 h. This work sheds a light on exploring highly active and stable bifunctional electrocatalysts by the interface engineering coupled with shell-protection strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120, "DOI": "10.1007/s40820-022-00860-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00860-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790259600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, HD; Huang, JJ; Tian, SH; Liu, L; Qin, TF; Song, L; Liu, YP; Zhang, YA; Wu, XG; Lei, SL; Peng, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hangda; Huang, Juanjuan; Tian, Shuhao; Liu, Li; Qin, Tianfeng; Song, Lei; Liu, Yanpeng; Zhang, Yanull; Wu, Xiaogang; Lei, Shulai; Peng, Shanglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interlayer Modification of Pseudocapacitive Vanadium Oxide and Zn(H2O)n2+ Migration Regulation for Ultrahigh Rate and Durable Aqueous Zinc-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interlayer modification and the intercalation pseudocapacitance have been combined in vanadium oxide electrode for aqueous zinc-ion batteries. Intercalation pseudocapacitive hydrated vanadium oxide Mn1.4V10O24 center dot 12H(2)O with defective crystal structure, interlayer water, and large interlayer distance has been prepared by a spontaneous chemical synthesis method. The inserted Mn2+ forms coordination bonds with the oxygen of the host material and strengthens the interaction between the layers, preventing damage to the structure. Combined with the experimental data and DFT calculation, it is found that Mn2+ refines the structure stability, adjusts the electronic structure, and improves the conductivity of hydrated vanadium oxide. Also, Mn2+ changes the migration path of Zn2+, reduces the migration barrier, and improves the rate performance. Therefore, Mn2+-inserted hydrated vanadium oxide electrode delivers a high specific capacity of 456 mAh g(-1) at 0.2 A g(-1), 173 mAh g(-1) at 40 A g(-1), and a capacity retention of 80% over 5000 cycles at 10 A g(-1). Furthermore, based on the calculated zinc ion mobility coefficient and Zn(H2O)(n)(2+) diffusion energy barrier, the possible migration behavior of Zn(H2O)(n)(2+) in vanadium oxide electrode has also been speculated, which will provide a new reference for understanding the migration behavior of hydrated zinc-ion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004924, "DOI": "10.1002/advs.202004924", "DOI Link": "http://dx.doi.org/10.1002/advs.202004924", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653222800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moitra, P; Slovick, BA; Li, W; Kraychencko, II; Briggs, DP; Krishnamurthy, S; Valentine, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moitra, Parikshit; Slovick, Brian A.; Li, Wei; Kraychencko, Ivan I.; Briggs, Dayrl P.; Krishnamurthy, S.; Valentine, Jason", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Scale All-Dielectric Metamaterial Perfect Reflectors", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-dielectric metamaterials offer a potential low-loss alternative to plasmonic metamaterials at optical frequencies. Here, we take advantage of the low absorption loss as well as the simple unit cell geometry to demonstrate large-scale (centimeter-sized) all-dielectric metamaterial perfect reflectors made from silicon cylinder resonators. These perfect reflectors, operating in the telecommunications band, were fabricated using self-assembly based nullosphere lithography. In spite of the disorder originating from the self-assembly process, the average reflectance of the metamaterial perfect reflectors is 99.7% at 1530 nm, surpassing the Moreover, the spectral separation of the electric and magnetic resonullces can be chosen to bandwidth while maintaining a high tolerance to disorder. The scalability of this design manipulating light for low-loss and large-area photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 692, "End Page": 698, "Article Number": null, "DOI": "10.1021/acsphotonics.5b00148", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.5b00148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356757900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, JJ; Musgrave, CB; Song, Y; Huang, LB; Liu, Y; Li, G; Xin, YE; Xiong, P; Li, MMJ; Wu, HR; Zhu, MH; Chen, HM; Zhang, JY; Shen, HC; Tang, BZ; Robert, M; Goddard, W ; Ye, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Jianjun; Musgrave, Charles B.; Song, Yun; Huang, Libei; Liu, Yong; Li, Geng; Xin, Yinger; Xiong, Pei; Li, Molly Meng-Jung; Wu, Haoran; Zhu, Minghui; Chen, Hao Ming; Zhang, Jianyu; Shen, Hanchen; Tang, Ben Zhong; Robert, Marc; Goddard, William A., III; Ye, Ruquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain enhances the activity of molecular electrocatalysts via carbon nullotube supports", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Support-induced strain engineering is useful for modulating the properties of two-dimensional materials. However, controlling strain of planar molecules is technically challenging due to their sub-2 nm lateral size. Additionally, the effect of strain on molecular properties remains poorly understood. Here we show that carbon nullotubes (CNTs) are ideal substrates for inducing optimum properties through molecular curvature. In a tandem-flow electrolyser with monodispersed cobalt phthalocyanine (CoPc) on single-walled CNTs (CoPc/SWCNTs) for CO2 reduction, we achieve a methanol partial current density of >90 mA cm(-2) with >60% selectivity, surpassing wide multiwalled CNTs at 16.6%. We report vibronic and X-ray spectroscopies to unravel the distinct local geometries and electronic structures induced by the strong molecule-support interactions. Grand canonical density functional theory confirms that curved CoPc/SWCNTs improve *CO binding to enable subsequent reduction, whereas wide multiwalled CNTs favour CO desorption. Our results show the important role of SWCNTs beyond catalyst dispersion and electron conduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 818, "End Page": 828, "Article Number": null, "DOI": "10.1038/s41929-023-01005-3", "DOI Link": "http://dx.doi.org/10.1038/s41929-023-01005-3", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001048827200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Robin, P; Emmerich, T; Ismail, A; Niguès, A; You, Y; Nam, GH; Keerthi, A; Siria, A; Geim, AK; Radha, B; Bocquet, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Robin, P.; Emmerich, T.; Ismail, A.; Nigues, A.; You, Y.; Nam, G. -H.; Keerthi, A.; Siria, A.; Geim, A. K.; Radha, B.; Bocquet, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-term memory and synapse-like dynamics in two-dimensional nullofluidic channels", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fine-tuned ion transport across nulloscale pores is key to many biological processes, including neurotransmission. Recent advances have enabled the confinement of water and ions to two dimensions, unveiling transport properties inaccessible at larger scales and triggering hopes of reproducing the ionic machinery of biological systems. Here we report experiments demonstrating the emergence of memory in the transport of aqueous electrolytes across (sub)nulloscale channels. We unveil two types of nullofluidic memristors depending on channel material and confinement, with memory ranging from minutes to hours. We explain how large time scales could emerge from interfacial processes such as ionic self-assembly or surface adsorption. Such behavior allowed us to implement Hebbian learning with nullofluidic systems. This result lays the foundation for biomimetic computations on aqueous electrolytic chips.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2023, "Volume": 379, "Issue": 6628, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 161, "End Page": 167, "Article Number": null, "DOI": "10.1126/science.adc9931", "DOI Link": "http://dx.doi.org/10.1126/science.adc9931", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000933946800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, D; Wang, PY; Qin, R; Shi, WJ; Gong, L; Zhu, JW; Ma, QL; Chen, L; Yu, J; Liu, SL; Mu, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Dong; Wang, Pengyan; Qin, Rui; Shi, Wenjie; Gong, Lei; Zhu, Jiawei; Ma, Qianli; Chen, Lei; Yu, Jun; Liu, Suli; Mu, Shichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flower-Like Amorphous MoO3-x Stabilized Ru Single Atoms for Efficient Overall Water/Seawater Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Benefitting from the maximum atom utilization efficiency, special size quantum effects and tailored active sites, single-atom catalysts (SACs) have been promising candidates for bifunctional catalysts toward water splitting. Besides, due to the unique structure and properties, some amorphous materials have been found to possess better performance than their crystalline counterparts in electrocatalytic water splitting. Herein, by combining the advantages of ruthenium (Ru) single atoms and amorphous substrates, amorphous molybdenum-based oxide stabilized single-atomic-site Ru (Ru SAs-MoO3-x/NF) catalysts are conceived as a self-supported electrode. By virtue of the large surface area, enhanced intrinsic activity and fast reaction kinetics, the as-prepared Ru SAs-MoO3-x/NF electrode effectively drives both oxygen evolution reaction (209 mV @ 10 mA cm(-2)) and hydrogen evolution reaction (36 mV @ 10 mA cm(-2)) in alkaline media. Impressively, the assembled electrolyzer merely requires an ultralow cell voltage of 1.487 V to deliver the current density of 10 mA cm(-2). Furthermore, such an electrode also exhibits a great application potential in alkaline seawater electrolysis, achieving a current density of 100 mA cm(-2) at a low cell voltage of 1.759 V. In addition, Ru SAs-MoO3-x/NF only has very small current density decay in the long-term constant current water splitting test.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300342", "DOI Link": "http://dx.doi.org/10.1002/advs.202300342", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972748800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TZ; Gou, GY; Gao, FP; Yao, P; Wu, HY; Guo, YS; Yin, MH; Yang, J; Wen, TC; Zhao, M; Li, T; Chen, G; Sun, JH; Ma, TJ; Cheng, JQ; Qi, ZM; Chen, JM; Wang, JB; Han, MD; Fang, Z; Gao, YY; Liu, CX; Xue, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tiezhu; Gou, Guang-yang; Gao, Fupeng; Yao, Pan; Wu, Haoyu; Guo, Yusen; Yin, Minghui; Yang, Jie; Wen, Tiancai; Zhao, Ming; Li, Tong; Chen, Gang; Sun, Jianhai; Ma, Tianjun; Cheng, Jianqun; Qi, Zhimei; Chen, Jiamin; Wang, Junbo; Han, Mengdi; Fang, Zhen; Gao, Yangyang; Liu, Chunxiu; Xue, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multichannel Flexible Pulse Perception Array for Intelligent Disease Diagnosis System", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure sensors with high sensitivity, a wide linear range, and a quick response time are critical for building an intelligent disease diagnosis system that directly detects and recognizes pulse signals for medical and health applications. However, conventional pressure sensors have limited sensitivity and nonideal response ranges. We proposed a multichannel flexible pulse perception array based on polyimide/multiwalled carbon nullotube- polydimethylsiloxane nullocomposite/polyimide (PI/MPN/PI) sandwich-structure pressure sensor that can be applied for remote disease diagnosis. Furthermore, we established a mechanical model at the molecular level and guided the preparation of MPN. At the structural level, we achieved high sensitivity (35.02 kPa-1) and a broad response range (0-18 kPa) based on a pyramid-like bilayer microstructure with different upper and lower surfaces. A 27-channel (3 x 9) high-density sensor array was integrated at the device level, which can extract the spatial and temporal distribution information on a pulse. Furthermore, two intelligent algorithms were developed for extracting six-dimensional pulse information and automatic pulse recognition (the recognition rate reaches 97.8%). The results indicate that intelligent disease diagnosis systems have great potential applications in wearable healthcare devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2023, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5673, "End Page": 5685, "Article Number": null, "DOI": "10.1021/acsnullo.2c11897", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c11897", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926740000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, ZX; Zhou, XR; Smejkal, L; Wu, L; Zhu, ZW; Guo, HX; González-Hernández, R; Wang, XN; Yan, H; Qin, PX; Zhang, X; Wu, HJ; Chen, HY; Meng, Z; Liu, L; Xia, ZC; Sinova, J; Jungwirth, T; Liu, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Zexin; Zhou, Xiaorong; Smejkal, Libor; Wu, Lei; Zhu, Zengwei; Guo, Huixin; Gonzalez-Hernulldez, Rafael; Wang, Xiaoning; Yan, Han; Qin, Peixin; Zhang, Xin; Wu, Haojiang; Chen, Hongyu; Meng, Ziang; Liu, Li; Xia, Zhengcai; Sinova, Jairo; Jungwirth, Tomas; Liu, Zhiqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An anomalous Hall effect in altermagnetic ruthenium dioxide", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The anomalous Hall effect is a time-reversal symmetry-breaking magneto-electronic phenomenon originally discovered in ferromagnets. Recently, ruthenium dioxide (RuO2) with a compensated antiparallel magnetic order has been predicted to generate an anomalous Hall effect of comparable strength to ferromagnets. The phenomenon arises from an altermagnetic phase of RuO2 with a characteristic alternating spin polarization in both real-space crystal structure and momentum-space band structure. Here we report an anomalous Hall effect in RuO2 with an anomalous Hall conductivity exceeding 1,000 omega(-1) cm(-1). We combine the vector magnetometry and magneto-transport measurements of epitaxial RuO2 films of different crystallographic orientations. We show that the anomalous Hall effect dominates over an ordinary Hall contribution, and a contribution due to a weak field-induced magnetization. Our results could lead to the exploration of topological Berry phases and dissipationless quantum transport in crystals of abundant elements and with a compensated antiparallel magnetic order. By combining vector magnetometry and magneto-transport measurements of epitaxial films with different crystallographic orientations, an anomalous Hall effect can be measured in collinear altermagnetic ruthenium dioxide with an anomalous Hall conductivity exceeding 1,000 omega(-1) cm(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 735, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41928-022-00866-z", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00866-z", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000879720400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JP; Liu, CH; Wang, MX; Ge, JF; Liu, ZL; Yang, XJ; Chen, Y; Liu, Y; Xu, ZA; Gao, CL; Qian, D; Zhang, FC; Jia, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jin-Peng; Liu, Canhua; Wang, Mei-Xiao; Ge, Jianfeng; Liu, Zhi-Long; Yang, Xiaojun; Chen, Yan; Liu, Ying; Xu, Zhu-An; Gao, Chun-Lei; Qian, Dong; Zhang, Fu-Chun; Jia, Jin-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Artificial Topological Superconductor by the Proximity Effect", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological superconductors (TSCs), featuring fully gapped bulk and gapless surface states as well as Majorana fermions, have potential applications in fault-tolerant topological quantum computing. Because TSCs are very rare in nature, an alternative way to study the TSC is to artificially introduce superconductivity into the surface states of a topological insulator through the proximity effect [X. L. Qi, T. L. Hughse, S. Raghu, and S. C. Zhang, Phys. Rev. Lett. 102, 187001 (2009); L. Fu and C. L. Kane, Phys. Rev. Lett. 100, 096407 (2008); J. Alicea, Rep. Prog. Phys. 75, 076501 (2012); C. W. J. Beenakker, Annu. Rev. Condens. Matter Phys. 4, 113 (2013)]. Here we report the experimental realization of the proximity effect-induced TSC in Bi2Te3 thin films grown on a NbSe2 substrate, as demonstrated by the density of states probed using scanning tunneling spectroscopy. We observed Abrikosov vortices and Andreev lower energy bound states on the surface of the topological insulator, with the superconducting coherence length depending on the film thickness and the magnetic field. These results also indicate that the topological surface states of Bi2Te3 thin films are superconducting and, thus, that the Bi2Te3/NbSe2 is an artificial TSC. The feasibility of fabricating a TSC with an individual Majorana fermion bound to a superconducting vortex for topological quantum computing is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2014, "Volume": 112, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 217001, "DOI": "10.1103/PhysRevLett.112.217001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.217001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338034400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bohn, BJ; Tong, Y; Gramlich, M; Lai, ML; Döblinger, M; Wang, K; Hoye, RLZ; Müller-Buschbaum, P; Stranks, SD; Urban, AS; Polavarapu, L; Feldmann, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bohn, Bernhard J.; Tong, Yu; Gramlich, Moritz; Lai, May Ling; Doeblinger, Markus; Wang, Kun; Hoye, Robert L. Z.; Mueller-Buschbaum, Peter; Stranks, Samuel D.; Urban, Alexander S.; Polavarapu, Lakshminarayana; Feldmann, Jochen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Tunable Blue Luminescence of Halide Perovskite nulloplatelets through Postsynthetic Surface Trap Repair", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The easily tunable emission of halide perovskite nullocrystals throughout the visible spectrum makes them an extremely promising material for light-emitting applications. Whereas high quantum yields and long-term colloidal stability have already been achieved for nullocrystals emitting in the red and green spectral range, the blue region currently lags behind with low quantum yields, broad emission profiles, and insufficient colloidal stability. In this work, we present a facile synthetic approach for obtaining two-dimensional CsPbBr3 nulloplatelets with monolayer-precise control over their thickness, resulting in sharp photoluminescence and electroluminescence peaks with a tunable emission wavelength between 432 and 497 nm due to quantum confinement. Subsequent addition of a PbBrr-ligand solution repairs surface delects likely stemming from bromide and lead vacancies in a subensemble of weakly emissive nulloplatelets. The overall photoluminescence quantum yield of the blue-emissive colloidal dispersions is consequently enhanced up to a value of 73 +/- 2%. Transient optical spectroscopy measurements focusing on the excitonic resonullces further confirm the proposed repair process. Additionally, the high stability of these nulloplatelets in films and to prolonged ultraviolet light exposure is shown.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 18, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5231, "End Page": 5238, "Article Number": null, "DOI": "10.1021/acs.nullolett.8b02190", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.8b02190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441478300085", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ellingsen, LAW; Majeau-Bettez, G; Singh, B; Srivastava, AK; Valoen, LO; Stromman, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ellingsen, Linda Ager-Wick; Majeau-Bettez, Guillaume; Singh, Bhawna; Srivastava, Akhilesh Kumar; Valoen, Lars Ole; Stromman, Anders Hammer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Life Cycle Assessment of a Lithium-Ion Battery Vehicle Pack", "Source Title": "JOURNAL OF INDUSTRIAL ECOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electric vehicles (EVs) have no tailpipe emissions, but the production of their batteries leads to environmental burdens. In order to avoid problem shifting, a life cycle perspective should be applied in the environmental assessment of traction batteries. The aim of this study was to provide a transparent inventory for a lithium-ion nickel-cobalt-manganese traction battery based on primary data and to report its cradle-to-gate impacts. The study was carried out as a process-based attributional life cycle assessment. The environmental impacts were analyzed using midpoint indicators. The global warming potential of the 26.6kilowatt-hour(kWh), 253-kilogram battery pack was found to be 4.6tonnes of carbon dioxide equivalents. Regardless of impact category, the production impacts of the battery were caused mainly by the production chains of battery cell manufacture, positive electrode paste, and negative current collector. The robustness of the study was tested through sensitivity analysis, and results were compared with preceding studies. Sensitivity analysis indicated that the most effective approach to reducing climate change emissions would be to produce the battery cells with electricity from a cleaner energy mix. On a per-kWh basis, cradle-to-gate greenhouse gas emissions of the battery were within the range of those reported in preceding studies. Contribution and structural path analysis allowed for identification of the most impact-intensive processes and value chains. This article provides an inventory based mainly on primary data, which can easily be adapted to subsequent EV studies, and offers an improved understanding of environmental burdens pertaining to lithium-ion traction batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 435, "Times Cited, All Databases": 473, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 113, "End Page": 124, "Article Number": null, "DOI": "10.1111/jiec.12072", "DOI Link": "http://dx.doi.org/10.1111/jiec.12072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331442900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Katsenis, AD; Puskaric, A; Strukil, V; Mottillo, C; Julien, PA; Uzarevic, K; Pham, MH; Do, TO; Kimber, SAJ; Lazic, P; Magdysyuk, O; Dinnebier, RE; Halasz, I; Friscic, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Katsenis, Athanassios D.; Puskaric, Andreas; Strukil, Vjekoslav; Mottillo, Cristina; Julien, Patrick A.; Uzarevic, Krunoslav; Minh-Hao Pham; Trong-On Do; Kimber, Simon A. J.; Lazic, Predrag; Magdysyuk, Oxana; Dinnebier, Robert E.; Halasz, Ivan; Friscic, Tomislav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical and physical transformations by milling are attracting enormous interest for their ability to access new materials and clean reactivity, and are central to a number of core industries, from mineral processing to pharmaceutical manufacturing. While continuous mechanical stress during milling is thought to create an environment supporting non-conventional reactivity and exotic intermediates, such speculations have remained without proof. Here we use in situ, real-time powder X-ray diffraction monitoring to discover and capture a metastable, novel-topology intermediate of a mechanochemical transformation. Monitoring the mechanochemical synthesis of an archetypal metal-organic framework ZIF-8 by in situ powder X-ray diffraction reveals unexpected amorphization, and on further milling recrystallization into a non-porous material via a metastable intermediate based on a previously unreported topology, herein named katsenite (kat). The discovery of this phase and topology provides direct evidence that milling transformations can involve short-lived, structurally unusual phases not yet accessed by conventional chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6662, "DOI": "10.1038/ncomms7662", "DOI Link": "http://dx.doi.org/10.1038/ncomms7662", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353042000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SJ; Kim, YI; Lamichhane, B; Kim, YH; Lee, Y; Cho, CR; Cheon, M; Kim, JC; Jeong, HY; Ha, T; Kim, J; Lee, YH; Kim, SG; Kim, YM; Jeong, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Su Jae; Kim, Yong In; Lamichhane, Bipin; Kim, Young-Hoon; Lee, Yousil; Cho, Chae Ryong; Cheon, Miyeon; Kim, Jong Chan; Jeong, Hu Young; Ha, Taewoo; Kim, Jungdae; Lee, Young Hee; Kim, Seong-Gon; Kim, Young-Min; Jeong, Se-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flat-surface-assisted and self-regulated oxidation resistance of Cu(111)", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxidation can deteriorate the properties of copper that are critical for its use, particularly in the semiconductor industry and electro-optics applications(1-7). This has prompted numerous studies exploring copper oxidation and possible passivation strategies(8). In situ observations have, for example, shown that oxidation involves stepped surfaces: Cu2O growth occurs on flat surfaces as a result of Cu adatoms detaching from steps and diffusing across terraces(9-11). But even though this mechanism explains why single-crystalline copper is more resistant to oxidation than polycrystalline copper, the fact that flat copper surfaces can be free of oxidation has not been explored further. Here we report the fabrication of copper thin films that are semi-permanently oxidation resistant because they consist of flat surfaces with only occasional mono-atomic steps. First-principles calculations confirm that mono-atomic step edges are as impervious to oxygen as flat surfaces and that surface adsorption of O atoms is suppressed once an oxygen face-centred cubic (fcc) surface site coverage of 50% has been reached. These combined effects explain the exceptional oxidation resistance of ultraflat Cu surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2022, "Volume": 603, "Issue": 7901, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 434, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04375-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04375-5", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000769827000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Woods, J; Mahvi, A; Goyal, A; Kozubal, E; Odukomaiya, A; Jackson, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Woods, Jason; Mahvi, Allison; Goyal, Anurag; Kozubal, Eric; Odukomaiya, Adewale; Jackson, Roderick", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rate capability and Ragone plots for phase change thermal energy storage", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase change materials can improve the efficiency of energy systems by time shifting or reducing peak thermal loads. The value of a phase change material is defined by its energy and power density-the total available storage capacity and the speed at which it can be accessed. These are influenced by material properties but cannot be defined with these properties alone. Here we show the close link between energy and power density by developing thermal rate capability and Ragone plots, a framework widely used to describe the trade-off between energy and power in electrochemical storage systems (that is, batteries). Our results elucidate how material properties, geometry and operating conditions influence the performance of phase change thermal storage. This research sets a clear framework for comparing thermal storage materials and devices and can be used by researchers and designers to increase clean energy use with storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 295, "End Page": 302, "Article Number": null, "DOI": "10.1038/s41560-021-00778-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00778-w", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617092500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, LH; Liu, XM; He, T; Li, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Lin-Hua; Liu, Xiao-Min; He, Tao; Li, Jian-Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for the Capture of Trace Aromatic Volatile Organic Compounds", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Air pollution, typically haze air, is getting worse in the urban areas of many countries worldwide. The development of advanced materials for the removal of air pollutants is of great significance for protecting public health. We herein present two promising metal-organic frameworks (MOFs) that show high capture capacities for aromatic volatile organic compounds even at low pressure and high temperature, e.g. benzene uptakes of 1.65 and 0.71 mmol g(-1) at 0.12 kPa and 80 degrees C. Breakthrough experiments verify their excellent performance in capturing trace benzene in humid air, also showing them to be comparable with some benchmark materials, including Carboxen 1000, PAF-1, MIL-101 (Cr), and so on. Furthermore, the capture performance is well interpreted by the single-crystal structures of guest-loaded phases, where distinct adsorption sites, multiple synergistic host-guest and guest-guest interactions, and adaptive local flexibility are disclosed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2018, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1911, "End Page": 1927, "Article Number": null, "DOI": "10.1016/j.chempr.2018.05.017", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.05.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441194300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheema, SS; Shanker, N; Hsu, SL; Rho, Y; Hsu, CH; Stoica, VA; Zhang, Z; Freeland, JW; Shafer, P; Grigoropoulos, CP; Ciston, J; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheema, Suraj S.; Shanker, Nirmaan; Hsu, Shang-Lin; Rho, Yoonsoo; Hsu, Cheng-Hsiang; Stoica, Vladimir A.; Zhang, Zhan; Freeland, John W.; Shafer, Padraic; Grigoropoulos, Costas P.; Ciston, Jim; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergent ferroelectricity in subnullometer binary oxide films on silicon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The critical size limit of voltage-switchable electric dipoles has extensive implications for energy-efficient electronics, underlying the importance of ferroelectric order stabilized at reduced dimensionality. We report on the thickness-dependent antiferroelectric-to-ferroelectric phase transition in zirconium dioxide (ZrO2) thin films on silicon. The emergent ferroelectricity and hysteretic polarization switching in ultrathin ZrO2, conventionally a paraelectric material, notably persists down to a film thickness of 5 angstroms, the fluorite-structure unit-cell size. This approach to exploit three-dimensional centrosymmetric materials deposited down to the two-dimensional thickness limit, particularly within this model fluorite-structure system that possesses unconventional ferroelectric size effects, offers substantial promise for electronics, demonstrated by proof-of-principle atomic-scale nonvolatile ferroelectric memory on silicon. Additionally, it is also indicative of hidden electronic phenomena that are achievable across a wide class of simple binary materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 6", "Publication Year": 2022, "Volume": 376, "Issue": 6593, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 648, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm8642", "DOI Link": "http://dx.doi.org/10.1126/science.abm8642", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796932700047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, YC; Fan, XC; Huang, F; Xiong, X; Yu, J; Wang, K; Lee, CS; Zhang, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Ying-Chun; Fan, Xiao-Chun; Huang, Feng; Xiong, Xin; Yu, Jia; Wang, Kai; Lee, Chun-Sing; Zhang, Xiao-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Twisted Carbazole-Fused DABNA Derivative as an Orange-Red TADF Emitter for OLEDs with Nearly 40 % EQE", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiple resonullce (MR) type thermally activated delayed fluorescence (TADF) material is currently a research hotspot in organic light-emitting diodes (OLEDs) due to their high color purity and high exciton utilization. However, there are only a handful of MR-TADF emitters with emissions beyond the blue-to-green region. The very limited emission colors for MR-TADF emitters are mainly caused by the fact that so far molecular modifications of MR-TADF do not offer much change in the emission colors. Here, we report a new approach to modifying a prototypical MR core of DABNA by fusing carbazoles to the MR framework. The carbazole-fused molecule (TCZ-F-DABNA) basically maintains the MR-dominated features of DABNA while red-shifting the emission. Its OLED achieves an external quantum efficiency of 39.2 % with a peak at 588 nm, which is a record-high efficiency for OLEDs with peaks beyond 560 nm. This work provides a new approach for significantly tunning emission colors of MR-TADF emitters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2022, "Volume": 61, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212575", "DOI Link": "http://dx.doi.org/10.1002/anie.202212575", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870421700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YP; Yavuz, I; Wang, MH; Weber, M; Xu, MJ; Lee, JH; Tan, S; Huang, TY; Meng, D; Wang, R; Xue, JJ; Lee, SJ; Bae, SH; Zhang, A; Choi, SG; Yin, YF; Liu, J; Han, TH; Shi, YT; Ma, HR; Yang, WX; Xing, QY; Zhou, YF; Shi, PJ; Wang, SS; Zhang, E; Bian, JM; Pan, XQ; Park, NG; Lee, JW; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yepin; Yavuz, Ilhan; Wang, Minhuan; Weber, Marc H.; Xu, Mingjie; Lee, Joo-Hong; Tan, Shaun; Huang, Tianyi; Meng, Dong; Wang, Rui; Xue, Jingjing; Lee, Sung-Joon; Bae, Sang-Hoon; Zhang, Anni; Choi, Seung-Gu; Yin, Yanfeng; Liu, Jin; Han, Tae-Hee; Shi, Yantao; Ma, Hongru; Yang, Wenxin; Xing, Qiyu; Zhou, Yifan; Shi, Pengju; Wang, Sisi; Zhang, Elizabeth; Bian, Jiming; Pan, Xiaoqing; Park, Nam-Gyu; Lee, Jin-Wook; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressing ion migration in metal halide perovskite via interstitial doping with a trace amount of multivalent cations", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cations with suitable sizes to occupy an interstitial site of perovskite crystals have been widely used to inhibit ion migration and promote the performance and stability of perovskite optoelectronics. However, such interstitial doping inevitably leads to lattice microstrain that impairs the long-range ordering and stability of the crystals, causing a sacrificial trade-off. Here, we unravel the evident influence of the valence states of the interstitial cations on their efficacy to suppress the ion migration. Incorporation of a trivalent neodymium cation (Nd3+) effectively mitigates the ion migration in the perovskite lattice with a reduced dosage (0.08%) compared to a widely used monovalent cation dopant (Na+, 0.45%). The photovoltaic performances and operational stability of the prototypical perovskite solar cells are enhanced with a trace amount of Nd3+ doping while minimizing the sacrificial trade-off. Ion migration has a detrimental effect on the performance and stability of halide perovskite optoelectronics. Here, the authors incorporated a small dosage of high-valence neodymium cation to suppress this, with a minimal impact on the lattice microstrain.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 21, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1396, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01390-3", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01390-3", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884954300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YY; Kottwitz, M; Vincent, JL; Enright, MJ; Liu, ZY; Zhang, LH; Huang, JH; Senullayake, SD; Yang, WCD; Crozier, PA; Nuzzo, RG; Frenkel, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuanyuan; Kottwitz, Matthew; Vincent, Joshua L.; Enright, Michael J.; Liu, Zongyuan; Zhang, Lihua; Huang, Jiahao; Senullayake, Sanjaya D.; Yang, Wei-Chang D.; Crozier, Peter A.; Nuzzo, Ralph G.; Frenkel, Anatoly, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxide-supported noble metal catalysts have been extensively studied for decades for the water gas shift (WGS) reaction, a catalytic transformation central to a host of large volume processes that variously utilize or produce hydrogen. There remains considerable uncertainty as to how the specific features of the active metal-support interfacial bonding-perhaps most importantly the temporal dynamic changes occurring therein-serve to enable high activity and selectivity. Here we report the dynamic characteristics of a Pt/CeO2 system at the atomic level for the WGS reaction and specifically reveal the synergistic effects of metal-support bonding at the perimeter region. We find that the perimeter Pt-0-O vacancy-Ce3+ sites are formed in the active structure, transformed at working temperatures and their appearance regulates the adsorbate behaviors. We find that the dynamic nature of this site is a key mechanistic step for the WGS reaction. Revealing the structure and dynamics of active sites is essential to understand catalytic mechanisms. Here the authors demonstrate the dynamic nature of perimeter Pt-0-O vacancy-Ce3+ sites in Pt/CeO2 and the key effects of their dynamics on the mechanism of the water gas shift reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 914, "DOI": "10.1038/s41467-021-21132-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21132-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620139600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QS; Zhang, SN; Song, HF; Troyer, M; Soluyanov, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, QuanSheng; Zhang, Shengnull; Song, Hai-Feng; Troyer, Matthias; Soluyanov, Alexey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WannierTools: An open-source software package for novel topological materials", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an open-source software package Wannier Tools, a tool for investigation of novel topological materials. This code works in the tight-binding framework, which can be generated by another software package Wannier90 (Mostofi et al., 2008). It can help to classify the topological phase of a given material by calculating the Wilson loop, and can get the surface state spectrum, which is detected by angle resolved photoemission (ARPES) and in scanning tunneling microscopy (STM) experiments. It also identifies positions of Weyl/Dirac points and nodal line structures, calculates the Berry phase around a closed momentum loop and Berry curvature in a part of the Brillouin zone (BZ). Program summary Program title: WannierTools Program Files doi: http://dx.doi.org/10.17632/ygsmh4hyh6.1 Licensing provisions: GNU General Public Licence 3.0 Programming language: Fortran 90 External routines/libraries used: BIAS (http://www/netlib.org/blas) LAPACK (http://www.netlib.org/lapack) Nature of problem: Identifying topological classificatiOns of crystalline systems including insulators, semimetals, metals, and studying the electronic properties of the related slab and ribbon systems. Solution method: Tight-binding method is a good approximation for solid systems. Based on that, Wilson loop is used for topological phase classification. The iterative Green's function is used for obtaining the surface state spectrum. (C) 2017 Elsevier BV. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1950, "Times Cited, All Databases": 2057, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 224, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 405, "End Page": 416, "Article Number": null, "DOI": "10.1016/j.cpc.2017.09.033", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2017.09.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424726700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "DeForest, CA; Tirrell, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "DeForest, Cole A.; Tirrell, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A photoreversible protein-patterning approach for guiding stem cell fate in three-dimensional gels", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although biochemically patterned hydrogels are capable of recapitulating many critical aspects of the heterogeneous cellular niche, exercising spatial and temporal control of the presentation and removal of biomolecular signalling cues in such systems has proved difficult. Here, we demonstrate a synthetic strategy that exploits two bioorthogonal photochemistries to achieve reversible immobilization of bioactive full-length proteins with good spatial and temporal control within synthetic, cellladen biomimetic scaffolds. A photodeprotection-oxime-ligation sequence permits user-defined quantities of proteins to be anchored within distinct subvolumes of a three-dimensional matrix, and an ortho-nitrobenzyl ester photoscission reaction facilitates subsequent protein removal. By using this approach to pattern the presentation of the extracellular matrix protein vitronectin, we accomplished reversible differentiation of human mesenchymal stem cells to osteoblasts in a spatially defined manner. Our protein-patterning approach should provide further avenues to probe and direct changes in cell physiology in response to dynamic biochemical signalling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 523, "End Page": 531, "Article Number": null, "DOI": "10.1038/NMAT4219", "DOI Link": "http://dx.doi.org/10.1038/NMAT4219", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353305700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bandurin, DA; Torre, I; Kumar, RK; Ben Shalom, M; Tomadin, A; Principi, A; Auton, GH; Khestanova, E; Novoselov, KS; Grigorieva, IV; Ponomarenko, LA; Geim, AK; Polini, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bandurin, D. A.; Torre, I.; Kumar, R. Krishna; Ben Shalom, M.; Tomadin, A.; Principi, A.; Auton, G. H.; Khestanova, E.; Novoselov, K. S.; Grigorieva, I. V.; Ponomarenko, L. A.; Geim, A. K.; Polini, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative local resistance caused by viscous electron backflow in graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene hosts a unique electron system in which electron-phonon scattering is extremely weak but electron-electron collisions are sufficiently frequent to provide local equilibrium above the temperature of liquid nitrogen. Under these conditions, electrons can behave as a viscous liquid and exhibit hydrodynamic phenomena similar to classical liquids. Here we report strong evidence for this transport regime. We found that doped graphene exhibits an anomalous (negative) voltage drop near current-injection contacts, which is attributed to the formation of submicrometer-size whirlpools in the electron flow. The viscosity of graphene's electron liquid is found to be similar to 0.1 squaremeters per second, an order of magnitude higher than that of honey, in agreement with many-body theory. Our work demonstrates the possibility of studying electron hydrodynamics using high-quality graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 564, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2016, "Volume": 351, "Issue": 6277, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1055, "End Page": 1058, "Article Number": null, "DOI": "10.1126/science.aad0201", "DOI Link": "http://dx.doi.org/10.1126/science.aad0201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371597500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sajadi, E; Palomaki, T; Fei, ZY; Zhao, WJ; Bement, P; Olsen, C; Luescher, S; Xu, XD; Folk, JA; Cobden, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sajadi, Ebrahim; Palomaki, Tauno; Fei, Zaiyao; Zhao, Wenjin; Bement, Philip; Olsen, Christian; Luescher, Silvia; Xu, Xiaodong; Folk, Joshua A.; Cobden, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-induced superconductivity in a monolayer topological insulator", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The layered semimetal tungsten ditelluride (WTe2) has recently been found to be a two-dimensional topological insulator (2D TI) when thinned down to a single monolayer, with conducting helical edge channels. We found that intrinsic superconductivity can be induced in this monolayer 2D TI by mild electrostatic doping at temperatures below 1 kelvin. The 2D TI-superconductor transition can be driven by applying a small gate voltage. This discovery offers possibilities for gate-controlled devices combining superconductivity and nontrivial topological properties, and could provide a basis for quantum information schemes based on topological protection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2018, "Volume": 362, "Issue": 6417, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 922, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar4426", "DOI Link": "http://dx.doi.org/10.1126/science.aar4426", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451124500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubicki, DJ; Prochowicz, D; Hofstetter, A; Zakeeruddin, SM; Grätzel, M; Emsley, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubicki, Dominik J.; Prochowicz, Daniel; Hofstetter, Albert; Zakeeruddin, Shaik M.; Graetzel, Michael; Emsley, Lyndon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA)x(FA)1-xPbl3 Hybrid Perovskites from Solid-State NMR", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid (organic-inorganic) multication lead halide perovskites hold promise for a new generation of easily processable solar cells. Best performing compositions to date are multiple-cation solid alloys of formamidinium (FA), methylammonium (MA), cesium, and rubidium lead halides which provide power conversion efficiencies up to around 22%. Here, we elucidate the atomic-level nature of Cs and Rb incorporation into the perovskite lattice of FA-based materials. We use Cs-23, Rb-87, K-89, C-13, and N-14 solid-state MAS NMR to probe microscopic composition of Cs-, Rb-, K-, MA-, and FA-containing phases in double-, triple-, and quadruple-cation lead halides in bulk and in a thin film. Contrary to previous reports, we have found no proof of Rb or K incorporation into the 3D perovskite lattice in these systems. We also show that the structure of bulk mechanochemical perovskites bears close resemblance to that of thin films, making them a good benchmark for structural studies. These findings provide fundamental understanding of previously reported excellent photovoltaic parameters in these systems and their superior stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 139, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14173, "End Page": 14180, "Article Number": null, "DOI": "10.1021/jacs.7b07223", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b07223", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413057100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuzyk, A; Jungmann, R; Acuna, GP; Liu, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuzyk, Anton; Jungmann, Ralf; Acuna, Guillermo P.; Liu, Na", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DNA Origami Route for nullophotonics", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The specificity and simplicity of the Watson Crick base pair interactions make DNA one of the most versatile construction materials for creating nulloscale structures and devices. Among several DNA-based approaches, the DNA origami technique excels in programmable self-assembly of complex, arbitrary shaped structures with dimensions of hundreds of nullometers. Importantly, DNA origami can be used as templates for assembly of functional nulloscale components into three-dimensional structures with high precision and controlled stoichiometry. This is often beyond the reach of other nullofabrication techniques. In this Perspective, we highlight the capability of the DNA origami technique for realization of novel nullophotonic systems. First, we introduce the basic principles of designing and fabrication of DNA origami structures. Subsequently, we review recent advances of the DNA origami applications in nulloplasmonics, single-molecule and super resolution fluorescent imaging, as well as hybrid photonic systems. We conclude by outlining the future prospects of the DNA origami technique for advanced nullophotonic systems with tailored functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1151, "End Page": 1163, "Article Number": null, "DOI": "10.1021/acsphotonics.7b01580", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.7b01580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430642500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sahin, ME; Blaabjerg, F; Sangwongwanich, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sahin, Mustafa Ergin; Blaabjerg, Frede; Sangwongwanich, Ariya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Comprehensive Review on Supercapacitor Applications and Developments", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The storage of enormous energies is a significant challenge for electrical generation. Researchers have studied energy storage methods and increased efficiency for many years. In recent years, researchers have been exploring new materials and techniques to store more significant amounts of energy more efficiently. In particular, renewable energy sources and electric vehicle technologies are triggering these scientific studies. Scientists and manufacturers recently proposed the supercapacitor (SC) as an alternating or hybrid storage device. This paper aims to provide a comprehensive review of SC applications and their developments. Accordingly, a detailed literature review was first carried out. The historical results of SCs are revealed in this paper. The structure, working principle, and materials of SC are given in detail to be analysed more effectively. The advantages and disadvantages, market profile, and new technologies with manufacturer corporations are investigated to produce a techno-economic analysis of SCs. The electric vehicle, power systems, hybrid energy storage systems with integration of renewable energy sources, and other applications of SCs are investigated in this paper. Additionally, SC modelling design principles with charge and discharge tests are explored. Other components and their price to produce a compact module for high power density are also investigated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 674, "DOI": "10.3390/en15030674", "DOI Link": "http://dx.doi.org/10.3390/en15030674", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000759423300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dixon, PG; Gibson, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dixon, P. G.; Gibson, L. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The structure and mechanics of Moso bamboo material", "Source Title": "JOURNAL OF THE ROYAL SOCIETY INTERFACE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although bamboo has been used structurally for millennia, there is currently increasing interest in the development of renewable and sustainable structural bamboo products (SBPs). These SBPs are analogous to wood products such as plywood, oriented strand board and glue-laminated wood. In this study, the properties of natural Moso bamboo (Phyllostachys pubescens) are investigated to further enable the processing and design of SBPs. The radial and longitudinal density gradients in bamboo give rise to variations in the mechanical properties. Here, we measure the flexural properties of Moso bamboo in the axial direction, along with the compressive strengths in the axial and transverse directions. Based on the microstructural variations (observed with scanning electron microscopy) and extrapolated solid cell wall properties of bamboo, we develop models, which describe the experimental results well. Compared to common North American construction woods loaded along the axial direction, Moso bamboo is approximately as stiff and substantially stronger, in both flexure and compression but denser. This work contributes to critical knowledge surrounding the microstructure and mechanical properties of bamboo, which are vital to the engineering and design of sustainable SBPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2014, "Volume": 11, "Issue": 99, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20140321, "DOI": "10.1098/rsif.2014.0321", "DOI Link": "http://dx.doi.org/10.1098/rsif.2014.0321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341100800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, KK; Li, Q; Lyu, YB; Ding, JC; Lu, Y; Cheng, ZY; Qiu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Kai-Kai; Li, Qiang; Lyu, Yan-Biao; Ding, Ji-Chao; Lu, Yue; Cheng, Zhi-Yuan; Qiu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control over emissivity of zero-static-power thermal emitters based on phase-changing material GST", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling the emissivity of a thermal emitter has attracted growing interest, with a view toward a new generation of thermal emission devices. To date, all demonstrations have involved using sustained external electric or thermal consumption to maintain a desired emissivity. In the present study, we demonstrated control over the emissivity of a thermal emitter consisting of a film of phase-changing material Ge2Sb2Te5 (GST) on top of a metal film. This thermal emitter achieves broad wavelength-selective spectral emissivity in the mid-infrared. The peak emissivity approaches the ideal blackbody maximum, and a maximum extinction ratio of > 10 dB is attainable by switching the GST between the crystalline and amorphous phases. By controlling the intermediate phases, the emissivity can be continuously tuned. This switchable, tunable, wavelength-selective and thermally stable thermal emitter will pave the way toward the ultimate control of thermal emissivity in the field of fundamental science as well as for energy harvesting and thermal control applications, including thermophotovoltaics, light sources, infrared imaging and radiative coolers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e16194", "DOI": "10.1038/lsa.2016.194", "DOI Link": "http://dx.doi.org/10.1038/lsa.2016.194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395833100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YF; Chou, JB; Li, JY; Li, HS; Du, QY; Yadav, A; Zhou, S; Shalaginov, MY; Fang, ZR; Zhong, HK; Roberts, C; Robinson, P; Bohlin, B; Ríos, C; Lin, HT; Kang, M; Gu, T; Warner, J; Liberman, V; Richardson, K; Hu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yifei; Chou, Jeffrey B.; Li, Junying; Li, Huashan; Du, Qingyang; Yadav, Anupama; Zhou, Si; Shalaginov, Mikhail Y.; Fang, Zhuoran; Zhong, Huikai; Roberts, Christopher; Robinson, Paul; Bohlin, Bridget; Rios, Carlos; Lin, Hongtao; Kang, Myungkoo; Gu, Tian; Warner, Jamie; Liberman, Vladimir; Richardson, Kathleen; Hu, Juejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband transparent optical phase change materials for high-performance nonvolatile photonics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical phase change materials (O-PCMs), a unique group of materials featuring exceptional optical property contrast upon a solid-state phase transition, have found widespread adoption in photonic applications such as switches, routers and reconfigurable meta-optics. Current O-PCMs, such as Ge-Sb-Te (GST), exhibit large contrast of both refractive index (Delta n) and optical loss (Delta k), simultaneously. The coupling of both optical properties fundamentally limits the performance of many applications. Here we introduce a new class of O-PCMs based on Ge-Sb-Se-Te (GSST) which breaks this traditional coupling. The optimized alloy, Ge2Sb2-Se4Te1, combines broadband transparency (1-18.5 mu m), large optical contrast (Delta n = 2.0), and significantly improved glass forming ability, enabling an entirely new range of infrared and thermal photonic devices. We further demonstrate nonvolatile integrated optical switches with record low loss and large contrast ratio and an electrically-addressed spatial light modulator pixel, thereby validating its promise as a material for scalable nonvolatile photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4279, "DOI": "10.1038/s41467-019-12196-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12196-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488234700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, HM; Dai, X; Fang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Hongming; Dai, Xi; Fang, Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition-Metal Pentatelluride ZrTe5 and HfTe5: A Paradigm for Large-Gap Quantum Spin Hall Insulators", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin Hall (QSH) insulators, a new class of quantum matter, can support topologically protected helical edge modes inside a bulk insulating gap, which can lead to dissipationless transport. A major obstacle to reaching a wide application of QSH is the lack of suitable QSH compounds, which should be easily fabricated and have a large bulk gap. Here, we predict that single-layer ZrTe5 and HfTe5 are the most promising candidates for large-gap insulators, with a bulk direct (indirect) band gap as large as 0.4 eV (0.1 eV) and which are robust against external strains. The three-dimensional crystals of these two materials are good layered compounds with very weak interlayer bonding, and they are located near the phase boundary between weak and strong topological insulators, paving a new way for future experimental studies on both the QSH effect and topological phase transitions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2014, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11002, "DOI": "10.1103/PhysRevX.4.011002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.4.011002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332154000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XH; Xi, SB; Kim, H; Kumar, A; Lee, J; Wang, J; Tran, NQ; Yang, T; Shao, XD; Liang, MF; Kim, MG; Lee, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xinghui; Xi, Shibo; Kim, Hyunwoo; Kumar, Ashwani; Lee, Jinsun; Wang, Jian; Ngoc Quang Tran; Yang, Taehun; Shao, Xiaodong; Liang, Mengfang; Kim, Min Gyu; Lee, Hyoyoung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Restructuring highly electron-deficient metal-metal oxides for boosting stability in acidic oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor catalyst stability in acidic oxidation evolution reaction (OER) has been a long-time issue. Herein, we introduce electron-deficient metal on semiconducting metal oxides-consisting of Ir (Rh, Au, Ru)-MoO3 embedded by graphitic carbon layers (IMO) using an electrospinning method. We systematically investigate IMO's structure, electron transfer behaviors, and OER catalytic performance by combining experimental and theoretical studies. Remarkably, IMO with an electron-deficient metal surface (Irx+; x > 4) exhibit a low overpotential of only similar to 156 mV at 10 mA cm(-2) and excellent durability in acidic media due to the high oxidation state of metal on MoO3. Furthermore, the proton dissociation pathway is suggested via surface oxygen serving as proton acceptors. This study suggests high stability with high catalytic performance in these materials by creating electron-deficient surfaces and provides a general, unique strategy for guiding the design of other metal-semiconductor nullocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5676, "DOI": "10.1038/s41467-021-26025-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26025-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701980200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, FF; Huang, R; Wang, CM; Yu, XL; Liu, HJ; Wu, QC; Qian, KY; Bhagat, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Fenfang; Huang, Rui; Wang, Chongming; Yu, Xiaoli; Liu, Huijun; Wu, Qichao; Qian, Keyu; Bhagat, Rohit", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air and PCM cooling for battery thermal management considering battery cycle life", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cycle life of lithium-ion batteries (LIBs) is essential for the application of hybrid electric vehicles (HEV) and electric vehicles (EV). Since temperature greatly affects degradation rate and safety of LIBs, battery thermal management system (BTMS) is required. In this paper, the performance of active air cooling and passive phase change material (PCM) cooling for BTMS are assessed in terms of battery thermal states and cycle life. A coupled one-dimensional electrochemical and two-dimensional thermal models are developed to simulate the temperature of a battery module with 16 cylindrical (26650) graphite-LiFePO4 lithium-ion battery cells. The model is validated with the experimental data taken from literature. By applying a realistic current profile of a HEV to the battery model, simulations are performed at various ambient temperatures, inlet velocities of air cooling and PCM phase change temperatures. The battery cycle life and its non-uniformity across the module are estimated with a battery degradation model with inputs of battery temperature results. The study shows that active air cooling has a better cooling effect than PCM cooling, especially at high ambient temperatures. But the active air cooling leads to a large temperature non-uniformity at low inlet air velocities. The cycle life of the battery module under air cooling is longer than that of PCM cooling, although a larger life non-uniformity is observed. Furthermore, two methods are compared by a newly proposed evaluation index called cyclical cost. This index considers both the battery cycle life and the parasitic power consumption of the BTMS. The result demonstrates that air cooling has a lower cyclical cost than PCM cooling. When the inlet velocity of the air cooling system increases, the cyclical cost has a trend of decreasing first and then increasing. This paper provides a guide for the development of BTMS to further prolong the cycle life and reduce total operating cost of LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2020, "Volume": 173, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115154, "DOI": "10.1016/j.applthermaleng.2020.115154", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2020.115154", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526111200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, XY; Sun, K; Liu, ZK; Liu, XH; Dong, WK; Zuo, XT; Shao, RW; Tao, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Xue-Yang; Sun, Ke; Liu, Zhi-Kun; Liu, Xinghui; Dong, Weikang; Zuo, Xintao; Shao, Ruiwen; Tao, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct electrochemical nitrate reduction reaction (NITRR) is a promising strategy to alleviate the unbalanced nitrogen cycle while achieving the electrosynthesis of ammonia. However, the restructuration of the high-activity Cu-based electrocatalysts in the NITRR process has hindered the identification of dynamical active sites and in-depth investigation of the catalytic mechanism. Herein, Cu species (single-atom, clusters, and nulloparticles) with tunable loading supported on N-doped TiO2/C are successfully manufactured with MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy. Restructuration behavior among Cu species is co-dependent on the Cu loading and reaction potential, as evidenced by the advanced operando X-ray absorption spectroscopy, and there exists an incompletely reversible transformation of the restructured structure to the initial state. Notably, restructured CuN4&Cu-4 deliver the high NH3 yield of 88.2 mmol h(-1) g(cata)(-1) and FE ( 94.3%) at - 0.75 V, resulting from the optimal adsorption of NO3- as well as the rapid conversion of *NH2OH to *NH2 intermediates originated from the modulation of charge distribution and d-band center for Cu site. This work not only uncovers CuN4&Cu-4 have the promising NITRR but also identifies the dynamic Cu species active sites that play a critical role in the efficient electrocatalytic reduction in nitrate to ammonia.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110, "DOI": "10.1007/s40820-023-01091-9", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01091-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980608600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YN; Liu, CH; Debnath, T; Wang, Y; Pohl, D; Besteiro, LV; Meira, DM; Huang, SY; Yang, F; Rellinghaus, B; Chaker, M; Perepichka, DF; Ma, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yannull; Liu, Cheng-Hao; Debnath, Tushar; Wang, Yong; Pohl, Darius; Besteiro, Lucas V.; Meira, Debora Motta; Huang, Shengyun; Yang, Fan; Rellinghaus, Bernd; Chaker, Mohamed; Perepichka, Dmytro F.; Ma, Dongling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silver nulloparticle enhanced metal-organic matrix with interface-engineering for efficient photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integrating plasmonic nulloparticles into the photoactive metal-organic matrix is highly desirable due to the plasmonic near field enhancement, complementary light absorption, and accelerated separation of photogenerated charge carriers at the junction interface. The construction of a well-defined, intimate interface is vital for efficient charge carrier separation, however, it remains a challenge in synthesis. Here we synthesize a junction bearing intimate interface, composed of plasmonic Ag nulloparticles and matrix with silver node via a facile one-step approach. The plasmonic effect of Ag nulloparticles on the matrix is visualized through electron energy loss mapping. Moreover, charge carrier transfer from the plasmonic nulloparticles to the matrix is verified through ultrafast transient absorption spectroscopy and in-situ photoelectron spectroscopy. The system delivers highly efficient visible-light photocatalytic H-2 generation, surpassing most reported metal-organic framework-based photocatalytic systems. This work sheds light on effective electronic and energy bridging between plasmonic nulloparticles and organic semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 541, "DOI": "10.1038/s41467-023-35981-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35981-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001034930800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anastasaki, A; Nikolaou, V; Zhang, Q; Burns, J; Samanta, SR; Waldron, C; Haddleton, AJ; McHale, R; Fox, D; Percec, V; Wilson, P; Haddleton, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anastasaki, Athina; Nikolaou, Vasiliki; Zhang, Qiang; Burns, James; Samanta, Shampa R.; Waldron, Christopher; Haddleton, Alice J.; McHale, Ronull; Fox, David; Percec, Virgil; Wilson, Paul; Haddleton, David M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper(II)/Tertiary Amine Synergy in Photoinduced Living Radical Polymerization: Accelerated Synthesis of ω-Functional and α,ω-Heterofunctional Poly(acrylates)", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoinduced living radical polymerization of acrylates, in the absence of conventional photoinitiators or dye sensitizers, has been realized in daylight' and is enhanced upon irradiation with UV radiation (lambda(max) approximate to 360 nm). In the presence of low concentrations of copper(II) bromide and an aliphatic tertiary amine ligand (Me-6-Tren; Tren = tris(2-aminoethyl)amine), near-quantitative monomer conversion (>95%) is obtained within 80 min, yielding poly(acrylates) with dispersities as low as 1.05 and excellent end group fidelity (>99%). The versatility of the technique is demonstrated by polymerization of methyl acrylate to a range of chain lengths (DPn = 25-800) and a number of (meth)acrylate monomers, including macromonomer poly(ethylene glycol) methyl ether acrylate (PEGA(480)), tert-butyl acrylate, and methyl methacrylate, as well as styrene. Moreover, hydroxyl- and vic-diol-functional initiators are compatible with the polymerization conditions, forming alpha,omega-heterofunctional poly(acrylates) with unparalleled efficiency and control. The control retained during polymerization is confirmed by MALDI-ToF-MS and exemplified by in situ chain extension upon sequential monomer addition, furnishing higher molecular weight polymers with an observed reduction in dispersity (D = 1.03). Similarly, efficient one-pot diblock copolymerization by sequential addition of ethylene glycol methyl ether acrylate and PEGA(480) to a poly(methyl acrylate) macroinitiator without prior workup or purification is also reported. Minimal polymerization in the absence of light confers temporal control and alludes to potential application at one of the frontiers of materials chemistry whereby precise spatiotemporal on/off' control and resolution is desirable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2014, "Volume": 136, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1141, "End Page": 1149, "Article Number": null, "DOI": "10.1021/ja411780m", "DOI Link": "http://dx.doi.org/10.1021/ja411780m", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330202300051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HJ; Huang, SH; Montes-García, V; Pakulski, D; Guo, HP; Richard, F; Zhuang, XD; Samorì, P; Ciesielski, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Haijun; Huang, Senhe; Montes-Garcia, Veronica; Pakulski, Dawid; Guo, Haipeng; Richard, Fanny; Zhuang, Xiaodong; Samori, Paolo; Ciesielski, Artur", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular Engineering of Cathode Materials for Aqueous Zinc-ion Energy Storage Devices: Novel Benzothiadiazole Functionalized Two-Dimensional Olefin-Linked COFs", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional covalent organic frameworks (COFs) have emerged as promising materials for energy storage applications exhibiting enhanced electrochemical performance. While most of the reported organic cathode materials for zinc-ion batteries use carbonyl groups as electrochemically-active sites, their high hydrophilicity in aqueous electrolytes represents a critical drawback. Herein, we report a novel and structurally robust olefin-linked COF-TMT-BT synthesized via the aldol condensation between 2,4,6-trimethyl-1,3,5-triazine (TMT) and 4,4 '-(benzothiadiazole-4,7-diyl)dibenzaldehyde (BT), where benzothiadiazole units are explored as novel electrochemically-active groups. Our COF-TMT-BT exhibits an outstanding Zn2+ storage capability, delivering a state-of-the-art capacity of 283.5 mAh g(-1) at 0.1 A g(-1). Computational and experimental analyses reveal that the charge-storage mechanism in COF-TMT-BT electrodes is based on the supramolecularly engineered and reversible Zn2+ coordination by the benzothiadiazole units.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 62, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202216136", "DOI Link": "http://dx.doi.org/10.1002/anie.202216136", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000920582900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, RZ; Dong, XS; Liang, P; Li, HP; Zhang, TS; Zhou, WH; Wang, BY; Yang, ZD; Wang, X; Wang, LP; Sun, ZH; Bu, FX; Zhao, ZW; Li, W; Zhao, DY; Chao, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ruizheng; Dong, Xusheng; Liang, Pei; Li, Hongpeng; Zhang, Tengsheng; Zhou, Wanhai; Wang, Boya; Yang, Zhoudong; Wang, Xia; Wang, Lipeng; Sun, Zhihao; Bu, Fanxing; Zhao, Zaiwang; Li, Wei; Zhao, Dongyuan; Chao, Dongliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prioritizing Hetero-Metallic Interfaces via Thermodynamics Inertia and Kinetics Zincophilia Metrics for Tough Zn-Based Aqueous Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poor thermodynamic stability and sluggish electrochemical kinetics of metallic Zn anode in aqueous solution greatly hamper its practical application. To solve such problems, to date, various zincophilic surface modification strategies are developed, which can facilitate reversible Zn plating/stripping behavior. However, there is still a lack of systematic and fundamental understanding regarding the metrics of thermodynamics inertia and kinetics zincophilia in selecting zincophilic sites. Herein, hetero-metallic interfaces are prioritized for the first time via optimizing different hetero metals (Fe, Co, Ni, Sn, Bi, Cu, Zn, etc.) and synthetic solvents (ethanol, ethylene glycol, n-propanol, etc.). Specifically, both theoretical simulations and experimental results suggest that this Bi@Zn interface can exhibit high efficiency owing to the thermodynamics inertia and kinetics zincophilia. A best practice for prioritizing zincophilic sites in a more practical metric is also proposed. As a proof of concept, the Bi@Zn anode delivers ultralow overpotential of approximate to 55 mV at a high rate of 10 mA cm(-2) and stable cycle life over 4700 cycles. The elaborated thermodynamics inertia and kinetics metalphilia metrics for hetero-metallic interfaces can benchmark the success of other metal-based batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 35, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209288", "DOI Link": "http://dx.doi.org/10.1002/adma.202209288", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000949378100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Zhou, YH; Xu, J; Chen, GR; Fang, YS; Tat, T; Xiao, X; Song, Y; Li, S; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xun; Zhou, Yihao; Xu, Jing; Chen, Guorui; Fang, Yunsheng; Tat, Trinny; Xiao, Xiao; Song, Yang; Li, Song; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft fibers with magnetoelasticity for wearable electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetoelastic effect characterizes the change of materials' magnetic properties under mechanical deformation, which is conventionally observed in some rigid metals or metal alloys. Here we show magnetoelastic effect can also exist in 1D soft fibers with stronger magnetomechanical coupling than that in traditional rigid counterparts. This effect is explained by a wavy chain model based on the magnetic dipole-dipole interaction and demagnetizing factor. To facilitate practical applications, we further invented a textile magnetoelastic generator (MEG), weaving the 1D soft fibers with conductive yarns to couple the observed magnetoelastic effect with magnetic induction, which paves a new way for biomechanical-to-electrical energy conversion with short-circuit current density of 0.63 mA cm(-2), internal impedance of 180 ohm, and intrinsic waterproofness. Textile MEG was demonstrated to convert the arterial pulse into electrical signals with a low detection limit of 0.05 kPa, even with heavy perspiration or in underwater situations without encapsulations. The authors invented a textile magnetoelastic generator, weaving 1D soft fibers with conductive yarns to couple the observed magnetoelastic effect with magnetic induction, which paves a new way for biomechanical-to-electrical energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6755, "DOI": "10.1038/s41467-021-27066-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27066-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720682600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, H; Bruns, OT; Kaul, MG; Hansen, EC; Barch, M; Wisniowska, A; Chen, O; Chen, Y; Li, N; Okada, S; Cordero, JM; Heine, M; Farrar, CT; Montana, DM; Adam, G; Ittrich, H; Jasanoff, A; Nielsen, P; Bawendi, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, He; Bruns, Oliver T.; Kaul, Michael G.; Hansen, Eric C.; Barch, Mariya; Wisniowska, Agata; Chen, Ou; Chen, Yue; Li, null; Okada, Satoshi; Cordero, Jose M.; Heine, Markus; Farrar, Christian T.; Montana, Daniel M.; Adam, Gerhard; Ittrich, Harald; Jasanoff, Alan; Nielsen, Peter; Bawendi, Moungi G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceedingly small iron oxide nulloparticles as positive MRI contrast agents", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Medical imaging is routine in the diagnosis and staging of a wide range of medical conditions. In particular, magnetic resonullce imaging (MRI) is critical for visualizing soft tissue and organs, with over 60 million MRI procedures performed each year worldwide. About one-third of these procedures are contrast-enhanced MRI, and gadolinium-based contrast agents (GBCAs) are the mainstream MRI contrast agents used in the clinic. GBCAs have shown efficacy and are safe to use with most patients; however, some GBCAs have a small risk of adverse effects, including nephrogenic systemic fibrosis (NSF), the untreatable condition recently linked to gadolinium (Gd) exposure during MRI with contrast. In addition, Gd deposition in the human brain has been reported following contrast, and this is now under investigation by the US Food and Drug Administration (FDA). To address a perceived need for a Gd-free contrast agent with pharmacokinetic and imaging properties comparable to GBCAs, we have designed and developed zwitterion-coated exceedingly small superparamagnetic iron oxide nulloparticles (ZES-SPIONs) consisting of similar to 3-nm inorganic cores and similar to 1-nm ultrathin hydrophilic shell. These ZES-SPIONs are free of Gd and show a high T-1 contrast power. We demonstrate the potential of ZES-SPIONs in preclinical MRI and magnetic resonullce angiography.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2017, "Volume": 114, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2325, "End Page": 2330, "Article Number": null, "DOI": "10.1073/pnas.1620145114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1620145114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395101200066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoon, JH; Wang, ZR; Kim, KM; Wu, HQ; Ravichandran, V; Xia, QF; Hwang, CS; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoon, Jung Ho; Wang, Zhongrui; Kim, Kyung Min; Wu, Huaqiang; Ravichandran, Vignesh; Xia, Qiangfei; Hwang, Cheol Seong; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An artificial nociceptor based on a diffusive memristor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A nociceptor is a critical and special receptor of a sensory neuron that is able to detect noxious stimulus and provide a rapid warning to the central nervous system to start the motor response in the human body and humanoid robotics. It differs from other common sensory receptors with its key features and functions, including the no adaptation and sensitization phenomena. In this study, we propose and experimentally demonstrate an artificial nociceptor based on a diffusive memristor with critical dynamics for the first time. Using this artificial nociceptor, we further built an artificial sensory alarm system to experimentally demonstrate the feasibility and simplicity of integrating such novel artificial nociceptor devices in artificial intelligence systems, such as humanoid robots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 417, "DOI": "10.1038/s41467-017-02572-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02572-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423431900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dankert, A; Dash, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dankert, Andre; Dash, Saroj P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical gate control of spin current in van der Waals heterostructures at room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) crystals offer a unique platform due to their remarkable and contrasting spintronic properties, such as weak spin-orbit coupling (SOC) in graphene and strong SOC in molybdenum disulfide (MoS2). Here we combine graphene and MoS2 in a van der Waals heterostructure (vdWh) to demonstrate the electric gate control of the spin current and spin lifetime at room temperature. By performing non-local spin valve and Hanle measurements, we unambiguously prove the gate tunability of the spin current and spin lifetime in graphene/MoS2 vdWhs at 300 K. This unprecedented control over the spin parameters by orders of magnitude stems from the gate tuning of the Schottky barrier at the MoS2/graphene interface and MoS2 channel conductivity leading to spin dephasing in high-SOC material. Our findings demonstrate an all-electrical spintronic device at room temperature with the creation, transport and control of the spin in 2D materials heterostructures, which can be key building blocks in future device architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16093, "DOI": "10.1038/ncomms16093", "DOI Link": "http://dx.doi.org/10.1038/ncomms16093", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404781400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XC; Zhao, GP; Fangohr, H; Liu, JP; Xia, WX; Xia, J; Morvan, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xichao; Zhao, G. P.; Fangohr, Hans; Liu, J. Ping; Xia, W. X.; Xia, J.; Morvan, F. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skyrmion-skyrmion and skyrmion-edge repulsions in skyrmion-based racetrack memory", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are promising for building next-generation magnetic memories and spintronic devices due to their stability, small size and the extremely low currents needed to move them. In particular, skyrmion-based racetrack memory is attractive for information technology, where skyrmions are used to store information as data bits instead of traditional domain walls. Here we numerically demonstrate the impacts of skyrmion-skyrmion and skyrmion-edge repulsions on the feasibility of skyrmion-based racetrack memory. The reliable and practicable spacing between consecutive skyrmionic bits on the racetrack as well as the ability to adjust it are investigated. Clogging of skyrmionic bits is found at the end of the racetrack, leading to the reduction of skyrmion size. Further, we demonstrate an effective and simple method to avoid the clogging of skyrmionic bits, which ensures the elimination of skyrmionic bits beyond the reading element. Our results give guidance for the design and development of future skyrmion-based racetrack memory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 468, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7643, "DOI": "10.1038/srep07643", "DOI Link": "http://dx.doi.org/10.1038/srep07643", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347796200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, K; Chen, NF; Wang, CJ; Wei, LS; Chen, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Kai; Chen, Nuofu; Wang, Congjie; Wei, Lishuai; Chen, Jikun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Method for Determining Crystal Grain Size by X-Ray Diffraction", "Source Title": "CRYSTAL RESEARCH AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystalgrain size can be quantitatively calculated by Scherrer equation according to the diffraction peak broadening in the XRD curves. Actually, the results calculated by the Scherrer equation are the thickness that perpendicular to the crystal planes. However, in the actual XRD measurements, the broadening of the diffraction peaks is not only because of the Micro-level changes of crystal such as grain size and lattice distortion, but also due to the instrumental broadening. Thus, the Scherrer equation is less reliable if the full width at half maximum caused by the physical broadening is smaller than that caused by the instrumental broadening. In this paper, it is concluded that the applicable range of the Scherrer equation will increases with the increasing diffraction angle. As an example of Scherrer equation's application, the calculation result for the maximum applicable scope of Si(100) films is 137nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 53, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700157, "DOI": "10.1002/crat.201700157", "DOI Link": "http://dx.doi.org/10.1002/crat.201700157", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Crystallography", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425628900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwak, H; Kim, JS; Han, D; Kim, JS; Park, J; Kwon, G; Bak, SM; Heo, U; Park, C; Lee, HW; Nam, KW; Seo, DH; Jung, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwak, Hiram; Kim, Jae-Seung; Han, Daseul; Kim, Jong Seok; Park, Juhyoun; Kwon, Gihan; Bak, Seong-Min; Heo, Unseon; Park, Changhyun; Lee, Hyun-Wook; Nam, Kyung-Wan; Seo, Dong-Hwa; Jung, Yoon Seok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting the interfacial superionic conduction of halide solid electrolytes for all-solid-state batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing highly conductive and (electro)chemical stable inorganic solid electrolytes using cost-effective materials is crucial for developing all-solid-state batteries. Here, we report halide nullocomposite solid electrolytes (HNSEs) ZrO2(-ACl)-A(2)ZrCl(6) (A = Li or Na) that demonstrate improved ionic conductivities at 30 degrees C, from 0.40 to 1.3 mS cm(-1) and from 0.011 to 0.11 mS cm(-1) for Li+ and Na+, respectively, compared to A(2)ZrCl(6), and improved compatibility with sulfide solid electrolytes. The mechanochemical method employing Li2O for the HNSEs synthesis enables the formation of nullostructured networks that promote interfacial superionic conduction. Via density functional theory calculations combined with synchrotron X-ray and Li-6 nuclear magnetic resonullce measurements and analyses, we demonstrate that interfacial oxygen-substituted compounds are responsible for the boosted interfacial conduction mechanism. Compared to state-of-the-art Li2ZrCl6, the fluorinated ZrO2-2Li(2)ZrCl(5)F HNSE shows improved high-voltage stability and interfacial compatibility with Li6PS5Cl and layered lithium transition metal oxide-based positive electrodes without detrimentally affecting Li+ conductivity. We also report the assembly and testing of a Li-In||LiNi0.88Co0.11Mn0.01O2 all-solid-state lab-scale cell operating at 30 degrees C and 70 MPa and capable of delivering a specific discharge of 115 mAh g(-1) after almost 2000 cycles at 400 mA g(-1). Compositional tuning is a standard procedure to improve the ionic conductivity of inorganic superionic conductors. Here, the authors report (electro)chemical stable composite halide solid electrolytes applying a nullostructure approach that promotes interfacial superionic conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-38037-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38037-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983415900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JS; Yoon, G; Kim, S; Sugata, S; Yashiro, N; Suzuki, S; Lee, MJ; Kim, R; Badding, M; Song, Z; Chang, JM; Im, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Ju-Sik; Yoon, Gabin; Kim, Sewon; Sugata, Shoichi; Yashiro, Nobuyoshi; Suzuki, Shinya; Lee, Myung-Jin; Kim, Ryounghee; Badding, Michael; Song, Zhen; Chang, JaeMyung; Im, Dongmin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface engineering of inorganic solid-state electrolytes via interlayers strategy for developing long-cycling quasi-all-solid-state lithium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries (LMBs) with inorganic solid-state electrolytes suffer from lithium dendrites propagation. Here, the authors demonstrate the production of stable lab-scale LMBs using an Ag-coated Li6.4La3Zr1.7Ta0.3O12 inorganic solid electrolyte in combination with a silver-carbon interlayer. Lithium metal batteries (LMBs) with inorganic solid-state electrolytes are considered promising secondary battery systems because of their higher energy content than their Li-ion counterpart. However, the LMB performance remains unsatisfactory for commercialization, primarily owing to the inability of the inorganic solid-state electrolytes to hinder lithium dendrite propagation. Here, using an Ag-coated Li6.4La3Zr1.7Ta0.3O12 (LLZTO) inorganic solid electrolyte in combination with a silver-carbon interlayer, we demonstrate the production of stable interfacially engineered lab-scale LMBs. Via experimental measurements and computational modelling, we prove that the interlayers strategy effectively regulates lithium stripping/plating and prevents dendrite penetration in the solid-state electrolyte pellet. By coupling the surface-engineered LLZTO with a lithium metal negative electrode, a high-voltage positive electrode with an ionic liquid-based liquid electrolyte solution in pouch cell configuration, we report 800 cycles at 1.6 mA/cm(2) and 25 degrees C without applying external pressure. This cell enables an initial discharge capacity of about 3 mAh/cm(2) and a discharge capacity retention of about 85%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 782, "DOI": "10.1038/s41467-023-36401-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36401-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002560100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, F; Wang, KZ; Yan, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Fei; Wang, Ke-Zhi; Yan, Dongpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supramolecular glasses with color-tunable circularly polarized afterglow through evaporation-induced self-assembly of chiral metal-organic complexes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Material designs with multicolor circularly polarized emissions are desirable for photonic applications. Here, the authors report supramolecular glasses based on self-assembled chiral metal-organic complexes with color-tunable circularly polarized afterglow. The fabrication of chiral molecules into macroscopic systems has many valuable applications, especially in the fields of optical displays, data encryption, information storage, and so on. Here, we design and prepare a serious of supramolecular glasses (SGs) based on Zn-L-Histidine complexes, via an evaporation-induced self-assembly (EISA) strategy. Metal-ligand interactions between the zinc(II) ion and chiral L-Histidine endow the SGs with interesting circularly polarized afterglow (CPA). Multicolored CPA emissions from blue to red with dissymmetry factor as high as 9.5 x 10(-3) and excited-state lifetime up to 356.7 ms are achieved under ambient conditions. Therefore, this work not only communicates the bulk SGs with wide-tunable afterglow and large circular polarization, but also provides an EISA method for the macroscopic self-assembly of chiral metal-organic hybrids toward photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1654, "DOI": "10.1038/s41467-023-37331-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37331-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959887700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, L; Sun, SR; Lin, JX; Zhong, L; Chen, LH; Guo, J; Yin, J; Alshareef, HN; Qiu, XQ; Zhang, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lei; Sun, Shirong; Lin, Jinxin; Zhong, Lei; Chen, Liheng; Guo, Jing; Yin, Jian; Alshareef, Husam N.; Qiu, Xueqing; Zhang, Wenli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect Engineering of Disordered Carbon Anodes with Ultra-High Heteroatom Doping Through a Supermolecule-Mediated Strategy for Potassium-Ion Hybrid Capacitors", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Amorphous carbons are promising anodes for high-rate potassium-ion batteries. Most low-temperature annealed amorphous carbons display unsatisfactory capacities. Heteroatom-induced defect engineering of amorphous carbons could enhance their reversible capacities. Nevertheless, most lignocellulose biomasses lack heteroatoms, making it a challenge to design highly heteroatom-doped carbons (> 10 at%). Herein, we report a new preparation strategy for amorphous carbon anodes. Nitrogen/sulfur co-doped lignin-derived porous carbons (NSLPC) with ultra-high nitrogen doping levels (21.6 at% of N and 0.8 at% of S) from renewable lignin biomacromolecule precursors were prepared through a supramolecule-mediated pyrolysis strategy. This supermolecule/lignin composite decomposes forming a covalently bonded graphitic carbon/amorphous carbon intermediate product, which induces the formation of high heteroatom doping in the obtained NSLPC. This unique pyrolysis chemistry and high heteroatom doping of NSLPC enable abundant defective active sites for the adsorption of K+ and improved kinetics. The NSLPC anode delivered a high reversible capacity of 419 mAh g(-1) and superior cycling stability (capacity retention of 96.6% at 1 A g(-1) for 1000 cycles). Potassium-ion hybrid capacitors assembled by NSLPC anode exhibited excellent cycling stability (91% capacity retention for 2000 cycles) and a high energy density of 71 Wh kg(-1) at a power density of 92 W kg(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41, "DOI": "10.1007/s40820-022-01006-0", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-01006-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923130500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, MJ; Wang, CW; Qiang, B; Wang, FK; Ye, M; Han, S; Luo, Y; Wang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Mingjin; Wang, Chongwu; Qiang, Bo; Wang, Fakun; Ye, Ming; Han, Song; Luo, Yu; Wang, Qi Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-chip mid-infrared photothermoelectric detectors for full-Stokes detection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-chip polarimeters are highly desirable for the next-generation ultra-compact optical and optoelectronic systems. Polarization-sensitive photodetectors relying on anisotropic absorption of natural/artificial materials have emerged as a promising candidate for on-chip polarimeters owing to their filterless configurations. However, these photodetectors can only be applied for detection of either linearly or circularly polarized light, not applicable for full-Stokes detection. Here, we propose and demonstrate three-ports polarimeters comprising on-chip chiral plasmonic metamaterial-mediated mid-infrared photodetectors for full-Stokes detection. By manipulating the spatial distribution of chiral metamaterials, we could convert polarization-resolved absorptions to corresponding polarization-resolved photovoltages of three ports through the photothermoelectric effect. We utilize the developed polarimeter in an imaging demonstration showing reliable ability for polarization reconstruction. Our work provides an alternative strategy for developing polarization-resolved photodetectors with a bandgap-independent operation range in the mid-infrared. Mid-infrared polarization-sensitive photodetectors are desired for several applications, such as chemical analysis and biomedical diagnosis. Here, the authors report on-chip polarimeters based on the combination of plasmonic chiral metamaterials and 2D thermoelectric materials, showing tunable full-Stokes detection of linearly and circularly polarized light at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4560, "DOI": "10.1038/s41467-022-32309-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32309-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836609800030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, M; Deng, BW; Zhao, XL; Zhang, ZY; Li, F; Li, KL; Cui, ZH; Kong, LX; Lu, JM; Dong, F; Zhang, LL; Chen, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Ming; Deng, Bangwei; Zhao, Xiaoli; Zhang, Zheye; Li, Fei; Li, Kanglu; Cui, Zhihao; Kong, Lingxuan; Lu, Jianmei; Dong, Fan; Zhang, Lili; Chen, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Template-Sacrificing Synthesis of Well-Defined Asymmetrically Coordinated Single-Atom Catalysts for Highly Efficient CO2 Electrocatalytic Reduction", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although various single-atom catalysts have been designed, atomically engineering their coordination environment remains a great challenge. Herein, a one-pot template-sacrificing pyrolysis approach is developed to synthesize well-defined Ni-N-4-O catalytic sites on highly porous graphitic carbon for electrocatalytic CO2 reduction to CO with high Faradaic efficiency (maximum of 97.2%) in a wide potential window (-0.56 to -1.06 V vs RHE) and with high stability. In-depth experimental and theoretical studies reveal that the axial Ni-O coordination introduces asymmetry to the catalytic center, leading to lower Gibbs free energy for the rate-limiting step, strengthened binding with *COOH, and a weaker association with *CO. The present results demonstrate the successful atomic-level coordination environment engineering of high-surface-area porous graphitic carbon-supported Ni single-atom catalysts (SACs), and the demonstrated method can be applied to synthesize an array of SACs (metal-N-4-O) for various catalysis applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2022, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2110, "End Page": 2119, "Article Number": null, "DOI": "10.1021/acsnullo.1c07746", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.1c07746", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776691400035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cortés, E; Xie, W; Cambiasso, J; Jermyn, AS; Sundararaman, R; Narang, P; Schlücker, S; Maier, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cortes, Emiliano; Xie, Wei; Cambiasso, Javier; Jermyn, Adam S.; Sundararaman, Ravishankar; Narang, Prineha; Schlueker, Sebastian; Maier, Stefan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic hot electron transport drives nullo-localized chemistry", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale localization of electromagnetic fields near metallic nullostructures underpins the fundamentals and applications of plasmonics. The unavoidable energy loss from plasmon decay, initially seen as a detriment, has now expanded the scope of plasmonic applications to exploit the generated hot carriers. However, quantitative understanding of the spatial localization of these hot carriers, akin to electromagnetic near-field maps, has been elusive. Here we spatially map hot-electron-driven reduction chemistry with 15nm resolution as a function of time and electromagnetic field polarization for different plasmonic nullostructures. We combine experiments employing a six-electron photo-recycling process that modify the terminal group of a self-assembled monolayer on plasmonic silver nulloantennas, with theoretical predictions from first-principles calculations of non-equilibrium hot-carrier transport in these systems. The resulting localization of reactive regions, determined by hot-carrier transport from high-field regions, paves the way for improving efficiency in hot-carrier extraction science and nulloscale regio-selective surface chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14880, "DOI": "10.1038/ncomms14880", "DOI Link": "http://dx.doi.org/10.1038/ncomms14880", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397544600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shui, JL; Chen, C; Grabstanowicz, L; Zhao, D; Liu, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shui, Jianglan; Chen, Chen; Grabstanowicz, Lauren; Zhao, Dan; Liu, Di-Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient nonprecious metal catalyst prepared with metal-organic framework in a continuous carbon nullofibrous network", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fuel cell vehicles, the only all-electric technology with a demonstrated >300 miles per fill travel range, use Pt as the electrode catalyst. The high price of Pt creates a major cost barrier for large-scale implementation of polymer electrolyte membrane fuel cells. Nonprecious metal catalysts (NPMCs) represent attractive low-cost alternatives. However, a significantly lower turnover frequency at the individual catalytic site renders the traditional carbon-supported NPMCs inadequate in reaching the desired performance afforded by Pt. Unconventional catalyst design aiming at maximizing the active site density at much improved mass and charge transports is essential for the next-generation NPMC. We report here a method of preparing highly efficient, nullofibrous NPMC for cathodic oxygen reduction reaction by electro-spinning a polymer solution containing ferrous organometallics and zeolitic imidazolate framework followed by thermal activation. The catalyst offers a carbon nullonetwork architecture made of microporous nullofibers decorated by uniformly distributed high-density active sites. In a single-cell test, the membrane electrode containing such a catalyst delivered unprecedented volumetric activities of 3.3 A.cm(-3) at 0.9 V or 450 A.cm(-3) extrapolated at 0.8 V, representing the highest reported value in the literature. Improved fuel cell durability was also observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2015, "Volume": 112, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10629, "End Page": 10634, "Article Number": null, "DOI": "10.1073/pnas.1507159112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1507159112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360005600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, GB; Lu, RH; Li, CZ; Yu, JM; Li, XD; Ni, LM; Zhang, Q; Zhu, GQ; Liu, SW; Zhang, JX; Kramm, UI; Zhao, Y; Wu, G; Xie, J; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Guangbo; Lu, Ruihu; Li, Chenzhao; Yu, Jianmin; Li, Xiaodong; Ni, Lingmei; Zhang, Qi; Zhu, Guangqi; Liu, Shengwen; Zhang, Jiaxu; Kramm, Ulrike. I. I.; Zhao, Yan; Wu, Gang; Xie, Jian; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchically Porous Carbons with Highly Curved Surfaces for Hosting Single Metal FeN4 Sites as Outstanding Oxygen Reduction Catalysts", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron-nitrogen-carbon (Fe-N-C) materials have emerged as a promising alternative to platinum-group metals for catalyzing the oxygen reduction reaction (ORR) in proton-exchange-membrane fuel cells. However, their low intrinsic activity and stability are major impediments. Herein, an Fe-N-C electrocatalyst with dense FeN4 sites on hierarchically porous carbons with highly curved surfaces (denoted as FeN4-hcC) is reported. The FeN4-hcC catalyst displays exceptional ORR activity in acidic media, with a high half-wave potential of 0.85 V (versus reversible hydrogen electrode) in 0.5 m H2SO4. When integrated into a membrane electrode assembly, the corresponding cathode displays a high maximum peak power density of 0.592 W cm(-2) and demonstrates operating durability over 30 000 cycles under harsh H-2/air conditions, outperforming previously reported Fe-N-C electrocatalysts. These experimental and theoretical studies suggest that the curved carbon support fine-tunes the local coordination environment, lowers the energies of the Fe d-band centers, and inhibits the adsorption of oxygenated species, which can enhance the ORR activity and stability. This work provides new insight into the carbon nullostructure-activity correlation for ORR catalysis. It also offers a new approach to designing advanced single-metal-site catalysts for energy-conversion applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 35, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300907", "DOI Link": "http://dx.doi.org/10.1002/adma.202300907", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001020089900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, W; Liu, T; Wu, F; Wang, SJ; Ge, SB; Li, YH; Liu, JL; Ye, HR; Lei, RX; Wang, C; Che, QL; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Wei; Liu, Tong; Wu, Fan; Wang, Shujuan; Ge, Shengbo; Li, Yunhong; Liu, Jinlin; Ye, Haoran; Lei, Ruixin; Wang, Chan; Che, Qiuling; Li, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Antisweat Interference and Highly Sensitive Temperature Sensor Based on Poly(3,4-ethylenedioxythiophene)-Poly(styrenesulfonate) Fiber Coated with Polyurethane/Graphene for Real-Time Monitoring of Body Temperature", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Body temperature is an important indicator of human health. The traditional mercury and medical electronic thermometers have a slow response (>= 1 min) and can not be worn for long to achieve continuous temperature monitoring due to their rigidity. In this work, we prepared a skin-core structure polyurethane (PU)/graphene encapsulated poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) temperature-sensitive fiber in one step by combining wet spinning technology with impregnation technology. The composite fiber has high sensitivity (-1.72%/degrees C), super-resolution (0.1 degrees C), fast time response (17 s), antisweat interference, and high linearity (R-2 = 0.98) in the temperature sensing range of 30-50 degrees C. The fiber is strong enough to be braided into the temperature-sensitive fabric with commercial cotton yarns. The fabric with good comfort and durability can be arranged in the armpit position of the cloth to realize real-time body temperature monitoring without interruption during daily activities. Through Bluetooth wireless transmission, body temperature can be monitored in real-time and displayed on mobile phones to the parents or guardians. Overall, the fiber-based temperature sensor will significantly improve the practical applications of wearable temperature sensors in intelligent medical treatment due to its sensing stability, comfort, and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2023, "Volume": 17, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21073, "End Page": 21082, "Article Number": null, "DOI": "10.1021/acsnullo.3c04246", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.3c04246", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001092753500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SL; Mao, JF; Zhang, Q; Wang, ZJ; Pang, WK; Zhang, L; Du, AJ; Sencadas, OR; Zhang, WC; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Sailin; Mao, Jianfeng; Zhang, Qing; Wang, Zhijie; Pang, Wei Kong; Zhang, Lei; Du, Aijun; Sencadas, Vitor; Zhang, Wenchao; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Intrinsically Non-flammable Electrolyte for High-Performance Potassium Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries are promising for low-cost and large-scale energy storage applications, but the major obstacle to their application is the lack of safe and effective electrolytes. A phosphate-based fire retardant such as triethyl phosphate is now shown to work as a single solvent with potassium bis(fluorosulfonyl)imide at 0.9 m, in contrast to previous Li and Na systems where phosphates cannot work at low concentrations. This electrolyte is optimized at 2 m, where it exhibits the advantages of low cost, low viscosity, and high conductivity, as well as the formation of a uniform and robust salt-derived solid-electrolyte interphase layer, leading to non-dendritic K-metal plating/stripping with Coulombic efficiency of 99.6 % and a highly reversible graphite anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2020, "Volume": 59, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3638, "End Page": 3644, "Article Number": null, "DOI": "10.1002/anie.201913174", "DOI Link": "http://dx.doi.org/10.1002/anie.201913174", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509770000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Lin, BY; Chen, M; Zhao, CX; Tian, H; Qu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qian; Lin, Biyan; Chen, Meng; Zhao, Chengxi; Tian, He; Qu, Da-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A dynamic assembly-induced emissive system for advanced information encryption with time-dependent security", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of advanced materials for information encryption is desirable. Here, the authors report materials that enable orthogonal and temporal encryption of information via dynamic assembly-induced multicolor pyrene-based supramolecular systems. The development of advanced materials for information encryption with time-dependent features is essential to meet the increasing demand on encryption security. Herein, smart materials with orthogonal and temporal encryption properties are successfully developed based on a dynamic assembly-induced multicolour supramolecular system. Multicolour fluorescence, including blue, orange and even white light emissions, is achieved by controlling the supramolecular assembly of pyrene derivatives by tailoring the solvent composition. By taking advantage of the tuneable fluorescence, dynamically controlled information encryption materials with orthogonal encryption functions, e.g., 3D codes, are successfully developed. Moreover, time-dependent information encryption materials, such as temporal multi-information displays and 4D codes, are also developed by enabling the fluorescence-controllable supramolecular system in the solid phase, showing multiple pieces of information on a time scale, and the correct information can be identified only at a specified time. This work provides an inspiring point for the design of information encryption materials with higher security requirements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4185, "DOI": "10.1038/s41467-022-31978-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31978-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828281800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Daglar, H; Gulbalkan, HC; Avci, G; Aksu, GO; Altundal, OF; Altintas, C; Erucar, I; Keskin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Daglar, Hilal; Gulbalkan, Hasan Can; Avci, Gokay; Aksu, Gokhan Onder; Altundal, Omer Faruk; Altintas, Cigdem; Erucar, Ilknur; Keskin, Seda", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Metal-Organic Framework (MOF) Database Selection on the Assessment of Gas Storage and Separation Potentials of MOFs", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of computation-ready metal-organic framework databases (MOF DBs) has accelerated high-throughput computational screening (HTCS) of materials to identify the best candidates for gas storage and separation. These DBs were constructed using structural curations to make MOFs directly usable for molecular simulations, which caused the same MOF to be reported with different structural features in different DBs. We examined thousands of common materials of the two recently updated, very widely used MOF DBs to reveal how structural discrepancies affect simulated CH4, H-2, CO2 uptakes and CH4/H-2 separation performances of MOFs. Results showed that DB selection has a significant effect on the calculated gas uptakes and ideal selectivities of materials at low pressure. A detailed analysis on the curated structures was provided to isolate the critical elements of MOFs determining the gas uptakes. Identification of the top-performing materials for gas separation was shown to strongly depend on the DB used in simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2021, "Volume": 60, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7828, "End Page": 7837, "Article Number": null, "DOI": "10.1002/anie.202015250", "DOI Link": "http://dx.doi.org/10.1002/anie.202015250", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623504200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Sun, Y; Yang, H; Zelezny, J; Parkin, SPP; Felser, C; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yang; Sun, Yan; Yang, Hao; Zelezny, Jakub; Parkin, Stuart P. P.; Felser, Claudia; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong anisotropic anomalous Hall effect and spin Hall effect in the chiral antiferromagnetic compounds Mn3X (X = Ge, Sn, Ga, Ir, Rh, and Pt)", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have carried out a comprehensive study of the intrinsic anomalous Hall effect and spin Hall effect of several chiral antiferromagnetic compounds Mn3X (X = Ge, Sn, Ga, Ir, Rh and Pt) by ab initio band structure and Berry phase calculations. These studies reveal large and anisotropic values of both the intrinsic anomalous Hall effect and spin Hall effect. The Mn3X materials exhibit a noncollinear antiferromagnetic order which, to avoid geometrical frustration, forms planes of Mn moments that are arranged in a Kagome-type lattice. With respect to these Kagome planes, we find that both the anomalous Hall conductivity (AHC) and the spin Hall conductivity (SHC) are quite anisotropic for any of these materials. Based on our calculations, we propose how to maximize AHC and SHC for different materials. The band structures and corresponding electron filling, that we show are essential to determine the AHC and SHC, are compared for these different compounds. We point out that Mn3Ga shows a large SHC of about 600 (h/e)(Omega cm)(-1). Our work provides insights into the realization of strong anomalous Hall effects and spin Hall effects in chiral antiferromagnetic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2017, "Volume": 95, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75128, "DOI": "10.1103/PhysRevB.95.075128", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.075128", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393943600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bischak, CG; Hetherington, CL; Wu, H; Aloni, S; Ogletree, DF; Limmer, DT; Ginsberg, NS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bischak, Connor G.; Hetherington, Craig L.; Wu, Hao; Aloni, Shaul; Ogletree, D. Frank; Limmer, David T.; Ginsberg, Naomi S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The distinct physical properties of hybrid organic inorganic materials can lead to unexpected non equilibrium phenomena that are difficult to characterize due to the broad range of length and time scales involved. For instance, mixed halide hybrid perovskites are promising materials for optoelectronics, yet bulk measurements suggest the halides reversibly phase separate upon photoexcitation. By combining nulloscale imaging and multiscale modeling, we find that the nature of halide demixing in these materials is distinct from macroscopic phase separation. We propose that the localized strain induced by a single photoexcited charge interacting with the soft, ionic lattice is sufficient to promote halide phase separation and nucleate a light-stabilized, low-bandgap, similar to 8 mm iodide-rich cluster. The limited extent of this polaron is essential to promote demixing because by contrast bulk strain would simply be relaxed. Photoinduced phase separation is therefore a consequence of the unique electromechanical properties of this hybrid class of materials. Exploiting photoinduced phase separation and other nonequilibrium phenomena in hybrid materials more generally could expand applications in sensing, switching, memory, and energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 579, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1028, "End Page": 1033, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b04453", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b04453", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393848800060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Meng, ZN; Zhu, H; Wang, YL; Peng, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, P.; Meng, Z. N.; Zhu, H.; Wang, Y. L.; Peng, S. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Melting heat transfer characteristics of a composite phase change material fabricated by paraffin and metal foam", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Paraffin has a great potential as the phase change material (PCM) to be applied in many energy-related applications, such as thermal energy storage and thermal management, due to its appropriate phase change temperature and large latent heat. The heat transfer characteristics during phase change of paraffin play a very important role in determining the thermo-fluidic performance of the systems. However, the drawback of small thermal conductivity of PCM hampers its application. In the present study, the composite PCM was fabricated by using copper foam to enhance the thermal conductivity of paraffin, and an experimental setup was built to study the phase change heat transfer characteristics of composite PCM. The evolvement of solid-liquid interface and temperature variation during the melting process were experimentally investigated, and the experimental results were compared with the numerical results obtained by the two-temperature energy model. It was indicated that there was a quite large temperature difference between the ligament of copper foam and paraffin, which was due to the thermal non-equilibrium effect in heat transfer between the paraffin and copper foam. Good agreement between the experimental and numerical results showed that the heat transfer characteristics could be well depicted by the two-temperature energy model, which can be further used to depict the heat transfer in thermal energy storage or temperature management using composite PCM. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2017, "Volume": 185, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1971, "End Page": 1983, "Article Number": null, "DOI": "10.1016/j.apenergy.2015.10.075", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2015.10.075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390494800099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Yang, F; Suh, J; Yang, SJ; Lee, Y; Li, G; Choe, HS; Suslu, A; Chen, YB; Ko, C; Park, J; Liu, K; Li, JB; Hippalgaonkar, K; Urban, JJ; Tongay, S; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Sangwook; Yang, Fan; Suh, Joonki; Yang, Sijie; Lee, Yeonbae; Li, Guo; Choe, Hwan Sung; Suslu, Aslihan; Chen, Yabin; Ko, Changhyun; Park, Joonsuk; Liu, Kai; Li, Jingbo; Hippalgaonkar, Kedar; Urban, Jeffrey J.; Tongay, Sefaattin; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic in-plane thermal conductivity of black phosphorus nulloribbons at temperatures higher than 100 K", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus attracts enormous attention as a promising layered material for electronic, optoelectronic and thermoelectric applications. Here we report large anisotropy in in-plane thermal conductivity of single-crystal black phosphorus nulloribbons along the zigzag and armchair lattice directions at variable temperatures. Thermal conductivity measurements were carried out under the condition of steady-state longitudinal heat flow using suspended-pad micro-devices. We discovered increasing thermal conductivity anisotropy, up to a factor of two, with temperatures above 100 K. A size effect in thermal conductivity was also observed in which thinner nulloribbons show lower thermal conductivity. Analysed with the relaxation time approximation model using phonon dispersions obtained based on density function perturbation theory, the high anisotropy is attributed mainly to direction-dependent phonon dispersion and partially to phonon-phonon scattering. Our results revealing the intrinsic, orientation-dependent thermal conductivity of black phosphorus are useful for designing devices, as well as understanding fundamental physical properties of layered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8573, "DOI": "10.1038/ncomms9573", "DOI Link": "http://dx.doi.org/10.1038/ncomms9573", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364932600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kanakaraju, D; Chandrasekaran, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kanakaraju, Devagi; Chandrasekaran, Aneshaa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances in TiO2/ZnS-based binary and ternary photocatalysts for the degradation of organic pollutants", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor-mediated photocatalysis plays a pivotal role in the elimination of organic pollutants from water systems. Titanium dioxide (TiO2) and zinc sulphide (ZnS) semiconductors are commonly utilized as photocatalysts in water purification due to their physical and chemical stability and also large band gap. The drawbacks of both semiconductors, nevertheless, prevent them from being used in real and large-scale treatments. Therefore, binary and ternary-based TiO2/ZnS nullostructured materials may be a promising solution to improve the quantum efficiency, structural, and electrical features of pure TiO2 and ZnS semiconductors for improved photoefficiency. This review aims to unravel the development of binary TiO2/ZnS and the modification of ternary photocatalysts (TiO2/ZnS-X, X = metal, non-metal, and dye sensitization) by various approaches. The engineered TiO2/ZnS-based ternary nullostructured materials have exhibited exceptional performance to accelerate the degradation of organic pollutants in wastewater. These materials were fabricated by modifying TiO2/ZnS binary composite and embedding co-catalysts like carbonaceous material, polymeric material, transition metal, metal oxide, and metal. The relationship between the properties of the resulting nullomaterials and their photocatalytic performances has been examined. This review has also placed a special focus on the synthetic routes applied to derive the binary and ternary TiO2/ZnS composites. Another aim of this review is to scrutinize the factors that influence the performance of binary and ternary-based TiO2/ZnS composites on the degradation of organic pollutants. Opportunities for further investigation have been also outlined, along with limitations and impediments based on the current findings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2023, "Volume": 868, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 161525, "DOI": "10.1016/j.scitotenv.2023.161525", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2023.161525", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921020400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, XY; Zhao, J; Li, XN; Shao, JM; Pan, BB; Salamé, A; Boutin, E; Groizard, T; Wang, SF; Ding, J; Zhang, X; Huang, WY; Zeng, WJ; Liu, CY; Li, YG; Hung, SF; Huang, YQ; Robert, M; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xinyi; Zhao, Jian; Li, Xuning; Shao, Junming; Pan, Binbin; Salame, Aude; Boutin, Etienne; Groizard, Thomas; Wang, Shifu; Ding, Jie; Zhang, Xiong; Huang, Wen-Yang; Zeng, Wen-Jing; Liu, Chengyu; Li, Yanguang; Hung, Sung-Fu; Huang, Yanqiang; Robert, Marc; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While exploring the process of CO/CO2 electroreduction (COxRR) is of great significance to achieve carbon recycling, deciphering reaction mechanisms so as to further design catalytic systems able to overcome sluggish kinetics remains challenging. In this work, a model single-Co-atom catalyst with well-defined coordination structure is developed and employed as a platform to unravel the underlying reaction mechanism of COxRR. The as-prepared single-Co-atom catalyst exhibits a maximum methanol Faradaic efficiency as high as 65% at 30mA/cm(2) in a membrane electrode assembly electrolyzer, while on the contrary, the reduction pathway of CO2 to methanol is strongly decreased in CO2RR. In-situ X-ray absorption and Fourier-transform infrared spectroscopies point to a different adsorption configuration of *CO intermediate in CORR as compared to that in CO2RR, with a weaker stretching vibration of the C-O bond in the former case. Theoretical calculations further evidence the low energy barrier for the formation of a H-CoPc-CO- species, which is a critical factor in promoting the electrochemical reduction of CO to methanol. Deciphering the reaction mechanisms of CO/CO2 electroreduction to methanol remains challenging. Here the authors report the higher electron density of single-Co-atom center, along with a different adsorption configuration of *CO, is crucial for promoting the CO electroreduction to methanol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3401, "DOI": "10.1038/s41467-023-39153-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39153-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026289800041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Gong, LQ; Wang, HM; Dong, CL; Wang, JL; Qi, K; Liu, HF; Guo, XP; Xia, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Huan; Gong, Lanqian; Wang, Hongming; Dong, Chungli; Wang, Junlei; Qi, Kai; Liu, Hongfang; Guo, Xingpeng; Xia, Bao Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of nickel-iron hydroxides by microorganism corrosion for efficient oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel-iron composites are efficient in catalyzing oxygen evolution. Here, we develop a microorganism corrosion approach to construct nickel-iron hydroxides. The anaerobic sulfate-reducing bacteria, using sulfate as the electron acceptor, play a significant role in the formation of iron sulfide decorated nickel-iron hydroxides, which exhibit excellent electrocatalytic performance for oxygen evolution. Experimental and theoretical investigations suggest that the synergistic effect between oxyhydroxides and sulfide species accounts for the high activity. This microorganism corrosion strategy not only provides efficient candidate electrocatalysts but also bridges traditional corrosion engineering and emerging electrochemical energy technologies. Developing facile strategies to realize the precise construction of Ni-Fe structures is of significance for water oxidation. Here, the authors demonstrate a universal microorganism-assisted corrosion strategy for preparing highly efficient Ni-Fe composites towards oxygen evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 8", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5075, "DOI": "10.1038/s41467-020-18891-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18891-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000581918200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, MM; Zhang, ZJ; Xu, WH; Wen, HF; Zhu, W; Wu, Q; Wu, HZ; Gong, JY; Wang, ZJ; Wang, D; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Miaomiao; Zhang, Zhijun; Xu, Wenhan; Wen, Haifei; Zhu, Wei; Wu, Qian; Wu, Hongzhuo; Gong, Junyi; Wang, Zhijia; Wang, Dong; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Good Steel Used in the Blade: Well-Tailored Type-I Photosensitizers with Aggregation-Induced Emission Characteristics for Precise Nuclear Targeting Photodynamic Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photodynamic therapy (PDT) has long been recognized to be a promising approach for cancer treatment. However, the high oxygen dependency of conventional PDT dramatically impairs its overall therapeutic efficacy, especially in hypoxic solid tumors. Exploration of distinctive PDT strategy involving both high-performance less-oxygen-dependent photosensitizers (PSs) and prominent drug delivery system is an appealing yet significantly challenging task. Herein, a precise nuclear targeting PDT protocol based on type-I PSs with aggregation-induced emission (AIE) characteristics is fabricated for the first time. Of the two synthesized AIE PSs, TTFMN is demonstrated to exhibit superior AIE property and stronger type-I reactive oxygen species (ROS) generation efficiency owing to the introduction of tetraphenylethylene and smaller singlet-triplet energy gap, respectively. With the aid of a lysosomal acid-activated TAT-peptide-modified amphiphilic polymer poly(lactic acid)12k-poly(ethylene glycol)5k-succinic anhydride-modified TAT, the corresponding TTFMN-loaded nulloparticles accompanied with acid-triggered nuclear targeting peculiarity can quickly accumulate in the tumor site, effectively generate type-I ROS in the nuclear region and significantly suppress the tumor growth under white light irradiation with minimized systematic toxicity. This delicate Good Steel Used in the Blade tactic significantly maximizes the PDT efficacy and offers a conceptual while practical paradigm for optimized cancer treatment in further translational medicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100524, "DOI": "10.1002/advs.202100524", "DOI Link": "http://dx.doi.org/10.1002/advs.202100524", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652757100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Estakhri, NM; Edwards, B; Engheta, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Estakhri, Nasim Mohammadi; Edwards, Brian; Engheta, Nader", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverse-designed metastructures that solve equations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metastructures hold the potential to bring a new twist to the field of spatial-domain optical analog computing: migrating from free-space and bulky systems into conceptually wavelength-sized elements. We introduce a metamaterial platform capable of solving integral equations using monochromatic electromagnetic fields. For an arbitrary wave as the input function to an equation associated with a prescribed integral operator, the solution of such an equation is generated as a complex-valued output electromagnetic field. Our approach is experimentally demonstrated at microwave frequencies through solving a generic integral equation and using a set of waveguides as the input and output to the designed metastructures. By exploiting subwavelength-scale light-matter interactions in a metamaterial platform, our wave-based, material-based analog computer may provide a route to achieve chip-scale, fast, and integrable computing elements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 363, "Issue": 6433, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1333, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw2498", "DOI Link": "http://dx.doi.org/10.1126/science.aaw2498", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462016400051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jauregui, LA; Joe, AY; Pistunova, K; Wild, DS; High, AA; Zhou, Y; Scuri, G; De Greve, K; Sushko, A; Yu, CH; Taniguchi, T; Watanabe, K; Needleman, DJ; Lukin, MD; Park, H; Kim, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jauregui, Luis A.; Joe, Andrew Y.; Pistunova, Kateryna; Wild, Dominik S.; High, Alexander A.; Zhou, You; Scuri, Giovanni; De Greve, Kristiaan; Sushko, Andrey; Yu, Che-Hang; Taniguchi, Takashi; Watanabe, Kenji; Needleman, Daniel J.; Lukin, Mikhail D.; Park, Hongkun; Kim, Philip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical control of interlayer exciton dynamics in atomically thin heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A van der Waals heterostructure built from atomically thin semiconducting transition metal dichalcogenides (TMDs) enables the formation of excitons from electrons and holes in distinct layers, producing interlayer excitons with large binding energy and a long lifetime. By employing heterostructures of monolayer TMDs, we realize optical and electrical generation of long-lived neutral and charged interlayer excitons. We demonstrate that neutral interlayer excitons can propagate across the entire sample and that their propagation can be controlled by excitation power and gate electrodes. We also use devices with ohmic contacts to facilitate the drift motion of charged interlayer excitons. The electrical generation and control of excitons provide a route for achieving quantum manipulation of bosonic composite particles with complete electrical tunability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 366, "Issue": 6467, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 870, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw4194", "DOI Link": "http://dx.doi.org/10.1126/science.aaw4194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496946200053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kante, MV; Weber, ML; Ni, S; van den Bosch, ICG; van der Minne, E; Heymann, L; Falling, LJ; Gauquelin, N; Tsvetanova, M; Cunha, DM; Koster, G; Gunkel, F; Nemsák, S; Hahn, H; Estrada, LV; Baeumer, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kante, Mohana, V; Weber, Moritz L.; Ni, Shu; van den Bosch, Iris C. G.; van der Minne, Emma; Heymann, Lisa; Falling, Lorenz J.; Gauquelin, Nicolas; Tsvetanova, Martina; Cunha, Daniel M.; Koster, Gertjan; Gunkel, Felix; Nemsak, Slavomir; Hahn, Horst; Estrada, Leonardo Velasco; Baeumer, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A High-Entropy Oxide as High-Activity Electrocatalyst for Water Oxidation", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy materials are an emerging pathway in the development of high-activity (electro)catalysts because of the inherent tunability and coexistence of multiple potential active sites, which may lead to earth-abundant catalyst materials for energy-efficient electrochemical energy storage. In this report, we identify how the multication composition in high-entropy perovskite oxides (HEO) contributes to high catalytic activity for the oxygen evolution reaction (OER), i.e., the key kinetically limiting half-reaction in several electrochemical energy conversion technologies, including green hydrogen generation. We compare the activity of the (001) facet of LaCr0.2Mn0.2Fe0.2Co0.2Ni0.2O3-delta with the parent compounds (single B-site in the ABO3 perovskite). While the single B-site perovskites roughly follow the expected volcano-type activity trends, the HEO clearly outperforms all of its parent compounds with 17 to 680 times higher currents at a fixed overpotential. As all samples were grown as an epitaxial layer, our results indicate an intrinsic composition-function relationship, avoiding the effects of complex geometries or unknown surface composition. In-depth X-ray photoemission studies reveal a synergistic effect of simultaneous oxidation and reduction of different transition metal cations during the adsorption of reaction intermediates. The surprisingly high OER activity demonstrates that HEOs are a highly attractive, earth-abundant material class for high-activity OER electrocatalysts, possibly allowing the activity to be fine-tuned beyond the scaling limits of mono-or bimetallic oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2023, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5329, "End Page": 5339, "Article Number": null, "DOI": "10.1021/acsnullo.2c08096", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c08096", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953440900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kharel, P; Reimer, C; Luke, K; He, LY; Zhang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kharel, Prashanta; Reimer, Christian; Luke, Kevin; He, Lingyan; Zhang, Mian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking voltage-bandwidth limits in integrated lithium niobate modulators using micro-structured electrodes", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electro-optic modulators with low voltages and large bandwidths are crucial for both analog and digital communication. Recently, thin-film lithium niobate modulators have emerged as a strong candidate for next generation electro-optic solutions. These modulators offer significantly improved voltage-bandwidth performances over the existing bulk lithium niobate modulators while preserving key material advantages such as linear response, high extinction ratio, high optical power handling ability, and low optical losses. However, reduced electrode gaps in miniaturized thin-film modulators lead to higher microwave losses, which limit electro-optic performances at high frequencies. Here we overcome this limitation to achieve a record combination of low RF half-wave voltage (V-pi) of 1.3 V while maintaining electro-optic response with 1.8 dB roll-off at 50 GHz using micro-structured electrodes. Our demonstration represents a significant improvement in voltage-bandwidth performance, one that is comparable to the performance gain in switching from legacy bulk to thin-film lithium niobate modulators. Such a micro-structured electrode design could enable sub-volt modulators with >100 GHz bandwidth. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2021, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 357, "End Page": 363, "Article Number": null, "DOI": "10.1364/OPTICA.416155", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.416155", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631516600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, Y; Yao, HF; Hong, L; Zhang, T; Tang, YB; Lin, BJ; Xian, KH; Gao, BW; An, CB; Bi, PQ; Ma, W; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Yong; Yao, Huifeng; Hong, Ling; Zhang, Tao; Tang, Yabing; Lin, Baojun; Xian, Kaihu; Gao, Bowei; An, Cunbin; Bi, Pengqing; Ma, Wei; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic photovoltaic cell with 17% efficiency and superior processability", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of organic photoactive materials, especially the newly emerging non-fullerene electron acceptors (NFAs), has enabled rapid progress in organic photovoltaic (OPV) cells in recent years. Although the power conversion efficiencies (PCEs) of the top-performance OPV cells have surpassed 16%, the devices are usually fabricated via a spin-coating method and are not suitable for large-area production. Here, we demonstrate that the fine-modification of the flexible side chains of NFAs can yield 17% PCE for OPV cells. More crucially, as the optimal NFA has a suitable solubility and thus a desirable morphology, the high efficiencies of spin-coated devices can be maintained when using scalable blade-coating processing technology. Our results suggest that optimization of the chemical structures of the OPV materials can improve device performance. This has great significance in larger-area production technologies that provide important scientific insights for the commercialization of OPV cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 472, "Times Cited, All Databases": 481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1239, "End Page": 1246, "Article Number": null, "DOI": "10.1093/nsr/nwz200", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwz200", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572865000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Wu, ZF; Guo, CJ; Guo, HM; Su, YG; Chen, Q; Sun, CG; Liu, QM; Chen, DQ; Mu, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xue; Wu, Zhenfeng; Guo, Chunjing; Guo, Huimin; Su, Yanguo; Chen, Qiang; Sun, Changgang; Liu, Qingming; Chen, Daquan; Mu, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hypoxia responsive nullo-drug delivery system based on angelica polysaccharide for liver cancer therapy", "Source Title": "DRUG DELIVERY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on the tumor hypoxic microenvironment and the new programmed cell death mode of combined ferroptosis, an angelica polysaccharide-based nullocarrier material was synthesized. The polymer contains hydrophilic angelica polysaccharide (ASP) that is linked by azobenzene (AZO) linker with ferrocene (Fc), and then the side chain was covalently modified with arachidonic acid (AA). It was postulated that the polymer micelles could work as an instinctive liver targeting drug delivery carrier, owing to the existence of ASP with liver targeting. Moreover, the aim was to engineer hypoxia-responsive polymer micelles which was modified by AA, for selective enhancement of ferroptosis in solid tumor, via diminishing glutathione (GSH) under hypoxia. Finally, we synthesized the amphiphilic polymer micelles AA/ASP-AZO-Fc (AAAF) by self-assembling. The structure of AAAF was confirmed by H-1-NMR and FT-IR. Then, we exemplified the hydrophobic medication curcumin into polymer micelles AAAF@Cur, which has smooth and regular spheres. In vitro release test affirmed that AAAF@Cur can achieve hypoxia response to drug release. In addition, a series of cell experiments confirmed that hypoxia could enhance cell uptake and effectively improve the proliferation inhibitory activity of HepG2 cells. In conclusion, AAAF, as an effective cell carrier, is expected to develop in sensitizing ferroptosis and anti-tumor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 31", "Publication Year": 2022, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 138, "End Page": 148, "Article Number": null, "DOI": "10.1080/10717544.2021.2021324", "DOI Link": "http://dx.doi.org/10.1080/10717544.2021.2021324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000736474800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Li, HZ; Yu, WW; Elezzabi, AY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wu; Li, Haizeng; Yu, William W.; Elezzabi, Abdulhakem Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent inorganic multicolour displays enabled by zinc-based electrochromic devices", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochromic displays have been the subject of extensive research as a promising colour display technology. The current state-of-the-art inorganic multicolour electrochromic displays utilize nullocavity structures that sacrifice transparency and thus limit their diverse applications. Herein, we demonstrate a transparent inorganic multicolour display platform based on Zn-based electrochromic devices. These devices enable independent operation of top and bottom electrochromic electrodes, thus providing additional configuration flexibility of the devices through the utilization of dual electrochromic layers under the same or different colour states. Zn-sodium vanadium oxide (Zn-SVO) electrochromic displays were assembled by sandwiching Zn between two SVO electrodes, and they could be reversibly switched between multiple colours (orange, amber, yellow, brown, chartreuse and green) while preserving a high optical transparency. These Zn-SVO electrochromic displays represent the most colourful transparent inorganic-based electrochromic displays to date. In addition, the Zn-SVO electrochromic displays possess an open-circuit potential (OCP) of 1.56V, which enables a self-colouration behaviour and compelling energy retrieval functionality. This study presents a new concept integrating high transparency and high energy efficiency for inorganic multicolour displays. Electrochromic displays: superior colourTransparent electrochromic displays with a richer colour palette are now possible. Electrochromic displays, which change their colour due to electrochemistry, are receiving interest due to their low power consumption but a lack of colours is problematic. Wu Zhang and coworkers from the University of Alberta in Canada and Louisiana State University in the USA fabricated multicolour displays using sodium ion stabilized vanadium oxide nullorods (Zn-SVO) as the electrochromic material. Two layers of this material, separated by a layer of zinc and a gel electrolyte were sandwiched between glass coated with indium tin oxide. Application of a small voltage causes the SVO film to exhibit a reversible switch between orange, yellow and green. The use of two independently-controlled films in the display provides a broader range of colours (orange, amber, yellow, brown, chartreuse and green).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121, "DOI": "10.1038/s41377-020-00366-9", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-00366-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000553171800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, TE; Peng, LC; Liang, JH; Hallal, A; Yasin, FS; Zhang, XC; Song, KM; Kim, SJ; Kim, K; Weigand, M; Schütz, G; Finizio, S; Raabe, J; Garcia, K; Xia, J; Zhou, Y; Ezawa, M; Liu, XX; Chang, J; Koo, HC; Kim, YD; Chshiev, M; Fert, A; Yang, HX; Yu, XZ; Woo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Tae-Eon; Peng, Licong; Liang, Jinghua; Hallal, Ali; Yasin, Fehmi Sami; Zhang, Xichao; Song, Kyung Mee; Kim, Sung Jong; Kim, Kwangsu; Weigand, Markus; Schutz, Gisela; Finizio, Simone; Raabe, Jorg; Garcia, Karin; Xia, Jing; Zhou, Yan; Ezawa, Motohiko; Liu, Xiaoxi; Chang, Joonyeon; Koo, Hyun Cheol; Kim, Young Duck; Chshiev, Mairbek; Fert, Albert; Yang, Hongxin; Yu, Xiuzhen; Woo, Seonghoon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neel-type skyrmions and their current-induced motion in van der Waals ferromagnet-based heterostructures", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the discovery of ferromagnetic two-dimensional (2D) van der Waals (vdW) crystals, significant interest on such 2D magnets has emerged, inspired by their appealing physical properties and integration with other 2D family for unique heterostructures. In known 2D magnets, spin-orbit coupling (SOC) stabilizes perpendicular magnetic anisotropy down to one or a few monolayers. Such a strong SOC could also lift the chiral degeneracy, leading to the formation of topological magnetic textures such as skyrmions through the Dzyaloshinskii-Moriya interaction (DMI). Here, we report the experimental observation of Neel-type chiral magnetic skyrmions and their lattice (SkX) formation in a vdW ferromagnet Fe3GeTe2 (FGT). We demonstrate the ability to drive an individual skyrmion by short current pulses along a vdW heterostructure, FGT/h-BN, as highly required for any skyrmion-based spintronic device. Using first principle calculations supported by experiments, we unveil the origin of DMI being the interfaces with oxides, which then allows us to engineer vdW heterostructures for desired chiral states. Our finding opens the door to topological spin textures in the 2D vdW magnet and their potential device application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2021, "Volume": 103, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104410, "DOI": "10.1103/PhysRevB.103.104410", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.103.104410", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627551900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, T; Han, Y; Fraggedakis, D; Das, S; Zhou, TT; Yeh, CN; Xu, SM; Chueh, WC; Li, J; Bazant, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Tao; Han, Yu; Fraggedakis, Dimitrios; Das, Supratim; Zhou, Tingtao; Yeh, Che-Ning; Xu, Shengming; Chueh, William C.; Li, Ju; Bazant, Martin Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interplay of Lithium Intercalation and Plating on a Single Graphite Particle", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving safety while increasing the charging rates and extending the lifetime is the grand challenge for lithium-ion batteries. The key challenge is to control lithium plating, a parasitic reaction on graphite anodes that competes with lithium intercalation. Here, we determine the fundamental mechanism for the onset of lithium plating on graphite particles. We perform in situ optical microscopy coupled with electrochemical measurements to resolve the spatial dynamics of lithiation and plating on the surface of a single graphite particle. We observe that the onset of plating is strongly coupled with phase separation in graphite and occurs only on the fully lithiated edges of the particles. The competition between Li insertion and plating is further elucidated by examining the energetics and kinetics of both reactions. Based on the physical insights drawn from the experiments, we propose a phase-field model that predicts the onset of Li plating.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 393, "End Page": 414, "Article Number": null, "DOI": "10.1016/j.joule.2020.12.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.12.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629204800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nadell, CC; Huang, BH; Malof, JM; Padilla, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nadell, Christian C.; Huang, Bohao; Malof, Jordan M.; Padilla, Willie J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep learning for accelerated all-dielectric metasurface design", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep learning has risen to the forefront of many fields in recent years, overcoming challenges previously considered intractable with conventional means. Materials discovery and optimization is one such field, but significant challenges remain, including the requirement of large labeled datasets and one-to-many mapping that arises in solving the inverse problem. Here we demonstrate modeling of complex all-dielectric metasurface systems with deep neural networks, using both the metasurface geometry and knowledge of the underlying physics as inputs. Our deep learning network is highly accurate, achieving an average mean square error of only 1.16 x 10(-3) and is over five orders of magnitude faster than conventional electromagnetic simulation software. We further develop a novel method to solve the inverse modeling problem, termed fast forward dictionary search (FFDS), which offers tremendous controls to the designer and only requires an accurate forward neural network model. These techniques significantly increase the viability of more complex all-dielectric metasurface designs and provide opportunities for the future of tailored light matter interactions. (C) 2019 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2019, "Volume": 27, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 27523, "End Page": 27535, "Article Number": null, "DOI": "10.1364/OE.27.027523", "DOI Link": "http://dx.doi.org/10.1364/OE.27.027523", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488282800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, JY; Liu, TY; Zhao, YH; Yang, RO; Zhao, Y; Wang, WB; Liu, YW; Li, HQ; Li, YF; Zhai, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Junyuan; Liu, Tianyang; Zhao, Yinghe; Yang, Ruoou; Zhao, Yang; Wang, Wenbin; Liu, Youwen; Li, Huiqiao; Li, Yafei; Zhai, Tianyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active and conductive layer stacked superlattices for highly selective CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal oxides are archetypal CO2 reduction reaction electrocatalysts, yet inevitable self-reduction will enhance competitive hydrogen evolution and lower the CO2 electroreduction selectivity. Herein, we propose a tangible superlattice model of alternating metal oxides and selenide sublayers in which electrons are rapidly exported through the conductive metal selenide layer to protect the active oxide layer from self-reduction. Taking BiCuSeO superlattices as a proof-of-concept, a comprehensive characterization reveals that the active [Bi2O2](2+) sublayers retain oxidation states rather than their self-reduced Bi metal during CO2 electroreduction because of the rapid electron transfer through the conductive [Cu2Se2](2-) sublayer. Theoretical calculations uncover the high activity over [Bi2O2](2+) sublayers due to the overlaps between the Bi p orbitals and O p orbitals in the OCHO* intermediate, thus achieving over 90% formate selectivity in a wide potential range from -0.4 to -1.1 V. This work broadens the studying and improving of the CO2 electroreduction properties of metal oxide systems. It is important yet challenging to improve the interface contact between commonly used carbon conductive layer and metal oxide catalysts. Here the authors propose BiCuSeO with alternullt active [Bi2O2](2+) sublayers and conductive [Cu2Se2](2-) sublayer within its superlattice as efficient catalyst for CO2 electroreduction to formate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2039, "DOI": "10.1038/s41467-022-29699-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29699-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784997300061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, TL; Troiani, HE; Mogni, LV; Han, MF; Barnett, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Tenglong; Troiani, Horacio E.; Mogni, Liliana, V; Han, Minfang; Barnett, Scott A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni-Substituted Sr(Ti,Fe)O3 SOFC Anodes: Achieving High Performance via Metal Alloy nulloparticle Exsolution", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrically conducting oxides have been proposed as alternatives to Ni-based cermet anodes for solid oxide fuel cells (SOFCs) to overcome issues such as coking and impurity poisoning, but their electrochemical performance is typically inferior to that of Ni-based cermets. Here we show that a new oxide composition, Sr-0.95(Ti0.3Fe0.63Ni0.07)O3-delta, yields anode polarization resistance competitive with Ni cermets, and substantially better than that of the corresponding Ni-free compound, SrTi0.3Fe0.7O3-delta. Exposure to fuel results in exso-lution and nucleation of Ni0.5Fe0.5 nulloparticles uniformly dispersed on the Ni-substituted perovskite surface, whereas no nulloparticles are observed on SrTi0.3Fe0.7O3-delta. A general thermodynamic model is developed that quantitatively predicts exsolved nulloparticle composition. The reduction in anode polarization resistance by the nulloparticles, by as much as 4 times, is most pronounced at cell operating temperatures below 800 degrees C and low H-2 partial pressures, suggesting that the nulloparticles improve performance by promoting H-2 adsorption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2018, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 478, "End Page": 496, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435091500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motealleh, B; Liu, ZC; Masel, RI; Sculley, JP; Ni, ZR; Meroueh, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motealleh, Behrooz; Liu, Zengcai; Masel, Rich, I; Sculley, Julian P.; Ni, Zheng Richard; Meroueh, Laureen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Next-generation anion exchange membrane water electrolyzers operating for commercially relevant lifetimes", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkaline anion exchange membrane (AEM) water electrolysis has gained increasing attention due to its potential to achieve low-cost, high performance hydrogen production. However, most existing membranes are not durable in industrial settings. Here, we demonstrate good performance relative to industrial parameters using Sustainion (R) anion exchange membranes. Long-duration tests showed stable performance of 1 A/cm(2) at 1.85 V with a degradation rate of less than 1 mu V/h over 10,000 h. The projected lifetime is thus over 20 years. Daily on/off cycling performance over the course of 30 years was simulated experimentally through accelerated voltage shock tests, resulting in a performance loss of only 0.15 mu V/cycle over 11,000 cycles. As shown through impact and crossover testing, an improvement in performance is achieved by the addition of zirconia to the polymer matrix and mechanically reinforcing the membrane. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2021, "Volume": 46, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3379, "End Page": 3386, "Article Number": null, "DOI": "10.1016/j.ijhydene.2020.10.244", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2020.10.244", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607474700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Favaro, M; Yang, JH; Nappini, S; Magnullo, E; Toma, FM; Crumlin, EJ; Yano, J; Sharp, ID", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Favaro, Marco; Yang, Jinhui; Nappini, Silvia; Magnullo, Elena; Toma, Francesca M.; Crumlin, Ethan J.; Yano, Junko; Sharp, Ian D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the Oxygen Evolution Reaction Mechanism on CoOx using Operando Ambient-Pressure X-ray Photoelectron Spectroscopy", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical water splitting is a promising approach for renewable production of hydrogen from solar energy and requires interfacing advanced water-splitting catalysts, with semiconductors. Understanding the mechanism of function of such electrocatalysts at the atomic scale and under realistic working conditions is a challenging, yet important, task for advancing efficient and stable function. This is particularly true for the case of oxygen evolution catalysts and, here, we study a highly active Co3O4/Co(OH)(2) biphasic electrocatalyst on Si by means of operando ambient-pressure X-ray photoelectron spectroscopy performed at the solid/liquid electrified interface. Spectral simulation and multiplet fitting reveal that the catalyst undergoes chemical-structural transformations as a function of the applied anodic potential, with complete conversion of the Co(OH)(2) and partial conversion of the spinel Co3O4 phases to CoO(OH) under precatalytic electrochemical conditions. Furthermore, we observe new spectral features in both Co 2p and O 1s core-level regions to emerge under oxygen evolution reaction conditions on CoO(OH). The operando photoelectron spectra support assignment of these newly observed features to highly active Co4+ centers under catalytic conditions. Comparison of these results to those from a pure phase spinel Co3O4 catalyst supports this interpretation and reveals that the presence of Co(OH)(2) enhances catalytic activity by promoting transformations to CoO(OH). The direct investigation of electrified interfaces presented in this work can be extended to different materials under realistic catalytic conditions, thereby providing a powerful tool for mechanism discovery and an enabling capability for catalyst design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2017, "Volume": 139, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8960, "End Page": 8970, "Article Number": null, "DOI": "10.1021/jacs.7b03211", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b03211", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405158900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reizer, E; Viskolcz, B; Fiser, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reizer, Edina; Viskolcz, Bela; Fiser, Bela", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation and growth mechanisms of polycyclic aromatic hydrocarbons: A mini-review", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polycyclic aromatic hydrocarbons (PAHs) are mostly formed during the incomplete combustion of organic materials, but their importance and presence in materials science, and astrochemistry has also been proven. These carcinogenic persistent organic pollutants are essential in the formation of combustion generated particles as well. Due to their significant impact on the environment and human health, to understand the formation and growth of PAHs is essential. Therefore, the most important growth mechanisms are reviewed, and presented here from the past four decades (1981-2021) to initiate discussions from a new perspective. Although, the collected and analyzed observations are derived from both experimental, and computational studies, it is neither a systematic nor a comprehensive review. Nevertheless, the mechanisms were divided into three main categories, acetylene additions (e.g. HACA), vinylacetylene additions (HAVA), and radical reactions, and discussed accordingly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 291, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 132793, "DOI": "10.1016/j.chemosphere.2021.132793", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2021.132793", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757883700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benduhn, J; Tvingstedt, K; Piersimoni, F; Ullbrich, S; Fan, YL; Tropiano, M; McGarry, KA; Zeika, O; Riede, MK; Douglas, CJ; Barlow, S; Marder, SR; Neher, D; Spoltore, D; Vandewal, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benduhn, Johannes; Tvingstedt, Kristofer; Piersimoni, Fortunato; Ullbrich, Sascha; Fan, Yeli; Tropiano, Manuel; McGarry, Kathryn A.; Zeika, Olaf; Riede, Moritz K.; Douglas, Christopher J.; Barlow, Stephen; Marder, Seth R.; Neher, Dieter; Spoltore, Donato; Vandewal, Koen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic non-radiative voltage losses in fullerene-based organic solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic solar cells demonstrate external quantum efficiencies and fill factors approaching those of conventional photovoltaic technologies. However, as compared with the optical gap of the absorber materials, their open-circuit voltage is much lower, largely due to the presence of significant non-radiative recombination. Here, we study a large data set of published and new material combinations and find that non-radiative voltage losses decrease with increasing charge-transfer-state energies. This observation is explained by considering non-radiative charge-transfer-state decay as electron transfer in the Marcus inverted regime, being facilitated by a common skeletal molecular vibrational mode. Our results suggest an intrinsic link between non-radiative voltage losses and electron-vibration coupling, indicating that these losses are unavoidable. Accordingly, the theoretical upper limit for the power conversion efficiency of single-junction organic solar cells would be reduced to about 25.5% and the optimal optical gap increases to (1.45-1.65) eV, that is, (0.2-0.3) eV higher than for technologies with minimized non-radiative voltage losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 552, "Times Cited, All Databases": 593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17053, "DOI": "10.1038/nenergy.2017.53", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.53", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405744700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Y; Li, YT; Fung, V; Jiang, DE; Huang, WX; Zhang, SR; Iwasawa, Y; Sakata, T; Nguyen, L; Zhang, XY; Frenkel, AI; Tao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yu; Li, Yuting; Fung, Victor; Jiang, De-en; Huang, Weixin; Zhang, Shiran; Iwasawa, Yasuhiro; Sakata, Tomohiro; Luan Nguyen; Zhang, Xiaoyan; Frenkel, Anatoly I.; Tao, Franklin (Feng)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Catalytic transformation of CH4 under a mild condition is significant for efficient utilization of shale gas under the circumstance of switching raw materials of chemical industries to shale gas. Here, we report the transformation of CH4 to acetic acid and methanol through coupling of CH4, CO and O-2 on single-site Rh1O5 anchored in microporous aluminosilicates in solution at <= 150 degrees C. The activity of these singly dispersed precious metal sites for production of organic oxygenates can reach about 0.10 acetic acid molecules on a Rh1O5 site per second at 150 degrees C with a selectivity of similar to 70% for production of acetic acid. It is higher than the activity of free Rh cations by >1000 times. Computational studies suggest that the first C-H bond of CH4 is activated by Rh1O5 anchored on the wall of micropores of ZSM-5; the formed CH3 then couples with CO and OH, to produce acetic acid over a low activation barrier.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1231, "DOI": "10.1038/s41467-018-03235-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03235-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428237700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, T; Wang, YD; Wu, X; Wu, P; Yang, XF; Li, Q; Zhang, ZZ; Zhang, DK; Owens, G; Xu, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Ting; Wang, Yida; Wu, Xuan; Wu, Pan; Yang, Xiaofei; Li, Qin; Zhang, Zhezi; Zhang, Dongke; Owens, Gary; Xu, Haolan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "More from less: improving solar steam generation by selectively removing a portion of evaporation surface", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using minimal photothermal material to achieve maximum evaporation rate is extremely important for practical applications of interfacial solar evaporation technology. In this work, we found that with the increase in the size of evaporation surfaces, the evaporation rate decreased. Both experimental and numerical simulation results confirmed that when the evaporation surface size increased, the middle portion of the evaporation surface acted as a dead evaporation zone with little contribution to water evaporation. Based on this, the middle portion of the evaporation surface was selectively removed, and counterintuitively, both the evaporation rate and vapor output were increased due to the reconfigured and enhanced convection above the entire evaporation surface. As such, this work developed an important strategy to achieve a higher evaporation rate and increased vapour output while using less material. (c) 2022 Science China Press. Published by Elsevier B.V. and Science China Press. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2022, "Volume": 67, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1572, "End Page": 1580, "Article Number": null, "DOI": "10.1016/j.scib.2022.07.004", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2022.07.004", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000848639000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, Q; Kammoun, M; Erturk, A; Sharma, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Qian; Kammoun, Mejdi; Erturk, Alper; Sharma, Pradeep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale flexoelectric energy harvesting", "Source Title": "INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the most tantalizing applications of piezoelectricity is to harvest energy from ambient mechanical vibrations for powering micro and nullo devices. However, piezoelectricity is restricted only to certain materials and is severely compromised at high temperatures. In this article, we examine in detail, the possibility of using the phenomenon of flexoelectricity for energy harvesting. The flexoelectric effect is universally present in all dielectrics and exhibits a strong scaling with size. Using a simple beam-based paradigmatical design, we theoretically and computationally examine flexoelectric energy harvesting under harmonic mechanical excitation. We find that the output power density and conversion efficiency increase significantly when the beam thickness reduces from micro to nulloscale and flexoelectricity-based energy harvesting can be a viable alternative to piezoelectrics. Specifically, the conversion efficiency in flexoelectric transduction at sub-micron thickness levels is observed to increase by two orders of magnitude as the thickness is reduced by an order of magnitude. The flexoelectric energy harvester works even for a single layer beam with a symmetric cross section which is not possible in piezoelectric energy harvesting. Our results also pave the way for exploration of high temperature energy harvesting since unlike piezoelectricity, flexoelectricity persists well beyond the Curie temperatures of the high electromechanical coupling ferroelectrics that are often used. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 51, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3218, "End Page": 3225, "Article Number": null, "DOI": "10.1016/j.ijsolstr.2014.05.018", "DOI Link": "http://dx.doi.org/10.1016/j.ijsolstr.2014.05.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340141100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reeder, JT; Choi, J; Xue, YG; Gutruf, P; Hanson, J; Liu, M; Ray, T; Bandodkar, AJ; Avila, R; Xia, W; Krishnull, S; Xu, S; Barnes, K; Pahnke, M; Ghaffari, R; Huang, Y; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reeder, Jonathan T.; Choi, Jungil; Xue, Yeguang; Gutruf, Philipp; Hanson, Justin; Liu, Mark; Ray, Tyler; Bandodkar, Amay J.; Avila, Raudel; Xia, Wei; Krishnull, Siddharth; Xu, Shuai; Barnes, Kelly; Pahnke, Matthew; Ghaffari, Roozbeh; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Waterproof, electronics-enabled, epidermal microfluidic devices for sweat collection, biomarker analysis, and thermography in aquatic settings", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noninvasive, in situ biochemical monitoring of physiological status, via the use of sweat, could enable new forms of health care diagnostics and personalized hydration strategies. Recent advances in sweat collection and sensing technologies offer powerful capabilities, but they are not effective for use in extreme situations such as aquatic or arid environments, because of unique challenges in eliminating interference/contamination from surrounding water, maintaining robust adhesion in the presence of viscous drag forces and/or vigorous motion, and preventing evaporation of collected sweat. This paper introduces materials and designs for waterproof, epidermal, microfluidic and electronic systems that adhere to the skin to enable capture, storage, and analysis of sweat, even while fully underwater. Field trials demonstrate the ability of these devices to collect quantitative in situ measurements of local sweat chloride concentration, local sweat loss (and sweat rate), and skin temperature during vigorous physical activity in controlled, indoor conditions and in open-ocean swimming.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau6356", "DOI": "10.1126/sciadv.aau6356", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau6356", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457547900072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jang, M; Horie, Y; Shibukawa, A; Brake, J; Liu, Y; Kamali, SM; Arbabi, A; Ruan, HW; Faraon, A; Yang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jang, Mooseok; Horie, Yu; Shibukawa, Atsushi; Brake, Joshua; Liu, Yan; Kamali, Seyedeh Mahsa; Arbabi, Amir; Ruan, Haowen; Faraon, Andrei; Yang, Changhuei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wavefront shaping with disorder-engineered metasurfaces", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, wavefront shaping with disordered media has demonstrated optical manipulation capabilities beyond those of conventional optics, including extended volume, aberration-free focusing and subwavelength focusing. However, translating these capabilities to useful applications has remained challenging as the input-output characteristics of the disordered media (P variables) need to be exhaustively determined via O(P) measurements. Here, we propose a paradigm shift where the disorder is specifically designed so its exact input-output characteristics are known a priori and can be used with only a few alignment steps. We implement this concept with a disorder-engineered metasurface, which exhibits additional unique features for wavefront shaping such as a large optical memory effect range in combination with a wide angular scattering range, excellent stability, and a tailorable angular scattering profile. Using this designed metasurface with wavefront shaping, we demonstrate high numerical aperture (NA > 0.5) focusing and fluorescence imaging with an estimated similar to 2.2 x 10(8) addressable points in an similar to 8 mm field of view.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 84, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-017-0078-z", "DOI Link": "http://dx.doi.org/10.1038/s41566-017-0078-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423445500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Senden, T; van Dijk-Moes, RJA; Meijerink, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Senden, Tim; van Dijk-Moes, Relinde J. A.; Meijerink, Andries", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quenching of the red Mn4+ luminescence in Mn4+-doped fluoride LED phosphors", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Red-emitting Mn4+-doped fluorides are a promising class of materials to improve the color rendering and luminous efficacy of white light-emitting diodes (w-LEDs). For w-LEDs, the luminescence quenching temperature is very important, but surprisingly no systematic research has been conducted to understand the mechanism for thermal quenching in Mn4+-doped fluorides. Furthermore, concentration quenching of the Mn4+ luminescence can be an issue but detailed investigations are lacking. In this work, we study thermal quenching and concentration quenching in Mn4+-doped fluorides by measuring luminescence spectra and decay curves of K2TiF6:Mn4+ between 4 and 600 K and for Mn4+ concentrations from 0.01% to 15.7%. Temperature-dependent measurements on K2TiF6:Mn4+ and other Mn4+-doped phosphors show that quenching occurs through thermally activated crossover between the T-4(2) excited state and (4)A(2) ground state. The quenching temperature can be optimized by designing host lattices in which Mn4+ has a high T-4(2) state energy. Concentration-dependent studies reveal that concentration quenching effects are limited in K2TiF6:Mn4+ up to 5% Mn4+. This is important, as high Mn4+ concentrations are required for sufficient absorption of blue LED light in the parity-forbidden Mn4+ d-d transitions. At even higher Mn4+ concentrations (> 10%), the quantum efficiency decreases, mostly due to direct energy transfer to quenching sites (defects and impurity ions). Optimization of the synthesis to reduce quenchers is crucial for developing more efficient highly absorbing Mn4+ phosphors. The present systematic study provides detailed insights into temperature and concentration quenching of Mn4+ emission and can be used to realize superior narrow-band red Mn4+ phosphors for w-LEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2018, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8, "DOI": "10.1038/s41377-018-0013-1", "DOI Link": "http://dx.doi.org/10.1038/s41377-018-0013-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433279100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thirimanne, HM; Jayawardena, KDGI; Parnell, AJ; Bandara, RMI; Karalasingam, A; Pani, S; Huerdler, JE; Lidzey, DG; Tedde, SF; Nisbet, A; Mills, CA; Silva, SRP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thirimanne, H. M.; Jayawardena, K. D. G. I.; Parnell, A. J.; Bandara, R. M. I.; Karalasingam, A.; Pani, S.; Huerdler, J. E.; Lidzey, D. G.; Tedde, S. F.; Nisbet, A.; Mills, C. A.; Silva, S. R. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High sensitivity organic inorganic hybrid X-ray detectors with direct transduction and broadband response", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray detectors are critical to healthcare diagnostics, cancer therapy and homeland security, with many potential uses limited by system cost and/or detector dimensions. Current X-ray detector sensitivities are limited by the bulk X-ray attenuation of the materials and consequently necessitate thick crystals (similar to 1 mm(-1) cm), resulting in rigid structures, high operational voltages and high cost. Here we present a disruptive, flexible, low cost, broadband, and high sensitivity direct X-ray transduction technology produced by embedding high atomic number bismuth oxide nulloparticles in an organic bulk heterojunction. These hybrid detectors demonstrate sensitivities of 1712 mu C mGy(-1) cm(-3) for soft X-rays and similar to 30 and 58 mu C mGy(-1) cm(-3) under 6 and 15 MV hard X-rays generated from a medical linear accelerator; strongly competing with the current solid state detectors, all achieved at low bias voltages (-10 V) and low power, enabling detector operation powered by coin cell batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2926, "DOI": "10.1038/s41467-018-05301-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05301-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439809400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CP; Xie, XS; Liu, H; Wang, PJ; Deng, CB; Lu, BA; Zhou, J; Liang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Canpeng; Xie, Xuesong; Liu, Hui; Wang, Pinji; Deng, Canbin; Lu, Bingan; Zhou, Jiang; Liang, Shuquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integrated 'all-in-one' strategy to stabilize zinc anodes for high-performance zinc-ion batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many optimization strategies have been employed to stabilize zinc anodes of zinc-ion batteries (ZIBs). Although these commonly used strategies can improve anode performance, they simultaneously induce specific issues. In this study, through the combination of structural design, interface modification, and electrolyte optimization, an 'all-in-one' (AIO) electrode was developed. Compared to the three-dimensional (3D) anode in routine liquid electrolytes, the new AIO electrode can greatly suppress gas evolution and the occurrence of side reactions induced by active water molecules, while retaining the merits of a 3D anode. Moreover, the integrated AIO strategy achieves a sufficient electrode/electrolyte interface contact area, so that the electrode can promote electron/ion transfer, and ensure a fast and complete redox reaction. As a result, it achieves excellent shelving-restoring ability (60 hours, four times) and 1200 cycles of long-term stability without apparent polarization. When paired with two common cathode materials used in ZIBs (alpha-MnO2 and NH4V4O10), full batteries with the AIO electrode demonstrate high capacity and good stability. The strategy of the 'all-in-one' architectural design is enlightened to solve the issues of zinc anodes in advanced Zn-based batteries. The integrated 'all-in-one' electrode combines the merits of structural design, interface modification and electrolyte optimization, which can effectively promote the reversibility and stability of zinc-based batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2022, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab177", "DOI": "10.1093/nsr/nwab177", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab177", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765479400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, Z; Ju, ZC; Zhao, YL; Wan, JL; Zhu, YB; Qiang, YH; Qian, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Zheng; Ju, Zhicheng; Zhao, Yulong; Wan, Jialu; Zhu, Yabo; Qiang, Yinghuai; Qian, Yitai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped (N-doped) graphene has been prepared by a simple one-step hydrothermal approach using hexamethylenetetramine (HMTA) as single carbon and nitrogen source. In this hydrothermal process, HMTA pyrolyzes at high temperature and the N-doped graphene subsequently self-assembles on the surface of MgO particles (formed by the Mg powder reacting with H2O) during which graphene synthesis and nitrogen doping are simultaneously achieved. The as-synthesized graphene with incorporation of nitrogen groups possesses unique structure including thin layer thickness, high surface area, mesopores and vacancies. These structural features and their synergistic effects could not only improve ions and electrons transportation with nullometer-scale diffusion distances but also promote the penetration of electrolyte. The N-doped graphene exhibits high reversible capacity, superior rate capability as well as long-term cycling stability, which demonstrate that the N-doped graphene with great potential to be an efficient electrode material. The experimental results provide a new hydrothermal route to synthesize N-doped graphene with potential application for advanced energy storage, as well as useful information to design new graphene materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26146, "DOI": "10.1038/srep26146", "DOI Link": "http://dx.doi.org/10.1038/srep26146", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375980800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, YS; Liu, T; Liu, KL; Zhao, YH; Liu, L; Li, PH; Nie, AM; Liu, LX; Yu, J; Feng, X; Zhuge, FW; Li, HQ; Wang, XR; Zhai, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yongshan; Liu, Teng; Liu, Kailang; Zhao, Yinghe; Liu, Lei; Li, Penghui; Nie, Anmin; Liu, Lixin; Yu, Jun; Feng, Xin; Zhuge, Fuwei; Li, Huiqiao; Wang, Xinran; Zhai, Tianyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable integration of hybrid high-κ dielectric materials on two-dimensional semiconductors", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) semiconductors are promising channel materials for next-generation field-effect transistors (FETs). However, it remains challenging to integrate ultrathin and uniform high-& kappa; dielectrics on 2D semiconductors to fabricate FETs with large gate capacitance. We report a versatile two-step approach to integrating high-quality dielectric film with sub-1 nm equivalent oxide thickness (EOT) on 2D semiconductors. Inorganic molecular crystal Sb2O3 is homogeneously deposited on 2D semiconductors as a buffer layer, which forms a high-quality oxide-to-semiconductor interface and offers a highly hydrophilic surface, enabling the integration of high-& kappa; dielectrics via atomic layer deposition. Using this approach, we can fabricate monolayer molybdenum disulfide-based FETs with the thinnest EOT (0.67 nm). The transistors exhibit an on/off ratio of over 10(6) using an ultra-low operating voltage of 0.4 V, achieving unprecedently high gating efficiency. Our results may pave the way for the application of 2D materials in low-power ultrascaling electronics. A van der Waals buffer layer of Sb2O3 enables the integration of high-& kappa; dielectric layer with sub-1 nm equivalent oxide thickness on two-dimensional semiconductors, resulting in high performance of two-dimensional field-effect transistors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 22, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41563-023-01626-w", "DOI Link": "http://dx.doi.org/10.1038/s41563-023-01626-w", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042051700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fatimi, A; Okoro, OV; Podstawczyk, D; Siminska-Stanny, J; Shavandi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fatimi, Ahmed; Okoro, Oseweuba Valentine; Podstawczyk, Daria; Siminska-Stanny, Julia; Shavandi, Amin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural Hydrogel-Based Bio-Inks for 3D Bioprinting in Tissue Engineering: A Review", "Source Title": "GELS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) printing is well acknowledged to constitute an important technology in tissue engineering, largely due to the increasing global demand for organ replacement and tissue regeneration. In 3D bioprinting, which is a step ahead of 3D biomaterial printing, the ink employed is impregnated with cells, without compromising ink printability. This allows for immediate scaffold cellularization and generation of complex structures. The use of cell-laden inks or bio-inks provides the opportunity for enhanced cell differentiation for organ fabrication and regeneration. Recognizing the importance of such bio-inks, the current study comprehensively explores the state of the art of the utilization of bio-inks based on natural polymers (biopolymers), such as cellulose, agarose, alginate, decellularized matrix, in 3D bioprinting. Discussions regarding progress in bioprinting, techniques and approaches employed in the bioprinting of natural polymers, and limitations and prospects concerning future trends in human-scale tissue and organ fabrication are also presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 179, "DOI": "10.3390/gels8030179", "DOI Link": "http://dx.doi.org/10.3390/gels8030179", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000775298300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, YJ; Yu, Y; Xu, HF; Guo, C; Li, JT; Sun, S; Zhou, ZK; Qiu, CW; Wang, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Yanjun; Yu, Ying; Xu, Haofei; Guo, Chao; Li, Juntao; Sun, Shang; Zhou, Zhang-Kai; Qiu, Cheng-Wei; Wang, Xue-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-colour nulloprint-hologram synchronous metasurface with arbitrary hue-saturation-brightness control", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The colour gamut, a two-dimensional (2D) colour space primarily comprising hue and saturation (HS), lays the most important foundation for the colour display and printing industries. Recently, the metasurface has been considered a promising paradigm for nulloprinting and holographic imaging, demonstrating a subwavelength image resolution, a flat profile, high durability, and multi-functionalities. Much effort has been devoted to broaden the 2D HS plane, also known as the CIE map. However, the brightness (B), as the carrier of chiaroscuro information, has long been neglected in metasurface-based nulloprinting or holograms due to the challenge in realising arbitrary and simultaneous control of full-colour HSB tuning in a passive device. Here, we report a dielectric metasurface made of crystal silicon nulloblocks, which achieves not only tailorable coverage of the primary colours red, green and blue (RGB) but also intensity control of the individual colours. The colour gamut is hence extruded from the 2D CIE to a complete 3D HSB space. Moreover, thanks to the independent control of the RGB intensity and phase, we further show that a single-layer silicon metasurface could simultaneously exhibit arbitrary HSB colour nulloprinting and a full-colour hologram image. Our findings open up possibilities for high-resolution and high-fidelity optical security devices as well as advanced cryptographic approaches.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 95, "DOI": "10.1038/s41377-019-0206-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0206-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000491486800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, K; Knie, C; Bléger, D; Peletier, MA; Friedrich, H; Hecht, S; Broer, DJ; Debije, MG; Schenning, APHJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Kamlesh; Knie, Christopher; Bleger, David; Peletier, Mark A.; Friedrich, Heiner; Hecht, Stefan; Broer, Dirk J.; Debije, Michael G.; Schenning, Albertus P. H. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A chaotic self-oscillating sunlight-driven polymer actuator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature provides much inspiration for the design of materials capable of motion upon exposure to external stimuli, and many examples of such active systems have been created in the laboratory. However, to achieve continuous motion driven by an unchanging, constant stimulus has proven extremely challenging. Here we describe a liquid crystalline polymer film doped with a visible light responsive fluorinated azobenzene capable of continuous chaotic oscillatory motion when exposed to ambient sunlight in air. The presence of simultaneous illumination by blue and green light is necessary for the oscillating behaviour to occur, suggesting that the dynamics of continuous forward and backward switching are causing the observed effect. Our work constitutes an important step towards the realization of autonomous, persistently self-propelling machines and self-cleaning surfaces powered by sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11975, "DOI": "10.1038/ncomms11975", "DOI Link": "http://dx.doi.org/10.1038/ncomms11975", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379906300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arabnejad, S; Johnston, RB; Pura, JA; Singh, B; Tanzer, M; Pasini, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arabnejad, Sajad; Johnston, R. Burnett; Pura, Jenny Ann; Singh, Baljinder; Tanzer, Michael; Pasini, Damiano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-strength porous biomaterials for bone replacement: A strategy to assess the interplay between cell morphology, mechanical properties, bone ingrowth and manufacturing constraints", "Source Title": "ACTA BIOMATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-strength fully porous biomaterials built with additive manufacturing provide an exciting opportunity for load-bearing orthopedic applications. While factors controlling their mechanical and biological response have recently been the subject of intense research, the interplay between mechanical properties, bone ingrowth requirements, and manufacturing constraints, is still unclear. In this paper, we present two high-strength stretch-dominated topologies, the Tetrahedron and the Octet truss, as well as an intuitive visualization method to understand the relationship of cell topology, pore size, porosity with constraints imposed by bone ingrowth requirements and additive manufacturing. 40 samples of selected porosities are fabricated using Selective Laser Melting (SLM), and their morphological deviations resulting from SLM are assessed via micro-CF. Mechanical compression testing is used to obtain stiffness and strength properties, whereas bone ingrowth is assessed in a canine in vivo model at four and eight weeks. The results show that the maximum strength and stiffness ranged from 227.86 +/- 10.15 to 31.37 +/- 2.19 MPa and 4.58 +/- 0.18 to 1.23 +/- 0.40 GPa respectively, and the maximum 0.2% offset strength is almost 5 times stronger than that of tantalum foam. For Tetrahedron samples, bone ingrowth after four and eight weeks is 28.6% +/- 11.6%, and 41.3% +/- 4.3%, while for the Octet truss 35.5% +/- 1.9% and 56.9% +/- 4.0% respectively. This research is the first to demonstrate the occurrence of bone ingrowth into high-strength porous biomaterials which have higher structural efficiency than current porous biomaterials in the market. Statement of significance We present two stretch-dominated cell topologies for porous biomaterials that can be used for load bearing orthopaedic applications, and prove that they encourage bone ingrowth in a canine model. We also introduce an intuitive method to visualize and understand the relationship of cell topology, pore size, porosity with constraints imposed by bone ingrowth requirements and additive manufacturing. We show this strategy helps to gain insight into the interaction of exogenous implant factors and endogenous system factors that can affect the success of load-bearing orthopaedic devices. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2016, "Volume": 30, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 356, "Article Number": null, "DOI": "10.1016/j.actbio.2015.10.048", "DOI Link": "http://dx.doi.org/10.1016/j.actbio.2015.10.048", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368563600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, C; You, P; Liu, ZK; Li, L; Yan, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Chao; You, Peng; Liu, Zhike; Li, Li; Yan, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive broadband phototransistors based on perovskite/organic-semiconductor vertical heterojunctions", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organolead halide perovskites have emerged as the most promising materials for various optoelectronic devices, especially solar cells, because of their excellent optoelectronic properties. Here, we present the first report of low-voltage high-gain phototransistors based on perovskite/organic-semiconductor vertical heterojunctions, which show ultrahigh responsivities of similar to 10(9)A W-1 and specific detectivities of similar to 10(14) Jones in a broadband region from the ultraviolet to the near infrared. The high sensitivity of the devices is attributed to a pronounced photogating effect that is mainly due to the long carrier lifetimes and strong light absorption in the perovskite material. In addition, flexible perovskite photodetectors have been successfully prepared via a solution process and show high sensitivity as well as excellent flexibility and bending durability. The high performance and facile solution-based fabrication of the perovskite/organic-semiconductor phototransistors indicate their promise for potential application for ultrasensitive broadband photodetection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2017, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e17023", "DOI": "10.1038/lsa.2017.23", "DOI Link": "http://dx.doi.org/10.1038/lsa.2017.23", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407510200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reckmeier, CJ; Schneider, J; Susha, AS; Rogach, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reckmeier, C. J.; Schneider, J.; Susha, A. S.; Rogach, A. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Luminescent colloidal carbon dots: optical properties and effects of doping [Invited]", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We review the effect of doping on the optical properties of luminescent colloidal carbon dots. They are considered as a hybrid material featuring both molecular and semiconductor-like characteristics, where doping plays an important role. Starting from the short overview of synthetic strategies, we consider the evolution of carbon dots from molecular precursors to fluorescent nulloparticles, and the relevant structural properties of carbon dots. Choice of the reactant materials, dopant atoms and reaction parameters provide carbon dots with varying optical properties. High chemical stability, bright luminescence and customizable surface functionalization of carbon dots open their use in a broad range of applications, which are exemplary presented at the end of this review. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2016, "Volume": 24, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A312", "End Page": "A340", "Article Number": null, "DOI": "10.1364/OE.24.00A312", "DOI Link": "http://dx.doi.org/10.1364/OE.24.00A312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369066300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, J; Salunkhe, RR; Zhang, HB; Malgras, V; Ahamad, T; Alshehri, SM; Kobayashi, N; Tominaka, S; Ide, Y; Kim, JH; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Jing; Salunkhe, Rahul R.; Zhang, Huabin; Malgras, Victor; Ahamad, Tansir; Alshehri, Saad M.; Kobayashi, Naoya; Tominaka, Satoshi; Ide, Yusuke; Kim, Jung Ho; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimetallic Metal-Organic Frameworks for Controlled Catalytic Graphitization of nulloporous Carbons", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single metal-organic frameworks (MOFs), constructed from the coordination between one-fold metal ions and organic linkers, show limited functionalities when used as precursors for nulloporous carbon materials. Herein, we propose to merge the advantages of zinc and cobalt metals ions into one single MOF crystal (i.e., bimetallic MOFs). The organic linkers that coordinate with cobalt ions tend to yield graphitic carbons after carbonization, unlike those bridging with zinc ions, due to the controlled catalytic graphitization by the cobalt nulloparticles. In this work, we demonstrate a feasible method to achieve nulloporous carbon materials with tailored properties, including specific surface area, pore size distribution, degree of graphitization, and content of heteroatoms. The bimetallic-MOF-derived nulloporous carbon are systematically characterized, highlighting the importance of precisely controlling the properties of the carbon materials. This can be done by finely tuning the components in the bimetallic MOF precursors, and thus designing optimal carbon materials for specific applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 30295, "DOI": "10.1038/srep30295", "DOI Link": "http://dx.doi.org/10.1038/srep30295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380637300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WD; Dolocan, A; Oh, P; Celio, H; Park, S; Cho, J; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wangda; Dolocan, Andrei; Oh, Pilgun; Celio, Hugo; Park, Suhyeon; Cho, Jaephil; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Undesired electrode-electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominulltly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14589, "DOI": "10.1038/ncomms14589", "DOI Link": "http://dx.doi.org/10.1038/ncomms14589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400064000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, YQ; Zhang, JL; Wu, YQ; Wang, CL; Koval, V; Shi, BG; Ye, HT; McKinnon, R; Viola, G; Yan, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Yongqiang; Zhang, Jialiang; Wu, Yanqing; Wang, Chunlei; Koval, Vladimir; Shi, Baogui; Ye, Haitao; McKinnon, Ruth; Viola, Giuseppe; Yan, Haixue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unfolding grain size effects in barium titanate ferroelectric ceramics", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Grain size effects on the physical properties of polycrystalline ferroelectrics have been extensively studied for decades; however there are still major controversies regarding the dependence of the piezoelectric and ferroelectric properties on the grain size. Dense BaTiO3 ceramics with different grain sizes were fabricated by either conventional sintering or spark plasma sintering using micro-and nullo-sized powders. The results show that the grain size effect on the dielectric permittivity is nearly independent of the sintering method and starting powder used. A peak in the permittivity is observed in all the ceramics with a grain size near 1 mm and can be attributed to a maximum domain wall density and mobility. The piezoelectric coefficient d(33) and remnullt polarization P-r show diverse grain size effects depending on the particle size of the starting powder and sintering temperature. This suggests that besides domain wall density, other factors such as back fields and point defects, which influence the domain wall mobility, could be responsible for the different grain size dependence observed in the dielectric and piezoelectric/ferroelectric properties. In cases where point defects are not the dominullt contributor, the piezoelectric constant d33 and the remnullt polarization Pr increase with increasing grain size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9953, "DOI": "10.1038/srep09953", "DOI Link": "http://dx.doi.org/10.1038/srep09953", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354110100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, T; Xiao, H; Goddard, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Tao; Xiao, Hai; Goddard, William A., III", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reaction Mechanisms for the Electrochemical Reduction of CO2 to CO and Formate on the Cu(100) Surface at 298 K from Quantum Mechanics Free Energy Calculations with Explicit Water", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper is the only elemental metal that reduces a significant fraction of CO2 to hydrocarbons and alcohols, but the atomistic reaction mechanism that controls the product distributions is not known because it has not been possible to detect the reaction intermediates on the electrode surface experimentally, or to carry out Quantum Mechanics (QM) calculations with a realistic description of the electrolyte (water). Here, we carry out QM calculations with an explicit description of water on the Cu(100) surface (experimentally shown to be stable under CO2 reduction reaction conditions) to examine the initial reaction pathways to form CO and formate (HCOO-) from CO2 through free energy calculations at 298 K and pH 7. We find that CO formation proceeds from physisorbed CO2 to chemisorbed CO2 (*CO2 delta-), with a free energy barrier of Delta G(double dagger) = 0.43 eV, the rate-determining step (RDS). The subsequent barriers of protonating *CO2 delta- to form COOH* and then dissociating COOH* to form *CO are 0.37 and 0.30 eV, respectively. HCOO- formation proceeds through a very different pathway in which physisorbed CO2 reacts directly with a surface H* (along with electron transfer), leading to Delta G(double dagger) = 0.80 eV. Thus, the competition between CO formation and HCOO- formation occurs in the first electron-transfer step. On Cu(100), the RDS for CO formation is lower, making CO the predominullt product. Thus, to alter the product distribution, we need to control this first step of CO2 binding, which might involve controlling pH, alloying, or changing the structure at the nulloscale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2016, "Volume": 138, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13802, "End Page": 13805, "Article Number": null, "DOI": "10.1021/jacs.6b08534", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b08534", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386540500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Xu, GL; Kolluru, VSC; Zhao, C; Li, QT; Zhou, XW; Liu, YZ; Yin, L; Zhuo, ZQ; Daali, A; Fan, JJ; Liu, WJ; Ren, Y; Xu, WQ; Deng, JJ; Hwang, I; Ren, DS; Feng, XN; Sun, CJ; Huang, L; Zhou, T; Du, M; Chen, ZH; Sun, SG; Chan, MKY; Yang, WL; Ouyang, MG; Amine, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiang; Xu, Gui-Liang; Kolluru, Venkata Surya Chaitanya; Zhao, Chen; Li, Qingtian; Zhou, Xinwei; Liu, Yuzi; Yin, Liang; Zhuo, Zengqing; Daali, Amine; Fan, Jing-Jing; Liu, Wenjun; Ren, Yang; Xu, Wenqian; Deng, Junjing; Hwang, Inhui; Ren, Dongsheng; Feng, Xuning; Sun, Chengjun; Huang, Ling; Zhou, Tao; Du, Ming; Chen, Zonghai; Sun, Shi-Gang; Chan, Maria K. Y.; Yang, Wanli; Ouyang, Minggao; Amine, Khalil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin and regulation of oxygen redox instability in high-voltage battery cathodes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen redox instability at high voltages hinders the application of high-energy battery cathodes. Here the authors report that elimination of domain boundaries in single-crystal cathodes improves the redox stability and consequently the electrochemical performance in extended high-voltage cycling. Oxygen redox at high voltage has emerged as a transformative paradigm for high-energy battery cathodes such as layered transition-metal oxides by offering extra capacity beyond conventional transition-metal redox. However, these cathodes suffer from voltage hysteresis, voltage fade and capacity drop upon cycling. Single-crystalline cathodes have recently shown some improvements, but these challenges remain. Here we reveal the fundamental origin of oxygen redox instability to be from the domain boundaries that are present in single-crystalline cathode particles. By investigating single-crystalline cathodes with different domain boundaries structures, we show that the elimination of domain boundaries enhances the reversible lattice oxygen redox while inhibiting the irreversible oxygen release. This leads to significantly suppressed structural degradation and improved mechanical integrity during battery cycling and abuse heating. The robust oxygen redox enabled through domain boundary control provides practical opportunities towards high-energy, long-cycling, safe batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 7, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 808, "End Page": 817, "Article Number": null, "DOI": "10.1038/s41560-022-01036-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01036-3", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805082400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, YX; Liu, BB; Li, JC; Li, MH; Yao, Z; Dong, LL; Rao, DW; Zhang, P; Cao, XZ; Villalobos, LF; Zhang, CF; An, QF; Elimelech, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yunxiang; Liu, Beibei; Li, Jiachen; Li, Minghui; Yao, Zheng; Dong, Liangliang; Rao, Dewei; Zhang, Peng; Cao, Xingzhong; Villalobos, Luis Francisco; Zhang, Chunfang; An, Quan-Fu; Elimelech, Menachem", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure optimization of bioderived polyester nullofilms for antibiotic desalination via nullofiltration", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The successful implementation of thin-film composite membranes (TFCM) for challenging solute-solute sepa-rations in the pharmaceutical industry requires a fine control over the microstructure (size, distribution, and connectivity of the free-volume elements) and thickness of the selective layer. For example, desalinating anti-biotic streams requires highly interconnected free-volume elements of the right size to block antibiotics but allow the passage of salt ions and water. Here, we introduce stevioside, a plant-derived contorted glycoside, as a promising aqueous phase monomer for optimizing the microstructure of TFCM made via interfacial poly-merization. The low diffusion rate and moderate reactivity of stevioside, together with its nonplanar and dis-torted conformation, produced thin selective layers with an ideal microporosity for antibiotic desalination. For example, an optimized 18-nm membrane exhibited an unprecedented combination of high water permeance (81.2 liter m-2 hour-1 bar-1), antibiotic desalination efficiency (NaCl/tetracycline separation factor of 11.4), an-tifouling performance, and chlorine resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2023, "Volume": 9, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadg6134", "DOI": "10.1126/sciadv.adg6134", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adg6134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000988274400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mannino, G; Deretzis, I; Smecca, E; La Magna, A; Alberti, A; Ceratti, D; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mannino, Giovanni; Deretzis, Ioannis; Smecca, Emanuele; La Magna, Antonino; Alberti, Alessandra; Ceratti, Davide; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-Dependent Optical Band Gap in CsPbBr3, MAPbBr3, and FAPbBr3 Single Crystals", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals represent a benchmark for understanding the bulk properties of halide perovskites. We have indeed studied the dielectric function of lead bromide perovskite single crystals (MAPbBr(3), CsPbBr3 and for the first time FAPbBr(3)) by spectroscopic ellipsometry in the range of 1-5 eV while varying the temperature from 183 to 440 K. An extremely low absorption coefficient in the sub-band gap region was found, indicating the high optical quality of all three crystals. We extracted the band gap values through critical point analysis showing that Tauc-based values are systematically underestimated. The two structural phase transitions, i.e., orthorhombic-tetragonal and tetragonal-cubic, show distinct optical behaviors, with the former having a discontinuous character. The cross-correlation of optical data with DFT calculations evidences the role of octahedral tilting in tailoring the value of the band gap at a given temperature, whereas differences in the thermal expansion affect the slope of the band gap trend as a function of temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2020, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2490, "End Page": 2496, "Article Number": null, "DOI": "10.1021/acs.jpclett.0c00295", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.0c00295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526348400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ediger, MD; Forrest, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ediger, M. D.; Forrest, J. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamics near Free Surfaces and the Glass Transition in Thin Polymer Films: A View to the Future", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The past 20 years have seen a substantial effort to understand dynamics and the glass transition in thin polymer films. In this Perspective, we consider developments in this field and offer a consistent interpretation of some major findings. We discuss recent experiments that directly measure mobility at or near the surface of glassy polymers. These experiments indicate that enhanced mobility near the free surface can exceed bulk mobility by several orders of magnitude and extend for several nullometers into the bulk polymer. Enhanced mobility near the free surface allows a qualitative understanding of many of the observations of a reduced glass transition temperature T-g in thin films. For thin films, knowledge of T-g by itself is less useful than for bulk materials. Because of this, new experimental methods that directly measure important material properties are being developed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 433, "Times Cited, All Databases": 492, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2014, "Volume": 47, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 471, "End Page": 478, "Article Number": null, "DOI": "10.1021/ma4017696", "DOI Link": "http://dx.doi.org/10.1021/ma4017696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330543500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pappu, A; Pickering, KL; Thakur, VK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pappu, Asokan; Pickering, Kim L.; Thakur, Vijay Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manufacturing and characterization of sustainable hybrid composites using sisal and hemp fibres as reinforcement of poly (lactic acid) via injection moulding", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural polymers based composites offers significant advantages over synthetic fibre reinforced petroleum matrix based composites with regard to biodegradability, biocompatibility, design flexibility and sustainability. This work reports for the first time manufacturing of hybrid fibre reinforced biodegradable composites using sisal and hemp fibre with polylactic acid employing melt processing and injection moulding techniques. Granulated sisal and hemp fibres were blended and hybrid composites were manufactured using aliphatic polyester made up of lactic acid (PLA) through extrusion and injection moulding and their performance was evaluated. Experimental results revealed that density, elongation at break and water absorption capacity of hybrid composites were 1.14 +/- 0.07 g/cm(3), 0.93 +/- 0.35% and 1.06 +/- 0.18% respectively. The achieved mean tensile strength (46.25 +/- 6.75 MPa), Young's modulus (6.1 +/- 0.58 GPa) and specific tensile strength (38.86 +/- 5.0) of hybrid fibre reinforced PLA composites were improved compared to neat PLA. The flexural strength (94.83 +/- 11.21 MPa), flexural modulus (6.04 +/- 0.55 GPA) and specific flexural strength (79.76 +/- 8.80) of hybrid fibre composites also showed better performance than those of neat PLA. Incorporation of sisal and hemp fibre with polylactide remarkably increased the impact strength of composites. Overall, the hybrid composites demonstrated good performance suggesting that they have great potential for use as an environmentally friendly alternative material in automotive, packaging, electronics, interiors and agricultural applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 260, "End Page": 269, "Article Number": null, "DOI": "10.1016/j.indcrop.2019.05.040", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2019.05.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473376800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Caldwell, JD; Kretinin, AV; Chen, YG; Giannini, V; Fogler, MM; Francescato, Y; Ellis, CT; Tischler, JG; Woods, CR; Giles, AJ; Hong, M; Watanabe, K; Taniguchi, T; Maier, SA; Novoselov, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Caldwell, Joshua D.; Kretinin, Andrey V.; Chen, Yiguo; Giannini, Vincenzo; Fogler, Michael M.; Francescato, Yan; Ellis, Chase T.; Tischler, Joseph G.; Woods, Colin R.; Giles, Alexander J.; Hong, Minghui; Watanabe, Kenji; Taniguchi, Takashi; Maier, Stefan A.; Novoselov, Kostya S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-diffractional volume-confined polaritons in the natural hyperbolic material hexagonal boron nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strongly anisotropic media, where the principal components of the dielectric tensor have opposite signs, are called hyperbolic. Such materials exhibit unique nullophotonic properties enabled by the highly directional propagation of slow-light modes localized at deeply sub-diffractional length scales. While artificial hyperbolic metamaterials have been demonstrated, they suffer from high plasmonic losses and require complex nullofabrication, which in turn induces size-dependent limitations on optical confinement. The low-loss, mid-infrared, natural hyperbolic material hexagonal boron nitride is an attractive alternative. Here we report on three-dimensionally confined 'hyperbolic polaritons' in boron nitride nullocones that support four series (up to the seventh order) modes in two spectral bands. The resonullt modes obey the predicted aspect ratio dependence and exhibit high-quality factors (Q up to 283) in the strong confinement regime (up to lambda/86). These observations assert hexagonal boron nitride as a promising platform for studying novel regimes of light-matter interactions and nullophotonic device engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 732, "Times Cited, All Databases": 810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5221, "DOI": "10.1038/ncomms6221", "DOI Link": "http://dx.doi.org/10.1038/ncomms6221", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343983000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, MS; Ma, SB; Lee, DJ; Im, D; Doo, SG; Yamamoto, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Min Sik; Ma, Sang Bok; Lee, Dong Joon; Im, Dongmin; Doo, Seok-Gwang; Yamamoto, Osamu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Reversible Lithium Metal Anode", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has shown a lot of promise for use as an anode material in rechargeable batteries owing to its high theoretical capacity. However, it does not meet the cycle life and safety requirements of rechargeable batteries owing to electrolyte decomposition and dendrite formation on the surfaces of the lithium anodes during electrochemical cycling. Here, we propose a novel electrolyte system that is relatively stable against lithium metal and mitigates dendritic growth. Systematic design methods that combined simulations, model-based experiments, and in situ analyses were employed to design the system. The reduction potential of the solvent, the size of the salt anions, and the viscosity of the electrolyte were found to be critical parameters determining the rate of dendritic growth. A lithium metal anode in contact with the designed electrolyte exhibited remarkable cyclability (more than 100 cycles) at a high areal capacity of 12 mAh cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3815, "DOI": "10.1038/srep03815", "DOI Link": "http://dx.doi.org/10.1038/srep03815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330044700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, F; Cheng, L; Yang, NL; Gong, YH; Ni, YW; Bai, S; Wang, XW; Chen, MC; Chen, Q; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Fei; Cheng, Liang; Yang, Nailin; Gong, Yuehan; Ni, Yanwen; Bai, Shang; Wang, Xianwen; Chen, Muchao; Chen, Qian; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of TiH1.924 nullodots by liquid-phase exfoliation for enhanced sonodynamic cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal hydrides have been rarely used in biomedicine. Herein, we fabricate titanium hydride (TiH1.924) nullodots from its powder form via the liquid-phase exfoliation, and apply these metal hydride nullodots for effective cancer treatment. The liquid-phase exfoliation is an effective method to synthesize these metal hydride nullomaterials, and its efficiency is determined by the matching of surface energy between the solvent and the metal hydrides. The obtained TiH1.924 nullodots can produce reactive oxygen species (ROS) under ultrasound, presenting a highly efficient sono-sensitizing effect. Meanwhile, TiH1.924 nullodots with strong near-infrared (NIR) absorbance can serve as a robust photothermal agent. By using the mild photothermal effect to enhance intra-tumoral blood flow and improve tumor oxygenation, a remarkable synergistic therapeutic effect is achieved in the combined photothermal-sonodynamic therapy. Importantly, most of these TiH1.924 nullodots can be cleared out from the body. This work presents the promises of functional metal hydride nullomaterials for biomedical applications. Dynamic therapy is attracting attention for cancer treatment. Here, the authors report that metal hydride nullodots can be used for sonodynamic therapy, which can be further enhanced by photothermal heating to increase tissue oxygenation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3712, "DOI": "10.1038/s41467-020-17485-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17485-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556360300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Wang, ZJ; Wu, XX; Yaji, K; Ishida, Y; Kohama, Y; Dai, GY; Sun, Y; Bareille, C; Kuroda, K; Kondo, T; Okazaki, K; Kindo, K; Wang, XC; Jin, CQ; Hu, JP; Thomale, R; Sumida, K; Wu, SL; Miyamoto, K; Okuda, T; Ding, H; Gu, GD; Tamegai, T; Kawakami, T; Sato, M; Shin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Wang, Zhijun; Wu, Xianxin; Yaji, Koichiro; Ishida, Yukiaki; Kohama, Yoshimitsu; Dai, Guangyang; Sun, Yue; Bareille, Cedric; Kuroda, Kenta; Kondo, Takeshi; Okazaki, Kozo; Kindo, Koichi; Wang, Xiancheng; Jin, Changqing; Hu, Jiangping; Thomale, Ronny; Sumida, Kazuki; Wu, Shilong; Miyamoto, Koji; Okuda, Taichi; Ding, Hong; Gu, G. D.; Tamegai, Tsuyoshi; Kawakami, Takuto; Sato, Masatoshi; Shin, Shik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple topological states in iron-based superconductors", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological materials and unconventional iron-based superconductors are both important areas of study but, to date, relatively little overlap has been identified between these two fields. However, the combination of topological bands and superconductivity promises the manifestation of exotic superconducting states, including Majorana fermions, the central component of topological quantum computation. Here, using laser-based, spin-resolved and angle-resolved photoemission spectroscopy and density functional theory calculations, we have identified both topological insulator and Dirac semimetal states near the Fermi energy in different iron-based superconducting compounds. Carrier doping can tune these topologically non-trivial bands to the Fermi energy, potentially allowing access to several different superconducting topological states in the same material. These results reveal the generic coexistence of superconductivity and multiple topological states in iron-based superconductors, indicating that this broad class of materials is a promising platform for high-temperature topological superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 41, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-018-0280-z", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0280-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454733100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, X; Kushima, A; Halliday, C; Zhou, J; Li, J; Hatton, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Xiao; Kushima, Akihiro; Halliday, Cameron; Zhou, Jian; Li, Ju; Hatton, T. Alan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically-mediated selective capture of heavy metal chromium and arsenic oxyanions from water", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The removal of highly toxic, ultra-dilute contaminullts of concern has been a primary challenge for clean water technologies. Chromium and arsenic are among the most prevalent heavy metal pollutants in urban and agricultural waters, with current separation processes having severe limitations due to lack of molecular selectivity. Here, we report redox-active metallopolymer electrodes for the selective electrochemical removal of chromium and arsenic. An uptake greater than 100 mg Cr/g adsorbent can be achieved electrochemically, with a 99% reversible working capacity, with the bound chromium ions released in the less harmful trivalent form. Furthermore, we study the metallopolymer response during electrochemical modulation by in situ transmission electron microscopy. The underlying mechanisms for molecular selectivity are investigated through electronic structure calculations, indicating a strong charge transfer to the heavy metal oxyanions. Finally, chromium and arsenic are remediated efficiently at concentrations as low as 100 ppb, in the presence of over 200-fold excess competing salts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4701, "DOI": "10.1038/s41467-018-07159-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07159-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449494700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YJ; Li, M; Pan, F; Zhu, ZY; Sun, HM; Tang, YW; Fu, GT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yujie; Li, Meng; Pan, Fei; Zhu, Zhuoya; Sun, Huamei; Tang, Yawen; Fu, Gengtao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasma-induced Mo-doped Co3O4 with enriched oxygen vacancies for electrocatalytic oxygen evolution in water splitting", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heteroatomic substitution and vacancy engineering of spinel oxides can theoretically optimize the oxygen evolution reaction (OER) through charge redistribution and d-band center modification but still remain a great challenge in both the preparation and catalytic mechanism. Herein, we proposed a novel and efficient Ar-plasma (P)-assisted strategy to construct heteroatom Mo-substituted and oxygen vacancies enriched hierarchical spinel Co3O4 porous nulloneedle arrays in situ grown on carbon cloth (denoted P-Mo-Co3O4@CC) to improve the OER performance. Ar-plasma technology can efficiently generate vacancy sites at the surface of hydroxide, which induces the anchoring of Mo anion salts through electrostatic interaction, finally facilitating the substitution of Mo atoms and the formation of oxygen vacancies on the Co3O4 surface. The P-Mo-Co3O4@CC affords a low overpotential of only 276 mV at 10 mA cm(-2) for the OER, which is 58 mV superior to that of Mo-free Co3O4@CC and surpasses commercial RuO2 catalyst. The robust stability and satisfactory selectivity (nearly 100% Faradic efficiency) of P-Mo-Co3O4@CC for the OER are also demonstrated. Theoretical studies demonstrate that Mo with variable valance states can efficiently regulates the atomic ratio of Co3+/Co2+ and increases the number of oxygen vacancies, thereby inducing charge redistribution and tuning the d-band center of Co3O4, which improve the adsorption energy of oxygen intermediates (e.g., *OOH) on P-Mo-Co3O4@CC during OER. Furthermore, the two-electrode OER//HER electrolyzer equipped with P-Mo-Co3O4@CC as anode displays a low operation potential of 1.54 V to deliver a current density of 10 mA cm(-2), and also exhibits good reversibility and anticurrent fluctuation ability under simulated real energy supply conditions, demonstrating the great potential of P-Mo-Co3O4@CC in water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/cey2.279", "DOI Link": "http://dx.doi.org/10.1002/cey2.279", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000876032900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Errea, I; Calandra, M; Pickard, CJ; Nelson, J; Needs, RJ; Li, YW; Liu, HY; Zhang, YW; Ma, YM; Mauri, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Errea, Ion; Calandra, Matteo; Pickard, Chris J.; Nelson, Joseph; Needs, Richard J.; Li, Yinwei; Liu, Hanyu; Zhang, Yunwei; Ma, Yanming; Mauri, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Pressure Hydrogen Sulfide from First Principles: A Strongly Anharmonic Phonon-Mediated Superconductor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use first-principles calculations to study structural, vibrational, and superconducting properties of H2S at pressures P >= 200 GPa. The inclusion of zero-point energy leads to two different possible dissociations of H2S, namely 3H(2)S -> 2H(3)S -> S and 5H(2)S -> 3H(3)S + HS2, where both H3S and HS2 are metallic. For H3S, we perform nonperturbative calculations of anharmonic effects within the self-consistent harmonic approximation and show that the harmonic approximation strongly overestimates the electronphonon interaction (lambda approximate to 2.64 at 200 GPa) and T-c. Anharmonicity hardens H-S bond-stretching modes and softens H-S bond-bending modes. As a result, the electron-phonon coupling is suppressed by 30% (lambda approximate to 1.84 at 200 GPa). Moreover, while at the harmonic level T-c decreases with increasing pressure, the inclusion of anharmonicity leads to a T-c that is almost independent of pressure. High-pressure hydrogen sulfide is a strongly anharmonic superconductor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2015, "Volume": 114, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 157004, "DOI": "10.1103/PhysRevLett.114.157004", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.157004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352990700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XK; Xu, LL; Li, C; Zhang, CH; Yao, HX; Xu, R; Cui, PX; Zheng, XS; Gu, M; Lee, J; Jiang, HQ; Huang, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xingkun; Xu, Liangliang; Li, Cheng; Zhang, Canhui; Yao, Hanxu; Xu, Ren; Cui, Peixin; Zheng, Xusheng; Gu, Meng; Lee, Jinwoo; Jiang, Heqing; Huang, Minghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developing a class of dual atom materials for multifunctional catalytic reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dual atom catalysts, bridging single atom and metal/alloy nulloparticle catalysts, offer more opportunities to enhance the kinetics and multifunctional performance of oxygen reduction/evolution and hydrogen evolution reactions. However, the rational design of efficient multifunctional dual atom catalysts remains a blind area and is challenging. In this study, we achieved controllable regulation from Co nulloparticles to CoN4 single atoms to Co2N5 dual atoms using an atomization and sintering strategy via an N-stripping and thermal-migrating process. More importantly, this strategy could be extended to the fabrication of 22 distinct dual atom catalysts. In particular, the Co2N5 dual atom with tailored spin states could achieve ideally balanced adsorption/desorption of intermediates, thus realizing superior multifunctional activity. In addition, it endows Zn-air batteries with long-term stability for 800 h, allows water splitting to continuously operate for 1000 h, and can enable solar-powered water splitting systems with uninterrupted large-scale hydrogen production throughout day and night. This universal and scalable strategy provides opportunities for the controlled design of efficient multifunctional dual atom catalysts in energy conversion technologies. This work developed a class of dual atom materials that can act as efficient and stable catalysts for multifunctional catalytic reactions in an uninterrupted water splitting system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7210, "DOI": "10.1038/s41467-023-42756-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42756-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001102128500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CF; Zhong, WD; Shen, K; Zhang, Q; Zhao, R; Xiang, H; Wu, J; Li, XK; Yang, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chenfan; Zhong, Wenda; Shen, Ke; Zhang, Qin; Zhao, Rong; Xiang, Hui; Wu, Jing; Li, Xuanke; Yang, Nianjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemically Reconstructed Cu-FeOOH/Fe3O4 Catalyst for Efficient Hydrogen Evolution in Alkaline Media", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface self-reconstruction via incorporating an amorphous structure on the surface of a catalyst can induce abundant defects and unsaturated sites for enhanced hydrogen evolution reaction (HER) activity. Herein, an electrochemical activation method is proposed to reconstruct the surface of a Cu-Fe3O4 catalyst. Following a dissolution-redeposition path, the defective FeOOH is formed under potential stimulation on the surface of the Cu-Fe3O4 precursor during the electrochemical activation process. This Cu-FeOOH/Fe3O4 catalyst exhibits excellent stability as well as extremely low overpotential toward the alkaline HER (e.g., 129 and 285 mV at the large current densities of -100 and 500 mA cm(-2), respectively), much superior to the Pt/C catalyst. The experimental and density functional theory calculation results demonstrate that the Cu-FeOOH/Fe3O4 catalyst has abundant oxygen vacancies, featuring optimized surface chemical composition and electronic structure for improving the active sites and intrinsic activity. Introducing defective FeOOH on the surface of a Cu-Fe3O4 catalyst by means of an electrochemical activation method decreases the energy barrier of both H2O dissociation and H-2 generation. Such a surface self-reconstruction strategy provides a new avenue toward the production of efficient non-noble metal catalysts for the HER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 12, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200077, "DOI": "10.1002/aenm.202200077", "DOI Link": "http://dx.doi.org/10.1002/aenm.202200077", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768033400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YY; Ji, HD; Liu, QM; Sun, ZY; Li, PS; Ding, PR; Guo, M; Yi, XH; Xu, WL; Wang, CC; Gao, S; Wang, Q; Liu, W; Chen, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yunyun; Ji, Haodong; Liu, Qiming; Sun, Zhaoyang; Li, Peisheng; Ding, Peiren; Guo, Ming; Yi, Xiaohong; Xu, Wenlu; Wang, Chong-Chen; Gao, Shuai; Wang, Qiang; Liu, Wen; Chen, Shaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visible light photocatalytic degradation of sulfanilamide enhanced by Mo doping of BiOBr nulloflowers", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design of high-efficiency visible light photocatalysts is critical in the degradation of antibiotic pollutants in water, a key step towards environmental remediation. In the present study, Mo-doped BiOBr nullocomposites are prepared hydrothermally at different feed ratios, and display remarkable visible light photocatalytic activity towards the degradation of sulfanilamide, a common antibacterial drug. Among the series, the sample with 2% Mo dopants exhibits the best photocatalytic activity, with a performance 2.3 times better that of undoped BiOBr. This is attributed to Mo doping that narrows the band gap of BiOBr and enhances absorption in the visible region. Additional contributions arise from the unique materials morphology, where the highly exposed (102) crystal planes enrich the photocatalytic active sites, and facilitate the adsorption of sulfanilamide molecules and their eventual attack by free radicals. The reaction mechanism and pathways are then unraveled based on theoretical calculations of the Fukui index and liquid chromatography/mass spectrometry measurements of the reaction intermediates and products. Results from this study indicate that deliberate structural engineering based on heteroatom doping and morphological control may serve as an effective strategy in the design of highly active photocatalysts towards antibiotic degradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2022, "Volume": 424, "Issue": null, "Part Number": "C", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127563, "DOI": "10.1016/j.jhazmat.2021.127563", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2021.127563", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719943700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Price, MB; Butkus, J; Jellicoe, TC; Sadhanala, A; Briane, A; Halpert, JE; Broch, K; Hodgkiss, JM; Friend, RH; Deschler, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Price, Michael B.; Butkus, Justinas; Jellicoe, Tom C.; Sadhanala, Aditya; Briane, Anouk; Halpert, Jonathan E.; Broch, Katharina; Hodgkiss, Justin M.; Friend, Richard H.; Deschler, Felix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hot-carrier cooling and photoinduced refractive index changes in organic-inorganic lead halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-halide perovskites are at the frontier of optoelectronic research due to solution processability and excellent semiconductor properties. Here we use transient absorption spectroscopy to study hot-carrier distributions in CH3NH3PbI3 and quantify key semiconductor parameters. Above bandgap, non-resonullt excitation creates quasi-thermalized carrier distributions within 100 fs. During carrier cooling, a sub-bandgap transient absorption signal arises at similar to 1.6 eV, which is explained by the interplay of bandgap renormalization and hot-carrier distributions. At higher excitation densities, a 'phonon bottleneck' substantially slows carrier cooling. This effect indicates a low contribution from inelastic carrier-impurity or phonon-impurity scattering in these polycrystalline materials, which supports high charge-carrier mobilities. Photoinduced reflectivity changes distort the shape of transient absorption spectra and must be included to extract physical constants. Using a simple band-filling model that accounts for these changes, we determine a small effective mass of m(r) = 0.14 m(o), which agrees with band structure calculations and high photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 553, "Times Cited, All Databases": 596, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8420, "DOI": "10.1038/ncomms9420", "DOI Link": "http://dx.doi.org/10.1038/ncomms9420", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363139900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brown, MA; Abbas, Z; Kleibert, A; Green, RG; Goel, A; May, S; Squires, TM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brown, Matthew A.; Abbas, Zareen; Kleibert, Armin; Green, Richard G.; Goel, Alok; May, Sylvio; Squires, Todd M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of Surface Potential and Electrical Double-Layer Structure at the Aqueous Electrolyte-nulloparticle Interface", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The structure of the electrical double layer has been debated for well over a century, since it mediates colloidal interactions, regulates surface structure, controls reactivity, sets capacitance, and represents the central element of electrochemical supercapacitors. The surface potential of such surfaces generally exceeds the electrokinetic potential, often substantially. Traditionally, a Stern layer of nonspecifically adsorbed ions has been invoked to rationalize the difference between these two potentials; however, the inability to directly measure the surface potential of dispersed systems has rendered quantitative measurements of the Stern layer potential, and other quantities associated with the outer Helmholtz plane, impossible. Here, we use x-ray photoelectron spectroscopy from a liquid microjet to measure the absolute surface potentials of silica nulloparticles dispersed in aqueous electrolytes. We quantitatively determine the impact of specific cations (Li+, Na+, K+, and Cs+) in chloride electrolytes on the surface potential, the location of the shear plane, and the capacitance of the Stern layer. We find that the magnitude of the surface potential increases linearly with the hydrated-cation radius. Interpreting our data using the simplest assumptions and most straightforward understanding of Gouy-Chapman-Stern theory reveals a Stern layer whose thickness corresponds to a single layer of water molecules hydrating the silica surface, plus the radius of the hydrated cation. These results subject electrical double-layer theories to direct and falsifiable tests to reveal a physically intuitive and quantitatively verified picture of the Stern layer that is consistent across multiple electrolytes and solution conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2016, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11007, "DOI": "10.1103/PhysRevX.6.011007", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.6.011007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369335400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tokunaga, Y; Yu, XZ; White, JS; Ronnow, HM; Morikawa, D; Taguchi, Y; Tokura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tokunaga, Y.; Yu, X. Z.; White, J. S.; Ronnow, H. M.; Morikawa, D.; Taguchi, Y.; Tokura, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new class of chiral materials hosting magnetic skyrmions beyond room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skyrmions, topologically protected vortex-like nullometric spin textures in magnets, have been attracting increasing attention for emergent electromagnetic responses and possible technological applications for spintronics. In particular, metallic magnets with chiral and cubic/tetragonal crystal structure may have high potential to host skyrmions that can be driven by low electrical current excitation. However, experimental observations of skyrmions have been limited to below room temperature for the metallic chiral magnets, specifically for the MnSi-type B20 compounds. Towards technological applications, transcending this limitation is crucial. Here we demonstrate the formation of skyrmions with unique spin helicity both at and above room temperature in a family of cubic chiral magnets: beta-Mn-type Co-Zn-Mn alloys with a different chiral space group from that of B20 compounds. Lorentz transmission electron microscopy, magnetization and small-angle neutron scattering measurements unambiguously reveal formation of a skyrmion crystal under application of a magnetic field in both thin-plate and bulk forms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7638, "DOI": "10.1038/ncomms8638", "DOI Link": "http://dx.doi.org/10.1038/ncomms8638", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358857800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, N; Yang, X; Zhang, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, null; Yang, Xin; Zhang, Xinxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrarobust subzero healable materials enabled by polyphenol nullo-assemblies", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-healing materials hold great promise for applications in wearable electronics, artificial muscles and soft robots but selfhealing at subzero temperatures remains a great challenge. Here, the authors present a robust subzero healable glassy polymer by incorporating polyphenol nullo-assemblies with a large number of end groups into polymerizable deep eutectic solvent elastomers. Bio-inspired self-healing materials hold great promise for applications in wearable electronics, artificial muscles and soft robots, etc. However, self-healing at subzero temperatures remains a great challenge because the reconstruction of interactions will experience resistance of the frozen segments. Here, we present an ultrarobust subzero healable glassy polymer by incorporating polyphenol nullo-assemblies with a large number of end groups into polymerizable deep eutectic solvent elastomers. The combination of multiple dynamic bonds and rapid secondary relaxations with low activation energy barrier provides a promising method to overcome the limited self-healing ability of glassy polymers, which can rarely be achieved by conventional dynamic cross-linking. The resulted material exhibits remarkably improved adhesion force at low temperature (promotes 30 times), excellent mechanical properties (30.6 MPa) and desired subzero healing efficiencies (85.7% at -20 degrees C). We further demonstrated that the material also possesses reliable cryogenic strain-sensing and functional-healing ability. This work provides a viable approach to fabricate ultrarobust subzero healable glassy polymers that are applicable for winter sports wearable devices, subzero temperature-suitable robots and artificial muscles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 814, "DOI": "10.1038/s41467-023-36461-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36461-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001009851700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hwang, MT; Heiranian, M; Kim, Y; You, S; Leem, J; Taqieddin, A; Faramarzi, V; Jing, YH; Park, I; van der Zande, AM; Nam, S; Aluru, NR; Bashir, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hwang, Michael Taeyoung; Heiranian, Mohammad; Kim, Yerim; You, Seungyong; Leem, Juyoung; Taqieddin, Amir; Faramarzi, Vahid; Jing, Yuhang; Park, Insu; van der Zande, Arend M.; Nam, Sungwoo; Aluru, Narayana R.; Bashir, Rashid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive detection of nucleic acids using deformed graphene channel field effect biosensors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Field-effect transistor (FET)-based biosensors allow label-free detection of biomolecules by measuring their intrinsic charges. The detection limit of these sensors is determined by the Debye screening of the charges from counter ions in solutions. Here, we use FETs with a deformed monolayer graphene channel for the detection of nucleic acids. These devices with even millimeter scale channels show an ultra-high sensitivity detection in buffer and human serum sample down to 600 zM and 20 aM, respectively, which are similar to 18 and similar to 600 nucleic acid molecules. Computational simulations reveal that the nulloscale deformations can form 'electrical hot spots' in the sensing channel which reduce the charge screening at the concave regions. Moreover, the deformed graphene could exhibit a band-gap, allowing an exponential change in the source-drain current from small numbers of charges. Collectively, these phenomena allow for ultrasensitive electronic biomolecular detection in millimeter scale structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1543, "DOI": "10.1038/s41467-020-15330-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15330-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530024800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsao, YC; Lee, M; Miller, EC; Gao, GP; Park, J; Chen, SC; Katsumata, T; Tran, H; Wang, LW; Toney, MF; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsao, Yuchi; Lee, Minah; Miller, Elizabeth C.; Gao, Guoping; Park, Jihye; Chen, Shucheng; Katsumata, Toru; Tran, Helen; Wang, Lin-Wang; Toney, Michael F.; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing a Quinone-Based Redox Mediator to Facilitate Li2S Oxidation in Li-S Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In lithium-sulfur (Li-S) batteries, the insulating nature of sulfur and lithium sulfide (Li2S) results in large polarization and low sulfur utilization while the soluble polysulfides lead to internal shuttle upon cycling. Furthermore, the redox reaction via the dissolution-precipitation route destroys the electrode architecture by passivating the active interface responsible for the redox reaction, and thus the performance deteriorates with cycling. Here, we employ the redox chemistry of quinone to realize efficient, fast, and stable operation of Li-S batteries using Li2S microparticles. By adding a quinone derivative with tailored properties (e.g., oxidation potential, solubility, and electrochemical stability) to an electrolyte as a redox mediator (RM), initial charging of Li2S electrodes occurs below 2.5V at 0.5C, and the subsequent discharge capacity is as high as 1,300 mAh gs(-1). Moreover, deposition of dead Li2S, which was the primary cause of increasing polarization and decreasing capacity upon cycling, is effectively prevented with the RM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 872, "End Page": 884, "Article Number": null, "DOI": "10.1016/j.joule.2018.12.018", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.12.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462010600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ballesteros, LF; Ramirez, MJ; Orrego, CE; Teixeira, JA; Mussatto, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ballesteros, Lina F.; Ramirez, Monica J.; Orrego, Carlos E.; Teixeira, Jose A.; Mussatto, Solange I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encapsulation of antioxidant phenolic compounds extracted from spent coffee grounds by freeze-drying and spray-drying using different coating materials", "Source Title": "FOOD CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Freeze-drying and spray-drying techniques were evaluated for encapsulation of phenolic compounds (PC) extracted from spent coffee grounds. Additionally, the use of maltodextrin, gum arabic and a mixture of these components (ratio 1: 1) as wall material to retain the PC and preserve their antioxidant activity was also assessed. The contents of PC and flavonoids (FLA), as well as the antioxidant activity of the encapsulated samples were determined in order to verify the efficiency of each studied condition. Additional analyses for characterization of the samples were also performed. Both the technique and the coating material greatly influenced the encapsulation of antioxidant PC. The best results were achieved when PC were encapsulated by freeze-drying using maltodextrin as wall material. Under these conditions, the amount of PC and FLA retained in the encapsulated sample corresponded to 62% and 73%, respectively, and 73-86% of the antioxidant activity present in the original extract was preserved. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2017, "Volume": 237, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 623, "End Page": 631, "Article Number": null, "DOI": "10.1016/j.foodchem.2017.05.142", "DOI Link": "http://dx.doi.org/10.1016/j.foodchem.2017.05.142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology; Nutrition & Dietetics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406199900077", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, PQ; Zhang, SQ; Chen, ZH; Xu, Y; Cui, Y; Zhang, T; Ren, JZ; Qin, JZ; Hong, L; Hao, XT; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Pengqing; Zhang, Shaoqing; Chen, Zhihao; Xu, Ye; Cui, Yong; Zhang, Tao; Ren, Junzhen; Qin, Jinzhao; Hong, Ling; Hao, Xiaotao; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced non-radiative charge recombination enables organic photovoltaic cell approaching 19% efficiency", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing non-radiative charge recombination is of critical importance to achieving high- performance organic photovoltaic (OPV) cells. The correlation between the exciton behaviors and non-radiative charge recombination is rarely studied. In this work, we achieved an increase in the exciton diffusion length (L-D) in the acceptor phase via introducing HDO-4Cl to the PBDB-TF: eC9-based system. Compared with the eC9-based film, the exciton L-D in the HDO- 4Cl: eC9-based film is increased from 12.2 to 16.3 nm. The enlarged exciton L-D can obviously decrease the non- radiative charge recombination and increase the efficiency of photon utilization in the PBDB-TF: eC9-based OPV cell. Finally, we not only obtained an outstanding power conversion efficiency (PCE) of 18.86% but also demonstrated the correlations between the nonradiative energy loss and exciton behaviors. The results show that regulating the exciton behaviors is an effective way to reduce the non-radiative energy loss and realize high-efficiency OPV cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2021, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2408, "End Page": 2419, "Article Number": null, "DOI": "10.1016/j.joule.2021.06.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.06.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696854300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, B; Yu, ZS; Liu, K; Zheng, XP; Liu, Y; Shi, JW; Spronk, D; Rudd, PN; Holman, Z; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Bo; Yu, Zhengshan; Liu, Kong; Zheng, Xiaopeng; Liu, Ye; Shi, Jianwei; Spronk, Derrek; Rudd, Peter N.; Holman, Zachary; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain Engineering for Perovskite/Silicon Monolithic Tandem Solar Cells with Efficiency of 25.4%", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic halide perovskites are promising semiconductors to mate with silicon in tandem photovoltaic cells due to their solution processability and tunable complementary bandgaps. Herein, we show that a combination of two additives, MACl and MAH(2)PO(2), in the perovskite precursor can significantly improve the grain morphology of wide-bandgap (1.64-1.70 eV) perovskite films, resulting in solar cells with increased photocurrent while reducing the open-circuit voltage deficit to 0.49-0.51 V. The addition of MACl enlarges the grain size, while MAH(2)PO(2) reduces non-radiative recombination through passivation of the perovskite grain boundaries, with good synergy of functions from MACl and MAH(2)PO(2). Matching the photocurrent between the two subcells in a perovskite/silicon monolithic tandem solar cell by using a bandgap of 1.64 eV for the top cell results in a high tandem V-oc of 1.80 V and improved power conversion efficiency of 25.4%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 177, "End Page": 190, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, YK; Wu, Y; Zhou, XC; Ye, YF; Nie, KQ; Wang, JO; Xie, M; Zhang, ZX; Liu, ZJ; Cheng, T; Gao, CB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yuke; Wu, Yu; Zhou, Xichen; Ye, Yifan; Nie, Kaiqi; Wang, Jiaou; Xie, Miao; Zhang, Zhixue; Liu, Zhaojun; Cheng, Tao; Gao, Chuanbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting nickel oxidation state transitions in single-layer NiFeB hydroxide nullosheets for efficient oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Promoting the formation of high-oxidation-state transition metal species in a hydroxide catalyst may improve its catalytic activity in the oxygen evolution reaction, which remains difficult to achieve with current synthetic strategies. Herein, we present a synthesis of single-layer NiFeB hydroxide nullosheets and demonstrate the efficacy of electron-deficient boron in promoting the formation of high-oxidation-state Ni for improved oxygen evolution activity. Raman spectroscopy, X-ray absorption spectroscopy, and electrochemical analyses show that incorporation of B into a NiFe hydroxide causes a cathodic shift of the Ni2+(OH)(2) -> Ni3+delta OOH transition potential. Density functional theory calculations suggest an elevated oxidation state for Ni and decreased energy barriers for the reaction with the NiFeB hydroxide catalyst. Consequently, a current density of 100 mA cm(-2) was achieved in 1 M KOH at an overpotential of 252 mV, placing it among the best Ni-based catalysts for this reaction. This work opens new opportunities in electronic engineering of metal hydroxides (or oxides) for efficient oxygen evolution in water-splitting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6094, "DOI": "10.1038/s41467-022-33846-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33846-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874078400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sachs, M; Sprick, RS; Pearce, D; Hillman, SAJ; Monti, A; Guilbert, AAY; Brownbill, NJ; Dimitrov, S; Shi, XY; Blanc, F; Zwijnenburg, MA; Nelson, J; Durrant, JR; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sachs, Michael; Sprick, Reiner Sebastian; Pearce, Drew; Hillman, Sam A. J.; Monti, Adriano; Guilbert, Anne A. Y.; Brownbill, Nick J.; Dimitrov, Stoichko; Shi, Xingyuan; Blanc, Frederic; Zwijnenburg, Martijn A.; Nelson, Jenny; Durrant, James R.; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding structure-activity relationships in linear polymer photocatalysts for hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymers have sparked much interest as photocatalysts for hydrogen production. However, beyond basic considerations such as spectral absorption, the factors that dictate their photocatalytic activity are poorly understood. Here we investigate a series of linear conjugated polymers with external quantum efficiencies for hydrogen production between 0.4 and 11.6%. We monitor the generation of the photoactive species from femtoseconds to seconds after light absorption using transient spectroscopy and correlate their yield with the measured photocatalytic activity. Experiments coupled with modeling suggest that the localization of water around the polymer chain due to the incorporation of sulfone groups into an otherwise hydrophobic backbone is crucial for charge generation. Calculations of solution redox potentials and charge transfer free energies demonstrate that electron transfer from the sacrificial donor becomes thermodynamically favored as a result of the more polar local environment, leading to the production of long-lived electrons in these amphiphilic polymers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4968, "DOI": "10.1038/s41467-018-07420-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07420-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451047900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gnullasekaran, K; Heijmans, T; van Bennekom, S; Woldhuis, H; Wijnia, S; de With, G; Friedrich, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gnullasekaran, K.; Heijmans, T.; van Bennekom, S.; Woldhuis, H.; Wijnia, S.; de With, G.; Friedrich, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of CNT-and graphene-based conductive polymer nullocomposites by fused deposition modeling", "Source Title": "APPLIED MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused deposition modeling (FDM) is limited by the availability of application specific functional materials. Here we illustrate printing of non-conventional polymer nullocomposites (CNT- and graphene-based polybutylene terephthalate (PBT)) on a commercially available desktop 3D printer leading toward printing of electrically conductive structures. The printability, electrical conductivity and mechanical stability of the polymer nullocomposites before and after 3D printing was evaluated. The results show that 3D printed PBT/CNT objects have better conductive and mechanical properties and a better performance than 3D printed PBT/graphene structures. In addition to that, printing more than one material (multi materials) and challenges in using abrasive conductive fillers (i.e., CNT and graphene) are also discussed. Overall this study demonstrates that a commercially available desktop 3D printer can be used to fabricate low-cost functional objects. (C) 2017 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21, "End Page": 28, "Article Number": null, "DOI": "10.1016/j.apmt.2017.04.003", "DOI Link": "http://dx.doi.org/10.1016/j.apmt.2017.04.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417805400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, WK; Xie, SH; Lin, HL; Zhang, GJ; Wu, H; Hu, TG; Wang, Z; Zhang, XM; Xu, JH; Wang, YJ; Zheng, YH; Yan, FG; Zhang, J; Zhao, LX; Patané, A; Zhang, J; Chang, HX; Wang, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Wenkai; Xie, Shihong; Lin, Hailong; Zhang, Gaojie; Wu, Hao; Hu, Tiangui; Wang, Ziao; Zhang, Xiaomin; Xu, Jiahan; Wang, Yujing; Zheng, Yuanhui; Yan, Faguang; Zhang, Jing; Zhao, Lixia; Patane, Amalia; Zhang, Jia; Chang, Haixin; Wang, Kaiyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large Room-Temperature Magnetoresistance in van der Waals Ferromagnet/Semiconductor Junctions", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A magnetic tunnel junction (MTJ) is the core component in memory technologies, such as the magnetic random-access memory, magnetic sensors and programmable logic devices. In particular, MTJs based on two-dimensional van der Waals (vdW) heterostructures offer unprecedented opportunities for low power consumption and miniaturization of spintronic devices. However, their operation at room temperature remains a challenge. Here, we report a large tunnel magnetoresistance (TMR) of up to 85% at room temperature (T = 300 K) in vdW MTJs based on a thin (< 10 nm) semiconductor spacer WSe2 layer embedded between two Fe3GaTe2 electrodes with intrinsic above-room-temperature ferromagnetism. The TMR in the MTJ increases with decreasing temperature up to 164% at T = 10 K. The demonstration of TMR in ultra-thin MTJs at room temperature opens a realistic and promising route for next-generation spintronic applications beyond the current state of the art.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2022, "Volume": 39, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 128501, "DOI": "10.1088/0256-307X/39/12/128501", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/39/12/128501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000890238500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HT; Mao, J; Li, YW; Sun, JF; Wang, YM; Zhu, Q; Li, GN; Song, QC; Zhou, JW; Fu, YH; He, R; Tong, T; Liu, ZH; Ren, WY; You, L; Wang, ZM; Luo, J; Sotnikov, A; Bao, JM; Nielsch, K; Chen, G; Singh, DJ; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Hangtian; Mao, Jun; Li, Yuwei; Sun, Jifeng; Wang, Yumei; Zhu, Qing; Li, Guannull; Song, Qichen; Zhou, Jiawei; Fu, Yuhao; He, Ran; Tong, Tian; Liu, Zihang; Ren, Wuyang; You, Li; Wang, Zhiming; Luo, Jun; Sotnikov, Andrei; Bao, Jiming; Nielsch, Kornelius; Chen, Gang; Singh, David J.; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of TaFeSb-based half-Heuslers with high thermoelectric performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discovery of thermoelectric materials has long been realized by the Edisonian trial and error approach. However, recent progress in theoretical calculations, including the ability to predict structures of unknown phases along with their thermodynamic stability and functional properties, has enabled the so-called inverse design approach. Compared to the traditional materials discovery, the inverse design approach has the potential to substantially reduce the experimental efforts needed to identify promising compounds with target functionalities. By adopting this approach, here we have discovered several unreported half-Heusler compounds. Among them, the p-type TaFeSb-based half-Heusler demonstrates a record high ZT of -1.52 at 973 K. Additionally, an ultrahigh average ZT of -0.93 between 300 and 973 K is achieved. Such an extraordinary thermoelectric performance is further verified by the heatto- electricity conversion efficiency measurement and a high efficiency of -11.4% is obtained. Our work demonstrates that the TaFeSb-based half-Heuslers are highly promising for thermoelectric power generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 270, "DOI": "10.1038/s41467-018-08223-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08223-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455953600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, WQ; Wei, Z; Li, RZ; Li, ZH; Shi, R; Ouyang, SX; Qi, YH; Philips, DL; Yuan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Weiqin; Wei, Zhen; Li, Ruizhe; Li, Zhenhua; Shi, Run; Ouyang, Shuxin; Qi, Yuhang; Philips, David Lee; Yuan, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subsurface oxygen defects electronically interacting with active sites on In2O3 for enhanced photothermocatalytic CO2 reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "How to effectively extract electrons from subsurface oxygen defects is challenging in heterogeneous catalysis. Here the authors demonstrate that Metallic In-embedded In2O3 nulloflake catalyst promotes the delocalization of electrons among subsurface oxygen defects, obviously increasing electron density of surface active sites. Oxygen defects play an important role in many catalytic reactions. Increasing surface oxygen defects can be done through reduction treatment. However, excessive reduction blocks electron channels and deactivates the catalyst surface due to electron-trapped effects by subsurface oxygen defects. How to effectively extract electrons from subsurface oxygen defects which cannot directly interact with reactants is challenging and remains elusive. Here, we report a metallic In-embedded In2O3 nulloflake catalyst over which the turnover frequency of CO2 reduction into CO increases by a factor of 866 (7615 h(-1)) and 376 (2990 h(-1)) at the same light intensity and reaction temperature, respectively, compared to In2O3. Under electron-delocalization effect of O-In-(O)V-o-In-In structural units at the interface, the electrons in the subsurface oxygen defects are extracted and gather at surface active sites. This improves the electronic coupling with CO2 and stabilizes intermediate. The study opens up new insights for exquisite electronic manipulation of oxygen defects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3199, "DOI": "10.1038/s41467-022-30958-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30958-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809423400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sherkar, TS; Momblona, C; Gil-Escrig, L; Avila, J; Sessolo, M; Bolink, HJ; Koster, LJA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sherkar, Tejas S.; Momblona, Cristina; Gil-Escrig, Lidon; Avila, Jorge; Sessolo, Michele; Bolink, Henk J.; Koster, L. Jan Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recombination in Perovskite Solar Cells: Significance of Grain Boundaries, Interface Traps, and Defect Ions", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Trap-assisted recombination, despite being lower as compared with traditional inorganic solar cells, is still the dominullt recombination mechanism in perovskite solar cells (PSCs) and limits their efficiency. We investigate the attributes of the primary trap assisted recombination channels (grain boundaries and interfaces) and their correlation to defect ions in PSCs. We achieve this by using a validated device model to fit the simulations to the experimental data of efficient vacuum-deposited p-i-n and n-i-p CH3NH3PbI3 solar cells, including the light intensity dependence of the open circuit voltage and fill factor. We find that, despite the presence of traps at interfaces and grain boundaries (GBs), their neutral (when filled with photogenerated charges) disposition along with the long-lived nature of holes leads to the high performance of PSCs. The sign of the traps (when filled) is of little importance in efficient solar cells with compact morphologies (fused GBs, low trap density). On the other hand, solar cells with noncompact morphologies (open GBs, high trap density) are sensitive to the sign of the traps and hence to the cell preparation methods. Even in the presence of traps at GBs, trap-assisted recombination at interfaces (between the transport layers and the perovskite) is the dominullt loss mechanism. We find a direct correlation between the density of traps, the density of mobile ionic defects, and the degree of hysteresis observed in the current voltage (J-V) characteristics. The presence of defect states or mobile ions not only limits the device performance but also plays a role in the J-V hysteresis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 917, "Times Cited, All Databases": 955, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1214, "End Page": 1222, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00236", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00236", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401500200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YS; Yang, J; Fang, MM; Yu, YS; Zou, B; Wang, LW; Tian, Y; Cheng, JX; Tang, BZ; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yunsheng; Yang, Jie; Fang, Manman; Yu, Yishuai; Zou, Bo; Wang, Liwei; Tian, Yu; Cheng, Jingxi; Tang, Ben Zhong; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Forster Resonullce Energy Transfer: An Efficient WaytoDevelop Stimulus-Responsive Room-Temperature Phosphorescence Materials and Their Applications", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, Forster resonullce energy transfer (FRET) is utilized to construct a stimulus-responsive room-temperature phosphorescence (RTP) system. Owing to the specificity of the FRET system and its sensitivity to distance, the resultant material shows turn-on persistent RTP emission upon force or heating stimulus. Furthermore, a near-perfect compatibility with existing printing technology is demonstrated for this material, especially for thermal printing. This finding could provide a simple, efficient, and truly commercially viable construction strategy for RTP material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2020, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 449, "End Page": 463, "Article Number": null, "DOI": "10.1016/j.matt.2020.05.005", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2020.05.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555892900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CY; Liang, SJ; Wang, S; Wang, PF; Li, Z; Wang, ZR; Gao, AY; Pan, C; Liu, C; Liu, J; Yang, HF; Liu, XW; Song, WH; Wang, C; Wang, XM; Chen, KJ; Wang, ZL; Watanabe, K; Taniguchi, T; Yang, JJ; Miao, F; Cheng, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chen-Yu; Liang, Shi-Jun; Wang, Shuang; Wang, Pengfei; Li, Zhu'an; Wang, Zhongrui; Gao, Anyuan; Pan, Chen; Liu, Chuan; Liu, Jian; Yang, Huafeng; Liu, Xiaowei; Song, Wenhao; Wang, Cong; Wang, Xiaomu; Chen, Kunji; Wang, Zhenlin; Watanabe, Kenji; Taniguchi, Takashi; Yang, J. Joshua; Miao, Feng; Cheng, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable van der Waals heterostructure for reconfigurable neural network vision sensor", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Early processing of visual information takes place in the human retina. Mimicking neurobiological structures and functionalities of the retina provides a promising pathway to achieving vision sensor with highly efficient image processing. Here, we demonstrate a prototype vision sensor that operates via the gate-tunable positive and negative photoresponses of the van der Waals (vdW) vertical heterostructures. The sensor emulates not only the neurobiological functionalities of bipolar cells and photoreceptors but also the unique connectivity between bipolar cells and photoreceptors. By tuning gate voltage for each pixel, we achieve reconfigurable vision sensor for simultaneous image sensing and processing. Furthermore, our prototype vision sensor itself can be trained to classify the input images by updating the gate voltages applied individually to each pixel in the sensor. Our work indicates that vdW vertical heterostructures offer a promising platform for the development of neural network vision sensor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba6173", "DOI": "10.1126/sciadv.aba6173", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba6173", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543504100028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Xu, HY; Wang, SY; Huang, TQ; Xi, JB; Cai, SY; Guo, F; Xu, Z; Gao, WW; Gao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Xu, Hanyan; Wang, Siyao; Huang, Tieqi; Xi, Jiabin; Cai, Shengying; Guo, Fan; Xu, Zhen; Gao, Weiwei; Gao, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast all-climate aluminum-graphene battery with quarter-million cycle life", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aluminum-ion batteries are promising in high-power density but still face critical challenges of limited lifetime, rate capability, and cathodic capacity. We design a trihigh tricontinuous (3H3C) graphene film cathode with features of high quality, orientation, and channeling for local structures (3H) and continuous electron-conducting matrix, ion-diffusion highway, and electroactivemass for the whole electrode (3C). Such a cathode retains high specific capacity of around 120 mAh g(-1) at ultrahigh current density of 400 A g(-1) (charged in 1.1 s) with 91.7% retention after 250,000 cycles, surpassing all the previous batteries in terms of rate capability and cycle life. The assembled aluminum-graphene battery works well within a wide temperature range of -40 to 120 degrees C with remarkable flexibility bearing 10,000 times of folding, promising for all-climate wearable energy devices. This design opens an avenue for a future super-batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao7233", "DOI": "10.1126/sciadv.aao7233", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao7233", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418003100036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Lin, DY; Wang, H; Car, R; E, WN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linfeng; Lin, De-Ye; Wang, Han; Car, Roberto; E, Weinull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active learning of uniformly accurate interatomic potentials for materials simulation", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An active learning procedure called deep potential generator (DP-GEN) is proposed for the construction of accurate and transferable machine learning-based models of the potential energy surface (PES) for the molecular modeling of materials. This procedure consists of three main components: exploration, generation of accurate reference data, and training. Application to the sample systems of Al, Mg, and Al-Mg alloys demonstrates that DP-GEN can produce uniformly accurate PES models with a minimal number of reference data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 470, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2019, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 23804, "DOI": "10.1103/PhysRevMaterials.3.023804", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.3.023804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459927600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ping, P; Peng, RQ; Kong, DP; Chen, GM; Wen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ping, Ping; Peng, Rongqi; Kong, Depeng; Chen, Guoming; Wen, Jennifer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation on thermal management performance of PCM-fin structure for Li-ion battery module in high-temperature environment", "Source Title": "ENERGY CONVERSION AND MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The safety, performance and durability of the Li-ion battery module are limited by the operating temperature especially in the hot temperature regions, hence the thermal management system is essential for battery module. In this paper a novel phase change material (PCM) and fin structure was proposed for the thermal management system of LiFePO4 battery module to reduce the maximum temperature and improve the temperature uniformity in high-temperature environment (40 degrees C). Carefully designed experiments were performed for model validation. The effects of PCM species, fin thickness, fin spacing and PCM thickness on the cooling performance of battery module were investigated numerically. The results showed that PCM-fin structure thermal management system with optimized design exhibited good thermal performance, keeping the maximum temperature of the battery surface under 51 degrees C at relatively high discharge rate of 3C. Moreover, by investigating the thermal behavior of PCM during discharge process and cycle test, it has been found that PCM-fin structure has the advantage of improving natural convection and heat conduction within the PCM structure, and as a result enhances heat dissipation efficiency and reduces failure risk in passive thermal management systems using PCMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2018, "Volume": 176, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 131, "End Page": 146, "Article Number": null, "DOI": "10.1016/j.enconman.2018.09.025", "DOI Link": "http://dx.doi.org/10.1016/j.enconman.2018.09.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447578400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, GC; Wu, B; Wu, XY; Li, MJ; Du, B; Wei, Q; Guo, J; Yeow, EKL; Sum, TC; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Guichuan; Wu, Bo; Wu, Xiangyang; Li, Mingjie; Du, Bin; Wei, Qi; Guo, Jia; Yeow, Edwin K. L.; Sum, Tze Chien; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transcending the slow bimolecular recombination in lead-halide perovskites for electroluminescence", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The slow bimolecular recombination that drives three-dimensional lead-halide perovskites' outstanding photovoltaic performance is conversely a fundamental limitation for electroluminescence. Under electroluminescence working conditions with typical charge densities lower than 10(15) cm(-3), defect-states trapping in three-dimensional perovskites competes effectively with the bimolecular radiative recombination. Herein, we overcome this limitation using van-der-Waals-coupled Ruddlesden-Popper perovskite multi-quantum-wells. Injected charge carriers are rapidly localized from adjacent thin few layer (n <= 4) multi-quantum-wells to the thick (n >= 5) multi-quantum-wells with extremely high efficiency (over 85%) through quantum coupling. Light emission originates from excitonic recombination in the thick multi-quantum-wells at much higher decay rate and efficiency than bimolecular recombination in three-dimensional perovskites. These multi-quantum-wells retain the simple solution processability and high charge carrier mobility of two-dimensional lead-halide perovskites. Importantly, these Ruddlesden-Popper perovskites offer new functionalities unavailable in single phase constituents, permitting the transcendence of the slow bimolecular recombination bottleneck in lead-halide perovskites for efficient electroluminescence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 527, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14558, "DOI": "10.1038/ncomms14558", "DOI Link": "http://dx.doi.org/10.1038/ncomms14558", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394796300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oehzelt, M; Koch, N; Heimel, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oehzelt, Martin; Koch, Norbert; Heimel, Georg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic semiconductor density of states controls the energy level alignment at electrode interfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Minimizing charge carrier injection barriers and extraction losses at interfaces between organic semiconductors and metallic electrodes is critical for optimizing the performance of organic (opto-) electronic devices. Here, we implement a detailed electrostatic model, capable of reproducing the alignment between the electrode Fermi energy and the transport states in the organic semiconductor both qualitatively and quantitatively. Covering the full phenomenological range of interfacial energy level alignment regimes within a single, consistent framework and continuously connecting the limiting cases described by previously proposed models allows us to resolve conflicting views in the literature. Our results highlight the density of states in the organic semiconductor as a key factor. Its shape and, in particular, the energy distribution of electronic states tailing into the fundamental gap is found to determine both the minimum value of practically achievable injection barriers as well as their spatial profile, ranging from abrupt interface dipoles to extended band-bending regions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4174, "DOI": "10.1038/ncomms5174", "DOI Link": "http://dx.doi.org/10.1038/ncomms5174", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338838500030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Domanski, K; Roose, B; Matsui, T; Saliba, M; Turren-Cruz, SH; Correa-Baena, JP; Roldán-Carmona, C; Richardson, G; Foster, JM; De Angelis, F; Ball, JM; Petrozza, A; Mine, N; Nazeeruddin, MK; Tress, W; Grätzel, M; Steiner, U; Hagfeldt, A; Abate, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Domanski, Konrad; Roose, Bart; Matsui, Taisuke; Saliba, Michael; Turren-Cruz, Silver-Hamill; Correa-Baena, Juan-Pablo; Roldan-Carmona, Cristina; Richardson, Giles; Foster, Jamie M.; De Angelis, Filippo; Ball, James M.; Petrozza, Annamaria; Mine, Nicolas; Nazeeruddin, Mohammad K.; Tress, Wolfgang; Gratzel, Michael; Steiner, Ullrich; Hagfeldt, Anders; Abate, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskites have been demonstrated in solar cells with a power conversion efficiency of well above 20%, which makes them one of the strongest contenders for next generation photovoltaics. While there are no concerns about their efficiency, very little is known about their stability under illumination and load. Ionic defects and their migration in the perovskite crystal lattice are some of the most alarming sources of degradation, which can potentially prevent the commercialization of perovskite solar cells (PSCs). In this work, we provide direct evidence of electric field-induced ionic defect migration and we isolate their effect on the long-term performance of state-of-the-art devices. Supported by modelling, we demonstrate that ionic defects, migrating on timescales significantly longer (above 10(3) s) than what has so far been explored (from 10(-1) to 10(2) s), abate the initial efficiency by 10-15% after several hours of operation at the maximum power point. Though these losses are not negligible, we prove that the initial efficiency is fully recovered when leaving the device in the dark for a comparable amount of time. We verified this behaviour over several cycles resembling day/night phases, thus probing the stability of PSCs under native working conditions. This unusual behaviour reveals that research and industrial standards currently in use to assess the performance and the stability of solar cells need to be adjusted for PSCs. Our work paves the way for much needed new testing protocols and figures of merit specifically designed for PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 567, "Times Cited, All Databases": 600, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 604, "End Page": 613, "Article Number": null, "DOI": "10.1039/c6ee03352k", "DOI Link": "http://dx.doi.org/10.1039/c6ee03352k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395679100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prasanna, R; Leijtens, T; Dunfield, SP; Raiford, JA; Wolf, EJ; Swifter, SA; Werner, J; Eperon, GE; de Paula, C; Palmstrom, AF; Boyd, CC; van Hest, MFAM; Bent, SF; Teeter, G; Berry, JJ; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prasanna, Rohit; Leijtens, Tomas; Dunfield, Sean P.; Raiford, James A.; Wolf, Eli J.; Swifter, Simon A.; Werner, Jeremie; Eperon, Giles E.; de Paula, Camila; Palmstrom, Axel F.; Boyd, Caleb C.; van Hest, Maikel F. A. M.; Bent, Stacey F.; Teeter, Glenn; Berry, Joseph J.; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of low bandgap tin-lead halide perovskite solar cells to achieve thermal, atmospheric and operational stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low bandgap tin-lead iodide perovskites are key components of all-perovskite tandem solar cells, but can be unstable because tin is prone to oxidation. Here, to avoid a reaction with the most popular hole contact, we eliminated polyethylenedioxythioph ene:polystyrenesulfonate as a hole transport layer and instead used an upward band offset at an indium tin oxide-perovskite heterojunction to extract holes. To suppress oxidative degradation, we improved the morphology to create a compact and large-grained film. The tin content was kept at or below 50% and the device capped with a sputtered indium zinc oxide electrode. These advances resulted in a substantially improved thermal and environmental stability in a low bandgap perovskite solar cell without compromising the efficiency. The solar cells retained 95% of their initial efficiency after 1,000 h at 85 degrees C in air in the dark with no encapsulation and in a damp heat test (85 degrees C with 85% relative humidity) with encapsulation. The full initial efficiency was maintained under operation near the maximum power point and near 1 sun illumination for over 1,000h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 939, "End Page": 947, "Article Number": null, "DOI": "10.1038/s41560-019-0471-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0471-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496958300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, F; Borodin, O; Ding, MS; Gobet, M; Vatamanu, J; Fan, XL; Gao, T; Edison, N; Liang, YJ; Sun, W; Greenbaum, S; Xu, K; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Fei; Borodin, Oleg; Ding, Michael S.; Gobet, Mallory; Vatamanu, Jenel; Fan, Xiulin; Gao, Tao; Edison, Nico; Liang, Yujia; Sun, Wei; Greenbaum, Steve; Xu, Kang; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Aqueous/Non-aqueous Electrolyte for Safe and High-Energy Li-Ion Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent breakthroughs in aqueous electrolytes made highly safe 3.0 V class aqueous Li-ion batteries possible. However, the formed solid-electrolyte interphase therein still cannot effectively support the desired energy-dense anode and cathode materials. In this work, we report a new class of electrolytes, by hybridizing aqueous with non-aqueous solvents, that inherits the non-flammability and non-toxicity characteristics from aqueous and better electrochemical stability from non-aqueous systems. The secondary interphasial ingredient (alkylcarbonate) introduced by non-aqueous component helps to expand the electrochemical window of the hybridized electrolyte to 4.1 V, which supports the operation of a 3.2 V aqueous Li-ion battery based on Li4Ti5O12 and LiNi0.5Mn1.5O4 to deliver a high energy density of 165 Wh/kg for >1,000 cycles. The understanding of how a better interphase could be tailored by regulating the inner-Helmholtz interfacial structures of the hybridized electrolyte provides important guidelines for designing future electrolytes and interphases for new battery chemistries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 348, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 927, "End Page": 937, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rui, N; Wang, XL; Deng, KX; Moncada, J; Rosales, R; Zhang, F; Xu, WQ; Waluyo, I; Hunt, A; Stavitski, E; Senullayake, SD; Liu, P; Rodriguez, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rui, Ning; Wang, Xuelong; Deng, Kaixi; Moncada, Jorge; Rosales, Rina; Zhang, Feng; Xu, Wenqian; Waluyo, Iradwikanari; Hunt, Adrian; Stavitski, Eli; Senullayake, Sanjaya D.; Liu, Ping; Rodriguez, Jose A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Structural Origin of the High Methanol Selectivity over In2O3-Metal Interfaces: Metal-Support Interactions and the Formation of a InOX Overlayer in Ru/In2O3 Catalysts during CO2 Hydrogenation", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 hydrogenation to methanol is of great environmental and economic interest due to its potential to reduce carbon emissions and produce valuable chemicals in one single reaction. Compared with the unmodified traditional Cu/ZnO/Al2O3 catalyst, an indium oxide (In2O3)-based catalyst can double the methanol selectivity from 30-50 to 60-100%. It is worth noting that over catalysts involving various active metals dispersed on indium oxide (M/In2O3, M = Pd, Ni, Au, etc.), although the methanol yield is boosted, the selectivity remains similar to that of plain In2O3 despite the distinct chemical properties of the added metals. To investigate the phenomena behind this behavior, here we used RuO2/In2O3 as a test catalyst. The results of ambient pressure photoelectron spectroscopy, in situ X-ray absorption fine structure, and time-resolved X-ray diffraction indicate that the structure of the RuO2/In2O3 catalyst is highly dynamic in the presence of a reactive environment. Specifically, under CO2 hydrogenation conditions, Ru clusters facilitate the reduction of In2O3 to generate In2O3-x aggregates, which encapsulate the Ru systems in a migration driven by thermodynamics. In this way, the Ru-0 sites for CH4 production are blocked while creating RuOx-In2O3-x interfacial sites with tunable metal-oxide interactions for selective methanol production. In an inverse oxide/metal configuration, indium oxide has properties not seen in its bulk phase that are useful for the binding and conversion of CO2. This work reveals the dynamic nature of In2O3-based catalysts, providing insights for a rational design of materials for the selective synthesis of methanol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 FEB 17", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acscatal.2c06029", "DOI Link": "http://dx.doi.org/10.1021/acscatal.2c06029", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000944488900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, ZY; Zimmerman, AM; Ledwith, P; Khalaf, E; Najafabadi, DH; Watanabe, K; Taniguchi, T; Vishwanath, A; Kim, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Zeyu; Zimmerman, A. M.; Ledwith, Patrick; Khalaf, Eslam; Najafabadi, Danial Haie; Watanabe, Kenji; Taniguchi, Takashi; Vishwanath, Ashvin; Kim, Philip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric field-tunable superconductivity in alternating-twist magic-angle trilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering moire superlattices by twisting layers in van der Waals (vdW) heterostructures has uncovered a wide array of quantum phenomena. We constructed a vdW heterostructure that consists of three graphene layers stacked with alternating twist angles +/- theta. At the average twist angle theta similar to 1.56 degrees, a theoretically predicted magic angle for the formation of flat electron bands, we observed displacement field-tunable superconductivity with a maximum critical temperature of 2.1 kelvin. By tuning the doping level and displacement field, we found that superconducting regimes occur in conjunction with flavor polarization of moire bands and are bounded by a van Hove singularity (vHS) at high displacement fields. Our findings display inconsistencies with a weak coupling description, suggesting that the observed moire superconductivity has an unconventional nature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2021, "Volume": 371, "Issue": 6534, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1133, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg0399", "DOI Link": "http://dx.doi.org/10.1126/science.abg0399", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630096400029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Darling, RM; Gallagher, KG; Kowalski, JA; Ha, S; Brushett, FR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Darling, Robert M.; Gallagher, Kevin G.; Kowalski, Jeffrey A.; Ha, Seungbum; Brushett, Fikile R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy storage is increasingly seen as a valuable asset for electricity grids composed of high fractions of intermittent sources, such as wind power or, in developing economies, unreliable generation and transmission services. However, the potential of batteries to meet the stringent cost and durability requirements for grid applications is largely unquantified. We investigate electrochemical systems capable of economically storing energy for hours and present an analysis of the relationships among technological performance characteristics, component cost factors, and system price for established and conceptual aqueous and nonaqueous batteries. We identified potential advantages of nonaqueous flow batteries over those based on aqueous electrolytes; however, new challenging constraints burden the nonaqueous approach, including the solubility of the active material in the electrolyte. Requirements in harmony with economically effective energy storage are derived for aqueous and nonaqueous systems. The attributes of flow batteries are compared to those of aqueous and nonaqueous enclosed and hybrid (semi-flow) batteries. Flow batteries are a promising technology for reaching these challenging energy storage targets owing to their independent power and energy scaling, reliance on facile and reversible reactants, and potentially simpler manufacture as compared to established enclosed batteries such as lead-acid or lithium-ion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 665, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2014, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3459, "End Page": 3477, "Article Number": null, "DOI": "10.1039/c4ee02158d", "DOI Link": "http://dx.doi.org/10.1039/c4ee02158d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343974700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, RM; Jiang, ZY; Yang, C; Yu, JW; Feng, JR; Adil, MA; Deng, D; Zou, WJ; Zhang, JQ; Lu, K; Ma, W; Gao, F; Wei, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Ruimin; Jiang, Zhaoyan; Yang, Chen; Yu, Jianwei; Feng, Jirui; Adil, Muhammad Abdullah; Deng, Dan; Zou, Wenjun; Zhang, Jianqi; Lu, Kun; Ma, Wei; Gao, Feng; Wei, Zhixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-small-molecule organic solar cells with over 14% efficiency by optimizing hierarchical morphologies", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high efficiency all-small-molecule organic solar cells (OSCs) normally require optimized morphology in their bulk heterojunction active layers. Herein, a small-molecule donor is designed and synthesized, and single-crystal structural analyses reveal its explicit molecular planarity and compact intermolecular packing. A promising narrow bandgap small-molecule with absorption edge of more than 930 nm along with our home-designed small molecule is selected as electron acceptors. To the best of our knowledge, the binary all-small-molecule OSCs achieve the highest efficiency of 14.34% by optimizing their hierarchical morphologies, in which the donor or acceptor rich domains with size up to ca. 70 nm, and the donor crystals of tens of nullometers, together with the donor-acceptor blending, are proved coexisting in the hierarchical large domain. All-small-molecule photovoltaic system shows its promising for high performance OSCs, and our study is likely to lead to insights in relations between bulk heterojunction structure and photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5393, "DOI": "10.1038/s41467-019-13292-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13292-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498696700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, HD; Wang, QY; El-Awady, JA; Raabe, D; Zaiser, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Haidong; Wang, Qingyuan; El-Awady, Jaafar A.; Raabe, Dierk; Zaiser, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain rate dependency of dislocation plasticity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dislocation glide is a general deformation mode, governing the strength of metals. Via discrete dislocation dynamics and molecular dynamics simulations, we investigate the strain rate and dislocation density dependence of the strength of bulk copper and aluminum single crystals. An analytical relationship between material strength, dislocation density, strain rate and dislocation mobility is proposed, which agrees well with current simulations and published experiments. Results show that material strength displays a decreasing regime (strain rate hardening) and then increasing regime (classical forest hardening) as the dislocation density increases. Accordingly, the strength displays universally, as the strain rate increases, a strain rate-independent regime followed by a strain rate hardening regime. All results are captured by a single scaling function, which relates the scaled strength to a coupling parameter between dislocation density and strain rate. Such coupling parameter also controls the localization of plasticity, fluctuations of dislocation flow and distribution of dislocation velocity. The relationship between the strain rate and micro-scale deformation in metals is still poorly understood. Here the authors use discrete dislocation dynamics and molecular dynamics to establish a universal relationship between material strength, dislocation density, strain rate and dislocation mobility in fcc metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1845, "DOI": "10.1038/s41467-021-21939-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21939-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684714900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alsalloum, AY; Turedi, B; Almasabi, K; Zheng, XP; Naphade, R; Stranks, SD; Mohammed, OF; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alsalloum, Abdullah Y.; Turedi, Bekir; Almasabi, Khulud; Zheng, Xiaopeng; Naphade, Rounak; Stranks, Samuel D.; Mohammed, Omar F.; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "22.8%-Efficient single-crystal mixed-cation inverted perovskite solar cells with a near-optimal bandgap", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Expanding the near-infrared (NIR) response of perovskite materials to approach the ideal bandgap range (1.1-1.4 eV) for single-junction solar cells is an attractive step to unleash the full potential of perovskite solar cells (PSCs). However, polycrystalline formamidinium lead triiodide (FAPbI(3))-based absorbers, used in record-efficiency PSCs, currently offer the smallest bandgap that can be achieved for lead-halide perovskite thin films (>100 meV larger than the optimal bandgap). Here, we uncover that utilizing a mixed-cation single-crystal absorber layer (FA(0.6)MA(0.4)PbI(3)) is capable of redshifting the external quantum efficiency (EQE) band edge past that of FAPbI(3) polycrystalline solar cells by about 50 meV - only 60 meV larger than that of the top-performing photovoltaic material, GaAs - leading to EQE-verified short-circuit current densities exceeding 26 mA cm(-2) without sacrificing the open-circuit voltage (V-OC), and therefore, yielding power conversion efficiencies of up to 22.8%. These figures of merit not only set a new record for SC-PSCs and are among the highest reported for inverted-structured-PSCs, but also offer an avenue for lead halide PSCs to advance their performance toward their theoretical Shockley-Queisser Limit potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2021, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2263, "End Page": 2268, "Article Number": null, "DOI": "10.1039/d0ee03839c", "DOI Link": "http://dx.doi.org/10.1039/d0ee03839c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642435400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noël, P; Trier, F; Arche, LVM; Bréhin, J; Vaz, DC; Garcia, V; Fusil, S; Barthélémy, A; Vila, L; Bibes, M; Attané, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noel, Paul; Trier, Felix; Vicente Arche, Luis M.; Brehin, Julien; Vaz, Diogo C.; Garcia, Vincent; Fusil, Stephane; Barthelemy, Agnes; Vila, Laurent; Bibes, Manuel; Attane, Jean-Philippe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-volatile electric control of spin-charge conversion in a SrTiO3 Rashba system", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The polarization direction of a ferroelectric-like state can be used to control the conversion of spin currents into charge currents at the surface of strontium titanate, a non-magnetic oxide. After 50 years of development, the technology of today's electronics is approaching its physical limits, with feature sizes smaller than 10 nullometres. It is also becoming clear that the ever-increasing power consumption of information and communication systems(1) needs to be contained. These two factors require the introduction of non-traditional materials and state variables. As recently highlighted(2), the remanence associated with collective switching in ferroic systems is an appealing way to reduce power consumption. A promising approach is spintronics, which relies on ferromagnets to provide non-volatility and to generate and detect spin currents(3). However, magnetization reversal by spin transfer torques(4) is a power-consuming process. This is driving research on multiferroics to achieve low-power electric-field control of magnetization(5), but practical materials are scarce and magnetoelectric switching remains difficult to control. Here we demonstrate an alternative strategy to achieve low-power spin detection, in a non-magnetic system. We harness the electric-field-induced ferroelectric-like state of strontium titanate (SrTiO3)(6-9) to manipulate the spin-orbit properties(10) of a two-dimensional electron gas(11), and efficiently convert spin currents into positive or negative charge currents, depending on the polarization direction. This non-volatile effect opens the way to the electric-field control of spin currents and to ultralow-power spintronics, in which non-volatility would be provided by ferroelectricity rather than by ferromagnetism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 580, "Issue": 7804, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 483, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2197-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2197-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528065800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YT; Xu, YF; Xu, T; Wang, HX; Jiang, JH; Hu, X; Hang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yuting; Xu, Yun Fei; Xu, Tao; Wang, Hai-Xiao; Jiang, Jian-Hua; Hu, Xiao; Hang, Zhi Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization of a Unidirectional Electromagnetic Waveguide Using Topological Photonic Crystals Made of Dielectric Materials", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate experimentally that a photonic crystal made of Al2O3 cylinders exhibits topological time--reversal symmetric electromagnetic propagation, similar to the quantum spin Hall effect in electronic systems. A pseudospin degree of freedom in the electromagnetic system representing different states of orbital angular momentum arises due to a deformation of the photonic crystal from the ideal honeycomb lattice. It serves as the photonic analogue to the electronic Kramers pair. We visualized qualitatively and measured quantitatively that microwaves of a specific pseudospin propagate only in one direction along the interface between a topological photonic crystal and a trivial one. As only a conventional dielectric material is used and only local real--space manipulations are required, our scheme can be extended to visible light to inspire many future applications in the field of photonics and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2018, "Volume": 120, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 217401, "DOI": "10.1103/PhysRevLett.120.217401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.217401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433039600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, YX; Baniya, S; Zhang, C; Li, JW; Haney, P; Sheng, CX; Ehrenfreund, E; Vardeny, ZV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Yaxin; Baniya, Sangita; Zhang, Chuang; Li, Junwen; Haney, Paul; Sheng, Chuan-Xiang; Ehrenfreund, Eitan; Vardeny, Zeev Valy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant Rashba splitting in 2D organic-inorganic halide perovskites measured by transient spectroscopies", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) layered hybrid organic-inorganic halide perovskite semiconductors form natural multiple quantum wells that have strong spin-orbit coupling due to the heavy elements in their building blocks. This may lead to Rashba splitting close to the extrema in the electron bands. We have used a plethora of ultrafast transient, nonlinear optical spectroscopies and theoretical calculations to study the primary (excitons) and long-lived (free carriers) photoexcitations in thin films of 2D perovskite, namely, (C6H5C2H4NH3)(2)PbI4. The density functional theory calculation shows the occurrence of Rashba splitting in the plane perpendicular to the 2D barrier. From the electroabsorption spectrum and photoinduced absorption spectra from excitons and free carriers, we obtain a giant Rashba splitting in this compound, with energy splitting of (40 +/- 5) meV and Rashba parameter of (1.6 +/- 0.1) eV.angstrom, which are among the highest Rashba splitting size parameters reported so far. This finding shows that 2D hybrid perovskites have great promise for potential applications in spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 454, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700704", "DOI": "10.1126/sciadv.1700704", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700704", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411588000046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ward, L; Dunn, A; Faghaninia, A; Zimmermann, NER; Bajaj, S; Wang, Q; Montoya, J; Chen, JM; Bystrom, K; Dylla, M; Chard, K; Asta, M; Persson, KA; Snyder, GJ; Foster, I; Jain, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ward, Logan; Dunn, Alexander; Faghaninia, Alireza; Zimmermann, Nils E. R.; Bajaj, Saurabh; Wang, Qi; Montoya, Joseph; Chen, Jiming; Bystrom, Kyle; Dylla, Maxwell; Chard, Kyle; Asta, Mark; Persson, Kristin A.; Snyder, G. Jeffrey; Foster, Ian; Jain, Anubhav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Matminer: An open source toolkit for materials data mining", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As materials data sets grow in size and scope, the role of data mining and statistical learning methods to analyze these materials data sets and build predictive models is becoming more important. This manuscript introduces matminer, an open-source, Python-based software platform to facilitate data-driven methods of analyzing and predicting materials properties. Matminer provides modules for retrieving large data sets from external databases such as the Materials Project, Citrination, Materials Data Facility, and Materials Platform for Data Science. It also provides implementations for an extensive library of feature extraction routines developed by the materials community, with 47 featurization classes that can generate thousands of individual descriptors and combine them into mathematical functions. Finally, matminer provides a visualization module for producing interactive, shareable plots. These functions are designed in a way that integrates closely with machine learning and data analysis packages already developed and in use by the Python data science community. We explain the structure and logic of matminer, provide a description of its various modules, and showcase several examples of how matminer can be used to collect data, reproduce data mining studies reported in the literature, and test new methodologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 680, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 152, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 60, "End Page": 69, "Article Number": null, "DOI": "10.1016/j.commatsci.2018.05.018", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2018.05.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439718700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pfeifer, V; Jones, TE; Vélez, JJV; Massué, C; Arrigo, R; Teschner, D; Girgsdies, F; Scherzer, M; Greiner, MT; Allan, J; Hashagen, M; Weinberg, G; Piccinin, S; Hävecker, M; Knop-Gericke, A; Schlögl, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pfeifer, Verena; Jones, Travis E.; Velez, Juan J. Velasco; Massue, Cyriac; Arrigo, Rosa; Teschner, Detre; Girgsdies, Frank; Scherzer, Michael; Greiner, Mark T.; Allan, Jasmin; Hashagen, Maike; Weinberg, Gisela; Piccinin, Simone; Haevecker, Michael; Knop-Gericke, Axel; Schloegl, Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The electronic structure of iridium and its oxides", "Source Title": "SURFACE AND INTERFACE ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iridium-based materials are among the most active and stable electrocatalysts for the oxygen evolution reaction. Amorphous iridium oxide structures are found to be more active than their crystalline counterparts. Herein, we combine synchrotron-based X-ray photoemission and absorption spectroscopies with theoretical calculations to investigate the electronic structure of Ir metal, rutile-type IrO2, and an amorphous IrOx. Theory and experiment show that while the Ir 4f line shape of Ir metal is well described by a simple Doniach-Sunji function, the peculiar line shape of rutile-type IrO2 requires the addition of a shake-up satellite 1eV above the main line. In the catalytically more active amorphous IrOx, we find that additional intensity appears in the Ir 4f spectrum at higher binding energy when compared with rutile-type IrO2 along with a pre-edge feature in the O K-edge. We identify these additional features as electronic defects in the anionic and cationic frameworks, namely, formally OI- and Ir-III, which may explain the increased activity of amorphous IrOx electrocatalysts. We corroborate our findings by in situ X-ray diffraction as well as in situ X-ray photoemission and absorption spectroscopies. Copyright (c) 2015 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 48, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 261, "End Page": 273, "Article Number": null, "DOI": "10.1002/sia.5895", "DOI Link": "http://dx.doi.org/10.1002/sia.5895", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373935900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guria, AK; Dutta, SK; Das Adhikari, S; Pradhan, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guria, Amit K.; Dutta, Sumit K.; Das Adhikari, Samrat; Pradhan, Narayan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping Mn2+ in Lead Halide Perovskite nullocrystals: Successes and Challenges", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mn2+ ions doped in high-energy absorbing semiconductor host nullocrystals take away the exciton energy and result in spin-polarized d-d emission. For the last three decades this has been widely studied on group II-VI semiconductors. Recently, the doping has been extended to CsPbX3 perovskite nullocrystals. Although the optical transition follows a similar principle, in which the exciton energy is transferred to dopant Mn d-state, doping in perovskite also revealed several new fundamental aspects of doping and dopant-induced new optical properties. Here, anions which mostly tune the band gap controlled the fate of the appearance of Mn emission. Also, the doping process was observed to be different than traditional growth doping. Hence, in perovskite host nullocrystals, while some aspects of Mn doping are found to be in agreement with previous findings, some new facts also surfaced. Combining all these facts, this Perspective focuses on the journey of Mn doping from group II-VI semiconductors to lead halide perovskite nullostructures and provides an outline for plausible future studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1014, "End Page": 1021, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00177", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00177", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401500200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Errea, I; Calandra, M; Pickard, CJ; Nelson, JR; Needs, RJ; Li, YW; Liu, HY; Zhang, YW; Ma, YM; Mauri, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Errea, Ion; Calandra, Matteo; Pickard, Chris J.; Nelson, Joseph R.; Needs, Richard J.; Li, Yinwei; Liu, Hanyu; Zhang, Yunwei; Ma, Yanming; Mauri, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum hydrogen-bond symmetrization in the superconducting hydrogen sulfide system", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantum nature of the proton can crucially affect the structural and physical properties of hydrogen compounds. For example, in the high-pressure phases(1,2) of H2O, quantum proton fluctuations lead to symmetrization of the hydrogen bond and reduce the boundary between asymmetric and symmetric structures in the phase diagram by 30 gigapascals (ref. 3). Here we show that an analogous quantum symmetrization occurs in the recently discovered(4) sulfur hydride superconductor with a superconducting transition temperature T-c of 203 kelvin at 155 gigapascals-the highest T-c reported for any superconductor so far. Superconductivity occurs via the formation of a compound with chemical formula H3S (sulfur trihydride) with sulfur atoms arranged on a body-centred cubic lattice(5-9). If the hydrogen atoms are treated as classical particles, then for pressures greater than about 175 gigapascals they are predicted to sit exactly halfway between two sulfur atoms in a structure with Im (3) over barm symmetry. At lower pressures, the hydrogen atoms move to an off-centre position, forming a short H-S covalent bond and a longer H center dot center dot center dot S hydrogen bond in a structure with R3m symmetry(5-9). X-ray diffraction experiments confirm the H3S stoichiometry and the sulfur lattice sites, but were unable to discriminate between the two phases(10). Ab initio density-functional-theory calculations show that quantum nuclear motion lowers the symmetrization pressure by 72 gigapascals for H3S and by 60 gigapascals for D3S. Consequently, we predict that the Im (3) over barm phase dominates the pressure range within which the high T-c was measured. The observed pressure dependence of T-c is accurately reproduced in our calculations for the Im (3) over barm phase, but not for the R3m phase. Therefore, the quantum nature of the proton fundamentally changes the superconducting phase diagram of H3S.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2016, "Volume": 532, "Issue": 7597, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature17175", "DOI Link": "http://dx.doi.org/10.1038/nature17175", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373555500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carvalho, OQ; Marks, R; Nguyen, HKK; Vitale-Sullivan, ME; Martinez, SC; Arnadottir, L; Stoerzinger, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carvalho, O. Quinn; Marks, Rylee; Nguyen, Hoan K. K.; Vitale-Sullivan, Molly E.; Martinez, Selena C.; Arnadottir, Liney; Stoerzinger, Kelsey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of Electronic Structure on Nitrate Reduction to Ammonium: A Periodic Journey", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysis is a promising approach to convert waste nitrate to ammonia and help close the nitrogen cycle. This renewably powered ammonia production process sources hydrogen from water (as opposed to methane in the thermal Haber-Bosch process) but requires a delicate balance between a catalyst's activity for the hydrogen evolution reaction (HER) and the nitrate reduction reaction (NO3RR), influencing the Faradaic efficiency (FE) and selectivity to ammonia/ammonium over other nitrogen-containing products. We measure ammonium FEs ranging from 3.6 +/- 6.6% (on Ag) to 93.7 +/- 0.9% (on Co) across a range of transition metals (TMs; Ti, Fe, Co, Ni, Ni0.68Cu0.32, Cu, and Ag) in buffered neutral media. To better understand these competing reaction kinetics, we develop a microkinetic model that captures the voltage-dependent nitrate rate order and illustrates its origin as competitive adsorption between nitrate and hydrogen adatoms (H*). NO3RR FE can be described via competition for electrons with the HER, decreasing sharply for TMs with a high work function and a correspondingly high HER activity (e.g., Ni). Ammonium selectivity nominally increases as the TM d-band center energy (E-d) approaches and overcomes the Fermi level (E-F), but is exceptionally high for Co compared to materials with similar E-d. Density functional theory (DFT) calculations indicate Co maximizes ammonium selectivity via (1) strong nitrite binding enabling subsequent reduction and (2) promotion of nitric oxide dissociation, leading to selective reduction of the nitrogen adatom (N*) to ammonium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 AUG 4", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c05673", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c05673", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000844622400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rong, XH; Hu, EY; Lu, YX; Meng, FQ; Zhao, CL; Wang, XL; Zhang, QH; Yu, XQ; Gu, L; Hu, YS; Li, H; Huang, XJ; Yang, XQ; Delmas, C; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rong, Xiaohui; Hu, Enyuan; Lu, Yaxiang; Meng, Fanqi; Zhao, Chenglong; Wang, Xuelong; Zhang, Qinghua; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Li, Hong; Huang, Xuejie; Yang, Xiao-Qing; Delmas, Claude; Chen, Liquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anionic Redox Reaction-Induced High-Capacity and Low-Strain Cathode with Suppressed Phase Transition", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered metal oxides have attracted widespread attention as cathodes for Na-ion batteries (NIBs) because of easy synthesis, high specific capacity, and high energy density. However, most reported layered oxides suffer from complex phase transitions upon a large amount of Na deintercalation. Here we report a P2-type Na-0.72[Li0.24Mn0.76]O-2, exhibiting exceptionally high initial charge capacity of similar to 210 mAh/g (0.72 Na) based on a pure anionic redox reaction (ARR). Surprisingly, global P2 structure can be maintained with minimal volume change (1.35%) upon complete removal of Na+ ions. This is due to the reduced Coulombic repulsion associated with ARR and consequent suppression of the phase transition as observed in other P2 materials. Here we reveal for the first time that ARR has the functionality of stabilizing the structure, in addition to its role in increasing its already known capacity. This would pave the way for the further improvement of high-energy-density NIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 503, "End Page": 517, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.022", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460076100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, K; Zhang, XY; Wang, J; Li, X; Chen, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Kan; Zhang, Xiaoyan; Wang, Jun; Li, Xing; Chen, Jianping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WS2 as a saturable absorber for ultrafast photonic applications of mode-locked and Q-switched lasers", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) nullomaterials, especially the transition metal sulfide semiconductors, have drawn great interests due to their potential applications in viable photonic and optoelectronic devices. In this work, 2D tungsten disulfide (WS2) based saturable absorber (SA) for ultrafast photonic applications was demonstrated. WS2 nullosheets were prepared using liquid-phase exfoliation method and embedded in polyvinyl alcohol (PVA) thin film for the practical usage. Saturable absorption was discovered in the WS2-PVA SA at the telecommunication wavelength near 1550 nm. By incorporating WS2-PVA SA into a fiber laser cavity, both stable mode locking operation and Q-switching operation were achieved. In the mode locking operation, the laser obtained femtosecond output pulse width and high spectral purity in the radio frequency spectrum. In the Q-switching operation, the laser had tunable repetition rate and output pulse energy of a few tens of nullo joule. Our findings suggest that few-layer WS2 nullosheets embedded in PVA thin film are promising nonlinear optical materials for ultrafast photonic applications as a mode locker or Q-switcher. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2015, "Volume": 23, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11453, "End Page": 11461, "Article Number": null, "DOI": "10.1364/OE.23.011453", "DOI Link": "http://dx.doi.org/10.1364/OE.23.011453", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354337700057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CY; Ma, QY; Hung, SF; Chen, ZN; Ou, DH; Ren, B; Chen, HM; Fu, G; Zheng, NF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Chengyi; Ma, Qiuyu; Hung, Sung-Fu; Chen, Zhe-Ning; Ou, Daohui; Ren, Bin; Chen, Hao Ming; Fu, Gang; Zheng, nullfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Electrochemical Production of Ultrathin Nickel nullosheets for Hydrogen Evolution Electrocatalysis", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) nullosheets (NSs) of a Ni-S coordination polymer have been successfully synthesized with the use of 2D Ni(OH)(2) NSs grown on conductive carbon cloth as the template and 1,4-benzenedithiol as the ligand. In situ X-ray absorption spectroscopy revealed that the as-prepared catalyst was entirely transformed into ultrathin Ni NSs under alkaline reductive conditions. The in-situ-generated catalysts exhibited superior activity toward the hydrogen evolution reaction (HER) with an overpotential of 80 mV to reach 10 mA cm(-2). Studies revealed that the large-area ultrathin Ni NSs served as active sites for H-2 generation, and the trace sulfur adsorbed on the Ni surface promoted water dissociation. This work has developed a templating approach for preparing highly active HER electrocatalysts and identified the real active sites under electrocatalytic conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2017, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 122, "End Page": 133, "Article Number": null, "DOI": "10.1016/j.chempr.2017.05.011", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.05.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408622000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hahn, C; Hatsukade, T; Kim, YG; Vailionis, A; Baricuatro, JH; Higgins, DC; Nitopi, SA; Soriaga, MP; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hahn, Christopher; Hatsukade, Toru; Kim, Youn-Geun; Vailionis, Arturas; Baricuatro, Jack H.; Higgins, Drew C.; Nitopi, Stephanie A.; Soriaga, Manuel P.; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Cu surfaces for the electrocatalytic conversion of CO2: Controlling selectivity toward oxygenates and hydrocarbons", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study we control the surface structure of Cu thin-film catalysts to probe the relationship between active sites and catalytic activity for the electroreduction of CO2 to fuels and chemicals. Here, we report physical vapor deposition of Cu thin films on large-format (similar to 6 cm(2)) single-crystal substrates, and confirm epitaxial growth in the < 100 >, < 111 >, and < 751 > orientations using X-ray pole figures. To understand the relationship between the bulk and surface structures, in situ electrochemical scanning tunneling microscopy was conducted on Cu(100), (111), and (751) thin films. The studies revealed that Cu(100) and (111) have surface adlattices that are identical to the bulk structure, and that Cu(751) has a heterogeneous kinked surface with (110) terraces that is closely related to the bulk structure. Electrochemical CO2 reduction testing showed that whereas both Cu(100) and (751) thin films are more active and selective for C-C coupling than Cu(111), Cu(751) is the most selective for >2e(-) oxygenate formation at low overpotentials. Our results demonstrate that epitaxy can be used to grow single-crystal analogous materials as large-format electrodes that provide insights on controlling electrocatalytic activity and selectivity for this reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2017, "Volume": 114, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5918, "End Page": 5923, "Article Number": null, "DOI": "10.1073/pnas.1618935114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1618935114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402703800047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tringides, CM; Vachicouras, N; de Lazaro, I; Wang, H; Trouillet, A; Seo, BR; Elosegui-Artola, A; Fallegger, F; Shin, Y; Casiraghi, C; Kostarelos, K; Lacour, SP; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tringides, Christina M.; Vachicouras, Nicolas; de Lazaro, Irene; Wang, Hua; Trouillet, Alix; Seo, Bo Ri; Elosegui-Artola, Alberto; Fallegger, Florian; Shin, Yuyoung; Casiraghi, Cinzia; Kostarelos, Kostas; Lacour, Stephanie P.; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Viscoelastic surface electrode arrays to interface with viscoelastic tissues", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioelectronic interfacing with living tissues should match the biomechanical properties of biological materials to reduce damage to the tissues. Here, the authors present a fully viscoelastic microelectrode array composed of an alginate matrix and carbon-based nullomaterials encapsulated in a viscoelastic hydrogel for electrical stimulation and signal recording of heart and brain activities in vivo. Living tissues are non-linearly elastic materials that exhibit viscoelasticity and plasticity. Man-made, implantable bioelectronic arrays mainly rely on rigid or elastic encapsulation materials and stiff films of ductile metals that can be manipulated with microscopic precision to offer reliable electrical properties. In this study, we have engineered a surface microelectrode array that replaces the traditional encapsulation and conductive components with viscoelastic materials. Our array overcomes previous limitations in matching the stiffness and relaxation behaviour of soft biological tissues by using hydrogels as the outer layers. We have introduced a hydrogel-based conductor made from an ionically conductive alginate matrix enhanced with carbon nullomaterials, which provide electrical percolation even at low loading fractions. Our combination of conducting and insulating viscoelastic materials, with top-down manufacturing, allows for the fabrication of electrode arrays compatible with standard electrophysiology platforms. Our arrays intimately conform to the convoluted surface of the heart or brain cortex and offer promising bioengineering applications for recording and stimulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 16, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1019, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-021-00926-z", "DOI Link": "http://dx.doi.org/10.1038/s41565-021-00926-z", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662819200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Czerwieniec, R; Leitl, MJ; Homeier, HHH; Yersin, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Czerwieniec, Rafal; Leitl, Markus J.; Homeier, Herbert H. H.; Yersin, Hartmut", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu(I) complexes - Thermally activated delayed fluorescence. Photophysical approach and material design", "Source Title": "COORDINATION CHEMISTRY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu(I) complexes often show transitions of distinct metal-to-ligand charge transfer (MLCT) character. This can lead to small energy separations between the lowest singlet S-1 and triplet T-1 state. Hence, thermally activated delayed fluorescence (TADF) and, if applied to electroluminescent devices, singlet harvesting can become highly effective. In this contribution, we introduce the TADF mechanism and identify crucial parameters that are necessary to optimize materials' properties, in particular, with respect to short emission decay times and high quantum yields at ambient temperature. In different case studies, we present a photophysical background for a deeper understanding of the materials' properties. Accordingly, we elucidate strategies for obtaining high quantum yields. These are mainly based on enhancing the intrinsic rigidity of the complexes and of their environment. Efficient TADF essentially requires small energy separations Delta E(S-1-T-1) with preference below about 1000 cm(-1) (approximate to 120 meV). This is achievable with complexes that exhibit small spatial HOMO-LUMO overlap. Thus, energy separations below 300 cm(-1) (approximate to 37 meV) are obtained, giving short radiative TADF decay times of less than 5 mu s. In a case study, it is shown that the TADF properties may be tuned or the TADF effect can even be turned off. However, very small Delta E(S-1-T-1) energy separations are related to small radiative rates or small oscillator strengths of the S-1 -> S-0 transitions due to the (required) small HOMO-LUMO overlap, as discussed in a further case study. Moreover, large spin-orbit coupling (SOC) of the triplet state to higher lying singlet states can induce an additional phosphorescence decay path that leads to a luminescence consisting of TADF and phosphorescence, thus leading to a combined, singlet harvesting and triplet harvesting mechanism. This gives an overall reduction of the decay time. Finally, in a strongly simplified model, the SOC efficiency is traced back to easily obtainable results from DFT calculations. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 471, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2016, "Volume": 325, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 2, "End Page": 28, "Article Number": null, "DOI": "10.1016/j.ccr.2016.06.016", "DOI Link": "http://dx.doi.org/10.1016/j.ccr.2016.06.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384865100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mielke, C; Das, D; Yin, JX; Liu, H; Gupta, R; Jiang, YX; Medarde, M; Wu, X; Lei, HC; Chang, J; Dai, PC; Si, Q; Miao, H; Thomale, R; Neupert, T; Shi, Y; Khasanov, R; Hasan, MZ; Luetkens, H; Guguchia, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mielke, C.; Das, D.; Yin, J-X; Liu, H.; Gupta, R.; Jiang, Y-X; Medarde, M.; Wu, X.; Lei, H. C.; Chang, J.; Dai, Pengcheng; Si, Q.; Miao, H.; Thomale, R.; Neupert, T.; Shi, Y.; Khasanov, R.; Hasan, M. Z.; Luetkens, H.; Guguchia, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-reversal symmetry-breaking charge order in a kagome superconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The kagome lattice(1), which is the most prominent structural motif in quantum physics, benefits from inherent non-trivial geometry so that it can host diverse quantum phases, ranging from spin-liquid phases, to topological matter, to intertwined orders(2-8) and, most rarely, to unconventional superconductivity(6,9). Recently, charge sensitive probes have indicated that the kagome superconductors AV(3)Sb(5) (A = K, Rb, Cs)(9-11) exhibit unconventional chiral charge order(12-19), which is analogousto the long-sought-after quantum order in the Haldane model(20) or Varma model(21). However, direct evidence for the time-reversal symmetry breaking of the charge order remains elusive. Here we use muon spin relaxation to probe the kagome charge order and superconductivity in KV3Sb5. We observe a noticeable enhancement of the internal field width sensed by the muon ensemble, which takes place just below the charge orderingtemperature and persists into the superconducting state. Notably, the muon spin relaxation rate below the charge orderingtemperature is substantially enhanced by applying an external magnetic field. We further show the multigap nature of superconductivity in KV3Sb5 and that the T-c/lambda(-2)(ab) ratio (where T-c is the superconducting transition temperature and lambda(ab) is the magnetic penetration depth in the kagome plane) is comparable to those of unconventional high-temperature superconductors. Our results point to time-reversal symmetry-breaking charge order intertwining with unconventional superconductivity in the correlated kagome lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2022, "Volume": 602, "Issue": 7896, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04327-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04327-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753550800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gauthier, A; Symon, S; Clanet, C; Quéré, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gauthier, Anais; Symon, Sean; Clanet, Christophe; Quere, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water impacting on superhydrophobic macrotextures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It has been recently shown that the presence of macrotextures on superhydrophobic materials can markedly modify the dynamics of water impacting them, and in particular significantly reduce the contact time of bouncing drops, compared with what is observed on a flat surface. This finding constitutes a significant step in the maximization of water repellency, since it enables to minimize even further the contact between solid and liquid. It also opens a new axis of research on the design of super-structures to induce specific functions such as anti-freezing, liquid fragmentation and/or recomposition, guiding, trapping and so on. Here we show that the contact time of drops bouncing on a repellent macrotexture takes discrete values when varying the impact speed. This allows us to propose a quantitative analysis of the reduction of contact time and thus to understand how and why macrotextures can control the dynamical properties of bouncing drops.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8001, "DOI": "10.1038/ncomms9001", "DOI Link": "http://dx.doi.org/10.1038/ncomms9001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360351000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Green, MA; Emery, K; Hishikawa, Y; Warta, W; Dunlop, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro; Warta, Wilhelm; Dunlop, Ewan D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar cell efficiency tables (version 46)", "Source Title": "PROGRESS IN PHOTOVOLTAICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined, and new entries since January 2015 are reviewed. Copyright (c) 2015 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 535, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 23, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 805, "End Page": 812, "Article Number": null, "DOI": "10.1002/pip.2637", "DOI Link": "http://dx.doi.org/10.1002/pip.2637", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356369400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cornelissen, LJ; Liu, J; Duine, RA; Ben Youssef, J; van Wees, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cornelissen, L. J.; Liu, J.; Duine, R. A.; Ben Youssef, J.; van Wees, B. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-distance transport of magnon spin information in a magnetic insulator at room temperature", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The transport of spin information has been studied in various materials, such as metals(1), semiconductors(2) and graphene(3). In these materials, spin is transported by the diffusion of conduction electrons(4). Here we study the diffusion and relaxation of spin in a magnetic insulator, where the large bandgap prohibits the motion of electrons. Spin can still be transported, however, through the diffusion of non-equilibrium magnons, the quanta of spin-wave excitations in magnetically ordered materials. Here we show experimentally that these magnons can be excited and detected fully electrically(5-7) in a linear response, and can transport spin angular momentum through the magnetic insulator yttrium iron garnet (YIG) over distances as large as 40 mu m. We identify two transport regimes: the diffusion-limited regime for distances shorter than the magnon spin diffusion length, and the relaxation-limited regime for larger distances. With a model similar to the diffusion-relaxation model for electron spin transport in (semi) conducting materials, we extract the magnon spin diffusion length lambda = 9.4 +/- 0.6 mu m in a thin 200 nm YIG film at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 674, "Times Cited, All Databases": 719, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1022, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3465", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3465", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365898400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, H; Guo, QX; Feng, SY; Zhang, CE; Bi, ZZ; Xue, WY; Yang, JJ; Song, JS; Li, CH; Xu, XJ; Tang, Z; Ma, W; Bo, ZS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Hao; Guo, Qingxin; Feng, Shiyu; Zhang, Cai'e; Bi, Zhaozhao; Xue, Wenyue; Yang, Jinjin; Song, Jinsheng; Li, Cuihong; Xu, Xinjun; Tang, Zheng; Ma, Wei; Bo, Zhishan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Noncovalently fused-ring electron acceptors with near-infrared absorption for high-performance organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-fullerene fused-ring electron acceptors boost the power conversion efficiency of organic solar cells, but they suffer from high synthetic cost and low yield. Here, we show a series of low-cost noncovalently fused-ring electron acceptors, which consist of a ladder-like core locked by noncovalent sulfur-oxygen interactions and flanked by two dicyanoindanone electron-withdrawing groups. Compared with that of similar but unfused acceptor, the presence of ladder-like structure markedly broadens the absorption to the near-infrared region. In addition, the use of intramolecular noncovalent interactions avoids the tedious synthesis of covalently fused-ring structures and markedly lowers the synthetic cost. The optimized solar cells displayed an outstanding efficiency of 13.24%. More importantly, solar cells based on these acceptors demonstrate very low non-radiative energy losses. This research demonstrates that low-cost noncovalently fused-ring electron acceptors are promising to achieve high-efficiency organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3038, "DOI": "10.1038/s41467-019-11001-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11001-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474732500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, SS; Gu, MQ; Verma, M; Harbola, V; Wang, BY; Lu, D; Vailionis, A; Hikita, Y; Pentcheva, R; Rondinelli, JM; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Seung Sae; Gu, Mingqiang; Verma, Manish; Harbola, Varun; Wang, Bai Yang; Lu, Di; Vailionis, Arturas; Hikita, Yasuyuki; Pentcheva, Rossitza; Rondinelli, James M.; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extreme tensile strain states in La0.7Ca0.3MnO3 membranes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A defining feature of emergent phenomena in complex oxides is the competition and cooperation between ground states. In manganites, the balance between metallic and insulating phases can be tuned by the lattice; extending the range of lattice control would enhance the ability to access other phases. We stabilized uniform extreme tensile strain in nulloscale La0.7Ca0.3MnO3 membranes, exceeding 8% uniaxially and 5% biaxially. Uniaxial and biaxial strain suppresses the ferromagnetic metal at distinctly different strain values, inducing an insulator that can be extinguished by a magnetic field. Electronic structure calculations indicate that the insulator consists of charge-ordered Mn4+ and Mn3+ with staggered strain-enhanced Jahn-Teller distortions within the plane. This highly tunable strained membrane approach provides a broad opportunity to design and manipulate correlated electron states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2020, "Volume": 368, "Issue": 6486, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": "aax9753", "DOI": "10.1126/science.aax9753", "DOI Link": "http://dx.doi.org/10.1126/science.aax9753", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000523259700060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pallarés, J; González-Cencerrado, A; Arauzo, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pallares, Javier; Gonzalez-Cencerrado, Ana; Arauzo, Inmaculada", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Production and characterization of activated carbon from barley straw by physical activation with carbon dioxide and steam", "Source Title": "BIOMASS & BIOENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the growth of environmental protection policies has generated an increase in the global demand for activated carbon, the most widely used adsorbent in many industrial sectors, and with good prospects of implementation in others such as energy storage (electrodes in supercapacitors) and agriculture (fertilizer production). This demand is driving by the search for renewable, abundant and low-cost precursor materials, as an alternative to traditional fossil sources. This study investigates the production of activated carbon from barley straw using physical activation method with two different activating agents, carbon dioxide and steam. Experimental tests under different conditions at each stage of the process, carbonization and activation, have been conducted in order to maximize the BET surface area and microporosity of the final product. During the carbonization stage, temperature and heating rate have been found to be the most relevant factors, while activation temperature and hold time played this role during activation. Optimal conditions for the activation stage were obtained at 800 degrees C and a hold time of 1 h in the case of activation with carbon dioxide and at 700 degrees C and a hold time of 1 h in the case of activation with steam. The maximum BET surface area and micropore volume achieved by carbon dioxide activation were of 789 m(2)/g and 0.3268 cm(3)/g while for steam activation were 552 m(2)/g and 0.2304 cm(3)/g, which represent respectively an increase of more than 43% and 42% for the case of activation with carbon dioxide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 115, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 64, "End Page": 73, "Article Number": null, "DOI": "10.1016/j.biombioe.2018.04.015", "DOI Link": "http://dx.doi.org/10.1016/j.biombioe.2018.04.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436609000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, S; Jang, WS; Morozovska, AN; Kwon, O; Jin, Y; Kim, YN; Bae, H; Wane, CX; Yang, SH; Belianinov, A; Randolph, S; Eliseev, EA; Collins, L; Park, Y; Jo, S; Jung, MH; Go, KJ; Cho, HW; Choi, SY; Jang, JH; Kim, S; Jeon, HY; Lee, J; Ovchinnikova, OS; Heo, J; Kalinin, S; Kim, YM; Kim, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Seunghun; Jang, Woo Sung; Morozovska, Anna N.; Kwon, Owoong; Jin, Yeongrok; Kim, Young-Noon; Bae, Hagyoul; Wane, Chenxi; Yang, Sang-Hyeok; Belianinov, Alex; Randolph, Steven; Eliseev, Eugene A.; Collins, Liam; Park, Yeehyun; Jo, Sanghyun; Jung, Min-Hyoung; Go, Kyoung-June; Cho, Hae Won; Choi, Si-Young; Jang, Jae Hyuck; Kim, Sunkook; Jeon, Hu Young; Lee, Jaekwang; Ovchinnikova, Olga S.; Heo, Jinseong; Kalinin, Sergei, V; Kim, Young-Min; Kim, Yunseok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly enhanced ferroelectricity in HfO2-based ferroelectric thin film by light ion bombardment", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous advancement in nonvolatile and morphotropic beyond-Moore electronic devices requires integration of ferroelectric and semiconductor materials. The emergence of hafnium oxide (HfO2)-based ferroelectrics that are compatible with atomic-layer deposition has opened interesting and promising avenues of research. However, the origins of ferroelectricity and pathways to controlling it in HfO2 are still mysterious. We demonstrate that local helium (He) implantation can activate ferroelectricity in these materials. The possible competing mechanisms, including He ion-induced molar volume changes, vacancy redistribution, vacancy generation, and activation of vacancy mobility, are analyzed. These findings both reveal the origins of ferroelectricity in this system and open pathways for nulloengineered binary ferroelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2022, "Volume": 376, "Issue": 6594, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 731, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abk3195", "DOI Link": "http://dx.doi.org/10.1126/science.abk3195", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798488100044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Geisz, JF; France, RM; Schulte, KL; Steiner, MA; Norman, AG; Guthrey, HL; Young, MR; Song, T; Moriarty, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Geisz, John F.; France, Ryan M.; Schulte, Kevin L.; Steiner, Myles A.; Norman, Andrew G.; Guthrey, Harvey L.; Young, Matthew R.; Song, Tao; Moriarty, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Six-junction III-V solar cells with 47.1% conversion efficiency under 143 Suns concentration", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-junction flat-plate terrestrial solar cells are fundamentally limited to about 30% solar-to-electricity conversion efficiency, but multiple junctions and concentrated light make much higher efficiencies practically achievable. Until now, four-junction III-V concentrator solar cells have demonstrated the highest solar conversion efficiencies. Here, we demonstrate 47.1% solar conversion efficiency using a monolithic, series-connected, six-junction inverted metamorphic structure operated under the direct spectrum at 143 Suns concentration. When tuned to the global spectrum, a variation of this structure achieves a 1-Sun global efficiency of 39.2%. Nearly optimal bandgaps for six junctions were fabricated using alloys of III-V semiconductors. To develop these junctions, it was necessary to minimize threading dislocations in lattice-mismatched III-V alloys, prevent phase segregation in metastable quaternary III-V alloys and understand dopant diffusion in complex structures. Further reduction of the series resistance within this structure could realistically enable efficiencies over 50%. Stacking multiple junctions with different bandgaps and operating under concentrated light allows solar cells to reach efficiencies beyond the limits of standard devices. Geisz et al. present a six-junction solar cell based on III-V materials with a 47.1% efficiency-the highest reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 450, "Times Cited, All Databases": 490, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 326, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-020-0598-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0598-5", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526284200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, MH; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Menghao; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sliding ferroelectricity in 2D van der Waals materials: Related physics and future opportunities", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Near the 100th anniversary of the discovery of ferroelectricity, so-called sliding ferroelectricity has been proposed and confirmed recently in a series of experiments that have stimulated remarkable interest. Such ferroelectricity exists widely and exists only in two-dimensional (2D) van der Waals stacked layers, where the vertical electric polarization is switched by in-plane interlayer sliding. Reciprocally, interlayer sliding and the ripplocation domain wall can be driven by an external vertical electric field. The unique combination of intralayer stiffness and interlayer slipperiness of 2D van der Waals layers greatly facilitates such switching while still maintaining environmental and mechanical robustness at ambient conditions. In this perspective, we discuss the progress and future opportunities in this behavior. The origin of such ferroelectricity as well as a general rule for judging its existence are summarized, where the vertical stacking sequence is crucial for its formation. This discovery broadens 2D ferroelectrics from very few material candidates to most of the known 2D materials. Their low switching barriers enable high-speed data writing with low energy cost. Related physics like Moire ferroelectricity, the ferroelectric nonlinear anomalous Hall effect, and multiferroic coupling are discussed. For 2D valleytronics, nontrivial band topology and superconductivity, their possible couplings with sliding ferroelectricity via certain stacking or Moire ferroelectricity also deserve interest. We provide critical reviews on the current challenges in this emerging area.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2021, "Volume": 118, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2115703118", "DOI": "10.1073/pnas.2115703118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2115703118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000732715700052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YF; Rui, GC; Li, Q; Allahyarov, E; Li, RP; Fukuto, M; Zhong, GJ; Xu, JZ; Li, ZM; Taylor, PL; Zhu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yanfei; Rui, Guanchun; Li, Qiong; Allahyarov, Elshad; Li, Ruipeng; Fukuto, Masafumi; Zhong, Gan-Ji; Xu, Jia-Zhuang; Li, Zhong-Ming; Taylor, Philip L.; Zhu, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced piezoelectricity from highly polarizable oriented amorphous fractions in biaxially oriented poly(vinylidene fluoride) with pure β crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezoelectric polymers hold great potential for various electromechanical applications, but only show low performance, with |d(33)|< 30 pC/N. We prepare a highly piezoelectric polymer (d(33)=-62 pC/N) based on a biaxially oriented poly(vinylidene fluoride) (BOPVDF, crystallinity = 0.52). After unidirectional poling, macroscopically aligned samples with pure crystals are achieved, which show a high spontaneous polarization (P-s) of 140 mC/m(2). Given the theoretical limit of P-s,P-beta=188 mC/m(2) for the neat beta crystal, the high P-s cannot be explained by the crystalline-amorphous two-phase model (i.e., P-s,P-beta=270 mC/m(2)). Instead, we deduce that a significant amount (at least 0.25) of an oriented amorphous fraction (OAF) must be present between these two phases. Experimental data suggest that the mobile OAF resulted in the negative and high d(33) for the poled BOPVDF. The plausibility of this conclusion is supported by molecular dynamics simulations. Piezoelectric polymers usually have rather low piezoelectric coefficients less than 30 pC/N. Here, the authors achieve a highly piezoelectric polymer (d(33)=-62 pC/N) based on a poled biaxially oriented poly(vinylidene fluoride) with a pure beta phase due to the mobile oriented amorphous fraction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 675, "DOI": "10.1038/s41467-020-20662-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20662-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684845600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SL; Ma, RG; Hu, JC; Li, ZC; Liu, LJ; Wang, XL; Lu, Y; Sterbinsky, GE; Liu, SH; Zheng, L; Liu, J; Liu, DM; Wang, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shanlin; Ma, Ruguang; Hu, Jingcong; Li, Zichuang; Liu, Lijia; Wang, Xunlu; Lu, Yue; Sterbinsky, George E.; Liu, Shuhu; Zheng, Lei; Liu, Jie; Liu, Danmin; Wang, Jiacheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination environment tuning of nickel sites by oxyanions to optimize methanol electro-oxidation activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve zero-carbon economy, advanced anode catalysts are desirable for hydrogen production and biomass upgrading powered by renewable energy. Ni-based non-precious electrocatalysts are considered as potential candidates because of intrinsic redox attributes, but in-depth understanding and rational design of Ni site coordination still remain challenging. Here, we perform anodic electrochemical oxidation of Ni-metalloids (NiPx, NiSx, and NiSex) to in-situ construct different oxyanion-coordinated amorphous nickel oxyhydroxides (NiOOH-TOx), among which NiOOH-POx shows optimal local coordination environment and boosts electrocatalytic activity of Ni sites towards selective oxidation of methanol to formate. Experiments and theoretical results demonstrate that NiOOH-POx possesses improved adsorption of OH* and methanol, and favors the formation of CH3O* intermediates. The coordinated phosphate oxyanions effectively tailor the d band center of Ni sites and increases Ni-O covalency, promoting the catalytic activity. This study provides additional insights into modulation of active-center coordination environment via oxyanions for organic molecules transformation. Coordination environments around metal sites are important in electrocatalysis. Here, Ni metalloid oxidation produces oxyanion doped amorphous Ni-oxyhydroxides where substitution with phosphorus is found to boost methanol electrooxidation activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2916, "DOI": "10.1038/s41467-022-30670-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30670-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000802797000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Liu, BR; Shen, XJ; Arandiyan, H; Zhao, TW; Li, YB; Garbrecht, M; Su, Z; Han, L; Tricoli, A; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuan; Liu, Borui; Shen, Xiangjian; Arandiyan, Hamidreza; Zhao, Tingwen; Li, Yibing; Garbrecht, Magnus; Su, Zhen; Han, Li; Tricoli, Antonio; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering the Activity and Stability of MOF-nullocomposites for Efficient Water Oxidation", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are considered to be promising candidates for electrochemical water splitting. However, most MOFs are characterized by low electronic conductivity limiting their use as bulk materials for anodes and cathodes. Furthermore, the understanding of the critical parameters controlling the activity and stability of MOF electrocatalysts is still insufficient. Herein, a systematic analysis is presented of the key structural parameters controlling the oxygen evolution reaction (OER) performance and stability of a representative family of bimetallic NiFe-MOFs, where the role of the metal cations on the accessible active sites and intrinsic activity can be investigated independently from the crystal structure. The models and in-depth structural and morphological characterizations reveal a hierarchy of properties affecting the OER activity with accessible sites and intrinsic activity playing a major role in the charge transfer efficiency. Optimization of these properties and addition of a conductive support substrate leads to efficient MOF-nullocomposite electrocatalysts achieving a low overpotential of 258 mV at a current density of 10 mA cm(-2) with a small Tafel slope of 49 mV dec(-1) and excellent stability for more than 32 h of continuous OER in alkaline medium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 11, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003759, "DOI": "10.1002/aenm.202003759", "DOI Link": "http://dx.doi.org/10.1002/aenm.202003759", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000624574200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, W; Zhang, GJ; Wu, H; Yang, L; Zhang, WF; Chang, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Wen; Zhang, Gaojie; Wu, Hao; Yang, Li; Zhang, Wenfeng; Chang, Haixin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature spin-valve devices based on Fe3GaTe2/MoS2/Fe3GaTe2 2D van der Waals heterojunctions", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin-valve effect has been the focus of spintronics over the last decades due to its potential for application in many spintronic devices. Two-dimensional (2D) van der Waals (vdW) materials are highly efficient to build spin-valve heterojunctions. However, the Curie temperatures (T-C) of the vdW ferromagnetic (FM) 2D crystals are mostly below room temperature (similar to 30-220 K). It is very challenging to develop room-temperature, FM 2D crystal-based spin-valve devices. Here, we report room-temperature, FM 2D-crystal-based all-2D vdW Fe3GaTe2/MoS2/Fe3GaTe2 spin-valve devices. The magnetoresistance (MR) of the device was up to 15.89% at 2.3 K and 11.97% at 10 K, which are 4-30 times the MR of the spin valves of Fe3GeTe2/MoS2/Fe3GeTe2 and conventional NiFe/MoS2/NiFe. The typical spin valve effect showed strong dependence on the MoS2 spacer thickness in the vdW heterojunction. Importantly, the spin valve effect (0.31%) robustly existed even at 300 K with low working currents down to 10 nA (0.13 A cm(-2)). This work provides a general vdW platform to develop room-temperature, 2D FM-crystal-based 2D spin-valve devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 45, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2023, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5371, "End Page": 5378, "Article Number": null, "DOI": "10.1039/d2nr06886a", "DOI Link": "http://dx.doi.org/10.1039/d2nr06886a", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937462600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gund, GS; Park, JH; Harpalsinh, R; Kota, M; Shin, JH; Kim, TI; Gogotsi, Y; Park, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gund, Girish Sambhaji; Park, Jeong Hee; Harpalsinh, Rana; Kota, Manikantan; Shin, Joo Hwan; Kim, Tae-il; Gogotsi, Yury; Park, Ho Seok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene/Polymer Hybrid Materials for Flexible AC-Filtering Electrochemical Capacitors", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy storage devices are limited by the trade-off between the transport properties and charge storage ability of materials. Electrolytic capacitors are kinetically fast, operating at kilohertz frequency, but limited by low capacitance. Electrochemical capacitors (ECs) provide high capacitance, yet their sluggish kinetics limit frequency response to a few hertz. Here, we devise strongly interacting, porous MXene/conducting polymer hybrids for large-scale flexible alternating current filtering symmetric ECs with high areal and volumetric capacitances of 0.56mF cm(-2) and 24.2 F cm(-3) at 120 Hz, respectively. The high capacitance was maintained up to 1,000 V s(-1) and originates from synergy of MXene/polymer hybrids. The operation of tandem ECs that filter a pulsating voltage from 60 to 10,000 Hz is demonstrated with device flexibility and durability over 30,000 cycles. These MXene hybrid-based ECs are expected to bridge the performance gap between high capacitance and the high-frequency response toward the form-factor-free miniature and scalable devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 164, "End Page": 176, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Lu, HL; Pi, MH; Zhou, H; Wang, YF; Yan, B; Cui, W; Ran, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Min; Lu, Honglang; Pi, Menghan; Zhou, Hui; Wang, Yufei; Yan, Bin; Cui, Wei; Ran, Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water-Induced Phase Separation for Anti-Swelling Hydrogel Adhesives in Underwater Soft Electronics", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of hydrogel-based underwater electronics has gained significant attention due to their flexibility and portability compared to conventional rigid devices. However, common hydrogels face challenges such as swelling and poor underwater adhesion, limiting their practicality in water environments. Here, a water-induced phase separation strategy to fabricate hydrogels with enhanced anti-swelling properties and underwater adhesion is presented. By leveraging the contrasting affinity of different polymer chains to water, a phase-separated structure with rich hydrophobic and dilute hydrophilic polymer phases is achieved. This dual-phase structure, meticulously characterized from the macroscopic to the nulloscale, confers the hydrogel network with augmented retractive elastic forces and facilitates efficient water drainage at the gel-substrate interface. As a result, the hydrogel exhibits remarkable swelling resistance and long-lasting adhesion to diverse substrates. Additionally, the integration of carboxylic multiwalled carbon nullotubes into the hydrogel system preserves its anti-swelling and adhesion properties while imparting superior conductivity. The conductive phase-separated hydrogel exhibited great potential in diverse underwater applications, including sensing, communication, and energy harvesting. This study elucidates a facile strategy for designing anti-swelling underwater adhesives by leveraging the ambient solvent effect, which is expected to offer some insights for the development of next-generation adhesive soft materials tailored for aqueous environments. Water-induced phase separation strategy is utilized to develop anti-swelling hydrogels for underwater adhesion. The formation of hydrophobic domains at the gel surface facilitates water drainage at the interface, resulting in satisfactory adhesion capability of the gel underwater. By introducing carboxylic multiwalled carbon nullotubes into the hydrogel system, the hydrogel adhesive holds great potential in underwater sensing, communication, and energy harvesting.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202304780", "DOI Link": "http://dx.doi.org/10.1002/advs.202304780", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001070315300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tyndall, D; Craig, MJ; Gannon, L; McGuinness, C; McEvoy, N; Roy, A; García-Melchor, M; Browne, MP; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tyndall, Daire; Craig, Michael John; Gannon, Lee; McGuinness, Cormac; McEvoy, Niall; Roy, Ahin; Garcia-Melchor, Max; Browne, Michelle P.; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Demonstrating the source of inherent instability in NiFe LDH-based OER electrocatalysts", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel-iron layered double hydroxides are known to be one of the most highly active catalysts for the oxygen evolution reaction in alkaline conditions. The high electrocatalytic activity of the material however cannot be sustained within the active voltage window on timescales consistent with commercial requirements. The goal of this work is to identify and prove the source of inherent catalyst instability by tracking changes in the material during OER activity. By combining in situ and ex situ Raman analyses we elucidate long-term effects on the catalyst performance from a changing crystallographic phase. In particular, we attribute electrochemically stimulated compositional degradation at active sites as the principal cause of the sharp loss of activity from NiFe LDHs shortly after the alkaline cell is turned on. EDX, XPS, and EELS analyses performed after OER also reveal noticeable leaching of Fe metals compared to Ni, principally from highly active edge sites. In addition, post-cycle analysis identified a ferrihydrite by-product formed from the leached Fe. Density functional theory calculations shed light on the thermodynamic driving force for the leaching of Fe metals and propose a dissolution pathway which involves [FeO4](2-) removal at relevant OER potentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2023, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4067, "End Page": 4077, "Article Number": null, "DOI": "10.1039/d2ta07261k", "DOI Link": "http://dx.doi.org/10.1039/d2ta07261k", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000920168600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peeters, N; Binnemans, K; Riaño, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peeters, nulld; Binnemans, Koen; Riano, Sofia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvometallurgical recovery of cobalt from lithium-ion battery cathode materials using deep-eutectic solvents", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recycling of cobalt from end-of-life lithium-ion batteries (LIBs) is gaining interest because they are increasingly used in commercial applications such as electrical vehicles. A common LIB cathode material is lithium cobalt oxide (LiCoO2). Besides the cathode, LIBs contain other components, such as metallic aluminium and copper as current collectors, which are often separated at initial hydrometallurgical recycling stages. Leaching of cobalt from LiCoO(2)is mainly driven by reducing cobalt(iii) in LiCoO(2)to cobalt(ii)viaadding reducing agents. In this work, a green, cheap and safe approach is proposed by using a choline chloride-citric acid deep-eutectic solvent (DES) as lixiviant. Aluminium and copper were evaluated as reducing agents for cobalt(iii). After optimisation, lithium and cobalt were quantitatively leached from LiCoO(2)in the presence of aluminium and copper. Copper was the most effective reducing agent for cobalt(iii), so that no additional reducing agents or a pre-separation step were required. A speciation study of the pregnullt leach solution (PLS) confirmed the dominullce of chloro complexes. DES leaching was compared with conventional hydrochloric acid leaching, whereby the DES avoided the formation of toxic chlorine gas. Finally, the DES PLS was used as the more polar phase in a non-aqueous solvent extraction process. This process consisted of a copper(i/ii) extraction step with the extractant LIX 984, followed by selective extraction of cobalt(ii) with the extractant Aliquat 336. Both metals were completely stripped from the loaded organic phases by oxalic acid. The total recovery yield of cobalt was 81%, as a 99.9% pure oxalate precipitate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2020, "Volume": 22, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4210, "End Page": 4221, "Article Number": null, "DOI": "10.1039/d0gc00940g", "DOI Link": "http://dx.doi.org/10.1039/d0gc00940g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545862800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KH; Xiao, JD; Vequizo, JJM; Hisatomi, T; Ma, YW; Nakabayashi, M; Takata, T; Yamakata, A; Shibata, N; Domen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Kaihong; Xiao, Jiadong; Vequizo, Junie Jhon M.; Hisatomi, Takashi; Ma, Yiwen; Nakabayashi, Mamiko; Takata, Tsuyoshi; Yamakata, Akira; Shibata, Naoya; Domen, Kazunari", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overall Water Splitting by a SrTaO2N-Based Photocatalyst Decorated with an Ir-Promoted Ru-Based Cocatalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of narrow-bandgap photocatalysts for one-step-excitation overall water splitting (OWS) remains a critical challenge in the field of solar hydrogen production. SrTaO2N is a photocatalytic material having a band structure suitable for OWS under visible light (lambda < 600 nm). However, the presence of defects in the oxynitride and the lack of cocatalysts to promote simultaneous hydrogen and oxygen evolution make it challenging to realize OWS using this material. The present work demonstrates a SrTaO2N-based particulate photocatalyst for OWS. This photocatalyst, which was composed of single crystals, was obtained by nitriding SrCl2 and Ta2O5 together with NaOH, with the latter added to control the formation of defects. The subsequent loading of bimetallic RuIrOx nulloparticles accelerated charge separation and allowed the SrTaO2N photocatalyst to exhibit superior OWS activity. This research presenting the strategies of controlling the oxygen sources and promoting the cocatalyst function is expected to expand the range of potential OWS-active oxynitride photocatalysts and permit the design of efficient cocatalysts for photocatalytic OWS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 20", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c11025", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c11025", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000924123000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Jiao, Y; Zheng, Y; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xin; Jiao, Yan; Zheng, Yao; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of C-N bonds formation in electrocatalytic urea production revealed by ab initio molecular dynamics simulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrosynthesis of urea from CO2 and NOX provides an exceptional opportunity for human society, given the increasingly available renewable energy. Urea electrosynthesis is challenging. In order to raise the overall electrosynthesis efficiency, the most critical reaction step for such electrosynthesis, C-N coupling, needs to be significantly improved. The C-N coupling can only happen at a narrow potential window, generally in the low overpotential region, and a fundamental understanding of the C-N coupling is needed for further development of this strategy. In this regard, we perform ab initio Molecular Dynamics simulations to reveal the origin of C-N coupling under a small electrode potential window with both the dynamic nature of water as a solvent, and the electrode potentials considered. We explore the key reaction networks for urea formation on Cu(100) surface in neutral electrolytes. Our work shows excellent agreement with experimentally observed selectivity under different potentials on the Cu electrode. We discover that the *NH and *CO are the key precursors for C-N bonds formation at low overpotential, while at high overpotential the C-N coupling occurs between adsorbed *NH and solvated CO. These insights provide vital information for future spectroscopic measurements and enable us to design new electrochemical systems for more value-added chemicals. Urea electrosyntehsis from CO2 and NOx is a challenging reaction that is becoming increasingly important. This work uses ab initio molecular dynamics simulations to reveal the origin of C-N coupling mechanisms and reaction networks in urea synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5471, "DOI": "10.1038/s41467-022-33258-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33258-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854873600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Y; Zhang, S; Yu, TH; Zhang, Y; Ye, G; Cui, H; He, CZ; Jiang, WC; Zhai, Y; Lu, CM; Gu, XD; Liu, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yan; Zhang, Song; Yu, Tianhao; Zhang, Yan; Ye, Guo; Cui, Han; He, Chengzhi; Jiang, Wenchao; Zhai, Yu; Lu, Chunming; Gu, Xiaodan; Liu, null", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-conformal skin electrodes with synergistically enhanced conductivity for long-time and low-motion artifact epidermal electrophysiology", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate and imperceptible monitoring of electrophysiological signals is of primary importance for wearable healthcare. Stiff and bulky pregelled electrodes are now commonly used in clinical diagnosis, causing severe discomfort to users for long-time using as well as artifact signals in motion. Here, we report a similar to 100 nm ultra-thin dry epidermal electrode that is able to conformably adhere to skin and accurately measure electrophysiological signals. It showed low sheet resistance (similar to 24 Omega/sq, 4142 S/cm), high transparency, and mechano-electrical stability. The enhanced optoelectronic performance was due to the synergistic effect between graphene and poly (3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), which induced a high degree of molecular ordering on PEDOT and charge transfer on graphene by strong pi-pi interaction. Together with ultra-thin nature, this dry epidermal electrode is able to accurately monitor electrophysiological signals such as facial skin and brain activity with low-motion artifact, enabling human-machine interfacing and long-time mental/physical health monitoring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4880, "DOI": "10.1038/s41467-021-25152-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25152-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686181800026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YY; Li, TT; Scarpa, F; Wang, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yanyu; Li, Tiantian; Scarpa, Fabrizio; Wang, Lifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice Metamaterials with Mechanically Tunable Poisson's Ratio for Vibration Control", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterials with artificially designed architectures are increasingly considered as new paradigmatic material systems with unusual physical properties. Here, we report a class of architected lattice metamaterials with mechanically tunable negative Poisson's ratios and vibration-mitigation capability. The proposed lattice metamaterials are built by replacing regular straight beams with sinusoidally shaped ones, which are highly stretchable under uniaxial tension. Our experimental and numerical results indicate that the proposed lattices exhibit extreme Poisson's-ratio variations between -0.7 and 0.5 over large tensile deformations up to 50%. This large variation of Poisson's-ratio values is attributed to the deformation pattern switching from bending to stretching within the sinusoidally shaped beams. The interplay between the multiscale (ligament and cell) architecture and wave propagation also enables remarkable broadband vibration-mitigation capability of the lattice metamaterials, which can be dynamically tuned by an external mechanical stimulus. The material design strategy provides insights into the development of classes of architected metamaterials with potential applications including energy absorption, tunable acoustics, vibration control, responsive devices, soft robotics, and stretchable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24012, "DOI": "10.1103/PhysRevApplied.7.024012", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.7.024012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393748700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kozbial, A; Li, ZT; Conaway, C; McGinley, R; Dhingra, S; Vahdat, V; Zhou, F; D'Urso, B; Liu, HT; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kozbial, Andrew; Li, Zhiting; Conaway, Caitlyn; McGinley, Rebecca; Dhingra, Shonali; Vahdat, Vahid; Zhou, Feng; D'Urso, Brian; Liu, Haitao; Li, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study on the Surface Energy of Graphene by Contact Angle Measurements", "Source Title": "LANGMUIR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Because of the atomic thinness of graphene, its integration into a device will always involve its interaction with at least one supporting substrate, making the surface energy of graphene critical to its real-life applications. In the current paper, the contact angle of graphene synthesized by chemical vapor deposition (CVD) was monitored temporally after synthesis using water, diiodomethane, ethylene glycol, and glycerol. The surface energy was then calculated based on the contact angle data by the Fowkes, Owens-Wendt (extended Fowkes), and Neumann models. The surface energy of fresh CVD graphene grown on a copper substrate (G/Cu) immediately after synthesis was determined to be 62.2 +/- 3.1 mJ/m(2) (Fowkes), 53.0 +/- 4.3 mJ/m(2) (Owens- Wendt) and 63.8 +/- 2.0 mJ/m(2) (Neumann), which decreased to 45.6 +/- 3.9, 37.5 +/- 2.3, and 57.4 +/- 2.1 mJ/m(2), respectively, after 24 h of air exposure. The ellipsometry characterization indicates that the surface energy of G/Cu is affected by airborne hydrocarbon contamination. G/Cu exhibits the highest surface energy immediately after synthesis, and the surface energy decreases after airborne contamination occurs. The root cause of intrinsically mild polarity of G/Cu surface is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2014, "Volume": 30, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8598, "End Page": 8606, "Article Number": null, "DOI": "10.1021/la5018328", "DOI Link": "http://dx.doi.org/10.1021/la5018328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339463000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, L; Wang, JZ; Wang, K; Gu, ZQ; Xi, ZW; Li, H; Chen, F; Wang, YX; Li, ZY; Ma, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Lv; Wang, Jinzhu; Wang, Kai; Gu, Zhenqi; Xi, Zhiwei; Li, Hui; Chen, Fang; Wang, Youxi; Li, Zhenyu; Ma, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To enable the development of all-solid-state batteries, an inorganic solid-state electrolyte should demonstrate high ionic conductivity (i.e., > 1 mS cm(-1) at 25 & DEG;C), compressibility (e.g., > 90% density under 250-350 MPa), and cost-effectiveness (e.g., < $50/kg). Here we report the development and preparation of Li1.75ZrCl4.75O0.5 oxychloride solid-state electrolyte that demonstrates an ionic conductivity of 2.42 mS cm(-1) at 25 & DEG;C, a compressibility enabling 94.2% density under 300 MPa and an estimated raw materials cost of $11.60/kg. As proof of concept, the Li1.75ZrCl4.75O0.5 is tested in combination with a LiNi0.8Mn0.1Co0.1O2-based positive electrode and a Li6PS5Cl-coated Li-In negative electrode in lab-scale cell configuration. This all-solid-state cell delivers a discharge capacity retention of 70.34% (final discharge capacity of 70.2 mAh g(-1)) after 2082 cycles at 1 A g(-1), 25 & DEG;C and 1.5 tons of stacking pressure. Ionic conductivity > 1 mS cm(-1) at 25 & DEG;C, compressibility enabling > 90% density at 250 - 350 MPa, and cost < $50/kg are desirable for inorganic solid-state electrolytes. Here, the authors report Li1.75ZrCl4.75O0.5 as a solid-state electrolyte capable of satisfying these requirements simultaneously.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3807, "DOI": "10.1038/s41467-023-39522-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39522-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022863800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Perry, ML; Weber, AZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perry, Mike L.; Weber, Adam Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced Redox-Flow Batteries: A Perspective", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Redox-flow batteries are entering a period of renaissance, buoyed by both the increasing need for affordable large-scale energy-storage solutions, as well as leveraging the advancements in flow-cell technology, mainly in polymer-electrolyte fuel cells. This perspective highlights the research-and-development avenues and opportunities for redox-flow-battery cells and materials. (C) The Author(s) 2015. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 163, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A5064", "End Page": "A5067", "Article Number": null, "DOI": "10.1149/2.0101601jes", "DOI Link": "http://dx.doi.org/10.1149/2.0101601jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366180300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abbas, S; Nehdi, ML; Saleem, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abbas, S.; Nehdi, M. L.; Saleem, M. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-High Performance Concrete: Mechanical Performance, Durability, Sustainability and Implementation Challenges", "Source Title": "INTERNATIONAL JOURNAL OF CONCRETE STRUCTURES AND MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, an extensive literature review has been conducted on the material characterization of UHPC and its potential for large-scale field applicability. The successful production of ultra-high performance concrete (UHPC) depends on its material ingredients and mixture proportioning, which leads to denser and relatively more homogenous particle packing. A database was compiled from various research and field studies around the world on the mechanical and durability performance of UHPC. It is shown that UHPC provides a viable and long-term solution for improved sustainable construction owing to its ultra-high strength properties, improved fatigue behavior and very low porosity, leading to excellent resistance against aggressive environments. The literature review revealed that the curing regimes and fiber dosage are the main factors that control the mechanical and durability properties of UHPC. Currently, the applications of UHPC in construction are very limited due to its higher initial cost, lack of contractor experience and the absence of widely accepted design provisions. However, sustained research progress in producing UHPC using locally available materials under normal curing conditions should reduce its material cost. Current challenges regarding the implementation of UHPC in full-scale structures are highlighted. This study strives to assist engineers, consultants, contractors and other construction industry stakeholders to better understand the unique characteristics and capabilities of UHPC, which should demystify this resilient and sustainable construction material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": 295, "Article Number": null, "DOI": "10.1007/s40069-016-0157-4", "DOI Link": "http://dx.doi.org/10.1007/s40069-016-0157-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382704200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chechetka, SA; Yu, Y; Zhen, X; Pramanik, M; Pu, KY; Miyako, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chechetka, Svetlana A.; Yu, Yue; Zhen, Xu; Pramanik, Manojit; Pu, Kanyi; Miyako, Eijiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-driven liquid metal nullotransformers for biomedical theranostics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Room temperature liquid metals (LMs) represent a class of emerging multifunctional materials with attractive novel properties. Here, we show that photopolymerized LMs present a unique nulloscale capsule structure characterized by high water dispersibility and low toxicity. We also demonstrate that the LM nullocapsule generates heat and reactive oxygen species under biologically neutral near- infrared (NIR) laser irradiation. Concomitantly, NIR laser exposure induces a transformation in LM shape, destruction of the nullocapsules, contactless controlled release of the loaded drugs, optical manipulations of a microfluidic blood vessel model and spatiotemporal targeted marking for X- ray- enhanced imaging in biological organs and a living mouse. By exploiting the physicochemical properties of LMs, we achieve effective cancer cell elimination and control of intercellular calcium ion flux. In addition, LMs display a photoacoustic effect in living animals during NIR laser treatment, making this system a powerful tool for bioimaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15432, "DOI": "10.1038/ncomms15432", "DOI Link": "http://dx.doi.org/10.1038/ncomms15432", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402389100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubacka, T; Johnson, JA; Hoffmann, MC; Vicario, C; de Jong, S; Beaud, P; Grübel, S; Huang, SW; Huber, L; Patthey, L; Chuang, YD; Turner, JJ; Dakovski, GL; Lee, WS; Minitti, MP; Schlotter, W; Moore, RG; Hauri, CP; Koohpayeh, SM; Scagnoli, V; Ingold, G; Johnson, SL; Staub, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubacka, T.; Johnson, J. A.; Hoffmann, M. C.; Vicario, C.; de Jong, S.; Beaud, P.; Gruebel, S.; Huang, S. -W.; Huber, L.; Patthey, L.; Chuang, Y. -D.; Turner, J. J.; Dakovski, G. L.; Lee, W. -S.; Minitti, M. P.; Schlotter, W.; Moore, R. G.; Hauri, C. P.; Koohpayeh, S. M.; Scagnoli, V.; Ingold, G.; Johnson, S. L.; Staub, U.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Amplitude Spin Dynamics Driven by a THz Pulse in Resonullce with an Electromagnon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiferroics have attracted strong interest for potential applications where electric fields control magnetic order. The ultimate speed of control via magnetoelectric coupling, however, remains largely unexplored. Here, we report an experiment in which we drove spin dynamics in multiferroic TbMnO3 with an intense few-cycle terahertz (THz) light pulse tuned to resonullce with an electromagnon, an electric-dipole active spin excitation. We observed the resulting spin motion using time-resolved resonullt soft x-ray diffraction. Our results show that it is possible to directly manipulate atomic-scale magnetic structures with the electric field of light on a sub-picosecond time scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2014, "Volume": 343, "Issue": 6177, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1333, "End Page": 1336, "Article Number": null, "DOI": "10.1126/science.1242862", "DOI Link": "http://dx.doi.org/10.1126/science.1242862", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333108500031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, YZ; Weber, J; Mills, BM; Ren, ZH; Faul, CFJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Yaozu; Weber, Jens; Mills, Benjamin M.; Ren, Zihao; Faul, Charl F. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient and Reversible Iodine Capture in Hexaphenylbenzene-Based Conjugated Microporous Polymers", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The effective and safe capture and storage of radioactive iodine (1291 or 1311) is of significant importance during nuclear waste storage and nuclear energy generation. Here we present detailed evidence of highly efficient and reversible iodine capture in hexaphenylbenzene-based conjugated microporous polymers (HCMPs), synthesized via Buchwald-Hartwig (BH) cross-coupling of a hexakis(4-bromophenyl)benzene (HBB) core and aryl diamine linkers. The HCMPs present moderate surface areas up to 430 m(2) g(-1), with narrow pore size distribution and uniform ultramicropore sizes of less than 1 nm. Porous properties are controlled by the strut lengths and rigidities of linkers, while porosity and uptake properties can be tuned by changing the oxidation state of the HCMPs. The presence of a high number of amine functional groups combined with microporosity provides the HCMPs with extremely high iodine affinity with uptake capacities up to 336 wt %, which is to the best of our knowledge the highest reported to date. Two ways to release the adsorbed iodine were explored: either slow release into ethanol or quick release upon heating (with a high degree of control). Spectral studies indicate that the combination of microporosity, amine functionality, and abundant pi-electrons ensured well-defined host-guest interactions and controlled uptake of iodine. In addition, the HCMPs could be recycled while maintaining 90% iodine uptake capacity (up to 295%). We envisage wider application of these materials in the facile uptake and removal of unwanted oxidants from the environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2016, "Volume": 49, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6322, "End Page": 6333, "Article Number": null, "DOI": "10.1021/acs.macromol.6b00901", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.6b00901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383318300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HY; Li, SW; Regan, EC; Wang, DQ; Zhao, WY; Kahn, S; Yumigeta, K; Blei, M; Taniguchi, T; Watanabe, K; Tongay, S; Zettl, A; Crommie, MF; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hongyuan; Li, Shaowei; Regan, Emma C.; Wang, Danqing; Zhao, Wenyu; Kahn, Salman; Yumigeta, Kentaro; Blei, Mark; Taniguchi, Takashi; Watanabe, Kenji; Tongay, Sefaattin; Zettl, Alex; Crommie, Michael F.; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imaging two-dimensional generalized Wigner crystals", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Wigner crystal(1) has fascinated condensed matter physicists for nearly 90 years(2-14). Signatures of two-dimensional (2D) Wigner crystals were first observed in 2D electron gases under high magnetic field(2-4), and recently reported in transition metal dichalcogenide moire superlattices(6-9). Direct observation of the 2D Wigner crystal lattice in real space, however, has remained an outstanding challenge. Conventional scanning tunnelling microscopy (STM) has sufficient spatial resolution but induces perturbations that can potentially alter this fragile state. Here we demonstrate real-space imaging of 2D Wigner crystals in WSe2/WS2 moire heterostructures using a specially designed non-invasive STM spectroscopy technique. This employs a graphene sensing layer held close to the WSe2/WS2 moire superlattice. Local STM tunnel current into the graphene layer is modulated by the underlying Wigner crystal electron lattice in the WSe2/WS2 heterostructure. Different Wigner crystal lattice configurations at fractional electron fillings of n = 1/3, 1/2 and 2/3, where n is the electron number per site, are directly visualized. The n = 1/3 and n = 2/3 Wigner crystals exhibit triangular and honeycomb lattices, respectively, to minimize nearest-neighbour occupations. The n = 1/2 state spontaneously breaks the original C3 symmetry and forms a stripe phase. Our study lays a solid foundation for understanding Wigner crystal states in WSe2/WS2 moire heterostructures and provides an approach that is generally applicable for imaging novel correlated electron lattices in other systems. So far, only indirect evidence of Wigner crystals has been reported, but a specially designed scanning tunnelling microscope is used here to directly image them in a moire heterostructure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2021, "Volume": 597, "Issue": 7878, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 650, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03874-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03874-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701996800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Resasco, J; Zhang, H; Kornienko, N; Becknell, N; Lee, H; Guo, JH; Briseno, AL; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Resasco, Joaquin; Zhang, Hao; Kornienko, Nikolay; Becknell, Nigel; Lee, Hyunbok; Guo, Jinghua; Briseno, Alejandro L.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "TiO2/BiVO4 nullowire Heterostructure Photoanodes Based on Type II Band Alignment", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal oxides that absorb visible light are attractive for use as photoanodes in photoelectrosynthetic cells. However, their performance is often limited by poor charge carrier transport. We show that this problem can be addressed by using separate materials for light absorption and carrier transport. Here, we report a Ta:TiO2|BiVO4 nullowire photoanode, in which BiVO4 acts as a visible light-absorber and Ta:TiO2 acts as a high surface area electron conductor. Electrochemical and spectroscopic measurements provide experimental evidence for the type II band alignment necessary for favorable electron transfer from BiVO4 to TiO2. The host-guest nullowire architecture presented here allows for simultaneously high light absorption and carrier collection efficiency, with an onset of anodic photocurrent near 0.2 V vs RHE, and a photocurrent density of 2.1 mA/cm(2) at 1.23 V vs RHE.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2016, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 80, "End Page": 88, "Article Number": null, "DOI": "10.1021/acscentsci.5b00402", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.5b00402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373182300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Canil, L; Cramer, T; Fraboni, B; Ricciarelli, D; Meggiolaro, D; Singh, A; Liu, MN; Rusu, M; Wolff, CM; Phung, N; Wang, Q; Neher, D; Unold, T; Vivo, P; Gagliardi, A; De Angelis, F; Abate, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Canil, Laura; Cramer, Tobias; Fraboni, Beatrice; Ricciarelli, Damiano; Meggiolaro, Daniele; Singh, Ajay; Liu, Maning; Rusu, Marin; Wolff, Christian M.; Nga Phung; Wang, Qiong; Neher, Dieter; Unold, Thomas; Vivo, Paola; Gagliardi, Alessio; De Angelis, Filippo; Abate, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning halide perovskite energy levels", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to control the energy levels in semiconductors is compelling for optoelectronic applications. In this study, we managed to tune the work function (WF) of halide perovskite semiconductors using self-assembled monolayers of small molecules to induce stable dipoles at the surface. The direction and intensity of the surface dipoles rely on specific molecule-to-surface interactions. Electron acceptor or donor molecules result in the positive or negative WF shifts up to several hundreds of meV. Our approach provides a versatile tool to control the WF of halide perovskite and adjust the energy level alignment at the interface with charge transport materials in perovskite-based optoelectronics. The impact on perovskite solar cells is reported and discussed in detail with the support of modelling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1429, "End Page": 1438, "Article Number": null, "DOI": "10.1039/d0ee02216k", "DOI Link": "http://dx.doi.org/10.1039/d0ee02216k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000639555200030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shinagawa, T; Larrazábal, GO; Martín, AJ; Krumeich, F; Pérez-Ramírez, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shinagawa, Tatsuya; Larrazabal, Gaston O.; Martin, Antonio J.; Krumeich, Frank; Perez-Ramirez, Javier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrocatalytic CO2 reduction reaction (eCO(2)RR) has been gaining increasing attention owing to its potential to contribute to sustainability in our society, although enhanced catalytic performance is a prerequisite for its implementation. Herein, Cu electrocatalysts modified with sulfur proved to selectively produce formate via aqueous eCO(2)RR and thus to unexpectedly prevent the mechanistic fingerprint of Cu (i.e., the CO path). Initially, sulfur-modified copper catalysts (Cu-S) were prepared by the in situ reductive reconstruction of nullo Cu-S precursors, revealing a positive correlation between particle size and selectivity toward formate. Subsequent studies over targeted submicron Cu-S particles with varying sulfur content demonstrated their evolution under reaction conditions, attaining a similar surface state comprising metallic Cu and sulfide phases, irrespective of the initial structure of the materials. In accordance, the initial sulfur content showed only a very limited influence on the catalytic performance, which remained at approximately 80% Faradaic efficiency toward formate at -0.8 V vs RHE, outperforming all cost-effective, earth-abundant, and nontoxic electrocatalysts reported to date for the production of formate via the aqueous eCO(2)RR", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 837, "End Page": 844, "Article Number": null, "DOI": "10.1021/acscatal.7b03161", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b03161", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424735000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YT; Liu, S; Li, GR; Yan, TY; Gao, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu Ya-Tao; Liu Sheng; Li Guo-Ran; Yan Tian-Ying; Gao Xue-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Volumetric Energy Density Sulfur Cathode with Heavy and Catalytic Metal Oxide Host for Lithium-Sulfur Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For high-energy lithium-sulfur batteries, the poor volumetric energy density is a bottleneck as compared with lithium-ion batteries, due to the low density of both the sulfur active material and sulfur host. Herein, in order to enhance the volumetric energy density of sulfur cathode, a universal approach is proposed to fabricate a compact sulfur cathode with dense materials as sulfur host, instead of the old-fashioned lightweight carbon nullomaterials. Based on this strategy, heavy lanthanum strontium manganese oxide (La0.8Sr0.2MnO3), with a high theoretical density of up to 6.5 g cm(-3), is introduced as sulfur host. Meanwhile, the La0.8Sr0.2MnO3 host also acts as an efficient electrocatalyst to accelerate the diffusion, adsorption, and redox dynamics of lithium polysulfides in the charge-discharge processes. As a result, such S/La0.8Sr0.2MnO3 cathode presents high gravimetric/volumetric capacity and outstanding cycling stability. Moreover, an ultra-high volumetric energy density of 2727 Wh L--cathode(-1) is achieved based on the densification effect with higher density (1.69 g cm(-3)), which is competitive to the Ni-rich oxide cathode (1800-2160 Wh L-1) of lithium-ion batteries. The current study opens up a path for constructing high volumetric capacity sulfur cathode with heavy and catalytic host toward practical applications of lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903693, "DOI": "10.1002/advs.201903693", "DOI Link": "http://dx.doi.org/10.1002/advs.201903693", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530638000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hyland, M; Hunter, H; Liu, J; Veety, E; Vashaee, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hyland, Melissa; Hunter, Haywood; Liu, Jie; Veety, Elena; Vashaee, Daryoosh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable thermoelectric generators for human body heat harvesting", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A thermoelectric generator (TEG) can be used to harvest electrical energy from human body heat for the purpose of powering wearable electronics. At the NSF Advanced Self-Powered Systems of Integrated Sensors and Technologies (ASSIST), TEGs are one of the enabling technologies being explored to advance the center's mission of creating wearable, self-powered, health and environmental monitoring systems. As part of this effort, an exploration of the relevant parameters for maximizing the wearable TEG power output from the body heat and maintaining the body comfort is particularly important. For this purpose, the heat from the body must be directed into TEG with minimal loss, the generator must be designed for maintaining a high temperature differential across the thermoelectric material, and the generator must have a small form factor to maintain the body comfort. In order to address these requirements, an optimum TEG design was developed and experiments were conducted both on a temperature-controlled hot plate and on different body locations including the wrist, upper arm, and chest. The TEG was further fabricated into a T-shirt and the power was recorded for different human activities. Comparison of the experiments on various body locations and on the T-shirt yielded the highest to lowest power generated on the upper arm, wrist, chest and T-shirt, respectively. The prospect of powering a wearable electrocardiogram sensor by a TEG on the upper arm is discussed. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2016, "Volume": 182, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 518, "End Page": 524, "Article Number": null, "DOI": "10.1016/j.apenergy.2016.08.150", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2016.08.150", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387626600046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YJ; Xing, J; Gong, QY; Chen, LC; Liu, GF; Yao, CJ; Wang, ZR; Zhang, HL; Chen, Z; Zhang, QC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yinjuan; Xing, Jie; Gong, Qiuyu; Chen, Li-Chuan; Liu, Guangfeng; Yao, Changjiang; Wang, Zongrui; Zhang, Hao-Li; Chen, Zhong; Zhang, Qichun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reducing aggregation caused quenching effect through co-assembly of PAH chromophores and molecular barriers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The features of well-conjugated and planar aromatic structures make p-conjugated luminescent materials suffer from aggregation caused quenching (ACQ) effect when used in solid or aggregated states, which greatly impedes their applications in optoelectronic devices and biological applications. Herein, we reduce the ACQ effect by demonstrating a facile and low cost method to co-assemble polycyclic aromatic hydrocarbon (PAH) chromophores and octafluoronaphthalene together. Significantly, the solid photoluminescence quantum yield (PLQYs) for the as-resulted four micro/nullococrystals are enhanced by 254%, 235%, 474 and 582%, respectively. Protection from hydrophilic polymer chains (P123 (PEO20-PPO70-PEO20)) endows the cocrystals with superb dispersibility in water. More importantly, profiting from the above-mentioned highly improved properties, nullo-cocrystals present good biocompatibility and considerable cell imaging performance. This research provides a simple method to enhance the emission, biocompatibility and cellular permeability of common chromophores, which may open more avenues for the applications of originally non- or poor fluorescent PAHs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 418, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 169, "DOI": "10.1038/s41467-018-08092-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08092-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455475000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GD; Sun, B; Hu, XF; Sun, LF; Zou, Z; Xiao, B; Qiu, WK; Wu, B; Li, J; Han, JJ; Liao, LP; Xu, CY; Xiao, G; Xiao, LH; Cheng, JB; Zheng, SH; Wang, LD; Song, QL; Duan, SK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangdong; Sun, Bai; Hu, Xiaofang; Sun, Linfeng; Zou, Zhuo; Xiao, Bo; Qiu, Wuke; Wu, Bo; Li, Jie; Han, Juanjuan; Liao, Liping; Xu, Cunyun; Xiao, Gang; Xiao, Lihua; Cheng, Jianbo; Zheng, Shaohui; Wang, Lidan; Song, Qunliang; Duan, Shukai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative Photoconductance Effect: An Extension Function of the TiOx-Based Memristor", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The negative photoconductance (NPC) effect, defined as an increase in resistance upon exposure to illumination, holds great potential for application in photoelectric devices. A prepared memristor with the structure of Ag|graphene quantum dots (GQDs)|TiOx|F-doped SnO2 exhibits typical bipolar resistive switching (RS) memory behavior. The NPC effect is impressively observed in the high resistance state branch of the RS memory, enabling the memristor function to be extended to both memory logic display and multistate data storage. The observed NPC effect is attributed to the excitation, migration, and compensation of oxygen vacancy at the GQDs/TiOx interface, at which the electron transportation is efficiently restricted because of the variation in the charge distribution and electrostatic potential under illumination. Experiments, theoretical calculations, and physical models are used to provide engineer the interface with the aim of building the NPC effect in the memristive device. These results unveil a new horizon on extending the functionality of the memristor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003765, "DOI": "10.1002/advs.202003765", "DOI Link": "http://dx.doi.org/10.1002/advs.202003765", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000647901600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Favaro, M; Xiao, H; Cheng, T; Goddard, WA ; Yano, J; Crumlin, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Favaro, Marco; Xiao, Hai; Cheng, Tao; Goddard, William A., III; Yano, Junko; Crumlin, Ethan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subsurface oxide plays a critical role in CO2 activation by Cu(111) surfaces to form chemisorbed CO2, the first step in reduction of CO2", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A national priority is to convert CO2 into high-value chemical products such as liquid fuels. Because current electrocatalysts are not adequate, we aim to discover new catalysts by obtaining a detailed understanding of the initial steps of CO2 electroreduction on copper surfaces, the best current catalysts. Using ambient pressure X-ray photoelectron spectroscopy interpreted with quantum mechanical prediction of the structures and free energies, we show that the presence of a thin suboxide structure below the copper surface is essential to bind the CO2 in the physisorbed configuration at 298 K, and we show that this suboxide is essential for converting to the chemisorbed CO2 in the presence of water as the first step toward CO2 reduction products such as formate and CO. This optimum suboxide leads to both neutral and charged Cu surface sites, providing fresh insights into how to design improved carbon dioxide reduction catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 422, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2017, "Volume": 114, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6706, "End Page": 6711, "Article Number": null, "DOI": "10.1073/pnas.1701405114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1701405114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404108400045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bakulin, AA; Selig, O; Bakker, HJ; Rezus, YLA; Müller, C; Glaser, T; Lovrincic, R; Sun, ZH; Chen, ZY; Walsh, A; Frost, JM; Jansen, TLC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bakulin, Artem A.; Selig, Oleg; Bakker, Huib J.; Rezus, Yves L. A.; Mueller, Christian; Glaser, Tobias; Lovrincic, Robert; Sun, Zhenhua; Chen, Zhuoying; Walsh, Aron; Frost, Jarvist M.; Jansen, Thomas L. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The introduction of a mobile and polarized organic moiety as a cation in 3D lead-iodide perovskites brings fascinating optoelectronic properties to these materials. The extent and the time scales of the orientational mobility of the organic cation and the molecular mechanism behind its motion remain unclear, with different experimental and computational approaches providing very different qualitative and quantitative description of the molecular dynamics. Here we use ultrafast 2D vibrational spectroscopy of methylammonium (MA) lead iodide to directly resolve the rotation of the organic cations within the MAPbI(3) lattice. Our results reveal two characteristic time constants of motion. Using ab initio molecular dynamics simulations, we identify these as a fast (similar to 300 Is) wobbling-in-a-cone motion around the crystal axis and a relatively slow (similar to 3 ps) jump-like reorientation of the molecular dipole with respect to the iodide lattice. The observed dynamics are essential for understanding the electronic properties of perovskite materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 17", "Publication Year": 2015, "Volume": 6, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3663, "End Page": 3669, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b01555", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b01555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361858800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SE; Mujid, F; Rai, A; Eriksson, F; Suh, J; Poddar, P; Ray, A; Park, C; Fransson, E; Zhong, Y; Muller, DA; Erhart, P; Cahill, DG; Park, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Shi En; Mujid, Fauzia; Rai, Akash; Eriksson, Fredrik; Suh, Joonki; Poddar, Preeti; Ray, Ariana; Park, Chibeom; Fransson, Erik; Zhong, Yu; Muller, David A.; Erhart, Paul; Cahill, David G.; Park, Jiwoong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely anisotropic van der Waals thermal conductors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The densification of integrated circuits requires thermal management strategies and high thermal conductivity materials(1-3). Recent innovations include the development of materials with thermal conduction anisotropy, which can remove hotspots along the fast-axis direction and provide thermal insulation along the slow axis(4,5). However, most artificially engineered thermal conductors have anisotropy ratios much smaller than those seen in naturally anisotropic materials. Here we report extremely anisotropic thermal conductors based on large-area van der Waals thin films with random interlayer rotations, which produce a room-temperature thermal anisotropy ratio close to 900 in MoS2, one of the highest ever reported. This is enabled by the interlayer rotations that impede the through-plane thermal transport, while the long-range intralayer crystallinity maintains high in-plane thermal conductivity. We measure ultralow thermal conductivities in the through-plane direction for MoS2 (57 +/- 3 mW m(-1) K-1) and WS2 (41 +/- 3 mW m(-1) K-1) films, and we quantitatively explain these values using molecular dynamics simulations that reveal one-dimensional glass-like thermal transport. Conversely, the in-plane thermal conductivity in these MoS2 films is close to the single-crystal value. Covering nullofabricated gold electrodes with our anisotropic films prevents overheating of the electrodes and blocks heat from reaching the device surface. Our work establishes interlayer rotation in crystalline layered materials as a new degree of freedom for engineering-directed heat transport in solid-state systems. Extremely anisotropic thermal conductors based on large-area van der Waals thin films with random interlayer rotations are reported here.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2021, "Volume": 597, "Issue": 7878, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 660, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03867-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03867-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701996800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HQ; Wu, JY; Jiang, Z; Ma, JZ; Zavala, VM; Landis, CR; Mavrikakis, M; Huber, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Houqian; Wu, Jiayang; Jiang, Zhen; Ma, Jiaze; Zavala, Victor M.; Landis, Clark R.; Mavrikakis, Manos; Huber, George W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydroformylation of pyrolysis oils to aldehydes and alcohols from polyolefin waste", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Waste plastics are an abundant feedstock for the production of renewable chemicals. Pyrolysis of waste plastics produces pyrolysis oils with high concentrations of olefins (>50 weight %). The traditional petrochemical industry uses several energy-intensive steps to produce olefins from fossil feedstocks such as naphtha, natural gas, and crude oil. In this work, we demonstrate that pyrolysis oil can be used to produce aldehydes through hydroformylation, taking advantage of the olefin functionality. These aldehydes can then be reduced to mono- and dialcohols, oxidized to mono- and dicarboxylic acids, or aminated to mono- and diamines by using homogeneous and heterogeneous catalysis. This route produces high-value oxygenated chemicals from low-value postconsumer recycled polyethylene. We project that the chemicals produced by this route could lower greenhouse gas emissions similar to 60% compared with their production through petroleum feedstocks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2023, "Volume": 381, "Issue": 6658, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 660, "End Page": 665, "Article Number": null, "DOI": "10.1126/science.adh1853", "DOI Link": "http://dx.doi.org/10.1126/science.adh1853", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054584400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, B; Saeed, MZ; Li, QQ; Zhu, ML; Feng, Y; Zhou, ZQ; Fang, JZ; Hossain, M; Zhang, ZC; Zhou, YC; Huangfu, Y; Song, R; Tang, JM; Li, BL; Liu, JL; Wang, D; He, K; Zhang, HM; Wu, RX; Zhao, B; Li, J; Liao, L; Wei, ZM; Li, B; Duan, XF; Duan, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Biao; Saeed, Muhammad Zeeshan; Li, Qiuqiu; Zhu, Manli; Feng, Ya; Zhou, Ziqi; Fang, Jingzhi; Hossain, Mongur; Zhang, Zucheng; Zhou, Yucheng; Huangfu, Ying; Song, Rong; Tang, Jingmei; Li, Bailing; Liu, Jialing; Wang, Di; He, Kun; Zhang, Hongmei; Wu, Ruixia; Zhao, Bei; Li, Jia; Liao, Lei; Wei, Zhongming; Li, Bo; Duan, Xiangfeng; Duan, Xidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General low-temperature growth of two-dimensional nullosheets from layered and nonlayered materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most of the current methods for the synthesis of two-dimensional materials (2DMs) require temperatures not compatible with traditional back-end-of-line (BEOL) processes in semiconductor industry (450 degrees C). Here, we report a general BiOCl-assisted chemical vapor deposition (CVD) approach for the low-temperature synthesis of 27 ultrathin 2DMs. In particular, by mixing BiOCl with selected metal powders to produce volatile intermediates, we show that ultrathin 2DMs can be produced at 280-500 degrees C, which are similar to 200-300 degrees C lower than the temperatures required for salt-assisted CVD processes. In-depth characterizations and theoretical calculations reveal the low-temperature processes promoting 2D growth and the oxygen-inhibited synthetic mechanism ensuring the formation of ultrathin nonlayered 2DMs. We demonstrate that the resulting 2DMs exhibit electrical, magnetic and optoelectronic properties comparable to those of 2DMs grown at much higher temperatures. The general low-temperature preparation of ultrathin 2DMs defines a rich material platform for exploring exotic physics and facile BEOL integration in semiconductor industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 304, "DOI": "10.1038/s41467-023-35983-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35983-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982581400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, CC; Yang, Y; Wu, XD; Chen, L; Liu, ZL; Tang, L; Lyu, L; Huang, DL; Wang, DB; Zhang, C; Yuan, XZ; Liu, W; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Chencheng; Yang, Yi; Wu, Xiaodong; Chen, Long; Liu, Zhaoli; Tang, Lin; Lyu, Lai; Huang, Danlian; Wang, Dongbo; Zhang, Chang; Yuan, Xingzhong; Liu, Wen; Wang, Hou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Twistedly hydrophobic basis with suitable aromatic metrics in covalent organic networks govern micropollutant decontamination", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pre-designable structure and unique architectures of covalent organic frameworks (COFs) render them attractive as active and porous medium for water crisis. However, the effect of functional basis with different metrics on the regulation of interfacial behavior in advanced oxidation decontamination remains a significant challenge. In this study, we pre-design and fabricate different molecular interfaces by creating ordered pi skeletons, incorporating different pore sizes, and engineering hydrophilic or hydrophobic channels. These synergically break through the adsorption energy barrier and promote inner-surface renewal, achieving a high removal rate for typical antibiotic contaminullts (like levofloxacin) by BTT-DATP-COF, compared with BTT-DADP-COF and BTT-DAB-COF. The experimental and theoretical calculations reveal that such functional basis engineering enable the hole-driven levofloxacin oxidation at the interface of BTT fragments to occur, accompanying with electron-mediated oxygen reduction on terphenyl motif to active radicals, endowing it facilitate the balanced extraction of holes and electrons. The synergetic regulation of the electronic structure and interfacial reaction of covalent organic frameworks (COF) for water purification remains a challenge. Here the authors propose that COFs materials possessing molecular interfaces with ordered pi skeletons, suitable pore size, and hydrophilic/hydrophobic channels synergically break through the adsorption energy barrier achieving high removal rates for micropollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6740, "DOI": "10.1038/s41467-023-42513-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42513-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001089230100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ju, L; Bie, M; Tang, X; Shang, J; Kou, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ju, Lin; Bie, Mei; Tang, Xiao; Shang, Jing; Kou, Liangzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Janus WSSe Monolayer: An Excellent Photocatalyst for Overall Water Splitting", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stable photocatalysts with excellent optical adsorption and low reaction barrier are the key for the water splitting. Here, we find that a two-dimensional Janus WSSe monolayer possesses the compelling photocatalytic properties from density functional theory simulations, which can be well modulated with strain deformation. Comprehensive investigations indicate that the Janus material not only exhibits strong optical absorbance in the visible spectrum, suitable band edge potentials, high carrier separation, and transfer efficiency but also has adequate driving forces of photoexcited carrier for water redox reaction and good resistance against photoinduced corrosion. Janus WSSe is therefore predicted to be a promising photocatalyst for water splitting. Moreover, we also find that tensile strains could further improve the photocatalytic performance for water splitting by effectively increasing the energy conversion efficiency and reducing the exciton binding energy. Our results not only predict a photocatalyst, which can utilize the visible light for overall water splitting, but also propose an effective path to extend the absorption spectra and raise the photocatalytic efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2020, "Volume": 12, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 29335, "End Page": 29343, "Article Number": null, "DOI": "10.1021/acsami.0c06149", "DOI Link": "http://dx.doi.org/10.1021/acsami.0c06149", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546698600042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LR; Gaisinskaya-Kipnis, A; Kampf, N; Klein, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Liran; Gaisinskaya-Kipnis, Anastasia; Kampf, Nir; Klein, Jacob", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origins of hydration lubrication", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Why is friction in healthy hips and knees so low? Hydration lubrication, according to which hydration shells surrounding charges act as lubricating elements in boundary layers (including those coating cartilage in joints), has been invoked to account for the extremely low sliding friction between surfaces in aqueous media, but not well understood. Here we report the direct determination of energy dissipation within such sheared hydration shells. By trapping hydrated ions in a 0.4-1 nm gap between atomically smooth charged surfaces as they slide past each other, we are able to separate the dissipation modes of the friction and, in particular, identify the viscous losses in the subnullometre hydration shells. Our results shed light on the origins of hydration lubrication, with potential implications both for aqueous boundary lubricants and for biolubrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6060, "DOI": "10.1038/ncomms7060", "DOI Link": "http://dx.doi.org/10.1038/ncomms7060", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348830300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ao, DW; Liu, WD; Chen, YX; Wei, M; Jabar, B; Li, F; Shi, XL; Zheng, ZH; Liang, GX; Zhang, XH; Fan, P; Chen, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ao, Dong-Wei; Liu, Wei-Di; Chen, Yue-Xing; Wei, Meng; Jabar, Bushra; Li, Fu; Shi, Xiao-Lei; Zheng, Zhuang-Hao; Liang, Guang-Xing; Zhang, Xiang-Hua; Fan, Ping; Chen, Zhi-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel Thermal Diffusion Temperature Engineering Leading to High Thermoelectric Performance in Bi2Te3-Based Flexible Thin-Films", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible Bi2Te3-based thermoelectric devices can function as power generators for powering wearable electronics or chip-sensors for internet-of-things. However, the unsatisfied performance of n-type Bi2Te3 flexible thin films significantly limits their wide application. In this study, a novel thermal diffusion method is employed to fabricate n-type Te-embedded Bi2Te3 flexible thin films on flexible polyimide substrates, where Te embeddings can be achieved by tuning the thermal diffusion temperature and correspondingly result in an energy filtering effect at the Bi2Te3/Te interfaces. The energy filtering effect can lead to a high Seebeck coefficient approximate to 160 mu V K-1 as well as high carrier mobility of approximate to 200 cm(2) V-1 s(-1) at room-temperature. Consequently, an ultrahigh room-temperature power factor of 14.65 mu W cm(-1) K-2 can be observed in the Te-embedded Bi2Te3 flexible thin films prepared at the diffusion temperature of 623 K. A thermoelectric sensor is also assembled through integrating the n-type Bi2Te3 flexible thin films with p-type Sb2Te3 counterparts, which can fast reflect finger-touch status and demonstrate the applicability of as-prepared Te-embedded Bi2Te3 flexible thin films. This study indicates that the thermal diffusion method is an effective way to fabricate high-performance and applicable flexible Te-embedded Bi2Te3-based thin films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103547, "DOI": "10.1002/advs.202103547", "DOI Link": "http://dx.doi.org/10.1002/advs.202103547", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733269500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zielinski, PS; Gudeti, PKR; Rikmanspoel, T; Wlodarczyk-Biegun, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zielinski, Piotr Stanislaw; Gudeti, Pavan Kumar Reddy; Rikmanspoel, Timo; Wlodarczyk-Biegun, Malgorzata Katarzyna", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of bio-instructive materials: Toward directing the cell", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fabrication of functional scaffolds for tissue engineering and regenerative medicine applications requires material systems with precise control over cellular performance. 3D printing is a powerful technique to create highly complex and multicomponent structures with well-defined architecture and composition. In this review paper, we explore extrusion-based 3D printing methods (EBP, i.e., Near Field Electmspinning (NFES), Melt Electro-writing (MEW), Fused Deposition Modeling (FDM), and extrusion bioprinting) in terms of their ability to produce scaffolds with bio-instructive properties. These material systems provide spatio-temporal guidance for cells, allowing controlled tissue regeneration and maturation. Multiple physical and biochemical cues introduced to the EBP scaffolds are evaluated in their ability to direct cell alignment, proliferation, differentiation, specific ECM production, and tissue maturation. We indicate that the cues have different impacts depending on the material system, cell type used, or coexistence of multiple cues. Therefore, they must be carefully chosen based on the targeted application. We propose future directions in bio-instructive materials development, including such concepts as metamaterials, hybrid living materials, and 4D printing. The review gathers the knowledge essential for designing new materials with a controlled cellular response, fabrication of advanced engineered tissue, and developing a better understanding of cell biology, especially in response to the biomaterial.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 292, "End Page": 327, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.04.008", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.04.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000793320100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JJ; Fu, CH; Ye, K; Liang, Z; Jiang, FL; Shen, SY; Zhao, XR; Ma, L; Shadike, Z; Wang, XM; Zhang, JL; Jiang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jiajun; Fu, Cehuang; Ye, Ke; Liang, Zheng; Jiang, Fangling; Shen, Shuiyun; Zhao, Xiaoran; Ma, Lu; Shadike, Zulipiya; Wang, Xiaoming; Zhang, Junliang; Jiang, Kun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulating the oxygen reduction reaction pathway on Pt-coordinated motifs", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling O-2 reduction pathways can help optimize catalytic activity and product selectivity. Here the authors report facile manipulation of 2e(-) /4e(-) pathways on Pt-coordinated motifs by varying the Pt site density or the coordination environment. Electrochemical oxygen reduction could proceed via either 4e(-)-pathway toward maximum chemical-to-electric energy conversion or 2e(-)-pathway toward onsite H2O2 production. Bulk Pt catalysts are known as the best monometallic materials catalyzing O-2-to-H2O conversion, however, controversies on the reduction product selectivity are noted for atomic dispersed Pt catalysts. Here, we prepare a series of carbon supported Pt single atom catalyst with varied neighboring dopants and Pt site densities to investigate the local coordination environment effect on branching oxygen reduction pathway. Manipulation of 2e(-) or 4e(-) reduction pathways is demonstrated through modification of the Pt coordination environment from Pt-C to Pt-N-C and Pt-S-C, giving rise to a controlled H2O2 selectivity from 23.3% to 81.4% and a turnover frequency ratio of H2O2/H2O from 0.30 to 2.67 at 0.4 V versus reversible hydrogen electrode. Energetic analysis suggests both 2e(-) and 4e(-) pathways share a common intermediate of *OOH, Pt-C motif favors its dissociative reduction while Pt-S and Pt-N motifs prefer its direct protonation into H2O2. By taking the Pt-N-C catalyst as a stereotype, we further demonstrate that the maximum H2O2 selectivity can be manipulated from 70 to 20% with increasing Pt site density, providing hints for regulating the stepwise oxygen reduction in different application scenarios.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 685, "DOI": "10.1038/s41467-022-28346-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28346-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752207900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, HM; Ranjbar, A; Liang, YY; Song, ZD; Khazaei, M; Yunoki, S; Arai, M; Kawazoe, Y; Fang, Z; Dai, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Hongming; Ranjbar, Ahmad; Liang, Yunye; Song, Zhida; Khazaei, Mohammad; Yunoki, Seiji; Arai, Masao; Kawazoe, Yoshiyuki; Fang, Zhong; Dai, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-gap two-dimensional topological insulator in oxygen functionalized MXene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) topological insulators (TIs) have been recognized as a new class of quantum state of matter. They are distinguished from normal 2D insulators with their nontrivial band-structure topology identified by the Z(2) number as protected by time-reversal symmetry (TRS). Two-dimensional TIs have intriguing spin-velocity locked conducting edge states and insulating properties in the bulk. In the edge states, the electrons with opposite spins propagate in opposite directions and the backscattering is fully prohibited when the TRS is conserved. This leads to a quantized dissipationless two-lane highway for charge and spin transportation and promises potential applications. Up to now, only very few 2D systems have been discovered to possess this property. The lack of suitable material obstructs further study and application. Here, by using first-principles calculations, we propose that functionalized MXenes with oxygen, M2CO2 (M= W, Mo, and Cr), are 2D TIs with the largest gap of 0.194 eV in the Wcase. They are dynamically stable and natively antioxidant. Most importantly, they are very likely to be easily synthesized by recently developed selective chemical etching of transition-metal carbides (the M(n+1)AX(n) phase). This will pave the way to tremendous applications of 2D TIs, such as ideal conducting wire, multifunctional spintronic devices, and the realization of topological superconductivity and Majorana modes for quantum computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2015, "Volume": 92, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75436, "DOI": "10.1103/PhysRevB.92.075436", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.075436", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362213300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, HH; Kim, UH; Park, JH; Park, SW; Seo, DH; Heller, A; Mullins, CB; Yoon, CS; Sun, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, H. Hohyun; Kim, Un-Hyuck; Park, Jeong-Hyeon; Park, Sang-Wook; Seo, Dong-Hwa; Heller, Adam; Mullins, C. Buddie; Yoon, Chong S.; Sun, Yang-Kook", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition metal-doped Ni-rich layered cathode materials for durable Li-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term efficient cycling stability is of paramount importance for the development of high-energy Li-ion batteries. Here, the authors investigate the effect of transition metal dopants on the electrochemical, morphological, and structural properties of Ni-rich cathode active materials. Doping is a well-known strategy to enhance the electrochemical energy storage performance of layered cathode materials. Many studies on various dopants have been reported; however, a general relationship between the dopants and their effect on the stability of the positive electrode upon prolonged cell cycling has yet to be established. Here, we explore the impact of the oxidation states of various dopants (i.e., Mg2+, Al3+, Ti4+, Ta5+, and Mo6+) on the electrochemical, morphological, and structural properties of a Ni-rich cathode material (i.e., Li[Ni0.91Co0.09]O-2). Galvanostatic cycling measurements in pouch-type Li-ion full cells show that cathodes featuring dopants with high oxidation states significantly outperform their undoped counterparts and the dopants with low oxidation states. In particular, Li-ion pouch cells with Ta5+- and Mo6+-doped Li[Ni0.91Co0.09]O-2 cathodes retain about 81.5% of their initial specific capacity after 3000 cycles at 200 mA g(-1). Furthermore, physicochemical measurements and analyses suggest substantial differences in the grain geometries and crystal lattice structures of the various cathode materials, which contribute to their widely different battery performances and correlate with the oxidation states of their dopants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6552, "DOI": "10.1038/s41467-021-26815-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26815-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000718060500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WY; Dong, MY; Jiang, KR; Yang, DL; Tan, XH; Zhai, SL; Feng, RF; Chen, N; King, G; Zhang, H; Zeng, HB; Li, H; Antonietti, M; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenyao; Dong, Muyao; Jiang, Keren; Yang, Diling; Tan, Xuehai; Zhai, Shengli; Feng, Renfei; Chen, Ning; King, Graham; Zhang, Hao; Zeng, Hongbo; Li, Hui; Antonietti, Markus; Li, Zhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-repairing interphase reconstructed in each cycle for highly reversible aqueous zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc (Zn) chemistry features intrinsic safety, but suffers from severe irreversibility, as exemplified by low Coulombic efficiency, sustained water consumption and dendrite growth, which hampers practical applications of rechargeable Zn batteries. Herein, we report a highly reversible aqueous Zn battery in which the graphitic carbon nitride quantum dots additive serves as fast colloid ion carriers and assists the construction of a dynamic & self-repairing protective interphase. This real-time assembled interphase enables an ion-sieving effect and is found actively regenerate in each battery cycle, in effect endowing the system with single Zn2+ conduction and constant conformal integrality, executing timely adaption of Zn deposition, thus retaining sustainable long-term protective effect. In consequence, dendrite-free Zn plating/stripping at similar to 99.6% Coulombic efficiency for 200 cycles, steady charge-discharge for 1200 h, and impressive cyclability (61.2% retention for 500 cycles in a Zn parallel to MnO2 full battery, 73.2% retention for 500 cycles in a Zn parallel to V2O5 full battery and 93.5% retention for 3000 cycles in a Zn parallel to VOPO4 full battery) are achieved, which defines a general pathway to challenge Lithium in all low-cost, large-scale applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5348, "DOI": "10.1038/s41467-022-32955-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32955-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853182100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Habib, T; Zhao, XF; Shah, SA; Chen, YX; Sun, WM; An, H; Lutkenhaus, JL; Radovic, M; Green, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Habib, Touseef; Zhao, Xiaofei; Shah, Smit A.; Chen, Yexiao; Sun, Wanmei; An, Hyosung; Lutkenhaus, Jodie L.; Radovic, Miladin; Green, Micah J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxidation stability of Ti3C2Tx MXene nullosheets in solvents and composite films", "Source Title": "NPJ 2D MATERIALS AND APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ti3C2Tx belongs to the family of MXenes, 2D materials with an attractive combination of functional properties suitable for applications such as batteries, supercapacitors, and strain sensors. However, the fabrication of devices and functional coatings based on Ti3C2Tx remains challenging as they are prone to chemical degradation by their oxidation to TiO2. In this paper, we examine the oxidation of Ti(3)C(2)T(x )in air, liquid, and solid media via conductivity measurements to assess the shelf life of Ti3C2Tx MXenes. The oxidation of Ti3C2Tx was observed in all the media used in this study, but it is fastest in liquid media and slowest in solid media (including polymer matrices). We also show that the conventional indicators of MXene oxidation, such as changes in color and colloidal stability, are not always reliable. Finally, we demonstrate the acceleration of oxidation under exposure to UV light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2019, "Volume": 3, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8, "DOI": "10.1038/s41699-019-0089-3", "DOI Link": "http://dx.doi.org/10.1038/s41699-019-0089-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466141700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MB; Sun, RM; Chang, JX; Dong, JJ; Tian, QS; Wang, HZ; Li, ZH; Yang, PH; Shi, HK; Yang, C; Wu, ZC; Li, RZ; Yang, YG; Wang, AF; Zhang, ST; Wang, FF; Huang, W; Qin, TS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mubai; Sun, Riming; Chang, Jingxi; Dong, Jingjin; Tian, Qiushuang; Wang, Hongze; Li, Zihao; Yang, Pinghui; Shi, Haokun; Yang, Chao; Wu, Zichao; Li, Renzhi; Yang, Yingguo; Wang, Aifei; Zhang, Shitong; Wang, Fangfang; Huang, Wei; Qin, Tianshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Incorporating mixed ion is a frequently used strategy to stabilize black-phase formamidinum lead iodide perovskite for high-efficiency solar cells. However, these devices commonly suffer from photoinduced phase segregation and humidity instability. Herein, we find that the underlying reason is that the mixed halide perovskites generally fail to grow into homogenous and highcrystalline film, due to the multiple pathways of crystal nucleation originating from various intermediate phases in the film-forming process. Therefore, we design a multifunctional fluorinated additive, which restrains the complicated intermediate phases and promotes orientated crystallization of a-phase of perovskite. Furthermore, the additives in-situ polymerize during the perovskite film formation and form a hydrogen-bonded network to stabilize aphase. Remarkably, the polymerized additives endow a strongly hydrophobic effect to the bare perovskite film against liquid water for 5min. The unencapsulated devices achieve 24.10% efficiency and maintain >95% of the initial efficiency for 1000 h under continuous sunlight soaking and for 2000 h at air ambient of similar to 50% humid, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 573, "DOI": "10.1038/s41467-023-36224-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36224-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076389000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheng, L; Wang, QQ; Liu, X; Cui, H; Wang, XL; Xu, YL; Li, ZL; Wang, L; Chen, ZH; Xu, GL; Wang, JL; Tang, YP; Amine, K; Xu, H; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheng, Li; Wang, Qianqian; Liu, Xiang; Cui, Hao; Wang, Xiaolin; Xu, Yulong; Li, Zonglong; Wang, Li; Chen, Zonghai; Xu, Gui-Liang; Wang, Jianlong; Tang, Yaping; Amine, Khalil; Xu, Hong; He, Xiangming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressing electrolyte-lithium metal reactivity via Li+-desolvation in uniform nullo-porous separator", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium reactivity with electrolytes leads to their continuous consumption and dendrite growth, which constitute major obstacles to harnessing the tremendous energy of lithium-metal anode in a reversible manner. Considerable attention has been focused on inhibiting dendrite via interface and electrolyte engineering, while admitting electrolyte-lithium metal reactivity as a thermodynamic inevitability. Here, we report the effective suppression of such reactivity through a nullo-porous separator. Calculation assisted by diversified characterizations reveals that the separator partially desolvates Li+ in confinement created by its uniform nullopores, and deactivates solvents for electrochemical reduction before Li-0-deposition occurs. The consequence of such deactivation is realizing dendrite-free lithium-metal electrode, which even retaining its metallic lustre after long-term cycling in both Li-symmetric cell and high-voltage Li-metal battery with LiNi0.6Mn0.2Co0.2O2 as cathode. The discovery that a nullo-structured separator alters both bulk and interfacial behaviors of electrolytes points us toward a new direction to harness lithium-metal as the most promising anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 172, "DOI": "10.1038/s41467-021-27841-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27841-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028317800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Sheng S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding of Sulfurized Polyacrylonitrile for Superior Performance Lithium/Sulfur Battery", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfurized polyacrylonitrile (SPAN) is one of the most important sulfurized carbon materials that can potentially be coupled with the carbonaceous anode to fabricate a safe and low cost all carbon lithium-ion battery. However, its chemical structure and electrochemical properties have been poorly understood. In this discussion, we analyze the previously published data in combination with our own results to propose a more reasonable chemical structure that consists of short -S-x- chains covalently bonded onto cyclized, partially dehydrogenated, and ribbon-like polyacrylonitrile backbones. The proposed structure fits all previous structural characterizations and explains many unique electrochemical phenomena that were observed from the Li/SPAN cells but have not been understood clearly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4588, "End Page": 4600, "Article Number": null, "DOI": "10.3390/en7074588", "DOI Link": "http://dx.doi.org/10.3390/en7074588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339989200031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, L; Rada, J; Zhang, HF; Song, HM; Mirniaharikandi, S; Ooi, BS; Gan, QQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Lyu; Rada, Jacob; Zhang, Huafan; Song, Haomin; Mirniaharikandi, Seyededriss; Ooi, Boon S.; Gan, Qiaoqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainable and Inexpensive Polydimethylsiloxane Sponges for Daytime Radiative Cooling", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radiative cooling is an emerging cooling technology that can passively release heat to the environment. To obtain a subambient cooling effect during the daytime, chemically engineered structural materials are widely explored to simultaneously reject sunlight and preserve strong thermal emission. However, many previously reported fabrication processes involve hazardous chemicals, which can hinder a material's ability to be mass produced. In order to eliminate the hazardous chemicals used in the fabrication of previous works, this article reports a white polydimethylsiloxane (PDMS) sponge fabricated by a sustainable process using microsugar templates. By substituting the chemicals for sugar, the manufacturing procedure produces zero toxic waste and can also be endlessly recycled via methods widely used in the sugar industry. The obtained porous PDMS exhibits strong visible scattering and thermal emission, resulting in an efficient temperature reduction of 4.6 degrees C and cooling power of 43 W m(-2) under direct solar irradiation. In addition, due to the air-filled voids within the PDMS sponge, its thermal conductivity remains low at 0.06 W (m K)(-1). This unique combination of radiative cooling and thermal insulation properties can efficiently suppress the heat exchange with the solar-heated rooftop or the environment, representing a promising future for new energy-efficient building envelope material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 8, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102502, "DOI": "10.1002/advs.202102502", "DOI Link": "http://dx.doi.org/10.1002/advs.202102502", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000709155600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Forgan, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Forgan, Ross S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulated self-assembly of metal-organic frameworks", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exercising fine control over the synthesis of metal-organic frameworks (MOFs) is key to ensuring reproducibility of physical properties such as crystallinity, particle size, morphology, porosity, defectivity, and surface chemistry. The principle of modulated self-assembly - incorporation of modulator molecules into synthetic mixtures - has emerged as the primary means to this end. This perspective article will detail the development of modulated synthesis, focusing primarily on coordination modulation, from a technique initially intended to cap the growth of MOF crystals to one that is now used regularly to enhance crystallinity, control particle size, induce defectivity and select specific phases. The various mechanistic driving forces will be discussed, as well as the influence of modulation on physical properties and how this can facilitate potential applications. Modulation is also increasingly being used to exert kinetic control over self-assembly; examples of phase selection and the development of new protocols to induce this will be provided. Finally, the application of modulated self-assembly to alternative materials will be discussed, and future perspectives on the area given.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2020, "Volume": 11, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4546, "End Page": 4562, "Article Number": null, "DOI": "10.1039/d0sc01356k", "DOI Link": "http://dx.doi.org/10.1039/d0sc01356k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535674600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SS; Xiao, X; Gu, HY; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shangshang; Xiao, Xun; Gu, Hangyu; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iodine reduction for reproducible and high-performance perovskite solar cells and modules", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite-based electronic materials and devices such as perovskite solar cells (PSCs) have notoriously bad reproducibility, which greatly impedes both fundamental understanding of their intrinsic properties and real-world applications. Here, we report that organic iodide perovskite precursors can be oxidized to I-2 even for carefully sealed precursor powders or solutions, which markedly deteriorates the performance and reproducibility of PSCs. Adding benzylhydrazine hydrochloride (BHC) as a reductant into degraded precursor solutions can effectively reduce the detrimental I-2 back to I-, accompanied by a substantial reduction of I-3(-)-induced charge traps in the films. BHC residuals in perovskite films further stabilize the PSCs under operation conditions. BHC improves the stabilized efficiency of the blade-coated p-i-n structure PSCs to a record value of 23.2% (22.62 +/- 0.40% certified by National Renewable Energy Laboratory), and the high-efficiency devices have a very high yield. A stabilized aperture efficiency of 18.2% is also achieved on a 35.8-cm(2) mini-module.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe8130", "DOI": "10.1126/sciadv.abe8130", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe8130", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625411900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "da Cunha, MP; Ambergen, S; Debije, MG; Homburg, EFGA; den Toonder, JMJ; Schenning, APHJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "da Cunha, Marina Pilz; Ambergen, Sebastiaan; Debije, Michael G.; Homburg, Erik F. G. A.; den Toonder, Jaap M. J.; Schenning, Albert P. H. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Soft Transporter Robot Fueled by Light", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mobile organisms with ability for locomotion and transportation, such as humans and other animals, utilize orchestrated actuation to perform actions. Mimicking these functionalities in synthetic, light-responsive untethered soft-bodied devices remains a challenge. Inspired by multitasking and mobile biological systems, an untethered soft transporter robot with controlled multidirectional locomotion with the ability of picking up, transporting, and delivering cargo driven entirely by blue light is created. The soft robot design is an ensemble of light-responsive liquid crystalline polymers that can harness motion either collectively or individually to obtain a high degree of motion control for the execution of advanced tasks in a dry environment. Through orchestrated motion of the device's legs, single displacement strides, which exceed 4 mm and can be taken in any direction, allow for locomotion around objects. Untethered cargo transportation is demonstrated by a pickup and release mechanism using the device's arms. This strategy demonstrates the constructive harnessing of orchestrated motion in assemblies of established actuators, performing complex functions, mimicking constructive behavior seen in nature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902842, "DOI": "10.1002/advs.201902842", "DOI Link": "http://dx.doi.org/10.1002/advs.201902842", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507979400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WT; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Wentao; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for Water Harvesting from Air, Anywhere, Anytime", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water is essential to life. It is estimated that by 2050 nearly half of the world population will live in water stressed regions, due to either arid conditions or lack of access to clean water. This Outlook, written for the general readers, outlines the parameters of this vexing societal problem and presents a solution to the global water challenge. There is plenty of water in the air that potentially can be harvested not only from the desert atmosphere where the humidity is low but also from more humid regions of the world where dean water is needed. In principle, the materials used to harvest water from air in these climates should be applicable to deployment anywhere in the world to extract atmospheric water at any time of the year. Metal-organic frameworks (MOFs) have emerged as a unique class of porous materials capable of trapping water at relative humidity levels as low as 10%, and doing so with facile uptake and release kinetics. From laboratory testing to field trials in the driest deserts, kilogram quantities of MOFs have been tested in several generations of devices. The initial results of these experiments showed that MOFs could capture water from desert climates and deliver over one liter per kilogram of MOF per day. More than an order of magnitude increase in water productivity could be achieved with members of the MOF family when employed in an electrified device operating at many cycles per day. We show that the vision of having clean water from air anywhere in the world at any time of the year is potentially realizable with MOFs and so is the idea of giving water independence to the citizens of the world.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2020, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1348, "End Page": 1354, "Article Number": null, "DOI": "10.1021/acscentsci.0c00678", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c00678", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000566668400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, KL; Kas, R; Smith, WA; Burdyny, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Kailun; Kas, Recep; Smith, Wilson A.; Burdyny, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of the Carbon-Based Gas Diffusion Layer on Flooding in a Gas Diffusion Electrode Cell for Electrochemical CO2 Reduction", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The deployment of gas diffusion electrodes (GDEs) for the electrochemical CO2 reduction reaction (CO2RR) has enabled current densities an order of magnitude greater than those of aqueous H cells. The gains in production, however, have come with stability challenges due to rapid flooding of GDEs, which frustrate both laboratory experiments and scale-up prospects. Here, we investigate the role of carbon gas diffusion layers (GDLs) in the advent of flooding during CO2RR, finding that applied potential plays a central role in the observed instabilities. Electrochemical characterization of carbon GDLs with and without catalysts suggests that the high overpotential required during electrochemical CO2RR initiates hydrogen evolution on the carbon GDL support. These potentials impact the wetting characteristics of the hydrophobic GDL, resulting in flooding that is independent of CO2RR. Findings from this work can be extended to any electrochemical reduction reaction using carbon-based GDEs (CORR or N2RR) with cathodic overpotentials of less than -0.65 V versus a reversible hydrogen electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 33, "End Page": 40, "Article Number": null, "DOI": "10.1021/acsenergylett.0c02184", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.0c02184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609250200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lewis, JA; Cortes, FJQ; Liu, Y; Miers, JC; Verma, A; Vishnugopi, BS; Tippens, J; Prakash, D; Marchese, TS; Han, SY; Lee, C; Shetty, PP; Lee, HW; Shevchenko, P; De Carlo, F; Saldana, C; Mukherjee, PP; McDowell, MT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lewis, John A.; Cortes, Francisco Javier Quintero; Liu, Yuhgene; Miers, John C.; Verma, Ankit; Vishnugopi, Bairav S.; Tippens, Jared; Prakash, Dhruv; Marchese, Thomas S.; Han, Sang Yun; Lee, Chanhee; Shetty, Pralav P.; Lee, Hyun-Wook; Shevchenko, Pavel; De Carlo, Francesco; Saldana, Christopher; Mukherjee, Partha P.; McDowell, Matthew T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Linking void and interphase evolution to electrochemistry in solid-state batteries using operando X-ray tomography", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite progress in solid-state battery engineering, our understanding of the chemo-mechanical phenomena that govern electrochemical behaviour and stability at solid-solid interfaces remains limited compared to at solid-liquid interfaces. Here, we use operando synchrotron X-ray computed microtomography to investigate the evolution of lithium/solid-state electrolyte interfaces during battery cycling, revealing how the complex interplay among void formation, interphase growth and volumetric changes determines cell behaviour. Void formation during lithium stripping is directly visualized in symmetric cells, and the loss of contact that drives current constriction at the interface between lithium and the solid-state electrolyte (Li10SnP2S12) is quantified and found to be the primary cause of cell failure. The interphase is found to be redox-active upon charge, and global volume changes occur owing to partial molar volume mismatches at either electrode. These results provide insight into how chemo-mechanical phenomena can affect cell performance, thus facilitating the development of solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 20, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 503, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-00903-2", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-00903-2", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612600400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, CX; Xu, WD; Yang, J; Bai, S; Teng, PP; Yang, Y; Wang, JP; Zhao, N; Zhang, WJ; Huang, W; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Chunxiong; Xu, Weidong; Yang, Jie; Bai, Sai; Teng, Pengpeng; Yang, Ying; Wang, Jianpu; Zhao, Ni; Zhang, Wenjing; Huang, Wei; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bidirectional optical signal transmission between two identical devices using perovskite diodes", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A solution-processed perovskite diode that functions as both optical transmitter and receiver can be used to build a monolithic pulse sensor and a bidirectional optical communication system. The integration of optical signal generation and reception into one device-thus allowing a bidirectional optical signal transmission between two identical devices-is of value in the development of miniaturized and integrated optoelectronic devices. However, conventional solution-processable semiconductors have intrinsic material and design limitations that prevent them from being used to create such devices with a high performance. Here we report an efficient solution-processed perovskite diode that is capable of working in both emission and detection modes. The device can be switched between modes by changing the bias direction, and it exhibits light emission with an external quantum efficiency of over 21% and a light detection limit on a subpicowatt scale. The operation speed for both functions can reach tens of megahertz. Benefiting from the small Stokes shift of perovskites, our diodes exhibit a high specific detectivity (more than 2 x 10(12) Jones) at its peak emission (~804 nm), which allows an optical signal exchange between two identical diodes. To illustrate the potential of the dual-functional diode, we show that it can be used to create a monolithic pulse sensor and a bidirectional optical communication system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": 164, "Article Number": null, "DOI": "10.1038/s41928-020-0382-3", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-0382-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521121700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gild, J; Braun, J; Kaufmann, K; Marin, E; Harrington, T; Hopkins, P; Vecchio, K; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gild, Joshua; Braun, Jeffrey; Kaufmann, Kevin; Marin, Eduardo; Harrington, Tyler; Hopkins, Patrick; Vecchio, Kenneth; Luo, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-entropy silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si2", "Source Title": "JOURNAL OF MATERIOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-entropy metal disilicide, (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si-2, has been successfully synthesized. X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), and electron backscatter diffraction (EBSD) collectively show the formation of a single high-entropy silicide phase. This high-entropy (Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si-2 possesses a hexagonal C40 crystal structure with ABC stacking sequence and a space group of P6(2)22. This discovery expands the known families of high-entropy materials from metals, oxides, borides, carbides, and nitrides to a silicide, for the first time to our knowledge, as well as demonstrating that a new, non-cubic, crystal structure (with lower symmetry) can be made into high-entropy phase. This(Mo0.2Nb0.2Ta0.2Ti0.2W0.2)Si-2 exhibits high nullohardness of 16.7 +/- 1.9 GPa and Vickers hardness of 11.6 +/- 0.5 GPa. Moreover, it has a low thermal conductivity of 6.9 +/- 1.1 W m(-1) K-1, which is approximately one order of magnitude lower than that of the widely-used tetragonal MoSi2 and similar to 1/3 of those reported values for the hexagonal NbSi2 and TaSi2 with the same crystal structure. (C) 2019 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": 343, "Article Number": null, "DOI": "10.1016/j.jmat.2019.03.002", "DOI Link": "http://dx.doi.org/10.1016/j.jmat.2019.03.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000487537700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Broedersz, CP; MacKintosh, FC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Broedersz, C. P.; MacKintosh, F. C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling semiflexible polymer networks", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This is an overview of theoretical approaches to semiflexible polymers and their networks. Such semiflexible polymers have large bending rigidities that can compete with the entropic tendency of a chain to crumple up into a random coil. Many studies on semiflexible polymers and their assemblies have been motivated by their importance in biology. Indeed, cross-linked networks of semiflexible polymers form a major structural component of tissue and living cells. Reconstituted networks of such biopolymers have emerged as a new class of biological soft matter systems with remarkable material properties, which have spurred many of the theoretical developments discussed here. Starting from the mechanics and dynamics of individual semiflexible polymers, the physics of semiflexible bundles, entangled solutions, and disordered cross-linked networks are reviewed. Finally, recent developments on marginally stable fibrous networks, which exhibit critical behavior similar to other marginal systems such as jammed soft matter, are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 576, "Times Cited, All Databases": 648, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2014, "Volume": 86, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 995, "End Page": 1036, "Article Number": null, "DOI": "10.1103/RevModPhys.86.995", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.86.995", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341117500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahmood, J; Lee, EK; Jung, M; Shin, D; Choi, HJ; Seo, JM; Jung, SM; Kim, D; Li, F; Lah, MS; Park, N; Shin, HJ; Oh, JH; Baek, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahmood, Javeed; Lee, Eun Kwang; Jung, Minbok; Shin, Dongbin; Choi, Hyun-Jung; Seo, Jeong-Min; Jung, Sun-Min; Kim, Dongwook; Li, Feng; Lah, Myoung Soo; Park, Noejung; Shin, Hyung-Joon; Oh, Joon Hak; Baek, Jong-Beom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional polyaniline (C3N) from carbonized organic single crystals in solid state", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of 2D polyaniline (PANI) has attracted considerable interest due to its expected electronic and optoelectronic properties. Although PANI was discovered over 150 y ago, obtaining an atomically well-defined 2D PANI framework has been a longstanding challenge. Here, we describe the synthesis of 2D PANI via the direct pyrolysis of hexaaminobenzene trihydrochloride single crystals in solid state. The 2D PANI consists of three phenyl rings sharing six nitrogen atoms, and its structural unit has the empirical formula of C3N. The topological and electronic structures of the 2D PANI were revealed by scanning tunneling microscopy and scanning tunneling spectroscopy combined with a first-principle density functional theory calculation. The electronic properties of pristine 2D PANI films (undoped) showed ambipolar behaviors with a Dirac point of -37 V and an average conductivity of 0.72 S/cm. After doping with hydrochloric acid, the conductivity jumped to 1.41 x 10(3) S/cm, which is the highest value for doped PANI reported to date. Although the structure of 2D PANI is analogous to graphene, it contains uniformly distributed nitrogen atoms for multifunctionality; hence, we anticipate that 2D PANI has strong potential, from wet chemistry to device applications, beyond linear PANI and other 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 418, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2016, "Volume": 113, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7414, "End Page": 7419, "Article Number": null, "DOI": "10.1073/pnas.1605318113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1605318113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379021700048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, C; Ma, SJ; Hao, JM; Qiu, M; Li, X; Xiao, SY; Miao, ZQ; Dai, N; He, Q; Sun, SL; Zhou, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Che; Ma, Shaojie; Hao, Jiaming; Qiu, Meng; Li, Xin; Xiao, Shiyi; Miao, Ziqi; Dai, Ning; He, Qiong; Sun, Shulin; Zhou, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailor the Functionalities of Metasurfaces Based on a Complete Phase Diagram", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces in a metal-insulator-metal configuration have been widely used in photonics, with applications ranging from perfect absorption to phase modulation, but why and when such structures can realize what functionalities are not yet fully understood. Here, we establish a complete phase diagram in which the optical properties of such systems are fully controlled by two simple parameters (i.e., the intrinsic and radiation losses), which are, in turn, dictated by the geometrical or material properties of the underlying structures. Such a phase diagram can greatly facilitate the design of appropriate metasurfaces with tailored functionalities demonstrated by our experiments and simulations in the terahertz regime. In particular, our experiments show that, through appropriate structural or material tuning, the device can be switched across the phase boundaries yielding dramatic changes in optical responses. Our discoveries lay a solid basis for realizing functional and tunable photonic devices with such structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2015, "Volume": 115, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235503, "DOI": "10.1103/PhysRevLett.115.235503", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.235503", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365877700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, LM; Li, Q; Gui, L; Deng, Y; Wang, L; Jiao, JL; Hu, YR; Lan, XQ; Hou, JH; Li, Y; Lu, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Limei; Li, Qing; Gui, Li; Deng, Yi; Wang, Lu; Jiao, Jianlin; Hu, Yingrui; Lan, Xiaoqian; Hou, Jianhong; Li, Yao; Lu, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sequential gastrodin release PU/n-HA composite scaffolds reprogram macrophages for improved osteogenesis and angiogenesis", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wound healing is a highly orchestrated process involving a variety of cells, including immune cells. Developing immunomodulatory biomaterials for regenerative engineering applications, such as bone regeneration, is an appealing strategy. Herein, inspired by the immunomodulatory effects of gastrodin (a bioactive component in traditional Chinese herbal medicine), a series of new immunomodulatory gastrodin-comprising biodegradable polyurethane (gastrodin-PU) and nullo-hydroxyapatite (n-HA) (gastrodin-PU/n-HA) composites were developed. RAW 264.7 macrophages, rat bone marrow mesenchymal stem cells (rBMSCs), and human umbilical vein endothelial cells (HUVECs) were cultured with gastrodin-PU/n-HA containing different concentrations of gastrodin (0.5%, 1%, and 2%) to decipher their immunomodulatory effects on osteogenesis and angiogenesis in vitro. Results demonstrated that, compared with PU/n-HA, gastrodin-PU/n-HA induced macrophage polarization toward the M2 phenotype, as evidenced by the higher expression level of pro-regenerative cytokines (CD206, Arg-1) and the lower expression of pro-inflammatory cytokines (iNOS). The expression levels of osteogenesis-related factors (BMP-2 and ALP) in the rBMSCs and angiogenesis-related factors (VEGF and BFGF) in the HUVECs were significantly up-regulated in gastrodin-PU/n-HA/macrophage-conditioned medium. The immunomodulatory effects of gastrodin-PU/n-HA to reprogram macrophages from a pro-inflammatory (Ml) phenotype to an anti-inflammatory and pro-healing (M2) phenotype were validated in a rat subcutaneous implantation model. And the 2% gastrodin-PU/n-HA significantly decreased fibrous capsule formation and enhanced angiogenesis. Additionally, 2% gastrodin-PU/n-HA scaffolds implanted in the rat femoral condyle defect model showed accelerated osteogenesis and angiogenesis. Thus, the novel gastrodin-PU/n-HA scaffold may represent a new and promising immunomodulatory biomaterial for bone repair and regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24, "End Page": 37, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.03.037", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.03.037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788642400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Ozden, A; Guo, SY; de Arquer, FPG; Wang, CH; Zhang, MZ; Zhang, J; Jiang, HY; Wang, W; Dong, H; Sinton, D; Sargent, EH; Zhong, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Le; Ozden, Adnull; Guo, Shuyi; de Arquer, F. Pelayo Garcia; Wang, Chuanhao; Zhang, Mingzhe; Zhang, Jin; Jiang, Haoyang; Wang, Wei; Dong, Hao; Sinton, David; Sargent, Edward H.; Zhong, Miao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 (CO2R) to formic acid upgrades waste CO2; however, up to now, chemical and structural changes to the electrocatalyst have often led to the deterioration of performance over time. Here, we find that alloying p-block elements with differing electronegativities modulates the redox potential of active sites and stabilizes them throughout extended CO2R operation. Active Sn-Bi/SnO2 surfaces formed in situ on homogeneously alloyed Bi0.1Sn crystals stabilize the CO2R-to-formate pathway over 2400 h (100 days) of continuous operation at a current density of 100 mA cm(-2). This performance is accompanied by a Faradaic efficiency of 95% and an overpotential of similar to -0.65 V. Operating experimental studies as well as computational investigations show that the stabilized active sites offer near-optimal binding energy to the key formate intermediate OCHO. Using a cation-exchange membrane electrode assembly device, we demonstrate the stable production of concentrated HCOO- solution (3.4 molar, 15 wt%) over 100 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5223, "DOI": "10.1038/s41467-021-25573-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25573-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692406100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karmakar, S; Barman, S; Rahimi, FA; Rambabu, D; Nath, S; Maji, TK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karmakar, Sanchita; Barman, Soumitra; Rahimi, Faruk Ahamed; Rambabu, Darsi; Nath, Sukhendu; Maji, Tapas Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confining charge-transfer complex in a metal-organic framework for photocatalytic CO2 reduction in water", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the quest for renewable fuel production, the selective conversion of CO2 to CH4 under visible light in water is a leading-edge challenge considering the involvement of kinetically sluggish multiple elementary steps. Herein, 1-pyrenebutyric acid is post-synthetically grafted in a defect-engineered Zr-based metal organic framework by replacing exchangeable formate. Then, methyl viologen is incorporated in the confined space of post-modified MOF to achieve donor-acceptor complex, which acts as an antenna to harvest visible light, and regulates electron transfer to the catalytic center (Zr-oxo cluster) to enable visible-light-driven CO2 reduction reaction. The proximal presence of the charge transfer complex enhances charge transfer kinetics as realized from transient absorption spectroscopy, and the facile electron transfer helps to produce CH4 from CO2. The reported material produces 7.3 mmol g(-1) of CH4 under light irradiation in aqueous medium using sacrificial agents. Mechanistic information gleans from electron paramagnetic resonullce, in situ diffuse reflectance FT-IR and density functional theory calculation. Maji and coworkers report the selective conversion of CO2 to CH4 under visible light by utilizing a charge transfer complex within Zr-MOF-808 pores. The complex ultimately facilitates efficient multielectron reduction at the Zr-catalytic center.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4508, "DOI": "10.1038/s41467-023-40117-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40117-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038216100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HL; Qin, Y; Zhu, ZY; Jiang, Q; Ouyang, SN; Wan, YH; Qu, XR; Xu, J; Yu, ZC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Hualing; Qin, Yi; Zhu, Zhenyu; Jiang, Qing; Ouyang, Shengnull; Wan, Yuhang; Qu, Xueru; Xu, Jie; Yu, Zhicai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-Arousing Self-Powered Fire Warning E-Textile Based on p-n Segment Coaxial Aerogel Fibers for Active Fire Protection in Firefighting Clothing", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Firefighting protective clothing is a crucial protective equipment for firefighters to minimize skin burn and ensure safety firefighting operation and rescue mission. A recent increasing concern is to develop self-powered fire warning materials that can be incorporated into the firefighting clothing to achieve active fire protection for firefighters before the protective clothing catches fire on fireground. However, it is still a challenge to facilely design and manufacture thermoelectric (TE) textile (TET)-based fire warning electronics with dynamic surface conformability and breathability. Here, we develop an alternate coaxial wet-spinning strategy to continuously produce alternating p/n-type TE aerogel fibers involving n-type Ti3C2Tx MXene and p-type MXene/SWCNT-COOH as core materials, and tough aramid nullofiber as protective shell, which simultaneously ensure the flexibility and high-efficiency TE power generation. With such alternating p/n-type TE fibers, TET-based self-powered fire warning sensors with high mechanical stability and wearability are successfully fabricated through stitching the alternating p-n segment TE fibers into aramid fabric. The results indicate that TET-based fire warning electronics containing 50 p-n pairs produce the open-circuit voltage of 7.5 mV with a power density of 119.79 nW cm(-2) at a temperature difference of 300 degrees C. The output voltage signal is then calculated as corresponding surface temperature of firefighting clothing based on a linear relationship between TE voltage and temperature. The fire alarm response time and flame-retardant properties are further displayed. Such self-powered fire warning electronics are true textiles that offer breathability and compatibility with body movement, demonstrating their potential application in firefighting clothing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 226, "DOI": "10.1007/s40820-023-01200-8", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01200-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001086797900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Talirz, L; Ruffieux, P; Fasel, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Talirz, Leopold; Ruffieux, Pascal; Fasel, Roman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On-Surface Synthesis of Atomically Precise Graphene nulloribbons", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface-assisted polymerization and cyclodehydrogenation of specifically designed organic precursors provides a route toward atomically precise graphene nulloribbons, which promises to combine the outstanding electronic properties of graphene with a bandgap that is sufficiently large for room-temperature digital-logic applications. Starting from the basic concepts behind the on-surface synthesis approach, this report covers the progress made in understanding the different reaction steps, in synthesizing atomically precise graphene nulloribbons of various widths and edge structures, and in characterizing their properties, ending with an outlook on the challenges that still lie ahead.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2016, "Volume": 28, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 6222, "End Page": 6231, "Article Number": null, "DOI": "10.1002/adma.201505738", "DOI Link": "http://dx.doi.org/10.1002/adma.201505738", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382479400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, CY; Han, QR; Zhou, YQ; Wu, JJ; Shi, WQ; Gao, LP; Leblanc, RM; Peng, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Chunyu; Han, Qiurui; Zhou, Yiqun; Wu, Jiajia; Shi, Wenquan; Gao, Lipeng; Leblanc, Roger M.; Peng, Zhili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phenylenediamine-derived near infrared carbon dots: The kilogram-scale preparation, formation process, photoluminescence tuning mechanism and application as red phosphors", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Kilogram-scale preparation of near infrared (NIR) carbon dots (C-dots) from o-phenylenediamine (o-PDA) with over 96% yield was reported in this study, and the estimated cost for each gram of C-dots was only $ 0.1. The formation process of the C-dots was elucidated and the structural model was also proposed in which the key intermediates were revealed. Excitingly, the optical properties of the C-dots could be reversibly tuned via a facile protonation-deprotonation process. Upon protonation, fluorescence emission wavelength of the C-dots could be red shifted for 47 nm, and deprotonation could enhance the photoluminescence quantum yield by three times. These optical alterations were attributed to stabilization of the excited electrons by the surface protons, and diagrams showing the electronic transition states of the C-dots were proposed according to the calculated band gaps. The as prepared C-dots demonstrated themselves as cheap and readily available phosphors for the assembling of red LEDs. (C) 2022 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 198, "End Page": 208, "Article Number": null, "DOI": "10.1016/j.carbon.2022.02.054", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2022.02.054", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783471100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moll, PJW; Nair, NL; Helm, T; Potter, AC; Kimchi, I; Vishwanath, A; Analytis, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moll, Philip J. W.; Nair, Nityan L.; Helm, Toni; Potter, Andrew C.; Kimchi, Itamar; Vishwanath, Ashvin; Analytis, James G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transport evidence for Fermi-arc-mediated chirality transfer in the Dirac semimetal Cd3As2", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The dispersion of charge carriers in a metal is distinctly different from that of free electrons owing to their interactions with the crystal lattice. These interactions may lead to quasiparticles mimicking the massless relativistic dynamics of high-energy particle physics(1-3), and they can twist the quantum phase of electrons into topologically non-trivial knots-producing protected surface states with anomalous electromagnetic properties(4-9). These effects intertwine in materials known as Weyl semimetals, and in their crystal-symmetry-protected analogues, Dirac semimetals(10). The latter show a linear electronic dispersion in three dimensions described by two copies of the Weyl equation (a theoretical description of massless relativistic fermions). At the surface of a crystal, the broken translational symmetry creates topological surface states, so-called Fermi arcs(11), which have no counterparts in high-energy physics or conventional condensed matter systems. Here we present Shubnikov-de Haas oscillations in focused-ion-beam-prepared microstructures of Cd3As2 that are consistent with the theoretically predicted 'Weyl orbits', a kind of cyclotron motion that weaves together Fermi-arc and chiral bulk states(12). In contrast to conventional cyclotron orbits, this motion is driven by the transfer of chirality from one Weyl node to another, rather than momentum transfer of the Lorentz force. Our observations provide evidence for direct access to the topological properties of charge in a transport experiment, a first step towards their potential application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 343, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2016, "Volume": 535, "Issue": 7611, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 266, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature18276", "DOI Link": "http://dx.doi.org/10.1038/nature18276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379912600053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, Y; Chung, JW; Lee, GH; Kang, H; Kim, JY; Bae, C; Yoo, H; Jeong, S; Cho, H; Kang, SG; Jung, JY; Lee, DW; Gam, S; Hahm, SG; Kuzumoto, Y; Kim, SJ; Bao, ZN; Hong, Y; Yun, Y; Kim, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Yeongjun; Chung, Jong Won; Lee, Gae Hwang; Kang, Hyunbum; Kim, Joo-Young; Bae, Chisung; Yoo, Hyunjun; Jeong, Sujin; Cho, Hyeon; Kang, Sung-Gyu; Jung, Ji Young; Lee, Don-Wook; Gam, Sangah; Hahm, Suk Gyu; Kuzumoto, Yasutaka; Kim, Sang Joon; Bao, Zhenull; Hong, Yongtaek; Yun, Youngjun; Kim, Sunghan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Standalone real-time health monitoring patch based on a stretchable organic optoelectronic system", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin-like health care patches (SHPs) are next-generation health care gadgets that will enable seamless monitoring of biological signals in daily life. Skin-conformable sensors and a stretchable display are critical for the development of standalone SHPs that provide real-time information while alleviating privacy concerns related to wireless data transmission. However, the production of stretchable wearable displays with sufficient pixels to display this information remains challenging. Here, we report a standalone organic SHP that provides real-time heart rate information. The 15-mu m-thick SHP comprises a stretchable organic light-emitting diode display and stretchable organic photoplethysmography (PPG) heart rate sensor on all-elastomer substrate and operates stably under 30% strain using a combination of stress relief layers and deformable micro-cracked interconnects that reduce the mechanical stress on the active optoelectronic components. This approach provides a rational strategy for high-resolution stretchable displays, enabling the production of ideal platforms for next-generation wearable health care electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 7, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg9180", "DOI": "10.1126/sciadv.abg9180", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg9180", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658757100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Xu, YF; Lou, R; Liu, ZH; Li, M; Huang, YB; Shen, DW; Weng, HM; Wang, SC; Lei, HC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qi; Xu, Yuanfeng; Lou, Rui; Liu, Zhonghao; Li, Man; Huang, Yaobo; Shen, Dawei; Weng, Hongming; Wang, Shancai; Lei, Hechang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large intrinsic anomalous Hall effect in half-metallic ferromagnet Co3Sn2S2 with magnetic Weyl fermions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The origin of anomalous Hall effect (AHE) in magnetic materials is one of the most intriguing aspects in condensed matter physics and has been a controversial topic for a long time. Recent studies indicate that the intrinsic AHE is closely related to the Berry curvature of occupied electronic states. In a magnetic Weyl semimetal with broken time-reversal symmetry, there are significant contributions to Berry curvature around Weyl nodes, possibly leading to a large intrinsic AHE. Here, we report the quite large AHE in the half-metallic ferromagnet Co3Sn2S2 single crystal. By systematically mapping out the electronic structure of Co3Sn2S2 both theoretically and experimentally, we demonstrate that the intrinsic AHE from the Weyl fermions near the Fermi energy is dominating. The intrinsic anomalous Hall conductivity depends linearly on the magnetization and can be reproduced by theoretical simulation, in which the Weyl nodes monotonically move with the constrained magnetic moment on Co atom.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3681, "DOI": "10.1038/s41467-018-06088-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06088-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444282600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, Y; Xing, GC; Liu, K; Li, GG; Dang, PP; Liang, SS; Liu, M; Cheng, ZY; Jin, DY; Lin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Yi; Xing, Gongcheng; Liu, Kang; Li, Guogang; Dang, Peipei; Liang, Sisi; Liu, Min; Cheng, Ziyong; Jin, Dayong; Lin, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New strategy for designing orangish-redemitting phosphor via oxygen-vacancy-induced electronic localization", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphor-converted white-light-emitting diodes (pc-WLED) have been extensively employed as solid-state lighting sources, which have a very important role in people's daily lives. However, due to the scarcity of the red component, it is difficult to realize warm white light efficiently. Hence, red-emitting phosphors are urgently required for improving the illumination quality. In this work, we develop a novel orangish-red La4GeO8:Bi3+ phosphor, the emission peak of which is located at 600 nm under near-ultraviolet (n-UV) light excitation. The full width at half maximum (fwhm) is 103 nm, the internal quantum efficiency (IQE) exceeds 88%, and the external quantum efficiency (EQE) is 69%. According to Rietveld refinement analysis and density functional theory (DFT) calculations, Bi3+ ions randomly occupy all La sites in orthorhombic La4GeO8. Importantly, the oxygen-vacancy-induced electronic localization around the Bi3+ ions is the main reason for the highly efficient orangish-red luminescence. These results provide a new perspective and insight from the local electron structure for designing inorganic phosphor materials that realize the unique luminescence performance of Bi3+ ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15, "DOI": "10.1038/s41377-019-0126-1", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0126-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458554000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JW; Song, LR; Madsen, GKH; Fischer, KFF; Zhang, WQ; Shi, X; Iversen, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiawei; Song, Lirong; Madsen, Georg K. H.; Fischer, Karl F. F.; Zhang, Wenqing; Shi, Xun; Iversen, Bo B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing high-performance layered thermoelectric materials through orbital engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric technology, which possesses potential application in recycling industrial waste heat as energy, calls for novel high-performance materials. The systematic exploration of novel thermoelectric materials with excellent electronic transport properties is severely hindered by limited insight into the underlying bonding orbitals of atomic structures. Here we propose a simple yet successful strategy to discover and design high-performance layered thermoelectric materials through minimizing the crystal field splitting energy of orbitals to realize high orbital degeneracy. The approach naturally leads to design maps for optimizing the thermoelectric power factor through forming solid solutions and biaxial strain. Using this approach, we predict a series of potential thermoelectric candidates from layered CaAl2Si2-type Zintl compounds. Several of them contain nontoxic, low-cost and earth-abundant elements. Moreover, the approach can be extended to several other non-cubic materials, thereby substantially accelerating the screening and design of new thermoelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10892, "DOI": "10.1038/ncomms10892", "DOI Link": "http://dx.doi.org/10.1038/ncomms10892", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371719900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Jin, ZW; Liang, L; Bian, H; Bai, DL; Wang, HR; Zhang, JR; Wang, Q; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kang; Jin, Zhiwen; Liang, Lei; Bian, Hui; Bai, Dongliang; Wang, Haoran; Zhang, Jingru; Wang, Qian; Liu Shengzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-inorganic cesium lead iodide perovskite solar cells with stabilized efficiency beyond 15%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the black cesium lead iodide (CsPbI3) tends to transit into a yellow d-phase at ambient, it is imperative to develop a stabilized black phase for photovoltaic applications. Herein, we report a distorted black CsPbI3 film by exploiting the synergistic effect of hydroiodic acid (HI) and phenylethylammonium iodide (PEAI) additives. It is found that the HI induces formation of hydrogen lead iodide (HPbI3+x), an intermediate to the distorted black phase with appropriate band gap of 1.69 eV; while PEAI provides nucleation for optimized crystallization. More importantly, it stabilizes the distorted black phase by hindering phase transition via its steric effects. Upon optimization, we have attained solar cell efficiency as high as 15.07%. Specifically, the bare cell without any encapsulation shows negligible efficiency loss after 300 h of light soaking. The device keeps 92% of its initial cell efficiency after being stored for 2 months under ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4544, "DOI": "10.1038/s41467-018-06915-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06915-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448807000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abanades, JC; Arias, B; Lyngfelt, A; Mattisson, T; Wiley, DE; Li, H; Ho, MT; Mangano, E; Brandani, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abanades, J. C.; Arias, B.; Lyngfelt, A.; Mattisson, T.; Wiley, D. E.; Li, H.; Ho, M. T.; Mangano, E.; Brandani, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging CO2 capture systems", "Source Title": "INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In 2005, the IPCC SRCCS recognized the large potential for developing and scaling up a wide range of emerging CO2 capture technologies that promised to deliver lower energy penalties and cost. These included new energy conversion technologies such as chemical looping and novel capture systems based on the use of solid sorbents or membrane-based separation systems. In the last 10 years, a substantial body of scientific and technical literature on these topics has been produced from a large number of R&D projects worldwide, trying to demonstrate these concepts at increasing pilot scales, test and model the performance of key components at bench scale, investigate and develop improved functional materials, optimize the full process schemes with a view to a wide range of industrial applications, and to carry out more rigorous cost studies etc. This paper presents a general and critical review of the state of the art of these emerging CO2 capture technologies paying special attention to specific process routes that have undergone a substantial increase in technical readiness level toward the large scales required by any CO2 capture system. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 40, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 126, "End Page": 166, "Article Number": null, "DOI": "10.1016/j.ijggc.2015.04.018", "DOI Link": "http://dx.doi.org/10.1016/j.ijggc.2015.04.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361577100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Buswell, RA; de Silva, WRL; Jones, SZ; Dirrenberger, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Buswell, R. A.; de Silva, W. R. Leal; Jones, S. Z.; Dirrenberger, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing using concrete extrusion: A roadmap for research", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale additive manufacturing processes for construction utilise computer-controlled placement of extruded cement-based mortar to create physical objects layer-by-layer. Demonstrated applications include component manufacture and placement of in-situ walls for buildings. These applications vary the constraints on design parameters and present different technical issues for the production process. In this paper, published and new work are utilised to explore the relationship between fresh and hardened paste, mortar, and concrete material properties and how they influence the geometry of the created object. Findings are classified by construction application to create a matrix of issues that identifies the spectrum of future research exploration in this emerging field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 862, "Times Cited, All Databases": 933, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 37, "End Page": 49, "Article Number": null, "DOI": "10.1016/j.cemconres.2018.05.006", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2018.05.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444357300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, XS; Ke, CF; Bruns, CJ; McGonigal, PR; Pettman, RB; Stoddart, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Xisen; Ke, Chenfeng; Bruns, Carson J.; McGonigal, Paul R.; Pettman, Roger B.; Stoddart, J. Fraser", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable solid-state fluorescent materials for supramolecular encryption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tunable solid-state fluorescent materials are ideal for applications in security printing technologies. A document possesses a high level of security if its encrypted information can be authenticated without being decoded, while also being resistant to counterfeiting. Herein, we describe a heterorotaxane with tunable solid-state fluorescent emissions enabled through reversible manipulation of its aggregation by supramolecular encapsulation. The dynamic nature of this fluorescent material is based on a complex set of equilibria, whose fluorescence output depends non-linearly on the chemical inputs and the composition of the paper. By applying this system in fluorescent security inks, the information encoded in polychromic images can be protected in such a way that it is close to impossible to reverse engineer, as well as being easy to verify. This system constitutes a unique application of responsive complex equilibria in the form of a cryptographic algorithm that protects valuable information printed using tunable solid-state fluorescent materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6884, "DOI": "10.1038/ncomms7884", "DOI Link": "http://dx.doi.org/10.1038/ncomms7884", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353703600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZX; He, TYY; Zhu, ML; Sun, ZD; Shi, QF; Zhu, JX; Dong, BW; Yuce, MR; Lee, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zixuan; He, Tianyiyi; Zhu, Minglu; Sun, Zhongda; Shi, Qiongfeng; Zhu, Jianxiong; Dong, Bowei; Yuce, Mehmet Rasit; Lee, Chengkuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep learning-enabled triboelectric smart socks for IoT-based gait analysis and VR applications", "Source Title": "NPJ FLEXIBLE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The era of artificial intelligence and internet of things is rapidly developed by recent advances in wearable electronics. Gait reveals sensory information in daily life containing personal information, regarding identification and healthcare. Current wearable electronics of gait analysis are mainly limited by high fabrication cost, operation energy consumption, or inferior analysis methods, which barely involve machine learning or implement nonoptimal models that require massive datasets for training. Herein, we developed low-cost triboelectric intelligent socks for harvesting waste energy from low-frequency body motions to transmit wireless sensory data. The sock equipped with self-powered functionality also can be used as wearable sensors to deliver information, regarding the identity, health status, and activity of the users. To further address the issue of ineffective analysis methods, an optimized deep learning model with an end-to-end structure on the socks signals for the gait analysis is proposed, which produces a 93.54% identification accuracy of 13 participants and detects five different human activities with 96.67% accuracy. Toward practical application, we map the physical signals collected through the socks in the virtual space to establish a digital human system for sports monitoring, healthcare, identification, and future smart home applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2020, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29, "DOI": "10.1038/s41528-020-00092-7", "DOI Link": "http://dx.doi.org/10.1038/s41528-020-00092-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605476200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, MJ; Sun, P; Han, K; Pang, ZJ; Du, J; Li, JL; Chen, J; Wang, ZL; Mai, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Meijia; Sun, Peng; Han, Kai; Pang, Zhenjiang; Du, Jun; Li, Jinliang; Chen, Jian; Wang, Zhong Lin; Mai, Wenjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring water structure with high-tetrahedral-entropy for antifreezing electrolytes and energy storage at-80 °C", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of unsolved puzzles about water lies in how ion-water interplay affects its freezing point. Here, we report the direct link between tetrahedral entropy and the freezing behavior of water in Zn2+-based electrolytes by analyzing experimental spectra and molecular simulation results. A higher tetrahedral entropy leads to lower freezing point, and the freezing temperature is directly related to the entropy value. By tailoring the entropy of water using different anions, we develop an ultralow temperature aqueous polyaniline| |Zn battery that exhibits a high capacity (74.17 mAh g(-1)) at 1 A g(-1) and -80 degrees C with similar to 85% capacity retention after 1200 cycles due to the high electrolyte ionic conductivity (1.12 mS cm(-1)). Moreover, an improved cycling life is achieved with similar to 100% capacity retention after 5000 cycles at -70 degrees C. The fabricated battery delivers appreciably enhanced performance in terms of frost resistance and stability. This work serves to provide guidance for the design of ultralow temperature aqueous batteries by precisely tuning the water structure within electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 601, "DOI": "10.1038/s41467-023-36198-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36198-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jouny, M; Hutchings, GS; Jiao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jouny, Matthew; Hutchings, Gregory S.; Jiao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon monoxide electroreduction as an emerging platform for carbon utilization", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical conversion of carbon dioxide to value-added chemical products has been heavily explored as a promising strategy for carbon utilization. However, the direct synthesis of multi-carbon (C2+) products suffers from undesired side reactions and relatively low selectivity. Electrochemically converting CO2 to single-carbon products is much more effective and being commercially deployed. Recent studies have shown that CO can be electrochemically transformed further to C2+ at high reaction rates, high C2+ selectivity and inherently improved electrolyte stability, raising the prospect of a two-step pathway to transform CO2. In this Perspective, the progress towards high-rate CO conversion is shown alongside mechanistic insights and device designs that can improve performance even further. A techno-economic analysis of the two-step conversion process and cradle-to-gate lifecycle assessment shows the economic feasibility and improved environmental impact of a high-volume commercial process generating acetic acid and ethylene compared to the current state of the art.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1062, "End Page": 1070, "Article Number": null, "DOI": "10.1038/s41929-019-0388-2", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0388-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502586500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mattos, BD; Zhu, Y; Tardy, BL; Beaumont, M; Ribeiro, ACR; Missio, AL; Otoni, CG; Rojas, OJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mattos, Bruno D.; Zhu, Ya; Tardy, Blaise L.; Beaumont, Marco; Ribeiro, Ana Carolina R.; Missio, Andre L.; Otoni, Caio G.; Rojas, Orlando J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Versatile Assembly of Metal-Phenolic Network Foams Enabled by Tannin-Cellulose nullofibers", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-phenolic network (MPN) foams are prepared using colloidal suspensions of tannin-containing cellulose nullofibers (CNFs) that are ice-templated and thawed in ethanolic media in the presence of metal nitrates. The MPN facilitates the formation of solid foams by air drying, given the strength and self-supporting nature of the obtained tannin-cellulose nullohybrid structures. The porous characteristics and (dry and wet) compression strength of the foams are rationalized by the development of secondary, cohesive metal-phenolic layers combined with a hydrogen bonding network involving the CNF. The shrinkage of the MPN foams is as low as 6% for samples prepared with 2.5-10% tannic acid (or condensed tannin at 2.5%) with respect to CNF content. The strength of the MPN foams reaches a maximum at 10% tannic acid (using Fe-(III) ions), equivalent to a compressive strength 70% higher than that produced with tannin-free CNF foams. Overall, a straightforward framework is introduced to synthesize MPN foams whose physical and mechanical properties are tailored by the presence of tannins as well as the metal ion species that enable the metal-phenolic networking. Depending on the metal ion, the foams are amenable to modification according to the desired application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209685", "DOI Link": "http://dx.doi.org/10.1002/adma.202209685", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000929509900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Jungfleisch, MB; Jiang, WJ; Pearson, JE; Hoffmann, A; Freimuth, F; Mokrousov, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Jungfleisch, Matthias B.; Jiang, Wanjun; Pearson, John E.; Hoffmann, Axel; Freimuth, Frank; Mokrousov, Yuriy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin Hall Effects in Metallic Antiferromagnets", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate four CuAu-I-type metallic antiferromagnets for their potential as spin current detectors using spin pumping and inverse spin Hall effect. Nontrivial spin Hall effects were observed for FeMn, PdMn, and IrMn while a much higher effect was obtained for PtMn. Using thickness-dependent measurements, we determined the spin diffusion lengths of these materials to be short, on the order of 1 nm. The estimated spin Hall angles of the four materials follow the relationship PtMn > IrMn > PdMn > FeMn, highlighting the correlation between the spin-orbit coupling of nonmagnetic species and the magnitude of the spin Hall effect in their antiferromagnetic alloys. These experiments are compared with first-principles calculations. Engineering the properties of the antiferromagnets as well as their interfaces can pave the way for manipulation of the spin dependent transport properties in antiferromagnet-based spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2014, "Volume": 113, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 196602, "DOI": "10.1103/PhysRevLett.113.196602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.196602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344496600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XN; Tong, YF; Feng, WT; Liu, PY; Li, XJ; Cui, YP; Cai, TH; Zhao, LM; Xue, QZ; Yan, ZF; Yuan, X; Xing, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoning; Tong, Yanfu; Feng, Wenting; Liu, Pengyun; Li, Xuejin; Cui, Yongpeng; Cai, Tonghui; Zhao, Lianming; Xue, Qingzhong; Yan, Zifeng; Yuan, Xun; Xing, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Embedding oxophilic rare-earth single atom in platinum nulloclusters for efficient hydrogen electro-oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing Pt-based electrocatalysts with high catalytic activity and CO tolerance is challenging but extremely desirable for alkaline hydrogen oxidation reaction. Herein we report the design of a series of single-atom lanthanide (La, Ce, Pr, Nd, and Lu)-embedded ultrasmall Pt nulloclusters for efficient alkaline hydrogen electro-oxidation catalysis based on vapor filling and spatially confined reduction/growth of metal species. Mechanism studies reveal that oxophilic single-atom lanthanide species in Pt nulloclusters can serve as the Lewis acid site for selective OH- adsorption and regulate the binding strength of intermediates on Pt sites, which promotes the kinetics of hydrogen oxidation and CO oxidation by accelerating the combination of OH- and *H/*CO in kinetics and thermodynamics, endowing the electrocatalyst with up to 14.3-times higher mass activity than commercial Pt/C and enhanced CO tolerance. This work may shed light on the design of metal nullocluster-based electrocatalysts for energy conversion. Exploring enhanced catalysts for alkaline hydrogen oxidation with high catalytic activity and CO tolerance is highly desired yet challenging. Here, the authors report single-atom lanthanide embedded Pt nulloclusters with high activities and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3767, "DOI": "10.1038/s41467-023-39475-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39475-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001018100800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, X; Wang, XT; Le, JB; Li, SM; Wang, X; Zhang, YJ; Radjenovic, P; Zhao, Y; Wang, YH; Lin, XM; Dong, JC; Li, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xing; Wang, Xiao-Ting; Le, Jia-Bo; Li, Shu-Min; Wang, Xue; Zhang, Yu-Jin; Radjenovic, Petar; Zhao, Yu; Wang, Yao-Hui; Lin, Xiu-Mei; Dong, Jin-Chao; Li, Jian-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the role of interfacial water and key intermediates at ruthenium surfaces in the alkaline hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ruthenium exhibits comparable or even better alkaline hydrogen evolution reaction activity than platinum, however, the mechanistic aspects are yet to be settled, which are elucidated by combining in situ Raman spectroscopy and theoretical calculations herein. We simultaneously capture dynamic spectral evidence of Ru surfaces, interfacial water, *H and *OH intermediates. Ru surfaces exist in different valence states in the reaction potential range, dissociating interfacial water differently and generating two distinct *H, resulting in different activities. The local cation tuning effect of hydrated Na+ ion water and the large work function of high-valence Ru(n+) surfaces promote interfacial water dissociation. Moreover, compared to low-valence Ru(0) surfaces, high-valence Ru(n+) surfaces have more moderate adsorption energies for interfacial water, *H, and *OH. They, therefore, facilitate the activity. Our findings demonstrate the regulation of valence state on interfacial water, intermediates, and finally the catalytic activity, which provide guidelines for the rational design of high-efficiency catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5289, "DOI": "10.1038/s41467-023-41030-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41030-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058614600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, ML; Guo, QL; Escano, L; Nabaa, A; Hojjatzadeh, SMH; Young, ZA; Chen, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Minglei; Guo, Qilin; Escano, Luis, I; Nabaa, Ali; Hojjatzadeh, S. Mohammad H.; Young, Zachary A.; Chen, Lianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling process instability for defect lean metal additive manufacturing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects induced by process instabilities in metal additive manufacturing limit its applications. Here, the authors report controlling laser-powder bed interaction instabilities by nulloparticles leads to defect lean metal additive manufacturing. The process instabilities intrinsic to the localized laser-powder bed interaction cause the formation of various defects in laser powder bed fusion (LPBF) additive manufacturing process. Particularly, the stochastic formation of large spatters leads to unpredictable defects in the as-printed parts. Here we report the elimination of large spatters through controlling laser-powder bed interaction instabilities by using nulloparticles. The elimination of large spatters results in 3D printing of defect lean sample with good consistency and enhanced properties. We reveal that two mechanisms work synergistically to eliminate all types of large spatters: (1) nulloparticle-enabled control of molten pool fluctuation eliminates the liquid breakup induced large spatters; (2) nulloparticle-enabled control of the liquid droplet coalescence eliminates liquid droplet colliding induced large spatters. The nulloparticle-enabled simultaneous stabilization of molten pool fluctuation and prevention of liquid droplet coalescence discovered here provide a potential way to achieve defect lean metal additive manufacturing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1079, "DOI": "10.1038/s41467-022-28649-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28649-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000762439700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; Li, JL; Liu, Y; Wang, MW; Qiao, L; Gao, XY; Chang, YF; Du, HL; Xu, Z; Zhang, SJ; Li, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuai; Li, Jinglei; Liu, Yao; Wang, Mingwen; Qiao, Liao; Gao, Xiangyu; Chang, Yunfei; Du, Hongliang; Xu, Zhuo; Zhang, Shujun; Li, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Textured ferroelectric ceramics with high electromechanical coupling factors over a broad temperature range", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The figure-of-merits of ferroelectrics for transducer applications are their electromechanical coupling factor and the operable temperature range. Relaxor-PbTiO3 ferroelectric crystals show a much improved electromechanical coupling factor k(33) (88 similar to 93%) compared to their ceramic counterparts (65 similar to 78%) by taking advantage of the strong anisotropy of crystals. However, only a few relaxor-PbTiO3 systems, for example Pb(In1/2Nb1/2)O-3-Pb(Mg1/3Nb2/3)O-3-PbTiO3, can be grown into single crystals, whose operable temperature range is limited by their rhombohedral-tetragonal phase transition temperatures (T-rt: 60 similar to 120 degrees C). Here, we develop a templated grain-growth approach to fabricate <001>-textured Pb(In1/2Nb1/2)O-3-Pb(Sc1/2Nb1/2)O-3-PbTiO3 (PIN-PSN-PT) ceramics that contain a large amount of the refractory component Sc2O3, which has the ability to increase the T-rt of the system. The high k(33) of 85 similar to 89% and the greatly increased T-rt of 160 similar to 200 degrees C are simultaneously achieved in the textured PIN-PSN-PT ceramics. The above merits will make textured PIN-PSN-PT ceramics an alternative to single crystals, benefiting the development of numerous advanced piezoelectric devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1414, "DOI": "10.1038/s41467-021-21673-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21673-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626587500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amdouni, W; Fricaudet, M; Otonicar, M; Garcia, V; Fusil, S; Kreisel, J; Maghraoui-Meherzi, H; Dkhil, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amdouni, Wafa; Fricaudet, Matthieu; Otonicar, Mojca; Garcia, Vincent; Fusil, Stephane; Kreisel, Jens; Maghraoui-Meherzi, Hager; Dkhil, Brahim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "BiFeO3 nulloparticles: The Holy-Grail of Piezo-Photocatalysts?", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, piezoelectric-based catalysis has been demonstrated to be an efficient means and promising alternative to sunlight-driven photocatalysis, where mechanical vibrations trigger redox reactions. Here, 60 nm-size BiFeO3 nulloparticles are shown to be very effective for piezo-degrading Rhodamine B (RhB) model dye with record degradation rate reaching 13 810 L mol(-1) min(-1), and even 41 750 L mol(-1) min(-1) (i.e., 100% RhB degradation within 5 min) when piezocatalysis is synergistically combined with sunlight photocatalysis. These BiFeO3 piezocatalytic nulloparticles are also demonstrated to be versatile toward several dyes and pharmaceutical pollutants, with over 80% piezo-decomposition within 120 min. The maintained high piezoelectric coefficient combined with low dielectric constant, high-elastic modulus, and the nullosized shape make these BiFeO3 nulloparticles extremely efficient piezocatalysts. To avoid subsequent secondary pollution and enable their reusability, the BiFeO3 nulloparticles are further embedded in a polymer P(VDF-TrFE) matrix. The as-designed flexible, chemically stable, and recyclable nullocomposites still keep remarkable piezocatalytic and piezo-photocatalytic performances (i.e., 92% and 100% RhB degradation, respectively, within 20 min). This work opens a new research avenue for BiFeO3 that is the model multiferroic and offers a new platform for water cleaning, as well as other applications such as water splitting, CO2 reduction, or surface purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 35, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202301841", "DOI Link": "http://dx.doi.org/10.1002/adma.202301841", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011440900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Shen, ZH; Pan, ZH; Kou, ZK; Liu, XM; Zhang, H; Gu, QL; Guan, C; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Shen, Zhehong; Pan, Zhenghui; Kou, Zongkui; Liu, Ximeng; Zhang, Hong; Gu, Qilin; Guan, Cao; Wang, John", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical Micro-nullo Sheet Arrays of Nickel-Cobalt Double Hydroxides for High-Rate Ni-Zn Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of nickel-based cathodes with highly ordered micro-nullo hierarchical architectures by a facile process is fantastic but challenging to achieve for high-capacity and high-rate Ni-Zn batteries. Herein, a one-step etching-deposition-growth process is demonstrated to prepare hierarchical micro-nullo sheet arrays for Ni-Zn batteries with outstanding performance and high rate. The fabrication process is conducted at room temperature without any need of heating and stirring, and the as-grown nickel-cobalt double hydroxide (NiCo-DH) supported on conductive nickel substrate is endowed with a unique 3D hierarchical architecture of micro-nullo sheet arrays, which empower the effective exposure of active materials, easy electrolyte access, fast ion diffusion, and rapid electron transfer. Benefiting from these merits in combination, the NiCo-DH electrode delivers a high specific capacity of 303.6 mAh g(-1) and outstanding rate performance (80% retention after 20-fold current increase), which outperforms the electrodes made of single Ni(OH)(2) and Co(OH)(2) , and other similar materials. The NiCo-DH electrode, when employed as the cathode for a Ni-Zn battery, demonstrates a high specific capacity of 329 mAh g(-1) . Moreover, the NiCo-DH//Zn battery also exhibits high electrochemical energy conversion efficiency, excellent rate capability (62% retention after 30-fold current increase), ultrafast charge characteristics, and strong tolerance to the high-speed conversion reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802002, "DOI": "10.1002/advs.201802002", "DOI Link": "http://dx.doi.org/10.1002/advs.201802002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464827300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YK; Wang, YJ; Yu, JY; Xiong, GW; Niu, HS; Li, Y; Sun, DH; Zhang, XL; Liu, H; Zhou, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuke; Wang, Yijie; Yu, Jiayuan; Xiong, Guowei; Niu, Hongsen; Li, Yang; Sun, Dehui; Zhang, Xiaoli; Liu, Hong; Zhou, Weijia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Underfocus Laser Induced Ni nulloparticles Embedded Metallic MoN Microrods as Patterned Electrode for Efficient Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal nitrides have shown large potential in industrial application for realization of the high active and large current density toward overall water splitting, a strategy to synthesize an inexpensive electrocatalyst consisting of Ni nulloparticles embedded metallic MoN microrods cultured on roughened nickel sheet (Ni/MoN/rNS) through underfocus laser heating on NiMoO4 center dot xH(2)O under NH3 atmosphere is posited. The proposed laser preparation mechanism of infocus and underfocus modes confirms that the laser induced stress and local high temperature controllably and rapidly prepared the patterned Ni/MoN/rNS electrodes in large size. The designed Ni/MoN/rNS presents outstanding catalytic performance for hydrogen evolution reaction (HER) with a low overpotential of 67 mV to deliver a current density of 10 mA cm(-2) and for the oxygen evolution reaction (OER) with a small overpotential of 533 mV to deliver 200 mA cm(-2). Density functional theory (DFT) calculations and Kelvin probe force microscopy (KPFM) further verify that the constructed interface of Ni/MoN with small hydrogen absorption Gibbs free energy (Delta G(H*)) (-0.19 eV) and similar electrical conductivity between Ni and metallic MoN, which can explain the high intrinsic catalytic activity of Ni/MoN. Further, the constructed two-electrode system (-) Ni/MoN/rNS||Ni/MoN/rNS (+) is employed in an industrial water-splitting electrolyzer (460 mA cm(-2) for 120 h), being superior to the performance of commercial nickel electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105869, "DOI": "10.1002/advs.202105869", "DOI Link": "http://dx.doi.org/10.1002/advs.202105869", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750342400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, KL; Li, CH; Zhang, XL; Wang, L; Wang, WT; Meng, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Kelei; Li, Chunhu; Zhang, Xiuli; Wang, Liang; Wang, Wentai; Meng, Xiangchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembly synthesis of phosphorus-doped tubular g-C3N4/Ti3C2 MXene Schottky junction for boosting photocatalytic hydrogen evolution", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Establishing highly effective charge transfer channels in carbon nitride (g-C3N4) to enhance its photocatalytic activity is still a challenging issue. Herein, the delaminated 2D Ti3C2 MXene nullosheets were employed to decorate the P-doped tubular g-C3N4 (PTCN) for engineering 1D/2D Schottky heterojunction (PTCN/TC) through electrostatic self-assembly. The optimized PTCN/TC exhibited the highest hydrogen evolution rate (565 mmol h-1 g-1), which was 4.3 and 2.0-fold higher than pristine bulk g-C3N4 and PTCN, respectively. Such enhancement may be primarily attributed to the phosphorus heteroatom doped and unique structure of 1D/2D g-C3N4/Ti3C2 Schottky heterojunction, enhancing the light-harvesting and charges' separation. One-dimensional pathway of g-C3N4 tube and built-in electric field of interfacial Schottky effect can significantly facilitate the spatial separation of photogenerated charge carriers, and simultaneously inhibit their recombination via Schottky barrier. In this composite, metallic Ti3C2 was served as electrons sink and photons collector. Moreover, ultrathin Ti3C2 flake with exposed terminal metal sites as a co-catalyst exhibited higher photocatalytic reactivity in H2 evo-lution compared to carbon materials (such as reduced graphene oxide). This work not only proposed the mechanism of tubular g-C3N4/ Ti3C2 Schottky junction in photocatalysis, but also provided a feasible way to load ultrathin Ti3C2 as a co-catalyst for designing highly efficient photocatalysts. (c) 2021 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Com-munications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 233, "End Page": 245, "Article Number": null, "DOI": "10.1016/j.gee.2021.03.011", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2021.03.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937733100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DW; Fan, ZM; Zhou, D; Khesro, A; Murakami, S; Feteira, A; Zhao, QL; Tan, XL; Reaney, IM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dawei; Fan, Zhongming; Zhou, Di; Khesro, Amir; Murakami, Shunsuke; Feteira, Antonio; Zhao, Quanliang; Tan, Xiaoli; Reaney, Ian M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuth ferrite-based lead-free ceramics and multilayers with high recoverable energy density", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead-free ceramics with high recoverable energy density (W-rec) and energy storage efficiency () are attractive for advanced pulsed power capacitors to enable greater miniaturization and integration. In this work, dense bismuth ferrite (BF)-based, lead-free 0.75(Bi1-xNdx)FeO3-0.25BaTiO(3) (BNxF-BT) ceramics and multilayers were fabricated. A transition from a mixed pseudocubic and R3c to a purely pseudocubic structure was observed as x increased with the optimum properties obtained for mixed compositions. The highest energy densities, W approximate to 4.1 J cm(-3) and W-rec approximate to 1.82 J cm(-3), were achieved for BN15F-BT, due to the enhanced breakdown field strength (BDS approximate to 180 kV cm(-1)) and large maximum polarization (P-max approximate to 40 C cm(-2)). The multilayers of this composition possessed both a high W-rec of 6.74 J cm(-3) and of 77% and were stable up to 125 degrees C. Nd doped BF-based ceramics with enhanced BDS and large W-rec are therefore considered promising candidates for lead-free energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2018, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4133, "End Page": 4144, "Article Number": null, "DOI": "10.1039/c7ta09857j", "DOI Link": "http://dx.doi.org/10.1039/c7ta09857j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426704100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XK; Xu, LC; Ding, LC; Wang, JH; Shen, MS; Lu, XF; Zhu, ZW; Behnia, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaokang; Xu, Liangcai; Ding, Linchao; Wang, Jinhua; Shen, Mingsong; Lu, Xiufang; Zhu, Zengwei; Behnia, Kamran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalous Nernst and Righi-Leduc Effects in Mn3Sn: Berry Curvature and Entropy Flow", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a study of electric, thermal and thermoelectric response in noncollinear antiferromagnet Mn3Sn, which hosts a large anomalous Hall effect (AHE). Berry curvature generates off-diagonal thermal (Righi-Leduc) and thermoelectric (Nernst) signals, which are detectable at room temperature and invertible with a small magnetic field. The thermal and electrical Hall conductivities respect the Wiedemann-Franz law, implying that the transverse currents induced by the Berry curvature are carried by Fermi surface quasiparticles. In contrast to conventional ferromagnets, the anomalous Lorenz number remains close to the Sommerfeld number over the whole temperature range of study, excluding any contribution by inelastic scattering and pointing to the Berry curvature as the unique source of AHE. The anomalous off-diagonal thermo-electric and Hall conductivities are strongly temperature dependent and their ratio is close to k(B)/e.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 119, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 56601, "DOI": "10.1103/PhysRevLett.119.056601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.056601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406678000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZK; Jiang, K; Yang, GF; Lai, JYL; Ma, TX; Zhao, JB; Ma, W; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhengke; Jiang, Kui; Yang, Guofang; Lai, Joshua Yuk Lin; Ma, Tingxuan; Zhao, Jingbo; Ma, Wei; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Donor polymer design enables efficient non-fullerene organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve efficient organic solar cells, the design of suitable donor-acceptor couples is crucially important. State-of-the-art donor polymers used in fullerene cells may not perform well when they are combined with non-fullerene acceptors, thus new donor polymers need to be developed. Here we report non-fullerene organic solar cells with efficiencies up to 10.9%, enabled by a novel donor polymer that exhibits strong temperature-dependent aggregation but with intentionally reduced polymer crystallinity due to the introduction of a less symmetric monomer unit. Our comparative study shows that an analogue polymer with a C2 symmetric monomer unit yields highly crystalline polymer films but less efficient non-fullerene cells. Based on a monomer with a mirror symmetry, our best donor polymer exhibits reduced crystallinity, yet such a polymer matches better with small molecular acceptors. This study provides important insights to the design of donor polymers for non-fullerene organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13094, "DOI": "10.1038/ncomms13094", "DOI Link": "http://dx.doi.org/10.1038/ncomms13094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386217500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dramicanin, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dramicanin, Miroslav D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trends in luminescence thermometry", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Following astonishing growth in the last decade, the field of luminescence thermometry has reached the stage of becoming a mature technology. To achieve that goal, further developments should resolve inherent problems and methodological faults to facilitate its widespread use. This perspective presents recent findings in luminescence thermometry, with the aim of providing a guide for the reader to the paths in which this field is currently directed. Besides the well-known temperature read-out techniques, which are outlined and compared in terms of performance, some recently introduced read-out methods have been discussed in more detail. These include intensity ratio measurements that exploit emissions from excited lanthanide levels with large energy differences, dual-excited and time-resolved single-band ratiometric methods, and phase-angle temperature readouts. The necessity for the extension of theoretical models and a careful re-examination of those currently in use are emphasized. Regarding materials, the focus of this perspective is on dual-activated probes for the luminescence intensity ratio (LIR) and transition-metal-ion-activated phosphors for both lifetime and LIR thermometry. Several particularly important applications of luminescence thermometry are presented. These include temperature measurement in catalysis, in situ temperature mapping for microfluidics, thermal history measurement, thermometry at extremely high temperatures, fast temperature transient measurement, low-pressure measurement via upconversion nulloparticle emission intensity ratios, evaluation of the photothermal chirality of noble metal clusters, and luminescence thermometry using mobile devices. Routes for the development of primary luminescence thermometry are discussed in view of the recent redefinition of the kelvin. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2020, "Volume": 128, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 40902, "DOI": "10.1063/5.0014825", "DOI Link": "http://dx.doi.org/10.1063/5.0014825", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555430700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rajendran, S; Khan, MM; Gracia, F; Qin, JQ; Gupta, VK; Arumainathan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rajendran, Saravanull; Khan, Mohammad Mansoob; Gracia, F.; Qin, Jiaqian; Gupta, Vinod Kumar; Arumainathan, Stephen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ce3+-ion-induced visible-light photocatalytic degradation and electrochemical activity of ZnO/CeO2 nullocomposite", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, pure ZnO, CeO2 and ZnO/CeO2 nullocomposites were synthesized using a thermal decomposition method and subsequently characterized using different standard techniques. High-resolution X-ray photoelectron spectroscopy measurements confirmed the oxidation states and presence of Zn2+, Ce4+, Ce3+ and different bonded oxygen species in the nullocomposites. The prepared pure ZnO and CeO2 as well as the ZnO/CeO2 nullocomposites with various proportions of ZnO and CeO2 were tested for photocatalytic degradation of methyl orange, methylene blue and phenol under visible-light irradiation. The optimized and highly efficient ZnO/CeO2 (90:10) nullocomposite exhibited enhanced photocatalytic degradation performance for the degradation of methyl orange, methylene blue, and phenol as well as industrial textile effluent compared to ZnO, CeO2 and the other investigated nullocomposites. Moreover, the recycling results demonstrate that the ZnO/CeO2 (90:10) nullocomposite exhibited good stability and long-term durability. Furthermore, the prepared ZnO/CeO2 nullocomposites were used for the electrochemical detection of uric acid and ascorbic acid. The ZnO/CeO2 (90:10) nullocomposite also demonstrated the best detection, sensitivity and performance among the investigated materials in this application. These findings suggest that the synthesized ZnO/CeO2 (90:10) nullocomposite could be effectively used in various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 536, "Times Cited, All Databases": 541, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31641, "DOI": "10.1038/srep31641", "DOI Link": "http://dx.doi.org/10.1038/srep31641", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392124500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McGuire, CV; Forgan, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McGuire, Christina V.; Forgan, Ross S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The surface chemistry of metal-organic frameworks", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) have received particular attention over the last 20 years as a result of their attractive properties offering potential applications in a number of areas. Typically, these characteristics are tuned by functionalisation of the bulk of the MOF material itself. This Feature Article focuses instead on modification of MOF particles at their surfaces only, which can also offer control over the bulk properties of the material. The differing surface modification techniques available to the synthetic chemist will be discussed, with a focus on the effect of surface modification of MOFs on their fundamental properties and application in adsorption, catalysis, drug delivery and other areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 51, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5199, "End Page": 5217, "Article Number": null, "DOI": "10.1039/c4cc04458d", "DOI Link": "http://dx.doi.org/10.1039/c4cc04458d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351393600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, X; Hajek, J; Jena, HS; Wang, GB; Veerapandian, SKP; Morent, R; De Geyter, N; Leyssens, K; Hoffman, AEJ; Meynen, V; Marquez, C; De Vos, DE; Van Speybroeck, V; Leus, K; Van Der Voort, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Xiao; Hajek, Julianna; Jena, Himanshu Sekhar; Wang, Guangbo; Veerapandian, Savita K. P.; Morent, Rino; De Geyter, Nathalie; Leyssens, Karen; Hoffman, Alexander E. J.; Meynen, Vera; Marquez, Carlos; De Vos, Dirk E.; Van Speybroeck, Veronique; Leus, Karen; Van Der Voort, Pascal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering a Highly Defective Stable UiO-66 with Tunable Lewis-Bronsted Acidity: The Role of the Hemilabile Linker", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stability of metal-organic frameworks (MOFs) typically decreases with an increasing number of defects, limiting the number of defects that can be created and limiting catalytic and other applications. Herein, we use a hemilabile (Hl) linker to create up to a maximum of six defects per cluster in UiO-66. We synthesized hemilabile UiO-66 (Hl-UiO-66) using benzene dicarboxylate (BDC) as linker and 4-sulfonatobenzoate (PSBA) as the hemilabile linker. The PSBA acts not only as a modulator to create defects but also as a coligand that enhances the stability of the resulting defective framework. Furthermore, upon a postsynthetic treatment in H2SO4, the average number of defects increases to the optimum of six missing BDC linkers per cluster (three per formula unit), leaving the Zr-nodes on average sixfold coordinated. Remarkably, the thermal stability of the materials further increases upon this treatment. Periodic density functional theory calculations confirm that the hemilabile ligands strengthen this highly defective structure by several stabilizing interactions. Finally, the catalytic activity of the obtained materials is evaluated in the acid-catalyzed isomerization of a-pinene oxide. This reaction is particularly sensitive to the Bronsted or Lewis acid sites in the catalyst. In comparison to the pristine UiO-66, which mainly possesses Bronsted acid sites, the Hl-UiO-66 and the postsynthetically treated Hl-UiO-66 structures exhibited a higher Lewis acidity and an enhanced activity and selectivity. This is further explored by CD3CN spectroscopic sorption experiments. We have shown that by tuning the number of defects in UiO-66 using PSBA as the hemilabile linker, one can achieve highly defective and stable MOFs and easily control the Bronsted to Lewis acid ratio in the materials and thus their catalytic activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2020, "Volume": 142, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3174, "End Page": 3183, "Article Number": null, "DOI": "10.1021/jacs.9b13070", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13070", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514255300056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SF; Xu, HH; Li, WD; Dolocan, A; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shaofei; Xu, Henghui; Li, Wangda; Dolocan, Andrei; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Chemistry in Solid-State Batteries: Formation of Interphase and Its Consequences", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Benefiting from extremely high shear modulus and high ionic transference number, solid electrolytes are promising candidates to address both the dendrite-growth and electrolyte-consumption problems inherent to the widely adopted liquid-phase electrolyte batteries. However, solid electrolyte/electrode interfaces present high resistance and complicated morphology, hampering the development of solid-state battery systems, while requiring advanced analysis for rational improvement. Here, we employ an ultrasensitive three-dimensional (3D) chemical analysis to uncover the dynamic formation of interphases at the solid electrolyte/electrode interface. While the formation of interphases widens the electrochemical window, their electronic and ionic conductivities determine the electrochemical performance and have a large influence on dendrite growth. Our results suggest that, contrary to the general understanding, highly stable solid electrolytes with metal anodes in fact promote fast dendritic formation, as a result of less Li consumption and much larger curvature of dendrite tips that leads to an enhanced electric driving force. Detailed thermodynamic analysis shows an interphase with low electronic conductivity, high ionic conductivity, and chemical stability, yet having a dynamic thickness and uniform coverage is needed to prevent dendrite growth. This work provides a paradigm for interphase design to address the dendrite challenge, paving the way for the development of robust, fully operational solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2018, "Volume": 140, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 257, "Article Number": null, "DOI": "10.1021/jacs.7b09531", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b09531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422813300052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Ma, ZL; Qiu, H; Zhang, YL; Yu, Z; Gu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Ma, Zhonglei; Qiu, Hua; Zhang, Yali; Yu, Ze; Gu, Junwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Significantly Enhanced Electromagnetic Interference Shielding Performances of Epoxy nullocomposites with Long-Range Aligned Lamellar Structures", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-efficiency electromagnetic interference (EMI) shielding materials are of great importance for electronic equipment reliability, information security and human health. In this work, bidirectional aligned Ti3C2Tx@Fe3O4/CNF aerogels (BTFCA) were firstly assembled by bidirectional freezing and freeze-drying technique, and the BTFCA/epoxy nullocomposites with long-range aligned lamellar structures were then prepared by vacuum-assisted impregnation of epoxy resins. Benefitting from the successful construction of bidirectional aligned three-dimensional conductive networks and electromagnetic synergistic effect, when the mass fraction of Ti3C2Tx and Fe3O4 are 2.96 and 1.48 wt%, BTFCA/epoxy nullocomposites show outstanding EMI shielding effectiveness of 79 dB, about 10 times of that of blended Ti3C2Tx@Fe3O4/epoxy (8 dB) nullocomposites with the same loadings of Ti3C2Tx and Fe3O4. Meantime, the corresponding BTFCA/epoxy nullocomposites also present excellent thermal stability (Theat-resistance index of 198.7 degrees C) and mechanical properties (storage modulus of 9902.1 MPa, Young's modulus of 4.51 GPa and hardness of 0.34 GPa). Our fabricated BTFCA/epoxy nullocomposites would greatly expand the applications of MXene and epoxy resins in the fields of information security, aerospace and weapon manufacturing, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 224, "DOI": "10.1007/s40820-022-00949-8", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00949-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884895700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HX; Hu, GW; Wang, YZ; Wang, CH; Wang, MZ; Wang, SJ; Huang, YJ; Genevet, P; Huang, W; Qiu, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, He-Xiu; Hu, Guangwei; Wang, Yanzhao; Wang, Chaohui; Wang, Mingzhao; Wang, Shaojie; Huang, Yongjun; Genevet, Patrice; Huang, Wei; Qiu, Cheng-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polarization-insensitive 3D conformal-skin metasurface cloak", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic metasurface cloaks provide an alternative paradigm toward rendering arbitrarily shaped scatterers invisible. Most transformation-optics (TO) cloaks intrinsically need wavelength-scale volume/thickness, such that the incoming waves could have enough long paths to interact with structured meta-atoms in the cloak region and consequently restore the wavefront. Other challenges of TO cloaks include the polarization-dependent operation to avoid singular parameters of composite cloaking materials and limitations of canonical geometries, e.g., circular, elliptical, trapezoidal, and triangular shapes. Here, we report for the first time a conformal-skin metasurface carpet cloak, enabling to work under arbitrary states of polarization (SOP) at Poincare sphere for the incident light and arbitrary conformal platform of the object to be cloaked. By exploiting the foundry three-dimensional (3D) printing techniques to fabricate judiciously designed meta-atoms on the external surface of a conformal object, the spatial distributions of intensity and polarization of its scattered lights can be reconstructed exactly the same as if the scattering wavefront were deflected from a flat ground at any SOP, concealing targets under polarization-scanning detections. Two conformal-skin carpet cloaks working for partial- and full-azimuth plane operation are respectively fabricated on trapezoid and pyramid platforms via 3D printing. Experimental results are in good agreement with numerical simulations and both demonstrate the polarization-insensitive cloaking within a desirable bandwidth. Our approach paves a deterministic and robust step forward to the realization of interfacial, free-form, and full-polarization cloaking for a realistic arbitrary-shape target in real-world applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75, "DOI": "10.1038/s41377-021-00507-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00507-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000638192000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, KM; Jeong, JS; Pan, B; Zhang, XC; Xia, J; Cha, S; Park, TE; Kim, K; Finizio, S; Raabe, J; Chang, J; Zhou, Y; Zhao, WS; Kang, W; Ju, HS; Woo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Kyung Mee; Jeong, Jae-Seung; Pan, Biao; Zhang, Xichao; Xia, Jing; Cha, Sunkyung; Park, Tae-Eon; Kim, Kwangsu; Finizio, Simone; Raabe, Joerg; Chang, Joonyeon; Zhou, Yan; Zhao, Weisheng; Kang, Wang; Ju, Hyunsu; Woo, Seonghoon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skyrmion-based artificial synapses for neuromorphic computing", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are topologically protected spin textures that have nulloscale dimensions and can be manipulated by an electric current. These properties make the structures potential information carriers in data storage, processing and transmission devices. However, the development of functional all-electrical electronic devices based on skyrmions remains challenging. Here we show that the current-induced creation, motion, detection and deletion of skyrmions at room temperature can be used to mimic the potentiation and depression behaviours of biological synapses. In particular, the accumulation and dissipation of magnetic skyrmions in ferrimagnetic multilayers can be controlled with electrical pulses to represent the variations in the synaptic weights. Using chip-level simulations, we demonstrate that such artificial synapses based on magnetic skyrmions could be used for neuromorphic computing tasks such as pattern recognition. For a handwritten pattern dataset, our system achieves a recognition accuracy of similar to 89%, which is comparable to the accuracy achieved with software-based ideal training (similar to 93%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 148, "End Page": 155, "Article Number": null, "DOI": "10.1038/s41928-020-0385-0", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-0385-0", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519841100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JY; Zhu, P; Chen, FY; Wu, ZY; Cullen, DA; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jung Yoon 'Timothy'; Zhu, Peng; Chen, Feng-Yang; Wu, Zhen-Yu; Cullen, David A.; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The practical implementation of electrochemical CO2 reduction technology is greatly challenged by notable CO2 crossover to the anode side, where the crossed-over CO2 is mixed with O-2, via interfacial carbonate formation in traditional CO2 electrolysers. Here we report a porous solid electrolyte reactor strategy to efficiently recover these carbon losses. By creating a permeable and ion-conducting sulfonated polymer electrolyte between cathode and anode as a buffer layer, the crossover carbonate can combine with protons generated from the anode to re-form CO2 gas for reuse without mixing with anodic O-2. Using a silver nullowire catalyst for CO2 reduction to CO, we demonstrated up to 90% recovery of the crossover CO2 in an ultrahigh gas purity form (>99%), while delivering over 90% CO Faradaic efficiency under a 200 mA cm(-2) current. A high continuous CO(2 )conversion efficiency of over 90% was achieved by recycling the recovered CO2 to the CO2 input stream.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 288, "End Page": 299, "Article Number": null, "DOI": "10.1038/s41929-022-00763-w", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00763-w", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784396300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sadhanala, A; Deschler, F; Thomas, TH; Dutton, SE; Goedel, KC; Hanusch, FC; Lai, ML; Steiner, U; Bein, T; Docampo, P; Cahen, D; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sadhanala, Aditya; Deschler, Felix; Thomas, Tudor H.; Dutton, Sian E.; Goedel, Karl C.; Hanusch, Fabian C.; Lai, May L.; Steiner, Ullrich; Bein, Thomas; Docampo, Pablo; Cahen, David; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of Single-Phase Films of CH3NH3Pb(I1-x,Brx)3 with Sharp Optical Band Edges", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometallic lead-halide perovskite-based solar cells now approach 18% efficiency. Introducing a mixture of bromide and iodide in the halide composition allows tuning of the optical bandgap. We prepare mixed bromide-iodide lead perovskite films CH3NH3Pb(I1-xBrx)(3) (0 <= x <= 1) by spin-coating from solution and obtain films with monotonically varying bandgaps across the full composition range. Photothermal deflection spectroscopy, photoluminescence, and X-ray diffraction show that following suitable fabrication protocols these mixed lead-halide perovskite films form a single phase. The optical absorption edge of the pure triiodide and tribromide perovskites is sharp with Urbach energies of 15 and 23 meV, respectively, and reaches a maximum of 90 meV for CH3NH3PbI1.2Br1.8. We demonstrate a bromide-iodide lead perovskite film (CH3NH3PbI1.2Br1.8) with an optical bandgap of 1.94 eV, which is optimal for tandem cells of these materials with crystalline silicon devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2014, "Volume": 5, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2501, "End Page": 2505, "Article Number": null, "DOI": "10.1021/jz501332v", "DOI Link": "http://dx.doi.org/10.1021/jz501332v", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340222200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, YS; Chilton, NF; Winpenny, REP; Zheng, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, You-Song; Chilton, Nicholas F.; Winpenny, Richard E. P.; Zheng, Yan-Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a monometallic dysprosium complex, [Dy((OBu)-Bu-t)(2)(py)(5)][BPh4] (5), that shows the largest effective energy barrier to magnetic relaxation of U-eff=1815(1)K. The massive magnetic anisotropy is due to bis-trans-disposed tert-butoxide ligands with weak equatorial pyridine donors, approaching proposed schemes for high-temperature single-molecule magnets (SMMs). The blocking temperature, T-B, is 14K, defined by zero-field-cooled magnetization experiments, and is the largest for any monometallic complex and equal with the current record for [Tb2N2{N(SiMe3)(2)}(4)(THF)(2)].", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 789, "Times Cited, All Databases": 814, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2016, "Volume": 55, "Issue": 52, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16071, "End Page": 16074, "Article Number": null, "DOI": "10.1002/anie.201609685", "DOI Link": "http://dx.doi.org/10.1002/anie.201609685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392875700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yarali, E; Baniasadi, M; Zolfagharian, A; Chavoshi, M; Arefi, F; Hossain, M; Bastola, A; Ansari, M; Foyouzat, A; Dabbagh, A; Ebrahimi, M; Mirzaali, MJ; Bodaghi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yarali, Ebrahim; Baniasadi, Mahdi; Zolfagharian, Ali; Chavoshi, Maede; Arefi, Fatemeh; Hossain, Mokarram; Bastola, Anil; Ansari, Mahdi; Foyouzat, Alireza; Dabbagh, Ali; Ebrahimi, Mohamad; Mirzaali, Mohammad J.; Bodaghi, Mahdi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magneto-/electro-responsive polymers toward manufacturing, characterization, and biomedical/soft robotic applications", "Source Title": "APPLIED MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magneto-/ electro-responsive polymers (MERPs) are a class of stimuli-responsive materials that are actuated when triggered by external magnetic/ electric fields. MERPs exhibit rapid, reversible, and safe multifunctional and dynamic (i.e., changing with time) properties, which can effectively be manipulated at different length scales. These features make MERPs very attractive particularly in biomedical engineering (e.g., drug delivery systems and tissue engineering), soft matter engineering (e.g., soft robotics), and structural design of smart materials with unprecedented properties (e.g., complex shape morphing). Due to the recent progress in the design and development of MERPs, here, we highlighted the current advances in fabricating MERPs using various manufacturing methods including 3D/ 4D printing and conventional techniques. We also summarized the methods used for the characterization of MERPs and discussed their important structure-property relationship. We also highlighted the potential applications of MERPs in biomedical engineering, soft robotic, and the design of smart materials and systems. MERPs show great potentials for creating smart materials with predictable dynamic properties. More studies are necessary to investigate the biological responses of MERP both in-vivo and in-vitro , which is essential for biomedical engineering applications. (c) 2021 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101306, "DOI": "10.1016/j.apmt.2021.101306", "DOI Link": "http://dx.doi.org/10.1016/j.apmt.2021.101306", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778812000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZA; Mackanic, DG; Michaels, W; Lee, M; Pei, A; Feng, DW; Zhang, QH; Tsao, YC; Amanchukwu, CV; Yan, XZ; Wang, HS; Chen, SC; Liu, K; Kang, J; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhiao; Mackanic, David G.; Michaels, Wesley; Lee, Minah; Pei, Allen; Feng, Dawei; Zhang, Qiuhong; Tsao, Yuchi; Amanchukwu, Chibueze, V; Yan, Xuzhou; Wang, Hansen; Chen, Shucheng; Liu, Kai; Kang, Jiheong; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Dynamic, Electrolyte-Blocking, and Single-Ion-Conductive Network for Stable Lithium-Metal Anodes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Implementation of lithium (Li)-metal anodes requires developments to solve the heterogeneity and instability issues of naturally formed solid-electrolyte interphase (SEI). The artificial SEI, as an alternative, enables an ideal interface by regulating critical features such as fast ion transport, conformal protection, and parasitic reaction mitigation. Herein, for the first time, we integrate all of these desired properties into a single matrix, the dynamic single-ion-conductive network (DSN), as a multifunctional artificial SEI. The DSN incorporates the tetrahedral Al(OR)(4)(-) (R = soft fluorinated linker) centers as both dynamic bonding motifs and counter anions, endowing it with flowability and Li+ single-ion conductivity. Simultaneously, the fluorinated linkers provide chain mobility and electrolyte-blocking capability. A solution-processed DSN coating was found to simultaneously hinder electrolyte penetration, mitigate side reactions between Li and electrolyte, maintain low interfacial impedance, and allow homogenous Li deposition, With this coating, long cycle life and high Coulombic efficiency are achieved for Li-metal battery in a commercial carbonate electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2019, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2761, "End Page": 2776, "Article Number": null, "DOI": "10.1016/j.joule.2019.07.025", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.07.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497987900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, J; Li, JC; Zhang, K; Zhang, T; Li, CW; Ma, HX; Zhu, J; Braun, P; Lu, J; Zhang, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Jun; Li, Jiachen; Zhang, Kai; Zhang, Tao; Li, Chaowei; Ma, Haixia; Zhu, Jia; Braun, Paul, V; Lu, Jun; Zhang, Huigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal anodes hold great promise to enable high-energy battery systems. However, lithium dendrites at the interface between anode and separator pose risks of short circuits and fire, impeding the safe application. In contrast to conventional approaches of suppressing dendrites, here we show a deposition-regulating strategy by electrically passivating the top of a porous nickel scaffold and chemically activating the bottom of the scaffold to form conductivity/lithiophilicity gradients, whereby lithium is guided to deposit preferentially at the bottom of the anode, safely away from the separator. The resulting lithium anodes significantly reduce the probability of dendrite-induced short circuits. Crucially, excellent properties are also demonstrated at extremely high capacity (up to 40 mAh cm(-2)), high current density, and/or low temperatures (down to -15 degrees C), which readily induce dendrite shorts in particular. This facile and viable deposition-regulating strategy provides an approach to preferentially deposit lithium in safer positions, enabling a promising anode for next-generation lithium batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1896, "DOI": "10.1038/s41467-019-09932-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09932-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465202300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Jiang, P; Chen, L; Zhang, JF; Yuan, FP; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, X. L.; Jiang, P.; Chen, L.; Zhang, J. F.; Yuan, F. P.; Zhu, Y. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergetic Strengthening by Gradient Structure", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gradient structures are characterized with a systematic change in microstructures on a macroscopic scale. Here, we report that gradient structures in engineering materials such as metals produce an intrinsic synergetic strengthening, which is much higher than the sum of separate gradient layers. This is caused by macroscopic stress gradient and the bi-axial stress generated by mechanical incompatibility between different layers. This represents a new mechanism for strengthening that exploits the principles of both mechanics and materials science. It may provide for a novel strategy for designing material structures with superior properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 548, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 185, "End Page": 191, "Article Number": null, "DOI": "10.1080/21663831.2014.935821", "DOI Link": "http://dx.doi.org/10.1080/21663831.2014.935821", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000209768000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Filipic, M; Löper, P; Niesen, B; De Wolf, S; Krc, J; Ballif, C; Topic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filipic, Miha; Loeper, Philipp; Niesen, Bjoern; De Wolf, Stefaan; Krc, Janez; Ballif, Christophe; Topic, Marko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CH3NH3PbI3 perovskite/silicon tandem solar cells: characterization based optical simulations", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study we analyze and discuss the optical properties of various tandem architectures: mechanically stacked (four-terminal) and monolithically integrated (two-terminal) tandem devices, consisting of a methyl ammonium lead triiodide (CH3NH3PbI3) perovskite top solar cell and a crystalline silicon bottom solar cell. We provide layer thickness optimization guidelines and give estimates of the maximum tandem efficiencies based on state-of-the-art sub cells. We use experimental complex refractive index spectra for all involved materials as input data for an in-house developed optical simulator CROWM. Our characterization based simulations forecast that with optimized layer thicknesses the four-terminal configuration enables efficiencies over 30%, well above the current single-junction crystalline silicon cell record of 25.6%. Efficiencies over 30% can also be achieved with a two-terminal monolithic integration of the sub-cells, combined with proper selection of layer thicknesses. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2015, "Volume": 23, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A263", "End Page": "A278", "Article Number": null, "DOI": "10.1364/OE.23.00A263", "DOI Link": "http://dx.doi.org/10.1364/OE.23.00A263", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352290000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lien, DH; Uddin, SZ; Yeh, M; Amani, M; Kim, H; Ager, JW; Yablonovitch, E; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lien, Der-Hsien; Uddin, Shiekh Zia; Yeh, Matthew; Amani, Matin; Kim, Hyungjin; Ager, Joel W., III; Yablonovitch, Eli; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DEVICE TECHNOLOGY Electrical suppression of all nonradiative recombination pathways in monolayer semiconductors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects in conventional semiconductors substantially lower the photoluminescence (PL) quantum yield (QY), a key metric of optoelectronic performance that directly dictates the maximum device efficiency. Two-dimensional transition-metal dichalcogenides (TMDCs), such as monolayer MoS2, often exhibit low PL QY for as-processed samples, which has typically been attributed to a large native defect density. We show that the PL QY of as-processed MoS2 and WS2 monolayers reaches near-unity when they are made intrinsic through electrostatic doping, without any chemical passivation. Surprisingly, neutral exciton recombination is entirely radiative even in the presence of a high native defect density. This finding enables TMDC monolayers for optoelectronic device applications as the stringent requirement of low defect density is eased.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 364, "Issue": 6439, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 468, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw8053", "DOI Link": "http://dx.doi.org/10.1126/science.aaw8053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466809600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SS; Lin, H; Ma, CG; Cheng, Y; Ye, SZ; Lin, FL; Li, RF; Xu, J; Wang, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Shisheng; Lin, Hang; Ma, Chonggeng; Cheng, Yao; Ye, Sizhe; Lin, Fulin; Li, Renfu; Xu, Ju; Wang, Yuansheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-security-level multi-dimensional optical storage medium: nullostructured glass embedded with LiGa5O8: Mn2+ with photostimulated luminescence", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optics: Next generation of optical data storage systems An optical data storage (ODS) system that is cost-effective to make and easily scalable could lay the foundations for data storage technologies with higher capacity and improved security. The era of big data is driving the need for data storage systems with larger capacity, better security and improved performance. However, even the latest two-dimensional optical disk technologies cannot store more than one terabyte of data, leading scientists to explore alternative technologies. Now, a team of Chinese researchers, led by Yuansheng Wang from the Chinese Academy of Sciences, has developed a three-dimensional ODS system that uses light-emitting nullocrystals (NCs) to store and retrieve information. Made from a transparent glass ceramic embedded with photostimulated luminescent rare-earth-doped metallic NCs, the new ODS system can store 3D optical data with increased capacity and improved security compared with current technologies. The launch of the big data era puts forward challenges for information preservation technology, both in storage capacity and security. Herein, a brand new optical storage medium, transparent glass ceramic (TGC) embedded with photostimulated LiGa5O8: Mn2+ nullocrystals, capable of achieving bit-by-bit optical data write-in and read-out in a photon trapping/detrapping mode, is developed. The highly ordered nullostructure enables light-matter interaction with high encoding/decoding resolution and low bit error rate. Importantly, going beyond traditional 2D optical storage, the high transparency of the studied bulk medium makes 3D volumetric optical data storage (ODS) possible, which brings about the merits of expanded storage capacity and improved information security. Demonstration application confirmed the erasable-rewritable 3D storage of binary data and display items in TGC with intensity/wavelength multiplexing. The present work highlights a great leap in photostimulated material for ODS application and hopefully stimulates the development of new multi-dimensional ODS media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 22, "DOI": "10.1038/s41377-020-0258-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0258-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515025400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cortecchia, D; Neutzner, S; Kandada, ARS; Mosconi, E; Meggiolaro, D; De Angelis, F; Soci, C; Petrozza, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cortecchia, Daniele; Neutzner, Stefanie; Kandada, Ajay Ram Srimath; Mosconi, Edoardo; Meggiolaro, Daniele; De Angelis, Filippo; Soci, Cesare; Petrozza, Annamaria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Only a selected group of two-dimensional (2D) lead halide perovskites shows a peculiar broad-band photoluminescence. Here we show that the structural distortions of the perovskite lattice can determine the defectivity of the material by modulating the defect formation energies. By selecting and comparing two archetype systems, namely, (NBT)(2)PbI4 and (EDBE)PbI4 perovskites (NBT = n-butylammonium and EDBE = 2,2-(ethylenedioxy)bis(ethylammonium)), we find that only the latter, subject to larger deformation of the Pb-X bond length and X-Pb-X bond angles, sees the formation of V-F color centers whose radiative decay ultimately leads to broadened PL. These findings highlight the importance of structural engineering to control the optoelectronic properties of this class of soft materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2017, "Volume": 139, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 39, "End Page": 42, "Article Number": null, "DOI": "10.1021/jacs.6b10390", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b10390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392036900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZH; Li, XF; Zhou, H; Xu, Y; Xu, SM; Ren, Y; Yan, YF; Yang, JR; Ji, KY; Li, L; Xu, M; Shao, MF; Kong, XG; Sun, XM; Duan, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhenhua; Li, Xiaofan; Zhou, Hua; Xu, Yan; Xu, Si-Min; Ren, Yue; Yan, Yifan; Yang, Jiangrong; Ji, Kaiyue; Li, Li; Xu, Ming; Shao, Mingfei; Kong, Xianggui; Sun, Xiaoming; Duan, Haohong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrocatalytic synthesis of adipic acid coupled with H2 production enhanced by a ligand modification strategy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adipic acid is an important building block of polymers, although its production relies on harmful reagents. Here, authors examined surfactant-modified nickel hydroxide for adipic acid electrosynthesis coupled with hydrogen gas evolution. Adipic acid is an important building block of polymers, and is commercially produced by thermo-catalytic oxidation of ketone-alcohol oil (a mixture of cyclohexanol and cyclohexanone). However, this process heavily relies on the use of corrosive nitric acid while releases nitrous oxide as a potent greenhouse gas. Herein, we report an electrocatalytic strategy for the oxidation of cyclohexanone to adipic acid coupled with H-2 production over a nickel hydroxide (Ni(OH)(2)) catalyst modified with sodium dodecyl sulfonate (SDS). The intercalated SDS facilitates the enrichment of immiscible cyclohexanone in aqueous medium, thus achieving 3.6-fold greater productivity of adipic acid and higher faradaic efficiency (FE) compared with pure Ni(OH)(2) (93% versus 56%). This strategy is demonstrated effective for a variety of immiscible aldehydes and ketones in aqueous solution. Furthermore, we design a realistic two-electrode flow electrolyzer for electrooxidation of cyclohexanone coupling with H-2 production, attaining adipic acid productivity of 4.7 mmol coupled with H-2 productivity of 8.0 L at 0.8 A (corresponding to 30 mA cm(-2)) in 24 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5009, "DOI": "10.1038/s41467-022-32769-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32769-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000845603400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, HR; Jang, JY; Li, CH; Aigner, A; Plidschun, M; Kim, J; Rho, J; Schmidt, MA; Maier, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Haoran; Jang, Jaehyuck; Li, Chenhao; Aigner, Andreas; Plidschun, Malte; Kim, Jisoo; Rho, Junsuk; Schmidt, Markus A.; Maier, Stefan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An achromatic metafiber for focusing and imaging across the entire telecommunication range", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The authors fabricate a 3D achromatic diffractive metalens on the end face of a single-mode fiber, useful for endoscopic applications. They demonstrate achromatic and polarization insensitive focusing across the entire near-infrared telecommunication wavelength band ranging from 1.25 to 1.65 mu m. Dispersion engineering is essential to the performance of most modern optical systems including fiber-optic devices. Even though the chromatic dispersion of a meter-scale single-mode fiber used for endoscopic applications is negligible, optical lenses located on the fiber end face for optical focusing and imaging suffer from strong chromatic aberration. Here we present the design and nulloprinting of a 3D achromatic diffractive metalens on the end face of a single-mode fiber, capable of performing achromatic and polarization-insensitive focusing across the entire near-infrared telecommunication wavelength band ranging from 1.25 to 1.65 mu m. This represents the whole single-mode domain of commercially used fibers. The unlocked height degree of freedom in a 3D nullopillar meta-atom largely increases the upper bound of the time-bandwidth product of an achromatic metalens up to 21.34, leading to a wide group delay modulation range spanning from -8 to 14 fs. Furthermore, we demonstrate the use of our compact and flexible achromatic metafiber for fiber-optic confocal imaging, capable of creating in-focus sharp images under broadband light illumination. These results may unleash the full potential of fiber meta-optics for widespread applications including hyperspectral endoscopic imaging, femtosecond laser-assisted treatment, deep tissue imaging, wavelength-multiplexing fiber-optic communications, fiber sensing, and fiber lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4183, "DOI": "10.1038/s41467-022-31902-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31902-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827790500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bodnarchuk, MI; Boehme, SC; ten Brinck, S; Bernasconi, C; Shynkarenko, Y; Krieg, F; Widmer, R; Aeschlimann, B; Günther, D; Kovalenko, MV; Infante, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bodnarchuk, Maryna I.; Boehme, Simon C.; ten Brinck, Stephanie; Bernasconi, Caterina; Shynkarenko, Yevhen; Krieg, Franziska; Widmer, Roland; Aeschlimann, Beat; Guenther, Detlef; Kovalenko, Maksym V.; Infante, Ivan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationalizing and Controlling the Surface Structure and Electronic Passivation of Cesium Lead Halide nullocrystals", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal lead halide perovskite nullocrystals (NCs) have recently emerged as versatile photonic sources. Their processing and luminescent properties are challenged by the lability of their surfaces, i.e., the interface of the NC core and the ligand shell. On the example of CsPbBr3 NCs, we model the nullocrystal surface structure and its effect on the emergence of trap states using density functional theory. We rationalize the typical observation of a degraded luminescence upon aging or the luminescence recovery upon postsynthesis surface treatments. The conclusions are corroborated by the elemental analysis. We then propose a strategy for healing the surface trap states and for improving the colloidal stability by the combined treatment with didodecyldimethylammonium bromide and lead bromide and validate this approach experimentally. This simple procedure results in robust colloids, which are highly pure and exhibit high photoluminescence quantum yields of up to 95-98%, retained even after three to four rounds of washing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": 74, "Article Number": null, "DOI": "10.1021/acsenergylett.8b01669", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b01669", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456493100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, S; Li, Y; Tang, YJ; Sun, YY; Li, WT; Guo, XT; Yang, FY; Zhang, GX; Zhou, HJ; Liu, Z; Li, Q; Shakouri, M; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Shuai; Li, Yong; Tang, Yijian; Sun, Yangyang; Li, Wenting; Guo, Xiaotian; Yang, Feiyu; Zhang, Guangxun; Zhou, Huijie; Liu, Zheng; Li, Qing; Shakouri, Mohsen; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Space-Confined Metal Ion Strategy for Carbon Materials Derived from Cobalt Benzimidazole Frameworks with High Desalination Performance in Simulated Seawater", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various metal ions with different valence states (Mg2+, Al3+, Ca2+, Ti4+, Mn2+, Fe3+, Ni2+, Zn2+, Pb2+, Ba2+, Ce4+) are successfully confined in quasi-microcube shaped cobalt benzimidazole frameworks using a space-confined synthesis strategy. More importantly, a series of derived carbon materials that confine metal ions are obtained by high-temperature pyrolysis. Interestingly, the derived carbon materials exhibited electric double-layer and pseudocapacitance properties because of the presence of metal ions with various valence states. Moreover, the presence of additional metal ions within carbon materials may create new phases, which can accelerate Na+ insertion/extraction and thus increase electrochemical adsorption. Density functional theory results showed that carbon materials in which Ti ions are confined exhibit enhanced insertion/extraction of Na+ resulting from the presence of the characteristic anatase crystalline phases of TiO2. The Ti-containing materials have an impressive desalination capacity (62.8 mg g(-1)) in capacitive deionization (CDI) applications with high cycling stability. This work provides a facile synthetic strategy for the confinement of metal ions in metal-organic frameworks and thus supports the further development of derived carbon materials for seawater desalination by CDI.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202301011", "DOI Link": "http://dx.doi.org/10.1002/adma.202301011", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000974514600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Enright, R; Miljkovic, N; Alvarado, JL; Kim, K; Rose, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Enright, Ryan; Miljkovic, Nenad; Alvarado, Jorge L.; Kim, Kwang; Rose, John W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DROPWISE CONDENSATION ON MICRO- AND nullOSTRUCTURED SURFACES", "Source Title": "nullOSCALE AND MICROSCALE THERMOPHYSICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this review we cover recent developments in the area of surface-enhanced dropwise condensation against the background of earlier work. The development of fabrication techniques to create surface structures at the micro-and nulloscale using both bottom-up and top-down approaches has led to increased study of complex interfacial phenomena. In the heat transfer community, researchers have been extensively exploring the use of advanced surface structuring techniques to enhance phase-change heat transfer processes. In particular, the field of vapor-to-liquid condensation and especially that of water condensation has experienced a renaissance due to the promise of further optimizing this process at the micro-and nulloscale by exploiting advances in surface engineering developed over the last several decades.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 18, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 223, "End Page": 250, "Article Number": null, "DOI": "10.1080/15567265.2013.862889", "DOI Link": "http://dx.doi.org/10.1080/15567265.2013.862889", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Engineering; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340471000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Greczynski, G; Hultman, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Greczynski, Grzegorz; Hultman, Lars", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A step-by-step guide to perform x-ray photoelectron spectroscopy", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is a growing concern within the surface science community that the massive increase in the number of XPS articles over the last few decades is accompanied by a decrease in work quality including in many cases meaningless chemical bond assignment. Should this trend continue, it would have disastrous consequences for scientific research. While there are many factors responsible for this situation, the lack of insight of physical principles combined with seeming ease of XPS operation and insufficient training are certainly the major ones. To counter that, we offer a comprehensive tutorial written in the form of a step-by-step guide starting from experimental planning, through sample selection and handling, instrument setup, data acquisition, spectra analysis, and results presentation. Six application examples highlight the broad range of research questions that can be answered by XPS. The topic selection and the discussion level are intended to be accessible for novices yet challenging possible preconceptions of experienced practitioners. The analyses of thin film samples are chosen for model cases as this is from where the bulk of XPS reports presently emanate and also where the author's key expertise lies. At the same time, the majority of discussed topics is applicable to surface science in general and is, thus, of relevance for the analyses of any type of sample and material class. The tutorial contains ca. 160 original spectra and over 290 references for further reading. Particular attention is paid to the correct workflow, development of good research practices, and solid knowledge of factors that impact the quality and reliability of the obtained information. What matters in the end is that the conclusions from the analysis can be trusted. Our aspiration is that after reading this tutorial each practitioner will be able to perform error-free data analysis and draw meaningful insights from the rich well of XPS. Published under an exclusive license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2022, "Volume": 132, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11101, "DOI": "10.1063/5.0086359", "DOI Link": "http://dx.doi.org/10.1063/5.0086359", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000886015200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, R; Li, C; Cui, HL; Wang, YB; Zhang, SC; Li, P; Hou, Y; Guo, Y; Liang, GJ; Huang, ZD; Peng, C; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Rong; Li, Chuan; Cui, Huilin; Wang, Yanbo; Zhang, Shaoce; Li, Pei; Hou, Yue; Guo, Ying; Liang, Guojin; Huang, Zhaodong; Peng, Chao; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical nitrate reduction in acid enables high-efficiency ammonia synthesis and high-voltage pollutes-based fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most current research is devoted to electrochemical nitrate reduction reaction for ammonia synthesis under alkaline/neutralmedia while the investigation of nitrate reduction under acidic conditions is rarely reported. In this work, we demonstrate the potential of TiO2 nullosheet with intrinsically poor hydrogen-evolution activity for selective and rapid nitrate reduction to ammonia under acidic conditions. Hybridized with iron phthalocyanine, the resulting catalyst displays remarkably improved efficiency toward ammonia formation owing to the enhanced nitrate adsorption, suppressed hydrogen evolution and lowered energy barrier for the rate-determining step. Then, an alkaline-acid hybrid Zn-nitrate battery was developed with high open-circuit voltage of 1.99 V and power density of 91.4 mW cm(-2). Further, the environmental sulfur recovery can be powered by above hybrid battery and the hydrazine-nitrate fuel cell can be developed for simultaneously hydrazine/nitrate conversion and electricity generation. This work demonstrates the attractive potential of acidic nitrate reduction for ammonia electrosynthesis and broadens the field of energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8036, "DOI": "10.1038/s41467-023-43897-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43897-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001141884600046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, ZW; Meng, X; Lai, H; Zhang, DF; Pu, XP; Su, CH; Li, H; Ren, XZ; Geng, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Zhuwang; Meng, Xiao; Lai, Hong; Zhang, Dafeng; Pu, Xipeng; Su, Changhua; Li, Hong; Ren, Xiaozhen; Geng, Yanling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coralline-like Ni2P decorated novel tetrapod-bundle Cd0.9Zn0.1S ZB/WZ homojunctions for highly efficient visible-light photocatalytic hydrogen evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, Ni2P-Cd0.9Zn0.1S (NPCZS) composites were synthesized by coupling tetrapod bundle Cd0.9Zn0.1S (CZS) and coralline-like Ni2P (NP) via a simple calcination method. CZS shows outstanding activity in photocatalytic hydrogen evolution (1.31 mmol h(-1)), owing to its unique morphology and heterophase homojunctions (ZB/WZ), which accelerate the separation and transfer of photogenerated charges. After coupling with NP, the photoactivity of NPCZS was enhanced, and the maximum hydrogen evolution rate of 1.88 mmol h(-1) was reached at a NP content of 12 wt%, which was 1.43 times higher than that of pure CZS. The experimental results of the photocatalytic activity, viz. photoluminescence spectra, surface photovoltage spectra, and electrochemical test showed that the enhanced photoactivity of NPCZS should be attributed to the synergistic effects of the novel tetrapod-bundle morphology, heterophase homojunctions, and decoration of the NP co-catalyst. Moreover, the as-prepared NPCZS composites exhibited excellent photostability and recyclability. Herein, we propose a possible mechanism for the enhanced photocatalytic activity. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 42, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 439, "End Page": 449, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63597-5", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63597-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582726000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faria, M; Björnmalm, M; Thurecht, KJ; Kent, SJ; Parton, RG; Kavallaris, M; Johnston, APR; Gooding, JJ; Corrie, SR; Boyd, BJ; Thordarson, P; Whittaker, AK; Stevens, MM; Prestidge, CA; Porter, CJH; Parak, WJ; Davis, TP; Crampin, EJ; Caruso, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faria, Matthew; Bjornmalm, Mattias; Thurecht, Kristofer J.; Kent, Stephen J.; Parton, Robert G.; Kavallaris, Maria; Johnston, Angus P. R.; Gooding, J. Justin; Corrie, Simon R.; Boyd, Ben J.; Thordarson, Pall; Whittaker, Andrew K.; Stevens, Molly M.; Prestidge, Clive A.; Porter, Christopher J. H.; Parak, Wolfgang J.; Davis, Thomas P.; Crampin, Edmund J.; Caruso, Frank", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimum information reporting in bio-nullo experimental literature", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Studying the interactions between nulloengineered materials and biological systems plays a vital role in the development of biological applications of nullotechnology and the improvement of our fundamental understanding of the bio-nullo interface. A significant barrier to progress in this multidisciplinary area is the variability of published literature with regards to characterizations performed and experimental details reported. Here, we suggest a 'minimum information standard' for experimental literature investigating bio-nullo interactions. This standard consists of specific components to be reported, divided into three categories: material characterization, biological characterization and details of experimental protocols. Our intention is for these proposed standards to improve reproducibility, increase quantitative comparisons of bio-nullo materials, and facilitate meta analyses and in silico modelling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 478, "Times Cited, All Databases": 499, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 777, "End Page": 785, "Article Number": null, "DOI": "10.1038/s41565-018-0246-4", "DOI Link": "http://dx.doi.org/10.1038/s41565-018-0246-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443851800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ng, HK; Xiang, D; Suwardi, A; Hu, GW; Yang, K; Zhao, YS; Liu, T; Cao, ZH; Liu, HJ; Li, SS; Cao, J; Zhu, Q; Dong, ZG; Tan, CKI; Chi, DZ; Qiu, CW; Hippalgaonkar, K; Eda, G; Yang, M; Wu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ng, Hong Kuan; Xiang, Du; Suwardi, Ady; Hu, Guangwei; Yang, Ke; Zhao, Yunshan; Liu, Tao; Cao, Zhonghan; Liu, Huajun; Li, Shisheng; Cao, Jing; Zhu, Qiang; Dong, Zhaogang; Tan, Chee Kiang Ivan; Chi, Dongzhi; Qiu, Cheng-Wei; Hippalgaonkar, Kedar; Eda, Goki; Yang, Ming; Wu, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving carrier mobility in two-dimensional semiconductors with rippled materials", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice distortions induced by ripples in two-dimensional molybdenum disulfide can reduce electron-phonon scattering, leading to improved charge carrier mobility and enhanced transistor performance. Two-dimensional (2D) semiconductors could potentially replace silicon in future electronic devices. However, the low carrier mobility in 2D semiconductors at room temperature, caused by strong phonon scattering, remains a critical challenge. Here we show that lattice distortions can reduce electron-phonon scattering in 2D materials and thus improve the charge carrier mobility. We introduce lattice distortions into 2D molybdenum disulfide (MoS2) using bulged substrates, which create ripples in the 2D material leading to a change in the dielectric constant and a suppressed phonon scattering. A two orders of magnitude enhancement in room-temperature mobility is observed in rippled MoS2, reaching similar to 900 cm(2) V-1 s(-1), which exceeds the predicted phonon-limited mobility of flat MoS2 of 200-410 cm(2) V-1 s(-1). We show that our approach can be used to create high-performance room-temperature field-effect transistors and thermoelectric devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 489, "End Page": 496, "Article Number": null, "DOI": "10.1038/s41928-022-00777-z", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00777-z", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808423800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, PZ; Zhang, N; Wang, SB; Zhou, TP; Tong, Y; Ao, CC; Yan, WS; Zhang, LD; Chu, WS; Wu, CZ; Xie, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Pengzuo; Zhang, null; Wang, Sibo; Zhou, Tianpei; Tong, Yun; Ao, Chengcheng; Yan, Wensheng; Zhang, Lidong; Chu, Wangsheng; Wu, Changzheng; Xie, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial engineering of cobalt sulfide/graphene hybrids for highly efficient ammonia electrosynthesis", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic N-2 reduction reaction (NRR) into ammonia (NH3), especially if driven by renewable energy, represents a potentially clean and sustainable strategy for replacing traditional Haber-Bosch process and dealing with climate change effect. However, electrocatalytic NRR process under ambient conditions often suffers from low Faradaic efficiency and high overpotential. Developing newly regulative methods for highly efficient NRR electrocatalysts is of great significance for NH3 synthesis. Here, we propose an interfacial engineering strategy for designing a class of strongly coupled hybrid materials as highly active electrocatalysts for catalytic N-2 fixation. X-ray absorption near-edge spectroscopy (XANES) spectra confirm the successful construction of strong bridging bonds (Co-N/S-C) at the interface between CoSx nulloparticles and NS-G (nitrogen- and sulfur-doped reduced graphene). These bridging bonds can accelerate the reaction kinetics by acting as an electron transport channel, enabling electrocatalytic NRR at a low overpotential. As expected, CoS2/NS-G hybrids show superior NRR activity with a high NH3 Faradaic efficiency of 25.9% at -0.05 V versus reversible hydrogen electrode (RHE). Moreover, this strategy is general and can be extended to a series of other strongly coupled metal sulfide hybrids. This work provides an approach to design advanced materials for ammonia production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 116, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6635, "End Page": 6640, "Article Number": null, "DOI": "10.1073/pnas.1817881116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1817881116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463069900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumaravel, V; Nair, KM; Mathew, S; Bartlett, J; Kennedy, JE; Manning, HG; Whelan, BJ; Leyland, NS; Pillai, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumaravel, Vignesh; Nair, Keerthi M.; Mathew, Snehamol; Bartlett, John; Kennedy, James E.; Manning, Hugh G.; Whelan, Barry J.; Leyland, Nigel S.; Pillai, Suresh C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antimicrobial TiO2 nullocomposite coatings for surfaces, dental and orthopaedic implants", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering of self-disinfecting surfaces to constrain the spread of SARS-CoV-2 is a challenging task for the scientific community because the human coronavirus spreads through respiratory droplets. Titania (TiO2) nullocomposite antimicrobial coatings is one of the ideal remedies to disinfect pathogens (virus, bacteria, fungi) from common surfaces under light illumination. The photocatalytic disinfection efficiency of recent TiO2 nullocomposite antimicrobial coatings for surfaces, dental and orthopaedic implants are emphasized in this review. Mostly, inorganic metals (e.g. copper (Cu), silver (Ag), manganese (Mn), etc), non-metals (e.g. fluorine (F), calcium (Ca), phosphorus (P)) and two-dimensional materials (e.g. MXenes, MOF, graphdiyne) were incorporated with TiO2 to regulate the charge transfer mechanism, surface porosity, crystallinity, and the microbial disinfection efficiency. The antimicrobial activity of TiO2 coatings was evaluated against the most crucial pathogenic microbes such as Escherichia coli, methicillin-resistant Staphylococcus aureus, Pseudomonas aeruginosa, Bacillus subtilis, Legionella pneumophila, Staphylococcus aureus, Streptococcus mutans, T2 bacteriophage, H1N1, HCoVNL63, vesicular stomatitis virus, bovine coronavirus. Silane functionalizing agents and polymers were used to coat the titanium (Ti) metal implants to introduce superhydrophobic features to avoid microbial adhesion. TiO2 nullocomposite coatings in dental and orthopaedic metal implants disclosed exceptional bio-corrosion resistance, durability, biocompatibility, bone-formation capability, and long-term antimicrobial efficiency. Moreover, the commercial trend, techno-economics, challenges, and prospects of antimicrobial nullocomposite coatings are also discussed briefly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2021, "Volume": 416, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 129071, "DOI": "10.1016/j.cej.2021.129071", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.129071", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649666100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wheeler, LM; Sanehira, EM; Marshall, AR; Schulz, P; Suri, M; Anderson, NC; Christians, JA; Nordlund, D; Sokaras, D; Kroll, T; Harvey, SP; Berry, JJ; Lin, LY; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wheeler, Lance M.; Sanehira, Erin M.; Marshall, Ashley R.; Schulz, Philip; Suri, Mokshin; Anderson, Nicholas C.; Christians, Jeffrey A.; Nordlund, Dennis; Sokaras, Dimosthenis; Kroll, Thomas; Harvey, Steven P.; Berry, Joseph J.; Lin, Lih Y.; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Targeted Ligand-Exchange Chemistry on Cesium Lead Halide Perovskite Quantum Dots for High-Efficiency Photovoltaics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to manipulate quantum dot (QD) surfaces is foundational to their technological deployment. Surface manipulation of metal halide perovskite (MHP) QDs has proven particularly challenging in comparison to that of more established inorganic materials due to dynamic surface species and low material formation energy; most conventional methods of chemical manipulation targeted at the MHP QD surface will result in transformation or dissolution of the MHP crystal. In previous work, we have demonstrated record-efficiency QD solar cells (QDSCs) based on ligand-exchange procedures that electronically couple MHP QDs yet maintain their nullocrystalline size, which stabilizes the corner-sharing structure of the constituent PbI64- octahedra with optoelectronic properties optimal for solar energy conversion. In this work, we employ a variety of spectroscopic techniques to develop a molecular-level understanding of the MHP QD surface chemistry in this system. We individually target both the anionic (oleate) and cationic (oleylammonium) ligands. We find that atmospheric moisture aids the process by hydrolysis of methyl acetate to generate acetic acid and methanol. Acetic acid then replaces native oleate ligands to yield QD surface-bound acetate and free oleic acid. The native oleylammonium ligands remain throughout this film deposition process and are exchanged during a final treatment step employing smaller cations-namely, formamidinium. This final treatment has a narrow processing window; initial treatment at this stage leads to a more strongly coupled QD regime followed by transformation into a bulk MHP film after longer treatment. These insights provide chemical understanding to the deposition of high-quality, electronically coupled MHP QD films that maintain both quantum confinement and their crystalline phase and attain high photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2018, "Volume": 140, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10504, "End Page": 10513, "Article Number": null, "DOI": "10.1021/jacs.8b04984", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b04984", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442706400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zachäus, C; Abdi, FF; Peter, LM; van de Krol, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zachaeus, Carolin; Abdi, Fatwa F.; Peter, Laurence M.; van de Krol, Roel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocurrent of BiVO4 is limited by surface recombination, not surface catalysis", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bismuth vanadate is one of the most promising photoanode materials for photoelectrochemical water splitting. In order to achieve high photocurrents the surface of BiVO4 always has to be modified with water oxidation catalysts, such as cobalt phosphate (CoPi), FeOOH, or NiFeOx. While this has generally been attributed to the poor intrinsic catalytic activity of BiVO4, detailed insight into the fate of the photogenerated charge carriers at the surface is still lacking. We used intensity modulated photocurrent spectroscopy (IMPS) to investigate the surface carrier dynamics of bare and CoPi-modified spray-deposited BiVO4 films. Using a model developed by Peter et al., it was possible to distinguish the reaction rate constants for surface recombination and charge transfer to the electrolyte. We found that modification with CoPi reduced the surface recombination of BiVO4 with a factor of 10-20, without significantly influencing the charge transfer kinetics. Control experiments with RuOx, one of the best known OER electrocatalysts, did not affect surface recombination and led to an actual decrease of the photocurrent. These results show that the main role of the CoPi is to passivate the surface of BiVO4 and that, contrary to earlier assumptions, the photocurrent of BiVO4 is limited by surface recombination instead of charge transfer. The importance of surface recombination is well recognized for conventional semiconductors in the field of photovoltaics; these findings show that it may also play a crucial role in oxide-based semiconductors for photoelectrochemical energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3712, "End Page": 3719, "Article Number": null, "DOI": "10.1039/c7sc00363c", "DOI Link": "http://dx.doi.org/10.1039/c7sc00363c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400553000049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamali, SM; Arbabi, E; Arbabi, A; Horie, Y; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamali, Seyedeh Mahsa; Arbabi, Ehsan; Arbabi, Amir; Horie, Yu; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly tunable elastic dielectric metasurface lenses", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric metasurfaces are two-dimensional structures composed of nullo-scatterers that manipulate the phase and polarization of optical waves with subwavelength spatial resolution, thus enabling ultra-thin components for free-space optics. While high performance devices with various functionalities, including some that are difficult to achieve using conventional optical setups have been shown, most demonstrated components have fixed parameters. Here, we demonstrate highly tunable dielectric metasurface devices based on subwavelength thick silicon nullo-posts encapsulated in a thin transparent elastic polymer. As proof of concept, we demonstrate a metasurface microlens operating at 915 nm, with focal distance tuning from 600 mu m to 1400 mu m (over 952 diopters change in optical power) through radial strain, while maintaining a diffraction limited focus and a focusing efficiency above 50%. The demonstrated tunable metasurface concept is highly versatile for developing ultra-slim, multi-functional and tunable optical devices with widespread applications ranging from consumer electronics to medical devices and optical communications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1002, "End Page": 1008, "Article Number": null, "DOI": "10.1002/lpor.201600144", "DOI Link": "http://dx.doi.org/10.1002/lpor.201600144", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393051500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CH; Xu, Z; Han, NA; Tian, Y; Kallio, T; Yu, CM; Jiang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chunhui; Xu, Zhe; Han, nulla; Tian, Ye; Kallio, Tanja; Yu, Cunming; Jiang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superaerophilic/superaerophobic cooperative electrode for efficient hydrogen evolution reaction via enhanced mass transfer", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction (HER), as an effective method to produce green hydrogen, is greatly impeded by inefficient mass transfer, i.e., bubble adhesion on electrode, bubble dispersion in the vicinity of electrode, and poor dissolved H2 diffusion, which results in blocked electrocatalytic area and large H2 concentration overpo-tential. Here, we report a superaerophilic/superaerophobic (SAL/SAB) cooperative electrode to efficiently promote bubble transfer by asymmetric Laplace pressure and accelerate dissolved H2 diffusion through reduc-ing diffusion distance. Benefiting from the enhanced mass transfer, the overpotential for the SAL/SAB cooper-ative electrode at -10 mA cm-2 is only -19 mV, compared to -61 mV on the flat Pt electrode. By optimizing H2SO4 concentration, the SAL/SAB cooperative electrode can achieve ultrahigh current density (-1867 mA cm-2) at an overpotential of -500 mV. We can envision that the SAL/SAB cooperative strategy is an effective method to improve HER efficiency and stimulate the understanding of various gas-involved processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2023, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/sciadv.add6978", "DOI Link": "http://dx.doi.org/10.1126/sciadv.add6978", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964550100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, SN; Liu, QR; Kidkhunthod, P; Zhou, XL; Wang, WL; Tang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Sainull; Liu, Qirong; Kidkhunthod, Pinit; Zhou, Xiaolong; Wang, Wenlou; Tang, Yongbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular grafting towards high-fraction active nullodots implanted in N-doped carbon for sodium dual-ion batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-based dual-ion batteries (Na-DIBs) show a promising potential for large-scale energy storage applications due to the merits of environmental friendliness and low cost. However, Na-DIBs are generally subject to poor rate capability and cycling stability for the lack of suitable anodes to accommodate large Na+ ions. Herein, we propose a molecular grafting strategy to in situ synthesize tin pyrophosphate nullodots implanted in N-doped carbon matrix (SnP2O7@N-C), which exhibits a high fraction of active SnP2O7 up to 95.6 wt% and a low content of N-doped carbon (4.4 wt%) as the conductive framework. As a result, this anode delivers a high specific capacity similar to 400 mAh g(-1) at 0.1Ag(-1), excellent rate capability up to 5.0Ag(-1) and excellent cycling stability with a capacity retention of 92% after 1200 cycles under a current density of 1.5Ag(-1). Further, pairing this anode with an environmentally friendly KS6 graphite cathode yields a SnP2O7@N-C||KS6 Na-DIB, exhibiting an excellent rate capability up to 30 C, good fast-charge/slow-discharge performance and long-term cycling life with a capacity retention of similar to 96% after 1000 cycles at 20 C. This study provides a feasible strategy to develop high-performance anodes with high-fraction active materials for Na-based energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwaa178", "DOI": "10.1093/nsr/nwaa178", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa178", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000697170300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, JX; Li, Y; Wang, L; Liao, WG; Dong, BW; Xu, C; Zhu, CX; Ang, KW; Qiu, CW; Lee, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Jingxuan; Li, Ying; Wang, Lin; Liao, Wugang; Dong, Bowei; Xu, Cheng; Zhu, Chunxiang; Ang, Kah-Wee; Qiu, Cheng-Wei; Lee, Chengkuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zero-bias mid-infrared graphene photodetectors with bulk photoresponse and calibration-free polarization detection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bulk photovoltaic effect (BPVE), featuring polarization-dependent uniform photoresponse at zero external bias, holds potential for exceeding the Shockley-Queisser limit in the efficiency of existing opto-electronic devices. However, the implementation of BPVE has been limited to the naturally existing materials with broken inversion symmetry, such as ferroelectrics, which suffer low efficiencies. Here, we propose metasurface-mediated graphene photodetectors with cascaded polarization-sensitive photoresponse under uniform illumination, mimicking an artificial BPVE. With the assistance of non-centrosymmetric metallic nulloantennas, the hot photocarriers in graphene gain a momentum upon their excitation and form a shift current which is nonlocal and directional. Thereafter, we demonstrate zero-bias uncooled mid-infrared photodetectors with three orders higher responsivity than conventional BPVE and a noise equivalent power of 0.12nWHz(-1/2). Besides, we observe a vectorial photoresponse which allows us to detect the polarization angle of incident light with a single device. Our strategy opens up alternative possibilities for scalable, low-cost, multifunctional infrared photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6404, "DOI": "10.1038/s41467-020-20115-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20115-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600191300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YH; Tan, SQ; Li, NX; Huang, BL; Niu, XX; Li, L; Sun, MZ; Zhang, Y; Zhang, X; Zhu, C; Yang, N; Zai, HC; Wu, YL; Ma, S; Bai, Y; Chen, Q; Xiao, F; Sun, KW; Zhou, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yihua; Tan, Shunquan; Li, Nengxu; Huang, Bolong; Niu, Xiuxiu; Li, Liang; Sun, Mingzi; Zhang, Yu; Zhang, Xiao; Zhu, Cheng; Yang, Ning; Zai, Huachao; Wu, Yiliang; Ma, Sai; Bai, Yang; Chen, Qi; Xiao, Fei; Sun, Kangwen; Zhou, Huanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Elimination of Intrinsic Defects Improves the Low-Temperature Performance of Perovskite Photovoltaics", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid halide perovskite solar cells have found potential applications beyond terrestrial implementation due to their unique advantages in cold environments. Unfortunately, the pioneer exploits are limited in inferior device efficiency, while the operating mechanisms at low temperatures remain unclear. Here, we revealed substantial performance enhancement for (FA,MA,Cs)Pb(I,Br)(3)-based perovskite solar cells at temperatures from 290 to 180 K. Remarkably, the device obtained the highest efficiency of 25.2% (stabilized 24.2%) at 220 K, boosted from a certified efficiency of 23.3% (stabilized 22.8%) at 300 K. We proposed that the phase transition and lattice distortion in perovskite films during temperature cycling effectively activates the self-elimination of intrinsic defects, which contributes to the improved open-circuit voltage (1.153 to 1.229 V) and, thus, efficiency. In addition, the device without encapsulation was tested in the simulated near-space environment, demonstrating their operational feasibility and stability for practical low-temperature applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2020, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1961, "End Page": 1976, "Article Number": null, "DOI": "10.1016/j.joule.2020.07.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.07.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571389400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baek, J; Hossain, MD; Mukherjee, P; Lee, JH; Winther, KT; Leem, J; Jiang, Y; Chueh, WC; Bajdich, M; Zheng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baek, Jihyun; Hossain, Md Delowar; Mukherjee, Pinaki; Lee, Junghwa; Winther, Kirsten T.; Leem, Juyoung; Jiang, Yue; Chueh, William C.; Bajdich, Michal; Zheng, Xiaolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic effects of mixing and strain in high entropy spinel oxides for oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing stable and efficient electrocatalysts is vital for boosting oxygen evolution reaction (OER) rates in sustainable hydrogen production. High-entropy oxides (HEOs) consist of five or more metal cations, providing opportunities to tune their catalytic properties toward high OER efficiency. This work combines theoretical and experimental studies to scrutinize the OER activity and stability for spinel-type HEOs. Density functional theory confirms that randomly mixed metal sites show thermodynamic stability, with intermediate adsorption energies displaying wider distributions due to mixing-induced equatorial strain in active metal-oxygen bonds. The rapid sol-flame method is employed to synthesize HEO, comprising five 3d-transition metal cations, which exhibits superior OER activity and durability under alkaline conditions, outperforming lower-entropy oxides, even with partial surface oxidations. The study highlights that the enhanced activity of HEO is primarily attributed to the mixing of multiple elements, leading to strain effects near the active site, as well as surface composition and coverage. Efficient and durable electrocatalysts are essential for boosting oxygen evolution reaction toward hydrogen production. Here, the authors report a combined theoretical and experimental study on high-entropy spinel oxide with element mixing and strains providing superior activity and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5936, "DOI": "10.1038/s41467-023-41359-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41359-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001074590000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZQ; Dong, LB; Huang, WY; Jia, H; Zhao, QH; Wang, YD; Fei, B; Pan, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ziqi; Dong, Liubing; Huang, Weiyuan; Jia, Hao; Zhao, Qinghe; Wang, Yidi; Fei, Bin; Pan, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneously Regulating Uniform Zn2+ Flux and Electron Conduction by MOF/rGO Interlayers for High-Performance Zn Anodes", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the merits of low cost, high safety and environmental benignity, rechargeable aqueous Zn-based batteries (ZBs) have gained tremendous attention in recent years. Nevertheless, the poor reversibility of Zn anodes that originates from dendrite growth, surface passivation and corrosion, severely hinders the further development of ZBs. To tackle these issues, here we report a Janus separator based on a Zn-ion conductive metal-organic framework (MOF) and reduced graphene oxide (rGO), which is able to regulate uniform Zn2+ flux and electron conduction simultaneously during battery operation. Facilitated by the MOF/rGO bifunctional interlayers, the Zn anodes demonstrate stable plating/stripping behavior (over 500 h at 1 mA cm(-2)), high Coulombic efficiency (99.2% at 2 mA cm(-2) after 100 cycles) and reduced redox barrier. Moreover, it is also found that the Zn corrosion can be effectively retarded through diminishing the potential discrepancy on Zn surface. Such a separator engineering also saliently promotes the overall performance of Zn|MnO2 full cells, which deliver nearly 100% capacity retention after 2000 cycles at 4 A g(-1) and high power density over 10 kW kg(-1). This work provides a feasible route to the high-performance Zn anodes for ZBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 73, "DOI": "10.1007/s40820-021-00594-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00594-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618350000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Himanen, L; Jäger, MOJ; Morooka, EV; Canova, FF; Ranawat, YS; Gao, DZ; Rinke, P; Foster, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Himanen, Lauri; Jager, Marc O. J.; Morooka, Eiaki, V; Canova, Filippo Federici; Ranawat, Yashasvi S.; Gao, David Z.; Rinke, Patrick; Foster, Adam S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DScribe: Library of descriptors for machine learning in materials science", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "DScribe is a software package for machine learning that provides popular feature transformations (descriptors) for atomistic materials simulations. DScribe accelerates the application of machine learning for atomistic property prediction by providing user-friendly, off-the-shelf descriptor implementations. The package currently contains implementations for Coulomb matrix, Ewald sum matrix, sine matrix, Many-body Tensor Representation (MBTR), Atom-centered Symmetry Function (ACSF) and Smooth Overlap of Atomic Positions (SOAP). Usage of the package is illustrated for two different applications: formation energy prediction for solids and ionic charge prediction for atoms in organic molecules. The package is freely available under the open-source Apache License 2.0. Program summary Program Title: DScribe Program Files doi: http://dx.doLorg/10.17632/vzrs8n8pk6.1 Licensing provisions: Apache-2.0 Programming language: Python/C/C++ Supplementary material: Supplementary Information as PDF Nature of problem: The application of machine learning for materials science is hindered by the lack of consistent software implementations for feature transformations. These feature transformations, also called descriptors, are a key step in building machine learning models for property prediction in materials science. Solution method: We have developed a library for creating common descriptors used in machine learning applied to materials science. We provide an implementation the following descriptors: Coulomb matrix, Ewald sum matrix, sine matrix, Many-body Tensor Representation (MBTR), Atom centered Symmetry Functions (ACSF) and Smooth Overlap of Atomic Positions (SOAP). The library has a python interface with computationally intensive routines written in C or C++. The source code, tutorials and documentation are provided online. A continuous integration mechanism is set up to automatically run a series of regression tests and check code coverage when the codebase is updated. (C) 2019 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 520, "Times Cited, All Databases": 569, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 247, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106949, "DOI": "10.1016/j.cpc.2019.106949", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2019.106949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503093400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, H; Zhu, GZ; Xu, XT; Liao, M; Li, YY; Angell, M; Gu, M; Zhu, YM; Hung, WH; Li, JC; Kuang, Y; Meng, YT; Lin, MC; Peng, HS; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Hao; Zhu, Guanzhou; Xu, Xintong; Liao, Meng; Li, Yuan-Yao; Angell, Michael; Gu, Meng; Zhu, Yuanmin; Hung, Wei Hsuan; Li, Jiachen; Kuang, Yun; Meng, Yongtao; Lin, Meng-Chang; Peng, Huisheng; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable sodium metal batteries with high energy density could be important to a wide range of energy applications in modern society. The pursuit of higher energy density should ideally come with high safety, a goal difficult for electrolytes based on organic solvents. Here we report a chloroaluminate ionic liquid electrolyte comprised of aluminium chloride/1-methyl-3-ethylimidazolium chloride/sodium chloride ionic liquid spiked with two important additives, ethylaluminum dichloride and 1-ethyl-3-methylimidazolium bis(fluorosulfonyl) imide. This leads to the first chloroaluminate based ionic liquid electrolyte for rechargeable sodium metal battery. The obtained batteries reached voltages up to similar to 4 V, high Coulombic efficiency up to 99.9%, and high energy and power density of similar to 420 Wh kg(-1) and similar to 1766 W kg(-1), respectively. The batteries retained over 90% of the original capacity after 700 cycles, suggesting an effective approach to sodium metal batteries with high energy/high power density, long cycle life and high safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3302, "DOI": "10.1038/s41467-019-11102-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11102-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476877400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grancini, G; Kandada, ARS; Frost, JM; Barker, AJ; De Bastiani, M; Gandini, M; Marras, S; Lanzani, G; Walsh, A; Petrozza, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grancini, Giulia; Kandada, Ajay Ram Srimath; Frost, Jarvist M.; Barker, Alex J.; De Bastiani, Michele; Gandini, Marina; Marras, Sergio; Lanzani, Guglielmo; Walsh, Aron; Petrozza, Annamaria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of microstructure in the electron-hole interaction of hybrid lead halide perovskites", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic metal halide perovskites have demonstrated high power conversion efficiencies in solar cells and promising performance in a wide range of optoelectronic devices. The existence and stability of bound electron-hole pairs in these materials and their role in the operation of devices with different architectures remains a controversial issue. Here we demonstrate, through a combination of optical spectroscopy and multiscale modelling as a function of the degree of polycrystallinity and temperature, that the electron-hole interaction is sensitive to the microstructure of the material. The long-range order is disrupted by polycrystalline disorder and the variations in electrostatic potential found for smaller crystals suppress exciton formation, while larger crystals of the same composition demonstrate an unambiguous excitonic state. We conclude that fabrication procedures and morphology strongly influence perovskite behaviour, with both free carrier and excitonic regimes possible, with strong implications for optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 695, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.151", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.151", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361974200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, FH; Zeng, C; Long, R; Miao, YP; Wei, L; Xu, QZ; Min, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Fanghao; Zeng, Chen; Long, Rong; Miao, Yupeng; Wei, Lu; Xu, Qizhi; Min, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supermultiplexed optical imaging and barcoding with engineered polyynes", "Source Title": "NATURE METHODS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical multiplexing has a large impact in photonics, the life sciences and biomedicine. However, current technology is limited by a 'multiplexing ceiling' from existing optical materials. Here we engineered a class of polyyne-based materials for optical supermultiplexing. We achieved 20 distinct Raman frequencies, as 'Carbon rainbow', through rational engineering of conjugation length, bond-selective isotope doping and end-capping substitution of polyynes. With further probe functionalization, we demonstrated ten-color organelle imaging in individual living cells with high specificity, sensitivity and photostability. Moreover, we realized optical data storage and identification by combinatorial barcoding, yielding to our knowledge the largest number of distinct spectral barcodes to date. Therefore, these polyynes hold great promise in live-cell imaging and sorting as well as in high-throughput diagnostics and screening.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 194, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMETH.4578", "DOI Link": "http://dx.doi.org/10.1038/NMETH.4578", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426303200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paxton, N; Smolan, W; Böck, T; Melchels, F; Groll, J; Jungst, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paxton, Naomi; Smolan, Willi; Boeck, Thomas; Melchels, Ferry; Groll, Juergen; Jungst, Tomasz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Proposal to assess printability of bioinks for extrusion-based bioprinting and evaluation of rheological properties governing bioprintability", "Source Title": "BIOFABRICATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development and formulation of printable inks for extrusion-based 3D bioprinting has been a major challenge in the field of biofabrication. Inks, often polymer solutions with the addition of crosslinking to form hydrogels, must not only display adequate mechanical properties for the chosen application but also show high biocompatibility as well as printability. Here we describe a reproducible two-step method for the assessment of the printability of inks for bioprinting, focussing firstly on screening ink formulations to assess fibre formation and the ability to form 3D constructs before presenting a method for the rheological evaluation of inks to characterise the yield point, shear thinning and recovery behaviour. In conjunction, a mathematical model was formulated to provide a theoretical understanding of the pressure-driven, shear thinning extrusion of inks through needles in a bioprinter. The assessment methods were trialled with a commercially available creme, poloxamer 407, alginate-based inks and an alginate-gelatine composite material. Yield stress was investigated by applying a stress ramp to a number of inks, which demonstrated the necessity of high yield for printable materials. The shear thinning behaviour of the inks was then characterised by quantifying the degree of shear thinning and using the mathematical model to predict the window of printer operating parameters in which the materials could be printed. Furthermore, the model predicted high shear conditions and high residence times for cells at the walls of the needle and effects on cytocompatibility at different printing conditions. Finally, the ability of the materials to recover to their original viscosity after extrusion was examined using rotational recovery rheological measurements. Taken together, these assessment techniques revealed significant insights into the requirements for printable inks and shear conditions present during the extrusion process and allow the rapid and reproducible characterisation of a wide variety of inks for bioprinting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 619, "Times Cited, All Databases": 699, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 44107, "DOI": "10.1088/1758-5090/aa8dd8", "DOI Link": "http://dx.doi.org/10.1088/1758-5090/aa8dd8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415327400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meghana, S; Kabra, P; Chakraborty, S; Padmavathy, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meghana, Surapaneni; Kabra, Prachi; Chakraborty, Swati; Padmavathy, Nagarajan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the pathway of antibacterial activity of copper oxide nulloparticles", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work investigates the role of oxidation state in the antibacterial activity of copper oxide nulloparticles (NPs). The findings add strong support to a contact killing mechanism of copper oxides (CuO and Cu2O) through which bacteria initially suffer severe damage to the cell envelope. Then further damage ensues by an independent pathway of each copper oxide nulloparticle. Formation of copper(I)-peptide complex from cuprous oxide (Cu2O) and free radical generation from cupric oxide (CuO) were identified as key sources of toxicity towards E. coli. Cu2O rapidly inactivated Fumarase A, an iron sulphur cluster enzyme suggesting the cuprous state of copper binding to the proteins. This inactivation was not noticed in CuO. The percentage of biocidal/bacteriostatic activity is closely related to the oxidation state of the copper oxides. In the case of E. coli, Cu2O nulloparticles showed more efficient antibacterial activity and higher affinity to the bacterial cells. CuO nulloparticles produced significant ROS in terms of super oxides while Cu2O did not. The diminishing defective emission peaks of Cu2O after incubation with microbes strongly suggest the formation of protein complexes. This work is carried out to enable better understanding of the mechanistic pathways of copper oxide nulloparticles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 455, "Times Cited, All Databases": 472, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 5, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12293, "End Page": 12299, "Article Number": null, "DOI": "10.1039/c4ra12163e", "DOI Link": "http://dx.doi.org/10.1039/c4ra12163e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348985400076", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ribeiro-Palau, R; Zhang, CJ; Watanabe, K; Taniguchi, T; Hone, J; Dean, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ribeiro-Palau, Rebeca; Zhang, Changjian; Watanabe, Kenji; Taniguchi, Takashi; Hone, James; Dean, Cory R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Twistable electronics with dynamically rotatable heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In heterostructures of two-dimensional materials, electronic properties can vary dramatically with relative interlayer angle. This effect makes it theoretically possible to realize a new class of twistable electronics in which properties can be manipulated on demand by means of rotation. We demonstrate a device architecture in which a layered heterostructure can be dynamically twisted in situ. We study graphene encapsulated by boron nitride, where, at small rotation angles, the device characteristics are dominated by coupling to a long-wavelength moire superlattice. The ability to investigate arbitrary rotation angle in a single device reveals features of the optical, mechanical, and electronic response in this system not captured in static rotation studies. Our results establish the capability to fabricate twistable electronic devices with dynamically tunable properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2018, "Volume": 361, "Issue": 6403, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 693, "Article Number": null, "DOI": "10.1126/science.aat6981", "DOI Link": "http://dx.doi.org/10.1126/science.aat6981", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442818200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Frith, JT; Lacey, MJ; Ulissi, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Frith, James T. T.; Lacey, Matthew J. J.; Ulissi, Ulderico", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A non-academic perspective on the future of lithium-based batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the field of lithium-based batteries, there is often a substantial divide between academic research and industrial market needs. This is in part driven by a lack of peer-reviewed publications from industry. Here we present a non-academic view on applied research in lithium-based batteries to sharpen the focus and help bridge the gap between academic and industrial research. We focus our discussion on key metrics and challenges to be considered when developing new technologies in this industry. We also explore the need to consider various performance aspects in unison when developing a new material/technology. Moreover, we also investigate the suitability of supply chains, sustainability of materials and the impact on system-level cost as factors that need to be accounted for when working on new technologies. With these considerations in mind, we then assess the latest developments in the lithium-based battery industry, providing our views on the challenges and prospects of various technologies. In the field of lithium-based batteries, there is often a divide between academic research and industrial needs. Here, the authors present a view on applied research to help bridge academia and industry, focusing on metrics and challenges to be considered for the development of practical batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 420, "DOI": "10.1038/s41467-023-35933-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35933-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001008541400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, DX; Sun, X; Li, F; Bak, SM; Ji, TT; Geiwitz, M; Burch, KS; Du, YH; Yang, GC; Zhu, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Daxian; Sun, Xiao; Li, Fei; Bak, Seong-Min; Ji, Tongtai; Geiwitz, Michael; Burch, Kenneth S.; Du, Yonghua; Yang, Guochun; Zhu, Hongli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Electrochemical Reaction Mechanisms of Sulfur in All-Solid-State Batteries through Operando and Theoretical Studies", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to its outstanding safety and high energy density, all-solid-state lithium-sulfur batteries (ASLSBs) are considered as a potential future energy storage technology. The electrochemical reaction pathway in ASLSBs with inorganic solid-state electrolytes is different from Li-S batteries with liquid electrolytes, but the mechanism remains unclear. By combining operando Raman spectroscopy and ex situ X-ray absorption spectroscopy, we investigated the reaction mechanism of sulfur (S-8) in ASLSBs. Our results revealed that no Li2S8, Li2S6, and Li2S4 were formed, yet Li2S2 was detected. Furthermore, first-principles structural calculations were employed to disclose the formation energy of solid state Li2Sn (1=n=8), in which Li2S2 was a metastable phase, consistent with experimental observations. Meanwhile, partial S-8 and Li2S2 remained at the full lithiation stage, suggesting incomplete reaction due to sluggish reaction kinetics in ASLSBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2023, "Volume": 62, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202302363", "DOI": "10.1002/anie.202302363", "DOI Link": "http://dx.doi.org/10.1002/anie.202302363", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000969700400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, KT; Chermprayong, P; Xiao, F; Tzoumanikas, D; Dams, B; Kay, S; Kocer, BB; Burns, A; Orr, L; Choi, C; Darekar, DD; Li, WB; Hirschmann, S; Soana, V; Ngah, SA; Sareh, S; Choubey, A; Margheri, L; Pawar, VM; Ball, RJ; Williams, C; Shepherd, P; Leutenegger, S; Stuart-Smith, R; Kovac, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ketao; Chermprayong, Pisak; Xiao, Feng; Tzoumanikas, Dimos; Dams, Barrie; Kay, Sebastian; Kocer, Basaran Bahadir; Burns, Alec; Orr, Lachlan; Choi, Christopher; Darekar, Durgesh Dattatray; Li, Wenbin; Hirschmann, Steven; Soana, Valentina; Ngah, Shamsiah Awang; Sareh, Sina; Choubey, Ashutosh; Margheri, Laura; Pawar, Vijay M.; Ball, Richard J.; Williams, Chris; Shepherd, Paul; Leutenegger, Stefan; Stuart-Smith, Robert; Kovac, Mirko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aerial additive manufacturing with multiple autonomous robots", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing methods(1-4) using static and mobile robots are being developed for both on-site construction(5-8) and off-site prefabrication(9,10). Here we introduce a method of additive manufacturing, referred to as aerial additive manufacturing (Aerial-AM), that utilizes a team of aerial robots inspired by natural builders(11) such as wasps who use collective building methods(12,13). We present a scalable multi-robot three-dimensional (3D) printing and path-planning framework that enables robot tasks and population size to be adapted to variations in print geometry throughout a building mission. The multi-robot manufacturing framework allows for autonomous three-dimensional printing under human supervision, real-time assessment of printed geometry and robot behavioural adaptation. To validate autonomous Aerial-AM based on the framework, we develop BuilDrones for depositing materials during flight and ScanDrones for measuring the print quality, and integrate a generic real-time model-predictive-control scheme with the Aerial-AM robots. In addition, we integrate a dynamically self-aligning delta manipulator with the BuilDrone to further improve the manufacturing accuracy to five millimetres for printing geometry with precise trajectory requirements, and develop four cementitious-polymeric composite mixtures suitable for continuous material deposition. We demonstrate proof-of-concept prints including a cylinder 2.05 metres high consisting of 72 layers of a rapid-curing insulation foam material and a cylinder 0.18 metres high consisting of 28 layers of structural pseudoplastic cementitious material, a light-trail virtual print of a dome-like geometry, and multi-robot simulations. Aerial-AM allows manufacturing in-flight and offers future possibilities for building in unbounded, at-height or hard-to-access locations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 22", "Publication Year": 2022, "Volume": 609, "Issue": 7928, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 709, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04988-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04988-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000859132200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liccardo, L; Bordin, M; Sheverdyaeva, PM; Belli, M; Moras, P; Vomiero, A; Moretti, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liccardo, Letizia; Bordin, Matteo; Sheverdyaeva, Polina M.; Belli, Matteo; Moras, Paolo; Vomiero, Alberto; Moretti, Elisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Defect Engineering in Colored TiO2 Hollow Spheres Toward Efficient Photocatalysis", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured TiO2 is one of the best materials for photocatalysis, thanks to its high surface area and surface reactivity, but its large energy bandgap (3.2 eV) hinders the use of the entire solar spectrum. Here, it is proposed that defect-engineered nullostructured TiO2 photocatalysts are obtained by hydrogenation strategy to extend its light absorption up to the near-infrared region. It is demonstrated that hydrogenated or colored TiO2 hollow spheres (THS) composed of hierarchically assembled nulloparticles result in much broader exploitation of the solar spectrum (up to 1200 nm) and the engineered surface enhances the photogeneration of charges for photocatalytic processes. In turn, when applied for photodegradation of a targeted drug (Ciprofloxacin) this results in 82% degradation after 6 h under simulated sunlight. Valence band analysis by photoelectron spectroscopy revealed the presence of oxygen vacancies, whose surface density increases with the hydrogenation rate. Thus, a tight correlation between degree of hydrogenation and photocatalytic activity is directly established. Further insight comes from electron paramagnetic resonullce, which evidences bulk Ti3+ centers only in hydrogenated THS. The results are anticipated to disclose a new path toward highly efficient photocatalytic titania in a series of applications targeting water remediation and solar fuel production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 33, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202212486", "DOI Link": "http://dx.doi.org/10.1002/adfm.202212486", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950427100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rojo, E; Peresin, MS; Sampson, WW; Hoeger, IC; Vartiainen, J; Laine, J; Rojas, OJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rojo, Ester; Peresin, Maria Soledad; Sampson, William W.; Hoeger, Ingrid C.; Vartiainen, Jari; Laine, Janne; Rojas, Orlando J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comprehensive elucidation of the effect of residual lignin on the physical, barrier, mechanical and surface properties of nullocellulose films", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We elucidate the effect of residual lignin on the interfacial, physical and mechanical properties of lignocellulose nullofibrils (LCNF) and respective nullopapers. Fibers containing similar to 0, 2, 4, and 14 wt% residual lignin were microfluidized into LCNF aqueous suspensions and were processed into dry films (nullopapers). A systematic decrease in fibril diameter with increasing residual lignin was observed upon fibrillation, consistent with the radical scavenging ability of the lignin that results in better cell wall deconstruction. The stiff nature of the lignin-containing fibrils made them less able to conform during filtration and improved extensively dewatering, owing to a more open structure. However, the softening of the lignin during hot-pressing of the nullopapers and its amorphous nature enabled a binding effect, filling the voids between the nullofibers (thus reducing the number of micropores) and making the surface of the nullopapers smoother. The interfacial free energy of interaction changed drastically with the increased lignin content: the corresponding water contact angles were 35 degrees and 78 degrees for the lignin-free and for the (14%) lignin-containing nullopaper, respectively, revealing the increase in hydrophobicity. Together with the significantly less porous structure of LCNF nullopapers, lower water absorbency was observed with increased lignin content. Lignin in the nullopapers reduced the oxygen permeability by up to 200-fold. Water vapor permeability, in turn, did not correlate linearly with lignin content but depended most significantly on material density. The tensile strength, modulus, and strain for the LCNF nullopapers were found to be in the range 116-164 MPa, 10.5-14.3 GPa, and 1.7-3.5%, respectively. To a good degree of approximation, these mechanical properties were rather insensitive to lignin content and comparable to those of nullopapers derived from fully bleached CNF. Whilst it might be expected that lignin interferes in hydrogen bonding between fibrils, this was apparently counteracted by the uniform distribution of lignin seemingly aiding stress-transfer between fibrils and thus preserving mechanical properties. Overall, LCNF is demonstrated to be a suitable precursor of nullopaper, especially when reduced polarity and low hydrophilicity are desirable in related bio-products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1853, "End Page": 1866, "Article Number": null, "DOI": "10.1039/c4gc02398f", "DOI Link": "http://dx.doi.org/10.1039/c4gc02398f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351091300058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, ZP; Zhao, G; Zhang, YY; Gu, ZH; Tang, YH; Aladejana, JT; Ren, JN; Jiang, YH; Guo, ZH; Peng, XF; Zhang, XH; Xu, BB; Chen, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Zipeng; Zhao, Gang; Zhang, Yaoyang; Gu, Zhiheng; Tang, Yuhan; Aladejana, John Tosin; Ren, Junna; Jiang, Yunhong; Guo, Zhanhu; Peng, Xiangfang; Zhang, Xuehua; Xu, Ben Bin; Chen, Tingjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Simple and Effective Physical Ball-Milling Strategy to Prepare Super-Tough and Stretchable PVA@MXene@PPy Hydrogel for Flexible Capacitive Electronics", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimetic flexible electronics for E-skin have received increasing attention, due to their ability to sense various movements. However, the development of smart skin-mimic material remains a challenge. Here, a simple and effective approach is reported to fabricate super-tough, stretchable, and self-healing conductive hydrogel consisting of polyvinyl alcohol (PVA), Ti3C2Tx MXene nullosheets, and polypyrrole (PPy) (PMP hydrogel). The MXene nullosheets and Fe3+ serve as multifunctional cross-linkers and effective stress transfer centers, to facilitate a considerable high conductivity, super toughness, and ultra-high stretchability (elongation up to 4300%) for the PMP hydrogel with. The hydrogels also exhibit rapid self-healing and repeatable self-adhesive capacity because of the presence of dynamic borate ester bond. The flexible capacitive strain sensor made by PMP hydrogel shows a relatively broad range of strain sensing (up to 400%), with a self-healing feature. The sensor can precisely monitor various human physiological signals, including joint movements, facial expressions, and pulse waves. The PMP hydrogel-based supercapacitor is demonstrated with a high capacitance retention of & AP;92.83% and a coulombic efficiency of & AP;100%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2023, "Volume": 19, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/smll.202303038", "DOI Link": "http://dx.doi.org/10.1002/smll.202303038", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032464000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Granberg, F; Nordlund, K; Ullah, MW; Jin, K; Lu, C; Bei, H; Wang, LM; Djurabekova, F; Weber, WJ; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Granberg, F.; Nordlund, K.; Ullah, Mohammad W.; Jin, K.; Lu, C.; Bei, H.; Wang, L. M.; Djurabekova, F.; Weber, W. J.; Zhang, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of Radiation Damage Reduction in Equiatomic Multicomponent Single Phase Alloys", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently a new class of metal alloys, of single-phase multicomponent composition at roughly equal atomic concentrations (equiatomic), have been shown to exhibit promising mechanical, magnetic, and corrosion resistance properties, in particular, at high temperatures. These features make them potential candidates for components of next-generation nuclear reactors and other high-radiation environments that will involve high temperatures combined with corrosive environments and extreme radiation exposure. In spite of a wide range of recent studies of many important properties of these alloys, their radiation tolerance at high doses remains unexplored. In this work, a combination of experimental and modeling efforts reveals a substantial reduction of damage accumulation under prolonged irradiation in single-phase NiFe and NiCoCr alloys compared to elemental Ni. This effect is explained by reduced dislocation mobility, which leads to slower growth of large dislocation structures. Moreover, there is no observable phase separation, ordering, or amorphization, pointing to a high phase stability of this class of alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2016, "Volume": 116, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 135504, "DOI": "10.1103/PhysRevLett.116.135504", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.135504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373202000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Xiao, X; Ran, Y; Bin, ZY; You, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yang; Xiao, Xin; Ran, You; Bin, Zhengyang; You, Jingsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular design of thermally activated delayed fluorescent emitters for narrowband orange-red OLEDs boosted by a cyano-functionalization strategy", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The establishment of a simple molecular design strategy to realize red-shifted emission while maintaining good color purity for multi-resonullce induced thermally activated delayed fluorescent (MR-TADF) materials remains an appealing yet challenging task. Herein, we demonstrate that the attachment of a cyano (CN) functionality at the lowest unoccupied molecular orbital location of the MR-TADF skeleton can promote attractive red-shifted emission due to the exceptional electron-withdrawing capacity of the CN group, which represents the first example of orange-red MR-TADF emitters. Meanwhile, the linear CN group adopts a coplanar conformation with the MR-framework to restrict structure relaxation associated with rotation, which is beneficial to maintain a small full-width at half-maximum and thus a good color purity. The CNCz-BNCz-based OLED device, which utilizes a TADF sensitized mechanism to accelerate the up-conversion process of triplet excitons in the emitting layer, exhibits an outstanding external quantum efficiency (EQE) as high as 33.7%, representing the state-of-the-art performance for orange-red TADF-OLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2021, "Volume": 12, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9408, "End Page": 9412, "Article Number": null, "DOI": "10.1039/d1sc02042k", "DOI Link": "http://dx.doi.org/10.1039/d1sc02042k", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662326300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MF; Liu, SS; Qian, T; Liul, J; Zhou, JQ; Ji, HQ; Xiong, J; Zhong, J; Yan, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mengfan; Liu, Sisi; Qian, Tao; Liul, Jie; Zhou, Jinqiu; Ji, Haoqing; Xiong, Jie; Zhong, Jun; Yan, Chenglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 56.55% Faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient electrochemical N-2 reduction is emerging as a highly promising alternative to the Haber-Bosch process but is typically hampered by a high reaction barrier and competing hydrogen evolution, leading to an extremely low Faradaic efficiency. Here, we demonstrate that under ambient conditions, a single-atom catalyst, iron on nitrogen-doped carbon, could positively shift the ammonia synthesis process to an onset potential of 0.193 V, enabling a dramatically enhanced Faradaic efficiency of 56.55%. The only doublet coupling representing (NH4+)-N-15 in an isotopic labeling experiment confirms reliable NH3 production data. Molecular dynamics simulations suggest efficient N-2 access to the single-atom iron with only a small energy barrier, which benefits preferential N-2 adsorption instead of H adsorption via a strong exothermic process, as further confirmed by first-principle calculations. The released energy helps promote the following process and the reaction bottleneck, which is widely considered to be the first hydrogenation step, is successfully overcome.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 341, "DOI": "10.1038/s41467-018-08120-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08120-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456164400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wolfs, RJM; Bos, FP; Salet, TAM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wolfs, R. J. M.; Bos, F. P.; Salet, T. A. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hardened properties of 3D printed concrete: The influence of process parameters on interlayer adhesion", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The technology of 3D Concrete Printing (3DCP) has progressed rapidly over the last years. With the aim to realize both buildings and civil works, the need for reliable mechanical properties of printed concrete grows. As a consequence of the additive manufacturing technique, 3D printed structures may consist of several layers that should exhibit bond to guarantee a safe structural design. This paper presents the results of an experimental study on the relation between the 3DCP process parameters and the bond strength of 3D printed concrete. The effect of 3 process parameters (interlayer interval time, nozzle height, and surface dehydration) on two mechanical properties (compressive strength and tensile strength, determined through flexural and splitting tests), has been established, in three perpendicular directions. A very limited influence of layer orientation was found for the given process-material combination, given a sufficiently short interlayer interval time. However, the bond strength between the layers reduced for increasing interlayer interval times. This was also reflected by the failure mode of the samples. The reduction in strength became more pronounced for the samples that were left uncovered during the interval time, exposed to drying. No clear relation was found between the height of the nozzle, and the bond strength between layers. The results of this study, in comparison to various other works on 3DCP, emphasize the need for standardization of test methods and characterization of 3D printed concrete, as individual process parameters clearly must be considered in relation to the applied material and other process parameters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 426, "Times Cited, All Databases": 455, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 132, "End Page": 140, "Article Number": null, "DOI": "10.1016/j.cemconres.2019.02.017", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2019.02.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464482200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, ZP; Sánchez-Lengeling, B; Bobbitt, NS; Bucior, BJ; Kumar, SGH; Collins, SP; Burns, T; Woo, TK; Farha, OK; Snurr, RQ; Aspuru-Guzik, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Zhenpeng; Sanchez-Lengeling, Benjamin; Bobbitt, N. Scott; Bucior, Benjamin J.; Kumar, Sai Govind Hari; Collins, Sean P.; Burns, Thomas; Woo, Tom K.; Farha, Omar K.; Snurr, Randall Q.; Aspuru-Guzik, Alan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverse design of nulloporous crystalline reticular materials with deep generative models", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reticular frameworks are crystalline porous materials that form via the self-assembly of molecular building blocks in different topologies, with many having desirable properties for gas storage, separation, catalysis, biomedical applications and so on. The notable variety of building blocks makes reticular chemistry both promising and challenging for prospective materials design. Here we propose an automated nulloporous materials discovery platform powered by a supramolecular variational autoencoder for the generative design of reticular materials. We demonstrate the automated design process with a class of metal-organic framework (MOF) structures and the goal of separating carbon dioxide from natural gas or flue gas. Our model shows high fidelity in capturing MOF structural features. We show that the autoencoder has a promising optimization capability when jointly trained with multiple top adsorbent candidates identified for superior gas separation. MOFs discovered here are strongly competitive against some of the best-performing MOFs/zeolites ever reported.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": 86, "Article Number": null, "DOI": "10.1038/s42256-020-00271-1", "DOI Link": "http://dx.doi.org/10.1038/s42256-020-00271-1", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607597200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hojjatzadeh, SMH; Parab, ND; Guo, QL; Qu, ML; Xiong, LH; Zhao, C; Escano, LI; Fezzaa, K; Everhart, W; Sun, T; Chen, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hojjatzadeh, S. Mohammad H.; Parab, Niranjan D.; Guo, Qilin; Qu, Minglei; Xiong, Lianghua; Zhao, Cang; Escano, Luis, I; Fezzaa, Kamel; Everhart, Wes; Sun, Tao; Chen, Lianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of pore formation mechanisms during LPBF additive manufacturing process and high energy density laser welding", "Source Title": "INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser powder bed fusion (LPBF) is a 3D printing technology that can print parts with complex geometries that are unachievable by conventional manufacturing technologies. However, pores formed during the printing process impair the mechanical performance of the printed parts, severely hindering their widespread application. Here, we report six pore formation mechanisms that were observed during the LPBF process. Our results reconfirm three pore formation mechanisms - keyhole induced pores, pore formation from feedstock powder and pore formation along the melting boundary during laser melting from vaporization of a volatile substance or an expansion of a tiny trapped gas. We also observe three new pore formation mechanisms: (1) pore trapped by surface fluctuation, (2) pore formation due to depression zone fluctuation when the depression zone is shallow and (3) pore formation from a crack. The results presented here provide direct evidence and insight into pore formation mechanisms during the LPBF process, which may guide the development of pore elimination/mitigation approaches. Since certain laser processing conditions studied here are similar to the situations in high energy density laser welding, the results presented here also have implications for laser welding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 153, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103555, "DOI": "10.1016/j.ijmachtools.2020.103555", "DOI Link": "http://dx.doi.org/10.1016/j.ijmachtools.2020.103555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536177300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ley, MB; Jepsen, LH; Lee, YS; Cho, YW; von Colbe, JMB; Dornheim, M; Rokni, M; Jensen, JO; Sloth, M; Filinchuk, Y; Jorgensen, JE; Besenbacher, F; Jensen, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ley, Morten B.; Jepsen, Lars H.; Lee, Young-Su; Cho, Young Whan; von Colbe, Jose M. Bellosta; Dornheim, Martin; Rokni, Masoud; Jensen, Jens Oluf; Sloth, Mikael; Filinchuk, Yaroslav; Jorgensen, Jens Erik; Besenbacher, Flemming; Jensen, Torben R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Complex hydrides for hydrogen storage - new perspectives", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the 1970s, hydrogen has been considered as a possible energy carrier for the storage of renewable energy. The main focus has been on addressing the ultimate challenge: developing an environmentally friendly successor for gasoline. This very ambitious goal has not yet been fully reached, as discussed in this review, but a range of new lightweight hydrogen-containing materials has been discovered with fascinating properties. State-of-the-art and future perspectives for hydrogen-containing solids will be discussed, with a focus on metal borohydrides, which reveal significant structural flexibility and may have a range of new interesting properties combined with very high hydrogen densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 431, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 122, "End Page": 128, "Article Number": null, "DOI": "10.1016/j.mattod.2014.02.013", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.02.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334584400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, MY; Qin, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Mengyue; Qin, Faxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Clarification of basic concepts for electromagnetic interference shielding effectiveness", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There exists serious miscomprehension in the open literature about the electromagnetic interference shielding effectiveness (EMI SE) as a critical index to evaluate the shielding performance, which is misleading to the graduates and newcomers embarking on the field of electromagnetic shielding materials. EMI SE is defined as the sum of three terms including reflection loss, absorption loss, and multiple reflection loss in the classical Schelkunoff theory, while it is decomposed into two terms named reflection loss and absorption loss in practice, which is called Calculation theory here. In this paper, we elucidate the widely seen misconceptions connected with EMI SE via theoretical derivation and instance analysis. First, the terms in Calculation theory are often mistakenly regarded as the approximation of the terms with the same names in Schelkunoff theory when multiple reflection loss is negligible. Second, it is insufficient and unreasonable to determine the absorption-dominullt shielding performance in the case that absorption loss is higher than reflection loss since reflection loss and absorption loss cannot represent the actual levels of reflected and absorbed power. Power coefficients are recommended to compare the contribution of reflection and absorption to shielding performance. Third, multiple reflection effect is included in the definitions of reflection loss and absorption loss in Calculation theory, and the effect of multiple reflections on shielding property is clarified as against the commonly wrong understandings. These clarifications offer correct comprehension about the shielding mechanism and assessment of reflection and absorption contribution to the total shielding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2021, "Volume": 130, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 225108, "DOI": "10.1063/5.0075019", "DOI Link": "http://dx.doi.org/10.1063/5.0075019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733892100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZY; Sun, RB; Huang, ZX; Han, X; Wang, HR; Chen, C; Liu, YQ; Zheng, XS; Zhang, WJ; Hong, X; Li, WW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhi-Yan; Sun, Rongbo; Huang, Zixiang; Han, Xiao; Wang, Haoran; Chen, Cai; Liu, Yu-Qin; Zheng, Xusheng; Zhang, Wenjun; Hong, Xun; Li, Wen-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystallinity engineering for overcoming the activity-stability tradeoff of spinel oxide in Fenton- like catalysis", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A precise modulation of heterogeneous catalysts in structural and surface properties promises the development of more sustainable advanced oxidation water purification technologies. However, while catalysts with superior decontamination activity and selectivity are already achievable, maintaining a long- term service life of such materials remains challenging. Here, we propose a crystallinity engineering strategy to break the activity-stability tradeoff of metal oxides in Fenton- like catalysis. The amorphous/crystalline cobalt-manganese spinel oxide (A/C-CoMnOx) provided highly active, hydroxyl group- rich surface, with moderate peroxymonosulfate (PMS)-binding affinity and charge transfer energy and strong pollutant adsorption, to trigger concerted radical and non-radical reactions for efficient pollutant mineralization, thereby alleviating the catalyst passivation by oxidation intermediate accumulation. Meanwhile, the surface- confined reactions, benefited from the enhanced adsorption of pollutants at A/C interface, rendered the A/C-CoMnOx/PMS system ultrahigh PMS utilization efficiency (82.2%) and unprecedented decontamination activity (rate constant of 1.48 min(-1)) surpassing almost all the state- of-the- art heterogeneous Fenton- like catalysts. The superior cyclic stability and environmental robustness of the system for real water treatment was also demonstrated. Our work unveils a critical role of material crystallinity in modulating the Fenton- like catalytic activity and pathways of metal oxides, which fundamentally improves our understanding of the structure-activity-selectivity relationships of heterogeneous catalysts and may inspire material design for more sustainable water purification application and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2023, "Volume": 120, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2220608120", "DOI": "10.1073/pnas.2220608120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2220608120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038063300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, JL; Xie, WH; Guo, Y; Zhao, T; Zhou, H; Wang, QY; Li, HD; Guo, ZH; Bin Xu, B; Gu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Junling; Xie, Wenhao; Guo, Ying; Zhao, Tong; Zhou, Heng; Wang, Qiaoying; Li, Handong; Guo, Zhanhu; Bin Xu, Ben; Gu, Hongbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 340, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123225, "DOI": "10.1016/j.apcatb.2023.123225", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2023.123225", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001069094400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, J; Li, YY; Alsem, DH; So, H; Lee, SC; Bai, P; Cogswell, DA; Liu, XZ; Jin, N; Yu, YS; Salmon, NJ; Shapiro, DA; Bazant, MZ; Tyliszczak, T; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Jongwoo; Li, Yiyang; Alsem, Daan Hein; So, Hongyun; Lee, Sang Chul; Bai, Peng; Cogswell, Daniel A.; Liu, Xuzhao; Jin, Norman; Yu, Young-sang; Salmon, Norman J.; Shapiro, David A.; Bazant, Martin Z.; Tyliszczak, Tolek; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The kinetics and uniformity of ion insertion reactions at the solid-liquid interface govern the rate capability and lifetime, respectively, of electrochemical devices such as Li-ion batteries. Using an operando x-ray microscopy platform that maps the dynamics of the Li composition and insertion rate in LixFePO4, we found that nulloscale spatial variations in rate and in composition control the lithiation pathway at the subparticle length scale. Specifically, spatial variations in the insertion rate constant lead to the formation of nonuniform domains, and the composition dependence of the rate constant amplifies nonuniformities during delithiation but suppresses them during lithiation, and moreover stabilizes the solid solution during lithiation. This coupling of lithium composition and surface reaction rates controls the kinetics and uniformity during electrochemical ion insertion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2016, "Volume": 353, "Issue": 6299, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 566, "End Page": 571, "Article Number": null, "DOI": "10.1126/science.aaf4914", "DOI Link": "http://dx.doi.org/10.1126/science.aaf4914", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381560900036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lang, L; Yang, JH; Liu, HR; Xiang, HJ; Gong, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lang, Li; Yang, Ji-Hui; Liu, Heng-Rui; Xiang, H. J.; Gong, X. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles study on the electronic and optical properties of cubic ABX3 halide perovskites", "Source Title": "PHYSICS LETTERS A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic properties of ABX(3) type compounds in the cubic phase are systematically studied using the first-principles calculations. The chemical trend of their properties as A or B or X varies is fully investigated. The optical properties of the ABX(3) compounds are also investigated. Our calculations show that taking into account the spin-orbit coupling effect is crucial for predicting the accurate band gap of these halide perovskites. We predict that CH3NH3SnBr3 is a promising material for solar cells absorber with a perfect band gap and good optical absorption. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2014, "Volume": 378, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 293, "Article Number": null, "DOI": "10.1016/j.physleta.2013.11.018", "DOI Link": "http://dx.doi.org/10.1016/j.physleta.2013.11.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330500800032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, W; Wang, H; Boyle, DT; Li, YZ; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, William; Wang, Hansen; Boyle, David T.; Li, Yuzhang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resolving nulloscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stability of lithium batteries is tied to the physicochemical properties of the solid-electrolyte interphase (SEI). Owing to the difficulty in characterizing this sensitive interphase, the nulloscale distribution of SEI components is poorly understood. Here, we use cryogenic scanning transmission electron microscopy (cryo-STEM) to map the spatial distribution of SEI components across the metallic Li anode. We reveal that LiF, an SEI component widely believed to play an important role in battery passivation, is absent within the compact SEI film (similar to 15 nm); instead, LiF particles (100-400 nm) precipitate across the electrode surface. We term this larger length scale as the indirect SEI regime. On the basis of these observations, we conclude that LiF cannot be a dominullt contribution to anode passivation nor does it influence Li+ transport across the compact SEI film. We refine the traditional SEI structure derived from ensemble-averaged characterizations and nuance the role of SEI components on battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2020, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1128, "End Page": 1135, "Article Number": null, "DOI": "10.1021/acsenergylett.0c00194", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.0c00194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526315900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, JH; Liao, JF; Zhou, L; Luo, JB; Wang, XD; Kuang, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Jun-Hua; Liao, Jin-Feng; Zhou, Lei; Luo, Jian-Bin; Wang, Xu-Dong; Kuang, Dai-Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Indium-antimony-halide single crystals for high-efficiency white-light emission and anti-counterfeiting", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although single-source white emissive perovskite has emerged as a class of encouraging light-emitting material, the synthesis of lead-free halide perovskite materials with high luminous efficiency is still challenging. Here, we report a series of zero-dimensional indium-antimony (In/Sb) alloyed halide single crystals, BAPPIn(2-2x)Sb(2x)Cl(10) (BAPP = C10H28N4, x = 0 to 1), with tunable emission. In BAPPIn(1.996)Sb(0.004)Cl(10), bright yellow emission with near 100% photoluminescence quantum yield (PLQY) is yielded when it was excited at 320 nm, which turns into bright white-light emission with a PLQY of 44.0% when excited at 365 nm. Combined spectroscopy and theoretical studies reveal that the BAPP(4+)-associated blue emission and inorganic polyhedron-afforded orange emission function as a perfect pair of complementary colors affording white light in BAPPIn(1.996)Sb(0.004)Cl(10). Moreover, the interesting afterglow behavior, together with excitation-dependent emission property, makes BAPPIn(2-2x)Sb(2x)Cl(10) as high-performance anti-counterfeiting/information storage materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 7, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg3989", "DOI": "10.1126/sciadv.abg3989", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg3989", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000689732700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, FY; Xu, N; Zhao, W; Zhou, L; Zhu, PC; Wang, XY; Zhu, B; Zhu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Fengyue; Xu, Ning; Zhao, Wei; Zhou, Lin; Zhu, Pengcheng; Wang, Xueyang; Zhu, Bin; Zhu, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-performing single-stage invert-structured solar water purifier through enhanced absorption and condensation", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfacial solar vapor generation is an emerging technology for producing purified water with a minimized carbon footprint. While the evaporation rate has been significantly increased, the rate of water collection has been limited because of ineffective heat transfer during condensation and compromised light absorption in the conventionally designed solar still. In this work, an invert-structured, single-stage solar water purifier (ISWP) is elaborately designed and fabricated and consists of a top selective absorber and a honeycombed bottom water condenser based on hydrophobic nullostructured copper. This inverted structure not only avoids optical loss due to the vapor condensation but also realizes enhanced heat transfer and condensation. As a result, it can achieve a high water-collection rate of 1.063 kg m(-2) h(-1) and an overall efficiency of solar collected water of similar to 70% for single-stage solar purification systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2021, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1602, "End Page": 1612, "Article Number": null, "DOI": "10.1016/j.joule.2021.04.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.04.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663028600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YH; Goulet, MA; Tong, LC; Liu, YZ; Ji, YL; Wu, L; Gordon, RG; Aziz, MJ; Yang, ZJ; Xu, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yahua; Goulet, Marc-Antoni; Tong, Liuchuan; Liu, Yazhi; Ji, Yunlong; Wu, Liang; Gordon, Roy G.; Aziz, Michael J.; Yang, Zhengjin; Xu, Tongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Long-Lifetime All-Organic Aqueous Flow Battery Utilizing TMAP-TEMPO Radical", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The massive-scale integration of renewable electricity into the power grid is impeded by its intrinsic intermittency. The aqueous organic redox flow battery (AORFB) rises as a potential storage solution; however, the choice of positive electrolytes is limited, and the aqueous-soluble organic positive redox-active species reported to date have short lifetimes. Here we report a stable organic molecule for the positive terminal, 4-(3-(trimethylammonio)propoxy)-2,2,6,6-tetramethylpiperidine-1-oxyl (TMAP-TEMPO) chloride, exhibiting high (4.62 M) aqueous solubility. When operated in a practical AORFB against a negative electrolyte comprising BTMAP-viologen at neutral pH, the flow cell displayed an open-circuit voltage of 1.1 volts and a Coulombic efficiency of >99.73%. The capacity retention rate is among the highest of all-organic AORFBs reported to date, at 99-993% per cycle over 1,000 consecutive cycles; the temporal capacity fade rate of 0.026% per h is independent of concentration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2019, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1861, "End Page": 1870, "Article Number": null, "DOI": "10.1016/j.chempr.2019.04.021", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.04.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476612700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ZR; Gu, FD; Li, YL; Sun, WH; Ye, SY; Rao, HX; Liu, ZW; Bian, ZQ; Huang, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ziran; Gu, Feidan; Li, Yunlong; Sun, Weihai; Ye, Senyun; Rao, Haixia; Liu, Zhiwei; Bian, Zuqiang; Huang, Chunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed-Organic-Cation Tin Iodide for Lead-Free Perovskite Solar Cells with an Efficiency of 8.12%", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a fully tin-based, mixed-organic-cation perovskite absorber (FA)(x)(MA)(1-x)SnI3 (FA = NH2CH = NH2+, MA = CH3NH3+) for lead-free perovskite solar cells (PSCs) with inverted structure is presented. By optimizing the ratio of FA and MA cations, a maximum power conversion efficiency of 8.12% is achieved for the (FA)(0.75)(MA)(0.25)SnI3-based device along with a high open-circuit voltage of 0.61 V, which originates from improved perovskite film morphology and inhibits recombination process in the device. The cation-mixing approach proves to be a facile method for the efficiency enhancement of tin-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700204, "DOI": "10.1002/advs.201700204", "DOI Link": "http://dx.doi.org/10.1002/advs.201700204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416155900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Csernica, PM; Kalirai, SS; Gent, WE; Lim, K; Yu, YS; Liu, YZ; Ahn, SJ; Kaeli, E; Xu, X; Stone, KH; Marshall, AF; Sinclair, R; Shapiro, DA; Toney, MF; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Csernica, Peter M.; Kalirai, Samanbir S.; Gent, William E.; Lim, Kipil; Yu, Young-Sang; Liu, Yunzhi; Ahn, Sung-Jin; Kaeli, Emma; Xu, Xin; Stone, Kevin H.; Marshall, Ann F.; Sinclair, Robert; Shapiro, David A.; Toney, Michael F.; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Persistent and partially mobile oxygen vacancies in Li-rich layered oxides", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing the energy density of layered oxide battery electrodes is challenging as accessing high states of delithiation often triggers voltage degradation and oxygen release. Here we utilize transmission-based X-ray absorption spectromicroscopy and ptychography on mechanically cross-sectioned Li1.18-xNi0.21Mn0.53Co0.08O2-delta electrodes to quantitatively profile the oxygen deficiency over cycling at the nulloscale. The oxygen deficiency penetrates into the bulk of individual primary particles (similar to 200 nm) and is well-described by oxygen vacancy diffusion. Using an array of characterization techniques, we demonstrate that, surprisingly, bulk oxygen vacancies that persist within the native layered phase are indeed responsible for the observed spectroscopic changes. We additionally show that the arrangement of primary particles within secondary particles (similar to 5 mu m) causes considerable heterogeneity in the extent of oxygen release between primary particles. Our work merges an ensemble of length-spanning characterization methods and informs promising approaches to mitigate the deleterious effects of oxygen release in lithium-ion battery electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 642, "End Page": 652, "Article Number": null, "DOI": "10.1038/s41560-021-00832-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00832-7", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661400300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yufit, V; Tariq, F; Eastwood, DS; Biton, M; Wu, B; Lee, PD; Brandon, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yufit, Vladimir; Tariq, Farid; Eastwood, David S.; Biton, Moshiel; Wu, Billy; Lee, Peter D.; Brandon, Nigel P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando Visualization and Multi-scale Tomography Studies of Dendrite Formation and Dissolution in Zinc Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alternative battery technologies are required to meet growing energy demands and address the limitations of present technologies. As such, it is necessary to look beyond lithium-ion batteries. Zinc batteries enable high power density while being sourced from ubiquitous and cost-effective materials. This paper presents, for the first time known to the authors, multi-length scale tomography studies of failure mechanisms in zinc batteries with and without commercial microporous separators. In both cases, dendrites were grown, dissolved, and regrown, critically resulting in different morphology of dendritic layer formed on both the electrode and the separator. The growth of dendrites and their volume-specific areas were quantified using tomography and radiography data in unprecedented resolution. High-resolution ex situ analysis was employed to characterize single dendrites and dendritic deposits inside the separator. The findings provide unique insights into mechanisms of metal-battery failure effected by growing dendrites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 485, "End Page": 502, "Article Number": null, "DOI": "10.1016/j.joule.2018.11.002", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.11.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460076100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, Y; Yue, YY; Ding, QQ; Mei, CT; Xu, XW; Jiang, SH; He, SJ; Wu, QL; Xiao, HN; Han, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Ya; Yue, Yiying; Ding, Qinqin; Mei, Changtong; Xu, Xinwu; Jiang, Shaohua; He, Shuijian; Wu, Qinglin; Xiao, Huining; Han, Jingquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environment-tolerant ionic hydrogel-elastomer hybrids with robust interfaces, high transparence, and biocompatibility for a mechanical-thermal multimode sensor", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The human skin, an important sensory organ, responds sensitively to external stimuli under various harsh conditions. However, the simultaneous achievement of mechanical/thermal sensitivity and extreme environmental tolerance remains an enormous challenge for skin-like hydrogel-based sensors. In this study, a novel skin-inspired hydrogel-elastomer hybrid with a sandwich structure and strong interfacial bonding for mechanical-thermal multimode sensing applications is developed. An inner-layered ionic hydrogel with a semi-interpenetrating network is prepared using sodium carboxymethyl cellulose (CMC) as a nullofiller, lithium chloride (LiCl) as an ionic transport conductor, and polyacrylamide (PAM) as a polymer matrix. The outer-layered polydimethylsiloxane (PDMS) elastomers fully encapsulating the hydrogel endow the hybrids with improved mechanical properties, intrinsic waterproofness, and long-term water retention (> 98%). The silane modification of the hydrogels and elastomers imparts the hybrids with enhanced interfacial bonding strength and integrity. The hybrids exhibit a high transmittance (similar to 91.2%), fatigue resistance, and biocompatibility. The multifunctional sensors assembled from the hybrids realize real-time temperature (temperature coefficient of resistance, approximately -1.1% degrees C-1) responsiveness, wide-range strain sensing capability (gauge factor, similar to 3.8) over a wide temperature range (from -20 degrees C to 60 degrees C), and underwater information transmission. Notably, the dual-parameter sensor can recognize the superimposed signals of temperature and strain. The designed prototype sensor arrays can detect the magnitude and spatial distribution of forces and temperatures. The comprehensive performance of the sensor prepared via a facile method is superior to that of most similar sensors previously reported. Finally, this study develops a new material platform for monitoring human health in extreme environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e12409", "DOI": "10.1002/inf2.12409", "DOI Link": "http://dx.doi.org/10.1002/inf2.12409", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939825100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Llinas, JP; Fairbrother, A; Barin, GB; Shi, W; Lee, K; Wu, S; Choi, BY; Braganza, R; Lear, J; Kau, N; Choi, W; Chen, C; Pedramrazi, Z; Dumslaff, T; Narita, A; Feng, XL; Müllen, K; Fischer, F; Zettl, A; Ruffieux, P; Yablonovitch, E; Crommie, M; Fasel, R; Bokor, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Llinas, Juan Pablo; Fairbrother, Andrew; Barin, Gabriela Borin; Shi, Wu; Lee, Kyunghoon; Wu, Shuang; Choi, Byung Yong; Braganza, Rohit; Lear, Jordan; Kau, Nicholas; Choi, Wonwoo; Chen, Chen; Pedramrazi, Zahra; Dumslaff, Tim; Narita, Akimitsu; Feng, Xinliang; Muellen, Klaus; Fischer, Felix; Zettl, Alex; Ruffieux, Pascal; Yablonovitch, Eli; Crommie, Michael; Fasel, Roman; Bokor, Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Short-channel field-effect transistors with 9-atom and 13-atom wide graphene nulloribbons", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bottom-up synthesized graphene nulloribbons and graphene nulloribbon heterostructures have promising electronic properties for high-performance field-effect transistors and ultr-alow power devices such as tunneling field-effect transistors. However, the short length and wide band gap of these graphene nulloribbons have prevented the fabrication of devices with the desired performance and switching behavior. Here, by fabricating short channel (L-ch similar to 20 nm) devices with a thin, high-kappa gate dielectric and a 9-atom wide (0.95 nm) armchair graphene nulloribbon as the channel material, we demonstrate field-effect transistors with high on-current (I-on > 1 mu A at V-d = -1 V) and high I-on/I-off similar to 10(5) at room temperature. We find that the performance of these devices is limited by tunneling through the Schottky barrier at the contacts and we observe an increase in the transparency of the barrier by increasing the gate field near the contacts. Our results thus demonstrate successful fabrication of high-performance short-channel field-effect transistors with bottom-up synthesized armchair graphene nulloribbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 633, "DOI": "10.1038/s41467-017-00734-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00734-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411416000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, H; Chen, N; Teng, HC; Yu, RW; Xue, MF; Chen, K; Xiao, YC; Qu, YP; Hu, DB; Chen, JN; Sun, ZP; Li, PN; de Abajo, FJ; Dai, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Hai; Chen, Na; Teng, Hanchao; Yu, Renwen; Xue, Mengfei; Chen, Ke; Xiao, Yuchuan; Qu, Yunpeng; Hu, Debo; Chen, Jianing; Sun, Zhipei; Li, Peining; Garcia de Abajo, F. Javier; Dai, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable negative refraction of mid-infrared polaritons", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Negative refraction provides a platform to manipulate mid-infrared and terahertz radiation for molecular sensing and thermal emission applications. However, its implementation based on metamaterials and plasmonic media presents challenges with optical losses, limited spatial confinement, and lack of active tunability in this spectral range. We demonstrate gate-tunable negative refraction at mid-infrared frequencies using hybrid topological polaritons in van der Waals heterostructures. Specifically, we visualize wide-angle negatively refracted polaritons in a-MoO3 films partially decorated with graphene, undergoing reversible planar nulloscale focusing. Our atomically thick heterostructures weaken scattering losses at the interface while enabling an actively tunable transition of normal to negative refraction through electrical gating. We propose polaritonic negative refraction as a promising platform for infrared applications such as electrically tunable super-resolution imaging, nulloscale thermal manipulation, enhanced molecular sensing, and on-chip optical circuitry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2023, "Volume": 379, "Issue": 6632, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 558, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.adf1251", "DOI Link": "http://dx.doi.org/10.1126/science.adf1251", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011102400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, XY; Cheng, ZX; Chen, ZB; Liu, Y; Meng, XY; Zhang, X; Wang, JL; Guo, QH; Li, B; Sun, HJ; Gu, QF; Hao, H; Shen, Q; Wu, JS; Liao, XZ; Ringer, SP; Liu, HX; Zhang, LM; Chen, W; Li, F; Zhang, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xiaoyi; Cheng, Zhenxiang; Chen, Zibin; Liu, Yao; Meng, Xiangyu; Zhang, Xu; Wang, Jianli; Guo, Qinghu; Li, Bei; Sun, Huajun; Gu, Qinfen; Hao, Hua; Shen, Qiang; Wu, Jinsong; Liao, Xiaozhou; Ringer, Simon P.; Liu, Hanxing; Zhang, Lianmeng; Chen, Wen; Li, Fei; Zhang, Shujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The mechanism for the enhanced piezoelectricity in multi-elements doped (K,Na)NbO3 ceramics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "(K,Na)NbO3 based ceramics are considered to be one of the most promising lead-free ferroelectrics replacing Pb(Zr,Ti)O-3. Despite extensive studies over the last two decades, the mechanism for the enhanced piezoelectricity in multi-elements doped (K,Na)NbO3 ceramics has not been fully understood. Here, we combine temperature-dependent synchrotron x-ray diffraction and property measurements, atomic-scale scanning transmission electron microscopy, and first-principle and phase-field calculations to establish the dopant-structure-property relationship for multi-elements doped (K,Na)NbO3 ceramics. Our results indicate that the dopants induced tetragonal phase and the accompanying high-density nulloscale heterostructures with low-angle polar vectors are responsible for the high dielectric and piezoelectric properties. This work explains the mechanism of the high piezoelectricity recently achieved in (K,Na)NbO3 ceramics and provides guidance for the design of high-performance ferroelectric ceramics, which is expected to benefit numerous functional materials. The mechanism for the enhanced piezoelectricity in (K,Na)NbO3 based ceramics has not been fully understood. Here, the authors find that the dopants induced tetragonal phase and the accompanying high-density nulloscale heterostructures are responsible for the high dielectric and piezoelectric properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 881, "DOI": "10.1038/s41467-021-21202-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21202-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620230000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xin, SS; Tang, Y; Jia, BH; Zhang, ZF; Li, CP; Bao, R; Li, CJ; Yi, JH; Wang, JS; Ma, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xin, Sisi; Tang, Yu; Jia, Baohua; Zhang, Zhengfu; Li, Chengping; Bao, Rui; Li, Caiju; Yi, Jianhong; Wang, Jinsong; Ma, Tianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling Adsorbed Evolution and Lattice Oxygen Mechanism in Fe-Co(OH)2/Fe2O3 Heterostructure for Enhanced Electrochemical Water Oxidation", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction (OER) remains a bottleneck for electrocatalytic water-splitting to generate hydrogen. However, the traditional adsorbed evolution mechanism (AEM) possesses sluggish reaction kinetics due to the scaling relationship, while lattice oxygen mechanism (LOM) triggers an unstable structure due to the escaping of lattice oxygen. Herein, a proof-of-concept Fe-Co(OH)(2)/Fe2O3 heterostructure is put forward, where Fe-Co(OH)(2) following AEM can complete rapidly deprotonation process while Fe2O3 following LOM can trigger OO coupling step. Combining the theoretical and experimental investigation confirmed that the redistributed space-charge of Fe-Co(OH)(2)/Fe2O3 junction can optimize synergistically adsorbed and lattice oxygen, the coupling mechanism of AEM and LOM can facilitate synchronously the OER activity and stability. As a result, the Fe-Co(OH)(2)/Fe2O3 heterostructure shows excellent OER performance with low overpotential of only 219 and 249 mV to reach a current density of 10 and 100 mA cm(-2). Specifically, the Fe-Co(OH)(2)/Fe2O3 electrocatalyst maintains excellent long-term stability for 100 h at a large current density of 100 mA cm(-2). This work paves an avenue to break through the limit of the conventional OER mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 33, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202305243", "DOI Link": "http://dx.doi.org/10.1002/adfm.202305243", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059827500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, MD; Wen, XR; Wang, MY; Iocozzia, J; Zhang, N; Lin, CJ; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Meidan; Wen, Xiaoru; Wang, Mengye; Iocozzia, James; Zhang, null; Lin, Changjian; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances in dye-sensitized solar cells: from photoanodes, sensitizers and electrolytes to counter electrodes", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dye-sensitized solar cells (DSSCs), as low-cost photovoltaic devices compared to conventional silicon solar cells, have received widespread attention in recent years; although much work is required to reach optimal device efficiencies. This review highlights recent developments in DSSCs and their key components, including the photoanode, sensitizer, electrolyte and counter electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 575, "Times Cited, All Databases": 578, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 18, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 155, "End Page": 162, "Article Number": null, "DOI": "10.1016/j.mattod.2014.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351057200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, K; Zhao, J; Zhussupbekova, A; Shuck, CE; Hughes, L; Dong, YY; Barwich, S; Vaesen, S; Shvets, I; Möbius, M; Schmitt, W; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ke; Zhao, Juan; Zhussupbekova, Ainur; Shuck, Christopher E.; Hughes, Lucia; Dong, Yueyao; Barwich, Sebastian; Vaesen, Sebastien; Shvets, Igor, V; Mobius, Matthias; Schmitt, Wolfgang; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4D printing of MXene hydrogels for high-efficiency pseudocapacitive energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D material hydrogels have recently sparked tremendous interest owing to their potential in diverse applications. However, research on the emerging 2D MXene hydrogels is still in its infancy. Herein, we show a universal 4D printing technology for manufacturing MXene hydrogels with customizable geometries, which suits a family of MXenes such as Nb2CTx, Ti3C2Tx, and Mo2Ti2C3Tx. The obtained MXene hydrogels offer 3D porous architectures, large specific surface areas, high electrical conductivities, and satisfying mechanical properties. Consequently, ultrahigh capacitance (3.32 F cm(-2) (10 mV s(-1)) and 233 F g(-1) (10 V s(-1))) and mass loading/thickness-independent rate capabilities are achieved. The further 4D-printed Ti3C2Tx hydrogel micro-supercapacitors showcase great low-temperature tolerance (down to -20 degrees C) and deliver high energy and power densities up to 93 mu Wh cm(-2) and 7 mW cm(-2), respectively, surpassing most state-of-the-art devices. This work brings new insights into MXene hydrogel manufacturing and expands the range of their potential applications. 2D MXene hydrogels are promising for diverse applications. Here, the authors report a universal 4D printing technology to manufacture MXene hydrogels with customizable geometry, high conductivity, and efficient pseudocapacitive energy storage ability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6884, "DOI": "10.1038/s41467-022-34583-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-34583-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000882468500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mueller, DN; Machala, ML; Bluhm, H; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mueller, David N.; Machala, Michael L.; Bluhm, Hendrik; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox activity of surface oxygen anions in oxygen-deficient perovskite oxides during electrochemical reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface redox-active centres in transition-metal oxides play a key role in determining the efficacy of electrocatalysts. The extreme sensitivity of surface redox states to temperatures, to gas pressures and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Here we report the direct observation of surface redox processes by surface-sensitive, operando X-ray absorption spectroscopy using thin-film iron and cobalt perovskite oxides as model electrodes for elevated-temperature oxygen incorporation and evolution reactions. In contrast to the conventional view that the transition metal cations are the dominullt redox-active centres, we find that the oxygen anions near the surface are a significant redox partner to molecular oxygen due to the strong hybridization between oxygen 2p and transition metal 3d electronic states. We propose that a narrow electronic state of significant oxygen 2p character near the Fermi level exchanges electrons with the oxygen adsorbates. This result highlights the importance of surface anion-redox chemistry in oxygen-deficient transition-metal oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6097, "DOI": "10.1038/ncomms7097", "DOI Link": "http://dx.doi.org/10.1038/ncomms7097", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351857300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sotor, J; Sobon, G; Macherzynski, W; Paletko, P; Abramski, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sotor, J.; Sobon, G.; Macherzynski, W.; Paletko, P.; Abramski, K. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black phosphorus saturable absorber for ultrashort pulse generation", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-dimensional materials, due to their unique and versatile properties, are very interesting for numerous applications in electronics and optoelectronics. Recently rediscovered black phosphorus, with a graphite-like layered structure, can be effectively exfoliated up to the single atomic layer called phosphorene. Contrary to graphene, it possesses a direct band gap controllable by the number of stacked atomic layers. For those reasons, black phosphorus is now intensively investigated and can complement or replace graphene in various photonics and electronics applications. Here, we demonstrate that black phosphorus can serve as a broadband saturable absorber and can be used for ultrashort optical pulse generation. The mechanically exfoliated similar to 300 nm thick layers of black phosphorus were transferred onto the fiber core, and under pulsed excitation at 1560 nm wavelength, its transmission increases by 4.6%. We have demonstrated that the saturable absorption of black phosphorus is polarization sensitive. The fabricated device was used to mode-lock an Er-doped fiber laser. The generated optical solitons with the 10.2 nm bandwidth and 272 fs duration were centered at 1550 nm. The obtained results unambiguously show that black phosphorus can be effectively used for ultrashort pulse generation with performances similar or even better than currently used graphene or carbon nullotubes. This application of black phosphorus proves its great potential to future practical use in photonics. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2015, "Volume": 107, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 51108, "DOI": "10.1063/1.4927673", "DOI Link": "http://dx.doi.org/10.1063/1.4927673", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359375700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, G; Hu, M; Xu, XT; Alothman, AA; Mushab, MSS; Ma, SJ; Shen, PK; Zhu, JL; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Guo; Hu, Miao; Xu, Xingtao; Alothman, Asma A.; Mushab, Mohammed Sheikh Saleh; Ma, Shaojian; Shen, Pei Kang; Zhu, Jinliang; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimizing Heterointerface of Co2P-CoxOy nulloparticles within a Porous Carbon Network for Deciphering Superior Water Splitting", "Source Title": "SMALL STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of great significance to design a bifunctional electrocatalyst for promoting hydrogen (HER) and oxygen (OER) evolution reactions simultaneously. Herein, inspired by the appropriate H atom binding energy on cobalt phosphides and excellent oxygen evolution kinetics on cobalt oxides, the regulative synthesis of a Co2P-CoxOy (CoxOy = CoO or Co3O4) heterogeneous nulloparticle-anchored porous carbon network electrocatalyst via one-pot heat treatment is reported. The as-synthesized Co2P-Co3O4/C exhibits superior electrochemical activity with low overpotentials of 86 mV for HER and 246 mV for OER at 10 mA cm(-2) in an alkaline electrolyte. Moreover, compared to the commercial Pt/C || RuO2/C system, the Co2P-Co3O4/C || Co2P-Co3O4/C system presents outstanding activity toward overall water splitting (1.55 V@10 mA cm(-2)), which is well maintained over long-term (120 h) electrocatalysis. Density functional theory calculations show that the rich interfaces between Co2P and Co3O4 offer a synergistic effect, which enables Co2P-Co3O4/C as an excellent electrocatalyst toward both HER and OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/sstr.202200235", "DOI Link": "http://dx.doi.org/10.1002/sstr.202200235", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000907346400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ilyas, RA; Zuhri, MYM; Norrrahim, MNF; Misenull, MSM; Jenol, MA; Samsudin, SA; Nurazzi, NM; Asyraf, MRM; Supian, ABM; Bangar, SP; Nadlene, R; Sharma, S; Omran, AAB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ilyas, R. A.; Zuhri, M. Y. M.; Norrrahim, Mohd Nor Faiz; Misenull, Muhammad Syukri Mohamad; Jenol, Mohd Azwan; Samsudin, Sani Amril; Nurazzi, N. M.; Asyraf, M. R. M.; Supian, A. B. M.; Bangar, Sneh Punia; Nadlene, R.; Sharma, Shubham; Omran, Abdoulhdi A. Borhana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural Fiber-Reinforced Polycaprolactone Green and Hybrid Biocomposites for Various Advanced Applications", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent developments within the topic of biomaterials has taken hold of researchers due to the mounting concern of current environmental pollution as well as scarcity resources. Amongst all compatible biomaterials, polycaprolactone (PCL) is deemed to be a great potential biomaterial, especially to the tissue engineering sector, due to its advantages, including its biocompatibility and low bioactivity exhibition. The commercialization of PCL is deemed as infant technology despite of all its advantages. This contributed to the disadvantages of PCL, including expensive, toxic, and complex. Therefore, the shift towards the utilization of PCL as an alternative biomaterial in the development of biocomposites has been exponentially increased in recent years. PCL-based biocomposites are unique and versatile technology equipped with several importance features. In addition, the understanding on the properties of PCL and its blend is vital as it is influenced by the application of biocomposites. The superior characteristics of PCL-based green and hybrid biocomposites has expanded their applications, such as in the biomedical field, as well as in tissue engineering and medical implants. Thus, this review is aimed to critically discuss the characteristics of PCL-based biocomposites, which cover each mechanical and thermal properties and their importance towards several applications. The emergence of nullomaterials as reinforcement agent in PCL-based biocomposites was also a tackled issue within this review. On the whole, recent developments of PCL as a potential biomaterial in recent applications is reviewed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 182, "DOI": "10.3390/polym14010182", "DOI Link": "http://dx.doi.org/10.3390/polym14010182", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741317600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, F; Chen, Z; Li, JF; Wu, R; Zhang, B; Nie, GH; Xie, ZJ; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Fei; Chen, Zhi; Li, Jingfeng; Wu, Rui; Zhang, Bin; Nie, Guohui; Xie, Zhongjian; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Sensitive CRISPR-Empowered Surface Plasmon Resonullce Sensor for Diagnosis of Inherited Diseases with Femtomolar-Level Real-Time Quantification", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The clustered regularly interspaced short palindromic repeats (CRISPR) molecular system has emerged as a promising technology for the detection of nucleic acids. Herein, the development of a surface plasmon resonullce (SPR) sensor that is functionalized with a layer of locally grown graphdiyne film, achieving excellent sensing performance when coupled with catalytically deactivated CRISPR-associated protein 9 (dCas9), is reported. dCas9 protein is immobilized on the sensor surface and complexed with a specific single-guide RNA, enabling the amplification-free detection of target sequences within genomic DNA. The sensor, termed CRISPR-SPR-Chip, is used to successfully analyze recombinullt plasmids with only three-base mutations with a limit of detection as low as 1.3 fM. Real-time monitoring CRISPR-SPR-Chip is used to analyze clinical samples of patients with Duchenne muscular dystrophy with two exon deletions, which are detected without any pre-amplification step, yielding significantly positive results within 5 min. The ability of this novel CRISPR-empowered SPR (CRISPR-eSPR) sensing platform to rapidly, precisely, sensitively, and specifically detect a target gene sequence provides a new on-chip optic approach for clinical gene analysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105231, "DOI": "10.1002/advs.202105231", "DOI Link": "http://dx.doi.org/10.1002/advs.202105231", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773413600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, HY; Yu, Y; Wang, XL; Luo, Y; Zu, S; Du, BW; Han, TY; Li, BW; Li, Y; Wu, JR; Lin, F; Shi, KB; Tay, BK; Liu, Z; Zhu, X; Fang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Hangyong; Yu, Ying; Wang, Xingli; Luo, Yang; Zu, Shuai; Du, Bowen; Han, Tianyang; Li, Bowen; Li, Yu; Wu, Jiarui; Lin, Feng; Shi, Kebin; Tay, Beng Kang; Liu, Zheng; Zhu, Xing; Fang, Zheyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of ultrafast plasmonic hot electron transfer in the strong coupling regime", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving strong coupling between plasmonic oscillators can significantly modulate their intrinsic optical properties. Here, we report the direct observation of ultrafast plasmonic hot electron transfer from an Au grating array to an MoS2 monolayer in the strong coupling regime between localized surface plasmons (LSPs) and surface plasmon polaritons (SPPs). By means of femtosecond pump-probe spectroscopy, the measured hot electron transfer time is approximately 40 fs with a maximum external quantum yield of 1.65%. Our results suggest that strong coupling between LSPs and SPPs has synergetic effects on the generation of plasmonic hot carriers, where SPPs with a unique nonradiative feature can act as an 'energy recycle bin' to reuse the radiative energy of LSPs and contribute to hot carrier generation. Coherent energy exchange between plasmonic modes in the strong coupling regime can further enhance the vertical electric field and promote the transfer of hot electrons between the Au grating and the MoS2 monolayer. Our proposed plasmonic strong coupling configuration overcomes the challenge associated with utilizing hot carriers and is instructive in terms of improving the performance of plasmonic opto-electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9, "DOI": "10.1038/s41377-019-0121-6", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0121-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456399500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JY; Mahajan, A; Riekehr, L; Zhang, HF; Yang, B; Meng, N; Zhang, Z; Yan, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jiyue; Mahajan, Amit; Riekehr, Lars; Zhang, Hangfeng; Yang, Bin; Meng, null; Zhang, Zhen; Yan, Haixue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite Srx(Bi1-xNa0.97-xLi0.03)0.5TiO3 ceramics with polar nullo regions for high power energy storage", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors are very attractive for high power energy storage. However, the low energy density of these capacitors, which is mainly limited by the dielectric materials, is still the bottleneck for their applications. In this work, lead-free single-phase perovskite Srx(Bi1-xNa0.97-xLi0.03)(0.5)TiO3 (x = 0.30 and 0.38) bulk ceramics, prepared using solid-state reaction method, were carefully studied for the dielectric capacitor application. Polar nullo regions (PNRs) were created in this material using co-substitution at A-site to enable relaxor behaviour with low remnullt polarization (P-r) and high maximum polarization (P-max). Moreover, P-max was further increased due to the electric field induced reversible phase transitions in nullo regions. Comprehensive structural and electrical studies were performed to confirm the PNRs and reversible phase transitions. And finally a high energy density (1.70 J/cm(3)) with an excellent efficiency (87.2%) was achieved using the contribution of field-induced rotations of PNRs and PNR-related reversible transitions in this material, making it among the best performing lead-free dielectric ceramic bulk material for high energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 723, "End Page": 732, "Article Number": null, "DOI": "10.1016/j.nulloen.2018.06.016", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2018.06.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438076200084", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Laronda, MM; Rutz, AL; Xiao, S; Whelan, KA; Duncan, FE; Roth, EW; Woodruff, TK; Shah, RN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Laronda, Monica M.; Rutz, Alexandra L.; Xiao, Shuo; Whelan, Kelly A.; Duncan, Francesca E.; Roth, Eric W.; Woodruff, Teresa K.; Shah, Ramille N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A bioprosthetic ovary created using 3D printed microporous scaffolds restores ovarian function in sterilized mice", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emerging additive manufacturing techniques enable investigation of the effects of pore geometry on cell behavior and function. Here, we 3D print microporous hydrogel scaffolds to test how varying pore geometry, accomplished by manipulating the advancing angle between printed layers, affects the survival of ovarian follicles. 30 degrees and 60 degrees scaffolds provide corners that surround follicles on multiple sides while 90 degrees scaffolds have an open porosity that limits follicle-scaffold interaction. As the amount of scaffold interaction increases, follicle spreading is limited and survival increases. Follicle-seeded scaffolds become highly vascularized and ovarian function is fully restored when implanted in surgically sterilized mice. Moreover, pups are born through natural mating and thrive through maternal lactation. These findings present an in vivo functional ovarian implant designed with 3D printing, and indicate that scaffold pore architecture is a critical variable in additively manufactured scaffold design for functional tissue engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15261, "DOI": "10.1038/ncomms15261", "DOI Link": "http://dx.doi.org/10.1038/ncomms15261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401348300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Heinemann, SH; Hoshi, T; Westerhausen, M; Schiller, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Heinemann, Stefan H.; Hoshi, Toshinori; Westerhausen, Matthias; Schiller, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon monoxide - physiology, detection and controlled release", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon monoxide (CO) is increasingly recognized as a cell-signalling molecule akin to nitric oxide (NO). CO has attracted particular attention as a potential therapeutic agent because of its reported antihypertensive, anti-inflammatory and cell-protective effects. We discuss recent progress in identifying new effector systems and elucidating the mechanisms of action of CO on, e. g., ion channels, as well as the design of novel methods to monitor CO in cellular environments. We also report on recent developments in the area of CO-releasing molecules (CORMs) and materials for controlled CO application. Novel triggers for CO release, metal carbonyls and degradation mechanisms of CORMs are highlighted. In addition, potential formulations of CORMs for targeted CO release are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 50, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3644, "End Page": 3660, "Article Number": null, "DOI": "10.1039/c3cc49196j", "DOI Link": "http://dx.doi.org/10.1039/c3cc49196j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332927500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Banszerus, L; Schmitz, M; Engels, S; Dauber, J; Oellers, M; Haupt, F; Watanabe, K; Taniguchi, T; Beschoten, B; Stampfer, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Banszerus, Luca; Schmitz, Michael; Engels, Stephan; Dauber, Jan; Oellers, Martin; Haupt, Federica; Watanabe, Kenji; Taniguchi, Takashi; Beschoten, Bernd; Stampfer, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-mobility graphene devices from chemical vapor deposition on reusable copper", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene research has prospered impressively in the past few years, and promising applications such as highfrequency transistors, magnetic field sensors, and flexible optoelectronics are just waiting for a scalable and costefficient fabrication technology to produce high-mobility graphene. Although significant progress has been made in chemical vapor deposition (CVD) and epitaxial growth of graphene, the carrier mobility obtained with these techniques is still significantly lower than what is achieved using exfoliated graphene. We show that the quality of CVD-grown graphene depends critically on the used transfer process, and we report on an advanced transfer technique that allows both reusing the copper substrate of the CVD growth and making devices with mobilities as high as 350,000 cm(2) V-1 s(-1), thus rivaling exfoliated graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 744, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 1, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500222", "DOI": "10.1126/sciadv.1500222", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500222", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216595400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Luo, FF; Kao, TS; Li, X; Ho, GW; Teng, JH; Luo, XG; Hong, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jing; Luo, Fangfang; Kao, Tsung Sheng; Li, Xiong; Ho, Ghim Wei; Teng, Jinghua; Luo, Xiangang; Hong, Minghui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and fabrication of broadband ultralow reflectivity black Si surfaces by laser micro/nulloprocessing", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light collection efficiency is an important factor that affects the performance of many optical and optoelectronic devices. In these devices, the high reflectivity of interfaces can hinder efficient light collection. To minimize unwanted reflection, anti-reflection surfaces can be fabricated by micro/nullopatterning. In this paper, we investigate the fabrication of broadband anti-reflection Si surfaces by laser micro/nulloprocessing. Laser direct writing is applied to create microstructures on Si surfaces that reduce light reflection by light trapping. In addition, laser interference lithography and metal assisted chemical etching are adopted to fabricate the Si nullowire arrays. The anti-reflection performance is greatly improved by the high aspect ratio subwavelength structures, which create gradients of refractive index from the ambient air to the substrate. Furthermore, by decoration of the Si nullowires with metallic nulloparticles, surface plasmon resonullce can be used to further control the broadband reflections, reducing the reflection to below 1.0% across from 300 to 1200 nm. An average reflection of 0.8% is achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 3, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e185", "DOI": "10.1038/lsa.2014.66", "DOI Link": "http://dx.doi.org/10.1038/lsa.2014.66", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345187300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Li, C; Tan, CH; Pei, ZX; Yang, T; Zhang, SZ; Huang, QW; Wang, YH; Zhou, Z; Liao, XZ; Dong, JC; Tan, H; Yan, WS; Yin, HJ; Liu, ZQ; Huang, J; Zhao, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yangyang; Li, Can; Tan, Chunhui; Pei, Zengxia; Yang, Tao; Zhang, Shuzhen; Huang, Qianwei; Wang, Yihan; Zhou, Zheng; Liao, Xiaozhou; Dong, Juncai; Tan, Hao; Yan, Wensheng; Yin, Huajie; Liu, Zhao-Qing; Huang, Jun; Zhao, Shenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrosynthesis of chlorine from seawater-like solution through single-atom catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The chlor-alkali process plays an essential and irreplaceable role in the modern chemical industry due to the wide-ranging applications of chlorine gas. However, the large overpotential and low selectivity of current chlorine evolution reaction (CER) electrocatalysts result in significant energy consumption during chlorine production. Herein, we report a highly active oxygen-coordinated ruthenium single-atom catalyst for the electrosynthesis of chlorine in seawater-like solutions. As a result, the as-prepared single-atom catalyst with Ru-O-4 moiety (Ru-O-4 SAM) exhibits an overpotential of only similar to 30 mV to achieve a current density of 10mA cm(-2) in an acidic medium (pH = 1) containing 1M NaCl. Impressively, the flow cell equipped with Ru-O-4 SAM electrode displays excellent stability and Cl-2 selectivity over 1000 h continuous electrocatalysis at a high current density of 1000mA cm(-2). Operando characterizations and computational analysis reveal that compared with the benchmark RuO2 electrode, chloride ions preferentially adsorb directly onto the surface of Ru atoms on Ru-O-4 SAM, thereby leading to a reduction in Gibbs free-energy barrier and an improvement in Cl-2 selectivity during CER. This finding not only offers fundamental insights into the mechanisms of electrocatalysis but also provides a promising avenue for the electrochemical synthesis of chlorine from seawater electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2475, "DOI": "10.1038/s41467-023-38129-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38129-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022903400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Osada, M; Wang, BY; Goodge, BH; Harvey, SP; Lee, KH; Li, DF; Kourkoutis, LF; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Osada, Motoki; Wang, Bai Yang; Goodge, Berit H.; Harvey, Shannon P.; Lee, Kyuho; Li, Danfeng; Kourkoutis, Lena F.; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickelate Superconductivity without Rare-Earth Magnetism: (La,Sr)NiO2", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The occurrence of unconventional superconductivity in cuprates has long motivated the search for manifestations in other layered transition metal oxides. Recently, superconductivity is found in infinite-layer nickelate (Nd,Sr)NiO2 and (Pr,Sr)NiO2 thin films, formed by topotactic reduction from the perovskite precursor phase. A topic of much current interest is whether rare-earth moments are essential for superconductivity in this system. In this study, it is found that with significant materials optimization, substantial portions of the La1-xSrxNiO2 phase diagram can enter the regime of coherent low-temperature transport (x = 0.14 - 0.20), with subsequent superconducting transitions and a maximum onset of approximate to 9 K at x = 0.20. Additionally, the unexpected indication of a superconducting ground state in undoped LaNiO2 is observed, which likely reflects the self-doped nature of the electronic structure. Combining the results of (La/Pr/Nd)(1-)xSrxNiO2 reveals a generalized superconducting dome, characterized by systematic shifts in the unit cell volume and in the relative electron-hole populations across the lanthanides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 33, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104083, "DOI": "10.1002/adma.202104083", "DOI Link": "http://dx.doi.org/10.1002/adma.202104083", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696901900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brasch, V; Geiselmann, M; Herr, T; Lihachev, G; Pfeiffer, MHP; Gorodetsky, ML; Kippenberg, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brasch, V.; Geiselmann, M.; Herr, T.; Lihachev, G.; Pfeiffer, M. H. P.; Gorodetsky, M. L.; Kippenberg, T. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonic chip-based optical frequency comb using soliton Cherenkov radiation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical solitons are propagating pulses of light that retain their shape because nonlinearity and dispersion balance each other. In the presence of higher-order dispersion, optical solitons can emit dispersive waves via the process of soliton Cherenkov radiation. This process underlies supercontinuum generation and is of critical importance in frequency metrology. Using a continuous wave-pumped, dispersion-engineered, integrated silicon nitride microresonator, we generated continuously circulating temporal dissipative Kerr solitons. The presence of higher-order dispersion led to the emission of red-shifted soliton Cherenkov radiation. The output corresponds to a fully coherent optical frequency comb that spans two-thirds of an octave and whose phase we were able to stabilize to the sub-Hertz level. By preserving coherence over a broad spectral bandwidth, our device offers the opportunity to develop compact on-chip frequency combs for frequency metrology or spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 636, "Times Cited, All Databases": 723, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2016, "Volume": 351, "Issue": 6271, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 357, "End Page": 360, "Article Number": null, "DOI": "10.1126/science.aad4811", "DOI Link": "http://dx.doi.org/10.1126/science.aad4811", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368440500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kong, HJ; Chu, Q; Fang, C; Cao, GD; Han, GR; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kong, Hanjing; Chu, Qiang; Fang, Chao; Cao, Guodong; Han, Gaorong; Li, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cu-Ferrocene-Functionalized CaO2 nulloparticles to Enable Tumor-Specific Synergistic Therapy with GSH Depletion and Calcium Overload", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion of endogenous H2O2 into toxic hydroxyl radical ((OH)-O-center dot) via catalytic nulloparticles is explored for tumor therapy and received considerable success. The intrinsic characteristics of microenvironment in tumor cells, such as limited H2O2 and overexpressed glutathione (GSH), hinder the intracellular (OH)-O-center dot accumulation and thus weaken therapeutic efficacy considerably. In this study, fine CaO2 nulloparticles with Cu-ferrocene molecules at the surface (CaO2/Cu-ferrocene) are successfully designed and synthesized. Under an acidic condition, the particles release Ca2+ ions and H2O2 in a rapid fashion, while they can remain stable in neutral. In addition, agitated production of (OH)-O-center dot occurs following the Fenton reaction of H2O2 and ferrocene molecules, and GSH is consumed by Cu2+ ions to avoid the potential (OH)-O-center dot consumption. More interestingly, in addition to the exogenous Ca2+ released by the particles, the enhanced (OH)-O-center dot production facilitates intracellular calcium accumulation by regulating Ca2+ channels and pumps of tumor cells. It turns out that promoted (OH)-O-center dot induction and intracellular calcium overload enable significant in vitro and in vivo antitumor phenomena.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100241, "DOI": "10.1002/advs.202100241", "DOI Link": "http://dx.doi.org/10.1002/advs.202100241", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653526900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, Y; Mao, Z; Wang, Y; Pan, C; Ou, MT; Zhang, HJ; Zeng, WW; Ji, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Yong; Mao, Zhuo; Wang, Ying; Pan, Chao; Ou, Meitong; Zhang, Hanjie; Zeng, Weiwei; Ji, Xiaoyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of a two-dimensional interplanar heterojunction for catalytic cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemodynamic therapy relies on Fenton or Fenton-like reactions to produce hydroxyl radical in the tumor region. Here the authors design a two-dimensional interplanar heterojunction with in situ hydroxyl radical generation under ultrasound irradiation, showing anti-cancer activity in preclinical models. Limited substrates content is a major hurdle dampening the antitumor effect of catalytic therapy. Herein, a two-dimensional interplanar heterojunction (FeOCl/FeOOH NSs) with center dot OH generation under ultrasound irradiation is fabricated and utilized for catalytic cancer therapy. This interplanar heterojunction is prepared through replacing chlorine from iron oxychloride with hydroxyl. Benefiting from the longer hydroxyl bond length and enhanced affinity with water, the alkali replacement treatment integrates interplanar heterojunction synthesis and exfoliation in one step. In particular, a build-in electric field facilitated Z-scheme interplanar heterojunction is formed due to the aligning Fermi levels. The holes on the valence band of FeOCl have great ability to catalyze O-2 evolution from H2O, meanwhile, the generated O-2 is immediately and directly reduced to H2O2 by the electrons on the conductive band of FeOOH. The self-supplying H2O2 ability guarantees efficient center dot OH generation via the Fenton-like reaction catalyzed by FeOCl/FeOOH NSs, which exhibits excellent anti-tumor performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2425, "DOI": "10.1038/s41467-022-30166-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30166-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790385800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shaikh, S; Yaqoob, M; Aggarwal, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shaikh, Salman; Yaqoob, Mudasir; Aggarwal, Poonam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An overview of biodegradable packaging in food industry", "Source Title": "CURRENT RESEARCH IN FOOD SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For many years, conventional plastics are manufactured and used for packaging applications in different sectors. As the food industries are increasing, the demand for packaging material is also increasing. Plastics have transformed the food industry to higher levels; however, conventional petroleum-based plastics are nondegradable which has created severe ecological problems to the environment like a threat to aquatic life and degrading air quality. Biodegradable polymers or biopolymers emerged as an alternative approach for many industrial applications to control the risk caused by non-biodegradable plastic. According to the type of starting material, they have been categorized as polymers extracted from biomass, synthesized from monomers, and produced from microorganisms. The quality of biopolymers depends on the physical, mechanical, thermal, and barrier properties. The present review highlights the characteristics of various biopolymers and their blends, comparison of properties between non-biodegradable and biopolymers, the market potential for food packaging applications. The review also emphasizes different commercial forms like films, trays, bags, coatings, and foamed products for application as modified atmosphere packaging, active packaging, and edible packaging. Different issues affecting market growth like harmful products formed during production and consumer perception have also been discussed. Information on biopolymers is widely scattered over many sources, this article aims to provide an overview of biodegradable polymer packages for food applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2021, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 503, "End Page": 520, "Article Number": null, "DOI": "10.1016/j.crfs.2021.07.005", "DOI Link": "http://dx.doi.org/10.1016/j.crfs.2021.07.005", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731150300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, LK; Cui, X; Wang, ZW; Sewell, CD; Li, ZL; Liang, S; Zhang, MY; Li, J; Hu, YJ; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Likun; Cui, Xun; Wang, Zewei; Sewell, Christopher D.; Li, Zili; Liang, Shuang; Zhang, Mingyue; Li, Jian; Hu, Yingjie; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando unraveling photothermal-promoted dynamic active-sites generation in NiFe2O4 for markedly enhanced oxygen evolution", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to develop highly active and low-cost electrocatalysts represents an important endeavor toward accelerating sluggish water-oxidation kinetics. Herein, we report the implementation and unraveling of the photothermal effect of spinel nulloparticles (NPs) on promoting dynamic active-sites generation to markedly enhance their oxygen evolution reaction (OER) activity via an integrated operando Raman and density functional theory (DFT) study. Specifically, NiFe2O4 (NFO) NPs are first synthesized by capitalizing on amphiphilic star-like diblock copolymers as nulloreactors. Upon the near-infrared light irradiation, the photothermal heating of the NFO-based electrode progressively raises the temperature, accompanied by a marked decrease of overpotential. Accordingly, only an overpotential of 309 mV is required to yield a high current density of 100 mA cm(-2), greatly lower than recently reported earth-abundant electrocatalysts. More importantly, the photothermal effect of NFO NPs facilitates surface reconstruction into high-active oxyhydroxides at lower potential (1.36 V) under OER conditions, as revealed by operando Raman spectroelectro-chemistry. The DFT calculation corroborates that these reconstructed (Ni,Fe)oxyhydroxides are electrocatalytically active sites as the kinetics barrier is largely reduced over pure NFO without surface reconstruction. Given the diversity of materials (metal oxides, sulfides, phosphides, etc.) possessing the photo-to-thermal conversion, this effect may thus provide a unique and robust platform to boost highly active surface species in nullomaterials for a fundamental understanding of enhanced performance that may underpin future advances in electrocatalysis, photocatalysis, solar-energy conversion, and renewable-energy production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2021, "Volume": 118, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2023421118", "DOI": "10.1073/pnas.2023421118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2023421118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621748600059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sutherland, BR; Johnston, AK; Ip, AH; Xu, JX; Adinolfi, V; Kanjanaboos, P; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sutherland, Brandon R.; Johnston, Andrew K.; Ip, Alexander H.; Xu, Jixian; Adinolfi, Valerio; Kanjanaboos, Pongsakorn; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive, Fast, and Stable Perovskite Photodetectors Exploiting Interface Engineering", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometallic halide perovskites are a class of solution-processed semiconductors exhibiting remarkable optoelectronic properties. They have seen rapid strides toward enabling efficient third-generation solar cell technologies. Here, we report the first material-tailoring of TiO2/perovskite/spiro-OMeTAD junction-based photodiodes toward applications in photodetection, a field in need of fast, sensitive, low-cost, spectrally tunable materials that offer facile integration across a broad range of substrates. We report photodetection that exhibits 1 its temporal response, and we showcase stable operation in the detection of over 7 billion transient light pulses through a continuous pulsed-illumination period. The perovskite diode photodetector has a peak responsivity approaching 0.4 A W-1 at 600 nm wavelength, which is superior to red light detection in crystalline silicon photodiodes used in commercial image sensors. Only by developing a composite Al2O3/PCBM front contact interface layer were we able to stabilize device operation in air, reduce dark current, and enhance the responsivity in the low-bias regime to achieve an experimentally measured specific detectivity of 10(12) Jones.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1117, "End Page": 1123, "Article Number": null, "DOI": "10.1021/acsphotonics.5b00164", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.5b00164", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359967400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Sun, JF; Mao, J; Zhu, HT; Ren, WY; Zhou, JC; Wang, ZM; Singh, DJ; Sui, JH; Chu, CW; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zihang; Sun, Jifeng; Mao, Jun; Zhu, Hangtian; Ren, Wuyang; Zhou, Jingchao; Wang, Zhiming; Singh, David J.; Sui, Jiehe; Chu, Ching-Wu; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-transition temperature suppression to achieve cubic GeTe and high thermoelectric performance by Bi and Mn codoping", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Germanium telluride (GeTe)-based materials, which display intriguing functionalities, have been intensively studied from both fundamental and technological perspectives. As a thermoelectric material, though, the phase transition in GeTe from a rhombohedral structure to a cubic structure at similar to 700 K is a major obstacle impeding applications for energy harvesting. In this work, we discovered that the phase-transition temperature can be suppressed to below 300 K by a simple Bi and Mn codoping, resulting in the high performance of cubic GeTe from 300 to 773 K. Bi doping on the Ge site was found to reduce the hole concentration and thus to enhance the thermoelectric properties. Mn alloying on the Ge site simultaneously increased the hole effective mass and the Seebeck coefficient through modification of the valence bands. With the Bi and Mn codoping, the lattice thermal conductivity was also largely reduced due to the strong point-defect scattering for phonons, resulting in a peak thermoelectric figure of merit (ZT) of similar to 1.5 at 773 K and an average ZT of similar to 1.1 from 300 to 773 K in cubic Ge0.81Mn0.15Bi0.04Te. Our results open the door for further studies of this exciting material for thermoelectric and other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2018, "Volume": 115, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5332, "End Page": 5337, "Article Number": null, "DOI": "10.1073/pnas.1802020115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1802020115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432663000036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Higashitarumizu, N; Kawamoto, H; Lee, CJ; Lin, BH; Chu, FH; Yonemori, I; Nishimura, T; Wakabayashi, K; Chang, WH; Nagashio, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Higashitarumizu, Naoki; Kawamoto, Hayami; Lee, Chien-Ju; Lin, Bo-Han; Chu, Fu-Hsien; Yonemori, Itsuki; Nishimura, Tomonori; Wakabayashi, Katsunori; Chang, Wen-Hao; Nagashio, Kosuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Purely in-plane ferroelectricity in monolayer SnS at room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D van der Waals ferroelectrics have emerged as an attractive building block with immense potential to provide multifunctionality in nulloelectronics. Although several accomplishments have been reported in ferroelectric switching for out-of-plane ferroelectrics down to the monolayer, a purely in-plane ferroelectric has not been experimentally validated at the monolayer thickness. Herein, an in-plane ferroelectricity is demonstrated for micrometer-size monolayer SnS at room temperature. SnS has been commonly regarded to exhibit the odd-even effect, where the centrosymmetry breaks only in the odd-number layers to exhibit ferroelectricity. Remarkably, however, a robust room temperature ferroelectricity exists in SnS below a critical thickness of 15 layers with both an odd and even number of layers, suggesting the possibility of controlling the stacking sequence of multilayer SnS beyond the limit of ferroelectricity in the monolayer. This work will pave the way for nulloscale ferroelectric applications based on SnS as a platform for in-plane ferroelectrics. Out-of-plane ferroelectricity is usually unstable in the two dimensional limit due to the presence of the depolarization field. Here, the authors successfully circumvent this issue by growing mu m-sized SnS monolayers that exhibit in-plane ferroelectricity that is stable at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2428, "DOI": "10.1038/s41467-020-16291-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16291-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Zhou, YY; Zhou, YT; Wang, K; Yun, Y; Chen, SY; Jiao, WT; Chen, L; Zou, B; Zhu, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhi; Zhou, Yuanyi; Zhou, Yingtang; Wang, Kai; Yun, Yang; Chen, Shanyong; Jiao, Wentao; Chen, Li; Zou, Bo; Zhu, Mingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dipole field in nitrogen-enriched carbon nitride with external forces to boost the artificial photosynthesis of hydrogen peroxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis is a promising strategy for efficient hydrogen peroxide production, but the poor directional charge transfer from bulk to active sites restricts the overall photocatalytic efficiency. To address this, a new process of dipole field-driven spontaneous polarization in nitrogen-rich triazole-based carbon nitride (C3N5) to harness photogenerated charge kinetics for hydrogen peroxide production is constructed. Here, C3N5 achieves a hydrogen peroxide photosynthesis rate of 3809.5 & mu;mol g-1 h-1 and a 2e- transfer selectivity of 92% under simulated sunlight and ultrasonic forces. This high performance is attributed to the introduction of rich nitrogen active sites of the triazole ring in C3N5, which brings a dipole field. This dipole field induces a spontaneous polarization field to accelerate a rapid directional electron transfer process to nitrogen active sites and therefore induces Pauling-type adsorption of oxygen through an indirect 2e- transfer pathway to form hydrogen peroxide. This innovative concept using a dipole field to harness the migration and transport of photogenerated carriers provides a new route to improve photosynthesis efficiency via structural engineering. The poor directional charge transfer from bulk to active sites restricts the overall photocatalytic efficiency. Here, the authors report a new process of dipole field-driven spontaneous polarization in nitrogen-rich triazole-based carbon nitride to harness photogenerated charge kinetics for hydrogen peroxide production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5742, "DOI": "10.1038/s41467-023-41522-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41522-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001068915700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ST; Li, ZZ; Zhu, CY; Yang, W; Zhang, ZR; Armstrong, DEJ; Grant, PS; Ritchie, RO; Meyers, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Shiteng; Li, Zezhou; Zhu, Chaoyi; Yang, Wen; Zhang, Zhouran; Armstrong, David E. J.; Grant, Patrick S.; Ritchie, Robert O.; Meyers, Marc A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphization in extreme deformation of the CrMnFeCoNi high-entropy alloy", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ever-harsher service conditions in the future will call for materials with increasing ability to undergo deformation without sustaining damage while retaining high strength. Prime candidates for these conditions are certain high-entropy alloys (HEAs), which have extraordinary work-hardening ability and toughness. By subjecting the equiatomic CrMnFeCoNi HEA to severe plastic deformation through swaging followed by either quasi-static compression or dynamic deformation in shear, we observe a dense structure comprising stacking faults, twins, transformation from the face-centered cubic to the hexagonal close-packed structure, and, of particular note, amorphization. The coordinated propagation of stacking faults and twins along {111} planes generates high-deformation regions, which can reorganize into hexagonal packets; when the defect density in these regions reaches a critical level, they generate islands of amorphous material. These regions can have outstanding mechanical properties, which provide additional strengthening and/or toughening mechanisms to enhance the capability of these alloys to withstand extreme loading conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb3108", "DOI": "10.1126/sciadv.abb3108", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb3108", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000614004600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LQ; Xu, ZP; Kuo, CH; Peng, J; Hu, F; Li, LL; Chen, HY; Wang, JZ; Peng, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Luqi; Xu, Zipeng; Kuo, Chun-Han; Peng, Jian; Hu, Feng; Li, Linlin; Chen, Han-Yi; Wang, Jiazhao; Peng, Shengjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing Low-Valence Single Atoms by Constructing Metalloid Tungsten Carbide Supports for Efficient Hydrogen Oxidation and Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing novel single-atom catalysts (SACs) supports to modulate the electronic structure is crucial to optimize the catalytic activity, but rather challenging. Herein, a general strategy is proposed to utilize the metalloid properties of supports to trap and stabilize single-atoms with low-valence states. A series of single-atoms supported on the surface of tungsten carbide (M-WCx, M=Ru, Ir, Pd) are rationally developed through a facile pyrolysis method. Benefiting from the metalloid properties of WCx, the single-atoms exhibit weak coordination with surface W and C atoms, resulting in the formation of low-valence active centers similar to metals. The unique metal-metal interaction effectively stabilizes the low-valence single atoms on the WCx surface and improves the electronic orbital energy level distribution of the active sites. As expected, the representative Ru-WCx exhibits superior mass activities of 7.84 and 62.52 A mgRu-1 for the hydrogen oxidation and evolution reactions (HOR/HER), respectively. In-depth mechanistic analysis demonstrates that an ideal dual-sites cooperative mechanism achieves a suitable adsorption balance of Had and OHad, resulting in an energetically favorable Volmer step. This work offers new guidance for the precise construction of highly active SACs. Low-valence single-atom sites are induced and stabilized by constructing a metalloid tungsten carbide support (M-WCx, M=Ru, Ir, Pd), leading to the realization of superior mass activity for hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER).image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2023, "Volume": 62, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202311937", "DOI Link": "http://dx.doi.org/10.1002/anie.202311937", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001064571300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Young, SM; Kane, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Young, Steve M.; Kane, Charles L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac Semimetals in Two Dimensions", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is famous for being a host of 2D Dirac fermions. However, spin-orbit coupling introduces a small gap, so that graphene is formally a quantum spin Hall insulator. Here we present symmetry-protected 2D Dirac semimetals, which feature Dirac cones at high-symmetry points that are not gapped by spin-orbit interactions and exhibit behavior distinct from both graphene and 3D Dirac semimetals. Using a two-site tight-binding model, we construct representatives of three possible distinct Dirac semimetal phases and show that single symmetry-protected Dirac points are impossible in two dimensions. An essential role is played by the presence of nonsymmorphic space group symmetries. We argue that these symmetries tune the system to the boundary between a 2D topological and trivial insulator. By breaking the symmetries we are able to access trivial and topological insulators as well as Weyl semimetal phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 579, "Times Cited, All Databases": 604, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2015, "Volume": 115, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126803, "DOI": "10.1103/PhysRevLett.115.126803", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.126803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361316500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, YT; Xie, K; Ou, PF; Lavallais, C; Peng, T; Chen, Z; Zhang, ZY; Wang, N; Li, XY; Grigioni, I; Liu, BL; Sinton, D; Dunn, JB; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Yuting; Xie, Ke; Ou, Pengfei; Lavallais, Chayse; Peng, Tao; Chen, Zhu; Zhang, Zhiyuan; Wang, Ning; Li, Xiao-Yan; Grigioni, Ivan; Liu, Bilu; Sinton, David; Dunn, Jennifer B.; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective electrochemical synthesis of urea from nitrate and CO2 via relay catalysis on hybrid catalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The nitrogen cycle needed for scaled agriculture relies on energy- and carbon-intensive processes and generates nitrate-containing wastewater. Here we focus on an alternative approach-the electrified co- electrolysis of nitrate and CO2 to synthesize urea. When this is applied to industrial wastewater or agricultural runoff, the approach has the potential to enable low-carbon-intensity urea production while simultaneously providing wastewater denitrification. We report a strategy that increases selectivity to urea using a hybrid catalyst: two classes of site independently stabilize the key intermediates needed in urea formation, *CO2NO2 and *COOHNH2, via a relay catalysis mechanism. A Faradaic efficiency of 75% at wastewater-level nitrate concentrations (1,000 ppm NO3- [N]) is achieved on Zn/Cu catalysts. The resultant catalysts show a urea production rate of 16 mu mol h(-1) cm(-2). Life- cycle assessment indicates greenhouse gas emissions of 0.28 kg CO(2)e per kg urea for the electrochemical route, compared to 1.8 kg CO(2)e kg(-1) for the present-day route.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 939, "End Page": 948, "Article Number": null, "DOI": "10.1038/s41929-023-01020-4", "DOI Link": "http://dx.doi.org/10.1038/s41929-023-01020-4", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001065790700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZF; Huang, Y; Wei, B; Yang, YY; Yu, DH; Zheng, YP; He, DS; Zhang, WY; Zou, MC; Lan, JL; He, JQ; null, CW; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhifang; Huang, Yi; Wei, Bin; Yang, Yueyang; Yu, Dehong; Zheng, Yunpeng; He, Dongsheng; Zhang, Wenyu; Zou, Mingchu; Lan, Jin-Le; He, Jiaqing; null, Ce-Wen; Lin, Yuan-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compositing effects for high thermoelectric performance of Cu2Se-based materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric materials can realize direct conversion between heat and electricity, showing excellent potential for waste heat recovery. Cu2Se is a typical superionic conductor thermoelectric material having extraordinary ZT values, but its superionic feature causes poor service stability and low mobility. Here, we reported a fast preparation method of self-propagating high-temperature synthesis to realize in situ compositing of BiCuSeO and Cu2Se to optimize the service stability. Additionally, using the interface design by introducing graphene in these composites, the carrier mobility could be obviously enhanced, and the strong phonon scatterings could lead to lower lattice thermal conductivity. Ultimately, the Cu2Se-BiCuSeO-graphene composites presented excellent thermoelectric properties with a ZT(max) value of similar to 2.82 at 1000 K and a ZT(ave) value of similar to 1.73 from 473 K to 1000 K. This work provides a facile and effective strategy to largely improve the performance of Cu2Se-based thermoelectric materials, which could be further adopted in other thermoelectric systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2410, "DOI": "10.1038/s41467-023-38054-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38054-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000989625000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, J; Ko, Y; Kim, JP; Kim, JY; Kim, J; Kwon, O; Kim, KC; Kim, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Junhyeok; Ko, Yeongnam; Kim, Jeong Pil; Kim, Ju Yeon; Kim, Jiwon; Kwon, Ohchan; Kim, Ki Chul; Kim, Dae Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microwave-assisted design of nulloporous graphene membrane for ultrafast and switchable organic solvent nullofiltration", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered two-dimensional materials can potentially be utilized for organic solvent nullofiltration (OSN) membrane fabrication owing to their precise molecular sieving by the interlayer structure and excellent stability in harsh conditions. Nevertheless, the extensive tortuosity of nullochannels and bulky solvent molecules impede rapid permeability. Herein, nulloporous graphene (NG) with a high density of sp(2) carbon domain was synthesized via sequential thermal pore activation of graphene oxide (GO) and microwave-assisted reduction. Due to the smooth sp(2) carbon domain surfaces and dense nullopores, the microwave-treated nulloporous graphene membrane exhibited ultrafast organic solvent permeance (e.g., IPA: 2278 LMH/bar) with excellent stability under practical cross-flow conditions. Furthermore, the membrane molecular weight cut-off (MWCO) is switchable from 500 Da size of molecule to sub-nullometer-size molecules depending on the solvent type, and this switching occurs spontaneously with solvent change. These properties indicate feasibility of multiple (both binary and ternary) organic mixture separation using a single membrane. The nullochannel structure effect on solvent transport is also investigated using computation calculations. Layered 2D materials can be used for organic solvent nullofiltration (OSN) membrane fabrication due to precise molecular sieving by the interlayer structure and stability in harsh conditions. Here authors synthesise sp(2)-enriched nulloporous graphene by microwave treatment and demonstrate its excellent OSN performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 901, "DOI": "10.1038/s41467-023-36524-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36524-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002520500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jodlowski, AD; Roldán-Carmona, C; Grancini, G; Salado, M; Ralaiarisoa, M; Ahmad, S; Koch, N; Camacho, L; de Miguel, G; Nazeeruddin, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jodlowski, Alexander D.; Roldan-Carmona, Cristina; Grancini, Giulia; Salado, Manuel; Ralaiarisoa, Maryline; Ahmad, Shahzada; Koch, Norbert; Camacho, Luis; de Miguel, Gustavo; Nazeeruddin, Mohammad Khaja", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large guanidinium cation mixed with methylammonium in lead iodide perovskites for 19% efficient solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic lead halide perovskites have shown photovoltaic performances above 20% in a range of solar cell architectures while offering simple and low-cost processability. Despite the multiple ionic compositions that have been reported so far, the presence of organic constituents is an essential element in all of the high-efficiency formulations, with the methylammonium and formamidinium cations being the sole efficient options available to date. In this study, we demonstrate improved material stability after the incorporation of a large organic cation, guanidinium, into the MAPbI(3) crystal structure, which delivers average power conversion efficiencies over 19%, and stabilized performance for 1,000 h under continuous light illumination, a fundamental step within the perovskite field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 972, "End Page": 979, "Article Number": null, "DOI": "10.1038/s41560-017-0054-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-017-0054-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418244000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, L; Papanikolaou, KG; Lechner, BAJ; Je, L; Somorjai, GA; Salmeron, M; Mavrikakis, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Lang; Papanikolaou, Konstantinos G.; Lechner, Barbara A. J.; Je, Lisa; Somorjai, Gabor A.; Salmeron, Miquel; Mavrikakis, Manos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of active sites on transition metals through reaction-driven migration of surface atoms", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adopting low-index single-crystal surfaces as models for metal nulloparticle catalysts has been questioned by the experimental findings of adsorbate-induced formation of subnullometer clusters on several single-crystal surfaces. We used density functional theory calculations to elucidate the conditions that lead to cluster formation and show how adatom formation energies enable efficient screening of the conditions required for adsorbate-induced cluster formation. We studied a combination of eight face-centered cubic transition metals and 18 common surface intermediates and identified systems relevant to catalytic reactions, such as carbon monoxide (CO) oxidation and ammonia (NH3) oxidation. We used kinetic Monte Carlo simulations to elucidate the CO-induced cluster formation process on a copper surface. Scanning tunneling microscopy of CO on a nickel (111) surface that contains steps and dislocations points to the structure sensitivity of this phenomenon. Metal-metal bond breaking that leads to the evolution of catalyst structures under realistic reaction conditions occurs much more broadly than previously thought.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2023, "Volume": 380, "Issue": 6640, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 70, "End Page": 76, "Article Number": null, "DOI": "10.1126/science.add0089", "DOI Link": "http://dx.doi.org/10.1126/science.add0089", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973332200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JH; Bao, SY; Wang, XZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Jihong; Bao, Siyu; Wang, Xinzhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Applications of Graphene-Based Materials in Sensors: A Review", "Source Title": "MICROMACHINES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the research and the development of graphene-based materials, new sensors based on graphene compound materials are of great significance to scientific research and the consumer market. However, in the past ten years, due to the requirements of sensor accuracy, reliability, and durability, the development of new graphene sensors still faces many challenges in the future. Due to the special structure of graphene, the obtained characteristics can meet the requirements of high-performance sensors. Therefore, graphene materials have been applied in many innovative sensor materials in recent years. This paper introduces the important role and specific examples of sensors based on graphene and its base materials in biomedicine, photoelectrochemistry, flexible pressure, and other fields in recent years, and it puts forward the difficulties encountered in the application of graphene materials in sensors. Finally, the development direction of graphene sensors has been prospected. For the past two years of the COVID-19 epidemic, the detection of the virus sensor has been investigated. These new graphene sensors can complete signal detection based on accuracy and reliability, which provides a reference for researchers to select and manufacture sensor materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 184, "DOI": "10.3390/mi13020184", "DOI Link": "http://dx.doi.org/10.3390/mi13020184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767143600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smidstrup, S; Markussen, T; Vancraeyveld, P; Wellendorff, J; Schneider, J; Gunst, T; Verstichel, B; Stradi, D; Khomyakov, PA; Vej-Hansen, UG; Lee, ME; Chill, ST; Rasmussen, F; Penazzi, G; Corsetti, F; Ojanperä, A; Jensen, K; Palsgaard, MLN; Martinez, U; Blom, A; Brandbyge, M; Stokbro, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smidstrup, Soren; Markussen, Troels; Vancraeyveld, Pieter; Wellendorff, Jess; Schneider, Julian; Gunst, Tue; Verstichel, Brecht; Stradi, Daniele; Khomyakov, Petr A.; Vej-Hansen, Ulrik G.; Lee, Maeng-Eun; Chill, Samuel T.; Rasmussen, Filip; Penazzi, Gabriele; Corsetti, Fabiano; Ojanpera, Ari; Jensen, Kristian; Palsgaard, Mattias L. N.; Martinez, Umberto; Blom, Anders; Brandbyge, Mads; Stokbro, Kurt", "Book Author Full Names": null, "Group Authors": null, "Article Title": "QuantumATK: an integrated platform of electronic and atomic-scale modelling tools", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "QuantumATK is an integrated set of atomic-scale modelling tools developed since 2003 by professional software engineers in collaboration with academic researchers. While different aspects and individual modules of the platform have been previously presented, the purpose of this paper is to give a general overview of the platform. The QuantumATK simulation engines enable electronic-structure calculations using density functional theory or tight-binding model Hamiltonians, and also offers bonded or reactive empirical force fields in many different parametrizations. Density functional theory is implemented using either a plane-wave basis or expansion of electronic states in a linear combination of atomic orbitals. The platform includes a long list of advanced modules, including Green?s-function methods for electron transport simulations and surface calculations, first-principles electron-phonon and electron-photon couplings, simulation of atomic-scale heat transport, ion dynamics, spintronics, optical properties of materials, static polarization, and more. Seamless integration of the different simulation engines into a common platform allows for easy combination of different simulation methods into complex workflows. Besides giving a general overview and presenting a number of implementation details not previously published, we also present four different application examples. These are calculations of the phonon-limited mobility of Cu, Ag and Au, electron transport in a gated 2D device, multi-model simulation of lithium ion drift through a battery cathode in an external electric field, and electronic-structure calculations of the composition-dependent band gap of SiGe alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1409, "Times Cited, All Databases": 1439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 32, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15901, "DOI": "10.1088/1361-648X/ab4007", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ab4007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499348200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KJ; Scott, HS; Madden, DG; Pham, T; Kumar, A; Bajpai, A; Lusi, M; Forrest, KA; Space, B; Perry, JJ; Zaworotko, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Kai-Jie; Scott, Hayley S.; Madden, David G.; Pham, Tony; Kumar, Amrit; Bajpai, Alankriti; Lusi, Matteo; Forrest, Katherine A.; Space, Brian; Perry, John J.; Zaworotko, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Benchmark C2H2/CO2 and CO2/C2H2 Separation by Two Closely Related Hybrid Ultramicroporous Materials", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The removal of CO2 impurities from C2H2-containing gas mixtures is an important step in purifying C2H2, a feedstock chemical used in the production of several commodity chemicals. However, that C2H2 and CO2 exhibit similar size and physicochemical properties makes their separation by physisorption extremely difficult. In this work, we detail how two hybrid ultramicroporous materials (HUMs)-known variant SIFSIX-3-Ni and variant TIFSIX-2-Cu-i-exhibit exceptional CO2/C2H2 and C2H2/CO2 selectivity, respectively. SIFSIX-3-Ni sets a benchmark for CO2/C2H2 selectivity at low partial pressures, whereas TIFSIX-2-Cu-i ranks among the best porous materials in the context of C2H2/CO2 selectivity. The performance of these HUMs was confirmed by real-time dynamic breakthrough experiments. To our knowledge, such yin-yang inversion of selectivity in closely related compounds is unprecedented. We attribute this to the distinct sorbate binding sites in SIFSIX-3-Ni and TIFSIX-2-Cu-i, as revealed by modeling studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2016, "Volume": 1, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 753, "End Page": 765, "Article Number": null, "DOI": "10.1016/j.chempr.2016.10.009", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2016.10.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389801400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Radin, MD; Vinckeviciute, J; Seshadri, R; Vander Ven, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Radin, Maxwell D.; Vinckeviciute, Julija; Seshadri, Ram; Vander Ven, Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lithium-excess manganese oxides are a candidate cathode material for the next generation of Li-ion batteries because of their ability to reversibly intercalate more Li than traditional cathode materials. Although reversible oxidation of lattice oxygen has been proposed as the origin of this anomalous excess capacity, questions about the underlying electrochemical reaction mechanisms remain unresolved. Here, we critically analyse the O2-/O- oxygen redox hypothesis and explore alternative explanations for the origin of the anomalous capacity, including the formation of peroxide ions or trapped oxygen molecules and the oxidation of Mn. First-principles calculations motivated by the Li-Mn-O phase diagram show that the electrochemical behaviour of the Li-excess manganese oxides is thermodynamically consistent with the oxidation of Mn from the +4 oxidation state to the +7 oxidation state and the concomitant migration of Mn from octahedral sites to tetrahedral sites. It is shown that the Mn oxidation hypothesis can explain the poorly understood electrochemical behaviour of Li-excess materials, including the activation step, the voltage hysteresis and voltage fade.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 639, "End Page": 646, "Article Number": null, "DOI": "10.1038/s41560-019-0439-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0439-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000481484400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Coudert, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Coudert, Francois-Xavier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Responsive Metal-Organic Frameworks and Framework Materials: Under Pressure, Taking the Heat, in the Spotlight, with Friends", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent years have seen a large increase of the research effort focused on framework materials, including the nowadays-ubiquitous metal organic frameworks but also dense coordination polymers, covalent organic frameworks, and molecular frameworks. With the quickly increasing number of structures synthesized and characterized, one pattern emerging is the common occurrence of flexibility. More specifically, an important number of framework materials are stimuli-responsive: their structure can undergo changes of large amplitude in response to physical or chemical stimulation. They can display transformations induced by temperature, mechanical pressure, guest adsorption or evacuation, light absorption, etc. and are sometimes referred to as smart materials, soft crystals, or dynamic materials. This Perspective highlights recent progress in this field, showcasing some of the most novel and unusual responses to stimuli, as well as advances in the fundamental understanding of flexible framework materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2015, "Volume": 27, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1905, "End Page": 1916, "Article Number": null, "DOI": "10.1021/acs.chemmater.5b00046", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.5b00046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351971600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peurifoy, J; Shen, YC; Jing, L; Yang, Y; Cano-Renteria, F; DeLacy, BG; Joannopoulos, JD; Tegmark, M; Soljacic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peurifoy, John; Shen, Yichen; Jing, Li; Yang, Yi; Cano-Renteria, Fidel; DeLacy, Brendan G.; Joannopoulos, John D.; Tegmark, Max; Soljacic, Marin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullophotonic particle simulation and inverse design using artificial neural networks", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a method to use artificial neural networks to approximate light scattering by multilayer nulloparticles. We find that the network needs to be trained on only a small sampling of the data to approximate the simulation to high precision. Once the neural network is trained, it can simulate such optical processes orders of magnitude faster than conventional simulations. Furthermore, the trained neural network can be used to solve nullophotonic inverse design problems by using back propagation, where the gradient is analytical, not numerical.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 681, "Times Cited, All Databases": 748, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar4206", "DOI": "10.1126/sciadv.aar4206", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar4206", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, ZX; Tan, H; Gu, JX; Lu, LG; Zeng, X; Zhang, TQ; Wang, C; Ding, LY; Cullen, PJ; Chen, ZF; Zhao, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, Zengxia; Tan, Hao; Gu, Jinxing; Lu, Linguo; Zeng, Xin; Zhang, Tianqi; Wang, Cheng; Ding, Luyao; Cullen, Patrick J.; Chen, Zhongfang; Zhao, Shenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A polymeric hydrogel electrocatalyst for direct water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are networked hydrophilic polymers with enriched polar groups and confined water but are relatively less explored as electrocatalysts. Here, the authors demonstrate that insulative polymeric hydrogels can be an underlying catalogue of metal-free oxygen evolution electrocatalyst with huge extension potentials. Metal-free electrocatalysts represent a main branch of active materials for oxygen evolution reaction (OER), but they excessively rely on functionalized conjugated carbon materials, which substantially restricts the screening of potential efficient carbonaceous electrocatalysts. Herein, we demonstrate that a mesostructured polyacrylate hydrogel can afford an unexpected and exceptional OER activity - on par with that of benchmark IrO2 catalyst in alkaline electrolyte, together with a high durability and good adaptability in various pH environments. Combined theoretical and electrokinetic studies reveal that the positively charged carbon atoms within the carboxylate units are intrinsically active toward OER, and spectroscopic operando characterizations also identify the fingerprint superoxide intermediate generated on the polymeric hydrogel backbone. This work expands the scope of metal-free materials for OER by providing a new class of polymeric hydrogel electrocatalysts with huge extension potentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 818, "DOI": "10.1038/s41467-023-36532-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36532-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001009851700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, NK; Seo, J; Lee, S; Kim, HJ; Kim, U; Lee, J; Han, YK; Park, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Nam Khen; Seo, Jihyung; Lee, Sangjin; Kim, Hyung-Jin; Kim, Ungsoo; Lee, Junghyun; Han, Young-Kyu; Park, Hyesung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient and robust noble-metal free bifunctional water electrolysis catalyst achieved via complementary charge transfer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The operating principle of conventional water electrolysis using heterogenous catalysts has been primarily focused on the unidirectional charge transfer within the heterostructure. Herein, multidirectional charge transfer concept has been adopted within heterostructured catalysts to develop an efficient and robust bifunctional water electrolysis catalyst, which comprises perovskite oxides (La0.5Sr0.5CoO3-delta, LSC) and potassium ion-bonded MoSe2 (K-MoSe2). The complementary charge transfer from LSC and K to MoSe2 endows MoSe2 with the electron-rich surface and increased electrical conductivity, which improves the hydrogen evolution reaction (HER) kinetics. Excellent oxygen evolution reaction (OER) kinetics of LSC/K-MoSe2 is also achieved, surpassing that of the noble metal (IrO2), attributed to the enhanced adsorption capability of surface-based oxygen intermediates of the heterostructure. Consequently, the water electrolysis efficiency of LSC/K-MoSe2 exceeds the performance of the state-of-the-art Pt/C||IrO2 couple. Furthermore, LSC/K-MoSe2 exhibits remarkable chronopotentiometric stability over 2,500h under a high current density of 100mAcm(-2). While water electrolysis offers a renewable means to obtain H-2, it is necessary to understand the roles adopted by catalytic components. Here, authors explore a heterostructured MoSe2/perovskite oxide catalyst that shows multidirectional charge transfer to boost electrocatalytic water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4606, "DOI": "10.1038/s41467-021-24829-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24829-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680897400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Le Corre, VM; Duijnstee, EA; El Tambouli, O; Ball, JM; Snaith, HJ; Lim, J; Koster, LJA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Le Corre, Vincent M.; Duijnstee, Elisabeth A.; El Tambouli, Omar; Ball, James M.; Snaith, Henry J.; Lim, Jongchul; Koster, L. Jan Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing Charge Carrier Mobility and Defect Densities in Metal Halide Perovskites via Space-Charge-Limited Current Measurements", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Space-charge-limited current (SCLC) measurements have been widely used to study the charge carrier mobility and trap density in semiconductors. However, their applicability to metal halide perovskites is not straightforward, due to the mixed ionic and electronic nature of these materials. Here, we discuss the pitfalls of SCLC for perovskite semiconductors, and especially the effect of mobile ions. We show, using driftdiffusion (DD) simulations, that the ions strongly affect the measurement and that the usual analysis and interpretation of SCLC need to be refined. We highlight that the trap density and mobility cannot be directly quantified using classical methods. We discuss the advantages of pulsed SCLC for obtaining reliable data with minimal influence of the ionic motion. We then show that fitting the pulsed SCLC with DD modeling is a reliable method for extracting mobility, trap, and ion densities simultaneously. As a proof of concept, we obtain a trap density of 1.3 x 10(13) cm(-3), an ion density of 1.1 x 10(13) cm(-3), and a mobility of 13 cm(2) V-1 s(-1) for a MAPbBr(3) single crystal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1087, "End Page": 1094, "Article Number": null, "DOI": "10.1021/acsenergylett.0c02599", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.0c02599", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629230800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JZ; Xu, X; Wu, HJ; Wang, JL; Lou, LC; Yin, K; Gong, YC; Shi, JJ; Luo, YH; Li, DM; Xin, H; Meng, QB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jiazheng; Xu, Xiao; Wu, Huijue; Wang, Jinlin; Lou, Licheng; Yin, Kang; Gong, Yuancai; Shi, Jiangjian; Luo, Yanhong; Li, Dongmei; Xin, Hao; Meng, Qingbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of the phase evolution of kesterite by tuning of the selenium partial pressure for solar cells with 13.8% certified efficiency", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The control of the phase evolution during the selenization of kesterite Cu2ZnSn(S,Se)(4) (CZTSSe) is crucial for efficient solar cells. Here, we regulate the phase-evolution kinetics of Ag-alloyed CZTSSe by applying a positive pressure in the reaction chamber at the initial stage of the annealing process. The partial pressure of Se decreases, reducing the collision probability between selenium molecules and the kesterite precursor during the initial formation of the crystals. This results in the precursor transforming into CZTSSe in a single step, without the formation of secondary phases. CZTSSe forms at relatively higher temperature than conventional methods, leading to high-crystallinity kesterite films with fewer defects. We demonstrate solar cells with a total area efficiency of 14.1% and a certified total area efficiency of 13.8%. This work provides insights into the selenization mechanism and phase evolution of kesterite absorbers, enabling efficient solar cells. Secondary phases or multi-step phase formation lead to poorly crystallized and defective kesterite films. Now Zhou et al. convert precursors into kesterite in a single step, using low partial pressure of selenium, and achieve solar cells with 13.8% certified efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01251-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01251-6", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968306600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Perumal, S; Samanta, M; Ghosh, T; Shenoy, US; Bohra, AK; Bhattacharya, S; Singh, A; Waghmare, UV; Biswas, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perumal, Suresh; Samanta, Manisha; Ghosh, Tanmoy; Shenoy, U. Sandhya; Bohra, Anil K.; Bhattacharya, Shovit; Singh, Ajay; Waghmare, Umesh, V; Biswas, Kanishka", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of High Thermoelectric Figure of Merit in GeTe by Complementary Co-doping of Bi and In", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "GeTe and its derivatives have recently attracted wide attention as promising thermoelectric materials. The principle challenge in optimizing the thermoelectric figure of merit, zT, is the low Seebeck coefficient (S) and high thermal conductivity of GeTe. Here, we report a high zT of similar to 2.1 at 723 K in In and Bi co-doped GeTe along with an extremely high TE conversion efficiency of similar to 12.3% in a single-leg thermoelectric generator for the temperature difference of 445 K. In and Bi play a distinct but complementary role. In doping significantly enhances the S through the formation of resonullce level, which is confirmed with first-principles density functional theory calculations and Pisarenko plot considering two valance band model. However, Bi doping markedly reduces the lattice thermal conductivity due to the formation of extensive solid solution point defects and domain variants. Moreover, a high value of Vickers microhardness (similar to 200 H-v, H-v = kgf/mm(2)) reveals excellent mechanical stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2019, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2565, "End Page": 2580, "Article Number": null, "DOI": "10.1016/j.joule.2019.08.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.08.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490703300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, XY; Wang, YB; Lin, JB; Liu, X; He, X; Barbaud, J; Wu, TH; Noda, T; Yang, XD; Han, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Xiangyue; Wang, Yanbo; Lin, Jianbo; Liu, Xiao; He, Xin; Barbaud, Julien; Wu, Tianhao; Noda, Takeshi; Yang, Xudong; Han, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface-Controlled Oriented Growth of FASnI3 Crystals for Efficient Lead-free Perovskite Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin-based perovskites with narrow band gap and high carrier mobility are promising candidates for the preparation of efficient lead-free perovskite solar cells (PSCs). However, the poor crystallization of tin-based perovskite films with unfavorable defects and rough morphology is still the biggest challenge to achieve high power conversion efficiency. In this work, we reveal the surface-controlled growth of FASnI(3) perovskite films, and then precisely control the crystallization process by reducing the surface energy of the solution-air surface with a tailormade pentafluorophen-oxyethylammonium iodide (FOEI). The demonstrated strategy enabled us to achieve highly oriented and smooth FASnI(3)-FOEI films with lower defect density and longer lifetime of charge carriers. A certificated efficiency of 10.16% for tin-based PSCs was obtained from an accredited institute.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2020, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 902, "End Page": 912, "Article Number": null, "DOI": "10.1016/j.joule.2020.03.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.03.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527264500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Siminska-Stanny, J; Niziol, M; Szymczyk-Ziólkowska, P; Brozyna, M; Junka, A; Shavandi, A; Podstawczyk, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Siminska-Stanny, Julia; Niziol, Martyna; Szymczyk-Ziolkowska, Patrycja; Brozyna, Malwina; Junka, Adam; Shavandi, Amin; Podstawczyk, Daria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4D printing of patterned multimaterial magnetic hydrogel actuators", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper demonstrates a new class of printable magnetic hydrogels that can be successfully used for multimaterial direct ink printing (4D printing) of soft actuators. To date, most reports on magnetic actuation have not considered biocompatibility issues associated with magnetic materials and synthetic polymers. For this reason, in this study, considerable attention was given to developing bionullocomposites that exhibit noncytotoxicity and biocompatibility and hence may be used in biomedical applications. Three inks with various concentrations of magnetic nulloparticles (MNPs) were used to print 3D objects, such as tubes (wheels), cubes, and cantilevers. The interactions between MNPs and hydrogel precursor network accounted for excellent shear thinning properties of the inks. Usually, hydrogel actuators move or change a shape upon anisotropic swelling and deswelling, possible only in an aqueous environment. Our study addresses this challenge by incorporating magnetic nulloparticles into the hydrogel, allowing for contactless in-air control of hydrogel motion. Because of the high structural integrity of the hydrogel, we can state that multimaterial direct ink printing is an excellent method for obtaining a 3D construct of high resolution, shape fidelity, tunable distribution of MNPs, and induced macroscopic anisotropy. The magnetic hydrogels are not only highly porous and noncytotoxic towards fibroblasts but also exhibit good mechanical stability and unique magnetic responsiveness. The simple approach allowed us to fabricate different magnetic actuators with various patterns, composed of magnetic and non-magnetic materials. The results demonstrate the interplay between magnetic and nonmagnetic hydrogels that influences the actuation performance of multimaterial objects, as illustrated by magnetically induced rolling, jumping, and bending. It was shown that programmable patterning of the hydrogels leads to the development of macroscopically anisotropic magnetic material. Our study confirmed that the intersection of 4D printing of magnetically responsive hydrogel materials and programmable patterning promises to fulfill future soft robotics' biocompatibility and functionality requirements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 49, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102506, "DOI": "10.1016/j.addma.2021.102506", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.102506", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752205500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, ML; Zhang, Q; Ye, CL; Liu, ZB; Zhong, XW; Wang, JX; Li, C; Dai, LX; Zhou, GM; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Miaolun; Zhang, Qi; Ye, Chenliang; Liu, Zhibo; Zhong, Xiongwei; Wang, Junxiong; Li, Chuang; Dai, Lixin; Zhou, Guangmin; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling spent LiNi1-x-yMnxCoyO2 cathodes to bifunctional NiMnCo catalysts for zinc-air batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The skyrocketing production of lithium-ion batteries (LIBs) for electric vehicles portends that tremendous numbers of used LIBs will be generated. However, the recycling of used LIBs is limited by the complicated separation processes of traditional pyrometallurgy and hydrometallurgy methods. Here, we applied a rapid thermal radiation method to convert spent LiNi1-x-yMnxCoyO2 (NMC) cathodes from used LIBs into highly efficient NiMnCo-based catalysts for zinc-air batteries (ZABs) through acid leaching and radiative heating processes, which avoids sophisticated separation of different metals and can synthesize the catalysts rapidly. The prepared NiMnCo-activated carbon (NiMnCo-AC) catalyst presents a unique core-shell structure, with facecentered cubic Ni in the core and spinel NiMnCoO4 in the shell, which redistributes the electronic structure of the NiMnCoO4 shell to decrease the energy barrier for oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) processes and ensures high electrocatalytic activities. The NiMnCo-AC catalyst in ZABs as cathode materials exhibits a high power density of 187.7 mW cm(-2), low voltage gap of 0.72 V at the initial three cycles, and long cycling duration of 200 h at the current density of 10 mA cm(-2). This work provides a promising strategy to recycle spent LIBs to highly efficient catalysts for ZABs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2022, "Volume": 119, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2202202119", "DOI": "10.1073/pnas.2202202119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2202202119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854008900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, Y; Qin, ZH; Wu, H; Li, M; Hu, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Ying; Qin, Zihao; Wu, Huan; Li, Man; Hu, Yongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible thermal interface based on self-assembled boron arsenide for high-performance thermal management", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal management is the most critical technology challenge for modern electronics. Recent key materials innovation focuses on developing advanced thermal interface of electronic packaging for achieving efficient heat dissipation. Here, for the first time we report a record-high performance thermal interface beyond the current state of the art, based on self-assembled manufacturing of cubic boron arsenide (s-BAs). The s-BAs exhibits highly desirable characteristics of high thermal conductivity up to 21W/m.K and excellent elastic compliance similar to that of soft biological tissues down to 100kPa through the rational design of BAs microcrystals in polymer composite. In addition, the s-BAs demonstrates high flexibility and preserves the high conductivity over at least 500 bending cycles, opening up new application opportunities for flexible thermal cooling. Moreover, we demonstrated device integration with power LEDs and measured a superior cooling performance of s-BAs beyond the current state of the art, by up to 45 degrees C reduction in the hot spot temperature. Together, this study demonstrates scalable manufacturing of a new generation of energy-efficient and flexible thermal interface that holds great promise for advanced thermal management of future integrated circuits and emerging applications such as wearable electronics and soft robotics. Well-developed prototype interface materials for electronics thermal management are limited to a low thermal conductivity or high elastic modulus. Here, the authors report flexible thermal interfaces through self-assembled manufacturing of polymetric composites based on the high thermal conductivity of cubic boron arsenide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1284, "DOI": "10.1038/s41467-021-21531-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21531-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626610200027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XL; Yan, W; Levy, U; Mortensen, NA; Kristensen, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xiaolong; Yan, Wei; Levy, Uriel; Mortensen, N. Asger; Kristensen, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resonullt laser printing of structural colors on high-index dielectric metasurfaces", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Man-made structural colors, which originate from resonullt interactions between visible light and manufactured nullostructures, are emerging as a solution for ink-free color printing. We show that non-iridescent structural colors can be conveniently produced by nullostructures made from high-index dielectric materials. Compared to plasmonic analogs, color surfaces with high-index dielectrics, such as germanium (Ge), have a lower reflectance, yielding a superior color contrast. Taking advantage of band-to-band absorption in Ge, we laser-postprocess Ge color metasurfaces with morphology-dependent resonullces. Strong on-resonullce energy absorption under pulsed laser irradiation locally elevates the lattice temperature (exceeding 1200 K) in an ultrashort time scale (1 ns). This forms the basis for resonullt laser printing, where rapid melting allows for surface energy-driven morphology changes with associated modification of color appearance. Laser-printable high-index dielectric color metasurfaces are scalable to a large area and open a new paradigm for printing and decoration with nonfading and vibrant colors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602487", "DOI": "10.1126/sciadv.1602487", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602487", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401955300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, M; Wang, ZQ; Mei, AH; Yang, ZF; Chen, W; Ou, SY; Wang, SY; Chen, KQ; Reiss, P; Qi, K; Ma, JY; Liu, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Min; Wang, Zhiqing; Mei, Aohan; Yang, Zifan; Chen, Wen; Ou, Siyong; Wang, Shengyao; Chen, Keqiang; Reiss, Peter; Qi, Kun; Ma, Jingyuan; Liu, Yueli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic CO2 reduction using La-Ni bimetallic sites within a covalent organic framework", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The precise construction of photocatalysts with diatomic sites that simultaneously foster light absorption and catalytic activity is a formidable challenge, as both processes follow distinct pathways. Herein, an electrostatically driven self-assembly approach is used, where phenullthroline is used to synthesize bifunctional LaNi sites within covalent organic framework. The La and Ni site acts as optically and catalytically active center for photocarriers generation and highly selective CO2-to-CO reduction, respectively. Theory calculations and in-situ characterization reveal the directional charge transfer between LaNi double-atomic sites, leading to decreased reaction energy barriers of *COOH intermediate and enhanced CO2-to-CO conversion. As a result, without any additional photosensitizers, a 15.2 times enhancement of the CO2 reduction rate (605.8 mu mol.g(-1).h(-1)) over that of a benchmark covalent organic framework colloid (39.9 mu mol.g(-1).h(-1)) and improved CO selectivity (98.2%) are achieved. This work presents a potential strategy for integrating optically and catalytically active centers to enhance photocatalytic CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2473, "DOI": "10.1038/s41467-023-37545-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37545-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022903400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saito, Y; Nakamura, Y; Bahramy, MS; Kohama, Y; Ye, JT; Kasahara, Y; Nakagawa, Y; Onga, M; Tokunaga, M; Nojima, T; Yanase, Y; Iwasa, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saito, Yu; Nakamura, Yasuharu; Bahramy, Mohammad Saeed; Kohama, Yoshimitsu; Ye, Jianting; Kasahara, Yuichi; Nakagawa, Yuji; Onga, Masaru; Tokunaga, Masashi; Nojima, Tsutomu; Yanase, Youichi; Iwasa, Yoshihiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity protected by spin-valley locking in ion-gated MoS2", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symmetry-breaking has been known to play a key role in non-centrosymmetric superconductors with strong spin-orbit interactions (SOIs; refs 1-6). The studies, however, have been so far mainly focused on a particular type of SOI, known as the Rashba SOI (ref. 7), whereby the electron spin is locked to its momentum at a right-angle, thereby leading to an in-plane helical spin texture. Here we discuss electric-field-induced superconductivity in molybdenum disulphide (MoS2), which exhibits a fundamentally different type of intrinsic SOI, manifested by an out-of-plane Zeeman-type spin polarization of energy valleys(8-10). We find an upper critical field of approximately 52 T at 1.5 K, which indicates an enhancement of the Pauli limit by a factor of four as compared to that in centrosymmetric conventional superconductors. Using realistic tight-binding calculations, we reveal that this unusual behaviour is due to an inter-valley pairing that is symmetrically protected by Zeeman-type spin-valley locking against external magnetic fields. Our study sheds light on the interplay of inversion asymmetry with SOIs in confined geometries, and its role in superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 475, "Times Cited, All Databases": 524, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 144, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3580", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3580", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369319500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZL; Huang, SB; Li, DT; Zhu, J; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhiling; Huang, Sibo; Li, Dongting; Zhu, Jie; Li, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband impedance modulation via non-local acoustic metamaterials", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The nonlocality between subunits was utilized to approach the causality-governed minimal thickness, thereby enabling ultrathin acoustic metamaterials to achieve broadband sound absorption and desired impedance profiles over four octaves. Causality of linear time-invariant systems inherently defines the wave-matter interaction process in wave physics. This principle imposes strict constraints on the interfacial response of materials on various physical platforms. A typical consequence is that a delicate balance has to be struck between the conflicting bandwidth and geometric thickness when constructing a medium with desired impedance, which makes it challenging to realize broadband impedance modulation with compact structures. In pursuit of improvement, the over-damped recipe and the reduced excessive response recipe are creatively presented in this work. As a proof-of-concept demonstration, we construct a metamaterial with intensive mode density that supports strong non-locality over a frequency band from 320 Hz to 6400 Hz. Under the guidelines of the over-damped recipe and the reduced excessive response recipe, the metamaterial realizes impedance matching to air and exhibits broadband near-perfect absorption without evident impedance oscillation and absorption dips in the working frequency band. We further present a dual-functional design capable of frequency-selective absorption and reflection by concentrating the resonullce modes in three frequency bands. Our research reveals the significance of over-damped recipe and the strong non-local effect in broadband impedance modulation, which may open up avenues for constructing efficient artificial impedance boundaries for energy absorption and other wave manipulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2022, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab171", "DOI": "10.1093/nsr/nwab171", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab171", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849495900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Zhang, D; Li, WJ; Lin, HB; Ding, CD; Liu, QY; Wang, LL; Li, ZM; Mei, L; Chen, HZ; Zhao, YL; Zeng, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Li; Zhang, Dan; Li, Wenjing; Lin, Hongbing; Ding, Chendi; Liu, Qingyun; Wang, Liangliang; Li, Zimu; Mei, Lin; Chen, Hongzhong; Zhao, Yanli; Zeng, Xiaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biofilm microenvironment triggered self-enhancing photodynamic immunomodulatory microneedle for diabetic wound therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The treatment of diabetic wounds faces enormous challenges due to complex wound environments, such as infected biofilms, excessive inflammation, and impaired angiogenesis. The critical role of the microenvironment in the chronic diabetic wounds has not been addressed for therapeutic development. Herein, we develop a microneedle (MN) bandage functionalized with dopamine-coated hybrid nulloparticles containing selenium and chlorin e6 (SeC@PA), which is capable of the dual-directional regulation of reactive species (RS) generation, including reactive oxygen species (ROS) and reactive nitrogen species (RNS), in response to the wound microenvironment. The SeC@PA MN bandage can disrupt barriers in wound coverings for efficient SeC@PA delivery. SeC@PA not only depletes endogenous glutathione (GSH) to enhance the anti-biofilm effect of RS, but also degrades GSH in biofilms through cascade reactions to generate more lethal RS for biofilm eradication. SeC@PA acts as an RS scavenger in wound beds with low GSH levels, exerting an anti-inflammatory effect. SeC@PA also promotes the M2-phenotype polarization of macrophages, accelerating wound healing. This self-enhanced, catabolic and dynamic therapy, activated by the wound microenvironment, provides an approach for treating chronic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7658, "DOI": "10.1038/s41467-023-43067-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43067-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001110180200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, K; Roberts, MR; Guerrini, N; Tapia-Ruiz, N; Hao, R; Massel, F; Pickup, DM; Ramos, S; Liu, YS; Guo, JH; Chadwick, AV; Duda, LC; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Kun; Roberts, Matthew R.; Guerrini, Niccolo; Tapia-Ruiz, Nuria; Hao, Rong; Massel, Felix; Pickup, David M.; Ramos, Silvia; Liu, Yi-Sheng; Guo, Jinghua; Chadwick, Alan V.; Duda, Laurent C.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li0.2Ni0.2Mn0.6]O2", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional intercalation cathodes for lithium batteries store charge in redox reactions associated with the transition metal cations, e.g., Mn3+/4+ in LiMn2O4, and this limits the energy storage of Li-ion batteries. Compounds such as Li[Li0.2Ni0.2Mn0.6]O-2 exhibit a capacity to store charge in excess of the transition metal redox reactions. The additional capacity occurs at and above 4.5 V versus Li+/Li. The capacity at 4.5 V is dominated by oxidation of the O-2(-) anions accounting for similar to 0.43 e(-)/formula unit, with an additional 0.06 e(-)/formula unit being associated with O loss from the lattice. In contrast, the capacity above 4.5 V is mainly O loss, similar to 0.08 e(-)/formula. The O redox reaction involves the formation of localized hole states on O during charge, which are located on O coordinated by (Mn4+/Li+). The results have been obtained by combining operando electrochemical mass spec on 180 labeled Li[Li0.2Ni0.2Mn0.6]O-2 with XANES, soft X-ray spectroscopy, resonullt inelastic X-ray spectroscopy, and Raman spectroscopy. Finally the general features of O redox are described with discussion about the role of comparatively ionic (less covalent) 3d metal oxygen interaction on anion redox in lithium rich cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2016, "Volume": 138, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11211, "End Page": 11218, "Article Number": null, "DOI": "10.1021/jacs.6b05111", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b05111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382901800031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huan, TD; Sharma, V; Rossetti, GA; Ramprasad, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huan, Tran Doan; Sharma, Vinit; Rossetti, George A., Jr.; Ramprasad, Rampi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pathways towards ferroelectricity in hafnia", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The question of whether one can systematically identify (previously unknown) ferroelectric phases of a given material is addressed, taking hafnia (HfO2) as an example. Low free energy phases at various pressures and temperatures are identified using a first-principles based structure search algorithm. Ferroelectric phases are then recognized by exploiting group theoretical principles for the symmetry-allowed displacive transitions between nonpolar and polar phases. Two orthorhombic polar phases occurring in space groups Pca2(1) and Pmn2(1) are singled out as the most viable ferroelectric phases of hafnia, as they display low free energies (relative to known nonpolar phases), and substantial switchable spontaneous electric polarization. These results provide an explanation for the recently observed surprising ferroelectric behavior of hafnia, and reveal pathways for stabilizing ferroelectric phases of hafnia as well as other compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 27", "Publication Year": 2014, "Volume": 90, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 64111, "DOI": "10.1103/PhysRevB.90.064111", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.064111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341258500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Yu, MY; Yu, ZZ; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ji; Yu, Ming-Yuan; Yu, Zhong-Zhen; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and advanced manufacturing of electromagnetic interference shielding materials", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic interference (EMI) shielding is critical in electronic applications. However, the currently available EMI shielding materials are restricted in customizability and application flexibility. Recent advances in manufacturing technologies have provided a unique path to achieve the custom creation of EMI shielding solutions. A successful example is additive manufacturing (AM), which has enabled high design freedom, efficient performance regulation, and multifunctionality simultaneously into fabricated shields, offering an opportunity to start a revolution in the field of EMI shielding. In this review, we summarize the latest advances in AM of EMI shielding materials, aiming to provide a deep understanding of the connection between raw materials, manufacturing methods, design considerations, and performances of the fabricated EMI shields. We first introduce the EMI shielding mechanism and available raw materials, subsequently focusing on the characteristics of representative AM methods and the as-created EMI shielding solutions. Based on the requirements to create application-oriented EMI shielding solutions, these methods are also critically compared. Thereafter, we present the state-of-the-art design considerations of EMI shields and examine the pivotal roles of AM in realizing the designs. We conclude by discussing future research directions, aiming at motivating the use of AM in the future developments of EMI shielding solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 66, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": 272, "Article Number": null, "DOI": "10.1016/j.mattod.2023.03.022", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2023.03.022", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001034164300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, H; Han, L; Feng, XY; Zhou, YJ; Su, RX; Wang, Q; Liao, LY; Zhu, WX; Chen, XZ; Pan, F; Fan, XL; Song, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, H.; Han, L.; Feng, X. Y.; Zhou, Y. J.; Su, R. X.; Wang, Q.; Liao, L. Y.; Zhu, W. X.; Chen, X. Z.; Pan, F.; Fan, X. L.; Song, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Spin Splitting Torque in a Collinear Antiferromagnet RuO2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current-induced spin torques provide efficient data writing approaches for magnetic memories. Recently, the spin splitting torque (SST) was theoretically predicted, which combines advantages of conventional spin transfer torque (STT) and spin-orbit torque (SOT) as well as enables controllable spin polarization. Here we provide the experimental evidence of SST in collinear antiferromagnet RuO2 films. The spin current direction is found to be correlated to the crystal orientation of RuO2 and the spin polarization direction is dependent on (parallel to) the Neel vector. These features are quite characteristic for the predicted SST. Our finding not only presents a new member for the spin torques besides traditional STT and SOT, but also proposes a promising spin source RuO2 for spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2022, "Volume": 128, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 197202, "DOI": "10.1103/PhysRevLett.128.197202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.128.197202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000807542100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sui, FR; Jin, M; Zhang, YY; Qi, RJ; Wu, YN; Huang, R; Yue, FY; Chu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sui, Fengrui; Jin, Min; Zhang, Yuanyuan; Qi, Ruijuan; Wu, Yu-Ning; Huang, Rong; Yue, Fangyu; Chu, Junhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sliding ferroelectricity in van der Waals layered γ-InSe semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) van-der-Waals (vdW) layered ferroelectric semiconductors are highly desired for in-memory computing and ferroelectric photovoltaics or detectors. Beneficial from the weak interlayer vdW-force, controlling the structure by interlayer twist/translation or doping is an effective strategy to manipulate the fundamental properties of 2D-vdW semiconductors, which has contributed to the newly-emerging sliding ferroelectricity. Here, we report unconventional room-temperature ferroelectricity, both out-of-plane and in-plane, in vdW-layered gamma-InSe semiconductor triggered by yttrium-doping (InSe:Y). We determine an effective piezoelectric constant of similar to 7.5 pm/V for InSe:Y flakes with thickness of similar to 50 nm, about one order of magnitude larger than earlier reports. We directly visualize the enhanced sliding switchable polarization originating from the fantastic microstructure modifications including the stacking-faults elimination and a subtle rhombohedral distortion due to the intralayer compression and continuous interlayer pre-sliding. Our investigations provide new freedom degrees of structure manipulation for intrinsic properties in 2D-vdW-layered semiconductors to expand ferroelectric candidates for next-generation nulloelectronics. Exploring two-dimensional layered ferroelectric semiconductors is highly desired for ferroelectric-based devices. Here, the authors realize the room-temperature ferroelectricity in layered Y-doped gamma-InSe due to the microstructure modifications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-022-35490-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35490-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953169900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Banerjee, S; Pillai, SC; Falaras, P; O'Shea, KE; Byrne, JA; Dionysiou, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Banerjee, Swagata; Pillai, Suresh C.; Falaras, Polycarpos; O'Shea, Kevin E.; Byrne, John A.; Dionysiou, Dionysios D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Insights into the Mechanism of Visible Light Photocatalysis", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the area of developing visible-light-active photocatalysts based on titanium dioxide has been enormously investigated due to its wide range of applications in energy and environment related fields. Various strategies have been designed to efficiently utilize the solar radiation and to enhance the efficiency of photocatalytic processes. Building on the fundamental strategies to improve the visible light activity of TiO2-based photocatalysts, this Perspective aims to give an insight into many contemporary developments in the field of visible-light-active photocatalysis. Various examples of advanced TiO2 composites have been discussed in relation to their visible light induced photoconversion efficiency, dynamics of electron-hole separation, and decomposition of organic and inorganic pollutants, which suggest the critical need for further development of these types of materials for energy conversion and environmental remediation purposes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 621, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2014, "Volume": 5, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2543, "End Page": 2554, "Article Number": null, "DOI": "10.1021/jz501030x", "DOI Link": "http://dx.doi.org/10.1021/jz501030x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340222200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bian, T; Gardin, A; Gemen, J; Houben, L; Perego, C; Lee, B; Elad, N; Chu, ZL; Pavan, GM; Klajn, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bian, Tong; Gardin, Andrea; Gemen, Julius; Houben, Lothar; Perego, Claudio; Lee, Byeongdu; Elad, Nadav; Chu, Zonglin; Pavan, Giovanni M.; Klajn, Rafal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatic co-assembly of nulloparticles with oppositely charged small molecules into static and dynamic superstructures", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coulombic interactions can be used to assemble charged nulloparticles into higher-order structures, but the process requires oppositely charged partners that are similarly sized. The ability to mediate the assembly of such charged nulloparticles using structurally simple small molecules would greatly facilitate the fabrication of nullostructured materials and harnessing their applications in catalysis, sensing and photonics. Here we show that small molecules with as few as three electric charges can effectively induce attractive interactions between oppositely charged nulloparticles in water. These interactions can guide the assembly of charged nulloparticles into colloidal crystals of a quality previously only thought to result from their co-crystallization with oppositely charged nulloparticles of a similar size. Transient nulloparticle assemblies can be generated using positively charged nulloparticles and multiply charged anions that are enzymatically hydrolysed into mono- and/or dianions. Our findings demonstrate an approach for the facile fabrication, manipulation and further investigation of static and dynamic nullostructured materials in aqueous environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 13, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 940, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-021-00752-9", "DOI Link": "http://dx.doi.org/10.1038/s41557-021-00752-9", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692966000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Green, AJ; Speck, J; Xing, G; Moens, P; Allerstam, F; Gumaelius, K; Neyer, T; Arias-Purdue, A; Mehrotra, V; Kuramata, A; Sasaki, K; Watanabe, S; Koshi, K; Blevins, J; Bierwagen, O; Krishnamoorthy, S; Leedy, K; Arehart, AR; Neal, AT; Mou, S; Ringel, SA; Kumar, A; Sharma, A; Ghosh, K; Singisetti, U; Li, WS; Chabak, K; Liddy, K; Islam, A; Rajan, S; Graham, S; Choi, S; Cheng, Z; Higashiwaki, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Green, Andrew J.; Speck, James; Xing, Grace; Moens, Peter; Allerstam, Fredrik; Gumaelius, Krister; Neyer, Thomas; Arias-Purdue, Andrea; Mehrotra, Vivek; Kuramata, Akito; Sasaki, Kohei; Watanabe, Shinya; Koshi, Kimiyoshi; Blevins, John; Bierwagen, Oliver; Krishnamoorthy, Sriram; Leedy, Kevin; Arehart, Aaron R.; Neal, Adam T.; Mou, Shin; Ringel, Steven A.; Kumar, Avinash; Sharma, Ankit; Ghosh, Krishnendu; Singisetti, Uttam; Li, Wenshen; Chabak, Kelson; Liddy, Kyle; Islam, Ahmad; Rajan, Siddharth; Graham, Samuel; Choi, Sukwon; Cheng, Zhe; Higashiwaki, Masataka", "Book Author Full Names": null, "Group Authors": null, "Article Title": "β-Gallium oxide power electronics", "Source Title": "APL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gallium Oxide has undergone rapid technological maturation over the last decade, pushing it to the forefront of ultra-wide band gap semiconductor technologies. Maximizing the potential for a new semiconductor system requires a concerted effort by the community to address technical barriers which limit performance. Due to the favorable intrinsic material properties of gallium oxide, namely, critical field strength, widely tunable conductivity, mobility, and melt-based bulk growth, the major targeted application space is power electronics where high performance is expected at low cost. This Roadmap presents the current state-of-the-art and future challenges in 15 different topics identified by a large number of people active within the gallium oxide research community. Addressing these challenges will enhance the state-of-the-art device performance and allow us to design efficient, high-power, commercially scalable microelectronic systems using the newest semiconductor platform. (c) 2022 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license(http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2022, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29201, "DOI": "10.1063/5.0060327", "DOI Link": "http://dx.doi.org/10.1063/5.0060327", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754819400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, FF; Chen, MB; Song, WJ; Feng, ZP; Li, YL; Ding, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Fanfei; Chen, Mingbiao; Song, Wenji; Feng, Ziping; Li, Yongliang; Ding, Yulong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal management performances of PCM/water cooling-plate using for lithium-ion battery module based on non-uniform internal heat source", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to improve the working performance of the lithium-ion battery, the battery module with Phase change material/water cooling-plate was designed and numerically analyzed based on the energy conservation and fluid dynamics. The non-uniform internal heat source based on 2D electro-thermal model for battery LiFePO4/C was used to simulate the heat generation of each battery. Then factors such as height of water cooling-plate, space between adjacent batteries, inlet mass flow rate, flow direction, thermal conductivity and melting point of PCM were discussed to research their influences on the cooling performance of module. And the 5 continuous charge-discharge cycles was used to research the effect of PCM/water cooling plate on preventing thermal runaway. The results showed that the water cooling plate set close to the near-electrode area of battery removed the majority of heat generated during discharging and decreased the maximum temperature efficiently. The PCM between the adjacent batteries could improve the uniformity of temperature field. In addition, the PCM/water cooling plate could limit the maximum temperature effectively and improve the uniformity of temperature field during the 5 continuous charge-discharge cycles. As a result, it prevented the emergence of thermal runaway and increased the safety of module. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2017, "Volume": 126, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17, "End Page": 27, "Article Number": null, "DOI": "10.1016/j.applthermaleng.2017.07.141", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2017.07.141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412251200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, L; Griesbeck, S; Marder, TB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Lei; Griesbeck, Stefanie; Marder, Todd B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent developments in and perspectives on three-coordinate boron materials: a bright future", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The empty p(z)-orbital of a three-coordinate organoboron compound leads to its electron-deficient properties, which make it an excellent p-acceptor in conjugated organic chromophores. The empty p-orbital in such Lewis acids can be attacked by nucleophiles, so bulky groups are often employed to provide air-stable materials. However, many of these can still bind fluoride and cyanide anions leading to applications as anion-selective sensors. One electron reduction generates radical anions. The p-acceptor strength can be easily tuned by varying the organic substituents. Many of these compounds show strong two-photon absorption (TPA) and two-photon excited fluorescence (TPEF) behaviour, which can be applied for e.g. biological imaging. Furthermore, these chromophores can be used as emitters and electron transporters in OLEDs, and examples have recently been found to exhibit efficient thermally activated delayed fluorescence (TADF). The three-coordinate organoboron unit can also be incorporated into polycyclic aromatic hydrocarbons. Such boron-doped compounds exhibit very interesting properties, distinct from their all-carbon analogues. Significant developments have been made in all of these areas in recent years and new applications are rapidly emerging for this class of boron compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 558, "Times Cited, All Databases": 581, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 846, "End Page": 863, "Article Number": null, "DOI": "10.1039/c6sc04245g", "DOI Link": "http://dx.doi.org/10.1039/c6sc04245g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395428300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Patel, AK; Kaczmarek, JC; Bose, S; Kauffman, KJ; Mir, F; Heartlein, MW; DeRosa, F; Langer, R; Anderson, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Patel, Asha Kumari; Kaczmarek, James C.; Bose, Suman; Kauffman, Kevin J.; Mir, Faryal; Heartlein, Michael W.; DeRosa, Frank; Langer, Robert; Anderson, Daniel G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inhaled nulloformulated mRNA Polyplexes for Protein Production in Lung Epithelium", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noninvasive aerosol inhalation is an established method of drug delivery to the lung, and remains a desirable route for nucleic-acid-based therapeutics. In vitro transcribed (IVT) mRNA has broad therapeutic applicability as it permits temporal and dose-dependent control of encoded protein expression. Inhaled delivery of IVT-mRNA has not yet been demonstrated and requires development of safe and effective materials. To meet this need, hyperbranched poly(beta amino esters) (hPBAEs) are synthesized to enable nulloformulation of stable and concentrated polyplexes suitable for inhalation. This strategy achieves uniform distribution of luciferase mRNA throughout all five lobes of the lung and produces 101.2 ng g(-1) of luciferase protein 24 h after inhalation of hPBAE polyplexes. Importantly, delivery is localized to the lung, and no luminescence is observed in other tissues. Furthermore, using an Ai14 reporter mouse model it is identified that 24.6% of the total lung epithelial cell population is transfected after a single dose. Repeat dosing of inhaled hPBAE-mRNA generates consistent protein production in the lung, without local or systemic toxicity. The results indicate that nebulized delivery of IVT-mRNA facilitated by hPBAE vectors may provide a clinically relevant delivery system to lung epithelium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2019, "Volume": 31, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1805116, "DOI": "10.1002/adma.201805116", "DOI Link": "http://dx.doi.org/10.1002/adma.201805116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459798700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bonn, D; Denn, MM; Berthier, L; Divoux, T; Manneville, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bonn, Daniel; Denn, Morton M.; Berthier, Ludovic; Divoux, Thibaut; Manneville, Sebastien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Yield stress materials in soft condensed matter", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A comprehensive review is presented of the physical behavior of yield stress materials in soft condensed matter, which encompasses a broad range of materials from colloidal assemblies and gels to emulsions and non-Brownian suspensions. All these disordered materials display a nonlinear flow behavior in response to external mechanical forces due to the existence of a finite force threshold for flow to occur: the yield stress. Both the physical origin and rheological consequences associated with this nonlinear behavior are discussed and an overview is given of experimental techniques available to measure the yield stress. Recent progress is discussed concerning a microscopic theoretical description of the flow dynamics of yield stress materials, emphasizing, in particular, the role played by relaxation time scales, the interplay between shear flow and aging behavior, the existence of inhomogeneous shear flows and shear bands, wall slip, and nonlocal effects in confined geometries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 588, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2017, "Volume": 89, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35005, "DOI": "10.1103/RevModPhys.89.035005", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.89.035005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407999000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lothenbach, B; Kulik, DA; Matschei, T; Balonis, M; Baquerizo, L; Dilnesa, B; Miron, GD; Myers, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lothenbach, Barbara; Kulik, Dmitrii A.; Matschei, Thomas; Balonis, Magdalena; Baquerizo, Luis; Dilnesa, Belay; Miron, George D.; Myers, Rupert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cemdata 18: A chemical thermodynamic database for hydrated Portland cements and alkali-activated materials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermodynamic modelling can reliably predict hydrated cement phase assemblages and chemical compositions, including their interactions with prevailing service environments, provided an accurate and complete thermodynamic database is used. Here, we summarise the Cemdata18 database, which has been developed specifically for hydrated Portland, calcium aluminate, calcium sulfoaluminate and blended cements, as well as for alkali activated materials. It is available in GEMS and PHREEQC computer program formats, and includes thermodynamic properties determined from various experimental data published in recent years. Cemdata18 contains thermodynamic data for common cement hydrates such as C-S-H, AFm and AFt phases, hydrogarnet, hydrotalcite, zeolites, and M-S-H that are valid over temperatures ranging from 0 to at least 100 degrees C. Solid solution models for AFm, AFt, C-S-H, and M-S-H are also included in the Cemdata18 database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 750, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 115, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 472, "End Page": 506, "Article Number": null, "DOI": "10.1016/j.cemconres.2018.04.018", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2018.04.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452935100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsai, HH; Liu, FZ; Shrestha, S; Fernulldo, K; Tretiak, S; Scott, B; Vo, DT; Strzalka, J; Nie, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsai, Hsinhan; Liu, Fangze; Shrestha, Shreetu; Fernulldo, Kasun; Tretiak, Sergei; Scott, Brian; Duc Ta Vo; Strzalka, Joseph; Nie, Wanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state radiation detectors, using crystalline semiconductors to convert radiation photons to electrical charges, outperform other technologies with high detectivity and sensitivity. Here, we demonstrate a thin-film x-ray detector comprised with highly crystalline two-dimensional Ruddlesden-Popper phase layered perovskites fabricated in a fully depleted p-i-n architecture. It shows high diode resistivity of 10(12) ohm.cm in reverse-bias regime leading to a high x-ray detecting sensitivity up to 0.276 C Gy(air)(-1) cm(-3). Such high signal is collected by the built-in potential underpinning operation of primary photocurrent device with robust operation. The detectors generate substantial x-ray photon-induced open-circuit voltages that offer an alternative detecting mechanism. Our findings suggest a new generation of x-ray detectors based on low-cost layered perovskite thin films for future x-ray imaging technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay0815", "DOI": "10.1126/sciadv.aay0815", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay0815", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000525751400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JB; Zhang, HK; Weng, ST; Li, RH; Lu, D; Deng, T; Zhang, SQ; Lv, L; Qi, JC; Xiao, XZ; Fan, LW; Geng, SJ; Wang, FH; Chen, LX; Noked, M; Wang, XF; Fan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Junbo; Zhang, Haikuo; Weng, Suting; Li, Ruhong; Lu, Di; Deng, Tao; Zhang, Shuoqing; Lv, Ling; Qi, Jiacheng; Xiao, Xuezhang; Fan, Liwu; Geng, Shujiang; Wang, Fuhui; Chen, Lixin; Noked, Malachi; Wang, Xuefeng; Fan, Xiulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional solvent molecule design enables high-voltage Li-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The parasitic reactions at the electrolyte/electrode interfaces inhibit the increase of the charging cut-off voltage and the improvement of energy density. Herein, the authors design multifunctional solvent molecules and propose a practical design principle to stabilize the electrolyte/electrode interfaces for high-voltage Li ion batteries. Elevating the charging cut-off voltage is one of the efficient approaches to boost the energy density of Li-ion batteries (LIBs). However, this method is limited by the occurrence of severe parasitic reactions at the electrolyte/electrode interfaces. Herein, to address this issue, we design a non-flammable fluorinated sulfonate electrolyte by multifunctional solvent molecule design, which enables the formation of an inorganic-rich cathode electrolyte interphase (CEI) on high-voltage cathodes and a hybrid organic/inorganic solid electrolyte interphase (SEI) on the graphite anode. The electrolyte, consisting of 1.9 M LiFSI in a 1:2 v/v mixture of 2,2,2-trifluoroethyl trifluoromethanesulfonate and 2,2,2-trifluoroethyl methanesulfonate, endows 4.55 V-charged graphite||LiCoO2 and 4.6 V-charged graphite||NCM811 batteries with capacity retentions of 89% over 5329 cycles and 85% over 2002 cycles, respectively, thus resulting in energy density increases of 33% and 16% compared to those charged to 4.3 V. This work demonstrates a practical strategy for upgrading the commercial LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2211, "DOI": "10.1038/s41467-023-37999-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37999-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984481700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCoy, DE; Feo, T; Harvey, TA; Prum, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCoy, Dakota E.; Feo, Teresa; Harvey, Todd Alan; Prum, Richard O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural absorption by barbule microstructures of super black bird of paradise feathers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many studies have shown how pigments and internal nullostructures generate color in nature. External surface structures can also influence appearance, such as by causing multiple scattering of light (structural absorption) to produce a velvety, super black appearance. Here we show that feathers from five species of birds of paradise (Aves: Paradisaeidae) structurally absorb incident light to produce extremely low-reflectance, super black plumages. Directional reflectance of these feathers (0.05-0.31%) approaches that of man-made ultra-absorbent materials. SEM, nullo-CT, and ray-tracing simulations show that super black feathers have titled arrays of highly modified barbules, which cause more multiple scattering, resulting in more structural absorption, than normal black feathers. Super black feathers have an extreme directional reflectance bias and appear darkest when viewed from the distal direction. We hypothesize that structurally absorbing, super black plumage evolved through sensory bias to enhance the perceived brilliance of adjacent color patches during courtship display.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 529, "Times Cited, All Databases": 584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1, "DOI": "10.1038/s41467-017-02088-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02088-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419657800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, CY; Yang, XH; Xiong, PX; Lin, H; He, LJ; Yao, Q; Wei, MD; Qian, QR; Chen, QH; Zeng, LX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Chuyuan; Yang, Xuhui; Xiong, Peixun; Lin, Hui; He, Lingjun; Yao, Qi; Wei, Mingdeng; Qian, Qingrong; Chen, Qinghua; Zeng, Lingxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Rate, Large Capacity, and Long Life Dendrite-Free Zn Metal Anode Enabled by Trifunctional Electrolyte Additive with a Wide Temperature Range", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-ion batteries (AZIBs) have been recognized as promising energy storage devices due to their high theoretical energy density and cost-effectiveness. However, side reactions and Zn dendrite generation during cycling limit their practical application. Herein, ammonium acetate (CH3COONH4) is selected as a trifunctional electrolyte additive to enhance the electrochemical performance of AZIBs. Research findings show that NH4+ (oxygen ligand) and CH3COO- (hydrogenligand) with preferential adsorption on the Zn electrode surface can not only hinder Zn anode directly contact with active H2O, but also regulate the pH value of the electrolyte, thus suppressing the parasitic reactions. Additionally, the formed SEI is mainly consisted of Zn-5(CO3)(2)(OH)(6) with a high Zn2+ transference number, which could achieve a dendrite-free Zn anode by homogenizing Zn deposition. Consequently, the Zn||Zn symmetric batteries with CH3COONH4-based electrolyte can operate steadily at an ultrahigh current density of 40 mA cm(-2) with a cumulative capacity of 6880 mAh cm(-2), especially stable cycling at -10 degrees C. The assembled Zn||MnO2 full cell and Zn||activated carbon capacitor also deliver prominent electrochemical reversibility. This work provides unique understanding of designing multi-functional electrolyte additive and promotes a long lifespan at ultrahigh current density for AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 9, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201433, "DOI": "10.1002/advs.202201433", "DOI Link": "http://dx.doi.org/10.1002/advs.202201433", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805375100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lian, YB; Sun, H; Wang, XB; Qi, PW; Mu, QQ; Chen, YJ; Ye, J; Zhao, XH; Deng, Z; Peng, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lian, Yuebin; Sun, Hao; Wang, Xuebin; Qi, Pengwei; Mu, Qiaoqiao; Chen, Yujie; Ye, Jing; Zhao, Xiaohui; Deng, Zhao; Peng, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carved nulloframes of cobalt-iron bimetal phosphide as a bifunctional electrocatalyst for efficient overall water splitting", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water electrolysis for hydrogen production has long been regarded as an ideal tactic for renewable energy conversion and storage, but is impeded by the sluggish kinetics of both the hydrogen and oxygen evolution reactions, which are therefore in urgent need for high-performance but low-cost electrocatalysts. Herein, nulloframes of transition metal phosphides (TMPs) with the 3D framework carved open have been demonstrated as highly potent bifunctional catalysts for overall water splitting, reaching the benchmark performance of the Pt/CRuO2 couple, and are much superior to their nullocubic counterparts. This excellent water splitting behavior can be attributed to the enlarged active surface area, less obstructed electrolyte infiltration, promoted charge transfer, and facilitated gas release. Further through in-depth activity analysis and post-electrocatalysis characterization, special attention has been paid to the fate and role of phosphorus in the electrocatalytic process, suggesting that despite the chemical instability of the TMPs (especially under OER conditions), excellent electrocatalytic stability can still be achieved through the amorphous bimetallic hydroxides/oxides formed in situ.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2019, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 464, "End Page": 474, "Article Number": null, "DOI": "10.1039/c8sc03877e", "DOI Link": "http://dx.doi.org/10.1039/c8sc03877e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454938900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, YT; Qian, C; Fan, ZX; Cai, T; Li, EP; Chen, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Yuetian; Qian, Chao; Fan, Zhixiang; Cai, Tong; Li, Er-Ping; Chen, Hongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A knowledge-inherited learning for intelligent metasurface design and assembly", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent breakthroughs in deep learning have ushered in an essential tool for optics and photonics, recurring in various applications of material design, system optimization, and automation control. Deep learning-enabled on-demand metasurface design has been the subject of extensive expansion, as it can alleviate the time-consuming, low-efficiency, and experience-orientated shortcomings in conventional numerical simulations and physics-based methods. However, collecting samples and training neural networks are fundamentally confined to predefined individual metamaterials and tend to fail for large problem sizes. Inspired by object-oriented C++ programming, we propose a knowledge-inherited paradigm for multi-object and shape-unbound metasurface inverse design. Each inherited neural network carries knowledge from the parent metasurface and then is freely assembled to construct the offspring metasurface; such a process is as simple as building a container-type house. We benchmark the paradigm by the free design of aperiodic and periodic metasurfaces, with accuracies that reach 86.7%. Furthermore, we present an intelligent origami metasurface to facilitate compatible and lightweight satellite communication facilities. Our work opens up a new avenue for automatic metasurface design and leverages the assemblability to broaden the adaptability of intelligent metadevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 82, "DOI": "10.1038/s41377-023-01131-4", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01131-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000960368100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, HX; Quhe, RG; Wang, YY; Ni, ZY; Ye, M; Song, ZG; Pan, YY; Yang, JB; Yang, L; Lei, M; Shi, JJ; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Hongxia; Quhe, Ruge; Wang, Yangyang; Ni, Zeyuan; Ye, Meng; Song, Zhigang; Pan, Yuanyuan; Yang, Jinbo; Yang, Li; Lei, Ming; Shi, Junjie; Lu, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Properties of Monolayer and Bilayer MoS2 Contacts with Metals: Beyond the Energy Band Calculations", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although many prototype devices based on two-dimensional (2D) MoS2 have been fabricated and wafer scale growth of 2D MoS2 has been realized, the fundamental nature of 2D MoS2-metal contacts has not been well understood yet. We provide a comprehensive ab initio study of the interfacial properties of a series of monolayer (ML) and bilayer (BL) MoS2-metal contacts (metal = Sc, Ti, Ag, Pt, Ni, and Au). A comparison between the calculated and observed Schottky barrier heights (SBHs) suggests that many-electron effects are strongly suppressed in channel 2D MoS2 due to a charge transfer. The extensively adopted energy band calculation scheme fails to reproduce the observed SBHs in 2D MoS2-Sc interface. By contrast, an ab initio quantum transport device simulation better reproduces the observed SBH in 2D MoS2-Sc interface and highlights the importance of a higher level theoretical approach beyond the energy band calculation in the interface study. BL MoS2-metal contacts generally have a reduced SBH than ML MoS2-metal contacts due to the interlayer coupling and thus have a higher electron injection efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21786, "DOI": "10.1038/srep21786", "DOI Link": "http://dx.doi.org/10.1038/srep21786", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371039400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, W; Wong, KHM; Shen, J; Wang, WH; Wu, J; Li, JH; Lin, ZJ; Chen, ZT; Matinlinna, JP; Zheng, YF; Wu, SL; Liu, XY; Lai, KP; Chen, ZF; Lam, YW; Cheung, KMC; Yeung, KWK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Wei; Wong, Karen H. M.; Shen, Jie; Wang, Wenhao; Wu, Jun; Li, Jinhua; Lin, Zhengjie; Chen, Zetao; Matinlinna, Jukka P.; Zheng, Yufeng; Wu, Shuilin; Liu, Xuanyong; Lai, Keng Po; Chen, Zhuofan; Lam, Yun Wah; Cheung, Kenneth M. C.; Yeung, Kelvin W. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "TRPM7 kinase-mediated immunomodulation in macrophage plays a central role in magnesium ion-induced bone regeneration", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the widespread observations on the osteogenic effects of magnesium ion (Mg2+), the diverse roles of Mg2+ during bone healing have not been systematically dissected. Here, we reveal a previously unknown, biphasic mode of action of Mg2+ in bone repair. During the early inflammation phase, Mg2+ contributes to an upregulated expression of transient receptor potential cation channel member 7 (TRPM7), and a TRPM7-dependent influx of Mg2+ in the monocyte-macrophage lineage, resulting in the cleavage and nuclear accumulation of TRPM7-cleaved kinase fragments (M7CKs). This then triggers the phosphorylation of Histone H3 at serine 10, in a TRPM7-dependent manner at the promoters of inflammatory cytokines, leading to the formation of a pro-osteogenic immune microenvironment. In the later remodeling phase, however, the continued exposure of Mg2+ not only lead to the over-activation of NF-kappa B signaling in macrophages and increased number of osteoclastic-like cells but also decelerates bone maturation through the suppression of hydroxyapatite precipitation. Thus, the negative effects of Mg2+ on osteogenesis can override the initial pro-osteogenic benefits of Mg2+. Taken together, this study establishes a paradigm shift in the understanding of the diverse and multifaceted roles of Mg2+ in bone healing. Supplementation of magnesium (Mg2+) or its inclusion in biomaterials has beneficial effects for bone formation, but it has also been reported that it can have detrimental effects. Here, the authors analyse dose- and time-dependent effects of Mg2+ on bone regeneration and show that it can stimulate monocyte-macrophage lineage cells to support bone formation in the early phases of repair, but inhibit bone repair and mineralization in later stages by promoting a pro-inflammatory environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2885, "DOI": "10.1038/s41467-021-23005-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23005-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658736300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hirai, H; Nakajima, K; Nakatsuka, S; Shiren, K; Ni, J; Nomura, S; Ikuta, T; Hatakeyama, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hirai, Hiroki; Nakajima, Kiichi; Nakatsuka, Soichiro; Shiren, Kazushi; Ni, Jingping; Nomura, Shintaro; Ikuta, Toshiaki; Hatakeyama, Takuji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Step Borylation of 1,3-Diaryloxybenzenes Towards Efficient Materials for Organic Light-Emitting Diodes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of a one-step borylation of 1,3-diaryloxybenzenes, yielding novel boron-containing polycyclic aromatic compounds, is reported. The resulting boron-containing compounds possess high singlet-triplet excitation energies as a result of localized frontier molecular orbitals induced by boron and oxygen. Using these compounds as a host material, we successfully prepared phosphorescent organic light-emitting diodes exhibiting high efficiency and adequate lifetimes. Moreover, using the present one-step borylation, we succeeded in the synthesis of an efficient, thermally activated delayed fluorescence emitter and boron-fused benzo[6]helicene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2015, "Volume": 54, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13581, "End Page": 13585, "Article Number": null, "DOI": "10.1002/anie.201506335", "DOI Link": "http://dx.doi.org/10.1002/anie.201506335", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364395100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Feng, XN; Peng, Y; Zhang, FK; Ren, DS; Liu, X; Lu, LG; Nitta, Y; Wang, L; Ouyang, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yu; Feng, Xuning; Peng, Yong; Zhang, Fukui; Ren, Dongsheng; Liu, Xiang; Lu, Languang; Nitta, Yoshiaki; Wang, Li; Ouyang, Minggao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reductive gas manipulation at early self-heating stage enables controllable battery thermal failure", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Li-ion batteries are regarded as unsafe due to the volatility and flammability of the organic liquid electrolytes. However, research on substitutes (solid, inorganic, etc.) still encounters tough obstacles toward commercialization. Here, we manage to control the thermal failure process of liquid batteries by manipulating the deleterious reactions at an earlier stage, where heat accumulates mildly before accelerating to catastrophes. We reveal that the reductive gases, specifically those with low bond dissociation energies (unsaturated hydrocarbons as alkenes and alkynes), can induce cathode crystal change with oxygen release and initiate and accelerate battery thermal failure from lower than 80 degrees C. Four safety countermeasures to break this reductive attackpathway are designed and successfully prevent commercial Li-ion batteries from thermal runaway (capacity of 60 Ah and energy density of 280 Wh kg -1). We anticipate that our new safety insights and methodologies will overcome the limitations of liquid electrolytes for safe energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2022, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2810, "End Page": 2820, "Article Number": null, "DOI": "10.1016/j.joule.2022.10.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.10.010", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000910663900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, SB; Alvi, NU; Granlöf, L; Granberg, H; Berggren, M; Fabiano, S; Crispin, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Shaobo; Alvi, Naveed Ul Hassan; Granlof, Lars; Granberg, Hjalmar; Berggren, Magnus; Fabiano, Simone; Crispin, Xavier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Multiparameter Pressure-Temperature-Humidity Sensor Based on Mixed Ionic-Electronic Cellulose Aerogels", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure (P), temperature (T), and humidity (H) are physical key parameters of great relevance for various applications such as in distributed diagnostics, robotics, electronic skins, functional clothing, and many other Internet-of-Things (IoT) solutions. Previous studies on monitoring and recording these three parameters have focused on the integration of three individual single-parameter sensors into an electronic circuit, also comprising dedicated sense amplifiers, signal processing, and communication interfaces. To limit complexity in, e.g., multifunctional IoT systems, and thus reducing the manufacturing costs of such sensing/communication outposts, it is desirable to achieve one single-sensor device that simultaneously or consecutively measures P-T-H without cross-talks in the sensing functionality. Herein, a novel organic mixed ion-electron conducting aerogel is reported, which can sense P-T-H with minimal cross-talk between the measured parameters. The exclusive read-out of the three individual parameters is performed electronically in one single device configuration and is enabled by the use of a novel strategy that combines electronic and ionic Seebeck effect along with mixed ion-electron conduction in an elastic aerogel. The findings promise for multipurpose IoT technology with reduced complexity and production costs, features that are highly anticipated in distributed diagnostics, monitoring, safety, and security applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802128, "DOI": "10.1002/advs.201802128", "DOI Link": "http://dx.doi.org/10.1002/advs.201802128", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464827300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bandres, MA; Wittek, S; Harari, G; Parto, M; Ren, JH; Segev, M; Christodoulides, DN; Khajavikhan, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bandres, Miguel A.; Wittek, Steffen; Harari, Gal; Parto, Midya; Ren, Jinhan; Segev, Mordechai; Christodoulides, Demetrios N.; Khajavikhan, Mercedeh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological insulator laser: Experiments", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Physical systems exhibiting topological invariants are naturally endowed with robustness against perturbations, as manifested in topological insulators-materials exhibiting robust electron transport, immune from scattering by defects and disorder. Recent years have witnessed intense efforts toward exploiting these phenomena in photonics. Here we demonstrate a nonmagnetic topological insulator laser system exhibiting topologically protected transport in the cavity. Its topological properties give rise to single-mode lasing, robustness against defects, and considerably higher slope efficiencies compared to the topologically trivial counterparts. We further exploit the properties of active topological platforms by assembling the system from S-chiral microresonators, enforcing predetermined unidirectional lasing without magnetic fields. This work paves the way toward active topological devices with exciting properties and functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2018, "Volume": 359, "Issue": 6381, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar4005", "DOI": "10.1126/science.aar4005", "DOI Link": "http://dx.doi.org/10.1126/science.aar4005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435220800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XX; Meng, Y; Tian, JX; Huang, YZ; Xiang, H; Han, DZ; Wen, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaoxiao; Meng, Yan; Tian, Jingxuan; Huang, Yingzhou; Xiang, Hong; Han, Dezhuan; Wen, Weijia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of valley-polarized topological edge states in designer surface plasmon crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The extensive research of two-dimensional layered materials has revealed that valleys, as energy extrema in momentum space, could offer a new degree of freedom for carrying information. Based on this concept, researchers have predicted valley-Hall topological insulators that could support valley-polarized edge states at non-trivial domain walls. Recently, several kinds of photonic and sonic crystals have been proposed as classical counterparts of valley-Hall topological insulators. However, direct experimental observation of valley-polarized edge states in photonic crystals has remained difficult until now. Here, we demonstrate a designer surface plasmon crystal comprising metallic patterns deposited on a dielectric substrate, which can become a valley-Hall photonic topological insulator by exploiting the mirror-symmetry-breaking mechanism. Topological edge states with valley-dependent transport are directly visualized in the microwave regime. The observed edge states are confirmed to be fully valley-polarized through spatial Fourier transforms. Topological protection of the edge states at sharp corners is also experimentally demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1304, "DOI": "10.1038/s41467-017-01515-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01515-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414376900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CH; Wang, FQ; Meng, YF; Yuan, X; Xiu, FX; Luo, HY; Wang, YZ; Li, JF; Lv, XJ; He, L; Xu, YB; Liu, JF; Zhang, C; Shi, Y; Zhang, R; Zhu, SN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Chunhui; Wang, Fengqiu; Meng, Yafei; Yuan, Xiang; Xiu, Faxian; Luo, Hongyu; Wang, Yazhou; Li, Jianfeng; Lv, Xinjie; He, Liang; Xu, Yongbing; Liu, Junfeng; Zhang, Chao; Shi, Yi; Zhang, Rong; Zhu, Shining", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust and tuneable mid-infrared optical switch enabled by bulk Dirac fermions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pulsed lasers operating in the mid-infrared (3-20 mu m) are important for a wide range of applications in sensing, spectroscopy, imaging and communications. Despite recent advances with mid-infrared gain platforms, the lack of a capable pulse generation mechanism remains a significant technological challenge. Here we show that bulk Dirac fermions in molecular beam epitaxy grown crystalline Cd3As2, a three-dimensional topological Dirac semimetal, constitutes an exceptional ultrafast optical switching mechanism for the mid-infrared. Significantly, we show robust and effective tuning of the scattering channels of Dirac fermions via an element doping approach, where photocarrier relaxation times are found flexibly controlled over an order of magnitude (from 8 ps to 800 fs at 4.5 mu m). Our findings reveal the strong impact of Cr doping on ultrafast optical properties in Cd3As2 and open up the long sought parameter space crucial for the development of compact and high-performance mid-infrared ultrafast sources.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14111, "DOI": "10.1038/ncomms14111", "DOI Link": "http://dx.doi.org/10.1038/ncomms14111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392540100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Carrier Mobilities in Metal Halide Perovskites: Fundamental Mechanisms and Limits", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite photovoltaic cells have seen a remarkable rise in power conversion efficiencies over a period of only a few years. Much of this performance is underpinned by the favorable charge carrier mobilities in metal halide perovskites (MHPs), which are remarkably high for materials with such facile and versatile processing routes. This Perspective outlines the mechanisms that set a fundamental upper limit to charge-carrier mobility values in MHPs and reveals how they may be tuned through changes in stoichiometry. In addition, extrinsic effects such as grain size, energetic disorder, and self-doping are discussed for specific MHPs in the context of remedies designed to avoid them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1025, "Times Cited, All Databases": 1089, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1539, "End Page": 1548, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00276", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405979900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JZ; Sharma, N; Jiang, ZS; Yang, Y; Monaco, F; Xu, ZR; Hou, D; Ratner, D; Pianetta, P; Cloetens, P; Lin, F; Zhao, KJ; Liu, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jizhou; Sharma, Nikhil; Jiang, Zhisen; Yang, Yang; Monaco, Federico; Xu, Zhengrui; Hou, Dong; Ratner, Daniel; Pianetta, Piero; Cloetens, Peter; Lin, Feng; Zhao, Kejie; Liu, Yijin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamics of particle network in composite battery cathodes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving composite battery electrodes requires a delicate control of active materials and electrode formulation. The electrochemically active particles fulfill their role as energy exchange reservoirs through interacting with the surrounding conductive network. We formulate a network evolution model to interpret the regulation and equilibration between electrochemical activity and mechanical damage of these particles. Through statistical analysis of thousands of particles using x-ray phase contrast holotomography in a LiNi0.8Mn0.1Co0.1O2-based cathode, we found that the local network heterogeneity results in asynchronous activities in the early cycles, and subsequently the particle assemblies move toward a synchronous behavior. Our study pinpoints the chemomechanical behavior of individual particles and enables better designs of the conductive network to optimize the utility of all the particles during operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2022, "Volume": 376, "Issue": 6592, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 517, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm8962", "DOI Link": "http://dx.doi.org/10.1126/science.abm8962", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791247600075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Laird, EA; Kuemmeth, F; Steele, GA; Grove-Rasmussen, K; Nygård, J; Flensberg, K; Kouwenhoven, LP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Laird, Edward A.; Kuemmeth, Ferdinulld; Steele, Gary A.; Grove-Rasmussen, Kasper; Nygard, Jesper; Flensberg, Karsten; Kouwenhoven, Leo P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum transport in carbon nullotubes", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nullotubes are a versatile material in which many aspects of condensed matter physics come together. Recent discoveries have uncovered new phenomena that completely change our understanding of transport in these devices, especially the role of the spin and valley degrees of freedom. This review describes the modern understanding of transport through nullotube devices. Unlike in conventional semiconductors, electrons in nullotubes have two angular momentum quantum numbers, arising from spin and valley freedom. The interplay between the two is the focus of this review. The energy levels associated with each degree of freedom, and the spin-orbit coupling between them, are explained, together with their consequences for transport measurements through nullotube quantum dots. In double quantum dots, the combination of quantum numbers modifies the selection rules of Pauli blockade. This can be exploited to read out spin and valley qubits and to measure the decay of these states through coupling to nuclear spins and phonons. A second unique property of carbon nullotubes is that the combination of valley freedom and electron-electron interactions in one dimension strongly modifies their transport behavior. Interaction between electrons inside and outside a quantum dot is manifested in SU(4) Kondo behavior and level renormalization. Interaction within a dot leads to Wigner molecules and more complex correlated states. This review takes an experimental perspective informed by recent advances in theory. As well as the well-understood overall picture, open questions for the field are also clearly stated. These advances position nullotubes as a leading system for the study of spin and valley physics in one dimension where electronic disorder and hyperfine interaction can both be reduced to a low level.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2015, "Volume": 87, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 703, "End Page": 764, "Article Number": null, "DOI": "10.1103/RevModPhys.87.703", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.87.703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358610500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, A; Xie, RK; Zhang, Y; Feng, YL; Wang, WZ; Zhang, SF; Huang, ZA; Zhu, LH; Chai, GL; Yang, ZQ; Gao, QS; Ye, HQ; Shang, CX; Chen, BH; Guo, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, An; Xie, Ruikuan; Zhang, Yun; Feng, Yingliang; Wang, Weizhen; Zhang, Sifan; Huang, Zinull; Zhu, Lihua; Chai, Guoliang; Yang, Zhiqing; Gao, Qingsheng; Ye, Hengqiang; Shang, Congxiao; Chen, Bing Hui; Guo, Zhengxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effective electronic tuning of Pt single atoms via heterogeneous atomic coordination of (Co,Ni)(OH)2 for efficient hydrogen evolution", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydroxide-supported atomic structures, particularly single atoms, offer a wide scope for active microenvironmental tuning to enhance the catalytic performance, but little has been explored on the electronic synergy between mono- and dual-hydroxides. Here, we propose a way of constructing a Pt-1/(Co,Ni)(OH)(2)/C single-atom catalyst (SAC), with Pt single-atoms, Pt-1, stabilized and anchored on the surface of defective (Co,Ni)(OH)(2), which is further supported on carbon black. This catalyst exhibits a far superior hydrogen evolution reaction (HER) activity to Pt-1/Co(OH)(2)/C, Pt-1/Ni(OH)(2)/C, Pt-1/C, and the commercial 20 wt% Pt/C. Particularly, it shows an almost zero onset overpotential and an outstanding electrocatalytic mass activity for the HER, 29.7 times higher than that of Pt-1/C and 115.9 times higher than that of the commercial 20 wt% Pt/C at -0.09 V vs. RHE, respectively. There is negligible attenuation after the chronopotentiometry test at 100 mA cm(-2) for 24 h and cyclic voltammetry for 20 000 cycles. Operando Raman spectra clarified that the Volmer step for water decomposition (the H-OH bond breaking) takes place around the defective sites of (Co,Ni)(OH)(2). Density functional theory (DFT) calculations confirmed the electronic synergy between the Pt single atoms and bimetallic (Co,Ni)(OH)(2), which leads to stable anchoring of Pt and yields an appropriate adsorption energy of *H, leading to rapid H-2 generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2023, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1035, "End Page": 1048, "Article Number": null, "DOI": "10.1039/d2ee02785b", "DOI Link": "http://dx.doi.org/10.1039/d2ee02785b", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000912021200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, JW; Xie, XS; Liang, SQ; Lu, BA; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Jiawei; Xie, Xuesong; Liang, Shuquan; Lu, Bingan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inorganic Colloidal Electrolyte for Highly Robust Zinc-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsThe Zn/MnO2 cell with inorganic colloidal electrolyte demonstrates unprecedented durability over 1000 cycles.For the cathode, the presence of the protective film can inhibit the dissolution of manganese element and the formation of irreversible by-products.For the anode, it can reduce the corrosion and de-solvation energy, inhibit the growth of dendrite and irreversible by-products. AbstractZinc-ion batteries (ZIBs) is a promising electrical energy storage candidate due to its eco-friendliness, low cost, and intrinsic safety, but on the cathode the element dissolution and the formation of irreversible products, and on the anode the growth of dendrite as well as irreversible products hinder its practical application. Herein, we propose a new type of the inorganic highly concentrated colloidal electrolytes (HCCE) for ZIBs promoting simultaneous robust protection of both cathode/anode leading to an effective suppression of element dissolution, dendrite, and irreversible products growth. The new HCCE has high Zn2+ ion transference number (0.64) endowed by the limitation of SO42-, the competitive ion conductivity (1.1x10(-2) S cm(-1)) and Zn2+ ion diffusion enabled by the uniform pore distribution (3.6 nm) and the limited free water. The Zn/HCCE/alpha -MnO2 cells exhibit high durability under both high and low current densities, which is almost 100% capacity retention at 200 mA g(-1) after 400 cycles (290 mAh g(-1)) and 89% capacity retention under 500 mA g(-1) after 1000 cycles (212 mAh g(-1)). Considering material sustainability and batteries' high performances, the colloidal electrolyte may provide a feasible substitute beyond the liquid and all-solid-state electrolyte of ZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 69, "DOI": "10.1007/s40820-021-00595-6", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00595-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620057300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gartner, TE; Jayaraman, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gartner, Thomas E., III; Jayaraman, Arthi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling and Simulations of Polymers: A Roadmap", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular modeling and simulations are invaluable tools for the polymer science and engineering community. These computational approaches enable predictions and provide explanations of experimentally observed macro molecular structure, dynamics, thermodynamics, and microscopic and macroscopic material properties. With recent advances in computing power, polymer simulations can synergistically inform, guide, and complement in vitro macromolecular materials design and discovery efforts. To ensure that this growing power of simulations is harnessed correctly, and meaningful results are achieved, care must be taken to ensure the validity and reproducibility of these simulations. With these considerations in mind, in this Perspective we discuss our philosophy for carefully developing or selecting appropriate models, performing, and analyzing polymer simulations. We highlight best practices, key challenges, and important advances in model development/selection, computational method choices, advanced sampling methods, and data analysis, with the goal of educating potential polymer simulators about ways to improve the validity, usefulness, and impact of their polymer computational research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2019, "Volume": 52, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 755, "End Page": 786, "Article Number": null, "DOI": "10.1021/acs.macromol.8b01836", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.8b01836", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458937700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Li, L; Shi, JH; Xie, MY; Nie, JH; Huang, GF; Li, B; Hu, WY; Pan, AL; Huang, WQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yu-Han; Li, Lei; Shi, Jinghui; Xie, Meng-Yuan; Nie, Jianhang; Huang, Gui-Fang; Li, Bo; Hu, Wangyu; Pan, Anlian; Huang, Wei-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen Defect Engineering Promotes Synergy Between Adsorbate Evolution and Single Lattice Oxygen Mechanisms of OER in Transition Metal-Based (oxy)Hydroxide", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The oxygen evolution reaction (OER) activity of transition metal (TM)-based (oxy)hydroxide is dominated by the number and nature of surface active sites, which are generally considered to be TM atoms occupying less than half of surface sites, with most being inactive oxygen atoms. Herein, based on an in situ competing growth strategy of bimetallic ions and OH- ions, a facile one-step method is proposed to modulate oxygen defects in NiFe-layered double hydroxide (NiFe-LDH)/FeOOH heterostructure, which may trigger the single lattice oxygen mechanism (sLOM). Interestingly, by only varying the addition of H2O2, one can simultaneously regulate the concentration of oxygen defects, the valence of metal sites, and the ratio of components. The proper oxygen defects promote synergy between the adsorbate evolution mechanism (AEM, metal redox chemistry) and sLOM (oxygen redox chemistry) of OER in NiFe-based (oxy)hydroxide, practically maximizing the use of surface TM and oxygen atoms as active sites. Consequently, the optimal NiFe-LDH/FeOOH heterostructure outperforms the reported non-noble OER catalysts in electrocatalytic activity, with an overpotential of 177 mV to deliver a current density of 20 mA cm-2 and high stability. The novel strategy exemplifies a facile and versatile approach to designing highly active TM-LDH-based OER electrocatalysts for energy and environmental applications. The proper oxygen defects promote the synergy between the adsorbate evolution mechanism (AEM) and single lattice oxygen mechanism (sLOM) of OER in NiFe-based (oxy)hydroxide has been demonstrated, which can nearly maximize the use of surface metal and oxygen atoms as active sites, contributing ultralow overpotential of 177 mV (eta 20) and long-term stability over 60 h, outmatching the reported non-noble OER catalysts so far.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202303321", "DOI Link": "http://dx.doi.org/10.1002/advs.202303321", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078004300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cherevan, AS; nulldan, SP; Roger, I; Liu, RJ; Streb, C; Eder, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cherevan, Alexey S.; nulldan, Sreejith P.; Roger, Isolda; Liu, Rongji; Streb, Carsten; Eder, Dominik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground-breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular-level understanding of POM-support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting-edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nullo- and micrometer level are discussed. Future development in this fast-moving field is explored and emerging fields of research in POM heterogenization are identified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903511, "DOI": "10.1002/advs.201903511", "DOI Link": "http://dx.doi.org/10.1002/advs.201903511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529216500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, X; Zhou, JH; Zhang, WS; Du, ZL; Liu, C; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xu; Zhou, Jianhua; Zhang, Weisheng; Du, Zongliang; Liu, Chang; Liu, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-supporting structure design in additive manufacturing through explicit topology optimization", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the challenging issues in additive manufacturing (AM) oriented topology optimization is how to design structures that are self-supportive in a manufacture process without introducing additional supporting materials. In the present contribution, it is intended to resolve this problem under an explicit topology optimization framework where optimal structural topology can be found by optimizing a set of explicit geometry parameters. Two solution approaches established based on the Moving Morphable Components (MMC) and Moving Morphable Voids (MMV) frameworks, respectively, are proposed and some theoretical issues associated with AM oriented topology optimization are also analyzed. Numerical examples provided demonstrate the effectiveness of the proposed methods. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2017, "Volume": 323, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 27, "End Page": 63, "Article Number": null, "DOI": "10.1016/j.cma.2017.05.003", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2017.05.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406570900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krauskopf, T; Mogwitz, B; Rosenbach, C; Zeier, WC; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krauskopf, Thorben; Mogwitz, Boris; Rosenbach, Carolin; Zeier, Wolfgang C.; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diffusion Limitation of Lithium Metal and Li-Mg Alloy Anodes on LLZO Type Solid Electrolytes as a Function of Temperature and Pressure", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The morphological instability of the lithium metal anode is the key factor restricting the rate capability of lithium metal solid state batteries. During lithium stripping, pore formation takes place at the interface due to the slow diffusion kinetics of vacancies in the lithium metal. The resulting current focusing increases the internal cell resistance and promotes fast lithium penetration. In this work, galvanostatic electrochemical impedance spectroscopy is used to investigate operando the morphological changes at the interface by analysis of the interface capacitances. Therewith, the effect of temperature, stack pressure, and chemical modification is investigated. The work demonstrates that introducing 10 at% Mg into the lithium metal anode can effectively prevent contact loss. Nevertheless, a fundamental kinetic limitation is also observed for the Li-rich alloy, namely the diffusion controlled decrease of the lithium metal concentration at the interface. An analytical diffusion model is used to describe the temperature-dependent delithiation kinetics of Li-Mg alloys. Overall, it is shown that different electrode design concepts should be considered. Mg alloying can increase lithium utilization, when no external pressure is applied while pure lithium metal is superior for setups that allow stack pressures in the MPa range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 9, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902568, "DOI": "10.1002/aenm.201902568", "DOI Link": "http://dx.doi.org/10.1002/aenm.201902568", "Book DOI": null, "Early Access Date": "OCT 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489143900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, L; Khajehtourian, R; Mueller, J; Rafsanjani, A; Tournat, V; Bertoldi, K; Kochmann, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Lishuai; Khajehtourian, Romik; Mueller, Jochen; Rafsanjani, Ahmad; Tournat, Vincent; Bertoldi, Katia; Kochmann, Dennis M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Guided transition waves in multistable mechanical metamaterials", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition fronts, moving through solids and fluids in the form of propagating domain or phase boundaries, have recently been mimicked at the structural level in bistable architectures. What has been limited to simple one-dimensional (1D) examples is here cast into a blueprint for higher dimensions, demonstrated through 2D experiments and described by a continuum mechanical model that draws inspiration from phase transition theory in crystalline solids. Unlike materials, the presented structural analogs admit precise control of the transition wave's direction, shape, and velocity through spatially tailoring the underlying periodic network architecture (locally varying the shape or stiffness of the fundamental building blocks, and exploiting interactions of transition fronts with lattice defects such as point defects and free surfaces). The outcome is a predictable and programmable strongly nonlinear metamaterial motion with potential for, for example, propulsion in soft robotics, morphing surfaces, reconfigurable devices, mechanical logic, and controlled energy absorption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2020, "Volume": 117, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2319, "End Page": 2325, "Article Number": null, "DOI": "10.1073/pnas.1913228117", "DOI Link": "http://dx.doi.org/10.1073/pnas.1913228117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512340900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Menon, AK; Haechler, I; Kaur, S; Lubner, S; Prasher, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Menon, Akanksha K.; Haechler, Iwan; Kaur, Sumanjeet; Lubner, Sean; Prasher, Ravi S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced solar evaporation using a photo-thermal umbrella for wastewater management", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By passively evaporating water from waste streams, evaporation ponds work with different waste streams but need large areas due to low evaporation rates. This study shows that a photo-thermal device converting sunlight into mid-infrared radiation could enhance evaporation and reduce land needs. Zero-liquid discharge is an emerging wastewater management strategy that maximizes water recovery for reuse and produces a solid waste, thereby lowering the environmental impact of wastewater disposal. Evaporation ponds harvest solar energy as heat for zero-liquid discharge, but require large land areas due to low evaporation rates. Here, we demonstrate a passive and non-contact approach to enhance evaporation by more than 100% using a photo-thermal device that converts sunlight into mid-infrared radiation where water is strongly absorbing. As a result, heat is localized at the water's surface through radiative coupling, resulting in better utilization of solar energy with a conversion efficiency of 43%. The non-contact nature of the device makes it uniquely suited to treat a wide range of wastewater without contamination, and the use of commercial materials enables a potentially low-cost and highly scalable technology for sustainable wastewater management, with the added benefit of salt recovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 144, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41893-019-0445-5", "DOI Link": "http://dx.doi.org/10.1038/s41893-019-0445-5", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507792200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, J; Huang, TY; Cheng, P; Zou, YP; Zhang, HT; Yang, JL; Chang, SY; Zhang, ZZ; Huang, WC; Wang, R; Meng, D; Gao, F; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Jun; Huang, Tianyi; Cheng, Pei; Zou, Yingping; Zhang, Huotian; Yang, Jonathan Lee; Chang, Sheng-Yung; Zhang, Zhenzhen; Huang, Wenchao; Wang, Rui; Meng, Dong; Gao, Feng; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite significant development recently, improving the power conversion efficiency of organic photovoltaics (OPVs) is still an ongoing challenge to overcome. One of the prerequisites to achieving this goal is to enable efficient charge separation and small voltage losses at the same time. In this work, a facile synthetic strategy is reported, where optoelectronic properties are delicately tuned by the introduction of electron-deficient-core-based fused structure into non-fullerene acceptors. Both devices exhibited a low voltage loss of 0.57 V and high short-circuit current density of 22.0 mA cm(-2), resulting in high power conversion efficiencies of over 13.4%. These unconventional electron-deficient-core-based non-fullerene acceptors with near-infrared absorption lead to low non-radiative recombination losses in the resulting organic photovoltaics, contributing to a certified high power conversion efficiency of 12.6%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 570, "DOI": "10.1038/s41467-019-08386-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08386-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457582900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "May, AF; Calder, S; Cantoni, C; Cao, HB; McGuire, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "May, Andrew F.; Calder, Stuart; Cantoni, Claudia; Cao, Huibo; McGuire, Michael A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic structure and phase stability of the van der Waals bonded ferromagnet Fe3-xGeTe2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The magnetic structure and phase diagram of the layered ferromagnetic compound Fe3GeTe2 has been investigated by a combination of synthesis, x-ray and neutron diffraction, high-resolution microscopy, and magnetization measurements. Single crystals were synthesized by self-flux reactions, and single-crystal neutron diffraction finds ferromagnetic order with moments of 1.11(5)mu B/Fe aligned along the c axis at 4 K. These flux-grown crystals have a lower Curie temperature T-c approximate to 150 K compared to crystals previously grown by vapor transport (T-c = 220 K). The difference is a reduced Fe content in the flux-grown crystals, as illustrated by the behavior observed in a series of polycrystalline samples. As Fe content decreases, so does the Curie temperature, magnetic anisotropy, and net magnetization. In addition, Hall effect and thermoelectric measurements on flux-grown crystals suggest multiple carrier types contribute to electrical transport in Fe3-xGeTe2 and structurally similar Ni3-xGeTe2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 93, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14411, "DOI": "10.1103/PhysRevB.93.014411", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.014411", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367779000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nielsen, CB; Giovannitti, A; Sbircea, DT; Bandiello, E; Niazi, MR; Hanifi, DA; Sessolo, M; Amassian, A; Malliaras, GG; Rivnay, J; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nielsen, Christian B.; Giovannitti, Alexander; Sbircea, Dan-Tiberiu; Bandiello, Enrico; Niazi, Muhammad R.; Hanifi, David A.; Sessolo, Michele; Amassian, Aram; Malliaras, George G.; Rivnay, Jonathan; McCulloch, Iain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular Design of Semiconducting Polymers for High-Performance Organic Electrochemical Transistors", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The organic electrochemical transistor (OECT), capable of transducing small ionic fluxes into electronic signals in an aqueous environment, is an ideal device to utilize in bioelectronic applications. Currently, most OECTs are fabricated with commercially available conducting poly(3,4-ethylenedioxythiophene) (PEDOT)based suspensions and are therefore operated in depletion mode. we present a series of semiconducting polymers designed to elucidate important structure property guidelines required for accumulation mode OECT operation. We discuss key aspects relating to QECT performance such as ion and hole transport, electrochromic properties, operational voltage, and stability.. The demonstration of Our molecular design strategy is the fabrication of accumulation mode OECTs that clearly outperform state-of-the-art PEDOT-based devices, and show stability under aqueous operation without the need,for formulation additives and cross-linkers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2016, "Volume": 138, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10252, "End Page": 10259, "Article Number": null, "DOI": "10.1021/jacs.6b05280", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b05280", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381715700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, YY; Guo, YB; Zhang, QM; Xie, ZJ; Wei, JP; Zhou, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Yuanyuan; Guo, Yibo; Zhang, Qinming; Xie, Zhaojun; Wei, Jinping; Zhou, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOF-Derived Co and Fe Species Loaded on N-Doped Carbon Networks as Efficient Oxygen Electrocatalysts for Zn-Air Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for cheap, efficient, and stable oxygen electrocatalysts is vital to promote the practical performance of Zn-air batteries with high theoretic energy density. Herein, a series of Co nulloparticles and highly dispersed Fe loaded on N-doped porous carbon substrates are prepared through a double-solvent method with in situ doped metal-organic frameworks as precursors. The optimized catalysts exhibit excellent performance for oxygen reduction and evolution reaction. Furthermore, rechargeable Zn-air batteries with designed catalysts demonstrate higher peak power density and better cycling stability than those with commercial Pt/C+RuO2. According to structure characterizations and electrochemical tests, the interaction of Co nulloparticles and highly dispersed Fe contributes to the superior performance for oxygen electrocatalysis. In addition, large specific surface areas, porous structures and interconnected three-dimensional carbon networks also play important roles in improving oxygen electrocatalysis. This work provides inspiration for rational design of advanced oxygen electrocatalysts and paves a way for the practical application of rechargeable Zn-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1007/s40820-022-00890-w", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00890-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000839646500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tofail, SAM; Koumoulos, EP; Bandyopadhyay, A; Bose, S; O'Donoghue, L; Charitidis, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tofail, Syed A. M.; Koumoulos, Elias P.; Bandyopadhyay, Amit; Bose, Susmita; O'Donoghue, Lisa; Charitidis, Costas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing: scientific and technological challenges, market uptake and opportunities", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) is fundamentally different from traditional formative or subtractive manufacturing in that it is the closest to the 'bottom up' manufacturing where a structure can be built into its designed shape using a 'layer-by-layer' approach rather than casting or forming by technologies such as forging or machining. AM is versatile, flexible, highly customizable and, as such, can suite most sectors of industrial production. Materials to make these parts/objects can be of a widely varying type. These include metallic, ceramic and polymeric materials along with combinations in the form of composites, hybrid, or functionally graded materials (FGMs). The challenge remains, however, to transfer this 'making' shapes and structures into obtaining objects that are functional. A great deal of work is needed in AM in addressing the challenges related to its two key enabling technologies namely 'materials' and 'metrology' to achieve this functionality in a predictive and reproductive ways. The good news is that there is a significant interest in industry for taking up AM as one of the main production engineering route. Additive Manufacturing, in our opinion, is definitely at the cross-road from where this new, much-hyped but somewhat unproven manufacturing process must move towards a technology that can demonstrate the ability to produce real, innovative, complex and robust products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1282, "Times Cited, All Databases": 1427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2018, "Volume": 21, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22, "End Page": 37, "Article Number": null, "DOI": "10.1016/j.mattod.2017.07.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2017.07.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426035100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, RR; Kolb, MJ; Giordano, L; Pedersen, AF; Katayama, Y; Hwang, J; Mehta, A; You, H; Lunger, JR; Zhou, H; Halck, NB; Vegge, T; Chorkendorff, I; Stephens, IEL; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Reshma R.; Kolb, Manuel J.; Giordano, Livia; Pedersen, Anders Filsoe; Katayama, Yu; Hwang, Jonathan; Mehta, Apurva; You, Hoydoo; Lunger, Jaclyn R.; Zhou, Hua; Halck, Niels Bendtsen; Vegge, Tejs; Chorkendorff, Ib; Stephens, Ifan E. L.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando identification of site-dependent water oxidation activity on ruthenium dioxide single-crystal surfaces", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the nature of active sites is central to controlling the activity of a given catalyst. This work combines operando characterization and computational techniques to examine the oxygen evolution reaction mechanism on RuO2 surfaces. Understanding the nature of active sites is central to controlling (electro)catalytic activity. Here we employed surface X-ray scattering coupled with density functional theory and surface-enhanced infrared absorption spectroscopy to examine the oxygen evolution reaction on RuO2 surfaces as a function of voltage. At 1.5 V-RHE, our results suggest that there is an -OO group on the coordinatively unsaturated ruthenium (Ru-CUS) site of the (100) surface (and similarly for (110)), but adsorbed oxygen on the Ru-CUS site of (101). Density functional theory results indicate that the removal of -OO from the Ru-CUS site, which is stabilized by a hydrogen bond to a neighbouring -OH (-OO-H), could be the rate-determining step for (100) (similarly for (110)), where its reduced binding on (100) increased activity. A further reduction in binding energy on the Ru-CUS site of (101) resulted in a different rate-determining step (-O + H2O - (H+ + e(-)) -> -OO-H) and decreased activity. Our study provides molecular details on the active sites, and the influence of their local coordination environment on activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 516, "End Page": 525, "Article Number": null, "DOI": "10.1038/s41929-020-0457-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0457-6", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531778200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, MT; Vaitiekenas, S; Hansen, EB; Danon, J; Leijnse, M; Flensberg, K; Nygård, J; Krogstrup, P; Marcus, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, M. T.; Vaitiekenas, S.; Hansen, E. B.; Danon, J.; Leijnse, M.; Flensberg, K.; Nygard, J.; Krogstrup, P.; Marcus, C. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Majorana bound state in a coupled quantum-dot hybrid-nullowire system", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid nullowires combining semiconductor and superconductor materials appear well suited for the creation, detection, and control of Majorana bound states (MBSs). We demonstrate the emergence of MBSs from coalescing Andreev bound states (ABSs) in a hybrid InAs nullowire with epitaxial Al, using a quantum dot at the end of the nullowire as a spectrometer. Electrostatic gating tuned the nullowire density to a regime of one or a few ABSs. In an applied axial magnetic field, a topological phase emerges in which ABSs move to zero energy and remain there, forming MBSs. We observed hybridization of the MBS with the end-dot bound state, which is in agreement with a numerical model. The ABS/MBS spectra provide parameters that are useful for understanding topological superconductivity in this system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 863, "Times Cited, All Databases": 928, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2016, "Volume": 354, "Issue": 6319, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1557, "End Page": 1562, "Article Number": null, "DOI": "10.1126/science.aaf3961", "DOI Link": "http://dx.doi.org/10.1126/science.aaf3961", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390254300045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, Y; Yang, H; Gao, ZY; Liu, YX; Xing, GC; Dang, PP; Al Kheraif, AA; Li, GG; Lin, J; Liu, RS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Yi; Yang, Hang; Gao, Zhiyu; Liu, Yixin; Xing, Gongcheng; Dang, Peipei; Al Kheraif, Abdulaziz A.; Li, Guogang; Lin, Jun; Liu, Ru-Shi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategies for Designing Antithermal-Quenching Red Phosphors", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nowadays, red phosphor plays a key role in improving the lighting quality and color rendering index of phosphor-converted white light emitting diodes (w-LEDs). However, the development of thermally stable and highly efficient red phosphor is still a pivotal challenge. Herein, a new strategy to design antithermal-quenching red emission in Eu3+, Mn4+-codoped phosphors is proposed. The photoluminescence intensity of Mg3Y2(1-y)Ge3O12:yEu(3+), Mn4+ (0 <= y <= 1) phosphors continuously enhances with rising temperature from 298 to 523 K based on Eu3+ -> Mn4+ energy transfer. For Mg3Eu2Ge3O12:Mn4+ sample, the integrated intensity at 523 K remarkably reaches 120% of that at 298 K. Interestingly, through codoping Eu3+ and Mn4+ in Mg3Y2Ge3O12, the photoluminescence color is controllably tuned from orangish-red (610 nm) to deep-red (660 nm) light by changing Eu3+ concentration. The fabricated w-LEDs exhibit superior warm white light with low corrected color temperature (CCT = 4848 K) and high color rendering index (R-a = 96.2), indicating the promising red component for w-LED applications. Based on the abnormal increase in antistokes peaks of Mn4+ with temperatures, Mg3Eu2Ge3O12:Mn4+ phosphor also presents a potential application in optical thermometry sensors. This work initiates a new insight to construct thermally stable and spectra-tunable red phosphors for various optical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903060, "DOI": "10.1002/advs.201903060", "DOI Link": "http://dx.doi.org/10.1002/advs.201903060", "Book DOI": null, "Early Access Date": "FEB 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517266300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hickey, JW; Santos, JL; Williford, JM; Mao, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hickey, John W.; Santos, Jose Luis; Williford, John-Michael; Mao, Hai-Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of polymeric nulloparticle size to improve therapeutic delivery", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As nulloparticle (NP)-mediated drug delivery research continues to expand, understanding parameters that govern NP interactions with the biological environment becomes paramount. The principles identified from the study of these parameters can be used to engineer new NPs, impart unique functionalities, identify novel utilities, and improve the clinical translation of NP formulations. One key design parameter is NP size. New methods have been developed to produce NPs with increased control of NP size between 10 and 200 nm, a size range most relevant to physical and biochemical targeting through both intravascular and site-specific deliveries. Three notable techniques best suited for generating polymeric NPs with narrow size distributions are highlighted in this review: self-assembly, microfluidics-based preparation, and flash nulloprecipitation. Furthermore, the effect of NP size on the biological fate and transport properties at the molecular scale (protein-NP interactions) and the tissue and systemic scale (convective and diffusive transport of NPs) are analyzed here. These analyses underscore the importance of NP size control in considering clinical translation and assessment of therapeutic outcomes of NP delivery vehicles. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2015, "Volume": 219, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 536, "End Page": 547, "Article Number": null, "DOI": "10.1016/j.jconrel.2015.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2015.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365587800042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gobert, C; Reutzel, EW; Petrich, J; Nassar, AR; Phoha, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gobert, Christian; Reutzel, Edward W.; Petrich, Jan; Nassar, Abdalla R.; Phoha, Shashi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application of supervised machine learning for defect detection during metallic powder bed fusion additive manufacturing using high resolution imaging", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Process monitoring in additive manufacturing (AM) is a crucial component in the mission of broadening AM industrialization. However, conventional part evaluation and qualification techniques, such as computed tomography (CT), can only be utilized after the build is complete, and thus eliminate any potential to correct defects during the build process. In contrast to post-build CT, in situ defect detection based on in situ sensing, such as layerwise visual inspection, enables the potential for in-process re-melting and correction of detected defects and thus facilitates in-process part qualification. This paper describes the development and implementation of such an in situ defect detection strategy for powder bed fusion (PBF) AM using supervised machine learning. During the build process, multiple images were collected at each build layer using a high resolution digital single-lens reflex (DSLR) camera. For each neighborhood in the resulting layerwise image stack, multi-dimensional visual features were extracted and evaluated using binary classification techniques, i.e. a linear support vector machine (SVM). Through binary classification, neighborhoods are then categorized as either a flaw, i.e. an undesirable interruption in the typical structure of the material, or a nominal build condition. Ground truth labels, i.e. the true location of flaws and nominal build areas, which are needed to train the binary classifiers, were obtained from post-build high-resolution 3D CT scan data. In CT scans, discontinuities, e.g. incomplete fusion, porosity, cracks, or inclusions, were identified using automated analysis tools or manual inspection. The xyz locations of the CT data were transferred into the layerwise image domain using an affine transformation, which was estimated using reference points embedded in the part. After the classifier had been properly trained, in situ defect detection accuracies greater than 80% were demonstrated during cross-validation experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 517, "End Page": 528, "Article Number": null, "DOI": "10.1016/j.addma.2018.04.005", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2018.04.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751300052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, LB; Wang, LL; Zhao, WW; Liu, SJ; Huang, W; Zhao, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Lingbin; Wang, Longlu; Zhao, Weiwei; Liu, Shujuan; Huang, Wei; Zhao, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WS2 moire superlattices derived from mechanical flexibility for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of moire superlattices (MSLs) opened an era in the research of 'twistronics'. Engineering MSLs and realizing unique emergent properties are key challenges. Herein, we demonstrate an effective synthetic strategy to fabricate MSLs based on mechanical flexibility of WS2 nullobelts by a facile one-step hydrothermal method. Unlike previous MSLs typically created through stacking monolayers together with complicated method, WS2 MSLs reported here could be obtained directly during synthesis of nullobelts driven by the mechanical instability. Emergent properties are found including superior conductivity, special superaerophobicity and superhydrophilicity, and strongly enhanced electro-catalytic activity when we apply 'twistronics' to the field of catalytic hydrogen production. Theoretical calculations show that such excellent catalytic performance could be attributed to a closer to thermoneutral hydrogen adsorption free energy value of twisted bilayers active sites. Our findings provide an exciting opportunity to design advanced WS2 catalysts through moire superlattice engineering based on mechanical flexibility. Expanding the available materials with moire superlattices is interesting but also challenging. Here the authors use a one-step hydrothermal approach to synthesis WS2 moire superlattices with high catalytic activity for hydrogen evolution reaction", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5070, "DOI": "10.1038/s41467-021-25381-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25381-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687171500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, HG; Liu, GJ; You, SJ; Camargo, FVA; Zavelani-Rossi, M; Wang, XH; Sun, CC; Liu, B; Zhang, YM; Han, GT; Vomiero, A; Gong, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Haiguang; Liu, Guiju; You, Shujie; Camargo, Franco V. A.; Zavelani-Rossi, Margherita; Wang, Xiaohan; Sun, Changchun; Liu, Bing; Zhang, Yuanming; Han, Guangting; Vomiero, Alberto; Gong, Xiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gram-scale synthesis of carbon quantum dots with a large Stokes shift for the fabrication of eco-friendly and high-efficiency luminescent solar concentrators", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Luminescent solar concentrators (LSCs) are large-area sunlight collectors coupled to small area solar cells, for efficient solar-to-electricity conversion. The three key points for the successful market penetration of LSCs are: (i) removal of light losses due to reabsorption during light collection; (ii) high light-to-electrical power conversion efficiency of the final device; (iii) long-term stability of the LSC structure related to the stability of both the matrix and the luminophores. Among various types of fluorophores, carbon quantum dots (C-dots) offer a wide absorption spectrum, high quantum yield, non-toxicity, environmental friendliness, low-cost, and eco-friendly synthetic methods. However, they are characterized by a relatively small Stokes shift, compared to inorganic quantum dots, which limits the highest external optical efficiency that can be obtained for a large-area single-layer LSC (>100 cm(2)) based on C-dots below 2%. Herein, we report highly efficient large-area LSCs (100-225 cm(2)) based on colloidal C-dots synthesized via a space-confined vacuum-heating approach. This one batch reaction could produce Gram-scale C-dots with a high quantum yield (QY) (similar to 65%) using eco-friendly citric acid and urea as precursors. Thanks to their very narrow size distribution, the C-dots produced via the space-confined vacuum-heating approach had a large Stokes shift of 0.53 eV, 50% larger than C-dots synthesized via a standard solvothermal reaction using the same precursors with a similar absorption range. The large-area LSC (15 x 15 x 0.5 cm(3)) prepared by using polyvinyl pyrrolidone (PVP) polymer as a matrix exhibited an external optical efficiency of 2.2% (under natural sun irradiation, 60 mW cm(-2), uncharacterized spectrum). After coupling to silicon solar cells, the LSC exhibited a power conversion efficiency (PCE) of 1.13% under natural sunlight illumination (20 mW cm(-2), uncharacterized spectrum). These unprecedented results were obtained by completely suppressing the reabsorption losses during light collection, as proved by optical spectroscopy. These findings demonstrate the possibility of obtaining eco-friendly, high-efficiency, large-area LSCs through scalable production techniques, paving the way to the lab-to-fab transition of this kind of devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1039/d0ee02235g", "DOI Link": "http://dx.doi.org/10.1039/d0ee02235g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000611850000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hatzell, KB; Chen, XC; Cobb, CL; Dasgupta, NP; Dixit, MB; Marbella, LE; McDowell, MT; Mukherjee, PP; Verma, A; Viswanathan, V; Westover, AS; Zeier, WG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hatzell, Kelsey B.; Chen, Xi Chelsea; Cobb, Corie L.; Dasgupta, Neil P.; Dixit, Marm B.; Marbella, Lauren E.; McDowell, Matthew T.; Mukherjee, Partha P.; Verma, Ankit; Viswanathan, Venkatasubramanian; Westover, Andrew S.; Zeier, Wolfgang G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges in Lithium Metal Anodes for Solid-State Batteries", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this Perspective, we highlight recent progress and challenges related to the integration of lithium metal anodes in solid-state batteries. While prior reports have suggested that solid electrolytes may be impermeable to lithium metal, this hypothesis has been disproven under a variety of electrolyte compositions and cycling conditions. Herein, we describe the mechanistic origins and importance of lithium filament growth and interphase formation in inorganic and organic solid electrolytes. Multimodal techniques that combine real and reciprocal space imaging and modeling will be necessary to fully understand nonequilibrium dynamics at these buried interfaces. Currently, most studies on lithium electrode kinetics at solid electrolyte interfaces are completed in symmetric Li-Li configurations. To fully understand the challenges and opportunities afforded by Li-metal anodes, full-cell experiments are necessary. Finally, the impacts of operating conditions on solid-state batteries are largely unknown with respect to pressure, geometry, and break-in protocols. Given the rapid growth of this community and the diverse portfolio of solid electrolytes, we highlight the need for detailed reporting of experimental conditions and standardization of protocols across the community.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2020, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 922, "End Page": 934, "Article Number": null, "DOI": "10.1021/acsenergylett.9b02668", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526311000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Clark, EL; Resasco, J; Landers, A; Lin, J; Chung, LT; Walton, A; Hahn, C; Jaramillo, TF; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Clark, Ezra L.; Resasco, Joaquin; Landers, Alan; Lin, John; Chung, Linh-Thao; Walton, Amber; Hahn, Christopher; Jaramillo, Thomas F.; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Standards and Protocols for Data Acquisition and Reporting for Studies of the Electrochemical Reduction of Carbon Dioxide", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objective evaluation of the performance of electrocatalysts for CO2 reduction has been complicated by a lack of standardized methods for measuring and reporting activity data. In this perspective, we advocate that standardizing these practices can aid in advancing research efforts toward the development of efficient and selective CO2 reduction electrocatalysts. Using information taken from experimental studies, we identify variables that influence the measured activity of CO2 reduction electrocatalysts and propose procedures to account for these variables in order to improve the accuracy and reproducibility of reported data. We recommend that catalysts be measured under conditions which do not introduce artifacts from impurities, from either the electrolyte or counter electrode, and advocate the acquisition of data measured in the absence of mass transport effects. Furthermore, measured rates of electrochemical reactions should be normalized to both the geometric electrode area as well as the electrochemically active surface area to facilitate the comparison of reported catalysts with those previously known. We demonstrate that, when these factors are accounted for, the CO2 reduction activities of Ag and Cu measured in different laboratories exhibit little difference. Adoption of the recommendations presented in this perspective would greatly facilitate the identification of superior catalysts for CO2 reduction arising solely from changes in their composition and pretreatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6560, "End Page": 6570, "Article Number": null, "DOI": "10.1021/acscatal.8b01340", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b01340", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438475100092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuo, CT; Neumann, M; Balamurugan, K; Park, HJ; Kang, S; Shiu, HW; Kang, JH; Hong, BH; Han, M; Noh, TW; Park, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuo, Cheng-Tai; Neumann, Michael; Balamurugan, Karuppannull; Park, Hyun Ju; Kang, Soonmin; Shiu, Hung Wei; Kang, Jin Hyoun; Hong, Byung Hee; Han, Moonsup; Noh, Tae Won; Park, Je-Geun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exfoliation and Raman Spectroscopic Fingerprint of Few-Layer NiPS3 Van der Waals Crystals", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The range of mechanically cleavable Van der Waals crystals covers materials with diverse physical and chemical properties. However, very few of these materials exhibit magnetism or magnetic order, and thus the provision of cleavable magnetic compounds would supply invaluable building blocks for the design of heterostructures assembled from Van der Waals crystals. Here we report the first successful isolation of monolayer and few-layer samples of the compound nickel phosphorus trisulfide (NiPS3) by mechanical exfoliation. This material belongs to the class of transition metal phosphorus trisulfides (MPS3), several of which exhibit antiferromagnetic order at low temperature, and which have not been reported in the form of ultrathin sheets so far. We establish layer numbers by optical bright field microscopy and atomic force microscopy, and perform a detailed Raman spectroscopic characterization of bilayer and thicker NiPS3 flakes. Raman spectral features are strong functions of excitation wavelength and sample thickness, highlighting the important role of interlayer coupling. Furthermore, our observations provide a spectral fingerprint for distinct layer numbers, allowing us to establish a sensitive and convenient means for layer number determination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20904, "DOI": "10.1038/srep20904", "DOI Link": "http://dx.doi.org/10.1038/srep20904", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370054900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, S; Wu, WK; Feng, XL; Guan, S; Feng, WX; Yao, YG; Yang, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Si; Wu, Weikang; Feng, Xiaolong; Guan, Shan; Feng, Wanxiang; Yao, Yugui; Yang, Shengyuan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valley-dependent properties of monolayer MoSi2N4, WSi2N4, and MoSi2As4", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In a recent work, new two-dimensional materials, monolayer MoSi2N4 and WSi2N4, were successfully synthesized in experiment, and several other monolayer materials with a similar structure, such as MoSi2As4, were predicted [Hong et al., Science 369, 670 (2020)]. Here, based on first-principles calculations and theoretical analysis, we investigate the electronic and optical properties of monolayer MoSi2N4, WSi2N4, and MoSi2As4. We show that these materials are semiconductors, with a pair of Dirac-type valleys located at the corners of the hexagonal Brillouin zone. Due to the broken inversion symmetry and the effect of spin-orbit coupling, the valley fermions manifest spin-valley coupling, valley-contrasting Berry curvature, and valley-selective optical circular dichroism. We also construct the low-energy effective model for the valleys, calculate the spin Hall conductivity and the permittivity, and investigate the strain effect on the band structure. Our result reveals interesting valley physics in monolayer MoSi2N4, WSi2N4, and MoSi2As4, suggesting their great potential for valleytronics and spintronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 29", "Publication Year": 2020, "Volume": 102, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235435, "DOI": "10.1103/PhysRevB.102.235435", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.102.235435", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000603248600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kieslich, G; Sun, SJ; Cheetham, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kieslich, Gregor; Sun, Shijing; Cheetham, Anthony K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An extended Tolerance Factor approach for organic-inorganic perovskites", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Goldschmidt's concept of ionic Tolerance Factors was recently shown to be a valuable guideline for the preparation of new compounds within the field of organic-inorganic perovskites. Here, we extend this approach and calculate Tolerance Factors for over 2500 amine-metal-anion permutations of the periodic table. The results suggest the potential existence of more than 600 undiscovered hybrid perovskites including alkaline earth metal and lanthanide based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 657, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3430, "End Page": 3433, "Article Number": null, "DOI": "10.1039/c5sc00961h", "DOI Link": "http://dx.doi.org/10.1039/c5sc00961h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354815600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZM; Ma, T; Tang, R; Cheng, Q; Wang, X; Krishnaraju, D; Panat, R; Chan, CK; Yu, HY; Jiang, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Zeming; Ma, Teng; Tang, Rui; Cheng, Qian; Wang, Xu; Krishnaraju, Deepakshyam; Panat, Rahul; Chan, Candace K.; Yu, Hongyu; Jiang, Hanqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origami lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There are significant challenges in developing deformable devices at the system level that contain integrated, deformable energy storage devices. Here we demonstrate an origami lithium-ion battery that can be deformed at an unprecedented high level, including folding, bending and twisting. Deformability at the system level is enabled using rigid origami, which prescribes a crease pattern such that the materials making the origami pattern do not experience large strain. The origami battery is fabricated through slurry coating of electrodes onto paper current collectors and packaging in standard materials, followed by folding using the Miura pattern. The resulting origami battery achieves significant linear and areal deformability, large twistability and bendability. The strategy described here represents the fusion of the art of origami, materials science and functional energy storage devices, and could provide a paradigm shift for architecture and design of flexible and curvilinear electronics with exceptional mechanical characteristics and functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 551, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3140, "DOI": "10.1038/ncomms4140", "DOI Link": "http://dx.doi.org/10.1038/ncomms4140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331097100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZW; Huang, JH; Dong, XL; Xia, YY; Yan, L; Wang, Z; Wang, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhaowei; Huang, Jianhang; Dong, Xiaoli; Xia, Yongyao; Yan, Lei; Wang, Zhuo; Wang, Yonggang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An organic/inorganic electrode-based hydronium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydronium-ion batteries are regarded as one of the most promising energy technologies as next-generation power sources, benefiting from their cost effectivity and sustainability merits. Herein, we propose a hydronium-ion battery which is based on an organic pyrene-4,5,9,10-tetraone anode and an inorganic MnO2@graphite felt cathode in an acid electrolyte. Its operation involves a quinone/hydroquinone redox reaction on anode and a MnO2/Mn2+ conversion reaction on cathode, in parallel with the transfer of H3O+ between two electrodes. The distinct operation mechanism affords this hydronium-ion battery an energy density up to 132.6Whkg(-1) and a supercapacitor-comparable power density of 30.8kWkg(-1), along with a long-term cycling life over 5000 cycles. Furthermore, surprisingly, this hydronium-ion battery works well even with a frozen electrolyte under -40 degrees C, and superior rate performance and cycle stability remain at -70 degrees C. The authors show a hydronium-ion battery with an organic pyrene-4,5,9,10-tetraone anode and a MnO2@graphite cathode and H3O+ as the charge carrier. In addition to exhibiting promising energy density and power density, this battery works well even under low temperatures ranging from -40 degrees C to -70 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 959, "DOI": "10.1038/s41467-020-14748-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14748-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558871300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, T; Gao, DX; Song, XM; Zhou, ZP; Zhou, LX; Tao, MX; Jiang, ZX; Yang, L; Luo, L; Zhou, AK; Hu, L; Qin, HB; Wu, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Tuo; Gao, Dongxiu; Song, Xuemei; Zhou, Zhipeng; Zhou, Lixiao; Tao, Maixian; Jiang, Zexiu; Yang, Lian; Luo, Lan; Zhou, Ankun; Hu, Lin; Qin, Hongbo; Wu, Mingyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A natural biological adhesive from snail mucus for wound repair", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of natural adhesion phenomena andmechanisms has advanced the development of a new generation of tissue adhesives in recent decades. In this study, we develop a natural biological adhesive from snail mucus gel, which consists a network of positively charged protein and polyanionic glycosaminoglycan. The malleable bulk adhesive matrix can adhere to wet tissue through multiple interactions. The biomaterial exhibits excellent haemostatic activity, biocompatibility and biodegradability, and it is effective in accelerating the healing of full-thickness skin wounds in both normal and diabetic male rats. Further mechanistic study shows it effectively promotes the polarization of macrophages towards the anti-inflammatory phenotype, alleviates inflammation in chronic wounds, and significantly improves epithelial regeneration and angiogenesis. Its abundant heparin-like glycosaminoglycan component is the main active ingredient. These findings provide theoretical and material insights into bio-inspired tissue adhesives and bioengineered scaffold designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 396, "DOI": "10.1038/s41467-023-35907-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35907-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001170148000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, C; Zhang, M; Yu, MJ; Zhu, RR; Hu, H; Loncar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Cheng; Zhang, Mian; Yu, Mengjie; Zhu, Rongrong; Hu, Han; Loncar, Marko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithic lithium niobate photonic circuits for Kerr frequency comb generation and modulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microresonator Kerr frequency combs could provide miniaturised solutions for a wide range of applications. Many of these applications however require further manipulation of the generated frequency comb signal using photonic elements with strong second-order nonlinearity (chi((2))). To date these functionalities have largely been implemented as discrete components due to material limitations, which comes at the expense of extra system complexity and increased optical losses. Here we demonstrate the generation, filtering and electro-optic modulation of a frequency comb on a single monolithic integrated chip, using a nullophotonic lithium-niobate platform that simultaneously possesses large electro-optic (chi((2))) and Kerr (chi((3))) nonlinearities, and low optical losses. We generate broadband Kerr frequency combs using a dispersion-engineered high-Q lithium-niobate microresonator, select a single comb line using an electrically programmable add-drop filter, and modulate the intensity of the selected line. Our results pave the way towards monolithic integrated frequency comb solutions for spectroscopy, data communication, ranging and quantum photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 978, "DOI": "10.1038/s41467-019-08969-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08969-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459899700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Q; Wu, J; Chen, XZ; Sanchis-Gual, R; Veciana, A; Franco, C; Kim, D; Surin, I; Pérez-Ramfrez, J; Mattera, M; Terzopoulou, A; Qin, N; Vukomanovic, M; Nelson, BJ; Puigmartf-Luis, J; Pan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Qiao; Wu, Jiang; Chen, Xiang-Zhong; Sanchis-Gual, Roger; Veciana, Andrea; Franco, Carlos; Kim, Donghoon; Surin, Ivan; Perez-Ramirez, Javier; Mattera, Michele; Terzopoulou, Anastasia; Qin, Ni; Vukomanovic, Marija; Nelson, Bradley J.; Luis, Josep; Pan, Salvador", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning oxygen vacancies in Bi4Ti3O12 nullosheets to boost piezo-photocatalytic activity", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Piezo-photocatalysis has emerged as a promising strategy to address environmental pollution and the fastgrowing energy shortage. Unfortunately, current efficiencies of piezo-photocatalysts are still far from ideal, and improving their catalytic efficiency remains challenging. In this paper, we introduce oxygen vacancies (OVs) in Bi4Ti3O12 (BIT) nullosheets to boost their piezo-photocatalytic performance. Compared to pristine BIT nullosheets, BIT with an optimized OV concentration exhibit excellent piezo-photocatalytic activity, with an enhancement of 2.2 times the degradation rate constant (k = 0.214 min-1) for Rhodamine B (RhB). The effect of OVs on the adsorption energy and Bader charges was also investigated using density functional theory (DFT) calculations, which shed light on the underlying mechanism that improves the piezo-photocatalytic process in the presence of OVs. Specifically, the introduction of OVs increases the adsorption energy and Bader charges, resulting in an enhancement of charge transfer between O2/H2O and BIT, thus facilitating the catalytic process. This study provides a deeper understanding into the regulation mechanism of OV enhanced piezo-photocatalytic activity and opens new avenues for designing high-performance piezo-photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108202, "DOI": "10.1016/j.nulloen.2023.108202", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2023.108202", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923843800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ganose, AM; Park, J; Faghaninia, A; Woods-Robinson, R; Persson, KA; Jain, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ganose, Alex M.; Park, Junsoo; Faghaninia, Alireza; Woods-Robinson, Rachel; Persson, Kristin A.; Jain, Anubhav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient calculation of carrier scattering rates from first principles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic transport behaviour of materials determines their suitability for technological applications. We develop a computationally efficient method for calculating carrier scattering rates of solid-state semiconductors and insulators from first principles inputs. The present method extends existing polar and non-polar electron-phonon coupling, ionized impurity, and piezoelectric scattering mechanisms formulated for isotropic band structures to support highly anisotropic materials. We test the formalism by calculating the electronic transport properties of 23 semiconductors, including the large 48 atom CH3NH3PbI3 hybrid perovskite, and comparing the results against experimental measurements and more detailed scattering simulations. The Spearman rank coefficient of mobility against experiment (r(s)=0.93) improves significantly on results obtained using a constant relaxation time approximation (r(s)=0.52). We find our approach offers similar accuracy to state-of-the art methods at approximately 1/500th the computational cost, thus enabling its use in high-throughput computational workflows for the accurate screening of carrier mobilities, lifetimes, and thermoelectric power. It is difficult to compute the transport properties of a broad array of complex materials both accurately and inexpensively. Here, the authors develop a computationally efficient method for calculating carrier scattering rates of semiconductors, with good accuracy but low cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2222, "DOI": "10.1038/s41467-021-22440-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22440-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640639700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, Z; Qiao, Y; Deng, H; Yang, HJ; He, P; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Zhi; Qiao, Yu; Deng, Han; Yang, Huijun; He, Ping; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Liquid Electrolyte with De-Solvated Lithium Ions for Lithium-Metal Battery", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional liquid electrolytes used in rechargeable batteries, fuel cells, and electrochemical capacitors composed of solvents, anions, and solvents solvated cations (e.g., lithium ions, Li+), follow classic cations with solvation electrolyte configuration and can be defined as cations solvated electrolytes. In these electrolytes, the de-solvation processes of solvated cations only occur when the cations inserted-deposited on the electrodes' surface. Here, different from traditional electrolytes, a new liquid electrolyte with de-solvated Li+ was discovered (Li+ de-solvated electrolyte), since it merely composed of inactive frozen-like solvent and crystal-like salt solute. Inspiringly, its electrochemical stability was remarkably improved (extended to 4 5 V for Li+ de-solvated ether-based electrolyte). Ultra-stable high-energy-density lithium-metal batteries (LiNi0.8Co0.1Mn0.1O2//Li) were achieved (half-cell: 140 mAh g(-1) after 830 cycles; full-cell: 170 mAh g(-1) after 200 cycles under twice excessed Li). It is also surprising that this does not present any cathode-electrolyte interface (CEI) layer on the cycled NCM-811 surface benefit from the Li+ de-solvated electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2020, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1776, "End Page": 1789, "Article Number": null, "DOI": "10.1016/j.joule.2020.06.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.06.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561454400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gou, J; Bai, H; Zhang, XL; Huang, YL; Duan, SS; Ariando, A; Yang, SYA; Chen, L; Lu, YH; Wee, ATS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gou, Jian; Bai, Hua; Zhang, Xuanlin; Huang, Yu Li; Duan, Sisheng; Ariando, A.; Yang, Shengyuan A.; Chen, Lan; Lu, Yunhao; Wee, Andrew Thye Shen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional ferroelectricity in a single-element bismuth monolayer", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectric materials are fascinating for their non-volatile switchable electric polarizations induced by the spontaneous inversion-symmetry breaking. However, in all of the conventional ferroelectric compounds, at least two constituent ions are required to support the polarization switching(1,2). Here, we report the observation of a single-element ferroelectric state in a black phosphorus-like bismuth layer(3), in which the ordered charge transfer and the regular atom distortion between sublattices happen simultaneously. Instead of a homogenous orbital configuration that ordinarily occurs in elementary substances, we found the Bi atoms in a black phosphorous-like Bi monolayer maintain a weak and anisotropic sp orbital hybridization, giving rise to the inversion-symmetry-broken buckled structure accompanied with charge redistribution in the unit cell. As a result, the in-plane electric polarization emerges in the Bi monolayer. Using the in-plane electric field produced by scanning probe microscopy, ferroelectric switching is further visualized experimentally. Owing to the conjugative locking between the charge transfer and atom displacement, we also observe the anomalous electric potential profile at the 180 degrees tail-to-tail domain wall induced by competition between the electronic structure and electric polarization. This emergent single-element ferroelectricity broadens the mechanism of ferroelectrics and may enrich the applications of ferroelectronics in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2023, "Volume": 617, "Issue": 7959, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 67, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05848-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05848-5", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000990835100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, TH; Gao, LL; Lu, J; Ma, C; Du, YC; Wang, PJ; Ding, ZC; Wang, SQ; Xu, P; Liu, DL; Li, HJ; Chang, XM; Fang, JJ; Tian, WM; Yang, YG; Liu, SZ; Zhao, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Tinghuan; Gao, Lili; Lu, Jing; Ma, Chuang; Du, Yachao; Wang, Peijun; Ding, Zicheng; Wang, Shiqiang; Xu, Peng; Liu, Dongle; Li, Haojin; Chang, Xiaoming; Fang, Junjie; Tian, Wenming; Yang, Yingguo; Liu, Shengzhong (Frank); Zhao, Kui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-stone-for-two-birds strategy to attain beyond 25% perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Even though the perovskite solar cell has been so popular for its skyrocketing power conversion efficiency, its further development is still roadblocked by its overall performance, in particular long-term stability, large-area fabrication and stable module efficiency. In essence, the soft component and ionic-electronic nature of metal halide perovskites usually chaperonage large number of anion vacancy defects that act as recombination centers to decrease both the photovoltaic efficiency and operational stability. Herein, we report a one-stone-for-two-birds strategy in which both anion-fixation and associated undercoordinated-Pb passivation are in situ achieved during crystallization by using a single amidino-based ligand, namely 3-amidinopyridine, for metal-halide perovskite to overcome above challenges. The resultant devices attain a power conversion efficiency as high as 25.3% (certified at 24.8%) with substantially improved stability. Moreover, the device without encapsulation retained 92% of its initial efficiency after 5000 h exposure in ambient and the device with encapsulation retained 95% of its initial efficiency after >500 h working at the maximum power point under continuous light irradiation in ambient. It is expected this one-stone-for-two-birds strategy will benefit large-area fabrication that desires for simplicity. Long-term stability and stable efficiency are essential for large-area fabrication of perovskite solar cells. Here, the authors achieve in situ anion-fixation and undercoordinated-Pb passivation using amidino-based ligand, realizing maximum power conversion efficiency of 25.3% with T95 over 500 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 839, "DOI": "10.1038/s41467-023-36229-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36229-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940806000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, JW; Hu, XZ; Wang, C; Liang, C; Chen, C; Xiao, M; Li, JS; Tao, C; Xing, GC; Yu, R; Ke, WJ; Fang, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Jiwei; Hu, Xuzhi; Wang, Chen; Liang, Chao; Chen, Cong; Xiao, Meng; Li, Jiashuai; Tao, Chen; Xing, Guichuan; Yu, Rui; Ke, Weijun; Fang, Guojia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origins and influences of metallic lead in perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic lead (Pb-0) impurities in metal-halide perovskites have attracted tremendous research concerns owing to their detrimental effects on perovskite solar cells (PSCs). However, the origins and influences of the Pb-0 behind this issue have yet to bewell understood. Herein, we show that Pb-0 is hardly formed in the growth of halide perovskites but is easily postformed in the perovskite films with excess PbI2. It is found that Pb-0 impurities are decomposition byproducts of residual PbI2 in perovskites under light or X-ray irradiation. Therefore, PSCs obtained using photodegraded PbI2 films show large efficiency and stability losses. By contrast, the perovskite devices without detectable Pb-0 impurities have a much better efficiency and stability. This work reveals the origins and influences of Pb-0 in halide perovskites and provides a strategy for avoiding the formation of detrimental Pb-0 byproducts, which would drive further enhancements in device performance of halide perovskite solar cells, detectors, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 816, "End Page": 833, "Article Number": null, "DOI": "10.1016/j.joule.2022.03.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.03.005", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798575600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leblebici, SY; Leppert, L; Li, Y; Reyes-Lillo, SE; Wickenburg, S; Wong, E; Lee, J; Melli, M; Ziegler, D; Angell, DK; Ogletree, DF; Ashby, PD; Toma, FM; Neaton, JB; Sharp, ID; Weber-Bargioni, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leblebici, Sibel Y.; Leppert, Linn; Li, Yanbo; Reyes-Lillo, Sebastian E.; Wickenburg, Sebastian; Wong, Ed; Lee, Jiye; Melli, Mauro; Ziegler, Dominik; Angell, Daniel K.; Ogletree, D. Frank; Ashby, Paul D.; Toma, Francesca M.; Neaton, Jeffrey B.; Sharp, Ian D.; Weber-Bargioni, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facet-dependent photovoltaic efficiency variations in single grains of hybrid halide perovskite", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photovoltaic devices based on hybrid perovskite materials have exceeded 22% efficiency due to high charge-carrier mobilities and lifetimes. Properties such as photocurrent generation and open-circuit voltage are influenced by the microscopic structure and orientation of the perovskite crystals, but are difficult to quantify on the intra-grain length scale and are often treated as homogeneous within the active layer. Here, we map the local short-circuit photocurrent, open-circuit photovoltage, and dark drift current in state-of-the-art methylammonium lead iodide solar cells using photoconductive atomic force microscopy. We find, within individual grains, spatially correlated heterogeneity in short-circuit current and open-circuit voltage up to 0.6V. These variations are related to different crystal facets and have a direct impact on the macroscopic power conversion efficiency. We attribute this heterogeneity to a facet-dependent density of trap states. These results imply that controlling crystal grain and facet orientation will enable a systematic optimization of polycrystalline and single-crystal devices for photovoltaic and lighting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 463, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16093, "DOI": "10.1038/NENERGY.2016.93", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.93", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394178100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, BJ; Sugino, O; Liu, RY; Zhang, J; Yukawa, R; Kawamura, M; Iimori, T; Kim, H; Hasegawa, Y; Li, H; Chen, L; Wu, KH; Kumigashira, H; Komori, F; Chiang, TC; Meng, S; Matsuda, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Baojie; Sugino, Osamu; Liu, Ro-Ya; Zhang, Jin; Yukawa, Ryu; Kawamura, Mitsuaki; Iimori, Takushi; Kim, Howon; Hasegawa, Yukio; Li, Hui; Chen, Lan; Wu, Kehui; Kumigashira, Hiroshi; Komori, Fumio; Chiang, Tai-Chang; Meng, Sheng; Matsuda, Iwao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac Fermions in Borophene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Honeycomb structures of group IV elements can host massless Dirac fermions with nontrivial Berry phases. Their potential for electronic applications has attracted great interest and spurred a broad search for new Dirac materials especially in monolayer structures. We present a detailed investigation of the beta(12) sheet, which is a borophene structure that can form spontaneously on a Ag(111) surface. Our tight-binding analysis revealed that the lattice of the beta(12) sheet could be decomposed into two triangular sublattices in a way similar to that for a honeycomb lattice, thereby hosting Dirac cones. Furthermore, each Dirac cone could be split by introducing periodic perturbations representing overlayer-substrate interactions. These unusual electronic structures were confirmed by angle-resolved photoemission spectroscopy and validated by first-principles calculations. Our results suggest monolayer boron as a new platform for realizing novel high-speed low-dissipation devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2017, "Volume": 118, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 96401, "DOI": "10.1103/PhysRevLett.118.096401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.096401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396044600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, B; Zheng, JJ; Feng, L; Du, C; Jian, SJ; Yang, WS; Wu, YMA; Jiang, SH; He, SJ; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Bing; Zheng, Jiaojiao; Feng, Li; Du, Cheng; Jian, Shaoju; Yang, Weisen; Wu, Yimin A.; Jiang, Shaohua; He, Shuijian; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wood-derived biochar as thick electrodes for high-rate performance supercapacitors", "Source Title": "BIOCHAR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing effective electrodes with commercial-level active mass-loading (>10 mg cm(-2)) is vital for the practical application of supercapacitors. However, high active mass-loading usually requires thick active mass layer, which severely hinders the ion/electron transport and results in poor capacitive performance. Herein, a self-standing biochar electrode with active mass-loading of ca. 40 mg cm(-2) and thickness of 800 pm has been developed from basswood. The basswood was treated with formamide to incorporate N/O in the carbon structure, followed by mild KOH activation to ameliorate the pore size and introduce more 0 species in the carbon matrix. The as-prepared carbon monoliths possess well conductive carbon skeleton, abundant N/O dopant and 3D porous structure, which are favorable for the ion/electron transport and promoting capacitance performance. The self-standing carbon electrode not only exhibits the maximum areal/mass/volumetric specific capacitance of 5037.5 mF cm(-2)/1 72.5 F g(-1)/63.0 F cm(-3) at 2 mA cm(-2) (0.05 A g(-1)), but also displays excellent rate performance with 76% capacitance retention at 500 mA cm(-2) (12.5 A g(-1)) in a symmetric supercapacitor, surpassing the state-of-art biomass-based thick carbon electrode. The assembled model can power typical electron devices including a fan, a digital watch and a logo made up of 34 light-emitting diodes for a proper period, revealing its practical application potential. This study not only puts forward a commercial-level high active mass-loading electrode from biomass for supercapacitor, but also bridges the gap between the experimental research and practical application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 50, "DOI": "10.1007/s42773-022-00176-9", "DOI Link": "http://dx.doi.org/10.1007/s42773-022-00176-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000844763800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZP; Li, JT; Su, RB; Yao, BM; Fang, HL; Li, KZ; Zhou, LD; Liu, J; Stellinga, D; Reardon, CP; Krauss, TF; Wang, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhenpeng; Li, Juntao; Su, Rongbin; Yao, Beimeng; Fang, Hanlin; Li, Kezheng; Zhou, Lidan; Liu, Jin; Stellinga, Daan; Reardon, Christopher P.; Krauss, Thomas F.; Wang, Xuehua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Silicon Metasurfaces for Visible Light", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric metasurfaces require high refractive index contrast materials for optimum performance. This requirement imposes a severe restraint; either devices have been demonstrated at wavelengths of 700 nm and above using high index semiconductors such as silicon, or they use lower index dielectric materials such as TiO2 or Si3N4 and operate in the visible wavelength regime. Here, we show that the high refractive index of silicon can be exploited at wavelengths as short as 532 nm by demonstrating a crystalline silicon metasurface with a transmission efficiency of 71% at this wavelength and a diffraction efficiency of 95% into the desired diffraction order. The metasurfaces consist of a graded array of silicon posts arranged in a square lattice on a quartz substrate. We show full 2 pi phase control, and we experimentally demonstrate polarization-independent beam deflection at 532 nm wavelength. Our results open a new way for realizing efficient metasurfaces based on silicon for the technologically all-important display applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 544, "End Page": 551, "Article Number": null, "DOI": "10.1021/acsphotonics.6b00740", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.6b00740", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396808000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HW; Yu, KC; Liu, XF; Li, JP; Hu, XG; Zhao, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Huawen; Yu, Kaicheng; Liu, Xufei; Li, Jiapeng; Hu, Xiangguo; Zhao, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quaternization-spiro design of chlorine-resistant and high-permeance lithium separation membranes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current polyamide lithium extraction nullofiltration membranes are susceptible to chlorine degradation and/or low permeance, two problems that are hard to reconcile. Here we simultaneously circumvented these problems by designing a quaternized-spiro piperazine monomer and translating its beneficial properties into large-area membranes (1 x 2 m(2)) via interfacial polymerization with trimesoyl chloride. The quaternary ammonium and spiral conformation of themonomer confermore positive charge and free volume to the membrane, leading to one of the highest permeance (similar to 22 Lm(-2) h(-1) bar(-1)) compared to the state-of-the-art Mg2+/Li+ nullofiltration membranes. Meanwhile, membrane structures are chlorine resistant as the amine-acyl bonding contains no sensitive N-H group. Thus the high performance of membrane is stable versus 400-h immersion in sodium hypochlorite, while control membranes degraded readily. Molecular simulations show that the high permeance and chlorine resistance, which were reproducible at the membrane module level, arise from the spiral conformation and secondary amine structures of the monomer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5483, "DOI": "10.1038/s41467-023-41169-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41169-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001064301800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HR; Raftrey, D; Chan, YT; Shao, YT; Chen, R; Chen, X; Huang, XX; Reichanadter, JT; Dong, KC; Susarla, S; Caretta, L; Chen, Z; Yao, J; Fischer, P; Neaton, JB; Wu, WD; Muller, DA; Birgeneau, RJ; Ramesh, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hongrui; Raftrey, David; Chan, Ying-Ting; Shao, Yu-Tsun; Chen, Rui; Chen, Xiang; Huang, Xiaoxi; Reichanadter, Jonathan T.; Dong, Kaichen; Susarla, Sandhya; Caretta, Lucas; Chen, Zhen; Yao, Jie; Fischer, Peter; Neaton, Jeffrey B.; Wu, Weida; Muller, David A.; Birgeneau, Robert J.; Ramesh, Ramamoorthy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature skyrmion lattice in a layered magnet (Fe0.5Co0.5)5GeTe2", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel magnetic ground states have been stabilized in two-dimensional (2D) magnets such as skyrmions, with the potential next-generation information technology. Here, we report the experimental observation of a Neel-type skyrmion lattice at room temperature in a single-phase, layered 2D magnet, specifically a 50% Co-doped Fe5GeTe2 (FCGT) system. The thickness-dependent magnetic domain size follows Kittel's law. The static spin textures and spin dynamics in FCGT nulloflakes were studied by Lorentz electron microscopy, variable-temperature magnetic force microscopy, micromagnetic simulations, and magnetotransport measurements. Current-induced skyrmion lattice motion was observed at room temperature, with a threshold current density, j(th) = 1 x 10(6) A/cm(2). This discovery of a skyrmion lattice at room temperature in a noncentrosymmetric material opens the way for layered device applications and provides an ideal platform for studies of topological and quantum effects in 2D.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm7103", "DOI": "10.1126/sciadv.abm7103", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm7103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772464300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, YX; Xian, SK; Cui, H; Tan, K; Gong, LS; Liang, B; Pham, T; Pandey, H; Krishna, R; Lan, PC; Forrest, KA; Space, B; Thonhauser, T; Li, J; Ma, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Yingxiang; Xian, Shikai; Cui, Hui; Tan, Kui; Gong, Lingshan; Liang, Bin; Pham, Tony; Pandey, Haardik; Krishna, Rajamani; Lan, Pui Ching; Forrest, Katherine A.; Space, Brian; Thonhauser, Timo; Li, Jing; Ma, Shengqian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Based Hydrogen-Bonding nullotrap for Efficient Acetylene Storage and Separation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The removal of carbon dioxide (CO2) from acetylene (C2H2) is a critical industrial process for manufacturing high-purity C2H2. However, it remains challenging to address the tradeoff between adsorption capacity and selectivity, on account of their similar physical properties and molecular sizes. To overcome this difficulty, here we report a novel strategy involving the regulation of a hydrogen-bonding nullotrap on the pore surface to promote the separation of C2H2/CO2 mixtures in three isostructural metal-organic frameworks (MOFs, named MIL-160, CAU-10H, and CAU-23, respectively). Among them, MIL-160, which has abundant hydrogen-bonding acceptors as nullotraps, can selectively capture acetylene molecules and demonstrates an ultrahigh C2H2 storage capacity (191 cm(3) g(-1), or 213 cm(3) cm(-3)) but much less CO2 uptake (90 cm(3) g(-1)) under ambient conditions. The C(2)H(2 )adsorption amount of MIL-160 is remarkably higher than those for the other two isostructural MOFs (86 and 119 cm(3) g(-1) for CAU-10H and CAU-23, respectively) under the same conditions. More importantly, both simulation and experimental breakthrough results show that MIL-160 sets a new benchmark for equimolar C2H2/CO2 separation in terms of the separation potential (Delta(qbreak) = 5.02 mol/kg) and C(2)H(2 )productivity (6.8 mol/kg). In addition, in situ FT-IR experiments and computational modeling further reveal that the unique host-guest multiple hydrogen-bonding interaction between the nullotrap and C(2)H(2 )is the key factor for achieving the extraordinary acetylene storage capacity and superior C2 H-2/CO2 selectivity. This work provides a novel and powerful approach to address the tradeoff of this extremely challenging gas separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2022, "Volume": 144, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1681, "End Page": 1689, "Article Number": null, "DOI": "10.1021/jacs.1c10620", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c10620", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739359500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Makam, P; Yamijala, SSRKC; Bhadram, VS; Shimon, LJW; Wong, BM; Gazit, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Makam, Pandeeswar; Yamijala, Sharma S. R. K. C.; Bhadram, Venkata S.; Shimon, Linda J. W.; Wong, Bryan M.; Gazit, Ehud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single amino acid bionullozyme for environmental remediation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymes are extremely complex catalytic structures with immense biological and technological importance. Nevertheless, their widespread environmental implementation faces several challenges, including high production costs, low operational stability, and intricate recovery and reusability. Therefore, the de novo design of minimalistic biomolecular nullomaterials that can efficiently mimic the biocatalytic function (bionullozymes) and overcome the limitations of natural enzymes is a critical goal in biomolecular engineering. Here, we report an exceptionally simple yet highly active and robust single amino acid bionullozyme that can catalyze the rapid oxidation of environmentally toxic phenolic contaminates and serves as an ultrasensitive tool to detect biologically important neurotransmitters similar to the laccase enzyme. While inspired by the laccase catalytic site, the substantially simpler copper-coordinated bionullozyme is similar to 5400 times more cost-effective, four orders more efficient, and 36 times more sensitive compared to the natural protein. Furthermore, the designed mimic is stable under extreme conditions (pH, ionic strength, temperature, storage time), markedly reusable for several cycles, and displays broad substrate specificity. These findings hold great promise in developing efficient bionullozymes for analytical chemistry, environmental protection, and biotechnology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1505, "DOI": "10.1038/s41467-022-28942-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28942-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771678500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Righettoni, M; Amann, A; Pratsinis, SE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Righettoni, Marco; Amann, Anton; Pratsinis, Sotiris E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breath analysis by nullostructured metal oxides as chemo-resistive gas sensors", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently breath analysis has attracted a lot of attention for disease monitoring and clinical diagnostics as spectrometric techniques of high sophistication and novel sensing materials become available. Here advances in these technologies in connection to breath analysis are critically reviewed. A number of breath markers or tracer compounds are summarized and related to different diseases, either for diagnostics or for monitoring. Emphasis is placed on chemo-resistive gas sensors for their low cost and portability highlighting their potential and challenges for breath analysis as they start to be used in studies involving humans.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 18, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 163, "End Page": 171, "Article Number": null, "DOI": "10.1016/j.mattod.2014.08.017", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.08.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351057200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, B; Zheng, JJ; Feng, L; Zhang, Q; Zhang, CM; Ding, YC; Han, JQ; Jiang, SH; He, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Bing; Zheng, Jiaojiao; Feng, Li; Zhang, Qian; Zhang, Chunmei; Ding, Yichun; Han, Jingquan; Jiang, Shaohua; He, Shuijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore engineering: Structure-capacitance correlations for biomass-derived porous carbon materials", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the world's demand for green energy storage systems continues to increase, electrochemical doublelayer supercapacitors based on porous carbon electrodes are receiving more attention than ever. Porous carbon materials can be designed and synthesized from biomass residues/extracts through various technologies, which realizes the value-added utilization of biomass and meets the targets of circular economy. Pore characteristics are particularly important for the capacitive performance of carbon-based electrodes. This review outlines the biomass-derived porous carbon materials and their corresponding capacitive properties, which are divided into biomass-derived ultra/super-microporous carbon, mesoporous carbon, macroporous carbon and hierarchical porous carbon according to the category of pore size. The synthesis methods, pore characteristic testing probes/calculation models and capacitance performance are discussed in detail, and the corresponding advantages and bottlenecks are pointed out critically. Emphasis is laid on the research status and development trend of biomass-derived hierarchical porous carbon materials, including the effects of the structure and composition of biomass precursors, advanced nullotechnologies and the proportion of various pores in carbonaceous products on the capacitance performance. Finally, the coping strategies are proposed for the further development of high capacitance biomass-derived porous carbon materials.(C) 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 229, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111904, "DOI": "10.1016/j.matdes.2023.111904", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2023.111904", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026449900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, KY; Zhao, SL; Zhou, YH; Wu, YF; Zhang, SL; He, Q; Wang, X; Zhou, ZH; Fan, WJ; Tan, XL; Yang, J; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Keyu; Zhao, Shenlong; Zhou, Yihao; Wu, Yufen; Zhang, Songlin; He, Qiang; Wang, Xue; Zhou, Zhihao; Fan, Wenjing; Tan, Xulong; Yang, Jin; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Wireless Textile-Based Sensor System for Self-Powered Personalized Health Care", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Internet-connected clothing/textiles is a promising but underexplored option for future personalized health care. Here, we report a textile-based sensor (TS) system with art design for wearable biomonitoring and interacting over the Internet. The TS is capable of delivering a sensitivity up to 3.88 V/kPa for ambient tiny pressure sensing. Made of durable materials, the TS exhibits remarkable robustness after more than 80,000 cycles of continuous operation. A wireless biomonitoring system (WBS) has been developed for timely processing of the acquired human pulse wave signals, wirelessly transmitting and displaying the patient's health data via an APP interface onto a smartphone. The WBS was used to effectively diagnose obstructive sleep apnea-hypopnea syndrome during a whole night of sleep even with body movements. The textile-based wireless biomonitoring system represents a solid step toward constructing a body area network for personalized health care in the era of the Internet of Things.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 896, "End Page": 907, "Article Number": null, "DOI": "10.1016/j.matt.2019.12.025", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2019.12.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522913200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, L; Han, XY; Wang, KR; Xu, YX; Xiong, LQ; Ma, JN; Guo, ZX; Tang, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Lei; Han, Xiaoyu; Wang, Keran; Xu, Youxun; Xiong, Lunqiao; Ma, Jiani; Guo, Zhengxiao; Tang, Junwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nearly 100% selective and visible-light-driven methane conversion to formaldehyde via. single-atom Cu and Wδ+", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct solar-driven methane (CH4) reforming is highly desirable but challenging, particularly to achieve a value-added product with high selectivity. Here, we identify a synergistic ensemble effect of atomically dispersed copper (Cu) species and partially reduced tungsten (W delta+), stabilised over an oxygen-vacancy-rich WO3, which enables exceptional photocatalytic CH4 conversion to formaldehyde (HCHO) under visible light, leading to nearly 100% selectivity, a very high yield of 4979.0 mu mol center dot g(-1) within 2 h, and the normalised mass activity of 8.5 x 10(6) mu mol center dot g(Cu)(-1)center dot h(-1) of HCHO at ambient temperature. In-situ EPR and XPS analyses indicate that the Cu species serve as the electron acceptor, promoting the photo-induced electron transfer from the conduction band to O-2, generating reactive center dot OOH radicals. In parallel, the adjacent W delta+ species act as the hole acceptor and the preferred adsorption and activation site of H2O to produce hydroxyl radicals (center dot OH), and thus activate CH4 to methyl radicals (center dot CH3). The synergy of the adjacent dual active sites boosts the overall efficiency and selectivity of the conversion process. Direct solar-driven methane (CH4) reforming is highly desirable but challenging. Here, the synergy of atomic Cu species and partially reduced tungsten (W delta+), stabilized over an oxygen-vacancy-rich WO3, enables exceptional CH4 conversion to formaldehyde (HCHO) under visible light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2690, "DOI": "10.1038/s41467-023-38334-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38334-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001546000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holmberg, K; Erdemir, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holmberg, Kenneth; Erdemir, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The impact of tribology on energy use and CO2 emission globally and in combustion engine and electric cars", "Source Title": "TRIBOLOGY INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Growing concerns over energy and environmental sustainability have lately sparked worldwide interest in more efficient and cleaner transportation systems and industrial activities. Friction roughly consumes one-fifth of all energy used worldwide. One-third of all energy used in transportation goes to overcome friction. At the same time, the fruits of decades of dedicated research on all-electric vehicles powered by advanced batteries are paving the way toward a much cleaner and sustainable transportation future. In this article, we provide a short overview of what are the energy efficiency and environmental impacts of current transportation, industrial, and residential systems and how much of that efficiency is adversely affected by friction and wear losses in moving mechanical parts and components. We also touch upon recent advances in new materials, lubricants, and design changes that could reduce energy losses by 18-40%, mainly resulting from friction and wear. The savings would be up to 8.7% of the total global energy use and 1.4% of the gross national products (GNP). Finally, we calculate the energy consumption and friction losses in battery-powered electric passenger cars and show the benefit of electric cars where the total energy use is in average 3.4 times lower compared to combustion engine powered cars. The CO2 emissions are 4.5 times higher for a combustion engine car compared to an electric car when the electricity comes from renewable energy sources. Moving from fossil to renewable energy sources may cut down the energy losses due to friction in energy production by more than 60%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 389, "End Page": 396, "Article Number": null, "DOI": "10.1016/j.triboint.2019.03.024", "DOI Link": "http://dx.doi.org/10.1016/j.triboint.2019.03.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469157500038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, CY; He, DD; Zhang, Q; Tong, F; Shi, ZT; Tian, H; Qu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Chen-Yu; He, Dan-Dan; Zhang, Qi; Tong, Fei; Shi, Zhao-Tao; Tian, He; Qu, Da-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust and dynamic underwater adhesives enabled by catechol-functionalized poly(disulfides) network", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A robust underwater adhesive material is achieved by coupling natural thioctic acid with mussel-inspired iron-catechol chemistry, showing a high-strength, tunable and reusable adhesion to diverse surfaces. Developing molecular approaches to the creation of robust and water-resistant adhesive materials promotes a fundamental understanding of interfacial adhesion mechanisms as well as future applications of biomedical adhesive materials. Here, we present a simple and robust strategy that combines natural thioctic acid and mussel-inspired iron-catechol complexes to enable ultra-strong adhesive materials that can be used underwater and simultaneously exhibit unprecedentedly high adhesion strength on diverse surfaces. Our experimental results show that the robust crosslinking interaction of the iron-catechol complexes, as well as high-density hydrogen bonding, are responsible for the ultra-high interfacial adhesion strength. The embedding effect of the hydrophobic solvent-free network of poly(disulfides) further enhances the water-resistance. The dynamic covalent poly(disulfides) network also makes the resulting materials reconfigurable, thus enabling reusability via repeated heating and cooling. This molecule-engineering strategy offers a general and versatile solution to the design and construction of dynamic supramolecular adhesive materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2023, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwac139", "DOI": "10.1093/nsr/nwac139", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac139", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001218600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, XL; Zeng, AP; Gao, JH; Hu, ZH; Xu, CY; Son, JH; Jeong, SY; Zhang, CX; Li, MY; Wang, K; Yan, H; Ma, ZF; Wang, YS; Woo, HY; Zhang, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Xiaoling; Zeng, Anping; Gao, Jinhua; Hu, Zhenghao; Xu, Chunyu; Son, Jae Hoon; Jeong, Sang Young; Zhang, Caixia; Li, Mengyang; Wang, Kai; Yan, He; Ma, Zaifei; Wang, Yongsheng; Woo, Han Young; Zhang, Fujun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching 18% efficiency of ternary organic photovoltaics with wide bandgap polymer donor and well compatible Y6:Y6-1O as acceptor", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A series of ternary organic photovoltaics (OPVs) are fabricated with one wide bandgap polymer D18-Cl as donor, and well compatible Y6 and Y6-1O as acceptor. The open-circuit-voltage (V-OC) of ternary OPVs is monotonously increased along with the incorporation of Y6-1O, indicating that the alloy state should be formed between Y6 and Y6-1O due to their excellent compatibility. The energy loss can be minimized by incorporating Y6-1O, leading to the V-OC improvement of ternary OPVs. By finely adjusting the Y6-1O content, a power conversion efficiency of 17.91% is achieved in the optimal ternary OPVs with 30 wt% Y6-1O in acceptors, resulting from synchronously improved short-circuit-current density (J(SC)) of 25.87 mA cm(-2), fill factor (FF) of 76.92% and V-OC of 0.900 V in comparison with those of D18-Cl : Y6 binary OPVs. The J(SC) and FF improvement of ternary OPVs should be ascribed to comprehensively optimal photon harvesting, exciton dissociation and charge transport in ternary active layers. The more efficient charge separation and transport process in ternary active layers can be confirmed by the magnetophotocurrent and impedance spectroscopy experimental results, respectively. This work provides new insight into constructing highly efficient ternary OPVs with well compatible Y6 and its derivative as acceptor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwaa305", "DOI": "10.1093/nsr/nwaa305", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa305", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692594900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YX; Li, JX; Song, S; Kang, J; Tsao, Y; Chen, SC; Mottini, V; McConnell, K; Xu, WH; Zheng, YQ; Tok, JBH; George, PM; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yuxin; Li, Jinxing; Song, Shang; Kang, Jiheong; Tsao, Yuchi; Chen, Shucheng; Mottini, Vittorio; McConnell, Kelly; Xu, Wenhui; Zheng, Yu-Qing; Tok, Jeffrey B-H; George, Paul M.; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphing electronics enable neuromodulation in growing tissue", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bioelectronics for modulating the nervous system have shown promise in treating neurological diseases(1-3). However, their fixed dimensions cannot accommodate rapid tissue growth(4,5) and may impair development(6). For infants, children and adolescents, once implanted devices are outgrown, additional surgeries are often needed for device replacement, leading to repeated interventions and complications(6-8). Here, we address this limitation with morphing electronics, which adapt to in vivo nerve tissue growth with minimal mechanical constraint. We design and fabricate multilayered morphing electronics, consisting of viscoplastic electrodes and a strain sensor that eliminate the stress at the interface between the electronics and growing tissue. The ability of morphing electronics to self-heal during implantation surgery allows a reconfigurable and seamless neural interface. During the fastest growth period in rats, morphing electronics caused minimal damage to the rat nerve, which grows 2.4-fold in diameter, and allowed chronic electrical stimulation and monitoring for 2 months without disruption of functional behavior. Morphing electronics offers a path toward growth-adaptive pediatric electronic medicine. Viscoplastic electronic devices adapt as nerves enlarge in growing animals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 38, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1031, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41587-020-0495-2", "DOI Link": "http://dx.doi.org/10.1038/s41587-020-0495-2", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529298500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raizada, P; Soni, V; Kumar, A; Singh, P; Khan, AAP; Asiri, AM; Thakur, VK; Nguyen, VH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raizada, Pankaj; Soni, Vatika; Kumar, Abhinulldan; Singh, Pardeep; Khan, Aftab Aslam Parwaz; Asiri, Abdullah M.; Thakur, Vijay Kumar; Van-Huy Nguyen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface defect engineering of metal oxides photocatalyst for energy application and water treatment", "Source Title": "JOURNAL OF MATERIOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite metal oxides offer excellent characteristics in the field of photocatalysis, they often suffer from charge carrier recombination as well as limited visible response, which indeed reduce the charge kinetics process and ultimately reduce the photocatalytic output. Defect engineering is a sophisticated technique to manufacture defects and alter the geometric structure and chemical environment of the host. The present study provides an all-inclusive outline of recent developments on the classification of metal oxide defects based on the dimensions of a host crystal lattice. Precisely, surface modification of metal oxides through OD (point), 1D (line), 2D (planar), and 3D (volume) defects with their subsequent mechanism and impact on photocatalytic performance are presented. By wisely amending the morphology (cores along with the shells) and electronic structure of metal oxide photocatalysts (TiO2, ZnO, Bi2O3, Fe2O4 etc.) through different attuned and veritable approaches, their photocatalytic activity can be substantially improved. Optimal studies on defect engineering not only expose the altered physicochemical features but also modulate the electron-hole pair dynamics, stability, and active radical production for various photoredox reactions. Altered atomic, as well as electronic configuration, facilitated a photocatalyst material to have different optical features, adsorption properties along with improved carrier transfer as well as isolation rate. Thus, the systematic exploration of photocatalytic rudiments of defect rich metal oxide for various applications such as H-2 evolution, CO2 reduction, pollutant degradation, and bacterial disinfection could bring significant research advancement in this field. (C) 2020 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 388, "End Page": 418, "Article Number": null, "DOI": "10.1016/j.jmat.2020.10.009", "DOI Link": "http://dx.doi.org/10.1016/j.jmat.2020.10.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609500200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JF; Hörmann, N; Oveisi, E; Loiudice, A; De Gregorio, GL; Andreussi, O; Marzari, N; Buonsanti, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jianfeng; Hormann, Nicolas; Oveisi, Emad; Loiudice, Anna; De Gregorio, Gian Luca; Andreussi, Oliviero; Marzari, Nicola; Buonsanti, Raffaella", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potential-induced nulloclustering of metallic catalysts during electrochemical CO2 reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In catalysis science stability is as crucial as activity and selectivity. Understanding the degradation pathways occurring during operation and developing mitigation strategies will eventually improve catalyst design, thus facilitating the translation of basic science to technological applications. Herein, we reveal the unique and general degradation mechanism of metallic nullocatalysts during electrochemical CO2 reduction, exemplified by different sized copper nullocubes. We follow their morphological evolution during operation and correlate it with the electrocatalytic performance. In contrast with the most common coalescence and dissolution/precipitation mechanisms, we find a potential-driven nulloclustering to be the predominullt degradation pathway. Grand-potential density functional theory calculations confirm the role of the negative potential applied to reduce CO2 as the main driving force for the clustering. This study offers a novel outlook on future investigations of stability and degradation reaction mechanisms of nullocatalysts in electrochemical CO2 reduction and, more generally, in electroreduction reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3117, "DOI": "10.1038/s41467-018-05544-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05544-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440777100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YJ; Qiao, JW; Ma, SG; Gao, MC; Yang, HJ; Chen, MW; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Y. J.; Qiao, J. W.; Ma, S. G.; Gao, M. C.; Yang, H. J.; Chen, M. W.; Zhang, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A hexagonal close-packed high-entropy alloy: The effect of entropy", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of disordered solid solution in the hexagonal close-packed (hcp) structure in the GdHoLaTbY alloy and its mechanical properties were investigated in this study. The single hcp phase of the alloy in the as-cast state was confirmed by X-ray diffraction and scanning electron microscopy analyses. The compressive yield strength, fracture strength, and plastic strain of the alloy are 108 MPa, 880 MPa, and 21.8%, respectively, and the Vickers hardness is 96 HV. The results show that the yield strength, fracture strength, and hardness of the alloy obey the rule of mixture, which indicates that there is no hardening effect from entropy. Although the high entropy of mixing stabilizes the solid solution against intermetallic compounds, lack of severe lattice distortion from elastic strain or electronic interactions between principal elements impacts little on the mechanical properties. Crown Copyright (C) 2016 Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2016, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10, "End Page": 15, "Article Number": null, "DOI": "10.1016/j.matdes.2016.01.149", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2016.01.149", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371296000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QQ; He, XD; Peng, JJ; Yu, XH; Tang, H; Zhang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qinqin; He, Xudong; Peng, Jinjun; Yu, Xiaohui; Tang, Hua; Zhang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hot-electron-assisted S-scheme heterojunction of tungsten oxide/graphitic carbon nitride for broad-spectrum photocatalytic H2 generation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extended light absorption and dynamic charge separation are vital factors that determine the effectiveness of photocatalysts. In this study, a nonmetallic plasmonic S-scheme photocatalyst was fabricated by loading 1D plasmonic W18O49 nullowires onto 2D g-C3N4 nullosheets. W18O49 nullowires play the dual role of a light absorption antenna-that extends light adsorption-and a hot electron donor-that assists the water reduction reaction in a wider light spectrum range. Moreover, S-scheme charge transfer resulting from the matching bandgaps of W18O49 and g-C3N4 can lead to strong redox capability and high migration speed of the photoinduced charges. Consequently, in this study, W18O49/g-C3N4 hybrids exhibited higher photocatalytic H-2 generation than that of pristine g-C3N4 under light irradiation of 420-550 nm. Furthermore, the H-2 production rate of the best-performing W18O49/g-C3N4 hybrid was 41.5 mu mol.g(-1).h(-1) upon exposure to monochromatic light at 550 nm, whereas pure g-C3N4 showed negligible activity. This study promotes novel and environmentally friendly hot-electron-assisted S-scheme photocatalysts for the broad-spectrum utilization of solar light. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 42, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1478, "End Page": 1487, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63753-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63753-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649097900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, J; Wang, QK; Jiang, GB; Xu, CW; Zhao, CJ; Xiang, YJ; Chen, Y; Wen, SC; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Juan; Wang, Qingkai; Jiang, Guobao; Xu, Changwen; Zhao, Chujun; Xiang, Yuanjiang; Chen, Yu; Wen, Shuangchun; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ytterbium-doped fiber laser passively mode locked by few-layer Molybdenum Disulfide (MoS2) saturable absorber functioned with evanescent field interaction", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By coupling few-layer Molybdenum Disulfide (MoS2) with fiber-taper evanescent light field, a new type of MoS2 based nonlinear optical modulating element had been successfully fabricated as a two-dimensional layered saturable absorber with strong light-matter interaction. This MoS2-taper-fiber device is not only capable of passively mode-locking an all-normal-dispersion ytterbium-doped fiber laser and enduring high power laser excitation (up to 1 W), but also functions as a polarization sensitive optical modulating component (that is, different polarized light can induce different nonlinear optical response). Thanks to the combined advantages from the strong nonlinear optical response in MoS2 together with the sufficiently-long-range interaction between light and MoS2, this device allows for the generation of high power stable dissipative solitons at 1042.6 nm with pulse duration of 656 ps and a repetition rate of 6.74 MHz at a pump power of 210 mW. Our work may also constitute the first example of MoS2-enabled wave-guiding photonic device, and potentially give some new insights into two-dimensional layered materials related photonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 12", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6346, "DOI": "10.1038/srep06346", "DOI Link": "http://dx.doi.org/10.1038/srep06346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341935800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, YB; Zhang, GX; Zhou, HJ; Cao, S; Zhang, Y; Wang, SL; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yibo; Zhang, Guangxun; Zhou, Huijie; Cao, Shuai; Zhang, Yi; Wang, Shuli; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Active Sites and Stability in nullo-MOFs for Electrochemical Energy Storage through Dual Regulation by Tannic Acid", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The limited active sites and poor acid-alkaline solution stability of metal-organic frameworks (MOFs), significantly limit their wider application. In this study, the acid property of tannic acid (TA) was used as an etchant to etch the surface-active sites. Subsequently, the further chelation of the protonated TA with the exposed metal active site can effectively protect the metal ions. Meanwhile, the TA provided a large amount of phenolic hydroxyl groups, which can greatly improve the stability of imidazolate-coordinated MOFs. The electrochemical test results indicated that the MOFs composite materials synthesized using this scheme had high specific capacitance and stability. And the mechanism of its electrochemical reaction process was explored through in situ X-ray diffraction (XRD) and theoretical calculations. In addition, the same treatment was carried out through a series of carboxyl-coordinated MOFs, which further confirmed the principle of this scheme to obtain a higher active site and stability. This paper explains the mechanism of functionalization of nullo-MOFs by polyphenolic compounds, providing new ideas for the research of nullo-MOFs. This study utilized the rich chemical properties of TA to achieve functionalization of nullo-MOFs through acid-etching and further chelation strategies. The results indicated that the functionalization effect of TA on MOFs is both universal and targeted.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2023, "Volume": 62, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202311075", "DOI Link": "http://dx.doi.org/10.1002/anie.202311075", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057880000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boley, JW; van Rees, WM; Lissandrello, C; Horenstein, MN; Truby, RL; Kotikian, A; Lewis, JA; Mahadevan, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boley, J. William; van Rees, Wim M.; Lissandrello, Charles; Horenstein, Mark N.; Truby, Ryan L.; Kotikian, Arda; Lewis, Jennifer A.; Mahadevan, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape-shifting structured lattices via multimaterial 4D printing", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape-morphing structured materials have the ability to transform a range of applications. However, their design and fabrication remain challenging due to the difficulty of controlling the underlying metric tensor in space and time. Here, we exploit a combination of multiple materials, geometry, and 4-dimensional (4D) printing to create structured heterogeneous lattices that overcome this problem. Our printable inks are composed of elastomeric matrices with tunable cross-link density and anisotropic filler that enable precise control of their elastic modulus (E) and coefficient of thermal expansion (alpha). The inks are printed in the form of lattices with curved bilayer ribs whose geometry is individually programmed to achieve local control over the metric tensor. For independent control of extrinsic curvature, we created multiplexed bilayer ribs composed of 4 materials, which enables us to encode a wide range of 3-dimensional (3D) shape changes in response to temperature. As exemplars, we designed and printed planar lattices that morph into frequency-shifting antennae and a human face, demonstrating functionality and geometric complexity, respectively. Our inverse geometric design and multimaterial 4D printing method can be readily extended to other stimuli-responsive materials and different 2-dimensional (2D) and 3D cell designs to create scalable, reversible, shape-shifting structures with unprecedented complexity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2019, "Volume": 116, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20856, "End Page": 20862, "Article Number": null, "DOI": "10.1073/pnas.1908806116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1908806116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000490183000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, SD; Yuan, YY; Cai, XL; Zhang, CJ; Hu, F; Liang, J; Zhang, GX; Zhang, DQ; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Shidang; Yuan, Youyong; Cai, Xiaolei; Zhang, Chong-Jing; Hu, Fang; Liang, Jing; Zhang, Guanxin; Zhang, Deqing; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the singlet-triplet energy gap: a unique approach to efficient photosensitizers with aggregation-induced emission (AIE) characteristics", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficiency of the intersystem crossing process can be improved by reducing the energy gap between the singlet and triplet excited states (Delta E-ST), which offers the opportunity to improve the yield of the triplet excited state. Herein, we demonstrate that modulation of the excited states is also an effective strategy to regulate the singlet oxygen generation of photosensitizers. Based on our previous studies that photosensitizers with aggregation-induced emission characteristics (AIE) showed enhanced fluorescence and efficient singlet oxygen production in the aggregated state, a series of AIE fluorogens such as TPDC, TPPDC and PPDC were synthesized, which showed DEST values of 0.48, 0.35 and 0.27 eV, respectively. A detailed study revealed that PPDC exhibited the highest singlet oxygen efficiency (0.89) as nulloaggregates, while TPDC exhibited the lowest efficiency (0.28), inversely correlated with their DEST values. Due to their similar optical properties, TPDC and PPDC were further encapsulated into nulloparticles (NPs). Subsequent surface modification with cell penetrating peptide (TAT) yielded TAT-TPDC NPs and TAT-PPDC NPs. As a result of the stronger singlet oxygen generation, TAT-PPDC NPs showed enhanced cancer cell ablation as compared to TAT-TPDC NPs. Fine-tuning of the singlet-triplet energy gap is thus proven to be an effective new strategy to generate efficient photosensitizers for photodynamic therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 434, "Times Cited, All Databases": 448, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5824, "End Page": 5830, "Article Number": null, "DOI": "10.1039/c5sc01733e", "DOI Link": "http://dx.doi.org/10.1039/c5sc01733e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361212000058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Talaie, E; Duffort, V; Smith, HL; Fultz, B; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Talaie, Elahe; Duffort, Victor; Smith, Hillary L.; Fultz, Brent; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure of the high voltage phase of layered P2-Na2/3-z[Mn1/2Fe1/2]O2 and the positive effect of Ni substitution on its stability", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A combination of operando X-ray diffraction, pair distribution function (PDF) analysis coupled with electrochemical measurements and Mossbauer spectroscopy elucidates the nature of the phase transitions induced by insertion and extraction of sodium ions in P2-Na-0.67[NiyMn0.5+yFe0.5-2y]O-2 (y = 0, 0.10, 0.15). When phase transitions are avoided, the optimal cathode material - P2-Na0.67Fe0.2Mn0.65Ni0.15O2 - delivers 25% more energy than the unsubstituted material, sustaining high specific energy (350 Wh kg(-1)) at moderate rates and maintains 80% of the original energy density after 150 cycles - a significant improvement in performance vs. the unsubstituted analogue. The crystal structure of the high voltage phase is solved for the first time by X-ray PDF analysis of P2-Na0.67-zFe0.5Mn0.5O2 (where z similar to 0.5), revealing that migration of the transition metals - particularly Fe3+ - into tetrahedral sites in the interlayer space occurs at high potential. This results in new short range order between two adjacent layers. Although the transition metal migration is reversible as proven by electrochemical performance, it induces a large disfavourable cell polarization. The deleterious high voltage transition is mitigated by substitution of Fe3+ by Mn4+/Ni2+, giving rise to better cycling performance. Moreover, as demonstrated by Fe-57 Mossbauer spectroscopy, the much lower ratio of Fe4+O6 to Fe3+O6 observed systematically across the range of Ni content - compared to the values expected from a purely ionic model - suggests redox activity involves the O-2p orbitals owing to their overlap with the transition metal-3d orbitals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2512, "End Page": 2523, "Article Number": null, "DOI": "10.1039/c5ee01365h", "DOI Link": "http://dx.doi.org/10.1039/c5ee01365h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358730600029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, J; Kuang, XF; Li, JZ; Zhong, JH; Zeng, C; Cao, LK; Liu, ZW; Zeng, ZXS; Luo, ZY; He, TC; Pan, AL; Liu, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Juan; Kuang, Xiaofei; Li, Junzi; Zhong, Jiahong; Zeng, Cheng; Cao, Lingkai; Liu, Zongwen; Zeng, Zhouxiaosong; Luo, Ziyu; He, Tingchao; Pan, Anlian; Liu, Yanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant nonlinear optical activity in two-dimensional palladium diselenide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonlinear optical effects in layered two-dimensional transition metal chalcogenides have been extensively explored recently because of the promising prospect of the nonlinear optical effects for various optoelectronic applications. However, these materials possess sizable bandgaps ranging from visible to ultraviolet region, so the investigation of narrow-bandgap materials remains deficient. Here, we report our comprehensive study on the nonlinear optical processes in palladium diselenide (PdSe2) that has a near-infrared bandgap. Interestingly, this material exhibits a unique thickness-dependent second harmonic generation feature, which is in contrast to other transition metal chalcogenides. Furthermore, the two-photon absorption coefficients of 1-3 layer PdSe2 (beta similar to 4.16x10(5), 2.58x10(5), and 1.51x10(5)cmGW(-1)) are larger by two and three orders of magnitude than that of the conventional two-dimensional materials, and giant modulation depths (alpha(s)similar to 32%, 27%, and 24%) were obtained in 1-3 layer PdSe2. Such unique nonlinear optical characteristics make PdSe2 a potential candidate for technological innovations in nonlinear optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1083, "DOI": "10.1038/s41467-021-21267-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21267-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621232800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Juenger, MCG; Snellings, R; Bernal, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Juenger, Maria C. G.; Snellings, Ruben; Bernal, Susan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supplementary cementitious materials: New sources, characterization, and performance insights", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional supplementary cementitious materials (SCMs), such as blast furnace slags or fly ashes, have been used for many decades, and a large body of knowledge has been collected regarding their compositional make-up and their impacts on cement hydration and concrete properties. This accumulated empirical experience can provide a solid, confident base to go beyond the status quo and develop a new generation of low-clinker cements composed of new types and combinations of SCMs. The need for new sources of SCMs has never been greater, as supplies of traditional SCMs are becoming restricted, and the demand for SCMs to reduce CO2 emissions from concrete production is increasing. In this paper, recent research on emerging SCM sources is reviewed, along with new developments in characterizing and qualifying SCMs for use and improved knowledge of SCMs on long-term concrete performance and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 656, "Times Cited, All Databases": 682, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 122, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 257, "End Page": 273, "Article Number": null, "DOI": "10.1016/j.cemconres.2019.05.008", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2019.05.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473380700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mastro, MA; Kuramata, A; Calkins, J; Kim, J; Ren, F; Peartong, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mastro, Michael A.; Kuramata, Akito; Calkins, Jacob; Kim, Jihyun; Ren, Fan; Peartong, S. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Opportunities and Future Directions for Ga2O3", "Source Title": "ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The beta-polytype of Ga2O3 has a bandgap of similar to 4.8 eV, can be grown in bulk form from melt sources, has a high breakdown field of similar to 8MV. cm(-1) and is promising for power electronics and solar blind UV detectors, as well as extreme environment electronics (high temperature, high radiation, and high voltage (low power) switching. High quality bulk Ga2O3 is now commercially available from several sources and n-type epi structures are also coming onto the market. There are also significant efforts worldwide to grow more complex epi structures, including beta-(AlxGa(1x)) O-2(3)/Ga2O3 and beta-(InxGa(1-x))(2)O-3/Ga2O3 heterostructures, and thus this materials system is poised to make rapid advances in devices. To fully exploit these advantages, advances in bulk and epitaxial crystal growth, device design and processing are needed. This article provides some perspectives on these needs. (C) The Author(s) 2017. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "P356", "End Page": "P359", "Article Number": null, "DOI": "10.1149/2.0031707jss", "DOI Link": "http://dx.doi.org/10.1149/2.0031707jss", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409027700030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, L; Hendon, CH; Minier, MA; Walsh, A; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Lei; Hendon, Christopher H.; Minier, Mikael A.; Walsh, Aron; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Million-Fold Electrical Conductivity Enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reaction of FeCl2 and H4DSBDC (2,5-disulfhydrylbenzene-1,4-dicarboxylic acid) leads to the formation of Fe-2(DSBDC), an analogue of M-2(DOBDC) (MOE-74, DOBDC4- = 2,5-dihydroxybenzene-1,4-dicarboxylate), The bulk electrical conductivity values of both Fe-2(DSBDC) and Fe-2(DOBDC) are similar to 6 orders of magnitude higher than those of the Mn2+ analogues, Mn-2(DEBDC) (E = O, S). Because the metals are of the same formal oxidation state, the increase in conductivity is attributed to the loosely bound Fe2+ beta-spin electron. These results provide important insight for the rational design of conductive metal-organic frameworks, highlighting in particular the advantages of iron for synthesizing Such materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2015, "Volume": 137, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6164, "End Page": 6167, "Article Number": null, "DOI": "10.1021/jacs.5b02897", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b02897", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355053100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, L; Bai, JX; To, AC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Lin; Bai, Jiaxi; To, Albert C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functionally graded lattice structure topology optimization for the design of additive manufactured components with stress constraints", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in additive manufacturing (AM) have drawn considerable interest due to its ability to produce geometrically complex structure, such as lattice materials. In this work, a novel methodology is proposed to design graded lattice structure through topology optimization under stress constraint, in order to generate lightweight lattice structure design with predictable yield performance. Instead of using the power law of material interpolation in the SIMP method, asymptotic homogenization method is employed to compute the effective elastic properties of lattice material in terms of design variable, i.e. relative density. For yield strength, a multiscale failure model is proposed to capture yield strength of microstructure with macroscopic stress. At macroscale, a modified Hill's yield criterion is employed to describe anisotropic yield strength of lattice material. The material constants in Hill's model are assumed to be a function of relative density, and thus a model is built up to formulate yield strength of lattice structure with macroscopic stress. The experimental verification on the printed samples demonstrates that both the homogenized elastic model and yield model can accurately describe the elasticity and plasticity of the lattice structure. Based on the proposed material interpolation for lattice structure, a lattice structure topology optimization framework is proposed for minimizing total weight of the structure under stress constraint. The sensitivity analysis is performed for the implementation of the optimization algorithm. Two three-dimensionally numerical examples are performed to demonstrate the effectiveness of the proposed optimization method, as well as accuracy of the proposed homogenization technique for graded lattice structure design. Experiment is conducted to systematically examine yielding of the optimally graded lattice structure design and compare its performance with a uniform structure. It is found that the proposed optimization framework is valid for the design examples examined and can significantly enhance mechanical performance of the structure (i.e. yield loading, stiffness, energy absorption, etc.) (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 344, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 334, "End Page": 359, "Article Number": null, "DOI": "10.1016/j.cma.2018.10.010", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2018.10.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456330300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZQ; Liang, XY; Li, G; Liu, HX; Zhang, HY; Guo, JX; Chen, JW; Shen, K; San, XY; Yu, W; Schropp, REI; Mai, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiqiang; Liang, Xiaoyang; Li, Gang; Liu, Haixu; Zhang, Huiyu; Guo, Jianxin; Chen, Jingwei; Shen, Kai; San, Xingyuan; Yu, Wei; Schropp, Ruud E. I.; Mai, Yaohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "9.2%-efficient core-shell structured antimony selenide nullorod array solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimony selenide (Sb2Se3) has a one-dimensional (1D) crystal structure comprising of covalently bonded (Sb4Se6)(n) ribbons stacking together through van der Waals force. This special structure results in anisotropic optical and electrical properties. Currently, the photovoltaic device performance is dominated by the grain orientation in the Sb2Se3 thin film absorbers. Effective approaches to enhance the carrier collection and overall power-conversion efficiency are urgently required. Here, we report the construction of Sb2Se3 solar cells with high-quality Sb2Se3 nullorod arrays absorber along the [001] direction, which is beneficial for sun-light absorption and charge carrier extraction. An efficiency of 9.2%, which is the highest value reported so far for this type of solar cells, is achieved by junction interface engineering. Our cell design provides an approach to further improve the efficiency of Sb2Se3-based solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 611, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125, "DOI": "10.1038/s41467-018-07903-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07903-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455354800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, YH; Miara, LJ; Wang, Y; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Yihan; Miara, Lincoln J.; Wang, Yan; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computational Screening of Cathode Coatings for Solid-State Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state batteries are on the roadmap for commercialization as the next generation of batteries because of their potential for improved safety, power density, and energy density compared with conventional Li-ion batteries. However, the interfacial reactivity and resulting resistance between the cathode and solid-state electrolyte (SSE) lead to deterioration of cell performance. Although reduction of the cathode/SSE interfacial impedance can be achieved using cathode coatings, optimizing their compositions remains a challenge. In this work, we employ a computational framework to evaluate and screen Li-containing materials as cathode coatings, focusing on their phase stability, electrochemical and chemical stability, and ionic conductivity. From this tiered screening, polyanionic oxide coatings were identified as exhibiting optimal properties, with LiH2PO4, LiTi2(PO4)(3), and LiPO3 being particularly appealing candidates. Some lithium borates exhibiting excellent (electro) chemical stability at various interfaces are also highlighted. These results highlight the promise of using optimized polyanionic materials as cathode coatings for solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 358, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1252, "End Page": 1275, "Article Number": null, "DOI": "10.1016/j.joule.2019.02.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.02.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467969300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, YJ; Andrabi, SM; Shahriar, SMS; Wong, SL; Wang, GS; Xie, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yajuan; Andrabi, Syed Muntazir; Shahriar, S. M. Shatil; Wong, Shannon L.; Wang, Guangshun; Xie, Jingwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triggered release of antimicrobial peptide from microneedle patches for treatment of wound biofilms", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biofilms pose a great challenge for wound management. Herein, this study describes a near-infrared (NIR) light -responsive microneedle patch for on-demand release of antimicrobial peptide for treatment of wound biofilms. IR780 iodide as a photothermal conversion agent and molecularly engineered peptide W379 as an antimicrobial agent are loaded in dissolvable poly(vinylpyrrolidone) (PVP) microneedle patches followed by coating with a phase change material 1-tetradecanol (TD). After placing in an aqueous solution or biofilm containing wounds ex vivo and in vivo, upon exposure to NIR light, the incorporated IR780 induces light-to-heat conversion, causing the melting of TD. This leads to the dissolution of PVP microneedles, enabling the release of loaded W379 peptide from the microneedles into surrounding regions (e.g., solution, biofilm, wound bed). Compared with traditional microneedle patches, NIR light responsive microneedle patches can program the release of antimicrobial peptide and show high antibacterial efficacy in vitro. Meanwhile, this work indicates that NIR light responsive TD-coated, W379-loaded PVP microneedle patches show excellent antibiofilm activities ex vivo and in vivo. Additionally, this microneedle system could be a promising platform for delivering other antimicrobial agents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 43, "Times Cited, All Databases": 43, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 356, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 131, "End Page": 141, "Article Number": null, "DOI": "10.1016/j.jconrel.2023.02.030", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2023.02.030", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000956480300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, C; Huang, Y; Yu, YF; Zhang, JF; Zhuo, SF; Zhang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chao; Huang, Yi; Yu, Yifu; Zhang, Jingfang; Zhuo, Sifei; Zhang, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-1.1 nm ultrathin porous CoP nullosheets with dominullt reactive {200} facets: a high mass activity and efficient electrocatalyst for the hydrogen evolution reaction", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of a facile strategy to synthesize porous ultrathin nullosheets of non-layered materials, especially with exposed reactive facets, as highly efficient electrocatalysts for the hydrogen evolution reaction (HER), remains challenging. Herein we demonstrate a chemical transformation strategy to synthesize porous CoP ultrathin nullosheets with sub-1.1 nm thickness and exposed {200} facets via phosphidation of Co3O4 precursors. The resultant samples exhibit outstanding electrochemical HER performance: a low overpotential (only 56 and 131 mV are required for current densities of 10 and 100 mA cm(-2), respectively), a small Tafel slope of 44 mV per decade, a good stability of over 20 h, and a high mass activity of 151 A g(-1) at an overpotential of 100 mV. The latter is about 80 times higher than that of CoP nulloparticles. Experimental data and density functional theory calculations reveal that a high proportion of reactive {200} facets, high utilization efficiency of active sites, metallic nature, appropriate structural disorder, facile electron/mass transfer and rich active sites benefiting from the unique ultrathin and porous structure are the key factors for the greatly improved activity. Additionally, this facile chemical conversion strategy can be developed to a generalized method for preparing porous ultrathin nullosheets of CoSe2 and CoS that cannot be obtained using other methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2017, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2769, "End Page": 2775, "Article Number": null, "DOI": "10.1039/c6sc05687c", "DOI Link": "http://dx.doi.org/10.1039/c6sc05687c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397560500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, YH; Zhang, CY; Zhang, W; Cui, LM; Ye, CM; Hong, XF; Li, JH; Chen, RW; Zong, W; Gao, X; Zhu, JX; Jiang, PE; An, QY; Brett, DJL; Parkin, IP; He, GJ; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Yuhang; Zhang, Chengyi; Zhang, Wei; Cui, Lianmeng; Ye, Chumei; Hong, Xufeng; Li, Jinghao; Chen, Ruwei; Zong, Wei; Gao, Xuan; Zhu, Jiexin; Jiang, Peie; An, Qinyou; Brett, Dan J. L.; Parkin, Ivan P.; He, Guanjie; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible Zn Metal Anodes Enabled by Trace Amounts of Underpotential Deposition Initiators", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Routine electrolyte additives are not effective enough for uniform zinc (Zn) deposition, because they are hard to proactively guide atomic-level Zn deposition. Here, based on underpotential deposition (UPD), we propose an escort effect of electrolyte additives for uniform Zn deposition at the atomic level. With nickel ion (Ni2+) additives, we found that metallic Ni deposits preferentially and triggers the UPD of Zn on Ni. This facilitates firm nucleation and uniform growth of Zn while suppressing side reactions. Besides, Ni dissolves back into the electrolyte after Zn stripping with no influence on interfacial charge transfer resistance. Consequently, the optimized cell operates for over 900 h at 1 mA cm(-2) (more than 4 times longer than the blank one). Moreover, the universality of escort effect is identified by using Cr3+ and Co2+ additives. This work would inspire a wide range of atomic-level principles by controlling interfacial electrochemistry for various metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2023, "Volume": 62, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202301192", "DOI Link": "http://dx.doi.org/10.1002/anie.202301192", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955710500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, ZP; Ismail, BB; Zhang, XH; Yang, ZH; Liu, DH; Guo, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Zhipeng; Ismail, Balarabe B.; Zhang, Xinhui; Yang, Zhehao; Liu, Donghong; Guo, Mingming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving barrier and antibacterial properties of chitosan composite films by incorporating lignin nulloparticles and acylated soy protein isolate nullogel", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chitosan (CS) films have demonstrated strong antibacterial properties, excellent biocompatibility and biode-gradability, but poor UV blocking, oxygen and water barrier and mechanical properties limit their application in antimicrobial food packaging. In this study, CS films were incorporated with nullofillers, including lignin nulloparticles (LNP, 1-5 wt %) and acylated soy protein isolate nullogel (ASPNG, 3-7 wt %) to improve their tensile strength, oxygen and water barrier, UV blocking and antibacterial properties. SEM images illustrated that the addition of LNP and ASPNG significantly affected the surface morphology of the CS film. Meanwhile, LNP incorporation improved UV blocking property of composite film, while an improved sustained antibacterial property was achieved with ASPNG incorporation. Interestingly, CS composite film incorporated with 3% LNP and 5% ASPNG showed a remarkable increase in tensile strength (37.29-54.29 MPa) and decreased oxygen barrier property (5.73-2.83 cm3/m2.24 h MPa) relative to pure CS film. It is worth mentioning that the bacterial counts in samples treated by 3% LNP/5% ASPNG-CS composite film decreased approximately 2.37 log CFU/mL, which exhibited higher antibacterial activity than other composite films. However, this study also demonstrated that incorporation of LNP and ASPNG slightly decreased the light transmission and increased surface roughness of CS film. All in all, the CS composite film with enhanced mechanical, barriers, antibacterial properties were obtained by incorporating an appropriate proportion of LNP and ASPNG and could further be utilized as a promising antibacterial food packaging material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 134, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108091, "DOI": "10.1016/j.foodhyd.2022.108091", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2022.108091", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000862805400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Juarez-Perez, EJ; Hawash, Z; Raga, SR; Ono, LK; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Juarez-Perez, Emilio J.; Hawash, Zafer; Raga, Sonia R.; Ono, Luis K.; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal degradation of CH3NH3PbI3 perovskite into NH3 and CH3I gases observed by coupled thermogravimetry-mass spectrometry analysis", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal gravimetric and differential thermal analysis (TG-DTA) coupled with quadrupole mass spectrometry (MS) and first principles calculations were employed to elucidate the chemical nature of released gases during the thermal decomposition of CH3NH3PbI3. In contrast to the common wisdom that CH3NH3PbI3 is decomposed into CH3NH2 and HI, the major gases were methyliodide (CH3I) and ammonia (NH3). We anticipate that our findings will provide new insights into further formulations of the perovskite active material and device design that can prevent methylammonium decomposition and thus increase the long-term stability of perovskite-based opto-electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 653, "Times Cited, All Databases": 694, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3406, "End Page": 3410, "Article Number": null, "DOI": "10.1039/c6ee02016j", "DOI Link": "http://dx.doi.org/10.1039/c6ee02016j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387862100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Pang, JB; Li, YF; Yang, F; Gemming, T; Wang, K; Wang, X; Peng, SG; Liu, XY; Chang, B; Liu, H; Zhou, WJ; Cuniberti, G; Rümmeli, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shu; Pang, Jinbo; Li, Yufen; Yang, Feng; Gemming, Thomas; Wang, Kai; Wang, Xiao; Peng, Songang; Liu, Xiaoyan; Chang, Bin; Liu, Hong; Zhou, Weijia; Cuniberti, Gianaurelio; Ruemmeli, Mark H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging Internet of Things driven carbon nullotubes-based devices", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nullotubes (CNTs) have attracted great attentions in the field of electronics, sensors, healthcare, and energy conversion. Such emerging applications have driven the carbon nullotube research in a rapid fashion. Indeed, the structure control over CNTs has inspired an intensive research vortex due to the high promises in electronic and optical device applications. Here, this in-depth review is anticipated to provide insights into the controllable synthesis and applications of high-quality CNTs. First, the general synthesis and post-purification of CNTs are briefly discussed. Then, the state-of-the-art electronic device applications are discussed, including field-effect transistors, gas sensors, DNA biosensors, and pressure gauges. Besides, the optical sensors are delivered based on the photoluminescence. In addition, energy applications of CNTs are discussed such as thermoelectric energy generators. Eventually, future opportunities are proposed for the Internet of Things (IoT) oriented sensors, data processing, and artificial intelligence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4613, "End Page": 4637, "Article Number": null, "DOI": "10.1007/s12274-021-3986-7", "DOI Link": "http://dx.doi.org/10.1007/s12274-021-3986-7", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742334900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Le Roux, L; Körner, C; Tabaste, O; Lacan, F; Bigot, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chao; Le Roux, Leopold; Korner, Carolin; Tabaste, Olivier; Lacan, Franck; Bigot, Samuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Digital Twin-enabled Collaborative Data Management for Metal Additive Manufacturing Systems", "Source Title": "JOURNAL OF MANUFACTURING SYSTEMS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal Additive Manufacturing (AM) has been attracting a continuously increasing attention due to its great advantages compared to traditional subtractive manufacturing in terms of higher design flexibility, shorter development time, lower tooling cost, and fewer production wastes. However, the lack of process robustness, stability and repeatability caused by the unsolved complex relationships between material properties, product design, process parameters, process signatures, post AM processes and product quality has significantly impeded its broad acceptance in the industry. To facilitate efficient implementation of advanced data analytics in metal AM, which would support the development of intelligent process monitoring, control and optimisation, this paper proposes a novel Digital Twin (DT)-enabled collaborative data management framework for metal AM systems, where a Cloud DT communicates with distributed Edge DTs in different product lifecycle stages. A metal AM product data model that contains a comprehensive list of specific product lifecycle data is developed to support the collaborative data management. The feasibility and advantages of the proposed framework are validated through the practical implementation in a distributed metal AM system developed in the project MANUELA. A representative application scenario of cloud-based and deep learning-enabled metal AM layer defect analysis is also presented. The proposed DT-enabled collaborative data management has shown great potential in enhancing fundamental understanding of metal AM processes, developing simulation and prediction models, reducing development times and costs, and improving product quality and production efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 857, "End Page": 874, "Article Number": null, "DOI": "10.1016/j.jmsy.2020.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.jmsy.2020.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Operations Research & Management Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772827300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, F; Wang, CH; Li, YY; Ma, H; Wang, R; Liu, YC; Suzuki, N; Terashima, C; Ohtani, B; Ochiai, T; Fujishima, A; Zhang, XT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fei; Wang, Changhua; Li, Yingying; Ma, He; Wang, Rui; Liu, Yichun; Suzuki, Norihiro; Terashima, Chiaki; Ohtani, Bunsho; Ochiai, Tsuyoshi; Fujishima, Akira; Zhang, Xintong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Solar Photothermal Catalysis over Solution Plasma Activated TiO2", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colored wide-bandgap semiconductor oxides with abundant mid-gap states have long been regarded as promising visible light responsive photocatalysts. However, their catalytic activities are hampered by charge recombination at deep level defects, which constitutes the critical challenge to practical applications of these oxide photocatalysts. To address the challenge, a strategy is proposed here that includes creating shallow-level defects above the deep-level defects and thermal activating the migration of trapped electrons out of the deep-level defects via these shallow defects. A simple and scalable solution plasma processing (SPP) technique is developed to process the presynthesized yellow TiO(2)with numerous oxygen vacancies (Ov), which incorporates hydrogen dopants into the TiO(2)lattice and creates shallow-level defects above deep level of Ov, meanwhile retaining the original visible absorption of the colored TiO2. At elevated temperature, the SPP-treated TiO(2)exhibits a 300 times higher conversion rate for CO(2)reduction under solar light irradiation and a 7.5 times higher removal rate of acetaldehyde under UV light irradiation, suggesting the effectiveness of the proposed strategy to enhance the photoactivity of colored wide-bandgap oxides for energy and environmental applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 7, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000204, "DOI": "10.1002/advs.202000204", "DOI Link": "http://dx.doi.org/10.1002/advs.202000204", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000539587300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, HY; Yuan, FL; Johnston, A; Gao, CC; Choubisa, H; Gao, Y; Wang, YK; Sagar, LK; Sun, B; Li, PC; Bappi, G; Chen, B; Li, J; Wang, YK; Dong, YT; Ma, DX; Gao, YN; Liu, YC; Yuan, MJ; Saidaminov, MI; Hoogland, S; Lu, ZH; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Hongyan; Yuan, Fanglong; Johnston, Andrew; Gao, Congcong; Choubisa, Hitarth; Gao, Yuan; Wang, Ya-Kun; Sagar, Laxmi Kishore; Sun, Bin; Li, Peicheng; Bappi, Golam; Chen, Bin; Li, Jun; Wang, Yunkun; Dong, Yitong; Ma, Dongxin; Gao, Yunull; Liu, Yongchang; Yuan, Mingjian; Saidaminov, Makhsud I.; Hoogland, Sjoerd; Lu, Zheng-Hong; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Color Purity Lead-Free Perovskite Light-Emitting Diodes via Sn Stabilization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite-based light-emitting diodes (PeLEDs) are now approaching the upper limits of external quantum efficiency (EQE); however, their application is currently limited by reliance on lead and by inadequate color purity. The Rec. 2020 requires Commission Internationale de l'Eclairage coordinates of (0.708, 0.292) for red emitters, but present-day perovskite devices only achieve (0.71, 0.28). Here, lead-free PeLEDs are reported with color coordinates of (0.706, 0.294)-the highest purity reported among red PeLEDs. The variation of the emission spectrum is also evaluated as a function of temperature and applied potential, finding that emission redshifts by <3 nm under low temperature and by <0.3 nm V-1 with operating voltage. The prominent oxidation pathway of Sn is identified and this is suppressed with the aid of H3PO2. This strategy prevents the oxidation of the constituent precursors, through both its moderate reducing properties and through its forming complexes with the perovskite that increase the energetic barrier toward Sn oxidation. The H3PO2 additionally seeds crystal growth during film formation, improving film quality. PeLEDs are reported with an EQE of 0.3% and a brightness of 70 cd m(-2); this is the record among reported red-emitting, lead-free PeLEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1903213, "DOI": "10.1002/advs.201903213", "DOI Link": "http://dx.doi.org/10.1002/advs.201903213", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517147000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SC; Chang, CC; Chiu, SY; Pai, HT; Liao, TY; Hsu, CS; Chiang, WH; Tsai, MK; Chen, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Sheng-Chih; Chang, Chun-Chih; Chiu, Shih-Yun; Pai, Hsiao-Tien; Liao, Tzu-Yu; Hsu, Chia-Shuo; Chiang, Wei-Hung; Tsai, Ming-Kang; Chen, Hao Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando time-resolved X-ray absorption spectroscopy reveals the chemical nature enabling highly selective CO2 reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper electrocatalysts have been shown to selectively reduce carbon dioxide to hydrocarbons. Nevertheless, the absence of a systematic study based on time-resolved spectroscopy renders the functional agent-either metallic or oxidative Copper-for the selectivity still undecidable. Herein, we develop an operando seconds-resolved X-ray absorption spectroscopy to uncover the chemical state evolution of working catalysts. An oxide-derived Copper electrocatalyst is employed as a model catalyst to offer scientific insights into the roles metal states serve in carbon dioxide reduction reaction (CO2RR). Using a potential switching approach, the model catalyst can achieve a steady chemical state of half-Cu(0)-and-half-Cu(I) and selectively produce asymmetric C-2 products - C2H5OH. Furthermore, a theoretical analysis reveals that a surface composed of Cu-Cu(I) ensembles can have dual carbon monoxide molecules coupled asymmetrically, which potentially enhances the catalyst's CO2RR product selectivity toward C-2 products. Our results offer understandings of the fundamental chemical states and insights to the establishment of selective CO2RR. A systematic time-resolved study can provide key insights on selective carbon dioxide electro-reduction. Here, the authors report operando seconds-resolved X-ray absorption spectroscopy to uncover the chemical state evolution of working catalysts in a carbon dioxide electroreduction process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17231-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17231-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000550062500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, GQ; Hou, HS; Foster, CW; Banks, CE; Guo, TX; Jiang, YL; Zhang, Y; Ji, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Guoqiang; Hou, Hongshuai; Foster, Christopher W.; Banks, Craig E.; Guo, Tianxiao; Jiang, Yunling; Zhang, Yun; Ji, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced Hierarchical Vesicular Carbon Co-Doped with S, P, N for High-Rate Sodium Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hierarchical nulloscale carbons have received wide interest as electrode materials for energy storage and conversion due to their fast mass transfer processes, outstanding electronic conductivity, and high stability. Here, heteroatom (S, P, and N) doped hierarchical vesicular carbon (HHVC) materials with a high surface area up to 867.5 m(2) g(-1) are successfully prepared using a surface polymerization of hexachloro-cyclotriphosphazene (HCCP) and 4,4-sulfonyldiphenol (BPS) on the ZIF-8 polyhedrons. Significantly, it is the first time to achieve a controllability of the wall thickness for this unique carbon, ranging from 18 to 52 nm. When utilized as anodes for sodium ion batteries, these novel carbon materials exhibit a high specific capacity of 327.2 mAh g(-1) at 100 mA g(-1) after 100 cycles, which can be attributed to the expanded interlayer distance and enhanced conductivity derived from the doping of heteroatoms. Importantly, a high capacity of 142.6 mAh g(-1) can be obtained even at a high current density of 5 A g(-1), assigning to fast ion/electronic transmission processes stemming from the unique hierarchical vesicular structure. This work offers a new route for the fabrication/preparation of multi-heteroatom doped hierarchical vesicular materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800241, "DOI": "10.1002/advs.201800241", "DOI Link": "http://dx.doi.org/10.1002/advs.201800241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439842100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bertoli, US; Wolfer, AJ; Matthews, MJ; Delplanque, JPR; Schoenung, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bertoli, Umberto Scipioni; Wolfer, Alexander J.; Matthews, Manyalibo J.; Delplanque, Jean-Pierre R.; Schoenung, Julie M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the limitations of Volumetric Energy Density as a design parameter for Selective Laser Melting", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy density is often used as a metric to compare components manufactured with Selective Laser Melting (SLM) under different sets of deposition parameters (e.g., laser power, scan speed, layer thickness, etc.). We present a brief review of the current literature on additive manufacturing of 316L stainless steel (SS) related to input parameter scaling relations. From previously published work we identified a range of Volumetric Energy Density (VED) values that should lead to deposition of fully dense parts. In order to corroborate these data, we designed a series of experiments to investigate the reliability of VED as a design parameter by comparing single tracks of 316L SS deposited with variable deposition parameters. Our results show the suitability of VED as a design parameter to describe SLM to be limited to a narrow band of applicability, which is attributed to the inability of this parameter to capture the complex physics of the melt pool. Caution should be exercised when using VED as a design parameter for SLM. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 624, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2017, "Volume": 113, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 331, "End Page": 340, "Article Number": null, "DOI": "10.1016/j.matdes.2016.10.037", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2016.10.037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389142800039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Melocchi, A; Parietti, F; Maroni, A; Foppoli, A; Gazzaniga, A; Zema, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Melocchi, Alice; Parietti, Federico; Maroni, Alessandra; Foppoli, Anastasia; Gazzaniga, Andrea; Zema, Lucia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hot-melt extruded filaments based on pharmaceutical grade polymers for 3D printing by fused deposition modeling", "Source Title": "INTERNATIONAL JOURNAL OF PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused deposition modeling (FDM) is a 3D printing technique based on the deposition of successive layers of thermoplastic materials following their softening/melting. Such a technique holds huge potential for the manufacturing of pharmaceutical products and is currently under extensive investigation. Challenges in this field are mainly related to the paucity of adequate filaments composed of pharmaceutical grade materials, which are needed for feeding the FDM equipment. Accordingly, a number of polymers of common use in pharmaceutical formulation were evaluated as starting materials for fabrication via hot melt extrusion of filaments suitable for FDM processes. By using a twin-screw extruder, filaments based on insoluble (ethylcellulose, Eudragit (R) RL), promptly soluble (polyethylene oxide, Kollicoat (R) IR), enteric soluble (Eudragit (R) L, hydroxypropyl methylcellulose acetate succinate) and swellable/erodible (hydrophilic cellulose derivatives, polyvinyl alcohol, Soluplus (R)) polymers were successfully produced, and the possibility of employing them for printing 600 mu m thick disks was demonstrated. The behavior of disks as barriers when in contact with aqueous fluids was shown consistent with the functional application of the relevant polymeric components. The produced filaments were thus considered potentially suitable for printing capsules and coating layers for immediate or modified release, and, when loaded with active ingredients, any type of dosage forms. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 334, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2016, "Volume": 509, "Issue": "1-2", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 255, "End Page": 263, "Article Number": null, "DOI": "10.1016/j.ijpharm.2016.05.036", "DOI Link": "http://dx.doi.org/10.1016/j.ijpharm.2016.05.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378949800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, LL; Lin, HP; Li, YY; Liao, F; Lifshitz, Y; Sheng, MQ; Lee, ST; Shao, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Lili; Lin, Haiping; Li, Youyong; Liao, Fan; Lifshitz, Yeshayahu; Sheng, Minqi; Lee, Shuit-Tong; Shao, Mingwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A rhodium/silicon co-electrocatalyst design concept to surpass platinum hydrogen evolution activity at high overpotentials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, platinum-based electrocatalysts show the best performance for hydrogen evolution. All hydrogen evolution reaction catalysts should however obey Sabatier's principle, that is, the adsorption energy of hydrogen to the catalyst surface should be neither too high nor too low to balance between hydrogen adsorption and desorption. To overcome the limitation of this principle, here we choose a composite (rhodium/silicon nullowire) catalyst, in which hydrogen adsorption occurs on rhodium with a large adsorption energy while hydrogen evolution occurs on silicon with a small adsorption energy. We show that the composite is stable with better hydrogen evolution activity than rhodium nulloparticles and even exceeding those of commercial platinum/carbon at high overpotentials. The results reveal that silicon plays a key role in the electrocatalysis. This work may thus open the door for the design and fabrication of electrocatalysts for high-efficiency electric energy to hydrogen energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12272, "DOI": "10.1038/ncomms12272", "DOI Link": "http://dx.doi.org/10.1038/ncomms12272", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380842200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JF; Luo, HY; Zhai, B; Lu, RG; Guo, ZN; Zhang, H; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianfeng; Luo, Hongyu; Zhai, Bo; Lu, Rongguo; Guo, Zhinull; Zhang, Han; Liu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black phosphorus: a two-dimension saturable absorption material for mid-infrared Q-switched and mode-locked fiber lasers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Black phosphorus (BP) as a novel class of two-dimension (2D) materials has recently attracted enormous attention as a result of its unique physical and chemical features. The remarkably strong light-matter interaction and tunable direct band-gap at a wide range make it an ideal candidate especially in the mid-infrared wavelength region as the saturable absorber (SA). In this paper, the simple and effective liquid phase exfoliation (LPE) method was used to fabricate BP. By introducing the same BP SA into two specifically designed rare earth ions doped fluoride fiber lasers at mid-infrared wavebands, Q-switching with the pulse energy of 4.93 mu J and mode-locking with the pulse duration of 8.6 ps were obtained, respectively. The operation wavelength of similar to 2970 nm for generated pulse is the reported longest wavelength for BP SA based fiber lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 30361, "DOI": "10.1038/srep30361", "DOI Link": "http://dx.doi.org/10.1038/srep30361", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380214800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Chen, ZH; Yang, H; Wen, LH; Yi, Z; Zhou, ZG; Dai, B; Zhang, JG; Wu, XW; Wu, PH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hao; Chen, Zihao; Yang, Hua; Wen, Lianghua; Yi, Zao; Zhou, Zigang; Dai, Bo; Zhang, Jianguo; Wu, Xianwen; Wu, Pinghui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-mode surface plasmon resonullce absorber based on dart-type single-layer graphene", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, a multi-mode surface plasmon resonullce absorber based on dart-type single-layer graphene is proposed, which has the advantages of polarization independence, tunability, high sensitivity, high figure of merit, etc. The device consists of a top layer dart-like patterned single-layer graphene array, a thicker silicon dioxide spacer layer and a metal reflector layer, and has simple structural characteristics. The numerical results show that the device achieves the perfect polarization-independent absorption at the resonullce wavelengths of lambda(I) = 3369.55 nm, lambda(II) = 3508.35 nm, lambda(III) = 3689.09 nm and lambda(IV) = 4257.72 nm, with the absorption efficiencies of 99.78%, 99.40%, 99.04% and 99.91%, respectively. The absorption effect of the absorber can be effectively regulated and controlled by adjusting the numerical values such as the geometric parameters and the structural period p of the single-layer graphene array. In addition, by controlling the chemical potential and the relaxation time of the graphene layer, the resonullt wavelength and the absorption efficiency of the mode can be dynamically tuned. And can keep high absorption in a wide incident angle range of 0 degrees to 50 degrees. At last, we exposed the structure to different environmental refractive indices, and obtained the corresponding maximum sensitivities in four resonullce modes, which are S-I = 635.75 nm RIU-1, S-II = 695.13 nm RIU-1, S-III = 775.38 nm RIU-1 and S-IV = 839.39 nm RIU-1. Maximum figure of merit are 54.03 RIU-1, 51.49 RIU-1, 43.56 RIU-1, and 52.14 RIU-1, respectively. Therefore, this study has provided a new inspiration for the design of the graphene-based tunable multi-band perfect metamaterial absorber, which can be applied to the fields such as photodetectors and chemical sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2022, "Volume": 12, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7821, "End Page": 7829, "Article Number": null, "DOI": "10.1039/d2ra00611a", "DOI Link": "http://dx.doi.org/10.1039/d2ra00611a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766251000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Matussin, SN; Harunsani, MH; Khan, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Matussin, Shaidatul Najihah; Harunsani, Mohammad Hilni; Khan, Mohammad Mansoob", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CeO2 and CeO2-based nullomaterials for photocatalytic, antioxidant and antimicrobial activities", "Source Title": "JOURNAL OF RARE EARTHS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cerium oxide (CeO2), one of the most significant rare-earth oxides, has attracted considerable interest over the past decades. This is primarily due to the ease in Ce3+/Ce4+ redox ability as well as other factors that affect the efficacy of CeO2 and CeO2-based materials. CeO2 and CeO2-based materials have shown enhanced responses in catalytic and photocatalytic activities for environmental and biological applica-tions. In addition, the formation of Ce3+ and oxygen vacancies in CeO2 has aided in enhancing CeO2 activities. In order to produce oxygen-deficient CeO2 and CeO2-based materials, a variety of synthesis methods were used and are highlighted in this review. Therefore, this review compiles and discusses the mechanisms that involve oxygen vacancies, defects, and Ce3+ formation for environmental applications, such as photocatalytic dye degradation, photocatalytic CO2 reduction, and non-colored pollutants removal. The biological applications of CeO2, such as antioxidant enzyme mimetic, antioxidant reactive oxygen species/reactive nitrogen species, and antimicrobial activities, are also discussed. Additionally, future prospects are also suggested for future development and detailed investigations. (c) 2022 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 41, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 167, "End Page": 181, "Article Number": null, "DOI": "10.1016/j.jre.2022.09.003", "DOI Link": "http://dx.doi.org/10.1016/j.jre.2022.09.003", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964038700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Sun, ML; Qiao, RM; Renfrew, SE; Ma, L; Wu, TP; Hwang, S; Nordlund, D; Su, D; Amine, K; Lu, J; McCloskey, BD; Yang, WL; Tong, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jing; Sun, Meiling; Qiao, Ruimin; Renfrew, Sara E.; Ma, Lu; Wu, Tianpin; Hwang, Sooyeon; Nordlund, Dennis; Su, Dong; Amine, Khalil; Lu, Jun; McCloskey, Bryan D.; Yang, Wanli; Tong, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elucidating anionic oxygen activity in lithium-rich layered oxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent research has explored combining conventional transition-metal redox with anionic lattice oxygen redox as a new and exciting direction to search for high-capacity lithium-ion cathodes. Here, we probe the poorly understood electrochemical activity of anionic oxygen from a material perspective by elucidating the effect of the transition metal on oxygen redox activity. We study two lithium-rich layered oxides, specifically lithium nickel metal oxides where metal is either manganese or ruthenium, which possess a similar structure and discharge characteristics, but exhibit distinctly different charge profiles. By combining X-ray spectroscopy with operando differential electrochemical mass spectrometry, we reveal completely different oxygen redox activity in each material, likely resulting from the different interaction between the lattice oxygen and transition metals. This work provides additional insights into the complex mechanism of oxygen redox and development of advanced high-capacity lithium-ion cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 947, "DOI": "10.1038/s41467-018-03403-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03403-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426543800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Szymanski, NJ; Rendy, B; Fei, YX; Kumar, RE; He, TJ; Milsted, D; McDermott, MJ; Gallant, M; Cubuk, ED; Merchant, A; Kim, H; Jain, A; Bartel, CJ; Persson, K; Zeng, Y; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Szymanski, Nathan J.; Rendy, Bernardus; Fei, Yuxing; Kumar, Rishi E.; He, Tanjin; Milsted, David; McDermott, Matthew J.; Gallant, Max; Cubuk, Ekin Dogus; Merchant, Amil; Kim, Haegyeom; Jain, Anubhav; Bartel, Christopher J.; Persson, Kristin; Zeng, Yan; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An autonomous laboratory for the accelerated synthesis of novel materials", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To close the gap between the rates of computational screening and experimental realization of novel materials1,2, we introduce the A-Lab, an autonomous laboratory for the solid-state synthesis of inorganic powders. This platform uses computations, historical data from the literature, machine learning (ML) and active learning to plan and interpret the outcomes of experiments performed using robotics. Over 17 days of continuous operation, the A-Lab realized 41 novel compounds from a set of 58 targets including a variety of oxides and phosphates that were identified using large-scale ab initio phase-stability data from the Materials Project and Google DeepMind. Synthesis recipes were proposed by natural-language models trained on the literature and optimized using an active-learning approach grounded in thermodynamics. Analysis of the failed syntheses provides direct and actionable suggestions to improve current techniques for materials screening and synthesis design. The high success rate demonstrates the effectiveness of artificial-intelligence-driven platforms for autonomous materials discovery and motivates further integration of computations, historical knowledge and robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2023, "Volume": 624, "Issue": 7990, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 86, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06734-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06734-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169148800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jindo, K; Mizumoto, H; Sawada, Y; Sanchez-Monedero, MA; Sonoki, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jindo, K.; Mizumoto, H.; Sawada, Y.; Sanchez-Monedero, M. A.; Sonoki, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physical and chemical characterization of biochars derived from different agricultural residues", "Source Title": "BIOGEOSCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biochar is widely recognized as an efficient tool for carbon sequestration and soil fertility. The understanding of its chemical and physical properties, which are strongly related to the type of the initial material used and pyrolysis conditions, is crucial to identify the most suitable application of biochar in soil. A selection of organic wastes with different characteristics (e.g., rice husk (RH), rice straw (RS), wood chips of apple tree (Malus pumila) (AB), and oak tree (Quercus serrata) (OB)) were pyrolyzed at different temperatures (400, 500, 600, 700, and 800 degrees C) in order to optimize the physicochemical properties of biochar as a soil amendment. Low-temperature pyrolysis produced high biochar yields; in contrast, high-temperature pyrolysis led to biochars with a high C content, large surface area, and high adsorption characteristics. Biochar obtained at 600 degrees C leads to a high recalcitrant character, whereas that obtained at 400 degrees C retains volatile and easily labile compounds. The biochar obtained from rice materials (RH and RS) showed a high yield and unique chemical properties because of the incorporation of silica elements into its chemical structure. The biochar obtained from wood materials (AB and OB) showed high carbon content and a high absorption character.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 11, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6613, "End Page": 6621, "Article Number": null, "DOI": "10.5194/bg-11-6613-2014", "DOI Link": "http://dx.doi.org/10.5194/bg-11-6613-2014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346357100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dovesi, R; Orlando, R; Erba, A; Zicovich-Wilson, CM; Civalleri, B; Casassa, S; Maschio, L; Ferrabone, M; De La Pierre, M; D'Arco, P; Noël, Y; Causà, M; Rérat, M; Kirtman, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dovesi, Roberto; Orlando, Roberto; Erba, Alessandro; Zicovich-Wilson, Claudio M.; Civalleri, Bartolomeo; Casassa, Silvia; Maschio, Lorenzo; Ferrabone, Matteo; De La Pierre, Marco; D'Arco, Philippe; Noel, Yves; Causa, Mauro; Rerat, Michel; Kirtman, Bernard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CRYSTAL14: A Program for the Ab Initio Investigation of Crystalline Solids", "Source Title": "INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capabilities of the CRYSTAL14 program are presented, and the improvements made with respect to the previous CRYSTAL09 version discussed. CRYSTAL14 is an ab initio code that uses a Gaussian-type basis set: both pseudopotential and all-electron strategies are permitted; the latter is not much more expensive than the former up to the first-second transition metal rows of the periodic table. A variety of density functionals is available, including as an extreme case Hartree-Fock; hybrids of various nature (global, range-separated, double) can be used. In particular, a very efficient implementation of global hybrids, such as popular B3LYP and PBE0 prescriptions, allows for such calculations to be performed at relatively low computational cost. The program can treat on the same grounds zero-dimensional (molecules), one-dimensional (polymers), two-dimensional (slabs), as well as three-dimensional (3D; crystals) systems. No spurious 3D periodicity is required for low-dimensional systems as happens when plane-waves are used as a basis set. Symmetry is fully exploited at all steps of the calculation; this permits, for example, to investigate nullotubes of increasing radius at a nearly constant cost (better than linear scaling!) or to perform self-consistent-field (SCF) calculations on fullerenes as large as (10,10), with 6000 atoms, 84,000 atomic orbitals, and 20 SCF cycles, on a single core in one day. Three versions of the code exist, serial, parallel, and massive-parallel. In the second one, the most relevant matrices are duplicated, whereas in the third one the matrices in reciprocal space are distributed for diagonalization. All the relevant vectors are now dynamically allocated and deallocated after use, making CRYSTAL14 much more agile than the previous version, in which they were statically allocated. The program now fits more easily in low-memory machines (as many supercomputers nowadays are). CRYSTAL14 can be used on parallel machines up to a high number of cores (benchmarks up to 10,240 cores are documented) with good scalability, the main limitation remaining the diagonalization step. Many tensorial properties can be evaluated in a fully automated way by using a single input keyword: elastic, piezoelectric, photoelastic, dielectric, as well as first and second hyperpolarizabilies, electric field gradients, Born tensors and so forth. Many tools permit a complete analysis of the vibrational properties of crystalline compounds. The infrared and Raman intensities are now computed analytically and related spectra can be generated. Isotopic shifts are easily evaluated, frequencies of only a fragment of a large system computed and nuclear contribution to the dielectric tensor determined. New algorithms have been devised for the investigation of solid solutions and disordered systems. The topological analysis of the electron charge density, according to the Quantum Theory of Atoms in Molecules, is now incorporated in the code via the integrated merge of the TOPOND package. Electron correlation can be evaluated at the Moller-Plesset second-order level (namely MP2) and a set of double-hybrids are presently available via the integrated merge with the CRYSCOR program. (C) 2014 Wiley Periodicals, Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1152, "Times Cited, All Databases": 1180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2014, "Volume": 114, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1287, "End Page": 1317, "Article Number": null, "DOI": "10.1002/qua.24658", "DOI Link": "http://dx.doi.org/10.1002/qua.24658", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Mathematics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341718400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, CZ; Li, ZL; Zhang, XM; Xu, WW; Chen, WM; Zhao, KN; Wang, Y; Hong, S; Wu, QL; Li, MC; Mei, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chaozheng; Li, Zhenglin; Zhang, Xiaoman; Xu, Wangwang; Chen, Weimin; Zhao, Kangning; Wang, Yao; Hong, Shu; Wu, Qinglin; Li, Mei-Chun; Mei, Changtong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergic Effect of Dendrite-Free and Zinc Gating in Lignin-Containing Cellulose nullofibers-MXene Layer Enabling Long-Cycle-Life Zinc Metal Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uncontrollable zinc dendrite growth and parasitic reactions have greatly hindered the development of high energy and long life rechargeable aqueous zinc-ion batteries. Herein, the synergic effect of a bifunctional lignin-containing cellulose nullofiber (LCNF)-MXene (LM) layer to stabilize the interface of zinc anode is reported. On one hand, the LCNF provides enough strength (43.7 MPa) at relative low porosity (52.2%) to enable the diffusion limited dendrite suppression, while, on the other hand, the MXene serves as a zinc gating layer, facilitating the zinc ion mobility, restricting the active water/anions from degradation in the electrode/electrolyte interface, and epitaxially guiding zinc deposition along (002) plane. Benefiting from the synergic effect of diffusion limited dendrite suppression and zinc gate, the LM layer enabled a high coulombic efficiency (CE) of 98.9% with a low overpotential of 43.1 mV at 1 mA cm(-2) in Zn//Cu asymmetric cells. More importantly, Zn//MnO2 full cells with the LM layer achieve a high-capacity retention of 90.0% for over 1000 cycles at 1 A g(-1), much higher than the full cell without the protective layer (73.9% over 500 cycles). The work provides a new insight in designing a dendrite-free zinc anode for long-cycle-life batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 9, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202380, "DOI": "10.1002/advs.202202380", "DOI Link": "http://dx.doi.org/10.1002/advs.202202380", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000825379800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MY; Biesold, GM; Choi, W; Yu, J; Deng, YL; Silvestre, C; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mingyue; Biesold, Gill M.; Choi, Woosung; Yu, Jiwoo; Deng, Yulin; Silvestre, Clara; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances in polymers and polymer composites for food packaging", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growing world population, evolving urbanization, and globalization have created more demand for food, which has increased challenges in food safety. Development and innovations in food packaging, one of the most important components in the food industry, is of key importance as food safety issues have gathered tremendous attention of the world. Food packaging is mainly intended to prevent a deterioration in quality of foods and beverages during distribution, sales, and consumption. Polymeric materials have been widely used as packaging materials due to their advantageous characteristics, including excellent mechanical, thermal, and corrosion-resistant properties, a light-weight nature, and ease in production. Polymer composites refer to polymers impregnated with nullomaterials and organic or inorganic compounds. Polymer composites have been applied in the packaging industry to enhance or bestow additional properties to packaging materials. This review summarizes the recent advances in polymer and polymer composites used in food packaging applications. First, progress in the polymers utilized for food packaging, with a focus on biodegradable polymers, will be introduced. Subsequently, the utilities of polymer composites in advanced food packaging will be highlighted and categorized into three classifications of packaging: improved, active, and intelligent packaging. Next, concerns on the relevant safety issues and regulations will be briefly discussed. Finally, an outlook on the future research directions of polymer and polymer composites for food packaging will be provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 53, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 134, "End Page": 161, "Article Number": null, "DOI": "10.1016/j.mattod.2022.01.022", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2022.01.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000796538100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lesiak, B; Kövér, L; Tóth, J; Zemek, J; Jiricek, P; Kromka, A; Rangam, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lesiak, B.; Kover, L.; Toth, J.; Zemek, J.; Jiricek, P.; Kromka, A.; Rangam, N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "C sp2/sp3 hybridisations in carbon nullomaterials - XPS and (X)AES study", "Source Title": "APPLIED SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape of the C KLL (KVV) Auger spectrum provides a measure of C sp(2)/sp(3) hybridisations, alternative to C 1s spectra fitting. Due to a smaller kinetic energy of C KLL electrons than C 1s photoelectrons the investigated information depths are attributed to lower or higher surface sensitivity, respectively. Shape of the KLL Auger spectrum of carbon nullostructures reflects density of electronic states (DOS) and contains contributions of sp(2) (graphite) and/or sp(3) (diamond) hybridisations, whereas for oxygen and hydrogen containing nullostructures this shape reflects chemical effects. C sp(2)/sp(3) content is evaluated from parameter D, which is defined as an energy difference between the maximum and minimum of the first-derivative C KLL spectrum, where dependence of parameter D on C sp(2)/sp(3) hybridisations is assumed to be linear between the D values of graphite and diamond. Derived values of parameter D and therefore C sp(2)/sp(3) hybridisations were found to be influenced by procedure of smoothing the Auger spectrum and D values used for reference materials with pure sp(3) and pure sp(2) hybridisations. Purpose of this work was to estimate reliability of C sp(2)/sp(3) hybridisations derived from parameters D determined for a set of carbon nullomaterials and study the chemical and morphological effects on the measured parameter D values. Presence of an inhomogeneous distribution of hybridisation as a function of depth from the surface was identified mainly in graphene oxides in contrast to graphite and reduced graphene oxide. The largest influence on parameter D and then evaluated C sp(2)/sp(3) content resulted from oxygen and hydrogen at the surface and applied smoothing procedure in contrary to structural properties of carbon nullomaterials (crystallinity, grain size). Values of parameter D for C sp(3) and C sp2 hybridisations, i.e. 13.2 eV and 23.1 eV, respectively, are recommended to be used for linear interpolation proposed by Lascovich et al. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2018, "Volume": 452, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 223, "End Page": 231, "Article Number": null, "DOI": "10.1016/j.apsusc.2018.04.269", "DOI Link": "http://dx.doi.org/10.1016/j.apsusc.2018.04.269", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433203600026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, N; Lee, H; Han, G; Kang, M; Park, S; Kim, DE; Lee, M; Kim, MJ; Na, Y; Oh, S; Bang, SJ; Jang, TS; Kim, HE; Park, J; Shin, SR; Jung, HD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Nahyun; Lee, Hyun; Han, Ginam; Kang, Minho; Park, Sinwoo; Kim, Dong Eung; Lee, Minyoung; Kim, Moon-Jo; Na, Yuhyun; Oh, SeKwon; Bang, Seo-Jun; Jang, Tae-Sik; Kim, Hyoun-Ee; Park, Jungwon; Shin, Su Ryon; Jung, Hyun-Do", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D-Printed Functional Hydrogel by DNA-Induced Biomineralization for Accelerated Diabetic Wound Healing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chronic wounds in diabetic patients are challenging because their prolonged inflammation makes healing difficult, thus burdening patients, society, and health care systems. Customized dressing materials are needed to effectively treat such wounds that vary in shape and depth. The continuous development of 3D-printing technology along with artificial intelligence has increased the precision, versatility, and compatibility of various materials, thus providing the considerable potential to meet the abovementioned needs. Herein, functional 3D-printing inks comprising DNA from salmon sperm and DNA-induced biosilica inspired by marine sponges, are developed for the machine learning-based 3D-printing of wound dressings. The DNA and biomineralized silica are incorporated into hydrogel inks in a fast, facile manner. The 3D-printed wound dressing thus generates provided appropriate porosity, characterized by effective exudate and blood absorption at wound sites, and mechanical tunability indicated by good shape fidelity and printability during optimized 3D printing. Moreover, the DNA and biomineralized silica act as nullotherapeutics, enhancing the biological activity of the dressings in terms of reactive oxygen species scavenging, angiogenesis, and anti-inflammation activity, thereby accelerating acute and diabetic wound healing. These bioinspired 3D-printed hydrogels produce using a DNA-induced biomineralization strategy are an excellent functional platform for clinical applications in acute and chronic wound repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300816", "DOI Link": "http://dx.doi.org/10.1002/advs.202300816", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972345100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, NN; Yu, LL; Liu, BJ; Yu, F; Li, LQ; Xiao, Y; Yang, JH; Ma, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ningning; Yu, Lanlan; Liu, Baojun; Yu, Fei; Li, Liqing; Xiao, Yi; Yang, Jinhu; Ma, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti3C2-MXene Partially Derived Hierarchical 1D/2D TiO2/Ti3C2 Heterostructure Electrode for High-Performance Capacitive Deionization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing faradaic electrode with superior desalination performance is important for expanding the applications of capacitive deionization (CDI). Herein, a simple one-step alkalized treatment for in situ synthesis of 1D TiO2 nullowires on the surface of 2D Ti3C2 nullosheets, forming a Ti3C2-MXene partially derived hierarchical 1D/2D TiO2/Ti3C2 heterostructure as the cathode electrode is reported. Cross-linked TiO2 nullowires on the surface help avoid layer stacking while acting as the protective layer against contact of internal Ti3C2 with dissolved oxygen in water. The inner Ti3C2 MXene nullosheets cross over the TiO2 nullowires can provide abundant active adsorption sites and short ion/electron diffusion pathways. . Density functional theory calculations demonstrated that Ti3C2 can consecutively inject electrons into TiO2, indicating the high electrochemical activity of the TiO2/Ti3C2. Benefiting from the 1D/2D hierarchical structure and synergistic effect of TiO2 and Ti3C2, TiO2/Ti3C2 heterostructure presents a favorable hybrid CDI performance, with a superior desalination capacity (75.62 mg g(-1)), fast salt adsorption rate (1.3 mg g(-1) min(-1)), and satisfactory cycling stability, which is better than that of most published MXene-based electrodes. This study provides a feasible partial derivative strategy for construction of a hierarchical 1D/2D heterostructure to overcome the restrictions of 2D MXene nullosheets in CDI.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202204041", "DOI Link": "http://dx.doi.org/10.1002/advs.202204041", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000890426600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Caspani, L; Kaipurath, RPM; Clerici, M; Ferrera, M; Roger, T; Kim, J; Kinsey, N; Pietrzyk, M; Di Falco, A; Shalaev, VM; Boltasseva, A; Faccio, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Caspani, L.; Kaipurath, R. P. M.; Clerici, M.; Ferrera, M.; Roger, T.; Kim, J.; Kinsey, N.; Pietrzyk, M.; Di Falco, A.; Shalaev, V. M.; Boltasseva, A.; Faccio, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Nonlinear Refractive Index in ε-Near-Zero Materials", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New propagation regimes for light arise from the ability to tune the dielectric permittivity to extremely low values. Here, we demonstrate a universal approach based on the low linear permittivity values attained in the epsilon-near-zero (ENZ) regime for enhancing the nonlinear refractive index, which enables remarkable light-induced changes of the material properties. Experiments performed on Al-doped ZnO (AZO) thin films show a sixfold increase of the Kerr nonlinear refractive index (n(2)) at the ENZ wavelength, located in the 1300 nm region. This in turn leads to ultrafast light-induced refractive index changes of the order of unity, thus representing a new paradigm for nonlinear optics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2016, "Volume": 116, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 233901, "DOI": "10.1103/PhysRevLett.116.233901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.233901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377338900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dujardin, C; Auffray, E; Bourret-Courchesne, E; Dorenbos, P; Lecoq, P; Nikl, M; Vasil'ev, AN; Yoshikawa, A; Zhu, RY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dujardin, C.; Auffray, E.; Bourret-Courchesne, E.; Dorenbos, P.; Lecoq, P.; Nikl, M.; Vasil'ev, A. N.; Yoshikawa, A.; Zhu, R. -Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Needs, Trends, and Advances in Inorganic Scintillators", "Source Title": "IEEE TRANSACTIONS ON NUCLEAR SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents new developments in inorganic scintillators widely used for radiation detection. It addresses major emerging research topics outlining current needs for applications and material sciences issues with the overall aim to provide an up-to-date picture of the field. While the traditional forms of scintillators have been crystals and ceramics, new research on films, nulloparticles, and microstructured materials is discussed as these material forms can bring new functionality and therefore find applications in radiation detection. The last part of the contribution reports on the very recent evolutions of the most advanced theories, methods, and analyses to describe the scintillation mechanisms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 65, "Issue": 8, "Part Number": 2, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1977, "End Page": 1997, "Article Number": null, "DOI": "10.1109/TNS.2018.2840160", "DOI Link": "http://dx.doi.org/10.1109/TNS.2018.2840160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442365000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Sun, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kun; Sun, WaiChing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A multiscale multi-permeability poroplasticity model linked by recursive homogenizations and deep learning", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many geological materials, such as shale, mudstone, carbonate rock, limestone and rock salt are multi-porosity porous media in which pores of different scales may co-exist in the host matrix. When fractures propagate in these multi-porosity materials, these pores may enlarge and coalesce and therefore change the magnitude and the principal directions of the effective permeability tensors. The pore-fluid inside the cracks and the pores of host matrix may interact and exchange fluid mass, but the difference in hydraulic properties of these pores often means that a single homogenized effective permeability tensor field is insufficient to characterize the evolving hydraulic properties of these materials at smaller time scale. Furthermore, the complexity of the hydro-mechanical coupling process and the induced mechanical and hydraulic anisotropy originated from the micro-fracture and plasticity at grain scale also makes it difficult to propose, implement and validate separated macroscopic constitutive laws for numerical simulations. This article presents a hybrid data-driven method designed to capture the multiscale hydro-mechanical coupling effect of porous media with pores of various different sizes. At each scale, data-driven models generated from supervised machine learning are hybridized with classical constitutive laws in a directed graph that represents the numerical models. By using sub-scale simulations to generate database to train material models, an offline homogenization procedure is used to replace the up-scaling procedure to generate cohesive laws for localized physical discontinuities at both grain and specimen scales. Through a proper homogenization procedure that preserves spatial length scales, the proposed method enables field-scale simulations to gather insights from meso-scale and grain-scale micro-structural attributes. This method is proven to be much more computationally efficient than the classical DEM-FEM or FEM2 approach while at the same time more robust and flexible than the classical surrogate modeling approach. Due to the usage of bridging-scale technique, the proposed model may provide multiple opportunities to incorporate different types of simulations and experimental data across different length scales for machine learning. Numerical issues will also be discussed. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2018, "Volume": 334, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": 380, "Article Number": null, "DOI": "10.1016/j.cma.2018.01.036", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2018.01.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431197000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JH; Jang, JW; Jo, YH; Abdi, FF; Lee, YH; van de Krol, R; Lee, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jin Hyun; Jang, Ji-Wook; Jo, Yim Hyun; Abdi, Fatwa F.; Lee, Young Hye; van de Krol, Roel; Lee, Jae Sung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hetero-type dual photoanodes for unbiased solar water splitting with extended light harvesting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal oxide semiconductors are promising photoelectrode materials for solar water splitting due to their robustness in aqueous solutions and low cost. Yet, their solar-to-hydrogen conversion efficiencies are still not high enough for practical applications. Here we present a strategy to enhance the efficiency of metal oxides, hetero-type dual photoelectrodes, in which two photoanodes of different bandgaps are connected in parallel for extended light harvesting. Thus, a photoelectrochemical device made of modified BiVO4 and alpha-Fe2O3 as dual photoanodes utilizes visible light up to 610nm for water splitting, and shows stable photocurrents of 7.0 +/- 0.2 mA cm(-2) at 1.23 V-RHE under 1 sun irradiation. A tandem cell composed with the dual photoanodes-silicon solar cell demonstrates unbiased water splitting efficiency of 7.7%. These results and concept represent a significant step forward en route to the goal of >10% efficiency required for practical solar hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13380, "DOI": "10.1038/ncomms13380", "DOI Link": "http://dx.doi.org/10.1038/ncomms13380", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389816900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Even, J; Pedesseau, L; Katan, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Even, Jacky; Pedesseau, Laurent; Katan, Claudine", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processable metal halide perovskites recently opened a new route toward low-cost manufacture of photovoltaic cells. Converting sunlight into electrical energy depends on several factors among which a broad absorption across the solar spectrum and attractive charge transport properties are of primary importance. Hybrid perovskites meet such prerequisites, but despite foremost experimental research efforts, their understanding remains scanty. Here we show that in these materials the appropriate absorption and transport properties are afforded by the multibandgap and multivalley nature of their band structure. We also investigate the nature Of the photoexcited species. Our analysis suggests exciton screening by collective orientational motion of the organic cations at room temperature, leading to almost free carriers. Molecular collective motion is also expected to couple to carrier diffusion at room temperature. In mixed halides, our interpretation indicates that doping might hinder collective molecular motions, leading to good transport properties despite alloying and local lattice strain.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 470, "Times Cited, All Databases": 523, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2014, "Volume": 118, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11566, "End Page": 11572, "Article Number": null, "DOI": "10.1021/jp503337a", "DOI Link": "http://dx.doi.org/10.1021/jp503337a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337013400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, HR; Zhou, CK; Tian, Y; Siegrist, T; Ma, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Haoran; Zhou, Chenkun; Tian, Yu; Siegrist, Theo; Ma, Biwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Dimensional Organometal Halide Perovskites", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometal halide perovskites have recently emerged as a highly promising class of functional materials for a variety of applications. The exceptional structural tunability enables these materials to possess three- (3D), two- (2D), one- (1D), and zero-dimensional (OD) structures at the molecular level. Remarkable progress has been realized in the research of perovskites in recent years, focusing mainly on 3D and 2D structures but leaving low dimensional 1D and OD structures significantly underexplored. Here we offer our perspective on the most exciting developments in the low-dimensional organometal halide perovskites. Due to the strong quantum confinement and site isolation, 1D and OD perovskites exhibit remarkable and useful properties that are significantly different from those of 3D and 2D perovskites. The excitement about the recent developments lies not only in the specific achievements but also in what these materials represent in terms of a new paradigm in materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 598, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 54, "End Page": 62, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00926", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00926", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422814500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Knobloch, T; Illarionov, YY; Ducry, F; Schleich, C; Wachter, S; Watanabe, K; Taniguchi, T; Mueller, T; Waltl, M; Lanza, MR; Vexler, MI; Luisier, M; Grasser, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Knobloch, Theresia; Illarionov, Yury Yu.; Ducry, Fabian; Schleich, Christian; Wachter, Stefan; Watanabe, Kenji; Taniguchi, Takashi; Mueller, Thomas; Waltl, Michael; Lanza, Mario; Vexler, Mikhail I.; Luisier, Mathieu; Grasser, Tibor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The performance limits of hexagonal boron nitride as an insulator for scaled CMOS devices based on two-dimensional materials", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Complementary metal-oxide-semiconductor (CMOS) logic circuits at their ultimate scaling limits place extreme demands on the properties of all materials involved. The requirements for semiconductors are well explored and could possibly be satisfied by a number of layered two-dimensional (2D) materials, such as transition metal dichalcogenides or black phosphorus. The requirements for gate insulators are arguably even more challenging. At present, hexagonal boron nitride (hBN) is the most common 2D insulator and is widely considered to be the most promising gate insulator in 2D material-based transistors. Here we assess the material parameters and performance limits of hBN. We compare experimental and theoretical tunnel currents through ultrathin layers (equivalent oxide thickness of less than 1 nm) of hBN and other 2D gate insulators, including the ideal case of defect-free hBN. Though its properties make hBN a candidate for many applications in 2D nulloelectronics, excessive leakage currents lead us to conclude that hBN is unlikely to be suitable for use as a gate insulator in ultrascaled CMOS devices. This Perspective assesses the performance limits of hexagonal boron nitride when used as a gate insulator in complementary metal-oxide-semiconductor (CMOS) devices based on two-dimensional materials, concluding that due to excessive leakage currents, the material is unlikely to be suitable for use in ultrascaled CMOS devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 98, "End Page": 108, "Article Number": null, "DOI": "10.1038/s41928-020-00529-x", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-00529-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620936200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, JJ; He, CT; Pei, JJ; Chen, WX; He, DS; He, YQ; Zhuang, ZB; Chen, C; Peng, Q; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Junjie; He, Chun-Ting; Pei, Jiajing; Chen, Wenxing; He, Dongsheng; He, Yiqing; Zhuang, Zhongbin; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating water dissociation kinetics by isolating cobalt atoms into ruthenium lattice", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing highly active and robust platinum-free catalysts for hydrogen evolution reaction is of vital importance for clean energy applications yet challenging. Here we report highly active and stable cobalt-substituted ruthenium nullosheets for hydrogen evolution, in which cobalt atoms are isolated in ruthenium lattice as revealed by aberration-corrected high-resolution transmission electron microscopy and X-ray absorption fine structure measurement. Impressively, the cobalt-substituted ruthenium nullosheets only need an extremely low overpotential of 13 mV to achieve a current density of 10 mA cm(-2) in 1M KOH media and an ultralow Tafel slope of 29 mV dec(-1), which exhibit top-level catalytic activity among all reported platinum-free electrocatalysts. The theoretical calculations reveal that the energy barrier of water dissociation can greatly reduce after single cobalt atom substitution, leading to its superior hydrogen evolution performance. This study provides a new insight into the development of highly efficient platinum-free hydrogen evolution catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4958, "DOI": "10.1038/s41467-018-07288-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07288-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451047100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Romano, S; Brückner-Foit, A; Brandao, A; Gumpinger, J; Ghidini, T; Beretta, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Romano, S.; Brueckner-Foit, A.; Brandao, A.; Gumpinger, J.; Ghidini, T.; Beretta, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fatigue properties of AlSi10Mg obtained by additive manufacturing: Defect-based modelling and prediction of fatigue strength", "Source Title": "ENGINEERING FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ability to predict the fatigue resistance of parts produced by additive manufacturing (AM) is a very current and frequently relevant open issue. The qualification of AM structural parts often needs a costly and time-consuming series of fatigue tests, on both samples and full-scale parts. Proper control of the AM process allows obtaining comparable and even better fatigue resistance than those obtained with standard manufacturing. Despite this, the experimental results often show a large scatter, mostly due to the presence of defects. In this framework, the present work summarizes the research activity aimed at modelling the high cycle fatigue (HCF) resistance in the presence of defects, focusing on AlSi10Mg produced by selective laser melting. Three batches of samples were investigated by X-ray micro computed tomography and tested under fatigue. A lower bound resistance curve was obtained, which introduced artificial defects of size corresponding to that of the largest occurring defects. The analysis shows that a combination of defect-tolerant design with well-established and newly proposed fracture mechanics methods is the key to expressing the relationship between the fatigue strength and material quality. This is done through suitable statistics of material defects induced by the AM process. The same concepts are then applied in a fatigue crack growth simulation model based on the maximum defect size, for estimating both the life and scatter of the data in the region of elastic material response. Based on this wide activity, it can be concluded that fracture mechanics-based analysis appears to be the tool needed for supporting the application of additive manufacturing to safety-critical components and their qualification. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 187, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 165, "End Page": 189, "Article Number": null, "DOI": "10.1016/j.engfracmech.2017.11.002", "DOI Link": "http://dx.doi.org/10.1016/j.engfracmech.2017.11.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428231700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Nitopi, SA; Bertheussen, E; Orazov, M; Morales-Guio, CG; Liu, XY; Higgins, DC; Chan, KR; Norskov, JK; Hahn, C; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Nitopi, Stephanie A.; Bertheussen, Erlend; Orazov, Marat; Morales-Guio, Carlos G.; Liu, Xinyan; Higgins, Drew C.; Chan, Karen; Norskov, Jens K.; Hahn, Christopher; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Carbon Monoxide Reduction on Polycrystalline Copper: Effects of Potential, Pressure, and pH on Selectivity toward Multicarbon and Oxygenated Products", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the surface reactivity of CO, which is a key intermediate during electrochemical CO2 reduction, is crucial for the development of catalysts that selectively target desired products for the conversion of CO2 to fuels and chemicals. In this study, a custom designed electrochemical cell is utilized to investigate planar polycrystalline copper as an electrocatalyst for CO reduction under alkaline conditions. Seven major CO reduction products have been observed including various hydrocarbons and oxygenates which are also common CO2 reduction products, strongly indicating that CO is a key reaction intermediate for these further-reduced products. A comparison of CO and CO2 reduction demonstrates that there is a large decrease in the overpotential for C-C coupled products under CO reduction conditions. The effects of CO partial pressure and electrolyte pH are investigated; we conclude that the aforementioned large potential shift is primarily a pH effect. Thus, alkaline conditions can be used to increase the energy efficiency of CO and CO, reduction to C-C coupled products, when these cathode reactions are coupled to the oxygen evolution reaction at the anode. Further analysis of the reaction products reveals common trends in selectivity that indicate both the production of oxygenates and C-C coupled products are favored at lower overpotentials. These selectivity trends are generalized by comparing the results on planar Cu to current state-of-the-art high-surface-area Cu catalysts, which are able to achieve high oxygenate selectivity by operating at the same geometric current density at lower overpotentials. Combined, these findings outline key principles for designing CO and CO2 electrolyzers that are able to produce valuable C-C coupled products with high energy efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7445, "End Page": 7454, "Article Number": null, "DOI": "10.1021/acscatal.8b01200", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b01200", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441112400064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, ZL; Wang, G; Bao, WC; Li, JL; Li, LH; Mostaed, A; Yang, HJ; Ji, HF; Li, DJ; Feteira, A; Xu, FF; Sinclair, DC; Wang, DW; Liu, SY; Reaney, IM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Zhilun; Wang, Ge; Bao, Weichao; Li, Jinglei; Li, Linhao; Mostaed, Ali; Yang, Huijing; Ji, Hongfen; Li, Dejun; Feteira, Antonio; Xu, Fangfang; Sinclair, Derek C.; Wang, Dawei; Liu, Shi-Yu; Reaney, Ian M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior energy density through tailored dopant strategies in multilayer ceramic capacitors", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Gerson-Marshall (1959) relationship predicts an increase in dielectric breakdown strength (BDS) and therefore, recoverable energy density (W-rec) with decreasing dielectric layer thickness. This relationship only operates however, if the total resistivity of the dielectric is sufficiently high and the electrical microstructure is homogeneous (no short circuit diffusion paths). BiFeO3-SrTiO3(BF-ST) is a promising base for developing high energy density capacitors but Bi-rich compositions which have the highest polarisability per unit volume are ferroelectric rather than relaxor and are electrically too conductive. Here, we present a systematic strategy to optimise BDS and maximum polarisationvia: (i) Nb-doping to increase resistivity by eliminating hole conduction and promoting electrical homogeneity and (ii) alloying with a third perovskite end-member, BiMg2/3Nb1/3O3(BMN), to reduce long range polar coupling without decreasing the average ionic polarisability. These strategies result in an increase in BDS to giveW(rec)= 8.2 J cm(-3)at 460 kV cm(-1)for BF-ST-0.03Nb-0.1BMN ceramics, which when incorporated in a multilayer capacitor with dielectric layers of 8 mu m thickness gives BDS > 1000 kV cm(-1)andW(rec)= 15.8 J cm(-3).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2020, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2938, "End Page": 2948, "Article Number": null, "DOI": "10.1039/d0ee02104k", "DOI Link": "http://dx.doi.org/10.1039/d0ee02104k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000570224500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, N; Chen, D; Niu, F; Wang, S; Qin, LS; Huang, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ning; Chen, Da; Niu, Feng; Wang, Sen; Qin, Laishun; Huang, Yuexiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced visible light photocatalytic activity of Gd-doped BiFeO3 nulloparticles and mechanism insight", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To investigate the effect of Gd doping on photocatalytic activity of BiFeO3 (BFO), Gd-doped BFO nulloparticles containing different Gd doping contents (Bi(1-x)GdxFeO3, x = 0.00, 0.01, 0.03, 0.05) were synthesized using a facile sol-gel route. The obtained products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectra, and ultraviolet-visible diffuse reflectance spectroscopy, and their photocatalytic activities were evaluated by photocatalytic decomposition of Rhodamine B in aqueous solution under visible light irradiation. It was found that the Gd doping content could significantly affect the photocatalytic activity of as-prepared Gd-doped BFO, and the photocatalytic activity increased with increasing the Gd doping content up to the optimal value and then decreased with further enhancing Gd doping content. To elucidate the enhanced photocatalytic mechanism of Gd-doped BFO, the trapping experiments, photoluminescence, photocurrent and electrochemical impedance measurements were performed. On the basis of these experimental results, the enhanced photocatalytic activities of Gd-doped BFO could be ascribed to the increased optical absorption, the efficient separation and migration of photogenerated charge carriers as well as the decreased recombination probability of electron-hole pairs derived from the Gd doping effect. Meanwhile, the possible photocatalytic mechanism of Gd-doped BFO was critically discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26467, "DOI": "10.1038/srep26467", "DOI Link": "http://dx.doi.org/10.1038/srep26467", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376189200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arbabi, E; Arbabi, A; Kamali, SM; Horie, Y; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arbabi, Ehsan; Arbabi, Amir; Kamali, Seyedeh Mahsa; Horie, Yu; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling the sign of chromatic dispersion in diffractive optics with dielectric metasurfaces", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diffraction gratings disperse light in a rainbow of colors with the opposite order than refractive prisms, a phenomenon known as negative dispersion. While refractive dispersion can be controlled via material refractive index, diffractive dispersion is fundamentally an interference effect dictated by geometry. Here we show that this fundamental property can be altered using dielectric metasurfaces, and we experimentally demonstrate diffractive gratings and focusing mirrors with positive, zero, and hyper-negative dispersion. These optical elements are implemented using a reflective metasurface composed of dielectric nullo-posts that provide simultaneous control over phase and its wavelength derivative. In addition, as a first practical application, we demonstrate a focusing mirror that exhibits a five-fold reduction in chromatic dispersion, and thus an almost three-times increase in operation bandwidth compared with a regular diffractive element. This concept challenges the generally accepted dispersive properties of diffractive optical devices and extends their applications and functionalities. (C) 2017 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 625, "End Page": 632, "Article Number": null, "DOI": "10.1364/OPTICA.4.000625", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.4.000625", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404108200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Einaga, M; Sakata, M; Ishikawa, T; Shimizu, K; Eremets, MI; Drozdov, AP; Troyan, IA; Hirao, N; Ohishi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Einaga, Mari; Sakata, Masafumi; Ishikawa, Takahiro; Shimizu, Katsuya; Eremets, Mikhail I.; Drozdov, Alexander P.; Troyan, Ivan A.; Hirao, Naohisa; Ohishi, Yasuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal structure of the superconducting phase of sulfur hydride", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A superconducting critical temperature above 200 K has recently been discovered in H2S (or D2S) under high hydrostatic pressure(1,2). These measurements were interpreted in terms of a decomposition of these materials into elemental sulfur and a hydrogen-rich hydride that is responsible for the superconductivity, although direct experimental evidence for this mechanism has so far been lacking. Here we report the crystal structure of the superconducting phase of hydrogen sulfide (and deuterium sulfide) in the normal and superconducting states obtained by means of synchrotron X-ray diffraction measurements, combined with electrical resistance measurements at both room and low temperatures. We find that the superconducting phase is mostly in good agreement with the theoretically predicted body-centred cubic (bcc) structure for H3S3. The presence of elemental sulfur is also manifest in the X-ray diffraction patterns, thus proving the decomposition mechanism of H2S to H3S + S under pressure(4-6).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 835, "End Page": 838, "Article Number": null, "DOI": "10.1038/nphys3760", "DOI Link": "http://dx.doi.org/10.1038/nphys3760", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383219800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WK; Liu, H; Du, HY; Zhang, MY; Wang, CF; Yin, R; Pan, CF; Liu, CT; Shen, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wenke; Liu, Hu; Du, Houyi; Zhang, Minyue; Wang, Chunfeng; Yin, Rui; Pan, Caofeng; Liu, Chuntai; Shen, Changyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust and superelastic spider web-like polyimide fiber-based conductive composite aerogel for extreme temperature-tolerant linear pressure sensor", "Source Title": "SCIENCE CHINA-MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure sensors represent the cornerstone of artificial tactile sensing. Extensive research has been conducted on high-performance pressure sensors; however, the realization of high sensitivity, wide linear response range, and wide working temperature range remains a tremendous challenge. Here, triethylamine was innovatively applied to achieve the homogeneous dispersion of hydrophobic polyimide fibres (PIFs) in a carbon nullotube (CNT) aqueous dispersion without deteriorating the structure of the fibres, and a robust and superelastic spider web-like PIF/CNT conductive composite aerogel was developed using the freezedrying and thermal imidization technique for a pressure sensor with a wide linear sensing range (0.01-53.34 kPa), ultralow detection limit (10 Pa), high sensitivity (0.507 kPa-1), fast response/recovery time (85/80 ms), stable fast compression response (500 mm min-1), and excellent cyclic fatigue resistance (5000 times). Finite element analysis indicates that the hierarchical fibrous network induces a significant linear variation in the contact area between adjacent conductive fibres upon external pressure and contributes to the excellent linear sensing capacity. The pressure sensor is demonstrated to be applicable in human physiology and motion signal detection, electronic skin, and intelligence control. Notably, it also exhibits amazing sensing stability and thermal insulation under extreme temperature conditions, demonstrating much promise for emerging applications such as the sensing unit for space suits and inflatable structures for future lunar/Mars habitats. This work provides a simple but powerful strategy for developing next-generation linear pressure sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 66, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2829, "End Page": 2842, "Article Number": null, "DOI": "10.1007/s40843-022-2418-1", "DOI Link": "http://dx.doi.org/10.1007/s40843-022-2418-1", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979431500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, ZR; la Monaca, A; Murray, J; Speidel, A; Ushmaev, D; Clare, A; Axinte, D; M'Saoubi, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Zhirong; la Monaca, Andrea; Murray, James; Speidel, Alistair; Ushmaev, Dmitrii; Clare, Adam; Axinte, Dragos; M'Saoubi, Rachid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface integrity in metal machining - Part I: Fundamentals of surface characteristics and formation mechanisms", "Source Title": "INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface integrity of machined metal components is critical to their in-service functionality, longevity and overall performance. Surface defects induced by machining operations vary from the nullo to macro scale, which cause microstructural, mechanical and chemical effects. Hence, they require advanced evaluation and post processing techniques. While surface integrity varies significantly across the range of machining processes, this paper explores the state-of-the-art of surface integrity research with an emphasis on their governing mechanisms and emerging evaluation approaches. In this review, removal mechanisms are grouped by their primary energy transfer mechanisms; mechanical, thermal and chemical based. Accordingly, the resultant multi-scale phenomena associated with metal machining are analyzed. The contribution of these material removal mechanisms to the workpiece surfaces/subsurface characteristics is reviewed. Post-processing options for the mitigation of induced surface defects are also discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 162, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103687, "DOI": "10.1016/j.ijmachtools.2020.103687", "DOI Link": "http://dx.doi.org/10.1016/j.ijmachtools.2020.103687", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618554800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, HL; Tang, DS; Kang, XX; Yuan, HT; Yu, YJ; Xiong, XL; Wu, NE; Chen, FZ; Wang, X; Xiao, HH; Zhou, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Huiling; Tang, Dongsheng; Kang, Xiaoxu; Yuan, Haitao; Yu, Yingjie; Xiong, Xiaolu; Wu, Nier; Chen, Fangzhou; Wang, Xing; Xiao, Haihua; Zhou, Dongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Degradable Pseudo Conjugated Polymer nulloparticles with NIR-II Photothermal Effect and Cationic Quaternary Phosphonium Structural Bacteriostasis for Anti-Infection Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy based on conjugated polymers represents a promising antibacterial strategy but still possesses notable limitations. Herein, degradable pseudo conjugated polymers (PCPs) containing photothermal molecular backbones and reactive oxygen species (ROS)-sensitive thioketal bonds are designed. Triphenylphosphine (PPh3) is introduced into PCPs to generate phosphonium-based PCPs (pPCPs), which further assembled with hyaluronic acid into pPCP nulloparticles (pPCP-NPs). pPCP-NPs with quaternary phosphonium cations selectively anchor on and destroy bacterial cell membranes through electrostatic action. Under 1064 nm laser irradiation, pPCP-NPs (pPCP-NPs/+L) produce near-infrared-II (NIR-II) photothermal antibacterial effect, thereby killing bacteria in a sustained manner. pPCP-NPs are readily degraded upon ROS abundant at infection sites, therefore exhibiting enough biosafety. pPCP-NPs/+L display an almost 100% bacterial inhibition rate in vitro and resultin a nearly complete recovery of bacteria-induced mouse wounds. A further metabolomics analysis denotes that pPCP-NPs/+L work in a concerted way to induce bacterial DNA damage, inhibit bacterial carbon/nitrogen utilization and amino acid/nucleotide synthesis. Taken together, degradable pPCP-NPs with both NIR-II photothermal effect and cationic phosphonium structural bacteriostasis provide a new avenue for antibiotics-alternative anti-infection therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200732, "DOI": "10.1002/advs.202200732", "DOI Link": "http://dx.doi.org/10.1002/advs.202200732", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773442000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsen, AW; Hunt, B; Kim, YD; Yuan, ZJ; Jia, S; Cava, RJ; Hone, J; Kim, P; Dean, CR; Pasupathy, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsen, A. W.; Hunt, B.; Kim, Y. D.; Yuan, Z. J.; Jia, S.; Cava, R. J.; Hone, J.; Kim, P.; Dean, C. R.; Pasupathy, A. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of the quantum metal in a two-dimensional crystalline superconductor", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials are not expected to be metals at low temperature owing to electron localization(1). Consistent with this, pioneering studies on thin films reported only superconducting and insulating ground states, with a direct transition between the two as a function of disorder or magnetic field(2-6). However, more recent works have revealed the presence of an intermediate quantum metallic state occupying a substantial region of the phase diagram(7-10), whose nature is intensely debated(11-17). Here, we observe such a state in the disorder-free limit of a crystalline 2D superconductor, produced by mechanical co-lamination of NbSe2 in an inert atmosphere. Under a small perpendicular magnetic field, we induce a transition from superconductor to the quantum metal. We find a unique power-law scaling with field in this phase, which is consistent with the Bose-metal model where metallic behaviour arises from strong phase fluctuations caused by the magnetic field(11-14).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 12, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 208, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3579", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3579", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371505200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ha, T; Tran, J; Liu, SY; Jang, H; Jeong, H; Mitbander, R; Huh, H; Qiu, YT; Duong, J; Wang, RL; Wang, PL; Tandon, A; Sirohi, J; Lu, NS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ha, Taewoo; Tran, Jason; Liu, Siyi; Jang, Hongwoo; Jeong, Hyoyoung; Mitbander, Ruchika; Huh, Heeyong; Qiu, Yitao; Duong, Jason; Wang, Rebecca L.; Wang, Pulin; Tandon, Animesh; Sirohi, Jayant; Lu, nullshu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Chest-Laminated Ultrathin and Stretchable E-Tattoo for the Measurement of Electrocardiogram, Seismocardiogram, and Cardiac Time Intervals", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seismocardiography (SCG) is a measure of chest vibration associated with heartbeats. While skin soft electronic tattoos (e-tattoos) have been widely reported for electrocardiogram (ECG) sensing, wearable SCG sensors are still based on either rigid accelerometers or non-stretchable piezoelectric membranes. This work reports an ultrathin and stretchable SCG sensing e-tattoo based on the filamentary serpentine mesh of 28-mu m-thick piezoelectric polymer, polyvinylidene fluoride (PVDF). 3D digital image correlation (DIC) is used to map chest vibration to identify the best location to mount the e-tattoo and to investigate the effects of substrate stiffness. As piezoelectric sensors easily suffer from motion artifacts, motion artifacts are effectively reduced by performing subtraction between a pair of identical SCG tattoos placed adjacent to each other. Integrating the soft SCG sensor with a pair of soft gold electrodes on a single e-tattoo platform forms a soft electro-mechano-acoustic cardiovascular (EMAC) sensing tattoo, which can perform synchronous ECG and SCG measurements and extract various cardiac time intervals including systolic time interval (STI). Using the EMAC tattoo, strong correlations between STI and the systolic/diastolic blood pressures, are found, which may provide a simple way to estimate blood pressure continuously and noninvasively using one chest-mounted e-tattoo.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900290, "DOI": "10.1002/advs.201900290", "DOI Link": "http://dx.doi.org/10.1002/advs.201900290", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477711600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, A; Bui, VQ; Lee, J; Wang, LL; Jadhav, AR; Liu, XH; Shao, XD; Liu, Y; Yu, JM; Hwang, Y; Bui, HTD; Ajmal, S; Kim, MG; Kim, SG; Park, GS; Kawazoe, Y; Lee, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Ashwani; Bui, Viet Q.; Lee, Jinsun; Wang, Lingling; Jadhav, Amol R.; Liu, Xinghui; Shao, Xiaodong; Liu, Yang; Yu, Jianmin; Hwang, Yosep; Bui, Huong T. D.; Ajmal, Sara; Kim, Min Gyu; Kim, Seong-Gon; Park, Gyeong-Su; Kawazoe, Yoshiyuki; Lee, Hyoyoung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Moving beyond bimetallic-alloy to single-atom dimer atomic-interface for all-pH hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While single, dispersed atoms enable efficient atomic utilization, controllably preparing single-atom dimers remains challenging. Here, authors prepare nickel-cobalt single-atom dimers as high-performance pH-universal H-2 evolution electrocatalysts. Single-atom-catalysts (SACs) afford a fascinating activity with respect to other nullomaterials for hydrogen evolution reaction (HER), yet the simplicity of single-atom center limits its further modification and utilization. Obtaining bimetallic single-atom-dimer (SAD) structures can reform the electronic structure of SACs with added atomic-level synergistic effect, further improving HER kinetics beyond SACs. However, the synthesis and identification of such SAD structure remains conceptually challenging. Herein, systematic first-principle screening reveals that the synergistic interaction at the NiCo-SAD atomic interface can upshift the d-band center, thereby, facilitate rapid water-dissociation and optimal proton adsorption, accelerating alkaline/acidic HER kinetics. Inspired by theoretical predictions, we develop a facile strategy to obtain NiCo-SAD on N-doped carbon (NiCo-SAD-NC) via in-situ trapping of metal ions followed by pyrolysis with precisely controlled N-moieties. X-ray absorption spectroscopy indicates the emergence of Ni-Co coordination at the atomic-level. The obtained NiCo-SAD-NC exhibits exceptional pH-universal HER-activity, demanding only 54.7 and 61 mV overpotentials at -10 mA cm(-2) in acidic and alkaline media, respectively. This work provides a facile synthetic strategy for SAD catalysts and sheds light on the fundamentals of structure-activity relationships for future applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6766, "DOI": "10.1038/s41467-021-27145-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27145-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720682600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MY; Chen, Q; Xue, RM; Zhan, Y; Wang, C; Lai, JQ; Yang, J; Lin, HZ; Yao, JL; Li, YW; Chen, LW; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Moyao; Chen, Qi; Xue, Rongming; Zhan, Yu; Wang, Cheng; Lai, Junqi; Yang, Jin; Lin, Hongzhen; Yao, Jianlin; Li, Yaowen; Chen, Liwei; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconfiguration of interfacial energy band structure for high-performance inverted structure perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charged defects at the surface of the organic-inorganic perovskite active layer are detrimental to solar cells due to exacerbated charge carrier recombination. Here we show that charged surface defects can be benign after passivation and further exploited for reconfiguration of interfacial energy band structure. Based on the electrostatic interaction between oppositely charged ions, Lewis-acid-featured fullerene skeleton after iodide ionization (PCBB-3N-3I) not only efficiently passivates positively charged surface defects but also assembles on top of the perovskite active layer with preferred orientation. Consequently, PCBB-3N-3I with a strong molecular electric dipole forms a dipole interlayer to reconfigure interfacial energy band structure, leading to enhanced built-in potential and charge collection. As a result, inverted structure planar heterojunction perovskite solar cells exhibit the promising power conversion efficiency of 21.1% and robust ambient stability. This work opens up a new window to boost perovskite solar cells via rational exploitation of charged defects beyond passivation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4593, "DOI": "10.1038/s41467-019-12613-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12613-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489244400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Wang, L; Li, YB; Li, YZ; Lee, HR; Pei, A; He, XM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yongming; Wang, Li; Li, Yanbin; Li, Yuzhang; Lee, Hye Ryoung; Pei, Allen; He, Xiangming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Red Phosphorus nullostructured Electrode for Fast-Charging Lithium-Ion Batteries with High Energy Density", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose that red phosphorus (P) is an ideal anode material for fast-charging lithium-ion batteries (LIBs) because of the combined advantages of high capacity (6,075 mAh cm(-3)) and relatively low yet safe lithiation potential (similar to 0.7 V versus Li/Li+). A red P/C nullocomposite has been fabricated, featuring amorphous red P nullodomains embedded in the nullopores of micrometer-scale porous conductive carbon with interior nulloscale void spaces, a conductive P-free carbon superficial layer, and a high tap density of 1.0 g cm(-3). At an industrial-level areal capacity (3 mAh cm(-2) or higher), a P/C electrode shows considerably better fast-charging capability than commercial graphite and Li4Ti5O12 electrodes, as well as much higher volumetric capacity and specific capacity based on the whole electrode. Meanwhile, our P/C electrode shows excellent long-term cycling stability with Coulombic efficiency of 100.0% (+/- 0.1%) and 90% capacity retention from the 5th to 500th cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1080, "End Page": 1093, "Article Number": null, "DOI": "10.1016/j.joule.2019.01.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.01.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465149000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JW; Bae, SH; Hsieh, YT; De Marco, N; Wang, MK; Sun, PY; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jin-Wook; Bae, Sang-Hoon; Hsieh, Yao-Tsung; De Marco, Nicholas; Wang, Mingkui; Sun, Pengyu; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Bifunctional Lewis Base Additive for Microscopic Homogeneity in Perovskite Solar Cells", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Certified power conversion efficiencies (PCEs) of perovskite solar cells have increased to reach an impressive 22.1%. However, there exists microscopic in-homogeneity that limits high PCE, primarily as a result of defects at grain interiors and boundaries of perovskite films. Here, we report a strategy for reducing heterogeneity by using a bifunctional non-volatile Lewis base additive urea. The addition of 4 mol % urea results in significant enhancement of the macroscopic photoluminescence lifetime from 200.5 to 752.4 ns and elimination of trap-mediated non-radiative recombination, resulting in an improved PCE. The Lewis base urea is found to interact with solution precursors to retard crystal growth and enhance crystallinity, which subsequently precipitates at grain boundaries to passivate defects after completion of crystal growth. The resulting perovskite films show superior homogeneity in conductivity at both grain interior and boundaries in comparison with the bare perovskite films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2017, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 302, "Article Number": null, "DOI": "10.1016/j.chempr.2017.05.020", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.05.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408622600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QB; Xu, WZ; Hu, XM; Zhu, WQ; Yue, T; Zhang, C; Yan, F; Chen, L; Lezec, HJ; Lu, YQ; Agrawal, A; Xu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Qingbin; Xu, Weizhu; Hu, Xuemei; Zhu, Wenqi; Yue, Tao; Zhang, Cheng; Yan, Feng; Chen, Lu; Lezec, Henri J.; Lu, Yanqing; Agrawal, Amit; Xu, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trilobite-inspired neural nullophotonic light-field camera with extreme depth-of-field", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the optical structure of bifocal compound eyes, the authors demonstrate a nullophotonic light-field camera with large depth of field. By using a spin-multiplexed bifocal metalens array and neural network-based reconstruction, they capture high-resolution images at centimeter to kilometer scale. A unique bifocal compound eye visual system found in the now extinct trilobite, Dalmanitina socialis, may enable them to be sensitive to the light-field information and simultaneously perceive both close and distant objects in the environment. Here, inspired by the optical structure of their eyes, we demonstrate a nullophotonic light-field camera incorporating a spin-multiplexed bifocal metalens array capable of capturing high-resolution light-field images over a record depth-of-field ranging from centimeter to kilometer scale, simultaneously enabling macro and telephoto modes in a snapshot imaging. By leveraging a multi-scale convolutional neural network-based reconstruction algorithm, optical aberrations induced by the metalens are eliminated, thereby significantly relaxing the design and performance limitations on metasurface optics. The elegant integration of nullophotonic technology with computational photography achieved here is expected to aid development of future high-performance imaging systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2130, "DOI": "10.1038/s41467-022-29568-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29568-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784997300080", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, W; Ye, JT; Zhang, YJ; Suzuki, R; Yoshida, M; Miyazaki, J; Inoue, N; Saito, Y; Iwasa, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Wu; Ye, Jianting; Zhang, Yijin; Suzuki, Ryuji; Yoshida, Masaro; Miyazaki, Jun; Inoue, Naoko; Saito, Yu; Iwasa, Yoshihiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity Series in Transition Metal Dichalcogenides by Ionic Gating", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functionalities of two-dimensional (2D) crystals based on semiconducting transition metal dichalcogenides (TMDs) have now stemmed from simple field effect transistors (FETs) to a variety of electronic and opto-valleytronic devices, and even to superconductivity. Among them, superconductivity is the least studied property in TMDs due to methodological difficulty accessing it in different TMD species. Here, we report the systematic study of superconductivity in MoSe2, MoTe2 and WS2 by ionic gating in different regimes. Electrostatic gating using ionic liquid was able to induce superconductivity in MoSe2 but not in MoTe2 because of inefficient electron accumulation limited by electronic band alignment. Alternative gating using KClO4/polyethylene glycol enabled a crossover from surface doping to bulk doping, which induced superconductivities in MoTe2 and WS2 electrochemically. These new varieties greatly enriched the TMD superconductor families and unveiled critical methodology to expand the capability of ionic gating to other materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12534, "DOI": "10.1038/srep12534", "DOI Link": "http://dx.doi.org/10.1038/srep12534", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358853700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baldim, V; Bedioui, F; Mignet, N; Margaill, I; Berret, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baldim, V.; Bedioui, F.; Mignet, N.; Margaill, I.; Berret, J. -F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The enzyme-like catalytic activity of cerium oxide nulloparticles and its dependency on Ce3+ surface area concentration", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cerium oxide nulloparticles are known to catalyze the decomposition of reactive oxygen species such as the superoxide radical and hydrogen peroxide. Herein, we examine the superoxide dismutase (SOD) and catalase (CAT) mimetic catalytic activities of nulloceria and demonstrate the existence of generic behaviors. For particles of sizes 4.5, 7.8, 23 and 28 nm, the SOD and CAT catalytic activities exhibit the characteristic shape of a Langmuir isotherm as a function of cerium concentration. The results show that the catalytic effects are enhanced for smaller particles and for the particles with the largest Ce3+ fraction. The SOD-like activity obtained from the different samples is found to superimpose on a single master curve using the Ce3+ surface area concentration as a new variable, indicating the existence of particle independent redox mechanisms. For the CAT assays, the adsorption of H2O2 molecules at the particle surface modulates the efficacy of the decomposition process and must be taken into account. We design an amperometry-based experiment to evaluate the H2O2 adsorption at nulloceria surfaces, leading to the renormalization of the particle specific area. Depending on the particle type the amount of adsorbed H2O2 molecules varies from 2 to 20 nm(-2). The proposed scalings are predictive and allow the determination of the SOD and CAT catalytic properties of cerium oxide solely from physicochemical features.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2018, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6971, "End Page": 6980, "Article Number": null, "DOI": "10.1039/c8nr00325d", "DOI Link": "http://dx.doi.org/10.1039/c8nr00325d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430537200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Wang, HT; Li, YZ; Liu, YY; Sun, J; Lee, SH; Lee, JS; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wei; Wang, Haotian; Li, Yuzhang; Liu, Yayuan; Sun, Jie; Lee, Sanghan; Lee, Jang-Soo; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Situ Electrochemical Oxidation Tuning of Transition Metal Disulfides to Oxides for Enhanced Water Oxidation", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of catalysts with earth-abundant elements for efficient oxygen evolution reactions is of paramount significance for clean and sustainable energy storage and conversion devices. Our group demonstrated recently that the electrochemical tuning of catalysts via lithium insertion and extraction has emerged as a powerful approach to improve catalytic activity. Here we report a novel in situ electrochemical oxidation tuning approach to develop a series of binary, ternary, and quaternary transition metal (e.g., Co, Ni, Fe) oxides from their corresponding sulfides as highly active catalysts for much enhanced water oxidation. The electrochemically tuned cobalt-nickel-iron oxides grown directly on the three-dimensional carbon fiber electrodes exhibit a low overpotential of 232 mV at current density of 10 mA cm(-2), small Tafel slope of 37.6 mV dec(-1), and exceptional long-term stability of electrolysis for over 100 h in 1 M KOH alkaline medium, superior to most non-noble oxygen evolution catalysts reported so far. The materials evolution associated with the electrochemical oxidation tuning is systematically investigated by various characterizations, manifesting that the improved activities are attributed to the significant grain size reduction and increase of surface area and electroactive sites. This work provides a promising strategy to develop electrocatalysts for large-scale water-splitting systems and many other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2015, "Volume": 1, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 244, "End Page": 251, "Article Number": null, "DOI": "10.1021/acscentsci.5b00227", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.5b00227", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365968800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, CJ; Jiang, YZ; Cui, MH; Qiao, L; Wei, JL; Huang, YM; Zhang, L; He, TW; Li, SS; Hsu, HY; Qin, CC; Long, R; Yuan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Changjiu; Jiang, Yuanzhi; Cui, Minghuan; Qiao, Lu; Wei, Junli; Huang, Yanmin; Zhang, Li; He, Tingwei; Li, Saisai; Hsu, Hsien-Yi; Qin, Chaochao; Long, Run; Yuan, Mingjian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance large-area quasi-2D perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Serious performance decline arose for perovskite light-emitting diodes (PeLEDs) once the active area was enlarged. Here we investigate the failure mechanism of the widespread active film fabrication method; and ascribe severe phase-segregation to be the reason. We thereby introduce L-Norvaline to construct a COO--coordinated intermediate phase with low formation enthalpy. The new intermediate phase changes the crystallization pathway, thereby suppressing the phase-segregation. Accordingly, high-quality large-area quasi-2D films with desirable properties are obtained. Based on this, we further rationally adjusted films' recombination kinetics. We reported a series of highly-efficient green quasi-2D PeLEDs with active areas of 9.0 cm(2). The peak EQE of 16.4% is achieved in = 3, represent the most efficient large-area PeLEDs yet. Meanwhile, high brightness device with luminullce up to 9.1 x 10(4)cdm(-2) has achieved in = 10 film. Performance of perovskite LED tends to decline as the active area increases, thus understanding the failure mechanism is paramount to surmount this limitation. Here, the authors report severe phase-segregation to be the cause, and introduce L-Norvaline to overcome it, as the result, highly-efficient 9.0 cm(2) green PeLED is realised.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 13", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2207, "DOI": "10.1038/s41467-021-22529-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22529-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640638000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schuepfer, DB; Badaczewski, F; Guerra-Castro, JM; Hofmann, DM; Heiliger, C; Smarsly, B; Klar, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuepfer, Dominique B.; Badaczewski, Felix; Guerra-Castro, Juan Manuel; Hofmann, Detlev M.; Heiliger, Christian; Smarsly, Bernd; Klar, Peter J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assessing the structural properties of graphitic and non-graphitic carbons by Raman spectroscopy", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study the transformation from molecular to crystalline of (non-)graphitic carbons synthesized from organic precursors by heat-treatment. Easy assessment of structural properties resulting from heat-treatment protocols is mandatory for industrial process monitoring. We demonstrate that Raman spectroscopy, in particular, the Raman lineshape analysis of G and D mode, offers quick assessment of the average sheet size of such carbons. We validate this method by performing Raman, WAXS and EPR measurements of series of resin and pitch-based carbons synthesized. The crystallite sizes of the WAXS analysis for the individual samples are related to corresponding positions and linewidths of G and D Raman modes and show excellent agreement between experiment and modelling from large sizes down to 4 nm. The theoretical master curves are independent of the precursor used in the synthesis, in contrast to models for the intensity ratio of D and G band versus size. We show that the latter are not universally valid and differ for each class of precursors. For sizes below 4 nm, our lineshape model fails as it is based on the bandstructure and phonon dispersions of ideal graphene. Thus, 4 nm corresponds to the fundamental transition from molecular to crystalline character for non-graphitic carbons. (C) 2020 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 161, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 359, "End Page": 372, "Article Number": null, "DOI": "10.1016/j.carbon.2019.12.094", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2019.12.094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000523561700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Windisch-Kern, S; Gerold, E; Nigl, T; Jandric, A; Altendorfer, M; Rutrecht, B; Scherhaufer, S; Raupenstrauch, H; Pomberger, R; Antrekowitsch, H; Part, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Windisch-Kern, Stefan; Gerold, Eva; Nigl, Thomas; Jandric, Aleksander; Altendorfer, Michael; Rutrecht, Bettina; Scherhaufer, Silvia; Raupenstrauch, Harald; Pomberger, Roland; Antrekowitsch, Helmut; Part, Florian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling chains for lithium-ion batteries: A critical examination of current challenges, opportunities and process dependencies", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) show high energy densities and are therefore used in a wide range of applications: from portable electronics to stationary energy storage systems and traction batteries used for e-mobility. Considering the projected increase in global demand for this energy storage technology, driven primarily by growth in e-vehicles, and looking at the criticality of some raw materials used in LIBs, the need for an efficient recycling strategy emerges. In this study, current state-of-the-art technologies for LIB recycling are reviewed and future opportunities and challenges, in particular to recover critical raw materials such as lithium or cobalt, are derived. Special attention is paid to the interrelationships between mechanical or thermal pre-treatment and hydro- or pyrometallurgical post-treatment processes. Thus, the unique approach of the article is to link processes beyond individual stages within the recycling chain. It was shown that influencing the physicochemical properties of intermediate products can lead to reduced recycling rates or even the exclusion of certain process options at the end of the recycling chain. More efforts are needed to improve information and data sharing on the exact composition of feedstock for recycling as well as on the processing history of intermediates to enable closed loop LIB recycling. The technical understanding of the interrelationships between different process combinations, such as pyrolytic or mechanical pre-treatment for LIB deactivation and metal separation, respectively, followed by hydrometallurgical treatment, is of crucial importance to increase recovery rates of cathodic metals such as cobalt, nickel, and lithium, but also of other battery components.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2022, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 125, "End Page": 139, "Article Number": null, "DOI": "10.1016/j.wasman.2021.11.038", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2021.11.038", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788837300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smejkal, L; Sinova, J; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smejkal, Libor; Sinova, Jairo; Jungwirth, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beyond Conventional Ferromagnetism and Antiferromagnetism: A Phase with Nonrelativistic Spin and Crystal Rotation Symmetry", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent series of theoretical and experimental reports have driven attention to time-reversal symmetry -breaking spintronic and spin-splitting phenomena in materials with collinear-compensated magnetic order incompatible with conventional ferromagnetism or antiferromagnetism. Here we employ an approach based on nonrelativistic spin-symmetry groups that resolves the conflicting notions of unconventional ferromagnetism or antiferromagnetism by delimiting a third basic collinear magnetic phase. We derive that all materials hosting this collinear-compensated magnetic phase are characterized by crystal-rotation symmetries connecting opposite-spin sublattices separated in the real space and opposite-spin electronic states separated in the momentum space. We describe prominent extraordinary characteristics of the phase, including the alternating spin-splitting sign and broken time-reversal symmetry in the nonrelativistic band structure, the planar or bulk d-, g-, or i-wave symmetry of the spin-dependent Fermi surfaces, spin -degenerate nodal lines and surfaces, band anisotropy of individual spin channels, and spin-split general, as well as time-reversal invariant momenta. Guided by the spin-symmetry principles, we discover in ab initio calculations outlier materials with an extraordinary nonrelativistic spin splitting, whose eV-scale and momentum dependence are determined by the crystal potential of the nonmagnetic phase. This spin -splitting mechanism is distinct from conventional relativistic spin-orbit coupling and ferromagnetic exchange, as well as from the previously considered anisotropic exchange mechanism in compensated magnets. Our results, combined with our identification of material candidates for the phase ranging from insulators and metals to a parent crystal of cuprate superconductors, underpin research of novel quantum phenomena and spintronic functionalities in high-temperature magnets with light elements, vanishing net magnetization, and strong spin coherence. In the discussion, we argue that the conflicting notions of unconventional ferromagnetism or antiferromagnetism, on the one hand, and our symmetry-based delimitation of the third phase, on the other hand, favor a distinct term referring to the phase. The alternating spin polarizations in both the real-space crystal structure and the momentum-space band structure characteristic of this unconventional magnetic phase suggest a term altermagnetism. We point out that d-wave altermagnetism represents a realization of the long-sought-after counterpart in magnetism of the unconventional d-wave superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 12, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31042, "DOI": "10.1103/PhysRevX.12.031042", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.12.031042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000865310200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Zhu, BC; Cheng, B; Luo, GQ; Xu, JS; Cao, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Han; Zhu, Bicheng; Cheng, Bei; Luo, Guoqiang; Xu, Jingsan; Cao, Shaowen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Cu anchored on N-doped graphene/carbon nitride heterojunction for enhanced photocatalytic H 2 O 2 production", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic production of H 2 O 2 by polymeric carbon nitride has been regarded as a promising approach for the conversion of solar energy into valuable chemicals. However, the efficiency of pristine carbon nitride is limited by the rapid charge recombination and the lack of suitable active sites. Herein, we introduce single-atom Cu anchored on N-doped graphene (Cu-NG) as a cocatalyst coupled with carbon nitride via covalent bonding to enhance photocatalytic H 2 O 2 production. The Cu-NG/carbon nitride could broaden the light absorption from UV to near-infrared region, contributing to the photocatalytic process. Moreover, NG containing electron-rich N atoms could serve as anchoring sites for stabilizing single-atom Cu. Importantly, the single-atom Cu acts not only as an electron sink to steer the interfacial charge separation but also as an active site for molecular oxygen adsorption and activation. With the synergistic effect of the enhanced interfacial charge separation and suitable active sites, Cu-NG/carbon nitride exhibits improved photocatalytic performance with an H 2 O 2 generation rate of 2856 mu mol g -1 h -1 , which is 2.6 times that of pristine carbon nitride. This work provides a protocol for high-performance photocatalytic H 2 O 2 production using a single-atom cocatalyst.(c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2023, "Volume": 161, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 192, "End Page": 200, "Article Number": null, "DOI": "10.1016/j.jmst.2023.03.039", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2023.03.039", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002101400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Orikasa, Y; Masese, T; Koyama, Y; Mori, T; Hattori, M; Yamamoto, K; Okado, T; Huang, ZD; Minato, T; Tassel, C; Kim, J; Kobayashi, Y; Abe, T; Kageyama, H; Uchimoto, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Orikasa, Yuki; Masese, Titus; Koyama, Yukinori; Mori, Takuya; Hattori, Masashi; Yamamoto, Kentaro; Okado, Tetsuya; Huang, Zhen-Dong; Minato, Taketoshi; Tassel, Cedric; Kim, Jungeun; Kobayashi, Yoji; Abe, Takeshi; Kageyama, Hiroshi; Uchimoto, Yoshiharu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable magnesium batteries are poised to be viable candidates for large-scale energy storage devices in smart grid communities and electric vehicles. However, the energy density of previously proposed rechargeable magnesium batteries is low, limited mainly by the cathode materials. Here, we present new design approaches for the cathode in order to realize a high-energy-density rechargeable magnesium battery system. Ion-exchanged MgFeSiO4 demonstrates a high reversible capacity exceeding 300 mAh? g21 at a voltage of approximately 2.4 V vs. Mg. Further, the electronic and crystal structure of ion-exchanged MgFeSiO4 changes during the charging and discharging processes, which demonstrates the (de) insertion of magnesium in the host structure. The combination of ion-exchanged MgFeSiO4 with a magnesium bis(trifluoromethylsulfonyl) imide-triglyme electrolyte system proposed in this work provides a low-cost and practical rechargeable magnesium battery with high energy density, free from corrosion and safety problems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5622, "DOI": "10.1038/srep05622", "DOI Link": "http://dx.doi.org/10.1038/srep05622", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338828100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prasanna, R; Gold-Parker, A; Leijtens, T; Conings, B; Babayigit, A; Boyen, HG; Toney, MF; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prasanna, Rohit; Gold-Parker, Aryeh; Leijtens, Tomas; Conings, Bert; Babayigit, Aslihan; Boyen, Hans-Gerd; Toney, Michael F.; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band Gap Tuning via Lattice Contraction and Octahedral Tilting in Perovskite Materials for Photovoltaics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin and lead iodide perovskite semiconductors of the composition AMX(3), where M is a metal and X is a halide, are leading candidates for high efficiency low cost tandem photovoltaics, in part because they have band gaps that can be tuned over a wide range by compositional substitution. We experimentally identify two competing mechanisms through which the A-site cation influences the band gap of 3D metal halide perovskites. Using a smaller A-site cation can distort the perovskite lattice in two distinct ways: by tilting the MX6 octahedra or by simply contracting the lattice isotropically. The former effect tends to raise the band gap, while the latter tends to decrease it. Lead iodide perovskites show an increase in band gap upon partial substitution of the larger formamidinium with the smaller cesium, due to octahedral tilting. Perovskites based on tin, which is slightly smaller than lead, show the opposite trend: they show no octahedral tilting upon Cs-substitution but only a contraction of the lattice, leading to progressive reduction of the band gap. We outline a strategy to systematically tune the band gap and valence and conduction band positions of metal halide perovskites through control of the cation composition. Using this strategy, we demonstrate solar cells that harvest light in the infrared up to 1040 nm, reaching a stabilized power conversion efficiency of 17.8%, showing promise for improvements of the bottom cell of all-perovskite tandem solar cells. The mechanisms of cation based band gap tuning we describe are broadly applicable to 3D metal halide perovskites and will be useful in further development of perovskite semiconductors for optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 650, "Times Cited, All Databases": 711, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 139, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11117, "End Page": 11124, "Article Number": null, "DOI": "10.1021/jacs.7b04981", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b04981", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408074800036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, FH; Yuwono, JA; Hao, JN; Long, J; Yuan, LB; Wang, YY; Liu, SL; Fan, YM; Zhao, SY; Davey, K; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Fuhua; Yuwono, Jodie A.; Hao, Junnull; Long, Jun; Yuan, Libei; Wang, Yanyan; Liu, Sailin; Fan, Yameng; Zhao, Shiyong; Davey, Kenneth; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding H2 Evolution Electrochemistry to Minimize Solvated Water Impact on Zinc-Anode Performance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "H-2 evolution is the reason for poor reversibility and limited cycle stability with Zn-metal anodes, and impedes practical application in aqueous zinc-ion batteries (AZIBs). Here, using a combined gas chromatography experiment and computation, it is demonstrated that H-2 evolution primarily originates from solvated water, rather than free water without interaction with Zn2+. Using linear sweep voltammetry (LSV) in salt electrolytes, H-2 evolution is evidenced to occur at a more negative potential than zinc reduction because of the high overpotential against H-2 evolution on Zn metal. The hypothesis is tested and, using a glycine additive to reduce solvated water, it is confirmed that H-2 evolution and parasitic side reactions are suppressed on the Zn anode. This electrolyte additive is evidenced to suppress H-2 evolution, reduce corrosion, and give a uniform Zn deposition in Zn|Zn and Zn|Cu cells. It is demonstrated that Zn|PANI (highly conductive polyaniline) full cells exhibit boosted electrochemical performance in 1 M ZnSO4-3 M glycine electrolyte. It is concluded that this new understanding of electrochemistry of H-2 evolution can be used for design of relatively low-cost and safe AZIBs for practical large-scale energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 34, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202206754", "DOI Link": "http://dx.doi.org/10.1002/adma.202206754", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000868832000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shiogai, J; Ito, Y; Mitsuhashi, T; Nojima, T; Tsukazaki, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shiogai, J.; Ito, Y.; Mitsuhashi, T.; Nojima, T.; Tsukazaki, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric-field-induced superconductivity in electrochemically etched ultrathin FeSe films on SrTiO3 and MgO", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among the recently discovered iron-based superconductors(1-3), ultrathin films of FeSe grown on SrTiO3 substrates have uniquely evolved into a high-transition-temperature (T-c) superconducting material(4-15). The mechanisms for the high-T-c superconductivity are under debate, with the superconducting gap mainly characterized with in situ analysis for FeSe films grown by molecular beam epitaxy. Here, we investigate the high-T-c superconductivity in ultrathin FeSe using an alternative top-down electrochemical etching technique in a three-terminal transistor configuration. In addition to the high-temperature superconductivity in FeSe on SrTiO3, the electrochemically etched ultrathin FeSe transistor on MgO also exhibits superconductivity around 40 K, implying that the application of an electric field effectively contributes to the high-T-c superconductivity in ultrathin FeSe regardless of substrate material. Moreover, the observable critical thickness for the high-T-c superconductivity is expanded up to 10 unit cells under an applied electric field and the insulator-superconductor transition is electrostatically controlled. The present demonstration implies that the modification of charge imbalance of holes and electrons by the electric-field effect plays a crucial role in inducing high-T-c superconductivity in FeSe-based electric double-layer transistors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 42, "End Page": "U71", "Article Number": null, "DOI": "10.1038/NPHYS3530", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3530", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367835400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YJ; Liu, EF; Liu, HM; Pan, YM; Zhang, LQ; Zeng, JW; Fu, YJ; Wang, M; Xu, K; Huang, Z; Wang, ZL; Lu, HZ; Xing, DY; Wang, BG; Wan, XG; Miao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yaojia; Liu, Erfu; Liu, Huimei; Pan, Yiming; Zhang, Longqiang; Zeng, Junwen; Fu, Yajun; Wang, Miao; Xu, Kang; Huang, Zhong; Wang, Zhenlin; Lu, Hai-Zhou; Xing, Dingyu; Wang, Baigeng; Wan, Xiangang; Miao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable negative longitudinal magnetoresistance in the predicted type-II Weyl semimetal WTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The progress in exploiting new electronic materials has been a major driving force in solid-state physics. As a new state of matter, a Weyl semimetal (WSM), in particular a type-II WSM, hosts Weyl fermions as emergent quasiparticles and may harbour novel electrical transport properties. Nevertheless, such a type-II WSM material has not been experimentally observed. In this work, by performing systematic magneto-transport studies on thin films of a predicted material candidate WTe2, we observe notable negative longitudinal magnetoresistance, which can be attributed to the chiral anomaly in WSM. This phenomenon also exhibits strong planar orientation dependence with the absence along the tungsten chains, consistent with the distinctive feature of a type-II WSM. By applying a gate voltage, we demonstrate that the Fermi energy can be in-situ tuned through the Weyl points via the electric field effect. Our results may open opportunities for implementing new electronic applications, such as field-effect chiral devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13142, "DOI": "10.1038/ncomms13142", "DOI Link": "http://dx.doi.org/10.1038/ncomms13142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385545600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyu, Y; Yuwono, JA; Wang, PT; Wang, YY; Yang, FH; Liu, SL; Zhang, SL; Wang, BF; Davey, K; Mao, JF; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyu, Yanqiu; Yuwono, Jodie A.; Wang, Pengtang; Wang, Yanyan; Yang, Fuhua; Liu, Sailin; Zhang, Shilin; Wang, Baofeng; Davey, Kenneth; Mao, Jianfeng; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic pH Buffer for Dendrite-Free and Shuttle-Free Zn-I2 Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-Iodine (I-2) batteries are attractive for large-scale energy storage. However, drawbacks include, Zn dendrites, hydrogen evolution reaction (HER), corrosion and, cathode shuttle of polyiodines. Here we report a class of N-containing heterocyclic compounds as organic pH buffers to obviate these. We evidence that addition of pyridine /imidazole regulates electrolyte pH, and inhibits HER and anode corrosion. In addition, pyridine and imidazole preferentially absorb on Zn metal, regulating non-dendritic Zn plating /stripping, and achieving a high Coulombic efficiency of 99.6 % and long-term cycling stability of 3200 h at 2 mA cm(-2), 2 mAh cm(-2). It is also confirmed that pyridine inhibits polyiodines shuttling and boosts conversion kinetics for I-/I-2. As a result, the Zn-I-2 full battery exhibits long cycle stability of >25 000 cycles and high specific capacity of 105.5 mAh g(-1) at 10 A g(-1). We conclude organic pH buffer engineering is practical for dendrite-free and shuttle-free Zn-I-2 batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2023, "Volume": 62, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202303011", "DOI Link": "http://dx.doi.org/10.1002/anie.202303011", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973532300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Y; Xue, YR; He, F; Li, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yang; Xue, Yurui; He, Feng; Li, Yuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlled growth of a high selectivity interface for seawater electrolysis", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Overall seawater electrolysis is an important direction for the development of hydrogen energy conversion. The key issues include how to achieve high selectivity, activity, and stability in seawater electrolysis reactions. In this report, the heterostructures of graphdiyne-RhOx-graphdiyne (GDY/RhOx/GDY) were constructed by in situ-controlled growth of GDY on RhOx nullocrystals. A double layer interface of sp-hybridized carbon-oxide-Rhodium (sp-C similar to O-Rh) was formed in this system. The microstructures at the interface are composed of active sites of sp-C similar to O-Rh. The obvious electron-withdrawing surface enhances the catalytic activity with orders of magnitude, while the GDY outer of the metal oxides guarantees the stability. The electron-donating and withdrawing sp-C similar to O-Rh structures enhance the catalytic activity, achieving high-performance overall seawater electrolysis with very small cell voltages of 1.42 and 1.52 V at large current densities of 10 and 500 mA cm(-2) at room temperatures and ambient pressures, respectively. The compositional and structural superiority of the GDY-derived sp-C-metal-oxide active center offers great opportunities to engineer tunable redox properties and catalytic performance for seawater electrolysis and beyond. This is a typical successful example of the rational design of catalytic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2022, "Volume": 119, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2206946119", "DOI": "10.1073/pnas.2206946119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2206946119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000899768900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, FH; Zhang, SS; Cheng, QQ; Long, YD; Liu, D; Paul, R; Fang, YM; Su, YQ; Qu, LT; Dai, LM; Hu, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Fenghui; Zhang, Shishi; Cheng, Qingqing; Long, Yongde; Liu, Dong; Paul, Rajib; Fang, Yunming; Su, Yaqiong; Qu, Liangti; Dai, Liming; Hu, Chuangang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of oxygen-vacancy in bifunctional indium oxyhydroxide catalysts for electrochemical coupling of biomass valorization with CO2 conversion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical coupling of biomass valorization with CO2 conversion provides a promising approach to generate value-added chemicals on both sides. However, bifunctional catalysts are lacking. Here the authors report oxygen-vacancy-rich indium oxyhydroxide as a bifunctional catalyst for CO2 reduction to formate and 5-hydroxymethylfurfural electrooxidation to 2,5-furandicarboxylic acid with faradaic efficiencies for both > 90.0%. Electrochemical coupling of biomass valorization with carbon dioxide (CO2) conversion provides a promising approach to generate value-added chemicals on both sides of the electrolyzer. Herein, oxygen-vacancy-rich indium oxyhydroxide (InOOH-O-V) is developed as a bifunctional catalyst for CO2 reduction to formate and 5-hydroxymethylfurfural electrooxidation to 2,5-furandicarboxylic acid with faradaic efficiencies for both over 90.0% at optimized potentials. Atomic-scale electron microscopy images and density functional theory calculations reveal that the introduction of oxygen vacancy sites causes lattice distortion and charge redistribution. Operando Raman spectra indicate oxygen vacancies could protect the InOOH-O-V from being further reduced during CO2 conversion and increase the adsorption competitiveness for 5-hydroxymethylfurfural over hydroxide ions in alkaline electrolytes, making InOOH-O-V a main-group p-block metal oxide electrocatalyst with bifunctional activities. Based on the catalytic performance of InOOH-O-V, a pH-asymmetric integrated cell is fabricated by combining the CO2 reduction and 5-hydroxymethylfurfural oxidation together in a single electrochemical cell to produce 2,5-furandicarboxylic acid and formate with high yields (both around 90.0%), providing a promising approach to generate valuable commodity chemicals simultaneously on both electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2040, "DOI": "10.1038/s41467-023-37679-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37679-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001166947800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, X; Zhao, JX; Wei, Q; Ma, YJ; Guo, HR; Liu, Q; Wang, Y; Cui, GW; Asiri, AM; Li, BH; Tang, B; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xiang; Zhao, Jinxiu; Wei, Qin; Ma, Yongjun; Guo, Haoran; Liu, Qian; Wang, Yuan; Cui, Guanwei; Asiri, Abdullah M.; Li, Baihai; Tang, Bo; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Performance N2-to-NH3 Conversion Electrocatalyzed by Mo2C nullorod", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of NH3 is mainly dominated by the traditional energy-consuming Haber-Bosch process with a mass of CO2 emission. Electrochemical conversion of N-2 to NH3 emerges as a carbon-free process for the sustainable artificial N-2 reduction reaction (NRR), but requires an efficient and stable electrocatalyst. Here, we report that the Mo2C nullorod serves as an excellent NRR electrocatalyst for artificial N-2 fixation to NH3 with strong durability and acceptable selectivity under ambient conditions. Such a catalyst shows a high Faradaic efficiency of 8.13% and NH3 yield of 95.1 mu g h(-1) mg(cat)(-1) at -0.3 V in 0.1 M HCl, surpassing the majority of reported electrochemical conversion NRR catalysts. Density functional theory calculation was carried out to gain further insight into the catalytic mechanism involved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 116, "End Page": 121, "Article Number": null, "DOI": "10.1021/acscentsci.8b00734", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.8b00734", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456525100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jain, A; McGaughey, AJH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jain, Ankit; McGaughey, Alan J. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly anisotropic in-plane thermal transport in single-layer black phosphorene", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using first principles calculations, we predict the thermal conductivity of the two-dimensional materials black phosphorene and blue phosphorene. Black phosphorene has an unprecedented thermal conductivity anisotropy ratio of three, with predicted values of 110 W/m-K and 36 W/m-K along its armchair and zigzag directions at a temperature of 300 K. For blue phosphorene, which is isotropic with a zigzag structure, the predicted value is 78 W/m-K. The two allotropes show strikingly different thermal conductivity accumulation, with phonons of mean free paths between 10 nm and 1 mu m dominating in black phosphorene, while a much narrower band of mean free paths (50-200 nm) dominate in blue phosphorene. Black phosphorene shows intriguing potential for strain-tuning of its thermal conductivity tensor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 483, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8501, "DOI": "10.1038/srep08501", "DOI Link": "http://dx.doi.org/10.1038/srep08501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349454800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XY; Fan, HQ; Hu, FL; Chen, SM; Yan, K; Ma, LT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xueya; Fan, Huiqing; Hu, Fulong; Chen, Shengmei; Yan, Kang; Ma, Longtao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous Zinc Batteries with Ultra-Fast Redox Kinetics and High Iodine Utilization Enabled by Iron Single Atom Catalysts", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc iodine (Zn parallel to I-2) batteries have been promising energy storage technologies due to low-cost position and constitutional safety of zinc anode, iodine cathode and aqueous electrolytes. Whereas, on one hand, the low-fraction utilization of electrochemically inert host causes severe shuttle of soluble polyiodides, deficient iodine utilization and sluggish reaction kinetics. On the other hand, the usage of high mass polar electrocatalysts occupies mass and volume of electrode materials and sacrifices device-level energy density. Here, we propose a confinement-catalysis host composed of Fe single atom catalyst embedding inside ordered mesoporous carbon host, which can effectively confine and catalytically convert I-2/I- couple and polyiodide intermediates. Consequently, the cathode enables the high capacity of 188.2 mAh g(-1) at 0.3 A g(-1), excellent rate capability with a capacity of 139.6 mAh g(-1) delivered at high current density of 15 A g(-1) and ultra-long cyclic stability over 50,000 cycles with 80.5% initial capacity retained under high iodine loading of 76.72 wt%. Furthermore, the electrocatalytic host can also accelerate the I+ <-> I-2 conversion. The greatly improved electrochemical performance originates from the modulation of physicochemical confinement and the decrease of energy barrier for reversible I-/I-2 and I-2/I+ couples, and polyiodide intermediates conversions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126, "DOI": "10.1007/s40820-023-01093-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01093-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000993094000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, LL; Guo, PJ; Kepenekian, M; Hadar, I; Katan, C; Even, J; Schaller, RD; Stoumpos, CC; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Lingling; Guo, Peijun; Kepenekian, Mikael; Hadar, Ido; Katan, Claudine; Even, Jacky; Schaller, Richard D.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic halide perovskites are under intense investigations because of their astounding physical properties and promises for optoelectronics. Lead bromide and chloride perovskites exhibit intrinsic white-light emission believed to arise from self-trapped excitons (STEs). Here, we report a series of new structurally diverse hybrid lead bromide perovskites that have broad-band emission at room temperature. They feature Pb/Br structures which vary from 1D face sharing structures to 3D corner- and edge-sharing structures. Through single-crystal X-ray diffraction and low-frequency Raman spectroscopy, we have identified the local distortion level of the octahedral environments of Pb2+ within the structures. The band gaps of these compounds range from 2.92 to 3.50 eV, following the trend of corner-sharing < edge-sharing < face-sharing. Density functional theory calculations suggest that the electronic structure is highly dependent on the connectivity mode of the PbBr6 octahedra, where the edge- and corner-sharing 1D structure of (2,6-dmpz)(3)Pb2Br10 exhibits more disperse bands and smaller band gap (2.49 eV) than the face-sharing 1D structure of (hep)PbBr3 (3.10 eV). Using photoemission spectroscopy, we measured the energies of the valence band of these compounds and found them to remain almost constant, while the energy of conduction bands varies. Temperature-dependent PL measurements reveal that the 2D and 3D compounds have narrower PL emission at low temperature (similar to 5 K), whereas the 1D compounds have both free exciton emission and STE emission. The 1D compound (2,6-dmpz)(3)Pb2Br10 has the highest photoluminescence quantum yield of 12%, owing to its unique structure that allows efficient charge carrier relaxation and light emission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2018, "Volume": 140, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13078, "End Page": 13088, "Article Number": null, "DOI": "10.1021/jacs.8b08691", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b08691", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447354800060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schindler, F; Wang, ZJ; Vergniory, MG; Cook, AM; Murani, A; Sengupta, S; Kasumov, AY; Deblock, R; Jeon, S; Drozdov, I; Bouchiat, H; Guéron, S; Yazdani, A; Bernevig, BA; Neupert, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schindler, Frank; Wang, Zhijun; Vergniory, Maia G.; Cook, Ashley M.; Murani, Anil; Sengupta, Shamashis; Kasumov, Alik Yu.; Deblock, Richard; Jeon, Sangjun; Drozdov, Ilya; Bouchiat, Helene; Gueron, Sophie; Yazdani, Ali; Bernevig, B. Andrei; Neupert, Titus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-order topology in bismuth", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mathematical field of topology has become a framework in which to describe the low-energy electronic structure of crystalline solids. Typical of a bulk insulating three-dimensional topological crystal are conducting two-dimensional surface states. This constitutes the topological bulk-boundary correspondence. Here, we establish that the electronic structure of bismuth, an element consistently described as bulk topologically trivial, is in fact topological and follows a generalized bulk-boundary correspondence of higher-order: not the surfaces of the crystal, but its hinges host topologically protected conducting modes. These hinge modes are protected against localization by time-reversal symmetry locally, and globally by the three-fold rotational symmetry and inversion symmetry of the bismuth crystal. We support our claim theoretically and experimentally. Our theoretical analysis is based on symmetry arguments, topological indices, first-principles calculations, and the recently introduced framework of topological quantum chemistry. We provide supporting evidence from two complementary experimental techniques. With scanning-tunnelling spectroscopy, we probe the signatures of the rotational symmetry of the one-dimensional states located at the step edges of the crystal surface. With Josephson interferometry, we demonstrate their universal topological contribution to the electronic transport. Our work establishes bismuth as a higher-order topological insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 664, "Times Cited, All Databases": 698, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 14, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 918, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-018-0224-7", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0224-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443584000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Janisch, C; Wang, YX; Ma, D; Mehta, N; Elias, AL; Perea-Lopez, N; Terrones, M; Crespi, V; Liu, ZW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Janisch, Corey; Wang, Yuanxi; Ma, Ding; Mehta, Nikhil; Elias, Ana Laura; Perea-Lopez, Nestor; Terrones, Mauricio; Crespi, Vincent; Liu, Zhiwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinary Second Harmonic Generation in Tungsten Disulfide Monolayers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate Second Harmonic Generation (SHG) in monolayer WS2 both deposited on a SiO2/Si substrate or suspended using transmission electron microscopy grids. We find unusually large second order nonlinear susceptibility, with an estimated value of d(eff) similar to 4.5 nm/V nearly three orders of magnitude larger than other common nonlinear crystals. In order to quantitatively characterize the nonlinear susceptibility of two-dimensional (2D) materials, we have developed a formalism to model SHG based on the Green's function with a 2D nonlinear sheet source. In addition, polarized SHG is demonstrated as a useful method to probe the structural symmetry and crystal orientation of 2D materials. To understand the large second order nonlinear susceptibility of monolayer WS2, density functional theory based calculation is performed. Our analysis suggests the origin of the large nonlinear susceptibility in resonullce enhancement and a large joint density of states, and yields an estimate of the nonlinear susceptibility value d(eff) = 0.77 nm/V for monolayer WS2, which shows good order-of-magnitude agreement with the experimental result.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5530, "DOI": "10.1038/srep05530", "DOI Link": "http://dx.doi.org/10.1038/srep05530", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338421000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SH; Chen, R; Zhang, SS; Babu, BH; Yue, YF; Zhu, HM; Yang, ZC; Chen, CL; Chen, WT; Huang, YQ; Fang, SY; Liu, TL; Han, LY; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shaohang; Chen, Rui; Zhang, Shasha; Babu, B. Hari; Yue, Youfeng; Zhu, Hongmei; Yang, Zhichun; Chen, Chuanliang; Chen, Weitao; Huang, Yuqian; Fang, Shaoying; Liu, Tianlun; Han, Liyuan; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A chemically inert bismuth interlayer enhances long-term stability of inverted perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term stability remains a key issue impeding the commercialization of halide perovskite solar cells (HPVKSCs). The diffusion of molecules and ions causes irreversible degradation to photovoltaic device performance. Here, we demonstrate a facile strategy for producing highly stable HPVKSCs by using a thin but compact semimetal Bismuth interlayer. The Bismuth film acts as a robust permeation barrier that both insulates the perovskite from intrusion by undesirable external moisture and protects the metal electrode from iodine corrosion. The Bismuth-interlayer-based devices exhibit greatly improved stability when subjected to humidity, thermal and light stresses. The unencapsulated device retains 88% of its initial efficiency in ambient air in the dark for over 6000 h; the devices maintain 95% and 97% of their initial efficiencies after 85 degrees C thermal aging and light soaking in nitrogen atmosphere for 500 h, respectively. These sound stability parameters are among the best for planar structured HPVKSCs reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1161, "DOI": "10.1038/s41467-019-09167-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09167-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460759800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Hazarika, A; Chen, XH; Harvey, SP; Larson, BW; Teeter, GR; Liu, J; Song, T; Xiao, CX; Shaw, L; Zhang, MH; Li, GR; Beard, MC; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qian; Hazarika, Abhijit; Chen, Xihan; Harvey, Steve P.; Larson, Bryon W.; Teeter, Glenn R.; Liu, Jun; Song, Tao; Xiao, Chuanxiao; Shaw, Liam; Zhang, Minghui; Li, Guoran; Beard, Matthew C.; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High efficiency perovskite quantum dot solar cells with charge separating heterostructure", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskite semiconductors possess outstanding characteristics for optoelectronic applications including but not limited to photovoltaics. Low-dimensional and nullostructured motifs impart added functionality which can be exploited further. Moreover, wider cation composition tunability and tunable surface ligand properties of colloidal quantum dot (QD) perovskites now enable unprecedented device architectures which differ from thin-film perovskites fabricated from solvated molecular precursors. Here, using layer-by-layer deposition of perovskite QDs, we demonstrate solar cells with abrupt compositional changes throughout the perovskite film. We utilize this ability to abruptly control composition to create an internal heterojunction that facilitates charge separation at the internal interface leading to improved photocarrier harvesting. We show how the photovoltaic performance depends upon the heterojunction position, as well as the composition of each component, and we describe an architecture that greatly improves the performance of perovskite QD photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2842, "DOI": "10.1038/s41467-019-10856-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10856-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473132200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teng, XK; Chen, LB; Ye, F; Rosenberg, E; Liu, ZY; Yin, JX; Jiang, YX; Oh, JS; Hasan, MZ; Neubauer, KJ; Gao, B; Xie, YF; Hashimoto, M; Lu, DH; Jozwiak, C; Bostwick, A; Rotenberg, E; Birgeneau, RJ; Chu, JH; Yi, M; Dai, PC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teng, Xiaokun; Chen, Lebing; Ye, Feng; Rosenberg, Elliott; Liu, Zhaoyu; Yin, Jia-Xin; Jiang, Yu-Xiao; Oh, Ji Seop; Hasan, M. Zahid; Neubauer, Kelly J.; Gao, Bin; Xie, Yaofeng; Hashimoto, Makoto; Lu, Donghui; Jozwiak, Chris; Bostwick, Aaron; Rotenberg, Eli; Birgeneau, Robert J.; Chu, Jiun-Haw; Yi, Ming; Dai, Pengcheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of charge density wave in a kagome lattice antiferromagnet", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A hallmark of strongly correlated quantum materials is the rich phase diagram resulting from competing and intertwined phases with nearly degenerate ground-state energies(1,2). A well-known example is the copper oxides, in which a charge density wave (CDW) is ordered well above and strongly coupled to the magnetic order to form spin-charge-separated stripes that compete with superconductivity(1,2). Recently, such rich phase diagrams have also been shown in correlated topological materials. In 2D kagome lattice metals consisting of corner-sharing triangles, the geometry of the lattice can produce flat bands with localized electrons(3,4), non-trivial topology(5-7), chiral magnetic order(8,9), superconductivity and CDW order(10-15). Although CDW has been found in weakly electron-correlated non-magnetic AV(3)Sb(5) (A = K, Rb, Cs)(10-15), it has not yet been observed in correlated magnetic-ordered kagome lattice metals(4,16-21). Here we report the discovery of CDW in the antiferromagnetic (AFM) ordered phase of kagome lattice FeGe (refs. (16-19)). The CDW in FeGe occurs at wavevectors identical to that of AV(3)Sb(5) (refs. (10-15)), enhances the AFM ordered moment and induces an emergent anomalous Hall effect(22,23). Our findings suggest that CDW in FeGe arises from the combination of electron-correlations-driven AFM order and van Hove singularities (vHSs)-driven instability possibly associated with a chiral flux phase(24-28), in stark contrast to strongly correlated copper oxides(1,2) and nickelates(29-31), in which the CDW precedes or accompanies the magnetic order.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2022, "Volume": 609, "Issue": 7927, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 490, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05034-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05034-z", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854742300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hanifi, DA; Bronstein, ND; Koscher, BA; Nett, Z; Swabeck, JK; Takano, K; Schwartzberg, AM; Maserati, L; Vandewal, K; van de Burgt, Y; Salleo, A; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hanifi, David A.; Bronstein, Noah D.; Koscher, Brent A.; Nett, Zach; Swabeck, Joseph K.; Takano, Kaori; Schwartzberg, Adam M.; Maserati, Lorenzo; Vandewal, Koen; van de Burgt, Yoeri; Salleo, Alberto; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redefining near-unity luminescence in quantum dots with photothermal threshold quantum yield", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of optical applications rely on the absorption and reemission of light. The quantum yield of this process often plays an essential role. When the quantum yield deviates from unity by significantly less than 1%, applications such as luminescent concentrators and optical refrigerators become possible. To evaluate such high performance, we develop a measurement technique for luminescence efficiency with sufficient accuracy below one part per thousand. Photothermal threshold quantum yield is based on the quantization of light to minimize overall measurement uncertainty. This technique is used to guide a procedure capable of making ensembles of near-unity emitting cadmium selenide/cadmium sulfide (CdSe/CdS) core-shell quantum dots. We obtain a photothermal threshold quantum yield luminescence efficiency of 99.6 +/- 0.2%, indicating nearly complete suppression of nonradiative decay channels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2019, "Volume": 363, "Issue": 6432, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1199, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aat3803", "DOI Link": "http://dx.doi.org/10.1126/science.aat3803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461329000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nerella, VN; Hempel, S; Mechtcherine, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nerella, Venkatesh Naidu; Hempel, Simone; Mechtcherine, Viktor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of layer-interface properties on mechanical performance of concrete elements produced by extrusion-based 3D-printing", "Source Title": "CONSTRUCTION AND BUILDING MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfaces between layers in 3D-printed elements produced by extrusion-based material deposition were investigated on both macro- and micro-scales. On the macro-scale, compression and flexural tests were performed on two 3D-printable cement-based compositions (3PCs), namely Mixtures C1 (with Portland cement as sole binder) and C2 (containing pozzolanic additives) at testing ages of 1 day and 28 days. The influences of binder composition and time interval between layers on layer-interface strength were critically analyzed. The investigated time intervals were 2 min, 10 min and I day. The investigations revealed that Mixture C2 exhibited lower degrees of anisotropy and heterogeneity as well as superior mechanical performance in comparison to Mixture 1. In particular, Mixture C2 showed a less pronounced (below 25%) decrease in interface bond strength as observed in flexural tests for all time intervals under investigation. In contrast, the decrease in flexural strength measured for Cl specimens amounted to over 90% due to the higher porosity at the interfaces of the printed concrete layers. Microscopic observations supported the findings of the macroscopic investigations. SEM images also delivered additional information on morphology of interfacial defects as well as self-healing. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2019, "Volume": 205, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 586, "End Page": 601, "Article Number": null, "DOI": "10.1016/j.conbuildmat.2019.01.235", "DOI Link": "http://dx.doi.org/10.1016/j.conbuildmat.2019.01.235", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464483600049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Swearer, DF; Zhao, HQ; Zhou, LN; Zhang, C; Robatjazi, H; Martirez, JMP; Krauter, CM; Yazdi, S; McClain, MJ; Ringe, E; Carter, EA; Nordlander, P; Halas, NJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Swearer, Dayne F.; Zhao, Hangqi; Zhou, Linull; Zhang, Chao; Robatjazi, Hossein; Martirez, John Mark P.; Krauter, Caroline M.; Yazdi, Sadegh; McClain, Michael J.; Ringe, Emilie; Carter, Emily A.; Nordlander, Peter; Halas, Naomi J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterometallic antenna-reactor complexes for photocatalysis", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic nulloparticles with strong optically resonullt properties behave as nulloscale optical antennas, and have recently shown extraordinary promise as light-driven catalysts. Traditionally, however, heterogeneous catalysis has relied upon weakly light-absorbing metals such as Pd, Pt, Ru, or Rh to lower the activation energy for chemical reactions. Here we show that coupling a plasmonic nullo-antenna directly to catalytic nulloparticles enables the light-induced generation of hot carriers within the catalyst nulloparticles, transforming the entire complex into an efficient light-controlled reactive catalyst. In Pd-decorated Al nullocrystals, photocatalytic hydrogen desorption closely follows the antenna-induced local absorption cross-section of the Pd islands, and a supralinear power dependence strongly suggests that hot-carrier-induced desorption occurs at the Pd island surface. When acetylene is present along with hydrogen, the selectivity for photocatalytic ethylene production relative to ethane is strongly enhanced, approaching 40:1. These observations indicate that antenna-reactor complexes may greatly expand possibilities for developing designer photocatalytic substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2016, "Volume": 113, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8916, "End Page": 8920, "Article Number": null, "DOI": "10.1073/pnas.1609769113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1609769113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381293300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Shyamsunder, A; Hoane, AG; Long, DM; Kwok, CY; Kotula, PG; Zavadil, KR; Gewirth, AA; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chang; Shyamsunder, Abhinulldan; Hoane, Alexis Grace; Long, Daniel M.; Kwok, Chun Yuen; Kotula, Paul G.; Zavadil, Kevin R.; Gewirth, Andrew A.; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly reversible Zn anode with a practical areal capacity enabled by a sustainable electrolyte and superacid interfacial chemistry", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-metal batteries are plagued by poor Zn reversibility owing to zinc dendrite and layered double hydroxide (LDH) formation. Here, we introduce a novel additive-N,N-dimethylformamidium trifluoromethanesulfonate (DOTf)-in a low-cost aqueous electrolyte that can very effectively address these issues. The initial water-assisted dissociation of DOTf into triflic superacid creates a robust nullostructured solid-electrolyte interface (SEI)-revealed by operando spectroscopy and cryomicroscopy-which excludes water and enables dense Zn deposition. We demonstrate excellent Zn plating/stripping in a Zn||Cu asymmetric cell for more than 3,500 cycles. Furthermore, near 100% CE is realized at a combined high current density of 4 mA cm(-2) and an areal capacity of 4 mAh cm(-2) over long-term cycling. Zn||Zn0.25V2O5 center dot nH(2)O full cells retain similar to 83% of their capacity after 1,000 cycles with mass-limited Zn anodes. By restricting the depth of discharge, the cathodes exhibit less proton intercalation and LDH formation with an extended lifetime of 2,000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2022, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1103, "End Page": 1120, "Article Number": null, "DOI": "10.1016/j.joule.2022.04.017", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.04.017", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000832847800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YW; Cheng, Y; Peng, SP; Xu, L; He, CX; Qi, FW; Zhao, MC; Shuai, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Youwen; Cheng, Yun; Peng, Shuping; Xu, Liang; He, Chongxian; Qi, Fangwei; Zhao, Mingchun; Shuai, Cijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure evolution and texture tailoring of reduced graphene oxide reinforced Zn scaffold", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc (Zn) possesses desirable degradability and favorable biocompatibility, thus being recognized as a promising bone implant material. Nevertheless, the insufficient mechanical performance limits its further clinical application. In this study, reduced graphene oxide (RGO) was used as reinforcement in Zn scaffold fabricated via laser additive manufacturing. Results showed that the homogeneously dispersed RGO simultaneously enhanced the strength and ductility of Zn scaffold. On one hand, the enhanced strength was ascribed to (i) the grain refinement caused by the pinning effect of RGO, (ii) the efficient load shift due to the huge specific surface area of RGO and the favorable interface bonding between RGO and Zn matrix, and (iii) the Orowan strengthening by the homogeneously distributed RGO. On the other hand, the improved ductility was owing to the RGO-induced random orientation of grain with texture index reducing from 20.5 to 7.3, which activated more slip systems and provided more space to accommodate dislocation. Furthermore, the cell test confirmed that RGO promoted cell growth and differentiation. This study demonstrated the great potential of RGO in tailoring the mechanical performance and cell behavior of Zn scaffold for bone repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1230, "End Page": 1241, "Article Number": null, "DOI": "10.1016/j.bioactmat.2020.10.017", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2020.10.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623072800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feig, VR; Tran, H; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feig, Vivian R.; Tran, Helen; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable Polymeric Materials in Degradable Electronic Devices", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biodegradable electronics have great potential to reduce the environmental footprint of devices and enable advanced health monitoring and therapeutic technologies. Complex biodegradable electronics require biodegradable substrates, insulators, conductors, and semiconductors, all of which comprise the fundamental building blocks of devices. This review will survey recent trends in the strategies used to fabricate biodegradable forms of each of these components. Polymers that can disintegrate without full chemical breakdown (type I), as well as those that can be recycled into monomeric and oligomeric building blocks (type II), will be discussed. Type I degradation is typically achieved with engineering and material science based strategies, whereas type II degradation often requires deliberate synthetic approaches. Notably, unconventional degradable linkages capable of maintaining long-range conjugation have been relatively unexplored, yet may enable fully biodegradable conductors and semiconductors with uncompromised electrical properties. While substantial progress has been made in developing degradable device components, the electrical and mechanical properties of these materials must be improved before fully degradable complex electronics can be realized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": 348, "Article Number": null, "DOI": "10.1021/acscentsci.7b00595", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00595", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428801200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gunst, T; Markussen, T; Stokbro, K; Brandbyge, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gunst, Tue; Markussen, Troels; Stokbro, Kurt; Brandbyge, Mads", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles method for electron-phonon coupling and electron mobility: Applications to two-dimensional materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present density functional theory calculations of the phonon-limited mobility in n-type monolayer graphene, silicene, and MoS2. The material properties, including the electron-phonon interaction, are calculated from first principles. We provide a detailed description of the normalized full-band relaxation time approximation for the linearized Boltzmann transport equation (BTE) that includes inelastic scattering processes. The bulk electron-phonon coupling is evaluated by a supercell method. The method employed is fully numerical and does therefore not require a semianalytic treatment of part of the problem and, importantly, it keeps the anisotropy information stored in the coupling as well as the band structure. In addition, we perform calculations of the low-field mobility and its dependence on carrier density and temperature to obtain a better understanding of transport in graphene, silicene, and monolayer MoS2. Unlike graphene, the carriers in silicene show strong interaction with the out-of-plane modes. We find that graphene has more than an order of magnitude higher mobility compared to silicene in the limit where the silicene out-of-plane interaction is reduced to zero (by substrate interaction, clamping, or similar). If the out-of-plane interaction is not actively reduced, the mobility of silicene will essentially be zero. For MoS2, we obtain several orders of magnitude lower mobilities compared to graphene in agreement with other recent theoretical results. The simulations illustrate the predictive capabilities of the newly implemented BTE solver applied in simulation tools based on first-principles and localized basis sets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 93, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35414, "DOI": "10.1103/PhysRevB.93.035414", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.035414", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367779800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Sun, LJ; Huang, HF; Zhu, WF; Wang, YH; Wu, ZK; Neisiany, RE; Gu, SJ; You, ZW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Lei; Sun, Lijie; Huang, Hongfei; Zhu, Wenfan; Wang, Yihan; Wu, Zekai; Neisiany, Rasoul Esmaeely; Gu, Shijia; You, Zhengwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically Robust and Room Temperature Self-Healing Ionogel Based on Ionic Liquid Inhibited Reversible Reaction of Disulfide Bonds", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although highly desired, it is difficult to develop mechanically robust and room temperature self-healing ionic liquid-based gels (ionogels), which are very promising for next-generation stretchable electronic devices. Herein, it is discovered that the ionic liquid significantly reduces the reversible reaction rate of disulfide bonds without altering its thermodynamic equilibrium constant via small molecule model reaction and activation energy evolution of the dissociation of the dynamic network. This inhibitory effect would reduce the dissociated units in the dynamic polymeric network, beneficial for the strength of the ionogel. Furthermore, aromatic disulfide bonds with high reversibility are embedded in the polyurethane to endow the ionogel with superior room temperature self-healing performance. Isocyanates with an asymmetric alicyclic structure are chosen to provide optimal exchange efficiencies for the embedded disulfide bonds relative to aromatic and linear aliphatic. Carbonyl-rich poly(ethylene-glycol-adipate) diols are selected as soft segments to provide sufficient interaction sites for ionic liquids to endow the ionogel with high transparency, stretchability, and elasticity. Finally, a self-healing ionogel with a tensile strength of 1.65 +/- 0.08 MPa is successfully developed, which is significantly higher than all the reported transparent room temperature self-healing ionogel and its application in a 3D printed stretchable numeric keyboard is exemplified.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207527", "DOI Link": "http://dx.doi.org/10.1002/advs.202207527", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979894700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Zha, M; Du, CF; Jia, HL; Wang, C; Guan, K; Gao, YP; Wang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tong; Zha, Min; Du, Chunfeng; Jia, Hai-Long; Wang, Cheng; Guan, Kai; Gao, Yipeng; Wang, Hui-Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High strength and high ductility achieved in a heterogeneous lamella-structured magnesium alloy", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "IMPACT STATEMENT The heterogeneous lamella-structure leads to sustained strain-hardenability in Mg-alloy with unique accommodating deformation modes (extensive abnormal slips and feather-shaped twins), induced by grain-boundary disclinations and intergranular slip transfers. By introducing heterogeneous lamella-structure, we obtained a superior strength-ductility synergy in Mg-alloy associated with excellent strain-hardening ability, i.e. yield strength of similar to 251 MPa, tensile strength of similar to 393 MPa and elongation of similar to 23%. By using advanced characterization techniques, we showed that strengthening was mainly caused by the non-uniform distribution of hetero-deformation induced (HDI) stress associated with grain-boundary disclinations, which are mediated by heterogeneous multi-grain interactions. Induced by grain-boundary disclinations and intergranular slip transfers, a variety of abnormal deformation modes have been activated?which contributed significantly to enhanced ductility. This work suggests a new avenue to evade strength-ductility trade-off dilemma in Mg-alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2023, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 187, "End Page": 195, "Article Number": null, "DOI": "10.1080/21663831.2022.2133976", "DOI Link": "http://dx.doi.org/10.1080/21663831.2022.2133976", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870507700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mendes, JF; Paschoalin, RT; Carmona, VB; Neto, ARS; Marques, ACP; Marconcini, M; Mattoso, LHC; Medeiros, ES; Oliveira, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mendes, J. F.; Paschoalin, R. T.; Carmona, V. B.; Sena Neto, Alfredo R.; Marques, A. C. P.; Marconcini, M.; Mattoso, L. H. C.; Medeiros, E. S.; Oliveira, J. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable polymer blends based on corn starch and thermoplastic chitosan processed by extrusion", "Source Title": "CARBOHYDRATE POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Blends of thermoplastic cornstarch (TPS) and chitosan (TPC) were obtained by melt extrusion. The effect of TPC incorporation in TPS matrix and polymer interaction on morphology and thermal and mechanical properties were investigated. Possible interactions between the starch molecules and thermoplastic chitosan were assessed by XRD and FTIR techniques. Scanning Electron Microscopy (SEM) analyses showed a homogeneous fracture surface without the presence of starch granules or chitosan aggregates. Although the incorporation of thermoplastic chitosan caused a decrease in both tensile strength and stiffness, films with better extensibility and thermal stability were produced. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2016, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 452, "End Page": 458, "Article Number": null, "DOI": "10.1016/j.carbpol.2015.10.093", "DOI Link": "http://dx.doi.org/10.1016/j.carbpol.2015.10.093", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366938200052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Isayev, O; Oses, C; Toher, C; Gossett, E; Curtarolo, S; Tropsha, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Isayev, Olexandr; Oses, Corey; Toher, Cormac; Gossett, Eric; Curtarolo, Stefano; Tropsha, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal fragment descriptors for predicting properties of inorganic crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although historically materials discovery has been driven by a laborious trial-and-error process, knowledge-driven materials design can now be enabled by the rational combination of Machine Learning methods and materials databases. Here, data from the AFLOW repository for ab initio calculations is combined with Quantitative Materials Structure-Property Relationship models to predict important properties: metal/insulator classification, band gap energy, bulk/shear moduli, Debye temperature and heat capacities. The prediction's accuracy compares well with the quality of the training data for virtually any stoichiometric inorganic crystalline material, reciprocating the available thermomechanical experimental data. The universality of the approach is attributed to the construction of the descriptors: Property-Labelled Materials Fragments. The representations require only minimal structural input allowing straightforward implementations of simple heuristic design rules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 469, "Times Cited, All Databases": 532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15679, "DOI": "10.1038/ncomms15679", "DOI Link": "http://dx.doi.org/10.1038/ncomms15679", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402755100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, KS; Wang, JY; Cao, L; Yang, W; Guo, WC; Liu, SH; Li, W; Wang, FY; Li, XA; Xu, ZP; Wang, ZB; Wang, HY; Hou, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Kesong; Wang, Junyan; Cao, Ling; Yang, Wei; Guo, Wanchun; Liu, Shuhu; Li, Wei; Wang, Fengyan; Li, Xueai; Xu, Zhaopeng; Wang, Zhenbo; Wang, Haiyan; Hou, Yanglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-site pyrrolic-nitrogen-doped sp2-hybridized carbon materials and their pseudocapacitance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integrating nitrogen species into sp(2)-hybridized carbon materials has proved an efficient means to improve their electrochemical performance. Nevertheless, an inevitable mixture of nitrogen species in carbon materials, due to the uncontrolled conversion among different nitrogen configurations involved in synthesizing nitrogen-doped carbon materials, largely retards the precise identification of electrochemically active nitrogen configurations for specific reactions. Here, we report the preparation of single pyrrolic N-doped carbon materials (SPNCMs) with a tunable nitrogen content from 0 to 4.22at.% based on a strategy of low-temperature dehalogenation-induced and subsequent alkaline-activated pyrolysis of 3-halogenated phenol-3-aminophenol-formaldehyde (X-APF) co-condensed resins. Additionally, considering that the pseudocapacitance of SPNCMs is positively dependent on the pyrrolic nitrogen content, it could be inferred that pyrrolic nitrogen species are highly active pseudocapacitive sites for nitrogen-doped carbon materials. This work gives an ideal model for understanding the contribution of pyrrolic nitrogen species in N-doped carbon materials. A mixture of nitrogen species in carbon materials typically hinders the precise identification of electrochemically active nitrogen configurations for specific reactions. Here the authors show single-site pyrrolic-nitrogen-doped sp(2)-hybridized carbon materials and their pseudocapacitive properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3884, "DOI": "10.1038/s41467-020-17727-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17727-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561116100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Toki, GFI; Kuddus, A; Rubel, MHK; Hossain, MM; Bencherif, H; Rahman, MF; Islam, MR; Mushtaq, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Toki, G. F. Ishraque; Kuddus, Abdul; Rubel, M. H. K.; Hossain, M. M.; Bencherif, H.; Rahman, Md. Ferdous; Islam, Md. Rasidul; Mushtaq, Muhammad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An extensive study on multiple ETL and HTL layers to design and simulation of high-performance lead-free CsSnCl3-based perovskite solar cells", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cesium tin chloride (CsSnCl3) is a potential and competitive absorber material for lead-free perovskite solar cells (PSCs). The full potential of CsSnCl3 not yet been realized owing to the possible challenges of defect-free device fabrication, non-optimized alignment of the electron transport layer (ETL), hole transport layer (HTL), and the favorable device configuration. In this work, we proposed several CsSnCl3-based solar cell (SC) configurations using one dimensional solar cell capacitance simulator (SCAPS-1D) with different competent ETLs like indium-gallium-zinc-oxide (IGZO), tin-dioxide (SnO2), tungsten disulfide (WS2), ceric dioxide (CeO2), titanium dioxide (TiO2), zinc oxide (ZnO), C-60, PCBM, and HTLs of cuprous oxide (Cu2O), cupric oxide (CuO), nickel oxide (NiO), vanadium oxide (V2O5), copper iodide (CuI), CuSCN, CuSbS2, Spiro MeOTAD, CBTS, CFTS, P3HT, PEDOT:PSS. Simulation results revealed that ZnO, TiO2, IGZO, WS2, PCBM, and C-60 ETLs-based halide perovskites with ITO/ETLs/CsSnCl3/CBTS/Au heterostructure exhibited outstanding photoconversion efficiency retaining nearest photovoltaic parameters values among 96 different configurations. Further, for the six best-performing configurations, the effect of the CsSnCl3 absorber and ETL thickness, series and shunt resistance, working temperature, impact of capacitance, Mott-Schottky, generation and recombination rate, current-voltage properties, and quantum efficiency on performance were assessed. We found that ETLs like TiO2, ZnO, and IGZO, with CBTS HTL can act as outstanding materials for the fabrication of CsSnCl3-based high efficiency (eta >= 22%) heterojunction SCs with ITO/ETL/CsSnCl3/CBTS/Au structure. The simulation results obtained by the SCAPS-1D for the best six CsSnCl3-perovskites SC configurations were compared by the wxAMPS (widget provided analysis of microelectronic and photonic structures) tool for further validation. Furthermore, the structural, optical and electronic properties along with electron charge density, and Fermi surface of the CsSnCl3 perovskite absorber layer were computed and analyzed using first-principle calculations based on density functional theory. Thus, this in-depth simulation paves a constructive research avenue to fabricate cost-effective, high-efficiency, and lead-free CsSnCl3 perovskite-based high-performance SCs for a lead-free green and pollution-free environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2023, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2521, "DOI": "10.1038/s41598-023-28506-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-023-28506-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984284300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Danz, T; Domröse, T; Ropers, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Danz, Thomas; Domroese, Till; Ropers, Claus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast nulloimaging of the order parameter in a structural phase transition", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding microscopic processes in materials and devices that can be switched by light requires experimental access to dynamics on nullometer length and femtosecond time scales. Here, we introduce ultrafast dark-field electron microscopy to map the order parameter across a structural phase transition. We use ultrashort laser pulses to locally excite a 1T-TaS2 (1T-polytype of tantalum disulfide) thin film and image the transient state of the specimen by ultrashort electron pulses. A tailored dark-field aperture array allows us to track the evolution of charge-density wave domains in the material with simultaneous femtosecond temporal and 5-nullometer spatial resolution, elucidating relaxation pathways and domain wall dynamics. The distinctive benefits of selective contrast enhancement will inspire future beam-shaping technology in ultrafast transmission electron microscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2021, "Volume": 371, "Issue": 6527, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd2774", "DOI Link": "http://dx.doi.org/10.1126/science.abd2774", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609884600036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, K; Lim, SY; Lee, JU; Lee, S; Kim, TY; Park, K; Jeon, GS; Park, CH; Park, JG; Cheong, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Kangwon; Lim, Soo Yeon; Lee, Jae-Ung; Lee, Sungmin; Kim, Tae Yun; Park, Kisoo; Jeon, Gun Sang; Park, Cheol-Hwan; Park, Je-Geun; Cheong, Hyeonsik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "How a certain ground state of complex physical systems emerges, especially in two-dimensional materials, is a fundamental question in condensed-matter physics. A particularly interesting case is systems belonging to the class of XY Hamiltonian where the magnetic order parameter of conventional nature is unstable in two-dimensional materials leading to a Berezinskii-Kosterlitz-Thouless transition. Here, we report how the XXZ-type anti-ferromagnetic order of a magnetic van der Waals material, NiPS3, behaves upon reducing the thickness and ultimately becomes unstable in the monolayer limit. Our experimental data are consistent with the findings based on renormalization-group theory that at low temperatures a two-dimensional XXZ system behaves like a two-dimensional XY one, which cannot have a long-range order at finite temperatures. This work provides the experimental examination of the XY magnetism in the atomically thin limit and opens opportunities of exploiting these fundamental theorems of magnetism using magnetic van der Waals materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 345, "DOI": "10.1038/s41467-018-08284-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08284-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456164800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, TW; Yang, TJ; Zhang, Q; Yuan, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Tianwen; Yang, Tianjia; Zhang, Qiang; Yuan, Wang Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Clustering and halogen effects enabled red/near-infrared room temperature phosphorescence from aliphatic cyclic imides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pure organic room temperature phosphorescence (RTP) materials become increasingly important but achieving red and near-infrared (NIR) RTP remains challenging. Here, the authors demonstrate that succinimide derived cyclic imides can emit RTP in the red and NIR spectral range with outstanding efficiencies of up to 9.2%. Pure organic room temperature phosphorescence (RTP) materials become increasingly important in advanced optoelectronic and bioelectronic applications. Current phosphors based on small aromatic molecules show emission characteristics generally limited to short wavelengths. It remains an enormous challenge to achieve red and near-infrared (NIR) RTP, particularly for those from nonaromatics. Here we demonstrate that succinimide derived cyclic imides can emit RTP in the red (665, 690 nm) and NIR (745 nm) spectral range with high efficiencies of up to 9.2%. Despite their rather limited molecular conjugations, their unique emission stems from the presence of the imide unit and heavy atoms, effective molecular clustering, and the electron delocalization of halogens. We further demonstrate that the presence of heavy atoms like halogen or chalcogen atoms in these systems is important to facilitate intersystem crossing as well as to extend through-space conjugation and to enable rigidified conformations. This universal strategy paves the way to the design of nonconventional luminophores with long wavelength emission and for emerging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2658, "DOI": "10.1038/s41467-022-30368-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30368-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000795171100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chernikov, A; van der Zande, AM; Hill, HM; Rigosi, AF; Velauthapillai, A; Hone, J; Heinz, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chernikov, Alexey; van der Zande, Arend M.; Hill, Heather M.; Rigosi, Albert F.; Velauthapillai, Ajanth; Hone, James; Heinz, Tony F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical Tuning of Exciton Binding Energies in Monolayer WS2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate continuous tuning of the exciton binding energy in monolayer WS2 by means of an externally applied voltage in a field-effect transistor device. Using optical spectroscopy, we monitor the ground and excited excitonic states as a function of gate voltage and track the evolution of the quasiparticle band gap. The observed decrease of the exciton binding energy over the range of about 100 meV, accompanied by the renormalization of the quasiparticle band gap, is associated with screening of the Coulomb interaction by the electrically injected free charge carriers at densities up to 8 x 10(12) cm(-2). Complete ionization of the excitons due to the electrical doping is estimated to occur at a carrier density of several 10(13) cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2015, "Volume": 115, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126802, "DOI": "10.1103/PhysRevLett.115.126802", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.126802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361316500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lei, Y; Butler, D; Lucking, MC; Zhang, F; Xia, TN; Fujisawa, K; Granzier-Nakajima, T; Cruz-Silva, R; Endo, M; Terrones, H; Terrones, M; Ebrahimi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lei, Yu; Butler, Derrick; Lucking, Michael C.; Zhang, Fu; Xia, Tunull; Fujisawa, Kazunori; Granzier-Nakajima, Tomotaroh; Cruz-Silva, Rodolfo; Endo, Morinobu; Terrones, Humberto; Terrones, Mauricio; Ebrahimi, Aida", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom doping of MoS2 with manganese enables ultrasensitive detection of dopamine: Experimental and computational approach", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition metal dichalcogenides (TMDs) emerged as a promising platform to construct sensitive biosensors. We report an ultrasensitive electrochemical dopamine sensor based on manganese-doped MoS2 synthesized via a scalable two-step approach (with Mn similar to 2.15 atomic %). Selective dopamine detection is achieved with a detection limit of 50 pM in buffer solution, 5 nM in 10% serum, and 50 nM in artificial sweat. Density functional theory calculations and scanning transmission electron microscopy show that two types of Mn defects are dominullt: Mn on top of a Mo atom (Mn-t(opMo)) and Mn substituting a Mo atom (Mn-Mo). At low dopamine concentrations, physisorption on Mn-Mo. dominates. At higher concentrations, dopamine chemisorbs on Mn-topMo, which is consistent with calculations of the dopamine binding energy (2.91 eV for Mn-topMo versus 0.65 eV for Mn-Mo). Our results demonstrate that metal-doped layered materials, such as TMDs, constitute an emergent platform to construct ultrasensitive and tunable biosensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 6, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabc4250", "DOI": "10.1126/sciadv.abc4250", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abc4250", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560452300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, NN; Ren, J; Liu, Y; Huang, Y; Petit, T; Zhang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, nullnull; Ren, Jian; Liu, Yang; Huang, Yi; Petit, Tristan; Zhang, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering oxygen-containing and amino groups into two-dimensional atomically-thin porous polymeric carbon nitrogen for enhanced photocatalytic hydrogen production", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymeric carbon nitride (PCN) is a promising earth-abundant photocatalyst for solar energy conversion. However, the photocatalytic activities of PCN-based materials remain moderate because of their poor dispersion in water and their fast electron-hole recombination. Here, a facile two-step continuous thermal treatment strategy is presented to endow the bulk PCN nullosheets with an atomically-thin structure, strong hydrophilicity and Lewis basicity to dramatically enhance the photocatalytic hydrogen (H-2) generation performance. The formation of the oxygen-containing and amino groups in the atomically-thin PCN sheets improves the charge separation and provides rich active sites for the surface reaction. Such synergistic effects lead to a superior visible-light-driven photocatalytic activity and its H-2 evolution rate (1233.5 mu mol h(-1)g(-1)) is more than 11 times higher than the bulk PCN using Ni as a cocatalyst. Additionally, the H-2 evolution rate can reach 20948.6 mu mol h(-1)g(-1) using Pt as a cocatalyst under AM1.5G solar irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2018, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 566, "End Page": 571, "Article Number": null, "DOI": "10.1039/c7ee03592f", "DOI Link": "http://dx.doi.org/10.1039/c7ee03592f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428187100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Rodan-Legrain, D; Park, JM; Yuan, NFQ; Watanabe, K; Taniguchi, T; Fernulldes, RM; Fu, L; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuan; Rodan-Legrain, Daniel; Park, Jeong Min; Yuan, Noah F. Q.; Watanabe, Kenji; Taniguchi, Takashi; Fernulldes, Rafael M.; Fu, Liang; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nematicity and competing orders in superconducting magic-angle graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strongly interacting electrons in solid-state systems often display multiple broken symmetries in the ground state. The interplay between different order parameters can give rise to a rich phase diagram. We report on the identification of intertwined phases with broken rotational symmetry in magic-angle twisted bilayer graphene (TBG). Using transverse resistance measurements, we find a strongly anisotropic phase located in a wedge above the underdoped region of the superconducting dome. Upon its crossing with the superconducting dome, a reduction of the critical temperature is observed. Furthermore, the superconducting state exhibits an anisotropic response to a direction-dependent in-plane magnetic field, revealing nematic ordering across the entire superconducting dome. These results indicate that nematic fluctuations might play an important role in the low-temperature phases of magic-angle TBG.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2021, "Volume": 372, "Issue": 6539, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 264, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abc2836", "DOI Link": "http://dx.doi.org/10.1126/science.abc2836", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641286700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reeder, JT; Xie, ZQ; Yang, QS; Seo, MH; Yan, Y; Deng, YJ; Jinkins, KR; Krishnull, SR; Liu, C; McKay, S; Patnaude, E; Johnson, A; Zhao, ZC; Kim, MJ; Xu, YM; Huang, I; Avila, R; Felicelli, C; Ray, E; Guo, X; Ray, WZ; Huang, YG; MacEwan, MR; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reeder, Jonathan T.; Xie, Zhaoqian; Yang, Quansan; Seo, Min-Ho; Yan, Ying; Deng, Yujun; Jinkins, Katherine R.; Krishnull, Siddharth R.; Liu, Claire; McKay, Shannon; Patnaude, Emily; Johnson, Alexandra; Zhao, Zichen; Kim, Moon Joo; Xu, Yameng; Huang, Ivy; Avila, Raudel; Felicelli, Christopher; Ray, Emily; Guo, Xu; Ray, Wilson Z.; Huang, Yonggang; MacEwan, Matthew R.; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft, bioresorbable coolers for reversible conduction block of peripheral nerves", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Implantable devices capable of targeted and reversible blocking of peripheral nerve activity may provide alternatives to opioids for treating pain. Local cooling represents an attractive means for on-demand elimination of pain signals, but traditional technologies are limited by rigid, bulky form factors; imprecise cooling; and requirements for extraction surgeries. Here, we introduce soft, bioresorbable, microfluidic devices that enable delivery of focused, minimally invasive cooling power at arbitrary depths in living tissues with real-time temperature feedback control. Construction with water-soluble, biocompatible materials leads to dissolution and bioresorption as a mechanism to eliminate unnecessary device load and risk to the patient without additional surgeries. Multiweek in vivo trials demonstrate the ability to rapidly and precisely cool peripheral nerves to provide local, on-demand analgesia in rat models for neuropathic pain.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 377, "Issue": 6601, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 109, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abl8532", "DOI Link": "http://dx.doi.org/10.1126/science.abl8532", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822009800052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khorshidi, B; Thundat, T; Fleck, BA; Sadrzadeh, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khorshidi, Behnam; Thundat, Thomas; Fleck, Brian A.; Sadrzadeh, Mohtada", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Approach Toward Fabrication of High Performance Thin Film Composite Polyamide Membranes", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A practical method is reported to enhance water permeability of thin film composite (TFC) polyamide (PA) membranes by decreasing the thickness of the selective PA layer. The composite membranes were prepared by interfacial polymerization (IP) reaction between meta-phenylene diamine (MPD)-aqueous and trimesoyl chloride (TMC)-organic solvents at the surface of polyethersulfone (PES) microporous support. Several PA TFC membranes were prepared at different temperatures of the organic solution ranging from -20 degrees C to 50 degrees C. The physico-chemical and morphological properties of the synthesized membranes were carefully characterized using serval analytical techniques. The results confirmed that the TFC membranes, synthesized at sub-zero temperatures of organic solution, had thinner and smoother PA layer with a greater degree of cross-linking and wettability compared to the PA films prepared at 50 degrees C. We demonstrated that reducing the temperature of organic solution effectively decreased the thickness of the PA active layer and thus enhanced water permeation through the membranes. The most water permeable membrane was prepared at -20 degrees C and exhibited nine times higher water flux compared to the membrane synthesized at room temperature. The method proposed in this report can be effectively applied for energy-and cost-efficient development of high performance nullofiltration and reverse osmosis membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 29", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 22069, "DOI": "10.1038/srep22069", "DOI Link": "http://dx.doi.org/10.1038/srep22069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371107600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, L; Li, YF; Zhang, YK; Qiu, LW; Xing, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Liang; Li, Yunfeng; Zhang, Yongkang; Qiu, Liewei; Xing, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 0D/2D Bi4V2O11/g-C3N4 S-Scheme Heterojunction with Rapid Interfacial Charges Migration for Photocatalytic Antibiotic Degradation", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the rapid development of industrial technology, a large number of organic pollutants are routinely released into the environment, which has caused serious problems. Semiconductor photocatalysis is an environmentally-friendly and effective method to degrade and remove typical pollutants, and photocatalysts play a key role in the application of this technology. Therefore, various semiconductor materials have been tried and used in the field of pollutant removal. Graphite carbon nitride (g-C3N4) has attracted great interest because of its two-dimensional layered structure and good visible light response range. Owing to a narrow bandgap, adjustable band structure, and high physicochemical stability, g-C3N4 absorbs wavelengths up to 450 nm in the visible spectrum, leading to an opportunity for visible-light photocatalytic performance. Nevertheless, there are still some drawbacks that limit the photocatalytic efficiency of g-C3N4 in the removal of antibiotics and dyes under visible light, such as the rapid recombination of photoinduced charges and the weak oxidation capacity of holes. To advance this promising photocatalytic material, multiple methods have been tried to optimize the electronic band structure of g-C3N4, such as doping with various elements, morphology control, and functional group modification. Recently, a novel type of Step-scheme (S-scheme) heterojunction composed of two n-type semiconductor photocatalysts has been proposed, which can utilize a more positive valance band and a more negative conduction band. It was demonstrated that the formation of S-scheme heterojunctions is a valid way to increase photocatalytic activity of g-C3N4. Herein, novel 0D/2D Bi4V2O11/g-C3N4 S-scheme heterojunctions were prepared by a simple in situ solvothermal growth method. The Bi4V2O11/g-C3N4 composites displayed a high photocatalytic activity through the removal of oxytetracycline (OTC) and Reactive Red 2. In particular, the BVCN-50 composite showed the highest degradation efficiency for OTC of 74.1% and for Reactive Red 2 of 84.2% with center dot O2- as the primary active species. This highly improved photocatalytic performance can be ascribed to the generation of S-scheme heterojunctions, which provides for a high redox capacity of the heterojunction system (strong oxidative ability of Bi4V2O11 and strong reductive capacity of g-C3N4) and facilitates the space separation of photo-generated charges. Moreover, the surface plasmon resonullce effect of metallic Bi0 broadens the light utilization range of the heterojunction system. In addition, the possible degradation pathway and intermediates throughout the degradation process of OTC based on liquid chromatograph mass spectrometer (LC-MS) analysis were also studied. This work provides a novel tactic for the design and fabrication of g-C3N4-based S-scheme heterojunctions with enhanced photocatalytic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 38, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2112027, "DOI": "10.3866/PKU.WHXB202112027", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202112027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760791100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, JS; Xiong, W; Zhou, XH; Zhang, Y; Shi, D; Li, ZC; Lu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Jingsong; Xiong, Wei; Zhou, Xuhao; Zhang, Yi; Shi, Dong; Li, Zichen; Lu, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4-Hydroxyproline-Derived Sustainable Polythioesters: Controlled Ring-Opening Polymerization, Complete Recyclability, and Facile Functionalization", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sustainable production of chemically recyclable polymers presents a significant opportunity to polymer scientists to tackle the growing environmental and energy problems of current petroleum-based plastics. Despite recent advances, however, there are still pressing needs for an expanded horizon of chemically recyclable polymers. Herein, we introduce a new paradigm of biosourced polythioesters (PTEs) with high polymerizability and complete recyclability under mild and economical conditions. The thiolactone monomers with a high ring strain can be easily prepared in a two-step process from 4-hydroxyproline. Controlled ring-opening polymerizations (ROP) using inexpensive and weak bases afford PTEs with high molar masses (M-n) up to 259 kg mol(-1) and narrow dispersities generally below 1.15. The properties of PTEs can be readily adjusted by copolymerization and/or pre/post-functionalization on the side chains. Selective and complete depolymerizations of the PTEs in dilute solution at ambient to modest temperatures recycle clean monomers. Density functional theory (DFT) calculation of model reactions provides mechanistic insights and highlights the importance of judicious molecular design. Taken together, the unique ROP/depolymerization chemistry of such PTEs may offer a sustainable solution for creating and manufacturing high-value materials such as optical/photochemical plastics, self-immolative polymers, and degradable biomaterials under situations where recycle and reuse are indispensable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2019, "Volume": 141, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4928, "End Page": 4935, "Article Number": null, "DOI": "10.1021/jacs.9b00031", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462950800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Titchener, JG; Kruk, SS; Xu, L; Chung, HP; Parry, M; Kravchenko, II; Chen, YH; Solntsev, AS; Kivshar, YS; Neshev, DN; Sukhorukov, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kai; Titchener, James G.; Kruk, Sergey S.; Xu, Lei; Chung, Hung-Pin; Parry, Matthew; Kravchenko, Ivan I.; Chen, Yen-Hung; Solntsev, Alexander S.; Kivshar, Yuri S.; Neshev, Dragomir N.; Sukhorukov, Andrey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum metasurface for multiphoton interference and state reconstruction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metasurfaces based on resonullt nullophotonic structures have enabled innovative types of flat-optics devices that often outperform the capabilities of bulk components, yet these advances remain largely unexplored for quantum applications. We show that nonclassical multiphoton interferences can be achieved at the subwavelength scale in all-dielectric metasurfaces. We simultaneously image multiple projections of quantum states with a single metasurface, enabling a robust reconstruction of amplitude, phase, coherence, and entanglement of multiphoton polarization-encoded states. One-and two-photon states are reconstructed through nonlocal photon correlation measurements with polarization-insensitive click detectors positioned after the metasurface, and the scalability to higher photon numbers is established theoretically. Our work illustrates the feasibility of ultrathin quantum metadevices for the manipulation and measurement of multiphoton quantum states, with applications in free-space quantum imaging and communications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2018, "Volume": 361, "Issue": 6407, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1104, "End Page": 1107, "Article Number": null, "DOI": "10.1126/science.aat8196", "DOI Link": "http://dx.doi.org/10.1126/science.aat8196", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444513300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Ghosh, S; Roeser, J; Acharjya, A; Penschke, C; Tsutsui, Y; Rabeah, J; Wang, TY; Tameu, SYD; Ye, MY; Grüneberg, J; Li, S; Li, CX; Schomäcker, R; Van de Krol, R; Seki, S; Saalfrank, P; Thomas, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jin; Ghosh, Samrat; Roeser, Jerome; Acharjya, Amitava; Penschke, Christopher; Tsutsui, Yusuke; Rabeah, Jabor; Wang, Tianyi; Tameu, Simon Yves Djoko; Ye, Meng-Yang; Gruneberg, Julia; Li, Shuang; Li, Changxia; Schomaecker, Reinhard; Van de Krol, Roel; Seki, Shu; Saalfrank, Peter; Thomas, Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constitutional isomerism of the linkages in donor-acceptor covalent organic frameworks and its impact on photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Systematic investigation of isomerism in covalent organic frameworks (COFs) can provide key insights into their properties. Here, the authors reveal that the constitutional isomerism of the linkage i.e., linkage orientations distinctly impact COFs' structural and photophysical properties. When new covalent organic frameworks (COFs) are designed, the main efforts are typically focused on selecting specific building blocks with certain geometries and properties to control the structure and function of the final COFs. The nature of the linkage (imine, boroxine, vinyl, etc.) between these building blocks naturally also defines their properties. However, besides the linkage type, the orientation, i.e., the constitutional isomerism of these linkages, has rarely been considered so far as an essential aspect. In this work, three pairs of constitutionally isomeric imine-linked donor-acceptor (D-A) COFs are synthesized, which are different in the orientation of the imine bonds (D-C=N-A (DCNA) and D-N=C-A (DNCA)). The constitutional isomers show substantial differences in their photophysical properties and consequently in their photocatalytic performance. Indeed, all DCNA COFs show enhanced photocatalytic H-2 evolution performance than the corresponding DNCA COFs. Besides the imine COFs shown here, it can be concluded that the proposed concept of constitutional isomerism of linkages in COFs is quite universal and should be considered when designing and tuning the properties of COFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6317, "DOI": "10.1038/s41467-022-33875-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33875-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000871230700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grilli, F; Pardo, E; Stenvall, A; Nguyen, DN; Yuan, WJ; Gömöry, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grilli, Francesco; Pardo, Enric; Stenvall, Antti; Nguyen, Doan N.; Yuan, Weijia; Goemoery, Fedor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computation of Losses in HTS Under the Action of Varying Magnetic Fields and Currents", "Source Title": "IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Numerical modeling of superconductors is widely recognized as a powerful tool for interpreting experimental results, understanding physical mechanisms, and predicting the performance of high-temperature-superconductor (HTS) tapes, wires, and devices. This is particularly true for ac loss calculation since a sufficiently low ac loss value is imperative to make these materials attractive for commercialization. In recent years, a large variety of numerical models, which are based on different techniques and implementations, has been proposed by researchers around the world, with the purpose of being able to estimate ac losses in HTSs quickly and accurately. This paper presents a literature review of the methods for computing ac losses in HTS tapes, wires, and devices. Technical superconductors have a relatively complex geometry (filaments, which might be twisted or transposed, or layers) and consist of different materials. As a result, different loss contributions exist. In this paper, we describe the ways of computing such loss contributions, which include hysteresis losses, eddy-current losses, coupling losses, and losses in ferromagnetic materials. We also provide an estimation of the losses occurring in a variety of power applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 24, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8200433, "DOI": "10.1109/TASC.2013.2259827", "DOI Link": "http://dx.doi.org/10.1109/TASC.2013.2259827", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330297100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chae, OB; Lucht, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chae, Oh B.; Lucht, Brett L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Issues and Modification of Solid Electrolyte Interphase for Li Metal Anode in Liquid and Solid Electrolytes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The high energy density required for the next generation of lithium batteries will likely be enabled by a shift toward lithium metal anode from the conventional intercalation-based anode such as graphite. However, several critical challenges for Li metal originate from its highly reactive nature and the hostless reaction of deposition and stripping impede the practical use of Li metal as an anode. The role of the solid electrolyte interphase (SEI) is very important for the Li metal anode where the SEI must protect the dynamically changing surface of the Li metal. Since the SEI-generating reaction mechanisms for the two different electrolyte systems, liquid and solid, are considerably different, the SEI layers formed between the Li metal and the electrolytes in the two electrolyte systems have substantially different properties, causing different interfacial issues. Inhibition of the interfacial problems requires different strategies to reinforce the SEI layer for each of the electrolyte systems. However, the differences in the two electrolyte systems have not been clearly compared in the prior literature. In this report, the interfacial issues for the two different electrolyte systems are compared and different strategies for SEI modification are provided to overcome the issues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 13, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202203791", "DOI Link": "http://dx.doi.org/10.1002/aenm.202203791", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939423300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Zhu, YJ; Fu, J; Yang, MC; Ran, ZY; Li, JL; Li, MX; Hu, J; He, JL; Li, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Zhu, Yujie; Fu, Jing; Yang, Mingcong; Ran, Zhaoyu; Li, Junluo; Li, Manxi; Hu, Jun; He, Jinliang; Li, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing tailored combinations of structural units in polymer dielectrics for high-temperature capacitive energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer dielectrics face huge challenges in the harsh environments of emergent applications. Now, increased energy storage of polymer dielectrics at temperatures up to 250 degrees C by designing tailored combinations of structural units is reported. Many mainstream dielectric energy storage technologies in the emergent applications, such as renewable energy, electrified transportations and advanced propulsion systems, are usually required to operate under harsh-temperature conditions. However, excellent capacitive performance and thermal stability tend to be mutually exclusive in the current polymer dielectric materials and applications. Here, we report a strategy to tailor structural units for the design of high-temperature polymer dielectrics. A library of polyimide-derived polymers from diverse combinations of structural units are predicted, and 12 representative polymers are synthesized for direct experimental investigation. This study provides important insights into decisive structural factors necessary to achieve robust and stable dielectrics with high energy storage capabilities at elevated temperature. We also find that the high-temperature insulation performance would experience diminishing marginal utility as the bandgap increases beyond a critical point, which is strongly correlated to the dihedral angle between neighboring planes of conjugation in these polymers. By experimentally testing the optimized and predicted structures, an increased energy storage at temperatures up to 250 degrees C is observed. We discuss the possibility for this strategy to be generally applied to other polymer dielectrics to achieve further performance enhancement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2406, "DOI": "10.1038/s41467-023-38145-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38145-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979744000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YN; Tian, C; Liu, YM; Liu, ZQ; Li, J; Wang, ZJ; Han, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yanull; Tian, Chuan; Liu, Yiming; Liu, Zaoqu; Li, Jing; Wang, Zijian; Han, Xinwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-in-one bioactive properties of photothermal nullofibers for accelerating diabetic wound healing", "Source Title": "BIOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diabetic wound healing has attracted widespread attention in biomedical engineering. However, the harsh hypoxic microenvironment (HME) comprising high glucose levels, local bleeding, and bacterial infection often leads to the formation of hyperplastic scars, increasing the clinical demand for wound dressings. Here, we report a comprehensive strategy using near-infrared NIR-assisted oxygen delivery combined with the bioactive nature of biopolymers for remodeling the HME. Black phosphorus (BP) nullosheets and hemoglobin (Hb) were self-assembled layerwise onto electrospun poly-l-lactide (PLLA) nullofibers using charged quaternized chitosan (QCS) and hyaluronic acid. BP converts NIR radiation into heat and stimulates Hb to release oxygen in situ. QCS is a hemostatic and broad-spectrum antibacterial material. Moderate BP-derived photothermal therapy can in-crease the sensitivity of bacteria to QCS. A series of composite wound dressings (coded as PQBH-n) with different numbers of layers were fabricated, and the in vivo diabetic wound healing potentials were tested. The molecular mechanism can be partly attributed to the cytokine-cytokine receptor interaction. Notably, this comprehensive strategy based on NIR-assisted oxygen delivery combined with the bioactive properties of biopolymers is not only applicable for fabricating multifunctional wound dressings but also has a great potential in expanding biomedical engineering fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 295, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 122029, "DOI": "10.1016/j.biomaterials.2023.122029", "DOI Link": "http://dx.doi.org/10.1016/j.biomaterials.2023.122029", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965186200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, Q; Cheng, HY; Jang, KI; Luan, HW; Hwang, KC; Rogers, JA; Huang, YG; Zhang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Qiang; Cheng, Huanyu; Jang, Kyung-In; Luan, Haiwen; Hwang, Keh-Chih; Rogers, John A.; Huang, Yonggang; Zhang, Yihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A nonlinear mechanics model of bio-inspired hierarchical lattice materials consisting of horseshoe microstructures", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of advanced synthetic materials that can mimic the mechanical properties of non-mineralized soft biological materials has important implications in a wide range of technologies. Hierarchical lattice materials constructed with horseshoe microstructures belong to this class of bio-inspired synthetic materials, where the mechanical responses can be tailored to match the nonlinear J-shaped stress-strain curves of human skins. The underlying relations between the J-shaped stress-strain curves and their microstructure geometry are essential in designing such systems for targeted applications. Here, a theoretical model of this type of hierarchical lattice material is developed by combining a finite deformation constitutive relation of the building block (i.e., horseshoe microstructure), with the analyses of equilibrium and deformation compatibility in the periodical lattices. The nonlinear J-shaped stress-strain curves and Poisson ratios predicted by this model agree very well with results of finite element analyses (FEA) and experiment. Based on this model, analytic solutions were obtained for some key mechanical quantities, e.g., elastic modulus, Poisson ratio, peak modulus, and critical strain around which the tangent modulus increases rapidly. A negative Poisson effect is revealed in the hierarchical lattice with triangular topology, as opposed to a positive Poisson effect in hierarchical lattices with Kagome and honeycomb topologies. The lattice topology is also found to have a strong influence on the stress-strain curve. For the three isotropic lattice topologies (triangular, Kagome and honeycomb), the hierarchical triangular lattice material renders the sharpest transition in the stress-strain curve and relative high stretchability, given the same porosity and arc angle of horseshoe microstructure. Furthermore, a demonstrative example illustrates the utility of the developed model in the rapid optimization of hierarchical lattice materials for reproducing the desired stress-strain curves of human skins. This study provides theoretical guidelines for future designs of soft bio-mimetic materials with hierarchical lattice constructions. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 90, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 179, "End Page": 202, "Article Number": null, "DOI": "10.1016/j.jmps.2016.02.012", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2016.02.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375631900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barai, P; Higa, K; Srinivasan, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium dendrite growth mechanisms in polymer electrolytes and prevention strategies", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Future lithium-ion batteries must use lithium metal anodes to fulfill the demands of high energy density applications with the potential to enable affordable electric cars with 350-mile range. However, dendrite growth during charging prevents the commercialization of this technology. It has been demonstrated that the presence of a compressive mechanical stress field around a dendritic protrusion prevents growth. Several techniques based on this concept, such as protective layers, externally applied pressure and solid electrolytes have been investigated by other researchers. Because of the low coulombic efficiencies associated with the stiff protective layers and high-pressure conditions, implementation of these techniques in commercial cells is complicated. Polymer-based solid electrolytes demonstrate better efficiency and capacity retention capabilities. However, dendrite growth is still possible in polymer electrolytes at higher current densities. The simulations described in this article provide guidance on the conditions under which dendrite growth is possible in polymer cells and targets for material properties needed for dendrite prevention. Increasing the elastic modulus of the electrolyte prevents the growth of dendritic protrusions in two ways: (i) higher compressive mechanical stress leads to reduced exchange current density at the protrusion peak compared to the valley, and (ii) plastic deformation of lithium metal results in reduction of the height of the dendritic protrusion. A phase map is constructed, showing the range of operation (applied current) and design (electrolyte elastic modulus) parameters that corresponds to stable lithium deposition. It is found that increasing the yield strength of the polymer electrolyte plays a significant role in preventing dendrite growth in lithium metal anodes, providing a new avenue for further exploration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2017, "Volume": 19, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20493, "End Page": 20505, "Article Number": null, "DOI": "10.1039/c7cp03304d", "DOI Link": "http://dx.doi.org/10.1039/c7cp03304d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407763700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barja, S; Refaely-Abramson, S; Schuler, B; Qiu, DY; Pulkin, A; Wickenburg, S; Ryu, H; Ugeda, MM; Kastl, C; Chen, C; Hwang, C; Schwartzberg, A; Aloni, S; Mo, SK; Ogletree, DF; Crommie, MF; Yazyev, O; Louie, SG; Neaton, JB; Weber-Bargioni, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barja, Sara; Refaely-Abramson, Sivan; Schuler, Bruno; Qiu, Diana Y.; Pulkin, Artem; Wickenburg, Sebastian; Ryu, Hyejin; Ugeda, Miguel M.; Kastl, Christoph; Chen, Christopher; Hwang, Choongyu; Schwartzberg, Adam; Aloni, Shaul; Mo, Sung-Kwan; Ogletree, D. Frank; Crommie, Michael F.; Yazyev, Oleg, V; Louie, Steven G.; Neaton, Jeffrey B.; Weber-Bargioni, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying substitutional oxygen as a prolific point defect in monolayer transition metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chalcogen vacancies are generally considered to be the most common point defects in transition metal dichalcogenide (TMD) semiconductors because of their low formation energy in vacuum and their frequent observation in transmission electron microscopy studies. Consequently, unexpected optical, transport, and catalytic properties in 2D-TMDs have been attributed to in-gap states associated with chalcogen vacancies, even in the absence of direct experimental evidence. Here, we combine low-temperature non-contact atomic force microscopy, scanning tunneling microscopy and spectroscopy, and state-of-the-art ab initio density functional theory and GW calculations to determine both the atomic structure and electronic properties of an abundant chalcogen-site point defect common to MoSe2 and WS2 monolayers grown by molecular beam epitaxy and chemical vapor deposition, respectively. Surprisingly, we observe no in-gap states. Our results strongly suggest that the common chalcogen defects in the described 2D-TMD semiconductors, measured in vacuum environment after gentle annealing, are oxygen substitutional defects, rather than vacancies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3382, "DOI": "10.1038/s41467-019-11342-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11342-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477706100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, Z; Li, H; Shaw, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Zhao; Li, Hao; Shaw, Leon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New insights into the solid-state hydrogen storage of nullostructured LiBH4-MgH2 system", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the nullo-mixture of LiBH4 + MgH2 is prepared by ball milling (BM) of 1 mol MgH2 with in-situ aerosol-spraying (AS) of 1 mol of LiBH4 (called BMAS). It is shown, for the first time, that Mg(BH4)(2) can be formed via the reaction between MgH2 and LiBH4 through the BMAS process and it contributes to H-2 release at temperature <= 265 degrees C. Three parallel H-2 release mechanisms have been identified from the BMAS powder. These include (i) H-2 release from the decomposition of nullo-LiBH4 and then Li2B12H12 decomposition product reacts with nullo-MgH2 to release H-2, (ii) H-2 release from the decomposition of nullo-Mg(BH4)(2), and (iii) H-2 release from the decomposition of nullo-MgH2. Together, these three mechanisms result in 4.11 wt% H-2 release in the solid-state at temperature <= 265 degrees C, which is among the highest quantities ever reported for LiBH4 + MgH2 mixtures to date. Furthermore, the H-2 release temperature for each mechanism described above is lower than the corresponding temperature reported using other synthesis methods. In addition, the predicted property of a small amount of the Fe3B phase in the BMAS powder in absorbing more H-2 than releasing is confirmed experimentally for the first time in this study. All these enhancements are achieved in the solid-state without any catalyst, which highlights the efficacy of mechanical activation and nulloengineering as well as the future opportunity to further improve the reversible hydrogen storage properties of LiBH4 + MgH2 in solid-state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 385, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123856, "DOI": "10.1016/j.cej.2019.123856", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2019.123856", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507465200107", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, EZ; Li, F; Zhang, DW; Xu, DK; Li, Z; Jia, R; Jin, YT; Song, H; Li, HB; Wang, Q; Wang, JJ; Li, XG; Gu, TY; Homborg, AM; Mol, JMC; Smith, JA; Wang, FH; Lovley, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Enze; Li, Feng; Zhang, Dawei; Xu, Dake; Li, Zhong; Jia, Ru; Jin, Yuting; Song, Hao; Li, Huabing; Wang, Qiang; Wang, Jianjun; Li, Xiaogang; Gu, Tingyue; Homborg, Axel M.; Mol, Johannes M. C.; Smith, Jessica A.; Wang, Fuhui; Lovley, Derek R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct microbial electron uptake as a mechanism for stainless steel corrosion in aerobic environments", "Source Title": "WATER RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shewanella oneidensis MR-1 is an attractive model microbe for elucidating the biofilm-metal interactions that contribute to the billions of dollars in corrosion damage to industrial applications each year. Multiple mechanisms for S. oneidensis-enhanced corrosion have been proposed, but none of these mechanisms have previously been rigorously investigated with methods that rule out alternative routes for electron transfer. We found that S. oneidensis grown under aerobic conditions formed thick biofilms (similar to 50 mu m) on stainless steel coupons, accelerating corrosion over sterile controls. H-2 and flavins were ruled out as intermediary electron carriers because stainless steel did not reduce riboflavin and previous studies have demonstrated stainless does not generate H-2. Strain Delta mtrCBA, in which the genes for the most abundant porin-cytochrome conduit in S. oneidensis were deleted, corroded stainless steel substantially less than wild-type in aerobic cultures. Wild-type biofilms readily reduced nitrate with stainless steel as the sole electron donor under anaerobic conditions, but strain Delta mtrCBA did not. These results demonstrate that S. oneidensis can directly consume electrons from ironcontaining metals and illustrate how direct metal-to-microbe electron transfer can be an important route for corrosion, even in aerobic environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 219, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118553, "DOI": "10.1016/j.watres.2022.118553", "DOI Link": "http://dx.doi.org/10.1016/j.watres.2022.118553", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000831180000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Savinov, V; Fedotov, VA; Zheludev, NI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Savinov, V.; Fedotov, V. A.; Zheludev, N. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toroidal dipolar excitation and macroscopic electromagnetic properties of metamaterials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The toroidal dipole is a peculiar electromagnetic excitation that can not be presented in terms of standard electric and magnetic multipoles. A static toroidal dipole has been shown to lead to violation of parity in atomic spectra and many other unusual electromagnetic phenomena. The existence of electromagnetic resonullces of toroidal nature was experimentally demonstrated only recently, first in the microwave metamaterials, and then at optical frequencies, where they could be important in spectroscopy analysis of a wide class of media with constituents of toroidal symmetry, such as complex organic molecules, fullerenes, bacteriophages, etc. Despite the experimental progress in studying toroidal resonullces, no direct link has yet been established between microscopic toroidal excitations and macroscopic scattering characteristics of the medium. To address this essential gap in the electromagnetic theory, we have developed an analytical approach for calculating the transmissivity and reflectivity of thin slabs of materials that exhibit toroidal dipolar excitations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2014, "Volume": 89, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205112, "DOI": "10.1103/PhysRevB.89.205112", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.205112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335914500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Davoodi, E; Montazerian, H; Mirhakimi, AS; Zhianmanesh, M; Ibhadode, O; Shahabad, SI; Esmaeilizadeh, R; Sarikhani, E; Toorandaz, S; Sarabi, SA; Nasiri, R; Zhu, YZ; Kadkhodapour, J; Li, BB; Khademhosseini, A; Toyserkani, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Davoodi, Elham; Montazerian, Hossein; Mirhakimi, Anooshe Sadat; Zhianmanesh, Masoud; Ibhadode, Osezua; Shahabad, Shahriar Imani; Esmaeilizadeh, Reza; Sarikhani, Einollah; Toorandaz, Sahar; Sarabi, Shima A.; Nasiri, Rohollah; Zhu, Yangzhi; Kadkhodapour, Javad; Li, Bingbing; Khademhosseini, Ali; Toyserkani, Ehsan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additively manufactured metallic biomaterials", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal additive manufacturing (AM) has led to an evolution in the design and fabrication of hard tissue substitutes, enabling personalized implants to address each patient's specific needs. In addition, internal pore architectures integrated within additively manufactured scaffolds, have provided an opportunity to further develop and engineer functional implants for better tissue integration, and long-term durability. In this review, the latest advances in different aspects of the design and manufacturing of additively manufactured metallic biomaterials are highlighted. After introducing metal AM processes, biocompatible metals adapted for integration with AM machines are presented. Then, we elaborate on the tools and approaches undertaken for the design of porous scaffold with engineered internal architecture including, topology optimization techniques, as well as unit cell patterns based on lattice networks, and triply periodic minimal surface. Here, the new possibilities brought by the functionally gradient porous structures to meet the conflicting scaffold design requirements are thoroughly discussed. Subsequently, the design constraints and physical characteristics of the additively manufactured constructs are reviewed in terms of input parameters such as design features and AM processing parameters. We assess the proposed applications of additively manufactured implants for regeneration of different tissue types and the efforts made towards their clinical translation. Finally, we conclude the review with the emerging directions and perspectives for further development of AM in the medical industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 15, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": 249, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.12.027", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.12.027", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789696200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blancon, JC; Stier, AV; Tsai, H; Nie, W; Stoumpos, CC; Traore, B; Pedesseau, L; Kepenekian, M; Katsutani, F; Noe, GT; Kono, J; Tretiak, S; Crooker, SA; Katan, C; Kanatzidis, MG; Crochet, JJ; Even, J; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blancon, J. -C.; Stier, A. V.; Tsai, H.; Nie, W.; Stoumpos, C. C.; Traore, B.; Pedesseau, L.; Kepenekian, M.; Katsutani, F.; Noe, G. T.; Kono, J.; Tretiak, S.; Crooker, S. A.; Katan, C.; Kanatzidis, M. G.; Crochet, J. J.; Even, J.; Mohite, A. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling law for excitons in 2D perovskite quantum wells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ruddlesden-Popper halide perovskites are 2D solution-processed quantum wells with a general formula A(2)A'n-1MnX3n+1, where optoelectronic properties can be tuned by varying the perovskite layer thickness (n-value), and have recently emerged as efficient semiconductors with technologically relevant stability. However, fundamental questions concerning the nature of optical resonullces (excitons or free carriers) and the exciton reduced mass, and their scaling with quantum well thickness, which are critical for designing efficient optoelectronic devices, remain unresolved. Here, using optical spectroscopy and 60-Tesla magnetoabsorption supported by modeling, we unambiguously demonstrate that the optical resonullces arise from tightly bound excitons with both exciton reduced masses and binding energies decreasing, respectively, from 0.221 m(0) to 0.186 m(0) and from 470 meV to 125 meV with increasing thickness from n equals 1 to 5. Based on this study we propose a general scaling law to determine the binding energy of excitons in perovskite quantum wells of any layer thickness.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2254, "DOI": "10.1038/s41467-018-04659-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04659-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434648600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, G; Son, JH; Lee, S; Kim, SW; Kim, D; Nguyen, NN; Lee, SG; Cho, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Giwon; Son, Jong Hyun; Lee, Siyoung; Kim, Seong Won; Kim, Daegun; Nguyen, Nguyen Ngan; Lee, Seung Goo; Cho, Kilwon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fingerpad-Inspired Multimodal Electronic Skin for Material Discrimination and Texture Recognition", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Human skin plays a critical role in a person communicating with his or her environment through diverse activities such as touching or deforming an object. Various electronic skin (E-skin) devices have been developed that show functional or geometrical superiority to human skin. However, research into stretchable E-skin that can simultaneously distinguish materials and textures has not been established yet. Here, the first approach to achieving a stretchable multimodal device is reported, that operates on the basis of various electrical properties of piezoelectricity, triboelectricity, and piezoresistivity and that exceeds the capabilities of human tactile perception. The prepared E-skin is composed of a wrinkle-patterned silicon elastomer, hybrid nullomaterials of silver nullowires and zinc oxide nullowires, and a thin elastomeric dielectric layer covering the hybrid nullomaterials, where the dielectric layer exhibits high surface roughness mimicking human fingerprints. This versatile device can identify and distinguish not only mechanical stress from a single stimulus such as pressure, tensile strain, or vibration but also that from a combination of multiple stimuli. With simultaneous sensing and analysis of the integrated stimuli, the approach enables material discrimination and texture recognition for a biomimetic prosthesis when the multifunctional E-skin is applied to a robotic hand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002606, "DOI": "10.1002/advs.202002606", "DOI Link": "http://dx.doi.org/10.1002/advs.202002606", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615805000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Zhou, PF; Liu, FM; Li, HX; Cheng, FY; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hang; Zhou, Pengfei; Liu, Fangming; Li, Haixia; Cheng, Fangyi; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing nickel-rich layered oxide cathodes by magnesium doping for rechargeable lithium-ion batteries", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel-rich layered transition metal oxides are attractive cathode materials for rechargeable lithium-ion batteries but suffer from inherent structural and thermal instabilities that limit the deliverable capacity and cycling performance on charging to a cutoff voltage above 4.3 V. Here we report LiNi0.90Co0.07Mg0.03O2 as a stable cathode material. The obtained LiNi0.90Co0.07Mg0.03O2 microspheres exhibit high capacity (228.3 mA h g(-1) at 0.1C) and remarkable cyclability (84.3% capacity retention after 300 cycles). Combined X-ray diffraction and Cs-corrected microscopy reveal that Mg doping stabilizes the layered structure by suppressing Li/Ni cation mixing and Ni migration to interlayer Li slabs. Because of the pillar effect of Mg in Li sites, LiNi0.90Co0.07Mg0.03O2 shows decent thermal stability and small lattice variation until it is charged to 4.7 V, undergoing a H1-H2 phase transition without discernible formation of an unstable H3 phase. The results indicate that moderate Mg doping is a facile yet effective strategy to develop high-performance Ni-rich cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2019, "Volume": 10, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1374, "End Page": 1379, "Article Number": null, "DOI": "10.1039/c8sc03385d", "DOI Link": "http://dx.doi.org/10.1039/c8sc03385d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457448700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sinhamahapatra, A; Jeon, JP; Kang, J; Han, B; Yu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sinhamahapatra, Apurba; Jeon, Jong-Pil; Kang, Joonhee; Han, Byungchan; Yu, Jong-Sung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen-Deficient Zirconia (ZrO2-x): A New Material for Solar Light Absorption", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we present oxygen-deficient black ZrO2-x as a new material for sunlight absorption with a low band gap around similar to 1.5 eV, via a controlled magnesiothermic reduction in 5% H-2/Ar from white ZrO2, a wide bandgap(-5 eV) semiconductor, usually not considered for solar light absorption. It shows for the first time a dramatic increase in solar light absorbance and significant activity for solar light-induced H-2 production from methanol-water with excellent stability up to 30 days while white ZrO2 fails. Generation of large amounts of oxygen vacancies or surface defects clearly visualized by the HR-TEM and HR-SEM images is the main reason for the drastic alteration of the optical properties through the formation of new energy states near valence band and conduction band towards Fermi level in black ZrO2-x as indicated by XPS and DFT calculations of black ZrO2-x. Current reduction method using Mg and H-2 is mild, but highly efficient to produce solar light-assisted photocatalytically active black ZrO2-x.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27218, "DOI": "10.1038/srep27218", "DOI Link": "http://dx.doi.org/10.1038/srep27218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377077900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, MY; Zhu, YT; Pittalà, F; Tang, J; He, MB; Ng, WC; Wang, JY; Ruan, ZL; Tang, XF; Kuschnerov, M; Liu, L; Yu, SY; Zheng, BF; Cai, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Mengyue; Zhu, Yuntao; Pittala, Fabio; Tang, Jin; He, Mingbo; Ng, Wing Chau; Wang, Jingyi; Ruan, Ziliang; Tang, Xuefeng; Kuschnerov, Maxim; Liu, Liu; Yu, Siyuan; Zheng, Bofang; Cai, Xinlun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-polarization thin-film lithium niobate in-phase quadrature modulators for terabit-per-second transmission", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report, to our knowledge, the first dual-polarization thin-film lithium niobate coherent modulator for next-generation optical links with sub-1-V driving voltage and 110-GHz bandwidth, enabling a record single-wavelength 1.96-Tb/s net data rate with ultrahigh energy efficiency. (C) 2022 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2022, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 61, "End Page": 62, "Article Number": null, "DOI": "10.1364/OPTICA.449691", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.449691", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746018800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kong, N; Zhang, HJ; Feng, C; Liu, C; Xiao, YF; Zhang, XC; Mei, L; Kim, JS; Tao, W; Ji, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kong, Na; Zhang, Hanjie; Feng, Chan; Liu, Chuang; Xiao, Yufen; Zhang, Xingcai; Mei, Lin; Kim, Jong Seung; Tao, Wei; Ji, Xiaoyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Arsenene-mediated multiple independently targeted reactive oxygen species burst for cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The modulation of intracellular reactive oxygen species (ROS) levels is crucial for cellular homeostasis and determination of cellular fate. A sublethal level of ROS sustains cell proliferation, differentiation and promotes tumor metastasis, while a drastic ROS burst directly induces apoptosis. Herein, surface-oxidized arsenene nullosheets (As/AsxOy NSs) with type II heterojunction are fabricated with efficient .O-2(-) and O-1(2) production and glutathione consumption through prolonging the lifetime of photo-excited electron-hole pairs. Moreover, the portion of AsxOy with oxygen vacancies not only catalyzes a Fenton-like reaction, generating .OH and O-2 from H2O2, but also inactivates main anti-oxidants to cut off the retreat routes of ROS. After polydopamine (PDA) and cancer cell membrane (M) coating, the engineered As/AsxOy@PDA@M NSs serve as an intelligent theranostic platform with active tumor targeting and long-term blood circulation. Given its narrow-band-gap-enabled in vivo fluorescence imaging properties, As/AsxOy@PDA@M NSs could be applied as an imaging-guided non-invasive and real-time nullomedicine for cancer therapy. Multifunctional materials with a number of effects are important for dealing with the complex environment in cancer therapy. Here, the authors report on surface-oxidized arsenene nullosheets coated with polydopamine and cancer cell membrane as a multi theranostic tumour targeting cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4777, "DOI": "10.1038/s41467-021-24961-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24961-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000684548700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, RT; Nguyen, NT; Nakajima, T; He, JL; Liu, XH; Zhang, XY; Wang, L; Wu, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Rui-Ting; Nguyen, Nhat Truong; Nakajima, Tomohiko; He, Jinlu; Liu, Xianhu; Zhang, Xueyuan; Wang, Lei; Wu, Limin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic semiconductor-electrolyte interface for sustainable solar water splitting over 600 hours under neutral conditions", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoelectrochemical (PEC) water splitting that functions in pH-neutral electrolyte attracts increasing attention to energy demand sustainability. Here, we propose a strategy to in situ form a NiB layer by tuning the compo-sition of the neutral electrolyte with the additions of nickel and borate species, which improves the PEC perfor-mance of the BiVO4 photoanode. The NiB/BiVO4 exhibits a photocurrent density of 6.0 mA cm-2 at 1.23 VRHE with an onset potential of 0.2 VRHE under 1 sun illumination. The photoanode displays a photostability of over 600 hours in a neutral electrolyte. The additive of Ni2+ in the electrolyte, which efficiently inhibits the dissolution of NiB, can accelerate the photogenerated charge transfer and enhance the water oxidation kinetics. The borate species with BO bonds act as a promoter of catalyst activity by accelerating proton-coupled electron transfer. The synergy effect of both species suppresses the surface charge recombination and inhibits the photocorrosion of BiVO4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2023, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eade4589", "DOI": "10.1126/sciadv.ade4589", "DOI Link": "http://dx.doi.org/10.1126/sciadv.ade4589", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936020700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, SJ; Stocks, GM; Zhang, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Shijun; Stocks, G. Malcolm; Zhang, Yanwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking fault energies of face-centered cubic concentrated solid solution alloys", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the stacking fault energy (SFE) for a series of face-centered cubic (fcc) equiatomic concentrated solid solution alloys (CSAs) derived as subsystems from the NiCoFeCrMn and NiCoFeCrPd high entropy alloys based on ab initio calculations. At low temperatures, these CSAs display very low even negative SFEs, indicating that hexagonal close-pack (hcp) is more energy favorable than fcc structure. The temperature dependence of SFE for some CSAs is studied. With increasing temperature, a hcp-to-fcc transition is revealed for those CSAs with negative SFEs, which can be attributed to the role of intrinsic vibrational entropy. The analysis of the vibrational modes suggests that the vibrational entropy arises from the high frequency states in the hcp structure that originate from local vibrational mode. Our results underscore the importance of vibrational entropy in determining the temperature dependence of SFE for CSAs. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 134, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 334, "End Page": 345, "Article Number": null, "DOI": "10.1016/j.actamat.2017.05.001", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.05.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406987700030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kulkarni, SA; Baikie, T; Boix, PP; Yantara, N; Mathews, N; Mhaisalkar, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kulkarni, Sneha A.; Baikie, Tom; Boix, Pablo P.; Yantara, Natalia; Mathews, Nripan; Mhaisalkar, Subodh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band-gap tuning of lead halide perovskites using a sequential deposition process", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Band-gap tuning of mixed anion lead halide perovskites (MAPb(I1-xBrx)(2) (0 <= x <= 1)) has been demonstrated by means of a sequential deposition process. The optical properties of perovskite hybrids can be flexibly modified by changing (mixing) the concentration of halogen precursors. The concentrations of precursor solution as well as the conversion time play an important role in determining the band-gap of perovskites. A systematic shift of the absorption band edge to shorter wavelengths is observed with increasing Br content in the perovskite films, which results in the decrement of the photocurrent. nullorod like morphological features are also observed for perovskite films with an iodide to bromide molar ratio of <0.7.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 518, "Times Cited, All Databases": 581, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9221, "End Page": 9225, "Article Number": null, "DOI": "10.1039/c4ta00435c", "DOI Link": "http://dx.doi.org/10.1039/c4ta00435c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336850600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, WK; Droguet, B; Shen, QC; Zhang, Y; Parton, TG; Shan, XW; Parker, RM; De Volder, MFL; Deng, T; Vignolini, S; Li, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Wenkai; Droguet, Benjamin; Shen, Qingchen; Zhang, Yun; Parton, Thomas G.; Shan, Xiwei; Parker, Richard M.; De Volder, Michael F. L.; Deng, Tao; Vignolini, Silvia; Li, Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structurally Colored Radiative Cooling Cellulosic Films", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Daytime radiative cooling (DRC) materials offer a sustainable approach to thermal management by exploiting net positive heat transfer to deep space. While such materials typically have a white or mirror-like appearance to maximize solar reflection, extending the palette of available colors is required to promote their real-world utilization. However, the incorporation of conventional absorption-based colorants inevitably leads to solar heating, which counteracts any radiative cooling effect. In this work, efficient sub-ambient DRC (Day: -4 degrees C, Night: -11 degrees C) from a vibrant, structurally colored film prepared from naturally derived cellulose nullocrystals (CNCs), is instead demonstrated. Arising from the underlying photonic nullostructure, the film selectively reflects visible light resulting in intense, fade-resistant coloration, while maintaining a low solar absorption (approximate to 3%). Additionally, a high emission within the mid-infrared atmospheric window (>90%) allows for significant radiative heat loss. By coating such CNC films onto a highly scattering, porous ethylcellulose (EC) base layer, any sunlight that penetrates the CNC layer is backscattered by the EC layer below, achieving broadband solar reflection and vibrant structural color simultaneously. Finally, scalable manufacturing using a commercially relevant roll-to-roll process validates the potential to produce such colored radiative cooling materials at a large scale from a low-cost and sustainable feedstock.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 9, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202061, "DOI": "10.1002/advs.202202061", "DOI Link": "http://dx.doi.org/10.1002/advs.202202061", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826199300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JT; Uddin, MA; Chen, B; Ying, XJ; Ni, ZY; Zhou, Y; Li, MZ; Wang, MR; Yu, ZH; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiantao; Uddin, Md Aslam; Chen, Bo; Ying, Xingjian; Ni, Zhenyi; Zhou, Ying; Li, Mingze; Wang, Mengru; Yu, Zhenhua; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing Photostability of Sn-Pb Perovskite Solar Cells by an Alkylammonium Pseudo-Halogen Additive", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance tin-lead perovskite solar cells (PSCs) are needed for all-perovskite-tandem solar cells. However, iodide related fast photodegradation severely limits the operational stability of Sn-Pb perovskites despite the demonstrated high efficiency and thermal stability. Herein, this work employs an alkylammonium pseudo-halogen additive to enhance the power conversion efficiency (PCE) and photostability of methylammonium (MA)-free, Sn-Pb PSCs. Density functional theory (DFT) calculations reveal that the pseudo-halogen tetrafluoroborate (BF4-) has strong binding capacity with metal ions (Sn2+/Pb2+) in the Sn-Pb perovskite lattice, which lowers iodine vacancy formation. Upon combining BF4- with an octylammonium (OA(+)) cation, the PCE of the device with a built-in light-scattering layer is boosted to 23.7%, which represents a new record for Sn-Pb PSCs. The improved efficiency benefits from the suppressed defect density. Under continuous 1 sun illumination, the OABF(4) embodied PSCs show slower generation of interstitial iodides and iodine, which greatly improves the device photostability under open-circuit condition. Moreover, the device based on OABF(4) retains 88% of the initial PCE for 1000 h under the maximum-power-point tracking (MPPT) without cooling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 13, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202204115", "DOI Link": "http://dx.doi.org/10.1002/aenm.202204115", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000941909000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, LP; Hong, XC; Dong, JK; Pan, J; Zhang, Z; Zhang, J; Li, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, L. P.; Hong, X. C.; Dong, J. K.; Pan, J.; Zhang, Z.; Zhang, J.; Li, S. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum Transport Evidence for the Three-Dimensional Dirac Semimetal Phase in Cd3As2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the quantum transport properties of Cd3As2 single crystals in a magnetic field. A large linear quantum magnetoresistance is observed near room temperature. With decreasing temperature, the Shubnikov-de Haas oscillations appear in both the longitudinal resistance R-xx and the transverse Hall resistance R-xy. From the strong oscillatory component Delta R-xx, a linear dependence of the Landau index n on 1/B is obtained, and it gives an n-axis intercept between 1/2 and 5/8. This clearly reveals a nontrivial pi Berry's phase, which is a distinguished feature of Dirac fermions. Our quantum transport results provide bulk evidence for the existence of a three-dimensional Dirac semimetal phase in Cd-3 As-2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 9", "Publication Year": 2014, "Volume": 113, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 246402, "DOI": "10.1103/PhysRevLett.113.246402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.246402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346387700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZJ; Song, HM; Ji, DX; Li, CY; Cheney, A; Liu, YH; Zhang, N; Zeng, X; Chen, BR; Gao, J; Li, YS; Liu, X; Aga, D; Jiang, SH; Yu, ZF; Gan, QQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhejun; Song, Haomin; Ji, Dengxin; Li, Chenyu; Cheney, Alec; Liu, Youhai; Zhang, null; Zeng, Xie; Chen, Borui; Gao, Jun; Li, Yuesheng; Liu, Xiang; Aga, Diana; Jiang, Suhua; Yu, Zongfu; Gan, Qiaoqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely Cost-Effective and Efficient Solar Vapor Generation under Nonconcentrated Illumination Using Thermally Isolated Black Paper", "Source Title": "GLOBAL CHALLENGES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive solar vapor generation represents a promising and environmentally benign method of water purification/desalination. However, conventional solar steam generation techniques usually rely on costly and cumbersome optical concentration systems and have relatively low efficiency due to bulk heating of the entire liquid volume. Here, an efficient strategy using extremely low-cost materials, i.e., carbon black (powder), hydrophilic porous paper, and expanded polystyrene foam is reported. Due to the excellent thermal insulation between the surface liquid and the bulk volume of the water and the suppressed radiative and convective losses from the absorber surface to the adjacent heated vapor, a record thermal efficiency of approximate to 88% is obtained under 1 sun without concentration, corresponding to the evaporation rate of 1.28 kg (m(2) h)(-1). When scaled up to a 100 cm(2) array in a portable solar water still system and placed in an outdoor environment, the freshwater generation rate is 2.4 times of that of a leading commercial product. By simultaneously addressing both the need for high-efficiency operation as well as production cost limitations, this system can provide an approach for individuals to purify water for personal needs, which is particularly suitable for undeveloped regions with limited/no access to electricity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2017, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600003, "DOI": "10.1002/gch2.201600003", "DOI Link": "http://dx.doi.org/10.1002/gch2.201600003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419786400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XK; Bertei, A; Finegan, DP; Tan, C; Daemi, SR; Weaving, JS; O'Regan, KB; Heenull, TMM; Hinds, G; Kendrick, E; Brett, DJL; Shearing, PR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xuekun; Bertei, Antonio; Finegan, Donal P.; Tan, Chun; Daemi, Sohrab R.; Weaving, Julia S.; O'Regan, Kieran B.; Heenull, Thomas M. M.; Hinds, Gareth; Kendrick, Emma; Brett, Dan J. L.; Shearing, Paul R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D microstructure design of lithium-ion battery electrodes assisted by X-ray nullo-computed tomography and modelling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Driving range and fast charge capability of electric vehicles are heavily dependent on the 3D microstructure of lithium-ion batteries (LiBs) and substantial fundamental research is required to optimise electrode design for specific operating conditions. Here we have developed a full microstructure-resolved 3D model using a novel X-ray nullo-computed tomography (CT) dual-scan superimposition technique that captures features of the carbon-binder domain. This elucidates how LiB performance is markedly affected by microstructural heterogeneities, particularly under high rate conditions. The elongated shape and wide size distribution of the active particles not only affect the lithium-ion transport but also lead to a heterogeneous current distribution and non-uniform lithiation between particles and along the through-thickness direction. Building on these insights, we propose and compare potential graded-microstructure designs for next-generation battery electrodes. To guide manufacturing of electrode architectures, in-situ X-ray CT is shown to reliably reveal the porosity and tortuosity changes with incremental calendering steps. The 3D microstructure of the electrode predominulltly determines the electrochemical performance of Li-ion batteries. Here, the authors show that the microstructural heterogeneities lead to non-uniform Li insertion and current distribution while graded-microstructures improve the performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2079, "DOI": "10.1038/s41467-020-15811-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15811-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531855500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LG; Ye, C; Yu, YJ; Lu, XF; Niu, XH; Kim, S; Feng, DL; Tománek, D; Son, YW; Chen, XH; Zhang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Liguo; Ye, Cun; Yu, Yijun; Lu, Xiu Fang; Niu, Xiaohai; Kim, Sejoong; Feng, Donglai; Tomanek, David; Son, Young-Woo; Chen, Xian Hui; Zhang, Yuanbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A metallic mosaic phase and the origin of Mott-insulating state in 1T-TaS2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron-electron and electron-phonon interactions are two major driving forces that stabilize various charge-ordered phases of matter. In layered compound 1T-TaS2, the intricate interplay between the two generates a Mott-insulating ground state with a peculiar charge-density-wave (CDW) order. The delicate balance also makes it possible to use external perturbations to create and manipulate novel phases in this material. Here, we study a mosaic CDW phase induced by voltage pulses, and find that the new phase exhibits electronic structures entirely different from that of the original Mott ground state. The mosaic phase consists of nullometre-sized domains characterized by well-defined phase shifts of the CDW order parameter in the topmost layer, and by altered stacking relative to the layers underneath. We discover that the nature of the new phase is dictated by the stacking order, and our results shed fresh light on the origin of the Mott phase in 1T-TaS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10956, "DOI": "10.1038/ncomms10956", "DOI Link": "http://dx.doi.org/10.1038/ncomms10956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371737900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, B; Zhang, H; Shao, HZ; Xu, YC; Zhang, XC; Zhu, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Bo; Zhang, Hao; Shao, Hezhu; Xu, Yuchen; Zhang, Xiangchao; Zhu, Heyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal conductivity of monolayer MoS2, MoSe2, and WS2: interplay of mass effect, interatomic bonding and anharmonicity", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonons are essential for understanding the thermal properties in monolayer transition metal dichalcogenides. We investigate the lattice dynamics and thermodynamic properties of MoS2, MoSe2, and WS2 by first principles calculations. The obtained phonon frequencies and thermal conductivities agree well with the measurements. Our results show that the thermal conductivity of MoS2 is highest among the three materials due to its low average atomic mass. We also discuss the competition between mass effect, interatomic bonding and anharmonic vibrations in determining the thermal conductivity of WS2. Strong covalent W-S bonding and low anharmonicity in WS2 are found to be crucial in understanding its much higher thermal conductivity compared to MoSe2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5767, "End Page": 5773, "Article Number": null, "DOI": "10.1039/c5ra19747c", "DOI Link": "http://dx.doi.org/10.1039/c5ra19747c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368941700073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koshelev, K; Tang, YT; Hu, ZX; Kravchenko, II; Li, GX; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koshelev, Kirill; Tang, Yutao; Hu, Zixian; Kravchenko, Ivan I.; Li, Guixin; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resonullt Chiral Effects in Nonlinear Dielectric Metasurfaces", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study the resonullt enhancement of linear and nonlinear chiroptical effects in planar silicon metasurfaces with an in-plane asymmetry supporting multipolar Mie resonullces and quasi-bound states in the continuum (quasi-BICs). We demon-strate theoretically and observe in experiment the pronounced linear circular dichroism at the quasi-BIC resonullces originating from the interaction of modes with the substrate. We further find that both local field enhancement and third-harmonic signal are large for Mie resonullces and some quasi-BIC modes due to the critical coupling. We demonstrate experimentally a strong nonlinear chiroptical response associated with high efficiency of the third-harmonic generation and large nonlinear circular dichroism varying from +0.918 +/- 0.049 to -0.771 +/- 0.004 for the samples with different asymmetries. We reveal the nonreciprocal nature of nonlinear chirality governed by the microscopic symmetry of nonlinearities and macroscopic symmetries of the meta-atom and metasurface lattice. We believe our results suggest a general strategy for engineering nonlinear chiroptical response in dielectric resonullt metasurfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 4", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acsphotonics.2c01926", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.2c01926", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000910959100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raja, A; Chaves, A; Yu, J; Arefe, G; Hill, HM; Rigosi, AF; Berkelbach, TC; Nagler, P; Schüller, C; Korn, T; Nuckolls, C; Hone, J; Brus, LE; Heinz, TF; Reichman, DR; Chernikov, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raja, Archana; Chaves, Andrey; Yu, Jaeeun; Arefe, Ghidewon; Hill, Heather M.; Rigosi, Albert F.; Berkelbach, Timothy C.; Nagler, Philipp; Schueller, Christian; Korn, Tobias; Nuckolls, Colin; Hone, James; Brus, Louis E.; Heinz, Tony F.; Reichman, David R.; Chernikov, Alexey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coulomb engineering of the bandgap and excitons in two-dimensional materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to control the size of the electronic bandgap is an integral part of solid-state technology. Atomically thin two-dimensional crystals offer a new approach for tuning the energies of the electronic states based on the unusual strength of the Coulomb interaction in these materials and its environmental sensitivity. Here, we show that by engineering the surrounding dielectric environment, one can tune the electronic bandgap and the exciton binding energy in monolayers of WS2 and WSe2 by hundreds of meV. We exploit this behaviour to present an in-plane dielectric heterostructure with a spatially dependent bandgap, as an initial step towards the creation of diverse lateral junctions with nulloscale resolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 597, "Times Cited, All Databases": 660, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15251, "DOI": "10.1038/ncomms15251", "DOI Link": "http://dx.doi.org/10.1038/ncomms15251", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400561500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yabuuchi, N; Nakayama, M; Takeuchi, M; Komaba, S; Hashimoto, Y; Mukai, T; Shiiba, H; Sato, K; Kobayashi, Y; Nakao, A; Yonemura, M; Yamanaka, K; Mitsuhara, K; Ohta, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yabuuchi, Naoaki; Nakayama, Masanobu; Takeuchi, Mitsue; Komaba, Shinichi; Hashimoto, Yu; Mukai, Takahiro; Shiiba, Hiromasa; Sato, Kei; Kobayashi, Yuki; Nakao, Aiko; Yonemura, Masao; Yamanaka, Keisuke; Mitsuhara, Kei; Ohta, Toshiaki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Further increase in energy density of lithium batteries is needed for zero emission vehicles. However, energy density is restricted by unavoidable theoretical limits for positive electrodes used in commercial applications. One possibility towards energy densities exceeding these limits is to utilize anion (oxide ion) redox, instead of classical transition metal redox. Nevertheless, origin of activation of the oxide ion and its stabilization mechanism are not fully understood. Here we demonstrate that the suppression of formation of superoxide-like species on lithium extraction results in reversible redox for oxide ions, which is stabilized by the presence of relatively less covalent character of Mn4+ with oxide ions without the sacrifice of electronic conductivity. On the basis of these findings, we report an electrode material, whose metallic constituents consist only of 3d transition metal elements. The material delivers a reversible capacity of 300 mAhg(-1) based on solid-state redox reaction of oxide ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13814, "DOI": "10.1038/ncomms13814", "DOI Link": "http://dx.doi.org/10.1038/ncomms13814", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390358000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yokota, T; Inoue, Y; Terakawa, Y; Reeder, J; Kaltenbrunner, M; Ware, T; Yang, KJ; Mabuchi, K; Murakawa, T; Sekino, M; Voit, W; Sekitani, T; Someya, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yokota, Tomoyuki; Inoue, Yusuke; Terakawa, Yuki; Reeder, Jonathan; Kaltenbrunner, Martin; Ware, Taylor; Yang, Kejia; Mabuchi, Kunihiko; Murakawa, Tomohiro; Sekino, Masaki; Voit, Walter; Sekitani, Tsuyoshi; Someya, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultraflexible, large-area, physiological temperature sensors for multipoint measurements", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a fabrication method for flexible and printable thermal sensors based on composites of semicrystalline acrylate polymers and graphite with a high sensitivity of 20 mK and a high-speed response time of less than 100 ms. These devices exhibit large resistance changes near body temperature under physiological conditions with high repeatability (1,800 times). Device performance is largely unaffected by bending to radii below 700 mu m, which allows for conformal application to the surface of living tissue. The sensing temperature can be tuned between 25 degrees C and 50 degrees C, which covers all relevant physiological temperatures. Furthermore, we demonstrate flexible active-matrix thermal sensors which can resolve spatial temperature gradients over a large area. With this flexible ultrasensitive temperature sensor we succeeded in the in vivo measurement of cyclic temperatures changes of 0.1 degrees C in a rat lung during breathing, without interference from constant tissue motion. This result conclusively shows that the lung of a warm-blooded animal maintains surprising temperature stability despite the large difference between core temperature and inhaled air temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2015, "Volume": 112, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14533, "End Page": 14538, "Article Number": null, "DOI": "10.1073/pnas.1515650112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1515650112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365173100052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, QS; Feng, TL; Tao, SY; Zhu, SJ; Yang, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Qingsen; Feng, Tanglue; Tao, Songyuan; Zhu, Shoujun; Yang, Bai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precursor-dependent structural diversity in luminescent carbonized polymer dots (CPDs): the nomenclature", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dots (CDs) have received immense attention in the last decade because they are easy-to-prepare, nontoxic, and tailorable carbon-based fluorescent nullomaterials. CDs can be categorized into three subgroups based on their morphology and chemical structure: graphene quantum dots (GQDs), carbon quantum dots (CQDs), and carbonized polymer dots (CPDs). The detailed structures of the materials can vary significantly, even within the same category. This property is particularly predominullt in chemically synthesized CPDs, as their formation proceeds via the polymerization-carbonization of molecules or polymer precursors. Abundant precursors endow CPDs with versatile structures and properties. A wide variety of carbon nullomaterials can be grouped under the category of CPDs because of their observed diversity. It is important to understand the precursor-dependent structural diversity observed in CPDs. Appropriate nomenclature for all classes and types of CPDs is proposed for the better utilization of these emerging materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1038/s41377-021-00579-6", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00579-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672411500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, JW; Li, GD; Zhu, HT; Chen, N; Lu, TB; Gao, JL; Guo, LW; Xiang, JS; Sun, PJ; Yao, Y; Yang, RG; Zhao, HZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jiawei; Li, Guodong; Zhu, Hangtian; Chen, null; Lu, Tianbo; Gao, Junling; Guo, Liwei; Xiang, Junsen; Sun, Peijie; Yao, Yuan; Yang, Ronggui; Zhao, Huaizhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Next-generation thermoelectric cooling modules based on high-performance Mg3(Bi,Sb)2 material", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the core component of any real thermoelectric cooling system, the Bi2Te3-based modules have been used for decades. Recently, n-type Mg-3(Bi,Sb)(2) material was proposed as a promising substitute for Bi2Te3. However, the fabrication of commercially viable modules with such new materials is challenging. Herein, full-scale cooling modules based on the optimized n-type Mg3.2Bi1.4975Sb0.5Te0.0025 and p-type (Sb0.75Bi0.25)(2)(Te0.97Se0.03)(3) were successfully fabricated. A maximum DT of 76 K with the hot-side temperature of 350 K, a COP of 8 with a temperature difference of 5 K, and a serving time >6 months were achieved. These were attributed to the enhanced stability and well secured n-type transport of the Mg3.2Bi1.4975Sb0.5Te0.0025, a highly reliable Mg2Cu barrier layer, and other key techniques involved in the module assembling. The most striking benefit of our modules lies in its 23% higher performance-cost ratio over commercial Bi2Te3 system, which paves its way for next-generation thermoelectric cooling applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2022, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": 204, "Article Number": null, "DOI": "10.1016/j.joule.2021.11.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.11.008", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745656500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Yang, HB; Lin, Y; Yuan, QB; Du, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Miao; Yang, Haibo; Lin, Ying; Yuan, Qinbin; Du, Hongliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Significant increase in comprehensive energy storage performance of potassium sodium niobate-based ceramics via synergistic optimization strategy", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "K0.5Na0.5NbO3 (KNN)-based ceramics are considered as one of the most promising lead-free dielectric ceramics owing to relatively high dielectric breakdown strength (DBS) resulted from their unique submicron grains. Unfortunately, it has been difficult to increase recoverable energy-storage density (W-rec) and energy-storage efficiency (eta) simultaneously at present. Herein, we propose a synergistic optimization strategy, namely, simultaneously enhancing DBS by tailoring grain size to submicron scale and inducing the temperature range between the maximum dielectric permittivity temperature (T-max ) and the Burns temperature (T-B) to room temperature, for solving the bottleneck. (1- x)K0.5Na0.5NbO3- xBi(Ni0.5Zr0.5)O-3(KNN-BNZ) ceramics were chosen as an example to illustrate the validity of this strategy. An ultrahigh W-rec of 8.09 J.cm(-3) was obtained at the optimum composition of x = 0.15 under the electric field of 870 kV .cm(-1), which is much higher than those of other reported KNNbased ceramics. Most importantly, this high W-rec was accompanied by a high eta of 88.46%, which is superior to those of other KNN-based ceramics and very important for practical applications. The excellent comprehensive energy storage performance was resulted from the polar nulloregions, which is confirmed by high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), piezo-force microscopy (PFM) and first order reversal curve (FORC) distributions. The work not only finds out novel KNN-based ceramics with excellent comprehensive energy storage properties, but also provides a remarkable designing strategy for exploring a series of novel lead-free dielectric ceramics with high energy storage properties for practical applications in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 45, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 861, "End Page": 868, "Article Number": null, "DOI": "10.1016/j.ensm.2021.12.037", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2021.12.037", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781812700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, BD; Lian, YX; Cui, LS; Divitini, G; Kusch, G; Ruggeri, E; Auras, F; Li, WW; Yang, DX; Zhu, BN; Oliver, RA; MacManus-Driscoll, JL; Stranks, SD; Di, DW; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Baodan; Lian, Yaxiao; Cui, Linsong; Divitini, Giorgio; Kusch, Gunnar; Ruggeri, Edoardo; Auras, Florian; Li, Weiwei; Yang, Dexin; Zhu, Bonull; Oliver, Rachel A.; MacManus-Driscoll, Judith L.; Stranks, Samuel D.; Di, Dawei; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient light-emitting diodes from mixed-dimensional perovskites on a fluoride interface", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-emitting diodes based on halide perovskites have recently reached external quantum efficiencies of over 20%. However, the performance of visible perovskite light-emitting diodes has been hindered by non-radiative recombination losses and limited options for charge-transport materials that are compatible with perovskite deposition. Here, we report efficient, green electroluminescence from mixed-dimensional perovskites deposited on a thin (similar to 1 nm) lithium fluoride layer on an organic semiconductor hole-transport layer. The highly polar dielectric interface acts as an effective template for forming high-quality bromide perovskites on otherwise incompatible hydrophobic charge-transport layers. The control of crystallinity and dimensionality of the perovskite layer is achieved by using tetraphenylphosphonium chloride as an additive, leading to external photoluminescence quantum efficiencies of around 65%. With this approach, we obtain light-emitting diodes with external quantum efficiencies of up to 19.1% at high brightness (>1,500 cd m(-2)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 704, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41928-020-00487-4", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-00487-4", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000580737500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, YN; Deng, XW; Li, QD; Zhang, GB; Xiong, FY; Tan, SS; Wei, QL; Lu, J; Li, JT; An, QY; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yanull; Deng, Xuanwei; Li, Qidong; Zhang, Guobin; Xiong, Fangyu; Tan, Shuangshuang; Wei, Qiulong; Lu, Jun; Li, Jiantao; An, Qinyou; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vanadium Oxide Pillared by Interlayer Mg2+ Ions and Water as Ultralong-Life Cathodes for Magnesium-Ion Batteries", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium-ion batteries (MIBs) show great potential for large-scale energy storage because of the advantages of low cost and safety, but their application is severely hindered by the difficulty in finding desirable electrode materials. Herein, we develop a bilayer-structured vanadium oxide (Mg0.3V2O5 center dot 1.1H(2)O) with synergistic effect of Mg2+ ions and lattice water as the cathode material for MIBs. The pre-intercalated Mg2+ ions provide high electronic conductivity and excellent structural stability. The lattice water enables fast Mg2+ ions mobility because of its charge shielding effect. As a result, the Mg0.3V2O5 center dot 1.1H(2)O exhibits excellent rate performance and an unprecedented cycling life with capacity retention of 80.0% after 10,000 cycles. In addition, the Mg0.3V2O5 center dot 1.1H(2)O exhibits good electrochemical performance in full MIBs. This scalable Mg2+ host material is a promising candidate as a cathode for MIBs, and its high performance is expected to meet the requirements for large-scale storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2019, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1194, "End Page": 1209, "Article Number": null, "DOI": "10.1016/j.chempr.2019.02.014", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.02.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467750100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, DT; Whitehead, J; Alfarra, MR; Reyes-Villegas, E; Spracklen, DV; Reddington, CL; Kong, SF; Williams, PI; Ting, YC; Haslett, S; Taylor, JW; Flynn, MJ; Morgan, WT; McFiggans, G; Coe, H; Allan, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dantong; Whitehead, James; Alfarra, M. Rami; Reyes-Villegas, Ernesto; Spracklen, Dominick V.; Reddington, Carly L.; Kong, Shaofei; Williams, Paul I.; Ting, Yu-Chieh; Haslett, Sophie; Taylor, Jonathan W.; Flynn, Michael J.; Morgan, William T.; McFiggans, Gordon; Coe, Hugh; Allan, James D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black-carbon absorption enhancement in the atmosphere determined by particle mixing state", "Source Title": "NATURE GEOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atmospheric black carbon makes an important but poorly quantified contribution to the warming of the global atmosphere. Laboratory and modelling studies have shown that the addition of non-black-carbon materials to black-carbon particles may enhance the particles' light absorption by 50 to 60% by refracting and reflecting light. Real-world experimental evidence for this 'lensing' effect is scant and conflicting, showing that absorption enhancements can be less than 5% or as large as 140%. Here we present simultaneous quantifications of the composition and optical properties of individual atmospheric black-carbon particles. We show that particles with a mass ratio of non-black carbon to black carbon of less than 1.5, which is typical of fresh traffic sources, are best represented as having no absorption enhancement. In contrast, black-carbon particles with a ratio greater than 3, which is typical of biomass-burning emissions, are best described assuming optical lensing leading to an absorption enhancement. We introduce a generalized hybrid model approach for estimating scattering and absorption enhancements based on laboratory and atmospheric observations. We conclude that the occurrence of the absorption enhancement of black-carbon particles is determined by the particles' mass ratio of non-black carbon to black carbon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 184, "End Page": "U132", "Article Number": null, "DOI": "10.1038/NGEO2901", "DOI Link": "http://dx.doi.org/10.1038/NGEO2901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395791400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chae, S; Ko, M; Kim, K; Ahn, K; Cho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chae, Sujong; Ko, Minseong; Kim, Kyungho; Ahn, Kihong; Cho, Jaephil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confronting Issues of the Practical Implementation of Si Anode in High-Energy Lithium-Ion Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over 20 years, Si has been investigated as a promising alternative to conventional graphite because of its high specific capacity and proper working voltage. As numerous strategies have demonstrated their improved electrochemical properties by addressing the intrinsic challenges of Si anode, the practical investigation with a full cell has been regarded as an important task to verify their feasibilities. In this Perspective, we discuss key issues in the practical implementation of the Si anode in the high-energy full cell. With the target of improvement in the volumetric energy density, the comprehensive overview of an electrochemical cell design for Si anodes is presented with its influence on electrochemical properties. Moreover, we highlight the electrode swelling issues and the capacity fading of the Si anode, which is pronounced in the full cell rather than in the half cell. Finally, we offer insights regarding the potential future directions in the development of the Si anode for high-energy lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2017, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 47, "End Page": 60, "Article Number": null, "DOI": "10.1016/j.joule.2017.07.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.07.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425179500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, ZK; Ke, CQ; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Zikai; Ke, Chunqiao; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Journey of Aggregation-Induced Emission Research", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly efficient luminescent materials in solid states are promising candidates for the development of organic optoelectrical materials and devices and chemical and biological sensors. Aggregation-induced emission (AIE), a novel photophyscial phenomena coined in 2001 where the aggregate formation enhances the light emission, has drawn great attention because it provides a fantastic platform for the development of these useful luminescent materials. After 17 years of AIE research, diverse AIE luminogens with tunable color and high quantum yields have been explored, which finds diverse applications from optics and electronics to energy and bioscience. Most importantly, the concept of AIE has gradually changed people's thinking way about the aggregation of luminogen and put forth a revolution of luminogen research both conceptually and technically. This perspective revisits our journey of AIE research, discusses our current understanding of the AIE mechanism, debates current challenges, and looks for the potential breakthroughs in this exciting research area.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3267, "End Page": 3277, "Article Number": null, "DOI": "10.1021/acsomega.8b00062", "DOI Link": "http://dx.doi.org/10.1021/acsomega.8b00062", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427939400088", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hojjatzadeh, SMH; Parab, ND; Yan, WT; Guo, QL; Xiong, LH; Zhao, C; Qu, ML; Escano, L; Xiao, XH; Fezzaa, K; Everhart, W; Sun, T; Chen, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hojjatzadeh, S. Mohammad H.; Parab, Niranjan D.; Yan, Wentao; Guo, Qilin; Xiong, Lianghua; Zhao, Cang; Qu, Minglei; Escano, Luis, I; Xiao, Xianghui; Fezzaa, Kamel; Everhart, Wes; Sun, Tao; Chen, Lianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore elimination mechanisms during 3D printing of metals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser powder bed fusion (LPBF) is a 3D printing technology that can print metal parts with complex geometries without the design constraints of traditional manufacturing routes. However, the parts printed by LPBF normally contain many more pores than those made by conventional methods, which severely deteriorates their properties. Here, by combining in-situ high-speed high-resolution synchrotron x-ray imaging experiments and multi-physics modeling, we unveil the dynamics and mechanisms of pore motion and elimination in the LPBF process. We find that the high thermocapillary force, induced by the high temperature gradient in the laser interaction region, can rapidly eliminate pores from the melt pool during the LPBF process. The thermocapillary force driven pore elimination mechanism revealed here may guide the development of 3D printing approaches to achieve pore-free 3D printing of metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3088, "DOI": "10.1038/s41467-019-10973-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10973-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475295300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neto, EHD; Aynajian, P; Frano, A; Comin, R; Schierle, E; Weschke, E; Gyenis, A; Wen, JS; Schneeloch, J; Xu, ZJ; Ono, S; Gu, GD; Le Tacon, M; Yazdani, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "da Silva Neto, Eduardo H.; Aynajian, Pegor; Frano, Alex; Comin, Riccardo; Schierle, Enrico; Weschke, Eugen; Gyenis, Andras; Wen, Jinsheng; Schneeloch, John; Xu, Zhijun; Ono, Shimpei; Gu, Genda; Le Tacon, Mathieu; Yazdani, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ubiquitous Interplay Between Charge Ordering and High-Temperature Superconductivity in Cuprates", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Besides superconductivity, copper-oxide high-temperature superconductors are susceptible to other types of ordering. We used scanning tunneling microscopy and resonullt elastic x-ray scattering measurements to establish the formation of charge ordering in the high-temperature superconductor Bi2Sr2CaCu2O8+x. Depending on the hole concentration, the charge ordering in this system occurs with the same period as those found in Y-based or La-based cuprates and displays the analogous competition with superconductivity. These results indicate the similarity of charge organization competing with superconductivity across different families of cuprates. We observed this charge ordering to leave a distinct electron-hole asymmetric signature (and a broad resonullce centered at +20 milli-electron volts) in spectroscopic measurements, indicating that it is likely related to the organization of holes in a doped Mott insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 545, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2014, "Volume": 343, "Issue": 6169, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 393, "End Page": 396, "Article Number": null, "DOI": "10.1126/science.1243479", "DOI Link": "http://dx.doi.org/10.1126/science.1243479", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330039300041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Bampoulis, P; Rudenko, AN; Yao, Q; van Houselt, A; Poelsema, B; Katsnelson, MI; Zandvliet, HJW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, L.; Bampoulis, P.; Rudenko, A. N.; Yao, Q.; van Houselt, A.; Poelsema, B.; Katsnelson, M. I.; Zandvliet, H. J. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural and Electronic Properties of Germanene on MoS2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date germanene has only been synthesized on metallic substrates. A metallic substrate is usually detrimental for the two-dimensional Dirac nature of germanene because the important electronic states near the Fermi level of germanene can hybridize with the electronic states of the metallic substrate. Here we report the successful synthesis of germanene on molybdenum disulfide (MoS2), a band gap material. Preexisting defects in the MoS2 surface act as preferential nucleation sites for the germanene islands. The lattice constant of the germanene layer (3.8 +/- 0.2 angstrom) is about 20% larger than the lattice constant of the MoS2 substrate (3.16 angstrom). Scanning tunneling spectroscopy measurements and density functional theory calculations reveal that there are, besides the linearly dispersing bands at the K points, two parabolic bands that cross the Fermi level at the G point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2016, "Volume": 116, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 256804, "DOI": "10.1103/PhysRevLett.116.256804", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.256804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378209900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, YA; Chang, YL; Lu, K; Chen, ZH; Zhang, JQ; Yan, YJ; Qiu, DD; Liu, YA; Adil, MA; Ma, W; Hao, XT; Zhu, LY; Wei, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yanull; Chang, Yilin; Lu, Kun; Chen, Zhihao; Zhang, Jianqi; Yan, Yangjun; Qiu, Dingding; Liu, Yanull; Adil, Muhammad Abdullah; Ma, Wei; Hao, Xiaotao; Zhu, Lingyun; Wei, Zhixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Small reorganization energy acceptors enable low energy losses in non-fullerene organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Minimizing energy loss is of critical importance in the pursuit of attaining high-performance organic solar cells. Interestingly, reorganization energy plays a crucial role in photoelectric conversion processes. However, the understanding of the relationship between reorganization energy and energy losses has rarely been studied. Here, two acceptors, Qx-1 and Qx-2, were developed. The reorganization energies of these two acceptors during photoelectric conversion processes are substantially smaller than the conventional Y6 acceptor, which is beneficial for improving the exciton lifetime and diffusion length, promoting charge transport, and reducing the energy loss originating from exciton dissociation and non-radiative recombination. So, a high efficiency of 18.2% with high open circuit voltage above 0.93 V in the PM6:Qx-2 blend, accompanies a significantly reduced energy loss of 0.48 eV. This work underlines the importance of the reorganization energy in achieving small energy losses and paves a way to obtain high-performance organic solar cells. Minimising energy loss is important for achieving high-performance organic solar cells. Here, the authors design and synthesise two acceptors with small reorganisation energies and reveal the relationship between reorganisation energy and energy losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3256, "DOI": "10.1038/s41467-022-30927-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30927-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808128800053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, GR; Zhang, Q; Liu, QS; Bai, QY; Quan, YZ; Gao, Y; Wu, G; Wang, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Guo-Rui; Zhang, Qin; Liu, Qing-Song; Bai, Qi-Yao; Quan, Yi-Zhou; Gao, You; Wu, Gang; Wang, Yu-Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a replacement for highly flammable and volatile organic liquid electrolyte, solid polymer electrolyte shows attractive practical prospect in high-energy lithium metal batteries. However, unsatisfied interface performance and ionic conductivities are two critical challenges. A common strategy involves introducing organic solvents or plasticizers, but this violates the original intention of security design. Here, an electrolyte concept called liquid polymer electrolyte without any small molecular solvents is proposed for safe and highperformance batteries, based on the design of a room-temperature liquid state brush-like polymer as the sole solvent of lithium salts. This liquid polymer electrolyte is non-flammable and exhibits high ionic conductivity (1.09 x 10(-4)S cm(-1) at 25 degrees C), significant lithium dendrite suppression, and stable longterm cycling over a wide operating temperature range ( = 1000 cycles at 60 degrees C and 90 degrees C). Moreover, the pouch cell can resist thermal abuse, vacuum environment, and mechanical abuse. This electrolyte and design strategy are expected to provide enlightening ideas for the development of safe and highperformance polymer electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4617, "DOI": "10.1038/s41467-023-40394-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40394-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001048667500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, YS; Kim, JH; Xie, ZQ; Cho, S; Han, H; Jeon, SW; Park, M; Namkoong, M; Avila, R; Song, Z; Lee, SU; Ko, K; Lee, J; Lee, JS; Min, WG; Lee, BJ; Choi, M; Chung, H; Kim, J; Han, MD; Koo, J; Choi, YS; Kwak, SS; Kim, SB; Kim, J; Choi, J; Kang, CM; Kim, JU; Kwon, K; Won, SM; Baek, JM; Lee, Y; Kim, SY; Lu, W; Vazquez-Guardado, A; Jeong, H; Ryu, H; Lee, G; Kim, K; Kim, S; Kim, MS; Choi, J; Choi, DY; Yang, QS; Zhao, HB; Bai, WB; Jang, H; Yu, Y; Lim, J; Guo, X; Kim, BH; Jeon, S; Davies, C; Banks, A; Sung, HJ; Huang, Y; Park, I; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Yong Suk; Kim, Jae-Hwan; Xie, Zhaoqian; Cho, Seokjoo; Han, Hyeonseok; Jeon, Sung Woo; Park, Minsu; Namkoong, Myeong; Avila, Raudel; Song, Zhen; Lee, Sung-Uk; Ko, Kabseok; Lee, Jungyup; Lee, Je-Sang; Min, Weon Gi; Lee, Byeong-Ju; Choi, Myungwoo; Chung, Ha Uk; Kim, Jongwon; Han, Mengdi; Koo, Jahyun; Choi, Yeon Sik; Kwak, Sung Soo; Kim, Sung Bong; Kim, Jeonghyun; Choi, Jungil; Kang, Chang-Mo; Kim, Jong Uk; Kwon, Kyeongha; Won, Sang Min; Baek, Janice Mihyun; Lee, Yujin; Kim, So Young; Lu, Wei; Vazquez-Guardado, Abraham; Jeong, Hyoyoung; Ryu, Hanjun; Lee, Geumbee; Kim, Kyuyoung; Kim, Seunghwan; Kim, Min Seong; Choi, Jungrak; Choi, Dong Yun; Yang, Quansan; Zhao, Hangbo; Bai, Wubin; Jang, Hokyung; Yu, Yongjoon; Lim, Jaeman; Guo, Xu; Kim, Bong Hoon; Jeon, Seokwoo; Davies, Charles; Banks, Anthony; Sung, Hyung Jin; Huang, Yonggang; Park, Inkyu; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Battery-free, wireless soft sensors for continuous multi-site measurements of pressure and temperature from patients at risk for pressure injuries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Capabilities for continuous monitoring of pressures and temperatures at critical skin interfaces can help to guide care strategies that minimize the potential for pressure injuries in hospitalized patients or in individuals confined to the bed. This paper introduces a soft, skin-mountable class of sensor system for this purpose. The design includes a pressure-responsive element based on membrane deflection and a battery-free, wireless mode of operation capable of multi-site measurements at strategic locations across the body. Such devices yield continuous, simultaneous readings of pressure and temperature in a sequential readout scheme from a pair of primary antennas mounted under the bedding and connected to a wireless reader and a multiplexer located at the bedside. Experimental evaluation of the sensor and the complete system includes benchtop measurements and numerical simulations of the key features. Clinical trials involving two hemiplegic patients and a tetraplegic patient demonstrate the feasibility, functionality and long-term stability of this technology in operating hospital settings. Uninterrupted monitoring of pressure and temperature at skin interfaces can help to minimize the potential for pressure injuries in hospitalized or bedridden patients. Here, the authors introduce a soft, skin-mountable sensor that can continuously provide readings via antennas mounted under bedding, and demonstrate the functionality and robustness of the devices on patients.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5008, "DOI": "10.1038/s41467-021-25324-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25324-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000688006200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, TC; Sun, QC; Anderson, E; Wang, C; Qian, JM; Taniguchi, T; Watanabe, K; McGuire, MA; Stöhr, R; Xiao, D; Cao, T; Wrachtrup, J; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Tiancheng; Sun, Qi-Chao; Anderson, Eric; Wang, Chong; Qian, Jimin; Taniguchi, Takashi; Watanabe, Kenji; McGuire, Michael A.; Stohr, Rainer; Xiao, Di; Cao, Ting; Wrachtrup, Jorg; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct visualization of magnetic domains and moire magnetism in twisted 2D magnets", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moire superlattices of twisted nonmagnetic two-dimensional (2D) materials are highly controllable platforms for the engineering of exotic correlated and topological states. Here, we report emerging magnetic textures in small-angle twisted 2D magnet chromium triiodide (CrI3). Using single-spin quantum magnetometry, we directly visualized nulloscale magnetic domains and periodic patterns, a signature of moire magnetism, and measured domain size and magnetization. In twisted bilayer CrI3, we observed the coexistence of antiferromagnetic (AFM) and ferromagnetic (FM) domains with disorder-like spatial patterns. In twisted double-trilayer CrI3, AFM and FM domains with periodic patterns appear, which is in good agreement with the calculated spatial magnetic structures that arise from the local stacking-dependent interlayer exchange interactions in CrI3 moire superlattices. Our results highlight magnetic moire superlattices as a platform for exploring nullomagnetism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2021, "Volume": 374, "Issue": 6571, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1140, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj7478", "DOI Link": "http://dx.doi.org/10.1126/science.abj7478", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000725668600048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, HS; Nong, HN; Reier, T; Gliech, M; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Hyung-Suk; Nong, Hong Nhan; Reier, Tobias; Gliech, Manuel; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxide-supported Ir nullodendrites with high activity and durability for the oxygen evolution reaction in acid PEM water electrolyzers", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing the noble-metal catalyst content of acid Polymer Electrolyte Membrane (PEM) water electrolyzers without compromising catalytic activity and stability is a goal of fundamental scientific interest and substantial technical importance for cost-effective hydrogen-based energy storage. This study presents nullostructured iridium nullodendrites (Ir-ND) supported on antimony doped tin oxide (ATO) as efficient and stable water splitting catalysts for PEM electrolyzers. The active Ir-ND structures exhibited superior structural and morphological properties, such as particle size and surface area compared to commercial state-of-art Ir catalysts. Supported on tailored corrosion-stable conductive oxides, the Ir-ND catalysts exhibited a more than 2-fold larger kinetic water splitting activity compared with supported Ir nulloparticles, and a more than 8-fold larger catalytic activity than commercial Ir blacks. In single-cell PEM electrolyzer tests, the Ir-ND/ATO outperformed commercial Ir catalysts more than 2-fold at technological current densities of 1.5 A cm(-2) at a mere 1.80 V cell voltage, while showing excellent durability under constant current conditions. We conclude that Ir-ND/ATO catalysts have the potential to substantially reduce the required noble metal loading, while maintaining their catalytic performance, both in idealized three-electrode set ups and in the real electrolyzer device environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3321, "End Page": 3328, "Article Number": null, "DOI": "10.1039/c5sc00518c", "DOI Link": "http://dx.doi.org/10.1039/c5sc00518c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354815600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, CH; Wu, Y; Sun, KA; Fang, JJ; Huang, AJ; Pan, Y; Cheong, WO; Zhuang, ZW; Zhuang, ZB; Yuan, QH; Xin, HL; Zhang, C; Zhang, JW; Xiao, H; Chen, C; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chuhao; Wu, Yue; Sun, Kaian; Fang, Jinjie; Huang, Aijian; Pan, Yuan; Cheong, Weng-Chon; Zhuang, Zewen; Zhuang, Zhongbin; Yuan, Qiuhua; Xin, Huolin L.; Zhang, Chao; Zhang, Jiangwei; Xiao, Hai; Chen, Chen; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed Fe-N-C catalyst has shown great performance in the CO2-to-CO conversion, yet the high CO selectivity is achieved only within a rather narrow potential range, which cannot well meet the requirements for the following CO dimerization or hydrogenation. Here, we developed a hydrogen-pyrolysis etching strategy to precisely manipulate the uncoordinated N dopants in the Fe-N-C catalyst. This strategy could preferentially eliminate pyridinic and pyrrolic N atoms while leaving graphitic N. The resulting catalyst gave a CO faradaic efficiency (FECO) above 90% over a broad window from -0.3 to -0.8 V (versus RHE) (in particular, FECO > 97% at -0.6 V). In situ ATR-SEIRAS and first-principle calculations further revealed that this strategy can not only suppress the parasitic H-2 generation but also promote CO2 activation and protonation with the assistance of co-adsorbed H2O on the atomic interface'' of FeN4/graphitic N.''", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2021, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2021.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2021.02.001", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652330400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XH; Zhao, CC; Zhou, X; Shen, ZJ; Liu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xihe; Zhao, Congcong; Zhou, Xin; Shen, Zhijian; Liu, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure of selective laser melted AlSi10Mg alloy", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The influence of laser power during selective laser melting (SLM) on the grain morphology and texture component in AlSi10Mg alloy has been investigated, using electron backscattered diffraction (EBSD). Both equiaxed and columnar grainswere observed. The formation of equiaxed grainswas attributed to the huge thermal gradient on the border of melt pool and the columnar to equiaxed transition (CET) occurred in front of the columnar grains. The grain size of lowlaser power samplewas found smaller than that of higher ones. A fine pseudoeutectic structure, in which Si existed as fibrous, was observed because of the high cooling rate. This paper, from a new angle, explained the formations of three different zones across the melt pool, which were differentiated by the morphology of Si phase. The three zones correspond to the three temperature zones, whichwere divided by liquidus and solidus temperature, during the heating by laser beam. The coarse zones are formed by reheating the basic metal to semi-solid state when the temperature is lower than the liquidus temperature but higher than the solidus temperature. (c) 2019 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2019, "Volume": 168, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107677, "DOI": "10.1016/j.matdes.2019.107677", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2019.107677", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460664500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, S; Yang, MX; Jiang, P; Wang, J; Wu, XL; Zhou, H; Yuan, FP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Shuang; Yang, Muxin; Jiang, Ping; Wang, Jian; Wu, Xiaolei; Zhou, Hao; Yuan, Fuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing structures with combined gradients of grain size and precipitation in high entropy alloys for simultaneous improvement of strength and ductility", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Suppressing the early strain localization at the nullostructured topmost layer is crucial for achieving better tensile ductility in the gradient structure. Thus, structures with combined gradient distributions along the depth for both grain size and volume fraction of precipitates were designed and introduced in a high entropy alloy by surface mechanical attrition treatment and aging. Yield strength and uniform elongation were observed to be simultaneously improved in the structures with combined gradients as compared to the corresponding structures with only grain size gradient. More severe strain gradients and higher density of geometrically necessary dislocations were observed to be produced at various domain boundaries in the structures with combined gradients, resulting in stronger hetero-deformation-induced (HDI) extra hardening for better tensile properties. Shearing and bowing hardening mechanisms were observed for L1( 2) and B2 precipitates, respectively. Higher volume fractions of B2 and L1( 2) phases at the topmost layer induce stronger precipitation hardening, which compensates the diminished strain hardening due to the reduced grain size at the topmost layer for better tensile ductility in the structures with combined gradients. The observed higher yield strength in the structures with combined gradients have been discussed based on mechanisms of dislocation strengthening, precipitation strengthening and HDI strengthening. (C)& nbsp;2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.& nbsp;", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2022, "Volume": 230, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 117847, "DOI": "10.1016/j.actamat.2022.117847", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2022.117847", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791271900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Latimer, AA; Kakekhani, A; Kulkarni, AR; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Latimer, Allegra A.; Kakekhani, Arvin; Kulkarni, Ambarish R.; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct Methane to Methanol: The Selectivity-Conversion Limit and Design Strategies", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, methane is transformed into methanol through the two-step syngas process, which requires high temperatures and centralized production. While the slightly exothermic direct partial oxidation of methane to methanol would be preferable, no such process has been established despite over a century of research. Generally, this failure has been attributed to both the high barriers required to activate methane as well as the higher activity of the CH bonds in methanol compared to those in methane. However, a precise and general quantification of the limitations of catalytic direct methane to methanol has yet to be established. Herein, we present a simple kinetic model to explain the selectivity-conversion trade-off that hampers continuous partial oxidation of methane to methanol. For the same kinetic model, we apply two distinct methods, (1) using ab initio calculations and (2) fitting to a large experimental database, to fully define the model parameters. We find that both methods yield strikingly similar results, namely, that the selectivity of methane to methanol in a direct, continuous process can be fully described by the methane conversion, the temperature, and a catalyst-independent difference in methane and methanol activation free energies, Delta G(a), which is dictated by the relative reactivity of the C-H bonds in methane and methanol. Stemming from this analysis, we suggest several design strategies for increasing methanol yields under the constraint of constant Delta G(a). These strategies include (1) collectors, materials with strong methanol adsorption potential that can help to lower the partial pressure of methanol in the gas phase, (2) aqueous reaction conditions, and/or (3) diffusion-limited systems. By using this simple model to successfully rationalize a representative library of experimental studies from the diverse fields of heterogeneous, homogeneous, biological, and gas-phase methane to methanol catalysis, we underscore the idea that continuous methane to methanol is generally limited and provide a framework for understanding and evaluating new catalysts and processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6894, "End Page": 6907, "Article Number": null, "DOI": "10.1021/acscatal.8b00220", "DOI Link": "http://dx.doi.org/10.1021/acscatal.8b00220", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441112400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HQ; Wang, G; Zhang, ZM; Lei, JH; Liu, TM; Xing, GC; Deng, CX; Tang, ZK; Qu, SN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Huiqi; Wang, Gang; Zhang, Zhiming; Lei, Josh Haipeng; Liu, Tzu-Ming; Xing, Guichuan; Deng, Chu-Xia; Tang, Zikang; Qu, Songnull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One step synthesis of efficient red emissive carbon dots and their bovine serum albumin composites with enhanced multi-photon fluorescence for in vivo bioimaging", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient red emissive carbon dots (CDs) in aqueous solutions are very scarce for high performance bioimaging applications. In this work, we report a one-step solvothermal treatment to synthesize pure red emissive CDs (FA-CDs) from citric acid and urea in formic acid without complicated purification procedures. Photoluminescence quantum yield (PLQY) of 43.4% was observed in their dimethyl sulfoxide solutions. High PLQY up to 21.9% in aqueous solutions was achieved in their bovine serum albumin (BSA) composites (FA-CDs@BSA) with significantly enhanced multi-photon fluorescence. The strong surface electron-withdrawing structure of FA-CDs caused by the high content of C = O groups contributes for their pure red emission. Owing to the significantly enhanced single and multi-photon red fluorescence and enlarged particle sizes after composing with BSA, in vivo tumor imaging and two-photon fluorescence imaging of blood vessels in mouse ear have been realized via intravenous injection of FA-CDs@BSA aqueous solutions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113, "DOI": "10.1038/s41377-022-00798-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00798-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788327300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hage, FS; Radtke, G; Kepaptsoglou, DM; Lazzeri, M; Ramasse, QM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hage, F. S.; Radtke, G.; Kepaptsoglou, D. M.; Lazzeri, M.; Ramasse, Q. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom vibrational spectroscopy in the scanning transmission electron microscope", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom impurities and other atomic-scale defects can notably alter the local vibrational responses of solids and, ultimately, their macroscopic properties. Using high-resolution electron energy-loss spectroscopy in the electron microscope, we show that a single substitutional silicon impurity in graphene induces a characteristic, localized modification of the vibrational response. Extensive ab initio calculations reveal that the measured spectroscopic signature arises from defect-induced pseudo-localized phonon modes-that is, resonullt states resulting from the hybridization of the defect modes and the bulk continuum-with energies that can be directly matched to the experiments. This finding realizes the promise of vibrational spectroscopy in the electron microscope with single-atom sensitivity and has broad implications across the fields of physics, chemistry, and materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2020, "Volume": 367, "Issue": 6482, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1124, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba1136", "DOI Link": "http://dx.doi.org/10.1126/science.aba1136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520018400040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Wang, ZH; Li, L; Fan, YX; Tao, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huan; Wang, Zhi-Hang; Li, Lin; Fan, Ya-Xian; Tao, Zhi-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vanadium dioxide-assisted broadband tunable terahertz metamaterial absorber", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tunable terahertz (THz) functional devices have exhibited superior performances due to the use of active materials, such as liquid crystals, graphene, and semiconductors. However, the tunable range of constitutive parameters of materials is still limited, which leads to the low modulation depth of THz devices. Here, we demonstrate a broadband tunable THz absorber based on hybrid vanadium dioxide (VO2) metamaterials. Unlike other phase change materials, VO2 exhibits an insulator-to-metal transition characteristic and the conductivity can be increased by 4-5 orders of magnitude under external stimulus including electric fields, optical, and thermal pumps. Based on the unique transition character of VO2, the maximum tunable range of the proposed absorber can be realized from 5% to 100% by an external thermal excitation. Meanwhile, an absorption greater than 80% in a continuous range with a bandwidth about 2.0 THz can be obtained when VO2 is in its metal phase at high temperature. Furthermore, the absorber is insensitive to the incident angle up to 50 degrees and such a broadband THz absorber can be used in applications including imaging, modulating, cloaking, and so on.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5751, "DOI": "10.1038/s41598-019-42293-9", "DOI Link": "http://dx.doi.org/10.1038/s41598-019-42293-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463695800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, CH; Kim, J; Utama, MIB; Regan, EC; Kleemann, H; Cai, H; Shen, YX; Shinner, MJ; Sengupta, A; Watanabe, K; Taniguchi, T; Tongay, S; Zettl, A; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Chenhao; Kim, Jonghwan; Utama, M. Iqbal Bakti; Regan, Emma C.; Kleemann, Hans; Cai, Hui; Shen, Yuxia; Shinner, Matthew James; Sengupta, Arjun; Watanabe, Kenji; Taniguchi, Takashi; Tongay, Sefaattin; Zettl, Alex; Wang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imaging of pure spin-valley diffusion current in WS2-WSe2 heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dichalcogenide (TMDC) materials are promising for spintronic and valleytronic applications because valley-polarized excitations can be generated and manipulated with circularly polarized photons and the valley and spin degrees of freedom are locked by strong spin-orbital interactions. In this study we demonstrate efficient generation of a pure and locked spin-valley diffusion current in tungsten disulfide (WS2)-tungsten diselenide (WSe2) heterostructures without any driving electric field. We imaged the propagation of valley current in real time and space by pump-probe spectroscopy. The valley current in the heterostructures can live for more than 20 microseconds and propagate over 20 micrometers; both the lifetime and the diffusion length can be controlled through electrostatic gating. The high-efficiency and electric-field-free generation of a locked spin-valley current in TMDC heterostructures holds promise for applications in spin and valley devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2018, "Volume": 360, "Issue": 6391, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 893, "End Page": 896, "Article Number": null, "DOI": "10.1126/science.aao3503", "DOI Link": "http://dx.doi.org/10.1126/science.aao3503", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433039800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Basharin, AA; Kafesaki, M; Economou, EN; Soukoulis, CM; Fedotov, VA; Savinov, V; Zheludev, NI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Basharin, Alexey A.; Kafesaki, Maria; Economou, Eleftherios N.; Soukoulis, Costas M.; Fedotov, Vassili A.; Savinov, Vassili; Zheludev, Nikolay I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dielectric Metamaterials with Toroidal Dipolar Response", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Toroidal multipoles are the terms missing in the standard multipole expansion; they are usually overlooked due to their relatively weak coupling to the electromagnetic fields. Here, we propose and theoretically study all-dielectric metamaterials of a special class that represent a simple electromagnetic system supporting toroidal dipolar excitations in the THz part of the spectrum. We show that resonullt transmission and reflection of such metamaterials is dominated by toroidal dipole scattering, the neglect of which would result in a misunderstanding interpretation of the metamaterials' macroscopic response. Because of the unique field configuration of the toroidal mode, the proposed metamaterials could serve as a platform for sensing or enhancement of light absorption and optical nonlinearities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11036, "DOI": "10.1103/PhysRevX.5.011036", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.011036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351735100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khan, I; Saeed, K; Zekker, I; Zhang, BL; Hendi, AH; Ahmad, A; Ahmad, S; Zada, N; Ahmad, H; Shah, LA; Shah, TR; Khan, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khan, Idrees; Saeed, Khalid; Zekker, Ivar; Zhang, Baoliang; Hendi, Abdulmajeed H.; Ahmad, Ashfaq; Ahmad, Shujaat; Zada, Noor; Ahmad, Hanif; Shah, Luqman Ali; Shah, Tariq; Khan, Ibrahim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Review on Methylene Blue: Its Properties, Uses, Toxicity and Photodegradation", "Source Title": "WATER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The unavailability of clean drinking water is one of the significant health issues in modern times. Industrial dyes are one of the dominullt chemicals that make water unfit for drinking. Among these dyes, methylene blue (MB) is toxic, carcinogenic, and non-biodegradable and can cause a severe threat to human health and environmental safety. It is usually released in natural water sources, which becomes a health threat to human beings and living organisms. Hence, there is a need to develop an environmentally friendly, efficient technology for removing MB from wastewater. Photodegradation is an advanced oxidation process widely used for MB removal. It has the advantages of complete mineralization of dye into simple and nontoxic species with the potential to decrease the processing cost. This review provides a tutorial basis for the readers working in the dye degradation research area. We not only covered the basic principles of the process but also provided a wide range of previously published work on advanced photocatalytic systems (single-component and multi-component photocatalysts). Our study has focused on critical parameters that can affect the photodegradation rate of MB, such as photocatalyst type and loading, irradiation reaction time, pH of reaction media, initial concentration of dye, radical scavengers and oxidising agents. The photodegradation mechanism, reaction pathways, intermediate products, and final products of MB are also summarized. An overview of the future perspectives to utilize MB at an industrial scale is also provided. This paper identifies strategies for the development of effective MB photodegradation systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 799, "Times Cited, All Databases": 813, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 242, "DOI": "10.3390/w14020242", "DOI Link": "http://dx.doi.org/10.3390/w14020242", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747131200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reilly, AM; Cooper, RI; Adjiman, CS; Bhattacharya, S; Boese, AD; Brandenburg, JG; Bygrave, PJ; Bylsma, R; Campbell, JE; Car, R; Case, DH; Chadha, R; Cole, JC; Cosburn, K; Cuppen, HM; Curtis, F; Day, GM; DiStasio, RA; Dzyabchenko, A; van Eijck, BP; Elking, DM; van den Ende, JA; Facelli, JC; Ferraro, MB; Fusti-Molnar, L; Gatsiou, CA; Gee, TS; de Gelder, R; Ghiringhelli, LM; Goto, H; Grimme, S; Guo, R; Hofmann, DWM; Hoja, J; Hylton, RK; Iuzzolino, L; Jankiewicz, W; de Jong, DT; Kendrick, J; de Klerk, NJJ; Ko, HY; Kuleshova, LN; Li, XY; Lohani, S; Leusen, FJJ; Lund, AM; Lv, J; Ma, YM; Marom, N; Masunov, AE; McCabe, P; McMahon, DP; Meekes, H; Metz, MP; Misquitta, AJ; Mohamed, S; Monserrat, B; Needs, RJ; Neumann, MA; Nyman, J; Obata, S; Oberhofer, H; Oganov, AR; Orendt, AM; Pagola, GI; Pantelides, CC; Pickard, CJ; Podeszwa, R; Price, LS; Price, SL; Pulido, A; Read, MG; Reuter, K; Schneider, E; Schober, C; Shields, GP; Singh, P; Sugden, IJ; Szalewicz, K; Taylor, CR; Tkatchenko, A; Tuckerman, ME; Vacarro, F; Vasileiadis, M; Vazquez-Mayagoitia, A; Vogt, L; Wang, YC; Watson, RE; de Wijs, GA; Yang, J; Zhu, Q; Groom, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reilly, Anthony M.; Cooper, Richard I.; Adjiman, Claire S.; Bhattacharya, Saswata; Boese, A. Daniel; Brandenburg, Jan Gerit; Bygrave, Peter J.; Bylsma, Rita; Campbell, Josh E.; Car, Roberto; Case, David H.; Chadha, Renu; Cole, Jason C.; Cosburn, Katherine; Cuppen, Herma M.; Curtis, Farren; Day, Graeme M.; DiStasio, Robert A.; Dzyabchenko, Alexander; van Eijck, Bouke P.; Elking, Dennis M.; van den Ende, Joost A.; Facelli, Julio C.; Ferraro, Marta B.; Fusti-Molnar, Laszlo; Gatsiou, Christina-Anna; Gee, Thomas S.; de Gelder, Rene; Ghiringhelli, Luca M.; Goto, Hitoshi; Grimme, Stefan; Guo, Rui; Hofmann, Detlef W. M.; Hoja, Johannes; Hylton, Rebecca K.; Iuzzolino, Luca; Jankiewicz, Wojciech; de Jong, Daniel T.; Kendrick, John; de Klerk, Niek J. J.; Ko, Hsin-Yu; Kuleshova, Liudmila N.; Li, Xiayue; Lohani, Sanjaya; Leusen, Frank J. J.; Lund, Albert M.; Lv, Jian; Ma, Yanming; Marom, Noa; Masunov, Artem E.; McCabe, Patrick; McMahon, David P.; Meekes, Hugo; Metz, Michael P.; Misquitta, Alston J.; Mohamed, Sharmarke; Monserrat, Bartomeu; Needs, Richard J.; Neumann, Marcus A.; Nyman, Jonas; Obata, Shigeaki; Oberhofer, Harald; Oganov, Artem R.; Orendt, Anita M.; Pagola, Gabriel I.; Pantelides, Constantinos C.; Pickard, Chris J.; Podeszwa, Rafal; Price, Louise S.; Price, Sarah L.; Pulido, Angeles; Read, Murray G.; Reuter, Karsten; Schneider, Elia; Schober, Christoph; Shields, Gregory P.; Singh, Pawanpreet; Sugden, Isaac J.; Szalewicz, Krzysztof; Taylor, Christopher R.; Tkatchenko, Alexandre; Tuckerman, Mark E.; Vacarro, Francesca; Vasileiadis, Manolis; Vazquez-Mayagoitia, Alvaro; Vogt, Leslie; Wang, Yanchao; Watson, Rona E.; de Wijs, Gilles A.; Yang, Jack; Zhu, Qiang; Groom, Colin R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Report on the sixth blind test of organic crystal structure prediction methods", "Source Title": "ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sixth blind test of organic crystal structure prediction (CSP) methods has been held, with five target systems: a small nearly rigid molecule, a polymorphic former drug candidate, a chloride salt hydrate, a co-crystal and a bulky flexible molecule. This blind test has seen substantial growth in the number of participants, with the broad range of prediction methods giving a unique insight into the state of the art in the field. Significant progress has been seen in treating flexible molecules, usage of hierarchical approaches to ranking structures, the application of density-functional approximations, and the establishment of new workflows and 'best practices' for performing CSP calculations. All of the targets, apart from a single potentially disordered Z' = 2 polymorph of the drug candidate, were predicted by at least one submission. Despite many remaining challenges, it is clear that CSP methods are becoming more applicable to a wider range of real systems, including salts, hydrates and larger flexible molecules. The results also highlight the potential for CSP calculations to complement and augment experimental studies of organic solid forms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 535, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 72, "Issue": null, "Part Number": 4, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 439, "End Page": 459, "Article Number": null, "DOI": "10.1107/S2052520616007447", "DOI Link": "http://dx.doi.org/10.1107/S2052520616007447", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Crystallography", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380772000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, LJ; Jin, R; Zhou, CB; Li, GH; Xu, L; Overvig, A; Deng, F; Chen, XS; Lu, W; Alu, A; Miroshnichenko, AE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Lujun; Jin, Rong; Zhou, Chaobiao; Li, Guanhai; Xu, Lei; Overvig, Adam; Deng, Fu; Chen, Xiaoshuang; Lu, Wei; Alu, Andrea; Miroshnichenko, Andrey E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-Q guided mode resonullces in an All-dielectric metasurface", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High quality(Q) factor optical resonators are indispensable for many photonic devices. While very large Q-factors can be obtained theoretically in guided-mode settings, free-space implementations suffer from various limitations on the narrowest linewidth in real experiments. Here, we propose a simple strategy to enable ultrahigh-Q guided-mode resonullces by introducing a patterned perturbation layer on top of a multilayer-waveguide system. We demonstrate that the associated Q-factors are inversely proportional to the perturbation squared while the resonullt wavelength can be tuned through material or structural parameters. We experimentally demonstrate such high-Q resonullces at telecom wavelengths by patterning a low-index layer on top of a 220 nm silicon on insulator substrate. The measurements show Q-factors up to 2.39 x 10(5), comparable to the largest Q-factor obtained by topological engineering, while the resonullt wavelength is tuned by varying the lattice constant of the top perturbation layer. Our results hold great promise for exciting applications like sensors and filters. The authors report a simple strategy to enable ultrahigh-Q guided-mode resonullces by introducing a patterned perturbation layer on top of a multilayer-waveguide system. Such high-Q resonullces are experimentally demonstrated with measured Q-factors up to 2.4 x 10(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3433, "DOI": "10.1038/s41467-023-39227-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39227-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001003866300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Poulose, AC; Zoppellaro, G; Konidakis, I; Serpetzoglou, E; Stratakis, E; Tomanec, O; Beller, M; Bakandritsos, A; Zboril, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Poulose, Aby Cheruvathoor; Zoppellaro, Giorgio; Konidakis, Ioannis; Serpetzoglou, Efthymis; Stratakis, Emmanuel; Tomanec, Ondrej; Beller, Matthias; Bakandritsos, Aristides; Zboril, Radek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and selective reduction of nitroarenes under visible light with an earth-abundant plasmonic photocatalyst", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A low-cost plasmonic photocatalyst based on earth-abundant metals (Fe, Cu) maximizes solar energy conversion due to the concerted interplay of energies and interactions between reactants and hot carriers, thus producing aromatic amines with a high yield. Reduction of nitroaromatics to the corresponding amines is a key process in the fine and bulk chemicals industry to produce polymers, pharmaceuticals, agrochemicals and dyes. However, their effective and selective reduction requires high temperatures and pressurized hydrogen and involves noble metal-based catalysts. Here we report on an earth-abundant, plasmonic nullo-photocatalyst, with an excellent reaction rate towards the selective hydrogenation of nitroaromatics. With solar light as the only energy input, the chalcopyrite catalyst operates through the combined action of hot holes and photothermal effects. Ultrafast laser transient absorption and light-induced electron paramagnetic resonullce spectroscopies have unveiled the energy matching of the hot holes in the valence band of the catalyst with the frontier orbitals of the hydrogen and electron donor, via a transient coordination intermediate. Consequently, the reusable and sustainable copper-iron-sulfide (CuFeS2) catalyst delivers previously unattainable turnover frequencies, even in large-scale reactions, while the cost-normalized production rate stands an order of magnitude above the state of the art.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 17, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 485, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-022-01087-3", "DOI Link": "http://dx.doi.org/10.1038/s41565-022-01087-3", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773853000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bryant, D; Aristidou, N; Pont, S; Sanchez-Molina, I; Chotchunullgatchaval, T; Wheeler, S; Durrant, JR; Haque, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bryant, Daniel; Aristidou, Nicholas; Pont, Sebastian; Sanchez-Molina, Irene; Chotchunullgatchaval, Thana; Wheeler, Scot; Durrant, James R.; Haque, Saif A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we demonstrate that light and oxygen-induced degradation is the main reason for the low operational stability of methylammonium lead triiodide (MeNH3PbI3) perovskite solar cells exposed to ambient conditions. When exposed to both light and dry air, unencapsulated MeNH3PbI3 solar cells rapidly degrade on timescales of minutes to a few hours. This rapid degradation is also observed under electrically bias driven current flow in the dark in the presence of O-2. In contrast, significantly slower degradation is observed when the MeNH3PbI3 devices are exposed to moisture alone (e.g. 85% relative humidity in N-2). We show that this light and oxygen induced degradation can be slowed down by the use of interlayers that are able to remove electrons from the perovskite film before they can react with oxygen to form O-2(-). These observations demonstrate that the operational stability of electronic and optoelectronic devices that exploit the electron transporting properties of MeNH3PbI3 will be critically dependent upon the use of suitable barrier layers and device configurations to mitigate the oxygen sensitivity of this remarkable material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 834, "Times Cited, All Databases": 898, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1655, "End Page": 1660, "Article Number": null, "DOI": "10.1039/c6ee00409a", "DOI Link": "http://dx.doi.org/10.1039/c6ee00409a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375699500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, S; Wang, AX; Li, QQ; Wu, JS; Chiou, KV; Huang, JX; Luo, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shan; Wang, Aoxuan; Li, Qianqian; Wu, Jinsong; Chiou, Kevin; Huang, Jiaxing; Luo, Jiayan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crumpled Graphene Balls Stabilized Dendrite-free Lithium Metal Anodes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With its high theoretical capacity and low electrochemical potential, Li metal itself would be the ideal anode for Li-ion batteries. However, practical use of the Li anode has been hindered by its tendency for dendritic growth, which leads to unstable solid electrolyte interphase, volume fluctuation during cycling, and even shorting of the battery. This problem can be solved by employing a conducting, lightweight, and lithiophilic scaffold that can stabilize high loading of Li during cycling and avoid its dendritic filament growth. Here we report that crumpled paper ball-like graphene particles can readily assemble to yield a scaffold with scalable Li loading up to 10 mA hr cm(-2) within tolerable volume fluctuation. High Coulombic efficiency of 97.5% over 750 cycles (1,500 hr) was achieved. Plating/stripping Li up to 12 mA hr cm(-2) on crumpled graphene scaffold does not experience dendrite growth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2018, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 184, "End Page": 193, "Article Number": null, "DOI": "10.1016/j.joule.2017.11.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.11.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425303800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, DQ; Yang, QG; Chen, HY; Wobben, F; Le Corre, VM; Singh, R; Liu, T; Ma, RJ; Tang, H; Koster, LJA; Duan, TN; Yan, H; Kan, ZP; Xiao, ZY; Lu, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Dingqin; Yang, Qianguang; Chen, Haiyan; Wobben, Friso; Le Corre, Vincent M.; Singh, Ranbir; Liu, Tao; Ma, Ruijie; Tang, Hua; Koster, L. Jan Anton; Duan, Tainull; Yan, He; Kan, Zhipeng; Xiao, Zeyun; Lu, Shirong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "15.34% efficiency all-small-molecule organic solar cells with an improved fill factor enabled by a fullerene additive", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution processed organic solar cells (OSCs) composed of all small molecules (ASM) are promising for production on an industrial scale owing to the properties of small molecules, such as well-defined chemical structures, high purity of materials, and outstanding repeatability from batch to batch synthesis. Remarkably, ASM OSCs with power conversion efficiency (PCE) beyond 13% were achieved by structure improvement of the electron donor and choosingY6as the electron acceptor. However, the fill factor (FF) is an obstacle that limits the further improvement of the PCE for these ASM OSCs. Herein, we focus on the FF improvement of recently reported ASM OSCs withBTR-Cl:Y6as the active layer by miscibility-induced active layer morphology optimization. The incorporation of fullerene derivatives, which have good miscibility with bothBTR-ClandY6, results in reduced bimolecular recombination and thus improved FF. In particular, whenca.5 wt% ofPC(71)BMwas added in the active layer, a FF of 77.11% was achieved without sacrificing the open circuit voltage (V-OC) and the short circuit current density (J(SC)), leading to a record PCE of 15.34% (certified at 14.7%) for ASM OSCs. We found that the optimized device showed comparable charge extraction, longer charge carrier lifetime, and slower bimolecular recombination rate compared with those of the control devices (w/o fullerene). Our results demonstrate that the miscibility driven regulation of active layer morphology by incorporation of a fullerene derivative delicately optimizes the active layer microstructures and improves the device performance, which brings vibrancy to OSC research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2020, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2134, "End Page": 2141, "Article Number": null, "DOI": "10.1039/d0ee00714e", "DOI Link": "http://dx.doi.org/10.1039/d0ee00714e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549074800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Berman, D; Narayanull, B; Cherukara, MJ; Sankaranarayanull, SKRS; Erdemir, A; Zinovev, A; Sumant, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Berman, Diana; Narayanull, Badri; Cherukara, Mathew J.; Sankaranarayanull, Subramanian K. R. S.; Erdemir, Ali; Zinovev, Alexander; Sumant, Anirudha V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando tribochemical formation of onion-like-carbon leads to macroscale superlubricity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stress-induced reactions at the sliding interface during relative movement are known to cause structural or chemical modifications in contacting materials. The nature of these modifications at the atomic level and formation of byproducts in an oil-free environment, however, remain poorly understood and pose uncertainties in predicting the tribological performance of the complete tribosystem. Here, we demonstrate that tribochemical reactions occur even in dry conditions when hydrogenated diamond-like carbon (H-DLC) surface is slid against two-dimensional (2D) molybdenum disulfide along with nullodiamonds in dry nitrogen atmosphere. Detailed experimental studies coupled with reactive molecular dynamics simulations reveal that at high contact pressures, diffusion of sulfur from the dissociated molybdenum disulfide led to amorphization of nullodiamond and subsequent transformation to onion-like carbon structures (OLCs). The in situ formation of OLCs at the sliding interface provide reduced contact area as well as incommensurate contact with respect to the H-DLC surface, thus enabling successful demonstration of superlubricity", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1164, "DOI": "10.1038/s41467-018-03549-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03549-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427928500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Gogna, R; Burg, W; Tutuc, E; Deng, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Long; Gogna, Rahul; Burg, Will; Tutuc, Emanuel; Deng, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonic-crystal exciton-polaritons in monolayer semiconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor microcavity polaritons, formed via strong exciton-photon coupling, provide a quantum many-body system on a chip, featuring rich physics phenomena for better photonic technology. However, conventional polariton cavities are bulky, difficult to integrate, and inflexible for mode control, especially for room-temperature materials. Here we demonstrate sub-wavelength-thick, one-dimensional photonic crystals as a designable, compact, and practical platform for strong coupling with atomically thin van der Waals crystals. Polariton dispersions and mode anti-crossings are measured up to room temperature. Non-radiative decay to dark excitons is suppressed due to polariton enhancement of the radiative decay. Unusual features, including highly anisotropic dispersions and adjustable Fano resonullces in reflectance, may facilitate high temperature polariton condensation in variable dimensions. Combining slab photonic crystals and van der Waals crystals in the strong coupling regime allows unprecedented engineering flexibility for exploring novel polariton phenomena and device concepts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 713, "DOI": "10.1038/s41467-018-03188-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03188-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425382800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suchomel, P; Kvitek, L; Prucek, R; Panacek, A; Halder, A; Vajda, S; Zboril, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suchomel, Petr; Kvitek, Libor; Prucek, Robert; Panacek, Ales; Halder, Avik; Vajda, Stefan; Zboril, Radek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simple size-controlled synthesis of Au nulloparticles and their size-dependent catalytic activity", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The controlled preparation of Au nulloparticles (NPs) in the size range of 6 to 22 nm is explored in this study. The Au NPs were prepared by the reduction of tetrachloroauric acid using maltose in the presence of nonionic surfactant Tween 80 at various concentrations to control the size of the resulting Au NPs. With increasing concentration of Tween 80 a decrease in the size of produced Au NPs was observed, along with a significant decrease in their size distribution. The size-dependent catalytic activity of the synthesized Au NPs was tested in the reduction of 4-nitrophenol with sodium borohydride, resulting in increasing catalytic activity with decreasing size of the prepared nulloparticles. Eley-Rideal catalytic mechanism emerges as the more probable, in contrary to the Langmuir-Hinshelwood mechanism reported for other noble metal nullocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4589, "DOI": "10.1038/s41598-018-22976-5", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-22976-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427461900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abranches, DO; Martins, MAR; Silva, LP; Schaeffer, N; Pinho, SP; Coutinho, JAP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abranches, Dinis O.; Martins, Monia A. R.; Silva, Liliana P.; Schaeffer, Nicolas; Pinho, Simao P.; Coutinho, Joao A. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixtures of non-ionic compounds have been reported as DES but most are just ideal mixtures. In the thymol-menthol system, an abnormal strong interaction was identified stemming from the acidity difference of the phenolic and aliphatic hydroxyl groups. This type of interaction is found to be the key to prepare non-ionic DES, that may be classified as type V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2019, "Volume": 55, "Issue": 69, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10253, "End Page": 10256, "Article Number": null, "DOI": "10.1039/c9cc04846d", "DOI Link": "http://dx.doi.org/10.1039/c9cc04846d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482412300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, GX; Chen, CT; Richmond, DJ; Buehler, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Grace X.; Chen, Chun-Teh; Richmond, Deon J.; Buehler, Markus J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired hierarchical composite design using machine learning: simulation, additive manufacturing, and experiment", "Source Title": "MATERIALS HORIZONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomimicry, adapting and implementing nature's designs provides an adequate first-order solution to achieving superior mechanical properties. However, the design space is too vast even using biomimetic designs as prototypes for optimization. Here, we propose a new approach to design hierarchical materials using machine learning, trained with a database of hundreds of thousands of structures from finite element analysis, together with a self-learning algorithm for discovering high-performing materials where inferior designs are phased out for superior candidates. Results show that our approach can create microstructural patterns that lead to tougher and stronger materials, which are validated through additive manufacturing and testing. We further show that machine learning can be used as an alternative method of coarse-graining - analyzing and designing materials without the use of full microstructural data. This novel paradigm of smart additive manufacturing can aid in the discovery and fabrication of new material designs boasting orders of magnitude increase in computational efficacy over conventional methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 390, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2018, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 939, "End Page": 945, "Article Number": null, "DOI": "10.1039/c8mh00653a", "DOI Link": "http://dx.doi.org/10.1039/c8mh00653a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444245600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, WK; Wei, JX; Xiao, K; Ouyang, T; Peng, XW; Zhao, SL; Liu, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Wen-Kai; Wei, Jin-Xin; Xiao, Kang; Ouyang, Ting; Peng, Xinwen; Zhao, Shenlong; Liu, Zhao-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating Lattice Oxygen in Layered Lithium Oxides through Cation Vacancies for Enhanced Urea Electrolysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the fact that high-valent nickel-based oxides exhibit promising catalytic activity for the urea oxidation reaction (UOR), the fundamental questions concerning the origin of the high performance and the structure-activity correlations remain to be elucidated. Here, we unveil the underlying enhanced mechanism of UOR by employing a series of prepared cation-vacancy controllable LiNiO2 (LNO) model catalysts. Impressively, the optimized layered LNO-2 exhibits an extremely low overpotential at 10 mA cm(-2) along with excellent stability after the 160 h test. Operando characterisations combined with the theoretical analysis reveal the activated lattice oxygen in layered LiNiO2 with moderate cation vacancies triggers charge disproportion of the Ni site to form Ni4+ species, facilitating deprotonation in a lattice oxygen involved catalytic process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2022, "Volume": 61, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202206050", "DOI": "10.1002/anie.202206050", "DOI Link": "http://dx.doi.org/10.1002/anie.202206050", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000814565200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhan, C; Naguib, M; Lukatskaya, M; Kent, PRC; Gogotsi, Y; Jiang, DE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhan, Cheng; Naguib, Michael; Lukatskaya, Maria; Kent, Paul R. C.; Gogotsi, Yury; Jiang, De-en", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the MXene Pseudocapacitance", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes have attracted great attention as next-generation capacitive energy-storage materials, but the mechanisms underlying their pseudocapacitive behavior are not well understood. Here we provide a theoretical description of the surface redox process of Ti3C2Tx (T = O, OH), a prototypical MXene, in 1 M H2SO4 electrolyte, based on joint density functional theory with an implicit solvation model and the analysis of Gibbs free energy under a constant-electrode potential. From the dependence of the O/OH ratio (or the surface H coverage) and the surface charge on the applied potential, we obtain a clear picture of the capacitive energy-storage mechanism of Ti3C2Tx that shows good agreement with previous experimental findings in terms of the integral capacitance and Ti valence change. We find a voltage-dependent redox/double-layer co-charging behavior: the capacitive mechanism is dominated by the redox process, but the electric double-layer charge works against the redox process. This new insight may be useful in improving the capacitance of MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1223, "End Page": 1228, "Article Number": null, "DOI": "10.1021/acs.jpclett.8b00200", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.8b00200", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427910200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tshephe, TS; Akinwamide, SO; Olevsky, E; Olubambi, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tshephe, Thato Sharon; Akinwamide, Samuel Olukayode; Olevsky, Eugene; Olubambi, Peter Apata", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of titanium-based alloys- A review of methods, properties, challenges, and prospects", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of materials for biomedical, aerospace, and automobile industries has been a significant area of research in recent years. Various metallic materials, including steels, cast iron, nickel-based alloys, and other metals with exceptional mechanical properties, have been reportedly utilized for fabrication in these industries. However, titanium and its alloys have proven to be outstanding due to their enhanced properties. The beta-titanium alloys with reduced modulus compared with the human bone have found more usage in the biomedical industry. In contrast, the alpha and alpha thorn beta titanium alloys are more utilized to fabricate parts in the automobile and aerospace industries due to their relatively lightweight. Amongst the numerous additive manufacturing (AM) techniques, selective laser and electron beam melting techniques are frequently used for the fabrication of metallic components due to the full densification and high dimensional accuracy they offer. This paper reviews and discusses the different types of AM techniques, attention is also drawn to the properties and challenges associated with additively manufactured titanium-based alloys. The outcome from this study shows that 3D printed titanium and titanium-alloys exhibit huge prospects for various applications in the medical and aerospace industries. Also, laser-assisted 3D technologies were found to be the most effective AM method for achieving enhanced or near-full densification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e09041", "DOI": "10.1016/j.heliyon.2022.e09041", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2022.e09041", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784250800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, ZW; Du, KZ; Meng, WW; Wang, JB; Mitzi, DB; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Zewen; Du, Ke-Zhao; Meng, Weiwei; Wang, Jianbo; Mitzi, David B.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Instability of Cs2In(I)M(III)X6 (M = Bi, Sb; X = Halogen) Double Perovskites: A Combined Density Functional Theory and Experimental Study", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, there has been substantial interest in developing double-B-cation halide perovskites, which hold the potential to overcome the toxicity and instability issues inherent within emerging lead halide-based solar absorber materials. Among all double perovskites investigated, In(I)-based Cs2InBiCl6 and Cs2InSbCl6 have been proposed as promising thin-film,film photovoltaic absorber candidates, with computational examination predicting suitable materials properties, including direct bandgap and small effective masses for both electrons and-holes. In this study, we report the intrinsic instability Of Cs2In(I)M-(III)X-6 (M = Bi, Sb; X = halogen) double perovskites by a combination of density functional theory and experimental study. Our results suggest that the In(I)-based double perovskites are unstable against oxidation into In(III)-based compounds. Further, the results show the need to consider reduction-oxidation (redox) chemistry when predicting stability of new prospective electronic materials, especially when less. common oxidation states are involved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2017, "Volume": 139, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6054, "End Page": 6057, "Article Number": null, "DOI": "10.1021/jacs.7b02227", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b02227", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400802300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, BY; Chen, X; Qiu, W; Zhao, RR; Duan, JZ; Zhang, SJ; Pan, ZW; Zhao, SL; Guo, QD; Qi, YH; Wang, WH; Deng, L; Ni, SL; Sang, YH; Xue, H; Liu, H; Li, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Boyan; Chen, Xin; Qiu, Wei; Zhao, Rongrong; Duan, Jiazhi; Zhang, Shouji; Pan, Ziwen; Zhao, Shulin; Guo, Qindong; Qi, Yanhua; Wang, Wenhan; Deng, Lin; Ni, Shilei; Sang, Yuanhua; Xue, Hao; Liu, Hong; Li, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synchronous Disintegration of Ferroptosis Defense Axis via Engineered Exosome-Conjugated Magnetic nulloparticles for Glioblastoma Therapy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glioblastoma (GBM) is one of the most fatal central nervous system tumors and lacks effective or sufficient therapies. Ferroptosis is a newly discovered method of programmed cell death and opens a new direction for GBM treatment. However, poor blood-brain barrier (BBB) penetration, reduced tumor targeting ability, and potential compensatory mechanisms hinder the effectiveness of ferroptosis agents during GBM treatment. Here, a novel composite therapeutic platform combining the magnetic targeting features and drug delivery properties of magnetic nulloparticles with the BBB penetration abilities and siRNA encapsulation properties of engineered exosomes for GBM therapy is presented. This platform can be enriched in the brain under local magnetic localization and angiopep-2 peptide-modified engineered exosomes can trigger transcytosis, allowing the particles to cross the BBB and target GBM cells by recognizing the LRP-1 receptor. Synergistic ferroptosis therapy of GBM is achieved by the combined triple actions of the disintegration of dihydroorotate dehydrogenase and the glutathione peroxidase 4 ferroptosis defense axis with Fe3O4 nulloparticle-mediated Fe2+ release. Thus, the present findings show that this system can serve as a promising platform for the treatment of glioblastoma.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 9, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105451, "DOI": "10.1002/advs.202105451", "DOI Link": "http://dx.doi.org/10.1002/advs.202105451", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790500700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Coyle, S; Majidi, C; LeDuc, P; Hsia, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Coyle, Stephen; Majidi, Carmel; LeDuc, Philip; Hsia, K. Jimmy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-inspired soft robotics: Material selection, actuation, and design", "Source Title": "EXTREME MECHANICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Animals exploit the deformability of soft structures to move efficiently in complex natural environments. These soft structures are inherently compliant and enable large strains in components not typically found in robotics. Such capabilities have inspired robotic engineers to incorporate soft technologies into their designs. One goal in soft robotics is to endow robots with new, bioinspired features that permit morphologically adaptive interactions with unpredictable environments. Here, we review three key elements of bioinspired soft robots from a mechanics vantage point, namely, materials selection, actuation, and design. Soft materials are necessary for safe interaction and overall actuation of bioinspired robots. The intrinsic properties of materials in soft robots allow for an embodied intelligence that can potentially reduce the mechanical and algorithmic complexity in ways not possible with rigid-bodied robots Finally, soft robotics can be combined with tissue engineering and synthetic biology to create bio-hybrid systems with unique sensing, dynamic response, and mobility. Bioinspired soft robots have the ability to also expedite the evolution of co-robots that can safely interact with humans. (c) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 51, "End Page": 59, "Article Number": null, "DOI": "10.1016/j.eml.2018.05.003", "DOI Link": "http://dx.doi.org/10.1016/j.eml.2018.05.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438991600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheen, M; Ko, Y; Kim, DU; Kim, J; Byun, JH; Choi, Y; Ha, J; Yeon, KY; Kim, D; Jung, J; Choi, J; Kim, R; Yoo, J; Kim, I; Joo, C; Hong, N; Lee, J; Jeon, SH; Oh, SH; Lee, J; Ahn, N; Lee, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheen, Mihyang; Ko, Yunhyuk; Kim, Dong-uk; Kim, Jongil; Byun, Jin-ho; Choi, YongSeok; Ha, Jonghoon; Yeon, Ki Young; Kim, Dohyung; Jung, Jungwoon; Choi, Jinyoung; Kim, Ran; Yoo, Jewon; Kim, Inpyo; Joo, Chanwoo; Hong, Nami; Lee, Joohee; Jeon, Sang Ho; Oh, Sang Ho; Lee, Jaekwang; Ahn, Nari; Lee, Changhee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient blue InGaN nulloscale light-emitting diodes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Indium gallium nitride (InGaN)-based micro-LEDs (mu LEDs) are suitable for meeting ever-increasing demands for high-performance displays owing to their high efficiency, brightness and stability(1-5). However, mu LEDs have a large problem in that the external quantum efficiency (EQE) decreases with the size reduction(6-9). Here we demonstrate a blue InGaN/GaN multiple quantum well (MQW) nullorod-LED (nLED) with high EQE. To overcome the size-dependent EQE reduction problem(8,9), we studied the interaction between the GaN surface and the sidewall passivation layer through various analyses. Minimizing the point defects created during the passivation process is crucial to manufacturing high-performance nLEDs. Notably, the sol-gel method is advantageous for the passivation because SiO2 nulloparticles are adsorbed on the GaN surface, thereby minimizing its atomic interactions. The fabricated nLEDs showed an EQE of 20.2 +/- 0.6%, the highest EQE value ever reported for the LED in the nulloscale. This work opens the way for manufacturing self-emissive nLED displays that can become an enabling technology for next-generation displays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2022, "Volume": 608, "Issue": 7921, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 56, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04933-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04933-5", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000835655400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duine, RA; Lee, KJ; Parkin, SSP; Stiles, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duine, R. A.; Lee, Kyung-Jin; Parkin, Stuart S. P.; Stiles, M. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic antiferromagnetic spintronics", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spintronic and nullomagnetic devices often derive their functionality from layers of different materials and the interfaces between them. We discuss the opportunities that arise from synthetic antiferromagnets consisting of two or more ferromagnetic layers that are separated by metallic spacers or tunnel barriers and have antiparallel magnetizations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 217, "End Page": 219, "Article Number": null, "DOI": "10.1038/s41567-018-0050-y", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0050-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426546300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CH; Planella, FB; O'Regan, K; Gastol, D; Widanage, WD; Kendrick, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chang-Hui; Planella, Ferran Brosa; O'Regan, Kieran; Gastol, Dominika; Widanage, W. Dhammika; Kendrick, Emma", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of Experimental Techniques for Parameterization of Multi-scale Lithium-ion Battery Models", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Presented here, is an extensive 35 parameter experimental data set of a cylindrical 21700 commercial cell (LGM50), for an electrochemical pseudo-two-dimensional (P2D) model. The experimental methodologies for tear-down and subsequent chemical, physical, electrochemical kinetics and thermodynamic analysis, and their accuracy and validity are discussed. Chemical analysis of the LGM50 cell shows that it is comprised of a NMC 811 positive electrode and bi-component Graphite-SiOx negative electrode. The thermodynamic open circuit voltages (OCV) and lithium stoichiometry in the electrode are obtained using galvanostatic intermittent titration technique (GITT) in half cell and three-electrode full cell configurations. The activation energy and exchange current coefficient through electrochemical impedance spectroscopy (EIS) measurements. Apparent diffusion coefficients are estimated using the Sand equation on the voltage transient during the current pulse; an expansion factor was applied to the bicomponent negative electrode data to reflect the average change in effective surface area during lithiation. The 35 parameters are applied within a P2D model to show the fit to experimental validation LGM50 cell discharge and relaxation voltage profiles at room temperature. The accuracy and validity of the processes and the techniques in the determination of these parameters are discussed, including opportunities for further modelling and data analysis improvements. (C) 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 167, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 80534, "DOI": "10.1149/1945-7111/ab9050", "DOI Link": "http://dx.doi.org/10.1149/1945-7111/ab9050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535362900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kozawa, D; Kumar, R; Carvalho, A; Amara, KK; Zhao, WJ; Wang, SF; Toh, ML; Ribeiro, RM; Neto, AHC; Matsuda, K; Eda, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kozawa, Daichi; Kumar, Rajeev; Carvalho, Alexandra; Amara, Kiran Kumar; Zhao, Weijie; Wang, Shunfeng; Toh, Minglin; Ribeiro, Ricardo M.; Castro Neto, A. H.; Matsuda, Kazunari; Eda, Goki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocarrier relaxation pathway in two-dimensional semiconducting transition metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional crystals of semiconducting transition metal dichalcogenides absorb a large fraction of incident photons in the visible frequencies despite being atomically thin. It has been suggested that the strong absorption is due to the parallel band or 'band nesting' effect and corresponding divergence in the joint density of states. Here, we use photoluminescence excitation spectroscopy to show that the band nesting in mono-and bilayer MX2 (M = Mo, W and X = S, Se) results in excitation-dependent characteristic relaxation pathways of the photoexcited carriers. Our experimental and simulation results reveal that photoexcited electron-hole pairs in the nesting region spontaneously separate in k-space, relaxing towards immediate band extrema with opposite momentum. These effects imply that the loss of photocarriers due to direct exciton recombination is temporarily suppressed for excitation in resonullce with band nesting. Our findings highlight the potential for efficient hot carrier collection using these materials as the absorbers in optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 396, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4543, "DOI": "10.1038/ncomms5543", "DOI Link": "http://dx.doi.org/10.1038/ncomms5543", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340626300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, BY; Fan, Z; Li, WJ; Chen, YH; Dong, S; Tan, ZW; Cheng, SL; Tian, BB; Tao, RQ; Tian, G; Chen, DY; Hou, ZP; Qin, MH; Zeng, M; Lu, XB; Zhou, GF; Gao, XS; Liu, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Boyuan; Fan, Zhen; Li, Wenjie; Chen, Yihong; Dong, Shuai; Tan, Zhengwei; Cheng, Shengliang; Tian, Bobo; Tao, Ruiqiang; Tian, Guo; Chen, Deyang; Hou, Zhipeng; Qin, Minghui; Zeng, Min; Lu, Xubing; Zhou, Guofu; Gao, Xingsen; Liu, Jun-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric photosensor network: an advanced hardware solution to real-time machine vision", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Robust, fast, and low-power hardware platforms are desirable for the implementation of real-time machine vision. Here the authors develop a computing-in-sensor network using ferroelectric photo sensors with remanent-polarization-controlled photo responsivities. Nowadays the development of machine vision is oriented toward real-time applications such as autonomous driving. This demands a hardware solution with low latency, high energy efficiency, and good reliability. Here, we demonstrate a robust and self-powered in-sensor computing paradigm with a ferroelectric photosensor network (FE-PS-NET). The FE-PS-NET, constituted by ferroelectric photosensors (FE-PSs) with tunable photoresponsivities, is capable of simultaneously capturing and processing images. In each FE-PS, self-powered photovoltaic responses, modulated by remanent polarization of an epitaxial ferroelectric Pb(Zr0.2Ti0.8)O-3 layer, show not only multiple nonvolatile levels but also sign reversibility, enabling the representation of a signed weight in a single device and hence reducing the hardware overhead for network construction. With multiple FE-PSs wired together, the FE-PS-NET acts on its own as an artificial neural network. In situ multiply-accumulate operation between an input image and a stored photoresponsivity matrix is demonstrated in the FE-PS-NET. Moreover, the FE-PS-NET is faultlessly competent for real-time image processing functionalities, including binary classification between 'X' and 'T' patterns with 100% accuracy and edge detection for an arrow sign with an F-Measure of 1 (under 365 nm ultraviolet light). This study highlights the great potential of ferroelectric photovoltaics as the hardware basis of real-time machine vision.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1707, "DOI": "10.1038/s41467-022-29364-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29364-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777008300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "DeBruler, C; Hu, B; Moss, J; Liu, XA; Luo, JA; Sun, YJ; Liu, TL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "DeBruler, Camden; Hu, Bo; Moss, Jared; Liu, Xuan; Luo, Jian; Sun, Yujie; Liu, T. Leo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designer Two-Electron Storage Viologen Anolyte Materials for Neutral Aqueous Organic Redox Flow Batteries", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous organic redox flow batteries (AORFBs) are highly attractive for large-scale energy storage because redox-active organic molecules are synthetically tunable, sustainable, and potentially low cost. Here, we show that rational molecular engineering yielded a series of two-electron storage viologen molecules as anolyte materials for AORFBs. In neutral NaCl solutions, these viologen anolytes have a theoretical capacity of up to 96.5 Ah/L in H2O and exhibit a reduction potential as low as -0.78 V versus normal hydrogen electrode. The neutral aqueous flow batteries with two two-electron storage viologen molecules delivered a cell voltage of up to 1.38 V and outstanding battery performance, including a power density of up to 130 mW/cm(2), capacity retention of up to 99.99% per cycle, and energy efficiency of up to 65% at 60 mA/cm(2). Density functional theory calculations revealed that the 1e(-) and 2e(-) reduced redox states of these molecules were stabilized by the high charge delocalization of their frontier SOMO or HOMO.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 961, "End Page": 978, "Article Number": null, "DOI": "10.1016/j.chempr.2017.11.001", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.11.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418335800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, MW; Dallmeyer, I; Johnson, TJ; Brauer, CS; McEwen, JS; Espinal, JF; Garcia-Perez, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Matthew W.; Dallmeyer, Ian; Johnson, Timothy J.; Brauer, Carolyn S.; McEwen, Jean-Sabin; Espinal, Juan F.; Garcia-Perez, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural analysis of char by Raman spectroscopy: Improving band assignments through computational calculations from first principles", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complex heterogeneous nature of chars has confounded the complete analysis of the Raman spectra of these materials. The additional shoulders observed on the defect (D)-band and high intensity valley between the D and graphitic (G)-bands represent the primary regions of uncertainty. In this paper the effects of various vacancy and substitution defects in a coronene parent molecule have been systematically analyzed using density functional theory (DFT). The impacts of these defects are best understood in terms of a reduced symmetry as compared to a parent coronene molecule. Based on simulation results, a total of ten potential bands have been assigned between 1000 cm(-1) and 1800 cm(-1). These bands have been used to deconvolute a thermoseries of cellulose chars produced by pyrolysis at 300-700 degrees C. The shoulder observed in chars near 1200 cm(-1) has been assigned to the symmetric breathing mode of various small polyaromatic hydrocarbons (PAH) as well as rings containing seven or more carbons. Intensity between 1400 cm(-1) and 1550 cm(-1) results from a range of coupled vibrational modes from various defect structures. The deconvolution of cellulose derived chars shows consistent growth of PAH clusters, loss of oxygen, and development of non-hexoganal ring systems as pyrolysis temperature increased. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 678, "End Page": 692, "Article Number": null, "DOI": "10.1016/j.carbon.2016.01.031", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2016.01.031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369961400076", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pizzocchero, F; Gammelgaard, L; Jessen, BS; Caridad, JM; Wang, L; Hone, J; Boggild, P; Booth, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pizzocchero, Filippo; Gammelgaard, Lene; Jessen, Bjarke S.; Caridad, Jose M.; Wang, Lei; Hone, James; Boggild, Peter; Booth, Timothy J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The hot pick-up technique for batch assembly of van der Waals heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The assembly of individual two-dimensional materials into van der Waals heterostructures enables the construction of layered three-dimensional materials with desirable electronic and optical properties. A core problem in the fabrication of these structures is the formation of clean interfaces between the individual two-dimensional materials which would affect device performance. We present here a technique for the rapid batch fabrication of van der Waals heterostructures, demonstrated by the controlled production of 22 mono-, bi- and trilayer graphene stacks encapsulated in hexagonal boron nitride with close to 100% yield. For the monolayer devices, we found semiclassical mean-free paths up to 0.9 mu m, with the narrowest samples showing clear indications of the transport being affected by boundary scattering. The presented method readily lends itself to fabrication of van der Waals heterostructures in both ambient and controlled atmospheres, while the ability to assemble pre-patterned layers paves the way for complex three-dimensional architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 496, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11894, "DOI": "10.1038/ncomms11894", "DOI Link": "http://dx.doi.org/10.1038/ncomms11894", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378813900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Sheng, P; Takahashi, S; Mitani, S; Hayashi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Junyeon; Sheng, Peng; Takahashi, Saburo; Mitani, Seiji; Hayashi, Masamitsu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin Hall Magnetoresistance in Metallic Bilayers", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin Hall magnetoresistance (SMR) is studied in metallic bilayers that consist of a heavy metal (HM) layer and a ferromagnetic metal (FM) layer. We find a nearly tenfold increase of SMR in W/CoFeB compared to previously studied HM/ferromagnetic insulator systems. The SMR increases with decreasing temperature despite the negligible change in the W layer resistivity. A model is developed to account for the absorption of the longitudinal spin current to the FM layer, one of the key characteristics of a metallic ferromagnet. We find that the model not only quantitatively describes the HM layer thickness dependence of SMR, allowing accurate estimation of the spin Hall angle and the spin diffusion length of the HM layer, but also can account for the temperature dependence of SMR by assuming a temperature dependent spin polarization of the FM layer. These results illustrate the unique role a metallic ferromagnetic layer plays in defining spin transmission across the HM/FM interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 29", "Publication Year": 2016, "Volume": 116, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 97201, "DOI": "10.1103/PhysRevLett.116.097201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.097201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371772600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, JS; Li, X; Niu, Q; Feng, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Jingshan; Li, Xiao; Niu, Qian; Feng, Ji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant and tunable valley degeneracy splitting in MoTe2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Valleys in monolayer transition-metal dichalcogenides seamlessly connect two basic carriers of quantum information, namely, the electron spin and photon helicity. Lifting the valley degeneracy is an attractive route to achieve further optoelectronic manipulations. However, the magnetic field only creates a very small valley splitting. We propose a strategy to create giant valley splitting by the proximity-induced Zeeman effect. Our first principles calculations of monolayer MoTe2 on a EuO substrate show that valley splitting over 300 meV can be generated. Interband transition energies become valley dependent, leading to selective spin-photon coupling by optical frequency tuning. The valley splitting is also continuously tunable by rotating the substrate magnetization. The giant and tunable valley splitting adds a different dimension to the exploration of unique optoelectronic devices based on magneto-optical coupling and magnetoelectric coupling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2015, "Volume": 92, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121403, "DOI": "10.1103/PhysRevB.92.121403", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.121403", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360885400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ming, DW; Archer, PD; Glavin, DP; Eigenbrode, JL; Franz, HB; Sutter, B; Brunner, AE; Stern, JC; Freissinet, C; McAdam, AC; Mahaffy, PR; Cabane, M; Coll, P; Campbell, JL; Atreya, SK; Niles, PB; Bell, JF; Bish, DL; Brinckerhoff, WB; Buch, A; Conrad, PG; Des Marais, DJ; Ehlmann, BL; Fairén, AG; Farley, K; Flesch, GJ; Francois, P; Gellert, R; Grant, JA; Grotzinger, JP; Gupta, S; Herkenhoff, KE; Hurowitz, JA; Leshin, LA; Lewis, KW; McLennull, SM; Miller, KE; Moersch, J; Morris, RV; Navarro-González, R; Pavlov, AA; Perrett, GM; Pradler, I; Squyres, SW; Summons, RE; Steele, A; Stolper, EM; Sumner, DY; Szopa, C; Teinturier, S; Trainer, MG; Treiman, AH; Vaniman, DT; Vasavada, AR; Webster, CR; Wray, JJ; Yingst, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ming, D. W.; Archer, P. D., Jr.; Glavin, D. P.; Eigenbrode, J. L.; Franz, H. B.; Sutter, B.; Brunner, A. E.; Stern, J. C.; Freissinet, C.; McAdam, A. C.; Mahaffy, P. R.; Cabane, M.; Coll, P.; Campbell, J. L.; Atreya, S. K.; Niles, P. B.; Bell, J. F., III; Bish, D. L.; Brinckerhoff, W. B.; Buch, A.; Conrad, P. G.; Des Marais, D. J.; Ehlmann, B. L.; Fairen, A. G.; Farley, K.; Flesch, G. J.; Francois, P.; Gellert, R.; Grant, J. A.; Grotzinger, J. P.; Gupta, S.; Herkenhoff, K. E.; Hurowitz, J. A.; Leshin, L. A.; Lewis, K. W.; McLennull, S. M.; Miller, K. E.; Moersch, J.; Morris, R. V.; Navarro-Gonzalez, R.; Pavlov, A. A.; Perrett, G. M.; Pradler, I.; Squyres, S. W.; Summons, R. E.; Steele, A.; Stolper, E. M.; Sumner, D. Y.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Treiman, A. H.; Vaniman, D. T.; Vasavada, A. R.; Webster, C. R.; Wray, J. J.; Yingst, R. A.", "Book Author Full Names": null, "Group Authors": "MSL Sci Team", "Article Title": "Volatile and Organic Compositions of Sedimentary Rocks in Yellowknife Bay, Gale Crater, Mars", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "H2O, CO2, SO2, O-2, H-2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O-2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2014, "Volume": 343, "Issue": 6169, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1245267, "DOI": "10.1126/science.1245267", "DOI Link": "http://dx.doi.org/10.1126/science.1245267", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330039300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rochman, CM; Hentschel, BT; Teh, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rochman, Chelsea M.; Hentschel, Brian T.; Teh, Swee J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-Term Sorption of Metals Is Similar among Plastic Types: Implications for Plastic Debris in Aquatic Environments", "Source Title": "PLOS ONE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concerns regarding plastic debris and its ability to accumulate large concentrations of priority pollutants in the aquatic environment led us to quantify relationships between different types of mass-produced plastic and metals in seawater. At three locations in San Diego Bay, we measured the accumulation of nine targeted metals (aluminum, chromium, manganese, iron, cobalt, nickel, zinc, cadmium and lead) sampling at 1, 3, 6, 9 and 12 months, to five plastic types: polyethylene terephthalate (PET), high-density polyethylene (HDPE), polyvinyl chloride (PVC), low-density polyethylene (LDPE), and polypropylene (PP). Accumulation patterns were not consistent over space and time, and in general all types of plastic tended to accumulate similar concentrations of metals. When we did observe significant differences among concentrations of metals at a single sampling period or location in San Diego Bay, we found that HDPE typically accumulated lesser concentrations of metals than the other four polymers. Furthermore, over the 12-month study period, concentrations of all metals increased over time, and chromium, manganese, cobalt, nickel, zinc and lead did not reach saturation on at least one plastic type during the entire 12-month exposure. This suggests that plastic debris may accumulate greater concentrations of metals the longer it remains at sea. Overall, our work shows that a complex mixture of metals, including those listed as priority pollutants by the US EPA (Cd, Ni, Zn and Pb), can be found on plastic debris composed of various plastic types.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2014, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e85433", "DOI": "10.1371/journal.pone.0085433", "DOI Link": "http://dx.doi.org/10.1371/journal.pone.0085433", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330235100084", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, J; Zeng, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Jun; Zeng, Xiao Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Titanium Trisulfide Monolayer: Theoretical Prediction of a New Direct-Gap Semiconductor with High and Anisotropic Carrier Mobility", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new two-dimensional (2D) layered material, namely, titanium trisulfide (TiS3) monolayer, is predicted to possess novel electronic properties. Abinitio calculations show that the perfect TiS3 monolayer is a direct-gap semiconductor with a bandgap of 1.02eV, close to that of bulk silicon, and with high carrier mobility. More remarkably, the in-plane electron mobility of the 2D TiS3 is highly anisotropic, amounting to about 10000cm(2)V(-1)s(-1) in the b direction, which is higher than that of the MoS2 monolayer, whereas the hole mobility is about two orders of magnitude lower. Furthermore, TiS3 possesses lower cleavage energy than graphite, suggesting easy exfoliation for TiS3. Both dynamical and thermal stability of the TiS3 monolayer is examined by phonon-spectrum calculation and Born-Oppenheimer molecular dynamics simulation. The desired electronic properties render the TiS3 monolayer a promising 2D atomic-layer material for applications in future nulloelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2015, "Volume": 54, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7572, "End Page": 7576, "Article Number": null, "DOI": "10.1002/anie.201502107", "DOI Link": "http://dx.doi.org/10.1002/anie.201502107", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356390900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, KY; Wu, T; Huang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Kaiyue; Wu, Tao; Huang, Kevin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NaCa0.6V6O16•3H2O as an Ultra-Stable Cathode for Zn-Ion Batteries: The Roles of Pre-Inserted Dual-Cations and Structural Water in V3O8 Layer", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous batteries with Zn2+ as a working-ion are promising candidates for grid-scale energy storage because of their intrinsic safety, low-cost, and high energy-intensity. However, suitable cathode materials with excellent Zn2+-storage cyclability must be found in order for Zinc-ion batteries (ZIBs) to find practical applications. Herein, NaCa0.6V6O16 center dot 3H(2)O (NaCaVO) barnesite nullobelts are reported as an ultra-stable ZIB cathode material. The original capacity reaches 347 mAh g(-1) at 0.1 A g(-1), and the capacity retention rate is 94% after 2000 cycles at 2 A g(-1) and 83% after 10 000 cycles at 5 A g(-1), respectively. Through a combined theoretical and experimental approach, it is discovered that the unique V3O8 layered structure in NaCaVO is energetically favorable for Zn2+ diffusion and the structural water situated between V3O8 layers promotes a fast charge-transfer and bulk migration of Zn2+ by enlarging gallery spacing and providing more Zn-ion storage sites. It is also found that Na+ and Ca2+ alternately suited in V3O8 layers are the essential stabilizers for the layered structure, which play a crucial role in retaining long-term cycling stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 9, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901968, "DOI": "10.1002/aenm.201901968", "DOI Link": "http://dx.doi.org/10.1002/aenm.201901968", "Book DOI": null, "Early Access Date": "AUG 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483956200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rolston, N; Bush, KA; Printz, AD; Gold-Parker, A; Ding, YC; Toney, MF; McGehee, MD; Dauskardt, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rolston, Nicholas; Bush, Kevin A.; Printz, Adam D.; Gold-Parker, Aryeh; Ding, Yichuan; Toney, Michael F.; McGehee, Michael D.; Dauskardt, Reinhold H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Stress in Perovskite Solar Cells to Improve Stability", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An overlooked factor affecting stability: the residual stresses in perovskite films, which are tensile and can exceed 50 MPa in magnitude, a value high enough to deform copper, is reported. These stresses provide a significant driving force for fracture. Films are shown to be more unstable under tensile stress-and conversely more stable under compressive stress-when exposed to heat or humidity. Increasing the formation temperature of perovskite films directly correlates with larger residual stresses, a result of the high thermal expansion coefficient of perovskites. Specifically, this tensile stress forms upon cooling to room temperature, as the substrate constrains the perovskite from shrinking. No evidence of stress relaxation is observed, with the purely elastic film stress attributed to the thermal expansion mismatch between the perovskite and substrate. Additionally, the authors demonstrate that using a bath conversion method to form the perovskite film at room temperature leads to low stress values that are unaffected by further annealing, indicating complete perovskite formation prior to annealing. It is concluded that reducing the film stress is a novel method for improving perovskite stability, which can be accomplished by lower formation temperatures, flexible substrates with high thermal expansion coefficients, and externally applied compressive stress after fabrication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2018, "Volume": 8, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802139, "DOI": "10.1002/aenm.201802139", "DOI Link": "http://dx.doi.org/10.1002/aenm.201802139", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447257000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, CQ; Zhou, QC; Yu, L; Duan, DS; Cao, TY; Qiu, SH; Wang, ZZ; Guo, J; Xie, YX; Li, LP; Yu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Chuqiang; Zhou, Qiancheng; Yu, Luo; Duan, Dingshuo; Cao, Tianyu; Qiu, Shunhang; Wang, Zhouzhou; Guo, Jin; Xie, Yuxin; Li, Liping; Yu, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional Bimetal Co-Modification for Boosting Large-Current-Density Seawater Electrolysis by Inhibiting Adsorption of Chloride Ions", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing efficient and durable electrocatalysts for seawater splitting to avoid undesired chlorine evolution reaction and resist the corrosive seawater is crucial for seawater electrolysis technology. Herein, a functional bimetal (Co and Fe) is designed specifically to modify nickel phosphide (denoted as CoFe-Ni2P) for boosting seawater splitting, where the Fe atom improves the conductivity of Ni2P for improving electron transfer, and the Co atom accelerates the self-reconstruction process to favorably generate bimetal co-incorporated NiOOH (CoFe-NiOOH) species on the electrode surface. Additionally, these in situ-generated CoFe-NiOOH species remarkably inhibit the adsorption of Cl- ions but selectively adsorb OH- ions, which contributes to excellent performance of the CoFe-Ni2P electrode for large-current-density seawater splitting. Therefore, the CoFe-Ni2P electrode only requires low overpotentials of 266 and 304 mV to afford current densities of 100 and 500 mA cm(-2) in a harsh 6 m KOH + seawater electrolyte, and can work stably for 600 h. Impressively, a flow-type anion exchange membrane electrolyzer assembled by the CoFe-Ni2P/Ni-felt bifunctional electrode is demonstrated to run stably at an industrially large current density of 1.0 A cm(-2) in 6 m KOH + seawater electrolyte for 350 h, which shows promising application prospects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 13, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202301475", "DOI Link": "http://dx.doi.org/10.1002/aenm.202301475", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001020229400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, M; Dong, CY; Gao, R; Xiao, DQ; Liu, HY; Ma, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Mi; Dong, Chunyang; Gao, Rui; Xiao, Dequan; Liu, Hongyang; Ma, Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully Exposed Cluster Catalyst (FECC): Toward Rich Surface Sites and Full Atom Utilization Efficiency", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing attention has been paid to single-atom catalysts (SACs) in heterogeneous catalysis because of their unique electronic properties, maximized atomic utilization efficiency, and potential to serve as a bridge between the heterogeneous and homogeneous catalysis. However, SACs can have limited advantages or even constrained applications for the reactions that require designated metallic states with multiple atoms or surface sites with metal-metal bonds. As a cross-dimensional extension to the concept of SACs, fully exposed cluster catalysts (FECCs) offer diverse surface sites formed by an ensemble of metal atoms, for the adsorption and transformation of reactants/intermediates. More importantly, FECCs have the advantage of maximized atom utilization efficiency. Thus, FECCs provide a novel platform to design effective and efficient catalysts for certain chemical processes. This outlook summarizes recent advances and proposes prospective research directions in the design of catalysts and characterizations of FECCs, together with potential challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2021, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 262, "End Page": 273, "Article Number": null, "DOI": "10.1021/acscentsci.0c01486", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c01486", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000624340000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Torkian, N; Bahrami, A; Hosseini-Abari, A; Momeni, MM; Abdolkarimi-Mahabadi, M; Bayat, A; Hajipour, P; Rourani, HA; Abbasi, MS; Torkian, S; Wen, YP; Mehr, MY; Hojjati-Najafabadi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Torkian, Niloufar; Bahrami, Abbas; Hosseini-Abari, Afrouzossadat; Momeni, Mohammad Mohsen; Abdolkarimi-Mahabadi, Meisam; Bayat, Ahmad; Hajipour, Pejman; Rourani, Hamed Amini; Abbasi, Mohammad Saeid; Torkian, Sima; Wen, Yangping; Mehr, Maryam Yazdan; Hojjati-Najafabadi, Akbar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and characterization of Ag-ion-exchanged zeolite/TiO2 nullocomposites for antibacterial applications and photocatalytic degradation of antibiotics", "Source Title": "ENVIRONMENTAL RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper investigates the synthesis, antibacterial, and photocatalytic properties of silver ion-exchanged natural zeolite/TiO2 photocatalyst nullocomposite. Zeolite is known to have a porous surface structure, making it an ideal substrate and framework in different nullocomposites. Moreover, natural zeolite has a superior thermal and chemical stability, with hardly any reactivity with chemicals. Finding an effective and low-cost method to remove both antibiotics and bacteria from water resources has become a vital global issue due to the worldwide excessive use of chemicals and antibiotics. This research aims to propose a facile method to synthesize Ag-ion-exchanged zeolite/TiO2 catalyst for anti-bacterial purposes and photocatalytic removal of atibiotics from wastewaters. TiO2 particles were deposited on the surface of natural zeolite. Ag ion exchanging was performed via a liquid ion-exchange method using 0.1 M AgNO3 solution. X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and Fourier-transform infrared spectroscopy (FTIR) were used to evaluate the structure of synthesized powders. Antibacterial activities of samples were assessed, using Staphylococcus aureus ATCC 25923 and Escherichia coli ATCC 25922 by disc diffusion method. It was shown that Ag-containing nullocomposite samples have an improved antibacterial performance in both cases. Results showed that the synthesized catalyst has promising potentials in wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2022, "Volume": 207, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112157, "DOI": "10.1016/j.envres.2021.112157", "DOI Link": "http://dx.doi.org/10.1016/j.envres.2021.112157", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Public, Environmental & Occupational Health", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751897700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roy, C; Sebok, B; Scott, SB; Fiordaliso, EM; Sorensen, JE; Bodin, A; Trimarco, DB; Damsgaard, CD; Vesborg, PCK; Hansen, O; Stephens, IEL; Kibsgaard, J; Chorkendorff, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roy, C.; Sebok, B.; Scott, S. B.; Fiordaliso, E. M.; Sorensen, J. E.; Bodin, A.; Trimarco, D. B.; Damsgaard, C. D.; Vesborg, P. C. K.; Hansen, O.; Stephens, I. E. L.; Kibsgaard, J.; Chorkendorff, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of nulloparticle size and lattice oxygen on water oxidation on NiFeOxHy", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NiFeOxHy are the most active catalysts for oxygen evolution in a base. For this reason, they are used widely in alkaline electrolysers. Several open questions remain as to the reason for their exceptionally high catalytic activity. Here we use a model system of mass-selected NiFe nulloparticles and isotope labelling experiments to show that oxygen evolution in 1M KOH does not proceed via lattice exchange. We complement our activity measurements with electrochemistry-mass spectrometry, taken under operando conditions, and transmission electron microscopy and low-energy ion-scattering spectroscopy, taken ex situ. Together with the trends in particle size, the isotope results indicate that oxygen evolution is limited to the near-surface region. Using the surface area of the particles, we determined that the turnover frequency was 6.2 +/- 1.6 s(-1) at an overpotential of 0.3 V, which is, to the best of our knowledge, the highest reported for oxygen evolution in alkaline solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 1, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 820, "End Page": 829, "Article Number": null, "DOI": "10.1038/s41929-018-0162-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0162-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449799200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YZ; Huang, W; Li, YB; Pei, A; Boyle, DT; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuzhang; Huang, William; Li, Yanbin; Pei, Allen; Boyle, David Thomas; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlating Structure and Function of Battery Interphases at Atomic Resolution Using Cryoelectron Microscopy", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Battery decay and failure depend strongly on the solid electrolyte interphase (SEI), a surface corrosion layer that forms on the surface of all battery electrodes. Recently, we revealed the atomic structure of these reactive and sensitive battery materials and their SEIs using cryoelectron microscopy (cryo-EM). However, the SEI nullostructure's fundamental role and effect on battery performance remain unclear. Here, we use cryo-EM to discover the function of two distinct SEI nullostructures (i.e., mosaic and multilayer) and correlate their stark effects with Li metal battery performance. We identify fluctuations in crystalline grain distribution within the SEI as the critical feature differentiating the mosaic SEI from the multilayer SEI, resulting in their distinct electrochemical stripping mechanisms. Whereas localized Li dissolution occurs quickly through regions of high crystallinity in the mosaic SEI, uniform Li stripping is observed for the more ordered multilayer SEIs, which reduces Li loss during battery cycling by a factor of three. This dramatic performance enhancement from a subtle change in SEI nullostructure highlights the importance of cryo-EM studies in revealing crucial failure modes of high-energy batteries at the nulloscale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 369, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2018, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2167, "End Page": 2177, "Article Number": null, "DOI": "10.1016/j.joule.2018.08.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.08.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447735000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teale, AM; Helgaker, T; Savin, A; Adamo, C; Aradi, B; Arbuznikov, A; Ayers, PW; Baerends, EJ; Barone, V; Calaminici, P; Cancès, E; Carter, EA; Chattaraj, PK; Chermette, H; Ciofini, I; Crawford, TD; De Proft, F; Dobson, JF; Draxl, C; Frauenheim, T; Fromager, E; Fuentealba, P; Gagliardi, L; Galli, G; Gao, JL; Geerlings, P; Gidopoulos, N; Gill, PMW; Gori-Giorgi, P; Görling, A; Gould, T; Grimme, S; Gritsenko, O; Jensen, HJA; Johnson, ER; Jones, RO; Kaupp, M; Köster, AM; Kronik, L; Krylov, A; Kvaal, S; Laestadius, A; Levy, M; Lewin, M; Liu, SB; Loos, PF; Maitra, NT; Neese, F; Perdew, JP; Pernal, K; Pernot, P; Piecuch, P; Rebolini, E; Reining, L; Romaniello, P; Ruzsinszky, A; Salahub, DR; Scheffler, M; Schwerdtfeger, P; Staroverov, VN; Sun, JW; Tellgren, E; Tozer, DJ; Trickey, SB; Ullrich, CA; Vela, A; Vignale, G; Wesolowski, TA; Xu, X; Yang, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teale, Andrew M.; Helgaker, Trygve; Savin, Andreas; Adamo, Carlo; Aradi, Balint; Arbuznikov, Alexei, V; Ayers, Paul W.; Baerends, Evert Jan; Barone, Vincenzo; Calaminici, Patrizia; Cances, Eric; Carter, Emily A.; Chattaraj, Pratim Kumar; Chermette, Henry; Ciofini, Ilaria; Crawford, T. Daniel; De Proft, Frank; Dobson, John F.; Draxl, Claudia; Frauenheim, Thomas; Fromager, Emmanuel; Fuentealba, Patricio; Gagliardi, Laura; Galli, Giulia; Gao, Jiali; Geerlings, Paul; Gidopoulos, Nikitas; Gill, Peter M. W.; Gori-Giorgi, Paola; Gorling, Andreas; Gould, Tim; Grimme, Stefan; Gritsenko, Oleg; Jensen, Hans Jorgen Aagaard; Johnson, Erin R.; Jones, Robert O.; Kaupp, Martin; Koster, Andreas M.; Kronik, Leeor; Krylov, Anna, I; Kvaal, Simen; Laestadius, Andre; Levy, Mel; Lewin, Mathieu; Liu, Shubin; Loos, Pierre-Francois; Maitra, Neepa T.; Neese, Frank; Perdew, John P.; Pernal, Katarzyna; Pernot, Pascal; Piecuch, Piotr; Rebolini, Elisa; Reining, Lucia; Romaniello, Pina; Ruzsinszky, Adrienn; Salahub, Dennis R.; Scheffler, Matthias; Schwerdtfeger, Peter; Staroverov, Viktor N.; Sun, Jianwei; Tellgren, Erik; Tozer, David J.; Trickey, Samuel B.; Ullrich, Carsten A.; Vela, Alberto; Vignale, Giovanni; Wesolowski, Tomasz A.; Xu, Xin; Yang, Weitao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, the history, present status, and future of density-functional theory (DFT) is informally reviewed and discussed by 70 workers in the field, including molecular scientists, materials scientists, method developers and practitioners. The format of the paper is that of a roundtable discussion, in which the participants express and exchange views on DFT in the form of 302 individual contributions, formulated as responses to a preset list of 26 questions. Supported by a bibliography of 777 entries, the paper represents a broad snapshot of DFT, anno 2022.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2022, "Volume": 24, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 28700, "End Page": 28781, "Article Number": null, "DOI": "10.1039/d2cp02827a", "DOI Link": "http://dx.doi.org/10.1039/d2cp02827a", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870798400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pun, GPP; Batra, R; Ramprasad, R; Mishin, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pun, G. P. Purja; Batra, R.; Ramprasad, R.; Mishin, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physically informed artificial neural networks for atomistic modeling of materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale atomistic computer simulations of materials heavily rely on interatomic potentials predicting the energy and Newtonian forces on atoms. Traditional interatomic potentials are based on physical intuition but contain few adjustable parameters and are usually not accurate. The emerging machine-learning (ML) potentials achieve highly accurate interpolation within a large DFT database but, being purely mathematical constructions, suffer from poor transferability to unknown structures. We propose a new approach that can drastically improve the transferability of ML potentials by informing them of the physical nature of interatomic bonding. This is achieved by combining a rather general physics-based model (analytical bond-order potential) with a neural-network regression. This approach, called the physically informed neural network (PINN) potential, is demonstrated by developing a general-purpose PINN potential for Al. We suggest that the development of physics-based ML potentials is the most effective way forward in the field of atomistic simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2339, "DOI": "10.1038/s41467-019-10343-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10343-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469221900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Y; Johnson, D; Peng, R; Hensley, DK; Bonnesen, PV; Liang, LB; Huang, JS; Yang, FC; Zhang, F; Qiao, R; Baddorf, AP; Tschaplinski, TJ; Engle, NL; Hatzell, MC; Wu, ZL; Cullen, DA; Meyer, HM ; Sumpter, BG; Rondinone, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Yang; Johnson, Daniel; Peng, Rui; Hensley, Dale K.; Bonnesen, Peter V.; Liang, Liangbo; Huang, Jingsong; Yang, Fengchang; Zhang, Fei; Qiao, Rui; Baddorf, Arthur P.; Tschaplinski, Timothy J.; Engle, nullcy L.; Hatzell, Marta C.; Wu, Zili; Cullen, David A.; Meyer, Harry M., III; Sumpter, Bobby G.; Rondinone, Adam J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A physical catalyst for the electrolysis of nitrogen to ammonia", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia synthesis consumes 3 to 5% of the world's natural gas, making it a significant contributor to greenhouse gas emissions. Strategies for synthesizing ammonia that are not dependent on the energy-intensive and methane-based Haber-Bosch process are critically important for reducing global energy consumption and minimizing climate change. Motivated by a need to investigate novel nitrogen fixation mechanisms, we herein describe a highly textured physical catalyst, composed of N-doped carbon nullospikes, that electrochemically reduces dissolved N-2 gas to ammonia in an aqueous electrolyte under ambient conditions. The Faradaic efficiency (FE) achieves 11.56 +/- 0.85% at -1.19 V versus the reversible hydrogen electrode, and the maximum production rate is 97.18 +/- 7.13 mu g hour(-1) cm(-2). The catalyst contains no noble or rare metals but rather has a surface composed of sharp spikes, which concentrates the electric field at the tips, thereby promoting the electroreduction of dissolved N-2 molecules near the electrode. The choice of electrolyte is also critically important because the reaction rate is dependent on the counterion type, suggesting a role in enhancing the electric field at the sharp spikes and increasing N-2 concentration within the Stern layer. The energy efficiency of the reaction is estimated to be 5.25% at the current FE of 11.56%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700336", "DOI": "10.1126/sciadv.1700336", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700336", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431374900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Liu, D; He, L; Qin, S; Wang, JM; Razal, JM; Kotov, NA; Lei, WW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Cheng; Liu, Dan; He, Li; Qin, Si; Wang, Jiemin; Razal, Joselito M.; Kotov, Nicholas A.; Lei, Weiwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-inspired nullocomposite Membranes for Osmotic Energy Harvesting", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Osmotic energy represents a widespread and reliable source of renewable energy with minimal daily variability. The key technological bottleneck for osmotic electricity is that membranes must combine highly efficient ion rectification and high ionic flux with long-term robustness in seawater. Here, we show that nullocomposite membranes with structural organization inspired by soft biological tissues with high mechanical and transport characteristics can address these problems. The layered membranes engineered with molecular-scale precision from aramid nullofibers and BN nullosheets simultaneously display high stiffness and tensile strength even when exposed to repeated pressure drops and salinity gradients. The total generated power density over large areas exceeded 0.6 W m(-2) and was retained for as long as 20 cycles (200 h), demonstrating exceptional robustness. Furthermore, the membranes showed high performance in osmotic energy harvesting in unprecedentedly wide ranges of temperature (0 degrees C-95 degrees C) and pH (2.8-10.8) essential for the economic viability of osmotic energy generators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2020, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 247, "End Page": 261, "Article Number": null, "DOI": "10.1016/j.joule.2019.11.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.11.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507640500022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faraji-Dana, M; Arbabi, E; Arbabi, A; Kamali, SM; Kwon, H; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faraji-Dana, MohammadSadegh; Arbabi, Ehsan; Arbabi, Amir; Kamali, Seyedeh Mahsa; Kwon, Hyounghan; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compact folded metasurface spectrometer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An optical design space that can highly benefit from the recent developments in metasurfaces is the folded optics architecture where light is confined between reflective surfaces, and the wavefront is controlled at the reflective interfaces. In this manuscript, we introduce the concept of folded metasurface optics by demonstrating a compact spectrometer made from a 1-mm-thick glass slab with a volume of 7 cubic millimeters. The spectrometer has a resolution of -1.2 nm, resolving more than 80 spectral points from 760 to 860 nm. The device is composed of three reflective dielectric metasurfaces, all fabricated in a single lithographic step on one side of a substrate, which simultaneously acts as the propagation space for light. The folded metasystem design can be applied to many optical systems, such as optical signal processors, interferometers, hyperspectral imagers, and computational optical systems, significantly reducing their sizes and increasing their mechanical robustness and potential for integration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4196, "DOI": "10.1038/s41467-018-06495-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06495-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446846600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HT; He, R; Mao, J; Zhu, Q; Li, CH; Sun, JF; Ren, WY; Wang, YM; Liu, ZH; Tang, ZJ; Sotnikov, A; Wang, ZM; Broido, D; Singh, DJ; Chen, G; Nielsch, K; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Hangtian; He, Ran; Mao, Jun; Zhu, Qing; Li, Chunhua; Sun, Jifeng; Ren, Wuyang; Wang, Yumei; Liu, Zihang; Tang, Zhongjia; Sotnikov, Andrei; Wang, Zhiming; Broido, David; Singh, David J.; Chen, Gang; Nielsch, Kornelius; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of ZrCoBi based half Heuslers with high thermoelectric conversion efficiency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric materials are capable of converting waste heat into electricity. The dimensionless figure-of-merit (ZT), as the critical measure for the material's thermoelectric performance, plays a decisive role in the energy conversion efficiency. Half-Heusler materials, as one of the most promising candidates for thermoelectric power generation, have relatively low ZTs compared to other material systems. Here we report the discovery of p-type ZrCoBibased half-Heuslers with a record-high ZT of similar to 1.42 at 973 K and a high thermoelectric conversion efficiency of similar to 9% at the temperature difference of similar to 500 K. Such an outstanding thermoelectric performance originates from its unique band structure offering a high band degeneracy (N-v) of 10 in conjunction with a low thermal conductivity benefiting from the low mean sound velocity (v(m) similar to 2800ms(-1)). Our work demonstrates that ZrCoBi-based half-Heuslers are promising candidates for high-temperature thermoelectric power generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 340, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2497, "DOI": "10.1038/s41467-018-04958-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04958-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436540700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, R; Morasch, R; Karayaylali, P; Phillips, K; Maglia, F; Stinner, C; Shao-Horn, Y; Gasteiger, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Roland; Morasch, Robert; Karayaylali, Pinar; Phillips, Katherine; Maglia, Filippo; Stinner, Christoph; Shao-Horn, Yang; Gasteiger, Hubert A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Ambient Storage on the Degradation of Ni-Rich Positive Electrode Materials (NMC811) for Li-Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered LiNi0.8Mn0.1Co0.1O2 (NMC811) is one of the high-energy positive electrode (cathode) materials for next generation Li-ion batteries. However, compared to the structurally similar LiNi1/3Mn1/3Co1/3O2 (NMC111), it can suffer from a shorter lifetime due to its higher surface reactivity. This work studied and compared the formation of surface contaminations on NMC811 and NMC111 when stored under ambient conditions using electrochemical cycling, Raman spectroscopy, and X-ray photoelectron spectroscopy. NMC811 was found to develop a surface layer of up to similar to 10 nm thickness that was mostly composed of nickel carbonate species mixed with minor quantities of hydroxide and water after ambient storage for 1 year, while no significant changes were observed on the NMC111 surface. The amount of carbonate species was quantified by gas chromatographic (GC) detection of carbon dioxide generated when the NMC particles were dispersed in hydrochloric acid. Surface impurity species formed on NMC811 upon ambient storage not only lead to a significant delithiation voltage peak in the first charge, but also markedly reduce the cycling stability of NMC811-graphite cells due to significantly growing polarization of the NMC811 electrode. (C) The Author(s) 2018. Published by ECS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 165, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A132", "End Page": "A141", "Article Number": null, "DOI": "10.1149/2.0401802jes", "DOI Link": "http://dx.doi.org/10.1149/2.0401802jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431786800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Xu, Y; Noh, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chuan; Xu, Yong; Noh, Yong-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contact engineering in organic field-effect transistors", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic field-effect transistors (OFETs) are promising for numerous potential applications but suffer from poor charge injection, such that their performance is severely limited. Recent efforts in lowering contact resistance have led to significantly improved field-effect mobility of OFETs, up to 100 times higher, as the results of careful choice of contact materials and/or chemical treatment of contact electrodes. Here we review the innovative developments of contact engineering and focus on the mechanisms behind them. Further improvement toward Ohmic contact can be expected along with the rapid advance in material research, which will also benefit other organic and electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 18, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 79, "End Page": 96, "Article Number": null, "DOI": "10.1016/j.mattod.2014.08.037", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2014.08.037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349625100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Heiden, A; Preninger, D; Lehner, L; Baumgartner, M; Drack, M; Woritzka, E; Schiller, D; Gerstmayr, R; Hartmann, F; Kaltenbrunner, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Heiden, A.; Preninger, D.; Lehner, L.; Baumgartner, M.; Drack, M.; Woritzka, E.; Schiller, D.; Gerstmayr, R.; Hartmann, F.; Kaltenbrunner, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of resilient biogels for omnidirectional and exteroceptive soft actuators", "Source Title": "SCIENCE ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft robotics greatly benefits from nature as a source of inspiration, introducing innate means of safe interaction between robotic appliances and living organisms. In contrast, the materials involved are often nonbiodegradable or stem from nonrenewable resources, contributing to an ever-growing environmental footprint. Furthermore, conventional manufacturing methods, such as mold casting, are not suitable for replicating or imitating the com-plexity of nature's creations. Consequently, the inclusion of sustainability concepts alongside the development of new fabrication procedures is required. We report a customized 3D-printing process based on fused deposition modeling, printing a fully biodegradable gelatin-based hydrogel (biogel) ink into dimensionally stable, complex objects. This process enables fast and cost-effective prototyping of resilient, soft robotic applications from gels that stretch to six times their original length, as well as an accessible recycling procedure with zero waste. We present printed pneumatic actuators performing omnidirectional movement at fast response times (less than a second), featuring integrated 3D-printed stretchable waveguides, capable of both proprio-and exteroception. These soft devices are endowed with dynamic real-time control capable of automated search-and-wipe routines to detect and remove obstacles. They can be reprinted several times or disposed of hazard-free at the end of their lifetime, potentially unlocking a sustainable future for soft robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2022, "Volume": 7, "Issue": 63, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabk2119", "DOI": "10.1126/scirobotics.abk2119", "DOI Link": "http://dx.doi.org/10.1126/scirobotics.abk2119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752135400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, F; Xue, HR; Yang, ZJ; Lai, KF; Yu, Y; Lin, X; Chong, YD; Shvets, G; Zhang, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Fei; Xue, Haoran; Yang, Zhaoju; Lai, Kueifu; Yu, Yang; Lin, Xiao; Chong, Yidong; Shvets, Gennady; Zhang, Baile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topologically protected refraction of robust kink states in valley photonic crystals", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently discovered(1,2) valley photonic crystals (VPCs) mimic many of the unusual properties of two-dimensional (2D) gapped valleytronic materials(3-9). Of the utmost interest to optical communications is their ability to support topologically protected chiral edge (kink) states(3-9) at the internal domain wall between two VPCs with opposite valley-Chern indices. Here we experimentally demonstrate valley-polarized kink states with polarization multiplexing in VPCs, designed from a spin-compatible four-band model. When the valley pseudospin is conserved, we show that the kink states exhibit nearly perfect out-coupling effciency into directional beams, through the intersection between the internal domain wall and the external edge separating the VPCs from ambient space. The out-coupling behaviour remains topologically protected even when we break the spin-like polarization degree of freedom (DOF), by introducing an effective spin-orbit coupling in one of the VPC domains. This also constitutes the first realization of spin-valley locking for topological valley transport.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 14, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 140, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS4304", "DOI Link": "http://dx.doi.org/10.1038/NPHYS4304", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423846600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, T; Chen, HS; Jia, ZA; Deng, ZF; Chen, LN; Peterman, EM; Weaver, JC; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Ting; Chen, Hongshun; Jia, Zian; Deng, Zhifei; Chen, Liuni; Peterman, Emily M.; Weaver, James C.; Li, Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A damage-tolerant, dual-scale, single-crystalline microlattice in the knobby starfish, Protoreaster nodosus", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cellular solids (e.g., foams and honeycombs) are widely found in natural and engineering systems because of their high mechanical efficiency and tailorable properties. While these materials are often based on polycrystalline or amorphous constituents, here we report an unusual dual-scale, single-crystalline microlattice found in the biomineralized skeleton of the knobby starfish, Protoreaster nodosus. This structure has a diamond-triply periodic minimal surface geometry (lattice constant, approximately 30 micrometers), the [111] direction of which is aligned with the c-axis of the constituent calcite at the atomic scale. This dual-scale crystallographically coaligned microlattice, which exhibits lattice-level structural gradients and dislocations, combined with the atomic-level conchoidal fracture behavior of biogenic calcite, substantially enhances the damage tolerance of this hierarchical biological microlattice, thus providing important insights for designing synthetic architected cellular solids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2022, "Volume": 375, "Issue": 6581, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 647, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj9472", "DOI Link": "http://dx.doi.org/10.1126/science.abj9472", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753975300035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zograf, G; Koshelev, K; Zalogina, A; Korolev, V; Hollinger, R; Choi, DY; Zuerch, M; Spielmann, C; Luther-Davies, B; Kartashov, D; Makarov, S; Kruk, SS; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zograf, George; Koshelev, Kirill; Zalogina, Anastasiia; Korolev, Viacheslav; Hollinger, Richard; Choi, Duk-Yong; Zuerch, Michael; Spielmann, Christian; Luther-Davies, Barry; Kartashov, Daniil; Makarov, Sergey, V; Kruk, Sergey S.; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Harmonic Generation from Resonullt Dielectric Metasurfaces Empowered by Bound States in the Continuum", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical bound states in the continuum (BICs) underpin the existence of strongly localized waves embedded into the radiation spectrum. Here we bring the concept of BICs to the field of high-harmonic generation and employ resonullt dielectric metasurfaces to generate efficiently optical harmonics up to the 11th order. We design BIC-resonullt metasurfaces with a broken in-plane symmetry for the lower harmonics and then observe a transition to the nonlinear regime for higher harmonics. Our approach bridges the fields of perturbative and nonperturbative nonlinear optics on the subwavelength scale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2022, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 567, "End Page": 574, "Article Number": null, "DOI": "10.1021/acsphotonics.1c01511", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.1c01511", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746417200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, C; Wang, JL; Sun, RX; Ali, T; Wang, HF; Xie, BB; Zhong, YJ; Hu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Cong; Wang, Jielei; Sun, Ruoxuan; Ali, Tariq; Wang, Hongfei; Xie, Bin-Bin; Zhong, Yijun; Hu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved Interfacial Ion Migration and Deposition through the Chain-Liquid Synergistic Effect by a Carboxylated Hydrogel Electrolyte for Stable Zinc Metal Anodes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large-scale applicability of Zn-metal anodes is severely impeded by the issues such as the dendrite growth, complicated hydrogen evolution, and uncontrollable passivation reaction. Herein, a negatively charged carboxylated double-network hydrogel electrolyte (Gelatin/Sodium alginate-acetate, denoted as Gel/SA-acetate) has been developed to stabilize the interfacial electrochemistry, which restructures a type of Zn2+ ion solvent sheath optimized via a chain-liquid synergistic effect. New hydrogen bonds are reconstructed with water molecules by the zincophilic functional groups, and directional migration of hydrated Zn2+ ions is therefore induced. Concomitantly, the robust chemical bonding of such hydrogel layers to the Zn slab exhibits a desirable anti-catalytic effect, thereby greatly diminishing the water activity and eliminating side reactions. Subsequently, a symmetric cell using the Gel/SA-acetate electrolyte demonstrates a reversible plating/stripping performance for 1580 h, and an asymmetric cell reaches a state-of-the-art runtime of 5600 h with a high average Coulombic efficiency of 99.9 %. The resultant zinc ion hybrid capacitors deliver exceptional properties including the capacity retention of 98.5 % over 15000 cycles, energy density of 236.8 Wh kg-1, and high mechanical adaptability. This work is expected to pave a new avenue for the development of novel hydrogel electrolytes towards safe and stable Zn anodes. An innovative double-network carboxylated hydrogel electrolyte was designed to stabilize zinc anode. The charged functional groups on polymer chains synergize with liquid phase components to reconstruct the solvent sheath and guide the directional migration of Zn2+ ions. The robust chemical bonding of hydrogel layer to Zn slab induces a dendrite-free plating behavior, ultimately ensuring the long-term operation of zinc ion hybrid capacitors.+image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2023, "Volume": 62, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202310970", "DOI Link": "http://dx.doi.org/10.1002/anie.202310970", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001060394900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, J; Tang, H; Huang, JM; Yan, CQ; Liu, K; Yang, QG; Hu, DQ; Singh, R; Lee, J; Lu, SR; Li, G; Kan, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Jie; Tang, Hua; Huang, Jiaming; Yan, Cenqi; Liu, Kuan; Yang, Qianguang; Hu, Dingqin; Singh, Ranbir; Lee, Jawon; Lu, Shirong; Li, Gang; Kan, Zhipeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive-induced miscibility regulation and hierarchical morphology enable 17.5% binary organic solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves an excellent power conversion efficiency (PCE) of 15.7%. However, the deficient hole transfer from Y6 to PM6 limits the further enhancement of the device performance. Herein, we demonstrate an additive-induced miscibility and morphology control strategy to achieve the balance of exciton dissociation and charge collection, prompting an increase in the PCE of OSCs composed of PM6:Y6 from 15.7% to 17.5%, which stands as the top PCE value of PM6:Y6 binary OSCs. The external quantum efficiency (EQE) of the optimal device significantly improves in the wavelength range where Y6 harvests photons. Therefore, the short-circuit current density (J(SC)) was enhanced to 26.98 mA cm(-2), achieving 94.4% of the maximum theoretical J(SC) obtained from the identical device configuration. The remarkable performance enhancement mainly results from the miscibility-driven donor and acceptor phase optimization with hierarchical morphology formation, leading to the improved photon-to-electron response of the Y6 phase, enhanced and balanced charge extraction and collection. Our findings highlight the significance of morphology control towards unleashing the full potential of OSC materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2021, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3044, "End Page": 3052, "Article Number": null, "DOI": "10.1039/d0ee04012f", "DOI Link": "http://dx.doi.org/10.1039/d0ee04012f", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000644940400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chmiela, S; Tkatchenko, A; Sauceda, HE; Poltavsky, I; Schütt, KT; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chmiela, Stefan; Tkatchenko, Alexandre; Sauceda, Huziel E.; Poltavsky, Igor; Schuett, Kristof T.; Mueller, Klaus-Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning of accurate energy-conserving molecular force fields", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using conservation of energy-a fundamental property of closed classical and quantum mechanical systems-we develop an efficient gradient-domain machine learning (GDML) approach to construct accurate molecular force fields using a restricted number of samples from ab initio molecular dynamics (AIMD) trajectories. The GDML implementation is able to reproduce global potential energy surfaces of intermediate-sized molecules with an accuracy of 0.3 kcal mol(-1) for energies and 1 kcal mol(-1) angstrom(-1) for atomic forces using only 1000 conformational geometries for training. We demonstrate this accuracy for AIMD trajectories of molecules, including benzene, toluene, naphthalene, ethanol, uracil, and aspirin. The challenge of constructing conservative force fields is accomplished in our work by learning in a Hilbert space of vector-valued functions that obey the law of energy conservation. The GDML approach enables quantitative molecular dynamics simulations for molecules at a fraction of cost of explicit AIMD calculations, thereby allowing the construction of efficient force fields with the accuracy and transferability of high-level ab initio methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 852, "Times Cited, All Databases": 949, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1603015, "DOI": "10.1126/sciadv.1603015", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401955300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chou, SF; Carson, D; Woodrow, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chou, Shih-Feng; Carson, Daniel; Woodrow, Kim A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current strategies for sustaining drug release from electrospun nullofibers", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrospun drug-eluting fibers are emerging as a novel dosage form for multipurpose prevention against sexually transmitted infections, including HIV, and unintended pregnullcy. Previous work from our lab and others show the versatility of this platform to deliver large doses of physico-chemically diverse agents. However, there is still an unmet need to develop practical fiber formulations for water-soluble small molecule drugs needed at high dosing due to intrinsic low potency or desire for sustained prevention. To date, most sustained release fibers have been restricted to the delivery of biologics or hydrophobic small molecules at low drug loading of typically <1 wt.%, which is often impractical for most clinical applications. For hydrophilic small molecule drugs, their high aqueous solubility and poor partitioning and incompatibility with insoluble polymers make long-term release even more challenging. Here we investigate several existing strategies to sustain release of hydrophilic small molecule drugs that are highly-loaded in electrospun fibers. In particular, we investigate what is known about the design constraints required to realize multi-day release from fibers fabricated from uniaxial and coaxial electrospinning. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2015, "Volume": 220, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 584, "End Page": 591, "Article Number": null, "DOI": "10.1016/j.jconrel.2015.09.008", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2015.09.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368021100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, SQ; Li, TH; Cai, WB; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Shangqian; Li, Tiehuai; Cai, Wen-Bin; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO2 Electrochemical Reduction As Probed through Infrared Spectroscopy", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 electrochemical reduction shows great promise in storing renewable energy and alleviating global warming. Its large-scale applications in the industry, however, are still in infancy mainly due to the unsatisfactory performance of electrocatalysts. Rational design of advanced electrocatalysts would be the ultimate solution, which has yet to be achieved currently because of the lack of understandings of reaction mechanisms. In the past few years, in situ attenuated total reflection infrared (ATR-IR) spectroscopy has been successfully adopted to study the electrochemical interface of the CO2 reduction reaction (CO2RR) and significantly advanced our understandings of this reaction. In this Perspective, these advances as well as the challenges and opportunities faced in further studying CO2RR by this technique are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 682, "End Page": 689, "Article Number": null, "DOI": "10.1021/acsenergylett.8b02525", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b02525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461271600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mayyas, A; Steward, D; Mann, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mayyas, Ahmad; Steward, Darlene; Mann, Margaret", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The case for recycling: Overview and challenges in the material supply chain for automotive li-ion batteries", "Source Title": "SUSTAINABLE MATERIALS AND TECHNOLOGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium ion batteries (LIB) continue to gain market share in response to the increasing demand for electric vehicles, consumer electronics, and energy storage. The increased demand for LIB has highlighted potential problems in the supply chain of raw materials needed for their manufacture. Some critical metals used in LIB, namely lithium, cobalt, and graphite are scarce, are not currently mined in large quantities, or are mined in only a few countries whose trade policies could limit availability and impact prices. The environmental and social impacts of mining these materials have also drawn attention as production ramps up to meet the increased demand. Closed-loop systems with recycling at the end-of-life provide a pathway to lower environmental impacts and a source of high value materials that can be used in producing new batteries. Because environmental regulations concerning end-of-life batteries are not fully developed or implemented, most of these batteries currently end up in the landfills, with a very small number of spent batteries sent to the existing recycling facilities. However, with proactive regulations, an increasing supply of spent batteries, and innovations in recycling technologies, end-of-life batteries could supply a significant fraction of the materials needed for manufacturing of new LIB. This paper reviews the current state of the LIB manufacturing supply chain, addresses some issues associated with battery end-of-life, and sheds light on the importance of LIB recycling from the environmental and value chain perspectives. We also discuss the expected benefits of recycling on the global LIB supply chain. (C) 2018 Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e00087", "DOI": "10.1016/j.susmat.2018.e00087", "DOI Link": "http://dx.doi.org/10.1016/j.susmat.2018.e00087", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459835700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, SH; Alpeggiani, F; Sciacca, B; Garnett, EC; Kuipers, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Su-Hyun; Alpeggiani, Filippo; Sciacca, Beniamino; Garnett, Erik C.; Kuipers, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale chiral valley-photon interface through optical spin-orbit coupling", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of two-dimensional transition metal dichalcogenide materials has sparked intense activity in valleytronics, as their valley information can be encoded and detected with the spin angular momentum of light. We demonstrate the valley-dependent directional coupling of light using a plasmonic nullowire-tungsten disulfide (WS2) layers system. We show that the valley pseudospin in WS2 couples to transverse optical spin of the same handedness with a directional coupling efficiency of 90 +/- 1%. Our results provide a platform for controlling, detecting, and processing valley and spin information with precise optical control at the nulloscale.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2018, "Volume": 359, "Issue": 6374, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 443, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aan8010", "DOI Link": "http://dx.doi.org/10.1126/science.aan8010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423283200043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HY; Yi, J; Li, MY; Xiao, J; Zhang, LF; Yang, CW; Kaindl, RA; Li, LJ; Wang, Y; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Hanyu; Yi, Jun; Li, Ming-Yang; Xiao, Jun; Zhang, Lifa; Yang, Chih-Wen; Kaindl, Robert A.; Li, Lain-Jong; Wang, Yuan; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of chiral phonons", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2018, "Volume": 359, "Issue": 6375, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 579, "End Page": 581, "Article Number": null, "DOI": "10.1126/science.aar2711", "DOI Link": "http://dx.doi.org/10.1126/science.aar2711", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423795800043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdolmaleki, H; Haugen, AB; Buhl, KB; Daasbjerg, K; Agarwala, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdolmaleki, Hamed; Haugen, Astri Bjornetun; Buhl, Kristian Birk; Daasbjerg, Kim; Agarwala, Shweta", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Engineering of PVDF-TrFE toward Higher Piezoelectric, Ferroelectric, and Dielectric Performance for Sensing and Energy Harvesting Applications", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrical properties of pristine fluoropolymers are inferior due to their low polar crystalline phase content and rigid dipoles that tend to retain their fixed moment and orientation. Several strategies, such as electrospinning, electrohydrodynamic pulling, and template-assisted growing, have been proven to enhance the electrical properties of fluoropolymers; however, these techniques are mostly very hard to scale-up and expensive. Here, a facile interfacial engineering approach based on amine-functionalized graphene oxide (AGO) is proposed to manipulate the intermolecular interactions in poly(vinylidenefluoride-trifluoroethylene) (PVDF-TrFE) to induce beta-phase formation, enlarge the lamellae dimensions, and align the micro-dipoles. The coexistence of primary amine and hydroxyl groups on AGO nullosheets offers strong hydrogen bonding with fluorine atoms, which facilitates domain alignment, resulting in an exceptional remnullt polarization of 11.3 mu C cm(-2). PVDF-TrFE films with 0.1 wt.% AGO demonstrate voltage coefficient, energy density, and energy-harvesting figure of merit values of 0.30 Vm N-1, 4.75 J cm(-3), and 14 pm(3) J(-1), respectively, making it outstanding compared with state-of-the-art ceramic-free ferroelectric films. It is believed that this work can open-up new insights toward structural and morphological tailoring of fluoropolymers to enhance their electrical and electromechanical performance and pave the way for their industrial deployment in next-generation wearables and human-machine interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205942", "DOI Link": "http://dx.doi.org/10.1002/advs.202205942", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906450800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, ZY; Wang, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "XU, Zhengyang; WANG, Yudi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical machining of complex components of aero-engines: Developments, trends, and technological advances", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Because of several advantages, such as no tool wear, independence on the mechanical properties of the material, and high machining efficiency, electrochemical machining (ECM) has become a viable method for machining components in numerous industrial applications, particularly in the manufacture of typical aero-engine components with complex structures fabricated from materials that are difficult to cut. This paper highlights the current developments, new trends, and technological advances of key factors of ECM, such as electrochemical dissolution characteristics of novel difficult to cut materials which are often used in aero-engine, numerical simulation of electrochemical process, design for the complex profile and structure of cathode tool, flow field simulation and design for uniform electrolyte flow, and innovation of electrochemical machining or hybrid methods which reflect the state of the art in academic and industrial research on electrochemical machining in aero-engine manufacturing. (c) 2019 Chinese Society of Aeronautics and Astronautics. Production and hosting by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 34, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 28, "End Page": 53, "Article Number": null, "DOI": "10.1016/j.cja.2019.09.016", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2019.09.016", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000635646700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wilson, NR; Nguyen, PV; Seyler, K; Rivera, P; Marsden, AJ; Laker, ZPL; Constantinescu, GC; Kandyba, V; Barinov, A; Hine, NDM; Xu, XD; Cobden, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wilson, Neil R.; Nguyen, Paul V.; Seyler, Kyle; Rivera, Pasqual; Marsden, Alexander J.; Laker, Zachary P. L.; Constantinescu, Gabriel C.; Kandyba, Viktor; Barinov, Alexei; Hine, Nicholas D. M.; Xu, Xiaodong; Cobden, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of band offsets, hybridization, and exciton binding in 2D semiconductor heterostructures", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining monolayers of different two-dimensional semiconductors into heterostructures creates new phenomena and device possibilities. Understanding and exploiting these phenomena hinge on knowing the electronic structure and the properties of interlayer excitations. We determine the key unknown parameters in MoSe2/WSe2 heterobilayers by using rational device design and submicrometer angle-resolved photoemission spectroscopy (m-ARPES) in combination with photoluminescence. We find that the bands in the K-point valleys are weakly hybridized, with a valence band offset of 300 meV, implying type II band alignment. We deduce that the binding energy of interlayer excitons is more than 200 meV, an order of magnitude higher than that in analogous GaAs structures. Hybridization strongly modifies the bands at G, but the valence band edge remains at the K points. We also find that the spectrum of a rotationally aligned heterobilayer reflects a mixture of commensurate and incommensurate domains. These results directly answer many outstanding questions about the electronic nature of MoSe2/WSe(2)x heterobilayers and demonstrate a practical approach for high spectral resolution in ARPES of device-scale structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601832", "DOI": "10.1126/sciadv.1601832", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601832", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397039500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trahey, L; Brushett, FR; Balsara, NP; Ceder, G; Cheng, L; Chiang, YM; Hahn, NT; Ingram, BJ; Minteer, SD; Moore, JS; Mueller, KT; Nazar, LF; Persson, KA; Siegel, DJ; Xu, K; Zavadil, KR; Srinivasan, V; Crabtree, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trahey, Lynn; Brushett, Fikile R.; Balsara, Nitash P.; Ceder, Gerbrand; Cheng, Lei; Chiang, Yet-Ming; Hahn, Nathan T.; Ingram, Brian J.; Minteer, Shelley D.; Moore, Jeffrey S.; Mueller, Karl T.; Nazar, Linda F.; Persson, Kristin A.; Siegel, Donald J.; Xu, Kang; Zavadil, Kevin R.; Srinivasan, Venkat; Crabtree, George W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy storage emerging: A perspective from the Joint Center for Energy Storage Research", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy storage is an integral part of modern society. A contemporary example is the lithium (Li)-ion battery, which enabled the launch of the personal electronics revolution in 1991 and the first commercial electric vehicles in 2010. Most recently, Li-ion batteries have expanded into the electricity grid to firm variable renewable generation, increasing the efficiency and effectiveness of transmission and distribution. Important applications continue to emerge including decarbonization of heavy-duty vehicles, rail, maritime shipping, and aviation and the growth of renewable electricity and storage on the grid. This perspective compares energy storage needs and priorities in 2010 with those now and those emerging over the next few decades. The diversity of demands for energy storage requires a diversity of purpose-built batteries designed to meet disparate applications. Advances in the frontier of battery research to achieve transformative performance spanning energy and power density, capacity, charge/discharge times, cost, lifetime, and safety are highlighted, along with strategic research refinements made by the Joint Center for Energy Storage Research (JCESR) and the broader community to accommodate the changing storage needs and priorities. Innovative experimental tools with higher spatial and temporal resolution, in situ and operando characterization, first-principles simulation, high throughput computation, machine learning, and artificial intelligence work collectively to reveal the origins of the electrochemical phenomena that enable new means of energy storage. This knowledge allows a constructionist approach to materials, chemistries, and architectures, where each atom or molecule plays a prescribed role in realizing batteries with unique performance profiles suitable for emergent demands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2020, "Volume": 117, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12550, "End Page": 12557, "Article Number": null, "DOI": "10.1073/pnas.1821672117", "DOI Link": "http://dx.doi.org/10.1073/pnas.1821672117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545947700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Choi, YM; Yoo, S; Ding, Y; Yan, RQ; Pei, K; Qu, C; Zhang, L; Chang, I; Zhao, BT; Zhang, YX; Chen, HJ; Chen, Y; Yang, CH; deGlee, B; Murphy, R; Liu, J; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yu; Choi, YongMan; Yoo, Seonyoung; Ding, Yong; Yan, Ruiqiang; Pei, Kai; Qu, Chong; Zhang, Lei; Chang, Ikwhang; Zhao, Bote; Zhang, Yanxiang; Chen, Huijun; Chen, Yan; Yang, Chenghao; deGlee, Ben; Murphy, Ryan; Liu, Jiang; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work demonstrates that a multi-phase catalyst coating (similar to 30 nm thick), composed of BaCoO3-x (BCO) and PrCoO3-x (PCO) nulloparticles (NPs) and a conformal PrBa0.8Ca0.2CO2O5+delta (PBCC) thin film, has dramatically enhanced the rate of oxygen reduction reaction (ORR). When applied to a state-of-theart La0.6Sr0.4Co0.2Fe0.8O3 (LSCF) cathode in a solid oxide fuel cell (SOFC), the catalyst coating reduced the cathodic polarization resistance from 2.57 to 0.312 Omega cm(2) at 600 degrees C. Oxygen molecules adsorb and dissociate rapidly on the NPs due to enriched surface oxygen vacancies and then quickly transport through the PBCC film, as confirmed by density functional theory-based computations. The synergistic combination of the distinctive properties of the two separate phases dramatically enhances the ORR kinetics, which is attractive not only for intermediate-temperature SOFCs but also for other types of energy conversion and storage systems, including electrolysis cells and membrane reactors for synthesis of clean fuels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 938, "End Page": 949, "Article Number": null, "DOI": "10.1016/j.joule.2018.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.02.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435093800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZF; Rhodes, DA; Watanabe, K; Taniguchi, T; Hone, JC; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zefang; Rhodes, Daniel A.; Watanabe, Kenji; Taniguchi, Takashi; Hone, James C.; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence of high-temperature exciton condensation in two-dimensional atomic double layers", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Bose-Einstein condensate is the ground state of a dilute gas of bosons, such as atoms cooled to temperatures close to absolute zero(1). With much smaller mass, excitons (bound electron-hole pairs) are expected to condense at considerably higher temperatures(2-7). Two-dimensional van der Waals semiconductors with very strong exciton binding are ideal systems for the study of high-temperature exciton condensation. Here we study electrically generated interlayer excitons in MoSe2-WSe2 atomic double layers with a density of up to 10(12) excitons per square centimetre. The interlayer tunnelling current depends only on the exciton density, which is indicative of correlated electron-hole pair tunnelling(8). Strong electroluminescence arises when a hole tunnels from WSe2 to recombine with an electron in MoSe2. We observe a critical threshold dependence of the electroluminescence intensity on exciton density, accompanied by super-Poissonian photon statistics near the threshold, and a large electroluminescence enhancement with a narrow peak at equal electron and hole densities. The phenomenon persists above 100 kelvin, which is consistent with the predicted critical condensation temperature(9-12). Our study provides evidence for interlayer exciton condensation in two-dimensional atomic double layers and opens up opportunities for exploring condensate-based optoelectronics and exciton-mediated high-temperature superconductivity(13).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2019, "Volume": 574, "Issue": 7776, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1591-7", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1591-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488832500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, BF; Yao, WJ; Zheng, YP; Kidkhunthod, P; Zhou, XL; Tunmee, S; Sattayaporn, S; Cheng, HM; He, HY; Tang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Bifa; Yao, Wenjiao; Zheng, Yongping; Kidkhunthod, Pinit; Zhou, Xiaolong; Tunmee, Sarayut; Sattayaporn, Suchinda; Cheng, Hui-Ming; He, Haiyan; Tang, Yongbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fluoroxalate cathode material for potassium-ion batteries with ultra-long cyclability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries are a compelling technology for large scale energy storage due to their low-cost and good rate performance. However, the development of potassium-ion batteries remains in its infancy, mainly hindered by the lack of suitable cathode materials. Here we show that a previously known frustrated magnet, KFeC2O4F, could serve as a stable cathode for potassium ion storage, delivering a discharge capacity of similar to 112 mAh g(-1) at 0.2 A g(-1) and 94% capacity retention after 2000 cycles. The unprecedented cycling stability is attributed to the rigid framework and the presence of three channels that allow for minimized volume fluctuation when Fe2+/Fe3+ redox reaction occurs. Further, pairing this KFeC2O4F cathode with a soft carbon anode yields a potassium-ion full cell with an energy density of similar to 235Wh kg(-1), impressive rate performance and negligible capacity decay within 200 cycles. This work sheds light on the development of low-cost and high-performance K-based energy storage devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1225, "DOI": "10.1038/s41467-020-15044-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15044-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549162600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sulley, GS; Gregory, GL; Chen, TTD; Carrodeguas, LP; Trott, G; Santmarti, A; Lee, KY; Terrill, NJ; Williams, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sulley, Gregory S.; Gregory, Georgina L.; Chen, Thomas T. D.; Carrodeguas, Leticia Pena; Trott, Gemma; Santmarti, Alba; Lee, Koon-Yang; Terrill, Nicholas J.; Williams, Charlotte K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives, Elastomers, and Toughened Plastics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide/epoxide copolymerization is an efficient way to add value to waste CO2 and to reduce pollution in polymer manufacturing. Using this process to make low molar mass polycarbonate polyols is a commercially relevant route to new thermosets and polyurethanes. In contrast, high molar mass polycarbonates, produced from CO2, generally under-deliver in terms of properties, and one of the most widely investigated, poly(cyclohexene carbonate), is limited by its low elongation at break and high brittleness. Here, a new catalytic polymerization process is reported that selectively and efficiently yields degradable ABA-block polymers, incorporating 6-23 wt % CO2. The polymers are synthesized using a new, highly active organometallic heterodinuclear Zn(II)/Mg(II) catalyst applied in a one-pot procedure together with biobased e-decalactone, cyclohexene oxide, and carbon dioxide to make a series of poly(cyclohexene carbonate-b-decalactone-b-cyclohexene carbonate) [PCHC-PDL-PCHC]. The process is highly selective (CO2 selectivity >99% of theoretical value), allows for high monomer conversions (>90%), and yields polymers with predictable compositions, molar mass (from 38-71 kg mol(-1)), and forms dihydroxyl telechelic chains. These new materials improve upon the properties of poly(cyclohexene carbonate) and, specifically, they show good thermal stability (T-d,T-S similar to 280 degrees C), high toughness (112 MJ m(-3)), and very high elongation at break (>900%). Materials properties are improved by precisely controlling both the quantity and location of carbon dioxide in the polymer chain. Preliminary studies show that polymers are stable in aqueous environments at room temperature over months, but they are rapidly degraded upon gentle heating in an acidic environment (60 degrees C, toluene, p-toluene sulfonic acid). The process is likely generally applicable to many other lactones, lactides, anhydrides, epoxides, and heterocumulenes and sets the scene for a host of new applications for CO2-derived polymers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2020, "Volume": 142, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4367, "End Page": 4378, "Article Number": null, "DOI": "10.1021/jacs.9b13106", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b13106", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518700800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, Z; Wei, KC; Wang, QX; Kim, MJ; Sun, SH; Fung, V; Xia, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Zheng; Wei, Kecheng; Wang, Qingxiao; Kim, Moon J.; Sun, Shouheng; Fung, Victor; Xia, Xiaohu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel-Platinum nulloparticles as Peroxidase Mimics with a Record High Catalytic Efficiency", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While nulloscale mimics of peroxidase have been extensively developed over the past decade or so, their catalytic efficiency as a key parameter has not been substantially improved in recent years. Herein, we report a class of highly efficient peroxidase mimic-nickel-platinum nulloparticles (Ni-Pt NPs) that consist of nickel-rich cores and platinum-rich shells. The Ni-Pt NPs exhibit a record high catalytic efficiency with a catalytic constant (K-cat) as high as 4.5 x 10(7) s(-1), which is similar to 46- and 10(4)-fold greater than the K-cat values of conventional Pt nulloparticles and natural peroxidases, respectively. Density functional theory calculations reveal that the unique surface structure of Ni-Pt NPs weakens the adsorption of key intermediates during catalysis, which boosts the catalytic efficiency. The Ni-Pt NPs were applied to an immunoassay of a carcinoembryonic antigen that achieved an ultralow detection limit of 1.1 pg/mL, hundreds of times lower than that of the conventional enzyme-based assay.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2021, "Volume": 143, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2660, "End Page": 2664, "Article Number": null, "DOI": "10.1021/jacs.0c12605", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c12605", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623246000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, XQ; Song, SJ; Cai, WW; Luo, X; Jiao, L; Fang, Q; Wang, XS; Wu, NN; Luo, Z; Wang, HJ; Zhu, ZH; Li, J; Zheng, LR; Gu, WL; Song, WY; Guo, SJ; Zhu, CZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Xiaoqian; Song, Shaojia; Cai, Weiwei; Luo, Xin; Jiao, Lei; Fang, Qie; Wang, Xiaosi; Wu, nullnull; Luo, Zhen; Wang, Hengjia; Zhu, Zhihong; Li, Jing; Zheng, Lirong; Gu, Wenling; Song, Weiyu; Guo, Shaojun; Zhu, Chengzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the spin state of Fe single atoms by Pd nulloclusters enables robust oxygen reduction with dissociative pathway", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of Fe single-atom catalysts is greatly impeded by their lower oxygen reduction reaction (ORR) performance in acid electrolytes when compared with Pt/C catalyst. Herein, we report an unprecedented ORR catalyst consisting of Pd nulloclusters (PdNC) and Fe single atoms (Fe-N-C/PdNC). Experimental investiga-tions and theoretical calculations indicate that the enhanced ORR activity results from the PdNC-induced spin-state transition of Fe(II) from low spin to intermediate spin, activating O-O bond through the side-on overlapping and achieving the pathway transition from associative to dissociative process. The over-binding of OH* can be facilely released to suppress the site-blocking effect and accel-erate the removal of OH*. In acid conditions, Fe-N-C/PdNC exhibits excellent ORR performance with impressive half-wave potential (0.87 V), insignificant decay after 30,000 cycles, and a high maximum power density of 920 mW/cm2 in fuel cell, superior to Pt/C catalyst. This work provides an efficient pathway to design non-Pt catalysts through the spin-regulation strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 181, "End Page": 197, "Article Number": null, "DOI": "10.1016/j.chempr.2022.10.001", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2022.10.001", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991423800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MH; Song, N; Luo, W; Chen, J; Jiang, W; Yang, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Minhan; Song, null; Luo, Wei; Chen, Jun; Jiang, Wan; Yang, Jianping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Surface Oxophilicity of Copper for Electrochemical CO2 Reduction to Ethanol", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-based materials are known for converting CO2 into deep reduction products via electrochemical reduction reaction (CO2RR). As the major multicarbon products (C2+), ethanol (C2H5OH) and ethylene (C2H4) are believed to share a common oxygenic intermediate according to theoretical studies, while the key factors that bifurcate C2H5OH and C2H4 pathways on Cu-based catalysts are not fully understood. Here, a surface oxophilicity regulation strategy to enhance C2H5OH production in CO2RR is proposed, demonstrated by a Cu-Sn bimetallic system. Compared with bare Cu catalyst, the Cu-Sn bimetallic catalysts show improved C2H5OH but suppressed C2H4 selectivity. The experimental results and theoretical calculations demonstrate that the surface oxophilicity of Cu-Sn catalysts plays an important role in steering the protonation of the key oxygenic intermediate and guides the reaction pathways to C2H5OH. This study provides new insights into the electrocatalyst design for enhanced production of oxygenic products from CO2RR by engineering the surface oxophilicity of copper-based catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202204579", "DOI Link": "http://dx.doi.org/10.1002/advs.202204579", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888394700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, L; Wu, FC; Hou, SC; Zhang, Z; Chou, YH; Watanabe, K; Taniguchi, T; Forrest, SR; Deng, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Long; Wu, Fengcheng; Hou, Shaocong; Zhang, Zhe; Chou, Yu-Hsun; Watanabe, Kenji; Taniguchi, Takashi; Forrest, Stephen R.; Deng, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals heterostructure polaritons with moire-induced nonlinearity", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling matter-light interactions with cavities is of fundamental importance in modern science and technology(1). This is exemplified in the strong-coupling regime, where matter-light hybrid modes form, with properties that are controllable by optical-wavelength photons(2,3). By contrast, matter excitations on the nullometre scale are harder to access. In two-dimensional van der Waals heterostructures, a tunable moire lattice potential for electronic excitations may form(4), enabling the generation of correlated electron gases in the lattice potentials(5-9). Excitons confined in moire lattices have also been reported(10,11), but no cooperative effects have been observed and interactions with light have remained perturbative(12-15). Here, by integrating MoSe2-WS2 heterobilayers in a microcavity, we establish cooperative coupling between moire-lattice excitons and microcavity photons up to the temperature of liquid nitrogen, thereby integrating versatile control of both matter and light into one platform. The density dependence of the moire polaritons reveals strong nonlinearity due to exciton blockade, suppressed exciton energy shift and suppressed excitation-induced dephasing, all of which are consistent with the quantum confined nature of the moire excitons. Such a moire polariton system combines strong nonlinearity and microscopic-scale tuning of matter excitations using cavity engineering and long-range light coherence, providing a platform with which to study collective phenomena from tunable arrays of quantum emitters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2021, "Volume": 591, "Issue": 7848, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 61, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03228-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03228-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626921700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, WJ; Shi, Z; Huang, MJ; Feng, ST; Wang, C; Wang, F; Lopez, J; Qiao, B; Xu, GY; Zhang, WX; Dong, YH; Gao, R; Shao-Horn, Y; Johnson, JA; Li, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Weijiang; Shi, Zhe; Huang, Mingjun; Feng, Shuting; Wang, Chao; Wang, Fei; Lopez, Jeffrey; Qiao, Bo; Xu, Guiyin; Zhang, Wenxu; Dong, Yanhao; Gao, Rui; Shao-Horn, Yang; Johnson, Jeremiah A.; Li, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FSI-inspired solvent and full fluorosulfonyl electrolyte for 4 V class lithium-metal batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-voltage rechargeable lithium-metal batteries (LMBs) require electrolytes that are compatible with both the Li metal anode (LMA) and the metal-oxide cathode. Herein, by imitating the fluorosulfonyl imide group from a well-known LMA-compatible salt, lithium bis(fluorosulfonyl) imide (LiFSI), we come up with an organic solvent dimethylsulfamoyl fluoride (FSO2NC2H6), a fluorosulfonamide (FSA) with two methyl substituents, to develop a new full fluorosulfonyl (FFS) electrolyte. Remarkably, it enables a highly reversible LMA with an excellent initial coulombic efficiency (CE) similar to 91%, and rapidly approaching 99% within only 10 cycles, with average CE outperforming the well-known LMA-compatible fluoroethylene carbonate (FEC)-based electrolyte. Furthermore, benefitting from its high anodic stability against the oxidative LiNi0.6Mn0.2Co0.2O2 (NMC622) and LiMn2O4 (LMO) surfaces, the Li||NMC622 cell retains 89% of its original capacity after 200 cycles using a limited Li excess anode. This electrolyte design strategy opens a new avenue for exploring new medium-concentration organic electrolytes for 4 V class lithium-metal batteries (LMBs).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 220, "Article Number": null, "DOI": "10.1039/c9ee02538c", "DOI Link": "http://dx.doi.org/10.1039/c9ee02538c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508857600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barchiesi, E; Spagnuolo, M; Placidi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barchiesi, Emilio; Spagnuolo, Mario; Placidi, Luca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical metamaterials: a state of the art", "Source Title": "MATHEMATICS AND MECHANICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, we give a review of the state of the art in the study of mechanical metamaterials. The very attractive property of having a microstructure capable of determining exotic and specifically tailored macroscopic behaviour makes the study of metamaterials a field that is actually in expansion, from both a theoretical and a technological point of view. This work is divided into two sections, describing the phenomenological and theoretical aspects of metamaterials. We first give an overview of some existing metamaterials, such as pentamode materials, auxetic materials, materials with negative mechanical constitutive coefficients and materials with enhanced mechanical properties. We also focus on some emerging areas, such as origami. Then, we present some theoretical studies in the field of mechanical metamaterials, such as those related to first- and second-gradient theories.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 24, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 234, "Article Number": null, "DOI": "10.1177/1081286517735695", "DOI Link": "http://dx.doi.org/10.1177/1081286517735695", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454517400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, V; Yang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vy Tran; Yang, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling laws for the band gap and optical response of phosphorene nulloribbons", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the electronic structure and optical absorption spectra of monolayer black phosphorus (phosphorene) nulloribbons (PNRs) via first-principles simulations. The band gap of PNRs is strongly enhanced by quantum confinement. However, differently orientated PNRs exhibit distinct scaling laws for the band gap vs the ribbon width omega. The band gaps of armchair PNRs scale as 1/omega(2), while zigzag PNRs exhibit a 1/omega behavior. These distinct scaling laws reflect a significant implication of the band dispersion of phosphorene: electrons and holes behave as nonrelativistic particles along the zigzag direction but resemble relativistic particles along the armchair direction. This unexpected merging of nonrelativistic and relativistic properties in a single material may produce novel electrical and magnetotransport properties of few-layer black phosphorus and its ribbon structures. Finally, the respective PNRs host electrons and holes with markedly different effective masses and optical absorption spectra, which are suitable for a wide range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2014, "Volume": 89, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 245407, "DOI": "10.1103/PhysRevB.89.245407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.245407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336976400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, Y; Wang, ZY; Owens, ACE; Kulaots, I; Chen, YT; Kane, AB; Hurt, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Yang; Wang, Zhongying; Owens, Alisa C. E.; Kulaots, Indrek; Chen, Yantao; Kane, Agnes B.; Hurt, Robert H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antioxidant chemistry of graphene-based materials and its role in oxidation protection technology", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional nullomaterials have potential as a new class of antioxidants that combine physical barrier function with ultrahigh surface area for free radical scavenging. This work presents the first measurements of the chemical reactivities of graphene-based materials toward a set of model free radicals and reactive oxygen species using electron paramagnetic resonullce spectroscopy (EPR) and sacrificial dye protection assays. Graphene-based materials are shown to protect a variety of molecular targets from oxidation by these species, and to be highly effective as hydroxyl-radical scavengers. When the hydroxyl radical is produced photolytically, the overall antioxidant effect is a combination of preventative antioxidant activity (UV absorption) and (OH)-O-center dot radical scavenging. Few-layer graphene is more active than monolayer graphene oxide, despite its lower surface area, which indicates that the primary scavenging sites are associated with the sp(2)-carbon network rather than oxygen-containing functional groups. To explain this trend, we propose that GO is a weak hydrogen donor, due to the non-phenolic nature of most OH groups on GO, which reside at basal sp(3)-carbon sites that do not allow for radical resonullce stabilization following hydrogen donation. As an example application of graphene antioxidant behavior, we show that encapsulation of TiO2 nulloparticles in graphene nullosacks reduces undesired photo-oxidative damage to nearby organic target molecules, which suggests graphene encapsulation as a new approach to managing adverse environmental or health impacts of redox-active nullomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 392, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11744, "End Page": 11755, "Article Number": null, "DOI": "10.1039/c4nr03275f", "DOI Link": "http://dx.doi.org/10.1039/c4nr03275f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343000800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XM; Meng, WW; Liao, WQ; Wang, JB; Xiong, RG; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoming; Meng, Weiwei; Liao, Weiqiang; Wang, Jianbo; Xiong, Ren-Gen; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomistic Mechanism of Broadband Emission in Metal Halide Perovskites", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broadband emission is attributed to the formation of self-trapped excitons (STEs) due to the strong electron-phonon coupling. Interestingly, it has been observed in only certain three-dimensional and low-dimensional metal halide perovskites. Here, we show by density functional theory calculation that a low electronic dimensionality is a prerequisite for the formation of STE and, therefore, broadband emission. We further show that multiple STE structures exist in each perovskite exhibiting broadband emission. However, only the STE with Jahn-Teller-like octahedral distortion is mainly responsible for the observed broadband emission, though it may not be the lowest-energy structure. Our results provide important insights for designing perovskite materials for broadband emissions with preferred chromaticity coordinator or color temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2019, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 501, "End Page": 506, "Article Number": null, "DOI": "10.1021/acs.jpclett.8b03717", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.8b03717", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458704800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Green, MA; Emery, K; Hishikawa, Y; Warta, W; Dunlop, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro; Warta, Wilhelm; Dunlop, Ewan D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar cell efficiency tables (version 44)", "Source Title": "PROGRESS IN PHOTOVOLTAICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Consolidated tables showing an extensive listing of the highest independently confirmed efficiencies for solar cells and modules are presented. Guidelines for inclusion of results into these tables are outlined and new entries since January 2014 are reviewed. Copyright (c) 2014 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 546, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 22, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 701, "End Page": 710, "Article Number": null, "DOI": "10.1002/pip.2525", "DOI Link": "http://dx.doi.org/10.1002/pip.2525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337953300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZB; Tao, Z; Han, LH; Uy, B; Lam, D; Kang, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhi-Bin; Tao, Zhong; Han, Lin-Hai; Uy, Brian; Lam, Dennis; Kang, Won-Hee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strength, stiffness and ductility of concrete-filled steel columns under axial compression", "Source Title": "ENGINEERING STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extensive experimental and theoretical studies have been conducted on the compressive strength of concrete-filled steel tubular (CFST) columns, but little attention has been paid to their compressive stiffness and deformation capacity. Despite this, strength prediction approaches in existing design codes still have various limitations. A finite element model, which was previously proposed by the authors and verified using a large amount of experimental data, is used in this paper to generate simulation data covering a wide range of parameters for circular and rectangular CFST stub columns under axial Compression. Regression analysis is conducted to propose simplified models to predict the compressive strength, the compressive stiffness, and the compressive strain corresponding to the compressive strength (ductility) for the composite columns. Based on the new strength prediction model, the capacity reduction factors for the steel and concrete materials are recalibrated to achieve a target reliability index of 3.04 when considering resistance effect only. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2017, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 209, "End Page": 221, "Article Number": null, "DOI": "10.1016/j.engstruct.2016.12.049", "DOI Link": "http://dx.doi.org/10.1016/j.engstruct.2016.12.049", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394191000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, T; Kong, XJ; Bian, ZX; Zhang, YZ; Si, GR; Xie, LH; Wu, XQ; Huang, HL; Chang, Z; Bu, XH; Zaworotko, MJ; Nie, ZR; Li, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Tao; Kong, Xiang-Jing; Bian, Zhen-Xing; Zhang, Yong-Zheng; Si, Guang-Rui; Xie, Lin-Hua; Wu, Xue-Qian; Huang, Hongliang; Chang, Ze; Bu, Xian-He; Zaworotko, Michael J.; Nie, Zuo-Ren; Li, Jian-Rong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trace removal of benzene vapour using double-walled metal-dipyrazolate frameworks", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In principle, porous physisorbents are attractive candidates for the removal of volatile organic compounds such as benzene by virtue of their low energy for the capture and release of this pollutant. Unfortunately, many physisorbents exhibit weak sorbate-sorbent interactions, resulting in poor selectivity and low uptake when volatile organic compounds are present at trace concentrations. Herein, we report that a family of double-walled metal-dipyrazolate frameworks, BUT-53 to BUT-58, exhibit benzene uptakes at 298 K of 2.47-3.28 mmol g(-1) at <10 Pa. Breakthrough experiments revealed that BUT-55, a supramolecular isomer of the metal-organic framework Co(BDP) (H2BDP = 1,4-di(1H-pyrazol-4-yl)benzene), captures trace levels of benzene, producing an air stream with benzene content below acceptable limits. Furthermore, BUT-55 can be regenerated with mild heating. Insight into the performance of BUT-55 comes from the crystal structure of the benzene-loaded phase (C6H6@BUT-55) and density functional theory calculations, which reveal that C-H center dot center dot center dot X interactions drive the tight binding of benzene. Our results demonstrate that BUT-55 is a recyclable physisorbent that exhibits high affinity and adsorption capacity towards benzene, making it a candidate for environmental remediation of benzene-contaminated gas mixtures. Volatile organic compounds such as benzene are toxic pollutants that cause health issues even at trace concentrations. Here, a double-walled metal-organic framework is presented that demonstrates high uptake at very low pressures (<10 Pa), allowing the removal of benzene to below acceptable indoor limits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 21, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 689, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01237-x", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01237-x", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788444400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, F; Yue, XY; Liao, YL; Qiao, L; Lv, KL; Xiang, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fang; Yue, Xiaoyang; Liao, Yulong; Qiao, Liang; Lv, Kangle; Xiang, Quanjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the unique S-scheme charge migration in triazine/heptazine crystalline carbon nitride homojunction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding charge transfer dynamics and carrier separation pathway is challenging due to the lack of appropriate characterization strategies. In this work, a crystalline triazine/heptazine carbon nitride homojunction is selected as a model system to demonstrate the interfacial electron-transfer mechanism. Surface bimetallic cocatalysts are used as sensitive probes during in situ photoemission for tracing the S-scheme transfer of interfacial photogenerated electrons from triazine phase to the heptazine phase. Variation of the sample surface potential under light on/off confirms dynamic S-scheme charge transfer. Further theoretical calculations demonstrate an interesting reversal of interfacial electron-transfer path under light/dark conditions, which also supports the experimental evidence of S-scheme transport. Benefiting from the unique merit of S-scheme electron transfer, homojunction shows significantly enhanced activity for CO2 photoreduction. Our work thus provides a strategy to probe dynamic electron transfer mechanisms and to design delicate material structures towards efficient CO2 photoreduction. Here, the authors reveal how interfacial electron migration occurs in S-scheme crystalline carbon nitrides by applying several dynamic in situ characterization and theoretical calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39578-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39578-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028011500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guerrero, A; Garcia-Belmonte, G; Mora-Sero, I; Bisquert, J; Kang, YS; Jacobsson, TJ; Correa-Baena, JP; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guerrero, Antonio; Garcia-Belmonte, Germa; Mora-Sero, Ivan; Bisquert, Juan; Kang, Yong Soo; Jacobsson, T. Jesper; Correa-Baena, Juan-Pablo; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Properties of Contact and Bulk Impedances in Hybrid Lead Halide Perovskite Solar Cells Including Inductive Loop Elements", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Impedance spectroscopy offers access to all the different electronic and ionic processes taking place simultaneously in an operating solar cell. To date, its use on perovskite solar cells has been challenging because of the richness of the physical processes occurring within similar time domains. The aim of this work is to understand the general impedance response and propose a general equivalent circuit model that accounts for the different processes and gives access to quantitative analysis. When the electron-selective contacts and the thickness of the perovskite film are systematically modified, it is possible to distinguish between the characteristic impedance signals of the perovskite layer and those arising from the contacts. The study is carried out using mixed organic lead halogen perovskite (FA(0.85)MA(0.15)Pb(I0.85Br0.15)(3)) solar cells with three different electron-selective contacts: SnO2, TiO2, and Nb2O5. The contacts have been deposited by atomic layer deposition (ALD), which provides pinhole-free films and excellent thickness control in the absence of a mesoporous layer to simplify the impedance analysis. It was found that the interfacial impedance has a rich structure that reveals different capacitive processes, serial steps for electron extraction, and a prominent inductive loop related to negative capacitance at intermediate frequencies. Overall, the present report provides insights into the impedance response of perovskite solar cells which enable an understanding of the different electronic and ionic processes taking place during device operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 428, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2016, "Volume": 120, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8023, "End Page": 8032, "Article Number": null, "DOI": "10.1021/acs.jpcc.6b01728", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.6b01728", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374811100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, HB; Xu, YH; Huang, X; Chen, JZ; Pei, LJ; Zhang, JM; Chen, JGG; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Hua Bing; Xu, Yinghua; Huang, Xiang; Chen, Jiazang; Pei, Linjuan; Zhang, Junming; Chen, Jingguang G.; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A General Method to Probe Oxygen Evolution Intermediates at Operating Conditions", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing high overpotential for the oxygen evolution reaction (OER) is an important challenge for the utilization of clean and renewable energy resources. An obstacle that badly impedes the design of efficient OER catalysts is the weak understanding of the oxygen intermediates. Because of the aqueous reaction environment of OER, direct detection of oxygen intermediates is very challenging. Herein, we develop a general method for operando probing OER intermediates under real working conditions. We proved that the electrochemically generated oxygen intermediates of OER, e. g., OH*, are electrophiles, which could be probed by reaction with nucleophiles such as alcohol molecules. The exceptional generality of this method is demonstrated in different reaction mediums (alkaline and acid) and on various types of materials (oxides and hydroxides). The new insights of the surface chemistry on OER catalysts from the experimental approach will benefit the design of new catalysts to reduce the cost of hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2019, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1498, "End Page": 1509, "Article Number": null, "DOI": "10.1016/j.joule.2019.03.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.03.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472067900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naranjo-Lozada, J; Ahuett-Garza, H; Orta-Castañón, P; Verbeeten, WMH; Sáiz-González, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naranjo-Lozada, Juan; Ahuett-Garza, Horacio; Orta-Castanon, Pedro; Verbeeten, Wilco M. H.; Saiz-Gonzalez, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tensile properties and failure behavior of chopped and continuous carbon fiber composites produced by additive manufacturing", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of additive manufacturing (AM) is rapidly expanding in many industries mostly because of the flexibility to manufacture complex geometries. Recently, a family of technologies that produce fiber reinforced components has been introduced, widening the options available to designers. AM fiber reinforced composites are characterized by the fact that process related parameters such as the amount of reinforcement fiber, or printing architecture, significantly affect the tensile properties of final parts. To find optimal structures using new AM technologies, guidelines for the design of 3D printed composite parts are needed. This paper presents an evaluation of the effects that different geometric parameters have on the tensile properties of 3D printed composites manufactured by fused filament fabrication (FFF) out of continuous and chopped carbon fiber reinforcement. Parameters such as infill density and infill patterns of chopped composite material, as well as fiber volume fraction and printing architecture of continuous fiber reinforcement (CFR) composites are varied. The effect of the location of the initial deposit point of reinforcement fibers on the tensile properties of the test specimens is studied. Also, the effect that the fiber deposition pattern has on tensile performance is quantified. Considering the geometric parameters that were studied, a variation of the Rule of Mixtures (ROM) that provides a way to estimate the elastic modulus of a 3D printed composite is proposed. Findings may be used by designers to define the best construction parameters for 3D printed composite parts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 26, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 241, "Article Number": null, "DOI": "10.1016/j.addma.2018.12.020", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2018.12.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460083000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FC; Lovorn, T; Tutuc, E; Martin, I; MacDonald, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fengcheng; Lovorn, Timothy; Tutuc, Emanuel; Martin, Ivar; MacDonald, A. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Insulators in Twisted Transition Metal Dichalcogenide Homobilayers", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show that moire bands of twisted homobilayers can be topologically nontrivial, and illustrate the tendency by studying valence band states in +/- K valleys of twisted bilayer transition metal dichalcogenides, in particular, bilayer MoTe2. Because of the large spin-orbit splitting at the monolayer valence band maxima, the low energy valence states of the twisted bilayer MoTe2 at the +K (-K) valley can be described using a two-band model with a layer-pseudospin magnetic field Delta(r) that has the moire period. We show that Delta(r) has a topologically nontrivial skyrmion lattice texture in real space, and that the topmost moire valence bands provide a realization of the Kane-Mele quantum spin-Hall model, i. e., the two-dimensional time-reversal-invariant topological insulator. Because the bands narrow at small twist angles, a rich set of broken symmetry insulating states can occur at integer numbers of electrons per moire cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 476, "Times Cited, All Databases": 519, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2019, "Volume": 122, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86402, "DOI": "10.1103/PhysRevLett.122.086402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.086402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459920900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XJ; Li, FK; Zhang, DC; Liu, ZB; Zuo, SY; Zeng, ZY; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xijun; Li, Fangkun; Zhang, Dechao; Liu, Zhengbo; Zuo, Shiyong; Zeng, Zhiyuan; Liu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-Sacrifice Template Construction of Uniform Yolk-Shell ZnS@C for Superior Alkali-Ion Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Secondary batteries have been widespread in the daily life causing an ever-growing demand for long-cycle lifespan and high-energy alkali-ion batteries. As an essential constituent part, electrode materials with superior electrochemical properties play a vital role in the battery systems. Here, an outstanding electrode of yolk-shell ZnS@C nullorods is developed, introducing considerable void space via a self-sacrificial template method. Such carbon encapsulated nullorods moderate integral electronic conductivity, thus ensuring rapid alkali-ions/electrons transporting. Furthermore, the porous structure of these nullorods endows enough void space to mitigate volume stress caused by the insertion/extraction of alkali-ions. Due to the unique structure, these yolk-shell ZnS@C nullorods achieve superior rate performance and cycling performance (740 mAh g(-1) at 1.0 A g(-1) after 540 cycles) for lithium-ion batteries. As a potassium-ion batteries anode, they achieve an ultra-long lifespan delivering 211.1 mAh g(-1) at 1.0 A g(-1) after 5700 cycles. The kinetic analysis reveals that these ZnS@C nullorods with considerable pseudocapacitive contribution benefit the fast lithiation/delithiation. Detailed transmission electron microscopy (TEM) and X-ray diffraction (XRD) analyses indicate that such yolk-shell ZnS@C anode is a typical reversible conversion reaction mechanism accomplished by alloying processes. This rational design strategy opens a window for the development of superior energy storage materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200247, "DOI": "10.1002/advs.202200247", "DOI Link": "http://dx.doi.org/10.1002/advs.202200247", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768651300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hitz, GT; McOwen, DW; Zhang, L; Ma, ZH; Fu, ZZ; Wen, Y; Gong, YH; Dai, JQ; Hamann, TR; Hu, LB; Wachsman, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hitz, Gregory T.; McOwen, Dennis W.; Zhang, Lei; Ma, Zhaohui; Fu, Zhezhen; Wen, Yang; Gong, Yunhui; Dai, Jiaqi; Hamann, Tanner R.; Hu, Liangbing; Wachsman, Eric D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-rate lithium cycling in a scalable trilayer Li-garnet-electrolyte architecture", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state lithium batteries promise to exceed the capabilities of traditional Li-ion batteries in safety and performance. However, a number of obstacles have stood in the path of solid-state battery development, primarily high resistance and low capacity. In this work, these barriers are overcome through the fabrication of a uniquely microstructured solid electrolyte architecture based on a doped Li7La3Zr2O12 (LLZ) ceramic Li-conductor. Specifically, a porous-dense-porous trilayer structure was fabricated by tape casting, a scalable roll-to-roll manufacturing technique. The dense (>99%) center layer can be fabricated as thin as similar to 10 mu m and blocks dendrites over hundreds of cycles. The microstructured porous layers serve as electrode supports and increase the mechanical strength by similar to 9x, making the cells strong enough to handle with ease. Additionally, the porous layers multiply the electrode-electrolyte interfacial surface area by >40x compared to a typical planar interface. Lithium symmetric cells based on the trilayer architecture were cycled at room temperature and achieved area-specific resistances (similar to 7 Omega-cm(2)) dramatically lower, and current densities dramatically higher (10 mA/cm(2)), than previously reported literature results. Moreover, to demonstrate scalability a large-format cell was fabricated with lithium metal in one porous layer and a sulfur electrode with conductive carbon and an ionic liquid interface in the other, achieving 1244 mAh/g S utilization and 195 Wh/kg based on total cell mass, showing a promising path to commercially viable, intrinsically safe lithium batteries with high specific energy and high energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2019, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 50, "End Page": 57, "Article Number": null, "DOI": "10.1016/j.mattod.2018.04.004", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2018.04.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458525700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Ling, HL; Wang, T; Jiang, YJ; Song, GY; Zhao, W; Zhao, LB; Cheng, TT; Xie, YX; Guo, YY; Zhao, WX; Yuan, LY; Meng, A; Li, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Meng; Ling, Hailong; Wang, Ting; Jiang, Yingjing; Song, Guanying; Zhao, Wen; Zhao, Laibin; Cheng, Tingting; Xie, Yuxin; Guo, Yuying; Zhao, Wenxin; Yuan, Liying; Meng, Alan; Li, Zhenjiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Equivalent Substitute Strategy for Constructing 3D Ordered Porous Carbon Foams and Their Electromagnetic Attenuation Mechanism", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) ordered porous carbon is generally believed to be a promising electromagnetic wave (EMW) absorbing material. However, most research works targeted performance improvement of 3D ordered porous carbon, and the specific attenuation mechanism is still ambiguous. Therefore, in this work, a novel ultra-light egg-derived porous carbon foam (EDCF) structure has been successfully constructed by a simple carbonization combined with the silica microsphere template-etching process. Based on an equivalent substitute strategy, the influence of pore volume and specific surface area on the electromagnetic parameters and EMW absorption properties of the EDCF products was confirmed respectively by adjusting the addition content and diameter of silica microspheres. As a primary attenuation mode, the dielectric loss originates from the comprehensive effect of conduction loss and polarization loss in S-band and C band, and the value is dominated by polarization loss in X band and Ku band, which is obviously greater than that of conduction loss. Furthermore, in all samples, the largest effective absorption bandwidth of EDCF-3 is 7.12 GHz under the thickness of 2.13 mm with the filling content of approximately 5 wt%, covering the whole Ku band. Mean while, the EDCF-7 sample with optimized pore volume and specific surface area achieves minimum reflection loss (RLmin) of- 58.08 dB at 16.86 GHz while the thickness is 1.27 mm. The outstanding research results not only provide a novel insight into enhancement of EMW absorption properties but also clarify the dominullt dissipation mechanism for the porous carbon-based absorber from the perspective of objective experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 157, "DOI": "10.1007/s40820-022-00900-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00900-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836666000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuo, YZ; Xiao, SB; Amirfazli, A; He, JY; Zhang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuo, Yizhi; Xiao, Senbo; Amirfazli, Alidad; He, Jianying; Zhang, Zhiliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polysiloxane as icephobic materials - The past, present and the future", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polysiloxane is one of the most favorite polymeric materials used in the emerging field of passive surface icephobicity; This is due to its tailorable softness, hydrophobicity, and relatively high durability. Given the state-of-the-art ice adhesion strength of polysiloxane surfaces has reached a threshold below 1 kPa, a timely survey on the published polysiloxane icephobic surfaces can serve as a valuable reference concerning how far the research field has already progressed and how much potential remains to be exploited for the future development of polymeric icephobic materials. This review categorizes the use of polysiloxane materials for icephobic strategies into three classes according to their surface stiffness. The advantages and shortcomings of each polysiloxane material group are assessed. By scrutinizing the current ice adhesion strength theory, a reference coating thickness is identified, which can be used for optimizing icephobic coating design. A surface icephobicity diagram is also presented, where a lower bound of ice adhesion on a smooth surface is derived, depicting the needs of incorporating different mechanisms to break the theoretical low ice adhesion limit. Finally, the challenges in applying the polysiloxane icephobic materials are discussed, and the possible key research directions are highlighted.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 405, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127088, "DOI": "10.1016/j.cej.2020.127088", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2020.127088", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621646600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JY; Yan, YL; Wang, X; Cui, YY; Zhang, ZF; Wang, S; Xie, ZK; Yan, PF; Chen, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jiyu; Yan, Yongliang; Wang, Xin; Cui, Yanyan; Zhang, Zhengfeng; Wang, Sen; Xie, Zhengkun; Yan, Pengfei; Chen, Weihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bridging multiscale interfaces for developing ionically conductive high-voltage iron sulfate-containing sodium-based battery positive electrodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-aqueous sodium-ion batteries (SiBs) are a viable electrochemical energy storage system for grid storage. However, the practical development of SiBs is hindered mainly by the sluggish kinetics and interfacial instability of positive-electrode active materials, such as polyanion-type iron-based sulfates, at high voltage. Here, to circumvent these issues, we proposed the multiscale interface engineering of Na2.26Fe1.87(SO4)(3), where bulk heterostructure and exposed crystal plane were tuned to improve the Na-ion storage performance. Physicochemical characterizations and theoretical calculations suggested that the heterostructure of Na6Fe(SO4)(4) phase facilitated ionic kinetics by densifying Na-ion migration channels and lowering energy barriers. The (11-2) plane of Na2.26Fe1.87(SO4)(3) promoted the adsorption of the electrolyte solution ClO4- anions and fluoroethylene carbonate molecules, which formed an inorganic-rich Na-ion conductive interphase at the positive electrode. When tested in combination with a presodiated FeS/carbon-based negative electrode in laboratory- scale single-layer pouch cell configuration, the Na2.26Fe1.87(SO4)(3)-based positive electrode enables an initial discharge capacity of about 83.9 mAh g(-1), an average cell discharge voltage of 2.35V and a specific capacity retention of around 97% after 40 cycles at 24 mA g(-1) and 25 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3701, "DOI": "10.1038/s41467-023-39384-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39384-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058061100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, RX; Ansari, MA; Ahmed, H; Li, Y; Cai, WF; Liu, YJ; Li, ST; Liu, JL; Li, L; Chen, XZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ruoxing; Ansari, Muhammad Afnull; Ahmed, Hammad; Li, Yan; Cai, Wenfeng; Liu, Yanjun; Li, Songtao; Liu, Jianlong; Li, Li; Chen, Xianzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compact multi-foci metalens spectrometer", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A lightweight and portable spectrometer is desirable for miniaturization and integration. The unprecedented capability of optical metasurfaces has shown much promise to perform such a task. We propose and experimentally demonstrate a compact high-resolution spectrometer with a multi-foci metalens. The novel metalens is designed based on wavelength and phase multiplexing, which can accurately map the wavelength information into its focal points located on the same plane. The measured wavelengths in the light spectra agree with simulation results upon the illumination of various incident light spectra. The uniqueness of this technique lies in the novel metalens that can simultaneously realize wavelength splitting and light focusing. The compactness and ultrathin nature of the metalens spectrometer render this technology have potential applications in on-chip integrated photonics where spectral analysis and information processing can be performed in a compact platform.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103, "DOI": "10.1038/s41377-023-01148-9", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01148-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982190500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, XD; Gao, PY; Zou, LF; Jiao, SH; Cao, X; Zhang, XH; Jia, H; Engelhard, MH; Matthews, BE; Wu, HP; Lee, H; Niu, CJ; Wang, CM; Arey, BW; Xiao, J; Liu, J; Zhang, JG; Xu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xiaodi; Gao, Peiyuan; Zou, Lianfeng; Jiao, Shuhong; Cao, Xia; Zhang, Xianhui; Jia, Hao; Engelhard, Mark H.; Matthews, Bethany E.; Wu, Haiping; Lee, Hongkyung; Niu, Chaojiang; Wang, Chongmin; Arey, Bruce W.; Xiao, Jie; Liu, Jun; Zhang, Ji-Guang; Xu, Wu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of inner solvation sheath within salt-solvent complexes in tailoring electrode/electrolyte interphases for lithium metal batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functional electrolyte is the key to stabilize the highly reductive lithium (Li) metal anode and the high-voltage cathode for long-life, high-energy-density rechargeable Li metal batteries (LMBs). However, fundamental mechanisms on the interactions between reactive electrodes and electrolytes are still not well understood. Recently localized high-concentration electrolytes (LHCEs) are emerging as a promising electrolyte design strategy for LMBs. Here, we use LHCEs as an ideal platform to investigate the fundamental correlation between the reactive characteristics of the inner solvation sheath on electrode surfaces due to their unique solvation structures. The effects of a series of LHCEs with model electrolyte solvents (carbonate, sulfone, phosphate, and ether) on the stability of high-voltage LMBs are systematically studied. The stabilities of electrodes in different LHCEs indicate the intrinsic synergistic effects between the salt and the solvent when they coexist on electrode surfaces. Experimental and theoretical analyses reveal an intriguing general rule that the strong interactions between the salt and the solvent in the inner solvation sheath promote their intermolecular proton/charge transfer reactions, which dictates the properties of the electrode/electrolyte inter-phases and thus the battery performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2020, "Volume": 117, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 28603, "End Page": 28613, "Article Number": null, "DOI": "10.1073/pnas.2010852117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2010852117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595339600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Howe, RCT; Woodward, RI; Kelleher, EJR; Torrisi, F; Hu, GH; Popov, SV; Taylor, JR; Hasan, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Meng; Howe, Richard C. T.; Woodward, Robert I.; Kelleher, Edmund J. R.; Torrisi, Felice; Hu, Guohua; Popov, Sergei V.; Taylor, J. Roy; Hasan, Tawfique", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution processed MoS2-PVA composite for sub-bandgap mode-locking of a wideband tunable ultrafast Er:fiber laser", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We fabricate a free-standing few-layer molybdenum disulfide (MoS2)-polymer composite by liquid phase exfoliation of chemically pristine MoS2 crystals and use this to demonstrate a wideband tunable, ultrafast mode-locked fiber laser. Stable, picosecond pulses, tunable from 1,535 nm to 1,565 nm, are generated, corresponding to photon energies below the MoS2 material bandgap. These results contribute to the growing body of work studying the nonlinear optical properties of transition metal dichalcogenides that present new opportunities for ultrafast photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1522, "End Page": 1534, "Article Number": null, "DOI": "10.1007/s12274-014-0637-2", "DOI Link": "http://dx.doi.org/10.1007/s12274-014-0637-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354625600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Min, J; Xue, T; Jiang, PC; Liu, X; Peng, RM; Huang, JW; Qu, YY; Li, X; Ma, N; Tsai, FC; Dai, LH; Zhang, Q; Liu, YL; Chen, CC; Guo, RT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yu; Min, Jian; Xue, Ting; Jiang, Pengcheng; Liu, Xin; Peng, Rouming; Huang, Jian-Wen; Qu, Yingying; Li, Xian; Ma, Ning; Tsai, Fang-Chang; Dai, Longhai; Zhang, Qi; Liu, Yingle; Chen, Chun-Chi; Guo, Rey-Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Complete bio-degradation of poly(butylene adipate-co-terephthalate) via engineered cutinases", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Poly(butylene adipate-co-terephthalate) (PBAT), a polyester made of terephthalic acid (TPA), 1,4-butanediol, and adipic acid, is extensively utilized in plastic production and has accumulated globally as environmental waste. Biodegradation is an attractive strategy to manage PBAT, but an effective PBAT-degrading enzyme is required. Here, we demonstrate that cutinases are highly potent enzymes that can completely decompose PBAT films in 48 h. We further show that the engineered cutinases, by applying a double mutation strategy to render a more flexible substrate-binding pocket exhibit higher decomposition rates. Notably, these variants produce TPA as a major end-product, which is beneficial feature for the future recycling economy. The crystal structures of wild type and double mutation of a cutinase from Thermobifida fusca in complex with a substrate analogue are also solved, elucidating their substrate-binding modes. These structural and biochemical analyses enable us to propose the mechanism of cutinase-mediated PBAT degradation. Bio-degradation of poly(butylene adipate-co-terephthalate) is an attractive tactic but requires an effective hydrolytic enzyme. Here, the authors demonstrate that cutinases are highly potent PBAT-decomposing enzymes and their mechanism is proposed based on substrate-binding mode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1645, "DOI": "10.1038/s41467-023-37374-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37374-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959887700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kirchdoerfer, T; Ortiz, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kirchdoerfer, T.; Ortiz, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-driven computational mechanics", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a new computing paradigm, which we refer to as data-driven computing, according to which calculations are carried out directly from experimental material data and pertinent constraints and conservation laws, such as compatibility and equilibrium, thus bypassing the empirical material modeling step of conventional computing altogether. Data-driven solvers seek to assign to each material point the state from a prespecified data set that is closest to satisfying the conservation laws. Equivalently, data-driven solvers aim to find the state satisfying the conservation laws that is closest to the data set. The resulting data-driven problem thus consists of the minimization of a distance function to the data set in phase space subject to constraints introduced by the conservation laws. We motivate the data-driven paradigm and investigate the performance of data-driven solvers by means of two examples of application, namely, the static equilibrium of nonlinear three-dimensional trusses and linear elasticity. In these tests, the data-driven solvers exhibit good convergence properties both with respect to the number of data points and with regard to local data assignment. The variational structure of the data-driven problem also renders it amenable to analysis. We show that, as the data set approximates increasingly closely a classical material law in phase space, the data-driven solutions converge to the classical solution. We also illustrate the robustness of data-driven solvers with respect to spatial discretization. In particular, we show that the data-driven solutions of finite-element discretizations of linear elasticity converge jointly with respect to mesh size and approximation by the data set. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 502, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2016, "Volume": 304, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": 101, "Article Number": null, "DOI": "10.1016/j.cma.2016.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.02.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374506600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XG; Ma, LF; Yan, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaogang; Ma, Lu-Fang; Yan, Dongpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile synthesis of 1D organic-inorganic perovskite micro-belts with high water stability for sensing and photonic applications", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of low-dimensional perovskite micro/nullostructures with high water stability for novel photonic/electronic applications is highly desirable. Herein, one-dimensional (1D) organic-inorganic hybrid perovskite micro-belts [(AD) Pb2Cl5] (OIHP-AD, AD = acridine) were facilely synthesized through fast precipitation in aqueous solution at room temperature without any organic solvent and expensive alkyl halide. Luminescent properties and water stability are efficiently enhanced due to the highly regular arrangement of the protonated AD dyes with larger steric hindrance distributed in the perovskite hostguest system, which can afford denser crystal packing to prevent water erosion. The OIHP-AD microbelts present upconversion fluorescence, polarized photoemission and optical waveguide performances with a low loss coefficient (0.004 dB mm 1) during propagation, thus extending the applications of 1D perovskite micro/nullostructures to potential optical communication micro-devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2019, "Volume": 10, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4567, "End Page": 4572, "Article Number": null, "DOI": "10.1039/c9sc00162j", "DOI Link": "http://dx.doi.org/10.1039/c9sc00162j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465940700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lou, WC; Mao, MM; Song, KX; Xu, KW; Liu, B; Li, WJ; Yang, B; Qi, ZM; Zhao, JW; Sun, SK; Lin, HX; Hu, YY; Zhou, D; Wang, DW; Reaney, IM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lou, Weichao; Mao, Minmin; Song, Kaixin; Xu, Kuiwen; Liu, Bing; Li, Wenjun; Yang, Bin; Qi, Zeming; Zhao, Jianwei; Sun, Shikuan; Lin, Huixin; Hu, Yuanyun; Zhou, Di; Wang, Dawei; Reaney, Ian M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low permittivity cordierite-based microwave dielectric ceramics for 5G/6G telecommunications", "Source Title": "JOURNAL OF THE EUROPEAN CERAMIC SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "5G and forthcoming 6G communication systems require dielectric ceramics with low relative permittivity (epsilon(r)) and near-zero temperature coefficient of resonullt frequency (tau(f)) for the lower part of the microwave (MW) band and at sub-Terahertz. Mg2Al4Si5O18 (MAS) ceramics are promising candidates due to their low epsilon(r) (-6) and high-quality factor (Qxf > 40,000 GHz) but have a large tau(f). In this study, 5.5 wt% TiO2 (MAS-T-5.5) was used to adjust tau(f) of MAS to-2.8 ppm/celcius whilst retaining low epsilon(r) (5.24) and good Qxf (33,400 GHz), properties consistent with those obtained by infrared reflectance. A demonstrator microstrip patch antenna with gain 4.92 dBi and 76.3% efficiency was fabricated from MAS-T-5.5.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 42, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2820, "End Page": 2826, "Article Number": null, "DOI": "10.1016/j.jeurceramsoc.2022.01.050", "DOI Link": "http://dx.doi.org/10.1016/j.jeurceramsoc.2022.01.050", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766633800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DZ; Wang, RC; Wang, XH; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Danzhen; Wang, Ruocun (John); Wang, Xuehang; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ monitoring redox processes in energy storage using UV-Vis spectroscopy", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding energy storage mechanisms in electrochemical energy storage devices lays the foundations for improving their energy and power density. Here we introduce in situ ultraviolet-visible (UV-Vis) spectroscopy method to distinguish battery-type, pseudocapacitive and electrical double-layer charge storage processes. On the basis of Ti3C2Tx MXene in aqueous acidic and neutral electrolytes, and lithium titanium oxide in an organic electrolyte, we found a correlation between the evolution of UV-Vis spectra and the charge storage mechanism. The electron transfer number for Ti3C2Tx in an acidic electrolyte was calculated using quantitative analysis, which was close to previous measurements using X-ray absorption spectroscopy. Further, we tested the methodology to distinguish the non-Faradaic process in Ti3C2Tx MXene in a water-in-salt electrolyte, despite well-defined peaks in cyclic voltammograms. In situ UV-Vis spectroscopy is a fast and cost-effective technique that effectively supplements electrochemical characterization to track changes in oxidation state and materials chemistry and determine the charge storage mechanism. It can be challenging for conventional electrochemical measurements to distinguish different types of charge storage mechanisms in electrochemical systems. Here the authors develop an in situ ultraviolet-visible spectroscopy approach as a powerful and affordable tool for this purpose.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 567, "End Page": 576, "Article Number": null, "DOI": "10.1038/s41560-023-01240-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01240-9", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968306900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JS; Li, LM; Ma, XY; Han, X; Xing, CC; Qi, XQ; He, R; Arbiol, J; Pan, HY; Zhao, J; Deng, J; Zhang, Y; Yang, YY; Cabot, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Junshan; Li, Luming; Ma, Xingyu; Han, Xu; Xing, Congcong; Qi, Xueqiang; He, Ren; Arbiol, Jordi; Pan, Huiyan; Zhao, Jun; Deng, Jie; Zhang, Yu; Yang, Yaoyue; Cabot, Andreu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective Ethylene Glycol Oxidation to Formate on Nickel Selenide with Simultaneous Evolution of Hydrogen", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is an urgent need for cost-effective strategies to produce hydrogen from renewable net-zero carbon sources using renewable energies. In this context, the electrochemical hydrogen evolution reaction can be boosted by replacing the oxygen evolution reaction with the oxidation of small organic molecules, such as ethylene glycol (EG). EG is a particularly interesting organic liquid with two hydroxyl groups that can be transformed into a variety of C1 and C2 chemicals, depending on the catalyst and reaction conditions. Here, a catalyst is demonstrated for the selective EG oxidation reaction (EGOR) to formate on nickel selenide. The catalyst nulloparticle (NP) morphology and crystallographic phase are tuned to maximize its performance. The optimized NiS electrocatalyst requires just 1.395 V to drive a current density of 50 mA cm(-2) in 1 m potassium hydroxide (KOH) and 1 m EG. A combination of in situ electrochemical infrared absorption spectroscopy (IRAS) to monitor the electrocatalytic process and ex situ analysis of the electrolyte composition shows the main EGOR product is formate, with a Faradaic efficiency above 80%. Additionally, C2 chemicals such as glycolate and oxalate are detected and quantified as minor products. Density functional theory (DFT) calculations of the reaction process show the glycol-to-oxalate pathway to be favored via the glycolate formation, where the C-C bond is broken and further electro-oxidized to formate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300841", "DOI Link": "http://dx.doi.org/10.1002/advs.202300841", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954802700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, JQ; Xie, YH; Yang, Y; Wang, XH; Li, WY; Zhang, QL; Ma, S; Cheng, SY; Lu, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Jiaqi; Xie, Yonghui; Yang, Yang; Wang, Xinghui; Li, Wangyang; Zhang, Qiaoli; Ma, Shun; Cheng, Shuying; Lu, Bingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Uniform Li Plating/Stripping at Ultrahigh Currents and Capacities by Optimizing 3D Nucleation Sites and Li2Se-Enriched SEI", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium (Li) has garnered considerable attention as an alternative anodes of next-generation high-performance batteries owing to its prominent theoretical specific capacity. However, the commercialization of Li metal anodes (LMAs) is significantly compromised by non-uniform Li deposition and inferior electrolyte-anode interfaces, particularly at high currents and capacities. Herein, a hierarchical three-dimentional structure with CoSe2-nulloparticle-anchored nitrogen-doped carbon nulloflake arrays is developed on a carbon fiber cloth (CoSe2-NC@CFC) to regulate the Li nucleation/plating process and stabilize the electrolyte-anode interface. Owing to the enhanced lithiophilicity endowed by CoSe2-NC, in situ-formed Li2Se and Co nulloparticles during initial Li nucleation, and large void space, CoSe2-NC@CFC can induce homogeneous Li nucleation/plating, optimize the solid electrolyte interface, and mitigate volume change. Consequently, the CoSe2-NC@CFC can accommodate Li with a high areal capacity of up to 40 mAh cm(-2). Moreover, the Li/CoSe2-NC@CFC anodes possess outstanding cycling stability and lifespan in symmetric cells, particularly under ultrahigh currents and capacities (1600 h at 10 mA cm(-2)/10 mAh cm(-2) and 5 mA cm(-2)/20 mAh cm(-2)). The Li/CoSe2-NC@CFC//LiFePO4 full cell delivers impressive long-term performance and favorable flexibility. The developed CoSe2-NC@CFC provides insights into the development of advanced Li hosts for flexible and stable LMAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104689, "DOI": "10.1002/advs.202104689", "DOI Link": "http://dx.doi.org/10.1002/advs.202104689", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745950200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SY; Hai, X; Ding, X; Jin, SB; Xiang, YG; Wang, P; Jiang, B; Ichihara, F; Oshikiri, M; Meng, XG; Li, YX; Matsuda, W; Ma, J; Seki, S; Wang, XP; Huang, H; Wada, Y; Chen, H; Ye, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shengyao; Hai, Xiao; Ding, Xing; Jin, Shangbin; Xiang, Yonggang; Wang, Pei; Jiang, Bo; Ichihara, Fumihiko; Oshikiri, Mitsutake; Meng, Xianguang; Li, Yunxiang; Matsuda, Wakana; Ma, Jun; Seki, Shu; Wang, Xuepeng; Huang, Hao; Wada, Yoshiki; Chen, Hao; Ye, Jinhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intermolecular cascaded π-conjugation channels for electron delivery powering CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoreduction of CO2 to fuels offers a promising strategy for managing the global carbon balance using renewable solar energy. But the decisive process of oriented photogenerated electron delivery presents a considerable challenge. Here, we report the construction of intermolecular cascaded pi-conjugation channels for powering CO2 photoreduction by modifying both intramolecular and intermolecular conjugation of conjugated polymers (CPs). This coordination of dual conjugation is firstly proved by theoretical calculations and transient spectroscopies, showcasing alkynyl-removed CPs blocking the delocalization of electrons and in turn delivering the localized electrons through the intermolecular cascaded channels to active sites. Therefore, the optimized CPs (N-CP-D) exhibiting CO evolution activity of 2247 mu mol g(-1) h(-1) and revealing a remarkable enhancement of 138-times compared to unmodified CPs (N-CP-A). While conversion of CO2 to fuels may offer a bio-inspired means to renewably utilize fossil fuel emission, most materials demonstrate poor activities for CO2 reduction. Here, authors construct conjugated polymers that modulate photo-induced electron transfer to CO2 reduction catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1149, "DOI": "10.1038/s41467-020-14851-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14851-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520939200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, F; Zhu, JY; Sun, PZ; Zhang, MR; Li, ZQ; Xu, DX; Gong, XY; Zou, XL; Geim, AK; Su, Y; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fei; Zhu, Jiuyi; Sun, Pengzhan; Zhang, Mingrui; Li, Zhenqing; Xu, Dingxin; Gong, Xinyu; Zou, Xiaolong; Geim, A. K.; Su, Yang; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient and selective extraction of gold by reduced graphene oxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High extraction capacity with precise selectivity to trace amounts of gold over a wide range of co-existing elements remains a challenge for effective e-waste recycling. Here, authors demonstrate the excellent performance of rGO for gold extraction from e-waste leachate, even at minute concentrations. Materials capable of extracting gold from complex sources, especially electronic waste (e-waste), are needed for gold resource sustainability and effective e-waste recycling. However, it remains challenging to achieve high extraction capacity and precise selectivity if only a trace amount of gold is present along with other metallic elements . Here we report an approach based on reduced graphene oxide (rGO) which provides an ultrahigh capacity and selective extraction of gold ions present in ppm concentrations (>1000 mg of gold per gram of rGO at 1 ppm). The excellent gold extraction performance is accounted to the graphene areas and oxidized regions of rGO. The graphene areas spontaneously reduce gold ions to metallic gold, and the oxidized regions allow good dispersibility of the rGO material so that efficient adsorption and reduction of gold ions at the graphene areas can be realized. By controlling the protonation of the oxidized regions of rGO, gold can be extracted exclusively, without contamination by the other 14 co-existing elements typically present in e-waste. These findings are further exploited to demonstrate recycling gold from real-world e-waste with good scalability and economic viability, as exemplified by using rGO membranes in a continuous flow-through process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4472, "DOI": "10.1038/s41467-022-32204-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32204-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836703600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, F; Ward, L; Williams, T; Laws, KJ; Wolverton, C; Hattrick-Simpers, J; Mehta, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Fang; Ward, Logan; Williams, Travis; Laws, Kevin J.; Wolverton, Christopher; Hattrick-Simpers, Jason; Mehta, Apurva", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated discovery of metallic glasses through iteration of machine learning and high-throughput experiments", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With more than a hundred elements in the periodic table, a large number of potential new materials exist to address the technological and societal challenges we face today; however, without some guidance, searching through this vast combinatorial space is frustratingly slow and expensive, especially for materials strongly influenced by processing. We train a machine learning (ML) model on previously reported observations, parameters from physiochemical theories, and make it synthesis method-dependent to guide high-throughput (HiTp) experiments to find a new system of metallic glasses in the Co-V-Zr ternary. Experimental observations are in good agreement with the predictions of the model, but there are quantitative discrepancies in the precise compositions predicted. We use these discrepancies to retrain the ML model. The refined model has significantly improved accuracy not only for the Co-V-Zr system but also across all other available validation data. We then use the refined model to guide the discovery of metallic glasses in two additional previously unreported ternaries. Although our approach of iterative use of ML and HiTp experiments has guided us to rapid discovery of three new glass-forming systems, it has also provided us with a quantitatively accurate, synthesis method-sensitive predictor for metallic glasses that improves performance with use and thus promises to greatly accelerate discovery of many new metallic glasses. We believe that this discovery paradigm is applicable to a wider range of materials and should prove equally powerful for other materials and properties that are synthesis path-dependent and that current physiochemical theories find challenging to predict.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 392, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaq1566", "DOI": "10.1126/sciadv.aaq1566", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaq1566", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431374900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, B; Li, J; Zhang, J; Ning, HY; Fang, XQ; Shen, J; Zhou, H; Jiang, TL; Gao, ZH; Meng, XE; Wang, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Bin; Li, Jie; Zhang, Jing; Ning, Huiying; Fang, Xiaoqi; Shen, Jian; Zhou, Heng; Jiang, Tianlong; Gao, Zhenhua; Meng, Xiangeng; Wang, Zifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solid-State Fluorescent Carbon Dots with Unprecedented Efficiency from Visible to Near-Infrared Region", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing solid-state luminescent materials with bright long-wavelength emissions is of considerable practical importance in light-emitting diodes (LEDs) but remains a formidable challenge. Here, a novel structure engineering strategy is reported to realize solid-state fluorescence (FL)-emitted carbon dots (CDs) from visible to near-infrared region. This is the first report of such an extended wavelength emission of self-quenching-resistant solid-state CDs. Notably, the quantum yields of these CDs are remarkably improved up to 67.7%, which is the highest value for solid-state CDs. The surface polymer chains of CDs can efficiently suppress the conjugated sp(2) carbon cores from pi-pi stacking inducing aggregation caused FL quenching, and the redshift of FL emissions is attributed to narrowing bandgap caused by an enlarged sp(2) carbon core. Using these CDs as conversion phosphors, the fabrication of white LEDs with adjustable correlated color temperatures of 1882-5019 K is achieved. Moreover, a plant growth LED device is assembled with a blue-LED chip and deep-red/near-infrared-emitted CDs. Compared with sunlight and white LEDs, the peanuts irradiated by plant growth LED lamp show higher growth efficiency in terms of branches and leaves. This work provides high-quality solid-state CD-based phosphors for LED lighting sources that are required for diverse optoelectronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205788", "DOI Link": "http://dx.doi.org/10.1002/advs.202205788", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000925023200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, JR; Gao, GY; Huang, JR; Yang, XX; Han, J; Zhang, H; Chen, YH; Zhao, CL; Sun, QJ; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Jinran; Gao, Guoyun; Huang, Jinrong; Yang, Xixi; Han, Jing; Zhang, Huai; Chen, Youhui; Zhao, Chunlin; Sun, Qijun; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contact-electrification-activated artificial afferents at femtojoule energy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low power electronics endowed with artificial intelligence and biological afferent characters are beneficial to neuromorphic sensory network. Highly distributed synaptic sensory neurons are more readily driven by portable, distributed, and ubiquitous power sources. Here, we report a contact-electrification-activated artificial afferent at femtojoule energy. Upon the contact-electrification effect, the induced triboelectric signals activate the ion-gel-gated MoS2 postsynaptic transistor, endowing the artificial afferent with the adaptive capacity to carry out spatiotemporal recognition/sensation on external stimuli (e.g., displacements, pressures and touch patterns). The decay time of the synaptic device is in the range of sensory memory stage. The energy dissipation of the artificial afferents is significantly reduced to 11.9 fJ per spike. Furthermore, the artificial afferents are demonstrated to be capable of recognizing the spatiotemporal information of touch patterns. This work is of great significance for the construction of next-generation neuromorphic sensory network, self-powered biomimetic electronics and intelligent interactive equipment. Low power electronics endowed with artificial intelligence and biological afferent characters are beneficial to neuromorphic sensory network. Here, the authors report contact-electrification-activated artificial afferent at femtojoule energy, which is able to carry out spatiotemporal recognition on external stimuli.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1581, "DOI": "10.1038/s41467-021-21890-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21890-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629597700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elling, BR; Dichtel, WR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elling, Benjamin R.; Dichtel, William R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reprocessable Cross-Linked Polymer Networks: Are Associative Exchange Mechanisms Desirable?", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent adaptable networks (CANs) are covalently cross-linked polymers that may be reshaped via cross-linking and/or strand exchange at elevated temperatures. They represent an exciting and rapidly developing frontier in polymer science for their potential as stimuli-responsive materials and to make traditionally nonrecyclable thermosets more sustainable. CANs whose cross-links undergo exchange via associative intermediates rather than dissociating to separate reactive groups are termed vitrimers. Vitrimers were postulated to be an attractive subset of CANs, because associative cross-link exchange mechanisms maintain the original cross-link density of the network throughout the exchange process. As a result, associative CANs demonstrate a gradual, Arrhenius-like reduction in viscosity at elevated temperatures while maintaining mechanical integrity. In contrast, CANs reprocessed by dissociation and reformation of cross-links have been postulated to exhibit a more rapid decrease in viscosity with increasing temperature. Here, we survey the stress relaxation behavior of all dissociative CANs for which variable temperature stress relaxation or viscosity data are reported to date. All exhibit an Arrhenius relationship between temperature and viscosity, as only a small percentage of the cross-links are broken instantaneously under typical reprocessing conditions. As such, dissociative and associative CANs show nearly identical reprocessing behavior over broad temperature ranges typically used for reprocessing. Given that the term vitrimer was coined to highlight an Arrhenius relationship between viscosity and temperature, in analogy to vitreous glasses, we discourage its continued use to describe associative CANs. The realization that the cross-link exchange mechanism does not greatly influence the practical reprocessing behavior of most CANs suggests that exchange chemistries can be considered with fewer constraints, focusing instead on their activation parameters, synthetic convenience, and application-specific considerations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2020, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1488, "End Page": 1496, "Article Number": null, "DOI": "10.1021/acscentsci.0c00567", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c00567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000575687100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ban, MY; Zou, YT; Rivett, JPH; Yang, YG; Thomas, TH; Tan, YS; Song, T; Gao, XY; Credington, D; Deschler, F; Sirringhaus, H; Sun, BQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ban, Muyang; Zou, Yatao; Rivett, Jasmine P. H.; Yang, Yingguo; Thomas, Tudor H.; Tan, Yeshu; Song, Tao; Gao, Xingyu; Credington, Dan; Deschler, Felix; Sirringhaus, Henning; Sun, Baoquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nullostructure tailoring", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organometal halide perovskites (OHP) are promising materials for low-cost, high-efficiency light-emitting diodes. In films with a distribution of two-dimensional OHP nullosheets and small three-dimensional nullocrystals, an energy funnel can be realized that concentrates the excitations in highly efficient radiative recombination centers. However, this energy funnel is likely to contain inefficient pathways as the size distribution of nullocrystals, the phase separation between the OHP and the organic phase. Here, we demonstrate that the OHP crystallite distribution and phase separation can be precisely controlled by adding a molecule that suppresses crystallization of the organic phase. We use these improved material properties to achieve OHP light-emitting diodes with an external quantum efficiency of 15.5%. Our results demonstrate that through the addition of judiciously selected molecular additives, sufficient carrier confinement with first-order recombination characteristics, and efficient suppression of non-radiative recombination can be achieved while retaining efficient charge transport characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3892, "DOI": "10.1038/s41467-018-06425-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06425-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445329000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chabak, KD; Moser, N; Green, AJ; Walker, DE; Tetlak, SE; Heller, E; Crespo, A; Fitch, R; McCandless, JP; Leedy, K; Baldini, M; Wagner, G; Galazka, Z; Li, XL; Jessen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chabak, Kelson D.; Moser, Neil; Green, Andrew J.; Walker, Dennis E.; Tetlak, Stephen E.; Heller, Eric; Crespo, Antonio; Fitch, Robert; McCandless, Jonathan P.; Leedy, Kevin; Baldini, Michele; Wagner, Gunter; Galazka, Zbigniew; Li, Xiuling; Jessen, Gregg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement-mode Ga2O3 wrap-gate fin field-effect transistors on native (100) β-Ga2O3 substrate with high breakdown voltage", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sn-doped gallium oxide (Ga2O3) wrap-gate fin-array field-effect transistors (finFETs) were formed by top-down BCl3 plasma etching on a native semi-insulating Mg-doped (100) beta-Ga2O3 substrate. The fin channels have a triangular cross-section and are approximately 300 nm wide and 200 nm tall. FinFETs, with 20 nm Al2O3 gate dielectric and similar to 2 mu m wrap-gate, demonstrate normally-off operation with a threshold voltage between 0 and +1V during high-voltage operation. The I-ON/I-OFF ratio is greater than 10(5) and is mainly limited by high on-resistance that can be significantly improved. At V-G = 0, a finFET with 21 mu m gate-drain spacing achieved a three-terminal breakdown voltage exceeding 600V without a field-plate. (C) 2016 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2016, "Volume": 109, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 213501, "DOI": "10.1063/1.4967931", "DOI Link": "http://dx.doi.org/10.1063/1.4967931", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388834200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YS; Chen, G; Tong, W; Pi, L; Liu, JJ; Yang, ZR; Wang, XQ; Zhang, QM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuesheng; Chen, Gang; Tong, Wei; Pi, Li; Liu, Juanjuan; Yang, Zhaorong; Wang, Xiaoqun; Zhang, Qingming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rare-Earth Triangular Lattice Spin Liquid: A Single-Crystal Study of YbMgGaO4", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "YbMgGaO4, a structurally perfect two-dimensional triangular lattice with an odd number of electrons per unit cell and spin-orbit entangled effective spin-1/2 local moments for the Yb3+ ions, is likely to experimentally realize the quantum spin liquid ground state. We report the first experimental characterization of single-crystal YbMgGaO4 samples. Because of the spin-orbit entanglement, the interaction between the neighboring Yb3+ moments depends on the bond orientations and is highly anisotropic in the spin space. We carry out thermodynamic and the electron spin resonullce measurements to confirm the anisotropic nature of the spin interaction as well as to quantitatively determine the couplings. Our result is a first step towards the theoretical understanding of the possible quantum spin liquid ground state in this system and sheds new light on the search for quantum spin liquids in strong spin-orbit coupled insulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2015, "Volume": 115, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 167203, "DOI": "10.1103/PhysRevLett.115.167203", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.167203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362909100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Connolly, BM; Madden, D; Wheatley, A; Fairen-Jimenez, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Connolly, Bethany M.; Madden, David; Wheatley, Andrew; Fairen-Jimenez, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shaping the Future of Fuel: Monolithic Metal-Organic Frameworks for High-Density Gas Storage", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The environmental benefits of cleaner, gaseous fuels such as natural gas and hydrogen are widely reported. Yet, practical usage of these fuels is inhibited by current gas storage technology. Here, we discuss the wide-ranging potential of gas-fuels to revolutionize the energy sector and introduce the limitations of current storage technology that prevent this transition from taking place. The practical capabilities of adsorptive gas storage using porous, crystalline metal-organic frameworks (MOFs) are examined with regard to recent benchmark results and ultimate storage targets in this field. In particular, the industrial limitations of typically powdered MOFs are discussed while recent breakthroughs in MOF processing are highlighted. We offer our perspective on the future of practical, rather than purely academic, MOF developments in the increasingly critical field of environmental fuel storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2020, "Volume": 142, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8541, "End Page": 8549, "Article Number": null, "DOI": "10.1021/jacs.0c00270", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c00270", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535252100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WF; Han, W; Jiang, X; Yang, SH; Parkin, SSP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Weifeng; Han, Wei; Jiang, Xin; Yang, See-Hun; Parkin, Stuart S. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of transparency of platinum-ferromagnet interfaces in determining the intrinsic magnitude of the spin Hall effect", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin Hall effect converts charge current to pure spin currents in orthogonal directions in materials that have significant spin-orbit coupling. The efficiency of the conversion is described by the spin Hall angle (SHA). The SHA can most readily be inferred by using the generated spin currents to excite or rotate the magnetization of ferromagnetic films or nullo-elements via spin-transfer torques. Some of the largest spin-torque-derived spin Hall angles (ST-SHA) have been reported in platinum. Here we show, using spin-torque ferromagnetic resonullce measurements, that the transparency of the Pt-ferromagnet interface to the spin current plays a central role in determining the magnitude of the ST-SHA. We measure a much larger ST-SHA in Pt/cobalt (similar to 0.11) compared to Pt/permalloy (similar to 0.05) bilayers when the interfaces are assumed to be completely transparent. Taking into account the transparency of these interfaces, as derived from spin-mixing conductances, we find that the intrinsic SHA in platinum has a much higher value of 0.19 +/- 0.04 as compared to the ST-SHA. The importance of the interface transparency is further exemplified by the insertion of atomically thin magnetic layers at the Pt/permalloy interface that we show strongly modulates the magnitude of the ST-SHA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 496, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3304", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3304", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355552200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Broom, DP; Webb, CJ; Fanourgakis, GS; Froudakis, GE; Trikalitis, PN; Hirscher, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Broom, D. P.; Webb, C. J.; Fanourgakis, G. S.; Froudakis, G. E.; Trikalitis, P. N.; Hirscher, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Concepts for improving hydrogen storage in nulloporous materials", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen storage in nulloporous materials has been attracting a great deal of attention in recent years, as high gravimetric H-2 capacities, exceeding 10 wt% in some cases, can be achieved at 77 K using materials with particularly high surface areas. However, volumetric capacities at low temperatures, and both gravimetric and volumetric capacities at ambient temperature, need to be improved before such adsorbents become practically viable. This article therefore discusses approaches to increasing the gravimetric and volumetric hydrogen storage capacities of nulloporous materials, and maximizing the usable capacity of a material between the upper storage and delivery pressures. In addition, recent advances in machine learning and data science provide an opportunity to apply this technology to the search for new materials for hydrogen storage. The large number of possible component combinations and substitutions in various porous materials, including Metal-Organic Frameworks (MOFs), is ideally suited to a machine learning approach; so this is also discussed, together with some new material types that could prove useful in the future for hydrogen storage applications. (C) 2019 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2019, "Volume": 44, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 7768, "End Page": 7779, "Article Number": null, "DOI": "10.1016/j.ijhydene.2019.01.224", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2019.01.224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463306900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, BY; Wang, HF; Wang, HX; Zhu, XY; Jiang, JH; Lu, MH; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Bi-Ye; Wang, Hong-Fei; Wang, Hai-Xiao; Zhu, Xue-Yi; Jiang, Jian-Hua; Lu, Ming-Hui; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Second-order photonic topological insulator with corner states", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Higher-order topological insulators (HOTIs) which go beyond the description of conventional bulk-boundary correspondence, broaden the understanding of topological insulating phases. Being mainly focused on electronic materials, HOTIs have not yet been found in photonic crystals. Here, we propose a type of two-dimensional second-order photonic crystals with zero-dimensional corner states and one-dimensional boundary states for optical frequencies. All of these states are topologically nontrivial and can be understood based on the theory of topological polarization. Moreover, by tuning the easily fabricated structure of the photonic crystals, different topological phases can be realized straightforwardly. Our study can be generalized to higher dimensions and provides a platform for higher-order photonic topological insulators and semimetals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2018, "Volume": 98, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205147, "DOI": "10.1103/PhysRevB.98.205147", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.98.205147", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451333100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, B; He, B; Peng, HQ; Zhao, YF; Cheng, JY; Xia, J; Shen, JH; Ng, TW; Meng, XM; Lee, CS; Zhang, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Bin; He, Bin; Peng, Hui-Qing; Zhao, Yufei; Cheng, Junye; Xia, Jing; Shen, Jianhua; Ng, Tsz-Wai; Meng, Xiangmin; Lee, Chun-Sing; Zhang, Wenjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional Nickel Nitride Enriched with Nitrogen Vacancies as a High-Efficiency Electrocatalyst for Hydrogen Evolution", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of high-performance and cost-effective non-noble metal electrocatalysts is pivotal for the eco-friendly production of hydrogen through electrolysis and hydrogen energy applications. Herein, the synthesis of an unconventional nickel nitride nullostructure enriched with nitrogen vacancies (Ni3N1-x) through plasma-enhanced nitridation of commercial Ni foam (NF) is reported. The self-supported Ni3N1-x/NF electrode can deliver a hydrogen evolution reaction (HER) activity competitive to commercial Pt/C catalyst in alkaline condition (i.e., an overpotential of 55 mV at 10 mA cm(-2) and a Tafel slope of 54 mV dec(-1)), which is much superior to the stoichiometric Ni3N, and is the best among all nitride-based HER electrocatalysts in alkaline media reported thus far. Based on theoretical calculations, it is further verified that the presence of nitrogen vacancies effectively enhances the adsorption of water molecules and ameliorates the adsorption-desorption behavior of intermediately adsorbed hydrogen, which leads to an advanced HER activity of Ni3N1-x/NF.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800406, "DOI": "10.1002/advs.201800406", "DOI Link": "http://dx.doi.org/10.1002/advs.201800406", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441869400037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, ZH; Pang, CS; Wang, PQ; Le, ST; Wu, YQ; Shahrjerdi, D; Radu, I; Lemme, MC; Peng, LM; Duan, XF; Chen, ZH; Appenzeller, J; Koester, SJ; Pop, E; Franklin, AD; Richter, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Zhihui; Pang, Chin-Sheng; Wang, Peiqi; Le, Son T.; Wu, Yanqing; Shahrjerdi, Davood; Radu, Iuliana; Lemme, Max C.; Peng, Lian-Mao; Duan, Xiangfeng; Chen, Zhihong; Appenzeller, Joerg; Koester, Steven J.; Pop, Eric; Franklin, Aaron D.; Richter, Curt A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How to report and benchmark emerging field-effect transistors", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of organic, oxide and low-dimensional materials in field-effect transistors has now been studied for decades. However, properly reporting and comparing device performance remains challenging due to the interdependency of multiple device parameters. The interdisciplinarity of this research community has also led to a lack of consistent reporting and benchmarking guidelines. Here we propose guidelines for reporting and benchmarking key field-effect transistor parameters and performance metrics. We provide an example of this reporting and benchmarking process using a two-dimensional semiconductor field-effect transistor. Our guidelines should help promote an improved approach for assessing device performance in emerging field-effect transistors, helping the field to progress in a more consistent and meaningful way. This Perspective examines the challenges involved in assessing the operation and performance of field-effect transistors based on emerging materials, and provides guidelines for the consistent reporting and benchmarking of the devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 416, "End Page": 423, "Article Number": null, "DOI": "10.1038/s41928-022-00798-8", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00798-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000833024400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YZ; Hu, Q; Liang, HM; Wang, AP; Xu, H; Wang, L; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yanzhou; Hu, Qiao; Liang, Hongmei; Wang, Aiping; Xu, Hong; Wang, Li; He, Xiangming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatic Potential as Solvent Descriptor to Enable Rational Electrolyte Design for Lithium Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial intelligence/machine learning (AI/ML) applied to battery research is considered to be a powerful tool for accelerating the research cycle. However, the development of appropriate materials descriptors is often the first hurdle toward implementing meaningful and accurate AI/ML. Currently, rational solvent selection remains a significant challenge in electrolyte development and is still based on experiments. The dielectric constant (e) and donor number (DN) in electrolyte design are insufficient. Finding theoretically computable solvent descriptors for evaluating Li+ solvation is a significant step toward accelerating electrolyte development. Here, based on the electrostatic interaction between Li+ and solvent, the electrostatic potential (ESP) of electrolyte solvent is calculated by density functional theory calculations and reveals significant regularity. ESP as a direct and simple solvent descriptor for conveniently designing electrolytes is proposed. The lowest negative electrostatic potential (ESPmin) ensures the nucleophilic capacity of the solvating solvent and the weak ESPmin means decreased solvation energy. Weak ESPmin and strong highest positive electrostatic potential (ESPmax) are the main characteristics of non-solvating antisolvents. Using the plot of ESPmin - ESPmax strong solvating solvent, weakly solvating solvent, or antisolvent are identified that have been used in electrolyte engineering. This solvent descriptor can boost AI/ML to develop high performance electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 13, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202300259", "DOI Link": "http://dx.doi.org/10.1002/aenm.202300259", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000970755900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CX; Hua, LJ; Yan, HZ; Li, BJ; Tu, YD; Wang, RZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenxi; Hua, Lingji; Yan, Hongzhi; Li, Bangjun; Tu, Yaodong; Wang, Ruzhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Thermal Management Strategy for Electronic Devices Based on Moisture Sorption-Desorption Processes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, the thermal management of electronics has been drawing growing attention. The use of latent heat emerges as an attractive means for intermittent heat dissipation. However, traditional phase change materials (PCMs) are limited by their relatively low enthalpies. In this paper, we demonstrate a passive thermal management strategy through the desorption process of water inside sorbents. The spontaneous adsorption enables self-recovery of working capacity at rest mode. The basic guideline for selecting proper sorbents is outlined. In the proof-of-concept test, we coated MIL-101(Cr) powders onto metallic substrates. The coating of 0.288 g achieved a temperature drop (maximum 8.6 degrees C) for 25 min at a heating power of 1.5 W. The equivalent enthalpy of the coating can be up to 1,950 J/g(coating), indicating a significant improvement compared to that of traditional PCMs. Our results suggest that this strategy could find promising applications in a variety of practical scenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2020, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 435, "End Page": 447, "Article Number": null, "DOI": "10.1016/j.joule.2019.12.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.12.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515121700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teo, WZ; Chng, ELK; Sofer, Z; Pumera, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teo, Wei Zhe; Chng, Elaine Lay Khim; Sofer, Zdenek; Pumera, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cytotoxicity of Exfoliated Transition-Metal Dichalcogenides (MoS2, WS2, and WSe2) is Lower Than That of Graphene and its Analogues", "Source Title": "CHEMISTRY-A EUROPEAN JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Studies involving transition-metal dichalcogenides (TMDs) have been around for many decades and in recent years, many were focused on using TMDs to synthesize inorganic analogues of carbon nullotubes, fullerene, as well as graphene and its derivatives with the ultimate aim of employing these materials into consumer products. In view of this rising trend, we investigated the cytotoxicity of three common exfoliated TMDs (exTMDs), namely MoS2, WS2, and WSe2, and compared their toxicological effects with graphene oxides and halogenated graphenes to find out whether these inorganic analogues of graphenes and derivatives would show improved biocompatibility. Based on the cell viability assessments using methylthiazolyldiphenyl-tetrazolium bromide (MTT) and water-soluble tetrazolium salt (WST-8) assays on human lung carcinoma epithelial cells (A549) following a 24 h exposure to varying concentrations of the three exTMDs, it was concluded that MoS2 and WS2 nullosheets induced very low cytotoxicity to A549 cells, even at high concentrations. On the other hand, WSe2 exhibited dose-dependent toxicological effects on A549 cells, reducing cell viability to 31.8% at the maximum concentration of 400 mu g mL(-1); the higher cytotoxicity displayed by WSe2 might be linked to the identity of the chalcogen. In comparison with graphene oxides and halogenated graphenes, MoS2 and WS2 were much less hazardous, whereas WSe2 showed similar degree of cytotoxicity. Future in-depth studies should be built upon this first work on the in vitro cytotoxicity of MoS2 and WS2 to ensure that they do not pose acute toxicity. Lastly, nullomaterial-induced interference control experiments revealed that exTMDs were capable of reacting with MTT assay viability markers in the absence of cells, but not with WST-8 assay. This suggests that the MTT assay is not suitable for measuring the cytotoxicity of exTMDs because inflated results will be obtained, giving false impressions that the materials are less toxic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2014, "Volume": 20, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9627, "End Page": 9632, "Article Number": null, "DOI": "10.1002/chem.201402680", "DOI Link": "http://dx.doi.org/10.1002/chem.201402680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340176600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YJ; Wu, Y; Li, HY; Chen, JH; Lei, DN; Wang, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuji; Wu, Yuan; Li, Huiyi; Chen, Jinghao; Lei, Danni; Wang, Chengxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A dual-function liquid electrolyte additive for high-energy non-aqueous lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering the formulation of non-aqueous liquid electrolytes is a viable strategy to produce high-energy lithium metal batteries. However, when the lithium metal anode is combined with a Ni-rich layered cathode, the (electro)chemical stability of both electrodes could be compromised. To circumvent this issue, we report a combination of aluminum ethoxide (0.4 wt.%) and fluoroethylene carbonate (5 vol.%) as additives in a conventional LiPF6-containing carbonate-based electrolyte solution. This electrolyte formulation enables the formation of mechanically robust and ionically conductive interphases on both electrodes' surfaces. In particular, the alumina formed at the interphases prevents the formation of dendritic structures on the lithium metal anode and mitigate the stress-induced cracking and phase transformation in the Ni-rich layered cathode. By coupling a thin (i.e., about 40 mu m) lithium metal anode with a high-loading (i.e., 21.5 mg cm(-2)) LiNi0.8Co0.1Mn0.1O2-based cathode in coin cell configuration and lean electrolyte conditions, the engineered electrolyte allows a specific discharge capacity retention of 80.3% after 130 cycles at 60 mA g(-1) and 30 degrees C which results in calculated specific cell energy of about 350 Wh kg(-1). Lithium metal batteries suffer from poor (electro)chemical stability of the electrodes during prolonged cycling. Here, the authors report a dual function liquid electrolyte additive to form protective interphases on both electrodes to produce lab-scale high energy lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1297, "DOI": "10.1038/s41467-022-28959-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28959-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767892300027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, J; Ivanov, MS; Khomchenko, VA; Mamontova, E; Thibaud, JM; Rouquette, J; Beaudhuin, M; Granier, D; Ferreira, RAS; Carlos, LD; Donnadieu, B; Henriques, MSC; Paixao, JA; Guari, Y; Larionova, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Jerome; Ivanov, Maxim S.; Khomchenko, Vladimir A.; Mamontova, Ekaterina; Thibaud, Jean-Marc; Rouquette, Jerome; Beaudhuin, Mickael; Granier, Dominique; Ferreira, Rute A. S.; Carlos, Luis D.; Donnadieu, Bruno; Henriques, Marta S. C.; Paixao, Jose Antonio; Guari, Yannick; Larionova, Joulia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature magnetoelectric coupling in a molecular ferroelectric ytterbium(III) complex", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetoelectric (ME) materials combine magnetic and electric polarizabilities in the same phase, offering a basis for developing high-density data storage and spintronic or low-consumption devices owing to the possibility of triggering one property with the other. Such applications require strong interaction between the constitutive properties, a criterion that is rarely met in classical inorganic ME materials at room temperature. We provide evidence of a strong ME coupling in a paramagnetic ferroelectric lanthanide coordination complex with magnetostrictive phenomenon. The properties of this molecular material suggest that it may be competitive with inorganic magnetoelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2020, "Volume": 367, "Issue": 6478, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 671, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz2795", "DOI Link": "http://dx.doi.org/10.1126/science.aaz2795", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512382900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sanchez, DS; Belopolski, I; Cochran, TA; Xu, XT; Yin, JX; Chang, GQ; Xie, WW; Manna, K; Süss, V; Huang, CY; Alidoust, N; Multer, D; Zhang, STS; Shumiya, N; Wang, XR; Wang, GQ; Chang, TR; Felser, C; Xu, SY; Jia, S; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sanchez, Daniel S.; Belopolski, Ilya; Cochran, Tyler A.; Xu, Xitong; Yin, Jia-Xin; Chang, Guoqing; Xie, Weiwei; Manna, Kaustuv; Suss, Vicky; Huang, Cheng-Yi; Alidoust, Nasser; Multer, Daniel; Zhang, Songtian S.; Shumiya, nulla; Wang, Xirui; Wang, Guang-Qiang; Chang, Tay-Rong; Felser, Claudia; Xu, Su-Yang; Jia, Shuang; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological chiral crystals with helicoid-arc quantum states", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantum behaviour of electrons in materials is the foundation of modern electronics and information technology(1-11), and quantum materials with topological electronic and optical properties are essential for realizing quantized electronic responses that can be used for next generation technology. Here we report the first observation of topological quantum properties of chiral crystals(6,7) in the RhSi family. We find that this material class hosts a quantum phase of matter that exhibits nearly ideal topological surface properties originating from the crystals' structural chirality. Electrons on the surface of these crystals show a highly unusual helicoid fermionic structure that spirals around two high-symmetry momenta, indicating electronic topological chirality. The existence of bulk multiply degenerate band fermions is guaranteed by the crystal symmetries; however, to determine the topological invariant or charge in these chiral crystals, it is essential to identify and study the helicoid topology of the arc states. The helicoid arcs that we observe on the surface characterize the topological charges of +/- 2, which arise from bulk higher-spin chiral fermions. These topological conductors exhibit giant Fermi arcs of maximum length (pi), which are orders of magnitude larger than those found in known chiral Weyl fermion semimetals(5,8-11). Our results demonstrate an electronic topological state of matter on structurally chiral crystals featuring helicoid-arc quantum states. Such exotic multifold chiral fermion semimetal states could be used to detect a quantized photogalvanic optical response, the chiral magnetic effect and other optoelectronic phenomena predicted for this class of materials(6).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2019, "Volume": 567, "Issue": 7749, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 500, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1037-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1037-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462655800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XG; Chen, CX; Kaj, K; Hammock, I; Huang, YW; Averitt, RD; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xiaoguang; Chen, Chunxu; Kaj, Kelson; Hammock, Ian; Huang, Yuwei; Averitt, Richard D.; Zhang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Terahertz investigation of bound states in the continuum of metallic metasurfaces", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The concept of bound states in the continuum (BIC) describes an idealized physical system exhibiting zero radiative loss composed, for example, of an infinitely extended array of resonators. In principle, vanishing of radiative losses enables an infinitely high-quality factor and corresponding infinite lifetime of the resonullce. As such, BIC inspired metasurfaces and photonic designs aim to achieve superior performance in various applications including sensing and lasing. We describe an analytical model based on temporal coupled mode theory to realize an accidental (i.e., parameter-tuned) Friedrich-Wintgen BIC. Further, we experimentally verify this model with measurements of quasi-BICs in a metallic terahertz metasurface (MS) and the corresponding complementary metasurface (CMS) using terahertz time domain spectroscopy. For the MS and CMS structures, quality factors of similar to 20 are achieved, limited by non-radiative intrinsic loss in the materials. Our results reveal that Babinet's principle qualitatively holds for the MS and CMS quasi-BIC structures. In addition, ultra-high electric and magnetic field enhancement MS and CMS structures, respectively, are presented. (C) 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2020, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1548, "End Page": 1554, "Article Number": null, "DOI": "10.1364/OPTICA.404754", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.404754", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000593390500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZJ; Gresch, D; Soluyanov, AA; Xie, WW; Kushwaha, S; Dai, X; Troyer, M; Cava, RJ; Bernevig, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhijun; Gresch, Dominik; Soluyanov, Alexey A.; Xie, Weiwei; Kushwaha, S.; Dai, Xi; Troyer, Matthias; Cava, Robert J.; Bernevig, B. Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoTe2: A Type-II Weyl Topological Metal", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on the ab initio calculations, we show that MoTe2, in its low-temperature orthorhombic structure characterized by an x-ray diffraction study at 100 K, realizes 4 type-II Weyl points between the Nth and (N + 1)th bands, where N is the total number of valence electrons per unit cell. Other WPs and nodal lines between different other bands also appear close to the Fermi level due to a complex topological band structure. We predict a series of strain-driven topological phase transitions in this compound, opening a wide range of possible experimental realizations of different topological semimetal phases. Crucially, with no strain, the number of observable surface Fermi arcs in this material is 2-the smallest number of arcs consistent with time-reversal symmetry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2016, "Volume": 117, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 56805, "DOI": "10.1103/PhysRevLett.117.056805", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.056805", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381470200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, QF; Cai, J; Tong, WY; Gong, SJ; Wang, JQ; Wan, XG; Duan, CG; Chu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Qun-Fang; Cai, Jia; Tong, Wen-Yi; Gong, Shi-Jing; Wang, Ji-Qing; Wan, Xiangang; Duan, Chun-Gang; Chu, J. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Manipulation of the large Rashba spin splitting in polar two-dimensional transition-metal dichalcogenides", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition-metal dichalcogenide (TMD) monolayers MXY (M = Mo, W; X not equal Y = S, Se, Te) are two-dimensional polar semiconductors. Setting the WSeTe monolayer as an example and using density functional theory calculations, we investigate the manipulation of Rashba spin-orbit coupling (SOC) in the MXY monolayer. It is found that the intrinsic out-of-plane electric field due to the mirror symmetry breaking induces the large Rashba spin splitting around the F point, which, however, can be easily tuned by applying the in-plane biaxial strain. Through a relatively small strain (from -2% to 2%), a large tunability (from around -50% to 50%) of Rashba SOC can be obtained due to the modified orbital overlap, which can in turn modulate the intrinsic electric field. The orbital selective external potential method further confirms the significance of the orbital overlap between W-d(z2) and Se-p(z) in Rashba SOC. In addition, we also explore the influence of the external electric field on Rashba SOC in the WSeTe monolayer, which is less effective than strain. By calculating the electric-field-induced Rashba SOC in all six MX2 monolayers, the rule of the electric-field influence on Rashba SOC in TMD monolayers is demonstrated. The large Rashba spin splitting, together with the valley spin splitting in MXY monolayers, may make a special contribution to semiconductor spintronics and valleytronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2017, "Volume": 95, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 165401, "DOI": "10.1103/PhysRevB.95.165401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.165401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440606200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, LF; Chen, B; Zhang, ZH; Ma, C; Chen, JC; Huang, Y; Zhang, F; Dong, QY; Xue, GY; Chen, D; Hu, C; Li, S; Liu, Z; Shen, YB; Chen, Q; Chen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Lingfei; Chen, Bowen; Zhang, Zhonghan; Ma, Changqi; Chen, Junchao; Huang, Yage; Zhang, Fengrui; Dong, Qingyu; Xue, Guoyong; Chen, Daiqian; Hu, Chenji; Li, Shuzhou; Liu, Zheng; Shen, Yanbin; Chen, Qi; Chen, Liwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyfluorinated crosslinker-based solid polymer electrolytes for long-cycling 4.5V lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid polymer electrolytes (SPEs), which are favorable to form intimate interfacial contacts with electrodes, are promising electrolyte of choice for long-cycling lithium metal batteries (LMBs). However, typical SPEs with easily oxidized oxygen-bearing polar groups exhibit narrow electrochemical stability window (ESW), making it impractical to increase specific capacity and energy density of SPE based LMBs with charging cut-off voltage of 4.5V or higher. Here, we apply a polyfluorinated crosslinker to enhance oxidation resistance of SPEs. The crosslinked network facilitates transmission of the inductive electron-withdrawing effect of polyfluorinated segments. As a result, polyfluorinated crosslinked SPE exhibits a wide ESW, and the Li vertical bar SPE vertical bar LiNi0.5Co0.2Mn0.3O2 cell with a cutoff voltage of 4.5V delivers a high discharge specific capacity of similar to 164.19 mAh g(-1) at 0.5C and capacity retention of similar to 90% after 200 cycles. This work opens a direction in developing SPEs for long-cycling high-voltage LMBs by using polyfluorinated crosslinking strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2301, "DOI": "10.1038/s41467-023-37997-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37997-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghiringhelli, LM; Vybiral, J; Levchenko, SV; Draxl, C; Scheffler, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghiringhelli, Luca M.; Vybiral, Jan; Levchenko, Sergey V.; Draxl, Claudia; Scheffler, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Big Data of Materials Science: Critical Role of the Descriptor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Statistical learning of materials properties or functions so far starts with a largely silent, nonchallenged step: the choice of the set of descriptive parameters (termed descriptor). However, when the scientific connection between the descriptor and the actuating mechanisms is unclear, the causality of the learned descriptor-property relation is uncertain. Thus, a trustful prediction of new promising materials, identification of anomalies, and scientific advancement are doubtful. We analyze this issue and define requirements for a suitable descriptor. For a classic example, the energy difference of zinc blende or wurtzite and rocksalt semiconductors, we demonstrate how a meaningful descriptor can be found systematically.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 678, "Times Cited, All Databases": 770, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2015, "Volume": 114, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105503, "DOI": "10.1103/PhysRevLett.114.105503", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.105503", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352073400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, JX; Xiao, K; Chen, YX; Guo, XP; Huang, BL; Liu, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Jinxin; Xiao, Kang; Chen, Yanxiang; Guo, Xing-Peng; Huang, Bolong; Liu, Zhao-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ precise anchoring of Pt single atoms in spinel Mn3O4 for a highly efficient hydrogen evolution reaction", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the synthesis of single atom catalysts (SACs) has attracted intensive attention for the hydrogen evolution reaction (HER), realizing the precise control of the structure of atomic catalysts and the electronic metal-support interaction is still highly challenging. The understanding of SACs at the atomic level is particularly important for further improving their electrochemical performances. Herein, we have reported the synthesis of a spinel Mn3O4 supported Pt SAC (Pt-SA-Mn3O4) based on the in situ precise anchoring of the Pt atoms in the octahedral sites for the first time. The strong interactions between Pt and Mn3O4 have significantly modulated the electronic structures with an optimized d-band center and binding strength of intermediates. In an alkaline environment, the catalyst shows an excellent HER performance with an ultra-low overpotential of 24 mV at 10 mA cm(-2) and a high mass activity of 374 mA mg(Pt)(-1) (50 mV), which are superior to those of 20 wt% Pt/C and the most reported high-performance catalysts. This work has supplied insightful information for the rational design of efficient SACs with high controllability and superior performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2022, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4592, "End Page": 4600, "Article Number": null, "DOI": "10.1039/d2ee02151j", "DOI Link": "http://dx.doi.org/10.1039/d2ee02151j", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000855733200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chai, LL; Wang, X; Hu, Y; Li, XF; Huang, SM; Pan, JQ; Qian, JJ; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chai, Lulu; Wang, Xian; Hu, Yue; Li, Xifei; Huang, Shaoming; Pan, Junqing; Qian, Jinjie; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-MOF-Derived Hierarchically Hollow Carbon nullostraws for Advanced Zinc-Iodine Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hollow carbon materials are regarded as crucial support materials in catalysis and electrochemical energy storage on account of their unique porous structure and electrical properties. Herein, an indium-based organic framework of InOF-1 can be thermally carbonized under inert argon to form indium particles through the redox reaction between nullosized indium oxide and carbon matrix. In particular, a type of porous hollow carbon nullostraw (HCNS) is in situ obtained by combining the fusion and removal of indium within the decarboxylation process. The as-synthesized HCNS, which possesses more charge active sites, short and quick electron, and ion transport pathways, has become an excellent carrier for electrochemically active species such as iodine with its unique internal cavity and interconnected porous structure on the tube wall. Furthermore, the assembled zinc-iodine batteries (ZIBs) provide a high capacity of 234.1 mAh g(-1) at 1 A g(-1), which ensures that the adsorption and dissolution of iodine species in the electrolyte reach a rapid equilibrium. The rate and cycle performance of the HCNS-based ZIBs are greatly improved, thereby exhibiting an excellent capacity retention rate. It shows a better electrochemical exchange capacity than typical unidirectional carbon nullotubes, making HCNS an ideal cathode material for a new generation of high-performance batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 9, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202105063", "DOI Link": "http://dx.doi.org/10.1002/advs.202105063", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000862239500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Piaskowski, K; Swiderska-Dabrowska, R; Zarzycki, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Piaskowski, Krzysztof; Swiderska-Dabrowska, Renata; Zarzycki, Pawel K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dye Removal from Water and Wastewater Using Various Physical, Chemical, and Biological Processes", "Source Title": "JOURNAL OF AOAC INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthetic dyes or colorants are key chemicals for various industries producing textiles, food, cosmetics, pharmaceutics, printer inks, leather, and plastics. Nowadays, the textile industry is the major consumer of dyes. The mass of synthetic colorants used by this industry is estimated at the level of 1 divided by 3 x 10(5) tons, in comparison with the total annual consumption of around 7 x 10(5) tons worldwide. Synthetic dyes are relatively easy to detect but difficult to eliminate from wastewater and surface water ecosystems because of their aromatic chemical structure. It should be highlighted that the relatively high stability of synthetic dyes leads to health and ecological concerns due to their toxic, mutagenic, and carcinogenic nature. Currently, removal of such chemicals from wastewater involves various techniques, including flocculation/coagulation, precipitation, photocatalytic degradation, biological oxidation, ion exchange, adsorption, and membrane filtration. In this review, a number of classical and modern technologies for synthetic dye removal from industry-originated wastewater were summarized and discussed. There is an increasing interest in the application of waste organic materials (e.g., compounds extracted from orange bagasse, fungus biosorbent, or green algal biomasses) as effective, low-cost, and ecologically friendly sorbents. Moreover, a number of dye removal processes are based on newly discovered carbon nullomaterials (carbon nullotubes and graphene as well as their derivatives).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP-OCT", "Publication Year": 2018, "Volume": 101, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1371, "End Page": 1384, "Article Number": null, "DOI": "10.5740/jaoacint.18-0051", "DOI Link": "http://dx.doi.org/10.5740/jaoacint.18-0051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444527600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, ZQ; Jiang, L; Wardini, JL; MacDonald, BE; Wen, HM; Xiong, W; Zhang, DL; Zhou, YZ; Rupert, TJ; Chen, WP; Lavernia, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Zhiqiang; Jiang, Lin; Wardini, Jenna L.; MacDonald, Benjamin E.; Wen, Haiming; Xiong, Wei; Zhang, Dalong; Zhou, Yizhang; Rupert, Timothy J.; Chen, Weiping; Lavernia, Enrique J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A high-entropy alloy with hierarchical nulloprecipitates and ultrahigh strength", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) are a class of metallic materials that have revolutionized alloy design. They are known for their high compressive strengths, often greater than 1 GPa; however, the tensile strengths of most reported HEAs are limited. Here, we report a strategy for the design and fabrication of HEAs that can achieve ultrahigh tensile strengths. The proposed strategy involves the introduction of a high density of hierarchical intragranular nulloprecipitates. To establish the validity of this strategy, we designed and fabricated a bulk Fe25Co25Ni25Al10Ti15 HEA to consist of a principal face-centered cubic (fcc) phase containing hierarchical intragranular nulloprecipitates. Our results show that precipitation strengthening, as one of the main strengthening mechanisms, contributes to a tensile yield strength (sigma 0.2) of similar to 1.86 GPa and an ultimate tensile strength of similar to 2.52 GPa at room temperature, which heretofore represents the highest strength reported for an HEA with an appreciable failure strain of similar to 5.2%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat8712", "DOI": "10.1126/sciadv.aat8712", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat8712", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449221200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, DQ; Xu, HY; Zhang, QW; Huang, YC; Shi, CL; Chang, YC; Xu, XM; Tang, JY; Gu, YX; Pao, CW; Haw, SC; Chen, JM; Hu, ZW; Ni, M; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Daqin; Xu, Hengyue; Zhang, Qingwen; Huang, Yu-Cheng; Shi, Chenliang; Chang, Yu-Chung; Xu, Xiaomin; Tang, Jiayi; Gu, Yuxing; Pao, Chih-Wen; Haw, Shu-Chih; Chen, Jin-Ming; Hu, Zhiwei; Ni, Meng; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying a Universal Activity Descriptor and a Unifying Mechanism Concept on Perovskite Oxides for Green Hydrogen Production", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Producing indispensable hydrogen and oxygen for social development via water electrolysis shows more prospects than other technologies. Although electrocatalysts have been explored for centuries, a universal activity descriptor for both hydrogen-evolution reaction (HER) and oxygen-evolution reaction (OER) is not yet developed. Moreover, a unifying concept is not yet established to simultaneously understand HER/OER mechanisms. Here, the relationships between HER/OER activities in three common electrolytes and over ten representative material properties on 12 3d-metal-based model oxides are rationally bridged through statistical methodologies. The orbital charge-transfer energy (& UDelta;) can serve as an ideal universal descriptor, where a neither too large nor too small & UDelta; (& AP;1 eV) with optimal electron-cloud density around Fermi level affords the best activities, fulfilling Sabatier's principle. Systematic experiments and computations unravel that pristine oxide with & UDelta; & AP; 1 eV possesses metal-like high-valence configurations and active lattice-oxygen sites to help adsorb key protons in HER and induce lattice-oxygen participation in the OER, respectively. After reactions, partially generated metals in the HER and high-valence hydroxides in the OER dominate proton adsorption and couple with pristine lattice-oxygen activation, respectively. These can be successfully rationalized by the unifying orbital charge-transfer theory. This work provides the foundation of rational material design and mechanism understanding for many potential applications. A universal activity descriptor (orbital charge-transfer energy) is successfully extracted from various materials' physicochemical properties for both hydrogen-evolving and oxygen-evolving reactions in multiple electrolytes. Systematic experiments and computations reveal the life-cycle HER and OER mechanisms and identify the unifying orbital charge-transfer theory as a powerful mechanism analysis tool and foundation.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 35, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202305074", "DOI Link": "http://dx.doi.org/10.1002/adma.202305074", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001068123400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Rothmann, MU; Zhu, Y; Chen, WJ; Yang, CQ; Yuan, YB; Choo, YY; Wen, XM; Cheng, YB; Bach, U; Etheridge, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Rothmann, Mathias Uller; Zhu, Ye; Chen, Weijian; Yang, Chenquan; Yuan, Yongbo; Choo, Yen Yee; Wen, Xiaoming; Cheng, Yi-Bing; Bach, Udo; Etheridge, Joanne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The critical role of composition-dependent intragrain planar defects in the performance of MA1-xFAxPbI3 perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The role of intragrain planar defects in halide perovskite solar cell devices remains elusive. Now, Li et al. tune the composition of the perovskite layer to minimize the planar defect density and observe an improvement in the device performance. Perovskite solar cells show excellent power conversion efficiencies, long carrier diffusion lengths and low recombination rates. This encourages a view that intragrain defects are electronically benign with little impact on device performance. In this study we varied the methylammonium (MA)/formamidinium (FA) composition in MA(1)(-)(x)FA(x)PbI(3) (x = 0-1), and compared the structure and density of the intragrain planar defects with device performance, otherwise keeping the device nominally the same. We found that charge carrier lifetime, open-circuit voltage deficit and current density-voltage hysteresis correlate empirically with the density and structure of {111}(c) planar defects (x = 0.5-1) and {112}(t) twin boundaries (x = 0-0.1). The best performance parameters were found when essentially no intragrain planar defects were evident (x = 0.2). Similarly, reducing the density of {111}(c) planar defects through MASCN vapour treatment of FAPbI(3) (x approximate to 1) also improved performance. These observations suggest that intragrain defect control can provide an important route for improving perovskite solar cell performance, in addition to well-established parameters such as grain boundaries and interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 624, "End Page": 632, "Article Number": null, "DOI": "10.1038/s41560-021-00830-9", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00830-9", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661400300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Balachandran, PV; Kowalski, B; Sehirlioglu, A; Lookman, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Balachandran, Prasanna V.; Kowalski, Benjamin; Sehirlioglu, Alp; Lookman, Turab", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental search for high-temperature ferroelectric perovskites guided by two-step machine learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Experimental search for high-temperature ferroelectric perovskites is a challenging task due to the vast chemical space and lack of predictive guidelines. Here, we demonstrate a two-step machine learning approach to guide experiments in search of xBi[Me'Me-y ''((1-y))]O-3-(1 - x) PbTiO3-based perovskites with high ferroelectric Curie temperature. These involve classification learning to screen for compositions in the perovskite structures, and regression coupled to active learning to identify promising perovskites for synthesis and feedback. The problem is challenging because the search space is vast, spanning similar to 61,500 compositions and only 167 are experimentally studied. Furthermore, not every composition can be synthesized in the perovskite phase. In this work, we predict x, y, Me', and Me '' such that the resulting compositions have both high Curie temperature and form in the perovskite structure. Outcomes from both successful and failed experiments then iteratively refine the machine learning models via an active learning loop. Our approach finds six perovskites out of ten compositions synthesized, including three previously unexplored {Me'Me ''} pairs, with 0.2Bi (Fe0.12Co0.88)O-3-0.8PbTiO(3) showing the highest measured Curie temperature of 898 K among them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1668, "DOI": "10.1038/s41467-018-03821-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03821-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430922400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, J; Wang, XD; Jin, SB; Liu, ZQ; Zhu, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Jie; Wang, Xuandong; Jin, Shangbin; Liu, Zhao-Qing; Zhu, Mingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D metal-free heterostructure of covalent triazine framework/g-C3N4 for enhanced photocatalytic CO2 reduction with high selectivity", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven CO2 conversion to precious fossil fuels has been proved to become a potential way to decrease CO2 with producing renewable fuels, which mainly relies on photocatalysts with efficient charge separation. In this work, a metal free heterostructure of covalent triazine framework (CTF) and graphite carbon nitride (g-C3N4, abbreviated as CN) is applied in the CO2 photoreduction for the first time. Detailed characterization methods such as photoluminescence (PL) and time-resolved PL (TR-PL) decay are utilized to reveal the photo-induced carries separating process on g-C3N4/CTF (CN/CTF) heterostructure. The introduced CTF demonstrated a great boosting photocatalytic activity for CN, bringing about the transform rates of CO2 to CO reaching 151.1 mu mol/(g.h) with a 30 h stabilization time, while negligible CH4 was detected. The optimal CN/CTF heterostructure could more efficiently separate charges with a lower probability of recombination under visible light irradiation, which made the photoreduction efficiency of CO2 to CO be 25.5 and 2.5 times higher than that of CTF and CN, respectively. This investigation is expected to offer a new thought for fabricating high-efficiency photocatalyst without metal in solar-energy-driven CO2 reduction. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 43, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1306, "End Page": 1315, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63936-0", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63936-0", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787374900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YX; Zhao, TT; Han, HC; Yang, ZY; Liu, JR; Wen, XD; Wang, FL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yunxiang; Zhao, Tingting; Han, Hecheng; Yang, Zhengyi; Liu, Jiurong; Wen, Xiaodong; Wang, Fenglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ir-CoO Active Centers Supported on Porous Al2O3 nullosheets as Efficient and Durable Photo-Thermal Catalysts for CO2 Conversion", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photo-thermal catalytic CO2 hydrogenation is currently extensively studied as one of the most promising approaches for the conversion of CO2 into value-added chemicals under mild conditions; however, achieving desirable conversion efficiency and target product selectivity remains challenging. Herein, the fabrication of Ir-CoO/Al2O3 catalysts derived from Ir/CoAl LDH composites is reported for photo-thermal CO2 methanation, which consist of Ir-CoO ensembles as active centers that are evenly anchored on amorphous Al2O3 nullosheets. A CH4 production rate of 128.9 mmol g(cat)(-1) h(-1) is achieved at 250 degrees C under ambient pressure and visible light irradiation, outperforming most reported metal-based catalysts. Mechanism studies based on density functional theory (DFT) calculations and numerical simulations reveal that the CoO nulloparticles function as photocatalysts to donate electrons for Ir nulloparticles and meanwhile act as nulloheaters to effectively elevate the local temperature around Ir active sites, thus promoting the adsorption, activation, and conversion of reactant molecules. In situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) demonstrates that illumination also efficiently boosts the conversion of formate intermediates. The mechanism of dual functions of photothermal semiconductors as photocatalysts for electron donation and as nullo-heaters for local temperature enhancement provides new insight in the exploration for efficient photo-thermal catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2300122, "DOI": "10.1002/advs.202300122", "DOI Link": "http://dx.doi.org/10.1002/advs.202300122", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000949349100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoerder, GJ; Seibald, M; Baumann, D; Schröder, T; Peschke, S; Schmid, PC; Tyborski, T; Pust, P; Stoll, I; Bergler, M; Patzig, C; Reissaus, S; Krause, M; Berthold, L; Höche, T; Johrendt, D; Huppertz, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hoerder, Gregor J.; Seibald, Markus; Baumann, Dominik; Schroeder, Thorsten; Peschke, Simon; Schmid, Philipp C.; Tyborski, Tobias; Pust, Philipp; Stoll, Ion; Bergler, Michael; Patzig, Christian; Reissaus, Stephan; Krause, Michael; Berthold, Lutz; Hoeche, Thomas; Johrendt, Dirk; Huppertz, Hubert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sr[Li2Al2O2N2]:Eu2+-A high performance red phosphor to brighten the future", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Innovative materials for phosphor converted white light-emitting diodes are in high demand owing to the huge potential of the light-emitting diode technology to reduce energy consumption worldwide. As the primary blue diode is already highly optimized, the conversion phosphors are of crucial importance for any further improvements. We report on the discovery of the high performance red phosphor Sr[Li2Al2O2N2]:Eu2+ meeting all requirements for a phosphor's optical properties. It combines the optimal spectral position for a red phosphor, as defined in the 2016 Research & Development-plan of the United States government, with an exceptionally small spectral full width at half maximum and excellent thermal stability. A white mid-power phosphor-converted light-emitting diode prototype utilising Sr[Li2Al2O2N2]:Eu2+ shows an increase of 16% in luminous efficacy compared to currently available commercial high colour-rendering phosphor-converted light-emitting diodes, while retaining excellent high colour rendition. This phosphor enables a big leap in energy efficiency of white emitting phosphor-converted light-emitting-diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1824, "DOI": "10.1038/s41467-019-09632-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09632-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465200000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tockhorn, P; Sutter, J; Cruz, A; Wagner, P; Jäger, K; Yoo, D; Lang, F; Grischek, M; Li, BR; Li, JZ; Shargaieva, O; Unger, E; Al-Ashouri, A; Köhnen, E; Stolterfoht, M; Neher, D; Schlatmann, R; Rech, B; Stannowski, B; Albrecht, S; Becker, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tockhorn, Philipp; Sutter, Johannes; Cruz, Alexandros; Wagner, Philipp; Jaeger, Klaus; Yoo, Danbi; Lang, Felix; Grischek, Max; Li, Bor; Li, Jinzhao; Shargaieva, Oleksandra; Unger, Eva; Al-Ashouri, Amran; Koehnen, Eike; Stolterfoht, Martin; Neher, Dieter; Schlatmann, Rutger; Rech, Bernd; Stannowski, Bernd; Albrecht, Steve; Becker, Christiane", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-optical designs for high-efficiency monolithic perovskite-silicon tandem solar cells", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing gentle sinusoidal nullotextures enables the realization of high-efficiency perovskite-silicon solar cells Perovskite-silicon tandem solar cells offer the possibility of overcoming the power conversion efficiency limit of conventional silicon solar cells. Various textured tandem devices have been presented aiming at improved optical performance, but optimizing film growth on surface-textured wafers remains challenging. Here we present perovskite-silicon tandem solar cells with periodic nullotextures that offer various advantages without compromising the material quality of solution-processed perovskite layers. We show a reduction in reflection losses in comparison to planar tandems, with the new devices being less sensitive to deviations from optimum layer thicknesses. The nullotextures also enable a greatly increased fabrication yield from 50% to 95%. Moreover, the open-circuit voltage is improved by 15 mV due to the enhanced optoelectronic properties of the perovskite top cell. Our optically advanced rear reflector with a dielectric buffer layer results in reduced parasitic absorption at near-infrared wavelengths. As a result, we demonstrate a certified power conversion efficiency of 29.80%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 17, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1214, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-022-01228-8", "DOI Link": "http://dx.doi.org/10.1038/s41565-022-01228-8", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000871281000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, GH; Yang, HY; Jiang, Y; Sun, ZQ; Li, XP; Yang, JP; Wang, HF; Zou, RJ; Jiang, W; Qiu, PP; Luo, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Guihua; Yang, Haoyu; Jiang, Ying; Sun, Ziqi; Li, Xiaopeng; Yang, Jianping; Wang, Haifeng; Zou, Rujia; Jiang, Wan; Qiu, Pengpeng; Luo, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating the Electronic Structure of FeCo nulloparticles in N-Doped Mesoporous Carbon for Efficient Oxygen Reduction Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly efficient and stable oxygen reduction electrocatalysts and revealing their underlying catalytic mechanism are crucial in expanding the applications of metal-air batteries. Herein, an excellent FeCo alloy nulloparticles (NPs)-decorated N-doped mesoporous carbon electrocatalyst (FeCo/NC) for oxygen reduction reaction, prepared through the pyrolysis of a dual metal containing metal-organic framework composite scaffold is reported. Benefiting from the highly exposed bimetal active sites and the carefully designed structure, the Fe0.25Co0.75/NC-800 catalyst exhibits a promising electrocatalytic activity and a superior durability, better than those of the state-of-the-art catalysts. Suggested by both the X-ray absorption fine structures and the density functional theoretical calculation, the outstanding catalytic performance is originated from the synergistic effects of the bimetallic loading in NC catalysts, where the electronic modulation of the Co active sites from the nearby Fe species leads to an optimized binding strength for reaction intermediates. This work demonstrates a class of highly active nonprecious metals electrocatalysts and provides valuable insights into investigating the structure-performance relationship of transition metal-based alloy catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200394, "DOI": "10.1002/advs.202200394", "DOI Link": "http://dx.doi.org/10.1002/advs.202200394", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772280100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, YQ; Rahn, CD; Archer, LA; You, FQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Yanqiu; Rahn, Christopher D.; Archer, Lynden A.; You, Fengqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Second life and recycling: Energy and environmental sustainability perspectives for high-performance lithium-ion batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Second life and recycling of retired automotive lithium-ion batteries (LIBs) have drawn growing attention, as large volumes of LIBs will retire in the coming decade. Here, we illustrate how battery chemistry, use, and recycling can influence the energy and environmental sustainability of LIBs. We find that LIBs with higher specific energy show better life cycle environmental performances, but their environmental benefits from second life application are less pronounced. Direct cathode recycling is found to be the most effective in reducing life cycle environmental impacts, while hydrometallurgical recycling provides limited sustainability benefits for high-performance LIBs. Battery design with less aluminum and alternative anode materials, such as silicon-based anode, could enable more sustainable LIB recycling. Compared to directly recycling LIBs after their electric vehicle use, carbon footprint and energy use of LIBs recycled after their second life can be reduced by 8 to 17% and 2 to 6%, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 7, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabi7633", "DOI": "10.1126/sciadv.abi7633", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abi7633", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000715554500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dyachenko, PN; Molesky, S; Petrov, AY; Störmer, M; Krekeler, T; Lang, S; Ritter, M; Jacob, Z; Eich, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dyachenko, P. N.; Molesky, S.; Petrov, A. Yu; Stoermer, M.; Krekeler, T.; Lang, S.; Ritter, M.; Jacob, Z.; Eich, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling thermal emission with refractory epsilon-near-zero metamaterials via topological transitions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control of thermal radiation at high temperatures is vital for waste heat recovery and for high-efficiency thermophotovoltaic (TPV) conversion. Previously, structural resonullces utilizing gratings, thin film resonullces, metasurfaces and photonic crystals were used to spectrally control thermal emission, often requiring lithographic structuring of the surface and causing significant angle dependence. In contrast, here, we demonstrate a refractory W-HfO2 metamaterial, which controls thermal emission through an engineered dielectric response function. The epsilon-near-zero frequency of a metamaterial and the connected optical topological transition (OTT) are adjusted to selectively enhance and suppress the thermal emission in the near-infrared spectrum, crucial for improved TPV efficiency. The near-omnidirectional and spectrally selective emitter is obtained as the emission changes due to material properties and not due to resonullces or interference effects, marking a paradigm shift in thermal engineering approaches. We experimentally demonstrate the OTT in a thermally stable metamaterial at high temperatures of 1,000 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11809, "DOI": "10.1038/ncomms11809", "DOI Link": "http://dx.doi.org/10.1038/ncomms11809", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377385000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morad, V; Shynkarenko, Y; Yakunin, S; Brumberg, A; Schaller, RD; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morad, Viktoriia; Shynkarenko, Yevhen; Yakunin, Sergii; Brumberg, Alexandra; Schaller, Richard D.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Disphenoidal Zero-Dimensional Lead, Tin, and Germanium Halides: Highly Emissive Singlet and Triplet Self-Trapped Excitons and X-ray Scintillation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-dimensional metal halides have been researched as optoelectronic materials for the past two decades. Zero-dimensional halides of ns(2) elements (Sn, Pb, Sb) have recently gained attention as highly efficient broadband light emitters. These compounds comprise discrete metal halide centers, isolated by bulky organic cations. Herein, we report isostructural halide complexes of Ge(II), Sn(II), and Pb(II) with a 1-butyl-1-methyl-piperidinium cation (Bmpip), featuring unusual disphenoidal coordination with a highly stereoactive lone pair. Spectrally broad, bright emission from highly localized excitons, with quantum efficiencies of up to 75%, is observed in blue to red spectral regions for bromides (for Pb, Sn, and Ge, respectively) and extends into the near-infrared for Bmpip(2)SnI(4) (peak at 730 nm). In the case of Sn(II) and Ge(II), both singlet and triplet excitonic emission bands have been observed. Furthermore, Bmpip(2)SnBr(4) and Bmpip(2)PbBr(4) exhibit X-ray-excited luminescence (radioluminescence) with brightness being commensurate with that of a commercial inorganic X-ray scintillator (NaI:Tl).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 434, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2019, "Volume": 141, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9764, "End Page": 9768, "Article Number": null, "DOI": "10.1021/jacs.9b02365", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b02365", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473251500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ergoktas, MS; Bakan, G; Kovalska, E; Le Fevre, LW; Fields, RP; Steiner, P; Yu, XX; Salihoglu, O; Balci, S; Fal'ko, VI; Novoselov, KS; Dryfe, RAW; Kocabas, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ergoktas, M. Said; Bakan, Gokhan; Kovalska, Evgeniya; Le Fevre, Lewis W.; Fields, Richard P.; Steiner, Pietro; Yu, Xiaoxiao; Salihoglu, Omer; Balci, Sinull; Fal'ko, Vladimir I.; Novoselov, Kostya S.; Dryfe, Robert A. W.; Kocabas, Coskun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multispectral graphene-based electro-optical surfaces with reversible tunability from visible to microwave wavelengths", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical materials with colour changing abilities have been explored for use in display devices(1), smart windows(2,3) or in the modulation of visual appearance(4-6). The efficiency of these materials, however, has strong wavelength dependence, which limits their functionality to a specific spectral range. Here, we report graphene-based electro-optical devices with unprecedented optical tunability covering the entire electromagnetic spectrum from the visible to microwave. We achieve this non-volatile and reversible tunability by electro-intercalation of lithium into graphene layers in an optically accessible device structure. The unique colour changing capability, together with area-selective intercalation, inspires the fabrication of new multispectral devices, including display devices and electro-optical camouflage coating. We anticipate that these results provide realistic approaches for programmable smart optical surfaces with a potential utility in many scientific and engineering fields such as active plasmonics and adaptive thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 15, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 493, "End Page": 498, "Article Number": null, "DOI": "10.1038/s41566-021-00791-1", "DOI Link": "http://dx.doi.org/10.1038/s41566-021-00791-1", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636924000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Almroth, BMC; Åström, L; Roslund, S; Petersson, H; Johansson, M; Persson, NK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Almroth, Bethanie M. Carney; Astrom, Linn; Roslund, Sofia; Petersson, Hanna; Johansson, Mats; Persson, Nils-Krister", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying shedding of synthetic fibers from textiles; a source of microplastics released into the environment", "Source Title": "ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastics in the environment are a subject of intense research as they pose a potential threat to marine organisms. Plastic fibers from textiles have been indicated as a major source of this type of contaminullt, entering the oceans via wastewater and diverse non-point sources. Their presence is also documented in terrestrial samples. In this study, the amount of microfibers shedding from synthetic textiles was measured for three materials (acrylic, nylon, polyester), knit using different gauges and techniques. All textiles were found to shed, but polyester fleece fabrics shed the greatest amounts, averaging 7360 fibers/m(-2)/L-1 in one wash, compared with polyester fabrics which shed 87 fibers/m(-2)/L-1. We found that loose textile constructions shed more, as did worn fabrics, and high twist yarns are to be preferred for shed reduction. Since fiber from clothing is a potentially important source of microplastics, we suggest that smarter textile construction, prewashing and vacuum exhaustion at production sites, and use of more efficient filters in household washing machines could help mitigate this problem.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 25, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1191, "End Page": 1199, "Article Number": null, "DOI": "10.1007/s11356-017-0528-7", "DOI Link": "http://dx.doi.org/10.1007/s11356-017-0528-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419944100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, HD; Li, HP; Lan, CY; Li, C; Zhang, XX; Zhang, SJ; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Handing; Li, Heping; Lan, Changyong; Li, Chun; Zhang, Xiaoxia; Zhang, Shangjian; Liu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast erbium-doped fiber laser mode-locked by a CVD-grown molybdenum disulfide (MoS2) saturable absorber", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate an erbium-doped fiber laser passively mode-locked by a multilayer molybdenum disulfide (MoS2) saturable absorber (SA). The multilayer MoS2 is prepared by the chemical vapor deposition (CVD) method and transferred onto the end-face of a fiber connector. Taking advantage of the excellent saturable absorption of the fabricated MoS2-based SA, stable mode locking is obtained at a pump threshold of 31 mW. Resultant output soliton pulses have central wavelength, spectral width, pulse duration, and repetition rate of 1568.9 nm, 2.6 nm, 1.28 ps, and 8.288 MHz, respectively. The experimental results show that multilayer MoS2 is a promising material for ultrafast laser systems. (C)2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2014, "Volume": 22, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17341, "End Page": 17348, "Article Number": null, "DOI": "10.1364/OE.22.017341", "DOI Link": "http://dx.doi.org/10.1364/OE.22.017341", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340674700064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wright, AJ; Wang, QY; Ko, ST; Chung, KM; Chen, RK; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wright, Andrew J.; Wang, Qingyang; Ko, Shu-Ting; Chung, Ka Man; Chen, Renkun; Luo, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size disorder as a descriptor for predicting reduced thermal conductivity in medium- and high-entropy pyrochlore oxides", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy ceramics generally exhibit reduced thermal conductivity, but little is known about what controls this suppression and which descriptor can predict it. Herein, 22 single-phase pyrochlores were examined. Up to 35% reductions in thermal conductivity were achieved in medium- and high-entropy compositions with retained moduli, thereby attaining insulative yet stiff properties for thermal barrier coating applications. Notably, the measured thermal conductivity correlates well with a modified size disorder parameter delta(Size)*, thereby suggesting the importance of severe lattice distortion. Thus, this delta(Size)* is suggested as a useful descriptor for designing thermally-insulative compositionally-complex ceramics, where medium-entropy ceramics can outperform their high-entropy counterparts. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 181, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": 81, "Article Number": null, "DOI": "10.1016/j.scriptamat.2020.02.011", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2020.02.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527323100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, MR; Horgen, FD; Orski, SV; Rodriguez, CV; Beers, KL; Balazs, GH; Jones, TT; Work, TM; Brignac, KC; Royer, SJ; Hyrenbach, KD; Jensen, BA; Lynch, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Melissa R.; Horgen, F. David; Orski, Sara V.; Rodriguez, Viviana C.; Beers, Kathryn L.; Balazs, George H.; Jones, T. Todd; Work, Thierry M.; Brignac, Kayla C.; Royer, Sarah-Jeanne; Hyrenbach, K. David; Jensen, Brenda A.; Lynch, Jennifer M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms", "Source Title": "MARINE POLLUTION BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer identification of plastic marine debris can help identify its sources, degradation, and fate. We optimized and validated a fast, simple, and accessible technique, attenuated total reflectance Fourier transform infrared spectroscopy (ATR FT-IR), to identify polymers contained in plastic ingested by sea turtles. Spectra of consumer good items with known resin identification codes #1-6 and several #7 plastics were compared to standard and raw manufactured polymers. High temperature size exclusion chromatography measurements confirmed ATR Fr-IR could differentiate these polymers. High-density (HDPE) and low-density polyethylene (LDPE) discrimination is challenging but a clear step-by-step guide is provided that identified 78% of ingested PE samples. The optimal cleaning methods consisted of wiping ingested pieces with water or cutting. Of 828 ingested plastics pieces from 50 Pacific sea turtles, 96% were identified by ATR FT-IR as HDPE, LDPE, unknown PE, polypropylene (PP), PE and PP mixtures, polystyrene, polyvinyl chloride, and nylon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 937, "Times Cited, All Databases": 996, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 127, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 704, "End Page": 716, "Article Number": null, "DOI": "10.1016/j.marpolbul.2017.12.061", "DOI Link": "http://dx.doi.org/10.1016/j.marpolbul.2017.12.061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427332900078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, N; Chen, Z; Zang, KT; Xu, J; Zhong, J; Luo, J; Xu, X; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Na; Chen, Zheng; Zang, Ketao; Xu, Jie; Zhong, Jun; Luo, Jun; Xu, Xin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping strain induced bi-Ti3+ pairs for efficient N2 activation and electrocatalytic fixation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical N-2 fixation to produce ammonia is attractive but significantly challenging with low yield and poor selectivity. Herein, we first used density function theory calculations to reveal adjacent bi-Ti3+ pairs formed on anatase TiO2 as the most active electrocatalytic centers for efficient N-2 lying-down chemisorption and activation. Then, by doping of anatase TiO2 with Zr4+ that has similar d-electron configuration and oxide structure but relatively larger ionic size, the adjacent bi-Ti3+ sites were induced and enriched via a strained effect, which in turn enhanced the formation of oxygen vacancies. The Zr4+-doped anatase TiO2 exhibited excellent electrocatalytic N-2 fixation performances, with an ammonia production rate (8.90 mu g.h(-1).cm(-2)) and a Faradaic efficiency of 17.3% at -0.45 V versus reversible hydrogen electrode under ambient aqueous conditions. Moreover, our work suggests a viewpoint to understand and apply the same-valance dopants in heterogeneous catalysis, which is generally useful but still poorly understood.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2877, "DOI": "10.1038/s41467-019-10888-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10888-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473132200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, YH; Li, Q; Lu, GY; Ryu, HS; Li, Y; Jin, H; Chen, ZH; Tang, Z; Lu, GH; Hao, XT; Woo, HY; Zhang, CF; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Yunhao; Li, Qian; Lu, Guanyu; Ryu, Hwa Sook; Li, Yun; Jin, Hui; Chen, Zhihao; Tang, Zheng; Lu, Guanghao; Hao, Xiaotao; Woo, Han Young; Zhang, Chunfeng; Sun, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertically optimized phase separation with improved exciton diffusion enables efficient organic solar cells with thick active layers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exciton diffusion length and graded vertical phase separation of the active layer play a critical role in the realization of high-performance thick-film organic solar cells (OSCs). Here, authors demonstrated OSCs with an efficiency of 17.31%, with an active layer thickness of around 300 nm. The development of organic solar cells (OSCs) with thick active layers is of crucial importance for the roll-to-roll printing of large-area solar panels. Unfortunately, increasing the active layer thickness usually results in a significant reduction in efficiency. Herein, we fabricated efficient thick-film OSCs with an active layer consisting of one polymer donor and two non-fullerene acceptors. The two acceptors were found to possess enlarged exciton diffusion length in the mixed phase, which is beneficial to exciton generation and dissociation. Additionally, layer by layer approach was employed to optimize the vertical phase separation. Benefiting from the synergetic effects of enlarged exciton diffusion length and graded vertical phase separation, an efficiency of 17.31% (certified value of 16.9%) is obtained for the 300 nm-thick OSC, with a short-circuit current density of 28.36 mA cm(-2), and a high fill factor of 73.0%. Moreover, the device with an active layer thickness of 500 nm also shows an efficiency of 15.21%. This work provides valuable insights into the fabrication of OSCs with thick active layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2369, "DOI": "10.1038/s41467-022-29803-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29803-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789924700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WJ; Chuu, CP; Huang, JK; Chen, CH; Tsai, ML; Chang, YH; Liang, CT; Chen, YZ; Chueh, YL; He, JH; Chou, MY; Li, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenjing; Chuu, Chih-Piao; Huang, Jing-Kai; Chen, Chang-Hsiao; Tsai, Meng-Lin; Chang, Yung-Huang; Liang, Chi-Te; Chen, Yu-Ze; Chueh, Yu-Lun; He, Jr-Hau; Chou, Mei-Yin; Li, Lain-Jong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-Gain Photodetectors Based on Atomically Thin Graphene-MoS2 Heterostructures", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to its high carrier mobility, broadband absorption, and fast response time, the semi-metallic graphene is attractive for optoelectronics. Another two-dimensional semiconducting material molybdenum disulfide (MoS2) is also known as light-sensitive. Here we show that a large-area and continuous MoS2 monolayer is achievable using a CVD method and graphene is transferable onto MoS2. We demonstrate that a photodetector based on the graphene/MoS2 heterostructure is able to provide a high photogain greater than 108. Our experiments show that the electron-hole pairs are produced in the MoS2 layer after light absorption and subsequently separated across the layers. Contradictory to the expectation based on the conventional built-in electric field model for metal-semiconductor contacts, photoelectrons are injected into the graphene layer rather than trapped in MoS2 due to the presence of a perpendicular effective electric field caused by the combination of the built-in electric field, the applied electrostatic field, and charged impurities or adsorbates, resulting in a tuneable photoresponsivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 610, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3826, "DOI": "10.1038/srep03826", "DOI Link": "http://dx.doi.org/10.1038/srep03826", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330045000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, YY; Chen, CY; Mao, ZM; Bachman, H; Becker, R; Rufo, J; Wang, ZY; Zhang, PR; Mai, J; Yang, SJ; Zhang, JX; Zhao, SG; Ouyang, YS; Wong, DTW; Sadovsky, Y; Huang, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Yuyang; Chen, Chuyi; Mao, Zhangming; Bachman, Hunter; Becker, Ryan; Rufo, Joseph; Wang, Zeyu; Zhang, Peiran; Mai, John; Yang, Shujie; Zhang, Jinxin; Zhao, Shuaiguo; Ouyang, Yingshi; Wong, David T. W.; Sadovsky, Yoel; Huang, Tony Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acoustofluidic centrifuge for nulloparticle enrichment and separation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Liquid droplets have been studied for decades and have recently experienced renewed attention as a simplified model for numerous fascinating physical phenomena occurring on size scales from the cell nucleus to stellar black holes. Here, we present an acoustofluidic centrifugation technique that leverages an entanglement of acoustic wave actuation and the spin of a fluidic droplet to enable nulloparticle enrichment and separation. By combining acoustic streaming and droplet spinning, rapid (<1 min) nulloparticle concentration and size-based separation are achieved with a resolution sufficient to identify and isolate exosome subpopulations. The underlying physical mechanisms have been characterized both numerically and experimentally, and the ability to process biological samples (including DNA segments and exosome subpopulations) has been successfully demonstrated. Together, this acoustofluidic centrifuge overcomes existing limitations in the manipulation of nulloscale (<100 nm) bioparticles and can be valuable for various applications in the fields of biology, chemistry, engineering, material science, and medicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabc0467", "DOI": "10.1126/sciadv.abc0467", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abc0467", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605159200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XL; Lan, PC; Ma, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoliang; Lan, Pui Ching; Ma, Shengqian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for Enzyme Immobilization: Beyond Host Matrix Materials", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzyme immobilization in metal-organic frameworks (MOFs) as a promising strategy is attracting the interest of scientists from different disciplines with the expansion of MOFs' development. Different from other traditional host materials, their unique strengths of high surface areas, large yet adjustable pore sizes, functionalizable pore walls, and diverse architectures make MOFs an ideal platform to investigate hosted enzymes, which is critical to the industrial and commercial process. In addition to the protective function of MOFs, the extensive roles of MOFs in the enzyme immobilization are being well-explored by making full use of their remarkable properties like well-defined structure, high porosity, and tunable functionality. Such development shifts the focus from the exploration of immobilization strategies toward functionalization. Meanwhile, this would undoubtedly contribute to a better understanding of enzymes in regards to the structural transformation after being hosted in a confinement environment, particularly to the orientation and conformation change as well as the interplay between enzyme and matrix MOFs. In this Outlook, we target a comprehensive review of the role diversities of the host matrix MOF based on the current enzyme immobilization research, along with proposing an outlook toward the future development of this field, including the representatives of potential techniques and methodologies being capable of studying the hosted enzymes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2020, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1497, "End Page": 1506, "Article Number": null, "DOI": "10.1021/acscentsci.0c00687", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.0c00687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000575687100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akinwolemiwa, B; Peng, C; Chen, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akinwolemiwa, Bamidele; Peng, Chuang; Chen, George Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox Electrolytes in Supercapacitors", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most methods for improving supercapacitor performance are based on developments of electrode materials to optimally exploit their storage mechanisms, namely electrical double layer capacitance and pseudocapacitance. In such cases, the electrolyte is supposed to be electrochemically as inert as possible so that a wide potential window can be achieved. Interestingly, in recent years, there has been a growing interest in the investigation of supercapacitors with an electrolyte that can offer redox activity. Such redox electrolytes have been shown to offer increased charge storage capacity, and possibly other benefits. There are however some confusions, for example; on the nature of contributions of the redox electrolyte to the increased storage capacity in comparison with pseudocapacitance, or by expression of the overall increased charge storage capacity as capacitance. This report intends to provide a brief but critical review on the pros and cons of the application of such redox electrolytes in supercapacitors, and to advocate development of the relevant research into a new electrochemical energy storage device in parallel with, but not the same as that of supercapacitors. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 419, "Times Cited, All Databases": 437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 162, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A5054", "End Page": "A5059", "Article Number": null, "DOI": "10.1149/2.0111505jes", "DOI Link": "http://dx.doi.org/10.1149/2.0111505jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351976200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schütt, KT; Gastegger, M; Tkatchenko, A; Müller, KR; Maurer, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuett, K. T.; Gastegger, M.; Tkatchenko, A.; Mueller, K-R.; Maurer, R. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unifying machine learning and quantum chemistry with a deep neural network for molecular wavefunctions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning advances chemistry and materials science by enabling large-scale exploration of chemical space based on quantum chemical calculations. While these models supply fast and accurate predictions of atomistic chemical properties, they do not explicitly capture the electronic degrees of freedom of a molecule, which limits their applicability for reactive chemistry and chemical analysis. Here we present a deep learning framework for the prediction of the quantum mechanical wavefunction in a local basis of atomic orbitals from which all other ground-state properties can be derived. This approach retains full access to the electronic structure via the wavefunction at force-field-like efficiency and captures quantum mechanics in an analytically differentiable representation. On several examples, we demonstrate that this opens promising avenues to perform inverse design of molecular structures for targeting electronic property optimisation and a clear path towards increased synergy of machine learning and quantum chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5024, "DOI": "10.1038/s41467-019-12875-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12875-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496713500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vansteenkiste, A; Leliaert, J; Dvornik, M; Helsen, M; Garcia-Sanchez, F; Van Waeyenberge, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vansteenkiste, Arne; Leliaert, Jonathan; Dvornik, Mykola; Helsen, Mathias; Garcia-Sanchez, Felipe; Van Waeyenberge, Bartel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The design and verification of MuMax3", "Source Title": "AIP ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the design, verification and performance of MUMAX3, an open-source GPU-accelerated micromagnetic simulation program. This software solves the time-and space dependent magnetization evolution in nullo-to micro scale magnets using a finite-difference discretization. Its high performance and low memory requirements allow for large-scale simulations to be performed in limited time and on inexpensive hardware. We verified each part of the software by comparing results to analytical values where available and to micromagnetic standard problems. MUMAX3 also offers specific extensions like MFM image generation, moving simulation window, edge charge removal and material grains. (C) 2014 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution 3.0 Unported License.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2680, "Times Cited, All Databases": 2833, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107133, "DOI": "10.1063/1.4899186", "DOI Link": "http://dx.doi.org/10.1063/1.4899186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344588200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Beretta, S; Romano, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Beretta, S.; Romano, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A comparison of fatigue strength sensitivity to defects for materials manufactured by AM or traditional processes", "Source Title": "INTERNATIONAL JOURNAL OF FATIGUE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fatigue behavior of metallic materials fabricated via additive manufacturing processes is currently not well understood and it has been the subject of many experimental investigations in recent years. In this paper we carried out a literature review about the fatigue strength of additively manufactured AlSi10Mg and Ti6Al4V, especially in terms of sensitivity to defects and inhomogeneities. The analysis shows that fatigue properties and key variables (heat treatment, defect size) are very similar to the ones of parts obtained with traditional manufacturing processes. These results confirm that defect tolerant design concepts can be adopted also for AM components. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 448, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 94, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 178, "End Page": 191, "Article Number": null, "DOI": "10.1016/j.ijfatigue.2016.06.020", "DOI Link": "http://dx.doi.org/10.1016/j.ijfatigue.2016.06.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388783600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCluskey, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCluskey, Matthew D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Point defects in Ga2O3", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the field of high-power electronics, gallium oxide (Ga2O3) is attracting attention due to its wide bandgap and ability to be doped n-type. Point defects, including vacancies, impurities, and dopants, play important roles in optimizing device performance. This tutorial discusses the fundamental properties of point defects in monoclinic beta-Ga2O3 and the methods employed to study them. Oxygen vacancies are deep donors that do not cause n-type conductivity but may compensate acceptors. Gallium vacancies are deep acceptors that can be partially passivated by hydrogen. Substitutional magnesium is a promising acceptor that produces a semi-insulating material and also forms a complex with hydrogen. Calcium and iron also have deep acceptor levels. Iridium deep donors are introduced into crystals grown from a melt in an Ir crucible. Other defects are introduced by irradiation with energetic particles such as neutrons or protons. In addition to altering the electronic properties, defects give rise to UV/visible emission bands in photoluminescence and cathodoluminescence spectra. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2020, "Volume": 127, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101101, "DOI": "10.1063/1.5142195", "DOI Link": "http://dx.doi.org/10.1063/1.5142195", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521342400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wilhelm, S; Kaiser, M; Würth, C; Heiland, J; Carrillo-Carrion, C; Muhr, V; Wolfbeis, OS; Parak, WJ; Resch-Genger, U; Hirsch, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wilhelm, Stefan; Kaiser, Martin; Wuerth, Christian; Heiland, Josef; Carrillo-Carrion, Carolina; Muhr, Verena; Wolfbeis, Otto S.; Parak, Wolfgang J.; Resch-Genger, Ute; Hirsch, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water dispersible upconverting nulloparticles: effects of surface modification on their luminescence and colloidal stability", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a systematic study on the effect of surface ligands on the luminescence properties and colloidal stability of beta-NaYF4:Yb3+, Er3+ upconversion nulloparticles (UCNPs), comparing nine different surface coatings to render these UCNPs water-dispersible and bioconjugatable. A prerequisite for this study was a large-scale synthetic method that yields similar to 2 g per batch of monodisperse oleate-capped UCNPs providing identical core particles. These similar to 23 nm sized UCNPs display an upconversion quantum yield of similar to 0.35% when dispersed in cyclohexane and excited with a power density of 150 W cm(-2), underlining their high quality. A comparison of the colloidal stability and luminescence properties of these UCNPs, subsequently surface modified with ligand exchange or encapsulation protocols, revealed that the ratio of the green (545 nm) and red (658 nm) emission bands determined at a constant excitation power density clearly depends on the surface chemistry. Modifications relying on the deposition of additional (amphiphilic) layer coatings, where the initial oleate coating is retained, show reduced non-radiative quenching by water as compared to UCNPs that are rendered water-dispersible via ligand exchange. Moreover, we could demonstrate that the brightness of the upconversion luminescence of the UCNPs is strongly affected by the type of surface modification, i.e., ligand exchange or encapsulation, yet hardly by the chemical nature of the ligand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1403, "End Page": 1410, "Article Number": null, "DOI": "10.1039/c4nr05954a", "DOI Link": "http://dx.doi.org/10.1039/c4nr05954a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347374600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "English, CD; Shine, G; Dorgan, VE; Saraswat, KC; Pop, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "English, Chris D.; Shine, Gautam; Dorgan, Vincent E.; Saraswat, Krishna C.; Pop, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improved Contacts to MoS2 Transistors by Ultra-High Vacuum Metal Deposition", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scaling of transistors to sub-10 nm dimensions is strongly limited by their contact resistance (R-C). Here we present a systematic study of scaling MoS2 devices and contacts with varying electrode metals and controlled deposition conditions, over a wide range of temperatures (80 to 500 K), carrier densities (1012 to 1013 cm(-2)), and contact dimensions (20 to 500 nm). We uncover that Au deposited in ultra-high vacuum (similar to 10(-9) Torr) yields three times lower Rc than under normal conditions, reaching 740 Omega.mu m and specific contact resistivity 3 X 10(-7) Omega.cm(2), stable for over four months. Modeling reveals separate R-C contributions from the Schottky barrier and the series access resistance, providing key insights on how to further improve scaling of MoS2 contacts and transistor dimensions. The contact transfer length is similar to 35 nm at 300 K, which is verified experimentally using devices with 20 mn contacts and 70 nm contact pitch (CP), equivalent to the 14 nm technology node.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 525, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3824, "End Page": 3830, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b01309", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b01309", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377642700060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, YH; Park, H; Smit, B; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Yeonghun; Park, Hyunsoo; Smit, Berend; Kim, Jihan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A multi-modal pre-training transformer for universal transfer learning in metal-organic frameworks", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are a class of crystalline porous materials that exhibit a vast chemical space owing to their tunable molecular building blocks with diverse topologies. An unlimited number of MOFs can, in principle, be synthesized. Machine learning approaches can help to explore this vast chemical space by identifying optimal candidates with desired properties from structure-property relationships. Here we introduce MOFTransformer, a multi-modal Transformer encoder pre-trained with 1 million hypothetical MOFs. This multi-modal model utilizes integrated atom-based graph and energy-grid embeddings to capture both local and global features of MOFs, respectively. By fine-tuning the pre-trained model with small datasets ranging from 5,000 to 20,000 MOFs, our model achieves state-of-the-art results for predicting across various properties including gas adsorption, diffusion, electronic properties, and even text-mined data. Beyond its universal transfer learning capabilities, MOFTransformer generates chemical insights by analyzing feature importance through attention scores within the self-attention layers. As such, this model can serve as a platform for other MOF researchers that seek to develop new machine learning models for their work. Metal-organic frameworks are of high interest for a range of energy and environmental applications due to their stable gas storage properties. A new machine learning approach based on a pre-trained multi-modal transformer can be fine-tuned with small datasets to predict structure-property relationships and design new metal-organic frameworks for a range of specific tasks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 309, "End Page": 318, "Article Number": null, "DOI": "10.1038/s42256-023-00628-2", "DOI Link": "http://dx.doi.org/10.1038/s42256-023-00628-2", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948642600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SQ; Li, RH; Hu, N; Deng, T; Weng, ST; Wu, ZC; Lu, D; Zhang, HK; Zhang, JB; Wang, XF; Chen, LX; Fan, LW; Fan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuoqing; Li, Ruhong; Hu, null; Deng, Tao; Weng, Suting; Wu, Zunchun; Lu, Di; Zhang, Haikuo; Zhang, Junbo; Wang, Xuefeng; Chen, Lixin; Fan, Liwu; Fan, Xiulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tackling realistic Li+ flux for high-energy lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low conductivity of LiF disturbs Li+ diffusion across solid electrolyte interphase (SEI) and induces Li+ transfer-driven dendritic growth. Herein, the authors establish a mechanistic model to decipher how the SEI affects realistic Li plating in high-fluorine electrolytes. Electrolyte engineering advances Li metal batteries (LMBs) with high Coulombic efficiency (CE) by constructing LiF-rich solid electrolyte interphase (SEI). However, the low conductivity of LiF disturbs Li+ diffusion across SEI, thus inducing Li+ transfer-driven dendritic deposition. In this work, we establish a mechanistic model to decipher how the SEI affects Li plating in high-fluorine electrolytes. The presented theory depicts a linear correlation between the capacity loss and current density to identify the slope k (determined by Li+ mobility of SEI components) as an indicator for describing the homogeneity of Li+ flux across SEI, while the intercept dictates the maximum CE that electrolytes can achieve. This model inspires the design of an efficient electrolyte that generates dual-halide SEI to homogenize Li+ distribution and Li deposition. The model-driven protocol offers a promising energetic analysis to evaluate the compatibility of electrolytes to Li anode, thus guiding the design of promising electrolytes for LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5431, "DOI": "10.1038/s41467-022-33151-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33151-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854793700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akolpoglu, MB; Alapan, Y; Dogan, NO; Baltaci, SF; Yasa, O; Tural, GA; Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akolpoglu, Mukrime Birgul; Alapan, Yunus; Dogan, Nihal Olcay; Baltaci, Saadet Fatma; Yasa, Oncay; Tural, Gulsen Aybar; Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetically steerable bacterial microrobots moving in 3D biological matrices for stimuli-responsive cargo delivery", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial biohybrids, composed of self-propelling bacteria carrying micro/nulloscale materials, can deliver their payload to specific regions under magnetic control, enabling additional frontiers in minimally invasive medicine. However, current bacterial biohybrid designs lack high-throughput and facile construction with favorable cargoes, thus underperforming in terms of propulsion, payload efficiency, tissue penetration, and spatiotemporal operation. Here, we report magnetically controlled bacterial biohybrids for targeted localization and multistimuliresponsive drug release in three-dimensional (3D) biological matrices. Magnetic nulloparticles and nulloliposomes loaded with photothermal agents and chemotherapeutic molecules were integrated onto Escherichia coil with similar to 90% efficiency. Bacterial biohybrids, outperforming previously reported E. coli-based microrobots, retained their original motility and were able to navigate through biological matrices and colonize tumor spheroids under magnetic fields for on-demand release of the drug molecules by near-infrared stimulus. Our work thus provides a multifunctional microrobotic platform for guided locomotion in 3D biological networks and stimuli-responsive delivery of therapeutics for diverse medical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 8, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaho6163", "DOI": "10.1126/sciadv.abo6163", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abo6163", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826385700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, B; Fei, FC; Zhang, DQ; Zhang, B; Liu, WL; Zhang, S; Wang, PD; Wei, BY; Zhang, Y; Zuo, ZW; Guo, JW; Liu, QQ; Wang, ZL; Wu, XC; Zong, JY; Xie, XD; Chen, W; Sun, Z; Wang, SC; Zhang, Y; Zhang, MH; Wang, XF; Song, FQ; Zhang, HJ; Shen, DW; Wang, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Bo; Fei, Fucong; Zhang, Dongqin; Zhang, Bo; Liu, Wanling; Zhang, Shuai; Wang, Pengdong; Wei, Boyuan; Zhang, Yong; Zuo, Zewen; Guo, Jingwen; Liu, Qianqian; Wang, Zilu; Wu, Xuchuan; Zong, Junyu; Xie, Xuedong; Chen, Wang; Sun, Zhe; Wang, Shancai; Zhang, Yi; Zhang, Minhao; Wang, Xuefeng; Song, Fengqi; Zhang, Haijun; Shen, Dawei; Wang, Baigeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic magnetic topological insulator phases in the Sb doped MnBi2Te4 bulks and thin flakes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic topological insulators (MTIs) offer a combination of topologically nontrivial characteristics and magnetic order and show promise in terms of potentially interesting physical phenomena such as the quantum anomalous Hall (QAH) effect and topological axion insulating states. However, the understanding of their properties and potential applications have been limited due to a lack of suitable candidates for MTIs. Here, we grow two-dimensional single crystals of Mn(SbxBi(1-x))(2)Te-4 bulk and exfoliate them into thin flakes in order to search for intrinsic MTIs. We perform angle-resolved photoemission spectroscopy, low-temperature transport measurements, and first-principles calculations to investigate the band structure, transport properties, and magnetism of this family of materials, as well as the evolution of their topological properties. We find that there exists an optimized MTI zone in the Mn (SbxBi(1-x))(2)Te-4 phase diagram, which could possibly host a high-temperature QAH phase, offering a promising avenue for new device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4469, "DOI": "10.1038/s41467-019-12485-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12485-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488485300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, JT; Yang, F; Lu, JP; Ye, S; Guo, HW; Nie, HK; Zhang, JL; He, JL; Zhang, BT; Ni, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Junting; Yang, Fang; Lu, Junpeng; Ye, Shuai; Guo, Haowen; Nie, Hongkun; Zhang, Jialin; He, Jingliang; Zhang, Baitao; Ni, Zhenhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High output mode-locked laser empowered by defect regulation in 2D Bi2O2Se saturable absorber", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bi2O2Se holds potential for the realization of 2D optical modulators due to its broadband nonlinear response, air stability and carrier mobility. Here, the authors report the realization of defect-engineered Bi2O2Se nulloplates as saturable absorbers for femtosecond solid-state lasers, showing improved output power and pulse duration. Atomically thin Bi2O2Se has emerged as a novel two-dimensional (2D) material with an ultrabroadband nonlinear optical response, high carrier mobility and excellent air stability, showing great potential for the realization of optical modulators. Here, we demonstrate a femtosecond solid-state laser at 1.0 mu m with Bi2O2Se nulloplates as a saturable absorber (SA). Upon further defect regulation in 2D Bi2O2Se, the average power of the mode-locked laser is improved from 421 mW to 665 mW, while the pulse width is decreased from 587 fs to 266 fs. Moderate Ar+ plasma treatments are employed to precisely regulate the O and Se defect states in Bi2O2Se nulloplates. Nondegenerate pump-probe measurements show that defect engineering effectively accelerates the trapping rate and defect-assisted Auger recombination rate of photocarriers. The saturation intensity is improved from 3.6 +/- 0.2 to 12.8 +/- 0.6 MW cm(-2) after the optimized defect regulation. The enhanced saturable absorption and ultrafast carrier lifetime endow the high-performance mode-locked laser with both large output power and short pulse duration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3855, "DOI": "10.1038/s41467-022-31606-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31606-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821901200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, S; Wang, W; Li, H; Zhang, JY; Chen, RF; Wang, S; Zheng, C; Xing, GC; Song, CY; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Shen; Wang, Wu; Li, Hui; Zhang, Jingyu; Chen, Runfeng; Wang, Shuang; Zheng, Chao; Xing, Guichuan; Song, Chunyuan; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of highly efficient deep-blue organic afterglow through guest sensitization and matrices rigidification", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Blue/deep-blue emission is crucial for organic optoelectronics but remains a formidable challenge in organic afterglow due to the difficulties in populating and stabilizing the high-energy triplet excited states. Here, a facile strategy to realize the efficient deep-blue organic afterglow is proposed via host molecules to sensitize the triplet exciton population of guest and water implement to suppress the non-radiative decays by matrices rigidification. A series of highly luminescent deep-blue (405-428nm) organic afterglow materials with lifetimes up to 1.67s and quantum yields of 46.1% are developed. With these high-performance water-responsive materials, lifetime-encrypted rewritable paper has been constructed for water-jet printing of high-resolution anti-counterfeiting patterns that can retain for a long time (>1 month) and be erased by dimethyl sulfoxide vapor in 15min with high reversibility for many write/erase cycles. These results provide a foundation for the design of high-efficient blue/deep-blue organic afterglow and stimuli-responsive materials with remarkable applications. Though realizing organic materials with deep blue emission is attractive for next-generation display technologies, achieving this emission in afterglow molecules remains a challenge. Here, the authors report blue organic afterglow via a strategy involving guest sensitization and matrix rigidification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4802, "DOI": "10.1038/s41467-020-18572-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18572-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573745600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Emami, FS; Puddu, V; Berry, RJ; Varshney, V; Patwardhan, SV; Perry, CC; Heinz, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Emami, Fateme S.; Puddu, Valeria; Berry, Rajiv J.; Varshney, Vikas; Patwardhan, Siddharth V.; Perry, Carole C.; Heinz, Hendrik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Force Field and a Surface Model Database for Silica to Simulate Interfacial Properties in Atomic Resolution", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silica nullostructures find applications in drug delivery, catalysis, and composites, however, understanding of the surface chemistry, aqueous interfaces, and biomolecule recognition remain difficult using current imaging techniques and spectroscopy. A silica force field is introduced that resolves numerous shortcomings of prior silica force fields over the last 30 years and reduces uncertainties in computed interfacial properties relative to experiment from several 100% to less than 5%. In addition, a silica surface model database is introduced for the full range of variable surface chemistry and pH (Q(2), Q(3), Q(4) environments with adjustable degree of ionization) that have shown to determine selective molecular recognition. The force field enables accurate computational predictions of aqueous interfacial properties of all types of silica, which is substantiated by extensive comparisons to experimental measurements. The parameters are integrated into multiple force fields for broad applicability to biomolecules, polymers, and inorganic materials (AMBER, CHARMM, COMPASS, CVFF, PCFF, INTERFACE force fields). We also explain mechanistic details of molecular adsorption of water vapor, as well as significant variations in the amount and dissociation depth of superficial cations at silica-water interfaces that correlate with zeta-potential measurements and create a wide range of aqueous environments for adsorption and self-assembly of complex molecules. The systematic analysis of binding conformations and adsorption free energies of distinct peptides to silica surfaces will be reported separately in a companion paper. The models aid to understand and design silica nullomaterials in 3D atomic resolution and are extendable to chemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 462, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2014, "Volume": 26, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2647, "End Page": 2658, "Article Number": null, "DOI": "10.1021/cm500365c", "DOI Link": "http://dx.doi.org/10.1021/cm500365c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334991300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, RJ; Kang, LQ; Zhao, TQ; Feng, JR; Celorrio, V; Zhang, GH; Cibin, G; Kucernak, A; Brett, DJL; Corà, F; Parkin, IP; He, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Runjia; Kang, Liqun; Zhao, Tianqi; Feng, Jianrui; Celorrio, Veronica; Zhang, Guohui; Cibin, Giannulltonio; Kucernak, Anthony; Brett, Dan J. L.; Cora, Furio; Parkin, Ivan P.; He, Guanjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification and manipulation of dynamic active site deficiency-induced competing reactions in electrocatalytic oxidation processes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic organic compound oxidation reactions (OCORs) have been intensively studied for energy and environmentally benign applications. However, relatively little effort has been devoted to developing a fundamental understanding of OCORs, including the detailed competition with side reactions and activity limitations, thus inhibiting the rational design of high-performance electrocatalysts. Herein, by taking the NiWO4-catalysed urea oxidation reaction (UOR) in aqueous media as an example, the competition between the OCOR and the oxygen evolution reaction (OER) within a wide potential range is examined. It is shown that the root of the competition can be ascribed to insufficient surface concentration of dynamic Ni3+, an active site shared by both the UOR and OER. A similar phenomenon is observed in other OCOR electrocatalysts and systems. To address the issue, a controllable reconstruction of pseudo-crystalline bimetal oxides design strategy is proposed to maximise the dynamic Ni3+ population and manipulate the competition between the UOR and the OER. The optimised electrocatalyst delivers best-in-class performance and an similar to 10-fold increase in current density at 1.6 V versus the reversible hydrogen electrode for alkaline urea electrolysis compared to those of the pristine materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2386, "End Page": 2396, "Article Number": null, "DOI": "10.1039/d1ee03522c", "DOI Link": "http://dx.doi.org/10.1039/d1ee03522c", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777694800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teh, SH; Wiedmann, T; Castel, A; de Burgh, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teh, Soo Huey; Wiedmann, Thomas; Castel, Arnaud; de Burgh, James", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid life cycle assessment of greenhouse gas emissions from cement, concrete and geopolymer concrete in Australia", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concrete is the second most used material after water and the production of cement is responsible for 5-8% of global carbon dioxide emissions. The development of low-carbon concretes is pursued worldwide to help the construction industry make its contribution to decarbonising the built environment and achieving carbon reduction targets agreed under the Paris Climate Agreement. However, there is uncertainty around the actual amount of greenhouse gas emissions that can be avoided by employing alternative types of concrete. This study quantifies the carbon footprint intensities of Australian cement and concrete production, including ordinary Portland cement, standard ordinary Portland cement concrete, blended cement-based concrete and geopolymer concrete production. For the first time, an input-output based hybrid life-cycle assessment method is used for these products. The main goal of this paper is therefore to make a methodological comparison between process-based and hybrid life cycle assessment using the Australian cement and concrete production as a case study. A comparison with published results from process-based life-cycle inventories as well as a decomposition of results into product categories is provided. The hybrid life cycle assessment resulted in higher greenhouse gas emissions for ordinary Portland cement and all types of concrete due to the methodology incorporating an economy-wide system boundary, which includes the emissions from upstream processes. For geopolymer concrete in particular, the results were also dependent on the method applied for allocating greenhouse gas emissions from fly ash and slag. The findings from this study are likely to inform the development of strategies and policies aimed at greenhouse gas reduction in the cement and concrete industries. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2017, "Volume": 152, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 312, "End Page": 320, "Article Number": null, "DOI": "10.1016/j.jclepro.2017.03.122", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2017.03.122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401379700028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, YH; Cho, H; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Young-Hoon; Cho, Himchan; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal halide perovskite light emitters", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Twenty years after layer-type metal halide perovskites were successfully developed, 3D metal halide perovskites (shortly, perovskites) were recently rediscovered and are attracting multidisciplinary interest from physicists, chemists, and material engineers. Perovskites have a crystal structure composed of five atoms per unit cell (ABX(3)) with cation A positioned at a corner, metal cation B at the center, and halide anion X at the center of six planes and unique optoelectronic properties determined by the crystal structure. Because of very narrow spectra (full width at half-maximum <= 20 nm), which are insensitive to the crystallite/grain/particle dimension and wide wavelength range (400 nm <= lambda <= 780 nm), perovskites are expected to be promising high-color purity light emitters that overcome inherent problems of conventional organic and inorganic quantum dot emitters. Within the last 2 y, perovskites have already demonstrated their great potential in light-emitting diodes by showing high electroluminescence efficiency comparable to those of organic and quantum dot light-emitting diodes. This article reviews the progress of perovskite emitters in two directions of bulk perovskite polycrystalline films and perovskite nulloparticles, describes current challenges, and suggests future research directions for researchers to encourage them to collaborate and to make a synergetic effect in this rapidly emerging multidisciplinary field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2016, "Volume": 113, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11694, "End Page": 11702, "Article Number": null, "DOI": "10.1073/pnas.1607471113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1607471113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385610400043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Campione, S; Liu, S; Basilio, LI; Warne, LK; Langston, WL; Luk, TS; Wendt, JR; Reno, JL; Keeler, GA; Brener, I; Sinclair, MB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Campione, Salvatore; Liu, Sheng; Basilio, Lorena I.; Warne, Larry K.; Langston, William L.; Luk, Ting S.; Wendt, Joel R.; Reno, John L.; Keeler, Gordon A.; Brener, Igal; Sinclair, Michael B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broken Symmetry Dielectric Resonators for High Quality Factor Fano Metasurfaces", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a new approach to dielectric metasurface design that relies on a single resonator per unit cell and produces robust, high quality factor Fano resonullces. Our approach utilizes symmetry breaking of highly symmetric resonator geometries, such as cubes, to induce couplings between the otherwise orthogonal resonator modes. In particular, we design perturbations that couple bright dipole modes to dark dipole modes whose radiative decay is suppressed by local field effects in the array. Our approach is widely scalable from the near-infrared to radio frequencies. We first unravel the Fano resonullce behavior through numerical simulations of a germanium resonator-based metasurface that achieves a quality factor of similar to 1300 at similar to 10.8 pm. Then, we present two experimental demonstrations operating in the infrared (similar to 1 mu m): a silicon-based implementation that achieves a quality factor of similar to 350; and a gallium arsenide-based structure that achieves a quality factor of similar to 600, the highest near-infrared quality factor experimentally demonstrated to date with this kind of metasurface. Importantly, large electromagnetic field enhancements appear within the resonators at the Fano resonullt frequencies. We envision that combining high quality factor, high field enhancement resonullces with nonlinear and active/gain materials such as gallium arsenide will lead to new classes of active optical devices. near-", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2362, "End Page": 2367, "Article Number": null, "DOI": "10.1021/acsphotonics.6b00556", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.6b00556", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390731700024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, AJ; Han, K; Huang, K; Ye, C; Wen, W; Zhu, RX; Zhu, R; Xu, J; Yu, T; Gao, P; Xiong, QH; Wang, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Allen Jian; Han, Kun; Huang, Ke; Ye, Chen; Wen, Wen; Zhu, Ruixue; Zhu, Rui; Xu, Jun; Yu, Ting; Gao, Peng; Xiong, Qihua; Renshaw Wang, X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals integration of high-κ perovskite oxides and two-dimensional semiconductors", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance n-type molybdenum disulfide and p-type tungsten diselenide field-effect transistors can be fabricated using single-crystal strontium titanate dielectrics that are transferred onto two-dimensional semiconductors with the help of van der Waals forces. Two-dimensional semiconductors can be used to build next-generation electronic devices with ultrascaled channel lengths. However, semiconductors need to be integrated with high-quality dielectrics-which are challenging to deposit. Here we show that single-crystal strontium titanate-a high-kappa perovskite oxide-can be integrated with two-dimensional semiconductors using van der Waals forces. Strontium titanate thin films are grown on a sacrificial layer, lifted off and then transferred onto molybdenum disulfide and tungsten diselenide to make n-type and p-type transistors, respectively. The molybdenum disulfide transistors exhibit an on/off current ratio of 10(8) at a supply voltage of 1 V and a minimum subthreshold swing of 66 mV dec(-1). We also show that the devices can be used to create low-power complementary metal-oxide-semiconductor inverter circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 233, "End Page": 240, "Article Number": null, "DOI": "10.1038/s41928-022-00753-7", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00753-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788302100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JJ; Wang, LX; Jiang, CH; Cheng, B; Chen, T; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jianjun; Wang, Linxi; Jiang, Chenhui; Cheng, Bei; Chen, Tao; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CsPbBr3 nullocrystal Induced Bilateral Interface Modification for Efficient Planar Perovskite Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic halide perovskite solar cells (PSCs) have drawn tremendous attention owing to their remarkable photovoltaic performance and simple preparation process. However, conventional wet-chemical synthesis methods inevitably create defects both in the bulk and at the interfaces of perovskites, leading to recombination of charge carriers and reduced stability. Herein, a bilateral interface modification to perovskites by doping room-temperature synthesized CsPbBr3 nullocrystals (CN) is reported. The ultrafast transient absorption measurement reveals that CN effectively suppresses the defect at the SnO2/perovskite interface and boosts the interfacial electron transport. Meanwhile, the in situ Kelvin probe force microscopy and contact potential difference characterizations verify that the CN within the upper part of the perovskites enhances the built-in electric field, facilitating oriented migration of the carriers within the perovskite. Combining the superiorities of CN modifiers on both sides, the bilaterally modified CH3NH3PbI3-based planar PSCs exhibit optimal power conversion efficiency exceeding 20% and improved device stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 8, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2102648, "DOI": "10.1002/advs.202102648", "DOI Link": "http://dx.doi.org/10.1002/advs.202102648", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000695164700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aktürk, OÜ; Özçelik, VO; Ciraci, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akturk, O. Uzengi; Ozcelik, V. Ongun; Ciraci, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-layer crystalline phases of antimony: Antimonenes", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pseudolayered character of 3D bulk crystals of antimony has led us to predict its 2D single-layer crystalline phase named antimonene in a buckled honeycomb structure like silicene. Sb atoms also form an asymmetric washboard structure like black phospherene. Based on an extensive analysis comprising ab initio phonon and finite-temperature molecular dynamics calculations, we show that these two single-layer phases are robust and can remain stable at high temperatures. They are nonmagnetic semiconductors with band gaps ranging from 0.3 eV to 1.5 eV, and are suitable for 2D electronic applications. The washboard antimonene displays strongly directional mechanical properties, which may give rise to a strong influence of strain on the electronic properties. Single-layer antimonene phases form bilayer and trilayer structures with wide interlayer spacings. In multilayers, this spacing is reduced and eventually the structure changes to 3D pseudolayered bulk crystals. The zigzag and armchair nulloribbons of the antimonene phases have fundamental band gaps derived from reconstructed edge states and display a diversity of magnetic and electronic properties depending on their width and edge geometry. Their band gaps are tunable with the widths of the nulloribbons. When grown on substrates, such as germanene or Ge(111), the buckled antimonene attains a significant influence of substrates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2015, "Volume": 91, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235446, "DOI": "10.1103/PhysRevB.91.235446", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.235446", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356899500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, F; Nguyen, HK; Song, SX; Aji, DPB; Hirata, A; Wang, H; Nakajima, K; Chen, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, F.; Nguyen, H. K.; Song, S. X.; Aji, Daisman P. B.; Hirata, A.; Wang, H.; Nakajima, K.; Chen, M. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic correlation between β-relaxation and spatial heterogeneity in a metallic glass", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "beta-relaxation has long been attributed to localized motion of constituent molecules or atoms confined to isolated regions in glasses. However, direct experimental evidence to support this spatially heterogeneous scenario is still missing. Here we report the evolution of nulloscale structural heterogeneity in a metallic glass during beta-relaxation by utilizing amplitude-modulation dynamic atomic force microscopy. The successive degeneration of heterogeneity during beta-relaxation can be well described by the Kohlrausch-Williams-Watts equation. The characteristic relaxation time and activation energy of the heterogeneity evolution are in accord with those of excess enthalpy release by beta-relaxation. Our study correlates beta-relaxation with nulloscale spatial heterogeneity and provides direct evidence on the structural origins of beta-relaxation in metallic glasses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11516, "DOI": "10.1038/ncomms11516", "DOI Link": "http://dx.doi.org/10.1038/ncomms11516", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375496300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neumann, C; Reichardt, S; Venezuela, P; Drögeler, M; Banszerus, L; Schmitz, M; Watanabe, K; Taniguchi, T; Mauri, F; Beschoten, B; Rotkin, SV; Stampfer, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Neumann, C.; Reichardt, S.; Venezuela, P.; Droegeler, M.; Banszerus, L.; Schmitz, M.; Watanabe, K.; Taniguchi, T.; Mauri, F.; Beschoten, B.; Rotkin, S. V.; Stampfer, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman spectroscopy as probe of nullometre-scale strain variations in graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Confocal Raman spectroscopy has emerged as a major, versatile workhorse for the non-invasive characterization of graphene. Although it is successfully used to determine the number of layers, the quality of edges, and the effects of strain, doping and disorder, the nature of the experimentally observed broadening of the most prominent Raman 2D line has remained unclear. Here we show that the observed 2D line width contains valuable information on strain variations in graphene on length scales far below the laser spot size, that is, on the nullometre-scale. This finding is highly relevant as it has been shown recently that such nullometre-scaled strain variations limit the carrier mobility in high-quality graphene devices. Consequently, the 2D line width is a good and easily accessible quantity for classifying the crystalline quality, nullometre-scale flatness as well as local electronic properties of graphene, all important for future scientific and industrial applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8429, "DOI": "10.1038/ncomms9429", "DOI Link": "http://dx.doi.org/10.1038/ncomms9429", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363140600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "López-Polin, G; Gómez-Navarro, C; Parente, V; Guinea, F; Katsnelson, MI; Pérez-Murano, F; Gómez-Herrero, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lopez-Polin, Guillermo; Gomez-Navarro, Cristina; Parente, Vincenzo; Guinea, Francisco; Katsnelson, Mikhail I.; Perez-Murano, Francesc; Gomez-Herrero, Julio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Increasing the elastic modulus of graphene by controlled defect creation", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The extraordinary strength, stiffness(1) and lightness of graphene have generated great expectations of its application in flexible electronics and as a mechanical reinforcement agent. However, the presence of lattice defects, unavoidable in sheets obtained by scalable routes, might degrade its mechanical properties(2,3). Here we report a systematic study on the elastic modulus and strength of graphene with a controlled density of defects. Counter-intuitively, the in-plane Young's modulus increases with increasing defect density up to almost twice the initial value for a vacancy content of similar to 0.2%. For a higher density of vacancies, the elastic modulus decreases with defect inclusions. The initial increase in Young's modulus is explained in terms of a dependence of the elastic coefficients on the momentum of flexural modes predicted for two-dimensional membranes(4,5). In contrast, the fracture strength decreases with defect density according to standard fracture continuum models. These quantitative structure-property relationships, measured in atmospheric conditions, are of fundamental and technological relevance and provide guidance for applications in which graphene mechanics represents a disruptive improvement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26, "End Page": 31, "Article Number": null, "DOI": "10.1038/NPHYS3183", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3183", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346831100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Jia, HL; Zhou, JK; Huang, XC; Xu, L; Jia, SX; Gao, Z; Yao, KM; Li, DF; Zhang, BB; Liu, YM; Huang, Y; Hu, Y; Zhao, GY; Xu, ZT; Li, JY; Yiu, CK; Gao, YY; Wu, MG; Jiao, YL; Zhang, Q; Tai, XC; Chan, RH; Zhang, YT; Ma, XH; Yu, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jian; Jia, Huiling; Zhou, Jingkun; Huang, Xingcan; Xu, Long; Jia, Shengxin; Gao, Zhan; Yao, Kuanming; Li, Dengfeng; Zhang, Binbin; Liu, Yiming; Huang, Ya; Hu, Yue; Zhao, Guangyao; Xu, Zitong; Li, Jiyu; Yiu, Chun Ki; Gao, Yuyu; Wu, Mengge; Jiao, Yanli; Zhang, Qiang; Tai, Xuecheng; Chan, Raymond H.; Zhang, Yuanting; Ma, Xiaohui; Yu, Xinge", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thin, soft, wearable system for continuous wireless monitoring of artery blood pressure", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous monitoring of arterial blood pressure (BP) outside of a clinical setting is crucial for preventing and diagnosing hypertension related diseases. However, current continuous BP monitoring instruments suffer from either bulky systems or poor user-device interfacial performance, hampering their applications in continuous BP monitoring. Here, we report a thin, soft, miniaturized system (TSMS) that combines a conformal piezoelectric sensor array, an active pressure adaptation unit, a signal processing module, and an advanced machine learning method, to allow real wearable, continuous wireless monitoring of ambulatory artery BP. By optimizing the materials selection, control/sampling strategy, and system integration, the TSMS exhibits improved interfacial performance while maintaining Grade A level measurement accuracy. Initial trials on 87 volunteers and clinical tracking of two hypertension individuals prove the capability of the TSMS as a reliable BP measurement product, and its feasibility and practical usability in precise BP control and personalized diagnosis schemes development. Continuous monitoring of arterial blood pressure is limited by bulky connecting systems and poor interfacial contact. Here, Li et al. report a wearable thin, soft, miniaturized system that integrates sensing, active pressure adaptation, and signal processing for improved performance and accuracy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5009, "DOI": "10.1038/s41467-023-40763-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40763-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001067877800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, J; Liu, CY; Duan, JY; Shao, AW; Li, JL; Li, JG; Gu, WJ; Li, ZX; Liu, SJ; Ma, Y; Huang, W; Zhao, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Juan; Liu, Chenyuan; Duan, Jiayu; Shao, Aiwen; Li, Jinlu; Li, Jiangang; Gu, Wenjie; Li, Zixian; Liu, Shujuan; Ma, Yun; Huang, Wei; Zhao, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformation-dependent dynamic organic phosphorescence through thermal energy driven molecular rotations", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic room-temperature phosphorescent (RTP) materials exhibiting stimuli responsive reversible changes in optical properties show great potential in diverse optoelectronic fields but a lack of mechanistic understanding limits their development. Here, the authors prepare a series of RTP polymers by incorporating phosphorescent rotors into polymer backbones and demonstrate colortunable persistent luminescence upon excitation at different wavelengths Organic room-temperature phosphorescent (RTP) materials exhibiting reversible changes in optical properties upon exposure to external stimuli have shown great potential in diverse optoelectronic fields. Particularly, dynamic manipulation of response behaviors for such materials is of fundamental significance, but it remains a formidable challenge. Herein, a series of RTP polymers were prepared by incorporating phosphorescent rotors into polymer backbone, and these materials show color-tunable persistent luminescence upon excitation at different wavelengths. Experimental results and theoretical calculations revealed that the various molecular conformations of monomers are responsible for the excitation wavelength-dependent (Ex-De) RTP behavior. Impressively, after gaining insights into the underlying mechanism, dynamic control of Ex-De RTP behavior was achieved through thermal energy driven molecular rotations of monomers. Eventually, we demonstrate the practical applications of these amorphous polymers in anti-counterfeiting areas. These findings open new opportunities for the control of response behaviors of smart-responsive RTP materials through external stimuli rather than conventional covalent modification method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-35930-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35930-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954587000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, ZP; Yang, XB; Zhang, P; Ke, XT; Yuan, X; Zhai, LP; Wang, WB; Qin, N; Cui, CX; Qu, LB; Chen, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Zhipeng; Yang, Xiubei; Zhang, Pei; Ke, Xiating; Yuan, Xin; Zhai, Lipeng; Wang, Wenbin; Qin, Na; Cui, Cheng-Xing; Qu, Lingbo; Chen, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vinylene-linked covalent organic frameworks with manipulated electronic structures for efficient solar-driven photocatalytic hydrogen production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vinylene-linked covalent organic frameworks (COFs) are promising photocatalysts owing to their fully conjugated skeletons that facilitate charge carrier mobility. Constructing donor-acceptor (D-A) architectures could further enhance photoinduced charge generation and transport, thus promoting photocatalysis. Therefore, three D-A-type vinylene-linked COFs were fabricated via Knoevenagel polymerization for efficient photocatalysis. By varying the donor moieties from phenyl to 2,5-dimethylbenzene and 3,3'-dimethyl-1,1'-biphenyl in the skeletons, the light-harvesting, opti-cal-bandgap, and charge-transfer properties of the COFs were precisely regulated. All three COFs exhibited attractive photocatalytic hydrogen evolution rates (HERs) upon visible-light irradiation, especially that fabricated using 2,4,6-trimethyl-1,3,5-triazine (TM) and 3,3'-dimethyl[1,1'-biphenyl]-4,4'-dicarboxaldehyde (DMA, TM-DMA-COF). TM-DMA-COF exhibited the strongest D-A interactions, excellent charge-carrier separation and transfer kinetics, and a re-duced energy barrier for H-2 formation. Thus, it afforded the highest HER of 4300 mu mol h(-1) gcat(-1), surpassing those of most state-of-the-art COF photocatalysts. This study provides a simple and effective protocol for modulating the photocatalytic activities of COFs at the molecular level and an interesting insight into the relationship between structural design and photocatalytic performance. (c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 171, "End Page": 180, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64397-9", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64397-9", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992995100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noculak, A; Morad, V; McCall, KM; Yakunin, S; Shynkarenko, Y; Wörle, M; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noculak, Agnieszka; Morad, Viktoriia; McCall, Kyle M.; Yakunin, Sergii; Shynkarenko, Yevhen; Worle, Michael; Kovalenko, Maksym, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bright Blue and Green Luminescence of Sb(III) in Double Perovskite Cs2MInCl6 (M = Na, K) Matrices", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The vast structural and compositional space of metal halides has recently become a major research focus for designing inexpensive and versatile light sources; in particular, for applications in displays, solid-state lighting, lasing, etc. Compounds with isolated ns(2)-metal halide centers often exhibit bright broadband emission that stems from self-trapped excitons (STEs). The Sb(III) halides are attractive STE emitters due to their low toxicity and oxidative stability; however, coupling these features with an appropriately robust, fully inorganic material containing Sb3+ in an octahedral halide environment has proven to be a challenge. Here, we investigate Sb3+ as a dopant in a solution-grown metal halide double perovskite (DP) matrix, namely Cs2MInCl6:xSb (M = Na, K, x = 0-100%). Cs2KInCl6 is found to crystallize in the tetragonal DP phase, unlike Cs2NaInCl6 that adopts the traditional cubic DP structure. This structural difference results in distinct emission colors, as Cs2NaInCl6:xSb and Cs2KInCl6:xSb compounds exhibit broadband blue and green emissions, respectively, with photoluminescence quantum yields (PLQYs) of up to 93%. Spectroscopic and computational investigations confirm that this efficient emission originates from Sb(III)-hosted STEs. These fully inorganic DP compounds demonstrate that Sb(III) can be incorporated as a bright emissive center for stable lighting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2020, "Volume": 32, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5118, "End Page": 5124, "Article Number": null, "DOI": "10.1021/acs.chemmater.0c01004", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.0c01004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543738500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, JH; Zhou, J; Wan, XG; Li, QF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Jihai; Zhou, Jian; Wan, Xiangang; Li, Qingfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High intrinsic lattice thermal conductivity in monolayer MoSi2N4", "Source Title": "NEW JOURNAL OF PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Very recently, a novel two-dimension (2D) MXene, MoSi2N4, was successfully synthesized with excellent ambient stability, high carrier mobility, and moderate band gap (2020 Science 369 670). In this work, the intrinsic lattice thermal conductivity of monolayer MoSi2N4 is predicted by solving the phonon Boltzmann transport equation based on the first-principles calculations. Despite the heavy atomic mass of Mo and complex crystal structure, the monolayer MoSi2N4 unexpectedly exhibits a quite high lattice thermal conductivity over a wide temperature range between 300 to 800 K. At 300 K, its in-plane lattice thermal conductivity is 224 Wm(-1) K-1. The detailed analysis indicates that the large group velocities and small anharmonicity are the main reasons for its high lattice thermal conductivity. We also calculate the lattice thermal conductivity of monolayer WSi2N4, which is only a little smaller than that of MoSi2N4. Our findings suggest that monolayer MoSi2N4 and WSi2N4 are potential 2D materials for thermal transport in future nullo-electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 23, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 33005, "DOI": "10.1088/1367-2630/abe8f7", "DOI Link": "http://dx.doi.org/10.1088/1367-2630/abe8f7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626445000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Yuan, LB; Zhu, YL; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Yuan, Libei; Zhu, Yilong; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triple-Function Electrolyte Regulation toward Advanced Aqueous Zn-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor Zn reversibility has been criticized for limiting applications of aqueous Zn-ion batteries (ZIBs); however, its behavior in aqueous media is not fully uncovered yet. Here, this knowledge gap is addressed, indicating that Zn electrodes face a O-2-involving corrosion, besides H-2 evolution and dendrite growth. Differing from aqueous Li/Na batteries, removing O-2 cannot enhance ZIB performance because of the aggravated competing H-2 evolution. To address Zn issues, a one-off electrolyte strategy is reported by introducing the triple-function C3H7Na2O6P, which can take effects during the shelf time of battery. It regulates H+ concentration and reduces free-water activity, inhibiting H-2 evolution. A self-healing solid/electrolyte interphase (SEI) can be triggered before battery operation, which suppresses O-2 adsorption corrosion and dendritic deposition. Consequently, a high Zn reversibility of 99.6% is achieved under a high discharge depth of 85%. The pouch full-cell with a lean electrolyte displays a record lifespan with capacity retention of 95.5% after 500 cycles. This study not only looks deeply into Zn behavior in aqueous media but also underscores rules for the design of active metal anodes, including Zn and Li metals, during shelf time toward real applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 34, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202206963", "DOI Link": "http://dx.doi.org/10.1002/adma.202206963", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863031000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baier, MC; Zuideveld, MA; Mecking, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baier, Moritz C.; Zuideveld, Martin A.; Mecking, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Post-Metallocenes in the Industrial Production of Polyolefins", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Research on post-metallocene polymerization catalysis ranges methodologically from fundamental mechanistic studies of polymerization reactions over catalyst design to material properties of the polyolefins prepared. A common goal of these studies is the creation of practically useful new polyolefin materials or polymerization processes. This Review gives a comprehensive overview of post-metallocene polymerization catalysts that have been put into practice. The decisive properties for this success of a given catalyst structure are delineated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 428, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2014, "Volume": 53, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9722, "End Page": 9744, "Article Number": null, "DOI": "10.1002/anie.201400799", "DOI Link": "http://dx.doi.org/10.1002/anie.201400799", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342678200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZY; Zhang, Y; Lopez, V; Sánchez-Tejerina, L; Shi, JC; Feng, XQ; Chen, L; Wang, ZL; Zhang, ZZ; Zhang, K; Hong, B; Xu, Y; Zhang, YG; Carpentieri, M; Fert, A; Finocchio, G; Zhao, WS; Amiri, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhenyi; Zhang, Yue; Lopez-Dominguez, Victor; Sanchez-Tejerina, Luis; Shi, Jiacheng; Feng, Xueqiang; Chen, Lei; Wang, Zilu; Zhang, Zhizhong; Zhang, Kun; Hong, Bin; Xu, Yong; Zhang, Youguang; Carpentieri, Mario; Fert, Albert; Finocchio, Giovanni; Zhao, Weisheng; Amiri, Pedram Khalili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-free spin-orbit torque-induced switching of perpendicular magnetization in a ferrimagnetic layer with a vertical composition gradient", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current-induced spin-orbit torques (SOTs) are of interest for fast and energy-efficient manipulation of magnetic order in spintronic devices. To be deterministic, however, switching of perpendicularly magnetized materials by SOT requires a mechanism for in-plane symmetry breaking. Existing methods to do so involve the application of an in-plane bias magnetic field, or incorporation of in-plane structural asymmetry in the device, both of which can be difficult to implement in practical applications. Here, we report bias-field-free SOT switching in a single perpendicular CoTb layer with an engineered vertical composition gradient. The vertical structural inversion asymmetry induces strong intrinsic SOTs and a gradient-driven Dzyaloshinskii-Moriya interaction (g-DMI), which breaks the in-plane symmetry during the switching process. Micromagnetic simulations are in agreement with experimental results, and elucidate the role of g-DMI in the deterministic switching processes. This bias-field-free switching scheme for perpendicular ferrimagnets with g-DMI provides a strategy for efficient and compact SOT device design. Switching of ferrimagnets by current-induced spin-orbit torque is promising for spintronics, due to their high-speed dynamics and small macroscopic magnetization. Switching of perpendicularly magnetized materials, however, requires a bias field for symmetry breaking. Here, Zheng et al demonstrate field-free current-induced switching of perpendicular ferrimagnets, using a compositional gradient-driven Dzyaloshinskii-Moriya interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4555, "DOI": "10.1038/s41467-021-24854-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24854-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683367300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, K; Feng, SZ; Han, Y; Gao, LB; Ly, TH; Xu, ZP; Lu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Ke; Feng, Shizhe; Han, Ying; Gao, Libo; Thuc Hue Ly; Xu, Zhiping; Lu, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic straining of free-standing monolayer graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sp(2) nature of graphene endows the hexagonal lattice with very high theoretical stiffness, strength and resilience, all well-documented. However, the ultimate stretchability of graphene has not yet been demonstrated due to the difficulties in experimental design. Here, directly performing in situ tensile tests in a scanning electron microscope after developing a protocol for sample transfer, shaping and straining, we report the elastic properties and stretchability of free-standing single-crystalline monolayer graphene grown by chemical vapor deposition. The measured Young's modulus is close to 1 TPa, aligning well with the theoretical value, while the representative engineering tensile strength reaches similar to 50-60GPa with sample-wide elastic strain up to similar to 6%. Our findings demonstrate that single-crystalline monolayer graphene can indeed display near ideal mechanical performance, even in a large area with edge defects, as well as resilience and mechanical robustness that allows for flexible electronics and mechatronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 284, "DOI": "10.1038/s41467-019-14130-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14130-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512534100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schlaus, AP; Spencer, MS; Miyata, K; Liu, F; Wang, XX; Datta, I; Lipson, M; Pan, AL; Zhu, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schlaus, Andrew P.; Spencer, Michael S.; Miyata, Kiyoshi; Liu, Fang; Wang, Xiaoxia; Datta, Ipshita; Lipson, Michal; Pan, Anlian; Zhu, X. -Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How lasing happens in CsPbBr3 perovskite nullowires", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskites are emerging as an excellent material platform for optoelectronic processes. There have been extensive discussions on lasing, polariton formation, and nonlinear processes in this material system, but the underlying mechanism remains unknown. Here we probe lasing from CsPbBr3 perovskite nullowires with picosecond (ps) time resolution and show that lasing originates from stimulated emission of an electron-hole plasma. We observe an anomalous blue-shifting of the lasing gain profile with time up to 25 ps, and assign this as a signature for lasing involving plasmon emission. The time domain view provides an ultra-sensitive probe of many-body physics which was obscured in previous time-integrated measurements of lasing from lead halide perovskite nullowires.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 265, "DOI": "10.1038/s41467-018-07972-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07972-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455762900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saif, T; Lin, QY; Butcher, AR; Bijeljic, B; Blunt, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saif, Tarik; Lin, Qingyang; Butcher, Alan R.; Bijeljic, Branko; Blunt, Martin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-scale multi-dimensional microstructure imaging of oil shale pyrolysis using X-ray micro-tomography, automated ultra-high resolution SEM, MAPS Mineralogy and FIB-SEM", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complexity of unconventional rock systems is expressed both in the compositional variance of the microstructure and the extensive heterogeneity of the pore space. Visualizing and quantifying the microstructure of oil shale before and after pyrolysis permits a more accurate determination of petrophysical properties which are important in modeling hydrocarbon production potential. We characterize the microstructural heterogeneity of oil shale using X-ray micro-tomography (ACT), automated ultra-high resolution scanning electron microscopy (SEM), MAPS Mineralogy (Modular Automated Processing System) and Focused Ion Beam Scanning Electron Microscopy (FIB-SEM). The organic-rich Eocene Green River (Mahogany zone) oil shale is characterized using a multi-scale multi-dimensional workflow both before and after pyrolysis. Observations in 2-D and 3-D and across nm-m-mm length scales demonstrate both heterogeneity and anisotropy at every scale. Image acquisition and analysis using mu CT and SEM reveal a microstructure of alternating kerogen-rich laminations interbedded with layers of fine-grained inorganic minerals. MAPS Mineralogy combined with ultrafast measurements reveal mineralogic textures dominated by dolomite, calcite, K-feldspar, quartz, pyrite and illitic clays along with their spatial distribution, augmenting conventional mineral analysis. From high resolution Backscattered electron (BSE) images, intra-organic, inter-organic-mineral, intra- and inter-mineral pores are observed with varying sizes and geometries. By using FIB milling and SEM imaging sequentially and repetitively, 3-D data sets were reconstructed. By setting 3-D gradient and marker-based watershed transforms, the organic matter, minerals and pore phases (including pore-back artifacts) were segmented and visualized and the pore-size distribution was computed. Following pyrolysis, fractures from the mm-to-pm scales were observed with preferential propagation along the kerogen-rich laminations and coalescence leading to an interconnected fracture network. The application of these techniques to worldwide oil shale deposits will allow significant insights into estimating mechanical and chemical proprieties of oil shale formations for modeling and designing oil shale pyrolysis processes. (C) 2017 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2017, "Volume": 202, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 628, "End Page": 647, "Article Number": null, "DOI": "10.1016/j.apenergy.2017.05.039", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2017.05.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407188500051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Skibsted, J; Snellings, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Skibsted, Jurgen; Snellings, Ruben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reactivity of supplementary cementitious materials (SCMs) in cement blends", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supplementary cementitious materials (SCMs) are key components of sustainable, low carbon cements. To maximize their use in blended cements, the impact of SCMs on cement hydration needs to be understood and accurately captured by models. A central element in such models is the reactivity of the SCM, which is tedious to measure. Establishing relationships between SCM properties and their intrinsic reactivity is therefore highly important. Moreover, mechanisms enhancing or limiting SCM reactivity in blended cements need to be well understood. This work reviews recent progress in the description and understanding of the reactivity of SCMs and their impact on Portland clinker hydration. Insights derived from fundamental work using synthetic SCMs, dissolution experiments and model systems are discussed as well as recent work studying the impact of common SCMs on hydration and microstructure of blended cements. Particular attention is paid to recent work on calcined clays, which are currently receiving substantial interest.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105799, "DOI": "10.1016/j.cemconres.2019.105799", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2019.105799", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495142700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rosenkrans, ZT; Sun, TW; Jiang, DW; Chen, WY; Barnhart, TE; Zhang, ZY; Ferreira, CA; Wang, XD; Engle, JW; Huang, P; Cai, WB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rosenkrans, Zachary T.; Sun, Tuanwei; Jiang, Dawei; Chen, Weiyu; Barnhart, Todd E.; Zhang, Ziyi; Ferreira, Carolina A.; Wang, Xudong; Engle, Jonathan W.; Huang, Peng; Cai, Weibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selenium-Doped Carbon Quantum Dots Act as Broad-Spectrum Antioxidants for Acute Kidney Injury Management", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The manifestation of acute kidney injury (AKI) is associated with poor patient outcomes, with treatment options limited to hydration or renal replacement therapies. The onset of AKI is often associated with a surfeit of reactive oxygen species. Here, it is shown that selenium-doped carbon quantum dots (SeCQDs) have broad-spectrum antioxidant properties and prominent renal accumulation in both healthy and AKI mice. Due to these properties, SeCQDs treat or prevent two clinically relevant cases of AKI induced in murine models by either rhabdomyolysis or cisplatin using only 1 or 50 mu g per mouse, respectively. The attenuation of AKI in both models is confirmed by blood serum measurements, kidney tissue staining, and relevant biomarkers. The therapeutic efficacy of SeCQDs exceeds amifostine, a drug approved by the Food and Drug Administration that also acts by scavenging free radicals. The findings indicate that SeCQDs show great potential as a treatment option for AKI and possibly other ROS-related diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000420, "DOI": "10.1002/advs.202000420", "DOI Link": "http://dx.doi.org/10.1002/advs.202000420", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529196800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sadeghi, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sadeghi, Gholamabbas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy storage on demand: Thermal energy storage development, materials, design, and integration challenges", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Climate change along with our insatiable need for energy demand a paradigm shift towards more rational and sustainable use of energy. To drive this transition, the deployment of innovative energy technologies is necessary and required. Thermal energy storage has a prominent role to play in this context as it can help us manage the demand and generation of energy that are currently out of phase. Even though there exist many valuable review contents in the literature addressing various heat storage methods separately, the need for a concise and comprehensive source of information to present related ideas and applications is still sensed. The overall aim of the present review paper after introducing the thermal energy storage materials and working procedure is to investigate significant research contributions focusing on, and linking both practical applications and scientific aspects of the problem. Articles reporting original, cutting-edge research with experimental, theoretical, and numerical findings unraveling pertinent aspects of novel thermal energy storage systems are considered. Furthermore, their design, characterization, optimization considerations, and integration challenges have been addressed in a multi scale manner from component to system level to present a broader standpoint in this field of science. Ultimately, short-term and long-term thermal energy storage processes have been discussed as well as the capability of thermal energy storage technology in the thermal management of batteries and high-heat-flux electronic devices has been revealed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 192, "End Page": 222, "Article Number": null, "DOI": "10.1016/j.ensm.2022.01.017", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2022.01.017", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783570800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YS; Zhang, P; Zhang, SJ; Wang, Z; Li, N; Silva, SRP; Shao, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yongshang; Zhang, Peng; Zhang, Shijie; Wang, Zheng; Li, Neng; Silva, S. Ravi P.; Shao, Guosheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A flexible metallic TiC nullofiber/vertical graphene 1D/2D heterostructured as active electrocatalyst for advanced Li-S batteries", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The realistic application of lithium-sulfur (Li-S) batteries has been severely hindered by the sluggish conversion kinetics of polysulfides (LiPS) and inhomogeneous deposition of Li2S at high sulfur loading and low electrolyte/sulfur ratio (E/S). Herein, a flexible Li-S battery architecture based on electrocatalyzed cathodes made of interfacial engineered TiC nullofibers and in situ grown vertical graphene are developed. Integrated 1D/2D heterostructured electrocatalysts are realized to enable highly improved Li+ and electron transportation together with significantly enhanced affinity to LiPS, which effectively accelerate the conversion kinetics between sulfur species, and thus induce homogeneous deposition of Li2S in the catalyzed cathodes. Consequently, highly active electro-electrocatalysts-based cells exhibit remarkable rate capability at 2C with a high specific capacity of 971 mAh g(-1). Even at ultra-high sulfur loading and low E/S ratio, the battery still delivers a high areal capacity of 9.1 mAh cm(-2), with a flexible pouch cell being demonstrated to power a LED array at different bending angles with a high capacity over 100 cycles. This work puts forward a novel pathway for the rational design of effective nullofiber electrocatalysts for cathodes of high-performance Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 790, "End Page": 803, "Article Number": null, "DOI": "10.1002/inf2.12214", "DOI Link": "http://dx.doi.org/10.1002/inf2.12214", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659020800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, R; Zheng, SJ; Liu, ZS; Ng, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Rong; Zheng, Shoujing; Liu, Zishun; Ng, Teng Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Advances of the Constitutive Models of Smart Materials - Hydrogels and Shape Memory Polymers", "Source Title": "INTERNATIONAL JOURNAL OF APPLIED MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels and shape memory polymers (SMPs) possess excellent and interesting properties that may be harnessed for future applications. However, this is not achievable if their mechanical behaviors are not well understood. This paper aims to discuss recent advances of the constitutive models of hydrogels and SMPs, in particular the theories associated with their deformations. On the one hand, constitutive models of six main types of hydrogels are introduced, the categorization of which is defined by the type of stimulus. On the other hand, constitutive models of thermal-induced SMPs are discussed and classified into three main categories, namely, rheological models; phase transition models; and models combining viscoelasticity and phase transition, respectively. Another feature in this paper is a summary of the common hyperelastic models, which can be potentially developed into the constitutive models of hydrogels and SMPs. In addition, the main advantages and disadvantages of these constitutive modes are discussed. In order to provide a compass for researchers involved in the study of mechanics of soft materials, some research gaps and new research directions for hydrogels and SMPs constitutive modes are presented. We hope that this paper can serve as a reference for future hydrogel and SMP studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2050014, "DOI": "10.1142/S1758825120500143", "DOI Link": "http://dx.doi.org/10.1142/S1758825120500143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528259500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, SC; Kang, K; Shayan, K; Yoshimura, A; Dadras, S; Wang, XT; Zhang, LH; Chen, SW; Liu, N; Jindal, A; Li, XZ; Pasupathy, AN; Vamivakas, AN; Meunier, V; Strauf, S; Yang, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Shichen; Kang, Kyungnam; Shayan, Kamran; Yoshimura, Anthony; Dadras, Siamak; Wang, Xiaotian; Zhang, Lihua; Chen, Siwei; Liu, Na; Jindal, Apoorv; Li, Xiangzhi; Pasupathy, Abhay N.; Vamivakas, A. Nick; Meunier, Vincent; Strauf, Stefan; Yang, Eui-Hyeok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling room temperature ferromagnetism in monolayer MoS2 via in situ iron-doping", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional semiconductors, including transition metal dichalcogenides, are of interest in electronics and photonics but remain nonmagnetic in their intrinsic form. Previous efforts to form two-dimensional dilute magnetic semiconductors utilized extrinsic doping techniques or bulk crystal growth, detrimentally affecting uniformity, scalability, or Curie temperature. Here, we demonstrate an in situ substitutional doping of Fe atoms into MoS2 monolayers in the chemical vapor deposition growth. The iron atoms substitute molybdenum sites in MoS2 crystals, as confirmed by transmission electron microscopy and Raman signatures. We uncover an Fe-related spectral transition of Fe:MoS2 monolayers that appears at 2.28eV above the pristine bandgap and displays pronounced ferromagnetic hysteresis. The microscopic origin is further corroborated by density functional theory calculations of dipole-allowed transitions in Fe:MoS2. Using spatially integrating magnetization measurements and spatially resolving nitrogen-vacancy center magnetometry, we show that Fe:MoS2 monolayers remain magnetized even at ambient conditions, manifesting ferromagnetism at room temperature. Ferromagnetism with a Curie temperature above room temperature in 2D materials is highly desirable for practical spintronics applications. Here, the authors demonstrate such phenomenon in monolayer MoS2 via in situ iron-doping and measured local magnetic field strength up to 0.5 +/- 0.1 mT.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2034, "DOI": "10.1038/s41467-020-15877-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15877-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530488100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhuo, Y; Tehrani, AM; Oliynyk, AO; Duke, AC; Brgoch, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhuo, Ya; Tehrani, Aria Mansouri; Oliynyk, Anton O.; Duke, Anna C.; Brgoch, Jakoah", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying an efficient, thermally robust inorganic phosphor host via machine learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rare-earth substituted inorganic phosphors are critical for solid state lighting. New phosphors are traditionally identified through chemical intuition or trial and error synthesis, inhibiting the discovery of potential high-performance materials. Here, we merge a support vector machine regression model to predict a phosphor host crystal structure's Debye temperature, which is a proxy for photoluminescent quantum yield, with high-throughput density functional theory calculations to evaluate the band gap. This platform allows the identification of phosphors that may have otherwise been overlooked. Among the compounds with the highest Debye temperature and largest band gap, NaBaB9O15 shows outstanding potential. Following its synthesis and structural characterization, the structural rigidity is confirmed to stem from a unique corner sharing [B3O7](5-) polyanionic backbone. Substituting this material with Eu2+ yields UV excitation bands and a narrow violet emission at 416 nm with a full-width at half-maximum of 34.5 nm. More importantly, NaBaB9O15: Eu2+ possesses a quantum yield of 95% and excellent thermal stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4377, "DOI": "10.1038/s41467-018-06625-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06625-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447840500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bayat, M; Thanki, A; Mohanty, S; Witvrouw, A; Yang, SF; Thorborg, J; Tiedje, NS; Hattel, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bayat, Mohamad; Thanki, Aditi; Mohanty, Sankhya; Witvrouw, Ann; Yang, Shoufeng; Thorborg, Jesper; Tiedje, Niels Skat; Hattel, Jesper Henri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Keyhole-induced porosities in Laser-based Powder Bed Fusion (L-PBF) of Ti6Al4V: High-fidelity modelling and experimental validation", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal additive manufacturing, despite of offering unique capabilities e.g. unlimited design freedom, short manufacturing time, etc., suffers from raft of intrinsic defects. Porosity is of the defects which can badly deteriorate a part's performance. In this respect, enabling one to observe and predict the porosity during this process is of high importance. To this end, in this work a combined numerical and experimental approach has been used to analyze the formation, evolution and disappearance of keyhole and keyhole-induced porosities along with their initiating mechanisms, during single track L-PBF of a Ti6Al4V alloy. In this respect, a high-fidelity numerical model based on the Finite Volume Method (FVM) and accomplished in the commercial software Flow-3D is developed. The model accounts for the major physics taking place during the laser-scanning step of the L-PBF process. To better simulate the actual laser-material interaction, multiple reflection with the ray-tracing method has been implemented along with the Fresnel absorption function. The results show that during the keyhole regime, the heating rises dramatically compared to the shallow-depth melt pool regime due to the large entrapment of laser rays in the keyhole cavities. Also a detailed parametric study is performed to investigate the effect of input power on thermal absorptivity, heat transfer and melt pool anatomy. Furthermore, an X-ray Computed Tomography (X-CT) analysis is carried out to visualize the pores formed during the L-PBF process. It is shown, that the predicted shape, size and depth of the pores are in very good agreement with those found by either X-CT or optical and 3D digital microscopic images.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 358, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 30, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100835, "DOI": "10.1016/j.addma.2019.100835", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2019.100835", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000501768100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JY; Yan, YL; Gao, ZH; Du, YX; Dong, HY; Yao, JN; Zhao, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jinyang; Yan, Yongli; Gao, Zhenhua; Du, Yuxiang; Dong, Haiyun; Yao, Jiannian; Zhao, Yong Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-color laser displays based on organic printed microlaser arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser displays, which exploit characteristic advantages of lasers, represent a promising next-generation display technology based on the ultimate visual experience they provide. However, the inability to obtain pixelated laser arrays as self-emissive full-color panels hinders the application of laser displays in the flat-panel sector. Due to their excellent optoelectronic properties and processability, organic materials have great potential for the production of periodically patterned multi-color microlaser arrays. Here, we demonstrate for the first time full-color laser displays on precisely patterned organic red-green-blue (RGB) microlaser matrices through inkjet printing. Individual RGB laser pixels are realized by doping respective luminescent dyes into the ink materials, resulting in a wide achievable color gamut 45% larger than the standard RGB space. Using as-prepared microlaser arrays as full-color panels, we achieve dynamic laser displays for video playing through consecutive beam scanning. These results represent a major step towards full-color laser displays with outstanding color expression.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 870, "DOI": "10.1038/s41467-019-08834-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08834-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459097100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anasori, B; Dahlqvist, M; Halim, J; Moon, EJ; Lu, J; Hosler, BC; Caspi, EN; May, SJ; Hultman, L; Eklund, P; Rosén, J; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anasori, Babak; Dahlqvist, Martin; Halim, Joseph; Moon, Eun Ju; Lu, Jun; Hosler, Brian C.; Caspi, El'ad N.; May, Steven J.; Hultman, Lars; Eklund, Per; Rosen, Johanna; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental and theoretical characterization of ordered MAX phases Mo2TiAlC2 and Mo2Ti2AlC3", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we report on the phase stabilities and crystal structures of two newly discovered ordered, quaternary MAX phases-Mo2TiAlC2 and Mo2Ti2AlC3-synthesized by mixing and heating different elemental powder mixtures of mMo:(3-m) Ti:1.1Al:2C with 1.5 <= m <= 2.2 and 2Mo: 2Ti:1.1Al:2.7C to 1600 degrees C for 4 h under Ar flow. In general, for m >= 2 an ordered 312 phase, (Mo2Ti) AlC2, was the majority phase; for m< 2, an ordered 413 phase (Mo2Ti2)AlC3, was the major product. The actual chemistries determined from X-ray photoelectron spectroscopy (XPS) are Mo2TiAlC1.7 and Mo2Ti1.9Al0.9C2.5, respectively. High resolution scanning transmission microscopy, XPS and Rietveld analysis of powder X-ray diffraction confirmed the general ordered stacking sequence to be Mo-Ti-Mo-Al-Mo-Ti-Mo for Mo2TiAlC2 and Mo-Ti-Ti-Mo-Al-Mo-Ti-Ti-Mo for Mo2Ti2AlC3, with the carbon atoms occupying the octahedral sites between the transition metal layers. Consistent with the experimental results, the theoretical calculations clearly show that M layer ordering is mostly driven by the high penalty paid in energy by having the Mo atoms surrounded by C in a face-centered configuration, i.e., in the center of the Mn+1Xn blocks. At 331 GPa and 367 GPa, respectively, the Young's moduli of the ordered Mo2TiAlC2 and Mo2Ti2AlC3 are predicted to be higher than those calculated for their ternary end members. Like most other MAX phases, because of the high density of states at the Fermi level, the resistivity measurement over 300 to 10K for both phases showed metallic behavior. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2015, "Volume": 118, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 94304, "DOI": "10.1063/1.4929640", "DOI Link": "http://dx.doi.org/10.1063/1.4929640", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360926500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Luo, JY; Fatemi, V; Fang, S; Sanchez-Yamagishi, JD; Watanabe, K; Taniguchi, T; Kaxiras, E; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Y.; Luo, J. Y.; Fatemi, V.; Fang, S.; Sanchez-Yamagishi, J. D.; Watanabe, K.; Taniguchi, T.; Kaxiras, E.; Jarillo-Herrero, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superlattice-Induced Insulating States and Valley-Protected Orbits in Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Twisted bilayer graphene (TBLG) is one of the simplest van der Waals heterostructures, yet it yields a complex electronic system with intricate interplay between moire physics and interlayer hybridization effects. We report on electronic transport measurements of high mobility small angle TBLG devices showing clear evidence for insulating states at the superlattice band edges, with thermal activation gaps several times larger than theoretically predicted. Moreover, Shubnikov-de Haas oscillations and tight binding calculations reveal that the band structure consists of two intersecting Fermi contours whose crossing points are effectively unhybridized. We attribute this to exponentially suppressed interlayer hopping amplitudes for momentum transfers larger than the moire wave vector.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2016, "Volume": 117, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116804, "DOI": "10.1103/PhysRevLett.117.116804", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.116804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383247500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mushtaq, F; Chen, XZ; Hoop, M; Torlakcik, H; Pellicer, E; Sort, J; Gattinoni, C; Nelson, BJ; Pané, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mushtaq, Fajer; Chen, Xiangzhong; Hoop, Marcus; Torlakcik, Harun; Pellicer, Eva; Sort, Jordi; Gattinoni, Chiara; Nelson, Bradley J.; Pane, Salvador", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Piezoelectrically Enhanced Photocatalysis with BiFeO3 nullostructures for Efficient Water Remediation", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing new catalysts that can efficiently utilize multiple energy sources can contribute to solving the current challenges of environmental remediation and increasing energy demands. In this work, we fabricated single-crystalline BiFeO3 (BFO) nullosheets and nullowires that can successfully harness visible light and mechanical vibrations and utilize them for degradation of organic pollutants. Under visible light both BFO nullostructures displayed a relatively slow reaction rate. However, under piezocatalysis both nullosheets and nullowires exhibited higher reaction rates in comparison with photocatalytic degradation. When both solar light and mechanical vibrations were used simultaneously, the reaction rates were elevated even further, with the BFO nullowires degrading 97% of RhB dye within 1 hr (k-value 0.058 min(-1)). The enhanced degradation under mechanical vibrations can be attributed to the promotion of charge separation caused by the internal piezoelectric field of BFO. BFO nullowires also exhibited good reusability and versatility toward degrading four different organic pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2018, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 236, "End Page": "+", "Article Number": null, "DOI": "10.1016/j.isci.2018.06.003", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2018.06.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449721800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sandberg, RB; Montoya, JH; Chan, K; Norskov, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sandberg, Robert B.; Montoya, Joseph H.; Chan, Karen; Norskov, Jens K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CO-CO coupling on Cu facets: Coverage, strain and field effects", "Source Title": "SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a DFT study on the effect of coverage, strain, and electric field on CO-CO coupling energetics on Cu (100), (111), and (211). Our calculations indicate that CO-CO coupling is facile on all three facets in the presence of a cation-induced electric field in the Helmholtz plane, with the lowest barrier on Cu(100). The CO dimerization pathway is therefore expected to play a role in C-2 formation at potentials negative of the Cu potential of zero charge, corresponding to CO2/CO reduction conditions at high pH. Both increased *CO coverage and tensile strain further improve C-C coupling energetics on Cu (111) and (211). Since CO dimerization is facile on all 3 Cu facets, subsequent surface hydrogenation steps may also play an important role in determining the overall activity towards C-2 products. Adsorption of *CO, *H, and *OH on the 3 facets were investigated with a Pourbaix analysis. The (211) facet has the largest propensity to co-adsorb *CO and *H, which would favor surface hydrogenation following CO dimerization. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 654, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 56, "End Page": 62, "Article Number": null, "DOI": "10.1016/j.susc.2016.08.006", "DOI Link": "http://dx.doi.org/10.1016/j.susc.2016.08.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396297900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Zhang, L; Zheng, Y; Guo, Z; Zhu, YM; Chen, HJ; Li, F; Liu, PP; Yu, B; Wang, XW; Liu, J; Chen, Y; Liu, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xi; Zhang, Lei; Zheng, Yun; Guo, Zheng; Zhu, Yunmin; Chen, Huijun; Li, Fei; Liu, Peipei; Yu, Bo; Wang, Xinwei; Liu, Jiang; Chen, Yan; Liu, Meilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uncovering the Effect of Lattice Strain and Oxygen Deficiency on Electrocatalytic Activity of Perovskite Cobaltite Thin Films", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing cost effective electrocatalysts with high oxygen evolution reaction (OER) activity is essential for large-scale application of many electrochemical energy systems. Although the impacts of either lattice strain or oxygen defects on the OER performance of oxide catalysts have been extensively investigated, the effects of both factors are normally treated separately. In this work, the coupled effects of both strain and oxygen deficiency on the electrocatalytic activity of La0.7Sr0.3CoO3- (LSC) thin films grown on single crystal substrates (LaAlO3 (LAO) and SrTiO3 (STO)) are investigated. Electrochemical tests show that the OER activities of LSC films are higher under compression than under tension, and are diminished as oxygen vacancies are introduced by vacuum annealing. Both experimental and computational results indicate that the LSC films under tension (e.g., LSC/STO) have larger oxygen deficiency than the films under compression (e.g., LSC/LAO), which attribute to smaller oxygen vacancy formation energy. Such strain-induced excessive oxygen vacancies in the LSC/STO increases the e(g) state occupancy and enlarges the energy gap between the O 2p and Co 3d band, resulting in lower OER activity. Understanding the critical role of strain-defect coupling is important for achieving the rational design of highly active and durable catalysts for energy devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1801898, "DOI": "10.1002/advs.201801898", "DOI Link": "http://dx.doi.org/10.1002/advs.201801898", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462613100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, XZ; Zheng, RJ; Gao, CY; Wei, WF; Peng, JGL; Wang, RH; Yang, SH; Zou, WS; Wu, XY; Ji, YF; Chen, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Xuezhen; Zheng, Renji; Gao, Caiyan; Wei, Wenfei; Peng, Jiangguli; Wang, Ranhao; Yang, Songhe; Zou, Wensong; Wu, Xiaoyong; Ji, Yongfei; Chen, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unlocking bimetallic active sites via a desalination strategy for photocatalytic reduction of atmospheric carbon dioxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin two-dimensional (2D) metal oxyhalides exhibit outstanding photocatalytic properties with unique electronic and interfacial structures. Compared with monometallic oxyhalides, bimetallic oxyhalides are less explored. In this work, we have developed a novel top-down wet-chemistry desalination approach to remove the alkali-halide salt layer within the complicated precursor bulk structural matrix Pb0.6Bi1.4Cs0.6O2Cl2, and successfully fabricate a new 2D ultrathin bimetallic oxyhalide Pb0.6Bi1.4O2Cl1.4. The unlocked larger surface area, rich bimetallic active sites, and faster carrier dynamics within Pb0.6Bi1.4O2Cl1.4 layers significantly enhance the photocatalytic efficiency for atmospheric CO2 reduction. It outperforms the corresponding parental matrix phase and other state-of-the-art bismuth-based monometallic oxyhalides photocatalysts. This work reports a top-down desalination strategy to engineering ultrathin bimetallic 2D material for photocatalytic atmospheric CO2 reduction, which sheds light on further constructing other ultrathin 2D catalysts for environmental and energy applications from similar complicate structure matrixes. Ultrathin two-dimensional metal oxyhalides show excellent photocatalytic properties with unique electronic and interfacial structures. Here, the authors develop a top-down desalination strategy to engineer ultrathin bimetallic two-dimensional material for photocatalytic atmospheric carbon dioxide reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2146, "DOI": "10.1038/s41467-022-29671-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29671-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784989100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HF; Xie, XH; Zheng, YF; Cong, Y; Zhou, FY; Qiu, KJ; Wang, X; Chen, SH; Huang, L; Tian, L; Qin, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, H. F.; Xie, X. H.; Zheng, Y. F.; Cong, Y.; Zhou, F. Y.; Qiu, K. J.; Wang, X.; Chen, S. H.; Huang, L.; Tian, L.; Qin, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of biodegradable Zn-1X binary alloys with nutrient alloying elements Mg, Ca and Sr", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biodegradable metals have attracted considerable attentions in recent years. Besides the early launched biodegradable Mg and Fe metals, Zn, an essential element with osteogenic potential of human body, is regarded and studied as a new kind of potential biodegradable metal quite recently. Unfortunately, pure Zn is soft, brittle and has low mechanical strength in the practice, which needs further improvement in order to meet the clinical requirements. On the other hand, the widely used industrial Zn-based alloys usually contain biotoxic elements (for instance, ZA series contain toxic Al elements up to 40 wt.%), which subsequently bring up biosafety concerns. In the present work, novel Zn-1X binary alloys, with the addition of nutrition elements Mg, Ca and Sr were designed (cast, rolled and extruded Zn-1Mg, Zn-1Ca and Zn-1Sr). Their microstructure and mechanical property, degradation and in vitro and in vivo biocompatibility were studied systematically. The results demonstrated that the Zn-1X (Mg, Ca and Sr) alloys have profoundly modified the mechanical properties and biocompatibility of pure Zn. Zn-1X (Mg, Ca and Sr) alloys showed great potential for use in a new generation of biodegradable implants, opening up a new avenue in the area of biodegradable metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10719, "DOI": "10.1038/srep10719", "DOI Link": "http://dx.doi.org/10.1038/srep10719", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355593600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dicker, KT; Gurski, LA; Pradhan-Bhatt, S; Witt, RL; Farach-Carson, MC; Jia, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dicker, Kevin T.; Gurski, Lisa A.; Pradhan-Bhatt, Swati; Witt, Robert L.; Farach-Carson, Mary C.; Jia, Xinqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyaluronull: A simple polysaccharide with diverse biological functions", "Source Title": "ACTA BIOMATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hyaluronull (HA) is a linear polysaccharide with disaccharide repeats of D-glucuronic acid and N-acetyl-D-glucosamine. It is evolutionarily conserved and abundantly expressed in the extracellular matrix (ECM), on the cell surface and even inside cells. Being a simple polysaccharide, HA exhibits an astonishing array of biological functions. HA interacts with various proteins or proteoglycans to organize the ECM and to maintain tissue homeostasis. The unique physical and mechanical properties of HA contribute to the maintenullce of tissue hydration, the mediation of solute diffusion through the extracellular space and the lubrication of certain tissues. The diverse biological functions of HA are manifested through its complex interactions with matrix components and resident cells. Binding of HA with cell surface receptors activates various signaling pathways, which regulate cell function, tissue development, inflammation, wound healing and tumor progression and metastasis. Taking advantage of the inherent biocompatibility and biodegradability of HA, as well as its susceptibility to chemical modification, researchers have developed various HA-based biomaterials and tissue constructs with promising and broad clinical potential. This paper illustrates the properties of HA from a matrix biology perspective by first introducing the principles underlying the biosynthesis and biodegradation of HA, as well as the interactions of HA with various proteins and proteoglycans. It next highlights the roles of HA in physiological and pathological states, including morphogenesis, wound healing and tumor metastasis. A deeper understanding of the mechanisms underlying the roles of HA in various physiological processes can provide new insights and tools for the engineering of complex tissues and tissue models. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 485, "Times Cited, All Databases": 558, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1558, "End Page": 1570, "Article Number": null, "DOI": "10.1016/j.actbio.2013.12.019", "DOI Link": "http://dx.doi.org/10.1016/j.actbio.2013.12.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334137700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LX; Rao, LJ; Ran, MX; Shentu, Q; Wu, ZL; Song, WK; Zhang, ZW; Li, H; Yao, YY; Lv, WY; Xing, MY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lixin; Rao, Longjun; Ran, Maoxi; Shentu, Qikai; Wu, Zenglong; Song, Wenkai; Zhang, Ziwei; Li, Hao; Yao, Yuyuan; Lv, Weiyang; Xing, Mingyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A polymer tethering strategy to achieve high metal loading on catalysts for Fenton reactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of heterogenous catalysts based on the synthesis of 2D carbon-supported metal nullocatalysts with high metal loading and dispersion is important. However, such practices remain challenging to develop. Here, we report a self-polymerization confinement strategy to fabricate a series of ultrafine metal embedded N-doped carbon nullosheets (M@N-C) with loadings of up to 30 wt%. Systematic investigation confirms that abundant catechol groups for anchoring metal ions and entangled polymer networks with the stable coordinate environment are essential for realizing high-loading M@N-C catalysts. As a demonstration, Fe@N-C exhibits the dual high-efficiency performance in Fenton reaction with both impressive catalytic activity (0.818 min-1) and H2O2 utilization efficiency (84.1%) using sulfamethoxazole as the probe, which has not yet been achieved simultaneously. Theoretical calculations reveal that the abundant Fe nullocrystals increase the electron density of the N-doped carbon frameworks, thereby facilitating the continuous generation of long-lasting surface-bound center dot OH through lowering the energy barrier for H2O2 activation. This facile and universal strategy paves the way for the fabrication of diverse high-loading heterogeneous catalysts for broad applications. This work reports a self-polymerization confinement strategy to develop and synthesize carbon-supported metal catalysts with high metal loading. Efficient Fenton reactivity is observed for samples containing well dispersed iron sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7841, "DOI": "10.1038/s41467-023-43678-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43678-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001111154200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, ZP; Liu, TY; Khan, AU; Liu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Zhengping; Liu, Tianyu; Khan, Assad U.; Liu, Guoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Block copolymer-based porous carbon fibers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon fibers have high surface areas and rich functionalities for interacting with ions, molecules, and particles. However, the control over their porosity remains challenging. Conventional syntheses rely on blending polyacrylonitrile with sacrificial additives, which macrophase-separate and result in poorly controlled pores after pyrolysis. Here, we use block copolymer microphase separation, a fundamentally disparate approach to synthesizing porous carbon fibers (PCFs) with well-controlled mesopores (similar to 10 nm) and micropores (similar to 0.5 nm). Without infiltrating any carbon precursors or dopants, poly(acrylonitrile-block-methyl methacrylate) is directly converted to nitrogen and oxygen dual-doped PCFs. Owing to the interconnected network and the highly optimal bimodal pores, PCFs exhibit substantially reduced ion transport resistance and an ultrahigh capacitance of 66 mu F cm(-2) (6.6 times that of activated carbon). The approach of using block copolymer precursors revolutionizes the synthesis of PCFs. The advanced electrochemical properties signify that PCFs represent a new platform material for electrochemical energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau6852", "DOI": "10.1126/sciadv.aau6852", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau6852", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ricciardulli, AG; Wang, Y; Yang, S; Samorì, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ricciardulli, Antonio Gaetano; Wang, Ye; Yang, Sheng; Samori, Paolo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Violet Phosphorus: A p-Type Semiconductor for (Opto)electronics", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of novel two-dimensional (2D) materials displaying an unprecedented composition and structure via the exfoliation of layered systems provides access to uncharted properties. For application in optoelectronics, a vast majority of exfoliated 2D semiconductors possess n-type or more seldom ambipolar characteristics. The shortage of p-type 2D semiconductors enormously hinders the extensive engineering of 2D devices for complementary metal oxide semiconductors (CMOSs) and beyond CMOS applications. However, despite the recent progress in the development of 2D materials endowed with p-type behaviors by direct synthesis or p-doping strategies, finding new structures is still of primary importance. Here, we report the sonication-assisted liquid-phase exfoliation of violet phosphorus VP crystals into few-layer-thick flakes and the first exploration of their electrical and optical properties. Field-effect transistors based on exfoliated VP thin films exhibit a p-type transport feature with an I-on/I-off ratio of 10(4) and a hole mobility of 2.25 cm(2) V-1 s(-1) at room temperature. In addition, the VP film-based photodetectors display a photoresponsivity (R) of 10 mA W-1 and a response time down to 0.16 s. Finally, VP embedded into CMOS inverter arrays displays a voltage gain of similar to 17. This scalable production method and high quality of the exfoliated material combined with the excellent optoelectronic performances make VP an enticing and versatile p-type candidate for next-generation more-than-Moore (opto)electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 144, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3660, "End Page": 3666, "Article Number": null, "DOI": "10.1021/jacs.1c12931", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c12931", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773646200038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hanbicki, AT; Currie, M; Kioseoglou, G; Friedman, AL; Jonker, BT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hanbicki, A. T.; Currie, M.; Kioseoglou, G.; Friedman, A. L.; Jonker, B. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Measurement of high exciton binding energy in the monolayer transition-metal dichalcogenides WS2 and WSe2", "Source Title": "SOLID STATE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer transition metal dichalcogenides are direct gap semiconductors with great promise for optoelectronic devices. Although spatial correlation of electrons and holes plays a key role, there is little experimental information on such fundamental properties as exciton binding energies and band gaps. We report here an experimental determination of exciton excited states and binding energies for monolayer WS2 and WSe2. We observe peaks in the optical reflectivity/absorption spectra Corresponding to the ground- and excited-state excitons (1s and 2s states). From these features, we determine lower bounds free of any model assumptions for the exciton binding energies as E-2s(A) - E-1s(A) of 0.83 eV and 0.79 eV for WS2 and WSe2, respectively, and for the corresponding band gaps E-g >= E-2s(A) 012.90 and 2.53 eV at 4 K. Because the binding energies are large, the true band gap is substantially higher than the dominullt spectral feature commonly observed with photoluminescence. This information is critical for emerging applications, and provides new insight into these novel monolayer semiconductors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 203, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16, "End Page": 20, "Article Number": null, "DOI": "10.1016/j.ssc.2014.11.005", "DOI Link": "http://dx.doi.org/10.1016/j.ssc.2014.11.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347035400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tammas-Williams, S; Zhao, H; Léonard, F; Derguti, F; Todd, I; Prangnell, PB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tammas-Williams, S.; Zhao, H.; Leonard, F.; Derguti, F.; Todd, I.; Prangnell, P. B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "XCT analysis of the influence of melt strategies on defect population in Ti-6Al-4V components manufactured by Selective Electron Beam Melting", "Source Title": "MATERIALS CHARACTERIZATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Selective Electron Beam Melting (SEBM) is a promising powder bed Additive Manufacturing technique for near-net-shape manufacture of high-value titanium components. However without post-manufacture HIPing the fatigue life of SEBM parts is currently dominated by the presence of porosity. In this study, the size, volume fraction, and spatial distribution of the pores in model samples have been characterised in 3D, using X-ray Computed Tomography, and correlated to the process variables. The average volume fraction of the pores (<0.2%) was measured to be lower than that usually observed in competing processes, such as selective laser melting, but a strong relationship was found with the different beam strategies used to contour, and infill by hatching, a part section. The majority of pores were found to be small spherical gas pores, concentrated in the infill hatched region; this was attributed to the lower energy density and less focused beam used in the infill strategy allowing less opportunity for gas bubbles to escape the melt pool. Overall, increasing the energy density or focus of the beam was found to correlate strongly to a reduction in the level of gas porosity. Rarer irregular shaped pores were mostly located in the contour region and have been attributed to a lack of fusion between powder particles. (C) 2015 The Authors. Published by Elsevier Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 513, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 102, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 47, "End Page": 61, "Article Number": null, "DOI": "10.1016/j.matchar.2015.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.matchar.2015.02.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355335200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JJ; Weng, GJ; Chen, SH; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianjun; Weng, G. J.; Chen, Shaohua; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On strain hardening mechanism in gradient nullostructures", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Experiments have shown that a gradient design, in which grain size spans over four orders of magnitude, can make strong nullomaterials ductile. The enhanced ductility is attributed to the considerable strain hardening capability obtained in the gradient metals. A non-uniform deformation on the lateral sample surface is also observed. This might inject geometrically necessary dislocations (GNDs) into the sample. However, no direct evidence has been provided. Therefore the issues remain: why can the gradient structure generate high strain hardening, and how does it reconcile the strength-ductility synergy of gradient nullostructures? Here for the first time we quantitatively investigate the strain hardening of a gradient interstitial-free steel by developing a dislocation density-based continuum plasticity model, in which the interaction of the component layers in the gradient structure is represented by incorporating GNDs and back stress. It is demonstrated that both the surface non-uniform deformation and the strain-hardening rate up-turn can be quantitatively well predicted. The results also show that the strain hardening rate of the gradient sample can reach as high as that of the coarse-grained counterpart. A strength-ductility map is then plotted, which clearly show that the gradient samples perform much more superior to their homogeneous counterparts in strength-ductility synergy. The predicted map has been verified by a series of experimental data. A detailed analysis on GNDs distribution and back stress evolution at the end further substantiates our view that the good strain hardening capability results from the generation of abundant GNDs by the surface non-uniform deformation into the nullo-grained layers of the gradient sample. (C) 2016 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 88, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 89, "End Page": 107, "Article Number": null, "DOI": "10.1016/j.ijplas.2016.10.003", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2016.10.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389105300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZJ; Wieder, BJ; Li, J; Yan, BH; Bernevig, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhijun; Wieder, Benjamin J.; Li, Jian; Yan, Binghai; Bernevig, B. Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-Order Topology, Monopole Nodal Lines, and the Origin of Large Fermi Arcs in Transition Metal Dichalcogenides XTe2 (X = Mo,W)", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, transition metal dichalcogenides (TMDs) have garnered great interest as topological materials. In particular, monolayers of centrosymmetric beta-phase TMDs have been identified as 2D topological insulators (TIs), and bulk crystals of noncentrosymmetric gamma-phase MoTe2 and WTe2 have been identified as type-II Weyl semimetals. However, angle-resolved photoemission spectroscopy and STM probes of these semimetals have revealed huge, arclike surface states that overwhelm, and are sometimes mistaken for, the much smaller topological surface Fermi arcs of bulk type-II Weyl points. In this Letter, we calculate the bulk and surface electronic structure of both beta- and gamma-MoTe2. We find that beta-MoTe2 is, in fact, a Z(4)-nontrivial higher-order TI (HOTI) driven by double band inversion and exhibits the same surface features as gamma-MoTe2 and gamma-WTe2. We discover that these surface states are not topologically trivial, as previously characterized by the research that differentiated them from the Weyl Fermi arcs but, rather, are the characteristic split and gapped fourfold Dirac surface states of a HOTI. In beta-MoTe2, this indicates that it would exhibit helical pairs of hinge states if it were bulk insulating, and in gamma-MoTe2 and gamma-WTe2, these surface states represent vestiges of HOTI phases without inversion symmetry that are nearby in parameter space. Using nested Wilson loops and first-principles calculations, we explicitly demonstrate that, when the Weyl points in gamma-MoTe2 are annihilated, which may be accomplished by symmetry-preserving strain or lattice distortion, gamma-MoTe2 becomes a nonsymmetry-indicated, noncentrosymmetric HOTI. We also show that, when the effects of spin-orbit coupling are neglected, beta-MoTe2 is a nodal-line semimetal with Z(2)-nontrivial monopole nodal lines (MNLSM). This finding confirms that MNLSMs driven by double band inversion are the weak-spin-orbit coupling limit of HOTIs, implying that MNLSMs are higher-order topological semimetals with flat-band-like hinge states, which we find to originate from the corner modes of 2D fragile TIs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2019, "Volume": 123, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 186401, "DOI": "10.1103/PhysRevLett.123.186401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.123.186401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492984300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, KTP; Liu, HL; Liu, YJ; Yang, JKW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Kevin T. P.; Liu, Hailong; Liu, Yejing; Yang, Joel K. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Holographic colour prints for enhanced optical security by combined phase and amplitude control", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional optical security devices provide authentication by manipulating a specific property of light to produce a distinctive optical signature. For instance, microscopic colour prints modulate the amplitude, whereas holograms typically modulate the phase of light. However, their relatively simple structure and behaviour is easily imitated. We designed a pixel that overlays a structural colour element onto a phase plate to control both the phase and amplitude of light, and arrayed these pixels into monolithic prints that exhibit complex behaviour. Our fabricated prints appear as colour images under white light, while projecting up to three different holograms under red, green, or blue laser illumination. These holographic colour prints are readily verified but challenging to emulate, and can provide enhanced security in anti-counterfeiting applications. As the prints encode information only in the surface relief of a single polymeric material, nulloscale 3D printing of customised masters may enable their mass-manufacture by nulloimprint lithography.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25, "DOI": "10.1038/s41467-018-07808-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07808-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Macknojia, A; Ayyagari, A; Zambrano, D; Rosenkranz, A; Shevchenko, E; Berman, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Macknojia, Ali; Ayyagari, Aditya; Zambrano, Dario; Rosenkranz, Andreas; Shevchenko, Elena, V; Berman, Diana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macroscale Superlubricity Induced by MXene/MoS2 nullocomposites on Rough Steel Surfaces under High Contact Stresses", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Toward the goal of achieving superlubricity, or near-zero friction, in industrially relevant material systems, solution-processed multilayer Ti3C2Tx-MoS2 blends are spray-coated onto rough 52100-grade steel surfaces as a solid lubricant. The tribological performance was assessed in a ball-on-disk configuration in a unidirectional sliding mode. The test results indicate that Ti3C2Tx-MoS2 nullocomposites led to superlubricious states, which has hitherto been unreported for both individual pristine materials, MoS2 and Ti3C2Tx, under macroscale sliding conditions, indicating a synergistic mechanism enabling the superlative performance. The processing, structure, and property correlation were studied to understand the underlying phenomena. Raman spectroscopy, scanning electron microscopy, and transmission electron microscopy revealed the formation of an in situ robust tribolayer that was responsible for the performance at high contact pressures (>1.1 GPa) and sliding speeds (0.1 m/s). This report presents the lowest friction obtained by either MoS2 or MXene or any combination of the two so far.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2023, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2421, "End Page": 2430, "Article Number": null, "DOI": "10.1021/acsnullo.2c09640", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.2c09640", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000925338300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Erans, M; Manovic, V; Anthony, EJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Erans, Maria; Manovic, Vasilije; Anthony, Edward J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Calcium looping sorbents for CO2 capture", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Calcium looping (CaL) is a promising technology for the decarbonation of power generation and carbon intensive (cement, lime and steel) industries. Although CaL has been extensively researched, some issues need to be addressed before deployment of this technology at commercial scale. One of the important challenges for CaL is decay of sorbent reactivity during capture/regeneration cycles. Numerous techniques have been explored to enhance natural sorbent performance, to create new synthetic sorbents, and to re-activate and re-use deactivated material. This review provides a critical analysis of natural and synthetic sorbents developed for use in CaL. Special attention is given to the suitability of modified materials for utilisation in fluidised-bed systems. Namely, besides requirements for a practical adsorption capacity, a mechanically strong material, resistant to attrition, is required for the fluidised bed CaL operating conditions. However, the main advantage of CaL is that it employs a widely available and inexpensive sorbent. Hence, a compromise must be made between improving the sorbent performance and increasing its cost, which means a relatively practical, scalable, and inexpensive method to enhance sorbent performance, should be found. This is often neglected when developing new materials focusing only on very high adsorption capacity. (C) 2016 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2016, "Volume": 180, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 722, "End Page": 742, "Article Number": null, "DOI": "10.1016/j.apenergy.2016.07.074", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2016.07.074", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383291900061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akselrod, GM; Deotare, PB; Thompson, NJ; Lee, J; Tisdale, WA; Baldo, MA; Menon, VM; Bulovic, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akselrod, Gleb M.; Deotare, Parag B.; Thompson, Nicholas J.; Lee, Jiye; Tisdale, William A.; Baldo, Marc A.; Menon, Vinod M.; Bulovic, Vladimir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization of exciton transport in ordered and disordered molecular solids", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transport of nulloscale energy in the form of excitons is at the core of photosynthesis and the operation of a wide range of nullostructured optoelectronic devices such as solar cells, light-emitting diodes and excitonic transistors. Of particular importance is the relationship between exciton transport and nulloscale disorder, the defining characteristic of molecular and nullostructured materials. Here we report a spatial, temporal and spectral visualization of exciton transport in molecular crystals and disordered thin films. Using tetracene as an archetype molecular crystal, the imaging reveals that exciton transport occurs by random walk diffusion, with a transition to subdiffusion as excitons become trapped. By controlling the morphology of the thin film, we show that this transition to subdiffusive transport occurs at earlier times as disorder is increased. Our findings demonstrate that the mechanism of exciton transport depends strongly on the nulloscale morphology, which has wide implications for the design of excitonic materials and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3646, "DOI": "10.1038/ncomms4646", "DOI Link": "http://dx.doi.org/10.1038/ncomms4646", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335221700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brûlé, S; Javelaud, EH; Enoch, S; Guenneau, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brule, S.; Javelaud, E. H.; Enoch, S.; Guenneau, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experiments on Seismic Metamaterials: Molding Surface Waves", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials engineered at the micro- and nullometer scales have had a tremendous and lasting impact in photonics and phononics. At much larger scales, natural soils civil engineered at decimeter to meter scales may interact with seismic waves when the global properties of the medium are modified, or alternatively thanks to a seismic metamaterial constituted of a mesh of vertical empty inclusions bored in the initial soil. Here, we show the experimental results of a seismic test carried out using seismic waves generated by a monochromatic vibrocompaction probe. Measurements of the particles' velocities show a modification of the seismic energy distribution in the presence of the metamaterial in agreement with numerical simulations using an approximate plate model. For complex natural materials such as soils, this large-scale experiment was needed to show the practical feasibility of seismic metamaterials and to stress their importance for applications in civil engineering. We anticipate this experiment to be a starting point for smart devices for anthropic and natural vibrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 529, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2014, "Volume": 112, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 133901, "DOI": "10.1103/PhysRevLett.112.133901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.133901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334336200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, JK; Xu, C; Lai, JW; Li, ZL; Zhang, YP; Liu, Y; Ding, K; Cai, YP; Shang, R; Zheng, QF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Junkai; Xu, Chao; Lai, Jiawei; Li, Zhongliang; Zhang, Yuping; Liu, Yan; Ding, Kui; Cai, Yue-Peng; Shang, Rui; Zheng, Qifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Amphiphilic Molecule-Regulated Core-Shell-Solvation Electrolyte for Li-Metal Batteries at Ultra-Low Temperature", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries hold great promise for promoting energy density and operating at low temperatures, yet they still suffer from insufficient Li compatibility and slow kinetic, especially at ultra-low temperatures. Herein, we rationally design and synthesize a new amphiphilic solvent, 1,1,2,2-tetrafluoro-3-methoxypropane, for use in battery electrolytes. The lithiophilic segment is readily to solvate Li+ to induce self-assembly of the electrolyte solution to form a peculiar core-shell-solvation structure. Such unique solvation structure not only largely improves the ionic conductivity to allow fast Li+ transport and lower the desolvation energy to enable facile desolvation, but also leads to the formation of a highly robust and conductive inorganic SEI. The resulting electrolyte demonstrates high Li efficiency and superior cycling stability from room temperature to -40 degrees C at high current densities. Meanwhile, anode-free high-voltage cell retains 87 % capacity after 100 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2023, "Volume": 62, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202218151", "DOI Link": "http://dx.doi.org/10.1002/anie.202218151", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939237000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, GJ; Liang, BC; Chen, A; Zhu, JX; Li, Q; Huang, ZD; Li, XL; Wang, Y; Wang, XQ; Xiong, B; Jin, X; Bai, SC; Fan, J; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Guojin; Liang, Bochun; Chen, Ao; Zhu, Jiaxiong; Li, Qing; Huang, Zhaodong; Li, Xinliang; Wang, Ying; Wang, Xiaoqi; Xiong, Bo; Jin, Xu; Bai, Shengchi; Fan, Jun; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of rechargeable high-energy hybrid zinc-iodine aqueous batteries exploiting reversible chlorine-based redox reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The chlorine-based redox reaction (ClRR) could be exploited to produce secondary high-energy aqueous batteries. However, efficient and reversible ClRR is challenging, and it is affected by parasitic reactions such as Cl-2 gas evolution and electrolyte decomposition. Here, to circumvent these issues, we use iodine as positive electrode active material in a battery system comprising a Zn metal negative electrode and a concentrated (e.g., 30 molal) ZnCl2 aqueous electrolyte solution. During cell discharge, the iodine at the positive electrode interacts with the chloride ions from the electrolyte to enable interhalogen coordinating chemistry and forming ICl3-. In this way, the redox-active halogen atoms allow a reversible three-electrons transfer reaction which, at the lab-scale cell level, translates into an initial specific discharge capacity of 612.5 mAh g(I2)(-1) at 0.5 A g(I2)(-1) and 25 degrees C (corresponding to a calculated specific energy of 905 Wh kg(I2)(-1)). We also report the assembly and testing of a Zn | |Cl-I pouch cell prototype demonstrating a discharge capacity retention of about 74% after 300 cycles at 200 mA and 25 degrees C (final discharge capacity of about 92 mAh). Cl-redox reactions cannot be fully exploited in batteries because of the Cl2 gas evolution. Here, reversible high-energy interhalogen reactions are demonstrated by using a iodine-based cathode in combination with a Zn anode and a Cl-containing aqueous electrolyte solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-37565-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37565-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002031500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SJ; Oh, HS; Gludovatz, B; Kim, SJ; Park, ES; Zhang, Z; Ritchie, RO; Yu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Sijing; Oh, Hyun Seok; Gludovatz, Bernd; Kim, Sang Jun; Park, Eun Soo; Zhang, Ze; Ritchie, Robert O.; Yu, Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Real-time observations of TRIP-induced ultrahigh strain hardening in a dual-phase CrMnFeCoNi high-entropy alloy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strategies involving metastable phases have been the basis of the design of numerous alloys, yet research on metastable high-entropy alloys is still in its infancy. In dual-phase high-entropy alloys, the combination of local chemical environments and loading-induced crystal structure changes suggests a relationship between deformation mechanisms and chemical atomic distribution, which we examine in here in a Cantor-like Cr20Mn6Fe34Co34Ni6 alloy, comprising both face-centered cubic (fcc) and hexagonal closed packed (hcp) phases. We observe that partial dislocation activities result in stable three-dimensional stacking-fault networks. Additionally, the fraction of the stronger hcp phase progressively increases during plastic deformation by forming at the stacking-fault network boundaries in the fcc phase, serving as the major source of strain hardening. In this context, variations in local chemical composition promote a high density of Lomer-Cottrell locks, which facilitate the construction of the stacking-fault networks to provide nucleation sites for the hcp phase transformation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 826, "DOI": "10.1038/s41467-020-14641-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14641-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514433900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YJ; Xu, LX; Li, JH; Li, YW; Zhang, CF; Li, H; Wu, Y; Liang, AJ; Chen, C; Jung, SW; Cacho, C; Wang, HY; Mao, YH; Liu, S; Wang, MX; Guo, YF; Xu, Y; Liu, ZK; Yang, LX; Chen, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Y. J.; Xu, L. X.; Li, J. H.; Li, Y. W.; Zhang, C. F.; Li, H.; Wu, Y.; Liang, A. J.; Chen, C.; Jung, S. W.; Cacho, C.; Wang, H. Y.; Mao, Y. H.; Liu, S.; Wang, M. X.; Guo, Y. F.; Xu, Y.; Liu, Z. K.; Yang, L. X.; Chen, Y. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Electronic Structure and Its Temperature Evolution in Antiferromagnetic Topological Insulator MnBi2Te4", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The intrinsic magnetic topological insulator MnBi2Te4 exhibits rich topological effects such as quantum anomalous Hall effect and axion electrodynamics. Here, by combining the use of synchrotron and laser light sources, we carry out comprehensive and high-resolution angle-resolved photoemission spectroscopy studies on MnBi2Te4 and clearly identify its topological electronic structure. In contrast to theoretical predictions and previous studies, we observe topological surface states with diminished gap forming a characteristic Dirac cone. We argue that the topological surface states are mediated by multidomains of different magnetization orientations. In addition, the temperature evolution of the energy bands clearly reveals their interplay with the magnetic phase transition by showing interesting differences between the bulk and surface states, respectively. The investigation of the detailed electronic structure of MnBi2Te4 and its temperature evolution provides important insight into not only the exotic properties of MnBi2Te4, but also the generic understanding of the interplay between magnetism and topological electronic structure in magnetic topological quantum materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2019, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41040, "DOI": "10.1103/PhysRevX.9.041040", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.9.041040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498062600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Zhu, YJ; Xu, WH; Wang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yao; Zhu, Yujie; Xu, Wenhan; Wang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular Trap Engineering Enables Superior High-Temperature Capacitive Energy Storage Performance in All-Organic Composite at 200 °C", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors are essential components of advanced high-power electrical and electronic systems for electrical energy storage. The drastic reductions in the energy density and the charge-discharge efficiency of dielectric polymers at elevated temperatures, owing to sharply increased electrical conduction, remain a major challenge. While substantial progress has been made in enhancing the high-temperature capacitive performance of dielectric polymers, the improvement has been rather limited when the temperature exceeds 150 degrees C. Here, a universal approach to the control of the energy level of charge traps in all-organic polymer composites by substituent engineering of organic semiconductors, leading to significantly suppressed high-field high-temperature conduction loss and improved capacitive performance is reported. At 200 degrees C, the polymer/organic semiconductor composite delivers ultrahigh energy densities of 3.4 and 5.0 J cm(-3) with an efficiency >90% at 10 and 100 Hz, respectively, outperforming the current dielectric polymers and composites. The underlying mechanism of the improved performance is revealed experimentally and confirmed computationally. Moreover, excellent cyclability and the ability to be fabricated into large-area high-quality films with uniform performance, along with an ultralow filler loading, further demonstrate the potential of molecularly engineered organic semiconductors for dielectric polymer composites operating under extreme conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 13, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202203961", "DOI Link": "http://dx.doi.org/10.1002/aenm.202203961", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000920370600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, S; Sokolov, A; Lavrentovich, OD; Aranson, IS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Shuang; Sokolov, Andrey; Lavrentovich, Oleg D.; Aranson, Igor S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Living liquid crystals", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Collective motion of self-propelled organisms or synthetic particles, often termed active fluid, has attracted enormous attention in the broad scientific community because of its fundamentally nonequilibrium nature. Energy input and interactions among the moving units and the medium lead to complex dynamics. Here, we introduce a class of active matter-living liquid crystals (LLCs)-that combines living swimming bacteria with a lyotropic liquid crystal. The physical properties of LLCs can be controlled by the amount of oxygen available to bacteria, by concentration of ingredients, or by temperature. Our studies reveal a wealth of intriguing dynamic phenomena, caused by the coupling between the activity-triggered flow and long-range orientational order of the medium. Among these are (i) nonlinear trajectories of bacterial motion guided by nonuniform director, (ii) local melting of the liquid crystal caused by the bacteria-produced shear flows, (iii) activity-triggered transition from a nonflowing uniform state into a flowing one-dimensional periodic pattern and its evolution into a turbulent array of topological defects, and (iv) birefringenceenabled visualization of microflow generated by the nullometersthick bacterial flagella. Unlike their isotropic counterpart, the LLCs show collective dynamic effects at very low volume fraction of bacteria, on the order of 0.2%. Our work suggests an unorthodox design concept to control and manipulate the dynamic behavior of soft active matter and opens the door for potential biosensing and biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2014, "Volume": 111, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1265, "End Page": 1270, "Article Number": null, "DOI": "10.1073/pnas.1321926111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1321926111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330231100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, BX; Pu, HB; Sun, DW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Bingxue; Pu, Hongbin; Sun, Da-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional cellulose based substrates for SERS smart sensing: Principles, applications and emerging trends for food safety detection", "Source Title": "TRENDS IN FOOD SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Food safety issues leading to severe healthy, economic and even social problems and detection of food contaminullts has been attracting remarkable attention in recent decades. Surface-enhanced Raman scattering (SERS) is one of the most promising techniques to enable detecting contaminullts at trace levels. Besides, with the emergence of global resource shortages and environmental problems, there is a growing demand for environmentally friendly and renewable resources. As a sustainable and biodegradable raw material, cellulose has aroused great interest and stimulated researchers to develop cellulose-based SERS substrates with novel functions. Scope and approach: The review focuses on the utilizing of cellulosic materials for the design and preparation of various SERS substrates, including cellulose-papers, cellulose fabrics (CFs) and membranes, cellulose nullofibrils (CNFs), bacterial cellulose (BC), nullocrystalline cellulose (NCC), and surface-modified cellulose. The applications, challenges and potential solutions of these cellulose-based substrates in food safety detection are also presented, proposed and evaluated. Key findings and conclusions: For the complexity and diversity of multitudinous food systems, multiple approaches have been successfully employed to manufacture cellulose-based SERS substrates. Various types of cellulose with diverse morphology and mechanical properties make them customizable and integratable with multiple technologies in certain realistic applications. The explorations of SERS detections displaying excellent performances especially for the complex system/surface analysis with the capability of extraction, swabbing, transferring and concentrating target molecules from complexing food systems. The widespread application and prominent performance demonstrating the huge potential for cellulose-based materials to realize commercially viable, sustainable, flexible and green substrates in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 304, "End Page": 320, "Article Number": null, "DOI": "10.1016/j.tifs.2021.02.005", "DOI Link": "http://dx.doi.org/10.1016/j.tifs.2021.02.005", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632793700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, Y; Song, YP; Sun, GT; Hu, PF; Bednarkiewicz, A; Sun, LN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yao; Song, Yapai; Sun, Guotao; Hu, Pengfei; Bednarkiewicz, Artur; Sun, Lining", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lanthanide-doped heterostructured nullocomposites toward advanced optical anti-counterfeiting and information storage", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The continuously growing importance of information storage, transmission, and authentication impose many new demands and challenges for modern nullo-photonic materials and information storage technologies, both in security and storage capacity. Recently, luminescent lanthanide-doped nullomaterials have drawn much attention in this field because of their photostability, multimodal/multicolor/narrowband emissions, and long luminescence lifetime. Here, we report a multimodal nullocomposite composed of lanthanide-doped upconverting nulloparticle and EuSe semiconductor, which was constructed by utilizing a cation exchange strategy. The nullocomposite can emit blue and white light under 365 and 394 nm excitation, respectively. Meanwhile, the nullocomposites show different colors under 980 nm laser excitation when the content of Tb3+ ions is changed in the upconversion nulloparticles. Moreover, the time-gating technology is used to filter the upconversion emission of a long lifetime from Tb3+ or Eu3+, and the possibilities for modulating the emission color of the nullocomposites are further expanded. Based on the advantage of multiple tunable luminescence, the nullocomposites are designed as optical modules to load optical information. This work enables multi-dimensional storage of information and provides new insights into the design and fabrication of next-generation storage materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 150, "DOI": "10.1038/s41377-022-00813-9", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00813-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798187100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schoop, LM; Ali, MN; Strasser, C; Topp, A; Varykhalov, A; Marchenko, D; Duppel, V; Parkin, SSP; Lotsch, BV; Ast, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schoop, Leslie M.; Ali, Mazhar N.; Strasser, Carola; Topp, Andreas; Varykhalov, Andrei; Marchenko, Dmitry; Duppel, Viola; Parkin, Stuart S. P.; Lotsch, Bettina V.; Ast, Christian R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac cone protected by non-symmorphic symmetry and three-dimensional Dirac line node in ZrSiS", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials harbouring exotic quasiparticles, such as massless Dirac and Weyl fermions, have garnered much attention from physics and material science communities due to their exceptional physical properties such as ultra-high mobility and extremely large magnetoresistances. Here, we show that the highly stable, non-toxic and earth-abundant material, ZrSiS, has an electronic band structure that hosts several Dirac cones that form a Fermi surface with a diamond-shaped line of Dirac nodes. We also show that the square Si lattice in ZrSiS is an excellent template for realizing new types of two-dimensional Dirac cones recently predicted by Young and Kane. Finally, we find that the energy range of the linearly dispersed bands is as high as 2 eV above and below the Fermi level; much larger than of other known Dirac materials. This makes ZrSiS a very promising candidate to study Dirac electrons, as well as the properties of lines of Dirac nodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 624, "Times Cited, All Databases": 653, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11696, "DOI": "10.1038/ncomms11696", "DOI Link": "http://dx.doi.org/10.1038/ncomms11696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376823900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, T; Ning, LX; Gao, Y; Qiao, JW; Song, EH; Chen, ZT; Zhou, YY; Wang, J; Molokeev, MS; Ke, XX; Xia, ZG; Zhang, QY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Tao; Ning, Lixin; Gao, Yan; Qiao, Jianwei; Song, Enhai; Chen, Zitao; Zhou, Yayun; Wang, Jing; Molokeev, Maxim S.; Ke, Xiaoxing; Xia, Zhiguo; Zhang, Qinyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Glass crystallization making red phosphor for high-power warm white lighting", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid development of solid-state lighting technology requires new materials with highly efficient and stable luminescence, and especially relies on blue light pumped red phosphors for improved light quality. Herein, we discovered an unprecedented red-emitting Mg2Al4Si5O18:Eu2+ composite phosphor (lambda(ex) = 450 nm, lambda(em) = 620 nm) via the crystallization of MgO-Al2O3-SiO2 aluminosilicate glass. Combined experimental measurement and first-principles calculations verify that Eu2+ dopants insert at the vacant channel of Mg2Al4Si5O18 crystal with six-fold coordination responsible for the peculiar red emission. Importantly, the resulting phosphor exhibits high internal/external quantum efficiency of 94.5/70.6%, and stable emission against thermal quenching, which reaches industry production. The maximum luminous flux and luminous efficiency of the constructed laser driven red emitting device reaches as high as 274 lm and 54 lm W-1, respectively. The combinations of extraordinary optical properties coupled with economically favorable and innovative preparation method indicate, that the Mg2Al4Si5O18:Eu2+ composite phosphor will provide a significant step towards the development of high-power solid-state lighting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 56, "DOI": "10.1038/s41377-021-00498-6", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00498-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628218800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nian, QS; Zhang, XR; Feng, YZ; Liu, S; Sun, TJ; Zheng, SB; Ren, XD; Tao, ZL; Zhang, DH; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nian, Qingshun; Zhang, Xiaoren; Feng, Yazhi; Liu, Shuang; Sun, Tianjiang; Zheng, Shibing; Ren, Xiaodi; Tao, Zhanliang; Zhang, Donghui; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Electrolyte Structure to Suppress Hydrogen Evolution Reaction in Aqueous Batteries", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous batteries (ABs) have attracted increasing attention because of their inherent safety and low cost. Nevertheless, hydrogen evolution reaction (HER) at the anode presents severe challenges for stable and safe operation of ABs. Instead of passivating the anode surface to hinder HER kinetics, a design strategy is proposed here to suppress the HER via alternating its thermodynamics pathway. Addition of a hydrogen bond acceptor, dimethyl sulfoxide (DMSO) can delay the onset potential of HER by as much as 1.0 V (on titanium mesh). Spectral characterization and molecular dynamics simulation confirm that the formation of hydrogen bonds between DMSO and water molecules can reduce the water activity, thereby suppressing the HER. This strategy has proven to be universal in expanding the electrochemical window of aqueous electrolytes. For instance, unconventional V2- <-> V3+ redox processes in Na3V2(PO4)(3) (-1.2 V versus Ag/AgCl) can be realized in ABs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2174, "End Page": 2180, "Article Number": null, "DOI": "10.1021/acsenergylett.1c00833", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.1c00833", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662227100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, ZL; Li, HY; Li, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Zhiliang; Li, Hongying; Li, Junke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient photocatalytic hydrogen evolution over graphdiyne boosted with a cobalt sulfide formed S-scheme heterojunction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphdiyne (GDY, g-CnH2n-2), a novel two-dimensional carbon hybrid material, has attracted significant attention owing to its unique and excellent properties. As a new type of carbon material, GDY has a layered structure and can be used in the field of photocatalytic water splitting. Therefore, herein, new progress in the preparation of graphene using CuI powder as a catalytic material and the combination of a facile hydrothermal method to prepare a new composite material, Co9S8-GDY-CuI, is reported. The hydrogen production activity of Co9S8-GDY-CuI in the sensitization system reached 1411.82 mu mol g(-1) h(-1), which is 10.29 times that of pure GDY. A series of characterization techniques were used to provide evidence for the successful preparation of the material and its superior photocatalytic activity. Raman spectroscopy showed that the material contains acetylenic bonds, and the X-ray photoelectron spectroscopy carbon fitting peaks indicated the presence of C-C(sp(2)) and C-C(sp), further demonstrating that GDY was successfully prepared. A possible reaction mechanism was proposed by making use of UV-visible diffuse reflectance and Mott-Schottky analyses. The results showed that a double S-scheme heterojunction was constructed between the samples, which effectively accelerated the separation and transfer of electrons. In addition, the introduction of Co9S8 nulloparticles greatly improved the visible light absorption capacity of Co9S8-GDY-CuI. Photoluminescence spectroscopy and related electrochemical characterization further proved that recombination of the electron-hole pairs in the composite material was effectively suppressed. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 303, "End Page": 315, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63818-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63818-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vybornyi, O; Yakunin, S; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vybornyi, Oleh; Yakunin, Sergii; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polar-solvent-free colloidal synthesis of highly luminescent alkylammonium lead halide perovskite nullocrystals", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel synthesis of hybrid organic-inorganic lead halide perovskite nullocrystals (CH3NH3PbX3, X = Br or I) that does not involve the use of dimethylformamide or other polar solvents is presented. The reaction between methylamine and PbX2 salts is conducted in a high-boiling nonpolar solvent (1-octadecene) in the presence of oleylamine and oleic acid as coordinating ligands. The resulting nullocrystals are characterized by high photoluminescence quantum efficiencies of 15-50%, outstanding phase purity and tunable shapes (nullocubes, nullowires, and nulloplatelets). nulloplatelets spontaneously assemble into micrometer-length wires by face-to-face stacking. In addition, we demonstrate amplified spontaneous emission from thin films of green-emitting CH3NH3PbBr3 nullowires with low pumping thresholds of 3 mu J cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6278, "End Page": 6283, "Article Number": null, "DOI": "10.1039/c5nr06890h", "DOI Link": "http://dx.doi.org/10.1039/c5nr06890h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372851500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Autore, M; Li, PN; Dolado, I; Alfaro-Mozaz, FJ; Esteban, R; Atxabal, A; Casanova, F; Hueso, LE; Alonso-González, P; Aizpurua, J; Nikitin, AY; Vélez, S; Hillenbrand, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Autore, Marta; Li, Peining; Dolado, Irene; Alfaro-Mozaz, Francisco J.; Esteban, Ruben; Atxabal, Ainhoa; Casanova, Felix; Hueso, Luis E.; Alonso-Gonzalez, Pablo; Aizpurua, Javier; Nikitin, Alexey Y.; Velez, Saul; Hillenbrand, Rainer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron nitride nulloresonators for phonon-enhanced molecular vibrational spectroscopy at the strong coupling limit", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhanced light-matter interactions are the basis of surface-enhanced infrared absorption (SEIRA) spectroscopy, and conventionally rely on plasmonic materials and their capability to focus light to nulloscale spot sizes. Phonon polariton nulloresonators made of polar crystals could represent an interesting alternative, since they exhibit large quality factors, which go far beyond those of their plasmonic counterparts. The recent emergence of van der Waals crystals enables the fabrication of high-quality nullophotonic resonators based on phonon polaritons, as reported for the prototypical infrared-phononic material hexagonal boron nitride (h-BN). In this work we use, for the first time, phonon-polariton-resonullt h-BN ribbons for SEIRA spectroscopy of small amounts of organic molecules in Fourier transform infrared spectroscopy. Strikingly, the interaction between phonon polaritons and molecular vibrations reaches experimentally the onset of the strong coupling regime, while numerical simulations predict that vibrational strong coupling can be fully achieved. Phonon polariton nulloresonators thus could become a viable platform for sensing, local control of chemical reactivity and infrared quantum cavity optics experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2018, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17172, "DOI": "10.1038/lsa.2017.172", "DOI Link": "http://dx.doi.org/10.1038/lsa.2017.172", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430146000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, C; Zhu, K; de Freitas, SC; Chang, JY; Davies, JE; Eames, P; Freitas, PP; Kazakova, O; Kim, C; Leung, CW; Liou, SH; Ognev, A; Piramanayagam, SN; Ripka, P; Samardak, A; Shin, KH; Tong, SY; Tung, MJ; Wang, SX; Xue, SS; Yin, XL; Pong, PWT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Chao; Zhu, Ke; de Freitas, Susana Cardoso; Chang, Jen-Yuan; Davies, Joseph E.; Eames, Peter; Freitas, Paulo P.; Kazakova, Olga; Kim, CheolGi; Leung, Chi-Wah; Liou, Sy-Hwang; Ognev, Alexey; Piramanayagam, S. N.; Ripka, Pavel; Samardak, Alexander; Shin, Kwang-Ho; Tong, Shi-Yuan; Tung, Mean-Jue; Wang, Shan X.; Xue, Songsheng; Yin, Xiaolu; Pong, Philip W. T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetoresistive Sensor Development Roadmap (Non-Recording Applications)", "Source Title": "IEEE TRANSACTIONS ON MAGNETICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetoresistive (MR) sensors have been identified as promising candidates for the development of high-performance magnetometers due to their high sensitivity, low cost, low power consumption, and small size. The rapid advance of MR sensor technology has opened up a variety of MR sensor applications. These applications are in different areas that require MR sensors with different properties. Future MR sensor development in each of these areas requires an overview and a strategic guide. An MR sensor roadmap (non-recording applications) was therefore developed and made public by the Technical Committee of the IEEE Magnetics Society with the aim to provide an research and development (R&D) guide for MR sensors intended to be used by industry, government, and academia. The roadmap was developed over a three-year period and coordinated by an international effort of 22 taskforce members from ten countries and 17 organizations, including universities, research institutes, and sensor companies. In this paper, the current status of MR sensors for non-recording applications was identified by analyzing the patent and publication statistics. As a result, timescales for MR sensor development were established and critical milestones for sensor parameters were extracted in order to gain insight into potential MR sensor applications (non-recording). Five application areas were identified, and five MR sensor roadmaps were established. These include biomedical applications, flexible electronics, position sensing and human-computer interactions, non-destructive evaluation and monitoring, and navigation and transportation. Each roadmap was analyzed using a logistic growth model, and new opportunities were predicted based on the extrapolated curve, forecast milestones, and professional judgment of the taskforce members. This paper provides a framework for MR sensor technology (non-recording applications) to be used for public and private R&D planning, in order to provide guidance into likely MR sensor applications, products, and services expected in the next 15 years and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 55, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 800130, "DOI": "10.1109/TMAG.2019.2896036", "DOI Link": "http://dx.doi.org/10.1109/TMAG.2019.2896036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461841100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lampel, A; McPhee, SA; Park, HA; Scott, GG; Humagain, S; Hekstra, DR; Yoo, B; Frederix, PWJM; Li, TD; Abzalimov, RR; Greenbaum, SG; Tuttle, T; Hu, CH; Bettinger, CJ; Ulijn, RV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lampel, Ayala; McPhee, Scott A.; Park, Hang-Ah; Scott, Gary G.; Humagain, Sunita; Hekstra, Doeke R.; Yoo, Barney; Frederix, Pim W. J. M.; Li, Tai-De; Abzalimov, Rinat R.; Greenbaum, Steven G.; Tuttle, Tell; Hu, Chunhua; Bettinger, Christopher J.; Ulijn, Rein V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymeric peptide pigments with sequence-encoded properties", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Melanins are a family of heterogeneous polymeric pigments that provide ultraviolet (UV) light protection, structural support, coloration, and free radical scavenging. Formed by oxidative oligomerization of catecholic small molecules, the physical properties of melanins are influenced by covalent and noncovalent disorder. We report the use of tyrosine-containing tripeptides as tunable precursors for polymeric pigments. In these structures, phenols are presented in a (supra-)molecular context dictated by the positions of the amino acids in the peptide sequence. Oxidative polymerization can be tuned in a sequence-dependent manner, resulting in peptide sequence-encoded properties such as UV absorbance, morphology, coloration, and electrochemical properties over a considerable range. Short peptides have low barriers to application and can be easily scaled, suggesting near-term applications in cosmetics and biomedicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2017, "Volume": 356, "Issue": 6342, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1064, "End Page": 1068, "Article Number": null, "DOI": "10.1126/science.aal5005", "DOI Link": "http://dx.doi.org/10.1126/science.aal5005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402871700051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Besteiro, LV; Kong, XT; Wang, ZM; Hartland, G; Govorov, AO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Besteiro, Lucas V.; Kong, Xiang-Tian; Wang, Zhiming; Hartland, Gregory; Govorov, Alexander O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Hot-Electron Generation and Plasmon Relaxation in Metal nullocrystals: Quantum and Classical Mechanisms", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Generation of energetic (hot) electrons is an intrinsic property of any plasmonic nullostructure under illumination. Simultaneously, a striking advantage of metal nullocrystals over semiconductors lies in their very large absorption cross sections. Therefore, metal nullostructures with strong and tailored plasmonic resonullces are very attractive for photocatalytic applications in which excited electrons play an important role. However, the central questions in the problem of plasmonic hot electrons are the number of optically excited energetic electrons in a nullocrystal and how to extract such electrons. Here we develop a theory describing the generation rates and the energy distributions of hot electrons in nullocrystals with various geometries. In our theory, hot electrons are generated due to surfaces and hot spots. As expected, the formalism predicts that large optically excited nullocrystals show the excitation of mostly low energy Drude electrons, whereakplasmons in small nullocrystals involve mostly high-energy (hot) electrons. We obtain analytical expressions for the distribution functions of excited carriers for simple shapes. For complex shapes with hot spots and for small quantum nullocrystals, our results are computational. By looking at the energy distributions of electrons in an optically excited nullocrystal, we see how the quantum many-body state in small particles evolves toward the classical state described by the Drude model when increasing nullocrystal size. We show that the rate of surface decay of plasmons in nullocrystals is directly related to the rate of generation of hot electrons. On the basis of a detailed many-body theory involving kinetic coefficients, we formulate a simple scheme describing how the plasmon in a nullocrystal dephases over time. In most nullocrystals, the main decay mechanisms of a plasmon are the Drude friction-like process and the interband electron hole excitation, and the secondary path comes from generation of hot electrons due to surfaces and electromagnetic hot spots. The hot-electron path strongly depends on the material system and on its shape. Correspondingly, the efficiency of hot-electron production in a nullocrystal strongly varies with size, shape, and material. The results in the paper can be used to guide the design of plasmonic nullomaterials for photochemistry and photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2759, "End Page": 2781, "Article Number": null, "DOI": "10.1021/acsphotonics.7b00751", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.7b00751", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415786300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Snitkoff-Sol, RZ; Friedman, A; Honig, HC; Yurko, Y; Kozhushner, A; Zachman, MJ; Zelenay, P; Bond, AM; Elbaz, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Snitkoff-Sol, Rifael Z.; Friedman, Ariel; Honig, Hilah C.; Yurko, Yan; Kozhushner, Alisa; Zachman, Michael J.; Zelenay, Piotr; Bond, Alan M.; Elbaz, Lior", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying the electrochemical active site density of precious metal-free catalysts in situ in fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advances in the development of precious-group metal-free (PGM-free) catalysts for the oxygen reduction reaction (ORR) in fuel cell cathodes have produced active catalysts that reduce the performance gap to the incumbent Pt-based materials. However, utilization of state-of-the-art PGM-free catalysts for commercial applications is currently impeded by their relatively low durability. Methods designed to study catalyst degradation in the operation of fuel cells are therefore critical for understanding durability issues and, ultimately, their solutions. Here we report the use of Fourier-transform alternating current voltammetry as an electrochemical method for accurate quantification of the electrochemically active site density of PGM-free cathode catalysts, and to follow their degradation in situ during the operation of polymer electrolyte fuel cells. Using this method, we were able to quantify the electrochemical active site density, which will enable the elucidation of degradation mechanisms of PGM-free ORR catalysts in situ in fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 163, "End Page": 170, "Article Number": null, "DOI": "10.1038/s41929-022-00748-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00748-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000761965400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Tao, L; He, JL; McCutcheon, JR; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jason; Tao, Lei; He, Jinlong; McCutcheon, Jeffrey R.; Li, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning enables interpretable discovery of innovative polymers for gas separation membranes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer membranes perform innumerable separations with far-reaching environmental implications. Despite decades of research, design of new membrane materials remains a largely Edisonian process. To address this shortcoming, we demonstrate a generalizable, accurate machine learning (ML) implementation for the discovery of innovative polymers with ideal performance. Specifically, multitask ML models are trained on experimental data to link polymer chemistry to gas permeabilities of He, H-2, O-2, N-2, CO2, and CH4. We interpret the ML models and extract valuable insights into the contributions of different chemical moieties to permeability and selectivity. We then screen over 9 million hypothetical polymers and identify thousands that lie well above current performance upper bounds, including hundreds of never-before-seen ultrapermeable polymer membranes with O-2 and CO2 permeability greater than 10(4) and 10(5) Barrers, respectively. High-fidelity molecular dynamics simulations confirm the ML-predicted gas permeabilities of the promising candidates, which suggests that many can be translated to reality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2022, "Volume": 8, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabn9545", "DOI": "10.1126/sciadv.abn9545", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abn9545", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828233900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Warby, J; Zu, FS; Zeiske, S; Gutierrez-Partida, E; Frohloff, L; Kahmann, S; Frohna, K; Mosconi, E; Radicchi, E; Lang, F; Shah, S; Pena-Camargo, F; Hempel, H; Unold, T; Koch, N; Armin, A; De Angelis, F; Stranks, SD; Neher, D; Stolterfoht, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Warby, Jonathan; Zu, Fengshuo; Zeiske, Stefan; Gutierrez-Partida, Emilio; Frohloff, Lennart; Kahmann, Simon; Frohna, Kyle; Mosconi, Edoardo; Radicchi, Eros; Lang, Felix; Shah, Sahil; Pena-Camargo, Francisco; Hempel, Hannes; Unold, Thomas; Koch, Norbert; Armin, Ardalan; De Angelis, Filippo; Stranks, Samuel D.; Neher, Dieter; Stolterfoht, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Performance Limiting Interfacial Recombination in pin Perovskite Solar Cells", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite semiconductors are an attractive option to overcome the limitations of established silicon based photovoltaic (PV) technologies due to their exceptional opto-electronic properties and their successful integration into multijunction cells. However, the performance of single- and multijunction cells is largely limited by significant nonradiative recombination at the perovskite/organic electron transport layer junctions. In this work, the cause of interfacial recombination at the perovskite/C-60 interface is revealed via a combination of photoluminescence, photoelectron spectroscopy, and first-principle numerical simulations. It is found that the most significant contribution to the total C-60-induced recombination loss occurs within the first monolayer of C-60, rather than in the bulk of C-60 or at the perovskite surface. The experiments show that the C-60 molecules act as deep trap states when in direct contact with the perovskite. It is further demonstrated that by reducing the surface coverage of C-60, the radiative efficiency of the bare perovskite layer can be retained. The findings of this work pave the way toward overcoming one of the most critical remaining performance losses in perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2103567, "DOI": "10.1002/aenm.202103567", "DOI Link": "http://dx.doi.org/10.1002/aenm.202103567", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753274300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cusenza, MA; Bobba, S; Ardente, F; Cellura, M; Di Persio, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cusenza, Maria Anna; Bobba, Silvia; Ardente, Fulvio; Cellura, Maurizio; Di Persio, Franco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy and environmental assessment of a traction lithium-ion battery pack for plug-in hybrid electric vehicles", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traction batteries are a key factor in the environmental sustainability of electric mobility and, therefore, it is necessary to evaluate their environmental performance to allow a comprehensive sustainability assessment of electric mobility. This article presents an environmental assessment of a lithium-ion traction battery for plug-in hybrid electric vehicles, characterized by a composite cathode material of lithium manganese oxide (LiMn2O4) and lithium nickel manganese cobalt oxide Li(NixCoyMn1-x-y)O-2. Composite cathode material is an emerging technology that promises to combine the merits of several active materials into a hybrid electrode to optimize performance and reduce costs. In this study, the environmental assessment of one battery pack (with a nominal capacity of 11.4 kWh able to be used for about 140,000 km of driving) is carried out by using the Life Cycle Assessment methodology consistent with ISO 14040. The system boundaries are the battery production, the operation phase and recycling at the end of life, including the recovery of various material fractions. The composite cathode technology examined besides a good compromise between the higher and the lower performance of NMC and LMO cathodes, can present good environmental performances. The results of the analysis show that the manufacturing phase is relevant to all assessed impact categories (contribution higher than 60%). With regard to electricity losses due to battery efficiency and battery transport, the contribution to the use phase impact of battery efficiency is larger than that of battery transport. Recycling the battery pack contributes less than 11% to all of the assessed impact categories, with the exception of freshwater ecotoxicity (60% of the life cycle impact). The environmental credits related to the recovery of valuable materials (e.g. cobalt and nickel sulphates) and other metal fractions (e.g. aluminium and steel) are particularly relevant to impact categories such as marine eutrophication, human toxicity and abiotic resource depletion. The main innovations of this article are that (1) it presents the first bill of materials of a lithium-ion battery cell for plug-in hybrid electric vehicles with a composite cathode active material; (2) it describes one of the first applications of the life cycle assessment to a lithium-ion battery pack for plug-in hybrid electric vehicles with a composite cathode active material with the aim of identifying the hot spots of this technology and providing useful information to battery manufacturers on potentially improving its environmental sustainability; (3) it evaluates the impacts associated with the use phase based on primary data about the battery pack's lifetime, in terms of kilometres driven; and (4) it models the end-of-life phase of the battery components through processes specifically created for or adapted to the case study. (C) 2019 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2019, "Volume": 215, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 634, "End Page": 649, "Article Number": null, "DOI": "10.1016/j.jclepro.2019.01.056", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2019.01.056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459358300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MZ; Liu, MX; She, LM; Zha, ZQ; Pan, JL; Li, SC; Li, T; He, YY; Cai, ZY; Wang, JB; Zheng, Y; Qiu, XH; Zhong, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Meizhuang; Liu, Mengxi; She, Limin; Zha, Zeqi; Pan, Jinliang; Li, Shichao; Li, Tao; He, Yangyong; Cai, Zeying; Wang, Jiaobing; Zheng, Yue; Qiu, Xiaohui; Zhong, Dingyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene-like nulloribbons periodically embedded with four- and eight-membered rings", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Embedding non-hexagonal rings into sp(2)-hybridized carbon networks is considered a promising strategy to enrich the family of low-dimensional graphenic structures. However, non-hexagonal rings are energetically unstable compared to the hexagonal counterparts, making it challenging to embed non-hexagonal rings into carbon-based nullostructures in a controllable manner. Here, we report an on-surface synthesis of graphene-like nulloribbons with periodically embedded four-and eight-membered rings. The scanning tunnelling microscopy and atomic force microscopy study revealed that four-and eight-membered rings are formed between adjacent perylene backbones with a planar configuration. The nonhexagonal rings as a topological modification markedly change the electronic properties of the nulloribbons. The highest occupied and lowest unoccupied ribbon states are mainly distributed around the eight-and four-membered rings, respectively. The realization of graphene-like nulloribbons comprising non-hexagonal rings demonstrates a controllable route to fabricate non-hexagonal rings in nulloribbons and makes it possible to unveil their unique properties induced by non-hexagonal rings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14924, "DOI": "10.1038/ncomms14924", "DOI Link": "http://dx.doi.org/10.1038/ncomms14924", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397881800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Zhao, RF; Nie, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xiao; Zhao, Ruifang; Nie, Guangjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocarriers based on bacterial membrane materials for cancer vaccine delivery", "Source Title": "NATURE PROTOCOLS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we present a protocol for the construction and use of two types of nullocarrier based on bacterial membrane materials for cancer vaccine delivery. Cancer vaccines induce tumor regression through triggering the specific T-cell responses against tumor neoantigens, a process that can be enhanced by nullocarrier delivery. Inspired by the body's natural immune defenses against bacterial invasion, we have developed two different types of nullocarrier based on bacterial membrane materials, which employ genetically engineered outer-membrane vesicles (OMVs), or hybrid membrane vesicles containing bacterial cytoplasmic membrane, respectively. The OMV-based nullocarriers can rapidly display different tumor antigens through the surface modified Plug-and-Display system, suitable for customized cancer vaccines when the tumor neoantigens can be identified. The hybrid membrane-based nullocarriers are prepared through fusion of the bacterial cytoplasmic membrane and the primary tumor cell membrane from surgically removed tumor tissues, possessing unique advantages as personalized cancer vaccines when the neoantigens are not readily available. Compared with chemically synthesized nullocarriers such as liposomes and polymer without intrinsic adjuvant properties, owing to the large amounts of pathogen-associated molecular patterns, the two nullocarriers can activate the antigenpresenting cells while delivering multiple antigens, thus inducing effective antigen presentation and robust adaptive immune activation. Excluding bacterial culture and tumor tissue collection, the preparation of OMV- and hybrid membrane-based nullocarriers takes similar to 8 h and 10 h for tumor vaccine construction, respectively. We also detail how to use these nullocarriers to create cancer nullovaccines and evaluate their immunostimulatory and antitumor effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 17, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2240, "End Page": 2274, "Article Number": null, "DOI": "10.1038/s41596-022-00713-7", "DOI Link": "http://dx.doi.org/10.1038/s41596-022-00713-7", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000829684700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Debsharma, T; Amfilochiou, V; Wróblewska, AA; De Baere, I; Van Paepegem, W; Du Prez, FE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Debsharma, Tapas; Amfilochiou, Virginia; Wroblewska, Aleksandra Alicja; De Baere, Ives; Van Paepegem, Wim; Du Prez, Filip E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast Dynamic Siloxane Exchange Mechanism for Reshapable Vitrimer Composites", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To develop siloxane-containing vitrimers with fast dynamic characteristics, different mechanistic pathways have been investigated using a range of catalysts. In particular, one siloxane exchange pathway has been found to show a fast dynamic behavior in a useful temperature range (180-220 degrees C) for its application in vitrimers. The mechanism is found to involve 1,5,7-triazabicyclo [4.4.0] dec-5-ene (TBD) as an organic catalyst in the presence of hydroxyl groups. Using this new mechanistic approach, vitrimers with ultrafast stress-relaxation characteristics (relaxation times below 10 s) have been prepared with a readily available epoxy resin and siloxane-amine hardener. Subsequently, the low viscosity siloxane-containing vitrimer resin enabled the preparation of glass fiber-reinforced vitrimer composites using an industrially relevant vacuum-assisted resin infusion technique. The resulting composite was successfully thermoformed into a new shape, which makes it possible to envision a second life for such highly engineered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 JUN 27", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c03518", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c03518", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821932900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ueda, J; Dorenbos, P; Bos, AJJ; Meijerink, A; Tanabe, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ueda, Jumpei; Dorenbos, Pieter; Bos, Adrie J. J.; Meijerink, Andries; Tanabe, Setsuhisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insight into the Thermal Quenching Mechanism for Y3Al5O12:Ce3+ through Thermo luminescence Excitation Spectroscopy", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Y3Al5O12(YAG):Ce3+ is the most widely applied phosphor in white LEDs (w-LEDs) because of strong blue absorption and efficient yellow luminescence combined with a high stability and thermal quenching temperature, required for the extreme operating conditions in high-power w-LEDs. The high luminescence quenching temperature (similar to 600 K) has been well established, but surprisingly, the mechanism for temperature quenching has not been elucidated yet. In this report we investigate the possibility of thermal ionization as a cause of this quenching process by measuring thermoluminescence (TL) excitation spectra at various temperatures. In the TL excitation (TLE) spectrum at room temperature there is no Ce3+:5d(1) band (the lowest excited 5d level). However, in the TLE spectrum at 573 K, which corresponds to the onset temperature of luminescence quenching, a TLE band due to the Ce3+:5d(1) excitation was observed at around 450 nm. On the basis of our observations we conclude that the luminescence quenching of YAG:Ce3+ at high temperatures is caused by the thermal ionization and not by the thermally activated cross over to the 4f ground state. The conclusion is confirmed by analysis of the positions of the Sd states of Ce3+ relative to the conduction band in the energy band diagram of YAG:Ce3+.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 5", "Publication Year": 2015, "Volume": 119, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 25003, "End Page": 25008, "Article Number": null, "DOI": "10.1021/acs.jpcc.5b08828", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.5b08828", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364435200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kun, D; Pukánszky, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kun, David; Pukanszky, Bela", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymer/lignin blends: Interactions, properties, applications", "Source Title": "EUROPEAN POLYMER JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignin is a cheap material available in large quantities, thus the interest in its valorization is increasing both in industry and academia. A possible approach towards value added applications is using it as a component in plastics. However, blending lignin with polymers is not straightforward because of the polarity of lignin molecules resulting in strong self-interactions. The structure and properties of lignin depend on the extraction technology used for its production. The structure of lignin is complex and its characterization difficult. Lignin has been added to various polymers in the last few decades and the resulting material was sometimes called blend, while in other cases composite. Based on arguments we show that lignin forms blends, and these are classified and discussed according to the interactions developing in them, since competitive interactions determine the structure and properties of the blends. Usually even strong interactions are not sufficient to result in complete miscibility. As a consequence, lignin is often modified chemically or by plasticization to improve its dispersion in plastics, or a compatibilizer is added to increase interfacial adhesion. Lignin can be used also as a reactive component in various resins and polymers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 93, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 618, "End Page": 641, "Article Number": null, "DOI": "10.1016/j.eurpolymj.2017.04.035", "DOI Link": "http://dx.doi.org/10.1016/j.eurpolymj.2017.04.035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407186200057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, BL; Qiu, B; Zhou, JW; Huberman, S; Esfarjani, K; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Bolin; Qiu, Bo; Zhou, Jiawei; Huberman, Samuel; Esfarjani, Keivan; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Significant Reduction of Lattice Thermal Conductivity by the Electron-Phonon Interaction in Silicon with High Carrier Concentrations: A First-Principles Study", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electron-phonon interaction is well known to create major resistance to electron transport in metals and semiconductors, whereas fewer studies are directed to its effect on phonon transport, especially in semiconductors. We calculate the phonon lifetimes due to scattering with electrons (or holes), combine them with the intrinsic lifetimes due to the anharmonic phonon-phonon interaction, all from first principles, and evaluate the effect of the electron-phonon interaction on the lattice thermal conductivity of silicon. Unexpectedly, we find a significant reduction of the lattice thermal conductivity at room temperature as the carrier concentration goes above 10(19) cm(-3) (the reduction reaches up to 45% in p-type silicon at around 10(21) cm(-3)), a range of great technological relevance to thermoelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2015, "Volume": 114, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115901, "DOI": "10.1103/PhysRevLett.114.115901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.115901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352192500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, R; Breite, D; Song, C; Gräsing, D; Ploss, T; Hille, P; Schwerdtfeger, R; Matysik, J; Schulze, A; Zimmermann, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Ren; Breite, Daniel; Song, Chen; Graesing, Daniel; Ploss, Tina; Hille, Patrick; Schwerdtfeger, Ruth; Matysik, Joerg; Schulze, Agnes; Zimmermann, Wolfgang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biocatalytic Degradation Efficiency of Postconsumer Polyethylene Terephthalate Packaging Determined by Their Polymer Microstructures", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyethylene terephthalate (PET) is the most important mass-produced thermoplastic polyester used as a packaging material. Recently, thermophilic polyester hydrolases such as TfCut2 from Thermobifida fusca have emerged as promising biocatalysts for an eco-friendly PET recycling process. In this study, postconsumer PET food packaging containers are treated with TfCut2 and show weight losses of more than 50% after 96 h of incubation at 70 degrees C. Differential scanning calorimetry analysis indicates that the high linear degradation rates observed in the first 72 h of incubation is due to the high hydrolysis susceptibility of the mobile amorphous fraction (MAF) of PET. The physical aging process of PET occurring at 70 degrees C is shown to gradually convert MAF to polymer microstructures with limited accessibility to enzymatic hydrolysis. Analysis of the chain-length distribution of degraded PET by nuclear magnetic resonullce spectroscopy reveals that MAF is rapidly hydrolyzed via a combinatorial exo- and endo-type degradation mechanism whereas the remaining PET microstructures are slowly degraded only by endo-type chain scission causing no detectable weight loss. Hence, efficient thermostable biocatalysts are required to overcome the competitive physical aging process for the complete degradation of postconsumer PET materials close to the glass transition temperature of PET.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900491, "DOI": "10.1002/advs.201900491", "DOI Link": "http://dx.doi.org/10.1002/advs.201900491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477711600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XZ; Qin, MK; Ma, SX; Chen, YZ; Ning, HH; Yang, R; Mao, SJ; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaozhong; Qin, Minkai; Ma, Shuangxiu; Chen, Yuzhuo; Ning, Honghui; Yang, Rui; Mao, Shanjun; Wang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Oxide-Support Interaction over IrO2/V2O5 for Efficient pH-Universal Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing strong oxide-support interaction (SOSI) is compelling for modulating the atomic configurations and electronic structures of supported catalysts. Herein, ultrafine iridium oxide nulloclusters (approximate to 1 nm) are anchored on vanadium oxide support (IrO2/V2O5) via SOSI. The as made catalyst, with a unique distorted IrO2 structure, is discovered to significantly boost the performance for pH-universal oxygen evolution reaction (OER). Based on experimental results and theoretical calculations, the distorted IrO2 active sites with flexible redox states in IrO2/V2O5 server as electrophilic centers balance the adsorption of oxo-intermediates and effectively facilitate the process of O-O coupling, eventually propelling the fast turnover of water oxidation. As a result, IrO2/V2O5 demonstrates not only ultralow overpotentials at 10 mA cm(-2) (266 mV, pH = 0; 329 mV, pH = 7; 283 mV, pH = 14) for OER, but also high-performance overall water electrolysis over a broad pH range, with a potential of mere 1.50 V (pH = 0), 1.65 V (pH = 7) or 1.49 V (pH = 14) at 10 mA cm(-2). In addition, SOSI can simultaneously secure the distorted active sites and thus remarkably improving the catalytic stability, making it a promising strategy to develop high-performance catalytic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2104636, "DOI": "10.1002/advs.202104636", "DOI Link": "http://dx.doi.org/10.1002/advs.202104636", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754330500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Snellings, R; Suraneni, P; Skibsted, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Snellings, Ruben; Suraneni, Prannoy; Skibsted, Jorgen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Future and emerging supplementary cementitious materials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To sustain the decarbonization of the cement industry, identifying new sources of supplementary cementitious materials (SCMs) is crucial. This review paper examines recent scientific literature on the understanding, assessment, and processing of future and emerging SCM resources. Among the SCMs that have generated sig-nificant interest are calcined clays, natural pozzolans, reclaimed coal fly ashes, certain biomass ashes, concrete recycling fines, and recycled glass. These SCMs are gaining market access, and their processing and performance have been well-established in local contexts.A growing body of research is considering a much wider array of by-product and waste materials as potential future SCM sources. These materials are often available in high volumes, but they typically require beneficiation processing to enhance their performance and compatibility as SCM. While promising results have been achieved for many materials, future research and development efforts are necessary to better understand their impact on cement and concrete properties and establish or improve the viability of the proposed beneficiation processing. In conclusion, this review highlights the latest developments in testing and specifications that support the uptake of a wider range of SCMs in cement and concrete.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 171, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107199, "DOI": "10.1016/j.cemconres.2023.107199", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2023.107199", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001013362100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stork, D; Agostini, P; Boutard, JL; Buckthorpe, D; Diegele, E; Dudarev, SL; English, C; Federici, G; Gilbert, MR; Gonzalez, S; Ibarra, A; Linsmeier, C; Li Puma, A; Marbach, G; Morris, PF; Packer, LW; Raj, B; Rieth, M; Tran, MQ; Ward, DJ; Zinkle, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stork, D.; Agostini, P.; Boutard, J. L.; Buckthorpe, D.; Diegele, E.; Dudarev, S. L.; English, C.; Federici, G.; Gilbert, M. R.; Gonzalez, S.; Ibarra, A.; Linsmeier, Ch.; Li Puma, A.; Marbach, G.; Morris, P. F.; Packer, L. W.; Raj, B.; Rieth, M.; Tran, M. Q.; Ward, D. J.; Zinkle, S. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developing structural, high-heat flux and plasma facing materials for a near-term DEMO fusion power plant: The EU assessment", "Source Title": "JOURNAL OF NUCLEAR MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The findings of the EU 'Materials Assessment Group' (MAG), within the 2012 EU Fusion Roadmap exercise, are discussed. MAG analysed the technological readiness of structural, plasma facing and high heat flux materials for a DEMO concept to be constructed in the early 2030s, proposing a coherent strategy for R&D up to a DEMO construction decision. A DEMO phase I with a 'Starter Blanket' and 'Starter Divertor' is foreseen: the blanket being capable of withstanding >= 2 MW yr m(-2) fusion neutron fluence (similar to 20 dpa in the front-wall steel). A second phase ensues for DEMO with >= 5 MW yr m(-2) first wall neutron fluence. Technical consequences for the materials required and the development, testing and modelling programmes, are analysed using: a systems engineering approach, considering reactor operational cycles, efficient maintenullce and inspection requirements, and interaction with functional materials/coolants; and a project-based risk analysis, with R&D to mitigate risks from material shortcomings including development of specific risk mitigation materials. The DEMO balance of plant constrains the blanket and divertor coolants to remain unchanged between the two phases. The blanket coolant choices (He gas or pressurised water) put technical constraints on the blanket steels, either to have high strength at higher temperatures than current baseline variants (above 650 degrees C for high thermodynamic efficiency from He-gas coolant), or superior radiation-embrittlement properties at lower temperatures (similar to 290-320 degrees C), for construction of water-cooled blankets. Risk mitigation proposed would develop these options in parallel, and computational and modelling techniques to shorten the cycle-time of new steel development will be important to achieve tight R&D timescales. The superior power handling of a water-cooled divertor target suggests a substructure temperature operating window (similar to 200-350 degrees C) that could be realised, as a baseline-concept, using tungsten on a copper-alloy substructure. The difficulty of establishing design codes for brittle tungsten puts great urgency on the development of a range of advanced ductile or strengthened tungsten and copper compounds. Lessons learned from Fission reactor material development have been included, especially in safety and licensing, fabrication/joining techniques and designing for in-vessel inspection. The technical basis of using the ITER licensing experience to refine the issues in nuclear testing of materials is discussed. Testing with 14 MeV neutrons is essential to Fusion Materials development, and the Roadmap requires acquisition of >= 30 dpa (steels) 14 MeV test data by 2026. The value and limits of pre-screening testing with fission neutrons on isotopically- or chemically-doped steels and with ion-beams are evaluated to help determine the minimum14 MeV testing programme requirements. (C) 2014 EURATION/CCFE. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 455, "Issue": "1-3", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 277, "End Page": 291, "Article Number": null, "DOI": "10.1016/j.jnucmat.2014.06.014", "DOI Link": "http://dx.doi.org/10.1016/j.jnucmat.2014.06.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348003600053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GD; Han, GQ; Wang, L; Cui, XY; Moehring, NK; Kidambi, PR; Jiang, DE; Sun, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guodong; Han, Guanqun; Wang, Lu; Cui, Xiaoyu; Moehring, Nicole K.; Kidambi, Piran R.; Jiang, De-en; Sun, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual hydrogen production from electrocatalytic water reduction coupled with formaldehyde oxidation via a copper-silver electrocatalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The broad employment of water electrolysis for hydrogen (H-2) production is restricted by its large voltage requirement and low energy conversion efficiency because of the sluggish oxygen evolution reaction (OER). Herein, we report a strategy to replace OER with a thermodynamically more favorable reaction, the partial oxidation of formaldehyde to formate under alkaline conditions, using a Cu3Ag7 electrocatalyst. Such a strategy not only produces more valuable anodic product than O-2 but also releases H-2 at the anode with a small voltage input. Density functional theory studies indicate the H2C(OH)O intermediate from formaldehyde hydration can be better stabilized on Cu3Ag7 than on Cu or Ag, leading to a lower C-H cleavage barrier. A two-electrode electrolyzer employing an electrocatalyst of Cu3Ag7(+)||Ni3N/Ni(-) can produce H-2 at both anode and cathode simultaneously with an apparent 200% Faradaic efficiency, reaching a current density of 500mA/cm(2) with a cell voltage of only 0.60V. Water electrolysis typically requires a large voltage input and produces H-2 only at the cathode. Here the authors present a strategy of coupling formaldehyde oxidation with water reduction and report H-2 production at both anode and cathode with small voltage inputs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 525, "DOI": "10.1038/s41467-023-36142-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36142-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026236800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suresh, SM; Zhang, L; Hall, D; Si, CF; Ricci, G; Matulaitis, T; Slawin, AMZ; Warriner, S; Olivier, Y; Samuel, IDW; Zysman-Colman, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suresh, Subeesh Madayanad; Zhang, Le; Hall, David; Si, Changfeng; Ricci, Gaetano; Matulaitis, Tomas; Slawin, Alexandra M. Z.; Warriner, Stuart; Olivier, Yoann; Samuel, Ifor D. W.; Zysman-Colman, Eli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Deep-Blue-Emitting Heteroatom-Doped MR-TADF Nonacene for High-Performance Organic Light-Emitting Diodes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a p- and n-doped nonacene compound, NOBNacene, that represents a rare example of a linearly extended ladder-type multiresonullt thermally activated delayed fluorescence (MR-TADF) emitter. This compound shows efficient narrow deep blue emission, with a lambda(PL) of 410 nm, full width at half maximum, FWHM, of 38 nm, photoluminescence quantum yield, phi(PL) of 71 %, and a delayed lifetime, tau(d) of 1.18 ms in 1.5 wt % TSPO1 thin film. The organic light-emitting diode (OLED) using this compound as the emitter shows a comparable electroluminescence spectrum peaked at 409 nm (FWHM=37 nm) and a maximum external quantum efficiency (EQE(max)) of 8.5 % at Commission Internationale de l'eclairage (CIE) coordinates of (0.173, 0.055). The EQE(max) values were increased to 11.2 % at 3 wt % doping of the emitter within the emissive layer of the device. At this concentration, the electroluminescence spectrum broadened slightly, leading to CIE coordinates of (0.176, 0.068).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2023, "Volume": 62, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202215522", "DOI Link": "http://dx.doi.org/10.1002/anie.202215522", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914240200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, WL; Chouchane, M; Li, WK; Bai, S; Liu, Z; Li, LT; Chen, AX; Sayahpour, B; Shimizu, R; Raghavendran, G; Schroeder, MA; Chen, YT; Tan, DHS; Sreenarayanull, B; Waters, CK; Sichler, A; Gould, B; Kountz, DJ; Lipomi, DJ; Zhang, MH; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Weiliang; Chouchane, Mehdi; Li, Weikang; Bai, Shuang; Liu, Zhao; Li, Letian; Chen, Alexander X.; Sayahpour, Baharak; Shimizu, Ryosuke; Raghavendran, Ganesh; Schroeder, Marshall A.; Chen, Yu-Ting; Tan, Darren H. S.; Sreenarayanull, Bhagath; Waters, Crystal K.; Sichler, Allison; Gould, Benjamin; Kountz, Dennis J.; Lipomi, Darren J.; Zhang, Minghao; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 5 V-class cobalt-free battery cathode with high loading enabled by dry coating", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transitioning toward more sustainable materials and manufacturing methods will be critical to continue supporting the rapidly expanding market for lithium-ion batteries. Meanwhile, energy storage applications are demanding higher power and energy densities than ever before, with aggressive performance targets like fast charging and greatly extended operating ranges and durations. Due to its high operating voltage and cobalt-free chemistry, the spinel-type LiNi0.5Mn1.5O4 (LNMO) cathode material has attracted great interest as one of the few next-generation candidates capable of addressing this combination of challenges. However, severe capacity degradation and poor interphase stability have thus far impeded the practical application of LNMO. In this study, by leveraging a dry electrode coating process, we demonstrate LNMO electrodes with stable full cell operation (up to 68% after 1000 cycles) and ultra-high loading (up to 9.5 mA h cm(-2) in half cells). This excellent cycling stability is ascribed to a stable cathode-electrolyte interphase, a highly distributed and interconnected electronic percolation network, and robust mechanical properties. High-quality images collected using plasma focused ion beam scanning electron microscopy (PFIB-SEM) provide additional insight into this behavior, with a complementary 2-D model illustrating how the electronic percolation network in the dry-coated electrodes more efficiently supports homogeneous electrochemical reaction pathways. These results strongly motivate that LNMO with a high voltage cobalt-free cathode chemistry combined with an energy-efficient dry electrode coating process opens up the possibility for sustainable electrode manufacturing using cost-effective and high-energy-density cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2023, "Volume": 16, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1620, "End Page": 1630, "Article Number": null, "DOI": "10.1039/d2ee03840d", "DOI Link": "http://dx.doi.org/10.1039/d2ee03840d", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000943808000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, DF; Wang, BY; Lee, K; Harvey, SP; Osada, M; Goodge, BH; Kourkoutis, LF; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Danfeng; Wang, Bai Yang; Lee, Kyuho; Harvey, Shannon P.; Osada, Motoki; Goodge, Berit H.; Kourkoutis, Lena F.; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconducting Dome in Nd1-xSrxNiO2 Infinite Layer Films", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the phase diagram of Nd1-xSrxNiO2 infinite layer thin films grown on SrTiO3. A superconducting dome spanning 0.125 < x < 0.25 is found, remarkably similar to cuprates, albeit over a narrower doping window. However, while cuprate superconductivity is bounded by an insulator for underdoping and a metal for overdoping, here we observe weakly insulating behavior on either side of the dome. Furthermore, the normal state Hall coefficient is always small and proximate to a continuous zero crossing in doping and in temperature, in contrast to the similar to 1/x dependence observed for cuprates. This suggests the presence of both electronlike and holelike bands, consistent with band structure calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 271, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2020, "Volume": 125, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27001, "DOI": "10.1103/PhysRevLett.125.027001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.027001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545870800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, B; Lee, S; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Baekjun; Lee, Sangwon; Kim, Jihan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverse design of porous materials using artificial neural networks", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Generating optimal nullomaterials using artificial neural networks can potentially lead to a notable revolution in future materials design. Although progress has been made in creating small and simple molecules, complex materials such as crystalline porous materials have yet to be generated using any of the neural networks. Here, we have implemented a generative adversarial network that uses a training set of 31,713 known zeolites to produce 121 crystalline porous materials. Our neural network takes in inputs in the form of energy and material dimensions, and we show that zeolites with a user-desired range of 4 kJ/mol methane heat of adsorption can be reliably produced using our neural network. The fine-tuning of user-desired capability can potentially accelerate materials development as it demonstrates a successful case of inverse design of porous materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax9324", "DOI": "10.1126/sciadv.aax9324", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax9324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507552400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, CHY; Kort-Kamp, WJM; Yu, HR; Cullen, DA; Patterson, BM; Arman, TA; Babu, SK; Mukundan, R; Borup, RL; Spendelow, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, ChungHyuk; Kort-Kamp, Wilton J. M.; Yu, Haoran; Cullen, David A.; Patterson, Brian M.; Arman, Tanvir Alam; Komini Babu, Siddharth; Mukundan, Rangachary; Borup, Rod L.; Spendelow, Jacob S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grooved electrodes for high-power-density fuel cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton exchange membrane fuel cells (PEMFCs) are leading candidates to decarbonize the transport sector, but widespread deployment will require improvements in lifetime, fuel economy and cost. Here we present the grooved electrode, an alternative electrode structure that enhances PEMFC performance and durability by coupling high ionomer (ion-conducting binder) content for improved H+ transport with grooves for rapid O-2 transport. Grooved electrodes provide up to 50% higher performance than state-of-the-art conventional electrodes under standard operating conditions. Fuel cell diagnostics combined with multiphysics modelling demonstrate that grooved electrodes provide facile O-2 transport despite their high ionomer content, enabling improved reaction rate uniformity. Grooved electrodes also provide improved durability, with less performance loss after carbon corrosion compared with baseline electrodes. Machine learning analysis demonstrates the potential to further optimize grooved structures for next-generation PEMFCs with enhanced performance and durability, enabling smaller and cheaper fuel cell stacks with higher fuel efficiency. The way catalysts are arranged and interfaced to form fuel cell electrodes is just as important as the catalysts themselves. Here Lee et al. report an up to 50% increase in performance and superior durability using grooved, rather than conventional flat, electrodes for hydrogen fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 685, "End Page": 694, "Article Number": null, "DOI": "10.1038/s41560-023-01263-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01263-2", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994723800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marechal, L; Balland, P; Lindenroth, L; Petrou, F; Kontovounisios, C; Bello, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marechal, Luc; Balland, Pascale; Lindenroth, Lukas; Petrou, Fotis; Kontovounisios, Christos; Bello, Fernulldo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward a Common Framework and Database of Materials for Soft Robotics", "Source Title": "SOFT ROBOTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To advance the field of soft robotics, a unified database of material constitutive models and experimental characterizations is of paramount importance. This will facilitate the use of finite element analysis to simulate their behavior and optimize the design of soft-bodied robots. Samples from seventeen elastomers, namely Body Double (TM) SILK, Dragon Skin (TM) 10 MEDIUM, Dragon Skin 20, Dragon Skin 30, Dragon Skin FX-Pro, Dragon Skin FX-Pro + Slacker, Ecoflex (TM) 00-10, Ecoflex 00-30, Ecoflex 00-50, Rebound (TM) 25, Mold Star (TM) 16 FAST, Mold Star 20T, SORTA-Clear (TM) 40, RTV615, PlatSil(R)Gel-10, Psycho Paint(R), and SOLOPLAST 150318, were subjected to uniaxial tensile tests according to the ASTM D412 standard. Sample preparation and tensile test parameters are described in detail. The tensile test data are used to derive parameters for hyperelastic material models using nonlinear least-squares methods, which are provided to the reader. This article presents the mechanical characterization and the resulting material properties for a wide set of commercially available hyperelastic materials, many of which are recognized and commonly applied in the field of soft robotics, together with some that have never been characterized. The experimental raw data and the algorithms used to determine material parameters are shared on theSoft Robotics Materials DatabaseGitHub repository to enable accessibility, as well as future contributions from the soft robotics community. The presented database is aimed at aiding soft roboticists in designing and modeling soft robots while providing a starting point for future material characterizations related to soft robotics research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2021, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": 297, "Article Number": null, "DOI": "10.1089/soro.2019.0115", "DOI Link": "http://dx.doi.org/10.1089/soro.2019.0115", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544391100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahn, N; Livache, C; Pinchetti, V; Jung, H; Jin, H; Hahm, D; Park, YS; Klimov, VI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahn, Namyoung; Livache, Clement; Pinchetti, Valerio; Jung, Heeyoung; Jin, Ho; Hahm, Donghyo; Park, Young-Shin; Klimov, Victor I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically driven amplified spontaneous emission from colloidal quantum dots", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal quantum dots (QDs) are attractive materials for realizing solution-processable laser diodes that could benefit from size-controlled emission wavelengths, low optical-gain thresholds and ease of integration with photonic and electronic circuits(1-7). However, the implementation of such devices has been hampered by fast Auger recombination of gain-active multicarrier states(1,8), poor stability of QD films at high current densities(9,10) and the difficulty to obtain net optical gain in a complex device stack wherein a thin electroluminescent QD layer is combined with optically lossy charge-conducting layers(11-13). Here we resolve these challenges and achieve amplified spontaneous emission (ASE) from electrically pumped colloidal QDs. The developed devices use compact, continuously graded QDs with suppressed Auger recombination incorporated into a pulsed, high-current-density charge-injection structure supplemented by a low-loss photonic waveguide. These colloidal QD ASE diodes exhibit strong, broadband optical gain and demonstrate bright edge emission with instantaneous power of up to 170 mu W.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2023, "Volume": 617, "Issue": 7959, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 79, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05855-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05855-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982019500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Low, ZX; Chua, YT; Ray, BM; Mattia, D; Metcalfe, IS; Patterson, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Low, Ze-Xian; Chua, Yen Thien; Ray, Brian Michael; Mattia, Davide; Metcalfe, Ian Saxley; Patterson, Darrell Alec", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective on 3D printing of separation membranes and comparison to related unconventional fabrication techniques", "Source Title": "JOURNAL OF MEMBRANE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing, likewise known as 3-dimensional (3D) printing and rapid prototyping, has the ability to create almost any geometrically complex shape or feature in a range of materials across different scales. It has found its applications in various areas, such as medicine (bioprinting), art, manufacturing and engineering. On the other hand, its use in separation membrane engineering is relatively new. The use of additive manufacturing techniques could provide more control towards the design of separation membrane systems and offers novel membrane preparation techniques that are able to produce membranes of different shapes, types and designs which cannot be made using conventional techniques such as phase inversion or sintering. Here we provide key background information on 3D printing technologies and applications in membrane engineering; a discussion of the potential and limitations of current 3D printing technologies for membrane engineering and future aspects of the technology. Due to the potential benefits of 3D printing in membrane manufacturing, in particular the unprecedented control over membrane architecture the technique could allow, the use of 3D printing in membrane systems should see significant growth in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 523, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 596, "End Page": 613, "Article Number": null, "DOI": "10.1016/j.memsci.2016.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.memsci.2016.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392772900062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sorbom, BN; Ball, J; Palmer, TR; Mangiarotti, FJ; Sierchio, JM; Bonoli, P; Kasten, C; Sutherland, DA; Barnard, HS; Haakonsen, CB; Goh, J; Sung, C; Whyte, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sorbom, B. N.; Ball, J.; Palmer, T. R.; Mangiarotti, F. J.; Sierchio, J. M.; Bonoli, P.; Kasten, C.; Sutherland, D. A.; Barnard, H. S.; Haakonsen, C. B.; Goh, J.; Sung, C.; Whyte, D. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ARC: A compact, high-field, fusion nuclear science facility and demonstration power plant with demountable magnets", "Source Title": "FUSION ENGINEERING AND DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The affordable, robust, compact (ARC) reactor is the product of a conceptual design study aimed at reducing the size, cost, and complexity of a combined fusion nuclear science facility (FNSF) and demonstration fusion Pilot power plant. ARC is a similar to 200-250 MWe tokamak reactor with a major radius of 3.3 m, a minor radius of 1.1 m, and an on-axis magnetic field of 9.2T. ARC has rare earth barium copper oxide (REBCO) superconducting toroidal field coils, which have joints to enable disassembly. This allows the vacuum vessel to be replaced quickly, mitigating first wall survivability concerns, and permits a single device to test many vacuum vessel designs and divertor materials. The design point has a plasma fusion gain of Q(p) approximate to 13.6, yet is fully non-inductive, with a modest bootstrap fraction of only similar to 63%. Thus ARC offers a high power gain with relatively large external control of the current profile. This highly attractive combination is enabled by the similar to 23 T peak field on coil achievable with newly available REBCO superconductor technology. External current drive is provided by two innovative inboard RF launchers using 25 MW of lower hybrid and 13.6 MW of ion cyclotron fast wave power. The resulting efficient current drive provides a robust, steady state core plasma far from disruptive limits. ARC uses an all-liquid blanket, consisting of low pressure, slowly flowing fluorine lithium beryllium (FLiBe) molten salt. The liquid blanket is low-risk technology and provides effective neutron moderation and shielding, excellent heat removal, and a tritium breeding ratio >= 1.1. The large temperature range over which FLiBe is liquid permits an output blanket temperature of 900 K, single phase fluid cooling, and a high efficiency helium Brayton cycle, which allows for net electricity generation when operating ARC as a Pilot power plant. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 405, "Article Number": null, "DOI": "10.1016/j.fusengdes.2015.07.008", "DOI Link": "http://dx.doi.org/10.1016/j.fusengdes.2015.07.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365055600046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, T; Gillispie, GJ; Copus, JS; Kumar, PRA; Seol, YJ; Atala, A; Yoo, JJ; Lee, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Teng; Gillispie, Gregory J.; Copus, Joshua S.; Kumar, Anil P. R.; Seol, Young-Joon; Atala, Anthony; Yoo, James J.; Lee, Sang Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimization of gelatin-alginate composite bioink printability using rheological parameters: a systematic approach", "Source Title": "BIOFABRICATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional bioprinting has emerged as a promising technique in tissue engineering applications through the precise deposition of cells and biomaterials in a layer-by-layer fashion. However, the limited availability of hydrogel bioinks is frequently cited as a major issue for the advancement of cell-based extrusion bioprinting technologies. It is well known that highly viscous materials maintain their structure better, but also have decreased cell viability due to the higher forces which are required for extrusion. However, little is known about the effect of the two distinct components of dynamic modulus of viscoelastic materials, storage modulus (G') and loss modulus (G''), on the printability of hydrogel-based bioinks. Additionally, 'printability' has been poorly defined in the literature, mostly consisting of gross qualitative measures which do not allow for direct comparison of bioinks. This study developed a framework for evaluating printability and investigated the effect of dynamic modulus, including storage modulus (G'), loss modulus (G''), and loss tangent (G''/G') on the printing outcome. Gelatin and alginate as model hydrogels were mixed at various concentrations to obtain hydrogel formulations with a wide range of storage and loss moduli. These formulations were then evaluated for the quantitatively defined values of extrudability, extrusion uniformity, and structural integrity. For extrudability, increasing either the loss or storage modulus increased the pressure required to extrude the bioink. A mathematical model relating the G' and G'' to the required extrusion pressure was derived based on the data. A lower loss tangent was correlated with increased structural integrity while a higher loss tangent correlated with increased extrusion uniformity. Gelatin-alginate composite hydrogels with a loss tangent in the range of 0.25-0.45 exhibited an excellent compromise between structural integrity and extrusion uniformity. In addition to the characterization of a common bioink, the methodology introduced in this paper could also be used to evaluate the printability of other bioinks in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34106, "DOI": "10.1088/1758-5090/aacdc7", "DOI Link": "http://dx.doi.org/10.1088/1758-5090/aacdc7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436969600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, J; Zhang, YP; Kimura, HD; Wu, HT; Yue, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Jian; Zhang, Yuping; Kimura, Hideo; Wu, Haitao; Yue, Zhenxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal structure, chemical bond characteristics, infrared reflection spectrum, and microwave dielectric properties of Nd2(Zr1-xTix)3(MoO4)9 ceramics", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microwave dielectric ceramics (MWDCs) with low dielectric constant and low dielectric loss are desired in contemporary society, where the communication frequency is developing to high frequency (sub-6G). Herein, Nd-2(Zr1-xTix)(3)(MoO4)(9) (NZ(1-x)T(x)M, x = 0.02-0.10) ceramics were prepared through a solid-phase process. According to X-ray diffraction (XRD) patterns, the ceramics could form a pure crystal structure with the R (3) over barc (167) space group. The internal parameters affecting the properties of the ceramics were calculated and analyzed by employing Clausius-Mossotti relationship, Shannon's rule, and Phillips-van Vechten-Levine (P-V-L) theory. Furthermore, theoretical dielectric loss of the ceramics was measured and analyzed by a Fourier transform infrared (IR) radiation spectrometer. Notably, when x = 0.08 and sintered at 700 degrees C, optimal microwave dielectric properties of the ceramics were obtained, including a dielectric constant (epsilon(r)) = 10.94, Q center dot f = 82,525 GHz (at 9.62 GHz), and near-zero resonullt frequency temperature coefficient (tau(f)) = -12.99 ppm/degrees C. This study not only obtained an MWDC with excellent properties but also deeply analyzed the effects of Ti4+ on the microwave dielectric properties and chemical bond characteristics of Nd2Zr3(MoO4)(9) (NZM), which laid a solid foundation for the development of rare-earth molybdate MWDC system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 82, "End Page": 92, "Article Number": null, "DOI": "10.26599/JAC.2023.9220668", "DOI Link": "http://dx.doi.org/10.26599/JAC.2023.9220668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923438100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, KJ; Hwang, JY; Ryu, HH; Maglia, F; Kim, SJ; Lamp, P; Yoon, CS; Sun, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Kang-Joon; Hwang, Jang-Yeon; Ryu, Hoon-Hee; Maglia, Filippo; Kim, Sung-Jin; Lamp, Peter; Yoon, Chong S.; Sun, Yang-Kook", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Degradation Mechanism of Ni-Enriched NCA Cathode for Lithium Batteries: Are Microcracks Really Critical?", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A series of Ni-enriched Li[NixCoyAlz]O-2 cathodes (x = 0.80-0.95) were synthesized and evaluated comprehensively to investigate the capacity fading mechanism. Capacity retention was shown to be strongly related to the extent of microcracking within the secondary particles. Moreover, the range and limit of the depth of discharge (DOD), which determined the extent of microcracking, critically affected the cycling stability such that the extremely Ni-rich Li[Ni-0.95 Co0.04Al0.01]O-2, cathode cycled at an upper DOD of 60% exhibited the poorest capacity retention. The anisotropic strain produced by the H2-H3 phase transition was not fully relieved, and persistent microcracks in the discharged state (3.76 V) allowed the electrolyte to penetrate the particle interior. Resultant extended exposure of the interior primary particles within secondary particle to electrolyte attack accelerated structural damage and eventually undermined the mechanical integrity of the cathode particles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1394, "End Page": 1400, "Article Number": null, "DOI": "10.1021/acsenergylett.9b00733", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b00733", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472121800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, QL; Chang, XQ; Butts, D; DeBlock, R; Lan, K; Li, JB; Chao, DL; Peng, DL; Dunn, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Qiulong; Chang, Xiaoqing; Butts, Danielle; DeBlock, Ryan; Lan, Kun; Li, Junbin; Chao, Dongliang; Peng, Dong-Liang; Dunn, Bruce", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface-redox sodium-ion storage in anatase titanium oxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion storage technologies are promising candidates for large-scale grid systems due to the abundance and low cost of sodium. However, compared to well-understood lithium-ion storage mechanisms, sodium-ion storage remains relatively unexplored. Herein, we systematically determine the sodium-ion storage properties of anatase titanium dioxide (TiO2(A)). During the initial sodiation process, a thin surface layer (similar to 3 to 5 nm) of crystalline TiO2(A) becomes amorphous but still undergoes Ti4+/Ti3+ redox reactions. A model explaining the role of the amorphous layer and the dependence of the specific capacity on the size of TiO2(A) nulloparticles is proposed. Amorphous nulloparticles of similar to 10 nm seem to be optimum in terms of achieving high specific capacity, on the order of 200 mAh g(-1), at high charge/discharge rates. Kinetic studies of TiO2(A) nulloparticles indicate that sodium-ion storage is due to a surface-redox mechanism that is not dependent on nulloparticle size in contrast to the lithiation of TiO2(A) which is a diffusion-limited intercalation process. The surface-redox properties of TiO2(A) result in excellent rate capability, cycling stability and low overpotentials. Moreover, tailoring the surface-redox mechanism enables thick electrodes of TiO2(A) to retain high rate properties, and represents a promising direction for high-power sodium-ion storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7, "DOI": "10.1038/s41467-022-35617-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35617-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953169900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, Y; Gao, ZM; Ye, KH; Park, HW; Zheng, YH; Zheng, YZ; Gao, JF; Park, MH; Choi, JH; Xue, KH; Hwang, CS; Lyu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Yan; Gao, Zhaomeng; Ye, Kun Hee; Park, Hyeon Woo; Zheng, Yonghui; Zheng, Yunzhe; Gao, Jianfeng; Park, Min Hyuk; Choi, Jung-Hae; Xue, Kan-Hao; Hwang, Cheol Seong; Lyu, Hangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible transition between the polar and antipolar phases and its implications for wake-up and fatigue in HfO2-based ferroelectric thin film", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic-resolution Cs-corrected scanning transmission electron microscopy revealed local shifting of two oxygen positions (O-I and O-II) within the unit cells of a ferroelectric (Hf0.5Zr0.5)O-2 thin film. A reversible transition between the polar Pbc2(1) and antipolar Pbca phases, where the crystal structures of the 180 degrees domain wall of the Pbc2(1) phase and the unit cell structure of the Pbca phase were identical, was induced by applying appropriate cycling voltages. The critical field strength that determined whether the film would be woken up or fatigued was similar to 0.8 MV/cm, above or below which wake-up or fatigue was observed, respectively. Repeated cycling with sufficiently high voltages led to development of the interfacial nonpolar P4(2)/nmc phase, which induced fatigue through the depolarizing field effect. The fatigued film could be rejuvenated by applying a slightly higher voltage, indicating that these transitions were reversible. These mechanisms are radically different from those of conventional ferroelectrics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 645, "DOI": "10.1038/s41467-022-28236-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28236-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000752207900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharma, V; Wang, CC; Lorenzini, RG; Ma, R; Zhu, Q; Sinkovits, DW; Pilania, G; Oganov, AR; Kumar, S; Sotzing, GA; Boggs, SA; Ramprasad, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharma, Vinit; Wang, Chenchen; Lorenzini, Robert G.; Ma, Rui; Zhu, Qiang; Sinkovits, Daniel W.; Pilania, Ghanshyam; Oganov, Artem R.; Kumar, Sanat; Sotzing, Gregory A.; Boggs, Steven A.; Ramprasad, Rampi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of all organic polymer dielectrics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To date, trial and error strategies guided by intuition have dominated the identification of materials suitable for a specific application. We are entering a data-rich, modelling-driven era where such Edisonian approaches are gradually being replaced by rational strategies, which couple predictions from advanced computational screening with targeted experimental synthesis and validation. Here, consistent with this emerging paradigm, we propose a strategy of hierarchical modelling with successive downselection stages to accelerate the identification of polymer dielectrics that have the potential to surpass 'standard' materials for a given application. Successful synthesis and testing of some of the most promising identified polymers and the measured attractive dielectric properties (which are in quantitative agreement with predictions) strongly supports the proposed approach to material selection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4845, "DOI": "10.1038/ncomms5845", "DOI Link": "http://dx.doi.org/10.1038/ncomms5845", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342841500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kibasomba, PM; Dhlamini, S; Maaza, M; Liu, CP; Rashad, MM; Rayan, DA; Mwakikunga, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kibasomba, Pierre M.; Dhlamini, Simon; Maaza, Malik; Liu, Chuan-Pu; Rashad, Mohamed M.; Rayan, Diaa A.; Mwakikunga, Bonex W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain and grain size of TiO2 nulloparticles from TEM, Raman spectroscopy and XRD: The revisiting of the Williamson-Hall plot method", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Williamson-Hall (W-H) equation, which has been used to obtain relative crystallite sizes and strains between samples since 1962, is revisited. A modified W-H equation is derived which takes into account the Scherrer equation, first published in 1918, (which traditionally gives more absolute crystallite size prediction) and strain prediction from Raman spectra. It is found that W-H crystallite sizes are on average 2.11 +/- 0.01 times smaller than the sizes from Scherrer equation. Furthermore the strain from the W-H plots when compared to strain obtained from Raman spectral red-shifts yield factors whose values depend on the phases in the materials - whether anatase, rutile or brookite. Two main phases are identified in the annealing temperatures (350 degrees C-700 degrees C) chosen herein - anatase and brookite. A transition temperature of 550 degrees C has been found for nullo-TiO2 to irreversibly transform from brookite to anatase by plotting the Raman peak shifts against the annealing temperatures. The W-H underestimation on the strain in the brookite phase gives W-H/Raman factor of 3.10 +/- 0.05 whereas for the anatase phase, one gets 2.46 +/- 0.03. The new beta(2)(tot)cos(2)theta-sin theta plot and when fitted with a polynomial yield less strain but much better matching with experimental TEM crystallite sizes and the agglomerates than both the traditional Williamson-Hall and the Scherrer methods. There is greater improvement in the model when linearized that is the beta(tot)cos(2)theta-sin theta plot rather than the beta(2)(tot)cos(2)theta-sin theta plot. (C) 2018 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 628, "End Page": 635, "Article Number": null, "DOI": "10.1016/j.rinp.2018.03.008", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2018.03.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435611100083", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, J; Sementa, L; Liu, ZY; Barcaro, G; Feng, M; Liu, ES; Jiao, L; Xu, MJ; Leshchev, D; Lee, SJ; Li, MF; Wan, CZ; Zhu, EB; Liu, Y; Peng, BS; Duan, XF; Goddard, WA ; Fortunelli, A; Jia, QY; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jin; Sementa, Luca; Liu, Zeyan; Barcaro, Giovanni; Feng, Miao; Liu, Ershuai; Jiao, Li; Xu, Mingjie; Leshchev, Denis; Lee, Sung-Joon; Li, Mufan; Wan, Chengzhang; Zhu, Enbo; Liu, Yang; Peng, Bosi; Duan, Xiangfeng; Goddard, William A., III; Fortunelli, Alessandro; Jia, Qingying; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Sabatier plot for predictive design of active and stable Pt-alloy oxygen reduction reaction catalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A critical technological roadblock to the widespread adoption of proton-exchange membrane fuel cells is the development of highly active and durable platinum-based catalysts for accelerating the sluggish oxygen reduction reaction, which has largely relied on anecdotal discoveries so far. While the oxygen binding energy Delta E-O has been frequently used as a theoretical descriptor for predicting the activity, there is no known descriptor for predicting durability. Here we developed a binary experimental descriptor that captures both the strain and Pt transition metal coupling contributions through X-ray absorption spectroscopy and directly correlated the binary experimental descriptor with the calculated Delta E-O of the catalyst surface. This leads to an experimentally validated Sabatier plot to predict both the catalytic activity and stability for a wide range of Pt-alloy oxygen reduction reaction catalysts. Based on the binary experimental descriptor, we further designed an oxygen reduction reaction catalyst wherein high activity and stability are simultaneously achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 513, "End Page": 523, "Article Number": null, "DOI": "10.1038/s41929-022-00797-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00797-0", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808394500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, ZY; Song, ZR; Huang, ZD; Tao, SS; Song, B; Cao, ZW; Hu, XY; Wu, JE; Li, FR; Deng, WT; Hou, HS; Ji, XB; Zou, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Zhiyu; Song, Zirui; Huang, Zhaodong; Tao, Shusheng; Song, Bai; Cao, Ziwei; Hu, Xinyu; Wu, Jiae; Li, Fengrong; Deng, Wentao; Hou, Hongshuai; Ji, Xiaobo; Zou, Guoqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstructing Hydrogen Bond Network Enables High Voltage Aqueous Zinc-Ion Supercapacitors", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-voltage aqueous rechargeable energy storage devices with safety and high specific energy are hopeful candidates for the future energy storage system. However, the electrochemical stability window of aqueous electrolytes is a great challenge. Herein, inspired by density functional theory (DFT), polyethylene glycol (PEG) can interact strongly with water molecules, effectively reconstructing the hydrogen bond network. In addition, N, N-dimethylformamide (DMF) can coordinate with Zn2+, assisting in the rapid desolvation of Zn2+ and stable plating/stripping process. Remarkably, by introducing PEG400 and DMF as co-solvents into the electrolyte, a wide electrochemical window of 4.27 V can be achieved. The shift in spectra indicate the transformation in the number and strength of hydrogen bonds, verifying the reconstruction of hydrogen bond network, which can largely inhibit the activity of water molecule, according well with the molecular dynamics simulations (MD) and online electrochemical mass spectroscopy (OEMS). Based on this electrolyte, symmetric Zn cells survived up to 5000 h at 1 mA cm(-2), and high voltage aqueous zinc ion supercapacitors assembled with Zn anode and activated carbon cathode achieved 800 cycles at 0.1 A g(-1). This work provides a feasible approach for constructing high-voltage alkali metal ion supercapacitors through reconstruction strategy of hydrogen bond network.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2023, "Volume": 62, "Issue": 38, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202309601", "DOI Link": "http://dx.doi.org/10.1002/anie.202309601", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001050946800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, TS; Eickemeyer, FT; Hope, MA; Jahanbakhshi, F; Mladenovic, M; Li, J; Zhou, ZW; Mishra, A; Yum, JH; Ren, D; Krishna, A; Ouellette, O; Wei, TC; Zhou, H; Huang, HH; Mensi, MD; Sivula, K; Zakeeruddin, SM; Milic, JV; Hagfeldt, A; Rothlisberger, U; Emsley, L; Zhang, H; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Tzu-Sen; Eickemeyer, Felix Thomas; Hope, Michael A.; Jahanbakhshi, Farzaneh; Mladenovic, Marko; Li, Jun; Zhou, Zhiwen; Mishra, Aditya; Yum, Jun-Ho; Ren, Dan; Krishna, Anurag; Ouellette, Olivier; Wei, Tzu-Chien; Zhou, Hua; Huang, Hsin-Hsiang; Mensi, Mounir Driss; Sivula, Kevin; Zakeeruddin, Shaik M.; Milic, Jovana, V; Hagfeldt, Anders; Rothlisberger, Ursula; Emsley, Lyndon; Zhang, Hong; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of molecular modulators to reduce the defect density at the surface and grain boundaries of perovskite materials has been demonstrated to be an effective approach to enhance the photovoltaic performance and device stability of perovskite solar cells. Herein, we employ crown ethers to modulate perovskite films, affording passivation of undercoordinated surface defects. This interaction has been elucidated by solid-state nuclear magnetic resonullce and density functional theory calculations. The crown ether hosts induce the formation of host-guest complexes on the surface of the perovskite films, which reduces the concentration of surface electronic defects and suppresses nonradiative recombination by 40%, while minimizing moisture permeation. As a result, we achieved substantially improved photovoltaic performance with power conversion efficiencies exceeding 23%, accompanied by enhanced stability under ambient and operational conditions. This work opens a new avenue to improve the performance and stability of perovskite-based optoelectronic devices through supramolecular chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 25", "Publication Year": 2020, "Volume": 142, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19980, "End Page": 19991, "Article Number": null, "DOI": "10.1021/jacs.0c08592", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c08592", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000595544800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paniagua-Domínguez, R; Yu, YF; Miroshnichenko, AE; Krivitsky, LA; Fu, YH; Valuckas, V; Gonzaga, L; Toh, YT; Kay, AYS; Luk'yanchuk, B; Kuznetsov, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paniagua-Dominguez, Ramon; Yu, Ye Feng; Miroshnichenko, Andrey E.; Krivitsky, Leonid A.; Fu, Yuan Hsing; Valuckas, Vytautas; Gonzaga, Leonard; Toh, Yeow Teck; Kay, Anthony Yew Seng; Luk'yanchuk, Boris; Kuznetsov, Arseniy I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generalized Brewster effect in dielectric metasurfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polarization is a key property defining the state of light. It was discovered by Brewster, while studying light reflected from materials at different angles. This led to the first polarizers, based on Brewster's effect. Now, one of the trends in photonics is the study of miniaturized devices exhibiting similar, or improved, functionalities compared with bulk optical elements. In this work, it is theoretically predicted that a properly designed all-dielectric metasurface exhibits a generalized Brewster's effect potentially for any angle, wavelength and polarization of choice. The effect is experimentally demonstrated for an array of silicon nullodisks at visible wavelengths. The underlying physics is related to the suppressed scattering at certain angles due to the interference between the electric and magnetic dipole resonullces excited in the nulloparticles. These findings open doors for Brewster phenomenon to new applications in photonics, which are not bonded to a specific polarization or angle of incidence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10362, "DOI": "10.1038/ncomms10362", "DOI Link": "http://dx.doi.org/10.1038/ncomms10362", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369018900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZN; Abate, A; Watthage, SC; Liyanage, GK; Phillips, AB; Steiner, U; Graetzel, M; Heben, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Zhaoning; Abate, Antonio; Watthage, Suneth C.; Liyanage, Geethika K.; Phillips, Adam B.; Steiner, Ullrich; Graetzel, Michael; Heben, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite Solar Cell Stability in Humid Air: Partially Reversible Phase Transitions in the PbI2-CH3NH3I-H2O System", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "After rapid progress over the past five years, organic-inorganic perovskite solar cells (PSCs) currently exhibit photoconversion efficiencies comparable to the best commercially available photovoltaic technologies. However, instabilities in the materials and devices, primarily due to reactions with water, have kept PSCs from entering the marketplace. Here, laser beam induced current imaging is used to investigate the spatial and temporal evolution of the quantum efficiency of perovskite solar cells under controlled humidity conditions. Several interesting mechanistic aspects are revealed as the degradation proceeds along a four-stage process. Three of the four stages can be reversed, while the fourth stage leads to irreversible decomposition of the photoactive perovskite material. A series of reactions in the PbI2-CH3NH3I-H2O system explains the interplay between the interactions with water and the overall stability. Understanding of the degradation mechanisms of PSCs on a microscopic level gives insight into improving the long-term stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2016, "Volume": 6, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600846, "DOI": "10.1002/aenm.201600846", "DOI Link": "http://dx.doi.org/10.1002/aenm.201600846", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387134800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HY; Wu, H; Zhang, J; Liu, YJ; Chen, DD; Pandey, C; Yin, JL; Wei, DH; Lei, N; Shi, SY; Lu, HC; Li, P; Fert, A; Wang, KL; Nie, TX; Zhao, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Haiyu; Wu, Hao; Zhang, Jie; Liu, Yingjie; Chen, Dongdong; Pandey, Chandan; Yin, Jialiang; Wei, Dahai; Lei, Na; Shi, Shuyuan; Lu, Haichang; Li, Peng; Fert, Albert; Wang, Kang L.; Nie, Tianxiao; Zhao, Weisheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature energy-efficient spin-orbit torque switching in two-dimensional van der Waals Fe3GeTe2 induced by topological insulators", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) ferromagnetic materials with unique magnetic properties have great potential for next-generation spintronic devices with high flexibility, easy controllability, and high heretointegrability. However, realizing magnetic switching with low power consumption at room temperature is challenging. Here, we demonstrate the room-temperature spin-orbit torque (SOT) driven magnetization switching in an all-van der Waals (vdW) heterostructure using an optimized epitaxial growth approach. The topological insulator Bi2Te3 not only raises the Curie temperature of Fe3GeTe2 (FGT) through interfacial exchange coupling but also works as a spin current source allowing the FGT to switch at a low current density of similar to 2.2x10(6) A/cm(2). The SOT efficiency is similar to 2.69, measured at room temperature. The temperature and thickness-dependent SOT efficiency prove that the larger SOT in our system mainly originates from the nontrivial topological origin of the heterostructure. Our experiments enable an all-vdW SOT structure and provides a solid foundation for the implementation of room-temperature all-vdW spintronic devices in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5173, "DOI": "10.1038/s41467-023-40714-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40714-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054501000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Rubel, MHK; Toki, GFI; Alam, I; Rahman, MF; Bencherif, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Rubel, Mirza Humaun Kabir; Toki, G. F. Ishraque; Alam, Intekhab; Rahman, Md. Ferdous; Bencherif, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Various Electron and Hole Transport Layers on the Performance of CsPbI3-Based Perovskite Solar Cells: A Numerical Investigation in DFT, SCAPS-1 D, and wxAMPS Frameworks", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CsPbI3 has recently received tremendous attention as a possible absorber of perovskite solar cells (PSCs). However, CsPbI3-based PSCs have yet to achieve the high performance of the hybrid PSCs. In this work, we performed a density functional theory (DFT) study using the Cambridge Serial Total Energy Package (CASTEP) code for the cubic CsPbI3 absorber to compare and evaluate its structural, electronic, and optical properties. The calculated electronic band gap (E-g) using the GGA-PBE approach of CASTEP was 1.483 eV for this CsPbI3 absorber. Moreover, the computed density of states (DOS) exhibited the dominullt contribution from the Pb-5d orbital, and most charges also accumulated for the Pb atom as seen from the electronic charge density map. Fermi surface calculation showed multiband character, and optical properties were computed to investigate the optical response of CsPbI3. Furthermore, we used IGZO, SnO2, WS2, CeO2, PCBM, TiO2, ZnO, and C-60 as the electron transport layers (ETLs) and Cu2O, CuSCN, CuSbS2, Spiro-MeOTAD, V2O5, CBTS, CFTS, P3HT, PEDOT:PSS, NiO, CuO, and CuI as the hole transport layers (HTLs) to identify the best HTL/CsPbI3/ETL combinations using the SCAPS-1D solar cell simulation software. Among 96 device structures, the best-optimized device structure, ITO/TiO2/CsPbI3/CBTS/Au, was identified, which exhibited an efficiency of 17.9%. The effect of the absorber and ETL thickness, series resistance, shunt resistance, and operating temperature was also evaluated for the six best devices along with their corresponding generation rate, recombination rate, capacitance-voltage, current density-voltage, and quantum efficiency characteristics. The obtained results from SCAPS-1D were also compared with wxAMPS simulation results.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2022, "Volume": 7, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 43210, "End Page": 43230, "Article Number": null, "DOI": "10.1021/acsomega.2c05912", "DOI Link": "http://dx.doi.org/10.1021/acsomega.2c05912", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000885779000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avsar, A; Tan, JY; Taychatanapat, T; Balakrishnull, J; Koon, GKW; Yeo, Y; Lahiri, J; Carvalho, A; Rodin, AS; O'Farrell, ECT; Eda, G; Neto, AHC; Özyilmaz, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avsar, A.; Tan, J. Y.; Taychatanapat, T.; Balakrishnull, J.; Koon, G. K. W.; Yeo, Y.; Lahiri, J.; Carvalho, A.; Rodin, A. S.; O'Farrell, E. C. T.; Eda, G.; Castro Neto, A. H.; Oezyilmaz, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-orbit proximity effect in graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of spintronics devices relies on efficient generation of spin-polarized currents and their electric-field-controlled manipulation. While observation of exceptionally long spin relaxation lengths makes graphene an intriguing material for spintronics studies, electric field modulation of spin currents is almost impossible due to negligible intrinsic spin-orbit coupling of graphene. In this work, we create an artificial interface between monolayer graphene and few-layer semiconducting tungsten disulphide. In these devices, we observe that graphene acquires spin-orbit coupling up to 17 meV, three orders of magnitude higher than its intrinsic value, without modifying the structure of the graphene. The proximity spin-orbit coupling leads to the spin Hall effect even at room temperature, and opens the door to spin field effect transistors. We show that intrinsic defects in tungsten disulphide play an important role in this proximity effect and that graphene can act as a probe to detect defects in semiconducting surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4875, "DOI": "10.1038/ncomms5875", "DOI Link": "http://dx.doi.org/10.1038/ncomms5875", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342983300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, CR; Yang, M; Fang, YJ; Luo, YF; Gao, SH; Xiao, XH; An, ZW; Zhou, BH; Zhang, B; Tan, XY; Yeang, HY; Qin, YX; Yang, JH; Lin, Q; Mei, HL; Montoro, P; Long, XY; Qi, JY; Hua, YW; He, ZL; Sun, M; Li, WJ; Zeng, X; Cheng, H; Liu, Y; Yang, J; Tian, WM; Zhuang, NS; Zeng, RZ; Li, DJ; He, P; Li, Z; Zou, Z; Li, SL; Li, CJ; Wang, JX; Wei, D; Lai, CQ; Luo, W; Yu, J; Hu, SN; Huang, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Chaorong; Yang, Meng; Fang, Yongjun; Luo, Yingfeng; Gao, Shenghan; Xiao, Xiaohu; An, Zewei; Zhou, Binhui; Zhang, Bing; Tan, Xinyu; Yeang, Hoong-Yeet; Qin, Yunxia; Yang, Jianghua; Lin, Qiang; Mei, Hailiang; Montoro, Pascal; Long, Xiangyu; Qi, Jiyan; Hua, Yuwei; He, Zilong; Sun, Min; Li, Wenjie; Zeng, Xia; Cheng, Han; Liu, Ying; Yang, Jin; Tian, Weimin; Zhuang, nullsheng; Zeng, Rizhong; Li, Dejun; He, Peng; Li, Zhe; Zou, Zhi; Li, Shuangli; Li, Chenji; Wang, Jixiang; Wei, Dong; Lai, Chao-Qiang; Luo, Wei; Yu, Jun; Hu, Songnian; Huang, Huasun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The rubber tree genome reveals new insights into rubber production and species adaptation", "Source Title": "NATURE PLANTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Para rubber tree (Hevea brasiliensis) is an economically important tropical tree species that produces natural rubber, an essential industrial raw material. Here we present a high-quality genome assembly of this species (1.37 Gb, scaffold N50 = 1.28 Mb) that covers 93.8% of the genome (1.47 Gb) and harbours 43,792 predicted protein-coding genes. A striking expansion of the REF/SRPP (rubber elongation factor/small rubber particle protein) gene family and its divergence into several laticifer-specific isoforms seem crucial for rubber biosynthesis. The REF/SRPP family has isoforms with sizes similar to or larger than SRPP1 (204 amino acids) in 17 other plants examined, but no isoforms with similar sizes to REF1 (138 amino acids), the predominullt molecular variant. A pivotal point in Hevea evolution was the emergence of REF1, which is located on the surface of large rubber particles that account for 93% of rubber in the latex (despite constituting only 6% of total rubber particles, large and small). The stringent control of ethylene synthesis under active ethylene signalling and response in laticifers resolves a longstanding mystery of ethylene stimulation in rubber production. Our study, which includes the re-sequencing of five other Hevea cultivars and extensive RNA-seq data, provides a valuable resource for functional genomics and tools for breeding elite Hevea cultivars.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16073, "DOI": "10.1038/NPLANTS.2016.73", "DOI Link": "http://dx.doi.org/10.1038/NPLANTS.2016.73", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Plant Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380346000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZY; Lu, L; Sang, M; Wu, JP; Wang, XY; Xu, F; Gong, XL; Luo, TZ; Leung, KCF; Xuan, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Ziyang; Lu, Liang; Sang, Min; Wu, Jianpeng; Wang, Xinyi; Xu, Feng; Gong, Xinglong; Luo, Tianzhi; Leung, Ken Cham-Fai; Xuan, Shouhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable Safeguarding Leather Composite with Excellent Sensing, Thermal Management, and Electromagnetic Interference Shielding", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work illustrates a soft-toughness coupling design method to integrate the shear stiffening gel (SSG), natural leather, and nonwoven fabrics (NWF) for preparing leather/MXene/SSG/NWF (LMSN) composite with high anti-impact protecting, piezoresistive sensing, electromagnetic interference (EMI) shielding, and human thermal management performance. Owing to the porous fiber structure of the leather, the MXene nullosheets can penetrate leather to construct a stable 3D conductive network; thus both the LM and LMSN composites exhibit superior conductivity, high Joule heating temperature, and an efficient EMI shielding effectiveness. Due to the excellent energy absorption of the SSG, the LMSN composites possess a huge force-buffering (about 65.5%), superior energy dissipation (above 50%), and a high limit penetration velocity of 91 m s(-1), showing extraordinary anti-impact performance. Interestingly, LMSN composites possess an unconventional opposite sensing behavior to piezoresistive sensing (resistance reduction) and impact stimulation (resistance growing), thus they can distinguish the low and high energy stimulus. Ultimately, a soft protective vest with thermal management and impact monitoring performance is further fabricated, and it shows a typical wireless impact-sensing performance. This method is expected to have broad application potential in the next-generation wearable electronic devices for human safeguarding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 10, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302412", "DOI Link": "http://dx.doi.org/10.1002/advs.202302412", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022128000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CF; Ma, DW; Yang, J; Manawan, M; Zhao, T; Feng, YY; Li, JH; Liu, ZZ; Zhang, YW; Von Dreele, RB; Toby, BH; Albarrán, CPD; Pan, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chengfu; Ma, Dongwei; Yang, Jing; Manawan, Maykel; Zhao, Ting; Feng, Yuanyuan; Li, Jiahui; Liu, Zhongzhu; Zhang, Yong-Wei; Von Dreele, Robert B.; Toby, Brian H.; Albarran, Carlos Ponce de Leon; Pan, Jia Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystallographic Insight of Reduced Lattice Volume Expansion in Mesoporous Cu2+-Doped TiNb2O7 Microspheres during Li+ Insertion", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TiNb2O7 represents a promising anode material for lithium-ion batteries (LIBs), but its practical applications are currently hampered by the non-negligible volumetric expansion and contraction during the charge/discharge process and the sluggish ion/electron kinetics. A combination technique is reported by systematically optimizing the porous and spherical morphology, crystal structure, and surface decoration of mesoporous Cu2+-doped TiNb2O7 microspheres to enhance the electrochemical Li+ storage performance and stability simultaneously. The Cu2+ dopants preferentially replace Ti4+ in crystal lattices, which decreases the Li+ diffusion barrier and increases the electronic conductivity, as confirmed by density functional theory (DFT) calculation and demonstrated by diverse electrochemical characterizations. The successful Cu2+ doping significantly reduces the lattice expansion coefficient from 7.26% to 4.61% after Li+ insertion along the b-axis of TiNb2O7, as visualized from in situ and ex situ XRD analysis. The optimal 5% Cu2+-doped TiNb2O7 with surface coating of N-doped carbon exhibits significantly enhanced specific capacity and rate and cyclic performances in both half- and full-cell configurations, demonstrating an excellent electrochemical behavior for fast-charging LIB applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 33, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202212854", "DOI Link": "http://dx.doi.org/10.1002/adfm.202212854", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000920565200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XD; Li, L; Chen, GB; Chu, XY; Liu, XH; Naisa, C; Pohl, D; Löffler, M; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaodong; Li, Li; Chen, Guangbo; Chu, Xingyuan; Liu, Xiaohui; Naisa, Chandrasekhar; Pohl, Darius; Loeffler, Markus; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accessing parity-forbidden d-d transitions for photocatalytic CO2 reduction driven by infrared light", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A general approach to promote IR light-driven CO2 reduction within ultrathin Cu-based hydrotalcite-like hydroxy salts is presented. Associated band structures and optical properties of the Cu-based materials are first predicted by theory. Subsequently, Cu-4(SO4)(OH)(6) nullosheets were synthesized and are found to undergo cascaded electron transfer processes based on d-d orbital transitions under infrared light irradiation. The obtained samples exhibit excellent activity for IR light-driven CO2 reduction, with a production rate of 21.95 and 4.11 & mu;mol g(-1) h(-1) for CO and CH4, respectively, surpassing most reported catalysts under the same reaction conditions. X-ray absorption spectroscopy and in situ Fourier-transform infrared spectroscopy are used to track the evolution of the catalytic sites and intermediates to understand the photocatalytic mechanism. Similar ultrathin catalysts are also investigated to explore the generality of the proposed electron transfer approach. Our findings illustrate that abundant transition metal complexes hold great promise for IR light-responsive photocatalysis. This study demonstrates the effectiveness and generality of utilizing ultrathin Cu-based hydrotalcite-like hydroxy salts as catalysts for infrared light-driven CO2 reduction based on their d-d orbital transition mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39666-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39666-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001025309600021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, RY; Chen, M; Zhou, H; Liu, T; Tang, XW; Zhang, K; Zhu, HX; Ye, JH; Zhang, D; Fan, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Runyu; Chen, Min; Zhou, Han; Liu, Tian; Tang, Xingwei; Zhang, Ke; Zhu, Hanxing; Ye, Jinhua; Zhang, Di; Fan, Tongxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-inspired Plasmonic nulloarchitectured Hybrid System Towards Enhanced Far Red-to-Near Infrared Solar Photocatalysis", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar conversion to fuels or to electricity in semiconductors using far red-to-near infrared (NIR) light, which accounts for about 40% of solar energy, is highly significant. One main challenge is the development of novel strategies for activity promotion and new basic mechanisms for NIR response. Mother Nature has evolved to smartly capture far red-to-NIR light via their intelligent systems due to unique micro/nulloarchitectures, thus motivating us for biomimetic design. Here we report the first demonstration of a new strategy, based on adopting nature's far red-to-NIR responsive architectures for an efficient bio-inspired photocatalytic system. The system is constructed by controlled assembly of light-harvesting plasmonic nulloantennas onto a typical photocatalytic unit with butterfly wings' 3D micro/nulloarchitectures. Experiments and finite-difference time-domain (FDTD) simulations demonstrate the structural effects on obvious far red-to-NIR photocatalysis enhancement, which originates from (1) Enhancing far red-to-NIR (700 similar to 1200 nm) harvesting, up to 25%. (2) Enhancing electric-field amplitude of localized surface plasmon (LSPs) to more than 3.5 times than that of the non-structured one, which promotes the rate of electron-hole pair formation, thus substantially reinforcing photocatalysis. This proof-of-concept study provides a new methodology for NIR photocatalysis and would potentially guide future conceptually new NIR responsive system designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20001, "DOI": "10.1038/srep20001", "DOI Link": "http://dx.doi.org/10.1038/srep20001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368777800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, LF; Xia, YD; Duan, XZ; Wang, Y; Ran, CX; Niu, TT; Gu, L; Li, DL; Hu, JF; Gao, XY; Zhang, J; Chen, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Lingfeng; Xia, Yingdong; Duan, Xiaozheng; Wang, Yue; Ran, Chenxin; Niu, Tingting; Gu, Lei; Li, Deli; Hu, Jianfei; Gao, Xingyu; Zhang, Jing; Chen, Yonghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct and stable α-phase formation via ionic liquid solvation for formamidinium-based perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct and stable alpha-phase formation of formamidinium lead triiodide (FAPbI(3)) perovskite serves as an indispensable prerequisite for constructing stable and efficient perovskite solar cells. However, the alpha-phase formation is highly limited by molecular additives. Here, we report a strategy for directly fabricating stable alpha-phase of FAPbI(3) perovskite by controlling the precursor solution on the molecular level using methylammonium acetate (MAAc) ionic liquid. We found that a strong interaction between Ac- and Pb2+ via C=O center dot center dot center dot Pb chelation enables the relaxation of Pb-I bonds and thus allows the effective insertion of formamidinium iodide (FAI) into soft Pb-I framework. Molecular dynamics simulations also show that the precursor solution has undergone an exchange of coordination between I- and Ac- to provide the reaction sites for FAI. With a one-step, antisolvent-treatment-free, and air-processing approach regardless of humidity, the corresponding photovoltaic cell exhibits an efficiency close to 24% along with long operational stability over 1,000 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2022, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2203, "End Page": 2217, "Article Number": null, "DOI": "10.1016/j.joule.2022.07.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.07.008", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000864999300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reddy, CV; Nagar, A; Shetti, NP; Reddy, IN; Basu, S; Shim, J; Kakarla, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reddy, Ch. Venkata; Nagar, Aashna; Shetti, Nagaraj P.; Reddy, I. Neelakanta; Basu, Soumen; Shim, Jaesool; Kakarla, Raghava Reddy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel g-C3N4/BiVO4 heterostructured nullohybrids for high efficiency photocatalytic degradation of toxic chemical pollutants", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel heterostructured hybrid catalysts are essential for the efficient photocatalytic removal of organic pollutants from wastewater generated by the pharmaceutical and textile industries. In this study, novel g-C3N4/BiVO4 nullohybrid catalysts were prepared using a solvothermal technique, and examined their structural and optical properties using different characterizations. The X-ray diffraction analysis confirmed the monoclinic crystal phase of BiVO4. Field emission scanning electron microscopy (FESEM) images revealed that g-C3N4 sheets anchored on the surface of BiVO4 nullospheres. X-ray photoelectron spectroscopy (XPS) analysis confirmed the oxidation states of g-C3N4/BiVO4 composite sample. UV-Vis DRS spectroscopy analysis revealed that the composite (2.08 eV) sample had a reduced bandgap compared to other samples. The photocatalytic properties of the prepared samples were tested in the presence of organic methylene blue (MB) and antibiotic tetracycline (TC) pollutants under visible light illumination. The hybrid composite catalyst exhibited enhanced photocatalytic degradation efficiency of MB (88%) and TC (89%) pollutants at elevated rate constants of 0.0128 and 0.01174 min(-1), respectively. The improved catalytic performance of the composite catalyst is due to the heterojunctions between g-C3N4 and BiVO4 that successfully reduced the rate of charge carrier recombination in the catalyst system. Scavenger experiments revealed that O-2(center dot-) and h(+) radicals played a main role in the degradation of the chemical pollutants. The developed g-C3N4/BiVO4 heterostructured catalyst is a suitable candidate for removing contaminullts from industrial wastewater because of its facile fabrication and exceptional photocatalytic activity under visible light irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 322, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 138146, "DOI": "10.1016/j.chemosphere.2023.138146", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2023.138146", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000944803400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LQ; Yu, HT; Chen, C; He, QX; Zhang, H; Zhao, FL; Qin, MM; Feng, YY; Feng, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lianqiang; Yu, Huitao; Chen, Can; He, Qingxia; Zhang, Heng; Zhao, Fulai; Qin, Mengmeng; Feng, Yiyu; Feng, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring Dense, Orientation-Tunable, and Interleavedly Structured Carbon-Based Heat Dissipation Plates", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The controllability of the microstructure of a compressed hierarchical building block is essential for optimizing a variety of performance parameters, such as thermal management. However, owing to the strong orientation effect during compression molding, optimizing the alignment of materials perpendicular to the direction of pressure is challenging. Herein, to illustrate the effect of the ordered microstructure on heat dissipation, thermally conductive carbon-based materials are fabricated by tailoring dense, orientation-tunable, and interleaved structures. Vertically aligned carbon nullotube arrays (VACNTs) interconnected with graphene films (GF) are prepared as a 3D core-ordered material to fabricate compressed building blocks of O-VA-GF and S-VA-GF. Leveraging the densified interleaved structure offered by VACNTs, the hierarchical O-VA-GF achieves excellent through-plane (41.7 W m(-1) K-1) and in-plane (397.9 W m(-1) K-1) thermal conductivities, outperforming similar composites of S-VA-GF (through-plane: 10.3 W m(-1) K-1 and in-plane: 240.9 W m(-1) K-1) with horizontally collapsed carbon nullotubes. As heat dissipation plates, these orderly assembled composites yield a 144% and 44% enhancement in the cooling coefficient compared with conventional Si3N4 for cooling high-power light-emitting diode chips.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 40, "Times Cited, All Databases": 41, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205962", "DOI Link": "http://dx.doi.org/10.1002/advs.202205962", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909839300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZH; Cui, T; Hutcheon, MJ; Shipley, AM; Song, H; Du, MY; Kresin, VZ; Duan, DF; Pickard, CJ; Yao, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zihan; Cui, Tian; Hutcheon, Michael J.; Shipley, Alice M.; Song, Hao; Du, Mingyang; Kresin, Vladimir Z.; Duan, Defang; Pickard, Chris J.; Yao, Yansun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design Principles for High-Temperature Superconductors with a Hydrogen-Based Alloy Backbone at Moderate Pressure", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen-based superconductors provide a route to the long-sought goal of room-temperature superconductivity, but the high pressures required to metallize these materials limit their immediate application. For example, carbonaceous sulfur hydride, the first room-temperature superconductor made in a laboratory, can reach a critical temperature (Tc) of 288 K only at the extreme pressure of 267 GPa. The next recognized challenge is the realization of room-temperature superconductivity at significantly lower pressures. Here, we propose a strategy for the rational design of high-temperature superconductors at low pressures by alloying small-radius elements and hydrogen to form ternary H-based superconductors with alloy backbones. We identify a fluorite-type backbone in compositions of the form AXH8, which exhibit high-temperature superconductivity at moderate pressures compared with other reported hydrogen-based superconductors. The Fm3 over bar m phase of LaBeH8, with a fluorite-type H-Be alloy backbone, is predicted to be thermodynamically stable above 98 GPa, and dynamically stable down to 20 GPa with a high Tc similar to 185 K. This is substantially lower than the synthesis pressure required by the geometrically similar clathrate hydride LaH10 (170 GPa). Our approach paves the way for finding high-Tc ternary H-based superconductors at conditions close to ambient pressures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2022, "Volume": 128, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 47001, "DOI": "10.1103/PhysRevLett.128.047001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.128.047001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749496800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pérez-Gallent, E; Marcandalli, G; Figueiredo, MC; Calle-Vallejo, F; Koper, MTM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perez-Gallent, Elena; Marcandalli, Giulia; Figueiredo, Marta Costa; Calle-Vallejo, Federico; Koper, Marc T. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure- and Potential-Dependent Cation Effects on CO Reduction at Copper Single-Crystal Electrodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The complexity of the electrocatalytic reduction of CO to CH4 and C2H4 on copper electrodes prevents a straightforward elucidation of the reaction mechanism and the design of new and better catalysts. Although structural and electrolyte effects have been separately studied, there are no reports on structure-sensitive cation effects on the catalysts selectivity over a wide potential range. Therefore, we investigated CO reduction on Cu(100), Cu(111), and Cu(polycrystalline) electrodes in 0.1 M alkaline hydroxide electrolytes (LiOH, NaOH, KOH, RbOH, CsOH) between 0 and -1.5 V vs RHE. We used online electrochemical mass spectrometry and high-performance liquid chromatography to determine the product distribution as a function of electrode structure, cation size, and applied potential. First, cation effects are potential dependent, as larger cations increase the selectivity of all electrodes toward ethylene at E > -0.45 V vs RHE, but methane is favored at more negative potentials. Second, cation effects are structure-sensitive, as the onset potential for C2H4 formation depends on the electrode structure and cation size, whereas that for CH4 does not. Fourier Transform infrared spectroscopy (FTIR) and density functional theory help to understand how cations favor ethylene over methane at low overpotentials on Cu(100). The rate-determining step to methane and ethylene formation is CO hydrogenation, which is considerably easier in the presence of alkaline cations for a CO dimer compared to a CO monomer. For Li+ and Na+, the stabilization is such that hydrogenated dimers are observable with FTIR at low overpotentials. Thus, potential-dependent, structure-sensitive cation effects help steer the selectivity toward specific products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 139, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16412, "End Page": 16419, "Article Number": null, "DOI": "10.1021/jacs.7b10142", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b10142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415785900058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Zhang, JM; Hu, BR; Liang, QW; Xiong, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chao; Zhang, Jiaming; Hu, Benrui; Liang, Qianwen; Xiong, Xunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic gel as artificial interphase layer for ultrahigh-rate and large-capacity lithium metal anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing a stable artificial solid-electrolyte interphase has become one of the most effective strategies to overcome the poor reversibility of lithium metal anode, yet the protection role is still insufficient at elevated current densities over 10 mA cm(-2) and large areal capacities over 10 mAh cm(-2). Herein, we propose a dynamic gel with reversible imine groups, which is prepared via a cross linking reaction between flexible dibenzaldehyde-terminated telechelic poly(ethylene glycol) and rigid chitosan, to fabricate a protective layer for Li metal anode. The as-prepared artificial film shows combined merits of high Young's modulus, strong ductility and high ionic conductivity. When the artificial film is fabricated on a lithium metal anode, the thin protective layer shows a dense and uniform surface owing to the interactions between the abundant polar groups and lithium metal. Besides, the polar groups in the artificial film can homogenize the distribution of Li+ at the electrode/electrolyte interface. As a result, cycle stability over 3200 h under an areal capacity of 10 mAh cm(-2) and a current density of 10 mA cm(-2) has been obtained for the protected lithium metal anodes. Moreover, cycling stability and rate capability has been also improved in the full cells. Achieving stable lithium metal anodes under large current densities over 10 mA cm(-2) and area capacities over 10 mAh cm(-2) remains a critical challenge. Here, authors propose a dynamic gel as protect layer for lithium metal anode to facilitate with the Young's modulus, flexibility and ionic conductivity, thus to stabilize the lithium metal anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39636-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39636-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001025309600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Wang, Q; Wang, GW; Yuan, ZH; Song, WH; Lou, R; Liu, ZT; Huang, YB; Liu, ZH; Lei, HC; Yin, ZP; Wang, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Man; Wang, Qi; Wang, Guangwei; Yuan, Zhihong; Song, Wenhua; Lou, Rui; Liu, Zhengtai; Huang, Yaobo; Liu, Zhonghao; Lei, Hechang; Yin, Zhiping; Wang, Shancai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac cone, flat band and saddle point in kagome magnet YMn6Sn6", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Kagome-lattices of 3d-transition metals hosting Weyl/Dirac fermions and topological flat bands exhibit non-trivial topological characters and novel quantum phases, such as the anomalous Hall effect and fractional quantum Hall effect. With consideration of spin-orbit coupling and electron correlation, several instabilities could be induced. The typical characters of the electronic structure of a kagome lattice, i.e., the saddle point, Dirac-cone, and flat band, around the Fermi energy (E-F) remain elusive in magnetic kagome materials. We present the experimental observation of the complete features in ferromagnetic kagome layers of YMn6Sn6 helically coupled along the c-axis, by using angle-resolved photoemission spectroscopy and band structure calculations. We demonstrate a Dirac dispersion near E-F, which is predicted by spin-polarized theoretical calculations, carries an intrinsic Berry curvature and contributes to the anomalous Hall effect in transport measurements. In addition, a flat band and a saddle point with a high density of states near E-F are observed. These multi-sets of kagome features are of orbital-selective origin and could cause multi-orbital magnetism. The Dirac fermion, flat band and saddle point in the vicinity of E-F open an opportunity in manipulating the topological properties in magnetic materials. The typical characters of the electronic structure of magnetic kagome materials remain elusive. Here, the authors observe a Dirac cone, a flat band and a saddle point near the Fermi energy in ferromagnetic kagome material YMn6Sn6.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3129, "DOI": "10.1038/s41467-021-23536-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23536-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658774600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Woods, LM; Dalvit, DAR; Tkatchenko, A; Rodriguez-Lopez, P; Rodriguez, AW; Podgornik, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Woods, L. M.; Dalvit, D. A. R.; Tkatchenko, A.; Rodriguez-Lopez, P.; Rodriguez, A. W.; Podgornik, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Materials perspective on Casimir and van der Waals interactions", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interactions induced by electromagnetic fluctuations, such as van der Waals and Casimir forces, are of universal nature present at any length scale between any types of systems. Such interactions are important not only for the fundamental science of materials behavior, but also for the design and improvement of micro- and nullostructured devices. In the past decade, many new materials have become available, which has stimulated the need for understanding their dispersive interactions. The field of van der Waals and Casimir forces has experienced an impetus in terms of developing novel theoretical and computational methods to provide new insights into related phenomena. The understanding of such forces has far reaching consequences as it bridges concepts in materials, atomic and molecular physics, condensed-matter physics, high-energy physics, chemistry, and biology. This review summarizes major breakthroughs and emphasizes the common origin of van der Waals and Casimir interactions. Progress related to novel ab initio modeling approaches and their application in various systems, interactions in materials with Dirac-like spectra, force manipulations through nontrivial boundary conditions, and applications of van der Waals forces in organic and biological matter are examined. The outlook of the review is to give the scientific community a materials perspective of van der Waals and Casimir phenomena and stimulate the development of experimental techniques and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2016, "Volume": 88, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45003, "DOI": "10.1103/RevModPhys.88.045003", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.88.045003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386653300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singh, MR; Clark, EL; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singh, Meenesh R.; Clark, Ezra L.; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of electrolyte, catalyst, and membrane composition and operating conditions on the performance of solar-driven electrochemical reduction of carbon dioxide", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven electrochemical cells can be used to convert carbon dioxide, water, and sunlight into transportation fuels or into precursors to such fuels. The voltage efficiency of such devices depends on the (i) physical properties of its components (catalysts, electrolyte, and membrane); (ii) operating conditions (carbon dioxide flowrate and pressure, current density); and (iii) physical dimensions of the cell. The sources of energy loss in a carbon dioxide reduction (CO2R) cell are the anode and cathode overpotentials, the difference in pH between the anode and cathode, the difference in the partial pressure of carbon dioxide between the bulk electrolyte and the cathode, the ohmic loss across the electrolyte and the diffusional resistances across the boundary layers near the electrodes. In this study, we analyze the effects of these losses and propose optimal device configurations for the efficient operation of a CO2R electrochemical cell operating at a current density of 10 mA cm(-2). Cell operation at near-neutral bulk pH offers not only lower polarization losses but also better selectivity to CO2R versus hydrogen evolution. Addition of supporting electrolyte to increase its conductivity has a negative impact on cell performance because it reduces the electric field and the solubility of CO2. Addition of a pH buffer reduces the polarization losses but may affect catalyst selectivity. The carbon dioxide flowrate and partial pressure can have severe effects on the cell efficiency if the carbon dioxide supply rate falls below the consumption rate. The overall potential losses can be reduced by use of an anion, rather than a cation, exchange membrane. We also show that the maximum polarization losses occur for the electrochemical synthesis of CO and that such losses are lower for the synthesis of products requiring a larger number of electrons per molecule, assuming a fixed current density. We also find that the reported electrocatalytic activity of copper below -1 V vs. RHE is strongly influenced by excessive polarization of the cathode and, hence, does not represent its true activity at bulk conditions. This article provides useful guidelines for minimizing polarization losses in solar-driven CO2R electrochemical cells and a method for predicting polarization losses and obtaining kinetic overpotentials from measured partial current densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 17, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18924, "End Page": 18936, "Article Number": null, "DOI": "10.1039/c5cp03283k", "DOI Link": "http://dx.doi.org/10.1039/c5cp03283k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358207400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Q; Goia, S; Yang, J; Hall, SCL; Staniforth, M; Stavros, VG; Perrier, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Qiao; Goia, Sofia; Yang, Jie; Hall, Stephen C. L.; Staniforth, Michael; Stavros, Vasilios G.; Perrier, Sebastien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Artificial Light-Harvesting System Based on Supramolecular Peptide nullotubes in Water", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial light-harvesting systems in aqueous media which mimic nature are of significant importance; however, they are often restrained by the solubility and the undesired aggregation-caused quenching effect of the hydrophobic chromophores. Here, we report a generalized strategy toward the construction of efficient artificial light-harvesting systems based on supramolecular peptide nullotubes in water. By molecularly aligning the hydrophobic chromophores along the nullotubes in a slipped manner, an artificial light-harvesting system with a two-step sequential Forster resonullce energy transfer process is successfully fabricated, showing an energy transfer efficiency up to 95% and a remarkably high fluorescence quantum yield of 30%, along with high stability. Furthermore, the spectral emission could be continuously tuned from blue through green to orange, as well as outputted as a white light continuum with a fluorescence quantum yield of 29.9%. Our findings provide a versatile approach of designing efficient artificial light-harvesting systems and constructing highly emissive organic materials in aqueous media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2021, "Volume": 143, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 382, "End Page": 389, "Article Number": null, "DOI": "10.1021/jacs.0c11060", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c11060", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000611083700047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Garello, K; Avci, CO; Miron, IM; Baumgartner, M; Ghosh, A; Auffret, S; Boulle, O; Gaudin, G; Gambardella, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garello, Kevin; Avci, Can Onur; Miron, Ioan Mihai; Baumgartner, Manuel; Ghosh, Abhijit; Auffret, Stephane; Boulle, Olivier; Gaudin, Gilles; Gambardella, Pietro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast magnetization switching by spin-orbit torques", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-orbit torques induced by spin Hall and interfacial effects in heavy metal/ferromagnetic bilayers allow for a switching geometry based on in-plane current injection. Using this geometry, we demonstrate deterministic magnetization reversal by current pulses ranging from 180 ps to ms in Pt/Co/AlOx dots with lateral dimensions of 90 nm. We characterize the switching probability and critical current I-c as a function of pulse length, amplitude, and external field. Our data evidence two distinct regimes: a short-time intrinsic regime, where I-c scales linearly with the inverse of the pulse length, and a long-time thermally assisted regime, where I-c varies weakly. Both regimes are consistent with magnetization reversal proceeding by nucleation and fast propagation of domains. We find that I-c is a factor 3-4 smaller compared to a single domain model and that the incubation time is negligibly small, which is a hallmark feature of spin-orbit torques. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2014, "Volume": 105, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 212402, "DOI": "10.1063/1.4902443", "DOI Link": "http://dx.doi.org/10.1063/1.4902443", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345639400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QP; Su, WY; Chen, SS; Kim, W; Chen, XB; Lee, B; Liu, T; Méndez-Romero, UA; Ma, RJ; Yang, T; Zhuang, WL; Li, Y; Li, YW; Kim, TS; Hou, LT; Yang, C; Yan, H; Yu, DH; Wang, EG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Qunping; Su, Wenyan; Chen, Shanshan; Kim, Wansun; Chen, Xiaobin; Lee, Byongkyu; Liu, Tao; Mendez-Romero, Ulises A.; Ma, Ruijie; Yang, Tao; Zhuang, Wenliu; Li, Yu; Li, Yaowen; Kim, Taek-Soo; Hou, Lintao; Yang, Changduk; Yan, He; Yu, Donghong; Wang, Ergang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically Robust All-Polymer Solar Cells from Narrow Band Gap Acceptors with Hetero-Bridging Atoms", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We developed three narrow band-gap polymer acceptors PF2-DTC, PF2-DTSi, and PF2-DTGe with different bridging atoms (i.e., C, Si, and Ge). Studies found that such different bridging atoms significantly affect the crystallinity, extinction coefficient, electron mobility of the polymer acceptors, and the morphology and mechanical robustness of related active layers. In all-polymer solar cells (all-PSCs), these polymer acceptors achieved high power conversion efficiencies (PCEs) over 8.0%, while PF2-DTSi obtained the highest PCE of 10.77% due to its improved exciton dissociation, charge transport, and optimized morphology. Moreover, the PF2-DTSi-based active layer showed excellent mechanical robustness with a high toughness value of 9.3 MJ m(-3) and a large elongation at a break of 8.6%, which is a great advantage for the practical applications of flexible devices. As a result, the PF2-DTSi-based flexible all-PSC retained >90% of its initial PCE (6.37%) after bending and relaxing 1,200 times at a bending radius of similar to 4 mm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2020, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 658, "End Page": 672, "Article Number": null, "DOI": "10.1016/j.joule.2020.01.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.01.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520874200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; An, HY; Arnouts, S; Wang, H; Yu, X; de Ruiter, J; Bals, S; Altantzis, T; Weckhuysen, BM; van der Stam, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuang; An, Hongyu; Arnouts, Sven; Wang, Hui; Yu, Xiang; de Ruiter, Jim; Bals, Sara; Altantzis, Thomas; Weckhuysen, Bert M.; van der Stam, Ward", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It remains a challenge to identify the active sites of bismuth catalysts in the electrochemical CO2 reduction reaction. Here we show through in situ characterization that the activation of bismuth oxyhalide electrocatalysts to metallic bismuth is guided by the halides. In situ X-ray diffraction results show that bromide promotes the selective exposure of planar bismuth surfaces, whereas chloride and iodide result in more disordered active sites. Furthermore, we find that bromide-activated bismuth catalysts outperform the chloride and iodide counterparts, achieving high current density (>100 mA cm(-2)) and formic acid selectivity (>90%), suggesting that planar bismuth surfaces are more active for the electrochemical CO2 reduction reaction. In addition, in situ X-ray absorption spectroscopy measurements reveal that the reconstruction proceeds rapidly in chloride-activated bismuth and gradually when bromide is present, facilitating the formation of ordered planar surfaces. These findings show the pivotal role of halogens on selective facet exposure in activated bismuth-based electrocatalysts during the electrochemical CO2 reduction reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 796, "End Page": 806, "Article Number": null, "DOI": "10.1038/s41929-023-01008-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-023-01008-0", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001050367400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hemmatpour, H; De Luca, O; Crestani, D; Stuart, MCA; Lasorsa, A; van der Wel, PCA; Loos, K; Giousis, T; Haddadi-Asl, V; Rudolf, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hemmatpour, Hamoon; De Luca, Oreste; Crestani, Dominic; Stuart, Marc C. A.; Lasorsa, Alessia; van der Wel, Patrick C. A.; Loos, Katja; Giousis, Theodosis; Haddadi-Asl, Vahid; Rudolf, Petra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New insights in polydopamine formation via surface adsorption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polydopamine is a biomimetic self-adherent polymer, which can be easily deposited on a wide variety of materials. Despite the rapidly increasing interest in polydopamine-based coatings, the polymerization mechanism and the key intermediate species formed during the deposition process are still controversial. Herein, we report a systematic investigation of polydopamine formation on halloysite nullotubes; the negative charge and high surface area of halloysite nullotubes favour the capture of intermediates that are involved in polydopamine formation and decelerate the kinetics of the process, to unravel the various polymerization steps. Data from X-ray photoelectron and solid-state nuclear magnetic resonullce spectroscopies demonstrate that in the initial stage of polydopamine deposition, oxidative coupling reaction of the dopaminechrome molecules is the main reaction pathway that leads to formation of polycatecholamine oligomers as an intermediate and the post cyclization of the linear oligomers occurs subsequently. Furthermore, TRIS molecules are incorporated into the initially formed oligomers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 664, "DOI": "10.1038/s41467-023-36303-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36303-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055384500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, NN; Yang, MW; Yang, Z; Chen, KY; Zhang, H; Zhang, QH; Zhu, ZH; Uwatoko, Y; Gu, L; Dong, XL; Sun, JP; Jin, KJ; Cheng, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, N. N.; Yang, M. W.; Yang, Z.; Chen, K. Y.; Zhang, H.; Zhang, Q. H.; Zhu, Z. H.; Uwatoko, Y.; Gu, L.; Dong, X. L.; Sun, J. P.; Jin, K. J.; Cheng, J-G", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-induced monotonic enhancement of Tc to over 30 K in superconducting Pr0.82Sr0.18NiO2 thin films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The successful synthesis of superconducting infinite-layer nickelate thin films with the highest T-c approximate to 15 K has ignited great enthusiasm for this material class as potential analogs of the high-T-c cuprates. Pursuing a higher T-c is always an imperative task in studying a new superconducting material system. Here we report high-quality Pr0.82Sr0.18NiO2 thin films with T-c(onset) approximate to 17 K synthesized by carefully tuning the amount of CaH2 in the topotactic chemical reduction and the effect of pressure on its superconducting properties by measuring electrical resistivity under various pressures in a cubic anvil cell apparatus. We find that the onset temperature of the superconductivity, T-c(onset), can be enhanced monotonically from similar to 17 K at ambient pressure to similar to 31 K at 12.1 GPa without showing signatures of saturation upon increasing pressure. This encouraging result indicates that the T-c of infinite-layer nickelates superconductors still has room to go higher and it can be further boosted by applying higher pressures or strain engineering in the heterostructure films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4367, "DOI": "10.1038/s41467-022-32065-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32065-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000833074200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, H; Qin, J; Wang, JJ; Sari, HMK; Lei, L; Xiao, W; Li, WB; Xie, C; Yang, HJ; Luo, YY; Zhang, GN; Li, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Hui; Qin, Jian; Wang, Jingjing; Sari, Hirbod Maleki Kheimeh; Lei, Li; Xiao, Wei; Li, Wenbin; Xie, Chong; Yang, Huijuan; Luo, Yangyang; Zhang, Gaini; Li, Xifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping-Induced Electronic/Ionic Engineering to Optimize the Redox Kinetics for Potassium Storage: A Case Study of Ni-Doped CoSe2", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heteroatom doping effectively tunes the electronic conductivity of transition metal selenides (TMSs) with rapid K+ accessibility in potassium ion batteries (PIBs). Although considerable efforts are dedicated to investigating the relationship between the doping strategy and the resulting electrochemistry, the doping mechanisms, especially in view of the ion and electronic diffusion kinetics upon cycling, are seldom elucidated systematically. Herein, the crystal structure stability, charge/ion state, and bandgap of the active materials are found to be precisely modulated by favorable heteroatom doping, resulting in intrinsically fast kinetics of the electrode materials. Based on the combined mechanisms of intercalation and conversion reactions, electron and K+ ion transfer in Ni-doped CoSe2 embedded in carbon nullocomposites (Ni-CoSe2@NC) can be significantly enhanced via electronic engineering. Benefiting from the synthetic controlled Ni grains, the heterointerface formed by the intermediate products of electrochemical reactions in Ni-CoSe2@NC strengthens the conversion kinetics and interdiffusion process, developing a low-barrier mesophase with optimized potassium storage. Overall, an electronic tuning strategy can offer deeper atomic insights into the conversion reaction of TMSs in PIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 9, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2200341, "DOI": "10.1002/advs.202200341", "DOI Link": "http://dx.doi.org/10.1002/advs.202200341", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787081000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Li, BQ; Chen, X; Xie, J; Yuan, H; Huang, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng; Li, Bo-Quan; Chen, Xiang; Xie, Jin; Yuan, Hong; Huang, Jia-Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) battery affords an ultrahigh theoretical energy density of 2,600 Wh kg(-1) as a promising next-generation energy storage technique, whose actual performance is heavily dependent on the sulfur redox kinetics. Lithium polysulfide intermediates play a decisive role on the complex sulfur redox reactions but are unfortunately insufficient to afford rapid kinetics, rendering reduced specific capacity especially at high rates. Herein, a redox comediation strategy is proposed and an organopolysulfide (di-t-butyl disulfide, DtbDS) is introduced as a model comediator to accelerate the sulfur redox kinetics. Concretely, DtbDS reacts with lithium polysulfides and provides a kinetically favorable pathway for polysulfide conversion. Consequently, high-rate (4 C), high-sulfur-loading (5 mg cm(-2)), or lean-electrolyte (5.0 mu L mgs(-1)) Li-S batteries are realized. The redox comediation strategy demonstrates a novel approach to promote the sulfur redox kinetics for high-performance Li-S batteries and inspires more redox comediators represented by DtbDS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2020, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3297, "End Page": 3311, "Article Number": null, "DOI": "10.1016/j.chempr.2020.09.015", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2020.09.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596158700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pedersen, KS; Bendix, J; Clérac, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pedersen, Kasper S.; Bendix, Jesper; Clerac, Rodolphe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-molecule magnet engineering: building-block approaches", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tailoring the specific magnetic properties of any material relies on the topological control of the constituent metal ion building blocks. Although this general approach does not seem to be easily applied to traditional inorganic bulk magnets, coordination chemistry offers a unique tool to delicately tune, for instance, the properties of molecules that behave as magnets'', the so-called single-molecule magnets (SMMs). Although many interesting SMMs have been prepared by a more or less serendipitous approach, the assembly of predesigned, isolatable molecular entities into higher nuclearity complexes constitutes an elegant and fascinating strategy. This Feature article focuses on the use of building blocks or modules (both terms being used indiscriminately) to direct the structure, and therefore also the magnetic properties, of metal ion complexes exhibiting SMM behaviour.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 50, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4396, "End Page": 4415, "Article Number": null, "DOI": "10.1039/c4cc00339j", "DOI Link": "http://dx.doi.org/10.1039/c4cc00339j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333580500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, YX; Cao, Y; Ding, SJ; Zhang, PP; Xu, L; Liu, CC; Hu, QL; Jin, CH; Peng, LM; Zhang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yanxia; Cao, Yu; Ding, Sujuan; Zhang, Panpan; Xu, Lin; Liu, Chenchen; Hu, Qianlan; Jin, Chuanhong; Peng, Lian-Mao; Zhang, Zhiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling aligned carbon nullotube transistors to a sub-10 nm node", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aligned semiconducting carbon nullotubes are a potential alternative to silicon in the creation of scaled field-effect transistors (FETs) due to their easy miniaturization and high energy efficiency. However, it remains unclear whether aligned nullotube transistors can be fabricated at the same dimensions as low-node silicon technology and maintaining high performance. Here we report aligned carbon nullotube FETs that can be scaled to a size corresponding to the 10 nm silicon technology node. We first fabricate nullotube FETs with a contacted gate pitch of 175 nm (achieved by scaling the gate length and contact length to 85 nm and 80 nm, respectively) that exhibit an on current of 2.24 mA & mu;m(-1) and peak transconductance of 1.64 mS & mu;m(-1); this is superior to 45 nm silicon technology node transistors in terms of size and electronic performance. Six nullotube FETs are used to create a static random-access memory cell with an area of 0.976 & mu;m(2), which is comparable with the 90 nm silicon technology node. A full-contact structure is then introduced between the metal and nullotubes to achieve a low contact resistance of 90 & omega; & mu;m and reduce the dependence on the contact length. This is used to create nullotube FETs with a contacted gate pitch of 55 nm-corresponding to the 10 nm node-with carrier mobility and Fermi velocity higher than the 10 nm silicon metal-oxide-semiconductor transistors. Aligned carbon nullotubes can be used to create six-transistor static random-access memory cells with an area of less than 1 & mu;m(2) and performance superior to cells made using 90-nm-node silicon transistors, as well as field-effect transistors with scaled contacted gate pitch comparable with the 10 nm silicon technology node.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 506, "End Page": 515, "Article Number": null, "DOI": "10.1038/s41928-023-00983-3", "DOI Link": "http://dx.doi.org/10.1038/s41928-023-00983-3", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001031314500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ZX; Yi, ZL; Duan, YR; Pathak, R; Cheng, XQ; Wang, YZ; Elam, JW; Wang, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Zhenxin; Yi, Zonglin; Duan, Yunrui; Pathak, Rajesh; Cheng, Xiaoqin; Wang, Yongzhen; Elam, Jeffrey W.; Wang, Xiaomin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating the d-p band center of FeP/Fe2P heterostructure host with built-in electric field enabled efficient bidirectional electrocatalyst toward advanced lithium-sulfur batteries", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring advanced electrocatalysts and understanding their mechanism in regulating polysulfides-transformation is of great importance but a challenging task for lithium-sulfur batteries (LSBs). Herein, FeP/Fe2P heterostructure nulloparticles with an internal electric field, prepared by a temperature-controlled phosphating process, can effectively improve the electrocatalytic activities of the bidirectional Li2S deposition/dissolution. This improvement can be attributed to the modulating absorptivity of lithium polysulfides (LiPSs) and propelling charge transfer. The reduced d-p band center between bonding and antibonding orbitals of the Fe 3d and P 2p band in the heterostructure enables bonding with LiPSs to achieve a higher electronic concentration at the Fermi level. This regulates the adsorption-diffusion-conversion process, reduces the activation energy, and improves the Li+ diffusion. Benefiting from the boosted kinetics of the FeP/Fe2P heterostructure, the cells exhibit a high reversible capacity of 1412 mAh g(-1) at 0.1 C and outstanding energy efficiency of similar to 90% from 0.1 C to 2 C. Furthermore, the cell with high sulfur loading of 4 mg cm(-2) demonstrates a high capacity of 786 mAh g(-1) after 100 cycles at 0.5 C. This work presents an effective method and favorable guidance for developing advanced heterostructures in LSBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2023, "Volume": 463, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142397, "DOI": "10.1016/j.cej.2023.142397", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2023.142397", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955609900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LJ; Wu, YL; Tsubaki, N; Jin, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lijun; Wu, Youlin; Tsubaki, Noritatsu; Jin, Zhiliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D/3D S-Scheme Heterojunction Interface of CeO2-Cu2O Promotes Ordered Charge Transfer for Efficient Photocatalytic Hydrogen Evolution", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid intrinsic carrier recombination severely restricts the photocatalytic activity of CeO2-based catalytic materials. In this study, a heterogeneous interfacial engineering strategy is proposed to rationally perform interface modulation. A 2D/3D S scheme heterojunction with strong electronic interactions was constructed. A composite photocatalyst was synthesized for the 3D Cu2O particles anchored at the edge of 2D CeO2. First principles calculations (based on density functional theory) and the experimental results show that a strongly coupled S-scheme heterojunction electron transport interface is formed between CeO2 and Cu2O, resulting in efficient carrier separation and transfer. The photocatalytic hydrogen evolution activity of the composite catalyst is significantly improved in the system with triethanolamine as the sacrificial agent and is 48 times as that of CeO2. In addition, the resulting CeO2-Cu2O photocatalyst affords highly stable photocatalytic hydrogen activity. This provides a general technique for constructing unique interfaces in novel nullocomposite structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2023, "Volume": 39, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2302051, "DOI": "10.3866/PKU.WHXB202302051", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202302051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001071597300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rajamalli, P; Senthilkumar, N; Huang, PY; Ren-Wu, CC; Lin, HW; Cheng, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rajamalli, P.; Senthilkumar, N.; Huang, P-Y.; Ren-Wu, C-C.; Lin, H-W.; Cheng, C-H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Molecular Design Concurrently Providing Superior Pure Blue, Thermally Activated Delayed Fluorescence and Optical Out-Coupling Efficiencies", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneous enhancement of out-coupling efficiency, internal quantum efficiency, and color purity in thermally activated delayed fluorescence (TADF) emitters is highly desired for the practical application of these materials. We designed and synthesized two isomeric TADF emitters, 2DPyM-mDTC and 3DPyM-pDTC, based on di(pyridinyl)methanone (DPyM) cores as the new electron-accepting units and di(tert-butyl)carbazole (DTC) as the electron-donating units. 3DPyM-pDTC, which is structurally nearly planar with a very small Delta E-ST, shows higher color purity, horizontal ratio, and quantum yield than 2DPyM-mDTC, which has a more flexible structure. An electroluminescence device based on 3DPyM-pDTC as the dopant emitter can reach an extremely high external quantum efficiency of 31.9% with a pure blue emission. This work also demonstrates a way to design materials with a high portion of horizontal molecular orientation to realize a highly efficient pure-blue device based on TADF emitters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 361, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 139, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10948, "End Page": 10951, "Article Number": null, "DOI": "10.1021/jacs.7b03848", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b03848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408074800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, MY; Liu, S; Chen, DM; Zhang, SS; Carabineiro, SAC; Lv, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Mengyu; Liu, Sen; Chen, Daimei; Zhang, Sushu; Carabineiro, Sonia A. C.; Lv, Kangle", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel S-scheme 3D ZnIn2S4/WO3 heterostructure for improved hydrogen production under visible light irradiation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In-plane epitaxial growth of ZnIn2S4 nullosheets on the surface of hexagonal phase WO3 nullorods was achieved by a facile solvothermal method. The unique 3D heterostructure not only enlarged the specific surface area, but also red-shifted the absorption edge from 381 to 476 nm to improve the light harvesting ability, which largely enhanced the photocatalytic hydrogen evolution. The H2 pro-duction rate of the best performing ZnIn2S4/WO3 photocatalyst (ZIS-2.5/W, the material with a molar rate of ZnIn2S4 (ZIS) to WO3 (W) of 2.5) was 300 iimol center dot g-1 center dot h-1, around 417 times and 2 times higher than the rates of pristine WO3 and ZnIn2S4, respectively. The apparent quantum efficiency for ZIS-2.5/W composite was up to 2.81% at 400 nm. Based on the difference in Fermi levels between WO3 and ZnIn2S4, and the distribution of the redox active sites on WO3/ZnIn2S4 heterostructure, a S-scheme electron transfer mechanism was proposed to illustrate the improved photocatalytic activity of WO3/ZnIn2S4 heterojunction, which not only stimulated the spatial separation of the photogenerated charge carriers, but also maintained the strong reduction/oxidation ability of the photocatalyst. (c) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 43, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2615, "End Page": 2624, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64134-2", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64134-2", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884673500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QH; Zhao, DL; Schneider, AM; Chen, W; Yu, LP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qinghe; Zhao, Donglin; Schneider, Alexander M.; Chen, Wei; Yu, Luping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Covalently Bound Clusters of Alpha-Substituted PDI-Rival Electron Acceptors to Fullerene for Organic Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A cluster type of electron acceptor, TPB, bearing four alpha-perylenediimides (PDIs), was developed, in which the four PDIs form a cross-like molecular conformation while still partially conjugated with the BDT-Th core. The blend TPB:PTB7-Th films show favorable morphology and efficient charge dissociation. The inverted solar cells exhibited the highest PCE of 8.47% with the extraordinarily high Js, values (>18 mA/cm(2)), comparable with those of the corresponding PC7IBM/PTB7-Th-based solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2016, "Volume": 138, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7248, "End Page": 7251, "Article Number": null, "DOI": "10.1021/jacs.6b03562", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b03562", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378193300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, JQ; Hu, K; Zhang, JY; Meng, L; Yue, JL; Angunawela, I; Yan, HP; Qin, SC; Kong, XL; Zhang, ZJ; Guan, B; Ade, H; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Jiaqi; Hu, Ke; Zhang, Jinyuan; Meng, Lei; Yue, Jiling; Angunawela, Indunil; Yan, Hongping; Qin, Shucheng; Kong, Xiaolei; Zhang, Zhanjun; Guan, Bo; Ade, Harald; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polymerized small molecular acceptor based all-polymer solar cells with an efficiency of 16.16% via tuning polymer blend morphology by molecular design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-polymer solar cells (all-PSCs) based on polymerized small molecular acceptors (PSMAs) have made significant progress recently. Here, we synthesize two A-DA'D-A small molecule acceptor based PSMAs of PS-Se with benzo[c][1,2,5]thiadiazole A'-core and PN-Se with benzotriazole A'-core, for the studies of the effect of molecular structure on the photovoltaic performance of the PSMAs. The two PSMAs possess broad absorption with PN-Se showing more red-shifted absorption than PS-Se and suitable electronic energy levels for the application as polymer acceptors in the all-PSCs with PBDB-T as polymer donor. Cryogenic transmission electron microscopy visualizes the aggregation behavior of the PBDB-T donor and the PSMA in their solutions. In addition, a bicontinuous-interpenetrating network in the PBDB-T:PN-Se blend film with aggregation size of 10 similar to 20 nm is clearly observed by the photoinduced force microscopy. The desirable morphology of the PBDB-T:PN-Se active layer leads its all-PSC showing higher power conversion efficiency of 16.16%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5264, "DOI": "10.1038/s41467-021-25638-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25638-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694666900045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hirano, M; Ando, R; Shimozono, S; Sugiyama, M; Takeda, N; Kurokawa, H; Deguchi, R; Endo, K; Haga, K; Takai-Todaka, R; Inaura, S; Matsumura, Y; Hama, H; Okada, Y; Fujiwara, T; Morimoto, T; Katayama, K; Miyawaki, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hirano, Masahiko; Ando, Ryoko; Shimozono, Satoshi; Sugiyama, Mayu; Takeda, Noriyo; Kurokawa, Hiroshi; Deguchi, Ryusaku; Endo, Kazuki; Haga, Kei; Takai-Todaka, Reiko; Inaura, Shunsuke; Matsumura, Yuta; Hama, Hiroshi; Okada, Yasushi; Fujiwara, Takahiro; Morimoto, Takuya; Katayama, Kazuhiko; Miyawaki, Atsushi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly photostable and bright green fluorescent protein", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low photostability of fluorescent proteins is a limiting factor in many applications of fluorescence microscopy. Here we present StayGold, a green fluorescent protein (GFP) derived from the jellyfish Cytaeis uchidae. StayGold is over one order of magnitude more photostable than any currently available fluorescent protein and has a cellular brightness similar to mNeonGreen. We used StayGold to image the dynamics of the endoplasmic reticulum (ER) with high spatiotemporal resolution over several minutes using structured illumination microscopy (SIM) and observed substantially less photobleaching than with a GFP variant optimized for stability in the ER. Using StayGold fusions and SIM, we also imaged the dynamics of mitochondrial fusion and fission and mapped the viral spike proteins in fixed cells infected with severe acute respiratory syndrome coronavirus 2. As StayGold is a dimer, we created a tandem dimer version that allowed us to observe the dynamics of microtubules and the excitatory post-synaptic density in neurons. StayGold will substantially reduce the limitations imposed by photobleaching, especially in live cell or volumetric imaging. StayGold is over one order of magnitude more photostable than current fluorescent proteins", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 40, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1132, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41587-022-01278-2", "DOI Link": "http://dx.doi.org/10.1038/s41587-022-01278-2", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787146500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, R; Wang, W; Yu, H; Chen, Z; Xia, XX; Shen, H; Guo, J; Shi, MM; Zheng, YN; Wu, Y; Yang, WY; Wang, T; Wu, Q; Yang, Y; Lu, XH; Xia, JL; Brabec, CJ; Yan, H; Li, YF; Min, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Rui; Wang, Wei; Yu, Han; Chen, Zeng; Xia, XinXin; Shen, Hao; Guo, Jing; Shi, Mumin; Zheng, Yina; Wu, Yao; Yang, Wenyan; Wang, Tao; Wu, Qiang; (Michael) Yang, Yang; Lu, Xinhui; Xia, Jianlong; Brabec, Christoph J.; Yan, He; Li, Yongfang; Min, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving over 17% efficiency of ternary all-polymer solar cells with two well-compatible polymer acceptors", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of all-polymer solar cells (all-PSCs) has experienced rapid development during the past few years, mainly driven by the design of efficient polymer acceptors (P(A)s). However, the polymer/polymer blend systems still lag far behind polymer/small molecule acceptor counterparts in power conversion efficiencies (PCEs). Here, we designed a near-infrared P-A PY2F-T and paired it with polymer donor PM6 to fabricate all-PSCs with 15.0% PCE. Afterwards, PYT as the third component was introduced into the PM6: PY2F-T host system. Because of the complementary absorption bands and finely tuned microstructures of the ternary blend, the PCE is improved up to 17.2%, with the external quantum efficiency over 80% in visible and near-infrared spectral regions. Impressively, the ternary blend exhibited less energy loss, better light- soaking and photo-thermal stabilities than did the corresponding binary systems. This work promotes the development of high-performance ternary all-polymer systems and heralds a brighter future for accelerating the possible applications of all-PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2021, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1548, "End Page": 1565, "Article Number": null, "DOI": "10.1016/j.joule.2021.04.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.04.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663028600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Wang, H; Car, R; Weinull, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linfeng; Wang, Han; Car, Roberto; Weinull, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Diagram of a Deep Potential Water Model", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using the Deep Potential methodology, we construct a model that reproduces accurately the potential energy surface of the SCAN approximation of density functional theory for water, from low temperature and pressure to about 2400 K and 50 GPa, excluding the vapor stability region. The computational efficiency of the model makes it possible to predict its phase diagram using molecular dynamics. Satisfactory overall agreement with experimental results is obtained. The fluid phases, molecular and ionic, and all the stable ice polymorphs, ordered and disordered, are predicted correctly, with the exception of ice III and XV that are stable in experiments, but metastable in the model. The evolution of the atomic dynamics upon heating, as ice VII transforms first into ice VII'' and then into an ionic fluid, reveals that molecular dissociation and breaking of the ice rules coexist with strong covalent fluctuations, explaining why only partial ionization was inferred in experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2021, "Volume": 126, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 236001, "DOI": "10.1103/PhysRevLett.126.236001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.236001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661898600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, LK; Li, FY; Huang, JS; Sumpter, BG; Mustain, WE; Chen, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Linke; Li, Fengyu; Huang, Jingsong; Sumpter, Bobby G.; Mustain, William E.; Chen, Zhongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double-Atom Catalysts Featuring Inverse Sandwich Structure for CO2 Reduction Reaction: A Synergetic First-Principles and Machine Learning Investigation", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic CO2 reduction reactions (CO2RR) based on scalable and highly efficient catalysis providean attractivestrategy for reducing CO2 emissions. In this work, we combinedfirst-principles density functional theory (DFT) and machine learning(ML) to comprehensively explore the potential of double-atom catalysts(DACs) featuring an inverse sandwich structure anchored on defectivegraphene (gra) to catalyze CO2RR to generate C-1 products. We started with five homonuclear M-2 & BOTTOM;gra(M = Co, Ni, Rh, Ir, and Pt), followed by 127 heteronuclear MM & PRIME;& BOTTOM;gra(M = Co, Ni, Rh, Ir, and Pt, M & PRIME; = Sc-Au). Stable DACswere screened by evaluating their binding energy, formation energy,and dissolution potential of metal atoms, as well as conducting first-principlesmolecular dynamics simulations with and without solvent water molecules.Based on DFT calculations, Rh-2 & BOTTOM;gra DAC was foundto outperform the other four homonuclear DACs and the Rh-based single-and double-atom catalysts of noninverse sandwich structures. Out ofthe 127 heteronuclear DACs, 14 were found to be stable and have goodcatalytic performance. An ML approach was adopted to correlate keyfactors with the activity and stability of the DACs, including thesum of radii of metal and ligand atoms (d (M-M & PRIME;), d (M-C), and d (M & PRIME;-C)), the sum and difference of electronegativityof two metal atoms (P (M) + P (M & PRIME;), P (M) - P (M & PRIME;)), the sum and difference of firstionization energy of two metal atoms (I (M) + I (M & PRIME;), I (M) - I (M & PRIME;)), the sumand difference of electron affinity of two metal atoms (A (M) + A (M & PRIME;), A (M) - A (M & PRIME;)), andthe number of d-electrons of the two metal atoms (N (d)). The obtained ML models were further used to predict154 potential electrocatalysts out of 784 possible DACs featuringthe same inverse sandwich configuration. Overall, this work not onlyidentified promising CO2RR DACs featuring the reportedinverse sandwich structure but also provided insights into key atomiccharacteristics associated with high CO2RR activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2023, "Volume": 13, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9616, "End Page": 9628, "Article Number": null, "DOI": "10.1021/acscatal.3c01584", "DOI Link": "http://dx.doi.org/10.1021/acscatal.3c01584", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001024819000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cook, AM; Fregoso, BM; de Juan, F; Coh, S; Moore, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cook, Ashley M.; Fregoso, Benjamin M.; de Juan, Fernulldo; Coh, Sinisa; Moore, Joel E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design principles for shift current photovoltaics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the basic principles of conventional solar cells are well understood, little attention has gone towards maximizing the efficiency of photovoltaic devices based on shift currents. By analysing effective models, here we outline simple design principles for the optimization of shift currents for frequencies near the band gap. Our method allows us to express the band edge shift current in terms of a few model parameters and to show it depends explicitly on wavefunctions in addition to standard band structure. We use our approach to identify two classes of shift current photovoltaics, ferroelectric polymer films and single-layer orthorhombic monochalcogenides such as GeS, which display the largest band edge responsivities reported so far. Moreover, exploring the parameter space of the tight-binding models that describe them we find photoresponsivities that can exceed 100 mAW(-1). Our results illustrate the great potential of shift current photovoltaics to compete with conventional solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14176, "DOI": "10.1038/ncomms14176", "DOI Link": "http://dx.doi.org/10.1038/ncomms14176", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392650600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de Juan, F; Grushin, AG; Morimoto, T; Moore, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de Juan, Fernulldo; Grushin, Adolfo G.; Morimoto, Takahiro; Moore, Joel E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantized circular photogalvanic effect in Weyl semimetals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The circular photogalvanic effect (CPGE) is the part of a photocurrent that switches depending on the sense of circular polarization of the incident light. It has been consistently observed in systems without inversion symmetry and depends on non-universal material details. Here we find that in a class of Weyl semimetals (for example, SrSi2) and three-dimensional Rashba materials (for example, doped Te) without inversion and mirror symmetries, the injection contribution to the CPGE trace is effectively quantized in terms of the fundamental constants e, h, c and epsilon(0) with no material-dependent parameters. This is so because the CPGE directly measures the topological charge of Weyl points, and non-quantized corrections from disorder and additional bands can be small over a significant range of incident frequencies. Moreover, the magnitude of the CPGE induced by a Weyl node is relatively large, which enables the direct detection of the monopole charge with current techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15995, "DOI": "10.1038/ncomms15995", "DOI Link": "http://dx.doi.org/10.1038/ncomms15995", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404837400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, Y; Liu, H; Tang, BZ; Zhao, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Yan; Liu, Hao; Tang, Ben Zhong; Zhao, Zujin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing efficient blue and deep-blue delayed fluorescence materials with record-beating electroluminescence efficiencies of 43.4%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As promising luminescent materials for organic light-emitting diodes (OLEDs), thermally activated delayed fluorescence materials are booming vigorously in recent years, but robust blue ones still remain challenging. Herein, we report three highly efficient blue and deep-blue delayed fluorescence materials comprised of a weak electron acceptor chromeno[3,2-c]carbazol-8(5H)-one with a rigid polycyclic structure and a weak electron donor spiro[acridine-9,9'-xanthene]. They hold distinguished merits of excellent photoluminescence quantum yields (99%), ultrahigh horizontal transition dipole ratios (93.6%), and fast radiative transition and reverse intersystem crossing, which furnish superb blue and deep-blue electroluminescence with Commission Internationale de I'Eclairage coordinates (CIEx,y) of (0.14, 0.18) and (0.14, 0.15) and record-beating external quantum efficiencies (eta(ext)s) of 43.4% and 41.3%, respectively. Their efficiency roll-offs are successfully reduced by suppressing triplet-triplet and singlet-singlet annihilations. Moreover, high-performance deep-blue and green hyperfluorescence OLEDs are achieved by utilizing these materials as sensitizers for multi-resonullce delayed fluorescence dopants, providing state-of-the-art eta(ext)s of 32.5% (CIEx,y = 0.14, 0.10) and 37.6% (CIEx,y = 0.32, 0.64), respectively, as well as greatly advanced operational lifetimes. These splendid results can surely inspire the development of blue and deep-blue luminescent materials and devices. Thermally activated delayed fluorescence materials are important for the development of OLED materials but the development of robust blue emitting materials remains challenging. Here, the authors report three highly efficient blue and deepblue delayed fluorescence materials demonstrating excellent electroluminescence performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2019, "DOI": "10.1038/s41467-023-37687-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37687-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967732600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cubukcu, M; Boulle, O; Drouard, M; Garello, K; Avci, CO; Miron, IM; Langer, J; Ocker, B; Gambardella, P; Gaudin, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cubukcu, Murat; Boulle, Olivier; Drouard, Marc; Garello, Kevin; Avci, Can Onur; Miron, Ioan Mihai; Langer, Juergen; Ocker, Berthold; Gambardella, Pietro; Gaudin, Gilles", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-orbit torque magnetization switching of a three-terminal perpendicular magnetic tunnel junction", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the current-induced magnetization switching of a three-terminal perpendicular magnetic tunnel junction by spin-orbit torque and its read-out using the tunnelling magnetoresistance (TMR) effect. The device is composed of a perpendicular Ta/FeCoB/MgO/FeCoB stack on top of a Ta current line. The magnetization of the bottom FeCoB layer can be switched reproducibly by the injection of current pulses with density 5 x 10(11) A/m(2) in the Ta layer in the presence of an in-plane bias magnetic field, leading to the full-scale change of the TMR signal. Our work demonstrates the proof of concept of a perpendicular spin-orbit torque magnetic memory cell. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2014, "Volume": 104, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42406, "DOI": "10.1063/1.4863407", "DOI Link": "http://dx.doi.org/10.1063/1.4863407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331209900049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XL; Xiang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xueli; Xiang, Zhonghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying the impact of the covalent-bonded carbon matrix to FeN4 sites for acidic oxygen reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The atomic configurations of FeNx moieties are the key to affect the activity of oxygen rection reaction (ORR). However, the traditional synthesis relying on high-temperature pyrolysis towards combining sources of Fe, N, and C often results in the plurality of local environments for the FeNx sites. Unveiling the effect of carbon matrix adjacent to FeNx sites towards ORR activity is important but still is a great challenge due to inevitable connection of diverse N as well as random defects. Here, we report a proof-of-concept study on the evaluation of covalent-bonded carbon environment connected to FeN4 sites on their catalytic activity via pyrolysis-free approach. Basing on the closed p conjugated phthalocyanine-based intrinsic covalent organic polymers (COPs) with well-designed structures, we directly synthesized a series of atomically dispersed Fe-N-C catalysts with various pure carbon environments connected to the same FeN4 sites. Experiments combined with density functional theory demonstrates that the catalytic activities of these COPs materials appear a volcano plot with the increasement of delocalized p electrons in their carbon matrix. The delocalized p electrons changed anti-bonding d-state energy level of the single FeN4 moieties, hence tailored the adsorption between active centers and oxygen intermediates and altered the ratedetermining step.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-021-27735-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27735-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028263400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FC; Qu, FY; MacDonald, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fengcheng; Qu, Fanyao; MacDonald, A. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton band structure of monolayer MoS2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We address the properties of excitons in monolayer MoS2 from a theoretical point of view, showing that low-energy excitonic states occur both at the Brillouin-zone center and at the Brillouin-zone corners, that binding energies at the Brillouin-zone center deviate strongly from the (n - 1/2)(-2) pattern of the two-dimensional hydrogenic model, and that the valley-degenerate exciton doublet at the Brillouin-zone center splits at finite momentum into an upper mode with nonullalytic linear dispersion and a lower mode with quadratic dispersion. Although monolayer MoS2 is a direct-gap semiconductor when classified by its quasiparticle band structure, it may well be an indirect gap material when classified by its excitation spectra.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2015, "Volume": 91, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75310, "DOI": "10.1103/PhysRevB.91.075310", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.075310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350103800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Chen, JB; Bi, ZH; Chen, SQ; Feng, LG; Zhou, XH; Zhang, HB; Zhou, YT; Wagberg, T; Hu, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xue; Chen, Jianbing; Bi, Zenghui; Chen, Songqing; Feng, Ligang; Zhou, Xiaohai; Zhang, Haibo; Zhou, Yingtang; Wagberg, Thomas; Hu, Guangzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron Modulation and Morphology Engineering Jointly Accelerate Oxygen Reaction to Enhance Zn-Air Battery Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining morphological control engineering and diatomic coupling strategies, heteronuclear Fe-Co bimetals are efficiently intercalated into nitrogen-doped carbon materials with star-like to simultaneously accelerate oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The half-wave potential and kinetic current density of the ORR driven by FeCoNC/SL surpass the commercial Pt/C catalyst. The overpotential of OER is as low as 316 mV (eta(10)), and the mass activity is at least 3.2 and 9.4 times that of mononuclear CoNC/SL and FeNC/SL, respectively. The power density and specific capacity of the Zn-air battery with FeCoNC/SL as air cathode are as high as 224.8 mW cm(-2) and 803 mAh g(-1), respectively. Morphologically, FeCoNC/SL endows more reactive sites and accelerates the process of oxygen reaction. Density functional theory reveals the active site of the heteronuclear diatomic, and the formation of FeCoN5C configuration can effectively tune the d-band center and electronic structure. The redistribution of electrons provides conditions for fast electron exchange, and the change of the center of the d-band avoids the strong adsorption of intermediate species to simultaneously take into account both ORR and OER and thus achieve high-performance Zn-air batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205889", "DOI Link": "http://dx.doi.org/10.1002/advs.202205889", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000919333100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZZ; Kushimoto, M; Sakai, T; Sugiyama, N; Schowalter, LJ; Sasaoka, C; Amano, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ziyi; Kushimoto, Maki; Sakai, Tadayoshi; Sugiyama, Naoharu; Schowalter, Leo J.; Sasaoka, Chiaki; Amano, Hiroshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 271.8 nm deep-ultraviolet laser diode for room temperature operation", "Source Title": "APPLIED PHYSICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a deep-ultraviolet semiconductor laser diode that operates under current injection at room temperature and at a very short wavelength. The laser structure was grown on the (0001) face of a single-crystal aluminum nitride substrate. The measured lasing wavelength was 271.8;nm with a pulsed duration of 50;ns and a repetition frequency of 2;kHz. A polarization-induced doping cladding layer was employed to achieve hole conductivity and injection without intentional impurity doping. Even with this undoped layer, we were still able to achieve a low operation voltage of 13.8;V at a lasing threshold current of 0.4;A.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2019, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124003, "DOI": "10.7567/1882-0786/ab50e0", "DOI Link": "http://dx.doi.org/10.7567/1882-0786/ab50e0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499933200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Q; Chen, A; Wang, DH; Zhao, YW; Wang, XQ; Jin, X; Xiong, B; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Qing; Chen, Ao; Wang, Donghong; Zhao, Yuwei; Wang, Xiaoqi; Jin, Xu; Xiong, Bo; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring the metal electrode morphology via electrochemical protocol optimization for long-lasting aqueous zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc metal batteries are a viable candidate for cost-effective energy storage. However, the cycle life of the cell is adversely affected by the morphological evolution of the metal electrode surface upon prolonged cycling. Here, we investigate different electrochemical protocols to favour the formation of stable zinc metal electrode surface morphologies. By coupling electrochemical and optical microscopy measurements, we demonstrate that an initial zinc deposition on the metal electrode allows homogeneous stripping and plating processes during prolonged cycling in symmetric Zn||Zn cell. Interestingly, when an initially plated zinc metal electrode is tested in combination with a manganese dioxide-based positive electrode and a two molar zinc sulfate aqueous electrolyte solution in coin cell configuration, a specific discharge capacity of about 90 mAh g(-1) can be delivered after 2000 cycles at around 5.6 mA cm(-2) and 25 degrees C. Long-lasting zinc metal electrodes are crucial in developing commercial zinc-based batteries. Here, the authors investigate the different morphology evolution between the stripping and plating process and propose electrochemical protocols to prolong the lifespan of zinc anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3699, "DOI": "10.1038/s41467-022-31461-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31461-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818961600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, SW; Tang, CS; Yin, XM; Li, CJ; Li, MS; Huang, Z; Hu, JX; Liu, W; Omar, GJ; Jani, H; Lim, ZS; Han, K; Wan, DY; Yang, P; Pennycook, SJ; Wee, ATS; Ariando, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Shengwei; Tang, Chi Sin; Yin, Xinmao; Li, Changjian; Li, Mengsha; Huang, Zhen; Hu, Junxiong; Liu, Wei; Omar, Ganesh Ji; Jani, Hariom; Lim, Zhi Shiuh; Han, Kun; Wan, Dongyang; Yang, Ping; Pennycook, Stephen John; Wee, Andrew T. S.; Ariando, Ariando", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Diagram and Superconducting Dome of Infinite-Layer Nd1-xSxNiO2 Thin Films", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Infinite-layer Nd1-xSxNiO2 thin films with Sr doping level x from 0.08 to 0.3 are synthesized and investigated. We find a superconducting dome x between 0.12 and 0.235 accompanied by a weakly insulating behavior in both under- and overdoped regimes. The dome is akin to that in the electron-doped 214-type and infinite-layer cuprate superconductors. For x >= 0.18, the normal state Hall coefficient (RH) changes the sign from negative to positive as the temperature decreases. The temperature of the sign changes decreases monotonically with decreasing x from the overdoped side and approaches the superconducting dome at the midpoint, suggesting a reconstruction of the Fermi surface with the dopant concentration across the dome.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2020, "Volume": 125, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147003, "DOI": "10.1103/PhysRevLett.125.147003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.147003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000574781200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YX; Liu, X; Liu, ZP; Han, L; Ai, J; Zhao, G; Terasaki, O; Cui, CH; Yang, JZ; Liu, CY; Zhou, ZY; Chen, LW; Che, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yuxi; Liu, Xi; Liu, Zhipan; Han, Lu; Ai, Jing; Zhao, Gui; Terasaki, Osamu; Cui, Cunhao; Yang, Jiuzhong; Liu, Chengyuan; Zhou, Zhongyue; Chen, Liwei; Che, Shunai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 reduction and fixation products, ranging from small molecules to biomolecules, are highly diverse in natural systems. Although various multicarbon products of CO2 reduction were artificially obtained, the C3+ products with various functional groups (e.g., C-N and C-O bonds), especially biomolecules, have never been reported. Herein, we synthesized C3+ amino acids via electrocatalytic synthesis from CO2 and NH3, using chiral Cu films (CCFs) as electrodes. Electron mi-croscopy and theoretical calculations suggested that chiral kink sites can possibly be formed on the surface of CCFs fabricated through electrodeposition in the presence of histidine (His). Serine (Ser), with an enulltiomeric excess (ee) greater than 90%, is the main component of various amino acids. Experimental and computational data showed that the 3-hydropyruvic acid formation from H2CO- CO* is the stereo-determining step in the Ser formation pathway. The chiral kink sites were speculated to be restricting the configura-tion changes of C3+ intermediates to involve a thermodynamically and kinetically favorable formation of enulltiomeric Ser.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2023, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 460, "End Page": 471, "Article Number": null, "DOI": "10.1016/j.chempr.2022.10.017", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2022.10.017", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000944777000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GQ; Li, MC; Liu, CZ; Liu, CH; Li, ZL; Mei, CT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guoqiang; Li, Mei-Chun; Liu, Chaozheng; Liu, Chuhang; Li, Zhenglin; Mei, Changtong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Nitrogen-Doped Thick Carbon Architectures for Supercapacitor: Ink Rheology and Electrochemical Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The 3D printing technique offers huge opportunities for customized thick-electrode designs with high loading densities to enhance the area capacity in a limited space. However, key challenges remain in formulating 3D printable inks with exceptional rheological performance and facilitating electronic/ion transport in thick bulk electrodes. Herein, a hybrid ink consisting of woody-derived cellulose nullofibers (CNFs), multiwalled carbon nullotubes (MWCNTs), and urea is formulated for the 3D printing nitrogen-doped thick electrodes, in which CNFs serve as both dispersing and thickening agents for MWCNTs, whereas urea acts as a doping agent. By systematically tailoring the concentration-dependent rheological performance and 3D printing process of the ink, a variety of gel architectures with high geometric accuracy and superior shape fidelity are successfully printed. The as-printed gel architecture is then transformed into a nitrogen-doped carbon block with a hierarchical porous structure and superior electrochemical performance after freeze-drying and annealing treatments. Furthermore, a quasi-solid-state symmetric supercapacitor assembled with two interdigitated carbon blocks obtained by a 3D printing technique combined with a nitrogen-doping strategy delivers an energy density of 0.10 mWh cm(-2) at 0.56 mW cm(-2). This work provides guidance for the formulation of the printable ink used for 3D printing of high-performance thick carbon electrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 44, "Times Cited, All Databases": 45, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206320", "DOI Link": "http://dx.doi.org/10.1002/advs.202206320", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928501900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, B; Qi, ZH; Dai, MQ; Xing, C; Yan, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Bo; Qi, Zhenhong; Dai, Meiqi; Xing, Chang; Yan, Dongpeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralow-loss Optical Waveguides through Balancing Deep-Blue TADF and Orange Room Temperature Phosphorescence in Hybrid Antimony Halide Microstructures", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harnessing the potential of thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP) is crucial for developing light-emitting diodes (LEDs), lasers, sensors, and many others. However, effective strategies in this domain are still relatively scarce. This study presents a new approach to achieving highly efficient deep-blue TADF (with a PLQY of 25 %) and low-energy orange RTP (with a PLQY of 90 %) through the fabrication of lead-free hybrid halides. This new class of monomeric and dimeric 0D antimony halides can be facilely synthesized using a bottom-up solution process, requiring only a few seconds to minutes, which offer exceptional stability and nontoxicity. By leveraging the highly adaptable molecular arrangement and crystal packing modes, the hybrid antimony halides demonstrate the ability to self-assemble into regular 1D microrod and 2D microplate morphologies. This self-assembly is facilitated by multiple non-covalent interactions between the inorganic cores and organic shells. Notably, these microstructures exhibit outstanding polarized luminescence and function as low-dimensional optical waveguides with remarkably low optical-loss coefficients. Therefore, this work not only presents a pioneering demonstration of deep-blue TADF in hybrid antimony halides, but also introduces 1D and 2D micro/nullostructures that hold promising potential for applications in white LEDs and low-dimensional photonic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2023, "Volume": 62, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202309913", "DOI Link": "http://dx.doi.org/10.1002/anie.202309913", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001050941600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lampropoulos, AP; Paschalis, SA; Tsioulou, OT; Dritsos, SE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lampropoulos, A. P.; Paschalis, S. A.; Tsioulou, O. T.; Dritsos, S. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strengthening of reinforced concrete beams using ultra high performance fibre reinforced concrete (UHPFRC)", "Source Title": "ENGINEERING STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study the efficiency of the use of Ultra High Performance Fibre Reinforced Concrete (UHPFRC) for the strengthening of existing Reinforced Concrete (RC) beams has been investigated. Experimental work has been conducted to determine UHPFRC material properties. Dog-bone shaped specimens have been tested under direct tensile loading, and standard cubes have been tested in compression. These results have been used for the development of a numerical model using Finite Element Method. The reliability of the numerical model has been validated using further experimental results of UHPFRC layers tested under flexural loading. Further numerical study has been conducted on full-scale beams strengthened with UHPFRC layers and jackets, and these results were compared to respective results of beams strengthened with conventional RC layers and with combination of UHPFRC and steel reinforcing bars. Superior performance was observed for strengthened beams with UHPFRC three side jackets, and the efficiency of this technique was highlighted by comparisons with other strengthening techniques. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2016, "Volume": 106, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 370, "End Page": 384, "Article Number": null, "DOI": "10.1016/j.engstruct.2015.10.042", "DOI Link": "http://dx.doi.org/10.1016/j.engstruct.2015.10.042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367022000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Delaney, M; Zeimpekis, I; Du, H; Yan, XZ; Banakar, M; Thomson, DJ; Hewak, DW; Muskens, OL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Delaney, Matthew; Zeimpekis, Ioannis; Du, Han; Yan, Xingzhao; Banakar, Mehdi; Thomson, David J.; Hewak, Daniel W.; Muskens, Otto L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonvolatile programmable silicon photonics using an ultralow-loss Sb2Se3 phase change material", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The next generation of silicon-based photonic processors and neural and quantum networks need to be adaptable, reconfigurable, and programmable. Phase change technology offers proven nonvolatile electronic programmability; however, the materials used to date have shown prohibitively high optical losses, which are incompatible with integrated photonic platforms. Here, we demonstrate the capability of the previously unexplored material Sb2Se3 for ultralow-loss programmable silicon photonics. The favorable combination of large refractive index contrast and ultralow losses seen in Sb2Se3 facilitates an unprecedented optical phase control exceeding 10 pi radians in a Mach-Zehnder interferometer. To demonstrate full control over the flow of light, we introduce nullophotonic digital patterning as a previously unexplored conceptual approach with a footprint orders of magnitude smaller than state-of-the-art interferometer meshes. Our approach enables a wealth of possibilities in high-density reconfiguration of optical functionalities on silicon chip.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 7, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabg3500", "DOI": "10.1126/sciadv.abg3500", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abg3500", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000664958400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tahersima, MH; Kojima, K; Koike-Akino, T; Jha, D; Wang, BN; Lin, CW; Parsons, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tahersima, Mohammad H.; Kojima, Keisuke; Koike-Akino, Toshiaki; Jha, Devesh; Wang, Bingnull; Lin, Chungwei; Parsons, Kieran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Neural Network Inverse Design of Integrated Photonic Power Splitters", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting physical response of an artificially structured material is of particular interest for scientific and engineering applications. Here we use deep learning to predict optical response of artificially engineered nullophotonic devices. In addition to predicting forward approximation of transmission response for any given topology, this approach allows us to inversely approximate designs for a targeted optical response. Our Deep Neural Network (DNN) could design compact (2.6 x 2.6 mu m(2)) silicon-on-insulator (SOI)-based 1 x 2 power splitters with various target splitting ratios in a fraction of a second. This model is trained to minimize the reflection (to smaller than similar to -20 dB) while achieving maximum transmission efficiency above 90% and target splitting specifications. This approach paves the way for rapid design of integrated photonic components relying on complex nullostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1368, "DOI": "10.1038/s41598-018-37952-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-37952-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457616300256", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Lin, SQ; Ge, BH; Yang, J; Zhang, WQ; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wen; Lin, Siqi; Ge, Binghui; Yang, Jiong; Zhang, Wenqing; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low Sound Velocity Contributing to the High Thermoelectric Performance of Ag8SnSe6", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional strategies for advancing thermoelectrics by minimizing the lattice thermal conductivity focus on phonon scattering for a short mean free path. Here, a design of slow phonon propagation as an effective approach for high-performance thermoelectrics is shown. Taking Ag8SnSe6 as an example, which shows one of the lowest sound velocities among known thermoelectric semiconductors, the lattice thermal conductivity is found to be as low as 0.2 W m(-1) K-1 in the entire temperature range. As a result, a peak thermoelectric figure of merit zT > 1.2 and an average zT as high as approximate to 0.8 are achieved in Nb-doped materials, without relying on a high thermoelectric power factor. This work demonstrates not only a guiding principle of low sound velocity for minimal lattice thermal conductivity and therefore high zT, but also argyrodite compounds as promising thermoelectric materials with weak chemical bonds and heavy constituent elements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600196, "DOI": "10.1002/advs.201600196", "DOI Link": "http://dx.doi.org/10.1002/advs.201600196", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387649100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bechtel, HA; Muller, EA; Olmon, RL; Martin, MC; Raschke, MB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bechtel, Hans A.; Muller, Eric A.; Olmon, Robert L.; Martin, Michael C.; Raschke, Markus B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrabroadband infrared nullospectroscopic imaging", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Characterizing and ultimately controlling the heterogeneity underlying biomolecular functions, quantum behavior of complex matter, photonic materials, or catalysis requires large-scale spectroscopic imaging with simultaneous specificity to structure, phase, and chemical composition at nullometer spatial resolution. However, as with any ultrahigh spatial resolution microscopy technique, the associated demand for an increase in both spatial and spectral bandwidth often leads to a decrease in desired sensitivity. We overcome this limitation in infrared vibrational scattering-scanning probe near-field optical microscopy using synchrotron midinfrared radiation. Tip-enhanced localized light-matter interaction is induced by low-noise, broadband, and spatially coherent synchrotron light of high spectral irradiance, and the near-field signal is sensitively detected using heterodyne interferometric amplification. We achieve sub-40-nm spatially resolved, molecular, and phonon vibrational spectroscopic imaging, with rapid spectral acquisition, spanning the full midinfrared (700-5,000 cm(-1)) with few cm(-1) spectral resolution. We demonstrate the performance of synchrotron infrared nullospectroscopy on semiconductor, biomineral, and protein nullostructures, providing vibrational chemical imaging with subzeptomole sensitivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2014, "Volume": 111, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7191, "End Page": 7196, "Article Number": null, "DOI": "10.1073/pnas.1400502111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1400502111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336168100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XW; Yu, X; Zhao, M; Li, ZD; Wang, ZG; Zhai, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xinwei; Yu, Xiang; Zhao, Miao; Li, Zhendong; Wang, Zhonggang; Zhai, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-Level Bioinspired Microlattice with Broadband Sound-Absorption Capabilities and Deformation-Tolerant Compressive Response", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the omnipresent noise and crash hazards, multifunctional sound-absorbing, and deformation-tolerant materials are highly sought-after for practical engineering design. However, challenges lie with designing such a material. Herein, leveraging the inherent mechanical robustness of the biological cuttlebone, by introducing dissipative pores, a high-strength microlattice is presented which is also sound-absorbing. Its absorption bandwidth and deformation tolerance are further enhanced by introducing another level of bioinspiration, based on geometrical heterogeneities amongst the building cells. A high-fidelity microstructure-based model is developed to predict and optimize properties. Across a broad range of frequencies from 1000 to 6300 Hz, at a low thickness of 21 mm, the optimized microlattice displays a high experimentally measured average absorption coefficient of 0.735 with 68% of the points higher than 0.7. The absorption mechanism attributes to the resonating air frictional loss whilst its broadband characteristics attribute to the multiple resonullce modes working in tandem. The heterogeneous architecture also enables the microlattice to deform with a deformation-tolerant plateau behavior not observed in its uniform counterpart, which thereby leads to a 30% improvement in the specific energy absorption. Overall, this work presents an effective approach to the design of sound and energy-absorbing materials by modifying state-of-the-art bioinspired structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 33, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202210160", "DOI Link": "http://dx.doi.org/10.1002/adfm.202210160", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000878784800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Q; Luo, DW; Hua, DP; Ye, WT; Li, S; Zou, QG; Chen, ZQ; Wang, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Qing; Luo, Dawei; Hua, Dongpeng; Ye, Wenting; Li, Shuo; Zou, Qiguang; Chen, Ziqiang; Wang, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design and characterization of metallic glass/graphene multilayer with excellent nullowear properties", "Source Title": "FRICTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The excellent properties of metallic glass (MG) films make them perfect candidates for the use in miniature systems and tools. However, their high coefficients of friction (COFs) and poor wear resistance considerably limit their long-term performance in nulloscale contact. We report the fabrication of a MG/graphene multilayer by the repeated deposition of Cu50Zr50 MG with alternating layers of graphene. The microstructure of the multilayer was characterized by the transmission electron microscopy (TEM). Its mechanical and nullotribological properties were studied by nulloindentation and nulloscratch tests, respectively. A molecular dynamics (MD) simulation revealed that the addition of graphene endowed the MG with superelastic recovery, which reduced friction during nulloscratching. In comparison with the monolithic MG film, the multilayer exhibited improved wear resistance and a low COF in repeated nullowear tests owing to the enhanced mechanical properties and lubricating effect caused by the graphene layer. This work is expected to motivate the design of other novel MG films with excellent nullowear properties for engineering applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 10, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1913, "End Page": 1926, "Article Number": null, "DOI": "10.1007/s40544-021-0581-6", "DOI Link": "http://dx.doi.org/10.1007/s40544-021-0581-6", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789082600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Chen, LX; Qu, ZY; Zhai, FW; Yin, XX; Zhang, D; Shen, YF; Li, H; Liu, W; Mei, S; Ji, GX; Zhang, C; Dai, X; Chai, ZF; Wang, SO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuo; Chen, Lixi; Qu, Zhiying; Zhai, Fuwan; Yin, Xinxin; Zhang, Duo; Shen, Yufei; Li, Hui; Liu, Wei; Mei, Sen; Ji, Guoxun; Zhang, Chao; Dai, Xing; Chai, Zhifang; Wang, Shuao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominullt uranium species in seawater", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic reduction is a promising strategy for uranium extraction from seawater. However, due to the lack of accessible active sites, current photocatalysts work poorly under visible-light irradiation in reducing UO2(CO3)34-, the dominullt uranium species in seawater. Here, a one-pot precursor preorganized encapsulation strategy was applied to confine Ti-oxo clusters (TiOCs) within the micropores of a photosensitive covalent organic framework (TiOCseCOF-TZ), leading to the first utilization of confined photo catalysis in uranium extraction. This strategy endows the material with photocatalytic reduction capability toward UO2(CO3)34- in natural seawater, where X89.9% of UO2(CO3)34- was extracted by TiOCseCOF-TZ under visible-light irradiation. In comparison with the unloaded COF-TZ and surface-loaded TiOCs@COF-TZ, the TiOCseCOF-TZ exhibits a clear superiority both in catalytic activity and efficiency. Density functional theory (DFT) calculations infer that the photoinduced electrons are derived from the COF-TZ, whereas the TiOCs act as indispensable mediums during the electron transfer process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2023, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2023.06.008", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2023.06.008", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001114814200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wolf, T; Neumann, P; Nakamura, K; Sumiya, H; Ohshima, T; Isoya, J; Wrachtrup, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wolf, Thomas; Neumann, Philipp; Nakamura, Kazuo; Sumiya, Hitoshi; Ohshima, Takeshi; Isoya, Junichi; Wrachtrup, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subpicotesla Diamond Magnetometry", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-vacancy (NV) defect centers in diamond are promising solid-state magnetometers. Single centers allow for high-spatial-resolution field imaging but are limited in their magnetic field sensitivity. Using defect-center ensembles, sensitivity can be scaled with root N when N is the number of defects. In the present work, we use an ensemble of N similar to 10(11) defect centers within an effective sensor volume of 8.5 x 10(-4) mm(3) for sensing at room temperature. By carefully eliminating noise sources and using high-quality diamonds with large NV concentrations, we demonstrate, for such sensors, a sensitivity scaling as 1/root t, where t is the total measurement time. The associated photon-shot-noise-limited magnetic-field sensitivity for ac signals of f = 20 kHz is 0.9 pT/root Hz. For a total measurement time of 100 s, we reach a standard deviation of about 100 fT. Further improvements using decoupling sequences and material optimization could lead to fT/root Hz sensitivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2015, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41001, "DOI": "10.1103/PhysRevX.5.041001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.041001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362338100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, Y; Luo, X; Li, ZC; Fan, XJ; Wang, YT; He, RR; Liu, MX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Yue; Luo, Xiang; Li, Zichun; Fan, Xinjuan; Wang, Yiting; He, Rong-Rong; Liu, Mingxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A ferroptosis-targeting ceria anchored halloysite as orally drug delivery system for radiation colitis therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radiation colitis is the leading cause of diarrhea and hematochezia in pelvic radiotherapy patients. This work advances the pathogenesis of radiation colitis from the perspective of ferroptosis. An oral Pickering emulsion is stabilized with halloysite clay nullotubes to alleviate radiation colitis by inhibiting ferroptosis. Ceria nullozyme grown in situ on nullotubes can scavenge reactive oxygen species, and deferiprone was loaded into the lumen of nullotubes to relieve iron stress. These two strategies effectively inhibit lipid peroxidation and rescue ferroptosis in the intestinal microenvironment. The clay nullotubes play a critical role as either a medicine to alleviate colitis, a nullocarrier that targets the inflamed colon by electrostatic adsorption, or an interfacial stabilizer for emulsions. This ferroptosis-based strategy was effective in vitro and in vivo, providing a prospective candidate for radiotherapy protection via rational regulation of specific oxidative stress. Radiation colitis is a major side effect for pelvic radiotherapy patients, but there are limited available treatments. Here, the authors use a halloysite clay based material for the alleviation of radiation colitis in mice by inhibiting ferroptosis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-40794-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40794-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053269200029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ziletti, A; Kumar, D; Scheffler, M; Ghiringhelli, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ziletti, Angelo; Kumar, Devinder; Scheffler, Matthias; Ghiringhelli, Luca M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insightful classification of crystal structures using deep learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational methods that automatically extract knowledge from data are critical for enabling data-driven materials science. A reliable identification of lattice symmetry is a crucial first step for materials characterization and analytics. Current methods require a user-specified threshold, and are unable to detect average symmetries for defective structures. Here, we propose a machine learning-based approach to automatically classify structures by crystal symmetry. First, we represent crystals by calculating a diffraction image, then construct a deep learning neural network model for classification. Our approach is able to correctly classify a dataset comprising more than 100,000 simulated crystal structures, including heavily defective ones. The internal operations of the neural network are unraveled through attentive response maps, demonstrating that it uses the same landmarks a materials scientist would use, although never explicitly instructed to do so. Our study paves the way for crystal structure recognition of-possibly noisy and incomplete-three-dimensional structural data in big-data materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2775, "DOI": "10.1038/s41467-018-05169-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05169-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438856900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, WJ; Xi, LL; Wei, P; Ke, XZ; Yang, JH; Zhang, WQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Wujie; Xi, Lili; Wei, Ping; Ke, Xuezhi; Yang, Jihui; Zhang, Wenqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Part-crystalline part-liquid state and rattling-like thermal damping in materials with chemical-bond hierarchy", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding thermal and phonon transport in solids has been of great importance in many disciplines such as thermoelectric materials, which usually requires an extremely low lattice thermal conductivity (LTC). By analyzing the finite-temperature structural and vibrational characteristics of typical thermoelectric compounds such as filled skutterudites and Cu3SbSe3, we demonstrate a concept of part-crystalline part-liquid state in the compounds with chemicalbond hierarchy, in which certain constituent species weakly bond to other part of the crystal. Such a material could intrinsically manifest the coexistence of rigid crystalline sublattices and other fluctuating noncrystalline sublattices with thermally induced largeamplitude vibrations and even flow of the group of species atoms, leading to atomic-level heterogeneity, mixed part-crystalline partliquid structure, and thus rattling-like thermal damping due to the collective soft-mode vibrations similar to the Boson peak in amorphous materials. The observed abnormal LTC close to the amorphous limit in these materials can only be described by an effective approach that approximately treats the rattling-like damping as a resonullt phonon scattering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2014, "Volume": 111, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15031, "End Page": 15035, "Article Number": null, "DOI": "10.1073/pnas.1410349111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1410349111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343302600034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZP; Lin, QQ; Wenger, B; Christoforo, MG; Lin, YH; Klug, MT; Johnston, MB; Herz, LM; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhiping; Lin, Qianqian; Wenger, Bernard; Christoforo, M. Greyson; Lin, Yen-Hung; Klug, Matthew T.; Johnston, Michael B.; Herz, Laura M.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High irradiance performance of metal halide perovskites for concentrator photovoltaics", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditionally, III-V multi-junction cells have been used in concentrator photovoltaic (CPV) applications, which deliver extremely high efficiencies but have failed to compete with 'flat-plate' silicon technologies owing to cost. Here, we assess the feasibility of using metal halide perovskites for CPVs, and we evaluate their device performance and stability under concentrated light. Under simulated sunlight, we achieve a peak efficiency of 23.6% under 14 Suns (that is,14 times the standard solar irradiance), as compared to 21.1% under 1 Sun, and measure 1.26 V open-circuit voltage under 53 Suns, for a material with a bandgap of 1.63 eV. Importantly, our encapsulated devices maintain over 90% of their original efficiency after 150 h aging under 10 Suns at maximum power point. Our work reveals the potential of perovskite CPVs, and may lead to new PV deployment strategies combining perovskites with low-concentration factor and lower-accuracy solar tracking systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 855, "End Page": 861, "Article Number": null, "DOI": "10.1038/s41560-018-0220-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0220-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446724600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, XW; Song, EH; Zhao, W; Xu, SM; Zhao, WL; Lei, YJ; Fang, YQ; Liu, JJ; Huang, FQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xiaowei; Song, Erhong; Zhao, Wei; Xu, Shumao; Zhao, Wenli; Lei, Yongjiu; Fang, Yuqiang; Liu, Jianjun; Huang, Fuqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge self-regulation in 1T'''-MoS2 structure with rich S vacancies for enhanced hydrogen evolution activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active electronic states in transition metal dichalcogenides are able to prompt hydrogen evolution by improving hydrogen absorption. However, the development of thermodynamically stable hexagonal 2H-MoS2 as hydrogen evolution catalyst is likely to be shadowed by its limited active electronic state. Herein, the charge self-regulation effect mediated by tuning Mo-Mo bonds and S vacancies is revealed in metastable trigonal MoS2 (1T'''-MoS2) structure, which is favarable for the generation of active electronic states to boost the hydrogen evolution reaction activity. The optimal 1T'''-MoS2 sample exhibits a low overpotential of 158 mV at 10 mA cm(-2) and a Tafel slope of 74.5 mV dec(-1) in acidic conditions, which are far exceeding the 2H-MoS2 counterpart (369 mV and 137 mV dec(-1)). Theoretical modeling indicates that the boosted performance is attributed to the formation of massive active electronic states induced by the charge self-regulation effect of Mo-Mo bonds in defective 1T'''-MoS2 with rich S vacancies. Metal chalcogenides have shown promising performances for renewable hydrogen evolution and such activities are sensitive to the material electronic structures. Here, authors modulate the electronic properties of molybdenum sulfide in 1T'''-MoS2 for hydrogen evolution electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5954, "DOI": "10.1038/s41467-022-33636-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33636-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867457000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Chen, MX; Cai, JL; Spooner, ELK; Zhang, HJ; Gurney, RS; Liu, D; Xiao, Z; Lidzey, DG; Ding, LM; Wang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Chen, Mengxue; Cai, Jinlong; Spooner, Emma L. K.; Zhang, Huijun; Gurney, Robert S.; Liu, Dan; Xiao, Zuo; Lidzey, David G.; Ding, Liming; Wang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular Order Control of Non-fullerene Acceptors for High-Efficiency Polymer Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adjusting molecular ordering, orientation, and nulloscale morphology within the photoactive layer of polymer:non-fullerene organic solar cells is crucial in achieving high power-conversion efficiency (PCE). Herein, we demonstrate that the molecular ordering and orientation of the n-type small-molecule acceptor COi8DFIC can be tuned from flat-on and edge-on lamellar crystalline to H-and J-type pi-pi stacking during the solution-casting process, resulting in broadened photon absorption and fine phase separation with the electron donor PTB7-Th. This favorable morphology with face-on pi-pi stacked electron donors and acceptors promotes efficient exciton dissociation at the donor/acceptor interface, together with enhanced and balanced carrier mobility. The enhanced short-circuit current density and fill factor lead to the achievement of a maximum PCE of 13.8% in binary, single-junction PTB7-Th:COi8DFIC non-fullerene polymer solar cells while also exhibiting superior stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 819, "End Page": 833, "Article Number": null, "DOI": "10.1016/j.joule.2018.11.023", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.11.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462010600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Goddard, WA ; Xiao, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zeyu; Goddard, William A., III; Xiao, Hai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potential-dependent transition of reaction mechanisms for oxygen evolution on layered double hydroxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction (OER) is of crucial importance to sustainable energy and environmental engineering, and layered double hydroxides (LDHs) are among the most active catalysts for OER in alkaline conditions, but the reaction mechanism for OER on LDHs remains controversial. Distinctive types of reaction mechanisms have been proposed for the O-O coupling in OER, yet they compose a coupled reaction network with competing kinetics dependent on applied potentials. Herein, we combine grand-canonical methods and micro-kinetic modeling to unravel that the nature of dominullt mechanism for OER on LDHs transitions among distinctive types as a function of applied potential, and this arises from the interplay among applied potential and competing kinetics in the coupled reaction network. The theory-predicted overpotentials, Tafel slopes, and findings are in agreement with the observations of experiments including isotope labelling. Thus, we establish a computational methodology to identify and elucidate the potential-dependent mechanisms for electrochemical reactions. The mechanisms for oxygen evolution reaction on layered double hydroxides remain controversial. Here, the authors use a computational methodology by combining grand-canonical methods and microkinetic modeling to unravel the potential-dependent transitions mechanisms for electrochemical reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4228, "DOI": "10.1038/s41467-023-40011-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40011-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001030115000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Steppke, A; Zhao, LS; Barber, ME; Scaffidi, T; Jerzembeck, F; Rosner, H; Gibbs, AS; Maeno, Y; Simon, SH; Mackenzie, AP; Hicks, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Steppke, Alexander; Zhao, Lishan; Barber, Mark E.; Scaffidi, Thomas; Jerzembeck, Fabian; Rosner, Helge; Gibbs, Alexandra S.; Maeno, Yoshiteru; Simon, Steven H.; Mackenzie, Andrew P.; Hicks, Clifford W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong peak in Tc of Sr2RuO4 under uniaxial pressure", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sr2RuO4 is an unconventional superconductor that has attracted widespread study because of its high purity and the possibility that its superconducting order parameter has odd parity. We study the dependence of its superconductivity on anisotropic strain. Applying uniaxial pressures of up to similar to 1 gigapascals along a < 100 > direction (a axis) of the crystal lattice results in the transition temperature (T-c) increasing from 1.5 kelvin in the unstrained material to 3.4 kelvin at compression by approximate to 0.6%, and then falling steeply. Calculations give evidence that the observed maximum T-c occurs at or near a Lifshitz transition when the Fermi level passes through a Van Hove singularity, and open the possibility that the highly strained, T-c = 3.4 K Sr2RuO4 has an even-parity, rather than an odd-parity, order parameter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2017, "Volume": 355, "Issue": 6321, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaf9398", "DOI": "10.1126/science.aaf9398", "DOI Link": "http://dx.doi.org/10.1126/science.aaf9398", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391743700034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, WH; Li, ZZ; Gong, ZH; Liang, ZH; Liu, HW; Han, YC; Niu, HT; Song, B; Chi, XD; Zhou, JH; Wang, H; Xia, BY; Yao, YG; Tian, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Wenhui; Li, Zezhou; Gong, Zhihao; Liang, Zihui; Liu, Hanwen; Han, Ye-Chuang; Niu, Huiting; Song, Bo; Chi, Xiaodong; Zhou, Jihan; Wang, Hua; Xia, Bao Yu; Yao, Yonggang; Tian, Zhong-Qun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transient and general synthesis of high-density and ultrasmall nulloparticles on two-dimensional porous carbon via coordinated carbothermal shock", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-supported nulloparticles are indispensable to enabling new energy technologies such as metal-air batteries and catalytic water splitting. However, achieving ultrasmall and high-density nulloparticles (optimal catalysts) faces fundamental challenges of their strong tendency toward coarsening and agglomeration. Herein, we report a general and efficient synthesis of high-density and ultrasmall nulloparticles uniformly dispersed on two-dimensional porous carbon. This is achieved through direct carbothermal shock pyrolysis of metal-ligand precursors in just similar to 100ms, the fastest among reported syntheses. Our results show that the in situ metal-ligand coordination (e.g., N -> Co2+) and local ordering during millisecond-scale pyrolysis play a crucial role in kinetically dominated fabrication and stabilization of high-density nulloparticles on two-dimensional porous carbon films. The as-obtained samples exhibit excellent activity and stability as bifunctional catalysts in oxygen redox reactions. Considering the huge flexibility in coordinated precursors design, diversified single and multielement nulloparticles (M=Fe, Co, Ni, Cu, Cr, Mn, Ag, etc) were generally fabricated, even in systems well beyond traditional crystalline coordination chemistry. Our method allows for the transient and general synthesis of well-dispersed nulloparticles with great simplicity and versatility for various application schemes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2294, "DOI": "10.1038/s41467-023-38023-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38023-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, KY; Zhu, Y; Zheng, ZH; Cheng, WK; Zi, YF; Zeng, SQ; Zhao, DW; Yu, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Kaiyue; Zhu, Ying; Zheng, Zihao; Cheng, Wanke; Zi, Yifei; Zeng, Suqing; Zhao, Dawei; Yu, Haipeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-Inspired Multiscale Design for Strong and Tough Biological Ionogels", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structure design provides an effective solution to develop advanced soft materials with desirable mechanical properties. However, creating multiscale structures in ionogels to obtain strong mechanical properties is challenging. Here, an in situ integration strategy for producing a multiscale-structured ionogel (M-gel) via ionothermal-stimulated silk fiber splitting and moderate molecularization in the cellulose-ions matrix is reported. The produced M-gel shows a multiscale structural superiority comprised of microfibers, nullofibrils, and supramolecular networks. When this strategy is used to construct a hexactinellid inspired M-gel, the resultant biomimetic M-gel shows excellent mechanical properties including elastic modulus of 31.5 MPa, fracture strength of 6.52 MPa, toughness reaching 1540 kJ m(-3), and instantaneous impact resistance of 3.07 kJ m(-1), which are comparable to those of most previously reported polymeric gels and even hardwood. This strategy is generalizable to other biopolymers, offering a promising in situ design method for biological ionogels that can be expanded to more demanding load-bearing materials requiring greater impact resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207233", "DOI Link": "http://dx.doi.org/10.1002/advs.202207233", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000946667300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, PP; Zhao, YG; Li, YK; Li, N; Silva, SRP; Shao, GS; Zhang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Pengpeng; Zhao, Yige; Li, Yukun; Li, Neng; Silva, S. Ravi P.; Shao, Guosheng; Zhang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the Selective Bifunctional Electrocatalytic Sites via In Situ Irradiated X-Ray Photoelectron Spectroscopy for Lithium-Sulfur Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrocatalysts are widely applied in lithium-sulfur (Li-S) batteries to selectively accelerate the redox kinetics behavior of Li2S, in which bifunctional active sites are established, thereby improving the electrochemical performance of the battery. Considering that the Li-S battery is a complex closed black box system, the internal redox reaction routes and active sites cannot be directly observed and monitored especially due to the distribution of potential active-site structures and their dynamic reconstruction. Empirical evidence demonstrates that traditional electrochemical test methods and theoretical calculations only probe the net result of multi-factors on an average and whole scale. Herein, based on the amorphous TiO2-x@Ni selective bifunctional model catalyst, these limitations are overcome by developing a system that couples the light field and in situ irradiated X-ray photoelectron spectroscopy to synergistically convert the black box battery into a see-through battery for direct observation of the charge transportation, thus revealing that amorphous TiO2-x and Ni nulloparticle as the oxidation and reduction sites selectively promote the decomposition and nucleation of Li2S, respectively. This work provides a universal method to achieve a deeper mechanistic understanding of bidirectional sulfur electrochemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206786", "DOI Link": "http://dx.doi.org/10.1002/advs.202206786", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913103200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, TH; Ono, LK; Yoshioka, R; Ding, CF; Zhang, CY; Mariotti, S; Zhang, JH; Mitrofanov, K; Liu, X; Segawa, H; Kabe, R; Han, LY; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Tianhao; Ono, Luis K.; Yoshioka, Rengo; Ding, Chenfeng; Zhang, Congyang; Mariotti, Silvia; Zhang, Jiahao; Mitrofanov, Kirill; Liu, Xiao; Segawa, Hiroshi; Kabe, Ryota; Han, Liyuan; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elimination of light-induced degradation at the nickel oxide-perovskite heterojunction by aprotic sulfonium layers towards long-term operationally stable inverted perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nickel oxide (NiOx) is a promising hole-selective contact to produce efficient inverted p-i-n structured perovskite solar cells (PSCs) due to its high carrier mobility and high transparency. However, the light-induced degradation of the NiOx-perovskite heterojunction is the main factor limiting its long-term operational lifetime. In this study, we used the time-resolved mass spectrometry technique to clarify the degradation mechanism of the NiOx-formamidinium-methylammonium iodide perovskite (a common composition for high-performance PSCs) heterojunction under operational conditions, and observed that (1) oxidation of iodide and generation of free protons under 1-sun illumination, (2) formation of volatile hydrogen cyanide, methyliodide, and ammonia at elevated temperatures, and (3) a condensation reaction between the organic components under a high vapor pressure. To eliminate these multi-step photochemical reactions, we constructed an aprotic trimethylsulfonium bromide (TMSBr) buffer layer at the NiOx/perovskite interface, which enables excellent photo-thermal stability, a matched lattice parameter with the perovskite crystal, and robust trap-passivation ability. Inverted PSCs stabilized with the TMSBr buffer layer reached the maximum efficiency of 22.1% and retained 82.8% of the initial value after continuous operation for 2000 hours under AM1.5G light illumination, which translates into a T-80 lifetime of 2310 hours that is among the highest operational lifetimes for NiOx-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2022, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4612, "End Page": 4624, "Article Number": null, "DOI": "10.1039/d2ee01801b", "DOI Link": "http://dx.doi.org/10.1039/d2ee01801b", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000857176800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, XZ; Chen, SS; Jiao, HY; Zhao, L; Wang, K; Ni, ZY; Yu, ZH; Chen, B; Gao, YL; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Xuezeng; Chen, Shangshang; Jiao, Haoyang; Zhao, Liang; Wang, Ke; Ni, Zhenyi; Yu, Zhenhua; Chen, Bo; Gao, Yongli; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient monolithic all-perovskite tandem solar modules with small cell-to-module derate", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scaling up all-perovskite tandem solar modules is challenging due to the degradation of the low-bandgap subcell during processing in ambient conditions. Here Dai et al. devise an additive- and hot gas-assisted blade-coating process that enables modules with 21.6% efficiency over an aperture area of 14.3 cm(2). All-perovskite tandem solar modules are promising to reduce the cost of photovoltaic systems with their high efficiency and solution fabrication, but their sensitivity to air still imposes a great challenge. Here a hot gas-assisted blading method is developed to accelerate the perovskite solidification, forming compact and thick narrow bandgap (NBG) perovskite films. Adding a reduction agent into NBG films followed by a short period of air exposure and a post-fabrication storage surprisingly increases carrier recombination lifetime and enables laser scribing in ambient conditions without obvious loss of device performance. This combination suppresses tin and iodide oxidation and forms a thin SnO2 layer on the NBG film surface. Monolithic all-perovskite tandem solar modules showed a champion efficiency of 21.6% with a 14.3 cm(2) aperture area, corresponding to an active area efficiency of 23.0%. The very small cell-to-module derate of 6.5% demonstrates the advantage of a tandem monolithic structure for solar modules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 923, "End Page": 931, "Article Number": null, "DOI": "10.1038/s41560-022-01102-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01102-w", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000847263200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Rao, H; Atwi, R; Sivakumar, BM; Gwalani, B; Gray, S; Han, KS; Everett, TA; Ajantiwalay, TA; Murugesan, V; Rajput, NN; Pol, VG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zheng; Rao, Harsha; Atwi, Rasha; Sivakumar, Bhuvaneswari M.; Gwalani, Bharat; Gray, Scott; Han, Kee Sung; Everett, Thomas A.; Ajantiwalay, Tanvi A.; Murugesan, Vijayakumar; Rajput, Nav Nidhi; Pol, Vilas G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-polar ether-based electrolyte solutions for stable high-voltage non-aqueous lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical instability of ether-based electrolyte solutions hinders their practical applications in high-voltage Li metal batteries. To circumvent this issue, here, we propose a dilution strategy to lose the Li+/solvent interaction and use the dilute non-aqueous electrolyte solution in high-voltage lithium metal batteries. We demonstrate that in a non-polar dipropyl ether (DPE)-based electrolyte solution with lithium bis(fluorosulfonyl) imide salt, the decomposition order of solvated species can be adjusted to promote the Li+/salt-derived anion clusters decomposition over free ether solvent molecules. This selective mechanism favors the formation of a robust cathode electrolyte interphase (CEI) and a solvent-deficient electric double-layer structure at the positive electrode interface. When the DPE-based electrolyte is tested in combination with a Li metal negative electrode (50 mu m thick) and a LiNi0.8Co0.1Mn0.1O2-based positive electrode (3.3 mAh/cm(2)) in pouch cell configuration at 25 degrees C, a specific discharge capacity retention of about 74% after 150 cycles (0.33 and 1mA/cm(2) charge and discharge, respectively) is obtained. Ether solvents have poor anodic stabilities in lithium metal batteries. Here, the authors propose a non-aqueous electrolyte solution with a non-polar and non-fluorinated ether solvent. The electrolyte enables stable cycling of high-voltage Li metal batteries in pouch cell configuration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 868, "DOI": "10.1038/s41467-023-36647-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36647-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053826400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MH; Shen, C; Zhao, CH; Dai, M; Yao, FZ; Wu, B; Ma, J; null, H; Wang, DW; Yuan, QB; Da Silva, LL; Fulanovic, L; Schökel, A; Liu, PT; Zhang, HB; Li, JF; Zhang, N; Wang, K; Rödel, J; Hinterstein, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mao-Hua; Shen, Chen; Zhao, Changhao; Dai, Mian; Yao, Fang-Zhou; Wu, Bo; Ma, Jian; null, Hu; Wang, Dawei; Yuan, Qibin; da Silva, Lucas Lemos; Fulanovic, Lovro; Schoekel, Alexander; Liu, Peitao; Zhang, Hongbin; Li, Jing-Feng; Zhang, null; Wang, Ke; Roedel, Juergen; Hinterstein, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deciphering the phase transition-induced ultrahigh piezoresponse in (K,Na)NbO3-based piezoceramics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we introduce phase change mechanisms in lead-free piezoceramics as a strategy to utilize attendant volume change for harvesting large electrostrain. In the newly developed (K,Na)NbO3 solid-solution at the polymorphic phase boundary we combine atomic mapping of the local polar vector with in situ synchrotron X-ray diffraction and density functional theory to uncover the phase change and interpret its underlying nature. We demonstrate that an electric field-induced phase transition between orthorhombic and tetragonal phases triggers a dramatic volume change and contributes to a huge effective piezoelectric coefficient of 1250 pm V-1 along specific crystallographic directions. The existence of the phase transition is validated by a significant volume change evidenced by the simultaneous recording of macroscopic longitudinal and transverse strain. The principle of using phase transition to promote electrostrain provides broader design flexibility in the development of high-performance piezoelectric materials and opens the door for the discovery of high-performance future functional oxides. Functional oxides with coexisting states of comparable energy typically exhibit extraordinary responses to external stimuli. Here, the authors demonstrate that coexisting phase structures provide large electric field-triggered volume change.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3434, "DOI": "10.1038/s41467-022-31158-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31158-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000811535400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, J; Zhou, Y; Ramanathan, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Jian; Zhou, You; Ramanathan, Shriram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colossal resistance switching and band gap modulation in a perovskite nickelate by electron doping", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic properties of correlated oxides are exceptionally sensitive to the orbital occupancy of electrons. Here we report an electron doping strategy via a chemical route, where interstitial dopants (for example, hydrogen) can be reversibly intercalated, realizing a sharp phase transition in a model correlated perovskite nickelate SmNiO3. The electron configuration of e(g) orbital of Ni(3+)t(2g)(6)e(g)(1) in SmNiO3 is modified by injecting and anchoring an extra electron, forming a strongly correlated Ni(2)(+)t(2g)(6)e(g)(2) structure leading to the emergence of a new insulating phase. A reversible resistivity modulation greater than eight orders of magnitude is demonstrated at room temperature. A solid-state room temperature nonvolatile proton-gated phase-change transistor is demonstrated based on this principle, which may inform new materials design for correlated oxide devices. Electron doping-driven phase transition accompanied by large conductance changes and band gap modulation opens up new directions to explore emerging electronic and photonic devices with correlated oxide systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4860, "DOI": "10.1038/ncomms5860", "DOI Link": "http://dx.doi.org/10.1038/ncomms5860", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418524700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Z; Rolston, N; Flick, AC; Colburn, TW; Ren, ZK; Dauskardt, RH; Buonassisi, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhe; Rolston, Nicholas; Flick, Austin C.; Colburn, Thomas W.; Ren, Zekun; Dauskardt, Reinhold H.; Buonassisi, Tonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning with knowledge constraints for process optimization of open-air perovskite solar cell manufacturing", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing a scalable manufacturing technique for perovskite solar cells requires process optimization in high-dimensional parameter space. Herein, we present a machine learning (ML)-guided framework of sequential learning for manufacturing the process optimization of perovskite solar cells. We apply our methodology to the rapid spray plasma processing (RSPP) technique for open-air perovskite device fabrication. With a limited experimental budget of screening 100 process conditions, we demonstrated an efficiency improvement to 18.5% as the best result from a device fabricated by RSPP. Our model is enabled by three innovations: flexible knowledge transfer between experimental processes by incorporating data from prior experimental data as a probabilistic constraint, incorporation of both subjective human observations and ML insights when selecting next experiments, and adaptive strategy of locating the region of interest using Bayesian optimization before conducting local exploration for high-efficiency devices. Furthermore, in virtual benchmarking, our framework achieves faster improvements with limited experimental budgets than traditional design-of-experiments methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 834, "End Page": 849, "Article Number": null, "DOI": "10.1016/j.joule.2022.03.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.03.003", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798575600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, XH; Steinle, T; Huang, LL; Taubner, T; Wuttig, M; Zentgraf, T; Giessen, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Xinghui; Steinle, Tobias; Huang, Lingling; Taubner, Thomas; Wuttig, Matthias; Zentgraf, Thomas; Giessen, Harald", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beam switching and bifocal zoom lensing using active plasmonic metasurfaces", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compact nullophotonic elements exhibiting adaptable properties are essential components for the miniaturization of powerful optical technologies such as adaptive optics and spatial light modulators. While the larger counterparts typically rely on mechanical actuation, this can be undesirable in some cases on a microscopic scale due to inherent space restrictions. Here, we present a novel design concept for highly integrated active optical components that employs a combination of resonullt plasmonic metasurfaces and the phase-change material Ge3Sb2Te6. In particular, we demonstrate beam switching and bifocal lensing, thus, paving the way for a plethora of active optical elements employing plasmonic metasurfaces, which follow the same design principles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2017, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e17016", "DOI": "10.1038/lsa.2017.16", "DOI Link": "http://dx.doi.org/10.1038/lsa.2017.16", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407509700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Endrödi, B; Samu, A; Kecsenovity, E; Halmágyi, T; Sebök, D; Janáky, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Endrodi, B.; Samu, A.; Kecsenovity, E.; Halmagyi, T.; Sebok, D.; Janaky, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando cathode activation with alkali metal cations for high current density operation of water-fed zero-gap carbon dioxide electrolysers", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous-flow electrolysers allow CO2 reduction at industrially relevant rates, but long-term operation is still challenging. One reason for this is the formation of precipitates in the porous cathode from the alkaline electrolyte and the CO2 feed. Here we show that while precipitate formation is detrimental for the long-term stability, the presence of alkali metal cations at the cathode improves performance. To overcome this contradiction, we develop an operando activation and regeneration process, where the cathode of a zero-gap electrolyser cell is periodically infused with alkali cation-containing solutions. This enables deionized water-fed electrolysers to operate at a CO2 reduction rate matching those using alkaline electrolytes (CO partial current density of 420 +/- 50 mA cm(-2) for over 200 hours). We deconvolute the complex effects of activation and validate the concept with five different electrolytes and three different commercial membranes. Finally, we demonstrate the scalability of this approach on a multicell electrolyser stack, with an active area of 100 cm(2) per cell. Precipitates that form in the cathode of continuous-flow CO2 electrolysers hamper their long-term operation, but the alkali metals they are formed from actually boost activity. Endrodi et al. mitigate this dichotomy by using pure water in the electrolyser and periodically infusing the cathode with alkaline cations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 439, "End Page": 448, "Article Number": null, "DOI": "10.1038/s41560-021-00813-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00813-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642499100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Mertens, R; Ferrucci, M; Yan, CZ; Shi, YS; Yang, SF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Lei; Mertens, Raya; Ferrucci, Massimiliano; Yan, Chunze; Shi, Yusheng; Yang, Shoufeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Continuous graded Gyroid cellular structures fabricated by selective laser melting: Design, manufacturing and mechanical properties", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functional graded cellular materials (FGCMs) have attracted increasing attentions for their improved properties when compared to uniform, cellular structures. In this work, graded Gyroid cellular structures (GCSs) with varying gradient directions were designed and manufactured via selective laser melting (SLM). As a reference, uniform structures were also manufactured. The surface morphology and mechanical response of these structures under compressive loads were investigated. Results indicate high manufacturability and repeatability of GCSs manufactured by SLM. Optimized density distribution gives these structures novel deformation and mechanical properties. GCSs with density gradient perpendicular to the loading direction exhibit deformation behaviours similar to uniform ones, while GCSs with the gradient parallel to the loading direction exhibit layer-by-layer deformation and collapse behaviour. A novel phenomenon of sub-layer collapses is found in GCSs with gradient parallel to the loading direction. Furthermore, mathematical models were developed to predict and customize the mechanical properties of graded cellular structures by optimizing the relative density of each layer. These significant findings illustrate that graded cellular structures have high application prospect in various industries, particularly given the fact that additive manufacturing has been an enabler of cellular structure fabrication. (C) 2018 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2019, "Volume": 162, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 394, "End Page": 404, "Article Number": null, "DOI": "10.1016/j.matdes.2018.12.007", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2018.12.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454128400039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maur, MAD; Pecchia, A; Penazzi, G; Rodrigues, W; Di Carlo, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maur, Matthias Auf Der; Pecchia, Alessandro; Penazzi, Gabriele; Rodrigues, Walter; Di Carlo, Aldo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficiency Drop in Green InGaN/GaN Light Emitting Diodes: The Role of Random Alloy Fluctuations", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "White light emitting diodes (LEDs) based on III-nitride InGaN/GaN quantum wells currently offer the highest overall efficiency for solid state lighting applications. Although current phosphor-converted white LEDs have high electricity-to-light conversion efficiencies, it has been recently pointed out that the full potential of solid state lighting could be exploited only by color mixing approaches without employing phosphor-based wavelength conversion. Such an approach requires direct emitting LEDs of different colors, including, in particular, the green-yellow range of the visible spectrum. This range, however, suffers from a systematic drop in efficiency, known as the green gap, whose physical origin has not been understood completely so far. In this work, we show by atomistic simulations that a consistent part of the green gap in c-plane InGaN/GaN-based light emitting diodes may be attributed to a decrease in the radiative recombination coefficient with increasing indium content due to random fluctuations of the indium concentration naturally present in any InGaN alloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2016, "Volume": 116, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27401, "DOI": "10.1103/PhysRevLett.116.027401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.027401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368286300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, CS; Feng, JS; Prokhorenko, S; Nahas, Y; Xiang, HJ; Bellaiche, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Changsong; Feng, Junsheng; Prokhorenko, Sergei; Nahas, Yousra; Xiang, Hongjun; Bellaiche, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological spin texture in Janus monolayers of the chromium trihalides Cr(I, X)3", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological magnetic states are promising for ultradense memory and logic devices. Recent progress in two-dimensional magnets encourages the idea to realize topological states, such as skyrmions and merons, in freestanding monolayers. However, monolayers such as CrI3 lack Dzyaloshinskii-Moriya interactions (DMIs) and thus do not naturally exhibit skyrmions/merons but rather a ferromagnetic state. Here we propose the fabrication of Cr(I, X)(3) Janus monolayers, in which the Cr atoms are covalently bonded to the underlying I ions and top-layer Br or Cl atoms. By performing first-principles calculations and Monte Carlo simulations, we identify strong enough DMIs, which leads to not only helical cycloid phases, but also to topologically nontrivial states, such as the intrinsic domain wall skyrmions in Cr(I, Br)(3) and the magnetic-field-induced bimerons in Cr(I, Cl)(3). Microscopic origins of such spin textures are revealed as well.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2020, "Volume": 101, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 60404, "DOI": "10.1103/PhysRevB.101.060404", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.101.060404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000512768900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rinkel, BLD; Hall, DS; Temprano, I; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rinkel, Bernardine L. D.; Hall, David S.; Temprano, Israel; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrolyte Oxidation Pathways in Lithium-Ion Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mitigation of decomposition reactions of lithium-ion battery electrolyte solutions is of critical importance in controlling device lifetime and performance. However, due to the complexity of the system, exacerbated by the diverse set of electrolyte compositions, electrode materials, and operating parameters, a clear understanding of the key chemical mechanisms remains elusive. In this work, operando pressure measurements, solution NMR, and electrochemical methods were combined to study electrolyte oxidation and reduction at multiple cell voltages. Two-compartment LiCoO2/Li cells were cycled with a lithium-ion conducting glass-ceramic separator so that the species formed at each electrode could be identified separately and further reactions of these species at the opposite electrode prevented. One principal finding is that chemical oxidation (with an onset voltage of similar to 4.7 V vs Li/Li+ for LiCoO2), rather than electrochemical reaction, is the dominullt decomposition process at the positive electrode surface in this system. This is ascribed to the well-known release of reactive oxygen at higher states-of-charge, indicating that reactions of the electrolyte at the positive electrode are intrinsically linked to surface reactivity of the active material. Soluble electrolyte decomposition products formed at both electrodes are characterized, and a detailed reaction scheme is constructed to rationalize the formation of the observed species. The insights on electrolyte decomposition through reactions with reactive oxygen species identified through this work have a direct impact on understanding and mitigating degradation in high-voltage/higher-energy-density LiCoO2-based cells, and more generally for cells containing nickel-containing cathode materials (e.g., LiNixMnyCOzO2; NMCs), as they lose oxygen at lower operating voltages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2020, "Volume": 142, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15058, "End Page": 15074, "Article Number": null, "DOI": "10.1021/jacs.0c06363", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c06363", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569271600024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, BJ; Fu, BT; Kasamatsu, S; Ito, S; Cheng, P; Liu, CC; Feng, Y; Wu, SL; Mahatha, SK; Sheverdyaeva, P; Moras, P; Arita, M; Sugino, O; Chiang, TC; Shimada, K; Miyamoto, K; Okuda, T; Wu, KH; Chen, L; Yao, YG; Matsuda, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Baojie; Fu, Botao; Kasamatsu, Shusuke; Ito, Suguru; Cheng, Peng; Liu, Cheng-Cheng; Feng, Ya; Wu, Shilong; Mahatha, Sanjoy K.; Sheverdyaeva, Polina; Moras, Paolo; Arita, Masashi; Sugino, Osamu; Chiang, Tai-Chang; Shimada, Kenya; Miyamoto, Koji; Okuda, Taichi; Wu, Kehui; Chen, Lan; Yao, Yugui; Matsuda, Iwao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental realization of two-dimensional Dirac nodal line fermions in monolayer Cu2Si", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological nodal line semimetals, a novel quantum state of materials, possess topologically nontrivial valence and conduction bands that touch at a line near the Fermi level. The exotic band structure can lead to various novel properties, such as long-range Coulomb interaction and flat Landau levels. Recently, topological nodal lines have been observed in several bulk materials, such as PtSn4, ZrSiS, TlTaSe2 and PbTaSe2. However, in two-dimensional materials, experimental research on nodal line fermions is still lacking. Here, we report the discovery of two-dimensional Dirac nodal line fermions in monolayer Cu2Si based on combined theoretical calculations and angle-resolved photoemission spectroscopy measurements. The Dirac nodal lines in Cu2Si form two concentric loops centred around the Gamma point and are protected by mirror reflection symmetry. Our results establish Cu2Si as a platform to study the novel physical properties in two-dimensional Dirac materials and provide opportunities to realize high-speed low-dissipation devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 18", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1007, "DOI": "10.1038/s41467-017-01108-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01108-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413168700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zelezny, J; Zhang, Y; Felser, C; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zelezny, Jakub; Zhang, Yang; Felser, Claudia; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-Polarized Current In Noncollinear Antiferromagnets", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noncollinear antiferromagnets, such as Mn-3 Sn and Mn-3 Ir, were recently shown to be analogous to ferromagnets in that they have a large anomalous Hall effect. Here we show that these materials are similar to ferromagnets in another aspect: the charge current in these materials is spin polarized. In addition, we show that the same mechanism that leads to the spin-polarized current also leads to a transverse spin current, which has a distinct symmetry and origin from the conventional spin Hall effect. We illustrate the existence of the spin-polarized current and the transverse spin current by performing ab initio microscopic calculations and by analyzing the symmetry. We discuss possible applications of these novel spin currents, such as an antiferromagnetic metallic or tunneling junction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2017, "Volume": 119, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 187204, "DOI": "10.1103/PhysRevLett.119.187204", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.187204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414323000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Tao, SR; Wan, SJ; Qiu, GG; Long, Q; Yu, JG; Cao, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Han; Tao, Shanren; Wan, Sijie; Qiu, Guogen; Long, Qing; Yu, Jiaguo; Cao, Shaowen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-scheme heterojunction of ZnCdS nullospheres and dibenzothiophene modified graphite carbon nitride for enhanced H2 production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "g-C3N4-based photocatalysts with an intramolecular donor-acceptor structure still suffer from in-adequate visible-light absorption and severe charge recombination. Constructing S-scheme hetero-junction is a promising approach to address these issues. Herein, ZCS (ZnCdS nullo-spheres)@DBTCN (g-C3N4 modified by dibenzothiophene groups) S-scheme heterojunction photo -catalyst was synthesized through a self-assembly approach. The ZCS@DBTCN material showed a superior photocatalytic H2 production activity of 8.87 mmol g-1 h-1, which is 3.46 and 2.55 times that of pure DBTCN and ZCS, respectively. This enhanced photocatalytic performance could be ascribed to the synergistic effect of intramolecular internal electric field and S-scheme heterojunction, which boosts the separation and transport of photogenerated carriers within the molecular framework and at the interface, and preserves the maximum redox capacity of the spatially separated electrons and holes. Moreover, the S-scheme charge migrate mechanism of ZCS@DBTCN was strongly evi-denced by the in -situ irradiated Kelvin probe force microscopy and in -situ irradiated X-ray photoe-lectron spectroscopy. This study provides a protocol for designing g-C3N4-based hybrid photocata-lysts with high charge separation efficiency and excellent photocatalytic activity.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 167, "End Page": 176, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64201-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64201-3", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000990101600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WW; Jin, Y; Mu, YR; Zhang, MH; Du, JK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Weiwei; Jin, Yuan; Mu, Yanru; Zhang, Minghua; Du, Jianke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel tubular structure with negative Poisson's ratio based on gyroid-type triply periodic minimal surfaces", "Source Title": "VIRTUAL AND PHYSICAL PROTOTYPING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel type of tubular structure with negative Poisson's ratio based on gyroid-type triply periodic minimal surfaces (TPMSs) is proposed in this study. This work is an attempt to design auxetic tubular structures based on TPMS. A series of auxetic tubular structures were designed and then fabricated using laser power bed fusion. Compressive behaviours of the fabricated auxetic tubular structures were investigated using experimental and numerical methods. To obtain optimal designs of tubular structures with controllable auxetic properties, the influence of several parameters were investigated comprehensively. Subsequently, several graded auxetic tubular structures were designed based on the parametric analysis and studied numerically. The mechanical properties of the tubular structures could be controlled effectively using the proposed approach. The proposed method can be used for guiding the design and optimisation of auxetic tubular structures, showing excellent potential for various applications such as biomedical devices, vehicle crashworthiness, and protective engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 31", "Publication Year": 2023, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2203701", "DOI": "10.1080/17452759.2023.2203701", "DOI Link": "http://dx.doi.org/10.1080/17452759.2023.2203701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000975686300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Liu, C; Wang, JX; Lv, JW; Lv, Y; Yang, L; An, N; Yi, Z; Liu, Q; Hu, CJ; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Liu, Chao; Wang, Jianxin; Lv, Jingwei; Lv, Yan; Yang, Lin; An, Ni; Yi, Zao; Liu, Qiang; Hu, Chunjie; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface plasmon resonullce sensor composed of microstructured optical fibers for monitoring of external and internal environments in biological and environmental sensing", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve simultaneous detection of analytes with different states in internal and external environments, A microstructured optical fibers (MOFs) biochemical sensor based on surface plasmon resonullce (SPR) is proposed. The micro-polished dual-open-loop structure with anti-corrosive gold as the sensing layer is designed, which greatly improves the phase matching between fundamental mode and plasmonic mode to further stimulate SPR effect. Numerical simulation by the full-vector finite element method (FEM) reveals that the even mode for ypolarized state has better sensing properties due to the more eminent electric field distribution and shift of the confinement loss peak. In order to better evaluate and analyze the output characteristics of this sensor, the wavelength modulation and amplitude interrogation methods are adopted. The results manifest that the maximum wavelength sensitivity (WS) of 20,000 nm/RIU and amplitude sensitivity (AS) of 208.21 RIU-1 with resolution (R) of 10-6 order can be acquired in operable infrared region (900-2,750 nm). Furthermore, this sensor has realized a broad range of detection for gas and liquid analytes with RIs from 1.00 to 1.38. On account of its simple structure, low cost, and industrial compatibility, this sensor has large potential in environmental and biological applications such as atmospheric monitoring, sewage treatment, food safety, humoral regulation, and medical diagnosis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106365, "DOI": "10.1016/j.rinp.2023.106365", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2023.106365", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000958868500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Badloe, T; Kim, J; Kim, I; Kim, WS; Kim, WS; Kim, YK; Rho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Badloe, Trevon; Kim, Joohoon; Kim, Inki; Kim, Won-Sik; Kim, Wook Sung; Kim, Young-Ki; Rho, Junsuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid crystal-powered Mie resonators for electrically tunable photorealistic color gradients and dark blacks", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Taking inspiration from beautiful colors in nature, structural colors produced from nullostructured metasurfaces have shown great promise as a platform for bright, highly saturated, and high-resolution colors. Both plasmonic and dielectric materials have been employed to produce static colors that fulfil the required criteria for high-performance color printing, however, for practical applications in dynamic situations, a form of tunability is desirable. Combinations of the additive color palette of red, green, and blue enable the expression of further colors beyond the three primary colors, while the simultaneous intensity modulation allows access to the full color gamut. Here, we demonstrate an electrically tunable metasurface that can represent saturated red, green, and blue pixels that can be dynamically and continuously controlled between on and off states using liquid crystals. We use this to experimentally realize ultrahigh-resolution color printing, active multicolor cryptographic applications, and tunable pixels toward high-performance full-color reflective displays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118, "DOI": "10.1038/s41377-022-00806-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00806-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788960200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Jeong, SY; Tian, JF; Zhang, YD; Naphade, DR; Alsufyani, M; Zhang, WM; Griggs, S; Hu, HL; Barlow, S; Woo, HY; Marder, SR; Anthopoulos, TD; McCulloch, I; Lin, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hu; Jeong, Sang Young; Tian, Junfu; Zhang, Yadong; Naphade, Dipti R.; Alsufyani, Maryam; Zhang, Weimin; Griggs, Sophie; Hu, Hanlin; Barlow, Stephen; Woo, Han Young; Marder, Seth R.; Anthopoulos, Thomas D.; McCulloch, Iain; Lin, Yuanbao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 19% efficient and stable organic photovoltaic device enabled by a guest nonfullerene acceptor with fibril-like morphology", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A nonfullerene acceptor, isoIDITC, capable of exhibiting fibril-like morphology, is utilized as a third component in organic photovoltaic devices (OPVs). A power conversion efficiency (PCE) of 19% is achieved in ternary PM6:BTP-eC9:isoIDITC bulk-heterojunction (BHJ) devices. Analyses reveal the formation of an alloy model (BTP-eC9:isoIDTIC) and a well-defined fibril-like network and enhanced crystallization of BHJ in the ternary blend. Slightly increased carrier mobilities, longer carrier lifetimes, and suppressed trap-assisted/bimolecular recombination are observed in the ternary BHJ-based devices compared to the binary PM6:BTP-eC9 BHJ cells. Moreover, because of the high surface energy (gamma) and low glass-transition temperature (T-g) of BTP-eC9, the acceptor and donor tend to migrate toward the hole and electron collecting electrodes, respectively, during aging tests. Crucially, isoIDTIC with low gamma and high T-g has a low diffusion coefficient and can suppress demixing in vertical stratification of the BHJ, resulting in an increase in T-80 lifetime from 101 hours to 254 hours. Our results highlight the utilization of the nonfullerene acceptor with fibril-like morphology and high T-g as an important third component toward high-performance and stable ternary OPVs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2023, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1062, "End Page": 1070, "Article Number": null, "DOI": "10.1039/d2ee03483b", "DOI Link": "http://dx.doi.org/10.1039/d2ee03483b", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000916970600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Shen, RP; Wang, S; Chen, QL; Gu, C; Zhang, WR; Yang, GJ; Chen, QN; Zhang, YM; Zhang, SAXA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuyang; Shen, Ruipeng; Wang, Shuo; Chen, Quanliang; Gu, Chang; Zhang, Weiran; Yang, Guojian; Chen, Qiaonull; Zhang, Yu-Mo; Zhang, Sean Xiao-An", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A see-through electrochromic display via dynamic metal-ligand interactions", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the dynamic coordination and dissociation between metal ions and ligands involved in biochemical reactions, we proposed and explored in detail a new electrochromic (EC) mechanism, based on the color conversion of dyes induced by electrical adjustable metal-ligand interactions. Different from the traditional EC materials, whose color-changing motifs and redox motifs are located at the same site, this new material is an indirect-redox-color-changing system composed by switchable dyes and multivalent metal ion. These EC devices combine the advantages of electrochemical stability of metal ions and the color adjustability of readily available dyes with high molar absorption coefficient, high transmittance change (74%), broad color tunability, and good coloration efficiency (506.67 cm(2)/C). A prototype of see-through EC reader with high white light contrast ratio (8.5:1) has been achieved based on dynamic metal-ligand interactions. More importantly, the new application of dynamic metal-ligand interactions might induce more pleasant surprise in other areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2021, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2021.02.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2021.02.005", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652330400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, QY; Liu, K; Hu, KM; Cai, C; Li, HJW; Li, HM; Herran, M; Lu, YR; Chan, TS; Ma, C; Fu, JW; Zhang, SG; Liang, Y; Cortes, E; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Qiyou; Liu, Kang; Hu, Kangman; Cai, Chao; Li, Huangjingwei; Li, Hongmei; Herran, Matias; Lu, Ying-Rui; Chan, Ting-Shan; Ma, Chao; Fu, Junwei; Zhang, Shiguo; Liang, Ying; Cortes, Emiliano; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Attenuating metal-substrate conjugation in atomically dispersed nickel catalysts for electroreduction of CO2 to CO", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically dispersed transition metals on carbon-based aromatic substrates are an emerging class of electrocatalysts for the electroreduction of CO2. However, electron delocalization of the metal site with the carbon support via d-pi conjugation strongly hinders CO2 activation at the active metal centers. Herein, we introduce a strategy to attenuate the d-pi conjugation at single Ni atomic sites by functionalizing the support with cyano moieties. In situ attenuated total reflection infrared spectroscopy and theoretical calculations demonstrate that this strategy increases the electron density around the metal centers and facilitates CO2 activation. As a result, for the electroreduction of CO2 to CO in aqueous KHCO3 electrolyte, the cyano-modified catalyst exhibits a turnover frequency of similar to 22,000 per hour at -1.178 V versus the reversible hydrogen electrode (RHE) and maintains a Faradaic efficiency (FE) above 90% even with a CO2 concentration of only 30% in an H-type cell. In a flow cell under pure CO2 at -0.93 V versus RHE the cyano-modified catalyst enables a current density of -300 mA/cm(2) with a FE above 90%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6082, "DOI": "10.1038/s41467-022-33692-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33692-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874078500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barker, AJ; Sadhanala, A; Deschler, F; Gandini, M; Senullayak, SP; Pearce, PM; Mosconi, E; Pearson, AJ; Wu, Y; Kandada, ARS; Leijtens, T; De Angelis, F; Dutton, SE; Petrozza, A; Friend, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barker, Alex J.; Sadhanala, Aditya; Deschler, Felix; Gandini, Marina; Senullayak, Satyaprasad P.; Pearce, Phoebe M.; Mosconi, Edoardo; Pearson, Andrew J.; Wu, Yue; Kandada, Ajay Ram Srimath; Leijtens, Tomas; De Angelis, Filippo; Dutton, Sian E.; Petrozza, Annamaria; Friend, Richard H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-Assisted Photoinduced Halide Segregation in Mixed-Halide Perovskite Thin Films", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processable metal halide perovskites show immense promise for use in photovoltaics and other optoelectronic applications. The ability to tune their bandgap by alloying various halide anions (for example, in CH3NH3Pb(I1-x Br-x)(3), 0 < x < 1) is however hampered by the reversible photoinduced formation of sub-bandgap emissive states. We find that ion segregation takes place via halide defects, resulting in iodide-rich low-bandgap regions close to the illuminated surface of the film. This segregation may be driven by the strong gradient in carrier generation rate through the thickness of these strongly absorbing materials. Once returned to the dark, entropically driven intermixing of halides returns the system to a homogeneous condition. We present approaches to suppress this process by controlling either the internal light distribution or the defect density within the film. These results are relevant to stability in both single- and mixed-halide perovskites, leading the way toward tunable and stable perovskite thin films for photovoltaic and light-emitting applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 462, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1416, "End Page": 1424, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00282", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00282", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403303500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SJ; Tian, ZH; Wang, ZY; Rufo, J; Li, P; Mai, J; Xia, JP; Bachman, H; Huang, PH; Wu, MX; Chen, CY; Lee, LP; Huang, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shujie; Tian, Zhenhua; Wang, Zeyu; Rufo, Joseph; Li, Peng; Mai, John; Xia, Jianping; Bachman, Hunter; Huang, Po-Hsun; Wu, Mengxi; Chen, Chuyi; Lee, Luke P.; Huang, Tony Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harmonic acoustics for dynamic and selective particle manipulation", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precise and selective manipulation of colloids and biological cells has long been motivated by applications in materials science, physics and the life sciences. Here we introduce our harmonic acoustics for a non-contact, dynamic, selective (HANDS) particle manipulation platform, which enables the reversible assembly of colloidal crystals or cells via the modulation of acoustic trapping positions with subwavelength resolution. We compose Fourier-synthesized harmonic waves to create soft acoustic lattices and colloidal crystals without using surface treatment or modifying their material properties. We have achieved active control of the lattice constant to dynamically modulate the interparticle distance in a high-throughput (>100 pairs), precise, selective and reversible manner. Furthermore, we apply this HANDS platform to quantify the intercellular adhesion forces among various cancer cell lines. Our biocompatible HANDS platform provides a highly versatile particle manipulation method that can handle soft matter and measure the interaction forces between living cells with high sensitivity. Precise manipulation of colloids and cells is desired for material and life sciences. However, such control remains challenging without material modifications. Here, the authors achieve reversible single-particle manipulation with subwavelength resolution and high throughput using harmonic acoustics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 21, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 540, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-022-01210-8", "DOI Link": "http://dx.doi.org/10.1038/s41563-022-01210-8", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772700300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Robertson, IM; Sofronis, P; Nagao, A; Martin, ML; Wang, S; Gross, DW; Nygren, KE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Robertson, Ian M.; Sofronis, P.; Nagao, A.; Martin, M. L.; Wang, S.; Gross, D. W.; Nygren, K. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen Embrittlement Understood", "Source Title": "METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The connection between hydrogen-enhanced plasticity and the hydrogen-induced fracture mechanism and pathway is established through examination of the evolved microstructural state immediately beneath fracture surfaces including voids, quasi-cleavage, and intergranular surfaces. This leads to a new understanding of hydrogen embrittlement in which hydrogen-enhanced plasticity processes accelerate the evolution of the microstructure, which establishes not only local high concentrations of hydrogen but also a local stress state. Together, these factors establish the fracture mechanism and pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 572, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": "46A", "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2323, "End Page": 2341, "Article Number": null, "DOI": "10.1007/s11661-015-2836-1", "DOI Link": "http://dx.doi.org/10.1007/s11661-015-2836-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353236700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lundeberg, MB; Gao, YD; Asgari, R; Tan, C; Van Duppen, B; Autore, M; Alonso-González, P; Woessner, A; Watanabe, K; Taniguchi, T; Hillenbrand, R; Hone, J; Polini, M; Koppens, FHL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lundeberg, Mark B.; Gao, Yuanda; Asgari, Reza; Tan, Cheng; Van Duppen, Ben; Autore, Marta; Alonso-Gonzalez, Pablo; Woessner, Achim; Watanabe, Kenji; Taniguchi, Takashi; Hillenbrand, Rainer; Hone, James; Polini, Marco; Koppens, Frank H. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning quantum nonlocal effects in graphene plasmonics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The response of electron systems to electrodynamic fields that change rapidly in space is endowed by unique features, including an exquisite spatial nonlocality. This can reveal much about the materials' electronic structure that is invisible in standard probes that use gradually varying fields. Here, we use graphene plasmons, propagating at extremely slow velocities close to the electron Fermi velocity, to probe the nonlocal response of the graphene electron liquid. The near-field imaging experiments reveal a parameter-free match with the full quantum description of the massless Dirac electron gas, which involves three types of nonlocal quantum effects: single-particle velocity matching, interaction-enhanced Fermi velocity, and interaction-reduced compressibility. Our experimental approach can determine the full spatiotemporal response of an electron system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2017, "Volume": 357, "Issue": 6347, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 187, "End Page": 190, "Article Number": null, "DOI": "10.1126/science.aan2735", "DOI Link": "http://dx.doi.org/10.1126/science.aan2735", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405391700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SQ; Xu, XL; Zhu, YZ; Niu, RR; Xu, CQ; Peng, YX; Cheng, X; Jia, XH; Huang, Y; Xu, XF; Lu, JM; Ye, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shiqi; Xu, Xiaolong; Zhu, Yaozheng; Niu, Ruirui; Xu, Chunqiang; Peng, Yuxuan; Cheng, Xing; Jia, Xionghui; Huang, Yuan; Xu, Xiaofeng; Lu, Jianming; Ye, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Odd-Even Layer-Number Effect and Layer-Dependent Magnetic Phase Diagrams in MnBi2Te4", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently reported with nontrivial topological properties and magnetic orders, MnBi2Te4 is an intrinsic, magnetic topological insulator which holds promise for exploring exotic quantum phenomena such as the quantum anomalous Hall effect. However, the layer-dependent magnetism of MnBi2Te4, which is fundamental and crucial for further exploration of related quantum phenomena in this system, remains elusive. Here, by using polar reflective magnetic circular dichroism spectroscopy, we show that few-layered MnBi2Te4 exhibits an evident odd-even layer-number effect, i.e., the oscillations of the coercivity of the hysteresis loop (at mu H-0(c)) and the spin-flop transition (at mu H-0(1)), concerning the Zeeman energy and magnetic anisotropy energy. Noticeably, an anomalous magnetic hysteresis loop is observed in the evennumber septuple-layered MnBi(2)Te(4)4, which might be attributed to the thickness-independent surfacerelated magnetization. A linear-chain model is applied to elucidate this odd-even layer-number effect of the spin-flop field and to determine the evolution of the magnetic states when subjected to an external magnetic field. A mean-field method further allows us to fully map the MnBi2Te4 flake's magnetic phase diagrams in the parameter space of the magnetic field, layer number, and, especially, temperature. By harnessing the unusual layer-dependent magnetic properties, our work paves the way for further study of quantum phenomena of MnBi2Te4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11003, "DOI": "10.1103/PhysRevX.11.011003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.011003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605184700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Markos, C; Travers, JC; Abdolvand, A; Eggleton, BJ; Bang, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Markos, Christos; Travers, John C.; Abdolvand, Amir; Eggleton, Benjamin J.; Bang, Ole", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid photonic-crystal fiber", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article offers an extensive survey of results obtained using hybrid photonic-crystal fibers (PCFs) which constitute one of the most active research fields in contemporary fiber optics. The ability to integrate novel and functional materials in solid-and hollow-core PCFs through various postprocessing methods has enabled new directions toward understanding fundamental linear and nonlinear phenomena as well as novel application aspects, within the fields of optoelectronics, material and laser science, remote sensing, and spectroscopy. Here the recent progress in the field of hybrid PCFs is reviewed from scientific and technological perspectives, focusing on how different fluids, solids, and gases can significantly extend the functionality of PCFs. The first part of this review discusses the efforts to develop tunable linear and nonlinear fiber-optic devices using PCFs infiltrated with various liquids, glasses, semiconductors, and metals. The second part concentrates on recent and state-of-the-art advances in the field of gas-filled hollow-core PCFs. Extreme ultrafast gas-based nonlinear optics toward light generation in the extreme wavelength regions of vacuum ultraviolet, pulse propagation, and compression dynamics in both atomic and molecular gases, and novel soliton-plasma interactions are reviewed. A discussion of future prospects and directions is also included.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2017, "Volume": 89, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45003, "DOI": "10.1103/RevModPhys.89.045003", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.89.045003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416247600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhattacharjee, T; Zehnder, SM; Rowe, KG; Jain, S; Nixon, RM; Sawyer, WG; Angelini, TE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhattacharjee, Tapomoy; Zehnder, Steven M.; Rowe, Kyle G.; Jain, Suhani; Nixon, Ryan M.; Sawyer, W. Gregory; Angelini, Thomas E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Writing in the granular gel medium", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gels made from soft microscale particles smoothly transition between the fluid and solid states, making them an ideal medium in which to create macroscopic structures with microscopic precision. While tracing out spatial paths with an injection tip, the granular gel fluidizes at the point of injection and then rapidly solidifies, trapping injected material in place. This physical approach to creating three-dimensional (3D) structures negates the effects of surface tension, gravity, and particle diffusion, allowing a limitless breadth of materials to be written. With this method, we used silicones, hydrogels, colloids, and living cells to create complex large aspect ratio 3D objects, thin closed shells, and hierarchically branched tubular networks. We crosslinked polymeric materials and removed them from the granular gel, whereas uncrosslinked particulate systems were left supported within the medium for long times. This approach can be immediately used in diverse areas, contributing to tissue engineering, flexible electronics, particle engineering, smart materials, and encapsulation technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 475, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 1, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500655", "DOI": "10.1126/sciadv.1500655", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500655", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216596900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lundt, N; Klembt, S; Cherotchenko, E; Betzold, S; Iff, O; Nalitov, AV; Klaas, M; Dietrich, CP; Kavokin, AV; Höfling, S; Schneider, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lundt, Nils; Klembt, Sebastian; Cherotchenko, Evgeniia; Betzold, Simon; Iff, Oliver; Nalitov, Anton V.; Klaas, Martin; Dietrich, Christof P.; Kavokin, Alexey V.; Hoefling, Sven; Schneider, Christian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature Tamm-plasmon exciton-polaritons with a WSe2 monolayer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state cavity quantum electrodynamics is a rapidly advancing field, which explores the frontiers of light-matter coupling. Metal-based approaches are of particular interest in this field, as they carry the potential to squeeze optical modes to spaces significantly below the diffraction limit. Transition metal dichalcogenides are ideally suited as the active material in cavity quantum electrodynamics, as they interact strongly with light at the ultimate monolayer limit. Here, we implement a Tamm-plasmon-polariton structure and study the coupling to a monolayer of WSe2, hosting highly stable excitons. Exciton-polariton formation at room temperature is manifested in the characteristic energy-momentum dispersion relation studied in photoluminescence, featuring an anti-crossing between the exciton and photon modes with a Rabi-splitting of 23.5 meV. Creating polaritonic quasiparticles in monolithic, compact architectures with atomic monolayers under ambient conditions is a crucial step towards the exploration of nonlinearities, macroscopic coherence and advanced spinor physics with novel, low-mass bosons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13328, "DOI": "10.1038/ncomms13328", "DOI Link": "http://dx.doi.org/10.1038/ncomms13328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386514900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhachu, DS; Moniz, SJA; Sathasivam, S; Scanlon, DO; Walsh, A; Bawaked, SM; Mokhtar, M; Obaid, AY; Parkin, IP; Tang, JW; Carmalt, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhachu, Davinder S.; Moniz, Savio J. A.; Sathasivam, Sanjayan; Scanlon, David O.; Walsh, Aron; Bawaked, Salem M.; Mokhtar, Mohamed; Obaid, Abdullah Y.; Parkin, Ivan P.; Tang, Junwang; Carmalt, Claire J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuth oxyhalides: synthesis, structure and photoelectrochemical activity", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the synthesis and photoelectrochemical assessment of phase pure tetragonal matlockite structured BiOX (where X = Cl, Br, I) films. The materials were deposited using aerosol-assisted chemical vapour deposition. The measured optical bandgaps of the oxyhalides, supported by density functional theory calculations, showed a red shift with the increasing size of halide following the binding energy of the anion p-orbitals that form the valence band. Stability and photoelectrochemical studies carried out without a sacrificial electron donor showed the n-type BiOBr film to have the highest photocurrent reported for BiOBr in the literature to date (0.3 mA cm(-2) at 1.23 V vs. RHE), indicating it is an excellent candidate for solar fuel production with a very low onset potential of 0.2 V vs. RHE. The high performance was attributed to the preferred growth of the film in the [011] direction, as shown by X-ray diffraction, leading to internal electric fields that minimize charge carrier recombination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4832, "End Page": 4841, "Article Number": null, "DOI": "10.1039/c6sc00389c", "DOI Link": "http://dx.doi.org/10.1039/c6sc00389c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380893900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hirschberger, M; Nakajima, T; Gao, S; Peng, LC; Kikkawa, A; Kurumaji, T; Kriener, M; Yamasaki, Y; Sagayama, H; Nakao, H; Ohishi, K; Kakurai, K; Taguchi, Y; Yu, XZ; Arima, T; Tokura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hirschberger, Max; Nakajima, Taro; Gao, Shang; Peng, Licong; Kikkawa, Akiko; Kurumaji, Takashi; Kriener, Markus; Yamasaki, Yuichi; Sagayama, Hajime; Nakao, Hironori; Ohishi, Kazuki; Kakurai, Kazuhisa; Taguchi, Yasujiro; Yu, Xiuzhen; Arima, Taka-hisa; Tokura, Yoshinori", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skyrmion phase and competing magnetic orders on a breathing kagome lattice", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmion textures are realized mainly in non-centrosymmetric, e.g. chiral or polar, magnets. Extending the field to centrosymmetric bulk materials is a rewarding challenge, where the released helicity/vorticity degree of freedom and higher skyrmion density result in intriguing new properties and enhanced functionality. We report here on the experimental observation of a skyrmion lattice (SkL) phase with large topological Hall effect and an incommensurate helical pitch as small as 2.8 nm in metallic Gd3Ru4Al12, which materializes a breathing kagome lattice of Gadolinium moments. The magnetic structure of several ordered phases, including the SkL, is determined by resonullt x-ray diffraction as well as small angle neutron scattering. The SkL and helical phases are also observed directly using Lorentz-transmission electron microscopy. Among several competing phases, the SkL is promoted over a low-temperature transverse conical state by thermal fluctuations in an intermediate range of magnetic fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 24", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5831, "DOI": "10.1038/s41467-019-13675-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13675-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509780700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, T; Wang, Y; Zheng, YS; Wang, L; He, X; Li, LQ; Deng, YF; Dong, H; Tian, HK; Geng, YH; Xie, LH; Lei, Y; Ling, HF; Ji, DY; Hu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Ting; Wang, Yiru; Zheng, Yingshuang; Wang, Le; He, Xiang; Li, Liqiang; Deng, Yunfeng; Dong, Huanli; Tian, Hongkun; Geng, Yanhou; Xie, Linghai; Lei, Yong; Ling, Haifeng; Ji, Deyang; Hu, Wenping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tetrachromatic vision-inspired neuromorphic sensors with ultraweak ultraviolet detection", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sensing and recognizing invisible ultraviolet (UV) light is vital for exploiting advanced artificial visual perception system. However, due to the uncertainty of the natural environment, the UV signal is very hard to be detected and perceived. Here, inspired by the tetrachromatic visual system, we report a controllable UV-ultrasensitive neuromorphic vision sensor (NeuVS) that uses organic phototransistors (OPTs) as the working unit to integrate sensing, memory and processing functions. Benefiting from asymmetric molecular structure and unique UV absorption of the active layer, the as fabricated UV-ultrasensitive NeuVS can detect 370nm UV-light with the illumination intensity as low as 31nWcm(-2), exhibiting one of the best optical figures of merit in UV-sensitive neuromorphic vision sensors. Furthermore, the NeuVS array exbibits good image sensing and memorization capability due to its ultrasensitive optical detection and large density of charge trapping states. In addition, the wavelength-selective response and multi-level optical memory properties are utilized to construct an artificial neural network for extract and identify the invisible UV information. The NeuVS array can perform static and dynamic image recognition from the original color image by filtering red, green and blue noise, and significantly improve the recognition accuracy from 46 to 90%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2281, "DOI": "10.1038/s41467-023-37973-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37973-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, JS; Nebgen, BT; Zubatyuk, R; Lubbers, N; Devereux, C; Barros, K; Tretiak, S; Isayev, O; Roitberg, AE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Justin S.; Nebgen, Benjamin T.; Zubatyuk, Roman; Lubbers, Nicholas; Devereux, Christian; Barros, Kipton; Tretiak, Sergei; Isayev, Olexandr; Roitberg, Adrian E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching coupled cluster accuracy with a general-purpose neural network potential through transfer learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational modeling of chemical and biological systems at atomic resolution is a crucial tool in the chemist's toolset. The use of computer simulations requires a balance between cost and accuracy: quantum-mechanical methods provide high accuracy but are computationally expensive and scale poorly to large systems, while classical force fields are cheap and scalable, but lack transferability to new systems. Machine learning can be used to achieve the best of both approaches. Here we train a general-purpose neural network potential (ANI-1ccx) that approaches CCSD(T)/CBS accuracy on benchmarks for reaction thermochemistry, isomerization, and drug-like molecular torsions. This is achieved by training a network to DFT data then using transfer learning techniques to retrain on a dataset of gold standard QM calculations (CCSD(T)/CBS) that optimally spans chemical space. The resulting potential is broadly applicable to materials science, biology, and chemistry, and billions of times faster than CCSD(T)/CBS calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2903, "DOI": "10.1038/s41467-019-10827-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10827-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473296000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muthukumar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muthukumar, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "50th Anniversary Perspective: A Perspective on Polyelectrolyte Solutions", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "From the beginning of life with the information-containing polymers until the present era of a plethora of water-based materials in health care industry and biotechnology, polyelectrolytes are ubiquitous with a broad range of structural and functional properties. The main attribute of polyelectrolyte solutions is that all molecules are strongly correlated both topologically and electrostatically in their neutralizing background of charged ions in highly polarizable solvent. These strong correlations and the necessary use of numerous variables in experiments on polyelectrolytes have presented immense challenges toward fundamental understanding of the various behaviors of charged polymeric systems. This Perspective presents the author's subjective summary of several conceptual advances and the remaining persistent challenges in the contexts of charge and size of polymers, structures in homogeneous solutions, thermodynamic instability and phase transitions, structural evolution with oppositely charged polymers, dynamics in polyelectrolyte solutions, kinetics of phase separation, mobility of charged macromolecules between compartments, and implications to biological systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 26", "Publication Year": 2017, "Volume": 50, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9528, "End Page": 9560, "Article Number": null, "DOI": "10.1021/acs.macromol.7b01929", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.7b01929", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418991000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Laniel, D; Winkler, B; Fedotenko, T; Pakhomova, A; Chariton, S; Milman, V; Prakapenka, V; Dubrovinsky, L; Dubrovinskaia, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Laniel, Dominique; Winkler, Bjoern; Fedotenko, Timofey; Pakhomova, Anna; Chariton, Stella; Milman, Victor; Prakapenka, Vitali; Dubrovinsky, Leonid; Dubrovinskaia, Natalia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Pressure Polymeric Nitrogen Allotrope with the Black Phosphorus Structure", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Studies of polynitrogen phases are of great interest for fundamental science and for the design of novel high energy density materials. Laser heating of pure nitrogen at 140 GPa in a diamond anvil cell led to the synthesis of a polymeric nitrogen allotrope with the black phosphorus structure, bp-N. The structure was identified in situ using synchrotron single-crystal x-ray diffraction and further studied by Raman spectroscopy and density functional theory calculations. The discovery of bp-N brings nitrogen in line with heavier pnictogen elements, resolves incongruities regarding polymeric nitrogen phases and provides insights into polynitrogen arrangements at extreme densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2020, "Volume": 124, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 216001, "DOI": "10.1103/PhysRevLett.124.216001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.216001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535862200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akkerman, QA; Abdelhady, AL; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akkerman, Quinten A.; Abdelhady, Ahmed L.; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zero-Dimensional Cesium Lead Halides: History, Properties, and Challenges", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the past decade, lead halide perovskites (LHPs) have emerged as new promising materials in the fields of photovoltaics and light emission due to their facile syntheses and exciting optical properties. The enthusiasm generated by LHPs has inspired research in perovskite-related materials, including the so-called zero-dimensional cesium lead halides, which will be the focus of this Perspective. The structure of these materials is formed of disconnected lead halide octahedra that are stabilized by cesium ions. Their optical properties are dominated by optical transitions that are localized within the individual octahedra, hence the title 'zero-dimensional perovskites. Controversial results on their physical properties have recently been reported, and the true nature of their photoluminescence is still unclear. In this Perspective, we will take a close look at these materials, both as nullocrystals and as bulk crystals/thin films, discuss the contrasting opinions on their properties, propose potential applications, and provide an outlook on future experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2018, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2326, "End Page": 2337, "Article Number": null, "DOI": "10.1021/acs.jpclett.8b00572", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.8b00572", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431724400035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, M; Bi, C; Yuan, YB; Bai, Y; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Miao; Bi, Cheng; Yuan, Yongbo; Bai, Yang; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized Wide Bandgap MAPbBrxI3-x Perovskite by Enhanced Grain Size and Improved Crystallinity", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The light instability of CH3NH3PbIxBr3-x is one of the biggest challenges for its application in tandem solar cells. Here we show that an improved crystallinity and grain size of CH3NH3PbIxBr3-x films could stabilize these materials under one sun illumination, improving both the efficiency and stability of the wide-bandgap perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500301, "DOI": "10.1002/advs.201500301", "DOI Link": "http://dx.doi.org/10.1002/advs.201500301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379934800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Chen, JQ; Yang, JH; Liu, JS; Tong, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yong; Chen, Jian-Qi; Yang, Jiang-Hao; Liu, Ji-Shan; Tong, Wang-Shu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of shale macroscale modulus based on microscale measurement: A case study concerning multiscale mechanical characteristics", "Source Title": "PETROLEUM SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shale mechanical properties are important for shale gas production, but the magnitudes are difficult to estimate, standard size cores are hard to sample, and secondary interstice generation is inevitable. This paper proposes a method for determining shale macroscale modulus, which is determined at a hierarchy of scales from the nullo-to macro-scales. Microscale measurements are upscaled to estimate the corresponding magnitudes at the macroscale. A case study is conducted with Silurian shale samples, using the hierarchy scales, gridding nulloindentation, atomic force microscopy (AFM), mineral liberation analysis (MLA), X-ray diffraction (XRD), and uniaxial compression tests. The mineral compositions are analyzed using MLA and XRD, and the shale composition is described in terms of clay minerals, organic matter, and siliceous and carbonate contents. The variation in the Young's modulus is analyzed based on the recorded indentation depth curves and modulus distributions. The nulloindentation and AFM results are upscaled to the centimeter scale through the Mori-Tanaka method. The upscaled results exhibit satisfactory fitting with the conventional uniaxial compression results, although the fitting of the upscaled AFM results is better than nulloindentation. The proposed approach can be applied to promptly and comprehensively predict the shale mechanical parameters during shale gas exploration. (c) 2021 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 19, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1262, "End Page": 1275, "Article Number": null, "DOI": "10.1016/j.petsci.2021.10.004", "DOI Link": "http://dx.doi.org/10.1016/j.petsci.2021.10.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826759500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CY; Jiang, T; Hou, JH; Zhang, TT; Zhang, GS; Zhang, YC; Wang, XZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Changyan; Jiang, Ting; Hou, Jianhua; Zhang, Tingting; Zhang, Geshan; Zhang, Yongcai; Wang, Xiaozhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen vacancies induced narrow band gap of BiOCl for efficient visible-light catalytic performance from double radicals", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a high-efficiency photocatalytic BiOCl material with a visible light absorption range was successfully prepared by one-pot molecular self-assembly and particle recrystallization method at room temperature. In the process of crystal growth, tartaric acid, as a structure control agent, gradually transforms the stacked two-dimensional nullo-sheet-like BiOCl into a hierarchical structure composed of petal-like nullo-sheets through hydrogen bonding. Besides, the acid etching of organic carboxylic acid on the crystal surface increases the number of micropores and mesopores, thereby the reaction interface. The thiourea (TU) molecules adsorbed on the BiOCl surface with a strong electronic effect introduce oxygen vacancies (OVs) under the condition of low oxygen content. The synergistic effect of hierarchical structure and OVs reduces the recombination of photogenerated carriers, but absorbs more O-2 and OH- to generate a large number of superoxide radicals (center dot O-2(-)) and hydroxyl radicals (center dot OH) effectively. The photocatalytic performance of the synthesized BiOCl material has been significantly improved, and it can effectively degrade 94.15% of rhodamine B (RhB) within 20 min. Furthermore, 90.95% of tetracycline (TC), 93.76% of ciprofloxacin (CIP), and 85.53% of methyl orange (MO) can be removed in 80 min. Therefore, our work provides an effective method for preparing BiOCl with visible light catalytic activity, which, of course, can be used to treat and repair actual environmental problems under mild conditions. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 114, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": 248, "Article Number": null, "DOI": "10.1016/j.jmst.2021.12.006", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2021.12.006", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788137300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, YL; Li, CL; Lu, S; Wang, ZZ; Liu, S; Yu, XJ; Li, XP; Sun, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yuling; Li, Chonglu; Lu, Shuai; Wang, Zhizheng; Liu, Shuang; Yu, Xiujun; Li, Xiaopeng; Sun, Yao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of emissive ruthenium(II) metallacycle over 1000 nm wavelength for in vivo biomedical applications", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although Ru(II)-based agents are expected to be promising candidates for substituting Pt-drug, their in vivo biomedical applications are still limited by the short excitation/emission wavelengths and unsatisfactory therapeutic efficiency. Herein, we rationally design a Ru(II) metallacycle with excitation at 808 nm and emission over 1000 nm, namely Ru1085, which holds deep optical penetration (up to 6 mm) and enhanced chemo-phototherapy activity. In vitro studies indicate that Ru1085 exhibits prominent cell uptake and desirable anticancer capability against various cancer cell lines, especially for cisplatin-resistant A549 cells. Further studies reveal Ru1085 induces mitochondria-mediated apoptosis along with S and G2/M phase cell cycle arrest. Finally, Ru1085 shows precise NIR-II fluorescence imaging guided and long-term monitored chemo-phototherapy against A549 tumor with minimal side effects. We envision that the design of long-wavelength emissive metallacycle will offer emerging opportunities of metal-based agents for in vivo biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2009, "DOI": "10.1038/s41467-022-29572-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29572-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000782630700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YT; Tang, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yantao; Tang, Hongwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Automatic Damage Detection and Diagnosis for Hydraulic Structures Using Drones and Artificial Intelligence Techniques", "Source Title": "REMOTE SENSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-volume hydraulic concrete structures, such as concrete dams, often suffer from damage due to the influence of alternating loads and material aging during the service process. The occurrence and further expansion of cracks will affect the integrity, impermeability, and durability of the dam concrete. Therefore, monitoring the changing status of cracks in hydraulic concrete structures is very important for the health service of hydraulic engineering. This study combines computer vision and artificial intelligence methods to propose an automatic damage detection and diagnosis method for hydraulic structures. Specifically, to improve the crack feature extraction effect, the Xception backbone network, which has fewer parameters than the ResNet backbone network, is adopted. With the aim of addressing the problem of premature loss of image detail information and small target information of tiny cracks in hydraulic concrete structures, an adaptive attention mechanism image semantic segmentation algorithm based on Deeplab V3+ network architecture is proposed. Crack images collected from concrete structures of different types of hydraulic structures were used to develop crack datasets. The experimental results show that the proposed method can realize high-precision crack identification, and the identification results have been obtained in the test set, achieving 90.537% Intersection over Union (IOU), 91.227% Precision, 91.301% Recall, and 91.264% F1_score. In addition, the proposed method has been verified on different types of cracks in actual hydraulic concrete structures, further illustrating the effectiveness of the method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 615, "DOI": "10.3390/rs15030615", "DOI Link": "http://dx.doi.org/10.3390/rs15030615", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Geology; Remote Sensing; Imaging Science & Photographic Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931369000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XZ; Shi, XY; Ning, HH; Yang, R; Lu, B; Luo, Q; Mao, SJ; Xi, LL; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaozhong; Shi, Xiaoyun; Ning, Honghui; Yang, Rui; Lu, Bing; Luo, Qian; Mao, Shanjun; Xi, Lingling; Wang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring a local acid-like microenvironment for efficient neutral hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of neutral hydrogen evolution catalysts is challenging due to their sluggish kinetics. Here the authors report HxWO3 support which acts as proton sponge to create a local acid-like microenvironment around Ir sites, realizing acid-like hydrogen evolution rate in neutral media. Electrochemical hydrogen evolution reaction in neutral media is listed as the most difficult challenges of energy catalysis due to the sluggish kinetics. Herein, the Ir-HxWO3 catalyst is readily synthesized and exhibits enhanced performance for neutral hydrogen evolution reaction. HxWO3 support is functioned as proton sponge to create a local acid-like microenvironment around Ir metal sites by spontaneous injection of protons to WO3, as evidenced by spectroscopy and electrochemical analysis. Rationalize revitalized lattice-hydrogen species located in the interface are coupled with H-ad atoms on metallic Ir surfaces via thermodynamically favorable Volmer-Tafel steps, and thereby a fast kinetics. Elaborated Ir-HxWO3 demonstrates acid-like activity with a low overpotential of 20 mV at 10 mA cm(-2) and low Tafel slope of 28 mV dec(-1), which are even comparable to those in acidic environment. The concept exemplified in this work offer the possibilities for tailoring local reaction microenvironment to regulate catalytic activity and pathway.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39963-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39963-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001033533300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Troyan, IA; Semenok, DV; Kvashnin, AG; Sadakov, AV; Sobolevskiy, OA; Pudalov, VM; Ivanova, AG; Prakapenka, VB; Greenberg, E; Gavriliuk, AG; Lyubutin, IS; Struzhkin, VV; Bergara, A; Errea, I; Bianco, R; Calandra, M; Mauri, F; Monacelli, L; Akashi, R; Oganov, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Troyan, Ivan A.; Semenok, Dmitrii V.; Kvashnin, Alexander G.; Sadakov, Andrey V.; Sobolevskiy, Oleg A.; Pudalov, Vladimir M.; Ivanova, Anna G.; Prakapenka, Vitali B.; Greenberg, Eran; Gavriliuk, Alexander G.; Lyubutin, Igor S.; Struzhkin, Viktor V.; Bergara, Aitor; Errea, Ion; Bianco, Raffaello; Calandra, Matteo; Mauri, Francesco; Monacelli, Lorenzo; Akashi, Ryosuke; Oganov, Artem R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalous High-Temperature Superconductivity in YH6", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pressure-stabilized hydrides are a new rapidly growing class of high-temperature superconductors, which is believed to be described within the conventional phonon-mediated mechanism of coupling. Here, the synthesis of one of the best-known high-T-C superconductors-yttrium hexahydride Im3 over bar m-YH6 is reported, which displays a superconducting transition at approximate to 224 K at 166 GPa. The extrapolated upper critical magnetic field B-c2(0) of YH6 is surprisingly high: 116-158 T, which is 2-2.5 times larger than the calculated value. A pronounced shift of T-C in yttrium deuteride YD6 with the isotope coefficient 0.4 supports the phonon-assisted superconductivity. Current-voltage measurements show that the critical current I-C and its density J(C) may exceed 1.75 A and 3500 A mm(-2) at 4 K, respectively, which is higher than that of the commercial superconductors, such as NbTi and YBCO. The results of superconducting density functional theory (SCDFT) and anharmonic calculations, together with anomalously high critical magnetic field, suggest notable departures of the superconducting properties from the conventional Migdal-Eliashberg and Bardeen-Cooper-Schrieffer theories, and presence of an additional mechanism of superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 33, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2006832, "DOI": "10.1002/adma.202006832", "DOI Link": "http://dx.doi.org/10.1002/adma.202006832", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626901900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, YN; Wu, SC; Withers, PJ; Zhang, J; Bao, HYX; Fu, YN; Kang, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Y. N.; Wu, S. C.; Withers, P. J.; Zhang, J.; Bao, H. Y. X.; Fu, Y. N.; Kang, G. Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The effect of manufacturing defects on the fatigue life of selective laser melted Ti-6Al-4V structures", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The manufacturing defects introduced by selective laser melting typically lead to lower fatigue strength and a larger variation in fatigue life compared to conventionally manufactured structures. X-ray micro computed tomography (mu CT) is used to characterize the porosity and lack of fusion defects in terms of population, morphol-ogy, dimension and location. The defect size and location are combined with the NASA/FLACGRO (NASGRO) fatigue crack growth model to predict the likely fatigue life, in which an effective initial crack length is de fined using the cyclic plastic zone and the defect radius. An eXtended defect zone (XDZ) describing the propensity for local plasticity during fatigue around a defect has been shown through numerical analysis to be a good indicator of the ranking of the threat to fatigue caused by differently located manufacturing defects. This indicates that the effect of a defect, initial radius, r(0) , is likely to be pronounced when its center is within 2r(0) of the surface and maximal when it lies just beneath the surface. (C) 2020 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108708, "DOI": "10.1016/j.matdes.2020.108708", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2020.108708", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568683200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Beck, A; Huang, X; Artiglia, L; Zabilskiy, M; Wang, X; Rzepka, P; Palagin, D; Willinger, MG; van Bokhoven, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Beck, Arik; Huang, Xing; Artiglia, Luca; Zabilskiy, Maxim; Wang, Xing; Rzepka, Przemyslaw; Palagin, Dennis; Willinger, Marc-Georg; van Bokhoven, Jeroen A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The dynamics of overlayer formation on catalyst nulloparticles and strong metal-support interaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous catalysts play a pivotal role in the chemical industry. The strong metal-support interaction (SMSI), which affects the catalytic activity, is a phenomenon researched for decades. However, detailed mechanistic understanding on real catalytic systems is lacking. Here, this surface phenomenon was studied on an actual platinum-titania catalyst by state-of-the-art in situ electron microscopy, in situ X-ray photoemission spectroscopy and in situ X-ray diffraction, aided by density functional theory calculations, providing a novel real time view on how the phenomenon occurs. The migration of reduced titanium oxide, limited in thickness, and the formation of an alloy are competing mechanisms during high temperature reduction. Subsequent exposure to oxygen segregates the titanium from the alloy, and a thicker titania overlayer forms. This role of oxygen in the formation process and stabilization of the overlayer was not recognized before. It provides new application potential in catalysis and materials science. Tuning the catalytic activity of metal nulloparticles by encapsulation is a long known process, but mechanistically poorly understood. Here, Beck and colleagues reveal the encapsulation mechanism by support material and the outstanding role of oxygen in the encapsulation mechanism by extensive in situ characterization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 203, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17070-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17070-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544946300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, BW; Kedem, N; Kulbak, M; Lee, DY; Yang, WS; Jeon, NJ; Seo, J; Kim, G; Kim, KJ; Shin, TJ; Hodes, G; Cahen, D; Seok, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Byung-wook; Kedem, Nir; Kulbak, Michael; Lee, Do Yoon; Yang, Woon Seok; Jeon, Nam Joong; Seo, Jangwon; Kim, Geonhwa; Kim, Ki Jeong; Shin, Tae Joo; Hodes, Gary; Cahen, David; Seok, Sang Il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding how excess lead iodide precursor improves halide perovskite solar cell performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The presence of excess lead iodide in halide perovskites has been key for surpassing 20% photon-to-power conversion efficiency. To achieve even higher power conversion efficiencies, it is important to understand the role of remnullt lead iodide in these perovskites. To that end, we explored the mechanism facilitating this effect by identifying the impact of excess lead iodide within the perovskite film on charge diffusion length, using electron-beam-induced current measurements, and on film formation properties, from grazing-incidence wide-angle X-ray scattering and high-resolution transmission electron microscopy. Based on our results, we propose that excess lead iodide in the perovskite precursors can reduce the halide vacancy concentration and lead to formation of azimuthal angle-oriented cubic alpha-perovskite crystals in-between 0 degrees and 90 degrees. We further identify a higher perovskite carrier concentration inside the nullostructured titanium dioxide layer than in the capping layer. These effects are consistent with enhanced lead iodide-rich perovskite solar cell performance and illustrate the role of lead iodide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3301, "DOI": "10.1038/s41467-018-05583-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05583-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441865600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Li, F; Li, YF; Chen, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yu; Li, Feng; Li, Yafei; Chen, Zhongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Semi-metallic Be5C2 monolayer global minimum with quasi-planar pentacoordinate carbons and negative Poisson's ratio", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing new materials with novel topological properties and reduced dimensionality is always desirable for material innovation. Here we report the design of a two-dimensional material, namely Be5C2 monolayer on the basis of density functional theory computations. In Be5C2 monolayer, each carbon atom binds with five beryllium atoms in almost the same plane, forming a quasi-planar pentacoordinate carbon moiety. Be5C2 monolayer appears to have good stability as revealed by its moderate cohesive energy, positive phonon modes and high melting point. It is the lowest-energy structure with the Be5C2 stoichiometry in two-dimensional space and therefore holds some promise to be realized experimentally. Be5C2 monolayer is a gapless semiconductor with a Dirac-like point in the band structure and also has an unusual negative Poisson's ratio. If synthesized, Be5C2 monolayer may find applications in electronics and mechanics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11488, "DOI": "10.1038/ncomms11488", "DOI Link": "http://dx.doi.org/10.1038/ncomms11488", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375223500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nembach, HT; Shaw, JM; Weiler, M; Jué, E; Silva, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nembach, Hans T.; Shaw, Justin M.; Weiler, Mathias; Jue, Emilie; Silva, Thomas J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Linear relation between Heisenberg exchange and interfacial Dzyaloshinskii-Moriya interaction in metal films", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proposals for novel spin-orbitronic logic(1) and memory devices(2) are often predicated on assumptions as to how materials with large spin-orbit coupling interact with ferromagnets when in contact. Such interactions give rise to a host of novel phenomena, such as spin-orbit torques(3,4), chiral spin structures(5,6) and chiral spin torques(7,8). These chiral properties are related to the antisymmetric exchange, also referred to as the interfacial Dzyaloshinskii-Moriya interaction (DMI; refs 9,10). For numerous phenomena, the relative strengths of the symmetric Heisenberg exchange and the DMI are of great importance. Here, we use optical spin-wave spectroscopy (Brillouin light scattering) to directly determine the volume-averaged DMI vector D for a series of Ni80Fe20/Pt thin films, and then compare the nearest-neighbour DMI coupling energy with an independently measured value of the Heisenberg exchange for each sample. We show that the dependence on Ni80Fe20 thickness of both the microscopic symmetric and antisymmetric exchange are nearly identical, consistent with the notion that the fundamentals of the DMI and Heisenberg exchange essentially share the same underlying physics, albeit with different symmetries, as was originally proposed by Moriya(11) for superexchange in magnetic oxides, and by Fert and Levy(12) for RKKY coupling in metallic spin glasses. Indeed, our result demonstrates the generality of the original DMI theory, insofar as the proportionality of the symmetric and antisymmetric exchange is robust with regard to the details of spin coupling for the material system in question. Although of significant fundamental importance, this result also leads us to a deeper understanding of DMI and how it could be optimized for spin-orbitronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 11, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 825, "End Page": "U139", "Article Number": null, "DOI": "10.1038/NPHYS3418", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3418", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362188600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Y; Du, XQ; Hou, Z; Shen, X; Mai, YW; Tarascon, JM; Zhang, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yao; Du, Xiaoqiong; Hou, Zhen; Shen, Xi; Mai, Yiu-Wing; Tarascon, Jean-Marie; Zhang, Biao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling the mechanical origin of stable solid electrolyte interphase", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capability of a solid electrolyte interphase (SEI) in accommodating deformation is critical to the electrode integrity. However, the nulloscale thickness and environmental sensitivity of SEI make it challenging to characterize multiple mechanical parameters and identify an appropriate predictor for such capability. Here, we develop a feasible atomic force microscopy (AFM)-based nulloindentation test that circumvents the interference of the anode substrate and allows accurate probing of Young's modulus and elastic strain limit of SEI, The maximum elastic deformation energy (U) that an SEI can absorb is proposed to predict the stability of the SEI, as successfully demonstrated in Li/K metal anodes. We show that another asset of U is to provide a rapid and effective means to screen proper electrolytes for the stabilization of Sn and Sb microparticle anodes through building high-U SEIs. Overall, this new indicator, U, offers future directions toward rational design of robust SEIs for advanced anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2021, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1860, "End Page": 1872, "Article Number": null, "DOI": "10.1016/j.joule.2021.05.015", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.05.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000675889700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, BS; Hsu, YT; Zeng, B; Hatnean, MC; Harrison, N; Zhu, Z; Hartstein, M; Kiourlappou, M; Srivastava, A; Johannes, MD; Murphy, TP; Park, JH; Balicas, L; Lonzarich, GG; Balakrishnull, G; Sebastian, SE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, B. S.; Hsu, Y. -T.; Zeng, B.; Hatnean, M. Ciomaga; Harrison, N.; Zhu, Z.; Hartstein, M.; Kiourlappou, M.; Srivastava, A.; Johannes, M. D.; Murphy, T. P.; Park, J. -H.; Balicas, L.; Lonzarich, G. G.; Balakrishnull, G.; Sebastian, Suchitra E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional Fermi surface in an insulating state", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Insulators occur in more than one guise; a recent finding was a class of topological insulators, which host a conducting surface juxtaposed with an insulating bulk. Here, we report the observation of an unusual insulating state with an electrically insulating bulk that simultaneously yields bulk quantum oscillations with characteristics of an unconventional Fermi liquid. We present quantum oscillation measurements of magnetic torque in high-purity single crystals of the Kondo insulator SmB6, which reveal quantum oscillation frequencies characteristic of a large three-dimensional conduction electron Fermi surface similar to the metallic rare earth hexaborides such as PrB6 and LaB6. The quantum oscillation amplitude strongly increases at low temperatures, appearing strikingly at variance with conventional metallic behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2015, "Volume": 349, "Issue": 6245, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 287, "End Page": 290, "Article Number": null, "DOI": "10.1126/science.aaa7974", "DOI Link": "http://dx.doi.org/10.1126/science.aaa7974", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358218600046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, Y; Liu, S; Rhodes, DA; Watanabe, K; Taniguchi, T; Hone, J; Elser, V; Mak, KF; Shan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yang; Liu, Song; Rhodes, Daniel A.; Watanabe, Kenji; Taniguchi, Takashi; Hone, James; Elser, Veit; Mak, Kin Fai; Shan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlated insulating states at fractional fillings of moire superlattices", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum particles on a lattice with competing long-range interactions are ubiquitous in physics; transition metal oxides(1,2), layered molecular crystals(3) and trapped-ion arrays(4) are a few examples. In the strongly interacting regime, these systems often show a rich variety of quantum many-body ground states that challenge theory(2). The emergence of transition metal dichalcogenide moire superlattices provides a highly controllable platform in which to study long-range electronic correlations(5-12). Here we report an observation of nearly two dozen correlated insulating states at fractional fillings of tungsten diselenide/tungsten disulfide moire superlattices. This finding is enabled by a new optical sensing technique that is based on the sensitivity to the dielectric environment of the exciton excited states in a single-layer semiconductor of tungsten diselenide. The cascade of insulating states shows an energy ordering that is nearly symmetric about a filling factor of half a particle per superlattice site. We propose a series of charge-ordered states at commensurate filling fractions that range from generalized Wigner crystals(7) to charge density waves. Our study lays the groundwork for using moire superlattices to simulate a wealth of quantum many-body problems that are described by the two-dimensional extended Hubbard model(3,13,14) or spin models with long-range charge-charge and exchange interactions(15,16). An optical sensing technique reveals an abundance of correlated insulating states at fractional fillings of moire superlattices that are proposed to arise from a series of charge-ordered states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2020, "Volume": 587, "Issue": 7833, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2868-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2868-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000588830300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, LC; Liu, WD; Li, M; Wang, DZ; Wu, H; Wang, YF; Zhang, LX; Shi, XL; Liu, QF; Chen, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Liang-Cao; Liu, Wei-Di; Li, Meng; Wang, De-Zhuang; Wu, Hao; Wang, Yifeng; Zhang, Lixiong; Shi, Xiao-Lei; Liu, Qingfeng; Chen, Zhi-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interstitial Cu: An Effective Strategy for High Carrier Mobility and High Thermoelectric Performance in GeTe", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dense point defects can strengthen phonon scattering to reduce the lattice thermal conductivity and induce outstanding thermoelectric performance in GeTe-based materials. However, extra point defects inevitably enlarge carrier scattering and deteriorate carrier mobility. Herein, it is found that the interstitial Cu in GeTe can result in synergistic effects, which include: 1) strengthened phonon scattering, leading to ultralow lattice thermal conductivity of 0.48 W m(-1) K-1 at 623 K; 2) weakened carrier scattering, contributing to high carrier mobility of 80 cm(2) V-1 s(-1) at 300 K; 3) optimized carrier concentration of 1.22 x 10(20) cm(-3). Correspondingly, a high figure-of-merit of approximate to 2.3 at 623 K can be obtained in the Ge0.93Ti0.01Bi0.06Te-0.01Cu, which corresponds to a maximum energy conversion efficiency of approximate to 10% at a temperature difference of 423 K. This study systematically investigates the doping behavior of the interstitial Cu in GeTe-based thermoelectric materials for the first time and demonstrates that the localized interstitial Cu is a new strategy to enhance the thermoelectric performance of GeTe-based thermoelectric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 33, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202301750", "DOI Link": "http://dx.doi.org/10.1002/adfm.202301750", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000947046700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Zhu, YJ; Ding, WF; Qiu, YT; Wang, LF; Xu, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yang; Zhu, Yejun; Ding, Wenfeng; Qiu, Yutong; Wang, Lifeng; Xu, Jiuhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vibration coupling effects and machining behavior of ultrasonic vibration plate device for creep-feed grinding of Inconel 718 nickel-based superalloy", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrasonic vibration-assisted grinding (UVAG) is an effective and promising method for machining of hard-to-cut materials. This article proposed an ultrasonic vibration plate device enabling the longitudinal full-wave and transverse half-wave (L2T1) vibration mode for UVAG. The characteristics of two-dimensional coupled vibration in different directions were analyzed on the basis of apparent elastic method and finite element method. Furthermore, a correction factor was applied to correct the frequency error caused by the apparent elastic method. Finally, the com-parative experiments between the conventional creep-feed grinding and UVAG of Inconel 718 nickel-based superalloy were carried out. The results indicate that the apparent elastic method with the correction factor is accurate for the design of plate device under the L2T1 vibration mode. Com-pared with the conventional creep-feed grinding, the UVAG causes the reduction of grinding force and the improvement of machined surface quality of Inconel 718 nickel-based superalloy. Further-more, under the current experimental conditions, the optimal ultrasonic vibration amplitude is determined as 6 lm, with which the minimum surface roughness is achieved. (c) 2021 Chinese Society of Aeronautics and Astronautics and Beihang University. Production and hosting by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons. org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 35, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 332, "End Page": 345, "Article Number": null, "DOI": "10.1016/j.cja.2020.12.039", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2020.12.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783649300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortazavi, B; Podryabinkin, EV; Novikov, IS; Rabczuk, T; Zhuang, XY; Shapeev, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortazavi, Bohayra; Podryabinkin, Evgeny, V; Novikov, Ivan S.; Rabczuk, Timon; Zhuang, Xiaoying; Shapeev, Alexander, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating first-principles estimation of thermal conductivity by machine-learning interatomic potentials: A MTP/ShengBTE solution", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate evaluation of the thermal conductivity of a material can be a challenging task from both experimental and theoretical points of view. In particular for the nullostructured materials, the experimental measurement of thermal conductivity is associated with diverse sources of uncertainty. As a viable alternative to experiment, the combination of density functional theory (DFT) simulations and the solution of Boltzmann transport equation is currently considered as the most trusted approach to examine thermal conductivity. The main bottleneck of the aforementioned method is to acquire the anharmonic interatomic force constants using the computationally demanding DFT calculations. In this work we propose a substantially accelerated approach for the evaluation of anharmonic interatomic force constants via employing machine-learning interatomic potentials (MLIPs) trained over short ab initio molecular dynamics trajectories. The remarkable accuracy of the proposed accelerated method is confirmed by comparing the estimated thermal conductivities of several bulk and two-dimensional materials with those computed by the full-DFT approach. The MLIP-based method proposed in this study can be employed as a standard tool, which would substantially accelerate and facilitate the estimation of lattice thermal conductivity in comparison with the commonly used full-DFT solution. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 258, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107583, "DOI": "10.1016/j.cpc.2020.107583", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2020.107583", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000587360000029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, Q; Ye, L; Xu, BW; An, CB; Stuard, SJ; Zhang, SQ; Yao, HF; Ade, H; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Qian; Ye, Long; Xu, Bowei; An, Cunbin; Stuard, Samuel J.; Zhang, Shaoqing; Yao, Huifeng; Ade, Harald; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Printable Organic Cathode Interlayer Enables over 13% Efficiency for 1-cm2 Organic Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, most cathode interlayer (CIL) materials for organic solar cells (OSCs) cannot be processed by printing techniques, which severely limits their use in practical productions. Herein, we report a naphthalene diimide (NDI)-based small-molecular compound (N,N-dimethylamino) propyl naphthalene diimide (NDI-N) as printable CIL for OSCs. NDI-N exhibits a unique advantage that combines the merits of high crystallinity and good film-forming property in one material, endowing the semiconductor with excellent electron-transport properties and good processability. By using the NDI-N as CIL, a high power-conversion efficiency (PCE) of 13.9% was achieved in a PBDB-T-2F:IT-4F-based OSC device. More importantly, a large-area OSC device of 1 cm(2) was fabricated by using the blade-coated NDI-N CIL and an outstanding PCE of 13.2% was achieved, which represents the highest efficiency of large-area OSCs. The results in this work may pave the way for low-cost and mass production of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 239, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.024", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Levengood, SKL; Zhang, MQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Levengood, Sheeny K. Lan; Zhang, Miqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chitosan-based scaffolds for bone tissue engineering", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bone defects requiring grafts to promote healing are frequently occurring and costly problems in health care. Chitosan, a biodegradable, naturally occurring polymer, has drawn considerable attention in recent years as a scaffolding material in tissue engineering and regenerative medicine. Chitosan is especially attractive as a bone scaffold material because it supports the attachment and proliferation of osteoblast cells as well as formation of mineralized bone matrix. In this review, we discuss the fundamentals of bone tissue engineering and the unique properties of chitosan as a scaffolding material to treat bone defects for hard tissue regeneration. We present common methods for fabrication and characterization of chitosan scaffolds, and discuss the influence of material preparation and addition of polymeric or ceramic components or biomolecules on chitosan scaffold properties such as mechanical strength, structural integrity, and functional bone regeneration. Finally, we highlight recent advances in the development of chitosan-based scaffolds with enhanced bone regeneration capability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 485, "Times Cited, All Databases": 523, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 2, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3161, "End Page": 3184, "Article Number": null, "DOI": "10.1039/c4tb00027g", "DOI Link": "http://dx.doi.org/10.1039/c4tb00027g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336072400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, N; Weng, HM; Lv, BQ; Matt, CE; Park, J; Bisti, F; Strocov, VN; Gawryluk, D; Pomjakushina, E; Conder, K; Plumb, NC; Radovic, M; Autès, G; Yazyev, OV; Fang, Z; Dai, X; Qian, T; Mesot, J; Ding, H; Shi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, N.; Weng, H. M.; Lv, B. Q.; Matt, C. E.; Park, J.; Bisti, F.; Strocov, V. N.; Gawryluk, D.; Pomjakushina, E.; Conder, K.; Plumb, N. C.; Radovic, M.; Autes, G.; Yazyev, O. V.; Fang, Z.; Dai, X.; Qian, T.; Mesot, J.; Ding, H.; Shi, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Weyl nodes and Fermi arcs in tantalum phosphide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Weyl semimetal possesses spin-polarized band-crossings, called Weyl nodes, connected by topological surface arcs. The low-energy excitations near the crossing points behave the same as massless Weyl fermions, leading to exotic properties like chiral anomaly. To have the transport properties dominated by Weyl fermions, Weyl nodes need to locate nearly at the chemical potential and enclosed by pairs of individual Fermi surfaces with non-zero Fermi Chern numbers. Combining angle-resolved photoemission spectroscopy and first-principles calculation, here we show that TaP is a Weyl semimetal with only a single type of Weyl fermions, topologically distinguished from TaAs where two types of Weyl fermions contribute to the low-energy physical properties. The simple Weyl fermions in TaP are not only of fundamental interests but also of great potential for future applications. Fermi arcs on the Ta-terminated surface are observed, which appear in a different pattern from that on the As-termination in TaAs and NbAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11006, "DOI": "10.1038/ncomms11006", "DOI Link": "http://dx.doi.org/10.1038/ncomms11006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372226300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, S; Ma, Q; Andersen, T; Mcleod, AS; Fei, Z; Liu, MK; Wagner, M; Watanabe, K; Taniguchi, T; Thiemens, M; Keilmann, F; Jarillo-Herrero, P; Fogler, MM; Basov, DN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, S.; Ma, Q.; Andersen, T.; Mcleod, A. S.; Fei, Z.; Liu, M. K.; Wagner, M.; Watanabe, K.; Taniguchi, T.; Thiemens, M.; Keilmann, F.; Jarillo-Herrero, P.; Fogler, M. M.; Basov, D. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subdiffractional focusing and guiding of polaritonic rays in a natural hyperbolic material", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uniaxial materials whose axial and tangential permittivities have opposite signs are referred to as indefinite or hyperbolic media. In such materials, light propagation is unusual leading to novel and often non-intuitive optical phenomena. Here we report infrared nullo-imaging experiments demonstrating that crystals of hexagonal boron nitride, a natural mid-infrared hyperbolic material, can act as a 'hyper-focusing lens' and as a multi-mode waveguide. The lensing is manifested by subdiffractional focusing of phonon-polaritons launched by metallic disks underneath the hexagonal boron nitride crystal. The waveguiding is revealed through the modal analysis of the periodic patterns observed around such launchers and near the sample edges. Our work opens new opportunities for anisotropic layered insulators in infrared nullophotonics complementing and potentially surpassing concurrent artificial hyperbolic materials with lower losses and higher optical localization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6963, "DOI": "10.1038/ncomms7963", "DOI Link": "http://dx.doi.org/10.1038/ncomms7963", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, RZ; Riddle, M; Graziano, D; Warren, J; Das, S; Nimbalkar, S; Cresko, J; Masanet, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Runze; Riddle, Matthew; Graziano, Diane; Warren, Joshua; Das, Sujit; Nimbalkar, Sachin; Cresko, Joe; Masanet, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) holds great potential for improving materials efficiency, reducing life-cycle impacts, and enabling greater engineering functionality compared to conventional manufacturing (CM), and AM has been increasingly adopted by aircraft component manufacturers for lightweight, costeffective designs. This study estimates the net changes in life-cycle primary energy and greenhouse gas emissions associated with AM technologies for lightweight metallic aircraft components through the year 2050, to shed light on the environmental benefits of a shift from CM to AM processes in the U.S. aircraft industry. A systems modeling framework is presented, with integrates engineering criteria, life cycle environmental data, aircraft fleet stock and fuel use models under different AM adoption scenarios. Estimated fleet-wide life-cycle primary energy savings at most reach 70-173 million GJ/year in 2050, with cumulative savings of 1.2-2.8 billion GJ. Associated cumulative GHG emission reductions were estimated at 92.1-215.0 million metric tons. In addition, thousands of tons of aluminum, titanium and nickel alloys could be potentially saved per year in 2050. The results indicate a significant role of AM technologies in helping society meet its long-term energy use and GHG emissions reduction goals, and highlight barriers and opportunities for AM adoption for the aircraft industry. (C) 2015 Elsevier Ltd. All rights", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2016, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1559, "End Page": 1570, "Article Number": null, "DOI": "10.1016/j.jclepro.2015.04.109", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2015.04.109", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382792900133", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seko, A; Hayashi, H; Nakayama, K; Takahashi, A; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seko, Atsuto; Hayashi, Hiroyuki; Nakayama, Keita; Takahashi, Akira; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Representation of compounds for machine-learning prediction of physical properties", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The representations of a compound, called descriptors or features, play an essential role in constructing a machine-learning model of its physical properties. In this study, we adopt a procedure for generating a set of descriptors from simple elemental and structural representations. First, it is applied to a large data set composed of the cohesive energy for about 18 000 compounds computed by density functional theory calculation. As a result, we obtain a kernel ridge prediction model with a prediction error of 0.041 eV/atom, which is close to the chemical accuracy of 1 kcal/mol (0.043 eV/atom). A prediction model with an error of 0.071 eV/atom of the cohesive energy is obtained for the normalized prototype structures, which can be used for the practical purpose of searching for as-yet-unknown structures. The procedure is also applied to two smaller data sets, i.e., a data set of the lattice thermal conductivity for 110 compounds computed by density functional theory calculation and a data set of the experimental melting temperature for 248 compounds. We examine the effect of the descriptor sets on the efficiency of Bayesian optimization in addition to the accuracy of the kernel ridge regression models. They exhibit good predictive performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2017, "Volume": 95, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144110, "DOI": "10.1103/PhysRevB.95.144110", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.144110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399792400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kruk, S; Hopkins, B; Kravchenko, II; Miroshnichenko, A; Neshev, DN; Kivshar, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kruk, Sergey; Hopkins, Ben; Kravchenko, Ivan I.; Miroshnichenko, Andrey; Neshev, Dragomir N.; Kivshar, Yuri S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Invited Article: Broadband highly efficient dielectric metadevices for polarization control", "Source Title": "APL PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metadevices based on dielectric nullostructured surfaces with both electric and magnetic Mie-type resonullces have resulted in the best efficiency to date for functional flat optics with only one disadvantage: a narrow operational bandwidth. Here we experimentally demonstrate broadband transparent all-dielectric metasurfaces for highly efficient polarization manipulation. We utilize the generalized Huygens principle, with a superposition of the scattering contributions from several electric and magnetic multipolar modes of the constituent meta-atoms, to achieve destructive interference in reflection over a large spectral bandwidth. By employing this novel concept, we demonstrate reflectionless (similar to 90% transmission) half-wave plates, quarter-wave plates, and vector beam q-plates that can operate across multiple telecom bands with similar to 99% polarization conversion efficiency. (C) 2016 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 30801, "DOI": "10.1063/1.4949007", "DOI Link": "http://dx.doi.org/10.1063/1.4949007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385587700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muthuraj, R; Lacoste, C; Lacroix, P; Bergeret, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muthuraj, Rajendran; Lacoste, Clement; Lacroix, Patrick; Bergeret, Anne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainable thermal insulation biocomposites from rice husk, wheat husk, wood fibers and textile waste fibers: Elaboration and performances evaluation", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Building materials derived from agricultural and industrial waste are becoming more attractive in the civil engineering and architectural applications because of their sustainability and lower environmental impact. In addition, substantial value can be added to the wastes by producing value added products from them. Therefore, four different types of locally available by-products (rice husk, wheat husk, wood fibers and textile waste fibers) were used to produce composites with a biodegradable poly(butylene adipate-co-terephthalate)/poly(lactic acid) (PBAT/PLA) blend binder by hot pressing. The morphological analysis of the composites revealed that the PBAT/ PLA binder had more affinity with wood and textile fibers than with wheat and rice husks. The prepared composites showed thermal stability until 250 degrees C. All the prepared biodegradable composites exhibited good compressive strength (11-40 MPa) and flexural strength (0.80-2.25 MPa). The observed mechanical properties allow easy handling without risk of breaking them when positioned in the buildings. The biodegradable composites were characterized for their thermal conductivity, diffusivity, effusivity and heat capacity. The density and thermal conductivity of the produced composite was in the range of 378-488 kg/m(3) and 0.08-0.14 W/m.K, respectively. The least thermal conductivity ie. 0.08 W/m.K was observed for the rice husk composite with a density of 378 kg/m(3) . A minimum water absorption (42%) was found in the rice husk composites after 24 h immersion in water. The composite samples were still cohesive after 24 h immersion in the water because of the water resistance nature of the binder. The prepared biodegradable composites meet most of the required properties for the indoor building insulation applications and show great potential to replace the conventional building material in current use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 135, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 238, "End Page": 245, "Article Number": null, "DOI": "10.1016/j.indcrop.2019.04.053", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2019.04.053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471086000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Crossno, J; Shi, JK; Wang, K; Liu, XM; Harzheim, A; Lucas, A; Sachdev, S; Kim, P; Taniguchi, T; Watanabe, K; Ohki, TA; Fong, KC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Crossno, Jesse; Shi, Jing K.; Wang, Ke; Liu, Xiaomeng; Harzheim, Achim; Lucas, Andrew; Sachdev, Subir; Kim, Philip; Taniguchi, Takashi; Watanabe, Kenji; Ohki, Thomas A.; Fong, Kin Chung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the Dirac fluid and the breakdown of the Wiedemann-Franz law in graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interactions between particles in quantum many-body systems can lead to collective behavior described by hydrodynamics. One such system is the electron-hole plasma in graphene near the charge-neutrality point, which can form a strongly coupled Dirac fluid. This charge-neutral plasma of quasi-relativistic fermions is expected to exhibit a substantial enhancement of the thermal conductivity, thanks to decoupling of charge and heat currents within hydrodynamics. Employing high-sensitivity Johnson noise thermometry, we report an order of magnitude increase in the thermal conductivity and the breakdown of the Wiedemann-Franz law in the thermally populated charge-neutral plasma in graphene. This result is a signature of the Dirac fluid and constitutes direct evidence of collective motion in a quantum electronic fluid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 519, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2016, "Volume": 351, "Issue": 6277, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1058, "End Page": 1061, "Article Number": null, "DOI": "10.1126/science.aad0343", "DOI Link": "http://dx.doi.org/10.1126/science.aad0343", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371597500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shu, JC; Zhang, YL; Qin, Y; Cao, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shu, Jin-Cheng; Zhang, Yan-Lan; Qin, Yong; Cao, Mao-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxidative Molecular Layer Deposition Tailoring Eco-Mimetic nulloarchitecture to Manipulate Electromagnetic Attenuation and Self-Powered Energy Conversion", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced electromagnetic devices, as the pillars of the intelligent age, are setting off a grand transformation, redefining the structure of society to present pluralism and diversity. However, the bombardment of electromagnetic radiation on society is also increasingly serious along with the growing popularity of Big Data. Herein, drawing wisdom and inspiration from nature, an eco-mimetic nulloarchitecture is constructed for the first time, highly integrating the advantages of multiple components and structures to exhibit excellent electromagnetic response. Its electromagnetic properties and internal energy conversion can be flexibly regulated by tailoring microstructure with oxidative molecular layer deposition (oMLD), providing a new cognition to frequency-selective microwave absorption. The optimal reflection loss reaches approximate to - 58 dB, and the absorption frequency can be shifted from high frequency to low frequency by increasing the number of oMLD cycles. Meanwhile, a novel electromagnetic absorption surface is designed to enable ultra-wideband absorption, covering almost the entire K and Ka bands. More importantly, an ingenious self-powered device is constructed using the eco-mimetic nulloarchitecture, which can convert electromagnetic radiation into electric energy for recycling. This work offers a new insight into electromagnetic protection and waste energy recycling, presenting a broad application prospect in radar stealth, information communication, aerospace engineering, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1007/s40820-023-01112-7", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01112-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000999079700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bao, WZ; Wan, JY; Han, XG; Cai, XH; Zhu, HL; Kim, DH; Ma, DK; Xu, YL; Munday, JN; Drew, HD; Fuhrer, MS; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bao, Wenzhong; Wan, Jiayu; Han, Xiaogang; Cai, Xinghan; Zhu, Hongli; Kim, Dohun; Ma, Dakang; Xu, Yunlu; Munday, Jeremy N.; Drew, H. Dennis; Fuhrer, Michael S.; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching the limits of transparency and conductivity in graphitic materials through lithium intercalation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various band structure engineering methods have been studied to improve the performance of graphitic transparent conductors; however, none has demonstrated an increase of optical transmittance in the visible range. Here we measure in situ optical transmittance spectra and electrical transport properties of ultrathin graphite (3-60 graphene layers) simultaneously during electrochemical lithiation/delithiation. On intercalation, we observe an increase of both optical transmittance (up to twofold) and electrical conductivity (up to two orders of magnitude), strikingly different from other materials. Transmission as high as 91.7% with a sheet resistance of 3.0 Omega per square is achieved for 19-layer LiC6, which corresponds to a figure of merit sigma(dc)/sigma(opt) = 1,400, significantly higher than any other continuous transparent electrodes. The unconventional modification of ultrathin graphite optoelectronic properties is explained by the suppression of interband optical transitions and a small intraband Drude conductivity near the interband edge. Our techniques enable investigation of other aspects of intercalation in nullostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4224, "DOI": "10.1038/ncomms5224", "DOI Link": "http://dx.doi.org/10.1038/ncomms5224", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340614000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, XY; Xing, GZ; Sheng, SP; Jin, LM; Zhang, Y; Zhu, DW; Mei, L; Dong, X; Lv, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Xuya; Xing, Guozheng; Sheng, Shupei; Jin, Limin; Zhang, Yan; Zhu, Dunwan; Mei, Lin; Dong, Xia; Lv, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neutrophil Camouflaged Stealth nullovehicle for Photothermal-Induced Tumor Immunotherapy by Triggering Pyroptosis", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The regulation of tumor immunosuppressive microenvironments via precise drug delivery is a promising strategy for preventing tumor recurrence and metastasis. Inspired by the stealth strategy, a stealthy nullovehicle based on neutrophil camouflage is developed to achieve precise delivery and tumor immunotherapy by triggering pyroptosis. The nullovehicle comprises anti-CD11b- and IR820-conjugated bovine serum albumin nulloparticles loaded with decitabine. Camouflaged by neutrophils, the nullovehicles achieve efficient tumor delivery by neutrophil hitchhiking owing to the biotropism of neutrophils for tumors. The fluorescent signal molecule, IR820, on the nullovehicle acts as a navigation monitor to track the precise delivery of the nullovehicle. The released decitabine upregulates gasdermin E, and laser irradiation activates caspase-3, thereby resulting in pyroptosis, which improves the system's adaptive immune response. In a triple-negative breast cancer animal model, it regulates the immunosuppressive microenvironment for effective tumor immunotherapy and induces a long-lasting and strong immune memory to prevent lung metastasis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207456", "DOI Link": "http://dx.doi.org/10.1002/advs.202207456", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952089500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Torrejon, J; Kim, J; Sinha, J; Mitani, S; Hayashi, M; Yamanouchi, M; Ohno, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Torrejon, Jacob; Kim, Junyeon; Sinha, Jaivardhan; Mitani, Seiji; Hayashi, Masamitsu; Yamanouchi, Michihiko; Ohno, Hideo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface control of the magnetic chirality in CoFeB/MgO heterostructures with heavy-metal underlayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in the understanding of spin orbital effects in ultrathin magnetic hetero-structures have opened new paradigms to control magnetic moments electrically. The Dzyaloshinskii-Moriya interaction (DMI) is said to play a key role in forming a Neel-type domain wall that can be driven by the spin Hall torque. Here we show that the strength and sign of the DMI can be changed by modifying the adjacent heavy-metal underlayer (X) in perpendicularly magnetized X/CoFeB/MgO heterostructures. The sense of rotation of a domain wall spiral is reversed when the underlayer is changed from Hf, Ta to W and the strength of DMI varies as the filling of 5d orbitals, or the electronegativity, of the heavy-metal layer changes. The DMI can even be tuned by adding nitrogen to the underlayer, thus allowing interface engineering of the magnetic texture in ultrathin magnetic heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 364, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4655, "DOI": "10.1038/ncomms5655", "DOI Link": "http://dx.doi.org/10.1038/ncomms5655", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341057500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cadiz, F; Courtade, E; Robert, C; Wang, G; Shen, Y; Cai, H; Taniguchi, T; Watanabe, K; Carrere, H; Lagarde, D; Manca, M; Amand, T; Renucci, P; Tongay, S; Marie, X; Urbaszek, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cadiz, F.; Courtade, E.; Robert, C.; Wang, G.; Shen, Y.; Cai, H.; Taniguchi, T.; Watanabe, K.; Carrere, H.; Lagarde, D.; Manca, M.; Amand, T.; Renucci, P.; Tongay, S.; Marie, X.; Urbaszek, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitonic Linewidth Approaching the Homogeneous Limit in MoS2-Based van der Waals Heterostructures", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The strong light-matter interaction and the valley selective optical selection rules make monolayer (ML) MoS2 an exciting 2D material for fundamental physics and optoelectronics applications. But, so far, optical transition linewidths even at low temperature are typically as large as a few tens of meV and contain homogeneous and inhomogeneous contributions. This prevented in-depth studies, in contrast to the better-characterized ML materials MoSe2 and WSe2. In this work, we show that encapsulation of ML MoS2 in hexagonal boron nitride can efficiently suppress the inhomogeneous contribution to the exciton linewidth, as we measure in photoluminescence and reflectivity a FWHM down to 2 meV at T = 4 K. Narrow optical transition linewidths are also observed in encapsulated WS2, WSe2, and MoSe2 MLs. This indicates that surface protection and substrate flatness are key ingredients for obtaining stable, high-quality samples. Among the new possibilities offered by the well-defined optical transitions, we measure the homogeneous broadening induced by the interaction with phonons in temperature-dependent experiments. We uncover new information on spin and valley physics and present the rotation of valley coherence in applied magnetic fields perpendicular to the ML.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 577, "Times Cited, All Databases": 638, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21026, "DOI": "10.1103/PhysRevX.7.021026", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.7.021026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401662800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, P; Vo, T; Cha, MJ; Visheratina, A; Kim, JY; Xu, WQ; Schwartz, J; Simon, A; Katz, D; Nicu, VP; Marino, E; Choi, WJ; Veksler, M; Chen, S; Murray, C; Hovden, R; Glotzer, S; Kotov, NA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Prashant; Vo, Thi; Cha, Minjeong; Visheratina, Anastasia; Kim, Ji-Young; Xu, Wenqian; Schwartz, Jonathan; Simon, Alexander; Katz, Daniel; Nicu, Valentin Paul; Marino, Emanuele; Choi, Won Jin; Veksler, Michael; Chen, Si; Murray, Christopher; Hovden, Robert; Glotzer, Sharon; Kotov, Nicholas A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonically active bowtie nulloassemblies with chirality continuum", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chirality is a geometrical property described by continuous mathematical functions(1-5). However, in chemical disciplines, chirality is often treated as a binary left or right characteristic of molecules rather than a continuity of chiral shapes. Although they are theoretically possible, a family of stable chemical structures with similar shapes and progressively tuneable chirality is yet unknown. Here we show that nullostructured microparticles with an anisotropic bowtie shape display chirality continuum and can be made with widely tuneable twist angle, pitch, width, thickness and length. The self-limited assembly of the bowties enables high synthetic reproducibility, size monodispersity and computational predictability of their geometries for different assembly conditions(6). The bowtie nulloassemblies show several strong circular dichroism peaks originating from absorptive and scattering phenomena. Unlike classical chiral molecules, these particles show a continuum of chirality measures(2) that correlate exponentially with the spectral positions of the circular dichroism peaks. Bowtie particles with variable polarization rotation were used to print photonically active metasurfaces with spectrally tuneable positive or negative polarization signatures for light detection and ranging (LIDAR) devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2023, "Volume": 615, "Issue": 7952, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 418, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05733-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05733-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954374800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carr, S; Massatt, D; Fang, S; Cazeaux, P; Luskin, M; Kaxiras, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carr, Stephen; Massatt, Daniel; Fang, Shiang; Cazeaux, Paul; Luskin, Mitchell; Kaxiras, Efthimios", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Twistronics: Manipulating the electronic properties of two-dimensional layered structures through their twist angle", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability in experiments to control the relative twist angle between successive layers in two-dimensional (2D) materials offers an approach to manipulating their electronic properties; we refer to this approach as twistronics. A major challenge to theory is that, for arbitrary twist angles, the resulting structure involves incommensurate (aperiodic) 2D lattices. Here, we present a general method for the calculation of the electronic density of states of aperiodic 2D layered materials, using parameter-free Hamiltonians derived from ab initio density-functional theory. We use graphene, a semimetal, and MoS2, a representative of the transition-metal dichalcogenide family of 2D semiconductors, to illustrate the application of our method, which enables fast and efficient simulation of multilayered stacks in the presence of local disorder and external fields. We comment on the interesting features of their density of states as a function of twist angle and local configuration and on how these features can be experimentally observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2017, "Volume": 95, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75420, "DOI": "10.1103/PhysRevB.95.075420", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.075420", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394368000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zomer, PJ; Guimaraes, MHD; Brant, JC; Tombros, N; van Wees, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zomer, P. J.; Guimaraes, M. H. D.; Brant, J. C.; Tombros, N.; van Wees, B. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast pick up technique for high quality heterostructures of bilayer graphene and hexagonal boron nitride", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a fast method to fabricate high quality heterostructure devices by picking up crystals of arbitrary sizes. Bilayer graphene is encapsulated with hexagonal boron nitride to demonstrate this approach, showing good electronic quality with mobilities ranging from 17 000 cm(2) V-1 s(-1) at room temperature to 49 000 cm(2) V-1 s(-1) at 4.2 K, and entering the quantum Hall regime below 0.5 T. This method provides a strong and useful tool for the fabrication of future high quality layered crystal devices. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2014, "Volume": 105, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13101, "DOI": "10.1063/1.4886096", "DOI Link": "http://dx.doi.org/10.1063/1.4886096", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339664900066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, F; Dai, J; Chen, YT; Zhu, JF; Jin, Y; Bozhevolnyi, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Fei; Dai, Jin; Chen, Yiting; Zhu, Jianfei; Jin, Yi; Bozhevolnyi, Sergey I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband near-infrared metamaterial absorbers utilizing highly lossy metals", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Radiation absorbers have increasingly been attracting attention as crucial components for controllable thermal emission, energy harvesting, modulators, etc. However, it is still challenging to realize thin absorbers which can operate over a wide spectrum range. Here, we propose and experimentally demonstrate thin, broadband, polarization-insensitive and omnidirectional absorbers working in the near-infrared range. We choose titanium (Ti) instead of the commonly used gold (Au) to construct nullo-disk arrays on the top of a silicon dioxide (SiO2) coated Au substrate, with the quality (Q) factor of the localized surface plasmon (LSP) resonullce being decreased due to the intrinsic high loss of Ti. The combination of this low-Q LSP resonullce and the propagating surface plasmon (PSP) excitation resonullce, which occur at different wavelengths, is the fundamental origin of the broadband absorption. The measured (at normal light incidence) absorption is over 90% in the wavelength range from 900 nm to 1825 nm, with high absorption persisting up to the incident angle of similar to 40 degrees. The demonstrated thin-film absorber configuration is relatively easy to fabricate and can be realized with other properly selected materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 39445, "DOI": "10.1038/srep39445", "DOI Link": "http://dx.doi.org/10.1038/srep39445", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390211000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sporrer, L; Zhou, GJ; Wang, MC; Balos, V; Revuelta, S; Jastrzembski, K; Löffler, M; Petkov, P; Heine, T; Kuc, A; Cánovas, E; Huang, ZH; Feng, XL; Dong, RH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sporrer, Lukas; Zhou, Guojun; Wang, Mingchao; Balos, Vasileios; Revuelta, Sergio; Jastrzembski, Kamil; Loeffler, Markus; Petkov, Petko; Heine, Thomas; Kuc, Angieszka; Canovas, Enrique; Huang, Zhehao; Feng, Xinliang; Dong, Renhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near IR Bandgap Semiconducting 2D Conjugated Metal-Organic Framework with Rhombic Lattice and High Mobility", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional conjugated metal-organic frameworks (2D c-MOFs) are emerging as a unique class of electronic materials. However, 2D c-MOFs with band gaps in the Vis-NIR and high charge carrier mobility are rare. Most of the reported conducting 2D c-MOFs are metallic (i.e. gapless), which largely limits their use in logic devices. Herein, we design a phenullthrotriphenylene-based, D-2h-symmetric pi-extended ligand (OHPTP), and synthesize the first rhombic 2D c-MOF single crystals (Cu-2(OHPTP)). The continuous rotation electron diffraction (cRED) analysis unveils the orthorhombic crystal structure at the atomic level with a unique slipped AA stacking. The Cu-2(OHPTP) is a p-type semiconductor with an indirect band gap of approximate to 0.50 eV and exhibits high electrical conductivity of 0.10 S cm(-1) and high charge carrier mobility of approximate to 10.0 cm(2) V-1 s(-1). Theoretical calculations underline the predominullt role of the out-of-plane charge transport in this semiquinone-based 2D c-MOF.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2023, "Volume": 62, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202300186", "DOI Link": "http://dx.doi.org/10.1002/anie.202300186", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000985073400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Wen, P; Itanze, DS; Hood, ZD; Ma, X; Kim, M; Adhikari, S; Lu, C; Dun, CC; Chi, MF; Qiu, YJ; Geyer, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hui; Wen, Peng; Itanze, Dominique S.; Hood, Zachary D.; Ma, Xiao; Kim, Michael; Adhikari, Shiba; Lu, Chang; Dun, Chaochao; Chi, Miaofang; Qiu, Yejun; Geyer, Scott M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloidal silver diphosphide (AgP2) nullocrystals as low overpotential catalysts for CO2 reduction to tunable syngas", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Production of syngas with tunable CO/H-2 ratio from renewable resources is an ideal way to provide a carbon-neutral feedstock for liquid fuel production. Ag is a benchmark electrocatalysts for CO2-to-CO conversion but high overpotential limits the efficiency. We synthesize AgP2 nullocrystals (NCs) with a greater than 3-fold reduction in overpotential for electrochemical CO2-to-CO reduction compared to Ag and greatly enhanced stability. Density functional theory calculations reveal a significant energy barrier decrease in the formate intermediate formation step. In situ X-ray absorption spectroscopy (XAS) shows that a maximum Faradaic efficiency is achieved at an average silver valence state of +1.08 in AgP2 NCs. A photocathode consisting of a n(+)p-Si wafer coated with ultrathin Al2O3 and AgP2 NCs achieves an onset potential of 0.2 V vs. RHE for CO production and a partial photocurrent density for CO at -0.11 V vs. RHE (j(-0.11, CO)) of -3.2 mA cm(-2). Conversion of CO2 into value-added chemicals by use of renewable energy is promising to achieve a carbon-neutral energy cycle. Here, the authors show that AgP2 is a stable, selective and efficient syngas catalyst for solar-to-fuel conversion with a 3-fold lower overpotential compared to the benchmark Ag catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2019, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5724, "DOI": "10.1038/s41467-019-13388-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13388-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000879385700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kotov, OV; Lozovik, YE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kotov, O. V.; Lozovik, Yu. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dielectric response and novel electromagnetic modes in three-dimensional Dirac semimetal films", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using the Kubo formalism we have calculated the local dynamic conductivity of a bulk, i.e., three-dimensional (3D), Dirac semimetal (BDS). We obtain that at frequencies lower than Fermi energy the metallic response in a BDS film manifests in the existence of surface-plasmon polaritons, but at higher frequencies the dielectric response is dominated and it occurs that a BDS film behaves as a dielectric waveguide. At this dielectric regime we predict the existence inside a BDS film of novel electromagnetic modes, a 3D analog of the transverse electric waves in graphene. We also find that the dielectric response manifests as the wide-angle passband in the mid-infrared (IR) transmission spectrum of light incident on aBDS film, which can be used for the interferenceless omnidirectional mid-IR filtering. The tuning of the Fermi level of the system allows us to switch between the metallic and the dielectric regimes and to change the frequency range of the predicted modes. This makes BDSs promising materials for photonics and plasmonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2016, "Volume": 93, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235417, "DOI": "10.1103/PhysRevB.93.235417", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.235417", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377799800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kasahara, S; Watashige, T; Hanaguri, T; Kohsaka, Y; Yamashita, T; Shimoyama, Y; Mizukami, Y; Endo, R; Ikeda, H; Aoyama, K; Terashima, T; Uji, S; Wolf, T; von Löhneysen, H; Shibauchi, T; Matsuda, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kasahara, Shigeru; Watashige, Tatsuya; Hanaguri, Tetsuo; Kohsaka, Yuhki; Yamashita, Takuya; Shimoyama, Yusuke; Mizukami, Yuta; Endo, Ryota; Ikeda, Hiroaki; Aoyama, Kazushi; Terashima, Taichi; Uji, Shinya; Wolf, Thomas; von Loehneysen, Hilbert; Shibauchi, Takasada; Matsuda, Yuji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-induced superconducting phase of FeSe in the BCS-BEC cross-over", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fermi systems in the cross-over regime between weakly coupled Bardeen-Cooper-Schrieffer (BCS) and strongly coupled Bose-Einstein-condensate (BEC) limits are among the most fascinating objects to study the behavior of an assembly of strongly interacting particles. The physics of this cross-over has been of considerable interest both in the fields of condensed matter and ultracold atoms. One of the most challenging issues in this regime is the effect of large spin imbalance on a Fermi system under magnetic fields. Although several exotic physical properties have been predicted theoretically, the experimental realization of such an unusual superconducting state has not been achieved so far. Here we show that pure single crystals of superconducting FeSe offer the possibility to enter the previously unexplored realm where the three energies, Fermi energy epsilon(F), superconducting gap Delta, and Zeeman energy, become comparable. Through the superfluid response, transport, thermoelectric response, and spectroscopic-imaging scanning tunneling microscopy, we demonstrate that epsilon(F) of FeSe is extremely small, with the rati Delta/epsilon(F) similar to 1(similar to 0.3) in the electron (hole) band. Moreover, thermal-conductivity measurements give evidence of a distinct phase line below the upper critical field, where the Zeeman energy becomes comparable to epsilon(F) and Delta. The observation of this field-induced phase provides insights into previously poorly understood aspects of the highly spin-polarized Fermi liquid in the BCS-BEC cross-over regime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2014, "Volume": 111, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16309, "End Page": 16313, "Article Number": null, "DOI": "10.1073/pnas.1413477111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1413477111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345153300035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tong, QJ; Yu, HY; Zhu, QZ; Wang, Y; Xu, XD; Yao, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tong, Qingjun; Yu, Hongyi; Zhu, Qizhong; Wang, Yong; Xu, Xiaodong; Yao, Wang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological mosaics in moire superlattices of van der Waals heterobilayers", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals (vdW) heterostructures formed by twodimensional atomic crystals provide a powerful approach towards designer condensed matter systems1-15. Incommensurate heterobilayers with small twisting and/or lattice mismatch lead to the interesting concept of moire superlattices2-7, where the atomic registry is locally indistinguishable from commensurate bilayers but has local-to-local variation over long range. Here we show that such moire superlattices can lead to periodic modulation of local topological order in vdW heterobilayers formed by two massive Dirac materials. By tuning the vdW heterojunction from normal to the inverted type-II regime via an interlayer bias, the commensurate heterobilayer can become a topological insulator (TI), depending on the interlayer hybridization controlled by the atomic registry between the vdW layers. This results in a mosaic pattern of TI regions and normal insulator (NI) regions in moire superlattices, where topologically protected helical modes exist at the TI/NI phase boundaries. By using symmetry-based k . p and tight-binding models, we predict that this topological phenomenon can be present in inverted transition metal dichalcogenides heterobilayers. Our work points to a new means of realizing programmable and electrically switchable topological superstructures from two-dimensional arrays of TI nullo-dots to one-dimensional arrays of TI nullo-stripes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 356, "End Page": 362, "Article Number": null, "DOI": "10.1038/NPHYS3968", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398262900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hui, SC; Zhou, X; Zhang, LM; Wu, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hui, Shengchong; Zhou, Xu; Zhang, Limin; Wu, Hongjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Multiphase-Induced Interfacial Polarization to Surpass Defect-Induced Polarization in Multielement Sulfide Absorbers", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The extremely weak heterointerface construction of high-entropy materials (HEM) hinders them being the electromagnetic wave (EMW) absorbers with ideal properties. To address this issue, this study proposes multiphase interfacial engineering and results in a multiphase-induced interfacial polarization loss in multielement sulfides. Through the selection of atoms with diverse reaction activities, the multiphase interfacial components of CuS (1 0 5), Fe0.5Ni0.5S2 (2 1 0), and CuFe2S3 (2 0 0) are constructed to enhance the interfacial polarization loss in multielement Cu-based sulfides. Compared with single-phase high-entropy Zn-based sulfides (ZnFeCoNiCr-S), the multiphase Cu-based sulfides (CuFeCoNiCr-S) possess optimized EMW absorption properties (effective absorption bandwidth (EAB) of 6.70 GHz at 2.00 mm) due to the existence of specific interface of CuS (1 0 5)/CuFe2S3 (2 0 0) with proper EM parameters. Furthermore, single-phase ZnFeCoNiCr-S into FeNi2S4 (3 1 1)/(Zn, Fe)S (1 1 1) heterointerface through 400 degrees C heat-treated is decomposed. The EMW absorption properties are enhanced by strong interfacial polarization (EAB of 4.83 GHz at 1.45 mm). This work reveals the reasons for the limited EMW absorption properties of high-entropy sulfides and proposes multiphase interface engineering to improve charge accumulation and polarization between specific interfaces, leading to the enhanced EMW absorption properties. This work shows that the weak electron exchange effect induced by high conformational entropy adversely affects microwave absorption. Constructing the heterointerfaces with significantly different work functions in multi-element sulfides can effectively enhance the phase interface polarization and eliminate these negative effects. This is expected to serve as a new design guideline for microwave absorbers.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2024, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202307649", "DOI Link": "http://dx.doi.org/10.1002/advs.202307649", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001113438000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zen, N; Puurtinen, TA; Isotalo, TJ; Chaudhuri, S; Maasilta, IJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zen, Nobuyuki; Puurtinen, Tuomas A.; Isotalo, Tero J.; Chaudhuri, Saumyadip; Maasilta, Ilari J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering thermal conductance using a two-dimensional phononic crystal", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling thermal transport has become relevant in recent years. Traditionally, this control has been achieved by tuning the scattering of phonons by including various types of scattering centres in the material (nulloparticles, impurities, etc). Here we take another approach and demonstrate that one can also use coherent band structure effects to control phonon thermal conductance, with the help of periodically nullostructured phononic crystals. We perform the experiments at low temperatures below 1K, which not only leads to negligible bulk phonon scattering, but also increases the wavelength of the dominullt thermal phonons by more than two orders of magnitude compared to room temperature. Thus, phononic crystals with lattice constants >= 1 mu m are shown to strongly reduce the thermal conduction. The observed effect is in quantitative agreement with the theoretical calculation presented, which accurately determined the ballistic thermal conductance in a phononic crystal device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3435, "DOI": "10.1038/ncomms4435", "DOI Link": "http://dx.doi.org/10.1038/ncomms4435", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334300400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, W; Zhang, KC; Osvet, A; Zhang, JY; Gruber, W; Forberich, K; Meyer, B; Heiss, W; Unruh, T; Li, N; Brabec, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Wei; Zhang, Kaicheng; Osvet, Andres; Zhang, Jiyun; Gruber, Wolfgang; Forberich, Karen; Meyer, Bernd; Heiss, Wolfgang; Unruh, Tobias; Li, Ning; Brabec, Christoph J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the strain-associated physical mechanisms impacting the performance and stability of perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identification and investigation of strain at buried interfaces in halide perovskite photovoltaics are crucial for directing research on the performance and stability of perovskite solar cells. In this work, we find a gradual shift in the band gap of up to 60 meV over a perovskite layer thickness of 300 nm caused by interfacial strain. This graded band gap is desired insofar as it relates to the aspect of device engineering. However, in parallel, the increased defect density causes charge recombination at the buried interface. These two effects compensate for each other, resulting in an overall performance improvement under standard 1 sun illumination. Nevertheless, the disadvantage of enhanced defect density is clearly observed at low-light intensities, where the device performance becomes dominated by charge recombination and ion migration. Moreover, the strained interfaces are proven to induce enhanced defect densities, causing significantly accelerated device degradation under illumination as well as in the dark.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2022, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 458, "End Page": "+", "Article Number": null, "DOI": "10.1016/j.joule.2022.01.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.01.011", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760126900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FL; Wang, SS; Zhao, CF; Hu, BW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fenglei; Wang, Shanshan; Zhao, Chaofeng; Hu, Baowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing coconut shell biochar/MXenes composites through self-assembly strategy to enhance U(VI) and Cs(I) immobilization capability", "Source Title": "BIOCHAR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, a biochar-based composite (Ti3C2Tx@biochar-PDA/PEI) was constructed by decorating Ti3C2Tx and polydopamine on coconut shell biochar via electrostatic self-assembly method. Different characterization techniques were applied to explore the structure, morphology and composition of the sorbents. It was found that the higher porosity and diverse functional groups were conducive for Ti3C2Tx@biochar-PDA/PEI to capture radionuclides, and the water environmental conditions made a great contribution to the adsorption process. The process of removing U(VI)/Cs(I) well complied with the Langmuir isotherm and Pseudo-second-order equations, which indicated that the single layer chemical adsorption occurred on the solid liquid interface. Meanwhile, this produced composite exhibited superior removal performance under complex co-existing ion environment, and the maximum adsorption amounts of U(VI) and Cs(I) reached up to 239.7 and 40.3 mg g(-1). Impressively, this adsorbent still exhibited good adsorption performance after three cycles of regeneration. The spectral analysis and DFT calculation demonstrated that adsorption of U(VI) might be a chemical process, while the adsorption of Cs(I) should be ion exchange or electrostatic attraction. This study demonstrated the potential application of Ti3C2Tx@biochar-PDA/PEI as an effective remediation strategy for radioactive wastewater cleanup.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2023, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1007/s42773-023-00231-z", "DOI Link": "http://dx.doi.org/10.1007/s42773-023-00231-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001000363600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, J; Patinet, S; Falk, ML; Cheng, YQ; Ma, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Jun; Patinet, Sylvain; Falk, Michael L.; Cheng, Yongqiang; Ma, Evan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft spots and their structural signature in a metallic glass", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In a 3D model mimicking realistic Cu64Zr36 metallic glass, we uncovered a direct link between the quasi-localized low-frequency vibrational modes and the local atomic packing structure. We also demonstrate that quasi-localized soft modes correlate strongly with fertile sites for shear transformations: geometrically unfavored motifs constitute the most flexible local environments that encourage soft modes and high propensity for shear transformations, whereas local configurations preferred in this alloy, i.e., the full icosahedra (around Cu) and Z16 Kasper polyhedra (around Zr), contribute the least.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 362, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2014, "Volume": 111, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14052, "End Page": 14056, "Article Number": null, "DOI": "10.1073/pnas.1412095111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1412095111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342350200023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, LY; Huang, HB; Xi, ZZ; Zheng, LM; Xu, SQ; Tian, G; Zhai, YZ; Guo, FF; Kong, LP; Wang, YG; Lu, WM; Yuan, L; Zhao, ML; Zheng, HW; Liu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Liya; Huang, Houbing; Xi, Zengzhe; Zheng, Limei; Xu, Shiqi; Tian, Gang; Zhai, Yuzhi; Guo, Feifei; Kong, Lingping; Wang, Yonggang; Lu, Weiming; Yuan, Long; Zhao, Minglei; Zheng, Haiwu; Liu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneously achieving giant piezoelectricity and record coercive field enhancement in relaxor-based ferroelectric crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A large coercive field (E-C) and ultrahigh piezoelectricity are essential for ferroelectrics used in high-drive electromechanical applications. The discovery of relaxor-PbTiO3 crystals is a recent breakthrough; they currently afford the highest piezoelectricity, but usually with a low E-C. Such performance deterioration occurs because high piezoelectricity is interlinked with an easy polarization rotation, subsequently favoring a dipole switch under small fields. Therefore, the search for ferroelectrics with both a large E-C and ultrahigh piezoelectricity has become an imminent challenge. Herein, ternary Pb(Sc1/2Nb1/2)O-3-Pb(Mg1/3Nb2/3)O-3-PbTiO3 crystals are reported, wherein the dispersed local heterogeneity comprises abundant tetragonal phases, affording a E-C of 8.2 kV/cm (greater than that of Pb(Mg1/3Nb2/3)O-3-PbTiO3 by a factor of three) and ultrahigh piezoelectricity (d(33) = 2630 pC/N; d(15) = 490 pC/N). The observed E-C enhancement is the largest reported for ultrahigh-piezoelectric materials, providing a simple, practical, and universal route for improving functionalities in ferroelectrics with an atomic-level understanding. High-drive electromechanical applications require ferroelectrics accounting for a large coercive field and high piezoelectricity simultaneously but it is still a challenge. Here, the authors demonstrate it in a relaxor-based ferroelectric crystal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2444, "DOI": "10.1038/s41467-022-29962-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29962-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790940000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zunino, F; Scrivener, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zunino, Franco; Scrivener, Karen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The reaction between metakaolin and limestone and its effect in porosity refinement and mechanical properties", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In limestone calcined clay cements (LC3), more hemicarboaluminate and monocarboaluminate is observed, as compared to other blended cements, from the reaction of metakaolin with limestone. In this study, it is shown that the formation of these carboaluminate phases, predominulltly occurs during a third hydration peak, after the main alite and aluminate peaks. The influence of the metakaolin content, level of sulfate addition and the water to binder ratio on the position and magnitude of this peak were investigated. This precipitation of hemi and monocarboaluminate has a significant effect on porosity refinement and strength development. It was also observed that alumina from metakaolin can contribute to the precipitation of ettringite if sufficient sulfate is available.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 140, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106307, "DOI": "10.1016/j.cemconres.2020.106307", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2020.106307", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000608762600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, MD; Jaffe, A; Dohner, ER; Lindenberg, AM; Karunadasa, HI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Matthew D.; Jaffe, Adam; Dohner, Emma R.; Lindenberg, Aaron M.; Karunadasa, Hemamala I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural origins of broadband emission from layered Pb-Br hybrid perovskites", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Through structural and optical studies of a series of two-dimensional hybrid perovskites, we show that broadband emission upon near-ultraviolet excitation is common to (001) lead-bromide perovskites. Importantly, we find that the relative intensity of the broad emission correlates with increasing out-of-plane distortion of the Pb-(mu-Br)-Pb angle in the inorganic sheets. Temperature-and power-dependent photoluminescence data obtained on a representative (001) perovskite support an intrinsic origin to the broad emission from the bulk material, where photogenerated carriers cause excited-state lattice distortions mediated through electron-lattice coupling. In contrast, most inorganic phosphors contain extrinsic emissive dopants or emissive surface sites. The design rules established here could allow us to systematically optimize white-light emission from layered hybrid perovskites by fine-tuning the bulk crystal structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2017, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4497, "End Page": 4504, "Article Number": null, "DOI": "10.1039/c7sc01590a", "DOI Link": "http://dx.doi.org/10.1039/c7sc01590a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402384900039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Linsmeier, C; Rieth, M; Aktaa, J; Chikada, T; Hoffmann, A; Hoffmann, J; Houben, A; Kurishita, H; Jin, X; Li, M; Litnovsky, A; Matsuo, S; von Müller, A; Nikolic, V; Palacios, T; Pippan, R; Qu, D; Reiser, J; Riesch, J; Shikama, T; Stieglitz, R; Weber, T; Wurster, S; You, JH; Zhou, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Linsmeier, Ch.; Rieth, M.; Aktaa, J.; Chikada, T.; Hoffmann, A.; Hoffmann, J.; Houben, A.; Kurishita, H.; Jin, X.; Li, M.; Litnovsky, A.; Matsuo, S.; von Mueller, A.; Nikolic, V.; Palacios, T.; Pippan, R.; Qu, D.; Reiser, J.; Riesch, J.; Shikama, T.; Stieglitz, R.; Weber, T.; Wurster, S.; You, J. -H.; Zhou, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of advanced high heat flux and plasma-facing materials", "Source Title": "NUCLEAR FUSION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasma-facing materials and components in a fusion reactor are the interface between the plasma and the material part. The operational conditions in this environment are probably the most challenging parameters for any material: high power loads and large particle and neutron fluxes are simultaneously impinging at their surfaces. To realize fusion in a tokamak or stellarator reactor, given the proven geometries and technological solutions, requires an improvement of the thermo-mechanical capabilities of currently available materials. In its first part this article describes the requirements and needs for new, advanced materials for the plasma-facing components. Starting points are capabilities and limitations of tungsten-based alloys and structurally stabilized materials. Furthermore, material requirements from the fusion-specific loading scenarios of a divertor in a water-cooled configuration are described, defining directions for the material development. Finally, safety requirements for a fusion reactor with its specific accident scenarios and their potential environmental impact lead to the definition of inherently passive materials, avoiding release of radioactive material through intrinsic material properties. The second part of this article demonstrates current material development lines answering the fusion-specific requirements for high heat flux materials. New composite materials, in particular fiber-reinforced and laminated structures, as well as mechanically alloyed tungsten materials, allow the extension of the thermo-mechanical operation space towards regions of extreme steady-state and transient loads. Self-passivating tungsten alloys, demonstrating favorable tungsten-like plasma-wall interaction behavior under normal operation conditions, are an intrinsic solution to otherwise catastrophic consequences of loss-of-coolant and air ingress events in a fusion reactor. Permeation barrier layers avoid the escape of tritium into structural and cooling materials, thereby minimizing the release of tritium under normal operation conditions. Finally, solutions for the unique bonding requirements of dissimilar material used in a fusion reactor are demonstrated by describing the current status and prospects of functionally graded materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 57, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 92007, "DOI": "10.1088/1741-4326/aa6f71", "DOI Link": "http://dx.doi.org/10.1088/1741-4326/aa6f71", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407854600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, J; Seko, A; Shitara, K; Nakayama, K; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Joohwi; Seko, Atsuto; Shitara, Kazuki; Nakayama, Keita; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction model of band gap for inorganic compounds by combination of density functional theory calculations and machine learning techniques", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning techniques are applied to make prediction models of the G(0)W(0) band gaps for 270 inorganic compounds using Kohn-Sham (KS) band gaps, cohesive energy, crystalline volume per atom, and other fundamental information of constituent elements as predictors. Ordinary least squares regression (OLSR), least absolute shrinkage and selection operator, and nonlinear support vector regression (SVR) methods are applied with two levels of predictor sets. When the KS band gap by generalized gradient approximation of Perdew-Burke-Ernzerhof (PBE) or modified Becke-Johnson (mBJ) is used as a single predictor, the OLSR model predicts the G(0)W(0) band gap of randomly selected test data with the root-mean-square error (RMSE) of 0.59 eV. When KS band gap by PBE and mBJ methods are used together with a set of predictors representing constituent elements and compounds, the RMSE decreases significantly. The best model by SVR yields the RMSE of 0.24 eV. Band gaps estimated in this way should be useful as predictors for virtual screening of a large set of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2016, "Volume": 93, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115104, "DOI": "10.1103/PhysRevB.93.115104", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.115104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371402800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Yang, L; Lu, XL; Liu, Q; Wang, FM; Lv, JW; Sun, T; Mu, HW; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chao; Yang, Lin; Lu, Xili; Liu, Qiang; Wang, Famei; Lv, Jingwei; Sun, Tao; Mu, Haiwei; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mid-infrared surface plasmon resonullce sensor based on photonic crystal fibers", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A surface plasmon resonullce (SPR) sensor with two open-ring channels based on a photonic crystal fiber (PCF) is described. The sensor is designed to detect low refractive indexes between 1.23 and 1.29 with the operation wavelength in mid-infrared region between 2550 nm and 2900 nm. The coupling characteristics and sensing properties are numerically analyzed by the finite element method. The average spectral sensitivity is 5500 nm/ RIU and a maximum resolution of 7.69 x 10(-6) RIU can be obtained. Our analysis shows that the PCFSPR sensor is suitable for mid-infrared detection. (C) 2017 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2017, "Volume": 25, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14227, "End Page": 14237, "Article Number": null, "DOI": "10.1364/OE.25.014238", "DOI Link": "http://dx.doi.org/10.1364/OE.25.014238", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404189800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fernulldez, ME; Nunell, GV; Bonelli, PR; Cukierman, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Emilia Fernulldez, Maria; Vanesa Nunell, Gisel; Ricardo Bonelli, Pablo; Lea Cukierman, Ana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Activated carbon from orange (Citrus sinensis) peel was developed through H-3 PO4 acid activation. Its ability as an adsorbent for the removal of two representative basic dyes (methylene blue and rhodamine B) from single and binary dyes solutions in batch and continuous modes was examined. The orange peel-based activated carbon presented a high specific surface area (1090 m(2)/g), predominullce of mesopores and acidic character. It also showed a high adsorption capacity for both dyes in batch and dynamic modes. Experimental equilibrium isotherms obtained from single-dye solutions fitted the Langmuir-Freundlich model, and those obtained from binary solutions were properly described by single and multi-component models. Breakthrough curves obtained from single-dye solutions exhibited a better removal performance for rhodamine B. Adsorption capacity at exhaustion time for this dye was 11% higher than for methylene blue. Additional experiments in dynamic conditions with a binary solution of both dyes pointed to adsorption competition for the active sites of the developed carbon. Breakthrough curves were adequately represented by a modified two-parameter model. (C) 2014 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 437, "End Page": 445, "Article Number": null, "DOI": "10.1016/j.indcrop.2014.09.015", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2014.09.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345468800059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tu, ZY; Choudhury, S; Zachman, MJ; Wei, SY; Zhang, KH; Kourkoutis, LF; Archer, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J.; Wei, Shuya; Zhang, Kaihang; Kourkoutis, Lena F.; Archer, Lynden A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Artificial Solid-Electrolyte Interphases for Single-Ion and High-Efficiency Transport in Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Substrates able to rectify transport of ions based on charge and/or size are ubiquitous in biological systems. Electrolytes and interphases that selectively transport electrochemically active ions are likewise of broad interest in all electrical energy storage technologies. In lithium-ion batteries, electrolytes with singleor near-single-ion conductivity reduce losses caused by ion polarization. In emergent lithium or sodium metal batteries, they maintain high conductivity at the anode and stabilize metal deposition by fundamental mechanisms. We report that 20- to 300-nm-thick, single-ion-conducting membranes deposited at the anode enable electrolytes with the highest combination of cation transference number, ionic conductivity, and electrochemical stability reported. By means of direct visualization we find that single-ion membranes also reduce dendritic deposition of Li in liquids. Galvanostatic measurements further show that the electrolytes facilitate long (3 mAh) recharge of full Li/LiNi0.8-Co0.15Al0.05O2 (NCA) cells with high cathode loadings (3 mAh cm(-2) /19.9 mg cm(-2)) and at high current densities (3 mA cm(-2)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2017, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 394, "End Page": 406, "Article Number": null, "DOI": "10.1016/j.joule.2017.06.002", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.06.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425180300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Checkelsky, JG; Yoshimi, R; Tsukazaki, A; Takahashi, KS; Kozuka, Y; Falson, J; Kawasaki, M; Tokura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Checkelsky, J. G.; Yoshimi, R.; Tsukazaki, A.; Takahashi, K. S.; Kozuka, Y.; Falson, J.; Kawasaki, M.; Tokura, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trajectory of the anomalous Hall effect towards the quantized state in a ferromagnetic topological insulator", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological insulators are bulk electronic insulators with symmetry-protected gapless modes on their surfaces(1-5). Breaking time-reversal symmetry in these systems via ferromagnetism induces a gapped state characterized by a zero magnetic field quantized Hall response-the quantum anomalous Hall (QAH) state(6-8). A key question that has remained experimentally unexplored is the relationship of this new type of quantum Hall (QH) state with the previously known orbitally driven QH states. Here, we show experimentally that a ferromagnetic topological insulator exhibiting the QAH state is well described by the global phase diagram of the QH effect. By mapping the conductivity tensor in the vicinity of the QAH phase, we find evidence for quantum criticality and delocalization behaviour(9,10) that can quantitatively be described by the renormalization group properties of the QH ground state(11,12). This result demonstrates that this QAH state can be understood within the context of the law of corresponding states that governs the QH state(13,14).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 540, "Times Cited, All Databases": 594, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 731, "End Page": 736, "Article Number": null, "DOI": "10.1038/NPHYS3053", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343225200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Perdew, JP; Yang, WT; Burke, K; Yang, ZH; Gross, EKU; Scheffler, M; Scuseria, GE; Henderson, TM; Zhang, IY; Ruzsinszky, A; Peng, HW; Sun, JW; Trushin, E; Görling, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perdew, John P.; Yang, Weitao; Burke, Kieron; Yang, Zenghui; Gross, Eberhard K. U.; Scheffler, Matthias; Scuseria, Gustavo E.; Henderson, Thomas M.; Zhang, Igor Ying; Ruzsinszky, Adrienn; Peng, Haowei; Sun, Jianwei; Trushin, Egor; Goerling, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding band gaps of solids in generalized Kohn-Sham theory", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fundamental energy gap of a periodic solid distinguishes insulators from metals and characterizes low- energy single-electron excitations. However, the gap in the band structure of the exact multiplicative Kohn-Sham (KS) potential substantially underestimates the fundamental gap, a major limitation of KS densityfunctional theory. Here, we give a simple proof of a theorem: In generalized KS theory (GKS), the band gap of an extended system equals the fundamental gap for the approximate functional if the GKS potential operator is continuous and the density change is delocalized when an electron or hole is added. Our theorem explains how GKS band gaps from metageneralized gradient approximations (meta-GGAs) and hybrid functionals can be more realistic than those from GGAs or even from the exact KS potential. The theorem also follows from earlier work. The band edges in the GKS one-electron spectrum are also related to measurable energies. A linear chain of hydrogen molecules, solid aluminum arsenide, and solid argon provide numerical illustrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2017, "Volume": 114, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2801, "End Page": 2806, "Article Number": null, "DOI": "10.1073/pnas.1621352114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1621352114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396094200028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, MJ; Sun, JM; Laemont, A; Liu, CH; Wang, LY; Bourda, L; Chakraborty, J; Van Hecke, K; Morent, R; De Geyter, N; Leus, K; Chen, H; van der Voort, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Maojun; Sun, Jiamin; Laemont, Andreas; Liu, Chunhui; Wang, Linyang; Bourda, Laurens; Chakraborty, Jeet; Van Hecke, Kristof; Morent, Rino; De Geyter, Nathalie; Leus, Karen; Chen, Hui; van der Voort, Pascal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extending the π-conjugation system of covalent organic frameworks for more efficient photocatalytic H2O2 production", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photocatalytic oxygen reduction reaction (ORR) towards hydrogen peroxide (H2O2) is a promising but challenging alternative to the industrial anthraquinone process. Crystalline porous covalent organic frameworks (COFs), a new generation of semiconductors, have attracted significant attention because they exhibit broad visible-light harvesting, possess tunable energy levels, and facilitate facile separation and migration of photogenerated charge pairs. The modulation of the energy levels of COFs could facilitate charge transport, resulting in better photocatalytic performance. Herein, the pi-conjugation system of COFs was extended via a post-sulfurization process, leading to a considerably enhanced photocatalytic activity. During the sulfurization process, imine-linked COFs were converted into thiazole-linked COFs to extend the conjugation structure of COFs in the x and y directions, resulting in higher transport of electrons. The thiazole-linked 4PE-N-S presents the best photocatalytic H2O2 generation performance with a rate of 1574 mu mol g(-1) h(-1), which is about 5.8 and 3.7 times higher than that of imine-linked 4PE-N and 4PE-TT, respectively. Our findings provide new prospects for the design and synthesis of highly active organic photocatalysts for solar-to-chemical energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2023, "Volume": 25, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3069, "End Page": 3076, "Article Number": null, "DOI": "10.1039/d2gc04459e", "DOI Link": "http://dx.doi.org/10.1039/d2gc04459e", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955677400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Worch, JC; Dove, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Worch, Joshua C.; Dove, Andrew P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "100th Anniversary of Macromolecular Science Viewpoint: Toward Catalytic Chemical Recycling of Waste (and Future) Plastics", "Source Title": "ACS MACRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The current global materials economy has long been inefficient due to unproductive reuse and recycling efforts. Within the wider materials portfolio, plastics have been revolutionary to many industries but they have been treated as disposable commodities leading to their increasing accumulation in the environment as waste. The field of chemistry has had significant bearing in ushering in the current plastics industry and will undoubtedly have a hand in transforming it to become more sustainable. Existing approaches include the development of synthetic biodegradable plastics and turning to renewable raw materials in order to produce plastics similar to our current petrol-based materials or to create new polymers. Additionally, chemists are confronting the environmental crisis by developing alternative recycling methods to deal with the legacy of plastic waste. Important emergent technologies, such as catalytic chemical recycling or upcycling, have the potential to alleviate numerous issues related to our current and future refuse and, in doing so, help pivot our materials economy from linearity to circularity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2020, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1494, "End Page": 1506, "Article Number": null, "DOI": "10.1021/acsmacrolett.0c00582", "DOI Link": "http://dx.doi.org/10.1021/acsmacrolett.0c00582", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592843400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Scragg, JJS; Choubrac, L; Lafond, A; Ericson, T; Platzer-Björkman, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Scragg, Jonathan J. S.; Choubrac, Leo; Lafond, Alain; Ericson, Tove; Platzer-Bjorkman, Charlotte", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A low-temperature order-disorder transition in Cu2ZnSnS4 thin films", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cu2ZnSnS4 (CZTS) is an interesting material for sustainable photovoltaics, but efficiencies are limited by the low open-circuit voltage. A possible cause of this is disorder among the Cu and Zn cations, a phenomenon which is difficult to detect by standard techniques. We show that this issue can be overcome using near-resonullt Raman scattering, which lets us estimate a critical temperature of 533 +/- 10K for the transition between ordered and disordered CZTS. These findings have deep significance for the synthesis of high-quality material, and pave the way for quantitative investigation of the impact of disorder on the performance of CZTS-based solar cells. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2014, "Volume": 104, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41911, "DOI": "10.1063/1.4863685", "DOI Link": "http://dx.doi.org/10.1063/1.4863685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331209900030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LY; Zhang, Y; Li, JP; Fan, MY; Wang, XY; Wu, GC; Yang, ZB; Luan, JH; Jiao, ZB; Liu, CT; Liaw, PK; Zhang, ZW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Liyuan; Zhang, Yang; Li, Junpeng; Fan, Mingyu; Wang, Xiyu; Wu, Guangchuan; Yang, Zhongbo; Luan, Junhua; Jiao, Zengbao; Liu, Chain Tsuan; Liaw, Peter K.; Zhang, Zhongwu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced strength-ductility synergy via novel bifunctional nullo-precipitates in a high-entropy alloy", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys (HEAs) with a single-phased face-centered-cubic structure possess excellent plasticity but generally low strength. Precipitation strengthening is one of the most promising methods to improve the strength of alloys. However, plagued by a nerve-wracking fact that strength-ductility trade-off frequently limits the improvement of alloy properties. To overcome this problem, a new Ni-35(CoFe)(55)V5Nb5 HEA with an excellent strength and ductility synergy was developed by introducing a novel bifunctional L-12-Ni3Nb nullo-precipitate. This HEA exhibits a high yield strength of 855 MPa, ultimate tensile strength of 1,302 MPa and marvelous elongation of ~ 50%. First-principles calculations show that the (Ni24Co18Fe6)(3)(Nb10V4Fe2) nullo-precipitate with a L-12 structure possesses lower formation energy than that with D0(22) structure. The novel nullo-precipitates provide two-fold functions. On the one hand, L-12-(Ni24Co18Fe6)(3)(Nb10V4Fe2) nullo-precipitates have a high anti-phase boundary energy, contributing to a significant increment in the yield strength through precipitation strengthening. More importantly, the precipitation of the precipitates lowers the stacking fault energy (SFE) of the alloy matrix, contributing to the excellent work-hardening ability and large plasticity through activating the continuous formation of SF networks and Lomer-Cottrell locks during deformation. The strategy to introduce the novel bifunctional nullo-precipitates paves a new way to enhance the strength-ductility synergy of alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 153, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103235, "DOI": "10.1016/j.ijplas.2022.103235", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2022.103235", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000793138200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, LR; Zhang, YH; Wu, Z; Tian, J; Wang, HR; Zhao, HJ; Xu, SD; Chen, L; Duan, XC; Zhang, D; Guo, HJ; You, Y; Zhu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Lin-Rong; Zhang, Yu-Han; Wu, Zhen; Tian, Jinlv; Wang, Haorui; Zhao, Haijun; Xu, Shoudong; Chen, Liang; Duan, Xiaochuan; Zhang, Ding; Guo, Huijuan; You, Ya; Zhu, Zhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized O3-Type Layered Sodium Oxides with Enhanced Rate Performance and Cycling Stability by Dual-Site Ti4+/K+ Substitution", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-capacity O-3-type layered sodium oxides are considered one of the most promising cathode materials for the next generation of Na-ion batteries (NIBs). However, these cathodes usually suffer from low high-rate capacity and poor cycling stability due to structure deformation, native air sensitivity, and interfacial side reactions. Herein, a multi-site substituted strategy is employed to enhance the stability of O-3-type nulli0.5Mn0.5O2. Simulations indicate that the Ti substitution decreases the charge density of Ni ions and improves the antioxidative capability of the material. In addition, the synergistic effect of K+ and Ti4+ significantly reduces the formation energy of Na+ vacancy and delivers an ultra-low lattice strain during the repeated Na+ extraction/insertion. In situ characterizations verify that the complicated phase transformation is mitigated during the charge/discharge process, resulting in greatly improved structure stability. The co-substituted cathode delivers a high-rate capacity of 97 mAh g(-1) at 5 C and excellent capacity retention of 81% after 400 cycles at 0.5 C. The full cell paired with commercial hard carbon anode also exhibits high capacity and long cycling life. This dual-ion substitution strategy will provide a universal approach for the new rational design of high-capacity cathode materials for NIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202304067", "DOI Link": "http://dx.doi.org/10.1002/advs.202304067", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001072129200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, L; Liu, HY; Pickard, CJ; Zou, GT; Ma, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Li; Liu, Hanyu; Pickard, Chris J.; Zou, Guangtian; Ma, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reactions of xenon with iron and nickel are predicted in the Earth's inner core", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Studies of the Earth's atmosphere have shown that more than 90% of the expected amount of Xe is depleted, a finding often referred to as the 'missing Xe paradox'. Although several models for a Xe reservoir have been proposed, whether the missing Xe could be contained in the Earth's inner core has not yet been answered. The key to addressing this issue lies in the reactivity of Xe with Fe/Ni, the main constituents of the Earth's core. Here, we predict, through first-principles calculations and unbiased structure searching techniques, a chemical reaction of Xe with Fe/Ni at the temperatures and pressures found in the Earth's core. We find that, under these conditions, Xe and Fe/Ni can form intermetallic compounds, of which XeFe3 and XeNi3 are energetically the most stable. This shows that the Earth's inner core is a natural reservoir for Xe storage and provides a solution to the missing Xe paradox.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 391, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 644, "End Page": 648, "Article Number": null, "DOI": "10.1038/nchem.1925", "DOI Link": "http://dx.doi.org/10.1038/nchem.1925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338444600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ko, YJ; Kim, JY; Lee, WH; Kim, MG; Seong, TY; Park, J; Jeong, Y; Min, BK; Lee, WS; Lee, DK; Oh, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ko, Young-Jin; Kim, Jun-Yong; Lee, Woong Hee; Kim, Min Gyu; Seong, Tae-Yeon; Park, Jongkil; Jeong, YeonJoo; Min, Byoung Koun; Lee, Wook-Seong; Lee, Dong Ki; Oh, Hyung-Suk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring dopant effects in stannic oxide nulloparticles for CO2 electro-reduction to formate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Though stannic oxides can catalyze CO2 electroreduction to formate, the stability of these catalysts has been limited. Here, the authors demonstrate stable fluorine-doped SnO2 materials toward formate production at current densities of >300 mA/cm(2). The electrosynthesis of formate from CO2 can mitigate environmental issues while providing an economically valuable product. Although stannic oxide is a good catalytic material for formate production, a metallic phase is formed under high reduction overpotentials, reducing its activity. Here, using a fluorine-doped tin oxide catalyst, a high Faradaic efficiency for formate (95% at 100 mA cm(-2)) and a maximum partial current density of 330 mA cm(-2) (at 400 mA cm(-2)) is achieved for the electroreduction of CO2. Furthermore, the formate selectivity (approximate to 90%) is nearly constant over 7 days of operation at a current density of 100 mA cm(-2). In-situ/operando spectroscopies reveal that the fluorine dopant plays a critical role in maintaining the high oxidation state of Sn, leading to enhanced durability at high current densities. First-principle calculation also suggests that the fluorine-doped tin oxide surface could provide a thermodynamically stable environment to form HCOO* intermediate than tin oxide surface. These findings suggest a simple and efficient approach for designing active and durable electrocatalysts for the electrosynthesis of formate from CO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2205, "DOI": "10.1038/s41467-022-29783-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29783-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785774400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, DH; Wang, H; Chen, MH; Lin, L; Car, R; E, WN; Jia, WL; Zhang, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Denghui; Wang, Han; Chen, Mohan; Lin, Lin; Car, Roberto; E, Weinull; Jia, Weile; Zhang, Linfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "86 PFLOPS Deep Potential Molecular Dynamics simulation of 100 million atoms with ab initio accuracy", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the GPU version of DeePMD-kit, which, upon training a deep neural network model using ab initio data, can drive extremely large-scale molecular dynamics (MD) simulation with ab initio accuracy. Our tests show that for a water system of 12, 582, 912 atoms, the GPU version can be 7 times faster than the CPU version under the same power consumption. The code can scale up to the entire Summit supercomputer. For a copper system of 113, 246, 208 atoms, the code can perform one nullosecond MD simulation per day, reaching a peak performance of 86 PFLOPS (43% of the peak). Such unprecedented ability to perform MD simulation with ab initio accuracy opens up the possibility of studying many important issues in materials and molecules, such as heterogeneous catalysis, electrochemical cells, irradiation damage, crack propagation, and biochemical reactions. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 259, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107624, "DOI": "10.1016/j.cpc.2020.107624", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2020.107624", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599925900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XS; Lan, LF; Pan, XH; Di, Q; Liu, XK; Li, L; Naumov, P; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xuesong; Lan, Linfeng; Pan, Xiuhong; Di, Qi; Liu, Xiaokong; Li, Liang; Naumov, Pance; Zhang, Hongyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinspired soft robots based on organic polymer-crystal hybrid materials with response to temperature and humidity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capability of stimulated response by mechanical deformation to induce motion or actuation is the foundation of lightweight organic, dynamic materials for designing light and soft robots. Various biomimetic soft robots are constructed to demonstrate the vast versatility of responses and flexibility in shape-shifting. We now report that the integration of organic molecular crystals and polymers brings about synergistic improvement in the performance of both materials as a hybrid materials class, with the polymers adding hygroresponsive and thermally responsive functionalities to the crystals. The resulting hybrid dynamic elements respond within milliseconds, which represents several orders of magnitude of improvement in the time response relative to some other type of common actuators. Combining molecular crystals with polymers brings crystals as largely overlooked materials much closer to specific applications in soft (micro)robotics and related fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2287, "DOI": "10.1038/s41467-023-37964-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37964-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, JW; Ma, Q; Lan, ZH; Xiao, Q; Panoiu, NC; Cui, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Jian Wei; Ma, Qian; Lan, Zhihao; Xiao, Qiang; Panoiu, Nicolae C.; Cui, Tie Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reprogrammable plasmonic topological insulators with ultrafast control", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological photonics has revolutionized our understanding of light propagation, providing a robust way to manipulate light. So far, most of studies in this field are focused on designing a static photonic structure. Developing a dynamic photonic topological platform to switch multiple topological functionalities at ultrafast speed is still a great challenge. Here we theoretically propose and experimentally demonstrate a reprogrammable plasmonic topological insulator, where the topological propagation route can be dynamically changed at nullosecond-level switching time, leading to an experimental demonstration of ultrafast multi-channel optical analog-digital converter. Due to the innovative use of electric switches to implement the programmability of plasmonic topological insulator, each unit cell can be encoded by dynamically controlling its digital plasmonic states while keeping its geometry and material parameters unchanged. Our reprogrammable topological plasmonic platform is fabricated by the printed circuit board technology, making it much more compatible with integrated photoelectric systems. Furthermore, due to its flexible programmability, many photonic topological functionalities can be integrated into this versatile topological platform. The development of fast and dynamic topological photonic platforms is an ongoing challenge. Here, the authors demonstrate a reprogrammable plasmonic topological insulator in which ultrafast electric switches allow for nullosecond-level switching time between different configurations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5468, "DOI": "10.1038/s41467-021-25835-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25835-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000697264200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CY; Chen, X; Low, J; Yang, YW; Li, H; Wu, D; Chen, SM; Jin, JB; Li, H; Ju, HX; Wang, CH; Lu, Z; Long, R; Song, L; Xiong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Canyu; Chen, Xing; Low, Jingxiang; Yang, Yaw-Wen; Li, Hao; Wu, Di; Chen, Shuangming; Jin, Jianbo; Li, He; Ju, Huanxin; Wang, Chia-Hsin; Lu, Zhou; Long, Ran; Song, Li; Xiong, Yujie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-infrared-featured broadband CO2 reduction with water to hydrocarbons by surface plasmon", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Imitating the natural photosynthesis to synthesize hydrocarbon fuels represents a viable strategy for solar-to-chemical energy conversion, where utilizing low-energy photons, especially near-infrared photons, has been the ultimate yet challenging aim to further improving conversion efficiency. Plasmonic metals have proven their ability in absorbing low-energy photons, however, it remains an obstacle in effectively coupling this energy into reactant molecules. Here we report the broadband plasmon-induced CO2 reduction reaction with water, which achieves a CH4 production rate of 0.55 mmol g(-1) h(-1) with 100% selectivity to hydrocarbon products under 400 mW cm(-2) full-spectrum light illumination and an apparent quantum efficiency of 0.38% at 800 nm illumination. We find that the enhanced local electric field plays an irreplaceable role in efficient multiphoton absorption and selective energy transfer for such an excellent light-driven catalytic performance. This work paves the way to the technique for low-energy photon utilization. Changes in Polycomb repression during interphase transition modulate the ability of pluripotent cells to enter cell differentiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 221, "DOI": "10.1038/s41467-023-35860-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35860-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953250500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, CY; Zhang, BY; Hao, L; Min, JK; Liu, N; Niu, R; Gong, J; Tang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Changyuan; Zhang, Boyi; Hao, Liang; Min, Jiakang; Liu, Ning; Niu, Ran; Gong, Jiang; Tang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Converting poly(ethylene terephthalate) waste into N-doped porous carbon as CO2 adsorbent and solar steam generator", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable conversion of waste plastics into valuable carbon materials for diverse applications provides a promising strategy to dispose the municipal and industrial waste plastics. However, it remains a challenge to precisely control the crosslinking reaction for transforming waste polyesters into N-doped porous carbon (NPC) with well-defined microstructures. Herein, we put forwards a strategy of stepwise crosslinking using melamine and ZnCl2/NaCl eutectic salts to convert poly (ethylene terephthalate) (PET) into NPC at 550 degrees C. We prove that firstly melamine reacts with PET degradation products to form a crosslinking structure, and subsequently ZnCl2/NaCl promote the dehydration and decarboxylation of the crosslinking structure to generate a more thermally stable crosslinking structure. The coordination of two tandem crosslinking reactions is critical to control the microstructure of NPC. Without activations, NPC shows large specific surface area of 1173 m(2) g(-1), abundant N dopants, and rich oxygen-containing groups. These combined features endure NPC with excellent performance in CO2 capture and solar steam generation, e.g., high CO2 adsorption capacity of 6.47 mmol g(-1) and evaporation rate of 1.62 kg m(-2 )h(-1). More importantly, NPC is compared to or prevails over previous carbon-based CO2 adsorbents or photothermal materials. This work will advance the research on green reutilization of low-cost polyester wastes to prepare sustainable carbon for solar energy conversion, environmental protection, etc. (C) 2020 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 411, "End Page": 422, "Article Number": null, "DOI": "10.1016/j.gee.2020.10.002", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2020.10.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780126100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YP; Zhang, JH; Liu, Y; Qian, QZ; Li, ZY; Zhu, Y; Zhang, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yapeng; Zhang, Jihua; Liu, Yi; Qian, Qizhu; Li, Ziyun; Zhu, Yin; Zhang, Genqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Partially exposed RuP2 surface in hybrid structure endows its bifunctionality for hydrazine oxidation and hydrogen evolution catalysis", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Replacing the sluggish anode reaction in water electrolysis with thermodynamically favorable hydrazine oxidation could achieve energy-efficient H-2 production, while the shortage of bifunctional catalysts limits its scale development. Here, we presented the scalable one-pot synthesis of partially exposed RuP2 nulloparticle-decorated carbon porous microsheets, which can act as the superior bifunctional catalyst outperforming Pt/C for both hydrazine oxidation reaction and hydrogen evolution reaction, where an ultralow working potential of -70 mV and an ultrasmall overpotential of 24 mV for 10 mA cm(-2) can be achieved. The two-electrode electrolyzer can reach 10 mA cm(-2) with a record-low cell voltage of 23 mV and an ultrahigh current density of 522 mA cm(-2) at 1.0 V. The DFT calculations unravel the notability of partial exposure in the hybrid structure, as the exposed Ru atoms are the active sites for hydrazine dehydrogenation, while the C atoms exhibit a more thermoneutral value for H* adsorption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 6, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb4197", "DOI": "10.1126/sciadv.abb4197", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb4197", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000583031400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, M; Fernulldo, JFS; Li, ZB; Alowasheeir, A; Ashok, A; Xin, RJ; Martin, D; nulljundan, AK; Golberg, DV; Yamauchi, Y; Amiralian, N; Li, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Minjun; Fernulldo, Joseph F. S.; Li, Zhibin; Alowasheeir, Azhar; Ashok, Aditya; Xin, Ruijing; Martin, Darren; nulljundan, Ashok Kumar; V. Golberg, Dmitri; Yamauchi, Yusuke; Amiralian, Nasim; Li, Jinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-stable sodium ion storage of biomass porous carbon derived from sugarcane", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of low-cost anode for sodium-ion battery (NIB) has become the most desirable target in today's energy demanding society. In this work, we present different treatments of sugarcane biomass to alter the lignocellulose compositions to obtain low-cost porous carbon as NIB's anode. The optimized sugarcane biomass derived carbon presents the initial reversible capacity of 229 mAh g-1 and the reversible capacity of 189 mAh g-1 at 100 mA g-1 after 50 cycles. It is worth noting that the carbon also exhibits an extremely low voltage plateau with 74.2 % of discharge capacity originating from the voltages below 0.5 V. In addition, the sugarcane biomass derived carbon displays an ultra-stable capacity with almost no attenuation even after 2000 cycles. In consideration of the low voltage plateau, we also calculated the relative energy density (ER, combination of the capacity and voltage plateau), and a high ER of 500 Wh kg-1 in the first cycle and 416 Wh kg-1 after 50 cycles are obtained. In situ TEM analysis was conducted to investigate the structural stability of sugarcane biomass derived carbon. Small volumetric changes are observed at different charge-discharge states, indicating the structural stability of our sugarcane biomass derived carbon during sodiation-desodiation process, which is conducive to the stable cycling of Na-ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2022, "Volume": 445, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136344, "DOI": "10.1016/j.cej.2022.136344", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.136344", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000818432800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, W; Shi, Y; Chen, Z; Fan, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wei; Shi, Yu; Chen, Zhen; Fan, Shanhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonic thermal management of coloured objects", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The colours of outdoor structures, such as automobiles, buildings and clothing, are typically chosen for functional or aesthetic reasons. With a chosen colour, however, one must control the radiative thermal load for heating or cooling purposes. Here we provide a comprehensive calculation of the tunable range of radiative thermal load for all colours. The range exceeds 680 Wm(-2) for all colours, and can be as high as 866 Wm(-2), resulting from effects of metamerism, infrared solar absorption and radiative cooling. We experimentally demonstrate that two photonic structures with the same pink colour can have their temperatures differ by 47.6 degrees C under sunlight. These structures are over 20 degrees C either cooler or hotter than a commercial paint with a comparable colour. Furthermore, the hotter pink structure is 10 degrees C hotter than a commercial black paint. These results elucidate the fundamental potentials of photonic thermal management for coloured objects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4240, "DOI": "10.1038/s41467-018-06535-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06535-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447123000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ganose, AM; Savory, CN; Scanlon, DO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ganose, Alex M.; Savory, Christopher N.; Scanlon, David O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beyond methylammonium lead iodide: prospects for the emergent field of ns2 containing solar absorbers", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of photovoltaics is undergoing a surge of interest following the recent discovery of the lead hybrid perovskites as a remarkably efficient class of solar absorber. Of these, methylammonium lead iodide (MAPI) has garnered significant attention due to its record breaking efficiencies, however, there are growing concerns surrounding its long-term stability. Many of the excellent properties seen in hybrid perovskites are thought to derive from the 6s(2) electronic configuration of lead, a configuration seen in a range of post-transition metal compounds. In this review we look beyond MAPI to other ns(2) solar absorbers, with the aim of identifying those materials likely to achieve high efficiencies. The ideal properties essential to produce highly efficient solar cells are discussed and used as a framework to assess the broad range of compounds this field encompasses. Bringing together the lessons learned from this wide-ranging collection of materials will be essential as attention turns toward producing the next generation of solar absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 53, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 20, "End Page": 44, "Article Number": null, "DOI": "10.1039/c6cc06475b", "DOI Link": "http://dx.doi.org/10.1039/c6cc06475b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391607100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, JN; Han, GK; Zhang, W; Li, LF; Yan, YQ; Shi, YX; Zhang, X; Geng, L; Wang, ZJ; Xiong, YP; Yin, GP; Du, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Jiannull; Han, Guokang; Zhang, Wei; Li, Lingfeng; Yan, Yuqi; Shi, Yaoxuan; Zhang, Xue; Geng, Lin; Wang, Zhijiang; Xiong, Yueping; Yin, Geping; Du, Chunyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CoIn dual-atom catalyst for hydrogen peroxide production via oxygen reduction reaction in acid", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The two-electron oxygen reduction reaction in acid is highly attractive to produce H2O2, a commodity chemical vital in various industry and household scenarios, which is still hindered by the sluggish reaction kinetics. Herein, both density function theory calculation and in-situ characterization demonstrate that in dual-atom CoIn catalyst, O-affinitive In atom triggers the favorable and stable adsorption of hydroxyl, which effectively optimizes the adsorption of OOH on neighboring Co. As a result, the oxygen reduction on Co atoms shifts to two-electron pathway for efficient H2O2 production in acid. The H2O2 partial current density reaches 1.92 mA cm(-2) at 0.65 V in the rotating ring-disk electrode test, while the H2O2 production rate is as high as 9.68 mol g(-1) h(-1) in the three-phase flow cell. Additionally, the CoIn-N-C presents excellent stability during the long-term operation, verifying the practicability of the CoIn-N-C catalyst. This work provides inspiring insights into the rational design of active catalysts for H2O2 production and other catalytic systems. The 2-electron oxygen reduction in acid is highly attractive to produce H2O2, a vital commodity chemical. Here, the authors report CoIn-N-C dual-atom catalyst for effective H(2)O2 production in acid, and show in-situ hydroxyl adsorption on In atoms is important for the selectivity alteration on nearby Co atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-40467-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40467-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001048553800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cubuk, ED; Schoenholz, SS; Rieser, JM; Malone, BD; Rottler, J; Durian, DJ; Kaxiras, E; Liu, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cubuk, E. D.; Schoenholz, S. S.; Rieser, J. M.; Malone, B. D.; Rottler, J.; Durian, D. J.; Kaxiras, E.; Liu, A. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identifying Structural Flow Defects in Disordered Solids Using Machine-Learning Methods", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use machine-learning methods on local structure to identify flow defects-or particles susceptible to rearrangement-in jammed and glassy systems. We apply this method successfully to two very different systems: a two-dimensional experimental realization of a granular pillar under compression and a Lennard-Jones glass in both two and three dimensions above and below its glass transition temperature. We also identify characteristics of flow defects that differentiate them from the rest of the sample. Our results show it is possible to discern subtle structural features responsible for heterogeneous dynamics observed across a broad range of disordered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 387, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2015, "Volume": 114, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108001, "DOI": "10.1103/PhysRevLett.114.108001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.108001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350624500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lim, CYJ; Yilmaz, M; Arce-Ramos, JM; Handoko, AD; Teh, WJ; Zheng, YG; Khoo, ZHJ; Lin, M; Isaacs, M; Tam, TLD; Bai, Y; Ng, CK; Yeo, BS; Sankar, G; Parkin, IP; Hippalgaonkar, K; Sullivan, MB; Zhang, J; Lim, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lim, Carina Yi Jing; Yilmaz, Meltem; Arce-Ramos, Juan Manuel; Handoko, Albertus D.; Teh, Wei Jie; Zheng, Yuangang; Khoo, Zi Hui Jonathan; Lin, Ming; Isaacs, Mark; Tam, Teck Lip Dexter; Bai, Yang; Ng, Chee Koon; Yeo, Boon Siang; Sankar, Gopinathan; Parkin, Ivan P.; Hippalgaonkar, Kedar; Sullivan, Michael B.; Zhang, Jia; Lim, Yee-Fun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface charge as activity descriptors for electrochemical CO2 reduction to multi-carbon products on organic-functionalised Cu", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intensive research in electrochemical CO2 reduction reaction has resulted in the discovery of numerous high-performance catalysts selective to multi-carbon products, with most of these catalysts still being purely transition metal based. Herein, we present high and stable multi-carbon products selectivity of up to 76.6% across a wide potential range of 1 V on histidine-functionalised Cu. In-situ Raman and density functional theory calculations revealed alternative reaction pathways that involve direct interactions between adsorbed histidine and CO2 reduction intermediates at more cathodic potentials. Strikingly, we found that the yield of multi-carbon products is closely correlated to the surface charge on the catalyst surface, quantified by a pulsed voltammetry-based technique which proved reliable even at very cathodic potentials. We ascribe the surface charge to the population density of adsorbed species on the catalyst surface, which may be exploited as a powerful tool to explain CO2 reduction activity and as a proxy for future catalyst discovery, including organic-inorganic hybrids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 335, "DOI": "10.1038/s41467-023-35912-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35912-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001164830900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, WK; Yang, NT; Li, XP; Linnemann, J; Hagemann, U; Ruediger, O; Heidelmann, M; Falk, T; Aramini, M; DeBeer, S; Muhler, M; Tschulik, K; Li, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Weikai; Yang, Nating; Li, Xiaopeng; Linnemann, Julia; Hagemann, Ulrich; Ruediger, Olaf; Heidelmann, Markus; Falk, Tobias; Aramini, Matteo; DeBeer, Serena; Muhler, Martin; Tschulik, Kristina; Li, Tong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D atomic-scale imaging of mixed Co-Fe spinel oxide nulloparticles during oxygen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The three-dimensional (3D) distribution of individual atoms on the surface of catalyst nulloparticles plays a vital role in their activity and stability. Optimising the performance of electrocatalysts requires atomic-scale information, but it is difficult to obtain. Here, we use atom probe tomography to elucidate the 3D structure of 10 nm sized Co2FeO4 and CoFe2O4 nulloparticles during oxygen evolution reaction (OER). We reveal nulloscale spinodal decomposition in pristine Co2FeO4. The interfaces of Co-rich and Fe-rich nullodomains of Co2FeO4 become trapping sites for hydroxyl groups, contributing to a higher OER activity compared to that of CoFe2O4. However, the activity of Co2FeO4 drops considerably due to concurrent irreversible transformation towards CoIVO2 and pronounced Fe dissolution. In contrast, there is negligible elemental redistribution for CoFe2O4 after OER, except for surface structural transformation towards (FeIII, CoIII)(2)O-3. Overall, our study provides a unique 3D compositional distribution of mixed Co-Fe spinel oxides, which gives atomic-scale insights into active sites and the deactivation of electrocatalysts during OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 179, "DOI": "10.1038/s41467-021-27788-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27788-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001187356000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grantham, NJ; Wurman-Rodrich, J; Terrett, OM; Lyczakowski, JJ; Stott, K; Iuga, D; Simmons, TJ; Durand-Tardif, M; Brown, SP; Dupree, R; Busse-Wicher, M; Dupree, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grantham, Nicholas J.; Wurman-Rodrich, Joel; Terrett, Oliver M.; Lyczakowski, Jan J.; Stott, Katherine; Iuga, Dinu; Simmons, Thomas J.; Durand-Tardif, Mylene; Brown, Steven. P.; Dupree, Ray; Busse-Wicher, Marta; Dupree, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An even pattern of xylan substitution is critical for interaction with cellulose in plant cell walls", "Source Title": "NATURE PLANTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Xylan and cellulose are abundant polysaccharides in vascular plants and essential for secondary cell wall strength. Acetate or glucuronic acid decorations are exclusively found on even-numbered residues in most of the glucuronoxylan polymer. It has been proposed that this even-specific positioning of the decorations might permit docking of xylan onto the hydrophilic face of a cellulose microfibril(1-3). Consequently, xylan adopts a flattened ribbon-like twofold screw conformation when bound to cellulose in the cell wall(4). Here we show that ESKIMO1/XOAT1/TBL29, a xylan-specific O-acetyltransferase, is necessary for generation of the even pattern of acetyl esters on xylan in Arabidopsis. The reduced acetylation in the esk1 mutant deregulates the position-specific activity of the xylan glucuronosyltransferase GUX1, and so the even pattern of glucuronic acid on the xylan is lost. Solid-state NMR of intact cell walls shows that, without the even-patterned xylan decorations, xylan does not interact normally with cellulose fibrils. We conclude that the even pattern of xylan substitutions seen across vascular plants enables the interaction of xylan with hydrophilic faces of cellulose fibrils, and is essential for development of normal plant secondary cell walls.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 3, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 859, "End Page": 865, "Article Number": null, "DOI": "10.1038/s41477-017-0030-8", "DOI Link": "http://dx.doi.org/10.1038/s41477-017-0030-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Plant Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414512800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CM; Wang, RY; Mishra, H; Liu, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chenmu; Wang, Ruoyu; Mishra, Himani; Liu, Yuanyue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Semiconductors with High Intrinsic Carrier Mobility at Room Temperature", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional semiconductors have demonstrated great potential for next-generation electronics and optoelectronics, however, the current 2D semiconductors suffer from intrinsically low carrier mobility at room temperature, which significantly limits their applications. Here we discover a variety of new 2D semiconductors with mobility 1 order of magnitude higher than the current ones and even higher than bulk silicon. The discovery was made by developing effective descriptors for computational screening of the 2D materials database, followed by high-throughput accurate calculation of the mobility using a state-of-the-art first-principles method that includes quadrupole scattering. The exceptional mobilities are explained by several basic physical features; particularly, we find a new feature: carrier-lattice distance, which is easy to calculate and correlates well with mobility. Our Letter opens up new materials for high performance device performance and/or exotic physics, and improves the understanding of the carrier transport mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2023, "Volume": 130, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 87001, "DOI": "10.1103/PhysRevLett.130.087001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.130.087001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936535100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boley, CD; Khairallah, SA; Rubenchik, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boley, C. D.; Khairallah, S. A.; Rubenchik, A. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Calculation of laser absorption by metal powders in additive manufacturing", "Source Title": "APPLIED OPTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have calculated the absorption of laser light by a powder of metal spheres, typical of the powder employed in laser powder-bed fusion additive manufacturing. Using ray-trace simulations, we show that the absorption is significantly larger than its value for normal incidence on a flat surface, due to multiple scattering. We investigate the dependence of absorption on powder content (material, size distribution, and geometry) and on beam size. (c) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 260, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2015, "Volume": 54, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2477, "End Page": 2482, "Article Number": null, "DOI": "10.1364/AO.54.002477", "DOI Link": "http://dx.doi.org/10.1364/AO.54.002477", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351638300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JJ; Liu, ZX; Han, SH; Zhou, P; Lu, BA; Zhou, JD; Zeng, ZY; Chen, ZZ; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jingjing; Liu, Zhexuan; Han, Shaohua; Zhou, Peng; Lu, Bingan; Zhou, Jianda; Zeng, Zhiyuan; Chen, Zhizhao; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hetero Nucleus Growth Stabilizing Zinc Anode for High-Biosecurity Zinc-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Animal models are applied to evaluate the biosecurity and biocompatibility of the zinc-ion batteries with the electrolytes of different zinc salts.Leakage scene simulations and histological analysis are employed in investigating the tissue response after battery implantations, in which ZnSO4 exhibits higher biosecurity.Sn hetero nucleus is introduced to stabilize the zinc anode, which not only facilitates the planar zinc deposition, but also contributes to higher hydrogen evolution overpotential. Biocompatible devices are widely employed in modernized lives and medical fields in the forms of wearable and implantable devices, raising higher requirements on the battery biocompatibility, high safety, low cost, and excellent electrochemical performance, which become the evaluation criteria toward developing feasible biocompatible batteries. Herein, through conducting the battery implantation tests and leakage scene simulations on New Zealand rabbits, zinc sulfate electrolyte is proved to exhibit higher biosecurity and turns out to be one of the ideal zinc salts for biocompatible zinc-ion batteries (ZIBs). Furthermore, in order to mitigate the notorious dendrite growth and hydrogen evolution in mildly acidic electrolyte as well as improve their operating stability, Sn hetero nucleus is introduced to stabilize the zinc anode, which not only facilitates the planar zinc deposition, but also contributes to higher hydrogen evolution overpotential. Finally, a long lifetime of 1500 h for the symmetrical cell, the specific capacity of 150 mAh g-1 under 0.5 A g-1 for the Zn-MnO2 battery and 212 mAh g-1 under 5 A g-1 for the Zn-NH4V4O10 battery are obtained. This work may provide unique perspectives on biocompatible ZIBs toward the biosecurity of their cell components.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 237, "DOI": "10.1007/s40820-023-01206-2", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01206-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001090531900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathew, K; Kolluru, VSC; Mula, S; Steinmann, SN; Hennig, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathew, Kiran; Kolluru, V. S. Chaitanya; Mula, Srinidhi; Steinmann, Stephan N.; Hennig, Richard G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Implicit self-consistent electrolyte model in plane-wave density-functional theory", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ab initio computational treatment of electrochemical systems requires an appropriate treatment of the solid/liquid interfaces. A fully quantum mechanical treatment of the interface is computationally demanding due to the large number of degrees of freedom involved. In this work, we develop a computationally efficient model where the electrode part of the interface is described at the density-functional theory (DFT) level, and the electrolyte part is represented through an implicit solvation model based on the Poisson-Boltzmann equation. We describe the implementation of the linearized Poisson-Boltzmann equation into the Vienna Ab initio Simulation Package, a widely used DFT code, followed by validation and benchmarking of the method. To demonstrate the utility of the implicit electrolyte model, we apply it to study the surface energy of Cu crystal facets in an aqueous electrolyte as a function of applied electric potential. We show that the applied potential enables the control of the shape of nullocrystals from an octahedral to a truncated octahedral morphology with increasing potential. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 829, "Times Cited, All Databases": 865, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2019, "Volume": 151, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 234101, "DOI": "10.1063/1.5132354", "DOI Link": "http://dx.doi.org/10.1063/1.5132354", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513157600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, TT; Guo, YY; Xie, YX; Zhao, LB; Wang, T; Meng, AL; Li, ZJ; Zhang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Tingting; Guo, Yuying; Xie, Yuxin; Zhao, Laibin; Wang, Ting; Meng, Alan; Li, Zhenjiang; Zhang, Meng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Customizing the structure and chemical composition of ultralight carbon foams for superior microwave absorption performance", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing biomass-derived three-dimensional porous carbon materials (porous carbon foam, PCF) has become a common strategy to obtain lightweight and efficient electromagnetic microwave-absorbing materials. Without the introduction of a template and subsequent activation process, several ultra-lightweight honeycomb PCF samples were successfully prepared from dried ballonflower/yamakurage (DB) by simple calcination. In addi-tion, the calcination temperature plays a decisive role in regulating the pore size, composition and microwave absorption properties of PCF samples. Furthermore, it is worth noting that different cutting directions also influenced the hole size of the PCF sample and the microwave absorption performances. Under the combined effects of multiple reflections and scattering of PCF porous structure, dipole polarization of abundant hetero-geneous atoms and good conductive loss of carbon material, the vertical cutting sample PCF-900V exhibits optimal microwave absorption performances with the minimal reflection loss (RLmin) value of-46.95 dB at 1.46 mm thickness and the effective absorption bandwidth (EAB) value of 5.52 GHz at 1.72 mm matching thickness respectively, indicating its great potential for application as a promising lightweight and efficient microwave absorbing material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2023, "Volume": 206, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 181, "End Page": 191, "Article Number": null, "DOI": "10.1016/j.carbon.2023.02.052", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.02.052", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965564000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, SL; Ma, S; Zhang, YH; Yuan, J; Yang, HT; Lu, ZYW; Wang, NN; Sun, JP; Zhao, Z; Li, D; Liu, SB; Zhang, H; Chen, H; Jin, K; Cheng, JG; Yu, L; Zhou, F; Dong, XL; Hu, JP; Gao, HJ; Zhao, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Shunli; Ma, Sheng; Zhang, Yuhang; Yuan, Jie; Yang, Haitao; Lu, Zouyouwei; Wang, Ningning; Sun, Jianping; Zhao, Zhen; Li, Dong; Liu, Shaobo; Zhang, Hua; Chen, Hui; Jin, Kui; Cheng, Jinguang; Yu, Li; Zhou, Fang; Dong, Xiaoli; Hu, Jiangping; Gao, Hong-Jun; Zhao, Zhongxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic Superconducting Properties of Kagome Metal CsV3Sb5", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We systematically measure the superconducting (SC) and mixed state properties of high-quality CsV3Sb5 single crystals with T-c similar to 3.5 K. We find that the upper critical field H-c2(T) exhibits a large anisotropic ratio of H-c2(ab)/H-c2(c)similar to 9 at zero temperature and fitting its temperature dependence requires a minimum two-band effective model. Moreover, the ratio of the lower critical field, H-c1(ab)/H-c1(c), is also found to be larger than 1, which indicates that the in-plane energy dispersion is strongly renormalized near Fermi energy. Both H-c1(T) and SC diamagnetic signal are found to change little initially below T-c similar to 3.5 K and then to increase abruptly upon cooling to a characteristic temperature of similar to 2.8 K. Furthermore, we identify a two-fold anisotropy of in-plane angular-dependent magnetoresistance in the mixed state. Interestingly, we find that, below the same characteristic T similar to 2.8 K, the orientation of this two-fold anisotropy displays a peculiar twist by an angle of 60 degrees characteristic of the Kagome geometry. Our results suggest an intriguing superconducting state emerging in the complex environment of Kagome lattice, which, at least, is partially driven by electron-electron correlation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 38, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57403, "DOI": "10.1088/0256-307X/38/5/057403", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/38/5/057403", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657486700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Selig, M; Berghäuser, G; Raja, A; Nagler, P; Schüller, C; Heinz, TF; Korn, T; Chernikov, A; Malic, E; Knorr, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Selig, Malte; Berghaeuser, Gunnar; Raja, Archana; Nagler, Philipp; Schueller, Christian; Heinz, Tony F.; Korn, Tobias; Chernikov, Alexey; Malic, Ermin; Knorr, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitonic linewidth and coherence lifetime in monolayer transition metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomically thin transition metal dichalcogenides are direct-gap semiconductors with strong light-matter and Coulomb interactions. The latter accounts for tightly bound excitons, which dominate their optical properties. Besides the optically accessible bright excitons, these systems exhibit a variety of dark excitonic states. They are not visible in the optical spectra, but can strongly influence the coherence lifetime and the linewidth of the emission from bright exciton states. Here, we investigate the microscopic origin of the excitonic coherence lifetime in two representative materials (WS2 and MoSe2) through a study combining microscopic theory with spectroscopic measurements. We show that the excitonic coherence lifetime is determined by phonon-induced intravalley scattering and intervalley scattering into dark excitonic states. In particular, in WS2, we identify exciton relaxation processes involving phonon emission into lower-lying dark states that are operative at all temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 453, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13279, "DOI": "10.1038/ncomms13279", "DOI Link": "http://dx.doi.org/10.1038/ncomms13279", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387000000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; Li, H; Zeng, XH; Xi, SB; Wang, R; Zhang, LH; Liang, GM; Davey, K; Liu, YP; Zhang, L; Zhang, SL; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chaofeng; Li, Hao; Zeng, Xiaohui; Xi, Shibo; Wang, Rui; Zhang, Longhai; Liang, Gemeng; Davey, Kenneth; Liu, Yuping; Zhang, Lin; Zhang, Shilin; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Diffusion Kinetics in ZnTe/CoTe2 Heterojunctions for High Rate Potassium Storage", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries hold practical potential for large-scale energy storage owing to their appealing cell voltage and cost-effective features. The development of anode materials with high rate capability and satisfactory cycle lifespan, however, is one of the key elements for exploiting this electrochemical energy storage system at practical levels. Here, a template-assisted strategy is reported for acquiring a bimetallic telluride heterostructure which is supported on N-doped carbon shell (ZnTe/CoTe2@NC) that promotes diffusion of K+ ions for rapid charge transfer. It is shown that in telluride heterojunctions, electron-rich Te sites and built-in electric fields contributed by electron transfer from ZnTe to CoTe2 concomitantly provide abundant cation adsorption sites and facilitate interfacial electron transport during potassiation/depotassiation. The relatively fine ZnTe/CoTe2 nulloparticles imparted by the heterojunction result in high structural stability, together with a highly reversible capacity up to 5000 cycles at 5 A g(-1). Moreover, using judiciously combined experiment and theoretical computation, it is demonstrated that the energy barrier for K+ diffusion in telluride heterojunctions is significantly lower than that in individual counterparts. This quantitative design for fast and durable charge transfer in telluride heterostructures can be of immediate benefit for the rational design of batteries for low-cost energy storage and conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 12, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202577, "DOI": "10.1002/aenm.202202577", "DOI Link": "http://dx.doi.org/10.1002/aenm.202202577", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849749400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, ZJ; Cui, ZW; Shi, XY; Wang, LY; Dou, YJ; Wang, FF; Lin, HR; Yan, H; Chen, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Zhijun; Cui, Zewei; Shi, Xiaoyu; Wang, Lingyuan; Dou, Yunjie; Wang, Feifei; Lin, Haoran; Yan, He; Chen, Shangshang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(carbazole phosphonic acid) as a versatile hole-transporting material for p-i-n perovskite solar cells and modules", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Commonly used poly(triaryl amine) and carbazole phosphonic acid (PACz) hole-transporting materials (HTMs) typically suffer from poor wettability for perovskite solutions and sensitiveness to layer thick-ness/substrate roughness, respectively, thus limiting their applications in the real-world manufacturing of perovskite modules. To address these issues, in this work, we report a new type of HTM by polymerizing PACz into a versatile polymeric material. The resultant polymeric HTM (named Poly-4PACz) exhibits excellent hole-extraction capacity and can further suppress the interfacial recombination and stabilize perov-skite/HTM interfaces. Most importantly, Poly-4PACz exhibits high conductance and is insensitive to layer thickness on both indium-doped tin oxide and fluorine-doped tin oxide substrates, which are highly desirable for the scalable coating of perovskite films. As a result, the blade-coated p-i-n perovskite solar cells and modules realize impres-sive power conversion efficiencies of 24.4% and 20.7% at 6.84 mm2 and 25.0 cm2 aperture areas, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2023, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.joule.2023.10.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.10.014", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142769500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, SY; Kong, LY; Cao, L; Chen, H; Papaj, M; Du, SX; Xing, YQ; Liu, WY; Wang, DF; Shen, CM; Yang, FZ; Schneeloch, J; Zhong, RD; Gu, GD; Fu, L; Zhang, YY; Ding, H; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Shiyu; Kong, Lingyuan; Cao, Lu; Chen, Hui; Papaj, Michal; Du, Shixuan; Xing, Yuqing; Liu, Wenyao; Wang, Dongfei; Shen, Chengmin; Yang, Fazhi; Schneeloch, John; Zhong, Ruidan; Gu, Genda; Fu, Liang; Zhang, Yu-Yang; Ding, Hong; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nearly quantized conductance plateau of vortex zero mode in an iron-based superconductor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Majorana zero modes (MZMs) are spatially localized, zero-energy fractional quasiparticles with non-Abelian braiding statistics that hold promise for topological quantum computing. Owing to the particle-antiparticle equivalence, MZMs exhibit quantized conductance at low temperature. By using variable-tunnel-coupled scanning tunneling spectroscopy, we studied tunneling conductance of vortex bound states on FeTe0.55Se0.45 superconductors. We report observations of conductance plateaus as a function of tunnel coupling for zero-energy vortex bound states with values close to or even reaching the 2e(2)/h quantum conductance (where e is the electron charge and h is Planck's constant). By contrast, no plateaus were observed on either finite energy vortex bound states or in the continuum of electronic states outside the superconducting gap. This behavior of the zero-mode conductance supports the existence of MZMs in FeTe0.55Se0.45.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 367, "Issue": 6474, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 189, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax0274", "DOI Link": "http://dx.doi.org/10.1126/science.aax0274", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506811300039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sandberg, D; Kutnar, A; Mantanis, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sandberg, Dick; Kutnar, Andreja; Mantanis, George", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wood modification technologies - a review", "Source Title": "IFOREST-BIOGEOSCIENCES AND FORESTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The market for new durable products of modified wood has increased substantially during the last few years, especially in Europe. This increased interest depends partly on the restricted use of toxic preservatives due to increased environmental concern, as well as the need for reduced maintenullce for wood products that are mainly for exterior use. Furthermore, as sustainability becomes a greater concern, the environmental impact of construction and interior materials should be included in planning by considering the entire life cycle and embodied energy of the materials used. As a result, wood modification has been implemented to improve the intrinsic properties of wood, widen the range of sawn timber applications, and acquire the form and functionality desired by engineers, without bringing environmental friendliness into question. The different wood modification processes are at various stages of development, and the challenges that must be overcome to expand to industrial applications differ amongst them. In this paper, three groups of wood modification processes are discussed and exemplified with modified wood products that have been newly introduced to the market: (i) chemical processing (acetylation, furfurylation, resin impregnation etc.); (ii) thermo-hydro processing (thermal treatment); and (iii) thermo-hydro-mechanical processing (surface densification). Building on these examples, the paper will discuss the environmental impact assessment of modification processes and further development needs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 895, "End Page": 908, "Article Number": null, "DOI": "10.3832/ifor2380-010", "DOI Link": "http://dx.doi.org/10.3832/ifor2380-010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Forestry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417157100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Phan, HT; Haes, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Phan, Hoa T.; Haes, Amanda J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "What Does nulloparticle Stability Mean?", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The term nulloparticle stability is widely used to describe the preservation of a particular nullostructure property ranging from aggregation, composition, crystallinity, shape, size, and surface chemistry. As a result, this catch-all term has various meanings, which depend on the specific nulloparticle property of interest and/or application. In this Feature Article, we provide an answer to the question, What does nulloparticle stability mean?. Broadly speaking, the definition of nulloparticle stability depends on the targeted size-dependent property that is exploited and can only exist for a finite period of time given all nullostructures are inherently thermodynamically and energetically unfavorable relative to bulk states. To answer this question specifically, however, the relationship between nulloparticle stability and the physical/chemical properties of metal/metal oxide nulloparticles is discussed. Specific definitions are explored in terms of aggregation state, core composition, shape, size, and surface chemistry. Next, mechanisms of promoting nulloparticle stability are defined and related to these same nulloparticle properties. Metrics involving both kinetics and thermodynamics are considered. Methods that provide quantitative metrics for measuring and modeling nulloparticle stability in terms of core composition, shape, size, and surface chemistry are outlined. The stability of solution-phase nulloparticles are also impacted by aggregation state. Thus, collision and DLVO theories are discussed. Finally, challenges and opportunities in understanding what nulloparticle stability means are addressed to facilitate further studies with this important class of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2019, "Volume": 123, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16495, "End Page": 16507, "Article Number": null, "DOI": "10.1021/acs.jpcc.9b00913", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.9b00913", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475537500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dhakal, KP; Duong, DL; Lee, J; Nam, H; Kim, M; Kan, M; Lee, YH; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dhakal, Krishna P.; Dinh Loc Duong; Lee, Jubok; Nam, Honggi; Kim, Minsu; Kan, Min; Lee, Young Hee; Kim, Jeongyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Confocal absorption spectral imaging of MoS2: optical transitions depending on the atomic thickness of intrinsic and chemically doped MoS2", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We performed a nulloscale confocal absorption spectral imaging to obtain the full absorption spectra (over the range 1.5-3.2 eV) within regions having different numbers of layers and studied the variation of optical transition depending on the atomic thickness of the MoS2 film. Three distinct absorption bands corresponding to A and B excitons and a high-energy background (BG) peak at 2.84 eV displayed a gradual redshift as the MoS2 film thickness increased from the monolayer, to the bilayer, to the bulk MoS2 and this shift was attributed to the reduction of the gap energy in the Brillouin zone at the K-point as the atomic thickness increased. We also performed n-type chemical doping of MoS2 films using reduced benzyl viologen (BV) and the confocal absorption spectra modified by the doping showed a strong dependence on the atomic thickness: A and B exciton peaks were greatly quenched in the monolayer MoS2 while much less effect was shown in larger thickness and the BG peak either showed very small quenching for 1 L MoS2 or remained constant for larger thicknesses. Our results indicate that confocal absorption spectral imaging can provide comprehensive information on optical transitions of microscopic size intrinsic and doped two-dimensional layered materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13028, "End Page": 13035, "Article Number": null, "DOI": "10.1039/c4nr03703k", "DOI Link": "http://dx.doi.org/10.1039/c4nr03703k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000344997500099", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, JH; Yu, N; Chen, ZH; Wei, YA; Li, CQ; Liu, TH; Gu, XB; Zhang, JQ; Wei, ZX; Tang, Z; Hao, XT; Zhang, FJ; Zhang, X; Huang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Jinhua; Yu, Na; Chen, Zhihao; Wei, Yanull; Li, Congqi; Liu, Tianhua; Gu, Xiaobin; Zhang, Jianqi; Wei, Zhixiang; Tang, Zheng; Hao, Xiaotao; Zhang, Fujun; Zhang, Xin; Huang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 19.2% Efficiency of Organic Solar Cells Enabled by Precisely Tuning the Charge Transfer State Via Donor Alloy Strategy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large energy loss (E-loss) is one of the main obstacles to further improve the photovoltaic performance of organic solar cells (OSCs), which is closely related to the charge transfer (CT) state. Herein, ternary donor alloy strategy is used to precisely tune the energy of CT state (E-CT) and thus the E-loss for boosting the efficiency of OSCs. The elevated E-CT in the ternary OSCs reduce the energy loss for charge generation (Delta E-CT), and promote the hybridization between localized excitation state and CT state to reduce the nonradiative energy loss (Delta E-nonrad). Together with the optimal morphology, the ternary OSCs afford an impressive power conversion efficiency of 19.22% with a significantly improved open-circuit voltage (V-oc) of 0.910 V without sacrificing short-cicuit density (J(sc)) and fill factor (FF) in comparison to the binary ones. This contribution reveals that precisely tuning the E-CT via donor alloy strategy is an efficient way to minimize E-loss and improve the photovoltaic performance of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 9, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203606, "DOI": "10.1002/advs.202203606", "DOI Link": "http://dx.doi.org/10.1002/advs.202203606", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843369200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bisogni, V; Catalano, S; Green, RJ; Gibert, M; Scherwitzl, R; Huang, YB; Strocov, VN; Zubko, P; Balandeh, S; Triscone, JM; Sawatzky, G; Schmitt, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bisogni, Valentina; Catalano, Sara; Green, Robert J.; Gibert, Marta; Scherwitzl, Raoul; Huang, Yaobo; Strocov, Vladimir N.; Zubko, Pavlo; Balandeh, Shadi; Triscone, Jean-Marc; Sawatzky, George; Schmitt, Thorsten", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ground-state oxygen holes and the metal-insulator transition in the negative charge-transfer rare-earth nickelates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The metal-insulator transition and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. Nonetheless, a complete understanding of these materials remains elusive. Here we combine X-ray absorption and resonullt inelastic X-ray scattering (RIXS) spectroscopies to resolve important aspects of the complex electronic structure of rare-earth nickelates, taking NdNiO3 thin film as representative example. The unusual coexistence of bound and continuum excitations observed in the RIXS spectra provides strong evidence for abundant oxygen holes in the ground state of these materials. Using cluster calculations and Anderson impurity model interpretation, we show that distinct spectral signatures arise from a Ni 3d(8) configuration along with holes in the oxygen 2p valence band, confirming suggestions that these materials do not obey a conventional positive charge-transfer picture, but instead exhibit a negative charge-transfer energy in line with recent models interpreting the metal-insulator transition in terms of bond disproportionation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 11", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13017, "DOI": "10.1038/ncomms13017", "DOI Link": "http://dx.doi.org/10.1038/ncomms13017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385550600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Griffith, KJ; Forse, AC; Griffin, JM; Grey, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Griffith, Kent J.; Forse, Alexander C.; Griffin, John M.; Grey, Clare P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Rate Intercalation without nullostructuring in Metastable Nb2O5 Bronze Phases", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructuring and nullosizing have been widely employed to increase the rate capability in a variety of energy storage materials. While nulloprocessing is required for many materials, we show here that both the capacity and rate performance of low-temperature bronze-phase TT- and T-polymorphs of Nb2O5 are inherent properties of the bulk crystal structure. Their unique room-and-pillar NbO6/NbO7 framework structure provides a stable host for lithium intercalation; bond valence sum mapping exposes the degenerate diffusion pathways in the sites (rooms) surrounding the oxygen pillars of this complex structure. Electrochemical analysis of thick films of micrometer-sized, insulating niobia particles indicates that the capacity of the T-phase, measured over a fixed potential window, is limited only by the Ohmic drop up to at least 60C (12.1 A.g(-1)), while the higher temperature (Wadsley-Roth, crystallographic shear structure) H-phase shows high intercalation capacity (>200 mA.h.g(-1)) but only at moderate rates. High-resolution Li-6/7 solid-state nuclear magnetic resonullce (NMR) spectroscopy of T-Nb2O5 revealed two distinct spin reservoirs, a small initial rigid population and a majority-component mobile distribution of lithium. Variable temperature NMR showed lithium dynamics for the majority lithium characterized by very low activation energies of 58(2)-98(1) meV. The fast rate, high density, good gravimetric capacity, excellent capacity retention, and safety features of bulk, insulating Nb2O5 synthesized in a single step at relatively low temperatures suggest that this material not only is structurally and electronically exceptional but merits consideration for a range of further applications. In addition, the realization of high rate performance without nullostructuring in a complex insulating oxide expands the field for battery material exploration beyond conventional strategies and structural motifs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2016, "Volume": 138, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8888, "End Page": 8899, "Article Number": null, "DOI": "10.1021/jacs.6b04345", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b04345", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380295600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Li, JS; Du, F; Yang, LY; Huang, SY; Gao, JF; Li, CM; Guo, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hui; Li, Jingsha; Du, Feng; Yang, Luyun; Huang, Shunyuan; Gao, Jingfeng; Li, Changming; Guo, Chunxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A core-shell copper oxides-cobalt oxides heterostructure nullowire arrays for nitrate reduction to ammonia with high yield rate", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical nitrate reduction to ammonia (NRA) can realize the green synthesis of ammonia (NH3) at ambient conditions, and also remove nitrate contamination in water. However, the current catalysts for NRA still face relatively low NH3 yield rate and poor stability. We present here a core-shell heterostructure comprising cobalt oxide anchored on copper oxide nullowire arrays (CuO NWAs@Co3O4) for efficient NRA. The CuO NWAs@Co3O4 demonstrates significantly enhanced NRA performance in alkaline media in comparison with plain CuO NWAs and Co3O4 flocs. Especially, at -0.23 V vs. RHE, NH3 yield rate of the CuO NWAs@Co3O4 reaches 1.915 mmol h-1 cm -2, much higher than those of CuO NWAs (1.472 mmol h-1 cm -2), Co3O4 flocs (1.222 mmol h-1 cm -2) and recent reported Cu-based catalysts. It is proposed that the synergetic effects of the heterostructure combing atom hydrogen adsorption and nitrate reduction lead to the enhanced NRA performance.(c) 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Commu-nications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1619, "End Page": 1629, "Article Number": null, "DOI": "10.1016/j.gee.2022.03.003", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2022.03.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001090191200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takagi, R; Matsuyama, N; Ukleev, V; Yu, L; White, JS; Francoual, S; Mardegan, JRL; Hayami, S; Saito, H; Kaneko, K; Ohishi, K; Onuki, Y; Arima, TH; Tokura, Y; Nakajima, T; Seki, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takagi, Rina; Matsuyama, Naofumi; Ukleev, Victor; Yu, Le; White, Jonathan S.; Francoual, Sonia; Mardegan, Jose R. L.; Hayami, Satoru; Saito, Hiraku; Kaneko, Koji; Ohishi, Kazuki; Onuki, Yoshichika; Arima, Taka-hisa; Tokura, Yoshinori; Nakajima, Taro; Seki, Shinichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Square and rhombic lattices of magnetic skyrmions in a centrosymmetric binary compound", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are topologically stable swirling spin textures with particle-like character, and have been intensively studied as a candidate of high-density information bit. While magnetic skyrmions were originally discovered in noncentrosymmetric systems with Dzyaloshinskii-Moriya interaction, recently a nullometric skyrmion lattice has also been reported for centrosymmetric rare-earth compounds, such as Gd2PdSi3 and GdRu2Si2. For the latter systems, a distinct skyrmion formation mechanism mediated by itinerant electrons has been proposed, and the search of a simpler model system allowing for a better understanding of their intricate magnetic phase diagram is highly demanded. Here, we report the discovery of square and rhombic lattices of nullometric skyrmions in a centrosymmetric binary compound EuAl4, by performing small-angle neutron and resonullt elastic X-ray scattering experiments. Unlike previously reported centrosymmetric skyrmion-hosting materials, EuAl4 shows multiple-step reorientation of the fundamental magnetic modulation vector as a function of magnetic field, probably reflecting a delicate balance of associated itinerant-electron-mediated interactions. The present results demonstrate that a variety of distinctive skyrmion orders can be derived even in a simple centrosymmetric binary compound, which highlights rare-earth intermetallic systems as a promising platform to realize/control the competition of multiple topological magnetic phases in a single material. Typically, skyrmions appear in magnet systems which are non-centrosymmetric. Here, using neutron and X-ray scattering, Takagi et al show the emergence of a skyrmion phase in the centrosymmetric material EuAl4. This expands the range of materials potential hosting skyrmions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1472, "DOI": "10.1038/s41467-022-29131-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29131-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776282500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sada, K; Darga, J; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sada, Krishnakanth; Darga, Joe; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and Prospects of Sodium-Ion and Potassium-Ion Batteries for Mass Production", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exponential growth of the lithium-ion (LIB) market is causing a significant disparity between the supply chain and demand for its resources. In this regard, sodium-ion and potassium-ion batteries are promising alternatives to LIBs due to their low cost. However, the larger sizes of Na+ and K+ ions create challenges that prevent them from achieving energy densities comparable to LIBs while maintaining an acceptable cycle life. In this perspective, the aim is to evaluate the status of Na-ion and K-ion batteries and the challenges associated with them on both fundamental and commercial levels. The focus is on the structural instability arising from phase transitions during cycling, intricate chemical degradation processes, and potential avenues for enhancing their performance with a specific goal of improving their viability for grid-scale energy storage. Materials production and abundance limitations for the chemistries of the state-of-the-art materials and account for critical parameters from both the perspective of researchers and investors are analyzed. This analysis aims to provide insights into the strategic trade-offs required to effectively implement the technology in real-world applications, such as grid-scale storage and other areas. Furthermore, the utilization of metals with low or no supply-chain problems as an important aspect of these trade-offs is considered. The challenges that must be overcome for the ubiquitous adoption of sodium-ion and potassium-ion batteries are discussed, with grid-scale energy storage in mind, including structural and interfacial stability of cathodes, electrolyte stability window, and cost-effectiveness in producing the materials at the necessary scale.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 13, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202302321", "DOI Link": "http://dx.doi.org/10.1002/aenm.202302321", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058125000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumagai, Y; Oba, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumagai, Yu; Oba, Fumiyasu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatics-based finite-size corrections for first-principles point defect calculations", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Finite-size corrections for charged defect supercell calculations typically consist of image-charge and potential alignment corrections. Regarding the image-charge correction, Freysoldt, Neugebauer, and Van de Walle (FNV) recently proposed a scheme that constructs the correction energy a posteriori through alignment of the defect-induced potential to a model charge potential [C. Freysoldt et al., Phys. Rev. Lett. 102, 016402 (2009)]. This, however, still has two shortcomings in practice. First, it uses a planar-averaged electrostatic potential for determining the potential offset, which can not be readily applied to defects with large atomic relaxation. Second, Coulomb interaction is screened by a macroscopic scalar dielectric constant, which can bring forth large errors for defects in layered and low-dimensional structures. In this study, we use the atomic site potential as a potential marker, and extend the FNV scheme by estimating long-range Coulomb interactions with a point charge model in an anisotropic medium. We also revisit the conventional potential alignment and show that it is unnecessary for correcting defect formation energies after the image-charge correction is properly applied. A systematic assessment of the accuracy of the extended FNV scheme is performed for defects and impurities in diverse materials: beta-Li2TiO3, ZnO, MgO, Al2O3, HfO2, cubic and hexagonal BN, Si, GaAs, and diamond. Defect formation energies with -6 to + 3 charges calculated using supercells containing around 100 atoms are successfully corrected even after atomic relaxation within 0.2 eV compared to those in the dilute limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 370, "Times Cited, All Databases": 399, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2014, "Volume": 89, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 195205, "DOI": "10.1103/PhysRevB.89.195205", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.195205", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336752600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rainò, G; Yazdani, N; Boehme, SC; Kober-Czerny, M; Zhu, CL; Krieg, F; Rossell, MD; Erni, R; Wood, V; Infante, I; Kovalenko, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raino, Gabriele; Yazdani, Nuri; Boehme, Simon C.; Kober-Czerny, Manuel; Zhu, Chenglian; Krieg, Franziska; Rossell, Marta D.; Erni, Rolf; Wood, Vanessa; Infante, Ivan; Kovalenko, Maksym, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-narrow room-temperature emission from single CsPbBr3 perovskite quantum dots", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor quantum dots have long been considered artificial atoms, but despite the overarching analogies in the strong energy-level quantization and the single-photon emission capability, their emission spectrum is far broader than typical atomic emission lines. Here, by using ab-initio molecular dynamics for simulating exciton-surface-phonon interactions in structurally dynamic CsPbBr3 quantum dots, followed by single quantum dot optical spectroscopy, we demonstrate that emission line-broadening in these quantum dots is primarily governed by the coupling of excitons to low-energy surface phonons. Mild adjustments of the surface chemical composition allow for attaining much smaller emission linewidths of 35-65 meV (vs. initial values of 70-120 meV), which are on par with the best values known for structurally rigid, colloidal II-VI quantum dots (20-60 meV). Ultra-narrow emission at room-temperature is desired for conventional light-emitting devices and paramount for emerging quantum light sources. Narrow emission is desired for light-emitting devices. Here, Kovalenko et al. demonstrate that the emission line-broadening in perovskite quantum dots is dominated by the coupling between excitons and surface phonon modes which can be controlled by minimal surface modifications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2587, "DOI": "10.1038/s41467-022-30016-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30016-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000801822900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pfeifer, V; Jones, TE; Vélez, JJV; Arrigo, R; Piccinin, S; Hävecker, M; Knop-Gericke, A; Schlögl, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pfeifer, Verena; Jones, Travis E.; Velez, Juan J. Velasco; Arrigo, Rosa; Piccinin, Simone; Haevecker, Michael; Knop-Gericke, Axel; Schloegl, Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ observation of reactive oxygen species forming on oxygen-evolving iridium surfaces", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water splitting performed in acidic media relies on the exceptional performance of iridium-based materials to catalyze the oxygen evolution reaction (OER). In the present work, we use in situ X-ray photoemission and absorption spectroscopy to resolve the long-standing debate about surface species present in iridium-based catalysts during the OER. We find that the surface of an initially metallic iridium model electrode converts into a mixed-valent, conductive iridium oxide matrix during the OER, which contains OII- and electrophilic OI- species. We observe a positive correlation between the OI- concentration and the evolved oxygen, suggesting that these electrophilic oxygen sites may be involved in catalyzing the OER. We can understand this observation by analogy with photosystem II; their electrophilicity renders the OI- species active in O-O bond formation, i.e. the likely potential-and rate-determining step of the OER. The ability of amorphous iridium oxyhydroxides to easily host such reactive, electrophilic species can explain their superior performance when compared to plain iridium metal or crystalline rutile-type IrO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2017, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2143, "End Page": 2149, "Article Number": null, "DOI": "10.1039/c6sc04622c", "DOI Link": "http://dx.doi.org/10.1039/c6sc04622c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395906900056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lawaniya, SD; Kumar, S; Yu, YT; Rubahn, HG; Mishra, YK; Awasthi, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lawaniya, Shiv Dutta; Kumar, Sanjay; Yu, Yeontae; Rubahn, Horst-Gunter; Mishra, Yogendra Kumar; Awasthi, Kamlendra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Functional nullomaterials in flexible gas sensors: recent progress and future prospects", "Source Title": "MATERIALS TODAY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible gas sensors have recently attracted researcher's great attention due to their applications in wearable electronics for different fields like environmental protection, food quality measurement, health supervision, etc. The bulky and complex system of conventional gas sensors hinders their applications in wearable sensing technology. Due to low cost, easy-to-use, and real-time monitoring of harmful gases, there is a rapid increase in the development of flexible gas sensors. With the mechanism of gas sensing and specification of various flexible substrates, this review article comprises a detailed discussion on nullomaterials utilized to fabricate flexible gas sensors. Specifically, all the functional materials are characterized according to their physical and chemical properties. In this article, flexible gas sensor characteristics such as sensitivity, selectivity, response time, operating temperature, and flexibility & bendability profile are discussed in detail for each material. The present review article shows the recent advancements in flexible gas sensors from the sensing material aspect and specifies their applications in various areas. Lastly, the future scope of development, like modification in morphology, functionalization, size alteration, etc., is summarized according to their current status. (c) 2023 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 29, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101428, "DOI": "10.1016/j.mtchem.2023.101428", "DOI Link": "http://dx.doi.org/10.1016/j.mtchem.2023.101428", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000949829900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, C; Wang, XC; Zhong, T; Zhou, RX; Zheng, XF; Liu, YR; Hu, TY; Luo, YX; Sun, FB; Xiao, B; Liu, ZT; Yang, CM; Yang, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Cong; Wang, Xunchang; Zhong, Tian; Zhou, Ruixue; Zheng, Xufan; Liu, Yirui; Hu, Tianyu; Luo, Yixuan; Sun, Fengbo; Xiao, Biao; Liu, Zhitian; Yang, Chunming; Yang, Renqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Cycloalkyl-Alkyl Chain-Based Symmetric/Asymmetric Acceptors with Optimized Crystal Packing and Interfacial Exciton Properties for Efficient Organic Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid cycloalkyl-alkyl side chains are considered a unique composite side-chain system for the construction of novel organic semiconductor materials. However, there is a lack of fundamental understanding of the variations in the single-crystal structures as well as the optoelectronic and energetic properties generated by the introduction of hybrid side chains in electron acceptors. Herein, symmetric/asymmetric acceptors (Y-C10ch and A-C10ch) bearing bilateral and unilateral 10-cyclohexyldecyl are designed, synthesized, and compared with the symmetric acceptor 2,2 '-((2Z,2 ' Z)-((12,13-bis(2-butyloctyl)-3,9 bis(ethylhexyl)-12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2 '',3 ''':4 ',5 ']thieno[2 ',3 ':4,5] pyrrolo[3,2-g]thieno[2 ',3 ':4,5]thieno[3,2-b]indole-2,10- diyl)bis(methanylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile (L8-BO). The stepwise introduction of 10-cyclohexyldecyl side chains decreases the optical bandgap, deepens the energy level, and enables the acceptor molecules to pack closely in a regular manner. Crystallographic analysis demonstrates that the 10-cyclohexyldecyl chain endows the acceptor with a more planar skeleton and enforces more compact 3D network packing, resulting in an active layer with higher domain purity. Moreover, the 10-cyclohexyldecyl chain affects the donor/acceptor interfacial energetics and accelerates exciton dissociation, enabling a power conversion efficiency (PCE) of >18% in the 2,2 '-((2Z,2 ' Z)-((12,13-bis(2-ethylhexyl)-3,9-diundecyl12,13-dihydro-[1,2,5]thiadiazolo[3,4-e]thieno[2 '',3 ''':4 ',5 ']thieno[2 ',3 ':4,5]pyrrolo[3,2-g]thieno[2 ',3 ':4,5]thieno[3,2-b]indole-2,10-diyl)bis(methanylylidene))bis(5,6-difluoro-3-oxo-2,3-dihydro-1H-indene-2,1-diylidene))dimalononitrile (Y6) (PM6):A-C10ch-based organic solar cells (OSCs). Importantly, the incorporation of Y-C10ch as the third component of the PM6:L8-BO blend results in a higher PCE of 19.1%. The superior molecular packing behavior of the 10-cyclohexyldecyl side chain is highlighted here for the fabrication of high-performance OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206580", "DOI Link": "http://dx.doi.org/10.1002/advs.202206580", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906046800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, KL; Zhu, JP; Wang, HL; Yang, KJ; Zhu, YM; Qing, YB; Ma, Z; Gao, LH; Liu, YB; Wei, SH; Shu, YC; Zhou, YC; He, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kailun; Zhu, Jinpeng; Wang, Hailong; Yang, Kaijun; Zhu, Yameng; Qing, Yubin; Ma, Zhuang; Gao, Lihong; Liu, Yanbo; Wei, Sihao; Shu, Yongchun; Zhou, Yanchun; He, Jilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Air plasma-sprayed high-entropy (Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 coating with high thermal protection performance", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy rare-earth aluminate (Y0.2Yb0.2Lu0.2Eu0.2Er0.2)(3)Al5O12 (HE-RE3Al5O12) has been considered as a promising thermal protection coating (TPC) material based on its low thermal conductivity and close thermal expansion coefficient to that of Al2O3. However, such a coating has not been experimentally prepared, and its thermal protection performance has not been evaluated. To prove the feasibility of utilizing HE-RE3Al5O12 as a TPC, HE-RE3Al5O12 coating was deposited on a nickelbased superalloy for the first time using the atmospheric plasma spraying technique. The stability, surface, and cross-sectional morphologies, as well as the fracture surface of the HE-RE3Al5O12 coating were investigated, and the thermal shock resistance was evaluated using the oxyacetylene flame test. The results show that the HE-RE3Al5O12 coating can remain intact after 50 cycles at 1200 degrees C for 200 s, while the edge peeling phenomenon occurs after 10 cycles at 1400 degrees C for 200 s. This study clearly demonstrates that HE-RE3Al5O12 coating is effective for protecting the nickel-based superalloy, and the atmospheric plasma spraying is a suitable method for preparing this kind of coatings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 11, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1571, "End Page": 1582, "Article Number": null, "DOI": "10.1007/s40145-022-0630-2", "DOI Link": "http://dx.doi.org/10.1007/s40145-022-0630-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000866144200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, YS; Wan, SL; Yang, S; Hu, HY; Zhang, CX; Lai, J; Zhou, JH; Chen, W; Tang, XQ; Luo, JS; Zhou, XG; Yu, L; Wang, L; Wu, AG; Fan, QZ; Wu, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yuesong; Wan, Shengli; Yang, Shuo; Hu, Haiyang; Zhang, Chunxiang; Lai, Jia; Zhou, Jiahan; Chen, Wang; Tang, Xiaoqin; Luo, Jiesi; Zhou, Xiaogang; Yu, Lu; Wang, Long; Wu, Anguo; Fan, Qingze; Wu, Jianming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macrophage cell membrane-based nulloparticles: a new promising biomimetic platform for targeted delivery and treatment", "Source Title": "JOURNAL OF nullOBIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthetic nulloparticles with surface bioconjugation are promising platforms for targeted therapy, but their simple biological functionalization is still a challenging task against the complex intercellular environment. Once synthetic nulloparticles enter the body, they are phagocytosed by immune cells by the immune system. Recently, the cell membrane camouflage strategy has emerged as a novel therapeutic tactic to overcome these issues by utilizing the fundamental properties of natural cells. Macrophage, a type of immune system cells, plays critical roles in various diseases, including cancer, atherosclerosis, rheumatoid arthritis, infection and inflammation, due to the recognition and engulfment function of removing substances and pathogens. Macrophage membranes inherit the surface protein profiles and biointerfacing properties of source cells. Therefore, the macrophage membrane cloaking can protect synthetic nulloparticles from phagocytosis by the immune cells. Meanwhile, the macrophage membrane can make use of the natural correspondence to accurately recognize antigens and target inflamed tissue or tumor sites. In this review, we have summarized the advances in the fabrication, characterization and homing capacity of macrophage membrane cloaking nulloparticles in various diseases, including cancers, immune diseases, cardiovascular diseases, central nervous system diseases, and microbial infections. Although macrophage membrane-camouflaged nulloparticles are currently in the fetal stage of development, there is huge potential and challenge to explore the conversion mode in the clinic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2022, "Volume": 20, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 542, "DOI": "10.1186/s12951-022-01746-6", "DOI Link": "http://dx.doi.org/10.1186/s12951-022-01746-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905062200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XJ; Pan, F; Sun, CK; Zhang, M; Wang, ZW; Du, JQ; Wang, J; Xiao, M; Xue, LW; Zhang, ZG; Zhang, CF; Liu, F; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xiaojun; Pan, Fei; Sun, Chenkai; Zhang, Ming; Wang, Zhiwei; Du, Jiaqi; Wang, Jing; Xiao, Min; Xue, Lingwei; Zhang, Zhi-Guo; Zhang, Chunfeng; Liu, Feng; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simplified synthetic routes for low cost and high photovoltaic performance n-type organic semiconductor acceptors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of polymer solar cells (PSCs) with n-type organic semiconductor as acceptor requires further improving powder conversion efficiency, increasing stability and decreasing cost of the related materials and devices. Here we report a simplified synthetic route for 4,4,9,9-tetrahexyl-4,9-dihydro-s-indaceno [1,2-b: 5,6-b'] dithiophene by using the catalyst of amberlyst15. Based on this synthetic route and methoxy substitution, two low cost acceptors with less synthetic steps, simple post-treatment and high yield were synthesized. In addition, the methoxy substitution improves both yield and efficiency. The high efficiency of 13.46% was obtained for the devices with MO-IDIC-2F (3,9-bis(2-methylene-5 or 6-fluoro-(3-(1,1-dicyanomethylene)- indanone)-4,4,9,9-tetrahexyl-5,10-dimethoxyl-4,9-dihydro-s-indaceno [1,2-b: 5,6-b'] dithiophene) as acceptor. Based on the cost analysis, the PSCs based on MO-IDIC- 2F possess the great advantages of low cost and high photovoltaic performance in comparison with those PSCs reported in literatures. Therefore, MO-IDIC-2F will be a promising low cost acceptor for commercial application of PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 519, "DOI": "10.1038/s41467-019-08508-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08508-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457291300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Soe, CMM; Nagabhushana, GP; Shivaramaiah, R; Tsai, HH; Nie, WY; Blancon, JC; Melkonyan, F; Cao, DH; Traoré, B; Pedesseau, L; Kepenekian, M; Katan, C; Even, J; Marks, TJ; Navrotsky, A; Mohite, AD; Stoumpos, CC; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha; Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe; Melkonyan, Ferdinulld; Cao, Duyen H.; Traore, Boubacar; Pedesseau, Laurent; Kepenekian, Mikael; Katan, Claudine; Even, Jacky; Marks, Tobin J.; Navrotsky, Alexandra; Mohite, Aditya D.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural and thermodynamic limits of layer thickness in 2D halide perovskites", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the fast-evolving field of halide perovskite semiconductors, the 2D perovskites (A')(2)(A)(n-1)MnX3n+1 [where A = Cs+, CH3NH3+, HC(NH2)(2)(+) ; A' = ammonium cation acting as spacer; M = Ge2+, Sn2+, Pb2+; and X = Cl-, Br-, I-] have recently made a critical entry. The n value defines the thickness of the 2D layers, which controls the optical and electronic properties. The 2D perovskites have demonstrated preliminary optoelectronic device lifetime superior to their 3D counterparts. They have also attracted fundamental interest as solution-processed quantum wells with structural and physical properties tunable via chemical composition, notably by the n value defining the perovskite layer thickness. The higher members (n > 5) have not been documented, and there are important scientific questions underlying fundamental limits for n. To develop and utilize these materials in technology, it is imperative to understand their thermodynamic stability, fundamental synthetic limitations, and the derived structure-function relationships. We report the effective synthesis of the highest iodide n-members yet, namely (CH3(CH2)(2)NH3)(2)(CH3NH3)(5)Pb6I19 (n = 6) and (CH3(CH2)(2)NH3)(2)(CH3NH3)(6)Pb7I22 (n = 7), and confirm the crystal structure with single-crystal X-ray diffraction, and provide indirect evidence for (CH3(CH2)(2)NH3)(2)(CH3NH3)(8)Pb9I28 (n = 9). Direct HCl solution calorimetric measurements show the compounds with n > 7 have unfavorable enthalpies of formation (Delta H-f), suggesting the formation of higher homologs to be challenging. Finally, we report preliminary n-dependent solar cell efficiency in the range of 9-12.6% in these higher n-members, highlighting the strong promise of these materials for high-performance devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2019, "Volume": 116, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 58, "End Page": 66, "Article Number": null, "DOI": "10.1073/pnas.1811006115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1811006115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454707700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Madsen, GKH; Carrete, J; Verstraete, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Madsen, Georg K. H.; Carrete, Jesus; Verstraete, Matthieu J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "BoltzTraP2, a program for interpolating band structures and calculating semi-classical transport coefficients", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "BoltzTraP2 is a software package for calculating a smoothed Fourier expression of periodic functions and the Onsager transport coefficients for extended systems using the linearized Boltzmann transport equation. It uses only the band and k-dependent quasi-particle energies, as well as the intra-band optical matrix elements and scattering rates, as input. The code can be used via a command-line interface and/or as a Python module. It is tested and illustrated on a simple parabolic band example as well as silicon. The positive Seebeck coefficient of lithium is reproduced in an example of going beyond the constant relaxation time approximation. Program summary Program Title: Bolt zTraP2 Program Files doi: http://dx.doLorg/10.17632/bzb9byx8g8.1 Licensing provisions: GPLv3 Programming language: Python and C++ External routines/libraries: NumPy, SciPy, Matplotlib, spglib, ase, fftw, VTK, netCDF4, Eigen Nature of problem: Calculating the transport coefficients using the linearized Boltzmann transport equation within the relaxation time approximation. Solution method: Smoothed Fourier interpolation (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 960, "Times Cited, All Databases": 1006, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 231, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 140, "End Page": 145, "Article Number": null, "DOI": "10.1016/j.cpc.2018.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2018.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437964200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Worthy, A; Grosjean, A; Pfrunder, MC; Xu, YA; Yan, C; Edwards, G; Clegg, JK; McMurtrie, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Worthy, Anna; Grosjean, Arnaud; Pfrunder, Michael C.; Xu, Yanull; Yan, Cheng; Edwards, Grant; Clegg, Jack K.; McMurtrie, John C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic resolution of structural changes in elastic crystals of copper(II) acetylacetonate", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals are typically brittle, inelastic materials. Such mechanical responses limit their use in practical applications, particularly in flexible electronics and optical devices. Here we describe single crystals of a well-known coordination compound-copper(II) acetylacetonate-that are flexible enough to be reversibly tied into a knot. Mechanical measurements indicate that the crystals exhibit an elasticity similar to that of soft materials such as nylon, and thus display properties normally associated with both hard and soft matter. Using microfocused synchrotron radiation, we mapped the changes in crystal structure that occur on bending, and determined the mechanism that allows this flexibility with atomic precision. We show that, under strain, the molecules in the crystal reversibly rotate, and thus reorganize to allow the mechanical compression and expansion required for elasticity and still maintain the integrity of the crystal structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 69, "Article Number": null, "DOI": "10.1038/NCHEM.2848", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423143500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mishra, R; Yu, JW; Qiu, XP; Motapothula, M; Venkatesan, T; Yang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mishra, Rahul; Yu, Jiawei; Qiu, Xuepeng; Motapothula, M.; Venkatesan, T.; Yang, Hyunsoo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalous Current-Induced Spin Torques in Ferrimagnets near Compensation", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While current-induced spin-orbit torques have been extensively studied in ferromagnets and anti-ferromagnets, ferrimagnets have been less studied. Here we report the presence of enhanced spin-orbit torques resulting from negative exchange interaction in ferrimagnets. The effective field and switching efficiency increase substantially as CoGd approaches its compensation point, giving rise to 9 times larger spin-orbit torques compared to that of a noncompensated one. The macrospin modeling results also support efficient spin-orbit torques in a ferrimagnet. Our results suggest that ferrimagnets near compensation can be a new route for spin-orbit torque applications due to their high thermal stability and easy current-induced switching assisted by negative exchange interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2017, "Volume": 118, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 167201, "DOI": "10.1103/PhysRevLett.118.167201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.167201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399816500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ER; Dao, M; Karniadakis, GE; Suresh, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Enrui; Dao, Ming; Karniadakis, George Em; Suresh, Subra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analyses of internal structures and defects in materials using physics-informed neural networks", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Characterizing internal structures and defects in materials is a challenging task, often requiring solutions to inverse problems with unknown topology, geometry, material properties, and nonlinear deformation. Here, we present a general framework based on physics-informed neural networks for identifying unknown geometric and material parameters. By using a mesh-free method, we parameterize the geometry of the material using a differentiable and trainable method that can identify multiple structural features. We validate this approach for materials with internal voids/inclusions using constitutive models that encompass the spectrum of linear elasticity, hyperelasticity, and plasticity. We predict the size, shape, and location of the internal void/inclusion as well as the elastic modulus of the inclusion. Our general framework can be applied to other inverse problems in different applications that involve unknown material properties and highly deformable geometries, targeting material characterization, quality assurance, and structural design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabk0644", "DOI": "10.1126/sciadv.abk0644", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abk0644", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757399100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khanzadeh, M; Chowdhury, S; Marufuzzaman, M; Tschopp, MA; Bian, LK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khanzadeh, Mojtaba; Chowdhury, Sudipta; Marufuzzaman, Mohammad; Tschopp, Mark A.; Bian, Linkan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porosity prediction: Supervised-learning of thermal history for direct laser deposition", "Source Title": "JOURNAL OF MANUFACTURING SYSTEMS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this study is to investigate the relationship between the melt pool characteristics and the defect occurrence in an as-built additive manufacturing part. One of the major detrimental microstructure properties associated with additive manufacturing (AM) is porosity within final parts. State-of-the-art porosity detection methods focus primarily on post-manufacturing approaches that are susceptible to high cost of process, longer process time, and are incapable of characterizing pores during fabrication. A real-time porosity prediction method is developed using morphological characteristics of the melt pool boundary (i.e., features obtained via functional principal component analysis (FPCA)). A thermal monitoring system is used to capture the time varying melt pool signal, which are labeled as either pores or normal melt pools by X-ray tomography. Supervised learning methods are utilized to identify the patterns of melt pool images and build a black-box model for the probability distribution of class labels (namely, porosity) based on data characteristics of predictors (e.g., melt pool characteristics). The resultant model does not depend on specific design of specimens with varying material properties; and can be effectively developed as long as thermal-porosity data can be obtained. In the current study, multiple supervised machine learning approaches are used to classify melt pools to predict porosity in a part. Two different accuracy measures are used and numerical experiments show that among the classification approaches used (i.e., Decision Tree (DT), K-Nearest Neighbor (KNN), Support Vector Machine (SVM), Linear Discriminullt Analysis (LDA), and Quadratic Discriminullt Analysis (QDA)), KNN results in the highest rate of accurately classifying melt pools (98.44%). However, DT results in the lowest rate for incorrectly identifying normal melt pools as pores (0.03%). A comparative study is conducted that compares the performance of supervised learning methods leveraging the proposed morphological model and simple metrics of the melt pool. Numerical experiments show that the morphological model combined with supervised learning techniques vastly outperform the simple melt pool metrics combined with supervised learning techniques (approximately 250% better performance for correctly predicting abnormal melt pools). Our approach may potentially be applied to other AM processes that share similar energy-material interactions (e.g., powder bed fusion, electron beam melting).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 69, "End Page": 82, "Article Number": null, "DOI": "10.1016/j.jmsy.2018.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.jmsy.2018.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Operations Research & Management Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435061400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krausmann, F; Wiedenhofer, D; Lauk, C; Haas, W; Tanikawa, H; Fishman, T; Miatto, A; Schandl, H; Haberl, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krausmann, Fridolin; Wiedenhofer, Dominik; Lauk, Christian; Haas, Willi; Tanikawa, Hiroki; Fishman, Tomer; Miatto, Alessio; Schandl, Heinz; Haberl, Helmut", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global socioeconomic material stocks rise 23-fold over the 20th century and require half of annual resource use", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Human-made material stocks accumulating in buildings, infrastructure, and machinery play a crucial but underappreciated role in shaping the use of material and energy resources. Building, maintaining, and in particular operating in-use stocks of materials require raw materials and energy. Material stocks create long-term pathdependencies because of their longevity. Fostering a transition toward environmentally sustainable patterns of resource use requires a more complete understanding of stock-flow relations. Here we show that about half of all materials extracted globally by humans each year are used to build up or renew in-use stocks of materials. Based on a dynamic stock-flow model, we analyze stocks, inflows, and outflows of all materials and their relation to economic growth, energy use, and CO2 emissions from 1900 to 2010. Over this period, global material stocks increased 23-fold, reaching 792 Pg (+/- 5%) in 2010. Despite efforts to improve recycling rates, continuous stock growth precludes closing material loops; recycling still only contributes 12% of inflows to stocks. Stocks are likely to continue to grow, driven by large infrastructure and building requirements in emerging economies. A convergence of material stocks at the level of industrial countries would lead to a fourfold increase in global stocks, and CO2 emissions exceeding climate change goals. Reducing expected future increases of material and energy demand and greenhouse gas emissions will require decoupling of services from the stocks and flows of materials through, for example, more intensive utilization of existing stocks, longer service lifetimes, and more efficient design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2017, "Volume": 114, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1880, "End Page": 1885, "Article Number": null, "DOI": "10.1073/pnas.1613773114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1613773114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395099500061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dang, HX; Wang, K; Ghasemi, M; Tang, MC; De Bastiani, M; Aydin, E; Dauzon, E; Barrit, D; Peng, J; Smilgies, DM; De Wolf, S; Amassian, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dang, Hoang X.; Wang, Kai; Ghasemi, Masoud; Tang, Ming-Chun; De Bastiani, Michele; Aydin, Erkan; Dauzon, Emilie; Barrit, Dounya; Peng, Jun; Smilgies, Detlef-M; De Wolf, Stefaan; Amassian, Aram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-cation Synergy Suppresses Phase Segregation in Mixed-Halide Perovskites", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixed lead halide perovskite solar cells have been demonstrated to benefit tremendously from the addition of Cs+ and Rb+, but its root cause is yet to be understood. This hinders further improvement, and processing approaches remain largely empirical. We address the challenge by tracking the solidification of precursors in situ and linking the evolutions of different crystalline phases to the presence of Cs+ and Rb+. In their absence, the perovskite film is inherently unstable, segregating into MA-I- and FA-Br-rich phases. Adding either Cs+ or Rb+ is shown to alter the solidification process of the perovskite films. The optimal addition of both Cs+ and Rb+ drastically suppress phase segregation and promotes the spontaneous formation of the desired alpha phase. We propose that the synergistic effect is due to the collective benefits of Cs+ and Rb+ on the formation kinetics of the alpha phase and on the halide distribution throughout the film.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1746, "End Page": 1764, "Article Number": null, "DOI": "10.1016/j.joule.2019.05.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.05.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476463300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, W; Falzon, BG; Chiu, LNS; Price, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Wei; Falzon, Brian G.; Chiu, Louis N. S.; Price, Mark", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Predicting low velocity impact damage and Compression-After-Impact (CAI) behaviour of composite laminates", "Source Title": "COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-velocity impact damage can drastically reduce the residual strength of a composite structure even when the damage is barely visible. The ability to computationally predict the extent of damage and compression-after-impact (CAI) strength of a composite structure can potentially lead to the exploration of a larger design space without incurring significant time and cost penalties. A high-fidelity three-dimensional composite damage model, to predict both low-velocity impact damage and CAI strength of composite laminates, has been developed and implemented as a user material subroutine in the commercial finite element package, ABAQUS/Explicit. The intralaminar damage model component accounts for physically-based tensile and compressive failure mechanisms, of the fibres and matrix, when subjected to a three-dimensional stress state. Cohesive behaviour was employed to model the interlaminar failure between plies with a bi-linear traction-separation law for capturing damage onset and subsequent damage evolution. The virtual tests, set up in ABAQUS/Explicit, were executed in three steps, one to capture the impact damage, the second to stabilize the specimen by imposing new boundary conditions required for compression testing, and the third to predict the CAI strength. The observed intralaminar damage features, delamination damage area as well as residual strength are discussed. It is shown that the predicted results for impact damage and CAI strength correlated well with experimental testing without the need of model calibration which is often required with other damage models. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 71, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 226, "Article Number": null, "DOI": "10.1016/j.compositesa.2015.01.025", "DOI Link": "http://dx.doi.org/10.1016/j.compositesa.2015.01.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350839800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XY; Wu, XY; Xu, K; Xu, H; Chen, HZ; Huang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xiaoyi; Wu, Xinyu; Xu, Kai; Xu, Hong; Chen, Hongzheng; Huang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore partition in two-dimensional covalent organic frameworks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) have emerged as a kind of crystalline polymeric materials with high compositional and geometric tunability. Most COFs are currently designed and synthesized as mesoporous (2-50nm) and microporous (1-2nm) materials, while the development of ultramicroporous (<1nm) COFs remains a daunting challenge. Here, we develop a pore partition strategy into COF chemistry, which allows for the segmentation of a mesopore into multiple uniform ultramicroporous domains. The pore partition is implemented by inserting an additional rigid building block with suitable symmetries and dimensions into a prebuilt parent framework, leading to the partitioning of one mesopore into six ultramicropores. The resulting framework features a wedge-shaped pore with a diameter down to 6.5 angstrom, which constitutes the smallest pore among COFs. The wedgy and ultramicroporous one-dimensional channels enable the COF to be highly efficient for the separation of five hexane isomers based on the sieving effect. The obtained average research octane number (RON) values of those isomer blends reach up to 99, which is among the highest records for zeolites and other porous materials. Therefore, this strategy constitutes an important step in the pore functional exploitation of COFs to implement pre-designed compositions, components, and functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3360, "DOI": "10.1038/s41467-023-39126-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39126-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001047512000034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, FJ; Liu, Y; Jiao, CY; El-Bahy, SM; Shao, Q; El-Bahy, ZM; Li, HD; Wasnik, P; Algadi, H; Xu, BB; Wang, N; Yuan, YH; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Fengjun; Liu, Yan; Jiao, Cuiyan; El-Bahy, Salah M.; Shao, Qian; El-Bahy, Zeinhom M.; Li, Handong; Wasnik, Priyanka; Algadi, Hassan; Xu, Ben Bin; Wang, Ning; Yuan, Yihui; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorine-phosphate copolymerization waterborne acrylic resin coating with enhanced anticorrosive performance", "Source Title": "JOURNAL OF POLYMER SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The modified waterborne acrylic resin was synthesized successfully by emulsion polymerization with octafluoropentyl methacrylate and phosphate functional monomer as monomers, showing an improved anti-corrosion performance of the resin coating. The existence and general distribution of the elements of the modified monomer in the emulsion were explored, and the anti-corrosion mechanism was disclosed. The results show that the modification of octafluoropentyl methacrylate and phosphate functional monomers improved the water resistance, corrosion resistance and thermal stability of acrylic resins. Compared with unmodified acrylic resin, the contact angle of the modified resin was increased from 74.23 degrees to 83.51 degrees, and the initial decomposition temperature was increased from 264 to 305 degrees C. At the same time, the corrosion voltage of the modified resin was increased, the corrosion current density was decreased, and the salt spray resistance was improved. This study provides a new way for the preparation of environmentally friendly, stable, and corrosion-resistant waterborne acrylic resins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2023, "Volume": 61, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2677, "End Page": 2687, "Article Number": null, "DOI": "10.1002/pol.20230108", "DOI Link": "http://dx.doi.org/10.1002/pol.20230108", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000974297100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, HW; Wang, ZL; Dai, K; Li, SW; Zhang, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Houwei; Wang, Zhongliao; Dai, Kai; Li, Suwen; Zhang, Jinfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LSPR-enhanced carbon-coated In2O3/W18O49 S-scheme heterojunction for efficient CO2 photoreduction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The special defect structure and localized surface plasmon resonullce (LSPR) effect offer W18O49 extraordinary potential and research value in photocatalysis. The LSPR effect optimizes the design of W18O49-sensitized photocatalytic composites and broadens the light-response range of W18O49. However, the high-energy hot electrons generated by W18O49 under the LSPR effect exhibit an extremely short lifetime and cannot be fully utilized. Therefore, the high electron conductivity of carbon can be used to increase the rate of hot-electron transfer, thereby extending the lifetime of hot electrons. In this study, a heterojunction photocatalyst was formed by growing a high-absorbance one-dimensional nullowire W18O49 on the surface of carbon-coated porous In2O3 nullorods (C-In2O3) derived from In-MOF. The C-In2O3/W18O49 composites exhibited optical re-sponses in both the visible and near-infrared regions. The carbon coatings acted as transport chan-nels to accelerate the transfer of carriers and hot electrons, and the activity of photocatalytic CO2 reduction (PCR) was significantly enhanced. The 40%C-In2O3/W18O49 composites had the highest CO yield in the photocatalytic reactions, which was 2.99 and 2.84 times greater than that of pure C-In2O3 and W18O49, respectively. The internal electronic transfer in the S-scheme heterojunction and LSPR-induced hot electrons injected into C-In2O3 achieved dual-path electron transfer for PCR. & COPY; 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 48, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 267, "End Page": 278, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64420-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64420-1", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026624000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Perry, SL; Leon, L; Hoffmann, KQ; Kade, MJ; Priftis, D; Black, KA; Wong, D; Klein, RA; Pierce, CF; Margossian, KO; Whitmer, JK; Qin, J; de Pablo, JJ; Tirrell, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Perry, Sarah L.; Leon, Lorraine; Hoffmann, Kyle Q.; Kade, Matthew J.; Priftis, Dimitrios; Black, Katie A.; Wong, Derek; Klein, Ryan A.; Pierce, Charles F., III; Margossian, Khatcher O.; Whitmer, Jonathan K.; Qin, Jian; de Pablo, Juan J.; Tirrell, Matthew", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chirality-selected phase behaviour in ionic polypeptide complexes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyelectrolyte complexes present new opportunities for self-assembled soft matter. Factors determining whether the phase of the complex is solid or liquid remain unclear. Ionic polypeptides enable examination of the effects of stereochemistry on complex formation. Here we demonstrate that chirality determines the state of polyelectrolyte complexes, formed from mixing dilute solutions of oppositely charged polypeptides, via a combination of electrostatic and hydrogen-bonding interactions. Fluid complexes occur when at least one of the polypeptides in the mixture is racemic, which disrupts backbone hydrogen-bonding networks. Pairs of purely chiral polypeptides, of any sense, form compact, fibrillar solids with a beta-sheet structure. Analogous behaviour occurs in micelles formed from polypeptide block copolymers with polyethylene oxide, where assembly into aggregates with either solid or fluid cores, and eventually into ordered phases at high concentrations, is possible. Chirality is an exploitable tool for manipulating material properties in polyelectrolyte complexation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6052, "DOI": "10.1038/ncomms7052", "DOI Link": "http://dx.doi.org/10.1038/ncomms7052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348830100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, QL; Duan, SY; Zhao, Z; Wang, PD; Lei, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Qingliang; Duan, Shengyu; Zhao, Zeang; Wang, Panding; Lei, Hongshuai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverse Design of Energy-Absorbing Metamaterials by Topology Optimization", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compared with the forward design method through the control of geometric parameters and material types, the inverse design method based on the target stress-strain curve is helpful for the discovery of new structures. This study proposes an optimization strategy for mechanical metamaterials based on a genetic algorithm and establishes a topology optimization method for energy-absorbing structures with the desired stress-strain curves. A series of structural mutation algorithms and design-domain-independent mesh generation method are developed to improve the efficiency of finite element analysis and optimization iteration. The algorithm realizes the design of ideal energy-absorbing structures, which are verified by additive manufacturing and experimental characterization. The error between the stress-strain curve of the designed structure and the target curve is less than 5%, and the densification strain reaches 0.6. Furthermore, special attention is paid to passive pedestrian protection and occupant protection, and a reasonable solution is given through the design of a multiplatform energy-absorbing structure. The proposed topology optimization framework provides a new solution path for the elastic-plastic large deformation problem that is unable to be resolved by using classical gradient algorithms or genetic algorithms, and simplifies the design process of energy-absorbing mechanical metamaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202204977", "DOI Link": "http://dx.doi.org/10.1002/advs.202204977", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000895970300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lou, XY; Andresen, PL; Rebak, RB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lou, Xiaoyuan; Andresen, Peter L.; Rebak, Raul B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxide inclusions in laser additive manufactured stainless steel and their effects on impact toughness and stress corrosion cracking behavior", "Source Title": "JOURNAL OF NUCLEAR MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intergranular and intragranular Si and Mn rich oxide inclusions are present in laser additive manufactured austenitic stainless steel. The uniform oxide dispersions in additive manufactured material promoted early initiation of microvoids and reduced its impact toughness relative to powder metallurgy (hot isostatic pressing) and wrought materials. For stress corrosion cracking in high temperature water, the silica inclusions along the grain boundaries preferentially dissolved and appeared to accelerate oxidation and caused extensive crack branching. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 499, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 182, "End Page": 190, "Article Number": null, "DOI": "10.1016/j.jnucmat.2017.11.036", "DOI Link": "http://dx.doi.org/10.1016/j.jnucmat.2017.11.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425106800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Heo, SY; Lee, GJ; Kim, H; Kim, YJ; Ishii, S; Kim, MS; Seok, TJ; Lee, BJ; Lee, H; Song, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Heo, Se-Yeon; Lee, Gil Ju; Kim, Hyeon; Kim, Yeong Jae; Ishii, Satoshi; Kim, Min Seok; Seok, Tae Joon; Lee, Bong Jae; Lee, Heon; Song, Young Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Janus emitter for passive heat release from enclosures", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passive radiative cooling functions by reflecting the solar spectrum and emitting infrared waves in broadband or selectively. However, cooling enclosed spaces that trap heat by greenhouse effect remains a challenge. We present a Janus emitter (JET) consisting of an Ag-polydimethylsiloxane layer on micropatterned quartz substrate. The induced spoof surface plasmon polariton helps overcome inherent emissivity loss of the polymer and creates near-ideal selective and broadband emission on the separate sides. This design results in not only remarkable surface cooling when the JET is attached with either side facing outwards but also space cooling when used as an enclosure wall. Thus, the JET can passively mitigate the greenhouse effect in enclosures while offering surface cooling performance comparable to conventional radiative coolers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb1906", "DOI": "10.1126/sciadv.abb1906", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb1906", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000567766700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, Z; Ou, YT; Zhang, B; Wang, JD; Fu, L; Wan, MT; Li, GC; Wang, WY; Wang, L; Jiang, JJ; Seh, ZW; Hu, EY; Yang, XQ; Cui, Y; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Zhao; Ou, Yangtao; Zhang, Bao; Wang, Jindi; Fu, Lin; Wan, Mintao; Li, Guocheng; Wang, Wenyu; Wang, Li; Jiang, Jianjun; Seh, Zhi Wei; Hu, Enyuan; Yang, Xiao-Qing; Cui, Yi; Sun, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Replacement Reaction Enabled Interdigitated Metal/Solid Electrolyte Architecture for Battery Cycling at 20 mA cm-2 and 20 mAh cm-2", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal anodes represent as a prime choice for the coming generation rechargeable batteries with high energy density. However, daunting challenges including electrode volume variation and inevitable side reactions preclude them from becoming a viable technology. Here, a facile replacement reaction was employed to fabricate a three-dimensional (3D) interdigitated metal/solid electrolyte composite electrode, which not only provides a stable host structure for buffering the volume change within the composite but also prevents side reactions by avoiding the direct contact between active metal and liquid electrolyte. As a proof-of-concept demonstration, a 3D interdigitated zinc (Zn) metal/solid electrolyte architecture was fabricated via a galvanic replacement reaction between Zn metal foil and indium (In) chloride solution followed by electrochemical activation, featuring the interdigitation between metallic Zn and amorphous indium hydroxide sulfate (IHS) with high Zn2+ conductivity (56.9 +/- 1.8 mS cm(-1)), large Zn2+ transference number (0.55), and high electronic resistivity [(2.08 +/- 0.01) x 10(3) Omega cm]. The as-designed Zn/IHS electrode sustained stable electrochemical Zn plating/stripping over 700 cycles with a record-low overpotential of 8 mV at 1 mA cm(-2) and 0.5 mAh cm(-2). More impressively, it displayed cycle-stable performance with low overpotential of 10 mV under ultrahigh current density and areal capacity (20 mA cm(-2), 20 mAh cm(-2)), which outperformed all the reported Zn metal electrodes in mild aqueous electrolyte. The fabrication of interdigitated metal/solid electrolyte was generalized to other metal pairs, including Zn/Sn and Zn/Co, which provide inspiration for next-generation Zn metal batteries with high energy density and reversibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2021, "Volume": 143, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3143, "End Page": 3152, "Article Number": null, "DOI": "10.1021/jacs.0c11753", "DOI Link": "http://dx.doi.org/10.1021/jacs.0c11753", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626325000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zarandona, I; Correia, DM; Moreira, J; Costa, CM; Lanceros-Mendez, S; Guerrero, P; de la Caba, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zarandona, Iratxe; Correia, Daniela M.; Moreira, Joana; Costa, Carlos M.; Lanceros-Mendez, Senentxu; Guerrero, Pedro; de la Caba, Koro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetically responsive chitosan-pectin films incorporating Fe3O4 nulloparticles with enhanced antimicrobial activity br", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chitosan-pectin films with iron oxide (Fe3O4) magnetic nulloparticles were prepared by solution casting in order to produce biopolymer based magnetically active materials. Infrared (FTIR) spectra indicated physical in-teractions between the matrix and nulloparticles, corroborated by differential scanning calorimetry (DSC) results. In addition, thermal characterization suggested that the interactions between chitosan, pectin and the nullo-particles resulted in a less compact structure, influencing the film mechanical properties. Regarding vibrating- sample magnetometry (VSM) and electrical analysis, chitosan-pectin films with Fe3O4 nulloparticles showed ferrimagnetic behavior, with an increase of the dielectric constant as the nulloparticle concentration increased. Furthermore, films displayed enhanced antimicrobial activity against Escherichia coli (Gram-negative) and Staphylococcus epidermidis (Gram-positive) bacteria. Therefore, chitosan-pectin films with Fe3O4 magnetic nulloparticles provide promising results for active and intelligent food packaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 227, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1070, "End Page": 1077, "Article Number": null, "DOI": "10.1016/j.ijbiomac.2022.11.286", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2022.11.286", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921884300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, HD; Kim, C; Chen, LH; Chandrasekaran, A; Batra, R; Venkatram, S; Kamal, D; Lightstone, JP; Gurnulli, R; Shetty, P; Ramprasad, M; Laws, J; Shelton, M; Ramprasad, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tran, Huan Doan; Kim, Chiho; Chen, Lihua; Chandrasekaran, Anulld; Batra, Rohit; Venkatram, Shruti; Kamal, Deepak; Lightstone, Jordan P.; Gurnulli, Rishi; Shetty, Pranav; Ramprasad, Manav; Laws, Julia; Shelton, Madeline; Ramprasad, Rampi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-learning predictions of polymer properties with Polymer Genome", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer Genome is a web-based machine-learning capability to perform near-instantaneous predictions of a variety of polymer properties. The prediction models are trained on (and interpolate between) an underlying database of polymers and their properties obtained from first principles computations and experimental measurements. In this contribution, we first provide an overview of some of the critical technical aspects of Polymer Genome, including polymer data curation, representation, learning algorithms, and prediction model usage. Then, we provide a series of pedagogical examples to demonstrate how Polymer Genome can be used to predict dozens of polymer properties, appropriate for a range of applications. This contribution is closed with a discussion on the remaining challenges and possible future directions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2020, "Volume": 128, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 171104, "DOI": "10.1063/5.0023759", "DOI Link": "http://dx.doi.org/10.1063/5.0023759", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591681100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, JM; Cao, Y; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jeong Min; Cao, Yuan; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flavour Hund's coupling, Chern gaps and charge diffusivity in moire graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interaction-driven spontaneous symmetry breaking lies at the heart of many quantum phases of matter. In moire systems, broken spin/valley 'flavour' symmetry in flat bands underlies the parent state from which correlated and topological ground states ultimately emerge(1-10). However, the microscopic mechanism of such flavour symmetry breaking and its connection to the low-temperature phases are not yet understood. Here we investigate the broken-symmetry many-body ground state of magic-angle twisted bilayer graphene (MATBG) and its nontrivial topology using simultaneous thermodynamic and transport measurements. We directly observe flavour symmetry breaking as pinning of the chemical potential at all integer fillings of the moire superlattice, demonstrating the importance of flavour Hund's coupling in the many-body ground state. The topological nature of the underlying flat bands is manifested upon breaking time-reversal symmetry, where we measure energy gaps corresponding to Chern insulator states with Chern numbers 3, 2, 1 at filling factors 1, 2, 3, respectively, consistent with flavour symmetry breaking in the Hofstadter butterfly spectrum of MATBG. Moreover, concurrent measurements of resistivity and chemical potential provide the temperature-dependent charge diffusivity of MATBG in the strange-metal regime(11)-a quantity previously explored only in ultracold atoms(12). Our results bring us one step closer to a unified framework for understanding interactions in the topological bands of MATBG, with and without a magnetic field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2021, "Volume": 592, "Issue": 7852, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 43, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03366-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03366-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000635764400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, XL; Zhou, LC; Wang, CX; Yu, K; Zhu, YQ; Yi, M; Wang, LF; Wen, SF; He, WF; Liang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Xinlei; Zhou, Liucheng; Wang, Chenxi; Yu, Kun; Zhu, Yiqi; Yi, Min; Wang, Lingfeng; Wen, Shifeng; He, Weifeng; Liang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure and residual stress modulation of 7075 aluminum alloy for improving fatigue performance by laser shock peening", "Source Title": "INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Laser shock peening (LSP) is an advanced surface-strengthening technology that improves the anti-fatigue per-formance of metallic components. However, there is a significant barrier to the application of thin-walled components because the high-energy laser causes deformation and nonuniformity of compressive residual stress, thereby reducing fatigue performance. In this study, an LSP technology based on a low-pulse-energy laser was developed. We applied it to a thin-walled AA7075 aluminium alloy specimen (similar to 4 mm thickness) and achieved an improvement in the high-cycle fatigue limit of 20.4 and 37.0% for the smooth and pre-cracked fatigue specimens, respectively, in the absence of deformation. It was discovered that the enhanced dynamic nulloscale precipitation and dislocation multiplication effects of the high-pressure shock wave contribute to microstructure stability under cyclic loading, resulting in high compressive residual stress stability. Moreover, the unique heterogeneous grain structure on the surface layer subjected to LSP at low pulse energy effectively restrains crack initiation and propagation. Because these findings apply to a wide range of alloys, the current results create new avenues for improving the fatigue performance of thin-walled components.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 184, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103979, "DOI": "10.1016/j.ijmachtools.2022.103979", "DOI Link": "http://dx.doi.org/10.1016/j.ijmachtools.2022.103979", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992011600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Wu, MM; Ma, JW; Wei, GF; Ling, Y; Zhang, RY; Huang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yi; Wu, Miaomiao; Ma, Jiwei; Wei, Guangfeng; Ling, Yun; Zhang, Renyuan; Huang, Yunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revisiting the Na2/3Ni1/3Mn2/3O2 Cathode: Oxygen Redox Chemistry and Oxygen Release Suppression", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium layered transition metal oxides have been considered as promising cathode materials for sodium ion batteries due to their large capacity and high operating voltage. However, mechanism investigations of chemical evolution and capacity failure at high voltage are inadequate. As a representative cathode, Na2/3Ni1/3Mn2/3O2, the capacity contribution at a 4.2 V plateau has long been assigned to the redox of the Ni3+/Ni4+ couple, while at the same time it suffers large irreversible capacity loss during the initial discharging process. In this work, we prove that the capacity at the 4.2 V plateau is contributed to the irreversible O2-/O-2(n-)/O-2 evolution based on in situ differential electrochemical mass spectrometry and density functional theory calculation results. Besides, a phenomenon of oxygen release and subsequent surface lattice densification is observed, which is responsible for the large irreversible capacity loss during the initial cycle. Furthermore, the oxygen release is successfully suppressed by Fe substitution due to the formation of a unique Fe-(O-O) species, which effectively stabilizes the reversibility of the O2-/O-2(n-) redox at high operating voltage. Our findings provide a new understanding of the chemical evolution in layered transition metal oxides at high operating voltage. Increasing the covalency of the TM-O bond has been proven to be effective in suppressing the oxygen release and hence improving the electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2020, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 232, "End Page": 240, "Article Number": null, "DOI": "10.1021/acscentsci.9b01166", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b01166", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517832800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, D; Go, D; Park, HJ; Jeong, W; Ko, HW; Yun, D; Jo, D; Lee, S; Go, G; Oh, JH; Kim, KJ; Park, BG; Min, BC; Koo, HC; Lee, HW; Lee, O; Lee, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Dongjoon; Go, Dongwook; Park, Hyeon-Jong; Jeong, Wonmin; Ko, Hye-Won; Yun, Deokhyun; Jo, Daegeun; Lee, Soogil; Go, Gyungchoon; Oh, Jung Hyun; Kim, Kab-Jin; Park, Byong-Guk; Min, Byoung-Chul; Koo, Hyun Cheol; Lee, Hyun-Woo; Lee, OukJae; Lee, Kyung-Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orbital torque in magnetic bilayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The orbital Hall effect describes the generation of the orbital current flowing in a perpendicular direction to an external electric field, analogous to the spin Hall effect. As the orbital current carries the angular momentum as the spin current does, injection of the orbital current into a ferromagnet can result in torque on the magnetization, which provides a way to detect the orbital Hall effect. With this motivation, we examine the current-induced spin-orbit torques in various ferromagnet/heavy metal bilayers by theory and experiment. Analysis of the magnetic torque reveals the presence of the contribution from the orbital Hall effect in the heavy metal, which competes with the contribution from the spin Hall effect. In particular, we find that the net torque in Ni/Ta bilayers is opposite in sign to the spin Hall theory prediction but instead consistent with the orbital Hall theory, which unambiguously confirms the orbital torque generated by the orbital Hall effect. Our finding opens a possibility of utilizing the orbital current for spintronic device applications, and it will invigorate researches on spin-orbit-coupled phenomena based on orbital engineering. The orbital Hall effect involves the transport of orbital angular momentum perpendicular to an applied charge current, analogous to the spin Hall effect. Here, Lee et al examine magnetic torques present in a Nickel/Tantalum bilayer, clearly demonstrating the contribution of the orbital Hall effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6710, "DOI": "10.1038/s41467-021-26650-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26650-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720682300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hwang, WS; Verma, A; Peelaers, H; Protasenko, V; Rouvimov, S; Xing, H; Seabaugh, A; Haensch, W; Van de Walle, CG; Galazka, Z; Albrecht, M; Fornari, R; Jena, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hwang, Wan Sik; Verma, Amit; Peelaers, Hartwin; Protasenko, Vladimir; Rouvimov, Sergei; Xing, Huili (Grace); Seabaugh, Alan; Haensch, Wilfried; Van de Walle, Chris G.; Galazka, Zbigniew; Albrecht, Martin; Fornari, Roberto; Jena, Debdeep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-voltage field effect transistors with wide-bandgap β-Ga2O3 nullomembranes", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloscale semiconductor materials have been extensively investigated as the channel materials of transistors for energy-efficient low-power logic switches to enable scaling to smaller dimensions. On the opposite end of transistor applications is power electronics for which transistors capable of switching very high voltages are necessary. Miniaturization of energy-efficient power switches can enable the integration with various electronic systems and lead to substantial boosts in energy efficiency. nullotechnology is yet to have an impact in this arena. In this work, it is demonstrated that nullomembranes of the wide-bandgap semiconductor gallium oxide can be used as channels of transistors capable of switching high voltages, and at the same time can be integrated on any platform. The findings mark a step towards using lessons learnt in nullomaterials and nullotechnology to address a challenge that yet remains untouched by the field. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2014, "Volume": 104, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 203111, "DOI": "10.1063/1.4879800", "DOI Link": "http://dx.doi.org/10.1063/1.4879800", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337140800064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fukamachi, S; Solis-Fernández, P; Kawahara, K; Tanaka, D; Otake, T; Lin, YC; Suenaga, K; Ago, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fukamachi, Satoru; Solis-Fernulldez, Pablo; Kawahara, Kenji; Tanaka, Daichi; Otake, Toru; Lin, Yung-Chang; Suenaga, Kazu; Ago, Hiroki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-area synthesis and transfer of multilayer hexagonal boron nitride for enhanced graphene device arrays", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multilayer hexagonal boron nitride (hBN) can be used to preserve the intrinsic physical properties of other two-dimensional materials in device structures. However, integrating the material into large-scale two-dimensional heterostructures remains challenging due to the difficulties in synthesizing high-quality large-area multilayer hBN and combining it with other two-dimensional material layers of the same scale. Here we show that centimetre-scale multilayer hBN can be synthesized on iron-nickel alloy foil by chemical vapour deposition, and then used as a substrate and as a surface-protecting layer in graphene field-effect transistors. We also develop an integrated electrochemical transfer and thermal treatment method that allows us to create high-performance graphene/hBN heterostacks. Arrays of graphene field-effect transistors fabricated by conventional and scalable methods show an enhancement in room-temperature carrier mobility when hBN is used as an insulating substrate, and a further increase-up to a value of 10,000 cm(2) V-1 s(-1)-when graphene is encapsulated with another hBN sheet. Multilayers of hexagonal boron nitride can be grown using a chemical vapour deposition process on iron-nickel foil and integrated into a large array of graphene devices that exhibit room-temperature carrier mobilities of up to around 10,000 cm(2) V-1 s(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 126, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41928-022-00911-x", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00911-x", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926319900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kyobula, M; Adedeji, A; Alexander, MR; Saleh, E; Wildman, R; Ashcroft, I; Gellert, PR; Roberts, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kyobula, Mary; Adedeji, Aremu; Alexander, Morgan R.; Saleh, Ehab; Wildman, Ricky; Ashcroft, Ian; Gellert, Paul R.; Roberts, Clive J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D inkjet printing of tablets exploiting bespoke complex geometries for controlled and tuneable drug release", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A hot melt 3D inkjet printing method with the potential to manufacture formulations in complex and adaptable geometries for the controlled loading and release of medicines is presented. This first use of a precisely controlled solvent free inkjet printing to produce drug loaded solid dosage forms is demonstrated using a naturally derived FDA approved material (beeswax) as the drug carrier and fenofibrate as the drug. Tablets with bespoke geometries (honeycomb architecture) were fabricated. The honeycomb architecture was modified by control of the honeycomb cell size, and hence surface area to enable control of drug release profiles without the need to alter the formulation. Analysis of the formed tablets showed the drug to be evenly distributed within the beeswax at the bulk scale with evidence of some localization at the micron scale. An analytical model utilizing a Fickian description of diffusion was developed to allow the prediction of drug release. A comparison of experimental and predicted drug release data revealed that in addition to surface area, other factors such as the cell diameter in the case of the honeycomb geometry and material wettability must be considered in practical dosage form design. This information when combined with the range of achievable geometries could allow the bespoke production of optimized personalised medicines for a variety of delivery vehicles in addition to tablets, such as medical devices for example.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 10", "Publication Year": 2017, "Volume": 261, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 207, "End Page": 215, "Article Number": null, "DOI": "10.1016/j.jconrel.2017.06.025", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2017.06.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406860400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lazouski, N; Schiffer, ZJ; Williams, K; Manthiram, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lazouski, Nikifar; Schiffer, Zachary J.; Williams, Kindle; Manthiram, Karthish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia is a large-scale commodity chemical that is crucial for producing nitrogen-containing fertilizers. Electrochemical methods have been proposed as renewable and distributed alternatives to the incumbent Haber-Bosch process, which utilizes fossil fuels for ammonia production. Herein, we report a mechanistic study of lithium-mediated electrochemical nitrogen reduction to ammonia in a non-aqueous system. The rate laws of the main reactions in the system were determined. At high current densities, nitrogen transport limitations begin to affect the nitrogen reduction process. Based on these observations, we developed a coupled kinetic-transport model of the process, which we used to optimize operating conditions for ammonia production. The highest Faradaic efficiency observed was 18.5% +/- 2.9%, while the highest production rate obtained was (7.9 +/- 1.6) x 10(-9) mol cm(-2) s(-1). Our understanding of the reaction network and the influence of transport provides foundational knowledge for future improvements in continuous lithium-mediated ammonia synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1127, "End Page": 1139, "Article Number": null, "DOI": "10.1016/j.joule.2019.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.02.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465149000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, KL; Li, J; Wang, HB; Lu, RH; Yang, XT; Luo, MC; Wang, N; Wang, ZY; Liu, CX; Jing, T; Chen, SH; Cortes, E; Maier, SA; Zhang, S; Li, TL; Yu, YF; Liu, YC; Kang, XC; Liang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Kaili; Li, Jun; Wang, Haibin; Lu, Ruihu; Yang, Xiaotao; Luo, Mingchuan; Wang, Ning; Wang, Ziyun; Liu, Changxu; Jing, Tan; Chen, Songhua; Cortes, Emiliano; Maier, Stefan A.; Zhang, Sheng; Li, Tieliang; Yu, Yifu; Liu, Yongchang; Kang, Xinchen; Liang, Hongyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanistic Insights into OC-COH Coupling in CO2 Electroreduction on Fragmented Copper", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The carbon-carbon (C-C) bond formation is essential for the electroconversion of CO2 into high-energy-density C2+ products, and the precise coupling pathways remain controversial. Although recent computational investigations have proposed that the OC-COH coupling pathway is more favorable in specific reaction conditions than the well-known CO dimerization pathway, the experimental evidence is still lacking, partly due to the separated catalyst design and mechanistic/spectroscopic exploration. Here, we employ density functional theory calculations to show that on low-coordinated copper sites, the *CO bindings are strengthened, and the adsorbed *CO coupling with their hydrogenation species, *COH, receives precedence over CO dimerization. Experimentally, we construct a fragmented Cu catalyst with abundant low-coordinated sites, exhibiting a 77.8% Faradaic efficiency for C2+ products at 300 mA cm-2. With a suite of in situ spectroscopic studies, we capture an *OCCOH intermediate on the fragmented Cu surfaces, providing direct evidence to support the OC-COH coupling pathway. The mechanistic insights of this research elucidate how to design materials in favor of OC-COH coupling toward efficient C2+ production from CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 JUL 29", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c01044", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c01044", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837252300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, JF; Wang, GZ; Chang, XX; Yang, ZZ; Wang, H; Li, BY; Zhang, W; Kovarik, L; Du, YG; Orlovskaya, N; Xu, BJ; Wang, GF; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Jinfa; Wang, Guanzhi; Chang, Xiaoxia; Yang, Zhenzhong; Wang, Han; Li, Boyang; Zhang, Wei; Kovarik, Libor; Du, Yingge; Orlovskaya, Nina; Xu, Bingjun; Wang, Guofeng; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface synergism and engineering of Pd/Co@N-C for direct ethanol fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct ethanol fuel cells have been widely investigated as nontoxic and low-corrosive energy conversion devices with high energy and power densities. It is still challenging to develop high-activity and durable catalysts for a complete ethanol oxidation reaction on the anode and accelerated oxygen reduction reaction on the cathode. The materials' physics and chemistry at the catalytic interface play a vital role in determining the overall performance of the catalysts. Herein, we propose a Pd/Co@N-C catalyst that can be used as a model system to study the synergism and engineering at the solid-solid interface. Particularly, the transformation of amorphous carbon to highly graphitic carbon promoted by cobalt nulloparticles helps achieve the spatial confinement effect, which prevents structural degradation of the catalysts. The strong catalyst-support and electronic effects at the interface between palladium and Co@N-C endow the electron-deficient state of palladium, which enhances the electron transfer and improved activity/durability. The Pd/Co@N-C delivers a maximum power density of 438 mW cm(-2) in direct ethanol fuel cells and can be operated stably for more than 1000 hours. This work presents a strategy for the ingenious catalyst structural design that will promote the development of fuel cells and other sustainable energy-related technologies. It is challenging to develop high-activity and durable catalysts for both ethanol oxidation reaction on the anode and oxygen reduction reaction on the cathode. Here in this work, authors proposed Pd/Co@N-C catalyst as a model to synergistically maximize the usage of catalyst nulloparticles and active interfaces for direct ethanol fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1346, "DOI": "10.1038/s41467-023-37011-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37011-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001718000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shimazaki, Y; Yamamoto, M; Borzenets, IV; Watanabe, K; Taniguchi, T; Tarucha, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shimazaki, Y.; Yamamoto, M.; Borzenets, I. V.; Watanabe, K.; Taniguchi, T.; Tarucha, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generation and detection of pure valley current by electrically induced Berry curvature in bilayer graphene", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of 'Valleytronics' has recently been attracting growing interest as a promising concept for the next generation electronics, because non-dissipative pure valley currents with no accompanying net charge flow can be manipulated for computational use, akin to pure spin currents(1). Valley is a quantum number defined in an electronic system whose energy bands contain energetically degenerate but non-equivalent local minima (conduction band) or maxima (valence band) due to a certain crystal structure. Specifically, spatial inversion symmetry broken two-dimensional honeycomb lattice systems exhibiting Berry curvature is a subset of possible systems that enable optical(2-5), magnetic(6-9) and electrical control of the valley degree of freedom(10-12). Here we use dual-gated bilayer graphene to electrically induce and control broken inversion symmetry (or Berry curvature) as well as the carrier density for generating and detecting the pure valley current. In the insulating regime, at zero-magnetic field, we observe a large nonlocal resistance that scales cubically with the local resistivity, which is evidence of pure valley current.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1032, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3551", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3551", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365898400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Crockett, MP; Evans, AM; Worthington, MJH; Albuquerque, IS; Slattery, AD; Gibson, CT; Campbell, JA; Lewis, DA; Bernardes, GJL; Chalker, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Crockett, Michael P.; Evans, Austin M.; Worthington, Max J. H.; Albuquerque, Ines S.; Slattery, Ashley D.; Gibson, Christopher T.; Campbell, Jonathan A.; Lewis, David A.; Bernardes, Goncalo J. L.; Chalker, Justin M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-Limonene Polysulfide: A Material Synthesized Entirely from Industrial By-Products and Its Use in Removing Toxic Metals from Water and Soil", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A polysulfide material was synthesized by the direct reaction of sulfur and D-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2016, "Volume": 55, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1714, "End Page": 1718, "Article Number": null, "DOI": "10.1002/anie.201508708", "DOI Link": "http://dx.doi.org/10.1002/anie.201508708", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arif, ZU; Khalid, MY; Sheikh, MF; Zolfagharian, A; Bodaghi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arif, Zia Ullah; Khalid, Muhammad Yasir; Sheikh, Muhammad Fahad; Zolfagharian, Ali; Bodaghi, Mahdi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biopolymeric sustainable materials and their emerging applications", "Source Title": "JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advancements in polymer science and engineering have helped the scientific community to shift its attention towards the use of environmentally benign materials for reducing the environmental impact of conventional synthetic plastics. Biopolymers are environmentally benign, chemically versatile, sustainable, biocompatible, biodegradable, inherently functional, and ecofriendly materials that exhibit tremendous potential for a wide range of applications including food, electronics, agriculture, textile, biomedical, and cosmetics. This review also inspires the researchers toward more consumption of biopolymer-based composite materials as an alternative to synthetic composite materials. Herein, an overview of the latest knowledge of different natural- and syntheticbased biodegradable polymers and their fiber-reinforced composites is presented. The review discusses different degradation mechanisms of biopolymer-based composites as well as their sustainability aspects. This review also elucidates current challenges, future opportunities, and emerging applications of biopolymeric sustainable composites in numerous engineering fields. Finally, this review proposes biopolymeric sustainable materials as a propitious solution to the contemporary environmental crisis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108159, "DOI": "10.1016/j.jece.2022.108159", "DOI Link": "http://dx.doi.org/10.1016/j.jece.2022.108159", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827606400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nuckolls, KP; Oh, M; Wong, D; Lian, B; Watanabe, K; Taniguchi, T; Bernevig, BA; Yazdani, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nuckolls, Kevin P.; Oh, Myungchul; Wong, Dillon; Lian, Biao; Watanabe, Kenji; Taniguchi, Takashi; Bernevig, B. Andrei; Yazdani, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly correlated Chern insulators in magic-angle twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strong electron-electron interactions in magic-angle twisted bilayer graphene can fundamentally change the topology of the system's flat bands, producing a hierarchy of strongly correlated topological insulators in modest magnetic fields. Interactions between electrons and the topology of their energy bands can create unusual quantum phases of matter. Most topological electronic phases appear in systems with weak electron-electron interactions. The instances in which topological phases emerge only as a result of strong interactions are rare and mostly limited to those realized in intense magnetic fields(1). The discovery of flat electronic bands with topological character in magic-angle twisted bilayer graphene (MATBG) has created a unique opportunity to search for strongly correlated topological phases(2-9). Here we introduce a local spectroscopic technique using a scanning tunnelling microscope to detect a sequence of topological insulators in MATBG with Chern numbers C = +/- 1, +/- 2 and +/- 3, which form near filling factors of +/- 3, +/- 2 and +/- 1 electrons per moire unit cell, respectively, and are stabilized by modest magnetic fields. One of the phases detected here (C = +1) was previously observed when the sublattice symmetry of MATBG was intentionally broken by a hexagonal boron nitride substrate, with interactions having a secondary role(9). We demonstrate that strong electron-electron interactions alone can produce not only the previously observed phase, but also other unexpected Chern insulating phases in MATBG. The full sequence of phases that we observe can be understood by postulating that strong correlations favour breaking time-reversal symmetry to form Chern insulators that are stabilized by weak magnetic fields. Our findings illustrate that many-body correlations can create topological phases in moire systems beyond those anticipated from weakly interacting models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 24", "Publication Year": 2020, "Volume": 588, "Issue": 7839, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 610, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-3028-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-3028-8", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000598702800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barré, E; Karni, O; Liu, EF; O'Beirne, AL; Chen, XQ; Ribeiro, HB; Yu, L; Kim, B; Watanabe, K; Taniguchi, T; Barmak, K; Lui, CH; Refaely-Abramson, S; da Jornada, FH; Heinz, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barre, Elyse; Karni, Ouri; Liu, Erfu; O'Beirne, Aidan L.; Chen, Xueqi; Ribeiro, Henrique B.; Yu, Leo; Kim, Bumho; Watanabe, Kenji; Taniguchi, Takashi; Barmak, Katayun; Lui, Chun Hung; Refaely-Abramson, Sivan; da Jornada, Felipe H.; Heinz, Tony F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical absorption of interlayer excitons in transition-metal dichalcogenide heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interlayer excitons, electron-hole pairs bound across two monolayer van der Waals semiconductors, offer promising electrical tunability and localizability. Because such excitons display weak electron-hole overlap, most studies have examined only the lowest-energy excitons through photoluminescence. We directly measured the dielectric response of interlayer excitons, which we accessed using their static electric dipole moment. We thereby determined an intrinsic radiative lifetime of 0.40 nulloseconds for the lowest direct-gap interlayer exciton in a tungsten diselenide/molybdenum diselenide heterostructure. We found that differences in electric field and twist angle induced trends in exciton transition strengths and energies, which could be related to wave function overlap, moire confinement, and atomic reconstruction. Through comparison with photoluminescence spectra, this study identifies a momentum-indirect emission mechanism. Characterization of the absorption is key for applications relying on light-matter interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 22", "Publication Year": 2022, "Volume": 376, "Issue": 6591, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm8511", "DOI Link": "http://dx.doi.org/10.1126/science.abm8511", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788553700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uekert, T; Singh, A; DesVeaux, JS; Ghosh, T; Bhatt, A; Yadav, G; Afzal, S; Walzberg, J; Knauer, KM; Nicholson, SR; Beckham, GT; Carpenter, AC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uekert, Taylor; Singh, Avantika; DesVeaux, Jason S.; Ghosh, Tapajyoti; Bhatt, Arpit; Yadav, Geetanjali; Afzal, Shaik; Walzberg, Julien; Knauer, Katrina M.; Nicholson, Scott R.; Beckham, Gregg T.; Carpenter, Alberta C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Technical, Economic, and Environmental Comparison of Closed- Loop Recycling Technologies for Common Plastics", "Source Title": "ACS SUSTAINABLE CHEMISTRY & ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over 400 million metric tons of plastic waste are generated globally each year, resulting in pollution and lost resources. Recycling strategies can recapture this wasted material, but there is a lack of quantitative and transparent data on the capabilities and impacts of these processes. Here, we develop a data set of material quality, material retention, circularity, contamination tolerance, minimum selling price, greenhouse gas emissions, energy use, land use, toxicity, waste generation, and water use metrics for closed-loop polymer recycling technologies, including mechan-ical recycling and solvent-based dissolution of polyethylene, polyethylene terephthalate (PET), and polypropylene, as well as enzymatic hydrolysis, glycolysis, and vapor methanolysis of PET. Mechanical recycling and PET glycolysis display the best economic (9%-73% lower than competing technologies) and environmental (7%-88% lower) performances, while dissolution, enzymatic hydrolysis, and methanolysis provide the best recyclate material qualities (2%-27% higher). We identify electricity, steam, and organic solvents as top process contributors to these metrics and apply sensitivity and multicriteria decision analyses to highlight key future research areas. The estimates derived in this work provide a quantitative baseline for comparing and improving recycling technologies, can help reclaimers identify optimal end-of-life routes for given waste streams, and serve as a framework for assessing future innovations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2023, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 965, "End Page": 978, "Article Number": null, "DOI": "10.1021/acssuschemeng.2c05497", "DOI Link": "http://dx.doi.org/10.1021/acssuschemeng.2c05497", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918787700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nilimaa, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nilimaa, Jonny", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smart materials and technologies for sustainable concrete construction", "Source Title": "DEVELOPMENTS IN THE BUILT ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents a comprehensive review of current trends and opportunities for sustainable concrete construction, emphasizing the importance of adopting eco-friendly practices to mitigate the industry's environmental impact. Green concrete, supplementary cementitious materials, permeable concrete, cool concrete, and the use of local materials are explored as sustainable materials and technologies. Innovations like self-healing concrete, 3D-printed concrete, photocatalytic concrete, electrified machineries, and carbon capture, utilization, and storage principles are also discussed, highlighting their potential to improve the sustainability of construction practices. Challenges faced in implementing sustainable concrete construction practices, such as technical, economic, and social barriers, are also addressed. The roles of governments, industry, and academia in promoting sustainable concrete construction are examined, stressing the need for interdisciplinary collaboration and research. Lastly, emerging trends and technologies, including digitalization, data-driven approaches, and circular economy principles, are identified as critical factors in driving the transition towards sustainable concrete construction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 15, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100177, "DOI": "10.1016/j.dibe.2023.100177", "DOI Link": "http://dx.doi.org/10.1016/j.dibe.2023.100177", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001144188500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, WH; Pang, R; Wang, SW; Tan, T; Li, CY; Wang, CW; Zhang, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Weihong; Pang, Ran; Wang, Shangwei; Tan, Tao; Li, Chengyu; Wang, Chaowei; Zhang, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced blue-light excited cyan-emitting persistent luminescence of BaLu2Al2Ga2SiO12:Ce3+, Bi3+ phosphors for AC-LEDs via defect modulation", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alternating current light-emitting diodes (AC-LEDs) have received significant attention from both academia and industry due to their remarkable benefits of more compact volume, cheaper manufacturing cost, greater energy usage efficiency, and longer service life. One of the most significant challenges for AC-LEDs is the flicker effect, which is mainly caused by the unavoidable 5-20 ms dimming time. Aiming to reduce the flicker effect, we designed a series of excellent blue-light excited cyan-emitting persistent luminescence (PersL) phosphors BaLu2Al2Ga2SiO12:Ce3+, Bi3+ via defect engineering of co-doping Bi3+. Interestingly, we found that co-doping Bi3+ not only effectively enhanced the PersL intensity, but also regulated the PersL lifetime of this phosphors. As the Bi3+ co-doping concentration increases to 0.01, the T80 value (the time when the PersL intensity decreases to 80% of the initial intensity) increases from 0.24 to 19.61 ms, which proves to be effective in compensating the flicker effect of AC-LEDs. A new method of generating white light emission during the dimming time through adding the blue-light excited cyan PersL phosphor to the original orange-red PersL phosphor was proposed and an AC-LED lamp with a decreased percent flicker of 48.15% was fabricated, which is significantly better than the other currently reported AC-LED devices based on PersL phosphors. These results demonstrate that BaLu2Al2Ga2SiO12:Ce3+, Bi3+ might be an attractive material for low-flicker AC-LEDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 184, "DOI": "10.1038/s41377-022-00868-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00868-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000812512500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smejkal, L; González-Hernández, R; Jungwirth, T; Sinova, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smejkal, Libor; Gonzalez-Hernulldez, Rafael; Jungwirth, T.; Sinova, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal time-reversal symmetry breaking and spontaneous Hall effect in collinear antiferromagnets", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrons, commonly moving along the applied electric field, acquire in certain magnets a dissipationless transverse velocity. This spontaneous Hall effect, found more than a century ago, has been understood in terms of the time-reversal symmetry breaking by the internal spin structure of a ferromagnetic, noncolinear anti-ferromagnetic, or skyrmionic form. Here, we identify previously overlooked robust Hall effect mechanism arising from collinear antiferromagnetism combined with nonmagnetic atoms at noncentrosymmetric positions. We predict a large magnitude of this crystal Hall effect in a room temperature collinear antiferromagnet RuO2 and catalog, based on symmetry rules, extensive families of material candidates. We show that the crystal Hall effect is accompanied by the possibility to control its sign by the crystal chirality. We illustrate that accounting for the full magnetization density distribution instead of the simplified spin structure sheds new light on symmetry breaking phenomena in magnets and opens an alternative avenue toward low-dissipation nulloelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz8809", "DOI": "10.1126/sciadv.aaz8809", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz8809", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540787200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Carlos, C; Zhou, H; Sui, JJ; Wang, YK; Silva-Pedraza, Z; Yang, F; Dong, YT; Zhang, ZY; Hacker, TA; Liu, B; Mao, YC; Wang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jun; Carlos, Corey; Zhou, Hao; Sui, Jiajie; Wang, Yikai; Silva-Pedraza, Zulmari; Yang, Fan; Dong, Yutao; Zhang, Ziyi; Hacker, Timothy A.; Liu, Bo; Mao, Yanchao; Wang, Xudong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stretchable piezoelectric biocrystal thin films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchability is an essential property for wearable devices to match varying strains when interfacing with soft tissues or organs. While piezoelectricity has broad application potentials as tactile sensors, artificial skins, or nullogenerators, enabling tissue-comparable stretchability is a main roadblock due to the intrinsic rigidity and hardness of the crystalline phase. Here, an amino acid-based piezoelectric biocrystal thin film that offers tissue-compatible omnidirectional stretchability with unimpaired piezoelectricity is reported. The stretchability was enabled by a truss-like microstructure that was self-assembled under controlled molecule-solvent interaction and interface tension. Through the open and close of truss meshes, this large scale biocrystal microstructure was able to endure up to 40% tensile strain along different directions while retained both structural integrity and piezoelectric performance. Built on this structure, a tissue-compatible stretchable piezoelectric nullogenerator was developed, which could conform to various tissue surfaces, and exhibited stable functions under multidimensional large strains. In this work, we presented a promising solution that integrates piezoelectricity, stretchability and biocompatibility in one material system, a critical step toward tissue-compatible biomedical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6562, "DOI": "10.1038/s41467-023-42184-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42184-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001086900900019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, Y; Yang, XX; Wang, XY; Guan, ZJ; Xing, H; Fang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Yu; Yang, Xiaoxin; Wang, Xiaoyu; Guan, Zong-Jie; Xing, Hang; Fang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A cage-on-MOF strategy to coordinatively functionalize mesoporous MOFs for manipulating selectivity in adsorption and catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functionalizing porous materials with capping agents generates hybrid materials with enhanced properties, while the challenge is how to improve the selectivity and maintain the porosity of the parent framework. Herein, we developed a Cage-on-MOF strategy to tune the recognition and catalytic properties of MOFs without impairing their porosity. Two types of porous coordination cages (PCCs) of opposite charges containing secondary binding groups were developed to coordinatively functionalize two distinct porous MOFs, namely MOF@PCC nullocomposites. We demonstrated that the surface-capped PCCs can act as modulators to effectively tune the surface charge, stability, and adsorption behavior of different host MOF particles. More importantly, the MOF@PCCs can serve as selective heterogeneous catalysts for condensation reactions to achieve reversed product selectivity and excellent recyclability. This work sets the foundation for using molecular cages as porous surface-capping agents to functionalize and manipulate another porous material, without affecting the intrinsic properties of the parent framework. Functionalising porous materials is a route to enhancing properties of hybrid materials. Here authors present a Cage-on-MOF strategy to modify the surface of mesoporous MOFs by using molecular cages to achieve selective dyes adsorption behavior and heterogeneous catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5223, "DOI": "10.1038/s41467-023-40973-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40973-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001064563400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lase, IS; Tonini, D; Caro, D; Albizzati, PF; Cristobal, J; Roosen, M; Kusenberg, M; Ragaert, K; Van Geem, KM; Dewulf, J; De Meester, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lase, Irdanto Saputra; Tonini, Davide; Caro, Dario; Albizzati, Paola F.; Cristobal, Jorge; Roosen, Martijn; Kusenberg, Marvin; Ragaert, Kim; Van Geem, Kevin M.; Dewulf, Jo; De Meester, Steven", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How much can chemical recycling contribute to plastic waste recycling in Europe? An assessment using material flow analysis modeling", "Source Title": "RESOURCES CONSERVATION AND RECYCLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic recycling rate in Europe is low, urging developments in recycling technology and strategies to increase circularity. Mechanical recycling (MR) has been the reference recycling technology for years, but in the near future chemical recycling (CR) options are expected to contribute to improve plastic circularity. This study uses a material flow analysis (MFA) at European level to provide quantitative estimates of the contribution of CR technologies to plastic recycling. Ten most used polymer types from five sectors are selected. A status quo 2018 scenario is modelled and compared to five potential future scenarios (in 2030) of plastic waste treatment, including one that only looks at improved waste collection, sorting, and MR technologies and four exploring developments of CR options. The so-called 'missing plastics', i.e., plastic waste generated but currently not accounted for in statistics, is considered in one of the future scenarios. The MFA results are compared by calculating four circularity indicators namely end-of-life recycling rate (EoL-RR), plastic-to-plastic rate, plasticto-chemicals rate, and plastic-to-fuels rate. The results indicate that in the most optimistic scenario the EoL-RR in 2030 is 73-80% (sum of plastic-to-plastic and plastic-to-chemical rates, excluding plastic-to-fuel rate), in which 41-46% is plastic-to-plastic from MR, 15-38% is plastic-to-plastic from CR and 19-35% is plastic-to-chemicals. The highest achievable plastic-to-plastic rate is estimated to be 61% (46% from MR and 15% from CR). In all future scenarios, the plastic-to-fuel rate is estimated to be 3-6%. The MFA results are also used to estimate potential recycled content availability in 2030, which suggest that closed-loop recycling and processing the 'missing plastics' will be necessary to achieve the targets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106916, "DOI": "10.1016/j.resconrec.2023.106916", "DOI Link": "http://dx.doi.org/10.1016/j.resconrec.2023.106916", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001010640600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JT; Liu, YW; Lin, JH; Su, JT; Redshaw, C; Feng, X; Min, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jintao; Liu, Yiwei; Lin, Jiahui; Su, Jingtao; Redshaw, Carl; Feng, Xing; Min, Yonggang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Novel pyrene-based aggregation-induced emission luminogen (AIEgen) composite phase change fibers with satisfactory fluorescence anti-counterfeiting, temperature sensing, and high-temperature warning functions for solar-thermal energy storage", "Source Title": "ADVANCED COMPOSITES AND HYBRID MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced multifunctional composite materials have been a significant force in the advancement of efficient solar-thermal energy conversion and storage, which is critical to address current energy shortage problems. In this study, novel phase change material (PCM) composite fiber films, composed of Py-CH (one novel pyrene-based aggregation-induced emission luminogen (AIEgen))/polyvinyl pyrrolidone (PVP)/polyethylene glycol (PEG), have been produced by electrospinning technology with PEG as the phase change material. The combination of AIE and twist intermolecular charge transfer (TICT) characteristics of Py-CH together with the water absorption performance of PVP afforded a temperature-dependent fluorescence change. On increasing the temperature from 30 to 160 degrees C, the APP (pyrene-based AIEgen/PVP/PEG) composites exhibit a blue-shifted emission with a color changed from green-yellow to cyan, from cyan to blue, and finally, to purple. Furthermore, the entanglement of the macromolecular chains and distinctive porous structure between PVP and PEG played a significant role in preventing the leakage and transfer issues of PEG. Therefore, the composite fiber films with a PEG content of 60% exhibited latent heat in the range of 79 similar to 89 J/g and were extremely stable for up to 100 heating-cooling cycles. As a result, the application of these APP composites could be further promoted to solar energy conversation and storage, high-temperature warning, and anti-counterfeiting applications. Hence, composite materials containing the pyrene-based AIEgen and phase change materials have opened up new avenues for the possible application of such materials in thermal energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126, "DOI": "10.1007/s42114-023-00706-4", "DOI Link": "http://dx.doi.org/10.1007/s42114-023-00706-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001012593200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dohi, T; DuttaGupta, S; Fukami, S; Ohno, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dohi, Takaaki; DuttaGupta, Samik; Fukami, Shunsuke; Ohno, Hideo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation and current-induced motion of synthetic antiferromagnetic skyrmion bubbles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skyrmion, a topologically-protected soliton, is known to emerge via electron spin in various magnetic materials. The magnetic skyrmion can be driven by low current density and has a potential to be stabilized in nulloscale, offering new directions of spintronics. However, there remain some fundamental issues in widely-studied ferromagnetic systems, which include a difficulty to realize stable ultrasmall skyrmions at room temperature, presence of the skyrmion Hall effect, and limitation of velocity owing to the topological charge. Here we show skyrmion bubbles in a synthetic antiferromagnetic coupled multilayer that are free from the above issues. Additive Dzyaloshinskii-Moriya interaction and spin-orbit torque (SOT) of the tailored stack allow stable skyrmion bubbles at room temperature, significantly smaller threshold current density or higher speed for motion, and negligible skyrmion Hall effect, with a potential to be scaled down to nullometer dimensions. The results offer a promising pathway toward nulloscale and energy-efficient skyrmion-based devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5153, "DOI": "10.1038/s41467-019-13182-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13182-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496409800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, CQ; Kang, MC; Lee, SH; Kwon, SJ; Cha, HW; Yang, CW; Park, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Chunqing; Kang, Min-Chul; Lee, Sun-Ho; Kwon, Seok Joon; Cha, Hyun-Woo; Yang, Cheol-Woong; Park, Nam-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photovoltaically top-performing perovskite crystal facets", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discovering the top-performing facets of perovskite crystals holds the secret to highly efficient perovskite solar cells (PSCs). However, the dominated facet properties of perovskite (i.e., (100), (110), (111) facets) remain elusive. Here, we demonstrate that exquisite control of the perovskite film formation enables the formation of perovskite polyhedral single crystals with well-defined facets. It is found that facets with variant densities and symmetries of atoms govern the perovskite surface chemical and electronic environment and generate significant effects on the photovoltaic performance. Car-rier mobility and photocurrent of the (100) crystal facet are almost comparable with those of the (111) facets, which are much higher than those of the (110) one. With the single-crystal-assembled perovskite thin film, the PSC achieves a quasi-steady-state (QSS) ef-ficiency of 24.64% with improved stability to light. Our work pro-vides a deep understanding of the optoelectronic properties of halide facets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2022, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2626, "End Page": 2643, "Article Number": null, "DOI": "10.1016/j.joule.2022.09.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.09.012", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000901852600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, SH; Zheng, JM; Li, QY; Li, X; Engelhard, MH; Cao, RG; Zhang, JG; Xu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Shuhong; Zheng, Jianming; Li, Qiuyan; Li, Xing; Engelhard, Mark H.; Cao, Ruiguo; Zhang, Ji-Guang; Xu, Wu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Behavior of Lithium Metal Anodes under Various Capacity Utilization and High Current Density in Lithium Metal Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium (Li) metal batteries (LMBs) have recently attracted extensive interest in the energy-storage field after silence from the public view for several decades. However, many challenges still need to be overcome before their practical application, especially those that are related to the interfacial instability of Li metal anodes. Here, we reveal for the first time that the thickness of the degradation layer on the metallic Li anode surface shows a linear relationship with Li areal capacity utilization up to 4.0 mAh cm(-2) in a practical LMB system. The increase in Li capacity utilization in each cycle causes variations in the morphology and composition of the degradation layer on the Li anode. Under high Li capacity utilization, the current density for charge (i.e., Li deposition) is identified to be a key factor controlling the corrosion of the Li metal anode. These fundamental findings provide new perspectives for the development of rechargeable LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2018, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 110, "End Page": 124, "Article Number": null, "DOI": "10.1016/j.joule.2017.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425303800013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Leo, V; Maurelli, AM; Giotta, L; Catucci, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Leo, Vincenzo; Maurelli, Anna Maria; Giotta, Livia; Catucci, Lucia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liposomes containing nulloparticles: preparation and applications", "Source Title": "COLLOIDS AND SURFACES B-BIOINTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The impetuous development of nullotechnology over the past two decades has enabled the production of a plethora of nullomaterials with outstanding optical, magnetic, electrical, catalytic and mechanical properties. The versatility of these materials attracted attention from the very beginning in the most disparate sectors of science and technology. The application of nullomaterials in the biological and biomedical fields soon benefited from the interaction with liposomes, which increased their biocompatibility and biostability. Liposomes indeed are versatile self-assembling supramolecular (nullo)structures constituted of an aqueous core enclosed by a lipid bilayer, able to host hydrophobic and hydrophilic cargo, and with superior biocompatibility and great similarity with the biological membranes. The result is the construction of hybrid nulloscale architectures, in which nulloparticles (NPs) are allocated either in the aqueous core, in the palisade of the lipid bilayer or on the outer surface of the vesicles. In the first part of this review, the principal methods for the preparation of NP-loaded liposomes are carefully illustrated in a tutorial manner. In the second part, an overview of the great potentialities deriving from the conjugation of liposomes with NPs is presented. In each paragraph, the main characteristics of the most notable classes of NPs, the related issues, and the advantages arising from their association with liposomes are shown. Here, the most significant research works in literature for each kind of system are presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 218, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112737, "DOI": "10.1016/j.colsurfb.2022.112737", "DOI Link": "http://dx.doi.org/10.1016/j.colsurfb.2022.112737", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000864479000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, SY; Qin, MB; Duan, JY; Wu, F; Liu, TT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Shuyuan; Qin, Meibao; Duan, Junyi; Wu, Feng; Liu, Tingting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polarization-controlled dynamically switchable high-harmonic generation from all-dielectric metasurfaces governed by dual bound states in the continuum", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tailoring optical nonlinear effects (e.g., harmonic generation, sum-frequency mixing, etc.) in the recently emerging all-dielectric platform is important for both fundamental science and industrial development of high efficiency, ultrafast, and miniaturized photonic devices. In this paper, we propose a method for the dynamically switchable high-harmonic generation in silicon nullodimer metasurfaces by exploiting the polarization-controlled dual bound states in the continuum (BIC). Owing to the high-quality factor of BIC resonullces, efficient harmonic signals including the third-harmonic generation and fifth-harmonic generation from a direct process as well as a cascaded process by degenerate four-wave mixing are obtained. Moreover, the BIC and their resonulltly enhanced harmonics can be switched on or off with high selectivity with respect to the fundamental pump polarization. Compared with previous reports, our paper provides a simple but effective tuning strategy by fully exploring the structural symmetry and polarization degree of freedom rather than resorting to additional external stimuli, which would possess great advantages in designing tunable and switchable nonlinear light sources for chip-scale applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2022, "Volume": 105, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 195440, "DOI": "10.1103/PhysRevB.105.195440", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.105.195440", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809498100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, C; Si, GF; Chen, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Chen; Si, Guifu; Chen, Changle", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general strategy for heterogenizing olefin polymerization catalysts and the synthesis of polyolefins and composites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The heterogenization of homogeneous metal complexes on solid supports has a series of drawbacks that restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. Here the authors show an ionic anchoring support strategy that is highly versatile, generally applicable to different systems, and enables strong catalyst-support interactions while tolerating various polar functional groups. The heterogenization of homogeneous metal complexes on solid supports presents an efficient strategy for bridging homogeneous catalysts with industrially-preferred heterogeneous catalysts; however, a series of drawbacks restrict their implementation in olefin polymerization, particularly for copolymerization with polar comonomers. In this contribution, we report an ionic anchoring strategy that is highly versatile, generally applicable to different systems, and enables strong catalyst-support interactions while tolerating various polar functional groups. In addition to greatly enhanced polymerization properties, the supported catalysts achieved higher comonomer incorporation than their unsupported counterparts. This strategy enabled efficient polymerization at high temperatures at large scale and great control over product morphology, and the facile synthesis of polyolefin composites. More importantly, the dispersion of different fillers in the polyolefin matrix produced great material properties even at low composite loadings. It is expected that this strategy will find applications in different catalytic systems and the synthesis of advanced engineering materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1954, "DOI": "10.1038/s41467-022-29533-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29533-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000782204100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sibhatu, AK; Weldegebrieal, GK; Sagadevan, S; Tran, NN; Hessel, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sibhatu, Assefu Kassegn; Weldegebrieal, Getu Kassegn; Sagadevan, Suresh; Tran, Nam Nghiep; Hessel, Volker", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic activity of CuO nulloparticles for organic and inorganic pollutants removal in wastewater remediation", "Source Title": "CHEMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous photocatalysis is a promising technology for eradicating organic, inorganic, and microbial pollutants in water and wastewater remediation. It is a more preferable method to other conventional wastewater treatment approaches on account of its low cost, environmental benignity, ability to proceed at ambient temperature and pressure conditions, and capability to completely degrade pollutants under appropriate conditions into environmentally safe products. In heterogeneous photocatalysis, pollutant removal is mainly induced by in-situ generated reactive radicals and their subsequent attack when energetic radiation impinges on the semiconductor catalyst. As such, for the effective and economical removal of wastewater pollutants, the employed catalyst should have high photonic efficiency, less toxic, abundant, chemically and photochemically stableand visible light active. Copper (II) oxide (CuO) is one among such promising compounds and its photocatalytic performance has been hampered primarily by rapid recombination and slow mobility of photogenerated charge carriers. So, this review provides an overview of the strategies adopted to mitigate the aforementioned drawbacks and also other operational parameters to boost its catalytic activity towards the elimination of toxic organic and inorganic metal ion contaminullts in an aqueous media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 300, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134623, "DOI": "10.1016/j.chemosphere.2022.134623", "DOI Link": "http://dx.doi.org/10.1016/j.chemosphere.2022.134623", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874490700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, AQ; Chen, W; Rasmussen, KD; Zhu, XH; Lundhaug, M; Müller, DB; Tan, J; Keiding, JK; Liu, LT; Dai, T; Wang, AJ; Liu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Anqi; Chen, Wu; Rasmussen, Kasper Dalgas; Zhu, Xuehong; Lundhaug, Maren; Muller, Daniel B.; Tan, Juan; Keiding, Jakob K.; Liu, Litao; Dai, Tao; Wang, Anjian; Liu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Battery technology and recycling alone will not save the electric mobility transition from future cobalt shortages", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, increasing attention has been given to the potential supply risks of critical battery materials, such as cobalt, for electric mobility transitions. While battery technology and recycling advancement are two widely acknowledged strategies for addressing such supply risks, the extent to which they will relieve global and regional cobalt demand-supply imbalance remains poorly understood. Here, we address this gap by simulating historical (1998-2019) and future (2020-2050) global cobalt cycles covering both traditional and emerging end uses with regional resolution (China, the U.S., Japan, the EU, and the rest of the world). We show that cobalt-free batteries and recycling progress can indeed significantly alleviate long-term cobalt supply risks. However, the cobalt supply shortage appears inevitable in the short- to medium-term (during 2028-2033), even under the most technologically optimistic scenario. Our results reveal varying cobalt supply security levels by region and indicate the urgency of boosting primary cobalt supply to ensure global e-mobility ambitions. New study finds cobalt-free batteries and recycling progress can significantly alleviate long-term cobalt supply risks, however a cobalt supply shortage appears inevitable in the short- to medium-term, even under the most technologically optimistic scenario.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1341, "DOI": "10.1038/s41467-022-29022-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29022-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804856300031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fischer, D; Klapötke, TM; Stierstorfer, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fischer, Dennis; Klapoetke, Thomas M.; Stierstorfer, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "1,5-Di(nitramino)tetrazole: High Sensitivity and Superior Explosive Performance", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly energetic 1,5-di(nitramino) tetrazole and its salts were synthesized. The neutral compound is very sensitive and one of the most powerful non-nuclear explosives to date. Selected nitrogen-rich and metal salts were prepared. The potassium salt can be used as a sensitizer in place of tetracene. The obtained compounds were characterized by low-temperature X-ray diffraction, IR and Raman spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and DSC. Calculated energetic performances using the EXPLO5 code based on calculated (CBS-4M) heats of formation and X-ray densities support the high energetic performances of the 1,5-dinitraminotetrazolates as energetic materials. The sensitivities towards impact, friction, and electrostatic discharge were also explored.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2015, "Volume": 54, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10299, "End Page": 10302, "Article Number": null, "DOI": "10.1002/anie.201502919", "DOI Link": "http://dx.doi.org/10.1002/anie.201502919", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360216800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, ZH; Shen, C; Li, JF; Reit, E; Bachman, H; Socolar, JES; Cummer, SA; Huang, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Zhenhua; Shen, Chen; Li, Junfei; Reit, Eric; Bachman, Hunter; Socolar, Joshua E. S.; Cummer, Steven A.; Jun Huang, Tony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dispersion tuning and route reconfiguration of acoustic waves in valley topological phononic crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The valley degree of freedom in crystals offers great potential for manipulating classical waves, however, few studies have investigated valley states with complex wavenumbers, valley states in graded systems, or dispersion tuning for valley states. Here, we present tunable valley phononic crystals (PCs) composed of hybrid channel-cavity cells with three tunable parameters. Our PCs support valley states and Dirac cones with complex wavenumbers. They can be configured to form chirped valley PCs in which edge modes are slowed to zero group velocity states, where the energy at different frequencies accumulates at different designated locations. They enable multiple functionalities, including tuning of dispersion relations for valley states, robust routing of surface acoustic waves, and spatial modulation of group velocities. This work may spark future investigations of topological states with complex wavenumbers in other classical systems, further study of topological states in graded materials, and the development of acoustic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 762, "DOI": "10.1038/s41467-020-14553-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14553-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513504100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, K; Zhong, WK; Peng, F; Deng, WY; Shang, Y; Quan, HL; Qiu, H; Wang, C; Liu, F; Wu, HB; Li, N; Huang, F; Ying, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Kang; Zhong, Wenkai; Peng, Feng; Deng, Wanyuan; Shang, Ying; Quan, Huilei; Qiu, Hong; Wang, Cheng; Liu, Feng; Wu, Hongbin; Li, Ning; Huang, Fei; Ying, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mastering morphology of non-fullerene acceptors towards long-term stable organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energetic traps accumulation aroused by thermal stress is a critical issue in organic solar cells. Here, authors integrate a wide bandgap polymer and two non-fullerene acceptors with different thermal and morphological properties, realizing a promising efficiency of 18.26% and long device stability. Despite the rapid progress of organic solar cells based on non-fullerene acceptors, simultaneously achieving high power conversion efficiency and long-term stability for commercialization requires sustainable research effort. Here, we demonstrate stable devices by integrating a wide bandgap electron-donating polymer (namely PTzBI-dF) and two acceptors (namely L8BO and Y6) that feature similar structures yet different thermal and morphological properties. The organic solar cell based on PTzBI-dF:L8BO:Y6 could achieve a promising efficiency of 18.26% in the conventional device structure. In the inverted structure, excellent long-term thermal stability over 1400 h under 85 degrees C continuous heating is obtained. The improved performance can be ascribed to suppressed charge recombination along with appropriate charge transport. We find that the morphological features in terms of crystalline coherence length of fresh and aged films can be gradually regulated by the weight ratio of L8BO:Y6. Additionally, the occurrence of melting point decrease and reduced enthalpy in PTzBI-dF:L8BO:Y6 films could prohibit the amorphous phase to cluster, and consequently overcome the energetic traps accumulation aroused by thermal stress, which is a critical issue in high efficiency non-fullerene acceptors-based devices. This work provides insight into understanding non-fullerene acceptors-based organic solar cells for improved efficiency and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2688, "DOI": "10.1038/s41467-023-38306-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38306-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001546000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vergniory, MG; Wieder, BJ; Elcoro, L; Parkin, SSP; Felser, C; Bernevig, BA; Regnault, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vergniory, Maia G.; Wieder, Benjamin J.; Elcoro, Luis; Parkin, Stuart S. P.; Felser, Claudia; Bernevig, B. Andrei; Regnault, Nicolas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All topological bands of all nonmagnetic stoichiometric materials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological quantum chemistry and symmetry-based indicators have facilitated large-scale searches for materials with topological properties at the Fermi energy (E-F). We report the implementation of a publicly accessible catalog of stable and fragile topology in all of the bands both at and away from E-F in the 96,196 processable entries in the Inorganic Crystal Structure Database. Our calculations, which represent the completion of the symmetry-indicated band topology of known nonmagnetic materials, have enabled the discovery of repeat-topological and supertopological materials, including rhombohedral bismuth and Bi2Mg3. We find that 52.65% of all materials are topological at E-F, roughly two-thirds of bands across all materials exhibit symmetry-indicated stable topology, and 87.99% of all materials contain at least one stable or fragile topological band.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2022, "Volume": 376, "Issue": 6595, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 816, "End Page": "+", "Article Number": "eabg9094", "DOI": "10.1126/science.abg9094", "DOI Link": "http://dx.doi.org/10.1126/science.abg9094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798495000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, WH; Richter, MH; May, MM; Ohlmann, J; Lackner, D; Dimroth, F; Hannappel, T; Atwater, HA; Lewerenz, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Wen-Hui; Richter, Matthias H.; May, Matthias M.; Ohlmann, Jens; Lackner, David; Dimroth, Frank; Hannappel, Thomas; Atwater, Harry A.; Lewerenz, Hans-Joachim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithic Photoelectrochemical Device for Direct Water Splitting with 19% Efficiency", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient unassisted solar water splitting, a pathway to storable renewable energy in the form of chemical bonds, requires optimization of a photoelectrochemical device based on photovoltaic tandem heterojunctions. We report a monolithic photocathode device architecture that exhibits significantly reduced surface reflectivity, minimizing parasitic light absorption and reflection losses. A tailored multifunctional crystalline titania interphase layer acts as a corrosion protection layer, with favorable band alignment between the semiconductor conduction band and the energy level for water reduction, facilitating electron transport at the cathode electrolyte interface. It also provides a favorable substrate for adhesion of high-activity Rh catalyst nulloparticles. Under simulated AM 1.5G irradiation, solar-to-hydrogen efficiencies of 19.3 and 18.5% are obtained in acidic and neutral electrolytes, respectively. The system reaches a value of 0.85 of the theoretical limit for photoelectrochemical water splitting for the energy gap combination employed in the tandem-junction photoelectrode structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1795, "End Page": 1800, "Article Number": null, "DOI": "10.1021/acsenergylett.8b00920", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b00920", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441852800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, TJ; Jiang, YC; He, JW; Li, FM; Ding, Y; Chen, P; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tian-Jiao; Jiang, Yu-Chuan; He, Jia-Wei; Li, Fu-Min; Ding, Yu; Chen, Pei; Chen, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous palladium phosphide nullotubes for formic acid electrooxidation", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of an efficient catalyst for formic acid electrocatalytic oxidation reaction (FAEOR) is of great significance to accelerate the commercial application of direct formic acid fuel cells (DFAFC). Herein, palladium phosphide (PdxPy) porous nullotubes (PNTs) with different phosphide content (i.e., Pd3P and Pd5P2) are prepared by combining the self-template reduction method of dimethylglyoxime-Pd(II) complex nullorods and succedent phosphating treatment. During the reduction process, the self-removal of the template and the continual inside-outside Ostwald ripening phenomenon are responsible for the generation of the one-dimensional hollow and porous architecture. On the basis of the unique synthetic procedure and structural advantages, Pd3P PNTs with optimized phosphide content show outstanding electroactivity and stability for FAEOR. Importantly, the strong electronic effect between Pd and P promotes the direct pathway of FAEOR and inhibits the occurrence of the formic acid decomposition reaction, which effectively enhances the FAEOR electroactivity of Pd3P PNTs. In view of the facial synthesis, excellent electroactivity, high stability, and unordinary selectivity, Pd3P PNTs have the potential to be an efficient anode electrocatalyst for DFAFC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 283, "End Page": 293, "Article Number": null, "DOI": "10.1002/cey2.170", "DOI Link": "http://dx.doi.org/10.1002/cey2.170", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000741462100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JZ; Liu, FC; Sasase, M; Ienaga, K; Obata, Y; Yukawa, R; Horiba, K; Kumigashira, H; Okuma, S; Inoshita, T; Hosono, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jiazhen; Liu, Fucai; Sasase, Masato; Ienaga, Koichiro; Obata, Yukiko; Yukawa, Ryu; Horiba, Koji; Kumigashira, Hiroshi; Okuma, Satoshi; Inoshita, Takeshi; Hosono, Hideo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural van der Waals heterostructural single crystals with both magnetic and topological properties", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterostructures having both magnetism and topology are promising materials for the realization of exotic topological quantum states while challenging in synthesis and engineering. Here, we report natural magnetic van der Waals heterostructures of (MnBi2Te4)(m)(Bi2Te3)(n) that exhibit controllable magnetic properties while maintaining their topological surface states. The interlayer antiferromagnetic exchange coupling is gradually weakened as the separation of magnetic layers increases, and an anomalous Hall effect that is well coupled with magnetization and shows ferromagnetic hysteresis was observed below 5 K. The obtained homogeneous heterostructure with atomically sharp interface and intrinsic magnetic properties will be an ideal platform for studying the quantum anomalous Hall effect, axion insulator states, and the topological magnetoelectric effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaax9989", "DOI": "10.1126/sciadv.aax9989", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aax9989", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499736100087", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdolhosseinzadeh, S; Jiang, XT; Zhang, H; Qiu, JS; Zhang, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdolhosseinzadeh, Sina; Jiang, Xiantao; Zhang, Han; Qiu, Jieshan; Zhang, Chuanfang (John)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspectives on solution processing of two-dimensional MXenes", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the discovery of two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, research on these wonder 2D inorganic compounds has become increasingly intensified with their members quickly expanding. MXenes' state-of-the-art applications are heavily dependent on their processing strategies and manufacturing methods. Nevertheless, the solution processing of MXenes has not been comprehensively reviewed. This review summarizes progress regarding solution processing of MXenes over the past decade as well as outlines key perspectives for future scalable manufacturing strategies. Etching of MAX phases and delamination of MXene are briefly introduced. Rheological properties of MXene dispersions and wetting of the MXene inks, which are crucial for the achievement of high-resolution printing and homogeneous coating, are discussed in detail. We have discussed the ink formulation strategies and fine-tuning of the ink properties to match with that of the targeted substrates to yield efficient yet high-quality printed/coated films/structures. As such, we demonstrate a map of guidelines for solution-based processing of MXenes toward high-performance applications, such as electrochemical energy storage, conductive electrodes, electromagnetic interference shielding, and so on.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 48, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": 240, "Article Number": null, "DOI": "10.1016/j.mattod.2021.02.010", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.02.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000711197100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, TT; Song, ZD; Alexandradinata, A; Wen, HM; Fang, C; Lu, L; Fang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Tiantian; Song, Zhida; Alexandradinata, A.; Wen, Hongming; Fang, Chen; Lu, Ling; Fang, Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double-Weyl Phonons in Transition-Metal Monosilicides", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We employed ab initio calculations to identify a class of crystalline materials of A/Si (M = Fe, Co, Mil, Re, Ru) having double-Weyl points in both their acoustic and optical phonon spectra. They exhibit novel topological points termed spin-1 Weyl point at the Brillouin zone center and charge-2 Dirac point at the zone corner. The corresponding gapless surface phonon dispersions are two helicoidal sheets whose isofrequency contours form a single noncontractible loop in the surface Brillouin zone. In addition, the global structure of the surface bands can be analytically expressed as double-periodic Weierstrass elliptic functions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 120, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16401, "DOI": "10.1103/PhysRevLett.120.016401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.016401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419325000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HY; Liu, GB; Gong, P; Xu, XD; Yao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Hongyi; Liu, Gui-Bin; Gong, Pu; Xu, Xiaodong; Yao, Wang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac cones and Dirac saddle points of bright excitons in monolayer transition metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In monolayer transition metal dichalcogenides, tightly bound excitons have been discovered with a valley pseudospin optically addressable through polarization selection rules. Here, we show that this valley pseudospin is strongly coupled to the exciton centre-of-mass motion through electron-hole exchange. This coupling realizes a massless Dirac cone with chirality index I = 2 for excitons inside the light cone, that is, bright excitons. Under moderate strain, the I = 2 Dirac cone splits into two degenerate I = 1 Dirac cones, and saddle points with a linear Dirac spectrum emerge. After binding an extra electron, the charged exciton becomes a massive Dirac particle associated with a large valley Hall effect protected from intervalley scattering. Our results point to unique opportunities to study Dirac physics, with exciton's optical addressability at specifiable momentum, energy and pseudospin. The strain-tunable valley-orbit coupling also implies new structures of exciton condensates, new functionalities of excitonic circuits and mechanical control of valley pseudospin.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3876, "DOI": "10.1038/ncomms4876", "DOI Link": "http://dx.doi.org/10.1038/ncomms4876", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337503800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kite, SV; Kadam, AN; Sathe, DJ; Patil, S; Mali, SS; Hong, CK; Lee, SW; Garadkar, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kite, Sagar, V; Kadam, Abhijit nullaso; Sathe, Dattatraya J.; Patil, Satish; Mali, Sawanta S.; Hong, Chang Kook; Lee, Sang-Wha; Garadkar, Kalyanrao M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullostructured TiO2 Sensitized with MoS2 nulloflowers for Enhanced Photodegradation Efficiency toward Methyl Orange", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullostructured titanium dioxide (TiO2) has a potential platform for the removal of organic contaminullts, but it has some limitations. To overcome these limitations, we devised a promising strategy in the present work, the heterostructures of TiO2 sensitized by molybdenum disulfide (MoS2) nulloflowers synthesized by the mechanochemical route and utilized as an efficient photocatalyst for methyl orange (MO) degradation. The surface of TiO2 sensitized by MoS2 was comprehensively characterized by X-ray diffraction (XRD), Raman spectroscopy, Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), photoluminescence spectroscopy (PL), Brunauer-Emmett-Teller (BET) surface area, and thermogravimetric analysis (TGA). From XRD results, the optimized MoS2-TiO2 (5.0 wt %) nullocomposite showcases the lowest crystallite size of 14.79 nm than pristine TiO2 (20 nm). The FT-IR and XPS analyses of the MoS2-TiO2 nullocomposite exhibit the strong interaction between MoS2 and TiO2. The photocatalytic results show that sensitization of TiO2 by MoS2 drastically enhanced the photocatalytic activity of pristine TiO2. According to the obtained results, the optimal amount of MoS2 loading was assumed to be 5.0 wt %, which exhibited a 21% increment of MO photodegradation efficiency compared to pristine TiO2 under UV-vis light. The outline of the overall study describes the superior photocatalytic performance of 5.0 wt % MoS2-TiO2 nullocomposite which is ascribed to the delayed recombination by efficient charge transfer, high surface area, and elevated surface oxygen vacancies. The context of the obtained results designates that the sensitization of TiO2 with MoS2 is a very efficient nullomaterial for photocatalytic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2021, "Volume": 6, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17071, "End Page": 17085, "Article Number": null, "DOI": "10.1021/acsomega.1c02194", "DOI Link": "http://dx.doi.org/10.1021/acsomega.1c02194", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000671852300035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, L; Xie, WQ; Shu, HW; Yang, QF; Shen, BQ; Boes, A; Peters, JD; Jin, WR; Xiang, C; Liu, ST; Moille, G; Yu, SP; Wang, XJ; Srinivasan, K; Papp, SB; Vahala, K; Bowers, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Lin; Xie, Weiqiang; Shu, Haowen; Yang, Qi-Fan; Shen, Boqiang; Boes, Andreas; Peters, Jon D.; Jin, Warren; Xiang, Chao; Liu, Songtao; Moille, Gregory; Yu, Su-Peng; Wang, Xingjun; Srinivasan, Kartik; Papp, Scott B.; Vahala, Kerry; Bowers, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-efficient frequency comb generation in AlGaAs-on-insulator microresonators", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in nonlinear optics have revolutionized integrated photonics, providing on-chip solutions to a wide range of new applications. Currently, state of the art integrated nonlinear photonic devices are mainly based on dielectric material platforms, such as Si3N4 and SiO2. While semiconductor materials feature much higher nonlinear coefficients and convenience in active integration, they have suffered from high waveguide losses that prevent the realization of efficient nonlinear processes on-chip. Here, we challenge this status quo and demonstrate a low loss AlGaAs-on-insulator platform with anomalous dispersion and quality (Q) factors beyond 1.5 x 10(6). Such a high quality factor, combined with high nonlinear coefficient and small mode volume, enabled us to demonstrate a Kerr frequency comb threshold of only similar to 36 mu W in a resonator with a 1 THz free spectral range, similar to 100 times lower compared to that in previous semiconductor platforms. Moreover, combs with broad spans (>250 nm) have been generated with a pump power of similar to 300 mu W, which is lower than the threshold power of state-of the-art dielectric micro combs. A soliton-step transition has also been observed for the first time in an AlGaAs resonator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1331, "DOI": "10.1038/s41467-020-15005-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15005-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563525700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aukland, MH; Siauciulis, M; West, A; Perry, GJP; Procter, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aukland, Miles H.; Siauciulis, Mindaugas; West, Adam; Perry, Gregory J. P.; Procter, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-free photoredox-catalysed formal C-H/C-H coupling of arenes enabled by interrupted Pummerer activation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aryl-aryl cross-coupling constitutes one of the most widely used procedures for the synthesis of high-value materials that range from pharmaceuticals to organic electronics and conducting polymers. The assembly of (hetero)biaryl scaffolds generally requires multiple steps; coupling partners must be functionalized before the key bond-forming event is considered. The development of selective C-H arylation processes in arenes-which sidestep the need for prefunctionalized partners-is thus crucial for streamlining the construction of these key architectures. Here we report an expedient, one-pot assembly of (hetero)biaryl motifs using photocatalysis and two non-prefunctionalized arene partners. The approach is underpinned by the functionalization of a C-H bond in an arene coupling partner using the interrupted Pummerer reaction. A unique pairing of the organic photoredox catalyst and the intermediate dibenzothiophenium salts enables highly selective reduction in the presence of sensitive functionalities. The utility of the metal-free, one-pot strategy is exemplified by the synthesis of a bioactive natural product and the modification of complex molecules of societal importance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 163, "End Page": 169, "Article Number": null, "DOI": "10.1038/s41929-019-0415-3", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0415-3", "Book DOI": null, "Early Access Date": "JAN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508320900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XX; Yu, L; Wu, XQ; Hu, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaoxing; Yu, Lei; Wu, Xiaoqing; Hu, Weihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Sensing and Density Functional Theory Study of H2S and SOF2 Adsorption on Au-Modified Graphene", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A gas sensor is used to detect SF6 decomposed gases, which are related to insulation faults, to accurately assess the insulated status of electrical equipment. Graphene films (GrF) modified with Au nulloparticles are used as an adsorbent for the detection of H2S and SOF2, which are two characteristic products of SF6 decomposed gases. Sensing experiments are conducted at room temperature. Results demonstrate that Au-modified GrF yields opposite responses to the tested gases and is thus considered a promising material for developing H2S- and SOF2-selective sensors. The first-principles approach is applied to simulate the interaction between the gases and Au-modified GrF systems and to interpret experimental data. The observed opposite resistance responses can be attributed to the charge-transfer differences related to the interfacial interaction between the gases and systems. The density of states and Mulliken population analysis results confirm the apparent charge transfer in Au-modified GrF chemisorption, whereas the van der Waals effect dominates the pristine graphene adsorption systems. Calculation results can also explicate the significant SOF2 responses on Au-modified GrF. This work is important in graphene modulation and device design for selective detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1500101, "DOI": "10.1002/advs.201500101", "DOI Link": "http://dx.doi.org/10.1002/advs.201500101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369001800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Jiang, LW; Shi, BY; Ryan, KM; Wang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yuan; Jiang, Li-Wen; Shi, Bu-Yan; Ryan, Kevin M.; Wang, Jian-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Oxygen Evolution Reaction Enabled by Phosphorus Doping of the Fe Electronic Structure in Iron-Nickel Selenide nullosheets", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic structure of active sites is critically important for electrochemical reactions. Here, the authors report a facile approach to independently regulate the electronic structure of Fe in Ni0.75Fe0.25Se2 by P doping. The resulting electrode exhibits superior catalytic performance for the oxygen evolution reaction (OER) showing a low overpotential (238 mV at 100 mA cm(-2), 185 mV at 10 mA cm(-2)) and an impressive durability in an alkaline medium. Additionally, the mass activity of 328.19 A g(-1) and turnover frequency (TOF) of 0.18 s(-1) at an overpotential of 500 mV are obtained for PNi0.75Fe0.25Se2 which is much higher than that of Ni0.75Fe0.25Se2 and RuO2. This work presents a new strategy for the rational design of efficient electrocatalysts for OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 8, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101775, "DOI": "10.1002/advs.202101775", "DOI Link": "http://dx.doi.org/10.1002/advs.202101775", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677217200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, AY; Liu, YF; Qiu, JX; Ghosh, B; Trevisan, TV; Onishi, Y; Hu, CW; Qian, TM; Tien, HJ; Chen, SW; Huang, MQ; Bérubé, D; Li, HC; Tzschaschel, C; Dinh, T; Sun, Z; Ho, SC; Lien, SW; Singh, B; Watanabe, K; Taniguchi, T; Bell, DC; Lin, H; Chang, TR; Du, CR; Bansil, A; Fu, L; Ni, N; Orth, PP; Ma, Q; Xu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Anyuan; Liu, Yu-Fei; Qiu, Jian-Xiang; Ghosh, Barun; Trevisan, Thais V.; Onishi, Yugo; Hu, Chaowei; Qian, Tiema; Tien, Hung-Ju; Chen, Shao-Wen; Huang, Mengqi; Berube, Damien; Li, Houchen; Tzschaschel, Christian; Dinh, Thao; Sun, Zhe; Ho, Sheng-Chin; Lien, Shang-Wei; Singh, Bahadur; Watanabe, Kenji; Taniguchi, Takashi; Bell, David C.; Lin, Hsin; Chang, Tay-Rong; Du, Chunhui Rita; Bansil, Arun; Fu, Liang; Ni, Ni; Orth, Peter P.; Ma, Qiong; Xu, Su-Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum metric nonlinear Hall effect in a topological antiferromagnetic heterostructure", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum geometry in condensed-matter physics has two components: the real part quantum metric and the imaginary part Berry curvature. Whereas the effects of Berry curvature have been observed through phenomena such as the quantum Hall effect in two-dimensional electron gases and the anomalous Hall effect (AHE) in ferromagnets, the quantum metric has rarely been explored. Here, we report a nonlinear Hall effect induced by the quantum metric dipole by interfacing even-layered MnBi2Te4 with black phosphorus. The quantum metric nonlinear Hall effect switches direction upon reversing the antiferromagnetic (AFM) spins and exhibits distinct scaling that is independent of the scattering time. Our results open the door to discovering quantum metric responses predicted theoretically and pave the way for applications that bridge nonlinear electronics with AFM spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2023, "Volume": 381, "Issue": 6654, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 181, "End Page": 186, "Article Number": null, "DOI": "10.1126/science.adf1506", "DOI Link": "http://dx.doi.org/10.1126/science.adf1506", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058656200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Y; Zhou, TH; Jeurgens, LPH; Kong, X; Choi, JW; Coskun, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yan; Zhou, Tianhong; Jeurgens, Lars P. H.; Kong, Xian; Choi, Jang Wook; Coskun, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolytes play pivotal roles in the stabilization of Li metal surface and operation at high voltages. In particular, localized high -concen-tration electrolytes have outperformed state-of-the-art electrolytes due to their unique solvation structures. However, a direct correla-tion between solvation structure in LHCEs, in particular for weakly coordinated diluents, and SEI composition is not well understood, yet it is highly critical to realize high Coulombic efficiency (CE) beyond 99.5%. Here, a class of electrolyte based on bis(2,2,2-tri-fluoroethoxy)methane and 1,2-dimethoxyethane was introduced to regulate anion decomposition to achieve ultra-high Li2O content of 63% in the SEI along with a highly uniform phase distribution. These unique features enabled a record-high CE of 99.72% and proved the impact of homogeneously distributed high Li2O SEI. The related Li|LiNi0.8Co0.1Mn0.1O2 full cell with a negative/positive capacity ratio of 2.5 achieved 90% capacity retention after 200 cy-cles at 1 C and 80% retention after 596 cycles at 3 C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2023, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 682, "End Page": 697, "Article Number": null, "DOI": "10.1016/j.chempr.2022.12.005", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2022.12.005", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000962536700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Gao, K; Kan, YY; Zhang, M; Qiu, CQ; Zhu, L; Zhao, Z; Peng, XB; Feng, W; Qian, ZY; Gu, XD; Jen, AKY; Tang, BZ; Cao, Y; Zhang, YM; Liu, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zaiyu; Gao, Ke; Kan, Yuanyuan; Zhang, Ming; Qiu, Chaoqun; Zhu, Lei; Zhao, Zhe; Peng, Xiaobin; Feng, Wei; Qian, Zhiyuan; Gu, Xiaodan; Jen, Alex K-Y; Tang, Ben Zhong; Cao, Yong; Zhang, Yongming; Liu, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The coupling and competition of crystallization and phase separation, correlating thermodynamics and kinetics in OPV morphology and performances", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The active layer morphology transition of organic photovoltaics under non-equilibrium conditions are of vital importance in determining the device power conversion efficiency and stability; however, a general and unified picture on this issue has not been well addressed. Using combined in situ and ex situ morphology characterizations, morphological parameters relating to kinetics and thermodynamics of morphology evolution are extracted and studied in model systems under thermal annealing. The coupling and competition of crystallization and demixing are found to be critical in morphology evolution, phase purification and interfacial orientation. A unified model summarizing different phase diagrams and all possible kinetic routes is proposed. The current observations address the fundamental issues underlying the formation of the complex multi-length scale morphology in bulk heterojunction blends and provide useful morphology optimization guidelines for processing devices with higher efficiency and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 332, "DOI": "10.1038/s41467-020-20515-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20515-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662811900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tadano, T; Tsuneyuki, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tadano, Terumasa; Tsuneyuki, Shinji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-consistent phonon calculations of lattice dynamical properties in cubic SrTiO3 with first-principles anharmonic force constants", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an ab initio framework to calculate anharmonic phonon frequency and phonon lifetime that is applicable to severely anharmonic systems. We employ self-consistent phonon (SCPH) theory with microscopic anharmonic force constants, which are extracted from density functional calculations using the least absolute shrinkage and selection operator technique. We apply the method to the high-temperature phase of SrTiO3 and obtain well-defined phonon quasiparticles that are free from imaginary frequencies. Here we show that the anharmonic phonon frequency of the antiferrodistortive mode depends significantly on the system size near the critical temperature of the cubic-to-tetragonal phase transition. By applying perturbation theory to the SCPH result, phonon lifetimes are calculated for cubic SrTiO3, which are then employed to predict lattice thermal conductivity using the Boltzmann transport equation within the relaxation-time approximation. The presented methodology is efficient and accurate, paving the way toward a reliable description of thermodynamic, dynamic, and transport properties of systems with severe anharmonicity, including thermoelectric, ferroelectric, and superconducting materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2015, "Volume": 92, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 54301, "DOI": "10.1103/PhysRevB.92.054301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.054301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358925200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JX; Li, JT; Lu, RH; Yu, RH; Zhao, SY; Li, CB; Lv, L; Xia, LX; Chen, XB; Cai, WW; Meng, JS; Zhang, W; Pan, XL; Hong, XF; Dai, YH; Mao, Y; Li, J; Zhou, L; He, GJ; Pang, QQ; Zhao, Y; Xia, C; Wang, ZY; Dai, LM; Mai, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jiexin; Li, Jiantao; Lu, Ruihu; Yu, Ruohan; Zhao, Shiyong; Li, Chengbo; Lv, Lei; Xia, Lixue; Chen, Xingbao; Cai, Wenwei; Meng, Jiashen; Zhang, Wei; Pan, Xuelei; Hong, Xufeng; Dai, Yuhang; Mao, Yu; Li, Jiong; Zhou, Liang; He, Guanjie; Pang, Quanquan; Zhao, Yan; Xia, Chuan; Wang, Ziyun; Dai, Liming; Mai, Liqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface passivation for highly active, selective, stable, and scalable CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical conversion of CO2 to formic acid using Bismuth catalysts is one the most promising pathways for industrialization. However, it is still difficult to achieve high formic acid production at wide voltage intervals and industrial current densities because the Bi catalysts are often poisoned by oxygenated species. Herein, we report a Bi3S2 nullowire-ascorbic acid hybrid catalyst that simultaneously improves formic acid selectivity, activity, and stability at high applied voltages. Specifically, a more than 95% faraday efficiency was achieved for the formate formation over a wide potential range above 1.0 V and at ampere-level current densities. The observed excellent catalytic performance was attributable to a unique reconstruction mechanism to form more defective sites while the ascorbic acid layer further stabilized the defective sites by trapping the poisoning hydroxyl groups. When used in an all-solid-state reactor system, the newly developed catalyst achieved efficient production of pure formic acid over 120 hours at 50 mA cm(-2) (200 mA cell current). Achieving high pure formic acid production from CO2 electroconversion is of high interest yet challenging. Here the authors report vitamin C functionalized Bi3S2 nullowire catalyst to achieve selective, active, and stable formic acid production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4670, "DOI": "10.1038/s41467-023-40342-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40342-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042819400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, J; Wei, ZM; Li, FH; Zhang, JC; Zhang, Q; Zhou, J; Wang, WJ; Liu, YH; Zhang, Z; Su, XZ; Yang, RZ; Liu, W; Su, CL; Yang, HB; Huang, YQ; Zhai, YM; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Jie; Wei, Zhiming; Li, Fuhua; Zhang, Jincheng; Zhang, Qiao; Zhou, Jing; Wang, Weijue; Liu, Yuhang; Zhang, Zhen; Su, Xiaozhi; Yang, Runze; Liu, Wei; Su, Chenliang; Yang, Hong Bin; Huang, Yanqiang; Zhai, Yueming; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, via engineering the conformation of cobalt active center in cobalt phthalocyanine molecular catalyst, the catalytic efficiency of electrochemical carbon monoxide reduction to methanol can be dramatically tuned. Based on a collection of experimental investigations and density functional theory calculations, it reveals that the electron rearrangement of the Co 3d orbitals of cobalt phthalocyanine from the low-spin state (S = 1/2) to the high-spin state (S = 3/2), induced by molecular conformation change, is responsible for the greatly enhanced CO reduction reaction performance. Operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy measurements disclose accelerated hydrogenation of CORR intermediates, and kinetic isotope effect validates expedited proton-feeding rate over cobalt phthalocyanine with high-spin state. Further natural population analysis and density functional theory calculations demonstrate that the high spin Co2+ can enhance the electron backdonation via the d(xz)/d(yz)-2 pi* bond and weaken the C-O bonding in *CO, promoting hydrogenation of CORR intermediates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6550, "DOI": "10.1038/s41467-023-42307-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42307-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001086900900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, PX; Kang, YB; Yao, N; Chen, X; Mao, HY; Jang, WS; Halat, DM; Fu, ZH; Jung, MH; Jeong, HY; Kim, YM; Reimer, JA; Zhang, Q; Park, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Peixun; Kang, Yingbo; Yao, null; Chen, Xiang; Mao, Haiyan; Jang, Woo-Sung; Halat, David M.; Fu, Zhong-Heng; Jung, Min-Hyoung; Jeong, Hu Young; Kim, Young-Min; Reimer, Jeffrey A.; Zhang, Qiang; Park, Ho Seok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zn-Ion Transporting, In Situ Formed Robust Solid Electrolyte Interphase for Stable Zinc Metal Anodes over a Wide Temperature Range", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution, corrosion, and dendrite for-mation in the Zn anodes limit their practical applications in aqueous Zn metal batteries. Herein, we propose an interfacial chemistry regulation strategy that uses hybrid electrolytes of water and a polar aprotic N,N-dimethylformamide to modify the Zn2+- solvation structure and in situ form a robust and Zn2+-conducting Zn5(CO3)2(OH)6 solid electrolyte interphase (SEI) on the Zn surface to achieve stable and dendrite-free Zn plating/stripping over a wide temperature range. As confirmed by 67Zn nuclear magnetic resonullce relaxometry, electrochemical characteriza-tions, and molecular dynamics simulation, the electrochemically and thermally stable Zn5(OH)6(CO3)2-contained SEI achieved a high ionic conductivity of 0.04 to 1.27 mS cm-1 from -30 to 70 degrees C and a thermally activated fast Zn2+ migration through the [010] plane. Consequently, extremely stable Zn-ion hybrid capacitors in hybrid electrolytes are demonstrated with high capacity retentions and Coulombic efficiencies over 14,000, 10,000, and 600 cycles at 25, -20, and 70 degrees C, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 FEB 27", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1613, "End Page": 1625, "Article Number": null, "DOI": "10.1021/acsenergylett.3c00154", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.3c00154", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939406800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, R; Wang, T; Fan, QP; Wu, MJ; Yang, XR; Wu, XH; Yu, Y; Xia, XX; Cui, FZ; Wan, J; Lu, XH; Hao, XT; Jen, AKY; Spiecker, E; Min, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Rui; Wang, Tao; Fan, Qunping; Wu, Mingjian; Yang, Xinrong; Wu, Xiaohei; Yu, Yue; Xia, Xinxin; Cui, Fengzhe; Wan, Ji; Lu, Xinhui; Hao, Xiaotao; Jen, Alex K. -Y.; Spiecker, Erdmann; Min, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "18.2%-efficient ternary all-polymer organic solar cells with improved stability enabled by a chlorinated guest polymer acceptor", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the polymer/polymer blend systems still lag far behind small -molecule-acceptor-based counterparts in power conversion effi-ciencies (PCEs), the ternary blending strategy provides a simple and promising avenue to achieve an ideal nulloscale blend morphology for reducing the efficiency-stability gap of all-polymer solar cells (all-PSCs). Herein, we designed a narrow-band-gap chlorinated polymer acceptor PY-2Cl and incorporated into the PM6:PY-1S1Se host blend. The addition of PY-2Cl extends the absorption spectra, improves the molecular packing of host-guest acceptors, solidifies the blend microstructure, and suppresses the non-radiative recombination. Consequently, the PCE of the ternary blend is improved up to 18.2% (certified value 17.8%), which represents the highest PCE reported for all-PSCs so far. Impressively, the ternary blend exhibited smaller Urbach energy and better operation stability than did the correspond-ing binary systems. This work heralds a brighter future for accelerating the development of high-performance all-polymer systems by molecu-lar design and ternary strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2023, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 221, "End Page": 237, "Article Number": null, "DOI": "10.1016/j.joule.2022.12.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.12.007", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000960679700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hosokai, T; Matsuzaki, H; Nakanotani, H; Tokumaru, K; Tsutsui, T; Furube, A; Nasu, K; Nomura, H; Yahiro, M; Adachi, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hosokai, Takuya; Matsuzaki, Hiroyuki; Nakanotani, Hajime; Tokumaru, Katsumi; Tsutsui, Tetsuo; Furube, Akihiro; Nasu, Keirou; Nomura, Hiroko; Yahiro, Masayuki; Adachi, Chihaya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence and mechanism of efficient thermally activated delayed fluorescence promoted by delocalized excited states", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of organic compounds with nearly no gap between the first excited singlet (S-1) and triplet (T-1) states has been demonstrated to result in an efficient spin-flip transition from the T-1 to S-1 state, that is, reverse intersystem crossing (RISC), and facilitate light emission as thermally activated delayed fluorescence (TADF). However, many TADF molecules have shown that a relatively appreciable energy difference between the S-1 and T-1 states (similar to 0.2 eV) could also result in a high RISC rate. We revealed from a comprehensive study of optical properties of TADF molecules that the formation of delocalized states is the key to efficient RISC and identified a chemical template for these materials. In addition, simple structural confinement further enhances RISC by suppressing structural relaxation in the triplet states. Our findings aid in designing advanced organic molecules with a high rate of RISC and, thus, achieving the maximum theoretical electroluminescence efficiency in organic light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1603282", "DOI": "10.1126/sciadv.1603282", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603282", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401955300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, XB; Liu, H; Yuan, H; Peng, HJ; Tang, C; Huang, JQ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Xin-Bing; Liu, He; Yuan, Hong; Peng, Hong-Jie; Tang, Cheng; Huang, Jia-Qi; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A perspective on sustainable energy materials for lithium batteries", "Source Title": "SUSMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium ion battery has achieved great success in portable electronics and even recently electronic vehicles since its commercialization in 1990s. However, lithium-ion batteries are confronted with several issues in terms of the sustainable development such as the high price of raw materials and electronic products, the emerging safety accidents, etc. The recent progresses are herein emphasized on lithium batteries for energy storage to clearly understand the sustainable energy chemistry and emerging energy materials. The Perspective presents novel lithium-ion batteries developed with the aims of enhancing the electrochemical performance and sustainability of energy storage systems. First, revolutionary material chemistries, including novel low-cobalt cathode, organic electrode, and aqueous electrolyte, are discussed. Then, the characteristics of safety performance are analyzed and strategies to enhance safety are subsequently evaluated. Battery recycling is considered as the key factor for a sustainable society and related technologies are present as well. Finally, conclusion and outlook are drawn to shed lights on the further development of sustainable lithium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 38, "End Page": 50, "Article Number": null, "DOI": "10.1002/sus2.4", "DOI Link": "http://dx.doi.org/10.1002/sus2.4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000904096600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, J; Florian, M; Steinhoff, A; Erben, D; Tran, K; Kim, DS; Sun, LY; Quan, JM; Claassen, R; Majumder, S; Hollingsworth, JA; Taniguchi, T; Watanabe, K; Ueno, K; Singh, A; Moody, G; Jahnke, F; Li, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Junho; Florian, Matthias; Steinhoff, Alexander; Erben, Daniel; Tran, Kha; Kim, Dong Seob; Sun, Liuyang; Quan, Jiamin; Claassen, Robert; Majumder, Somak; Hollingsworth, Jennifer A.; Taniguchi, Takashi; Watanabe, Kenji; Ueno, Keiji; Singh, Akshay; Moody, Galan; Jahnke, Frank; Li, Xiaoqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Twist Angle-Dependent Interlayer Exciton Lifetimes in van der Waals Heterostructures", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In van der Waals (vdW) heterostructures formed by stacking two monolayers of transition metal dichalcogenides, multiple exciton resonullces with highly tunable properties are formed and subject to both vertical and lateral confinement. We investigate how a unique control knob, the twist angle between the two monolayers, can be used to control the exciton dynamics. We observe that the interlayer exciton lifetimes in MoSe2/WSe2 twisted bilayers (TBLs) change by one order of magnitude when the twist angle is varied from 1 degrees to 3.5 degrees. Using a low-energy continuum model, we theoretically separate two leading mechanisms that influence interlayer exciton radiative lifetimes. The shift to indirect transitions in the momentum space with an increasing twist angle and the energy modulation from the moil 6 potential both have a significant impact on interlayer exciton lifetimes. We further predict distinct temperature dependence of interlayer exciton lifetimes in TBLs with different twist angles, which is partially validated by experiments. While many recent studies have highlighted how the twist angle in a vdW TBL can be used to engineer the ground states and quantum phases due to many-body interaction, our studies explore its role in controlling the dynamics of optically excited states, thus, expanding the conceptual applications of twistronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2021, "Volume": 126, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 47401, "DOI": "10.1103/PhysRevLett.126.047401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.047401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612144200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mendes, BB; Conniot, J; Avital, A; Yao, DB; Jiang, XY; Zhou, X; Sharf-Pauker, N; Xiao, YL; Adir, O; Liang, HJ; Shi, JJ; Schroeder, A; Conde, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mendes, Barbara B.; Conniot, Joao; Avital, Aviram; Yao, Dongbao; Jiang, Xingya; Zhou, Xiang; Sharf-Pauker, Noga; Xiao, Yuling; Adir, Omer; Liang, Haojun; Shi, Jinjun; Schroeder, Avi; Conde, Joao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullodelivery of nucleic acids", "Source Title": "NATURE REVIEWS METHODS PRIMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is growing need for a safe, efficient, specific and non-pathogenic means for delivery of gene therapy materials. nullomaterials for nucleic acid delivery offer an unprecedented opportunity to overcome these drawbacks; owing to their tunability with diverse physico-chemical properties, they can readily be functionalized with any type of biomolecules/moieties for selective targeting. Nucleic acid therapeutics such as antisense DNA, mRNA, small interfering RNA (siRNA) or microRNA (miRNA) have been widely explored to modulate DNA or RNA expression Strikingly, gene therapies combined with nulloscale delivery systems have broadened the therapeutic and biomedical applications of these molecules, such as bioanalysis, gene silencing, protein replacement and vaccines. Here, we overview how to design smart nucleic acid delivery methods, which provide functionality and efficacy in the layout of molecular diagnostics and therapeutic systems. It is crucial to outline some of the general design considerations of nucleic acid delivery nulloparticles, their extraordinary properties and the structure-function relationships of these nullomaterials with biological systems and diseased cells and tissues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2022, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24, "DOI": "10.1038/s43586-022-00104-y", "DOI Link": "http://dx.doi.org/10.1038/s43586-022-00104-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888571500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Müller, J; Polakowski, P; Mueller, S; Mikolajick, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mueller, J.; Polakowski, P.; Mueller, S.; Mikolajick, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric Hafnium Oxide Based Materials and Devices: Assessment of Current Status and Future Prospects", "Source Title": "ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bound to complex perovskite systems, ferroelectric random access memory (FRAM) suffers from limited CMOS-compatibility and faces severe scaling issues in today's and future technology nodes. Nevertheless, compared to its current-driven non-volatile memory contenders, the field-driven FRAM excels in terms of low voltage operation and power consumption and therewith has managed to claim embedded as well as stand-alone niche markets. However, in order to overcome this restricted field of application, a material innovation is needed. With the ability to engineer ferroelectricity in HfO2, a high-k dielectric well established in memory and logic devices, a new material choice for improved manufacturability and scalability of future 1T and 1T-1C ferroelectric memories has emerged. This paper reviews the recent progress in this emerging field and critically assesses its current and future potential. Suitable memory concepts as well as new applications will be proposed accordingly. Moreover, an empirical description of the ferroelectric stabilization in HfO2 will be given, from which additional dopants as well as alternative stabilization mechanism for this phenomenon can be derived. (C) The Author(s) 2015. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "N30", "End Page": "N35", "Article Number": null, "DOI": "10.1149/2.0081505jss", "DOI Link": "http://dx.doi.org/10.1149/2.0081505jss", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352224200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, YS; Yuan, J; Liu, TT; Wang, QQ; Cao, WQ; Cao, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Yong-Sheng; Yuan, Jie; Liu, Ting -Ting; Wang, Qiang-Qiang; Cao, Wen-Qiang; Cao, Mao-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Clipping electron transport and polarization relaxation of Ti3C2Tx based nullocomposites towards multifunction", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance multifunctional electromagnetic (EM) materials exhibit great potential for development, and have attracted extensive attention from the scientific field. Generally, the dielectric genes, including conductive networks, interfaces, and defects, are the pivotal factors that determine their performance. Herein, multifunctional Ti3C2Tx@polyaniline decorated MWCNT (TPMC) nullocomposites, containing generous dielectric genes, were synthesized via the electrostatic self-assembly method. Thanks to the regulation of internal dielectric genes, TPMC exhibited a tunable EM wave absorption (EMA) and EM interference (EMI) shielding performance. TPMC achieved a maximum reflection loss (RL) of -54.7 dB and an effective absorption bandwidth (EAB) of nearly 6 GHz at 1.5 mm. Moreover, the complete conductive networks endowed TPMC with a reliable EMI shielding capability. It exhibited a maximum EMI shielding effectiveness (SE) of 34 dB, and meanwhile, displayed an absorption-dominated green shielding performance. Furthermore, owing to the integration of the genes, TPMC showed a high coulomb efficiency (similar to 98%) and excellent cycling stability (exceeded 95% retation after 8000 cycles), indicating a great potential as outstanding supercapacitor electrode material. This work provides a promising strategy for controlling the EM pollution and alleviating the energy issues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 201, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 371, "End Page": 380, "Article Number": null, "DOI": "10.1016/j.carbon.2022.09.043", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2022.09.043", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863600500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, D; Zeng, K; Li, J; Qiu, Y; Flamant, G; Nzihou, A; Vladimirovich, VS; Yang, HP; Chen, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Dian; Zeng, Kuo; Li, Jun; Qiu, Yi; Flamant, Gilles; Nzihou, Ange; Vladimirovich, Vasilevich Sergey; Yang, Haiping; Chen, Hanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characteristics and evolution of heavy components in bio-oil from the pyrolysis of cellulose, hemicellulose and lignin", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Y Three main components of biomass were pyrolyzed individually in a closed reaction system at 500-700 degrees C for 60s and 90s. Then bio-oil heavy compounds were further analyzed with Fourier transform-ion cyclotron resonullce-mass spectrometry (FT-ICR-MS) and Kendrick mass defect (KMD) analysis. The evolution paths of heavy compounds for the different pyrolysis stages were proposed. It was found that the sugars and phenolic-like species in heavy compounds were the most active substances during secondary reactions. Moreover, the rising temperature promoted this secondary reaction of phenolic-like species as the decrease in their abundances growing from 13% to 54%, while contrarily inhibited it for hemicellulose as the decrease in their abundances changing from 44% to similar to 2%. The lignin-derived lipids and unsaturated hydrocarbons that generated in the secondary reactions increased with rising temperature. KMD analysis showed that the heavy compounds of cellulose and hemicellulose prefer homologous evolution during pyrolysis, while those of lignin had more complex evolution paths like cracking and recombination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111989, "DOI": "10.1016/j.rser.2021.111989", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2021.111989", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784449300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, B; Iñiguez, J; Bellaiche, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Bin; Iniguez, Jorge; Bellaiche, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing lead-free antiferroelectrics for energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors, although presenting faster charging/discharging rates and better stability compared with supercapacitors or batteries, are limited in applications due to their low energy density. Antiferroelectric (AFE) compounds, however, show great promise due to their atypical polarization-versus-electric field curves. Here we report our first-principles-based theoretical predictions that Bi1-xRxFeO3 systems (R being a lanthanide, Nd in this work) can potentially allow high energy densities (100-150 J cm(-3)) and efficiencies (80-88%) for electric fields that may be within the range of feasibility upon experimental advances (2-3 MV cm(-1)). In addition, a simple model is derived to describe the energy density and efficiency of a general AFE material, providing a framework to assess the effect on the storage properties of variations in doping, electric field magnitude and direction, epitaxial strain, temperature and so on, which can facilitate future search of AFE materials for energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15682, "DOI": "10.1038/ncomms15682", "DOI Link": "http://dx.doi.org/10.1038/ncomms15682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402306800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, QN; Yu, R; Fang, Z; Dai, X; Weng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Qiunull; Yu, Rui; Fang, Zhong; Dai, Xi; Weng, Hongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological nodal line semimetals in the CaP3 family of materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By using first-principles calculations and a k . p model analysis, we propose that the three-dimensional topological nodal line semimetal state can be realized in the CaP3 family of materials, which includes CaP3, CaAs3, SrP3, SrAs3, and BaAs3, when spin-orbit coupling (SOC) is ignored. The closed topological nodal line near the Fermi energy is protected by time reversal symmetry and spatial inversion symmetry. Moreover, drumheadlike two-dimensional surface states are also obtained on the c-direction surface of these materials. When SOC is included, the gaps open along the nodal line and these materials become strong topological insulators with Z(2) indices as (1; 010).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2017, "Volume": 95, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45136, "DOI": "10.1103/PhysRevB.95.045136", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.045136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400771400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aghababaei, R; Warner, DH; Molinari, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aghababaei, Ramin; Warner, Derek H.; Molinari, Jean-Francois", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Critical length scale controls adhesive wear mechanisms", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The adhesive wear process remains one of the least understood areas of mechanics. While it has long been established that adhesive wear is a direct result of contacting surface asperities, an agreed upon understanding of how contacting asperities lead to wear debris particle has remained elusive. This has restricted adhesive wear prediction to empirical models with limited transferability. Here we show that discrepant observations and predictions of two distinct adhesive wear mechanisms can be reconciled into a unified framework. Using atomistic simulations with model interatomic potentials, we reveal a transition in the asperity wear mechanism when contact junctions fall below a critical length scale. A simple analytic model is formulated to predict the transition in both the simulation results and experiments. This new understanding may help expand use of computer modelling to explore adhesive wear processes and to advance physics-based wear laws without empirical coefficients.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11816, "DOI": "10.1038/ncomms11816", "DOI Link": "http://dx.doi.org/10.1038/ncomms11816", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377385500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasmussen, LA; Lykkemark, J; Andersen, TR; Vollertsen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasmussen, Lasse Abraham; Lykkemark, Jeanette; Andersen, Theis Raaschou; Vollertsen, Jes", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Permeable pavements: A possible sink for tyre wear particles and other microplastics?", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, seven roads and parking lots were sampled by a road surface cleaning truck and approximately 100 kg of particulate material was collected per site. Thereafter, the samples were analysed for microplastics, including tyre wear particles. The analyses revealed that tyre wear constituted 0.09 % of the dry mass of the samples on average. Other plastic types were also identified in the samples, but at on average 49 times lower concentrations compared to tyre wear particles. Although the roads and parking lots were used for residential, industrial, and commercial purposes, no correlation between land use and the total concentrations of microplastics was identified. Of microplastics other than tyre wear particles, polypropylene constituted an important fraction in all samples, whereas other polymers were present at various degrees. The contents of heavy metals, sulphur, and total organic carbon were also measured in the samples, but no correlation between them and microplastics was determined. A back-of-the-envelope estimation indicated that the tyre wear material retained by permeable pavements constituted a non-negligible fraction of the total mass of microplastics released on roads and parking lots. Therefore, permeable pavements can serve as a tool for the management of this pollutant.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 44, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 869, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 161770, "DOI": "10.1016/j.scitotenv.2023.161770", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2023.161770", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964877000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ederer, J; Janos, P; Ecorchard, P; Tolasz, J; Stengl, V; Benes, H; Perchacz, M; Pop-Georgievski, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ederer, Jakub; Janos, Pavel; Ecorchard, Petra; Tolasz, Jakub; Stengl, Vaclav; Benes, Hynek; Perchacz, Magdalena; Pop-Georgievski, Ognen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of amino groups on functionalized graphene oxide for polyurethane nullomaterials: XPS quantitation vs. functional speciation", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Amino-functionalized graphene oxide was reacted with isocyanate monomer to evaluate the potential application of GO-NH2 as a functional filler for the preparation of polyurethane nullocomposites. A set of advanced techniques (XRD, FTIR spectroscopy, Raman spectroscopy, and TEM) was used to characterize the functionalized samples, together with elemental analysis and XPS, which provided valuable information on the total N content and the nitrogen (chemical) speciation, respectively. In addition, a simple and fast spectrophotometric method was developed for the estimation of accessible amino groups (functional speciation). The method is based on the interaction of NH2 groups with the anionic dye acid orange 7 under appropriate conditions (pH = 3.6) and shows good precision. It can be advantageously used for the fast evaluation of the GO-NH2 reactivity with isocyanate monomer and its applicability as the polymer filler.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12464, "End Page": 12473, "Article Number": null, "DOI": "10.1039/c6ra28745j", "DOI Link": "http://dx.doi.org/10.1039/c6ra28745j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395934500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QL; Jia, Y; Liu, Q; Mao, X; Guo, Q; Yan, XC; Zhao, JP; Liu, FC; Du, AJ; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qilong; Jia, Yi; Liu, Qian; Mao, Xin; Guo, Qi; Yan, Xuecheng; Zhao, Jiongpeng; Liu, Fuchen; Du, Aijun; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defective carbons have recently been considered as one of the most promising alternatives to precious metal electrocatalysts. However, atomic structural tailoring of carbon defects poses challenges, especially in regulating defect density to maximize the active sites. Herein, we report an interfacial self-corrosion strategy to control the removal and reconstruction of carbon atoms via a series of thermal redox reactions of ZnO quantum dots and formed CO2 gas in confined carbon cavity. The ultra-dense carbon defects (HDPC) (2.46 x 10(13) cm(-2)) in the derived porous carbon served as efficient active sites for oxygen reduction, resulting in an excellent catalyst in both base and acid (half-wave potentials of 0.90 or 0.75 V in 0.1 M KOH or HClO4). The normalized specific activity and density functional theory calculation reveal a gradient ``proximity effect'' between carbon defects with different spatial distance, indicating that the quantitative control of carbon defect density is the key to enhancing electrocatalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2022, "Volume": 8, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2715, "End Page": 2733, "Article Number": null, "DOI": "10.1016/j.chempr.2022.06.013", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2022.06.013", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000889489000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Q; Guo, ZQ; Wang, C; Guo, S; Xu, ZW; Hu, CG; Liu, YJ; Wang, YL; He, J; Wong, WY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qian; Guo, Zengqi; Wang, Cong; Guo, Su; Xu, Zhiwei; Hu, Chenguang; Liu, Yujing; Wang, Yalei; He, Jun; Wong, Wai-Yeung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Cobalt-Based Metal-Organic Framework nullosheet as the Electrode for High-Performance Asymmetric Supercapacitor", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the significant advantages of the bottom-up synthesis whose structures and functionalities can be customized by the selection of molecular components, a 2D metal-organic framework (MOF) nullosheet Co-BTB-LB has been synthesized by a liquid-liquid interface-assisted method. The as-prepared Co-BTB-LB is identified by scanning electron microscopy/energy dispersive spectroscopy (SEM/EDX) and X-ray photoelectron spectroscopy (XPS), and the sheet-like structure is verified by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and atomic force microscopy (AFM). Co-BTB-LB electrode exhibits an excellent capacity of 4969.3 F g(-1) at 1 A g(-1) and good cycling stability with 75% capacity retention after 1000 cycles. The asymmetric supercapacitor device with Co-BTB-LB as the positive electrode shows a maximum energy density of 150.2 Wh kg(-1) at a power density of 1619.2 W kg(-1) and good cycling stability with a capacitance retention of 97.1% after 10000 cycles. This represents a state-of-the-art performance reported for asymmetric supercapacitor device using electroactive bottom-up metal-complex nullosheet, which will clearly lead to a significant expansion of the applicability of this type of 2D nullomaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 43, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207545", "DOI Link": "http://dx.doi.org/10.1002/advs.202207545", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000974696700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bedoya-Pinto, A; Ji, JR; Pandeya, AK; Gargiani, P; Valvidares, M; Sessi, P; Taylor, JM; Radu, F; Chang, K; Parkin, SSP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bedoya-Pinto, Amilcar; Ji, Jing-Rong; Pandeya, Avanindra K.; Gargiani, Pierluigi; Valvidares, Manuel; Sessi, Paolo; Taylor, James M.; Radu, Florin; Chang, Kai; Parkin, Stuart S. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic 2D-XY ferromagnetism in a van der Waals monolayer", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The physics and universality scaling of phase transitions in low-dimensional systems has historically been a topic of great interest. Recently, two-dimensional (2D) materials exhibiting intriguing long-range magnetic order have been in the spotlight. Although an out-of-plane anisotropy has been shown to stabilize 2D magnetic order, the demonstration of a 2D magnet with in-plane rotational symmetry has remained elusive. We constructed a nearly ideal easy-plane system, a single CrCl3 monolayer on graphene/6H-SiC(0001), and observed robust ferromagnetic ordering with critical scaling characteristic of a 2D-XY system. These observations indicate the realization of a finite-size Berezinskii-Kosterlitz-Thouless phase transition in a large-area, quasi-free-standing van der Waals monolayer magnet with an XY universality class. This offers a material platform to host 2D superfluid spin transport and topological magnetic textures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2021, "Volume": 374, "Issue": 6567, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 616, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd5146", "DOI Link": "http://dx.doi.org/10.1126/science.abd5146", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714943400041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, B; Wang, SH; Wu, ZX; Wang, ZX; Wang, DH; Huang, H; Zhang, F; Ge, YQ; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Bo; Wang, Shi-Hao; Wu, Zhi-Xin; Wang, Ze-Xin; Wang, Da-He; Huang, Hao; Zhang, Feng; Ge, Yan-Qi; Zhang, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sub-200 fs soliton mode-locked fiber laser based on bismuthene saturable absorber", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer bismuthene is an emerging two-dimensional material in the fields of physics, chemistry, and material science. However, its nonlinear optical property and the related photonics device have been seldom studied so far. Here. we demonstrate a sub-200 fs soliton mode-locked erbium-doped fiber laser (EDFL) using a microfiber-based bismuthene saturable absorber for the fast time, to the best of our knowledge. The bismuthene nullosheets are synthesized by the sonochemical exfoliation method and transferred onto the taper region of a microfiber by the optical deposition method. Stable soliton pulses centered at 1561 nm with the shortest pulse duration of about 193 fs were obtained. Our findings unambiguously imply that apart from its fantastic electric and thermal properties, few-layer bismuthene may also possess attractive optoclectronic properties for nonlinear photonics, such as mode-lockers, Q-switchers, optical modulators and so on. (C) 2018 Optical Society of America under the terms of the OS.A Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2018, "Volume": 26, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22750, "End Page": 22760, "Article Number": null, "DOI": "10.1364/OE.26.022750", "DOI Link": "http://dx.doi.org/10.1364/OE.26.022750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443431400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, Y; Meng, MQ; Daouadji, A; Chen, QS; Wu, ZJ; Jiang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Yang; Meng, Minqiang; Daouadji, Ali; Chen, Qingsheng; Wu, Zhijun; Jiang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of particle size on crushing and deformation behaviors of rockfill materials", "Source Title": "GEOSCIENCE FRONTIERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strength and deformation behaviors of rockfill materials, key factors for determining the stability of dams, pertain strongly to the grain crushing characteristics. In this study, single-particle crushing tests were carried out on rockfill materials with nominal particle diameters of 2.5 mm, 5 mm and 10 mm to investigate the particle size effect on the single-particle strength and the relationship between the characteristic stress and probability of non-failure. Test data were found to be described by the Weibull distribution with the Weibull modulus of 3.24. Assemblies with uniform nominal grains were then subjected to one-dimensional compression tests at eight levels of vertical stress with a maximum of 100 MPa. The yield stress in one-dimensional compression tests increased with decreasing the particle size, which could be estimated from the single-particle crushing tests. The void ratio-vertical stress curve could be predicted by an exponential function. The particle size distribution curve increased obviously with applied stresses less than 16 MPa and gradually reached the ultimate fractal grading. The relative breakage index became constant with stress up to 64 MPa and was obtained from the ultimate grading at the fractal dimension (alpha = 2.7). A hyperbolical function was also found useful for describing the relationship between the relative breakage index and input work during one-dimensional compression tests. (C) 2020, China University of Geosciences (Beijing) and Peking University. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 375, "End Page": 388, "Article Number": null, "DOI": "10.1016/j.gsf.2018.10.010", "DOI Link": "http://dx.doi.org/10.1016/j.gsf.2018.10.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522623000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XH; Wang, YL; Wen, J; Zheng, LL; Qian, C; Cheng, ZH; Zuo, HY; Yu, MQ; Yuan, JY; Li, R; Zhang, WY; Liao, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xinghao; Wang, Yong-Lei; Wen, Jin; Zheng, Linlin; Qian, Cheng; Cheng, Zhonghua; Zuo, Hongyu; Yu, Mingqing; Yuan, Jiayin; Li, Rong; Zhang, Weiyi; Liao, Yaozu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous organic polycarbene nullotrap for efficient and selective gold stripping from electronic waste", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient and selective gold recovery from electronic waste is highly demanded. Here, authors demonstrate the application of a porous organic polycarbene adsorbent with up to 2.09 g/g gold-capturing capability. The role of N-heterocyclic carbene, a well-known reactive site, in chemical catalysis has long been studied. However, its unique binding and electron-donating properties have barely been explored in other research areas, such as metal capture. Herein, we report the design and preparation of a poly(ionic liquid)-derived porous organic polycarbene adsorbent with superior gold-capturing capability. With carbene sites in the porous network as the nullotrap, it exhibits an ultrahigh gold recovery capacity of 2.09 g/g. In-depth exploration of a complex metal ion environment in an electronic waste-extraction solution indicates that the polycarbene adsorbent possesses a significant gold recovery efficiency of 99.8%. X-ray photoelectron spectroscopy along with nuclear magnetic resonullce spectroscopy reveals that the high performance of the polycarbene adsorbent results from the formation of robust metal-carbene bonds plus the ability to reduce nearby gold ions into nulloparticles. Density functional theory calculations indicate that energetically favourable multinuclear Au binding enhances adsorption as clusters. Life cycle assessment and cost analysis indicate that the synthesis of polycarbene adsorbents has potential for application in industrial-scale productions. These results reveal the potential to apply carbene chemistry to materials science and highlight porous organic polycarbene as a promising new material for precious metal recovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 263, "DOI": "10.1038/s41467-023-35971-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35971-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953170300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Segev, G; Kibsgaard, J; Hahn, C; Xu, ZJ; Cheng, WH; Deutsch, TG; Xiang, CX; Zhang, JZ; Hammarström, L; Nocera, DG; Weber, AZ; Agbo, P; Hisatomi, T; Osterloh, FE; Domen, K; Abdi, FF; Haussener, S; Miller, DJ; Ardo, S; McIntyre, PC; Hannappel, T; Hu, S; Atwater, H; Gregoire, JM; Ertem, MZ; Sharp, ID; Choi, KS; Lee, JS; Ishitani, O; Ager, JW; Prabhakar, RR; Bell, AT; Boettcher, SW; Vincent, K; Takanabe, K; Artero, V; Napier, R; Roldan Cuenya, B; Koper, MTM; Van de Krol, R; Houle, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Segev, Gideon; Kibsgaard, Jakob; Hahn, Christopher; Xu, Zhichuan J.; Cheng, Wen-Hui (Sophia); Deutsch, Todd G.; Xiang, Chengxiang; Zhang, Jenny Z.; Hammarstrom, Leif; Nocera, Daniel G.; Weber, Adam Z.; Agbo, Peter; Hisatomi, Takashi; Osterloh, Frank E.; Domen, Kazunari; Abdi, Fatwa F.; Haussener, Sophia; Miller, Daniel J.; Ardo, Shane; McIntyre, Paul C.; Hannappel, Thomas; Hu, Shu; Atwater, Harry; Gregoire, John M.; Ertem, Mehmed Z.; Sharp, Ian D.; Choi, Kyoung-Shin; Lee, Jae Sung; Ishitani, Osamu; Ager, Joel W.; Prabhakar, Rajiv Ramanujam; Bell, Alexis T.; Boettcher, Shannon W.; Vincent, Kylie; Takanabe, Kazuhiro; Artero, Vincent; Napier, Ryan; Roldan Cuenya, Beatriz; Koper, Marc T. M.; Van de Krol, Roel; Houle, Frances", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The 2022 solar fuels roadmap", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Renewable fuel generation is essential for a low carbon footprint economy. Thus, over the last five decades, a significant effort has been dedicated towards increasing the performance of solar fuels generating devices. Specifically, the solar to hydrogen efficiency of photoelectrochemical cells has progressed steadily towards its fundamental limit, and the faradaic efficiency towards valuable products in CO2 reduction systems has increased dramatically. However, there are still numerous scientific and engineering challenges that must be overcame in order to turn solar fuels into a viable technology. At the electrode and device level, the conversion efficiency, stability and products selectivity must be increased significantly. Meanwhile, these performance metrics must be maintained when scaling up devices and systems while maintaining an acceptable cost and carbon footprint. This roadmap surveys different aspects of this endeavor: system benchmarking, device scaling, various approaches for photoelectrodes design, materials discovery, and catalysis. Each of the sections in the roadmap focuses on a single topic, discussing the state of the art, the key challenges and advancements required to meet them. The roadmap can be used as a guide for researchers and funding agencies highlighting the most pressing needs of the field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2022, "Volume": 55, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 323003, "DOI": "10.1088/1361-6463/ac6f97", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/ac6f97", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000814374800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tanné, E; Li, T; Bourdin, B; Marigo, JJ; Maurini, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tanne, E.; Li, T.; Bourdin, B.; Marigo, J. -J.; Maurini, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crack nucleation in variational phase-field models of brittle fracture", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase-field models, sometimes referred to as gradient damage or smeared crack models, are widely used methods for the numerical simulation of crack propagation in brittle materials. Theoretical results and numerical evidences show that they can predict the propagation of a pre-existing crack according to Griffith' criterion. For a one-dimensional problem, it has been shown that they can predict nucleation upon a critical stress, provided that the regularization parameter be identified with the material's internal or characteristic length. In this article, we draw on numerical simulations to study crack nucleation in commonly encountered geometries for which closed-form solutions are not available. We use U- and V-notches to show that the nucleation load varies smoothly from that predicted by a strength criterion to that of a toughness criterion when the strength of the stress concentration or singularity varies. We present validation and verification numerical simulations for both types of geometries. We consider the problem of an elliptic cavity in an infinite or elongated domain to show that variational phase field models properly account for structural and material size effects. Our main claim, supported by validation and verification in a broad range of materials and geometries, is that crack nucleation can be accurately predicted by minimization of a nonlinear energy in variational phase field models, and does not require the introduction of ad-hoc criteria. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 80, "End Page": 99, "Article Number": null, "DOI": "10.1016/j.jmps.2017.09.006", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2017.09.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415778400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dogra, P; Adolphi, NL; Wang, ZH; Lin, YS; Butler, KS; Durfee, PN; Croissant, JG; Noureddine, A; Coker, EN; Bearer, EL; Cristini, V; Brinker, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dogra, Prashant; Adolphi, Natalie L.; Wang, Zhihui; Lin, Yu-Shen; Butler, Kimberly S.; Durfee, Paul N.; Croissant, Jonas G.; Noureddine, Achraf; Coker, Eric N.; Bearer, Elaine L.; Cristini, Vittorio; Brinker, C. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Establishing the effects of mesoporous silica nulloparticle properties on in vivo disposition using imaging-based pharmacokinetics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The progress of nulloparticle (NP)-based drug delivery has been hindered by an inability to establish structure-activity relationships in vivo. Here, using stable, monosized, radiolabeled, mesoporous silica nulloparticles (MSNs), we apply an integrated SPECT/CT imaging and mathematical modeling approach to understand the combined effects of MSN size, surface chemistry and routes of administration on biodistribution and clearance kinetics in healthy rats. We show that increased particle size from similar to 32- to similar to 142-nm results in a monotonic decrease in systemic bioavailability, irrespective of route of administration, with corresponding accumulation in liver and spleen. Cationic MSNs with surface exposed amines (PEI) have reduced circulation, compared to MSNs of identical size and charge but with shielded amines (QA), due to rapid sequestration into liver and spleen. However, QA show greater total excretion than PEI and their size-matched neutral counterparts (TMS). Overall, we provide important predictive functional correlations to support the rational design of nullomedicines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4551, "DOI": "10.1038/s41467-018-06730-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06730-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448807000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ringe, S; Morales-Guio, CG; Chen, LD; Fields, M; Jaramillo, TF; Hahn, C; Chan, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ringe, Stefan; Morales-Guio, Carlos G.; Chen, Leanne D.; Fields, Meredith; Jaramillo, Thomas F.; Hahn, Christopher; Chan, Karen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical CO2 reduction is a potential route to the sustainable production of valuable fuels and chemicals. Here, we perform CO2 reduction experiments on Gold at neutral to acidic pH values to elucidate the long-standing controversy surrounding the rate-limiting step. We find the CO production rate to be invariant with pH on a Standard Hydrogen Electrode scale and conclude that it is limited by the CO2 adsorption step. We present a new multi-scale modeling scheme that integrates ab initio reaction kinetics with mass transport simulations, explicitly considering the charged electric double layer. The model reproduces the experimental CO polarization curve and reveals the rate-limiting step to be *COOH to *CO at low overpotentials, CO2 adsorption at intermediate ones, and CO2 mass transport at high overpotentials. Finally, we show the Tafel slope to arise from the electrostatic interaction between the dipole of *CO2 and the interfacial field. This work highlights the importance of surface charging for electrochemical kinetics and mass transport.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 33, "DOI": "10.1038/s41467-019-13777-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13777-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511958300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, YG; Haldoupis, E; Bucior, BJ; Haranczyk, M; Lee, S; Zhang, HD; Vogiatzis, KD; Milisavljevic, M; Ling, SL; Camp, JS; Slater, B; Siepmann, JI; Sholl, DS; Snurr, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Yongchul G.; Haldoupis, Emmanuel; Bucior, Benjamin J.; Haranczyk, Maciej; Lee, Seulchan; Zhang, Hongda; Vogiatzis, Konstantinos D.; Milisavljevic, Marija; Ling, Sanliang; Camp, Jeffrey S.; Slater, Ben; Siepmann, J. Ilja; Sholl, David S.; Snurr, Randall Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances, Updates, and Analytics for the Computation-Ready, Experimental Metal-Organic Framework Database: CoRE MOF 2019", "Source Title": "JOURNAL OF CHEMICAL AND ENGINEERING DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over 14 000 porous, three-dimensional metal-organic framework structures are compiled and analyzed as a part of an update to the Computation-Ready, Experimental Metal-Organic Framework Database (CoRE MOF Database). The updated database includes additional structures that were contributed by CoRE MOF users, obtained from updates of the Cambridge Structural Database and a Web of Science search, and derived through semiautomated reconstruction of disordered structures using a topology-based crystal generator. In addition, value is added to the CoRE MOF database through new analyses that can speed up future nulloporous materials discovery activities, including open metal site detection and duplicate searches. Crystal structures (only for the subset that underwent significant changes during curation), pore analytics, and physical property data are included with the publicly available CoRE MOF 2019 database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 510, "Times Cited, All Databases": 541, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 64, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5985, "End Page": 5998, "Article Number": null, "DOI": "10.1021/acs.jced.9b00835", "DOI Link": "http://dx.doi.org/10.1021/acs.jced.9b00835", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503115000098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Gao, SY; Duan, SF; Xu, YF; Zhu, KJ; Tian, SJ; Gao, JC; Fan, WH; Rao, ZC; Huang, JR; Li, JJ; Yan, Y; Liu, ZT; Liu, WL; Huang, YB; Li, YL; Liu, Y; Zhang, GB; Zhang, P; Kondo, T; Shin, S; Lei, HC; Shi, YG; Zhang, WT; Weng, HM; Qian, T; Ding, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hang; Gao, Shun-Ye; Duan, Shao-Feng; Xu, Yuan-Feng; Zhu, Ke-Jia; Tian, Shang-Jie; Gao, Jia-Cheng; Fan, Wen-Hui; Rao, Zhi-Cheng; Huang, Jie-Rui; Li, Jia-Jun; Yan, Yu; Liu, Zheng-Tai; Liu, Wan-Ling; Huang, Yao-Bo; Li, Yu-Liang; Liu, Yi; Zhang, Guo-Bin; Zhang, Peng; Kondo, Takeshi; Shin, Shik; Lei, He-Chang; Shi, You-Guo; Zhang, Wen-Tao; Weng, Hong-Ming; Qian, Tian; Ding, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac Surface States in Intrinsic Magnetic Topological Insulators EuSn2As2 and MnBi2nTe3n+1", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In magnetic topological insulators (TIs), the interplay between magnetic order and nontrivial topology can induce fascinating topological quantum phenomena, such as the quantum anomalous Hall effect, chiral Majorana fermions, and axion electrodynamics. Recently, a great deal of attention has been focused on the intrinsic magnetic TIs, where disorder effects can be eliminated to a large extent, which is expected to facilitate the emergence of topological quantum phenomena. Despite intensive efforts, experimental evidence of the topological surface states (SSs) remains elusive. Here, by combining first-principles calculations and angle-resolved photoemission spectroscopy (ARPES) experiments, we reveal that EuSn2As2 is an antiferromagnetic TI with the observation of Dirac SSs consistent with our prediction. We also observe nearly gapless Dirac SSs in antiferromagnetic TIs MnBi2nTe3n+1 (n = 1 and 2), which are absent in previous ARPES results. These results provide clear evidence for nontrivial topology of these intrinsic magnetic TIs. Furthermore, we find that the topological SSs show no observable changes across the magnetic transition within the experimental resolution, indicating that the magnetic order has a quite small effect on the topological SSs, which can be attributed to weak hybridization between the localized magnetic moments, from either 4f or 3d orbitals, and the topological electronic states. This finding provides insights for further research that the correlations between magnetism and topological states need to be strengthened to induce larger gaps in the topological SSs, which will facilitate the realization of topological quantum phenomena at higher temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 21", "Publication Year": 2019, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41039, "DOI": "10.1103/PhysRevX.9.041039", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.9.041039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498062600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lan, J; Wei, ZX; Lu, YR; Chen, DC; Zhao, SL; Chan, TS; Tan, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lan, Jiao; Wei, Zengxi; Lu, Ying-Rui; Chen, DeChao; Zhao, Shuangliang; Chan, Ting-Shan; Tan, Yongwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient electrosynthesis of formamide from carbon monoxide and nitrite on a Ru-dispersed Cu nullocluster catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conversion into high-value-added organic nitrogen compounds through electrochemical C-N coupling reactions under ambient conditions is regarded as a sustainable development strategy to achieve carbon neutrality and high-value utilization of harmful substances. Herein, we report an electrochemical process for selective synthesis of high-valued formamide from carbon monoxide and nitrite with a Ru1Cu single-atom alloy under ambient conditions, which achieves a high formamide selectivity with Faradaic efficiency of 45.65 +/- 0.76% at -0.5V vs. RHE. In situ X-ray absorption spectroscopy, coupled with in situ Raman spectroscopy and density functional theory calculations results reveal that the adjacent Ru-Cu dual active sites can spontaneously couple *CO and *NH2 intermediates to realize a critical C-N coupling reaction, enabling high-performance electrosynthesis of formamide. This work offers insight into the high-value formamide electrocatalysis through coupling CO and NO2- under ambient conditions, paving the way for the synthesis of more-sustainable and high-value chemical products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2870, "DOI": "10.1038/s41467-023-38603-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38603-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058116700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, RR; Yuan, CQ; Fan, W; Ren, XK; Yan, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Ruirui; Yuan, Chengqian; Fan, Wei; Ren, Xiaokang; Yan, Xuehai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomolecular glass with amino acid and peptide nulloarchitectonics", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glass is ubiquitous in life and widely used in various fields. However, there is an urgent need to develop biodegradable and biorecyclable glasses that have a minimal environmental footprint toward a sustainable society and a circular materials economy. Here, we report a family of eco-friendly glasses of biological origin fabricated using biologically derived amino acids or peptides through the classic heating-quenching procedure. Amino acids and peptides with chemical modification at their ends are found able to form a supercooled liquid before decomposition and eventually glass upon quenching. These developed glasses exhibit excellent glass-forming ability and optical characteristics and are amenable to three-dimensional-printed additive manufacturing and mold casting. Crucially, the glasses show biocompatibility, biodegradability, and biorecyclability beyond the currently used commercial glasses and plastic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2023, "Volume": 9, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadd8105", "DOI": "10.1126/sciadv.add8105", "DOI Link": "http://dx.doi.org/10.1126/sciadv.add8105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000969832000016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hummel, JR; Ellman, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hummel, Joshua R.; Ellman, Jonathan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt(III)-Catalyzed Synthesis of Indazoles and Furans by C-H Bond Functionalization/Addition/Cyclization Cascades", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of operationally straightforward and cost-effective routes for the assembly of heterocycles from simple inputs is important for many scientific endeavors, including pharmaceutical, agrochemical, and materials research. In this article we describe the development of a new air-stable cationic Co(III) catalyst for convergent, one-step benchtop syntheses of N-aryl-2H-indazoles and furans by C-H bond additions to aldehydes followed by in situ cyclization and aromatization. Only a substoichiometric amount of AcOH is required as an additive that is both low-cost and convenient to handle. The syntheses of these heterocycles are the first examples of Co(III)-catalyzed additions to aldehydes, and reactions are demonstrated for a variety of aromatic, heteroaromatic, and aliphatic derivatives. The syntheses of both N-aryl-2H-indazoles and furans have been performed on 20 mmol scales and should be readily applicable to larger scales. The reported heterocycle syntheses also demonstrate the use of directing groups that have not previously been applied to Co(III)-catalyzed C-H bond functionalizations. Additionally, the synthesis of furans demonstrates the first example of Co(III)-catalyzed functionalization of alkenyl C-H bonds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 137, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 490, "End Page": 498, "Article Number": null, "DOI": "10.1021/ja5116452", "DOI Link": "http://dx.doi.org/10.1021/ja5116452", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348483500080", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Gao, Y; Li, YY; Yan, YM; Ou, JY; Ma, WZ; Zhu, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wei; Gao, Yuan; Li, Yuyang; Yan, Yiming; Ou, Jun-Yu; Ma, Wenzhuang; Zhu, Jinfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Solar Metamaterial Absorbers Empowered by Transformer-Based Deep Learning", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The research of metamaterial shows great potential in the field of solar energy harvesting. In the past decade, the design of broadband solar metamaterial absorber (SMA) has attracted a surge of interest. The conventional design typically requires brute-force optimizations with a huge sampling space of structure parameters. Very recently, deep learning (DL) has provided a promising way in metamaterial design, but its application on SMA development is barely reported due to the complicated features of broadband spectrum. Here, this work develops the DL model based on metamaterial spectrum transformer (MST) for the powerful design of high-performance SMAs. The MST divides the optical spectrum of metamaterial into N patches, which overcomes the severe problem of overfitting in traditional DL and boosts the learning capability significantly. A flexible design tool based on free customer definition is developed to facilitate the real-time on-demand design of metamaterials with various optical functions. The scheme is applied to the design and fabrication of SMAs with graded-refractive-index nullostructures. They demonstrate the high average absorptance of 94% in a broad solar spectrum and exhibit exceptional advantages over many state-of-the-art counterparts. The outdoor testing implies the high-efficiency energy collection of about 1061 kW h m(-2) from solar radiation annually. This work paves a way for the rapid smart design of SMA, and will also provide a real-time developing tool for many other metamaterials and metadevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206718", "DOI Link": "http://dx.doi.org/10.1002/advs.202206718", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939817700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YJ; Xiao, TX; Chen, S; Xie, ZW; Zheng, J; Zhu, JQ; Su, YR; Chen, WD; Liu, K; Tang, MJ; Müller-Buschbaum, P; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yijia; Xiao, Tianxiao; Chen, Shuai; Xie, Zhengwei; Zheng, Jie; Zhu, Jianqi; Su, Yarong; Chen, Weidong; Liu, Ke; Tang, Mingjun; Mueller-Buschbaum, Peter; Li, Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-optical controlled-NOT logic gate achieving directional asymmetric transmission based on metasurface doublet", "Source Title": "OPTO-ELECTRONIC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical logic gates play important roles in all-optical logic circuits, which lie at the heart of the next-generation optical computing technology. However, the intrinsic contradiction between compactness and robustness hinders the develop-ment in this field. Here, we propose a simple design principle that can possess multiple-input-output states according to the incident circular polarization and direction based on the metasurface doublet, which enables controlled-NOT logic gates in infrared region. Therefore, the directional asymmetric electromagnetic transmission can be achieved. As a proof of concept, a spin-dependent Janus metasurface is designed and experimentally verified that four distinct images corres-ponding to four input states can be captured in the far-field. In addition, since the design method is derived from geomet-ric optics, it can be easily applied to other spectra. We believe that the proposed metasurface doublet may empower many potential applications in chiral imaging, chiroptical spectroscopy and optical computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2023, "Volume": 6, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 220073, "DOI": "10.29026/oea.2023.220073", "DOI Link": "http://dx.doi.org/10.29026/oea.2023.220073", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001039337300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gjerding, MN; Taghizadeh, A; Rasmussen, A; Ali, S; Bertoldo, F; Deilmann, T; Knosgaard, NR; Kruse, M; Larsen, AH; Manti, S; Pedersen, TG; Petralanda, U; Skovhus, T; Svendsen, MK; Mortensen, JJ; Olsen, T; Thygesen, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gjerding, Morten Niklas; Taghizadeh, Alireza; Rasmussen, Asbjorn; Ali, Sajid; Bertoldo, Fabian; Deilmann, Thorsten; Knosgaard, Nikolaj Rorbaek; Kruse, Mads; Larsen, Ask Hjorth; Manti, Simone; Pedersen, Thomas Garm; Petralanda, Urko; Skovhus, Thorbjorn; Svendsen, Mark Kamper; Mortensen, Jens Jorgen; Olsen, Thomas; Thygesen, Kristian Sommer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress of the computational 2D materials database (C2DB)", "Source Title": "2D MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Computational 2D Materials Database (C2DB) is a highly curated open database organising a wealth of computed properties for more than 4000 atomically thin two-dimensional (2D) materials. Here we report on new materials and properties that were added to the database since its first release in 2018. The set of new materials comprise several hundred monolayers exfoliated from experimentally known layered bulk materials, (homo)bilayers in various stacking configurations, native point defects in semiconducting monolayers, and chalcogen/halogen Janus monolayers. The new properties include exfoliation energies, Bader charges, spontaneous polarisations, Born charges, infrared polarisabilities, piezoelectric tensors, band topology invariants, exchange couplings, Raman spectra and second harmonic generation spectra. We also describe refinements of the employed material classification schemes, upgrades of the computational methodologies used for property evaluations, as well as significant enhancements of the data documentation and provenullce. Finally, we explore the performance of Gaussian process-based regression for efficient prediction of mechanical and electronic materials properties. The combination of open access, detailed documentation, and extremely rich materials property data sets make the C2DB a unique resource that will advance the science of atomically thin materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 350, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 44002, "DOI": "10.1088/2053-1583/ac1059", "DOI Link": "http://dx.doi.org/10.1088/2053-1583/ac1059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000675525600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jun, SE; Kim, YH; Kim, J; Cheon, WS; Choi, S; Yang, J; Park, H; Lee, H; Park, SH; Kwon, KC; Moon, J; Kim, SH; Jang, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jun, Sang Eon; Kim, Youn-Hye; Kim, Jaehyun; Cheon, Woo Seok; Choi, Sungkyun; Yang, Jinwook; Park, Hoonkee; Lee, Hyungsoo; Park, Sun Hwa; Kwon, Ki Chang; Moon, Jooho; Kim, Soo-Hyun; Jang, Ho Won", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed iridium catalysts on silicon photoanode for efficient photoelectrochemical water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stabilizing atomically dispersed single atoms (SAs) on silicon photoanodes for photoelectrochemical-oxygen evolution reaction is still challenging due to the scarcity of anchoring sites. Here, we elaborately demonstrate the decoration of iridium SAs on silicon photoanodes and assess the role of SAs on the separation and transfer of photogenerated charge carriers. NiO/Ni thin film, an active and highly stable catalyst, is capable of embedding the iridium SAs in its lattices by locally modifying the electronic structure. The isolated iridium SAs enable the effective photogenerated charge transport by suppressing the charge recombination and lower the thermodynamic energy barrier in the potential-determining step. The Ir SAs/NiO/Ni/ZrO2/n-Si photoanode exhibits a benchmarking photoelectrochemical performance with a high photocurrent density of 27.7mAcm(-2) at 1.23V vs. reversible hydrogen electrode and 130h stability. This study proposes the rational design of SAs on silicon photoelectrodes and reveals the potential of the iridium SAs to boost photogenerated charge carrier kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 609, "DOI": "10.1038/s41467-023-36335-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36335-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001024149400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, G; Robert, C; Glazov, MM; Cadiz, F; Courtade, E; Amand, T; Lagarde, D; Taniguchi, T; Watanabe, K; Urbaszek, B; Marie, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, G.; Robert, C.; Glazov, M. M.; Cadiz, F.; Courtade, E.; Amand, T.; Lagarde, D.; Taniguchi, T.; Watanabe, K.; Urbaszek, B.; Marie, X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-Plane Propagation of Light in Transition Metal Dichalcogenide Monolayers: Optical Selection Rules", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The optical selection rules for interband transitions in WSe2, WS2, and MoSe2 transition metal dichalcogenide monolayers are investigated by polarization-resolved photoluminescence experiments with a signal collection from the sample edge. These measurements reveal a strong polarization dependence of the emission lines. We see clear signatures of the emitted light with the electric field oriented perpendicular to the monolayer plane, corresponding to an interband optical transition forbidden at normal incidence used in standard optical spectroscopy measurements. The experimental results are in agreement with the optical selection rules deduced from group theory analysis, highlighting the key role played by the different symmetries of the conduction and valence bands split by the spin-orbit interaction. These studies yield a direct determination of the bright-dark exciton splitting, for which we measure 40 +/- 1 meV and 55 +/- 2 meV in WSe2 and WS2 monolayer, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 26", "Publication Year": 2017, "Volume": 119, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 47401, "DOI": "10.1103/PhysRevLett.119.047401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.047401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406334600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, Z; Zhang, J; Luo, HJ; Yao, YH; Wang, N; Chen, L; Li, TY; Hu, CZ; Qi, H; Deng, SQ; Gallington, LC; Zhang, YP; Neuefeind, JC; Liu, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zheng; Zhang, Ji; Luo, Huajie; Yao, Yonghao; Wang, Na; Chen, Liang; Li, Tianyu; Hu, Changzheng; Qi, He; Deng, Shiqing; Gallington, Leighanne C.; Zhang, Yuanpeng; Neuefeind, Joerg C.; Liu, Hui; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior Capacitive Energy-Storage Performance in Pb-Free Relaxors with a Simple Chemical Composition", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical design of lead-free relaxors with simultaneously high energy density (Wrec) and high efficiency (eta) for capacitive energy-storage has been a big challenge for advanced electronic systems. The current situation indicates that realizing such superior energy-storage properties requires highly complex chemical components. Herein, we demonstrate that, via local structure design, an ultrahigh Wrec of 10.1 J/cm3, concurrent with a high eta of 90%, as well as excellent thermal and frequency stabilities can be achieved in a relaxor with a very simple chemical composition. By introducing 6s2 lone pair stereochemical active Bi into the classical BaTiO3 ferroelectric to generate a mismatch between A-and B site polar displacements, a relaxor state with strong local polar fluctuations can be formed. Through advanced atomic-resolution displacement mapping and 3D reconstructing the nulloscale structure from neutron/X-ray total scattering, it is revealed that the localized Bi enhances the polar length largely at several perovskite unit cells and disrupts the long-range coherent Ti polar displacements, resulting in a slush-like structure with extremely small size polar clusters and strong local polar fluctuations. This favorable relaxor state exhibits substantially enhanced polarization, and minimized hysteresis at a high breakdown strength. This work offers a feasible avenue to chemically design new relaxors with a simple composition for high-performance capacitive energy-storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2023, "Volume": 145, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6194, "End Page": 6202, "Article Number": null, "DOI": "10.1021/jacs.2c12200", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c12200", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948786900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brennull, MC; Draguta, S; Kamat, PV; Kuno, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brennull, Michael C.; Draguta, Sergiu; Kamat, Prashant V.; Kuno, Masaru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-Induced Anion Phase Segregation in Mixed Halide Perovskites", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid lead halide perovskites such as MAPbI(3) (MA = CH3NH3+) and their mixed halide analogues represent an emerging class of materials for solar energy conversion. Intriguing aspects include sizable carrier diffusion lengths, large optical absorption coefficients, and certified power conversion efficiencies that now exceed 22%. Halide-composition-tunable band gaps also make MAPb(I1-x,Br-x)(3) systems ideal candidates for tandem solar cells. Unfortunately, preventing the effective integration of MAPb(I1-xBrx)(3) into working devices are intrinsic instabilities due to light-induced halide phase segregation. Namely, under illumination, mixed halide perovskites reversibly segregate into low-band-gap I-rich and high-band-gap Br-rich domains. Under electrical bias, halide migration has also been proposed as the source of undesirable charge injection barriers that degrade photovoltaic performance. In this Perspective, we review the origin of light-induced halide phase segregation, its effects on photovoltaic response, and ongoing research to suppress its influence on the optical and electronic response of mixed halide perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 531, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 213, "Article Number": null, "DOI": "10.1021/acsenergylett.7b01151", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b01151", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422814500031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Mao-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Density Functional Calculations of Native Defects in CH3NH3Pbl3: Effects of Spin-Orbit Coupling and Self-Interaction Error", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Native point defects play an important role in carrier transport properties of CH3NH3PbI3. However, the nature of many important defects remains controversial due partly to the conflicting results reported by recent density functional theory (DFT) calculations. In this Letter, we show that self-interaction error and the neglect of spin-orbit coupling (SOC) in many previous DFT calculations resulted in incorrect positions of valence and conduction band edges, although their difference, which is the band gap, is in good agreement with the experimental value. This problem has led to incorrect predictions of defect-level positions. Hybrid density functional calculations, which partially correct the self-interaction error and include the SOC, show that, among native point defects (including vacancies, interstitials, and antisites), only the iodine vacancy and its complexes induce deep electron and hole trapping levels inside of the band gap, acting as nonradiative recombination centers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2015, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1461, "End Page": 1466, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b00199", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b00199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353250500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chumak, AV; Serga, AA; Hillebrands, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chumak, Andrii V.; Serga, Alexander A.; Hillebrands, Burkard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnon transistor for all-magnon data processing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An attractive direction in next-generation information processing is the development of systems employing particles or quasiparticles other than electrons-ideally with low dissipation-as information carriers. One such candidate is the magnon: the quasiparticle associated with the eigen-excitations of magnetic materials known as spin waves. The realization of single-chip all-magnon information systems demands the development of circuits in which magnon currents can be manipulated by magnons themselves. Using a magnonic crystal-an artificial magnetic material-to enhance nonlinear magnon-magnon interactions, we have succeeded in the realization of magnon-by-magnon control, and the development of a magnon transistor. We present a proof of concept three-terminal device fabricated from an electrically insulating magnetic material. We demonstrate that the density of magnons flowing from the transistor's source to its drain can be decreased three orders of magnitude by the injection of magnons into the transistor's gate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 682, "Times Cited, All Databases": 729, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4700, "DOI": "10.1038/ncomms5700", "DOI Link": "http://dx.doi.org/10.1038/ncomms5700", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341078700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Caprioglio, P; Stolterfoht, M; Wolff, CM; Unold, T; Rech, B; Albrecht, S; Neher, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Caprioglio, Pietro; Stolterfoht, Martin; Wolff, Christian M.; Unold, Thomas; Rech, Bernd; Albrecht, Steve; Neher, Dieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the Relation between the Open-Circuit Voltage and Quasi-Fermi Level Splitting in Efficient Perovskite Solar Cells", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Today's perovskite solar cells (PSCs) are limited mainly by their open-circuit voltage (V-OC) due to nonradiative recombination. Therefore, a comprehensive understanding of the relevant recombination pathways is needed. Here, intensity-dependent measurements of the quasi-Fermi level splitting (QFLS) and of the V-OC on the very same devices, including pin-type PSCs with efficiencies above 20%, are performed. It is found that the QFLS in the perovskite lies significantly below its radiative limit for all intensities but also that the V-OC is generally lower than the QFLS, violating one main assumption of the Shockley-Queisser theory. This has far-reaching implications for the applicability of some well-established techniques, which use the V-OC as a measure of the carrier densities in the absorber. By performing drift-diffusion simulations, the intensity dependence of the QFLS, the QFLS-V-OC offset and the ideality factor are consistently explained by trap-assisted recombination and energetic misalignment at the interfaces. Additionally, it is found that the saturation of the V-OC at high intensities is caused by insufficient contact selectivity while heating effects are of minor importance. It is concluded that the analysis of the V-OC does not provide reliable conclusions of the recombination pathways and that the knowledge of the QFLS-V-OC relation is of great importance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2019, "Volume": 9, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901631, "DOI": "10.1002/aenm.201901631", "DOI Link": "http://dx.doi.org/10.1002/aenm.201901631", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478333300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Strelcov, E; Dong, QF; Li, T; Chae, J; Shao, YC; Deng, YH; Gruverman, A; Huang, JS; Centrone, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Strelcov, Evgheni; Dong, Qingfeng; Li, Tao; Chae, Jungseok; Shao, Yuchuan; Deng, Yehao; Gruverman, Alexei; Huang, Jinsong; Centrone, Andrea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CH3NH3PbI3 perovskites: Ferroelasticity revealed", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectricity has been proposed as a plausible mechanism to explain the high photovoltaic conversion efficiency in organic-inorganic perovskites; however, convincing experimental evidence in support of this hypothesis is still missing. Identifying and distinguishing ferroelectricity from other properties, such as piezoelectricity, ferroelasticity, etc., is typically nontrivial because these phenomena can coexist in many materials. In this work, a combination of microscopic and nulloscale techniques provides solid evidence for the existence of ferroelastic domains in both CH3NH3PbI3 polycrystalline films and single crystals in the pristine state and under applied stress. Experiments show that the configuration of CH3NH3PbI3 ferroelastic domains in single crystals and polycrystalline films can be controlled with applied stress, suggesting that strain engineering may be used to tune the properties of this material. No evidence of concomitant ferroelectricity was observed. Because grain boundaries have an impact on the long-term stability of organic-inorganic perovskite devices, and because the ferroelastic domain boundaries may differ from regular grain boundaries, the discovery of ferroelasticity provides a new variable to consider in the quest for improving their stability and enabling their widespread adoption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602165", "DOI": "10.1126/sciadv.1602165", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, W; Wang, M; Ambrosi, E; Bricalli, A; Laudato, M; Sun, Z; Chen, XD; Ielmini, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wei; Wang, Ming; Ambrosi, Elia; Bricalli, Alessandro; Laudato, Mario; Sun, Zhong; Chen, Xiaodong; Ielmini, Daniele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface diffusion-limited lifetime of silver and copper nullofilaments in resistive switching devices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silver/copper-filament-based resistive switching memory relies on the formation and disruption of a metallic conductive filament (CF) with relatively large surface-to-volume ratio. The nulloscale CF can spontaneously break after formation, with a lifetime ranging from few microseconds to several months, or even years. Controlling and predicting the CF lifetime enables device engineering for a wide range of applications, such as non-volatile memory for data storage, tunable short/long term memory for synaptic neuromorphic computing, and fast selection devices for crosspoint arrays. However, conflictive explanations for the CF retention process are being proposed. Here we show that the CF lifetime can be described by a universal surface-limited self-diffusion mechanism of disruption of the metallic CF. The surface diffusion process provides a new perspective of ion transport mechanism at the nulloscale, explaining the broad range of reported lifetimes, and paving the way for material engineering of resistive switching device for memory and computing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 81, "DOI": "10.1038/s41467-018-07979-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07979-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455102900020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rosenkranz, A; Righi, MC; Sumant, AV; Anasori, B; Mochalin, VN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rosenkranz, Andreas; Righi, Maria Clelia; Sumant, Anirudha V. V.; Anasori, Babak; Mochalin, Vadym N. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspectives of 2D MXene Tribology", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large and rapidly growing family of 2D early transition metal carbides, nitrides, and carbonitrides (MXenes) raises significant interest in the materials science and chemistry of materials communities. Discovered a little more than a decade ago, MXenes have already demonstrated outstanding potential in various applications ranging from energy storage to biology and medicine. The past two years have witnessed increased experimental and theoretical efforts toward studying MXenes' mechanical and tribological properties when used as lubricant additives, reinforcement phases in composites, or solid lubricant coatings. Although research on the understanding of the friction and wear performance of MXenes under dry and lubricated conditions is still in its early stages, it has experienced rapid growth due to the excellent mechanical properties and chemical reactivities offered by MXenes that make them adaptable to being combined with other materials, thus boosting their tribological performance. In this perspective, the most promising results in the area of MXene tribology are summarized, future important problems to be pursued further are outlined, and methodological recommendations that could be useful for experts as well as newcomers to MXenes research, in particular, to the emerging area of MXene tribology, are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 35, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207757", "DOI Link": "http://dx.doi.org/10.1002/adma.202207757", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000900149800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ramalho, A; Santos, TG; Bevans, B; Smoqi, Z; Rao, P; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ramalho, Andre; Santos, Telmo G.; Bevans, Ben; Smoqi, Ziyad; Rao, Prahalad; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of contaminations on the acoustic emissions during wire and arc additive manufacturing of 316L stainless steel", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive Manufacturing (AM) processes allow the creation of complex parts with near net shapes. Wire and arc additive manufacturing (WAAM) is an AM process that can produce large metallic components with low material waste and high production rates. Typically, WAAM enables over 10-times the volumetric deposition rates of powder-based AM processes. However, the high depositions rates of WAAM require high heat input to melt the large volume of material, which in turn results in potential flaws such as pores, cracks, distortion, loss of mechanical properties and low dimensional accuracy. Hence, for practical implementation of the WAAM process in an industrial environment it is necessary to ensure flaw-free production. Accordingly, to guarantee the production-level scalability of WAAM it is fundamental to monitor and detect flaw formation during the process. The objective of this work is to characterize the effects of different contaminations on the acoustic spectrum of WAAM and lay the foundations for a microphone-based acoustic sensing approach for monitoring the quality of WAAM-fabricated parts. To realize this objective, WAAM parts were processed with deliberately introduced flaws, such as material contamination, and the acoustic signals were analyzed using the time and frequency domain techniques, namely, Power Spectral Density, and Short Time Fourier Transform. The signatures obtained were used to pinpoint the location of flaw formation. The results obtained in this study show that the effects of contamination in WAAM can be identified through the analysis of the acoustic spectrum of the process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102585, "DOI": "10.1016/j.addma.2021.102585", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.102585", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787266000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qutub, N; Singh, P; Sabir, S; Sagadevan, S; Oh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qutub, Nida; Singh, Preeti; Sabir, Suhail; Sagadevan, Suresh; Oh, Won-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic degradation of Acid Blue dye using CdS/TiO2 nullocomposite", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic degradation is essential for the successful removal of organic contaminullts from wastewater, which is important for ecological and environmental safety. The advanced oxidation process of photocatalysis has become a hot topic in recent years for the remediation of water. Cadmium sulphide (CdS) nullostructures doped with Titanium oxide (CdS/TiO2) nullocomposites has manufactured under ambient conditions using a simple and modified Chemical Precipitation technique. The nullocomposites crystal structure, thermal stability, recombination of photo-generated charge carriers, bandgap, surface morphology, particle size, molar ratio, and charge transfer properties are determined. The production of nullocomposites (CdS-TiO2) and their efficient photocatalytic capabilities are observed. The goal of the experiment is to improve the photocatalytic efficiency of TiO2 in the visible region by doping CdS nullocomposites. The results showed that as-prepared CdS-TiO2 nullocomposites has exhibited the highest photocatalytic activity in the process of photocatalytic degradation of AB-29 dye, and its degradation efficiency is 84%. After 1 h 30 min of visible light irradiation, while CdS and TiO2 showed only 68% and 09%, respectively. The observed decolorization rate of AB-29 is also higher in the case of CdS-TiO2 photocatalyst similar to 5.8 x 10(-4)mol L-1 min(-1)) as compared to the reported decolorization rate of CdS similar to 4.5 x 10(-4)mol L-1 min(-1) and TiO2 similar to 0.67 x 10(-4)mol L-1 min(-1). This increased photocatalytic effectiveness of CdS-TiO2 has been accomplished by reduced charge carrier recombination as a result of improved charge separation and extension of TiO2 in response to visible light.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5759, "DOI": "10.1038/s41598-022-09479-0", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-09479-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780164200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LG; Nguyen, PX; Wang, ZF; Zeng, YX; Watanabe, K; Taniguchi, T; MacDonald, AH; Mak, KF; Shan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Liguo; Nguyen, Phuong X.; Wang, Zefang; Zeng, Yongxin; Watanabe, Kenji; Taniguchi, Takashi; MacDonald, Allan H.; Mak, Kin Fai; Shan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly correlated excitonic insulator in atomic double layers", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Excitonic insulators (EIs) arise from the formation of bound electron-hole pairs (excitons)(1,2) in semiconductors and provide a solid-state platform for quantum many-boson physics(3-8). Strong exciton-exciton repulsion is expected to stabilize condensed superfluid and crystalline phases by suppressing both density and phase fluctuations(8-11). Although spectroscopic signatures of EIs have been reported(6,12-14), conclusive evidence for strongly correlated EI states has remained elusive. Here we demonstrate a strongly correlated two-dimensional (2D) EI ground state formed in transition metal dichalcogenide (TMD) semiconductor double layers. A quasi-equilibrium spatially indirect exciton fluid is created when the bias voltage applied between the two electrically isolated TMD layers is tuned to a range that populates bound electron-hole pairs, but not free electrons or holes(15-17). Capacitance measurements show that the fluid is exciton-compressible but charge-incompressible-direct thermodynamic evidence of the EI. The fluid is also strongly correlated with a dimensionless exciton coupling constant exceeding 10. We construct an exciton phase diagram that reveals both the Mott transition and interaction-stabilized quasi-condensation. Our experiment paves the path for realizing exotic quantum phases of excitons(8), as well as multi-terminal exciton circuitry for applications(18-20). So far only signatures of excitonic insulators have been reported, but here direct thermodynamic evidence is provided for a strongly correlated excitonic insulating state in transition metal dichalcogenide semiconductor double layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2021, "Volume": 598, "Issue": 7882, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 585, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03947-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03947-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000712433300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, XW; Lu, Y; Shi, JQ; Hao, XY; Ma, ZL; Yang, K; Zhang, TY; Li, C; Zhang, DA; Huang, XL; He, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Xinwu; Lu, Yang; Shi, Junqing; Hao, Xiaoyu; Ma, Zelin; Yang, Ke; Zhang, Tianyi; Li, Chan; Zhang, Dina; Huang, Xiaolei; He, Yibo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion-resistant cobalt phosphide electrocatalysts for salinity tolerance hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater electrolysis is a viable method for producing hydrogen on a large scale and low-cost. However, the catalyst activity during the seawater splitting process will dramatically degrade as salt concentrations increasing. Herein, CoP is discovered that could reject chloride ions far from catalyst in electrolyte based on molecular dynamic simulation. Thus, a binder-free electrode is designed and constructed by in-situ growth of homogeneous CoP on rGO nullosheets wrapped around the surface of Ti fiber felt for seawater splitting. As expected, the as-obtained CoP/rGO@Ti electrode exhibits good catalytic activity and stability in alkaline electrolyte. Especially, benefitting from the highly effective repulsive Cl- intrinsic characteristic of CoP, the catalyst maintains good catalytic performance with saturated salt concentration, and the overpotential increasing is less than 28 mV at 10 mA cm-2 from 0 M to saturated NaCl in electrolyte. Furthermore, the catalyst for seawater splitting performs superior corrosion-resistance with a low solubility of 0.04%. This work sheds fresh light into the development of efficient HER catalysts for salinity tolerance hydrogen evolution. Seawater electrolysis for hydrogen production is limited by the poor salinity tolerance of catalysts. CoP was found to repel chlorine while attracting H2O molecules to form a thin layer on the catalyst surface, thus constructing a corrosion-resistant CoP/rGO@Ti catalyst for seawater splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7708, "DOI": "10.1038/s41467-023-43459-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43459-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001109312400034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Chen, HJ; Du, XZ; Wen, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hui; Chen, Hui-Jivan; Du, Xiaoze; Wen, Dongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photothermal conversion characteristics of gold nulloparticle dispersions", "Source Title": "SOLAR ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work proposes and validates a novel idea of using plasmonic nulloparticles (PNP) to improve the solar thermal conversion efficiency. Gold nulloparticle (GNP) is synthesized from an improved citrate-reduction method, and used as an example to illustrate the photothermal conversion characteristics of PNPs under a solar simulator. The experimental results show that GNP has the best photo-thermal conversion capability comparing to other reported materials. At the lowest particle concentration examined (i.e., 0.15 ppm), GNP increases the photo-thermal conversion efficiency of the base fluid by 20% and reaches a specific absorption rate (SAR) of similar to 10 kW/g. The photo-thermal conversion efficiency increases with increasing particle concentrations, but the SAR shows a reverse trend, which is unexpected as all GNPs should be still in the independent scattering regime. (C) 2013 Elsevier Ltd. All rights reserved..", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 141, "End Page": 147, "Article Number": null, "DOI": "10.1016/j.solener.2013.12.004", "DOI Link": "http://dx.doi.org/10.1016/j.solener.2013.12.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331007700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dastafkan, K; Shen, XJ; Hocking, RK; Meyer, Q; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dastafkan, Kamran; Shen, Xiangjian; Hocking, Rosalie K.; Meyer, Quentin; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monometallic interphasic synergy via nullo-hetero-interfacing for hydrogen evolution in alkaline electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic synergy is a functional yet underrated concept in electrocatalysis. Often, it materializes as intermetallic interaction between different metals. We demonstrate interphasic synergy in monometallic structures is as much effective. An interphasic synergy between Ni(OH)(2) and Ni-N/Ni-C phases is reported for alkaline hydrogen evolution reaction that lowers the energy barriers for hydrogen adsorption-desorption and facilitates that of hydroxyl intermediates. This makes ready-to-serve Ni active sites and allocates a large amount of Ni d-states at Fermi level to promote charge redistribution from Ni(OH)(2) to Ni-N/Ni-C and the co-adsorption of H-ads and OHads intermediates on Ni-N/Ni-C moieties. As a result, a Ni(OH)(2)@Ni-N/Ni-C hetero-hierarchical nullostructure is developed, lowering the overpotentials to deliver -10 and -100mA cm(-2) in alkaline media by 102 and 113mV, respectively, compared to monophasic Ni(OH)(2) catalyst. This study unveils the interphasic synergy as an effective strategy to design monometallic electrocatalysts for water splitting and other energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 547, "DOI": "10.1038/s41467-023-36100-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36100-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001034930800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tatara, R; Karayaylali, P; Yu, Y; Zhang, YR; Giordano, L; Maglia, F; Jung, R; Schmidt, JP; Lund, I; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tatara, Ryoichi; Karayaylali, Pinar; Yu, Yang; Zhang, Yirui; Giordano, Livia; Maglia, Filippo; Jung, Roland; Schmidt, Jan Philipp; Lund, Isaac; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Effect of Electrode-Electrolyte Interface on the Electrochemical Impedance Spectra for Positive Electrode in Li-Ion Battery", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the effect of electrode-electrolyte interface (EEI) on the kinetics of electrode reaction is critical to design high-energy Li-ion batteries. While electrochemical impedance spectroscopy (EIS) is used widely to examine the kinetics of electrode reaction in Li-ion batteries, ambiguities exist in the physical origin of EIS responses for composite electrodes. In this study, we performed EIS measurement by using a three-electrode cell with a mesh-reference electrode, to avoid the effect of counter electrode impedance and artefactual responses due to asymmetric cell configuration, and composite or oxide-only working electrodes. Here we discuss the detailed assignment of impedance spectra for LiCoO2 as a function of voltage. The high-frequency semicircle was assigned to the impedance associated with ion adsorption and desorption at the electrified interface while the low-frequency semicircle was related to the charge transfer impedance associated with desolvation/solvation of lithium ions, and lithium ion intercalation/de-intercalation into/from LixCoO(2). Exposure to higher charging voltages and greater hold time at high voltages led to no significant change for the high-frequency component but greater resistance and greater activation energy for the low-frequency circle. The greater charge transfer impedance was attributed to the growth of EEI layers on the charged LixCoO(2) surface associated with electrolyte oxidation promoted by ethylene carbonate dehydrogenation. (C) The Author(s) 2018. Published by ECS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2018, "Volume": 166, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A5090", "End Page": "A5098", "Article Number": null, "DOI": "10.1149/2.0121903jes", "DOI Link": "http://dx.doi.org/10.1149/2.0121903jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451414500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QL; Zou, HY; Mao, X; He, JH; Shi, YM; Chen, SM; Yan, XC; Wu, LY; Lang, CG; Zhang, B; Song, L; Wang, X; Du, AJ; Li, Q; Jia, Y; Chen, J; Yao, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qilong; Zou, Haiyuan; Mao, Xin; He, Jinghan; Shi, Yanmei; Chen, Shuangming; Yan, Xuecheng; Wu, Liyun; Lang, Chengguang; Zhang, Bin; Song, Li; Wang, Xin; Du, Aijun; Li, Qin; Jia, Yi; Chen, Jun; Yao, Xiangdong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the dynamic active site of defective carbon-based electrocatalysts for hydrogen peroxide production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active sites identification in metal-free carbon materials is crucial for developing practical electrocatalysts, but resolving precise configuration of active site remains a challenge because of the elusive dynamic structural evolution process during reactions. Here, we reveal the dynamic active site identification process of oxygen modified defective graphene. First, the defect density and types of oxygen groups were precisely manipulated on graphene, combined with electrocatalytic performance evaluation, revealing a previously overlooked positive correlation relationship between the defect density and the 2 e- oxygen reduction performance. An electrocatalytic-driven oxygen groups redistribution phenomenon was observed, which narrows the scope of potential configurations of the active site. The dynamic evolution processes are monitored via multiple in-situ technologies and theoretical spectra simulations, resolving the configuration of major active sites (carbonyl on pentagon defect) and key intermediates (*OOH), in-depth understanding the catalytic mechanism and providing a research paradigm for metal-free carbon materials. Active sites identification in metal-free carbon materials is crucial for developing practical electrocatalysts. Here the authors report a dynamic active site evolution phenomenon on oxygen modified defective graphene during electrochemical H2O2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6275, "DOI": "10.1038/s41467-023-41947-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41947-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142358600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nicolas, A; Ferrero, EE; Martens, K; Barrat, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nicolas, Alexandre; Ferrero, Ezequiel E.; Martens, Kirsten; Barrat, Jean-Louis", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deformation and flow of amorphous solids: Insights from elastoplastic models", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The deformation and flow of disordered solids, such as metallic glasses and concentrated emulsions, involves swift localized rearrangements of particles that induce a long-range deformation field. To describe these heterogeneous processes, elastoplastic models handle the material as a collection of mesoscopic blocks alternating between an elastic behavior and plastic relaxation, when they are loaded above a threshold. Plastic relaxation events redistribute stresses in the system in a very anisotropic way. A review is given of not only the physical insight provided by these models into practical issues such as strain localization, creep, and steady-state rheology, but also the fundamental questions that they address with respect to criticality at the yielding point and the statistics of avalanches of plastic events. Furthermore, connections are discussed with concurrent mean-field approaches and with related problems such as the plasticity of crystals and the depinning of an elastic line.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 26", "Publication Year": 2018, "Volume": 90, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45006, "DOI": "10.1103/RevModPhys.90.045006", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.045006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454435700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Slotwinski, JA; Garboczi, EJ; Hebenstreit, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Slotwinski, John A.; Garboczi, Edward J.; Hebenstreit, Keith M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porosity Measurements and Analysis for Metal Additive Manufacturing Process Control", "Source Title": "JOURNAL OF RESEARCH OF THE NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing techniques can produce complex, high-value metal parts, with potential applications as critical metal components such as those found in aerospace engines and as customized biomedical implants. Material porosity in these parts is undesirable for aerospace parts - since porosity could lead to premature failure - and desirable for some biomedical implants - since surface-breaking pores allows for better integration with biological tissue. Changes in a part's porosity during an additive manufacturing build may also be an indication of an undesired change in the build process. Here, we present efforts to develop an ultrasonic sensor for monitoring changes in the porosity in metal parts during fabrication on a metal powder bed fusion system. The development of well-characterized reference samples, measurements of the porosity of these samples with multiple techniques, and correlation of ultrasonic measurements with the degree of porosity are presented. A proposed sensor design, measurement strategy, and future experimental plans on a metal powder bed fusion system are also presented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2014, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 494, "End Page": 528, "Article Number": null, "DOI": "10.6028/jres.119.019", "DOI Link": "http://dx.doi.org/10.6028/jres.119.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350402800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Myers, PD; Goswami, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Myers, Philip D., Jr.; Goswami, D. Yogi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal energy storage using chloride salts and their eutectics", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving the goals of the U.S. Department of Energy (DOE) Sunshot initiative requires (1) higher operating temperatures for concentrating solar power (CSP) plants to increase theoretical efficiency, and (2) effective thermal energy storage (TES) strategies to ensure dispatchability. Current inorganic salt-based TES systems in large-scale CSP plants generally employ molten nitrate salts for energy storage, but nitrate salts are limited in application to lower temperatures-generally, below 600 degrees C. These materials are sufficient for parabolic trough power plants, but they are inadequate for use at higher temperatures. At the higher operating temperatures achievable in solar power tower-type CSP plants, chloride salts are promising candidates for application as TES materials, owing to their thermal stability and generally lower cost compared to nitrate salts. In light of this, a recent study was conducted, which included a preliminary survey of chloride salts and binary eutectic systems that show promise as high temperature TES media. This study provided some basic information about the salts, including phase equilibria data and estimates of latent heat of fusion for some of the eutectics. Cost estimates were obtained through a review of bulk pricing for the pure salts among various vendors. This review paper updates that prior study, adding data for additional salt eutectic systems obtained from the literature. Where possible, data are obtained from the thermodynamic database software, FactSage. Radiative properties are presented, as well, since at higher temperatures, thermal radiation becomes a significant mode of heat transfer. Material compatibility for inorganic salts is another important consideration (e.g., with regard to piping and/or containment), so a summary of corrosion studies with various materials is also presented. Lastly, cost data for these systems are presented, allowing for meaningful comparison among these systems and other materials for TES applications. Because chloride salts may be employed as either sensible heat storage in the molten phase or as sensible and latent heat thermal energy storage (LHTES) as phase change materials (PCMs), cost of the candidate salt systems are presented on a cost per unit mass basis (sensible heat storage application) and a cost per unit latent heat of fusion basis (latent heat storage application). A total of 133 chloride salt systems were investigated. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2016, "Volume": 109, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 889, "End Page": 900, "Article Number": null, "DOI": "10.1016/j.applthermaleng.2016.07.046", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2016.07.046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386738600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oh, M; Nuckolls, KP; Wong, D; Lee, RL; Liu, XM; Watanabe, K; Taniguchi, T; Yazdani, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oh, Myungchul; Nuckolls, Kevin P.; Wong, Dillon; Lee, Ryan L.; Liu, Xiaomeng; Watanabe, Kenji; Taniguchi, Takashi; Yazdani, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for unconventional superconductivity in twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of superconductivity and correlated insulators in magic-angle twisted bilayer graphene (MATBG) has raised the intriguing possibility that its pairing mechanism is distinct from that of conventional superconductors(1-4), as described by the Bardeen-Cooper-Schrieffer (BCS) theory. However, recent studies have shown that superconductivity persists even when Coulomb interactions are partially screened(5,6). This suggests that pairing in MATBG might be conventional in nature and a consequence of the large density of states of its flat bands. Here we combine tunnelling and Andreev reflection spectroscopy with a scanning tunnelling microscope to observe several key experimental signatures of unconventional superconductivity in MATBG. We show that the tunnelling spectra below the transition temperature T-c are inconsistent with those of a conventional s-wave superconductor, but rather resemble those of a nodal superconductor with an anisotropic pairing mechanism. We observe a large discrepancy between the tunnelling gap Delta(T), which far exceeds the mean-field BCS ratio (with 2 Delta(T)/k(B)T(c) similar to 25), and the gap Delta(AR) extracted from Andreev reflection spectroscopy (2 Delta(AR)/k(B)T(c) similar to 6). The tunnelling gap persists even when superconductivity is suppressed, indicating its emergence from a pseudogap phase. Moreover, the pseudogap and superconductivity are both absent when MATBG is aligned with hexagonal boron nitride. These findings and other observations reported here provide a preponderance of evidence for a non-BCS mechanism for superconductivity in MATBG.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 9", "Publication Year": 2021, "Volume": 600, "Issue": 7888, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04121-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04121-x", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000724704000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moseenkov, SI; Kuznetsov, VL; Zolotarev, NA; Kolesov, BA; Prosvirin, IP; Ishchenko, AV; Zavorin, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moseenkov, S. I.; Kuznetsov, V. L.; Zolotarev, N. A.; Kolesov, B. A.; Prosvirin, I. P.; Ishchenko, A. V.; Zavorin, A. V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation of Amorphous Carbon in nullostructured Carbon Materials (A Comparative Study by TEM, XPS, Raman Spectroscopy and XRD)", "Source Title": "MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Amorphous carbon (AC) is present in the bulk and on the surface of nullostructured carbon materials (NCMs) and exerts a significant effect on the physical, chemical and mechanical properties of NCMs. Thus, the determination of AC in NCMs is extremely important for controlling the properties of a wide range of materials. In this work, a comparative study of the effect of heat treatment on the structure and content of amorphous carbon in deposited AC film, nullodiamonds, carbon black and multiwalled carbon nullotube samples was carried out by TEM, XPS, XRD and Raman spectroscopy. It has been established that the use of the 7-peak model for fitting the Raman spectra makes it possible not only to isolate the contribution of the modes of amorphous carbon but also to improve the accuracy of fitting the fundamental G and D-2 (D) modes and obtain a satisfactory convergence between XPS and Raman spectroscopy. The use of this model for fitting the Raman spectra of deposited AC film, ND, CB and MWCNT films demonstrated its validity and effectiveness for investigating the amorphous carbon in various carbon systems and its applicability in comparative studies of other NCMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 16, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1112, "DOI": "10.3390/ma16031112", "DOI Link": "http://dx.doi.org/10.3390/ma16031112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930392300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, FP; Peng, XY; Hu, LZ; Yang, B; Li, ZJ; Dong, CL; Chen, EL; Hsu, LC; Lei, LC; Zheng, Q; Qiu, M; Dai, LM; Hou, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Fanpeng; Peng, Xianyun; Hu, Lingzi; Yang, Bin; Li, Zhongjian; Dong, Chung-Li; Chen, Jeng-Lung; Hsu, Liang-Ching; Lei, Lecheng; Zheng, Qiang; Qiu, Ming; Dai, Liming; Hou, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated water activation and stabilized metal-organic framework via constructing triangular active-regions for ampere-level current density hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional metal-organic frameworks (MOFs) have been explored as effective electrocatalysts for hydrogen evolution reaction (HER). However, the sluggish water activation kinetics and structural instability under ultrahigh-current density hinder their large-scale industrial applications. Herein, we develop a universal ligand regulation strategy to build well-aligned Ni-benzenedicarboxylic acid (BDC)-based MOF nullosheet arrays with S introducing (S-NiBDC). Benefiting from the closer p-band center to the Fermi level with strong electron transferability, S-NiBDC array exhibits a low overpotential of 310 mV to attain 1.0 A cm(-2) with high stability in alkaline electrolyte. We speculate the newly-constructed triangular Ni-2-S-1 motif as the improved HER active region based on detailed mechanism analysis and structural characterization, and the enhanced covalency of Ni-O bonds by S introducing stabilizes S-NiBDC structure. Experimental observations and theoretical calculations elucidate that such Ni sites in Ni-2-S-1 center distinctly accelerate the water activation kinetics, while the S site readily captures the H atom as the optimal HER active site, boosting the whole HER activity. The sluggish water activation kinetics and instability of metal-organic frameworks for hydrogen evolution reaction limit their industrial applications. Here, authors construct a unique triangular active region to accelerate the crucial water activation and stabilize metal-organic frameworks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6486, "DOI": "10.1038/s41467-022-34278-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-34278-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000885163200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, XD; Zhang, W; Chen, Y; Oliveira, JP; Zeng, Z; Li, Y; Luo, Z; Ao, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Xinde; Zhang, Wei; Chen, Yi; Oliveira, J. P.; Zeng, Zhi; Li, Yang; Luo, Zhen; Ao, Sansan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire-based directed energy deposition of NiTiTa shape memory alloys: Microstructure, phase transformation, electrochemistry, X-ray visibility and mechanical properties", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wire and arc additive manufacturing (WAAM) technology was used for the fabrication of NiTiTa (2.5 at. % Ta) shape memory alloys (SMAs) for the first time, using commercialy available NiTi wire and Ta foil as the feedstock materials. The addition of Ta significantly increased the phase transformation temperatures, leading to a room -temperature microstructure composed of both B19 ' martensite and B2 austenite, and (Ti,Ta)2Ni precipitates distributed at the grain boundaries. Compared with the WAAM fabricated NiTi counterpart, the corrosion po-tential (Ecorr) of the NiTiTa material increased from -0.55 to -0.44 V, while the corrosion current density (Icorr) decreased from 1.90 x 10-6 to 4.2 x 10- 7 A/cm2. The X-ray brightness increased from 19.6 to 56.4 %. These results indicate that the addition of Ta can enhance the corrosion resistance and X-ray visibility of NiTiTa parts. Furthermore, the WAAM fabricated NiTiTa material was able to retain a stable superelastic response under 10 loading-unloading cycles, highlighting the great potential application value in the biomedical field. Our work provides an innovative method for additively manufacturing NiTi-based multi-component SMAs through WAAM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 59, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103115, "DOI": "10.1016/j.addma.2022.103115", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2022.103115", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000869763200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nakayama, K; Miyata, Y; Phan, GN; Sato, T; Tanabe, Y; Urata, T; Tanigaki, K; Takahashi, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nakayama, K.; Miyata, Y.; Phan, G. N.; Sato, T.; Tanabe, Y.; Urata, T.; Tanigaki, K.; Takahashi, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstruction of Band Structure Induced by Electronic Nematicity in an FeSe Superconductor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have performed high-resolution angle-resolved photoemission spectroscopy on an FeSe superconductor (T-c similar to 8 K), which exhibits a tetragonal-to-orthorhombic structural transition at T-s similar to 90 K. At low temperature, we found splitting of the energy bands as large as 50 meVat the M point in the Brillouin zone, likely caused by the formation of electronically driven nematic states. This band splitting persists up to T similar to 110 K, slightly above T-s, suggesting that the structural transition is triggered by the electronic nematicity. We have also revealed that at low temperature the band splitting gives rise to a van Hove singularity within 5 meV of the Fermi energy. The present result strongly suggests that this unusual electronic state is responsible for the unconventional superconductivity in FeSe.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 239, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2014, "Volume": 113, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 237001, "DOI": "10.1103/PhysRevLett.113.237001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.237001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346836400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ko, TW; Finkler, JA; Goedecker, S; Behler, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ko, Tsz Wai; Finkler, Jonas A.; Goedecker, Stefan; Behler, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fourth-generation high-dimensional neural network potential with accurate electrostatics including non-local charge transfer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning potentials have become an important tool for atomistic simulations in many fields, from chemistry via molecular biology to materials science. Most of the established methods, however, rely on local properties and are thus unable to take global changes in the electronic structure into account, which result from long-range charge transfer or different charge states. In this work we overcome this limitation by introducing a fourth-generation high-dimensional neural network potential that combines a charge equilibration scheme employing environment-dependent atomic electronegativities with accurate atomic energies. The method, which is able to correctly describe global charge distributions in arbitrary systems, yields much improved energies and substantially extends the applicability of modern machine learning potentials. This is demonstrated for a series of systems representing typical scenarios in chemistry and materials science that are incorrectly described by current methods, while the fourth-generation neural network potential is in excellent agreement with electronic structure calculations. Machine learning potentials do not account for long-range charge transfer. Here the authors introduce a fourth-generation high-dimensional neural network potential including non-local information of charge populations that is able to provide forces, charges and energies in excellent agreement with DFT data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 398, "DOI": "10.1038/s41467-020-20427-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20427-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609615100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tietze, ML; Benduhn, J; Pahner, P; Nell, B; Schwarze, M; Kleemann, H; Krammer, M; Zojer, K; Vandewal, K; Leo, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tietze, Max L.; Benduhn, Johannes; Pahner, Paul; Nell, Bernhard; Schwarze, Martin; Kleemann, Hans; Krammer, Markus; Zojer, Karin; Vandewal, Koen; Leo, Karl", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elementary steps in electrical doping of organic semiconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fermi level control by doping is established since decades in inorganic semiconductors and has been successfully introduced in organic semiconductors. Despite its commercial success in the multi-billion OLED display business, molecular doping is little understood, with its elementary steps controversially discussed and mostly-empirical-materials design. Particularly puzzling is the efficient carrier release, despite a presumably large Coulomb barrier. Here we quantitatively investigate doping as a two-step process, involving single-electron transfer from donor to acceptor molecules and subsequent dissociation of the ground-state integercharge transfer complex (ICTC). We show that carrier release by ICTC dissociation has an activation energy of only a few tens of meV, despite a Coulomb binding of several 100 meV. We resolve this discrepancy by taking energetic disorder into account. The overall doping process is explained by an extended semiconductor model in which occupation of ICTCs causes the classically known reserve regime at device-relevant doping concentrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1182, "DOI": "10.1038/s41467-018-03302-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03302-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427929200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ngafwan, N; Rasyid, H; Abood, ES; Abdelbasset, WK; Al-Shawi, SG; Bokov, D; Jalil, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ngafwan, Ngafwan; Rasyid, Harun; Abood, Emad Salaam; Abdelbasset, Walid Kamal; Al-Shawi, Sarmad Ghazi; Bokov, Dmitry; Jalil, Abduladheem Turki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study on novel fluorescent carbon nullomaterials in food analysis", "Source Title": "FOOD SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the most significant nullobiotechnology and nullomaterial science areas today is the production of novel sensors and biosensors with applications in the food industry. Carbon quantum dots (CQDs) are a new generation of carbon nulloparticles with a lot of potential for food analysis. CQDs with robust physicochemical properties are one of the most recently researched carbon nullomaterials. This material has outstanding optical properties such as light persistence, photobleaching tolerance, photoluminescence, and the advantages of fast functionalization and strong biocompatibility, rendering it an excellent raw material for sensing devices. Thanks to its considerable features such as fast result outputs, low expense, ease of service, and high sensitivity, fluorescence analysis has tremendous potential for food protection. The aim of this article is to familiarise yourself with carbon points, their synthesis methods, and their optical properties. Finally, fluorescence sensors can be used to detect food additives, heavy metals, bacteria, insecticide residues, antibiotics, and nutritional components in food samples. CQDs' problems and opportunities in the area of food safety were also addressed. Practical Application: We aimed to study and review the novel fluorescent carbon nullomaterials in food analysis. Fluorescence sensors can be used to detect food additives, heavy metals, bacteria, insecticide residues, antibiotics, and nutritional components in food samples. Carbon quantum dots' problems and opportunities in the area of food safety were also addressed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 42, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e37821", "DOI": "10.1590/fst.37821", "DOI Link": "http://dx.doi.org/10.1590/fst.37821", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767939200035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, KX; Li, P; Sun, ZN; Shi, J; Huang, MH; Chen, JW; Liu, S; Shi, ZC; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Kaixuan; Li, Ping; Sun, Zining; Shi, Jing; Huang, Minghua; Chen, Jingwei; Liu, Shuai; Shi, Zhicheng; Wang, Huanlei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-cellulose-based quasi-solid-state supercapacitor with nitrogen and boron dual-doped carbon electrodes exhibiting high energy density and excellent cyclic stability", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The key to construct high-energy supercapacitors is to maximize the capacitance of electrode and the voltage of the device. Realizing this purpose by utilizing sustainable and low-cost resources is still a big challenge. Herein, N, B co-doped carbon nullosheets are obtained through the proposed dual-template assisted approach by using methyl cellulose as the precursor. Due to the synergistic effects form the high surface area with the hierarchical porous structure, N/B dual doping, and a high degree of graphitization, the resultant carbon electrode exhibits a high capacitance of 572 F g-1 at 0.5 A g-1 and retains 281 F g-1 at 50 A g-1 in an acidic electrolyte. Furthermore, the symmetric device assembled using bacterial cellulose-based gel polymer electrolyte can deliver high energy density of 43 W h kg-1 and excellent cyclability with 97.8% capacity retention after 20 000 cycles in water in salt electrolyte. This work successfully realizes the fabrication of high-performance allcellulose-based quasi-solid-state supercapacitors, which brings a cost-effective insight into jointly designing electrodes and electrolytes for supporting highly efficient energy storage.& COPY; 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1091, "End Page": 1101, "Article Number": null, "DOI": "10.1016/j.gee.2022.01.002", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2022.01.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037511400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Semenok, DV; Kvashnin, AG; Ivanova, AG; Svitlyk, V; Fominski, VY; Sadakov, AV; Sobolevskiy, OA; Pudalov, VM; Troyan, IA; Oganov, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Semenok, Dmitry V.; Kvashnin, Alexander G.; Ivanova, Anna G.; Svitlyk, Volodymyr; Fominski, Vyacheslav Yu.; Sadakov, Andrey V.; Sobolevskiy, Oleg A.; Pudalov, Vladimir M.; Troyan, Ivan A.; Oganov, Artem R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity at 161 K in thorium hydride ThH10: Synthesis and properties", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we report targeted high-pressure synthesis of two novel high-T-C hydride superconductors, P6(3)/mmc-ThH9 and Fm (3) over barm-ThH10, with the experimental critical temperatures (T-C) of 146 K and 159-161 K and upper critical magnetic fields (mu H-C) 38 and 45 Tesla at pressures 170-175 Gigapascals, respectively. Superconductivity was evidenced by the observation of zero resistance and a decrease of TC under external magnetic field up to 16 Tesla. This is one of the highest critical temperatures that has been achieved experimentally in any compound, along with such materials as LaH10, H3S and HgBa2Cax-Cu2O6+z. Our experiments show that fcc-ThH10 has stabilization pressure of 85 GPa, making this material unique among all known high-T-C metal polyhydrides. Two recently predicted Th-H compounds, I4/mmm-ThH4 (>86 GPa) and Cmc2(1)-ThH6 (86-104 GPa), were also synthesized. Equations of state of obtained thorium polyhydrides were measured and found to be in excellent agreement with the theoretical calculations. New phases were examined theoretically and their electronic, phonon, and superconducting properties were calculated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 36, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.mattod.2019.10.005", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2019.10.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522556600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Fuchs, T; Weber, SAL; Richter, FH; Glasser, G; Weber, F; Butt, HJ; Janek, J; Berger, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Chao; Fuchs, Till; Weber, Stefan A. L.; Richter, Felix. H.; Glasser, Gunnar; Weber, Franjo; Butt, Hans-Juergen; Janek, Juergen; Berger, Ruediger", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growth of lithium dendrites in inorganic solid electrolytes is an essential drawback that hinders the development of reliable all-solid-state lithium metal batteries. Generally, ex situ post mortem measurements of battery components show the presence of lithium dendrites at the grain boundaries of the solid electrolyte. However, the role of grain boundaries in the nucleation and dendritic growth of metallic lithium is not yet fully understood. Here, to shed light on these crucial aspects, we report the use of operando Kelvin probe force microscopy measurements to map locally time-dependent electric potential changes in the Li6.25Al0.25La3Zr2O12 garnet-type solid electrolyte. We find that the Galvani potential drops at grain boundaries near the lithium metal electrode during plating as a response to the preferential accumulation of electrons. Time-resolved electrostatic force microscopy measurements and quantitative analyses of lithium metal formed at the grain boundaries under electron beam irradiation support this finding. Based on these results, we propose a mechanistic model to explain the preferential growth of lithium dendrites at grain boundaries and their penetration in inorganic solid electrolytes. Lithium metal penetration into solid-state electrolytes is a major drawback for developing all-solid-state batteries. Here, authors, via operando force microscopy, demonstrate that the trapping of electrons in garnet-type solid-state electrolyte grain boundaries is the origin of cell failure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1300, "DOI": "10.1038/s41467-023-36792-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36792-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001683700013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Loterie, D; Delrot, P; Moser, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Loterie, Damien; Delrot, Paul; Moser, Christophe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-resolution tomographic volumetric additive manufacturing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tomographic additive manufacturing produces complex parts with a wide range of printable materials but remains limited in terms of resolution. Here, the authors tune the etendue of the light source and accurately control the photopolymerization kinetics using an integrated feedback system, leading to the fabrication of high resolution features. In tomographic volumetric additive manufacturing, an entire three-dimensional object is simultaneously solidified by irradiating a liquid photopolymer volume from multiple angles with dynamic light patterns. Though tomographic additive manufacturing has the potential to produce complex parts with a higher throughput and a wider range of printable materials than layer-by-layer additive manufacturing, its resolution currently remains limited to 300 mu m. Here, we show that a low-etendue illumination system enables the production of high-resolution features. We further demonstrate an integrated feedback system to accurately control the photopolymerization kinetics over the entire build volume and improve the geometric fidelity of the object solidification. Hard and soft centimeter-scale parts are produced in less than 30 seconds with 80 mu m positive and 500 mu m negative features, thus demonstrating that tomographic additive manufacturing is potentially suitable for the ultrafast fabrication of advanced and functional constructs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 852, "DOI": "10.1038/s41467-020-14630-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14630-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000514686900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hart, S; Ren, H; Wagner, T; Leubner, P; Mühlbauer, M; Brüne, C; Buhmann, H; Molenkamp, L; Yacoby, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hart, Sean; Ren, Hechen; Wagner, Timo; Leubner, Philipp; Muehlbauer, Mathias; Bruene, Christoph; Buhmann, Hartmut; Molenkamp, LaurensW.; Yacoby, Amir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Induced superconductivity in the quantum spin Hall edge", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological insulators are a newly discovered phase of matter characterized by gapped bulk states surrounded by conducting boundary states(1-3). Since their theoretical discovery, these materials have encouraged intense efforts to study their properties and capabilities. Among the most striking results of this activity are proposals to engineer a new variety of superconductor at the surfaces of topological insulators(4,5). These topological superconductors would be capable of supporting localized Majorana fermions, particles whose braiding properties have been proposed as the basis of a fault-tolerant quantum computer(6). Despite the clear theoretical motivation, a conclusive realization of topological superconductivity remains an outstanding experimental goal. Here we present measurements of superconductivity induced in two-dimensional HgTe/HgCdTe quantum wells, a material that becomes a quantum spin Hall insulator when the well width exceeds d(C) = 6.3nm (ref. 7). In wells that are 7.5 nm wide, we find that supercurrents are confined to the one-dimensional sample edges as the bulk density is depleted. However, when the well width is decreased to 4.5 nm the edge supercurrents cannot be distinguished from those in the bulk. Our results provide evidence for supercurrents induced in the helical edges of the quantum spin Hall effect, establishing this system as a promising avenue towards topological superconductivity. In addition to directly confirming the existence of the topological edge channels, our results also provide a measurement of their widths, which range from 180 nm to 408 nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2014, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 638, "End Page": 643, "Article Number": null, "DOI": "10.1038/NPHYS3036", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341820700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kou, XF; Guo, ST; Fan, YB; Pan, L; Lang, MR; Jiang, Y; Shao, QM; Nie, TX; Murata, K; Tang, JS; Wang, Y; He, L; Lee, TK; Lee, WL; Wang, KL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kou, Xufeng; Guo, Shih-Ting; Fan, Yabin; Pan, Lei; Lang, Murong; Jiang, Ying; Shao, Qiming; Nie, Tianxiao; Murata, Koichi; Tang, Jianshi; Wang, Yong; He, Liang; Lee, Ting-Kuo; Lee, Wei-Li; Wang, Kang L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scale-Invariant Quantum Anomalous Hall Effect in Magnetic Topological Insulators beyond the Two-Dimensional Limit", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate the quantum anomalous Hall effect (QAHE) and related chiral transport in the millimeter-size (Cr0.12Bi0.26Sb0.62)(2)Te-3 films. With high sample quality and robust magnetism at low temperatures, the quantized Hall conductance of e(2)/h is found to persist even when the film thickness is beyond the two-dimensional (2D) hybridization limit. Meanwhile, the Chern insulator-featured chiral edge conduction is manifested by the nonlocal transport measurements. In contrast to the 2D hybridized thin film, an additional weakly field-dependent longitudinal resistance is observed in the ten-quintuple-layer film, suggesting the influence of the film thickness on the dissipative edge channel in the QAHE regime. The extension of the QAHE into the three-dimensional thickness region addresses the universality of this quantum transport phenomenon and motivates the exploration of new QAHE phases with tunable Chern numbers. In addition, the observation of scale-invariant dissipationless chiral propagation on a macroscopic scale makes a major stride towards ideal low-power interconnect applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2014, "Volume": 113, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137201, "DOI": "10.1103/PhysRevLett.113.137201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.137201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342666500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, H; Zhang, GZ; Zhang, XX; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Hao; Zhang, Guozhi; Zhang, Xiaoxing; Tang, Ju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rh-doped MoSe2 as a toxic gas scavenger: a first-principles study", "Source Title": "nullOSCALE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using first-principles theory, we investigated the most stable configuration for the Rh dopant on a MoSe2 monolayer, and the interaction of the Rh-doped MoSe2 (Rh-MoSe2) monolayer with four toxic gases (CO, NO, NO2 and SO2) to exploit the potential application of the Rh-MoS2 monolayer as a gas sensor or adsorbent. Based on adsorption behavior comparison with other 2D adsorbents and desorption behavior analysis, we assume that the Rh-MoSe2 monolayer is a desirable adsorbent for CO, NO and NO2 storage or removal given the Larger adsorption energy (E-ad) of -2.00, -2.56 and -1.88 eV, respectively, compared with other materials. In the meanwhile, the Rh-MoSe2 monolayer is a good sensing material for SO2 detection according to its desirable adsorption and desorption behaviors towards the target molecule. Our theoretical calculation would provide a first insight into the TM-doping effect on the structural and electronic properties of the MoSe2 monolayer, and shed Light on the application of Rh-MoSe2 for the sensing or disposal of common toxic gases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 772, "End Page": 780, "Article Number": null, "DOI": "10.1039/c8na00233a", "DOI Link": "http://dx.doi.org/10.1039/c8na00233a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000479170600036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, XK; Yang, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Xiaokun; Yang, Ronggui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles prediction of phononic thermal conductivity of silicene: A comparison with graphene", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been great interest in two-dimensional materials, beyond graphene, for both fundamental sciences and technological applications. Silicene, a silicon counterpart of graphene, has been shown to possess some better electronic properties than graphene. However, its thermal transport properties have not been fully studied. In this paper, we apply the first-principles-based phonon Boltzmann transport equation to investigate the thermal conductivity of silicene as well as the phonon scattering mechanisms. Although both graphene and silicene are two-dimensional crystals with similar crystal structure, we find that phonon transport in silicene is quite different from that in graphene. The thermal conductivity of silicene shows a logarithmic increase with respect to the sample size due to the small scattering rates of acoustic in-plane phonon modes, while that of graphene is finite. Detailed analysis of phonon scattering channels shows that the linear dispersion of the acoustic out-of-plane (ZA) phonon modes, which is induced by the buckled structure, makes the long-wavelength longitudinal acoustic phonon modes in silicene not as efficiently scattered as that in graphene. Compared with graphene, where most of the heat is carried by the acoustic out-of-plane (ZA) phonon modes, the ZA phonon modes in silicene only have similar to 10% contribution to the total thermal conductivity, which can also be attributed to the buckled structure. This systematic comparison of phonon transport and thermal conductivity of silicene and graphene using the first-principle-based calculations shed some light on other two-dimensional materials, such as two-dimensional transition metal dichalcogenides. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 117, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25102, "DOI": "10.1063/1.4905540", "DOI Link": "http://dx.doi.org/10.1063/1.4905540", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348129300060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hartland, GV; Besteiro, LV; Johns, P; Govorov, AO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hartland, Gregory V.; Besteiro, Lucas V.; Johns, Paul; Govorov, Alexander O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "What's so Hot about Electrons in Metal nulloparticles?", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal nulloparticles are excellent light absorbers. The absorption processes create highly excited electronhole pairs, and recently there has been interest in harnessing these hot charge carriers for photocatalysis and solar energy conversion applications. The goal of this Perspective is to describe the dynamics and energy distribution of the charge carriers produced by photon absorption and the implications for the photocatalysis mechanism. We will also discuss how spectroscopy can be used to provide insight into the coupling between plasmons and molecular resonullces. In particular, the analysis shows that the choice of material and shape of the nullocrystal can play a crucial role in hot electron generation and coupling between plasmons and molecular transitions. The detection and even calculation of many-body hot-electron processes in the plasmonic systems with continuous spectra of electrons and short lifetimes are challenging, but at the same time they are very interesting from the points of view of both potential applications and fundamental science. We propose that developing an understanding of these processes will provide a pathway for improving the efficiency of plasmon-induced photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1641, "End Page": 1653, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00333", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00333", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405979900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Charbonneau, P; Kurchan, J; Parisi, G; Urbani, P; Zamponi, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Charbonneau, Patrick; Kurchan, Jorge; Parisi, Giorgio; Urbani, Pierfrancesco; Zamponi, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractal free energy landscapes in structural glasses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glasses are amorphous solids whose constituent particles are caged by their neighbours and thus cannot flow. This sluggishness is often ascribed to the free energy landscape containing multiple minima (basins) separated by high barriers. Here we show, using theory and numerical simulation, that the landscape is much rougher than is classically assumed. Deep in the glass, it undergoes a 'roughness transition' to fractal basins, which brings about isostaticity and marginal stability on approaching jamming. Critical exponents for the basin width, the weak force distribution and the spatial spread of quasi-contacts near jamming can be analytically determined. Their value is found to be compatible with numerical observations. This advance incorporates the jamming transition of granular materials into the framework of glass theory. Because temperature and pressure control what features of the landscape are experienced, glass mechanics and transport are expected to reflect the features of the topology we discuss here.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 414, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3725, "DOI": "10.1038/ncomms4725", "DOI Link": "http://dx.doi.org/10.1038/ncomms4725", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335223200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Glaser, J; Nguyen, TD; Anderson, JA; Lui, P; Spiga, F; Millan, JA; Morse, DC; Glotzer, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Glaser, Jens; Trung Dac Nguyen; Anderson, Joshua A.; Lui, Pak; Spiga, Filippo; Millan, Jaime A.; Morse, David C.; Glotzer, Sharon C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong scaling of general-purpose molecular dynamics simulations on GPUs", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We describe a highly optimized implementation of MPI domain decomposition in a GPU-enabled, general-purpose molecular dynamics code, HOOMD-blue (Anderson and Glotzer, 2013). Our approach is inspired by a traditional CPU-based code, LAMMPS (Plimpton, 1995), but is implemented within a code that was designed for execution on GPUs from the start (Anderson et al., 2008). The software supports short-ranged pair force and bond force fields and achieves optimal GPU performance using an autotuning algorithm. We are able to demonstrate equivalent or superior scaling on up to 3375 GPUs in Lennard-Jones and dissipative particle dynamics (DPD) simulations of up to 108 million particles. GPUDirect RDMA capabilities in recent GPU generations provide better performance in full double precision calculations. For a representative polymer physics application, HOOMD-blue 1.0 provides an effective GPU vs. CPU node speed-up of 12.5x. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 97, "End Page": 107, "Article Number": null, "DOI": "10.1016/j.cpc.2015.02.028", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2015.02.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354141100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, Y; Teicher, SML; Ortiz, BR; Luo, Y; Peng, ST; Huai, LW; Ma, JZ; Plumb, NC; Wilson, SD; He, JF; Shi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yong; Teicher, Samuel M. L.; Ortiz, Brenden R.; Luo, Yang; Peng, Shuting; Huai, Linwei; Ma, Junzhang; Plumb, Nicholas C.; Wilson, Stephen D.; He, Junfeng; Shi, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological surface states and flat bands in the kagome superconductor CsV3Sb5", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exotic quantum phenomena may appear in material systems with multiple orders or phases, where the mutual interactions can give rise to new physics beyond that of each component. Here, we report spectroscopic evidence for a unique combination of topology and correlation effects in the kagome superconductor CsV3Sb5. Topologically nontrivial surface states are observed near the Fermi energy (E-F), indicating that the topological physics may be active upon entering the superconducting state. Flat bands are observed, suggesting that electron correlation effects are also at play in this system. Our results reveal the peculiar electronic structure of CsV3Sb5, which holds the potential for realizing Majorana zero modes and anomalous superconducting states in kagome lattices. They also establish CsV3Sb5 as a unique platform for exploring the interactions between the charge order, topology, correlation effects and superconductivity. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2022, "Volume": 67, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 500, "Article Number": null, "DOI": "10.1016/j.scib.2021.11.026", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2021.11.026", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786594400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmed, S; Bloom, I; Jansen, AN; Tanim, T; Dufek, EJ; Pesaran, A; Burnham, A; Carlson, RB; Dias, F; Hardy, K; Keyser, M; Kreuzer, C; Markel, A; Meintz, A; Michelbacher, C; Mohanpurkar, M; Nelson, PA; Robertson, DC; Scoffield, D; Shirk, M; Stephens, T; Vijayagopal, R; Zhang, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmed, Shabbir; Bloom, Ira; Jansen, Andrew N.; Tanim, Tanvir; Dufek, Eric J.; Pesaran, Ahmad; Burnham, Andrew; Carlson, Richard B.; Dias, Fernulldo; Hardy, Keith; Keyser, Matthew; Kreuzer, Cory; Markel, Anthony; Meintz, Andrew; Michelbacher, Christopher; Mohanpurkar, Manish; Nelson, Paul A.; Robertson, David. C.; Scoffield, Don; Shirk, Matthew; Stephens, Thomas; Vijayagopal, Ram; Zhang, Jiucai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling fast charging - A battery technology gap assessment", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The battery technology literature is reviewed, with an emphasis on key elements that limit extreme fast charging. Key gaps in existing elements of the technology are presented as well as developmental needs. Among these needs are advanced models and methods to detect and prevent lithium plating; new positive-electrode materials which are less prone to stress-induced failure; better electrode designs to accommodate very rapid diffusion in and out of the electrode; measure temperature distributions during fast charge to enable/validate models; and develop thermal management and pack designs to accommodate the higher operating voltage. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2017, "Volume": 367, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 262, "Article Number": null, "DOI": "10.1016/j.jpowsour.2017.06.055", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2017.06.055", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415780000028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, JQ; Zhang, LF; Car, R; Weinull, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Jiequn; Zhang, Linfeng; Car, Roberto; Weinull, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Potential: A General Representation of a Many-Body Potential Energy Surface", "Source Title": "COMMUNICATIONS IN COMPUTATIONAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a simple, yet general, deep neural network representation of the potential energy surface for atomic and molecular systems. It is first-principle based, in the sense that no ad hoc approximations or empirical fitting functions are required. When tested on a wide variety of examples, it reproduces the original model within chemical accuracy. This brings us one step closer to carrying outmolecular simulations with quantum mechanics accuracy at empirical potential computational cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 23, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 629, "End Page": 639, "Article Number": null, "DOI": "10.4208/cicp.OA-2017-0213", "DOI Link": "http://dx.doi.org/10.4208/cicp.OA-2017-0213", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426270700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, C; Sun, XC; Liu, XP; Lu, MH; Chen, Y; Feng, L; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Cheng; Sun, Xiao-Chen; Liu, Xiao-Ping; Lu, Ming-Hui; Chen, Yulin; Feng, Liang; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonic topological insulator with broken time-reversal symmetry", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A topological insulator is a material with an insulating interior but time-reversal symmetry-protected conducting edge states. Since its prediction and discovery almost a decade ago, such a symmetry-protected topological phase has been explored beyond electronic systems in the realm of photonics. Electrons are spin-1/2 particles, whereas photons are spin-1 particles. The distinct spin difference between these two kinds of particles means that their corresponding symmetry is fundamentally different. It is well understood that an electronic topological insulator is protected by the electron's spin-1/2 (fermionic) time-reversal symmetry T-f(2) = -1. However, the same protection does not exist under normal circumstances for a photonic topological insulator, due to photon's spin-1 (bosonic) time-reversal symmetry T-b(2) = 1. In this work, we report a design of photonic topological insulator using the Tellegen magnetoelectric coupling as the photonic pseudospin orbit interaction for left and right circularly polarized helical spin states. The Tellegen magnetoelectric coupling breaks bosonic time-reversal symmetry but instead gives rise to a conserved artificial fermionic-like-pseudo time-reversal symmetry, T-p (T-p(2) = -1), due to the electromagnetic duality. Surprisingly, we find that, in this system, the helical edge states are, in fact, protected by this fermionic-like pseudo time-reversal symmetry T-p rather than by the bosonic time-reversal symmetry T-b. This remarkable finding is expected to pave a new path to understanding the symmetry protection mechanism for topological phases of other fundamental particles and to searching for novel implementations for topological insulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2016, "Volume": 113, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4924, "End Page": 4928, "Article Number": null, "DOI": "10.1073/pnas.1525502113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1525502113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375395700025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YM; He, CH; Cheng, CQ; Han, SH; He, M; Wang, YT; Meng, NN; Zhang, B; Lu, QP; Yu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yanmei; He, Caihong; Cheng, Chuanqi; Han, Shuhe; He, Meng; Wang, Yuting; Meng, nullnull; Zhang, Bin; Lu, Qipeng; Yu, Yifu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pulsed electroreduction of low-concentration nitrate to ammonia", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic nitrate (NO3-) reduction to ammonia (NRA) has emerged as an alternative strategy for effluent treatment and ammonia production. Despite significant advancements that have been achieved in this field, the efficient conversion of low-concentration nitrate to ammonia at low overpotential remains a formidable challenge. This challenge stems from the sluggish reaction kinetics caused by the limited distribution of negatively charged NO3- in the vicinity of the working electrode and the competing side reactions. Here, a pulsed potential approach is introduced to overcome these issues. A good NRA performance (Faradaic efficiency: 97.6%, yield rate: 2.7 mmol-1 h-1 mgRu-1, conversion rate: 96.4%) is achieved for low-concentration (<= 10 mM) nitrate reduction, obviously exceeding the potentiostatic test (Faradaic efficiency: 65.8%, yield rate: 1.1 mmol-1 h-1 mgRu-1, conversion rate: 54.1%). The combined results of in situ characterizations and finite element analysis unveil the performance enhancement mechanism that the periodic appearance of anodic potential can significantly optimize the adsorption configuration of the key *NO intermediate and increase the local NO3- concentration. Furthermore, our research implies an effective approach for the rational design and precise manipulation of reaction processes, potentially extending its applicability to a broader range of catalytic applications. Electrocatalytic nitrate reduction to ammonia has emerged as an alternative strategy for effluent treatment and ammonia production. Here, the authors report a pulsed potential approach to overcome the sluggish reaction kinetics caused by the limited distribution of negatively charged nitrate near the working electrode and the competing side reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7368, "DOI": "10.1038/s41467-023-43179-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43179-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001104729800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, YQ; Mei, P; Lu, YJ; Huang, R; Yu, XL; Chen, ZL; Roskilly, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yuqi; Mei, Pan; Lu, Yiji; Huang, Rui; Yu, Xiaoli; Chen, Zhuolie; Roskilly, Anthony Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel approach for Lithium-ion battery thermal management with streamline shape mini channel cooling plates", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mini-channel cooling plate has been widely used in the Lithium-ion battery thermal management for electric vehicles. The technology development of high efficiency and good temperature uniformity cooling plate can promote the application of electric vehicles by improving the lifespan of the battery. In this study, streamline concept, which is commonly used for the external design of car, aerospace and submarine system to improve the system performance, has been introduced to design and optimise the performance of inner mini channel cooling plate. The flow resistance was proved to be minimised when the streamline shape design was adopted. Moreover, the results have proven the novel designed mini channel cooling plate can keep the heat exchange ability within the acceptable level. The maximum improvement of the heat exchanger efficiency with streamline shape design could be as high as 44.52%. Results indicated the temperature uniformity could also be effectively improved. The streamline shape mini channel cooling plate could be a promising solution for Lithium-ion battery thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2019, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113623, "DOI": "10.1016/j.applthermaleng.2019.04.033", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2019.04.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475994000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "House, RA; Rees, GJ; McColl, K; Marie, JJ; Garcia-Fernulldez, M; Nag, A; Zhou, KJ; Cassidy, S; Morgan, BJ; Islam, MS; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "House, Robert A.; Rees, Gregory J.; McColl, Kit; Marie, John-Joseph; Garcia-Fernulldez, Mirian; Nag, Abhishek; Zhou, Ke-Jin; Cassidy, Simon; Morgan, Benjamin J.; Saiful Islam, M.; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Delocalized electron holes on oxygen in a battery cathode", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxide ions in transition metal oxide cathodes can store charge at high voltage offering a route towards higher energy density batteries. However, upon charging these cathodes, the oxidized oxide ions condense to form molecular O-2 trapped in the material. Consequently, the discharge voltage is much lower than charge, leading to undesirable voltage hysteresis. Here we capture the nature of the electron holes on O2- before O-2 formation by exploiting the suppressed transition metal rearrangement in ribbon-ordered Na-0.6[Li0.2Mn0.8]O-2. We show that the electron holes formed are delocalized across the oxide ions coordinated to two Mn (O-Mn-2) arranged in ribbons in the transition metal layers. Furthermore, we track these delocalized hole states as they gradually localize in the structure in the form of trapped molecular O-2 over a period of days. Establishing the nature of hole states on oxide ions is important if truly reversible high-voltage O-redox cathodes are to be realized. The mechanism of oxygen redox in high-energy transition metal oxide cathodes is elusive. Here the authors illustrate the nature of the electron-hole states on oxide ions, offering insights for realizing reversible, high-voltage cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 351, "End Page": 360, "Article Number": null, "DOI": "10.1038/s41560-023-01211-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01211-0", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939112200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ríos, C; Youngblood, N; Cheng, ZG; Le Gallo, M; Pernice, WHP; Wright, CD; Sebastian, A; Bhaskaran, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rios, Carlos; Youngblood, Nathan; Cheng, Zengguang; Le Gallo, Manuel; Pernice, Wolfram H. P.; Wright, C. David; Sebastian, Abu; Bhaskaran, Harish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-memory computing on a photonic platform", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Collocated data processing and storage are the norm in biological computing systems such as the mammalian brain. As our ability to create better hardware improves, new computational paradigms are being explored beyond von Neumann architectures. Integrated photonic circuits are an attractive solution for on-chip computing which can leverage the increased speed and bandwidth potential of the optical domain, and importantly, remove the need for electro-optical conversions. Here we show that we can combine integrated optics with collocated data storage and processing to enable all-photonic in-memory computations. By employing nonvolatile photonic elements based on the phase-change material, Ge2Sb2Te5, we achieve direct scalar and matrix-vector multiplication, featuring a novel single-shot Write/Erase and a drift-free process. The output pulse, carrying the information of the light-matter interaction, is the result of the computation. Our all-optical approach is novel, easy to fabricate and operate, and sets the stage for development of entirely photonic computers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaau5759", "DOI": "10.1126/sciadv.aau5759", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aau5759", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Lu, HY; Zhu, XG; Tan, SY; Feng, W; Liu, Q; Zhang, W; Chen, QY; Liu, Y; Luo, XB; Xie, DH; Luo, LZ; Zhang, ZJ; Lai, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yun; Lu, Haiyan; Zhu, Xiegang; Tan, Shiyong; Feng, Wei; Liu, Qin; Zhang, Wen; Chen, Qiuyun; Liu, Yi; Luo, Xuebing; Xie, Donghua; Luo, Lizhu; Zhang, Zhengjun; Lai, Xinchun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergence of Kondo lattice behavior in a van der Waals itinerant ferromagnet, Fe3GeTe2", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for heavy fermion (HF) states in non-f-electron systems becomes an interesting issue, especially in the presence of magnetism, and can help explain the physics of complex compounds. Using angle-resolved photo-emission spectroscopy, scanning tunneling microscopy, physical properties measurements, and the first-principles calculations, we observe the HF state in a 3d-electron van der Waals ferromagnet, Fe3GeTe2. Upon entering the ferromagnetic state, a massive spectral weight transfer occurs, which results from the exchange splitting. Meanwhile, the Fermi surface volume and effective electron mass are both enhanced. When the temperature drops below a characteristic temperature T*, heavy electrons gradually emerge with further enhanced effective electron mass. The coexistence of ferromagnetism and HF state can be well interpreted by the dual properties (itinerant and localized) of 3d electrons. This work expands the limit of ferromagnetic HF materials from f-to d-electron systems and illustrates the positive correlation between ferromagnetism and HF state in the 3d-electron material, which is quite different from the f-electron systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao6791", "DOI": "10.1126/sciadv.aao6791", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao6791", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426694200054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WW; Li, JT; Liao, XB; Zhang, L; Zhang, XM; Liu, CZ; Amine, K; Zhao, KN; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Wangwang; Li, Jiantao; Liao, Xiaobin; Zhang, Lei; Zhang, Xiaoman; Liu, Chaozheng; Amine, Khalil; Zhao, Kangning; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluoride-Rich, Organic-Inorganic Gradient Interphase Enabled by Sacrificial Solvation Shells for Reversible Zinc Metal Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc metal batteries are strongly hindered by water corrosion, as solvated zinc ions would bring the active water molecules to the electrode/electrolyte interface constantly. Herein, we report a sacrificial solvation shell to repel active water molecules from the electrode/electrolyte interface and assist in forming a fluoride-rich, organic-inorganic gradient solid electrolyte interface (SEI) layer. The simultaneous sacrificial process of methanol and Zn(CF3SO3)(2) results in the gradient SEI layer with an organic-rich surface (CH2OC- and C-5 product) and an inorganic-rich (ZnF2) bottom, which combines the merits of fast ion diffusion and high flexibility. As a result, the methanol additive enables corrosion-free zinc stripping/plating on copper foils for 300 cycles with an average coulombic efficiency of 99.5%, a record high cumulative plating capacity of 10 A h/cm(2) at 40 mA/cm(2) in Zn/Zn symmetrical batteries. More importantly, at an ultralow N/P ratio of 2, the practical VO2//20 mu m thick Zn plate full batteries with a high areal capacity of 4.7 mAh/cm(2) stably operate for over 250 cycles, establishing their promising application for grid-scale energy storage devices. Furthermore, directly utilizing the 20 mu m thick Zn for the commercial-level areal capacity (4.7 mAh/cm(2)) full zinc battery in our work would simplify the manufacturing process and boost the development of the commercial zinc battery for stationary storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2023, "Volume": 145, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22456, "End Page": 22465, "Article Number": null, "DOI": "10.1021/jacs.3c06523", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c06523", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001086400300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, T; Zhu, W; Wang, N; Zhang, KY; Wen, X; Xing, Y; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Tian; Zhu, Wei; Wang, Ning; Zhang, Keyu; Wen, Xue; Xing, Yan; Li, Yunfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of Structure Vacancy Defect Modified Diatomic-Layered g-C3N4 nullosheet with Enhanced Photocatalytic Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structure self-modification of graphitic carbon nitride (g-C3N4) without the assistance of other species has attracted considerable attention. In this study, the structure vacancy defect modified diatomic-layered g-C3N4 nullosheet (VCN) is synthesized by thermal treatment of bulk g-C3N4 in a quartz tube with vacuum atmosphere that will generate a pressure-thermal dual driving force to boost the exfoliation and formation of structure vacancy for g-C3N4. The as-prepared VCN possesses a large specific surface area with a rich pore structure to provide more active centers for catalytic reactions. Furthermore, the as-formed special defect level in VCN sample can generate a higher exciton density at photoexcitation stage. Meanwhile, the photogenerated charges will rapidly transfer to VCN surface due to the greatly shortened transfer path resulting from the ultrathin structure (& AP;1.5 nm), which corresponds to two graphite carbon nitride atomic layers. In addition, the defect level alleviates the drawback of enlarged bandgap caused by the quantum size effect of nullo-scaled g-C3N4, resulting in a well visible-light utilization. As a result, the VCN sample exhibits an excellent photocatalytic performance both in hydrogen production and photodegradation of typical antibiotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2023, "Volume": 10, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302503", "DOI Link": "http://dx.doi.org/10.1002/advs.202302503", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001013783700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HX; Lin, ZK; Jiang, B; Guo, GY; Jiang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hai-Xiao; Lin, Zhi-Kang; Jiang, Bin; Guo, Guang-Yu; Jiang, Jian-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-Order Weyl Semimetals", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Higher-order topology yields intriguing multidimensional topological phenomena, while Weyl semimetals have unconventional properties such as chiral anomaly. However, so far, Weyl physics remain disconnected with higher-order topology. Here, we report the theoretical discovery of higher-order Weyl semimetals and thereby the establishment of such an important connection. We demonstrate that higher-order Weyl semimetals can emerge in chiral materials such as chiral tetragonal crystals as the intermediate phase between the conventional Weyl semimetal and 3D higher-order topological phases. Higher-order Weyl semimetals manifest themselves uniquely by exhibiting concurrent chiral Fermi-arc surface states, topological hinge states, and the momentum-dependent fractional hinge charge, revealing a novel class of higher-order topological phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2020, "Volume": 125, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 146401, "DOI": "10.1103/PhysRevLett.125.146401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.146401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573184300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, DM; Rubab, N; Hyun, I; Kang, W; Kim, YJ; Kang, M; Choi, BO; Kim, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Dong-Min; Rubab, Najaf; Hyun, Inah; Kang, Wooseok; Kim, Young-Jun; Kang, Minki; Choi, Byung Ok; Kim, Sang-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-mediated triboelectric nullogenerator for powering on-demand transient electronics", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-demand transient electronics, technologies referring subsequent material disintegration under well-defined triggering events and programmed time lines, offer exceptional clinical experiences in diagnosis, treatment, and rehabilitation. Despite potential benefits, such as the elimination of surgical device removal and reduction of long-term inimical effects, their use is limited by the nontransient conventional power supplies. Here, we report an ultrasound-mediated transient triboelectric nullogenerator (TENG) where ultrasound determines energy generation and degradation period. Our findings on finite element method simulation show that porous structures of the poly(3-hydroxybutyrate-co-3-hydroxyvalerate) play an essential role in the triggering transient process of our device under high-intensity ultrasound. Besides, the addition of polyethylene glycol improves triboelectric output performance; the voltage output increased by 58.5%, from 2.625 to 4.160 V. We successfully demonstrate the tunable transient performances by ex vivo experiment using a porcine tissue. This study provides insight into practical use of implantable TENGs based on ultrasound-triggered transient material design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl8423", "DOI": "10.1126/sciadv.abl8423", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl8423", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742086300020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pi, YC; Qiu, ZM; Sun, Y; Ishii, H; Liao, YF; Zhang, XY; Chen, HY; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pi, Yecan; Qiu, Ziming; Sun, Yi; Ishii, Hirofumi; Liao, Yen-Fa; Zhang, Xiuyun; Chen, Han-Yi; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Mechanism of Sub-nullometric Ru Clusters Anchored on Tungsten Oxide nullowires for High-Efficient Bifunctional Hydrogen Electrocatalysis", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The construction of strong interactions and synergistic effects between small metal clusters and supports offers a great opportunity to achieve high-performance and cost-effective heterogeneous catalysis, however, studies on its applications in electrocatalysis are still insufficient. Herein, it is reported that W18O49 nullowires supported sub-nullometric Ru clusters (denoted as Ru SNC/W18O49 NWs) constitute an efficient bifunctional electrocatalyst for hydrogen evolution/oxidation reactions (HER and HOR) under acidic condition. Microstructural analyses, X-ray absorption spectroscopy, and density functional theory (DFT) calculations reveal that the Ru SNCs with an average Ru-Ru coordination number of 4.9 are anchored to the W18O49 NWs via Ru-O-W bonds at the interface. The strong metal-support interaction leads to the electron-deficient state of Ru SNCs, which enables a modulated Ru-H strength. Furthermore, the unique proton transport capability of the W18O49 also provides a potential migration channel for the reaction intermediates. These components collectively enable the remarkable performance of Ru SNC/W18O49 NWs for hydrogen electrocatalysis with 2.5 times of exchange current density than that of carbon-supported Ru nulloparticles, and even rival the state-of-the-art Pt catalyst. This work provides a new prospect for the development of supported sub-nullometric metal clusters for efficient electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206096", "DOI Link": "http://dx.doi.org/10.1002/advs.202206096", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906458500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, BL; Yoshida, S; Tsuji, N; Curtin, WA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Binglun; Yoshida, Shuhei; Tsuji, Nobuhiro; Curtin, W. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Yield strength and misfit volumes of NiCoCr and implications for short-range-order", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The face-centered cubic medium-entropy alloy NiCoCr has received considerable attention for its good mechanical properties, uncertain stacking fault energy, etc, some of which have been attributed to chemical short-range order (SRO). Here, we examine the yield strength and misfit volumes of NiCoCr to determine whether SRO has measurably influenced mechanical properties. Polycrystalline strengths show no systematic trend with different processing conditions. Measured misfit volumes in NiCoCr are consistent with those in random binaries. Yield strength prediction of a random NiCoCr alloy matches well with experiments. Finally, we show that standard spin-polarized density functional theory (DFT) calculations of misfit volumes are not accurate for NiCoCr. This implies that DFT may be inaccurate for other subtle structural quantities such as atom-atom bond distance so that caution is required in drawing conclusions about NiCoCr based on DFT. These findings all lead to the conclusion that, under typical processing conditions, SRO in NiCoCr is either negligible or has no systematic measurable effect on strength.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2507, "DOI": "10.1038/s41467-020-16083-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16083-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537282700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, YR; Wang, Q; Bak, SM; Hwang, S; Du, YH; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yiren; Wang, Qian; Bak, Seong-Min; Hwang, Sooyeon; Du, Yonghua; Wang, Hailiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification and Catalysis of the Potential-Limiting Step in Lithium-Sulfur Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Li-S chemistry is thermodynamically promising for high density energy storage but kinetically challenging. Over the past few years, many catalyst materials have been developed to improve the performance of Li-S batteries and their catalytic role has been increasingly accepted. However, the classic catalytic behavior, i.e., reduction of reaction barrier, has not been clearly observed. Crucial mechanistic questions, including what specific step is limiting the reaction rate, whether/how it can be catalyzed, and how the catalysis is sustained after the catalyst surface is covered by solid products, remain unullswered. Herein, we report the first identification of the potential-limiting step of Li-S batteries operating under lean electrolyte conditions and its catalysis that conforms to classic catalysis principles, where the catalyst lowers the kinetic barrier of the potential-limiting step and accelerates the reaction without affecting the product composition. After carefully examining the electrochemistry under lean electrolyte conditions, we update the pathway of the Li-S battery reaction: S8 solid is first reduced to Li2S8 and Li2S4 molecular species sequentially; the following reduction of Li2S4 to a Li2S2-Li2S solid with an almost constant ratio of 1:4 is the potential-limiting step; the previously believed Li2S2-to-Li2S solid-solid conversion does not occur; and the recharging reaction is relatively fast. We further demonstrate that supported cobalt phthalocyanine molecules can effectively catalyze the potential-limiting step. After Li2S2/Li2S buries the active sites, it can self catalyze the reaction and continue driving the discharging process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2023, "Volume": 145, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7390, "End Page": 7396, "Article Number": null, "DOI": "10.1021/jacs.2c13776", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c13776", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959417100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, SJ; Gong, C; Sun, YY; Tong, WY; Duan, CG; Chu, JH; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Shi-Jing; Gong, Cheng; Sun, Yu-Yun; Tong, Wen-Yi; Duan, Chun-Gang; Chu, Jun-Hao; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically induced 2D half-metallic antiferromagnets and spin field effect transistors", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering the electronic band structure of material systems enables the unprecedented exploration of new physical properties that are absent in natural or as-synthetic materials. Half metallicity, an intriguing physical property arising from the metallic nature of electrons with singular spin polarization and insulating for oppositely polarized electrons, holds a great potential for a 100% spin-polarized current for high-efficiency spintronics. Conventionally synthesized thin films hardly sustain half metallicity inherited from their 3D counterparts. A fundamental challenge, in systems of reduced dimensions, is the almost inevitable spinmixed edge or surface states in proximity to the Fermi level. Here, we predict electric field-induced half metallicity in bilayer A-type antiferromagnetic van der Waals crystals (i.e., intralayer ferromagnetism and interlayer antiferromagnetism), by employing density functional theory calculations on vanadium diselenide. Electric fields lift energy levels of the constituent layers in opposite directions, leading to the gradual closure of the gap of singular spin-polarized states and the opening of the gap of the others. We show that a vertical electrical field is a generic and effective way to achieve half metallicity in A-type antiferromagnetic bilayers and realize the spin field effect transistor. The electric field-induced half metallicity represents an appealing route to realize 2D half metals and opens opportunities for nulloscale highly efficient antiferromagnetic spintronics for information processing and storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2018, "Volume": 115, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8511, "End Page": 8516, "Article Number": null, "DOI": "10.1073/pnas.1715465115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1715465115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442351000039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZD; Wang, BY; Chen, YJ; Zhou, WH; Li, HP; Zhao, RZ; Li, XR; Zhang, TS; Bu, FX; Zhao, ZW; Li, W; Chao, DL; Zhao, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zhoudong; Wang, Boya; Chen, Yongjin; Zhou, Wanhai; Li, Hongpeng; Zhao, Ruizheng; Li, Xinran; Zhang, Tengsheng; Bu, Fanxing; Zhao, Zaiwang; Li, Wei; Chao, Dongliang; Zhao, Dongyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating sulfur oxidation reaction via six-electron redox mesocrystal NiS2 for sulfur-based aqueous batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sulfur-based aqueous batteries (SABs) are deemed promising candidates for safe, low-cost, and high-capacity energy storage. However, despite their high theoretical capacity, achieving high reversible value remains a great challenge due to the thermodynamic and kinetics problems of elemental sulfur. Here, the reversible six-electron redox electrochemistry is constructed by activating the sulfur oxidation reaction (SOR) process of the elaborate mesocrystal NiS2 (M-NiS2). Through the unique 6e(-) solid-to-solid conversion mechanism, SOR efficiency can reach an unprecedented degree of ca. 96.0%. The SOR efficiency is further revealed to be closely associated with the kinetics feasibility and thermodynamic stability of the M-NiS2 intermedium in the formation of elemental sulfur. Benefiting from the boosted SOR, compared with the bulk electrode, the M-NiS2 electrode exhibits a high reversible capacity (1258 mAh g(-1)), ultrafast reaction kinetics (932 mAh g(-1) at 12 A g(-1)), and long-term cyclability (2000 cycles at 20 A g(-1)). As a proof of concept, a new M-NiS2||Zn hybrid aqueous battery exhibits an output voltage of 1.60 V and an energy density of 722.4 Wh kg(cath)(-1), which opens a new opportunity for the development of high-energy aqueous batteries. Taking mesocrystal NiS2 as a model sulfur intermedium, we propose and figure out the kinetic and thermodynamic problems of sulfur oxidation reaction (SOR) process in S-based aqueous batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2023, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1093/nsr/nwac268", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac268", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914827900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, X; Li, TX; Cai, B; Miao, JS; Panin, GN; Ma, XY; Wang, JJ; Jiang, XY; Li, Q; Dong, Y; Hao, CH; Sun, JY; Xu, HY; Zhao, QX; Xia, MJ; Song, B; Chen, FS; Chen, XS; Lu, W; Hu, WD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Xiao; Li, Tangxin; Cai, Bin; Miao, Jinshui; Panin, Gennady N.; Ma, Xinyu; Wang, Jinjin; Jiang, Xiaoyong; Li, Qing; Dong, Yi; Hao, Chunhui; Sun, Juyi; Xu, Hangyu; Zhao, Qixiao; Xia, Mengjia; Song, Bo; Chen, Fansheng; Chen, Xiaoshuang; Lu, Wei; Hu, Weida", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graphene/MoS2-xOx/graphene photomemristor with tunable non-volatile responsivities for neuromorphic vision processing", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional artificial intelligence (AI) machine vision technology, based on the von Neumann architecture, uses separate sensing, computing, and storage units to process huge amounts of vision data generated in sensory terminals. The frequent movement of redundant data between sensors, processors and memory, however, results in high-power consumption and latency. A more efficient approach is to offload some of the memory and computational tasks to sensor elements that can perceive and process the optical signal simultaneously. Here, we proposed a non-volatile photomemristor, in which the reconfigurable responsivity can be modulated by the charge and/or photon flux through it and further stored in the device. The non-volatile photomemristor has a simple two-terminal architecture, in which photoexcited carriers and oxygen-related ions are coupled, leading to a displaced and pinched hysteresis in the current-voltage characteristics. For the first time, non-volatile photomemristors implement computationally complete logic with photoresponse-stateful operations, for which the same photomemristor serves as both a logic gate and memory, using photoresponse as a physical state variable instead of light, voltage and memresistance. The polarity reversal of photomemristors shows great potential for in-memory sensing and computing with feature extraction and image recognition for neuromorphic vision.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 39, "DOI": "10.1038/s41377-023-01079-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01079-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930948200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Courtade, E; Semina, M; Manca, M; Glazov, MM; Robert, C; Cadiz, F; Wang, G; Taniguchi, T; Watanabe, K; Pierre, M; Escoffier, W; Ivchenko, EL; Renucci, P; Marie, X; Amand, T; Urbaszek, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Courtade, E.; Semina, M.; Manca, M.; Glazov, M. M.; Robert, C.; Cadiz, F.; Wang, G.; Taniguchi, T.; Watanabe, K.; Pierre, M.; Escoffier, W.; Ivchenko, E. L.; Renucci, P.; Marie, X.; Amand, T.; Urbaszek, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charged excitons in monolayer WSe2: Experiment and theory", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charged excitons, or X-+/- trions, in monolayer transition-metal dichalcogenides have binding energies of several tens of meV. Together with the neutral exciton X-0 they dominate the emission spectrum at low and elevated temperatures. We use charge-tunable devices based on WSe2 monolayers encapsulated in hexagonal boron nitride to investigate the difference in binding energy between X+ and X- and the X- fine structure. We find in the charge-neutral regime, the X-0 emission accompanied at lower energy by a strong peak close to the longitudinal optical (LO) phonon energy. This peak is absent in reflectivity measurements, where only the X-0 and an excited state of the X-0 are visible. In the n-doped regime, we find a closer correspondence between emission and reflectivity as the trion transition with a well-resolved fine-structure splitting of 6 meV for X- is observed. We present a symmetry analysis of the different X+ and X- trion states and results of the binding energy calculations. We compare the trion binding energy for the n- and p-doped regimes with our model calculations for low carrier concentrations. We demonstrate that the splitting between the X+ and X- trions as well as the fine structure of the X(-)state can be related to the short-range Coulomb-exchange interaction between the charge carriers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2017, "Volume": 96, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85302, "DOI": "10.1103/PhysRevB.96.085302", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.085302", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407017100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdelhamid, HN; Georgouvelas, D; Edlund, U; Mathew, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdelhamid, Hani Nasser; Georgouvelas, Dimitrios; Edlund, Ulrica; Mathew, Aji P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CelloZIFPaper: Cellulose-ZIF hybrid paper for heavy metal removal and electrochemical sensing", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The processing of hierarchical porous zeolitic imidazolate frameworks (ZIF-8) into a cellulose paper using sheet former Rapid-Kothen (R.K.) is reported. The procedure is a promising route to overcome a significant bottleneck towards applying metal-organic frameworks (MOFs) in commercial products. ZIF-8 crystals were integrated into cellulose pulp (CP) or TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-oxidized cellulose nullofibrils (TOCNF) following an in-situ or ex-situ process; the materials were denoted as CelloZIFPaper_In Situ and CelloZIFPaper_Ex Situ, respectively. The materials were applied as adsorbents to remove heavy metals from water, with adsorption capacities of 66.2-354.0 mg/g. CelloZIFPaper can also be used as a stand-alone working electrode for the selective sensing of toxic heavy metals, for instance, lead ions (Pb2+), using electrochemical-based methods with a limit of detection (LOD) of 8 mu M. The electrochemical measurements may advance 'Lab-onCelloZIFPaper' technologies for label-free detection of heavy metal ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2022, "Volume": 446, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136614, "DOI": "10.1016/j.cej.2022.136614", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.136614", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830784600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krasnok, A; Tymchenko, M; Alù, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krasnok, Alexander; Tymchenko, Mykhailo; Alu, Andrea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonlinear metasurfaces: a paradigm shift in nonlinear optics", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Frequency conversion processes, such as second-and third-harmonic generation, are commonly realized in nonlinear optics, offering opportunities for applications in photonics, chemistry, material science and biosensing. Given the inherently weak nonlinear response of natural materials, optically large samples and complex phase-matching techniques are typically required to realize significant nonlinear responses. To produce similar effects in much smaller volumes, current research has been devoted to the quest of synthesizing novel materials with enhanced optical nonlinearities at moderate input intensities. In particular, several approaches to engineer the nonlinear properties of artificial materials, metamaterials and metasurfaces have been introduced. Here, we review the current state of the art in the field of small-scale nonlinear optics, with special emphasis on high-harmonic generation from ultrathin metasurfaces based on plasmonic and high-index dielectric resonators, as well as semiconductor-loaded plasmonic metasurfaces. In this context, we also discuss recent advances in controlling the optical wavefront of generated nonlinear waves using metasurfaces. Finally, we compare viable approaches to enhance nonlinearities in ultrathin metasurfaces, and we offer an outlook on the future development of this exciting field of research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 496, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2018, "Volume": 21, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8, "End Page": 21, "Article Number": null, "DOI": "10.1016/j.mattod.2017.06.007", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2017.06.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426035100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Freakley, SJ; Ruiz-Esquius, J; Morgan, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Freakley, S. J.; Ruiz-Esquius, J.; Morgan, D. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The X-ray photoelectron spectra of Ir, IrO2 and IrCl3 revisited", "Source Title": "SURFACE AND INTERFACE ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The X-ray photoelectron spectra of metallic iridium and the technologically important iridium compounds, IrO2 and IrCl3, have been studied. The results not only improve the accuracy of published data but also expand the binding energy database of other iridium core-levels. The difference between anhydrous and hydrated materials is explored, and the effect on curve-fitting is discussed, together with the derivation of suitable line shapes for peak fitting of data acquired from a conventional monochromatic Al K-alpha X-ray source. Copyright (C) 2017 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 49, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 794, "End Page": 799, "Article Number": null, "DOI": "10.1002/sia.6225", "DOI Link": "http://dx.doi.org/10.1002/sia.6225", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407287100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, L; Salehi, M; Koirala, N; Moon, J; Oh, S; Armitage, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Liang; Salehi, M.; Koirala, N.; Moon, J.; Oh, S.; Armitage, N. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantized Faraday and Kerr rotation and axion electrodynamics of a 3D topological insulator", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological insulators have been proposed to be best characterized as bulk magnetoelectric materials that show response functions quantized in terms of fundamental physical constants. Here, we lower the chemical potential of three-dimensional (3D) Bi2Se3 films to similar to 30 meV above the Dirac point and probe their low-energy electrodynamic response in the presence of magnetic fields with high-precision time-domain terahertz polarimetry. For fields higher than 5 tesla, we observed quantized Faraday and Kerr rotations, whereas the dc transport is still semiclassical. A nontrivial Berry's phase offset to these values gives evidence for axion electrodynamics and the topological magnetoelectric effect. The time structure used in these measurements allows a direct measure of the fine-structure constant based on a topological invariant of a solid-state system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2016, "Volume": 354, "Issue": 6316, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1124, "End Page": 1127, "Article Number": null, "DOI": "10.1126/science.aaf5541", "DOI Link": "http://dx.doi.org/10.1126/science.aaf5541", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388916400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZW; He, X; Zhang, CL; Wang, XC; Zhang, SJ; Jia, YT; Feng, SM; Lu, K; Zhao, JF; Zhang, J; Min, BS; Long, YW; Yu, RC; Wang, LH; Ye, MY; Zhang, ZS; Prakapenka, V; Chariton, S; Ginsberg, PA; Bass, J; Yuan, SH; Liu, HZ; Jin, CQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiwen; He, Xin; Zhang, Changling; Wang, Xiancheng; Zhang, Sijia; Jia, Yating; Feng, Shaomin; Lu, Ke; Zhao, Jianfa; Zhang, Jun; Min, Baosen; Long, Youwen; Yu, Richeng; Wang, Luhong; Ye, Meiyan; Zhang, Zhanshuo; Prakapenka, Vitali; Chariton, Stella; Ginsberg, Paul A.; Bass, Jay; Yuan, Shuhua; Liu, Haozhe; Jin, Changqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity above 200 K discovered in superhydrides of calcium", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Searching for superconductivity with T c near room temperature is of great interest both for fundamental science & many potential applications. Here we report the experimental discovery of superconductivity with maximum critical temperature (T-c) above 210 K in calcium superhydrides, the new alkali earth hydrides experimentally showing superconductivity above 200 K in addition to sulfur hydride & rare-earth hydride system. The materials are synthesized at the synergetic conditions of 160-190 GPa and similar to 2000 K using diamond anvil cell combined with in-situ laser heating technique. The superconductivity was studied through in-situ high pressure electric conductance measurements in an applied magnetic field for the sample quenched from high temperature while maintained at high pressures. The upper critical field Hc(0) was estimated to be similar to 268 T while the GL coherent length is similar to 11 angstrom. The in-situ synchrotron X-ray diffraction measurements suggest that the synthesized calcium hydrides are primarily composed of CaH6 while there may also exist other calcium hydrides with different hydrogen contents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2863, "DOI": "10.1038/s41467-022-30454-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30454-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000802699200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, ZX; Zhang, H; Priimagi, A; Zeng, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Zixuan; Zhang, Hang; Priimagi, Arri; Zeng, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-Fueled Nonreciprocal Self-Oscillators for Fluidic Transportation and Coupling", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-fueled self-oscillators based on soft actuating materials have triggered novel designs for small-scale robotic constructs that self-sustain their motion at non-equilibrium states and possess bioinspired autonomy and adaptive functions. However, the motions of most self-oscillators are reciprocal, which hinders their use in sophisticated biomimetic functions such as fluidic transportation. Here, an optically powered soft material strip that can perform nonreciprocal, cilia-like, self-sustained oscillation under water is reported. The actuator is made of planar-aligned liquid crystal elastomer responding to visible light. Two laser beams from orthogonal directions allow for piecewise control over the strip deformation, enabling two self-shadowing effects coupled in one single material to yield nonreciprocal strokes. The nonreciprocity, stroke pattern and handedness are connected to the fluidic pumping efficiency, which can be controlled by the excitation conditions. Autonomous microfluidic pumping in clockwise and anticlockwise directions, translocation of a micro-object by liquid propulsion, and coupling between two oscillating strips through liquid medium interaction are demonstrated. The results offer new concepts for non-equilibrium soft actuators that can perform bio-like functions under water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2024, "Volume": 36, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209683", "DOI Link": "http://dx.doi.org/10.1002/adma.202209683", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906511900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Binninger, T; Mohamed, R; Waltar, K; Fabbri, E; Levecque, P; Kötz, R; Schmidt, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Binninger, Tobias; Mohamed, Rhiyaad; Waltar, Kay; Fabbri, Emiliana; Levecque, Pieter; Koetz, Ruediger; Schmidt, Thomas J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamic explanation of the universal correlation between oxygen evolution activity and corrosion of oxide catalysts", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the oxygen evolution reaction (OER) has attracted increased research interest due to its crucial role in electrochemical energy conversion devices for renewable energy applications. The vast majority of OER catalyst materials investigated are metal oxides of various compositions. The experimental results obtained on such materials strongly suggest the existence of a fundamental and universal correlation between the oxygen evolution activity and the corrosion of metal oxides. This corrosion manifests itself in structural changes and/or dissolution of the material. We prove from basic thermodynamic considerations that any metal oxide must become unstable under oxygen evolution conditions irrespective of the pH value. The reason is the thermodynamic instability of the oxygen anion in the metal oxide lattice. Our findings explain many of the experimentally observed corrosion phenomena on different metal oxide OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 364, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12167, "DOI": "10.1038/srep12167", "DOI Link": "http://dx.doi.org/10.1038/srep12167", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358007900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dávila, ME; Le Lay, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Davila, Maria Eugenia; Le Lay, Guy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Few layer epitaxial germanene: a novel two-dimensional Dirac material", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer germanene, a novel graphene-like germanium allotrope akin to silicene has been recently grown on metallic substrates. Lying directly on the metal surfaces the reconstructed atom-thin sheets are prone to lose the massless Dirac fermion character and unique associated physical properties of free standing germanene. Here, we show that few layer germanene, which we create by dry epitaxy on a gold template, possesses Dirac cones thanks to a reduced interaction. This finding established on synchrotron-radiation-based photoemission, scanning tunneling microscopy imaging and surface electron diffraction places few layer germanene among the rare two-dimensional Dirac materials. Since germanium is currently used in the mainstream Si-based electronics, perspectives of using germanene for scaling down beyond the 5 nm node appear very promising. Other fascinating properties seem at hand, typically the robust quantum spin Hall effect for applications in spintronics and the engineering of Floquet Majorana fermions by light for quantum computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20714, "DOI": "10.1038/srep20714", "DOI Link": "http://dx.doi.org/10.1038/srep20714", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369744800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, DY; Wynn, TA; Wang, XF; Wang, S; Zhang, MH; Shimizu, R; Bai, S; Nguyen, H; Fang, CC; Kim, MC; Li, WK; Lu, BY; Kim, SJ; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Diyi; Wynn, Thomas A.; Wang, Xuefeng; Wang, Shen; Zhang, Minghao; Shimizu, Ryosuke; Bai, Shuang; Nguyen, Han; Fang, Chengcheng; Kim, Min-cheol; Li, Weikang; Lu, Bingyu; Kim, Suk Jun; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling the Stable Nature of the Solid Electrolyte Interphase between Lithium Metal and LiPON via Cryogenic Electron Microscopy", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The solid electrolyte interphase (SEI) is regarded as the most coin center dot plex but the least understood constituent in secondary batteries using liquid and solid electrolytes. The dearth of such knowledge in allsolid-state battery (ASSB) has hindered a complete understanding of how certain solid-state electrolytes, such as UPON, manifest exemplary stability against lithium metal By employing cryogenic electron microscopy (cryo-EM), the interphase between lithium metal and LiPON is successfully preserved and probed, revealing a multilayer-mosaic SEI structure with concentration gradients of nitrogen and phosphorus, materializing as crystallites within an amorphous matrix. This unique SEI nullostructure is less than 80 nm and is stable and free of any organic lithium-containing species or lithium fluoride components, in contrast to SEIs often found in state-of-the-art organic liquid electrolytes. Our findings reveal insights on the nullostructures and chemistry of such SEIs as a key component in lithium metal batteries to stabilize lithium metal anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2020, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2484, "End Page": 2500, "Article Number": null, "DOI": "10.1016/j.joule.2020.08.013", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.08.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592226000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YB; Sun, JW; Perdew, JP; Wu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yubo; Sun, Jianwei; Perdew, John P.; Wu, Xifan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparative first-principles studies of prototypical ferroelectric materials by LDA, GGA, and SCAN meta-GGA", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Originating from a broken spatial inversion symmetry, ferroelectricity is a functionality of materials with an electric dipole that can be switched by external electric fields. Spontaneous polarization is a crucial ferroelectric property, and its amplitude is determined by the strength of polar structural distortions. Density functional theory (DFT) is one of the most widely used theoretical methods to study ferroelectric properties, yet it is limited by the levels of approximations in electron exchange-correlation. On the one hand, the local density approximation (LDA) is considered to be more accurate for the conventional perovskite ferroelectrics such as BaTiO3 and PbTiO3 than the generalized gradient approximation (GGA), which suffers from the so-called super-tetragonality error. On the other hand, GGA is more suitable for hydrogen-bonded ferroelectrics than LDA, which largely overestimates the strength of hydrogen bonding in general. We show here that the recently developed general-purpose strongly constrained and appropriately normed (SCAN) meta-GGA functional significantly improves over the traditional LDA/GGA for structural, electric, and energetic properties of diversely bonded ferroelectric materials with a comparable computational effort and thus enhances largely the predictive power of DFT in studies of ferroelectric materials. We also address the observed system-dependent performances of LDA and GGA for ferroelectrics from a chemical bonding point of view.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2017, "Volume": 96, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35143, "DOI": "10.1103/PhysRevB.96.035143", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.035143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406244000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, NX; Luo, YQ; Chen, ZH; Niu, XX; Zhang, X; Lu, JZ; Kumar, R; Jiang, JK; Liu, HF; Guo, X; Lai, B; Brocks, G; Chen, Q; Tao, SX; Fenning, DP; Zhou, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Nengxu; Luo, Yanqi; Chen, Zehua; Niu, Xiuxiu; Zhang, Xiao; Lu, Jiuzhou; Kumar, Rishi; Jiang, Junke; Liu, Huifen; Guo, Xiao; Lai, Barry; Brocks, Geert; Chen, Qi; Tao, Shuxia; Fenning, David P.; Zhou, Huanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microscopic Degradation in Formamidinium-Cesium Lead Iodide Perovskite Solar Cells under Operational Stressors", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The most important obstacle to widespread use of perovskite solar cells is their poor stability under operational stressors. Here, we systematically monitor the evolution of the photovoltaic performance of perovskite solar cells based on formamidinium-cesium lead iodide (FA(0)(.)(9)Cs(0.1)PbI(3)) for 600 h, under a series of controlled oper center dot ational stressors. Although these devices exhibit reasonable thermal stability, their stability under illumination or stabilized power output (SPO) is far from commercial demands. Synchrotron-based nulloprobe X-ray fluorescence and X-ray-beam-induced current measurements reveal that current-blocking Cs-rich phases segregate during stress tests. The decrease in performance is in line with the increasing density of the Cs-rich clusters in area upon illumination. Theoretical calculations indicate that light-generated carriers provide the thermodynamic driving force for that phase segre center dot gation. Our findings correlate device performance to microscopic behavior and atomistic mechanisms and shed light on inhibiting the cation-dependent phase segregation during device operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2020, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1743, "End Page": 1758, "Article Number": null, "DOI": "10.1016/j.joule.2020.06.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.06.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561454400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saravanull, R; Khan, MM; Gupta, VK; Mosquera, E; Gracia, F; Narayanull, V; Stephen, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saravanull, R.; Khan, Mohammad Mansoob; Gupta, Vinod Kumar; Mosquera, E.; Gracia, F.; Narayanull, V.; Stephen, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ZnO/Ag/Mn2O3 nullocomposite for visible light-induced industrial textile effluent degradation, uric acid and ascorbic acid sensing and antimicrobial activity", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile and inexpensive route has been developed to synthesize a ternary ZnO/Ag/Mn2O3 nullocomposite having nullorod structures based on the thermal decomposition method. The as-synthesized ternary ZnO/g/Mn2O3 nullocomposite was characterized and used for visible light-induced photocatalytic, sensing and antimicrobial studies. The ternary ZnO/Ag/Mn2O3 nullocomposite exhibited excellent and enhanced visible light-induced photocatalytic degradation of industrial textile effluent (real sample analysis) compared to pure ZnO. Sensing studies showed that the ternary ZnO/Ag/Mn2O3 nullocomposite exhibited outstanding and improved detection of uric acid (UA) and ascorbic acid (AA). It also showed effective and efficient bactericidal activities against Staphylococcus aureus and Escherichia coli. These results suggest that the small size, high surface area and synergistic effect among ZnO, AgNPs and Mn2O3 induced visible light photocatalytic activity by decreasing the recombination of photogenerated electrons and holes, and extending the response of pure ZnO to visible light, enhanced sensing of UA and AA and antimicrobial activity. Overall, the ternary ZnO/Ag/Mn2O3 nullocomposite is a valuable material that can be used for a range of applications, such as visible light-induced photocatalysis, sensing and antimicrobial activity. Therefore, ternary nullocomposites could have important applications in environmental science, sensing, and biological fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 417, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 5, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 34645, "End Page": 34651, "Article Number": null, "DOI": "10.1039/c5ra02557e", "DOI Link": "http://dx.doi.org/10.1039/c5ra02557e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353168300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, QC; Liang, YP; Zou, QL; Hong, Y; Zhang, BC; Liu, H; Kong, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Qican; Liang, Yunpei; Zou, Quanle; Hong, Yang; Zhang, Bichuan; Liu, Hao; Kong, Fanjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental investigation on mechanical characteristics of red sandstone under graded cyclic loading and its inspirations for stability of overlying strata", "Source Title": "GEOMECHANICS AND GEOPHYSICS FOR GEO-ENERGY AND GEO-RESOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The horizontal stress in the fractured blocks of a fractured zone is in a stress relief status under repeated mining disturbances. To investigate the effect of the horizontal stress in fractured blocks on the stability of the overlying strata, uniaxially graded cyclic loading and unloading experiments on red sandstone with different initial stress level were carried out. First, the evolution of the loading and unloading elastic modulus, irreversible strain and load-unload response ratio were analyzed. Then, the strain energy evolution and damage variable characteristics were examined. Finally, the stability of a voussoir beam structure under repeated mining disturbances was discussed. The results showed that with increasing cycle number, the elastic modulus showed a nonlinear decreasing trend, the load-unload response ratio always fluctuated at approximately 1, and the irreversible strain showed a rapid and steady increasing trend. The proportion of elastic energy tended to increase linearly with increasing cycle number, while the proportion of dissipated strain energy tended to decrease. Moreover, the damage variable, based on the dissipation strain energy definition, showed a parabolic growth trend with increasing cycle number. The irreversible strain and damage variables showed an increasing-decreasing-increasing trend as the initial stress level increased. Finally, a stability criterion of the voussoir beam structure based on the effect of repeated mining disturbances on horizontal thrust was proposed. This research has important implications for overlying strata stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 44, "Times Cited, All Databases": 45, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11, "DOI": "10.1007/s40948-023-00555-x", "DOI Link": "http://dx.doi.org/10.1007/s40948-023-00555-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering; Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935895000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, YX; Huang, YX; Zhang, YG; Wu, TR; Liu, SS; Sun, ML; Lee, B; Lin, Z; Chen, H; Dai, P; Huang, Z; Yang, JA; Shi, CG; Wu, DY; Huang, L; Hua, YJ; Wang, CT; Sun, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yuxiang; Huang, Yixin; Zhang, Yinggan; Wu, Tairui; Liu, Shishi; Sun, Miaolan; Lee, Bruce; Lin, Zhen; Chen, Hui; Dai, Peng; Huang, Zheng; Yang, Jian; Shi, Chenguang; Wu, Deyin; Huang, Ling; Hua, Yingjie; Wang, Chongtai; Sun, Shigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface modification using heptafluorobutyric acid to produce highly stable Li metal anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200h at 1.0mAcm(-2)) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2883, "DOI": "10.1038/s41467-023-38724-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38724-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058116700029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YX; Guo, S; Chen, MJ; Lu, BA; Zhang, XT; Liang, SQ; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yunxiang; Guo, Shan; Chen, Manjing; Lu, Bingan; Zhang, Xiaotan; Liang, Shuquan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring grain boundary stability of zinc-titanium alloy for long-lasting aqueous zinc batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The detrimental parasitic reactions and uncontrolled deposition behavior derived from inherently unstable interface have largely impeded the practical application of aqueous zinc batteries. So far, tremendous efforts have been devoted to tailoring interfaces, while stabilization of grain boundaries has received less attention. Here, we demonstrate that preferential distribution of intermetallic compounds at grain boundaries via an alloying strategy can substantially suppress intergranular corrosion. In-depth morphology analysis reveals their thermodynamic stability, ensuring sustainable potency. Furthermore, the hybrid nucleation and growth mode resulting from reduced Gibbs free energy contributes to the spatially uniform distribution of Zn nuclei, promoting the dense Zn deposition. These integrated merits enable a high Zn reversibility of 99.85% for over 4000 cycles, steady charge-discharge at 10 mA cm-2, and impressive cyclability for roughly 3500 cycles in Zn-Ti//NH4V4O10 full cell. Notably, the multi-layer pouch cell of 34 mAh maintains stable cycling for 500 cycles. This work highlights a fundamental understanding of microstructure and motivates the precise tuning of grain boundary characteristics to achieve highly reversible Zn anodes. The electrochemical performance of metal electrodes is significantly influenced by their grain boundary stability. Here, the authors propose a zinc-titanium two-phase alloy via grain boundary engineering to inhibit intergranular corrosion and tailor deposition behavior for stable aqueous zinc batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7080, "DOI": "10.1038/s41467-023-42919-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42919-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001100866900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, ZG; Zhang, TS; Liu, X; Xu, ZB; Liu, JH; Zhou, WH; Qian, YT; Fan, HJ; Chao, DL; Zhao, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Zhiguo; Zhang, Tengsheng; Liu, Xin; Xu, Zhibin; Liu, Jiahao; Zhou, Wanhai; Qian, Yitai; Fan, Hong Jin; Chao, Dongliang; Zhao, Dongyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A solid-to-solid metallic conversion electrochemistry toward 91% zinc utilization for sustainable aqueous batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The diffusion-limited aggregation (DLA) of metal ion (Mn+) during the repeated solid-to-liquid (StoL) plating and liquid-to-solid (LtoS) stripping processes intensifies fatal dendrite growth of the metallic anodes. Here, we report a new solid-to-solid (StoS) conversion electrochemistry to inhibit dendrites and improve the utilization ratio of metals. In this StoS strategy, reversible conversion reactions between sparingly soluble carbonates (Zn or Cu) and their corresponding metals have been identified at the electrode/electrolyte interface. Molecular dynamics simulations confirm the superiority of the StoS process with accelerated anion transport, which eliminates the DLA and dendrites in the conventional LtoS/StoL processes. As proof of concept, 2ZnCO(3)center dot 3Zn(OH) (2) exhibits a high zinc utilization of ca. 95.7% in the asymmetry cell and 91.3% in a 2ZnCO(3)center dot 3Zn(OH) (2) || Ni-based full cell with 80% capacity retention over 2000 cycles. Furthermore, the designed 1-Ah pouch cell device can operate stably with 500 cycles, delivering a satisfactory total energy density of 135 Wh kg(-1)", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2022, "Volume": 8, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/sciadv.abp8960", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abp8960", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964410000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Inal, S; Malliaras, GG; Rivnay, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Inal, Sahika; Malliaras, George G.; Rivnay, Jonathan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Benchmarking organic mixed conductors for transistors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic mixed conductors have garnered significant attention in applications from bioelectronics to energy storage/generation. Their implementation in organic transistors has led to enhanced biosensing, neuromorphic function, and specialized circuits. While a narrow class of conducting polymers continues to excel in these new applications, materials design efforts have accelerated as researchers target new functionality, processability, and improved performance/stability. Materials for organic electrochemical transistors (OECTs) require both efficient electronic transport and facile ion injection in order to sustain high capacity. In this work, we show that the product of the electronic mobility and volumetric charge storage capacity (mu C*) is the materials/system figure of merit; we use this framework to benchmark and compare the steady-state OECT performance of ten previously reported materials. This product can be independently verified and decoupled to guide materials design and processing. OECTs can therefore be used as a tool for understanding and designing new organic mixed conductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1767, "DOI": "10.1038/s41467-017-01812-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01812-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416292800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, HD; Wang, Q; Zhang, A; Niu, GD; Nikl, M; Ming, C; Zhu, JS; Zhou, ZY; Sun, YY; null, GJ; Ren, GH; Wu, YT; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Haodi; Wang, Qian; Zhang, Ao; Niu, Guangda; Nikl, Martin; Ming, Chen; Zhu, Jinsong; Zhou, Zhengyang; Sun, Yi-Yang; null, Guangjun; Ren, Guohao; Wu, Yuntao; Tang, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-dimensional scintillator film with benign grain boundaries for high-resolution and fast x-ray imaging", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fast and high-resolution x-ray imaging demands scintillator films with negligible afterglow, high scintillation yield, and minimized cross-talk. However, grain boundaries (GBs) are abundant in polycrystalline scintillator film, and, for current inorganic scintillators, detrimental dangling bonds at GBs inevitably extend radioluminescence lifetime and increase nonradiative recombination loss, deteriorating afterglow and scintillation yield. Here, we demonstrate that scintillators with one-dimensional (1D) crystal structure, Cs5Cu3Cl6I2 explored here, possess benign GBs without dangling bonds, yielding nearly identical afterglow and scintillation yield for single crystals and polycrystalline films. Because of its 1D crystal structure, Cs5Cu3Cl6I2 films with desired columnar morphology are easily obtained via close space sublimation, exhibit negligible afterglow (0.1% at 10 ms) and high scintillation yield (1.2 times of CsI:Tl). We have also demonstrated fast x-ray imaging with 27 line pairs mm(-1) resolution and frame rate up to 33 fps, surpassing most existing scintillators. We believe that the 1D scintillators can greatly boost x-ray imaging performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 9, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadh1789", "DOI": "10.1126/sciadv.adh1789", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adh1789", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001039293600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, LW; Lytle, TK; Radhakrishna, M; Madinya, JJ; Vélez, J; Sing, CE; Perry, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Li-Wei; Lytle, Tyler K.; Radhakrishna, Mithun; Madinya, Jason J.; Velez, Jon; Sing, Charles E.; Perry, Sarah L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sequence and entropy-based control of complex coacervates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomacromolecules rely on the precise placement of monomers to encode information for structure, function, and physiology. Efforts to emulate this complexity via the synthetic control of chemical sequence in polymers are finding success; however, there is little understanding of how to translate monomer sequence to physical material properties. Here we establish design rules for implementing this sequence-control in materials known as complex coacervates. These materials are formed by the associative phase separation of oppositely charged polyelectrolytes into polyelectrolyte dense (coacervate) and polyelectrolyte dilute (supernatant) phases. We demonstrate that patterns of charges can profoundly affect the charge-charge associations that drive this process. Furthermore, we establish the physical origin of this pattern-dependent interaction: there is a nuanced combination of structural changes in the dense coacervate phase and a 1D confinement of counterions due to patterns along polymers in the supernatant phase.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1273, "DOI": "10.1038/s41467-017-01249-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01249-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414245600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YH; Valenzuela, C; Zhang, X; Yang, X; Wang, L; Feng, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuanhao; Valenzuela, Cristian; Zhang, Xuan; Yang, Xiao; Wang, Ling; Feng, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-driven dandelion-inspired microfliers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In nature, many plants have evolved diverse flight mechanisms to disperse seeds by wind and propagate their genetic information. Inspired by the flight mechanism of the dandelion seeds, we demonstrate light-driven dandelion-inspired microfliers based on ultralight and super-sensitive tubular-shaped bimorph soft actuator. Like dandelion seeds in nature, the falling velocity of the as-proposed microflier in air can be facilely controlled by tailoring the degree of deformation of the pappus under different light irradiations. Importantly, the resulting microflier is able to achieve a mid-air flight above a light source with a sustained flight time of similar to 8.9 s and a maximum flight height of similar to 350mm thanks to the unique dandelion-like 3D structures. Unexpectedly, the resulting microflier is found to exhibit light-driven upward flight accompanied by autorotating motion, and the rotation mode can be customized in either a clockwise or counterclockwise direction by engineering the shape programmability of bimorph soft actuator films. The research disclosed herein can offer new insights into the development of untethered and energy-efficient artificial aerial vehicles that are of paramount significance for many applications from environmental monitoring and wireless communication to future solar sail and robotic spacecraft.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3036, "DOI": "10.1038/s41467-023-38792-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38792-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004174800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XD; Liu, KW; Sha, YY; Yang, JC; Song, RT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xudong; Liu, Kewei; Sha, Yanyan; Yang, Jiacai; Song, Ruitao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical investigation on rock fragmentation under decoupled charge blasting", "Source Title": "COMPUTERS AND GEOTECHNICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Blasting using decoupled charge is extensively applied in rock excavation and rock fragmentation. In this study, the rock fragmentation induced by blasting using decoupled charge is investigated by combined finite element modelling and image-processing. After calibrating the numerical model developed in LS-DYNA against the fragment morphology and fragmentation size distribution (FSD) in three air-coupling blasts and three watercoupling blasts, a series of cubic single-hole models are constructed to simulate rock cracking induced by decoupled charge blasting with various decoupling ratios, distinct coupling mediums and different decoupled charge modes. The simulated fracture networks are obtained by blanking the damaged elements whose damage level is over the threshold of crack formation, and the resulting crack patterns are image-processed using ImageJ to identify fragment size. Then, the blast-created FSDs are characterized by a three-parameter generalized extreme value function, and the FSDs with decoupling ratios, coupling mediums and different decoupled charge modes are quantitatively analyzed and compared. The results show that rock fragmentation becomes finer and the FSD range gets narrower with the decrease in decoupling ratio. Meanwhile, smaller fragment sizes and narrower FSD spans are obtained when changing coupling material from air to water and altering radial decoupling to axial decoupling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105312, "DOI": "10.1016/j.compgeo.2023.105312", "DOI Link": "http://dx.doi.org/10.1016/j.compgeo.2023.105312", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000946742900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XB; Yang, JR; Li, P; Wang, QS; Wu, JB; Zhang, E; Chen, SH; Zhuang, ZC; Lai, WH; Dou, SX; Sun, WP; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaobo; Yang, Jiarui; Li, Peng; Wang, Qishun; Wu, Jiabin; Zhang, Erhuan; Chen, Shenghua; Zhuang, Zechao; Lai, Weihong; Dou, Shixue; Sun, Wenping; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ir-Sn pair-site triggers key oxygen radical intermediate for efficient acidic water oxidation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The anode corrosion induced by the harsh acidic and oxidative environment greatly restricts the lifespan of catalysts. Here, we propose an antioxidation strategy to mitigate Ir dissolution by triggering strong electronic interaction via elaborately constructing a heterostructured Ir-Sn pair-site catalyst. The formation of Ir-Sn dual-site at the heterointerface and the resulting strong electronic interactions considerably reduce d-band holes of Ir species during both the synthesis and the oxygen evolution reaction processes and suppress their overoxidation, enabling the catalyst with substantially boosted corrosion resistance. Consequently, the optimized catalyst exhibits a high mass activity of 4.4 A mg(Ir)(-1) at an overpotential of 320 mV and outstanding long-term stability. A proton-exchange-membrane water electrolyzer using this catalyst delivers a current density of 2 A cm(-2) at 1.711 V and low degradation in an accelerated aging test. Theoretical calculations unravel that the oxygen radicals induced by the pi* interaction between Ir 5d-O 2p might be responsible for the boosted activity and durability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2023, "Volume": 9, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadi8025", "DOI": "10.1126/sciadv.adi8025", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adi8025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001087790200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baghi, F; Gharsallaoui, A; Dumas, E; Ghnimi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baghi, Fatemeh; Gharsallaoui, Adem; Dumas, Emilie; Ghnimi, Sami", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advancements in Biodegradable Active Films for Food Packaging: Effects of nullo/Microcapsule Incorporation", "Source Title": "FOODS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Food packaging plays a fundamental role in the modern food industry as a main process to preserve the quality of food products from manufacture to consumption. New food packaging technologies are being developed that are formulated with natural compounds by substituting synthetic/chemical antimicrobial and antioxidant agents to fulfill consumers' expectations for healthy food. The strategy of incorporating natural antimicrobial compounds into food packaging structures is a recent and promising technology to reach this goal. Concepts such as biodegradable packaging, active packaging, and bioactive packaging currently guide the research and development of food packaging. However, the use of natural compounds faces some challenges, including weak stability and sensitivity to processing and storage conditions. The nullo/microencapsulation of these bioactive compounds enhances their stability and controls their release. In addition, biodegradable packaging materials are gaining great attention in the face of ever-growing environmental concerns about plastic pollution. They are a sustainable, environmentally friendly, and cost-effective alternative to conventional plastic packaging materials. Ultimately, a combined formulation of nullo/microencapsulated antimicrobial and antioxidant natural molecules, incorporated into a biodegradable food packaging system, offers many benefits by preventing food spoilage, extending the shelf life of food, reducing plastic and food waste, and preserving the freshness and quality of food. The main objective of this review is to illustrate the latest advances in the principal biodegradable materials used in the development of active antimicrobial and antioxidant packaging systems, as well as the most common nullo/microencapsulated active natural agents incorporated into these food-packaging materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 11, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 760, "DOI": "10.3390/foods11050760", "DOI Link": "http://dx.doi.org/10.3390/foods11050760", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771011300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, S; Rosales, HD; Albarracín, FGA; Tsurkan, V; Kaur, G; Fennell, T; Steffens, P; Boehm, M; Cermák, P; Schneidewind, A; Ressouche, E; Cabra, DC; Rüegg, C; Zaharko, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Shang; Rosales, H. Diego; Gomez Albarracin, Flavia A.; Tsurkan, Vladimir; Kaur, Guratinder; Fennell, Tom; Steffens, Paul; Boehm, Martin; Cermak, Petr; Schneidewind, Astrid; Ressouche, Eric; Cabra, Daniel C.; Rueegg, Christian; Zaharko, Oksana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractional antiferromagnetic skyrmion lattice induced by anisotropic couplings", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are topological solitons with a nulloscale winding spin texture that hold promise for spintronics applications(1-4). Skyrmions have so far been observed in a variety of magnets that exhibit nearly parallel alignment for neighbouring spins, but theoretically skyrmions with anti-parallel neighbouring spins are also possible. Such antiferromagnetic skyrmions may allow more flexible control than conventional ferromagnetic skyrmions(5-10). Here, by combining neutron scattering measurements and Monte Carlo simulations, we show that a fractional antiferromagnetic skyrmion lattice is stabilized in MnSc(2)S(4)through anisotropic couplings. The observed lattice is composed of three antiferromagnetically coupled sublattices, and each sublattice is a triangular skyrmion lattice that is fractionalized into two parts with an incipient meron (half-skyrmion) character(11,12). Our work demonstrates that the theoretically proposed antiferromagnetic skyrmions can be stabilized in real materials and represents an important step towards their implementation in spintronic devices. Theoretically predicted fractional antiferromagnetic skyrmions are experimentally realized in MnSc(2)S(4)and are found to originate from anisotropic couplings over nearest neighbours in the crystal lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2020, "Volume": 586, "Issue": 7827, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 37, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2716-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2716-8", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572352700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, T; Foley, BJ; Park, C; Brown, CM; Harriger, LW; Lee, J; Ruff, J; Yoon, M; Choi, JJ; Lee, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Tianran; Foley, Benjamin J.; Park, Changwon; Brown, Craig M.; Harriger, Leland W.; Lee, Jooseop; Ruff, Jacob; Yoon, Mina; Choi, Joshua J.; Lee, Seung-Hun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy-driven structural transition and kinetic trapping in formamidinium lead iodide perovskite", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A challenge of hybrid perovskite solar cells is device instability, which calls for an understanding of the perovskite structural stability and phase transitions. Using neutron diffraction and first-principles calculations on formamidinium lead iodide (FAPbI(3)), we show that the entropy contribution to the Gibbs free energy caused by isotropic rotations of the FA(+) cation plays a crucial role in the cubic-to-hexagonal structural phase transition. Furthermore, we observe that the cubic-to-hexagonal phase transition exhibits a large thermal hysteresis. Our first-principles calculations confirm the existence of a potential barrier between the cubic and hexagonal structures, which provides an explanation for the observed thermal hysteresis. By exploiting the potential barrier, we demonstrate kinetic trapping of the cubic phase, desirable for solar cells, even at 8.2 K by thermal quenching.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 2, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601650", "DOI": "10.1126/sciadv.1601650", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601650", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387991500047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, KK; Luo, YJ; Jin, YB; Liu, TX; Liang, YM; Yang, L; Song, PQ; Liu, ZY; Tian, CB; Xie, LQ; Wei, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kaikai; Luo, Yujie; Jin, Yongbin; Liu, Tianxiao; Liang, Yuming; Yang, Liu; Song, Peiquan; Liu, Zhiyong; Tian, Chengbo; Xie, Liqiang; Wei, Zhanhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Moisture-triggered fast crystallization enables efficient and stable perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite structure is disturbed by environmental moisture, limiting the device performance. Here, Wei et al. monitor the effect of moisture during the growth by N-2-protected characterization techniques, and obtain an operationally stable perovskite solar cell with efficiency approaching 24%. Understanding the function of moisture on perovskite is challenging since the random environmental moisture strongly disturbs the perovskite structure. Here, we develop various N-2-protected characterization techniques to comprehensively study the effect of moisture on the efficient cesium, methylammonium, and formamidinium triple-cation perovskite (Cs(0.05)FA(0.75)MA(0.20))Pb(I0.96Br0.04)(3). In contrast to the secondary measurements, the established air-exposure-free techniques allow us directly monitor the influence of moisture during perovskite crystallization. We find a controllable moisture treatment for the intermediate perovskite can promote the mass transportation of organic salts, and help them enter the buried bottom of the films. This process accelerates the quasi-solid-solid reaction between organic salts and PbI2, enables a spatially homogeneous intermediate phase, and translates to high-quality perovskites with much-suppressed defects. Consequently, we obtain a champion device efficiency of approaching 24% with negligible hysteresis. The devices exhibit an average T-80-lifetime of 852 h (maximum 1210 h) working at the maximum power point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4891, "DOI": "10.1038/s41467-022-32482-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-32482-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842533800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, C; Su, WQ; Liu, Q; Lu, XL; Wang, FM; Sun, T; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Chao; Su, Weiquan; Liu, Qiang; Lu, Xili; Wang, Famei; Sun, Tao; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symmetrical dual D-shape photonic crystal fibers for surface plasmon resonullce sensing", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symmetrical dual D-shape photonic crystal fibers (PCFs) for surface plasmon resonullce (SPR) sensing are designed and analyzed by the finite element method (FEM). The performance of the sensor is remarkably enhanced by the directional power coupling between the two fibers. We study the influence of the structural parameters on the performance of the sensor as well as the relationship between the resonullce wavelengths and analyze refractive indexes between 1.36 and 1.41. An average spectral sensitivity of 14660 nm/RIU can be achieved in this sensing range and the corresponding refractive index resolution is 6.82 x 10(-6) RIU. The characteristics of a single D-shape PCF-SPR sensor with the same structural parameters are compared with those of the dual PCFs sensor and the latter has distinct advantages concerning the spectral sensitivity, resolution, amplitude sensitivity, and figure of merits (FOM). (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2018, "Volume": 26, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9039, "End Page": 9049, "Article Number": null, "DOI": "10.1364/OE.26.009039", "DOI Link": "http://dx.doi.org/10.1364/OE.26.009039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428990200103", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Altuhafi, FN; Coop, MR; Georgiannou, VN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Altuhafi, Fatin N.; Coop, Matthew R.; Georgiannou, Vasiliki N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Particle Shape on the Mechanical Behavior of Natural Sands", "Source Title": "JOURNAL OF GEOTECHNICAL AND GEOENVIRONMENTAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A database of the mechanical behavior of 25 natural sands was compiled from the existing literature. Particle shape and size analysis, obtained by dynamic imaging analysis, for each material in the database has subsequently been linked to its mechanical properties; selected sands were also subject to interferometry study for particle surface roughness measurements. This paper reviews the effect of the particle shape properties of these sands on their Critical State and stiffness parameters, introducing a new parameter to optimize the correlations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 142, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4016071, "DOI": "10.1061/(ASCE)GT.1943-5606.0001569", "DOI Link": "http://dx.doi.org/10.1061/(ASCE)GT.1943-5606.0001569", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388609100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XX; Ji, CC; Shen, JK; Feng, JZ; Mi, HY; Xu, YT; Guo, FJ; Yan, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xixian; Ji, Chenchen; Shen, Jinke; Feng, Jianze; Mi, Hongyu; Xu, Yongtai; Guo, Fengjiao; Yan, Xingbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amorphous Heterostructure Derived from Divalent Manganese Borate for Ultrastable and Ultrafast Aqueous Zinc Ion Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-manganese (Zn-Mn) batteries have promising potential in large-scale energy storage applications since they are highly safe, environment-friendly, and low-cost. However, the practicality of Mn-based materials is plagued by their structural collapse and uncertain energy storage mechanism upon cycling. Herein, this work designs an amorphous manganese borate (a-MnBOx) material via disordered coordination to alleviate the above issues and improve the electrochemical performance of Zn-Mn batteries. The unique physicochemical characteristic of a-MnBOx enables the inner a-MnBOx to serve as a robust framework in the initial energy storage process. Additionally, the amorphous manganese dioxide, amorphous ZnxMnO(OH)(2), and Zn4SO4(OH)(6)center dot 4H(2)O active components form on the surface of a-MnBOx during the charge/discharge process. The detailed in situ/ex situ characterization demonstrates that the heterostructure of the inner a-MnBOx and surface multicomponent phases endows two energy storage modes (Zn2+/H+ intercalation/deintercalation process and reversible conversion mechanism between the ZnxMnO(OH)(2) and Zn4SO4(OH)(6)center dot 4H(2)O) phases). Therefore, the obtained Zn//a-MnBOx battery exhibits a high specific capacity of 360.4 mAh g(-1), a high energy density of 484.2 Wh kg(-1), and impressive cycling stability (97.0% capacity retention after 10 000 cycles). This finding on a-MnBOx with a dual-energy storage mechanism provides new opportunities for developing high-performance aqueous Zn-Mn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 43, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205794", "DOI Link": "http://dx.doi.org/10.1002/advs.202205794", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000917979900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roters, F; Diehl, M; Shanthraj, P; Eisenlohr, P; Reuber, C; Wong, SL; Maiti, T; Ebrahimi, A; Hochrainer, T; Fabritius, HO; Nikolov, S; Friák, M; Fujita, N; Grilli, N; Janssens, KGF; Jia, N; Kok, PJJ; Ma, D; Meier, F; Werner, E; Stricker, M; Weygand, D; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roters, F.; Diehl, M.; Shanthraj, P.; Eisenlohr, P.; Reuber, C.; Wong, S. L.; Maiti, T.; Ebrahimi, A.; Hochrainer, T.; Fabritius, H-O; Nikolov, S.; Friak, M.; Fujita, N.; Grilli, N.; Janssens, K. G. F.; Jia, N.; Kok, P. J. J.; Ma, D.; Meier, F.; Werner, E.; Stricker, M.; Weygand, D.; Raabe, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DAMASK - The Dusseldorf Advanced Material Simulation Kit for modeling multi-physics crystal plasticity, thermal, and damage phenomena from the single crystal up to the component scale", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystal Plasticity (CP) modeling is a powerful and well established computational materials science tool to investigate mechanical structure-property relations in crystalline materials. It has been successfully applied to study diverse micromechanical phenomena ranging from strain hardening in single crystals to texture evolution in polycrystalline aggregates. However, when considering the increasingly complex microstructural composition of modern alloys and their exposure to-often harsh-environmental conditions, the focus in materials modeling has shifted towards incorporating more constitutive and internal variable details of the process history and environmental factors into these structure-property relations. Technologically important fields of application of enhanced CP models include phase transformations, hydrogen embrittlement, irradiation damage, fracture, and recrystallization. A number of niche tools, containing multi-physics extensions of the CP method, have been developed to address such topics. Such implementations, while being very useful from a scientific standpoint, are, however, designed for specific applications and substantial efforts are required to extend them into flexible multi-purpose tools for a general end-user community. With the Dusseldorf Advanced Material Simulation Kit (DAMASK) we, therefore, undertake the effort to provide an open, flexible, and easy to use implementation to the scientific community that is highly modular and allows the use and straightforward implementation of different types of constitutive laws and numerical solvers. The internal modular structure of DAMASK follows directly from the hierarchy inherent to the employed continuum description. The highest level handles the partitioning of the prescribed field values on a material point between its underlying microstructural constituents and the subsequent homogenization of the constitutive response of each constituent. The response of each microstructural constituent is determined, at the intermediate level, from the time integration of the underlying constitutive laws for elasticity, plasticity, damage, phase transformation, and heat generation among other coupled multi-physical processes of interest. Various constitutive laws based on evolving internal state variables can be implemented to provide this response at the lowest level. DAMASK already contains various CP-based models to describe metal plasticity as well as constitutive models to incorporate additional effects such as heat production and transfer, damage evolution, and athermal transformations. Furthermore, the implementation of additional constitutive laws and homogenization schemes, as well as the integration of a wide class of suitable boundary and initial value problem solvers, is inherently considered in its modular design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2019, "Volume": 158, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 420, "End Page": 478, "Article Number": null, "DOI": "10.1016/j.commatsci.2018.04.030", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2018.04.030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456022400051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, YY; Fan, L; Rao, AM; Yu, WJ; Zhuoma, CX; Feng, YH; Qin, ZH; Zhou, J; Lu, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yanyao; Fan, Ling; Rao, Apparao M.; Yu, Weijian; Zhuoma, Caixiang; Feng, Yanhong; Qin, Zhihui; Zhou, Jiang; Lu, Bingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cyclic-anion salt for high-voltage stable potassium-metal batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte anions are critical for achieving high-voltage stable potassium-metal batteries (PMBs). However, the common anions cannot simultaneously prevent the formation of 'dead K' and the corrosion of Al current collector, resulting in poor cycling stability. Here, we demonstrate cyclic anion of hexafluoropropane-1,3-disulfonimide-based electrolytes that can mitigate the 'dead K' and remarkably enhance the high-voltage stability of PMBs. Particularly, even using low salt concentration (0.8 M) and additive-free carbonate-based electrolytes, the PMBs with a high-voltage polyanion cathode (4.4 V) also exhibit excellent cycling stability of 200 cycles with a good capacity retention of 83%. This noticeable electrochemical performance is due to the highly efficient passivation ability of the cyclic anions on both anode and cathode surfaces. This cyclic-anion-based electrolyte design strategy is also suitable for lithium and sodium-metal battery technologies. This work proposes a novel cyclic anion salt strategy for high-voltage potassium metal batteries, which is also suitable for other alkali metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 29", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1093/nsr/nwac134", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac134", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000846964200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JQ; Zheng, Z; Bi, PQ; Chen, ZH; Wang, YF; Liu, XY; Zhang, SQ; Hao, XT; Zhang, MJ; Li, YF; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianqiu; Zheng, Zhong; Bi, Pengqing; Chen, Zhihao; Wang, Yafei; Liu, Xiaoyu; Zhang, Shaoqing; Hao, Xiaotao; Zhang, Maojie; Li, Yongfang; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tandem organic solar cells with 20.6% efficiency enabled by reduced voltage losses", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tandem organic solar cells with recorded efficiency are achieved by implementing the ternary strategy to simultaneously reduce energy disorder and non-radiative voltage losses. Large voltage losses are the main obstacle for achieving high efficiency in organic solar cells (OSCs). Here we construct ternary OSCs by introducing an asymmetric small molecule acceptor AITC into PBDB-TCl : BTP-eC9 system and demonstrate the effectiveness in simultaneously decreasing energy disorder and non-radiative voltage losses. It is found that the introduction of AITC can modify domain size and increase the degree of crystallinity, which enhances open-circuit voltage and power conversion efficiency (19.1%, certified as 18.9%). Inspiringly, an output efficiency of 20.6% of the constructed tandem OSCs based on PBDB-TCl : AITC : BTP-eC9 ternary active layer output a recorded efficiency of 20.6% (certified as 20.3%), which is the highest value in OSCs field to date. This work demonstrates that decreasing the voltage losses by ternary strategy and constructing of tandem architecture are effective approaches towards improving photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2023, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwad085", "DOI": "10.1093/nsr/nwad085", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwad085", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026425400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morimoto, T; Nagaosa, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morimoto, Takahiro; Nagaosa, Naoto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological nature of nonlinear optical effects in solids", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There are a variety of nonlinear optical effects including higher harmonic generations, photovoltaic effects, and nonlinear Kerr rotations. They are realized by strong light irradiation to materials that results in nonlinear polarizations in the electric field. These are of great importance in studying the physics of excited states of the system as well as for applications to optical devices and solar cells. Nonlinear properties of materials are usually described by nonlinear susceptibilities, which have complex expressions including many matrix elements and energy denominators. On the other hand, a nonequilibrium steady state under an electric field periodic in time has a concise description in terms of the Floquet bands of electrons dressed by photons. We show theoretically, using the Floquet formalism, that various nonlinear optical effects, such as the shift current in noncentrosymmetric materials, photovoltaic Hall response, and photo-induced change of order parameters under the continuous irradiation of monochromatic light, can be described in a unified fashion by topological quantities involving the Berry connection and Berry curvature. We found that vector fields defined with the Berry connections in the space of momentum and/or parameters govern the nonlinear responses. This topological view offers a route to designing nonlinear optical materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501524", "DOI": "10.1126/sciadv.1501524", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501524", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380073000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Wang, JR; Xi, SB; Shen, JJ; Luo, SZ; Ge, JJ; Sun, SN; Chen, YB; Hanna, JV; Li, SZ; Wang, X; Xu, ZCJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yuanmiao; Wang, Jiarui; Xi, Shibo; Shen, Jingjing; Luo, Songzhu; Ge, Jingjie; Sun, Shengnull; Chen, Yubo; Hanna, John V.; Li, Shuzhou; Wang, Xin; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Navigating surface reconstruction of spinel oxides for electrochemical water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding and mastering the structural evolution of water oxidation electrocatalysts lays the foundation to finetune their catalytic activity. Herein, we demonstrate that surface reconstruction of spinel oxides originates from the metal-oxygen covalency polarity in the M-T-O-M-O backbone. A stronger M-O-O covalency relative to M-T-O covalency is found beneficial for a more thorough reconstruction towards oxyhydroxides. The structure-reconstruction relationship allows precise prediction of the reconstruction ability of spinel pre-catalysts, based on which the reconstruction degree towards the in situ generated oxyhydroxides can be controlled. The investigations of oxyhydroxides generated from spinel pre-catalysts with the same reconstruction ability provide guidelines to navigate the cation selection in spinel pre-catalysts design. This work reveals the fundamentals for manipulating the surface reconstruction of spinel pre-catalysts for water oxidation. Precise control of water oxidation activity calls for the mastery of surface reconstruction of electrocatalysts. Here, the authors identify the structural origin of surface reconstruction on spinel oxides and report a criterion to evaluate the reconstruction degree, which enable the design of spinel pre-catalyst with controlled reconstruction ability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-38017-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38017-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983415900027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aharoni, H; Xia, Y; Zhang, XY; Kamien, RD; Yang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aharoni, Hillel; Xia, Yu; Zhang, Xinyue; Kamien, Randall D.; Yang, Shu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal inverse design of surfaces with thin nematic elastomer sheets", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Programmable shape-shifting materials can take different physical forms to achieve multifunctionality in a dynamic and controllable manner. Although morphing a shape from 2D to 3D via programmed inhomogeneous local deformations has been demonstrated in various ways, the inverse problem-finding how to program a sheet in order for it to take an arbitrary desired 3D shape-is much harder yet critical to realize specific functions. Here, we address this inverse problem in thin liquid crystal elastomer (LCE) sheets, where the shape is preprogrammed by precise and local control of the molecular orientation of the liquid crystal monomers. We show how blueprints for arbitrary surface geometries can be generated using approximate numerical methods and how local extrinsic curvatures can be generated to assist in properly converting these geometries into shapes. Backed by faithfully alignable and rapidly lockable LCE chemistry, we precisely embed our designs in LCE sheets using advanced top-down microfabrication techniques. We thus successfully produce flat sheets that, upon thermal activation, take an arbitrary desired shape, such as a face. The general design principles presented here for creating an arbitrary 3D shape will allow for exploration of unmet needs in flexible electronics, metamaterials, aerospace and medical devices, and more.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2018, "Volume": 115, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7206, "End Page": 7211, "Article Number": null, "DOI": "10.1073/pnas.1804702115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1804702115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438050900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mleczko, MJ; Zhang, CF; Lee, HR; Kuo, HH; Magyari-Köpe, B; Moore, RG; Shen, ZX; Fisher, IR; Nishi, Y; Pop, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mleczko, Michal J.; Zhang, Chaofan; Lee, Hye Ryoung; Kuo, Hsueh-Hui; Magyari-Kope, Blanka; Moore, Robert G.; Shen, Zhi-Xun; Fisher, Ian R.; Nishi, Yoshio; Pop, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "HfSe2 and ZrSe2: Two-dimensional semiconductors with native high-κ oxides", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The success of silicon as a dominullt semiconductor technology has been enabled by its moderate band gap (1.1 eV), permitting low-voltage operation at reduced leakage current, and the existence of SiO2 as a high-quality native insulator. In contrast, other mainstream semiconductors lack stable oxides and must rely on deposited insulators, presenting numerous compatibility challenges. We demonstrate that layered two-dimensional (2D) semiconductors HfSe2 and ZrSe2 have band gaps of 0.9 to 1.2 eV (bulk to monolayer) and technologically desirable high-k native dielectrics HfO2 and ZrO2, respectively. We use spectroscopic and computational studies to elucidate their electronic band structure and then fabricate air-stable transistors down to three-layer thickness with careful processing and dielectric encapsulation. Electronic measurements reveal promising performance (on/off ratio > 10(6); on current, similar to 30 mu A/mm), with native oxides reducing the effects of interfacial traps. These are the first 2D materials to demonstrate technologically relevant properties of silicon, in addition to unique compatibility with high-k dielectrics, and scaling benefits from their atomically thin nature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700481", "DOI": "10.1126/sciadv.1700481", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700481", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411589900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, TL; Lindsay, L; Ruan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Tianli; Lindsay, Lucas; Ruan, Xiulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Four-phonon scattering significantly reduces intrinsic thermal conductivity of solids", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For decades, the three-phonon scattering process has been considered to govern thermal transport in solids, while the role of higher-order four-phonon scattering has been persistently unclear and so ignored. However, recent quantitative calculations of three-phonon scattering have often shown a significant overestimation of thermal conductivity as compared to experimental values. In this Rapid Communication we show that four-phonon scattering is generally important in solids and can remedy such discrepancies. For silicon and diamond, the predicted thermal conductivity is reduced by 30% at 1000 K after including four-phonon scattering, bringing predictions in excellent agreement with measurements. For the projected ultrahigh-thermal conductivity material, zinc-blende BAs, a competitor of diamond as a heat sink material, four-phonon scattering is found to be strikingly strong as three-phonon processes have an extremely limited phase space for scattering. The four-phonon scattering reduces the predicted thermal conductivity from 2200 to 1400 W/m K at room temperature. The reduction at 1000 K is 60%. We also find that optical phonon scattering rates are largely affected, being important in applications such as phonon bottlenecks in equilibrating electronic excitations. Recognizing that four-phonon scattering is expensive to calculate, in the end we provide some guidelines on how to quickly assess the significance of four-phonon scattering, based on energy surface anharmonicity and the scattering phase space. Our work clears the decades-long fundamental question of the significance of higher-order scattering, and points out ways to improve thermoelectrics, thermal barrier coatings, nuclear materials, and radiative heat transfer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 459, "Times Cited, All Databases": 504, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2017, "Volume": 96, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 161201, "DOI": "10.1103/PhysRevB.96.161201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.161201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413848300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gin, S; Jollivet, P; Fournier, M; Angeli, F; Frugier, P; Charpentier, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gin, Stephane; Jollivet, Patrick; Fournier, Maxime; Angeli, Frederic; Frugier, Pierre; Charpentier, Thibault", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin and consequences of silicate glass passivation by surface layers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicate glasses are durable materials, but are they sufficiently durable to confine highly radioactive wastes for hundreds of thousands years? Addressing this question requires a thorough understanding of the mechanisms underpinning aqueous corrosion of these materials. Here we show that in silica-saturated solution, a model glass of nuclear interest corrodes but at a rate that dramatically drops as a passivating layer forms. Water ingress into the glass, leading to the congruent release of mobile elements (B, Na and Ca), is followed by in situ repolymerization of the silicate network. This material is at equilibrium with pore and bulk solutions, and acts as a molecular sieve with a cutoff below 1 nm. The low corrosion rate resulting from the formation of this stable passivating layer enables the objective of durability to be met, while progress in the fundamental understanding of corrosion unlocks the potential for optimizing the design of nuclear glass-geological disposal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6360, "DOI": "10.1038/ncomms7360", "DOI Link": "http://dx.doi.org/10.1038/ncomms7360", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350295100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, ZZ; Cai, ST; Hao, SQ; Bailey, TP; Luo, YB; Luo, WJ; Yu, Y; Uher, C; Wolverton, C; Dravid, VP; Zou, ZG; Yan, QY; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Zhong-Zhen; Cai, Songting; Hao, Shiqiang; Bailey, Trevor P.; Luo, Yubo; Luo, Wenjun; Yu, Yan; Uher, Ctirad; Wolverton, Christopher; Dravid, Vinayak P.; Zou, Zhigang; Yan, Qingyu; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinary role of Zn in enhancing thermoelectric performance of Ga-doped n-type PbTe", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although Ga doping can weaken the electron phonon coupling in n-type PbTe, Ga-doped PbTe has a relatively low carrier concentration (n) and high lattice thermal conductivity (kappa(lat)), resulting in a lower figure of merit (ZT) compared with those of other top-performing n-type PbTe-based thermoelectric materials. Herein, we report the extraordinary role of Zn in enhancing the thermoelectric performance of Ga-doped PbTe. It is discovered that Zn can simultaneously improve the electronic transport properties and decrease the kappa(lat) of Ga-doped PbTe, thereby affording a record high ZT(avg) similar to 1.26 at 400-873 K, with a maximum ZT value of 1.55 at 723 K. The isoelectronic substitution of Zn for Pb in Ga-doped PbTe increases the electrical conductivity and n by inducing the nucleation and growth of Ga2Te3 in the second phase. The formation of Ga2Te3 results in nonstoichiometry and Te deficiency in the PbTe matrix, which increases the number of electron carriers. Additionally, discordant Zn and Ga atoms with displacing off-center from the ideal octahedral positions, as well as Ga2Te3 nullocrystals ranging from 30 to 200 nm coherently embedded into the PbTe matrix effectively weaken the phonon modes and scatter heat-carrying phonons, resulting in a significant reduction in kappa(lat).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2022, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 368, "End Page": 375, "Article Number": null, "DOI": "10.1039/d1ee02986j", "DOI Link": "http://dx.doi.org/10.1039/d1ee02986j", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000730381100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, I; Utermohlen, FG; Weber, D; Hwang, K; Zhang, C; van Tol, J; Goldberger, JE; Trivedi, N; Hammel, PC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Inhee; Utermohlen, Franz G.; Weber, Daniel; Hwang, Kyusung; Zhang, Chi; van Tol, Johan; Goldberger, Joshua E.; Trivedi, nulldini; Hammel, P. Chris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fundamental Spin Interactions Underlying the Magnetic Anisotropy in the Kitaev Ferromagnet CrI3", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We lay the foundation for determining the microscopic spin interactions in two-dimensional (2D) ferromagnets by combining angle-dependent ferromagnetic resonullce (FMR) experiments on high quality CrI3 single crystals with theoretical modeling based on symmetries. We discover that the Kitaev interaction is the strongest in this material with K similar to -5.2 meV, 25 times larger than the Heisenberg exchange J similar to -0.2 meV, and responsible for opening the similar to 5 meV gap at the Dirac points in the spin-wave dispersion. Furthermore, we find that the symmetric off-diagonal anisotropy Gamma similar to -67.5 mu eV, though small, is crucial for opening a similar to 0.3 meV gap in the magnon spectrum at the zone center and stabilizing ferromagnetism in the 2D limit. The high resolution of the FMR data further reveals a mu eV-scale quadrupolar contribution to the S = 3/2 magnetism. Our identification of the underlying exchange anisotropies opens paths toward 2D ferromagnets with higher T-C as well as magnetically frustrated quantum spin liquids based on Kitaev physics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2020, "Volume": 124, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17201, "DOI": "10.1103/PhysRevLett.124.017201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.017201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000505495300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HN; Liu, Z; Fu, ZQ; Dai, K; Lv, ZQ; Guo, SB; Hu, ZG; Xu, FF; Wang, GS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Haonull; Liu, Zhen; Fu, Zhengqian; Dai, Kai; Lv, Zhongqian; Guo, Shaobo; Hu, Zhigao; Xu, Fangfang; Wang, Genshui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superior Energy Density Achieved in Unfilled Tungsten Bronze Ferroelectrics via Multiscale Regulation Strategy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The most promising candidates for energy storage capacitor application are relaxor ferroelectrics, among which, the perovskite structure ferroelectric ceramics have witnessed great development progress. However, less attention has been paid on tetragonal tungsten bronze structure (TTBS) ceramics because of their lower breakdown strength and polarization. Herein, a multiscale regulation strategy is proposed to tune the energy storage performances (ESP) of TTBS ceramics from grain, domain, and macroscopic scale. The enhanced relaxor behavior with dynamic polar nullodomains guarantees low remanent polarization, while the refined grains and enlarged bandgap ensure increased breakdown strength. Hence, excellent ESP is realized in unfilled TTBS Sr0.425La0.10.05Ba0.425Nb1.4Ta0.6O6 (SLBNT) ceramics with an ultrahigh recoverable energy density of 5.895 J cm(-3) and a high efficiency of 85.37%. This achievement notably surpasses previous studies in TTBS ceramics and is comparable to that of perovskite components. Meanwhile, the energy density exhibits a wide temperature, frequency, and cycling fatigue stability. In addition, high power density (257.89 MW cm(-3)), especially the ultrafast discharge time (t(0.9) = 16.4 ns) are achieved. The multiscale regulation strategy unlocks the energy storage potential of TTBS ceramics and thus highlights TTBS ceramics as promising candidates for energy storage, like perovskite structured ceramics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300227", "DOI Link": "http://dx.doi.org/10.1002/advs.202300227", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971490900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, ZJ; Li, CH; Zhang, YB; Dong, L; Bai, XF; Yang, M; Jia, DZ; Li, RZ; Cao, HJ; Xu, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Zhenjing; Li, Changhe; Zhang, Yanbin; Dong, Lan; Bai, Xiufang; Yang, Min; Jia, Dongzhou; Li, Runzhe; Cao, Huajun; Xu, Xuafeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Milling surface roughness for 7050 aluminum alloy cavity influenced by nozzle position of nullofluid minimum quantity lubrication", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In nullofluid minimum quantity lubrication (NMQL) milling of aviation aluminum alloy, it is the bottleneck problem to adjust the position parameters (target distance, incidence angle, and elevation angle) of the nozzle to improve the surface roughness of milling, which has large and uncontrollable errors. In this paper, the influence law of milling cutter speed, helical angle, and cavity shape on the flow field around the milling cutter was studied, and the optimal nozzle profile parameters were obtained. Using 7050 aluminum alloy as the workpiece material, the milling experiment of the NMQL cavity was conducted by utilizing cottonseed oil-based Al2O3 nullofluid. Results show that the high velocity of the surrounding air flow field and the strong gas barrier could be attributed to high rotating velocities of the milling cutter. The incidence angle of the nozzle was consistent with the helical angle of the milling cutter, the target distance was appropriate at 2530 mm, and the elevation angle was suitable at 60 degrees-65 degrees. The range and variance analyses of the signal-to-noise ratio of milling force and roughness were performed, and the chip morphology was observed and analyzed. The results show that the optimal combination of nozzle position parameters was the target distance of 30 mm, the incidence angle of 35 degrees, and the elevation angle of 60 degrees. Among these parameters, target distance had the largest impact on cutting performance with a contribution rate of more than 55%, followed by incidence angle and elevation contribution rate. Analysis by orthogonal experiment revealed that the nozzle position parameters were appropriate, and R-a (0.087 mu m) was reduced by 30.4% from the maximum value (0.125 mu m). Moreover, R-sm (0.05 mm) was minimum, which was 36% lower than that of the seventh group (R-sm = 0.078 mm). (C) 2020 Chinese Society of Aeronautics and Astronautics. Production and hosting by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 34, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 33, "End Page": 53, "Article Number": null, "DOI": "10.1016/j.cja.2020.04.029", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2020.04.029", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000644828400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Turkel, S; Swann, J; Zhu, ZY; Christos, M; Watanabe, K; Taniguchi, T; Sachdev, S; Scheurer, MS; Kaxiras, E; Dean, CR; Pasupathy, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Turkel, Simon; Swann, Joshua; Zhu, Ziyan; Christos, Maine; Watanabe, K.; Taniguchi, T.; Sachdev, Subir; Scheurer, Mathias S.; Kaxiras, Efthimios; Dean, Cory R.; Pasupathy, Abhay N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orderly disorder in magic-angle twisted trilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magic-angle twisted trilayer graphene (TTG) has recently emerged as a platform to engineer strongly correlated flat bands. We reveal the normal-state structural and electronic properties of TTG using low-temperature scanning tunneling microscopy at twist angles for which superconductivity has been observed. Real trilayer samples undergo a strong reconstruction of the moire lattice, which locks layers into near-magic-angle, mirror symmetric domains comparable in size with the superconducting coherence length. This relaxation introduces an array of localized twist-angle faults, termed twistons and moire solitons, whose electronic structure deviates strongly from the background regions, leading to a doping-dependent, spatially granular electronic landscape. The Fermi-level density of states is maximally uniform at dopings for which superconductivity has been observed in transport measurements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2022, "Volume": 376, "Issue": 6589, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abk1895", "DOI Link": "http://dx.doi.org/10.1126/science.abk1895", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000783316500050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, FD; Chen, SG; Wang, AX; Wang, M; Guo, L; Wei, ZD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Fadong; Chen, Siguo; Wang, Aoxue; Wang, Meng; Guo, Lin; Wei, Zidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blocking the sulfonate group in Nafion to unlock platinum's activity in membrane electrode assemblies", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The specific adsorption of ionomer sulfonate groups on Pt-based catalysts in membrane electrode assemblies (MEAs) has severely restricted Pt catalytic activity, Pt utilization, proton conductivity and mass transport. Here we report a blocking strategy using cyclohexanol to mitigate the detrimental impacts of the Nafion ionomer. Cyclohexanol with a chair or boat conformation blocked the adsorption path of the ionomer onto the Pt surface via coordination with the ionomer, which released the Pt activity sites and dramatically improved the mass transport path. This MEA with cyclohexanol exhibits striking performance improvement in the kinetic and mass transport regions, along with strong stability. The proposed strategy provides a direction to tune the Pt/ionomer interface and improve the catalytic activity of Pt in MEA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 392, "End Page": 401, "Article Number": "s41929-023-00949-w", "DOI": "10.1038/s41929-023-00949-w", "DOI Link": "http://dx.doi.org/10.1038/s41929-023-00949-w", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973560700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Worthington, MJH; Kucera, RL; Chalker, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Worthington, Max J. H.; Kucera, Renata L.; Chalker, Justin M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green chemistry and polymers made from sulfur", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers are among the most important mass-produced materials on the planet, yet they are largely derived from a finite supply of petrochemicals. To ensure the sustainable production of polymers and functional materials, alternative feedstocks are required. This Perspective examines this challenge in the context of an emerging class of polymers made from elemental sulfur. Because sulfur is a by-product of the petroleum industry, converting it into useful polymers and related materials is an advance in waste valorisation. Additionally, co-polymerisation of sulfur with renewable monomers represents an additional contribution to sustainability. These reactions are often solvent free and benefit from full atom economy, futher augmenting their Green Chemistry credentials. Applications of these materials will be discussed, with a spotlight on environmental benefits. A forward looking assessment of the opportunities for using sulfur polymers in Green Chemistry is also included.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 327, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 19, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2748, "End Page": 2761, "Article Number": null, "DOI": "10.1039/c7gc00014f", "DOI Link": "http://dx.doi.org/10.1039/c7gc00014f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403572700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FC; Lovorn, T; MacDonald, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fengcheng; Lovorn, Timothy; MacDonald, A. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of optical absorption by interlayer excitons in transition metal dichalcogenide heterobilayers", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a theory of optical absorption by interlayer excitons in a heterobilayer formed from transition metal dichalcogenides. The theory accounts for the presence of small relative rotations that produce a momentum shift between electron and hole bands located in different layers, and a moire pattern in real space. Because of the momentum shift, the optically active interlayer excitons are located at the moire Brillouin zone's corners, instead of at its center, and would have elliptical optical selection rules if the individual layers were translationally invariant. We show that the exciton moire potential energy restores circular optical selection rules by coupling excitons with different center of mass momenta. A variety of interlayer excitons with both senses of circular optical activity, and energies that are tunable by twist angle, are present at each valley. The lowest energy exciton states are generally localized near the exciton potential energy minima. We discuss the possibility of using the moire pattern to achieve scalable two-dimensional arrays of nearly identical quantum dots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2018, "Volume": 97, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35306, "DOI": "10.1103/PhysRevB.97.035306", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.035306", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423341500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smith, JG; Siegel, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smith, Jeffrey G.; Siegel, Donald J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-temperature paddlewheel effect in glassy solid electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Glasses are promising electrolytes for use in solid-state batteries. Nevertheless, due to their amorphous structure, the mechanisms that underlie their ionic conductivity remain poorly understood. Here, ab initio molecular dynamics is used to characterize migration processes in the prototype glass, 75Li(2)S-25P(2)S(5). Lithium migration occurs via a mechanism that combines concerted motion of lithium ions with large, quasi-permanent reorientations of PS43- anions. This latter effect, known as the 'paddlewheel' mechanism, is typically observed in high-temperature crystalline polymorphs. In contrast to the behavior of crystalline materials, in the glass paddlewheel dynamics contribute to Lithium-ion mobility at room temperature. Paddlewheel contributions are confirmed by characterizing spatial, temporal, vibrational, and energetic correlations with Lithium motion. Furthermore, the dynamics in the glass differ from those in the stable crystalline analogue, gamma -Li3PS4, where anion reorientations are negligible and ion mobility is reduced. These data imply that glasses containing complex anions, and in which covalent network formation is minimized, may exhibit paddlewheel dynamics at low temperature. Consequently, these systems may be fertile ground in the search for new solid electrolytes. Glasses are promising electrolytes for solid-state lithium batteries; however, due to their amorphous structure, the ionic conduction mechanism remains poorly understood. Here, atomic-scale modeling reveals that lithium migration occurs via concerted hopping of Li-ions coupled to quasi-permanent rotations of tetrahedral anions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-15245-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15245-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522096100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sailer, I; Makarov, NA; Thoma, DS; Zwahlen, M; Pjetursson, BE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sailer, Irena; Makarov, Nikolay Alexandrouich; Thoma, Daniel Stefan; Zwahlen, Marcel; Pjetursson, Bjarni Eluar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-ceramic or metal-ceramic tooth-supported fixed dental prostheses (FDPs)? A systematic review of the survival and complication rates. Part I: Single crowns (SCs)", "Source Title": "DENTAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objective. To assess the 5-year survival of metal-ceramic and all-ceramic tooth-supported single crowns (SCs) and to describe the incidence of biological, technical and esthetic complications. Methods. Medline (PubMed), Embase, Cochrane Central Register of Controlled Trials (CENTRAL) searches (2006-2013) were performed for clinical studies focusing on tooth-supported fixed dental prostheses (FDPs) with a mean follow-up of at least 3 years. This was complimented by an additional hand search and the inclusion of 34 studies from a previous systematic review [1,4 Survival and complication rates were analyzed using robust Poisson's regression models to obtain summary estimates of 5-year proportions. Results. Sixty-seven studies reporting on 4663 metal-ceramic and 9434 all-ceramic SCs fulfilled the inclusion criteria. Seventeen studies reported on metal-ceramic crowns, and 54 studies reported on all-ceramic crowns. Meta-analysis of the included studies indicated an estimated survival rate of metal-ceramic SCs of 94.7% (95% CI: 94.1-96.9%) after 5 years. This was similar to the estimated 5-year survival rate of leucit or lithium-disilicate reinforced glass ceramic SCs (96.6%; 95% CI: 94.9-96.7%), of glass infiltrated alumina SCs (94.6%; 95% CI: 92.7-96%) and densely sintered alumina and zirconia SCs (96%; 95% CI: 93.8-97.5%; 92.1%; 95% CI: 82.8-95.6%). In contrast, the 5-year survival rates of feldspathic/silica-based ceramic crowns were lower (p < 0.001). When the outcomes in anterior and posterior regions were compared feldspathic/silica-based ceramic and zirconia crowns exhibited significantly lower survival rates in the posterior region (p < 0.0001), the other crown types performed similarly. Densely sintered zirconia SCs were more frequently lost due to veneering ceramic fractures than metal-ceramic SCs (p < 0.001), and had significantly more loss of retention (p < 0.001). In total higher 5 year rates of framework fracture were reported for the all-ceramic SCs than for metal-ceramic SCs. Conclusions. Survival rates of most types of all-ceramic SCs were similar to those reported for metal-ceramic SCs, both in anterior and posterior regions. Weaker feldspathic/silica-based ceramics should be limited to applications in the anterior region. Zirconia-based SCs should not be considered as primary option due to their high incidence of technical problems. (C) 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 532, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 31, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 603, "End Page": 623, "Article Number": null, "DOI": "10.1016/j.dental.2015.02.011", "DOI Link": "http://dx.doi.org/10.1016/j.dental.2015.02.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Dentistry, Oral Surgery & Medicine; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354118900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nagao, A; Dadfarnia, M; Somerday, BP; Sofronis, P; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nagao, Akihide; Dadfarnia, Mohsen; Somerday, Brian P.; Sofronis, Petros; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogen-enhanced-plasticity mediated decohesion for hydrogen-induced intergranular and quasi-cleavage fracture of lath martensitic steels", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen embrittlement of lath martenistic steels is characterized by intergranular and quasi-cleavage transgranular fracture. Recent transmission electron microscopy (TEM) analyses (Nagao et al., 2012a, 2014a, 2014b, 2014c) of samples lifted from beneath fracture surfaces through focused ion beam machining (FIB) revealed a failure mechanism that can be termed hydrogen-enhanced-plasticity mediated decohesion. Fracture occurs by the synergistic action of the hydrogen-enhanced localized plasticity and decohesion. In particular, intergranular cracking takes place by dislocation pile-ups impinging on prior austenite grain boundaries and quasi-cleavage is the case when dislocation pile-ups impinge on block boundaries. These high-angle boundaries, which have already weakened by the presence of hydrogen, debond by the pile-up stresses. The micromechanical model of Novak et al. (2010) is used to quantitatively describe and predict the hydrogen-induced failure of these steels. The model predictions verify that introduction of nullosized (Ti,Mo)C precipitates in the steel microstructure enhances the resistance to hydrogen embrittlement. The results are used to discuss microstructural designs that are less susceptible to hydrogen induced failure in systems with fixed hydrogen content (closed systems). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 403, "End Page": 430, "Article Number": null, "DOI": "10.1016/j.jmps.2017.12.016", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2017.12.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426536400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HY; Ren, Y; Zhu, Y; Tian, JM; Sun, XY; Sheng, CC; He, P; Guo, SH; Zhou, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Haoyu; Ren, Yu; Zhu, Yue; Tian, Jiaming; Sun, Xinyi; Sheng, Chuanchao; He, Ping; Guo, Shaohua; Zhou, Haoshen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Bio-Inspired Trehalose Additive for Reversible Zinc Anodes with Improved Stability and Kinetics", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The moderate reversibility of Zn anodes, as a long-standing challenge in aqueous zinc-ion batteries, promotes the exploration of suitable electrolyte additives continuously. It is crucial to establish the absolute predominullce of smooth deposition within multiple interfacial reactions for stable zinc anodes, including suppressing side parasitic reactions and facilitating Zn plating process. Trehalose catches our attention due to the reported mechanisms in sustaining biological stabilization. In this work, the inter-disciplinary application of trehalose is reported in the electrolyte modification for the first time. The pivotal roles of trehalose in suppressed hydrogen evolution and accelerated Zn deposition have been investigated based on the principles of thermodynamics as well as reaction kinetics. The electrodeposit changes from random accumulation of flakes to dense bulk with (002)-plane exposure due to the unlocked crystal-face oriented deposition with trehalose addition. As a result, the highly reversible Zn anode is obtained, exhibiting a high average CE of 99.8% in the Zn/Cu cell and stable cycling over 1500h under 9.0% depth of discharge in the Zn symmetric cell. The designing principles and mechanism analysis in this study could serve as a source of inspiration in exploring novel additives for advanced Zn anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2023, "Volume": 62, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202310143", "DOI": "10.1002/anie.202310143", "DOI Link": "http://dx.doi.org/10.1002/anie.202310143", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001183257100056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoshida, K; Gong, JY; Kanibolotsky, AL; Skabara, PJ; Turnbull, GA; Samuel, IDW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoshida, Kou; Gong, Junyi; Kanibolotsky, Alexander L.; Skabara, Peter J.; Turnbull, Graham A.; Samuel, Ifor D. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically driven organic laser using integrated OLED pumping", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic semiconductors are carbon-based materials that combine optoelectronic properties with simple fabrication and the scope for tuning by changing their chemical structure(1-3). They have been successfully used to make organic light-emitting diodes(2,4,5) (OLEDs, now widely found in mobile phone displays and televisions), solar cells(1), transistors(6) and sensors(7). However, making electrically driven organic semiconductor lasers is very challenging(8,9). It is difficult because organic semiconductors typically support only low current densities, suffer substantial absorption from injected charges and triplets, and have additional losses due to contacts(10,11). In short, injecting charges into the gain medium leads to intolerable losses. Here we take an alternative approach in which charge injection and lasing are spatially separated, thereby greatly reducing losses. We achieve this by developing an integrated device structure that efficiently couples an OLED, with exceptionally high internal-light generation, with a polymer distributed feedback laser. Under the electrical driving of the integrated structure, we observe a threshold in light output versus drive current, with a narrow emission spectrum and the formation of a beam above the threshold. These observations confirm lasing. Our results provide an organic electronic device that has not been previously demonstrated, and show that indirect electrical pumping by an OLED is a very effective way of realizing an electrically driven organic semiconductor laser. This provides an approach to visible lasers that could see applications in spectroscopy, metrology and sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2023, "Volume": 621, "Issue": 7980, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 746, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06488-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06488-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001096527500026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YW; Yuan, X; Zhang, C; Jin, Z; Narayan, A; Luo, C; Chen, ZG; Yang, L; Zou, J; Wu, X; Sanvito, S; Xia, ZC; Li, L; Wang, Z; Xiu, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yanwen; Yuan, Xiang; Zhang, Cheng; Jin, Zhao; Narayan, Awadhesh; Luo, Chen; Chen, Zhigang; Yang, Lei; Zou, Jin; Wu, Xing; Sanvito, Stefano; Xia, Zhengcai; Li, Liang; Wang, Zhong; Xiu, Faxian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zeeman splitting and dynamical mass generation in Dirac semimetal ZrTe5", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dirac semimetals have attracted extensive attentions in recent years. It has been theoretically suggested that many-body interactions may drive exotic phase transitions, spontaneously generating a Dirac mass for the nominally massless Dirac electrons. So far, signature of interaction-driven transition has been lacking. In this work, we report high-magnetic-field transport measurements of the Dirac semimetal candidate ZrTe5. Owing to the large g factor in ZrTe5, the Zeeman splitting can be observed at magnetic field as low as 3 T. Most prominently, high pulsed magnetic field up to 60 T drives the system into the ultra-quantum limit, where we observe abrupt changes in the magnetoresistance, indicating field-induced phase transitions. This is interpreted as an interaction-induced spontaneous mass generation of the Dirac fermions, which bears resemblance to the dynamical mass generation of nucleons in high-energy physics. Our work establishes Dirac semimetals as ideal platforms for investigating emerging correlation effects in topological matters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12516, "DOI": "10.1038/ncomms12516", "DOI Link": "http://dx.doi.org/10.1038/ncomms12516", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381528500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, T; Li, Z; Cheng, YF; Xie, HG; Wang, XX; Li Chen, Y; Cheng, L; Liang, Y; Hu, XY; Hung, CM; Hoa, ND; Yu, H; Zhang, BY; Xu, K; Ou, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Tao; Li, Zhong; Cheng, Yin Fen; Xie, Hua Guang; Wang, Xuan Xing; Li Chen, Yong; Cheng, Liang; Liang, Yi; Hu, Xin Yi; Hung, Chu Manh; Hoa, Nguyen Duc; Yu, Hao; Zhang, Bao Yue; Xu, Kai; Ou, Jian Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-situ mechanochemically tailorable 2D gallium oxyselenide for enhanced optoelectronic NO2 gas sensing at room temperature", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The adverse effects of NO2 on the environment and human health promote the development of high-performance gas sensors to address the need for monitoring. Two-dimensional (2D) metal chalcogenides have been considered an emerging group of NO2-sensitive materials, while incomplete recovery and low long-term stability are the two major hurdles for their practical implementation. The transformation into oxychalcogenides is an effective strategy to alleviate these drawbacks, but usually requires multiple-step synthesis and lacks controllability. Here, we prepare tailorable 2D p-type gallium oxyselenide with the thicknesses of 3-4 nm, through a single-step mechanochemical synthesis that combines the in-situ exfoliation and oxidation of bulk crystals. The optoelec-tronic NO2 sensing performances of such 2D gallium oxyselenide with different oxygen contents are investigated at room temperature, in which 2D GaSe0.58O0.42 exhibits the largest response magnitude of 82.2% towards 10 ppm NO2 at the irradiation of UV, with full reversibility, excellent selectivity, and long term stability for at least one month. Such overall performances are significantly improved over those of reported oxygen-incorporated metal chalcogenide-based NO2 sensors. This work provides a feasible approach to prepare 2D metal oxy-chalcogenides in a single-step manner and demonstrates their great potential for room-temperature fully reversible gas sensing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2023, "Volume": 451, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 131184, "DOI": "10.1016/j.jhazmat.2023.131184", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2023.131184", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000956626300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sayavong, P; Zhang, WB; Oyakhire, ST; Boyle, DT; Chen, YL; Kim, SC; Vilá, R; Holmes, SE; Kim, MS; Bent, SF; Bao, ZA; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sayavong, Philaphon; Zhang, Wenbo; Oyakhire, Solomon T.; Boyle, David T.; Chen, Yuelang; Kim, Sang Cheol; Vila, Rafael A.; Holmes, Sarah E.; Kim, Mun Sek; Bent, Stacey F.; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dissolution of the Solid Electrolyte Interphase and Its Effects on Lithium Metal Anode Cyclability", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At>95% Coulombic efficiencies, most of the capacity loss for Limetal anodes (LMAs) is through the formation and growth of the solidelectrolyte interphase (SEI). However, the mechanism through whichthis happens remains unclear. One property of the SEI that directlyaffects its formation and growth is the SEI's solubility inthe electrolyte. Here, we systematically quantify and compare thesolubility of SEIs derived from ether-based electrolytes optimizedfor LMAs using in-operando electrochemical quartzcrystal microbalance (EQCM). A correlation among solubility, passivity,and cyclability established in this work reveals that SEI dissolutionis a major contributor to the differences in passivity and electrochemicalperformance among battery electrolytes. Together with our EQCM, X-rayphotoelectron spectroscopy (XPS), and nuclear magnetic resonullce (NMR)spectroscopy results, we show that solubility depends on not onlythe SEI's composition but also the properties of the electrolyte.This provides a crucial piece of information that could help minimizecapacity loss due to SEI formation and growth during battery cyclingand aging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 23", "Publication Year": 2023, "Volume": 145, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12342, "End Page": 12350, "Article Number": null, "DOI": "10.1021/jacs.3c03195", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c03195", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011835700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Yasiri, Q; Szabó, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Yasiri, Qudama; Szabo, Marta", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Incorporation of phase change materials into building envelope for thermal comfort and energy saving: A comprehensive analysis", "Source Title": "JOURNAL OF BUILDING ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Building envelope is a key element in providing adequate energy and thermal comfort performance to buildings. In this regard, improvement solutions are implemented in recent studies that focus on new techniques and methods. The main techniques adopted in this context are discussed to identify modern and effective methods with a particular focus on phase change materials (PCMs). Incorporating PCMs with building construction materials is a booming technology, owing to their enhancement potential of storing and releasing heat during phase transition. This work highlights the importance of PCMs in building envelope, focusing on roof and external wall applications. PCM types, general and desired properties and application area are presented and discussed. Influential parameters, incorporation techniques and methods, main numerical tools, and modelling equations are used to describe the thermal behaviour of PCM. A comprehensive assessment on the basis of recent studies has been conducted to point out the potential of PCM with the most appropriate techniques under different locations. The main findings of PCM thermal performance have been described, considering the cooling/heating load reduction, energy-saving and thermal comfort gained along with several research hiatuses for future studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 36, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102122, "DOI": "10.1016/j.jobe.2020.102122", "DOI Link": "http://dx.doi.org/10.1016/j.jobe.2020.102122", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000624468500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, HZ; Zhu, JG; Wang, XY; Jiang, B; Sun, H; Liu, XH; Wei, XZ; Han, GS; Ding, SC; Yu, HQ; Li, WH; Sauer, DU; Dai, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Heze; Zhu, Jiangong; Wang, Xueyuan; Jiang, Bo; Sun, Hao; Liu, Xinhua; Wei, Xuezhe; Han, Guangshuai; Ding, Shicong; Yu, Hanqing; Li, Weihan; Sauer, Dirk Uwe; Dai, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonlinear health evaluation for lithium-ion battery within full-lifespan", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs), as the first choice for green batteries, have been widely used in energy storage, electric vehicles, 3C devices, and other related fields, and will have greater application prospects in the future. However, one of the obstacles hindering the future development of battery technology is how to accurately evaluate and monitor battery health, which affects the entire lifespan of battery use. It is not enough to assess battery health comprehensively through the state of health (SoH) alone, especially when nonlinear aging occurs in onboard applications. Here, for the first time, we propose a brand-new health evaluation indicator-state of nonlinear aging (SoNA) to explain the nonlinear aging phenomenon that occurs during the battery use, and also design a knee-point identification method and two SoNA quantitative methods. We apply our health evaluation indicator to build a complete LIB full-lifespan grading evaluation system and a ground-to-cloud service framework, which integrates multi-scenario data collection, multi-dimensional data-based grading evaluation, and cloud management functions. Our works fill the gap in the LIBs' health evaluation of nonlinear aging, which is of great significance for the health and safety evaluation of LIBs in the field of echelon utilization such as vehicles and energy storage. In addition, this comprehensive evaluation system and service framework are expected to be extended to other battery material systems other than LIBs, yet guiding the design of new energy ecosystem.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 72, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 333, "End Page": 341, "Article Number": null, "DOI": "10.1016/j.jechem.2022.04.013", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2022.04.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000831517500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, S; Huang, TY; Yavuz, I; Wang, R; Weber, MH; Zhao, YP; Abdelsamie, M; Liao, ME; Wang, HC; Huynh, K; Wei, KH; Xue, JJ; Babbe, F; Goorsky, MS; Lee, JW; Sutter-Fella, CM; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Shaun; Huang, Tianyi; Yavuz, Ilhan; Wang, Rui; Weber, Marc H.; Zhao, Yepin; Abdelsamie, Maged; Liao, Michael E.; Wang, Hao-Cheng; Huynh, Kenny; Wei, Kung-Hwa; Xue, Jingjing; Babbe, Finn; Goorsky, Mark S.; Lee, Jin-Wook; Sutter-Fella, Carolin M.; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Reconstruction of Halide Perovskites During Post-treatment", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Postfabrication surface treatment strategies have been instrumental to the stability and performance improvements of halide perovskite photovoltaics in recent years. However, a consensus understanding of the complex reconstruction processes occurring at the surface is still lacking. Here, we combined complementary surface-sensitive and depth-resolved techniques to investigate the mechanistic reconstruction of the perovskite surface at the microscale level. We observed a reconstruction toward a more PbI2-rich top surface induced by the commonly used solvent isopropyl alcohol (IPA). We discuss several implications of this reconstruction on the surface thermodynamics and energetics. Particularly, our observations suggest that IPA assists in the adsorption process of organic ammonium salts to the surface to enhance their defect passivation effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2021, "Volume": 143, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6781, "End Page": 6786, "Article Number": null, "DOI": "10.1021/jacs.1c00757", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c00757", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000651748000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kogar, A; Zong, AR; Dolgirev, PE; Shen, XZ; Straquadine, J; Bie, YQ; Wang, XR; Rohwer, T; Tung, IC; Yang, YF; Li, RK; Yang, J; Weathersby, S; Park, S; Kozina, ME; Sie, EJ; Wen, HD; Jarillo-Herrero, P; Fisher, IR; Wang, XJ; Gedik, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kogar, Anshul; Zong, Alfred; Dolgirev, Pavel E.; Shen, Xiaozhe; Straquadine, Joshua; Bie, Ya-Qing; Wang, Xirui; Rohwer, Timm; Tung, I-Cheng; Yang, Yafang; Li, Renkai; Yang, Jie; Weathersby, Stephen; Park, Suji; Kozina, Michael E.; Sie, Edbert J.; Wen, Haidan; Jarillo-Herrero, Pablo; Fisher, Ian R.; Wang, Xijie; Gedik, Nuh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-induced charge density wave in LaTe3", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When electrons in a solid are excited by light, they can alter the free energy landscape and access phases of matter that are out of reach in thermal equilibrium. This accessibility becomes important in the presence of phase competition, when one state of matter is preferred over another by only a small energy scale that, in principle, is surmountable by the excitation. Here, we study a layered compound, LaTe3, where a small lattice anisotropy in the a-c plane results in a unidirectional charge density wave (CDW) along the c axis(1,2). Using ultrafast electron diffraction, we find that, after photoexcitation, the CDW along the c axis is weakened and a different competing CDW along the a axis subsequently emerges. The timescales characterizing the relaxation of this new CDW and the reestablishment of the original CDW are nearly identical, which points towards a strong competition between the two orders. The new density wave represents a transient non-equilibrium phase of matter with no equilibrium counterpart, and this study thus provides a framework for discovering similar states of matter that are 'trapped' under equilibrium conditions. Short pulses of light shift the balance between two competing charge density wave phases, allowing the weaker one to manifest transiently while suppressing the stronger one. This shows that competing phases can be tuned in a non-equilibrium setting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 159, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-019-0705-3", "DOI Link": "http://dx.doi.org/10.1038/s41567-019-0705-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511518200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YW; Li, MH; Liu, Y; Jie, YL; Li, WX; Huang, FY; Li, XP; He, ZX; Ren, XD; Chen, YH; Meng, XH; Cheng, T; Gu, M; Jiao, SH; Cao, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yawei; Li, Menghao; Liu, Yue; Jie, Yulin; Li, Wanxia; Huang, Fanyang; Li, Xinpeng; He, Zixu; Ren, Xiaodi; Chen, Yunhua; Meng, Xianhui; Cheng, Tao; Gu, Meng; Jiao, Shuhong; Cao, Ruiguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of dendrite-free lithium deposition in concentrated electrolytes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrolyte solvation structure and the solid-electrolyte interphase (SEI) formation are critical to dictate the morphology of lithium deposition in organic electrolytes. However, the link between the electrolyte solvation structure and SEI composition and its implications on lithium morphology evolution are poorly understood. Herein, we use a single-salt and single-solvent model electrolyte system to systematically study the correlation between the electrolyte solvation structure, SEI formation process and lithium deposition morphology. The mechanism of lithium deposition is thoroughly investigated using cryo-electron microscopy characterizations and computational simulations. It is observed that, in the high concentration electrolytes, concentrated Li+ and anion-dominated solvation structure initiate the uniform Li nucleation kinetically and favor the decomposition of anions rather than solvents, resulting in inorganic-rich amorphous SEI with high interface energy, which thermodynamically facilitates the formation of granular Li. On the contrary, solvent-dominated solvation structure in the low concentration electrolytes tends to exacerbate the solvolysis process, forming organic-rich mosaic SEI with low interface energy, which leads to aggregated whisker-like nucleation and growth. These results are helpful to tackle the long-standing question on the origin of lithium dendrite formation and guide the rational design of high-performance electrolytes for advanced lithium metal batteries. The origin of dendrite growth and lithium deposition behavior remains not well understood. Here, authors use a single-salt and single-solvent model electrolyte system to study the correlations between the electrolyte solvation structure, interphase structure and lithium deposition morphology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2655, "DOI": "10.1038/s41467-023-38387-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38387-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053796300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jost, M; Köhnen, E; Morales-Vilches, AB; Lipovsek, B; Jäger, K; Macco, B; Al-Ashouri, A; Krc, J; Korte, L; Rech, B; Schlatmann, R; Topic, M; Stannowski, B; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jost, Marko; Koehnen, Eike; Morales-Vilches, Anna Belen; Lipovsek, Benjamin; Jaeger, Klaus; Macco, Bart; Al-Ashouri, Amran; Krc, Janez; Korte, Lars; Rech, Bernd; Schlatmann, Rutger; Topic, Marko; Stannowski, Bernd; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Textured interfaces in monolithic perovskite/silicon tandem solar cells: advanced light management for improved efficiency and energy yield", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient light management in monolithic perovskite/silicon tandem solar cells is one of the prerequisites for achieving high power conversion efficiencies (PCEs). Textured silicon wafers can be utilized for light management, however, this is typically not compatible with perovskite solution processing. Here, we instead employ a textured light management (LM) foil on the front-side of a tandem solar cell processed on a wafer with a planar front-side and textured back-side. This way the PCE of monolithic, 2-terminal perovskite/silicon-heterojunction tandem solar cells is significantly improved from 23.4% to 25.5%. Furthermore, we validate an advanced numerical model for our fabricated device and use it to optically optimize a number of device designs with textures at different interfaces with respect to the PCE and energy yield. These simulations predict a slightly lower optimal bandgap of the perovskite top cell in a textured device as compared to a flat one and demonstrate strong interdependency between the bandgap and the texture position in the monolithic stack. We estimate the PCE potential for the best performing both-side textured device to be 32.5% for a perovskite bandgap of 1.66 eV. Furthermore, the results show that under perpendicular illumination conditions, for optimized designs, the LM foil on top of the cell performs only slightly better than a flat anti-reflective coating. However, under diffuse illumination, the benefits of the LM foil are much greater. Finally, we calculate the energy yield for the different device designs, based on true weather data for three different locations throughout the year, taking direct as well as diffuse illumination fully into account. The results further confirm the benefits of front-side texture, even more for BIPV applications. Overall, devices built on a both-side textured silicon wafer perform best. However, we show that devices with textured LM foils on the cell's front-side are a highly efficient alternative.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2018, "Volume": 11, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3511, "End Page": 3523, "Article Number": null, "DOI": "10.1039/c8ee02469c", "DOI Link": "http://dx.doi.org/10.1039/c8ee02469c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452317700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Fan, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yao; Fan, Hong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Progress and Challenge of Amorphous Catalysts for Electrochemical Water Splitting", "Source Title": "ACS MATERIALS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting has been regarded a promising technology to provide a mobile and sustainable energy supply in the form of hydrogen fuel. The key to further development towards industrial application lies in high-efficiency and low-cost electrocatalysts. In recent years, new attention has been paid to amorphous electrocatalysts, which have short-range atomic ordering instead of translational periodicity. The structural flexibility and rich defects associated with amorphous catalyst materials offer enormous opportunities for electrochemical water splitting. In this Perspective, we elaborate on recent studies of amorphous electrocatalysts for electrochemical water splitting. Our discussion covers the diverse amorphization strategies, the positive role of structural flexibility and defects in enriching active sites, as well as challenges in the characterization of local geometry and in improving electrochemical stability. Finally, we conclude with prospective remarks for future development in amorphous electrocatalyst materials for electrochemical water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 136, "End Page": 147, "Article Number": null, "DOI": "10.1021/acsmaterialslett.0c00502", "DOI Link": "http://dx.doi.org/10.1021/acsmaterialslett.0c00502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000606804800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Muramatsu, H; Lam, K; Bajusz, C; Laczkó, D; Karikó, K; Schreiner, P; Martin, A; Lutwyche, P; Heyes, J; Pardi, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Muramatsu, Hiromi; Lam, Kieu; Bajusz, Csaba; Laczko, Dorottya; Kariko, Katalin; Schreiner, Petra; Martin, Alan; Lutwyche, Peter; Heyes, James; Pardi, Norbert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lyophilization provides long-term stability for a lipid nulloparticle-formulated , nucleoside-modified mRNA vaccine", "Source Title": "MOLECULAR THERAPY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lipid nulloparticle (LNP)-formulated nucleoside-modified mRNA vaccines have proven to be very successful in the fight against the coronavirus disease 2019 (COVID-19) pandemic. They are effective, safe, and can be produced in large quantities. However, the long-term storage of mRNA-LNP vaccines without freezing is still a challenge. Here, we demonstrate that nucleoside-modified mRNA-LNPs can be lyophilized, and the physicochemical properties of the lyophilized material do not significantly change for 12 weeks after storage at room temperature and for at least 24 weeks after storage at 4??C. Importantly, we show in comparative mouse studies that lyophilized firefly luciferase-encoding mRNA-LNPs maintain their high expression, and no decrease in the immunogenicity of a lyophilized influenza virus hemagglutinin-encoding mRNALNP vaccine was observed after 12 weeks of storage at room temperature or for at least 24 weeks after storage at 4??C. Our studies offer a potential solution to overcome the longterm storage-related limitations of nucleoside-modified", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2022, "Volume": 30, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1941, "End Page": 1951, "Article Number": null, "DOI": "10.1016/j.ymthe.2022.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.ymthe.2022.02.001", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Genetics & Heredity; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799823700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, HB; Wang, ZW; Chen, ZH; Pereyra, C; Pols, M; Galkowski, K; Anaya, M; Fu, S; Jia, XY; Tang, PY; Kubicki, DJ; Agarwalla, A; Kim, HS; Prochowicz, D; Borrisé, X; Bonn, M; Bao, CX; Sun, XX; Zakeeruddin, SM; Emsley, L; Arbiol, J; Gao, F; Fu, F; Wang, HI; Tielrooij, KJ; Stranks, SD; Tao, SX; Grätzel, M; Hagfeldt, A; Lira-Cantu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Haibing; Wang, Zaiwei; Chen, Zehua; Pereyra, Carlos; Pols, Mike; Galkowski, Krzysztof; Anaya, Miguel; Fu, Shuai; Jia, Xiaoyu; Tang, Pengyi; Kubicki, Dominik Jozef; Agarwalla, Anulld; Kim, Hui-Seon; Prochowicz, Daniel; Borrise, Xavier; Bonn, Mischa; Bao, Chunxiong; Sun, Xiaoxiao; Zakeeruddin, Shaik Mohammed; Emsley, Lyndon; Arbiol, Jordi; Gao, Feng; Fu, Fan; Wang, Hai, I; Tielrooij, Klaas-Jan; Stranks, Samuel D.; Tao, Shuxia; Graetzel, Michael; Hagfeldt, Anders; Lira-Cantu, Monica", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decoupling the effects of defects on efficiency and stability through phosphonates in stable halide perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding defects is of paramount importance for the development of stable halide perovskite solar cells (PSCs). However, isolating their distinctive effects on device efficiency and stability is currently a challenge. We report that adding the organic molecule 3-phosphonopropionic acid (H3pp) to the halide perovskite results in unchanged overall optoelectronic performance while having a tremendous effect on device stability. We obtained PSCs with similar to 21% efficiency that retain similar to 100% of the initial efficiency after 1,000 h at the maximum power point under simulated AM1.5G illumination. The strong interaction between the perovskite and the H3pp molecule through two types of hydrogen bonds (H center dot center dot center dot I and O center dot center dot center dot H) leads to shallow point defect passivation that has a significant effect on device stability but not on the non-radiative recombination and device efficiency. We expect that our work will have important implications for the current understanding and advancement of operational PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2021, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1246, "End Page": 1266, "Article Number": null, "DOI": "10.1016/j.joule.2021.04.003", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.04.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654225600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Drost, R; Ojanen, T; Harju, A; Liljeroth, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Drost, Robert; Ojanen, Teemu; Harju, Ari; Liljeroth, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological states in engineered atomic lattices", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological materials exhibit protected edge modes that have been proposed for applications in, for example, spintronics and quantum computation. Although a number of such systems exist(1-6), it would be desirable to be able to test theoretical proposals in an artificial system that allows precise control over the key parameters of the model(7). The essential physics of several topological systems can be captured by tight-binding models, which can also be implemented in artificial lattices(6,7). Here, we show that this method can be realized in a vacancy lattice in a chlorine monolayer on a Cu(100) surface. We use low-temperature scanning tunnelling microscopy (STM) to fabricate such lattices with atomic precision and probe the resulting local density of states (LDOS) with scanning tunnelling spectroscopy (STS). We create analogues of two tight-binding models of fundamental importance: the polyacetylene (dimer) chain with topological domain-wall states, and the Lieb lattice with a flat electron band. These results provide an important step forward in the ongoing effort to realize designer quantum materials with tailored properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 668, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS4080", "DOI Link": "http://dx.doi.org/10.1038/NPHYS4080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404629900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abueidda, DW; Elhebeary, M; Shiang, CS; Pang, SY; Abu Al-Rub, RK; Jasiuk, IM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abueidda, Diab W.; Elhebeary, Mohamed; Shiang, Cheng-Shen (Andrew); Pang, Siyuan; Abu Al-Rub, Rashid K.; Jasiuk, Iwona M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties of 3D printed polymeric Gyroid cellular structures: Experimental and finite element study", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gyroid is a member of the triply periodic minimal surfaces (TPMS) family. In this paper, the mechanical properties of Gyroid-structures are investigated both experimentally and computationally. 3D printing is used to fabricate polymeric Gyroid-structure specimens made of PA 2200 at different relative densities. In the finite element analysis, the Arruda-Boyce finite-deformation elasto-viscoplastic model is employed. To perform the finite element analysis, the properties of the 3D printed material are determined by a series of tension and compression tests. The finite element results of the Gyroid-structure agree verywell with the experimental data. Also, the uniaxialmodulus, compressive strength, and energy absorption of the Gyroid-structures are comparedwith those of the IWP-, Neovius-, and Primitive-structures from a previous study. The comparison shows that Gyroidstructures have relatively good mechanical properties and competewell with the other TPMS cellular structures. (c) 2019 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2019, "Volume": 165, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107597, "DOI": "10.1016/j.matdes.2019.107597", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2019.107597", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458259300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, GB; Yang, TH; Li, X; Ahmad, N; Zhang, XN; Yue, SL; Zhou, J; Li, YX; Wang, H; Shi, XH; Liu, SZ; Zhao, K; Zhou, HQ; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Guangbao; Yang, Tinghuan; Li, Xing; Ahmad, Nafees; Zhang, Xuning; Yue, Shengli; Zhou, Jin; Li, Yanxun; Wang, Hui; Shi, Xinghua; Liu, Shengzhong (Frank); Zhao, Kui; Zhou, Huiqiong; Zhang, Yuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular Engineering for Two-Dimensional Perovskites with Photovoltaic Efficiency Exceeding 18%", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) perovskites with excellent stability and optoelectronic properties have aroused great interest for use in perovskite solar cells (PSCs). To date, the power conversion efficiencies (PCEs) of state-of-the art 2D-PSCs are non-satisfactory because of higher recombination losses in 2D quantum wells. Here, based on a series of alkylic ammonium spacers (ethylamine to hexylamine) with different chain lengths, we present a strategy via the molecular van der Waals interaction to realize modified crystallization, phase distribution, and quantum-confined behaviors in Ruddlesden-Popper 2D perovskites (n = 4). With the optimal amylamine (AA) spacer, high-quality 2D perovskites featuring well-aligned phase alignments with fewer unfavorable n-value species and a reduced exciton binding energy have been realized, leading to sufficient charge transfers through different n -value components. The devices based on (AA)(2)MA(3)Pb(4)I(13) yield a champion PCE of 18.42%, showing an impressive open-circuit voltage of 1.25 V and a fill factor exceeding 0.80.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2021, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.matt.2020.11.011", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2020.11.011", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632645100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Riede, M; Spoltore, D; Leo, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Riede, Moritz; Spoltore, Donato; Leo, Karl", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic Solar Cells-The Path to Commercial Success", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic solar cells have the potential to become the cheapest form of electricity, beating even silicon photovoltaics. This article summarizes the state of the art in the field, highlighting research challenges, mainly the need for an efficiency increase as well as an improvement in long-term stability. It discusses possible current and future applications, such as building integrated photovoltaics or portable electronics. Finally, the environmental footprint of this renewable energy technology is evaluated, highlighting the potential to be the energy generation technology with the lowest carbon footprint of all.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002653, "DOI": "10.1002/aenm.202002653", "DOI Link": "http://dx.doi.org/10.1002/aenm.202002653", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000589525200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MQ; Yao, L; Ji, YC; Zhang, MZ; Cai, YL; Li, HY; Zhao, WG; Zhao, Y; Zou, ZX; Qin, RZ; Wang, YT; Liu, LL; Liu, H; Miller, TS; Pan, F; Yang, JL; Gan, YH; Yang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingqiang; Yao, Lu; Ji, Yuchen; Zhang, Mingzheng; Cai, Yulu; Li, Hongyang; Zhao, Wenguang; Zhao, Yan; Zou, Zexin; Qin, Runzhi; Wang, Yuetao; Liu, Lele; Liu, Hao; Miller, Thomas S.; Pan, Feng; Yang, Jinlong; Gan, Yihang; Yang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale Ultrafine Zinc Metal Anodes for High Stability Aqueous Zinc Ion Batteries", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn batteries (AZBs) are a promising energy storage technology, due to their high theoretical capacity, low redox potential, and safety. However, dendrite growth and parasitic reactions occurring at the surface of metallic Zn result in severe instability. Here we report a new method to achieve ultrafine Zn nullograin anodes by using ethylene glycol monomethyl ether (EGME) molecules to manipulate zinc nucleation and growth processes. It is demonstrated that EGME complexes with Zn2+ to moderately increase the driving force for nucleation, as well as adsorbs on the Zn surface to prevent H corrosion and dendritic protuberances by refining the grains. As a result, the nulloscale anode delivers high Coulombic efficiency (ca. 99.5%), long-term cycle life (over 366 days and 8800 cycles), and outstanding compatibility with state-of-the-art cathodes (ZnVO and AC) in full cells. This work offers a new route for interfacial engineering in aqueous metal-ion batteries, with significant implications for the commercial future of AZBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 3", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acs.nullolett.2c03919", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.2c03919", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000908829500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stier, AV; McCreary, KM; Jonker, BT; Kono, J; Crooker, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stier, Andreas V.; McCreary, Kathleen M.; Jonker, Berend T.; Kono, Junichiro; Crooker, Scott A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In bulk and quantum-confined semiconductors, magneto-optical studies have historically played an essential role in determining the fundamental parameters of excitons (size, binding energy, spin, dimensionality and so on). Here we report low-temperature polarized reflection spectroscopy of atomically thin WS2 and MoS2 in high magnetic fields to 65 T. Both the A and B excitons exhibit similar Zeeman splittings of approximately -230 mu eV T-1 (g-factor similar or equal to -4), thereby quantifying the valley Zeeman effect in monolayer transition-metal disulphides. Crucially, these large fields also allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer WS2, from which radii of similar to 1.53 and similar to 1.16nm are calculated. Further, when analysed within a model of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and B exciton binding energies (410 and 470 meV, respectively, using a reduced A exciton mass of 0.16 times the free electron mass). These results highlight the utility of high magnetic fields for understanding new two-dimensional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10643, "DOI": "10.1038/ncomms10643", "DOI Link": "http://dx.doi.org/10.1038/ncomms10643", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371020600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mitterreiter, E; Schuler, B; Micevic, A; Hernullgómez-Pérez, D; Barthelmi, K; Cochrane, KA; Kiemle, J; Sigger, F; Klein, J; Wong, E; Barnard, ES; Watanabe, K; Taniguchi, T; Lorke, M; Jahnke, F; Finley, JJ; Schwartzberg, AM; Qiu, DY; Refaely-Abramson, S; Holleitner, AW; Weber-Bargioni, A; Kastl, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mitterreiter, Elmar; Schuler, Bruno; Micevic, Ana; Hernullgomez-Perez, Daniel; Barthelmi, Katja; Cochrane, Katherine A.; Kiemle, Jonas; Sigger, Florian; Klein, Julian; Wong, Edward; Barnard, Edward S.; Watanabe, Kenji; Taniguchi, Takashi; Lorke, Michael; Jahnke, Frank; Finley, Johnathan J.; Schwartzberg, Adam M.; Qiu, Diana Y.; Refaely-Abramson, Sivan; Holleitner, Alexander W.; Weber-Bargioni, Alexander; Kastl, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of chalcogen vacancies for atomic defect emission in MoS2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For two-dimensional (2D) layered semiconductors, control over atomic defects and understanding of their electronic and optical functionality represent major challenges towards developing a mature semiconductor technology using such materials. Here, we correlate generation, optical spectroscopy, atomic resolution imaging, and ab initio theory of chalcogen vacancies in monolayer MoS2. Chalcogen vacancies are selectively generated by in-vacuo annealing, but also focused ion beam exposure. The defect generation rate, atomic imaging and the optical signatures support this claim. We discriminate the narrow linewidth photoluminescence signatures of vacancies, resulting predominulltly from localized defect orbitals, from broad luminescence features in the same spectral range, resulting from adsorbates. Vacancies can be patterned with a precision below 10nm by ion beams, show single photon emission, and open the possibility for advanced defect engineering of 2D semiconductors at the ultimate scale. The relation between the microscopic structure and the optical properties of atomic defects in 2D semiconductors is still debated. Here, the authors correlate different fabrication processes, optical spectroscopy and electron microscopy to identify the optical signatures of chalcogen vacancies in monolayer MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3822, "DOI": "10.1038/s41467-021-24102-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24102-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000669043000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yamada, H; Liu, C; Wu, S; Koyama, Y; Ju, SH; Shiomi, J; Morikawa, J; Yoshida, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yamada, Hironao; Liu, Chang; Wu, Stephen; Koyama, Yukinori; Ju, Shenghong; Shiomi, Junichiro; Morikawa, Junko; Yoshida, Ryo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Predicting Materials Properties with Little Data Using Shotgun Transfer Learning", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is a growing demand for the use of machine learning (ML) to derive fast-to-evaluate surrogate models of materials properties. In recent years, a broad array of materials property databases have emerged as part of a digital transformation of materials science. However, recent technological advances in ML are not fully exploited because of the insufficient volume and diversity of materials data. An ML framework called transfer learning has considerable potential to overcome the problem of limited amounts of materials data. Transfer learning relies on the concept that various property types, such as physical, chemical, electronic, thermodynamic, and mechanical properties, are physically interrelated. For a given target property to be predicted from a limited supply of training data, models of related proxy properties are pretrained using sufficient data; these models capture common features relevant to the target task. Repurposing of such machine-acquired features on the target task yields outstanding prediction performance even with exceedingly small data sets, as if highly experienced human experts can make rational inferences even for considerably less experienced tasks. In this study, to facilitate widespread use of transfer learning, we develop a pretrained model library called XenonPy.MDL. In this first release, the library comprises more than 140 000 pretrained models for various properties of small molecules, polymers, and inorganic crystalline materials. Along with these pretrained models, we describe some outstanding successes of transfer learning in different scenarios such as building models with only dozens of materials data, increasing the ability of extrapolative prediction through a strategic model transfer, and so on. Remarkably, transfer learning has autonomously identified rather nontrivial transferability across different properties transcending the different disciplines of materials science; for example, our analysis has revealed underlying bridges between small molecules and polymers and between organic and inorganic chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2019, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1717, "End Page": 1730, "Article Number": null, "DOI": "10.1021/acscentsci.9b00804", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492698300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, YW; Galarraga, H; Lados, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Yuwei; Galarraga, Haize; Lados, Diana A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure, static properties, and fatigue crack growth mechanisms in Ti-6Al-4V fabricated by additive manufacturing: LENS and EBM", "Source Title": "ENGINEERING FAILURE ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) technology is capable of building 3D near-net-shaped functional parts directly from computer models using unit materials, such as powder or wire. Additive manufacturing's computer-aided design offers superior geometrical flexibility. The near-net-shaping capability also significantly reduces materials waste. These benefits make AM desirable for critical applications, such as aerospace, ground transportation, and medical. Confident utilization of the technology requires thorough understanding of the AM materials, ensuring that structural integrity and performance requirements are met or exceeded. In this study, Ti-6Al-4V fabricated by two AM techniques: Laser Engineered Net Shaping (LENS) and Electron Beam Melting (EBM) were investigated and critically compared. Samples were built using various processing parameters and heat treated under different conditions, which resulted in different microstructures and mechanical properties. Characteristic microstructures were determined for all cases. Room temperature tensile and fatigue crack growth properties were also evaluated and compared in different orientations with respect to the building direction. The effects of post-AM heat treatments on microstructure and properties were also studied. The results are systematically presented and discussed from the material/process optimization, structural design, and fatigue life prediction perspectives. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 69, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3, "End Page": 14, "Article Number": null, "DOI": "10.1016/j.engfailanal.2016.05.036", "DOI Link": "http://dx.doi.org/10.1016/j.engfailanal.2016.05.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384144700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nian, L; Kan, YY; Gao, K; Zhang, M; Li, N; Zhou, GQ; Jo, SB; Shi, XL; Lin, F; Rong, QK; Liu, F; Zhou, GF; Jen, AKY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nian, Li; Kan, Yuanyuan; Gao, Ke; Zhang, Ming; Li, Na; Zhou, Guanqing; Jo, Sae Byeok; Shi, Xueliang; Lin, Francis; Rong, Qikun; Liu, Feng; Zhou, Guofu; Jen, Alex K-Y", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Approaching 16% Efficiency in All-Small-Molecule Organic Solar Cells Based on Ternary Strategy with a Highly Crystalline Acceptor", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-small-molecule organic solar cells (SM-OSCs) with a high power conversion efficiency (PCE) of 15.88% (certified 15.5%) are demonstrated by employing 4TIC as the additional non-fullerene acceptor (NFA) to construct ternary SM-OSCs. 4TIC is a highly crystalline acceptor with a similar molecular structure as 6TIC, the host NFA in the binary blend. The addition of 4TIC not only significantly enhances the crystallinity of the blend film but also maintains the desired face-on orientation in the proper multi-length scale morphology to improve both charge extraction and recombination in devices. As a result, the PCE of the ZnP-TBO: 6TIC-based SM-OSCs increases from 12.11% to 14.73% after the addition of 4TIC. For ZnP-TSEH: 6TIC-based SM-OSCs, the PCE increases from 13.54% to 15.88% (certified 15.5%) after the addition of 4TIC. The 15.88% efficiency is the best result for SM-OSCs reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2020, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2223, "End Page": 2236, "Article Number": null, "DOI": "10.1016/j.joule.2020.08.011", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.08.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000581182900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bose, A; Schreiber, NJ; Jain, R; Shao, DF; Nair, HP; Sun, JX; Zhang, XS; Muller, DA; Tsymbal, EY; Schlom, DG; Ralph, DC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bose, Arnab; Schreiber, Nathaniel J.; Jain, Rakshit; Shao, Ding-Fu; Nair, Hari P.; Sun, Jiaxin; Zhang, Xiyue S.; Muller, David A.; Tsymbal, Evgeny Y.; Schlom, Darrell G.; Ralph, Daniel C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tilted spin current generated by the collinear antiferromagnet ruthenium dioxide", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symmetry plays a central role in determining the polarization of spin currents induced by electric fields. It also influences how these spin currents generate spin-transfer torques in magnetic devices. Here we show that an out-of-plane damping-like torque can be generated in ruthenium dioxide (RuO2)/permalloy devices when the Neel vector of the collinear antiferromagnet RuO2 is canted relative to the sample plane. By measuring characteristic changes in all three components of the electric-field-induced torque vector as a function of the angle of the electric field relative to the crystal axes, we find that the RuO2 generates a spin current with a well-defined tilted spin orientation that is approximately parallel to the Neel vector. A maximum out-of-plane damping-like spin torque efficiency per unit electric field of 7 +/- 1 x 10(3) omega(-1) m(-1) is measured at room temperature. The observed angular dependence indicates that this is an antiferromagnetic spin Hall effect with symmetries that are distinct from other mechanisms of spin-current generation reported in antiferromagnetic and ferromagnetic materials. The collinear antiferromagnet ruthenium dioxide (RuO2) can generate an electric-field-induced spin current with a well-defined tilted spin orientation that is approximately parallel to the Neel vector.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 267, "End Page": 274, "Article Number": null, "DOI": "10.1038/s41928-022-00744-8", "DOI Link": "http://dx.doi.org/10.1038/s41928-022-00744-8", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791157800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khatami, K; Perez-Zabaleta, M; Owusu-Agyeman, I; Cetecioglu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khatami, Kasra; Perez-Zabaleta, Mariel; Owusu-Agyeman, Isaac; Cetecioglu, Zeynep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Waste to bioplastics: How close are we to sustainable polyhydroxyalkanoates production?", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increased awareness of environmental sustainability with associated strict environmental regulations has incentivized the pursuit of novel materials to replace conventional petroleum-derived plastics. Polyhydroxyalkanoates (PHAs) are appealing intracellular biopolymers and have drawn significant attention as a viable alternative to petrochemical based plastics not only due to their comparable physiochemical properties but also, their outstanding characteristics such as biodegradability and biocompatibility. This review provides a comprehensive overview of the recent developments on the involved PHA producer microorganisms, production process from different waste streams by both pure and mixed microbial cultures (MMCs). Bio-based PHA production, particularly using cheap carbon sources with MMCs, is getting more attention. The main bottlenecks are the low production yield and the inconsistency of the biopolymers. Bioaugmentation and metabolic engineering together with cost effective downstream processing are promising approaches to overcome the hurdles of commercial PHA production from waste streams. (C) 2020 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 374, "End Page": 388, "Article Number": null, "DOI": "10.1016/j.wasman.2020.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2020.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599766200036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, RJ; Yan, CQ; Fong, PWK; Yu, JS; Liu, H; Yin, JL; Huang, JH; Lu, XH; Yan, H; Li, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Ruijie; Yan, Cenqi; Fong, Patrick Wai-Keung; Yu, Jiangsheng; Liu, Heng; Yin, Junli; Huang, Jianhua; Lu, Xinhui; Yan, He; Li, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ and ex situ investigations on ternary strategy and co-solvent effects towards high-efficiency organic solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The morphology of organic solar cells (OSCs) is a core topic for achieving the ultimate photovoltaic performance. Herein, we focused on the combination of two important morphology regulation strategies, i.e., ternary strategy and cosolvent engineering. Using an amorphous polymer acceptor, BN-T, as the third component, the PM6:BTP-eC11 and PM6:eC9 host binary systems, treated by the o-xylene and 1-phenylnaphthalene solvent system and chlorobenzene and 1,8-diiodooctane solvent system, respectively, both realized an effective improvement in the power conversion efficiencies (PCEs). However, the ex situ morphological characterization revealed that these two systems undergo different types of changes in phase segregation and molecular packing, which cannot be understood by the current popular miscibility analysis. In this work, an in situ investigation was carried out during the spin casting and thermal annealing processes. The time-resolved reflection spectroscopy technique showed that BN-T retained more PN in the ternary films during the casting process, thereby facilitating the aggregation of eC11 and enlarging its domain size. In contrast, the incorporation of BN-T did not affect the DIO content in the films, resulting in a less separated morphology for the eC9-based systems, as predicted by the miscibility study. In addition to state-of-the-art PCEs, this work provides an insightful understanding of the morphology evolution in ternary OSCs assisted by a high-boiling solvent additive via in situ investigation techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2479, "End Page": 2488, "Article Number": null, "DOI": "10.1039/d2ee00740a", "DOI Link": "http://dx.doi.org/10.1039/d2ee00740a", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000790361200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Latini, S; Olsen, T; Thygesen, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Latini, S.; Olsen, T.; Thygesen, K. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitons in van der Waals heterostructures: The important role of dielectric screening", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The existence of strongly bound excitons is one of the hallmarks of the newly discovered atomically thin semiconductors. While it is understood that the large binding energy is mainly due to the weak dielectric screening in two dimensions, a systematic investigation of the role of screening on two-dimensional (2D) excitons is still lacking. Here we provide a critical assessment of a widely used 2D hydrogenic exciton model, which assumes a dielectric function of the form epsilon(q) = 1 + 2 pi alpha q, and we develop a quasi-2D model with a much broader applicability. Within the quasi-2D picture, electrons and holes are described as in-plane point charges with a finite extension in the perpendicular direction, and their interaction is screened by a dielectric function with a nonlinear q dependence which is computed ab initio. The screened interaction is used in a generalized Mott-Wannier model to calculate exciton binding energies in both isolated and supported 2D materials. For isolated 2D materials, the quasi-2D treatment yields results almost identical to those of the strict 2D model, and both are in good agreement with ab initio many-body calculations. On the other hand, for more complex structures such as supported layers or layers embedded in a van der Waals heterostructure, the size of the exciton in reciprocal space extends well beyond the linear regime of the dielectric function, and a quasi-2D description has to replace the 2D one. Our methodology has the merit of providing a seamless connection between the strict 2D limit of isolated monolayer materials and the more bulk-like screening characteristics of supported 2D materials or van der Waals heterostructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2015, "Volume": 92, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 245123, "DOI": "10.1103/PhysRevB.92.245123", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.245123", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366731800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghiotto, A; Shih, EM; Pereira, GSSG; Rhodes, DA; Kim, B; Zang, JW; Millis, AJ; Watanabe, K; Taniguchi, T; Hone, JC; Wang, L; Dean, CR; Pasupathy, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghiotto, Augusto; Shih, En-Min; Pereira, Giancarlo S. S. G.; Rhodes, Daniel A.; Kim, Bumho; Zang, Jiawei; Millis, Andrew J.; Watanabe, Kenji; Taniguchi, Takashi; Hone, James C.; Wang, Lei; Dean, Cory R.; Pasupathy, Abhay N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum criticality in twisted transition metal dichalcogenides", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-to-insulator transitions are characterized in twisted WSe, revealing strange metal behaviour and quantum criticality at low temperatures. Near the boundary between ordered and disordered quantum phases, several experiments have demonstrated metallic behaviour that defies the Landau Fermi paradigm(1-5). In moire heterostructures, gate-tuneable insulating phases driven by electronic correlations have been recently discovered(6-23). Here, we use transport measurements to characterize metal-insulator transitions (MITs) in twisted WSe2 near half filling of the first moire subband. We find that the MIT as a function of both density and displacement field is continuous. At the metal-insulator boundary, the resistivity displays strange metal behaviour at low temperatures, with dissipation comparable to that at the Planckian limit. Further into the metallic phase, Fermi liquid behaviour is recovered at low temperature, and this evolves into a quantum critical fan at intermediate temperatures, before eventually reaching an anomalous saturated regime near room temperature. An analysis of the residual resistivity indicates the presence of strong quantum fluctuations in the insulating phase. These results establish twisted WSe2 as a new platform to study doping and bandwidth-controlled metal-insulator quantum phase transitions on the triangular lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2021, "Volume": 597, "Issue": 7876, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03815-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03815-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696334600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Otterstrom, NT; Behunin, RO; Kittlaus, EA; Wang, Z; Rakich, PT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Otterstrom, Nils T.; Behunin, Ryan O.; Kittlaus, Eric A.; Wang, Zheng; Rakich, Peter T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A silicon Brillouin laser", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Brillouin laser oscillators offer powerful and flexible dynamics as the basis for mode-locked lasers, microwave oscillators, and optical gyroscopes in a variety of optical systems. However, Brillouin interactions are markedly weak in conventional silicon photonic waveguides, stifling progress toward silicon-based Brillouin lasers. The recent advent of hybrid photonic-phononic waveguides has revealed Brillouin interactions to be one of the strongest and most tailorable nonlinearities in silicon. In this study, we have harnessed these engineered nonlinearities to demonstrate Brillouin lasing in silicon. Moreover, we show that this silicon-based Brillouin laser enters a regime of dynamics in which optical self-oscillation produces phonon linewidth narrowing. Our results provide a platform to develop a range of applications for monolithic integration within silicon photonic circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2018, "Volume": 360, "Issue": 6393, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1113, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar6113", "DOI Link": "http://dx.doi.org/10.1126/science.aar6113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434635500044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hrabec, A; Sampaio, J; Belmeguenai, M; Gross, I; Weil, R; Chérif, SM; Stashkevich, A; Jacques, V; Thiaville, A; Rohart, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hrabec, A.; Sampaio, J.; Belmeguenai, M.; Gross, I.; Weil, R.; Cherif, S. M.; Stashkevich, A.; Jacques, V.; Thiaville, A.; Rohart, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current-induced skyrmion generation and dynamics in symmetric bilayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are quasiparticle-like textures which are topologically different from other states. Their discovery in systems with broken inversion symmetry sparked the search for materials containing such magnetic phase at room temperature. Their topological properties combined with the chirality-related spin-orbit torques make them interesting objects to control the magnetization at nulloscale. Here we show that a pair of coupled skyrmions of opposite chiralities can be stabilized in a symmetric magnetic bilayer system by combining Dzyaloshinskii-Moriya interaction (DMI) and dipolar coupling effects. This opens a path for skyrmion stabilization with lower DMI. We demonstrate in a device with asymmetric electrodes that such skyrmions can be independently written and shifted by electric current at large velocities. The skyrmionic nature of the observed quasiparticles is confirmed by the gyrotropic force. These results set the ground for emerging spintronic technologies where issues concerning skyrmion stability, nucleation and propagation are paramount.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15765, "DOI": "10.1038/ncomms15765", "DOI Link": "http://dx.doi.org/10.1038/ncomms15765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402870600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, N; Xia, N; Liao, LW; Zhu, M; Jin, FM; Jin, RC; Wu, ZK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, null; Xia, null; Liao, Lingwen; Zhu, Min; Jin, Fengming; Jin, Rongchao; Wu, Zhikun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling the long-pursued Au144 structure by x-ray crystallography", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The transition from nullocluster to nullocrystal is a central issue in nulloscience. The atomic structure determination of metal nulloparticles in the transition size range is challenging and particularly important in understanding the quantum size effect at the atomic level. On the basis of the rationale that the intra-and interparticle weak interactions play critical roles in growing high-quality single crystals of metal nulloparticles, we have reproducibly obtained ideal crystals of Au-144(SR)(60) and successfully solved its structure by x-ray crystallography (XRC); this structure was theoretically predicted a decade ago and has long been pursued experimentally but without success until now. Here, XRC reveals an interesting Au-12 hollow icosahedron in thiolated gold nulloclusters for the first time. The Au-Au bond length, close to that of bulk gold, shows better thermal extensibility than the other Au-Au bond lengths in Au-144(SR)(60), providing an atomic-level perspective because metal generally shows better thermal extensibility than nonmetal materials. Thus, our work not only reveals the mysterious, long experimentally pursued structure of a transition-sized nulloparticle but also has important implications for the growth of high-quality, single-crystal nulloparticles, as well as for the understanding of the thermal extensibility of metals from the perspective of chemical bonding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat7259", "DOI": "10.1126/sciadv.aat7259", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat7259", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000449221200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palacios-Berraquero, C; Kara, DM; Montblanch, ARP; Barbone, M; Latawiec, P; Yoon, D; Ott, AK; Loncar, M; Ferrari, AC; Atatüre, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palacios-Berraquero, Carmen; Kara, Dhiren M.; Montblanch, Alejandro R. -P.; Barbone, Matteo; Latawiec, Pawel; Yoon, Duhee; Ott, Anna K.; Loncar, Marko; Ferrari, Andrea C.; Atature, Mete", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale quantum-emitter arrays in atomically thin semiconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum light emitters have been observed in atomically thin layers of transition metal dichalcogenides. However, they are found at random locations within the host material and usually in low densities, hindering experiments aiming to investigate this new class of emitters. Here, we create deterministic arrays of hundreds of quantum emitters in tungsten diselenide and tungsten disulphide monolayers, emitting across a range of wavelengths in the visible spectrum (610-680 nm and 740-820 nm), with a greater spectral stability than their randomly occurring counterparts. This is achieved by depositing monolayers onto silica substrates nullopatterned with arrays of 150-nm-diameter pillars ranging from 60 to 190nm in height. The nullopillars create localized deformations in the material resulting in the quantum confinement of excitons. Our method may enable the placement of emitters in photonic structures such as optical waveguides in a scalable way, where precise and accurate positioning is paramount.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 503, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15093, "DOI": "10.1038/ncomms15093", "DOI Link": "http://dx.doi.org/10.1038/ncomms15093", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401906700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WD; Xu, HY; Zhang, HY; Wei, FC; Huang, LY; Ke, SZ; Fu, JW; Jing, CB; Cheng, JG; Liu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Wenda; Xu, Hengyue; Zhang, Hongyi; Wei, Facai; Huang, Lingyan; Ke, Shanzhe; Fu, Jianwei; Jing, Chengbin; Cheng, Jiangong; Liu, Shaohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning electron delocalization of hydrogen-bonded organic framework cathode for high-performance zinc-organic batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stable cathodes with multiple redox-active centres affording a high energy density, fast redox kinetics and a long life are continuous pursuits for aqueous zinc-organic batteries. Here, we achieve a high-performance zinc-organic battery by tuning the electron delocalization within a designed fully conjugated two-dimensional hydrogen-bonded organic framework as a cathode material. Notably, the intermolecular hydrogen bonds endow this framework with a transverse two-dimensional extended stacking network and structural stability, whereas the multiple C = O and C = N electroactive centres cooperatively trigger multielectron redox chemistry with super delocalization, thereby sharply boosting the redox potential, intrinsic electronic conductivity and redox kinetics. Further mechanistic investigations reveal that the fully conjugated molecular configuration enables reversible Zn2+/H+ synergistic storage accompanied by 10-electron transfer. Benefitting from the above synergistic effects, the elaborately tailored organic cathode delivers a reversible capacity of 498.6 mAh g(-1) at 0.2 A g(-1), good cyclability and a high energy density (355 Wh kg(-1)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5235, "DOI": "10.1038/s41467-023-40969-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40969-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057573200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, TR; Xu, SY; Chang, G; Lee, CC; Huang, SM; Wang, B; Bian, G; Zheng, H; Sanchez, DS; Belopolski, I; Alidoust, N; Neupane, M; Bansil, A; Jeng, HT; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Tay-Rong; Xu, Su-Yang; Chang, Guoqing; Lee, Chi-Cheng; Huang, Shin-Ming; Wang, BaoKai; Bian, Guang; Zheng, Hao; Sanchez, Daniel S.; Belopolski, Ilya; Alidoust, Nasser; Neupane, Madhab; Bansil, Arun; Jeng, Horng-Tay; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of an arc-tunable Weyl Fermion metallic state in MoxW1-xTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Weyl semimetal is a new state of matter that hosts Weyl fermions as emergent quasiparticles. The Weyl fermions correspond to isolated points of bulk band degeneracy, Weyl nodes, which are connected only through the crystal's boundary by exotic Fermi arcs. The length of the Fermi arc gives a measure of the topological strength, because the only way to destroy the Weyl nodes is to annihilate them in pairs in the reciprocal space. To date, Weyl semimetals are only realized in the TaAs class. Here, we propose a tunable Weyl state in MoxW1-xTe2 where Weyl nodes are formed by touching points between metallic pockets. We show that the Fermi arc length can be changed as a function of Mo concentration, thus tuning the topological strength. Our results provide an experimentally feasible route to realizing Weyl physics in the layered compound MoxW1-xTe2, where non-saturating magneto-resistance and pressure-driven superconductivity have been observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10639, "DOI": "10.1038/ncomms10639", "DOI Link": "http://dx.doi.org/10.1038/ncomms10639", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371020600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, GY; Dai, HY; Wang, Q; Zhou, JP; Fan, TJ; Zeng, X; Wang, X; Zhang, YW; Yang, DZ; Ma, DG; Zhang, DD; Duan, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Guoyun; Dai, Hengyi; Wang, Qi; Zhou, Jianping; Fan, Tianjiao; Zeng, Xuan; Wang, Xiang; Zhang, Yuewei; Yang, Dezhi; Ma, Dongge; Zhang, Dongdong; Duan, Lian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency and stable short-delayed fluorescence emitters with hybrid long- and short-range charge-transfer excitations", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To possess a small singlet-triplet energy gap and a large oscillator strength simultaneously is critical for efficient thermally activated delayed fluorescent emitters. Here, the authors attach an multiresonullce-acceptor onto a sterically-uncrowded donor for realizing a device efficiency of 40.4%. The pursuit of ideal short-delayed thermally activated delayed fluorescence (TADF) emitters is hampered by the mutual exclusion of a small singlet-triplet energy gap (Delta E-ST) and a large oscillator strength (f). Here, by attaching an multiresonullce-acceptor onto a sterically-uncrowded donor, we report TADF emitters bearing hybrid electronic excitations with a main donor-to-acceptor long-range (LR) and an auxiliary bridge-phenyl short-range (SR) charge-transfer characters, balancing a small Delta E-ST and a large f. Moreover, the incorporation of dual equivalent multiresonullce-acceptors is found to double the f value without affecting the Delta E-ST. A large radiative decay rate over an order of magnitude higher than the intersystem crossing (ISC) rate, and a decent reverse ISC rate of >10(6) s(-1) are simultaneously obtained in one emitter, leading to a short delayed-lifetime of similar to 0.88 mu s. The corresponding organic light-emitting diode exhibits a record-high maximum external quantum efficiency of 40.4% with alleviated efficiency roll-off and extended lifetime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2394, "DOI": "10.1038/s41467-023-38086-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38086-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979744000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HS; Truong, NP; Pei, ZP; Coote, ML; Anastasaki, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hyun Suk; Truong, Nghia P.; Pei, Zhipeng; Coote, Michelle L.; Anastasaki, Athina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversing RAFT Polymerization: Near-Quantitative Monomer Generation Via a Catalyst-Free Depolymerization Approach", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to reverse controlled radical polymerization and regenerate the monomer would be highly beneficial for both fundamental research and applications, yet this has remained very challenging to achieve. Herein, we report a near-quantitative (up to 92%) and catalyst-free depolymerization of various linear, bulky, cross-linked, and functional polymethacrylates made by reversible addition-fragmentation chain-transfer (RAFT) polymerization. Key to our approach is to exploit the high end-group fidelity of RAFT polymers to generate chain-end radicals at 120 degrees C. These radicals trigger a rapid unzipping of both conventional (e.g., poly(methyl methacrylate)) and bulky (e.g., poly(oligo(ethylene glycol) methyl ether methacrylate)) polymers. Importantly, the depolymerization product can be utilized to either reconstruct the linear polymer or create an entirely new insoluble gel that can also be subjected to depolymerization. This work expands the potential of polymers made by controlled radical polymerization, pushes the boundaries of depolymerization, offers intriguing mechanistic aspects, and enables new applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 144, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4678, "End Page": 4684, "Article Number": null, "DOI": "10.1021/jacs.2c00963", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c00963", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776234200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Zhao, W; Li, L; He, N; Chi, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xin; Zhao, Wei; Li, Liang; He, Ning; Chi, ShengWei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling and Application of Process Damping in Milling of Thin-Walled Workpiece Made of Titanium Alloy", "Source Title": "SHOCK AND VIBRATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The modeling as well as application of process damping in milling of thin-walled workpiece made of titanium alloy is investigated. Titanium alloy used commonly in aviation industry is one typical difficult-to-machine material. Chatter usually occurs in cutting of titanium alloy, which results in poor surface quality and damaged tool. Thus, chatter is one important restriction for the quality and efficiency of titanium alloy manufacture, especially for the thin-walled workpiece made of titanium alloy due to poor structural stiffness. Process damping results from interference between flank face and machined surface, which is critical but usually ignored in chatter analysis for difficult-to-machine material. The paper presents one nonlinear dynamic model considering process damping for milling of thin-walled workpiece made of titanium alloy and designs antivibration clearance angle to suppress chatter based on the model. The experimental and computational results indicate that the presented methods for chatter stability analysis are reasonable, and the antivibration clearance angle designed is effective in suppressing chatter and improving machining quality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 2015, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 431476, "DOI": "10.1155/2015/431476", "DOI Link": "http://dx.doi.org/10.1155/2015/431476", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348793200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gholami, P; Dinpazhoh, L; Khataee, A; Orooji, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gholami, Peyman; Dinpazhoh, Laleh; Khataee, Alireza; Orooji, Yasin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sonocatalytic activity of biochar-supported ZnO nullorods in degradation of gemifloxacin: Synergy study, effect of parameters and phytotoxicity evaluation", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study focuses on the facile preparation of ZnO-biochar (ZnO-BC) nullocomposite prepared by the hydrothermal approach as an efficient sonocatalyst for degradation and mineralization of gemifloxacin (GMF). Morphological and textural characteristics of bare biochar (BC), ZnO nullorods (ZnO NRs) and ZnO-BC nullo composite were investigated using TEM, SEM and BET analyses. Moreover, XRD, FTIR, EDX and UV vis DRS analyses were performed to study the crystalline structure, functional groups, elemental composition and optical properties of the samples, respectively. ZnO-BC nullocomposite showed better sonocatalytic performance than BC and ZnO NRs owing to its huge surface area, narrow band gap and enhanced sonoluminescence phenomenon. These properties led to the synergetic ability of ultrasonic irradiation and catalytic activity of ZnO-BC to generate reactive species and subsequent radical reactions. In addition, the effect of the addition of various gases and scavengers on the removal of GMF was evaluated. The GC MS analysis was used to verify the generation of some intermediates and a possible pathway was proposed accordingly. 83.7% COD removal efficiency was observed within 90 min treatment confirming efficient mineralization of GMF solution. The phytotoxicity test was carried out using Lerma minor and the results proved that after the treatment process, a considerable toxicity removal of the GMF solution had occured.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 55, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 44, "End Page": 56, "Article Number": null, "DOI": "10.1016/j.ultsonch.2019.03.001", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2019.03.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470047800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZZ; Yu, CH; Buehler, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zhenze; Yu, Chi-Hua; Buehler, Markus J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep learning model to predict complex stress and strain fields in hierarchical composites", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials-by-design is a paradigm to develop previously unknown high-performance materials. However, finding materials with superior properties is often computationally or experimentally intractable because of the astronomical number of combinations in design space. Here we report an AI-based approach, implemented in a game theory-based conditional generative adversarial neural network (cGAN), to bridge the gap between a material's microstructure-the design space-and physical performance. Our end-to-end deep learning model predicts physical fields like stress or strain directly from the material microstructure geometry, and reaches an astonishing accuracy not only for predicted field data but also for derivative material property predictions. Furthermore, the proposed approach offers extensibility by predicting complex materials behavior regardless of component shapes, boundary conditions, and geometrical hierarchy, providing perspectives of performing physical modeling and simulations. The method vastly improves the efficiency of evaluating physical properties of hierarchical materials directly from the geometry of its structural makeup.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 7, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabd7416", "DOI": "10.1126/sciadv.abd7416", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abd7416", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642446300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jariwala, S; Sun, HY; Adhyaksa, GWP; Lof, A; Muscarella, LA; Ehrler, B; Garnett, EC; Ginger, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jariwala, Sarthak; Sun, Hongyu; Adhyaksa, Gede W. P.; Lof, Andries; Muscarella, Loreta A.; Ehrler, Bruno; Garnett, Erik C.; Ginger, David S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Local Crystal Misorientation Influences Non-radiative Recombination in Halide Perovskites", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use ultrasensitive electron backscatter diffraction (EBSD) to map the local crystal orientations, grains, and grain boundaries in CH3NH3PbI3 (MAPI) perovskite thin films. Although the true grain structure is broadly consistent with the morphology visible in scanning electron microscopy (SEM), the inverse pole figure maps taken with EBSD reveal grain structure and internal misorientation that is otherwise hidden. Local crystal misorientation is consistent with the presence of local strain, which varies from one grain to the next. We acquire co-aligned confocal optical photoluminescence (PL) microscopy images on the same MAPI samples used for EBSD. We correlate optical and EBSD data, showing that PL is anticorrelated with the local grain orientation spread, suggesting that grains with higher degrees of crystalline orientational heterogeneity (local strain) exhibit more non-radiative recombination. We find that larger grains tend to have larger grain orientation spread, consistent with higher degrees of strain and non-radiative recombination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3048, "End Page": 3060, "Article Number": null, "DOI": "10.1016/j.joule.2019.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503428000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jones, TW; Osherov, A; Alsari, M; Sponseller, M; Duck, BC; Jung, YK; Settens, C; Niroui, F; Brenes, R; Stan, CV; Li, Y; Abdi-Jalebi, M; Tamura, N; Macdonald, JE; Burghammer, M; Friend, RH; Bulovic, V; Walsh, A; Wilson, GJ; Lilliu, S; Stranks, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jones, Timothy W.; Osherov, Anna; Alsari, Mejd; Sponseller, Melany; Duck, Benjamin C.; Jung, Young-Kwang; Settens, Charles; Niroui, Farnaz; Brenes, Roberto; Stan, Camelia V.; Li, Yao; Abdi-Jalebi, Mojtaba; Tamura, Nobumichi; Macdonald, J. Emyr; Burghammer, Manfred; Friend, Richard H.; Bulovic, Vladimir; Walsh, Aron; Wilson, Gregory J.; Lilliu, Samuele; Stranks, Samuel D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice strain causes non-radiative losses in halide perovskites", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskites are promising semiconductors for inexpensive, high-performance optoelectronics. Despite a remarkable defect tolerance compared to conventional semiconductors, perovskite thin films still show substantial microscale heterogeneity in key properties such as luminescence efficiency and device performance. However, the origin of the variations remains a topic of debate, and a precise understanding is critical to the rational design of defect management strategies. Through a multi-scale investigation - combining correlative synchrotron scanning X-ray diffraction and time-resolved photoluminescence measurements on the same scan area - we reveal that lattice strain is directly associated with enhanced defect concentrations and non-radiative recombination. The strain patterns have a complex heterogeneity across multiple length scales. We propose that strain arises during the film growth and crystallization and provides a driving force for defect formation. Our work sheds new light on the presence and influence of structural defects in halide perovskites, revealing new pathways to manage defects and eliminate losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 596, "End Page": 606, "Article Number": null, "DOI": "10.1039/c8ee02751j", "DOI Link": "http://dx.doi.org/10.1039/c8ee02751j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459741700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mutailipu, M; Zhang, M; Wu, HP; Yang, ZH; Shen, YH; Sun, JL; Pan, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mutailipu, Miriding; Zhang, Min; Wu, Hongping; Yang, Zhihua; Shen, Yihan; Sun, Junliang; Pan, Shilie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ba3Mg3(BO3)3F3 polymorphs with reversible phase transition and high performances as ultraviolet nonlinear optical materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonlinear optical (NLO) materials are the vital components of future photoelectric technologies as they can broaden the tunable wavelength range supplied by common laser sources. However, the necessary prerequisites for a practical NLO material are rather strict. Accordingly, considerable efforts have been focused on finding potential NLO materials. Here we report two asymmetric beryllium-free borates Pna2(1)- and P (6) over bar 2m-Ba3Mg3(BO3)(3)F-3 featuring NLO-favorable (2)(infinity)[Mg3O2F3(BO3)(2)] layered structures. The reversible phase transition among two polymorphs was demonstrated by multiple experimental tests. The optical measurements reveal that Pna2(1)-Ba3Mg3(BO3)(3)F-3 possesses the optical properties required for ultraviolet NLO applications. Remarkably, Pna2(1)-Ba(3)Mg3(BO3)(3)F-3 has a large laser damage threshold, a deep-ultraviolet cutoff edge, a favorable anisotropic thermal expansion as well as the capacity of insolubility in water. These optical properties can be comparable or superior to that of commercial NLO material beta-BaB2O4, which make Pna2(1)-Ba3Mg3(BO3)(3)F-3 a promising ultraviolet NLO material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3089, "DOI": "10.1038/s41467-018-05575-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05575-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440777000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Draguta, S; Sharia, O; Yoon, SJ; Brennull, MC; Morozov, YV; Manser, JM; Kamat, PV; Schneider, WF; Kuno, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Draguta, Sergiu; Sharia, Onise; Yoon, Seog Joon; Brennull, Michael C.; Morozov, Yurii V.; Manser, Joseph M.; Kamat, Prashant V.; Schneider, William F.; Kuno, Masaru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationalizing the light-induced phase separation of mixed halide organic-inorganic perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixed halide hybrid perovskites, CH3NH3Pb(I1-xBrx)(3), represent good candidates for low-ost, high efficiency photovoltaic, and light-emitting devices. Their band gaps can be tuned from 1.6 to 2.3 eV, by changing the halide anion identity. Unfortunately, mixed halide perovskites undergo phase separation under illumination. This leads to iodide-and bromide-rich domains along with corresponding changes to the material's optical/electrical response. Here, using combined spectroscopic measurements and theoretical modeling, we quantitatively rationalize all microscopic processes that occur during phase separation. Our model suggests that the driving force behind phase separation is the bandgap reduction of iodide-rich phases. It additionally explains observed non-linear intensity dependencies, as well as self-limited growth of iodide-rich domains. Most importantly, our model reveals that mixed halide perovskites can be stabilized against phase separation by deliberately engineering carrier diffusion lengths and injected carrier densities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 450, "Times Cited, All Databases": 485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 200, "DOI": "10.1038/s41467-017-00284-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00284-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406948000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Whitfield, PS; Herron, N; Guise, WE; Page, K; Cheng, YQ; Milas, I; Crawford, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Whitfield, P. S.; Herron, N.; Guise, W. E.; Page, K.; Cheng, Y. Q.; Milas, I.; Crawford, M. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have examined the crystal structures and structural phase transitions of the deuterated, partially deuterated and hydrogenous organic-inorganic hybrid perovskite methyl ammonium lead iodide (MAPbI(3)) using time-of-flight neutron and synchrotron X-ray powder diffraction. Near 330 K the high temperature cubic phases transformed to a body-centered tetragonal phase. The variation of the order parameter Q for this transition scaled with temperature T as Q similar to (T-c-T)(beta), where T-c is the critical temperature and the exponent beta was close to 1/4, as predicted for a tricritical phase transition. However, we also observed coexistence of the cubic and tetragonal phases over a range of temperature in all cases, demonstrating that the phase transition was in fact first-order, although still very close to tricritical. Upon cooling further, all the tetragonal phases transformed into a low temperature orthorhombic phase around 160 K, again via a first-order phase transition. Based upon these results, we discuss the impact of the structural phase transitions upon photovoltaic performance of MAPbI(3) based solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 454, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35685, "DOI": "10.1038/srep35685", "DOI Link": "http://dx.doi.org/10.1038/srep35685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385830600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xi, W; Lee, YJ; Yu, SL; Chen, ZH; Shiomi, J; Kim, SK; Hu, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xi, Wang; Lee, Yun-Jo; Yu, Shilv; Chen, Zihe; Shiomi, Junichiro; Kim, Sun-Kyung; Hu, Run", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh-efficient material informatics inverse design of thermal metamaterials for visible-infrared-compatible camouflage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multispectral camouflage technologies, especially in the most frequently-used visible and infrared (VIS-IR) bands, are in increasing demand for the ever-growing multispectral detection technologies. Nevertheless, the efficient design of proper materials and structures for VIS-IR camouflage is still challenging because of the stringent requirement for selective spectra in a large VIS-IR wavelength range and the increasing demand for flexible color and infrared signal adaptivity. Here, a material-informatics-based inverse design framework is proposed to efficiently design multilayer germanium (Ge) and zinc sulfide (ZnS) metamaterials by evaluating only similar to 1% of the total candidates. The designed metamaterials exhibit excellent color matching and infrared camouflage performance from different observation angles and temperatures through both simulations and infrared experiments. The present material informatics inverse design framework is highly efficient and can be applied to other multi-objective optimization problems beyond multispectral camouflage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4694, "DOI": "10.1038/s41467-023-40350-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40350-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042606700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "González-Hernández, R; Smejkal, L; Vyborny, K; Yahagi, Y; Sinova, J; Jungwirth, T; Zelezny, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonzalez-Hernulldez, Rafael; Smejkal, Libor; Vyborny, Karel; Yahagi, Yuta; Sinova, Jairo; Jungwirth, Tomas; Zelezny, Jakub", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Electrical Spin Splitter Based on Nonrelativistic Collinear Antiferromagnetism", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-current generation by electrical means is among the core phenomena driving the field of spintronics. Using ab initio calculations we show that a room-temperature metallic collinear antiferro-magnet RuO2 allows for highly efficient spin-current generation, arising from anisotropically spin-split bands with conserved up and down spins along the Neel vector axis. The zero net moment antiferromagnet acts as an electrical spin splitter with a 34 degrees propagation angle between spin-up and spin-down currents. The corresponding spin conductivity is a factor of 3 larger than the record value from a survey of 20 000 nonmagnetic spin-Hall materials. We propose a versatile spin-splitter-torque concept circumventing limitations of spin-transfer and spin-orbit torques in present magnetic memory devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 26", "Publication Year": 2021, "Volume": 126, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127701, "DOI": "10.1103/PhysRevLett.126.127701", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.127701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000646119900021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bustamante-Torres, M; Romero-Fierro, D; Arcentales-Vera, B; Palomino, K; Magana, H; Bucio, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bustamante-Torres, Moises; Romero-Fierro, David; Arcentales-Vera, Belen; Palomino, Kenia; Magana, Hector; Bucio, Emilio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogels Classification According to the Physical or Chemical Interactions and as Stimuli-Sensitive Materials", "Source Title": "GELS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are attractive biomaterials with favorable characteristics due to their water uptake capacity. However, hydrogel properties are determined by the cross-linking degree and nature, the tacticity, and the crystallinity of the polymer. These biomaterials can be sorted out according to the internal structure and by their response to external factors. In this case, the internal interaction can be reversible when the internal chains are led by physicochemical interactions. These physical hydrogels can be synthesized through several techniques such as crystallization, amphiphilic copolymers, charge interactions, hydrogen bonds, stereo-complexing, and protein interactions. In contrast, the internal interaction can be irreversible through covalent cross-linking. Synthesized hydrogels by chemical interactions present a high cross-linking density and are employed using graft copolymerization, reactive functional groups, and enzymatic methods. Moreover, specific smart hydrogels have also been denoted by their external response, pH, temperature, electric, light, and enzyme. This review deeply details the type of hydrogel, either the internal structure or the external response. Furthermore, we detail some of the main applications of these hydrogels in the biomedicine field, such as drug delivery systems, scaffolds for tissue engineering, actuators, biosensors, and many other applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 182, "DOI": "10.3390/gels7040182", "DOI Link": "http://dx.doi.org/10.3390/gels7040182", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737796700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Juarez-Perez, EJ; Ono, LK; Maeda, M; Jiang, Y; Hawash, Z; Qi, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Juarez-Perez, Emilio J.; Ono, Luis K.; Maeda, Maki; Jiang, Yan; Hawash, Zafer; Qi, Yabing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photodecomposition and thermal decomposition in methylammonium halide lead perovskites and inferred design principles to increase photovoltaic device stability", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid lead halide perovskites have emerged as promising active materials for photovoltaic cells. Although superb efficiencies have been achieved, it is widely recognized that long-term stability is a key challenge intimately determining the future development of perovskite-based photovoltaic technology. Herein, we present reversible and irreversible photodecomposition reactions of methylammonium lead iodide (MAPbI(3)). Simulated sunlight irradiation and temperature (40-80 degrees C) corresponding to solar cell working conditions lead to three degradation pathways: (1) CH3NH2 + HI (identified as the reversible path), (2) NH3 + CH3I (the irreversible or detrimental path), and (3) a reversible Pb(0) + I-2(g) photodecomposition reaction. If only the reversible reactions (1) and (3) take place and reaction (2) can be avoided, encapsulated MAPbI(3) can be regenerated during the off-illumination timeframe. Therefore, to further improve operational stability in hybrid perovskite solar cells, detailed understanding of how to mitigate photodegradation and thermal degradation processes is necessary. First, encapsulation of the device is necessary not only to avoid contact of the perovskite with ambient air, but also to prevent leakage of volatile products released from the perovskite. Second, careful selection of the organic cations in the compositional formula of the perovskite is necessary to avoid irreversible reactions. Third, selective contacts must be as chemically inert as possible toward the volatile released products. Finally, hybrid halide perovskite materials are speculated to undergo a dynamic formation and decomposition process; this can gradually decrease the crystalline grain size of the perovskite with time; therefore, efforts to deposit highly crystalline perovskites with large crystal sizes may fail to increase the long-term stability of photovoltaic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 512, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2018, "Volume": 6, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9604, "End Page": 9612, "Article Number": null, "DOI": "10.1039/c8ta03501f", "DOI Link": "http://dx.doi.org/10.1039/c8ta03501f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433427300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ermolaev, GA; Grudinin, DV; Stebunov, YV; Voronin, KV; Kravets, VG; Duan, J; Mazitov, AB; Tselikov, GI; Bylinkin, A; Yakubovsky, DI; Novikov, SM; Baranov, DG; Nikitin, AY; Kruglov, IA; Shegai, T; Alonso-González, P; Grigorenko, AN; Arsenin, AV; Novoselov, KS; Volkov, VS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ermolaev, G. A.; Grudinin, D., V; Stebunov, Y., V; Voronin, K. V.; Kravets, V. G.; Duan, J.; Mazitov, A. B.; Tselikov, G., I; Bylinkin, A.; Yakubovsky, D., I; Novikov, S. M.; Baranov, D. G.; Nikitin, A. Y.; Kruglov, I. A.; Shegai, T.; Alonso-Gonzalez, P.; Grigorenko, A. N.; Arsenin, A., V; Novoselov, K. S.; Volkov, V. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant optical anisotropy in transition metal dichalcogenides for next-generation photonics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large optical anisotropy observed in a broad spectral range is of paramount importance for efficient light manipulation in countless devices. Although a giant anisotropy has been recently observed in the mid-infrared wavelength range, for visible and near-infrared spectral intervals, the problem remains acute with the highest reported birefringence values of 0.8 in BaTiS3 and h-BN crystals. This issue inspired an intensive search for giant optical anisotropy among natural and artificial materials. Here, we demonstrate that layered transition metal dichalcogenides (TMDCs) provide an answer to this quest owing to their fundamental differences between intralayer strong covalent bonding and weak interlayer van der Waals interaction. To do this, we made correlative far- and near-field characterizations validated by first-principle calculations that reveal a huge birefringence of 1.5 in the infrared and 3 in the visible light for MoS2. Our findings demonstrate that this remarkable anisotropy allows for tackling the diffraction limit enabling an avenue for on-chip next-generation photonics. Optical anisotropy in a broad spectral range is pivotal to efficient light manipulation. Here, the authors measure a birefringence of 1.5 in the infrared range and 3 in the visible light for MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 854, "DOI": "10.1038/s41467-021-21139-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21139-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625204500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, YX; Rahul, AV; Mohan, MK; De Schutter, G; Van Tittelboom, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Yaxin; Rahul, A. V.; Mohan, Manu K.; De Schutter, Geert; Van Tittelboom, Kim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent progress and technical challenges in using calcium sulfoaluminate (CSA) cement", "Source Title": "CEMENT & CONCRETE COMPOSITES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Calcium sulfoaluminate (CSA) cement can be used as a replacement for Portland cement to reduce CO2 emis-sions. However, the performance of CSA cement remains unknown with regard to its hydration mechanism, mechanical and long-term performance. Therefore, it would be beneficial to consolidate the literature on CSA cement to facilitate its use in the construction industry. To this end, recent progress and technical challenges of using CSA cement are discussed in this paper. We begin with the introduction of the different types of CSA cement and the manufacturing process. This is followed by a detailed discussion on the hydration mechanisms and phase assemblage, mechanical performance, and long-term durability of CSA cement. Finally, the applica-tions of CSA cement are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 137, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104908, "DOI": "10.1016/j.cemconcomp.2022.104908", "DOI Link": "http://dx.doi.org/10.1016/j.cemconcomp.2022.104908", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961260900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hendon, CH; Rieth, AJ; Korzynski, MD; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hendon, Christopher H.; Rieth, Adam J.; Korzynski, Maciej D.; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grand Challenges and Future Opportunities for Metal-Organic Frameworks", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) allow compositional and structural diversity beyond conventional solid-state materials. Continued interest in the field is justified by potential applications of exceptional breadth, ranging from gas storage and separation, which takes advantage of the inherent pores and their volume, to electronic applications, which requires precise control of electronic structure. In this Outlook we present some of the pertinent challenges that MOFs face in their conventional implementations, as well as opportunities in less traditional areas. Here the aim is to discuss select design concepts and future research goals that emphasize nuances relevant to this class of materials as a whole. Particular emphasis is placed on synthetic aspects, as they influence the potential for MOFs in gas separation, electrical conductivity, and catalytic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 554, "End Page": 563, "Article Number": null, "DOI": "10.1021/acscentsci.7b00197", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00197", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404825000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Masi, F; Stefanou, I; Vannucci, P; Maffi-Berthier, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Masi, Filippo; Stefanou, Ioannis; Vannucci, Paolo; Maffi-Berthier, Victor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamics-based Artificial Neural Networks for constitutive modeling", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine Learning methods and, in particular, Artificial Neural Networks (ANNs) have demonstrated promising capabilities in material constitutive modeling. One of the main drawbacks of such approaches is the lack of a rigorous frame based on the laws of physics. This may render physically inconsistent the predictions of a trained network, which can be even dangerous for real applications. Here we propose a new class of data-driven, physics-based, neural networks for constitutive modeling of strain rate independent processes at the material point level, which we define as Thermodynamics-based Artificial Neural Networks (TANNs). The two basic principles of thermodynamics are encoded in the network's architecture by taking advantage of automatic differentiation to compute the numerical derivatives of a network with respect to its inputs. In this way, derivatives of the free-energy, the dissipation rate and their relation with the stress and internal state variables are hardwired in the architecture of TANNs. Consequently, our approach does not have to identify the underlying pattern of thermodynamic laws during training, reducing the need of large data-sets. Moreover the training is more efficient and robust, and the predictions more accurate. Finally and more important, the predictions remain thermodynamically consistent, even for unseen data. Based on these features, TANNs are a starting point for data-driven, physics-based constitutive modeling with neural networks. We demonstrate the wide applicability of TANNs for modeling elasto-plastic materials, using both hyperand hypo-plasticity models. Strain hardening and softening are also considered for the hyper-plastic scenario. Detailed comparisons show that the predictions of TANNs outperform those of standard ANNs. Finally, we demonstrate that the implementation of the laws of thermodynamics confers to TANNs high robustness in the presence of noise in the training data, compared to standard approaches. TANNs' architecture is general, enabling applications to materials with different or more complex behavior, without any modification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 147, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104277, "DOI": "10.1016/j.jmps.2020.104277", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2020.104277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612236600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, SX; Ta, N; Wang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Shi-Xiang; Ta, Na; Wang, Xu-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Temperature on the Structural and Physicochemical Properties of Biochar with Apple Tree Branches as Feedstock Material", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this study was to study the structure and physicochemical properties of biochar derived from apple tree branches (ATBs), whose valorization is crucial for the sustainable development of the apple industry. ATBs were collected from apple orchards located on the Weibei upland of the Loess Plateau and pyrolyzed at 300, 400, 500 and 600 degrees C (BC300, BC400, BC500 and BC600), respectively. Different analytical techniques were used for the characterization of the different biochars. In particular, proximate and element analyses were performed. Furthermore, the morphological, and textural properties were investigated using scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, Boehm titration and nitrogen manometry. In addition, the thermal stability of biochars was also studied by thermogravimetric analysis. The results indicated that the increasing temperature increased the content of fixed carbon (C), the C content and inorganic minerals (K, P, Fe, Zn, Ca, Mg), while the yield, the content of volatile matter (VM), O and H, cation exchange capacity, and the ratios of O/C and H/C decreased. Comparison between the different samples show that highest pH and ash content were observed in BC500. The number of acidic functional groups decreased as a function of pyrolysis temperature, especially for the carboxylic functional groups. In contrast, a reverse trend was found for the basic functional groups. At a higher temperature, the brunauer-emmett-teller (BET) surface area and pore volume are higher mostly due to the increase of the micropore surface area and micropore volume. In addition, the thermal stability of biochars also increased with the increasing temperature. Hence, pyrolysis temperature has a strong effect on biochar properties, and therefore biochars can be produced by changing pyrolysis temperature in order to better meet their applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1293, "DOI": "10.3390/en10091293", "DOI Link": "http://dx.doi.org/10.3390/en10091293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411225200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eriksen, MK; Christiansen, JD; Daugaard, AE; Astrup, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eriksen, M. K.; Christiansen, J. D.; Daugaard, A. E.; Astrup, T. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Closing the loop for PET, PE and PP waste from households: Influence of material properties and product design for plastic recycling", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recycling of plastic is an important step towards circular economy. However, plastic from household waste (HHW) is a heterogeneous and contaminated resource, leading to recycled plastic with reduced quality, limiting the potential for closed-loop recycling. In addition to regulatory requirements for the chemical composition of recycled plastic, reduced physical and mechanical properties may limit the potential for closed-loop recycling. Consequently, this study analyses the thermal degradation, processability and mechanical properties of a range of reprocessed PET, PE and PP samples from source-separated plastic in HHW. On this basis, the potential for closed-loop recycling is evaluated. The study demonstrated that PET, PE and PP recycling represent different challenges. Potential degradation of the PET polymer can be reversed in a decontamination process, making PET waste well-suited for closed-loop, multiple times recycling, even when the degree of heterogeneity in the waste is high. The processability of different kinds of PE and PP packaging types varied considerably, especially for PP. Consequently, current recycling of mixed PP waste and even separate recycling of individual PP waste packaging types, will not technically facilitate recycling into new packaging products. This highlights the importance of PE and PP waste homogeneity when sent to reprocessing. Such homogeneity may be achieved through additional plastic sorting and regulatory harmonisation of product design, accounting for polymer properties and recyclability. Degradation of PP during recycling was shown to be substantial, representing another important limitation for PP recycling, necessary to address in the future. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2019, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 75, "End Page": 85, "Article Number": null, "DOI": "10.1016/j.wasman.2019.07.005", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2019.07.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482245200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JF; Gao, JC; Li, WM; Qian, YT; Shen, XD; Wang, X; Shen, X; Hu, ZW; Dong, C; Huang, QZ; Cao, LP; Li, Z; Zhang, J; Ren, CW; Duan, L; Liu, QQ; Yu, RC; Ren, Y; Weng, SC; Lin, HJ; Chen, CT; Tjeng, LH; Long, YW; Deng, Z; Zhu, JL; Wang, XC; Weng, HM; Yu, RZ; Greenblatt, M; Jin, CQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Jianfa; Gao, Jiacheng; Li, Wenmin; Qian, Yuting; Shen, Xudong; Wang, Xiao; Shen, Xi; Hu, Zhiwei; Dong, Cheng; Huang, Qingzhen; Cao, Lipeng; Li, Zhi; Zhang, Jun; Ren, Chongwen; Duan, Lei; Liu, Qingqing; Yu, Richeng; Ren, Yang; Weng, Shih-Chang; Lin, Hong-Ji; Chen, Chien-Te; Tjeng, Liu-Hao; Long, Youwen; Deng, Zheng; Zhu, Jinlong; Wang, Xiancheng; Weng, Hongming; Yu, Runze; Greenblatt, Martha; Jin, Changqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A combinatory ferroelectric compound bridging simple ABO3 and A-site-ordered quadruple perovskite", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The simple ABO(3) and A-site-ordered AA ' 3B4O12 perovskites represent two types of classical perovskite functional materials. There are well-known simple perovskites with ferroelectric properties, while there is still no report of ferroelectricity due to symmetry breaking transition in A-site-ordered quadruple perovskites. Here we report the high pressure synthesis of an A-site-ordered perovskite PbHg3Ti4O12, the only known quadruple perovskite that transforms from high-temperature centrosymmetric paraelectric phase to low-temperature non-centrosymmetric ferroelectric phase. The coordination chemistry of Hg2+ is changed from square planar as in typical A-site-ordered quadruple perovskite to a rare stereo type with 8 ligands in PbHg3Ti4O12. Thus PbHg3Ti4O12 appears to be a combinatory link from simple ABO(3) perovskites to A-site-ordered AA ' 3Ti4O12 perovskites, sharing both displacive ferroelectricity with former and structure coordination with latter. This is the only example so far showing ferroelectricity due to symmetry breaking phase transition in AA ' 3B4O12-type A-site-ordered perovskites, and opens a direction to search for ferroelectric materials. There are few reports of ferroelectricity due to symmetry breaking transition in A-site-ordered quadruple perovskites. Here, the authors find one with phase transition from a high-temperature centrosymmetric paraelectric phase to a low-temperature non-centrosymmetric ferroelectric phase in a high pressure synthesized compound.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 747, "DOI": "10.1038/s41467-020-20833-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20833-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617063000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, HB; Banerjee, A; Yan, JQ; Bridges, CA; Lumsden, MD; Mandrus, DG; Tennullt, DA; Chakoumakos, BC; Nagler, SE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, H. B.; Banerjee, A.; Yan, J. -Q.; Bridges, C. A.; Lumsden, M. D.; Mandrus, D. G.; Tennullt, D. A.; Chakoumakos, B. C.; Nagler, S. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-temperature crystal and magnetic structure of α-RuCl3", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals of the Kitaev spin-liquid candidate alpha-RuCl3 have been studied to determine the low-temperature bulk properties, the structure, and the magnetic ground state. Refinements of x-ray diffraction data show that the low-temperature crystal structure is described by space group C2/m with a nearly perfect honeycomb lattice exhibiting less than 0.2% in-plane distortion. The as-grown single crystals exhibit only one sharp magnetic transition at T-N = 7K. The magnetic order belowthis temperature exhibits a propagation vector of k = (0,1,1/3), which coincides with a three-layer stacking of the C2/m unit cells. Magnetic transitions at higher temperatures up to 14 K can be introduced by deformations of the crystal that result in regions in the crystal with a two-layer stacking sequence. The best-fit symmetry-allowed magnetic structure of the as-grown crystals shows that the spins lie in the ac plane, with a zigzag configuration in each honeycomb layer. The three-layer repeat out-of-plane structure can be refined as a 120 degrees spiral order or a collinear structure with a spin direction of 35 degrees away from the a axis. The collinear spin configuration yields a slightly better fit and also is physically preferred. The average ordered moment in either structure is less than 0.45(5) mu(B) per Ru3+ ion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2016, "Volume": 93, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134423, "DOI": "10.1103/PhysRevB.93.134423", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.134423", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374528700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Y; Chi, YD; Hong, YY; Li, YB; Yang, S; Yin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yao; Chi, Yinding; Hong, Yaoye; Li, Yanbin; Yang, Shu; Yin, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Twisting for soft intelligent autonomous robot in unstructured environments", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft robots that can harvest energy from environmental resources for autonomous locomotion is highly desired; however, few are capable of adaptive navigation without human interventions. Here, we report twisting soft robots with embodied physical intelligence for adaptive, intelligent autonomous locomotion in various unstructured environments, without on-board or external controls and human interventions. The soft robots are constructed of twisted thermal-responsive liquid crystal elastomer ribbons with a straight centerline. They can harvest thermal energy from environments to roll on outdoor hard surfaces and challenging granular substrates without slip, including ascending loose sandy slopes, crossing sand ripples, escaping from burying sand, and crossing rocks with additional camouflaging features. The twisting body provides anchoring functionality by burrowing into loose sand. When encountering obstacles, they can either self-turn or self-snap for obstacle negotiation and avoidance. Theoretical models and finite element simulation reveal that such physical intelligence is achieved by spontaneously snapping-through its soft body upon active and adaptive soft body-obstacle interactions. Utilizing this strategy, they can intelligently escape from confined spaces and maze-like obstacle courses without any human intervention. This work presents a de novo design of embodied physical intelligence by harnessing the twisting geometry and snap-through instability for adaptive soft robot-environment interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2022, "Volume": 119, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2200265119", "DOI": "10.1073/pnas.2200265119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2200265119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001051437000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brando, M; Belitz, D; Grosche, FM; Kirkpatrick, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brando, M.; Belitz, D.; Grosche, F. M.; Kirkpatrick, T. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic quantum ferromagnets", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An overview of quantum phase transitions (QPTs) in metallic ferromagnets, discussing both experimental and theoretical aspects, is given. These QPTs can be classified with respect to the presence and strength of quenched disorder: Clean systems generically show a discontinuous, or first-order, QPT from a ferromagnetic to a paramagnetic state as a function of some control parameter, as predicted by theory. Disordered systems are much more complicated, depending on the disorder strength and the distance from the QPT. In many disordered materials the QPT is continuous, or second order, and Griffiths-phase effects coexist with QPT singularities near the transition. In other systems the transition from the ferromagnetic state at low temperatures is to a different type of long-range order, such as an antiferromagnetic or a spin-density-wave state. In still other materials a transition to a state with glasslike spin dynamics is suspected. The review provides a comprehensive discussion of the current understanding of these various transitions and of the relation between experiment and theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2016, "Volume": 88, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25006, "DOI": "10.1103/RevModPhys.88.025006", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.88.025006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376927900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoshida, M; Katsuno, S; Inoue, T; Gelleta, J; Izumi, K; De Zoysa, M; Ishizaki, K; Noda, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoshida, Masahiro; Katsuno, Shumpei; Inoue, Takuya; Gelleta, John; Izumi, Koki; De Zoysa, Menaka; Ishizaki, Kenji; Noda, Susumu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-brightness scalable continuous-wave single-mode photonic-crystal laser", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing large-scale single-mode, high-power, high-beam-quality semiconductor lasers, which rival (or even replace) bulky gas and solid-state lasers, is one of the ultimate goals of photonics and laser physics. Conventional high-power semiconductor lasers, however, inevitably suffer from poor beam quality owing to the onset of many-mode oscillation1,2, and, moreover, the oscillation is destabilized by disruptive thermal effects under continuous-wave (CW) operation3,4. Here, we surmount these challenges by developing large-scale photonic-crystal surface-emitting lasers with controlled Hermitian and non-Hermitian couplings inside the photonic crystal and a pre-installed spatial distribution of the lattice constant, which maintains these couplings even under CW conditions. A CW output power exceeding 50 W with purely single-mode oscillation and an exceptionally narrow beam divergence of 0.05 degrees has been achieved for photonic-crystal surface-emitting lasers with a large resonullt diameter of 3 mm, corresponding to over 10,000 wavelengths in the material. The brightness, a figure of merit encapsulating both output power and beam quality, reaches 1 GW cm(-2) sr(-1), which rivals those of existing bulky lasers. Our work is an important milestone toward the advent of single-mode 1-kW-class semiconductor lasers, which are expected to replace conventional, bulkier lasers in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2023, "Volume": 618, "Issue": 7966, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 727, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06059-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06059-8", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001010613600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, QY; Wang, CH; Guo, YY; Xiao, YH; Tan, XH; Chen, JP; He, WD; Li, Y; Cui, H; Wang, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Qiuyan; Wang, Chenhui; Guo, Yingying; Xiao, Yuhang; Tan, Xiaohong; Chen, Jianpo; He, Weidong; Li, Yan; Cui, Hao; Wang, Chengxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Axial Oxygen Ligands Regulating Electronic and Geometric Structure of Zn-N-C Sites to Boost Oxygen Reduction Reaction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn-N-C possesses the intrinsic inertia for Fenton-like reaction and can retain robust durability in harsh circumstance, but it is often neglected in oxygen reduction reaction (ORR) because of its poor catalytic activity. Zn is of fully filled 3d(10)4s(2) configuration and is prone to evaporation, making it difficult to regulate the electronic and geometric structure of Zn center. Here, guided by theoretical calculations, five-fold coordinated single-atom Zn sites with four in-plane N ligands is constructed and one axial O ligand (Zn-N-4-O) by ionic liquid-assisted molten salt template method. Additional axial O not only triggers a geometry transformation from the planar structure of Zn-N-4 to the non-planar structure of Zn-N-4-O, but also induces the electron transfer from Zn center to neighboring atoms and lower the d-band center of Zn atom, which weakens the adsorption strength of *OH and decreases the energy barrier of rate determining step of ORR. Consequently, the Zn-N-4-O sites exhibit improved ORR activity and excellent methanol tolerance with long-term durability. The Zn-air battery assembled by Zn-N-4-O presents a maximum power density of 182 mW cm(-2) and can operate continuously for over 160 h. This work provides new insights into the design of Zn-based single atom catalysts through axial coordination engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 25", "Publication Year": 2023, "Volume": 10, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302152", "DOI Link": "http://dx.doi.org/10.1002/advs.202302152", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001013057900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tripathi, N; Hills, CD; Singh, RS; Atkinson, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tripathi, Nimisha; Hills, Colin D.; Singh, Raj S.; Atkinson, Christopher J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass waste utilisation in low-carbon products: harnessing a major potential resource", "Source Title": "NPJ CLIMATE AND ATMOSPHERIC SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increasing demand for food and other basic resources from a growing population has resulted in the intensification of agricultural and industrial activities. The wastes generated from agriculture are a burgeoning problem, as their disposal, utilisation and management practices are not efficient or universally applied. Particularly in developing countries, most biomass residues are left in the field to decompose or are burned in the open, resulting in significant environmental impacts. Similarly, with rapid global urbanisation and the rising demand for construction products, alternative sustainable energy sources and raw material supplies are required. Biomass wastes are an under-utilised source of material (for both energy and material generation), and to date, there has been little activity focussing on a 'low-carbon' route for their valorisation. Thus, the present paper attempts to address this by reviewing the global availability of biomass wastes and their potential for use as a feedstock for the manufacture of high-volume construction materials. Although targeted at practitioners in the field of sustainable biomass waste management, this work may also be of interest to those active in the field of carbon emission reductions. We summarise the potential of mitigating CO2 in a mineralisation step involving biomass residues, and the implications for CO2 capture and utilisation (CCU) to produce construction products from both solid and gaseous wastes. This work contributes to the development of sustainable value-added lower embodied carbon products from solid waste. The approach will offer reduced carbon emissions and lower pressure on natural resources (virgin stone, soil etc.).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 337, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2019, "Volume": 2, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35, "DOI": "10.1038/s41612-019-0093-5", "DOI Link": "http://dx.doi.org/10.1038/s41612-019-0093-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Meteorology & Atmospheric Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496231100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalogerakis, N; Karkanorachaki, K; Kalogerakis, GC; Triantafyllidi, EI; Gotsis, AD; Partsinevelos, P; Fava, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalogerakis, Nicolas; Karkanorachaki, Katerina; Kalogerakis, G. Calypso; Triantafyllidi, Elisavet I.; Gotsis, Alexandros D.; Partsinevelos, Panagiotis; Fava, Fabio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microplastics Generation: Onset of Fragmentation of Polyethylene Films in Marine Environment Mesocosms", "Source Title": "FRONTIERS IN MARINE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fragmentation of high-density polyethylene (HDPE) films from single-use supermarket plastic bags to microplastics under laboratory-simulated onshore and nearshore conditions was investigated for a period of 6 months. The weathering process of the plastic strips either on beach sand or in seawater under direct natural sunlight was monitored by tensile strength, molecular weight measurements, FTIR, weight loss, and image processing of photographs of the plastic strips before and after mild mechanical stress was applied. The latter represents a novel method proposed for determining the onset of fragmentation through the application of mild mechanical stress on the weathered plastic samples emulating the action of sand and wind on a beach. It was found that 12 h of application of mild mechanical stress in rotating glass bottles filled partially with sand was sufficient time to reach the maximum degree of fragmentation that could occur for the weathered plastics samples being tested. For example, applied mechanical stress yielded an area loss of almost 14% for samples weathered for a period of 5 months and about 16.7% after 5.5 months. While tensile strength tests and molecular weight measurements were rather inconclusive till the very last month when the onset of fragmentation was identified; FTIR measurements revealed that samples under ultraviolet irradiation were gradually modified chemically until fragmentation commenced. After 6 months of weathering, molecular weight measurements showed a 60% reduction for sample SMB-1 whereas for sample SMB-2 the measurement was not possible due to extensive fragmentation. The onset of fragmentation for SMB-1 and SMB-2 samples occurred at a cumulative luminullce of 5.3 x 10(6) lux.d and in the presence of atmospheric oxygen whereby the polymer films broke down partially to microplastics. When the UV exposure reached 7.2 x 10(6) lux.d the weathered plastic strips broke down fully to microplastics with the application of a mild mechanical stress. Samples placed in seawater proved to be resistant to fragmentation compared to those on sand over the 6-month period of the weathering experiment. The direct implication of this work is that beached macroplastic debris should be regularly collected from the seashore before they are weathered by sunlight and returned to the sea as microplastics by the action of high waves or strong winds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 228, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 84, "DOI": "10.3389/fmars.2017.00084", "DOI Link": "http://dx.doi.org/10.3389/fmars.2017.00084", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457690600084", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, FC; Liang, ZT; Zhao, WA; Zuo, WH; Lin, M; Wu, YQ; Yang, XR; Gong, ZL; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Fucheng; Liang, Ziteng; Zhao, Wengao; Zuo, Wenhua; Lin, Min; Wu, Yuqi; Yang, Xuerui; Gong, Zhengliang; Yang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The nature and suppression strategies of interfacial reactions in all-solid-state batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state Li batteries are promising energy storage devices owing to their high safety and high theoretical energy density. However, the serious interfacial reaction between solid state electrolytes and cathodes deteriorates the battery performance, impeding the realization of long-term cyclability. The buried nature of the interphase layer presents a significant challenge in achieving a comprehensive understanding of the underlying interfacial reaction mechanisms. Herein, we systematically explore the interfacial reaction evolutions and interphase compositions and electronic properties between the popular oxide cathodes and sulfide solid electrolytes (SSEs). This includes analysis of the chemical and electrochemical reactions between cathodes/coatings and SSEs, as well as the electrochemical self-decomposition of SSEs by thermodynamic phase equilibrium analysis. We disclose that the driving force of the electrochemical reaction at the chemical potential of mu(Li) is much stronger than that of the chemical reaction, which dominates the interfacial reaction. Preventing the formation of an electronically conductive interphase is crucial in inhibiting the continuous interfacial degradation during long-term cycling, which can be achieved through the optimized combination of cathodes and SSEs, as well as the introduction of functional coatings between them. Based on these findings, the percentage of molar fraction (f) of electronically conductive species in the formed interphase is proposed as a key factor for indicating the interfacial stability for the first time. Furthermore, we propose a specific high-throughput screening scheme to filter the functional coating materials by comprehensively evaluating their functionality. The tiered screening identifies 48 coating materials with optimal properties. The work highlights the significant roles of rational coupling of the cathodes and SSEs, and optimizing interfacial coating materials for solid-state batteries. It opens new avenues for engineering an interphase with improved interfacial compatibility to realize long-term cyclability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2023, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2579, "End Page": 2590, "Article Number": null, "DOI": "10.1039/d3ee00870c", "DOI Link": "http://dx.doi.org/10.1039/d3ee00870c", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983240800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, TJ; Zhou, CC; Feng, XZ; Dong, NN; Chen, H; Chen, XF; Zhang, L; Lin, J; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Tianju; Zhou, Chaocheng; Feng, Xuezhen; Dong, Ningning; Chen, Hong; Chen, Xianfeng; Zhang, Long; Lin, Jia; Wang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulation of the luminescence mechanism of two-dimensional tin halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) Sn-based perovskites are a kind of non-toxic environment-friendly luminescent material. However, the research on the luminescence mechanism of this type of perovskite is still very controversial, which greatly limits the further improvement and application of the luminescence performance. At present, the focus of controversy is defects and phonon scattering rates. In this work, we combine the organic cation control engineering with temperature-dependent transient absorption spectroscopy to systematically study the interband exciton relaxation pathways in layered A2SnI4 (A = PEA+, BA+, HA+, and OA+) structures. It is revealed that exciton-phonon scattering and exciton-defect scattering have different effects on exciton relaxation. Our study further confirms that the deformation potential scattering by charged defects, not by the non-polar optical phonons, dominates the excitons interband relaxation, which is largely different from the Pb-based perovskites. These results enhance the understanding of the origin of the non-radiative pathway in Sn-based perovskite materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-021-27663-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27663-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028265700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baran, D; Kirchartz, T; Wheeler, S; Dimitrov, S; Abdelsamie, M; Gorman, J; Ashraf, RS; Holliday, S; Wadsworth, A; Gasparini, N; Kaienburg, P; Yan, H; Amassian, A; Brabec, CJ; Durrant, JR; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baran, D.; Kirchartz, T.; Wheeler, S.; Dimitrov, S.; Abdelsamie, M.; Gorman, J.; Ashraf, R. S.; Holliday, S.; Wadsworth, A.; Gasparini, N.; Kaienburg, P.; Yan, H.; Amassian, A.; Brabec, C. J.; Durrant, J. R.; McCulloch, I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced voltage losses yield 10% efficient fullerene free organic solar cells with >1 V open circuit voltages", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optimization of the energy levels at the donor-acceptor interface of organic solar cells has driven their efficiencies to above 10%. However, further improvements towards efficiencies comparable with inorganic solar cells remain challenging because of high recombination losses, which empirically limit the open-circuit voltage (V-oc) to typically less than 1 V. Here we show that this empirical limit can be overcome using non-fullerene acceptors blended with the low band gap polymer PffBT4T-2DT leading to efficiencies approaching 10% (9.95%). We achieve V-oc up to 1.12 V, which corresponds to a loss of only E-g/q - V-oc = 0.5 +/- 0.01 V between the optical bandgap E-g of the polymer and V-oc. This high V-oc is shown to be associated with the achievement of remarkably low non-geminate and non-radiative recombination losses in these devices. Suppression of non-radiative recombination implies high external electroluminescence quantum efficiencies which are orders of magnitude higher than those of equivalent devices employing fullerene acceptors. Using the balance between reduced recombination losses and good photocurrent generation efficiencies achieved experimentally as a baseline for simulations of the efficiency potential of organic solar cells, we estimate that efficiencies of up to 20% are achievable if band gaps and fill factors are further optimized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 466, "Times Cited, All Databases": 499, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3783, "End Page": 3793, "Article Number": null, "DOI": "10.1039/c6ee02598f", "DOI Link": "http://dx.doi.org/10.1039/c6ee02598f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392915500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZP; Wang, TM; Lu, ZG; Jin, CH; Chen, YW; Meng, YZ; Lian, Z; Taniguchi, T; Watanabe, K; Zhang, SB; Smirnov, D; Shi, SF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhipeng; Wang, Tianmeng; Lu, Zhengguang; Jin, Chenhao; Chen, Yanwen; Meng, Yuze; Lian, Zhen; Taniguchi, Takashi; Watanabe, Kenji; Zhang, Shengbai; Smirnov, Dmitry; Shi, Su-Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the biexciton and trion-exciton complexes in BN encapsulated WSe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strong Coulomb interactions in single-layer transition metal dichalcogenides (TMDs) result in the emergence of strongly bound excitons, trions, and biexcitons. These excitonic complexes possess the valley degree of freedom, which can be exploited for quantum optoelectronics. However, in contrast to the good understanding of the exciton and trion properties, the binding energy of the biexciton remains elusive, with theoretical calculations and experimental studies reporting discrepant results. In this work, we resolve the conflict by employing low-temperature photoluminescence spectroscopy to identify the biexciton state in BN-encapsulated single-layer WSe2. The biexciton state only exists in charge-neutral WSe2, which is realized through the control of efficient electrostatic gating. In the lightly electron-doped WSe2, one free electron binds to a biexciton and forms the trion-exciton complex. Improved understanding of the biexciton and trion-exciton complexes paves the way for exploiting the many-body physics in TMDs for novel optoelectronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3719, "DOI": "10.1038/s41467-018-05863-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05863-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444494800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brivio, F; Caetano, C; Walsh, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brivio, Federico; Caetano, Clovis; Walsh, Aron", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamic Origin of Photoinstability in the CH3NH3Pb(I1-xBrx)3 Hybrid Halide Perovskite Alloy", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of solid-solutions of iodide, bromide, and chloride provides the means to control the structure, band gap, and stability of hybrid halide perovskite semiconductors for photovoltaic applications. We report a computational investigation of the CH3NH3PbI3/CH3NH3PbBr3 alloy from density functional theory with a thermodynamic analysis performed within the generalized quasi-chemical approximation. We construct the phase diagram and identify a large miscibility gap, with a critical temperature of 343 K. The observed photoinstability in some mixed halide solar cells is explained by the thermodynamics of alloy formation, where an initially homogeneous solution is subject to spinodal decomposition with I and Br-rich phases, which is further complicated by a wide metastable region defined by the binodal line.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2016, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1083, "End Page": 1087, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b00226", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b00226", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372561900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, Y; Hays, MP; Hardwidge, PR; Kim, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Yue; Hays, Michael P.; Hardwidge, Philip R.; Kim, Jooyoun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface characteristics influencing bacterial adhesion to polymeric substrates", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superhydrophobic surfaces have been reported to reduce bacterial adhesion, but interactions between bacterial media and solid surfaces at the interface have rarely been associated with the solid area fraction (f) from the Cassie-Baxter wetting state. This study aimed to investigate the effective surface area for bacterial adhesion by analyzing the solid area fraction of surfaces where the bacterial medium is in contact with a solid surface. Also, the self-cleaning ability of the superhydrophobic surface against adhered bacteria was examined. The influences of roughness, surface energy, entrapped air, and surface charge of substrate materials on bacterial adhesion were examined, and the critical surface characteristics that are conducive to reducing Escherichia coli adherence to polymeric surfaces were determined. Moderate hydrophobicity with water contact angle of about 90 degrees produced the highest level of bacterial adhesion. Entrapped air at the interface of superhydrophobic surfaces interfered with the direct contact of bacteria to solid surfaces, leading to less bacterial adhesion. The superhydrophobic surface with a reduced solid area fraction displayed self-cleaning ability, where initially-adhered bacteria were removed by washing. The superhydrophilic substrate with negative zeta potential exhibited limited bacterial binding, due to the reduced hydrophobic interaction and possible repulsive interaction between bacteria and surface. The findings of this study can be utilized for an effective surface design to circumvent bacterial adhesion as an alternative solution to using antibiotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14254, "End Page": 14261, "Article Number": null, "DOI": "10.1039/c7ra01571b", "DOI Link": "http://dx.doi.org/10.1039/c7ra01571b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396012500068", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giannozzi, P; Baseggio, O; Bonfà, P; Brunato, D; Car, R; Carnimeo, I; Cavazzoni, C; de Gironcoli, S; Delugas, P; Ruffino, FF; Ferretti, A; Marzari, N; Timrov, I; Urru, A; Baroni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giannozzi, Paolo; Baseggio, Oscar; Bonfa, Pietro; Brunato, Davide; Car, Roberto; Carnimeo, Ivan; Cavazzoni, Carlo; de Gironcoli, Stefano; Delugas, Pietro; Ruffino, Fabrizio Ferrari; Ferretti, Andrea; Marzari, Nicola; Timrov, Iurii; Urru, Andrea; Baroni, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum ESPRESSO toward the exascale", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum ESPRESSO is an open-source distribution of computer codes for quantum-mechanical materials modeling, based on density-functional theory, pseudopotentials, and plane waves, and renowned for its performance on a wide range of hardware architectures, from laptops to massively parallel computers, as well as for the breadth of its applications. In this paper, we present a motivation and brief review of the ongoing effort to port Quantum ESPRESSO onto heterogeneous architectures based on hardware accelerators, which will overcome the energy constraints that are currently hindering the way toward exascale computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1098, "Times Cited, All Databases": 1142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2020, "Volume": 152, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 154105, "DOI": "10.1063/5.0005082", "DOI Link": "http://dx.doi.org/10.1063/5.0005082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529233100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prakash, A; Xu, P; Faghaninia, A; Shukla, S; Ager, JW; Lo, CS; Jalan, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prakash, Abhinav; Xu, Peng; Faghaninia, Alireza; Shukla, Sudhanshu; Ager, Joel W., III; Lo, Cynthia S.; Jalan, Bharat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wide bandgap BaSnO3 films with room temperature conductivity exceeding 104 S cm -1", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wide bandgap perovskite oxides with high room temperature conductivities and structural compatibility with a diverse family of organic/inorganic perovskite materials are of significant interest as transparent conductors and as active components in power electronics. Such materials must also possess high room temperature mobility to minimize power consumption and to enable high-frequency applications. Here, we report n-type BaSnO3 films grown using hybrid molecular beam epitaxy with room temperature conductivity exceeding 10(4) S cm(-1). Significantly, these films show room temperature mobilities up to 120 cm(2) V-1 s(-1) even at carrier concentrations above 3-10(20) cm(-3) together with a wide bandgap (3 eV). We examine the mobility-limiting scattering mechanisms by calculating temperature-dependent mobility, and Seebeck coefficient using the Boltzmann transport framework and ab-initio calculations. These results place perovskite oxide semiconductors for the first time on par with the highly successful III-N system, thereby bringing all-transparent, high-power oxide electronics operating at room temperature a step closer to reality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15167, "DOI": "10.1038/ncomms15167", "DOI Link": "http://dx.doi.org/10.1038/ncomms15167", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400850900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miller, TS; Jorge, AB; Suter, TM; Sella, A; Corà, F; McMillan, PF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miller, T. S.; Jorge, A. Belen; Suter, T. M.; Sella, A.; Cora, F.; McMillan, P. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon nitrides: synthesis and characterization of a new class of functional materials", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon nitride compounds with high N : C ratios and graphitic to polymeric structures are being investigated as potential next-generation materials for incorporation in devices for energy conversion and storage as well as for optoelectronic and catalysis applications. The materials are built from C- and N-containing heterocycles with heptazine or triazine rings linked via sp(2)-bonded N atoms (N(C)(3) units) or -NH- groups. The electronic, chemical and optical functionalities are determined by the nature of the local to extended structures as well as the chemical composition of the materials. Because of their typically amorphous to nullocrystalline nature and variable composition, significant challenges remain to fully assess and calibrate the structure-functionality relationships among carbon nitride materials. It is also important to devise a useful and consistent approach to naming the different classes of carbon nitride compounds that accurately describes their chemical and structural characteristics related to their functional performance. Here we evaluate the current state of understanding to highlight key issues in these areas and point out new directions in their development as advanced technological materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 363, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2017, "Volume": 19, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15613, "End Page": 15638, "Article Number": null, "DOI": "10.1039/c7cp02711g", "DOI Link": "http://dx.doi.org/10.1039/c7cp02711g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403965500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nejand, BA; Ritzer, DB; Hu, H; Schackmar, F; Moghadamzadeh, S; Feeney, T; Singh, R; Laufer, F; Schmager, R; Azmi, R; Kaiser, M; Abzieher, T; Gharibzadeh, S; Ahlswede, E; Lemmer, U; Richards, BS; Paetzold, UW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nejand, Bahram Abdollahi; Ritzer, David B.; Hu, Hang; Schackmar, Fabian; Moghadamzadeh, Somayeh; Feeney, Thomas; Singh, Roja; Laufer, Felix; Schmager, Raphael; Azmi, Raheleh; Kaiser, Milian; Abzieher, Tobias; Gharibzadeh, Saba; Ahlswede, Erik; Lemmer, Uli; Richards, Bryce S.; Paetzold, Ulrich W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable two-terminal all-perovskite tandem solar modules with a 19.1% efficiency", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolithic all-perovskite tandem photovoltaics promise to combine low-cost and high-efficiency solar energy harvesting with the advantages of all-thin-film technologies. To date, laboratory-scale all-perovskite tandem solar cells have only been fabricated using non-scalable fabrication techniques. In response, this work reports on laser-scribed all-perovskite tandem modules processed exclusively with scalable fabrication methods (blade coating and vacuum deposition), demonstrating power conversion efficiencies up to 19.1% (aperture area, 12.25 cm(2); geometric fill factor, 94.7%) and stable power output. Compared to the performance of our spin-coated reference tandem solar cells (efficiency, 23.5%; area, 0.1 cm(2)), our prototypes demonstrate substantial advances in the technological readiness of all-perovskite tandem photovoltaics. By means of electroluminescence imaging and laser-beam-induced current mapping, we demonstrate the homogeneous current collection in both subcells over the entire module area, which explains low losses (<5%(rel)) in open-circuit voltage and fill factor for our scalable modules. All-perovskite tandem photovoltaics hold technological potential yet their upscaling is not trivial. Here Nejand et al. fabricate mini-modules using scalable methods and laser-scribed interconnections, achieving a 19.1% efficiency over an aperture area of 12.25 cm(2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 620, "End Page": 630, "Article Number": null, "DOI": "10.1038/s41560-022-01059-w", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01059-w", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000824923700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Au, AK; Lee, W; Folch, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Au, Anthony K.; Lee, Wonjae; Folch, Albert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mail-order microfluidics: evaluation of stereolithography for the production of microfluidic devices", "Source Title": "LAB ON A CHIP", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The vast majority of microfluidic devices are developed in PDMS by molding (soft lithography) because PDMS is an inexpensive material, has physicochemical properties that are well suited for biomedical and physical sciences applications, and design cycle lengths are generally adequate for prototype development. However, PDMS molding is tediously slow and thus cannot provide the high-or medium-volume production required for the commercialization of devices. While high-throughput plastic molding techniques (e. g. injection molding) exist, the exorbitant cost of the molds and/or the equipment can be a serious obstacle for device commercialization, especially for small startups. High-volume production is not required to reach niche markets such as clinical trials, biomedical research supplies, customized research equipment, and classroom projects. Crucially, both PDMS and plastic molding are layer-by-layer techniques where each layer is produced as a result of physicochemical processes not specified in the initial photomask(s) and where the final device requires assembly by bonding, all resulting in a cost that is very hard to predict at the start of the project. By contrast, stereolithography (SL) is an automated fabrication technique that allows for the production of quasi-arbitrary 3D shapes in a single polymeric material at medium-volume throughputs (ranging from a single part to hundreds of parts). Importantly, SL devices can be designed between several groups using CAD tools, conveniently ordered by mail, and their cost precisely predicted via a web interface. Here we evaluate the resolution of an SL mail-order service and the main causes of resolution loss; the optical clarity of the devices and how to address the lack of clarity for imaging in the channels; and the future role that SL could play in the commercialization of microfluidic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 14, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1294, "End Page": 1301, "Article Number": null, "DOI": "10.1039/c3lc51360b", "DOI Link": "http://dx.doi.org/10.1039/c3lc51360b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Science & Technology - Other Topics; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332454600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leguy, AMA; Azarhoosh, P; Alonso, MI; Campoy-Quiles, M; Weber, OJ; Yao, JZ; Bryant, D; Weller, MT; Nelson, J; Walsh, A; van Schilfgaarde, M; Barnes, PRF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leguy, Aurelien M. A.; Azarhoosh, Pooya; Alonso, M. Isabel; Campoy-Quiles, Mariano; Weber, Oliver J.; Yao, Jizhong; Bryant, Daniel; Weller, Mark T.; Nelson, Jenny; Walsh, Aron; van Schilfgaarde, Mark; Barnes, Piers R. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental and theoretical optical properties of methylammonium lead halide perovskites", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The optical constants of methylammonium lead halide single crystals CH3NH3PbX3 (X = I, Br, Cl) are interpreted with high level ab initio calculations using the relativistic quasiparticle self-consistent GW approximation (QSGW). Good agreement between the optical constants derived from QSGW and those obtained from spectroscopic ellipsometry enables the assignment of the spectral features to their respective inter-band transitions. We show that the transition from the highest valence band (VB) to the lowest conduction band (CB) is responsible for almost all the optical response of MAPbI(3) between 1.2 and 5.5 eV (with minor contributions from the second highest VB and the second lowest CB). The calculations indicate that the orientation of [CH3NH3](+) cations has a significant influence on the position of the bandgap suggesting that collective orientation of the organic moieties could result in significant local variations of the optical properties. The optical constants and energy band diagram of CH3NH3PbI3 are then used to simulate the contributions from different optical transitions to a typical transient absorption spectrum (TAS).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6317, "End Page": 6327, "Article Number": null, "DOI": "10.1039/c5nr05435d", "DOI Link": "http://dx.doi.org/10.1039/c5nr05435d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372851500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chisnell, R; Helton, JS; Freedman, DE; Singh, DK; Bewley, RI; Nocera, DG; Lee, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chisnell, R.; Helton, J. S.; Freedman, D. E.; Singh, D. K.; Bewley, R. I.; Nocera, D. G.; Lee, Y. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Magnon Bands in a Kagome Lattice Ferromagnet", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is great interest in finding materials possessing quasiparticles with topological properties. Such materials may have novel excitations that exist on their boundaries which are protected against disorder. We report experimental evidence that magnons in an insulating kagome ferromagnet can have a topological band structure. Our neutron scattering measurements further reveal that one of the bands is flat due to the unique geometry of the kagome lattice. Spin wave calculations show that the measured band structure follows from a simple Heisenberg Hamiltonian with a Dzyaloshinkii-Moriya interaction. This serves as the first realization of an effectively two-dimensional topological magnon insulator-a new class of magnetic material that should display both a magnon Hall effect and protected chiral edge modes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2015, "Volume": 115, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147201, "DOI": "10.1103/PhysRevLett.115.147201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.147201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361815100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, G; Wang, PF; Hu, B; Shen, XY; Liu, CC; Tao, WX; Huang, PL; Liu, LZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Gang; Wang, Peifang; Hu, Bin; Shen, Xinyue; Liu, Chongchong; Tao, Weixiang; Huang, Peilin; Liu, Lizhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-related symmetry breaking induced by half-disordered hybridization in BixEr2-xRu2O7 pyrochlores for acidic oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While acidic oxygen evolution reaction plays a critical role in electrochemical energy conversion devices, the sluggish reaction kinetics and poor stability in acidic electrolyte challenges materials development. Unlike traditional nullo-structuring approaches, this work focuses on the structural symmetry breaking to rearrange spin electron occupation and optimize spin-dependent orbital interaction to alter charge transfer between catalysts and reactants. Herein, we propose an atomic half-disordering strategy in multistage-hybridized BixEr2-xRu2O7 pyrochlores to reconfigure orbital degeneracy and spin-related electron occupation. This strategy involves controlling the bonding interaction of Bi-6s lone pair electrons, in which partial atom rearrangement makes the active sites transform into asymmetric high-spin states from symmetric low-spin states. As a result, the half-disordered BixEr2-xRu2O7 pyrochlores demonstrate an overpotential of -0.18 V at 10 mA cm(-2) accompanied with excellent stability of 100 h in acidic electrolyte. Our findings not only provide a strategy for designing atom-disorder-related catalysts, but also provides a deeper understanding of the spin-related acidic oxygen evolution reaction kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4106, "DOI": "10.1038/s41467-022-31874-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31874-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826101400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lou, LY; Yang, JM; Zhu, YK; Liang, H; Zhang, YX; Feng, J; He, JQ; Ge, ZH; Zhao, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lou, Lu-Yao; Yang, Jianmin; Zhu, Yu-Ke; Liang, Hao; Zhang, Yi-Xin; Feng, Jing; He, Jiaqing; Ge, Zhen-Hua; Zhao, Li-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Electrical Conductivity and Simultaneously Enhanced Thermoelectric and Mechanical Properties in n-type Bi2Te3", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent growing energy crisis draws considerable attention to high-performance thermoelectric materials. n-type bismuth telluride is still irreplaceable at near room temperature for commercial application, and therefore, is worthy of further investigation. In this work, nullostructured Bi2Te3 polycrystalline materials with highly enhanced thermoelectric properties are obtained by alkali metal Na solid solution. Na is chosen as the cation site dopant for n-type polycrystalline Bi2Te3. Na enters the Bi site, introducing holes in the Bi2Te3 matrix and rendering the electrical conductivity tunable from 300 to 1800 Scm(-1). The solid solution limit of Na in Bi2Te3 exceeds 0.3 wt%. Owing to the effective solid solution, the Fermi level of Bi2Te3 is properly regulated, leading to an improved Seebeck coefficient. In addition, the scattering of both charge carriers and phonons is modulated, which ensured a high-power factor and low lattice thermal conductivity. Benefitting from the synergistic optimization of both electrical and thermal transport properties, a maximum figure of merit (ZT) of 1.03 is achieved at 303 K when the doping content is 0.25 wt%, which is 70% higher than that of the pristine sample. This work disclosed an effective strategy for enhancing the performance of n-type bismuth telluride-based alloy materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 9, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2203250, "DOI": "10.1002/advs.202203250", "DOI Link": "http://dx.doi.org/10.1002/advs.202203250", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000831340800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Retuerto, M; Pascual, L; Torrero, J; Salam, MA; Tolosana-Moranchel, A; Gianolio, D; Ferrer, P; Kayser, P; Wilke, V; Stiber, S; Celorrio, V; Mokthar, M; Sanchez, DG; Gago, AS; Friedrich, KA; Peña, MA; Alonso, JA; Rojas, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Retuerto, Maria; Pascual, Laura; Torrero, Jorge; Salam, Mohamed Abdel; Tolosana-Moranchel, Alvaro; Gianolio, Diego; Ferrer, Pilar; Kayser, Paula; Wilke, Vincent; Stiber, Svenja; Celorrio, Veronica; Mokthar, Mohamed; Sanchez, Daniel Garcia; Gago, Aldo Saul; Friedrich, Kaspar Andreas; Pena, Miguel Antonio; Alonso, Jose Antonio; Rojas, Sergio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active and stable OER electrocatalysts derived from Sr2MIrO6 for proton exchange membrane water electrolyzers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton exchange membrane water electrolysis is a promising technology to produce green hydrogen from renewables, as it can efficiently achieve high current densities. Lowering iridium amount in oxygen evolution reaction electrocatalysts is critical for achieving cost-effective production of green hydrogen. In this work, we develop catalysts from Ir double perovskites. Sr2CaIrO6 achieves 10 mA cm(-2) at only 1.48V. The surface of the perovskite reconstructs when immersed in an acidic electrolyte and during the first catalytic cycles, resulting in a stable surface conformed by short-range order edge-sharing IrO6 octahedra arranged in an open structure responsible for the high performance. A proton exchange membrane water electrolysis cell is developed with Sr2CaIrO6 as anode and low Ir loading (0.4 mg(Ir) cm(-2)). The cell achieves 2.40V at 6Acm(-2) (overload) and no loss in performance at a constant 2Acm(-2) (nominal load). Thus, reducing Ir use without compromising efficiency and lifetime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7935, "DOI": "10.1038/s41467-022-35631-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35631-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971044000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CW; Ding, L; Gordon, KN; Ghosh, B; Tien, HJ; Li, HX; Linn, AG; Lien, SW; Huang, CY; Mackey, S; Liu, JY; Reddy, PVS; Singh, B; Agarwal, A; Bansil, A; Song, M; Li, DS; Xu, SY; Lin, H; Cao, HB; Chang, TR; Dessau, D; Ni, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Chaowei; Ding, Lei; Gordon, Kyle N.; Ghosh, Barun; Tien, Hung-Ju; Li, Haoxiang; Linn, A. Garrison; Lien, Shang-Wei; Huang, Cheng-Yi; Mackey, Scott; Liu, Jinyu; Reddy, P. V. Sreenivasa; Singh, Bahadur; Agarwal, Amit; Bansil, Arun; Song, Miao; Li, Dongsheng; Xu, Su-Yang; Lin, Hsin; Cao, Huibo; Chang, Tay-Rong; Dessau, Dan; Ni, Ni", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of an intrinsic ferromagnetic topological state in MnBi8Te13", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel magnetic topological materials pave the way for studying the interplay between band topology and magnetism. However, an intrinsically ferromagnetic topological material with only topological bands at the charge neutrality energy has so far remained elusive. Using rational design, we synthesized MnBi8Te13, a natural heterostructure with [MnBi2Te4] and [Bi2Te3] layers. Thermodynamic, transport, and neutron diffraction measurements show that despite the adjacent [MnBi2Te4] being 44.1 angstrom apart, MnBi8Te13 manifests long-range ferromagnetism below 10.5 K with strong coupling between magnetism and charge carriers. First-principles calculations and angle-resolved photoemission spectroscopy measurements reveal it is an axion insulator with sizable surface hybridization gaps. Our calculations further demonstrate the hybridization gap persists in the two-dimensional limit with a nontrivial Chern number. Therefore, as an intrinsic ferromagnetic axion insulator with clean low-energy band structures, MnBi8Te13 serves as an ideal system to investigate rich emergent phenomena, including the quantized anomalous Hall effect and quantized magnetoelectric effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 6, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba4275", "DOI": "10.1126/sciadv.aba4275", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba4275", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552228100021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Zeng, MJ; Zhang, YW; Zhang, CY; Gao, ZS; He, F; Xue, XD; Li, HH; Li, P; Xie, GZ; Li, H; Zhang, X; Guo, NN; Cheng, H; Luo, AS; Zhao, W; Zhang, YZ; Tao, Y; Chen, RF; Huang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao; Zeng, Mingjian; Zhang, Yewen; Zhang, Chenyu; Gao, Zhisheng; He, Fei; Xue, Xudong; Li, Huanhuan; Li, Ping; Xie, Gaozhan; Li, Hui; Zhang, Xin; Guo, Ningning; Cheng, He; Luo, Ansheng; Zhao, Wei; Zhang, Yizhou; Tao, Ye; Chen, Runfeng; Huang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicolor hyperafterglow from isolated fluorescence chromophores", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-efficiency narrowband emission is always in the central role of organic optoelectronic display applications. However, the development of organic afterglow materials with sufficient color purity and high quantum efficiency for hyperafterglow is still great challenging due to the large structural relaxation and severe non-radiative decay of triplet excitons. Here we demonstrate a simple yet efficient strategy to achieve hyperafterglow emission through sensitizing and stabilizing isolated fluorescence chromophores by integrating multi-resonullce fluorescence chromophores into afterglow host in a single-component copolymer. Bright multicolor hyperafterglow with maximum photoluminescent efficiencies of 88.9%, minimum full-width at half-maximums (FWHMs) of 38 nm and ultralong lifetimes of 1.64 s under ambient conditions are achieved. With this facilely designed polymer, a large-area hyperafterglow display panel was fabricated. By virtue of narrow emission band and high luminescent efficiency, the hyperafterglow presents a significant technological advance in developing highly efficient organic afterglow materials and extends the domain to new applications. The development of organic afterglow materials with sufficient color purity and high quantum efficiency for hyperafterglow is a great challenging. Here, the authors demonstrate an efficient strategy to achieve hyperafterglow emission through sensitizing and stabilizing isolated fluorescence chromophores by integrating multiresonullce fluorescence chromophores into afterglow host in a singlecomponent copolymer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 475, "DOI": "10.1038/s41467-023-36105-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36105-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921576600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WW; Song, DS; Wei, WS; null, PF; Zhang, SL; Ge, BH; Tian, ML; Zang, JD; Du, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Weiwei; Song, Dongsheng; Wei, Wensen; null, Pengfei; Zhang, Shilei; Ge, Binghui; Tian, Mingliang; Zang, Jiadong; Du, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical manipulation of skyrmions in a chiral magnet", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been much interest in using skyrmions for new approaches to compution, however, creating, deleting and driving skyrmions remains a challenge. Here, Wang et al demonstrate all three operations for skyrmions in tailored Co8Zn10Mn2 nullodevices using tailored current pulses. Writing, erasing and computing are three fundamental operations required by any working electronic device. Magnetic skyrmions could be essential bits in promising in emerging topological spintronic devices. In particular, skyrmions in chiral magnets have outstanding properties like compact texture, uniform size, and high mobility. However, creating, deleting, and driving isolated skyrmions, as prototypes of aforementioned basic operations, have been a grand challenge in chiral magnets ever since the discovery of skyrmions, and achieving all these three operations in a single device is even more challenging. Here, by engineering chiral magnet Co8Zn10Mn2 into the customized micro-devices for in-situ Lorentz transmission electron microscopy observations, we implement these three operations of skyrmions using nullosecond current pulses with a low current density of about 10(10) A center dot m(-)(2) at room temperature. A notched structure can create or delete magnetic skyrmions depending on the direction and magnitude of current pulses. We further show that the magnetic skyrmions can be deterministically shifted step-by-step by current pulses, allowing the establishment of the universal current-velocity relationship. These experimental results have immediate significance towards the skyrmion-based memory or logic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1593, "DOI": "10.1038/s41467-022-29217-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29217-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773001900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abranches, DO; Coutinho, JAP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abranches, Dinis O.; Coutinho, Joao A. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Type V deep eutectic solvents: Design and applications", "Source Title": "CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Type V deep eutectic solvents are a novel class of sustainable solvents. They are prepared by physically mixing solid, non-ionic components and are characterized by strong negative deviations from thermodynamic ideality. This work provides guidelines for the rational design of these solvents and reviews some of their recent applications. Emphasis is given on the choice of hydrogen bond donors and acceptors to achieve the necessary liquid phase non-ideality, namely on the use of pairs of molecules with high polarity asymmetry, and stresses the importance of assessing their solid-liquid phase diagrams. Polymorphism and cocrystal formation are also briefly addressed, together with predictive methodologies that have been developed to estimate their properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 35, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100612, "DOI": "10.1016/j.cogsc.2022.100612", "DOI Link": "http://dx.doi.org/10.1016/j.cogsc.2022.100612", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806579800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FC; Lovorn, T; Tutuc, E; MacDonald, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fengcheng; Lovorn, Timothy; Tutuc, Emanuel; MacDonald, A. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hubbard Model Physics in Transition Metal Dichalcogenide Moire Bands", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible long period moire superlattices form in two-dimensional van der Waals crystals containing layers that differ slightly in lattice constant or orientation. In this Letter we show theoretically that isolated flat moire bands described by generalized triangular lattice Hubbard models are present in twisted transition metal dichalcogenide heterobilayers. The hopping and interaction strength parameters of the Hubbard model can be tuned by varying the twist angle and the three-dimensional dielectric environment. When the flat moire bands are partially filled, candidate many-body ground states at some special filling factors include spin-liquid states, quantum anomalous Hall insulators, and chiral d-wave superconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2018, "Volume": 121, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26402, "DOI": "10.1103/PhysRevLett.121.026402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.026402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438041900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, S; Zhou, ZD; Liu, ZS; Sharma, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Shuai; Zhou, Zidi; Liu, Zishun; Sharma, Pradeep", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Concurrent stiffening and softening in hydrogels under dehydration", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are an extraordinary soft matter system that serve as a laboratory for a rich plethora of multiphysical phenomena and find applications that range from biocompatible sensors to soft robots. Here, we report a pe-culiar experimental observation suggesting concurrent stiffening and softening in hydrogels during the dehy-dration process. Theories based on Flory's work fail to capture the scaling of mechanical behavior with water content, observed in our experiments. We perform coarse-grained molecular dynamics simulations to elucidate the mechanisms underpinning the odd softening-stiffening behavior during dehydration and propose a theo-retical model to correctly represent the underlying physics and the divergence from Flory-based theories.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2023, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eade3240", "DOI": "10.1126/sciadv.ade3240", "DOI Link": "http://dx.doi.org/10.1126/sciadv.ade3240", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937027000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, ST; Hao, SQ; Luo, ZZ; Li, X; Hadar, I; Bailey, T; Hu, XB; Uher, C; Hu, YY; Wolverton, C; Dravid, VP; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Songting; Hao, Shiqiang; Luo, Zhong-Zhen; Li, Xiang; Hadar, Ido; Bailey, Trevor; Hu, Xiaobing; Uher, Ctirad; Hu, Yan-Yan; Wolverton, Christopher; Dravid, Vinayak P.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discordant nature of Cd in PbSe: off-centering and core-shell nulloscale CdSe precipitates lead to high thermoelectric performance", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a novel hierarchical microstructure in the PbSe-CdSe system, which collectively contributes to significant enhancement in thermoelectric performance, with ZT(ave) similar to 0.83 across the 400-923 K temperature range, the highest reported for p-type, Te-free PbSe systems. We have investigated the local atomic structure as well as the microstructure of a series of PbSe-xCdSe materials, up to x = 10%. We find that the behavior of the Cd atoms in the octahedral rock salt sites is discordant and results in off-center displacement and distortion. Such off-centered Cd in the PbSe matrix creates (1) L-sigma electronic energy band convergence, (2) a flattened L band, both contributing to higher Seebeck coefficients, and (3) enhanced phonon scattering, which leads to lower thermal conductivity. These conclusions are supported by photoemission yield spectroscopy in air (PYSA), solid state Cd-111, Se-77 NMR spectroscopy and DFT calculations. Above the solubility limit (>6%CdSe), we also observe endotaxial CdSe nullo-precipitates with core-shell architecture formed in PbSe, whose size, distribution and structure gradually change with the Cd content. The nullo-precipitates exhibit a zinc blende crystal structure and a tetrahedral shape with significant local strain, but are covered with a thin wurtzite layer along the precipitate/matrix interface, creating a core-shell structure embedded in PbSe. This newly discovered architecture causes a further reduction in lattice thermal conductivity. Moreover, potassium is found to be an effective p-type dopant in the PbSe-CdSe system, leading to an enhanced power factor, a maximum ZT of similar to 1.4 at 923 K for Pb0.98K0.02Se-6%CdSe.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 200, "End Page": 211, "Article Number": null, "DOI": "10.1039/c9ee03087e", "DOI Link": "http://dx.doi.org/10.1039/c9ee03087e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508857600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JY; Aliasgar, M; Zamudio, FB; Zhang, TY; Zhao, YL; Lian, X; Wen, L; Yang, HZ; Sun, WP; Kozlov, SM; Chen, W; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jiayi; Aliasgar, Mohammed; Zamudio, Fernulldo Buendia; Zhang, Tianyu; Zhao, Yilin; Lian, Xu; Wen, Lan; Yang, Haozhou; Sun, Wenping; Kozlov, Sergey M.; Chen, Wei; Wang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membrane-based alkaline water electrolyser is promising for cost-effective green hydrogen production. One of its key technological obstacles is the development of active catalyst-materials for alkaline hydrogen-evolution reaction (HER). Here, we show that the activity of platinum towards alkaline HER can be significantly enhanced by anchoring platinum-clusters onto two-dimensional fullerene nullosheets. The unusually large lattice distance (similar to 0.8 nm) of the fullerene nullosheets and the ultra-small size of the platinumclusters (similar to 2 nm) leads to strong confinement of platinum clusters accompanied by pronounced charge redistributions at the intimate platinum/fullerene interface. As a result, the platinum-fullerene composite exhibits 12 times higher intrinsic activity for alkaline HER than the state-of-the-art platinum/ carbon black catalyst. Detailed kinetic and computational investigations revealed the origin of the enhanced activity to be the diverse binding properties of the platinum-sites at the interface of platinum/fullerene, which generates highly active sites for all elementary steps in alkaline HER, particularly the sluggish Volmer step. Furthermore, encouraging energy efficiency of 74% and stability were achieved for alkaline water electrolyser assembled using platinum-fullerene composite under industrially relevant testing conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1711, "DOI": "10.1038/s41467-023-37404-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37404-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001187299700032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Somerville, JW; Sobkowiak, A; Tapia-Ruiz, N; Billaud, J; Lozano, JG; House, RA; Gallington, LC; Ericsson, T; Häggström, L; Roberts, MR; Maitra, U; Bruce, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Somerville, James W.; Sobkowiak, Adam; Tapia-Ruiz, Nuria; Billaud, Juliette; Lozano, Juan G.; House, Robert A.; Gallington, Leighanne C.; Ericsson, Tore; Haggstrom, Lennart; Roberts, Matthew R.; Maitra, Urmimala; Bruce, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of the Z-phase in layered Na-ion battery cathodes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered sodium transition metal oxides with the P2 structure, e.g. Na-2/3[Ni1/3Mn2/3]O-2, are regarded as candidates for Na-ion battery cathodes. On charging, extraction of Na destabilizes the P2 phase (ABBA oxide ion stacking) in which Na+ is in trigonal prismatic coordination, resulting in layer gliding and formation of an O2 phase (ABAC stacking) with octahedral coordination. However, many related compounds do not exhibit such a simple P2 to O2 transition but rather form a so called Z-phase. Substituting Ni by Fe in Na-2/3[Ni1/3Mn2/3]O-2 is attractive as it reduces cost. The Fe containing compounds, such as Na-2/3[Ni1/6Mn1/2Fe1/3]O-2, form a Z-phase when charged above 4.1 V vs. Na+/Na. By combining ex situ and operando X-ray diffraction with scanning transmission electron microscopy and simulated diffraction patterns, we demonstrate that the Z-phase is most accurately described as a continuously changing intergrowth structure which evolves from P2 to O2 through the OP4 structure as an intermediate. On charging, Na+ removal results in O-type stacking faults within the P2 structure which increase in proportion. At 50% O-type stacking faults, the ordered OP4 phase forms and on further charging more O-type stacking faults are formed progressing towards a pure O2 structure. This gives the superficial appearance of a solid solution. Furthermore, in contrast to some previous studies, we did not detect Fe migration at any state-of-charge using Fe-57-Mossbauer spectroscopy. It was, however, found that the Fe-substitution serves to disrupt cation ordering in the material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2019, "Volume": 12, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2223, "End Page": 2232, "Article Number": null, "DOI": "10.1039/c8ee02991a", "DOI Link": "http://dx.doi.org/10.1039/c8ee02991a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477950000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zakrewsky, M; Lovejoy, KS; Kern, TL; Miller, TE; Le, V; Nagy, A; Goumas, AM; Iyer, RS; Del Sesto, RE; Koppisch, AT; Fox, DT; Mitragotri, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zakrewsky, Michael; Lovejoy, Katherine S.; Kern, Theresa L.; Miller, Tarryn E.; Le, Vivian; Nagy, Amber; Goumas, Andrew M.; Iyer, Rashi S.; Del Sesto, Rico E.; Koppisch, Andrew T.; Fox, David T.; Mitragotri, Samir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionic liquids as a class of materials for transdermal delivery and pathogen neutralization", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biofilm-protected microbial infections in skin are a serious health risk that remains to be adequately addressed. The lack of progress in developing effective treatment strategies is largely due to the transport barriers posed by the stratum corneum of the skin and the biofilm. In this work, we report on the use of Ionic Liquids (ILs) for biofilm disruption and enhanced antibiotic delivery across skin layers. We outline the syntheses of ILs, analysis of relevant physicochemical properties, and subsequent neutralization effects on two biofilm-forming pathogens: Pseudomonas aeruginosa and Salmonella enterica. Further, the ILs were also examined for cytotoxicity, skin irritation, delivery of antibiotics through the skin, and treatment of biofilms in a wound model. Of the materials examined, choline-geranate emerged as a multipurpose IL with excellent antimicrobial activity, minimal toxicity to epithelial cells as well as skin, and effective permeation enhancement for drug delivery. Specifically, choline-geranate was comparable with, or more effective than, bleach treatment against established biofilms of S. enterica and P. aeruginosa, respectively. In addition, choline-geranate increased delivery of cefadroxil, an antibiotic, by > 16-fold into the deep tissue layers of the skin without inducing skin irritation. The in vivo efficacy of choline-geranate was validated using a biofilm-infected wound model (> 95% bacterial death after 2-h treatment). This work establishes the use of ILs for simultaneous enhancement of topical drug delivery and antibiotic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2014, "Volume": 111, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13313, "End Page": 13318, "Article Number": null, "DOI": "10.1073/pnas.1403995111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1403995111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341630000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, J; DaSilva, AM; MacDonald, AH; Adam, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Jeil; DaSilva, Ashley M.; MacDonald, Allan H.; Adam, Shaffique", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of band gaps in graphene on hexagonal boron nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent progress in preparing well-controlled two-dimensional van der Waals heterojunctions has opened up a new frontier in materials physics. Here we address the intriguing energy gaps that are sometimes observed when a graphene sheet is placed on a hexagonal boron nitride substrate, demonstrating that they are produced by an interesting interplay between structural and electronic properties, including electronic many-body exchange interactions. Our theory is able to explain the observed gap behaviour by accounting first for the structural relaxation of graphene's carbon atoms when placed on a boron nitride substrate, and then for the influence of the substrate on low-energy p-electrons located at relaxed carbon atom sites. The methods we employ can be applied to many other van der Waals heterojunctions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6308, "DOI": "10.1038/ncomms7308", "DOI Link": "http://dx.doi.org/10.1038/ncomms7308", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350290300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Y; Zhou, TH; Mensi, M; Choi, JW; Coskun, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yan; Zhou, Tianhong; Mensi, Mounir; Choi, Jang Wook; Coskun, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fluorination of solvents, useful for non-aqueous lithium-based batteries, improves the electrochemical stability but decreases the ionic conductivity. Here, the authors report a targeted functionalization of an ether solvent to balance the electrolyte ionic conductivity and oxidative stability. Fluorination of ether solvents is an effective strategy to improve the electrochemical stability of non-aqueous electrolyte solutions in lithium metal batteries. However, excessive fluorination detrimentally impacts the ionic conductivity of the electrolyte, thus limiting the battery performance. Here, to maximize the electrolyte ionic conductivity and electrochemical stability, we introduce the targeted trifluoromethylation of 1,2-dimethoxyethane to produce 1,1,1-trifluoro-2,3-dimethoxypropane (TFDMP). TFDMP is used as a solvent to prepare a 2 M non-aqueous electrolyte solution comprising bis(fluorosulfonyl)imide salt. This electrolyte solution shows an ionic conductivity of 7.4 mS cm(-1) at 25 degrees C, an oxidation stability up to 4.8 V and an efficient suppression of Al corrosion. When tested in a coin cell configuration at 25 degrees C using a 20 mu m Li metal negative electrode, a high mass loading LiNi0.8Co0.1Mn0.1O2-based positive electrode (20 mg cm(-2)) with a negative/positive (N/P) capacity ratio of 1, discharge capacity retentions (calculated excluding the initial formation cycles) of 81% after 200 cycles at 0.1 A g(-1) and 88% after 142 cycles at 0.2 A g(-1) are achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 299, "DOI": "10.1038/s41467-023-35934-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35934-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001006189100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, K; Lu, C; Wang, LM; Qu, J; Weber, WJ; Zhang, Y; Bei, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, K.; Lu, C.; Wang, L. M.; Qu, J.; Weber, W. J.; Zhang, Y.; Bei, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of compositional complexity on the ion-irradiation induced swelling and hardening in Ni-containing equiatomic alloys", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The impact of compositional complexity on the ion-irradiation induced swelling and hardening is studied in Ni and six Ni-containing equiatomic alloys with face-centered cubic structure. The irradiation resistance at the temperature of 500 degrees C is improved by controlling the number and, especially, the type of alloying elements. Alloying with Fe and Mn has a stronger influence on swelling reduction than does alloying with Co and Cr. The quinary alloy NiCoFeCrMn, with known excellent mechanical properties, has shown 40 times higher swelling tolerance than nickel. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 374, "Times Cited, All Databases": 415, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2016, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 70, "Article Number": null, "DOI": "10.1016/j.scriptamat.2016.03.030", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2016.03.030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375814200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McKinlay, CJ; Vargas, JR; Blake, TR; Hardy, JW; Kanada, M; Contag, CH; Wender, PA; Waymouth, RM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McKinlay, Colin J.; Vargas, Jessica R.; Blake, Timothy R.; Hardy, Jonathan W.; Kanada, Masamitsu; Contag, Christopher H.; Wender, Paul A.; Waymouth, Robert M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-altering releasable transporters (CARTs) for the delivery and release of mRNA in living animals", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functional delivery of mRNA to tissues in the body is key to implementing fundamentally new and potentially transformative strategies for vaccination, protein replacement therapy, and genome editing, collectively affecting approaches for the prevention, detection, and treatment of disease. Broadly applicable tools for the efficient delivery of mRNA into cultured cells would advance many areas of research, and effective and safe in vivo mRNA delivery could fundamentally transform clinical practice. Here we report the step-economical synthesis and evaluation of a tunable and effective class of synthetic biodegradable materials: charge-altering releasable transporters (CARTs) for mRNA delivery into cells. CARTs are structurally unique and operate through an unprecedented mechanism, serving initially as oligo(a-amino ester) cations that complex, protect, and deliver mRNA and then change physical properties through a degradative, charge-neutralizing intramolecular rearrangement, leading to intracellular release of functional mRNA and highly efficient protein translation. With demonstrated utility in both cultured cells and animals, this mRNA delivery technology should be broadly applicable to numerous research and therapeutic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2017, "Volume": 114, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "E448", "End Page": "E456", "Article Number": null, "DOI": "10.1073/pnas.1614193114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1614193114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392597000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mauthe, S; Baumgartner, Y; Sousa, M; Ding, Q; Rossell, MD; Schenk, A; Czornomaz, L; Moselund, KE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mauthe, Svenja; Baumgartner, Yannick; Sousa, Marilyne; Ding, Qian; Rossell, Marta D.; Schenk, Andreas; Czornomaz, Lukas; Moselund, Kirsten E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-speed III-V nullowire photodetector monolithically integrated on Si", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct epitaxial growth of III-Vs on silicon for optical emitters and detectors is an elusive goal. nullowires enable the local integration of high-quality III-V material, but advanced devices are hampered by their high-aspect ratio vertical geometry. Here, we demonstrate the in-plane monolithic integration of an InGaAs nullostructure p-i-n photodetector on Si. Using free space coupling, photodetectors demonstrate a spectral response from 1200-1700 nm. The 60 nm thin devices, with footprints as low as -0.06 mu m(2), provide an ultra-low capacitance which is key for high-speed operation. We demonstrate high-speed optical data reception with a nullostructure photodetector at 32 Gb s(-1), enabled by a 3 dB bandwidth exceeding -25 GHz. When operated as light emitting diode, the p-i-n devices emit around 1600 nm, paving the way for future fully integrated optical links.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4565, "DOI": "10.1038/s41467-020-18374-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18374-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607111200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khanikaev, AB; Fleury, R; Mousavi, SH; Alù, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khanikaev, Alexander B.; Fleury, Romain; Mousavi, S. Hossein; Alu, Andrea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topologically robust sound propagation in an angular-momentum-biased graphene-like resonator lattice", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological insulators do not allow conduction in the bulk, yet they support edge modes that travel along the boundary only in one direction, determined by the carried electron spin, with inherent robustness to defects and disorder. Topological insulators have inspired analogues in photonics and optics, in which one-way edge propagation in topologically protected two-dimensional materials is achieved breaking time-reversal symmetry with a magnetic bias. Here, we introduce the concept of topological order in classical acoustics, realizing robust topological protection and one-way edge propagation of sound in a suitably designed resonator lattice biased with angular momentum, forming the acoustic analogue of a magnetically biased graphene layer. Extending the concept of an acoustic nonreciprocal circulator based on angular-momentum bias, time-reversal symmetry is broken here using moderate rotational motion of air within each element of the lattice, which takes the role of the electron spin in determining the direction of modal edge propagation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 511, "Times Cited, All Databases": 543, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8260, "DOI": "10.1038/ncomms9260", "DOI Link": "http://dx.doi.org/10.1038/ncomms9260", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364919700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chaudhary, V; Khanna, V; Awan, HTA; Singh, K; Khalid, M; Mishra, YK; Bhansali, S; Li, CZ; Kaushik, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chaudhary, Vishal; Khanna, Virat; Awan, Hafiz Taimoor Ahmed; Singh, Kamaljit; Khalid, Mohammad; Mishra, Yogendra Kumar; Bhansali, Shekhar; Li, Chen-Zhong; Kaushik, Ajeet", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards hospital-on-chip supported by 2D MXenes-based 5th generation intelligent biosensors", "Source Title": "BIOSENSORS & BIOELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Existing public health emergencies due to fatal/infectious diseases such as coronavirus disease (COVID-19) and monkeypox have raised the paradigm of 5th generation portable intelligent and multifunctional biosensors embedded on a single chip. The state-of-the-art 5th generation biosensors are concerned with integrating advanced functional materials with controllable physicochemical attributes and optimal machine processability. In this direction, 2D metal carbides and nitrides (MXenes), owing to their enhanced effective surface area, tunable physicochemical properties, and rich surface functionalities, have shown promising performances in biosensing flatlands. Moreover, their hybridization with diversified nullomaterials caters to their associated challenges for the commercialization of stability due to restacking and oxidation. MXenes and its hybrid bio-sensors have demonstrated intelligent and lab-on-chip prospects for determining diverse biomarkers/pathogens related to fatal and infectious diseases. Recently, on-site detection has been clubbed with solution-on-chip MXenes by interfacing biosensors with modern-age technologies, including 5G communication, internet-of-medical-things (IoMT), artificial intelligence (AI), and data clouding to progress toward hospital-on-chip (HOC) modules. This review comprehensively summarizes the state-of-the-art MXene fabrication, advance-ments in physicochemical properties to architect biosensors, and the progress of MXene-based lab-on-chip bio-sensors toward HOC solutions. Besides, it discusses sustainable aspects, practical challenges and alternative solutions associated with these modules to develop personalized and remote healthcare solutions for every in-dividual in the world.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2023, "Volume": 220, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114847, "DOI": "10.1016/j.bios.2022.114847", "DOI Link": "http://dx.doi.org/10.1016/j.bios.2022.114847", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biophysics; Biotechnology & Applied Microbiology; Chemistry; Electrochemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891931400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fountaine, KT; Lewerenz, HJ; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fountaine, Katherine T.; Lewerenz, Hans Joachim; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficiency limits for photoelectrochemical water-splitting", "Source Title": "Nature Communications", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Theoretical limiting efficiencies have a critical role in determining technological viability and expectations for device prototypes, as evidenced by the photovoltaics community's focus on detailed balance. However, due to their multicomponent nature, photoelectrochemical devices do not have an equivalent analogue to detailed balance, and reported theoretical efficiency limits vary depending on the assumptions made. Here we introduce a unified framework for photoelectrochemical device performance through which all previous limiting efficiencies can be understood and contextualized. Ideal and experimentally realistic limiting efficiencies are presented, and then generalized using five representative parameters-semiconductor absorption fraction, external radiative efficiency, series resistance, shunt resistance and catalytic exchange current density-to account for imperfect light absorption, charge transport and catalysis. Finally, we discuss the origin of deviations between the limits discussed herein and reported water-splitting efficiencies. This analysis provides insight into the primary factors that determine device performance and a powerful handle to improve device efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13706, "DOI": "10.1038/ncomms13706", "DOI Link": "http://dx.doi.org/10.1038/ncomms13706", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389306700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shumiya, N; Hossain, MS; Yin, JX; Jiang, YX; Ortiz, BR; Liu, HX; Shi, YG; Yin, QW; Le, HC; Zhan, ST; Chang, GQ; Zhang, Q; Cochran, TA; Multer, D; Litskevich, M; Cheng, ZJ; Yang, X; Guguchia, Z; Wilson, SD; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shumiya, nulla; Hossain, Md Shafayat; Yin, Jia-Xin; Jiang, Yu-Xiao; Ortiz, Brenden R.; Liu, Hongxiong; Shi, Youguo; Yin, Qiangwei; Le, Hechang; Zhan, Songtian S.; Chang, Guoqing; Zhang, Qi; Cochran, Tyler A.; Multer, Daniel; Litskevich, Maksim; Cheng, Zi-Jia; Yang, Xian P.; Guguchia, Zurab; Wilson, Stephen D.; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic nature of chiral charge order in the kagome superconductor RbV3Sb5", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductors with kagome lattices have been identified for over 40 years, with a superconducting transition temperature T-c up to 7 K. Recently, certain kagome superconductors have been found to exhibit an exotic charge order, which intertwines with superconductivity and persists to a temperature being one order of magnitude higher than T-c. In this work, we use scanning tunneling microscopy to study the charge order in kagome superconductor RbV3Sb5. We observe both a 2 x 2 chiral charge order and nematic surface superlattices (predominulltly 1 x 4). We find that the 2 x 2 charge order exhibits intrinsic chirality with magnetic field tunability. Defects can scatter electrons to introduce standing waves, which couple with the charge order to cause extrinsic effects. While the chiral charge order resembles that discovered in KV3Sb5, it further interacts with the nematic surface superlattices that are absent in KV3Sb5 but exist in CsV3Sb5.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2021, "Volume": 104, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35131, "DOI": "10.1103/PhysRevB.104.035131", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.104.035131", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000674317700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, XC; Barbosa, FAS; Roberts, SP; Dutt, A; Cardenas, J; Okawachi, Y; Bryant, A; Gaeta, AL; Lipson, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Xingchen; Barbosa, Felippe A. S.; Roberts, Samantha P.; Dutt, Avik; Cardenas, Jaime; Okawachi, Yoshitomo; Bryant, Alex; Gaeta, Alexander L.; Lipson, Michal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-low-loss on-chip resonators with sub-milliwatt parametric oscillation threshold", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-chip optical resonators have the promise of revolutionizing numerous fields, including metrology and sensing; however, their optical losses have always lagged behind those of their larger discrete resonator counterparts based on crystalline materials and silica microtoroids. Silicon nitride (Si3N4) ring resonators open up capabilities for frequency comb generation, optical clocks, and high-precision sensing on an integrated platform. However, simultaneously achieving a high quality factor (Q) and high confinement in Si3N4 (critical for nonlinear processes, for example) remains a challenge. Here we show that addressing surface roughness enables overcoming the loss limitations and achieving high-confinement on-chip ring resonators with Q of 37 million for a ring of 2.5 mu m width and 67 million for a ring of 10 mu m width. We show a clear systematic path for achieving these high Qs, and these techniques can also be used to reduce losses in other material platforms independent of geometry. Furthermore, we demonstrate optical parametric oscillation using the 2.5 mu m wide ring with sub-milliwatt pump powers and extract the loss limited by the material absorption in our films to be 0.13 +/- 0.05 dB/m, which corresponds to an absorption-limited Q of at least 170 million by comparing two resonators with different degrees of confinement. Our work provides a chip-scale platform for applications such as ultralow-power frequency comb generation, laser stabilization, and sideband-resolved optomechanics. (C) 2017 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 488, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 619, "End Page": 624, "Article Number": null, "DOI": "10.1364/OPTICA.4.000619", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.4.000619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404108200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ndao, A; Hsu, LY; Ha, JH; Park, JH; Chang-Hasnain, C; Kanté, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ndao, Abdoulaye; Hsu, Liyi; Ha, Jeongho; Park, Jun-Hee; Chang-Hasnain, Connie; Kante, Boubacar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Octave bandwidth photonic fishnet-achromatic-metalens", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Planar structured interfaces, also known as metasurfaces, are continuously attracting interest owing to their ability to manipulate fundamental attributes of light, including angular momentum, phase, or polarization. However, chromatic aberration, limiting broadband operation, has remained a challenge for metasurfaces-based optical components and imagers. The limitation stems from the intrinsic dispersion of existing materials and design principles. Here we report and experimentally demonstrate polarization-independent fishnet-achromatic-metalenses with measured average efficiencies over 70% in the continuous band from the visible (640nm) to the infrared (1200nm). Results of the scalable platform are enabling for applications requiring broad bandwidth and high efficiency including energy harvesting, virtual reality and information processing devices, or medical imaging. Here the authors demonstrate all-dielectric fishnet-achromatic-metalenses from the visible to the near-infrared region. This metalens performs efficiently independent of polarization over about an octave from 640nm to 1200nm.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17015-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17015-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549968400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choi, MJ; de Arquer, FPG; Proppe, AH; Seifitokaldani, A; Choi, J; Kim, J; Baek, SW; Liu, MX; Sun, B; Biondi, M; Scheffel, B; Walters, G; Nam, DH; Jo, JW; Ouellette, O; Voznyy, O; Hoogland, S; Kelley, SO; Jung, YS; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choi, Min-Jae; de Arquer, F. Pelayo Garcia; Proppe, Andrew H.; Seifitokaldani, Ali; Choi, Jongmin; Kim, Junghwan; Baek, Se-Woong; Liu, Mengxia; Sun, Bin; Biondi, Margherita; Scheffel, Benjamin; Walters, Grant; Nam, Dae-Hyun; Jo, Jea Woong; Ouellette, Olivier; Voznyy, Oleksandr; Hoogland, Sjoerd; Kelley, Shana O.; Jung, Yeon Sik; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cascade surface modification of colloidal quantum dot inks enables efficient bulk homojunction photovoltaics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Control over carrier type and doping levels in semiconductor materials is key for optoelectronic applications. In colloidal quantum dots (CQDs), these properties can be tuned by surface chemistry modification, but this has so far been accomplished at the expense of reduced surface passivation and compromised colloidal solubility; this has precluded the realization of advanced architectures such as CQD bulk homojunction solids. Here we introduce a cascade surface modification scheme that overcomes these limitations. This strategy provides control over doping and solubility and enables n-type and p-type CQD inks that are fully miscible in the same solvent with complete surface passivation. This enables the realization of homogeneous CQD bulk homojunction films that exhibit a 1.5 times increase in carrier diffusion length compared with the previous best CQD films. As a result, we demonstrate the highest power conversion efficiency (13.3%) reported among CQD solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103, "DOI": "10.1038/s41467-019-13437-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13437-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551441300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Werner, M; Blanquer, SBG; Haimi, SP; Korus, G; Dunlop, JWC; Duda, GN; Grijpma, DW; Petersen, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Werner, Maike; Blanquer, Sebastien B. G.; Haimi, Suvi P.; Korus, Gabriela; Dunlop, John W. C.; Duda, Georg N.; Grijpma, Dirk. W.; Petersen, Ansgar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Curvature Differentially Regulates Stem Cell Migration and Differentiation via Altered Attachment Morphology and Nuclear Deformation", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Signals from the microenvironment around a cell are known to influence cell behavior. Material properties, such as biochemical composition and substrate stiffness, are today accepted as significant regulators of stem cell fate. The knowledge of how cell behavior is influenced by 3D geometric cues is, however, strongly limited despite its potential relevance for the understanding of tissue regenerative processes and the design of biomaterials. Here, the role of surface curvature on the migratory and differentiation behavior of human mesenchymal stem cells (hMSCs) has been investigated on 3D surfaces with well-defined geometric features produced by stereolithography. Time lapse microscopy reveals a significant increase of cell migration speed on concave spherical compared to convex spherical structures and flat surfaces resulting from an upward-lift of the cell body due to cytoskeletal forces. On convex surfaces, cytoskeletal forces lead to substantial nuclear deformation, increase lamin-A levels and promote osteogenic differentiation. The findings of this study demonstrate a so far missing link between 3D surface curvature and hMSC behavior. This will not only help to better understand the role of extracellular matrix architecture in health and disease but also give new insights in how 3D geometries can be used as a cell-instructive material parameter in the field of biomaterial-guided tissue regeneration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600347, "DOI": "10.1002/advs.201600347", "DOI Link": "http://dx.doi.org/10.1002/advs.201600347", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397020800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Ye, ZL; Suzuki, R; Ye, Y; Zhu, HY; Xiao, J; Wang, Y; Iwasa, Y; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Mervin; Ye, Ziliang; Suzuki, Ryuji; Ye, Yu; Zhu, Hanyu; Xiao, Jun; Wang, Yuan; Iwasa, Yoshihiro; Zhang, Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically phase-matched second-harmonic generation in a 2D crystal", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Second-harmonic generation (SHG) has found extensive applications from hand-held laser pointers to spectroscopic and microscopic techniques. Recently, some cleavable van der Waals (vdW) crystals have shown SHG arising from a single atomic layer, where the SH light elucidated important information such as the grain boundaries and electronic structure in these ultra-thin materials. However, despite the inversion asymmetry of the single layer, the typical crystal stacking restores inversion symmetry for even numbers of layers leading to an oscillatory SH response, drastically reducing the applicability of vdW crystals such as molybdenum disulfide (MoS2). Here, we probe the SHG generated from the noncentrosymmetric 3R crystal phase of MoS2. We experimentally observed quadratic dependence of second-harmonic intensity on layer number as a result of atomically phase-matched nonlinear dipoles in layers of the 3R crystal that constructively interfere. By studying the layer evolution of the A and B excitonic transitions in 3R-MoS2 using SHG spectroscopy, we also found distinct electronic structure differences arising from the crystal structure and the dramatic effect of symmetry and layer stacking on the nonlinear properties of these atomic crystals. The constructive nature of the SHG in this 2D crystal provides a platform to reliably develop atomically flat and controllably thin nonlinear media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e16131", "DOI": "10.1038/lsa.2016.131", "DOI Link": "http://dx.doi.org/10.1038/lsa.2016.131", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385428300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fathabadi, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fathabadi, Hassan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High thermal performance lithium-ion battery pack including hybrid active passive thermal management system for using in hybrid/electric vehicles", "Source Title": "ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, a novel Li-ion battery pack design including hybrid active passive thermal management system is presented. The battery pack is suitable for using in hybrid/electric vehicles. Active part of the hybrid thermal management system uses distributed thin ducts, air flow and natural convection as cooling media while the passive part utilizes phase change material/expanded graphite composite (PCM/EG) as cooling/heating component to optimize the thermal performance of the proposed battery pack. High melting enthalpy of PCM/EG composite together with melting of PCM/EG composite at the temperature of 58.9 degrees C remains the temperature distribution of the battery units in the desired temperature range (below 60 degrees C). The temperature and voltage distributions in the proposed battery pack design consisting of battery units, distributed thin ducts and PCM/EG composite are calculated by numerical solving of the related partial differential equations. Simulation results obtained by writing M-files code in Matlab environment and plotting the numerical data are presented to validate the theoretical results. A comparison between the thermal and physical characteristics of the proposed battery pack and other latest works is presented that explicitly proves the battery pack performance. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2014, "Volume": 70, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 529, "End Page": 538, "Article Number": null, "DOI": "10.1016/j.energy.2014.04.046", "DOI Link": "http://dx.doi.org/10.1016/j.energy.2014.04.046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338806600053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kutz, RB; Chen, QM; Yang, HZ; Sajjad, SD; Liu, ZC; Masel, IR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kutz, Robert B.; Chen, Qingmei; Yang, Hongzhou; Sajjad, Syed D.; Liu, Zengcai; Masel, I. Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainion Imidazolium-Functionalized Polymers for Carbon Dioxide Electrolysis", "Source Title": "ENERGY TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CO2 electrolysis is a key step in CO2 conversion into fuels and chemicals as a way of mitigating climate change. We report the synthesis and testing of a series of new anion-conductive membranes (tradenamed SustainionS) for use in CO2 electrolysis. These membranes incorporate the functional character of imidazolium-based ionic liquids as co-catalysts in CO2 reduction into a solid membrane with a styrene backbone. We find that the addition of an imidazolium group onto the styrene side-chains increases the selectivity of the reaction from approximately 25% to approximately 95%. The current at 3 V is increased by a factor of 14. So far we have been able to tune these parameters to achieve stable cells that provide current densities higher than 100 mAcm(-2) at 3 V cell potential with a CO product selectivity over 98%. Stable performance was observed for 6 months of continuous operation (> 150 000 000 turnovers). These results demonstrate that imidazolium polymers are ideal membranes for CO2 electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 929, "End Page": 936, "Article Number": null, "DOI": "10.1002/ente.201600636", "DOI Link": "http://dx.doi.org/10.1002/ente.201600636", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634586000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Jiang, SP; Shao, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Y.; Jiang, S. P.; Shao, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intercalation pseudocapacitance in electrochemical energy storage: recent advances in fundamental understanding and materials development", "Source Title": "MATERIALS TODAY ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical energy storage (EES) plays an important role in personal electronics, electrified vehicles, and smart grid. Lithium-ion batteries (LIBs) and supercapacitors (SCs) are two of the most important EES devices that have been widely used in our daily life. The energy density of LIBs is heavily dependent on the electrode capacity, in which the charge storage proceeds mainly in three different mechanisms, that is, alloying, conversion, and intercalation. Conventional LIBs show high energy density, but the rate performance is usually unfavorable. As a comparison, the SCs, which store energy based on electrochemical double layer capacitance (EDLC) or surface Faradaic redox pseudocapacitance, shows outstanding rate performance, but the energy density is still much worse than LIBs. Recently, intercalation pseudocapacitance appears as a new type of EES mechanism which stores energy into the bulk of electrode through a battery-like intercalation process but behaves similar to an electrode of SCs (fast reaction kinetics). Such intercalation pseudocapacitance can effectively narrow the gap between SCs and LIBs in energy density and power density, providing a new opportunity for the development of advanced energy storage system with both high energy density and power density. Up to now, more and more reports about intercalation pseudocapacitive materials have been appeared in literature, however, a systematic analysis of the recent development in intercalation pseudocapacitance is still lack. In this article, we provided an in-time review of the recent progress in the understanding of intercalation pseudocapacitive process and the development of related electrode materials for EES. Importance was paid to the difference between Faradaic surface-redox pseudocapacitance and intercalation pseudocapacitance, as well between battery-like intercalation and pseudocapacitive intercalation. Both cation interaction (Li+ and Na+) and oxygen anion intercalation pseudocapacitance was summarized. (C) 2020 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100072, "DOI": "10.1016/j.mtadv.2020.100072", "DOI Link": "http://dx.doi.org/10.1016/j.mtadv.2020.100072", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568768400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XY; Lin, FT; Liu, F; Shi, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xiaoyong; Lin, Fangting; Liu, Feng; Shi, Wangzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Dirac semimetals supported tunable terahertz BIC metamaterials", "Source Title": "nullOPHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on the 3D Dirac semimetals (DSM) supported tilted double elliptical resonators, the tunable propagation properties of quasi-bound in continuum (BIC) resonullce have been investigated in the THz regime, including the effects of rotation angles, DSM Fermi level, and the configuration of resonators. The results manifest that by altering the rotation angle of elliptical resonator, an obvious sharp BIC transmission dip is observed with the Q-factor of more than 60. The DSM Fermi level affects the BIC resonullce significantly, a sharp resonullt dip is observed if Fermi level is larger than 0.05 eV, resulting from the contributions of reflection and absorption. If Fermi level changes in the range of 0.01-0.15 eV, the amplitude and frequency modulation depths are 92.75 and 44.99%, respectively. Additionally, with the modified configurations of elliptical resonators, e.g. inserting a dielectric hole into the elliptical resonator, another transmission dip resonullce is excited and indicates a red shift with the increase of the permittivity of the dielectric filling material. The results are very helpful to understand the mechanisms of DSM plasmonic structures and develop novel tunable THz devices, such as modulators, filters, and sensors in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2022, "Volume": 11, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4705, "End Page": 4714, "Article Number": null, "DOI": "10.1515/nulloph-2022-0285", "DOI Link": "http://dx.doi.org/10.1515/nulloph-2022-0285", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000871624200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdolhosseinzadeh, S; Asgharzadeh, H; Kim, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdolhosseinzadeh, Sina; Asgharzadeh, Hamed; Kim, Hyoung Seop", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and fully-scalable synthesis of reduced graphene oxide", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exfoliation of graphite is a promising approach for large-scale production of graphene. Oxidation of graphite effectively facilitates the exfoliation process, yet necessitates several lengthy washing and reduction processes to convert the exfoliated graphite oxide (graphene oxide, GO) to reduced graphene oxide (RGO). Although filtration, centrifugation and dialysis have been frequently used in the washing stage, none of them is favorable for large-scale production. Here, we report the synthesis of RGO by sonication-assisted oxidation of graphite in a solution of potassium permanganate and concentrated sulfuric acid followed by reduction with ascorbic acid prior to any washing processes. GO loses its hydrophilicity during the reduction stage which facilitates the washing step and reduces the time required for production of RGO. Furthermore, simultaneous oxidation and exfoliation significantly enhance the yield of few-layer GO. We hope this one-pot and fully-scalable protocol paves the road toward out of lab applications of graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 611, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10160, "DOI": "10.1038/srep10160", "DOI Link": "http://dx.doi.org/10.1038/srep10160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355248200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoshida, M; Suzuki, R; Zhang, YJ; Nakano, M; Iwasa, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoshida, Masaro; Suzuki, Ryuji; Zhang, Yijin; Nakano, Masaki; Iwasa, Yoshihiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Memristive phase switching in two-dimensional 1T-TaS2 crystals", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scaling down materials to an atomic-layer level produces rich physical and chemical properties as exemplified in various two-dimensional (2D) crystals including graphene, transition metal dichalcogenides, and black phosphorus. This is caused by the dramatic modification of electronic band structures. In such reduced dimensions, the electron correlation effects are also expected to be significantly changed from bulk systems. However, there are few attempts to realize novel phenomena in correlated 2D crystals. We report memristive phase switching in nullo-thick crystals of 1T-type tantalum disulfide (1T-TaS2), a first-order phase transition system. The ordering kinetics of the phase transition were found to become extremely slow as the thickness is reduced, resulting in an emergence of metastable states. Furthermore, we realized unprecedented memristive switching to multistep nonvolatile states by applying an in-plane electric field. The reduction of thickness is essential to achieve such nonvolatile electrical switching behavior. The thinning-induced slow kinetics possibly make the various metastable states robust and consequently realize the nonvolatile memory operation. The present result indicates that a 2D crystal with correlated electrons is a novel nullo-system to explore and functionalize multiple metastable states that are inaccessible in its bulk form.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 272, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 1, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500606", "DOI": "10.1126/sciadv.1500606", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216598200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, X; Duan, JY; Chen, WY; Zhou, CB; Liu, TT; Xiao, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xing; Duan, Junyi; Chen, Wenya; Zhou, Chaobiao; Liu, Tingting; Xiao, Shuyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling light absorption of graphene at critical coupling through magnetic dipole quasi-bound states in the continuum resonullce", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancing the light-matter interaction in two-dimensional (2D) materials with high Q resonullces in photonic structures has boosted the development of optical and photonic devices. Herein we intend to build a bridge between the radiation engineering and the bound states in the continuum (BIC), and present a general method to control light absorption at critical coupling through the quasi-BIC resonullce. In a single-mode, two-port system composed of graphene, coupled with silicon nullodisk metasurfaces, the maximum absorption of 0.5 can be achieved when the radiation rate of the magnetic dipole resonullce equals to the dissipate loss rate of graphene. Furthermore, the absorption bandwidth can be adjusted more than two orders of magnitude, from 0.9 nm to 94 nm, by simultaneously changing the asymmetric parameter of metasurfaces, the Fermi level, and the layer number of graphene. This work reveals the essential role of BIC in radiation engineering and provides promising strategies in controlling light absorption of 2D materials for the next-generation optical and photonic devices, e.g., light emitters, detectors, modulators, and sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2020, "Volume": 102, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 155432, "DOI": "10.1103/PhysRevB.102.155432", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.102.155432", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000583119700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blackwell, RE; Zhao, FZ; Brooks, E; Zhu, JM; Piskun, I; Wang, SK; Delgado, A; Lee, YL; Louie, SG; Fischer, FR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blackwell, Raymond E.; Zhao, Fangzhou; Brooks, Erin; Zhu, Junmian; Piskun, Ilya; Wang, Shenkai; Delgado, Aidan; Lee, Yea-Lee; Louie, Steven G.; Fischer, Felix R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin splitting of dopant edge state in magnetic zigzag graphene nulloribbons", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-ordered electronic states in hydrogen-terminated zigzag nullographene give rise to magnetic quantum phenomena(1,2) that have sparked renewed interest in carbon-based spintronics(3,4). Zigzag graphene nulloribbons (ZGNRs)-quasi one-dimensional semiconducting strips of graphene bounded by parallel zigzag edges-host intrinsic electronic edge states that are ferromagnetically ordered along the edges of the ribbon and antiferromagnetically coupled across its width(1,2,5). Despite recent advances in the bottom-up synthesis of GNRs featuring symmetry protected topological phases(6-8) and even metallic zero mode bands(9), the unique magnetic edge structure of ZGNRs has long been obscured from direct observation by a strong hybridization of the zigzag edge states with the surface states of the underlying support(10-15). Here, we present a general technique to thermodynamically stabilize and electronically decouple the highly reactive spin-polarized edge states by introducing a superlattice of substitutional N-atom dopants along the edges of a ZGNR. First-principles GW calculations and scanning tunnelling spectroscopy reveal a giant spin splitting of low-lying nitrogen lone-pair flat bands by an exchange field (similar to 850 tesla) induced by the ferromagnetically ordered edge states of ZGNRs. Our findings directly corroborate the nature of the predicted emergent magnetic order in ZGNRs and provide a robust platform for their exploration and functional integration into nulloscale sensing and logic devices(15-21).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2021, "Volume": 600, "Issue": 7890, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 647, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04201-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04201-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733421800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bartók, AP; Kermode, J; Bernstein, N; Csányi, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bartok, Albert P.; Kermode, James; Bernstein, Noam; Csanyi, Gabor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine Learning a General-Purpose Interatomic Potential for Silicon", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The success of first-principles electronic-structure calculation for predictive modeling in chemistry, solid-state physics, and materials science is constrained by the limitations on simulated length scales and timescales due to the computational cost and its scaling. Techniques based on machine-learning ideas for interpolating the Born-Oppenheimer potential energy surface without explicitly describing electrons have recently shown great promise, but accurately and efficiently fitting the physically relevant space of configurations remains a challenging goal. Here, we present a Gaussian approximation potential for silicon that achieves this milestone, accurately reproducing density-functional-theory reference results for a wide range of observable properties, including crystal, liquid, and amorphous bulk phases, as well as point, line, and plane defects. We demonstrate that this new potential enables calculations such as finite-temperature phase-boundary lines, self-diffusivity in the liquid, formation of the amorphous by slow quench, and dynamic brittle fracture, all of which are very expensive with a first-principles method. We show that the uncertainty quantification inherent to the Gaussian process regression framework gives a qualitative estimate of the potential's accuracy for a given atomic configuration. The success of this model shows that it is indeed possible to create a useful machine-learning-based interatomic potential that comprehensively describes a material on the atomic scale and serves as a template for the development of such models in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2018, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41048, "DOI": "10.1103/PhysRevX.8.041048", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.8.041048", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453474000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Martínez-Pañeda, E; Golahmar, A; Niordson, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martinez-Paneda, Emilio; Golahmar, Alireza; Niordson, Christian F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A phase field formulation for hydrogen assisted cracking", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a phase field modeling framework for hydrogen assisted cracking. The model builds upon a coupled mechanical and hydrogen diffusion response, driven by chemical potential gradients, and a hydrogen-dependent fracture energy degradation law grounded on first principles calculations. The coupled problem is solved in an implicit time integration scheme, where displacements, phase field order parameter and hydrogen concentration are the primary variables. We show that phase field formulations for fracture are particularly suitable to capture material degradation due to hydrogen. Specifically, we model (i) unstable crack growth in the presence of hydrogen, (ii) failure stress sensitivity to hydrogen content in notched specimens, (iii) cracking thresholds under constant load, (iv) internal hydrogen assisted fracture in cracked specimens, and (v) complex crack paths arising from corrosion pits. Computations reveal a good agreement with experiments, highlighting the predictive capabilities of the present scheme. The work could have important implications for the prediction and prevention of catastrophic failures in corrosive environments. The finite element code developed can be downloaded from www.empaneda.com/codes. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2018, "Volume": 342, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 742, "End Page": 761, "Article Number": null, "DOI": "10.1016/j.cma.2018.07.021", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2018.07.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444962500032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, Y; Bai, Y; Fang, YJ; Wang, Q; Deng, YH; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yun; Bai, Yang; Fang, Yanjun; Wang, Qi; Deng, Yehao; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressed Ion Migration in Low-Dimensional Perovskites", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ion migration, which occurs in regular three-dimensional perovskites, is shown to be suppressed in low-dimensional perovskites both in the dark and under illumination, an indication of better stability of these materials for solar cells and light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 468, "Times Cited, All Databases": 502, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1571, "End Page": 1572, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00442", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00442", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405979900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalz, KF; Kraehnert, R; Dvoyashkin, M; Dittmeyer, R; Gläser, R; Krewer, U; Reuter, K; Grunwaldt, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalz, Kai F.; Kraehnert, Ralph; Dvoyashkin, Muslim; Dittmeyer, Roland; Glaeser, Roger; Krewer, Ulrike; Reuter, Karsten; Grunwaldt, Jan-Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Future Challenges in Heterogeneous Catalysis: Understanding Catalysts under Dynamic Reaction Conditions", "Source Title": "CHEMCATCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the future, (electro-) chemical catalysts will have to be more tolerant towards a varying supply of energy and raw materials. This is mainly due to the fluctuating nature of renewable ener-gies. For example, power-to-chemical processes require a shift from steady-state operation towards operation under dynamic reaction conditions. This brings along a number of demands for the design of both catalysts and reactors, because it is well-known that the structure of catalysts is very dynamic. However, in-depth studies of catalysts and catalytic reactors under such transient conditions have only started recently. This requires studies and advances in the fields of 1) operando spectroscopy including time-resolved methods, 2) theory with predictive quality, 3) kinetic modelling, 4) design of catalysts by appropriate preparation concepts, and 5) novel/modular reactor designs. An intensive exchange between these scientific disciplines will enable a substantial gain of fundamental knowledge which is urgently required. This concept article highlights recent developments, challenges, and future directions for understanding catalysts under dynamic reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2017, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17, "End Page": 29, "Article Number": null, "DOI": "10.1002/cctc.201600996", "DOI Link": "http://dx.doi.org/10.1002/cctc.201600996", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395797000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wick, P; Louw-Gaume, AE; Kucki, M; Krug, HF; Kostarelos, K; Fadeel, B; Dawson, KA; Salvati, A; Vázquez, E; Ballerini, L; Tretiach, M; Benfenati, F; Flahaut, E; Gauthier, L; Prato, M; Bianco, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wick, Peter; Louw-Gaume, Anna E.; Kucki, Melanie; Krug, Harald F.; Kostarelos, Kostas; Fadeel, Bengt; Dawson, Kenneth A.; Salvati, Anna; Vazquez, Ester; Ballerini, Laura; Tretiach, Mauro; Benfenati, Fabio; Flahaut, Emmanuel; Gauthier, Laury; Prato, Maurizio; Bianco, Alberto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Classification Framework for Graphene-Based Materials", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2014, "Volume": 53, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7714, "End Page": 7718, "Article Number": null, "DOI": "10.1002/anie.201403335", "DOI Link": "http://dx.doi.org/10.1002/anie.201403335", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339562400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Wang, H; Chin, XY; Dewi, HA; Vergeer, K; Goh, TW; Lim, JWM; Lew, JH; Loh, KP; Soci, C; Sum, TC; Bolink, HJ; Mathews, N; Mhaisalkar, S; Bruno, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jia; Wang, Hao; Chin, Xin Yu; Dewi, Herlina Arianita; Vergeer, Kurt; Goh, Teck Wee; Lim, Jia Wei Melvin; Lew, Jia Haur; Loh, Kian Ping; Soci, Cesare; Sum, Tze Chien; Bolink, Henk J.; Mathews, Nripan; Mhaisalkar, Subodh; Bruno, Annalisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and Mini-modules", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid improvement in the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has prompted interest in bringing the technology toward commercialization. Capitalizing on existing industrial processes facilitates the transition from laboratory to production lines. In this work, we prove the scalability of thermally co-evaporated MAPbI(3) layers in PSCs and mini-modules. With a combined strategy of active layer engineering, interfacial optimization, surface treatments, and light management, we demonstrate PSCs (0.16 cm(2) active area) and mini-modules (21 cm(2) active area) achieving record PCEs of 20.28% and 18.13%, respectively. Un-encapsulated PSCs retained similar to 90% of their initial PCE under continuous illumination at 1 sun, without sample cooling, for more than 100 h. Looking toward tandem and building integrated photovoltaic applications, we have demonstrated semi-transparent mini-modules and colored PSCs with consistent PCEs of similar to 16% for a set of visible colors. Our work demonstrates the compatibility of perovskite technology with industrial processes and its potential for next-generation photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2020, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1035, "End Page": 1053, "Article Number": null, "DOI": "10.1016/j.joule.2020.03.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.03.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535806100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Malekpour, H; Ramnulli, P; Srinivasan, S; Balasubramanian, G; Nika, DL; Mulchandani, A; Lake, RK; Balandin, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Malekpour, Hoda; Ramnulli, Pankaj; Srinivasan, Srilok; Balasubramanian, Ganesh; Nika, Denis L.; Mulchandani, Ashok; Lake, Roger K.; Balandin, Alexander A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal conductivity of graphene with defects induced by electron beam irradiation", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate the thermal conductivity of suspended graphene as a function of the density of defects, ND, introduced in a controllable way. High-quality graphene layers are synthesized using chemical vapor deposition, transferred onto a transmission electron microscopy grid, and suspended over similar to 7.5 mu m size square holes. Defects are induced by irradiation of graphene with the low-energy electron beam (20 keV) and quantified by the Raman D-to-G peak intensity ratio. As the defect density changes from 2.0 x 10(10) cm(-2) to 1.8 x 10(11) cm(-2) the thermal conductivity decreases from similar to(1.8 +/- 0.2) x 10(3) W mK(-1) to similar to(4.0 +/- 0.2) x 10(2) W mK(-1) near room temperature. At higher defect densities, the thermal conductivity reveals an intriguing saturation-type behavior at a relatively high value of similar to 400 W mK(-1). The thermal conductivity dependence on the defect density is analyzed using the Boltzmann transport equation and molecular dynamics simulations. The results are important for understanding phonon-point defect scattering in two-dimensional systems and for practical applications of graphene in thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 8, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14608, "End Page": 14616, "Article Number": null, "DOI": "10.1039/c6nr03470e", "DOI Link": "http://dx.doi.org/10.1039/c6nr03470e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381417800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "D'Alessandro, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "D'Alessandro, D. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploiting redox activity in metal-organic frameworks: concepts, trends and perspectives", "Source Title": "CHEMICAL COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Of the many thousands of new metal-organic frameworks (MOFs) that are now discovered each year, many possess potential redox activity arising from the constituent metal ions and/or organic ligands, or the guest molecules located within their porous structures. Those redox states that can be accessed via postsynthetic redox modulation often possess distinct physical properties; if harnessed, these provide a basis for applications including microporous conductors, electrocatalysts, energy storage devices and electrochemical sensors, amongst others. This feature article highlights the latest developments in experimental, theoretical and computational concepts relevant to redox-active MOFs, including new solid state electrochemical and spectroelectrochemical techniques that have great utility in this field. A particular emphasis is on current and emerging trends at the fundamental level which underscore the importance of this promising class of electroactive materials for a wide range of technologically- and industrially-relevant applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 52, "Issue": 58, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8957, "End Page": 8971, "Article Number": null, "DOI": "10.1039/c6cc00805d", "DOI Link": "http://dx.doi.org/10.1039/c6cc00805d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379431000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Filatov, MA; Karuthedath, S; Polestshuk, PM; Savoie, H; Flanagan, KJ; Sy, C; Sitte, E; Telitchko, M; Laquai, F; Boyle, RW; Senge, MO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filatov, Mikhail A.; Karuthedath, Safakath; Polestshuk, Pavel M.; Savoie, Huguette; Flanagan, Keith J.; Sy, Cindy; Sitte, Elisabeth; Telitchko, Maxime; Laquai, Frederic; Boyle, Ross W.; Senge, Mathias O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generation of Triplet Excited States via Photoinduced Electron Transfer in meso-anthra-BODIPY: Fluorogenic Response toward Singlet Oxygen in Solution and in Vitro", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heavy atom-free BODIPY-anthracene dyads (BADs) generate locally excited triplet states by way of photoinduced electron transfer (PeT), followed by recombination of the resulting charge-separated states (CSS). Subsequent quenching of the triplet states by molecular oxygen produces singlet oxygen (O-1(2)), which reacts with the anthracene moiety yielding highly fluorescent species. The steric demand of the alkyl substituents in the BODIPY subunit defines the site of O-1(2) addition. Novel bis- and tetraepoxides and bicyclic acetal products, arising from rearrangements of anthracene endoperoxides were isolated and characterized. O-1(2) generation by BADs in living cells enables visualization of the dyads distribution, promising new imaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2017, "Volume": 139, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6282, "End Page": 6285, "Article Number": null, "DOI": "10.1021/jacs.7b00551", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b00551", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401307800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yadav, AA; Hunge, YM; Kang, SW; Fujishima, A; Terashima, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yadav, Anuja A.; Hunge, Yuvaraj M.; Kang, Seok-Won; Fujishima, Akira; Terashima, Chiaki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Photocatalytic Degradation Activity Using the V2O5/RGO Composite", "Source Title": "nullOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor-based photocatalyst materials played an important role in the degradation of organic compounds in recent years. Photocatalysis is a simple, cost-effective, and environmentally friendly process for degrading organic compounds. In this work, vanadium pentoxide (V2O5) and V2O5/RGO (reduced graphene oxide) composite were synthesized by a hydrothermal method. The prepared samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), Raman spectroscopy, and UV-Vis spectroscopic analysis, etc. Raman analysis shows the occurrence of RGO characteristic peaks in the composite and different vibrational modes of V2O5. The band gap of flake-shaped V2O5 is reduced and its light absorption capacity is enhanced by making its composite with RGO. The photocatalytic degradation of methylene blue (MB) was studied using both V2O5 and V2O5/RGO composite photocatalyst materials. The V2O5/RGO composite exhibits a superior photocatalytic performance to V2O5. Both catalyst and light play an important role in the degradation process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 13, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 338, "DOI": "10.3390/nullo13020338", "DOI Link": "http://dx.doi.org/10.3390/nullo13020338", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000915688400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, MT; Cai, A; Pandey, M; Shen, C; Zhang, YL; Hu, LL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Man -Tai; Cai, Ao; Pandey, Madhup; Shen, Chen; Zhang, Yuelong; Hu, Lili", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties of high strength steels and weld metals at arctic low temperatures", "Source Title": "THIN-WALLED STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper attempts to acquire fundamental knowledge on the mechanical properties of high strength steels and the corresponding high strength weld metals at arctic low temperatures. Two types of high strength steels (Q890, Q960) and three types of high strength weld metals (made of ER100S-G, ER110S-G, ER120S-G feedstock wires) were tested at arctic low and ambient temperatures ranging from -75 degrees C to 25 degrees C. Tensile coupon specimens for steel materials were directly extracted from high strength steel plates, whilst robotic gas metal arc welding was employed to fabricate the tensile specimens of weld metals. The tensile coupon specimens were designed as per ASTM E8M and wire-cut into shapes. Twenty-three tensile coupon tests on high strength steels and eighteen tensile coupon tests on high strength weld metals were carried out. Coupon specimens were tested in liquid nitrogen cooling chamber to mimic the arctic low temperature environment. The stress-strain responses and key mechanical properties of high strength steels and weld metals at both ambient and arctic low temperatures are presented and discussed. Prediction equations for key mechanical properties, including the Young's modulus, yield stress and ultimate tensile strength, of high strength steels and weld metals at arctic low temperatures were proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 185, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110543, "DOI": "10.1016/j.tws.2023.110543", "DOI Link": "http://dx.doi.org/10.1016/j.tws.2023.110543", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000944462600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, S; Dai, SN; Ma, J; Ren, QY; Hu, CL; Gao, ZH; Le, MD; Sheptyakov, D; Miao, P; Torii, S; Kamiyama, T; Felser, C; Yang, J; Fu, CG; Zhu, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Shen; Dai, Shengnull; Ma, Jie; Ren, Qingyong; Hu, Chaoliang; Gao, Ziheng; Duc Le, Manh; Sheptyakov, Denis; Miao, Ping; Torii, Shuki; Kamiyama, Takashi; Felser, Claudia; Yang, Jiong; Fu, Chenguang; Zhu, Tiejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong phonon softening and avoided crossing in aliovalence-doped heavy-band thermoelectrics", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aliovalent doping is a way to optimize the electrical properties of semiconductors, but its impact on the phonon structure and propagation is seldom considered properly. Here we show that aliovalent doping can be much more effective in reducing the lattice thermal conductivity of thermoelectric semiconductors than the commonly employed isoelectronic alloying strategy. We demonstrate this in the heavy-band NbFeSb system, finding that a reduction of 65% in the lattice thermal conductivity is achieved through only 10% aliovalent Hf doping, compared with the four times higher isoelectronic Ta alloying. We show that aliovalent doping introduces free charge carriers and enhances screening, leading to the softening and deceleration of optical phonons. Moreover, the heavy dopant can induce the avoided crossing of acoustic and optical phonon branches, decelerating the acoustic phonons. These results highlight the significant role of aliovalent dopants in regulating the phonon structure and suppressing the phonon propagation of semiconductors. Aliovalent doping affects the electrical properties of semiconductors, but its effect on phonons is unclear. Now, strong softening and deceleration of phonons, causing a significant reduction in lattice thermal conductivity, is reported for Hf-doped NbFeSb.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 19, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1649, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-023-02188-z", "DOI Link": "http://dx.doi.org/10.1038/s41567-023-02188-z", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001050101300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TX; Jiang, SW; Li, LZ; Zhang, Y; Kang, KF; Zhu, JC; Watanabe, K; Taniguchi, T; Chowdhury, D; Fu, L; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tingxin; Jiang, Shengwei; Li, Lizhong; Zhang, Yang; Kang, Kaifei; Zhu, Jiacheng; Watanabe, Kenji; Taniguchi, Takashi; Chowdhury, Debanjan; Fu, Liang; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Continuous Mott transition in semiconductor moire superlattices", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The evolution of a Landau Fermi liquid into a non-magnetic Mott insulator with increasing electronic interactions is one of the most puzzling quantum phase transitions in physics(1-6). The vicinity of the transition is believed to host exotic states of matter such as quantum spin liquids(4-7), exciton condensates(8) and unconventional superconductivity(1). Semiconductor moire materials realize a highly controllable Hubbard model simulator on a triangular lattice(9-22), providing a unique opportunity to drive a metal-insulator transition (MIT) via continuous tuning of the electronic interactions. Here, by electrically tuning the effective interaction strength in MoTe2/WSe2 moire superlattices, we observe a continuous MIT at a fixed filling of one electron per unit cell. The existence of quantum criticality is supported by the scaling collapse of the resistance, a continuously vanishing charge gap as the critical point is approached from the insulating side, and a diverging quasiparticle effective mass from the metallic side. We also observe a smooth evolution of the magnetic susceptibility across the MIT and no evidence of long-range magnetic order down to similar to 5% of the Curie-Weiss temperature. This signals an abundance of low-energy spinful excitations on the insulating side that is further corroborated by the Pomeranchuk effect observed on the metallic side. Our results are consistent with the universal critical theory of a continuous Mott transition in two dimensions(4,23). The interaction strength in moire superlattices is tuned to drive a continuous metal-to-insulator transition at a fixed electron density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2021, "Volume": 597, "Issue": 7876, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 350, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03853-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03853-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696334600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yi, RJ; Shi, XD; Tang, Y; Yang, YQ; Zhou, P; Lu, BG; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yi, Renjie; Shi, Xiaodong; Tang, Yan; Yang, Yongqiang; Zhou, Peng; Lu, Bingan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carboxymethyl Chitosan-Modified Zinc Anode for High-Performance Zinc-Iodine Battery with Narrow Operating Voltage", "Source Title": "SMALL STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reasonable regulation of iodine redox has gradually shown potential as a desirable cathodic reaction in zinc-based batteries, but suffers from poor cyclic reversibility caused by uncontrollable side reactions. Also, the irregular growth of dendrites and unavoidable occurrences of hydrogen evolution reaction in H2O-rich environment have become permanent topics in anodic zinc. Herein, a cross- linked gel based on carboxymethyl chitosan is proposed and serves as an artificial electrolyte interphase for zinc anode (marked as Zn-CMCS). Such a coating formed by crosslinking among a monodentate carboxyl group, a hydroxyl, an amino, and Zn2+ from adding solution closely adheres on the surface of the zinc foil with toughness, ductility, and ideal electrochemical kinetics. Additionally, its homogenized surface charge distribution provides a flexible substrate for zinc plating/stripping, resulting in a flat real-time interface. While introducing I-/I-0 conversion by matching adsorptive activated carbon on carbon fiber cloth (AC-CFC) as cathode, the internal space restricted by CMCS gel enables the assembled Zn- CMCS/AC-CFC battery to exhibit a greatly improved reversibility under long-cycling condition within 28 000 cycles (measured for more than 2 years) in a narrow operating voltage range of 0.23 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 4, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2300020, "DOI": "10.1002/sstr.202300020", "DOI Link": "http://dx.doi.org/10.1002/sstr.202300020", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000978669300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, W; Wu, Q; Sun, R; Guo, J; Wu, Y; Shi, MM; Yang, WY; Li, HN; Min, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wei; Wu, Qiang; Sun, Rui; Guo, Jing; Wu, Yao; Shi, Mumin; Yang, Wenyan; Li, Hongneng; Min, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling Molecular Mass of Low-Band-Gap Polymer Acceptors for High-Performance All-Polymer Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent advances in the development of polymer acceptors and the investigation of molecular mass have boosted the power conversion efficiency (PCE) of all-polymer solar cells (all-PSCs) to approximately 11%. Here, a fused-aromatic-ring-constructed polymer acceptor PYT (Poly[(2,2'-((2Z,2'Z)-(( 12,13-bis(2-octyldodecyl)-3,9-diundecyl12,13-dihydro[1,2,5]thiadiazolo[3,4e]thieno[2 '',3 '' :40,50]thieno[2',3':4,5] pyrrolo[3,2-g]thieno[2',3' :4,5]thieno[3,2-b]-indole-2,10-diyl)bis(methanylylidene))bis(3-oxo-2,3-dihydro-1H-indene-2,1-diylidene)) dimalononitrile-alt-2,5-thiophene)]) is reported, while a series of PYT polymers with different molecular masses (designated as PYTL, PYTM, and PYTH) are prepared to fine-tune the molecular crystallinity and miscibility. Benefiting from the advantages of PYT series, which possess broad absorption with a narrow band of 1.40-1.44 eV and high absorption coefficients of over 1.00 3 105 cm(-1), we investigated the blend miscibility and device performance of all-PSCs based on a wide-bandgap polymer donor, PM6. The PYTM-based all-PSCs exhibit an excellent PCE of 13.44%, outperforming those with PYTL (12.55%) and PYTH (8.61%). Our results provide insight into polymer acceptor backbone and molecular mass and suggest guidelines to rationally select polymers for all-PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2020, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1070, "End Page": 1086, "Article Number": null, "DOI": "10.1016/j.joule.2020.03.019", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.03.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535806100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, BT; Dong, B; Wang, F; Yang, QF; He, YP; Zhang, CJ; Jin, P; Feng, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Botao; Dong, Bo; Wang, Feng; Yang, Qifeng; He, Yunpeng; Zhang, Cunjin; Jin, Peng; Feng, Lai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling a bifunctional mechanism for methanol-to-formate electro-oxidation on nickel-based hydroxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For nickel-based catalysts, in-situ formed nickel oxyhydroxide has been generally believed as the origin for anodic biomass electro-oxidations. However, rationally understanding the catalytic mechanism still remains challenging. In this work, we demonstrate that NiMn hydroxide as the anodic catalyst can enable methanol-to-formate electro-oxidation reaction (MOR) with a low cellpotential of 1.33/1.41V at 10/100mAcm-2, a Faradaic efficiency of nearly 100% and good durability in alkaline media, remarkably outperforming NiFe hydroxide. Based on a combined experimental and computational study, we propose a cyclic pathway that consists of reversible redox transitions of NiII(OH)2/NiIII-OOH and a concomitant MOR. More importantly, it is proved that the NiIII-OOH provides combined active sites including NiIII and nearby electrophilic oxygen species, which work in a cooperative manner to promote either spontaneous or non-spontaneous MOR process. Such a bifunctional mechanism can well account for not only the highly selective formate formation but also the transient presence of NiIII-OOH. The different catalytic activities ofNiMn and NiFe hydroxides can be attributed to their different oxidation behaviors. Thus, our work provides a clear and rational understanding of the overall MOR mechanism on nickel-based hydroxides, which is beneficial for advanced catalyst design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1686, "DOI": "10.1038/s41467-023-37441-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37441-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001187299700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Walker, TW; Frelka, N; Shen, ZZ; Chew, AK; Banick, J; Grey, S; Kim, MS; Dumesic, JA; Van Lehn, RC; Huber, GW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Walker, Theodore W.; Frelka, Nathan; Shen, Zhizhang; Chew, Alex K.; Banick, Jesse; Grey, Steven; Kim, Min Soo; Dumesic, James A.; Van Lehn, Reid C.; Huber, George W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling of multilayer plastic packaging materials by solvent-targeted recovery and precipitation", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many plastic packaging materials manufactured today are composites made of distinct polymer layers (i.e., multilayer films). Billions of pounds of these multilayer films are produced annually, but manufacturing inefficiencies result in large, corresponding postindustrial waste streams. Although relatively clean (as opposed to municipal wastes) and of near-constant composition, no commercially practiced technologies exist to fully deconstruct postindustrial multilayer film wastes into pure, recyclable polymers. Here, we demonstrate a unique strategy we call solvent-targeted recovery and precipitation (STRAP) to deconstruct multilayer films into their constituent resins using a series of solvent washes that are guided by thermodynamic calculations of polymer solubility. We show that the STRAP process is able to separate three representative polymers (polyethylene, ethylene vinyl alcohol, and polyethylene terephthalate) from a commercially available multilayer film with nearly 100% material efficiency, affording recyclable resins that are cost-competitive with the corresponding virgin materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 6, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba7599", "DOI": "10.1126/sciadv.aba7599", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba7599", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592173500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weiss, A; Siebel, A; Bernt, M; Shen, TH; Tileli, V; Gasteiger, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weiss, A.; Siebel, A.; Bernt, M.; Shen, T. -H.; Tileli, V.; Gasteiger, H. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of Intermittent Operation on Lifetime and Performance of a PEM Water Electrolyzer", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this study is to provide a better understanding of performance degrading mechanisms occurring when a proton exchange membrane water electrolyzer (PEM-WE) is coupled with renewable energies, where times of operation and idle periods alternate. An accelerated stress test (AST) is proposed, mimicking a fluctuating power supply by operating the electrolyzer cell between high (3 A cm(geo)(-2)) and low current densities (0.1 A cm(geo)(-2)), alternating with idle periods during which no current is supplied and the cell rests at open circuit voltage (OCV). Polarization curves, periodically recorded during the OCV-AST, reveal an initial increase in activity (approximate to 50 mV after 10 cycles) followed by a significant decrease in performance during prolonged OCV cycling due to an increasing high frequency resistance (HFR) (approximate to 1.6-fold after 718 cycles). These performance changes can clearly be related to the OCV periods, since they are not observed in a reference experiment where the OCV period is replaced by a potential hold at 1.3 V. The origin of the phenomena, which are responsible for the initial performance gain as well as the subsequent decay are analyzed via detailed electrochemical and physical characterization of the MEAs, and an operating strategy to prevent performance degradation is proposed. (c) The Author(s) 2019. Published by ECS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2019, "Volume": 166, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "F487", "End Page": "F497", "Article Number": null, "DOI": "10.1149/2.0421908jes", "DOI Link": "http://dx.doi.org/10.1149/2.0421908jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466319300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fong, SW; Neumann, CM; Wong, HSP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fong, Scott W.; Neumann, Christopher M.; Wong, H. -S. Philip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-Change Memory-Towards a Storage-Class Memory", "Source Title": "IEEE TRANSACTIONS ON ELECTRON DEVICES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase-change memory (PCM) has undergone significant academic and industrial research in the last 15 years. After much development, it is now poised to enter the market as a storage-class memory (SCM), with performance and cost between that of nullD flash and DRAM. In this paper, we review the history of phase-transforming chalcogenides leading up to our current understanding of PCM as either a storage-type SCM, with high-density and better than nullD flash endurance, write speeds, and retention, or a memory-type SCM, with fast read/write times to function as a nonvolatile DRAM. Several of the key findings from the community relating to device dimensional scaling, cell design, thermal engineering, material exploration, and storing multiple levels per cell will be discussed. These areas have dramatically impacted the course of development and understanding of PCM. We will highlight the performance gains attained and the future prospects, which will help drive PCM to be as ubiquitous as nullD flash in the upcoming decade.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 64, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4374, "End Page": 4385, "Article Number": null, "DOI": "10.1109/TED.2017.2746342", "DOI Link": "http://dx.doi.org/10.1109/TED.2017.2746342", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413732500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, YK; Luo, Z; Cho, SP; Kanatzidis, MG; Chung, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Yong Kyu; Luo, Zhongzhen; Cho, Sung Pyo; Kanatzidis, Mercouri G.; Chung, In", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Oxide Removal for Polycrystalline SnSe Reveals Near-Single-Crystal Thermoelectric Performance", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin selenide (SnSe) has emerged as a surprising new material with exceptional thermal transport and charge transport properties such as ultralow thermal conductivity, which give it a record-high thermoelectric figure of merit (ZT) of similar to 2.5-2.7 at around 800 K. These properties, however, have been only observable in well-prepared and properly handled single-crystal samples. Polycrystalline SnSe samples have markedly inferior properties paradoxically with higher apparent thermal conductivity and much lower ZT values than single crystals. The high thermal conductivity in polycrystalline samples has been attributed to surface tin oxides. Based on this hypothesis, we have employed an oxide-removing strategy that involves a chemical reduction process at 613 K under a 4% H-2/Ar atmosphere. This leads to an exceptionally low lattice thermal conductivity of similar to 0.11 W m(-1)K(-1) in polycrystalline hole-doped SnSe alloyed with 5% lead selenide, even lower than that of single crystals, and boosts the ZT to similar to 2.5 at 773 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 719, "End Page": 731, "Article Number": null, "DOI": "10.1016/j.joule.2019.01.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.01.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462010600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ruan, JW; Jian, SK; Yao, H; Zhang, HJ; Zhang, SC; Xing, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ruan, Jiawei; Jian, Shao-Kai; Yao, Hong; Zhang, Haijun; Zhang, Shou-Cheng; Xing, Dingyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symmetry-protected ideal Weyl semimetal in HgTe-class materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ideal Weyl semimetals with all Weyl nodes exactly at the Fermi level and no coexisting trivial Fermi surfaces in the bulk, similar to graphene, could feature deep physics such as exotic transport phenomena induced by the chiral anomaly. Here, we show that HgTe and half-Heusler compounds, under a broad range of in-plane compressive strain, could be materials in nature realizing ideal Weyl semimetals with four pairs of Weyl nodes and topological surface Fermi arcs. Generically, we find that the HgTe-class materials with nontrivial band inversion and noncentrosymmetry provide a promising arena to realize ideal Weyl semimetals. Such ideal Weyl semimetals could further provide a unique platform to study emergent phenomena such as the interplay between ideal Weyl fermions and superconductivity in the half-Heusler compound LaPtBi.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11136, "DOI": "10.1038/ncomms11136", "DOI Link": "http://dx.doi.org/10.1038/ncomms11136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373477300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JR; Xu, L; Zhou, YJ; Yan, TR; Shao, YY; Yang, DZ; Zhang, L; Xia, Z; Wang, TH; Zhang, L; Cheng, T; Shao, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jinrong; Xu, Liang; Zhou, Yijing; Yan, Tianran; Shao, Yanyan; Yang, Dongzi; Zhang, Liang; Xia, Zhou; Wang, Tianheng; Zhang, Liang; Cheng, Tao; Shao, Yuanlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating the Inner Helmholtz Plane with a High Donor Additive for Efficient Anode Reversibility in Aqueous Zn-Ion Batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of aqueous Zn ion batteries (AZIBs) is highly dependent on inner Helmholtz plane (IHP) chemistry. Notorious parasitic reactions containing hydrogen evolution reactions (HER) and Zn dendrites both originate from abundant free H2O and random Zn deposition inside active IHP. Here, we report a universal high donor number (DN) additive pyridine (Py) with only 1 vol. % addition (Py-to-H2O volume ratio), for regulating molecule distribution inside IHP. Density functional theory (DFT) calculations and molecular dynamics (MD) simulation verify that incorporated Py additive could tailor Zn2+ solvation sheath and exclude H2O molecules from IHP effectively, which is in favor of preventing H2O decomposition. Consequently, even at extreme conditions such as high depth of discharge (DOD) of 80 %, the symmetric cell based on Py additive can sustain approximately 500 h long-term stability. This efficient strategy with high DN additives furnishes a promising direction for designing novel electrolytes and promoting the practical application of AZIBs, despite inevitably introducing trace organic additives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2023, "Volume": 62, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202302302", "DOI Link": "http://dx.doi.org/10.1002/anie.202302302", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000974411500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CQ; Gu, XB; Chen, ZH; Han, X; Yu, N; Wei, YN; Gao, JH; Chen, H; Zhang, M; Wang, A; Zhang, JQ; Wei, ZX; Peng, Q; Tang, Z; Hao, XT; Zhang, X; Huang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Congqi; Gu, Xiaobin; Chen, Zhihao; Han, Xiao; Yu, Na; Wei, Yanull; Gao, Jinhua; Chen, Hao; Zhang, Meng; Wang, Ao; Zhang, Jianqi; Wei, Zhixiang; Peng, Qian; Tang, Zheng; Hao, Xiaotao; Zhang, Xin; Huang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving Record-Efficiency Organic Solar Cells upon Tuning the Conformation of Solid Additives", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Volatile solid additives (SADs) are considered as a simple yet effective approach to tune the film morphology for high-performance organic solar cells (OSCs). However, the structural effects of the SADs on the photovoltaic performance are still elusive. Herein, two volatilizable SADs were designed and synthesized. One is SAD1 with twisted conformation, while the other one is planar SAD2 with the S center dot center dot center dot O noncovalent intra-molecular interactions (NIIs). The theoretical and experimental results revealed that the planar SAD2 with smaller space occupation can more easily insert between the Y6 molecules, which is beneficial to form a tighter intermolecular packing mode of Y6 after thermal treatment. As a result, the SAD2-treated OSCs exhibited less recombination loss, more balanced charge mobility, higher hole transfer rate, and more favorable morphology, resulting in a record power conversion efficiency (PCE) of 18.85% (certified PCE: 18.7%) for single-junction binary OSCs. The universality of this study shed light on understanding the conformation effects of SADs on photovoltaic performances of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 144, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14731, "End Page": 14739, "Article Number": null, "DOI": "10.1021/jacs.2c05303", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c05303", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874843800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Lany, S; Ghanbaja, J; Fagot-Revurat, Y; Chen, YP; Soldera, F; Horwat, D; Mücklich, F; Pierson, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Y.; Lany, S.; Ghanbaja, J.; Fagot-Revurat, Y.; Chen, Y. P.; Soldera, F.; Horwat, D.; Muecklich, F.; Pierson, J. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic structures of Cu2O, Cu4O3, and CuO: A joint experimental and theoretical study", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A joint experimental and theoretical study is presented for the electronic structures of copper oxides including Cu2O, CuO, and the metastable mixed-valence oxide Cu4O3. The optical band gap is determined by experimental optical absorption coefficient, and the electronic structure in valence and conduction bands is probed by photoemission and electron energy loss spectroscopies, respectively. The experimental results are compared with many-body GW calculations utilizing an additional on-site potential for d-orbital energies that facilitates tractable and predictive computations. The side-by-side comparison between the three oxides, including a band insulator (Cu2O) and two Mott/charge-transfer insulators (CuO, Cu4O3) leads to a consistent picture for the optical and band-structure properties of the Cu oxides, strongly supporting indirect band gaps of about 1.2 and 0.8 eV in CuO and Cu4O3, respectively. This comparison also points towards surface oxidation and reduction effects that can complicate the interpretation of the photoemission spectra.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 94, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 245418, "DOI": "10.1103/PhysRevB.94.245418", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.245418", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390258000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, W; He, HY; Yang, L; Jiang, QG; Yuliarto, B; Yamauchi, Y; Xu, XT; Huang, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Wei; He, Haiyan; Yang, Lu; Jiang, Quanguo; Yuliarto, Brian; Yamauchi, Yusuke; Xu, Xingtao; Huang, Huajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "1D-2D hybridization: nulloarchitectonics for grain boundary-rich platinum nullowires coupled with MXene nullosheets as efficient methanol oxidation electrocatalysts", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although a direct methanol fuel cell with high energy utilization efficiency and low hazardous emission has broad application prospects in various energy-related fields, the insufficient methanol oxidation activity as well as the short service life of the anode catalysts continue to hinder its large-scale commercialization. Herein, we demonstrate a convenient and robust approach for the controllable synthesis of 1D grain boundary-rich Pt nullowires strongly coupled with ultrathin Ti3C2Tx MXene nullosheets (Pt NWs/MX). Such a unique architectural design endows the heterojunction catalysts with a series of structural merits, including large accessible surface area, stable interconnected Pt networks, numerous grain boundary sites, ameliorative electronic structure, and excellent electron conductivity. Consequently, the optimized Pt NWs/MX catalyst exhibits a unique methanol oxidation performance with a large electrochemically active surface area of 105.5 m2 g-1, a high mass (specific) activity of 1621.5 mA mg-1 (1.6 mA cm-2), as well as superior long-term durability, making it more competitive than conventional Pt nulloparticle/carbon catalysts with the same Pt loading.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2022, "Volume": 450, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137932, "DOI": "10.1016/j.cej.2022.137932", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.137932", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830817600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qun, L; Yun, X; Bo, C; Baoshan, G; Xin, W; Guoqiang, B; Hui, L; Shuai, L; Bin, D; Haifeng, F; Zheng, T; Tao, L; Haoyu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qun, Lei; Yun, Xu; Bo, Cai; Baoshan, Guan; Xin, Wang; Guoqiang, Bi; Hui, Li; Shuai, L., I; Bin, Ding; Haifeng, Fu; Zheng, Tong; Tao, Li; Haoyu, Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Progress and prospects of horizontal well fracturing technology for shale oil and gas reservoirs", "Source Title": "PETROLEUM EXPLORATION AND DEVELOPMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By systematically summarizing horizontal well fracturing technology abroad for shale oil and gas reservoirs since the 13th Five-Year Plan, this article elaborates new horizontal well fracturing features in 3D development of stacked shale reservoirs, small well spacing and dense well pattern, horizontal well re-fracturing, fracturing parameters optimization and cost control. In light of requirements on horizontal well fracturing technology in China, we have summarized the technological progress in simulation of multi-fracture propagation, horizontal well frac-design, electric-drive fracturing equipment, soluble tools and low-cost downhole materials and factory-like operation. On this basis, combined with the demand analysis of horizontal well fracturing technology in the 14th Five-Year Plan for unconventional shale oil and gas, we suggest strengthening the research and development in the following 7 aspects: (1) geology-engineering integration; (2) basic theory and design optimization of fracturing for shale oil and gas reservoirs; (3) development of high-power electric-drive fracturing equipment; (4) fracturing tool and supporting equipment for long horizontal section; (5) horizontal well flexible-sidetracking drilling technology for tapping remaining oil; (6) post-frac workover technology for long horizontal well; (7) intelligent fracturing technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 49, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 191, "End Page": 199, "Article Number": null, "DOI": "10.1016/S1876-3804(22)60015-6", "DOI Link": "http://dx.doi.org/10.1016/S1876-3804(22)60015-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering; Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760343000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HX; Zhang, TT; Yilmaz, T; Pai, YY; Marvinney, CE; Said, A; Yin, QW; Gong, CS; Tu, ZJ; Vescovo, E; Nelson, CS; Moore, RG; Murakami, S; Lei, HC; Lee, HN; Lawrie, BJ; Miao, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Haoxiang; Zhang, T. T.; Yilmaz, T.; Pai, Y. Y.; Marvinney, C. E.; Said, A.; Yin, Q. W.; Gong, C. S.; Tu, Z. J.; Vescovo, E.; Nelson, C. S.; Moore, R. G.; Murakami, S.; Lei, H. C.; Lee, H. N.; Lawrie, B. J.; Miao, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Unconventional Charge Density Wave without Acoustic Phonon Anomaly in Kagome Superconductors AV3Sb5 (A = Rb, Cs)", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The combination of nontrivial band topology and symmetry-breaking phases gives rise to novel quantum states and phenomena such as topological superconductivity, quantum anomalous Hall effect, and axion electrodynamics. Evidence of intertwined charge density wave (CDW) and superconducting order parameters has recently been observed in a novel kagome material AV(3)Sb(5) (A = K, Rb, Cs) that features a Z(2) topological invariant in the electronic structure. However, the origin of the CDW and its intricate interplay with the topological state has yet to be determined. Here, using hard-x-ray scattering, we demonstrate a three-dimensional CDW with 2 x 2 x 2 superstructure in (Rb, Cs)V3Sb5. Unexpectedly, we find that the CDW fails to induce acoustic phonon anomalies at the CDW wave vector but yields a novel Raman mode that quickly damps into a broad continuum below the CDW transition temperature. Our observations exclude strong electron-phonon-coupling-driven CDW in AV(3)Sb(5) and support an unconventional CDW that was proposed in the kagome lattice at van Hove filling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2021, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31050, "DOI": "10.1103/PhysRevX.11.031050", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.031050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000692788500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Munkhbat, B; Wróbel, P; Antosiewicz, TJ; Shegai, TO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Munkhbat, Battulga; Wrobel, Piotr; Antosiewicz, Tomasz J.; Shegai, Timur O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical Constants of Several Multilayer Transition Metal Dichalcogenides Measured by Spectroscopic Ellipsometry in the 300-1700 nm Range: High Index, Anisotropy, and Hyperbolicity", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal dichalcogenides (TMDs) attract significant attention due to their remarkable optical and excitonic properties. It was understood already in the 1960s and recently rediscovered that many TMDs possess a high refractive index and optical anisotropy, which make them attractive for nullophotonic applications. However, accurate analysis and predictions of nullooptical phenomena require knowledge of dielectric constants along both in- and out-of-plane directions and over a broad spectral range, information that is often inaccessible or incomplete. Here, we present an experimental study of optical constants from several exfoliated TMD multilayers obtained using spectroscopic ellipsometry in the broad range of 300-1700 nm. The specific materials studied include semiconducting WS2, WSe2, MoS2, MoSe2, and MoTe2, as well as in-plane anisotropic ReS2 and WTe2 and metallic TaS2, TaSe2, and NbSe2. The extracted parameters demonstrate a high index (n up to similar to 4.84 for MoTe2), significant anisotropy (n(parallel to) - n(perpendicular to) approximate to 1.54 for MoTe2), and low absorption in the near-infrared region. Moreover, metallic TMDs show potential for combined plasmonic- dielectric behavior and hyperbolicity, as their plasma frequency occurs at around similar to 1000-1300 nm depending on the material. The knowledge of optical constants of these materials opens new experimental and computational possibilities for further development of all-TMD nullophotonics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 JUN 7", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acsphotonics.2c00433", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.2c00433", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819658400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, C; Guo, J; Jin, W; Wu, L; Peters, J; Xie, WQ; Chang, L; Shen, BQ; Wang, HM; Yang, QF; Kinghorn, D; Paniccia, M; Vahala, KJ; Morton, PA; Bowers, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Chao; Guo, Joel; Jin, Warren; Wu, Lue; Peters, Jonathan; Xie, Weiqiang; Chang, Lin; Shen, Boqiang; Wang, Heming; Yang, Qi-Fan; Kinghorn, David; Paniccia, Mario; Vahala, Kerry J.; Morton, Paul A.; Bowers, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance lasers for fully integrated silicon nitride photonics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving high output power and low noise integrated lasers is a major challenge. Here the authors experimentally demonstrate integrated lasers from a Si/SiN heterogeneous platform that shows Hertz-level linewidth, paving the way toward fully integrating low-noise silicon nitride photonics in volume using real devices for lasing. Silicon nitride (SiN) waveguides with ultra-low optical loss enable integrated photonic applications including low noise, narrow linewidth lasers, chip-scale nonlinear photonics, and microwave photonics. Lasers are key components to SiN photonic integrated circuits (PICs), but are difficult to fully integrate with low-index SiN waveguides due to their large mismatch with the high-index III-V gain materials. The recent demonstration of multilayer heterogeneous integration provides a practical solution and enabled the first-generation of lasers fully integrated with SiN waveguides. However, a laser with high device yield and high output power at telecommunication wavelengths, where photonics applications are clustered, is still missing, hindered by large mode transition loss, non-optimized cavity design, and a complicated fabrication process. Here, we report high-performance lasers on SiN with tens of milliwatts output power through the SiN waveguide and sub-kHz fundamental linewidth, addressing all the aforementioned issues. We also show Hertz-level fundamental linewidth lasers are achievable with the developed integration techniques. These lasers, together with high-Q SiN resonators, mark a milestone towards a fully integrated low-noise silicon nitride photonics platform. This laser should find potential applications in LIDAR, microwave photonics and coherent optical communications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6650, "DOI": "10.1038/s41467-021-26804-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26804-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720063500027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Zhao, R; Liu, MQ; Yang, JJ; Zhang, AQ; Yue, JS; Wu, C; Bai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yahui; Zhao, Ran; Liu, Mingquan; Yang, Jingjing; Zhang, Anqi; Yue, Jiasheng; Wu, Chuan; Bai, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressed Water Reactivity by Zincophilic-Hydrophobic Electrolyte Additive for Superior Aqueous Zn Metal Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As one of the most promising anodes of aqueous batteries, Zn metal faces uncontrollable side reactions and deleterious dendrite growth, which drastically compromise its cycle life and Coulombic efficiency (CE). To tackle these issues, a versatile electrolyte additive is reported that can regulate the solvation structure, adsorb on the Zn surface, and in situ generate a novel zincophilic-microhydrophobic interphase to isolate the anode from the reactive water molecules. Benefiting from its triple effects on the water reactivity modulation, the Zn metal anode exhibits excellent reversibility with an ultra-high average CE value of 99.92% at 5 mA cm-2 in the ZnSO4 electrolyte system, and the Zn||Zn symmetric cell with ethanesulfonamide additive achieves a long lifespan over 6000 h. The merits of ESA additives are further displayed in the Zn//MnO2 full cells and Zn ion hybrid capacitors, exhibiting excellent capacity retention of 81.60% at 5 C over 1000 cycles, and a 92.25% capacity retention over 50 000 cycles at 5 A g-1, respectively. What's more, the full cells exhibit outstanding stability of 100% capacity retention after 120 cycles at 0.1 C. This strategy shows a promising alternative for the further development of aqueous Zn metal batteries with low-cost ZnSO4-based electrolytes. Ethanesulfonamide is introduced into an aqueous ZnSO4 electrolyte to perform a triple effect of water activity suppression, which not only regulates the solvation structure of Zn2+, but also adsorbs on the Zn metal surface to repel the aggregation of water molecules, moreover, it can act as a barrier for water-related side reactions. Thus, an ultra-high plating/stripping efficiency and long cycle stability of 6000 h are achieved.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 13, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202302707", "DOI Link": "http://dx.doi.org/10.1002/aenm.202302707", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001073872400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WC; Lu, J; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wenchao; Lu, Jun; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and future perspectives on sodium and potassium ion batteries for grid-scale energy storage", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energy crisis and environmental pollution require the advancement of large-scale energy storage techniques. Among the various commercialized technologies, batteries have attracted enormous attention due to their relatively high energy density and long cycle life. Nevertheless, the limited supply and uneven distribution of lithium minerals, as well as their high cost, has greatly hindered the application of lithium-ion batteries in large-scale energy storage. Therefore, building next-generation alternative rechargeable batteries that feature low cost, long service life, and high safety is of the utmost importance. Over the past several years, we have witnessed many successful research outcomes for sodium and potassium ion batteries (SIBs and PIBs) in regard to electrode and electrolyte materials. In this Perspective, we summarize the current developments on SIBs/PIBs and their challenges when facing practical applications, including their cost, energy density, ion diffusivity in solids/electrolytes/interphases, cycle life, and safety concerns. Furthermore, we provide an overview of strategies to overcome the remaining challenges for achieving better electrochemical performance. Finally, we outline several possible directions for the future development of these two battery chemistries, with the hope of aiding the transition from the laboratory to next-generation practical applications for SIBs/PIBs batteries in grid-scale energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 400, "End Page": 417, "Article Number": null, "DOI": "10.1016/j.mattod.2021.03.015", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.03.015", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731397100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goy, RC; Morais, STB; Assis, OBG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goy, Rejane C.; Morais, Sinara T. B.; Assis, Odilio B. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluation of the antimicrobial activity of chitosan and its quaternized derivative on E-coli and S. aureus growth", "Source Title": "REVISTA BRASILEIRA DE FARMACOGNOSIA-BRAZILIAN JOURNAL OF PHARMACOGNOSY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chitosan is largely known for its activity against a wide range of microorganisms, in which the most acceptable antimicrobial mechanism is found to include the presence of charged groups in the polymer backbone and their ionic interactions with bacteria wall constituents. This interaction suggests the occurrence of a hydrolysis of the peptidoglycans in the microorganism wall, provoking the leakage of intracellular electrolytes, leading the microorganism to death. The charges present in chitosan chains are generated by protonation of amino groups when in acid medium or they may be introduced via structural modification. This latter can be achieved by a methylation reaction resulting in a quaternized derivative with a higher polymeric charge density. Since the charges in this derivative are permanents, it is expected a most efficient antimicrobial activity. Hence, in the present study, commercial chitosan underwent quaternization processes and both (mother polymer and derivative) were evaluated, in gel form, against Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative), as model bacteria. The results, as acquired from turbidity measurements, differ between materials with an expressive reduction on the Gram-positive microorganism (S. aureus) growth, while E. coli (Gram-negative) strain was less sensitive to both polymers. Additionally, the antibacterial effectiveness of chitosan was strongly dependent on the concentration, what is discussed in terms of spatial polymer conformation. (C) 2015 Sociedade Brasileira de Farmacognosia. Published by Elsevier Editora Ltda. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 401, "Times Cited, All Databases": 423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2016, "Volume": 26, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 122, "End Page": 127, "Article Number": null, "DOI": "10.1016/j.bjp.2015.09.010", "DOI Link": "http://dx.doi.org/10.1016/j.bjp.2015.09.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370121400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YYC; Davies, DM; Yin, YJ; Borodin, O; Lee, JZ; Fang, CC; Olguin, M; Zhang, YH; Sablina, ES; Wang, XF; Rustomji, CS; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yangyuchen; Davies, Daniel M.; Yin, Yijie; Borodin, Oleg; Lee, Jungwoo Z.; Fang, Chengcheng; Olguin, Marco; Zhang, Yihui; Sablina, Ekaterina S.; Wang, Xuefeng; Rustomji, Cyrus S.; Meng, Y. Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Efficiency Lithium-Metal Anode Enabled by Liquefied Gas Electrolytes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among the several challenges to enable next-generation batteries is the development of an electrolyte that maintains a dendrite-free and high Coulombic efficiency lithium-metal anode over extended cell cycling. A new electrolyte solvation structure and transport mechanism is demonstrated in fluoromethane-based liquefied gas electrolytes with the introduction of additive amounts of tetrahydrofuran, which is shown to fully coordinate with the lithium cations and greatly enhance salt dissociation and transport. The resulting electrolyte shows a high conductivity and transference number (t(+) > 0.79), which leads to a dramatic improvement of the cycling performance of the lithium-metal anode. Systems using the enhanced liquefied gas electrolytes demonstrate a long-term high average Coulombic efficiency of 99.6%, 99.4%, and 98.1% (+/- 0.3%) at capacities of 0.5, 1, and 3 mAh.cm(-2), respectively, with dendrite-free morphology and remarkable rate capability. Both the rate and cycling performance are well maintained from +20 degrees C to -60 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2019, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1986, "End Page": 2000, "Article Number": null, "DOI": "10.1016/j.joule.2019.06.008", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.06.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482204600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Frost, JM; Harriman, KLM; Murugesu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Frost, Jamie M.; Harriman, Katie L. M.; Murugesu, Muralee", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion magnets) theoretically represent the smallest possible unit for spin-based electronic devices. The realisation of this and related technologies, depends on first being able to design systems with sufficiently large energy barriers to magnetisation reversal, U-eff, and secondly, on being able to organise these molecules into addressable arrays. In recent years, significant progress has been made towards the former goal - principally as a result of efforts which have been directed towards studying complexes based on highly anisotropic lanthanide ions, such as Tb(III) and Dy(III). Since 2013 however, and the remarkable report by Long and co-workers of a linear Fe(I) system exhibiting U-eff = 325 K, single-ion systems of transition metals have undergone something of a renaissance in the literature. Not only do they have important lessons to teach us about anisotropy and relaxation dynamics in the quest to enhance U-eff, the ability to create strongly coupled spin systems potentially offers access to a whole of host of 1, 2 and 3-dimensional materials with interesting structural and physical properties. This perspective summarises recent progress in this rapidly expanding sub-genre of molecular magnetism from the viewpoint of the synthetic chemist, with a particular focus on the lessons that have so far been learned from single-ion magnets of the d-block, and, the future research directions which we feel are likely to emerge in the coming years.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 523, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2470, "End Page": 2491, "Article Number": null, "DOI": "10.1039/c5sc03224e", "DOI Link": "http://dx.doi.org/10.1039/c5sc03224e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372614800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pham, MS; Dovgyy, B; Hooper, PA; Gourlay, CM; Piglione, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Minh-Son Pham; Dovgyy, Bogdan; Hooper, Paul A.; Gourlay, Christopher M.; Piglione, Alessandro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of side-branching in microstructure development in laser powder-bed fusion", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In-depth understanding of microstructure development is required to fabricate high quality products by additive manufacturing (for example, 3D printing). Here we report the governing role of side-branching in the microstructure development of alloys by laser powder bed fusion. We show that perturbations on the sides of cells (or dendrites) facilitate crystals to change growth direction by side-branching along orthogonal directions in response to changes in local heat flux. While the continuous epitaxial growth is responsible for slender columnar grains confined to the centreline of melt pools, side-branching frequently happening on the sides of melt pools enables crystals to follow drastic changes in thermal gradient across adjacent melt pools, resulting in substantial broadening of grains. The variation of scan pattern can interrupt the vertical columnar microstructure, but promotes both in-layer and out-of-layer side-branching, in particular resulting in the helical growth of microstructure in a chessboard strategy with 67 degrees rotation between layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 749, "DOI": "10.1038/s41467-020-14453-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14453-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563522300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FC; MacDonald, AH; Martin, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fengcheng; MacDonald, A. H.; Martin, Ivar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of Phonon-Mediated Superconductivity in Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a theory of phonon-mediated superconductivity in near magic angle twisted bilayer graphene. Using a microscopic model for phonon coupling to moire band electrons, we find that phonons generate attractive interactions in both s- and d-wave pairing channels and that the attraction is strong enough to explain the experimental superconducting transition temperatures. Before including Coulomb repulsion, the s-wave channel is more favorable; however, on-site Coulomb repulsion can suppress s-wave pairing relative to d wave. The pair amplitude varies spatially with the moire period, and is identical in the two layers in the s-wave channel but phase shifted by pi in the d-wave channel. We discuss experiments that can distinguish the two pairing states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 402, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2018, "Volume": 121, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 257001, "DOI": "10.1103/PhysRevLett.121.257001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.257001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454178600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, L; Lee, O; Bhowmik, D; Labanowski, D; Hong, J; Bokor, J; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Long; Lee, OukJae; Bhowmik, Debanjan; Labanowski, Dominic; Hong, Jeongmin; Bokor, Jeffrey; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switching of perpendicularly polarized nullomagnets with spin orbit torque without an external magnetic field by engineering a tilted anisotropy", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin orbit torque (SOT) provides an efficient way to significantly reduce the current required for switching nullomagnets. However, SOT generated by an in-plane current cannot deterministically switch a perpendicularly polarized magnet due to symmetry reasons. On the other hand, perpendicularly polarized magnets are preferred over in-plane magnets for high-density data storage applications due to their significantly larger thermal stability in ultrascaled dimensions. Here, we show that it is possible to switch a perpendicularly polarized magnet by SOT without needing an external magnetic field. This is accomplished by engineering an anisotropy in the magnets such that the magnetic easy axis slightly tilts away from the direction, normal to the film plane. Such a tilted anisotropy breaks the symmetry of the problem and makes it possible to switch the magnet deterministically. Using a simple Ta/CoFeB/MgO/Ta heterostructure, we demonstrate reversible switching of the magnetization by reversing the polarity of the applied current. This demonstration presents a previously unidentified approach for controlling nullomagnets with SOT.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2015, "Volume": 112, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10310, "End Page": 10315, "Article Number": null, "DOI": "10.1073/pnas.1507474112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1507474112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359738300058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, RJ; Jiang, XY; Fu, JH; Zhu, T; Yan, CQ; Wu, KX; Müller-Buschbaum, P; Li, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Ruijie; Jiang, Xinyu; Fu, Jiehao; Zhu, Tao; Yan, Cenqi; Wu, Kexin; Mueller-Buschbaum, Peter; Li, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the underlying solvent effect on film morphology in high-efficiency organic solar cells through combined ex situ and in situ observations", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The morphological features and the film formation processes in high-performance donor-acceptor binary photovoltaic blends cast from three representative solvents are carefully investigated and analyzed. The PM6:L8-BO system shows a very significant efficiency change on varying the solvent from chloroform (CF) to chlorobenzene (CB) and o-xylene (XY), whereas the PM6:eC9 system shows limited influence of the solvent used. Ex situ characterization studies have revealed that CB and XY cause too-pronounced phase separation for PM6:L8-BO. In contrast, PM6:eC9 films display only slightly enhanced phase segregation in CB films and even better mixing in XY-processed films. The in situ observations further reveal that the PM6 aggregation-dominated stage during film formation is longer for the eC9 system than for L8-BO, effectively suppressing the separation of donors and acceptors. PM6 is found to be highly miscible with the acceptors when processed from XY. The ex situ analysis results correlate well with the device performance and are finely explained by the in situ and miscibility study. Furthermore, an excellent device efficiency of 19.10% (verified 18.77%) is achieved using a ternary design for XY-enabled organic solar cells (OSCs) with PTQ10, while the corresponding blade coating devices present an excellent PCE of 18.25%. Thereby, this work provides a clear understanding of film morphology formation and enables the realization of high-performance non-halogenated solvent-processed OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2023, "Volume": 16, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2316, "End Page": 2326, "Article Number": null, "DOI": "10.1039/d3ee00294b", "DOI Link": "http://dx.doi.org/10.1039/d3ee00294b", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000975138000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, WH; Sun, HL; Hu, XY; Bai, X; Fan, J; Liu, EZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Wenhua; Sun, Hongli; Hu, Xiaoyun; Bai, Xue; Fan, Jun; Liu, Enzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "UV-VIS-NIR-induced extraordinary H2 evolution over W18O49/Cd0.5Zn0.5S: Surface plasmon effect coupled with S-scheme charge transfer", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a novel plasmon-assisted UV-vis-NIR-driven W18O49/Cd0.5Zn0.5S heterostructure photocatalyst was obtained by a facile ultrasonic-assisted electrostatic self-assembly strategy. The hybrid exhibits extraordinary H-2 evolution activity of 147.7 mmol.g(-1).h(-1) at room temperature due to the efficient charge separation and expanded light absorption. Our investigation shows that the unique Step-scheme (S-scheme) charge transfer and the 'hot electron' injection are both responsible for the extraordinary H-2 evolution process, depending on the wavelength of the incident light. Moreover, by accelerating the surface reaction kinetics, the activity can be further elevated to 306.1 mmol.g(-1).h(-1), accompanied by a high apparent quantum yield of 45.3% at 365 +/- 7.5 nm. This work provides us a potential strategy for the highly efficient conversion of the solar energy by elaborately combining a nonstoichiometric ratio plasmonic material with an appropriate active photocatalyst. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 234, "End Page": 245, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63783-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63783-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pastewka, L; Robbins, MO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pastewka, Lars; Robbins, Mark O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contact between rough surfaces and a criterion for macroscopic adhesion", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At the molecular scale, there are strong attractive interactions between surfaces, yet few macroscopic surfaces are sticky. Extensive simulations of contact by adhesive surfaces with roughness on nullometer to micrometer scales are used to determine how roughness reduces the area where atoms contact and thus weakens adhesion. The material properties, adhesive strength, and roughness parameters are varied by orders of magnitude. In all cases, the area of atomic contact is initially proportional to the load. The prefactor rises linearly with adhesive strength for weak attractions. Above a threshold adhesive strength, the prefactor changes sign, the surfaces become sticky, and a finite force is required to separate them. A parameter-free analytic theory is presented that describes changes in these numerical results over up to five orders of magnitude in load. It relates the threshold adhesive strength to roughness and material properties, explaining why most macroscopic surfaces do not stick. The numerical results are qualitatively and quantitatively inconsistent with classical theories based on the Greenwood-Williamson approach that neglect the range of adhesion and do not include asperity interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2014, "Volume": 111, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3298, "End Page": 3303, "Article Number": null, "DOI": "10.1073/pnas.1320846111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1320846111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332560300034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Domínguez-Robles, J; Martin, NK; Fong, ML; Stewart, SA; Irwin, NJ; Rial-Hermida, MI; Donnelly, RF; Larrañeta, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dominguez-Robles, Juan; Martin, Niamh K.; Fong, Mun Leon; Stewart, Sarah A.; Irwin, Nicola J.; Rial-Hermida, Maria Isabel; Donnelly, Ryan F.; Larraneta, Eneko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antioxidant PLA Composites Containing Lignin for 3D Printing Applications: A Potential Material for Healthcare Applications", "Source Title": "PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lignin (LIG) is a natural biopolymer with well-known antioxidant capabilities. Accordingly, in the present work, a method to combine LIG with poly(lactic acid) (PLA) for fused filament fabrication applications (FFF) is proposed. For this purpose, PLA pellets were successfully coated with LIG powder and a biocompatible oil (castor oil). The resulting pellets were placed into an extruder at 200 degrees C. The resulting PLA filaments contained LIG loadings ranging from 0% to 3% (w/w). The obtained filaments were successfully used for FFF applications. The LIG content affected the mechanical and surface properties of the overall material. The inclusion of LIG yielded materials with lower resistance to fracture and higher wettabilities. Moreover, the resulting 3D printed materials showed antioxidant capabilities. By using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) method, the materials were capable of reducing the concentration of this compound up to ca. 80% in 5 h. This radical scavenging activity could be potentially beneficial for healthcare applications, especially for wound care. Accordingly, PLA/LIG were used to design meshes with different designs for wound dressing purposes. A wound healing model compound, curcumin (CUR), was applied in the surface of the mesh and its diffusion was studied. It was observed that the dimensions of the meshes affected the permeation rate of CUR. Accordingly, the design of the mesh could be modified according to the patient's needs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 165, "DOI": "10.3390/pharmaceutics11040165", "DOI Link": "http://dx.doi.org/10.3390/pharmaceutics11040165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467301400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pauliuk, S; Heeren, N; Berrill, P; Fishman, T; Nistad, A; Tu, QS; Wolfram, P; Hertwich, EG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pauliuk, Stefan; Heeren, Niko; Berrill, Peter; Fishman, Tomer; Nistad, Andrea; Tu, Qingshi; Wolfram, Paul; Hertwich, Edgar G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global scenarios of resource and emission savings from material efficiency in residential buildings and cars", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Material production accounts for a quarter of global greenhouse gas (GHG) emissions. Resource-efficiency and circular-economy strategies, both industry and demand-focused, promise emission reductions through reducing material use, but detailed assessments of their GHG reduction potential are lacking. We present a global-scale analysis of material efficiency for passenger vehicles and residential buildings. We estimate future changes in material flows and energy use due to increased yields, light design, material substitution, extended service life, and increased service efficiency, reuse, and recycling. Together, these strategies can reduce cumulative global GHG emissions until 2050 by 20-52 Gt CO2-eq (residential buildings) and 13-26 Gt CO(2)e-eq (passenger vehicles), depending on policy assumptions. Next to energy efficiency and low-carbon energy supply, material efficiency is the third pillar of deep decarbonization for these sectors. For residential buildings, wood construction and reduced floorspace show the highest potential. For passenger vehicles, it is ride sharing and car sharing. Material production accounts for a quarter of global greenhouse gas emissions. Here, the authors show that resource efficiency and circular-economy strategies can allow for cumulative emission reductions of 20-52 Gt CO2-eq from residential buildings and 13-26 Gt CO2e-eq from cars by 2050.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5097, "DOI": "10.1038/s41467-021-25300-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25300-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000688006200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rieth, AJ; Yang, S; Wang, EN; Dinca, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rieth, Adam J.; Yang, Sungwoo; Wang, Evelyn N.; Dinca, Mircea", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Record Atmospheric Fresh Water Capture and Heat Transfer with a Material Operating at the Water Uptake Reversibility Limit", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The capture of water vapor at low relative humidity is desirable for producing potable water in desert regions and for heat transfer and storage. Here, we report a mesoporous metal-organic framework that captures 82% water by weight below 30% relative humidity. Under simulated desert conditions, the sorbent would deliver 0.82 g(H2O) g(MOF)(-1)) nearly double the quantity of fresh water compared to the previous best material. The material further demonstrates a cooling capacity of 400 kWh m(-3) per cycle, also a record value for a sorbent capable of creating a 20 degrees C difference between ambient and output temperature. The water uptake in this sorbent is optimized: the pore diameter of our material is above the critical diameter for water capillary action, enabling water uptake at the limit of reversibility.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 668, "End Page": 672, "Article Number": null, "DOI": "10.1021/acscentsci.7b00186", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.7b00186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404825000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, Y; Huang, ZB; Wang, YC; Zhou, Q; Yang, T; Li, QK; Jia, Q; Wang, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Yue; Huang, Zhuobin; Wang, Yucheng; Zhou, Qing; Yang, Tao; Li, Qikang; Jia, Qian; Wang, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Friction-induced rapid amorphization in a wear-resistant (CoCrNi)88Mo12 dual-phase medium-entropy alloy at cryogenic temperature", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The CoCrNi medium-entropy alloy (MEA) has been proven to have excellent mechanical properties under cryogenic temperatures. Its low yield strength, however, limits practical application under harsh conditions, e.g., wear. Here, the (CoCrNi)88Mo12 dual-phase MEA, comprising a ductile face-centered cubic (FCC) matrix and a hard & sigma; phase, was fabricated to strengthen the matrix and achieve excellent cryogenic wear performance. A significant wear reduction of 73% is achieved as the temperature decreases from 233 K to 113 K. It is found that the friction-induced amorphous layer underneath the worn surface contributes to excellent wear behaviors at 113 K, and amorphization would be rapidly occurred within 10 s. A lower stacking fault energy of CoCrNi-rich matrix at cryogenic temperature and a high solute concentration of Mo contribute to more defect accumulation and increased free energy of the system for amorphization. The current work clarifies the cryogenic wear mechanisms of the (CoCrNi)88Mo12 dual-phase MEA and provides a novel strategy for designing wear-resistant alloys via friction-induced rapid amorphization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2023, "Volume": 263, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110833, "DOI": "10.1016/j.compositesb.2023.110833", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2023.110833", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054541600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McCall, KM; Morad, V; Benin, BM; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McCall, Kyle M.; Morad, Viktoriia; Benin, Bogdan M.; Kovalenko, Maksym, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Lone-Pair-Driven Luminescence: Structure-Property Relationships in Emissive 5s2 Metal Halides", "Source Title": "ACS MATERIALS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-dimensional metal halides have been the focus of intense investigations in recent years following the success of hybrid lead halide perovskites as optoelectronic materials. In particular, the light emission of low-dimensional halides based on the 5s(2) cations Sn2+ and Sb3+ has found utility in a variety of applications complementary to those of the three-dimensional halide perovskites because of its unusual properties such as broadband character and highly temperature-dependent lifetime. These properties derive from the exceptional chemistry of the 5s(2) lone pair, but the terminology and explanations given for such emission vary widely, hampering efforts to build a cohesive understanding of these materials that would lead to the development of efficient optoelectronic devices. In this Perspective, we provide a structural overview of these materials with a focus on the dynamics driven by the stereoactivity of the 5s(2) lone pair to identify the structural features that enable strong emission. We unite the different theoretical models that have been able to explain the success of these bright 5s(2) emission centers into a cohesive framework, which is then applied to the array of compounds recently developed by our group and other researchers, demonstrating its utility and generating a holistic picture of the field from the point of view of a materials chemist. We highlight those state-of-the-art materials and applications that demonstrate the unique capabilities of these versatile emissive centers and identify promising future directions in the field of low-dimensional 5s(2) metal halides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2020, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1218, "End Page": 1232, "Article Number": null, "DOI": "10.1021/acsmaterialslett.0c00211", "DOI Link": "http://dx.doi.org/10.1021/acsmaterialslett.0c00211", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571390700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Greczynski, G; Hultman, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Greczynski, Grzegorz; Hultman, Lars", "Book Author Full Names": null, "Group Authors": null, "Article Title": "C1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy", "Source Title": "CHEMPHYSCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The C1s signal from ubiquitous carbon contamination on samples forming during air exposure, so called adventitious carbon (AdC) layers, is the most common binding energy (BE) reference in X-ray photoelectron spectroscopy studies. We demonstrate here, by using a series of transition-metal nitride films with different AdC coverage, that the BE of the C1s peak E-B(F) varies by as much as 1.44 eV. This is a factor of 10 more than the typical resolvable difference between two chemical states of the same element, which makes BE referencing against the C1s peak highly unreliable. Surprisingly, we find that C1s shifts correlate to changes in sample work function phi(SA), such that the sum E-B(F) + phi(SA) is constant at 289.50 +/- 0.15 eV, irrespective of materials system and air exposure time, indicating vacuum level alignment. This discovery allows for significantly better accuracy of chemical state determination than offered by the conventional methods. Our findings are not specific to nitrides and likely apply to all systems in which charge transfer at the AdC/substrate interface is negligible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 860, "Times Cited, All Databases": 884, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 18, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1507, "End Page": 1512, "Article Number": null, "DOI": "10.1002/cphc.201700126", "DOI Link": "http://dx.doi.org/10.1002/cphc.201700126", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403885800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, L; Huang, JY; Qu, LJ; Chen, XH; Zhu, Y; Li, C; Tian, QC; Zhao, YL; Yang, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Liang; Huang, Jiayue; Qu, Lunjun; Chen, Xiaohong; Zhu, Ying; Li, Chen; Tian, Quanchi; Zhao, Yanli; Yang, Chaolong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stepwise taming of triplet excitons via multiple confinements in intrinsic polymers for long-lived room-temperature phosphorescence", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymeric materials exhibiting room temperature phosphorescence (RTP) show a promising application potential. However, the conventional ways of preparing such materials are mainly focused on doping, which may suffer from phase separation, poor compatibility, and lack of effective methods to promote intersystem crossing and suppress the nonradiative deactivation rates. Herein, we present an intrinsically polymeric RTP system producing long-lived phosphorescence, high quantum yields and multiple colors by stepwise structural confinement to tame triplet excitons. In this strategy, the performance of the materials is improved in two aspects simultaneously: the phosphorescence lifetime of one polymer (9VA-B) increased more than 4 orders of magnitude, and the maximum phosphorescence quantum yield reached 16.04% in halogen-free polymers. Moreover, crack detection is realized by penetrating steam through the materials exposed to humid surroundings as a special quenching effect, and the information storage is carried out by employing the Morse code and the variations in lifetimes. This study provides a different strategy for constructing intrinsically polymeric RTP materials toward targeted applications. Materials with room temperature phosphorescence have potential in a range of applications, but preparing the systems can still be challenging. Here, the authors report an intrinsically polymeric room temperature phosphorescent material, applied in crack detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7252, "DOI": "10.1038/s41467-023-43133-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43133-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001103080000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gottscholl, A; Diez, M; Soltamov, V; Kasper, C; Krausse, D; Sperlich, A; Kianinia, M; Bradac, C; Aharonovich, I; Dyakonov, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gottscholl, Andreas; Diez, Matthias; Soltamov, Victor; Kasper, Christian; Krausse, Dominik; Sperlich, Andreas; Kianinia, Mehran; Bradac, Carlo; Aharonovich, Igor; Dyakonov, Vladimir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin defects in hBN as promising temperature, pressure and magnetic field quantum sensors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin defects in two-dimensional materials potentially offer unique advantages for quantum sensing in terms of sensitivity and functionality. Here, the authors demonstrate the use of spin defects in hexagonal boron nitride as sensors of magnetic field, temperature and pressure, and show that their performance is comparable or exceeds that of existing platforms. Spin defects in solid-state materials are strong candidate systems for quantum information technology and sensing applications. Here we explore in details the recently discovered negatively charged boron vacancies (V-B(-)) in hexagonal boron nitride (hBN) and demonstrate their use as atomic scale sensors for temperature, magnetic fields and externally applied pressure. These applications are possible due to the high-spin triplet ground state and bright spin-dependent photoluminescence of the V-B(-). Specifically, we find that the frequency shift in optically detected magnetic resonullce measurements is not only sensitive to static magnetic fields, but also to temperature and pressure changes which we relate to crystal lattice parameters. We show that spin-rich hBN films are potentially applicable as intrinsic sensors in heterostructures made of functionalized 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4480, "DOI": "10.1038/s41467-021-24725-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24725-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683505900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, DF; Jiang, YY; Ding, J; Zhang, SH; Wang, ZA; Xiao, RC; Gurung, G; Lu, WJ; Sun, YP; Tsymbal, EY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Ding-Fu; Jiang, Yuan-Yuan; Ding, Jun; Zhang, Shu-Hui; Wang, Zi-An; Xiao, Rui-Chun; Gurung, Gautam; Lu, W. J.; Sun, Y. P.; Tsymbal, Evgeny Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neel Spin Currents in Antiferromagnets", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferromagnets are known to support spin-polarized currents that control various spin-dependent transport phenomena useful for spintronics. On the contrary, fully compensated antiferromagnets are expected to support only globally spin-neutral currents. Here, we demonstrate that these globally spin-neutral currents can represent the Neel spin currents, i.e., staggered spin currents flowing through different magnetic sublattices. The Neel spin currents emerge in antiferromagnets with strong intrasublattice coupling (hopping) and drive the spin-dependent transport phenomena such as tunneling magnetoresistance (TMR) and spin-transfer torque (STT) in antiferromagnetic tunnel junctions (AFMTJs). Using RuO2 and Fe4GeTe2 as representative antiferromagnets, we predict that the Neel spin currents with a strong staggered spin polarization produce a sizable fieldlike STT capable of the deterministic switching of the Neel vector in the associated AFMTJs. Our work uncovers the previously unexplored potential of fully compensated antiferromagnets and paves a new route to realize the efficient writing and reading of information for antiferromagnetic spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2023, "Volume": 130, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 216702, "DOI": "10.1103/PhysRevLett.130.216702", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.130.216702", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004221400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chun, SH; Kim, JW; Kim, J; Zheng, H; Stoumpos, CC; Malliakas, CD; Mitchell, JF; Mehlawat, K; Singh, Y; Choi, Y; Gog, T; Al-Zein, A; Sala, MM; Krisch, M; Chaloupka, J; Jackeli, G; Khaliullin, G; Kim, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chun, Sae Hwan; Kim, Jong-Woo; Kim, Jungho; Zheng, H.; Stoumpos, Constantinos C.; Malliakas, C. D.; Mitchell, J. F.; Mehlawat, Kavita; Singh, Yogesh; Choi, Y.; Gog, T.; Al-Zein, A.; Sala, M. Moretti; Krisch, M.; Chaloupka, J.; Jackeli, G.; Khaliullin, G.; Kim, B. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct evidence for dominullt bond-directional interactions in a honeycomb lattice iridate Na2IrO3", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heisenberg interactions are ubiquitous in magnetic materials and play a central role in modelling and designing quantum magnets. Bond-directional interactions(1-3) offer a novel alternative to Heisenberg exchange and provide the building blocks of the Kitaev model(4), which has a quantum spin liquid as its exact ground state. Honeycomb iridates, A(2)IrO(3) (A = Na, Li), offer potential realizations of the Kitaev magnetic exchange coupling, and their reported magnetic behaviour may be interpreted within the Kitaev framework. However, the extent of their relevance to the Kitaev model remains unclear, as evidence for bond-directional interactions has so far been indirect. Herewe present direct evidence for dominullt bond-directional interactions in antiferromagnetic Na2IrO3 and show that they lead to strong magnetic frustration. Diffuse magnetic X-ray scattering reveals broken spin-rotational symmetry even above the Neel temperature, with the three spin components exhibiting short-range correlations along distinct crystallographic directions. This spin- and real-space entanglement directly uncovers the bond-directional nature of these interactions, thus providing a direct connection between honeycomb iridates and Kitaev physics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 462, "End Page": "U183", "Article Number": null, "DOI": "10.1038/NPHYS3322", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3322", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355552200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pagoulatou, M; Sheehan, T; Dai, XH; Lam, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pagoulatou, M.; Sheehan, T.; Dai, X. H.; Lam, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Finite element analysis on the capacity of circular concrete-filled double-skin steel tubular (CFDST) stub columns", "Source Title": "ENGINEERING STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents the behaviour of circular concrete-filled double-skin steel tubular (CFDST) stub columns compressed under concentric axial loads. To predict the performance of such columns, a finite element analysis is conducted. Herein, for the accurate modelling of the double-skin specimens, the identification of suitable material properties for both the concrete infill and steel tubes is crucial. The applied methodology is validated through comparisons of the results obtained from the finite element analysis with those from past experiments. Aiming to examine the effect of various diameter-to-thickness (D/t) ratios, concrete cube strengths and steel yield strengths on the overall behaviour and ultimate resistance of the double-skin columns, a total of twenty-five models are created to conduct the parametric study. In addition, four circular concrete-filled steel tubes (CFST) are included to check the dissimilarities, in terms of their behaviour and weight, when compared with identical double-skin tubes. A new formula based on Eurocode 4 is proposed to evaluate the strength of the double-skin specimens. Based on the comparison between the results derived from the analysis, the proposed formulae for the concrete filled double-skin would appear to be satisfactory. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2014, "Volume": 72, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 102, "End Page": 112, "Article Number": null, "DOI": "10.1016/j.engstruct.2014.04.039", "DOI Link": "http://dx.doi.org/10.1016/j.engstruct.2014.04.039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337874200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZJ; Alexandradinata, A; Cava, RJ; Bernevig, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhijun; Alexandradinata, A.; Cava, R. J.; Bernevig, B. Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hourglass fermions", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spatial symmetries in crystals may be distinguished by whether they preserve the spatial origin. Here we study spatial symmetries that translate the origin by a fraction of the lattice period, and find that these non-symmorphic symmetries protect an exotic surface fermion whose dispersion relation is shaped like an hourglass; surface bands connect one hourglass to the next in an unbreakable zigzag pattern. These 'hourglass' fermions are formed in the large-gap insulators, KHgX (X = As, Sb, Bi), which we propose as the first material class whose band topology relies on non-symmorphic symmetries. Besides the hourglass fermion, another surface of KHgX manifests a three-dimensional generalization of the quantum spin Hall effect, which has previously been observed only in two-dimensional crystals. To describe the bulk topology of non-symmorphic crystals, we propose a non-Abelian generalization of the geometric theory of polarization. Our non-trivial topology originates from an inversion of the rotational quantum numbers, which we propose as a criterion in the search for topological materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2016, "Volume": 532, "Issue": 7598, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 189, "End Page": 194, "Article Number": null, "DOI": "10.1038/nature17410", "DOI Link": "http://dx.doi.org/10.1038/nature17410", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374415100030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ai, MH; Pan, L; Shi, CX; Huang, ZF; Zhang, XW; Mi, WB; Zou, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ai, Minhua; Pan, Lun; Shi, Chengxiang; Huang, Zhen-Feng; Zhang, Xiangwen; Mi, Wenbo; Zou, Ji-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin selection in atomic-level chiral metal oxide for photocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin degree of freedom is an important and intrinsic parameter in boosting carrier dynamics and surface reaction kinetics of photocatalysis. Here we show that chiral structure in ZnO can induce spin selectivity effect to promote photocatalytic performance. The ZnO crystals synthesized using chiral methionine molecules as symmetry-breaking agents show hierarchical chirality. Magnetic circular dichroism spectroscopic and magnetic conductive-probe atomic force microscopic measurements demonstrate that chiral structure acts as spin filters and induces spin polarization in photoinduced carriers. The polarized carriers not only possess the prolonged carrier lifetime, but also increase the triplet species instead of singlet byproducts during reaction. Accordingly, the left- and right-hand chiral ZnO exhibit 2.0- and 1.9-times higher activity in photocatalytic O-2 production and 2.5- and 2.0-times higher activities in contaminullt photodegradation, respectively, compared with achiral ZnO. This work provides a feasible strategy to manipulate the spin properties in metal oxides for electron spin-related redox catalysis. The spin degree of freedom is a key intrinsic parameter for carrier dynamics and surface reaction kinetics in photocatalysis. Here, the authors report a chiral zinc oxide with spin selectivity effect. It can effectively induce spin polarization, thereby promoting electron spin-related redox catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4562, "DOI": "10.1038/s41467-023-40367-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40367-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001040551400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HT; Sun, Q; Zhong, Y; Deng, Q; Gan, L; Lv, FL; Shi, XL; Chen, ZG; Ang, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hang-Tian; Sun, Qiang; Zhong, Yan; Deng, Qian; Gan, Lin; Lv, Fang-Lin; Shi, Xiao-Lei; Chen, Zhi-Gang; Ang, Ran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance in n-type PbTe-based thermoelectric materials achieved by synergistically dynamic doping and energy filtering", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of n-type high-performance PbTe thermoelectric materials for matching its p-type counterparts is an urgent matter to expand its practical applications. Here, we introduce Ag2Te into n-type Pb0.975Cr0.025Te for achieving a high peak figure of merit of 1.5 at 773 K. Such a high value is attributed to the synergistic optimization of carrier and phonon transports by Ag2Te introducing and the dynamic doping of Ag. From the detailed structure and property analysis, we found that Ag2Te nulloprecipitates establish coherent interfaces and hence potential barriers with the matrix to induce energy-dependent carrier scattering and maintain relatively high carrier mobility, leading to an optimal electrical-transport properties over a wide temperature range. Moreover, we employ comprehensive electron microscopy investigations and approximate Debye-Callaway model to reveal the origin of the significantly reduced lattice thermal conductivity in Ag2Te-alloyed Pb0.975Cr0.025Te. The strategies used here provide an effective method for designing high-performance thermoelectric material systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 91, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106706, "DOI": "10.1016/j.nulloen.2021.106706", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2021.106706", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720184500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, J; Wong, LNY; Teh, CI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Jun; Wong, Louis Ngai Yuen; Teh, Cee Ing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of grain size heterogeneity on strength and microcracking behavior of crystalline rocks", "Source Title": "JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study numerically investigates the influence of material heterogeneity on the strength and deformation behavior and the associated microcracking process of a felsic crystalline rock using a grain-based modeling approach in two-dimensional Particle Flow Code. By using a heterogeneity index defined in this study, the heterogeneity induced by variation of grain size distribution can be explicitly incorporated into the numerical specimen models quantitatively. Under compressive loading, the peak strength and the elastic modulus are found to increase as the numerical model gradually changes from heterogeneous to homogeneous, i.e., a decrease of heterogeneity index. Meanwhile, the number of grain boundary tensile cracks gradually decreases and the number of intragrain cracks increases at the moment of failure. However, the total number of generated microcracks seems not to be significantly influenced by heterogeneity. The orientation of grain boundary microcracks is mainly controlled by the geometry of assembled grain structure of the numerical specimen model, while the orientation of intragrain microcracks is to a large degree influenced by the confinement. In addition, the development of intragrain cracks (both tensile and shear) is much more favored in quartz than in other minerals. Under direct tensile loading, heterogeneity is found to have no significant influence on the simulated stress-strain responses and rock strength. Only grain boundary tensile cracks are generated when the numerical models are loaded in direct tension, and the position of generated macroscopic fracture developed upon failure of the specimen is largely affected by heterogeneity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 122, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1054, "End Page": 1073, "Article Number": null, "DOI": "10.1002/2016JB013469", "DOI Link": "http://dx.doi.org/10.1002/2016JB013469", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396132200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trail, MA; Zhang, C; Morin, TJ; Chang, L; Barik, S; Yuan, ZQ; Lee, W; Kim, G; Malik, A; Zhang, ZY; Guo, OE; Wang, HM; Shen, BQ; Wu, LE; Vahala, K; Bowers, J; Park, H; Komljenovic, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trail, Minh A.; Zhang, Chong; Morin, Theodore J.; Chang, Lin; Barik, Sabyasachi; Yuan, Zhiquan; Lee, Woonghee; Kim, Glenn; Malik, Aditya; Zhang, Zeyu; Guo, Joel; Wang, Heming; Shen, Boqiang; Wu, Lue; Vahala, Kerry; Bowers, JohnE; Park, Hyundai; Komljenovic, Tin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extending the spectrum of fully integrated photonics to submicrometre wavelengths", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Integrated photonics has profoundly affected a wide range of technologies underpinning modern society(1-4). The ability to fabricate a complete optical system on a chip offers unrivalled scalability, weight, cost and power efficiency(5,6). Over the last decade, the progression from pure III-V materials platforms to silicon photonics has significantly broadened the scope of integrated photonics, by combining integrated lasers with the high-volume, advanced fabrication capabilities of the commercial electronics industry(7,8). Yet, despite remarkable manufacturing advantages, reliance on silicon-based waveguides currently limits the spectral window available to photonic integrated circuits (PICs). Here, we present a new generation of integrated photonics by directly uniting III-V materials with silicon nitride waveguides on Si wafers. Using this technology, we present a fully integrated PIC at photon energies greater than the bandgap of silicon, demonstrating essential photonic building blocks, including lasers, amplifiers, photodetectors, modulators and passives, all operating at submicrometre wavelengths. Using this platform, we achieve unprecedented coherence and tunability in an integrated laser at short wavelength. Furthermore, by making use of this higher photon energy, we demonstrate superb high-temperature performance and kHz-level fundamental linewidths at elevated temperatures. Given the many potential applications at short wavelengths, the success of this integration strategy unlocks a broad range of new integrated photonics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2022, "Volume": 610, "Issue": 7930, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 54, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05119-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05119-9", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000861426000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weber, MC; Guennou, M; Zhao, HJ; Iñiguez, J; Vilarinho, R; Almeida, A; Moreira, JA; Kreisel, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weber, Mads Christof; Guennou, Mael; Zhao, Hong Jian; Iniguez, Jorge; Vilarinho, Rui; Almeida, Abilio; Moreira, Joaquim Agostinho; Kreisel, Jens", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman spectroscopy of rare-earth orthoferrites RFeO3 (R=La, Sm, Eu, Gd, Tb, Dy)", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a Raman scattering study of six rare-earth orthoferrites RFeO3, with R=La, Sm, Eu, Gd, Tb, Dy. The use of extensive polarized Raman scattering of SmFeO3 and first-principles calculations enable the assignment of the observed phonon modes to vibrational symmetries and atomic displacements. The assignment of the spectra and their comparison throughout the whole series allow correlating the phonon modes with the orthorhombic structural distortions of RFeO3 perovskites. In particular, the positions of two specific A(g) modes scale linearly with the two FeO6 octahedra tilt angles, allowing the distortion to be tracked throughout the series. At variance with literature, we find that the two octahedra tilt angles scale differently with the vibration frequencies of their respective A(g) modes. This behavior, as well as the general relations between the tilt angles, the frequencies of the associated modes, and the ionic radii are rationalized in a simple Landau model. The reported Raman spectra and associated phonon-mode assignment provide reference data for structural investigations of the whole series of orthoferrites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2016, "Volume": 94, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 214103, "DOI": "10.1103/PhysRevB.94.214103", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.214103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389501200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Haneef, M; Ceseracciu, L; Canale, C; Bayer, IS; Heredia-Guerrero, JA; Athanassiou, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Haneef, Muhammad; Ceseracciu, Luca; Canale, Claudio; Bayer, Ilker S.; Heredia-Guerrero, Jose A.; Athanassiou, Athanassia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced Materials From Fungal Mycelium: Fabrication and Tuning of Physical Properties", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work is presented a new category of self-growing, fibrous, natural composite materials with controlled physical properties that can be produced in large quantities and over wide areas, based on mycelium, the main body of fungi. Mycelia from two types of edible, medicinal fungi, Ganoderma lucidum and Pleurotus ostreatus, have been carefully cultivated, being fed by two bio-substrates: cellulose and cellulose/potato-dextrose, the second being easier to digest by mycelium due to presence of simple sugars in its composition. After specific growing times the mycelia have been processed in order to cease their growth. Depending on their feeding substrate, the final fibrous structures showed different relative concentrations in polysaccharides, lipids, proteins and chitin. Such differences are reflected as alterations in morphology and mechanical properties. The materials grown on cellulose contained more chitin and showed higher Young's modulus and lower elongation than those grown on dextrose-containing substrates, indicating that the mycelium materials get stiffer when their feeding substrate is harder to digest. All the developed fibrous materials were hydrophobic with water contact angles higher than 120 degrees. The possibility of tailoring mycelium materials' properties by properly choosing their nutrient substrates paves the way for their use in various scale applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41292, "DOI": "10.1038/srep41292", "DOI Link": "http://dx.doi.org/10.1038/srep41292", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392476900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Heng, ZG; Zeng, Z; Zhang, B; Luo, YF; Luo, JM; Chen, Y; Zou, HW; Liang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Heng, Zhengguang; Zeng, Zhong; Zhang, Bin; Luo, Yinfu; Luo, Jiemin; Chen, Yang; Zou, Huawei; Liang, Mei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing mechanical performance of epoxy thermosets via designing a block copolymer to self-organize into core-shell nullostructure", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A rigid-flexible amphiphilic pentablock copolymer, polystyrene-block-poly(epsilon-caprolactone)-block-polydimethylsiloxane-block-poly(epsilon-caprolactone)-block-polystyrene (PS-PCL-PDMS-PCL-PS, SLDLS), was designed. SLDLS block copolymers will self-organize into core-shell nullostructures in epoxy thermosets, with rigid PS as the shell and flexible PDMS as the core. Due to the incorporation of the core-shell nullostructures, the tensile strength and toughness of the epoxy composites were simultaneously improved and the storage modulus maintained. It is believed that designing specific structures in epoxy resins through self-organization could provide new methods for the preparation of advanced functional epoxy composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": 80, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 77030, "End Page": 77036, "Article Number": null, "DOI": "10.1039/c6ra15283j", "DOI Link": "http://dx.doi.org/10.1039/c6ra15283j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466963500116", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Swatek, P; Wu, Y; Wang, LL; Lee, K; Schrunk, B; Yan, JQ; Kaminski, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Swatek, Przemyslaw; Wu, Yun; Wang, Lin-Lin; Lee, Kyungchan; Schrunk, Benjamin; Yan, Jiaqiang; Kaminski, Adam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gapless Dirac surface states in the antiferromagnetic topological insulator MnBi2Te4", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We used angle-resolved photoemission spectroscopy (ARPES) and density functional theory calculations to study the electronic properties of MnBi2Te4, a material that was predicted to be an intrinsic antiferromagnetic (AFM) topological insulator. In striking contrast to earlier literature showing a full gap opening between two surface band manifolds on the (0001) surface, we observed a gapless Dirac surface state with a Dirac point sitting at E-B = -280 meV. Furthermore, our ARPES data revealed the existence of a second Dirac cone sitting closer to the Fermi level. Surprisingly, these surface states remain intact across the AFM transition. The presence of gapless Dirac states in this material may be caused by different ordering at the surface from the bulk or weaker magnetic coupling between the bulk and surface. Whereas the surface Dirac cones seem to be remarkably insensitive to the AFM ordering most likely due to weak coupling to magnetism, we did observe a splitting of the bulk band accompanying the AFM transition. With a moderately high ordering temperature and interesting gapless Dirac surface states, MnBi2Te4 provides a unique platform for studying the interplay between magnetic ordering and topology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 148, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2020, "Volume": 101, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 161109, "DOI": "10.1103/PhysRevB.101.161109", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.101.161109", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526036000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, SW; Li, CJ; Chow, LE; Cao, Y; Zhang, ZT; Tang, CS; Yin, XM; Lim, ZS; Hu, JX; Yang, P; Ariando, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Shengwei; Li, Changjian; Chow, Lin Er; Cao, Yu; Zhang, Zhaoting; Tang, Chi Sin; Yin, Xinmao; Lim, Zhi Shiuh; Hu, Junxiong; Yang, Ping; Ariando, Ariando", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity in infinite-layer nickelate La1-xCaxNiO2 thin films", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the observation of superconductivity in infinite-layer Ca-doped LaNiO2 (La1-xCaxNiO2) thin films and construct their phase diagram. Unlike the metal-insulator transition in Nd- and Pr-based nickelates, the undoped and underdoped La1-xCaxNiO2 thin films are entirely insulating from 300 K down to 2 K. A superconducting dome is observed at 0.15 < x < 0.3 with weakly insulating behavior at the overdoped regime. Moreover, the sign of the Hall coefficient R-H changes at low temperature for samples with a higher doping level. However, distinct from the Nd- and Pr-based nickelates, the R-H-sign-change temperature remains at around 35 K as the doping increases, which begs further theoretical and experimental investigation to reveal the role of the 4f orbital to the (multi) band nature of the superconducting nickelates. Our results also emphasize a notable role of lattice correlation on the multiband structures of the infinite-layer nickelates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabl9927", "DOI": "10.1126/sciadv.abl9927", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abl9927", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760189000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, YC; Liu, XH; Chen, YY; Du, ZZ; Jiang, N; Shen, C; Zhang, EZ; Zheng, HZ; Lu, HZ; Wang, KY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Yongcheng; Liu, Xionghua; Chen, Yiyuan; Du, Zongzheng; Jiang, Nai; Shen, Chao; Zhang, Enze; Zheng, Houzhi; Lu, Hai-Zhou; Wang, Kaiyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-electrical switching of a topological non-collinear antiferromagnet at room temperature", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-collinear antiferromagnetic Weyl semimetals, combining the advantages of a zero stray field and ultrafast spin dynamics, as well as a large anomalous Hall effect and the chiral anomaly of Weyl fermions, have attracted extensive interest. However, the all-electrical control of such systems at room temperature, a crucial step toward practical application, has not been reported. Here, using a small writing current density of around 5 x 10(6) A center dot cm(-2), we realize the all-electrical current-induced deterministic switching of the non-collinear antiferromagnet Mn3Sn, with a strong readout signal at room temperature in the Si/SiO2/Mn3Sn/AlOx structure, and without external magnetic field or injected spin current. Our simulations reveal that the switching originates from the current-induced intrinsic non-collinear spin-orbit torques in Mn3Sn itself. Our findings pave the way for the development of topological antiferromagnetic spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2023, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwac154", "DOI": "10.1093/nsr/nwac154", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac154", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942532100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZL; Skripka, A; Dahl, JC; Dun, CC; Urban, JJ; Jaque, D; Schuck, PJ; Cohen, BE; Chan, EM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhuolei; Skripka, Artiom; Dahl, Jakob C.; Dun, Chaochao; Urban, Jeffrey J.; Jaque, Daniel; Schuck, P. James; Cohen, Bruce E.; Chan, Emory M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Phonon Energies in Lanthanide-doped Potassium Lead Halide nullocrystals for Enhanced Nonlinearity and Upconversion", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical applications of lanthanide-doped nulloparticles require materials with low phonon energies to minimize nonradiative relaxation and promote nonlinear processes like upconversion. Heavy halide hosts offer low phonon energies but are challenging to synthesize as nullocrystals. Here, we demonstrate the size-controlled synthesis of low-phonon-energy KPb2X5 (X=Cl, Br) nulloparticles and the ability to tune nullocrystal phonon energies as low as 128 cm(-1). KPb2Cl5 nulloparticles are moisture resistant and can be efficiently doped with lighter lanthanides. The low phonon energies of KPb2X5 nulloparticles promote upconversion luminescence from higher lanthanide excited states and enable highly nonlinear, avalanche-like emission from KPb2Cl5 : Nd3+ nulloparticles. The realization of nulloparticles with tunable, ultra-low phonon energies facilitates the discovery of nullomaterials with phonon-dependent properties, precisely engineered for applications in nulloscale imaging, sensing, luminescence thermometry and energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2023, "Volume": 62, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212549", "DOI Link": "http://dx.doi.org/10.1002/anie.202212549", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000898399100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avci, UE; Morris, DH; Young, IA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avci, Uygar E.; Morris, Daniel H.; Young, Ian A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunnel Field-Effect Transistors: Prospects and Challenges", "Source Title": "IEEE JOURNAL OF THE ELECTRON DEVICES SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The tunnel field-effect transistor (TFET) is considered a future transistor option due to its steep-slope prospects and the resulting advantages in operating at low supply voltage (V-DD). In this paper, using atomistic quantum models that are in agreement with experimental TFET devices, we are reviewing TFETs prospects at L-G = 13 nm node together with the main challenges and benefits of its implementation. Significant power savings at iso-performance to CMOS are shown for GaSb/InAs TFET, but only for performance targets which use lower than conventional V-DD. Also, P-TFET current-drive is between 1x to 0.5x of N-TFET, depending on choice of I-OFF and V-DD. There are many challenges to realizing TFETs in products, such as the requirement of high quality III-V materials and oxides with very thin body dimensions, and the TFET's layout density and reliability issues due to its source/drain asymmetry. Yet, extremely parallelizable products, such as graphics cores, show the prospect of longer battery life at a cost of some chip area.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 381, "Times Cited, All Databases": 398, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 88, "End Page": 95, "Article Number": null, "DOI": "10.1109/JEDS.2015.2390591", "DOI Link": "http://dx.doi.org/10.1109/JEDS.2015.2390591", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369884400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Hazarika, A; Schelhas, LT; Liu, J; Gaulding, EA; Li, GR; Zhang, MH; Toney, MF; Sercel, PC; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qian; Hazarika, Abhijit; Schelhas, Laura T.; Liu, Jun; Gaulding, E. Ashley; Li, Guoran; Zhang, Minghui; Toney, Michael F.; Sercel, Peter C.; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Size-Dependent Lattice Structure and Confinement Properties in CsPbl3 Perovskite nullocrystals: Negative Surface Energy for Stabilization", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CsPbI3 nullocrystals with narrow size distributions were prepared to study the size-dependent properties. The nullocrystals adopt the perovskite (over the nonperovskite orthorhombic) structure with improved stability over thin-film materials. Among the perovskite phases (cubic alpha, tetragonal beta, and orthorhombic gamma), the samples are characterized by the gamma phase, rather than a, but may have a size-dependent average tilting between adjacent octahedra. Size-dependent lattice constants systematically vary 3% across the size range, with unit cell volume increasing linearly with the inverse of size to 2.1% for the smallest size. We estimate the surface energy to be from -3.0 to -5.1 eV nm(-2) for ligated CsPbI3 nullocrystals. Moreover, the size-dependent bandgap is best described using a nonparabolic intermediate confinement model. We experimentally determine the bulk bandgap, effective mass, and exciton binding energy, concluding with variations from the bulk alpha-phase values. This provides a robust route to understanding gamma-phase properties of CsPbI3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 238, "End Page": 247, "Article Number": null, "DOI": "10.1021/acsenergylett.9b02395", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.9b02395", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000507145900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XY; Lv, SN; Kang, JX; Wang, ZC; Guo, TQ; Wang, Y; Teobaldi, G; Liu, LM; Guo, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiangyu; Lv, Shuning; Kang, Jianxin; Wang, Zhongchang; Guo, Tianqi; Wang, Yu; Teobaldi, Gilberto; Liu, Li-Min; Guo, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient C-N coupling in the direct synthesis of urea from CO2 and N2 by amorphous SbxBi1-xOy clusters", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although direct generation of high -value complex molecules and feedstock by coupling of ubiquitous small molecules such as CO2 and N2 holds great appeal as a potential alternative to current fossil -fuel technologies, suitable scalable and efficient catalysts to this end are not currently available as yet to be designed and developed. To this end, here we prepare and characterize SbxBi1- xOy clusters for direct urea synthesis from CO2 and N2 via C-N coupling. The introduction of Sb in the amorphous BiOx clusters changes the adsorption geometry of CO2 on the catalyst from O -connected to C- connected, creating the possibility for the formation of complex products such as urea. The modulated Bi(II) sites can effectively inject electrons into N2, promoting C-N coupling by advantageous modification of the symmetry for the frontier orbitals of CO2 and N2 involved in the rate- determining catalytic step. Compared with BiOx, SbxBi1- xOy clusters result in a lower reaction potential of only -0.3 V vs. RHE, an increased production yield of 307.97 mu g h-1 mg-1cat, and a higher Faraday efficiency (10.9%), pointing to the present system as one of the best catalysts for urea synthesis in aqueous systems among those reported so far. Beyond the urea synthesis, the present results introduce and demonstrate unique strategies to modulate the electronic states of main group p- metals toward their use as effective catalysts for multistep electroreduction reactions requiring C-N coupling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2023, "Volume": 120, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2306841120", "DOI": "10.1073/pnas.2306841120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2306841120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169830700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klimovskikh, II; Otrokov, MM; Estyunin, D; Eremeev, SV; Filnov, SO; Koroleva, A; Shevchenko, E; Voroshnin, V; Rybkin, AG; Rusinov, IP; Blanco-Rey, M; Hoffmann, M; Aliev, ZS; Babanly, MB; Amiraslanov, IR; Abdullayev, NA; Zverev, VN; Kimura, A; Tereshchenko, OE; Kokh, KA; Petaccia, L; Di Santo, G; Ernst, A; Echenique, PM; Mamedov, NT; Shikin, AM; Chulkov, EV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klimovskikh, Ilya I.; Otrokov, Mikhail M.; Estyunin, Dmitry; Eremeev, Sergey V.; Filnov, Sergey O.; Koroleva, Alexandra; Shevchenko, Eugene; Voroshnin, Vladimir; Rybkin, Artem G.; Rusinov, Igor P.; Blanco-Rey, Maria; Hoffmann, Martin; Aliev, Ziya S.; Babanly, Mahammad B.; Amiraslanov, Imamaddin R.; Abdullayev, Nadir A.; Zverev, Vladimir N.; Kimura, Akio; Tereshchenko, Oleg E.; Kokh, Konstantin A.; Petaccia, Luca; Di Santo, Giovanni; Ernst, Arthur; Echenique, Pedro M.; Mamedov, Nazim T.; Shikin, Alexander M.; Chulkov, Eugene V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable 3D/2D magnetism in the (MnBi2Te4)(Bi2Te3)mtopological insulators family", "Source Title": "NPJ QUANTUM MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Feasibility of many emergent phenomena that intrinsic magnetic topological insulators (TIs) may host depends crucially on our ability to engineer and efficiently tune their electronic and magnetic structures. Here we report on a large family of intrinsic magnetic TIs in the homologous series of the van der Waals compounds (MnBi2Te4)(Bi2Te3)(m)withm = 0, MIDLINE HORIZONTAL ELLIPSIS, 6. Magnetic, electronic and, consequently, topological properties of these materials depend strongly on themvalue and are thus highly tunable. The antiferromagnetic (AFM) coupling between the neighboring Mn layers strongly weakens on moving from MnBi2Te4(m = 0) to MnBi4Te7(m = 1) and MnBi6Te10(m = 2). Further increase inmleads to change of the overall magnetic behavior to ferromagnetic (FM) one for (m = 3), while the interlayer coupling almost disappears. In this way, the AFM and FM TI states are, respectively, realized in them = 0, 1, 2 andm = 3 cases. For largemnumbers a hitherto-unknown topologically nontrivial phase can be created, in which below the corresponding critical temperature the magnetizations of the non-interacting 2D ferromagnets, formed by the MnBi(2)Te(4)building blocks, are disordered along the third direction. The variety of intrinsic magnetic TI phases in (MnBi2Te4)(Bi2Te3)(m)allows efficient engineering of functional van der Waals heterostructures for topological quantum computation, as well as antiferromagnetic and 2D spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 54, "DOI": "10.1038/s41535-020-00255-9", "DOI Link": "http://dx.doi.org/10.1038/s41535-020-00255-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556004600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holler, M; Diaz, A; Guizar-Sicairos, M; Karvinen, P; Färm, E; Härkönen, E; Ritala, M; Menzel, A; Raabe, J; Bunk, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holler, M.; Diaz, A.; Guizar-Sicairos, M.; Karvinen, P.; Farm, Elina; Harkonen, Emma; Ritala, Mikko; Menzel, A.; Raabe, J.; Bunk, O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "X-ray ptychographic computed tomography at 16 nm isotropic 3D resolution", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray ptychography is a scanning variant of coherent diffractive imaging with the ability to image large fields of view at high resolution. It further allows imaging of non-isolated specimens and can produce quantitative mapping of the electron density distribution in 3D when combined with computed tomography. The method does not require imaging lenses, which makes it dose efficient and suitable to multi-keV X-rays, where efficient photon counting, pixelated detectors are available. Here we present the first highly resolved quantitative X-ray ptychographic tomography of an extended object yielding 16 nm isotropic 3D resolution recorded at 2 angstrom wavelength. This first-of-its-kind demonstration paves the way for ptychographic X-ray tomography to become a promising method for X-ray imaging of representative sample volumes at unmatched resolution, opening tremendous potential for characterizing samples in materials science and biology by filling the resolution gap between electron microscopy and other X-ray imaging techniques.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 24", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3857, "DOI": "10.1038/srep03857", "DOI Link": "http://dx.doi.org/10.1038/srep03857", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000330138100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gordon, JV; Narra, SP; Cunningham, RW; Liu, H; Chen, HM; Suter, RM; Beuth, JL; Rollett, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gordon, Jerard, V; Narra, Sneha P.; Cunningham, Ross W.; Liu, He; Chen, Hangman; Suter, Robert M.; Beuth, Jack L.; Rollett, Anthony D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect structure process maps for laser powder bed fusion additive manufacturing", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate detection, characterization, and prediction of defects has great potential for immediate impact in the production of fully-dense and defect free metal additive manufacturing (AM) builds. Accordingly, this paper presents Defect Structure Process Maps (DSPMs) as a means of quantifying the role of porosity as an exemplary defect structure in powder bed printed materials. Synchrotron-based micro-computed tomography (iSXCT) was used to demonstrate that metal AM defects follow predictable trends within processing parameter space for laser powder bed fusion (LPBF) materials. Ti-6Al-4 V test blocks were fabricated on an EOS M290 utilizing variations in laser power, scan velocity, and hatch spacing. In general, characteristic under-melting or lack-of-fusion defects were discovered in the low laser power, high scan velocity region of process space via uSXCT. These defects were associated with insufficient overlap between adjacent melt tracks and can be avoided through the application of a lack-of-fusion criterion using melt pool geometric modeling. Large-scale keyhole defects were also successfully mitigated for estimated melt pool morphologies associated with shallow keyhole front wall angles. Process variable selections resulting in deep keyholes, i.e., high laser power and low scan velocity, exhibit a substantial increase of spherical porosity as compared to the nominal (manufacturer recommended) processing parameters for Ti-6Al-4 V. Defects within fully-dense process space were also discovered, and are associated with gas porosity transfer to the AM test blocks during the laser-powder interaction. Overall, this work points to the fact that large-scale defects in LPBF materials can be successfully predicted and thus mitigated/minimized via appropriate selection of processing parameters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 36, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101552, "DOI": "10.1016/j.addma.2020.101552", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2020.101552", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600807800136", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Valiev, RZ; Estrin, Y; Horita, Z; Langdon, TG; Zehetbauer, MJ; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Valiev, Ruslan Z.; Estrin, Yuri; Horita, Zenji; Langdon, Terence G.; Zehetbauer, Michael J.; Zhu, Yuntian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Producing Bulk Ultrafine-Grained Materials by Severe Plastic Deformation: Ten Years Later", "Source Title": "JOM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is now well established that the processing of bulk solids through the application of severe plastic deformation (SPD) leads to exceptional grain refinement to the submicrometer or nullometer level. Extensive research over the last decade has demonstrated that SPD processing also produces unusual phase transformations and leads to the introduction of a range of nullostructural features, including nonequilibrium grain boundaries, deformation twins, dislocation substructures, vacancy agglomerates, and solute segregation and clustering. These many structural changes provide new opportunities for fine tuning the characteristics of SPD metals to attain major improvements in their physical, mechanical, chemical, and functional properties. This review provides a summary of some of these recent developments. Special emphasis is placed on the use of SPD processing in achieving increased electrical conductivity, superconductivity, and thermoelectricity, an improved hydrogen storage capability, materials for use in biomedical applications, and the fabrication of high-strength metal-matrix nullocomposites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 68, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1216, "End Page": 1226, "Article Number": null, "DOI": "10.1007/s11837-016-1820-6", "DOI Link": "http://dx.doi.org/10.1007/s11837-016-1820-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373131200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leguy, AMA; Goñi, AR; Frost, JM; Skelton, J; Brivio, F; Rodríguez-Martínez, X; Weber, OJ; Pallipurath, A; Alonso, MI; Campoy-Quiles, M; Weller, MT; Nelson, J; Walsh, A; Barnes, PRF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leguy, Aurelien M. A.; Goni, Alejandro R.; Frost, Jarvist M.; Skelton, Jonathan; Brivio, Federico; Rodriguez-Martinez, Xabier; Weber, Oliver J.; Pallipurath, Anuradha; Isabel Alonso, M.; Campoy-Quiles, Mariano; Weller, Mark T.; Nelson, Jenny; Walsh, Aron; Barnes, Piers R. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic disorder, phonon lifetimes, and the assignment of modes to the vibrational spectra of methylammonium lead halide perovskites", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present Raman and terahertz absorbance spectra of methylammonium lead halide single crystals (MAPbX(3), X = I, Br, Cl) at temperatures between 80 and 370 K. These results show good agreement with density-functional-theory phonon calculations. Comparison of experimental spectra and calculated vibrational modes enables confident assignment of most of the vibrational features between 50 and 3500 cm(-1). Reorientation of the methylammonium cations, unlocked in their cavities at the orthorhombic-to-tetragonal phase transition, plays a key role in shaping the vibrational spectra of the different compounds. Calculations show that these dynamic effects split Raman peaks and create more structure than predicted from the independent harmonic modes. This explains the presence of extra peaks in the experimental spectra that have been a source of confusion in earlier studies. We discuss singular features, in particular the torsional vibration of the C-N axis, which is the only molecular mode that is strongly influenced by the size of the lattice. From analysis of the spectral linewidths, we find that MAPbI(3) shows exceptionally short phonon lifetimes, which can be linked to low lattice thermal conductivity. We show that optical rather than acoustic phonon scattering is likely to prevail at room temperature in these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 346, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2016, "Volume": 18, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 27051, "End Page": 27066, "Article Number": null, "DOI": "10.1039/c6cp03474h", "DOI Link": "http://dx.doi.org/10.1039/c6cp03474h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385177200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, ST; Zhang, X; Yang, GJ; Zhang, SM; Ma, BY; Liu, QY; Liu, Y; Peng, CX; Chen, HX; Yu, HL; Fan, XL; Cheng, T; Chen, LQ; Li, YJ; Wang, ZX; Wang, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Suting; Zhang, Xiao; Yang, Gaojing; Zhang, Simeng; Ma, Bingyun; Liu, Qiuyan; Liu, Yue; Peng, Chengxin; Chen, Huixin; Yu, Hailong; Fan, Xiulin; Cheng, Tao; Chen, Liquan; Li, Yejing; Wang, Zhaoxiang; Wang, Xuefeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-dependent interphase formation and Li+ transport in lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-performance Li-ion/metal batteries working at a low temperature (i.e., <-20 & DEG;C) are desired but hindered by the sluggish kinetics associated with Li+ transport and charge transfer. Herein, the temperature-dependent Li+ behavior during Li plating is profiled by various characterization techniques, suggesting that Li+ diffusion through the solid electrolyte interface (SEI) layer is the key rate-determining step. Lowering the temperature not only slows down Li+ transport, but also alters the thermodynamic reaction of electrolyte decomposition, resulting in different reaction pathways and forming an SEI layer consisting of intermediate products rich in organic species. Such an SEI layer is metastable and unsuitable for efficient Li+ transport. By tuning the solvation structure of the electrolyte with a lower lowest unoccupied molecular orbital (LUMO) energy level and polar groups, such as fluorinated electrolytes like 1 mol L-1 lithium bis(fluorosulfonyl)imide (LiFSI) in methyl trifluoroacetate (MTFA): fluoroethylene carbonate (FEC) (8:2, weight ratio), an inorganic-rich SEI layer more readily forms, which exhibits enhanced tolerance to a change of working temperature (thermodynamics) and improved Li+ transport (kinetics). Our findings uncover the kinetic bottleneck for Li+ transport at low temperature and provide directions to enhance the reaction kinetics/thermodynamics and low-temperature performance by constructing inorganic-rich interphases. High-performance lithium metal batteries operating below -20 & DEG;C are desired but hindered by slow reaction kinetics. Here, the authors uncover the temperature-dependent Li+ behavior and interphase formation in liquid electrolytes and provide directions to enhance the low temperature performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4474, "DOI": "10.1038/s41467-023-40221-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40221-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037058500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, PZ; Zhou, Q; Zhang, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Peizhe; Zhou, Quan; Zhang, Shou-Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple Types of Topological Fermions in Transition Metal Silicides", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exotic massless fermionic excitations with nonzero Berry flux, other than the Dirac and Weyl fermions, could exist in condensed matter systems under the protection of crystalline symmetries, such as spin-1 excitations with threefold degeneracy and spin-3= 2 Rarita-Schwinger-Weyl fermions. Herein, by using the ab initio density functional theory, we show that these unconventional quasiparticles coexist with type-I and type-IIWeyl fermions in a family of transition metal silicides, including CoSi, RhSi, RhGe, and CoGe, when spin-orbit coupling is considered. Their nontrivial topology results in a series of extensive Fermi arcs connecting projections of these bulk excitations on the side surface, which is confirmed by (001) surface electronic spectra of CoSi. In addition, these stable arc states exist within a wide energy window around the Fermi level, which makes them readily accessible in angle-resolved photoemission spectroscopy measurements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 340, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2017, "Volume": 119, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 206402, "DOI": "10.1103/PhysRevLett.119.206402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.206402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415604000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aldana, AA; Abraham, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aldana, Ana A.; Abraham, Gustavo A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current advances in electrospun gelatin-based scaffolds for tissue engineering applications", "Source Title": "INTERNATIONAL JOURNAL OF PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of biomimetic highly-porous scaffolds is essential for successful tissue engineering. Electrospun nullofibers are highly versatile platforms for a broad range of applications in different research areas. In the biomedical field, micro/nulloscale fibrous structures have gained great interest for wound dressings, drug delivery systems, soft and hard-tissue engineering scaffolds, enzyme immobilization, among other healthcare applications. In this mini-review, electrospun gelatin-based scaffolds for a variety of tissue engineering applications, such as bone, cartilage, skin, nerve, and ocular and vascular tissue engineering, are reviewed and discussed. Gelatin blends with natural or synthetic polymers exhibit physicochemical, biomechanical, and biocompatibility properties very attractive for scaffolding. Current advances and challenges on this research field are presented. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2017, "Volume": 523, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 441, "End Page": 453, "Article Number": null, "DOI": "10.1016/j.ijpharm.2016.09.044", "DOI Link": "http://dx.doi.org/10.1016/j.ijpharm.2016.09.044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401106000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Xu, XQ; Nie, Y; Wang, RH; Zou, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xinyu; Xu, Xiaoqin; Nie, Yao; Wang, Ruihong; Zou, Jinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic-State Modulation of Metallic Co-Assisted Co7Fe3 Alloy Heterostructure for Highly Efficient and Stable Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manipulating electronic structure of alloy-based electrocatalysts can eagerly regulate its catalytic efficiency and corrosion resistance for water splitting and fundamentally understand the catalytic mechanisms for oxygen/hydrogen evolution reactions (OER/HER). Herein, the metallic Co-assisted Co7Fe3 alloy heterojunction (Co7Fe3/Co) embeds in a 3D honeycomb-like graphitic carbon is purposely constructed as a bifunctional catalyst for overall water splitting. As-marked Co7Fe3/Co-600 displays the excellent catalytic activities in alkaline media with low overpotentials of 200 mV for OER and 68 mV for HER at 10 mA cm(-2). Theoretical calculations reveal the electronic redistribution after coupling Co with Co7Fe3, which likely forms the electron-rich state over interfaces and the electron-delocalized state at Co7Fe3 alloy. This process changes the d-band center position of Co7Fe3/Co and optimizes the affinity of catalyst surface to intermediates, thus promoting the intrinsic OER/HER activities. For overall water splitting, the electrolyzer only requires a cell voltage of 1.50 V to achieve 10 mA cm(-2) and dramatically retains 99.1% of original activity after 100 h of continuous operation. This work proposes an insight into modulation of electronic state in alloy/metal heterojunctions and explores a new path to construct more competitive electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 10, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202301961", "DOI Link": "http://dx.doi.org/10.1002/advs.202301961", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991568700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qian, YQ; Xiao, L; Wang, Q; Head, JW; Yang, RH; Kang, Y; van der Bogert, CH; Hiesinger, H; Lai, XM; Wang, GX; Pang, Y; Zhang, N; Yuan, YF; He, Q; Huang, J; Zhao, JN; Wang, J; Zhao, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qian, Yuqi; Xiao, Long; Wang, Qian; Head, James W.; Yang, Ruihong; Kang, Yan; van der Bogert, Carolyn H.; Hiesinger, Harald; Lai, Xiaoming; Wang, Guoxing; Pang, Yong; Zhang, Nai; Yuan, Yuefeng; He, Qi; Huang, Jun; Zhao, Jiannull; Wang, Jiang; Zhao, Siyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "China's Chang'e-5 landing site: Geology, stratigraphy, and provenullce of materials", "Source Title": "EARTH AND PLANETARY SCIENCE LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "China's Chang'e-5 (CE-5) mission, the first lunar sample return mission since 1976, landed at 43.06 degrees N, 51.92 degrees W on Dec. 1, 2020, in Northern Oceanus Procellarum. CE-5 targeted a mare plain (Em4/P58) composed of distinctive young (similar to 1.6-1.7 Ga) moderate-Ti mare basalts, with elevated Th abundance (inherent or extraneous). Thus, the regolith and rock fragments sampled by CE-5 come from some of the youngest mare basalts on the Moon, near Rima Sharp, and from the center of the globally anomalous Procellarum KREEP Terrane (PKT), hypothesized to be responsible for the generation of the young volcanism. To provide context for the analysis and interpretation of the returned samples and in-situ measurements of the regolith substructure with penetrating radar, we constructed a detailed geologic map and stratigraphic assessment of the site. The stratigraphy consists of ancient highland materials (PKT crust and ejecta from Iridum and Imbrium basins), local silica-rich volcanism, overlain by a sequence of mare basalts, capped with Em4/P58. A similar to 4-7 m thick regolith layer developed by post-mare bombardment overlies the Em4/P58 protolith and contains admixed impact ejecta from distant sources, mainly from Harpalus (similar to 6 wt.%), followed by Copernicus (similar to 2 wt.%) and Aristarchus (similar to 1 wt.%). New crater size-frequency measurements of Em4/P58 provide the necessary crater spatial density reference for calibration of the lunar cratering chronology with radiometric ages of the returned samples. The geological map and assessment of regolith provenullce indicate that samples returned by CE-5 will address fundamental questions in lunar chronology, thermal evolution, basalt petrogenesis, and the nature of PKT, as well as provide key calibration for lunar and planetary chronologies and remote sensing data. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2021, "Volume": 561, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116855, "DOI": "10.1016/j.epsl.2021.116855", "DOI Link": "http://dx.doi.org/10.1016/j.epsl.2021.116855", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631258000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reddy, DV; Nerem, RR; Nam, SW; Mirin, RP; Verma, VB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reddy, Dileep, V; Nerem, Robert R.; Nam, Sae Woo; Mirin, Richard P.; Verma, Varun B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconducting nullowire single-photon detectors with 98% system detection efficiency at 1550 nm", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconducting nullowire single-photon detectors (SNSPDs) are an enabling technology for myriad quantum-optics experiments that require high-efficiency detection, large count rates, and precise timing resolution. The system detection efficiencies (SDEs) for fiber-coupled SNSPDs have fallen short of theoretical predictions of near unity by at least 7%, with the discrepancy being attributed to scattering, material absorption, and other SNSPD dynamics. We optimize the design and fabrication of an all-dielectric layered stack and fiber coupling package in order to achieve 98.0 +/- 0.5% SDE, measured for single-mode-fiber guided photons derived from a highly attenuated 1550 nm continuous-wave laser. This enforces a smaller bound on the scattering and absorption losses in such systems and opens the use of SNSPDs for scenarios that demand high-SDE for throughput and fidelity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2020, "Volume": 7, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1649, "End Page": 1653, "Article Number": null, "DOI": "10.1364/OPTICA.400751", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.400751", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600773800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ozdemir, Z; Hernulldez-Nava, E; Tyas, A; Warren, JA; Fay, SD; Goodall, R; Todd, L; Askes, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozdemir, Zuhal; Hernulldez-Nava, Everth; Tyas, Andrew; Warren, James A.; Fay, Stephen D.; Goodall, Russell; Todd, Lain; Askes, Harm", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy absorption in lattice structures in dynamics: Experiments", "Source Title": "INTERNATIONAL JOURNAL OF IMPACT ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice structures offer the potential to relatively easily engineer specific (meso-scale properties (cell level)), to produce desirable macro-scale material properties for a wide variety of engineering applications including wave filters, blast and impact protection systems, thermal insulation, structural aircraft and vehicle components, and body implants. The work presented here focuses on characterising the quasi-static and, in particular, the dynamic load-deformation behaviour of lattice samples. First, cubic, diamond and re-entrant cube lattice structures were tested under quasi-static conditions to investigate failure process and stress-strain response of such materials. Following the quasi-static tests, Hopkinson pressure bar (HPB) tests were carried out to evaluate the impact response of these materials under high deformation rates. The HPB tests show that the lattice structures are able to spread impact loading in time and to reduce the peak impact stress. A significant rate dependency of load-deformation characteristics was identified. This is believed to be the first published results of experimental load-deformation studies of additively manufactured lattice structures. The cubic and diamond lattices are, by a small margin, the most effective of those lattices investigated to achieve this. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 89, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 49, "End Page": 61, "Article Number": null, "DOI": "10.1016/j.ijimpeng.2015.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.ijimpeng.2015.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368969600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, QW; Hou, H; Pan, Y; Pei, XL; Song, Z; Liaw, PK; Zhao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Qingwei; Hou, Hua; Pan, Yue; Pei, Xiaolong; Song, Zhuo; Liaw, Peter K.; Zhao, Yuhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hardening-softening of Al0.3CoCrFeNi high-entropy alloy under nulloindentation", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The competition and balance mechanism between work hardening resulting from the surge in disloca-tions and material softening caused by plastic deformation during contact loading in Al0.3CoCrFeNi high-entropy alloy is unclear. The structural transformation and strain localization of Al0.3CoCrFeNi high-entropy alloy during nulloindentation are investigated using molecular dynamics, and the hardening-softening mechanism is discussed. The simulations demonstrate that the prismatic dislocation loop with independent nucleation is discovered for the first time in the [111] orientation. Dislocation multiplication and cross-slip lead to an increase in indentation resistance, resulting in work hardening. Free dislocation slip and dislocation annihilation accommodate plastic strain will reduce indentation resistance, resulting in plastic softening. Twin boundaries can effectively block dislocation propagation, which contributes to hardening. However, twin boundaries cause a softening effect in the later stage of plastic deformation owing to two reasons: (1) the formation of steps and the partial slip where the slip plane and Burgers vector are parallel to the twin boundary, (2) steps and local damage zones in twin boundaries become new nucleation sites for dislocations. The phase-field-crystal method confirms that Al0.3CoCrFeNi high-entropy alloy has the highest hardness when the twin spacing is 2.467 nm.& COPY; 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 231, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112050, "DOI": "10.1016/j.matdes.2023.112050", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2023.112050", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054237100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Plummer, CM; Li, L; Chen, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Plummer, Christopher M.; Li, Le; Chen, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ring-Opening Polymerization for the Goal of Chemically Recyclable Polymers", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A crucial modern dilemma relates to the ecological crisis created by excess plastic waste production. An emerging technology for reducing plastic waste is the production of chemically recyclable polymers. These polymers can be efficiently synthesized through ring-opening polymerization (ROP/ROMP) and later recycled to pristine monomer by ring-closing depolyme-rization, in an efficient circular-type system. This Perspective aims to explore the chemistry involved in the preparation of these monomer/polymer systems, while also providing an overview of the challenges involved, including future directions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2023, "Volume": 56, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 731, "End Page": 750, "Article Number": null, "DOI": "10.1021/acs.macromol.2c01694", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.2c01694", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930585600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, BJ; Zhao, XY; Zhang, JQ; Sun, YC; Yang, HZ; Guo, LJ; Zhou, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Benjie; Zhao, Xiaoyu; Zhang, Jingqiong; Sun, Yuechang; Yang, Hongzhi; Guo, L. Jay; Zhou, Shengjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithically Integrating III-Nitride Quantum Structure for Full-Spectrum White LED via Bandgap Engineering Heteroepitaxial Growth", "Source Title": "LASER & PHOTONICS REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Great progress made by heteroepitaxial growth technology encourages rapid development of III-nitride heteroepitaxial structures and their applications in extensive fields. Particularly, innate bandgap tunability of III-nitride materials renders them attractive for white light-emitting diodes (WLEDs) that are considered as next-generation solid-state lighting sources. However, commercial phosphor-converted WLEDs suffer from poor color rendering index (CRI) and intense blue component, hard to fulfill demanding requirements simultaneously for energy efficiency and healthy lighting. Here, an efficient full-spectrum WLED excited by monolithically integrated III-nitride quantum structure is reported, in which trichromatic InGaN/GaN multiple quantum wells are constructed by bandgap engineering heteroepitaxy growth allowing flexible regulation of indium composition and quantum barrier thickness to manipulate carrier transport behavior. Furthermore, relationship between structural parameters and emission characteristics as well as their impact on white light performance is systematically demonstrated. Combined with commonly used green-red phosphor mixture, the fabricated full-spectrum warm/cold WLEDs can emit broadband and continuous spectra with low-ratio blue component, first exhibiting superior CRI (> 97/98), color fidelity (97/97), saturation (100/99), and luminous efficacy (>120/140 lm W-1). This work demonstrates the advantages of bandgap-engineered quantum structure applied in excitation source, and opens up new avenues for the exploration of high-quality solid-state lighting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 17, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/lpor.202200455", "DOI Link": "http://dx.doi.org/10.1002/lpor.202200455", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905255700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Piao, YC; Zhang, FH; Zhang, Y; Hu, YX; Wang, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chen; Piao, Yinchuan; Zhang, Feihu; Zhang, Yong; Hu, Yuxiu; Wang, Yongfei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understand anisotropy dependence of damage evolution and material removal during nulloscratch of MgF2 single crystals", "Source Title": "INTERNATIONAL JOURNAL OF EXTREME MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To understand the anisotropy dependence of the damage evolution and material removal during the machining process of MgF2 single crystals, nulloscratch tests of MgF2 single crystals with different crystal planes and directions were systematically performed, and surface morphologies of the scratched grooves under different conditions were analyzed. The experimental results indicated that anisotropy considerably affected the damage evolution in the machining process of MgF2 single crystals. A stress field model induced by the scratch was developed by considering the anisotropy, which indicated that during the loading process, median cracks induced by the tensile stress initiated and propagated at the front of the indenter. Lateral cracks induced by tensile stress initiated and propagated on the subsurface during the unloading process. In addition, surface radial cracks induced by the tensile stress were easily generated during the unloading process. The stress change led to the deflection of the propagation direction of lateral cracks. Therefore, the lateral cracks propagated to the workpiece surface, resulting in brittle removal in the form of chunk chips. The plastic deformation parameter indicated that the more the slip systems were activated, the more easily the plastic deformation occurred. The cleavage fracture parameter indicated that the cracks propagated along the activated cleavage planes, and the brittle chunk removal was owing to the subsurface cleavage cracks propagating to the crystal surface. Under the same processing parameters, the scratch of the (001) crystal plane along the [100] crystal-orientation was found to be the most conducive to achieving plastic machining of MgF2 single crystals. The theoretical results agreed well with the experimental results, which will not only enhance the understanding of the anisotropy dependence of the damage evolution and removal process during the machining of MgF2 crystals, but also provide a theoretical foundation for achieving the high-efficiency and low-damage processing of anisotropic single crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15101, "DOI": "10.1088/2631-7990/ac9eed", "DOI Link": "http://dx.doi.org/10.1088/2631-7990/ac9eed", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000890021200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Novikov, IS; Gubaev, K; Podryabinkin, E; Shapeev, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Novikov, Ivan S.; Gubaev, Konstantin; Podryabinkin, Evgeny, V; Shapeev, Alexander, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The MLIP package: moment tensor potentials with MPI and active learning", "Source Title": "MACHINE LEARNING-SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The subject of this paper is the technology (the 'how') of constructing machine-learning interatomic potentials, rather than science (the 'what' and 'why') of atomistic simulations using machine-learning potentials. Namely, we illustrate how to construct moment tensor potentials using active learning as implemented in the MLIP package, focusing on the efficient ways to automatically sample configurations for the training set, how expanding the training set changes the error of predictions, how to set up ab initio calculations in a cost-effective manner, etc. The MLIP package (short for Machine-Learning Interatomic Potentials) is available at https://mlip.skoltech.ru/download/.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 423, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25002, "DOI": "10.1088/2632-2153/abc9fe", "DOI Link": "http://dx.doi.org/10.1088/2632-2153/abc9fe", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000660868300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MJ; Guo, Q; Li, ZY; Zhou, YJ; Zhao, SS; Tong, Z; Wang, YX; Li, GG; Jin, S; Zhu, MZ; Zhuang, TT; Yu, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mingjiang; Guo, Qi; Li, Zeyi; Zhou, Yajie; Zhao, Shanshan; Tong, Zhi; Wang, Yaxin; Li, Guangen; Jin, Shan; Zhu, Manzhou; Zhuang, Taotao; Yu, Shu-Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Processable circularly polarized luminescence material enables flexible stereoscopic 3D imaging", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Endowing three-dimensional (3D) displays with flexibility drives innovation in the next-generation wearable and smart electronic technology. Printing circularly polarized luminescence (CPL) materials on stretchable panels gives the chance to build desired flexible stereoscopic displays: CPL provides unusual optical rotation characteristics to achieve the considerable contrast ratio and wide viewing angle. However, the lack of printable, intense circularly polarized optical materials suitable for flexible processing hinders the implementation of flexible 3D devices. Here, we report a controllable and macroscopic production of printable CPL-active photonic paints using a designed confining helical co-assembly strategy, achieving a maximum luminescence dissymmetry factor (g(lum)) value of 1.6. We print customized graphics and meter-long luminous coatings with these paints on a range of substates such as polypropylene, cotton fabric, and polyester fabric. We then demonstrate a flexible textile 3D display panel with two printed sets of pixel arrays based on the orthogonal CPL emission, which lays an efficient framework for future intelligent displays and clothing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2023, "Volume": 9, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadi9944", "DOI": "10.1126/sciadv.adi9944", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adi9944", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001261640600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sears, JA; Songvilay, M; Plumb, KW; Clancy, JP; Qiu, Y; Zhao, Y; Parshall, D; Kim, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sears, J. A.; Songvilay, M.; Plumb, K. W.; Clancy, J. P.; Qiu, Y.; Zhao, Y.; Parshall, D.; Kim, Young-June", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic order in α-RuCl3: A honeycomb-lattice quantum magnet with strong spin-orbit coupling", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report magnetic and thermodynamic properties of single crystal alpha-RuCl3, in which the Ru3+ (4d(5)) ion is in its low spin state and forms a honeycomb lattice. Two features are observed in both magnetic susceptibility and specific heat data; a sharp peak at 7 K and a broad hump near 10-15 K. In addition, we observe a metamagnetic transition between 5 and 10 T. Our neutron diffraction study of single crystal samples confirms that the low temperature peak in the specific heat is associated with a magnetic order with unit cell doubling along the honeycomb (100) direction, which is consistent with zigzag order, one of the types of magnetic order predicted within the framework of the Kitaev-Heisenberg model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 406, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2015, "Volume": 91, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144420, "DOI": "10.1103/PhysRevB.91.144420", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.144420", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353449400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barba-Bon, A; Salluce, G; Lostalé-Seijo, I; Assaf, K; Hennig, A; Montenegro, J; Nau, WM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barba-Bon, Andrea; Salluce, Giulia; Lostale-Seijo, Irene; Assaf, Khaleel, I; Hennig, Andreas; Montenegro, Javier; Nau, Werner M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron clusters as broadband membrane carriers", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The membrane translocation of hydrophilic substances constitutes a challenge for their application astherapeutic compounds and labelling probes(1-4) . To remedy this, charged amphiphilic molecules have been classically used as carriers(3,5). However, such amphiphilic carriers may cause aggregation and non-specific membrane lysis(6,7). Here we show that globular dodecaborate clusters, and prominently B12Br122-, can function as anionic inorganic membrane carriers for a broad range of hydrophilic cargo molecules (with molecular mass of146-4,500 Da). We show that cationic and neutral peptides, amino acids, neurotransmitters, vitamins, antibiotics and drugs can be carried across liposomal membranes. Mechanistic transport studies reveal that the carrier activity is related to the superchaotropic nature of these cluster anions(8-)(12). We demonstrate that B12Br122-- affects cytosolic uptake of different small bioactive molecules, including the antineoplastic monomethyl auristatin F, the proteolysis targeting chimera dBET1 and the phalloidin toxin, which has been successfully delivered in living cells for cytoskeleton labelling. We anticipate the broad and distinct delivery spectrum of our superchaotropic carriers to be the starting point of conceptually distinct cell-biological, neurobiological, physiological and pharmaceutical studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2022, "Volume": 603, "Issue": 7902, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 637, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04413-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04413-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000772661800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, ZW; Jiang, HT; Chen, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Zhiwei; Jiang, Haitao; Chen, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperbolic metamaterials: From dispersion manipulation to applications", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Manipulating the properties of the isofrequency contours (IFCs) of materials provides a powerful means of controlling the interaction between light and matter. Hyperbolic metamaterials (HMMs), an important class of artificial anisotropic materials with hyperbolic IFCs, have been intensively investigated. Because of their open dispersion curves, HMMs support propagating high-k modes and possess an enhanced photonic density of states. As a result, HMMs can be utilized to realize hyperlenses breaking the diffraction limit, metacavity lasers with subwavelength scale, high-sensitivity sensors, long-range energy transfer, and so on. Aimed at those who are about to enter this burgeoning and rapidly developing research field, this tutorial article not only introduces the basic physical properties of HMMs but also discusses dispersion manipulation in HMMs and HMM-based structures such as hypercrystals. Both theoretical methods and experimental platforms are detailed. Finally, some potential applications associated with hyperbolic dispersion are introduced. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 127, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 71101, "DOI": "10.1063/1.5128679", "DOI Link": "http://dx.doi.org/10.1063/1.5128679", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519616100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pitts, RA; Bonnin, X; Escourbiac, F; Frerichs, H; Gunn, JP; Hirai, T; Kukushkin, AS; Kaveeva, E; Miller, MA; Moulton, D; Rozhansky, V; Senichenkov, I; Sytova, E; Schmitz, O; Stangeby, PC; De Temmerman, G; Veselova, I; Wiesen, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pitts, R. A.; Bonnin, X.; Escourbiac, F.; Frerichs, H.; Gunn, J. P.; Hirai, T.; Kukushkin, A. S.; Kaveeva, E.; Miller, M. A.; Moulton, D.; Rozhansky, V.; Senichenkov, I.; Sytova, E.; Schmitz, O.; Stangeby, P. C.; De Temmerman, G.; Veselova, I.; Wiesen, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physics basis for the first ITER tungsten divertor", "Source Title": "NUCLEAR MATERIALS AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On the eve of component procurement, this paper discusses the present physics basis for the first ITER tungsten (W) divertor, beginning with a reminder of the key elements defining the overall design, and outlining relevant aspects of the Research Plan accompanying the new staged approach to ITER nuclear operations which fixes the overall divertor lifetime constraint. The principal focus is on the main design driver, steady state power fluxes in the DT phases, obtained from simulations using the 2-D SOLPS-4.3 and SOLPS-ITER plasma boundary codes, assuming the use of the low Z seeding impurities nitrogen (N) and neon (Ne). A new perspective on the simulation database is adopted, concentrating purely on the divertor physics aspects rather than on the core-edge integration, which has been studied extensively in the course of the divertor design evolution and is published elsewhere. Emphasis is placed on factors which may increase the peak steady state loads: divertor target shaping for component misalignment protection, the influence of fluid drifts, and the consequences of narrow scrape-off layer heat flux channels. All tend to push the divertor into an operating space at higher sub-divertor neutral pressure in order to remain at power flux densities acceptable for the target material. However, a revised criterion for the maximum tolerable loads based on avoidance of W recrystallization, sets an upper limit potentially similar to 50% higher than the previously accepted value of similar to 10 MW m(-2), a consequence both of the choice of material and the finalized component design. Although the simulation database is currently restricted to the 2-D toroidally symmetric situation, considerable progress is now also being made using the EMC3-Eirene 3-D code suite for the assessment of power loading in the presence of magnetic perturbations for ELM control. Some new results for low input power corresponding to the early H-mode operation phases are reported, showing that even if realistic plasma screening is taken into account, significant asymmetric divertor heat fluxes may arise far from the unperturbed strike point. The issue of tolerable limits for transient heat pulses is an open and key question. A new scaling for ELM power deposition has shown that whilst there may be more latitude for operation at higher current without ELM control, the ultimate limit is likely to be set more by material fatigue under large numbers of sub-threshold melting events.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100696, "DOI": "10.1016/j.nme.2019.100696", "DOI Link": "http://dx.doi.org/10.1016/j.nme.2019.100696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500930800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jana, MK; Song, RY; Xie, Y; Zhao, RD; Sercel, PC; Blum, V; Mitzi, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jana, Manoj K.; Song, Ruyi; Xie, Yi; Zhao, Rundong; Sercel, Peter C.; Blum, Volker; Mitzi, David B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) hybrid metal halide perovskites have emerged as outstanding optoelectronic materials and are potential hosts of Rashba/Dresselhaus spin-splitting for spin-selective transport and spin-orbitronics. However, a quantitative microscopic understanding of what controls the spin-splitting magnitude is generally lacking. Through crystallographic and first-principles studies on a broad array of chiral and achiral 2D perovskites, we demonstrate that a specific bond angle disparity connected with asymmetric tilting distortions of the metal halide octahedra breaks local inversion symmetry and strongly correlates with computed spin-splitting. This distortion metric can serve as a crystallographic descriptor for rapid discovery of potential candidate materials with strong spin-splitting. Our work establishes that, rather than the global space group, local inorganic layer distortions induced via appropriate organic cations provide a key design objective to achieve strong spin-splitting in perovskites. New chiral perovskites reported here couple a sizeable spin-splitting with chiral degrees of freedom and offer a unique paradigm of potential interest for spintronics. Two-dimensional hybrid perovskites exhibiting Rashba/Dresselhaus spin-splitting can be potentially used for spin-selective transport and spin-orbitronics, yet the structural determinullts of spin-splitting are not well-understood. Here, the authors reveal a specific inorganic layer distortion that correlates with bulk spin-splitting in these materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4982, "DOI": "10.1038/s41467-021-25149-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25149-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686662300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; Yao, JC; Quan, YN; Hu, MY; Su, R; Gao, M; Han, DL; Yang, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuo; Yao, Jiacheng; Quan, Yingnull; Hu, Mingyue; Su, Rui; Gao, Ming; Han, Donglai; Yang, Jinghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monitoring the charge-transfer process in a Nd-doped semiconductor based on photoluminescence and SERS technology", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface-enhanced Raman scattering (SERS) and photoluminescence (PL) are important photoexcitation spectroscopy techniques; however, understanding how to analyze and modulate the relationship between SERS and PL is rather important for enhancing SERS, having a great effect on practical applications. In this work, a charge-transfer (CT) mechanism is proposed to investigate the change and relationships between SERS and PL. Analyzing the change in PL and SERS before and after the adsorption of the probe molecules on Nd-doped ZnO indicates that the unique optical characteristics of Nd3+ ions increase the SERS signal. On the other hand, the observed SERS can be used to explain the cause of PL background reduction. This study demonstrates that modulating the interaction between the probe molecules and the substrate can not only enhance Raman scattering but also reduce the SERS background. Our work also provides a guideline for the investigation of CT as well as a new method for exploring fluorescence quenching. Spectroscopy: rare earths help sensors focus on the necessitiesSensors that use laser light scattering to detect molecular-scale changes to samples can be improved with a new substrate that naturally reduces background interference. Surface-enhanced Raman spectroscopy (SERS) setups typically use a combination of metal nulloparticles and fluorescent probes to capture vibrational signals from biomolecules including DNA. Ming Gao from Jilin Normal University in Siping, China, and colleagues now report a technique to keep probe emissions from interfering with SERS signals. To accomplish this, the team synthesized a neodymium-doped zinc oxide spiky nullostructures substrate. Spectroscopic measurements revealed that neodymium's electronic properties enabled it to transfer photoexcited electrons to the probes. This charge transfer reduced the probe's fluorescent intensity and simultaneously enhanced SERS emissions beyond that available on pure zinc oxide surfaces. This study provides a new way to naturally eliminate the SERS fluorescence background by doping with Nd ions. These fundamental discussions here provide a path to enhance Raman scattering and reduce the SERS background and a guideline for the investigation of CT and a new method for exploring fluorescence quenching.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 117, "DOI": "10.1038/s41377-020-00361-0", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-00361-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552063400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SM; Kim, CH; Kim, Y; Kim, N; Lee, WJ; Lee, EH; Kim, D; Park, S; Lee, K; Rivnay, J; Yoon, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Seong-Min; Kim, Chang-Hyun; Kim, Youngseok; Kim, Nara; Lee, Won-June; Lee, Eun-Hak; Kim, Dokyun; Park, Sungjun; Lee, Kwanghee; Rivnay, Jonathan; Yoon, Myung-Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of PEDOT:PSS crystallinity and composition on electrochemical transistor performance and long-term stability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the mixed electron/hole and ion transport in the aqueous environment, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)-based organic electrochemical transistor has been regarded as one of the most promising device platforms for bioelectronics. Nonetheless, there exist very few in-depth studies on how intrinsic channel material properties affect their performance and long-term stability in aqueous environments. Herein, we investigated the correlation among film microstructural crystallinity/composition, device performance, and aqueous stability in poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) films. The highly organized anisotropic ordering in crystallized conducting polymer films led to remarkable device characteristics such as large transconductance (similar to 20 mS), extraordinary volumetric capacitance (113 F.cm(-3)), and unprecedentedly high [mu C*] value (similar to 490 F.cm(-1) V-1 s(-1)). Simultaneously, minimized poly(styrenesulfonate) residues in the crystallized film substantially afforded marginal film swelling and robust operational stability even after >20-day water immersion, >2000-time repeated on-off switching, or high-temperature/pressure sterilization. We expect that the present study will contribute to the development of long-term stable implantable bioelectronics for neural recording/stimulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 359, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3858, "DOI": "10.1038/s41467-018-06084-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-06084-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445270100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ramakrishnull, R; Dral, PO; Rupp, M; von Lilienfeld, OA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ramakrishnull, Raghunathan; Dral, Pavlo O.; Rupp, Matthias; von Lilienfeld, O. Anatole", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum chemistry structures and properties of 134 kilo molecules", "Source Title": "SCIENTIFIC DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational de novo design of new drugs and materials requires rigorous and unbiased exploration of chemical compound space. However, large uncharted territories persist due to its size scaling combinatorially with molecular size. We report computed geometric, energetic, electronic, and thermodynamic properties for 134k stable small organic molecules made up of CHONF. These molecules correspond to the subset of all 133,885 species with up to nine heavy atoms (CONF) out of the GDB-17 chemical universe of 166 billion organic molecules. We report geometries minimal in energy, corresponding harmonic frequencies, dipole moments, polarizabilities, along with energies, enthalpies, and free energies of atomization. All properties were calculated at the B3LYP/6-31G(2df,p) level of quantum chemistry. Furthermore, for the predominullt stoichiometry, C7H10O2, there are 6,095 constitutional isomers among the 134k molecules. We report energies, enthalpies, and free energies of atomization at the more accurate G(4)MP(2) level of theory for all of them. As such, this data set provides quantum chemical properties for a relevant, consistent, and comprehensive chemical space of small organic molecules. This database may serve the benchmarking of existing methods, development of new methods, such as hybrid quantum mechanics/machine learning, and systematic identification of structure-property relationships.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1200, "Times Cited, All Databases": 1313, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 140022, "DOI": "10.1038/sdata.2014.22", "DOI Link": "http://dx.doi.org/10.1038/sdata.2014.22", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000209843500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de Jong, E; Visser, HA; Dias, AS; Harvey, C; Gruter, GJM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de Jong, Ed; Visser, Hendrikus (Roy) A.; Dias, Ana Sousa; Harvey, Clare; Gruter, Gert-Jan M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Road to Bring FDCA and PEF to the Market", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biobased polymers and materials are desperately needed to replace fossil-based materials in the world's transition to a more sustainable lifestyle. In this article, Avantium describes the path from invention towards commercialization of their YXY (R) plants-to-plastics Technology, which catalytically converts plant-based sugars into FDCA-the chemical building block for PEF (polyethylene furanoate). PEF is a plant-based, highly recyclable plastic, with superior performance properties compared to today's widely used petroleum-based packaging materials. The myriad of topics that must be addressed in the process of bringing a new monomer and polymer to market are discussed, including process development and application development, regulatory requirements, IP protection, commercial partnerships, by-product valorisation, life cycle assessment (LCA), recyclability and circular economy fit, and end-of-life. Advice is provided for others considering embarking on a similar journey, as well as an outlook on the next, exciting steps towards large-scale production of FDCA and PEF at Avantium's Flagship Plant and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 943, "DOI": "10.3390/polym14050943", "DOI Link": "http://dx.doi.org/10.3390/polym14050943", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771439700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mosser, L; Dubrule, O; Blunt, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mosser, Lukas; Dubrule, Olivier; Blunt, Martin J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstruction of three-dimensional porous media using generative adversarial neural networks", "Source Title": "PHYSICAL REVIEW E", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To evaluate the variability of multiphase flow properties of porous media at the pore scale, it is necessary to acquire a number of representative samples of the void-solid structure. While modern x-ray computer tomography has made it possible to extract three-dimensional images of the pore space, assessment of the variability in the inherent material properties is often experimentally not feasible. We present a method to reconstruct the solid-void structure of porous media by applying a generative neural network that allows an implicit description of the probability distribution represented by three-dimensional image data sets. We show, by using an adversarial learning approach for neural networks, that this method of unsupervised learning is able to generate representative samples of porous media that honor their statistics. We successfully compare measures of pore morphology, such as the Euler characteristic, two-point statistics, and directional single-phase permeability of synthetic realizations with the calculated properties of a bead pack, Berea sandstone, and Ketton limestone. Results show that generative adversarial networks can be used to reconstruct high-resolution three-dimensional images of porous media at different scales that are representative of the morphology of the images used to train the neural network. The fully convolutional nature of the trained neural network allows the generation of large samples while maintaining computational efficiency. Compared to classical stochastic methods of image reconstruction, the implicit representation of the learned data distribution can be stored and reused to generate multiple realizations of the pore structure very rapidly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2017, "Volume": 96, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 43309, "DOI": "10.1103/PhysRevE.96.043309", "DOI Link": "http://dx.doi.org/10.1103/PhysRevE.96.043309", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413450300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SQ; Li, W; Li, SS; Zhang, XY; Chen, ZW; Xu, YD; Chen, Y; Pei, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Siqi; Li, Wen; Li, Shasha; Zhang, Xinyue; Chen, Zhiwei; Xu, Yidong; Chen, Yue; Pei, Yanzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Thermoelectric Performance of Ag9GaSe6 Enabled by Low Cutoff Frequency of Acoustic Phonons", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When the number of atoms in a primitive cell (N) increases, the first Brillouin zone shrinks and folds back the high-frequency portion of acoustic vibrations as optical ones with reduced velocities near zone boundaries. Soft bonds lead to flattened phonon dispersion and thus a low sound velocity. This work shows the cutoff frequency of acoustic phonons (omega(m)) as an important parameter to include both effects on the lattice thermal conductivity (k(L)). A low omega(m) of similar to 0.5 THz in Ag(9)GaSe(6)due to its large N and weakly bonded Ag atoms leads this material to be one of the least thermally conductive dense solids (kL similar to 0.15 W/m K). This contributes to the peak thermoelectric figure of merit, zT, as high as 1.5. The principle used here not only leads to the exploration of Ag9GaSe6 as a promising thermoelectric but also enables a measurable parameter for designing materials with expected k(L).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2017, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 816, "End Page": 830, "Article Number": null, "DOI": "10.1016/j.joule.2017.09.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.09.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425302500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Madenci, E; Oterkus, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Madenci, Erdogan; Oterkus, Selda", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ordinary state-based peridynamics for plastic deformation according to von Mises yield criteria with isotropic hardening", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study presents the ordinary state-based peridynamic constitutive relations for plastic deformation based on von Mises yield criteria with isotropic hardening. The peridynamic force density-stretch relations concerning elastic deformation are augmented with increments of force density and stretch for plastic deformation. The expressions for the yield function and the rule of incremental plastic stretch are derived in terms of the horizon, force density, shear modulus, and hardening parameter of the material. The yield surface is constructed based on the relationship between the effective stress and equivalent plastic stretch. The validity of peridynamic predictions is established by considering benchmark solutions concerning a plate under tension, a plate with a hole and a crack also under tension. (C) 2015 Published by Elgevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 86, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 192, "End Page": 219, "Article Number": null, "DOI": "10.1016/j.jmps.2015.09.016", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2015.09.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365372200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roknuzzaman, M; Ostrikov, K; Wang, HX; Du, AJ; Tesfamichael, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roknuzzaman, Md; Ostrikov, Kostya (Ken); Wang, Hongxia; Du, Aijun; Tesfamichael, Tuquabo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards lead-free perovskite photovoltaics and optoelectronics by ab-initio simulations", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead (Pb) free non-toxic perovskite solar cells have become more important in the commercialization of the photovoltaic devices. In this study the structural, electronic, optical and mechanical properties of Pb-free inorganic metal halide cubic perovskites CsBX3 (B = Sn, Ge; X = I, Br, Cl) for perovskite solar cells are simulated using first-principles Density Functional Theory (DFT). These compounds are semiconductors with direct band gap energy and mechanically stable. Results suggest that the materials have high absorption coefficient, low reflectivity and high optical conductivity with potential application in solar cells and other optoelectronic energy devices. On the basis of the optical properties, one can expect that the Germanium (Ge) would be a better replacement of Pb as Ge containing compounds have higher optical absorption and optical conductivity than that of Pb containing compounds. A combinational analysis of the electronic, optical and mechanical properties of the compounds suggests that CsGeI3 based perovskite is the best Pb-free inorganic metal halide semiconductor for the solar cell application. However, the compound with solid solution of CsGe(I(0.)7Br(0.3))(3) is found to be mechanically more ductile than CsGeI3. This study will also guide to obtain Pb-free organic perovskites for optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 444, "Times Cited, All Databases": 451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 25", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14025, "DOI": "10.1038/s41598-017-13172-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-13172-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413700200064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, B; Li, B; Li, K; Liu, YY; Li, CH; Zheng, LL; Zhang, MJ; Yang, TR; Guo, S; Dong, XY; Zhang, T; Liu, Q; Hussain, A; Weng, YH; Peng, L; Zhao, YX; Liang, XJ; Huang, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Bo; Li, Bo; Li, Kun; Liu, Yuanyuan; Li, Chunhui; Zheng, Lulu; Zhang, Mengjie; Yang, Tongren; Guo, Shuai; Dong, Xiyu; Zhang, Tian; Liu, Qing; Hussain, Abid; Weng, Yuhua; Peng, Ling; Zhao, Yongxiang; Liang, Xing-Jie; Huang, Yuanyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermostable ionizable lipid-like nulloparticle (iLAND) for RNAi treatment of hyperlipidemia", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Small interfering RNA (siRNA) therapeutic is considered to be a promising modality for the treatment of hyperlipidemia. Establishment of a thermostable clinically applicable delivery system remains a most challenging issue for siRNA drug development. Here, a series of ionizable lipid-like materials were rationally designed; 4 panels of lipid formulations were fabricated and evaluated on the basis of four representative structures. The lead lipid (A1-D1-5) was stable at 40 degrees C, and the optimized formulation (iLAND) showed dose and time dual-dependent gene silencing pattern with median effective dose of 0.18 mg/kg. In addition, potent and durable reduction of serum cholesterol and triglyceride were achieved by administering siRNAs targeting angiopoietin-like 3 or apolipoprotein C3 (APOC3) in high-fat diet-fed mice, db/db mice, and human APOC3 transgenic mice, respectively, accompanied by displaying ideal safety profiles. Therefore, siRNA@iLAND prepared with thermostable A1-D1-5 demonstrates substantial value for siRNA delivery, hyperlipidemia therapy, and prevention of subsequent metabolic diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm1418", "DOI": "10.1126/sciadv.abm1418", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm1418", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757399100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, ZR; Xing, YQ; Cheng, JZ; Zhang, G; Shen, ZQ; Zhang, YJ; Liao, GF; Chen, L; Liu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Zhi-Rong; Xing, Yu-Qin; Cheng, Jing-Zhao; Zhang, Guang; Shen, Zhao-Qi; Zhang, Yu-Jie; Liao, Guangfu; Chen, Long; Liu, Shi-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "EDOT-based conjugated polymers accessed via C-H direct arylation for efficient photocatalytic hydrogen production", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "3,4-Ethylene dioxythiophene (EDOT), as a monomer of commercial conductive poly(3,4-ethylene dioxythiophene) (PEDOT), has been facilely incorporated into a series of new pi-conjugated polymer-based photocatalysts, i.e., BSO2-EDOT, DBT-EDOT, Py-EDOT and DFB-EDOT, through atom-economic C-H direct arylation polymerization (DArP). The photocatalytic hydrogen production (PHP) test shows that donor-acceptor (D-A)-type BSO2-EDOT renders the highest hydrogen evolution rate (HER) among the linear conjugated polymers (CPs) ever reported. A HER up to 0.95 mmol h(-1)/6 mg under visible light irradiation and an unprecedented apparent quantum yield of 13.6% at 550 nm are successfully achieved. Note that the photocatalytic activities of the C-H/C-Br coupling-derived EDOT-based CPs are superior to those of their counterparts derived from the classical C-Sn/C-Br Stille coupling, demonstrating that EDOT is a promising electron-rich building block which can be facilely integrated into CP-based photocatalysts. Systematic studies reveal that the enhanced water wettability by the integration of polar BSO2 with hydrophilic EDOT, the increased electron-donating ability by O-C p-pi conjugation, the improved electron transfer by D-A architecture, broad light harvesting, and the nullo-sized colloidal character in a H2O/NMP mixed solvent rendered BSO2-EDOT as one of the best CP photocatalysts toward PHP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2022, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1725, "End Page": 1733, "Article Number": null, "DOI": "10.1039/d1sc05784g", "DOI Link": "http://dx.doi.org/10.1039/d1sc05784g", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746048800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WX; Xie, X; Hao, HM; Dang, JC; Xiao, S; Shi, SS; Ni, HQ; Niu, ZC; Wang, C; Jin, KJ; Zhang, XD; Xu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Weixuan; Xie, Xin; Hao, Huiming; Dang, Jianchen; Xiao, Shan; Shi, Shushu; Ni, Haiqiao; Niu, Zhichuan; Wang, Can; Jin, Kuijuan; Zhang, Xiangdong; Xu, Xiulai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-threshold topological nullolasers based on the second-order corner state", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullophotonics: Creating better performing topological lasers A high-performance topological laser could pave the way for its use in a wide range of nullophotonic applications. Semiconductor lasers are the most common type of laser, but their performance deteriorates if there are any structural defects in the lasing material. Topological lasers allow light to travel around a cavity of any shape without scattering, promising better performing lasers. However, creating a topological laser with a low threshold for lasing and high efficiency has proved challenging. A team of Chinese researchers led by Xiulai Xu from the Chinese Academy of Sciences have now developed a topological laser made from a two-dimensional photonic crystal nullocavity slab with a lasing threshold of about one micro-watt and high spontaneous emission coupling factor of 0.25 and is comparable to the performance of conventional semiconductor lasers. Topological lasers are immune to imperfections and disorder. They have been recently demonstrated based on many kinds of robust edge states, which are mostly at the microscale. The realization of 2D on-chip topological nullolasers with a small footprint, a low threshold and high energy efficiency has yet to be explored. Here, we report the first experimental demonstration of a topological nullolaser with high performance in a 2D photonic crystal slab. A topological nullocavity is formed utilizing the Wannier-type 0D corner state. Lasing behaviour with a low threshold of approximately 1 mu W and a high spontaneous emission coupling factor of 0.25 is observed with quantum dots as the active material. Such performance is much better than that of topological edge lasers and comparable to that of conventional photonic crystal nullolasers. Our experimental demonstration of a low-threshold topological nullolaser will be of great significance to the development of topological nullophotonic circuitry for the manipulation of photons in classical and quantum regimes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 109, "DOI": "10.1038/s41377-020-00352-1", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-00352-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000545446300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sheng, XL; Chen, C; Liu, HY; Chen, ZY; Yu, ZM; Zhao, YX; Yang, SYA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sheng, Xian-Lei; Chen, Cong; Liu, Huiying; Chen, Ziyu; Yu, Zhi-Ming; Zhao, Y. X.; Yang, Shengyuan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional Second-Order Topological Insulator in Graphdiyne", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A second-order topological insulator (SOTI) in d spatial dimensions features topologically protected gapless states at its (d - 2)-dimensional boundary at the intersection of two crystal faces, but is gapped otherwise. As a novel topological state, it has been attracting great interest, but it remains a challenge to identify a realistic SOTI material in two dimensions (2D). Here, based on combined first-principles calculations and theoretical analysis, we reveal the already experimentally synthesized 2D material graphdiyne as the first realistic example of a 2D SOTI, with topologically protected 0D corner states. The role of crystalline symmetry, the robustness against symmetry breaking, and the possible experimental characterization are discussed. Our results uncover a hidden topological character of graphdiyne and promote it as a concrete material platform for exploring the intriguing physics of higher-order topological phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 123, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 256402, "DOI": "10.1103/PhysRevLett.123.256402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.123.256402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503245200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rydén, M; Leion, H; Mattisson, T; Lyngfelt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ryden, Magnus; Leion, Henrik; Mattisson, Tobias; Lyngfelt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen-carrier materials for chemical-looping with oxygen uncoupling (CLOU) must be capable of taking up and releasing gas-phase O-2 at conditions relevant for generation of heat and power. In principle, the capability of a certain material to do so is determined by its thermodynamic properties. This paper provides an overview of the possibility to design feasible oxygen carrier materials from combined oxides, i.e. oxides with crystal structures that include several different cations. Relevant literature is reviewed and the thermodynamic properties and key characteristics of a few selected combined oxide systems are calculated and compared to experimental data. The general challenges and opportunities of the combined oxide concept are discussed. The focus is on materials with manganese as one of its components and the following families of compounds and solid solutions have been considered: (MnyFe1-y)Ox, (MnySi1-y)Ox, caMnO(3-delta), (NiyMn1-y)Ox, MnyCu1-y)Ox and (MnyMg1-y)Ox. In addition to showing promise from a thermodynamic point of view, reactivity data from experimental investigations suggests that the rate of O-2 release can be high for all systems. Thus these combined oxides could also be very suitable for practical application. (C) 2013 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2014, "Volume": 113, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1924, "End Page": 1932, "Article Number": null, "DOI": "10.1016/j.apenergy.2013.06.016", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2013.06.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000329952500187", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Puckett, MW; Liu, KK; Chauhan, N; Zhao, QC; Jin, NJ; Cheng, HT; Wu, JF; Behunin, RO; Rakich, PT; Nelson, KD; Blumenthal, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Puckett, Matthew W.; Liu, Kaikai; Chauhan, Nitesh; Zhao, Qiancheng; Jin, Naijun; Cheng, Haotian; Wu, Jianfeng; Behunin, Ryan O.; Rakich, Peter T.; Nelson, Karl D.; Blumenthal, Daniel J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "422 Million intrinsic quality factor planar integrated all-waveguide resonator with sub-MHz linewidth", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High quality-factor (Q) optical resonators are a key component for ultra-narrow linewidth lasers, frequency stabilization, precision spectroscopy and quantum applications. Integration in a photonic waveguide platform is key to reducing cost, size, power and sensitivity to environmental disturbances. However, to date, the Q of all-waveguide resonators has been relegated to below 260 Million. Here, we report a Si3N4 resonator with 422 Million intrinsic and 3.4 Billion absorption-limited Qs. The resonator has 453kHz intrinsic, 906kHz loaded, and 57kHz absorption-limited linewidths and the corresponding 0.060dBm(-1) loss is the lowest reported to date for waveguides with deposited oxide upper cladding. These results are achieved through a careful reduction of scattering and absorption losses that we simulate, quantify and correlate to measurements. This advancement in waveguide resonator technology paves the way to all-waveguide Billion Q cavities for applications including nonlinear optics, atomic clocks, quantum photonics and high-capacity fiber communications. Integrated photonic all-waveguide resonators are a critical component in many future applications. Here the authors develop an optimized photonic all-waveguide resonator with an ultra-high quality factor, Q, of almost half a billion, and a narrow sub-MHz linewidth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 934, "DOI": "10.1038/s41467-021-21205-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21205-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000620139600035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moody, G; Dass, CK; Hao, K; Chen, CH; Li, LJ; Singh, A; Tran, K; Clark, G; Xu, XD; Berghäuser, G; Malic, E; Knorr, A; Li, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moody, Galan; Dass, Chandriker Kavir; Hao, Kai; Chen, Chang-Hsiao; Li, Lain-Jong; Singh, Akshay; Kha Tran; Clark, Genevieve; Xu, Xiaodong; Berghaeuser, Gunnar; Malic, Ermin; Knorr, Andreas; Li, Xiaoqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic homogeneous linewidth and broadening mechanisms of excitons in monolayer transition metal dichalcogenides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The band-edge optical response of transition metal dichalcogenides, an emerging class of atomically thin semiconductors, is dominated by tightly bound excitons localized at the corners of the Brillouin zone (valley excitons). A fundamental yet unknown property of valley excitons in these materials is the intrinsic homogeneous linewidth, which reflects irreversible quantum dissipation arising from system (exciton) and bath (vacuum and other quasiparticles) interactions and determines the timescale during which excitons can be coherently manipulated. Here we use optical two-dimensional Fourier transform spectroscopy to measure the exciton homogeneous linewidth in monolayer tungsten diselenide (WSe2). The homogeneous linewidth is found to be nearly two orders of magnitude narrower than the inhomogeneous width at low temperatures. We evaluate quantitatively the role of exciton-exciton and exciton-phonon interactions and population relaxation as linewidth broadening mechanisms. The key insights reported here-strong many-body effects and intrinsically rapid radiative recombination-are expected to be ubiquitous in atomically thin semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 438, "Times Cited, All Databases": 514, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8315, "DOI": "10.1038/ncomms9315", "DOI Link": "http://dx.doi.org/10.1038/ncomms9315", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363020300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Neupane, M; Belopolski, I; Hosen, MM; Sanchez, DS; Sankar, R; Szlawska, M; Xu, SY; Dimitri, K; Dhakal, N; Maldonado, P; Oppeneer, PM; Kaczorowski, D; Chou, FC; Hasan, MZ; Durakiewicz, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Neupane, Madhab; Belopolski, Ilya; Hosen, M. Mofazzel; Sanchez, Daniel S.; Sankar, Raman; Szlawska, Maria; Xu, Su-Yang; Dimitri, Klauss; Dhakal, Nagendra; Maldonado, Pablo; Oppeneer, Peter M.; Kaczorowski, Dariusz; Chou, Fangcheng; Hasan, M. Zahid; Durakiewicz, Tomasz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of topological nodal fermion semimetal phase in ZrSiS", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unveiling new topological phases of matter is one of the current objectives in condensed matter physics. Recent experimental discoveries of Dirac and Weyl semimetals prompt the search for other exotic phases of matter. Here we present a systematic angle-resolved photoemission spectroscopy study of ZrSiS, a prime topological nodal semimetal candidate. Our wider Brillouin zone (BZ) mapping shows multiple Fermi surface pockets such as the diamond-shaped Fermi surface, elliptical-shaped Fermi surface, and a small electron pocket encircling at the zone center (Gamma) point, the M point, and the X point of the BZ, respectively. We experimentally establish the spinless nodal fermion semimetal phase in ZrSiS, which is supported by our first-principles calculations. Our findings evidence that the ZrSiS-type of material family is a new platform on which to explore exotic states of quantum matter; these materials are expected to provide an avenue for engineering two-dimensional topological insulator systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 323, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2016, "Volume": 93, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 201104, "DOI": "10.1103/PhysRevB.93.201104", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.201104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375997100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Zhang, YQ; Jiang, SJ; Sun, CZ; Song, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jie; Zhang, Yiqi; Jiang, Shujuan; Sun, Chuanzhi; Song, Shaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulation of d-Band Centers in Localized CdS Homojunctions through Facet Control for Improved Photocatalytic Water Splitting", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The accelerated kinetic behaviour of charge carrier transfer and its unhindered surface reaction dynamic process involving oxygenated-intermediate activation and conversion are urgently required in photocatalytic water (H2O) overall splitting, which has not been nevertheless resolved yet. Herein, localized CdS homojunctions with optimal collocation of high and low index facets to regulate d-band center for chemically adsorbing and activating key intermediates (*-OH and *-O) have been achieved in H2O overall splitting into hydrogen. Density functional theory, hall effect, and in situ diffuse reflectance infrared Fourier transform spectroscopy confirm that, electrons and holes are kinetically transferred to reductive high index facet (002) and oxidative low index facet (110) of the localized CdS homojunction induced by facet Fermi level difference to dehydrogenate *-OH and couple *-O for hydrogen and oxygen evolution, respectively, along with a solar conversion into hydrogen (STH) of 2.20 % by Air Mass 1.5 Global filter irradiation. These findings contribute to solving the kinetic bottleneck issues of photocatalytic H2O splitting, which will further enhance STH.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2023, "Volume": 62, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202307808", "DOI Link": "http://dx.doi.org/10.1002/anie.202307808", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032249300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wahyudi, W; Guo, XR; Ladelta, V; Tsetseris, L; Nugraha, M; Lin, YB; Tung, V; Hadjichristidis, N; Li, Q; Xu, K; Ming, J; Anthopoulos, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wahyudi, Wandi; Guo, Xianrong; Ladelta, Viko; Tsetseris, Leonidas; Nugraha, Mohamad, I; Lin, Yuanbao; Tung, Vincent; Hadjichristidis, Nikos; Li, Qian; Xu, Kang; Ming, Jun; Anthopoulos, Thomas D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hitherto Unknown Solvent and Anion Pairs in Solvation Structures Reveal New Insights into High-Performance Lithium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solvent-solvent and solvent-anion pairings in battery electrolytes have been identified for the first time by nuclear magnetic resonullce spectroscopy. These hitherto unknown interactions are enabled by the hydrogen bonding induced by the strong Lewis acid Li+, and exist between the electron-deficient hydrogen (delta H+) present in the solvent molecules and either other solvent molecules or negatively-charged anions. Complementary with the well-established strong but short-ranged Coulombic interactions between cation and solvent molecules, such weaker but longer-ranged hydrogen-bonding casts the formation of an extended liquid structure in electrolytes that is influenced by their components (solvents, additives, salts, and concentration), which in turn dictates the ion transport within bulk electrolytes and across the electrolyte-electrode interfaces. The discovery of this new inter-component force completes the picture of how electrolyte components interact and arrange themselves, sets the foundation to design better electrolytes on the fundamental level, and probes battery performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 9, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202405, "DOI": "10.1002/advs.202202405", "DOI Link": "http://dx.doi.org/10.1002/advs.202202405", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000841117100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gan, ZR; Wang, L; Cai, JL; Guo, CH; Chen, C; Li, DH; Fu, YW; Zhou, BJ; Sun, YD; Liu, CH; Zhou, J; Liu, D; Li, W; Wang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gan, Zirui; Wang, Liang; Cai, Jinlong; Guo, Chuanhang; Chen, Chen; Li, Donghui; Fu, Yiwei; Zhou, Bojun; Sun, Yuandong; Liu, Chenhao; Zhou, Jing; Liu, Dan; Li, Wei; Wang, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrostatic force promoted intermolecular stacking of polymer donors toward 19.4% efficiency binary organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymers are generally featured with low structural order due to their aromatic and irregular structural units, which limits their light absorption and charge mobility in organic solar cells. In this work, we report a conjugated molecule INMB-F that can act as a molecular bridge via electrostatic force to enhance the intermolecular stacking of BDT-based polymer donors toward efficient and stable organic solar cells. Molecular dynamics simulations and synchrotron X-ray measurements reveal that the electronegative INMB-F adsorb on the electropositive main chain of polymer donors to increase the donor-donor interactions, leading to enhanced structural order with shortened pi-pi stacking distance and consequently enhanced charge transport ability. Casting the non-fullerene acceptor layer on top of the INMB-F modified donor layer to fabricate solar cells via layer-by-layer deposition evidences significant power conversion efficiency boosts in a range of photovoltaic systems. A power conversion efficiency of 19.4% (certified 18.96%) is realized in PM6/L8-BO binary devices, which is one of the highest reported efficiencies of this material system. The enhanced structural order of polymer donors by INMB-F also leads to a six-fold enhancement of the operational stability of PM6/L8-BO organic solar cells. The low structural order of conjugated polymers limits their photovoltaic properties in organic solar cells. Here, the authors report a conjugated molecule as molecular bridge via electrostatic force for enhancing intermolecular packing, achieving certified efficiency close to 19% in binary devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6297, "DOI": "10.1038/s41467-023-42071-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42071-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001084565900036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stern, HL; Gu, QS; Jarman, J; Barker, SE; Mendelson, N; Chugh, D; Schott, S; Tan, HH; Sirringhaus, H; Aharonovich, I; Atatüre, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stern, Hannah L.; Gu, Qiushi; Jarman, John; Barker, Simone Eizagirre; Mendelson, Noah; Chugh, Dipankar; Schott, Sam; Tan, Hoe H.; Sirringhaus, Henning; Aharonovich, Igor; Atature, Mete", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature optically detected magnetic resonullce of single defects in hexagonal boron nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optically active spins in solid-state materials hold promise for future quantum technologies. Here, the authors demonstrate optically detected magnetic resonullce at room temperature for single defects in a two-dimensional material, hexagonal boron nitride. Optically addressable solid-state spins are important platforms for quantum technologies, such as repeaters and sensors. Spins in two-dimensional materials offer an advantage, as the reduced dimensionality enables feasible on-chip integration into devices. Here, we report room-temperature optically detected magnetic resonullce (ODMR) from single carbon-related defects in hexagonal boron nitride with up to 100 times stronger contrast than the ensemble average. We identify two distinct bunching timescales in the second-order intensity-correlation measurements for ODMR-active defects, but only one for those without an ODMR response. We also observe either positive or negative ODMR signal for each defect. Based on kinematic models, we relate this bipolarity to highly tuneable internal optical rates. Finally, we resolve an ODMR fine structure in the form of an angle-dependent doublet resonullce, indicative of weak but finite zero-field splitting. Our results offer a promising route towards realising a room-temperature spin-photon quantum interface in hexagonal boron nitride.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 618, "DOI": "10.1038/s41467-022-28169-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28169-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749535300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YZ; Zhou, Q; Liu, HJ; Xu, WJ; Wang, ZX; Qiao, SC; Ding, HH; Chen, DL; Zhu, JF; Qi, ZM; Wu, XJ; He, Q; Song, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yuzhu; Zhou, Quan; Liu, Hengjie; Xu, Wenjie; Wang, Zhouxin; Qiao, Sicong; Ding, Honghe; Chen, Dongliang; Zhu, Junfa; Qi, Zeming; Wu, Xiaojun; He, Qun; Song, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Asymmetric dinitrogen-coordinated nickel single-atomic sites for efficient CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of electrocatalysts for selective CO2 conversion is of great interests. Here the authors show that Ni single atom with asymmetric pyrrolic and pyridinic nitrogen for efficient CO2 electroconversion to CO. Developing highly efficient, selective and low-overpotential electrocatalysts for carbon dioxide (CO2) reduction is crucial. This study reports an efficient Ni single-atom catalyst coordinated with pyrrolic nitrogen and pyridinic nitrogen for CO2 reduction to carbon monoxide (CO). In flow cell experiments, the catalyst achieves a CO partial current density of 20.1 mA cm(geo)(-2) at -0.15 V vs. reversible hydrogen electrode (V-RHE). It exhibits a high turnover frequency of over 274,000 site(-1) h(-1) at -1.0 V-RHE and maintains high Faradaic efficiency of CO (FECO) exceeding 90% within -0.15 to -0.9 V-RHE. Operando synchrotron-based infrared and X-ray absorption spectra, and theoretical calculations reveal that mono CO-adsorbed Ni single sites formed during electrochemical processes contribute to the balance between key intermediates formation and CO desorption, providing insights into the catalyst's origin of catalytic activity. Overall, this work presents a Ni single-atom catalyst with good selectivity and activity for CO2 reduction while shedding light on its underlying mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3776, "DOI": "10.1038/s41467-023-39505-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39505-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001018100800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Madéo, J; Man, MKL; Sahoo, C; Campbell, M; Pareek, V; Wong, EL; Al-Mahboob, A; Chan, NS; Karmakar, A; Mariserla, BMK; Li, XQ; Heinz, TF; Cao, T; Dani, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Madeo, Julien; Man, Michael K. L.; Sahoo, Chakradhar; Campbell, Marshall; Pareek, Vivek; Wong, E. Laine; Al-Mahboob, Abdullah; Chan, Nicholas S.; Karmakar, Arka; Mariserla, Bala Murali Krishna; Li, Xiaoqin; Heinz, Tony F.; Cao, Ting; Dani, Keshav M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directly visualizing the momentum-forbidden dark excitons and their dynamics in atomically thin semiconductors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Resolving momentum degrees of freedom of excitons, which are electron-hole pairs bound by the Coulomb attraction in a photoexcited semiconductor, has remained an elusive goal for decades. In atomically thin semiconductors, such a capability could probe the momentum-forbidden dark excitons, which critically affect proposed opto-electronic technologies but are not directly accessible using optical techniques. Here, we probed the momentum state of excitons in a tungsten diselenide monolayer by photoemitting their constituent electrons and resolving them in time, momentum, and energy. We obtained a direct visual of the momentum-forbidden dark excitons and studied their properties, including their near degeneracy with bright excitons and their formation pathways in the energy-momentum landscape. These dark excitons dominated the excited-state distribution, a surprising finding that highlights their importance in atomically thin semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 4", "Publication Year": 2020, "Volume": 370, "Issue": 6521, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1199, "End Page": 1203, "Article Number": null, "DOI": "10.1126/science.aba1029", "DOI Link": "http://dx.doi.org/10.1126/science.aba1029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596071300058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LW; Chan, YC; Ahmed, F; Liu, Z; Zhu, P; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Liwei; Chan, Yu-Chin; Ahmed, Faez; Liu, Zhao; Zhu, Ping; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep generative modeling for mechanistic-based learning and design of metamaterial systems", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metamaterials are emerging as a new paradigmatic material system to render unprecedented and tailorable properties for a wide variety of engineering applications. However, the inverse design of metamaterial and its multiscale system is challenging due to high-dimensional topological design space, multiple local optima, and high computational cost. To address these hurdles, we propose a novel data-driven metamaterial design framework based on deep generative modeling. A variational autoencoder (VAE) and a regressor for property prediction are simultaneously trained on a large metamaterial database to map complex microstructures into a low-dimensional, continuous, and organized latent space. We show in this study that the latent space of VAE provides a distance metric to measure shape similarity, enable interpolation between microstructures and encode meaningful patterns of variation in geometries and properties. Based on these insights, systematic data-driven methods are proposed for the design of microstructure, graded family, and multiscale system. For microstructure design, the tuning of mechanical properties and complex manipulations of microstructures are easily achieved by simple vector operations in the latent space. The vector operation is further extended to generate metamaterial families with a controlled gradation of mechanical properties by searching on a constructed graph model. For multiscale metamaterial systems design, a diverse set of microstructures can be rapidly generated using VAE for target properties at different locations and then assembled by an efficient graph-based optimization method to ensure compatibility between adjacent microstructures. We demonstrate our framework by designing both functionally graded and heterogeneous metamaterial systems that achieve desired distortion behaviors. (C) 2020 Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2020, "Volume": 372, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113377, "DOI": "10.1016/j.cma.2020.113377", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2020.113377", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592539200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, WH; Semenok, DV; Huang, XL; Shu, HY; Li, X; Duan, DF; Cui, T; Oganov, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wuhao; Semenok, Dmitrii, V; Huang, Xiaoli; Shu, Haiyun; Li, Xin; Duan, Defang; Cui, Tian; Oganov, Artem R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Temperature Superconducting Phases in Cerium Superhydride with a Tc up to 115 K below a Pressure of 1 Megabar", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discoveries of high-temperature superconductivity in H3S and LaH10 have excited the search for superconductivity in compressed hydrides, finally leading to the first discovery of a room-temperature superconductor in a carbonaceous sulfur hydride. In contrast to rapidly expanding theoretical studies, high-pressure experiments on hydride superconductors are expensive and technically challenging. Here, we experimentally discovered superconductivity in two new phases, Fm (3) over barm-CaH10 (SC-I phase) and P6(3)/mmc-CeH9 (SC-II phase) at pressures that are much lower (<100 GPa) than those needed to stabilize other polyhydride superconductors. Superconductivity was evidenced by a sharp drop of the electrical resistance to zero and decreased critical temperature in deuterated samples and in external magnetic field. SC-I has T-c = 115 K at 95 GPa, showing an expected decrease in further compression due to the decrease of the electron-phonon coupling (EPC) coefficient lambda (from 2.0 at 100 GPa to 0.8 at 200 GPa). SC-II has T-c = 57 K at 88 GPa, rapidly increasing to a maximum T-c similar to 100 K at 130 GPa, and then decreasing in further compression. According to the theoretical calculation, this is due to a maximum of lambda at the phase transition from P6(3)/mmc-CeH9 into a symmetry-broken modification C2/c-CeH9. The pressure-temperature conditions of synthesis affect the actual hydrogen content and the actual value of T-c. Anomalously low pressures of stability of cerium superhydrides make them appealing for studies of superhydrides and for designing new superhydrides with stability at even lower pressures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 171, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2021, "Volume": 127, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 117001, "DOI": "10.1103/PhysRevLett.127.117001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.127.117001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000704656200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jinnouchi, R; Lahnsteiner, J; Karsai, F; Kresse, G; Bokdam, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jinnouchi, Ryosuke; Lahnsteiner, Jonathan; Karsai, Ferenc; Kresse, Georg; Bokdam, Menno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase Transitions of Hybrid Perovskites Simulated by Machine-Learning Force Fields Trained on the Fly with Bayesian Inference", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realistic finite temperature simulations of matter are a formidable challenge for first principles methods. Long simulation times and large length scales are required, demanding years of computing time. Here we present an on-the-fly machine learning scheme that generates force fields automatically during molecular dynamics simulations. This opens up the required time and length scales, while retaining the distinctive chemical precision of first principles methods and minimizing the need for human intervention. The method is widely applicable to multielement complex systems. We demonstrate its predictive power on the entropy driven phase transitions of hybrid perovskites, which have never been accurately described in simulations. Using machine learned potentials, isothermal-isobaric simulations give direct insight into the underlying microscopic mechanisms. Finally, we relate the phase transition temperatures of different perovskites to the radii of the involved species, and we determine the order of the transitions in Landau theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 393, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2019, "Volume": 122, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 225701, "DOI": "10.1103/PhysRevLett.122.225701", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.225701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470885800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Passler, NC; Ni, X; Hu, GW; Matson, JR; Carini, G; Wolf, M; Schubert, M; Alù, A; Caldwell, JD; Folland, TG; Paarmann, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Passler, Nikolai C.; Ni, Xiang; Hu, Guangwei; Matson, Joseph R.; Carini, Giulia; Wolf, Martin; Schubert, Mathias; Alu, Andrea; Caldwell, Joshua D.; Folland, Thomas G.; Paarmann, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperbolic shear polaritons in low-symmetry crystals", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lattice symmetry of a crystal is one of the most important factors in determining its physical properties. Particularly, low-symmetry crystals offer powerful opportunities to control light propagation, polarization and phase(1-4). Materials featuring extreme optical anisotropy can support a hyperbolic response, enabling coupled light-matter interactions, also known as polaritons, with highly directional propagation and compression of light to deeply sub-wavelength scales(5). Here we show that monoclinic crystals can support hyperbolic shear polaritons, a new polariton class arising in the mid-infrared to far-infrared due to shear phenomena in the dielectric response. This feature emerges in materials in which the dielectric tensor cannot be diagonalized, that is, in low-symmetry monoclinic and triclinic crystals in which several oscillators with non-orthogonal relative orientations contribute to the optical response(6,7). Hyperbolic shear polaritons complement previous observations of hyperbolic phonon polaritons in orthorhombic(1,3,4) and hexagonal(8,9) crystal systems, unveiling new features, such as the continuous evolution of their propagation direction with frequency, tilted wavefronts and asymmetric responses. The interplay between diagonal loss and off-diagonal shear phenomena in the dielectric response of these materials has implications for new forms of non-Hermitian and topological photonic states. We anticipate that our results will motivate new directions for polariton physics in low-symmetry materials, which include geological minerals(10), many common oxides(11) and organic crystals(12), greatly expanding the material base and extending design opportunities for compact photonic devices. Shear phenomena in the infrared dielectric response of a monoclinic crystal are shown to unveil a new polariton class termed hyperbolic shear polariton that can emerge in any low-symmetry monoclinic or triclinic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2022, "Volume": 602, "Issue": 7898, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 595, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04328-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04328-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760423100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Berdyugin, AI; Xu, SG; Pellegrino, FMD; Kumar, RK; Principi, A; Torre, I; Ben Shalom, M; Taniguchi, T; Watanabe, K; Grigorieva, IV; Polini, M; Geim, AK; Bandurin, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Berdyugin, A. I.; Xu, S. G.; Pellegrino, F. M. D.; Kumar, R. Krishna; Principi, A.; Torre, I.; Ben Shalom, M.; Taniguchi, T.; Watanabe, K.; Grigorieva, I. V.; Polini, M.; Geim, A. K.; Bandurin, D. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Measuring Hall viscosity of graphene's electron fluid", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An electrical conductor subjected to a magnetic field exhibits the Hall effect in the presence of current flow. Here, we report a qualitative deviation from the standard behavior in electron systems with high viscosity. We found that the viscous electron fluid in graphene responds to nonquantizing magnetic fields by producing an electric field opposite to that generated by the ordinary Hall effect. The viscous contribution is substantial and identified by studying local voltages that arise in the vicinity of current-injecting contacts. We analyzed the anomaly over a wide range of temperatures and carrier densities and extracted the Hall viscosity, a dissipationless transport coefficient that was long identified theoretically but remained elusive in experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2019, "Volume": 364, "Issue": 6436, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 163, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau0685", "DOI Link": "http://dx.doi.org/10.1126/science.aau0685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464620000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, QH; Zhang, YF; Li, JY; Soref, R; Gu, T; Hu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qihang; Zhang, Yifei; Li, Junying; Soref, Richard; Gu, Tian; Hu, Juejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband nonvolatile photonic switching based on optical phase change materials: beyond the classical figure-of-merit", "Source Title": "OPTICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this Letter, we propose a broadband, nonvolatile on-chip switch design in the telecommunication C-band with record low loss and crosstalk. The unprecedented device performance builds on: 1) a new optical phase change material (O-PCM) Ge2Sb2Se4Te1 (GSST), which exhibits significantly reduced optical attenuation compared to traditional O-PCMs, and 2) a nonperturbative design that enables low-loss device operation beyond the classical figure-of- merit (FOM) limit. We further demonstrate that the 1-by-2 and 2-by-2 switches can serve as basic building blocks to construct nonblocking and nonvolatile on-chip switching fabric supporting arbitrary numbers of input and output ports. (C) 2017 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2018, "Volume": 43, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 97, "Article Number": null, "DOI": "10.1364/OL.43.000094", "DOI Link": "http://dx.doi.org/10.1364/OL.43.000094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418610900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rizzo, DJ; Veber, G; Jiang, JW; McCurdy, R; Cao, T; Bronner, C; Chen, T; Louie, SG; Fischer, FR; Crommie, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rizzo, Daniel J.; Veber, Gregory; Jiang, Jingwei; McCurdy, Ryan; Cao, Ting; Bronner, Christopher; Chen, Ting; Louie, Steven G.; Fischer, Felix R.; Crommie, Michael F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inducing metallicity in graphene nulloribbons via zero-mode superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design and fabrication of robust metallic states in graphene nulloribbons (GNRs) are challenging because lateral quantum confinement and many-electron interactions induce electronic band gaps when graphene is patterned at nullometer length scales. Recent developments in bottom-up synthesis have enabled the design and characterization of atomically precise GNRs, but strategies for realizing GNR metallicity have been elusive. Here we demonstrate a general technique for inducing metallicity in GNRs by inserting a symmetric superlattice of zero-energy modes into otherwise semiconducting GNRs. We verify the resulting metallicity using scanning tunneling spectroscopy as well as first-principles density-functional theory and tight-binding calculations. Our results reveal that the metallic bandwidth in GNRs can be tuned over a wide range by controlling the overlap of zero-mode wave functions through intentional sublattice symmetry breaking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2020, "Volume": 369, "Issue": 6511, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1597, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay3588", "DOI Link": "http://dx.doi.org/10.1126/science.aay3588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000574653300029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Watari, T; Cao, Z; Hata, S; nullsai, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Watari, Takuma; Cao, Zhi; Hata, Sho; nullsai, Keisuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient use of cement and concrete to reduce reliance on supply-side technologies for net-zero emissions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Decarbonization strategies for the cement and concrete sector have relied heavily on supply-side technologies, including carbon capture and storage (CCS), masking opportunities for demand-side intervention. Here we show that cross-cutting strategies involving both the supply and demand sides can achieve net-zero emissions by 2050 across the entire Japanese cement and concrete cycle without resorting to mass deployment of CCS. Our analysis shows that a series of mitigation efforts on the supply side can reduce 2050 CO2 emissions by up to 80% from baseline levels and that the remaining 20% mitigation gap can be fully bridged by the efficient use of cement and concrete in the built environment. However, this decarbonization pathway is dependent on how CO2 uptake by carbonation and carbon capture and utilization is accounted for in the inventory. Our analysis underscores the importance of including demand-side interventions at the heart of decarbonization strategies and highlights the urgent need to discuss how to account for CO2 uptake in national inventories under the Paris Agreement. A new study finds supply-side efforts alone are unlikely to lead to net-zero emissions across the cement and concrete cycle by 2050, advocating for more efficient use of cement and concrete in the built environment and more strategic options for decarbonization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4158, "DOI": "10.1038/s41467-022-31806-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31806-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827171100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Ashouri, A; Marcinskas, M; Kasparavicius, E; Malinauskas, T; Palmstrom, A; Getautis, V; Albrecht, S; McGehee, MD; Magomedov, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Ashouri, Amran; Marcinskas, Mantas; Kasparavicius, Ernestas; Malinauskas, Tadas; Palmstrom, Axel; Getautis, Vytautas; Albrecht, Steve; McGehee, Michael D.; Magomedov, Artiom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wettability Improvement of a Carbazole- Based Hole-Selective Monolayer for Reproducible Perovskite Solar Cells", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The wettability issue associated with the Me-4PACz hole-selective monolayer is solved by the introduction of the second component to the precursor solution. This results in a similar performance while simultaneously significantly improving the yield of the devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2023, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 898, "End Page": 900, "Article Number": null, "DOI": "10.1021/acsenergylett.2c02629", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.2c02629", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935438700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shu, JC; Cao, MS; Zhang, YL; Cao, WQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shu, Jin-Cheng; Cao, Mao-Sheng; Zhang, Yan-Lan; Cao, Wen-Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterodimensional Structure Switching Multispectral Stealth and Multimedia Interaction Devices", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lightweight and flexible electronic materials with high energy attenuation hold an unassailable position in electromagnetic stealth and intelligent devices. Among them, emerging heterodimensional structure draws intensive attention in the frontiers of materials, chemistry, and electronics, owing to the unique electronic, magnetic, thermal, and optical properties. Herein, an intrinsic heterodimensional structure consisting of alternating assembly of 0D magnetic clusters and 2D conductive layers is developed, and its macroscopic electromagnetic properties are flexibly designed by customizing the number of oxidative molecular layer deposition (oMLD) cycles. This unique heterodimensional structure features highly ordered spatial distribution, with an achievement of electron-dipole and magnetic-dielectric double synergies, which exhibits the high attenuation of electromagnetic energy (160) and substantial improvement of dielectric loss tangent (& AP;200%). It can respond to electromagnetic waves of different bands to achieve multispectral stealth, covering visible light, infrared radiation, and gigahertz wave. Importantly, two kinds of ingenious information interaction devices are constructed with heterodimensional structure. The hierarchical antennas allow precise targeting of operating bands (S- to Ku- bands) by oMLD cycles. The strain imaging device with high sensitivity opens a new horizon for visual interaction. This work provides a creative insight for developing advanced micro-nullo materials and intelligent devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 41, "Times Cited, All Databases": 41, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 10, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302361", "DOI Link": "http://dx.doi.org/10.1002/advs.202302361", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022724200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, MJ; Kim, Y; Cho, GY; Lee, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Moon Jip; Kim, Youngkuk; Cho, Gil Young; Lee, SungBin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-Order Topological Insulator in Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Higher-order topological insulators are newly proposed topological phases of matter, whose bulk topology manifests as localized modes at two- or higher-dimensional lower boundaries. In this Letter, we propose the twisted bilayer graphenes with large angles as higher-order topological insulators, hosting topological corner charges. At large commensurate angles, the intervalley scattering opens up the bulk gap and the corner states occur at half filling. Based on both first-principles calculations and analytic analysis, we show the striking results that the emergence of the corner states do not depend on the choice of the specific angles as long as the underlying symmetries are intact. Our results show that the twisted bilayer graphene can serve as a robust candidate material of a two-dimensional higher-order topological insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2019, "Volume": 123, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 216803, "DOI": "10.1103/PhysRevLett.123.216803", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.123.216803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498887900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hamad, HN; Idrus, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hamad, Hamad Noori; Idrus, Syazwani", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Developments in the Application of Bio-Waste-Derived Adsorbents for the Removal of Methylene Blue from Wastewater: A Review", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the last few years, various industries have released wastewater containing high concentrations of dyes straight into the ecological system, which has become a major environmental problem (i.e., soil, groundwater, surface water pollution, etc.). The rapid growth of textile industries has created an alarming situation in which further deterioration to the environment has been caused due to substances being left in treated wastewater, including dyes. The application of activated carbon has recently been demonstrated to be a highly efficient technology in terms of removing methylene blue (MB) from wastewater. Agricultural waste, as well as animal-based and wood products, are excellent sources of bio-waste for MB remediation since they are extremely efficient, have high sorption capacities, and are renewable sources. Despite the fact that commercial activated carbon is a favored adsorbent for dye elimination, its extensive application is restricted because of its comparatively high cost, which has prompted researchers to investigate alternative sources of adsorbents that are non-conventional and more economical. The goal of this review article was to critically evaluate the accessible information on the characteristics of bio-waste-derived adsorbents for MB's removal, as well as related parameters influencing the performance of this process. The review also highlighted the processing methods developed in previous studies. Regeneration processes, economic challenges, and the valorization of post-sorption materials were also discussed. This review is beneficial in terms of understanding recent advances in the status of biowaste-derived adsorbents, highlighting the accelerating need for the development of low-cost adsorbents and functioning as a precursor for large-scale system optimization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 783, "DOI": "10.3390/polym14040783", "DOI Link": "http://dx.doi.org/10.3390/polym14040783", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765174900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, J; Liu, YZ; Li, JH; Li, H; Luo, TC; Wu, Y; Xu, Y; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Jun; Liu, Yanzhao; Li, Jiaheng; Li, Hao; Luo, Tianchuang; Wu, Yang; Xu, Yong; Wang, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Chern-number and high-temperature quantum Hall effect without Landau levels", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantum Hall effect (QHE) with quantized Hall resistance of h/nu e(2) started the research on topological quantum states and laid the foundation of topology in physics. Since then, Haldane proposed the QHE without Landau levels, showing nonzero Chern number vertical bar C vertical bar = 1, which has been experimentally observed at relatively low temperatures. For emerging physics and low-power-consumption electronics, the key issues are how to increase the working temperature and realize high Chern numbers (C> 1). Here, we report the experimental discovery of high-Chern-number QHE (C = 2) without Landau levels and C = 1 Chern insulator state displaying a nearly quantized Hall resistance plateau above the Neel temperature in MnBi2Te4 devices. Our observations provide a new perspective on topological matter and open new avenues for exploration of exotic topological quantum states and topological phase transitions at higher temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1280, "End Page": 1287, "Article Number": null, "DOI": "10.1093/nsr/nwaa089", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa089", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572868500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kubota, Y; Tanaka, H; Ono, T; Narumi, Y; Kindo, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kubota, Yumi; Tanaka, Hidekazu; Ono, Toshio; Narumi, Yasuo; Kindo, Koichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Successive magnetic phase transitions in α-RuCl3: XY-like frustrated magnet on the honeycomb lattice", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The layered compound alpha-RuCl3 is composed of a honeycomb lattice of magnetic Ru3+ ions with the 4d(5) electronic state. We have investigated the magnetic properties of a-RuCl3 via magnetization and specific heat measurements using single crystals. It was observed that a-RuCl3 undergoes a structural phase transition at T-t similar or equal to 150 K accompanied by fairly large hysteresis. This structural phase transition is expected to be similar to that observed in closely related CrCl3. The magnetizations and magnetic susceptibilities are strongly anisotropic, which mainly arise from the anisotropic g factors, i.e., gab similar or equal to 2.5 and g(c) similar or equal to 0.4 for magnetic fields parallel and perpendicular to the ab plane, respectively. These g factors and the obtained entropy indicate that the effective spin of Ru3+ is one-half, which results from the low-spin state. Specific heat data show that magnetic ordering occurs in four steps at zero magnetic field. The successive magnetic phase transitions should be ascribed to the competition among exchange interactions. The magnetic phase diagram for H parallel to ab is obtained. We discuss the strongly anisotropic g factors in alpha-RuCl3 and deduce that the exchange interaction is strongly XY-like. alpha-RuCl3 is magnetically described as a three-dimensionally coupled XY-like frustrated magnet on a honeycomb lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2015, "Volume": 91, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 94422, "DOI": "10.1103/PhysRevB.91.094422", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.094422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351508400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, QX; Fan, RZ; Cheng, WH; Ji, PY; Sheng, J; Liao, QL; Lai, HR; Fu, XL; Zhang, CH; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qingxiao; Fan, Runze; Cheng, Weihua; Ji, Peiyi; Sheng, Jie; Liao, Qingliang; Lai, Huirong; Fu, Xueli; Zhang, Chenhao; Li, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Large-Area MXenes with High Yields through Power-Focused Delamination Utilizing Vortex Kinetic Energy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Evaluating the delamination process in the synthesis of MXenes (2D transition metal carbides and nitrides) is critical for their development and applications. However, the preparation of large defect-free MXene flakes with high yields is challenging. Here, a power-focused delamination (PFD) strategy is demonstrated that can enhance both the delamination efficiency and yield of large Ti3C2Tx MXene nullosheets through repetitive precipitation and vortex shaking processes. Following this protocol, a colloidal concentration of 20.4 mg mL(-1) of the Ti3C2Tx MXene can be achieved after five PFD cycles, and the yield of the basal-plane-defect-free Ti3C2Tx nullosheets reaches 61.2%, which is 6.4-fold higher than that obtained using the sonication-exfoliation method. Both nullometer-thin devices and self-supporting films exhibit excellent electrical conductivities (approximate to 25 000 and 8260 S cm(-1) for a 1.8 nm thick monolayer and 11 mu m thick film, respectively). Hydrodynamic simulations reveal that the PFD method can efficiently concentrate the shear stress on the surface of the unexfoliated material, leading to the exfoliation of the nullosheets. The PFD-synthesized large MXene nullosheets exhibit superior electrical conductivities and electromagnetic shielding (shielding effectiveness per unit volume: 35 419 dB cm(2) g(-1)). Therefore, the PFD strategy provides an efficient route for the preparation of high-performance single-layer MXene nullosheets with large areas and high yields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 9, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202748, "DOI": "10.1002/advs.202202748", "DOI Link": "http://dx.doi.org/10.1002/advs.202202748", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000841124600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Serafin, A; Culebras, M; Collins, MN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Serafin, Aleksandra; Culebras, Mario; Collins, Maurice N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and evaluation of alginate, gelatin, and hyaluronic acid hybrid hydrogels for tissue engineering applications", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tissue engineering (TE) has been proposed extensively as a potential solution to the worldwide shortages of donor organs needed for transplantation. Over the years, numerous hydrogel formulations have been studied for various TE endeavours, including bone, cardiac or neural TE treatment strategies. Amongst the materials used, organic and biocompatible materials which aim to mimic the natural extracellular matrix of the native tissue have been investigated to create biomimicry regenerative environments. As such, the comparison between studies using the same materials is often difficult to accomplish due to varying material concentrations, prep-aration strategies, and laboratory settings, and as such these variables have a huge impact on the physio-chemical properties of the hydrogel systems. The purpose of the current study is to investigate popular biomaterials such as alginate, hyaluronic acid and gelatin in a variety of concentrations and hydrogel formulations. This aims to provide a clear and comprehensive understanding of their behaviours and provide a rational approach as to the appropriate selection of natural polysaccharides in specific targeted TE strategies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2023, "Volume": 233, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123438, "DOI": "10.1016/j.ijbiomac.2023.123438", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2023.123438", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935200200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YH; Liu, KX; Hou, H; Chen, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yuhong; Liu, Kexin; Hou, Hua; Chen, Long-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of interfacial energy anisotropy in dendrite orientation in Al-Zn alloys: A phase field study", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The influence of interfacial energy anisotropy on dendrite morphology is still not well understood. We investigated the dendrite morphology and solute segregation in Al-Zn alloys using the phase-field method. We observed typical and atypical dendrite orientation transition and three types of dendrite morphology Christmas tree dendrite, seaweed dendrite and butterfly dendrite depending on the anisotropic interfacial energy. Two types of dendrite may undergo the so called-smooth dendrite orien-tation transition, which produces a large amount of solute segregation holes in (100) dendrites, and liq-uid grooves in (110) seaweed and butterfly patterns, thus may significantly impact the mechanical properties of castings. We identified a strong correlation between supersaturation and the formation of liquid holes and liquid grooves as well as the degree of solute segregation. We also proposed that the interfacial energy anisotropy can be related with Zn content by discussing the anisotropic Young's modulus and experimental pattern of Al-Zn alloys. The inducement of anisotropy and the quantitative relationship between interfacial energy anisotropy, Zn concentration, elastic anisotropy and dendrite orientation deserves attention. (c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 216, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110555, "DOI": "10.1016/j.matdes.2022.110555", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2022.110555", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000793271300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MZ; Li, CH; Zhang, YB; Yang, M; Gao, T; Cui, X; Wang, XM; Xu, WH; Zhou, ZM; Liu, B; Said, Z; Li, RZ; Sharma, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingzheng; LI, Changhe; Zhang, Yanbin; Yang, Min; Gao, Teng; Cui, Xin; Wang, Xiaoming; Xu, Wenhao; Zhou, Zongming; Liu, Bo; Said, Zafar; LI, Runze; Sharma, Shubham", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of grinding mechanics and improved grinding force model based on randomized grain geometric characteristics", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Too high grinding force will lead to a large increase in specific grinding energy, resulting in high temperature in grinding zone, especially for the aerospace difficult cutting metal materials, seriously affecting the surface quality and accuracy. At present, the theoretical models of grinding force are mostly based on the assumption of uniform or simplified morphological characteristics of grains, which is inconsistent with the actual grains. Especially for non-engineering grinding wheel, most geometric characteristics of grains are ignored, resulting in the calculation accuracy that cannot guide practical production. Based on this, an improved grinding force model based on random grain geometric characteristics is proposed in this paper. Firstly, the surface topography model of CBN grinding wheel is established, and the effective grain determination mechanism in grinding zone is revealed. Based on the known grinding force model and mechanical behavior of interaction between grains and workpiece in different stages, the concept of grain effective action area is proposed. The variation mechanism of effective action area under the influence of grain geometric and spatial characteristics is deeply analyzed, and the calculation method under random combination of five influencing parameters is obtained. The numerical simulation is carried out to reveal the dynamic variation process of grinding force in grinding zone. In order to verify the theoretical model, the experiments of dry grinding Ti-6Al-4 V are designed. The experimental results show that under different machining parameters, the results of numerical calculation and experimental measurement are in good agreement, and the minimum error value is only 2.1 %, which indicates that the calculation accuracy of grinding force model meets the requirements and is feasible. This study will provide a theoretical basis for optimizing the wheel structure, effectively controlling the grind -ing force range, adjusting the grinding zone temperature and improving the workpiece machining quality in the industrial grinding process.& COPY; 2022 Production and hosting by Elsevier Ltd. on behalf of Chinese Society of Aeronautics and Astronautics. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/ licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 36, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 160, "End Page": 193, "Article Number": null, "DOI": "10.1016/j.cja.2022.11.005", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2022.11.005", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001047338500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, X; Wang, L; Wu, YQ; Song, YZ; Chen, ZH; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Xiang; Wang, Li; Wu, Yingqiang; Song, Youzhi; Chen, Zonghai; He, Xiangming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cathode regeneration and upcycling of spent LIBs: toward sustainability", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "'Green ambition towards sustainability' is one of the hot research topics of the 21st century. With the sharp steering of the energy infrastructure toward fulfilling this radical expectation, the last decade has seen a global trend toward diversified sustainable renewable energy sources (such as solar, wind, and hydroelectric power) and electrification. Lithium-ion batteries (LIBs) are playing a significant role in this energy revolution. However, with the massive scale of the production of LIBs and their eventual retirement, attention has been turned to the erratic supply of raw materials used to manufacture these batteries and their disposal. Cathode regeneration technology is likely to be an optimal solution for the disposal of waste cathodes, aimed at non-destructively repairing and straightforwardly reusing degraded cathode materials for re-manufacturing LIBs with a shortened circular process, reasonable profits, and excellent efficiency. Cathode upcycling technology, aimed at upgrading the electrochemical performance of degraded materials, can be well adapted to the upgrading of battery chemistry and show excellent flexibility and potential for transforming the LIB industry from a resource-based to a circular economy. Thus, a holistic perspective based on the complete life cycle of LIBs is encouraged, and sustainability must be at the forefront regarding battery and pack design, raw material acquisition, materials synthesis, manufacturing, operating, retiring, and recycling processes of LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2023, "Volume": 16, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2856, "End Page": 2868, "Article Number": null, "DOI": "10.1039/d3ee00746d", "DOI Link": "http://dx.doi.org/10.1039/d3ee00746d", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001014280300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, JX; Feng, YH; Li, WM; Cheng, ZR; Rosenholm, JM; Yang, HL; Pan, GQ; Zhang, HB; Geng, DC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Jiaxiang; Feng, Yonghai; Li, Wenming; Cheng, Zerui; Rosenholm, Jessica M.; Yang, Huilin; Pan, Guoqing; Zhang, Hongbo; Geng, Dechun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alternative Copper-Based Single-Atom nullozyme with Superior Multienzyme Activities and NIR-II Responsiveness to Fight against Deep Tissue Infections", "Source Title": "RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullozymes are considered to represent a new era of antibacterial agents, while their antibacterial efficiency is limited by the increasing tissue depth of infection. To address this issue, here, we report a copper and silk fibroin (Cu-SF) complex strategy to synthesize alternative copper single-atom nullozymes (SAzymes) with atomically dispersed copper sites anchored on ultrathin 2D porous N-doped carbon nullosheets (CuNx-CNS) and tunable N coordination numbers in the CuNxsites (x = 2 or 4). The CuNx-CNS SAzymes inherently possess triple peroxidase (POD)-, catalase (CAT)-, and oxidase (OXD)-like activities, facilitating the conversion of H2O2 and O2 into reactive oxygen species (ROS) through parallel POD-and OXD-like or cascaded CAT-and OXD-like reactions. Compared to CuN2-CNS, tailoring the N coordination number from 2 to 4 endows the SAzyme (CuN4-CNS) with higher multienzyme activities due to its superior electron structure and lower energy barrier. Meanwhile, CuNx-CNS display strong absorption in the second near-infrared (NIR-II) biowindow with deeper tissue penetration, offering NIR-II-responsive enhanced ROS generation and photothermal treatment in deep tissues. The in vitro and in vivo results demonstrate that the optimal CuN4-CNS can effectively inhibit multidrug-resistant bacteria and eliminate stubborn biofilms, thus exhibiting high therapeutic efficacy in both superficial skin wound and deep implant-related biofilm infections.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2023, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.34133/research.0031", "DOI Link": "http://dx.doi.org/10.34133/research.0031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001030362600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Firdaus, Y; Le Corre, VM; Karuthedath, S; Liu, WL; Markina, A; Huang, WT; Chattopadhyay, S; Nahid, MM; Nugraha, MI; Lin, YB; Seitkhan, A; Basu, A; Zhang, WM; McCulloch, I; Ade, H; Labram, J; Laquai, F; Andrienko, D; Koster, LJA; Anthopoulos, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Firdaus, Yuliar; Le Corre, Vincent M.; Karuthedath, Safakath; Liu, Wenlan; Markina, Anastasia; Huang, Wentao; Chattopadhyay, Shirsopratim; Nahid, Masrur Morshed; Nugraha, Mohamad I.; Lin, Yuanbao; Seitkhan, Akmaral; Basu, Aniruddha; Zhang, Weimin; McCulloch, Iain; Ade, Harald; Labram, John; Laquai, Frederic; Andrienko, Denis; Koster, L. Jan Anton; Anthopoulos, Thomas D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-range exciton diffusion in molecular non-fullerene acceptors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The short exciton diffusion length associated with most classical organic semiconductors used in organic photovoltaics (5-20nm) imposes severe limits on the maximum size of the donor and acceptor domains within the photoactive layer of the cell. Identifying materials that are able to transport excitons over longer distances can help advancing our understanding and lead to solar cells with higher efficiency. Here, we measure the exciton diffusion length in a wide range of nonfullerene acceptor molecules using two different experimental techniques based on photocurrent and ultrafast spectroscopy measurements. The acceptors exhibit balanced ambipolar charge transport and surprisingly long exciton diffusion lengths in the range of 20 to 47nm. With the aid of quantum-chemical calculations, we are able to rationalize the exciton dynamics and draw basic chemical design rules, particularly on the importance of the end-group substituent on the crystal packing of nonfullerene acceptors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5220, "DOI": "10.1038/s41467-020-19029-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19029-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582681400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krieger, KJ; Bertollo, N; Dangol, M; Sheridan, JT; Lowery, MM; O'Cearbhaill, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krieger, Kevin J.; Bertollo, Nicky; Dangol, Manita; Sheridan, John T.; Lowery, Madeleine M.; O'Cearbhaill, Eoin D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simple and customizable method for fabrication of high-aspect ratio microneedle molds using low-cost 3D printing", "Source Title": "MICROSYSTEMS & nullOENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a simple and customizable microneedle mold fabrication technique using a low-cost desktop SLA 3D printer. As opposed to conventional microneedle fabrication methods, this technique neither requires complex and expensive manufacturing facilities nor expertise in microfabrication. While most low-cost 3D-printed microneedles to date display low aspect ratios and poor tip sharpness, we show that by introducing a two-step Print & Fill mold fabrication method, it is possible to obtain high-aspect ratio sharp needles that are capable of penetrating tissue. Studying first the effect of varying design input parameters and print settings, it is shown that printed needles are always shorter than specified. With decreasing input height, needles also begin displaying an increasingly greater than specified needle base diameter. Both factors contribute to low aspect ratio needles when attempting to print submillimeter height needles. By setting input height tall enough, it is possible to print needles with high-aspect ratios and tip radii of 20-40 mu m. This tip sharpness is smaller than the specified printer resolution. Consequently, high-aspect ratio sharp needle arrays are printed in basins which are backfilled and cured in a second step, leaving sub-millimeter microneedles exposed resulting microneedle arrays which can be used as male masters. Silicone female master molds are then formed from the fabricated microneedle arrays. Using the molds, both carboxymethyl cellulose loaded with rhodamine B as well as polylactic acid microneedle arrays are produced and their quality examined. A skin insertion study is performed to demonstrate the functional capabilities of arrays made from the fabricated molds. This method can be easily adopted by the microneedle research community for in-house master mold fabrication and parametric optimization of microneedle arrays.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 9", "Publication Year": 2019, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42, "DOI": "10.1038/s41378-019-0088-8", "DOI Link": "http://dx.doi.org/10.1038/s41378-019-0088-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485877300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bannigan, P; Bao, ZQ; Hickman, RJ; Aldeghi, M; Häse, F; Aspuru-Guzik, A; Allen, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bannigan, Pauric; Bao, Zeqing; Hickman, Riley J.; Aldeghi, Matteo; Hase, Florian; Aspuru-Guzik, Alan; Allen, Christine", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning models to accelerate the design of polymeric long-acting injectables", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-acting injectables are considered one of the most promising therapeutic strategies for the treatment of chronic diseases as they can afford improved therapeutic efficacy, safety, and patient compliance. The use of polymer materials in such a drug formulation strategy can offer unparalleled diversity owing to the ability to synthesize materials with a wide range of properties. However, the interplay between multiple parameters, including the physicochemical properties of the drug and polymer, make it very difficult to intuitively predict the performance of these systems. This necessitates the development and characterization of a wide array of formulation candidates through extensive and time-consuming in vitro experimentation. Machine learning is enabling leap-step advances in a number of fields including drug discovery and materials science. The current study takes a critical step towards data-driven drug formulation development with an emphasis on long-acting injectables. Here we show that machine learning algorithms can be used to predict experimental drug release from these advanced drug delivery systems. We also demonstrate that these trained models can be used to guide the design of new long acting injectables. The implementation of the described data-driven approach has the potential to reduce the time and cost associated with drug formulation development. Polymer-based long-acting injectable drugs are a promising therapeutic strategy for chronic diseases. Here the authors use machine learning to inform the data-driven development of advanced drug formulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35, "DOI": "10.1038/s41467-022-35343-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35343-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928461700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bokdam, M; Sander, T; Stroppa, A; Picozzi, S; Sarma, DD; Franchini, C; Kresse, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bokdam, Menno; Sander, Tobias; Stroppa, Alessandro; Picozzi, Silvia; Sarma, D. D.; Franchini, Cesare; Kresse, Georg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of Polar Phonons in the Photo Excited State of Metal Halide Perovskites", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of high efficiency perovskite solar cells has sparked a multitude of measurements on the optical properties of these materials. For the most studied methylammonium(MA) PbI3 perovskite, a large range (6-55 meV) of exciton binding energies has been reported by various experiments. The existence of excitons at room temperature is unclear. For the MAPbX(3) perovskites we report on relativistic Bethe-Salpeter Equation calculations (GW-BSE). This method is capable to directly calculate excitonic properties from first-principles. At low temperatures it predicts exciton binding energies in agreement with the reported 'large' values. For MAPbI(3), phonon modes present in this frequency range have a negligible contribution to the ionic screening. By calculating the polarization in time from finite temperature molecular dynamics, we show that at room temperature this does not change. We therefore exclude ionic screening as an explanation for the experimentally observed reduction of the exciton binding energy at room temperature and argue in favor of the formation of polarons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28618, "DOI": "10.1038/srep28618", "DOI Link": "http://dx.doi.org/10.1038/srep28618", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378789500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Becerril, R; Nerín, C; Silva, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Becerril, Raquel; Nerin, Cristina; Silva, Filomena", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bring some colour to your package: Freshness indicators based on anthocyanin extracts", "Source Title": "TRENDS IN FOOD SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Nowadays, consumers are more aware about what they eat and how it is packaged. Food quality is of paramount importance and consumers are eager to be constantly updated about the perishability and shelf-life of the food products they buy. This gave rise to intelligent packaging (IP) materials and devices that can communicate with all people throughout the entire food route. One of the main colour-based IP systems is based on the use of anthocyanin (ATH)-based natural dyes by exploiting their pH-dependent colour changes that can be easily readable by the naked eye. Scope and approach: This review focuses on recent studies regarding ATH-based sensor packaging materials development for IP applications, offering valuable insights regarding the main factors that affect the efficacy of the developed IP, such as the material where the ATH is anchored, ATH type and concentration, the ingredients used in the formulation of the sensor and the storage conditions of the food product. Additionally, the last ATHbased IP developed are also summed and discussed in detail to identify the major bottlenecks that need to be overcome for accelerating the commercial application of ATH-based sensors in IP. Key findings and conclusions: Although ATH-based indicators are able to correctly indicate food shelf-life in several products at a laboratory scale, their industrial production is still impaired by the production methods used for this type of sensors. Furthermore, ATHs are labile compounds that require stabilization in the packaging material to yield stable, standardized and durable IP materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 111, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 495, "End Page": 505, "Article Number": null, "DOI": "10.1016/j.tifs.2021.02.042", "DOI Link": "http://dx.doi.org/10.1016/j.tifs.2021.02.042", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640705100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duval, A; Vilaplana, F; Crestini, C; Lawoko, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duval, Antoine; Vilaplana, Francisco; Crestini, Claudia; Lawoko, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent screening for the fractionation of industrial kraft lignin", "Source Title": "HOLZFORSCHUNG", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The polydispersity of commercially available kraft lignins (KLs) is one of the factors limiting their applications in polymer-based materials. A prerequisite is thus to develop lignin fractionation strategies compatible with industrial requirements and restrictions. For this purpose, a solvent-based lignin fractionation technique has been addressed. The partial solubility of KL in common industrial solvents compliant with the requirements of sustainable chemistry was studied, and the results were discussed in relation to Hansen solubility parameters. Based on this screening, a solvent sequence is proposed, which is able to separate well-defined KL fractions with low polydispersity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 70, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11, "End Page": 20, "Article Number": null, "DOI": "10.1515/hf-2014-0346", "DOI Link": "http://dx.doi.org/10.1515/hf-2014-0346", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Forestry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367822500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, WJ; Smeaton, MA; Jia, CJ; Goodge, BH; Cho, BG; Lee, K; Osada, M; Jost, D; Ievlev, AV; Moritz, B; Kourkoutis, LF; Devereaux, TP; Hwang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Woo Jin; Smeaton, Michelle A.; Jia, Chunjing; Goodge, Berit H.; Cho, Byeong-Gwan; Lee, Kyuho; Osada, Motoki; Jost, Daniel; Ievlev, Anton V.; Moritz, Brian; Kourkoutis, Lena F.; Devereaux, Thomas P.; Hwang, Harold Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Geometric frustration of Jahn-Teller order in the infinite-layer lattice", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Jahn-Teller effect, in which electronic configurations with energetically degenerate orbitals induce lattice distortions to lift this degeneracy, has a key role in many symmetry-lowering crystal deformations(1). Lattices of Jahn-Teller ions can induce a cooperative distortion, as exemplified by LaMnO3 (refs. (2,3)). Although many examples occur in octahedrally(4) or tetrahedrally(5) coordinated transition metal oxides due to their high orbital degeneracy, this effect has yet to be manifested for square-planar anion coordination, as found in infinite-layer copper(6,7), nickel(8,9), iron(10,11) and manganese oxides12. Here we synthesize single-crystal CaCoO2 thin films by topotactic reduction of the brownmillerite CaCoO2.5 phase. We observe a markedly distorted infinite-layer structure, with angstrom-scale displacements of the cations from their high-symmetry positions. This can be understood to originate from the Jahn-Teller degeneracy of the d(xz) and d(yz) orbitals in the d(7) electronic configuration along with substantial ligand-transition metal mixing. A complex pattern of distortions arises in a 2 root 2 x 2 root 2 x 1 tetragonal supercell, reflecting the competition between an ordered Jahn-Teller effect on the CoO2 sublattice and the geometric frustration of the associated displacements of the Ca sublattice, which are strongly coupled in the absence of apical oxygen. As a result of this competition, the CaCoO2 structure forms an extended two-in-two-out type of Co distortion following ice rules'(13).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2023, "Volume": 615, "Issue": 7951, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 237, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05681-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05681-2", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937133200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, YG; Liu, JJ; Wu, XX; Guguchia, Z; Yin, JX; Mine, A; Li, YK; Najafzadeh, S; Das, D; Mielke, C; Khasanov, R; Luetkens, H; Suzuki, T; Liu, KC; Han, XL; Kondo, T; Hu, JP; Shin, S; Wang, ZW; Shi, X; Yao, YG; Okazaki, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Yigui; Liu, Jinjin; Wu, Xianxin; Guguchia, Zurab; Yin, J. -x.; Mine, Akifumi; Li, Yongkai; Najafzadeh, Sahand; Das, Debarchan; Mielke, Charles; Khasanov, Rustem; Luetkens, Hubertus; Suzuki, Takeshi; Liu, Kecheng; Han, Xinloong; Kondo, Takeshi; Hu, Jiangping; Shin, Shik; Wang, Zhiwei; Shi, Xun; Yao, Yugui; Okazaki, Kozo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nodeless electron pairing in CsV3Sb5-derived kagome superconductors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The newly discovered kagome superconductors represent a promising platform for investigating the interplay between band topology, electronic order and lattice geometry(1-9). Despite extensive research efforts on this system, the nature of the superconducting ground state remains elusive(10-17). In particular, consensus on the electron pairing symmetry has not been achieved so far(18-20), in part owing to the lack of a momentum-resolved measurement of the superconducting gap structure. Here we report the direct observation of a nodeless, nearly isotropic and orbital-independent superconducting gap in the momentum space of two exemplary CsV3Sb5-derived kagome superconductors-Cs(V0.93Nb0.07)(3)Sb-5 and Cs(V0.86Ta0.14)(3)Sb-5-using ultrahigh-resolution and low-temperature angle-resolved photoemission spectroscopy. Remarkably, such a gap structure is robust to the appearance or absence of charge order in the normal state, tuned by isovalent Nb/Ta substitutions of V. Our comprehensive characterizations of the superconducting gap provide indispensable information on the electron pairing symmetry of kagome superconductors, and advance our understanding of the superconductivity and intertwined electronic orders in quantum materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2023, "Volume": 617, "Issue": 7961, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 488, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05907-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05907-x", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002447800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, P; Jiao, YZ; Ruan, YE; Fei, HG; Men, Y; Guo, CL; Wu, Y; Chen, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Peng; Jiao, Yuzhou; Ruan, Yaner; Fei, Houguo; Men, Yana; Guo, Cunlan; Wu, Yuen; Chen, Shengli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the role of double-layer microenvironments in pH-dependent oxygen reduction activity over metal-nitrogen-carbon catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A standing puzzle in electrochemistry is that why the metal-nitrogen-carbon catalysts generally exhibit dramatic activity drop for oxygen reduction when traversing from alkaline to acid. Here, taking FeCo-N6-C double-atom catalyst as a model system and combining the ab initio molecular dynamics simulation and in situ surface-enhanced infrared absorption spectroscopy, we show that it is the significantly distinct interfacial double-layer structures, rather than the energetics of multiple reaction steps, that cause the pH-dependent oxygen reduction activity on metal-nitrogen-carbon catalysts. Specifically, the greatly disparate charge densities on electrode surfaces render different orientations of interfacial water under alkaline and acid oxygen reduction conditions, thereby affecting the formation of hydrogen bonds between the surface oxygenated intermediates and the interfacial water molecules, eventually controlling the kinetics of the proton-coupled electron transfer steps. The present findings may open new and feasible avenues for the design of advanced metal-nitrogen-carbon catalysts for proton exchange membrane fuel cells. By combining theoretical simulations and spectroscopic measurements, Peng Li et al. demonstrated that distinct interfacial double-layer structures play a key role in the pH-dependent oxygen reduction kinetics over metal-nitrogen-carbon catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6936, "DOI": "10.1038/s41467-023-42749-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42749-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001094448600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benalcazar, WA; Bernevig, BA; Hughes, TL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benalcazar, Wladimir A.; Bernevig, B. Andrei; Hughes, Taylor L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric multipole moments, topological multipole moment pumping, and chiral hinge states in crystalline insulators", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We extend the theory of dipole moments in crystalline insulators to higher multipole moments. As first formulated in Benalcazar et al. [Science 357, 61 (2017)], we show that bulk quadrupole and octupole moments can be realized in crystalline insulators. In this paper, we expand in great detail the theory presented previously [Benalcazar et al., Science 357, 61 (2017)] and extend it to cover associated topological pumping phenomena, and a class of three-dimensional (3D) insulator with chiral hinge states. We start by deriving the boundary properties of continuous classical dielectrics hosting only bulk dipole, quadrupole, or octupole moments. In quantum mechanical crystalline insulators, these higher multipole bulk moments manifest themselves by the presence of boundary-localized moments of lower dimension, in exact correspondence with the electromagnetic theory of classical continuous dielectrics. In the presence of certain symmetries, these moments are quantized, and their boundary signatures are fractionalized. These multipole moments then correspond to new symmetry-protected topological phases. The topological structure of these phases is described by nested Wilson loops, which we define. These Wilson loops reflect the bulk-boundary correspondence in a way that makes evident a hierarchical classification of the multipole moments. Just as a varying dipole generates charge pumping, a varying quadrupole generates dipole pumping, and a varying octupole generates quadrupole pumping. For nontrivial adiabatic cycles, the transport of these moments is quantized. An analysis of these interconnected phenomena leads to the conclusion that a new kind of Chern-type insulator exists, which has chiral, hinge-localized modes in 3D. We provide the minimal models for the quantized multipole moments, the nontrivial pumping processes, and the hinge Chern insulator, and describe the topological invariants that protect them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1068, "Times Cited, All Databases": 1124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2017, "Volume": 96, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 245115, "DOI": "10.1103/PhysRevB.96.245115", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.245115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417639900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Musaelian, A; Batzner, S; Johansson, A; Sun, LX; Owen, CJ; Kornbluth, M; Kozinsky, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Musaelian, Albert; Batzner, Simon; Johansson, Anders; Sun, Lixin; Owen, Cameron J.; Kornbluth, Mordechai; Kozinsky, Boris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Learning local equivariant representations for large-scale atomistic dynamics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A simultaneously accurate and computationally efficient parametrization of the potential energy surface of molecules and materials is a long-standing goal in the natural sciences. While atom-centered message passing neural networks (MPNNs) have shown remarkable accuracy, their information propagation has limited the accessible length-scales. Local methods, conversely, scale to large simulations but have suffered from inferior accuracy. This work introduces Allegro, a strictly local equivariant deep neural network interatomic potential architecture that simultaneously exhibits excellent accuracy and scalability. Allegro represents a many-body potential using iterated tensor products of learned equivariant representations without atom-centered message passing. Allegro obtains improvements over state-of-the-art methods on QM9 and revMD17. A single tensor product layer outperforms existing deep MPNNs and transformers on QM9. Furthermore, Allegro displays remarkable generalization to out-of-distribution data. Molecular simulations using Allegro recover structural and kinetic properties of an amorphous electrolyte in excellent agreement with ab-initio simulations. Finally, we demonstrate parallelization with a simulation of 100 million atoms. The paper presents a method that allows scaling machine learning interatomic potentials to extremely large systems, while at the same time retaining the remarkable accuracy and learning efficiency of deep equivariant models. This is obtained with an E(3)- equivariant neural network architecture that combines the high accuracy of equivariant neural networks with the scalability of local methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 579, "DOI": "10.1038/s41467-023-36329-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36329-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bafekry, A; Faraji, M; Fadlallah, MM; Jappor, HR; Karbasizadeh, S; Ghergherehchi, M; Gogova, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bafekry, A.; Faraji, M.; Fadlallah, M. M.; Jappor, H. R.; Karbasizadeh, S.; Ghergherehchi, M.; Gogova, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biphenylene monolayer as a two-dimensional nonbenzenoid carbon allotrope: a first-principles study", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In a very recent accomplishment, the two-dimensional form of biphenylene network (BPN) has been fabricated. Motivated by this exciting experimental result on 2D layered BPN structure, herein we perform detailed density-functional theory-based first-principles calculations, in order to gain insight into the structural, mechanical, electronic and optical properties of this promising nullomaterial. Our theoretical results reveal the BPN structure is constructed from three rings of tetragon, hexagon and octagon, meanwhile the electron localization function shows very strong bonds between the C atoms in the structure. The dynamical stability of BPN is verified via the phonon band dispersion calculations. The mechanical properties reveal the brittle behavior of BPN monolayer. The Young's modulus has been computed as 0.1 TPa, which is smaller than the corresponding value of graphene, while the Poisson's ratio determined to be 0.26 is larger than that of graphene. The band structure is evaluated to show the electronic features of the material; determining the BPN monolayer as metallic with a band gap of zero. The optical properties (real and imaginary parts of the dielectric function, and the absorption spectrum) uncover BPN as an insulator along the zz direction, while owning metallic properties in xx and yy directions. We anticipate that our discoveries will pave the way to the successful implementation of this 2D allotrope of carbon in advanced nulloelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2022, "Volume": 34, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15001, "DOI": "10.1088/1361-648X/ac2a7b", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ac2a7b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000711172400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elmobarak, WF; Almomani, F; Tawalbeh, M; Al-Othman, A; Martis, R; Rasool, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elmobarak, Wamda Faisal; Almomani, Fares; Tawalbeh, Muhammad; Al-Othman, Amani; Martis, Remston; Rasool, Kashif", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current status of CO2 capture with ionic liquids: Development and progress", "Source Title": "FUEL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Global warming triggered by greenhouse gas (GHG) emissions, particularly carbon dioxide (CO2), significantly influences climate change and has become a common environmental issue recently. The current amine-based technologies (ABTs) for CO2 capture (CAPCO2) have high energy demand, low absorption, and desorption rates, and are less environmentally sustainable due to high emissions of volatile solvents. Therefore, the development of environmentally friendly CAPCO2 materials and/or processes is a growing area of research. The utilization of ionic liquids (ILs) for CAPCO2 has recently attracted attention. The unique characteristics of ILs, such as their low vapor pressure and high affinity for CAPCO2 as well as their low volatility make them a viable substitute for the existing processes. This work provides a comprehensive overview of the accomplishments and challenges during the use of ILs for CAPCO2. The Review also outlines the mechanisms of the CAPCO2 with ILs at the molecular level, the properties of ILs, characterization of the CO2/IL systems, and the effect of operating conditions on CO2 uptake (UPCO2) capacity by ILs. It also emphasizes the impact of cations, anions, and func-tional groups on the solubility of CO2 ((SCO2)) in ILs as well as the biodegradability and toxicity of ILs. Addi-tionally, recent advances in IL membrane technology for the CAPCO2 processes are considered. Lastly, the contribution of molecular simulations to create and assess ILs was reviewed. Protic and aprotic ILs properties have shown outstanding efficiency of UPCO2. The interactions between the anionic part of IL and CO2 enhance the UPCO2 and outperform the efficiency of traditional organic solvents. Functionalized ionic liquids (FUNILs) with tuned functional groups, supported ionic liquids membranes (SILMs) as well as reversible ionic liquids (RILs) have improved the efficiency of ILs as a promising CO2 capturing process from industrial streams even under low CO2 partial pressure. The relative importance of the chemical breakdown of the IL constituents (cation-anion interfacial structuring) during the CAPCO2 process at different operating temperatures is unclear, and more research in this area is required to better inform the design of new ILs. This review provides a proper/systematic guideline to help ILs manufacturers and engineers design high-capacity ILs for appropriate CAPCO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2023, "Volume": 344, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 128102, "DOI": "10.1016/j.fuel.2023.128102", "DOI Link": "http://dx.doi.org/10.1016/j.fuel.2023.128102", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000958949900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YJ; Ma, JH; Xu, L; Liu, T; Xiao, TZ; Chen, DM; Song, ZG; Qiu, JB; Zhang, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yongjin; Ma, Junhao; Xu, Liang; Liu, Tong; Xiao, Taizhong; Chen, Daomei; Song, Zhiguo; Qiu, Jianbei; Zhang, Yueli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of Charge Separation and NIR Light Harvesting through Construction of 2D-2D Bi4O5I2/BiOBr:Yb3+, Er3+ Z-Scheme Heterojunctions for Improved Full-Spectrum Photocatalytic Performance", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing full-spectrum photocatalysts with simultaneous broadband light absorption, excellent charge separation, and high redox capabilities is becoming increasingly significant. Herein, inspired by the similarities in crystalline structures and compositions, a unique 2D-2D Bi4O5I2/BiOBr:Yb3+,Er3+ (BI-BYE) Z-scheme heterojunction with upconversion (UC) functionality is successfully designed and fabricated. The co-doped Yb3+ and Er3+ harvest near-infrared (NIR) light and then convert it into visible light via the UC function, expanding the optical response range of the photocatalytic system. The intimate 2D-2D interface contact provides more charge migration channels and enhances the Forster resonullt energy transfer of BI-BYE, leading to significantly improved NIR light utilization efficiency. Density functional theory (DFT) calculations and experimental results confirm that the Z-scheme heterojunction is formed and that this heterojunction endows the BI-BYE heterostructure with high charge separation and strong redox capability. Benefit from these synergies, the optimized 75BI-25BYE heterostructure exhibits the highest photocatalytic performance for Bisphenol A (BPA) degradation under full-spectrum and NIR light irradiation, outperforming BYE by 6.0 and 5.3 times, respectively. This work paves an effective approach for designing highly efficient full-spectrum responsive Z-scheme heterojunction photocatalysts with UC function.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207514", "DOI Link": "http://dx.doi.org/10.1002/advs.202207514", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936862000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hourahine, B; Aradi, B; Blum, V; Bonafé, F; Buccheri, A; Camacho, C; Cevallos, C; Deshaye, MY; Dumitrica, T; Dominguez, A; Ehlert, S; Elstner, M; van der Heide, T; Hermann, J; Irle, S; Kranz, JJ; Köhler, C; Kowalczyk, T; Kubar, T; Lee, IS; Lutsker, V; Maurer, RJ; Min, SK; Mitchell, I; Negre, C; Niehaus, TA; Niklasson, AMN; Page, AJ; Pecchia, A; Penazzi, G; Persson, MP; Rezác, J; Sánchez, CG; Sternberg, M; Stöhr, M; Stuckenberg, F; Tkatchenko, A; Yu, VWZ; Frauenheim, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hourahine, B.; Aradi, B.; Blum, V.; Bonafe, F.; Buccheri, A.; Camacho, C.; Cevallos, C.; Deshaye, M. Y.; Dumitrica, T.; Dominguez, A.; Ehlert, S.; Elstner, M.; van der Heide, T.; Hermann, J.; Irle, S.; Kranz, J. J.; Koehler, C.; Kowalczyk, T.; Kubar, T.; Lee, I. S.; Lutsker, V.; Maurer, R. J.; Min, S. K.; Mitchell, I.; Negre, C.; Niehaus, T. A.; Niklasson, A. M. N.; Page, A. J.; Pecchia, A.; Penazzi, G.; Persson, M. P.; Rezac, J.; Sanchez, C. G.; Sternberg, M.; Stoehr, M.; Stuckenberg, F.; Tkatchenko, A.; Yu, V. W. -z.; Frauenheim, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DFTB plus , a software package for efficient approximate density functional theory based atomistic simulations", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "DFTB+ is a versatile community developed open source software package offering fast and efficient methods for carrying out atomistic quantum mechanical simulations. By implementing various methods approximating density functional theory (DFT), such as the density functional based tight binding (DFTB) and the extended tight binding method, it enables simulations of large systems and long timescales with reasonable accuracy while being considerably faster for typical simulations than the respective ab initio methods. Based on the DFTB framework, it additionally offers approximated versions of various DFT extensions including hybrid functionals, time dependent formalism for treating excited systems, electron transport using non-equilibrium Green's functions, and many more. DFTB+ can be used as a user-friendly standalone application in addition to being embedded into other software packages as a library or acting as a calculation-server accessed by socket communication. We give an overview of the recently developed capabilities of the DFTB+ code, demonstrating with a few use case examples, discuss the strengths and weaknesses of the various features, and also discuss on-going developments and possible future perspectives. (C) 2020 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 780, "Times Cited, All Databases": 806, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2020, "Volume": 152, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124101, "DOI": "10.1063/1.5143190", "DOI Link": "http://dx.doi.org/10.1063/1.5143190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521986100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "You, YS; Reis, DA; Ghimire, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "You, Yong Sing; Reis, David A.; Ghimire, Shambhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anisotropic high-harmonic generation in bulk crystals", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The microscopic valence electron density determines the optical, electronic, structural and thermal properties of materials. However, current techniques for measuring this electron charge density are limited: for example, scanning tunnelling microscopy is confined to investigations at the surface, and electrondi diffraction requires very thin samples toavoid multiple scattering(1). Therefore, an optical method is desirable for measuring the valence charge density of bulk materials. Since the discovery of high-harmonic generation (HHG) in solids2, there has been growing interest in using HHG to probe the electronic structure of solids(3-11). Here, using single-crystal MgO, we demonstrate that high-harmonic generation in solids is sensitive to interatomic bonding. We find that harmonic eifficiency is enhanced (diminished) for semi-classical electron trajectories that connect (avoid) neighbouring atomic sites in the crystal. These results indicate the possibility of using materials' own electrons for retrieving the interatomic potential and thus the valence electron density, and perhaps even wavefunctions, in an all-optical setting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 13, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 349, "Article Number": null, "DOI": "10.1038/NPHYS3955", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3955", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398262900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Botu, V; Batra, R; Chapman, J; Ramprasad, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Botu, V.; Batra, R.; Chapman, J.; Ramprasad, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine Learning Force Fields: Construction, Validation, and Outlook", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Force fields developed with machine learning methods in tandem with quantum mechanics are beginning to find merit, given their (1) low cost, (ii) accuracy, and (iii) versatility. Recently, we proposed one such approach, wherein, the vectorial force on an atom is computed directly from its environment. Here, we discuss the multistep workflow required for their construction, which begins with generating diverse reference atomic environments and force data, choosing a numerical representation for the atomic environments, down selecting a representative training set, and lastly the learning method itself,,for the case of Al. The constructed force field is then validated by simulating complex materials phenomena such as surface melting and stress strain behavior,. that truly go beyond the realm of ab initio methods, both in length and time scales. To make such force fields truly versatile an attempt to estimate the uncertainty in force predictions is put forth, allowing one to identify areas of poor performance and,paving the way for their continual improvement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 426, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2017, "Volume": 121, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": 522, "Article Number": null, "DOI": "10.1021/acs.jpcc.6b10908", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.6b10908", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392035500054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YZ; Liang, J; Huang, ZH; Wang, Q; Zhu, GY; Dong, SY; Liang, HF; Dong, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yi-Zhou; Liang, Jin; Huang, Zihao; Wang, Qian; Zhu, Guoyin; Dong, Shengyang; Liang, Hanfeng; Dong, Xiaochen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ionically Conductive Tunnels in h-WO3 Enable High-Rate NH4+ Storage", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compared to the commonly applied metallic ion charge carriers (e.g., Li+ and Na+), batteries using nonmetallic charge carriers (e.g., H+ and NH4+) generally have much faster kinetics and high-rate capability thanks to the small hydrated ionic sizes and nondiffusion control topochemistry. However, the hosts for nonmetallic charge carriers are still limited. In this work, it is suggested that mixed ionic-electronic conductors can serve as a promising host for NH4+ storage. Using hexagonal tungsten oxide (h-WO3) as an example, it is shown that the existence of ionic conductive tunnels greatly promotes the high-rate NH4+ storage. Specifically, a much higher capacity of 82 mAh g(-1) at 1 A g(-1) is achieved on h-WO3, in sharp contrast to 14 mAh g(-1) of monoclinic tungsten oxide (m-WO3). In addition, unlike layered materials, the insertion and desertion of NH4+ ions are confined within the tunnels of the h-WO3, which minimizes the damage to the crystal structure. This leads to outstanding stability of up to 200 000 cycles with 68% capacity retention at a high current of 20 A g(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105158, "DOI": "10.1002/advs.202105158", "DOI Link": "http://dx.doi.org/10.1002/advs.202105158", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749574000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, L; Li, N; Childs, PRN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, L.; Li, N.; Childs, P. R. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-weighting in aerospace component and system design", "Source Title": "PROPULSION AND POWER RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-weighting involves the use of advanced materials and engineering methods to enable structural elements to deliver the same, or enhanced, technical performance while using less material. The concept has been extensively explored and utilised in many industries from automotive applications to fashion and packaging and offers significant potential in the aviation sector. Typical implementations of light-weighting have involved use of high performance materials such as composites and optimisation of structures using computational aided engineering approaches with production enabled by advanced manufacturing methods such as additive manufacture, foam metals and hot forming. This paper reviews the principal approaches used in light-weighting, along with the scope for application of light-weighting in aviation applications from power-plants to airframe components. A particular area identified as warranting attention and amenable to the use of light weighting approaches is the design of solar powered aircraft wings. The high aspect ratio typically used for these can be associated with insufficient stiffness, giving rise to non-linear deformation, aileron reversal, flutter and rigid-elastic coupling. Additional applications considered include ultralight aviation components and sub-systems, UAVs, and rockets. Advanced optimisation approaches can be applied to optimise the layout of structural elements, as well as geometrical parameters in order to maximise structural stiffness, minimise mass and enable incorporation of energy storage features. The use of additive manufacturing technologies, some capable of producing composite or multi-material components is an enabler for light-weighting, as features formally associated with one principal function can be designed to fulfil multiple functionalities. (C) 2018 National Laboratory for Aeronautics and Astronautics. Production and hosting by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 304, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": 119, "Article Number": null, "DOI": "10.1016/j.jppr.2018.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.jppr.2018.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437763400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, JY; Yu, GL; Xu, CS; Xiang, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Junyi; Yu, Guoliang; Xu, Changsong; Xiang, H. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General Theory for Bilayer Stacking Ferroelectricity", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) ferroelectrics, which are rare in nature, enable high-density nonvolatile memory with low energy consumption. Here, we propose a theory of bilayer stacking ferroelectricity (BSF), in which two stacked layers of the same 2D material, with different rotation and translation, exhibit ferroelectricity. By performing systematic group theory analysis, we find all the possible BSF in all 80 layer groups (LGs) and discover the rules about the creation and annihilation of symmetries in the bilayer. Our general theory can not only explain all the previous findings (including sliding ferroelectricity), but also provide a new perspective. Interestingly, the direction of the electric polarization of the bilayer could be totally different from that of the single layer. In particular, the bilayer could become ferroelectric after properly stacking two centrosymmetric nonpolar monolayers. By means of first-principles simulations, we predict that the ferroelectricity and thus multiferroicity can be introduced to the prototypical 2D ferromagnetic centrosymmetric material CrI3 by stacking. Furthermore, we find that the out-of-plane electric polarization in bilayer CrI3 is interlocked with the in-plane electric polarization, suggesting that the out-of-plane polarization can be manipulated in a deterministic way through the application of an in-plane electric field. The present BSF theory lays a solid foundation for designing a large number of bilayer ferroelectrics and thus colorful platforms for fundamental studies and applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2023, "Volume": 130, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 146801, "DOI": "10.1103/PhysRevLett.130.146801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.130.146801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001003983500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "null, T; Quintela, CX; Irwin, J; Gurung, G; Shao, DF; Gibbons, J; Campbell, N; Song, K; Choi, SY; Guo, L; Johnson, RD; Manuel, P; Chopdekar, RV; Hallsteinsen, I; Tybell, T; Ryan, PJ; Kim, JW; Choi, Y; Radaelli, PG; Ralph, DC; Tsymbal, EY; Rzchowski, MS; Eom, CB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "null, T.; Quintela, C. X.; Irwin, J.; Gurung, G.; Shao, D. F.; Gibbons, J.; Campbell, N.; Song, K.; Choi, S. -Y.; Guo, L.; Johnson, R. D.; Manuel, P.; Chopdekar, R. V.; Hallsteinsen, I.; Tybell, T.; Ryan, P. J.; Kim, J. -W.; Choi, Y.; Radaelli, P. G.; Ralph, D. C.; Tsymbal, E. Y.; Rzchowski, M. S.; Eom, C. B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling spin current polarization through non-collinear antiferromagnetism", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interconversion of charge and spin currents via spin-Hall effect is essential for spintronics. Energy-efficient and deterministic switching of magnetization can be achieved when spin polarizations of these spin currents are collinear with the magnetization. However, symmetry conditions generally restrict spin polarizations to be orthogonal to both the charge and spin flows. Spin polarizations can deviate from such direction in nonmagnetic materials only when the crystalline symmetry is reduced. Here, we show control of the spin polarization direction by using a non-collinear antiferromagnet Mn3GaN, in which the triangular spin structure creates a low magnetic symmetry while maintaining a high crystalline symmetry. We demonstrate that epitaxial Mn3GaN/permalloy heterostructures can generate unconventional spin-orbit torques at room temperature corresponding to out-of-plane and Dresselhaus-like spin polarizations which are forbidden in any sample with two-fold rotational symmetry. Our results demonstrate an approach based on spin-structure design for controlling spin-orbit torque, enabling high-efficient antiferromagnetic spintronics. In the typical spin-hall effect, spin-current, charge current, and spin polarisation are all mutually perpendicular, a feature enforced by symmetry. Here, using an anti-ferromagnet with a triangular spin structure, the authors demonstrate a spin-hall effect without a perpendicular spin alignment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4671, "DOI": "10.1038/s41467-020-17999-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17999-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000573779400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YS; Liao, HJ; Zhang, Z; Li, SY; Jin, F; Ling, LS; Zhang, L; Zou, YM; Pi, L; Yang, ZR; Wang, JF; Wu, ZH; Zhang, QM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuesheng; Liao, Haijun; Zhang, Zhen; Li, Shiyan; Jin, Feng; Ling, Langsheng; Zhang, Lei; Zou, Youming; Pi, Li; Yang, Zhaorong; Wang, Junfeng; Wu, Zhonghua; Zhang, Qingming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gapless quantum spin liquid ground state in the two-dimensional spin-1/2 triangular antiferromagnet YbMgGaO4", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin liquid (QSL) is a novel state of matter which refuses the conventional spin freezing even at 0 K. Experimentally searching for the structurally perfect candidates is a big challenge in condensed matter physics. Here we report the successful synthesis of a new spin-1/2 triangular antiferromagnet YbMgGaO4 with R (3) over barm symmetry. The compound with an ideal two-dimensional and spatial isotropic magnetic triangular-lattice has no site-mixing magnetic defects and no antisymmetric Dzyaloshinsky-Moriya (DM) interactions. No spin freezing down to 60 mK (despite theta(w) similar to -4 K), the power-law temperature dependence of heat capacity and nonzero susceptibility at low temperatures suggest that YbMgGaO4 is a promising gapless (<=vertical bar theta(w)vertical bar/100) QSL candidate. The residual spin entropy, which is accurately determined with a non-magnetic reference LuMgGaO4, approaches zero (< 0.6%). This indicates that the possible QSL ground state (GS) of the frustrated spin system has been experimentally achieved at the lowest measurement temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16419, "DOI": "10.1038/srep16419", "DOI Link": "http://dx.doi.org/10.1038/srep16419", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364384300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HG; Yang, JH; Kim, WJ; Koo, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyun-Gil; Yang, Jae-Ho; Kim, Weon-Ju; Koo, Yang-Hyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development Status of Accident-tolerant Fuel for Light Water Reactors in Korea", "Source Title": "NUCLEAR ENGINEERING AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For a long time, a top priority in the nuclear industry was the safe, reliable, and economic operation of light water reactors. However, the development of accident-tolerant fuel (ATF) became a hot topic in the nuclear research field after the March 2011 events at Fukushima, Japan. In Korea, innovative concepts of ATF have been developing to increase fuel safety and reliability during normal operations, operational transients, and also accident events. The microcell UO2 and high-density composite pellet concepts are being developed as ATF pellets. A microcell UO2 pellet is envisaged to have the enhanced retention capabilities of highly radioactive and corrosive fission products. High-density pellets are expected to be used in combination with the particular ATF cladding concepts. Two concepts-surface-modified Zr-based alloy and SiC composite material-are being developed as ATF cladding, as these innovative concepts can effectively suppress hydrogen explosions and the release of radionuclides into the environment. Copyright (C) 2015, Published by Elsevier Korea LLC on behalf of Korean Nuclear Society.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 48, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 15, "Article Number": null, "DOI": "10.1016/j.net.2015.11.011", "DOI Link": "http://dx.doi.org/10.1016/j.net.2015.11.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371043200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, K; Sales, BC; Stocks, GM; Samolyuk, GD; Daene, M; Weber, WJ; Zhang, Y; Bei, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, K.; Sales, B. C.; Stocks, G. M.; Samolyuk, G. D.; Daene, M.; Weber, W. J.; Zhang, Y.; Bei, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Equiatomic alloys (e.g. high entropy alloys) have recently attracted considerable interest due to their exceptional properties, which might be closely related to their extreme disorder induced by the chemical complexity. In order to understand the effects of chemical complexity on their fundamental physical properties, a family of (eight) Ni-based, face-center-cubic (FCC), equiatomic alloys, extending from elemental Ni to quinary high entropy alloys, has been synthesized, and their electrical, thermal, and magnetic properties are systematically investigated in the range of 4-300 K by combining experiments with ab initio Korring-Kohn-Rostoker coherent-potential-approximation (KKR-CPA) calculations. The scattering of electrons is significantly increased due to the chemical (especially magnetic) disorder. It has weak correlation with the number of elements but strongly depends on the type of elements. Thermal conductivities of the alloys are largely lower than pure metals, primarily because the high electrical resistivity suppresses the electronic thermal conductivity. The temperature dependence of the electrical and thermal transport properties is further discussed, and the magnetization of five alloys containing three or more elements is measured in magnetic fields up to 4 T.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20159, "DOI": "10.1038/srep20159", "DOI Link": "http://dx.doi.org/10.1038/srep20159", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368984700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, J; Li, YQ; Meng, JH; Pedersen, K; Gurevich, L; Stroe, DI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Jia; Li, Yaqi; Meng, Jinhao; Pedersen, Kjeld; Gurevich, Leonid; Stroe, Daniel-Ioan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the mechanism of capacity increase during early cycling of commercial NMC/graphite lithium-ion batteries", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A capacity increase is often observed in the early stage of Li-ion battery cycling. This study explores the phenomena involved in the capacity increase from the full cell, electrodes, and materials perspective through a combination of non-destructive diagnostic methods in a full cell and post-mortem analysis in a coin cell. The results show an increase of 1% initial capacity for the battery aged at 100% depth of discharge (DOD) and 45 degrees C. Furthermore, large DODs or high temperatures accelerate the capacity increase. From the incremental capacity and differential voltage (IC-DV) analysis, we concluded that the increased capacity in a full cell originates from the graphite anode. Furthermore, graphite/Li coin cells show an increased capacity for larger DODs and a decreased capacity for lower DODs, thus in agreement with the full cell results. Post-mortem analysis results show that a larger DOD enlarges the graphite d -space and separates the graphite layer structure, facilitating the Li+ diffusion, hence increasing the battery capacity.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. This is an open access article under the CC BY license (http://creati-vecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 74, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 34, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.jechem.2022.07.005", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2022.07.005", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000880388600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, B; Ding, WF; Shan, ZD; Wang, J; Yao, CF; Zhao, ZC; Liu, J; Xiao, SH; Ding, Y; Tang, XW; Wang, XC; Wang, YF; Wang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Biao; Ding, Wenfeng; Shan, Zhongde; Wang, Jun; Yao, Changfeng; Zhao, Zhengcai; Liu, Jia; Xiao, Shihong; Ding, Yue; Tang, Xiaowei; Wang, Xingchao; Wang, Yufeng; Wang, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Collaborative manufacturing technologies of structure shape and surface integrity for complex thin-walled components of aero-engine: Status, challenge and tendency", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Presently, the service performance of new-generation high-tech equipment is directly affected by the manufacturing quality of complex thin-walled components. A high-efficiency and quality manufacturing of these complex thin-walled components creates a bottleneck that needs to be solved urgently in machinery manufacturing. To address this problem, the collaborative manufacturing of structure shape and surface integrity has emerged as a new process that can shorten processing cycles, improve machining qualities, and reduce costs. This paper summarises the research status on the material removal mechanism, precision control of structure shape, machined surface integrity control and intelligent process control technology of complex thin-walled components. Numerous solutions and technical approaches are then put forward to solve the critical problems in the high-performance manufacturing of complex thin-wall components. The development status, challenge and tendency of collaborative manufacturing technologies in the high-efficiency and quality manufacturing of complex thin-wall components is also discussed.& COPY; 2023 Production and hosting by Elsevier Ltd. on behalf of Chinese Society of Aeronautics and Astronautics. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/ licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 36, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 24, "Article Number": null, "DOI": "10.1016/j.cja.2023.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2023.02.008", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001047288100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chumak, AV; Kabos, P; Wu, M; Abert, C; Adelmann, C; Adeyeye, AO; Åkerman, J; Aliev, FG; Anulle, A; Awad, A; Back, CH; Barman, A; Bauer, GEW; Becherer, M; Beginin, EN; Bittencourt, VASV; Blanter, YM; Bortolotti, P; Boventer, I; Bozhko, DA; Bunyaev, SA; Carmiggelt, JJ; Cheenikundil, RR; Ciubotaru, F; Cotofana, S; Csaba, G; Dobrovolskiy, OV; Dubs, C; Elyasi, M; Fripp, KG; Fulara, H; Golovchanskiy, IA; Gonzalez-Ballestero, C; Graczyk, P; Grundler, D; Gruszecki, P; Gubbiotti, G; Guslienko, K; Haldar, A; Hamdioui, S; Hertel, R; Hillebrands, B; Hioki, T; Houshang, A; Hu, CM; Huebl, H; Huth, M; Iacocca, E; Jungfleisch, MB; Kakazei, GN; Khitun, A; Khymyn, R; Kikkawa, T; Kläui, M; Klein, O; Klos, JW; Knauer, S; Koraltan, S; Kostylev, M; Krawczyk, M; Krivorotov, IN; Kruglyak, VV; Lachance-Quirion, D; Ladak, S; Lebrun, R; Li, Y; Lindner, M; Macedo, R; Mayr, S; Melkov, GA; Mieszczak, S; Nakamura, Y; Nembach, HT; Nikitin, AA; Nikitov, SA; Novosad, V; Otálora, JA; Otani, Y; Papp, A; Pigeau, B; Pirro, P; Porod, W; Porrati, F; Qin, H; Rana, B; Reimann, T; Riente, F; Romero-Isart, O; Ross, A; Sadovnikov, AV; Safin, AR; Saitoh, E; Schmidt, G; Schultheiss, H; Schultheiss, K; Serga, AA; Sharma, S; Shaw, JM; Suess, D; Surzhenko, O; Szulc, K; Taniguchi, T; Urbanek, M; Usami, K; Ustinov, AB; van der Sar, T; van Dijken, S; Vasyuchka, VI; Verba, R; Kusminskiy, SV; Wang, Q; Weides, M; Weiler, M; Wintz, S; Wolski, SP; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chumak, A. V.; Kabos, P.; Wu, M.; Abert, C.; Adelmann, C.; Adeyeye, A. O.; Akerman, J.; Aliev, F. G.; Anulle, A.; Awad, A.; Back, C. H.; Barman, A.; Bauer, G. E. W.; Becherer, M.; Beginin, E. N.; Bittencourt, V. A. S. V.; Blanter, Y. M.; Bortolotti, P.; Boventer, I.; Bozhko, D. A.; Bunyaev, S. A.; Carmiggelt, J. J.; Cheenikundil, R. R.; Ciubotaru, F.; Cotofana, S.; Csaba, G.; Dobrovolskiy, O. V.; Dubs, C.; Elyasi, M.; Fripp, K. G.; Fulara, H.; Golovchanskiy, I. A.; Gonzalez-Ballestero, C.; Graczyk, P.; Grundler, D.; Gruszecki, P.; Gubbiotti, G.; Guslienko, K.; Haldar, A.; Hamdioui, S.; Hertel, R.; Hillebrands, B.; Hioki, T.; Houshang, A.; Hu, C. -M.; Huebl, H.; Huth, M.; Iacocca, E.; Jungfleisch, M. B.; Kakazei, G. N.; Khitun, A.; Khymyn, R.; Kikkawa, T.; Klaui, M.; Klein, O.; Klos, J. W.; Knauer, S.; Koraltan, S.; Kostylev, M.; Krawczyk, M.; Krivorotov, I. N.; Kruglyak, V. V.; Lachance-Quirion, D.; Ladak, S.; Lebrun, R.; Li, Y.; Lindner, M.; Macedo, R.; Mayr, S.; Melkov, G. A.; Mieszczak, S.; Nakamura, Y.; Nembach, H. T.; Nikitin, A. A.; Nikitov, S. A.; Novosad, V.; Otalora, J. A.; Otani, Y.; Papp, A.; Pigeau, B.; Pirro, P.; Porod, W.; Porrati, F.; Qin, H.; Rana, B.; Reimann, T.; Riente, F.; Romero-Isart, O.; Ross, A.; Sadovnikov, A. V.; Safin, A. R.; Saitoh, E.; Schmidt, G.; Schultheiss, H.; Schultheiss, K.; Serga, A. A.; Sharma, S.; Shaw, J. M.; Suess, D.; Surzhenko, O.; Szulc, K.; Taniguchi, T.; Urbanek, M.; Usami, K.; Ustinov, A. B.; van der Sar, T.; van Dijken, S.; Vasyuchka, V. I.; Verba, R.; Kusminskiy, S. Viola; Wang, Q.; Weides, M.; Weiler, M.; Wintz, S.; Wolski, S. P.; Zhang, X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in Magnetics Roadmap on Spin-Wave Computing", "Source Title": "IEEE TRANSACTIONS ON MAGNETICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnonics addresses the physical properties of spin waves and utilizes them for data processing. Scalability down to atomic dimensions, operation in the GHz-to-THz frequency range, utilization of nonlinear and nonreciprocal phenomena, and compatibility with CMOS are just a few of many advantages offered by magnons. Although magnonics is still primarily positioned in the academic domain, the scientific and technological challenges of the field are being extensively investigated, and many proof-of-concept prototypes have already been realized in laboratories. This roadmap is a product of the collective work of many authors, which covers versatile spin-wave computing approaches, conceptual building blocks, and underlying physical phenomena. In particular, the roadmap discusses the computation operations with the Boolean digital data, unconventional approaches, such as neuromorphic computing, and the progress toward magnon-based quantum computing. This article is organized as a collection of sub-sections grouped into seven large thematic sections. Each sub-section is prepared by one or a group of authors and concludes with a brief description of current challenges and the outlook of further development for each research direction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 58, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 800172, "DOI": "10.1109/TMAG.2022.3149664", "DOI Link": "http://dx.doi.org/10.1109/TMAG.2022.3149664", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800187400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bian, G; Chang, TR; Zheng, H; Velury, S; Xu, SY; Neupert, T; Chiu, CK; Huang, SM; Sanchez, DS; Belopolski, I; Alidoust, N; Chen, PJ; Chang, GQ; Bansil, A; Jeng, HT; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bian, Guang; Chang, Tay-Rong; Zheng, Hao; Velury, Saavanth; Xu, Su-Yang; Neupert, Titus; Chiu, Ching-Kai; Huang, Shin-Ming; Sanchez, Daniel S.; Belopolski, Ilya; Alidoust, Nasser; Chen, Peng-Jen; Chang, Guoqing; Bansil, Arun; Jeng, Horng-Tay; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Drumhead surface states and topological nodal-line fermions in TlTaSe2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A topological nodal-line semimetal is a state of matter with one-dimensional bulk nodal lines and two-dimensional so-called drumhead surface bands. Based on first-principles calculations and an effective k.p model, we theoretically propose the existence of topological nodal-line fermions in the ternary transition-metal chalcogenide TlTaSe2. The noncentrosymmetric structure and strong spin-orbit coupling give rise to spinful nodal-line bulk states which are protected by a mirror reflection symmetry of this compound. This is remarkably distinguished from other proposed nodal-line semimetals such as Cu3NPb(Zn) in which the nodal line exists only in the limit of vanishing spin-orbit coupling and thus is not as robust. In addition, we show that the drumhead surface states in TlTaSe2, which are associated with the topological nodal lines, exhibit an unconventional chiral spin texture and an exotic Lifshitz transition as a consequence of the linkage among multiple drumhead surface-state pockets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2016, "Volume": 93, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121113, "DOI": "10.1103/PhysRevB.93.121113", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.121113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372799400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, PG; Koo, J; Ning, W; Li, JG; Miao, LX; Min, LJ; Zhu, YL; Wang, Y; Alem, N; Liu, CX; Mao, ZQ; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Peigang; Koo, Jahyun; Ning, Wei; Li, Jinguo; Miao, Leixin; Min, Lujin; Zhu, Yanglin; Wang, Yu; Alem, Nasim; Liu, Chao-Xing; Mao, Zhiqiang; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant room temperature anomalous Hall effect and tunable topology in a ferromagnetic topological semimetal Co2MnAl", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals exhibit unusual surface states and anomalous transport phenomena. It is hard to manipulate the band structure topology of specific Weyl materials. Topological transport phenomena usually appear at very low temperatures, which sets challenges for applications. In this work, we demonstrate the band topology modification via a weak magnetic field in a ferromagnetic Weyl semimetal candidate, Co2MnAl, at room temperature. We observe a tunable, giant anomalous Hall effect (AHE) induced by the transition involving Weyl points and nodal rings. The AHE conductivity is as large as that of a 3D quantum AHE, with the Hall angle (Theta (H)) reaching a record value (tan Theta H=0.21) at the room temperature among magnetic conductors. Furthermore, we propose a material recipe to generate large AHE by gaping nodal rings without requiring Weyl points. Our work reveals an intrinsically magnetic platform to explore the interplay between magnetic dynamics and topological physics for developing spintronic devices. Band topology of Weyl semimetals is usually predetermined by material parameters and can hardly be manipulated, and their transport properties appear at low temperature. Here, the authors modify the topology via a weak magnetic field and observe a giant anomalous Hall effect at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-17174-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17174-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548310100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Calderon, VS; Hayden, J; Baksa, SM; Tzou, W; Trolier-McKinstry, S; Dabo, I; Maria, JP; Dickey, EC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Calderon, V. Sebastian; Hayden, John; Baksa, Steven M.; Tzou, William; Trolier-McKinstry, Susan; Dabo, Ismaila; Maria, Jon -Paul; Dickey, Elizabeth C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-scale polarization switching in wurtzite ferroelectrics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectric wurtzites have the potential to revolutionize modern microelectronics because they are easily integrated with multiple mainstream semiconductor platforms. However, the electric fields required to reverse their polarization direction and unlock electronic and optical functions need substantial reduction for operational compatibility with complementary metal-oxide semiconductor (CMOS) electronics. To understand this process, we observed and quantified real-time polarization switching of a representative ferroelectric wurtzite (Al0.94B0.06N) at the atomic scale with scanning transmission electron microscopy. The analysis revealed a polarization reversal model in which puckered aluminum/boron nitride rings in the wurtzite basal planes gradually flatten and adopt a transient nonpolar geometry. Independent first-principles simulations reveal the details and energetics of the reversal process through an antipolar phase. This model and local mechanistic understanding are a critical initial step for property engineering efforts in this emerging material class.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2023, "Volume": 380, "Issue": 6649, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1034, "End Page": 1038, "Article Number": null, "DOI": "10.1126/science.adh7670", "DOI Link": "http://dx.doi.org/10.1126/science.adh7670", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059663700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XC; Zhou, Y; Ezawa, M; Zhao, GP; Zhao, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xichao; Zhou, Yan; Ezawa, Motohiko; Zhao, G. P.; Zhao, Weisheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic skyrmion transistor: skyrmion motion in a voltage-gated nullotrack", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are localized and topologically protected spin configurations, which are of both fundamental and applied interests for future electronics. In this work, we propose a voltage-gated skyrmion transistor within the well-established framework of micromagnetics. Its operating conditions and processes have been theoretically investigated and demonstrated, in which the gate voltage can be used to switch on/off a circuit. Our results provide the first time guidelines for practical realization of hybrid skyrmionic-electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11369, "DOI": "10.1038/srep11369", "DOI Link": "http://dx.doi.org/10.1038/srep11369", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356530500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LW; Wu, T; Wang, DL; Liang, ZM; Yang, X; Peng, ZZ; Liu, Y; Liang, YM; Zeng, Z; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Liwei; Wu, Tao; Wang, Dianlong; Liang, Zhimin; Yang, Xiao; Peng, Zhenzhen; Liu, Ying; Liang, Yongmei; Zeng, Zhi; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel heterogeneous multi-wire indirect arc directed energy deposition for in-situ synthesis Al-Zn-Mg-Cu alloy: Process, microstructure and mechanical properties", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aiming to decouple the inherent relationship between mass transfer and heat transfer in traditional arc-based directed energy deposition, a novel heterogeneous multi-wire indirect arc directed energy deposition (DED) has been developed for in-situ synthesis of Al-Zn-Mg-Cu alloy components. Multi-wires (Al-Cu and Al-Mg) with a bypassing Zn wire have been used to replace the traditional homogeneous twin-wires. The process, micro-structure and mechanical properties of the deposited Al-Zn-Mg-Cu alloy components obtained by multi-wire indirect arc DED were investigated. The results indicate that the wire feeding speed, current and angle be-tween the two wires have a significant influence on the multi-wire indirect arc DED process. When the current was 200 A, the different wire feeding speeds could be used for both wires and the angle between them was 90 degrees. The resulting indirect arc presented a 'heart' shape and allowed to obtain an Al-5.7Zn-3.4Mg-1.6Cu (wt%) alloy with a high deposition rate of 5.1 kg/h. The Al-5.7Zn-3.4Mg-1.6Cu alloy is mainly composed of & alpha;-Al, S (Al2CuMg), & eta; (Mg (Al, Zn, Cu)2) and & eta;& PRIME; phases. The composition and phases are in accordance with the 7xxx series aluminum alloys. The microstructure is dominated by columnar and equiaxed grains, and it has obvious periodic distribution along the building direction, which is related to the process thermal cycle. Fine second phases & eta;& PRIME; are observed to precipitate during the manufacturing process. Furthermore, the average hardness, ultimate tensile strength and elongation of the fabricated material are 98.6 HV, 243.9 MPa and 5.9%, respec-tively. These mechanical properties are higher than those of as-cast 7050 aluminum alloy, thus showing the potential of this new process variant to fabricate high strength Al alloys in the as-deposited state. The fracture morphology exhibit features mainly associated to a ductile-like fracture, accompanied by some transgranular and partial cleavage fracture characteristics. This novel multi-wire indirect arc DED provides a new choice for arc -based directed energy deposition of Al-Zn-Mg-Cu alloys and shows great potential for the in-situ synthesis of other high-performance alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2023, "Volume": 72, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103639, "DOI": "10.1016/j.addma.2023.103639", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2023.103639", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001023704800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, DY; da Jornada, FH; Louie, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Diana Y.; da Jornada, Felipe H.; Louie, Steven G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Screening and many-body effects in two-dimensional crystals: Monolayer MoS2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a systematic study of the variables affecting the electronic and optical properties of two-dimensional (2D) crystals within ab initio GW and GW plus Bethe-Salpeter equation (GW-BSE) calculations. As a prototypical 2D transition metal dichalcogenide material, we focus our study on monolayer MoS2. We find that the reported variations in GW-BSE results in the literature for monolayer MoS2 and related systems arise from different treatments of the long-range Coulomb interaction in supercell calculations and convergence of k-grid sampling and cutoffs for various quantities such as the dielectric screening. In particular, the quasi-2D nature of the system gives rise to fast spatial variations in the screening environment, which are computationally challenging to resolve. We also show that common numerical treatments to remove the divergence in the Coulomb interaction can shift the exciton continuum leading to false convergence with respect to k-point sampling. Our findings apply to GW-BSE calculations on any low-dimensional semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2016, "Volume": 93, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235435, "DOI": "10.1103/PhysRevB.93.235435", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.235435", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378105400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tay, YWD; Qian, Y; Tan, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tay, Yi Wei Daniel; Qian, Ye; Tan, Ming Jen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Printability region for 3D concrete printing using slump and slump flow test", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rheological studies are important for successful 3D concrete printing. The main challenge for successful 3D concrete printing is the complex characteristic the materials should possess. It should be flowable enough to be pumped and extruded through the hose, as well as gaining sufficient strength and stiffness for buildability after the layer by layer deposition. Existing literature has various mixtures proposed for successful 3D concrete printing. Most of these studies used rheometers to measure the dynamic yield stress and plastic viscosity. As the measurement with rheometer is sensitive to the protocols and is controlled by the rheologists, as well as data processing if non-standardized measuring geometries are used, results could vary significantly. This study used standardized field-friendly protocols to measure the slump and slump-flow of the mortars. The pumpability and buildability are evaluated in terms of the pumpability index and maximum height printed before collapsing. These result together with the slump and slump-flow values are used to define the printable region.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 174, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106968, "DOI": "10.1016/j.compositesb.2019.106968", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2019.106968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485853800030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hinuma, Y; Pizzi, G; Kumagai, Y; Oba, F; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hinuma, Yoyo; Pizzi, Giovanni; Kumagai, Yu; Oba, Fumiyasu; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band structure diagram paths based on crystallography", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Systematic and automatic calculations of the electronic band structure are a crucial component of computationally-driven high-throughput materials screening. An algorithm, for any crystal, to derive a unique description of the crystal structure together with a recommended band path is indispensable for this task. The electronic band structure is typically sampled along a path within the first Brillouin zone including the surface in reciprocal space. Some points in reciprocal space have higher site symmetries and/or have higher constraints than other points regarding the electronic band structure and therefore are likely to be more important than other points. This work categorizes points in reciprocal space according to their symmetry and provides recommended band paths that cover all special wavevector (k-vector) points and lines necessarily and sufficiently. Points in reciprocal space are labeled such that there is no conflict with the crystallographic convention. The k-vector coefficients of labeled points, which are located at Brillouin zone face and edge centers as well as vertices, are derived based on a primitive cell compatible with the crystallographic convention, including those with axial ratio-dependent coordinates. Furthermore, we provide an open-source implementation of the algorithms within our SeeK-path python code, to allow researchers to obtain k-vector coefficients and recommended band paths in an automated fashion. Finally, we created a free online service to compute and visualize the first Brillouin zone, labeled k-points and suggested band paths for any crystal structure, that we made available at http://www.materialscloud.org/tools/seekpath/. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 572, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2017, "Volume": 128, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 140, "End Page": 184, "Article Number": null, "DOI": "10.1016/j.commatsci.2016.10.015", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2016.10.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391022600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, Y; Wang, LL; Mun, E; Johnson, DD; Mou, DX; Huang, LN; Lee, Y; Bud'ko, SL; Canfield, PC; Kaminski, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yun; Wang, Lin-Lin; Mun, Eundeok; Johnson, D. D.; Mou, Daixiang; Huang, Lunull; Lee, Yongbin; Bud'ko, S. L.; Canfield, P. C.; Kaminski, Adam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dirac node arcs in PtSn4", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In topological quantum materials(1-3) the conduction and valence bands are connected at points or along lines in the momentum space. A number of studies have demonstrated that several materials are indeed Dirac/Weyl semimetals(4-8). However, there is still no experimental confirmation of materials with line nodes, in which the Dirac nodes form closed loops in the momentum space(2,3). Here we report the discovery of a novel topological structure-Dirac node arcs-in the ultrahigh magnetoresistive material PtSn4 using laser-based angle-resolved photoemission spectroscopy data and density functional theory calculations. Unlike the closed loops of line nodes, the Dirac node arc structure arises owing to the surface states and resembles the Dirac dispersion in graphene that is extended along a short line in the momentum space. We propose that this reported Dirac node arc structure is a novel topological state that provides an exciting platform for studying the exotic properties of Dirac fermions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 12, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 667, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3712", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3712", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379269900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tabis, W; Li, Y; Le Tacon, M; Braicovich, L; Kreyssig, A; Minola, M; Dellea, G; Weschke, E; Veit, MJ; Ramazanoglu, M; Goldman, AI; Schmitt, T; Ghiringhelli, G; Barisic, N; Chan, MK; Dorow, CJ; Yu, G; Zhao, X; Keimer, B; Greven, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tabis, W.; Li, Y.; Le Tacon, M.; Braicovich, L.; Kreyssig, A.; Minola, M.; Dellea, G.; Weschke, E.; Veit, M. J.; Ramazanoglu, M.; Goldman, A. I.; Schmitt, T.; Ghiringhelli, G.; Barisic, N.; Chan, M. K.; Dorow, C. J.; Yu, G.; Zhao, X.; Keimer, B.; Greven, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge order and its connection with Fermi-liquid charge transport in a pristine high-Tc cuprate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic inhomogeneity appears to be an inherent characteristic of the enigmatic cuprate superconductors. Here we report the observation of charge-density-wave correlations in the model cuprate superconductor HgBa2CuO4+delta (T-c = 72 K) via bulk Cu L-3-edge-resonullt X-ray scattering. At the measured hole-doping level, both the short-range charge modulations and Fermi-liquid transport appear below the same temperature of about 200 K. Our result points to a unifying picture in which these two phenomena are preceded at the higher pseudogap temperature by q = 0 magnetic order and the build-up of significant dynamic antiferromagnetic correlations. The magnitude of the charge modulation wave vector is consistent with the size of the electron pocket implied by quantum oscillation and Hall effect measurements for HgBa2CuO4+delta and with corresponding results for YBa2Cu3O6+delta, which indicates that charge-density-wave correlations are universally responsible for the low-temperature quantum oscillation phenomenon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5875, "DOI": "10.1038/ncomms6875", "DOI Link": "http://dx.doi.org/10.1038/ncomms6875", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347685800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, WQ; He, A; Yang, B; Wang, ZH; Huang, JZ; Han, D; Ming, M; Guo, XH; Su, YK; Zhang, JJ; Wang, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Wen-Qi; He, An; Yang, Bo; Wang, Zi-Hao; Huang, Jing-Zhi; Han, Dong; Ming, Ming; Guo, Xuhan; Su, Yikai; Zhang, Jian-Jun; Wang, Ting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithic integration of embedded III-V lasers on SOI", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon photonic integration has gained great success in many application fields owing to the excellent optical device properties and complementary metal-oxide semiconductor (CMOS) compatibility. Realizing monolithic integration of III-V lasers and silicon photonic components on single silicon wafer is recognized as a long-standing obstacle for ultra-dense photonic integration, which can provide considerable economical, energy-efficient and foundry-scalable on-chip light sources, that has not been reported yet. Here, we demonstrate embedded InAs/GaAs quantum dot (QD) lasers directly grown on trenched silicon-on-insulator (SOI) substrate, enabling monolithic integration with butt-coupled silicon waveguides. By utilizing the patterned grating structures inside pre-defined SOI trenches and unique epitaxial method via hybrid molecular beam epitaxy (MBE), high-performance embedded InAs QD lasers with monolithically out-coupled silicon waveguide are achieved on such template. By resolving the epitaxy and fabrication challenges in such monolithic integrated architecture, embedded III-V lasers on SOI with continuous-wave lasing up to 85 degrees C are obtained. The maximum output power of 6.8 mW can be measured from the end tip of the butt-coupled silicon waveguides, with estimated coupling efficiency of approximately -6.7 dB. The results presented here provide a scalable and low-cost epitaxial method for the realization of on-chip light sources directly coupling to the silicon photonic components for future high-density photonic integration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 84, "DOI": "10.1038/s41377-023-01128-z", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01128-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000962366500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalam, A; Al-Sehemi, AG; Assiri, M; Du, GH; Ahmad, T; Ahmad, I; Pannipara, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalam, Abul; Al-Sehemi, Abdullah G.; Assiri, Mohammed; Du, Gaohui; Ahmad, Tokeer; Ahmad, Irfan; Pannipara, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modified solvothermal synthesis of cobalt ferrite (CoFe2O4) magnetic nulloparticles photocatalysts for degradation of methylene blue with H2O2/visible light", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Different grads of magnetic nullo-scaled cobalt ferrites (CoFe2O4) photocatalysts were synthesized by modified Solvothermal (MST) process with and without polysaccharide. The indigenously synthesized photocatalysts were characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), thermo gravimetric analysis (TGA), Fourier transform infrared (FT-IR), UV-visible (UV-vis) spectroscopy and N-2 adsorption-desorption isotherm method. The Fourier transform infrared spectroscopy study showed the Fe-O stretching vibration 590-619 cm(-1), confirming the formation of metal oxide. The crystallite size of the synthesized photocatalysts was found in the range between 20.0 and 30.0 nm. The surface area of obtained magnetic nulloparticles is found to be reasonably high in the range of 63.0-76.0 m(2)/g. The results shown that only MST-2 is the most active catalyst for photo-Fenton like scheme for fast photodegradation action of methylene blue dye, this is possible due to optical band gap estimated of 2.65 eV. Captivatingly the percentage of degradation efficiency increases up to 80% after 140 min by using MST-2 photocatalyst. Photocatalytic degradation of methylene blue (MB) dye under visible light irradiation with cobalt ferrite magnetic nulloparticles followed first order kinetic constant and rate constant of MST-2 is almost 2.0 times greater than MST-1 photocatalyst. (C) 2018 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1046, "End Page": 1053, "Article Number": null, "DOI": "10.1016/j.rinp.2018.01.045", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2018.01.045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428027700144", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HJ; Xiao, D; Zhu, ZH; Zhang, C; Yang, L; He, HY; You, JM; Jiang, QG; Xu, XT; Yamauchi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Huajie; Xiao, Di; Zhu, Zihan; Zhang, Chi; Yang, Lu; He, Haiyan; You, Jungmok; Jiang, Quanguo; Xu, Xingtao; Yamauchi, Yusuke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A 2D/2D heterojunction of ultrathin Pd nullosheet/MXene towards highly efficient methanol oxidation reaction: the significance of 2D material nulloarchitectonics", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) Pd nullosheet-based catalysts have recently garnered widespread attention due to their high atom utilization efficiency. However, their catalytic ability and structural stability still require significant enhancement before they can be widely applied. In this study, we presented the rational design and controllable fabrication of a novel 2D/2D heterojunction, which consists of ultrathin Pd nullosheets (NSs) grown on the Ti3C2Tx MXene surface (Pd NSs/MXene). This heterostructure was achieved through a robust and convenient stereo-assembly strategy. The newly developed Pd NSs/MXene heterojunction not only provides numerous exposed active Pd atoms with an optimized electronic structure but also enables an intimate Pd/MXene interfacial interaction, ensuring a stable hybrid configuration. Consequently, the resulting Pd NSs/MXene heterojunction exhibits exceptional methanol oxidation properties. It possesses a large electrochemically active surface area, high mass and specific activities, and a long operating life, which are significantly superior to those of traditional Pd nulloparticle/carbon and Pd nullosheet/carbon catalysts. Theoretical simulations further reveal strong electronic interactions between the Pd nullosheet and MXene, which dramatically enhance the adsorption energy of the Pd component and simultaneously lower its d-band center. As a result, the Pd NSs/MXene heterojunction is less susceptible to CO poisoning. This work introduces a new 2D/2D heterojunction based on MXene and noble metallic materials and holds significance for the development of other novel heterojunctions, particularly within the realm of 2D material nulloarchitectonics. The stereo-assembly of ultrathin Pd nullosheets in situ grown on the MXene surface was achieved via a convenient wet-chemical approach, which possess superior electrocatalytic performance for the methanol oxidation reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2023, "Volume": 14, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9854, "End Page": 9862, "Article Number": null, "DOI": "10.1039/d3sc03735e", "DOI Link": "http://dx.doi.org/10.1039/d3sc03735e", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057864900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bartók, AP; De, S; Poelking, C; Bernstein, N; Kermode, JR; Csányi, G; Ceriotti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bartok, Albert P.; De, Sandip; Poelking, Carl; Bernstein, Noam; Kermode, James R.; Csanyi, Gabor; Ceriotti, Michele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning unifies the modeling of materials and molecules", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Determining the stability ofmolecules and condensed phases is the cornerstone of atomisticmodeling, underpinning our understanding of chemical andmaterials properties and transformations. We show that amachine-learningmodel, based on a local description of chemical environments and Bayesian statistical learning, provides a unified framework to predict atomic-scale properties. It captures the quantum mechanical effects governing the complex surface reconstructions of silicon, predicts the stability of different classes of molecules with chemical accuracy, and distinguishes active and inactive protein ligands with more than 99% reliability. The universality and the systematic nature of our framework provide new insight into the potential energy surface of materials and molecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 522, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1701816", "DOI": "10.1126/sciadv.1701816", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1701816", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418003100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parimi, LL; Ravi, GA; Clark, D; Attallah, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parimi, Lakshmi L.; Ravi, G. A.; Clark, Daniel; Attallah, Moataz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructural and texture development in direct laser fabricated IN718", "Source Title": "MATERIALS CHARACTERIZATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microstructural characterisation was performed for IN718 thin-walled builds, produced using direct laser fabrication (DLF), to understand the influence of the variations in the deposition path and the laser power on the microtexture, grain structures and intermetallic particle morphology development. Considerable differences were observed, with the high laser power input generating a columnar grain structure, with a strong < 001 > fibre texture along the build height, compared to a mixture of fine uniform and large columnar grains in the low power builds, with a near random texture. The influence of different DLF conditions on the formation of Laves and of delta phase was also found to be significant, with the Laves phase precipitates being larger in the high laser power sample. Carbides and delta were also present in the high power build, but were not observed in the low power samples regardless of the deposition path. (C) 2013 The Authors. Published by Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 486, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 89, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 102, "End Page": 111, "Article Number": null, "DOI": "10.1016/j.matchar.2013.12.012", "DOI Link": "http://dx.doi.org/10.1016/j.matchar.2013.12.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333513400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Helbig, C; Bradshaw, AM; Wietschel, L; Thorenz, A; Tuma, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Helbig, Christoph; Bradshaw, Alex M.; Wietschel, Lars; Thorenz, Andrea; Tuma, Axel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supply risks associated with lithium-ion battery materials", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One possibility for electrification of road transport consists of battery electric vehicles in combination with carbon-free sources of electricity. It is highly likely that lithium-ion batteries will provide the basis for this development. In the present paper, we use a recently developed, semi-quantitative assessment scheme to evaluate the relative supply risks associated with the elements used in the functional materials of six different lithium-ion battery types. Eleven different indicators in four supply risk categories are applied to each element; the weighting of the indicators is determined by external experts within the framework of an Analytic Hierarchy Process. The range of supply risk values on the elemental level is distinctly narrower than in our previous work on photovoltaic materials. The highest values are obtained for lithium and cobalt; the lowest for aluminium and titanium. Copper, iron, nickel, carbon (graphite), manganese and phosphorous form the middle group. We then carry out the assessment of the six battery types, to give comparative supply risks at the technology level. For this purpose the elemental supply risk values are aggregated using four different methods. Due to the small spread at the elemental level the supply risk values in all four aggregation methods also lie in a narrow range. Removing lithium, aluminium and phosphorous from the analysis, which are present in all types of battery, improves the situation. For aggregation with the simple arithmetic mean, an uncertainty analysis shows that only lithium-iron phosphate has a measurably lower supply risk compared to the other battery types. For the cost-share aggregation using seven elements, lithium cobalt oxide has a substantially higher supply risk than most other types. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2018, "Volume": 172, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 274, "End Page": 286, "Article Number": null, "DOI": "10.1016/j.jclepro.2017.10.122", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2017.10.122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423001900026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JX; Liu, JX; Baronett, SA; Liu, MF; Wang, L; Li, RH; Chen, Y; Li, DZ; Zhu, Q; Chen, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiangxu; Liu, Jiaxi; Baronett, Stanley A.; Liu, Mingfeng; Wang, Lei; Li, Ronghan; Chen, Yun; Li, Dianzhong; Zhu, Qiang; Chen, Xing-Qiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computation and data driven discovery of topological phononic materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of topological quantum states marks a new chapter in both condensed matter physics and materials sciences. By analogy to spin electronic system, topological concepts have been extended into phonons, boosting the birth of topological phononics (TPs). Here, we present a high-throughput screening and data-driven approach to compute and evaluate TPs among over 10,000 real materials. We have discovered 5014 TP materials and grouped them into two main classes of Weyl and nodal-line (ring) TPs. We have clarified the physical mechanism for the occurrence of single Weyl, high degenerate Weyl, individual nodal-line (ring), nodal-link, nodal-chain, and nodal-net TPs in various materials and their mutual correlations. Among the phononic systems, we have predicted the hourglass nodal net TPs in TeO3, as well as the clean and single type-I Weyl TPs between the acoustic and optical branches in half-Heusler LiCaAs. In addition, we found that different types of TPs can coexist in many materials (such as ScZn). Their potential applications and experimental detections have been discussed. This work substantially increases the amount of TP materials, which enables an in-depth investigation of their structure-property relations and opens new avenues for future device design related to TPs. Topological phononic (TP) materials are attracting wide attentions and it is more difficult to seek TP materials compared to electronic materials. Here, the authors present a high-throughput screening and data-driven approach to discover 5014 TP materials and further clarify the mechanism for the occurrence of various TPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1204, "DOI": "10.1038/s41467-021-21293-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21293-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621928300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bainsla, L; Mallick, AI; Raja, MM; Nigam, AK; Varaprasad, BSDCS; Takahashi, YK; Alam, A; Suresh, KG; Hono, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bainsla, Lakhan; Mallick, A. I.; Raja, M. Manivel; Nigam, A. K.; Varaprasad, B. S. D. Ch. S.; Takahashi, Y. K.; Alam, Aftab; Suresh, K. G.; Hono, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin gapless semiconducting behavior in equiatomic quaternary CoFeMnSi Heusler alloy", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, we report the signature of spin gapless semiconductor (SGS) in CoFeMnSi that belongs to the Heusler family. SGS is a new class of magnetic semiconductors which have a band gap for one spin subband and zero band gap for the other, and thus are useful for tunable spin transport based applications. We show various experimental evidences for SGS behavior in CoFeMnSi by carefully carrying out the transport and spin-polarization measurements. SGS behavior is also confirmed by first-principles band-structure calculations. The most stable configuration obtained by the theoretical calculation is verified by experiment. The alloy is found to crystallize in the cubic Heusler structure (LiMgPdSn type) with some amount of disorder and has a saturation magnetization of 3.7 mu(B)/f.u. and Curie temperature of similar to 620 K. The saturation magnetization is found to follow the Slater-Pauling behavior, one of the prerequisites for SGS. Nearly-temperature-independent carrier concentration and electrical conductivity are observed from 5 to 300 K. An anomalous Hall coefficient of 162 S/cm is obtained at 5 K. Point contact Andreev reflection data have yielded the current spin-polarization value of 0.64, which is found to be robust against the structural disorder. All these properties strongly suggest SGS nature of the alloy, which is quite promising for the spintronic applications such as spin injection as it can bridge the gap between the contrasting behaviors of half-metallic ferromagnets and semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2015, "Volume": 91, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104408, "DOI": "10.1103/PhysRevB.91.104408", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.104408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351431900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, C; Zhou, X; Tao, BJ; Wu, HT; Huang, SF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Chao; Zhou, Xu; Tao, Bingjing; Wu, Haitao; Huang, Shifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal structure and enhanced microwave dielectric properties of the Ce2[Zr1-x(Al1/2Ta1/2)x]3(MoO4)9 ceramics at microwave frequency", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dense microwave dielectric ceramics of Ce-2[Zr1-x(Al1/2Ta1/2)(x)](3)(MoO4)(9) (CZMAT) (x = 0.02-0.10) were prepared by the conventional solid-state route. The effects of (Al1/2Ta1/2)(4+) on their microstructures, sintering behaviors, and microwave dielectric properties were systematically investigated. On the basis of the X-ray diffraction (XRD) results, all the samples were matched well with Pr2Zr3(MoO4)(9) structures, which belonged to the space group R<(3)over bar >c. The lattice parameters were obtained using the Rietveld refinement method. The correlations between the chemical bond parameters and microwave dielectric properties were calculated and analyzed by using the Phillips-Van Vechten-Levine (P-V-L) theory. Excellent dielectric properties of Ce-2[Zr-0.94(Al1/2Ta1/2)(0.06)](3)(MoO4)(9) with a relative permittivity (epsilon(r)) of 10.46, quality factor (Q x f) of 83,796 GHz, and temperature coefficient of resonullt frequency (tau(f)) of -11.50 ppm/degrees C were achieved at 850 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 392, "End Page": 402, "Article Number": null, "DOI": "10.1007/s40145-021-0541-7", "DOI Link": "http://dx.doi.org/10.1007/s40145-021-0541-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753927800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WY; Wang, W; Wang, YH; Sun, R; Guo, J; Li, HN; Shi, MM; Guo, J; Wu, Y; Wang, T; Lu, GH; Brabec, CJ; Li, YF; Min, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wenyan; Wang, Wei; Wang, Yuheng; Sun, Rui; Guo, Jie; Li, Hongneng; Shi, Mumin; Guo, Jing; Wu, Yao; Wang, Tao; Lu, Guanghao; Brabec, Christoph J.; Li, Yongfang; Min, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Balancing the efficiency, stability, and cost potential for organic solar cells via a new figure of merit", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In spite of the great success in device efficiency resulting from the excessive design of photovoltaic materials, the stability and cost issues concerning basic commercial requirements of organic solar cells (OSCs) remain unresolved or controversial, slowing down the introduction of market-ready applications. We proposed an exciting discovery that as the active layer thickness decreases, the thermal stability increases gradually, even exceeding 100% of the initial efficiency under 150 degrees C thermal stress. This trend was further confirmed by investigating thermodynamics and kinetics of morphology evolution for PM6:Y6 as a reference example, Extended research found that there is a similar correlation between photo-thermal stability and blend thickness. Consequently, a new reliable industrial figure of merit (i-FOM2.0), including four main factors: efficiency, photo-thermal stability, synthesis complexity, and active layer thickness, is presented here. Our work provides a promising trade-off strategy for reducing efficiency-stability-cost gap and accelerates the commercialization of OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2021, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1209, "End Page": 1230, "Article Number": null, "DOI": "10.1016/j.joule.2021.03.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.03.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654225600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De, S; Bartók, AP; Csányi, G; Ceriotti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De, Sandip; Bartok, Albert P.; Csanyi, Gabor; Ceriotti, Michele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparing molecules and solids across structural and alchemical space", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Evaluating the (dis)similarity of crystalline, disordered and molecular compounds is a critical step in the development of algorithms to navigate automatically the configuration space of complex materials. For instance, a structural similarity metric is crucial for classifying structures, searching chemical space for better compounds and materials, and driving the next generation of machine-learning techniques for predicting the stability and properties of molecules and materials. In the last few years several strategies have been designed to compare atomic coordination environments. In particular, the smooth overlap of atomic positions (SOAPs) has emerged as an elegant framework to obtain translation, rotation and permutation-invariant descriptors of groups of atoms, underlying the development of various classes of machine-learned inter-atomic potentials. Here we discuss how one can combine such local descriptors using a regularized entropy match (REMatch) approach to describe the similarity of both whole molecular and bulk periodic structures, introducing powerful metrics that enable the navigation of alchemical and structural complexities within a unified framework. Furthermore, using this kernel and a ridge regression method we can predict atomization energies for a database of small organic molecules with a mean absolute error below 1 kcal mol(-1), reaching an important milestone in the application of machine-learning techniques for the evaluation of molecular properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 560, "Times Cited, All Databases": 614, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2016, "Volume": 18, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13754, "End Page": 13769, "Article Number": null, "DOI": "10.1039/c6cp00415f", "DOI Link": "http://dx.doi.org/10.1039/c6cp00415f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377042400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Siddiqui, SA; Han, JH; Finley, JT; Ross, CA; Liu, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Siddiqui, Saima A.; Han, Jiahao; Finley, Joseph T.; Ross, Caroline A.; Liu, Luqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current-Induced Domain Wall Motion in a Compensated Ferrimagnet", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the difficulty in detecting and manipulating the magnetic states of antiferromagnetic materials, studying their switching dynamics using electrical methods remains a challenging task. By employing heavy-metal-rare-earth-transition-metal alloy bilayers, we experimentally study current-induced domain wall dynamics in an antiferromagnetically coupled system. We show that the current-induced domain wall mobility reaches a maximum at the angular momentum compensation point. With experiment and modeling, we further reveal the internal structures of domain walls and the underlying mechanisms for their fast motion. We show that the chirality of the ferrimagnetic domain walls remains the same across the compensation points, suggesting that spin orientations of specific sublattices rather than net magnetization determine Dzyaloshinskii-Moriya interaction in heavy-metal-ferrimagnet bilayers. The high current-induced domain wall mobility and the robust domain wall chirality in compensated ferrimagnetic material opens new opportunities for high-speed spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2018, "Volume": 121, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57701, "DOI": "10.1103/PhysRevLett.121.057701", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.057701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440143200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peelaers, H; Varley, JB; Speck, JS; Van de Waller, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peelaers, Hartwin; Varley, Joel B.; Speck, James S.; Van de Waller, Chris G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural and electronic properties of Ga2O3-Al2O3 alloys", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ga2O3 is emerging as an important electronic material. Alloying with Al2O3 is a viable method to achieve carrier confinement, to increase the bandgap, or to modify the lattice parameters. However, the two materials have very different ground-state crystal structures (monoclinic beta-gallia for Ga2O3 and corundum for Al2O3). Here, we use hybrid density functional theory calculations to assess the alloy stabilities and electronic properties of the alloys. We find that the monoclinic phase is the preferred structure for up to 71% Al incorporation, in close agreement with experimental phase diagrams, and that the ordered monoclinic AlGaO3 alloy is exceptionally stable. We also discuss bandgap bowing, lattice constants, and band offsets that can guide future synthesis and device design efforts. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2018, "Volume": 112, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 242101, "DOI": "10.1063/1.5036991", "DOI Link": "http://dx.doi.org/10.1063/1.5036991", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435451600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klein, J; Kampermann, L; Mockenhaupt, B; Behrens, M; Strunk, J; Bacher, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klein, Julian; Kampermann, Laura; Mockenhaupt, Benjamin; Behrens, Malte; Strunk, Jennifer; Bacher, Gerd", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Limitations of the Tauc Plot Method", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Tauc plot is a method originally developed to derive the optical gap of amorphous semiconductors such as amorphous germanium or silicon. By measuring the absorption coefficient alpha(h nu) and plotting (alpha h nu)1/2 versus photon energy h nu, a value for the optical gap (Tauc gap) is determined. In this way non-direct optical transitions between approximately parabolic bands can be examined. In the last decades, a modification of this method for (poly-) crystalline semiconductors has become popular to study direct and indirect interband transitions. For this purpose, (alpha h nu)(n) (n = 1/2, 2) is plotted against h nu to determine a value of the electronic bandgap. Due to the ease of performing UV-vis measurements, this method has nowadays become a standard to analyze various (poly-) crystalline solids, regardless of their different electronic structure. Although this leads partially to widely varying values of the respective bandgap of nominally identical materials, there is still no study that critically questions which peculiarities in the electronic structure prevent a use of the Tauc plot for (poly-) crystalline solids and to which material classes this applies. This study aims to close this gap by discussing the Tauc plot and its limiting factors for exemplary (poly-)crystalline solids with different electronic structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 33, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202304523", "DOI Link": "http://dx.doi.org/10.1002/adfm.202304523", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057439700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, YC; Singh, RK; Feng, S; Liu, J; Xiao, J; Bao, J; Xu, ZJ; Lu, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Yucheng; Singh, Rajesh K.; Feng, Shuo; Liu, Jun; Xiao, Jie; Bao, Jie; Xu, Zhijie; Lu, Dongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding of Low-Porosity Sulfur Electrode for High-Energy Lithium-Sulfur Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lithium-sulfur (Li-S) battery is a promising technology for large-scale energy storage and vehicle electrification due to its high theoretical energy density and low cost. Reducing the sulfur cathode porosity has been identified recently as a viable strategy for improving the cell practical energy density and minimizing pore-filling electrolytes to extend cell life at lean electrolyte conditions. Direct use of a low-porosity cathode for Li-S battery results in poor electrode wetting, nonuniform electrode reactions, and thus early cell failure. To understand and mitigate the barriers associated with the use of low-porosity electrodes, multiscale modeling is performed to predict electrode wetting, electrolyte diffusion, and their impacts on sulfur reactions in Li-S cells by explicitly considering the electrode wettability impacts and electrode morphologies. The study elucidates the critical impact of low tortuosity and large channel pore design for promoting electrode wetting and species diffusion. It is suggested that the secondary particle size should be comparable with the electrode thickness to effectively promote electrolyte wettability and sulfur reactivity. This study provides new insights into the low-porosity electrode material and designs and is expected to accelerate the development of practical high-energy Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 13, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202203386", "DOI Link": "http://dx.doi.org/10.1002/aenm.202203386", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935111800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JJ; Zhao, Y; Zhang, K; Zada, A; Qi, KZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jingjing; Zhao, Yue; Zhang, Kai; Zada, Amir; Qi, Kezhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sonocatalytic degradation of tetracycline hydrochloride with CoFe2O4/g-C3N4 composite", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, different mass percent ratios of CoFe2O4 coupled g-C3N4 (w%-CoFe2O4/g-C3N4, CFO/CN) nullocomposites were integrated through a hydrothermal process for the sonocatalytic eradication of tetracycline hydrochloride (TCH) from aqueous media. The prepared sonocatalysts were subjected to various techniques to investigate their morphology, crystallinity, ultrasound wave capturing activity and charge conductivity. From the investigated activity of the composite materials, it has been registered that the best sonocatalytic degradation efficiency of 26.71 % in 10 min was delivered when the amount of CoFe2O4 was 25% in the nullocomposite. The delivered efficiency was higher than that of bare CoFe2O4 and g-C3N4. This enriched sonocatalytic efficiency was credited to the accelerated charge transfer and separation of e(-)-h(+) pair through the S-scheme heterojunctional interface. The trapping experiments confirmed that all the three species i.e. (OH)-O-center dot, h(+) and(center dot)O(2)(-) were involved in the eradication of antibiotics. A strong interaction was shown up between CoFe2O4 and g-C3N4 in the FTIR study to support charge transfer as confirmed from the photoluminescence and photocurrent analysis of the samples. This work will provide an easy approach for fabricating highly efficient low-cost magnetic sonocatalysts for the eradication of hazardous materials present in our environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 94, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106325, "DOI": "10.1016/j.ultsonch.2023.106325", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2023.106325", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940948000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, SJ; Kim, DH; Bae, G; Ringe, S; Choi, H; Lim, HK; Choi, CH; Kim, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Seung-Jae; Kim, Dong Hyun; Bae, Geunsu; Ringe, Stefan; Choi, Hansol; Lim, Hyung-Kyu; Choi, Chang Hyuck; Kim, Hyungjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the importance of the electric double layer structure in aqueous electrocatalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To design electrochemical interfaces for efficient electric-chemical energy interconversion, it is critical to reveal the electric double layer (EDL) structure and relate it with electrochemical activity; nonetheless, this has been a long-standing challenge. Of particular, no molecularlevel theories have fully explained the characteristic two peaks arising in the potentialdependence of the EDL capacitance, which is sensitively dependent on the EDL structure. We herein demonstrate that our first-principles-based molecular simulation reproduces the experimental capacitance peaks. The origin of two peaks emerging at anodic and cathodic potentials is unveiled to be an electrosorption of ions and a structural phase transition, respectively. We further find a cation complexation gradually modifies the EDL structure and the field strength, which linearly scales the carbon dioxide reduction activity. This study deciphers the complex structural response of the EDL and highlights its catalytic importance, which bridges the mechanistic gap between the EDL structure and electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 174, "DOI": "10.1038/s41467-021-27909-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27909-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965941000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SS; Zhang, JB; Gharbi, O; Vivier, V; Gao, M; Orazem, ME", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shangshang; Zhang, Jianbo; Gharbi, Oumaima; Vivier, Vincent; Gao, Ming; Orazem, Mark E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical impedance spectroscopy", "Source Title": "NATURE REVIEWS METHODS PRIMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical impedance spectroscopy (EIS) is a powerful tool to investigate properties of materials and electrode reactions. This Primer provides a guide to the use of EIS and a comparison with other electrochemical techniques. The analysis of impedance data for reduction of ferricyanide in a KCl supporting electrolyte is used to demonstrate the error structure for impedance measurements, the use of measurement and process models, and the sensitivity of impedance to the evolution of electrode properties. This Primer provides guidelines for experimental design, discusses the relevance of accuracy contour plots to wiring and instrumentation selection, and emphasizes the importance of the Kramers-Kronig relations to data validation and analysis. Applications of EIS to battery performance, metal and alloy corrosion, and electrochemical biosensors are highlighted. Electrochemical impedance measurements depend on both the mechanism under investigation and extrinsic parameters, such as the electrode geometry. Experimental complications are discussed, including the influence of non-stationary behaviour at low frequencies and the need for reference electrodes. Finally, emerging trends in experimental and interpretation approaches are also described.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 481, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 10", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41, "DOI": "10.1038/s43586-021-00039-w", "DOI Link": "http://dx.doi.org/10.1038/s43586-021-00039-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888180200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FL; Fang, S; Kuenzel, M; Mullaliu, A; Kim, JK; Gao, XP; Diemant, T; Kim, GT; Passerini, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fanglin; Fang, Shan; Kuenzel, Matthias; Mullaliu, Angelo; Kim, Jae-Kwang; Gao, Xinpei; Diemant, Thomas; Kim, Guk-Tae; Passerini, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium-metal batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy-density lithium-metal batteries face the challenge of developing functional electrolytes enabling both the stabilization of the lithium-metal negative electrode and high-voltage positive electrodes (> 4 V versus Li+/Li). Herein, a low-volatility and non-flammable ionic liquid electrolyte (ILE) incorporating two anions, bis(fluorosulfonyl) imide (FSI) and bis(trifluoromethanesulfonyl) imide (TFSI), is successfully applied to overcome this challenge, employing the high-energy, low-Co, and Ni-rich positive-electrode material, LiNi0.88Co0.09Mn0.03O2 (NCM88), in Li-metal batteries. With this specific electrolyte, the cathode exhibits remarkable electrochemical performance, achieving an initial specific capacity of 214 mAh g(-1) and outstanding capacity retention of 88% over 1,000 cycles. More importantly, this electrolyte enables an average Coulombic efficiency of 99.94%. The excellent compatibility of the dual-anion ILE with both the lithium metal (50 mu m) and the highvoltage positive- electrode material enables the realization of Li-metal cells achieving specific energies of more than 560 Wh kg(-1) based on their combined active material masses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2021, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2177, "End Page": 2194, "Article Number": null, "DOI": "10.1016/j.joule.2021.06.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.06.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686543600020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Minnmann, P; Quillman, L; Burkhardt, S; Richter, FH; Janek, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Minnmann, Philip; Quillman, Lars; Burkhardt, Simon; Richter, Felix H.; Janek, Juergen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Editors' Choice-Quantifying the Impact of Charge Transport Bottlenecks in Composite Cathodes of All-Solid-State Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state lithium batteries have the potential to provide increased energy and power density compared to conventional lithium-ion batteries with a liquid electrolyte. The charge transport within solid electrolyte-based composite cathodes determines the C-rate capability and ultimately the overall performance of a solid-state cell, making it one of the key remaining challenges. In this study, the charge transport in composite cathodes composed of Li6PS5Cl and NCM-622 is analyzed and characterized in terms of the effective ionic and electronic partial conductivities. The correlations between these effective conductivities, the microstructure of the composite cathodes, and the all-solid-state cell performance are revealed. By quantifying these correlations, bottlenecks for charge transport in composite cathodes are identified and strategies to optimize the cell performance are developed. The optimization potential of these strategies is demonstrated exemplarily by tuning electronic and ionic charge transport pathways using high active material loadings and an adjusted solid electrolyte particle size, respectively. The results will help to further increase energy and power density of all-solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2021, "Volume": 168, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 40537, "DOI": "10.1149/1945-7111/abf8d7", "DOI Link": "http://dx.doi.org/10.1149/1945-7111/abf8d7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645578600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ku, MJH; Zhou, TX; Li, Q; Shin, YJ; Shi, JK; Burch, C; Anderson, LE; Pierce, AT; Xie, YL; Hamo, A; Vool, U; Zhang, HL; Casola, F; Taniguchi, T; Watanabe, K; Fogler, MM; Kim, P; Yacoby, A; Walsworth, RL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ku, Mark J. H.; Zhou, Tony X.; Li, Qing; Shin, Young J.; Shi, Jing K.; Burch, Claire; Anderson, Laurel E.; Pierce, Andrew T.; Xie, Yonglong; Hamo, Assaf; Vool, Uri; Zhang, Huiliang; Casola, Francesco; Taniguchi, Takashi; Watanabe, Kenji; Fogler, Michael M.; Kim, Philip; Yacoby, Amir; Walsworth, Ronald L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imaging viscous flow of the Dirac fluid in graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electron-hole plasma in charge-neutral graphene is predicted to realize a quantum critical system in which electrical transport features a universal hydrodynamic description, even at room temperature(1,2). This quantum critical 'Dirac fluid' is expected to have a shear viscosity close to a minimum bound(3,4), with an interparticle scattering rate saturating(1)at the Planckian time, the shortest possible timescale for particles to relax. Although electrical transport measurements at finite carrier density are consistent with hydrodynamic electron flow in graphene(5-8), a clear demonstration of viscous flow at the charge-neutrality point remains elusive. Here we directly image viscous Dirac fluid flow in graphene at room temperature by measuring the associated stray magnetic field. nulloscale magnetic imaging is performed using quantum spin magnetometers realized with nitrogen vacancy centres in diamond. Scanning single-spin and wide-field magnetometry reveal a parabolic Poiseuille profile for electron flow in a high-mobility graphene channel near the charge-neutrality point, establishing the viscous transport of the Dirac fluid. This measurement is in contrast to the conventional uniform flow profile imaged in a metallic conductor and also in a low-mobility graphene channel. Via combined imaging and transport measurements, we obtain viscosity and scattering rates, and observe that these quantities are comparable to the universal values expected at quantum criticality. This finding establishes a nearly ideal electron fluid in charge-neutral, high-mobility graphene at room temperature(4). Our results will enable the study of hydrodynamic transport in quantum critical fluids relevant to strongly correlated electrons in high-temperature superconductors(9). This work also highlights the capability of quantum spin magnetometers to probe correlated electronic phenomena at the nulloscale. Viscous Dirac fluid flow in room-temperature graphene is imaged using quantum diamond magnetometry, revealing a parabolic Poiseuille profile for electron flow in a high-mobility graphene channel near the charge-neutrality point.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 23", "Publication Year": 2020, "Volume": 583, "Issue": 7817, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 537, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2507-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2507-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551954700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, HJ; Zhao, QQ; Chen, ZY; Chen, H; Chao, PJ; Zhu, YL; Lang, YW; Zhen, N; Mo, DZ; Zhang, YZ; He, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Hanjian; Zhao, Qiaoqiao; Chen, Ziyi; Chen, Hui; Chao, Pengjie; Zhu, Yulin; Lang, Yongwen; Zhen, null; Mo, Daize; Zhang, Yuanzhu; He, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trifluoromethylation Enables a 3D Interpenetrated Low-Band-Gap Acceptor for Efficient Organic Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Trifluoromethylation has been used for nonfullerene acceptors, resulting in an ultra-narrow band-gap molecule named BTIC-CF3-gamma. Compared to its fluorinated and chlorinated analogs, BTIC-CF3-gamma possesses the most red-shifted absorptions. The single-crystal structure of BTIC-CF3-gamma reveals that the cooperated pi-pi interactions from H aggregations of central fused cores and J aggregations of end groups lead to a three-dimensional (3D) interpenetrating network, which provides more electron-hopping junctions between different acceptor molecules. After blending with PBDB-TF, a champion power conversion efficiency (PCE) of 15.59% is realized, which is the highest value in reported ultra-narrow band-gap acceptors. Notably, a PCE of 16.50% is also achieved in BTIC-CF3-gamma-based ternary devices due to their red-shifted absorptions. Overall, our results provide a visualized understanding of molecule packings of this family of acceptors and also demonstrate that trifluoromethylation is a useful strategy to design highly efficient ultra-low band-gap acceptors for the next nonfullerene solar devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2020, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 688, "End Page": 700, "Article Number": null, "DOI": "10.1016/j.joule.2020.02.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.02.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520874200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kahmann, S; Tekelenburg, EK; Duim, H; Kamminga, ME; Loi, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kahmann, Simon; Tekelenburg, Eelco K.; Duim, Herman; Kamminga, Machteld E.; Loi, Maria A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden-Popper perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional metal halide perovskites of Ruddlesden-Popper type have recently moved into the centre of attention of perovskite research due to their potential for light generation and for stabilisation of their 3D counterparts. It has become widespread in the field to attribute broad luminescence with a large Stokes shift to self-trapped excitons, forming due to strong carrier-phonon interactions in these compounds. Contrarily, by investigating the behaviour of two types of lead-iodide based single crystals, we here highlight the extrinsic origin of their broad band emission. As shown by below-gap excitation, in-gap states in the crystal bulk are responsible for the broad emission. With this insight, we further the understanding of the emission properties of low-dimensional perovskites and question the generality of the attribution of broad band emission in metal halide perovskite and related compounds to self-trapped excitons. The Ruddlesden-Popper type of halide perovskites are gaining interest but the origin of their broad band emission remains elusive. Here Kahmann et al. suggest that in-gap states, instead of the commonly believed self-trapped excitons, are responsible for the broad band emission in crystalline samples.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2344, "DOI": "10.1038/s41467-020-15970-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15970-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558697900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, HW; Yang, ZH; Perdew, JP; Sun, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Haowei; Yang, Zeng-Hui; Perdew, John P.; Sun, Jianwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Versatile van der Waals Density Functional Based on a Meta-Generalized Gradient Approximation", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A best-of-both-worlds van der Waals (vdW) density functional is constructed, seamlessly supplementing the strongly constrained and appropriately normed (SCAN) meta-generalized gradient approximation for short-and intermediate-range interactions with the long-range vdW interaction from rVV10, the revised Vydrov-van Voorhis nonlocal correlation functional. The resultant SCAN+rVV10 is the only vdW density functional to date that yields excellent interlayer binding energies and spacings, as well as intralayer lattice constants in 28 layered materials. Its versatility for various kinds of bonding is further demonstrated by its good performance for 22 interactions between molecules; the cohesive energies and lattice constants of 50 solids; the adsorption energy and distance of a benzene molecule on coinage-metal surfaces; the binding energy curves for graphene on Cu(111), Ni(111), and Co(0001) surfaces; and the rare-gas solids. We argue that a good semilocal approximation should (as SCAN does) capture the intermediate-range vdW through its exchange term. We have found an effective range of the vdW interaction between 8 and 16 angstrom for systems considered here, suggesting that this interaction is negligibly small at the larger distances where it reaches its asymptotic power-law decay.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 563, "Times Cited, All Databases": 618, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2016, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41005, "DOI": "10.1103/PhysRevX.6.041005", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.6.041005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385640600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lan, CJ; Xu, J; Qiao, Y; Ma, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lan, Chuanjin; Xu, Jian; Qiao, Yu; Ma, Yanbao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal management for high power lithium-ion battery by minichannel aluminum tubes", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries are widely used for battery electric (all-electric) vehicles (BEV) and hybrid electric vehicles (HEV) due to their high energy and power density. An battery thermal management system (BTMS) is crucial for the performance, lifetime, and safety of lithium-ion batteries. In this paper, a novel design of BTMS based on aluminum minichannel tubes is developed and applied on a single prismatic Li-ion cell under different discharge rates. Parametric studies are conducted to investigate the performance of the BTMS using different flow rates and configurations. With minichannel cooling, the maximum cell temperature at a discharge rate of 1C is less than 27.8 degrees C, and the temperature difference across the cell is less than 0.80 degrees C using flow rate at 0.20 L/min, at the expense of 8.69e-6 W pumping power. At higher discharge rates, e.g., 1.5C and 2C, higher flow rates are required to maintain the same temperature rise and temperature difference. The flow rate needed is 0.8 L/min for 1.5C and 2.0 L/min for 2C, while the required pumping power is 4.23e-4 W and 5.27e-3 W, respectively. The uniform temperature distribution (<1 degrees C) inside the single cell and efficient pumping power demonstrate that the minichannel cooling system provides a promising solution for the BTMS. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 25", "Publication Year": 2016, "Volume": 101, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": 292, "Article Number": null, "DOI": "10.1016/j.applthermaleng.2016.02.070", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2016.02.070", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379636500029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Coles, RJ; Price, DM; Dixon, JE; Royall, B; Clarke, E; Kok, P; Skolnick, MS; Fox, AM; Makhonin, MN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Coles, R. J.; Price, D. M.; Dixon, J. E.; Royall, B.; Clarke, E.; Kok, P.; Skolnick, M. S.; Fox, A. M.; Makhonin, M. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chirality of nullophotonic waveguide with embedded quantum emitter for unidirectional spin transfer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalable quantum technologies may be achieved by faithful conversion between matter qubits and photonic qubits in integrated circuit geometries. Within this context, quantum dots possess well-defined spin states (matter qubits), which couple efficiently to photons. By embedding them in nullophotonic waveguides, they provide a promising platform for quantum technology implementations. In this paper, we demonstrate that the naturally occurring electromagnetic field chirality that arises in nullobeam waveguides leads to unidirectional photon emission from quantum dot spin states, with resultant in-plane transfer of matter-qubit information. The chiral behaviour occurs despite the non-chiral geometry and material of the waveguides. Using dot registration techniques, we achieve a quantum emitter deterministically positioned at a chiral point and realize spin-path conversion by design. We further show that the chiral phenomena are much more tolerant to dot position than in standard photonic crystal waveguides, exhibit spin-path readout up to 95 +/- 5% and have potential to serve as the basis of spin-logic and network implementations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11183, "DOI": "10.1038/ncomms11183", "DOI Link": "http://dx.doi.org/10.1038/ncomms11183", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373294500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roy, B; Juricic, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roy, Bitan; Juricic, Vladimir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional superconductivity in nearly flat bands in twisted bilayer graphene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flat electronic bands can accommodate a plethora of interaction-driven quantum phases, since kinetic energy is quenched therein and electronic interactions therefore prevail. Twisted bilayer graphene, near the so-called magic angles, features slow Dirac fermions close to the charge-neutrality point that persist up to high energies. Starting from a continuum model of slow but strongly interacting Dirac fermions, we show that with increasing chemical doping away from the charge-neutrality point, a time-reversal symmetry breaking, valley pseudospin-triplet, topological p + ip superconductor gradually sets in, when the system resides at the brink of an antiferromagnetic ordering (due to Hubbard repulsion), in qualitative agreement with recent experimental findings. The p ip paired state exhibits quantized spin and thermal Hall conductivities, and polar Kerr and Faraday rotations. Our conclusions should also be applicable for other correlated two-dimensional Dirac materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2019, "Volume": 99, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121407, "DOI": "10.1103/PhysRevB.99.121407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.99.121407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461962900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Malode, SJ; Shanbhag, MM; Kumari, R; Dkhar, DS; Chandra, P; Shetti, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Malode, Shweta J.; Shanbhag, Mahesh M.; Kumari, Rohini; Dkhar, Daphika S.; Chandra, Pranjal; Shetti, Nagaraj P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass-derived carbon nullomaterials for sensor applications", "Source Title": "JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, an increasing amount of attention has been paid to utilizing dedicated waste biomass as a sustainable, cheap, and abundant fuel and material source. There is a tremendous opportunity for maximizing energy production by applying different reliable waste biomass as a renewable, affordable, and excellent resource. As a result of renewable hydrocarbons such as biomass, bioenergy is produced, green chemicals are manufactured, and carbon materials are made. Furthermore, biomass can be utilized as a source of advanced carbon materials. Carbon materials derived from biomass can also be used to support catalysts in fuel cells with polymer electrolyte membranes. For the fabrication of electrochemical sensors, porous carbonaceous materials generated from biomass are highly advised owing to their specific qualities, including regenerative nature, affordability, distinctive structure, and sustainability. The surface morphology of the sensor, especially its pore volume, surface area, and pore size affects both its electrochemical and catalytic activity. Metal nulloparticle activation, doping, and dispersion are just a few of the methods that may be used to improve the performance of sensors. To detect a variety of target analytes, such as biomolecules, metal ions, contaminullts, food additives, and flavonoids, some of the key or seminal advances in the field of biomass-derived carbonaceous compounds are discussed. The materials and composites made of biomass-derived carbon will be in-depth examined, evaluated, and compared in this review. The associated technological difficulties are also discussed, and future research areas are suggested for use in practical applications. nullo carbon materials have several integrated advantages, including good electrical conductivity, structural and chemical flexibility, reduced chemical functionalization, and bulk production potential, making them viable candidates for various electrochemical processes. In the coming years, bio-carbon production from waste biomass is expected to gain rapid scientific and industrial interest because it will be used in electrochemical devices and rechargeable batteries. We emphasize the variety of waste biomass precursors that are accessible, as well as the recent developments in the manufacture of bio-carbon. Carbonaceous nulloparticles generated from biomass have shown potential for use in fuel cells, bioimaging, medicinal delivery, carbon fixation, catalysis, and gas sensors. Interestingly, this article has covered these nullomaterials' new and innovative energy conversion and storage services. Finally, the remaining difficulties, perspective views, and potential research trajectories in the area are described.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 222, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115102, "DOI": "10.1016/j.jpba.2022.115102", "DOI Link": "http://dx.doi.org/10.1016/j.jpba.2022.115102", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000878807300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XM; Dong, QB; Li, F; Zhu, QH; Tian, QY; Tian, L; Zhu, YY; Pan, B; Padervand, M; Wang, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ximing; Dong, Qibing; Li, Fei; Zhu, Qiuhui; Tian, Qingyun; Tian, Lin; Zhu, Yiyin; Pan, Bao; Padervand, Mohsen; Wang, Chuanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defective Bi@BiOBr/C microrods derived from Bi-MOF for efficient photocatalytic NO abatement: Directional regulation of interfacial charge transfer via carbon-loading", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The implementation of precisely directional electron transfer at the interface of catalysts is still considered a huge challenge. Herein, hierarchical Bi@BiOBr/C microrods derived from a novel Bi-MOF were employed as a model to precisely construct the atomic-level interface electrons transfer channels via carbon-bismuth bonding. The optimized Bi@BiOBr/C with plasmonic Bi and oxygen vacancies exhibited a photocatalytic removal efficiency of 69.5 % for ppb-level atmospheric NO, which is 3.5 times higher than that of pure BiOBr (19.8 %). The enhanced photocatalytic performance is owing to precisely constructed electron transport channels with loaded graphitic carbon as a bridge (i.e., BiOBr -> graphitic carbon -> Bi nulloparticles). Further DFT calculations demonstrated the built-in graphitic carbon reconstructs an Ohmic contact with BiOBr and eliminates the Schottky barrier between BiOBr and Bi nulloparticles, enhancing the photoelectron transfer efficiency. This research represents an exciting case for the modulation of photoelectron transfer at the catalysts interface for air purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 340, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123238, "DOI": "10.1016/j.apcatb.2023.123238", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2023.123238", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076231400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YF; Shen, ZY; Huo, JJ; Cao, XJ; Ou, PF; Qu, JP; Nie, XM; Zhang, JQ; Wu, MH; Wang, GX; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yufei; Shen, Ziyan; Huo, Juanjuan; Cao, Xianjun; Ou, Pengfei; Qu, Junpeng; Nie, Xinming; Zhang, Jinqiang; Wu, Minghong; Wang, Guoxiu; Liu, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Epoxy-rich Fe Single Atom Sites Boost Oxygen Reduction Electrocatalysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysts for highly efficient oxygen reduction reaction (ORR) are crucial for energy conversion and storage devices. Single-atom catalysts with maximized metal utilization and altered electronic structure are the most promising alternatives to replace current benchmark precious metals. However, the atomic level understanding of the functional role for each species at the anchoring sites is still unclear and poorly elucidated. Herein, we report Fe single atom catalysts with the sulfur and oxygen functional groups near the atomically dispersed metal centers (Fe1/NSOC) for highly efficient ORR. The Fe1/NSOC delivers a half-wave potential of 0.92 V vs. RHE, which is much better than those of commercial Pt/C (0.88 V), Fe single atoms on N-doped carbon (Fe1/NC, 0.89 V) and most reported nonprecious metal catalysts. The spectroscopic measurements reveal that the presence of sulfur group induces the formation of epoxy groups near the FeN4S2 centers, which not only modulate the electronic structure of Fe single atoms but also participate the catalytic process to improve the kinetics. The density functional theory calculations demonstrate the existence of sulfur and epoxy group engineer the charges of Fe reactive center and facilitate the reductive release of OH* (rate-limiting step), thus boosting the overall oxygen reduction efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2023, "Volume": 62, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202308349", "DOI Link": "http://dx.doi.org/10.1002/anie.202308349", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037273600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, SY; He, C; Wang, Z; Liu, FK; Sun, XC; Li, Z; Lu, HZ; Lu, MH; Liu, XP; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Si-Yuan; He, Cheng; Wang, Zhen; Liu, Fu-Kang; Sun, Xiao-Chen; Li, Zheng; Lu, Hai-Zhou; Lu, Ming-Hui; Liu, Xiao-Ping; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic pseudospin transport for integratable topological phononic circuits", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Precise control of solid-state elastic waves' mode content and coherence is of great use nowadays in reinforcing mechanical energy harvesting/storage, nondestructive material testing, wave-matter interaction, high sensitivity sensing, and information processing, etc. Its efficacy is highly dependent on having elastic transmission channels with lower loss and higher degree of freedom. Here, we demonstrate experimentally an elastic analog of the quantum spin Hall effects in a monolithically scalable configuration, which opens up a route in manipulating elastic waves represented by elastic pseudospins with spin-momentum locking. Their unique features including robustness and negligible propagation loss may enhance elastic planar-integrated circuit-level and system-level performance. Our approach promotes topological materials that can interact with solid-state phonons in both static and timedependent regimes. It thus can be immediately applied to multifarious chip-scale topological phononic devices, such as path-arbitrary elastic wave-guiding, elastic splitters and elastic resonators with high-quality factors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 6", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3072, "DOI": "10.1038/s41467-018-05461-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05461-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000440777000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Lee, KS; Kim, S; Yoon, K; Han, S; Lee, MH; Ko, Y; Noh, JH; Kim, W; Kang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Sunyoung; Lee, Kyeong-Su; Kim, Sewon; Yoon, Kyungho; Han, Sangwook; Lee, Myeong Hwan; Ko, Youngmin; Noh, Joo Hyeon; Kim, Wonju; Kang, Kisuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of a lithiophilic and electron-blocking interlayer for dendrite-free lithium-metal solid-state batteries", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state batteries are a potential game changer in the energy storage market; however, their practical employment has been hampered by premature short circuits caused by the lithium dendritic growth through the solid electrolyte. Here, we demonstrate that a rational layer-by-layer strategy using a lithiophilic and electron-blocking multilayer can substantially enhance the performance/stability of the system by effectively blocking the electron leakage and maintaining low electronic conductivity even at high temperature (60 degrees C) or under high electric field (3 V) while sustaining low interfacial resistance (13.4 ohm cm(2)). It subsequently results in a homogeneous lithium plating/stripping, thereby aiding in achieving one of the highest critical current densities (similar to 3.1 mA cm(-2)) at 60 degrees C in a symmetric cell. A full cell paired with a commercial-level cathode exhibits exceptionally long durability (>3000 cycles) and coulombic efficiency (99.96%) at a high current density (2 C; similar to 1.0 mA cm(-2)), which records the highest performance among all-solid-state lithium metal batteries reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 29", "Publication Year": 2022, "Volume": 8, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabq0153", "DOI": "10.1126/sciadv.abq0153", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abq0153", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000836554300036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, F; Luo, SS; Ortiz, BR; Chen, Y; Duan, WY; Zhang, DT; Lu, X; Wilson, SD; Song, Y; Yuan, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Feng; Luo, Shuaishuai; Ortiz, Brenden R.; Chen, Ye; Duan, Weiyin; Zhang, Dongting; Lu, Xin; Wilson, Stephen D.; Song, Yu; Yuan, Huiqiu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-induced double superconducting domes and charge instability in the kagome metal KV3Sb5", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The kagome metal KV3Sb5 hosts charge order, topologically nontrivial Dirac band crossings, and a super-conducting ground state with unconventional characteristics, providing an ideal platform to investigate the interplay between different electronic states on the kagome lattice. Here we study the evolution of charge order and superconductivity in KV3Sb5 under hydrostatic pressure using electrical resistivity measurements. With the application of pressure, the superconducting transition temperature T-c = 0.9 K under ambient pressure quickly increases to 3.1 K at p = 0.4 GPa, as charge order progressively weakens. Upon further increasing pressure, signatures of charge order disappear at p(c1) approximate to 0.5 GPa and Tc is gradually suppressed, forming a superconducting dome that terminates at p approximate to 10 GPa. Beyond p approximate to 10 GPa, a second superconducting dome emerges with maximum T-c approximate to 1.0 K at p(c2) approximate to 22 GPa, which becomes fully suppressed at p approximate to 28 GPa. The suppression of superconductivity for the second superconducting dome is associated with the appearance of a unique high-pressure phase, possibly a distinct charge order.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2021, "Volume": 103, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "L220504", "DOI": "10.1103/PhysRevB.103.L220504", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.103.L220504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665118600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Acharjee, SA; Bharali, P; Gogoi, B; Sorhie, V; Walling, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Acharjee, Shiva Aley; Bharali, Pranjal; Gogoi, Bhagyudoy; Sorhie, Viphrezolie; Walling, Bendangtula", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PHA-Based Bioplastic: a Potential Alternative to Address Microplastic Pollution", "Source Title": "WATER AIR AND SOIL POLLUTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Petroleum-derived plastics are linked to a variety of growing environmental issues throughout their lifecycle, including emission of greenhouse gases, accumulation in terrestrial and marine habitats, pollution, among others. There has been a lot of attention over the last decade in industrial and research communities in developing and producing eco-friendly polymers to deal with the current environmental issues. Bioplastics preferably are a fast-developing family of polymeric substances that are frequently promoted as substitutes to petroleum-derived plastics. Polyhydroxyalkanoates (PHAs) have a number of appealing properties that make PHAs a feasible source material for bioplastics, either as a direct replacement of petroleum-derived plastics or as a blend with elements derived from natural origin, fabricated biodegradable polymers, and/or non-biodegradable polymers. Among the most promising PHAs, polyhydroxybutyrates (PHBs) are the most well-known and have a significant potential to replace traditional plastics. These biodegradable plastics decompose faster after decomposing into carbon dioxide, water, and inorganic chemicals. Bioplastics have been extensively utilized in several sectors such as food-processing industry, medical, agriculture, automobile industry, etc. However, it is also associated with disadvantages like high cost, uneconomic feasibility, brittleness, and hydrophilic nature. A variety of tactics have been explored to improve the qualities of bioplastics, with the most prevalent being the development of gas and water barrier properties. The prime objective of this study is to review the current knowledge on PHAs and provide a brief introduction to PHAs, which have drawn attention as a possible potential alternative to conventional plastics due to their biological origin, biocompatibility, and biodegradability, thereby reducing the negative impact of microplastics in the environment. This review may help trigger further scientific interest to thoroughly research on PHAs as a sustainable option to greener bioplastics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 234, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21, "DOI": "10.1007/s11270-022-06029-2", "DOI Link": "http://dx.doi.org/10.1007/s11270-022-06029-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000905898000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shih, CY; Streubel, R; Heberle, J; Letzel, A; Shugaev, MV; Wu, CP; Schmidt, M; Gökce, B; Barcikowski, S; Zhigilei, LV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shih, Cheng-Yu; Streubel, Rene; Heberle, Johannes; Letzel, Alexander; Shugaev, Maxim V.; Wu, Chengping; Schmidt, Michael; Goekce, Bilal; Barcikowski, Stephan; Zhigilei, Leonid V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two mechanisms of nulloparticle generation in picosecond laser ablation in liquids: the origin of the bimodal size distribution", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The synthesis of chemically clean and environmentally friendly nulloparticles through pulsed laser ablation in liquids has shown a number of advantages over conventional chemical synthesis methods and has evolved into a thriving research field attracting laboratory and industrial applications. The fundamental understanding of processes leading to the nulloparticle generation, however, still remains elusive. In particular, the origin of bimodal nulloparticle size distributions in femto- and picosecond laser ablation in liquids, where small nulloparticles (several nullometers) with narrow size distribution are commonly observed to coexist with larger (tens to hundreds of nullometers) ones, has not been explained so far. In this paper, joint computational and experimental efforts are applied to understand the mechanisms of nulloparticle formation in picosecond laser ablation in liquids and to explain the bimodal nulloparticle size distributions. The results of a large-scale atomistic simulation reveal the critical role of the dynamic interaction between the ablation plume and the liquid environment, leading to the generation of large nulloparticles through a sequence of hydrodynamic instabilities at the plume-liquid interface and a concurrent nucleation and growth of small nulloparticles in an expanding metal-liquid mixing region. The computational predictions are supported by a series of stroboscopic videography experiments showing the emergence of small satellite bubbles surrounding the main cavitation bubble generated in single pulse experiments. Carefully timed double pulse irradiation triggers expansion of secondary cavitation bubbles indicating, in accord with the simulation results, the presence of localized sites of laser energy deposition (possibly large nulloparticles) injected into the liquid at the early stage of the bubble formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2018, "Volume": 10, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6900, "End Page": 6910, "Article Number": null, "DOI": "10.1039/c7nr08614h", "DOI Link": "http://dx.doi.org/10.1039/c7nr08614h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430537200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuo, HH; Chu, JH; Palmstrom, JC; Kivelson, SA; Fisher, IR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuo, Hsueh-Hui; Chu, Jiun-Haw; Palmstrom, Johanna C.; Kivelson, Steven A.; Fisher, Ian R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ubiquitous signatures of nematic quantum criticality in optimally doped Fe-based superconductors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A key actor in the conventional theory of superconductivity is the induced interaction between electrons mediated by the exchange of virtual collective fluctuations (phonons in the case of conventional s-wave superconductors). Other collective modes that can play the same role, especially spin fluctuations, have been widely discussed in the context of high-temperature and heavy Fermion superconductors. The strength of such collective fluctuations is measured by the associated susceptibility. Here we use differential elastoresistance measurements from five optimally doped iron-based superconductors to show that divergent nematic susceptibility appears to be a generic feature in the optimal doping regime of these materials. This observation motivates consideration of the effects of nematic fluctuations on the superconducting pairing interaction in this family of compounds and possibly beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2016, "Volume": 352, "Issue": 6288, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 958, "End Page": 962, "Article Number": null, "DOI": "10.1126/science.aab0103", "DOI Link": "http://dx.doi.org/10.1126/science.aab0103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376147800040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Hu, LY; Zhao, M; Dai, LY; Hrynsphan, D; Tatsiana, S; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zeyu; Hu, Liyong; Zhao, Min; Dai, Luyao; Hrynsphan, Dzmitry; Tatsiana, Savitskaya; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bamboo charcoal fused with polyurethane foam for efficiently removing organic solvents from wastewater: experimental and simulation", "Source Title": "BIOCHAR", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of a multifunctional oil adsorbing material which could effectively and quickly separate oily wastewater is one of the focuses in water environment restoration. In this study, bamboo charcoal (BC) was used as an improver to modify polyurethane (PU) foam. The results of scanning electron microscope (SEM) and Fourier-transform infrared spectroscopy (FTIR) revealed that the addition of BC could effectively improve the mechanical properties of PU. The adsorption data exhibited that the BC-loaded PU (BC/PU) foam composites effectively removed seven organic solvents (OSs, including octane, petroleum ether, soybean oil, chlorobenzene, 1,2-dichloroethane, n-hexane, cyclohexane), and the maximum adsorption capacity of BC/PU was 23.6 g g(-1) when BC content was 5%. The order of pseudo-second-order kinetic constants and maximum adsorption capacity of seven OS s was octane < petroleum ether < soybean oil < chlorobenzene < 1, 2-dichloroethane < cyclohexane < n- hexane. Based on the experimental data and density functional theory (DFT) simulation, the adsorption mechanism of OSs on BC/PU-5 was discussed. The E-HOMO and mu of OSs calculated by DFT were highly correlated with absorption affinity (K-2, Q(e) and Q(max)). Hence, the contribution of OSs to the adsorption efficiency of BC/PU-5 may be mainly due to electron donor-acceptor (EDA) interaction and non-hydrophobic interaction. In addition, the adsorption capacity did not change significantly after repeated recycling 5 times. Overall, the prepared BC/PU foam composites could be used as a potential candidate for separating OSs in engineering applications. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28, "DOI": "10.1007/s42773-022-00153-2", "DOI Link": "http://dx.doi.org/10.1007/s42773-022-00153-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799815400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hertwich, EG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hertwich, Edgar G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Increased carbon footprint of materials production driven by rise in investments", "Source Title": "NATURE GEOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The production of materials is an important source of greenhouse gas emissions. To reduce emissions, policies aim to enhance material efficiency and the circular economy, but our understanding of the dynamics of material-related greenhouse gas emissions is limited. Here, I quantify the greenhouse gas emissions from material production and the carbon footprint of materials in industries that are the first users of materials, and in final consumption, using a multiregional input-output model of the global economy and the hypothetical extraction method. From 1995 to 2015, greenhouse gas emissions from just material production increased by 120%, with 11 billion tons of CO2-equivalent emitted in 2015. As a proportion of global emissions, material production rose from 15 to 23%. China accounted for 75% of the growth. In terms of the first use of materials, two-fifths of the carbon footprint of materials is attributed to construction, and two-fifths to the manufacturing of machinery, vehicles and other durable products. Overall, the replacement of existing or formation of new capital stocks now accounts for 60% of material-related emissions. Policies that address the rapidly growing capital stocks in emerging economies therefore offer the best prospect for emission reductions from material efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 151, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41561-021-00690-8", "DOI Link": "http://dx.doi.org/10.1038/s41561-021-00690-8", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618174200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, L; Shrestha, S; Taylor, N; Nie, WY; Cao, LR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Lei; Shrestha, Shreetu; Taylor, Neil; Nie, Wanyi; Cao, Lei R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Determination of X-ray detection limit and applications in perovskite X-ray detectors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-ray detection limit and sensitivity are important figure of merits for perovskite X-ray detectors, but literatures lack a valid mathematic expression for determining the lower limit of detection for a perovskite X-ray detector. In this work, we present a thorough analysis and new method for X-ray detection limit determination based on a statistical model that correlates the dark current and the X-ray induced photocurrent with the detection limit. The detection limit can be calculated through the measurement of dark current and sensitivity with an easy-to-follow practice. Alternatively, the detection limit may also be obtained by the measurement of dark current and photocurrent when repeatedly lowering the X-ray dose rate. While the material quality is critical, we show that the device architecture and working mode also have a significant influence on the sensitivity and the detection limit. Our work establishes a fair comparison metrics for material and detector development. The limit of X-ray detection is an important figure of merit for X-ray detectors, yet the suitability of method adopted from Currie's 1968 paper and the following international standard is in doubt. Here, the authors propose a statistical model that correlates dark current and photo-current, show how it can be used to determine detection limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 6", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5258, "DOI": "10.1038/s41467-021-25648-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25648-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000694666900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gupta, B; Kumar, N; Panda, K; Kanull, V; Joshi, S; Visoly-Fisher, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gupta, Bhavana; Kumar, Niranjan; Panda, Kalpataru; Kanull, Vigneshwaran; Joshi, Shailesh; Visoly-Fisher, Iris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of oxygen functional groups in reduced graphene oxide for lubrication", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Functionalized and fully characterized graphene-based lubricant additives are potential 2D materials for energy-efficient tribological applications in machine elements, especially at macroscopic contacts. Two different reduced graphene oxide (rGO) derivatives, terminated by hydroxyl and epoxy-hydroxyl groups, were prepared and blended with two different molecular weights of polyethylene glycol (PEG) for tribological investigation. Epoxy-hydroxyl-terminated rGO dispersed in PEG showed significantly smaller values of the friction coefficient. In this condition, PEG chains intercalate between the functionalized graphene sheets, and shear can take place between the PEG and rGO sheets. However, the friction coefficient was unaffected when hydroxyl-terminated rGO was coupled with PEG. This can be explained by the strong coupling between graphene sheets through hydroxyl units, causing the interaction of PEG with the rGO to be non-effective for lubrication. On the other hand, antiwear properties of hydroxyl-terminated rGO were significantly enhanced compared to epoxy-hydroxyl functionalized rGO due to the integrity of graphene sheet clusters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45030, "DOI": "10.1038/srep45030", "DOI Link": "http://dx.doi.org/10.1038/srep45030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397723100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, BC; Wang, DY; Hong, T; Wang, YP; Liu, DR; Wang, ZY; Gao, X; Ge, ZH; Zhao, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Bingchao; Wang, Dongyang; Hong, Tao; Wang, Yuping; Liu, Dongrui; Wang, Ziyuan; Gao, Xiang; Ge, Zhen-Hua; Zhao, Li-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High thermoelectric efficiency realized in SnSe crystals via structural modulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystalline thermoelectrics have been developed to be potential candidates for power generation and electronic cooling, among which SnSe crystals are becoming the most representative. Herein, we realize high-performance SnSe crystals with promising efficiency through a structural modulation strategy. By alloying strontium at Sn sites, we modify the crystal structure and facilitate the multiband synglisis in p-type SnSe, favoring the optimization of interactive parameters mu and m(*). Resultantly, we obtain a significantly enhanced PF similar to 85 mu W cm(-1) K-2, with an ultrahigh ZT similar to 1.4 at 300K and ZT(ave) similar to 2.0 among 300-673K. Moreover, the excellent properties lead to single-leg device efficiency of similar to 8.9% under a temperature difference Delta T similar to 300K, showing superiority among the current low- to mid-temperature thermoelectrics, with an enhanced cooling Delta T-max of similar to 50.4K in the 7-pair thermoelectric device. Our study further advances p-type SnSe crystals for practical waste heat recovery and electronic cooling. Thermoelectric technology directly enables both power generation and electronic cooling. Here, the authors realize high-performance SnSe crystals with promising device efficiencies by modulating crystal and band structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1366, "DOI": "10.1038/s41467-023-37114-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37114-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001029839500034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rabbat, C; Awad, S; Villot, A; Rollet, D; Andrès, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rabbat, Christelle; Awad, Sary; Villot, Audrey; Rollet, Delphine; Andres, Yves", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainability of biomass-based insulation materials in buildings: Current status in France, end-of-life projections and energy recovery potentials", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concerns over climate change have driven the decarbonization of the building sector, the largest energy consumer in France. This consumption is primarily dedicated to heating and cooling. Thermal insulation in construction plays an important role in the minimization of operational energy consumption. Currently, insulation is performed via mineral and fossil-derived materials, which require high manufacturing energy. For this reason, attention has been paid to finding clean and energy-efficient alternatives. Subsequently, biomass-based insulation materials have been identified as low-embodied energy materials that reduce energy use and greenhouse gas emissions. These green and sustainable insulation materials fall in line with the transition in France towards low-carbon and positive-energy buildings. In this respect, research works have mostly focused on renewable biomass resources and wastes, the design and production of insulation materials, the testing of their properties and their installation in buildings; however, few articles have reviewed their durability and end-of-life management. To fit more in the circular bioeconomy concept, light has been shed in this review on the end-of-life of these biomaterials to avoid their landfilling. Therefore, this review provides a state-of-the-art of the different biobased building products commercialized in France, with a forecast of their volumes and waste deposits by 2050. Furthermore, this study explores waste management strategies, focusing on waste-to-energy routes, which are revealed to be the most promising. The energy recovery from bio-based insulation wastes expected in 2050 saves 4.1 million m(3) of land, 75,000 tons of fossil fuels and 89 million euros while avoiding the rejection of 312,771 t(CO2eq).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 156, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111962, "DOI": "10.1016/j.rser.2021.111962", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2021.111962", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786621800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, XF; Zhai, R; Lin, JJ; Wang, ZF; Meng, DK; Li, M; Mao, YL; Gao, BY; Ma, HY; Zhang, BF; Sun, Y; Li, S; Zhou, CG; Lin, YCJ; Wang, JP; Chiang, VL; Li, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Xiufang; Zhai, Rui; Lin, Jiaojiao; Wang, Zhifeng; Meng, Dekai; Li, Meng; Mao, Yuli; Gao, Boyuan; Ma, Hongyan; Zhang, Baofeng; Sun, Yi; Li, Shuang; Zhou, Chenguang; Lin, Ying-Chung Jimmy; Wang, Jack P. P.; Chiang, Vincent L. L.; Li, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cell-type-specific PtrWOX4a and PtrVCS2 form a regulatory nexus with a histone modification system for stem cambium development in Populus trichocarpa", "Source Title": "NATURE PLANTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stem vascular cambium cells in forest trees produce wood for materials and energy. WOX4 affects the proliferation of such cells in Populus. Here we show that PtrWOX4a is the most highly expressed stem vascular-cambium-specific (VCS) gene in P. trichocarpa, and its expression is controlled by the product of the second most highly expressed VCS gene, PtrVCS2, encoding a zinc finger protein. PtrVCS2 binds to the PtrWOX4a promoter as part of a PtrWOX13a-PtrVCS2-PtrGCN5-1-PtrADA2b-3 protein tetramer. PtrVCS2 prevented the interaction between PtrGCN5-1 and PtrADA2b-3, resulting in H3K9, H3K14 and H3K27 hypoacetylation at the PtrWOX4a promoter, which led to fewer cambium cell layers. These effects on cambium cell proliferation were consistent across more than 20 sets of transgenic lines overexpressing individual genes, gene-edited mutants and RNA interference lines in P. trichocarpa. We propose that the tetramer-PtrWOX4a system may coordinate genetic and epigenetic regulation to maintain normal vascular cambium development for wood formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 37, "Times Cited, All Databases": 44, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 96, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41477-022-01315-7", "DOI Link": "http://dx.doi.org/10.1038/s41477-022-01315-7", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Plant Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909780400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Ye, WJ; Xu, RZ; Sun, Y; Feng, J; Sareh, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yao; Ye, Wangjie; Xu, Ruizhi; Sun, Yue; Feng, Jian; Sareh, Pooya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A programmable auxetic metamaterial with tunable crystal symmetry", "Source Title": "INTERNATIONAL JOURNAL OF MECHANICAL SCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificially-structured materials with negative Poisson's ratio, also known as auxetics, have been the focus of numerous studies over the past few decades. In this paper, using a group-theory-based symmetry reduction approach, and based on a structure composed of rotating rigid triangles, we propose a new approach to designing auxetic metamaterials. These metamaterials can be fabricated by using a variety of active or smart structural members that undergo different deformations when subjected to external stimulations, e.g. by using temperature-sensitive members in a temperature-changing environment. Then, by applying controlled stimuli to the initial structure, we obtain desired symmetry-reduced structural configurations which facilitate the programmability of Poisson's ratio. In particular, to demonstrate this programmable metamaterial design approach, starting with an auxetic metamaterial with an initial C3v symmetry, we apply an external stimulus to reduce the symmetry of the initial structural configuration. The deformed configurations, which belong to the symmetry groups C3, CS, and C1, enable us to program the Poisson's ratio of the metamaterial. We derive theoretical expressions for the Poisson's ratio associated with different symmetries, which are subsequently verified by numerical studies and proof-of-concept Kirigami models. We anticipate that this approach to designing programmable structures will open up new avenues of research in metamaterial design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2023, "Volume": 249, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108249, "DOI": "10.1016/j.ijmecsci.2023.108249", "DOI Link": "http://dx.doi.org/10.1016/j.ijmecsci.2023.108249", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950281900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sabella, S; Carney, RP; Brunetti, V; Malvindi, MA; Al-Juffali, N; Vecchio, G; Janes, SM; Bakr, OM; Cingolani, R; Stellacci, F; Pompa, PP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sabella, Stefania; Carney, Randy P.; Brunetti, Virgilio; Malvindi, Maria Ada; Al-Juffali, Noura; Vecchio, Giuseppe; Janes, Sam M.; Bakr, Osman M.; Cingolani, Roberto; Stellacci, Francesco; Pompa, Pier Paolo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general mechanism for intracellular toxicity of metal-containing nulloparticles", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The assessment of the risks exerted by nulloparticles is a key challenge for academic, industrial, and regulatory communities worldwide. Experimental evidence points towards significant toxicity for a range of nulloparticles both in vitro and in vivo. Worldwide efforts aim at uncovering the underlying mechanisms for this toxicity. Here, we show that the intracellular ion release elicited by the acidic conditions of the lysosomal cellular compartment - where particles are abundantly internalized - is responsible for the cascading events associated with nulloparticles-induced intracellular toxicity. We call this mechanism a lysosome-enhanced Trojan horse effect since, in the case of nulloparticles, the protective cellular machinery designed to degrade foreign objects is actually responsible for their toxicity. To test our hypothesis, we compare the toxicity of similar gold particles whose main difference is in the internalization pathways. We show that particles known to pass directly through cell membranes become more toxic when modified so as to be mostly internalized by endocytosis. Furthermore, using experiments with chelating and lysosomotropic agents, we found that the toxicity mechanism for different metal containing NPs (such as metallic, metal oxide, and semiconductor NPs) is mainly associated with the release of the corresponding toxic ions. Finally, we show that particles unable to release toxic ions (such as stably coated NPs, or diamond and silica NPs) are not harmful to intracellular environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 6, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7052, "End Page": 7061, "Article Number": null, "DOI": "10.1039/c4nr01234h", "DOI Link": "http://dx.doi.org/10.1039/c4nr01234h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000337143900101", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shih, AJ; Monteiro, MCO; Dattila, F; Pavesi, D; Philips, M; da Silva, AHM; Vos, RE; Ojha, K; Park, S; van der Heijden, O; Marcandalli, G; Goyal, A; Villalba, M; Chen, XT; Gunasooriya, GTKK; McCrum, I; Mom, R; López, N; Koper, MTM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shih, Arthur J.; Monteiro, Mariana C. O.; Dattila, Federico; Pavesi, Davide; Philips, Matthew; da Silva, Alisson H. M.; Vos, Rafael E.; Ojha, Kasinath; Park, Sunghak; van der Heijden, Onno; Marcandalli, Giulia; Goyal, Akansha; Villalba, Matias; Chen, Xiaoting; Gunasooriya, G. T. Kasun Kalhara; McCrum, Ian; Mom, Rik; Lopez, Nuria; Koper, Marc T. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water electrolysis", "Source Title": "NATURE REVIEWS METHODS PRIMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemistry has the potential to sustainably transform molecules with electrons supplied by renewable electricity. It is one of many solutions towards a more circular, sustainable and equitable society. To achieve this, collaboration between industry and research laboratories is a must. Atomistic understanding from fundamental experiments and modelling can be used to engineer optimized systems whereas limitations set by the scaled-up technology can direct the systems studied in the research laboratory. In this Primer, best practices to run clean laboratory-scale electrochemical systems and tips for the analysis of electrochemical data to improve accuracy and reproducibility are introduced. How characterization and modelling are indispensable in providing routes to garner further insights into atomistic and mechanistic details is discussed. Finally, important considerations regarding material and cell design for scaling up water electrolysis are highlighted and the role of hydrogen in our society's energy transition is discussed. The future of electrochemistry is bright and major breakthroughs will come with rigour and improvements in the collection, analysis, benchmarking and reporting of electrochemical water splitting data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2022, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 84, "DOI": "10.1038/s43586-022-00164-0", "DOI Link": "http://dx.doi.org/10.1038/s43586-022-00164-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000889015800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Würfel, U; Neher, D; Spies, A; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wuerfel, Uli; Neher, Dieter; Spies, Annika; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of charge transport on current-voltage characteristics and power-conversion efficiency of organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work elucidates the impact of charge transport on the photovoltaic properties of organic solar cells. Here we show that the analysis of current-voltage curves of organic solar cells under illumination with the Shockley equation results in values for ideality factor, photo-current and parallel resistance, which lack physical meaning. Drift-diffusion simulations for a wide range of charge-carrier mobilities and illumination intensities reveal significant carrier accumulation caused by poor transport properties, which is not included in the Shockley equation. As a consequence, the separation of the quasi Fermi levels in the organic photoactive layer (internal voltage) differs substantially from the external voltage for almost all conditions. We present a new analytical model, which considers carrier transport explicitly. The model shows excellent agreement with full drift-diffusion simulations over a wide range of mobilities and illumination intensities, making it suitable for realistic efficiency predictions for organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6951, "DOI": "10.1038/ncomms7951", "DOI Link": "http://dx.doi.org/10.1038/ncomms7951", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Islam, A; Teo, SH; Awual, MR; Taufiq-Yap, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Islam, Aminul; Teo, Siow Hwa; Awual, Md. Rabiul; Taufiq-Yap, Yun Hin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assessment of clean H2 energy production from water using novel silicon photocatalyst", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullosheets of silicon have attracted a great deal of attention due to its tunable optical and electronic properties. However, the development of facile and easily scalable synthesis process has remained a great contest. Endeavor has been made in this research to find a waste inferred effective photocatalyst to deliver hydrogen (H-2) through visible light responsive water splitting. One-pot solid phase reaction was applied to synthesis catalyst and adopted ultrathin structure. The photocatalytic efficiency of catalyst was examined by XRD, XPS, and UV-VIS absorption spectra, PL, FESEM, HRTEM and EDX. The HRTEM and FESEM images revealed the interconnected nullosheets with Si having the average thickness of 5 nm and their band gaps were 2.3-2.5 eV corresponding to the absorption of visible light range. The H-2 production rate on photocatalyst was originated to 3200 mu mol h(-1) without utilizing any conciliatory electron givers, voltage or pH alteration, which beats the Pt, Ru, Rh, Pd and Au stacked photocatalyst ever detailed up until this point. The significant increase in photocatalytic activity could be the fast charge migration and separation from the silicon-hydrogen and silicon-hydroxyl bonds on Si surface and facilitation of charge separation could results from the multiple reflections of visible light on ultrathin nullosheets. It has been confirmed that the electron/hole recombination rate in ultrathin nullosheets of Si declined due to the oxidation of Si surface. It would be presumed that the approach of surface chemistry of silicon could not be limited towards the photocatalytic water splitting and could be applicable to remedy water pollution. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2020, "Volume": 244, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118805, "DOI": "10.1016/j.jclepro.2019.118805", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2019.118805", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503172600032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, H; Braveenth, R; Muruganulltham, S; Jeon, CY; Lee, HS; Kwon, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hyuna; Braveenth, Ramanaskanda; Muruganulltham, Subramanian; Jeon, Chae Yeon; Lee, Hyun Seung; Kwon, Jang Hyuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient pure blue hyperfluorescence devices utilizing quadrupolar donor-acceptor-donor type of thermally activated delayed fluorescence sensitizers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hyperfluorescence (HF) system has drawn great attention in display technology. However, the energy loss mechanism by low reverse intersystem crossing rate (k(RISC)) and the Dexter energy transfer (DET) channel is still challenging. Here, we demonstrate that this can be mitigated by the quadrupolar donor-acceptor-donor (D-A-D) type of thermally activated delayed fluorescence (TADF) sensitizer materials, DBA-DmICz and DBA-DTMCz. Further, the HF device with DBA-DTMCz and nu-DABNA exhibited 43.9% of high maximum external quantum efficiency (EQE(max)) with the Commission Internationale de l'eclairage coordinates of (0.12, 0.16). The efficiency values recorded for the device are among the highest reported for HF devices. Such high efficiency is assisted by hindered DET process through i) high k(RISC), and ii) shielded lowest unoccupied molecular orbital with the presence of two donors in D-A-D type of skeleton. Our current study provides an effective way of designing TADF sensitizer for future HF technology. A suppressed energy loss through Dexter energy transfer is crucial to achieve highly efficient blue organic light-emitting diodes. Here, authors synthesize quadrupolar donor-acceptor-donor type thermally activated delayed fluorescence sensitizers and realize device with maximum efficiency of 43.9%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 419, "DOI": "10.1038/s41467-023-35926-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35926-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953201000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stanev, V; Oses, C; Kusne, AG; Rodriguez, E; Paglione, J; Curtarolo, S; Takeuchi, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stanev, Valentin; Oses, Corey; Kusne, A. Gilad; Rodriguez, Efrain; Paglione, Johnpierre; Curtarolo, Stefano; Takeuchi, Ichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning modeling of superconducting critical temperature", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductivity has been the focus of enormous research effort since its discovery more than a century ago. Yet, some features of this unique phenomenon remain poorly understood; prime among these is the connection between superconductivity and chemical/structural properties of materials. To bridge the gap, several machine learning schemes are developed herein to model the critical temperatures (T-c) of the 12,000+ known superconductors available via the SuperCon database. Materials are first divided into two classes based on their T-c values, above and below 10 K, and a classification model predicting this label is trained. The model uses coarse-grained features based only on the chemical compositions. It shows strong predictive power, with out-of-sample accuracy of about 92%. Separate regression models are developed to predict the values of T-c for cuprate, iron-based, and low-T-c compounds. These models also demonstrate good performance, with learned predictors offering potential insights into the mechanisms behind superconductivity in different families of materials. To improve the accuracy and interpretability of these models, new features are incorporated using materials data from the AFLOW Online Repositories. Finally, the classification and regression models are combined into a single-integrated pipeline and employed to search the entire Inorganic Crystallographic Structure Database (ICSD) for potential new superconductors. We identify >30 non-cuprate and non-iron-based oxides as candidate materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 416, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29, "DOI": "10.1038/s41524-018-0085-8", "DOI Link": "http://dx.doi.org/10.1038/s41524-018-0085-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438373200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bauriedl, L; Bäuml, C; Fuchs, L; Baumgartner, C; Paulik, N; Bauer, JM; Lin, KQ; Lupton, JM; Taniguchi, T; Watanabe, K; Strunk, C; Paradiso, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bauriedl, Lorenz; Bauml, Christian; Fuchs, Lorenz; Baumgartner, Christian; Paulik, Nicolas; Bauer, Jonas M.; Lin, Kai-Qiang; Lupton, John M.; Taniguchi, Takashi; Watanabe, Kenji; Strunk, Christoph; Paradiso, Nicola", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supercurrent diode effect and magnetochiral anisotropy in few-layer NbSe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The supercurrent diode effect was recently observed in a Nb/V/Ta superlattice thin film with Rashba-type spin-orbit coupling. Here, the authors observe this effect in few-layer NbSe2 crystals driven by valley-Zeeman-type spin-orbit coupling and find that the effect is proportional to out-of-plane magnetic field. Nonreciprocal transport refers to charge transfer processes that are sensitive to the bias polarity. Until recently, nonreciprocal transport was studied only in dissipative systems, where the nonreciprocal quantity is the resistance. Recent experiments have, however, demonstrated nonreciprocal supercurrent leading to the observation of a supercurrent diode effect in Rashba superconductors. Here we report on a supercurrent diode effect in NbSe2 constrictions obtained by patterning NbSe2 flakes with both even and odd layer number. The observed rectification is a consequence of the valley-Zeeman spin-orbit interaction. We demonstrate a rectification efficiency as large as 60%, considerably larger than the efficiency of devices based on Rashba superconductors. In agreement with recent theory for superconducting transition metal dichalcogenides, we show that the effect is driven by the out-of-plane component of the magnetic field. Remarkably, we find that the effect becomes field-asymmetric in the presence of an additional in-plane field component transverse to the current direction. Supercurrent diodes offer a further degree of freedom in designing superconducting quantum electronics with the high degree of integrability offered by van der Waals materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4266, "DOI": "10.1038/s41467-022-31954-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31954-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830076200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XX; Wang, Z; Watanabe, K; Taniguchi, T; Vafek, OKR; Li, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaoxue; Wang, Zhi; Watanabe, K.; Taniguchi, T.; Vafek, Oskar; Li, J. I. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning electron correlation in magic-angle twisted bilayer graphene using Coulomb screening", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling the strength of interactions is essential for studying quantum phenomena emerging in systems of correlated fermions. We introduce a device geometry whereby magic-angle twisted bilayer graphene is placed in close proximity to a Bernal bilayer graphene, separated by a 3-nullometer-thick barrier. By using charge screening from the Bernal bilayer, the strength of electron-electron Coulomb interaction within the twisted bilayer can be continuously tuned. Transport measurements show that tuning Coulomb screening has opposite effects on the insulating and superconducting states: As Coulomb interaction is weakened by screening, the insulating states become less robust, whereas the stability of superconductivity at the optimal doping is enhanced. The results provide important constraints on theoretical models for understanding the mechanism of superconductivity in magic-angle twisted bilayer graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 371, "Issue": 6535, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1261, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb8754", "DOI Link": "http://dx.doi.org/10.1126/science.abb8754", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634054600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Månberger, A; Stenqvist, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Manberger, Andre; Stenqvist, Bjorn", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global metal flows in the renewable energy transition: Exploring the effects of substitutes, technological mix and development", "Source Title": "ENERGY POLICY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study analysed demand for 12 metals in global climate mitigation scenarios up to 2060 and quantified the impacts on demand of different assumptions on improvements and technological mix. Annual and cumulative demands were compared with reserves and current mining rates. The study results showed that reserves are sufficient to support the total level of solar power, wind power and electric motors. Insufficient reserves may very well constrain certain sub-technologies, but substitutes that take the role of 'back-stop' technologies can be used instead. The exception is batteries, since lithium battery chemistries and reserves were incompatible with the scenarios analysed. Batteries of moderate size, lithium-free chemistry or reserve expansion would make the transition feasible. Choice of sub-technology (e.g. type of solar PV) had a decisive impact on demand for certain metals. Perceptions that many metals are critical and scarce for renewable energy transitions appear exaggerated if a dynamic view on technological development is adopted. Policy-relevant conclusions can be drawn from this, regarding e.g. the benefits of technological diversity, increasing metal intensity, recycling and integrating infrastructure and energy policies (e.g. fast chargers).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 119, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 226, "End Page": 241, "Article Number": null, "DOI": "10.1016/j.enpol.2018.04.056", "DOI Link": "http://dx.doi.org/10.1016/j.enpol.2018.04.056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Business & Economics; Energy & Fuels; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439671200022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, DY; Wu, JD; Zhou, BT; Liang, J; Ideue, T; Siu, T; Awan, KM; Watanabe, K; Taniguchi, T; Iwasa, Y; Franz, M; Ye, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dongyang; Wu, Jingda; Zhou, Benjamin T.; Liang, Jing; Ideue, Toshiya; Siu, Teri; Awan, Kashif Masud; Watanabe, Kenji; Taniguchi, Takashi; Iwasa, Yoshihiro; Franz, Marcel; Ye, Ziliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous-polarization-induced photovoltaic effect in rhombohedrally stacked MoS2", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is shown that rhombohedral stacked MoS2 can enable scalable photovoltaic effects induced by spontaneous polarization throughout few-micrometre-sized exfoliated flakes. This is exploited in a graphene-MoS2-based photovoltaic device. Stacking order in van der Waals materials determines the coupling between atomic layers and is therefore the key to materials' properties. Recently, ferroelectricity, a phenomenon exhibiting reversible spontaneous electrical polarization, has been observed in zero-degree aligned van der Waals structures. In these artificial stacks, the single-domain size is limited by angle misalignment. Here we show that naturally rhombohedrally stacked MoS2 can host a homogeneous spontaneous polarization throughout the exfoliated flakes, free of misalignment. Utilizing this homogeneous polarization and its induced depolarization field, we build a graphene-MoS2-based photovoltaic device with high efficiency. Few-layer MoS2 is thinner than most oxide-based ferroelectric films, which allows us to maximize the depolarization field and study its impact at the atomically thin limit, whereas the highly uniform polarization in the commensurate crystal enables a tangible path for upscaling. The external quantum efficiency of our device is up to 16% at room temperature, over one order larger than the highest efficiency observed in bulk photovoltaic devices, owing to the reduced screening in graphene, exciton-enhanced light-matter interaction and ultrafast interlayer relaxation. Our findings make rhombohedral transition metal dichalcogenides a promising candidate for applications such as energy-efficient photodetection with high speed and programmable polarity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 469, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01008-9", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01008-9", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805500200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kadiyala, U; Turali-Emre, ES; Bahng, JH; Kotov, NA; VanEpps, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kadiyala, Usha; Turali-Emre, Emine Sumeyra; Bahng, Joong Hwan; Kotov, Nicholas A.; VanEpps, J. Scott", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unexpected insights into antibacterial activity of zinc oxide nulloparticles against methicillin resistant Staphylococcus aureus (MRSA)", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc oxide nulloparticles (ZnO-NPs) are attractive as broad-spectrum antibiotics, however, their further engineering as antimicrobial agents and clinical translation is impeded by controversial data about their mechanism of activity. It is commonly reported that ZnO-NP's antimicrobial activity is associated with the production of reactive oxygen species (ROS). Here we disprove this concept by comparing the antibacterial potency of ZnO-NPs and their capacity to generate ROS with hydrogen peroxide (H2O2). Then, using gene transcription microarray analysis, we provide evidence for a novel toxicity mechanism. Exposure to ZnO-NPs resulted in over three-log reduction in colonies of methicillin resistant S. aureus with minimal increase in ROS or lipid peroxidation. The amount of ROS required for the same amount of killing by H2O2 was much greater than that generated by ZnO-NPs. In contrast to H2O2, ZnO-NP mediated killing was not mitigated by the antioxidant, N-acetylcysteine. ZnO-NPs caused significant up-regulation of pyrimidine biosynthesis and carbohydrate degradation. Simultaneously, amino acid synthesis in S. aureus was significantly down-regulated indicating a complex mechanism of antimicrobial action involving multiple metabolic pathways. The results of this study point to the importance of specific experimental controls in the interpretation of antimicrobial mechanistic studies and the need for targeted molecular mechanism studies. Continued investigation on the antibacterial mechanisms of biomimetic ZnO-NPs is essential for future clinical translation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4927, "End Page": 4939, "Article Number": null, "DOI": "10.1039/c7nr08499d", "DOI Link": "http://dx.doi.org/10.1039/c7nr08499d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428786800037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raney, JR; Nadkarni, N; Daraio, C; Kochmann, DM; Lewis, JA; Bertoldi, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raney, Jordan R.; Nadkarni, Neel; Daraio, Chiara; Kochmann, Dennis M.; Lewis, Jennifer A.; Bertoldi, Katia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stable propagation of mechanical signals in soft media using stored elastic energy", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft structures with rationally designed architectures capable of large, nonlinear deformation present opportunities for unprecedented, highly tunable devices and machines. However, the highly dissipative nature of soft materials intrinsically limits or prevents certain functions, such as the propagation of mechanical signals. Here we present an architected soft system composed of elastomeric bistable beam elements connected by elastomeric linear springs. The dissipative nature of the polymer readily damps linear waves, preventing propagation of any mechanical signal beyond a short distance, as expected. However, the unique architecture of the system enables propagation of stable, nonlinear solitary transition waves with constant, controllable velocity and pulse geometry over arbitrary distances. Because the high damping of the material removes all other linear, small-amplitude excitations, the desired pulse propagates with high fidelity and controllability. This phenomenon can be used to control signals, as demonstrated by the design of soft mechanical diodes and logic gates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2016, "Volume": 113, "Issue": 35, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9722, "End Page": 9727, "Article Number": null, "DOI": "10.1073/pnas.1604838113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1604838113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383090700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Süsstrunk, R; Huber, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Susstrunk, Roman; Huber, Sebastian D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Classification of topological phonons in linear mechanical metamaterials", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological phononic crystals, alike their electronic counterparts, are characterized by a bulk-edge correspondence where the interior of a material dictates the existence of stable surface or boundary modes. In the mechanical setup, such surface modes can be used for various applications such as wave guiding, vibration isolation, or the design of static properties such as stable floppy modes where parts of a system move freely. Here, we provide a classification scheme of topological phonons based on local symmetries. We import and adapt the classification of noninteracting electron systems and embed it into the mechanical setup. Moreover, we provide an extensive set of examples that illustrate our scheme and can be used to generate models in unexplored symmetry classes. Our work unifies the vast recent literature on topological phonons and paves the way to future applications of topological surface modes in mechanical metamaterials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2016, "Volume": 113, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "E4767", "End Page": "E4775", "Article Number": null, "DOI": "10.1073/pnas.1605462113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1605462113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381399200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahi, A; Bedia, EA; Tounsi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahi, Amale; Bedia, El Abbas Adda; Tounsi, Abdelouahed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new hyperbolic shear deformation theory for bending and free vibration analysis of isotropic, functionally graded, sandwich and laminated composite plates", "Source Title": "APPLIED MATHEMATICAL MODELLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new hyperbolic shear deformation theory applicable to bending and free vibration analysis of isotropic, functionally graded, sandwich and laminated composite plates is presented. This new theory has five degrees of freedom, provides parabolic transverse shear strains across the thickness direction and hence, it does not need shear correction factor. Moreover, zero-traction boundary conditions on the top and bottom surfaces of the plate are satisfied rigorously. The energy functional of the system is obtained using Hamilton's principle. Analytical solutions of deflection and stresses are obtained using Navier-type procedure. Free vibration frequencies are then accurately calculated using a set of boundary characteristic orthogonal polynomials associated with Ritz method. Numerical comparisons are conducted to verify and to demonstrate the accuracy and efficiency of the present theory. Excellent agreement with the known results in the literature has been obtained. (C) 2014 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 622, "Times Cited, All Databases": 634, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2015, "Volume": 39, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2489, "End Page": 2508, "Article Number": null, "DOI": "10.1016/j.apm.2014.10.045", "DOI Link": "http://dx.doi.org/10.1016/j.apm.2014.10.045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354590200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gartner, E; Hirao, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gartner, Ellis; Hirao, Hiroshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A review of alternative approaches to the reduction of CO2 emissions associated with the manufacture of the binder phase in concrete", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this review we discuss a wide range of alternative approaches to the reduction of CO2 emissions associated with the manufacture of the binder phase in concrete. They are classified broadly as follows: (1) Use alternative fuels and/or alternative raw materials in the manufacture of Portland-based cements. (2) Replace Portland clinker with low-carbon supplementary cementitious materials (SCMs) in concrete. (3) Develop alternative low-carbon binders not based on Portland clinkers. The first approach mainly represents incremental improvements that can be achieved fairly easily and cheaply as long as suitable raw materials can be found. The second approach ranges from incremental improvements, if low levels of SCM substitution are used, all the way to major innovations for binders with very high Portland clinker replacement levels. The third approach is the most risky but also holds the greatest promise for truly significant CO2 reductions if it can be implemented on a large scale. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 411, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2015, "Volume": 78, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 126, "End Page": 142, "Article Number": null, "DOI": "10.1016/j.cemconres.2015.04.012", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2015.04.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364254800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MR; Shi, ZF; Fei, CB; Deng, ZJD; Yang, G; Dunfield, SP; Fenning, DP; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mengru; Shi, Zhifang; Fei, Chengbin; Deng, Zhewen J. D.; Yang, Guang; Dunfield, Sean P.; Fenning, David P.; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ammonium cations with high pKa in perovskite solar cells for improved high-temperature photostability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phenethylammonium (PEA(+)) and butylammonium (BA(+)) are widely used in three-dimensional (3D) perovskites to form two-dimensional perovskites at film surfaces and grain boundaries (GBs) for defect passivation and performance enhancement. Here we show that these cations are unstable with 3D formamidinium (FA(+))-containing perovskites under high-temperature light soaking. PEA(+) and BA(+) are found to deprotonate to amines, which then react with FA+ to produce (phenethylamino)methaniminium (PEAMA+) and (butylamino)methaniminium (BAMA(+)), respectively, severely limiting device high-temperature photostability. Removing these cations greatly improves the photostability but compromises device efficiency by leaving non-fully passivated surfaces and GBs. Ammonium cations with a high acid dissociation constant (pKa), including PEAMA(+) (pK(a) = 12.0) and BAMA(+) (pK(a) = 12.0), can replace PEA(+) or BA(+) for passivation and are stable with FA-based perovskites due to their resistance to further deprotonation. P-i-n structure solar cells with PEAMA(+) additive maintained over 90% of their initial efficiency after light soaking at open circuit and 90 C-degrees for 1,500 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 8, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1229, "End Page": 1239, "Article Number": null, "DOI": "10.1038/s41560-023-01362-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01362-0", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001074834300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, JC; Liu, YY; Pei, JJ; Li, HJ; Ji, SF; Shi, L; Zhang, YN; Li, C; Tang, C; Liao, JW; Xu, SQ; Zhang, HB; Li, Q; Zhao, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Juncai; Liu, Yangyang; Pei, Jiajing; Li, Haijing; Ji, Shufang; Shi, Lei; Zhang, Yaning; Li, Can; Tang, Cheng; Liao, Jiangwen; Xu, Shiqing; Zhang, Huabin; Li, Qi; Zhao, Shenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Continuous electroproduction of formate via CO2 reduction on local symmetry-broken single-atom catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic-level coordination engineering is an efficient strategy for tuning the catalytic performance of single-atom catalysts (SACs). However, their rational design has so far been plagued by the lack of a universal correlation between the coordination symmetry and catalytic properties. Herein, we synthesised planar-symmetry-broken CuN3 (PSB-CuN3) SACs through microwave heating for electrocatalytic CO2 reduction. Remarkably, the as-prepared catalysts exhibited a selectivity of 94.3% towards formate at -0.73 V vs. RHE, surpassing the symmetrical CuN4 catalyst (72.4% at -0.93 V vs. RHE). In a flow cell equipped with a PSB-CuN3 electrode, over 90% formate selectivity was maintained at an average current density of 94.4 mA cm(-2) during 100 h operation. By combining definitive structural identification with operando X-ray spectroscopy and theoretical calculations, we revealed that the intrinsic local symmetry breaking from planar D-4h configuration induces an unconventional dsp hybridisation, and thus a strong correlation between the catalytic activity and microenvironment of metal centre (i.e., coordination number and distortion), with high preference for formate production in CuN3 moiety. The finding opens an avenue for designing efficient SACs with specific local symmetries for selective electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6849, "DOI": "10.1038/s41467-023-42539-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42539-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001091497000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YW; Hao, J; Liu, HY; Tse, JS; Wang, YC; Ma, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yinwei; Hao, Jian; Liu, Hanyu; Tse, John S.; Wang, Yanchao; Ma, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-stabilized superconductive yttrium hydrides", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for high-temperature superconductors has been focused on compounds containing a large fraction of hydrogen, such as SiH4(H-2)(2), CaH6 and KH6. Through a systematic investigation of yttrium hydrides at different hydrogen contents using an structure prediction method based on the particle swarm optimization algorithm, we have predicted two new yttrium hydrides (YH4 and YH6), which are stable above 110 GPa. Three types of hydrogen species with increased H contents were found, monatomic H in YH3, monatomic H+molecular H-2 in YH4 and hexagonal H-6 unit in YH6. Interestingly, H atoms in YH6 form sodalite-like cage sublattice with centered Y atom. Electron-phonon calculations revealed the superconductive potential of YH4 and YH6 with estimated transition temperatures (T-c) of 84-95 K and 251-264 K at 120 GPa, respectively. These values are higher than the predicted maximal T-c of 40 K in YH3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9948, "DOI": "10.1038/srep09948", "DOI Link": "http://dx.doi.org/10.1038/srep09948", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353905200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YL; Zhao, MY; Huang, JB; Zhao, N; Yu, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yanlin; Zhao, Mingyu; Huang, Jubo; Zhao, null; Yu, Haihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controllable Synthesis, Photocatalytic Property, and Mechanism of a Novel POM-Based Direct Z-Scheme nullo-Heterojunction α-Fe2O3/P2Mo18", "Source Title": "MOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to improve photocatalytic activity and maximize solar energy use, a new composite material Fe2O3/P2Mo18 was prepared by combining polyoxometalates (P2Mo18) with Fe2O3 nullosheets. FT-IR, XRD, XPS, SEM, TEM, UV-vis, EIS, and PL were used to characterize the composite material, and nullo-Fe2O3 of different sizes and morphologies with a controllable absorption range was prepared by adjusting the reaction time, and, when combined with P2Mo18, a composite photocatalyst with efficient visible light response and photocatalytic activity was constructed. The EIS, Bode, and PL spectra analysis results show that the Fe2O3/P2Mo18 composite material has outstanding interfacial charge transfer efficiency and potential photocatalytic application possibilities. Model reactions of methylene blue (MB) and Cr (VI) photodegradation were used to evaluate the redox activity of Fe2O3/P2Mo18 composites under simulated visible light. The photocatalytic degradation rate was as high as 98.98% for MB and 96.86% for Cr (VI) when the composite ratio was Fe2O3/P2Mo18-5%. This research opens up a new avenue for the development of high-performance photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 28, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6671, "DOI": "10.3390/molecules28186671", "DOI Link": "http://dx.doi.org/10.3390/molecules28186671", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076936600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZB; Guo, X; Yang, MX; Jin, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zhaobo; Guo, Xin; Yang, Mengxue; Jin, Zhiliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanochemical preparation and application of graphdiyne coupled with CdSe nulloparticles for efficient photocatalytic hydrogen production", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphdiyne (GDY) has attracted considerable attention as a new two-dimensional (2D) carbon hybrid material because of its good conductivity, adjustable electronic structure, and special elec-tron transfer enhancement properties. GDY has great potential in the field of photocatalytic water splitting for hydrogen evolution, owing to its unique properties. In this study, GDY was successfully prepared by the mechanochemical coupling of precursors C6Br6 and CaC2 using a ball-milling ap-proach. The prepared GDY, especially its microstructure and composition, was well characterized using different techniques such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared, and Raman characterization techniques. By exploiting the unique two-dimensional (2D) structure and outstanding light absorption properties of GDY, GDY/CdSe 2D/0D heterojunctions were successful-ly established and applied to photocatalytic hydrogen evolution. The hydrogen evolution activity of GDY/CdSe-20, a type of composite material, reached 6470 limol g-1 h-1, which is 461 and 40 times higher than that of GDY and CdSe, respectively. Moreover, the fine electrical conductivity of GDY enabled rapid and effective transfer of the photogenerated electrons in CdSe into the hydrogen evolution reaction. The transfer path of the photogenerated electrons was studied through XPS with in situ irradiation, and a reasonable mechanism for the hydrogen evolution reaction was proposed. This study provides a feasible approach for the large-scale preparation of GDY and demonstrates the prospects of GDY in the field of photocatalysis.(c) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 43, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2708, "End Page": 2719, "Article Number": null, "DOI": "10.1016/S1872-2067(21)64053-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)64053-6", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000883826600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Betancourt, RDG; Zubác, J; Gonzalez-Hernulldez, R; Geishendorf, K; Sobán, Z; Springholz, G; Olejnik, K; Smejkal, L; Sinova, J; Jungwirth, T; Goennenwein, STB; Thomas, A; Reichlová, H; Zelezny, J; Kriegner, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Betancourt, R. D. Gonzalez; Zubac, J.; Gonzalez-Hernulldez, R.; Geishendorf, K.; Soban, Z.; Springholz, G.; Olejnik, K.; Smejkal, L.; Sinova, J.; Jungwirth, T.; Goennenwein, S. T. B.; Thomas, A.; Reichlova, H.; Zelezny, J.; Kriegner, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous Anomalous Hall Effect Arising from an Unconventional Compensated Magnetic Phase in a Semiconductor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The anomalous Hall effect, commonly observed in metallic magnets, has been established to originate from the time-reversal symmetry breaking by an internal macroscopic magnetization in ferromagnets or by a noncollinear magnetic order. Here we observe a spontaneous anomalous Hall signal in the absence of an external magnetic field in an epitaxial film of MnTe, which is a semiconductor with a collinear antiparallel magnetic ordering of Mn moments and a vanishing net magnetization. The anomalous Hall effect arises from an unconventional phase with strong time-reversal symmetry breaking and alternating spin polarization in real-space crystal structure and momentum-space electronic structure. The anisotropic crystal environment of magnetic Mn atoms due to the nonmagnetic Te atoms is essential for establishing the unconventional phase and generating the anomalous Hall effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2023, "Volume": 130, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36702, "DOI": "10.1103/PhysRevLett.130.036702", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.130.036702", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939267000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bestwick, AJ; Fox, EJ; Kou, XF; Pan, L; Wang, KL; Goldhaber-Gordon, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bestwick, A. J.; Fox, E. J.; Kou, Xufeng; Pan, Lei; Wang, Kang L.; Goldhaber-Gordon, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precise Quantization of the Anomalous Hall Effect near Zero Magnetic Field", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a nearly ideal quantum anomalous Hall effect in a three-dimensional topological insulator thin film with ferromagnetic doping. Near zero applied magnetic field we measure exact quantization in the Hall resistance to within a part per 10 000 and a longitudinal resistivity under 1 Omega per square, with chiral edge transport explicitly confirmed by nonlocal measurements. Deviations from this behavior are found to be caused by thermally activated carriers, as indicated by an Arrhenius law temperature dependence. Using the deviations as a thermometer, we demonstrate an unexpected magnetocaloric effect and use it to reach near-perfect quantization by cooling the sample below the dilution refrigerator base temperature in a process approximating adiabatic demagnetization refrigeration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 272, "Times Cited, All Databases": 317, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2015, "Volume": 114, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 187201, "DOI": "10.1103/PhysRevLett.114.187201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.187201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353787800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Purdie, DG; Pugno, NM; Taniguchi, T; Watanabe, K; Ferrari, AC; Lombardo, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Purdie, D. G.; Pugno, N. M.; Taniguchi, T.; Watanabe, K.; Ferrari, A. C.; Lombardo, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cleaning interfaces in layered materials heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterostructures formed by stacking layered materials require atomically clean interfaces. However, contaminullts are usually trapped between the layers, aggregating into randomly located blisters, incompatible with scalable fabrication processes. Here we report a process to remove blisters from fully formed heterostructures. Our method is over an order of magnitude faster than those previously reported and allows multiple interfaces to be cleaned simultaneously. We fabricate blister-free regions of graphene encapsulated in hexagonal boron nitride with an area similar to 5000 mu m(2), achieving mobilities up to 180,000 cm(2) V-1 s(-1) at room temperature, and 1.8 x 10(6) cm(2) V-1 s(-1) at 9 K. We also assemble heterostructures using graphene intentionally exposed to polymers and solvents. After cleaning, these samples reach similar mobilities. This demonstrates that exposure of graphene to process-related contaminullts is compatible with the realization of high mobility samples, paving the way to the development of wafer-scale processes for the integration of layered materials in (opto)electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 19", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5387, "DOI": "10.1038/s41467-018-07558-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07558-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453754200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, XX; Ding, YM; Duan, Y; Ni, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xuexue; Ding, Yimin; Duan, Yao; Ni, Xingjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonreciprocal metasurface with space-time phase modulation", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Creating materials with time-variant properties is critical for breaking reciprocity that imposes fundamental limitations on wave propagation. However, it is challenging to realize efficient and ultrafast temporal modulation in a photonic system. Here, leveraging both spatial and temporal phase manipulation offered by an ultrathin nonlinear metasurface, we experimentally demonstrated nonreciprocal light reflection at wavelengths around 860 nm. The metasurface, with travelling-wave modulation upon nonlinear Kerr building blocks, creates spatial phase gradient and multi-terahertz temporal phase wobbling, which leads to unidirectional photonic transitions in both the momentum and energy spaces. We observed completely asymmetric reflections in forward and backward light propagations over a large bandwidth around 5.77 THz within a sub-wavelength interaction length of 150 nm. Our approach highlights a potential means for creating miniaturized and integratable nonreciprocal optical components.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123, "DOI": "10.1038/s41377-019-0225-z", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0225-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517097400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Zhang, WQ; Wang, JF; Li, XJ; Li, Y; Hu, X; Zhao, LH; Wu, Y; He, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Lu; Zhang, Wenqian; Wang, Junfeng; Li, Xiaojing; Li, Yi; Hu, Xin; Zhao, Leihong; Wu, Ying; He, Yiming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High piezo/photocatalytic efficiency of Ag/Bi5O7I nullocomposite using mechanical and solar energy for N2 fixation and methyl orange degradation", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, Ag/Bi5O7I nullocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange (MO) degradation. Bi5O7I was synthesized via a hydrothermal-calcination method and shows nullorods morphology. Ag nulloparticles (NPs) were photo deposited on the Bi5O7I nullorods as electron trappers to improve the spatial separation of charge carriers, which was confirmed via XPS, TEM, and electronic chemical analyses. The catalytic test indicates that Bi5O7I presents the piezoelectric-like behavior, while the loading of Ag NPs can strengthen the character. Under ultrasonic vibration, the optimal Ag/Bi5O7I presents high efficiency in MO degra-dation. The degradation rate is determined to be 0.033 min -1, which is 4.7 folds faster than that of Bi5O7I. The Ag/Bi5O7I also presents a high performance in piezocatalytic N2 fixation. The piezocatalytic NH3 generation rate reaches 65.4 mmol L-1 g-1 h-1 with water as a hole scavenger. The addition of methanol can hasten the piezoelectric catalytic reaction. Interestingly, when ultrasonic vibration and light irra-diation simultaneously act on the Ag/Bi5O7I catalyst, higher performance in NH3 generation and MO degradation is observed. However, due to the weak adhesion of Ag NPs, some Ag NPs would fall off from the Bi5O7I surface under long-term ultrasonic vibration, which would greatly reduce the piezoelectric catalytic performance. This result indicates that a strong binding force is required when preparing the piezoelectric composite catalyst. The current work provides new insights for the development of highly efficient catalysts that can use multiple energies.(c) 2021 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Commu-nications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 283, "End Page": 295, "Article Number": null, "DOI": "10.1016/j.gee.2021.04.009", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2021.04.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938188100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, QF; Zhao, Y; Qi, KZ; Yan, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Qingfeng; Zhao, Yue; Qi, Kezhen; Yan, Ya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-scheme CuInS2/ZnS heterojunctions for the visible light-driven photocatalytic degradation of tetracycline antibiotic drugs", "Source Title": "JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: In last few years, the researchers from different communities are focusing the wastewater treatment of medical and aquaculture industry. More importantly, the antibiotic released from the hospitals and aquaculture badly effecting water bodies. Methods: In this work, a series of CuInS2/ZnS (CIS/ZnS) heterojunction nullomaterials are prepared through solvothermal method and analyzed using different techniques. The photocatalytic behavior of CIS/ZnS heterojunctions in the degradation of tetracycline hydrochloride (TCH) is investigated under visible light irradiation. Significant findings: The results show that up to 86% of TCH degrades in 3 h with the optimized CIS/ZnS(1:2) sample. The enhanced photocatalytic activity is attributed to the formation of S-scheme heterojunctions, which promotes charge separation and transportation in CIS/ZnS composite materials. The photocatalytic mechanism is elucidated based on the electron paramagnetic resonullce technique, optical properties and charge/radical trapping experiments. The visible-light absorption ability is enhanced, and superoxide radical (O-center dot(2)-) is confirmed to be one of the main active species according to active substance capturing experiments. The high stability of CIS/ZnS composite provides a new way to design effective photocatalysts for the eradication of hazardous materials from environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 142, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104679, "DOI": "10.1016/j.jtice.2023.104679", "DOI Link": "http://dx.doi.org/10.1016/j.jtice.2023.104679", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926794500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Torricelli, F; Adrahtas, DZ; Bao, ZN; Berggren, M; Biscarini, F; Bonfiglio, A; Bortolotti, CA; Frisbie, CD; Macchia, E; Malliaras, GG; McCulloch, I; Moser, M; Nguyen, TQ; Owens, RM; Salleo, A; Spanu, A; Torsi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Torricelli, Fabrizio; Adrahtas, Demetra Z.; Bao, Zhenull; Berggren, Magnus; Biscarini, Fabio; Bonfiglio, Annalisa; Bortolotti, Carlo A.; Frisbie, C. Daniel; Macchia, Eleonora; Malliaras, George G.; McCulloch, Iain; Moser, Maximilian; Nguyen, Thuc-Quyen; Owens, Roisin M.; Salleo, Alberto; Spanu, Andrea; Torsi, Luisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrolyte-gated transistors for enhanced performance bioelectronics", "Source Title": "NATURE REVIEWS METHODS PRIMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte-gated transistors (EGTs), capable of transducing biological and biochemical inputs into amplified electronic signals and stably operating in aqueous environments, have emerged as fundamental building blocks in bioelectronics. In this Primer, the different EGT architectures are described with the fundamental mechanisms underpinning their functional operation, providing insight into key experiments including necessary data analysis and validation. Several organic and inorganic materials used in the EGT structures and the different fabrication approaches for an optimal experimental design are presented and compared. The functional bio-layers and/or biosystems integrated into or interfaced to EGTs, including self-organization and self-assembly strategies, are reviewed. Relevant and promising applications are discussed, including two-dimensional and three-dimensional cell monitoring, ultra-sensitive biosensors, electrophysiology, synaptic and neuromorphic bio-interfaces, prosthetics and robotics. Advantages, limitations and possible optimizations are also surveyed. Finally, current issues and future directions for further developments and applications are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 66, "DOI": "10.1038/s43586-021-00065-8", "DOI Link": "http://dx.doi.org/10.1038/s43586-021-00065-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888188000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, SY; Alidoust, N; Chang, GQ; Lu, H; Singh, B; Belopolski, I; Sanchez, DS; Zhang, X; Bian, G; Zheng, H; Husanu, MA; Bian, Y; Huang, SM; Hsu, CH; Chang, TR; Jeng, HT; Bansil, A; Neupert, T; Strocov, VN; Lin, H; Jia, SA; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Su-Yang; Alidoust, Nasser; Chang, Guoqing; Lu, Hong; Singh, Bahadur; Belopolski, Ilya; Sanchez, Daniel S.; Zhang, Xiao; Bian, Guang; Zheng, Hao; Husanu, Marious-Adrian; Bian, Yi; Huang, Shin-Ming; Hsu, Chuang-Han; Chang, Tay-Rong; Jeng, Horng-Tay; Bansil, Arun; Neupert, Titus; Strocov, Vladimir N.; Lin, Hsin; Jia, Shuang; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of Lorentz-violating type II Weyl fermions in LaAlGe", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In quantum field theory, Weyl fermions are relativistic particles that travel at the speed of light and strictly obey the celebrated Lorentz symmetry. Their low-energy condensed matter analogs are Weyl semimetals, which are conductors whose electronic excitations mimic the Weyl fermion equation of motion. Although the traditional (type I) emergent Weyl fermions observed in TaAs still approximately respect Lorentz symmetry, recently, the so-called type II Weyl semimetal has been proposed, where the emergent Weyl quasiparticles break the Lorentz symmetry so strongly that they cannot be smoothly connected to Lorentz symmetric Weyl particles. Despite some evidence of nontrivial surface states, the direct observation of the type II bulk Weyl fermions remains elusive. We present the direct observation of the type II Weyl fermions in crystalline solid lanthanum aluminum germanide (LaAlGe) based on our photoemission data alone, without reliance on band structure calculations. Moreover, our systematic data agree with the theoretical calculations, providing further support on our experimental results.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2017, "Volume": 3, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1603266", "DOI": "10.1126/sciadv.1603266", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603266", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406370700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, SJ; Choi, H; Ringe, S; Won, DH; Oh, HS; Kim, DH; Lee, T; Nam, DH; Kim, H; Choi, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Seung-Jae; Choi, Hansol; Ringe, Stefan; Won, Da Hye; Oh, Hyung-Suk; Kim, Dong Hyun; Lee, Taemin; Nam, Dae-Hyun; Kim, Hyungjun; Choi, Chang Hyuck", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A unifying mechanism for cation effect modulating C1 and C2 productions from CO2 electroreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysis, whose reaction venue locates at the catalyst-electrolyte interface, is controlled by the electron transfer across the electric double layer, envisaging a mechanistic link between the electron transfer rate and the electric double layer structure. A fine example is in the CO2 reduction reaction, of which rate shows a strong dependence on the alkali metal cation (M+) identity, but there is yet to be a unified molecular picture for that. Using quantum-mechanics-based atom-scale simulation, we herein scrutinize the M+-coupling capability to possible intermediates, and establish H+- and M+-associated ET mechanisms for CH4 and CO/C2H4 formations, respectively. These theoretical scenarios are successfully underpinned by Nernstian shifts of polarization curves with the H+ or M+ concentrations and the first-order kinetics of CO/C2H4 formation on the electrode surface charge density. Our finding further rationalizes the merit of using Nafion-coated electrode for enhanced C2 production in terms of enhanced surface charge density. CO2 reduction rate shows a strong dependence on alkali metal cation identity but a unified molecular picture for underlying mechanism requires further investigation. Using advanced molecular simulations and experimental kinetic studies, here the authors establish a unified mechanism for cation-coupled electron transfer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5482, "DOI": "10.1038/s41467-022-33199-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33199-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000855490900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, L; Sharf, A; Zhao, HS; Wei, Y; Fan, QN; Chen, XL; Savoye, Y; Tu, CH; Cohen-Or, D; Chen, BQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Lin; Sharf, Andrei; Zhao, Haisen; Wei, Yuan; Fan, Qingnull; Chen, Xuelin; Savoye, Yann; Tu, Changhe; Cohen-Or, Daniel; Chen, Baoquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Build-to-Last: Strength to Weight 3D Printed Objects", "Source Title": "ACM TRANSACTIONS ON GRAPHICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of low-cost 3D printers steers the investigation of new geometric problems that control the quality of the fabricated object. In this paper, we present a method to reduce the material cost and weight of a given object while providing a durable printed model that is resistant to impact and external forces. We introduce a hollowing optimization algorithm based on the concept of honeycomb-cells structure. Honeycombs structures are known to be of minimal material cost while providing strength in tension. We utilize the Voronoi diagram to compute irregular honeycomb-like volume tessellations which define the inner structure. We formulate our problem as a strength-to-weight optimization and cast it as mutually finding an optimal interior tessellation and its maximal hollowing subject to relieve the interior stress. Thus, our system allows to build-to-last 3D printed objects with large control over their strength-to-weight ratio and easily model various interior structures. We demonstrate our method on a collection of 3D objects from different categories. Furthermore, we evaluate our method by printing our hollowed models and measure their stress and weights.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 33, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 97, "DOI": "10.1145/2601097.2601168", "DOI Link": "http://dx.doi.org/10.1145/2601097.2601168", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340000100064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mishin, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mishin, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-learning interatomic potentials for materials science", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale atomistic computer simulations of materials rely on interatomic potentials providing computationally efficient predictions of energy and Newtonian forces. Traditional potentials have served in this capacity for over three decades. Recently, a new class of potentials has emerged, which is based on a radically different philosophy. The new potentials are constructed using machine-learning (ML) methods and a massive reference database generated by quantum-mechanical calculations. While the traditional potentials are derived from physical insights into the nature of chemical bonding, the ML potentials utilize a high-dimensional mathematical regression to interpolate between the reference energies. We review the current status of the interatomic potential field, comparing the strengths and weaknesses of the traditional and ML potentials. A third class of potentials is introduced, in which an ML model is coupled with a physics-based potential to improve the transferability to unknown atomic environments. The discussion is focused on potentials intended for materials science applications. Possible future directions in this field are outlined. (c) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2021, "Volume": 214, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116980, "DOI": "10.1016/j.actamat.2021.116980", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2021.116980", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663791200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MZ; Xiao, B; Wang, H; Han, MK; Zhang, Z; Viennois, E; Xu, CL; Merlin, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mingzhen; Xiao, Bo; Wang, Huan; Han, Moon Kwon; Zhang, Zhan; Viennois, Emilie; Xu, Changlong; Merlin, Didier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edible Ginger-derived nullo-lipids Loaded with Doxorubicin as a Novel Drug-delivery Approach for Colon Cancer Therapy", "Source Title": "MOLECULAR THERAPY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of nullotechnology for drug delivery has shown great promise for improving cancer treatment. However, potential toxicity, hazardous environmental effects, issues with large-scale production, and potential excessive costs are challenges that confront their further clinical applications. Here, we describe a nullovector made from ginger-derived lipids that can serve as a delivery platform for the therapeutic agent doxorubicin (Dox) to treat colon cancer. We created nulloparticles from ginger and reassembled their lipids into ginger-derived nullovectors (GDNVs). A subsequent characterization showed that GDNVs were efficiently taken up by colon cancer cells. Viability and apoptosis assays and electric cell-substrate impedance-sensing technology revealed that GDNVs exhibited excellent biocompatibility up to 200 mu mol/l; by contrast, cationic liposomes at the same concentrations decreased cell proliferation and increased apoptosis. GDNVs were capable of loading Dox with high efficiency and showed a better pH-dependent drug-release profile than commercially available liposomal-Dox. Modified GDNVs conjugated with the targeting ligand folic acid mediated targeted delivery of Dox to Colon-26 tumors in vivo and enhanced the chemotherapeutic inhibition of tumor growth compared with free drug. Current experiments explore the feasibility of producing nature-derived nulloparticles that are effective as a treatment vehicle while potentially attenuating the issues related to traditional synthetic nulloparticles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 24, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1783, "End Page": 1796, "Article Number": null, "DOI": "10.1038/mt.2016.159", "DOI Link": "http://dx.doi.org/10.1038/mt.2016.159", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Genetics & Heredity; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387256700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hübener, H; Sentef, MA; De Giovannini, U; Kemper, AF; Rubio, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hubener, Hannes; Sentef, Michael A.; De Giovannini, Umberto; Kemper, Alexander F.; Rubio, Angel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creating stable Floquet-Weyl semimetals by laser-driving of 3D Dirac materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tuning and stabilizing topological states, such as Weyl semimetals, Dirac semimetals or topological insulators, is emerging as one of the major topics in materials science. Periodic driving of many-body systems offers a platform to design Floquet states of matter with tunable electronic properties on ultrafast timescales. Here we show by first principles calculations how femtosecond laser pulses with circularly polarized light can be used to switch between Weyl semimetal, Dirac semimetal and topological insulator states in a prototypical three-dimensional (3D) Dirac material, Na3Bi. Our findings are general and apply to any 3D Dirac semimetal. We discuss the concept of time-dependent bands and steering of Floquet-Weyl points and demonstrate how light can enhance topological protection against lattice perturbations. This work has potential practical implications for the ultrafast switching of materials properties, such as optical band gaps or anomalous magnetoresistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13940, "DOI": "10.1038/ncomms13940", "DOI Link": "http://dx.doi.org/10.1038/ncomms13940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391931400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dey, S; Fan, CH; Gothelf, K; Li, J; Lin, CX; Liu, LF; Liu, N; Nijenhuis, MAD; Saccà, B; Simmel, FC; Yan, H; Zhan, PF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dey, Swarup; Fan, Chunhai; Gothelf, Kurt, V; Li, Jiang; Lin, Chenxiang; Liu, Longfei; Liu, Na; Nijenhuis, Minke A. D.; Sacca, Barbara; Simmel, Friedrich C.; Yan, Hao; Zhan, Pengfei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DNA origami", "Source Title": "NATURE REVIEWS METHODS PRIMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biological materials are self-assembled with near-atomic precision in living cells, whereas synthetic 3D structures generally lack such precision and controllability. Recently, DNA nullotechnology, especially DNA origami technology, has been useful in the bottom-up fabrication of well-defined nullostructures ranging from tens of nullometres to sub-micrometres. In this Primer, we summarize the methodologies of DNA origami technology, including origami design, synthesis, functionalization and characterization. We highlight applications of origami structures in nullofabrication, nullophotonics and nulloelectronics, catalysis, computation, molecular machines, bioimaging, drug delivery and biophysics. We identify challenges for the field, including size limits, stability issues and the scale of production, and discuss their possible solutions. We further provide an outlook on next-generation DNA origami techniques that will allow in vivo synthesis and multiscale manufacturing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 482, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13, "DOI": "10.1038/s43586-020-00009-8", "DOI Link": "http://dx.doi.org/10.1038/s43586-020-00009-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888215100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nordlund, K; Zinkle, SJ; Sand, AE; Granberg, F; Averback, RS; Stoller, R; Suzudo, T; Malerba, L; Banhart, F; Weber, WJ; Willaime, F; Dudarev, SL; Simeone, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nordlund, Kai; Zinkle, Steven J.; Sand, Andrea E.; Granberg, Fredric; Averback, Robert S.; Stoller, Roger; Suzudo, Tomoaki; Malerba, Lorenzo; Banhart, Florian; Weber, William J.; Willaime, Francois; Dudarev, Sergei L.; Simeone, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving atomic displacement and replacement calculations with physically realistic damage models", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic collision processes are fundamental to numerous advanced materials technologies such as electron microscopy, semiconductor processing and nuclear power generation. Extensive experimental and computer simulation studies over the past several decades provide the physical basis for understanding the atomic-scale processes occurring during primary displacement events. The current international standard for quantifying this energetic particle damage, the Norgett-Robinson-Torrens displacements per atom (NRT-dpa) model, has nowadays several well-known limitations. In particular, the number of radiation defects produced in energetic cascades in metals is only similar to 1/3 the NRT-dpa prediction, while the number of atoms involved in atomic mixing is about a factor of 30 larger than the dpa value. Here we propose two new complementary displacement production estimators (athermal recombination corrected dpa, arc-dpa) and atomic mixing (replacements per atom, rpa) functions that extend the NRT-dpa by providing more physically realistic descriptions of primary defect creation in materials and may become additional standard measures for radiation damage quantification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1084, "DOI": "10.1038/s41467-018-03415-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03415-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427377800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Norman, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Norman, M. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloquium: Herbertsmithite and the search for the quantum spin liquid", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin liquids form a novel class of matter where, despite the existence of strong exchange interactions, spins do not order down to the lowest measured temperature. Typically, these occur in lattices that act to frustrate the appearance of magnetism. In two dimensions, the classic example is the kagome lattice composed of corner sharing triangles. There are a variety of minerals whose transition metal ions form such a lattice. Hence, a number of them have been studied and were then subsequently synthesized in order to obtain more pristine samples. Of particular note was the report in 2005 by Dan Nocera's group of the synthesis of herbertsmithite, composed of a lattice of copper ions sitting on a kagome lattice, which indeed does not order down to the lowest measured temperature despite the existence of a large exchange interaction of 17 meV. Over the past decade, this material has been extensively studied, yielding a number of intriguing surprises that have in turn motivated a resurgence of interest in the theoretical study of the spin 1/2 Heisenberg model on a kagome lattice. This Colloquium reviews these developments and then discusses potential future directions, both experimental and theoretical, as well as the challenge of doping these materials with the hope that this could lead to the discovery of novel topological and superconducting phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 432, "Times Cited, All Databases": 464, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 2", "Publication Year": 2016, "Volume": 88, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41002, "DOI": "10.1103/RevModPhys.88.041002", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.88.041002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389033500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parameswaran, SA; Grover, T; Abanin, DA; Pesin, DA; Vishwanath, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parameswaran, S. A.; Grover, T.; Abanin, D. A.; Pesin, D. A.; Vishwanath, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing the Chiral Anomaly with Nonlocal Transport in Three-Dimensional Topological Semimetals", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are three-dimensional crystalline systems where pairs of bands touch at points in momentum space, termed Weyl nodes, that are characterized by a definite topological charge: the chirality. Consequently, they exhibit the Adler-Bell-Jackiw anomaly, which in this condensed-matter realization implies that the application of parallel electric (E) and magnetic (B) fields pumps electrons between nodes of opposite chirality at a rate proportional to E . B. We argue that this pumping is measurable via nonlocal transport experiments, in the limit of weak internode scattering. Specifically, we show that as a consequence of the anomaly, applying a local magnetic field parallel to an injected current induces a valley imbalance that diffuses over long distances. A probe magnetic field can then convert this imbalance into a measurable voltage drop far from source and drain. Such nonlocal transport vanishes when the injected current and magnetic field are orthogonal and therefore serves as a test of the chiral anomaly. We further demonstrate that a similar effect should also characterize Dirac semimetals-recently reported to have been observed in experiments-where the coexistence of a pair of Weyl nodes at a single point in the Brillouin zone is protected by a crystal symmetry. Since the nodes are analogous to valley degrees of freedom in semiconductors, the existence of the anomaly suggests that valley currents in three-dimensional topological semimetals can be controlled using electric fields, which has potential practical valleytronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2014, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31035, "DOI": "10.1103/PhysRevX.4.031035", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.4.031035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341249000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, Q; Lu, TT; Zhu, X; Wei, TB; Li, H; Zhang, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Qi; Lu, Tao-Tao; Zhu, Xin; Wei, Tai-Bao; Li, Hui; Zhang, You-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rationally introduce multi-competitive binding interactions in supramolecular gels: a simple and efficient approach to develop multi-analyte sensor array", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sensor arrays are a powerful tool for multianalyte sensing and the development of an efficient sensor array has become one of the most intriguing problems. However, sensor arrays often employ lots of receptors which need large amounts of work to synthesise. This study describes an efficient method for the fabrication of a simple sensor array based on the competitive binding in supramolecular gels. By rationally introducing various well-designed competitive binding interactions into the supramolecular gel, which is self-assembled from a naphthylhydrazone-based organogelator, a supramolecular gel-based twenty-two-member sensor array has been created. Interestingly, the sensor array has been shown to accurately identify fourteen kinds of important ions (F-, Cl-, I-, CN-, HSO4-, SCN-, S2-, OH-, Al3+, Fe3+, Zn2+, Hg2+, Pb2+ and H+) in water. It's important to note that this sensor array needs only one synthesized receptor. Moreover, using this method, we also obtained a series of ion response fluorescent supramolecular materials, which could act as security display materials. Therefore, it's a novel and facile way for the design of a simple sensor array as well as ion response fluorescent supramolecular materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 298, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5341, "End Page": 5346, "Article Number": null, "DOI": "10.1039/c6sc00955g", "DOI Link": "http://dx.doi.org/10.1039/c6sc00955g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380893900067", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shin, SJ; Gittins, JW; Balhatchet, CJ; Walsh, A; Forse, AC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shin, Seung-Jae; Gittins, Jamie W.; Balhatchet, Chloe J.; Walsh, Aron; Forse, Alexander C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Framework Supercapacitors: Challenges and Opportunities", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Supercapacitors offer superior energy storage capabilities than traditional capacitors, making them useful for applications such as electric vehicles and rapid large-scale energy storage. The energy storage performance of these devices relies on electrical double-layer capacitance and/or pseudocapacitance from rapid reversible redox reactions. Metal-organic frameworks (MOFs) have recently emerged as a new class of electrode materials with promising supercapacitor performances and capacitances that exceed those of traditional materials. However, the comparison of the supercapacitor performance of a porous carbon and a state-of-the-art MOF highlights a number of challenges for MOF supercapacitors, including low potential windows, limited cycle lifetimes, and poor rate performances. It is proposed that the well-defined and tuneable chemical structures of MOFs present a number of avenues for improving supercapacitor performance. Recent experimental and theoretical work on charging mechanisms in MOF-based supercapacitors is also discussed, and it is found that there is a need for more studies that elucidate the charge storage and degradation mechanisms. Ultimately, a deeper understanding will lead to design principles for realizing improved supercapacitor energy storage devices. Metal-organic frameworks (MOFs) are promising electrode materials for supercapacitor energy storage devices. They have shown high capacitances, but have some disadvantages compared to traditional carbon electrodes. Here, strategies are discussed for tuning MOF structures to improve their energy storage performance, as well as approaches to better understand the underlying mechanisms of energy storage and degradation.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2024, "Volume": 34, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202308497", "DOI Link": "http://dx.doi.org/10.1002/adfm.202308497", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001119241500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, C; Lee, JW; Lee, CY; Lee, DC; Cho, SN; Kwon, SK; Kim, BJ; Kim, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Cheng; Lee, Jin-Woo; Lee, Changyeon; Lee, Dongchan; Cho, Shinuk; Kwon, Soon-Ki; Kim, Bumjoon J.; Kim, Yun-Hi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dimerized small-molecule acceptors enable efficient and stable organic solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The power conversion efficiencies (PCEs) of small-molecule acceptor (SMA)-based organic solar cells (OSCs) have increased remarkably, but their long-term stability is insufficient for commercialization. Here, we demonstrate that the dimerization of an SMA significantly enhances the stability of SMA-based OSCs. The dimerized SMA (DYBO) results in OSCs with high PCEs (> 18%), which allows them to outperform OSCs based on their monomer counterpart, MYBO (PCE = 17.1%). Importantly, DYBO-based OSCs exhibit excellent thermal and photo stability. For example, DYBO-based OSCs retain more than 80% of their initial PCE even after 6,000 h of thermal exposure at 100 degrees C, whereas MYBO-based OSCs degrade to -80% of their initial PCE value in 36 h. The high stability of DYBO-based OSCs is mainly attributed to the high glass transition temperature (Tg) of DYBO of 179 degrees C (Tg of MYBO = 80 degrees C) and the improved blend miscibility, which stabilizes the blend morphology under thermal stress.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 416, "End Page": 430, "Article Number": null, "DOI": "10.1016/j.joule.2023.01.009", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.01.009", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939569700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Roques-Carmes, C; Kooi, SE; Tang, HN; Beroz, J; Mazur, E; Kaminer, I; Joannopoulos, JD; Soljacic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yi; Roques-Carmes, Charles; Kooi, Steven E.; Tang, Haoning; Beroz, Justin; Mazur, Eric; Kaminer, Ido; Joannopoulos, John D.; Soljacic, Marin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photonic flatband resonullces for free-electron radiation", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flatbands have become a cornerstone of contemporary condensed-matter physics and photonics. In electronics, flatbands entail comparable energy bandwidth and Coulomb interaction, leading to correlated phenomena such as the fractional quantum Hall effect and recently those in magic-angle systems. In photonics, they enable properties including slow light(1) and lasing(2). Notably, flatbands support supercollimation-diffractionless wavepacket propagation-in both systems(3,4). Despite these intense parallel efforts, flatbands have never been shown to affect the core interaction between free electrons and photons. Their interaction, pivotal for free-electron lasers(5), microscopy and spectroscopy(6,7), and particle accelerators(8,9), is, in fact, limited by a dimensionality mismatch between localized electrons and extended photons. Here we reveal theoretically that photonic flatbands can overcome this mismatch and thus remarkably boost their interaction. We design flatband resonullces in a silicon-on-insulator photonic crystal slab to control and enhance the associated free-electron radiation by tuning their trajectory and velocity. We observe signatures of flatband enhancement, recording a two-order increase from the conventional diffraction-enabled Smith-Purcell radiation. The enhancement enables polarization shaping of free-electron radiation and characterization of photonic bands through electron-beam measurements. Our results support the use of flatbands as test beds for strong light-electron interaction, particularly relevant for efficient and compact free-electron light sources and accelerators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 613, "Issue": 7942, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 42, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05387-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05387-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936943400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, M; Im, J; Freeman, AJ; Ihm, J; Jin, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Minsung; Im, Jino; Freeman, Arthur J.; Ihm, Jisoon; Jin, Hosub", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switchable S=1/2 and J=1/2 Rashba bands in ferroelectric halide perovskites", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Rashba effect is spin degeneracy lift originated from spin-orbit coupling under inversion symmetry breaking and has been intensively studied for spintronics applications. However, easily implementable methods and corresponding materials for directional controls of Rashba splitting are still lacking. Here, we propose organic-inorganic hybrid metal halide perovskites as 3D Rashba systems driven by bulk ferroelectricity. In these materials, it is shown that the helical direction of the angular momentum texture in the Rashba band can be controlled by external electric fields via ferroelectric switching. Our tight-binding analysis and first-principles calculations indicate that S = 1/2 and J = 1/2 Rashba bands directly coupled to ferroelectric polarization emerge at the valence and conduction band edges, respectively. The coexistence of two contrasting Rashba bands having different compositions of the spin and orbital angular momentum is a distinctive feature of these materials. With recent experimental evidence for the ferroelectric response, the halide perovskites will be, to our knowledge, the first practical realization of the ferroelectric-coupled Rashba effect, suggesting novel applications to spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2014, "Volume": 111, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6900, "End Page": 6904, "Article Number": null, "DOI": "10.1073/pnas.1405780111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1405780111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335798000045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mustapha, T; Misni, N; Ithnin, NR; Daskum, AM; Unyah, NZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mustapha, Tijjani; Misni, Norashiqin; Ithnin, Nur Raihana; Daskum, Abdullahi Muhammad; Unyah, Ngah Zasmy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Review on Plants and Microorganisms Mediated Synthesis of Silver nulloparticles, Role of Plants Metabolites and Applications", "Source Title": "INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silver nulloparticles are one of the most extensively studied nullomaterials due to their high stability and low chemical reactivity in comparison to other metals. They are commonly synthesized using toxic chemical reducing agents which reduce metal ions into uncharged nulloparticles. However, in the last few decades, several efforts were made to develop green synthesis methods to avoid the use of hazardous materials. The natural biomolecules found in plants such as proteins/enzymes, amino acids, polysaccharides, alkaloids, alcoholic compounds, and vitamins are responsible for the formation of silver nulloparticles. The green synthesis of silver nulloparticles is an eco-friendly approach, which should be further explored for the potential of different plants to synthesize nulloparticles. In the present review we describe the green synthesis of nulloparticles using plants, bacteria, and fungi and the role of plant metabolites in the synthesis process. Moreover, the present review also describes some applications of silver nulloparticles in different aspects such as antimicrobial, biomedicine, mosquito control, environment and wastewater treatment, agricultural, food safety, and food packaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 19, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 674, "DOI": "10.3390/ijerph19020674", "DOI Link": "http://dx.doi.org/10.3390/ijerph19020674", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Public, Environmental & Occupational Health", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748058100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, YF; Chen, S; Zhang, Q; Li, L; Zhao, LM; Zhang, H; Tang, DY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Yufeng; Chen, Si; Zhang, Qian; Li, Lei; Zhao, Luming; Zhang, Han; Tang, Dingyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vector soliton fiber laser passively mode locked by few layer black phosphorus-based optical saturable absorber", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on the optical saturable absorption of few-layer black phosphorus nulloflakes and demonstrate its application for the generation of vector solitons in an erbium-doped fiber laser. By incorporating the black phosphorus nulloflakes-based saturable absorber (SA) into an all-fiber erbium-doped fiber laser cavity, we are able to obtain passive mode-locking operation with soliton pulses down to similar to 670 fs. The properties and dynamics of the as-generated vector solitons are experimentally investigated. Our results show that BP nulloflakes could be developed as an effective SA for ultrashort pulse fiber lasers, particularly for the generation of vector soliton pulses in fiber lasers. (C) 2016 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2016, "Volume": 24, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 25933, "End Page": 25942, "Article Number": null, "DOI": "10.1364/OE.24.025933", "DOI Link": "http://dx.doi.org/10.1364/OE.24.025933", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388414600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baranwal, J; Barse, B; Fais, A; Delogu, GL; Kumar, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baranwal, Jaya; Barse, Brajesh; Fais, Antonella; Delogu, Giovanna Lucia; Kumar, Amit", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biopolymer: A Sustainable Material for Food and Medical Applications", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biopolymers are a leading class of functional material suitable for high-value applications and are of great interest to researchers and professionals across various disciplines. Interdisciplinary research is important to understand the basic and applied aspects of biopolymers to address several complex problems associated with good health and well-being. To reduce the environmental impact and dependence on fossil fuels, a lot of effort has gone into replacing synthetic polymers with biodegradable materials, especially those derived from natural resources. In this regard, many types of natural or biopolymers have been developed to meet the needs of ever-expanding applications. These biopolymers are currently used in food applications and are expanding their use in the pharmaceutical and medical industries due to their unique properties. This review focuses on the various uses of biopolymers in the food and medical industry and provides a future outlook for the biopolymer industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 983, "DOI": "10.3390/polym14050983", "DOI Link": "http://dx.doi.org/10.3390/polym14050983", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000768932000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Recordati, C; De Maglie, M; Bianchessi, S; Argentiere, S; Cella, C; Mattiello, S; Cubadda, F; Aureli, F; D'Amato, M; Raggi, A; Lenardi, C; Milani, P; Scanziani, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Recordati, Camilla; De Maglie, Marcella; Bianchessi, Silvia; Argentiere, Simona; Cella, Claudia; Mattiello, Silvana; Cubadda, Francesco; Aureli, Federica; D'Amato, Marilena; Raggi, Andrea; Lenardi, Cristina; Milani, Paolo; Scanziani, Eugenio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tissue distribution and acute toxicity of silver after single intravenous administration in mice: nullo-specific and size-dependent effects", "Source Title": "PARTICLE AND FIBRE TOXICOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Silver nulloparticles (AgNPs) are an important class of nullomaterials used as antimicrobial agents for a wide range of medical and industrial applications. However toxicity of AgNPs and impact of their physicochemical characteristics in in vivo models still need to be comprehensively characterized. The aim of this study was to investigate the effect of size and coating on tissue distribution and toxicity of AgNPs after intravenous administration in mice, and compare the results with those obtained after silver acetate administration. Methods: Male CD-1(ICR) mice were intravenously injected with AgNPs of different sizes (10 nm, 40 nm, 100 nm), citrate-or polyvinylpyrrolidone-coated, at a single dose of 10 mg/kg bw. An equivalent dose of silver ions was administered as silver acetate. Mice were euthanized 24 h after the treatment, and silver quantification by ICP-MS and histopathology were performed on spleen, liver, lungs, kidneys, brain, and blood. Results: For all particle sizes, regardless of their coating, the highest silver concentrations were found in the spleen and liver, followed by lung, kidney, and brain. Silver concentrations were significantly higher in the spleen, lung, kidney, brain, and blood of mice treated with 10 nm AgNPs than those treated with larger particles. Relevant toxic effects (midzonal hepatocellular necrosis, gall bladder hemorrhage) were found in mice treated with 10 nm AgNPs, while in mice treated with 40 nm and 100 nm AgNPs lesions were milder or negligible, respectively. In mice treated with silver acetate, silver concentrations were significantly lower in the spleen and lung, and higher in the kidney than in mice treated with 10 nm AgNPs, and a different target organ of toxicity was identified (kidney). Conclusions: Administration of the smallest (10 nm) nulloparticles resulted in enhanced silver tissue distribution and overt hepatobiliary toxicity compared to larger ones (40 and 100 nm), while coating had no relevant impact. Distinct patterns of tissue distribution and toxicity were observed after silver acetate administration. It is concluded that if AgNPs become systemically available, they behave differently from ionic silver, exerting distinct and sizedependent effects, strictly related to the nulloparticulate form.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 29", "Publication Year": 2016, "Volume": 13, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12, "DOI": "10.1186/s12989-016-0124-x", "DOI Link": "http://dx.doi.org/10.1186/s12989-016-0124-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Toxicology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371293000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, X; Youngblood, N; Ríos, C; Cheng, ZG; Wright, CD; Pernice, WHP; Bhaskaran, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xuan; Youngblood, Nathan; Rios, Carlos; Cheng, Zengguang; Wright, C. David; Pernice, Wolfram H. P.; Bhaskaran, Harish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast and reliable storage using a 5 bit, nonvolatile photonic memory cell", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optically storing and addressing data on photonic chips is of particular interest as such capability would eliminate optoelectronic conversion losses in data centers. It would also enable on-chip non-von Neumann photonic computing by allowing multinary data storage with high fidelity. Here, we demonstrate such an optically addressed, multilevel memory capable of storing up to 34 nonvolatile reliable and repeatable levels (over 5 bits) using the phase change material Ge2Sb2Te5 integrated on a photonic waveguide. Crucially, we demonstrate for the first time, to the best of our knowledge, a technique that allows us to program the device with a single pulse regardless of the previous state of the material, providing an order of magnitude improvement over previous demonstrations in terms of both time and energy consumption. We also investigate the influence of write-and-erase pulse parameters on the single-pulse recrystallization, amorphization, and readout error in our multilevel memory, thus tailoring pulse properties for optimum performance. Our work represents a significant step in the development of photonic memories and their potential for novel integrated photonic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2019, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 6, "Article Number": null, "DOI": "10.1364/OPTICA.6.000001", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.6.000001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456199400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, TZ; Li, JT; Roy, JC; Koroma, M; Zhu, ZX; Yang, H; Zhang, L; Ouyang, T; Balogun, MS; Al-Mamun, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Tuzhi; Li, Jingting; Roy, Jagadish Chandra; Koroma, Malcolm; Zhu, Zhixiao; Yang, Hao; Zhang, Lei; Ouyang, Ting; Balogun, M. -Sadeeq; Al-Mamun, Mohammad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hetero-interfacial nickel nitride/vanadium oxynitride porous nullosheets as trifunctional electrodes for HER, OER and sodium ion batteries", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of single electrode with multifunctional purposes for electrochemical devices remains a symbolic challenge in recent technology. This work explores interfacially-rich transition metal nitride hybrid that consist of nickel nitride and vanadium oxynitride (VO0.26N0.52) on robust carbon fiber (de-noted CF/Ni3N/VON) as trifunctional electrode for hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and sodium ion batteries (SIBs). The as-prepared CF/Ni3N/VON exhibits low HER overpo-tential of 48 mV@10 mA cm-2, OER overpotential of 287 mV@10 mA cm-2, and sodium-ion anode storage reversible capacity of 555 mA h g-1@0.2 C. Theoretical analyses reveal that the Ni3N effectively facilitates hydrogen desorption for HER, increases the electrical conductivity for OER, and promotes the Na-ion stor-age intercalation process, while the VON substantially elevates the water dissociation kinetics for HER, accelerates the adsorption of OH* intermediate for OER and enhances the Na-ion surface adsorption stor-age process. Owing to the excellent HER and OER performances of the CF/Ni3N/VON electrode, an overall water splitting device denoted as CF/Ni3N/VON//CF/Ni3N/VON was not only assembled showing an oper-ating voltage of 1.63 V at current density of 10 mA cm-2 but was also successfully self-powered by the assembled CF/Ni3N/VON//CF/Na3V2(PO4)3 flexible sodium ion battery. This work will contribute to the development of efficient and cost-effective flexible integrated electrochemical energy devices. (c) 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 81, "Article Number": null, "DOI": "10.1016/j.jechem.2023.01.064", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2023.01.064", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000951633100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avci, CO; Garello, K; Gabureac, M; Ghosh, A; Fuhrer, A; Alvarado, SF; Gambardella, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avci, Can Onur; Garello, Kevin; Gabureac, Mihai; Ghosh, Abhijit; Fuhrer, Andreas; Alvarado, Santos F.; Gambardella, Pietro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interplay of spin-orbit torque and thermoelectric effects in ferromagnet/normal-metal bilayers", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present harmonic transverse voltage measurements of current-induced thermoelectric and spin-orbit torque (SOT) effects in ferromagnet/normal-metal bilayers, in which thermal gradients produced by Joule heating and SOT coexist and give rise to ac transverse signals with comparable symmetry and magnitude. Based on the symmetry and field dependence of the transverse resistance, we develop a consistent method to separate thermoelectric and SOT measurements. By addressing first ferromagnet/light-metal bilayers with negligible spin-orbit coupling, we show that in-plane current injection induces a vertical thermal gradient whose sign and magnitude are determined by the resistivity difference and stacking order of the magnetic and nonmagnetic layers. We then study ferromagnet/heavy-metal bilayers with strong spin-orbit coupling, showing that second harmonic thermoelectric contributions to the transverse voltage may lead to a significant overestimation of the antidamping SOT. We find that thermoelectric effects are very strong in Ta(6 nm)/Co(2.5 nm) and negligible in Pt(6 nm)/Co(2.5 nm) bilayers. After including these effects in the analysis of the transverse voltage, we find that the antidamping SOTs in these bilayers, after normalization to the magnetization volume, are comparable to those found in thinner Co layers with perpendicular magnetization, whereas the fieldlike SOTs are about an order of magnitude smaller.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 366, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 31", "Publication Year": 2014, "Volume": 90, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 224427, "DOI": "10.1103/PhysRevB.90.224427", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.224427", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349891200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, Y; Wu, YH; Li, B; Mo, TD; Li, Y; Feng, SP; Qu, JK; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Yang; Wu, Yinghong; Li, Bo; Mo, Tiande; Li, Yu; Feng, Shien-Ping; Qu, Jingkui; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development and application of fuel cells in the automobile industry", "Source Title": "JOURNAL OF ENERGY STORAGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The automotive industry consumes a large amount of fossil fuels consequently exacerbating the global environmental and energy crisis and fuel cell electric vehicles (FCEVs) are promising alternatives in the continuous transition to clean energy. This paper summarizes the recent development of fuel cell technologies from the perspectives of the automobile industry and discusses current bottlenecks hindering commercialization of FCEVs. Current status of the fuel cell technology, policies and market prospect of FCEVs, as well as recent progress of FCEVs are reviewed. Polymer electrolyte membrane fuel cells constitute the mainstream and most mature fuel cell technology for automobile applications. Hybridization with an auxiliary battery system will greatly boost the dynamic response of FCEVs. Hydrogen FCEVs have entered the preliminary commercialization stage since 2015 and the market share of FCEVs is expected to grow at a high rate. Challenges encountered by commercialization of FCEVs and future outlook are also discussed. Future efforts are expected to focus on solving problems such as the high cost of fuel cell stack production and maintenullce, insufficient hydrogen supply facilities, insufficient reliability, slow cold start, safety concerns, and immature energy management systems of FCEVs. This review serves as a reference and guide for future technological development and commercialization of FCEVs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 42, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103124, "DOI": "10.1016/j.est.2021.103124", "DOI Link": "http://dx.doi.org/10.1016/j.est.2021.103124", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701815500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Davies, CL; Filip, MR; Patel, JB; Crothers, TW; Verdi, C; Wright, AD; Milot, RL; Giustino, F; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Davies, Christopher L.; Filip, Marina R.; Patel, Jay B.; Crothers, Timothy W.; Verdi, Carla; Wright, Adam D.; Milot, Rebecca L.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bimolecular recombination in methylammonium lead triiodide perovskite is an inverse absorption process", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photovoltaic devices based on metal halide perovskites are rapidly improving in efficiency. Once the Shockley-Queisser limit is reached, charge-carrier extraction will be limited only by radiative bimolecular recombination of electrons with holes. Yet, this fundamental process, and its link with material stoichiometry, is still poorly understood. Here we show that bimolecular charge-carrier recombination in methylammonium lead triiodide perovskite can be fully explained as the inverse process of absorption. By correctly accounting for contributions to the absorption from excitons and electron-hole continuum states, we are able to utilise the van Roosbroeck-Shockley relation to determine bimolecular recombination rate constants from absorption spectra. We show that the sharpening of photon, electron and hole distribution functions significantly enhances bimolecular charge recombination as the temperature is lowered, mirroring trends in transient spectroscopy. Our findings provide vital understanding of band-to-band recombination processes in this hybrid perovskite, which comprise direct, fully radiative transitions between thermalized electrons and holes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 281, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 293, "DOI": "10.1038/s41467-017-02670-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02670-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422745800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HS; Shankar, VV; Catuneanu, A; Kee, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Heung-Sik; Shankar, Vijay V.; Catuneanu, Andrei; Kee, Hae-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kitaev magnetism in honeycomb RuCl3 with intermediate spin-orbit coupling", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intensive studies of the interplay between spin-orbit coupling (SOC) and electronic correlations in transition-metal compounds have recently been undertaken. In particular, j(eff) = 1/2 bands on a honeycomb lattice provide a pathway to realize Kitaev's exactly solvable spin model. However, since current wisdom requires strong atomic SOC to make j(eff) = 1/2 bands, studies have been limited to iridium oxides. Contrary to this expectation, we demonstrate how Kitaev interactions arise in 4d-orbital honeycomb alpha-RuCl3, despite having significantly weaker SOC than the iridium oxides, via assistance from electron correlations. A strong-coupling spin model for these correlation-assisted j(eff) = 1/2 bands is derived, in which large antiferromagnetic Kitaev interactions emerge along with ferromagnetic Heisenberg interactions. Our analyses suggest that the ground state is a zigzag-ordered phase lying close to the antiferromagnetic Kitaev spin liquid. Experimental implications for angle-resolved photoemission spectroscopy, neutron scattering, and optical conductivities are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2015, "Volume": 91, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 241110, "DOI": "10.1103/PhysRevB.91.241110", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.91.241110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356481200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Galarraga, H; Lados, DA; Dehoff, RR; Kirka, MM; nulldwana, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Galarraga, Haize; Lados, Diana A.; Dehoff, Ryan R.; Kirka, Michael M.; nulldwana, Peeyush", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of the microstructure and porosity on properties of Ti-6Al-4V ELI alloy fabricated by electron beam melting (EBM)", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron beam melting (EBM) is a metal powder bed fusion additive manufacturing (AM) technology that makes possible the fabrication of three-dimensional near-net-shaped parts directly from computer models. EBM technology has been continuously evolving, optimizing the properties and the microstructure of the as-fabricated alloys. Ti-6Al-4V ELI (Extra Low Interstitials) titanium alloy is the most widely used and studied alloy for this technology and is the focus of this work. Several research works have been completed to study the mechanisms of microstructure formation, evolution, and its subsequent influence on mechanical properties of the alloy. However, the relationship is not completely understood, and more systematic research work is necessary in order to attain a better understanding of these features. In this work, samples fabricated at different locations, orientations, and distances from the build platform have been characterized, studying the relationship of these variables with the resulting material intrinsic characteristics and properties (surface topography, microstructure, porosity, micro-hardness and static mechanical properties). This study has revealed that porosity is the main factor controlling mechanical properties relative to the other studied variables. Therefore, in future process development, decreasing the porosity should be considered the primary goal in order to improve mechanical properties. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 47, "End Page": 57, "Article Number": null, "DOI": "10.1016/j.addma.2016.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2016.02.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435752200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YK; Zhuang, Y; Wang, LL; Tang, H; Meng, XF; She, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yukun; Zhuang, Yan; Wang, Lele; Tang, Hua; Meng, Xianfeng; She, Xilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing 0D/1D Ag3PO4/TiO2 S-scheme heterojunction for efficient photodegradation and oxygen evolution", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An S-scheme heterojunction photocatalyst is capable of boosting photogenerated carrier separation and transfer, thus maintaining high photooxidation and photoredox ability. Herein, a 0D Ag3PO4 nulloparticles (NPs)/1D TiO2 nullofibers (NFs) S-scheme heterojunction with intimate interfacial contact was designed via the the hydro-thermal method. Benefiting from the abundant hydroxyl groups and size confinement effect of TiO2 NFs, the average diameter of the Ag3PO4 nulloparticles decreased from 100 to 22 nm, which favored the construction of a 0D/1D geometry heterojunction. The multifunctional Ag3PO4/TiO2 sample exhibited excellent photocatalytic activity and stability in photocatalytic oxygen production (726 mu mol/g/h) and photocatalytic degradation of various organic contaminullts such as rhodamine B (100%), phenol (60%) and tetracycline hydrochloride (100%). The significant improvements in the photocatalytic performance and stability can be attributed to the intimate interfacial contacts and rich active sites of 0D/1D geometry, fast charge carrier migration, and outstanding photoredox properties induced by the S-scheme charge-transfer route. This work offers a promising strategy for constructing 0D/1D S-scheme heterojunction photocatalysts for improved photocatalytic performance. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 43, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2558, "End Page": 2568, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64099-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64099-3", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884389000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, Q; Chen, XJ; Wang, HJ; Yang, HM; Yang, YJ; Huang, W; Wang, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Qing; Chen, Xijiang; Wang, Haojun; Yang, Huamei; Yang, Yuanjun; Huang, Wei; Wang, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Segmentation of Concrete Cracks by Using Fractal Dimension and UHK-Net", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concrete wall surfaces are prone to cracking for a long time, which affects the stability of concrete structures and may even lead to collapse accidents. In view of this, it is necessary to recognize and distinguish the concrete cracks. Then, the stability of concrete will be known. In this paper, we propose a novel approach by fusing fractal dimension and UHK-Net deep learning network to conduct the semantic recognition of concrete cracks. We first use the local fractal dimensions to study the concrete cracking and roughly determine the location of concrete crack. Then, we use the U-Net Haar-like (UHK-Net) network to construct the crack segmentation network. Ultimately, the different types of concrete crack images are used to verify the advantage of the proposed method by comparing with FCN, U-Net, YOLO v5 network. Results show that the proposed method can not only characterize the dark crack images, but also distinguish small and fine crack images. The pixel accuracy (PA), mean pixel accuracy (MPA), and mean intersection over union (MIoU) of crack segmentation determined by the proposed method are all greater than 90%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 39, "Times Cited, All Databases": 40, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 95, "DOI": "10.3390/fractalfract6020095", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6020095", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806288600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdou, M; Morley, NB; Smolentsev, S; Ying, A; Malang, S; Rowcliffe, A; Ulrickson, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdou, Mohamed; Morley, Neil B.; Smolentsev, Sergey; Ying, Alice; Malang, Siegfried; Rowcliffe, Arthur; Ulrickson, Mike", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blanket/first wall challenges and required R&D on the pathway to DEMO", "Source Title": "FUSION ENGINEERING AND DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The breeding blanket with integrated first wall (FW) is the key nuclear component for power extraction, tritium fuel sustainability, and radiation shielding in fusion reactors. The ITER device will address plasma burn physics and plasma support technology, but it does not have a breeding blanket. Current activities to develop roadmaps for realizing fusion power recognize the blanket/FW as one of the principal remaining challenges. Therefore, a central element of the current planning activities is focused on the question: what are the research and major facilities required to develop the blanket/FW to a level which enables the design, construction and successful operation of a fusion DEMO? The principal challenges in the development of the blanket/FW are: (1) the Fusion Nuclear Environment - a multiple-field environment (neutrons, heat/particle fluxes, magnetic field, etc.) with high magnitudes and steep gradients and transients; (2) Nuclear Heating in a large volume with sharp gradients - the nuclear heating drives most blanket phenomena, but accurate simulation of this nuclear heating can be done only in a DT-plasma based facility; and (3) Complex Configuration with blanket/first wall/divertor inside the vacuum vessel - the consequence is low fault tolerance and long repair/replacement time. These blanket/FW development challenges result in critical consequences: (a) non-fusion facilities (laboratory experiments) need to be substantial to simulate multiple fields/multiple effects and must be accompanied by extensive modeling; (b) results from non-fusion facilities will be limited and will not fully resolve key technical issues. A DT-plasma based fusion nuclear science facility (FNSF) is required to perform multiple effects and integrated experiments in the fusion nuclear environment; and (c) the Reliability/Availability/Maintainability/Inspectability (RAMI) of fusion nuclear components is a major challenge and is one of the primary reasons why the blanket/FW will pace fusion development toward a DEMO. This paper summarizes the top technical issues and elucidates the primary challenges in developing the blanket/first wall and identifies the key R&D needs in non-fusion and fusion facilities on the path to DEMO. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 100, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2, "End Page": 43, "Article Number": null, "DOI": "10.1016/j.fusengdes.2015.07.021", "DOI Link": "http://dx.doi.org/10.1016/j.fusengdes.2015.07.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365055600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, T; Yin, S; Zhang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Tong; Yin, Shi; Zhang, null", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Energy-Driven Construction Industry: Digital Green Innovation Investment Project Selection of Photovoltaic Building Materials Enterprises Using an Integrated Fuzzy Decision Approach", "Source Title": "SYSTEMS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the context of carbon peak and carbon neutrality, digital green innovation development is becoming more and more important for enterprises. In order to effectively improve green competitiveness and increase profits, photovoltaic building materials enterprises must choose digital green innovation projects for investment. The purpose of this study is to build a reasonable investment project selection framework system and propose appropriate methods for photovoltaic building materials enterprises to help them correctly choose digital green innovation investment projects. This study firstly combines relevant theories and digital green innovation characteristics of target investment projects to build a framework system for photovoltaic building materials enterprises to select investment projects. Secondly, this study innovatively proposes a dynamic intuitionistic fuzzy multi-attribute group decision-making method considering the interaction between attributes. Finally, this study takes Yingli Group as the research object and conducts an empirical study on it to verify the scientific nature and reliability of the framework system and method selection. The results show that the framework system includes four aspects: external support system, commercialization expectation, project operation ability and project operation resources. Yingli Group should choose project A(3) for cooperation. The framework system and method proposed in this study are feasible and can help Yingli Group correctly choose digital green innovation investment projects. At the same time, this study also brings positive enlightenment to other photovoltaic building materials enterprises in the world when choosing digital green innovation investment projects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11, "DOI": "10.3390/systems11010011", "DOI Link": "http://dx.doi.org/10.3390/systems11010011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Social Sciences - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927096100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZW; Li, WJ; Fan, Z; Dong, S; Chen, YH; Qin, MH; Zeng, M; Lu, XB; Zhou, GF; Gao, XS; Liu, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zhiwei; Li, Wenjie; Fan, Zhen; Dong, Shuai; Chen, Yihong; Qin, Minghui; Zeng, Min; Lu, Xubing; Zhou, Guofu; Gao, Xingsen; Liu, Jun-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-ferroelectric implementation of reservoir computing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reservoir computing (RC) offers efficient temporal information processing with low training cost. All-ferroelectric implementation of RC is appealing because it can fully exploit the merits of ferroelectric memristors (e.g., good controllability); however, this has been undemonstrated due to the challenge of developing ferroelectric memristors with distinctly different switching characteristics specific to the reservoir and readout network. Here, we experimentally demonstrate an all-ferroelectric RC system whose reservoir and readout network are implemented with volatile and nonvolatile ferroelectric diodes (FDs), respectively. The volatile and nonvolatile FDs are derived from the same Pt/BiFeO3/SrRuO3 structure via the manipulation of an imprint field (E-imp). It is shown that the volatile FD with E-imp exhibits short-term memory and nonlinearity while the nonvolatile FD with negligible E-imp displays long-term potentiation/depression, fulfilling the functional requirements of the reservoir and readout network, respectively. Hence, the all-ferroelectric RC system is competent for handling various temporal tasks. In particular, it achieves an ultralow normalized root mean square error of 0.017 in the Henon map time-series prediction. Besides, both the volatile and nonvolatile FDs demonstrate long-term stability in ambient air, high endurance, and low power consumption, promising the all-ferroelectric RC system as a reliable and low-power neuromorphic hardware for temporal information processing. While reservoir computing can process temporal information efficiently, its hardware implementation remains a challenge due to the lack of robust and energy efficient hardware. Here, the authors develop an all-ferroelectric reservoir computing system, showing high accuracies and low power consumptions in various tasks like the time-series prediction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39371-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39371-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001018392800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JE; Zhang, ZX; Gu, JG; Zhou, WX; Liang, XY; Zhou, GQ; Han, CC; Xu, SS; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jiaen; Zhang, Zixin; Gu, Jin'ge; Zhou, Weixian; Liang, Xiaoyu; Zhou, Guoqiang; Han, Charles C.; Xu, Shanshan; Liu, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism of a long-term controlled drug release system based on simple blended electrospun fibers", "Source Title": "JOURNAL OF CONTROLLED RELEASE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Drug delivery systems based on electrospun fibers have been under development for many years. However, studies of controllable long-term drug release from electrospun membrane systems and the underlying release mechanisms have seldom been reported. Methods: In this study, electrospun membrane drug delivery systems consisting of the antibiotic ciprofloxacin hydrochloride and FDA-approved polymers are fabricated. Different second-component polymers are introduced to change the properties of a poly(D,L-lactide-co-glycolide) (PLGA) matrix, thereby altering the drug release behavior. On the basis of observations of morphology, cumulative release profiles, and determinations of release duration, the drug release kinetics and critical characteristics influencing drug release behavior are discussed. Results: It is found that the drug release profiles can be divided into three stages according to the rate of drug release. Stage I is controlled by fiber swelling and diffusion according to Fick's second law. Stage II is controlled by diffusion through a fused membrane structure, which results in very slow drug release. Stage III is controlled by polymer degradation and involves release of the remaining drug. Conclusions: The results of this study of release mechanisms should provide a basis for adjustments of drug release dosage and duration, thereby contributing to the development of drug delivery systems satisfying clinical requirements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2020, "Volume": 320, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": 346, "Article Number": null, "DOI": "10.1016/j.jconrel.2020.01.020", "DOI Link": "http://dx.doi.org/10.1016/j.jconrel.2020.01.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522794800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, GM; Yang, YF; Zhang, FC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Guang-Ming; Yang, Yi-Feng; Zhang, Fu-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-doped Mott insulator for parent compounds of nickelate superconductors", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose the parent compound of the newly discovered superconducting nickelate Nd1-xSrxNiO2 as a self-doped Mott insulator, in which the low-density Nd 5d conduction electrons couple to localized Ni 3d(x2-y2) electrons to form Kondo spin singlets at low temperatures. This proposal is motivated with our analyses of the reported resistivity and Hall coefficient data in the normal state, showing logarithmic temperature dependence at low temperatures. In the strong Kondo coupling limit, we derive a generalized t -J model with both Kondo singlets and nickel holons moving through the lattice of an otherwise nickel spin-1/2 background. The antiferromagnetic long-range order is therefore suppressed as observed in experiments. With Sr doping, the number of holons on the nickel sites increases, giving rise to the superconductivity and a strange metal phase analogous to those in superconducting copper oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2020, "Volume": 101, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20501, "DOI": "10.1103/PhysRevB.101.020501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.101.020501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000505983000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ingebrigtsen, ME; Varley, JB; Kuznetsov, AY; Svensson, BG; Alfieri, G; Mihaila, A; Badstübner, U; Vines, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ingebrigtsen, M. E.; Varley, J. B.; Kuznetsov, A. Yu.; Svensson, B. G.; Alfieri, G.; Mihaila, A.; Badstubner, U.; Vines, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron and intrinsic deep level states in Ga2O3", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using a combination of deep level transient spectroscopy, secondary ion mass spectrometry, proton irradiation, and hybrid functional calculations, we identify two similar deep levels that are associated with Fe impurities and intrinsic defects in bulk crystals and molecular beam epitaxy and hydride vapor phase epitaxi-grown epilayers of beta-Ga2O3. First, our results indicate that Fe-Ga, and not an intrinsic defect, acts as the deep acceptor responsible for the often dominating E2 level at similar to 0.78 eV below the conduction band minimum. Second, by provoking additional intrinsic defect generation via proton irradiation, we identified the emergence of a new level, labeled as E2*, having the ionization energy very close to that of E2, but exhibiting an order of magnitude larger capture cross section. Importantly, the properties of E2* are found to be consistent with its intrinsic origin. As such, contradictory opinions of a long standing literature debate on either extrinsic or intrinsic origin of the deep acceptor in question converge accounting for possible contributions from E2 and E2* in different experimental conditions. (C) 2018 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http:// creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2018, "Volume": 112, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42104, "DOI": "10.1063/1.5020134", "DOI Link": "http://dx.doi.org/10.1063/1.5020134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423724300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Kravchenko, II; Wang, H; Zheng, HY; Gu, G; Valentine, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, You; Kravchenko, Ivan I.; Wang, Hao; Zheng, Hanyu; Gu, Gong; Valentine, Jason", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional metaoptics based on bilayer metasurfaces", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical metasurfaces have become versatile platforms for manipulating the phase, amplitude, and polarization of light. A platform for achieving independent control over each of these properties, however, remains elusive due to the limited engineering space available when using a single-layer metasurface. For instance, multiwavelength metasurfaces suffer from performance limitations due to space filling constraints, while control over phase and amplitude can be achieved, but only for a single polarization. Here, we explore bilayer dielectric metasurfaces to expand the design space for metaoptics. The ability to independently control the geometry and function of each layer enables the development of multifunctional metaoptics in which two or more optical properties are independently designed. As a proof of concept, we demonstrate multiwavelength holograms, multiwavelength waveplates, and polarization-insensitive 3D holograms based on phase and amplitude masks. The proposed architecture opens a new avenue for designing complex flat optics with a wide variety of functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2019, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 80, "DOI": "10.1038/s41377-019-0193-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-019-0193-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483658300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, QL; Zhao, C; Qu, ML; Xiong, LH; Escano, LI; Hojjatzadeh, SMH; Parab, ND; Fezzaa, K; Everhart, W; Sun, T; Chen, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Qilin; Zhao, Cang; Qu, Minglei; Xiong, Lianghua; Escano, Luis, I; Hojjatzadeh, S. Mohammad H.; Parab, Niranjan D.; Fezzaa, Kamel; Everhart, Wes; Sun, Tao; Chen, Lianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-situ characterization and quantification of melt pool variation under constant input energy density in laser powder bed fusion additive manufacturing process", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Size and shape of a melt pool play a critical role in determining the microstructure in additively manufactured metals. However, it is very challenging to directly characterize the size and shape of the melt pool beneath the surface of the melt pool during the additive manufacturing process. Here, we report the direct observation and quantification of melt pool variation during the laser powder bed fusion (LPBF) additive manufacturing process under constant input energy density by in-situ high-speed high-energy x-ray imaging. We show that the melt pool can undergo different melting regimes and both the melt pool dimension and melt pool volume can have orders-of-magnitude change under a constant input energy density. Our analysis shows that the significant melt pool variation cannot be solely explained by the energy dissipation rate. We found that energy absorption changes significantly under a constant input energy density, which is another important cause of melt pool variation. Our further analysis reveals that the significant change in energy absorption originates from the separate roles of laser power and scan speed in depression zone development. The results reported here are important for understanding the laser powder bed fusion additive manufacturing process and guiding the development of better metrics for processing parameter design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 28, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 600, "End Page": 609, "Article Number": null, "DOI": "10.1016/j.addma.2019.04.021", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2019.04.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000492672300057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Zhang, N; Gao, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chi; Zhang, Ni; Gao, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lessons learned: how to report XPS data incorrectly about lead-halide perovskites", "Source Title": "MATERIALS CHEMISTRY FRONTIERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "X-Ray photoelectron spectroscopy is a powerful tool for identifying the interactions of additives or surface treatments with components in lead halide perovskites. However, with the increasing number of studies using XPS, inaccurate or faulty data analysis has been encountered during a literature survey. Herein, we describe the fundamental principle of chemical shifts of Pb atoms in XPS and critically review the commonly seen mistakes in the literature: (i) misinterpretation of the XPS mechanism; (ii) misinterpretations due to disturbed chemical environments; (iii) lack of awareness of the properties of the passivator; iv. misquoted references. We hope that this perspective can help the community avoid the pitfalls in applying the XPS technique and in explaining their experimental results.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2023, "Volume": 7, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3797, "End Page": 3802, "Article Number": null, "DOI": "10.1039/d3qm00574g", "DOI Link": "http://dx.doi.org/10.1039/d3qm00574g", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028679800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choudhary, K; DeCost, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choudhary, Kamal; DeCost, Brian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomistic Line Graph Neural Network for improved materials property predictions", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graph neural networks (GNN) have been shown to provide substantial performance improvements for atomistic material representation and modeling compared with descriptor-based machine learning models. While most existing GNN models for atomistic predictions are based on atomic distance information, they do not explicitly incorporate bond angles, which are critical for distinguishing many atomic structures. Furthermore, many material properties are known to be sensitive to slight changes in bond angles. We present an Atomistic Line Graph Neural Network (ALIGNN), a GNN architecture that performs message passing on both the interatomic bond graph and its line graph corresponding to bond angles. We demonstrate that angle information can be explicitly and efficiently included, leading to improved performance on multiple atomistic prediction tasks. We ALIGNN models for predicting 52 solid-state and molecular properties available in the JARVIS-DFT, Materials project, and QM9 databases. ALIGNN can outperform some previously reported GNN models on atomistic prediction tasks by up to 85% in accuracy with better or comparable model training speed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2021, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 185, "DOI": "10.1038/s41524-021-00650-1", "DOI Link": "http://dx.doi.org/10.1038/s41524-021-00650-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000718821000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pollard, SD; Garlow, JA; Yu, JW; Wang, Z; Zhu, YM; Yang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pollard, Shawn D.; Garlow, Joseph A.; Yu, Jiawei; Wang, Zhen; Zhu, Yimei; Yang, Hyunsoo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of stable Neel skyrmions in cobalt/palladium multilayers with Lorentz transmission electron microscopy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neel skyrmions are of high interest due to their potential applications in a variety of spintronic devices, currently accessible in ultrathin heavy metal/ferromagnetic bilayers and multilayers with a strong Dzyaloshinskii-Moriya interaction. Here we report on the direct imaging of chiral spin structures including skyrmions in an exchange-coupled cobalt/palladium multilayer at room temperature with Lorentz transmission electron microscopy, a high-resolution technique previously suggested to exhibit no Neel skyrmion contrast. Phase retrieval methods allow us to map the internal spin structure of the skyrmion core, identifying a 25 nm central region of uniform magnetization followed by a larger region characterized by rotation from in-to out-of-plane. The formation and resolution of the internal spin structure of room temperature skyrmions without a stabilizing out-of-plane field in thick magnetic multilayers opens up a new set of tools and materials to study the physics and device applications associated with chiral ordering and skyrmions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14761, "DOI": "10.1038/ncomms14761", "DOI Link": "http://dx.doi.org/10.1038/ncomms14761", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395907500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Law, JY; Franco, V; Moreno-Ramírez, LM; Conde, A; Karpenkov, DY; Radulov, I; Skokov, KP; Gutfleisch, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan Law, Jia; Franco, Victorino; Miguel Moreno-Ramirez, Luis; Conde, Alejandro; Karpenkov, Dmitriy Y.; Radulov, Iliya; Skokov, Konstantin P.; Gutfleisch, Oliver", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A quantitative criterion for determining the order of magnetic phase transitions using the magnetocaloric effect", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ideal magnetocaloric material would lay at the borderline of a first-order and a second-order phase transition. Hence, it is crucial to unambiguously determine the order of phase transitions for both applied magnetocaloric research as well as the characterization of other phase change materials. Although Ehrenfest provided a conceptually simple definition of the order of a phase transition, the known techniques for its determination based on magnetic measurements either provide erroneous results for specific cases or require extensive data analysis that depends on subjective appreciations of qualitative features of the data. Here we report a quantitative fingerprint of first-order thermomagnetic phase transitions: the exponent n from field dependence of magnetic entropy change presents a maximum of n > 2 only for first-order thermomagnetic phase transitions. This model-independent parameter allows evaluating the order of phase transition without any subjective interpretations, as we show for different types of materials and for the Bean-Rodbell model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 351, "Times Cited, All Databases": 362, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2680, "DOI": "10.1038/s41467-018-05111-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05111-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438197600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, DY; Li, R; Chen, XH; Chen, C; Wang, CL; Zhang, BX; Li, MJ; Shang, XN; Yu, XM; Gong, SK; Pauporté, T; Yang, H; Ding, LM; Tang, JX; Chen, JZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Deyu; Li, Ru; Chen, Xihan; Chen, Cong; Wang, Chenglin; Zhang, Boxue; Li, Mengjia; Shang, Xueni; Yu, Xuemeng; Gong, Shaokuan; Pauporte, Thierry; Yang, Hua; Ding, Liming; Tang, JianXin; Chen, Jiangzhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Managing Interfacial Defects and Carriers by Synergistic Modulation of Functional Groups and Spatial Conformation for High-Performance Perovskite Photovoltaics Based on Vacuum Flash Method", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interfacial nonradiative recombination loss is a huge barrier to advance the photovoltaic performance. Here, one effective interfacial defect and carrier dynamics management strategy by synergistic modulation of functional groups and spatial conformation of ammonium salt molecules is proposed. The surface treatment with 3-ammonium propionic acid iodide (3-APAI) does not form 2D perovskite passivation layer while the propylammonium ions and 5-aminopentanoic acid hydroiodide post-treatment lead to the formation of 2D perovskite passivation layers. Due to appropriate alkyl chain length, theoretical and experimental results manifest that -COOH and -NH3+ groups in 3-APAI molecules can form coordination bonding with undercoordinated Pb2+ and ionic bonding and hydrogen bonding with octahedron PbI64-, respectively, which makes both groups be simultaneously firmly anchored on the surface of perovskite films. This will strengthen defect passivation effect and improve interfacial carrier transport and transfer. The synergistic effect of functional groups and spatial conformation confers 3-APAI better defect passivation effect than 2D perovskite layers. The 3-APAI-modified device based on vacuum flash technology achieves an alluring peak efficiency of 24.72% (certified 23.68%), which is among highly efficient devices fabricated without antisolvents. Furthermore, the encapsulated 3-APAI-modified device degrades by less than 4% after 1400 h of continuous one sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 35, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202301028", "DOI Link": "http://dx.doi.org/10.1002/adma.202301028", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000974366700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Zheng, XW; Liu, M; Zhao, N; Luo, AP; Luo, ZC; Xu, WC; Zhang, H; Zhao, CJ; Wen, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hao; Zheng, Xu-Wu; Liu, Meng; Zhao, Nian; Luo, Ai-Ping; Luo, Zhi-Chao; Xu, Wen-Cheng; Zhang, Han; Zhao, Chu-Jun; Wen, Shuang-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Femtosecond pulse generation from a topological insulator mode-locked fiber laser", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We reported on the generation of femtosecond pulse in a fiber ring laser by using a polyvinyl alcohol (PVA)-based topological insulator (TI), Bi2Se3 saturable absorber (SA). The PVA-TI composite has a low saturable optical intensity of 12 MW/cm(2) and a modulation depth of similar to 3.9%. By incorporating the fabricated PVA-TISA into a fiber laser, mode-locking operation could be achieved at a low pump threshold of 25 mW. After an optimization of the cavity parameters, optical pulse with similar to 660 fs centered at 1557.5 nm wavelength had been generated. The experimental results demonstrate that the PVA could be an excellent host material for fabricating high-performance TISA, and also indicate that the filmy PVA-TISA is indeed a good candidate for ultrafast saturable absorption device. (C) 2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2014, "Volume": 22, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6868, "End Page": 6873, "Article Number": null, "DOI": "10.1364/OE.22.006868", "DOI Link": "http://dx.doi.org/10.1364/OE.22.006868", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333579300066", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shapeev, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shapeev, Alexander V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOMENT TENSOR POTENTIALS: A CLASS OF SYSTEMATICALLY IMPROVABLE INTERATOMIC POTENTIALS", "Source Title": "MULTISCALE MODELING & SIMULATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Density functional theory offers a very accurate way of computing materials properties from first principles. However, it is too expensive for modeling large-scale molecular systems whose properties are, in contrast, computed using interatomic potentials. The present paper considers, from a mathematical point of view, the problem of constructing interatomic potentials that approximate a given quantum-mechanical interaction model. In particular, a new class of systematically improvable potentials is proposed, analyzed, and tested on an existing quantum-mechanical database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 944, "Times Cited, All Databases": 1033, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1153, "End Page": 1173, "Article Number": null, "DOI": "10.1137/15M1054183", "DOI Link": "http://dx.doi.org/10.1137/15M1054183", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388444300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Teicher, SML; Kautzsch, L; Sarte, PM; Ratcliff, N; Harter, J; Seshadri, R; Wilson, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Teicher, Samuel M. L.; Kautzsch, Linus; Sarte, Paul M.; Ratcliff, Noah; Harter, John; Seshadri, Ram; Wilson, Stephen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fermi Surface Mapping and the Nature of Charge-Density-Wave Order in the Kagome Superconductor CsV3Sb5", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recently discovered family of AV(3)Sb(5) (A: K, Rb Cs) kagome metals possess a unique combination of nontrivial band topology, superconducting ground states, and signatures of electron correlations manifest via competing charge density wave order. Little is understood regarding the nature of the charge density wave (CDW) instability inherent to these compounds and the potential correlation with the onset of a large anomalous Hall response. To understand the impact of the CDWorder on the electronic structure in these systems, we present quantum oscillation measurements on single crystals of CsV(3)b(5). Our data provide direct evidence that the CDWinvokes a substantial reconstruction of the Fermi surface pockets associated with the vanadium orbitals and the kagome lattice framework. In conjunction with density functional theory modeling, we are able to identify split oscillation frequencies originating from reconstructed pockets built from vanadium orbitals and Dirac-like bands. Complementary diffraction measurements are further able to demonstrate that the CDW instability has a correlated phasing of distortions between neighboring V3Sb5 planes, and the average structure in the CDW state is proposed. These results provide critical insights into the underlying CDW instability in AV(3)Sb(5) kagome metals and support minimal models of CDW order arising from within the vanadium-based kagome lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2021, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41030, "DOI": "10.1103/PhysRevX.11.041030", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.041030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719457800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZQ; Xu, XT; Wang, K; Jiang, D; Meng, FY; Lu, T; Yamauchi, Y; Pan, LK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zeqiu; Xu, Xingtao; Wang, Kai; Jiang, Dong; Meng, Fanyue; Lu, Ting; Yamauchi, Yusuke; Pan, Likun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid of pyrazine based π-conjugated organic molecule and MXene for hybrid capacitive deionization", "Source Title": "SEPARATION AND PURIFICATION TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we report a hybrid material of pyrazine based pi-conjugated organic molecule, hexaazatrinaph-thalene (HATN), and MXene. In this hybrid, MXene serves as a conductive substrate and HATN provides multiple electroactive sites, which are jointly combined to build a unique 3D structure with more ion transport channels for accelerating the charge transfer and ion diffusion rates. The as-obtained HATN/MXene composite displays a superior desalination capacity of 57.5 mg g(-1) with an excellent desalination rate of 13.2 mg g(-1) min(-1) and good long-term stability. This work provides a meaningful guidance for designing and applying organic molecules in capacitive deionization field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2023, "Volume": 315, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123628, "DOI": "10.1016/j.seppur.2023.123628", "DOI Link": "http://dx.doi.org/10.1016/j.seppur.2023.123628", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000976564600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dirnberger, F; Quan, JM; Bushati, R; Diederich, GM; Florian, M; Klein, J; Mosina, K; Sofer, Z; Xu, XD; Kamra, A; Garcia-Vidal, FJ; Alù, A; Menon, VM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dirnberger, Florian; Quan, Jiamin; Bushati, Rezlind; Diederich, Geoffrey M.; Florian, Matthias; Klein, Julian; Mosina, Kseniia; Sofer, Zdenek; Xu, Xiaodong; Kamra, Akashdeep; Garcia-Vidal, Francisco J.; Alu, Andrea; Menon, Vinod M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magneto-optics in a van der Waals magnet tuned by self-hybridized polaritons", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling quantum materials with light is of fundamental and technological importance. By utilizing the strong coupling of light and matter in optical cavities1-3, recent studies were able to modify some of their most defining features4-6. Here we study the magneto-optical properties of a van der Waals magnet that supports strong coupling of photons and excitons even in the absence of external cavity mirrors. In this material-the layered magnetic semiconductor CrSBr-emergent light-matter hybrids called polaritons are shown to substantially increase the spectral bandwidth of correlations between the magnetic, electronic and optical properties, enabling largely tunable optical responses to applied magnetic fields and magnons. Our results highlight the importance of exciton-photon self-hybridization in van der Waals magnets and motivate novel directions for the manipulation of quantum material properties by strong light-matter coupling. In the layered magnetic semiconductor CrSBr, emergent light-matter hybrids (polaritons) increase the spectral bandwidth of correlations between the magnetic, electronic and optical properties, enabling largely tunable optical responses to applied magnetic fields and magnons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2023, "Volume": 620, "Issue": 7974, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 533, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06275-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06275-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055488300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HM; Xie, RK; Luo, YT; Cui, ZC; Yu, QM; Gao, ZQ; Zhang, ZY; Yang, FN; Kang, X; Ge, SY; Li, SH; Gao, XF; Chai, GL; Liu, L; Liu, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Heming; Xie, Ruikuan; Luo, Yuting; Cui, Zhicheng; Yu, Qiangmin; Gao, Zhiqiang; Zhang, Zhiyuan; Yang, Fengning; Kang, Xin; Ge, Shiyu; Li, Shaohai; Gao, Xuefeng; Chai, Guoliang; Liu, Le; Liu, Bilu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual interfacial engineering of a Chevrel phase electrode material for stable hydrogen evolution at 2500 mA cm-2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing stable electrodes which function over long timescales at large current density is essential for the industrial realization and implementation of water electrolysis. However, rapid gas bubble detachment at large current density usually results in peeling-off of electrocatalysts and performance degradation, especially for long term operations. Here we construct a mechanically-stable, all-metal, and highly active CuMo6S8/Cu electrode by in-situ reaction between MoS2 and Cu. The Chevrel phase electrode exhibits strong binding at the electrocatalyst-support interface with weak adhesion at electrocatalyst-bubble interface, in addition to fast hydrogen evolution and charge transfer kinetics. These features facilitate the achievement of large current density of 2500 mA cm(-2) at a small overpotential of 334 mV which operate stably at 2500 mA cm(-2) for over 100 h. In-situ total internal reflection imaging at micrometer level and mechanical tests disclose the relationships of two interfacial forces and performance of electrocatalysts. This dual interfacial engineering strategy can be extended to construct stable and high-performance electrodes for other gas-involving reactions. Stable electrodes which operate at large current density are essential for industrial water electrolysis. Here, a highly active Chevrel phase electrode is reported to achieve 2500 mA/cm(-2) current density for 300 hours at small overpotentials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6382, "DOI": "10.1038/s41467-022-34121-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-34121-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874935700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, JJ; Guo, Y; Qi, JL; Yao, WD; Yu, SX; Liu, WL; Guo, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Jiajing; Guo, Yue; Qi, Jing-Li; Yao, Wen-Dong; Yu, Su-Xin; Liu, Wenlong; Guo, Sheng-Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-Stimuli Responsive Luminescence and Domino Phase Transition of Hybrid Copper Halides with Nonlinear Optical Switching Behavior", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although phase transition materials (PTMs) under external stimuli are of great research interest duo to their rich potential applications, it is still challenging to explore multi-responsive PTMs. Herein, two different phases of organic-inorganic hybrid copper-based halides, alpha- and beta-Gua(3)Cu(2)I(5) (Gua(+)=CN3H6+), were synthesized by solvent evaporation method, which they crystalize in the noncentrosymmetric space group Fdd2 with zero-dimensional structure and centrosymmetric space group C2/c with one-dimensional metal-halogen framework, respectively. Interestingly, it is firstly demonstrated that Gua(3)Cu(2)I(5) simultaneously possesses reversible PL conversion and NLO switching properties in response to thermal stimulus. Strikingly, apart from heat, its structural phase transition can also be triggered by crystalline-phase-recognition (CPR) and mechanical force. These new findings may pave a path for future exploration of PTMs with multiple physical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2023, "Volume": 62, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202301937", "DOI Link": "http://dx.doi.org/10.1002/anie.202301937", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955570800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, MR; Ji, C; Tan, JB; Du, BQ; Zhao, XF; Yu, J; Man, BY; Xu, KC; Zhang, C; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Mingrui; Ji, Chang; Tan, Jibing; Du, Baoqiang; Zhao, Xiaofei; Yu, Jing; Man, Baoyuan; Xu, Kaichen; Zhang, Chao; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectrically modulate the Fermi level of graphene oxide to enhance SERS response", "Source Title": "OPTO-ELECTRONIC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface-enhanced Raman scattering (SERS) substrates based on chemical mechanism (CM) have received widespread attentions for the stable and repeatable signal output due to their excellent chemical stability, uniform molecular adsorption and controllable molecular orientation. However, it remains huge challenges to achieve the optimal SERS signal for diverse molecules with different band structures on the same substrate. Herein, we demonstrate a graphene oxide (GO) energy band regulation strategy through ferroelectric polarization to facilitate the charge transfer process for improving SERS activity. The Fermi level (Ef) of GO can be flexibly manipulated by adjusting the ferroelectric polarization direction or the temperature of the ferroelectric substrate. Experimentally, kelvin probe force microscopy (KPFM) is employed to quantitatively analyze the Ef of GO. Theoretically, the density functional theory calculations are also performed to verify the proposed modulation mechanism. Consequently, the SERS response of probe molecules with different band structures (R6G, CV, MB, PNTP) can be improved through polarization direction or temperature changes without the necessity to redesign the SERS substrate. This work provides a novel insight into the SERS substrate design based on CM and is expected to be applied to other two-dimensional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 154, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2023, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 230094, "DOI": "10.29026/oea.2023.230094", "DOI Link": "http://dx.doi.org/10.29026/oea.2023.230094", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001106360800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, GX; Chen, MD; Ishaq, M; Li, XR; Tang, R; Zheng, ZH; Su, ZH; Fan, P; Zhang, XH; Chen, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Guangxing; Chen, Mingdong; Ishaq, Muhammad; Li, Xinru; Tang, Rong; Zheng, Zhuanghao; Su, Zhenghua; Fan, Ping; Zhang, Xianghua; Chen, Shuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal Growth Promotion and Defects Healing Enable Minimum Open-Circuit Voltage Deficit in Antimony Selenide Solar Cells", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimony selenide (Sb2Se3) is an ideal photovoltaic candidate profiting from its advantageous material characteristics and superior optoelectronic properties, and has gained considerable development in recent years. However, the further device efficiency breakthrough is largely plagued by severe open-circuit voltage (V-OC) deficit under the existence of multiple defect states and detrimental recombination loss. In this work, an effective absorber layer growth engineering involved with vapor transport deposition and post-selenization is developed to grow Sb2Se3 thin films. High-quality Sb2Se3 with large compact crystal grains, benign [hk1] growth orientation, stoichiometric chemical composition, and suitable direct bandgap are successfully fulfilled under an optimized post-selenization scenario. Planar Sb2Se3 thin-film solar cells with substrate configuration of Mo/Sb2Se3/CdS/ITO/Ag are constructed. By contrast, such engineering effort can remarkably mitigate the device V-OC deficit, owing to the healed detrimental defects, the suppressed interface and space-charge region recombination, the prolonged carrier lifetime, and the enhanced charge transport. Accordingly, a minimum V-OC deficit of 0.647 V contributes to a record V-OC of 0.513 V, a champion device with highly interesting efficiency of 7.40% is also comparable to those state-of-the-art Sb2Se3 solar cells, paving a bright avenue to broaden its scope of photovoltaic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105142, "DOI": "10.1002/advs.202105142", "DOI Link": "http://dx.doi.org/10.1002/advs.202105142", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747683800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niaki, SA; Haghighat, E; Campbell, T; Poursartip, A; Vaziri, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niaki, Sina Amini; Haghighat, Ehsan; Campbell, Trevor; Poursartip, Anoush; Vaziri, Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physics-informed neural network for modelling the thermochemical curing process of composite-tool systems during manufacture", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a Physics-Informed Neural Network (PINN) to simulate the thermochemical evolution of a composite material on a tool undergoing cure in an autoclave. In particular, we solve the governing coupled system of differential equations - including conductive heat transfer and resin cure kinetics - by optimizing the parameters of a deep neural network (DNN) using a physics-based loss function. To account for the vastly different behaviour of thermal conduction and resin cure, we design a PINN consisting of two disconnected subnetworks, and develop a sequential training algorithm that mitigates instability present in traditional training methods. Further, we incorporate explicit discontinuities into the DNN at the composite-tool interface and enforce known physical behaviour directly in the loss function to improve the solution near the interface. We train the PINN with a technique that automatically adapts the weights on the loss terms corresponding to PDE, boundary, interface, and initial conditions. Finally, we demonstrate that one can include problem parameters as an input to the model - resulting in a surrogate that provides real-time simulation for a range of problem settings - and that one can use transfer learning to significantly reduce the training time for problem settings similar to that of an initial trained model. The performance of the proposed PINN is demonstrated in multiple scenarios with different material thicknesses and thermal boundary conditions. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2021, "Volume": 384, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113959, "DOI": "10.1016/j.cma.2021.113959", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2021.113959", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000677395100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, J; Choi, JH; Kong, K; Han, JH; Park, JH; Kim, N; Lee, E; Kim, D; Kim, J; Chung, D; Jun, S; Kim, M; Yoon, E; Shin, J; Hwang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jinjoo; Choi, Jun Hee; Kong, Kiho; Han, Joo Hun; Park, Jung Hun; Kim, Nakhyun; Lee, Eunsung; Kim, Dongho; Kim, Joosung; Chung, Deukseok; Jun, Shinae; Kim, Miyoung; Yoon, Euijoon; Shin, Jaikwang; Hwang, Sungwoo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically driven mid-submicrometre pixelation of InGaN micro-light-emitting diode displays for augmented-reality glasses", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "InGaN-based blue light-emitting diodes (LEDs), with their high efficiency and brightness, are entering the display industry. However, a significant gap remains between the expectation of highly efficient light sources and their experimental realization into tiny pixels for ultrahigh-density displays for augmented reality. Herein, we report using tailored ion implantation (TIIP) to fabricate highly efficient, electrically-driven pixelated InGaN micro-LEDs (mu LEDs) at the mid-submicrometre scale (line/space of 0.5/0.5 mu m), corresponding to 8,500 pixels per inch (ppi) (RGB). Creating a laterally confined non-radiative region around each pixel with a controlled amount of mobile vacancies, TIIP pixelation produces relatively invariant luminullce, and high pixel distinctiveness, at submicrometre-sized pixels. Moreover, with the incomparable integration capability of TIIP pixelation due to its planar geometry, we demonstrate 2,000 ppi mu LED displays with monolithically integrated thin-film transistor pixel circuits, and 5,000 ppi compatible core technologies. We expect that the demonstrated method will pave the way toward high-performance mu LED displays for seamless augmented-reality glasses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 137, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 449, "End Page": 455, "Article Number": null, "DOI": "10.1038/s41566-021-00783-1", "DOI Link": "http://dx.doi.org/10.1038/s41566-021-00783-1", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000632786400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, CY; Putzke, C; Konyzheva, S; Huang, XW; Gutierrez-Amigo, M; Errea, I; Chen, D; Vergniory, MG; Felser, C; Fischer, MH; Neupert, T; Moll, PJW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Chunyu; Putzke, Carsten; Konyzheva, Sofia; Huang, Xiangwei; Gutierrez-Amigo, Martin; Errea, Ion; Chen, Dong; Vergniory, Maia G.; Felser, Claudia; Fischer, Mark H.; Neupert, Titus; Moll, Philip J. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Switchable chiral transport in charge-ordered kagome metal CsV3Sb5", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When electric conductors differ from their mirror image, unusual chiral transport coefficients appear that are forbidden in achiral metals, such as a non-linear electric response known as electronic magnetochiral anisotropy (eMChA)(1-6). Although chiral transport signatures are allowed by symmetry in many conductors without a centre of inversion, they reach appreciable levels only in rare cases in which an exceptionally strong chiral coupling to the itinerant electrons is present. So far, observations of chiral transport have been limited to materials in which the atomic positions strongly break mirror symmetries. Here, we report chiral transport in the centrosymmetric layered kagome metal CsV3Sb5 observed via second-harmonic generation under an in-plane magnetic field. The eMChA signal becomes significant only at temperatures below T 'approximate to\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${T}<^>{{\\prime} }\\approx $$\\end{document} 35 K, deep within the charge-ordered state of CsV3Sb5 (T-CDW approximate to 94 K). This temperature dependence reveals a direct correspondence between electronic chirality, unidirectional charge order(7) and spontaneous time-reversal symmetry breaking due to putative orbital loop currents(8-10). We show that the chirality is set by the out-of-plane field component and that a transition from left- to right-handed transport can be induced by changing the field sign. CsV3Sb5 is the first material in which strong chiral transport can be controlled and switched by small magnetic field changes, in stark contrast to structurally chiral materials, which is a prerequisite for applications in chiral electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2022, "Volume": 611, "Issue": 7936, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 461, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05127-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05127-9", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000866362700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, CG; Liu, HW; Wang, WQ; Xiang, L; Jiang, J; Shuai, Q; Yang, X; Zhang, T; Zheng, BY; Wang, H; Li, D; Pan, AL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Chenguang; Liu, Huawei; Wang, Wenqiang; Xiang, Li; Jiang, Jie; Shuai, Qin; Yang, Xin; Zhang, Tian; Zheng, Biyuan; Wang, Hui; Li, Dong; Pan, Anlian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical synaptic devices with ultra-low power consumption for neuromorphic computing", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Brain-inspired neuromorphic computing, featured by parallel computing, is considered as one of the most energy-efficient and time-saving architectures for massive data computing. However, photonic synapse, one of the key components, is still suffering high power consumption, potentially limiting its applications in artificial neural system. In this study, we present a BP/CdS heterostructure-based artificial photonic synapse with ultra-low power consumption. The device shows remarkable negative light response with maximum responsivity up to 4.1 x 10(8) A W-1 at V-D = 0.5 V and light power intensity of 0.16 mu W cm(-2) (1.78 x 10(8) A W-1 on average), which further enables artificial synaptic applications with average power consumption as low as 4.78 fi for each training process, representing the lowest among the reported results. Finally, a fully-connected optoelectronic neural network (FONN) is simulated with maximum image recognition accuracy up to 94.1%. This study provides new concept towards the designing of energy-efficient artificial photonic synapse and shows great potential in high-performance neuromorphic vision systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 337, "DOI": "10.1038/s41377-022-01031-z", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-01031-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000889556500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, C; Ma, YW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Chao; Ma, Yanwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconducting materials: Challenges and opportunities for large-scale applications", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconducting materials hold great potential to bring radical changes for electric power and high-field magnet technology, enabling high-efficiency electric power generation, high-capacity loss-less electric power transmission, small light-weight electrical equipment, high-speed maglev transportation, ultra-strong magnetic field generation for high-resolution magnetic resonullce imaging (MRI) systems, nuclear magnetic resonullce (NMR) systems, future advanced high energy particle accelerators, nuclear fusion reactors, and so on. The performance, economy, and operating parameters (temperatures and magnetic fields) of these applications strongly depend on the electromagnetic and mechanical properties, as well as the manufacturing and material cost of superconductors. This perspective examines the basic properties relevant to practical applications and key issues ofwire fabrication for practical superconductingmaterials, and describes their challenges and current state in practical applications. Finally, future perspectives for their opportunities and development in the applications of superconducting power and magnetic technologies are considered.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 24, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102541, "DOI": "10.1016/j.isci.2021.102541", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2021.102541", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667301700043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bykov, M; Fedotenko, T; Chariton, S; Laniel, D; Glazyrin, K; Hanfland, M; Smith, JS; Prakapenka, VB; Mahmood, MF; Goncharov, AF; Ponomareva, AV; Tasnádi, F; Abrikosov, AI; Bin Masood, T; Hotz, I; Rudenko, AN; Katsnelson, MI; Dubrovinskaia, N; Dubrovinsky, L; Abrikosov, IA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bykov, Maxim; Fedotenko, Timofey; Chariton, Stella; Laniel, Dominique; Glazyrin, Konstantin; Hanfland, Michael; Smith, Jesse S.; Prakapenka, Vitali B.; Mahmood, Mohammad F.; Goncharov, Alexander F.; Ponomareva, Alena, V; Tasnadi, Ferenc; Abrikosov, Alexei, I; Bin Masood, Talha; Hotz, Ingrid; Rudenko, Alexander N.; Katsnelson, Mikhail, I; Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Abrikosov, Igor A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Pressure Synthesis of Dirac Materials: Layered van der Waals Bonded BeN4 Polymorph", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-pressure chemistry is known to inspire the creation of unexpected new classes of compounds with exceptional properties. Here, we employ the laser-heated diamond anvil cell technique for synthesis of a Dirac material BeN4. A triclinic phase of beryllium tetranitride tr-BeN4 was synthesized from elements at similar to 85 GPa. Upon decompression to ambient conditions, it transforms into a compound with atomic-thick BeN4 layers interconnected via weak van der Waals bonds and consisting of polyacetylene-like nitrogen chains with conjugated pi systems and Be atoms in square-planar coordination. Theoretical calculations for a single BeN4 layer show that its electronic lattice is described by a slightly distorted honeycomb structure reminiscent of the graphene lattice and the presence of Dirac points in the electronic band structure at the Fermi level. The BeN4 layer, i.e., beryllonitrene, represents a qualitatively new class of 2D materials that can be built of a metal atom and polymeric nitrogen chains and host anisotropic Dirac fermions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2021, "Volume": 126, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 175501, "DOI": "10.1103/PhysRevLett.126.175501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.175501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652836300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Demasius, KU; Phung, T; Zhang, WF; Hughes, BP; Yang, SH; Kellock, A; Han, W; Pushp, A; Parkin, SSP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Demasius, Kai-Uwe; Phung, Timothy; Zhang, Weifeng; Hughes, Brian P.; Yang, See-Hun; Kellock, Andrew; Han, Wei; Pushp, Aakash; Parkin, Stuart S. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced spin-orbit torques by oxygen incorporation in tungsten films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The origin of spin-orbit torques, which are generated by the conversion of charge-to-spin currents in non-magnetic materials, is of considerable debate. One of the most interesting materials is tungsten, for which large spin-orbit torques have been found in thin films that are stabilized in the A15 (beta-phase) structure. Here we report large spin Hall angles of up to approximately -0.5 by incorporating oxygen into tungsten. While the incorporation of oxygen into the tungsten films leads to significant changes in their microstructure and electrical resistivity, the large spin Hall angles measured are found to be remarkably insensitive to the oxygen-doping level (12-44%). The invariance of the spin Hall angle for higher oxygen concentrations with the bulk properties of the films suggests that the spin-orbit torques in this system may originate dominulltly from the interface rather than from the interior of the films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10644, "DOI": "10.1038/ncomms10644", "DOI Link": "http://dx.doi.org/10.1038/ncomms10644", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371020600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mozaffar, M; Bostanabad, R; Chen, W; Ehmann, K; Cao, J; Bessa, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mozaffar, M.; Bostanabad, R.; Chen, W.; Ehmann, K.; Cao, J.; Bessa, M. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep learning predicts path-dependent plasticity", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plasticity theory aims at describing the yield loci and work hardening of a material under general deformation states. Most of its complexity arises from the nontrivial dependence of the yield loci on the complete strain history of a material and its microstructure. This motivated 3 ingenious simplifications that underpinned a century of developments in this field: 1) yield criteria describing yield loci location; 2) associative or nonassociative flow rules defining the direction of plastic flow; and 3) effective stress-strain laws consistent with the plastic work equivalence principle. However, 2 key complications arise from these simplifications. First, finding equations that describe these 3 assumptions for materials with complex microstructures is not trivial. Second, yield surface evolution needs to be traced iteratively, i.e., through a return mapping algorithm. Here, we show that these assumptions are not needed in the context of sequence learning when using recurrent neural networks, diverting the above-mentioned complications. This work offers an alternative to currently established plasticity formulations by providing the foundations for finding history- and microstructure-dependent constitutive models through deep learning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 26", "Publication Year": 2019, "Volume": 116, "Issue": 52, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26414, "End Page": 26420, "Article Number": null, "DOI": "10.1073/pnas.1911815116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1911815116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000504656900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, N; Sun, YL; Shi, WW; Wang, P; Nagaoka, Y; Cai, T; Wu, RZ; Dube, L; Nyiera, HN; Liu, YZ; Mani, T; Wang, XZ; Zhao, J; Chen, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Na; Sun, Yonglei; Shi, Wenwu; Wang, Ping; Nagaoka, Yasutaka; Cai, Tong; Wu, Rongzhen; Dube, Lacie; Nyiera, Hawi N.; Liu, Yuzi; Mani, Tomoyasu; Wang, Xinzhong; Zhao, Jing; Chen, Ou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Type-I CdS/ZnS Core/Shell Quantum Dot-Gold Heterostructural nullocrystals for Enhanced Photocatalytic Hydrogen Generation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing Type-I core/shell quantum dots is of great importance toward fabricating stable and sustainable photocatalysts. However, the application of Type-I systems has been limited due to the strongly confined photogenerated charges by the energy barrier originating from the wide-bandgap shell material. In this project, we found that through the decoration of Au satellite-type domains on the surface of Type-I CdS/ZnS core/shell quantum dots, such an energy barrier can be effectively overcome and an over 400-fold enhancement of photocatalytic H(2 )evolution rate was achieved compared to bare CdS/ZnS quantum dots. Transient absorption spectroscopic studies indicated that the charges can be effectively extracted and subsequently transferred to surrounding molecular substrates in a subpicosecond time scale in such hybrid nullocrystals. Based on density functional theory calculations, the ultrafast charge separation rates were ascribed to the formation of intermediate Au2S layer at the semiconductor-metal interface, which can successfully offset the energy confinement introduced by the ZnS shell. Our findings not only provide insightful understandings on charge carrier dynamics in semiconductor-metal heterostructural materials but also pave the way for the future design of quantum dot-based hybrid photocatalytic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2023, "Volume": 145, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21886, "End Page": 21896, "Article Number": null, "DOI": "10.1021/jacs.3c06065", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c06065", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001074935300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, L; Li, DM; Xie, X; Ji, DD; Li, LW; Li, L; He, ZX; Lu, BA; Liang, SQ; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Long; Li, Dongmin; Xie, Xian; Ji, Dongdong; Li, Liwei; Li, Le; He, Zhangxing; Lu, Bingan; Liang, Shuquan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric double layer design for Zn-based batteries", "Source Title": "ENERGY STORAGE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc-based batteries (ZBs) have recently attracted wide attention energy storage with cost-effectiveness and intrinsic safety. However, it suffers from poor interface stability between the zinc anode and the electrolyte. Although the structure of the electrical double layer (EDL) is the key factor governing the interfacial properties, its understanding is still in infancy due to limited characterization techniques. In this review, we systematically discuss the relationship between interface properties, solvation sheath structure and the components of the Helmholtz layer. The possible transport pathway of zinc ions and the structural evolution mechanism of EDL at the interface are emphasized, with a scientific principle for the EDL regulation to inspire the rational design of future electrolytes and interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102932, "DOI": "10.1016/j.ensm.2023.102932", "DOI Link": "http://dx.doi.org/10.1016/j.ensm.2023.102932", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001066968000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cecchini, L; Mariani, S; Ronzan, M; Mondini, A; Pugno, NM; Mazzolai, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cecchini, Luca; Mariani, Stefano; Ronzan, Marilena; Mondini, Alessio; Pugno, Nicola M.; Mazzolai, Barbara", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4D Printing of Humidity-Driven Seed Inspired Soft Robots", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Geraniaceae seeds represent a role model in soft robotics thanks to their ability to move autonomously across and into the soil driven by humidity changes. The secret behind their mobility and adaptivity is embodied in the hierarchical structures and anatomical features of the biological hygroscopic tissues, geometrically designed to be selectively responsive to environmental humidity. Following a bioinspired approach, the internal structure and biomechanics of Pelargonium appendiculatum (L.f.) wild seeds are investigated to develop a model for the design of a soft robot. The authors exploit the re-shaping ability of 4D printed materials to fabricate a seed-like soft robot, according to the natural specifications and model, and using biodegradable and hygroscopic polymers. The robot mimics the movement and performances of the natural seed, reaching a torque value of approximate to 30 mu N m, an extensional force of approximate to 2.5 mN and it is capable to lift approximate to 100 times its own weight. Driven by environmental humidity changes, the artificial seed is able to explore a sample soil, adapting its morphology to interact with soil roughness and cracks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205146", "DOI Link": "http://dx.doi.org/10.1002/advs.202205146", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922938000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Postberg, F; Khawaja, N; Abel, B; Choblet, G; Glein, CR; Gudipati, MS; Henderson, BL; Hsu, HW; Kempf, S; Klenner, F; Moragas-Klostermeyer, G; Magee, B; Nölle, L; Perry, M; Reviol, R; Schmidt, J; Srama, R; Stolz, F; Tobie, G; Trieloff, M; Waite, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Postberg, Frank; Khawaja, Nozair; Abel, Bernd; Choblet, Gael; Glein, Christopher R.; Gudipati, Murthy S.; Henderson, Bryana L.; Hsu, Hsiang-Wen; Kempf, Sascha; Klenner, Fabian; Moragas-Klostermeyer, Georg; Magee, Brian; Noelle, Lenz; Perry, Mark; Reviol, Rene; Schmidt, Jurgen; Srama, Ralf; Stolz, Ferdinulld; Tobie, Gabriel; Trieloff, Mario; Waite, J. Hunter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macromolecular organic compounds from the depths of Enceladus", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Saturn's moon Enceladus harbours a global water ocean(1), which lies under an ice crust and above a rocky core(2). Through warm cracks in the crust(3) a cryo-volcanic plume ejects ice grains and vapour into space(4-7) that contain materials originating from the ocean(8,9). Hydrothermal activity is suspected to occur deep inside the porous core(10-12), powered by tidal dissipation(13). So far, only simple organic compounds with molecular masses mostly below 50 atomic mass units have been observed in plume material(6,14,15). Here we report observations of emitted ice grains containing concentrated and complex macromolecular organic material with molecular masses above 200 atomic mass units. The data constrain the macromolecular structure of organics detected in the ice grains and suggest the presence of a thin organic-rich film on top of the oceanic water table, where organic nucleation cores generated by the bursting of bubbles allow the probing of Enceladus' organic inventory in enhanced concentrations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 268, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 558, "Issue": 7711, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 564, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0246-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0246-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436594300055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, HL; Yang, J; Ling, TC; Ghataora, GS; Dirar, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Haolin; Yang, Jian; Ling, Tung-Chai; Ghataora, Gurmel S.; Dirar, Samir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Properties of concrete prepared with waste tyre rubber particles of uniform and varying sizes", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Investigations and research into the recent use of rubber particles in concrete has been well documented. However, information on the rubber particle sizes or their distributions within concrete which may also influence the concrete properties is still limited. In this study, three groups of singly-sized rubber particle samples (3 mm, 0.5 mm and 03 mm) and one sample of continuous size grading (prepared by blending the three singly-sized samples to form the same particle distribution curve of sand) were used to replace 20% of the natural fine aggregate by volume. The reference concrete containing 100% sand was also prepared to compare its properties with those of the samples in terms of workability, fresh density, compressive strength, tensile splitting strength, flexural strength and water permeability. The experimental results demonstrated that the rubber particle size affects the concrete's workability and water permeability to a greater extent than the fresh density and strength. Concrete with rubber particles of larger size tends to have a higher workability and fresh density than that with smaller particle sizes. However, the rubber aggregates with smaller or continuously graded particle sizes are shown to have higher strengths and lower water permeability. (C) 2015 The Authors, Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2015, "Volume": 91, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 288, "End Page": 296, "Article Number": null, "DOI": "10.1016/j.jclepro.2014.12.022", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2014.12.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350940400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SQ; Du, JX; Song, Z; Ma, CG; Liu, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shengqiang; Du, Jingxuan; Song, Zhen; Ma, Chonggeng; Liu, Quanlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intervalence charge transfer of Cr3+-Cr3+ aggregation for NIR-II luminescence", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increasing demand for high-contrast biological imaging, non-destructive testing, and infrared night vision can be addressed by the development of high-performance NIR light-emitting materials. Unlike lanthanide (Ln(3+)) with sharpline multiplets and isolated Cr3+ with NIR-I emission, this study reports the first-ever NIR-II broadband luminescence based on the intervalence charge transfer (IVCT) of Cr3+-Cr3+ aggregation in gallate magentoplumbite. In particular, LaMgGa11O19:0.7Cr(3+) exhibits dual-emission (NIR-I, 890 nm and NIR-II, 1200 nm) with a full width at half maximum (FWHM) of 626 nm under 450 nm blue LED excitation. Moreover, this dual-emission exhibits anti-thermal quenching behavior (432% @ 290 K), attributed to the energy transfer among multiple Cr3+ centers. Cryogen absorption spectra, lifetimes decay (2.3 ms), and electron paramagnetic experiments reveal the NIR-II luminescence of the Cr3+-Cr3+. Cr2+-Cr4+ IVCT transition. The application of LaMgGa11O19:0.7Cr(3+) in NIR-II biological imaging as an optical contrast agent, non-destructive testing, and night vision is demonstrated. This work provides new insights into broadband NIRII luminescence under UV-NIR excitation based on the IVCT of Cr3+-Cr3+ aggregation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 181, "DOI": "10.1038/s41377-023-01219-x", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01219-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001033472400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Back, C; Cros, V; Ebert, H; Everschor-Sitte, K; Fert, A; Garst, M; Ma, TP; Mankovsky, S; Monchesky, TL; Mostovoy, M; Nagaosa, N; Parkin, SSP; Pfleiderer, C; Reyren, N; Rosch, A; Taguchi, Y; Tokura, Y; von Bergmann, K; Zang, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Back, C.; Cros, V; Ebert, H.; Everschor-Sitte, K.; Fert, A.; Garst, M.; Ma, Tianping; Mankovsky, S.; Monchesky, T. L.; Mostovoy, M.; Nagaosa, N.; Parkin, S. S. P.; Pfleiderer, C.; Reyren, N.; Rosch, A.; Taguchi, Y.; Tokura, Y.; von Bergmann, K.; Zang, Jiadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The 2020 skyrmionics roadmap", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The notion of non-trivial topological winding in condensed matter systems represents a major area of present-day theoretical and experimental research. Magnetic materials offer a versatile platform that is particularly amenable for the exploration of topological spin solitons in real space such as skyrmions. First identified in non-centrosymmetric bulk materials, the rapidly growing zoology of materials systems hosting skyrmions and related topological spin solitons includes bulk compounds, surfaces, thin films, heterostructures, nullo-wires and nullo-dots. This underscores an exceptional potential for major breakthroughs ranging from fundamental questions to applications as driven by an interdisciplinary exchange of ideas between areas in magnetism which traditionally have been pursued rather independently. The skyrmionics Roadmap provides a review of the present state of the art and the wide range of research directions and strategies currently under way. These are, for instance, motivated by the identification of the fundamental structural properties of skyrmions and related textures, processes of nucleation and annihilation in the presence of non-trivial topological winding, an exceptionally efficient coupling to spin currents generating spin transfer torques at tiny current densities, as well as the capability to purpose-design broad-band spin dynamic and logic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 2", "Publication Year": 2020, "Volume": 53, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 363001, "DOI": "10.1088/1361-6463/ab8418", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/ab8418", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546895900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, SL; Ross, A; Go, D; Baldrati, L; Ren, ZY; Freimuth, F; Becker, S; Kammerbauer, F; Yang, JB; Jakob, G; Mokrousov, Y; Kläui, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Shilei; Ross, Andrew; Go, Dongwook; Baldrati, Lorenzo; Ren, Zengyao; Freimuth, Frank; Becker, Sven; Kammerbauer, Fabian; Yang, Jinbo; Jakob, Gerhard; Mokrousov, Yuriy; Klaeui, Mathias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harnessing Orbital-to-Spin Conversion of Interfacial Orbital Currents for Efficient Spin-Orbit Torques", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current-induced spin-orbit torques (SOTs) allow for the efficient electrical manipulation of magnetism in spintronic devices. Engineering the SOT efficiency is a key goal that is pursued by maximizing the active interfacial spin accumulation or modulating the nonequilibrium spin density that builds up through the spin Hall and inverse spin galvanic effects. Regardless of the origin, the fundamental requirement for the generation of the current-induced torques is a net spin accumulation. We report on the large enhancement of the SOT efficiency in thulium iron garnet (TmIG)/Pt by capping with a CuOx layer. Considering the weak spin-orbit coupling (SOC) of CuOx these surprising findings likely result from an orbital current generated at the interface between CuOx and Pt, which is injected into the Pt layer and converted into a spin current by strong SOC. The converted spin current decays across the Pt layer and exerts a nonlocal torque on TmIG. This additional torque leads to a maximum colossal enhancement of the SOT efficiency of a factor 16 for 1.5 nm of Pt at room temperature, thus opening a path to increase torques while at the same time offering insights into the underlying physics of orbital transport, which has so far been elusive.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 125, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 177201, "DOI": "10.1103/PhysRevLett.125.177201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.177201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000580892200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, QB; Bie, BL; Guo, QN; Yuan, YP; Han, Q; Han, XC; Chen, MW; Zhang, X; Yang, YH; Liu, ML; Liu, P; Deng, HX; Zhou, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Qingbin; Bie, Binglin; Guo, Qianni; Yuan, Yaping; Han, Qi; Han, Xiaocang; Chen, Mingwei; Zhang, Xu; Yang, Yunhuang; Liu, Maili; Liu, Pan; Deng, Hexiang; Zhou, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperpolarized Xe NMR signal advancement by metal-organic framework entrapment in solution", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report hyperpolarized Xe signal advancement by metal-organic framework (MOF) entrapment (Hyper-SAME) in aqueous solution. The Xe-129 NMR signal is drastically promoted by entrapping the Xe into the pores of MOFs. The chemical shift of entrapped Xe-129 is clearly distinguishable from that of free Xe-129 in water, due to the surface and pore environment of MOFs. The influences from the crystal size of MOFs and their concentration in water are studied. A zinc imidazole MOF, zeolitic imidazole framework-8 (ZIF-8), with particle size of 110 nm at a concentration of 100 mg/mL, was used to give an NMR signal with intensity four times that of free Xe-129 in water. Additionally, Hyper-SAME is compatible with hyperpolarized Xe-129 chemical exchange saturation transfer. The Xe-129 NMR signal can be amplified further by combining the two techniques. More importantly, Hyper-SAME provides a way to make detection of hyperpolarized Xe-129 in aqueous solution convenient and broadens the application area of MOFs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2020, "Volume": 117, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17558, "End Page": 17563, "Article Number": null, "DOI": "10.1073/pnas.2004121117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2004121117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000555851800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karube, S; Tanaka, T; Sugawara, D; Kadoguchi, N; Kohda, M; Nitta, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karube, Shutaro; Tanaka, Takahiro; Sugawara, Daichi; Kadoguchi, Naohiro; Kohda, Makoto; Nitta, Junsaku", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Spin-Splitter Torque in Collinear Antiferromagnetic RuO2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin-splitter effect is theoretically predicted to generate an unconventional spin current with x- and z- spin polarization via the spin-split band in antiferromagnets. The generated torque, namely, spin-splitter torque, is effective for the manipulation of magnetization in an adjacent magnetic layer without an external magnetic field for spintronic devices such as MRAM. Here, we study the generation of torque in collinear antiferromagnetic RuO2 with (100), (101), and (001) crystal planes. Next we find all x-, y-, and z-polarized spin currents depending on the Ne ' el vector direction in RuO2(101). For RuO2(100) and (001), only y-polarized spin current was present, which is independent of the Ne ' el vector. Using the z-polarized spin currents, we demonstrate field-free switching of the perpendicular magnetized ferromagnet at room temperature. The spin-splitter torque generated from RuO2 is verified to be useful for the switching phenomenon and paves the way for a further understanding of the detailed mechanism of the spin-splitter effect and for developing antiferromagnetic spin-orbitronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2022, "Volume": 129, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 137201, "DOI": "10.1103/PhysRevLett.129.137201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.129.137201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000865420000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, JQ; Yuan, Q; Tan, MJ; Han, XQ; Gao, MB; Zhang, C; Yang, X; Shi, ZL; Ma, YB; Xiao, H; Zhang, JW; Lu, TB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Jiqing; Yuan, Qing; Tan, Meijie; Han, Xiaoqian; Gao, Mingbin; Zhang, Chao; Yang, Xuan; Shi, Zhaolin; Ma, Yanbin; Xiao, Hai; Zhang, Jiangwei; Lu, Tongbu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing asymmetric double-atomic sites for synergistic catalysis of electrochemical CO2 reduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elucidating the synergistic catalytic mechanism between multiple active centers is of great significance for heterogeneous catalysis; however, finding the corresponding experimental evidence remains challenging owing to the complexity of catalyst structures and interface environment. Here we construct an asymmetric TeN2-CuN3 double-atomic site catalyst, which is analyzed via full-range synchrotron pair distribution function. In electrochemical CO2 reduction, the catalyst features a synergistic mechanism with the double-atomic site activating two key molecules: operando spectroscopy confirms that the Te center activates CO2, and the Cu center helps to dissociate H2O. The experimental and theoretical results reveal that the TeN2-CuN3 could cooperatively lower the energy barriers for the rate-determining step, promoting proton transfer kinetics. Therefore, the TeN2-CuN3 displays a broad potential range with high CO selectivity, improved kinetics and good stability. This work presents synthesis and characterization strategies for double-atomic site catalysts, and experimentally unveils the underpinning mechanism of synergistic catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6164, "DOI": "10.1038/s41467-023-41863-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41863-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001084392600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Islam, F; Shohag, S; Uddin, MJ; Islam, MR; Nafady, MH; Akter, A; Mitra, S; Roy, A; Bin Emran, T; Cavalu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Islam, Fahadul; Shohag, Sheikh; Uddin, Md Jalal; Islam, Md Rezaul; Nafady, Mohamed H.; Akter, Aklima; Mitra, Saikat; Roy, Arpita; Bin Emran, Talha; Cavalu, Simona", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring the Journey of Zinc Oxide nulloparticles (ZnO-NPs) toward Biomedical Applications", "Source Title": "MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of nullotechnology is concerned with the creation and application of materials having a nulloscale spatial dimensioning. Having a considerable surface area to volume ratio, nulloparticles have particularly unique properties. Several chemical and physical strategies have been used to prepare zinc oxide nulloparticles (ZnO-NPs). Still, biological methods using green or natural routes in various underlying substances (e.g., plant extracts, enzymes, and microorganisms) can be more environmentally friendly and cost-effective than chemical and/or physical methods in the long run. ZnO-NPs are now being studied as antibacterial agents in nulloscale and microscale formulations. The purpose of this study is to analyze the prevalent traditional method of generating ZnO-NPs, as well as its harmful side effects, and how it might be addressed utilizing an eco-friendly green approach. The study's primary focus is on the potential biomedical applications of green synthesized ZnO-NPs. Biocompatibility and biomedical qualities have been improved in green-synthesized ZnO-NPs over their traditionally produced counterparts, making them excellent antibacterial and cancer-fighting drugs. Additionally, these ZnO-NPs are beneficial when combined with the healing processes of wounds and biosensing components to trace small portions of biomarkers linked with various disorders. It has also been discovered that ZnO-NPs can distribute and sense drugs. Green-synthesized ZnO-NPs are compared to traditionally synthesized ones in this review, which shows that they have outstanding potential as a potent biological agent, as well as related hazardous properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2160, "DOI": "10.3390/ma15062160", "DOI Link": "http://dx.doi.org/10.3390/ma15062160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000775161600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Lin, QY; Chen, SY; Yang, HB; Liu, K; Pang, B; Xu, T; Si, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Lin, Qingyi; Chen, Siyu; Yang, Hongbin; Liu, Kun; Pang, Bo; Xu, Ting; Si, Chuanling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microencapsulated phase change material through cellulose nullofibrils stabilized Pickering emulsion templating", "Source Title": "ADVANCED COMPOSITES AND HYBRID MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase change materials (PCMs) possess remarkable capability to store and release substantial amounts of energy during the processes of melting and crystallization across a wide temperature range, thus holding great promise in applications related to temperature regulation and thermal energy storage. Herein, to effectively address PCM leakage and enhance thermal conduction, PCM microcapsules with melamine-formaldehyde resin (MF) shell were prepared using in situ polymerization of Pickering emulsions stabilized by cellulose nullofibrils (CNFs). CNFs were selected as the stabilizers for the Pickering emulsions and as reinforcing nullofillers for the MF shell, owing to their excellent emulsifying capability, high mechanical strength, and sustainable nature. Paraffin wax (PW) was utilized as the PCM material. The resulting PCM microcapsules with MF resin shells and PW core had a diameter ranging from 2 to 4 & mu;m. Results showed that microcapsule with the core-shell ratio of 2 (Micro-2.0) exhibited the highest latent heat of crystallization and latent heat of fusion, measuring approximately 128.40 J/g and 120.23 J/g, respectively. The encapsulation efficiency of Micro-2.0 was determined to be approximately 79.84%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 149, "DOI": "10.1007/s42114-023-00725-1", "DOI Link": "http://dx.doi.org/10.1007/s42114-023-00725-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042761300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Preger, Y; Barkholtz, HM; Fresquez, A; Campbell, DL; Juba, BW; Romàn-Kustas, J; Ferreira, SR; Chalamala, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Preger, Yuliya; Barkholtz, Heather M.; Fresquez, Armando; Campbell, Daniel L.; Juba, Benjamin W.; Roman-Kustas, Jessica; Ferreira, Summer R.; Chalamala, Babu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Degradation of Commercial Lithium-Ion Cells as a Function of Chemistry and Cycling Conditions", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy storage systems with Li-ion batteries are increasingly deployed to maintain a robust and resilient grid and facilitate the integration of renewable energy resources. However, appropriate selection of cells for different applications is difficult due to limited public data comparing the most commonly used off-the-shelf Li-ion chemistries under the same operating conditions. This article details a multi-year cycling study of commercial LiFePO4(LFP), LiNixCoyAl1-x-yO2(NCA), and LiNixMnyCo1-x-yO2(NMC) cells, varying the discharge rate, depth of discharge (DOD), and environment temperature. The capacity and discharge energy retention, as well as the round-trip efficiency, were compared. Even when operated within manufacturer specifications, the range of cycling conditions had a profound effect on cell degradation, with time to reach 80% capacity varying by thousands of hours and cycle counts among cells of each chemistry. The degradation of cells in this study was compared to that of similar cells in previous studies to identify universal trends and to provide a standard deviation for performance. All cycling files have been made publicly available at batteryarchive.org, a recently developed repository for visualization and comparison of battery data, to facilitate future experimental and modeling efforts. (c) 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BYNC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: permissions@ioppublishing.org.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2020, "Volume": 167, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120532, "DOI": "10.1149/1945-7111/abae37", "DOI Link": "http://dx.doi.org/10.1149/1945-7111/abae37", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568420800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Marmur, A; Della Volpe, C; Siboni, S; Amirfazli, A; Drelich, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Marmur, Abraham; Della Volpe, Claudio; Siboni, Stefano; Amirfazli, Alidad; Drelich, Jaroslaw W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contact angles and wettability: towards common and accurate terminology", "Source Title": "SURFACE INNOVATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Much interest has recently been focused on contact angles, wetting and non-wettable surfaces as is evidenced by the rapid pace and sheer number of papers published in recent years. However, in many cases there exist misconceptions and misuses of terminology, leading to misinterpretation of experimental contact angles, measurements of which deceptively appear to be simple. Terms describing contact angles, wettability, superhydrophobicity and similar other terminology are loosely used. In this contribution, key terms used in relation to contact angles are defined precisely based on the accumulative knowledge from the surface chemistry community over the last decades. The definitions provided are scientifically rigorous to avoid any ambiguity and confusion. The theoretical considerations underlying these definitions are only briefly mentioned, with references to the relevant papers. Interpretation and meaning of the measured contact angles can be made simpler if the basic concepts are clearly understood and theory-based indications are applied. The clarity of definitions should make data interpretation and comparison easier for future contributions to journals, including this journal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3, "End Page": 8, "Article Number": null, "DOI": "10.1680/jsuin.17.00002", "DOI Link": "http://dx.doi.org/10.1680/jsuin.17.00002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393170700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, B; Zhang, JB; Hua, Y; Liu, P; Wang, LQ; Ruan, CQ; Li, YY; Boschloo, G; Johansson, EMJ; Kloo, L; Hagfeldt, A; Jen, AKY; Sun, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Bo; Zhang, Jinbao; Hua, Yong; Liu, Peng; Wang, Linqin; Ruan, Changqing; Li, Yuanyuan; Boschloo, Gerrit; Johansson, Erik M. J.; Kloo, Lars; Hagfeldt, Anders; Jen, Alex K. -Y.; Sun, Licheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailor-Making Low-Cost Spiro[fluorene-9,9′-xanthene]-Based 3D Oligomers for Perovskite Solar Cells", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The power-conversion efficiencies (PCEs) of perovskite solar cells (PSCs) have increased rapidly from about 4% to 22% during the past few years. One of the major challenges for further improvement of the efficiency of PSCs is the lack of sufficiently good hole transport materials (HTMs) to efficiently scavenge the photogenerated holes and aid the transport of the holes to the counter-electrode in the PSCs. In this study, we tailor-made two low-cost spiro[fluorene-9,9'-xanthene] (SFX)-based 3D oligomers, termed X54 and X55, by using a one-pot synthesis approach for PSCs. One of the HTMs, X55, gives a much deeper HOMO level and a higher hole mobility and conductivity than the state-of-theart HTM, Spiro-OMeTAD. PSC devices based on X55 as the HTM show a very impressive PCE of 20.8% under 100mW.cm(-2) AM1.5G solar illumination, which is much higher than the PCE of the reference devices based on Spiro-OMeTAD (18.8%) and X54 (13.6%) under the same conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 676, "End Page": 687, "Article Number": null, "DOI": "10.1016/j.chempr.2017.03.011", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2017.03.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408621100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alhijjaj, M; Belton, P; Qi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alhijjaj, Muqdad; Belton, Peter; Qi, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An investigation into the use of polymer blends to improve the printability of and regulate drug release from pharmaceutical solid dispersions prepared via fused deposition modeling (FDM) 3D printing", "Source Title": "EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "FDM 3D printing has been recently attracted increasing research efforts towards the production of personalized solid oral formulations. However, commercially available FDM printers are extremely limited with regards to the materials that can be processed to few types of thermoplastic polymers, which often may not be pharmaceutically approved materials nor ideal for optimizing dosage form performance of poor soluble compounds. This study explored the use of polymer blends as a formulation strategy to overcome this processability issue and to provide adjustable drug release rates from the printed dispersions. Solid dispersions of felodipine, the model drug, were successfully fabricated using FDM 3D printing with polymer blends of PEG, PEO and Tween 80 with either Eudragit E PO or Soluplus. As PVA is one of most widely used polymers in FDM 3D printing, a PVA based solid dispersion was used as a benchmark to compare the polymer blend systems to in terms of processability. The polymer blends exhibited excellent printability and were suitable for processing using a commercially available FDM 3D printer. With 10% drug loading, all characterization data indicated that the model drug was molecularly dispersed in the matrices. During in vitro dissolution testing, it was dear that the disintegration behavior of the formulations significantly influenced the rates of drug release. Eudragit EPO based blend dispersions showed bulk disintegration; whereas the Soluplus based blends showed the 'peeling' style disintegration of strip-by strip. The results indicated that interplay of the miscibility between excipients in the blends, the solubility of the materials in the dissolution media and the degree of fusion between the printed strips during FDM process can be used to manipulate the drug release rate of the dispersions. This brings new insight into the design principles of controlled release formulations using FDM 3D printing. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2016, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 111, "End Page": 125, "Article Number": null, "DOI": "10.1016/j.ejpb.2016.08.016", "DOI Link": "http://dx.doi.org/10.1016/j.ejpb.2016.08.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388052600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de Jong, M; Chen, W; Angsten, T; Jain, A; Notestine, R; Gamst, A; Sluiter, M; Ande, CK; van der Zwaag, S; Plata, JJ; Toher, C; Curtarolo, S; Ceder, G; Persson, KA; Asta, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de Jong, Maarten; Chen, Wei; Angsten, Thomas; Jain, Anubhav; Notestine, Randy; Gamst, Anthony; Sluiter, Marcel; Ande, Chaitanya Krishna; van der Zwaag, Sybrand; Plata, Jose J.; Toher, Cormac; Curtarolo, Stefano; Ceder, Gerbrand; Persson, Kristin A.; Asta, Mark", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charting the complete elastic properties of inorganic crystalline compounds", "Source Title": "SCIENTIFIC DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The elastic constant tensor of an inorganic compound provides a complete description of the response of the material to external stresses in the elastic limit. It thus provides fundamental insight into the nature of the bonding in the material, and it is known to correlate with many mechanical properties. Despite the importance of the elastic constant tensor, it has been measured for a very small fraction of all known inorganic compounds, a situation that limits the ability of materials scientists to develop new materials with targeted mechanical responses. To address this deficiency, we present here the largest database of calculated elastic properties for inorganic compounds to date. The database currently contains full elastic information for 1,181 inorganic compounds, and this number is growing steadily. The methods used to develop the database are described, as are results of tests that establish the accuracy of the data. In addition, we document the database format and describe the different ways it can be accessed and analyzed in efforts related to materials discovery and design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 809, "Times Cited, All Databases": 873, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2015, "Volume": 2, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 150009, "DOI": "10.1038/sdata.2015.9", "DOI Link": "http://dx.doi.org/10.1038/sdata.2015.9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390328900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jood, P; Ohta, M; Yamamoto, A; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jood, Priyanka; Ohta, Michihiro; Yamamoto, Atsushi; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excessively Doped PbTe with Ge-Induced nullostructures Enables High-Efficiency Thermoelectric Modules", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of thermoelectrics in waste heat recovery requires high conversion efficiency, which is best achieved through the combination of progressive performance-enhancing strategies. In this study, we combined engineered doping, nullostructuring, and module fabrication in PbTe-based thermoelectrics to generate high-ZT materials along with high-efficiency modules. The use of excess Na (4%) as a p-type dopant greatly enhanced the thermoelectric power factor by generating extra charge carriers at high temperature. The addition of minute amounts of Ge (<= 1%) generated nulloprecipitates, which greatly reduced the lattice thermal conductivity. An optimal ZT of similar to 1.9 at similar to 805 K was achieved for Pb0.953Na0.040Ge0.007Te as a p-type leg, which was combined with PbTe0.9964I0.0036 as an n-type leg to fabricate thermoelectric modules. An exceptionally high efficiency of similar to 12% for a temperature difference of 590 K was obtained in a cascade Bi2Te3/nullostructured PbTe module with eight p-n pairs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2018, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1339, "End Page": 1355, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.025", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439698900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Emery, AA; Wolverton, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Emery, Antoine A.; Wolverton, Chris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput DFT calculations of formation energy, stability and oxygen vacancy formation energy of ABO3 perovskites", "Source Title": "SCIENTIFIC DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Data Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ABO(3) perovskites are oxide materials that are used for a variety of applications such as solid oxide fuel cells, piezo-, ferro-electricity and water splitting. Due to their remarkable stability with respect to cation substitution, new compounds for such applications potentially await discovery. In this work, we present an exhaustive dataset of formation energies of 5,329 cubic and distorted perovskites that were calculated using first-principles density functional theory. In addition to formation energies, several additional properties such as oxidation states, band gap, oxygen vacancy formation energy, and thermodynamic stability with respect to all phases in the Open Quantum Materials Database are also made publicly available. This large dataset for this ubiquitous crystal structure type contains 395 perovskites that are predicted to be thermodynamically stable, of which many have not yet been experimentally reported, and therefore represent theoretical predictions. The dataset thus opens avenues for future use, including materials discovery in many research-active areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2017, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 170153, "DOI": "10.1038/sdata.2017.153", "DOI Link": "http://dx.doi.org/10.1038/sdata.2017.153", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413080900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, QF; Zhou, J; Yu, R; Wang, Z; Weng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Qi-Feng; Zhou, Jian; Yu, Rui; Wang, Zhi; Weng, Hongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Node-surface and node-line fermions from nonsymmorphic lattice symmetries", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a kind of topological quantum state of semimetals in the quasi-one-dimensional (1D) crystal family BaMX3 (M = V, Nb, or Ta; X = S or Se) by using symmetry analysis and first-principles calculation. We find that in BaVS3 the valence and conduction bands are degenerate in the k(z) = pi/c plane (c is the lattice constant along the (z) over cap axis) of the Brillouin zone (BZ). These nodal points form a node surface, and they are protected by a nonsymmorphic crystal symmetry consisting of a twofold rotation about the (z) over cap axis and a half-translation along the same (z) over cap axis. The band degeneracy in the node surface is lifted in BaTaS3 by including strong spin-orbit coupling (SOC) of Ta. The node surface is reduced into 1D node lines along the high-symmetry paths k(x) = 0 and k(x) = +/-root 3k(y) on the k(z) = pi/ c plane. These node lines are robust against SOC and guaranteed by the symmetries of the P6(3)/mmc space group. These node-line states are entirely different from previous proposals which are based on the accidental band touchings. We also propose a useful material design for realizing topological node-surface and node-line semimetals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2016, "Volume": 93, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85427, "DOI": "10.1103/PhysRevB.93.085427", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.085427", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370488300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takayama, T; Kato, A; Dinnebier, R; Nuss, J; Kono, H; Veiga, LSI; Fabbris, G; Haskel, D; Takagi, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takayama, T.; Kato, A.; Dinnebier, R.; Nuss, J.; Kono, H.; Veiga, L. S. I.; Fabbris, G.; Haskel, D.; Takagi, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperhoneycomb Iridate β-Li2IrO3 as a Platform for Kitaev Magnetism", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A complex iridium oxide beta-Li2IrO3 crystallizes in a hyperhoneycomb structure, a three-dimensional analogue of honeycomb lattice, and is found to be a spin-orbital Mott insulator with J(eff) = 1/2 moment. Ir ions are connected to the three neighboring Ir ions via Ir-O-2-Ir bonding planes, which very likely gives rise to bond-dependent ferromagnetic interactions between the J(eff) = 1/2 moments, an essential ingredient of Kitaev model with a spin liquid ground state. Dominullt ferromagnetic interaction between J(eff) = 1/2 moments is indeed confirmed by the temperature dependence of magnetic susceptibility chi(T) which shows a positive Curie-Weiss temperature theta(CW) similar to +40 K. A magnetic ordering with a very small entropy change, likely associated with a noncollinear arrangement of J(eff) = 1/2 moments, is observed at T-c = 38 K. With the application of magnetic field to the ordered state, a large moment of more than 0.35 mu(B)/Ir is induced above 3 T, a substantially polarized J(eff) = 1/2 state. We argue that the close proximity to ferromagnetism and the presence of large fluctuations evidence that the ground state of hyperhoneycomb beta-Li2IrO3 is located in close proximity of a Kitaev spin liquid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 331, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 19", "Publication Year": 2015, "Volume": 114, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77202, "DOI": "10.1103/PhysRevLett.114.077202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.077202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350274900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zuo, Y; Bellani, S; Saleh, G; Ferri, M; Shinde, DV; Zappia, MI; Buha, J; Brescia, R; Prato, M; Pascazio, R; Annamalai, A; de Souza, DO; De Trizio, L; Infante, I; Bonaccorso, F; Manna, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zuo, Yong; Bellani, Sebastiano; Saleh, Gabriele; Ferri, Michele; Shinde, Dipak V.; Zappia, Marilena Isabella; Buha, Joka; Brescia, Rosaria; Prato, Mirko; Pascazio, Roberta; Annamalai, Abinaya; de Souza, Danilo Oliveira; De Trizio, Luca; Infante, Ivan; Bonaccorso, Francesco; Manna, Liberato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ru-Cu nulloheterostructures for Efficient Hydrogen Evolution Reaction in Alkaline Water Electrolyzers", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Combining multiple species working in tandem for different hydrogen evolution reaction (HER) steps is an effective strategy to design HER electrocatalysts. Here, we engineered a hierarchical electrode for the HER composed of amorphous-TiO2/Cu nullorods (NRs) decorated with cost-effective Ru-Cu nulloheterostructures (Ru mass loading = 52 mu g/cm(2)). Such an electrode exhibits a stable, over 250 h, low overpotential of 74 mV at -200 mA/cm2 for the HER in 1 M NaOH. The high activity of the electrode is attributed, by structural analysis, operando X-ray absorption spectroscopy, and first-principles simulations, to synergistic functionalities: (1) mechanically robust, vertically aligned Cu NRs with high electrical conductivity and porosity provide fast charge and gas transfer channels; (2) the Ru electronic structure, regulated by the size of Cu clusters at the surface, facilitates the water dissociation (Volmer step); (3) the Cu clusters grown atop Ru exhibit a close-to-zero Gibbs free energy of the hydrogen adsorption, promoting fast Heyrovsky/Tafel steps. An alkaline electrolyzer (AEL) coupling the proposed cathode and a stainless-steel anode can stably operate in both continuous (1 A/cm(2) for over 200 h) and intermittent modes (accelerated stress tests). A techno-economic analysis predicts the minimal overall hydrogen production cost of US$2.12/kg in a 1 MW AEL plant of 30 year lifetime based on our AEL single cell, hitting the worldwide targets (US$2-2.5/kg(H2) ).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2023, "Volume": 145, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21419, "End Page": 21431, "Article Number": null, "DOI": "10.1021/jacs.3c06726", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c06726", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001071995000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baek, SH; Do, SH; Choi, KY; Kwon, YS; Wolter, AUB; Nishimoto, S; van den Brink, J; Büchner, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baek, S-H.; Do, S-H.; Choi, K-Y.; Kwon, Y. S.; Wolter, A. U. B.; Nishimoto, S.; van den Brink, Jeroen; Buechner, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for a Field-Induced Quantum Spin Liquid in α-RuCl3", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a Cl-35 nuclear magnetic resonullce study in the honeycomb lattice alpha-RuCl3, a material that has been suggested to potentially realize a Kitaev quantum spin liquid (QSL) ground state. Our results provide direct evidence that alpha-RuCl3 exhibits a magnetic-field-induced QSL. For fields larger than similar to 10 T, a spin gap opens up while resonullce lines remain sharp, evidencing that spins are quantum disordered and locally fluctuating. The spin gap increases linearly with an increasing magnetic field, reaching similar to 50 K at 15 T, and is nearly isotropic with respect to the field direction. The unusual rapid increase of the spin gap with increasing field and its isotropic nature are incompatible with conventional magnetic ordering and, in particular, exclude that the ground state is a fully polarized ferromagnet. The presence of such a field-induced gapped QSL phase has indeed been predicted in the Kitaev model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 306, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 18", "Publication Year": 2017, "Volume": 119, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37201, "DOI": "10.1103/PhysRevLett.119.037201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.037201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405718200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seifi, M; Salem, A; Beuth, J; Harrysson, O; Lewandowski, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seifi, Mohsen; Salem, Ayman; Beuth, Jack; Harrysson, Ola; Lewandowski, John J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overview of Materials Qualification Needs for Metal Additive Manufacturing", "Source Title": "JOM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This overview highlights some of the key aspects regarding materials qualification needs across the additive manufacturing (AM) spectrum. AM technology has experienced considerable publicity and growth in the past few years with many successful insertions for non-mission-critical applications. However, to meet the full potential that AM has to offer, especially for flight-critical components (e.g., rotating parts, fracture-critical parts, etc.), qualification and certification efforts are necessary. While development of qualification standards will address some of these needs, this overview outlines some of the other key areas that will need to be considered in the qualification path, including various process-, microstructure-, and fracture-modeling activities in addition to integrating these with lifing activities targeting specific components. Ongoing work in the Advanced Manufacturing and Mechanical Reliability Center at Case Western Reserve University is focusing on fracture and fatigue testing to rapidly assess critical mechanical properties of some titanium alloys before and after post-processing, in addition to conducting nondestructive testing/evaluation using micro-computerized tomography at General Electric. Process mapping studies are being conducted at Carnegie Mellon University while large area microstructure characterization and informatics (EBSD and BSE) analyses are being conducted at Materials Resources LLC to enable future integration of these efforts via an Integrated Computational Materials Engineering approach to AM. Possible future pathways for materials qualification are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 453, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 68, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 747, "End Page": 764, "Article Number": null, "DOI": "10.1007/s11837-015-1810-0", "DOI Link": "http://dx.doi.org/10.1007/s11837-015-1810-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371292100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ajarostaghi, SSM; Zaboli, M; Javadi, H; Badenes, B; Urchueguia, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mousavi Ajarostaghi, Seyed Soheil; Zaboli, Mohammad; Javadi, Hossein; Badenes, Borja; Urchueguia, Javier F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Review of Recent Passive Heat Transfer Enhancement Methods", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improvements in miniaturization and boosting the thermal performance of energy conservation systems call for innovative techniques to enhance heat transfer. Heat transfer enhancement methods have attracted a great deal of attention in the industrial sector due to their ability to provide energy savings, encourage the proper use of energy sources, and increase the economic efficiency of thermal systems. These methods are categorized into active, passive, and compound techniques. This article reviews recent passive heat transfer enhancement techniques, since they are reliable, cost-effective, and they do not require any extra power to promote the energy conversion systems' thermal efficiency when compared to the active methods. In the passive approaches, various components are applied to the heat transfer/working fluid flow path to improve the heat transfer rate. The passive heat transfer enhancement methods studied in this article include inserts (twisted tapes, conical strips, baffles, winglets), extended surfaces (fins), porous materials, coil/helical/spiral tubes, rough surfaces (corrugated/ribbed surfaces), and nullofluids (mono and hybrid nullofluids).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 986, "DOI": "10.3390/en15030986", "DOI Link": "http://dx.doi.org/10.3390/en15030986", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000759496100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fogler, MM; Butov, LV; Novoselov, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fogler, M. M.; Butov, L. V.; Novoselov, K. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-temperature superfluidity with indirect excitons in van der Waals heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All known superfluid and superconducting states of condensed matter are enabled by composite bosons (atoms, molecules and Cooper pairs) made of an even number of fermions. Temperatures where such macroscopic quantum phenomena occur are limited by the lesser of the binding energy and the degeneracy temperature of the bosons. High-critical temperature cuprate superconductors set the present record of similar to 100 K. Here we propose a design for artificially structured materials to rival this record. The main elements of the structure are two monolayers of a transition metal dichalcogenide separated by an atomically thin spacer. Electrons and holes generated in the system would accumulate in the opposite monolayers and form bosonic bound states-the indirect excitons. The resultant degenerate Bose gas of indirect excitons would exhibit macroscopic occupation of a quantum state and vanishing viscosity at high temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 430, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4555, "DOI": "10.1038/ncomms5555", "DOI Link": "http://dx.doi.org/10.1038/ncomms5555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340658500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, J; Yao, ZY; Zhang, W; Liu, B; Chen, KM; Li, L; Teng, B; Du, XF; Li, CR; Yu, XF; Qin, L; Lai, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Jing; Yao, Zhenyu; Zhang, Wei; Liu, Ben; Chen, Kaiming; Li, Long; Teng, Bin; Du, Xiang-Fu; Li, Cairong; Yu, Xue-Feng; Qin, Ling; Lai, Yuxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulation of Osteoimmune Microenvironment and Osteogenesis by 3D-Printed PLAG/black Phosphorus Scaffolds for Bone Regeneration", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The treatment of bone defects remains a significant challenge to be solved clinically. Immunomodulatory properties of orthopedic biomaterials have significance in regulating osteoimmune microenvironment for osteogenesis. A lactic acid-co-glycolic acid (PLGA) scaffold incorporates black phosphorus (BP) fabricated by 3D printing technology to investigate the effect of BP on osteoimmunomodulation and osteogenesis in site. The PLGA/BP scaffold exhibits suitable biocompatibility, biodegradability, and mechanical properties as an excellent microenvironment to support new bone formation. The studies' result also demonstrate that the PLGA/BP scaffolds are able to recruit and stimulate macrophages M2 polarization, inhibit inflammation, and promote human bone marrow mesenchymal stem cells (hBMSCs) proliferation and differentiation, which in turn promotes bone regeneration in the distal femoral defect region of steroid-associated osteonecrosis (SAON) rat model. Moreover, it is screened and demonstrated that PLGA/BP scaffolds can promote osteogenic differentiation by transcriptomic analysis, and PLGA/BP scaffolds promote osteogenic differentiation and mineralization by activating PI3K-AKT signaling pathway in hBMSC cells. In this study, it is shown that the innovative PLGA/BP scaffolds are extremely effective in stimulating bone regeneration by regulating macrophage M2 polarization and a new strategy for the development of biomaterials that can be used to repair bone defects is offered. A PLGA/BP scaffold fabricated by 3D printing technology to improve the bone immune microenvironment and promote bone regeneration is intoduced. PLGA/BP scaffolds modulate the polarization of macrophages from M1 to M2, effectively inhibiting the inflammatory response. Furthermore, the activation of the PI3K-AKT pathways by PLGA/BP scaffolds promotes the transcriptional regulation of Runx2 and IBSP, SPP1, therefore promoting osteogenesis and bone regeneration.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 10, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302539", "DOI Link": "http://dx.doi.org/10.1002/advs.202302539", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001133172600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JJ; Cao, S; Yilmaz, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiajian; Cao, Shuai; Yilmaz, Erol", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of Macro Mechanical Properties and Microstructures of Cement-Based Composites Prepared from Fly Ash, Gypsum and Steel Slag", "Source Title": "MINERALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using solid wastes (SWs) as backfilling material to fill underground mined-out areas (UMOAs) solved the environmental problems caused by SWs and reduced the backfilling cost. In this study, fly ash (FA), gypsum and steel slag (SS) were used to prepare cement-based composites (CBC). The uniaxial compression, computed tomography (CT) and scanning electron microscope (SEM) laboratory experiments were conducted to explore the macro and micromechanical properties of CBC. The findings showed that the uniaxial compressive strength (UCS) of CBC with a curing time of 7 d could reach 6.54 MPa. The increase of SS content reduced the UCS of CBC, while the gypsum and FA content could increase the UCS of CBC. Microscopic studies have shown that the SS particles in CBC have noticeable sedimentation, and the increase of SS content causes the failure mode of CBC from tensile to tensile-shear. These research results can provide a scientific reference for the preparation of backfilling materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6, "DOI": "10.3390/min12010006", "DOI Link": "http://dx.doi.org/10.3390/min12010006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758743800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Lu, X; Liu, LS; Xiao, J; Zhang, G; Guo, FX; Li, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Lu, Xiao; Liu, Lisheng; Xiao, Jie; Zhang, Ge; Guo, Fanxing; Li, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of MgO on the Hydration and Shrinkage Behavior of Low Heat Portland Cement-Based Materials via Pore Structural and Fractal Analysis", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, low heat Portland (LHP) cement is widely used in mass concrete structures. The magnesia expansion agent (MgO) can be adopted to reduce the shrinkage of conventional Portland cement-based materials, but very few studies can be found that investigate the influence of MgO on the properties of LHP cement-based materials. In this study, the influences of two types of MgO on the hydration, as well as the shrinkage behavior of LHP cement-based materials, were studied via pore structural and fractal analysis. The results indicate: (1) The addition of reactive MgO (with a reactivity of 50 s and shortened as M50 thereafter) not only extends the induction stage of LHP cement by about 1-2 h, but also slightly increases the hydration heat. In contrast, the addition of weak reactive MgO (with a reactivity of 300 s and shortened as M300 thereafter) could not prolong the induction stage of LHP cement. (2) The addition of 4 wt.%-8 wt.% MgO (by weight of binder) lowers the mechanical property of LHP concrete. Higher dosages of MgO and stronger reactivity lead to a larger reduction in mechanical properties at all of the hydration times studied. M300 favors the strength improvement of LHP concrete at later ages. (3) M50 effectively compensates the shrinkage of LHP concrete at a much earlier time than M300, whereas M300 compensates the long-term shrinkage more effectively than M50. Thus, M300 with an optimal dosage of 8 wt.% is suggested to be applied in mass LHP concrete structures. (4) The addition of M50 obviously refines the pore structures of LHP concrete at 7 days, whereas M300 starts to refine the pore structure at around 60 days. At 360 days, the concretes containing M300 exhibits much finer pore structures than those containing M50. (5) Fractal dimension is closely correlated with the pore structure of LHP concrete. Both pore structure and fractal dimension exhibit weak (or no) correlations with shrinkage of LHP concrete.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 40, "DOI": "10.3390/fractalfract6010040", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6010040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756297100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, X; Zhan, XH; Wang, XJ; Deng, J; Liu, XB; Chen, X; Guo, JG; Chen, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xu; Zhan, Xinhui; Wang, Xiaojun; Deng, Jun; Liu, Xiao-Bing; Chen, Xin; Guo, Jian-Gang; Chen, Xiaolong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Robust Reentrant Superconductivity in CsV3Sb5 under Pressure", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the superconducting (SC) property and high-robustness of structural stability of kagome CsV3Sb5 under in situ high pressures. For the initial SC-I phase, its T (c) is quickly enhanced from 3.5 K to 7.6 K and then totally suppressed at P similar to 10 GPa. With further increasing pressure, an SC-II phase emerges at P similar to 15 GPa and persists up to 100 GPa. The T (c) rapidly increases to the maximal value of 5.2 K at P = 53.6 GPa and slowly decreases to 4.7 K at P = 100 GPa. A two-dome-like variation of T (c) in CsV3Sb5 is concluded here. The Raman measurements demonstrate that weakening of E (2g) mode and strengthening of E (1g) mode occur without phase transition in the SC-II phase, which is supported by the results of phonon spectra calculations. Electronic structure calculations reveal that exertion of pressure may bridge the gap of topological surface nontrivial states near E (F), i.e., disappearance of Z (2) invariant. Meanwhile, the Fermi surface enlarges significantly, consistent with the increased carrier density. The findings here suggest that the change of electronic structure and strengthened electron-phonon coupling should be responsible for the pressure-induced reentrant SC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 38, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57402, "DOI": "10.1088/0256-307X/38/5/057402", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/38/5/057402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657487200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Sun, Z; Zhang, J; Luo, HJ; Zhang, QH; Yao, YH; Deng, SQ; Qi, H; Liu, J; Gallington, LC; Neuefeind, JC; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Hui; Sun, Zheng; Zhang, Ji; Luo, Huajie; Zhang, Qinghua; Yao, Yonghao; Deng, Shiqing; Qi, He; Liu, Jue; Gallington, Leighanne. C. C.; Neuefeind, Joerg. C. C.; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical Design of Pb-Free Relaxors for Giant Capacitive Energy Storage", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric capacitors have captured substantial attentionfor advancedelectrical and electronic systems. Developing dielectrics with highenergy density and high storage efficiency is challenging owing tothe high compositional diversity and the lack of general guidelines.Herein, we propose a map that captures the structural distortion (delta)and tolerance factor (t) of perovskites to designPb-free relaxors with extremely high capacitive energy storage. Ourmap shows how to select ferroelectric with large delta and paraelectriccomponents to form relaxors with a t value closeto 1 and thus obtaining eliminated hysteresis and large polarizationunder a high electric breakdown. Taking the Bi0.5Na0.5TiO3-based solid solution as an example, we demonstratethat composition-driven predominullt order-disorder characteristicof local atomic polar displacements endows the relaxor with a slushlikestructure and strong local polar fluctuations at several nulloscale.This leads to a giant recoverable energy density of 13.6 J cm(-3), along with an ultrahigh efficiency of 94%, whichis far beyond the current performance boundary reported in Pb-freebulk ceramics. Our work provides a solution through rational chemicaldesign for obtaining Pb-free relaxors with outstanding energy-storageproperties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2023, "Volume": 145, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11764, "End Page": 11772, "Article Number": null, "DOI": "10.1021/jacs.3c02811", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c02811", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001014365700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, ZM; Zhang, XC; Shu, YQ; Guo, M; Zhang, H; Tao, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Zhongmin; Zhang, Xingcai; Shu, Yiqing; Guo, Ming; Zhang, Han; Tao, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights from nullotechnology in COVID-19 treatment", "Source Title": "nullO TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In just a few months, SARS-CoV-2 and the disease it causes, COVID-19, created a worldwide pandemic. Virologists, biologists, pharmacists, materials scientists, and clinicians are collaborating to develop efficient treatment strategies. Overall, in addition to the use of clinical equipment to assist patient rehabilitation, antiviral drugs and vaccines are the areas of greatest focus. Given the physical size of SARS-CoV-2 and the vaccine delivery platforms currently in clinical trials, the relevance of nullotechnology is clear, and previous antiviral research using nullomaterials also supports this connection. Herein we briefly summarize current representative strategies regarding nullomaterials in antiviral research. We focus specifically on SARS-CoV-2 and the detailed role that nullotechnology can play in addressing this pandemic, including i) using FDA-approved nullomaterials for drug/vaccine delivery, including further exploration of the inhalation pathway; ii) introducing promising nullomaterials currently in clinical trials for drug/vaccine delivery; iii) designing novel biocompatible nullomaterials to combat the virus via interfering in its life cycle; and iv) promoting the utilization of nullomaterials in pneumonia treatment. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 36, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101019, "DOI": "10.1016/j.nulltod.2020.101019", "DOI Link": "http://dx.doi.org/10.1016/j.nulltod.2020.101019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637808000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Yang, P; Kots, PA; Cohen, M; Chen, Y; Quinn, CM; De Mello, MD; Anibal Boscoboinik, J; Shaw, WJ; Caratzoulas, S; Zheng, W; Vlachos, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jiahua; Yang, Piaoping; Kots, Pavel A.; Cohen, Maximilian; Chen, Ying; Quinn, Caitlin M.; de Mello, Matheus Dorneles; Anibal Boscoboinik, J.; Shaw, Wendy J.; Caratzoulas, Stavros; Zheng, Weiqing; Vlachos, Dionisios G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the reactivity of carbon surfaces with oxygen-containing functional groups", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen-containing carbons are promising supports and metal-free catalysts for many reactions. However, distinguishing the role of various oxygen functional groups and quantifying and tuning each functionality is still difficult. Here we investigate the role of BrOnsted acidic oxygen-containing functional groups by synthesizing a diverse library of materials. By combining acid-catalyzed elimination probe chemistry, comprehensive surface characterizations, N-15 isotopically labeled acetonitrile adsorption coupled with magic-angle spinning nuclear magnetic resonullce, machine learning, and density-functional theory calculations, we demonstrate that phenolic is the main acid site in gas-phase chemistries and unexpectedly carboxylic groups are much less acidic than phenolic groups in the graphitized mesoporous carbon due to electron density delocalization induced by the aromatic rings of graphitic carbon. The methodology can identify acidic sites in oxygenated carbon materials in solid acid catalyst-driven chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2293, "DOI": "10.1038/s41467-023-37962-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37962-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gemmi, M; Mugnaioli, E; Gorelik, TE; Kolb, U; Palatinus, L; Boullay, P; Hovmöller, S; Abrahams, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gemmi, Mauro; Mugnaioli, Enrico; Gorelik, Tatiana E.; Kolb, Ute; Palatinus, Lukas; Boullay, Philippe; Hovmoller, Sven; Abrahams, Jan Pieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Electron Diffraction: The nullocrystallography Revolution", "Source Title": "ACS CENTRAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Crystallography of nullocrystalline materials has witnessed a true revolution in the past 10 years, thanks to the introduction of protocols for 3D acquisition and analysis of electron diffraction data. This method provides single-crystal data of structure solution and refinement quality, allowing the atomic structure determination of those materials that remained hitherto unknown because of their limited crystallinity. Several experimental protocols exist, which share the common idea of sampling a sequence of diffraction patterns while the crystal is tilted around a noncrystallographic axis, namely, the goniometer axis of the transmission electron microscope sample stage. This Outlook reviews most important 3D electron diffraction applications for different kinds of samples and problematics, related with both materials and life sciences. Structure refinement including dynamical scattering is also briefly discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2019, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1315, "End Page": 1329, "Article Number": null, "DOI": "10.1021/acscentsci.9b00394", "DOI Link": "http://dx.doi.org/10.1021/acscentsci.9b00394", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486591500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, TX; Jiang, SW; Shen, BW; Zhang, Y; Li, LZ; Tao, Z; Devakul, T; Watanabe, K; Taniguchi, T; Fu, L; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tingxin; Jiang, Shengwei; Shen, Bowen; Zhang, Yang; Li, Lizhong; Tao, Zui; Devakul, Trithep; Watanabe, Kenji; Taniguchi, Takashi; Fu, Liang; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum anomalous Hall effect from intertwined moire bands", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron correlation and topology are two central threads of modern condensed matter physics. Semiconductor moire materials provide a highly tuneable platform for studies of electron correlation(1-12). Correlation-driven phenomena, including the Mott insulator(2-5), generalized Wigner crystals(2,6,9), stripe phases(10) and continuous Mott transition(11,12), have been demonstrated. However, non-trivial band topology has remained unclear. Here we report the observation of a quantum anomalous Hall effect in AB-stacked MoTe2 /WSe2 moire heterobilayers. Unlike in the AA-stacked heterobilayers(11), an out-of-plane electric field not only controls the bandwidth but also the band topology by intertwining moire bands centred at different layers. At half band filling, corresponding to one particle per moire unit cell, we observe quantized Hall resistance, h/e(2) (with h and e denoting the Planck's constant and electron charge, respectively), and vanishing longitudinal resistance at zero magnetic field. The electric-field-induced topological phase transition from a Mott insulator to a quantum anomalous Hall insulator precedes an insulator-to-metal transition. Contrary to most known topological phase transitions(13), it is not accompanied by a bulk charge gap closure. Our study paves the way for discovery of emergent phenomena arising from the combined influence of strong correlation and topology in semiconductor moire materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 371, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2021, "Volume": 600, "Issue": 7890, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 641, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04171-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04171-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733421800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, R; Chen, CZ; Gao, JH; Zhou, B; Xu, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Rui; Chen, Chui-Zhen; Gao, Jin-Hua; Zhou, Bin; Xu, Dong-Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Higher-Order Topological Insulators in Quasicrystals", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current understanding of higher-order topological insulators (HOTIs) is based primarily on crystalline materials. Here, we propose that HOTIs can be realized in quasicrystals. Specifically, we show that two distinct types of second-order topological insulators (SOTIs) can be constructed on the quasicrystalline lattices (QLs) with different tiling patterns. One is derived by using a Wilson mass term to gap out the edge states of the quantum spin Hall insulator on QLs. The other is the quasicrystalline quadrupole insulator (QI) with a quantized quadrupole moment. We reveal some unusual features of the corner states (CSs) in the quasicrystalline SOTIs. We also show that the quasicrystalline QI can be simulated by a designed electrical circuit, where the CSs can be identified by measuring the impedance resonullce peak. Our findings not only extend the concept of HOTIs into quasicrystals but also provide a feasible way to detect the topological property of quasicrystals in experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2020, "Volume": 124, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36803, "DOI": "10.1103/PhysRevLett.124.036803", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.036803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509506000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aprà, E; Bylaska, EJ; de Jong, WA; Govind, N; Kowalski, K; Straatsma, TP; Valiev, M; van Dam, HJJ; Alexeev, Y; Anchell, J; Anisimov, V; Aquino, FW; Atta-Fynn, R; Autschbach, J; Bauman, NP; Becca, JC; Bernholdt, DE; Bhaskaran-Nair, K; Bogatko, S; Borowski, P; Boschen, J; Brabec, J; Bruner, A; Cauet, E; Chen, Y; Chuev, GN; Cramer, CJ; Daily, J; Deegan, MJO; Dunning, TH; Dupuis, M; Dyall, KG; Fann, GI; Fischer, SA; Fonari, A; Früchtl, H; Gagliardi, L; Garza, J; Gawande, N; Ghosh, S; Glaesemann, K; Götz, AW; Hammond, J; Helms, V; Hermes, ED; Hirao, K; Hirata, S; Jacquelin, M; Jensen, L; Johnson, BG; Jonsson, H; Kendall, RA; Klemm, M; Kobayashi, R; Konkov, V; Krishnamoorthy, S; Krishnull, M; Lin, Z; Lins, RD; Littlefield, RJ; Logsdail, AJ; Lopata, K; Ma, W; Marenich, AV; del Campo, JM; Mejia-Rodriguez, D; Moore, JE; Mullin, JM; Nakajima, T; Nascimento, DR; Nichols, JA; Nichols, PJ; Nieplocha, J; Otero-de-la-Roza, A; Palmer, B; Panyala, A; Pirojsirikul, T; Peng, B; Peverati, R; Pittner, J; Pollack, L; Richard, RM; Sadayappan, P; Schatz, GC; Shelton, WA; Silverstein, DW; Smith, DMA; Soares, TA; Song, D; Swart, M; Taylor, HL; Thomas, GS; Tipparaju, V; Truhlar, DG; Tsemekhman, K; Van Voorhis, T; Vázquez-Mayagoitia, A; Verma, P; Villa, O; Vishnu, A; Vogiatzis, KD; Wang, D; Weare, JH; Williamson, MJ; Windus, TL; Wolinski, K; Wong, AT; Wu, Q; Yang, C; Yu, Q; Zacharias, M; Zhang, Z; Zhao, Y; Harrison, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Apra, E.; Bylaska, E. J.; de Jong, W. A.; Govind, N.; Kowalski, K.; Straatsma, T. P.; Valiev, M.; van Dam, H. J. J.; Alexeev, Y.; Anchell, J.; Anisimov, V; Aquino, F. W.; Atta-Fynn, R.; Autschbach, J.; Bauman, N. P.; Becca, J. C.; Bernholdt, D. E.; Bhaskaran-Nair, K.; Bogatko, S.; Borowski, P.; Boschen, J.; Brabec, J.; Bruner, A.; Cauet, E.; Chen, Y.; Chuev, G. N.; Cramer, C. J.; Daily, J.; Deegan, M. J. O.; Dunning, T. H., Jr.; Dupuis, M.; Dyall, K. G.; Fann, G., I; Fischer, S. A.; Fonari, A.; Fruechtl, H.; Gagliardi, L.; Garza, J.; Gawande, N.; Ghosh, S.; Glaesemann, K.; Goetz, A. W.; Hammond, J.; Helms, V; Hermes, E. D.; Hirao, K.; Hirata, S.; Jacquelin, M.; Jensen, L.; Johnson, B. G.; Jonsson, H.; Kendall, R. A.; Klemm, M.; Kobayashi, R.; Konkov, V; Krishnamoorthy, S.; Krishnull, M.; Lin, Z.; Lins, R. D.; Littlefield, R. J.; Logsdail, A. J.; Lopata, K.; Ma, W.; Marenich, A., V; del Campo, J. Martin; Mejia-Rodriguez, D.; Moore, J. E.; Mullin, J. M.; Nakajima, T.; Nascimento, D. R.; Nichols, J. A.; Nichols, P. J.; Nieplocha, J.; Otero-de-la-Roza, A.; Palmer, B.; Panyala, A.; Pirojsirikul, T.; Peng, B.; Peverati, R.; Pittner, J.; Pollack, L.; Richard, R. M.; Sadayappan, P.; Schatz, G. C.; Shelton, W. A.; Silverstein, D. W.; Smith, D. M. A.; Soares, T. A.; Song, D.; Swart, M.; Taylor, H. L.; Thomas, G. S.; Tipparaju, V; Truhlar, D. G.; Tsemekhman, K.; Van Voorhis, T.; Vazquez-Mayagoitia, A.; Verma, P.; Villa, O.; Vishnu, A.; Vogiatzis, K. D.; Wang, D.; Weare, J. H.; Williamson, M. J.; Windus, T. L.; Wolinski, K.; Wong, A. T.; Wu, Q.; Yang, C.; Yu, Q.; Zacharias, M.; Zhang, Z.; Zhao, Y.; Harrison, R. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "NWChem: Past, present, and future", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Specialized computational chemistry packages have permanently reshaped the landscape of chemical and materials science by providing tools to support and guide experimental efforts and for the prediction of atomistic and electronic properties. In this regard, electronic structure packages have played a special role by using first-principle-driven methodologies to model complex chemical and materials processes. Over the past few decades, the rapid development of computing technologies and the tremendous increase in computational power have offered a unique chance to study complex transformations using sophisticated and predictive many-body techniques that describe correlated behavior of electrons in molecular and condensed phase systems at different levels of theory. In enabling these simulations, novel parallel algorithms have been able to take advantage of computational resources to address the polynomial scaling of electronic structure methods. In this paper, we briefly review the NWChem computational chemistry suite, including its history, design principles, parallel tools, current capabilities, outreach, and outlook.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 545, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2020, "Volume": 152, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 184102, "DOI": "10.1063/5.0004997", "DOI Link": "http://dx.doi.org/10.1063/5.0004997", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533417100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gunawardene, OHP; Gunathilake, CA; Vikrant, K; Amaraweera, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gunawardene, Oneesha H. P.; Gunathilake, Chamila A.; Vikrant, Kumar; Amaraweera, Sumedha M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Dioxide Capture through Physical and Chemical Adsorption Using Porous Carbon Materials: A Review", "Source Title": "ATMOSPHERE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to rapid industrialization and urban development across the globe, the emission of carbon dioxide (CO2) has been significantly increased, resulting in adverse effects on the climate and ecosystems. In this regard, carbon capture and storage (CCS) is considered to be a promising technology in reducing atmospheric CO2 concentration. Among the CO2 capture technologies, adsorption has grabbed significant attention owing to its advantageous characteristics discovered in recent years. Porous carbon-based materials have emerged as one of the most versatile CO2 adsorbents. Numerous research activities have been conducted by synthesizing carbon-based adsorbents using different precursors to investigate their performances towards CCS. Additionally, amine-functionalized carbon-based adsorbents have exhibited remarkable potential for selective capturing of CO2 in the presence of other gases and humidity conditions. The present review describes the CO2 emission sources, health, and environmental impacts of CO2 towards the human beings, options for CCS, and different CO2 separation technologies. Apart from the above, different synthesis routes of carbon-based adsorbents using various precursors have been elucidated. The CO2 adsorption selectivity, capacity, and reusability of the current and applied carbon materials have also been summarized. Furthermore, the critical factors controlling the adsorption performance (e.g., the effect of textural and functional properties) are comprehensively discussed. Finally, the current challenges and future research directions have also been summarized.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 13, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 397, "DOI": "10.3390/atmos13030397", "DOI Link": "http://dx.doi.org/10.3390/atmos13030397", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000775896900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singha, R; Pariari, AK; Satpati, B; Mandal, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singha, Ratnadwip; Pariari, Arnab Kumar; Satpati, Biswarup; Mandal, Prabhat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large nonsaturating magnetoresistance and signature of nondegenerate Dirac nodes in ZrSiS", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Whereas the discovery of Dirac-andWeyl-type excitations in ele-ctronic systems is a major breakthrough in recent condensed matter physics, finding appropriate materials for fundamental physics and technological applications is an experimental challenge. In all of the reported materials, linear dispersion survives only up to a few hundred millielectronvolts from the Dirac or Weyl nodes. On the other hand, real materials are subject to uncontrolled dop-ing during preparation and thermal effect near room temperature can hinder the rich physics. In ZrSiS, angle-resolved photoemission spectroscopy measurements have shown an unusually robust lin-ear dispersion (up to similar to 2 eV) with multiple nondegenerate Dirac nodes. In this context, we present the magnetotransport study on ZrSiS crystal, which represents a large family of materials (WHM with W = Zr, Hf; H = Si, Ge, Sn; M = O, S, Se, Te) with identi-cal band topology. Along with extremely large and nonsaturating magnetoresistance (MR),similar to 1.4 x 10(5)% at 2 K and 9 T, it shows strong anisotropy, depending on the direction of the magnetic field. Quantum oscillation and Hall effect measurements have revealed large hole and small electron Fermi pockets. A nontriv-ial pi Berry phase confirms the Dirac fermionic nature for both types of charge carriers. The long-sought relativistic phenomenon of massless Dirac fermions, known as the Adler-Bell-Jackiw chiral anomaly, has also been observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2017, "Volume": 114, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2468, "End Page": 2473, "Article Number": null, "DOI": "10.1073/pnas.1618004114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1618004114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395511400046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wiedenmann, J; Bocquillon, E; Deacon, RS; Hartinger, S; Herrmann, O; Klapwijk, TM; Maier, L; Ames, C; Brüne, C; Gould, C; Oiwa, A; Ishibashi, K; Tarucha, S; Buhmann, H; Molenkamp, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wiedenmann, J.; Bocquillon, E.; Deacon, R. S.; Hartinger, S.; Herrmann, O.; Klapwijk, T. M.; Maier, L.; Ames, C.; Bruene, C.; Gould, C.; Oiwa, A.; Ishibashi, K.; Tarucha, S.; Buhmann, H.; Molenkamp, L. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4π-periodic Josephson supercurrent in HgTe-based topological Josephson junctions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Josephson effect describes the generic appearance of a supercurrent in a weak link between two superconductors. Its exact physical nature deeply influences the properties of the supercurrent. In recent years, considerable efforts have focused on the coupling of superconductors to the surface states of a three-dimensional topological insulator. In such a material, an unconventional induced p-wave superconductivity should occur, with a doublet of topologically protected gapless Andreev bound states, whose energies vary 4 pi-periodically with the superconducting phase difference across the junction. In this article, we report the observation of an anomalous response to rf irradiation in a Josephson junction made of a HgTe weak link. The response is understood as due to a 4 pi-periodic contribution to the supercurrent, and its amplitude is compatible with the expected contribution of a gapless Andreev doublet. Our work opens the way to more elaborate experiments to investigate the induced superconductivity in a three-dimensional insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 320, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10303, "DOI": "10.1038/ncomms10303", "DOI Link": "http://dx.doi.org/10.1038/ncomms10303", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369019100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Breschi, L; Maravic, T; Cunha, SR; Comba, A; Cadenaro, M; Tjäderhane, L; Pashley, DH; Tay, FR; Mazzoni, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Breschi, Lorenzo; Maravic, Tatjana; Cunha, Sandra Ribeiro; Comba, Allegra; Cadenaro, Milena; Tjaderhane, Leo; Pashley, David H.; Tay, Franklin R.; Mazzoni, Annalisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dentin bonding systems: From dentin collagen structure to bond preservation and clinical applications", "Source Title": "DENTAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objectives. Efforts towards achieving durable resin-dentin bonds have been made for decades, including the understanding of the mechanisms underlying hybrid layer (HL) degradation, manufacturing of improved adhesive systems, as well as developing strategies for the preservation of the HL. Methods. This study critically discusses the available peer-reviewed research concerning the formation and preservation of the HL, the mechanisms that lead to the degradation of the HL as well as the strategies to prevent it. Results. The degradation of the HL occurs through two main mechanisms: the enzymatic degradation of its collagen fibrils, and the leaching of the resin from the HL. They are enabled by residual unbound water between the denuded collagen fibrils, trapped at the bottom of the HL. Consequently, endogenous dentinal enzymes, such as the matrix metalloproteinases (MMPs) and cysteine cathepsins are activated and can degrade the denuded collagen matrix. Strategies for the preservation of the HL over time have been developed, and they entail the removal of the unbound water from the gaps between the collagen fibrils as well as different modes of silencing endogenous enzymatic activity. Significance. Although there are many more hurdles to be crossed in the field of adhesive dentistry, impressive progress has been achieved so far, and the vast amount of available research on the topic is an indicator of the importance of this matter and of the great efforts of researchers and dental material companies to reach a new level in the quality and longevity of resin-dentin bonds. (C) 2017 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 313, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 34, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 96, "Article Number": null, "DOI": "10.1016/j.dental.2017.11.005", "DOI Link": "http://dx.doi.org/10.1016/j.dental.2017.11.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Dentistry, Oral Surgery & Medicine; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418642500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pescetelli, S; Agresti, A; Viskadouros, G; Razza, S; Rogdakis, K; Kalogerakis, I; Spiliarotis, E; Leonardi, E; Mariani, P; Sorbello, L; Pierro, M; Cornaro, C; Bellani, S; Najafi, L; Martín-García, B; Castillo, AED; Oropesa-Nuñez, R; Prato, M; Maranghi, S; Parisi, ML; Sinicropi, A; Basosi, R; Bonaccorso, F; Kymakis, E; Di Carlo, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pescetelli, Sara; Agresti, Antonio; Viskadouros, George; Razza, Stefano; Rogdakis, Konstantinos; Kalogerakis, Ioannis; Spiliarotis, Emmanuel; Leonardi, Enrico; Mariani, Paolo; Sorbello, Luca; Pierro, Marco; Cornaro, Cristina; Bellani, Sebastiano; Najafi, Leyla; Martin-Garcia, Beatriz; Castillo, Antonio Esau Del Rio; Oropesa-Nunez, Reinier; Prato, Mirko; Maranghi, Simone; Parisi, Maria Laura; Sinicropi, Adalgisa; Basosi, Riccardo; Bonaccorso, Francesco; Kymakis, Emmanuel; Di Carlo, Aldo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of two-dimensional materials-based perovskite solar panels into a stand-alone solar farm", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a vital step towards the industrialization of perovskite solar cells, outdoor field tests of large-scale perovskite modules and panels represent a mandatory step to be accomplished. Here we demonstrate the manufacturing of large-area (0.5 m(2)) perovskite solar panels, each containing 40 modules whose interfaces are engineered with two-dimensional materials (GRAphene-PErovskite (GRAPE) panels). We further integrate nine GRAPE panels for a total panel area of 4.5 m(2) in a stand-alone solar farm infrastructure with peak power exceeding 250 W, proving the scalability of this technology. We provide insights on the system operation by analysing the panel characteristics as a function of temperature and light intensity. The analysis, carried out over a months-long timescale, highlights the key role of the lamination process of the panels on the entire system degradation. A life-cycle assessment based on primary data indicates the high commercial potential of the GRAPE panel technology in terms of energy and environmental performances. Demonstration of scalability, manufacturability and outdoor operation is key to the deployment of perovskite solar cells. Now, Pescetelli et al. fabricate a large number of perovskite solar modules, assemble them in panels and integrate them in an outdoor 4.5 m(2) solar farm infrastructure whose operation is monitored over 12 months.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 597, "End Page": 607, "Article Number": null, "DOI": "10.1038/s41560-022-01035-4", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01035-4", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000811990400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, ZH; Li, XD; Mullen, JT; Kim, KW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Zhenghe; Li, Xiaodong; Mullen, Jeffrey T.; Kim, Ki Wook", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic transport properties of electrons and holes in monolayer transition-metal dichalcogenides", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsic electron-and hole-phonon interactions are investigated in monolayer transition-metal dichalcogenides MX2 (M=Mo, W; X=S, Se) based on a density functional theory formalism. Due to their structural similarities, all four materials exhibit qualitatively comparable scattering characteristics with the acoustic phonons playing a dominullt role near the conduction and valence band extrema at the K point. However, substantial differences are observed quantitatively leading to disparate results in the transport properties. Of those considered, WS2 provides the best performance for both electrons and holes with high mobilities and saturation velocities in the full-band Monte Carlo analysis of the Boltzmann transport equation. It is also found that monolayer MX2 crystals with an exception of MoSe2 generally show hole mobilities comparable to or even larger than the value for bulk silicon at room temperature, suggesting a potential opportunity in p-type devices. The analysis is extended to estimate the effective deformation potential constants for a simplified treatment as well.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 429, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 24", "Publication Year": 2014, "Volume": 90, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45422, "DOI": "10.1103/PhysRevB.90.045422", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.045422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341253000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YK; Tian, Y; Zhang, ZQ; Jia, YS; Zhang, B; Jiang, MQ; Wang, J; Ren, ZM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yikun; Tian, Yun; Zhang, Zhenqian; Jia, Youshun; Zhang, Bin; Jiang, Minqiang; Wang, Jiang; Ren, Zhongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic properties and giant cryogenic magnetocaloric effect in B-site ordered antiferromagnetic Gd2MgTiO6 double perovskite oxide", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The magnetic refrigeration (MR) technology by utilizing the magnetocaloric (MC) effects of magnetic solids have been realized to be a promising energy efficiency and environmentally friendly technology. Developing or discovering proper magnetic solids with promising MC performances is one of the most important tasks at present stage since a huge gap still exists between the requirement of practical MR application and the MC performances of the magnetic solids. Herein, we reported a combined theoretical and experimental investigation of the crystal structure together with the magnetic properties, magnetic phase transition (MPT) and MC performances in Gd2MgTiO6 oxide. The Gd2MgTiO6 is confirmed to crystalize in a B-site ordered monoclinic double perovskite (DP) crystal structure. A rather unstable anti ferromagnetic (AFM) interaction with large magnetic moment and semi-conductor characteristic with the band gap of 2.977 eV have been confirmed in Gd2MgTiO6 DP oxide at ground state. Giant reversible cryogenic MC effect together with excellent MC performances have been confirmed by a series of the figure of merits including the values of maximum magnetic entropy change (-Delta S-M) and refrigerant capacity ( RC ), which are evaluated to be 46.21 J/kgK and 300.27 J/kg around 3.3 K with the magnetic change of 0-7 T, these values are much better than most of the recently reported famous cryogenic MC materials and the commercialized magnetic refrigerants gadolinium gallium garnet (GGG) as well. The observed excellent MC performances suggest that Gd2MgTiO6 DP oxide is a promising candidate material for cryogenic MR applications. (c) 2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 226, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 117669, "DOI": "10.1016/j.actamat.2022.117669", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2022.117669", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789635400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arachchige, HWS; Meier, WR; Marshall, M; Matsuoka, T; Xue, R; McGuire, MA; Hermann, RP; Cao, HB; Mandrus, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arachchige, Hasitha W. Suriya; Meier, William R.; Marshall, Madalynn; Matsuoka, Takahiro; Xue, Rui; McGuire, Michael A.; Hermann, Raphael P.; Cao, Huibo; Mandrus, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge Density Wave in Kagome Lattice Intermetallic ScV6Sn6", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials hosting kagome lattices have drawn interest for the diverse magnetic and electronic states generated by geometric frustration. In the AV(3)Sb(5) compounds (A = K, Rb, Cs), stacked vanadium kagome layers give rise to unusual charge density waves (CDW) and superconductivity. Here we report singlecrystal growth and characterization of ScV6Sn6, a hexagonal HfFe6Ge6-type compound that shares this structural motif. We identify a first-order phase transition at 92 K. Single crystal x-ray and neutron diffraction reveal a charge density wave modulation of the atomic lattice below this temperature. This is a distinctly different structural mode than that observed in the AV(3)Sb(5) compounds, but both modes have been anticipated in kagome metals. The diverse HfFe6Ge6 family offers more opportunities to tune ScV6Sn6 and explore density wave order in kagome lattice materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2022, "Volume": 129, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 216402, "DOI": "10.1103/PhysRevLett.129.216402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.129.216402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000917059900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, C; Xia, RX; Shi, H; Yao, HF; Liu, X; Hou, JH; Huang, F; Yip, HL; Cao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Chen; Xia, Ruoxi; Shi, Hui; Yao, Huifeng; Liu, Xiang; Hou, Jianhui; Huang, Fei; Yip, Hin-Lap; Cao, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heat-Insulating Multifunctional Semitransparent Polymer Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semitransparent organic photovoltaics (ST-OPVs) have attracted extensive attention due to their potential for integration into the windows of buildings. Herein, we propose a dual-functional ST-OPV device that is not only highly efficient but also very effective for heat insulation. By introducing non-fullerene acceptor with enhanced near-infrared absorption and distributed Bragg reflectors for selectively enhancing the transmittance in visible wavelengths while keeping high reflectance for near-infrared light, the ST-OPVs generate over 6% power conversion efficiency with high visible light transmission of over 25% and outstanding infrared radiation rejection rate of over 80%. Our results show that with proper design of ST-OPVs, they can be used not only for generating power from sunlight but also for solar shading and heat insulation, which opens up a new application of OPVs for both energy harvesting and saving.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2018, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1816, "End Page": 1826, "Article Number": null, "DOI": "10.1016/j.joule.2018.06.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.06.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445021000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiménez, M; Romero, L; Domínguez, IA; Espinosa, MD; Domínguez, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jimenez, Mariano; Romero, Luis; Dominguez, Iris A.; del Mar Espinosa, Maria; Dominguez, Manuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive Manufacturing Technologies: An Overview about 3D Printing Methods and Future Prospects", "Source Title": "COMPLEXITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of conventional manufacturing methods is mainly limited by the size of the production run and the geometrical complexity of the component, and as a result we are occasionally forced to use processes and tools that increase the final cost of the element being produced. Additive manufacturing techniques provide major competitive advantages due to the fact that they adapt to the geometrical complexity and customised design of the part to be manufactured. The following may also be achieved according to field of application: lighter weight products, multimaterial products, ergonomic products, efficient short production runs, fewer assembly errors and, therefore, lower associated costs, lower tool investment costs, a combination of different manufacturing processes, an optimised use of materials, and a more sustainable manufacturing process. Additive manufacturing is seen as being one of the major revolutionary industrial processes of the next few years. Additive manufacturing has several alternatives ranging from simple RepRap machines to complex fused metal deposition systems. This paper will expand upon the structural design of the machines, their history, classification, the alternatives existing today, materials used and their characteristics, the technology limitations, and also the prospects that are opening up for different technologies both in the professional field of innovation and the academic field of research. It is important to say that the choice of technology is directly dependent on the particular application being planned: first the application and then the technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9656938, "DOI": "10.1155/2019/9656938", "DOI Link": "http://dx.doi.org/10.1155/2019/9656938", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460236400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smejkal, L; Hellenes, AB; González-Hernández, R; Sinova, J; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smejkal, Libor; Hellenes, Anna Birk; Gonzalez-Hernulldez, Rafael; Sinova, Jairo; Jungwirth, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant and Tunneling Magnetoresistance in Unconventional Collinear Antiferromagnets with Nonrelativistic-Momentum", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Giant and tunneling magnetoresistance are physical phenomena used for reading information in commercial spintronic devices. The effects rely on a conserved spin current passing between a reference and a sensing ferromagnetic electrode in a multilayer structure. Recently, we have proposed that these fundamental spintronic effects can be realized in unconventional collinear antiferromagnets with nonrelativistic alternating spin-momentum coupling. Here, we elaborate on the proposal by presenting archetype model mechanisms for the giant and tunneling magnetoresistance effects in multilayers composed of these unconventional collinear antiferromagnets. The models are based, respectively, on anisotropic and valley-dependent forms of the alternating spin-momentum coupling. Using first-principles calculations, we link these model mechanisms to real materials and predict an approximately 100% scale for the effects. We point out that, besides the giant or tunneling magnetoresistance detection, the alternating spin-momentum coupling can allow for magnetic excitation by the spin-transfer torque.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1103/PhysRevX.12.011028", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.12.011028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754669000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Murali, A; Lokhande, G; Deo, KA; Brokesh, A; Gaharwar, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Murali, Aparna; Lokhande, Giriraj; Deo, Kaivalya A.; Brokesh, Anna; Gaharwar, Akhilesh K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emerging 2D nullomaterials for biomedical applications", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) nullomaterials are an emerging class of biomaterials with remarkable potential for biomedical applications. The planar topography of these nullomaterials confers unique physical, chemical, electronic and optical properties, making them attractive candidates for therapeutic delivery, biosensing, bioimaging, regenerative medicine, and additive manufacturing strategies. The high surface-to-volume ratio of 2D nullomaterials promotes enhanced interactions with biomolecules and cells. A range of 2D nullomaterials, including transition metal dichalcogenides (TMDs), layered double hydroxides (LDHs), layered silicates (nulloclays), 2D metal carbides and nitrides (MXenes), metal-organic framework (MOFs), covalent organic frameworks (COFs) and polymer nullosheets have been investigated for their potential in biomedical applications. Here, we will critically evaluate recent advances of 2D nullomaterial strategies in biomedical engineering and discuss emerging approaches and current limitations associated with these nullomaterials. Due to their unique physical, chemical, and biological properties, this new class of nullomaterials has the potential to become a platform technology in regenerative medicine and other biomedical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 276, "End Page": 302, "Article Number": null, "DOI": "10.1016/j.mattod.2021.04.020", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.04.020", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731397100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jariwala, D; Davoyan, AR; Wong, J; Atwater, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jariwala, Deep; Davoyan, Artur R.; Wong, Joeson; Atwater, Harry A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals Materials for Atomically-Thin Photovoltaics: Promise and Outlook", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) semiconductors provide a unique opportunity for optoelectronics due to their layered atomic structure and electronic and optical properties. To date, a majority of the application oriented research in this field has been focused on field-effect electronics as well as photodetectors and light emitting diodes. Here we present a perspective on the use of 2D semiconductors for photovoltaic applications. We discuss photonic device designs that enable light trapping in nullometer-thickness absorber layers, and we also outline schemes for efficient carrier transport and collection. We further provide theoretical estimates of efficiency indicating that 2D semiconductors can indeed be competitive with and complementary to conventional photovoltaics, based on favorable energy bandgap, absorption, external radiative efficiency, along with recent experimental demonstrations. Photonic and electronic design of 2D semiconductor photovoltaics represents a new direction for realizing ultrathin, efficient solar cells with applications ranging from conventional power generation to portable and ultralight solar power.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 2962, "End Page": 2970, "Article Number": null, "DOI": "10.1021/acsphotonics.7b01103", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.7b01103", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418786000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, HR; Yang, YH; Liu, GG; Gao, F; Chong, YD; Zhang, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Haoran; Yang, Yahui; Liu, Guigeng; Gao, Fei; Chong, Yidong; Zhang, Baile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of an Acoustic Third-Order Topological Insulator", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of higher-order topological insulators (TIs) has opened new possibilities in the search for novel topological materials and metamaterials. Second-order TIs have been implemented in two-dimensional (2D) systems exhibiting topological corner states, as well as three-dimensional (3D) systems having one-dimensional (1D) topological hinge states. Third-order TIs, which have topological states three dimensions lower than the bulk (which must thus be 3D or higher), have not yet been reported. Here, we describe the realization of a third-order TI in an anisotropic diamond-lattice acoustic metamaterial. The bulk acoustic band structure has nontrivial topology characterized by quantized Wannier centers. By direct acoustic measurement, we observe corner states at two corners of a rhombohedronlike structure, as predicted by the quantized Wannier centers. This work extends topological corner states from 2D to 3D, and may find applications in novel acoustic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2019, "Volume": 122, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 244301, "DOI": "10.1103/PhysRevLett.122.244301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.244301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473034200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "MacCabe, GS; Ren, HJ; Luo, J; Cohen, JD; Zhou, HY; Sipahigil, A; Mirhosseini, M; Painter, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "MacCabe, Gregory S.; Ren, Hengjiang; Luo, Jie; Cohen, Justin D.; Zhou, Hengyun; Sipahigil, Alp; Mirhosseini, Mohammad; Painter, Oskar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullo-acoustic resonator with ultralong phonon lifetime", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The energy damping time in a mechanical resonator is critical to many precision metrology applications, such as timekeeping and force measurements. We present measurements of the phonon lifetime of a microwave-frequency, nulloscale silicon acoustic cavity incorporating a phononic bandgap acoustic shield. Using pulsed laser light to excite a colocalized optical mode of the cavity, we measured the internal acoustic modes with single-phonon sensitivity down to millikelvin temperatures, yielding a phonon lifetime of up to tau(ph,0) approximate to 1.5 seconds (quality factor Q = 5 x 10(10)) and a coherence time of tau(coh,0) approximate to 130 microseconds for bandgap-shielded cavities. These acoustically engineered nulloscale structures provide a window into the material origins of quantum noise and have potential applications ranging from tests of various collapse models of quantum mechanics to miniature quantum memory elements in hybrid superconducting quantum circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 13", "Publication Year": 2020, "Volume": 370, "Issue": 6518, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 840, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abc7312", "DOI Link": "http://dx.doi.org/10.1126/science.abc7312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000590522900061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, SQ; Lu, CH; Zhu, XY; Li, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Siqi; Lu, Chenghong; Zhu, Xingyi; Li, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation and Characterization of High-Strength Geopolymer Based on BH-1 Lunar Soil Simulant with Low Alkali Content", "Source Title": "ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The construction of a lunar base and habitation on the Moon has always been on researchers' minds. Building materials used in in situ lunar resources are of great significance for saving expensive space freight. In this study, a new type of lunar soil simulant named Beihang (BH)-1 was developed. The chemical mineral composition and microstructure of BH-1 closely resemble those of real lunar soil, as verified by X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), and reflectance spectra. This research also synthesized a geopolymer based on BH-1 cured at simulated lunar atmospheric conditions. We also investigated the effect of supplementing aluminum (Al) sources on the enhancement of geopolymer strength based on BH-1. The rheological behavior of alkali-activated BH-1 pastes was determined for workability. XRF, XRD, Fourier transform infrared spectroscopy, SEM coupled with energy dispersive spectroscopy, and Al-27 magic angle spinning-nuclear magnetic resonullce were used to characterize resulting geopolymers. Rheological test findings showed that the rheology of BH-1 pastes fits the Herschel-Bulkley model, and they behaved like a shear-thinning fluid. The results showed that the 28-day compressive strength of the BH-1 geopolymer was improved by up to 100.8%. Meanwhile, the weight of additives required to produce per unit strength decreased, significantly reducing the mass of materials transported from the Earth for the construction of lunar infrastructure and saving space transportation costs. Microscopic analyses showed that the mechanism to improve the mechanical properties of the BH-1 geopolymer by adding an additional Al source enhances the replacement of silicon atoms by Al atoms in the silicon-oxygen group and generates a more complete and dense amorphous gel structure. (C) 2020 THE AUTHORS. Published by Elsevier LTD on behalf of Chinese Academy of Engineering and Higher Education Press Limited Company.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1631, "End Page": 1645, "Article Number": null, "DOI": "10.1016/j.eng.2020.10.016", "DOI Link": "http://dx.doi.org/10.1016/j.eng.2020.10.016", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000738823500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mi, X; Cady, JV; Zajac, DM; Deelman, PW; Petta, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mi, X.; Cady, J. V.; Zajac, D. M.; Deelman, P. W.; Petta, J. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong coupling of a single electron in silicon to a microwave photon", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon is vital to the computing industry because of the high quality of its native oxide and well-established doping technologies. Isotopic purification has enabled quantum coherence times on the order of seconds, thereby placing silicon at the forefront of efforts to create a solid-state quantum processor. We demonstrate strong coupling of a single electron in a silicon double quantum dot to the photonic field of a microwave cavity, as shown by the observation of vacuum Rabi splitting. Strong coupling of a quantum dot electron to a cavity photon would allow for long-range qubit coupling and the long-range entanglement of electrons in semiconductor quantum dots.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2017, "Volume": 355, "Issue": 6321, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aal2469", "DOI Link": "http://dx.doi.org/10.1126/science.aal2469", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391743700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chan, CK; Lindner, NH; Refael, G; Lee, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chan, Ching-Kit; Lindner, Netanel H.; Refael, Gil; Lee, Patrick A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocurrents in Weyl semimetals", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The generation of photocurrent in an ideal two-dimensional Dirac spectrum is symmetry forbidden. In sharp contrast, we show that three-dimensionalWeyl semimetals can generically support significant photocurrents due to the combination of inversion symmetry breaking and finite tilts of the Weyl spectra. Symmetry properties, chirality relations, and various dependencies of this photovoltaic effect on the system and the light source are explored in detail. Our results suggest that noncentrosymmetric Weyl materials can be advantageously applied to room temperature detections of mid-and far-infrared radiations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2017, "Volume": 95, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41104, "DOI": "10.1103/PhysRevB.95.041104", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.041104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391856700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Zhang, YY; Chen, L; Guo, BL; Tan, YS; Sasaki, K; Tsang, DCW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Zhang, Yuying; Chen, Liang; Guo, Binglin; Tan, Yongshan; Sasaki, Keiko; Tsang, Daniel C. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing novel magnesium oxysulfate cement for stabilization/solidification of municipal solid waste incineration fly ash", "Source Title": "JOURNAL OF HAZARDOUS MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Municipal solid waste incineration (MSWI) fly ash is a typical hazardous waste worldwide. In this study, an innovative magnesium oxysulfate cement (MOSC) binder was designed for stabilization/solidification (S/S) of MSWI fly ash, focusing on the interactions between MOSC binder and typical metallic cations (Pb2+)/oxyanions (AsO33-). Experimental results showed that Pb and As slightly inhibited the reaction of high-sulfate 5MS system but significantly suppressed the reaction process of low-sulfate 10MS system. The 5MS binder system exhibited excellent immobilization efficiencies (99.8%) for both Pb and As. The extended X-ray absorption fine structure spectra suggested that Pb2+ coordinated with SO42-/OH- in the MOSC system and substituted Mg2+ ion sites in the internal structure of 5Mg(OH)(2)center dot MgSO4 center dot 7H(2)O (5-1-7) phase. In contrast, the AsO(3)(3-)substituted SO(4)(2-)sites with the formation of inner-sphere complexes with Mg2+ in the large interlayer space of the 5-1-7 structure. Subsequent MSWI fly ash S/S experiments showed that a small amount of reactive Si in MSWI fly ash interfered with the MOSC reaction and adversely influenced the immobilization efficiencies of Pb, As, and other elements. Through the use of 33 wt% tailored MOSC binder for MSWI fly ash treatment, a satisfying S/S performance could be achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2022, "Volume": 423, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127025, "DOI": "10.1016/j.jhazmat.2021.127025", "DOI Link": "http://dx.doi.org/10.1016/j.jhazmat.2021.127025", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000713262900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalashnikov, DA; Paterova, AV; Kulik, SP; Krivitsky, LA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalashnikov, Dmitry A.; Paterova, Anna V.; Kulik, Sergei P.; Krivitsky, Leonid A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared spectroscopy with visible light", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spectral measurements in the infrared optical range provide unique fingerprints of materials, which are useful for material analysis, environmental sensing and health diagnostics(1). Current infrared spectroscopy techniques require the use of optical equipment suited for operation in the infrared range, components of which face challenges of inferior performance and high cost. Here, we develop a technique that allows spectral measurements in the infrared range using visible-spectral-range components. The technique is based on nonlinear interference of infrared and visible photons, produced via spontaneous parametric down conversion(2,3). The intensity interference pattern for a visible photon depends on the phase of an infrared photon travelling through a medium. This allows the absorption coefficient and refractive index of the medium in the infrared range to be determined from the measurements of visible photons. The technique can substitute and/or complement conventional infrared spectroscopy and refractometry techniques, as it uses well-developed components for the visible range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 98, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.252", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.252", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369321400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carozo, V; Wang, YX; Fujisawa, K; Carvalho, BR; McCreary, A; Feng, SM; Lin, Z; Zhou, CJ; Perea-López, N; Elías, AL; Kabius, B; Crespi, VH; Terrones, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carozo, Victor; Wang, Yuanxi; Fujisawa, Kazunori; Carvalho, Bruno R.; McCreary, Amber; Feng, Simin; Lin, Zhong; Zhou, Chanjing; Perea-Lopez, Nestor; Laura Elias, Ana; Kabius, Bernd; Crespi, Vincent H.; Terrones, Mauricio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical identification of sulfur vacancies: Bound excitons at the edges of monolayer tungsten disulfide", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects play a significant role in tailoring the optical properties of two-dimensional materials. Optical signatures of defect-bound excitons are important tools to probe defective regions and thus interrogate the optical quality of asgrown semiconducting monolayer materials. We have performed a systematic study of defect-bound excitons using photoluminescence (PL) spectroscopy combined with atomically resolved scanning electron microscopy and firstprinciples calculations. Spatially resolved PL spectroscopy at low temperatures revealed bound excitons that were present only on the edges of monolayer tungsten disulfide and not in the interior. Optical pumping of the bound excitons was sublinear, confirming their bound nature. Atomic-resolution images reveal that the areal density of monosulfur vacancies is much larger near the edges (0.92 +/- 0.45 nm(-2)) than in the interior (0.33 +/- 0.11 nm(-2)). Temperature- dependent PL measurements found a thermal activation energy of similar to 36 meV; surprisingly, this is much smaller than the bound-exciton binding energy of similar to 300 meV. We show that this apparent inconsistency is related to a thermal dissociation of the bound exciton that liberates the neutral excitons from negatively charged point defects. First-principles calculations confirm that sulfur monovacancies introduce midgap states that host optical transitions with finite matrix elements, with emission energies ranging from 200 to 400 meV below the neutral-exciton emission line. These results demonstrate that bound-exciton emission induced by monosulfur vacancies is concentrated near the edges of as-grown monolayer tungsten disulfide.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602813", "DOI": "10.1126/sciadv.1602813", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602813", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jacobsson, TJ; Hultqvist, A; García-Fernández, A; Anulld, A; Al-Ashouri, A; Hagfeldt, A; Crovetto, A; Abate, A; Ricciardulli, AG; Vijayan, A; Kulkarni, A; Anderson, AY; Darwich, BP; Yang, BW; Coles, BL; Perini, CAR; Rehermann, C; Ramirez, D; Fairen-Jimenez, D; Di Girolamo, D; Jia, DL; Avila, E; Juarez-Perez, EJ; Baumann, F; Mathies, F; González, GSA; Boschloo, G; Nasti, G; Paramasivam, G; Martínez-Denegri, G; Näsström, H; Michaels, H; Köbler, H; Wu, H; Benesperi, I; Dar, MI; Pehlivan, IB; Gould, IE; Vagott, JN; Dagar, J; Kettle, J; Yang, J; Li, JZ; Smith, JA; Pascual, J; Jerónimo-Rendón, JJ; Montoya, JF; Correa-Baena, JP; Qiu, JM; Wang, JX; Sveinbjörnsson, K; Hirselandt, K; Dey, K; Frohna, K; Mathies, L; Castriotta, LA; Aldamasy, MH; Vasquez-Montoya, M; Ruiz-Preciado, MA; Flatken, MA; Khenkin, M; Grischek, M; Kedia, M; Saliba, M; Anaya, M; Veldhoen, M; Arora, N; Shargaieva, O; Maus, O; Game, OS; Yudilevich, O; Fassl, P; Zhou, QS; Betancur, R; Munir, R; Patidar, R; Stranks, SD; Alam, S; Kar, S; Unold, T; Abzieher, T; Edvinsson, T; David, TW; Paetzold, UW; Zia, W; Fu, WF; Zuo, WW; Schröder, VRF; Tress, W; Zhang, XL; Chiang, YH; Iqbal, Z; Xie, ZQ; Unger, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jacobsson, T. Jesper; Hultqvist, Adam; Garcia-Fernulldez, Alberto; Anulld, Aman; Al-Ashouri, Amran; Hagfeldt, Anders; Crovetto, Andrea; Abate, Antonio; Ricciardulli, Antonio Gaetano; Vijayan, Anuja; Kulkarni, Ashish; Anderson, Assaf Y.; Darwich, Barbara Primera; Yang, Bowen; Coles, Brendan L.; Perini, Carlo A. R.; Rehermann, Carolin; Ramirez, Daniel; Fairen-Jimenez, David; Di Girolamo, Diego; Jia, Donglin; Avila, Elena; Juarez-Perez, Emilio J.; Baumann, Fanny; Mathies, Florian; Gonzalez, G. S. Anaya; Boschloo, Gerrit; Nasti, Giuseppe; Paramasivam, Gopinath; Martinez-Denegri, Guillermo; Nasstrom, Hampus; Michaels, Hannes; Kobler, Hans; Wu, Hua; Benesperi, Iacopo; Dar, M. Ibrahim; Pehlivan, Ilknur Bayrak; Gould, Isaac E.; Vagott, Jacob N.; Dagar, Janardan; Kettle, Jeff; Yang, Jie; Li, Jinzhao; Smith, Joel A.; Pascual, Jorge; Jeronimo-Rendon, Jose J.; Montoya, Juan Felipe; Correa-Baena, Juan-Pablo; Qiu, Junming; Wang, Junxin; Sveinbjornsson, Kari; Hirselandt, Katrin; Dey, Krishanu; Frohna, Kyle; Mathies, Lena; Castriotta, Luigi A.; Aldamasy, Mahmoud H.; Vasquez-Montoya, Manuel; Ruiz-Preciado, Marco A.; Flatken, Marion A.; Khenkin, Mark, V; Grischek, Max; Kedia, Mayank; Saliba, Michael; Anaya, Miguel; Veldhoen, Misha; Arora, Neha; Shargaieva, Oleksandra; Maus, Oliver; Game, Onkar S.; Yudilevich, Ori; Fassl, Paul; Zhou, Qisen; Betancur, Rafael; Munir, Rahim; Patidar, Rahul; Stranks, Samuel D.; Alam, Shahidul; Kar, Shaoni; Unold, Thomas; Abzieher, Tobias; Edvinsson, Tomas; David, Tudur Wyn; Paetzold, Ulrich W.; Zia, Waqas; Fu, Weifei; Zuo, Weiwei; Schroeder, Vincent R. F.; Tress, Wolfgang; Zhang, Xiaoliang; Chiang, Yu-Hsien; Iqbal, Zafar; Xie, Zhiqiang; Unger, Eva", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An open-access database and analysis tool for perovskite solar cells based on the FAIR data principles", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Making large datasets findable, accessible, interoperable and reusable could accelerate technology development. Now, Jacobsson et al. present an approach to build an open-access database and analysis tool for perovskite solar cells. Large datasets are now ubiquitous as technology enables higher-throughput experiments, but rarely can a research field truly benefit from the research data generated due to inconsistent formatting, undocumented storage or improper dissemination. Here we extract all the meaningful device data from peer-reviewed papers on metal-halide perovskite solar cells published so far and make them available in a database. We collect data from over 42,400 photovoltaic devices with up to 100 parameters per device. We then develop open-source and accessible procedures to analyse the data, providing examples of insights that can be gleaned from the analysis of a large dataset. The database, graphics and analysis tools are made available to the community and will continue to evolve as an open-source initiative. This approach of extensively capturing the progress of an entire field, including sorting, interactive exploration and graphical representation of the data, will be applicable to many fields in materials science, engineering and biosciences.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 107, "End Page": 115, "Article Number": null, "DOI": "10.1038/s41560-021-00941-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00941-3", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000729687900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Imani, IM; Kim, B; Xiao, X; Rubab, N; Park, BJ; Kim, YJ; Zhao, P; Kang, MK; Kim, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Imani, Iman M.; Kim, Bosung; Xiao, Xiao; Rubab, Najaf; Park, Byung-Joon; Kim, Young-Jun; Zhao, Pin; Kang, Minki; Kim, Sang-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasound-Driven On-Demand Transient Triboelectric nullogenerator for Subcutaneous Antibacterial Activity", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To prevent surgical site infection (SSI), which significantly increases the rate morbidity and mortality, eliminating microorganisms is prominent. Antimicrobial resistance is identified as a global health challenge. This work proposes a new strategy to eliminate microorganisms of deep tissue through electrical stimulation with an ultrasound (US)-driven implantable, biodegradable, and vibrant triboelectric nullogenerator (IBV-TENG). After a programmed lifetime, the IBV-TENG can be eliminated by provoking the on-demand device dissolution by controlling US intensity with no surgical removal of the device from the body. A voltage of approximate to 4 V and current of approximate to 22 mu A generated from IBV-TENG under ultrasound in vitro, confirming inactivating approximate to 100% of Staphylococcus aureus and approximate to 99% of Escherichia coli. Furthermore, ex vivo results show that IBV-TENG implanted under porcine tissue successfully inactivates bacteria. This antibacterial technology is expected to be a countermeasure strategy against SSIs, increasing life expectancy and healthcare quality by preventing microorganisms of deep tissue.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2023, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202204801", "DOI Link": "http://dx.doi.org/10.1002/advs.202204801", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891017700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, WC; Du, LL; Xia, RQ; Liang, RH; Zhou, T; Lee, HK; Yan, ZP; Luo, H; Shang, CX; Phillips, DL; Guo, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Wenchao; Du, Lili; Xia, Ruiqin; Liang, Runhui; Zhou, Tao; Lee, Hung Kay; Yan, Zhiping; Luo, Hao; Shang, Congxiao; Phillips, David Lee; Guo, Zhengxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ protonated-phosphorus interstitial doping induces long-lived shallow charge trapping in porous C3-xN4 photocatalysts for highly efficient H2 generation", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient photocatalytic solar-to-H-2 conversion is pivotal to zero-carbon energy supply. Graphitic carbon nitride (g-C3N4) is a promising visible-light photocatalyst but suffers from intrinsic electron-hole recombination and deep-charge trapping, limiting its efficiency. Here, we show a synergistic strategy of porosity, vacancy and shallow(trapping)-state engineering to enrich catalytic sites and promote the lifetime of active electrons by thermochemical treatment and phosphorus-interstitial-doping. The latter enhances the electron delocalization in the pi-conjugate polymeric structure. The optimized photocatalyst shows a similar to 800% increase in H-2 generation (6323 mu mol h(-1) g(-1)) and an about 5-fold increase in quantum efficiency (QE(420 nm) = 5.08%). The superior performance is attributed to the long-lived shallow charge trapping, as a result of proton-feeding to the coordinated phosphorus site during the photocatalytic reaction, which enhances the photogenerated carrier lifetime and positively optimizes the band structure of the catalyst. Femtosecond transient absorption spectroscopy reveals a doubling lifetime of shallow-trapped charges (similar to 405.5 ps), favoring high mobility for electron-involved photocatalytic H-2 generation. This work provides a new mechanism for improving charge carrier dynamics and photocatalytic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2023, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 460, "End Page": 472, "Article Number": null, "DOI": "10.1039/d2ee02680e", "DOI Link": "http://dx.doi.org/10.1039/d2ee02680e", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000898177500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YR; Polski, R; Thomson, A; Lantagne-Hurtubise, E; Lewandowski, C; Zhou, HX; Watanabe, K; Taniguchi, T; Alicea, J; Nadj-Perge, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yiran; Polski, Robert; Thomson, Alex; Lantagne-Hurtubise, Etienne; Lewandowski, Cyprian; Zhou, Haoxin; Watanabe, Kenji; Taniguchi, Takashi; Alicea, Jason; Nadj-Perge, Stevan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced superconductivity in spin-orbit proximitized bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the presence of a large perpendicular electric field, Bernal-stacked bilayer graphene (BLG) features several broken-symmetry metallic phases(1-3) as well as magnetic-field-induced superconductivity(1). The superconducting state is quite fragile, however, appearing only in a narrow window of density and with a maximum critical temperature T-c approximate to 30 mK. Here we show that placing monolayer tungsten diselenide (WSe2) on BLG promotes Cooper pairing to an extraordinary degree: superconductivity appears at zero magnetic field, exhibits an order of magnitude enhancement in T-c and occurs over a density range that is wider by a factor of eight. By mapping quantum oscillations in BLG-WSe2 as a function of electric field and doping, we establish that superconductivity emerges throughout a region for which the normal state is polarized, with two out of four spin-valley flavours predominulltly populated. In-plane magnetic field measurements further reveal that superconductivity in BLG-WSe2 can exhibit striking dependence of the critical field on doping, with the Chandrasekhar-Clogston (Pauli) limit roughly obeyed on one end of the superconducting dome, yet sharply violated on the other. Moreover, the superconductivity arises only for perpendicular electric fields that push BLG hole wavefunctions towards WSe2, indicating that proximity-induced (Ising) spin-orbit coupling plays a key role in stabilizing the pairing. Our results pave the way for engineering robust, highly tunable and ultra-clean graphene-based superconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 613, "Issue": 7943, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 268, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05446-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05446-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955880900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Otero-de-la-Roza, A; Johnson, ER; Luaña, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Otero-de-la-Roza, A.; Johnson, Erin R.; Luana, Victor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CRITIC2: A program for real-space analysis of quantum chemical interactions in solids", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present CRITIC2, a program for the analysis of quantum-mechanical atomic and molecular interactions in periodic solids. This code, a greatly improved version of the previous CRITIC program (Otero-de-la Roza et al., 2009), can: (i) find critical points of the electron density and related scalar fields such as the electron localization function (ELF), Laplacian,... (ii) integrate atomic properties in the framework of Bader's Atoms-in-Molecules theory (QTAIM), (iii) visualize non-covalent interactions in crystals using the non-covalent interactions (NCI) index, (iv) generate relevant graphical representations including lines, planes, gradient paths, contour plots, atomic basins,... and (v) perform transformations between file formats describing scalar fields and crystal structures. CRITIC2 can interface with the output produced by a variety of electronic structure programs including WIEN2k, elk, PI, abinit, Quantum ESPRESSO, VASP, Gaussian, and, in general, any other code capable of writing the scalar field under study to a three-dimensional grid. CRITIC2 is parallelized, completely documented (including illustrative test cases) and publicly available under the GNU General Public License. Program summary Program title: CRITIC2 Catalogue identifier: AECB_v2_0 Program summary URL: http://cpc.cs.qub.ac.uk/summaries/AECB_v2_0.html Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland Licensing provisions: yes No. of lines in distributed program, including test data, etc.: 11686949 No. of bytes in distributed program, including test data, etc.: 337020731 Distribution format: tar.gz Programming language: Fortran 77 and 90. Computer: Workstations. Operating system: Unix, GNU/Linux. Has the code been vectorized or parallelized?: Shared-memory parallelization can be used for most tasks. Classification: 7.3. Catalogue identifier of previous version: AECB_v1_0 Journal reference of previous version: Comput. Phys. Comm. 180 (2009) 157 Nature of problem: Analysis of quantum-chemical interactions in periodic solids by means of atoms-in-molecules and related formalisms. Solution method: Critical point search using Newton's algorithm, atomic basin integration using bisection, qtree and grid-based algorithms, diverse graphical representations and computation of the non-covalent interactions index on a three-dimensional grid. Additional comments: !!!!! The distribution file for this program is over 330 Mbytes and therefore is not delivered directly when download or Email is requested. Instead a html file giving details of how the program can be obtained is sent. !!!!! Running time: Variable, depending on the crystal and the source of the underlying scalar field. (C) 2013 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 603, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 185, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1007, "End Page": 1018, "Article Number": null, "DOI": "10.1016/j.cpc.2013.10.026", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2013.10.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331919100032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guan, XW; Kumar, P; Li, ZX; Tran, TKA; Chahal, S; Lei, ZH; Huang, CY; Lin, CH; Huang, JK; Hu, L; Chang, YC; Wang, L; Britto, JSJ; Panneerselvan, L; Chu, DW; Wu, TM; Karakoti, A; Yi, JB; Vinu, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guan, Xinwei; Kumar, Prashant; Li, Zhixuan; Tran, Thi Kim Anh; Chahal, Sumit; Lei, Zhihao; Huang, Chien-Yu; Lin, Chun-Ho; Huang, Jing-Kai; Hu, Long; Chang, Yuan-Chih; Wang, Li; Britto, Jolitta S. J.; Panneerselvan, Logeshwaran; Chu, Dewei; Wu, Tom; Karakoti, Ajay; Yi, Jiabao; Vinu, Ajayan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Borophene Embedded Cellulose Paper for Enhanced Photothermal Water Evaporation and Prompt Bacterial Killing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar-driven photothermal water evaporation is considered an elegant and sustainable technology for freshwater production. The existing systems, however, often suffer from poor stability and biofouling issues, which severely hamper their prospects in practical applications. Conventionally, photothermal materials are deposited on the membrane supports via vacuum-assisted filtration or dip-coating methods. Nevertheless, the weak inherent material-membrane interactions frequently lead to poor durability, and the photothermal material layer can be easily peeled off from the hosting substrates or partially dissolved when immersed in water. In the present article, the discovery of the incorporation of borophene into cellulose nullofibers (CNF), enabling excellent environmental stability with a high light-to-heat conversion efficiency of 91.5% and water evaporation rate of 1.45 kg m(-2) h(-1) under simulated sunlight is reported. It is also demonstrated that borophene papers can be employed as an excellent active photothermal material for eliminating almost 100% of both gram-positive and gram-negative bacteria within 20 min under three sun irradiations. The result opens a new direction for the design of borophene-based papers with unique photothermal properties which can be used for the effective treatment of a wide range of wastewaters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205809", "DOI Link": "http://dx.doi.org/10.1002/advs.202205809", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000920581900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kapfer, M; Jessen, BS; Eisele, ME; Fu, M; Danielsen, DR; Darlington, TP; Moore, SL; Finney, NR; Marchese, A; Hsieh, V; Majchrzak, P; Jiang, ZH; Biswas, D; Dudin, P; Avila, J; Watanabe, K; Taniguchi, T; Ulstrup, S; Boggild, P; Schuck, PJ; Basov, DN; Hone, J; Dean, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kapfer, Maelle; Jessen, Bjarke S.; Eisele, Megan E.; Fu, Matthew; Danielsen, Dorte R.; Darlington, Thomas P.; Moore, Samuel L.; Finney, Nathan R.; Marchese, Ariane; Hsieh, Valerie; Majchrzak, Paulina; Jiang, Zhihao; Biswas, Deepnarayan; Dudin, Pavel; Avila, Jose; Watanabe, Kenji; Taniguchi, Takashi; Ulstrup, Soren; Boggild, Peter; Schuck, P. J.; Basov, Dmitri N.; Hone, James; Dean, Cory R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programming twist angle and strain profiles in 2D materials", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moire superlattices in twisted two-dimensional materials have generated tremendous excitement as a platform for achieving quantum properties on demand. However, the moire pattern is highly sensitive to the interlayer atomic registry, and current assembly techniques suffer from imprecise control of the average twist angle, spatial inhomogeneity in the local twist angle, and distortions caused by random strain. We manipulated the moire patterns in hetero- and homobilayers through in-plane bending of monolayer ribbons, using the tip of an atomic force microscope. This technique achieves continuous variation of twist angles with improved twist-angle homogeneity and reduced random strain, resulting in moire patterns with tunable wavelength and ultralow disorder. Our results may enable detailed studies of ultralow-disorder moire systems and the realization of precise strain-engineered devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2023, "Volume": 381, "Issue": 6658, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 677, "End Page": 681, "Article Number": null, "DOI": "10.1126/science.ade9995", "DOI Link": "http://dx.doi.org/10.1126/science.ade9995", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054584400031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schutt, KT; Kessel, P; Gastegger, M; Nicoli, KA; Tkatchenko, A; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schutt, K. T.; Kessel, P.; Gastegger, M.; Nicoli, K. A.; Tkatchenko, A.; Muller, K. -R", "Book Author Full Names": null, "Group Authors": null, "Article Title": "SchNetPack: A Deep Learning Toolbox For Atomistic Systems", "Source Title": "JOURNAL OF CHEMICAL THEORY AND COMPUTATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "SchNetPack is a toolbox for the development and application of deep neural networks that predict potential energy surfaces and other quantum-chemical properties of molecules and materials. It contains basic building blocks of atomistic neural networks, manages their training, and provides simple access to common benchmark datasets. This allows for an easy implementation and evaluation of new models. For now, SchNetPack includes implementations of (weighted) atom-centered symmetry functions and the deep tensor neural network SchNet, as well as ready-to-use scripts that allow one to train these models on molecule and material datasets. Based on the PyTorch deep learning framework, SchNetPack allows one to efficiently apply the neural networks to large datasets with millions of reference calculations, as well as parallelize the model across multiple GPUs. Finally, SchNetPack provides an interface to the Atomic Simulation Environment in order to make trained models easily accessible to researchers that are not yet familiar with neural networks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 448, "End Page": 455, "Article Number": null, "DOI": "10.1021/acs.jctc.8b00908", "DOI Link": "http://dx.doi.org/10.1021/acs.jctc.8b00908", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455558200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Ren, XM; Yin, YC; Zhao, K; Chew, A; Cheng, Y; Cunningham, E; Wang, Y; Hu, SY; Wu, Y; Chini, M; Chang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jie; Ren, Xiaoming; Yin, Yanchun; Zhao, Kun; Chew, Andrew; Cheng, Yan; Cunningham, Eric; Wang, Yang; Hu, Shuyuan; Wu, Yi; Chini, Michael; Chang, Zenghu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "53-attosecond X-ray pulses reach the carbon K-edge", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The motion of electrons in the microcosm occurs on a time scale set by the atomic unit of time-24 attoseconds. Attosecond pulses at photon energies corresponding to the fundamental absorption edges of matter, which lie in the soft X-ray regime above 200 eV, permit the probing of electronic excitation, chemical state, and atomic structure. Here we demonstrate a soft X-ray pulse duration of 53 as and single pulse streaking reaching the carbon K-absorption edge (284 eV) by utilizing intense two-cycle driving pulses near 1.8-mu m center wavelength. Such pulses permit studies of electron dynamics in live biological samples and next-generation electronic materials such as diamond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-017-00321-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00321-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406947700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raviv, D; Zhao, W; McKnelly, C; Papadopoulou, A; Kadambi, A; Shi, BX; Hirsch, S; Dikovsky, D; Zyracki, M; Olguin, C; Raskar, R; Tibbits, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raviv, Dan; Zhao, Wei; McKnelly, Carrie; Papadopoulou, Athina; Kadambi, Achuta; Shi, Boxin; Hirsch, Shai; Dikovsky, Daniel; Zyracki, Michael; Olguin, Carlos; Raskar, Ramesh; Tibbits, Skylar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Active Printed Materials for Complex Self- Evolving Deformations", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a new design of complex self-evolving structures that vary over time due to environmental interaction. In conventional 3D printing systems, materials are meant to be stable rather than active and fabricated models are designed and printed as static objects. Here, we introduce a novel approach for simulating and fabricating self-evolving structures that transform into a predetermined shape, changing property and function after fabrication. The new locally coordinated bending primitives combine into a single system, allowing for a global deformation which can stretch, fold and bend given environmental stimulus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 402, "Times Cited, All Databases": 450, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2014, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7422, "DOI": "10.1038/srep07422", "DOI Link": "http://dx.doi.org/10.1038/srep07422", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346701300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seko, A; Maekawa, T; Tsuda, K; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seko, Atsuto; Maekawa, Tomoya; Tsuda, Koji; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning with systematic density-functional theory calculations: Application to melting temperatures of single- and binary-component solids", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A combination of systematic density-functional theory (DFT) calculations and machine learning techniques has a wide range of potential applications. This study presents an application of the combination of systematic DFT calculations and regression techniques to the prediction of the melting temperature for single and binary compounds. Here we adopt the ordinary least-squares regression, partial least-squares regression, support vector regression, and Gaussian process regression. Among the four kinds of regression techniques, SVR provides the best prediction. The inclusion of physical properties computed by the DFT calculation to a set of predictor variables makes the prediction better. In addition, limitation of the predictive power is shown when extrapolation from the training dataset is required. Finally, a simulation to find the highest melting temperature toward the efficient materials design using kriging is demonstrated. The kriging design finds the compound with the highest melting temperature much faster than random designs. This result may stimulate the application of kriging to efficient materials design for a broad range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2014, "Volume": 89, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 54303, "DOI": "10.1103/PhysRevB.89.054303", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.054303", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332388700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Scarpulla, MA; McCandless, B; Phillips, AB; Yan, YF; Heben, MJ; Wolden, C; Xiong, G; Metzger, WK; Mao, D; Krasikov, D; Sankin, I; Grover, S; Munshi, A; Sampath, W; Sites, JR; Bothwell, A; Albin, D; Reese, MO; Romeo, A; Nardone, M; Klie, R; Walls, JM; Fiducia, T; Abbas, A; Hayes, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Scarpulla, Michael A.; McCandless, Brian; Phillips, Adam B.; Yan, Yanfa; Heben, Michael J.; Wolden, Colin; Xiong, Gang; Metzger, Wyatt K.; Mao, Dan; Krasikov, Dmitry; Sankin, Igor; Grover, Sachit; Munshi, Amit; Sampath, Walajabad; Sites, James R.; Bothwell, Alexandra; Albin, David; Reese, Matthew O.; Romeo, Alessandro; Nardone, Marco; Klie, Robert; Walls, J. Michael; Fiducia, Thomas; Abbas, Ali; Hayes, Sarah M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CdTe-based thin film photovoltaics: Recent advances, current challenges and future prospects", "Source Title": "SOLAR ENERGY MATERIALS AND SOLAR CELLS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cadmium telluride (CdTe)-based cells have emerged as the leading commercialized thin film photovoltaic technology and has intrinsically better temperature co-efficients, energy yield, and degradation rates than Si technologies. More than 30 GW peak (GWp) of CdTe-based modules are installed worldwide, multiple com-panies are in production, modules are shipping at up to 18.6% efficiency, and lab cell efficiency is above 22%. We review developments in the science and technology that have occurred over approximately the past decade. These achievements were enabled by manufacturing innovations and scaling module production, as well as maximizing photocurrent through window layer optimization and alloyed CdSexTe1-x (CST) absorbers. Improved chlorine passivation processes, film microstructure, and serendipitous Se defect passivation significantly increased minority carrier lifetime. Efficiencies >22% have been realized for both Cu and As doped CST-based cells. The path to further efficiency gains hinges primarily on increasing open circuit voltage (Voc) and fill factor (FF) through innovations in materials, fabrication methods, and device stacks. Replacing the longstanding Cu doping with As doping is resulting in better module stability and is being translated to large-scale production. To realize 25% efficiency and >1 V Voc, research and development is needed to increase the minority carrier lifetime beyond 100 ns, reduce grain boundary and interface recombination, and tailor band diagrams at the front and back interfaces. Many of these goals have been realized separately however combining them together using scalable manufacturing approaches has been elusive to date. We review these achievements and outstanding opportunities for this remarkable photovoltaic technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2023, "Volume": 255, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112289, "DOI": "10.1016/j.solmat.2023.112289", "DOI Link": "http://dx.doi.org/10.1016/j.solmat.2023.112289", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971407100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Q; Lin, YT; Gu, S; Cheng, ZQ; Xie, LS; Sun, SJ; Zhang, LC; Luo, YS; Alshehri, AA; Hamdy, MS; Kong, QQ; Wang, JH; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qian; Lin, Yiting; Gu, Shuang; Cheng, Ziqiang; Xie, Lisi; Sun, Shengjun; Zhang, Longcheng; Luo, Yongsong; Alshehri, Abdulmohsen Ali; Hamdy, Mohamed S.; Kong, Qingquan; Wang, Jiahong; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced N2-to-NH3 conversion efficiency on Cu3P nulloribbon electrocatalyst", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient electroreduction of nitrogen (N-2) is considered as a green and feasible approach for ammonia (NH3) synthesis, which urgently demands for efficient electrocatalyst. Morphology has close relationship with catalytic activity of heterogeneous catalysts. nulloribbon is attractive nullostructure, which possesses the flexibility of one-dimensional nullomaterials, the large surface area of two-dimensional nullomaterials, and lateral size confinement effects. In this work, Cu3P nulloribbon is proposed as a highly efficient electrocatalyst for N-2-to-NH3 conversion under benign conditions. When measured in N-2-saturated 0.1 M HCl, such Cu3P nulloribbon achieves high performance with an excellent Faradaic efficiency as high as 37.8% and a large yield of 18.9 mu g center dot h(-1)center dot mg(cat.)(-1) at -0.2 V. It also demonstrates outstanding stability in long-term electrolysis test at least for 45 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7134, "End Page": 7138, "Article Number": null, "DOI": "10.1007/s12274-022-4568-z", "DOI Link": "http://dx.doi.org/10.1007/s12274-022-4568-z", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000812630400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kruk, SS; Wang, L; Sain, B; Dong, ZG; Yang, J; Zentgraf, T; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kruk, Sergey S.; Wang, Lei; Sain, Basudeb; Dong, Zhaogang; Yang, Joel; Zentgraf, Thomas; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Asymmetric parametric generation of images with nonlinear dielectric metasurfaces", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Subwavelength dielectric resonators assembled into metasurfaces have become a versatile tool for miniaturizing optical components approaching the nulloscale(1-3). An important class of metasurface functionalities is associated with asymmetry in both the generation and transmission of light with respect to reversals of the positions of emitters and receivers(4-6). The nonlinear light-matter interaction in metasurfaces(7-9) offers a promising pathway towards miniaturization of the asymmetric control of light. Here we demonstrate asymmetric parametric generation of light in nonlinear metasurfaces. We assemble dissimilar nonlinear dielectric resonators into translucent metasurfaces that produce images in the visible spectral range on being illuminated by infrared radiation. By design, the metasurfaces produce different and completely independent images for the reversed direction of illumination, that is, when the positions of the infrared emitter and the visible light receiver are exchanged. Nonlinearity-enabled asymmetric control of light by subwavelength resonators paves the way towards novel nullophotonic components via dense integration of large quantities of nonlinear resonators into compact metasurface designs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 16, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01018-7", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01018-7", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000813788600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parto, K; Azzam, SI; Banerjee, K; Moody, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parto, Kamyar; Azzam, Shaimaa, I; Banerjee, Kaustav; Moody, Galan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect and strain engineering of monolayer WSe2 enables site-controlled single-photon emission up to 150K", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, quantum-dot-like single-photon emitters in atomically thin van der Waals materials have become a promising platform for future on-chip scalable quantum light sources with unique advantages over existing technologies, notably the potential for site-specific engineering. However, the required cryogenic temperatures for the functionality of these sources has been an inhibitor of their full potential. Existing methods to create emitters in 2D materials face fundamental challenges in extending the working temperature while maintaining the emitter's fabrication yield and purity. In this work, we demonstrate a method of creating site-controlled single-photon emitters in atomically thin WSe2 with high yield utilizing independent and simultaneous strain engineering via nulloscale stressors and defect engineering via electron-beam irradiation. Many of the emitters exhibit biexciton cascaded emission, single-photon purities above 95%, and working temperatures up to 150K. This methodology, coupled with possible plasmonic or optical micro-cavity integration, furthers the realization of scalable, room-temperature, and high-quality 2D single- and entangled-photon sources. Quantum defects in 2D semiconductors are promising quantum light sources, but the required cryogenic temperatures limit their applicability. Here, the authors report a method to create single-photon emitters in monolayer WSe2 operating at temperatures up to 150K without plasmonic or optical cavities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3585, "DOI": "10.1038/s41467-021-23709-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23709-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663757900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmed, DN; Naji, LA; Faisal, AAH; Al-Ansari, N; Naushad, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmed, Dooraid N.; Naji, Laith A.; Faisal, Ayad A. H.; Al-Ansari, Nadhir; Naushad, Mu.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Waste foundry sand/MgFe-layered double hydroxides composite material for efficient removal of Congo red dye from aqueous solution", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We aimed to obtain magnesium/iron (Mg/Fe)-layered double hydroxides (LDHs) nulloparticles-immobilized on waste foundry sand-a byproduct of the metal casting industry. XRD and FT-IR tests were applied to characterize the prepared sorbent. The results revealed that a new peak reflected LDHs nulloparticles. In addition, SEM-EDS mapping confirmed that the coating process was appropriate. Sorption tests for the interaction of this sorbent with an aqueous solution contaminated with Congo red dye revealed the efficacy of this material where the maximum adsorption capacity reached approximately 9127.08mg/g. The pseudo-first-order and pseudo-second-order kinetic models helped to describe the sorption measurements, indicating that the physical and chemical forces governed the removal process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2042, "DOI": "10.1038/s41598-020-58866-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-020-58866-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000559760300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahne, N; Renfrew, SE; McCloskey, BD; Freunberger, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahne, Nika; Renfrew, Sara E.; McCloskey, Bryan D.; Freunberger, Stefan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Oxidation of Lithium Carbonate Generates Singlet Oxygen", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid alkali metal carbonates are universal passivation layer components of intercalation battery materials and common side products in metal-O-2 batteries, and are believed to form and decompose reversibly in metal-O-2/CO2 cells. In these cathodes, Li2CO3 decomposes to CO2 when exposed to potentials above 3.8V vs. Li/Li+. However, O-2 evolution, as would be expected according to the decomposition reaction 2Li(2)CO(3)4Li(+)+4e(-)+2CO(2)+O-2, is not detected. O atoms are thus unaccounted for, which was previously ascribed to unidentified parasitic reactions. Here, we show that highly reactive singlet oxygen (O-1(2)) forms upon oxidizing Li2CO3 in an aprotic electrolyte and therefore does not evolve as O-2. These results have substantial implications for the long-term cyclability of batteries: they underpin the importance of avoiding O-1(2) in metal-O-2 batteries, question the possibility of a reversible metal-O-2/CO2 battery based on a carbonate discharge product, and help explain the interfacial reactivity of transition-metal cathodes with residual Li2CO3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 258, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2018, "Volume": 57, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5529, "End Page": 5533, "Article Number": null, "DOI": "10.1002/anie.201802277", "DOI Link": "http://dx.doi.org/10.1002/anie.201802277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431035500064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ramutshatsha-Makhwedzha, D; Mavhungu, A; Moropeng, ML; Mbaya, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ramutshatsha-Makhwedzha, Denga; Mavhungu, Avhafunulli; Moropeng, Mapula Lucey; Mbaya, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activated carbon derived from waste orange and lemon peels for the adsorption of methyl orange and methylene blue dyes from wastewater", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The study of adsorbent behaviour in laboratory conditions helps to predict the adsorption process in a large industrial scale. In this study, orange and lemon peels-derived activated carbon (OLPAC) was successfully synthesized and activated using phosphoric acid. Characterization was performed on the OLPAC and the material was used for the removal of methyl orange (MO) and methylene (MB) dyes from wastewater. The results of the scanning electron microscope and N2 adsorption/desorption examination affirmed that the prepared nullocomposite is permeable, which is an advantage for the efficient removal of contaminullts. Optimal conditions for the batch removal process were investigated using a one-factor time approach in different conditions of adsorption (Dye concentration 50-200 mg L-1, pH 2-10, adsorbent mass 0.010-0.8, and contact time 5-180 min. The adsorption isotherm equilibrium data were examined by Langmuir, Freundlich, and Temkin, isotherm model. As shown by the correlation coefficient (R2), the data were best described by Langmuir isotherms with maximum adsorption capacities of 33 and 38 mg g1 for methyl orange and methylene blue, respectively. Adsorption kinetic data were described using the pseudo-second-order model which suggests that adsorption of MO and MB was by chemisorption mechanism. The method was applicable to real wastewater samples, with satisfactory removal percentages of OM and MB (96 and 98 %). The results of this study show that OLPAC is an inexpensive biosorbent that is successfully utilized in removing methyl orange and methylene blue dyes from wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e09930", "DOI": "10.1016/j.heliyon.2022.e09930", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2022.e09930", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000843529200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lischke, S; Peczek, A; Morgan, JS; Sun, K; Steckler, D; Yamamoto, Y; Korndörfer, F; Mai, C; Marschmeyer, S; Fraschke, M; Krüger, A; Beling, A; Zimmermann, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lischke, S.; Peczek, A.; Morgan, J. S.; Sun, K.; Steckler, D.; Yamamoto, Y.; Korndoerfer, F.; Mai, C.; Marschmeyer, S.; Fraschke, M.; Krueger, A.; Beling, A.; Zimmermann, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-fast germanium photodiode with 3-dB bandwidth of 265 GHz", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By sandwiching a germanium fin between complementary in situ-doped silicon layers, a waveguide-coupled germanium photodiode with a 3-dB bandwidth of 265 GHz, accompanied by high responsivity and low dark current, is realized. On a scalable silicon technology platform, we demonstrate photodetectors matching or even surpassing state-of-the-art III-V devices. As key components in high-speed optoelectronics, photodetectors with bandwidths greater than 100 GHz have been a topic of intense research for several decades. Solely InP-based detectors could satisfy the highest performance specifications. Devices based on other materials, such as germanium-on-silicon devices, used to lag behind in speed, but enabled complex photonic integrated circuits and co-integration with silicon electronics. Here we demonstrate waveguide-coupled germanium photodiodes with optoelectrical 3-dB bandwidths of 265 GHz and 240 GHz at a photocurrent of 1 mA. This outstanding performance is achieved by a novel device concept in which a germanium fin is sandwiched between complementary in situ-doped silicon layers. Our photodetectors show internal responsivities of 0.3 A W-1 (265 GHz) and 0.45 A W-1 (240 GHz) at a wavelength of 1,550 nm. The internal bandwidth-efficiency product of the latter device is 86 GHz. Low dark currents of 100-200 nA are obtained from these ultra-fast photodetectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 15, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 925, "End Page": 931, "Article Number": null, "DOI": "10.1038/s41566-021-00893-w", "DOI Link": "http://dx.doi.org/10.1038/s41566-021-00893-w", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720282000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, QQ; Li, YY; Wan, SY; Li, HZ; Guo, W; Yang, H; Li, Q; Zhu, XY; Pan, XQ; Nie, YF; Wen, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Qiangqiang; Li, Yueying; Wan, Siyuan; Li, Huazhou; Guo, Wei; Yang, Huan; Li, Qing; Zhu, Xiyu; Pan, Xiaoqing; Nie, Yuefeng; Wen, Hai-Hu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single particle tunneling spectrum of superconducting Nd1-xSrxNiO2 thin films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pairing mechanism in cuprates remains as one of the most challenging issues in condensed matter physics. Recently, superconductivity was discovered in thin films of the infinite-layer nickelate Nd1-xSrxNiO2 (x=0.12-0.25) which is believed to have the similar 3d(9) orbital electrons as that in cuprates. Here we report single-particle tunneling measurements on the superconducting nickelate thin films. We find predominulltly two types of tunneling spectra, one shows a V-shape feature which can be fitted well by a d-wave gap function with gap maximum of about 3.9meV, another one exhibits a full gap of about 2.35meV. Some spectra demonstrate mixed contributions of these two components. Combining with theoretical calculations, we attribute the d-wave gap to the pairing potential of the Ni-3dx2-y2 orbital. Several possible reasons are given for explaining the full gap feature. Our results indicate both similarities and distinctions between the newly found Ni-based superconductors and cuprates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6027, "DOI": "10.1038/s41467-020-19908-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19908-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596476900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, MH; Lee, YH; Kim, HJ; Kim, YJ; Moon, T; Do Kim, K; Hyun, SD; Mikolajick, T; Schroeder, U; Hwang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Min Hyuk; Lee, Young Hwan; Kim, Han Joon; Kim, Yu Jin; Moon, Taehwan; Do Kim, Keum; Hyun, Seung Dam; Mikolajick, Thomas; Schroeder, Uwe; Hwang, Cheol Seong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the formation of the metastable ferroelectric phase in hafnia-zirconia solid solution thin films", "Source Title": "nullOSCALE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hf1-xZrxO2 (x similar to 0.5-0.7) has been the leading candidate of ferroelectric materials with a fluorite crystal structure showing highly promising compatibility with complementary metal oxide semiconductor devices. Despite the notable improvement in device performance and processing techniques, the origin of its ferroelectric crystalline phase (space group: Pca2(1)) formation has not been clearly elucidated. Several recent experimental and theoretical studies evidently showed that the interface and grain boundary energies of the higher symmetry phases (orthorhombic and tetragonal) contribute to the stabilization of the metastable non-centrosymmetric orthorhombic phase or tetragonal phase. However, there was a clear quantitative discrepancy between the theoretical expectation and experiment results, suggesting that the thermodynamic model may not provide the full explanation. This work, therefore, focuses on the phase transition kinetics during the cooling step after the crystallization annealing. It was found that the large activation barrier for the transition from the tetragonal/orthorhombic to the monoclinic phase, which is the stable phase at room temperature, suppresses the phase transition, and thus, plays a critical role in the emergence of ferroelectricity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2018, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 716, "End Page": 725, "Article Number": null, "DOI": "10.1039/c7nr06342c", "DOI Link": "http://dx.doi.org/10.1039/c7nr06342c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419152600024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Farhadian, A; Zhao, Y; Naeiji, P; Rahimi, A; Berisha, A; Zhang, LX; Rizi, ZT; Iravani, D; Zhao, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Farhadian, Abdolreza; Zhao, Yang; Naeiji, Parisa; Rahimi, Alireza; Berisha, Avni; Zhang, Lunxiang; Rizi, Zahra Taheri; Iravani, Danial; Zhao, Jiafei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneous inhibition of natural gas hydrate formation and CO2/H2S corrosion for flow assurance inside the oil and gas pipelines", "Source Title": "ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compatibility problems are observed during the co-injection of corrosion and gas hydrate inhibitors inside oil and gas pipelines, which reduces their performance. In this study, the newly synthesized dual-purpose inhibitors (DPIs) were developed to overcome the compatibility challenge between the inhibitors. A detailed experimental and computational study was performed to investigate the inhibition activity of DPIs. The results of constant cooling experiments showed that the inhibitors significantly prevented natural gas hydrate formation. DPI2 with a propyl pendant group was the best sample by providing a subcooling temperature of 18.1 degrees C at 5000 ppm. DPI1 and DPI3 decreased gas consumption by 2.6 and 2.4 times, respectively, compared to pure water. In addition, molecular dynamics simulation revealed that the transportation of gas molecules to the growing hydrate cages was disrupted due to DPI2 adsorption on the surface of the hydrate, which partially covered it and acted as a mass transfer barrier. Furthermore, the interaction of the anion part of the inhibitor with the nearest neighbor water molecules lowered the water activity to form the hydrogen-bonding networks for the hydrate formation. According to corrosion measurements, DPIs suppressed the corrosion rate of mild steel in H2S-CO2 saturated oilfield-produced water, and a maximum inhibition efficiency of 96.3% was obtained by adding 1000 ppm of DPI2. Moreover, the estimated adsorption energy of DPI2 were relatively high and matched with experimental data, implying that the inhibitor has a high degree of adsorption on the metal for forming a protective layer on the mild steel surface. These findings signified that DPIs provide a potential hybrid inhibition of corrosion and gas hydrate formation for flow assurance applications and reduce the operation costs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 269, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126797, "DOI": "10.1016/j.energy.2023.126797", "DOI Link": "http://dx.doi.org/10.1016/j.energy.2023.126797", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000929764000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kinsey, N; DeVault, C; Kim, J; Ferrera, M; Shalaev, VM; Boltasseva, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kinsey, N.; DeVault, C.; Kim, J.; Ferrera, M.; Shalaev, V. M.; Boltasseva, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Epsilon-near-zero Al-doped ZnO for ultrafast switching at telecom wavelengths", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transparent conducting oxides have recently gained great attention as CMOS-compatible materials for applications in nullophotonics due to their low optical loss, metal-like behavior, versatile/tailorable optical properties, and established fabrication procedures. In particular, aluminum-doped zinc oxide (AZO) is very attractive because its dielectric permittivity can be engineered over a broad range in the near-IR and IR. However, despite all these beneficial features, the slow (>100 ps) electron-hole recombination time typical of these compounds still represents a fundamental limitation impeding ultrafast optical modulation. Here we report the first epsilon-near-zero AZO thin films that simultaneously exhibit ultrafast carrier dynamics (excitation and recombination time below 1 ps) and an outstanding reflectance modulation up to 40% for very low pump fluence levels (<4 mJ/cm(2)) at a telecom wavelength of 1.3 mu m. The unique properties of the demonstrated AZO thin films are the result of a low-temperature fabrication procedure promoting deep-level defects within the film and an ultrahigh carrier concentration. (C) 2015 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2015, "Volume": 2, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 616, "End Page": 622, "Article Number": null, "DOI": "10.1364/OPTICA.2.000616", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.2.000616", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364484300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SY; Yang, C; Hsu, WY; Lin, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Sung-Yueh; Yang, Chen; Hsu, Wensyang; Lin, Liwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D-printed microelectronics for integrated circuitry and passive wireless sensors", "Source Title": "MICROSYSTEMS & nullOENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional (3D) additive manufacturing techniques have been utilized to make 3D electrical components, such as resistors, capacitors, and inductors, as well as circuits and passive wireless sensors. Using the fused deposition modeling technology and a multiple-nozzle system with a printing resolution of 30 mu m, 3D structures with both supporting and sacrificial structures are constructed. After removing the sacrificial materials, suspensions with silver particles are injected subsequently solidified to form metallic elements/interconnects. The prototype results show good characteristics of fabricated 3D microelectronics components, including an inductor-capacitor-resonullt tank circuitry with a resonullce frequency at 0.53 GHz. A 3D smart cap with an embedded inductor-capacitor tank as the wireless passive sensor was demonstrated to monitor the quality of liquid food (e.g., milk and juice) wirelessly. The result shows a 4.3% resonullce frequency shift from milk stored in the room temperature environment for 36 h. This work establishes an innovative approach to construct arbitrary 3D systems with embedded electrical structures as integrated circuitry for various applications, including the demonstrated passive wireless sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15013, "DOI": "10.1038/micronullo.2015.13", "DOI Link": "http://dx.doi.org/10.1038/micronullo.2015.13", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000218367600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, S; Zhang, YX; Qu, H; Li, M; Zhang, SL; Yang, JC; Zhang, XP; Tan, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Shuai; Zhang, Yaoxin; Qu, Hao; Li, Meng; Zhang, Songlin; Yang, Jiachen; Zhang, Xueping; Tan, Swee Ching", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Repurposing face mask waste to construct floating photothermal evaporator for autonomous solar ocean farming", "Source Title": "ECOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastic waste caused by the extensive usage of face masks during COVID-19 pandemic has become a severe threat to natural environment and ecosystem. Herein, an eco-friendly approach to repurpose face mask waste for clean water production via solar thermal evaporation is proposed. By taking advantage of its interwind structure, face mask holds the promise to be an ideal candidate material for constructing photothermal evaporator. In-situ surface modifications are performed successively with polyvinyl alcohol and polypyrrole to improve its wettability and solar absorption (97%). The obtained face mask-based evaporator achieves significantly enhanced solar efficiency (91.5%) and long-term salt-rejection stability. The harvested clean water befits plant growing to enable farming on sea surface. A floating photothermal evaporation prototype is then developed to demonstrate autonomous solar ocean farming, with plants successfully cultivated over time. As such, the proposed strategy provides a promising solution towards ecological sustainability by tapping multiple benefits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e12179", "DOI": "10.1002/eom2.12179", "DOI Link": "http://dx.doi.org/10.1002/eom2.12179", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737406900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gnilitskyi, I; Derrien, TJY; Levy, Y; Bulgakova, NM; Mocek, T; Orazi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gnilitskyi, Iaroslav; Derrien, Thibault J. -Y.; Levy, Yoann; Bulgakova, Nadezhda M.; Mocek, Tomas; Orazi, Leonardo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-speed manufacturing of highly regular femtosecond laser-induced periodic surface structures: physical origin of regularity", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly regular laser-induced periodic surface structures (HR-LIPSS) have been fabricated on surfaces of Mo, steel alloy and Ti at a record processing speed on large areas and with a record regularity in the obtained sub-wavelength structures. The physical mechanisms governing LIPSS regularity are identified and linked with the decay length (i.e. the mean free path) of the excited surface electromagnetic waves (SEWs). The dispersion of the LIPSS orientation angle well correlates with the SEWs decay length: the shorter this length, the more regular are the LIPSS. A material dependent criterion for obtaining HR-LIPSS is proposed for a large variety of metallic materials. It has been found that decreasing the spot size close to the SEW decay length is a key for covering several cm(2) of material surface by HR-LIPSS in a few seconds. Theoretical predictions suggest that reducing the laser wavelength can provide the possibility of HR-LIPSS production on principally any metal. This new achievement in the unprecedented level of control over the laser-induced periodic structure formation makes this laser-writing technology to be flexible, robust and, hence, highly competitive for advanced industrial applications based on surface nullostructuring.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8485, "DOI": "10.1038/s41598-017-08788-z", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-08788-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407677800039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YW; Wu, YH; Li, TT; Lu, MT; Chen, Y; Cui, YJ; Gao, JK; Qian, GD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yuwen; Wu, Yuhang; Li, Tongtong; Lu, Mengting; Chen, Yi; Cui, Yuanjing; Gao, Junkuo; Qian, Guodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the electronic structure of a metal-organic framework for an efficient oxygen evolution reaction by introducing minor atomically dispersed ruthenium", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The establishment of efficient oxygen evolution electrocatalysts is of great value but also challenging. Herein, a durable metal-organic framework (MOF) with minor atomically dispersed ruthenium and an optimized electronic structure is constructed as an efficient electrocatalyst. Significantly, the obtained NiRu0.08-MOF with doping Ru only needs an overpotential of 187 mV at 10 mA cm(-2) with a Tafel slop of 40 mV dec(-1) in 0.1 M KOH for the oxygen evolution reaction, and can work continuously for more than 300 h. Ultrahigh Ru mass activity is achieved, reaching 56.7 A g(Ru)(-1) at an overpotential of 200 mV, which is 36 times higher than that of commercial RuO2. X-ray adsorption spectroscopy and density function theory calculations reveal that atomically dispersed ruthenium on metal sites in MOFs is expected to optimize the electronic structure of nickel sites, thus improving the conductivity of the catalyst and optimizing the adsorption energy of intermediates, resulting in significant optimization of electrocatalytic performance. This study could provide a new avenue for the design of efficient and stable MOF electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e265", "DOI": "10.1002/cey2.265", "DOI Link": "http://dx.doi.org/10.1002/cey2.265", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860249900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, Y; Boss, JM; Moores, BA; Degen, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Y.; Boss, J. M.; Moores, B. A.; Degen, C. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-crystal diamond nullomechanical resonators with quality factors exceeding one million", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Diamond has gained a reputation as a uniquely versatile material, yet one that is intricate to grow and process. Resonating nullostructures made of single-crystal diamond are expected to possess excellent mechanical properties, including high-quality factors and low dissipation. Here we demonstrate batch fabrication and mechanical measurements of single-crystal diamond cantilevers with thickness down to 85 nm, thickness uniformity better than 20 nm and lateral dimensions up to 240 mu m. Quality factors exceeding one million are found at room temperature, surpassing those of state-of-the-art single-crystal silicon cantilevers of similar dimensions by roughly an order of magnitude. The corresponding thermal force noise for the best cantilevers is similar to 5.10(-19) NHz(-1/2) at millikelvin temperatures. Single-crystal diamond could thus directly improve existing force and mass sensors by a simple substitution of resonator material. Presented methods are easily adapted for fabrication of nulloelectro-mechanical systems, optomechanical resonators or nullophotonic devices that may lead to new applications in classical and quantum science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 280, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3638, "DOI": "10.1038/ncomms4638", "DOI Link": "http://dx.doi.org/10.1038/ncomms4638", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335220900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Rodriguez, JO; Jiao, L; Howard, S; Graham, M; Gu, GD; Hughes, TL; Morr, DK; Madhavan, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhenyu; Rodriguez, Jorge Olivares; Jiao, Lin; Howard, Sean; Graham, Martin; Gu, G. D.; Hughes, Taylor L.; Morr, Dirk K.; Madhavan, Vidya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for dispersing 1D Majorana channels in an iron-based superconductor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The possible realization of Majorana fermions as quasiparticle excitations in condensed-matter physics has created much excitement. Most studies have focused on Majorana bound states; however, propagating Majorana states with linear dispersion have also been predicted. Here, we report scanning tunneling spectroscopic measurements of crystalline domain walls (DWs) in FeSe0.45Te0.55. We located DWs across which the lattice structure shifts by half a unit cell. These DWs have a finite, flat density of states inside the superconducting gap, which is a hallmark of linearly dispersing modes in one dimension. This signature is absent in DWs in the related superconductor, FeSe, which is not in the topological phase. Our combined data are consistent with the observation of dispersing Majorana states at a p-phase shift DW in a proximitized topological material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2020, "Volume": 367, "Issue": 6473, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 104, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw8419", "DOI Link": "http://dx.doi.org/10.1126/science.aaw8419", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506686400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "As'ad, F; Avery, P; Farhat, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "As'ad, Faisal; Avery, Philip; Farhat, Charbel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mechanics-informed artificial neural network approach in data-driven constitutive modeling", "Source Title": "INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A mechanics-informed artificial neural network approach for learning constitutive laws governing complex, nonlinear, elastic materials from strain-stress data is proposed. The approach features a robust and accurate method for training a regression-based model capable of capturing highly nonlinear strain-stress mappings, while preserving some fundamental principles of solid mechanics. In this sense, it is a structure-preserving approach for constructing a data-driven model featuring both the form-agnostic advantage of purely phenomenological data-driven regressions and the physical soundness of mechanistic models. The proposed methodology enforces desirable mathematical properties on the network architecture to guarantee the satisfaction of physical constraints such as objectivity, consistency (preservation of rigid body modes), dynamic stability, and material stability, which are important for successfully exploiting the resulting model in numerical simulations. Indeed, embedding such notions in a learning approach reduces a model's sensitivity to noise and promotes its robustness to inputs outside the training domain. The merits of the proposed learning approach are highlighted using several finite element analysis examples. Its potential for ensuring the computational tractability of multi-scale applications is demonstrated with the acceleration of the nonlinear, dynamic, multi-scale, fluid-structure simulation of the supersonic inflation dynamics of a parachute system with a canopy made of a woven fabric.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2022, "Volume": 123, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2738, "End Page": 2759, "Article Number": null, "DOI": "10.1002/nme.6957", "DOI Link": "http://dx.doi.org/10.1002/nme.6957", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765500200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JJ; Willatzen, M; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jiajia; Willatzen, Morten; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theoretical modeling of triboelectric nullogenerators (TENGs)", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Triboelectric nullogenerators (TENGs), using Maxwell's displacement current as the driving force, can effectively convert mechanical energy into electricity. In this work, an extensive review of theoretical models of TENGs is presented. Based on Maxwell's equations, a formal physical model is established referred to as the quasi-electrostatic model of a TENG. Since a TENG is electrically neutral at any time owing to the low operation frequency, it is conveniently regarded as a lumped circuit element. Then, using the lumped parameter equivalent circuit theory, the conventional capacitive model and Norton's equivalent circuit model are derived. Optimal conditions for power, voltage, and total energy conversion efficiency can be calculated. The presented TENG models provide an effective theoretical foundation for understanding and predicting the performance of TENGs for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2020, "Volume": 128, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111101, "DOI": "10.1063/5.0020961", "DOI Link": "http://dx.doi.org/10.1063/5.0020961", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000574535100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, XL; Jiang, K; Wang, ZQ; Hu, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Xilin; Jiang, Kun; Wang, Ziqiang; Hu, Jiangping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral flux phase in the Kagome superconductor AV3Sb5", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We argue that the topological charge density wave phase in the quasi-2D Kagome superconductor AV(3)Sb(5) is a chiral flux phase. Considering the symmetry of the Kagome lattice, we show that the chiral flux phase has the lowest energy among those states which exhibit 2 x 2 charge orders observed experimentally. This state breaks the time-reversal symmetry and displays anomalous Hall effect. The explicit pattern of the density of state in real space is calculated. These results are supported by recent experiments and suggest that these materials are new platforms to investigate the interplay between topology, superconductivity and electron-electron correlations. (C) 2021 Published by Elsevier B.V. on behalf of Science China Press.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2021, "Volume": 66, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1384, "End Page": 1388, "Article Number": null, "DOI": "10.1016/j.scib.2021.04.043", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2021.04.043", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680282600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Finzel, J; Gutierrez, KMS; Hoffman, AS; Resasco, J; Christopher, P; Bare, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Finzel, Jordan; Gutierrez, Kenzie M. Sanroman; Hoffman, Adam S.; Resasco, Joaquin; Christopher, Phillip; Bare, Simon R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Limits of Detection for EXAFS Characterization of Heterogeneous Single-Atom Catalysts", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs), consisting of individual metal atoms dispersed on a support, attract attention due to their unique reactivity, efficient use of precious metals, and precise chemical tunability. Character-ization of the metal species is crucial to substantiate structure-function relationships. Authors often use -and referees often require -X-ray absorption spectroscopy (XAS) data to prove the absence of clustered metal (or metal oxide) structures after pre-treatment and under in situ or operando conditions. However, there has been no critical assessment of the limitations of XAS in substantiating such conclusive statements, which is particularly important given the potential outsized influence of minority catalyst structures in dictating catalytic activity. In this article, we quantitatively assess the detection limits of XAS to identify metal (or metal oxide) clusters in samples containing predominulltly single atoms by modeling the extended X-ray absorption fine structure (EXAFS) of mixtures of structures. We identified that a significant fraction of clusters can coexist with SAC active sites (e.g., similar to 10% metallic Pt or similar to 40% oxidized Pt clusters in Pt/CeO2 SACs), while eluding detection via EXAFS with any statistical significance. To generalize these conclusions, a descriptor -based screening of bulk metal oxides using a continuous Cauchy wavelet transform was proposed that suggests certain materials for which differentiating atomically dispersed metal species and metal oxide clusters would be infeasible by EXAFS (e.g., ReOx). Based on this analysis, we suggest best practices for the study of SACs using EXAFS and provide recommendations to ensure that conclusions do not outpace the evidence used to support them. In this rapidly expanding research area, rigorous characterization will lead to greater understanding of the behavior of SACs and ultimately improved catalytic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2023, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6462, "End Page": 6473, "Article Number": null, "DOI": "10.1021/acscatal.3c01116", "DOI Link": "http://dx.doi.org/10.1021/acscatal.3c01116", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000981759800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pershin, A; Hall, D; Lemaur, V; Sancho-Garcia, JC; Muccioli, L; Zysman-Colman, E; Beljonne, D; Olivier, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pershin, Anton; Hall, David; Lemaur, Vincent; Sancho-Garcia, Juan-Carlos; Muccioli, Luca; Zysman-Colman, Eli; Beljonne, David; Olivier, Yoann", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly emissive excitons with reduced exchange energy in thermally activated delayed fluorescent molecules", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unlike conventional thermally activated delayed fluorescence chromophores, boron-centered azatriangulene-like molecules combine a small excited-state singlet-triplet energy gap with high oscillator strengths and minor reorganization energies. Here, using highly correlated quantum-chemical calculations, we report this is driven by short-range reorganization of the electron density taking place upon electronic excitation of these multi-resonullt structures. Based on this finding, we design a series of pi-extended boron- and nitrogen-doped nullographenes as promising candidates for efficient thermally activated delayed fluorescence emitters with concomitantly decreased singlet-triplet energy gaps, improved oscillator strengths and core rigidity compared to previously reported structures, permitting both emission color purity and tunability across the visible spectrum.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 597, "DOI": "10.1038/s41467-019-08495-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08495-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457749000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, YJ; Zhang, LT; Qiao, JC; Wang, YJ; Yang, Y; Wada, T; Kato, H; Pelletier, JM; Pineda, E; Crespo, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Y. J.; Zhang, L. T.; Qiao, J. C.; Wang, Yun-Jiang; Yang, Y.; Wada, T.; Kato, H.; Pelletier, J. M.; Pineda, E.; Crespo, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Correlation between the Fraction of Liquidlike Zones and the β Relaxation in High-Entropy Metallic Glasses", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lacking the structural information of crystalline solids, the origin of the relaxation dynamics of metallic glasses is unclear. Here, we report the evolution of stress relaxation of high-entropy metallic glasses with distinct beta relaxation behavior. The fraction of liquidlike zones, determined at each temperature by the intensity of stress decay, is shown to be directly related to both the aging process and the spectrum of relaxation modes obtained by mechanical spectroscopy. The results shed light on the intrinsic correlation between the static and dynamic mechanical response in high-entropy and conventional metallic glasses, pointing toward a sluggish diffusion high-entropy effect in the liquid dynamics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2022, "Volume": 129, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 175501, "DOI": "10.1103/PhysRevLett.129.175501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.129.175501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000876995900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arakha, M; Pal, S; Samantarrai, D; Panigrahi, TK; Mallick, BC; Pramanik, K; Mallick, B; Jha, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arakha, Manoranjan; Pal, Sweta; Samantarrai, Devyani; Panigrahi, Tapan K.; Mallick, Bairagi C.; Pramanik, Krishna; Mallick, Bibekanulld; Jha, Suman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antimicrobial activity of iron oxide nulloparticle upon modulation of nulloparticle-bacteria interface", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Investigating the interaction patterns at nullo-bio interface is a key challenge for safe use of nulloparticles (NPs) to any biological system. The study intends to explore the role of interaction pattern at the iron oxide nulloparticle (IONP)-bacteria interface affecting antimicrobial propensity of IONP. To this end, IONP with magnetite like atomic arrangement and negative surface potential (n-IONP) was synthesized by co-precipitation method. Positively charged chitosan molecule coating was used to reverse the surface potential of n-IONP, i.e. positive surface potential IONP (p-IONP). The comparative data from fourier transform infrared spectroscope, XRD, and zeta potential analyzer indicated the successful coating of IONP surface with chitosan molecule. Additionally, the nullocrystals obtained were found to have spherical size with 10-20 nm diameter. The BacLight fluorescence assay, bacterial growth kinetic and colony forming unit studies indicated that n-IONP (< 50 mu M) has insignificant antimicrobial activity against Bacillus subtilis and Escherichia coli. However, coating with chitosan molecule resulted significant increase in antimicrobial propensity of IONP. Additionally, the assay to study reactive oxygen species (ROS) indicated relatively higher ROS production upon p-IONP treatment of the bacteria. The data, altogether, indicated that the chitosan coating of IONP result in interface that enhances ROS production, hence the antimicrobial activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 495, "Times Cited, All Databases": 527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14813, "DOI": "10.1038/srep14813", "DOI Link": "http://dx.doi.org/10.1038/srep14813", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362278000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takane, D; Wang, ZW; Souma, S; Nakayama, K; Nakamura, T; Oinuma, H; Nakata, Y; Iwasawa, H; Cacho, C; Kim, T; Horiba, K; Kumigashira, H; Takahashi, T; Ando, Y; Sato, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takane, Daichi; Wang, Zhiwei; Souma, Seigo; Nakayama, Kosuke; Nakamura, Takechika; Oinuma, Hikaru; Nakata, Yuki; Iwasawa, Hideaki; Cacho, Cephise; Kim, Timur; Horiba, Koji; Kumigashira, Hiroshi; Takahashi, Takashi; Ando, Yoichi; Sato, Takafumi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of Chiral Fermions with a Large Topological Charge and Associated Fermi-Arc Surface States in CoSi", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological semimetals materialize a new state of quantum matter where massless fermions protected by a specific crystal symmetry host exotic quantum phenomena. Distinct from well-known Dirac and Weyl fermions, structurally chiral topological semimetals are predicted to host new types of massless fermions characterized by a large topological charge, whereas such exotic fermions are yet to be experimentally established. Here, by using angle-resolved photoemission spectroscopy, we experimentally demonstrate that a transition-metal silicide CoSi hosts two types of chiral topological fermions, a spin-1 chiral fermion and a double Weyl fermion, in the center and corner of the bulk Brillouin zone, respectively. Intriguingly, we found that the bulk Fermi surfaces are purely composed of the energy bands related to these fermions. We also find the surface states connecting the Fermi surfaces associated with these fermions, suggesting the existence of the predicted Fermi-arc surface states. Our result provides the first experimental evidence for the chiral topological fermions beyond Dirac and Weyl fermions in condensed-matter systems, and paves the pathway toward realizing exotic electronic properties associated with unconventional chiral fermions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 122, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76402, "DOI": "10.1103/PhysRevLett.122.076402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.076402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459215000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ou, YQ; Twight, LP; Samanta, B; Liu, L; Biswas, S; Fehrs, JL; Sagui, NA; Villalobos, J; Morales-Santelices, J; Antipin, D; Risch, M; Toroker, MC; Boettcher, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ou, Yingqing; Twight, Liam P.; Samanta, Bipasa; Liu, Lu; Biswas, Santu; Fehrs, Jessica L.; Sagui, Nicole A.; Villalobos, Javier; Morales-Santelices, Joaquin; Antipin, Denis; Risch, Marcel; Toroker, Maytal Caspary; Boettcher, Shannon W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cooperative Fe sites on transition metal (oxy)hydroxides drive high oxygen evolution activity in base", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fe-containing transition-metal (oxy)hydroxides are highly active oxygen-evolution reaction (OER) electrocatalysts in alkaline media and ubiquitously form across many materials systems. The complexity and dynamics of the Fe sites within the (oxy)hydroxide have slowed understanding of how and where the Fe-based active sites form-information critical for designing catalysts and electrolytes with higher activity and stability. We show that where/how Fe species in the electrolyte incorporate into host Ni or Co (oxy)hydroxides depends on the electrochemical history and structural properties of the host material. Substantially less Fe is incorporated from Fe-spiked electrolyte into Ni (oxy)hydroxide at anodic potentials, past the nominally Ni2+/3+ redox wave, compared to during potential cycling. The Fe adsorbed under constant anodic potentials leads to impressively high per-Fe OER turn-over frequency (TOFFe) of ~40 s(-1) at 350 mV overpotential which we attribute to under-coordinated surface Fe. By systematically controlling the concentration of surface Fe, we find TOFFe increases linearly with the Fe concentration. This suggests a changing OER mechanism with increased Fe concentration, consistent with a mechanism involving cooperative Fe sites in FeOx clusters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7688, "DOI": "10.1038/s41467-023-43305-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-43305-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001109312400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Liu, DY; Liu, LM; Li, XY; Wu, H; Sun, ZJ; Li, MT; Vasenko, AS; Ding, SJ; Wang, FM; Xiao, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ke; Liu, Dongyu; Liu, Limin; Li, Xinyang; Wu, Hu; Sun, Zongjie; Li, Mingtao; Vasenko, Andrey S.; Ding, Shujiang; Wang, Fengmei; Xiao, Chunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated Metalloid Tellurium Atomic Cluster on Nitrogen-Doped Carbon nullosheet for High-Capacity Rechargeable Lithium-CO2 Battery", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable Li-CO2 battery represents a sustainable technology by virtue of CO2 recyclability and energy storage capability. Unfortunately, the sluggish mass transport and electron transfer in bulky high-crystalline discharge product of Li2CO3, severely hinder its practical capacity and rechargeability. Herein, a heterostructure of isolated metalloid Te atomic cluster anchored on N-doped carbon nullosheets is designed (Te-AC@NCNS) as a metal-free cathode for Li-CO2 battery. X-ray absorption spectroscopy analysis demonstrates that the abundant and dispersed Te active centers can be stabilized by C atoms in form of the covalent bond. The fabricated battery shows an unprecedented full-discharge capacity of 28.35 mAh cm(-2) at 0.05 mA cm(-2) and long-term cycle life of up to 1000 h even at a high cut-off capacity of 1 mAh cm(-2). A series of ex situ characterizations combined with theoretical calculations demonstrate that the abundant Te atomic clusters acting as active centers can drive the electron redistribution of carbonate via forming Te-O bonds, giving rise to poor-crystalline Li2CO3 film during the discharge process. Moreover, the efficient electron transfer between the Te centers and intermediate species is energetically beneficial for nucleation and accelerates the decomposition of Li2CO3 on the Te-AC@NCNS during the discharge/charge process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 10, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202205959", "DOI Link": "http://dx.doi.org/10.1002/advs.202205959", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913108800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, J; Yu, FL; Liu, XS; Bao, YJ; Chen, RS; Zhao, ZY; Wang, JX; Wang, XX; Liu, W; Shi, YZ; Qiu, CW; Chen, XS; Lu, W; Li, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jin; Yu, Feilong; Liu, Xingsi; Bao, Yanjun; Chen, Rongsheng; Zhao, Zengyue; Wang, Jiuxu; Wang, Xiuxia; Liu, Wen; Shi, Yuzhi; Qiu, Cheng-Wei; Chen, Xiaoshuang; Lu, Wei; Li, Guanhai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polychromatic full-polarization control in mid-infrared light", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objects with different shapes, materials and temperatures can emit distinct polarizations and spectral information in mid-infrared band, which provides a unique signature in the transparent window for object identification. However, the crosstalk among various polarization and wavelength channels prevents from accurate mid-infrared detections at high signal-to-noise ratio. Here, we report full-polarization metasurfaces to break the inherent eigen-polarization constraint over the wavelengths in mid-infrared. This recipe enables to select arbitrary orthogonal polarization basis at individual wavelength independently, therefore alleviating the crosstalk and efficiency degradation. A six-channel all-silicon metasurface is specifically presented to project focused mid-infrared light to distinct positions at three wavelengths, each with a pair of arbitrarily chosen orthogonal polarizations. An isolation ratio of 117 between neighboring polarization channels is experimentally recorded, exhibiting detection sensitivity one order of magnitude higher than existing infrared detectors. Remarkably, the high aspect ratio similar to 30 of our meta-structures manufactured by deep silicon etching technology at temperature -150 degrees C guarantees the large and precise phase dispersion control over a broadband from 3 to 4.5 mu m. We believe our results would benefit the noise-immune mid-infrared detections in remote sensing and space-to-ground communications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105, "DOI": "10.1038/s41377-023-01140-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01140-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982190500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LM; Larsson, A; Moldin, A; Edlund, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Liming; Larsson, Anette; Moldin, Annelie; Edlund, Ulrica", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparison of lignin distribution, structure, and morphology in wheat straw and wood", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Agricultural fiber sources, such as wheat straw, are promising lignocellulosic feedstocks for the generation of renewable substitutes for synthetic materials (e.g., plastics, construction materials, biofuel, and other biorefinery products). The interest in the utilization of lignin has increased rapidly during the last years; the number of publications increased more than five times between 2000 and 2020. The number of publications concerning lignin from wheat straw follows the general trend with an increasing scientific interest in lignin but comprises less than 5% of the total lignin publications. The structure and morphology of lignin in straw and wood differ between the different species. The monolignol composition and spatial location in plant tissue are notably different, as well as the nature and abundance of lignin-carbohydrate linkages involving p-coumaric acid (pCA) and ferulic acid (FA) units in wheat straw lignin. To further enable the utilization of wheat straw as a resource for bio-based materials, a solid understanding of the wheat lignin structure and composition is required. This review aims to consolidate the state-of-the-art in wheat lignin and focuses on lignin and its distribution, fundamental chemical structures, and morphology in wheat straw and compares these features with lignin in wood cell walls.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2022, "Volume": 187, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115432, "DOI": "10.1016/j.indcrop.2022.115432", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2022.115432", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000877803800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MH; Ding, H; Egert, S; Zhao, CH; Villa, L; Fulanovic, L; Groszewicz, PB; Buntkowsky, G; Kleebe, HJ; Albe, K; Klein, A; Koruza, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Mao-Hua; Ding, Hui; Egert, Sonja; Zhao, Changhao; Villa, Lorenzo; Fulanovic, Lovro; Groszewicz, Pedro B.; Buntkowsky, Gerd; Kleebe, Hans-Joachim; Albe, Karsten; Klein, Andreas; Koruza, Jurij", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring high-energy storage nullbO3-based materials from antiferroelectric to relaxor states", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferroelectrics are important in emerging energy-storage technologies. Here, the authors present an approach to adjust their local structure and defect chemistry, in order to overcome the current limitations and make them suitable for environmentally-friendly dielectric energy storage. Reversible field-induced phase transitions define antiferroelectric perovskite oxides and lay the foundation for high-energy storage density materials, required for future green technologies. However, promising new antiferroelectrics are hampered by transition ' s irreversibility and low electrical resistivity. Here, we demonstrate an approach to overcome these problems by adjusting the local structure and defect chemistry, delivering nullbO3-based antiferroelectrics with well-defined double polarization loops. The attending reversible phase transition and structural changes at different length scales are probed by in situ high-energy X-ray diffraction, total scattering, transmission electron microcopy, and nuclear magnetic resonullce spectroscopy. We show that the energy-storage density of the antiferroelectric compositions can be increased by an order of magnitude, while increasing the chemical disorder transforms the material to a relaxor state with a high energy efficiency of 90%. The results provide guidelines for efficient design of (anti-)ferroelectrics and open the way for the development of new material systems for a sustainable future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1525, "DOI": "10.1038/s41467-023-37060-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37060-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000957141600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, B; Drissi, S; Liu, JH; Hu, X; Song, BX; Shi, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Bao; Drissi, Sarra; Liu, Jianhui; Hu, Xiang; Song, Baixin; Shi, Caijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of temperature on CO2 curing, compressive strength and microstructure of cement paste", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigated the effect of temperature (5 degrees C-50 degrees C) on the carbonation process, compressive strength and microstructure of CO2-cured cement paste. Results showed that the carbonation process and rate were significantly affected by temperature and time. When the curing temperature increased, the rate of improvement of cement paste's properties was accelerated. The carbonation reaction was mainly kinetically controlled by product layer diffusion with an activation energy of about 10.8 kJ/mol. Temperature had greatly affected the structural transformation, morphological changes, size and amounts of calcium carbonate polymorphs (calcite, aragonite and vaterite) as well as their degree of crystallinity and decomposition temperature. Alongside calcite, vaterite and aragonite were formed at low and high curing temperatures, respectively. Apart from microstructure, the compressive strength was also found to be very sensitive to temperature and carbonation products. The relationship between the amount of different carbonate polymorphs and the compressive strength was also provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106827, "DOI": "10.1016/j.cemconres.2022.106827", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2022.106827", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000861299800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheon, JY; Kim, SJ; Rhee, YH; Kwon, OH; Park, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheon, Ja Young; Kim, Su Jun; Rhee, Young Ha; Kwon, Oh Hyeong; Park, Won Ho", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape-dependent antimicrobial activities of silver nulloparticles", "Source Title": "INTERNATIONAL JOURNAL OF nullOMEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Purpose: An important application of silver nulloparticles (Ag NPs) is their use as an antimicrobial and wound dressing material. The aim of this study is to investigate the morphological dependence on the antimicrobial activity and cellular response of Ag NPs. Materials and methods: Ag NPs of various shapes were synthesized in an aqueous solution using a simple method. The morphology of the synthesized Ag NPs was observed via TEM imaging. The antimicrobial activity of the Ag NPs with different morphologies was evaluated against various microorganisms (Escherichia coli [E. coli], Staphylococcus aureus [S. aureus], Pseudomonas aeruginosa [P. aeruginosa]). The antimicrobial activity of the Ag NPs was also examined according to the concentration in terms of the growth rate of E. coli. Results: The TEM images indicated that the Ag NPs with different morphologies (sphere, disk and triangular plate) had been successfully synthesized. The antimicrobial activity obtained from the inhibition zone was in the order of spherical Ag NPs > disk Ag NPs > triangular plate Ag NPs. In contrast, fibroblast cells grew well in all types of Ag NPs when the cell viability was evaluated via an MTT assay. An inductively coupled plasma mass assay showed that the difference in the antimicrobial activities of the Ag NPs was closely associated with the difference in the release rate of the Ag ions due to the difference in the surface area of the Ag NPs. Conclusion: The morphological dependence of the antimicrobial activity of the Ag NPs can be explained by the difference in the Ag ion release depending on the shape. Therefore, it will be possible to control the antimicrobial activity by controlling the shape and size of the Ag NPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": 14, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2773, "End Page": 2780, "Article Number": null, "DOI": "10.2147/IJN.S196472", "DOI Link": "http://dx.doi.org/10.2147/IJN.S196472", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465568500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QP; Ma, RJ; Bi, ZZ; Liao, XF; Wu, BH; Zhang, S; Su, WY; Fang, J; Zhao, C; Yan, CQ; Chen, K; Li, YX; Gao, C; Li, G; Ma, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Qunping; Ma, Ruijie; Bi, Zhaozhao; Liao, Xunfan; Wu, Baohua; Zhang, Sen; Su, Wenyan; Fang, Jin; Zhao, Chao; Yan, Cenqi; Chen, Kai; Li, Yuxiang; Gao, Chao; Li, Gang; Ma, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "19.28% Efficiency and Stable Polymer Solar Cells Enabled by Introducing an NIR-Absorbing Guest Acceptor", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, a near-infrared (NIR)-absorbing small-molecule acceptor (SMA) Y-SeNF with strong intermolecular interaction and crystallinity is developed by combining selenophene-fused core with naphthalene-containing end-group, and then as a custom-tailor guest acceptor is incorporated into the binary PM6:L8-BO host system. Y-SeNF shows a 65 nm red-shifted absorption compared to L8-BO. Thanks to the strong crystallinity and intermolecular interaction of Y-SeNF, the morphology of PM6:L8-BO:Y-SeNF can be precisely regulated by introducing Y-SeNF, achieving improved charge-transporting and suppressed non-radiative energy loss. Consequently, ternary polymer solar cells (PSCs) offer an impressive device efficiency of 19.28% with both high photovoltage (0.873 V) and photocurrent (27.88 mA cm(-2)), which is one of the highest efficiencies in reported single-junction PSCs. Notably, ternary PSC has excellent stability under maximum-power-point tracking for even over 200 h, which is better than its parental binary devices. The study provides a novel strategy to construct NIR-absorbing SMA for efficient and stable PSCs toward practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 33, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202211385", "DOI Link": "http://dx.doi.org/10.1002/adfm.202211385", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000908269500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Masubuchi, S; Morimoto, M; Morikawa, S; Onodera, M; Asakawa, Y; Watanabe, K; Taniguchi, T; Machida, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Masubuchi, Satoru; Morimoto, Masataka; Morikawa, Sei; Onodera, Momoko; Asakawa, Yuta; Watanabe, Kenji; Taniguchi, Takashi; Machida, Tomoki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Autonomous robotic searching and assembly of two-dimensional crystals to build van der Waals superlattices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals heterostructures are comprised of stacked atomically thin two-dimensional crystals and serve as novel materials providing unprecedented properties. However, the random natures in positions and shapes of exfoliated two-dimensional crystals have required the repetitive manual tasks of optical microscopy-based searching and mechanical transferring, thereby severely limiting the complexity of heterostructures. To solve the problem, here we develop a robotic system that searches exfoliated two-dimensional crystals and assembles them into superlattices inside the glovebox. The system can autonomously detect 400 monolayer graphene flakes per hour with a small error rate (< 7%) and stack four cycles of the designated two-dimensional crystals per hour with few minutes of human intervention for each stack cycle. The system enabled fabrication of the superlattice consisting of 29 alternating layers of the graphene and the hexagonal boron nitride. This capacity provides a scalable approach for prototyping a variety of van der Waals superlattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1413, "DOI": "10.1038/s41467-018-03723-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03723-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429794300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, JJ; Lee, JW; Dai, ZH; Wang, R; Nuryyeva, S; Liao, ME; Chang, SY; Meng, L; Meng, D; Sun, PY; Lin, O; Goorsky, MS; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Jingjing; Lee, Jin-Wook; Dai, Zhenghong; Wang, Rui; Nuryyeva, Selbi; Liao, Michael E.; Chang, Sheng-Yung; Meng, Lei; Meng, Dong; Sun, Pengyu; Lin, Oliver; Goorsky, Mark S.; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Ligand Management for Stable FAPbI3 Perovskite Quantum Dot Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In contrast to conventional colloidal quantum dots (CQDs), management of insulating ligands on perovskite CQDs is challenging because their ionic bonds are highly vulnerable to polar solvents. Consequently, there have been only a few examples of perovskite CQD solar cells incorporating relatively robust inorganic perovskite of which optoelectronic properties are not ideal for photovoltaic devices. Here, we report efficient and stable CQD solar cells based on formamidinium lead triiodide (FAPbI(3)) CQDs realized by rational surface regulation. Tailoring polarity of antisolvents for the post-synthetic process enabled effective removal of the insulating ligands on FAPbI(3) CQDs while preserving perovskite cores. Owing to the enhanced inter-dot electrical coupling, a power-conversion efficiency of 8.38% was demonstrated. Furthermore, the FAPbI(3) CQDs-based devices showed superior stability over those of bulk FAPbI(3) devices. Thermodynamic and crystallographic analyses revealed that enhanced contribution of the surface energy and lattice contraction contribute to their superior stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 219, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 19", "Publication Year": 2018, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1866, "End Page": 1878, "Article Number": null, "DOI": "10.1016/j.joule.2018.07.018", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.07.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445021000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thompson, AP; Swiler, LP; Trott, CR; Foiles, SM; Tucker, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thompson, A. P.; Swiler, L. P.; Trott, C. R.; Foiles, S. M.; Tucker, G. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spectral neighbor analysis method for automated generation of quantum-accurate interatomic potentials", "Source Title": "JOURNAL OF COMPUTATIONAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a new interatomic potential for solids and liquids called Spectral Neighbor Analysis Potential (SNAP). The SNAP potential has a very general form and uses machine-learning techniques to reproduce the energies, forces, and stress tensors of a large set of small configurations of atoms, which are obtained using high-accuracy quantum electronic structure (QM) calculations. The local environment of each atom is characterized by a set of bispectrum components of the local neighbor density projected onto a basis of hyperspherical harmonics in four dimensions. The bispectrum components are the same bond-orientational order parameters employed by the GAP potential[1]. The SNAP potential, unlike GAP, assumes a linear relationship between atom energy and bispectrum components. The linear SNAP coefficients are determined using weighted least-squares linear regression against the full QM training set. This allows the SNAP potential to be fit in a robust, automated manner to large QM data sets using many bispectrum components. The calculation of the bispectrum components and the SNAP potential are implemented in the LAMMPS parallel molecular dynamics code. We demonstrate that a previously unnoticed symmetry property can be exploited to reduce the computational cost of the force calculations by more than one order of magnitude. We present results for a SNAP potential for tantalum, showing that it accurately reproduces a range of commonly calculated properties of both the crystalline solid and the liquid phases. In addition, unlike simpler existing potentials, SNAP correctly predicts the energy barrier for screw dislocation migration in BCC tantalum. (C) 2014 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 740, "Times Cited, All Databases": 826, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2015, "Volume": 285, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 316, "End Page": 330, "Article Number": null, "DOI": "10.1016/j.jcp.2014.12.018", "DOI Link": "http://dx.doi.org/10.1016/j.jcp.2014.12.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349599500019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nomura, Y; Hirayama, M; Tadano, T; Yoshimoto, Y; Nakamura, K; Arita, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nomura, Yusuke; Hirayama, Motoaki; Tadano, Terumasa; Yoshimoto, Yoshihide; Nakamura, Kazuma; Arita, Ryotaro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of a two-dimensional single-component correlated electron system and band engineering in the nickelate superconductor NdNiO2", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recent experimental discovery of superconductivity in the infinite-layer nickelate Nd0.8Sr0.2NiO2 [Li et al., Nature (London) 572, 624 (2019)], we study how the correlated Ni 3d(x2-y2) electrons in the NiO2 layer interact with the electrons in the Nd layer. We show that three orbitals are necessary to represent the electronic structure around the Fermi level: Ni 3d(x2-y2) Nd 5d(3z2-r2), and a bonding orbital made from an interstitial s orbital in the Nd layer and the Nd 5d(xy) orbital. By constructing a three-orbital model for these states, we find that the hybridization between the Ni 3d(x2- y2) state and the states in the Nd layer is tiny. We also find that the metallic screening by the Nd layer is not so effective in that it reduces the Hubbard U between the Ni 3d(x2- y2) electrons just by 10%-20%. On the other hand, the electron-phonon coupling is not strong enough to mediate superconductivity of T-c similar to 10 K. These results indicate that NdNiO2 hosts an almost isolated correlated 3d(x2- y2) orbital system. We further study the possibility of realizing a more ideal single-orbital system in the Mott-Hubbard regime. We find that the Fermi pockets formed by the Nd-layer states dramatically shrink when the hybridization between the interstitial s state and Nd 5d(xy) state becomes small. By an extensive materials search, we find that the Fermi pockets almost disappear in nulld2NiO4 and NaCa2NiO3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 100, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205138, "DOI": "10.1103/PhysRevB.100.205138", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.100.205138", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498861700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, XD; Liu, Q; Miao, BF; Yu, R; Feng, Z; Sun, L; You, B; Du, J; Chen, K; Zhang, SF; Zhang, L; Yuan, Z; Wu, D; Ding, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Xinde; Liu, Qi; Miao, Bingfeng; Yu, Rui; Feng, Zheng; Sun, Liang; You, Biao; Du, Jun; Chen, Kai; Zhang, Shufeng; Zhang, Luo; Yuan, Zhe; Wu, Di; Ding, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-consistent determination of spin Hall angle and spin diffusion length in Pt and Pd: The role of the interface spin loss", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin Hall angle (theta(SH)) and spin diffusion length (lambda(sd)) are the key parameters in describing the spin-charge conversion, which is an integral part of spintronics. Despite their importance and much effort devoted to quantifying them, significant inconsistencies in the reported values for the same given material exist. We report a self-consistent method to quantify both theta(SH) and lambda(sd) of nonmagnetic materials by spin pumping with various ferromagnetic (FM) pumping sources. We characterize the spin-charge conversion for Pt and Pd with various FM combinations using (i) effective spin-mixing conductance, (ii) microwave photoresistance, and (iii) inverse spin Hall effect measurements and find that the pumped spin current suffers an interfacial spin loss (ISL), whose magnitude varies for different interfaces. By properly treating the ISL effect, we obtained consistent values of theta(SH) and lambda(sd) for both Pt and Pd regardless of the ferromagnet used.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat1670", "DOI": "10.1126/sciadv.aat1670", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat1670", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Calvo, G; Valero, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Calvo, Guiomar; Valero, Alicia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategic mineral resources: Availability and future estimations for the renewable energy sector", "Source Title": "ENVIRONMENTAL DEVELOPMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To keep the increase in global average temperature below 2 C the use of renewable energy sources is essential. There are various scenarios for this energy transition depending on the amounts and types of renewable energies implemented. However, the material requirements to build new renewable power systems is rarely considered. It is key to understand the impact that the increasing demand of materials for renewable technologies could have on mining and mineral availability and so avoid potential disruptions. Thirteen strategic elements for the renewable energy sector have been analyzed which could generate supply shortages in the medium to long term. From the supply side, production, current resources and data related to future production have been compiled. From the demand side, element use in solar power (PV and CSP), wind energy (on and off-shore), and electric vehicles have been analyzed, as well as the demand of each element in other sectors from 2018 to 2050. Of the 13 elements included in this study, cobalt, lithium, tellurium, and nickel are the most critical of all. Technologies should be more effective in their use. Governments and companies should incorporate policies related to the conservation and extension of its life through recycling and servitisation to avoid resource depletion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 122, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 41, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100640, "DOI": "10.1016/j.envdev.2021.100640", "DOI Link": "http://dx.doi.org/10.1016/j.envdev.2021.100640", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771013100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, X; Zhao, ZL; Liang, JS; Li, SZ; Lu, G; Priest, C; Wang, TY; Han, JT; Wu, G; Wang, XM; Huang, YH; Li, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xuan; Zhao, Zhonglong; Liang, Jiashun; Li, Shenzhou; Lu, Gang; Priest, Cameron; Wang, Tanyuan; Han, Jiantao; Wu, Gang; Wang, Xiaoming; Huang, Yunhui; Li, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inducing Covalent Atomic Interaction in Intermetallic Pt Alloy nullocatalysts for High-Performance Fuel Cells", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The harsh working environments of proton exchange membrane fuel cells (PEMFCs) pose huge challenges to the stability of Pt-based alloy catalysts. The widespread presence of metallic bonds with significantly delocalized electron distribution often lead to component segregation and rapid performance decay. Here we report L1(0)-Pt2CuGa intermetallic nulloparticles with a unique covalent atomic interaction between Pt-Ga as high-performance PEMFC cathode catalysts. The L1(0)-Pt2CuGa/C catalyst shows superb oxygen reduction reaction (ORR) activity and stability in fuel cell cathode (mass activity=0.57 A mg(Pt)(-1) at 0.9 V, peak power density=2.60/1.24 W cm(-2) in H-2-O-2/air, 28 mV voltage loss at 0.8 A cm(-2) after 30 000 cycles). Theoretical calculations reveal the optimized adsorption of oxygen intermediates via the formed biaxial strain on L1(0)-Pt2CuGa surface, and the durability enhancement stems from the stronger Pt-M bonds than those in L1(1)-PtCu resulted from Pt-Ga covalent interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2023, "Volume": 62, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202302134", "DOI Link": "http://dx.doi.org/10.1002/anie.202302134", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000977939800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, D; Jiang, J; Shin, JH; Wang, WB; Wang, F; Zhao, YF; Liu, CX; Wu, WD; Chan, MHW; Samarth, N; Chang, CZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Di; Jiang, Jue; Shin, Jae-Ho; Wang, Wenbo; Wang, Fei; Zhao, Yi-Fan; Liu, Chaoxing; Wu, Weida; Chan, Moses H. W.; Samarth, Nitin; Chang, Cui-Zu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of the Axion Insulator State in Quantum Anomalous Hall Sandwich Heterostructures", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The magnetoelectric effect arises from the coupling between magnetic and electric properties in materials. The Z(2) invariant of topological insulators (TIs) leads to a quantized version of this phenomenon, known as the topological magnetoelectric (TME) effect. This effect can be realized in a new topological phase called an axion insulator whose surface states are all gapped but the interior still obeys time reversal symmetry. We demonstrate such a phase using electrical transport measurements in a quantum anomalous Hall (QAH) sandwich heterostructure, in which two compositionally different magnetic TI layers are separated by an undoped TI layer. Magnetic force microscopy images of the same sample reveal sequential magnetization reversals of the top and bottom layers at different coercive fields, a consequence of the weak interlayer exchange coupling due to the spacer. When the magnetization is antiparallel, both the Hall resistance and Hall conductance show zero plateaus, accompanied by a large longitudinal resistance and vanishing longitudinal conductance, indicating the realization of an axion insulator state. Our findings thus show evidence for a phase of matter distinct from the established QAH state and provide a promising platform for the realization of the TME effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2018, "Volume": 120, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 56801, "DOI": "10.1103/PhysRevLett.120.056801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.056801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423657500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Wang, JF; Li, XJ; Zhang, JY; Zhao, CR; Hu, X; Lin, HJ; Zhao, LH; Wu, Y; He, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Lu; Wang, Junfeng; Li, Xiaojing; Zhang, Jiayu; Zhao, Chunran; Hu, Xin; Lin, Hongjun; Zhao, Leihong; Wu, Ying; He, Yiming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile preparation of Ag2S/KTa0.5Nb0.5O3 heterojunction for enhanced performance in catalytic nitrogen fixation via photocatalysis and piezo-photocatalysis", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a novel heterojunction composite Ag2S/KTaxNb1-xO3 was designed and synthesized through a combination of hydrothermal and precipitation procedures. The Ta/Nb ratio of the KTaxNb1-xO3 and the Ag2S content were optimized. The best 0.5% Ag2S/KTa0.5Nb0.5O3 (KTN) sample presents an enhanced photocatalytic performance in ammonia synthesis than KTN and Ag2S. Under simulated sunlight, the NH3 generation rate of 0.5% Ag2S/KTN reaches 2.0 times that of pure KTN. Under visible light, the reaction rate ratio of the two catalysts is 6.0. XRD, XPS, and TEM analysis revealed that Ag2S was intimately decorated on the KTN nullocubes surface, which promoted the electron transfer between the two semiconductors. The band structure investigation indicated that the Ag2S/KTN heterojunction established a type-II band alignment with intimate contact, thus realizing the effective transfer and separation of photogenerated carriers. The change in charge separation was considered as the main reason for the enhanced photocatalytic performance. Interestingly, the Ag2S/KTN composite exhibited higher NH3 generation performance under the combined action of ultrasonic vibration and simulated sunlight. The enhanced piezo-photocatalytic perfor-mance can be ascribed that the piezoelectric effect of KTN improved the bulk separation of charge carriers in KTN. This study not only provides a potential catalyst for photocatalytic nitrogen fixation but also shows new ideas for the design of highly efficient catalysts via semiconductor modification and external field coupling.(c) 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communi-cations Co., Ltd.This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1630, "End Page": 1643, "Article Number": null, "DOI": "10.1016/j.gee.2022.03.007", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2022.03.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001089715900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sternbach, AJ; Moore, SL; Rikhter, A; Zhang, S; Jing, R; Shao, Y; Kim, BSY; Xu, S; Liu, S; Edgar, JH; Rubio, A; Dean, C; Hone, J; Fogler, MM; Basov, DN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sternbach, A. J.; Moore, S. L.; Rikhter, A.; Zhang, S.; Jing, R.; Shao, Y.; Kim, B. S. Y.; Xu, S.; Liu, S.; Edgar, J. H.; Rubio, A.; Dean, C.; Hone, J.; Fogler, M. M.; Basov, D. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Negative refraction in hyperbolic hetero-bicrystals", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We visualized negative refraction of phonon polaritons, which occurs at the interface between two natural crystals. The polaritons-hybrids of infrared photons and lattice vibrations-form collimated rays that display negative refraction when passing through a planar interface between the two hyperbolic van der Waals materials: molybdenum oxide (MoO3) and isotopically pure hexagonal boron nitride (h11BN). At a special frequency co0, these rays can circulate along closed diamond-shaped trajectories. We have shown that polariton eigenmodes display regions of both positive and negative dispersion interrupted by multiple gaps that result from polaritonic-level repulsion and strong coupling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2023, "Volume": 379, "Issue": 6632, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 555, "End Page": 557, "Article Number": null, "DOI": "10.1126/science.adf1065", "DOI Link": "http://dx.doi.org/10.1126/science.adf1065", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001011102400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Li, XY; Zhang, YZ; Li, X; Guan, QH; Wang, J; Zhuang, ZC; Zhuang, Q; Cheng, XM; Liu, HT; Zhang, J; Shen, CY; Lin, HZ; Wang, YL; Zhan, L; Ling, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xin; Li, Xiangyang; Zhang, Yongzheng; Li, Xiang; Guan, Qinghua; Wang, Jian; Zhuang, Zechao; Zhuang, Quan; Cheng, Xiaomin; Liu, Haitao; Zhang, Jing; Shen, Chunyin; Lin, Hongzhen; Wang, Yanli; Zhan, Liang; Ling, Licheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Li+ Desolvation for Diffusion Booster Enabling Low-Temperature Sulfur Redox Kinetics via Electrocatalytic Carbon-Grazfted-CoP Porous nullosheets", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries are famous for their high energy density and low cost, but prevented by sluggish redox kinetics of sulfur species due to depressive Li ion diffusion kinetics, especially under low-temperature environment. Herein, a combined strategy of electrocatalysis and pore sieving effect is put forward to dissociate the Li+ solvation structure to stimulate the free Li+ diffusion, further improving sulfur redox reaction kinetics. As a protocol, an electrocatalytic porous diffusion-boosted nitrogen-doped carbon-grafted-CoP nullosheet is designed via forming the N-Co-P active structure to release more free Li+ to react with sulfur species, as fully investigated by electrochemical tests, theoretical simulations and in situ/ex situ characterizations. As a result, the cells with diffusion booster achieve desirable lifespan of 800 cycles at 2 C and excellent rate capability (775 mAh g(-1) at 3 C). Impressively, in a condition of high mass loading or low-temperature environment, the cell with 5.7 mg cm(-2) stabilizes an areal capacity of 3.2 mAh cm(-2) and the charming capacity of 647 mAh g(-1) is obtained under 0 degrees C after 80 cycles, demonstrating a promising route of providing more free Li ions toward practical high-energy Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 33, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202302624", "DOI Link": "http://dx.doi.org/10.1002/adfm.202302624", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991450300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, CH; van der Sar, T; Zhou, TX; Upadhyaya, P; Casola, F; Zhang, HL; Onbasli, MC; Ross, CA; Walsworth, RL; Tserkovnyak, Y; Yacoby, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Chunhui; van der Sar, Toeno; Zhou, Tony X.; Upadhyaya, Pramey; Casola, Francesco; Zhang, Huiliang; Onbasli, Mehmet C.; Ross, Caroline A.; Walsworth, Ronald L.; Tserkovnyak, Yaroslav; Yacoby, Amir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control and local measurement of the spin chemical potential in a magnetic insulator", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin chemical potential characterizes the tendency of spins to diffuse. Probing this quantity could provide insight into materials such as magnetic insulators and spin liquids and aid optimization of spintronic devices. Here we introduce single-spin magnetometry as a generic platform for nonperturbative, nulloscale characterization of spin chemical potentials. We experimentally realize this platform using diamond nitrogen-vacancy centers and use it to investigate magnons in a magnetic insulator, finding that the magnon chemical potential can be controlled by driving the system's ferromagnetic resonullce. We introduce a symmetry-based two-fluid theory describing the underlying magnon processes, measure the local thermomagnonic torque, and illustrate the detection sensitivity using electrically controlled spin injection. Our results pave the way for nulloscale control and imaging of spin transport in mesoscopic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2017, "Volume": 357, "Issue": 6347, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 195, "End Page": 198, "Article Number": null, "DOI": "10.1126/science.aak9611", "DOI Link": "http://dx.doi.org/10.1126/science.aak9611", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405391700044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, T; Zhang, YB; Li, CH; Wang, YQ; An, QL; Liu, B; Said, Z; Sharma, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Teng; Zhang, Yanbin; Li, Changhe; Wang, Yiqi; An, Qinglong; Liu, Bo; Said, Zafar; Sharma, Shubham", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grindability of carbon fiber reinforced polymer using CNT biological lubricant", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon fiber-reinforced polymer (CFRP) easily realizes the integrated manufacturing of components with high specific strength and stiffness, and it has become the preferred material in the aerospace field. Grinding is the key approach to realize precision parts and matching the positioning surface for assembly and precision. Hygroscopicity limits the application of flood lubrication in CFRP grinding, and dry grinding leads to large force, surface deterioration, and wheel clogging. To solve the above technical bottleneck, this study explored the grindability and frictional behavior of CNT biological lubricant MQL through grinding experiments and friction-wear tests. Results showed that the CNT biological lubricant reduced the friction coefficient by 53.47% compared with dry condition, showing optimal and durable antifriction characteristics. The new lubrication was beneficial to suppressing the removal of multifiber block debris, tensile fracture, and tensile-shear fracture, with the advantages of tribological properties and material removal behavior, the tangential and normal grinding force, and the specific grinding energy were reduced by 40.41%, 31.46%, and 55.78%, respectively, compared with dry grinding. The proposed method reduced surface roughness and obtained the optimal surface morphology by preventing burrs, fiber pull-out, and resin smearing, and wheel clogging was prevented by temperature reduction and lubricating oil film formation. S-a and S-q of the CNT biological lubricant were reduced by 8.4% and 7.9%, respectively, compared with dry grinding. This study provides a practical basis for further application of CNT biological lubricant in CFRP grinding.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 22535, "DOI": "10.1038/s41598-021-02071-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-02071-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720520100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, KJ; Kim, SK; Hirata, Y; Oh, SH; Tono, T; Kim, DH; Okuno, T; Ham, WS; Kim, S; Go, G; Tserkovnyak, Y; Tsukamoto, A; Moriyama, T; Lee, KJ; Ono, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Kab-Jin; Kim, Se Kwon; Hirata, Yuushou; Oh, Se-Hyeok; Tono, Takayuki; Kim, Duck-Ho; Okuno, Takaya; Ham, Woo Seung; Kim, Sanghoon; Go, Gyoungchoon; Tserkovnyak, Yaroslav; Tsukamoto, Arata; Moriyama, Takahiro; Lee, Kyung-Jin; Ono, Teruo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast domain wall motion in the vicinity of the angular momentum compensation temperature of ferrimagnets", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferromagnetic spintronics is an emerging research field which aims to utilize antiferromagnets as core elements in spintronic devices(1,2). A central motivation towards this direction is that antiferromagnetic spin dynamics is expected to be much faster than its ferromagnetic counterpart(3). Recent theories indeed predicted faster dynamics of antiferromagnetic domain walls (DWs) than ferromagnetic DWs(4-6). However, experimental investigations of antiferromagnetic spin dynamics have remained unexplored, mainly because of the magnetic field immunity of antiferromagnets(7). Here we show that fast field-driven antiferromagnetic spin dynamics is realized in ferrimagnets at the angular momentum compensation point TA. Using rare earth-3d-transition metal ferrimagnetic compounds where net magnetic moment is nonzero at TA, the field-driven DW mobility is remarkably enhanced up to 20 km s(-1) T-1. The collective coordinate approach generalized for ferrimagnets(8) and atomistic spin model simulations(6,9) show that this remarkable enhancement is a consequence of antiferromagnetic spin dynamics at TA. Our finding allows us to investigate the physics of antiferromagnetic spin dynamics and highlights the importance of tuning of the angular momentum compensation point of ferrimagnets, which could be a key towards ferrimagnetic spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 372, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 16, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1187, "End Page": "+", "Article Number": null, "DOI": "10.1038/nmat4990", "DOI Link": "http://dx.doi.org/10.1038/nmat4990", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416159700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Macauley, N; Papadias, DD; Fairweather, J; Spernjak, D; Langlois, D; Ahluwalia, R; More, KL; Mukundan, R; Borup, RL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Macauley, Natalia; Papadias, Dennis D.; Fairweather, Joseph; Spernjak, Dusan; Langlois, David; Ahluwalia, Rajesh; More, Karren L.; Mukundan, Rangachary; Borup, Rodney L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon Corrosion in PEM Fuel Cells and the Development of Accelerated Stress Tests", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon corrosion is an important degradation mechanism that can impair PEMFC performance through the destruction of catalyst connectivity, collapse of the electrode pore structure, loss of hydrophobic character, and an increase of the catalyst particle size. In this study, carbon corrosion was quantified in situ by measurement of carbon dioxide in the fuel cell exhaust gases through non-dispersive infrared spectroscopy during simulated drive cycle operations consisting of potential cycling with varying upper and lower potential limits. These studies were conducted for three different types of carbon supports. A reduction in the catalyst layer thickness was observed during a simulated drive cycle operation with a concomitant decrease in catalyst layer porosity, which led to performance losses due to increased mass transport limitations. The observed thickness reduction was primarily due to compaction of the catalyst layer, with the actual mass of carbon oxidation (loss) contributing only a small fraction (<20%). The dynamics of carbon corrosion are presented along with a model that simulates the transient and dynamic corrosion rates observed in our experiments. Accelerated carbon corrosion stress tests are presented and their effects are compared to those observed for the drive cycle test. (C) The Author(s) 2018. Published by ECS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 165, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "F3148", "End Page": "F3160", "Article Number": null, "DOI": "10.1149/2.0061806jes", "DOI Link": "http://dx.doi.org/10.1149/2.0061806jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431807600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZL; Bessa, MA; Liu, WK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zeliang; Bessa, M. A.; Liu, Wing Kam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-consistent clustering analysis: An efficient multi-scale scheme for inelastic heterogeneous materials", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of efficient and accurate descriptions for the macroscopic behavior of materials with complex microstructure is an outstanding challenge in mechanics of materials. A mechanistic, data-driven, two-scale approach is developed for predicting the behavior of general heterogeneous materials under irreversible processes such as inelastic deformation. The proposed approach includes two major innovations: (1) the use of a data compression algorithm, k-means clustering, during the offline stage of the method to homogenize the local features of the material microstructure into a group of clusters; and (2) a new method called self-consistent clustering analysis used in the online stage that is valid for any local plasticity laws of each material phase without the need for additional calibration. A particularly important feature of the proposed approach is that the offline stage only uses the linear elastic properties of each material phase, making it efficient. This work is believed to open new avenues in parameter-free multi-scale modeling of complex materials, and perhaps in other fields that require homogenization of irreversible processes. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 336, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2016, "Volume": 306, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 319, "End Page": 341, "Article Number": null, "DOI": "10.1016/j.cma.2016.04.004", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.04.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376485100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, XH; Shao, ZP; Li, ZP; Liu, DC; Gao, CY; Chen, C; Zhang, BQ; Hao, LZ; Zhao, QQ; Li, YM; Wang, XZ; Lu, Y; Wang, X; Cui, GL; Pang, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Xiuhong; Shao, Zhipeng; Li, Zhipeng; Liu, Dachang; Gao, Caiyun; Chen, Chen; Zhang, Bingqian; Hao, Lianzheng; Zhao, Qiangqiang; Li, Yimeng; Wang, Xianzhao; Lu, Yue; Wang, Xiao; Cui, Guanglei; Pang, Shuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient CsPbI3/Cs1-xDMAxPbI3 bulk heterojunction perovskite solar cell", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The open-circuit voltage (V-OC) of cesium-based perovskite solar cells (Cs-PSCs) is severely limited by carrier recombination both in bulk and at the interface of the perovskite layer, which mainly roots in its elevated fabrication temperature. Enhancing the quality of perovskite film and optimizing the device structure are effective strategies to improve the performance of Cs-PSCs. Here, the V-OC is markedly promoted by constructing CsPbI3/Cs(1-x)DMA(x)PbI(3) bulk heterojunction (BHJ) structure, which was spontaneously formed by a precisely controlled spatially selective phase transition method. The perovskite BHJ structure not only facilitates the charge separation and collection process by enhancing the built-in potential but also obviously reduces the carrier recombination loss. Importantly, a maximum V-OC of 1.23 V was obtained as the V-OC deficit was 0.45 V, and the champion power conversion efficiency (PCE) reached 20.32% (certified PCE of 19.66%). Our finding indicates that junction engineering will be a new strategy for efficient perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 850, "End Page": 860, "Article Number": null, "DOI": "10.1016/j.joule.2022.02.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.02.004", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798575600015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tacchi, S; Troncoso, RE; Ahlberg, M; Gubbiotti, G; Madami, M; Aring;kerman, J; Landeros, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tacchi, S.; Troncoso, R. E.; Ahlberg, M.; Gubbiotti, G.; Madami, M.; Akerman, J.; Landeros, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial Dzyaloshinskii-Moriya Interaction in Pt/CoFeB Films: Effect of the Heavy-Metal Thickness", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the observation of a Pt layer thickness dependence on the induced interfacial DzyaloshinskiiMoriya interaction in ultrathin Pt(d(Pt))/CoFeB films. Taking advantage of the large spin-orbit coupling of the heavy metal, the interfacial Dzyaloshinskii-Moriya interaction is quantified by Brillouin light scattering measurements of the frequency nonreciprocity of spin waves in the ferromagnet. The magnitude of the induced Dzyaloshinskii-Moriya coupling is found to saturate to a value of 0.45 mJ/m(2) for Pt thicknesses larger than similar to 2 nm. The experimental results are explained by analytical calculations based on the three-site indirect exchange mechanism that predicts a Dzyaloshinskii-Moriya interaction at the interface between a ferromagnetic thin layer and a heavy metal. Our findings open up a way to control and optimize chiral effects in ferromagnetic thin films through the thickness of the heavy-metal layer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2017, "Volume": 118, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147201, "DOI": "10.1103/PhysRevLett.118.147201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.147201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399395500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Haden, CV; Zeng, G; Carter, FM; Ruhl, C; Krick, BA; Harlow, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Haden, C., V; Zeng, G.; Carter, F. M., III; Ruhl, C.; Krick, B. A.; Harlow, D. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire and arc additive manufactured steel: Tensile and wear properties", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present study systematically investigated the mechanical properties of wire-based (wire and arc additive manufacturing, known as WAAM) deposition of steel metals, both stainless steel 304 and mild steel ER7OS. Graded material properties of stainless steel 304 were observed for wear and hardness in the direction of deposition and in Z height, due to variations in local thermal histories of the metal. Wear rates decreased significantly (p = 5.6 x 10(-12) by one-way ANOVA) along the length of the deposited material, from K = 2.62 x 10(-5 )mm(3)/N m (+/- 2.32 x 10(-6) mm(3)/N m), to K= 0.63 mm3 x 10(-5) mm3/N m (+/-3.08 x 10-6 mm(3)/N m), whereas microhardness values increased significantly (p similar to 0 by one-way ANOVA) along the same path from mu = 202.3 HV and sigma = 5.82 HV to 210.9 HV and sigma = 5.91 HV. The yield and ultimate strength, however, were not found to be statistically significantly different (p = 0.55) along the direction of deposition for SS304. During wear testing, a grain refinement was observed directly beneath the wear scar in these materials in a focused ion beam channel observed under scanning electron microscopy. Additionally, no significant difference in yield strength was observed in printed mild steel (ER70S) between vertical and horizontal specimens. The observed graded mechanical properties in stainless steel 304 allow the opportunity for varying the processing conditions to design parts with locally optimized or functionally graded mechanical properties. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 115, "End Page": 123, "Article Number": null, "DOI": "10.1016/j.addma.2017.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2017.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, AY; Zhang, C; Norman, J; Snyder, A; Lubyshev, D; Fastenau, JM; Liu, AWK; Gossard, AC; Bowers, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Alan Y.; Zhang, Chong; Norman, Justin; Snyder, Andrew; Lubyshev, Dmitri; Fastenau, Joel M.; Liu, Amy W. K.; Gossard, Arthur C.; Bowers, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performance continuous wave 1.3 μm quantum dot lasers on silicon", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate record performance 1.3 mu m InAs quantum dot lasers grown on silicon by molecular beam epitaxy. Ridge waveguide lasers fabricated from the as-grown material achieve room temperature continuous wave thresholds as low as 16 mA, output powers exceeding 176 mW, and lasing up to 119 degrees C. P-modulation doping of the active region improves T-0 to the range of 100-200K while maintaining low thresholds and high output powers. Device yield is presented showing repeatable performance across different dies and wafers. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2014, "Volume": 104, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41104, "DOI": "10.1063/1.4863223", "DOI Link": "http://dx.doi.org/10.1063/1.4863223", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331209900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chien, YC; Liu, H; Menon, AS; Brant, WR; Brandell, D; Lacey, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chien, Yu-Chuan; Liu, Haidong; Menon, Ashok S.; Brant, William R.; Brandell, Daniel; Lacey, Matthew J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rapid determination of solid-state diffusion coefficients in Li-based batteries via intermittent current interruption method", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The galvanostatic intermittent titration technique (GITT) is considered the go-to method for determining the Li+ diffusion coefficients in insertion electrode materials. However, GITT-based methods are either time-consuming, prone to analysis pitfalls or require sophisticated interpretation models. Here, we propose the intermittent current interruption (ICI) method as a reliable, accurate and faster alternative to GITT-based methods. Using Fick's laws, we prove that the ICI method renders the same information as the GITT within a certain duration of time since the current interruption. Via experimental measurements, we also demonstrate that the results from ICI and GITT methods match where the assumption of semi-infinite diffusion applies. Moreover, the benefit of the non-disruptive ICI method to operando materials characterization is exhibited by correlating the continuously monitored diffusion coefficient of Li+ in a LiNi0.8Mn0.1Co0.1O2-based electrode to its structural changes captured by operando X-ray diffraction measurements. The galvanostatic intermittent titration technique (GITT) is the state-of-the-art method for determining the Li+ diffusion coefficients in battery materials. Here, authors propose the intermittent current interruption method as a reliable, accurate and faster alternative to GITT-based methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2289, "DOI": "10.1038/s41467-023-37989-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37989-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, C; Yin, QW; Tu, ZJ; Gong, CS; Lei, HC; Li, Z; Luo, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Chao; Yin, Qiangwei; Tu, Zhijun; Gong, Chunsheng; Lei, Hechang; Li, Zheng; Luo, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-Wave Superconductivity in Kagome Metal CsV3Sb5 Revealed by 121/123Sb NQR and 51V NMR Measurements", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report Sb-121/123 nuclear quadrupole resonullce (NQR) and V-51 nuclear magnetic resonullce (NMR) measurements on kagome metal CsV3Sb5 with T (c) = 2.5 K. Both V-51 NMR spectra and Sb-121/123 NQR spectra split after a charge density wave (CDW) transition, which demonstrates a commensurate CDW state. The coexistence of the high temperature phase and the CDW phase between 91 K and 94 K manifests that it is a first-order phase transition. At low temperature, electric-field-gradient fluctuations diminish and magnetic fluctuations become dominullt. Superconductivity emerges in the charge order state. Knight shift decreases and 1/T (1) T shows a Hebel-Slichter coherence peak just below T (c), indicating that CsV3Sb5 is an s-wave superconductor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 38, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77402, "DOI": "10.1088/0256-307X/38/7/077402", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/38/7/077402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000681457900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, SY; Cheng, P; Li, G; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Sheng-Yung; Cheng, Pei; Li, Gang; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent Polymer Photovoltaics for Solar Energy Harvesting and Beyond", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer photovoltaics have become a promising alternative energy due to lightweight properties, environmental friendliness, and solution processability. Transparent organic photovoltaics in particular have been recently receiving more attention in the photovoltaics field due to their unique potential in future applications beyond mere harvesting of solar energy. This perspective is further enhanced by the recent developments of high-performance polymer photovoltaics (including infrared absorbing materials and devices) that could achieve superior visible transparency and power conversion efficiency. To realize high-performance transparent organic photovoltaics, the main strategy is to shift the active-layer absorption spectrum to the infrared region by designing new low-bandgap donors and non-fullerene acceptors, and to reduce the invalid absorption by developing new transparent electrode materials. The potential applications are diverse, especially for spectrum-sensitive ones such as the greenhouse in agriculture. Finally, some key research areas of transparent organic photovoltaics that may deserve further attention are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2018, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1039, "End Page": 1054, "Article Number": null, "DOI": "10.1016/j.joule.2018.04.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.04.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437403100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JH; Lee, S; Kim, T; Ahn, H; Jang, GY; Kim, KH; Cho, YJ; Zhang, K; Park, JS; Park, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jung Hwan; Lee, SunJe; Kim, Taehee; Ahn, Hyungju; Jang, Gyu Yong; Kim, Kwang Hee; Cho, Yoon Jun; Zhang, Kan; Park, Ji-Sang; Park, Jong Hyeok", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial ?-FAPbI3 phase stabilization by reducing oxygen vacancies in SnO2_x", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing nonradiative recombination in SnO2_x has been a critical point for fabricating efficient and stable perovskite solar cells (PSCs). Controlling oxygen vacancies in SnO2_x is an efficient strat-egy, but most research only presents the consequential results without scrutinizing the phenomenological part of the strategy. Here, we deeply examined and revealed a new beneficial effect of controlling oxygen vacancies in SnO2_x. Oxygen atoms of SnO2_x were responsible for retaining a-FAPbI3 at the FAPbI3/SnO2_x inter-face by controlling the formation of iodine interstitials, which are strong initiators of unfavorable perovskite phase transitions. Using crystallographic analysis, we observed suppression of these phase transitions when oxygen vacancies were mitigated in SnO2_x by oxidized black phosphorus quantum dots. Furthermore, formamidi-nium (FA) cation retention was also observed as a beneficial effect of the strategy by introducing hydrogen bonding sources for FA cat-ions at the interface. Our findings suggest the genuine necessity of oxygen vacancy reduction in SnO2_x.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 380, "End Page": 397, "Article Number": null, "DOI": "10.1016/j.joule.2022.12.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.12.006", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939881300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, DY; Bouzolin, D; Lu, HB; Griffith, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Dongyang; Bouzolin, Dan; Lu, Hongbing; Griffith, Todd", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bending and shear improvements in 3D-printed core sandwich composites through modification of resin uptake in the skin/core interphase region", "Source Title": "COMPOSITES PART B-ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused deposition modeling (FDM) printed polymers are rarely used as a structural material due to anisotropic and low mechanical properties compared with conventional composites. In recent years, greater need has been expressed for recycling of materials, such as recyclable FDM, at the end of service life to reduce environmental pollution and manufacture cost. However, how the amount of resin uptake in the skin and skin/core interphase affects the bending and shear performance of the sandwich composites when replacing the low strength and ductile core (conventional core) with a high strength and brittle core (FDM printed PLA (polylactic acid) core) still remains unclear. A new manufacturing routine is needed to improve the incorporation of FDM printed polymers in composite structures. In this work, FDM printed PLA was used as core material and sandwiched between two unidirectional glass fiber reinforced polymer (GFRP) skins to form a sandwich composite by compression-molding (CM) process, which provides a good manufacturing strategy for skin/core interphase modification. The significance of the CM process is proved by investigating the effect of resin uptake on bending and in-plane/out-of-plane shear performances. Current first order shear deformation (FSDT) theory lacks a direct connection between the in-plane shear stress and out-of-shear stress in the core region of sandwich composites. With the help of DIC, a connection between the in-plane shear and the out-of-plane shear strain was built and in plane shear properties can acquire through out-of-plane shear properties, hence reducing the redundancy of sample preparation or the need for simulation. A significant improvement was found compared with the optimized resin uptake (Optimized resin uptake range: 20.43%-22.86 wt%) 3D-printed PLA core sandwich composite and lowest performance sandwich composite (Improvement: in-plane shear strength (-34%)/modulus (-29%), out-of-plane shear strength (-25%)/modulus (-31%), specific peak bending load (-19%)). Compared with balsa core sandwich composites, the 3D-printed cores are suitable for use in composite sandwich structures in many applications with a satisfactory strength-to-weight ratio.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 264, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110912, "DOI": "10.1016/j.compositesb.2023.110912", "DOI Link": "http://dx.doi.org/10.1016/j.compositesb.2023.110912", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001106767900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, SM; Xu, SY; Belopolski, I; Lee, CC; Chang, G; Chang, TR; Wang, B; Alidoust, N; Bian, G; Neupane, M; Sanchez, D; Zheng, H; Jeng, HT; Bansil, A; Neupert, T; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Shin-Ming; Xu, Su-Yang; Belopolski, Ilya; Lee, Chi-Cheng; Chang, Guoqing; Chang, Tay-Rong; Wang, BaoKai; Alidoust, Nasser; Bian, Guang; Neupane, Madhab; Sanchez, Daniel; Zheng, Hao; Jeng, Horng-Tay; Bansil, Arun; Neupert, Titus; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New type of Weyl semimetal with quadratic double Weyl fermions", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals have attracted worldwide attention due to their wide range of exotic properties predicted in theories. The experimental realization had remained elusive for a long time despitemuch effort. Very recently, the first Weyl semimetal has been discovered in an inversion-breaking, stoichiometric solid TaAs. So far, the TaAs class remains the only Weyl semimetal available in real materials. To facilitate the transition of Weyl semimetals from the realm of purely theoretical interest to the realm of experimental studies and device applications, it is of crucial importance to identify other robust candidates that are experimentally feasible to be realized. In this paper, we propose such a Weyl semimetal candidate in an inversion-breaking, stoichiometric compound strontium silicide, SrSi2, with many new and novel properties that are distinct from TaAs. We show that SrSi2 is a Weyl semimetal even without spin-orbit coupling and that, after the inclusion of spin-orbit coupling, two Weyl fermions stick together forming an exotic double Weyl fermion with quadratic dispersions and a higher chiral charge of +/- 2. Moreover, we find that the Weyl nodes with opposite charges are located at different energies due to the absence of mirror symmetry in SrSi2, paving the way for the realization of the chiral magnetic effect. Our systematic results not only identify a much-needed robust Weyl semimetal candidate but also open the door to new topological Weyl physics that is not possible in TaAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2016, "Volume": 113, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1180, "End Page": 1185, "Article Number": null, "DOI": "10.1073/pnas.1514581113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1514581113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369085100042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mogi, M; Yoshimi, R; Tsukazaki, A; Yasuda, K; Kozuka, Y; Takahashi, KS; Kawasaki, M; Tokura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mogi, M.; Yoshimi, R.; Tsukazaki, A.; Yasuda, K.; Kozuka, Y.; Takahashi, K. S.; Kawasaki, M.; Tokura, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic modulation doping in topological insulators toward higher-temperature quantum anomalous Hall effect", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum anomalous Hall effect (QAHE), which generates dissipation-less edge current without external magnetic field, is observed in magnetic-ion doped topological insulators (TIs) such as Cr- and V-doped (Bi,Sb)(2)Te-3. The QAHE emerges when the Fermi level is inside the magnetically induced gap around the original Dirac point of the TI surface state. Although the size of gap is reported to be about 50 meV, the observable temperature of QAHE has been limited below 300 mK. We attempt magnetic-Cr modulation doping into topological insulator (Bi,Sb)(2)Te-3 films to increase the observable temperature of QAHE. By introducing the rich-Cr-doped thin (1 nm) layers at the vicinity of both the surfaces based on non-Cr-doped (Bi,Sb)(2)Te-3 films, we have succeeded in observing the QAHE up to 2K. The improvement in the observable temperature achieved by this modulation-doping appears to be originating from the suppression of the disorder in the surface state interacting with the rich magnetic moments. Such a superlattice designing of the stabilized QAHE may pave a way to dissipation-less electronics based on the higher-temperature and zero magnetic-field quantum conduction. (C) 2015 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2015, "Volume": 107, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 182401, "DOI": "10.1063/1.4935075", "DOI Link": "http://dx.doi.org/10.1063/1.4935075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364580800028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, J; Ma, LG; Liu, S; Watanabe, K; Taniguchi, T; Hone, JC; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Jie; Ma, Liguo; Liu, Song; Watanabe, Kenji; Taniguchi, Takashi; Hone, James C.; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dipolar excitonic insulator in a moire lattice", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional moire materials provide a highly controllable solid-state platform for studies of quantum phenomena(1-3). To date, experimental studies have focused on correlated electronic states, whereas correlated bosonic states in moire materials have received less attention. Here we report the observation of a correlated dipolar excitonic insulator-a charge-insulating state driven by exciton formation(4)-in a device where a WSe2 monolayer and WSe2/WS2 moire bilayer are coupled via Coulomb interactions. The system is a Mott insulator when all the holes reside in the moire layer. Under an out-of-plane electric field, the holes can be continuously transferred to the WSe2 monolayer, but remain strongly bound to the empty moire sites, effectively forming an interlayer exciton fluid in the moire lattice. We further observe the emergence of local magnetic moments in the WSe2 monolayer induced by the strong interlayer Coulomb correlation. Our result provides a platform for realizing correlated quantum phenomena described by bosonic lattice models in a solid-state system, complementary to cold-atom setups(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 18, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 395, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-022-01532-z", "DOI Link": "http://dx.doi.org/10.1038/s41567-022-01532-z", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767111500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, DC; Li, HY; Zhang, DW; Zhang, QY; Meijerink, A; Suta, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Dechao; Li, Huaiyong; Zhang, Dawei; Zhang, Qinyuan; Meijerink, Andries; Suta, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One ion to catch them all: Targeted high-precision Boltzmann thermometry over a wide temperature range with Gd3+", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ratiometric luminescence thermometry with trivalent lanthanide ions and their 4f(n) energy levels is an emerging technique for non-invasive remote temperature sensing with high spatial and temporal resolution. Conventional ratiometric luminescence thermometry often relies on thermal coupling between two closely lying energy levels governed by Boltzmann's law. Despite its simplicity, Boltzmann thermometry with two excited levels allows precise temperature sensing, but only within a limited temperature range. While low temperatures slow down the nonradiative transitions required to generate a measurable population in the higher excitation level, temperatures that are too high favour equalized populations of the two excited levels, at the expense of low relative thermal sensitivity. In this work, we extend the concept of Boltzmann thermometry to more than two excited levels and provide quantitative guidelines that link the choice of energy gaps between multiple excited states to the performance in different temperature windows. By this approach, it is possible to retain the high relative sensitivity and precision of the temperature measurement over a wide temperature range within the same system. We demonstrate this concept using YAl3(BO3)(4) (YAB):Pr3+, Gd3+ with an excited P-6(J) crystal field and spin-orbit split levels of Gd3+ in the UV range to avoid a thermal black body background even at the highest temperatures. This phosphor is easily excitable with inexpensive and powerful blue LEDs at 450 nm. Zero-background luminescence thermometry is realized by using blue-to-UV energy transfer upconversion with the Pr3+-Gd3+ couple upon excitation in the visible range. This method allows us to cover a temperature window between 30 and 800 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2021, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 236, "DOI": "10.1038/s41377-021-00677-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-021-00677-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722002600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Niu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Lifa; Niu, Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral Phonons at High-Symmetry Points in Monolayer Hexagonal Lattices", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In monolayer hexagonal lattices, the intravalley and intervalley scattering of electrons can involve chiral phonons at Brillouin-zone center and corners, respectively. At these high-symmetry points, there is a threefold rotational symmetry endowing phonon eigenmodes with a quantized pseudoangular momentum, which includes orbital and spin parts. Conservation of pseudoangular momentum yields selection rules for intravalley and intervalley scattering of electrons by phonons. Concrete predictions of helicity-resolved optical phenomena are made on monolayer molybdenum disulfide. The chiral phonons at Brillouin-zone corners excited by polarized photons can be detected by a valley phonon Hall effect. The chiral phonons, together with phonon circular polarization, phonon pseudoangular momentum, selection rules, and valley phonon Hall effect will extend the basis for valley-based electronics and phononics applications in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2015, "Volume": 115, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115502, "DOI": "10.1103/PhysRevLett.115.115502", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.115502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361040800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Arnab, AA; Das, RC; Hossain, KM; Rubel, MHK; Rahman, MF; Bencherif, H; Emetere, ME; Mohammed, MKA; Pandey, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Arnab, A. A.; Das, Ranjit C.; Hossain, K. M.; Rubel, M. H. K.; Rahman, Md. Ferdous; Bencherif, H.; Emetere, M. E.; Mohammed, Mustafa K. A.; Pandey, Rahul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combined DFT, SCAPS-1D, and wxAMPS frameworks for design optimization of efficient Cs2BiAgI6-based perovskite solar cells with different charge transport layers", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, combined DFT, SCAPS-1D, and wxAMPS frameworks are used to investigate the optimized designs of Cs2BiAgI6 double perovskite-based solar cells. First-principles calculations are employed to investigate the structural stability, optical responses, and electronic contribution of the constituent elements in Cs2BiAgI6 absorber material, where SCAPS-1D and wxAMPS simulators are used to scrutinize different configurations of Cs2BiAgI6 solar cells. Here, PCBM, ZnO, TiO2, C-60, IGZO, SnO2, WS2, and CeO2 are used as ETL, and Cu2O, CuSCN, CuSbS2, NiO, P3HT, PEDOT:PSS, spiro-MeOTAD, CuI, CuO, V2O5, CBTS, CFTS are used as HTL, and Au is used as a back contact. About ninety-six combinations of Cs2BiAgI6-based solar cell structures are investigated, in which eight sets of solar cell structures are identified as the most efficient structures. Besides, holistic investigation on the effect of different factors such as the thickness of different layers, series and shunt resistances, temperature, capacitance, Mott-Schottky and generation-recombination rates, and J-V (current-voltage density) and QE (quantum efficiency) characteristics is performed. The results show CBTS as the best HTL for Cs2BiAgI6 with all eight ETLs used in this work, resulting in a power conversion efficiency (PCE) of 19.99%, 21.55%, 21.59%, 17.47%, 20.42%, 21.52%, 14.44%, 21.43% with PCBM, TiO2, ZnO, C-60, IGZO, SnO2, CeO2, WS2, respectively. The proposed strategy may pave the way for further design optimization of lead-free double perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 6", "Publication Year": 2022, "Volume": 12, "Issue": 54, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 34850, "End Page": 34873, "Article Number": null, "DOI": "10.1039/d2ra06734j", "DOI Link": "http://dx.doi.org/10.1039/d2ra06734j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000893435000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ryu, H; Wu, HN; Rao, FB; Zhu, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ryu, Hojoon; Wu, Haonull; Rao, Fubo; Zhu, Wenjuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric Tunneling Junctions Based on Aluminum Oxide/Zirconium-Doped Hafnium Oxide for Neuromorphic Computing", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ferroelectric tunneling junctions (FTJs) with tunable tunneling electroresistance (TER) are promising for many emerging applications, including non-volatile memories and neurosynaptic computing. One of the key challenges in FTJs is the balance between the polarization value and the tunneling current. In order to achieve a sizable on-current, the thickness of the ferroelectric layer needs to be scaled down below 5 nm. However, the polarization in these ultra-thin ferroelectric layers is very small, which leads to a low tunneling electroresistance (TER) ratio. In this paper, we propose and demonstrate a new type of FTJ based on metal/Al2O3/Zr-doped HfO2/Si structure. The interfacial Al2O3 layer and silicon substrate enable sizable TERs even when the thickness of Zr-doped HfO2 (HZO) is above 10 nm. We found that F-N tunneling dominates at read voltages and that the polarization switching in HZO can alter the effective tunneling barrier height and tune the tunneling resistance. The FTJ synapses based on Al2O3/HZO stacks show symmetric potentiation/depression characteristics and widely tunable conductance. We also show that spike-timing-dependent plasticity (STDP) can be harnessed from HZO based FTJs. These novel FTJs will have high potential in non-volatile memories and neural network applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 31", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20383, "DOI": "10.1038/s41598-019-56816-x", "DOI Link": "http://dx.doi.org/10.1038/s41598-019-56816-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508985300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Airao, J; Nirala, CK; Bertolini, R; Krolczyk, GM; Khanna, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Airao, Jay; Nirala, Chandrakant K.; Bertolini, Rachele; Krolczyk, Grzegorz M.; Khanna, Navneet", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainable cooling strategies to reduce tool wear, power consumption and surface roughness during ultrasonic assisted turning of Ti-6Al-4V", "Source Title": "TRIBOLOGY INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Issues related to the machinability of difficult-to-machine materials such as Titanium and Nickel base superalloys are well explicated in the literature. In this regard, a novel study, applying ultrasonic vibration along with MQL and LCO2, is proposed to enhance the machinability of Ti-6Al-4V. In this regard, this article attempts to analyze machinability of Ti-6Al-4V in conventional and Ultrasonic Assisted Turning (UAT) under dry, wet, MQL and LCO2. The experiments are performed on an in-house developed ultrasonic assisted turning setup, keeping all the machining parameters constant. The main tool wear mechanisms observed are diffusion, adhesion, abrasion, and built-up edge formation in both cutting strategies. Moreover, the LCO2 and ultrasonic vibration significantly reduce specific cutting energy without compromising the surface roughness and tool life. Ultimately, the LCO2, along with ultrasonic assisted turning, promotes sustainability in the machining of Ti-6Al-4V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 169, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107494, "DOI": "10.1016/j.triboint.2022.107494", "DOI Link": "http://dx.doi.org/10.1016/j.triboint.2022.107494", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000761217800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Broido, D; Esfarjani, K; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Sangyeop; Broido, David; Esfarjani, Keivan; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrodynamic phonon transport in suspended graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent studies of thermal transport in nullomaterials have demonstrated the breakdown of Fourier's law through observations of ballistic transport. Despite its unique features, another instance of the breakdown of Fourier's law, hydrodynamic phonon transport, has drawn less attention because it has been observed only at extremely low temperatures and narrow temperature ranges in bulk materials. Here, we predict on the basis of first-principles calculations that the hydrodynamic phonon transport can occur in suspended graphene at significantly higher temperatures and wider temperature ranges than in bulk materials. The hydrodynamic transport is demonstrated through drift motion of phonons, phonon Poiseuille flow and second sound. The significant hydrodynamic phonon transport in graphene is associated with graphene's two-dimensional features. This work opens a new avenue for understanding and manipulating heat flow in two-dimensional materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6290, "DOI": "10.1038/ncomms7290", "DOI Link": "http://dx.doi.org/10.1038/ncomms7290", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350289700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kazakova, O; Puttock, R; Barton, C; Corte-León, H; Jaafar, M; Neu, V; Asenjo, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kazakova, O.; Puttock, R.; Barton, C.; Corte-Leon, H.; Jaafar, M.; Neu, V.; Asenjo, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Frontiers of magnetic force microscopy", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since it was first demonstrated in 1987, magnetic force microscopy (MFM) has become a truly widespread and commonly used characterization technique that has been applied to a variety of research and industrial applications. Some of the main advantages of the method includes its high spatial resolution (typically similar to 50 nm), ability to work in variable temperature and applied magnetic fields, versatility, and simplicity in operation, all without almost any need for sample preparation. However, for most commercial systems, the technique has historically provided only qualitative information, and the number of available modes was typically limited, thus not reflecting the experimental demands. Additionally, the range of samples under study was largely restricted to classic ferromagnetic samples (typically, thin films or patterned nullostructures). Throughout this Perspective article, the recent progress and development of MFM is described, followed by a summary of the current state-of-the-art techniques and objects for study. Finally, the future of this fascinating field is discussed in the context of emerging instrumental and material developments. Aspects including quantitative MFM, the accurate interpretation of the MFM images, new instrumentation, probe-engineering alternatives, and applications of MFM to new (often interdisciplinary) areas of the materials science, physics, and biology will be discussed. We first describe the physical principles of MFM, specifically paying attention to common artifacts frequently occurring in MFM measurements; then, we present a comprehensive review of the recent developments in the MFM modes, instrumentation, and the main application areas; finally, the importance of the technique is speculated upon for emerging or anticipated to emerge fields including skyrmions, 2D-materials, and topological insulators. Published under license by AIP Publishing", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2019, "Volume": 125, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 60901, "DOI": "10.1063/1.5050712", "DOI Link": "http://dx.doi.org/10.1063/1.5050712", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458877500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "La Monaca, A; Murray, JW; Liao, ZR; Speidel, A; Robles-Linares, JA; Axinte, DA; Hardy, MC; Clare, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "La Monaca, Andrea; Murray, James W.; Liao, Zhirong; Speidel, Alistair; Robles-Linares, Jose A.; Axinte, Dragos A.; Hardy, Mark C.; Clare, Adam T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface integrity in metal machining-Part II: Functional performance", "Source Title": "INTERNATIONAL JOURNAL OF MACHINE TOOLS & MANUFACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Material removal operations play a pivotal role in the manufacture of key components, required for engineering systems to operate safely and efficiently under ever more advanced functional requirements and over extended life cycles. To further step up the loading capability of machined parts, fundamental understanding of how of machining-induced features can influence the performance of advanced materials under complex service conditions is necessary over finer temporal and spatial scales. As discussed in Part I of this review, when engineering surfaces are generated by material removal processes, a wide range of physical mechanisms (e.g. mechanical, thermal, chemical and their combinations) drive the characteristics of workpiece surface integrity. In Part II of this review, the interplay between the metallurgical and micro-mechanical condition induced by material removal processes and their in-service response will be thoroughly explored, by a critical analysis of the state-ofthe-art in the field. Specifically, attention is focused on recent advances made towards the understanding of the mechanisms determining the resistance of machined surface to fatigue crack nucleation (Section 2), corrosion and stress-corrosion cracking (Section 3), and wear (Section 4). Furthermore, the impact of relevant postmachining treatments on the in-service behaviour of machined surfaces is analysed, and the possible strategies for the enhancement of the functional performance of machined surfaces are presented (Section 5). Finally, the current research gaps and the prospective challenges in understanding the in-service behaviour of machined surfaces are critically discussed, providing an interpretation of the possible directions of future scientific development of this field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 164, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103718, "DOI": "10.1016/j.ijmachtools.2021.103718", "DOI Link": "http://dx.doi.org/10.1016/j.ijmachtools.2021.103718", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641080000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weierstall, U; James, D; Wang, C; White, TA; Wang, DJ; Liu, W; Spence, JCH; Doak, RB; Nelson, G; Fromme, P; Fromme, R; Grotjohann, I; Kupitz, C; Zatsepin, NA; Liu, HG; Basu, S; Wacker, D; Han, GW; Katritch, V; Boutet, S; Messerschmidt, M; Williams, GJ; Koglin, JE; Seibert, MM; Klinker, M; Gati, C; Shoeman, RL; Barty, A; Chapman, HN; Kirian, RA; Beyerlein, KR; Stevens, RC; Li, DF; Shah, STA; Howe, N; Caffrey, M; Cherezov, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weierstall, Uwe; James, Daniel; Wang, Chong; White, Thomas A.; Wang, Dingjie; Liu, Wei; Spence, John C. H.; Doak, R. Bruce; Nelson, Garrett; Fromme, Petra; Fromme, Raimund; Grotjohann, Ingo; Kupitz, Christopher; Zatsepin, Nadia A.; Liu, Haiguang; Basu, Shibom; Wacker, Daniel; Han, Gye Won; Katritch, Vsevolod; Boutet, Sebastien; Messerschmidt, Marc; Williams, Garth J.; Koglin, Jason E.; Seibert, M. Marvin; Klinker, Markus; Gati, Cornelius; Shoeman, Robert L.; Barty, Anton; Chapman, Henry N.; Kirian, Richard A.; Beyerlein, Kenneth R.; Stevens, Raymond C.; Li, Dianfan; Shah, Syed T. A.; Howe, Nicole; Caffrey, Martin; Cherezov, Vadim", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lipidic cubic phase injector facilitates membrane protein serial femtosecond crystallography", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lipidic cubic phase (LCP) crystallization has proven successful for high-resolution structure determination of challenging membrane proteins. Here we present a technique for extruding gel-like LCP with embedded membrane protein microcrystals, providing a continuously renewed source of material for serial femtosecond crystallography. Data collected from sub-10-mu m-sized crystals produced with less than 0.5 mg of purified protein yield structural insights regarding cyclopamine binding to the Smoothened receptor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 461, "Times Cited, All Databases": 525, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3309, "DOI": "10.1038/ncomms4309", "DOI Link": "http://dx.doi.org/10.1038/ncomms4309", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332668300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmad, N; Zhao, YH; Ye, F; Zhao, J; Chen, S; Zheng, ZH; Fan, P; Yan, C; Li, YF; Su, ZH; Zhang, XH; Liang, GX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmad, Nafees; Zhao, Yunhai; Ye, Fan; Zhao, Jun; Chen, Shuo; Zheng, Zhuanghao; Fan, Ping; Yan, Chang; Li, Yingfen; Su, Zhenghua; Zhang, Xianghua; Liang, Guangxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cadmium-Free Kesterite Thin-Film Solar Cells with High Efficiency Approaching 12%", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cadmium sulfide (CdS) buffer layer is commonly used in Kesterite Cu2ZnSn(S,Se)(4) (CZTSSe) thin film solar cells. However, the toxicity of Cadmium (Cd) and perilous waste, which is generated during the deposition process (chemical bath deposition), and the narrow bandgap (& AP;2.4 eV) of CdS restrict its large-scale future application. Herein, the atomic layer deposition (ALD) method is proposed to deposit zinc-tin-oxide (ZTO) as a buffer layer in Ag-doped CZTSSe solar cells. It is found that the ZTO buffer layer improves the band alignment at the Ag-CZTSSe/ZTO heterojunction interface. The smaller contact potential difference of the ZTO facilitates the extraction of charge carriers and promotes carrier transport. The better p-n junction quality helps to improve the open-circuit voltage (V-OC) and fill factor (FF). Meanwhile, the wider bandgap of ZTO assists to transfer more photons to the CZTSSe absorber, and more photocarriers are generated thus improving short-circuit current density (Jsc). Ultimately, Ag-CZTSSe/ZTO device with 10 nm thick ZTO layer and 5:1 (Zn:Sn) ratio, Sn/(Sn + Zn): 0.28 deliver a superior power conversion efficiency (PCE) of 11.8%. As far as it is known that 11.8% is the highest efficiency among Cd-free kesterite thin film solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 10, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302869", "DOI Link": "http://dx.doi.org/10.1002/advs.202302869", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001020124100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ríos, C; Du, QY; Zhang, YF; Popescu, CC; Shalaginov, MY; Miller, P; Roberts, C; Kang, M; Richardson, KA; Gu, T; Vitale, SA; Hu, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rios, Carlos; Du, Qingyang; Zhang, Yifei; Popescu, Cosmin-Constantin; Shalaginov, Mikhail Y.; Miller, Paul; Roberts, Christopher; Kang, Myungkoo; Richardson, Kathleen A.; Gu, Tian; Vitale, Steven A.; Hu, Juejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-compact nonvolatile phase shifter based on electrically reprogrammable transparent phase change materials", "Source Title": "PHOTONIX", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical phase shifters constitute the fundamental building blocks that enable programmable photonic integrated circuits (PICs)-the cornerstone of on-chip classical and quantum optical technologies [1, 2] . Thus far, carrier modulation and thermo-optical effect are the chosen phenomena for ultrafast and low-loss phase shifters, respectively; however, the state and information they carry are lost once the power is turned off-they are volatile. The volatility not only compromises energy efficiency due to their demand for constant power supply, but also precludes them from emerging applications such as in-memory computing. To circumvent this limitation, we introduce a phase shifting mechanism that exploits the nonvolatile refractive index modulation upon structural phase transition of Sb2Se3, a bi-state transparent phase change material (PCM). A zero-static power and electrically-driven phase shifter is realized on a CMOS-backend silicon-on-insulator platform, featuring record phase modulation up to 0.09 pi/mu m and a low insertion loss of 0.3 dB/pi, which can be further improved upon streamlined design. Furthermore, we demonstrate phase and extinction ratio trimming of ring resonators and pioneer a one-step partial amorphization scheme to enhance speed and energy efficiency of PCM devices. A diverse cohort of programmable photonic devices is demonstrated based on the ultra-compact PCM phase shifter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2022, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26, "DOI": "10.1186/s43074-022-00070-4", "DOI Link": "http://dx.doi.org/10.1186/s43074-022-00070-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000871974600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JS; Oh, H; Choi, I; Yoon, CS; Han, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jung-Soo; Oh, Hyewon; Choi, Inyoung; Yoon, Chan Suk; Han, Jaejoon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physico-chemical characteristics of rice protein-based novel textured vegetable proteins as meat analogues produced by low-moisture extrusion cooking technology", "Source Title": "LWT-FOOD SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, active research is being focused on the development of future foods that can replace conventional meat. Meat analogues have been drawing considerable attention as possible alternatives to meat. In this study, the possibility of using rice protein isolate (RPI) to create meat analogues was investigated. Therefore, novel textured rice proteins (TRPs), which are meat analogues, were prepared from RPI and soy protein isolate (SPI) as primary raw materials by blending RPI and SPI at ratios approximately 25:75, 50:50, 75:25, and 100:0 (w/w). Meanwhile, corn starch and wheat gluten, minor ingredients, were added at 29% and 13% (w/w) of the total weight of the all ingredients, respectively, in all samples. Low-moisture extrusion cooking process using a twinscrew extruder was used for manufacturing TRPs. An analysis of physico-chemical characteristics showed that RPI replacement decreased specific mechanical energy, porosity, and water absorption capacity of the meat analogues. However, meat analogues made from combinations of RPI and SPI had better nutritional quality than commercial one, whose main ingredient is SPI without the addition of RPI and displayed desirable results pertaining to their soluble matter content during rehydration. Consequently, RPI exhibits potential to partially replace SPI in the manufacture of meat analogues.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113056, "DOI": "10.1016/j.lwt.2021.113056", "DOI Link": "http://dx.doi.org/10.1016/j.lwt.2021.113056", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745065700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZY; Wang, YZ; Ying, PH; Song, KK; Wang, JJ; Wang, Y; Zeng, ZZ; Ke, X; Lindgren, E; Rahm, JM; Gabourie, AJ; Liu, JH; Dong, HK; Wu, JY; Yue, C; Zheng, Z; Jian, S; Erhart, P; Su, YJ; Ala-Nissila, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zheyong; Wang, Yanzhou; Ying, Penghua; Song, Keke; Wang, Junjie; Wang, Yong; Zeng, Zezhu; Xu, Ke; Lindgren, Eric; Magnus Rahm, J.; J. Gabourie, Alexander; Liu, Jiahui; Dong, Haikuan; Wu, Jianyang; Chen, Yue; Zhong, Zheng; Sun, Jian; Erhart, Paul; Su, Yanjing; Ala-Nissila, Tapio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "GPUMD: A package for constructing accurate machine-learned potentials and performing highly efficient atomistic simulations", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present our latest advancements of machine-learned potentials (MLPs) based on the neuroevolution potential (NEP) framework introduced in [Fan et al., Phys. Rev. B 104, 104309 (2021)] and their implementation in the open-source package GPUMD. We increase the accuracy of NEP models both by improving the radial functions in the atomic-environment descriptor using a linear combination of Chebyshev basis functions and by extending the angular descriptor with some four-body and five-body contributions as in the atomic cluster expansion approach. We also detail our efficient implementation of the NEP approach in graphics processing units as well as our workflow for the construction of NEP models, and we demonstrate their application in large-scale atomistic simulations. By comparing to state-of-the-art MLPs, we show that the NEP approach not only achieves above-average accuracy but also is far more computationally efficient. These results demonstrate that the GPUMD package is a promising tool for solving challenging problems requiring highly accurate, large-scale atomistic simulations. To enable the construction of MLPs using a minimal training set, we propose an active-learning scheme based on the latent space of a pre-trained NEP model. Finally, we introduce three separate Python packages, GPYUMD, CALORINE, and PYNEP, which enable the integration of GPUMD into Python workflows.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2022, "Volume": 157, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114801, "DOI": "10.1063/5.0106617", "DOI Link": "http://dx.doi.org/10.1063/5.0106617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000861198300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jourdain, A; Asbai, R; Omaima, A; Chehimi, MM; Drockenmuller, E; Montarnal, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jourdain, Antoine; Asbai, Rawnaq; Omaima, Anaya; Chehimi, Mohamed M.; Drockenmuller, Eric; Montarnal, Damien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rheological Properties of Covalent Adaptable Networks with 1,2,3-Triazolium Cross-Links: The Missing Link between Vitrimers and Dissociative Networks", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vitrimers, in stringent contrast to dissociative networks, involve associative covalent exchanges and remain fully cross-linked at all temperatures. However, we have previously reported on poly(1,2,3-triazolium) dynamic networks that exhibit linear rheological characterization indistinguishable from vitrimers although being based on a dissociative covalent exchange process, i.e., de-N-alkylation and re-N-alkylation reactions. Herein, we highlight the main features of dissociative and associative covalent adaptable networks (CANs) and discuss their respective linear rheological behaviors. After giving a detailed overview of the extent and potential of dynamic polymer networks having 1,2,3-triazolium cross-links in particular and CANs involving trans-N-alkylation exchanges in general, we perform a detailed rheological comparative characterization of previously described aliphatic 1,2,3-triazolium-based dynamic networks and a new bicomponent thermosetting system issued from the mixing of linear polystyrene chains having complementary benzyl iodide and 1,2,3-triazole pendent groups. We propose a simple but comprehensive rheological characterization methodology that enables proper comparison between all types of CANs, i.e., vitrimers and dissociative networks. Owing to the combination of a high glass transition temperature dynamic network and fast trans-N-alkylation exchanges in this new dissociative network, it is possible to characterize both glass transition and network relaxation with single rheological experiments. We provide clear experimental evidence that although located within a narrow temperature range, the temperature dependences of these two transitions are distinct and follow WLF and Arrhenius models, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2020, "Volume": 53, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1884, "End Page": 1900, "Article Number": null, "DOI": "10.1021/acs.macromol.9b02204", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.9b02204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000526395700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, J; Jeong, C; Batagoda, T; Coburn, C; Thompson, ME; Forrest, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jaesang; Jeong, Changyeong; Batagoda, Thilini; Coburn, Caleb; Thompson, Mark E.; Forrest, Stephen R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hot excited state management for long-lived blue phosphorescent organic light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since their introduction over 15 years ago, the operational lifetime of blue phosphorescent organic light-emitting diodes (PHOLEDs) has remained insufficient for their practical use in displays and lighting. Their short lifetime results from annihilation between high-energy excited states, producing energetically hot states (46.0 eV) that lead to molecular dissociation. Here we introduce a strategy to avoid dissociative reactions by including a molecular hot excited state manager within the device emission layer. Hot excited states transfer to the manager and rapidly thermalize before damage is induced on the dopant or host. As a consequence, the managed blue PHOLED attains T80 = 334 +/- 5 h (time to 80% of the 1,000 cdm(-2) initial luminullce) with a chromaticity coordinate of (0.16, 0.31), corresponding to 3.6 +/- 0.1 times improvement in a lifetime compared to conventional, unmanaged devices. To our knowledge, this significant improvement results in the longest lifetime for such a blue PHOLED.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/ncomms15566", "DOI Link": "http://dx.doi.org/10.1038/ncomms15566", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402390700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, JH; Liu, XB; Li, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Jianhua; Liu, Xingbo; Li, Bingyun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capacity Fade Analysis of Sulfur Cathodes in Lithium-Sulfur Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium-sulfur (Li-S) batteries are receiving ever-increasing attention due to their high theoretical energy density and inexpensive raw sulfur materials. However, their rapid capacity fade has been one of the key barriers for their further improvement. It is well accepted that the major degradation mechanisms of S-cathodes include low electrical conductivity of S and sulfides, precipitation of nonconductive Li2S2 and Li2S, and poly-shuttle effects. To determine these degradation factors, a comprehensive study of sulfur cathodes with different amounts of electrolytes is presented here. A survey of the fundamentals of Li-S chemistry with respect to capacity fade is first conducted; then, the parameters obtained through electrochemical performance and characterization are used to determine the key causes of capacity fade in Li-S batteries. It is confirmed that the formation and accumulation of nonconductive Li2S2/Li2S films on sulfur cathode surfaces are the major parameters contributing to the rapid capacity fade of Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600101, "DOI": "10.1002/advs.201600101", "DOI Link": "http://dx.doi.org/10.1002/advs.201600101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390399000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cora, I; Mezzadri, F; Boschi, F; Bosi, M; Caplovicová, M; Calestani, G; Dódony, I; Pécz, B; Fornari, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cora, Ildiko; Mezzadri, Francesco; Boschi, Francesco; Bosi, Matteo; Caplovicova, Maria; Calestani, Gianluca; Dodony, Istvan; Pecz, Bela; Fornari, Roberto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The real structure of ε-Ga2O3 and its relation to κ-phase", "Source Title": "CRYSTENGCOMM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A comprehensive study by high-resolution transmission electron microscopy (TEM) and X-ray diffraction (XRD) was carried out on Ga2O3 epilayers grown at low temperature (650 degrees C) by vapor phase epitaxy in order to investigate the real structure at the nulloscale. Initial XRD measurements showed that the films were of the so-called epsilon phase; i.e. they exhibited hexagonal P6(3)mc space group symmetry, characterized by disordered and partial occupation of the Ga sites. This work clarifies the crystal structure of Ga2O(3) layers deposited at low temperature at the nulloscale: TEM investigation demonstrates that the Ga atoms and vacancies are not randomly distributed, but actually possess ordering, with (110)-twinned domains of 5-10 nm size. Each domain has orthorhombic structure with Pna2(1) space group symmetry, referred to as kappa-Ga2O3. Further XRD analysis carried out on thicker samples (9-10 mu m) confirmed this finding and provided refined structural parameters. The six (110)-type twinned ordered domains together - if the domain size falls below the actual resolution of the probing techniques - can be misinterpreted as the disordered structure with its P6(3)mc space group symmetry usually referred to as epsilon-Ga2O3 in the current literature. The crystal structure of these Ga2O3 layers consists of an ABAC oxygen close-packed stacking, where Ga atoms occupy octahedral and tetrahedral sites in between, forming two types of polyhedral layers parallel to (001). The edge-sharing octahedra and the corner-sharing tetrahedra form zig-zag ribbons along the [100] direction. Anti-phase boundaries are common inside the domains. The polar character of the structure is confirmed, in agreement with the characteristics of the Pna2(1) space group and previous observations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 257, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2017, "Volume": 19, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1509, "End Page": 1516, "Article Number": null, "DOI": "10.1039/c7ce00123a", "DOI Link": "http://dx.doi.org/10.1039/c7ce00123a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Crystallography", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397741500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giese, B; Klaessig, F; Park, B; Kaegi, R; Steinfeldt, M; Wigger, H; von Gleich, A; Gottschalk, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giese, Bernd; Klaessig, Fred; Park, Barry; Kaegi, Ralf; Steinfeldt, Michael; Wigger, Henning; von Gleich, Arnim; Gottschalk, Fadri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Risks, Release and Concentrations of Engineered nullomaterial in the Environment", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For frequently used engineered nullomaterials (ENMs) CeO2-, SiO2-, and Ag, past, current, and future use and environmental release are investigated. Considering an extended period (1950 to 2050), we assess ENMs released through commercial activity as well as found in natural and technical settings. Temporal dynamics, including shifts in release due to ENM product application, stock (delayed use), and subsequent end-of-life product treatment were taken into account. We distinguish predicted concentrations originating in ENM use phase and those originating from end-of-life release. Furthermore, we compare Ag- and CeO2-ENM predictions with existing measurements. The correlations and limitations of the model, and the analytic validity of our approach are discussed in the context of massive use of assumptive model data and high uncertainty on the colloidal material captured by the measurements. Predictions for freshwater CeO2-ENMs range from 1 pg/l (2017) to a few hundred ng/l (2050). Relative to CeO2, the SiO2-ENMs estimates are approximately 1,000 times higher, and those for Ag-ENMs 10 times lower. For most environmental compartments, ENM pose relatively low risk; however, organisms residing near ENM 'point sources' (e.g., production plant outfalls and waste treatment plants), which are not considered in the present work, may be at increased risk.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1565, "DOI": "10.1038/s41598-018-19275-4", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-19275-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423422000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "MacLeod, BP; Parlane, FGL; Morrissey, TD; Häse, F; Roch, LM; Dettelbach, KE; Moreira, R; Yunker, LPE; Rooney, MB; Deeth, JR; Lai, V; Ng, GJ; Situ, H; Zhang, RH; Elliott, MS; Haley, TH; Dvorak, DJ; Aspuru-Guzik, A; Hein, JE; Berlinguette, CP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "MacLeod, B. P.; Parlane, F. G. L.; Morrissey, T. D.; Hase, F.; Roch, L. M.; Dettelbach, K. E.; Moreira, R.; Yunker, L. P. E.; Rooney, M. B.; Deeth, J. R.; Lai, V; Ng, G. J.; Situ, H.; Zhang, R. H.; Elliott, M. S.; Haley, T. H.; Dvorak, D. J.; Aspuru-Guzik, A.; Hein, J. E.; Berlinguette, C. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-driving laboratory for accelerated discovery of thin-film materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discovering and optimizing commercially viable materials for clean energy applications typically takes more than a decade. Self-driving laboratories that iteratively design, execute, and learn from materials science experiments in a fully autonomous loop present an opportunity to accelerate this research process. We report here a modular robotic platform driven by a model-based optimization algorithm capable of autonomously optimizing the optical and electronic properties of thin-film materials by modifying the film composition and processing conditions. We demonstrate the power of this platform by using it to maximize the hole mobility of organic hole transport materials commonly used in perovskite solar cells and consumer electronics. This demonstration highlights the possibilities of using autonomous laboratories to discover organic and inorganic materials relevant to materials sciences and clean energy technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 6, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaz8867", "DOI": "10.1126/sciadv.aaz8867", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaz8867", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533573300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Go, D; Jo, D; Kim, C; Lee, HW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Go, Dongwook; Jo, Daegeun; Kim, Changyoung; Lee, Hyun-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Spin and Orbital Hall Effects from Orbital Texture", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show theoretically that both the intrinsic spin Hall effect (SHE) and orbital Hall effect (OHE) can arise in centrosymmetric systems through momentum-space orbital texture, which is ubiquitous even in centrosymmetric systems unlike spin texture. The OHE occurs even without spin-orbit coupling (SOC) and is converted into the SHE through SOC. The resulting spin Hall conductivity is large (comparable to that of Pt) but depends on the SOC strength in a nonmonotonic way. This mechanism is stable against orbital quenching. This work suggests a path for an ongoing search for materials with stronger SHE. It also calls for experimental efforts to probe orbital degrees of freedom in the OHE and SHE. Possible ways for experimental detection are briefly discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2018, "Volume": 121, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86602, "DOI": "10.1103/PhysRevLett.121.086602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.086602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442675400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koumpouras, K; Larsson, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koumpouras, Konstantinos; Larsson, J. Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Distinguishing between chemical bonding and physical binding using electron localization function (ELF)", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To distinguish between chemical bonding and physical binding is usually simple. They differ, in the normal case, in both interaction strength (binding energy) and interaction length (structure). However, chemical bonding can be weak (e.g. in some metallic bonding) and physical binding can be strong (e.g. due to permanent electrostatic moments, hydrogen binding, etc) making differentiation non-trivial. But since these are shared-electron or unshared-electron interactions, respectively, it is in principle possible to distinguish the type of interaction by analyzing the electron density around the interaction point(s)/interface. After all, the former should be a contact while the latter should be a tunneling barrier. Here, we investigate within the framework of density functional theory typical molecules and crystals to show the behaviour of the electron localization function (ELF) in different shared-electron interactions, such as chemical (covalent) and metallic bonding and compare to unshared-electron interactions typical for physical binding, such as ionic, hydrogen and Keesom, dispersion (van der Waals) binding and attempt to categorise them only by the ELF and the electron population in the interaction region. It is found that the ELF method is not only useful for the characterization of covalent bonds but a lot of information can be extracted also for weaker types of binding. Furthermore, the charge integration over the interaction region(s) and tracing the ELF profile can reveal the strength of the bonding/binding ranging from the triple bonds to weak dispersion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2020, "Volume": 32, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 315502, "DOI": "10.1088/1361-648X/ab7fd8", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ab7fd8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533865000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, XY; Hu, MM; Deetman, S; Steubing, B; Lin, HX; Hernulldez, GA; Harpprecht, C; Zhang, CB; Tukker, A; Behrens, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Xiaoyang; Hu, Mingming; Deetman, Sebastiaan; Steubing, Bernhard; Lin, Hai Xiang; Hernulldez, Glenn Aguilar; Harpprecht, Carina; Zhang, Chunbo; Tukker, Arnold; Behrens, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global greenhouse gas emissions from residential and commercial building materials and mitigation strategies to 2060", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Building stock growth around the world drives extensive material consumption and environmental impacts. Future impacts will be dependent on the level and rate of socioeconomic development, along with material use and supply strategies. Here we evaluate material-related greenhouse gas (GHG) emissions for residential and commercial buildings along with their reduction potentials in 26 global regions by 2060. For a middle-of-the-road baseline scenario, building material-related emissions see an increase of 3.5 to 4.6 Gt CO2eq yr-1 between 2020-2060. Low- and lower-middle-income regions see rapid emission increase from 750 Mt (22% globally) in 2020 and 2.4 Gt (51%) in 2060, while higher-income regions shrink in both absolute and relative terms. Implementing several material efficiency strategies together in a High Efficiency (HE) scenario could almost half the baseline emissions. Yet, even in this scenario, the building material sector would require double its current proportional share of emissions to meet a 1.5 degrees C-compatible target. Building construction causes large material-related emissions which present a serious decarbonization challenge. Here, the authors show that the building material sector could halve emissions by increasing efficiency until 2060 but even then its emissions would be twice as high as needed to meet the 1.5 degrees C target.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6126, "DOI": "10.1038/s41467-021-26212-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26212-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000710514300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Luo, RY; Zhang, W; Jin, MM; Tang, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Luo, Ruyi; Zhang, Wei; Jin, Minmin; Tang, Shengwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "EFFECTS OF FINENESS AND CONTENT OF PHOSPHORUS SLAG ON CEMENT HYDRATION, PERMEABILITY, PORE STRUCTURE AND FRACTAL DIMENSION OF CONCRETE", "Source Title": "FRACTALS-COMPLEX GEOMETRY PATTERNS AND SCALING IN NATURE AND SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The utilization of phosphorus slag (PHS) to replace the fly ash in the construction of hydraulic projects has attracted a growing attention in China. In this study, the influence of PHS fineness and content on cement hydration, mechanical strength, permeability as well as the pore structure and fractal dimension (Ds) of concrete have been discussed. The results indicate that the PHS addition retards the cement hydration and hence decreases the hydration heat within three days. The incorporation of PHS with a Blaine specific surface area of 505m(2)/kg could participate in the early pozzolanic reaction and consequently offsets the retarding effect to some extent. The incorporation of 20-40wt.% PHS declines the early strength of concrete, but this reduction effect on strength can be eliminated to some degrees by mechanically grinding the PHS. The compressive strengths of concrete added with PHS with a high fineness of 505m(2)/kg (abbreviated as PHS-H) are about 16.0-20.6% higher at three days and 8.9-11.0% higher at 180 days compared that of the control concrete. The contribution of PHS-H to the pore structure refinement is more significant than that of PHS with a low fineness of 302m(2)/kg (abbreviated as PHS-L) at various ages because PHS-H is of much higher reactivity and can consume more Ca(OH)(2) than PHS-L which leads to a denser microstructure and a lower chloride diffusion coefficient (DRCM). The incorporation of PHS decreases the Ds at three days, whereas the concrete incorporated with PHS has much higher Ds than that of control one at late age. The DRCM value increases with increasing the porosity and the most probable aperture, while Ds has a more significant effect on DRCM than the porosity and the most probable aperture. The concrete added with 20wt.% PHS-H exhibits the highest Ds and the lowest DRCM value at long-term age among the five concrete mixtures in this work.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 29, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2140004, "DOI": "10.1142/S0218348X21400041", "DOI Link": "http://dx.doi.org/10.1142/S0218348X21400041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641993400024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, QP; An, QS; Lin, YB; Xia, YX; Li, Q; Zhang, M; Su, WY; Peng, WH; Zhang, CF; Liu, F; Hou, LT; Zhu, WG; Yu, DH; Xiao, M; Moons, E; Zhang, FJ; Anthopoulos, TD; Inganäs, O; Wang, EG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Qunping; An, Qiaoshi; Lin, Yuanbao; Xia, Yuxin; Li, Qian; Zhang, Ming; Su, Wenyan; Peng, Wenhong; Zhang, Chunfeng; Liu, Feng; Hou, Lintao; Zhu, Weiguo; Yu, Donghong; Xiao, Min; Moons, Ellen; Zhang, Fujun; Anthopoulos, Thomas D.; Inganas, Olle; Wang, Ergang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Obtaining both high open-circuit voltage (V-oc) and short-circuit current density (J(sc)) has been a major challenge for efficient all-polymer solar cells (all-PSCs). Herein, we developed a polymer acceptor PF5-Y5 with excellent optical absorption capability (onset extending to similar to 880 nm and maximum absorption coefficient exceeding 105 cm(-1) in a film), high electron mobility (3.18 x 10(3) cm(2) V-1 s(-1)) and high LUMO level (-3.84 eV) to address such a challenge. As a result, the PBDB-T:PF5-Y5-based all-PSCs achieved a high power conversion efficiency of up to 14.45% with both a high Voc (0.946 V) and a high Jsc (20.65 mA cm(-2)), due to the high and broad absorption coverage, small energy loss (0.57 eV) and efficient charge separation and transport in the device, which are among the best values in the all-PSC field. In addition, the all-PSC shows a similar to 15% improvement in PCE compared to its counterpart small molecule acceptor (Y5)-based device. Our results suggest that PF5-Y5 is a very promising polymer acceptor candidate for applications in efficient all-PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2020, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5017, "End Page": 5027, "Article Number": null, "DOI": "10.1039/d0ee01828g", "DOI Link": "http://dx.doi.org/10.1039/d0ee01828g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599751100029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, X; Korblova, E; Dong, DP; Wei, XY; Shao, RF; Radzihovsky, L; Glaser, MA; Maclennull, JE; Bedrov, D; Walba, DM; Clark, NA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xi; Korblova, Eva; Dong, Dengpan; Wei, Xiaoyu; Shao, Renfan; Radzihovsky, Leo; Glaser, Matthew A.; Maclennull, Joseph E.; Bedrov, Dmitry; Walba, David M.; Clark, Noel A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First -principles experimental demonstration of ferroelectricity in a thermotropic nematic liquid crystal: Polar domains and striking electro-optics", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate (RM734). We exploit its electro-optics to visualize the appearance, in the absence of applied field, of a permanent electric polarization density, manifested as a spontaneously broken symmetry in distinct domains of opposite polar orientation. Polarization reversal is mediated by field-induced domain wall movement, making this phase ferroelectric, a 3D uniaxial nematic having a spontaneous, reorientable polarization locally parallel to the director. This polarization density saturates at a low temperature value of similar to 6 mu C/cm2, the largest ever measured for a fluid or glassy material. This polarization is comparable to that of solid state ferroelectrics and is close to the average value obtained by assuming perfect, polar alignment of molecular dipoles in the nematic. We find a host of spectacular optical and hydrodynamic effects driven by ultralow applied field (E similar to 1 V/cm), produced by the coupling of the large polarization to nematic birefringence and flow. Electrostatic selfinteraction of the polarization charge renders the transition from the nematic phase mean field-like and weakly first order and controls the director field structure of the ferroelectric phase. Atomistic molecular dynamics simulation reveals short-range polar molecular interactions that favor ferroelectric ordering, including a tendency for head-to-tail association into polar, chain-like assemblies having polar lateral correlations. These results indicate a significant potential for transformative, new nematic physics, chemistry, and applications based on the enhanced understanding, development, and exploitation of molecular electrostatic interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2020, "Volume": 117, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14021, "End Page": 14031, "Article Number": null, "DOI": "10.1073/pnas.2002290117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2002290117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546772500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peano, V; Brendel, C; Schmidt, M; Marquardt, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peano, V.; Brendel, C.; Schmidt, M.; Marquardt, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Phases of Sound and Light", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological states of matter are particularly robust, since they exploit global features of a material's band structure. Topological states have already been observed for electrons, atoms, and photons. It is an outstanding challenge to create a Chern insulator of sound waves in the solid state. In this work, we propose an implementation based on cavity optomechanics in a photonic crystal. The topological properties of the sound waves can be wholly tuned in situ by adjusting the amplitude and frequency of a driving laser that controls the optomechanical interaction between light and sound. The resulting chiral, topologically protected phonon transport can be probed completely optically. Moreover, we identify a regime of strong mixing between photon and phonon excitations, which gives rise to a large set of different topological phases and offers an example of a Chern insulator produced from the interaction between two physically distinct particle species, photons and phonons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31011, "DOI": "10.1103/PhysRevX.5.031011", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.031011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358607800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, JK; Nakamoto, Y; Zhang, PY; Shimizu, K; Zou, B; Liu, HY; Zhou, M; Liu, GT; Wang, HB; Ma, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Jingkai; Nakamoto, Yuki; Zhang, Peiyu; Shimizu, Katsuya; Zou, Bo; Liu, Hanyu; Zhou, Mi; Liu, Guangtao; Wang, Hongbo; Ma, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant enhancement of superconducting critical temperature in substitutional alloy (La,Ce)H9", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A sharp focus of current research on superconducting superhydrides is to raise their critical temperature T-c at moderate pressures. Here, we report a discovery of giant enhancement of T-c in CeH9 obtained via random substitution of half Ce by La, leading to equal-atomic (La,Ce)H-9 alloy stabilized by maximum configurational entropy, containing the LaH9 unit that is unstable in pure compound form. The synthesized (La,Ce)H-9 alloy exhibits T-c of 148-178 K in the pressure range of 97-172 GPa, representing up to 80% enhancement of T-c compared to pure CeH9 and showcasing the highest T-c at sub-megabar pressure among the known superhydrides. This work demonstrates substitutional alloying as a highly effective enabling tool for substantially enhancing T-c via atypical compositional modulation inside suitably selected host crystal. This optimal substitutional alloying approach opens a promising avenue for synthesis of high-entropy multinary superhydrides that may exhibit further increased T-c at even lower pressures. Superconductivity was recently discovered in the clathrate hydride CeH9 with superconducting temperature (T-c) of 57 K at pressures below 1 megabar. Here, the authors show that T-c can be increased to 148 K in the substitutional alloy (La,Ce)H-9, while maintaining a pressure below 1 megabar.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5952, "DOI": "10.1038/s41467-022-33743-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33743-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867457000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Woodard, LN; Grunlan, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Woodard, Lindsay N.; Grunlan, Melissa A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrolytic Degradation and Erosion of Polyester Biomaterials", "Source Title": "ACS MACRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strategies to refine the degradation behavior of polyester biomaterials, particularly to overcome the limitations of slow hydrolytic degradation, would broaden their utility. Herein, we examine the complexities of polyester degradation behavior, its assessment, and strategies for refinement. The factors governing polyester degradation are strikingly complex. In addition to the half-life of the hydrolytically labile bond, a series of interdependent material properties must be considered. Thus, methods used to characterize such material properties, both before and during degradation, must be carefully selected. Assessment of degradation behavior is further complicated by the variability of reported test protocols and the need for accelerated rather than real-time in vitro testing conditions. Ultimately, through better control of degradation behavior and correlation of in vitro, simulated degradation to that observed in vivo, the development of superior devices prepared with polyester biomaterials may be achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 299, "Times Cited, All Databases": 336, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 976, "End Page": 982, "Article Number": null, "DOI": "10.1021/acsmacrolett.8b00424", "DOI Link": "http://dx.doi.org/10.1021/acsmacrolett.8b00424", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444659000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghasemi, H; Park, HS; Rabczuk, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghasemi, Hamid; Park, Harold S.; Rabczuk, Timon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A multi-material level set-based topology optimization of flexoelectric composites", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a computational design methodology for topology optimization of multi-material-based flexoelectric composites. The methodology extends our recently proposed design methodology for a single flexoelectric material. We adopt the multiphase vector level set (LS) model which easily copes with various numbers of phases, efficiently satisfies multiple constraints and intrinsically avoids overlap or vacuum among different phases. We extend the point wise density mapping technique for multi-material design and use the B-spline elements to discretize the partial differential equations (PDEs) of flexoelectricity. The dependence of the objective function on the design variables is incorporated using the adjoint technique. The obtained design sensitivities are used in the Hamilton-Jacobi (H-J) equation to update the LS function. We provide numerical examples for two, three and four phase flexoelectric composites to demonstrate the flexibility of the model as well as the significant enhancement in electromechanical coupling coefficient that can be obtained using multi-material topology optimization for flexoelectric composites (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2018, "Volume": 332, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 47, "End Page": 62, "Article Number": null, "DOI": "10.1016/j.cma.2017.12.005", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2017.12.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425738900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, H; Liu, RP; Li, YT; Lü, XJ; Wang, Q; Zhao, SQ; Yuan, KJ; Cui, ZM; Li, X; Xin, S; Zhang, R; Lei, M; Lin, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hao; Liu, Ruiping; Li, Yutao; Lu, Xujie; Wang, Qi; Zhao, Shiqiang; Yuan, Kunjie; Cui, Zhiming; Li, Xiang; Xin, Sen; Zhang, Ru; Lei, Ming; Lin, Zhiqun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Durable and Efficient Hollow Porous Oxide Spinel Microspheres for Oxygen Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxide catalysts with high oxygen reduction activity and durability are highly desirable for use in fuel cells and metal-air batteries. Herein we report, for the first time, the oxygen reduction activity of hollow porous spinel AB(2)O(4) microspheres, where A = Zn2+ and B = Mn3+ and/or Co3+ (i.e., ZnMnxCo2-xO4). Among them, ZnMnCoO4 (x = 1) microspheres exhibit the best oxygen reduction activity with a half-wave-potential only 50 mV lower than that of the Pt/C counterpart and an excellent durability in the alkaline solution. Importantly, the electronic transition of Co3+ ions from low-spin state in commercial Co3O4 catalyst to a mixed high-spin and low-spin state in ZnMnCoO4 catalyst was found to weaken the Co3+-OH bond and facilitate the O-2(-)/OH- displacement. The density functional theory calculation substantiated that ZnMnCoO 4 displayed a more favorable binding energy with O-2 and oxygenated species, thereby enabling the fast reaction kinetics in the oxygen reduction reaction process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 337, "End Page": 348, "Article Number": null, "DOI": "10.1016/j.joule.2017.11.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.11.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435090900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "von der Assen, N; Bardow, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "von der Assen, Niklas; Bardow, Andre", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Life cycle assessment of polyols for polyurethane production using CO2 as feedstock: insights from an industrial case study", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyethercarbonate polyols from carbon dioxide (CO2) are starting to be synthesized on industrial scale. These polyols can be further processed into polyurethanes enabling CO2 to be utilized in large amounts. Utilization of CO2 as alternative carbon feedstock for polyols is motivated from the potential to reduce greenhouse gas (GHG) emissions and fossil resource depletion. This article presents a life cycle assessment for production of CO2-based polyethercarbonate polyols in a real industrial pilot plant. The considered cradle-to-gate system boundaries include polyol production and all upstream processes such as provision of energy and feedstocks. In particular, provision of CO2 from a lignite power plant equipped with a pilot plant for CO2 capture is considered. Production of polyols with 20 wt% CO2 in the polymer chains causes GHG emissions of 2.65-2.86 kg CO2-eq kg(-1) and thus, does not act as GHG sink. However, compared to production of conventional polyether polyols, production of polyols with 20 wt% CO2 allows for GHG reductions of 11-19%. Relating GHG emission reductions to the amount of CO2 incorporated, up to three kg CO2-eq emissions can be avoided per kg CO2 utilized. The use of fossil resources can be reduced by 13-16%. The impacts reductions increase with further increasing the CO2 content in the polyols. All other investigated environmental impacts such as eutrophication, ionizing radiation, ozone depletion, particulate matter formation, photochemical oxidant formation, and terrestrial acidification are also lowered. Therefore, synthesis of polyethercarbonate polyols from CO2 is clearly favorable compared to conventional polyether polyols from an environmental point of view.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3272, "End Page": 3280, "Article Number": null, "DOI": "10.1039/c4gc00513a", "DOI Link": "http://dx.doi.org/10.1039/c4gc00513a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336836100042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YX; Huang, XH; Ding, K; Sheriff, HKM; Ye, L; Liu, HR; Li, CZ; Ade, H; Forrest, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yongxi; Huang, Xiaheng; Ding, Kan; Sheriff, Hafiz K. M., Jr.; Ye, Long; Liu, Haoran; Li, Chang-Zhi; Ade, Harald; Forrest, Stephen R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-fullerene acceptor organic photovoltaics with intrinsic operational lifetimes over 30 years", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic photovoltaic cells (OPVs) have the potential of becoming a productive renewable energy technology if the requirements of low cost, high efficiency and prolonged lifetime are simultaneously fulfilled. So far, the remaining unfulfilled promise of this technology is its inadequate operational lifetime. Here, we demonstrate that the instability of NFA solar cells arises primarily from chemical changes at organic/inorganic interfaces bounding the bulk heterojunction active region. Encapsulated devices stabilized by additional protective buffer layers as well as the integration of a simple solution processed ultraviolet filtering layer, maintain 94% of their initial efficiency under simulated, 1 sun intensity, AM1.5 G irradiation for 1900 hours at 55 degrees C. Accelerated aging is also induced by exposure of light illumination intensities up to 27 suns, and operation temperatures as high as 65 degrees C. An extrapolated intrinsic lifetime of > 5.6 x 10(4) h is obtained, which is equivalent to 30 years outdoor exposure. Through development of non-fullerene acceptors, OPVs have reached efficiencies of 18%, yet the inadequate operational lifetime still poses a challenge for the commercialisation. Here, the authors investigate the origin of instability of NFA solar cells, and propose some strategies to mitigate this issue.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5419, "DOI": "10.1038/s41467-021-25718-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-25718-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696024700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Osada, A; Hisatomi, R; Noguchi, A; Tabuchi, Y; Yamazaki, R; Usami, K; Sadgrove, M; Yalla, R; Nomura, M; Nakamura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Osada, A.; Hisatomi, R.; Noguchi, A.; Tabuchi, Y.; Yamazaki, R.; Usami, K.; Sadgrove, M.; Yalla, R.; Nomura, M.; Nakamura, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cavity Optomagnonics with Spin-Orbit Coupled Photons", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We experimentally implement a system of cavity optomagnonics, where a sphere of ferromagnetic material supports whispering gallery modes (WGMs) for photons and the magnetostatic mode for magnons. We observe pronounced nonreciprocity and asymmetry in the sideband signals generated by the magnon-induced Brillouin scattering of light. The spin-orbit coupled nature of the WGM photons, their geometrical birefringence, and the time-reversal symmetry breaking in the magnon dynamics impose the angular-momentum selection rules in the scattering process and account for the observed phenomena. The unique features of the system may find interesting applications at the crossroad between quantum optics and spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 341, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2016, "Volume": 116, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 223601, "DOI": "10.1103/PhysRevLett.116.223601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.223601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377018100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jain, A; Ong, SP; Chen, W; Medasani, B; Qu, XH; Kocher, M; Brafman, M; Petretto, G; Rignullese, GM; Hautier, G; Gunter, D; Persson, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jain, Anubhav; Ong, Shyue Ping; Chen, Wei; Medasani, Bharat; Qu, Xiaohui; Kocher, Michael; Brafman, Miriam; Petretto, Guido; Rignullese, Gian-Marco; Hautier, Geoffroy; Gunter, Daniel; Persson, Kristin A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FireWorks: a dynamic workflow system designed for high-throughput applications", "Source Title": "CONCURRENCY AND COMPUTATION-PRACTICE & EXPERIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper introduces FireWorks, a workflow software for running high-throughput calculation workflows at supercomputing centers. FireWorks has been used to complete over 50 million CPU-hours worth of computational chemistry and materials science calculations at the National Energy Research Supercomputing Center. It has been designed to serve the demanding high-throughput computing needs of these applications, with extensive support for (i) concurrent execution through job packing, (ii) failure detection and correction, (iii) provenullce and reporting for long-running projects, (iv) automated duplicate detection, and (v) dynamic workflows (i.e., modifying the workflow graph during runtime). We have found that these features are highly relevant to enabling modern data-driven and high-throughput science applications, and we discuss our implementation strategy that rests on Python and NoSQL databases (MongoDB). Finally, we present performance data and limitations of our approach along with planned future work. Copyright (c) 2015 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2015, "Volume": 27, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5037, "End Page": 5059, "Article Number": null, "DOI": "10.1002/cpe.3505", "DOI Link": "http://dx.doi.org/10.1002/cpe.3505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363766600027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, DH; Ringe, S; Kim, H; Kim, S; Kim, B; Bae, G; Oh, HS; Jaouen, F; Kim, W; Kim, H; Choi, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Dong Hyun; Ringe, Stefan; Kim, Haesol; Kim, Sejun; Kim, Bupmo; Bae, Geunsu; Oh, Hyung-Suk; Jaouen, Frederic; Kim, Wooyul; Kim, Hyungjun; Choi, Chang Hyuck", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective electrochemical reduction of nitric oxide to hydroxylamine by atomically dispersed iron catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic conversion of nitrogen oxides to value-added chemicals is a promising strategy for mitigating the human-caused unbalance of the global nitrogen-cycle, but controlling product selectivity remains a great challenge. Here we show iron-nitrogen-doped carbon as an efficient and durable electrocatalyst for selective nitric oxide reduction into hydroxylamine. Using in operando spectroscopic techniques, the catalytic site is identified as isolated ferrous moieties, at which the rate for hydroxylamine production increases in a super-Nernstian way upon pH decrease. Computational multiscale modelling attributes the origin of unconventional pH dependence to the redox active (non-innocent) property of NO. This makes the rate-limiting NO adsorbate state more sensitive to surface charge which varies with the pH-dependent overpotential. Guided by these fundamental insights, we achieve a Faradaic efficiency of 71% and an unprecedented production rate of 215 mu molcm(-2) h(-1) at a short-circuit mode in a flow-type fuel cell without significant catalytic deactivation over 50 h operation. Electrocatalytic conversion of nitrogen oxides to value-added chemicals is a promising strategy for mitigating the imbalance in the global nitrogen cycle. Here, the authors present iron-nitrogen-doped carbon as an efficient and durable electrocatalyst for selective nitric oxide reduction to hydroxylamine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1856, "DOI": "10.1038/s41467-021-22147-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22147-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637989400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SX; Hu, YZ; Li, A; Lin, JH; Hsieh, KW; Schneiderman, Z; Zhang, PF; Zhu, YN; Qiu, CH; Kokkoli, E; Wang, TH; Mao, HQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Sixuan; Hu, Yizong; Li, Andrew; Lin, Jinghan; Hsieh, Kuangwen; Schneiderman, Zachary; Zhang, Pengfei; Zhu, Yining; Qiu, Chenhu; Kokkoli, Efrosini; Wang, Tza-Huei; Mao, Hai-Quan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Payload distribution and capacity of mRNA lipid nulloparticles", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lipid nulloparticles (LNPs) are effective vehicles to deliver mRNA vaccines and therapeutics but assessing the mRNA packaging characteristics in LNPs is challenging. Here, the authors report that mRNA and lipid contents in LNP formulations can be quantitatively examined by multi-laser cylindrical illumination confocal spectroscopy at the single-nulloparticle level. Lipid nulloparticles (LNPs) are effective vehicles to deliver mRNA vaccines and therapeutics. It has been challenging to assess mRNA packaging characteristics in LNPs, including payload distribution and capacity, which are critical to understanding structure-property-function relationships for further carrier development. Here, we report a method based on the multi-laser cylindrical illumination confocal spectroscopy (CICS) technique to examine mRNA and lipid contents in LNP formulations at the single-nulloparticle level. By differentiating unencapsulated mRNAs, empty LNPs and mRNA-loaded LNPs via coincidence analysis of fluorescent tags on different LNP components, and quantitatively resolving single-mRNA fluorescence, we reveal that a commonly referenced benchmark formulation using DLin-MC3 as the ionizable lipid contains mostly 2 mRNAs per loaded LNP with a presence of 40%-80% empty LNPs depending on the assembly conditions. Systematic analysis of different formulations with control variables reveals a kinetically controlled assembly mechanism that governs the payload distribution and capacity in LNPs. These results form the foundation for a holistic understanding of the molecular assembly of mRNA LNPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5561, "DOI": "10.1038/s41467-022-33157-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33157-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000857704600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abate, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abate, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite Solar Cells Go Lead Free", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Halide perovskites are one of the most promising materials for delivery of the next generation of solar cells. Perovskite solar cells have enabled power conversion efficiency comparable with established technologies, such as silicon and cadmium telluride. Their stability is constantly improving and it is not difficult to believe that stability will soon reach the market requirements. There remains amain concern about the toxicity of lead, a constituent of all the better performing perovskite solar cells so far demonstrated. Here, we discuss the environmental and toxicological implications of lead, paying particular attention to the existing regulations. Both regulation and common sense suggest that perovskite solar cells have to become lead free to deliver a sustainable technology. Thus, we provide a critical overview of the current research and an outlook of the paths toward lead- free perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2017, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 659, "End Page": 664, "Article Number": null, "DOI": "10.1016/j.joule.2017.09.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.09.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425302500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Beaucamp, A; Muddasar, M; Crawford, T; Collins, MN; Culebras, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Beaucamp, Anne; Muddasar, Muhammad; Crawford, Tara; Collins, Maurice N.; Culebras, Mario", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainable lignin precursors for tailored porous carbon-based supercapacitor electrodes", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable materials are attracting a lot of attention since they will be critical in the creation of the next generation of products and devices. In this study, hydrogels were effectively synthesized utilizing lignin, a non -valorised biopolymer from the paper industry. This study proposes a method based on utilizing lignin to create highly swollen hydrogels using poly(ethylene) glycol diglycidyl ether (PEGDGE) as a crosslinking agent. The influence of different crosslinker ratios on the structural and chemical properties of the resultant hydrogels was investigated. Pore size was observed to be lowered when the amount of crosslinker was increased. The inclusion of additional hydrophilic groups in the hydrogel network decreased the swelling capacity of the hydrogels as the crosslinking density increases. These precursor materials were carbonised and electrochemically tested for application as electrodes for supercapacitors with capacitance characterized as a function of crosslinker ratio.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2022, "Volume": 221, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1142, "End Page": 1149, "Article Number": null, "DOI": "10.1016/j.ijbiomac.2022.09.097", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2022.09.097", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860652500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Donkers, PAJ; Sögütoglu, LC; Huinink, HP; Fischer, HR; Adan, OCG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Donkers, P. A. J.; Sogutoglu, L. C.; Huinink, H. P.; Fischer, H. R.; Adan, O. C. G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A review of salt hydrates for seasonal heat storage in domestic applications", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A literature review is performed in order to collect and analyse the thermodynamic data of an utmost number of salt hydrate reactions (i.e., 563 reactions are reviewed). These data allow us to evaluate the theoretical possibilities and limitations of salt hydrates as thermochemical materials (TCMs) for seasonal heat storage in the built environment (1 GJ/m(3) on system level). Two filters are used for evaluation. Filter 1 including three criteria i.e., an ideal hydration reaction with a capacity larger than 2 GJ/m(3), a hydration temperature of 65 degrees C (suitable for domestic hot water) or higher, a dehydration temperature below 100 degrees C to profit as much as possible from the solar heat that can be harvested. Only four of the studied hydrates fit with these demands. For selecting a larger number of hydrates, a second filter is introduced with less demanding constraints. It is expected that modifications on heat storage system level are needed to reach an.acceptable system performance with the hydrates selected through filter 2 (hydration reaction with a capacity larger than 1.3 GJ/m(3), a hydration temperature of 50 degrees C or higher, a dehydration temperature below 120 degrees C). Based on this filter, a shortlist of 25 TCM hydrate reactions are identified, including the four of filter 1. The shortlist is analyzed by considering price, chemical stability, reaction kinetics and safety for domestic environment. Based on this additional analysis with the used constraints, K2CO3 is determined to be the most promising candidate for open or closed systems, but has a low energy density. Based on the review of 563 hydrate reactions, we concluded that no ideal salt exists for seasonal heat storage under the considered boundary conditions. With the current concept of seasonal heat storage, including closed and open systems, whereby only one dehydration cycle per year is performed under a system energy density of 1 GJ/m(3), it is not realistic for large scale implementation to use pure salt hydrates as heat storage material. By adjusting the constraints, such as multiple cycles per year or higher water vapor pressures, salt hydrates can still be used as TCMs. It should be mentioned that MgSO4 center dot 7H(2)O, MgSO4 center dot 6H(2)O and CaCl2 center dot 6H(2)O are not listed in our shortlist of 25 TCMs, although these hydrates are commonly suggested in the literature as promising TCM for seasonal heat storage. The present study on pT-characteristics shows, however, that these salts are not fitting the demands of such a heat storage system. (C) 2017 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 199, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": 68, "Article Number": null, "DOI": "10.1016/j.apenergy.2017.04.080", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2017.04.080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403031800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faber, F; Lindmaa, A; von Lilienfeld, OA; Armiento, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faber, Felix; Lindmaa, Alexander; von Lilienfeld, O. Anatole; Armiento, Rickard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal structure representations for machine learning models of formation energies", "Source Title": "INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce and evaluate a set of feature vector representations of crystal structures for machine learning (ML) models of formation energies of solids. ML models of atomization energies of organic molecules have been successful using a Coulomb matrix representation of the molecule. We consider three ways to generalize such representations to periodic systems: (i) a matrix where each element is related to the Ewald sum of the electrostatic interaction between two different atoms in the unit cell repeated over the lattice; (ii) an extended Coulomb-like matrix that takes into account a number of neighboring unit cells; and (iii) an ansatz that mimics the periodicity and the basic features of the elements in the Ewald sum matrix using a sine function of the crystal coordinates of the atoms. The representations are compared for a Laplacian kernel with Manhattan norm, trained to reproduce formation energies using a dataset of 3938 crystal structures obtained from the Materials Project. For training sets consisting of 3000 crystals, the generalization error in predicting formation energies of new structures corresponds to (i) 0.49, (ii) 0.64, and (iii) 0.37eV/atom for the respective representations. (c) 2015 Wiley Periodicals, Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 404, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2015, "Volume": 115, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1094, "End Page": 1101, "Article Number": null, "DOI": "10.1002/qua.24917", "DOI Link": "http://dx.doi.org/10.1002/qua.24917", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Mathematics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357606000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, RX; Zhang, SJ; Gao, HR; Murugan, GS; Liu, TG; Cheng, ZZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Rongxiang; Zhang, Shujiao; Gao, Haoran; Murugan, Ganapathy Senthil; Liu, Tiegen; Cheng, Zhenzhou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blazed subwavelength grating coupler", "Source Title": "PHOTONICS RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Short-wavelength mid-infrared (2-2.5 & mu;m wave band) silicon photonics has been a growing area to boost the applications of integrated optoelectronics in free-space optical communications, laser ranging, and biochemical sensing. In this spectral region, multi-project wafer foundry services developed for the telecommunication band are easily adaptable with the low intrinsic optical absorption from silicon and silicon dioxide materials. However, light coupling techniques at 2-2.5 & mu;m wavelengths, namely, grating couplers, still suffer from low efficiencies, mainly due to the moderated directionality and poor diffraction-field tailoring capability. Here, we demonstrate a foundry-processed blazed subwavelength coupler for high-efficiency, wide-bandwidth, and large-tolerance light coupling. We subtly design multi-step-etched hybrid subwavelength grating structures to significantly im-prove directionality, as well as an apodized structure to tailor the coupling strength for improving the optical mode overlap and backreflection. Experimental results show that the grating coupler has a recorded coupling efficiency of -4.53 dB at a wavelength of 2336 nm with a 3-dB bandwidth of & SIM;107 nm. The study opens an avenue to developing state-of-the-art light coupling techniques for short-wavelength mid-infrared silicon photonics. & COPY; 2023 Chinese Laser Press", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2023, "Volume": 11, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 189, "End Page": 195, "Article Number": null, "DOI": "10.1364/PRJ.474199", "DOI Link": "http://dx.doi.org/10.1364/PRJ.474199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001045077300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YD; Yao, WL; Xin, ZM; Han, TT; Wang, ZG; Chen, L; Cai, C; Li, Y; Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Y. D.; Yao, W. L.; Xin, Z. M.; Han, T. T.; Wang, Z. G.; Chen, L.; Cai, C.; Li, Yuan; Zhang, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band insulator to Mott insulator transition in 1T-TaS2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "1T-TaS2 undergoes successive phase transitions upon cooling and eventually enters an insulating state of mysterious origin. Some consider this state to be a band insulator with interlayer stacking order, yet others attribute it to Mott physics that support a quantum spin liquid state. Here, we determine the electronic and structural properties of 1T-TaS2 using angle-resolved photoemission spectroscopy and X-Ray diffraction. At low temperatures, the 2/2c-periodic band dispersion, along with half-integer-indexed diffraction peaks along the c axis, unambiguously indicates that the ground state of 1T-TaS2 is a band insulator with interlayer dimerization. Upon heating, however, the system undergoes a transition into a Mott insulating state, which only exists in a narrow temperature window. Our results refute the idea of searching for quantum magnetism in 1T-TaS2 only at low temperatures, and highlight the competition between on-site Coulomb repulsion and interlayer hopping as a crucial aspect for understanding the material's electronic properties. 1T-TaS2 possesses complex electronic phase behaviors in transition-metal di-chalcogenides, undergoing several charge-ordered phases before finally into an insulating state of unknown origin. Here, the authors determine its electronic and structural properties experimentally, revealing its origin.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4215, "DOI": "10.1038/s41467-020-18040-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18040-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568890900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Scuri, G; Zhou, Y; High, AA; Wild, DS; Shu, C; De Greve, K; Jauregui, LA; Taniguchi, T; Watanabe, K; Kim, P; Lukin, MD; Park, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Scuri, Giovanni; Zhou, You; High, Alexander A.; Wild, Dominik S.; Shu, Chi; De Greve, Kristiaan; Jauregui, Luis A.; Taniguchi, Takashi; Watanabe, Kenji; Kim, Philip; Lukin, Mikhail D.; Park, Hongkun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large Excitonic Reflectivity of Monolayer MoSe2 Encapsulated in Hexagonal Boron Nitride", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate that a single layer of MoSe2 encapsulated by hexagonal boron nitride can act as an electrically switchable mirror at cryogenic temperatures, reflecting up to 85% of incident light at the excitonic resonullce. This high reflectance is a direct consequence of the excellent coherence properties of excitons in this atomically thin semiconductor. We show that the MoSe2 monolayer exhibits power-and wavelength-dependent nonlinearities that stem from exciton-based lattice heating in the case of continuous-wave excitation and exciton-exciton interactions when fast, pulsed laser excitation is used.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2018, "Volume": 120, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37402, "DOI": "10.1103/PhysRevLett.120.037402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.037402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423132300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gutfleisch, O; Gottschall, T; Fries, M; Benke, D; Radulov, I; Skokov, KP; Wende, H; Gruner, M; Acet, M; Entel, P; Farle, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gutfleisch, O.; Gottschall, T.; Fries, M.; Benke, D.; Radulov, I.; Skokov, K. P.; Wende, H.; Gruner, M.; Acet, M.; Entel, P.; Farle, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mastering hysteresis in magnetocaloric materials", "Source Title": "PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hysteresis is more than just an interesting oddity that occurs in materials with a first-order transition. It is a real obstacle on the path from existing laboratoryscale prototypes of magnetic refrigerators towards commercialization of this potentially disruptive cooling technology. Indeed, the reversibility of the magnetocaloric effect, being essential for magnetic heat pumps, strongly depends on the width of the thermal hysteresis and, therefore, it is necessary to understand the mechanisms causing hysteresis and to find solutions to minimize losses associated with thermal hysteresis in order to maximize the efficiency of magnetic cooling devices. In this work, we discuss the fundamental aspects that can contribute to thermal hysteresis and the strategies that we are developing to at least partially overcome the hysteresis problem in some selected classes of magnetocaloric materials with large application potential. In doing so, we refer to the most relevant classes of magnetic refrigerants La-Fe-Si-, Heusler-and Fe2P-type compounds. This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2016, "Volume": 374, "Issue": 2074, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20150308, "DOI": "10.1098/rsta.2015.0308", "DOI Link": "http://dx.doi.org/10.1098/rsta.2015.0308", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391135500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sakakura, M; Lei, YH; Wang, L; Yu, YH; Kazansky, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sakakura, Masaaki; Lei, Yuhao; Wang, Lei; Yu, Yan-Hao; Kazansky, Peter G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralow-loss geometric phase and polarization shaping by ultrafast laser writing in silica glass", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polarization and geometric phase shaping via a space-variant anisotropy has attracted considerable interest for fabrication of flat optical elements and generation of vector beams with applications in various areas of science and technology. Among the methods for anisotropy patterning, imprinting of self-assembled nullograting structures in silica glass by femtosecond laser writing is promising for the fabrication of space-variant birefringent optics with high thermal and chemical durability and high optical damage threshold. However, a drawback is the optical loss due to the light scattering by nullograting structures, which has limited the application. Here, we report a new type of ultrafast laser-induced modification in silica glass, which consists of randomly distributed nullopores elongated in the direction perpendicular to the polarization, providing controllable birefringent structures with transmittance as high as 99% in the visible and near-infrared ranges and >90% in the UV range down to 330 nm. The observed anisotropic nulloporous silica structures are fundamentally different from the femtosecond laser-induced nullogratings and conventional nulloporous silica. A mechanism of nullocavitation via interstitial oxygen generation mediated by multiphoton and avanlanche defect ionization is proposed. We demonstrate ultralow-loss geometrical phase optical elements, including geometrical phase prism and lens, and a vector beam convertor in silica glass. Shaping light: nullopores offer control with lower losses The optical property of birefringence can be manipulated in silica glass using an ultrafast laser writing procedure, creating materials in which the phase and polarization of light can be controlled with significantly lower scattering losses than alternative techniques. Birefringence is the effect observed when the refractive index of a material varies depending on the polarization and direction of incident light. M. Sakakura, Y. Lei, L. Wang, Y.-H. Yu, and P. Kazansky at the University of Southampton, UK, used laser light with pulses in the femtosecond range to create elongated nullopores inside silica glass. When the nullopores are aligned perpendicular to incident polarized light they allow subtle control of the light's properties with transmission as high as 99%. The ability of the materials to shape visible, near-infrared and ultra-violet light is expected to be beneficial in a variety of specialist optical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15, "DOI": "10.1038/s41377-020-0250-y", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0250-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511413200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Henkes, A; Wessels, H; Mahnken, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Henkes, Alexander; Wessels, Henning; Mahnken, Rolf", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physics informed neural networks for continuum micromechanics", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, physics informed neural networks have successfully been applied to a broad variety of problems in applied mathematics and engineering. The principle idea is the usage of a neural network as a global ansatz function for partial differential equations. Due to the global approximation, physics informed neural networks have difficulties in displaying localized effects and strong nonlinear solution fields by optimization. In this work we consider nonlinear stress and displacement fields invoked by material inhomogeneities with sharp phase interfaces. This constitutes a challenging problem for a method relying on a global ansatz. To overcome convergence issues, adaptive training strategies and domain decomposition are studied. It is shown, that the domain decomposition approach is capable to accurately resolve nonlinear stress, displacement and energy fields in heterogeneous microstructures obtained from real-world mu CT-scans. (C)& nbsp;2022 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2022, "Volume": 393, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114790, "DOI": "10.1016/j.cma.2022.114790", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2022.114790", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000793366500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, Q; Wang, Z; Ding, Y; Li, FM; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Qi; Wang, Zhe; Ding, Yu; Li, Fumin; Chen, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical functionalized noble metal nullocrystals for electrocatalysis", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalysis is an interface-dominated process, in which the activity of the catalyst highly relates to the adsorption/desorption behaviors of the reactants/intermediates/products on the active sites. From the perspective of catalyst design, the chemical functionalization design on noble metal sur-faces will inevitably affect the reaction process, which is considered to be one of the effective strate-gies to tune the electrocatalytic performance of noble metal nullocrystals. Polyamines (PAM) with high stability and good coordination ability have been widely studied as important functional mol-ecules. In this account, we first introduce the PAM-assisted synthesis mechanism of noble metal nullocrystals, which provides a theoretical basis and guidance for their design and optimization with controllable morphology. Then, the effects of adsorbed PAM on the electronic structure, geo-metric structure, electrode/electrolyte interface structure and catalytic reaction pathway of noble metal-based catalysts are specifically described. The internal mechanism of noble metal-PAM inter-facial effect increasing catalyst activity and selectivity is stated, and the latest research progress of PAM functionalized catalysts applied in important reactions is listed, such as hydrogen evolution reaction, oxygen reduction reaction, formic acid oxidation reaction, and nitrate reduction reaction, and so on. These findings open a new avenue for constructing advanced electrocatalysts based on inorganic/organic polymer-mediated interface engineering in various energy-related cataly-sis/electrocatalysis fields. Finally, the current challenges and future prospects of PAM molecule functionalized noble metal electrocatalysts are proposed.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 45, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6, "End Page": 16, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64186-X", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64186-X", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000976858300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dixit, T; Al-Hajri, E; Paul, MC; Nithiarasu, P; Kumar, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dixit, Tisha; Al-Hajri, Ebrahim; Paul, Manosh C.; Nithiarasu, Perumal; Kumar, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High performance, microarchitected, compact heat exchanger enabled by 3D printing", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing has created a paradigm shift in materials design and innovation, providing avenues and opportunities for geometric design freedom and customizations. Here, we report a microarchitected gyroid lattice liquid-liquid compact heat exchanger realized via stereolithography additive manufacturing as a single ready-to-use unit. This lightweight (~240 kg/m(3)) compact heat exchanger (with conjoined headers), with an engineered porosity of 80% and a separating wall thickness of 300 mu m, has a surface to volume ratio of 670 m(2)/ m(3). X-ray computed tomography imaging confirms a defect-free 3D printed heat exchanger. The thermohydraulic characteristics were experimentally measured using water as the working fluid. The measurements indicate that the heat exchanger evinces an overall heat transfer coefficient of 120-160W/m(2)K for hot fluid Reynolds number Reh in the range of 10(-40). Additionally, finite element analysis was conducted to evaluate the thermo-hydraulic characteristics of the gyroid lattice heat exchanger. The experimental results show-a 55% increase in exchanger effectiveness for the additively manufactured gyroid lattice heat exchanger in comparison to a thermodynamically equivalent, most-efficient, counter-flow heat exchanger at one tenth of its size. The superiority of our architected heat exchanger to extant work is also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2022, "Volume": 210, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118339, "DOI": "10.1016/j.applthermaleng.2022.118339", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2022.118339", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000806558900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, RT; Liu, LJ; Li, YB; Yang, Y; He, JL; Liu, XH; Zhang, XY; Wang, L; Wu, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Rui-Ting; Liu, Lijia; Li, Yanbo; Yang, Yang; He, Jinlu; Liu, Xianhu; Zhang, Xueyuan; Wang, Lei; Wu, Limin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ru- P pair sites boost charge transport in hematite photoanodes for exceeding 1% efficient solar water splitting", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fast transport of charge carriers in semiconductor photoelectrodes are a major determi-nullt of the solar - to-hydrogen efficiency for photoelectrochemical (PEC) water slitting. While doping metal ions as single atoms/clusters in photoelectrodes has been popularly used to regulate their charge transport, PEC performances are often low due to the limited charge mobility and severe charge recombination. Here, we disperse Ru and P diatomic sites onto hematite (DASs Ru-P:Fe2O3) to construct an efficient photoelectrode inspired by the concept of correlated single -atom engineering. The resultant photoanode shows superior photocurrent densities of 4.55 and 6.5 mA cm-2 at 1.23 and 1.50 VRHE, a low -onset potential of 0.58 VRHE, and a high applied bias photon - to-current conversion efficiency of 1.00% under one sun illumination, which are much better than the pristine Fe2O3. A detailed dynamic analysis reveals that a remarkable synergetic ineraction of the reduced recombination by a low Ru doping concentration with substitution of Fe site as well as the construction of Ru- P bonds in the material increases the carrier separation and fast charge transportation dynamics. A systematic simulation study further proves the superiority of the Ru- P bonds compared to the Ru- O bonds, which allows more long -lived carriers to participate in the water oxidation reaction. This work offers an effective strategy for enhancing charge carrier transportation dynamics by constructing pair sites into semiconductors, which may be extended to other photoelectrodes for solar water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2023, "Volume": 120, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2300493120", "DOI": "10.1073/pnas.2300493120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2300493120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001041172600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lyubarov, M; Lumer, Y; Dikopoltsev, A; Lustig, E; Sharabi, Y; Segev, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lyubarov, Mark; Lumer, Yaakov; Dikopoltsev, Alex; Lustig, Eran; Sharabi, Yonatan; Segev, Mordechai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Amplified emission and lasing in photonic time crystals", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photonic time crystals (PTCs), materials with a dielectric permittivity that is modulated periodically in time, offer new concepts in light manipulation. We study theoretically the emission of light from a radiation source placed inside a PTC and find that radiation corresponding to the momentum bandgap is exponentially amplified, whether initiated by a macroscopic source, an atom, or vacuum fluctuations, drawing the amplification energy from the modulation. The radiation linewidth becomes narrower with time, eventually becoming monochromatic in the middle of the bandgap, which enables us to propose the concept of nonresonullt tunable PTC laser. Finally, we find that the spontaneous decay rate of an atom embedded in a PTC vanishes at the band edge because of the low density of photonic states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2022, "Volume": 377, "Issue": 6604, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 425, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abo3324", "DOI Link": "http://dx.doi.org/10.1126/science.abo3324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830834600039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bultinck, N; Chatterjee, S; Zaletel, MP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bultinck, Nick; Chatterjee, Shubhayu; Zaletel, Michael P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanism for Anomalous Hall Ferromagnetism in Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recent observation of an anomalous Hall effect in twisted bilayer graphene, we use a lowest Landau level model to understand the origin of the underlying symmetry-broken correlated state. This effective model is rooted in the occurrence of Chern bands which arise due to the coupling between the graphene device and its encapsulating substrate. Our model exhibits a phase transition from a spin-valley polarized insulator to a partial or fully valley unpolarized metal as the bandwidth is increased relative to the interaction strength, consistent with experimental observations. In sharp contrast to standard quantum Hall ferromagnetism, the Chern number structure of the flat bands precludes an instability to an intervalley coherent phase, but allows for an excitonic vortex lattice at large interaction anisotropy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2020, "Volume": 124, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 166601, "DOI": "10.1103/PhysRevLett.124.166601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.166601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000527135200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, W; Lei, ZY; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Wei; Lei, Zhouyue; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanically Adaptative and Environmentally Stable Ionogels for Energy Harvest", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Converting building and environment heat into electricity is a promising strategy for energy harvest to tackle global energy and environmental problems. The processing challenges, mechanical brittleness, and low environmental tolerance of typical thermoelectric materials, however, prevent them from realizing their full potential when employed in outdoor building systems. Herein, a general concept based on synergistic ionic associations to significantly improve the mechanical properties and harsh environment stability for high-performance ionic-type thermoelectric (i-TE) gels is explored. They demonstrate extraordinarily high stretchability (1300-2100%), fast self-healing (120 s), temperature insensitivity, and great water-proof performance, and could be painted on a variety of surfaces. The n-type ionic Seebeck coefficient is up to -8.8 mV K-1 and the ionic conductivity is more than 0.14 mS cm(-1). Both exhibit remarkable thermal and humidity stability (293-333 K, 20-100 RH%), which are rarely achieved in previous studies. Even on a cloudy day, the open-circuit thermovoltage for a painted i-TE array with an area of about 8.5 x 10(-3) m(2) is above 2 V. This research offers a promising approach for gathering significant waste heat and even solar energy on outside building surfaces in an effective and sustainable manner.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 45, "Times Cited, All Databases": 45, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300253", "DOI Link": "http://dx.doi.org/10.1002/advs.202300253", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971454100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lloveras, P; Aznar, A; Barrio, M; Negrier, P; Popescu, C; Planes, A; Mañosa, L; Stern-Taulats, E; Avramenko, A; Mathur, ND; Moya, X; Tamarit, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lloveras, P.; Aznar, A.; Barrio, M.; Negrier, Ph.; Popescu, C.; Planes, A.; Manosa, L.; Stern-Taulats, E.; Avramenko, A.; Mathur, N. D.; Moya, X.; Tamarit, J. -Ll.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is currently great interest in replacing the harmful volatile hydrofluorocarbon fluids used in refrigeration and air-conditioning with solid materials that display magnetocaloric, electrocaloric or mechanocaloric effects. However, the field-driven thermal changes in all of these caloric materials fall short with respect to their fluid counterparts. Here we show that plastic crystals of neopentylglycol (CH3)(2)C(CH2OH)(2) display extremely large pressure-driven thermal changes near room temperature due to molecular reconfiguration, that these changes outperform those observed in any type of caloric material, and that these changes are comparable with those exploited commercially in hydrofluorocarbons. Our discovery of colossal barocaloric effects in a plastic crystal should bring barocaloric materials to the forefront of research and development in order to achieve safe environmentally friendly cooling without compromising performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1803, "DOI": "10.1038/s41467-019-09730-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09730-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464979000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hajiesmaili, E; Clarke, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hajiesmaili, Ehsan; Clarke, David R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dielectric elastomer actuators", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectric elastomer actuators (DEAs) are soft, electrically powered actuators that have no discrete moving parts, yet can exhibit large strains (10%-50%) and moderate stress (similar to 100kPa). This Tutorial describes the physical basis underlying the operation of DEA's, starting with a simple linear analysis, followed by nonlinear Newtonian and energy approaches necessary to describe large strain characteristics of actuators. These lead to theoretical limits on actuation strains and useful non-dimensional parameters, such as the normalized electric breakdown field. The analyses guide the selection of elastomer materials and compliant electrodes for DEAs. As DEAs operate at high electric fields, this Tutorial describes some of the factors affecting the Weibull distribution of dielectric breakdown, geometrical effects, distinguishing between permanent and soft breakdown, as well as self-clearing and its relation to proof testing to increase device reliability. New evidence for molecular alignment under an electric field is also presented. In the discussion of compliant electrodes, the rationale for carbon nullotube (CNT) electrodes is presented based on their compliance and ability to maintain their percolative conductivity even when stretched. A procedure for making complaint CNT electrodes is included for those who wish to fabricate their own. Percolative electrodes inevitably give rise to only partial surface coverage and the consequences on actuator performance are introduced. Developments in actuator geometry, including recent 3D printing, are described. The physical basis of versatile and reconfigurable shape-changing actuators, together with their analysis, is presented and illustrated with examples. Finally, prospects for achieving even higher performance DEAs will be discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2021, "Volume": 129, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 151102, "DOI": "10.1063/5.0043959", "DOI Link": "http://dx.doi.org/10.1063/5.0043959", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641992200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Zhao, SH; Bi, FK; Chen, JF; Li, YT; Cui, LF; Xu, JC; Zhang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yang; Zhao, Shenghao; Bi, Fukun; Chen, Jinfeng; Li, Yintao; Cui, Lifeng; Xu, Jingcheng; Zhang, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen-vacancy-induced O2 activation and electron-hole migration enhance photothermal catalytic toluene oxidation", "Source Title": "CELL REPORTS PHYSICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid elimination of volatile organic compounds and the inter-mediate analysis with efficient photothermal catalysis are of great significance to the environment. Oxygen vacancies (Vo) play a crucial role in structural modification and performance improvement of heterogeneous catalysts. Accordingly, here, abundant Vo sites are introduced into Co3O4/TiO2 composite via treatment under H-2 and Ar flow at 200 & DEG;C, and the photothermal catalytic performance of toluene is significantly improved. The molecular oxygen (O-2) adsorbed by Vo is activated to form reactive oxygen species for deep oxidation of toluene. Vo generated on the unilateral side in Co3O4/TiO2 heterojunctions serves to capture electrons and break the dynamic balance of electron-hole pairs. The excited electrons are trapped by Vo, and the direct recombination of electron -hole pairs is inhibited, thus promoting the photochemical process. Moreover, the photothermal synergy effect and the relationship be-tween Vo evolution and intermediates transformation mechanism are systematically studied.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101011, "DOI": "10.1016/j.xcrp.2022.101011", "DOI Link": "http://dx.doi.org/10.1016/j.xcrp.2022.101011", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849615700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Winter, R; Montanari, F; Noé, F; Clevert, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Winter, Robin; Montanari, Floriane; Noe, Frank; Clevert, Djork-Arne", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Learning continuous and data-driven molecular descriptors by translating equivalent chemical representations", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been a recent surge of interest in using machine learning across chemical space in order to predict properties of molecules or design molecules and materials with the desired properties. Most of this work relies on defining clever feature representations, in which the chemical graph structure is encoded in a uniform way such that predictions across chemical space can be made. In this work, we propose to exploit the powerful ability of deep neural networks to learn a feature representation from low-level encodings of a huge corpus of chemical structures. Our model borrows ideas from neural machine translation: it translates between two semantically equivalent but syntactically different representations of molecular structures, compressing the meaningful information both representations have in common in a low-dimensional representation vector. Once the model is trained, this representation can be extracted for any new molecule and utilized as a descriptor. In fair benchmarks with respect to various human-engineered molecular fingerprints and graph-convolution models, our method shows competitive performance in modelling quantitative structure-activity relationships in all analysed datasets. Additionally, we show that our descriptor significantly outperforms all baseline molecular fingerprints in two ligand-based virtual screening tasks. Overall, our descriptors show the most consistent performances in all experiments. The continuity of the descriptor space and the existence of the decoder that permits deducing a chemical structure from an embedding vector allow for exploration of the space and open up new opportunities for compound optimization and idea generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 316, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2019, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1692, "End Page": 1701, "Article Number": null, "DOI": "10.1039/c8sc04175j", "DOI Link": "http://dx.doi.org/10.1039/c8sc04175j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458024700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Connor, P; Schuch, J; Kaiser, B; Jaegermann, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Connor, Paula; Schuch, Jona; Kaiser, Bernhard; Jaegermann, Wolfram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Determination of Electrochemical Active Surface Area and Specific Capacity Revisited for the System MnOx as an Oxygen Evolution Catalyst", "Source Title": "ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the last decades several different catalysts for the electrochemical water splitting reaction have been designed and tested. In so-called benchmark papers they are compared with respect to their efficiency and activity. In order to relate the different catalyst to each other the definition of well-defined procedures is required. Two different methods are mainly used: Either the normalization with respect to the geometric surface area or to the catalyst loading. Most often only one of these values is available for a sample and the other one cannot be estimated easily. One approach in electrocatalysis is to determine the Helmholtz double layer capacitance (DLC) and deduce the electrochemical active surface area (ECSA). The DLC can be obtained from two different methods, either using differential capacitance measurement (DCM) or impedance spectroscopy (EIS). The second value needed for the calculation of the ECSA is the specific capacitance, which is the capacitance for a perfectly flat surface of given catalyst material. Here, we present the determination of the different capacitance values using manganese oxide as the exemplary model for the oxygen evolution reaction (OER). We determine the capacitance by DCM and EIS to calculate the EC SA using literature values for the specific capacitance. The obtained values are comparable from the two methods, but are much larger than the surface areas obtained by atomic force microscopy. Therefore, we consider the possibility of using the measured AFM area together with the Helmholtz capacitance to determine the specific capacitances for this material class. The comparison of these results with literature values illustrates the actual limits of the ECSA method, which will be discussed in this paper.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 234, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 979, "End Page": 994, "Article Number": null, "DOI": "10.1515/zpch-2019-1514", "DOI Link": "http://dx.doi.org/10.1515/zpch-2019-1514", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000534258100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elias, C; Valvin, P; Pelini, T; Summerfield, A; Mellor, CJ; Cheng, TS; Eaves, L; Foxon, CT; Beton, PH; Novikov, SV; Gil, B; Cassabois, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elias, C.; Valvin, P.; Pelini, T.; Summerfield, A.; Mellor, C. J.; Cheng, T. S.; Eaves, L.; Foxon, C. T.; Beton, P. H.; Novikov, S., V; Gil, B.; Cassabois, G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct band-gap crossover in epitaxial monolayer boron nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride is a large band-gap insulating material which complements the electronic and optical properties of graphene and the transition metal dichalcogenides. However, the intrinsic optical properties of monolayer boron nitride remain largely unexplored. In particular, the theoretically expected crossover to a direct-gap in the limit of the single monolayer is presently not confirmed experimentally. Here, in contrast to the technique of exfoliating few-layer 2D hexagonal boron nitride, we exploit the scalable approach of high-temperature molecular beam epitaxy to grow high-quality monolayer boron nitride on graphite substrates. We combine deep-ultraviolet photoluminescence and reflectance spectroscopy with atomic force microscopy to reveal the presence of a direct gap of energy 6.1 eV in the single atomic layers, thus confirming a crossover to direct gap in the monolayer limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2639, "DOI": "10.1038/s41467-019-10610-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10610-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000471586700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hinuma, Y; Hatakeyama, T; Kumagai, Y; Burton, LA; Sato, H; Muraba, Y; Iimura, S; Hiramatsu, H; Tanaka, I; Hosono, H; Oba, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hinuma, Yoyo; Hatakeyama, Taisuke; Kumagai, Yu; Burton, Lee A.; Sato, Hikaru; Muraba, Yoshinori; Iimura, Soshi; Hiramatsu, Hidenori; Tanaka, Isao; Hosono, Hideo; Oba, Fumiyasu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of earth-abundant nitride semiconductors by computational screening and high-pressure synthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitride semiconductors are attractive because they can be environmentally benign, comprised of abundant elements and possess favourable electronic properties. However, those currently commercialized are mostly limited to gallium nitride and its alloys, despite the rich composition space of nitrides. Here we report the screening of ternary zinc nitride semiconductors using first-principles calculations of electronic structure, stability and dopability. This approach identifies as-yet-unreported CaZn2N2 that has earth-abundant components, smaller carrier effective masses than gallium nitride and a tunable direct bandgap suited for light emission and harvesting. High-pressure synthesis realizes this phase, verifying the predicted crystal structure and band-edge red photoluminescence. In total, we propose 21 promising systems, including Ca2ZnN2, Ba2ZnN2 and Zn2PN3, which have not been reported as semiconductors previously. Given the variety in bandgaps of the identified compounds, the present study expands the potential suitability of nitride semiconductors for a broader range of electronic, optoelectronic and photovoltaic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11962, "DOI": "10.1038/ncomms11962", "DOI Link": "http://dx.doi.org/10.1038/ncomms11962", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379086200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ling, J; Jones, R; Templeton, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ling, Julia; Jones, Reese; Templeton, Jeremy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning strategies for systems with invariance properties", "Source Title": "JOURNAL OF COMPUTATIONAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In many scientific fields, empirical models are employed to facilitate computational simulations of engineering systems. For example, in fluid mechanics, empirical Reynolds stress closures enable computationally-efficient Reynolds Averaged Navier Stokes simulations. Likewise, in solid mechanics, constitutive relations between the stress and strain in a material are required in deformation analysis. Traditional methods for developing and tuning empirical models usually combine physical intuition with simple regression techniques on limited data sets. The rise of high performance computing has led to a growing availability of high fidelity simulation data. These data open up the possibility of using machine learning algorithms, such as random forests or neural networks, to develop more accurate and general empirical models. A key question when using data-driven algorithms to develop these empirical models is how domain knowledge should be incorporated into the machine learning process. This paper will specifically address physical systems that possess symmetry or invariance properties. Two different methods for teaching a machine learning model an invariance property are compared. In the first method, a basis of invariant inputs is constructed, and the machine learning model is trained upon this basis, thereby embedding the invariance into the model. In the second method, the algorithm is trained on multiple transformations of the raw input data until the model learns invariance to that transformation. Results are discussed for two case studies: one in turbulence modeling and one in crystal elasticity. It is shown that in both cases embedding the invariance property into the input features yields higher performance at significantly reduced computational training costs. (C) 2016 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2016, "Volume": 318, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22, "End Page": 35, "Article Number": null, "DOI": "10.1016/j.jcp.2016.05.003", "DOI Link": "http://dx.doi.org/10.1016/j.jcp.2016.05.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377043400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naushad, M; Mittal, A; Rathore, M; Gupta, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naushad, Mu.; Mittal, Alok; Rathore, M.; Gupta, V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ion-exchange kinetic studies for Cd(II), Co(II), Cu(II), and Pb(II) metal ions over a composite cation exchanger", "Source Title": "DESALINATION AND WATER TREATMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Explicit Nernst-Planck approximation is used to study the kinetics of H(I)-metal ion-exchange processes for ions having different effective diffusion coefficients, that is, for non-isotopic exchange process. Kinetic studies of four heavy metal ions (Cd2+, Co2+, Cu2+, and Pb2+) of environmental importance on the surface of acetonitrile stannic(IV) selenite composite cation exchanger were carried out successfully. On the basis of kinetic studies, various physical parameters, that is, fractional attainment of equilibrium U(tau), self-diffusion coefficients (D-o), energy of activation (E-a), and entropy of activation (Delta S*) are estimated to evaluate the mechanism of ion exchange on the surface of composite ion-exchange material. The activation entropy and energy revealed that the greater degree and minimum energy was achieved during forward ion-exchange process. The results revealed that the kinetic studies are very important for the economic and industrial applications of ion-exchange materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2015, "Volume": 54, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2883, "End Page": 2890, "Article Number": null, "DOI": "10.1080/19443994.2014.904823", "DOI Link": "http://dx.doi.org/10.1080/19443994.2014.904823", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353715700023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, JX; Zhang, YH; Morissette, E; Wang, Z; Liu, S; Rhodes, D; Watanabe, K; Taniguchi, T; Hone, J; Li, JIA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Jiang-Xiazi; Zhang, Ya-Hui; Morissette, Erin; Wang, Zhi; Liu, Song; Rhodes, Daniel; Watanabe, K.; Taniguchi, T.; Hone, James; Li, J. I. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-orbit-driven ferromagnetism at half moire filling in magic-angle twisted bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Strong electron correlation and spin-orbit coupling (SOC) can have a profound influence on the electronic properties of materials. We examined their combined influence on a two-dimensional electronic system at the atomic interface between magic-angle twisted bilayer graphene and a tungsten diselenide crystal. We found that strong electron correlation within the moire flatband stabilizes correlated insulating states at both quarter and half filling, and that SOC transforms these Mott-like insulators into ferromagnets, as evidenced by a robust anomalous Hall effect with hysteretic switching behavior. The coupling between spin and valley degrees of freedom could be demonstrated through control of the magnetic order with an in-plane magnetic field or a perpendicular electric field. Our findings establish an experimental knob to engineer topological properties of moire bands in twisted bilayer graphene and related systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2022, "Volume": 375, "Issue": 6579, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 437, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh2889", "DOI Link": "http://dx.doi.org/10.1126/science.abh2889", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750899500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Si, WD; Zhang, CK; Zhou, M; Tian, WD; Wang, Z; Hu, QS; Song, KP; Feng, L; Huang, XQ; Gao, ZY; Tung, CH; Sun, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Si, Wei -Dan; Zhang, Chengkai; Zhou, Meng; Tian, Wei-Dong; Wang, Zhi; Hu, Qingsong; Song, Ke-Peng; Feng, Lei; Huang, Xian-Qiang; Gao, Zhi-Yong; Tung, Chen-Ho; Sun, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au20 nullocluster", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsic dual-emission (DE) of gold nulloclusters in the near-infrared (NIR) are fascinating for fundamental im-portance and practical applications, but their synthesis remains a formidable challenge and sophisticated excited-state processes make elucidating DE mechanisms much more arduous. Here, we report an all-alkynyl-protected gold nullocluster, Au20, showing a prolate Au12 tri-octahedral kernel surrounded by two Au2(CZ-PrA)3 dimers, four Au(CZ-PrA)2 monomers, and two CZ-PrA- bridges. Au20 exhibits distinguished pho-tophysical properties including NIR DE at 820 and 940 nm, microsecond radiative relaxation, and 6.26% photo -luminescent quantum yield at ambient environment in nondegassed solution. Combining systematic studies on steady/transient spectroscopy and theoretical calculation, we identified two triplet charge transfer (CT) states, ligand-to-kernel and kernel-based CT states as DE origins. Furthermore, this NIR DE exhibits highly independent and sensitive response to surrounding environments, which well coincide with its mechanism. This work not only provides a substantial structure model to understand a distinctive DE mechanism but also motivates the further development of NIR DE materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2023, "Volume": 9, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadg3587", "DOI": "10.1126/sciadv.adg3587", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adg3587", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000969620700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Modic, KA; Smidt, TE; Kimchi, I; Breznay, NP; Biffin, A; Choi, S; Johnson, RD; Coldea, R; Watkins-Curry, P; McCandless, GT; Chan, JY; Gandara, F; Islam, Z; Vishwanath, A; Shekhter, A; McDonald, RD; Analytis, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Modic, K. A.; Smidt, Tess E.; Kimchi, Itamar; Breznay, Nicholas P.; Biffin, Alun; Choi, Sungkyun; Johnson, Roger D.; Coldea, Radu; Watkins-Curry, Pilanda; McCandless, Gregory T.; Chan, Julia Y.; Gandara, Felipe; Islam, Z.; Vishwanath, Ashvin; Shekhter, Arkady; McDonald, Ross D.; Analytis, James G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of a three-dimensional spin-anisotropic harmonic honeycomb iridate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin and orbital quantum numbers play a key role in the physics of Mott insulators, but in most systems they are connected only indirectly-via the Pauli exclusion principle and the Coulomb interaction. Iridium-based oxides (iridates) introduce strong spin-orbit coupling directly, such that these numbers become entwined together and the Mott physics attains a strong orbital character. In the layered honeycomb iridates this is thought to generate highly spin-anisotropic magnetic interactions, coupling the spin to a given spatial direction of exchange and leading to strongly frustrated magnetism. Here we report a new iridate structure that has the same local connectivity as the layered honeycomb and exhibits striking evidence for highly spin-anisotropic exchange. The basic structural units of this material suggest that a new family of three-dimensional structures could exist, the 'harmonic honeycomb' iridates, of which the present compound is the first example.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4203, "DOI": "10.1038/ncomms5203", "DOI Link": "http://dx.doi.org/10.1038/ncomms5203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338838800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, DX; Gong, W; Tsuru, T; Lobzenko, I; Li, XQ; Harjo, S; Kawasaki, T; Do, HS; Bae, JW; Wagner, C; Laplanche, G; Koizumi, Y; Adachi, H; Aoyagi, K; Chiba, A; Lee, BJ; Kim, HS; Kato, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Daixiu; Gong, Wu; Tsuru, Tomohito; Lobzenko, Ivan; Li, Xiaoqing; Harjo, Stefanus; Kawasaki, Takuro; Do, Hyeon-Seok; Bae, Jae Wung; Wagner, Christian; Laplanche, Guillaume; Koizumi, Yuichiro; Adachi, Hiroki; Aoyagi, Kenta; Chiba, Akihiko; Lee, Byeong-Joo; Kim, Hyoung Seop; Kato, Hidemi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Si-addition contributes to overcoming the strength-ductility trade-off in high-entropy alloys", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Face-centered cubic single-phase high-entropy alloys (HEAs) containing multi-principal transition metals have attracted significant attention, exhibiting an unprecedented combination of strength and ductility owing to their low stacking fault energy (SFE) and large misfit parameter that creates severe local lattice distortion. Increasing both strength and ductility further is challenging. In the present study, we demonstrate via meticulous experiments that the CoCrFeNi HEA with the addition of the substitutional metalloid Si can retain a single-phase FCC structure while its yield strength (up to 65%), ultimate strength (up to 34%), and ductility (up to 15%) are simultaneously increased, owing to a synthetical effect of the enhanced solid solution strengthening and a reduced SFE. The dislocation behaviors and plastic deformation mechanisms were tuned by the addition of Si, which improves the strain hardening and tensile ductility. The present study provides new strategies for enhancing HEA performance by targeted metalloid additions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 159, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103443, "DOI": "10.1016/j.ijplas.2022.103443", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2022.103443", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000868938200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZN; Zhu, LX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhenong; Zhu, Linxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Nonreciprocal Thermal Emission", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reciprocity between thermal emission and absorption in materials that satisfy the Lorentz reciprocity places a fundamental constraint on photonic energy conversion and thermal management. For approaching the ultimate thermodynamic limits in various photonic energy conversions and achieving nonreciprocal radiative thermal management, broadband nonreciprocal thermal emission is desired. However, existing designs of nonreciprocal emitters are narrowband. Here, we introduce a gradient epsilon-near-zero magneto-optical metamaterial for achieving broadband nonreciprocal thermal emission. We start by analyzing the nonreciprocal thermal emission and absorption in a thin layer of epsilon-near-zero magneto-optical material atop a substrate. We use temporal coupled-mode theory to elucidate the mechanism of nonreciprocal emission in the thin-film emitter. We then introduce a general approach for achieving broadband nonreciprocal emission by using a gradient epsilon-near-zero magneto optical metamaterial. We numerically demonstrate broadband nonreciprocal emission in gradient-doped semiconductor multilayer, as well as in a magnetic Weyl semimetal multilayer with gradient chemical potential. Our approach for achieving broadband nonreciprocal emitters is useful for developing broadband nonreciprocal devices for energy conversion and thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 19, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14013, "DOI": "10.1103/PhysRevApplied.19.014013", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.19.014013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914770900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Taherifar, R; Zareei, SA; Bidgoli, MR; Kolahchi, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Taherifar, Reza; Zareei, Seyed Alireza; Bidgoli, Mahmood Rabani; Kolahchi, Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application of differential quadrature and Newmark methods for dynamic response in pad concrete foundation covered by piezoelectric layer", "Source Title": "JOURNAL OF COMPUTATIONAL AND APPLIED MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article deals with the dynamic analysis in pad concrete foundation containing Silica nulloparticles (SiO2) subject to seismic load. The foundation is covered by a piezoelectric layer for smart control of the structure. The weight of the building by a column on the foundation is assumed with an external force at the middle of the structure. The foundation is located in soil medium which is modeled by spring elements. The Mori-Tanaka low is utilized for calculating the equivalent material characteristics of the concrete foundation. The structural damping of the structure is considered based on Kelvin-Voigt model. The concrete structure is modeled by thick plate and the governing equations are derived based on first order shear deformation theory (FSDT) utilizing Hamilton's principle. Applying differential quadrature method (DQM) and Newmark method, the dynamic deflection is obtained. The effects of applied voltage to smart layer, volume percent and agglomeration of SiO2 nulloparticles, structural damping, soil medium and geometrical parameters of structure are shown on the dynamic deflection. Results indicate that with applying negative voltage, the dynamic deflection is reduced significantly. In addition, the SiO2 nulloparticles decreases the dynamic deflection of the concrete foundation. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 43, "Times Cited, All Databases": 43, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2021, "Volume": 382, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113075, "DOI": "10.1016/j.cam.2020.113075", "DOI Link": "http://dx.doi.org/10.1016/j.cam.2020.113075", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563527500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, HH; Xing, BL; Cao, YJ; Xu, B; Hou, L; Guo, H; Cheng, S; Huang, GX; Zhang, CX; Sun, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Huihui; Xing, Baolin; Cao, Yijun; Xu, Bing; Hou, Lei; Guo, Hui; Cheng, Song; Huang, Guangxu; Zhang, Chuanxiang; Sun, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insight into the microstructural evolution of anthracite during carbonization-graphitization process from the perspective of materialization", "Source Title": "INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materialization of coal is one of effective and clean pathways for its utilization. The microstructures of coal-based carbon materials have an important influence on their functional applications. Herein, the microstructural evolution of anthracite in the temperature range of 1000-2800 degrees C was systematically investigated to provide a guidance for the microstructural regulation of coal-based carbon materials. The results indicate that the microstructure of anthracite undergoes an important change during carbonization-graphitization process. As the temperature increases, aromatic layers in anthracite gradu-ally transform into disordered graphite microcrystals and further grow into ordered graphite microcrys-tals, and then ordered graphite microcrystals are laterally linked to form pseudo-graphite phase and eventually transformed into highly ordered graphite-like sheets. In particular, 2000-2200 degrees C is a critical temperature region for the qualitative change of ordered graphite crystallites to pseudo-graphite phase, in which the relevant structural parameters including stacking height, crystallite lateral size and graphi-tization degree show a rapid increase. Moreover, both aromaticity and graphitization degree have a linear positive correlation with carbonization-graphitization temperature in a specific temperature range. Besides, after initial carbonization, some defect structures in anthracite such as aliphatic carbon and oxygen-containing functional groups are released in the form of gaseous low-molecular volatiles along with an increased pore structure, and the intermediates derived from minerals could facilitate the con-version of sp3 amorphous carbon to sp2 graphitic carbon. This work provides a valuable reference for the rational design of microstructure of coal-based carbon materials.(c) 2022 Published by Elsevier B.V. on behalf of China University of Mining & Technology. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 32, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1397, "End Page": 1406, "Article Number": null, "DOI": "10.1016/j.ijmst.2022.06.009", "DOI Link": "http://dx.doi.org/10.1016/j.ijmst.2022.06.009", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000910054600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Wu, Y; Shi, L; Hu, XH; Chen, M; Wu, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tong; Wu, Yi; Shi, Lan; Hu, Xinhua; Chen, Min; Wu, Limin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A structural polymer for highly efficient all-day passive radiative cooling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-day passive radiative cooling has recently attracted tremendous interest by reflecting sunlight and radiating heat to the ultracold outer space. While some progress has been made, it still remains big challenge in fabricating highly efficient and low-cost radiative coolers for all-day and all-climates. Herein, we report a hierarchically structured polymethyl methacrylate (PMMA) film with a micropore array combined with random nullopores for highly efficient day- and nighttime passive radiative cooling. This hierarchically porous array PMMA film exhibits sufficiently high solar reflectance (0.95) and superior longwave infrared thermal emittance (0.98) and realizes subambient cooling of similar to 8.2 degrees C during the night and similar to 6.0 degrees C to similar to 8.9 degrees C during midday with an average cooling power of similar to 85W/m(2) under solar intensity of similar to 900W/m(2), and promisingly similar to 5.5 degrees C even under solar intensity of similar to 930W/m(2) and relative humidity of similar to 64% in hot and moist climate. The micropores and nullopores in the polymer film play crucial roles in enhancing the solar reflectance and thermal emittance. There still remains a big challenge in fabricating highly efficient and low-cost radiative coolers for all-day and all-climates. Here, the authors report a hierarchically structured polymethyl methacrylate film with a micropore array combined with random nullopores for highly efficient day- and nighttime passive radiative cooling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 365, "DOI": "10.1038/s41467-020-20646-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20646-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000610677200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zasedatelev, AV; Baranikov, AV; Sannikov, D; Urbonas, D; Scafirimuto, F; Shishkov, VY; Andrianov, ES; Lozovik, YE; Scherf, U; Stöferle, T; Mahrt, RF; Lagoudakis, PG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zasedatelev, Anton V.; Baranikov, Anton V.; Sannikov, Denis; Urbonas, Darius; Scafirimuto, Fabio; Shishkov, Vladislav Yu.; Andrianov, Evgeny S.; Lozovik, Yurii E.; Scherf, Ullrich; Stoferle, Thilo; Mahrt, Rainer F.; Lagoudakis, Pavlos G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-photon nonlinearity at room temperature", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent progress in nullotechnology(1,2) and single-molecule spectroscopy(3-5) paves the way for emergent cost-effective organic quantum optical technologies with potential applications in useful devices operating at ambient conditions. We harness a pi-conjugated ladder-type polymer strongly coupled to a microcavity forming hybrid light-matter states, so-called exciton-polaritons, to create exciton-polariton condensates with quantum fluid properties. Obeying Bose statistics, exciton-polaritons exhibit an extreme nonlinearity when undergoing bosonic stimulation(6), which we have managed to trigger at the single-photon level, thereby providing an efficient way for all-optical ultrafast control over the macroscopic condensate wavefunction. Here, we utilize stable excitons dressed with high-energy molecular vibrations, allowing for single-photon nonlinear operation at ambient conditions. This opens new horizons for practical implementations like sub-picosecond switching, amplification and all-optical logic at the fundamental quantum limit. Nonlinearity induced by a single photon is desirable because it can drive power consumption of optical devices to their fundamental quantum limit, and is demonstrated here at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 103, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2021, "Volume": 597, "Issue": 7877, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 493, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03866-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03866-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698710300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "El Idi, MM; Karkri, M; Tankari, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "El Idi, Mohamed Moussa; Karkri, Mustapha; Tankari, Mahamadou Abdou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A passive thermal management system of Li-ion batteries using PCM composites: Experimental and numerical investigations", "Source Title": "INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper is dedicated to the design of an optimal thermal management system using a PCM-Metal Foam composite at the scale of a Li-ion batteries cells. To study the ability of a PCM and a PCM- Metal foam composite to absorb the heat generated by a Li-ion cell, a mathematical and numerical model was developed. The modeling is based on the data collected from characterizing experiments conducted with a new experimental test bench developed in the CERTES lab. In order to characterize the thermal behavior of Li-ion cell, the developed two-dimensional numerical model integrates the Brinkmann-Forchheimer-extended Darcy equation, the enthalpy-porosity method and two-temperature energy equations. The numerical study was made by coupling Matlab and COMSOL Multiphysics. The results showed that the addition of an aluminum foam allows a more efficient thermal management of the cell. The optimization study showed that an underestimation of the thickness (mass of PCM required) leads to extreme temperatures. It was also found that the addition of an extra volume of PCM does not have a great influence on the cell surface temperature. (C) 2021 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 138, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 169, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120894, "DOI": "10.1016/j.ijheatmasstransfer.2020.120894", "DOI Link": "http://dx.doi.org/10.1016/j.ijheatmasstransfer.2020.120894", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641139700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miller, DAB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miller, David A. B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Attojoule Optoelectronics for Low-Energy Information Processing and Communications", "Source Title": "JOURNAL OF LIGHTWAVE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optics offers unique opportunities for reducing energy in information processing and communications while simultaneously resolving the problem of interconnect bandwidth density inside machines. Such energy dissipation overall is now at environmentally significant levels; the source of that dissipation is progressively shifting from logic operations to interconnect energies. Without the prospect of substantial reduction in energy per bit communicated, we cannot continue the exponential growth of our use of information. The physics of optics and optoelectronics fundamentally addresses both interconnect energy and bandwidth density, and optics may be the only scalable solution to such problems. Here we summarize the corresponding background, status, opportunities, and research directions for optoelectronic technology and novel optics, including subfemtojoule devices in waveguide and novel two-dimensional (2-D) array optical systems. We compare different approaches to low-energy optoelectronic output devices and their scaling, including lasers, modulators and LEDs, optical confinement approaches (such as resonators) to enhance effects, and the benefits of different material choices, including 2-D materials and other quantum-confined structures. With such optoelectronic energy reductions, and the elimination of line charging dissipation by the use optical connections, the next major interconnect dissipations are in the electronic circuits for receiver amplifiers, timing recovery, and multiplexing. We show we can address these through the integration of photodetectors to reduce or eliminate receiver circuit energies, free-space optics to eliminate the need for timing and multiplexing circuits (while also solving bandwidth density problems), and using optics generally to save power by running large synchronous systems. One target concept is interconnects from similar to 1 cm to similar to 10 m that have the same energy (similar to 10 fJ/bit) and simplicity as local electrical wires on chip.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 488, "Times Cited, All Databases": 585, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 35, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 346, "End Page": 396, "Article Number": null, "DOI": "10.1109/JLT.2017.2647779", "DOI Link": "http://dx.doi.org/10.1109/JLT.2017.2647779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Optics; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397724700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, R; Iwamoto, S; Feng, L; Ju, SH; Hu, SQ; Ohnishi, M; Nagai, N; Hirakawa, K; Shiomi, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Run; Iwamoto, Sotaro; Feng, Lei; Ju, Shenghong; Hu, Shiqian; Ohnishi, Masato; Nagai, Naomi; Hirakawa, Kazuhiko; Shiomi, Junichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine-Learning-Optimized Aperiodic Superlattice Minimizes Coherent Phonon Heat Conduction", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lattice heat conduction can be modulated via nullostructure interfaces. Although advances have been made by viewing phonons as particles, the controllability should be enhanced by fully utilizing their wave nature. By considering phonons as coherent waves, herein we design an optimized aperiodic superlattice that minimizes the coherent phonon heat conduction by alternatingly coupling coherent phonon transport calculations and machine learning. The thermal conductivity of the fabricated aperiodic superlattice agrees well with the calculations over a temperature range of 77-300 K, indicating that complex aperiodic wave interference of coherent phonons can be controlled. The thermal conductivity of the aperiodic superlattice is significantly smaller than the conventional periodic superlattice due to enhanced phonon localization. The optimized aperiodic structure is formed by connecting weakly correlated local structures that introduce interference over broad phonon frequencies. Controlling coherent phonons by aperiodic interferences opens a new route for phonon engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 4", "Publication Year": 2020, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21050, "DOI": "10.1103/PhysRevX.10.021050", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.10.021050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537620400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, LK; Chen, YZ; Chow, PCY; Zhang, GY; Huang, JC; Ma, C; Zhang, JQ; Yin, H; Cheung, AMH; Wong, KS; So, SK; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Lik-Kuen; Chen, Yuzhong; Chow, Philip C. Y.; Zhang, Guangye; Huang, Jiachen; Ma, Chao; Zhang, Jianquan; Yin, Hang; Cheung, Andy Man Hong; Wong, Kam Sing; So, Shu Kong; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Efficiency Indoor Organic Photovoltaics with a Band-Aligned Interlayer", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The emergence of indoor electronic devices for internet of things (IoT) has motivated the scientific community to develop photovoltaic devices that can efficiently convert indoor light into electricity. In this paper, we report high-efficiency non-fullerene organic photovoltaic (OPV) cells with over 30% power conversion efficiency (PCE) under indoor conditions. Our results show that the choice of electron-transporting layer (ETL) is critically important to enable such performance. The use of an ETL (named PDI-NO) with a deep highest occupied molecular orbital (HOMO) level can effectively suppress leakage current and reduce trap-assisted recombination of the devices. Thus, using this ETL, we achieve record PCE of 31% by utilizing a low-band-gap acceptor in the bulk-heterojunction (BHJ) blend. Whereas, in another case, by employing a large-band-gap acceptor, a PCE of 26.7% with over 1V is achieved. Our study paves the way toward high-performance indoor OPV devices for powering IoT electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1486, "End Page": 1500, "Article Number": null, "DOI": "10.1016/j.joule.2020.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551427400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XX; Fu, WQ; Zhang, HX; Guo, JZ; Gu, ZY; Wang, XT; Yang, JL; Lü, HY; Wu, XL; Ang, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin-Xin; Fu, Wangqin; Zhang, Hong-Xia; Guo, Jin-Zhi; Gu, Zhen-Yi; Wang, Xiao-Tong; Yang, Jia-Lin; Lu, Hong-Yan; Wu, Xing-Long; Ang, Edison Huixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pearl-Structure-Enhanced NASICON Cathode toward Ultrastable Sodium-Ion Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on the favorable ionic conductivity and structural stability, sodium superionic conductor (NASICON) materials especially utilizing multivalent redox reaction of vanadium are one of the most promising cathodes in sodium-ion batteries (SIBs). To further boost their application in large-scale energy storage production, a rational strategy is to tailor vanadium with earth-abundant and cheap elements (such as Fe, Mn), reducing the cost and toxicity of vanadium-based NASICON materials. Here, the Na3.05V1.03Fe0.97(PO4)(3) (NVFP) is synthesized with highly conductive Ketjen Black (KB) by ball-milling assisted sol-gel method. The pearl-like KB branch chains encircle the NVFP (p-NVFP), the segregated particles possess promoted overall conductivity, balanced charge, and modulated crystal structure during electrochemical progress. The p-NVFP obtains significantly enhanced ion diffusion ability and low volume change (2.99%). Meanwhile, it delivers a durable cycling performance (87.7% capacity retention over 5000 cycles at 5 C) in half cells. Surprisingly, the full cells of p-NVFP reveal a remarkable capability of 84.9 mAh g(-1) at 20 C with good cycling performance (capacity decay rate is 0.016% per cycle at 2 C). The structure modulation of the p-NVFP provides a rational design on the superiority of others to be put into practice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202301308", "DOI Link": "http://dx.doi.org/10.1002/advs.202301308", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973253800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, P; Wang, TY; He, D; Shi, T; Chen, MF; Fang, K; Lin, HZ; Wang, J; Wang, CY; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Peng; Wang, Tianyi; He, Di; Shi, Ting; Chen, Manfang; Fang, Kan; Lin, Hongzhen; Wang, Jian; Wang, Chengyin; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Delocalized Isoelectronic Heterostructured FeCoOxSy Catalysts with Tunable Electron Density for Accelerated Sulfur Redox Kinetics in Li-S batteries", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High interconversion energy barriers, depressive reaction kinetics of sulfur species, and sluggish Li+ transport inhibit the wide development of high-energy-density lithium sulfur (Li-S) batteries. Herein, differing from random mixture of selected catalysts, the composite catalyst with outer delocalized isoelectronic heterostructure (DIHC) is proposed and optimized, enhancing the catalytic efficiency for decreasing related energy barriers. As a proof-of-content, the FeCoOxSy composites with different degrees of sulfurization are fabricated by regulating atoms ratio between O and S. The relationship of catalytic efficiency and principal mechanism in DIHCs are deeply understood from electrochemical experiments to in situ/operando spectral spectroscopies i.e., Raman, XRD and UV/Vis. Consequently, the polysulfide conversion and Li2S precipitation/dissolution experiments strongly demonstrate the volcano-like catalytic efficiency of various DIHCs. Furthermore, the FeCoOxSy-decorated cell delivers the high performance (1413 mAh g(-1) at 0.1 A g(-1)). Under the low electrolyte/sulfur ratio, the high loading cell stabilizes the areal capacity of 6.67 mAh cm(-2) at 0.2 A g(-1). Impressively, even resting for about 17 days for possible polysulfide shuttling, the high-mass-loading FeCoOxSy-decorated cell stabilizes the same capacity, showing the practical application of the DIHCs in improving catalytic efficiency and reaching high electrochemical performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2023, "Volume": 62, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202311693", "DOI Link": "http://dx.doi.org/10.1002/anie.202311693", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001086863300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, MJ; Okawachi, Y; Cheng, R; Wang, C; Zhang, M; Gaeta, AL; Loncar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Mengjie; Okawachi, Yoshitomo; Cheng, Rebecca; Wang, Cheng; Zhang, Mian; Gaeta, Alexander L.; Loncar, Marko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman lasing and soliton mode-locking in lithium niobate microresonators", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent advancement in lithium-niobite-on-insulator (LNOI) technology is opening up new opportunities in optoelectronics, as devices with better performance, lower power consumption and a smaller footprint can be realised due to the high optical confinement in the structures. The LNOI platform offers both large chi((2)) and chi((3)) nonlinearities along with the power of dispersion engineering, enabling brand new nonlinear photonic devices and applications for the next generation of integrated photonic circuits. However, Raman scattering and its interaction with other nonlinear processes have not been extensively studied in dispersion-engineered LNOI nullodevices. In this work, we characterise the Raman radiation spectra in a monolithic lithium niobate (LN) microresonator via selective excitation of Raman-active phonon modes. The dominullt mode for the Raman oscillation is observed in the backward direction for a continuous-wave pump threshold power of 20 mW with a high differential quantum efficiency of 46%. We explore the effects of Raman scattering on Kerr optical frequency comb generation. We achieve mode-locked states in an X-cut LNOI chip through sufficient suppression of the Raman effect via cavity geometry control. Our analysis of the Raman effect provides guidance for the development of future chip-based photonic devices on the LNOI platform. Lithium niobate on insulator: the Raman effect Better understanding, and thus control, of lithium niobate interactions with light could guide the development of an optical device that measures time even more precisely than atomic clocks. Marko Loncar of Harvard University and colleagues studied how light scatters when laser light is pumped into an optical cavity made from lithium niobate, a synthetic crystal widely used in optical materials. Their findings suggested that changing the shape of the lithium niobate cavity could help them suppress 'Raman scattering', a type of energy transfer that happens when light interacts with the material's molecules. When laser light was shone through the specially tuned cavity, it exited in the form of light pulses of extremely short duration. The findings could guide the development of optical devices that can more precisely measure standard units such as distance and time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 20", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9, "DOI": "10.1038/s41377-020-0246-7", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0246-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511410000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seppala, JE; Migler, KD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seppala, Jonathan E.; Migler, Kalman D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared thermography of welding zones produced by polymer extrusion additive manufacturing", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In common thermoplastic additive manufacturing (AM) processes, a solid polymer filament is melted, extruded though a rastering nozzle, welded onto neighboring layers and solidified. The temperature of the polymer at each of these stages is the key parameter governing these non-equilibrium processes, but due to its strong spatial and temporal variations, it is difficult to measure accurately. Here we utilize infrared (IR) imaging - in conjunction with necessary reflection corrections and calibration procedures - to measure these temperature profiles of a model polymer during 3D printing. From the temperature profiles of the printed layer (road) and sublayers, the temporal profile of the crucially important weld temperatures can be obtained. Under typical printing conditions, the weld temperature decreases at a rate of approximately 100 degrees C/s and remains above the glass transition temperature for approximately 1 s. These measurement methods are a first step in the development of strategies to control and model the printing processes and in the ability to develop models that correlate critical part strength with material and processing parameters. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2016, "Volume": 12, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 76, "Article Number": null, "DOI": "10.1016/j.addma.2016.06.007", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2016.06.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435752000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schoen, MAW; Thonig, D; Schneider, ML; Silva, TJ; Nembach, HT; Eriksson, O; Karis, O; Shaw, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schoen, Martin A. W.; Thonig, Danny; Schneider, Michael L.; Silva, T. J.; Nembach, Hans T.; Eriksson, Olle; Karis, Olof; Shaw, Justin M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-low magnetic damping of a metallic ferromagnet", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic damping is of critical importance for devices that seek to exploit the electronic spin degree of freedom, as damping strongly affects the energy required and speed at which a device can operate. However, theory has struggled to quantitatively predict the damping, even in common ferro-magnetic materials(1-3). This presents a challenge for a broad range of applications in spintronics(4) and spin-orbitronics that depend on materials and structures with ultra-low dampine(5,6). It is believed that achieving ultra-low damping in metallic ferromagnets is limited by the scattering of magnons by the conduction electrons. However, we report on a binary alloy of cobalt and iron that overcomes this obstacle and exhibits a damping parameter approaching 10(-4), which is comparable to values reported only for ferrimagnetic insulators(7,8). We explain this phenomenon by a unique feature of the band structure in this system: the density of states exhibits a sharp minimum at the Fermi level at the same alloy concentration at which the minimum in the magnetic damping is found. This discovery provides both a significant fundamental understanding of damping mechanisms and a test of the theoretical predictions proposed by Mankovsky and colleagues(3).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 839, "End Page": 842, "Article Number": null, "DOI": "10.1038/nphys3770", "DOI Link": "http://dx.doi.org/10.1038/nphys3770", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383219800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, FY; Jiang, XN; Wang, Y; Ren, JN; Xu, BB; Gao, GY; Huang, ZH; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Fuyan; Jiang, Xiaona; Wang, Yao; Ren, Juanna; Xu, Ben Bin; Gao, Guoyang; Huang, Zhanhua; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-rich biochar enhanced Z-scheme heterojunctioned bismuth tungstate/bismuth oxyiodide removing tetracycline", "Source Title": "INORGANIC CHEMISTRY FRONTIERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic treatment of antibiotics in aqueous ecosystems has become a promising method. However, the low efficiency photogenerated charge separation and slow kinetics of the catalyst severely limit its deployment for industrial applications. Here, the three-dimensional bismuth tungstate (Bi2WO6)/bismuth oxyiodide (BiOI) loaded on biochar (BC/BWI) composite catalyst was designed for the efficient removal of tetracycline (adsorption capacity: 227.09 mg g-1, removal rate: 99.8%). Via construction of Z-scheme heterojunctions at the interface of Bi2WO6 and BiOI, the built-in electric field promotes the directional separation of photogenerated carriers to achieve efficient separation and utilization of photogenerated charges. Meanwhile, the introduction of electron-rich biochar (BC) effectively enhances the adsorption performance, photogenerated electron migration capacity and mass transfer process of the material. The introduction of BC and the building of Z-scheme heterojunctions effectively achieve the spatially synergistic separation of photogenerated charges. The O2- dominates the photocatalytic process, according to the mechanistic studies. The degradation intermediate product testing revealed that tetracycline is efficiently degraded through two main pathways. This work provides ideas for the design of catalysts for the efficient removal of antibiotics from water bodies. In the synthesized BC/BWI catalyst, the introduction of biochar and construction of Z-type heterojunctions accelerated the photogenerated carrier separation to reach an efficient removal of tetracycline.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 10", "Publication Year": 2023, "Volume": 10, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6045, "End Page": 6057, "Article Number": null, "DOI": "10.1039/d3qi01283b", "DOI Link": "http://dx.doi.org/10.1039/d3qi01283b", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059646100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bastek, JH; Kumar, S; Telgen, B; Glaesener, RN; Kochmann, DM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bastek, Jan-Hendrik; Kumar, Siddhant; Telgen, Bastian; Glaesener, Raphael N.; Kochmann, Dennis M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inverting the structure-property map of truss metamaterials by deep learning", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by crystallography, the periodic assembly of trusses into architected materials has enjoyed popularity for more than a decade and produced countless cellular structures with beneficial mechanical properties. Despite the successful and steady enrichment of the truss design space, the inverse design has remained a challenge: While predicting effective truss properties is now commonplace, efficiently identifying architectures that have homogeneous or spatially varying target properties has remained a roadblock to applications from lightweight structures to biomimetic implants. To overcome this gap, we propose a deep-learning framework, which combines neural networks with enforced physical constraints, to predict truss architectures with fully tailored anisotropic stiffness. Trained on millions of unit cells, it covers an enormous design space of topologically distinct truss lattices and accurately identifies architectures matching previously unseen stiffness responses. We demonstrate the application to patient-specific bone implants matching clinical stiffness data, and we discuss the extension to spatially graded cellular structures with locally optimal properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2022, "Volume": 119, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2111505119", "DOI": "10.1073/pnas.2111505119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2111505119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748066000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fico, D; Rizzo, D; Casciaro, R; Corcione, CE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fico, Daniela; Rizzo, Daniela; Casciaro, Raffaele; Esposito Corcione, Carola", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Review of Polymer-Based Materials for Fused Filament Fabrication (FFF): Focus on Sustainability and Recycled Materials", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, Fused Filament Fabrication (FFF), one of the most encouraging additive manufacturing (AM) techniques, has fascinated great attention. Although FFF is growing into a manufacturing device with considerable technological and material innovations, there still is a challenge to convert FFF-printed prototypes into functional objects for industrial applications. Polymer components manufactured by FFF process possess, in fact, low and anisotropic mechanical properties, compared to the same parts, obtained by using traditional building methods. The poor mechanical properties of the FFF-printed objects could be attributed to the weak interlayer bond interface that develops during the layer deposition process and to the commercial thermoplastic materials used. In order to increase the final properties of the 3D printed models, several polymer-based composites and nullocomposites have been proposed for FFF process. However, even if the mechanical properties greatly increase, these materials are not all biodegradable. Consequently, their waste disposal represents an important issue that needs an urgent solution. Several scientific researchers have therefore moved towards the development of natural or recyclable materials for FFF techniques. This review details current progress on innovative green materials for FFF, referring to all kinds of possible industrial applications, and in particular to the field of Cultural Heritage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 141, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 465, "DOI": "10.3390/polym14030465", "DOI Link": "http://dx.doi.org/10.3390/polym14030465", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000759497100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alkauskas, A; Yan, QM; Van de Walle, CG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alkauskas, Audrius; Yan, Qimin; Van de Walle, Chris G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles theory of nonradiative carrier capture via multiphonon emission", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a practical first-principles methodology to determine nonradiative carrier capture coefficients at defects in semiconductors. We consider transitions that occur via multiphonon emission. Parameters in the theory, including electron-phonon coupling matrix elements, are computed consistently using state-of-the-art electronic structure techniques based on hybrid density functional theory. These provide a significantly improved description of bulk band structures, as well as defect geometries and wave functions. In order to properly describe carrier capture processes at charged centers, we put forward an approach to treat the effect of long-range Coulomb interactions on scattering states in the framework of supercell calculations. We also discuss the choice of initial conditions for a perturbative treatment of carrier capture. As a benchmark, we apply our theory to several hole-capturing centers in GaN and ZnO, materials of high technological importance in which the role of defects is being actively investigated. Calculated hole capture coefficients are in good agreement with experimental data. We discuss the insights gained into the physics of defects in wide-band-gap semiconductors, such as the strength of electron-phonon coupling and the role of different phonon modes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2014, "Volume": 90, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75202, "DOI": "10.1103/PhysRevB.90.075202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.075202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341268600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gerber, S; Yang, SL; Zhu, D; Soifer, H; Sobota, JA; Rebec, S; Lee, JJ; Jia, T; Moritz, B; Jia, C; Gauthier, A; Li, Y; Leuenberger, D; Zhang, Y; Chaix, L; Li, W; Jang, H; Lee, JS; Yi, M; Dakovski, GL; Song, S; Glownia, JM; Nelson, S; Kim, KW; Chuang, YD; Hussain, Z; Moore, RG; Devereaux, TP; Lee, WS; Kirchmann, PS; Shen, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gerber, S.; Yang, S. -L.; Zhu, D.; Soifer, H.; Sobota, J. A.; Rebec, S.; Lee, J. J.; Jia, T.; Moritz, B.; Jia, C.; Gauthier, A.; Li, Y.; Leuenberger, D.; Zhang, Y.; Chaix, L.; Li, W.; Jang, H.; Lee, J. -S.; Yi, M.; Dakovski, G. L.; Song, S.; Glownia, J. M.; Nelson, S.; Kim, K. W.; Chuang, Y. -D.; Hussain, Z.; Moore, R. G.; Devereaux, T. P.; Lee, W. -S.; Kirchmann, P. S.; Shen, Z. -X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Femtosecond electron-phonon lock-in by photoemission and x-ray free-electron laser", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interactions that lead to the emergence of superconductivity in iron-based materials remain a subject of debate. It has been suggested that electron-electron correlations enhance electron-phonon coupling in iron selenide (FeSe) and related pnictides, but direct experimental verification has been lacking. Here we show that the electron-phonon coupling strength in FeSe can be quantified by combining two time-domain experiments into a coherent lock-in measurement in the terahertz regime. X-ray diffraction tracks the light-induced femtosecond coherent lattice motion at a single phonon frequency, and photoemission monitors the subsequent coherent changes in the electronic band structure. Comparison with theory reveals a strong enhancement of the coupling strength in FeSe owing to correlation effects. Given that the electron-phonon coupling affects superconductivity exponentially, this enhancement highlights the importance of the cooperative interplay between electron-electron and electron-phonon interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 219, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2017, "Volume": 357, "Issue": 6346, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": 74, "Article Number": null, "DOI": "10.1126/science.aak9946", "DOI Link": "http://dx.doi.org/10.1126/science.aak9946", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000416909500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Been, E; Lee, WS; Hwang, HY; Cui, Y; Zaanen, J; Devereaux, T; Moritz, B; Jia, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Been, Emily; Lee, Wei-Sheng; Hwang, Harold Y.; Cui, Yi; Zaanen, Jan; Devereaux, Thomas; Moritz, Brian; Jia, Chunjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Structure Trends Across the Rare-Earth Series in Superconducting Infinite-Layer Nickelates", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of superconductivity in oxygen-reduced monovalent nickelates has raised a new platform for the study of unconventional superconductivity, with similarities to and differences from the cuprate high-temperature superconductors. In this paper, we investigate the family of infinite-layer nickelates RNiO2 with rare-earth R spanning across the lanthanide series, introducing a new and nontrivial knob with which to tune nickelate superconductivity. When traversing from La to Lu, the out-of-plane lattice constant decreases dramatically with an accompanying increase of Ni d(x2-y2) bandwidth; however, surprisingly, the role of oxygen charge transfer diminishes. In contrast, the magnetic exchange grows across the lanthanides, which may be favorable to superconductivity. Moreover, compensation effects from the itinerant 5d electrons present a closer analogy to Kondo lattices, indicating a stronger interplay between charge transfer, bandwidth renormalization, compensation, and magnetic exchange. We also obtain the microscopic Hamiltonian using the Wannier downfolding technique, which will provide the starting point for further many-body theoretical studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11050, "DOI": "10.1103/PhysRevX.11.011050", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.011050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627595600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, J; Koo, J; Jhon, YM; Lee, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Junsu; Koo, Joonhoi; Jhon, Young Min; Lee, Ju Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A femtosecond pulse erbium fiber laser incorporating a saturable absorber based on bulk-structured Bi2Te3 topological insulator", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We experimentally demonstrate the use of a bulk-structured Bi2Te3 topological insulator (TI) as an ultrafast mode-locker to generate femtosecond pulses from an all-fiberized cavity. Using a saturable absorber based on a mechanically exfoliated layer about 15 mu m thick deposited onto a side-polished fiber, we show that stable soliton pulses with a temporal width of similar to 600 fs can readily be produced at 1547 nm from an erbium fiber ring cavity. Unlike previous TI-based mode-locked laser demonstrations, in which high-quality nullosheet-based TIs were used for saturable absorption, we chose to use a bulk-structured Bi2Te3 layer because it is easy to fabricate. We found that the bulk-structured Bi2Te3 layer can readily provide sufficient nonlinear saturable absorption for femtosecond mode-locking even if its modulation depth of similar to 15.7% is much lower than previously demonstrated nullosheet-structured TI-based saturable absorbers. This experimental demonstration indicates that high-crystalline-quality atomic-layered films of TI, which demand complicated and expensive material processing facilities, are not essential for ultrafast laser mode-locking applications. (C) 2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2014, "Volume": 22, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6165, "End Page": 6173, "Article Number": null, "DOI": "10.1364/OE.22.006165", "DOI Link": "http://dx.doi.org/10.1364/OE.22.006165", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333579200166", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nimaming, N; Sadeghpour, A; Murray, BS; Sarkar, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nimaming, Nisufyan; Sadeghpour, Amin; Murray, Brent S.; Sarkar, Anwesha", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid particles for stabilization of food-grade Pickering emulsions: Fabrication principles and interfacial properties", "Source Title": "TRENDS IN FOOD SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Colloidal particles have garnered considerable research attention in recent times for fabrication of Pickering emulsions (PEs) because of their distinctive ultra-stabilization properties in comparison to conventional emulsion stabilizers. Significant progress has been made in designing novel hybrid particles, i.e., a combination of two or more materials comprising the particles, for tailoring emulsion stability as well as other functionalities that are not achievable with single particle-laden interfaces.Scope and approach: We aim to provide a critical survey of the latest advances in food-grade hybrid particles that have been used to prepare Pickering emulsions in this review with an emphasis on the engineering of hybrid particles through various physical and chemical synthesis routes. In particular, we have examined the hybrid protein-polysaccharide, protein-phenolic compound, polysaccharide-lipid particles that have surfaced in the last five years with respect to their ability to stabilize and provide additional functionalities to PEs. We discuss recent studies on interfacial characterization of hybrid particles using interfacial (tension, rheology, Langmuir Blodgett), adsorption (quartz crystal microbalance with dissipation monitoring), microscopy and X-ray scattering techniques.Key findings and conclusions: Synthesis of hybrid particles primarily depends on the properties of biopolymers: hybrid particles fabricated using water-insoluble biopolymers such as insoluble plant proteins exploit antisolvent precipitation methods, whilst fabrication using water-soluble components usually involve covalent (alkaline treatment/oxidation/Maillard) or ionic interactions. Hybrid particles stabilize PEs via a combination of denser interfacial layer formation as well as bulk stabilization and offer benefits in protection/release of active lipidic ingredients versus single particle stabilizers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 39, "Times Cited, All Databases": 39, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 671, "End Page": 684, "Article Number": null, "DOI": "10.1016/j.tifs.2023.06.034", "DOI Link": "http://dx.doi.org/10.1016/j.tifs.2023.06.034", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001046998400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raoui, Y; Ez-Zahraouy, H; Tahiri, N; El Bounagui, O; Ahmad, S; Kazim, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raoui, Yassine; Ez-Zahraouy, Hamid; Tahiri, Najim; El Bounagui, Omar; Ahmad, Shahzada; Kazim, Samrana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance analysis of MAPbI3 based perovskite solar cells employing diverse charge selective contacts: Simulation study", "Source Title": "SOLAR ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid development in the field of organo-metal halide perovskite solar cells (PSCs) has led to the report of power conversion efficiency of > 25%. However, their large-scale deployment and possible commercialization endeavor are currently limited due to the presence of high-temperature processed electron transport material (ETM) such as TiO2 and the expensive hole transport material (HTM) in the state-of-the-art devices. By employing Solar Cell Capacitance Simulator (SCAPS)-1D, we attempted to propose low cost charge selective materials as ETM and HTM, which can deliver high photovoltaic performance. For this, the evaluation of TiO2, ZnO and SnO2 as ETMs was validated. Besides this, the role of thickness of ETMs was also investigated in a PSCs using CH3NH3PbI3 as light harvester and Spiro-OMeTAD as HTM. Our simulation results suggests that 90 nm of SnO2 layer outperforms as ETM for device fabrication. Furthermore, in our pursuit to avoid the usage of Spiro-OMeTAD, different organic and inorganic HTMs (P3HT, CuSbS2, Cu2O, CuSCN) have been investigated, and specifically the HTM thickness was optimized for high performance. We have found that by using the configuration of FICO/SnO2 (90 nm)/MAPbI(3)/CuSCN (100 nm)/Au a PCE of 26.74% with a V-oc of 1180 mV can be acheived. The role of metal cathode work function was also studied to replace the expensive gold (Au) electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 193, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 948, "End Page": 955, "Article Number": null, "DOI": "10.1016/j.solener.2019.10.009", "DOI Link": "http://dx.doi.org/10.1016/j.solener.2019.10.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498747800088", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, C; Liu, XL; Wang, JP; Chen, FQ; Cheng, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Chao; Liu, Xiaoling; Wang, Jiapei; Chen, Fengqiu; Cheng, Dang-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterostructuring 2D Co2P nullosheets with 0D CoP via a salt-assisted strategy for boosting hydrogen evolution from ammonia borane hydrolysis", "Source Title": "nullO RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ammonia borane (NH3BH3, AB) holds promise for chemical storage of hydrogen. However, designing superb and low-cost photocatalyst to drive hydrogen evolution from AB under visible light irradiation is highly desirable but remains a major challenge for promoting the practical utilization of AB. Herein, we demonstrated a heterostructure photocatalyst consisting of zerodimensional (0D) CoP nulloparticles immobilized on two-dimensional (2D) Co2P nullosheets (CoP/Co(2)Ps) as a high-performance and low-cost catalyst for hydrogen evolution from AB hydrolysis, in which 0D/2D heterostructure was synthesized using the saltinduced phase transformation strategy. Interestingly, the optimized CoP/Co(2)Ps exhibit a robust H-2 evolution rate of 32.1 L.min(-1).gCo(-1), corresponding to a turnover frequency (TOF) value of 64.1 min(-1), being among the highest TOF for non-noblemetal catalysts ever reported, even outperforming some precious metal catalysts. This work not only opens a new avenue to accelerate hydrogen evolution from AB by regulating the electronic structures of heterointerfaces, but also provides a novel strategy for the construction of precious-metal-free materials for hydrogen-related energy catalysis in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 47, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 16, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6260, "End Page": 6269, "Article Number": null, "DOI": "10.1007/s12274-023-5388-5", "DOI Link": "http://dx.doi.org/10.1007/s12274-023-5388-5", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000915438800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, YT; Zhu, JQ; Long, X; Zhao, LG; Chen, CT; Liu, CQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Yutai; Zhu, Jiaqi; Long, Xu; Zhao, Liguo; Chen, Chuantong; Liu, Changqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Statistical effects of pore features on mechanical properties and fracture behaviors of heterogeneous random porous materials by phase-field modeling", "Source Title": "INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous materials with randomly distributed pores are ubiquitous, such as sintered silver nulloparticles, concrete materials, 3D printed polymers, and natural bones. Recent experimental investigations have revealed that porosity and also pore-related geometries (size, number, shape, distribution and alignment) have significant impacts on the mechanical behavior of random porous materials. However, existing studies focus on the porosity effect while ignoring other pore features such as pore size and pore shape. Our research is dedicated to a computational framework for generating isotropic/anisotropic random porous materials using Gaussian random fields with stochastic pore size and shape factor and addressing the mechanical properties and behavior of brittle fractures using a fracture phase-field model with a preferred degradation function. Sintered silver nulloparticles with typical randomly distributed pores, as representative porous materials, are chosen for their promising applications in emerging fields such as power electronics and wearable devices. In order to emphasize the effect of pore size and shape, 420 random samples with a fixed porosity were generated to discuss the stress-strain response during fracture and to establish statistical relationships between pore feature distributions and me-chanical properties such as Young's modulus, UTS, and average historical energy. Our findings suggest that the statical attributes of the pore sizes and shape factors significantly affect the material performance related to the mechanical properties and fracture behavior, which could give a better understanding of the random porous materials and guide reliability-based material design optimization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 101, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 264, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112098, "DOI": "10.1016/j.ijsolstr.2022.112098", "DOI Link": "http://dx.doi.org/10.1016/j.ijsolstr.2022.112098", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923459300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, T; Kindem, JM; Bartholomew, JG; Rochman, J; Craiciu, I; Miyazono, E; Bettinelli, M; Cavalli, E; Verma, V; Nam, SW; Marsili, F; Shaw, MD; Beyer, AD; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Tian; Kindem, Jonathan M.; Bartholomew, John G.; Rochman, Jake; Craiciu, Ioana; Miyazono, Evan; Bettinelli, Marco; Cavalli, Enrico; Verma, Varun; Nam, Sae Woo; Marsili, Francesco; Shaw, Matthew D.; Beyer, Andrew D.; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullophotonic rare-earth quantum memory with optically controlled retrieval", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical quantum memories are essential elements in quantum networks for long-distance distribution of quantum entanglement. Scalable development of quantum network nodes requires on-chip qubit storage functionality with control of the readout time. We demonstrate a high-fidelity nullophotonic quantum memory based on a mesoscopic neodymium ensemble coupled to a photonic crystal cavity. The nullocavity enables > 95% spin polarization for efficient initialization of the atomic frequency comb memory and time bin-selective readout through an enhanced optical Stark shift of the comb frequencies. Our solid-state memory is integrable with other chip-scale photon source and detector devices for multiplexed quantum and classical information processing at the network nodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 281, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 29", "Publication Year": 2017, "Volume": 357, "Issue": 6358, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1392, "End Page": 1395, "Article Number": null, "DOI": "10.1126/science.aan5959", "DOI Link": "http://dx.doi.org/10.1126/science.aan5959", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411880800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, M; Xu, XP; Duan, YW; Yu, LY; Li, RP; Peng, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Min; Xu, Xiaopeng; Duan, Yuwei; Yu, Liyang; Li, Ruipeng; Peng, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Y-Type Non-Fullerene Acceptors with Outer Branched Side Chains and Inner Cyclohexane Side Chains for 19.36% Efficiency Polymer Solar Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Raising the lowest unoccupied molecular orbital (LUMO) energy level of Y-type non-fullerene acceptors can increase the open-circuit voltage (V-oc) and thus the photovoltaic performance of the current top performing polymer solar cells (PSCs). One of the viable routes is demonstrated by the successful Y6 derivative of L8-BO with the branched alkyl chains at the outer side. This will introduce steric hindrance and reduce intermolecular aggregation, thus open up the bandgap and raise the LUMO energy level. To take further advantages of the steric hindrance influence on optoelectronic properties of Y6 derivatives, two Y-type non-fullerene acceptors of BTP-Cy-4F and BTP-Cy-4Cl are designed and synthesized by adopting outer branched side chains and inner cyclohexane side chains. An outstanding V-oc of 0.937 V is achieved in the D18:BTP-Cy-4F binary blend devices along with a power conversion efficiency (PCE) of 18.52%. With the addition of BTP-eC9 to extend the absorption spectral coverage, a remarkable PCE of 19.36% is realized finally in the related ternary blend devices, which is one of the highest values for single-junction PSCs at present. The results illustrate the great potential of cyclohexane side chains in constructing high-performance non-fullerene acceptors and their PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 35, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202210760", "DOI Link": "http://dx.doi.org/10.1002/adma.202210760", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000914044700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, Y; Li, GY; Zhou, HM; Zhang, GL; Guo, L; Guo, ZH; Yang, RA; Fan, YQ; Wang, WL; Du, Y; Dang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Yang; Li, Gaoyang; Zhou, Huimin; Zhang, Guoliang; Guo, Liang; Guo, Zhanhu; Yang, Ruonull; Fan, Yuqi; Wang, Weiliang; Du, Yong; Dang, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stable Garnet Fe2Mo3O12 Cathode Boosts the Lithium-Air Battery Performance Featuring a Polyhedral Framework and Cationic Vacancy Concentrated Surface", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-air batteries (LABs), owing to their ultrahigh theoretical energy density, are recognized as one of the next-generation energy storage techniques. However, it remains a tricky problem to find highly active cathode catalyst operating within ambient air. In this contribution, a highly active Fe2Mo3O12 (FeMoO) garnet cathode catalyst for LABs is reported. The experimental and theoretical analysis demonstrate that the highly stable polyhedral framework, composed of Fe-O octahedrons and M-O tetrahedrons, provides a highly effective air catalytic activity and long-term stability, and meanwhile keeps good structural stability. The FeMoO electrode delivers a cycle life of over 1800 h by applying a simple half-sealed condition in ambient air. It is found that surface-rich Fe vacancy can act as an O-2 pump to accelerate the catalytic reaction. Furthermore, the FeMoO catalyst exhibits a superior catalytic capability for the decomposition of Li2CO3. H2O in the air can be regarded as the main contribution to the anode corrosion and the deterioration of LAB cells could be attributed to the formation of LiOH center dot H2O at the end of cycling. The present work provides in-depth insights to understand the catalytic mechanism in air and constitutes a conceptual breakthrough in catalyst design for efficient cell structure in practical LABs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 10, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300482", "DOI Link": "http://dx.doi.org/10.1002/advs.202300482", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937758400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Waldecker, L; Bertoni, R; Ernstorfer, R; Vorberger, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Waldecker, Lutz; Bertoni, Roman; Ernstorfer, Ralph; Vorberger, Jan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-Phonon Coupling and Energy Flow in a Simple Metal beyond the Two-Temperature Approximation", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electron-phonon coupling and the corresponding energy exchange are investigated experimentally and by ab initio theory in nonequilibrium states of the free-electron metal aluminium. The temporal evolution of the atomic mean-squared displacement in laser-excited thin freestanding films is monitored by femtosecond electron diffraction. The electron-phonon coupling strength is obtained for a range of electronic and lattice temperatures from density functional theory molecular dynamics simulations. The electron-phonon coupling parameter extracted from the experimental data in the framework of a two-temperature model (TTM) deviates significantly from the ab initio values. We introduce a nonthermal lattice model (NLM) for describing nonthermal phonon distributions as a sum of thermal distributions of the three phonon branches. The contributions of individual phonon branches to the electron-phonon coupling are considered independently and found to be dominated by longitudinal acoustic phonons. Using all material parameters from first-principles calculations except the phonon-phonon coupling strength, the prediction of the energy transfer from electrons to phonons by the NLM is in excellent agreement with time-resolved diffraction data. Our results suggest that the TTM is insufficient for describing the microscopic energy flow even for simple metals like aluminium and that the determination of the electron-phonon coupling constant from time-resolved experiments by means of the TTM leads to incorrect values. In contrast, the NLM describing transient phonon populations by three parameters appears to be a sufficient model for quantitatively describing electron-lattice equilibration in aluminium. We discuss the general applicability of the NLM and provide a criterion for the suitability of the two-temperature approximation for other metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2016, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21003, "DOI": "10.1103/PhysRevX.6.021003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.6.021003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373586300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, P; Yin, ZY; Wang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pei; Yin, Zhen-Yu; Wang, Zi-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Micromechanical Investigation of Particle-Size Effect of Granular Materials in Biaxial Test with the Role of Particle Breakage", "Source Title": "JOURNAL OF ENGINEERING MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the effect of particle size on the shear strength of granular materials is important for geotechnical design and construction. However, previous studies show contradicting results on the relationship between particle size and shear strength. Additionally, the effect of particle breakage on this relationship has not been fully revealed. In this study, a series of biaxial tests have been simulated with the discrete element method to explore the particle-size effect of sand considering the role of particle breakage. The sand specimens have parallel particle-size distributions. The sequential breakage model has been used to simulate particle breakage, which is a combination of replacement and cluster methods. The main conclusions of this study are: (1) the relationship of peak shear strength and particle size depends on the crushability of particles and relative density of specimens; (2) the particle size and crushability have a very slight effect on the residual shear strength; and (3) at the microscale, the relationship between shear strength and particle size is positively related to the friction utilization ratio.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2022, "Volume": 148, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4021133, "DOI": "10.1061/(ASCE)EM.1943-7889.0002039", "DOI Link": "http://dx.doi.org/10.1061/(ASCE)EM.1943-7889.0002039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719533400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZY; Zeng, ZZ; Zhang, CZ; Wang, YZ; Song, KK; Dong, HK; Chen, Y; Nissila, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zheyong; Zeng, Zezhu; Zhang, Cunzhi; Wang, Yanzhou; Song, Keke; Dong, Haikuan; Chen, Yue; Nissila, Tapio Ala", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neuroevolution machine learning potentials: Combining high accuracy and low cost in atomistic simulations and application to heat transport", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a neuroevolution-potential (NEP) framework for generating neural network-based machine-learning potentials. They are trained using an evolutionary strategy for performing large-scale molecular dynamics (MD) simulations. A descriptor of the atomic environment is constructed based on Chebyshev and Legendre polynomials. The method is implemented in graphic processing units within the open-source GPUMD package, which can attain a computational speed over 10(7) atom-step per second using one Nvidia Tesla V100. Furthermore, per-atom heat current is available in NEP, which paves the way for efficient and accurate MD simulations of heat transport in materials with strong phonon anharmonicity or spatial disorder, which usually cannot be accurately treated either with traditional empirical potentials or with perturbative methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2021, "Volume": 104, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104309, "DOI": "10.1103/PhysRevB.104.104309", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.104.104309", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000704410100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anderson, JA; Glaser, J; Glotzer, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anderson, Joshua A.; Glaser, Jens; Glotzer, Sharon C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "HOOMD-blue: A Python package for high-performance molecular dynamics and hard particle Monte Carlo simulations", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HOOMD-blue is a particle simulation engine designed for nullo- and colloidal-scale molecular dynamics and hard particle Monte Carlo simulations. It has been actively developed since March 2007 and available open source since August 2008. HOOMD-blue is a Python package with a high performance C++/CUDA backend that we built from the ground up for GPU acceleration. The Python interface allows users to combine HOOMD-blue with other packages in the Python ecosystem to create simulation and analysis workflows. We employ software engineering practices to develop, test, maintain, and expand the code.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 425, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2020, "Volume": 173, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 109363, "DOI": "10.1016/j.commatsci.2019.109363", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2019.109363", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506172700065", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, PF; Li, JY; Han, JZ; Wan, XG; Liu, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Pengfei; Li, Jiayu; Han, Jingzhi; Wan, Xiangang; Liu, Qihang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-Group Symmetry in Magnetic Materials with Negligible Spin-Orbit Coupling", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Symmetry formulated by group theory plays an essential role with respect to the laws of nature, from fundamental particles to condensed-matter systems. Here, by combining symmetry analysis and model calculations, we elucidate that the crystallographic symmetry groups of a vast number of magnetic materials with light elements, in which the neglect of relativistic spin-orbit coupling (SOC) is an appropriate approximation, are considerably larger than the conventional magnetic groups. Thus, a symmetry description that involves partially decoupled spin and spatial rotations, dubbed spin group, is required. We derive the classifications of spin point groups describing coplanar and collinear magnetic structures, and the irreducible corepresentations of spin space groups illustrating more energy degeneracies that are disallowed by magnetic groups. One consequence of the spin group is the new antiunitary symmetries that protect SOC-free Z(2) topological phases with unprecedented surface-node structures. Our work not only manifests the physical reality of materials with weak SOC, but also sheds light on the understanding of all solids with and without SOC by a unified group theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2022, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21016, "DOI": "10.1103/PhysRevX.12.021016", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.12.021016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798381200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kusenberg, M; Eschenbacher, A; Djokic, MR; Zayoud, A; Ragaert, K; De Meester, S; Van Geem, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kusenberg, Marvin; Eschenbacher, Andreas; Djokic, Marko R.; Zayoud, Azd; Ragaert, Kim; De Meester, Steven; Van Geem, Kevin M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Opportunities and challenges for the application of post-consumer plastic waste pyrolysis oils as steam cracker feedstocks: To decontaminate or not to decontaminate?", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermochemical recycling of plastic waste to base chemicals via pyrolysis followed by a minimal amount of upgrading and steam cracking is expected to be the dominullt chemical recycling technology in the coming decade. However, there are substantial safety and operational risks when using plastic waste pyrolysis oils instead of conventional fossil-based feedstocks. This is due to the fact that plastic waste pyrolysis oils contain a vast amount of contaminullts which are the main drivers for corrosion, fouling and downstream catalyst poisoning in industrial steam cracking plants. Contaminullts are therefore crucial to evaluate the steam cracking feasibility of these alternative feedstocks.Indeed, current plastic waste pyrolysis oils exceed typical feedstock specifications for numerous known contaminullts, e.g. nitrogen (-1650 vs. 100 ppm max.), oxygen (-1250 vs. 100 ppm max.), chlorine (-1460 vs. 3 ppm max.), iron (-33 vs. 0.001 ppm max.), sodium (-0.8 vs. 0.125 ppm max.) and calcium (-17 vs. 0.5 ppm max.). Pyrolysis oils produced from post-consumer plastic waste can only meet the current specifications set for industrial steam cracker feedstocks if they are upgraded, with hydrogen based technologies being the most effective, in combination with an effective pre-treatment of the plastic waste such as dehalogenation.Moreover, steam crackers are reliant on a stable and predictable feedstock quality and quantity representing a challenge with plastic waste being largely influenced by consumer behavior, seasonal changes and local sorting efficiencies. Nevertheless, with standardization of sorting plants this is expected to become less problematic in the coming decade.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2022, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 83, "End Page": 115, "Article Number": null, "DOI": "10.1016/j.wasman.2021.11.009", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2021.11.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781133700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Iwasaki, T; Miyamoto, Y; Taniguchi, T; Siyushev, P; Metsch, MH; Jelezko, F; Hatano, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Iwasaki, Takayuki; Miyamoto, Yoshiyuki; Taniguchi, Takashi; Siyushev, Petr; Metsch, Mathias H.; Jelezko, Fedor; Hatano, Mutsuko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tin-Vacancy Quantum Emitters in Diamond", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin-vacancy (Sn-V) color centers were created in diamond via ion implantation and subsequent high-temperature annealing up to 2100 degrees C at 7.7 GPa. The first-principles calculation suggested that a large atom of tin can be incorporated into a diamond lattice with a split-vacancy configuration, in which a tin atom sits on an interstitial site with two neighboring vacancies. The Sn-V center showed a sharp zero phonon line at 619 nm at room temperature. This line split into four peaks at cryogenic temperatures, with a larger ground state splitting (similar to 850 GHz) than that of color centers based on other group-IV elements, i.e., silicon-vacancy (Si-V) and germanium-vacancy (Ge-V) centers. The excited state lifetime was estimated, via Hanbury Brown-Twiss interferometry measurements on single Sn-V quantum emitters, to be similar to 5 ns. The order of the experimentally obtained optical transition energies, compared with those of Si-V and Ge-V centers, was in good agreement with the theoretical calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2017, "Volume": 119, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 253601, "DOI": "10.1103/PhysRevLett.119.253601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.253601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418619100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bandyopadhyay, A; Traxel, KD; Lang, M; Juhasz, M; Eliaz, N; Bose, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bandyopadhyay, Amit; Traxel, Kellen D.; Lang, Melanie; Juhasz, Michael; Eliaz, Noam; Bose, Susmita", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloy design via additive manufacturing: Advantages, challenges, applications and perspectives", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) has rapidly changed both large-and small-scale production environments across many industries. By re-envisioning parts from the ground up, not limited to the challenges presented by traditional manufacturing techniques, researchers and engineers have developed new design strategies to solve large-scale materials and design problems worldwide. This is particularly true in the world of alloy design, where new metallic materials have historically been developed through tedious processes and procedures based primarily on casting methodologies. With the onset of directed energy deposition (DED) and powder bed fusion (PBF)-based AM, new alloys can be innovated and evaluated rapidly at a lower cost and considerably shorter lead time than has ever been achieved. This article details the advantages, challenges, applications, and perspectives of alloy design using primarily laser-based AM. It is envisioned that researchers in industry and academia can utilize this work to design new alloys leveraging metallic AM processes for various current and future applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 160, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2022, "Volume": 52, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 207, "End Page": 224, "Article Number": null, "DOI": "10.1016/j.mattod.2021.11.026", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2021.11.026", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789350200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, JJ; Lopes, JG; Zeng, Z; Choi, YT; Maawad, E; Schell, N; Kim, HS; Mishra, RS; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Jiajia; Lopes, J. G.; Zeng, Zhi; Choi, Yeon Taek; Maawad, E.; Schell, N.; Kim, Hyoung Seop; Mishra, Rajiv S.; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deformation behavior and strengthening effects of an eutectic AlCoCrFeNi2.1 high entropy alloy probed by in-situ synchrotron X-ray diffraction and post-mortem EBSD", "Source Title": "MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, high energy synchrotron X-ray diffraction was used during tensile testing of an as-cast eutectic AlCoCrFeNi2.1 high entropy alloy. Aside, from determining for the first time the volume fractions of existing phases, we further detail their role on the alloy deformation behavior. The two major phases, a soft disordered FCC and a hard ordered B2 BCC, were observed to exhibit a stress partitioning effect which can be used to modulate the mechanical response of the material based on the relative volume fraction of each phase. Dislo-cation density analysis revealed that the soft FCC phase had a significantly higher dislocation density right after the onset of plastic deformation. This is attributed to the existence of strain gradients across the lamellar structure, where the hard B2 BCC prevents free deformation of the FCC phase. Nonetheless, despite the increase of the dislocation density in the soft FCC phase, calculations of the strengthening effects induced by generation of dislocations are more significant in the hard B2 BCC phases, as this phase is primarily responsible for the strength increase in the alloy. Besides, the evolutions in dislocation density of the soft FCC and hard B2 BCC phases during tensile deformation obtained from synchrotron X-ray diffraction data are consistent with the evolution of KAM determined by EBSD characterization. Also, lattice strain analysis across two principal directions (parallel and perpendicular to the loading axis) reveals that for these specific orientations there is a preferential deformation of the hard FCC planes which can be related to the deformation response of specific lattice planes at distinct ori-entations, as well as to the phase partitioning stress behavior.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2023, "Volume": 872, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144946, "DOI": "10.1016/j.msea.2023.144946", "DOI Link": "http://dx.doi.org/10.1016/j.msea.2023.144946", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001029579200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Wang, Z; Zou, NL; Ye, M; Xu, RZ; Gong, XX; Duan, WH; Xu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, He; Wang, Zun; Zou, Nianlong; Ye, Meng; Xu, Runzhang; Gong, Xiaoxun; Duan, Wenhui; Xu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep-learning density functional theory Hamiltonian for efficient ab initio electronic-structure calculation", "Source Title": "NATURE COMPUTATIONAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The marriage of density functional theory (DFT) and deep-learning methods has the potential to revolutionize modern computational materials science. Here we develop a deep neural network approach to represent the DFT Hamiltonian (DeepH) of crystalline materials, aiming to bypass the computationally demanding self-consistent field iterations of DFT and substantially improve the efficiency of ab initio electronic-structure calculations. A general framework is proposed to deal with the large dimensionality and gauge (or rotation) covariance of the DFT Hamiltonian matrix by virtue of locality, and this is realized by a message-passing neural network for deep learning. High accuracy, high efficiency and good transferability of the DeepH method are generally demonstrated for various kinds of material system and physical property. The method provides a solution to the accuracy-efficiency dilemma of DFT and opens opportunities to explore large-scale material systems, as evidenced by a promising application in the study of twisted van der Waals materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 367, "End Page": 377, "Article Number": null, "DOI": "10.1038/s43588-022-00265-6", "DOI Link": "http://dx.doi.org/10.1038/s43588-022-00265-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888208100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Z; Chen, X; Jia, ZY; Zhou, GQ; Xu, JQ; Wu, YX; Xia, XX; Li, XF; Zhang, XN; Deng, C; Zhang, Y; Lu, XH; Liu, WM; Zhang, CF; Yang, Y; Zhu, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zeng; Chen, Xu; Jia, Ziyan; Zhou, Guanqing; Xu, Jianqiu; Wu, Yuexia; Xia, Xinxin; Li, Xufeng; Zhang, Xuning; Deng, Chao; Zhang, Yuan; Lu, Xinhui; Liu, Weimin; Zhang, Chunfeng; Yang, Yang (Michael); Zhu, Haiming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triplet exciton formation for non-radiative voltage loss in high-efficiency nonfullerene organic solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nonfullerene acceptor (NFA) organic solar cells (OSCs) with power conversion efficiency (PCE) reaching up to 18% has shown tremendous potential toward practical applications. However, the non-radiative recombination loss in high-efficiency NFA OSCs is evidently large, and the origin remains unclear. Herein, by combining transient absorption spectroscopy, photovoltaic characterization, and detailed energy loss analysis, we unambiguously show the formation of NFA triplet exciton from free carrier recombination as a main non-radiative recombination and energy loss channel. More importantly, in contrast to the previous energetics point of view, we show side-chain fluorination in high-efficiency NFA OSCs has little effect on charge transfer energy landscapes but efficiently inhibits charge recombination to NFA triplet excitons, leading to higher V-OC and PCE. Our findings provide a new view about energy loss in NFA OSCs and pave the way toward OSCs with lower V-OC loss and efficiency exceeding 20%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 125, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2021, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1832, "End Page": 1844, "Article Number": null, "DOI": "10.1016/j.joule.2021.04.002", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.04.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000675889700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prychynenko, D; Sitte, M; Litzius, K; Krüger, B; Bourianoff, G; Kläui, M; Sinova, J; Everschor-Sitte, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prychynenko, Diana; Sitte, Matthias; Litzius, Kai; Krueger, Benjamin; Bourianoff, George; Klaeui, Mathias; Sinova, Jairo; Everschor-Sitte, Karin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic Skyrmion as a Nonlinear Resistive Element: A Potential Building Block for Reservoir Computing", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inspired by the human brain, there is a strong effort to find alternative models of information processing capable of imitating the high energy efficiency of neuromorphic information processing. One possible realization of cognitive computing involves reservoir computing networks. These networks are built out of nonlinear resistive elements which are recursively connected. We propose that a Skyrmion network embedded in magnetic films may provide a suitable physical implementation for reservoir computing applications. The significant key ingredient of such a network is a two-terminal device with nonlinear voltage characteristics originating from magnetoresistive effects, such as the anisotropic magnetoresistance or the recently discovered noncollinear magnetoresistance. The most basic element for a reservoir computing network built from Skyrmion fabrics is a single Skyrmion embedded in a ferromagnetic ribbon. In order to pave the way towards reservoir computing systems based on Skyrmion fabrics, we simulate and analyze (i) the current flow through a single magnetic Skyrmion due to the anisotropic magnetoresistive effect and (ii) the combined physics of local pinning and the anisotropic magnetoresistive effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2018, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14034, "DOI": "10.1103/PhysRevApplied.9.014034", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.9.014034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423660800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SY; Yang, H; Derunova, E; Parkin, SSP; Yan, BH; Ali, MN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuo-Ying; Yang, Hao; Derunova, Elena; Parkin, Stuart S. P.; Yan, Binghai; Ali, Mazhar N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symmetry demanded topological nodal-line materials", "Source Title": "ADVANCES IN PHYSICS-X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The realization of Dirac and Weyl physics in solids has made topological materials one of the main focuses of condensed matter physics. Recently, the topic of topological nodal line semimetals, materials in which Dirac or Weyl-like crossings along special lines in momentum space create either a closed ring or line of degeneracies, rather than discrete points, has become a hot topic in topological quantum matter. Here, we review the experimentally confirmed and theoretically predicted topological nodal line semimetals, focusing in particular on the symmetry protection mechanisms of the nodal lines in various materials. Three different mechanisms: a combination of inversion and time-reversal symmetry, mirror reflection symmetry, and non-symmorphic symmetry and their robustness under the effect of spin orbit coupling are discussed. We also present a new Weyl nodal line material, the Te-square net compound KCu. Finally, we discuss potential experimental signatures for observing exotic properties of nodal line physics. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "UNSP 1414631", "DOI": "10.1080/23746149.2017.1414631", "DOI Link": "http://dx.doi.org/10.1080/23746149.2017.1414631", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434402100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saberian, M; Li, J; Kilmartin-Lynch, S; Boroujeni, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saberian, Mohammad; Li, Jie; Kilmartin-Lynch, Shannon; Boroujeni, Mahdi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Repurposing of COVID-19 single-use face masks for pavements base/subbase", "Source Title": "SCIENCE OF THE TOTAL ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The coronavirus (COVID-19) pandemic has not only created a global health crisis, but it is also now threatening the environment. A multidisciplinary collaborative approach is required to fight against the pandemic and reduce the environmental risks associated with the disposal of used personal protective equipment (PPE). This paper explores an innovative way to reduce pandemic-generated waste by recycling the used face masks with other waste materials in civil constructions. In this research, for the first time, a series of experiments, including modified compaction, unconfined compression strength and resilient modulus tests, were conducted on the blends of different percentages of the shredded face mask (SFM) added to the recycled concrete aggregate (RCA) for road base and subbase applications. The experimental results show that RCA mixed with three different percentages (i.e., 1%, 2% and 3%) of SFM satisfied the stiffness and strength requirements for pavements base/subbase. The introduction of the shredded face mask not only increased the strength and stiffness but also improved the ductility and flexibility of RCA/SFM blends. The inclusion of 1% SFM to RCA resulted in the highest values of unconfined compressive strength (216 kPa) and the highest resilient modulus (314.35 MP). However, beyond 2%, increasing the amount of SFM led to a decrease in strength and stiffness. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2021, "Volume": 769, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 145527, "DOI": "10.1016/j.scitotenv.2021.145527", "DOI Link": "http://dx.doi.org/10.1016/j.scitotenv.2021.145527", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626618100141", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, S; Liu, IL; Eo, YS; Campbell, DJ; Neves, PM; Fuhrman, WT; Saha, SR; Eckberg, C; Kim, H; Graf, D; Balakirev, F; Singleton, J; Paglione, J; Butch, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Sheng; Liu, I-Lin; Eo, Yun Suk; Campbell, Daniel J.; Neves, Paul M.; Fuhrman, Wesley T.; Saha, Shanta R.; Eckberg, Christopher; Kim, Hyunsoo; Graf, David; Balakirev, Fedor; Singleton, John; Paglione, Johnpierre; Butch, Nicholas P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extreme magnetic field-boosted superconductivity", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Applied magnetic fields underlie exotic quantum states, such as the fractional quantum Hall effect(1) and Bose-Einstein condensation of spin excitations(2). Superconductivity, however, is inherently antagonistic towards magnetic fields. Only in rare cases(3-5) can these effects be mitigated over limited fields, leading to re-entrant superconductivity. Here, we report the coexistence of multiple high-field re-entrant superconducting phases in the spin-triplet superconductor UTe2 (ref.(6)). We observe superconductivity in the highest magnetic field range identified for any re-entrant superconductor, beyond 65 T. Although the stability of superconductivity in these high magnetic fields challenges current theoretical models, these extreme properties seem to reflect a new kind of exotic superconductivity rooted in magnetic fluctuations(7) and boosted by a quantum dimensional crossover(8).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 15, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1250, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-019-0670-x", "DOI Link": "http://dx.doi.org/10.1038/s41567-019-0670-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500574300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Miao, Q; Ding, WF; Xu, JH; Cao, LJ; Wang, HC; Yin, Z; Dai, CW; Kuang, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Miao, Qing; Ding, Wenfeng; Xu, Jiuhua; Cao, Lijie; Wang, Hongcai; Yin, Zhen; Dai, Chenwei; Kuang, Weijie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creep feed grinding induced gradient microstructures in the superficial layer of turbine blade root of single crystal nickel-based superalloy", "Source Title": "INTERNATIONAL JOURNAL OF EXTREME MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The service performance of the turbine blade root of an aero-engine depends on the microstructures in its superficial layer. This work investigated the surface deformation structures of turbine blade root of single crystal nickel-based superalloy produced under different creep feed grinding conditions. Gradient microstructures in the superficial layer were clarified and composed of a severely deformed layer (DFL) with nullo-sized grains (48-67 nm) at the topmost surface, a DFL with submicron-sized grains (66-158 nm) and micron-sized laminated structures at the subsurface, and a dislocation accumulated layer extending to the bulk material. The formation of such gradient microstructures was found to be related to the graded variations in the plastic strain and strain rate induced in the creep feed grinding process, which were as high as 6.67 and 8.17 x 10(7) s(-1), respectively. In the current study, the evolution of surface gradient microstructures was essentially a transition process from a coarse single crystal to nullo-sized grains and, simultaneously, from one orientation of a single crystal to random orientations of polycrystals, during which the dislocation slips dominated the creep feed grinding induced microstructure deformation of single crystal nickel-based superalloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45102, "DOI": "10.1088/2631-7990/ac1e05", "DOI Link": "http://dx.doi.org/10.1088/2631-7990/ac1e05", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000693575300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, FJ; Zhang, JQ; Zeng, AP; Zhao, H; Duan, K; Yu, H; Cheng, K; Chai, GD; Chen, YZ; Liang, JE; Ma, W; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Fujin; Zhang, Jianquan; Zeng, Anping; Zhao, Heng; Duan, Ke; Yu, Han; Cheng, Kui; Chai, Gaoda; Chen, Yuzhong; Liang, Jiaen; Ma, Wei; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly crystalline non-fullerene acceptor enabling efficient indoor organic photovoltaics with high EQE and fill factor", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The growth of the internet of things (IoT) is creating a demand for convenient energy sources, like organic photovoltaics, to power various small loT devices. Here, we report a highly crystalline small molecular acceptor (named FCC-Cl) with an optical band gap of 1.71 eV suitable for indoor applications, The important design rationale of FCC-Cl is the combination of a weak electron-donating core and a moderate electron-withdrawing end group, which leads to needed band gap and high crystallinity. The OPVs based on D18:FCC-Cl achieved a high external quantum efficiency up to 85% and a high fill factor of 80% due to the high absorption coefficient and strong crystallinity of FCC-Cl. Consequently, an impressive power conversion efficiency of 28.8% was achieved under a 2,600 K LED lamp at 500 lux, It was also demonstrated that PM6:FCC-Cl-based devices can achieve high efficiencies over a wide range of active-layer thicknesses, which is a feature necessary for large-scale roll-to-roll printing processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 19", "Publication Year": 2021, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1231, "End Page": 1245, "Article Number": null, "DOI": "10.1016/j.joule.2021.03.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.03.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654225600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goodge, BH; Li, DF; Lee, K; Osada, M; Wang, BY; Sawatzky, GA; Hwang, HY; Kourkoutis, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goodge, Berit H.; Li, Danfeng; Lee, Kyuho; Osada, Motoki; Wang, Bai Yang; Sawatzky, George A.; Hwang, Harold Y.; Kourkoutis, Lena F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Doping evolution of the Mott-Hubbard landscape in infinite-layer nickelates", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent observation of superconductivity in Nd0.8Sr0.2NiO2 has raised fundamental questions about the hierarchy of the underlying electronic structure. Calculations suggest that this system falls in the Mott-Hubbard regime, rather than the charge-transfer configuration of other nickel oxides and the superconducting cuprates. Here, we use state-of-the-art, locally resolved electron energy-loss spectroscopy to directly probe the Mott-Hubbard character of Nd1-xSrxNiO2. Upon doping, we observe emergent hybridization reminiscent of the Zhang-Rice singlet via the oxygen-projected states, modification of the Nd 5d states, and the systematic evolution of Ni 3d hybridization and filling. These experimental data provide direct evidence for the multiband electronic structure of the superconducting infinite-layer nickelates, particularly via the effects of hole doping on not only the oxygen but also nickel and rare-earth bands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 133, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 118, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2007683118", "DOI": "10.1073/pnas.2007683118", "DOI Link": "http://dx.doi.org/10.1073/pnas.2007683118", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000607277100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thonhauser, T; Zuluaga, S; Arter, CA; Berland, K; Schröder, E; Hyldgaard, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thonhauser, T.; Zuluaga, S.; Arter, C. A.; Berland, K.; Schroder, E.; Hyldgaard, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin Signature of Nonlocal Correlation Binding in Metal-Organic Frameworks", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a proper nonempirical spin-density formalism for the van der Waals density functional (vdW-DF) method. We show that this generalization, termed svdW-DF, is firmly rooted in the single-particle nature of exchange and we test it on a range of spin systems. We investigate in detail the role of spin in the nonlocal correlation driven adsorption of H-2 and CO2 in the linear magnets Mn-MOF74, Fe-MOF74, Co-MOF74, and Ni-MOF74. In all cases, we find that spin plays a significant role during the adsorption process despite the general weakness of the molecular-magnetic responses. The case of CO2 adsorption in Ni-MOF74 is particularly interesting, as the inclusion of spin effects results in an increased attraction, opposite to what the diamagnetic nature of CO2 would suggest. We explain this counterintuitive result, tracking the behavior to a coincidental hybridization of the O p states with the Ni d states in the down-spin channel. More generally, by providing insight on nonlocal correlation in concert with spin effects, our nonempirical svdW-DF method opens the door for a deeper understanding of weak nonlocal magnetic interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 22", "Publication Year": 2015, "Volume": 115, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136402, "DOI": "10.1103/PhysRevLett.115.136402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.136402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361677000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deringer, VL; Caro, MA; Csányi, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deringer, Volker L.; Caro, Miguel A.; Csanyi, Gabor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine Learning Interatomic Potentials as Emerging Tools for Materials Science", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic-scale modeling and understanding of materials have made remarkable progress, but they are still fundamentally limited by the large computational cost of explicit electronic-structure methods such as density-functional theory. This Progress Report shows how machine learning (ML) is currently enabling a new degree of realism in materials modeling: by learning electronic-structure data, ML-based interatomic potentials give access to atomistic simulations that reach similar accuracy levels but are orders of magnitude faster. A brief introduction to the new tools is given, and then, applications to some select problems in materials science are highlighted: phase-change materials for memory devices; nulloparticle catalysts; and carbon-based electrodes for chemical sensing, supercapacitors, and batteries. It is hoped that the present work will inspire the development and wider use of ML-based interatomic potentials in diverse areas of materials research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 393, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 31, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1902765, "DOI": "10.1002/adma.201902765", "DOI Link": "http://dx.doi.org/10.1002/adma.201902765", "Book DOI": null, "Early Access Date": "SEP 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485330600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, B; Cho, H; Moon, S; Ko, Y; Ryu, YS; Kim, H; Jeong, J; Chung, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Byeongmoon; Cho, Hyunjoo; Moon, Sooyeon; Ko, Youngpyo; Ryu, Yong-Sang; Kim, Heesuk; Jeong, Jaewook; Chung, Seungjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Omnidirectional printing of elastic conductors for three-dimensional stretchable electronics", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Three-dimensional printing could be used to create complex and multifunctional soft electronic devices. However, printing solid-state elastic conductors with three-dimensional geometries is challenging because the rheological properties of existing inks typically only allow for layer-wise deposition. Here we show that an emulsion system-consisting of a conductive elastomer composite, immiscible solvent and emulsifying solvent-can be used for the omnidirectional printing of elastic conductors. The viscoelastic properties of the composite provide structural integrity to the printed features-allowing freestanding, filamentary and out-of-plane three-dimensional geometries to be directly written-and pseudo-plastic and lubrication behaviours that provide printing stability and prevent nozzle clogging. Printed structures of the intrinsically stretchable conductor exhibit a minimum feature size less than 100 mu m and stretchability of more than 150%. The vapourisation of the dispersed solvent phase in the emulsion results in the formation of microstructured, surface-localized conductive networks, which improve the electrical conductivity. To illustrate the capabilities of our approach, we create a skin-mountable temperature sensor with a matrix-type stretchable display based on omnidirectionally printed elastic interconnects. Freestanding, out-of-plane structures made of stretchable conductors can be printed using an emulsion-based ink that has the viscoelasticity to be extruded into three-dimensional geometries and supporting its own shape.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 307, "End Page": 318, "Article Number": null, "DOI": "10.1038/s41928-023-00949-5", "DOI Link": "http://dx.doi.org/10.1038/s41928-023-00949-5", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972785300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PT; Bai, XW; Jin, HY; Gao, XT; Davey, K; Zheng, Y; Jiao, Y; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengtang; Bai, Xiaowan; Jin, Huanyu; Gao, Xintong; Davey, Kenneth; Zheng, Yao; Jiao, Yan; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directed Urea-to-Nitrite Electrooxidation via Tuning Intermediate Adsorption on Co, Ge Co-Doped Ni Sites", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical urea oxidation reaction (UOR) is an alternative to electrooxidation of water for energy-saving hydrogen (H-2) production. To maximize this purpose, design of catalysts for selective urea-to-nitrite (NO2-) electrooxidation with increased electron transfer and high current is practically important. Herein, a cobalt, germanium (Co, Ge) co-doped nickel (Ni) oxyhydroxide catalyst is reported first time that directs urea-to-NO2- conversion with a significant Faradaic efficiency of 84.9% at 1.4 V versus reversible hydrogen electrode and significantly boosts UOR activity to 448.0 mA cm(-2). Importantly, this performance is greater than for most reported Ni-based catalysts. Based on judiciously combined synchrotron-based measurement, in situ spectroscopy and density functional theoretical computation, significantly boosted urea-to-NO2- production results from Co, Ge co-doping is demonstrated that optimizes electronic structure of Ni sites in which urea adsorption is altered as NO-terminal configuration to facilitate C-N cleavage for *NH formation, and thereby expedites pathway for urea to NO2- conversion. Findings highlight the importance of tuning intermediate adsorption behavior for design of high-performance UOR electrocatalysts, and will be of practical benefit to a range of researchers and manufacturers in replacing conventional water electrooxidation with UOR for energy-saving H-2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 33, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202300687", "DOI Link": "http://dx.doi.org/10.1002/adfm.202300687", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950364800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Field, KG; Hu, XX; Littrell, KC; Yamamoto, Y; Snead, LL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Field, Kevin G.; Hu, Xunxiang; Littrell, Kenneth C.; Yamamoto, Yukinori; Snead, Lance L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys", "Source Title": "JOURNAL OF NUCLEAR MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Fe-Cr-Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe-Cr-Al alloys has not been fully established. In this study, a series of Fe-Cr-Al alloys with 10-18 wt % Cr and 2.9-4.9 wt % Al were neutron irradiated at 382 degrees C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical- property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 < 111 > and a < 100 > were detected and quantified. Results indicate precipitation of Cr-rich alpha' is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. A structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich alpha' precipitates at sufficiently high chromium contents after irradiation. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 465, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 746, "End Page": 755, "Article Number": null, "DOI": "10.1016/j.jnucmat.2015.06.023", "DOI Link": "http://dx.doi.org/10.1016/j.jnucmat.2015.06.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364890300092", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Cheng, JW; Zhao, QY; Zhang, JN; Yang, HR; Zhang, YM; Hui, ZQ; Zhao, F; Liu, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "LI, Lu; Cheng, Jiawei; Zhao, Qiyi; Zhang, Jinniu; Yang, Huiran; Zhang, Yaming; Hui, Zhanqiang; Zhao, Feng; Liu, Wenjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chromium oxide film for Q-switched and mode-locked pulse generation", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chromium oxide (Cr2O3) is a promising material used in the applications such as photoelectrochemical devices, photocatalysis, magnetic random access memory, and gas sensors. But, its nonlinear optical characteristics and applications in ultrafast optics have not been studied yet. This study prepares a microfiber decorated with a Cr2O3 film via magnetron sputtering deposition and examines its nonlinear optical characteristics. The modulation depth and saturation intensity of this device are determined as 12.52% and 0.0176 MW/cm2. Meanwhile, the Cr2O3-microfiber is applied as a saturable absorber in an Er-doped fiber laser, and stable Q-switching and mode-locking laser pulses are successfully generated. In the Q-switched working state, the highest output power and shortest pulse width are measured as 12.8 mW and 1.385 mu s, respectively. The pulse duration of this mode-locked fiber laser is as short as 334 fs, and its signal-to-noise ratio is 65 dB. As far as we know, this is the first illustration of using Cr2O3 in ultrafast photonics. The results confirm that Cr2O3 is a promising saturable absorber material and significantly extend the scope of saturable absorber materials for innovative fiber laser technologies. (c) 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 8", "Publication Year": 2023, "Volume": 31, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16872, "End Page": 16881, "Article Number": null, "DOI": "10.1364/OE.491792", "DOI Link": "http://dx.doi.org/10.1364/OE.491792", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000996369500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, Z; Wang, JD; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Zhao; Wang, Jindi; Sun, Yongming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anode corrosion in aqueous Zn metal batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Given their low cost and intrinsic safety, aqueous Zn metal batteries (AZMBs) are drawing increasing attention in the field of smart grids and large-scale energy storage. However, the Zn metal anode in aqueous electrolyte suffers from a critical issue, corrosion, which must be fully addressed before the practical implementation of AZMBs. In this perspective, the mechanisms of aqueous Zn metal anode corrosion in both alkaline and neutral electrolytes are compared and discussed. The methods for studying the corrosion processes and the strategies for Zn corrosion protection in AZMBs are also summarized. Finally, some expectations about potential research directions for making corrosion-resistant AZMBs a commercial reality are provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100093, "DOI": "10.1016/j.esci.2023.100093", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100093", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081060600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, ZL; Magar, R; Wang, YY; Farimani, AB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Zhonglin; Magar, Rishikesh; Wang, Yuyang; Farimani, Amir Barati", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOFormer: Self-Supervised Transformer Model for Metal-Organic Framework Property Prediction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-organic frameworks (MOFs) are materials with a high degree of porosity that can be used for many applications. However, the chemical space of MOFs is enormous due to the large variety of possible combinations of building blocks and topology. Discovering the optimal MOFs for specific applications requires an efficient and accurate search over countless potential candidates. Previous high-throughput screening methods using computational simulations like DFT can be time-consuming. Such methods also require the 3D atomic structures of MOFs, which adds one extra step when evaluating hypothetical MOFs. In this work, we propose a structure-agnostic deep learning method based on the Transformer model, named as MOFormer, for property predictions of MOFs. MOFormer takes a text string representation of MOF (MOFid) as input, thus circumventing the need of obtaining the 3D structure of a hypothetical MOF and accelerating the screening process. By comparing to other descriptors such as Stoichiometric-120 and revised autocorrelations, we demonstrate that MOFormer can achieve state-of-the-art structure-agnostic prediction accuracy on all benchmarks. Furthermore, we introduce a self-supervised learning framework that pretrains the MOFormer via maximizing the cross-correlation between its structure-agnostic representations and structure-based representations of the crystal graph convolutional neural network (CGCNN) on >400k publicly available MOF data. Benchmarks show that pretraining improves the prediction accuracy of both models on various downstream prediction tasks. Furthermore, we revealed that MOFormer can be more data-efficient on quantum-chemical property prediction than structure-based CGCNN when training data is limited. Overall, MOFormer provides a novel perspective on efficient MOF property prediction using deep learning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 27", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c11420", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c11420", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000924951900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schloss, JM; Barry, JF; Turner, MJ; Walsworth, RL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schloss, Jennifer M.; Barry, John F.; Turner, Matthew J.; Walsworth, Ronald L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneous Broadband Vector Magnetometry Using Solid-State Spins", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate a vector magnetometer that simultaneously measures all Cartesian components of a dynamic magnetic field using an ensemble of nitrogen-vacancy (NV) centers in a single-crystal diamond. Optical NV-diamond measurements provide high-sensitivity, broadband magnetometry under ambient or extreme physical conditions and the fixed crystallographic axes inherent to this solid-state system enable vector sensing free from heading errors. In the present device, multichannel lock-in detection extracts the magnetic-field-dependent spin-resonullce shifts of NVs oriented along all four tetrahedral diamond axes from the optical signal measured on a single detector. The sensor operates from near dc (5 Hz) up to a 12.5-kHz measurement bandwidth and simultaneously achieves approximately 50 pT/root Hz magnetic-field sensitivity for each Cartesian component, which is, to date, the highest demonstrated sensitivity of a full vector magnetometer employing solid-state spins. Compared to optimized devices interrogating the four NV orientations sequentially, the simultaneous vector magnetometer enables a 4x measurement speedup. This technique can be extended to pulsed-type sensing protocols and parallel wide-field magnetic imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2018, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34044, "DOI": "10.1103/PhysRevApplied.10.034044", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.10.034044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445326900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Cheng, H; Lu, Y; Wang, T; Li, YF; Zhang, W; He, GJ; Tian, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zheng; Cheng, Hao; Lu, Yao; Wang, Tao; Li, Yifan; Zhang, Wei; He, Guanjie; Tian, Zhongliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potent Charge-Trapping for Boosted Electrocatalytic Oxygen Reduction", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal-free carbon-based materials are considered to be one of the most promising alternatives to precious metal Pt-based electrocatalysts. However, the electrocatalytic activity of heteroatom-modulated carbon rarely reaches the level of metal-based electrocatalysts. Here, electron-rich carbon and abundant pyridinic-N adjacent to C vacancies decorated with carbon nullosheets (E-NC-V) are synthesized and used as the host for boosting efficient oxygen reduction reaction. Rich pyridinic-N structures adjacent to C vacancies work in synergy with electron-rich carbon, which promotes the sharp decrease of |Delta G(O*)|, resulting in the balanced adsorption and dissociation of oxygen intermediates, and thus activating O(sic)O. This can be attributed to the abundant vacancies and d-p orbital hybridization between Zn and N/C. The E-NC-V catalyst drives the oxygen reduction reaction (ORR) via a 4e(-) transfer-dominated pathway with a half-wave potential of 0.87 V versus RHE in the alkaline solution, even superior to Pt/C. The assembled Al-air battery exhibits a high peak power density of 113 mW cm(-2). This promising strategy sheds light on the design and fabrication of robust, rich-density, and high-performance active sites for the ORR. The work is expected to inspire future work on the role of electronic structure modulation and defect engineering for enhanced reaction kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 13, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202203963", "DOI Link": "http://dx.doi.org/10.1002/aenm.202203963", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953437400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Oqla, FM; Sapuan, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "AL-Oqla, Faris M.; Sapuan, S. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural fiber reinforced polymer composites in industrial applications: feasibility of date palm fibers for sustainable automotive industry", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proper utilization of the available natural resources and wastes became crucial for developing sustainability in industry. In this work, the feasibility of using the date palm fibers in the natural fiber reinforced polymer composites (NFC) for automotive industry was reported. Moreover, this work identifies a gap in the way of evaluating NFC relative to comprehensive desired criteria. This gap leads to disregard potential natural fiber types in industrial applications and keep it no more than an environmental waste problem. Here, criteria that affect the NFC were categorized and classified into levels. Governing criteria were suggested, collected and tabulated according to each level. To ensure the potential and competitiveness of the date palm fiber (DPF) in developing sustainability of the automotive industry, several comparisons between DPF and other fiber types commonly used in this industry were carried out. In most comparisons, DPF was the best selected fiber among all other types. DPF was the best regarding specific Young's modulus to cost ratio criterion. Technical properties and performance, environmental, economical, and societal aspects strongly contribute toward adopting DPF into the automotive sector to improve its sustainability and productivity. Furthermore, this adoption has a significant environmental influence throughout achieving an efficient sustainable waste management practice. (C) 2013 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2014, "Volume": 66, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 347, "End Page": 354, "Article Number": null, "DOI": "10.1016/j.jclepro.2013.10.050", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2013.10.050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332356300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, NN; Ma, PF; Fu, SG; Shang, XX; Jiang, SZ; Wang, SY; Li, DW; Zhang, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, nullnull; Ma, Pengfei; Fu, Shenggui; Shang, Xinxin; Jiang, Shouzhen; Wang, Shuyun; Li, Dengwang; Zhang, Huanian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tellurene-based saturable absorber to demonstrate large-energy dissipative soliton and noise-like pulse generations", "Source Title": "nullOPHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional layered monoelemental materials (Xenes) with excellent optoelectronic properties have various property-related applications, such as energy, biomedicine, and optoelectronic devices. Xenes also show excellent performance in acting as saturable absorbers (SAs) for obtaining ultrafast laser operations. Few-layer tellurene as a typical Xenens exhibits distinct optoelectronic properties and promising practical application potential, and its nonlinear optical absorption characteristics and related ultrafast modulation applications have been investigated preliminarily. However, tellurene-based SAs to demonstrate large-energy mode-locked operations, which have special applications in industrial and scientific research areas, are seldom studied. In this work, we focus on the preparation of tellurene-based SAs and explore its applications in demonstrating large-energy mode-locked operations [dissipative soliton (DS) and noise-like pulses (NLP)]. For DS operation, the maximum average output power, pulse width, and largest pulse energy are 23.61 mW, 5.87 ps, and 1.94 nJ, respectively. NLP operation with a recorded average output power of 106.6 mW and a pulse energy of 8.76 nJ is also generated, which shows significant enhancement in comparison to previously reported Xenes-based works. Our contribution reveals the great potential and capacity of tellurene-based SAs in obtaining large-energy pulse operations and further promotes the explorative investigation of Xenes-based optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2783, "End Page": 2795, "Article Number": null, "DOI": "10.1515/nulloph-2019-0545", "DOI Link": "http://dx.doi.org/10.1515/nulloph-2019-0545", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000556630800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Yang, ZW; Yu, ZY; Liu, ZT; Liu, DH; Lin, HL; Li, MQ; Ma, SC; Avdeev, M; Shi, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yue; Yang, Zhengwei; Yu, Zhenyao; Liu, Zitu; Liu, Dahui; Lin, Hailong; Li, Mingqing; Ma, Shuchang; Avdeev, Maxim; Shi, Siqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generative artificial intelligence and its applications in materials science: Current situation and future perspectives", "Source Title": "JOURNAL OF MATERIOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Generative Artificial Intelligence (GAI) is attracting the increasing attention of materials community for its excellent capability of generating required contents. With the introduction of Prompt paradigm and reinforcement learning from human feedback (RLHF), GAI shifts from the task-specific to general pattern gradually, enabling to tackle multiple complicated tasks involved in resolving the structure-activity re-lationships. Here, we review the development status of GAI comprehensively and analyze pros and cons of various generative models in the view of methodology. The applications of task-specific generative models involving materials inverse design and data augmentation are also dissected. Taking ChatGPT as an example, we explore the potential applications of general GAI in generating multiple materials content, solving differential equation as well as querying materials FAQs. Furthermore, we summarize six challenges encountered for the use of GAI in materials science and provide the corresponding solutions. This work paves the way for providing effective and explainable materials data generation and analysis approaches to accelerate the materials research and development.& COPY; 2023 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 111, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 9, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 798, "End Page": 816, "Article Number": null, "DOI": "10.1016/j.jmat.2023.05.001", "DOI Link": "http://dx.doi.org/10.1016/j.jmat.2023.05.001", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001040340300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, DK; Xue, ZM; Mu, TC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Dongkun; Xue, Zhimin; Mu, Tiancheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep eutectic solvents as a green toolbox for synthesis", "Source Title": "CELL REPORTS PHYSICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Energy and environmental issues are increasingly prominent, and sustainable synthetic strategies are needed in response. As a class of green and easily modified solvent, deep eutectic solvents (DESs) may contribute to this goal. Composed of monomers from biological sources, they are biodegradable with low toxicity, facilitating large-scale use. Indeed, their applications are already widespread on both the laboratory and industrial scales. This review focuses on the application of DESs in materials synthesis. After a brief summary of their use in organic synthesis, four strategies for materials synthesis are surveyed: solvothermal methods, electrodeposition, calcination, and polymerization. Materials synthesized using DESs are expected to find application among both academia and industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100809, "DOI": "10.1016/j.xcrp.2022.100809", "DOI Link": "http://dx.doi.org/10.1016/j.xcrp.2022.100809", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000795711000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmad, A; Ahmad, W; Aslam, F; Joyklad, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmad, Ayaz; Ahmad, Waqas; Aslam, Fahid; Joyklad, Panuwat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compressive strength prediction of fly ash-based geopolymer concrete via advanced machine learning techniques", "Source Title": "CASE STUDIES IN CONSTRUCTION MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concrete is a widely used construction material, and cement is its main constituent. Production and utilization of cement severely affect the environment due to the emission of various gases. The application of geopolymer concrete plays a vital role in reducing this flaw. This study used supervised machine learning algorithms, decision tree (DT), bagging regressor (BR), and AdaBoost regressor (AR) to estimate the compressive strength of fly ash-based geopolymer concrete. The coefficient of determination (R2), mean absolute error, mean square error, and root mean square error were used to evaluate the model's performance. The model's performance was further confirmed using the k-fold cross-validation technique. Compared to the DT and AR model, the bagging model was more effective in predicting results, with an R2 value of 0.97. The lesser values of the errors (MAE, MSE, RMSE) and higher values of the R2 were the clear indications of the better performance of the model. Additionally, a sensitivity analysis was conducted to ascertain the degree of contribution of each parameter towards the prediction of the results. The application of machine learning techniques to predict concrete's mechanical properties will benefit the area of civil engineering by saving time, effort, and resources.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e00840", "DOI": "10.1016/j.cscm.2021.e00840", "DOI Link": "http://dx.doi.org/10.1016/j.cscm.2021.e00840", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740934300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, P; Ang, YS; Garner, AL; Valfells, A; Luginsland, JW; Ang, LK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Peng; Ang, Yee Sin; Garner, Allen L.; Valfells, Agust; Luginsland, J. W.; Ang, L. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Space-charge limited current in nullodiodes: Ballistic, collisional, and dynamical effects", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This Perspective reviews the fundamental physics of space-charge interactions that are important in various media: vacuum gap, air gap, liquids, and solids including quantum materials. It outlines the critical and recent developments since a previous review paper on diode physics [Zhang et al. Appl. Phys. Rev. 4, 011304 (2017)] with particular emphasis on various theoretical aspects of the space-charge limited current (SCLC) model: physics at the nullo-scale, time-dependent, and transient behaviors; higher-dimensional models; and transitions between electron emission mechanisms and material properties. While many studies focus on steady-state SCLC, the increasing importance of fast-rise time electric pulses, high frequency microwave and terahertz sources, and ultrafast lasers has motivated theoretical investigations in time-dependent SCLC. We particularly focus on recent studies in discrete particle effects, temporal phenomena, time-dependent photoemission to SCLC, and AC beam loading. Due to the reduction in the physical size and complicated geometries, we report recent studies in multi-dimensional SCLC, including finite particle effects, protrusive SCLC, novel techniques for exotic geometries, and fractional models. Due to the importance of using SCLC models in determining the mobility of organic materials, this paper shows the transition of the SCLC model between classical bulk solids and recent two-dimensional (2D) Dirac materials. Next, we describe some selected applications of SCLC in nullodiodes, including nulloscale vacuum-channel transistors, microplasma transistors, thermionic energy converters, and multipactor. Finally, we conclude by highlighting future directions in theoretical modeling and applications of SCLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2021, "Volume": 129, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100902, "DOI": "10.1063/5.0042355", "DOI Link": "http://dx.doi.org/10.1063/5.0042355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628795800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, XP; Quan, BQ; Zhu, CB; Wen, HY; Sheng, MJ; Liu, S; Li, XL; Wu, H; Lu, X; Qu, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Xinpeng; Quan, Bingqing; Zhu, Chuanbiao; Wen, Haoye; Sheng, Mengjie; Liu, Shuang; Li, Xiaolong; Wu, Hao; Lu, Xiang; Qu, Jinping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Upgrading Electricity Generation and Electromagnetic Interference Shielding Efficiency via Phase-Change Feedback and Simple Origami Strategy", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing ultimate electromagnetic interference (EMI) shielding materials that can simultaneously upgrade the quality of generated electricity and the light-thermal-electric conversion efficiency based on traditional thermoelectric devices is crucially desired. Herein, a series of flexible multilayered phase change films (PCFs) is developed by a simple and novel origami strategy. The PCFs are first reported to improve the light-thermal-electric conversion efficiency by as high as 11.3%. Simultaneously, the PCFs could significantly upgrade the generated electricity on average voltage (27.3%), average current (23.8%), and lasting power outputs by 2010 times from microwatts to milliwatts. Besides, the EMI shielding efficiency of PCFs could be tuned from 39.2 to 71.9 dB by the origami process, the wide-range EMI shielding performance could be suitable for varying occasions. Overall, this work provides a promising solution for both the preparation of multifunctional materials, high-efficiency solar energy harvesting and upgrading electricity generation, which shows broad application prospects in EMI shielding, energy storage, and conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 40, "Times Cited, All Databases": 40, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202206835", "DOI Link": "http://dx.doi.org/10.1002/advs.202206835", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000951759900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, GL; Zheng, JH; Duan, WY; Yang, J; Mahmud, MA; Lian, Q; Tang, S; Liao, CH; Bing, JM; Yi, JP; Leung, TL; Cui, X; Chen, HJ; Jiang, F; Huang, YL; Lambertz, A; Jankovec, M; Topic, M; Bremner, S; Zhang, YZ; Cheng, C; Ding, KN; Ho-Baillie, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Guoliang; Zheng, Jianghui; Duan, Weiyuan; Yang, Jiong; Mahmud, Md Arafat; Lian, Qing; Tang, Shi; Liao, Chwenhaw; Bing, Jueming; Yi, Jianpeng; Leung, Tik Lun; Cui, Xin; Chen, Hongjun; Jiang, Feng; Huang, Yulan; Lambertz, Andreas; Jankovec, Marko; Topic, Marko; Bremner, Stephen; Zhang, Yuan-Zhu; Cheng, Chun; Ding, Kaining; Ho-Baillie, Anita", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular engineering of hole-selective layer for high band gap perovskites for highly efficient and stable perovskite-silicon tandem solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a novel carbazole-based SAM (Ph-2PACz) was developed for facilitating efficient hole extraction and suppressing carrier recombination in high-band-gap (1.67 eV) perovskites for single junction and tandem-cell demonstrations. The champion 21.3% efficient 1.67 eV cell produced a high fill factor (FF) of 82.6% and an open-circuit voltage (VOC) of 1.26 V, representing low band-gap voltage offset at 0.41 V. When Ph-2PACz was applied to the top perovskite cell for a monolithic perovskite-Si tandem, a PCE of 28.9% (on 1 cm2) and a VOC of 1.91 V were obtained. When encapsulated, a tandem cell demonstrated excellent stability under continuous 1 sun illumination (680 h) and damp heat (280 h at 85 degrees C + 85% relative humidity) and passed the International Electrotechnical Commission (IEC) 61215 thermal cycling (200 cycles between -40 degrees C and 85 degrees C) test, retaining 98.8% of the initial PCE.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2023, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.joule.2023.09.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.09.007", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001148408000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QS; McDowell, MT; Qi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Qisheng; McDowell, Matthew T.; Qi, Yue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of the Electric Double Layer (EDL) in Multicomponent Electrolyte Reduction and Solid Electrolyte Interphase (SEI) Formation in Lithium Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolytes, consisting of salts, solvents, and additives, must form a stable solid electrolyte interphase (SEI) to ensure the performance and durability of lithium(Li)-ion batteries. However, the electric double layer (EDL) structure near charged surfaces is still unsolved, despite its importance in dictating the species being reduced for SEI formation near a negative electrode. In this work, a newly developed model was used to illustrate the effect of EDL on SEI formation in two essential electrolytes, the carbonate-based electrolyte for Li-ion batteries and the ether-based electrolyte for batteries with Li-metal anodes. Both electrolytes have fluoroethylene carbonate (FEC) as a common additive to form the beneficial F-containing SEI component (e.g., LiF). However, the role of FEC drastically differs in these electrolytes. FEC is an effective SEI modifier for the carbonate-based electrolyte by being the only F-containing species entering the EDL and being reduced, as the anion (PF6-) will not enter the EDL. For the ether-based electrolyte, both the anion (TFSI-) and FEC can enter the EDL and be reduced. The competition of the two species within the EDL due to the surface charge and temperature leads to a unique temperature effect observed in prior experiments: the FEC additive is more effective in modulating SEI components at a low temperature (-40 degrees C) than at room temperature (20 degrees C) in the ether-based electrolyte. These collective quantitative agreements with experiments emphasize the importance of incorporating the effect of the EDL in multicomponent electrolyte reduction reactions in simulations/experiments to predict/control the formation of the SEI layer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2023 JAN 23", "Publication Year": 2023, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/jacs.2c11807", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c11807", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922138700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, H; Kim, E; Lee, Y; Kim, H; Lee, J; Kim, M; Yoo, HJ; Yoo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hyeonwoo; Kim, Eunhye; Lee, Yongsu; Kim, Hoyeon; Lee, Jaeho; Kim, Mincheol; Yoo, Hoi-Jun; Yoo, Seunghyup", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward all-day wearable health monitoring: An ultralow-power, reflective organic pulse oximetry sensing patch", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pulse oximetry sensors have been playing a key role as devices to monitor elemental yet critical human health states. Conventional pulse oximetry sensors, however, have relatively large power consumption, impeding their use as stand-alone, continuous monitoring systems that can easily be integrated with everyday life. Here, we exploit the design freedom offered by organic technologies to realize a reflective patch-type pulse oximetry sensor with ultralow power consumption. On the basis of flexible organic light-emitting diodes and organic photodiodes designed via an optical simulation of color-sensitive light propagation within human skin, the proposed monolithically integrated organic pulse oximetry sensor heads exhibit successful operation at electrical power as low as 24 mu W on average. We thereby demonstrate that organic devices not only have form factor advantages for such applications but also hold great promise as enablers for all-day wearable health monitoring systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaas9530", "DOI": "10.1126/sciadv.aas9530", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aas9530", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472723800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barbone, M; Montblanch, ARP; Kara, DM; Palacios-Berraquero, C; Cadore, AR; De Fazio, D; Pingault, B; Mostaani, E; Li, H; Chen, B; Watanabe, K; Taniguchi, T; Tongay, S; Wang, G; Ferrari, AC; Atatüre, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Barbone, Matteo; Montblanch, Alejandro R. -P.; Kara, Dhiren M.; Palacios-Berraquero, Carmen; Cadore, Alisson R.; De Fazio, Domenico; Pingault, Benjamin; Mostaani, Elaheh; Li, Han; Chen, Bin; Watanabe, Kenji; Taniguchi, Takashi; Tongay, Sefaattin; Wang, Gang; Ferrari, Andrea C.; Atature, Mete", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-tuneable biexciton complexes in monolayer WSe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolayer transition metal dichalcogenides have strong Coulomb-mediated many-body interactions. Theoretical studies have predicted the existence of numerous multi-particle excitonic states. Two-particle excitons and three-particle trions have been identified by their optical signatures. However, more complex states such as biexcitons have been elusive due to limited spectral quality of the optical emission. Here, we report direct evidence of two biexciton complexes in monolayer tungsten diselenide: the four-particle neutral biexciton and the five-particle negatively charged biexciton. We distinguish these states by power-dependent photoluminescence and demonstrate full electrical switching between them. We determine the band states of the elementary particles comprising the biexcitons through magneto-optical spectroscopy. We also resolve a splitting of 2.5 meV for the neutral biexciton, which we attribute to the fine structure, providing reference for subsequent studies. Our results unveil the nature of multi-exciton complexes in transitionmetal dichalcogenides and offer direct routes towards deterministic control in many-body quantum phenomena.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3721, "DOI": "10.1038/s41467-018-05632-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05632-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444494800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kruchinin, SY; Krausz, F; Yakovlev, VS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kruchinin, Stanislav Yu.; Krausz, Ferenc; Yakovlev, Vladislav S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloquium: Strong-field phenomena in periodic systems", "Source Title": "REVIEWS OF MODERN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of visible-infrared laser pulses carrying a substantial fraction of their energy in a single field oscillation cycle has opened a new era in the experimental investigation of ultrafast processes in semiconductors and dielectrics (bulk as well as nullostructured), motivated by the quest for the ultimate frontiers of electron-based signal metrology and processing. Exploring ways to approach those frontiers requires insight into the physics underlying the interaction of strong high-frequency (optical) fields with electrons moving in periodic potentials. This Colloquium aims at providing this insight. Introduction to the foundations of strong-field phenomena defines and compares regimes of field-matter interaction in periodic systems, including (perfect) crystals as well as optical and semiconductor superlattices, followed by a review of recent experimental advances in the study of strong-field dynamics in crystals and nullostructures. Avenues toward measuring and controlling electronic processes up to petahertz frequencies are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2018, "Volume": 90, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21002, "DOI": "10.1103/RevModPhys.90.021002", "DOI Link": "http://dx.doi.org/10.1103/RevModPhys.90.021002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429532200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZL; Wu, CT; Koishi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zeliang; Wu, C. T.; Koishi, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A deep material network for multiscale topology learning and accelerated nonlinear modeling of heterogeneous materials", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, a new data-driven multiscale material modeling method, which we refer to as deep material network, is developed based on mechanistic homogenization theory of representative volume element (RVE) and advanced machine learning techniques. We propose to use a collection of connected mechanistic building blocks with analytical homogenization solutions to describe complex overall material responses which avoids the loss of essential physics in generic neural network. This concept is demonstrated for 2-dimensional RVE problems and network depth up to 7. Based on linear elastic RVE data from offline direct numerical simulations, the material network can be effectively trained using stochastic gradient descent with backpropagation algorithm, further enhanced by model compression methods. Importantly, the trained network is valid for any local material laws without the need for additional calibration or micromechanics assumption. Its extrapolations to unknown material and loading spaces for a wide range of problems are validated through numerical experiments, including linear elasticity with high contrast of phase properties, nonlinear history-dependent plasticity and finite-strain hyperelasticity under large deformations. By discovering a proper topological representation of RVE with fewer degrees of freedom, this intelligent material model is believed to open new possibilities of high-fidelity efficient concurrent simulations for a large-scale heterogeneous structure. It also provides a mechanistic understanding of structure-property relations across material length scales and enables the development of parameterized microstructural database for material design and manufacturing. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2019, "Volume": 345, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1138, "End Page": 1168, "Article Number": null, "DOI": "10.1016/j.cma.2018.09.020", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2018.09.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456953900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Dong, SF; Li, ZM; Han, BG; Ou, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xinyue; Dong, Sufen; Li, Zhenming; Han, Baoguo; Ou, Jinping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullomechanical Characteristics of Interfacial Transition Zone in nullo-Engineered Concrete", "Source Title": "ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigates the effects of nullofillers on the interfacial transition zone (ITZ) between aggregate and cement paste by using nulloindentation and statistical nulloindentation techniques. Moreover, the underlying mechanisms are revealed through micromechanical modeling. The nulloindentation results indicate that incorporating nullofillers increases the degree of hydration in the ITZ, reduces the content of micropores and low-density calcium silicate hydrate (LD C-S-H), and increases the content of high -density C-S-H (HD C-S-H) and ultrahigh-density C-S-H (UHD C-S-H). In particular, a new phase, namely nullo-core-induced low-density C-S-H (NCILD C-S-H), with a superior hardness of 2.50 GPa and an indentation modulus similar to those of HD C-S-H or UHD C-S-H was identified in this study. The modeling results revealed that the presence of nullofillers increased the packing density of LD C- S-H and significantly enhanced the interaction (adhesion and friction) among the basic building blocks of C-S-H gels owing to the formation of nullo-core-shell elements, thereby facilitating the formation of NCILD C-S-H and further improving the performance of the ITZ. This study provides insight into the effects of nullofillers on the ITZ in concrete at the nulloscale.(c) 2021 THE AUTHORS. Published by Elsevier LTD on behalf of Chinese Academy of Engineering and Higher Education Press Limited Company. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 17, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 99, "End Page": 109, "Article Number": null, "DOI": "10.1016/j.eng.2020.08.025", "DOI Link": "http://dx.doi.org/10.1016/j.eng.2020.08.025", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918837800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Q; Tang, BH; Romero, JC; Yang, YQ; Elsayed, SK; Pahapale, G; Lee, TJ; Pantoja, IEM; Han, F; Berlinicke, C; Xiang, T; Solazzo, M; Hartung, T; Qin, Z; Caffo, BS; Smirnova, L; Gracias, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Qi; Tang, Bohao; Romero, July Carolina; Yang, Yuqian; Elsayed, Saifeldeen Khalil; Pahapale, Gayatri; Lee, Tien-Jung; Pantoja, Itzy E. Morales; Han, Fang; Berlinicke, Cynthia; Xiang, Terry; Solazzo, Mallory; Hartung, Thomas; Qin, Zhao; Caffo, Brian S.; Smirnova, Lena; Gracias, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shell microelectrode arrays (MEAs) for brain organoids", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Brain organoids are important models for mimicking some three-dimensional (3D) cytoarchitectural and functional aspects of the brain. Multielectrode arrays (MEAs) that enable recording and stimulation of activity from electrogenic cells offer notable potential for interrogating brain organoids. However, conventional MEAs, initially designed for monolayer cultures, offer limited recording contact area restricted to the bottom of the 3D organoids. Inspired by the shape of electroencephalography caps, we developed miniaturized wafer-integrated MEA caps for organoids. The optically transparent shells are composed of self-folding polymer leaflets with conductive polymer-coated metal electrodes. Tunable folding of the minicaps' polymer leaflets guided by mechanics simulations enables versatile recording from organoids of different sizes, and we validate the feasibility of electrophysiology recording from 400- to 600-mu m-sized organoids for up to 4 weeks and in response to glutamate stimulation. Our studies suggest that 3D shell MEAs offer great potential for high signal-to-noise ratio and 3D spatiotemporal brain organoid recording.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2022, "Volume": 8, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabq5031", "DOI": "10.1126/sciadv.abq5031", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abq5031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842064500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XL; Yu, PC; Su, XZ; Hu, SJ; Shi, L; Wang, YH; Yang, PP; Gao, FY; Wu, ZZ; Chi, LP; Zheng, YR; Gao, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiao-Long; Yu, Peng-Cheng; Su, Xiao-Zhi; Hu, Shao-Jin; Shi, Lei; Wang, Ye-Hua; Yang, Peng-Peng; Gao, Fei-Yue; Wu, Zhi-Zheng; Chi, Li-Ping; Zheng, Ya-Rong; Gao, Min-Rui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient acidic hydrogen evolution in proton exchange membrane electrolyzers over a sulfur-doped marcasite-type electrocatalyst", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale deployment of proton exchange membrane (PEM) water electrolyzers has to overcome a cost barrier resulting from the exclusive adoption of platinum group metal (PGM) catalysts. Ideally, carbon-supported platinum used at cathode should be replaced with PGM-free catalysts, but they often undergo insufficient activity and stability subjecting to corrosive acidic conditions. Inspired by marcasite existed under acidic environments in nature, we report a sulfur doping-driven structural transformation from pyrite-type cobalt diselenide to pure marcasite counterpart. The resultant catalyst drives hydrogen evolution reaction with low overpotential of 67 millivolts at 10 milliamperes per square centimeter and exhibits no degradation after 1000 hours of testing in acid. Moreover, a PEM electrolyzer with this catalyst as cathode runs stably over 410 hours at 1 ampere per square centimeter and 60 degrees C. The marked properties arise from sulfur doping that not only triggers formation of acid-resistant marcasite structure but also tailors electronic states (e.g., work function) for improved hydrogen diffusion and electrocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 9, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadh2885", "DOI": "10.1126/sciadv.adh2885", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adh2885", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001030977500021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, YD; Liu, ZX; Li, LY; Guo, S; Xie, XF; Luo, ZG; Fang, GZ; Liang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yida; Liu, Zhexuan; Li, Lanyan; Guo, Shan; Xie, Xuefang; Luo, Zhigao; Fang, Guozhao; Liang, Shuquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstructing interfacial manganese deposition for durable aqueous zinc-manganese batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-cost, high-safety, and broad-prospect aqueous zinc-manganese batteries (ZMBs) are limited by complex interfacial reactions. The solid-liquid interfacial state of the cathode dominates the Mn dissolution/deposition process of aqueous ZMBs, especially the important influence on the mass and charge transfer behavior of Zn2+ and Mn2+. We proposed a quasi-eutectic electrolyte (QEE) that would stabilize the reversible behavior of interfacial deposition and favorable interfacial reaction kinetic of manganese-based cathodes in a long cycle process by optimizing mass and charge transfer. We emphasize that the initial interfacial reaction energy barrier is not the main factor affecting cycling performance, and the good reaction kinetics induced by interfacial deposition during the cycling process is more conducive to the stable cycling of the battery, which has been confirmed by theoretical analysis, quartz crystal microbalance with dissipation monitoring, depth etching X-ray photon-electron spectroscopy, etc. As a result, the QEE electrolyte maintained a stable specific capacity of 250 mAh g-1 at 0.5 A g-1 after 350 cycles in zinc-manganese batteries. The energy density retention rate of the ZMB with QEE increased by 174% compared to that of conventional aqueous electrolyte. Furthermore, the multi-stacked soft-pack battery with a cathodic mass load of 54.4 mg maintained a stable specific capacity of 200 mAh g-1 for 100 cycles, demonstrating its commercial potential. This work proves the feasibility of adapting lean-water QEE to the stable aqueous ZMBs. This paper demonstrates a novel quasi-eutectic electrolyte that enables the cycle life of aqueous zinc-manganese batteries by regulating ion behavior and interfacial deposition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2023, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwad220", "DOI": "10.1093/nsr/nwad220", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwad220", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058732500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, H; Chang, BS; Kim, H; Xie, ZL; Lainé, A; Ma, L; Xu, TL; Yang, CQ; Kwon, J; Shelton, SW; Klivansky, LM; Altoé, V; Gao, B; Schwartzberg, AM; Peng, ZR; Ritchie, RO; Xu, T; Salmeron, M; Ruiz, R; Sharpless, KB; Wu, P; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, He; Chang, Boyce S.; Kim, Hyunseok; Xie, Zongliang; Laine, Antione; Ma, Le; Xu, Tianlei; Yang, Chongqing; Kwon, Junpyo; Shelton, Steve W.; Klivansky, Liana M.; Altoe, Virginia; Gao, Bing; Schwartzberg, Adam M.; Peng, Zongren; Ritchie, Robert O.; Xu, Ting; Salmeron, Miquel; Ruiz, Ricardo; Sharpless, K. Barry; Wu, Peng; Liu, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performing polysulfate dielectrics for electrostatic energy under harsh conditions", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-capacity polymer dielectrics that operate with high efficiencies under harsh electrification conditions are essential components for advanced electronics and power systems. It is, however, fundamen-tally challenging to design polymer dielectrics that can reliably withstand demanding temperatures and electric fields, which neces-sitate the balance of key electronic, electrical, and thermal parame-ters. Herein, we demonstrate that polysulfates, synthesized by sulfur(VI) fluoride exchange (SuFEx) catalysis, another near-perfect click chemistry reaction, serve as high-performing dielectric poly-mers that overcome such bottlenecks. Free-standing polysulfate thin films from convenient solution processes exhibit superior insu-lating properties and dielectric stability at elevated temperatures, which are further enhanced when ultrathin (-5 nm) oxide coatings are deposited by atomic layer deposition. The corresponding elec-trostatic film capacitors display high breakdown strength (>700 MV m-1) and discharged energy density of 8.64 J cm -3 at 150 degrees C, outper-forming state-of-the-art free-standing capacitor films based on com-mercial and synthetic dielectric polymers and nullocomposites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2023, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 95, "End Page": 111, "Article Number": null, "DOI": "10.1016/j.joule.2022.12.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.12.010", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926113800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prakash, K; Harish, S; Kamalakannull, S; Logu, T; Shimomura, M; Archana, J; Navaneethan, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prakash, Kamarajar; Harish, Santhanakrishnull; Kamalakannull, Shanmugasundaram; Logu, Thirumalaisamy; Shimomura, Masaru; Archana, Jayaram; Navaneethan, Mani", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspective on ultrathin layered Ni-doped MoS2 hybrid nullostructures for the enhancement of electrochemical properties in supercapacitors", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the last two decades, extensive study has been done on two-dimensional Molybdenum Sulphide (MoS2) due to its outstanding features in energy storage applications. Although MoS2 has a lot of active sulphur edges, the presence of inactive surfaces leads to limit conductivity and efficiency. Hence, in this article, we aimed to promote the additional active sites by doping various weight percentages (2%, 4%, 6%, 8% and 10%) of Nickel (Ni) into the MoS2 matrix by simple hydrothermal technique, and their doping effects were investigated with the help of Physio-chemical analyses. X-ray diffraction (XRD) pattern, Raman, and chemical composition (XPS) analyses were used to confirm the Ni incorporation in MoS2 nullosheets. Microscopic investigations demonstrated that Ni-doped MoS2 nullosheets were vertically aligned with enhanced interlayer spacing. Cyclic voltammetry, Galvanostatic charge-discharge, and elec-trochemical impedance spectroscopy investigations were used to characterize the electrochemical char-acteristics. The 6% Ni-doped MoS2 electrode material showed better CSP of 528.7 F/g @ 1 A/g and excellent electrochemical stability (85% of capacitance retention after 10,000 cycles at 5 A/g) compared to other electrode materials. Furthermore, the solid-state asymmetric supercapacitor was assembled using Ni-doped MoS2 and graphite as anode and cathode materials and analysed the electrochemical properties in the two-electrode system. To determine the impact of the Ni-atom on the MoS2 surface, first -principles computations were performed. Further, it was examined for electronic band structure, the pro-jected density of states (PDOS) and Bader charge transfer analyses.(c) 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 80, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 335, "End Page": 349, "Article Number": null, "DOI": "10.1016/j.jechem.2023.01.002", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2023.01.002", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000947446700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alibakhshikenari, M; Virdee, BS; Azpilicueta, L; Naser-Moghadasi, M; Akinsolu, MO; See, CH; Liu, B; Abd-Alhameed, RA; Falcone, F; Huynen, I; Denidni, TA; Limiti, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alibakhshikenari, Mohammad; Virdee, Bal S.; Azpilicueta, Leyre; Naser-Moghadasi, Mohammad; Akinsolu, Mobayode Olusola; See, Chan Hwang; Liu, Bo; Abd-Alhameed, Raed A.; Falcone, Francisco; Huynen, Isabelle; Denidni, Tayeb A.; Limiti, Ernesto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Comprehensive Survey of Metamaterial Transmission-Line Based Antennas: Design, Challenges, and Applications", "Source Title": "IEEE ACCESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this review paper, a comprehensive study on the concept, theory, and applications of composite right/left-handed transmission lines (CRLH-TLs) by considering their use in antenna system designs have been provided. It is shown that CRLH-TLs with negative permittivity (epsilon < 0) and negative permeability (mu < 0) have unique properties that do not occur naturally. Therefore, they are referred to as artificial structures called metamaterials. These artificial structures include series left-handed (LH) capacitances (C-L), shunt LH inductances (L-L), series right-handed (RH) inductances (L-R), and shunt RH capacitances (C-R) that are realized by slots or interdigital capacitors, stubs or via-holes, unwanted current flowing on the surface, and gap distance between the surface and ground-plane, respectively. In the most cases, it is also shown that structures based on CRLH metamaterial-TLs are superior than their conventional alternatives, since they have smaller dimensions, lower-profile, wider bandwidth, better radiation patterns, higher gain and efficiency, which make them easier and more cost-effective to manufacture and mass produce. Hence, a broad range of metamaterial-based design possibilities are introduced to highlight the improvement of the performance parameters that are rare and not often discussed in available literature. Therefore, this survey provides a wide overview of key early-stage concepts of metematerial-based designs as a thorough reference for specialist antennas and microwave circuits designers. To analyze the critical features of metamaterial theory and concept, several examples are used. Comparisons on the basis of physical size, bandwidth, materials, gain, efficiency, and radiation patterns are made for all the examples that are based on CRLH metamaterial-TLs. As revealed in all the metematerial design examples, foot-print area decrement is an important issue of study that have a strong impact for the enlargement of the next generation wireless communication systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2020, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 144778, "End Page": 144808, "Article Number": null, "DOI": "10.1109/ACCESS.2020.3013698", "DOI Link": "http://dx.doi.org/10.1109/ACCESS.2020.3013698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000560336700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "González, J; Stauber, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonzalez, J.; Stauber, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kohn-Luttinger Superconductivity in Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show that the recently observed superconductivity in twisted bilayer graphene (TBG) can be explained as a consequence of the Kohn-Luttinger(KL) instability which leads to an effective attraction between electrons with originally repulsive interaction. Usually, the KL instability takes place at extremely low energy scales, but in TBG, a doubling and subsequent strong coupling of the van Hove singularities (vHS) in the electronic spectrum occurs as the magic angle is approached, leading to extended saddle points in the highest valence band with almost perfect nesting between states belonging to different valleys. The highly anisotropic screening induces an effective attraction in a p-wave channel with odd parity under the exchange of the two disjoined patches of the Fermi line. We also predict the appearance of a spin-density wave instability, adjacent to the superconducting phase, and the opening of a gap in the electronic spectrum from the condensation of spins with wave vector corresponding to the nesting vector close to the vHS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2019, "Volume": 122, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26801, "DOI": "10.1103/PhysRevLett.122.026801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.026801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456041800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, HX; Holleis, L; Saito, Y; Cohen, L; Huynh, W; Patterson, CL; Yang, FY; Taniguchi, T; Watanabe, K; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Haoxin; Holleis, Ludwig; Saito, Yu; Cohen, Liam; Huynh, William; Patterson, Caitlin L.; Yang, Fangyuan; Taniguchi, Takashi; Watanabe, Kenji; Young, Andrea F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isospin magnetism and spin-polarized superconductivity in Bernal bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In conventional superconductors, Cooper pairing occurs between electrons of opposite spin. We observe spin-polarized superconductivity in Bernal bilayer graphene when doped to a saddle-point van Hove singularity generated by a large applied perpendicular electric field. We observe a cascade of electrostatic gate-tuned transitions between electronic phases distinguished by their polarization within the isospin space defined by the combination of the spin and momentum-space valley degrees of freedom. Although all of these phases are metallic at zero magnetic field, we observe a transition to a superconducting state at finite magnetic field B-parallel to approximate to 150 milliteslas applied parallel to the two-dimensional sheet. Superconductivity occurs near a symmetry-breaking transition and exists exclusively above the B-parallel to limit expected of a paramagnetic superconductor with the observed transition critical temperature T-C approximate to 30 millikelvins, consistent with a spin-triplet order parameter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2022, "Volume": 375, "Issue": 6582, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 774, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm8386", "DOI Link": "http://dx.doi.org/10.1126/science.abm8386", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758142600047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdolrazzaghi, M; Daneshmand, M; Iyer, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdolrazzaghi, Mohammad; Daneshmand, Mojgan; Iyer, Ashwin K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strongly Enhanced Sensitivity in Planar Microwave Sensors Based on Metamaterial Coupling", "Source Title": "IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Limited sensitivity and sensing range are arguably the greatest challenges in microwave sensor design. Recent attempts to improve these properties have relied on metamaterial (MTM)-inspired open-loop resonators coupled to transmission lines (TLs). Although the strongly resonullt properties of the resonator sensitively reflect small changes in the environment through a shift in its resonullce frequency, the resulting sensitivities remain ultimately limited by the level of coupling between the resonator and the TL. This paper introduces a novel solution to this problem that employs negative-refractive-index TL MTMs to substantially improve this coupling so as to fully exploit its resonullt properties. AMTM-infused planar microwave sensor is designed for operation at 2.5 GHz, and is shown to exhibit a significant improvement in sensitivity and linearity. A rigorous signal-flow analysis of the sensor is proposed and shown to provide a fully analytical description of all salient features of both the conventional and MTM-infused sensors. Full-wave simulations confirm the analytical predictions, and all data demonstrate excellent agreement with measurements of a fabricated prototype. The proposed device is shown to be especially useful in the characterization of commonly available high-permittivity liquids as well as in sensitively distinguishing concentrations of ethanol/methanol in water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 66, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1843, "End Page": 1855, "Article Number": null, "DOI": "10.1109/TMTT.2018.2791942", "DOI Link": "http://dx.doi.org/10.1109/TMTT.2018.2791942", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429225200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Asuquo, E; Martin, A; Nzerem, P; Siperstein, F; Fan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Asuquo, Edidiong; Martin, Alastair; Nzerem, Petrus; Siperstein, Flor; Fan, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of Cd(II) and Pb(II) ions from aqueous solutions using mesoporous activated carbon adsorbent: Equilibrium, kinetics and characterisation studies", "Source Title": "JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, cadmium and lead ions removal from aqueous solutions using a commercial activated carbon adsorbent (CGAC) were investigated under batch conditions. The adsorbent was observed to have a coarse surface with crevices, high resistance to attrition, high surface area and pore volume with bimodal pore size distribution which indicates that the material was mesoporous. Sorption kinetics for Cd(II) and Pb(II) ions proceeded through a two-stage kinetic profile-initial quick uptake occurring within 30 min followed by a gradual removal of the two metal ions until 180 min with optimum uptake (q(e, exp)) of 17.23 mg g(-1) and 16.84 mg g(-1) for Cd(II) and Pb(II) ions respectively. Modelling of sorption kinetics indicates that the pseudo first order (PFO) model described the sorption of Pb(II) ion better than Cd(II), while the reverse was observed with respect to the pseudo second order (PSO) model. Intraparticle diffusion modelling showed that intraparticle diffusion may not be the only mechanism that influenced the rate of ions uptake. Isotherm modelling was carried out and the results indicated that the Langmuir and Freundlich models described the uptake of Pb(II) ion better than Cd(II) ion. A comparison of the two models indicated that the Langmuir isotherm is the better isotherm for the description of Cd(II) and Pb(II) ions sorption by the adsorbent. The maximum loading capacity (q(max)) obtained from the Langmuir isotherm was 27.3 mg g(-1) and 20.3 mg g(-1) for Cd(II) and Pb(II) ions respectively. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 679, "End Page": 698, "Article Number": null, "DOI": "10.1016/j.jece.2016.12.043", "DOI Link": "http://dx.doi.org/10.1016/j.jece.2016.12.043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398950800070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Adilah, AN; Jamilaha, B; Noranizan, MA; Hanulli, ZAN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Adilah, A. Nor; Jamilaha, B.; Noranizan, M. A.; Hanulli, Z. A. Nur", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Utilization of mango peel extracts on the biodegradable films for active packaging", "Source Title": "FOOD PACKAGING AND SHELF LIFE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mango peels extract (MPE) was incorporated into fish gelatin films to determine their physical, barrier, mechanical and antioxidant properties for active food packaging. Films with three different concentrations of MPE (1-5%) were prepared by solution casting method. Films incorporated with MPE showed a decrease (P > 0.05) of water vapor permeability (WVP) and lower (P <= 0.05) films solubility. High level of MPE films also exhibited more rigid and less flexible film formation. Colored tint films and a reduction in transparency were due to the hydrogen bond linkages between fish gelatin molecules and phenolic content within the film matrix. Higher free radicals scavenging activities also observed for films with higher concentrations of MPE. This study reveals the benefits of mango by-products incorporated into gelatin based films as a potential material for active packaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 7, "Article Number": null, "DOI": "10.1016/j.fpsl.2018.01.006", "DOI Link": "http://dx.doi.org/10.1016/j.fpsl.2018.01.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432696900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sander, G; Thomas, S; Cruz, V; Jurg, M; Birbilis, N; Gao, X; Brameld, M; Hutchinson, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sander, G.; Thomas, S.; Cruz, V.; Jurg, M.; Birbilis, N.; Gao, X.; Brameld, M.; Hutchinson, C. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On The Corrosion and Metastable Pitting Characteristics of 316L Stainless Steel Produced by Selective Laser Melting", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The austenitic stainless steel 316L was additively manufactured using Selective Laser Melting (SLM). The corrosion characteristics of the additively manufactured (3D printed) specimens were investigated by both potentiodynamic and potentiostatic techniques. The production parameters were deliberately varied during SLM, to produce 316L specimens fabricated by different laser scan speed (in the range of 860-1160 mm/s) and laser power (in the range of 165-285 W). The fabrication parameters were found to influence the porosity of the resulting specimens. The pitting potentials, metastable pitting rates and repassivation potentials of the 3D printed specimens are presented herein as a function of the laser scan speed and laser power, and also discussed in the context of specimen porosity. The corrosion characteristics of the 3D printed 316L were also compared with wrought 316L, revealing higher pitting potentials and lower rates of metastable pitting for most SLM 316L specimens, the related concepts of which are discussed herein. c The Author(s) 2017. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons. org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@ electrochem. org. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 164, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "C250", "End Page": "C257", "Article Number": null, "DOI": "10.1149/2.0551706jes", "DOI Link": "http://dx.doi.org/10.1149/2.0551706jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401607500098", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JS; Li, WW; Huang, DS; Wang, L; Chen, E; Wu, CY; Wang, BS; Deng, HY; Tang, SW; Shi, Y; Li, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jiasheng; Li, Wenwei; Huang, Desheng; Wang, Lei; Chen, E.; Wu, Chengyou; Wang, Baoshan; Deng, Hongyang; Tang, Shengwen; Shi, Yan; Li, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractal Analysis on Pore Structure and Hydration of Magnesium Oxysulfate Cements by First Principle, Thermodynamic and Microstructure-Based Methods", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium oxysulfate (MOS) cement is a typical eco-friendly cementitious material, which presents excellent performances. In this work, a novel multiscale modeling strategy is proposed to simulate the hydration and pore structure of MOS cement system. This work collected and evaluated the Gibbs free energy of formation for main hydrates and equilibrium constant of main reactions in MOS cement system based on a first principle calculation using Material Studio. Followingly, the equilibrium phase compositions of MOS cement system were simulated through PHREEQC to investigate the molar ratio dependence of equilibrium phase compositions. Results showed that large M (MgO/MgSO4) was beneficial for the formation of 5Mg(OH)(2)center dot MgSO4 center dot 7H(2)O (Phase 517) and large H (H2O/MgSO4) tended to decompose MOS cement paste and cause leaching. The microstructure-based method visualized the hydration status of MOS cement systems at initial and ultimate stages via MATLAB and the results showed that large M was significant to reduce porosity, and similar results for the case of small H. Fractal analysis confirms that fractal dimension of pore structure (D-f) was significantly decreased after the hydration of MOS and was positively correlated to the porosity of the paste. In addition, it can be referred that large M and small H were beneficial for modifying the microstructure of MOS paste by decreasing the value of D-f.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 164, "DOI": "10.3390/fractalfract5040164", "DOI Link": "http://dx.doi.org/10.3390/fractalfract5040164", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737207300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ben-Abdallah, P; Biehs, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ben-Abdallah, Philippe; Biehs, Svend-Age", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-Field Thermal Transistor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using a block of three separated solid elements, a thermal source and drain together with a gate made of an insulator-metal transition material exchanging near-field thermal radiation, we introduce a nulloscale analog of a field-effect transistor that is able to control the flow of heat exchanged by evanescent thermal photons between two bodies. By changing the gate temperature around its critical value, the heat flux exchanged between the hot body (source) and the cold body (drain) can be reversibly switched, amplified, and modulated by a tiny action on the gate. Such a device could find important applications in the domain of nulloscale thermal management and it opens up new perspectives concerning the development of contactless thermal circuits intended for information processing using the photon current rather than the electric current.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 429, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2014, "Volume": 112, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 44301, "DOI": "10.1103/PhysRevLett.112.044301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.044301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331948400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bourada, M; Kaci, A; Houari, MSA; Tounsi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bourada, Mohamed; Kaci, Abdelhakim; Houari, Mohammed Sid Ahmed; Tounsi, Abdelouahed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new simple shear and normal deformations theory for functionally graded beams", "Source Title": "STEEL AND COMPOSITE STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, a simple and refined trigonometric higher-order beam theory is developed for bending and vibration of functionally graded beams. The beauty of this theory is that, in addition to modeling the displacement field with only 3 unknowns as in Timoshenko beam theory, the thickness stretching effect (epsilon(z) not equal 0) is also included in the present theory. Thus, the present refined beam theory has fewer number of unknowns and equations of motion than the other shear and normal deformations theories, and it considers also the transverse shear deformation effects without requiring shear correction factors. The neutral surface position for such beams in which the material properties vary in the thickness direction is determined. Based on the present refined trigonometric higher-order beam theory and the neutral surface concept, the equations of motion are derived from Hamilton's principle. Numerical results of the present theory are compared with other theories to show the effect of the inclusion of transverse normal strain on the deflections and stresses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 459, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 18, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 409, "End Page": 423, "Article Number": null, "DOI": "10.12989/scs.2015.18.2.409", "DOI Link": "http://dx.doi.org/10.12989/scs.2015.18.2.409", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352361900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hosny, M; Fawzy, M; Eltaweil, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hosny, Mohamed; Fawzy, Manal; Eltaweil, Abdelazeem S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of bimetallic Ag/ZnO@Biohar nullocomposite for photocatalytic degradation of tetracycline, antibacterial and antioxidant activities", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a simple and green synthesis procedure for phytofabrication Zinc oxide-silver supported biochar nullocomposite (Ag/ZnO@BC) via Persicaria salicifolia biomass is investigated for the first time to uphold numerous green chemistry such as less hazardous chemical syntheses. XRD technique showed the crystal structure of the phytosynthesized Ag/ZnO@BC, whereas UV-visible spectroscopy, FT-IR, SEM, EDX, TEM, and XPS analyses indicated the successful biosynthesis of the nullocomposite. Testing the photocatalytic potential of this novel nullocomposite in the removal of TC under different conditions unraveled its powerful photodegradation efficiency that reached 70.3% under the optimum reaction conditions: TC concentration; 50 ppm, pH; 6, a dose of Ag/ZnO@BC; 0.01 g, temperature; 25 degrees C, and H2O2 concentration; 100 mM. The reusability of Ag/ZnO@BC was evident as it reached 53% after six cycles of regeneration. Ag/ZnO@BC was also shown to be a potent antimicrobial agent against Klebsiella pneumonia as well as a promising antioxidant material. Therefore, the current work presented a novel nullocomposite that could be efficiently employed in various environmental and medical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7316, "DOI": "10.1038/s41598-022-11014-0", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-11014-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791506100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, Y; Zhang, Z; Zhou, QJ; Geng, H; Chen, Q; Kim, S; Zhang, R; Zhang, C; Chang, BW; Li, SY; Fu, HY; Xue, LW; Wang, HQ; Li, WB; Chen, WH; Gao, MY; Ye, L; Zhou, YY; Ouyang, YN; Zhang, CF; Gao, F; Yang, C; Li, YF; Zhang, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Yang; Zhang, Ze; Zhou, Qiuju; Geng, Hua; Chen, Qi; Kim, Seoyoung; Zhang, Rui; Zhang, Cen; Chang, Bowen; Li, Shangyu; Fu, Hongyuan; Xue, Lingwei; Wang, Haiqiao; Li, Wenbin; Chen, Weihua; Gao, Mengyuan; Ye, Long; Zhou, Yuanyuan; Ouyang, Yanni; Zhang, Chunfeng; Gao, Feng; Yang, Changduk; Li, Yongfang; Zhang, Zhi-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Geometry design of tethered small-molecule acceptor enables highly stable and efficient polymer solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the power conversion efficiency of binary polymer solar cells dramatically improved, the thermal stability of the small-molecule acceptors raised the main concerns on the device operating stability. Here, to address this issue, thiophene-dicarboxylate spacer tethered small-molecule acceptors are designed, and their molecular geometries are further regulated via the thiophene-core isomerism engineering, affording dimeric TDY-alpha with a 2, 5-substitution and TDY-beta with 3, 4-substitution on the core. It shows that TDY-alpha processes a higher glass transition temperature, better crystallinity relative to its individual small-molecule acceptor segment and isomeric counterpart of TDY-beta, and amore stablemorphology with the polymer donor. As a result, the TDY-alpha based device delivers a higher device efficiency of 18.1%, and most important, achieves an extrapolated lifetime of about 35000 hours that retaining 80% of their initial efficiency. Our result suggests that with proper geometry design, the tethered small-molecule acceptors can achieve both high device efficiency and operating stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2926, "DOI": "10.1038/s41467-023-38673-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38673-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001024186000035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Boarino, A; Klok, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Boarino, Alice; Klok, Harm-Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Opportunities and Challenges for Lignin Valorization in Food Packaging, Antimicrobial, and Agricultural Applications", "Source Title": "BIOMACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The exploration of renewable resources is essential to help transition toward a more sustainable materials economy. The valorization of lignin can be a key component of this transition. Lignin is an aromatic polymer that constitutes approximately one-third of the total lignocellulosic biomass and is isolated in huge quantities as a waste material of biofuel and paper production. About 98% of the 100 million tons of lignin produced each year is simply burned as low-value fuel, so this renewable polymer is widely available at very low cost. Lignin has valuable properties that make it a promising material for numerous applications, but it is far from being fully exploited. The aim of this Perspective is to highlight opportunities and challenges for the use of lignin-based materials in food packaging, antimicrobial, and agricultural applications. In the first part, the ongoing research and the possible future developments for the use of lignin as an additive to improve mechanical, gas and UV barrier, and antioxidant properties of food packaging items will be treated. Second, the application of lignin as an antimicrobial agent will be discussed to elaborate on the activity of lignin against bacteria, fungi, and viruses. Finally, the use of lignin in agriculture will be presented by focusing on the application of lignin as fertilizer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2023, "Volume": 24, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1065, "End Page": 1077, "Article Number": null, "DOI": "10.1021/acs.biomac.2c01385", "DOI Link": "http://dx.doi.org/10.1021/acs.biomac.2c01385", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928613900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kazyak, E; Garcia-Mendez, R; LePage, WS; Sharafi, A; Davis, AL; Sanchez, AJ; Chen, KH; Haslam, C; Sakamoto, J; Dasgupta, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kazyak, Eric; Garcia-Mendez, Regina; LePage, William S.; Sharafi, Asma; Davis, Andrew L.; Sanchez, Adrian J.; Chen, Kuan-Hung; Haslam, Catherine; Sakamoto, Jeff; Dasgupta, Neil P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility", "Source Title": "MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state electrolytes (SSEs) have attracted substantial attention for next-generation Li-metal batteries, but Li-filament propagation at high current densities remains a significant challenge. This study probes the coupled electrochemicalmorphological-mechanical evolution of Li-metal-Li7La3Zr2O12 interfaces. Quantitative analysis of synchronized electrochemistry with operando video microscopy reveals new insights into the nature of Li propagation in SSEs. Several different filament morphologies are identified, demonstrating that a singular mechanism is insufficient to describe the complexity of Li propagation pathways. The dynamic evolution of the structures is characterized, which demonstrates the relationships between current density and propagation velocity, as well as reversibility of plated Li before short-circuit occurs. Under deep discharge, void formation and dewetting are directly observed, which are directly related to evolving overpotentials during stripping. Finally, similar Li penetration behavior is observed in glassy Li3PS4, demonstrating the relevance of the new insights to SSEs more generally.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1025, "End Page": 1048, "Article Number": null, "DOI": "10.1016/j.matt.2020.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.matt.2020.02.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522913200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gonze, X; Amadon, B; Antonius, G; Arnardi, F; Baguet, L; Beuken, JM; Bieder, J; Bottin, F; Bouchet, J; Bousquet, E; Brouwer, N; Bruneval, F; Brunin, G; Cavignac, T; Charraud, JB; Chen, W; Côté, M; Cottenier, S; Denier, J; Geneste, G; Ghosez, P; Giantomassi, M; Gillet, Y; Gingras, O; Hamann, DR; Hautier, G; He, X; Helbig, N; Holzwarth, N; Jia, YC; Jollet, F; Lafargue-Dit-Hauret, W; Lejaeghere, K; Marques, MAL; Martin, A; Martins, C; Miranda, HPC; Naccarato, F; Persson, K; Petretto, G; Planes, V; Pouillon, Y; Prokhorenko, S; Ricci, F; Rignullese, GM; Romero, AH; Schmitt, MM; Torrent, M; van Setten, MJ; Van Troeye, B; Verstraete, MJ; Zerah, G; Zwanziger, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gonze, Xavier; Amadon, Bernard; Antonius, Gabriel; Arnardi, Frederic; Baguet, Lucas; Beuken, Jean-Michel; Bieder, Jordan; Bottin, Francois; Bouchet, Johann; Bousquet, Eric; Brouwer, Nils; Bruneval, Fabien; Brunin, Guillaume; Cavignac, Theo; Charraud, Jean-Baptiste; Chen, Wei; Cote, Michel; Cottenier, Stefaan; Denier, Jules; Geneste, Gregory; Ghosez, Philippe; Giantomassi, Matteo; Gillet, Yannick; Gingras, Olivier; Hamann, Donald R.; Hautier, Geoffroy; He, Xu; Helbig, Nicole; Holzwarth, Natalie; Jia, Yongchao; Jollet, Francois; Lafargue-Dit-Hauret, William; Lejaeghere, Kurt; Marques, Miguel A. L.; Martin, Alexandre; Martins, Cyril; Miranda, Henrique P. C.; Naccarato, Francesco; Persson, Kristin; Petretto, Guido; Planes, Valentin; Pouillon, Yann; Prokhorenko, Sergei; Ricci, Fabio; Rignullese, Gian-Marco; Romero, Aldo H.; Schmitt, Michael Marcus; Torrent, Marc; van Setten, Michiel J.; Van Troeye, Benoit; Verstraete, Matthieu J.; Zerah, Gilles; Zwanziger, Josef W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The ABINIT project: Impact, environment and recent developments", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ABINIT is a material- and nullostructure-oriented package that implements density-functional theory (DFT) and many-body perturbation theory (MBPT) to find, from first principles, numerous properties including total energy, electronic structure, vibrational and thermodynamic properties, different dielectric and non-linear optical properties, and related spectra. In the special issue to celebrate the 40th anniversary of CPC, published in 2009, a detailed account of ABINIT was included [Gonze et al. (2009)], and has been amply cited. The present article comes as a follow-up to this 2009 publication. It includes an analysis of the impact that ABINIT has had, through for example the bibliometric indicators of the 2009 publication. Links with several other computational materials science projects are described. This article also covers the new capabilities of Mimi - that - have-been-implemented during_the_last three years, complementing a recent update of the 2009 article published in 2016. Physical and technical developments inside the abinit application are covered, as well as developments provided with the ABINIT package, Such as the MULTIBINIT and A-TDEP projects, and related ABImirorganization developments such as ABIPY. The new developments are described with relevant references, input variables, tests, and tutorials. Program summary Program Title: ABINIT Program Files doi : http://dx.doi.org/10.17632/csvdrr4d68.1 Licensing provisions: GPLv3 Programming language: Fortran2003, Python Journal reference of previous version: X .Gonze et al, Comput. Phys. Commun. 205 (2016) 106-131 Does the new version supersede the previous version?: Yes. The present 8.10.3 version is now the up-to-date stable version of abinit, and supercedes the 7.10.5 version. Reasons for the new version: New developments Summary of revisions: Many new capabilities of the main abinit application, related to density-functional theory, density-functional perturbation theory, GW, the Bethe-Salpeter equation, dynamical mean-field theory, etc. New applications in the package: multibinit (second-principles calculations) and tdep (temperature-dependent properties) Nature of problem: Computing accurately material and nullostructure properties: electronic structure, bond lengths, bond angles, primitive cell, cohesive energy, dielectric properties, vibrational properties, elastic properties, optical properties, magnetic properties, non-linear couplings, electronic and vibrational lifetimes, etc. For large-scale systems, second-principles calculations, building upon the first-principles results, are also possible. Solution method: Software application based on density-functional theory and many-body perturbation theory, pseudopotentials, with plane waves or wavelets as basis functions. Different real-time algorithms are implemented for second-principles calculations. (C) 2019 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 248, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107042, "DOI": "10.1016/j.cpc.2019.107042", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2019.107042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509613900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cornelissen, LJ; Peters, KJH; Bauer, GEW; Duine, RA; van Wees, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cornelissen, L. J.; Peters, K. J. H.; Bauer, G. E. W.; Duine, R. A.; van Wees, B. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnon spin transport driven by the magnon chemical potential in a magnetic insulator", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a linear-response transport theory of diffusive spin and heat transport by magnons in magnetic insulators with metallic contacts. The magnons are described by a position-dependent temperature and chemical potential that are governed by diffusion equations with characteristic relaxation lengths. Proceeding from a linearized Boltzmann equation, we derive expressions for length scales and transport coefficients. For yttrium iron garnet (YIG) at room temperature we find that long-range transport is dominated by the magnon chemical potential. We compare the model's results with recent experiments on YIG with Pt contacts [L. J. Cornelissen et al., Nat. Phys. 11, 1022 (2015)] and extract a magnon spin conductivity of sigma(m) = 5 x 10(5) S/m. Our results for the spin Seebeck coefficient in YIG agree with published experiments. We conclude that the magnon chemical potential is an essential ingredient for energy and spin transport in magnetic insulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 256, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2016, "Volume": 94, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14412, "DOI": "10.1103/PhysRevB.94.014412", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.014412", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379497400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pasaribu, KM; Ilyas, S; Tamrin, T; Radecka, I; Swingler, S; Gupta, A; Stamboulis, AG; Gea, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pasaribu, Khatarina Meldawati; Ilyas, Syafruddin; Tamrin, Tamrin; Radecka, Izabela; Swingler, Sam; Gupta, Abhishek; Stamboulis, Artemis G.; Gea, Saharman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioactive bacterial cellulose wound dressings for burns with collagen in-situ and chitosan ex-situ impregnation", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial cellulose (BC) is a biopolymer that commonly used for wound dressings regarding to its high in-vitro and in-vivo biocompatibility. Moreover, the three-dimensional fibers in BC become an advantageous for bioactive wound dressing application as they serve as templates for impregnation other supportive materials. Chitosan and collagen are two of the materials that can be impregnated to optimize the BC properties for serve as wound dressing material. Collagen can help skin cells grow on the wound sites, where chitosan has anti-bacterial properties and can bind red blood cells. BC-based wound dressings were made by impregnating collagen via in-situ method followed by immersing chitosan via ex-situ method into BC fibers for 24 h. The intermolecular interactions of amine groups in the wound dressing were confirmed by FTIR. The XRD diffractogram showed wider peaks at 14.2 degrees, 16.6 degrees, and 22.4 degrees due to the presence of collagen and chitosan molecules in the BC fibers. SEM images confirmed that chitosan and collagen could penetrate BC fibers well. Other tests, such as water content, porosity, antibacterial properties, and haemocompatibility, indicated that the wound dressing was non-hemolytic. In-vivo test indicated that BC/collagen/chitosan wound dressing supported the wound healing process on second degree burn.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 230, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123118, "DOI": "10.1016/j.ijbiomac.2022.123118", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2022.123118", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000963552100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ryou, J; Kim, YS; Santosh, KC; Cho, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ryou, Junga; Kim, Yong-Sung; Santosh, K. C.; Cho, Kyeongjae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolayer MoS2 Bandgap Modulation by Dielectric Environments and Tunable Bandgap Transistors", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductors with a moderate bandgap have enabled modern electronic device technology, and the current scaling trends down to nullometer scale have introduced two-dimensional (2D) semiconductors. The bandgap of a semiconductor has been an intrinsic property independent of the environments and determined fundamental semiconductor device characteristics. In contrast to bulk semiconductors, we demonstrate that an atomically thin two-dimensional semiconductor has a bandgap with strong dependence on dielectric environments. Specifically, monolayer MoS2 bandgap is shown to change from 2.8 eV to 1.9 eV by dielectric environment. Utilizing the bandgap modulation property, a tunable bandgap transistor, which can be in general made of a two-dimensional semiconductor, is proposed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29184, "DOI": "10.1038/srep29184", "DOI Link": "http://dx.doi.org/10.1038/srep29184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379191600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiang, LL; Darboe, AK; Luo, ZH; Qi, XS; Shao, JJ; Ye, XJ; Liu, CS; Sun, K; Qu, YP; Xu, J; Zhong, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiang, Lele; Darboe, Abdou Karim; Luo, Zhihong; Qi, Xiaosi; Shao, Jiao-jing; Ye, Xiao-Juan; Liu, Chun-Sheng; Sun, Kai; Qu, Yunpeng; Xu, Jing; Zhong, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing two-dimensional/two-dimensional reduced graphene oxide/MoX2 (X = Se and S) van der Waals heterojunctions: a combined composition modulation and interface engineering strategy for microwave absorption", "Source Title": "ADVANCED COMPOSITES AND HYBRID MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interface engineering and/or impedance matching characteristic played a very important role in microwave absorption. To simultaneously make best of these aspects, herein, two-dimensional (2D)/2D reduced graphene oxide (RGO)/MoSe2 van der Waals heterojunctions (VDWHs) were elaborately designed and successfully produced in large scale and high efficiency through a simple solvothermal method. By increasing the amount of graphene oxide (GO) from 15 to 45 mg, the designed 2D/2D RGO/MoSe2 VDWHs with enhanced RGO contents and interfaces could be synthesized, which resulted in their progressively boosted comprehensive microwave absorption properties (MAPs). Furthermore, the proposed route could also be expanded to fabricate 2D/2D RGO/MoS2 VDWHs. The obtained results demonstrated that the enhanced amount of GO effectively improved their impedance matching characteristics, conductivity loss, and polarization loss capabilities of 2D/2D RGO/MoX2 (X = Se and S) VDWHs, which contributed to their enhanced comprehensive MAPs. In particular, the RGO/MoSe2 VDWHs displayed a minimum reflection loss of - 65.34 dB at 6.40 GHz and an effective absorption bandwidth of 4.20 GHz. Therefore, the findings not only presented a combined composition modulation and interface engineering strategy to simultaneously take full advantage of impedance matching characteristics and interfaces for improving the comprehensive MAPs but also provided a simple and propagable route to design and synthesize 2D/2D RGO/MoX2 (X = Se and S) VDWHs, which could be acted as the good candidates for lightweight high-efficiency microwave absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 215, "DOI": "10.1007/s42114-023-00793-3", "DOI Link": "http://dx.doi.org/10.1007/s42114-023-00793-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001119523500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pizzi, G; Vitale, V; Arita, R; Blügel, S; Freimuth, F; Géranton, G; Gibertini, M; Gresch, D; Johnson, C; Koretsune, T; Ibañez-Azpiroz, J; Lee, H; Lihm, JM; Marchand, D; Marrazzo, A; Mokrousov, Y; Mustafa, JI; Nohara, Y; Nomura, Y; Paulatto, L; Poncé, S; Ponweiser, T; Qiao, JF; Thöle, F; Tsirkin, SS; Wierzbowska, M; Marzari, N; Vanderbilt, D; Souza, I; Mostofi, AA; Yates, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pizzi, Giovanni; Vitale, Valerio; Arita, Ryotaro; Bluegel, Stefan; Freimuth, Frank; Geranton, Guillaume; Gibertini, Marco; Gresch, Dominik; Johnson, Charles; Koretsune, Takashi; Ibanez-Azpiroz, Julen; Lee, Hyungjun; Lihm, Jae-Mo; Marchand, Daniel; Marrazzo, Antimo; Mokrousov, Yuriy; Mustafa, Jamal, I; Nohara, Yoshiro; Nomura, Yusuke; Paulatto, Lorenzo; Ponce, Samuel; Ponweiser, Thomas; Qiao, Junfeng; Thoele, Florian; Tsirkin, Stepan S.; Wierzbowska, Malgorzata; Marzari, Nicola; Vanderbilt, David; Souza, Ivo; Mostofi, Arash A.; Yates, Jonathan R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wannier90 as a community code: new features and applications", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wannier90 is an open-source computer program for calculating maximally-localised Wannier functions (MLWFs) from a set of Bloch states. It is interfaced to many widely used electronic-structure codes thanks to its independence from the basis sets representing these Bloch states. In the past few years the development of Wannier90 has transitioned to a community-driven model; this has resulted in a number of new developments that have been recently released in Wannier90 v3.0. In this article we describe these new functionalities, that include the implementation of new features for wannierisation and disentanglement (symmetry-adapted Wannier functions, selectively-localised Wannier functions, selected columns of the density matrix) and the ability to calculate new properties (shift currents and Berry-curvature dipole, and a new interface to many-body perturbation theory); performance improvements, including parallelisation of the core code; enhancements in functionality (support for spinor-valued Wannier functions, more accurate methods to interpolate quantities in the Brillouin zone); improved usability (improved plotting routines, integration with high-throughput automation frameworks), as well as the implementation of modern software engineering practices (unit testing, continuous integration, and automatic source-code documentation). These new features, capabilities, and code development model aim to further sustain and expand the community uptake and range of applicability, that nowadays spans complex and accurate dielectric, electronic, magnetic, optical, topological and transport properties of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1281, "Times Cited, All Databases": 1341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2020, "Volume": 32, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 165902, "DOI": "10.1088/1361-648X/ab51ff", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ab51ff", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520450700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bom, S; Ribeiro, R; Ribeiro, HM; Santos, C; Marto, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bom, Sara; Ribeiro, Ricardo; Ribeiro, Helena M.; Santos, Catarina; Marto, Joana", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the progress of hydrogel-based 3D printing: Correlating rheological properties with printing behaviour", "Source Title": "INTERNATIONAL JOURNAL OF PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the exciting future directions in the 3D printing field is the development of innovative personalized smart constructions for bio-applications, including drug delivery, namely high-throughput drug screening and customized topical/oral administration of pharmaceuticals, as well as tissue engineering. In this context, hydrogels have emerged as a promising material that, when combined with extrusion 3D printing, allow the creation of soft-material structures with defined spatial locations, that can be printed at room temperature and customized by tuning the geometric design and/or the formulation components. Thus, the efficacy and quality of such vehicles is dependent on formulation, design, and printing process parameters. However, hydrogel inks are often designed and characterized using different methods and this lack of uniformity impairs. Characterization techniques are usually arbitrary and differ among research groups, challenging the inference of possible con-clusions on hydrogel behaviour and potential applications. Therefore, to properly analyse the potential of a particular hydrogel ink formulation, we review, for the first time, the most frequently employed characterization procedures, from rheological approaches to printing parameters and settings, and discuss their relevance, lim-itations and drawbacks, and highlight future perspectives. Overall, to accelerate the development of high-quality 3D constructs, comprehensive characterization protocols for both pre-printing and printing assays should be adopted. Furthermore, their transversal adoption could serve as a boost in terms of quality requirements and regulatory aspects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 5", "Publication Year": 2022, "Volume": 615, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121506, "DOI": "10.1016/j.ijpharm.2022.121506", "DOI Link": "http://dx.doi.org/10.1016/j.ijpharm.2022.121506", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778367000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Müller, K; Krause, FF; Béché, A; Schowalter, M; Galioit, V; Löffler, S; Verbeeck, J; Zweck, J; Schattschneider, P; Rosenauer, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mueller, Knut; Krause, Florian F.; Beche, Armand; Schowalter, Marco; Galioit, Vincent; Loeffler, Stefan; Verbeeck, Johan; Zweck, Josef; Schattschneider, Peter; Rosenauer, Andreas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic electric fields revealed by a quantum mechanical approach to electron picodiffraction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By focusing electrons on probes with a diameter of 50 pm, aberration-corrected scanning transmission electron microscopy (STEM) is currently crossing the border to probing subatomic details. A major challenge is the measurement of atomic electric fields using differential phase contrast (DPC) microscopy, traditionally exploiting the concept of a field- induced shift of diffraction patterns. Here we present a simplified quantum theoretical interpretation of DPC. This enables us to calculate the momentum transferred to the STEM probe from diffracted intensities recorded on a pixel array instead of conventional segmented bright- field detectors. The methodical development yielding atomic electric field, charge and electron density is performed using simulations for binary GaN as an ideal model system. We then present a detailed experimental study of SrTiO3 yielding atomic electric fields, validated by comprehensive simulations. With this interpretation and upgraded instrumentation, STEM is capable of quantifying atomic electric fields and high-contrast imaging of light atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5653, "DOI": "10.1038/ncomms6653", "DOI Link": "http://dx.doi.org/10.1038/ncomms6653", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347227700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, P; Pan, JY; Han, L; Cui, JM; Gao, Y; Fan, MS; Li, WS; Chi, Z; Zhang, KH; Cheng, ZL; Liu, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Pei; Pan, Jun-Yi; Han, Liang; Cui, Jian-Ming; Gao, Yan; Fan, Ming-Sen; Li, Wen-Sheng; Chi, Zhe; Zhang, Kai-Han; Cheng, Zhi-Lin; Liu, Yu-Pei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tungsten and tin deposits in South China: Temporal and spatial distribution, metallogenic models and prospecting directions", "Source Title": "ORE GEOLOGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "South China is one of the most important tungsten-tin metallogenic areas in the world. Based on the up-to-date geological and chronological data of more than 130 deposits of economic significance, this paper preliminarily summarized the main types and temporal-spatial distribution characteristics of the large-scale tungsten and tin mineralization related to granite in South China. The statistical results show that skarn and quartz-vein types are the most important tungsten metallogenic styles, while skarn and cassiterite-sulfide types are the most important tin metallogenic styles in South China. Tungsten and tin mineralization related to granite in South China are multi-aged, but the largest scale of mineralization is developed within the Yanshanian period. Tungsten mineralization, the majority of which represented by the nullling and Ganbei metallogenic belts, mainly formed from the Late Jurassic to Early Cretaceous (160 -120 Ma), while the most important tin mineralization formed in the Late Cretaceous (110 -80 Ma, peaking at 90 -80 Ma) and Late Jurassic (160 -150 Ma) as represented by the Youjiang Basin and nullling metallogenic belt, respectively. The combined occurrence of different mineralization styles or metal assemblages in individual deposit and sometimes within the same orefield is the most striking feature of granite-related tungsten-tin deposits in South China, and a comprehensive understanding of their patterns are of great significance to guide ore prospecting. To address this issue, this paper proposed several combined metallogenic models and prospecting directions for tungsten-tin mineralization in South China based on recent researches and exploration progresses from typical examples including the Yaogangxian, Chuankou, Maoping, Shizhuyuan, Dachang and Gejiu deposits or orefields. In addition, conventional petrological and mineralogical characteristics that differentiates tungsten and tin granites are summarized, and on this basis the chemical composition of both melt inclusion and early stage fluid inclusion from granitic magmatic -hydrothermal systems were tested as new index to evaluate the tungsten and tin mineralization potential of granitic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105453, "DOI": "10.1016/j.oregeorev.2023.105453", "DOI Link": "http://dx.doi.org/10.1016/j.oregeorev.2023.105453", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000999873500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hannachi, E; Slimani, Y; Nawaz, M; Sivakumar, R; Trabelsi, Z; Vignesh, R; Akhtar, S; Almessiere, MA; Baykal, A; Yasin, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hannachi, Essia; Slimani, Yassine; Nawaz, Muhammad; Sivakumar, R.; Trabelsi, Zayneb; Vignesh, R.; Akhtar, Sultan; Almessiere, Munirah A.; Baykal, Abdulhadi; Yasin, Ghulam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of cerium and yttrium doped ZnO nulloparticles and tracking their structural, optical, and photocatalytic performances", "Source Title": "JOURNAL OF RARE EARTHS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Yttrium (Y) and cerium (Ce) co-doped ZnO nulloparticles (NPs) were synthesized via the simple sol-gel auto-combustion route. The effect of Ce and Y doping on the structure, morphology, optical, Zeta po-tential, and photocatalytic activities of ZnO NPs was examined by Fourier transform infrared (FTIR) spectrometer, X-ray diffraction (XRD), transmission electron microscope (TEM), UV-vis spectropho-tometer, and Zetasizer instrument. XRD data show that the fabricated samples crystallize into a hex-agonal wurtzite structure. The dopants Y and Ce affect the crystal structure of ZnO NPs. The crystallite size is reduced with the co-doping effect. TEM results confirm the nullo-sized particles of the prepared samples. An increase in optical bandgap values from 3.19 eV for x = 0.0 to 3.22, 3.24, and 3.25 eV for x = 0.01, 0.03, and 0.05 samples was confirmed by UV-Vis spectroscopy analysis. Y and Ce co-doped ZnO nulloparticles show significant alteration of zeta potential and photocatalytic properties compared to undoped ZnO NPs. Comparatively, undoped ZnO shows better stability in deionized water as compared to Ce-Y doped ZnO NPs and exhibits high photocatalytic activity (degradation rate, 97.92%) for methyl orange (MO) degradation.(c) 2022 Chinese Society of Rare Earths. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 41, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 682, "End Page": 688, "Article Number": null, "DOI": "10.1016/j.jre.2022.03.020", "DOI Link": "http://dx.doi.org/10.1016/j.jre.2022.03.020", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000988612900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rodrigues, TA; Farias, FWC; Zhang, KP; Shamsolhodaei, A; Shen, JJ; Zhou, N; Schell, N; Capek, J; Polatidis, E; Santos, TG; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rodrigues, Tiago A.; Farias, Francisco Werley Cipriano; Zhang, Kaiping; Shamsolhodaei, A.; Shen, Jiajia; Zhou, N.; Schell, Norbert; Capek, Jan; Polatidis, E.; Santos, Telmo G.; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire and arc additive manufacturing of 316L stainless steel/Inconel 625 functionally graded material: development and characterization", "Source Title": "JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a 316L stainless steel to Inconel 625 functionally graded material (FGM) was built using different deposition strategies (named as direct and smooth-type interfaces) by Twin-Wire and Arc Additive Manufacturing (T-WAAM). This combination of materials is of interest in chemical plants, oil & gas, and nuclear applications, where high corrosion and wear resistance are essential requirements. Although these properties are superior in Inconel 625, replacing Inconel with stainless steel in strategic regions of structural components can reduce the overall costs and parts' weight. Both direct and smooth transition interfaces were tested and characterized. Microscopic analysis revealed that each interface and the as-built samples had an austenitic matrix, and every sample was well bonded and free of defects. Different types of microstructures evolved at the interfaces due to distinct gradients in composition. Synchrotron X-ray diffraction measurements showed that the smooth-gradient produced secondary phases, such as delta-phase (Ni3Nb) and carbides, that were not present with the direct interface strategy. Overall, the properties were superior in the FGM with a direct interface, which experienced higher strengths and elongations upon failure. Moreover, neutron diffraction measurements revealed that lower residual stresses developed in the direct interface FGM than in the smooth gradient FGM. (c) 2022 The Author(s). Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 131, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV-DEC", "Publication Year": 2022, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 237, "End Page": 251, "Article Number": null, "DOI": "10.1016/j.jmrt.2022.08.169", "DOI Link": "http://dx.doi.org/10.1016/j.jmrt.2022.08.169", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000907502000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, XY; Heumueller, T; Gruber, W; Classen, A; Unruh, T; Li, N; Brabec, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Xiaoyan; Heumueller, Thomas; Gruber, Wolfgang; Classen, Andrej; Unruh, Tobias; Li, Ning; Brabec, Christoph J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Polymer Solar Cells Based on Non-fullerene Acceptors with Potential Device Lifetime Approaching 10 Years", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic solar cells (OSCs) based on non-fullerene acceptors (NFAs) have developed very fast in recent years. A proper balance among power conversion efficiency (PCE), stability, and production cost needs further elaboration. Here we investigate the industrial viability of highly efficient OSCs based on several representative NFAs. The most stable OSCs exhibit PCE of similar to 8% along with extrapolated T-80 lifetime (80% of the initial PCE) of over 11,000 hr under equivalent 1 sun illumination, which would lead to a very impressive operational lifetime approaching 10 years. Photo-stability is strongly dependent on the end-group and side-chain engineering of the NFAs. Breaking of conjugation during photo-aging leads to increased energetic traps. Fluorination of the end-group stabilizes molecules against light soaking, while adding methyl groups shows an opposite trend. Side-chain modification can significantly influence the morphological stability. Reducing synthetic complexity of this class of NFAs will ultimately push the organic photovoltaics technology into real-life applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 215, "End Page": 226, "Article Number": null, "DOI": "10.1016/j.joule.2018.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hea, R; Kraemer, D; Mao, J; Zeng, L; Jie, Q; Lan, YC; Li, CH; Shuai, J; Kim, HS; Liu, Y; Broido, D; Chu, CW; Chen, G; Ren, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hea, Ran; Kraemer, Daniel; Mao, Jun; Zeng, Lingping; Jie, Qing; Lan, Yucheng; Li, Chunhua; Shuai, Jing; Kim, Hee Seok; Liu, Yuan; Broido, David; Chu, Ching-Wu; Chen, Gang; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving high power factor and output power density in p-type half-Heuslers Nb1-xTixFeSb", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improvements in thermoelectric material performance over the past two decades have largely been based on decreasing the phonon thermal conductivity. Enhancing the power factor has been less successful in comparison. In this work, a peak power factor of similar to 106 mu W.cm(-1).K-2 is achieved by increasing the hot pressing temperature up to 1,373 K in the p-type half-Heusler Nb0.95Ti0.05FeSb. The high power factor subsequently yields a record output power density of similar to 22 W.cm(-2) based on a single-leg device operating at between 293 K and 868 K. Such a high-output power density can be beneficial for large-scale power generation applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2016, "Volume": 113, "Issue": 48, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13576, "End Page": 13581, "Article Number": null, "DOI": "10.1073/pnas.1617663113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1617663113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388835700038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Morimoto, N; Kubo, T; Nishina, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Morimoto, Naoki; Kubo, Takuya; Nishina, Yuta", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring the Oxygen Content of Graphite and Reduced Graphene Oxide for Specific Applications", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene oxide (GO) is widely recognized as a promising material in a variety of fields, but its structure and composition has yet to be fully controlled. We have developed general strategies to control the oxidation degree of graphene-like materials via two methods: oxidation of graphite by KMnO4 in H2SO4 (oGO), and reduction of highly oxidized GO by hydrazine (rGO). Even though the oxygen content may be the same, oGO and rGO have different properties, for example the adsorption ability, oxidation ability, and electron conductivity. These differences in property arise from the difference in the underlying graphitic structure and the type of defect present. Our results can be used as a guideline for the production of tailor-made graphitic carbons. As an example, we show that rGO with 23.1 wt% oxygen showed the best performance as an electrode of an electric double-layer capacitor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21715, "DOI": "10.1038/srep21715", "DOI Link": "http://dx.doi.org/10.1038/srep21715", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370787600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ashammakhi, N; Ahadian, S; Xu, C; Montazerian, H; Ko, H; Nasiri, R; Barros, N; Khademhosseini, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ashammakhi, N.; Ahadian, S.; Xu, C.; Montazerian, H.; Ko, H.; Nasiri, R.; Barros, N.; Khademhosseini, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bioinks and bioprinting technologies to make heterogeneous and biomimetic tissue constructs", "Source Title": "MATERIALS TODAY BIO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The native tissues are complex structures consisting of different cell types, extracellular matrix materials, and biomolecules. Traditional tissue engineering strategies have not been able to fully reproduce biomimetic and heterogeneous tissue constructs because of the lack of appropriate biomaterials and technologies. However, recently developed three-dimensional bioprinting techniques can be leveraged to produce biomimetic and complex tissue structures. To achieve this, multicomponent bioinks composed of multiple biomaterials (natural, synthetic, or hybrid natural-synthetic biomaterials), different types of cells, and soluble factors have been developed. In addition, advanced bioprinting technologies have enabled us to print multimaterial bioinks with spatial and microscale resolution in a rapid and continuous manner, aiming to reproduce the complex architecture of the native tissues. This review highlights important advances in heterogeneous bioinks and bioprinting technologies to fabricate biomimetic tissue constructs. Opportunities and challenges to further accelerate this research area are also described.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 354, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100008, "DOI": "10.1016/j.mtbio.2019.100008", "DOI Link": "http://dx.doi.org/10.1016/j.mtbio.2019.100008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546326200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pizzi, G; Cepellotti, A; Sabatini, R; Marzari, N; Kozinsky, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pizzi, Giovanni; Cepellotti, Andrea; Sabatini, Riccardo; Marzari, Nicola; Kozinsky, Boris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "AiiDA: automated interactive infrastructure and database for computational science", "Source Title": "COMPUTATIONAL MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Computational science has seen in the last decades a spectacular rise in the scope, breadth, and depth of its efforts. Notwithstanding this prevalence and impact, it is often still performed using the renaissance model of individual artisans gathered in a workshop, under the guidance of an established practitioner. Great benefits could follow instead from adopting concepts and tools coming from computer science to manage, preserve, and share these computational efforts. We illustrate here our paradigm sustaining such vision, based around the four pillars of Automation, Data, Environment, and Sharing. We then discuss its implementation in the open-source AiiDA platform (http://www.aiida.net), that has been tuned first to the demands of computational materials science. AiiDA's design is based on directed acyclic graphs to track the provenullce of data and calculations, and ensure preservation and searchability. Remote computational resources are managed transparently, and automation is coupled with data storage to ensure reproducibility. Last, complex sequences of calculations can be encoded into scientific workflows. We believe that AiiDA's design and its sharing capabilities will encourage the creation of social ecosystems to disseminate codes, data, and scientific workflows. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 394, "Times Cited, All Databases": 446, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 111, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 218, "End Page": 230, "Article Number": null, "DOI": "10.1016/j.commatsci.2015.09.013", "DOI Link": "http://dx.doi.org/10.1016/j.commatsci.2015.09.013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364164400030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Falagán, C; Grail, BM; Johnson, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Falagan, Carmen; Grail, Barry M.; Johnson, D. Barrie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New approaches for extracting and recovering metals from mine tailings", "Source Title": "MINERALS ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Waste materials from metal mining, such as mineral tailings, often contain significant amounts of potentially valuable metals particularly where, as in many historic operations, the efficiency of flotation technologies used to concentrate target minerals was not as good as those currently available. A two-stage mineral leaching and metal recovery protocol was developed to extract copper from tailings generated as waste materials in two mines currently operating in Spain and Serbia. The most effective extraction of copper (84 to >90%) was achieved by bioleaching the tailings at 45 degrees C, using a defined microbial consortium, where elemental sulfur was added to the tailings and the pH of leach liquors allowed to fall to similar to pH 1, at which point anaerobic conditions were imposed. The thermo-tolerant acidophiles Acidithiobacillus caldus and Sulfobacillus thermosulfidooxidans emerged as the dominullt bacteria present in both tailings leachates under these conditions. Copper present in the pregnullt leach solutions (PLS) produced were next precipitated as a sulfide phase using hydrogen sulfide generated in a low pH (4.0) sulfidogenic bioreactor. The off-line system used allowed the copper present in PLS to be precipitated selectively without the need to adjust the pH of the PLS, though small amounts of silver present in PLS from one of the tailings samples co-precipitated with copper sulfide. Experimental data also suggested that it would be possible to extract silver from bioleached solid residues (where it was mostly found) using a simple chemical extractant. The results suggested that bio-processing these waste materials would have economic as well as environmental benefits. (C) 2016 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2017, "Volume": 106, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 71, "End Page": 78, "Article Number": null, "DOI": "10.1016/j.mineng.2016.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.mineng.2016.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399518800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making yttria-stabilized tetragonal zirconia translucent", "Source Title": "DENTAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objective. The aim of this study was to provide a design guideline for developing tetragonal yttria-stabilized zirconia with improved translucency. Methods. The translucency, the in-line transmission in particular, of 3 mol.% yttria-stabilized tetragonal zirconia (3Y-TZP) has been examined using the Rayleigh scattering model. The theory predicts that the in-line transmission of 3Y-TZP can be related to its thickness with grain size and birefringence the governing parameters. To achieve a threshold value of translucency, the critical grain size of 3Y-TZP was predicted for various thicknesses (0.3-2.0 mm). The threshold value was defined by a measured average in-line transmission value of a suite of dental porcelains with a common thickness of 1 mm. Our theoretical predictions were calibrated with one of the very few experimental data available in the literature. Results. For a dense, high-purity zirconia, its in-line transmission increased with decreasing grain size and thickness. To achieve a translucency similar to that of dental porcelains, a nullocyrstalline 3Y-TZP structure was necessitated, due primarily to its large birefringence and high refractive index. Such a grain size dependence became more pronounced as the 3Y-TZP thickness increased. For example, at a thickness of 1.3 mm, the mean grain size of a translucent 3Y-TZP should be 82 nm. At 1.5 mm and 2 mm thicknesses, the mean grain size needed to be 77 nm and 70 nm, respectively. Signcance. A promising future for zirconia restorations, with combined translucency and mechanical properties, can be realized by reducing its grain size. (C) 2014 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2014, "Volume": 30, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1195, "End Page": 1203, "Article Number": null, "DOI": "10.1016/j.dental.2014.08.375", "DOI Link": "http://dx.doi.org/10.1016/j.dental.2014.08.375", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Dentistry, Oral Surgery & Medicine; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000342387700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lima, LD; Quartier, M; Buchmayr, A; Sanjuan-Delmás, D; Laget, H; Corbisier, D; Mertens, J; Dewulf, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lima, Ligia da Silva; Quartier, Mattijs; Buchmayr, Astrid; Sanjuan-Delmas, David; Laget, Hannes; Corbisier, Dominique; Mertens, Jan; Dewulf, Jo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Life cycle assessment of lithium-ion batteries and vanadium redox flow batteries-based renewable energy storage systems", "Source Title": "SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Renewable energy has become an important alternative to fossil energy, as it is associated with lower greenhouse gas emissions. However, the intermittent characteristic of renewables urges for energy storage systems, which play an important role in matching the supply and demand of renewable-based electricity. The life cycle of these storage systems results in environmental burdens, which are investigated in this study, focusing on lithium-ion and vanadium flow batteries for renewable energy (solar and wind) storage for grid applications. The impacts are assessed through a life cycle assessment covering the batteries supply phase, their use and end-of-life, with experimental data from test set-ups. The battery composition is investigated in detail as a factor for the final impacts, by comparing two types of cathodes for the lithium-ion battery and the use of recycled electrolyte for the vanadium flow battery. Results indicate that the vanadium-based storage system results in overall lower impacts when manufactured with 100% fresh raw materials, but the impacts are significantly lowered if 50% recycled electrolyte is used, with up to 45.2% lower acidification and 11.1% lower global warming potential. The new lithium-ion battery cathode chemistry results in overall higher impacts, with 41.7% more particulate matter and 52.2% more acidification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101286, "DOI": "10.1016/j.seta.2021.101286", "DOI Link": "http://dx.doi.org/10.1016/j.seta.2021.101286", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670347300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sipahigil, A; Jahnke, KD; Rogers, LJ; Teraji, T; Isoya, J; Zibrov, AS; Jelezko, F; Lukin, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sipahigil, A.; Jahnke, K. D.; Rogers, L. J.; Teraji, T.; Isoya, J.; Zibrov, A. S.; Jelezko, F.; Lukin, M. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Indistinguishable Photons from Separated Silicon-Vacancy Centers in Diamond", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate that silicon-vacancy (SiV) centers in diamond can be used to efficiently generate coherent optical photons with excellent spectral properties. We show that these features are due to the inversion symmetry associated with SiV centers. The generation of indistinguishable single photons from separated emitters at 5 K is demonstrated in a Hong-Ou-Mandel interference experiment. Prospects for realizing efficient quantum network nodes using SiV centers are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 11", "Publication Year": 2014, "Volume": 113, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113602, "DOI": "10.1103/PhysRevLett.113.113602", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.113602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341914100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gai, XP; Wang, HY; Liu, J; Zhai, LM; Liu, S; Ren, TZ; Liu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gai, Xiapu; Wang, Hongyuan; Liu, Jian; Zhai, Limei; Liu, Shen; Ren, Tianzhi; Liu, Hongbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of Feedstock and Pyrolysis Temperature on Biochar Adsorption of Ammonium and Nitrate", "Source Title": "PLOS ONE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biochar produced by pyrolysis of biomass can be used to counter nitrogen (N) pollution. The present study investigated the effects of feedstock and temperature on characteristics of biochars and their adsorption ability for ammonium N (NH4+-N) and nitrate N (NO3--N). Twelve biochars were produced from wheat-straw (W-BC), corn-straw (C-BC) and peanut-shell (P-BC) at pyrolysis temperatures of 400, 500, 600 and 700 degrees C. Biochar physical and chemical properties were determined and the biochars were used for N sorption experiments. The results showed that biochar yield and contents of N, hydrogen and oxygen decreased as pyrolysis temperature increased from 400 degrees C to 700 degrees C, whereas contents of ash, pH and carbon increased with greater pyrolysis temperature. All biochars could sorb substantial amounts of NH4+-N, and the sorption characteristics were well fitted to the Freundlich isotherm model. The ability of biochars to adsorb NH4+-N followed: C-BC. P-BC. W-BC, and the adsorption amount decreased with higher pyrolysis temperature. The ability of C-BC to sorb NH4+-N was the highest because it had the largest cation exchange capacity (CEC) among all biochars (e.g., C-BC400 with a CEC of 38.3 cmol kg(-1) adsorbed 2.3 mg NH4+-N g(-1) in solutions with 50 mg NH4+ L-1). Compared with NH4+-N, none of NO3 -N was adsorbed to biochars at different NO3 concentrations. Instead, some NO3- -N was even released from the biochar materials. We conclude that biochars can be used under conditions where NH4+-N (or NH3) pollution is a concern, but further research is needed in terms of applying biochars to reduce NO3--N pollution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 423, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2014, "Volume": 9, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e113888", "DOI": "10.1371/journal.pone.0113888", "DOI Link": "http://dx.doi.org/10.1371/journal.pone.0113888", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349128700050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, J; Raoux, A; Qiao, ZH; MacDonald, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Jeil; Raoux, Arnaud; Qiao, Zhenhua; MacDonald, A. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ab initio theory of moire superlattice bands in layered two-dimensional materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When atomically thin two-dimensional (2D) materials are layered, they often form incommensurate noncrystalline structures that exhibit long-period moire patternswhen examined by scanning probes. In this paper, we present an approach that uses information obtained from ab initio calculations performed on short-period crystalline structures to derive effective Hamiltonians that are able to efficiently describe the influence of the moire pattern superlattices on electronic properties. We apply our approach to the cases of graphene on graphene (G/G) and graphene on hexagonal boron nitride (G/BN), deriving explicit effective Hamiltonians that have the periodicity of the moire pattern and can be used to calculate electronic properties of interest for arbitrary twist angles and lattice constants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2014, "Volume": 89, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 205414, "DOI": "10.1103/PhysRevB.89.205414", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.205414", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335915100010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, MJ; He, YR; Zhu, JQ; Wen, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Meijie; He, Yurong; Zhu, Jiaqi; Wen, Dongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigating the collector efficiency of silver nullofluids based direct absorption solar collectors", "Source Title": "APPLIED ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A one-dimensional transient heat transfer analysis was carried out to analyze the effects of the nulloparticle (NP) volume fraction, collector height, irradiation time, solar flux, and NP material on the collector efficiency. The numerical results were compared with the experimental results obtained by silver nullofluids to validate the model, and good agreement was obtained. The numerical results show that the collector efficiency increases as the collector height and NP volume fraction increase and then reaches a maximum value. An optimum collector height (similar to 10 mm) and particle concentration.(similar to 0.03%) achieving a collector efficiency of 90% of the maximum efficiency can be obtained under the conditions used in the simulation. However, the collector efficiency decreases as the irradiation time increases owing to the increased heat loss. A high solar flux is desirable to maintain a high efficiency over a wide temperature range, which is beneficial for subsequent energy utilization. The modeling results also show silver and gold nullofluids obtain higher photothermal conversion efficiencies than the titanium dioxide nullofluid because their absorption spectra are similar to the solar radiation spectrum. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2016, "Volume": 181, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 74, "Article Number": null, "DOI": "10.1016/j.apenergy.2016.08.054", "DOI Link": "http://dx.doi.org/10.1016/j.apenergy.2016.08.054", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386644200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guguchia, Z; Mielke, C; Das, D; Gupta, R; Yin, JX; Liu, H; Yin, Q; Christensen, MH; Tu, Z; Gong, C; Shumiya, N; Hossain, MS; Gamsakhurdashvili, T; Elender, M; Dai, P; Amato, A; Shi, Y; Lei, HC; Fernulldes, RM; Hasan, MZ; Luetkens, H; Khasanov, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guguchia, Z.; Mielke, C.; Das, D.; Gupta, R.; Yin, J. -X.; Liu, H.; Yin, Q.; Christensen, M. H.; Tu, Z.; Gong, C.; Shumiya, N.; Hossain, Md Shafayat; Gamsakhurdashvili, Ts; Elender, M.; Dai, Pengcheng; Amato, A.; Shi, Y.; Lei, H. C.; Fernulldes, R. M.; Hasan, M. Z.; Luetkens, H.; Khasanov, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable unconventional kagome superconductivity in charge ordered RbV3Sb5 and KV3Sb5", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Unconventional superconductors often feature competing orders, small superfluid density, and nodal electronic pairing. While unusual superconductivity has been proposed in the kagome metals AV(3)Sb(5), key spectroscopic evidence has remained elusive. Here we utilize pressure-tuned and ultra-low temperature muon spin spectroscopy to uncover the unconventional nature of superconductivity in RbV3Sb5 and KV3Sb5. At ambient pressure, we observed time-reversal symmetry breaking charge order below T-1*similar or equal to 110 K in RbV3Sb5 with an additional transition at T-2*similar or equal to 50 K. Remarkably, the superconducting state displays a nodal energy gap and a reduced superfluid density, which can be attributed to the competition with the charge order. Upon applying pressure, the charge-order transitions are suppressed, the superfluid density increases, and the superconducting state progressively evolves from nodal to nodeless. Once optimal superconductivity is achieved, we find a superconducting pairing state that is not only fully gapped, but also spontaneously breaks time-reversal symmetry. Our results point to unprecedented tunable nodal kagome superconductivity competing with time-reversal symmetry-breaking charge order and offer unique insights into the nature of the pairing state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 153, "DOI": "10.1038/s41467-022-35718-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35718-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991281000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Oclon, P; Klemes, JJ; Michorczyk, P; Pielichowska, K; Pielichowski, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Sheng; Oclon, Pawel; Klemes, Jiri Jaromir; Michorczyk, Piotr; Pielichowska, Kinga; Pielichowski, Krzysztof", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Renewable energy systems for building heating, cooling and electricity production with thermal energy storage", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper introduces the recent developments in Renewable Energy Systems for building heating, cooling and electricity production with thermal energy storage. Due to the needed Clean Energy Transition in the many countries and regions and the goal of closing Net Zero Energy Buildings, it is crucial to provide efficient Renewable Energy Based heating/cooling systems for buildings. The buildings contribute about 40% of total energy consumption, with significant potential for primary energy savings. The application of various Renewable Energy based systems is discussed including: the presentation of Hybrid Renewable Energy bases systems, methodology for their design and methods for the optimisation of Buildings RES. At present, mostly the systems based on heat pumps and photovoltaics are applied in buildings. However, the sources of those energy systems are unstable, and they are influenced by the climate environment. It makes it necessary to combine thermal and electrical energy storage, to achieve high efficiency. The recently developing electrical energy and chemical storage are Battery Energy Storage Systems and Hydrogen Energy Systems, through it is urgently necessary to overcome the difficulties of high cost, relatively low efficiency and demanding storage environment and so on. For the thermal energy storage, Phase Change Materials (PCMs) show great potential for application - with their use the thermal energy can be accumulated at the time of low energy demand or availability and recovered during a high consumption period. This review also presents the recent developments in PCMs for their application in buildings, both for heating and cooling. Finally, it sorts out some challenging issues of the RES today and guides future development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 165, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112560, "DOI": "10.1016/j.rser.2022.112560", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2022.112560", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810514400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Law, JY; Moreno-Ramírez, LM; Díaz-García, A; Franco, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Law, Jia Yan; Moreno-Ramirez, Luis M.; Diaz-Garcia, Alvaro; Franco, Victorino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Current perspective in magnetocaloric materials research", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetocaloric refrigeration has remained a promising alternative to conventional refrigeration for the last few decades. The delay in reaching the market is significantly based on materials' related issues, such as hysteresis/reversibility, mechanical stability, or formability. This perspective paper shows the current trends in magnetocaloric materials research, highlighting the families of alloys and compounds that are gaining attention in the recent years. It also includes an overview of novel approaches that can be used to analyze these properties that could improve the applicability of magnetocaloric materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2023, "Volume": 133, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 40903, "DOI": "10.1063/5.0130035", "DOI Link": "http://dx.doi.org/10.1063/5.0130035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923070500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Du, J; Liu, Z; Christodoulatos, C; Conway, M; Bao, Y; Meng, WN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Du, Jiang; Liu, Zhuo; Christodoulatos, Christos; Conway, Matthew; Bao, Yi; Meng, Weina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Utilization of off-specification fly ash in preparing ultra-high-performance concrete (UHPC): Mixture design, characterization, and life-cycle assessment", "Source Title": "RESOURCES CONSERVATION AND RECYCLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents feasibility and benefits of utilizing off-specification fly ash (OSFA), which would have otherwise been landfilled, in preparing ultra-high-performance concrete (UHPC). Effects of mixture design variables, including OSFA content, water-to-binder ratio, and slag content, on compressive and flexural properties of UHPC were tested. Experimental results showed that UHPC with proper combination of OSFA and slag achieved desired compressive and flexural strengths, as well as low autogenous shrinkage and leachability of heavy metals. The underlying mechanisms of property development were investigated through isothermal calorimetry, thermogravimetric analysis, and X-ray diffraction. Results indicated that use of OSFA retarded hydration reactions, but incorporation of slag effectively suppressed adverse effects of OSFA. Economic and environmental analysis showed that use of OSFA greatly reduced the life-cycle cost, carbon footprint, and embodied energy consumption of UHPC. This study develops a new avenue for valorization of OSFA and development of cost-effective and eco-friendly UHPC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 180, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106136, "DOI": "10.1016/j.resconrec.2021.106136", "DOI Link": "http://dx.doi.org/10.1016/j.resconrec.2021.106136", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781488300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, X; Sepehri-Amin, H; Terada, N; Martin-Cid, A; Kurniawan, ; Kobayashi, S; Kotani, Y; Takeya, H; Lai, J; Matsushita, Y; Ohkubo, T; Miura, Y; Nakamura, T; Hono, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Xin; Sepehri-Amin, H.; Terada, N.; Martin-Cid, A.; Kurniawan, I; Kobayashi, S.; Kotani, Y.; Takeya, H.; Lai, J.; Matsushita, Y.; Ohkubo, T.; Miura, Y.; Nakamura, T.; Hono, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic refrigeration material operating at a full temperature range required for hydrogen liquefaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Application of magnetic refrigeration (MR) for hydrogen liquefaction is limited by lack of MR materials with a large magnetocaloric effect (MCE). Here the authors show a series of MR materials with a large and reversible MCE operating at a full temperature range required for hydrogen liquefaction. Magnetic refrigeration (MR) is a key technique for hydrogen liquefaction. Although the MR has ideally higher performance than the conventional gas compression technique around the hydrogen liquefaction temperature, the lack of MR materials with high magnetic entropy change in a wide temperature range required for the hydrogen liquefaction is a bottle-neck for practical applications of MR cooling systems. Here, we show a series of materials with a giant magnetocaloric effect (MCE) in magnetic entropy change (- increment S-m > 0.2 J cm(-3)K(-1)) in the Er(Ho)Co-2-based compounds, suitable for operation in the full temperature range required for hydrogen liquefaction (20-77 K). We also demonstrate that the giant MCE becomes reversible, enabling sustainable use of the MR materials, by eliminating the magneto-structural phase transition that leads to deterioration of the MCE. This discovery can lead to the application of Er(Ho)Co-2-based alloys for the hydrogen liquefaction using MR cooling technology for the future green fuel society.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1817, "DOI": "10.1038/s41467-022-29340-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29340-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777008300027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, DF; Zhang, SH; Li, M; Eom, CB; Tsymbal, EY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Ding-Fu; Zhang, Shu-Hui; Li, Ming; Eom, Chang-Beom; Tsymbal, Evgeny Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-neutral currents for spintronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electric currents carrying a net spin polarization are widely used in spintronics, whereas globally spin-neutral currents are expected to play no role in spin-dependent phenomena. Here we show that, in contrast to this common expectation, spin-independent conductance in compensated antiferromagnets and normal metals can be efficiently exploited in spintronics, provided their magnetic space group symmetry supports a non-spin-degenerate Fermi surface. Due to their momentum-dependent spin polarization, such antiferromagnets can be used as active elements in antiferromagnetic tunnel junctions (AFMTJs) and produce a giant tunneling magnetoresistance (TMR) effect. Using RuO2 as a representative compensated antiferromagnet exhibiting spin-independent conductance along the [001] direction but a non-spin-degenerate Fermi surface, we design a RuO2/TiO2/RuO2 (001) AFMTJ, where a globally spin-neutral charge current is controlled by the relative orientation of the Neel vectors of the two RuO2 electrodes, resulting in the TMR effect as large as similar to 500%. These results are expanded to normal metals which can be used as a counter electrode in AFMTJs with a single antiferromagnetic layer or other elements in spintronic devices. Our work uncovers an unexplored potential of the materials with no global spin polarization for utilizing them in spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 3", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7061, "DOI": "10.1038/s41467-021-26915-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26915-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000726143200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saleque, AM; Ma, SA; Thakur, AK; Saidur, R; Han, TK; Hossain, MI; Qarony, W; Ma, Y; Sathyamurthy, R; Tsang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saleque, Ahmed Mortuza; Ma, Sainull; Thakur, Amrit Kumar; Saidur, R.; Han, Tan Kim; Hossain, Mohammad Ismail; Qarony, Wayesh; Ma, Y.; Sathyamurthy, Ravishankar; Tsang, Yuen Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene/MnO2 nullocomposite coated superior salt-rejecting biodegradable luffa sponge for efficient solar steam generation", "Source Title": "DESALINATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar steam generation is widely regarded as one of the potential green approaches for freshwater regeneration by utilizing solar energy. Herein, the MXene/MnO2 nullocomposite-coated biodegradable luffa sponge (Ti3C2- MnO2@LS) is proposed as an efficient solar evaporator for solar steam generation. The thin layer of Ti3C2-MnO2 coated on the surface of the luffa sponge (LS) serves as the solar absorber and enhances the hydrophilicity of the LS, while the thermally insulating LS layer with microporous structure endows sufficient water transportation and localizes heat for interfacial water evaporation. Combining MXene with MnO2 can increase the surface area as well as the stability. The Ti3C2-MnO2@LS delivers a solar evaporation rate as high as 1.36 kg m- 2 h-1, with a solar steam conversion efficiency of 85.28 % under one sun irradiation. Furthermore, this Ti3C2-MnO2@LS ex-hibits superior salt-rejecting properties even under highly concentrated saltwater desalination and excellent wastewater purification performance. This work demonstrates the prospects of combining novel 2D materials with biomass-based materials for practical solar steam generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2023, "Volume": 554, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116488, "DOI": "10.1016/j.desal.2023.116488", "DOI Link": "http://dx.doi.org/10.1016/j.desal.2023.116488", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955781700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Orfano, M; Perego, J; Cova, F; Bezuidenhout, CX; Piva, S; Dujardin, C; Sabot, B; Pierre, S; Mai, PV; Daniel, C; Bracco, S; Vedda, A; Comotti, A; Monguzzi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Orfano, Matteo; Perego, Jacopo; Cova, Francesca; Bezuidenhout, Charl X. X.; Piva, Sergio; Dujardin, Christophe; Sabot, Benoit; Pierre, Sylvie; Mai, Pavlo; Daniel, Christophe; Bracco, Silvia; Vedda, Anna; Comotti, Angiolina; Monguzzi, Angelo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient radioactive gas detection by scintillating porous metal-organic frameworks", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detection of gas radionuclides is limited in sensitivity with present methods, but may be useful in energy, security, medical and other sectors. In this work, gas-concentrating porous scintillating metal-organic frameworks are demonstrated for gas radionuclide detection. Natural and anthropogenic gas radionuclides such as radon, xenon, hydrogen and krypton isotopes must be monitored to be managed as pathogenic agents, radioactive diagnostic agents or nuclear activity indicators. State-of-the-art detectors based on liquid scintillators suffer from laborious preparation and limited solubility for gases, which affect the accuracy of the measurements. The actual challenge is to find solid scintillating materials simultaneously capable of concentrating radioactive gases and efficiently producing visible light revealed with high sensitivity. The high porosity, combined with the use of scintillating building blocks in metal-organic frameworks (MOFs), offers the possibility to satisfy these requisites. We demonstrate the capability of a hafnium-based MOF incorporating dicarboxy-9,10-diphenylanthracene as a scintillating conjugated ligand to detect gas radionuclides. Metal-organic frameworks show fast scintillation, a fluorescence yield of similar to 40%, and accessible porosity suitable for hosting noble gas atoms and ions. Adsorption and detection of Kr-85, Rn-222 and H-3 radionuclides are explored through a newly developed device that is based on a time coincidence technique. Metal-organic framework crystalline powder demonstrated an improved sensitivity, showing a linear response down to a radioactivity value below 1 kBq m(-3) for Kr-85, which outperforms commercial devices. These results support the possible use of scintillating porous MOFs to fabricate sensitive detectors of natural and anthropogenic radionuclides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 17, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 672, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01211-2", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01211-2", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992146600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Wang, H; Muniz, MC; Panagiotopoulos, AZ; Car, R; E, WN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linfeng; Wang, Han; Muniz, Maria Carolina; Panagiotopoulos, Athanassios Z.; Car, Roberto; E, Weinull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A deep potential model with long-range electrostatic interactions", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning models for the potential energy of multi-atomic systems, such as the deep potential (DP) model, make molecular simulations with the accuracy of quantum mechanical density functional theory possible at a cost only moderately higher than that of empirical force fields. However, the majority of these models lack explicit long-range interactions and fail to describe properties that derive from the Coulombic tail of the forces. To overcome this limitation, we extend the DP model by approximating the long-range electrostatic interaction between ions (nuclei + core electrons) and valence electrons with that of distributions of spherical Gaussian charges located at ionic and electronic sites. The latter are rigorously defined in terms of the centers of the maximally localized Wannier distributions, whose dependence on the local atomic environment is modeled accurately by a deep neural network. In the DP long-range (DPLR) model, the electrostatic energy of the Gaussian charge system is added to short-range interactions that are represented as in the standard DP model. The resulting potential energy surface is smooth and possesses analytical forces and virial. Missing effects in the standard DP scheme are recovered, improving on accuracy and predictive power. By including long-range electrostatics, DPLR correctly extrapolates to large systems the potential energy surface learned from quantum mechanical calculations on smaller systems. We illustrate the approach with three examples: the potential energy profile of the water dimer, the free energy of interaction of a water molecule with a liquid water slab, and the phonon dispersion curves of the NaCl crystal. (C) 2022 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2022, "Volume": 156, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124107, "DOI": "10.1063/5.0083669", "DOI Link": "http://dx.doi.org/10.1063/5.0083669", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781453400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, BQ; Engel, EA; Behler, J; Dellago, C; Ceriotti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Bingqing; Engel, Edgar A.; Behler, Joerg; Dellago, Christoph; Ceriotti, Michele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ab initio thermodynamics of liquid and solid water", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermodynamic properties of liquid water as well as hexagonal (Ih) and cubic (Ic) ice are predicted based on density functional theory at the hybrid-functional level, rigorously taking into account quantum nuclear motion, anharmonic fluctuations, and proton disorder. This is made possible by combining advanced free-energy methods and state-of-the-art machine-learning techniques. The ab initio description leads to structural properties in excellent agreement with experiments and reliable estimates of the melting points of light and heavy water. We observe that nuclear-quantum effects contribute a crucial 0.2 meV/H2O to the stability of ice Ih, making it more stable than ice Ic. Our computational approach is general and transferable, providing a comprehensive framework for quantitative predictions of ab initio thermodynamic properties using machine-learning potentials as an intermediate step.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 242, "Times Cited, All Databases": 264, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2019, "Volume": 116, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1110, "End Page": 1115, "Article Number": null, "DOI": "10.1073/pnas.1815117116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1815117116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456336100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Cheng, XC; Wang, BZ; Zhang, JY; Lu, YH; Yi, CR; Niu, S; Deng, YJ; Liu, XJ; Chen, S; Pan, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zong-Yao; Cheng, Xiang-Can; Wang, Bao-Zong; Zhang, Jin-Yi; Lu, Yue-Hui; Yi, Chang-Rui; Niu, Sen; Deng, Youjin; Liu, Xiong-Jun; Chen, Shuai; Pan, Jian-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of an ideal Weyl semimetal band in a quantum gas with 3D spin-orbit coupling", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are three- dimensional (3D) gapless topological phases with Weyl cones in the bulk band. According to lattice theory, Weyl cones must come in pairs, with the minimum number of cones being two. A semimetal with only two Weyl cones is an ideal Weyl semimetal (IWSM). Here we report the experimental realization of an IWSM band by engineering 3D spin-orbit coupling for ultracold atoms. The topological Weyl points are clearly measured via the virtual slicing imaging technique in equilibrium and are further resolved in the quench dynamics. The realization of an IWSM band opens an avenue to investigate various exotic phenomena that are difficult to access in solids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2021, "Volume": 372, "Issue": 6539, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 271, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abc0105", "DOI Link": "http://dx.doi.org/10.1126/science.abc0105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641286700036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Borden, MJ; Hughes, TJR; Landis, CM; Anvari, A; Lee, IJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Borden, Michael J.; Hughes, Thomas J. R.; Landis, Chad M.; Anvari, Amin; Lee, Isaac J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A phase-field formulation for fracture in ductile materials: Finite defonnation balance law derivation, plastic degradation, and stress triaxiality effects", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase-field models have been a topic of much research in recent years. Results have shown that these models are able to produce complex crack patterns in both two and three dimensions. A number of extensions from brittle to ductile materials have been proposed and results are promising. To date, however, these extensions have not accurately represented strains after crack initiation or included important aspects of ductile fracture such as stress triaxiality. This work introduces a number of contributions to further develop phase-field models for fracture in ductile materials. These contributions include: a cubic degradation function that provides a stress strain response prior to crack initiation that more closely approximates linear elastic behavior, a derivation of the governing equations in terms of a general energy potential from balance laws that describe the kinematics of both the body and phase-field, introduction of a yield surface degradation function that provides a mechanism for plastic softening and corrects the non-physical elastic deformations after crack initiation, a proposed mechanism for including a measure of stress triaxiality as a driving force for crack initiation and propagation, and a correction to an error in the configuration update of an elastoplastic return-mapping algorithm for J(2) flow theory. We also present a heuristic time stepping scheme that facilitates computations that require a relatively long load time prior to crack initiation. A number of numerical results will be presented that demonstrate the effects of these contributions. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 495, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2016, "Volume": 312, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 130, "End Page": 166, "Article Number": null, "DOI": "10.1016/j.cma.2016.09.005", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.09.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389784000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bach, TC; Schuster, SF; Fleder, E; Müller, J; Brand, MJ; Lorrmann, H; Jossen, A; Sextl, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bach, Tobias C.; Schuster, Simon F.; Fleder, Elena; Mueller, Jana; Brand, Martin J.; Lorrmann, Henning; Jossen, Andreas; Sextl, Gerhard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonlinear aging of cylindrical lithium-ion cells linked to heterogeneous compression", "Source Title": "JOURNAL OF ENERGY STORAGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Second-life applications of automotive lithium-ion batteries are currently investigated for grid stabilization. Reutilization depends on reliable projections of the remaining useful life. However, reports on sudden degradation of lithium-ion-cells near 80% state of health challenge these extrapolations. Sudden degradation was demonstrated for different positive active materials. This work elucidates the cause of sudden degradation in detail. As part of a larger study on nonlinear degradation, in-depth analyses of cells with different residual capacities are performed. Sudden degradation of capacity is found to be triggered by the appearance of lithium plating confined to small characteristic areas, generated by heterogeneous compression. The resulting lithium loss rapidly alters the balancing of the electrodes, thus generating a self-amplifying circle of active material and lithium loss. Changes in impedance and open-circuit voltage are explained by the expansion of degraded patches. Destructive analysis reveals that sudden degradation is caused by the graphite electrode while the positive electrode is found unchanged except for delithiation caused by side reactions on the negative electrode. Our findings illustrate the importance of homogeneous compression of the electrode assembly and carbon electrode formulation. Finally, a quick test to evaluate the vulnerability of cell designs toward sudden degradation is proposed. (C) 2016 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 233, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 212, "End Page": 223, "Article Number": null, "DOI": "10.1016/j.est.2016.01.003", "DOI Link": "http://dx.doi.org/10.1016/j.est.2016.01.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377035500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bridge, G; Faigen, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bridge, Gavin; Faigen, Erika", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards the lithium-ion battery production network: Thinking beyond mineral supply chains", "Source Title": "ENERGY RESEARCH & SOCIAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The increasing role of electricity as an energy carrier in decarbonising economies is driving a growing demand for electrical energy storage in the form of battery systems. Two battery applications driving demand growth are electric vehicles and stationary forms of energy storage. Consequently, established battery production networks are increasingly intersecting with - and being transformed by - actors and strategies in the transport and power sectors, in ways that are important to understand. Most analyses of battery production adopt a supply chain approach, focussing on the flow and transformation of materials from primary production via manufacturing to final assembly. They pay only limited attention to organisational and geographical relations, and they overlook critical areas of intersection between battery production and OEM manufacturing for automotive and power sectors. As a result, supply chain approaches do not fully account for emergent properties of battery production networks. To remedy this, we deploy a global production network (GPN) approach that highlights the increasing intersection of battery manufacturing with the automotive and power sectors, informed by original research with key respondents in battery R&D and commercialization at the collaborative interfaces of academia, industry and government. Our GPN approach augments conventional supply chain accounts based on battery manufacturing in two ways: it identifies the economic and non-economic actors, network relations and multiple locations that constitute the global battery production network; and focuses on firm strategies of innovation, cooperation and competition through which this network acquires its organisationally and geographically dynamic character, (specifically increasing inter-industry intersections), and the multifaceted role of the state. The paper concludes by reflecting on the implications of this alternative account for understanding key areas of policy concern, and for analyses of the geopolitical economy of energy system transformation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 89, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102659, "DOI": "10.1016/j.erss.2022.102659", "DOI Link": "http://dx.doi.org/10.1016/j.erss.2022.102659", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000817181000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HQ; Liu, JP; Vanderbilt, D; Duan, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Huaqing; Liu, Jianpeng; Vanderbilt, David; Duan, Wenhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological nodal-line semimetals in alkaline-earth stannides, germanides, and silicides", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on first-principles calculations and an effective Hamiltonian analysis, we systematically investigate the electronic and topological properties of alkaline-earth compounds AX(2) (A = Ca, Sr, Ba; X = Si, Ge, Sn). Taking BaSn2 as an example, we find that when spin-orbit coupling is ignored, these materials are three-dimensional topological nodal-line semimetals characterized by a snakelike nodal loop in three-dimensional momentum space. Drumheadlike surface states emerge either inside or outside the loop circle on the (001) surface depending on surface termination, while complicated double-drumhead-like surface states appear on the (010) surface. When spin-orbit coupling is included, the nodal line is gapped and the system becomes a topological insulator with Z(2) topological invariants (1;001). Since spin-orbit coupling effects are weak in light elements, the nodal-line semimetal phase is expected to be achievable in some alkaline-earth germanides and silicides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2016, "Volume": 93, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 201114, "DOI": "10.1103/PhysRevB.93.201114", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.201114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376638700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jahangiri, H; Bennett, J; Mahjoubi, P; Wilson, K; Gu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jahangiri, Hessam; Bennett, James; Mahjoubi, Parvin; Wilson, Karen; Gu, Sai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A review of advanced catalyst development for Fischer-Tropsch synthesis of hydrocarbons from biomass derived syn-gas", "Source Title": "CATALYSIS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fischer-Tropsch synthesis (FTS) is a process which converts syn-gas (H-2 and CO) to synthetic liquid fuels and valuable chemicals. Thermal gasification of biomass represents a convenient route to produce syn-gas from intractable materials particularly those derived from waste that are not cost effective to process for use in biocatalytic or other milder catalytic processes. The development of novel catalysts with high activity and selectivity is desirable as it leads to improved quality and value of FTS products. This review paper summarises recent developments in FT-catalyst design with regards to optimising catalyst activity and selectivity towards synthetic fuels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2210, "End Page": 2229, "Article Number": null, "DOI": "10.1039/c4cy00327f", "DOI Link": "http://dx.doi.org/10.1039/c4cy00327f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339551400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YJ; Yi, YT; Li, WX; Liang, SR; Ma, J; Cheng, SB; Yang, WX; Yi, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuanjian; Yi, Yingting; Li, Wenxin; Liang, Shiri; Ma, Jing; Cheng, Shubo; Yang, Wenxing; Yi, Yougen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Absorptivity and Ultra-Wideband Solar Absorber Based on Ti-Al2O3 Cross Elliptical Disk Arrays", "Source Title": "COATINGS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perfect metamaterial absorbers have attracted researchers' attention in solar energy harvesting and utilization. An ideal solar absorber should provide high absorption, be ultra-wideband, and be insensitive to polarization and incident angles, which brings challenges to research. In this paper, we proposed and optimized an ultra-wideband solar absorber based on Ti-Al2O3 cross elliptical disk arrays to obtain the ultra-wideband absorption of solar energy. The addition of a cavity greatly improves the energy-absorbing effect in the operating band, which has research value. The absorption spectrum and field distribution were analyzed by the finite difference time domain method. For the physical mechanism, the electric and magnetic field distribution indicates that ultra-wideband absorption is caused by propagation surface plasmon resonullce (SPR), localized SPR and Fabry-Perot (F-P) resonullce excited between Ti and Al2O3 disks. The results demonstrate that the absorption bandwidth with the absorption rate beyond 90% reaches 1380 nm (385-1765 nm), and the average absorption reaches an astonishing 98.78%. The absorption bandwidth matches the main radiation bandwidth of the solar energy, which is approximately 295-2500 nm according to the data from the literature, and the total thickness of the structure is only 445 nm. Moreover, the ultra-wideband solar absorber is insensitive to the polarization angle and oblique incidence angle. The proposed ultra-wideband solar absorber has research and application value in solar energy harvesting, photothermal conversion and utilization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 13, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 531, "DOI": "10.3390/coatings13030531", "DOI Link": "http://dx.doi.org/10.3390/coatings13030531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955053100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, BW; Cai, JJ; Zhang, JJ; Tan, HY; Cheng, B; Xu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Bowen; Cai, Jiajie; Zhang, Jianjun; Tan, Haiyan; Cheng, Bei; Xu, Jingsan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneous benzyl alcohol oxidation and H2 generation over MOF/CdS S-scheme photocatalysts and mechanism study", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The conversion from solar energy into storable chemical energy can be achieved through synergistic coupling of photocatalytic H2 production and organic synthesis, during which photogenerated electrons and holes can be simultaneously utilized. Herein, we combined a zirconium-based metal-organic framework, UiO-66-NH2, and CdS nulloparticles (NPs) to form a core-shell structure by a chemical bath method. The step-scheme (S-scheme) heterojunction exhibits both substantially enhanced selective oxidation of benzyl alcohol and efficient H2 generation under light irradiation simultaneously. The electron transfer paths at the S-scheme heterostructure interface were investigated in depth by in situ irradiated X-ray photoelectron spectroscopy. The dynamics of carrier migration at the heterojunction were obtained through femtosecond transient absorption (fs-TA) spectroscopy. Furthermore, the evolution mechanism of benzaldehyde was revealed by in situ diffuse reflectance infrared Fourier transform spectroscopy and electron paramagnetic resonullce. This work illustrates the electron transfer mechanism of S-scheme heterojunction by fs-TA spectroscopy and provides new insights into the design of MOF/inorganic composite photocatalysts. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 215, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64466-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64466-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001136281000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Metz, S; Kästner, J; Sokol, AA; Keal, TW; Sherwood, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Metz, Sebastian; Kaestner, Johannes; Sokol, Alexey A.; Keal, Thomas W.; Sherwood, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ChemShell-a modular software package for QM/MM simulations", "Source Title": "WILEY INTERDISCIPLINARY REVIEWS-COMPUTATIONAL MOLECULAR SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ChemShell is a modular computational chemistry package with a particular focus on hybrid quantum mechanical/molecular mechanical (QM/MM) simulations. A core set of chemical data handling modules and scripted interfaces to a large number of quantum chemistry and molecular modeling packages underpin a flexible QM/MM scheme. ChemShell has been used in the study of small molecules, molecular crystals, biological macromolecules such as enzymes, framework materials including zeolites, ionic solids, and surfaces. We outline the range of QM/MM coupling schemes and supporting functions for system setup, geometry optimization, and transition-state location (including those from the open-source DL-FIND optimization library). We discuss recently implemented features allowing a more efficient treatment of long range electrostatic interactions, X-ray based quantum refinement of crystal structures, free energy methods, and excited-state calculations. ChemShell has been ported to a range of parallel computers and we describe a number of options including parallel execution based on the message-passing capabilities of the interfaced packages and task-farming for applications in which a number of individual QM, MM, or QM/MM calculations can performed simultaneously. We exemplify each of the features by brief reference to published applications. (C) 2013 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 441, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2014, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 110, "Article Number": null, "DOI": "10.1002/wcms.1163", "DOI Link": "http://dx.doi.org/10.1002/wcms.1163", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Mathematical & Computational Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331228500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motelica, L; Ficai, D; Oprea, O; Ficai, A; Trusca, RD; Andronescu, E; Holban, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motelica, Ludmila; Ficai, Denisa; Oprea, Ovidiu; Ficai, Anton; Trusca, Roxana-Doina; Andronescu, Ecaterina; Holban, Alina Maria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable Alginate Films with ZnO nulloparticles and Citronella Essential Oil-A Novel Antimicrobial Structure", "Source Title": "PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The petroleum-based materials could be replaced, at least partially, by biodegradable packaging. Adding antimicrobial activity to the new packaging materials can also help improve the shelf life of food and diminish the spoilage. The objective of this research was to obtain a novel antibacterial packaging, based on alginate as biodegradable polymer. The antibacterial activity was induced to the alginate films by adding various amounts of ZnO nulloparticles loaded with citronella (lemongrass) essential oil (CEO). The obtained films were characterized, and antibacterial activity was tested against two Gram-negative (Escherichia coli and Salmonella Typhi) and two Gram-positive (Bacillus cereus and Staphylococcus aureus) bacterial strains. The results suggest the existence of synergy between antibacterial activities of ZnO and CEO against all tested bacterial strains. The obtained films have a good antibacterial coverage, being efficient against several pathogens, the best results being obtained against Bacillus cereus. In addition, the films presented better UV light barrier properties and lower water vapor permeability (WVP) when compared with a simple alginate film. The preliminary tests indicate that the alginate films with ZnO nulloparticles and CEO can be used to successfully preserve the cheese. Therefore, our research evidences the feasibility of using alginate/ZnO/CEO films as antibacterial packaging for cheese in order to extend its shelf life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1020, "DOI": "10.3390/pharmaceutics13071020", "DOI Link": "http://dx.doi.org/10.3390/pharmaceutics13071020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000676222800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schumacher, C; Bickel, B; Rys, J; Marschner, S; Daraio, C; Gross, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schumacher, Christian; Bickel, Bernd; Rys, Jan; Marschner, Steve; Daraio, Chiara; Gross, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructures to Control Elasticity in 3D Printing", "Source Title": "ACM TRANSACTIONS ON GRAPHICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a method for fabricating deformable objects with spatially varying elasticity using 3D printing. Using a single, relatively stiff printer material, our method designs an assembly of small-scale microstructures that have the effect of a softer material at the object scale, with properties depending on the microstructure used in each part of the object. We build on work in the area of meta-materials, using numerical optimization to design tiled microstructures with desired properties, but with the key difference that our method designs families of related structures that can be interpolated to smoothly vary the material properties over a wide range. To create an object with spatially varying elastic properties, we tile the object's interior with microstructures drawn from these families, generating a different microstructure for each cell using an efficient algorithm to select compatible structures for neighboring cells. We show results computed for both 2D and 3D objects, validating several 2D and 3D printed structures using standard material tests as well as demonstrating various example applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 34, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136, "DOI": "10.1145/2766926", "DOI Link": "http://dx.doi.org/10.1145/2766926", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358786600102", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duty, C; Ajinjeru, C; Kishore, V; Compton, B; Hmeidat, N; Chen, X; Liu, P; Hassen, AA; Lindahl, J; Kunc, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duty, Chad; Ajinjeru, Christine; Kishore, Vidya; Compton, Brett; Hmeidat, Nadim; Chen, Xun; Liu, Peng; Hassen, Ahmed Arabi; Lindahl, John; Kunc, Vlastimil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "What makes a material printable? A viscoelastic model for extrusion-based 3D printing of polymers", "Source Title": "JOURNAL OF MANUFACTURING PROCESSES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article presents a practical model for evaluating polymer feedstock materials as candidates for 3D printing across a variety of extrusion-based platforms. In order for a material to be successfully utilized for 3D printing operations, a series of fundamental conditions must be met. First, pressure-driven extrusion must occur through a given diameter nozzle at a specified flow rate. Second, the extruded material must form and sustain the desired shape. Third, the extruded structure must be able to bridge a specified gap and serve as a mechanically sound foundation for successive deposits. Finally, the deposited structure must be dimensionally stable during the transition to the final state (i.e. fully cured at room temperature). This article presents a framework for extrusionbased printing and a simple viscoelastic model for each of these conditions based on the rheological and thermophysical properties of the candidate material and the processing parameters of the extrusion-based deposition platform. The model is demonstrated to be a useful tool for the evaluation of example test cases including: high temperature thermoplastics (polyphenylsulfone), fiber reinforced thermoplastics (acrylonitrile butadiene styrene), low-viscosity thermosets (epoxy resins), and thermoplastics with a high coefficient of thermal expansion (polypropylene).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 35, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": 537, "Article Number": null, "DOI": "10.1016/j.jmapro.2018.08.008", "DOI Link": "http://dx.doi.org/10.1016/j.jmapro.2018.08.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448225000054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khalifa, AZ; Cizer, Ö; Pontikes, Y; Heath, A; Patureau, P; Bernal, SA; Marsh, ATM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khalifa, Ahmed Z.; Cizer, Ozlem; Pontikes, Yiannis; Heath, Andrew; Patureau, Pascaline; Bernal, Susan A.; Marsh, Alastair T. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in alkali-activation of clay minerals", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To future-proof alkali-activation technology, there is a need to look beyond well-established precursors such as fly ash and blast furnace slag, due to resource competition, geographical distribution and technical limitations. Clay minerals are abundant and diverse aluminosilicate resources available around the world. However, due to the mineralogical complexity amongst the most common 1:1 (kaolinite, halloysite) and 2:1 (montmorillonite, illite) clay minerals, and practical issues such as workability, their use has been more limited. Recent advances have improved understanding both of pre-activation treatments (thermal, mechanical, chemical), and of the factors influencing clay reactivity, phase assemblages and properties of final products. This opens new opportunities for the exploitation of these resources to produce sustainable cements. A one-size-fits-all approach for processing and activating clay minerals is not viable. Instead, activation routes need to be tailored according to the clay mineralogy to achieve the binder properties required for key applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 132, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106050, "DOI": "10.1016/j.cemconres.2020.106050", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2020.106050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537846000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nilsson, K; Johansson, M; Sandström, C; Röhnisch, HE; Hedenqvist, MS; Langton, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nilsson, Klara; Johansson, Mathias; Sandstrom, Corine; Rohnisch, Hanna Eriksson; Hedenqvist, Mikael S.; Langton, Maud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pasting and gelation of faba bean starch-protein mixtures", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Starch and protein are major components in many foods, contributing to nutritional and textural properties. Understanding how the behaviour and interactions of these components contribute to different textures is important. In this study, mixed gel systems were created with different ratios of starch to protein (constant solid content 12%) extracted from faba bean, a promising crop for locally produced plant-based foods in cold climate regions. The mixed starch-protein gels were characterised in terms of pasting, texture and microstructure. Starch-rich mixtures showed higher water binding and water absorption than samples with higher protein content. A tendency for more efficient hydration in starch-rich samples was confirmed by NMR. Iodine affinity appeared to be lower for high-protein samples, particularly at higher temperatures. Mixtures with high starch content also showed higher viscosity during pasting, higher storage modulus throughout gelation, lower tan delta and lower frequency dependence of the final gel. Characterisation by compression tests showed stronger and more elastic gels with increasing starch content. Light microscopy revealed that starch granules were tightly packed, espe-cially at higher starch content, with protein filling the spaces between starch granules. SEM micrographs revealed a network structure with larger pores and thicker strands in samples with higher starch content. Overall, increasing protein content reduced viscosity during pasting and caused softer gels, likely owing to different gelation and hydration properties of starch and protein.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 42, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108494, "DOI": "10.1016/j.foodhyd.2023.108494", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2023.108494", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964784800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Campanale, C; Savino, I; Massarelli, C; Uricchio, VF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Campanale, Claudia; Savino, Ilaria; Massarelli, Carmine; Uricchio, Vito Felice", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fourier Transform Infrared Spectroscopy to Assess the Degree of Alteration of Artificially Aged and Environmentally Weathered Microplastics", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fourier transform infrared (FTIR) is a spectroscopy technique widely used to identify organic materials. It has recently gained popularity in microplastic (MP) pollution research to determine the chemical composition of unknown plastic fragments. However, it could also be used to evaluate the degree of ageing of MPs collected from the environment. In this context, the principal aim of our research has been to qualitatively evaluate the natural weathering of environmental MPs collected in an Italian freshwater body (the Ofanto River) using ATR-FTIR technology. Furthermore, we compared environmental particles to weathered artificial MPs under controlled light and temperature conditions and to unaltered pristine materials to assess the results. FTIR spectra were acquired using a Nicolet Summit FTIR (ThermoFisher Scientific) equipped with an Everest ATR with a diamond Crystal plate and a DTGS KBr detector (wavenumber range 4000-500 cm(-1), 32 scans per spectrum, spectral resolution of 4 cm(-1)). The degree of ageing was assessed using three different indexes known to be related to changes in MPs: Carbonyl Index (CI), Hydroxyl Index (HI), and Carbon-Oxygen Index (COI). The overall results showed that the regions reflecting changes (hydroxyl groups, peaks from 3100 to 3700 cm(-1), alkenes or carbon double bonds, 1600 and 1680 cm(-1), and carbonyl groups, 1690 and 1810 cm(-1)) appeared significantly modified in artificial and natural weathered particles compared to the pristine materials. The indexes calculated for polymers degraded under the artificial photo and thermo ageing conditions displayed a general tendency to increase with the time in contact with irradiation time. Particular enhancements of CI of PS fragment and PE pellet, HI of PE and PS fragments and PE pellet, and COI of PS fragment were observed. Otherwise, the following incubation of the same particles at a constant temperature of 45 degrees C did not further affect the chemical composition of the particles. Moreover, new unique peaks were also observed in the freshwater particles, almost all in the fingerprint region (1500-500 cm(-1)). Differences in CI, HI, and COI were evidenced among the different morphological MP shapes. On the one hand, the CI calculated for the environmental PE pellets showed values ranging from 0.05 to 0.26 with a mean value of 0.17 +/- 0.10. Most samples (57%) presented a CI with values between 0.16 and 0.30. On the other hand, fragments presented slicer modifications in the carbonyl region with CI values lower than pellets (0.05 +/- 0.05). This index helps evaluate the degradation of PE MPs by UV light, increasing with enhancing residence time in the environment. Conversely, fragments showed greater values of HI (5.90 +/- 2.57) and COI (1.04 +/- 0.48) than pellets, as well as lines, which presented the maximum value of HI (11.51). HI is attributed to the bond vibrations of hydroxyl, carboxyl, or phenol groups. In contrast, COI is frequently attributed to the vibrations of C_O bonds found in carbohydrates, alkanes, secondary alcohols, and ketones. In conclusion, our results showed characteristics spectra acquired from environmental particles compared to pristine and artificial aged ones. The interpretation of our main results emphasizes the need to conduct ecotoxicological experimental studies using naturally weathered particles due to the unicity of their properties, which are more helpful for understanding microplastic pollution effects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 911, "DOI": "10.3390/polym15040911", "DOI Link": "http://dx.doi.org/10.3390/polym15040911", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940933200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Spanton, EM; Zibrov, AA; Zhou, HX; Taniguchi, T; Watanabe, K; Zaletel, MP; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Spanton, Eric M.; Zibrov, Alexander A.; Zhou, Haoxin; Taniguchi, Takashi; Watanabe, Kenji; Zaletel, Michael P.; Young, Andrea F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of fractional Chern insulators in a van der Waals heterostructure", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topologically ordered phases are characterized by long-range quantum entanglement and fractional statistics rather than by symmetry breaking. First observed in a fractionally filled continuum Landau level, topological order has since been proposed to arise more generally at fractional fillings of topologically nontrivial Chern bands. Here we report the observation of gapped states at fractional fillings of Harper-Hofstadter bands arising from the interplay of a magnetic field and a superlattice potential in a bilayer graphene-hexagonal boron nitride heterostructure. We observed phases at fractional filling of bands with Chern indices C = -1, +/- 2, and +/- 3. Some of these phases, in C = -1 and C = 2 bands, are characterized by fractional Hall conductance-that is, they are known as fractional Chern insulators and constitute an example of topological order beyond Landau levels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2018, "Volume": 360, "Issue": 6384, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 62, "End Page": 66, "Article Number": "aan8458", "DOI": "10.1126/science.aan8458", "DOI Link": "http://dx.doi.org/10.1126/science.aan8458", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429263100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, YX; Tang, SW; Huang, JS; Tang, C; Wang, L; Liu, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Yuxiang; Tang, Shengwen; Huang, Jiasheng; Tang, Can; Wang, Lei; Liu, Yufei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractal Analysis on Pore Structure and Modeling of Hydration of Magnesium Phosphate Cement Paste", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnesium phosphate cement (MPC) paste is hardened by the acid-base reaction between magnesium oxide and phosphate. This work collects and evaluates the thermodynamic data at 25 degrees C and a pressure of 0.1 MPa and establishes the hydration reaction model of MPC pastes. The influence of the magnesium-phosphorus molar (M/P) ratio and water-to-binder (W/B) ratio on the hydration product is explored by the thermodynamic simulation. Following this, the initial and ultimate states of the hydration state of MPC pastes are visualized, and the porosity of different pastes as well as fractal analysis are presented. The result shows that a small M/P ratio is beneficial for the formation of main hydration products. The boric acid acts as a retarder, has a significant effect on lowering the pH of the paste, and slows down the formation of hydration products. After the porosity comparison, it can be concluded that the decreasing of M/P and W/B ratios helps reduce porosity. In addition, the fractal dimension D-f of MPC pastes is positively proportional to the porosity, and small M/P ratios as well as small W/B ratios are beneficial for reducing the D-f of MKPC pastes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 337, "DOI": "10.3390/fractalfract6060337", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6060337", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000816444700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, T; Runowski, M; Xue, JP; Luo, LH; Rodríguez-Mendoza, UR; Lavín, V; Martín, IR; Rodríguez-Hernández, P; Muñoz, A; Du, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Teng; Runowski, Marcin; Xue, Junpeng; Luo, Laihui; Rodriguez-Mendoza, Ulises R.; Lavin, Victor; Martin, Inocencio R.; Rodriguez-Hernulldez, Placida; Munoz, Alfonso; Du, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant Pressure-Induced Spectral Shift in Cyan-Emitting Eu2+-Activated Sr8Si4O12Cl8 Microspheres for Ultrasensitive Visual Manometry", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To address the unsatisfactory pressure sensitivity of luminescent manometers, Eu2+-activated supersensitive microspheres operating in the visible range are developed. A series of Eu2+-doped Sr8Si4O12Cl8 materials are synthesized as microspheres, and their structural and spectroscopic properties are studied theoretically and experimentally. Excited at 350 nm, the samples emit a bright cyan luminescence at ambient conditions that, upon pressure, changes to green emission and finally to yellow light above 7 GPa. Most importantly, a huge red-shift of the emission band from 497.3 to 568.8 nm is observed as the pressure increases, leading to an ultrahigh-pressure sensitivity of 9.69 nm/GPa, which is the highest sensitivity ever reported. The designed microspheres with polychromatic emissions and high-pressure sensitivity are suitable for visual optical pressure sensing, and the applied strategy provides some important guidelines for the development of new optical manometers, allowing pressure monitoring with unprecedented accuracy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 33, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202214663", "DOI Link": "http://dx.doi.org/10.1002/adfm.202214663", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961715700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kent, N; Reynolds, N; Raftrey, D; Campbell, ITG; Virasawmy, S; Dhuey, S; Chopdekar, RV; Hierro-Rodriguez, A; Sorrentino, A; Pereiro, E; Ferrer, S; Hellman, F; Sutcliffe, P; Fischer, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kent, Noah; Reynolds, Neal; Raftrey, David; Campbell, Ian T. G.; Virasawmy, Selven; Dhuey, Scott; Chopdekar, Rajesh V.; Hierro-Rodriguez, Aurelio; Sorrentino, Andrea; Pereiro, Eva; Ferrer, Salvador; Hellman, Frances; Sutcliffe, Paul; Fischer, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Creation and observation of Hopfions in magnetic multilayer systems", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Among topological solitons, magnetic skyrmions are two-dimensional particle-like objects with a continuous winding of the magnetization, and magnetic Hopfions are three-dimensional objects that can be formed from a closed loop of twisted skyrmion strings. Theoretical models suggest that magnetic Hopfions can be stabilized in frustrated or chiral magnetic systems, and target skymions can be transformed into Hopfions by adapting their perpendicular magnetic anisotropy, but their experimental verification has been elusive so far. Here, we present an experimental study of magnetic Hopfions that are created in Ir/Co/Pt multilayers shaped into nulloscale disks, known to host target skyrmions. To characterize three-dimensional spin textures that distinguish Hopfions from target skyrmions magnetic images are recorded with surface-sensitive X-ray photoemission electron microscopy and bulk-sensitive soft X-ray transmission microscopy using element-specific X-ray magnetic circular dichroism effects as magnetic contrast. These results could stimulate further investigations of Hopfions and their potential application in three-dimensional spintronics devices. In three dimensions, magnetic Skyrmions can form extended strings. By connecting the ends of a Skyrmionic string, a magnetic Hopfion is formed. Here, the authors present experimental evidence for the appearance of Hopfions, a topological soliton defined by a Hopf number, in a magnetic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1562, "DOI": "10.1038/s41467-021-21846-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21846-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627889300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Yu, ZQ; Liu, B; Zhao, F; Tang, SW; Jin, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Yu, Zhiqiang; Liu, Bo; Zhao, Feng; Tang, Shengwen; Jin, Minmin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of Fly Ash Dosage on Shrinkage, Crack Resistance and Fractal Characteristics of Face Slab Concrete", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crack resistance of face slab concretes to various shrinkages is crucial for the structural integrity and the normal operation of concrete-faced rockfill dams (CFRDs). In this work, the effects of fly ash with four dosages (i.e., 10%, 20%, 30% and 40%) on the drying shrinkage, autogenous shrinkage and the cracking resistance of face slab concrete were studied. Besides, the difference in shrinkage behavior due to fly ash addition was revealed from the viewpoint of the pore structure and fractal dimension of the pore surface (D-s). The findings demonstrate that (1) the incorporation of 10-40% fly ash could slightly reduce the drying shrinkage by about 2.2-13.5% before 14 days of hydration, and it could reduce the drying shrinkage at 180 days by about 5.1-23.2%. By contrast, the fly ash addition could markedly reduce the autogenous shrinkage at early, middle and long-term ages. (2) Increasing fly ash dosage from 0 to 40% considerably improves the crack resistance of concrete to plastic shrinkage. Nevertheless, the increase in fly ash dosage increases the drying-induced cracking risk under restrained conditions. (3) The pore structures of face slab concrete at 3 and 28 days become coarser with the increase in fly ash dosage up to 40%. At 180 days, the pore structures become more refined as the fly ash dosage increases to 30%; however, this refinement effect is not as appreciable as the fly ash dosage increases from 30% to 40%. (4) The D-s of face slab concrete is closely related with the concrete pore structures. The D-s of face slab concrete at a. late age increases from 2.902 to 2.946 with increasing of the fly ash dosage. The pore structure and D-s are closely correlated with the shrinkage of face slab concrete. (5) The fly ash dosage around 30% is optimal for face slab concretes in terms of lowering shrinkage and refining the pore structures, without compromising much mechanical property. However, the face slab concretes with a large fly ash dosage should be well cured under restrained and evaporation conditions at an initial hydration age.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 335, "DOI": "10.3390/fractalfract6060335", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6060335", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819611000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Passarelli, JV; Fairfield, DJ; Sather, NA; Hendricks, MP; Sai, H; Stern, CL; Stupp, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Passarelli, James, V; Fairfield, Daniel J.; Sather, Nicholas A.; Hendricks, Mark P.; Sai, Hiroaki; Stern, Charlotte L.; Stupp, Samuel, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Out-of-Plane Conductivity and Photovoltaic Performance in n=1 Layered Perovskites through Organic Cation Design", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered perovskites with the formula (R-NH3)(2) PbI4 have excellent environmental stability but poor photovoltaic function due to the preferential orientation of the semiconducting layer parallel to the substrate and the typically insulating nature of the R-NH3+ cation. Here, we report a series of these n = 1 layered perovskites with the form (aromatic-O-linker-NH3)(2) PbI4 where the aromatic moiety is naphthalene, pyrene, or perylene and the linker is ethyl, propyl, or butyl. These materials achieve enhanced conductivity perpendicular to the inorganic layers due to better energy level matching between the inorganic layers and organic galleries. The enhanced conductivity and visible absorption of these materials led to a champion power conversion efficiency of 1.38%, which is the highest value reported for any n = 1 layered perovskite, and it is an order of magnitude higher efficiency than any other n substrate. These findings demonstrate the importance of leveraging optoelectronic properties and thus the photovoltaic performance of n = 1 layered perovskite oriented with layers parallel to the the electronic character of the organic cation to improve these chemically stable low n layered perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 13", "Publication Year": 2018, "Volume": 140, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7313, "End Page": 7323, "Article Number": null, "DOI": "10.1021/jacs.8b03659", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b03659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435525500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Garnica, M; Otrokov, MM; Aguilar, PC; Klimovskikh, II; Estyunin, D; Aliev, ZS; Amiraslanov, IR; Abdullayev, NA; Zverev, VN; Babanly, MB; Mamedov, NT; Shikin, AM; Arnau, A; de Parga, ALV; Chulkov, E; Miranda, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garnica, M.; Otrokov, M. M.; Casado Aguilar, P.; Klimovskikh, I. I.; Estyunin, D.; Aliev, Z. S.; Amiraslanov, I. R.; Abdullayev, N. A.; Zverev, V. N.; Babanly, M. B.; Mamedov, N. T.; Shikin, A. M.; Arnau, A.; Vazquez de Parga, A. L.; Chulkov, E., V; Miranda, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Native point defects and their implications for the Dirac point gap at MnBi2Te4(0001)", "Source Title": "NPJ QUANTUM MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study the surface crystalline and electronic structures of the antiferromagnetic topological insulator MnBi2Te4 using scanning tunneling microscopy/spectroscopy (STM/S), micro(mu)-laser angle-resolved photoemission spectroscopy (ARPES), and density functional theory calculations. Our STM images reveal native point defects at the surface that we identify as Bi-Te antisites and Mn-Bi substitutions. Bulk X-ray diffraction further evidences the presence of the Mn-Bi intermixing. Overall, our characterizations suggest that the defects concentration is nonuniform within crystals and differs from sample to sample. Consistently, the ARPES and STS experiments reveal that the Dirac point gap of the topological surface state is different for different samples and sample cleavages, respectively. Our calculations show that the antiparallel alignment of the Mn-Bi moments with respect to those of the Mn layer can indeed cause a strong reduction of the Dirac point gap size. The present study provides important insights into a highly debated issue of the MnBi2Te4 Dirac point gap.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7, "DOI": "10.1038/s41535-021-00414-6", "DOI Link": "http://dx.doi.org/10.1038/s41535-021-00414-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742660300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmadi, E; Oshima, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmadi, Elaheh; Oshima, Yuichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Materials issues and devices of α- and β-Ga2O3", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ga2O3 is an ultrawide bandgap semiconductor with a bandgap energy of 4.5-5.3 eV (depending on its crystal structure), which is much greater than those of conventional wide bandgap semiconductors such as SiC and GaN (3.3 eV and 3.4 eV, respectively). Therefore, Ga2O3 is promising for future power device applications, and further high-performance is expected compared to those of SiC or GaN power devices, which are currently in the development stage for commercial use. Ga2O3 crystallizes into various structures. Among them, promising results have already been reported for the most stable beta-Ga2O3, and for alpha-Ga2O3, which has the largest bandgap energy of 5.3 eV. In this article, we overview state-of-the-art technologies of beta-Ga2O3 and alpha-Ga2O3 for future power device applications. We will give a perspective on the advantages and disadvantages of these two phases in the context of comparing the two most promising polymorphs, concerning material properties, bulk crystal growth, epitaxial growth, device fabrication, and resulting device performance. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2019, "Volume": 126, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 160901, "DOI": "10.1063/1.5123213", "DOI Link": "http://dx.doi.org/10.1063/1.5123213", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515172200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhong, Q; Ren, J; Khajavikhan, M; Christodoulides, DN; Özdemir, SK; El-Ganainy, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhong, Q.; Ren, J.; Khajavikhan, M.; Christodoulides, D. N.; Ozdemir, S. K.; El-Ganainy, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensing with Exceptional Surfaces in Order to Combine Sensitivity with Robustness", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exceptional points (EPs) are singularities that arise in non-Hermitian physics. Current research efforts focus only on systems supporting isolated EPs characterized by increased sensitivity to external perturbations, which makes them potential candidates for building next generation optical sensors. On the downside, this feature is also the Achilles heel of these devices: they are very sensitive to fabrication errors and experimental uncertainties. To overcome this problem, we introduce a new design concept for implementing photonic EPs that combine the robustness required for practical use together with their hallmark sensitivity. Particularly, our proposed structure exhibits a hypersurface of Jordan EPs embedded in a larger space, and having the following peculiar features: (1) A large class of undesired perturbations shift the operating point along the exceptional surface (ES), thus, leaving the system at another EP which explains the robustness; (2) Perturbations due to back reflection or backscattering force the operating point out of the ES, leading to enhanced sensitivity. Importantly, our proposed geometry is relatively easy to implement using standard photonics components and the design concept can be extended to other physical platforms such as microwave or acoustics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 16", "Publication Year": 2019, "Volume": 122, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 153902, "DOI": "10.1103/PhysRevLett.122.153902", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.153902", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464756500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kitchaev, DA; Peng, HW; Liu, Y; Sun, JW; Perdew, JP; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kitchaev, Daniil A.; Peng, Haowei; Liu, Yun; Sun, Jianwei; Perdew, John P.; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energetics of MnO2 polymorphs in density functional theory", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the energetics and properties of the beta, alpha, R, gamma, lambda, and delta polymorphs of MnO2 within density functional theory, comparing the performance of the recently introduced SCAN functional with that of conventional exchange-correlation functionals and experiment. We find that SCAN uniquely yields accurate formation energies and properties across all MnO2 polymorphs. We explain the superior performance of SCAN based on its satisfaction of all known constraints appropriate to a semilocal exchange-correlation functional and its accurate representation of all types of orbital overlap.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2016, "Volume": 93, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45132, "DOI": "10.1103/PhysRevB.93.045132", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.045132", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369223400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, YB; Zhou, X; Wang, J; Deng, QH; Li, MA; Du, SY; Han, YH; Lee, J; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Youbing; Zhou, Xiaobing; Wang, Jing; Deng, Qihuang; Li, Mian; Du, Shiyu; Han, Young-Hwan; Lee, Jaehyung; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile preparation of in situ coated Ti3C2Tx/Ni0.5Zn0.5Fe2O4 composites and their electromagnetic performance", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel family of Ti3C2Tx/ferrite composites with high reflection loss was developed using a facile in situ coprecipitation method. The as-synthesized Ti3C2Tx/ferrite composite with a 5 wt% Ti3C2Tx MXenes loading exhibited high reflection loss (- 42.5 dB) at 13.5 GHz. The effective absorption bandwidth of the 5 wt% Ti3C2Tx/Ni0.5Zn0.5Fe2O4 composite reached similar to 3 GHz (12-15 GHz) in the K-band. The incorporation of Ti3C2Tx MXenes improved the electromagnetic impedance of the Ti3C2Tx/Ni0.5Zn0.5Fe2O4 composite resulting from the enhanced electrical conductivity. The potential electromagnetic wave absorption mechanisms were revealed, which may contain magnetic loss, dielectric loss, conductivity loss, multiple reflections, and scattering. The technique is facile, fast, scalable, and favorable for the commercialization of this composite. This study provides a potential way to develop EM wave absorbing materials for a large family of MXenes/ferrite composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24698, "End Page": 24708, "Article Number": null, "DOI": "10.1039/c7ra03402d", "DOI Link": "http://dx.doi.org/10.1039/c7ra03402d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401525700019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deshmukh, AA; Wu, C; Yassin, O; Mishra, A; Chen, LH; Alamri, A; Li, ZZ; Zhou, JR; Mutlu, Z; Sotzing, M; Rajak, P; Shukla, S; Vellek, J; Baferani, MA; Cakmak, M; Vashishta, P; Ramprasad, R; Cao, Y; Sotzing, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deshmukh, Ajinkya A.; Wu, Chao; Yassin, Omer; Mishra, Ankit; Chen, Lihua; Alamri, Abdullah; Li, Zongze; Zhou, Jierui; Mutlu, Zeynep; Sotzing, Michael; Rajak, Pankaj; Shukla, Stuti; Vellek, John; Baferani, Mohamadreza Arab; Cakmak, Mukerrem; Vashishta, Priya; Ramprasad, Rampi; Cao, Yang; Sotzing, Gregory", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible polyolefin dielectric by strategic design of organic modules for harsh condition electrification", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible polymers that can withstand temperature and electric field extremes are critical to advanced electrical and electronic systems. High thermal stability of polymers is generally achieved through the introduction of highly conjugated aromatic structures, that lower the bandgap and thus diminish the electric field endurance. Here, we demonstrate a class of flexible all-organic polyolefins by a strategic modular structure design to eliminate the impact of conjugation on bandgap. The one such designed polymer exhibits superior operational temperature and T-g of 244 degrees C without compromising the bandgap (similar to 5 eV), exhibiting significantly suppressed electrical conductivity when subjected to a high electric field. It reveals the highest ever recorded energy density of 6.5 J cc(-1) at 200 degrees C, a 2x improvement over the best reported flexible dielectric polymers or polymer composites. The uncovered polymer design strategy introduces a platform for high performance dielectric development for extreme thermal and electric field conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1307, "End Page": 1314, "Article Number": null, "DOI": "10.1039/d1ee02630e", "DOI Link": "http://dx.doi.org/10.1039/d1ee02630e", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000755178900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JB; Laan, N; de Bruin, KG; Skantzaris, G; Shahidzadeh, N; Derome, D; Carmeliet, J; Bonn, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, J. B.; Laan, N.; de Bruin, K. G.; Skantzaris, G.; Shahidzadeh, N.; Derome, D.; Carmeliet, J.; Bonn, D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal rescaling of drop impact on smooth and rough surfaces", "Source Title": "JOURNAL OF FLUID MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The maximum spreading of drops impacting on smooth and rough surfaces is measured from low to high impact velocity for liquids with different surface tensions and viscosities. We demonstrate that dynamic wetting plays an important role in the spreading at low velocity, characterized by the dynamic contact angle at maximum spreading In the energy balance, we account for the dynamic wettability by introducing the capillary energy at zero impact velocity, which relates to the spreading ratio at zero impact velocity. Correcting the measured spreading ratio by the spreading ratio at zero velocity, we find a correct scaling behaviour for low and high impact velocity and, by interpolation between the two, we find a universal scaling curve. The influence of the liquid as well as the nature and roughness of the surface are taken into account properly by resealing with the spreading ratio at zero velocity, which, as demonstrated, is equivalent to accounting for the dynamic contact angle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 786, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "R4", "DOI": "10.1017/jfm.2015.620", "DOI Link": "http://dx.doi.org/10.1017/jfm.2015.620", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366298600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Topalov, AA; Cherevko, S; Zeradjanin, AR; Meier, JC; Katsounaros, I; Mayrhofer, KJJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Topalov, Angel A.; Cherevko, Serhiy; Zeradjanin, Aleksandar R.; Meier, Josef C.; Katsounaros, Ioannis; Mayrhofer, Karl J. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards a comprehensive understanding of platinum dissolution in acidic media", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum is one of the most important electrode materials for continuous electrochemical energy conversion due to its high activity and stability. The resistance of this scarce material towards dissolution is however limited under the harsh operational conditions that can occur in fuel cells or other energy conversion devices. In order to improve the understanding of dissolution of platinum, we therefore investigate this issue with an electrochemical flow cell system connected to an inductively coupled plasma mass spectrometer (ICP-MS) capable of online quantification of even small traces of dissolved elements in solution. The electrochemical data combined with the downstream analytics are used to evaluate the influence of various operational parameters on the dissolution processes in acidic electrolytes at room temperature. Platinum dissolution is a transient process, occurring during both positive-and negative-going sweeps over potentials of ca. 1.1 V-RHE and depending strongly on the structure and chemistry of the formed oxide. The amount of anodically dissolved platinum is thereby strongly related to the number of low-coordinated surface sites, whereas cathodic dissolution depends on the amount of oxide formed and the timescale. Thus, a tentative mechanism for Pt dissolution is suggested based on a place exchange of oxygen atoms from surface to sub-surface positions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 631, "End Page": 638, "Article Number": null, "DOI": "10.1039/c3sc52411f", "DOI Link": "http://dx.doi.org/10.1039/c3sc52411f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000328954200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HH; Zhang, HB; Cheng, JY; Liu, TT; Zhang, DQ; Zheng, GP; Zhai, SR; Cao, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Honghan; Zhang, Huibin; Cheng, Junye; Liu, Tingting; Zhang, Deqing; Zheng, Guangping; Zhai, Shangru; Cao, Maosheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building the conformal protection of VB-group VS2 laminated heterostructure based on biomass-derived carbon for excellent broadband electromagnetic waves absorption", "Source Title": "JOURNAL OF MATERIOMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although VB-Group transition metal disulfides (TMDs) VS2 nullomaterials with specific electronic properties and multiphase microstructures have shown fascinating potential in the field of electro-magnetic wave (EMW) absorption, the efficient utilization of VS2 is limited by the technical bottleneck of its narrow effective absorption bandwidth (EAB) which is attributed to environmental instability and a deficient electromagnetic (EM) loss mechanism. In order to fully exploit the maximal utilization values of VS2 nullomaterials for EMW absorption through mitigating the chemical instability and optimizing the EM parameters, biomass-based glucose derived carbon (GDC) like sugar-coating has been decorated on the surface of stacked VS2 nullosheets via a facile hydrothermal method, followed by high-temperature carbonization. As a result, the modulation of doping amount of glucose injection solution (Glucose) could effectively manipulate the encapsulation degree of GDC coating on VS2 nullosheets, further imple-menting the EM response mechanisms of the VS2/GDC hybrids (coupling effect of conductive loss, interfacial polarization, relaxation, dipole polarization, defect engineering and multiple reflections and absorptions) through regulating the conductivity and constructing multi-interface heterostructures, as reflected by the enhanced EMW absorption performance to a great extent. The minimum reflection loss (Rmin) of VS2/GDC hybrids could reach -52.8 dB with a thickness of 2.7 mm at 12.2 GHz. Surprisingly, compared with pristine VS2, the EAB of the VS2/GDC hybrids increased from 2.0 to 5.7 GHz, while their environmental stability was effectively enhanced by virtue of GDC doping. Obviously, this work provides a promising candidate to realize frequency band tunability of EMW absorbers with exceptional perfor-mance and environmental stability.(c) 2023 The Authors. Published by Elsevier B.V. on behalf of The Chinese Ceramic Society. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 492, "End Page": 501, "Article Number": null, "DOI": "10.1016/j.jmat.2022.12.003", "DOI Link": "http://dx.doi.org/10.1016/j.jmat.2022.12.003", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983588200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, W; Zeng, GL; Jin, HT; Jiang, SH; Huang, MJ; Zhang, CM; Chen, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Wei; Zeng, Guilin; Jin, Haotian; Jiang, Shaohua; Huang, Minjie; Zhang, Chunmei; Chen, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-Template Synthesis of V2O3@Carbonized Dictyophora Composites for Advanced Aqueous Zinc-Ion Batteries", "Source Title": "MOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In terms of new-generation energy-storing devices, aqueous zinc-ion batteries (AZIBs) are becoming the prime candidates because of their inexpensive nature, inherent safety, environmental benignity and abundant resources. Nevertheless, due to a restrained selection of cathodes, AZIBs often perform unsatisfactorily under long-life cycling and high-rate conditions. Consequently, we propose a facile evaporation-induced self-assembly technique for preparing V2O3@carbonized dictyophora (V2O3@CD) composites, utilizing economical and easily available biomass dictyophora as carbon sources and NH4VO3 as metal sources. When assembled in AZIBs, the V2O3@CD exhibits a high initial discharge capacity of 281.9 mAh g(-1) at 50 mA g(-1). The discharge capacity is still up to 151.9 mAh g(-1) after 1000 cycles at 1 A g(-1), showing excellent long-cycle durability. The extraordinary high electrochemical effectiveness of V2O3@CD could be mainly attributed to the formation of porous carbonized dictyophora frame. The formed porous carbon skeleton can ensure efficient electron transport and prevent V2O3 from losing electrical contact due to volume changes caused by Zn2+ intercalation/deintercalation. The strategy of metal-oxide-filled carbonized biomass material may provide insights into developing high-performance AZIBs and other potential energy storage devices, with a wide application range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 28, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2147, "DOI": "10.3390/molecules28052147", "DOI Link": "http://dx.doi.org/10.3390/molecules28052147", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948142900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vabishchevich, PP; Liu, S; Sinclair, MB; Keeler, GA; Peake, GM; Brener, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vabishchevich, Polina P.; Liu, Sheng; Sinclair, Michael B.; Keeler, Gordon A.; Peake, Gregory M.; Brener, Igal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Second-Harmonic Generation Using Broken Symmetry III-V Semiconductor Fano Metasurfaces", "Source Title": "ACS PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-dielectric metasurfaces, two-dimensional arrays of subwavelength low loss dielectric inclusions, can be used not only to control the amplitude and phase of optical beams, but also to generate new wavelengths through enhanced nonlinear optical processes that are free from some of the constraints dictated by the use of bulk materials. Recently, high quality factor (Q) resonullces in these metasurfaces have been revealed and utilized for applications such as sensing and lasing. The origin of these resonullces stems from the interference of two nulloresonator modes with vastly different Q Here we show that nonlinear optical processes can be further enhanced by utilizing these high-Q resonullces in broken symmetry all-dielectric metasurfaces. We study second harmonic generation from broken symmetry metasurfaces made from III-V semiconductors and observe nontrivial spectral shaping of second-harmonic and multifold efficiency enhancement induced by high field localization and enhancement inside the nulloresonators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1685, "End Page": 1690, "Article Number": null, "DOI": "10.1021/acsphotonics.7b01478", "DOI Link": "http://dx.doi.org/10.1021/acsphotonics.7b01478", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432751800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Griffith, LD; Mudryk, Y; Slaughter, J; Pecharsky, VK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Griffith, L. D.; Mudryk, Y.; Slaughter, J.; Pecharsky, V. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Material-based figure of merit for caloric materials", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficient use of reversible thermal effects in magnetocaloric, electrocaloric, and elastocaloric materials is a promising avenue that can lead to a substantially increased efficiency of refrigeration and heat pumping devices, most importantly, those used in household and commercial cooling applications near ambient temperature. A proliferation in caloric material research has resulted in a wide array of materials where only the isothermal change in entropy in response to a handful of different field strengths over a limited range of temperatures has been evaluated and reported. Given the abundance of such data, there is a clear need for a simple and reliable figure of merit enabling fast screening and down-selection to justify further detailed characterization of those material systems that hold the greatest promise. Based on the analysis of several well-known materials that exhibit vastly different magnetocaloric effects, the Temperature averaged Entropy Change is introduced as a suitable early indicator of the material's utility for magnetocaloric cooling applications, and its adoption by the caloric community is recommended. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 321, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2018, "Volume": 123, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34902, "DOI": "10.1063/1.5004173", "DOI Link": "http://dx.doi.org/10.1063/1.5004173", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423028400028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wakatsuki, R; Saito, Y; Hoshino, S; Itahashi, YM; Ideue, T; Ezawa, M; Iwasa, Y; Nagaosa, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wakatsuki, Ryohei; Saito, Yu; Hoshino, Shintaro; Itahashi, Yuki M.; Ideue, Toshiya; Ezawa, Motohiko; Iwasa, Yoshihiro; Nagaosa, Naoto", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonreciprocal charge transport in noncentrosymmetric superconductors", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lack of spatial inversion symmetry in crystals offers a rich variety of physical phenomena, such as ferroelectricity and nonlinear optical effects (for example, second harmonic generation). One such phenomenon is magnetochiral anisotropy, where the electrical resistance depends on the current direction under the external magnetic field. We demonstrate both experimentally and theoretically that this magnetochiral anisotropy is markedly enhanced by orders of magnitude once the materials enter into a superconducting state. To exemplify this enhancement, we study the magnetotransport properties of the two-dimensional noncentrosymmetric superconducting state induced by gating of MoS2. These results indicate that electrons feel the noncentrosymmetric crystal potential much coherently and sensitively over the correlation length when they form Cooper pairs, and show open a new route to enhance the nonreciprocal response toward novel functionalities, including superconducting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602390", "DOI": "10.1126/sciadv.1602390", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, J; Quattrocchi, E; Ciucci, F; Chen, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Juan; Quattrocchi, Emanuele; Ciucci, Francesco; Chen, Yuhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charging processes in lithium-oxygen batteries unraveled through the lens of the distribution of relaxation times", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large overpotential is one of the biggest challenges of Li-O2 batteries, and it is contributed by multiple factors, i.e., surface passivation, sluggish kinetics, poor mass transport, etc. For a better catalyst design, we need to identify the major origin of the overpotential during charging. Herein, we applied the advanced EIS method and decoupled those factors. The slow kinetics of Li2O2 oxidation leads to large overpotential at the initial/final stage of charging, whereas the overpotential", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2023, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2023.04.022", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2023.04.022", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001147814000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maczewsky, LJ; Zeuner, JM; Nolte, S; Szameit, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maczewsky, Lukas J.; Zeuner, Julia M.; Nolte, Stefan; Szameit, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of photonic anomalous Floquet topological insulators", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological insulators are a new class of materials that exhibit robust and scatter-free transport along their edges - independently of the fine details of the system and of the edge - due to topological protection. To classify the topological character of two-dimensional systems without additional symmetries, one commonly uses Chern numbers, as their sum computed from all bands below a specific bandgap is equal to the net number of chiral edge modes traversing this gap. However, this is strictly valid only in settings with static Hamiltonians. The Chern numbers do not give a full characterization of the topological properties of periodically driven systems. In our work, we implement a system where chiral edge modes exist although the Chern numbers of all bands are zero. We employ periodically driven photonic waveguide lattices and demonstrate topologically protected scatter-free edge transport in such anomalous Floquet topological insulators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 414, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13756, "DOI": "10.1038/ncomms13756", "DOI Link": "http://dx.doi.org/10.1038/ncomms13756", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391095000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TT; Yvonnet, J; Zhu, QZ; Bornert, M; Chateau, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, T. T.; Yvonnet, J.; Zhu, Q. -Z.; Bornert, M.; Chateau, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A phase-field method for computational modeling of interfacial damage interacting with crack propagation in realistic microstructures obtained by microtomography", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a formulation is developed within the phase field method for modeling interactions between interfacial damage and bulk brittle cracking in complex microstructures. The method is dedicated to voxel-based models of highly complex microstructures, as obtained from X-ray microtomography images. A smoothed displacement jump approximation is introduced by means of level-set functions to overcome the issue of pixelized interfaces in voxel-based models. A simple technique is proposed to construct the level-set function in that case. Compared to recent work aiming at modeling cohesive cracks within the phase field method, our framework differs in several points: the formulation is such that interfaces are not initially damaged; no additional variables are required to describe the discontinuities at the interface and fatigue cracks can be modeled. The technique allows interaction between bulk and interface cracks, e.g. nucleation from interfaces and propagation within the matrix, and for arbitrary geometries and interactions between cracks. Several benchmarks are presented to validate the model. The technique is illustrated through numerical examples involving complex microcracking in X-ray CT image-based models of concrete microstructures. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 256, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2016, "Volume": 312, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 567, "End Page": 595, "Article Number": null, "DOI": "10.1016/j.cma.2015.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2015.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389784000025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vahabi, H; Kandola, BK; Saeb, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vahabi, Henri; Kandola, Baljinder K.; Saeb, Mohammad Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flame Retardancy Index for Thermoplastic Composites", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flame Retardancy Index, FRI, was defined as a simple yet universal dimensionless criterion born out of cone calorimetry data on thermoplastic composites and then put into practice for quantifying the flame retardancy performance of different polymer composites on a set of reliable data. Four types of thermoplastic composites filled with a wide variety of flame retardant additives were chosen for making comparative evaluations regardless of the type and loading level of the additive as well as the irradiance flux. The main features of cone calorimetry including peak of Heat Release Rate (pHRR), Total Heat Release (THR), and Time-To-Ignition (TTI) served to calculate a dimensionless measure that reflects an improvement in the flame retardancy of nominated thermoplastic composites with respect to the neat thermoplastic, quantitatively. A meaningful trend was observed among well-classified ranges of FRI quantities calculated for the studied dataset on thermoplastic composites by which Poor, Good, and Excellent flame retardancy performances were explicitly defined and exhibited on logarithmic scales of FRI axis. The proposed index remains adaptable to thermoplastic systems whatever the polymer or additive is.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 240, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2019, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 407, "DOI": "10.3390/polym11030407", "DOI Link": "http://dx.doi.org/10.3390/polym11030407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464512400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, HY; Bonati, L; Piaggi, PM; Parrinello, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Haiyang; Bonati, Luigi; Piaggi, Pablo M.; Parrinello, Michele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ab initio phase diagram and nucleation of gallium", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elemental gallium possesses several intriguing properties, such as a low melting point, a density anomaly and an electronic structure in which covalent and metallic features coexist. In order to simulate this complex system, we construct an ab initio quality interaction potential by training a neural network on a set of density functional theory calculations performed on configurations generated in multithermal-multibaric simulations. Here we show that the relative equilibrium between liquid gallium, alpha-Ga, beta-Ga, and Ga-II is well described. The resulting phase diagram is in agreement with the experimental findings. The local structure of liquid gallium and its nucleation into alpha-Ga and beta-Ga are studied. We find that the formation of metastable beta-Ga is kinetically favored over the thermodinamically stable alpha-Ga. Finally, we provide insight into the experimental observations of extreme undercooling of liquid Ga.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 27", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2654, "DOI": "10.1038/s41467-020-16372-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16372-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000538030400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hankin, A; Bedoya-Lora, FE; Alexander, JC; Regoutz, A; Kelsall, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hankin, Anna; Bedoya-Lora, Franky E.; Alexander, John C.; Regoutz, Anna; Kelsall, Geoff H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flat band potential determination: avoiding the pitfalls", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The flat band potential is one of the key characteristics of photoelectrode performance. However, its determination on nullostructured materials is associated with considerable uncertainty. The complexity, applicability and pitfalls associated with the four most common experimental techniques used for evaluating flat band potentials, are illustrated using nullostructured synthetic hematite (alpha-Fe2O3) in strongly alkaline solutions as a case study. The motivation for this study was the large variance in flat band potential values reported for synthetic hematite electrodes that could not be justified by differences in experimental conditions, or by differences in their charge carrier densities. We demonstrate through theory and experiments that different flat band potential determination methods can yield widely different results, so could mislead the analysis of the photoelectrode performance. We have examined: (a) application of the Mott-Schottky (MS) equation to the interfacial capacitance, determined by electrochemical impedance spectroscopy as a function of electrode potential and potential perturbation frequency; (b) Gartner-Butler (GB) analysis of the square of the photocurrent as a function of electrode potential; (c) determination of the potential of transition between cathodic and anodic photocurrents during slow potentiodynamic scans under chopped illumination (CI); (d) open circuit electrode potential (OCP) under high irradiance. Methods GB, CI and OCP were explored in absence and presence of H2O2 as hole scavenger. The CI method was found to give reproducible and the most accurate results on hematite but our overall conclusion and recommendation is that multiple methods should be employed for verifying a reported flat band potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 353, "Times Cited, All Databases": 368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2019, "Volume": 7, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 26162, "End Page": 26176, "Article Number": null, "DOI": "10.1039/c9ta09569a", "DOI Link": "http://dx.doi.org/10.1039/c9ta09569a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509471800045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Law, KT; Lee, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Law, K. T.; Lee, Patrick A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "1T-TaS2 as a quantum spin liquid", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "1T-TaS2 is unique among transition metal dichalcogenides in that it is understood to be a correlation-driven insulator, where the unpaired electron in a 13-site cluster experiences enough correlation to form a Mott insulator. We argue, based on existing data, that this well-known material should be considered as a quantum spin liquid, either a fully gapped Z2 spin liquid or a Dirac spin liquid. We discuss the exotic states that emerge upon doping and propose further experimental probes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 249, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2017, "Volume": 114, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6996, "End Page": 7000, "Article Number": null, "DOI": "10.1073/pnas.1706769114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1706769114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404576100052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Toher, C; Plata, JJ; Levy, O; de Jong, M; Asta, M; Nardelli, MB; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Toher, Cormac; Plata, Jose J.; Levy, Ohad; de Jong, Maarten; Asta, Mark; Nardelli, Marco Buongiorno; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput computational screening of thermal conductivity, Debye temperature, and Gruneisen parameter using a quasiharmonic Debye model", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quasiharmonic Debye approximation has been implemented within the AFLOW and Materials Project frameworks for high-throughput computational materials science (Automatic Gibbs Library, AGL), in order to calculate thermal properties such as the Debye temperature and the thermal conductivity of materials. We demonstrate that the AGL method, which is significantly cheaper computationally compared to the fully ab initio approach, can reliably predict the ordinal ranking of the thermal conductivity for several different classes of semiconductor materials. In particular, a high Pearson (i.e., linear) correlation is obtained between the experimental and AGL computed values of the lattice thermal conductivity for a set of 75 compounds including materials with cubic, hexagonal, rhombohedral, and tetragonal symmetry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2014, "Volume": 90, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 174107, "DOI": "10.1103/PhysRevB.90.174107", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.174107", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348773000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Daido, A; Ikeda, Y; Yanase, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Daido, Akito; Ikeda, Yuhei; Yanase, Youichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Superconducting Diode Effect", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stimulated by the recent experiment [F. Ando et al., Nature (London) 584, 373 (2020).], we propose an intrinsic mechanism to cause the superconducting diode effect (SDE). SDE refers to the nonreciprocity of the critical current for the metal-superconductor transition. Among various mechanisms for the critical current, the depairing current is known to be intrinsic to each material and has recently been observed in several superconducting systems. We clarify the temperature scaling of the nonreciprocal depairing current near the critical temperature and point out its significant enhancement at low temperatures. It is also found that the nonreciprocal critical current shows sign reversals upon increasing the magnetic field. These behaviors are understood by the nonreciprocity of the Landau critical momentum and the change in the nature of the helical superconductivity. The intrinsic SDE unveils the rich phase diagram and functionalities of noncentrosymmetric superconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2022, "Volume": 128, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37001, "DOI": "10.1103/PhysRevLett.128.037001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.128.037001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766017200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rana, AK; Scarpa, F; Thakur, VK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rana, Ashvinder K.; Scarpa, Fabrizio; Thakur, Vijay Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cellulose/polyaniline hybrid nullocomposites: Design, fabrication, and emerging multidimensional applications", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyaniline, a special class of intrinsic conducting polymers, has a wide range of potential applications in multiple fields, such as in biosensors, electronics devices and biomedical applications. Polyaniline possesses high electrical conductivity, low toxic contents, hydrophilic character, better environmental stability and nullostructured surface characteristics. Polyaniline has however a current limited set of applications because of its low degradation rate and poor processibility; for this reason, polyaniline has been blended with different nullo/micro cellulosic biomaterials (i.e. cellulose nullo crystals and nullo fibers, bacterial cellulose and macro cellulose). Furthermore, cellulose-reinforced polyaniline matrices have shown significant potential for antibacterial agents, antioxidants, sensors, electromagnetic shielding device, adsorbent in water treatment, fuel cells, electrochromic and in biomedical applications. These biodegradable and environmentally benign conducting polymers have also been used in tissue engineering, biosensors, and drug delivery. In the present review article we have surveyed recent advancements in the synthesis process and progress of polyaniline/cellulose based bio-composites for water treatment, electrical devices, biosensors, biomedical application and other areas. The article aims at providing a comprehensive background on the topic, as well as at proposing innovative strategies among investigators for the use of these biobased polymers in future work. The various factors and conditions that impact the adsorption/deterioration behavior of cellulose/PANI composites during the removal of heavy metals, dyes, and other effluents from waste water have also been discussed. Additionally, a comparative view of various fuel cells, electrochromic devices and the electrical and magnetic properties of different cellulose/polyaniline composites has also been provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2022, "Volume": 187, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115356, "DOI": "10.1016/j.indcrop.2022.115356", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2022.115356", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000877791500053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Provin, AP; Dutra, ARD; Gouveia, ICADES; Cubas, ALV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Provin, Ana Paula; de Aguiar Dutra, Ana Regina; Aguiar de Sousa e Silva Gouveia, Isabel Cristina; Vieira Cubas, Anelise Leal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Circular economy for fashion industry: Use of waste from the food industry for the production of biotextiles", "Source Title": "TECHNOLOGICAL FORECASTING AND SOCIAL CHANGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the context of current environmental, social and economic issues, it is imperative to perform more in-depth studies on waste management and the life cycle of a product. Thus, the concept of circular economy, aimed at transforming traditional patterns of production and economic growth, is extremely important. One way to mitigate negative environmental impacts that is consistent with a circular economic system is to encourage interdisciplinarity between sectors, that is, one production sector can provide a function for waste from another. In this context, this article gathers scientific information on two sectors relevant to the global economy (textiles and food), with the aim of reusing waste from the food industry to manufacture a new textile product with added value. Specifically, the focus is on the use of bacterial cellulose from the probiotic drinks from kombucha, for the manufacture of biotextiles for fashion industry. A discussion is also presented, relating the circular economy concept to the UN Sustainable Development Goals, in order to understand which goals can be achieved with this approach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 169, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120858, "DOI": "10.1016/j.techfore.2021.120858", "DOI Link": "http://dx.doi.org/10.1016/j.techfore.2021.120858", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Business & Economics; Public Administration", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670357900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, F; Pan, SY; Xie, YH; Li, C; Yu, YJ; Bao, HF; Yang, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Fang; Pan, Shuyuan; Xie, Yuhua; Li, Chen; Yu, Yingjie; Bao, Haifeng; Yang, Zehui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrazine-Assisted Acidic Water Splitting Driven by Iridium Single Atoms", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water splitting, an efficient technology to produce purified hydrogen, normally requires high cell voltage (>1.5 V), which restricts the application of single atoms electrocatalyst in water oxidation due to the inferior stability, especially in acidic environment. Substitution of anodic oxygen evolution reaction (OER) with hydrazine oxidation reaction (HzOR) effectually reduces the overall voltage. In this work, the utilization of iridium single atom (Ir-SA/NC) as robust hydrogen evolution reaction (HER) and HzOR electrocatalyst in 0.5 m H2SO4 electrolyte is reported. Mass activity of Ir-SA/NC is as high as 37.02 A mg(Ir)(-1) at overpotential of 50 mV in HER catalysis, boosted by 127-time than Pt/C. Besides, Ir-SA/NC requires only 0.39 V versus RHE to attain 10 mA cm(-2) in HzOR catalysis, dramatically lower than OER (1.5 V versus RHE); importantly, a superior stability is achieved in HzOR. Moreover, the mass activity at 0.5 V versus RHE is enhanced by 83-fold than Pt/C. The in situ Raman spectroscopy investigation suggests the HzOR pathway follows *N2H4 ->*2NH(2)->*2NH -> 2N ->*N-2 -> N-2 for Ir-SA/NC. The hydrazine assisted water splitting demands only 0.39 V to drive, 1.25 V lower than acidic water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202305058", "DOI Link": "http://dx.doi.org/10.1002/advs.202305058", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001075105500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bucalossi, J; Achard, J; Agullo, O; Alarcon, T; Allegretti, L; Ancher, H; Antar, G; Antusch, S; Anzallo, ; Arnas, C; Arranger, D; Artaud, JF; Aumeunier, MH; Baek, SG; Bai, X; Balbin, J; Balorin, C; Barbui, T; Barbuti, A; Barlerin, J; Basiuk, ; Batal, T; Baulaigue, O; Bec, A; Bécoulet, M; Benoit, E; Benard, E; Benard, JM; Bertelli, N; Bertrand, E; Beyer, P; Bielecki, J; Bienvenu, P; Bisson, R; Bobkov, ; Bodner, G; Bottereau, C; Bouchand, C; Bouquey, F; Bourdelle, C; Bourg, J; Brezinsek, S; Brochard, F; Brun, C; Bruno, ; Bufferand, H; Bureau, A; Burles, S; Camenen, Y; Cantone, B; Caprin, E; Carpentier, S; Caulier, G; Chanet, N; Chellai, O; Chen, Y; Chernyshova, M; Chmielewski, P; Choe, W; Chomiczewska, A; Ciraolo, G; Clairet, F; Coenen, J; Colas, L; Colledani, G; Colnel, J; Coquillat, P; Corbel, E; Corre, Y; Costea, S; Courtois, X; Czarski, T; Daniel, R; Daumas, J; De Combarieu, M; De Temmerman, G; De Vries, P; Dechelle, C; Deguara, F; Dejarnac, R; Delaplanche, JM; Delgado-Aparicio, LF; Delmas, E; Delpech, L; Desgranges, C; Devynck, P; Di Genova, S; Diab, R; Diallo, A; Diez, M; Dif-Pradalier, G; Dimitrova, M; Ding, B; Dittmar, T; Doceul, L; Domenes, M; Douai, D; Dougnac, H; Duan, X; Dubus, L; Dumas, N; Dumont, R; Durand, F; Durif, A; Durocher, A; Durodié, F; Ekedahl, A; Elbeze, D; Ertmer, S; Escarguel, A; Escourbiac, F; Ezato, K; Faisse, F; Faure, N; Fedorczak, N; Fejoz, P; Fenzi-Bonizec, C; Ferlay, F; Firdaouss, M; Fleury, L; Flouquet, D; Gallo, A; Gao, Y; Garbet, X; Garcia, J; Gardarein, JL; Gargiulo, L; Garibaldi, P; Garitta, S; Gaspar, J; Gauthier, E; Gavila, P; Gazzotti, S; Gely, F; Geynet, M; Gharafi, S; Ghendrih, P; Giacalone, ; Gil, C; Ginoux, S; Girard, S; Giroux, E; Giruzzi, G; Goletto, C; Goniche, M; Gray, T; Grelier, E; Greuner, H; Grigore, E; Grisolia, C; Grosjean, A; Grosman, A; Guibert, D; Guilhem, D; Guillemaut, C; Guillermin, B; Guirlet, R; Gunn, JP; Gunsu, Y; Gyergyek, T; Hakola, A; Harris, J; Hatchressian, JC; Helou, W; Hennequin, P; Hernulldez, C; Hill, K; Hillairet, J; Hirai, T; Hoang, GT; Houry, M; Hutter, T; Imbeaux, F; Imbert, N; Ivanova-Stanik, I; Jalageas, R; Jardin, A; Jaubert, L; Jiolat, G; Jonas, A; Joubert, P; Kirschner, A; Klepper, C; Komm, M; Koubiti, M; Kovacic, J; Kozeiha, M; Krieger, K; Krol, K; Lacroix, B; Laguardia, L; Lamaison, ; Laqua, H; Lau, C; Lausenaz, Y; Lé, R; Le Bohec, M; Lefevre, N; Lemoine, N; Lerche, E; Lewerentz, M; Li, Y; Li, M; Liang, A; Linczuk, P; Linsmeier, C; Lipa, M; Litaudon, X; Liu, X; Llorens, J; Loarer, T; Loarte, A; Loewenhoff, T; Lombard, G; Lore, J; Lorenzetto, P; Lotte, P; Lozano, M; Lu, B; Lunsford, R; Luo, G; Magaud, P; Maget, P; Mahieu, JF; Maini, P; Malard, P; Malinowski, K; Manas, P; Manenc, L; Marandet, Y; Marechal, JL; Marek, S; Martin, C; Martin, E; Martinez, A; Martino, P; Mazon, D; Messina, P; Meunier, L; Midou, D; Mineo, Y; Missilian, M; Mitteau, R; Mitu, B; Mollard, P; Moncada, ; Mondiere, T; Morales, J; Moreau, M; Moreau, P; Moudden, Y; Moureau, G; Mouyon, D; Muraglia, M; Nagy, A; Nakano, T; Nardon, E; Neff, A; Nespoli, F; Nichols, J; Nicollet, S; Nouailletas, R; Ono, M; Ostuni, ; Parish, C; Park, H; Parrat, H; Pascal, JY; Pégourié, B; Pellissier, FP; Peneliau, Y; Peret, M; Peysson, Y; Pignoly, E; Pintsuk, G; Pitts, R; Pocheau, C; Portafaix, C; Poulos, M; Prochet, P; Sitjes, AP; Rasinski, M; Raup, G; Regal-Mezin, X; Reux, C; Riccardi, B; Rice, J; Richou, M; Rigollet, F; Roche, H; Romazanov, J; Ruset, C; Sabot, R; Saille, A; Sakamoto, R; Salmon, T; Samaille, F; Santagiustina, A; Santraine, B; Sarazin, Y; Serre, E; Shin, H; Shiraiwai, S; Signoret, J; Signoret, J; Simonin, A; Fettachi, OS; Song, Y; Spring, A; Spuig, P; Sridhar, S; Stratton, B; Talatizi, C; Tamain, P; Tatali, R; Téna, M; Torre, A; Toulouse, L; Travère, JM; Treutterer, W; Tsitrone, E; Unterberg, E; Urbanczyk, G; Van Eester, D; Van Rooij, G; Vartanian, S; Verger, JM; Vermare, L; Vézinet, D; Vignal, N; Vincent, B; Vives, S; Volpe, D; Wallace, G; Wang, E; Wang, L; Wang, Y; Wang, Y; Wauters, T; Wirth, B; Wirtz, M; Wojenski, A; Wright, J; Xu, M; Yang, Q; Yang, H; Zago, B; Zagorski; Zhang, B; Zhang, X; Zou, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bucalossi, J.; Achard, J.; Agullo, O.; Alarcon, T.; Allegretti, L.; Ancher, H.; Antar, G.; Antusch, S.; Anzallo, V; Arnas, C.; Arranger, D.; Artaud, J. F.; Aumeunier, M. H.; Baek, S. G.; Bai, X.; Balbin, J.; Balorin, C.; Barbui, T.; Barbuti, A.; Barlerin, J.; Basiuk, V; Batal, T.; Baulaigue, O.; Bec, A.; Becoulet, M.; Benoit, E.; Benard, E.; Benard, J. M.; Bertelli, N.; Bertrand, E.; Beyer, P.; Bielecki, J.; Bienvenu, P.; Bisson, R.; Bobkov, V; Bodner, G.; Bottereau, C.; Bouchand, C.; Bouquey, F.; Bourdelle, C.; Bourg, J.; Brezinsek, S.; Brochard, F.; Brun, C.; Bruno, V; Bufferand, H.; Bureau, A.; Burles, S.; Camenen, Y.; Cantone, B.; Caprin, E.; Carpentier, S.; Caulier, G.; Chanet, N.; Chellai, O.; Chen, Y.; Chernyshova, M.; Chmielewski, P.; Choe, W.; Chomiczewska, A.; Ciraolo, G.; Clairet, F.; Coenen, J.; Colas, L.; Colledani, G.; Colnel, J.; Coquillat, P.; Corbel, E.; Corre, Y.; Costea, S.; Courtois, X.; Czarski, T.; Daniel, R.; Daumas, J.; De Combarieu, M.; De Temmerman, G.; De Vries, P.; Dechelle, C.; Deguara, F.; Dejarnac, R.; Delaplanche, J. M.; Delgado-Aparicio, L. F.; Delmas, E.; Delpech, L.; Desgranges, C.; Devynck, P.; Di Genova, S.; Diab, R.; Diallo, A.; Diez, M.; Dif-Pradalier, G.; Dimitrova, M.; Ding, B.; Dittmar, T.; Doceul, L.; Domenes, M.; Douai, D.; Dougnac, H.; Duan, X.; Dubus, L.; Dumas, N.; Dumont, R.; Durand, F.; Durif, A.; Durocher, A.; Durodie, F.; Ekedahl, A.; Elbeze, D.; Ertmer, S.; Escarguel, A.; Escourbiac, F.; Ezato, K.; Faisse, F.; Faure, N.; Fedorczak, N.; Fejoz, P.; Fenzi-Bonizec, C.; Ferlay, F.; Firdaouss, M.; Fleury, L.; Flouquet, D.; Gallo, A.; Gao, Y.; Garbet, X.; Garcia, J.; Gardarein, J. L.; Gargiulo, L.; Garibaldi, P.; Garitta, S.; Gaspar, J.; Gauthier, E.; Gavila, P.; Gazzotti, S.; Gely, F.; Geynet, M.; Gharafi, S.; Ghendrih, P.; Giacalone, I; Gil, C.; Ginoux, S.; Girard, S.; Giroux, E.; Giruzzi, G.; Goletto, C.; Goniche, M.; Gray, T.; Grelier, E.; Greuner, H.; Grigore, E.; Grisolia, C.; Grosjean, A.; Grosman, A.; Guibert, D.; Guilhem, D.; Guillemaut, C.; Guillermin, B.; Guirlet, R.; Gunn, J. P.; Gunsu, Y.; Gyergyek, T.; Hakola, A.; Harris, J.; Hatchressian, J. C.; Helou, W.; Hennequin, P.; Hernulldez, C.; Hill, K.; Hillairet, J.; Hirai, T.; Hoang, G. T.; Houry, M.; Hutter, T.; Imbeaux, F.; Imbert, N.; Ivanova-Stanik, I.; Jalageas, R.; Jardin, A.; Jaubert, L.; Jiolat, G.; Jonas, A.; Joubert, P.; Kirschner, A.; Klepper, C.; Komm, M.; Koubiti, M.; Kovacic, J.; Kozeiha, M.; Krieger, K.; Krol, K.; Lacroix, B.; Laguardia, L.; Lamaison, V; Laqua, H.; Lau, C.; Lausenaz, Y.; Le, R.; Le Bohec, M.; Lefevre, N.; Lemoine, N.; Lerche, E.; Lewerentz, M.; Li, Y.; Li, M.; Liang, A.; Linczuk, P.; Linsmeier, C.; Lipa, M.; Litaudon, X.; Liu, X.; Llorens, J.; Loarer, T.; Loarte, A.; Loewenhoff, T.; Lombard, G.; Lore, J.; Lorenzetto, P.; Lotte, P.; Lozano, M.; Lu, B.; Lunsford, R.; Luo, G.; Magaud, P.; Maget, P.; Mahieu, J. F.; Maini, P.; Malard, P.; Malinowski, K.; Manas, P.; Manenc, L.; Marandet, Y.; Marechal, J. L.; Marek, S.; Martin, C.; Martin, E.; Martinez, A.; Martino, P.; Mazon, D.; Messina, P.; Meunier, L.; Midou, D.; Mineo, Y.; Missilian, M.; Mitteau, R.; Mitu, B.; Mollard, P.; Moncada, V; Mondiere, T.; Morales, J.; Moreau, M.; Moreau, P.; Moudden, Y.; Moureau, G.; Mouyon, D.; Muraglia, M.; Nagy, A.; Nakano, T.; Nardon, E.; Neff, A.; Nespoli, F.; Nichols, J.; Nicollet, S.; Nouailletas, R.; Ono, M.; Ostuni, V; Parish, C.; Park, H.; Parrat, H.; Pascal, J. Y.; Pegourie, B.; Pellissier, F. P.; Peneliau, Y.; Peret, M.; Peysson, Y.; Pignoly, E.; Pintsuk, G.; Pitts, R.; Pocheau, C.; Portafaix, C.; Poulos, M.; Prochet, P.; Sitjes, A. Puig; Rasinski, M.; Raup, G.; Regal-Mezin, X.; Reux, C.; Riccardi, B.; Rice, J.; Richou, M.; Rigollet, F.; Roche, H.; Romazanov, J.; Ruset, C.; Sabot, R.; Saille, A.; Sakamoto, R.; Salmon, T.; Samaille, F.; Santagiustina, A.; Santraine, B.; Sarazin, Y.; Serre, E.; Shin, H.; Shiraiwai, S.; Signoret, Ja; Signoret, Je; Simonin, A.; Fettachi, O. Skalli; Song, Y.; Spring, A.; Spuig, P.; Sridhar, S.; Stratton, B.; Talatizi, C.; Tamain, P.; Tatali, R.; Tena, M.; Torre, A.; Toulouse, L.; Travere, J. M.; Treutterer, W.; Tsitrone, E.; Unterberg, E.; Urbanczyk, G.; Van Eester, D.; Van Rooij, G.; Vartanian, S.; Verger, J. M.; Vermare, L.; Vezinet, D.; Vignal, N.; Vincent, B.; Vives, S.; Volpe, D.; Wallace, G.; Wang, E.; Wang, L.; Wang, Yi; Wang, Yo; Wauters, T.; Wirth, B.; Wirtz, M.; Wojenski, A.; Wright, J.; Xu, M.; Yang, Q.; Yang, H.; Zago, B.; Zagorski; Zhang, B.; Zhang, X.; Zou, X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operating a full tungsten actively cooled tokamak: overview of WEST first phase of operation", "Source Title": "NUCLEAR FUSION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "WEST is an MA class superconducting, actively cooled, full tungsten (W) tokamak, designed to operate in long pulses up to 1000 s. In support of ITER operation and DEMO conceptual activities, key missions of WEST are: (i) qualification of high heat flux plasma-facing components in integrating both technological and physics aspects in relevant heat and particle exhaust conditions, particularly for the tungsten monoblocks foreseen in ITER divertor; (ii) integrated steady-state operation at high confinement, with a focus on power exhaust issues. During the phase 1 of operation (2017-2020), a set of actively cooled ITER-grade plasma facing unit prototypes was integrated into the inertially cooled W coated startup lower divertor. Up to 8.8 MW of RF power has been coupled to the plasma and divertor heat flux of up to 6 MW m(-2) were reached. Long pulse operation was started, using the upper actively cooled divertor, with a discharge of about 1 min achieved. This paper gives an overview of the results achieved in phase 1. Perspectives for phase 2, operating with the full capability of the device with the complete ITER-grade actively cooled lower divertor, are also described.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2022, "Volume": 62, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42007, "DOI": "10.1088/1741-4326/ac2525", "DOI Link": "http://dx.doi.org/10.1088/1741-4326/ac2525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000755288400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SM; Wang, TR; Ma, LT; Zhou, BB; Wu, JH; Zhu, DM; Li, YY; Fan, J; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shengmei; Wang, Tairan; Ma, Longtao; Zhou, Binbin; Wu, Jianghua; Zhu, Daming; Li, Yang Yang; Fan, Jun; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous rechargeable zinc air batteries operated at-110?C", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc air batteries (ZABs) based on alkaline aqueous electrolytes us-ing metallic zinc and air as electrodes have attracted significant attention for large-scale energy conversion systems. Nonetheless, the freezing of aqueous electrolytes and the catalytic performance deterioration in electrocatalysts hinder the ultralow-temperature operation of ZABs. Herein, we develop an ultralow-temperature-tolerant ZAB by fine-tuning the structure of the conventional KOH and developing an ultralow-temperature-tolerant FeCo-PC bifunc-tional electrocatalyst, which can endure the ultralow working tem-perature of a ZAB down to -110 degrees C and exhibit an unprecedented battery performance with a maximum power density of 61.3 mW cm -2, capacity of 627.9 mAh g-1, and cycling stability of about 140 h at -70 degrees C. This work represents a remarkable advance toward profoundly understanding the antifreezing properties of the con-ventional KOH electrolyte and the design of a low-temperature electrocatalyst, which will promote the development of ZABs with remarkably enhanced environmental adaptability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2023, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2022.10.028", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2022.10.028", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965588200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ju, SH; Shiga, T; Feng, L; Hou, ZF; Tsuda, K; Shiomi, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ju, Shenghong; Shiga, Takuma; Feng, Lei; Hou, Zhufeng; Tsuda, Koji; Shiomi, Junichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing nullostructures for Phonon Transport via Bayesian Optimization", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate optimization of thermal conductance across nullostructures by developing a method combining atomistic Green's function and Bayesian optimization. With an aim to minimize and maximize the interfacial thermal conductance (ITC) across Si-Si and Si-Ge interfaces by means of the Si/Ge composite interfacial structure, the method identifies the optimal structures from calculations of only a few percent of the entire candidates (over 60 000 structures). The obtained optimal interfacial structures are nonintuitive and impacting: the minimum ITC structure is an aperiodic superlattice that realizes 50% reduction from the best periodic superlattice. The physical mechanism of the minimum ITC can be understood in terms of the crossover of the two effects on phonon transport: as the layer thickness in the superlattice increases, the impact of Fabry-Perot interference increases, and the rate of reflection at the layer interfaces decreases. An aperiodic superlattice with spatial variation in the layer thickness has a degree of freedom to realize optimal balance between the above two competing mechanisms. Furthermore, the spatial variation enables weakening the impact of constructive phonon interference relative to that of destructive interference. The present work shows the effectiveness and advantage of material informatics in designing nullostructures to control heat conduction, which can be extended to other nullostructures and properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21024, "DOI": "10.1103/PhysRevX.7.021024", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.7.021024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401458400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benzerga, AA; Leblond, JB; Needleman, A; Tvergaard, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benzerga, Ahmed Amine; Leblond, Jean-Baptiste; Needleman, Alan; Tvergaard, Viggo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ductile failure modeling", "Source Title": "INTERNATIONAL JOURNAL OF FRACTURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ductile fracture of structural metals occurs mainly by the nucleation, growth and coalescence of voids. Here an overview of continuum models for this type of failure is given. The most widely used current framework is described and its limitations discussed. Much work has focused on extending void growth models to account for non-spherical initial void shapes and for shape changes during growth. This includes cases of very low stress triaxiality, where the voids can close up to micro-cracks during the failure process. The void growth models have also been extended to consider the effect of plastic anisotropy, or the influence of nonlocal effects that bring a material size scale into the models. Often the voids are not present in the material from the beginning, and realistic nucleation models are important. The final failure process by coalescence of neighboring voids is an issue that has been given much attention recently. At ductile fracture, localization of plastic flow is often important, leading to failure by a void-sheet mechanism. Various applications are presented to illustrate the models, including welded specimens, shear tests on butterfly specimens, and analyses of crack growth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 201, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 29, "End Page": 80, "Article Number": null, "DOI": "10.1007/s10704-016-0142-6", "DOI Link": "http://dx.doi.org/10.1007/s10704-016-0142-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382692000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ossonon, BD; Bélanger, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ossonon, Benjamin Diby; Belanger, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and characterization of sulfophenyl-functionalized reduced graphene oxide sheets", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the modification of graphene oxide (GO) by thermal reduction to obtain reduced graphene oxide (RGO) and subsequent modification by sulfophenyl groups as well as the characterization of these materials by thermogravimetric analysis coupled with mass spectroscopy (TGA-MS). The chemical modification of RGO was carried out by the spontaneous reaction of RGO with in situ generated sulfophenyl diazonium ions. The three different types of materials were also characterized by elemental analysis, Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The characteristic absorption band at 1034 and 1160 cm(-1) in the FTIR spectrum of the sulfophenyl-modified RGO (SRGO), as well as Raman spectroscopy and TGA-MS data indicated that sulfophenyl groups were successfully grafted on RGO. The presence of organic molecules at the SRGO surface was also demonstrated by elemental analysis, transmission electron microscopy, energy dispersive X-ray spectroscopy and XPS. TGA data and elemental analysis results showed that the loading of sulfophenyl groups was about 12 wt% and UV-visible-near IR spectroscopy confirms the slight increase of the optical band gap of RGO after covalent grafting of sulfophenyl groups on its surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 408, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 27224, "End Page": 27234, "Article Number": null, "DOI": "10.1039/c6ra28311j", "DOI Link": "http://dx.doi.org/10.1039/c6ra28311j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402166600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, ZY; Pereira, LFC; Wang, HQ; Zheng, JC; Donadio, D; Harju, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zheyong; Pereira, Luiz Felipe C.; Wang, Hui-Qiong; Zheng, Jin-Cheng; Donadio, Davide; Harju, Ari", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Force and heat current formulas for many-body potentials in molecular dynamics simulations with applications to thermal conductivity calculations", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We derive expressions of interatomic force and heat current for many-body potentials such as the Tersoff, the Brenner, and the Stillinger-Weber potential used extensively in molecular dynamics simulations of covalently bonded materials. Although these potentials have a many-body nature, a pairwise force expression that follows Newton's third law can be found without referring to any partition of the potential. Based on this force formula, a stress applicable for periodic systems can be unambiguously defined. The force formula can then be used to derive the heat current formulas using a natural potential partitioning. Our heat current formulation is found to be equivalent to most of the seemingly different heat current formulas used in the literature, but to deviate from the stress-based formula derived from two-body potential. We validate our formulation numerically on various systems described by the Tersoff potential, namely three-dimensional silicon and diamond, two-dimensional graphene, and quasi-one-dimensional carbon nullotube. The effects of cell size and production time used in the simulation are examined.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2015, "Volume": 92, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 94301, "DOI": "10.1103/PhysRevB.92.094301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.92.094301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360330400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oehrlein, GS; Metzler, D; Li, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oehrlein, G. S.; Metzler, D.; Li, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic Layer Etching at the Tipping Point: An Overview", "Source Title": "ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to achieve near-atomic precision in etching different materials when transferring lithographically defined templates is a requirement of increasing importance for nulloscale structure fabrication in the semiconductor and related industries. The use of ultra-thin gate dielectrics, ultra thin channels, and sub-20 nm film thicknesses in field effect transistors and other devices requires near-atomic scale etching control and selectivity. There is an emerging consensus that as critical dimensions approach the sub-10 nm scale, the need for an etching method corresponding to Atomic Layer Deposition (ALD), i.e. Atomic Layer Etching (ALE), has become essential, and that the more than 30-year quest to complement/replace continuous directional plasma etching (PE) methods for critical applications by a sequence of individual, self-limited surface reaction steps has reached a crucial stage. A key advantage of this approach relative to continuous PE is that it enables optimization of the individual steps with regard to reactant adsorption, self-limited etching, selectivity relative to other materials, and damage of critical surface layers. In this overview we present basic approaches to ALE of materials, discuss similarities/crucial differences relative to thermal and plasma-enhanced ALD, and then review selected results on ALE of materials aimed at pattern transfer. The overview concludes with a discussion of opportunities and challenges ahead. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email:oa@electrochem.org. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 224, "Times Cited, All Databases": 266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "N5041", "End Page": "N5053", "Article Number": null, "DOI": "10.1149/2.0061506jss", "DOI Link": "http://dx.doi.org/10.1149/2.0061506jss", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354783100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, BW; Zhong, PC; Jun, K; Riebesell, J; Han, K; Bartel, CJ; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Bowen; Zhong, Peichen; Jun, KyuJung; Riebesell, Janosh; Han, Kevin; Bartel, Christopher J.; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CHGNet as a pretrained universal neural network potential for charge-informed atomistic modelling", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale simulations with complex electron interactions remain one of the greatest challenges for atomistic modelling. Although classical force fields often fail to describe the coupling between electronic states and ionic rearrangements, the more accurate ab initio molecular dynamics suffers from computational complexity that prevents long-time and large-scale simulations, which are essential to study technologically relevant phenomena. Here we present the Crystal Hamiltonian Graph Neural Network (CHGNet), a graph neural network-based machine-learning interatomic potential (MLIP) that models the universal potential energy surface. CHGNet is pretrained on the energies, forces, stresses and magnetic moments from the Materials Project Trajectory Dataset, which consists of over 10 years of density functional theory calculations of more than 1.5 million inorganic structures. The explicit inclusion of magnetic moments enables CHGNet to learn and accurately represent the orbital occupancy of electrons, enhancing its capability to describe both atomic and electronic degrees of freedom. We demonstrate several applications of CHGNet in solid-state materials, including charge-informed molecular dynamics in LixMnO2, the finite temperature phase diagram for LixFePO4 and Li diffusion in garnet conductors. We highlight the significance of charge information for capturing appropriate chemistry and provide insights into ionic systems with additional electronic degrees of freedom that cannot be observed by previous MLIPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1031, "End Page": 1041, "Article Number": null, "DOI": "10.1038/s42256-023-00716-3", "DOI Link": "http://dx.doi.org/10.1038/s42256-023-00716-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001085170400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Van Nguyen, D; Nguyen, HM; Le, NT; Nguyen, KH; Nguyen, HT; Le, HM; Nguyen, AT; Dinh, NTT; Hoang, SA; Van Ha, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Van Nguyen, Dong; Nguyen, Huong Mai; Le, Nga Thanh; Nguyen, Kien Huu; Nguyen, Hoa Thi; Le, Huong Mai; Nguyen, Anh Trung; Dinh, Ngan Thi Thu; Hoang, Son Anh; Van Ha, Chien", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Copper nulloparticle Application Enhances Plant Growth and Grain Yield in Maize Under Drought Stress Conditions", "Source Title": "JOURNAL OF PLANT GROWTH REGULATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Abiotic stresses, including drought, detrimentally affect the growth and productivity of many economically important crop plants, leading to significant yield losses, which can result in food shortages and threaten the sustainability of agriculture. Balancing plant growth and stress responses is one of the most important functions of agricultural application to optimize plant production. In this study, we initially report that copper nulloparticle priming positively regulates drought stress responses in maize. The copper nulloparticle priming plants displayed enhanced drought tolerance indicated by their higher leaf water content and plant biomass under drought as compared with water-treated plants. Moreover, our data showed that the treatment of copper nulloparticle on plants increased anthocyanin, chlorophyll and carotenoid contents compared to water-treated plants under drought stress conditions. Additionally, histochemical analyses with nitro blue tetrazolium and 3,3 '-diaminobenzidine revealed that reactive oxygen species accumulation of priming plants was decreased as a result of enhancement of reactive oxygen species scavenging enzyme activities under drought. Furthermore, our comparative yield analysis data indicated applying copper nulloparticles to the plant increased total seed number and grain yield under drought stress conditions. Our data suggest that copper nulloparticle regulates plant protective mechanisms associated with drought tolerance, which is a promising approach for the production of drought-tolerant crop plants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 364, "End Page": 375, "Article Number": null, "DOI": "10.1007/s00344-021-10301-w", "DOI Link": "http://dx.doi.org/10.1007/s00344-021-10301-w", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Plant Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613971100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Würfel, U; Cuevas, A; Würfel, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wuerfel, Uli; Cuevas, Andres; Wuerfel, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge Carrier Separation in Solar Cells", "Source Title": "IEEE JOURNAL OF PHOTOVOLTAICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The selective transport of electrons and holes to the two terminals of a solar cell is often attributed to an electric field, although well-known physics states that they are driven by gradients of quasi-Fermi energies. However, in an illuminated semiconductor, these forces are not selective, and they drive both charge carriers toward both contacts. This paper shows that the necessary selectivity is achieved by differences in the conductivities of electrons and holes in two distinct regions of the device, which, for one charge carrier, allows transport to one contact and block transport to the other contact. To clarify the physics, we perform numerical simulations of three different solar cell structures with asymmetric carrier conductivities. Two of them achieve the ideal conversion efficiency limit, despite the fact that the charge carriers flow against an internal electric field, proving that the latter cannot explain carrier separation. A third, i.e., conceptual structure, has no electric field at all but still works ideally as a solar cell. In conclusion, the different conductivities of electrons and holes in two regions of the device can be identified as the essential ingredient for charge carrier separation in solar cells, regardless of the existence of an electric field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 461, "End Page": 469, "Article Number": null, "DOI": "10.1109/JPHOTOV.2014.2363550", "DOI Link": "http://dx.doi.org/10.1109/JPHOTOV.2014.2363550", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346732700069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sanchez-Diaz, J; Sánchez, RS; Masi, S; Krecmarová, M; Alvarez, AO; Barea, EM; Rodriguez-Romero, J; Chirvony, VS; Sánchez-Royo, JF; Martinez-Pastor, JP; Mora-Seró, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sanchez-Diaz, Jesus; Sanchez, Rafael S.; Masi, Sofia; Krecmarova, Marie; Alvarez, Agustin O.; Barea, Eva M.; Rodriguez-Romero, Jesus; Chirvony, Vladimir S.; Sanchez-Royo, Juan F.; Martinez-Pastor, Juan P.; Mora-Sero, Ivan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tin perovskite solar cells with >1,300 h of operational stability in N2 through a synergistic chemical engineering approach", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the promising properties of tin-based halide perovskites, one clear limitation is the fast Sn+2 oxidation. Consequently, the preparation of long-lasting devices remains challenging. Here, we report a chemical engineering approach, based on adding Dipropylammonium iodide (DipI) together with a well-known reducing agent, sodium borohydride (NaBH4), aimed at preventing the premature degradation of Sn-HPs. This strategy allows for obtaining efficiencies (PCE) above 10% with enhanced stability. The initial PCE remained unchanged upon 5 h in air (60% RH) at maximum-power point (MPP). Remarkably, 96% of the initial PCE was kept after 1,300 h at MPP in N-2. To the best of our knowledge, these are the highest reported values for Sn-based solar cells. Our findings demonstrate a beneficial synergistic effect when additives are incorporated, highlight the important role of iodide in the performance upon light soaking, and, ultimately, unveil the relevance of controlling the halide chemistry for future improvement of Sn-based perovskite devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 131, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 861, "End Page": 883, "Article Number": null, "DOI": "10.1016/j.joule.2022.02.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.02.014", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798575600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, YT; Das, S; Hong, ZJ; Xu, RJ; Chandrika, S; Gómez-Ortiz, F; García-Fernández, P; Chen, LQ; Hwang, HY; Junquera, J; Martin, LW; Ramesh, R; Muller, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Yu-Tsun; Das, Sujit; Hong, Zijian; Xu, Ruijuan; Chandrika, Swathi; Gomez-Ortiz, Fernulldo; Garcia-Fernulldez, Pablo; Chen, Long-Qing; Hwang, Harold Y.; Junquera, Javier; Martin, Lane W.; Ramesh, Ramamoorthy; Muller, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergent chirality in a polar meron to skyrmion phase transition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polar skyrmions are particle-like objects consisted of swirling electric dipoles that hold promise for next generation nullodevices. Here, the authors explore the strain-induced transition from skyrmions to merons using electron imaging methods. Polar skyrmions are predicted to emerge from the interplay of elastic, electrostatic and gradient energies, in contrast to the key role of the anti-symmetric Dzyalozhinskii-Moriya interaction in magnetic skyrmions. Here, we explore the reversible transition from a skyrmion state (topological charge of -1) to a two-dimensional, tetratic lattice of merons (with topological charge of -1/2) upon varying the temperature and elastic boundary conditions in [(PbTiO3)(16)/(SrTiO3)(16)](8) membranes. This topological phase transition is accompanied by a change in chirality, from zero-net chirality (in meronic phase) to net-handedness (in skyrmionic phase). We show how scanning electron diffraction provides a robust measure of the local polarization simultaneously with the strain state at sub-nm resolution, while also directly mapping the chirality of each skyrmion. Using this, we demonstrate strain as a crucial order parameter to drive isotropic-to-anisotropic structural transitions of chiral polar skyrmions to non-chiral merons, validated with X-ray reciprocal space mapping and phase-field simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1355, "DOI": "10.1038/s41467-023-36950-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36950-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948845000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takakura, A; Beppu, K; Nishihara, T; Fukui, A; Kozeki, T; Namazu, T; Miyauchi, Y; Itami, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takakura, Akira; Beppu, Ko; Nishihara, Taishi; Fukui, Akihito; Kozeki, Takahiro; Namazu, Takahiro; Miyauchi, Yuhei; Itami, Kenichiro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strength of carbon nullotubes depends on their chemical structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-walled carbon nullotubes theoretically possess ultimate intrinsic tensile strengths in the 100-200 GPa range, among the highest in existing materials. However, all of the experimentally reported values are considerably lower and exhibit a considerable degree of scatter, with the lack of structural information inhibiting constraints on their associated mechanisms. Here, we report the first experimental measurements of the ultimate tensile strengths of individual structure-defined, single-walled carbon nullotubes. The strength depends on the chiral structure of the nullotube, with small-diameter, near-armchair nullotubes exhibiting the highest tensile strengths. This observed structural dependence is comprehensively understood via the intrinsic structure-dependent inter-atomic stress, with its concentration at structural defects inevitably existing in real nullotubes. These findings highlight the target nullotube structures that should be synthesized when attempting to fabricate the strongest materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3040, "DOI": "10.1038/s41467-019-10959-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10959-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474732500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Foroutan, R; Peighambardoust, SJ; Ghojavand, S; Farjadfard, S; Ramavandi, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Foroutan, Rauf; Peighambardoust, Seyed Jamaleddin; Ghojavand, Solmaz; Farjadfard, Sima; Ramavandi, Bahman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cadmium elimination from wastewater using potato peel biochar modified by ZIF-8 and magnetic nulloparticle", "Source Title": "COLLOID AND INTERFACE SCIENCE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A recyclable and magnetic nullocomposite was fabricated from biochar of potato peel (BPP), MnFe2O4, and ZIF-8 (BET area: 174.92m2/g). The Cd2+ removal using BPP/MnFe2O4@ZIF-8 was maximized at pH 6, a temperature of 45 degrees C, and a time of 100 min. The capacity of Cd adsorption using BPP, BPP/MnFe2O4, and BPP/ MnFe2O4@ZIF-8 was computed to be 33.76, 45.02, and 80.52 mg/g, respectively. The influence of coexistence ions on cadmium elimination by BPP/MnFe2O4@ZIF-8 was explored. Shipbuilding wastewater was treated to an acceptable level using the nullocomposite. The Cd adsorption was endothermic and followed the pseudo-secondorder (R2 > 0.98). Therefore, BPP/MnFe2O4@ZIF-8 is an affordable material for treating cadmium.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 55, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100723, "DOI": "10.1016/j.colcom.2023.100723", "DOI Link": "http://dx.doi.org/10.1016/j.colcom.2023.100723", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001027971000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JG; Wan, WC; Triana, CA; Chen, H; Zhao, YG; Mavrokefalos, CK; Patzke, GR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jingguo; Wan, Wenchao; Triana, Carlos A.; Chen, Hang; Zhao, Yonggui; Mavrokefalos, Christos K.; Patzke, Greta R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reaction kinetics and interplay of two different surface states on hematite photoanodes for water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding the function of surface states on photoanodes is crucial for unraveling the underlying reaction mechanisms of water oxidation. For hematite photoanodes, only one type of surface states with higher oxidative energy (S1) has been proposed and verified as reaction intermediate, while the other surface state located at lower potentials (S2) was assigned to inactive or recombination sites. Through employing rate law analyses and systematical (photo)electrochemical characterizations, here we show that S2 is an active reaction intermediate for water oxidation as well. Furthermore, we demonstrate that the reaction kinetics and dynamic interactions of both S1 and S2 depend significantly on operational parameters, such as illumination intensity, nature of the electrolyte, and applied potential. These insights into the individual reaction kinetics and the interplay of both surface states are decisive for designing efficient photoanodes. Detailed understanding of the reaction kinetics of the surface states of hematite photoanodes is crucial to improving their water oxidation performance. Here the authors reveal two dynamically interacting states which play a key part in the structure properties of these anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 255, "DOI": "10.1038/s41467-020-20510-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20510-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670285300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, GQ; Xu, SY; Wieder, BJ; Sanchez, DS; Huang, SM; Belopolski, I; Chang, TR; Zhang, ST; Bansil, A; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Guoqing; Xu, Su-Yang; Wieder, Benjamin J.; Sanchez, Daniel S.; Huang, Shin-Ming; Belopolski, Ilya; Chang, Tay-Rong; Zhang, Songtian; Bansil, Arun; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional Chiral Fermions and Large Topological Fermi Arcs in RhSi", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The theoretical proposal of chiral fermions in topological semimetals has led to a significant effort towards their experimental realization. In particular, the Fermi surfaces of chiral semimetals carry quantized Chern numbers, making them an attractive platform for the observation of exotic transport and optical phenomena. While the simplest example of a chiral fermion in condensed matter is a conventional vertical bar C vertical bar = 1 Weyl fermion, recent theoretical works have proposed a number of unconventional chiral fermions beyond the standard model which are protected by unique combinations of topology and crystalline symmetries. However, materials candidates for experimentally probing the transport and response signatures of these unconventional fermions have thus far remained elusive. In this Letter, we propose the RhSi family in space group No. 198 as the ideal platform for the experimental examination of unconventional chiral fermions. We find that RhSi is a filling-enforced semimetal that features near its Fermi surface a chiral double sixfold-degenerate spin-1 Weyl node at R and a previously uncharacterized fourfold-degenerate chiral fermion at Gamma. Each unconventional fermion displays Chern number +/- 4 at the Fermi level. We also show that RhSi displays the largest possible momentum separation of compensative chiral fermions, the largest proposed topologically nontrivial energy window, and the longest possible Fermi arcs on its surface. We conclude by proposing signatures of an exotic bulk photogalvanic response in RhSi.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 17", "Publication Year": 2017, "Volume": 119, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 206401, "DOI": "10.1103/PhysRevLett.119.206401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.206401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000415604000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MF; Liu, SS; Ji, HQ; Yang, TZ; Qian, T; Yan, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mengfan; Liu, Sisi; Ji, Haoqing; Yang, Tingzhou; Qian, Tao; Yan, Chenglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Salting-out effect promoting highly efficient ambient ammonia synthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electroreduction of nitrogen to ammonia offers a promising alternative to the energy-intensive Haber-Bosch process. Unfortunately, the reaction suffers from low activity and selectivity, owing to competing hydrogen evolution and the poor accessibility of nitrogen to the electrocatalyst. Here, we report that deliberately triggering a salting-out effect in a highly concentrated electrolyte can simultaneously tackle the above challenges and achieve highly efficient ammonia synthesis. The solute ions exhibit strong affinity for the surrounding H2O molecules, forming a hydration shell and limiting their efficacy as both proton sources and solvents. This not only effectively suppresses hydrogen evolution but also ensures considerable nitrogen flux at the reaction interface via heterogeneous nucleation of the precipitate, thus facilitating the subsequent reduction process in terms of both selectivity and activity. As expected, even when assembled with a metal-free electrocatalyst, a high Faradaic efficiency of 711.9% is achieved with this proof-of-concept system. The electroreduction of nitrogen to ammonia offers a promising alternative to the Haber-Bosch process but suffers from low activity and selectivity. Here, authors demonstrate that triggering a salting-out effect in a highly concentrated electrolyte can achieve highly efficient ammonia synthesis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 27", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3198, "DOI": "10.1038/s41467-021-23360-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23360-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659058200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chumak, AV; Serga, AA; Hillebrands, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chumak, A. V.; Serga, A. A.; Hillebrands, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnonic crystals for data processing", "Source Title": "JOURNAL OF PHYSICS D-APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnons (the quanta of spin waves) propagating in magnetic materials with wavelengths at the nullometer-scale and carrying information in the form of an angular momentum can be used as data carriers in next-generation, nullo-sized low-loss information processing systems. In this respect, artificial magnetic materials with properties periodically varied in space, known as magnonic crystals, are especially promising for controlling and manipulating magnon currents. In this article, different approaches for the realization of static, reconfigurable, and dynamic magnonic crystals are presented along with a variety of novel wave phenomena discovered in these crystals. Special attention is devoted to the utilization of magnonic crystals for processing of analog and digital information.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 368, "Times Cited, All Databases": 384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 50, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 244001, "DOI": "10.1088/1361-6463/aa6a65", "DOI Link": "http://dx.doi.org/10.1088/1361-6463/aa6a65", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402368400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Finley, J; Liu, LQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Finley, Joseph; Liu, Luqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin-Orbit-Torque Efficiency in Compensated Ferrimagnetic Cobalt-Terbium Alloys", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the potential advantages of information storage in antiferromagnetically coupled materials, it remains unclear whether one can control the magnetic-moment orientation efficiently because of the canceled magnetic moment. Here, we report spin-orbit-torque-induced magnetization switching of ferrimagnetic Co1-xTbx films with perpendicular magnetic anisotropy. Current-induced switching is demonstrated in all of the studied film compositions, including those near the magnetization compensation point. The spin-orbit-torque-induced effective field is further quantified in the domain-wall motion regime. A divergent behavior that scales with the inverse of magnetic moment is confirmed close to the compensation point, which is consistent with angular momentum conservation. Moreover, we also quantify the Dzyaloshinskii-Moriya interaction energy in the Ta/Co1-xTbx system and we find that the energy density increases as a function of the Tb concentration. The demonstrated spin-orbit-torque switching, in combination with the fast magnetic dynamics and minimal net magnetization of ferrimagnetic alloys, promises spintronic devices that are faster and with higher density than traditional ferromagnetic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2016, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 54001, "DOI": "10.1103/PhysRevApplied.6.054001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.6.054001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386653200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, P; Liu, JR; Xu, LJ; Wang, J; Ouyang, XP; Jiang, JH; Huang, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Peng; Liu, Jinrong; Xu, Liujun; Wang, Jun; Ouyang, Xiaoping; Jiang, Jian-Hua; Huang, Jiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable liquid-solid hybrid thermal metamaterials with a topology transition", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal metamaterials provide rich control of heat transport which is becoming the foundation of cutting-edge applications ranging from chip cooling to biomedical. However, due to the fundamental laws of physics, the manipulation of heat is much more constrained in conventional thermal metamaterials where effective heat conduction with Onsager reciprocity dominates. Here, through the inclusion of thermal convection and breaking the Onsager reciprocity, we unveil a regime in thermal metamaterials and transformation thermotics that goes beyond effective heat conduction. By designing a liquid-solid hybrid thermal metamaterial, we demonstrate a continuous switch from thermal cloaking to thermal concentration in one device with external tuning. Underlying such a switch is a topology transition in the virtual space of the thermotic transformation which is achieved by tuning the liquid flow via external control. These findings illustrate the extraordinary heat transport in complex multicomponent thermal metamaterials and pave the way toward an unprecedented regime of heat manipulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 41, "Times Cited, All Databases": 46, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2023, "Volume": 120, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2217068120", "DOI": "10.1073/pnas.2217068120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2217068120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001050016100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schreuders, FKG; Sagis, LMC; Bodnar, I; Erni, P; Boom, RM; van der Goot, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schreuders, F. K. G.; Sagis, L. M. C.; Bodnar, I; Erni, P.; Boom, R. M.; van der Goot, A. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Small and large oscillatory shear properties of concentrated proteins", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A closed cavity rheometer was employed to assess the properties of concentrated protein materials before, during and after thermal treatment, using conditions that are relevant to the production of meat analogues. Pea and soy protein isolate and wheat gluten were used as model matrices. The analysis was done using Lissajous curves, both for small and large amplitude oscillatory shear deformation. The energy dissipation ratios based on the enclosed area inside the Lissajous curves characterize the plasticity of the materials. The results show that the modulus of wheat gluten increases during heating and remains elevated after cooling. In contrast, the moduli of pea and soy protein isolates decrease during heating. Subsequent cooling leads to properties that are similar to the rheological properties of unheated pea and soy protein isolates. Lissajous curves and energy dissipation ratios provide insight in the non-linear response. At 30 degrees C, pea and soy protein isolate have a higher dissipation ratio than wheat gluten. Upon a heat treatment and even after cooling, the dissipation ratio was smaller at similar strain amplitude compared with 30 degrees C. This indicates that heating induced more elasticity. Upon heating, pea protein isolate loses its elastic properties faster than soy protein isolate, while wheat gluten showed abrupt dissipation after extensive deformation. The observed characteristics are consistent with the behaviour during extrusion and shearing, in which wheat gluten forms extended filaments, while soy and pea protein isolates form a homogeneous matrix. Studying the large oscillatory shear behaviour during and after thermal treatment provides a more detailed picture of the rheological changes during processing, than one would obtain through classical rheology. The dissipation ratio summarizes the information in the Lissajous curves. These insights help to better identify material-structure-process relationships for concentrated plant protein materials during thermomechanical conversions, such as extrusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106172, "DOI": "10.1016/j.foodhyd.2020.106172", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2020.106172", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571502100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, RK; Bandurin, DA; Pellegrino, FMD; Cao, Y; Principi, A; Guo, H; Auton, GH; Ben Shalom, M; Ponomarenko, LA; Falkovich, G; Watanabe, K; Taniguchi, T; Grigorieva, IV; Levitov, LS; Polini, M; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, R. Krishna; Bandurin, D. A.; Pellegrino, F. M. D.; Cao, Y.; Principi, A.; Guo, H.; Auton, G. H.; Ben Shalom, M.; Ponomarenko, L. A.; Falkovich, G.; Watanabe, K.; Taniguchi, T.; Grigorieva, I. V.; Levitov, L. S.; Polini, M.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superballistic flow of viscous electron fluid through graphene constrictions", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electron-electron (e-e) collisions can impact transport in a variety of surprising and sometimes counterintuitive ways(1-6). Despite strong interest, experiments on the subject proved challenging because of the simultaneous presence of different scattering mechanisms that suppress or obscure consequences of e-e scattering(7-11). Only recently, suffciently clean electron systems with transport dominated by e-e collisions have become available, showing behaviour characteristic of highly viscous fluids(12-14). Here we study electron transport through graphene constrictions and show that their conductance below 150 K increases with increasing temperature, in stark contrast to the metallic character of doped graphene(15). Notably, the measured conductance exceeds the maximum conductance possible for free electrons(16,17). This anomalous behaviour is attributed to collective movement of interacting electrons, which 'shields' individual carriers from momentum loss at sample boundaries(18,19). The measurements allow us to identify the conductance contribution arising due to electron viscosity and determine its temperature dependence. Besides fundamental interest, our work shows that viscous effects can facilitate high-mobility transport at elevated temperatures, a potentially useful behaviour for designing graphene-based devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2017, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1182, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS4240", "DOI Link": "http://dx.doi.org/10.1038/NPHYS4240", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417049400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, TT; Zhao, B; Xin, W; Wang, Y; Wang, B; Zheng, X; Xie, HB; Zhang, ZY; Yang, JJ; Guo, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou Tingting; Zhao Bo; Xin Wei; Wang Ye; Wang Bin; Zheng Xin; Xie Hongbo; Zhang Zhiyu; Yang Jianjun; Guo, Chun-Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-speed femtosecond laser plasmonic lithography and reduction of graphene oxide for anisotropic photoresponse", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Micro/nulloprocessing of graphene surfaces has attracted significant interest for both science and applications due to its effective modulation of material properties, which, however, is usually restricted by the disadvantages of the current fabrication methods. Here, by exploiting cylindrical focusing of a femtosecond laser on graphene oxide (GO) films, we successfully produce uniform subwavelength grating structures at high speed along with a simultaneous in situ photoreduction process. Strikingly, the well-defined structures feature orientations parallel to the laser polarization and significant robustness against distinct perturbations. The proposed model and simulations reveal that the structure formation is based on the transverse electric (TE) surface plasmons triggered by the gradient reduction of the GO film from its surface to the interior, which eventually results in interference intensity fringes and spatially periodic interactions. Further experiments prove that such a regular structured surface can cause enhanced optical absorption (>20%) and an anisotropic photoresponse (-0.46 ratio) for the reduced GO film. Our work not only provides new insights into understanding the laser-GO interaction but also lays a solid foundation for practical usage of femtosecond laser plasmonic lithography, with the prospect of expansion to other two-dimensional materials for novel device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 69, "DOI": "10.1038/s41377-020-0311-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0311-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528588800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maamoun, AH; Elbestawi, M; Dosbaeva, GK; Veldhuis, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maamoun, Ahmed H.; Elbestawi, Mohamed; Dosbaeva, Goulnara K.; Veldhuis, Stephen C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal post-processing of AlSi10Mg parts produced by Selective Laser Melting using recycled powder", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance enhancement of parts produced using Selective Laser Melting (SLM) is an important goal for various industrial applications. In order to achieve this goal, obtaining a homogeneous microstructure and eliminating material defects within the fabricated parts are important research issues. The objective of this experimental study is to evaluate the effect of thermal post-processing of AlSi10Mg parts, using recycled powder, with the aim of improving the microstructure homogeneity of the as-built parts. This work is essential for the cost-effective additive manufacturing (AM) of metal optics and optomechanical systems. To achieve this goal, a full characterization of fresh and recycled powder was performed, in addition to a microstructure assessment of the as-built fabricated samples. Annealing, solution heat treatment (SHT) and T6 heat treatment (T6 HT) were applied under different processing conditions. The results demonstrated an improvement in microstructure homogeneity after thermal post-processing under specific conditions of SHT and T6 HT. A micro-hardness map was developed to assist in the selection of the optimized post-processing parameters in order to satisfy the design requirements of the part.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 234, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 234, "End Page": 247, "Article Number": null, "DOI": "10.1016/j.addma.2018.03.014", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2018.03.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435751300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Appugliese, F; Enkner, J; Paravicini-Bagliani, GL; Beck, M; Reichl, C; Wegscheider, W; Scalari, G; Ciuti, C; Faist, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Appugliese, Felice; Enkner, Josefine; Paravicini-Bagliani, Gian Lorenzo; Beck, Mattias; Reichl, Christian; Wegscheider, Werner; Scalari, Giacomo; Ciuti, Cristiano; Faist, Jerome", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breakdown of topological protection by cavity vacuum fields in the integer quantum Hall effect", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The prospect of controlling the electronic properties of materials via the vacuum fields of cavity electromagnetic resonators is emerging as one of the frontiers of condensed matter physics. We found that the enhancement of vacuum field fluctuations in subwavelength split-ring resonators strongly affects one of the most paradigmatic quantum protectorates, the quantum Hall electron transport in high-mobility two-dimensional electron gases. The observed breakdown of the topological protection of the integer quantum Hall effect is interpreted in terms of a long-range cavity-mediated electron hopping where the anti-resonullt terms of the light-matter coupling Hamiltonian develop into a finite resistivity induced by the vacuum fluctuations. Our experimental platform can be used for any two-dimensional material and provides a route to manipulate electron phases in matter by means of vacuum-field engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2022, "Volume": 375, "Issue": 6584, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1030, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abl5818", "DOI Link": "http://dx.doi.org/10.1126/science.abl5818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000764236900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghalambaz, M; Chamkha, AJ; Wen, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghalambaz, Mohammad; Chamkha, Ali J.; Wen, Dongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural convective flow and heat transfer of nullo-Encapsulated Phase Change Materials (NEPCMs) in a cavity", "Source Title": "INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free convective flow and heat transfer of a suspension of nullo Encapsulated Phase Change Materials (NEPCMs) in an enclosure is studied. NEPCM particles are core-shell structured with Phase Change Material (PCM) as the core. The enclosure is a square cavity with top and bottom insulated walls and differentially-heated isothermal vertical walls. The NEPCM particles circulate under natural convection inside the cavity. The PCM cores undergo phase change from solid to liquid and absorb some of the surrounding's heat in the form of latent heat in the hot region, and release the absorbed heat in the cold region by solidification. The governing equations representing the conservation of mass, flow, and heat of NEPCM suspension are introduced in the form of partial differential equations. The governing equations are transformed into non-dimensional form and solved by the finite element method. A grid check and validation test are performed to ensure the accuracy of the results. The outcomes show that the fusion temperature of NEPCM particles is the key factor affecting the heat transfer enhancement of NEPCMs in the natural convection flow. The enhancement of heat transfer is highly dependent on the non-dimensional fusion temperature, theta(f), and very good performance can be achieved in the range of 1/4 < theta(f) < 3/4. Comparing to the base fluid, a relative enhancement of about 10% can be achieved by using NEPCMs at a non-dimensional fusion temperature of 1/4. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2019, "Volume": 138, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 738, "End Page": 749, "Article Number": null, "DOI": "10.1016/j.ijheatmasstransfer.2019.04.037", "DOI Link": "http://dx.doi.org/10.1016/j.ijheatmasstransfer.2019.04.037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472695300069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gorgon, S; Lv, K; Grüne, J; Drummond, BH; Myers, WK; Londi, G; Ricci, G; Valverde, D; Tonnelé, C; Murto, P; Romanov, AS; Casanova, D; Dyakonov, V; Sperlich, A; Beljonne, D; Olivier, Y; Li, F; Friend, RH; Evans, EW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gorgon, Sebastian; Lv, Kuo; Grune, Jeannine; Drummond, Bluebell H.; Myers, William K.; Londi, Giacomo; Ricci, Gaetano; Valverde, Danillo; Tonnele, Claire; Murto, Petri; Romanov, Alexander S.; Casanova, David; Dyakonov, Vladimir; Sperlich, Andreas; Beljonne, David; Olivier, Yoann; Li, Feng; Friend, Richard H.; Evans, Emrys W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible spin-optical interface in luminescent organic radicals", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecules present a versatile platform for quantum information science(1,2) and are candidates for sensing and computation applications(3,4). Robust spin-optical interfaces are key to harnessing the quantum resources of materials(5). To date, carbon-based candidates have been non-luminescent(6,7), which prevents optical readout via emission. Here we report organic molecules showing both efficient luminescence and near-unity generation yield of excited states with spin multiplicity S > 1. This was achieved by designing an energy resonullce between emissive doublet and triplet levels, here on covalently coupled tris(2,4,6-trichlorophenyl) methyl-carbazole radicals and anthracene. We observed that the doublet photoexcitation delocalized onto the linked acene within a few picoseconds and subsequently evolved to a pure high-spin state (quartet for monoradical, quintet for biradical) of mixed radical-triplet character near 1.8 eV. These high-spin states are coherently addressable with microwaves even at 295 K, with optical readout enabled by reverse intersystem crossing to emissive states. Furthermore, for the biradical, on return to the ground state the previously uncorrelated radical spins either side of the anthracene shows strong spin correlation. Our approach simultaneously supports a high efficiency of initialization, spin manipulations and light-based readout at room temperature. The integration of luminescence and high-spin states creates an organic materials platform for emerging quantum technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2023, "Volume": 620, "Issue": 7974, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 538, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06222-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06222-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169143500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, S; Yavuz, I; Weber, MH; Huang, TY; Chen, CH; Wang, R; Wang, HC; Ko, JH; Nuryyeva, S; Xue, JJ; Zhao, YP; Wei, KH; Lee, JW; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Shaun; Yavuz, Ilhan; Weber, Marc H.; Huang, Tianyi; Chen, Chung-Hao; Wang, Rui; Wang, Hao-Cheng; Ko, Jeong Hoon; Nuryyeva, Selbi; Xue, Jingjing; Zhao, Yepin; Wei, Kung-Hwa; Lee, Jin-Wook; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shallow Iodine Defects Accelerate the Degradation of α-Phase Formamidinium Perovskite", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shallow defects are mostly benign in covalent semiconductors, such as silicon, given that they do not constitute non-radiative recombination sites. In contrast, the existence of shallow defects in ionic perovskite crystals might have significant repercussions on the long-term stability of perovskite solar cells (PSCs) because of the metastability of the ubiquitous formamidinium lead triiodide (FAPbI(3)) perovskite and the migration of charged point defects. Here, we show that shallow iodine interstitial defects (I-i) can be generated unintentionally during commonly used post-fabrication treatments, which can lower the cubic-to-hexagonal transformation barrier of FAPbI(3)-based perovskites to accelerate its phase degradation. We demonstrate that concurrently avoiding the generation of I-i and the more effective passivation of iodine vacancies (V-I) can improve the thermodynamic stability of the films and operational stability of the PSCs. Our most stable PSC retained 92.1 % of its initial performance after nearly 1,000 h of continuous illumination operational stability testing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 227, "Times Cited, All Databases": 238, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2020, "Volume": 4, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2426, "End Page": 2442, "Article Number": null, "DOI": "10.1016/j.joule.2020.08.016", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.08.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000592226000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Yao, MJ; Yang, M; Zhu, JC; Chen, J; Niu, ZQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Yao, Minjie; Yang, Min; Zhu, Jiacai; Chen, Jun; Niu, Zhiqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergetic modulation on ionic association and solvation structure by electron- withdrawing effect for aqueous zinc-ion batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc- ion batteries are emerging as one of the most promising large- scale energy storage systems due to their low cost and high safety. However, Zn anodes often encoun-ter the problems of Zn dendrite growth, hydrogen evolution reaction, and formation of by-products. Herein, we developed the low ionic association electrolytes (LIAEs) by introducing 2, 2, 2-trifluoroethanol (TFE) into 30 m ZnCl2 electrolyte. Owing to the electron-withdrawing effect of - CF3 groups in TFE molecules, in LIAEs, the Zn2+ sol-vation structures convert from larger aggregate clusters into smaller parts and TFE will construct H- bonds with H2O in Zn2+ solvation structure simultaneously. Consequently, ionic migration kinetics are significantly enhanced and the ionization of solvated H2O is effectively suppressed in LIAEs. As a result, Zn anodes in LIAE display a fast plating/ stripping kinetics and high Coulombic efficiency of 99.74%. The corresponding full batteries exhibit an improved comprehensive performance such as high- rate capability and long cycling life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2023, "Volume": 120, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2221980120", "DOI": "10.1073/pnas.2221980120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2221980120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038942900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chmiela, S; Vassilev-Galindo, V; Unke, OT; Kabylda, A; Sauceda, HE; Tkatchenko, A; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chmiela, Stefan; Vassilev-Galindo, Valentin; Unke, Oliver T.; Kabylda, Adil; Sauceda, Huziel E.; Tkatchenko, Alexandre; Mueller, Klaus-Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accurate global machine learning force fields for molecules with hundreds of atoms", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Global machine learning force fields, with the capacity to capture collective interactions in molecular systems, now scale up to a few dozen atoms due to considerable growth of model complexity with system size. For larger molecules, locality assumptions are introduced, with the consequence that nonlocal interactions are not described. Here, we develop an exact iterative approach to train global symmetric gradient domain machine learning (sGDML) force fields (FFs) for several hundred atoms, without resorting to any potentially uncontrolled approximations. All atomic degrees of freedom remain correlated in the global sGDML FF, allowing the accurate description of complex molecules and materials that present phenomena with far-reaching characteristic correlation lengths. We assess the accuracy and efficiency of sGDML on a newly developed MD22 benchmark dataset containing molecules from 42 to 370 atoms. The robustness of our approach is demonstrated in nullosecond path-integral molecular dynamics simulations for supramolecular complexes in the MD22 dataset.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2023, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eadf0873", "DOI": "10.1126/sciadv.adf0873", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adf0873", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911464300045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hung, LD; Pásztory, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hung, Le Duong; Pasztory, Zoltan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An overview of factors influencing thermal conductivity of building insulation materials", "Source Title": "JOURNAL OF BUILDING ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solving the matter of traditional energy consumption and finding the proper alternative resources are vital keys to a sustainable development policy. In recent years, many different thermal insulation materials have been developed for better energy efficiency and less environment damage. These products have confirmed their usefulness in buildings due to their benefits such as low density, high thermal resistance, and cost effectiveness. The efficiency of thermal insulation depends on their thermal conductivity and their ability to maintain their thermal characteristics over a period of time. This study presents factors influencing the thermal conductivity coefficient of three main groups including conventional, alternative, and new advanced materials. The most common factors are moisture content, temperature difference, and bulk density. Other factors are explained in some dependent studies such as airflow velocity, thickness, pressure, and material aging. The relationship between the thermal conductivity values with the mean temperature, moisture content, and density which were obtained from experimental investigation has also been summarized. Finally, uncertainty about the thermal conductivity value of some common insulation materials is also reviewed as the basis of selecting or designing the products used in building envelopes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 44, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102604, "DOI": "10.1016/j.jobe.2021.102604", "DOI Link": "http://dx.doi.org/10.1016/j.jobe.2021.102604", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000704373600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, H; Gül, Ö; Conesa-Boj, S; Nowak, MP; Wimmer, M; Zuo, K; Mourik, V; de Vries, FK; van Veen, J; de Moor, MWA; Bommer, JDS; van Woerkom, DJ; Car, D; Plissard, SR; Bakkers, EPAM; Quintero-Pérez, M; Cassidy, MC; Koelling, S; Goswami, S; Watanabe, K; Taniguchi, T; Kouwenhoven, LP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hao; Gul, Onder; Conesa-Boj, Sonia; Nowak, Michal P.; Wimmer, Michael; Zuo, Kun; Mourik, Vincent; de Vries, Folkert K.; van Veen, Jasper; de Moor, Michiel W. A.; Bommer, Jouri D. S.; van Woerkom, David J.; Car, Diana; Plissard, Sebastien R.; Bakkers, Erik P. A. M.; Quintero-Perez, Marina; Cassidy, Maja C.; Koelling, Sebastian; Goswami, Srijit; Watanabe, Kenji; Taniguchi, Takashi; Kouwenhoven, Leo P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ballistic superconductivity in semiconductor nullowires", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor nullowires have opened new research avenues in quantum transport owing to their confined geometry and electrostatic tunability. They have offered an exceptional testbed for superconductivity, leading to the realization of hybrid systems combining the macroscopic quantum properties of superconductors with the possibility to control charges down to a single electron. These advances brought semiconductor nullowires to the forefront of efforts to realize topological superconductivity and Majorana modes. A prime challenge to benefit from the topological properties of Majoranas is to reduce the disorder in hybrid nullowire devices. Here we show ballistic superconductivity in InSb semiconductor nullowires. Our structural and chemical analyses demonstrate a high-quality interface between the nullowire and a NbTiN superconductor that enables ballistic transport. This is manifested by a quantized conductance for normal carriers, a strongly enhanced conductance for Andreev-reflecting carriers, and an induced hard gap with a significantly reduced density of states. These results pave the way for disorder-free Majorana devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16025, "DOI": "10.1038/ncomms16025", "DOI Link": "http://dx.doi.org/10.1038/ncomms16025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404837800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Liu, ZK; Sun, Y; Yang, HF; Rajamathi, CR; Qi, YP; Yang, LX; Chen, C; Peng, H; Hwang, CC; Sun, SZ; Mo, SK; Vobornik, I; Fujii, J; Parkin, SSP; Felser, C; Yan, BH; Chen, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, J.; Liu, Z. K.; Sun, Y.; Yang, H. F.; Rajamathi, C. R.; Qi, Y. P.; Yang, L. X.; Chen, C.; Peng, H.; Hwang, C. -C.; Sun, S. Z.; Mo, S. -K.; Vobornik, I.; Fujii, J.; Parkin, S. S. P.; Felser, C.; Yan, B. H.; Chen, Y. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Signature of type-II Weyl semimetal phase in MoTe2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological Weyl semimetal (TWS), a new state of quantum matter, has sparked enormous research interest recently. Possessing unique Weyl fermions in the bulk and Fermi arcs on the surface, TWSs offer a rare platform for realizing many exotic physical phenomena. TWSs can be classified into type-I that respect Lorentz symmetry and type-II that do not. Here, we directly visualize the electronic structure of MoTe2, a recently proposed type-II TWS. Using angle-resolved photoemission spectroscopy (ARPES), we unravel the unique surface Fermi arcs, in good agreement with our ab initio calculations that have nontrivial topological nature. Our work not only leads to new understandings of the unusual properties discovered in this family of compounds, but also allows for the further exploration of exotic properties and practical applications of type-II TWSs, as well as the interplay between superconductivity (MoTe2 was discovered to be superconducting recently) and their topological order.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 424, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13973, "DOI": "10.1038/ncomms13973", "DOI Link": "http://dx.doi.org/10.1038/ncomms13973", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391950300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burg, GW; Zhu, JH; Taniguchi, T; Watanabe, K; MacDonald, AH; Tutuc, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burg, G. William; Zhu, Jihang; Taniguchi, Takashi; Watanabe, Kenji; MacDonald, Allan H.; Tutuc, Emanuel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlated Insulating States in Twisted Double Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a combined experimental and theoretical study of twisted double bilayer graphene with twist angles between 1 degrees and 1.35 degrees. Consistent with moire band structure calculations, we observe insulators at integer moire band fillings one and three, but not two. An applied transverse electric field separates the first moire conduction band from neighboring bands, and favors the appearance of correlated insulators at 1/4, 1/2, and 3/4 band filling. Insulating states at 1/4 and 3/4 band filling emerge only in a parallel magnetic field (B-parallel to), whereas the resistivity at half band filling is weakly dependent on B-parallel to. Our findings suggest that correlated insulators are favored when a moire flat band is spectrally isolated, and are consistent with a mean-field picture in which insulating states are established by breaking both spin and valley symmetries at 1/4 and 3/4 band filling and valley polarization alone at 1/2 band filling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 7", "Publication Year": 2019, "Volume": 123, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 197702, "DOI": "10.1103/PhysRevLett.123.197702", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.123.197702", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495073700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Toki, GFI; Samajdar, DP; Mushtaq, M; Rubel, MHK; Pandey, R; Madan, J; Mohammed, MKA; Islam, MR; Rahman, MF; Bencherif, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Toki, G. F. Ishraque; Samajdar, D. P.; Mushtaq, Muhammad; Rubel, M. H. K.; Pandey, Rahul; Madan, Jaya; Mohammed, Mustafa K. A.; Islam, Md. Rasidul; Rahman, Md. Ferdous; Bencherif, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Insights into the Coupled Optoelectronic and Photovoltaic Analysis of Lead-Free CsSnI3 Perovskite-Based Solar Cell Using DFT Calculations and SCAPS-1D Simulations", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "CsSnI3 is considered to be a viable alternativeto lead(Pb)-based perovskite solar cells (PSCs) due to its suitable optoelectronicproperties. The photovoltaic (PV) potential of CsSnI3 hasnot yet been fully explored due to its inherent difficulties in realizingdefect-free device construction owing to the nonoptimized alignmentof the electron transport layer (ETL), hole transport layer (HTL),efficient device architecture, and stability issues. In this work,initially, the structural, optical, and electronic properties of theCsSnI(3) perovskite absorber layer were evaluated using theCASTEP program within the framework of the density functional theory(DFT) approach. The band structure analysis revealed that CsSnI3 is a direct band gap semiconductor with a band gap of 0.95eV, whose band edges are dominated by Sn 5s/5p electrons After performingthe DFT analysis, we investigated the PV performance of a varietyof CsSnI3-based solar cell configurations utilizing a one-dimensionalsolar cell capacitance simulator (SCAPS-1D) with different competentETLs such as IGZO, WS2, CeO2, TiO2, ZnO, PCBM, and C-60. Simulation results revealed thatthe device architecture comprising ITO/ETL/CsSnI3/CuI/Auexhibited better photoconversion efficiency among more than 70 differentconfigurations. The effect of the variation in the absorber, ETL,and HTL thickness on PV performance was analyzed for the above-mentionedconfiguration thoroughly. Additionally, the impact of series and shuntresistance, operating temperature, capacitance, Mott-Schottky,generation, and recombination rate on the six superior configurationswere evaluated. The J-V characteristicsand the quantum efficiency plots for these devices are systematicallyinvestigated for in-depth analysis. Consequently, this extensive simulationwith validation results established the true potential of CsSnI3 absorber with suitable ETLs including ZnO, IGZO, WS2, PCBM, CeO2, and C-60 ETLs and CuI as HTL,paving a constructive research path for the photovoltaic industryto fabricate cost-effective, high-efficiency, and nontoxic CsSnI3 PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2023, "Volume": 8, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 22466, "End Page": 22485, "Article Number": null, "DOI": "10.1021/acsomega.3c00306", "DOI Link": "http://dx.doi.org/10.1021/acsomega.3c00306", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001006521300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, Y; Zhou, L; Ding, HH; Lewis, R; Liu, QY; Guo, J; Wang, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Y.; Zhou, L.; Ding, H. H.; Lewis, R.; Liu, Q. Y.; Guo, J.; Wang, W. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure evolution of railway pearlitic wheel steels under rolling-sliding contact loading", "Source Title": "TRIBOLOGY INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this work is to investigate the microstructure evolution of railway pearlitic wheel materials (ER7, CL60 and C-class) under a rolling-sliding contact loading. Firstly, microstructures of CL60 wheel steel at different depths from the strain-free matrix to the top surface were systematically investigated via laser scanning confocal microscope (LSCM), scanning electron microscopy (SEM), electron backscattered diffraction (EBSD), transmission electron microscopy (TEM) and X-ray diffraction (XRD). Secondly, the differences in microstructures of the top layers of those three types of wheel steels were explored. At last, the correlation between microstructure evolutions and their wear and rolling contact fatigue (RCF) behaviours was discussed. These information could provide a guide in development of premium railway wheel materials and choosing wheel materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 154, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106685, "DOI": "10.1016/j.triboint.2020.106685", "DOI Link": "http://dx.doi.org/10.1016/j.triboint.2020.106685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000596517100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vogt, K; Fradin, FY; Pearson, JE; Sebastian, T; Bader, SD; Hillebrands, B; Hoffmann, A; Schultheiss, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vogt, K.; Fradin, F. Y.; Pearson, J. E.; Sebastian, T.; Bader, S. D.; Hillebrands, B.; Hoffmann, A.; Schultheiss, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realization of a spin-wave multiplexer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent developments in the field of spin dynamics-like the interaction of charge and heat currents with magnons, the quasi-particles of spin waves-opens the perspective for novel information processing concepts and potential applications purely based on magnons without the need of charge transport. The challenges related to the realization of advanced concepts are the spin-wave transport in two-dimensional structures and the transfer of existing demonstrators to the micro-or even nulloscale. Here we present the experimental realization of a microstructured spin-wave multiplexer as a fundamental building block of a magnon-based logic. Our concept relies on the generation of local Oersted fields to control the magnetization configuration as well as the spin-wave dispersion relation to steer the spin-wave propagation in a Y-shaped structure. Thus, the present work illustrates unique features of magnonic transport as well as their possible utilization for potential technical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 335, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3727, "DOI": "10.1038/ncomms4727", "DOI Link": "http://dx.doi.org/10.1038/ncomms4727", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335223300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saito, Y; Yang, FY; Ge, JY; Liu, XX; Taniguchi, T; Watanabe, K; Li, JIA; Berg, E; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saito, Yu; Yang, Fangyuan; Ge, Jingyuan; Liu, Xiaoxue; Taniguchi, Takashi; Watanabe, Kenji; Li, J. I. A.; Berg, Erez; Young, Andrea F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isospin Pomeranchuk effect in twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In condensed-matter systems, higher temperatures typically disfavour ordered phases, leading to an upper critical temperature for magnetism, superconductivity and other phenomena. An exception is the Pomeranchuk effect in He-3, in which the liquid ground state freezes upon increasing the temperature(1), owing to the large entropy of the paramagnetic solid phase. Here we show that a similar mechanism describes the finite-temperature dynamics of spin and valley isospins in magic-angle twisted bilayer graphene(2). Notably, a resistivity peak appears at high temperatures near a superlattice filling factor of -1, despite no signs of a commensurate correlated phase appearing in the low-temperature limit. Tilted-field magnetotransport and thermodynamic measurements of the in-plane magnetic moment show that the resistivity peak is connected to a finite-field magnetic phase transition(3) at which the system develops finite isospin polarization. These data are suggestive of a Pomeranchuk-type mechanism, in which the entropy of disordered isospin moments in the ferromagnetic phase stabilizes the phase relative to an isospin-unpolarized Fermi liquid phase at higher temperatures. We find the entropy, in units of Boltzmann's constant, to be of the order of unity per unit cell area, with a measurable fraction that is suppressed by an in-plane magnetic field consistent with a contribution from disordered spins. In contrast to 3He, however, no discontinuities are observed in the thermodynamic quantities across this transition. Our findings imply a small isospin stiffness(4,5), with implications for the nature of finite-temperature electron transport(6-8), as well as for the mechanisms underlying isospin ordering and superconductivity(9,10) in twisted bilayer graphene and related systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2021, "Volume": 592, "Issue": 7853, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 220, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03409-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03409-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637887800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, ZB; Wu, PH; Wang, HL; Jiang, S; Huang, M; Lei, DG; Wu, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Zhibin; Wu, Pinghui; Wang, Hailun; Jiang, Shu; Huang, Meng; Lei, Dongge; Wu, Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multimode tunable terahertz absorber based on a quarter graphene disk structure", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this research work, in order to solve the unadjustability of traditional noble metal absorbers to meet the complex application requirements in the actual electromagnetic environment, we designed a simple tunable absorber based on graphene with tunable Fermi level. The performance of the proposed absorber is theoretically simulated by the finite difference time domain (FDTD) method. The proposed absorber has two perfect ab-sorption peaks with high efficiency of 99.51% and 99.548% in its working band (90-155 mu m). We have per-formed an in-depth analysis of the causes of perfect absorption and focused on the tunability of the absorber. The absorption frequency can be adjusted by controlling the relaxation time and Fermi level of graphene, and the same purpose can be achieved by changing the refractive index (relative dielectric constant) of the medium. In addition, we also explored the influence of the change of the top structure parameters on the absorption per-formance. The proposed absorber has the ability to adapt to different electromagnetic environments. In general, it can be flexibly regulated in practical applications, which will provide new possibilities for the development of many fields such as detection and communication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 48, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106420, "DOI": "10.1016/j.rinp.2023.106420", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2023.106420", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980940900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gupta, R; Xie, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gupta, Ritu; Xie, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticles in Daily Life: Applications, Toxicity and Regulations", "Source Title": "JOURNAL OF ENVIRONMENTAL PATHOLOGY TOXICOLOGY AND ONCOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At nulloscale. man-made materials may show unique properties that differ from bulk and dissolved counterparts. The unique properties of engineered nullomaterials not only impart critical advantages but also confer toxicity because of their unwanted interactions with different biological compartments and cellular processes. In this review, we discuss various entry routes of nullomaterials in the human body, their applications in daily life, and the mechanisms underlying their toxicity. We further explore the passage of nullomaterials into air, water, and soil ecosystems, resulting in diverse environmental impacts. Briefly, we probe the available strategies for risk assessment and risk management to assist in reducing the occupational risks of potentially hazardous engineered nullomaterials including the control banding (CB) approach. Moreover, we substantiate the need for uniform guidelines for systematic analysis of nullomaterial toxicity, in silico toxicological investigations, and obligation to ensure the safe disposal of nullowaste to reduce or eliminate untoward environmental and health impacts. At the end, we scrutinize global regulatory trends, hurdles, and efforts to develop better regulatory sciences in the field of nullomedicines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 37, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 209, "End Page": 230, "Article Number": null, "DOI": "10.1615/JEnvironPatholToxicolOncol.2018026009", "DOI Link": "http://dx.doi.org/10.1615/JEnvironPatholToxicolOncol.2018026009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Toxicology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443764100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sundararaman, R; Goddard, WA ; Arias, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sundararaman, Ravishankar; Goddard, William A., III; Arias, Tomas A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grand canonical electronic density-functional theory: Algorithms and applications to electrochemistry", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations combining density-functional theory and continuum solvation models enable realistic theoretical modeling and design of electrochemical systems. When a reaction proceeds in such systems, the number of electrons in the portion of the system treated quantum mechanically changes continuously, with a balancing charge appearing in the continuum electrolyte. A grand-canonical ensemble of electrons at a chemical potential set by the electrode potential is therefore the ideal description of such systems that directly mimics the experimental condition. We present two distinct algorithms: a self-consistent field method and a direct variational free energy minimization method using auxiliary Hamiltonians (GC-AuxH), to solve the Kohn-Sham equations of electronic density-functional theory directly in the grand canonical ensemble at fixed potential. Both methods substantially improve performance compared to a sequence of conventional fixed-number calculations targeting the desired potential, with the GC-AuxH method additionally exhibiting reliable and smooth exponential convergence of the grand free energy. Finally, we apply grand-canonical density-functional theory to the under-potential deposition of copper on platinum from chloride-containing electrolytes and show that chloride desorption, not partial copper monolayer formation, is responsible for the second voltammetric peak. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2017, "Volume": 146, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114104, "DOI": "10.1063/1.4978411", "DOI Link": "http://dx.doi.org/10.1063/1.4978411", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397313600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, DK; March, SD; Jones, AH; Shen, Y; Dadey, AA; Sun, KY; McArthur, JA; Skipper, AM; Xue, XJ; Guo, BT; Bai, JW; Bank, SR; Campbell, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Dekang; March, Stephen D.; Jones, Andrew H.; Shen, Yang; Dadey, Adam A.; Sun, Keye; McArthur, J. Andrew; Skipper, Alec M.; Xue, Xingjun; Guo, Bingtian; Bai, Junwu; Bank, Seth R.; Campbell, Joe C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photon-trapping-enhanced avalanche photodiodes for mid-infrared applications", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fast development of mid-wave infrared photonics has increased the demand for high-performance photodetectors that operate in this spectral range. However, the signal-to-noise ratio, regarded as a primary figure of merit for mid-wave infrared detection, is strongly limited by the high dark current in narrow-bandgap materials. Therefore, conventional mid-wave infrared photodetectors such as HgCdTe require cryogenic temperatures to avoid excessively high dark current. To address this challenge, we report an avalanche photodiode design using photon-trapping structures to enhance the quantum efficiency and minimize the absorber thickness to suppress the dark current. The device exhibits high quantum efficiency and dark current density that is nearly three orders of magnitude lower than that of the state-of-the-art HgCdTe avalanche photodiodes and nearly two orders lower than that of previously reported AlInAsSb avalanche photodiodes that operate at 2 mu m. Additionally, the bandwidth of these avalanche photodiodes reaches similar to 7 GHz, and the gain-bandwidth product is over 200 GHz; both are more than four times those of previously reported 2 mu m avalanche photodiodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 47, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 17, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 594, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01208-x", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01208-x", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000987898100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, L; Ding, SP; Gao, JH; Wu, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Liu; Ding, Shiping; Gao, Jinhua; Wu, Menghao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atypical Sliding and Moire Ferroelectricity in Pure Multilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most nonferroelectric two-dimensional materials can be endowed with so-called sliding ferroelectricity via nonequivalent homobilayer stacking, which is not applicable to monoelement systems like pure graphene bilayer with inversion symmetry at any sliding vector. Herein, we show first-principles evidence that multilayer graphene with N > 3 can all be ferroelectric, where the polarizations of polar states stem from the symmetry breaking in stacking configurations of across layer instead of adjacent layer, which are electrically switchable via interlayer sliding. The nonpolar states can also be electrically driven to polar states via sliding, and more diverse states with distinct polarizations will emerge in more layers. In contrast to the ferroelectric moire domains with opposite polarization directions in twisted bilayers reported previously, the moire pattern in some multilayer graphene systems (e.g., twisted monolayer-trilayer graphene) possess nonzero net polarizations with domains of the same direction separated by nonpolar regions, which can be electrically reversed upon interlayer sliding. The distinct moire bands of two polar states should facilitate electrical detection of such sliding moir ' e ferroelectricity during switching.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2023, "Volume": 131, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 96801, "DOI": "10.1103/PhysRevLett.131.096801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.096801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001127138800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Radhakrishnull, SS; Sebastian, A; Oberoi, A; Das, S; Das, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Radhakrishnull, Shiva Subbulakshmi; Sebastian, Amritanulld; Oberoi, Aaryan; Das, Sarbashis; Das, Saptarshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A biomimetic neural encoder for spiking neural network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spiking neural networks (SNNs) promise to bridge the gap between artificial neural networks (ANNs) and biological neural networks (BNNs) by exploiting biologically plausible neurons that offer faster inference, lower energy expenditure, and event-driven information processing capabilities. However, implementation of SNNs in future neuromorphic hardware requires hardware encoders analogous to the sensory neurons, which convert external/internal stimulus into spike trains based on specific neural algorithm along with inherent stochasticity. Unfortunately, conventional solid-state transducers are inadequate for this purpose necessitating the development of neural encoders to serve the growing need of neuromorphic computing. Here, we demonstrate a biomimetic device based on a dual gated MoS2 field effect transistor (FET) capable of encoding analog signals into stochastic spike trains following various neural encoding algorithms such as rate-based encoding, spike timing-based encoding, and spike count-based encoding. Two important aspects of neural encoding, namely, dynamic range and encoding precision are also captured in our demonstration. Furthermore, the encoding energy was found to be as frugal as approximate to 1-5pJ/spike. Finally, we show fast (approximate to 200 timesteps) encoding of the MNIST data set using our biomimetic device followed by more than 91% accurate inference using a trained SNN. The implementation of spiking neural network in future neuromorphic hardware requires hardware encoder analogous to the sensory neurons. The authors show a biomimetic dual-gated MoS2 field effect transistor capable of encoding analog signals into stochastic spike trains at energy cost of 1-5pJ/spike.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 9", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2143, "DOI": "10.1038/s41467-021-22332-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22332-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683544600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, HT; Lu, HC; Guo, ZX; Li, A; Wu, PC; Li, J; Xie, WR; Sun, ZM; Li, P; Damas, H; Friedel, AM; Migot, S; Ghanbaja, J; Moreau, L; Fagot-Revurat, Y; Petit-Watelot, S; Hauet, T; Robertson, J; Mangin, S; Zhao, WS; Nie, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Hangtian; Lu, Haichang; Guo, Zongxia; Li, Ang; Wu, Peichen; Li, Jing; Xie, Weiran; Sun, Zhimei; Li, Peng; Damas, Heloise; Friedel, Anna Maria; Migot, Sylvie; Ghanbaja, Jaafar; Moreau, Luc; Fagot-Revurat, Yannick; Petit-Watelot, Sebastien; Hauet, Thomas; Robertson, John; Mangin, Stephane; Zhao, Weisheng; Nie, Tianxiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial engineering of ferromagnetism in wafer-scale van derWaals Fe4GeTe2 far above room temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite recent advances in exfoliated vdW ferromagnets, the widespread application of 2D magnetism requires a Curie temperature (T-c) above room temperature as well as a stable and controllablemagnetic anisotropy. Here we demonstrate a large-scale iron-based vdW material Fe4GeTe2 with the Tc reaching similar to 530 K. We confirmed the high-temperature ferromagnetism by multiple characterizations. Theoretical calculations suggested that the interface-induced right shift of the localized states for unpaired Fe d electrons is the reason for the enhanced Tc, which was confirmed by ultraviolet photoelectron spectroscopy. Moreover, by precisely tailoring Fe concentration we achieved arbitrary control of magnetic anisotropy between out-of-plane and in-plane without inducing any phase disorders. Our finding sheds light on the high potential of Fe4GeTe2 in spintronics, which may open opportunities for room-temperature application of all-vdW spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2483, "DOI": "10.1038/s41467-023-37917-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37917-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022903400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Madenci, E; Barut, A; Futch, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Madenci, Erdogan; Barut, Atila; Futch, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Peridynamic differential operator and its applications", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The nonlocal peridynamic theory has been proven extremely robust for predicting damage nucleation and propagation in materials under complex loading conditions. Its equations of motion, originally derived based on the principle of virtual work, do not contain any spatial derivatives of the displacement components. Thus, their solution does not require special treatment in the presence of geometric and material discontinuities. This study presents an alternative approach to derive the peridynamic equations of motion by recasting Navier's displacement equilibrium equations into their nonlocal form by introducing the peridynamic differential operator. Also, this operator permits the nonlocal form of expressions for the determination of the stress and strain components. The capability of this differential operator is demonstrated by constructing solutions to ordinary, partial differential equations and derivatives of scattered data, as well as image compression and recovery without employing any special filtering and regularization techniques. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2016, "Volume": 304, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 408, "End Page": 451, "Article Number": null, "DOI": "10.1016/j.cma.2016.02.028", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.02.028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374506600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, KK; Liu, Q; Yang, DW; Liang, YC; Sui, LZ; Wei, JY; Xue, GW; Zhao, WB; Wu, XY; Dong, L; Shan, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Kai-Kai; Liu, Qian; Yang, Dong-Wen; Liang, Ya-Chuan; Sui, Lai-Zhi; Wei, Jian-Yong; Xue, Guo-Wei; Zhao, Wen-Bo; Wu, Xue-Ying; Dong, Lin; Shan, Chong-Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water-induced MAPbBr3@PbBr(OH) with enhanced luminescence and stability", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite LEDs: extending lifetimes with a splash of water Inexpensive crystals useful for applications including display devices can be manufactured with exceptional environmental stability by following a new synthetic technique. Lead halide perovskites are materials that emit light with a range of colors, but also suffer from poor moisture stability. Kai-Kai Liu, Lin Dong, Chong-Xin Shan from China's Zhengzhou University and colleagues now report that adding a dose of water to lead halide perovskites enables them to emit bright fluorescent light, even when submerged underwater for more than a year. The team's experiments revealed that controlled hydration of the perovskite's outer surface helped remove defects that decrease light output, as well as protected against further incursions by air and water molecules. Successful fabrication of the hydrated crystals as phosphors within light-emitting devices (LEDs) indicates their potential for industrial purposes. Poor stability has long been one of the key issues that hinder the practical applications of lead-based halide perovskites. In this paper, the photoluminescence (PL) quantum yield (QY) of bromide-based perovskites can be increased from 2.5% to 71.54% by introducing water, and the PL QY of a sample in aqueous solution decreases minimally over 1 year. The enhanced stability and PL QY can be attributed to the water-induced methylamino lead bromide perovskite (MAPbBr(3))@PbBr(OH). We note that this strategy is universal to MAPbBr(3), formamidine lead bromide perovskite (FAPbBr(3)), inorganic lead bromide perovskite (CsPbBr3), etc. Light-emitting devices (LEDs) are fabricated by using the as-prepared perovskite as phosphors on a 365 nm UV chip. The luminullce intensity of the LED is 9549 cd/m(2) when the driven current is 200 mA, and blemishes on the surface of glass are clearly observed under the illumination of the LEDs. This work provides a new strategy for highly stable and efficient perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 44, "DOI": "10.1038/s41377-020-0283-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0283-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522129100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leonov, AO; Mostovoy, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leonov, A. O.; Mostovoy, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiply periodic states and isolated skyrmions in an anisotropic frustrated magnet", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiply periodic states appear in a wide variety of physical contexts, such as the Rayleigh-Benard convection, Faraday waves, liquid crystals and skyrmion crystals recently observed in chiral magnets. Here we study the phase diagram of an anisotropic frustrated magnet which contains five different multiply periodic states including the skyrmion crystal. We clarify the mechanism for stabilization of these states and discuss how they can be observed in magnetic resonullce and electric polarization measurements. We also find stable isolated skyrmions with topological charge 1 and 2. Their spin structure, interactions and dynamics are more complex than those in chiral magnets. In particular, magnetic resonullce in the skyrmion crystal should be accompanied by oscillations of the electric polarization with a frequency depending on the amplitude of the a.c. magnetic field. These results show that skyrmion materials with rich physical properties can be found among frustrated magnets. We formulate rules to help the search.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 446, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8275, "DOI": "10.1038/ncomms9275", "DOI Link": "http://dx.doi.org/10.1038/ncomms9275", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363019000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, TW; Semperlotti, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ting-Wei; Semperlotti, Fabio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Acoustic Valley-Hall Edge States in Reconfigurable Phononic Elastic Waveguides", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate the occurrence of acoustic topological edge states in a 2D phononic elastic waveguide due to a phenomenon that is the acoustic analog of the quantum valley Hall effect. We show that a topological transition takes place between two lattices having broken space-inversion symmetry due to the application of a tunable strain field. This condition leads to the formation of gapless edge states at the domain walls, as further illustrated by the analysis of the bulk-edge correspondence and of the associated topological invariants. Interestingly, topological edge states can also be triggered at the boundary of a single domain, when boundary conditions are properly selected. We also show that the static modulation of the strain field allows us to tune the response of the material between the different supported edge states. Although time-reversal symmetry is still intact in this material system, the edge states are topologically protected when intervalley mixing is either weak or negligible. This characteristic enables selective valley injection, which is achieved via synchronized source strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 226, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2018, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14001, "DOI": "10.1103/PhysRevApplied.9.014001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.9.014001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419104200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Homann, G; Stolz, L; Nair, J; Laskovic, IC; Winter, M; Kasnatscheew, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Homann, Gerrit; Stolz, Lukas; Nair, Jijeesh; Laskovic, Isidora Cekic; Winter, Martin; Kasnatscheew, Johannes", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(Ethylene Oxide)-based Electrolyte for Solid-State-Lithium-Batteries with High Voltage Positive Electrodes: Evaluating the Role of Electrolyte Oxidation in Rapid Cell Failure", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs) typically reveal a sudden failure in Li metal cells particularly with high energy density/voltage positive electrodes, e.g. LiNi0.6Mn0.2Co0.2O2 (NMC622), which is visible in an arbitrary, time - and voltage independent, voltage noise during charge. A relation with SPE oxidation was evaluated, for validity reasons on different active materials in potentiodynamic and galvanostatic experiments. The results indicate an exponential current increase and a potential plateau at 4.6 V vs. Li vertical bar Li+, respectively, demonstrating that the main oxidation onset of the SPE is above the used working potential of NMC622 being < 4.3V vs. Li vertical bar Li+. Obviously, the SPE vertical bar NMC622 interface is unlikely to be the primary source of the observed sudden failure indicated by the voltage noise. Instead, our experiments indicate that the Li vertical bar SPE interface, and in particular, Li dendrite formation and penetration through the SPE membrane is the main source. This could be simply proven by increasing the SPE membrane thickness or by exchanging the Li metal negative electrode by graphite, which both revealed voltage noise-free operation. The effect of membrane thickness is also valid with LiFePO4 electrodes. In summary, it is the cell set-up (PEO thickness, negative electrode), which is crucial for the voltage-noise associated failure, and counterintuitively not a high potential of the positive electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4390, "DOI": "10.1038/s41598-020-61373-9", "DOI Link": "http://dx.doi.org/10.1038/s41598-020-61373-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563354500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, Y; Li, B; Liu, XA; Shen, HB; Song, Y; Song, JJ; Yan, ZJ; Yan, XH; Chong, YH; Yao, RY; Wang, SJ; Li, LS; Fan, FJ; Du, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Yan; Li, Bo; Liu, Xiaonull; Shen, Huaibin; Song, Yang; Song, Jiaojiao; Yan, Zhijie; Yan, Xiaohan; Chong, Yihua; Yao, Ruyun; Wang, Shujie; Li, Lin Song; Fan, Fengjia; Du, Zuliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimizing heat generation in quantum dot light-emitting diodes by increasing quasi-Fermi-level splitting", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Minimizing heat accumulation is essential to prolonging the operational lifetime of quantum dot light-emitting diodes (QD-LEDs). Reducing heat generation at the source is the ideal solution, which requires high brightness and quantum efficiency at low driving voltages. Here we propose to enhance the brightness of QD-LEDs at low driving voltages by using a monolayer of large QDs to reduce the packing number in the emitting layer. This strategy allows us to achieve a higher charge population per QD for a given number of charges without charge leakage, enabling enhanced quasi-Fermi-level splitting and brightness at low driving voltage. Due to the minimized heat generation, these LEDs show a high power conversion efficiency of 23% and a T-95 operation lifetime (the time for the luminullce to decrease to 95% of the initial value) of more than 48,000 h at 1,000 cd m(-2). Quantum dot LED brightness can be enhanced at low driving voltage using a monolayer of large quantum dots to reduce the packing number in the emitting layer and minimize heat generation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 18, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1168, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-023-01441-z", "DOI Link": "http://dx.doi.org/10.1038/s41565-023-01441-z", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032687300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leonov, AO; Monchesky, TL; Romming, N; Kubetzka, A; Bogdanov, AN; Wiesendanger, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Leonov, A. O.; Monchesky, T. L.; Romming, N.; Kubetzka, A.; Bogdanov, A. N.; Wiesendanger, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The properties of isolated chiral skyrmions in thin magnetic films", "Source Title": "NEW JOURNAL OF PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Axisymmetric solitonic states (chiral skyrmions) were first predicted theoretically more than two decades ago. However, until recently they have been observed in a form of skyrmionic condensates (hexagonal lattices and other mesophases). In this paper we report experimental and theoretical investigations of isolated chiral skyrmions discovered in PdFe/Ir(111) bilayers two years ago by Romming et al (2013 Science 341 636). The results of spin-polarized scanning tunneling microscopy analyzed within the continuum and discrete models provide a consistent description of isolated skyrmions in thin layers. The existence region of chiral skyrmions is restricted by strip-out instabilities at low fields and a collapse at high fields. We demonstrate that the same equations describe axisymmetric localized states in all condensed matter systems with broken mirror symmetry, and thus our findings establish basic properties of isolated skyrmions common for chiral liquid crystals, different classes of noncentrosymmetric magnets, ferroelectrics, and multiferroics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2016, "Volume": 18, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 65003, "DOI": "10.1088/1367-2630/18/6/065003", "DOI Link": "http://dx.doi.org/10.1088/1367-2630/18/6/065003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379288300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, MZ; Wu, ZF; Hu, JX; Cai, XB; Li, E; An, LH; Feng, XM; Ye, ZQ; Lin, N; Law, KT; Wang, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Meizhen; Wu, Zefei; Hu, Jinxin; Cai, Xiangbin; Li, En; An, Liheng; Feng, Xuemeng; Ye, Ziqing; Lin, Nian; Law, Kam Tuen; Wang, Ning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant nonlinear Hall effect in twisted bilayer WSe2", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "They report a giant nonlinear Hall generation efficiency of 1000 V-1 in small-angle-twisted bilayer WSe2, which is two orders of magnitude higher than previous records, and interpret the result by the correlation induced continuous Mott transition effect. The recently discovered nonlinear Hall effect (NHE) in a few non-interacting systems provides a novel mechanism for generating second-harmonic electrical Hall signals under time-reversal-symmetric conditions. Here, we introduce a new approach to engineering an NHE by using twisted moire structures. We found that the twisted WSe2 bilayer exhibited an NHE when the Fermi level was tuned to the moire flat bands. When the first moire band was half-filled, the nonlinear Hall signal exhibited a sharp peak with a generation efficiency that was at least two orders of magnitude greater than those obtained in previous experiments. We discuss the possible origins of the diverging generation efficiency in twisted WSe2 based on resistivity measurements, such as moire-interface-induced correlation effects and mass-diverging-type continuous Mott transition. This study demonstrates not only how interaction effects can combine with Berry curvature dipoles to produce novel quantum phenomena, but also the potential of NHE measurements as a new tool for studying quantum criticality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2023, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwac232", "DOI": "10.1093/nsr/nwac232", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac232", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000985122000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zong, KQ; Wang, ZC; Li, JW; He, Q; Li, YH; Becker, H; Zhang, W; Hu, ZC; He, T; Cao, KA; She, ZB; Wu, X; Xiao, L; Liu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zong, Keqing; Wang, Zaicong; Li, Jiawei; He, Qi; Li, Yiheng; Becker, Harry; Zhang, Wen; Hu, Zhaochu; He, Tao; Cao, Kenull; She, Zhenbing; Wu, Xiang; Xiao, Long; Liu, Yongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bulk compositions of the Chang'E-5 lunar soil: Insights into chemical homogeneity, exotic addition, and origin of landing site basalts", "Source Title": "GEOCHIMICA ET COSMOCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lunar soil is a fine mixture of local rocks and exotic components. The bulk-rock chemical composition of the newly returned Chang'E-5 (CE-5) lunar soil was studied to understand its chemical homogeneity, exotic additions, and origin of landing site basalts. Concentrations of 48 major and trace elements, including many low-concentration volatile and siderophile elements, of two batches of the scooped CE-5 soil samples were simultaneously obtained by inductively coupled plasma mass spectrometry (ICP-MS) with minimal sample consumption. Their major and trace elemental compositions (except for Ni) are uniform at milligram levels (2-4 mg), matching measured compositions of basaltic glasses and estimates based on mineral modal abundances of basaltic fragments. This result indicates that the exotic highland and KREEP (K, rare earth elements, and P-rich) materials are very low (< 5%) and the bulk chemical composition (except for Ni) of the CE-5 soil can be used to represent the underlying mare basalt. The elevated Ni concentrations reflect the addition of about 1 wt% meteoritic materials, which would not influence the other bulk composition except for some highly siderophile trace elements such as Ir. The CE-5 soil, which is overall the same as the underlying basalt in composition, displays low Mg# (34), high FeO (22.7 wt%), intermediate TiO2 (5.12 wt%), and high Th (5.14 lg/g) concentrations. The composition is distinct from basalts and soils returned by the Apollo and Luna missions, however, the depletion of volatile or siderophile elements such as K, Rb, Mo, and W in their mantle sources is comparable. The incompatible lithophile trace element concentrations (e.g., Ba, Rb, Th, U, Nb, Ta, Zr, Hf, and REE) of the CE-5 basalts are moderately high and their pattern mimics high-K KREEP. The pattern of these trace elements with K, Th, U, Nb, and Ta anomalies of the CE-5 basalts cannot be explained by the partial melting and crystallization of olivine, pyroxene, and plagioclase. Thus, the mantle source of the CE-5 landing site mare basalt could have contained KREEP components, likely as trapped interstitial melts. To reconcile these observations with the initial unradiogenic Sr and radiogenic Nd isotopic compositions of the CE-5 basalts, clinopyroxene characterized by low Rb/Sr and high Sm/Nd ratios could be one of the main minerals in the KREEP-bearing mantle source. Consequently, we propose that the CE-5 landing site mare basalts very likely originated from partial melting of a shallow and clinopyroxene-rich (relative to olivine and orthopyroxene) upper mantle cumulate with a small fraction (about 1-1.5 %) of KREEP-like materials. (c) 2022 The Author(s). Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2022, "Volume": 335, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": 296, "Article Number": null, "DOI": "10.1016/j.gca.2022.06.037", "DOI Link": "http://dx.doi.org/10.1016/j.gca.2022.06.037", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000862791900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, MH; Hanzic, L; Ho, JCM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Mianheng; Hanzic, Lucija; Ho, Johnny C. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fillers to improve passing ability of concrete", "Source Title": "STRUCTURAL CONCRETE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concrete possessing high-passing ability needs to be flowable and cohesive. Hence, passing ability cannot be improved by solely adding superplasticizer, which increases both flowability and segregation of concrete simultaneously. Decreasing the maximum size of aggregates so that concrete segregates at lower cohesiveness is a possible but undesirable way as it narrows the aggregates' grading and decrease dimensional stability of concrete. With the same maximum size of aggregates, passing ability can be improved by raising the concurrent flowability-segregation envelope of concrete. In this paper, fly ash and silica fume (cementitious fillers) and limestone (inert filler) were selected to replace cement partially and subsequently the passing ability of concrete was studied. From the results, it was evident that when either type of fillers were used, the passing ability and maximum limits of flowability and segregation achieved simultaneously increase. It is because these fillers are finer than cement that provides better filling effect to increase packing density and excess water leading to better flowability. Concurrently, the cohesiveness of concrete also increases as the content of fine particles increases. These allow concrete to hold the coarse aggregates more firmly when passing through narrow gaps, after which the concrete will keep flowing rapidly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 20, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 185, "End Page": 197, "Article Number": null, "DOI": "10.1002/suco.201800047", "DOI Link": "http://dx.doi.org/10.1002/suco.201800047", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459967500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, SD; Hu, BK; Li, ZX; Yuan, Y; Gong, C; Ning, ZY; Chau, C; Yang, SX; Zhang, SM; Pi, LQ; Tang, YT; Yue, JL; Marrow, TJ; Gao, XW; Bruce, PG; Robertson, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Shengda D.; Hu, Bingkun; Li, Zixuan; Yuan, Yi; Gong, Chen; Ning, Ziyang; Chau, Chloe; Yang, Sixie; Zhang, Shengming; Pi, Liquan; Tang, Yuanbo T.; Yue, Jili; Marrow, T. James; Gao, Xiangwen; Bruce, Peter G.; Robertson, Alex W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Decoupling, quantifying, and restoring aging-induced Zn-anode losses in rechargeable aqueous zinc batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc batteries offer low cost, safety, and good cycling capacity, largely due to the water-compatible Zn-metal anode. However, Zn anodes corrode in aqueous electrolytes. While such corrosion is well known, distinguishing the relative importance of corrosion contributions toward anode capacity loss remains less understood. Here, by systematically cycling Zn anodes with controlled loading and under different aging conditions, we suc-cessfully decouple and quantify the aging-induced contributions to-ward anode degradation in mildly acidic aqueous electrolytes. While some losses occur due to the irreversible consumption of Zn into corrosion by-products, we demonstrate that the bigger contributor to this efficiency loss (over 80%) is the physical screening effect of evolved gases, preventing the reversible dissolution of deposited Zn. Understanding the crucial role of evolved gas during cell aging, and how it can accumulate and effectively passivate large sections of the battery anode, will have important implications in the develop-ment of rechargeable aqueous zinc batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 90, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 366, "End Page": 379, "Article Number": null, "DOI": "10.1016/j.joule.2023.01.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.01.010", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000965202400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, L; Zhang, R; Cho, E; Li, HX; Coropceanu, V; Brédas, JL; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Li; Zhang, Rui; Cho, Eunkyung; Li, Hongxiang; Coropceanu, Veaceslav; Bredas, Jean-Luc; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sensitive near-infrared circularly polarized light detection via non-fullerene acceptor blends", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Circularly polarized light (CPL) is widely used for various applications in sensing and imaging(1-3). An ongoing challenge is to realize high-quality CPL detection using chiral organic semiconductors, especially in the near-infrared (NIR) region(4). Chiral molecules tend to rely on twisted stereogenic moieties; however, conventional approaches to reduce the bandgap of organic semiconductors are based on the use of co-planar backbones that commonly lead to molecular symmetries preventing chirality. Here we report a widely applicable strategy to directly induce chiroptical activity in planar non-fullerene acceptors(5-7), which are widely used for high-performance organic photovoltaics and provide a wealth of opportunities to fill the spectral gap of CPL detection in the NIR regime. We demonstrate proof-of-concept circularly polarized organic photodiodes using chiroptically active non-fullerene acceptor blends, which exhibit strong circular dichroism and hence great sensitivity to CPL in the NIR region. Importantly, this strategy is found to be effective in a wide series of state-of-the-art non-fullerene acceptor families including ITIC5, o-IDTBR6 and Y6 analogues(7), which substantially broadens the range of materials applicable to NIR CPL detection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 17, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 649, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01230-z", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01230-z", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004523900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giansante, C; Infante, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giansante, Carlo; Infante, Ivan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Traps in Colloidal Quantum Dots: A Combined Experimental and Theoretical Perspective", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface traps are ubiquitous to nulloscopic semiconductor materials. Understanding their atomistic origin and manipulating them chemically have capital importance to design defect-free colloidal quantum dots and make a leap forward in the development of efficient optoelectronic devices. Recent advances in computing power established computational chemistry as a powerful tool to describe accurately complex chemical species and nowadays it became conceivable to model colloidal quantum dots with realistic sizes and shapes. In this Perspective, we combine the knowledge gathered in recent experimental findings with the computation of quantum dot electronic structures. We analyze three different systems: namely, CdSe, PbS, and CsPbI3 as benchmark semiconductor nullo crystals showing how different types of trap states can form at their surface. In addition, we suggest experimental healing of such traps according to their chemical origin and nullocrystal composition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 291, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2017, "Volume": 8, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5209, "End Page": 5215, "Article Number": null, "DOI": "10.1021/acs.jpclett.7b02193", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.7b02193", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413798300038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Midya, R; Wang, ZR; Asapu, S; Zhang, XM; Rao, MY; Song, WH; Zhuo, Y; Upadhyay, N; Xia, QF; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Midya, Rivu; Wang, Zhongrui; Asapu, Shiva; Zhang, Xumeng; Rao, Mingyi; Song, Wenhao; Zhuo, Ye; Upadhyay, Navnidhi; Xia, Qiangfei; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reservoir Computing Using Diffusive Memristors", "Source Title": "ADVANCED INTELLIGENT SYSTEMS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reservoir computing (RC) is a framework that can extract features from a temporal input into a higher-dimension feature space. The reservoir is followed by a readout layer that can analyze the extracted features to accomplish tasks such as inference and classification. RC systems inherently exhibit an advantage, since the training is only performed at the readout layer, and therefore they are able to compute complicated temporal data with a low training cost. Herein, a physical reservoir computing system using diffusive memristor-based reservoir and drift memristor-based readout layer is experimentally implemented. The rich nonlinear dynamic behavior exhibited by a diffusive memristor due to Ag migration and the robust in situ training of drift memristor arrays makes the combined system ideal for temporal pattern classification. It is then demonstrated experimentally that the RC system can successfully identify handwritten digits from the Modified National Institute of Standards and Technology (MNIST) dataset, achieving an accuracy of 83%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 1, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900084, "DOI": "10.1002/aisy.201900084", "DOI Link": "http://dx.doi.org/10.1002/aisy.201900084", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Automation & Control Systems; Computer Science; Robotics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000675636200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Harris, NC; Ma, YJ; Mower, J; Baehr-Jones, T; Englund, D; Hochberg, M; Galland, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Harris, Nicholas C.; Ma, Yangjin; Mower, Jacob; Baehr-Jones, Tom; Englund, Dirk; Hochberg, Michael; Galland, Christophe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient, compact and low loss thermo-optic phase shifter in silicon", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We design a resistive heater optimized for efficient and low-loss optical phase modulation in a silicon-on-insulator (SOI) waveguide and characterize the fabricated devices. Modulation is achieved by flowing current perpendicular to a new ridge waveguide geometry. The resistance profile is engineered using different dopant concentrations to obtain localized heat generation and maximize the overlap between the optical mode and the high temperature regions of the structure, while simultaneously minimizing optical loss due to free-carrier absorption. A 61.6 m m long phase shifter was fabricated in a CMOS process with oxide cladding and two metal layers. The device features a phase-shifting efficiency of 24.77 +/- 0.43 mW/pi and a -3 dB modulation bandwidth of 130.0 +/- 5.59 kHz; the insertion loss measured for 21 devices across an 8-inch wafer was only 0.23 +/- 0.13 dB. Considering the prospect of densely integrated photonic circuits, we also quantify the separation necessary to isolate thermo-optic devices in the standard 220 nm SOI platform. (C) 2014 Optical Society of America", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 5", "Publication Year": 2014, "Volume": 22, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10487, "End Page": 10493, "Article Number": null, "DOI": "10.1364/OE.22.010487", "DOI Link": "http://dx.doi.org/10.1364/OE.22.010487", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000335905300078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, ZB; Song, F; Wang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Zhongbo; Song, Fei; Wang, Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Majorana Corner Modes in a High-Temperature Platform", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce two-dimensional topological insulators in proximity to high-temperature cuprate or iron-based superconductors as high-temperature platforms of Majorana Kramers pairs of zero modes. The proximity-induced pairing at the helical edge state of the topological insulator serves as a Dirac mass, whose sign changes at the sample corner because of the pairing symmetry of high-T-c superconductors. This sign changing naturally creates at each corner a pair of Majorana zero modes protected by time-reversal symmetry. Conceptually, this is a topologically trivial superconductor-based approach for Majorana zero modes. We provide quantitative criteria and suggest candidate materials for this proposal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2018, "Volume": 121, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 96803, "DOI": "10.1103/PhysRevLett.121.096803", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.096803", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443146700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, Y; Wu, XX; Ortiz, BR; Ju, SL; Han, XL; Ma, JZ; Plumb, NC; Radovic, M; Thomale, R; Wilson, SD; Schnyder, AP; Shi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yong; Wu, Xianxin; Ortiz, Brenden R.; Ju, Sailong; Han, Xinloong; Ma, Junzhang; Plumb, Nicholas C.; Radovic, Milan; Thomale, Ronny; Wilson, Stephen D.; Schnyder, Andreas P.; Shi, Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rich nature of Van Hove singularities in Kagome superconductor CsV3Sb5", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predictions suggest enhanced correlation effect due to multiple van Hove singularities (VHS) in the vicinity of the Fermi level in the recently discovered AV(3)Sb(5) kagome metals. Here the authors identify three VHSs close to the Fermi level with diverse sublattice characters in CsV3Sb5, and one of them shows flat dispersion suggesting the higher-order nature. The recently discovered layered kagome metals AV(3)Sb(5) (A = K, Rb, Cs) exhibit diverse correlated phenomena, which are intertwined with a topological electronic structure with multiple van Hove singularities (VHSs) in the vicinity of the Fermi level. As the VHSs with their large density of states enhance correlation effects, it is of crucial importance to determine their nature and properties. Here, we combine polarization-dependent angle-resolved photoemission spectroscopy with density functional theory to directly reveal the sublattice properties of 3d-orbital VHSs in CsV3Sb5. Four VHSs are identified around the M point and three of them are close to the Fermi level, with two having sublattice-pure and one sublattice-mixed nature. Remarkably, the VHS just below the Fermi level displays an extremely flat dispersion along MK, establishing the experimental discovery of higher-order VHS. The characteristic intensity modulation of Dirac cones around K further demonstrates the sublattice interference embedded in the kagome Fermiology. The crucial insights into the electronic structure, revealed by our work, provide a solid starting point for the understanding of the intriguing correlation phenomena in the kagome metals AV(3)Sb(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2220, "DOI": "10.1038/s41467-022-29828-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29828-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787388900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carrara, P; Ambati, M; Alessi, R; De Lorenzis, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carrara, P.; Ambati, M.; Alessi, R.; De Lorenzis, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A framework to model the fatigue behavior of brittle materials based on a variational phase-field approach", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel variational framework to model the fatigue behavior of brittle materials based on a phase-field approach to fracture is presented. The standard regularized free energy functional is modified introducing a fatigue degradation function that effectively reduces the fracture toughness as a proper history variable accumulates. This macroscopic approach allows to reproduce the main known features of fatigue crack growth in brittle materials. Numerical experiments show that the Wohler curve, the crack growth rate curve and the Paris law are naturally recovered, while the approximate Palmgren-Miner criterion and the monotonic loading condition are obtained as special cases. (C) 2019 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 1", "Publication Year": 2020, "Volume": 361, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112731, "DOI": "10.1016/j.cma.2019.112731", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2019.112731", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508937500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, SY; Belopolski, I; Sanchez, DS; Zhang, CL; Chang, GQ; Guo, C; Bian, G; Yuan, ZJ; Lu, H; Chang, TR; Shibayev, PP; Prokopovych, ML; Alidoust, N; Zheng, H; Lee, CC; Huang, SM; Sankar, R; Chou, FC; Hsu, CH; Jeng, HT; Bansil, A; Neupert, T; Strocov, VN; Lin, H; Jia, S; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Su-Yang; Belopolski, Ilya; Sanchez, Daniel S.; Zhang, Chenglong; Chang, Guoqing; Guo, Cheng; Bian, Guang; Yuan, Zhujun; Lu, Hong; Chang, Tay-Rong; Shibayev, Pavel P.; Prokopovych, Mykhailo L.; Alidoust, Nasser; Zheng, Hao; Lee, Chi-Cheng; Huang, Shin-Ming; Sankar, Raman; Chou, Fangcheng; Hsu, Chuang-Han; Jeng, Horng-Tay; Bansil, Arun; Neupert, Titus; Strocov, Vladimir N.; Lin, Hsin; Jia, Shuang; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental discovery of a topological Weyl semimetal state in TaP", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are expected to open up new horizons in physics and materials science because they provide the first realization of Weyl fermions and exhibit protected Fermi arc surface states. However, they had been found to be extremely rare in nature. Recently, a family of compounds, consisting of tantalum arsenide, tantalum phosphide (TaP), niobium arsenide, and niobium phosphide, was predicted as a Weyl semimetal candidates. We experimentally realize a Weyl semimetal state in TaP. Using photoemission spectroscopy, we directly observe the Weyl fermion cones and nodes in the bulk, and the Fermi arcs on the surface. Moreover, we find that the surface states show an unexpectedly rich structure, including both topological Fermi arcs and several topologically trivial closed contours in the vicinity of the Weyl points, which provides a promising platform to study the interplay between topological and trivial surface states on a Weyl semimetal's surface. We directly demonstrate the bulk-boundary correspondence and establish the topologically nontrivial nature of the Weyl semimetal state in TaP, by resolving the net number of chiral edge modes on a closed path that encloses the Weyl node. This also provides, for the first time, an experimentally practical approach to demonstrating a bulk Weyl fermion from a surface state dispersion measured in photoemission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 390, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 1, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501092", "DOI": "10.1126/sciadv.1501092", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501092", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216599300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Radulescu, DM; Neacsu, IA; Grumezescu, AM; Andronescu, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Radulescu, Denisa-Maria; Neacsu, Ionela Andreea; Grumezescu, Alexandru-Mihai; Andronescu, Ecaterina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New Insights of Scaffolds Based on Hydrogels in Tissue Engineering", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, biomaterials development and characterization for new applications in regenerative medicine or controlled release represent one of the biggest challenges. Tissue engineering is one of the most intensively studied domain where hydrogels are considered optimum applications in the biomedical field. The delicate nature of hydrogels and their low mechanical strength limit their exploitation in tissue engineering. Hence, developing new, stronger, and more stable hydrogels with increased biocompatibility, is essential. However, both natural and synthetic polymers possess many limitations. Hydrogels based on natural polymers offer particularly high biocompatibility and biodegradability, low immunogenicity, excellent cytocompatibility, variable, and controllable solubility. At the same time, they have poor mechanical properties, high production costs, and low reproducibility. Synthetic polymers come to their aid through superior mechanical strength, high reproducibility, reduced costs, and the ability to regulate their composition to improve processes such as hydrolysis or biodegradation over variable periods. The development of hydrogels based on mixtures of synthetic and natural polymers can lead to the optimization of their properties to obtain ideal scaffolds. Also, incorporating different nulloparticles can improve the hydrogel's stability and obtain several biological effects. In this regard, essential oils and drug molecules facilitate the desired biological effect or even produce a synergistic effect. This study's main purpose is to establish the main properties needed to develop sustainable polymeric scaffolds. These scaffolds can be applied in tissue engineering to improve the tissue regeneration process without producing other side effects to the environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 100, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 14, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 799, "DOI": "10.3390/polym14040799", "DOI Link": "http://dx.doi.org/10.3390/polym14040799", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000765172900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chanussot, L; Das, A; Goyal, S; Lavril, T; Shuaibi, M; Riviere, M; Tran, K; Heras-Domingo, J; Ho, C; Hu, WH; Palizhati, A; Sriram, A; Wood, B; Yoon, J; Parikh, D; Zitnick, CL; Ulissi, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chanussot, Lowik; Das, Abhishek; Goyal, Siddharth; Lavril, Thibaut; Shuaibi, Muhammed; Riviere, Morgane; Tran, Kevin; Heras-Domingo, Javier; Ho, Caleb; Hu, Weihua; Palizhati, Aini; Sriram, Anuroop; Wood, Brandon; Yoon, Junwoong; Parikh, Devi; Zitnick, C. Lawrence; Ulissi, Zachary", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Open Catalyst 2020 (OC20) Dataset and Community Challenges", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Catalyst discovery and optimization is key to solving many societal and energy challenges including solar fuel synthesis, long-term energy storage, and renewable fertilizer production. Despite considerable effort by the catalysis community to apply machine learning models to the computational catalyst discovery process, it remains an open challenge to build models that can generalize across both elemental compositions of surfaces and adsorbate identity/configurations, perhaps because datasets have been smaller in catalysis than in related fields. To address this, we developed the OC20 dataset, consisting of 1,281,040 density functional theory (DFT) relaxations (similar to 264,890,000 single-point evaluations) across a wide swath of materials, surfaces, and adsorbates (nitrogen, carbon, and oxygen chemistries). We supplemented this dataset with randomly perturbed structures, short timescale molecular dynamics, and electronic structure analyses. The dataset comprises three central tasks indicative of day-to-day catalyst modeling and comes with predefined train/validation/test splits to facilitate direct comparisons with future model development efforts. We applied three state-of-the-art graph neural network models (CGCNN, SchNet, and DimeNet++) to each of these tasks as baseline demonstrations for the community to build on. In almost every task, no upper limit on model size was identified, suggesting that even larger models are likely to improve on initial results. The dataset and baseline models are both provided as open resources as well as a public leader board to encourage community contributions to solve these important tasks.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 345, "Times Cited, All Databases": 375, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2021, "Volume": 11, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6059, "End Page": 6072, "Article Number": null, "DOI": "10.1021/acscatal.0c04525", "DOI Link": "http://dx.doi.org/10.1021/acscatal.0c04525", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000656056200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palmieri, V; Papi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palmieri, V.; Papi, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Can graphene take part in the fight against COVID-19?", "Source Title": "nullO TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The pneumonia outbreak of coronavirus disease 2019 (COVID-19) represents a global issue. The bidimensional material graphene has captured much attention due to promising antimicrobial applications and has also demonstrated antiviral efficacy. In response to this global outbreak, we summarized the current state of knowledge of graphene and virus interaction as well as possible successful applications to fight COVID-19. Antibody-conjugated graphene sheets can rapidly detect targeted virus proteins and can be useful for large population screening, but also for the development of environmental sensors and filters, given the low cost of graphene materials. Functionalized graphene has demonstrated a good viral capture capacity that, combined with heat or light-mediated inactivation, could be used as a disinfectant. Graphene sensors arrays can be implemented on standard utility textiles and drug efficacy screening. Thanks to its high versatility, we foresee that graphene may have a leading role in the fight against COVID-19. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100883, "DOI": "10.1016/j.nulltod.2020.100883", "DOI Link": "http://dx.doi.org/10.1016/j.nulltod.2020.100883", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000557793000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Xiong, TZ; Zhu, ZX; Xiao, R; Yao, XC; Huang, YC; Balogun, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hao; Xiong, Tuzhi; Zhu, Zhixiao; Xiao, Ran; Yao, Xincheng; Huang, Yongchao; Balogun, M-Sadeeq", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deciphering the lithium storage chemistry in flexible carbon fiber-based self-supportive electrodes", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flexible carbon fiber cloth (CFC) is an important scaffold and/or current collector for active materials in the development of flexible self-supportive electrode materials (SSEMs), especially in lithium-ion batteries. However, during the intercalation of Li ions into the matrix of CFC (below 0.5 V vs. Li/Li+), the incompatibility in the capacity of the CFC, when used directly as an anode material or as a current collector for active materials, leads to difficulty in the estimation of its actual contribution. To address this issue, we prepared Ni5P4 nullosheets on CFC (denoted CFC@Ni5P4) and investigated the contribution of CFC in the CFC@Ni5P4 by comparing to the powder Ni5P4 nullosheets traditionally coated on a copper foil (CuF) (denoted P-Ni5P4). At a current density of 0.4 mA cm(-2), the as-prepared CFC@Ni5P4 showed an areal capacity of 7.38 mAh cm(-2), which is significantly higher than that of the P-Ni5P4 electrode. More importantly, theoretical studies revealed that the CFC has a high Li adsorption energy that contributes to the low Li-ion diffusion energy barrier of the Ni5P4 due to the strong interaction between the CFC and Ni5P4, leading to the superior Li-ion storage performance of the CFC@Ni5P4 over the pristine Ni5P4 sample. This present work unveils the underlying mechanism leading to the achievement of high performance in SSEMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 820, "End Page": 832, "Article Number": null, "DOI": "10.1002/cey2.173", "DOI Link": "http://dx.doi.org/10.1002/cey2.173", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771007300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Tan, SJ; Zhou, ZT; Guan, XM; Liao, Y; Li, C; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yi; Tan, Shujuan; Zhou, Zhuoting; Guan, Xiaomeng; Liao, Yu; Li, Chen; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Co2NiO4@MnCo2O4.5 nulloparticles with multiple hetero-interfaces for enhanced electromagnetic wave absorption", "Source Title": "PARTICUOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocomposites with heterogeneous structures and magneto-electric synergistic losses have broad prospects for improving electromagnetic wave (EMW) absorption performance. In this study, we syn-thesized Co2NiO4@MnCo2O4.5 nulloparticles with abundant hetero-interfaces and multiple magneto -electric loss mechanisms by a facile hydrothermal method. The excess 0.5 oxygen atoms in MnCo2O4.5 produce more vacancies and contribute to the enhancement of electrical conductivity. Sequential nulloneedle clusters facilitate multiple reflections and absorption of EMW in the materials, which are accompanied by an abundance of heterogeneous interfaces to improve the dielectric loss. The Co2N-iO4@MnCo2O4.5 composites showed a minimum reflection loss (RLmin) of-30.01 dB and a superior effective absorption bandwidth (EAB) of 6.12 GHz (11.88 GHz-18 GHz) at a thickness of 2.00 mm. Computer Simulation Technology (CST) revealed that the obtained particles show very low radar cross-section (RCS) values and almost full coverage angles. The maximum reduction of RCS at vertical incidence reaches 19.98 dB m2. The Co2NiO4@MnCo2O4.5 nulloparticles exhibit outstanding radar attenuation properties, which can effectively inhibit the reflection and scattering of EMW. Therefore, the prepared Co2NiO4@MnCo2O4.5 absorbers have great application potential in the field of EMW absorption.(c) 2023 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 97, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 81, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 86, "End Page": 97, "Article Number": null, "DOI": "10.1016/j.partic.2022.12.013", "DOI Link": "http://dx.doi.org/10.1016/j.partic.2022.12.013", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000925476900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Knight, AJ; Borchert, J; Oliver, RDJ; Patel, JB; Radaelli, PG; Snaith, HJ; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Knight, Alexander J.; Borchert, Juliane; Oliver, Robert D. J.; Patel, Jay B.; Radaelli, Paolo G.; Snaith, Henry J.; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Halide Segregation in Mixed-Halide Perovskites: Influence of A-Site Cations", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixed-halide perovskites offer bandgap tunability essential for multijunction solar cells; however, a detrimental halide segregation under light is often observed. Here we combine simultaneous in situ photoluminescence and X-ray diffraction measurements to demonstrate clear differences in compositional and optoelectronic changes associated with halide segregation in MAPb(Br0.5I0.5)(3) and FA(0.83)Cs(0.17)Pb(Br0.4I0.6)(3) films. We report evidence for low-barrier ionic pathways in MAPb(Br0.5I0.5)(3), which allow for the rearrangement of halide ions in localized volumes of perovskite without significant compositional changes to the bulk material. In contrast, FA(0.83)Cs(0.17)Pb(Br0.4I0.6)(3) lacks such low-barrier ionic pathways and is, consequently, more stable against halide segregation. However, under prolonged illumination, it exhibits a considerable ionic rearrangement throughout the bulk material, which may be triggered by an initial demixing of A-site cations, altering the composition of the bulk perovskite and reducing its stability against halide segregation. Our work elucidates links between composition, ionic pathways, and halide segregation, and it facilitates the future engineering of phase-stable mixed-halide perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 12", "Publication Year": 2021, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 799, "End Page": 808, "Article Number": null, "DOI": "10.1021/acsenergylett.0c02475", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.0c02475", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000619803400059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YG; Lu, YM; Kee, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yige; Lu, Yuan-Ming; Kee, Hae-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological crystalline metal in orthorhombic perovskite iridates", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since topological insulators were theoretically predicted and experimentally observed in semiconductors with strong spin-orbit coupling, increasing attention has been drawn to topological materials that host exotic surface states. These surface excitations are stable against perturbations since they are protected by global or spatial/lattice symmetries. Following the success in achieving various topological insulators, a tempting challenge now is to search for metallic materials with novel topological properties. Here we predict that orthorhombic perovskite iridates realize a new class of metals dubbed topological crystalline metals, which support zero-energy surface states protected by certain lattice symmetry. These surface states can be probed by photoemission and tunnelling experiments. Furthermore, we show that by applying magnetic fields, the topological crystalline metal can be driven into other topological metallic phases, with different topological properties and surface states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6593, "DOI": "10.1038/ncomms7593", "DOI Link": "http://dx.doi.org/10.1038/ncomms7593", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353040300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Young, ZA; Guo, QL; Parab, ND; Zhao, C; Qu, ML; Escano, L; Fezzaa, K; Everhart, W; Sun, T; Chen, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Young, Zachary A.; Guo, Qilin; Parab, Niranjan D.; Zhao, Cang; Qu, Minglei; Escano, Luis, I; Fezzaa, Kamel; Everhart, Wes; Sun, Tao; Chen, Lianyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Types of spatter and their features and formation mechanisms in laser powder bed fusion additive manufacturing process", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spatter causes defect formation, powder redistribution and contamination in laser powder bed fusion (LPBF) additive manufacturing process. It is critical to distinguish different types of spatter and understand their features and formation mechanisms. This work reveals the features and formation mechanisms of five unique types of spatter during the LPBF process by in-situ high-speed, high-energy x-ray imaging. Spatters observed during LPBF testing are quantified by their speed, size, and direction. Distinct quantifiable characteristics for each type of spatter are identified. Effects of the laser power, scan speed, and ambient pressure on spatter formation and features are unraveled. A spatter formation map for AlSi10Mg alloy is constructed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 196, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 36, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101438, "DOI": "10.1016/j.addma.2020.101438", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2020.101438", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600807800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dulta, K; Agçeli, GK; Chauhan, P; Jasrotia, R; Chauhan, PK; Ighalo, JO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dulta, Kanika; Kosarsoy Agceli, Gozde; Chauhan, Parveen; Jasrotia, Rohit; Chauhan, P. K.; Ighalo, Joshua O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional CuO nulloparticles with enhanced photocatalytic dye degradation and antibacterial activity", "Source Title": "SUSTAINABLE ENVIRONMENT RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rhizome extract of Bergenia ciliata was used as a bio-functional reducing material for the green synthesis of copper oxide nulloparticles (CuO NPs). CuO NPs were characterized using ultraviolet-visible spectroscopy, Fourier transforms infrared spectroscopy, X-ray diffraction (XRD), dynamic light scattering, scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDX). XRD analysis revealed the monoclinic phase of synthesized CuO NPs with an average particle size of 20 nm. Spherical shaped nulloscale CuO particles were observed by EDX and SEM confirming the Cu and O presence in the synthesized NPs. CuO NPs showed antibacterial effects against Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Salmonella typhi. The antioxidant effect was measured and IC50 values for 2,2 '-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid (ABTS), 2,2-diphenyl-1-picrylhydrazyl and Ferric reducing antioxidant power assays were found to be 91.2, 72.4 and 109 mu g mL(- 1) respectively. Under sunlight, the CuO NPs reported extraordinary photocatalytic activity against Methylene Blue and Methyl Red degradation with efficiencies of 92-85%. CuO NPs have excellent potential application for the photocatalytic degradation of organic pollutants and in the development of antibacterial materials. This study offers new insights in the field of inexpensive and green synthesis-based antimicrobial effective CuO photocatalysts from B. ciliata to remove harmful dyes from industrial-based waters with high degradation efficiency, which is environmentally friendly.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2022, "Volume": 32, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2, "DOI": "10.1186/s42834-021-00111-w", "DOI Link": "http://dx.doi.org/10.1186/s42834-021-00111-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000739379000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oliveira, JP; Shamsolhodaei, A; Shen, JJ; Lopes, JG; Goncalves, RM; Ferraz, MD; Picarra, L; Zeng, Z; Schell, N; Zhou, N; Kim, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oliveira, J. P.; Shamsolhodaei, A.; Shen, Jiajia; Lopes, J. G.; Goncalves, R. M.; Ferraz, Mariana de Brito; Picarra, Lourenco; Zeng, Z.; Schell, N.; Zhou, N.; Kim, Hyoung Seop", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving the ductility in laser welded joints of CoCrFeMnNi high entropy alloy to 316 stainless steel", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dissimilar joining involving high entropy alloys is currently being explored to evaluate the suitability of these novel advanced engineering materials in structural applications. Recently, joining of a CoCrFeMnNi high entropy alloy to 316 stainless steel was successfully attempted. However, the joint ductility was lim-ited by the lack of deformation experienced by the cold-rolled CoCrFeMnNi base material during tensile loading. In this work, it is shown that by simply changing the base material condition, from cold-rolled to annealed, it is possible to significantly improve the joint fracture strain from 5 to 10 %, while preserv-ing the strength at 450 MPa. Using electron microscopy, high energy synchrotron X-ray diffraction and mechanical testing aided by digital image correlation, the microstructure evolution across the welded joint is assessed and correlated to its mechanical performance. Moreover, thermodynamic calculations considering the compositional changes across the fusion zone were used to predict the microstructure evolution of this region.(c) 2022 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 219, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110717, "DOI": "10.1016/j.matdes.2022.110717", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2022.110717", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808151400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hsueh, MH; Lai, CJ; Wang, SH; Zeng, YS; Hsieh, CH; Pan, CY; Huang, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hsueh, Ming-Hsien; Lai, Chao-Jung; Wang, Shi-Hao; Zeng, Yu-Shan; Hsieh, Chia-Hsin; Pan, Chieh-Yu; Huang, Wen-Chen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Printing Parameters on the Thermal and Mechanical Properties of 3D-Printed PLA and PETG, Using Fused Deposition Modeling", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fused Deposition Modeling (FDM) can be used to manufacture any complex geometry and internal structures, and it has been widely applied in many industries, such as the biomedical, manufacturing, aerospace, automobile, industrial, and building industries. The purpose of this research is to characterize the polylactic acid (PLA) and polyethylene terephthalate glycol (PETG) materials of FDM under four loading conditions (tension, compression, bending, and thermal deformation), in order to obtain data regarding different printing temperatures and speeds. The results indicated that PLA and PETG materials exhibit an obvious tensile and compression asymmetry. It was observed that the mechanical properties (tension, compression, and bending) of PLA and PETG are increased at higher printing temperatures, and that the effect of speed on PLA and PETG shows different results. In addition, the mechanical properties of PLA are greater than those of PETG, but the thermal deformation is the opposite. The above results will be a great help for researchers who are working with polymers and FDM technology to achieve sustainability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 13, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1758, "DOI": "10.3390/polym13111758", "DOI Link": "http://dx.doi.org/10.3390/polym13111758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000660516300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, BK; Li, CH; Zhang, YB; Wang, YG; Jia, DZ; Min, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li Benkai; Li Changhe; Zhang Yanbin; Wang Yaogang; Jia Dongzhou; Yang Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grinding temperature and energy ratio coefficient in MQL grinding of high-temperature nickel-base alloy by using different vegetable oils as base oil", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vegetable oil can be used as a base oil in minimal quantity of lubrication (MQL). This study compared the performances of MQL grinding by using castor oil, soybean oil, rapeseed oil, corn oil, sunflower oil, peanut oil, and palm oil as base oils. A K-P36 numerical-control precision surface grinder was used to perform plain grinding on a workpiece material with a high-temperature nickel base alloy. A YDM-III 99 three-dimensional dynamometer was used to measure grinding force, and a clip-type thermocouple was used to determine grinding temperature. The grinding force, grinding temperature, and energy ratio coefficient of MQL grinding were compared among the seven vegetable oil types. Results revealed that (1) castor oil-based MQL grinding yields the lowest grinding force but exhibits the highest grinding temperature and energy ratio coefficient; (2) palm oil-based MQL grinding generates the second lowest grinding force but shows the lowest grinding temperature and energy ratio coefficient; (3) MQL grinding based on the five other vegetable oils produces similar grinding forces, grinding temperatures, and energy ratio coefficients, with values ranging between those of castor oil and palm oil; (4) viscosity significantly influences grinding force and grinding temperature to a greater extent than fatty acid varieties and contents in vegetable oils; (5) although more viscous vegetable oil exhibits greater lubrication and significantly lower grinding force than less viscous vegetable oil, high viscosity reduces the heat exchange capability of vegetable oil and thus yields a high grinding temperature; (6) saturated fatty acid is a more efficient lubricant than unsaturated fatty acid; and (7) a short carbon chain transfers heat more effectively than a long carbon chain. Palm oil is the optimum base oil of MQL grinding, and this base oil yields 26.98 N tangential grinding force, 87.10 N normal grinding force, 119.6 degrees C grinding temperature, and 42.7% energy ratio coefficient. (C) 2015 The Authors. Production and hosting by Elsevier Ltd. on behalf of Chinese Society of Aeronautics and Astronautics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 29, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1084, "End Page": 1095, "Article Number": null, "DOI": "10.1016/j.cja.2015.10.012", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2015.10.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384735300023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Swager, TM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Swager, Timothy M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "50th Anniversary Perspective: Conducting/Semiconducting Conjugated Polymers. A Personal Perspective on the Past and the Future", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It has been about 40 years since the field of organic conducting polymers was ignited by the demonstration of metallic conductivity in polyacetylene. A retrospective view of this research area suggests some areas remain ripe for discovery/innovation. The breadth of activities is too large to be comprehensive; hence, selected seminal, as well as some personal, contributions will be used to illustrate concepts and anecdotal ways to think about conducting polymer systems. This Perspective can serve as a tutorial for newcomers to the field and will also remind experts about results from the past. It begins with some history and simple views of electronic structure, with selected examples. Segmented polymers containing isolated redox units will be discussed as well as how these materials can be made to have high conductivity. Key examples illustrating the matching of redox potentials are transition metal hybrid structures. Interchain interactions are emphasized along with their role in determining the nature of the charges. Recent results that demonstrate dramatic magneto-optical properties wherein the transmission of polarized light through conjugated polymers displays dramatic sensitivity to applied magnetic fields (Faraday effect) will also be discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2017, "Volume": 50, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4867, "End Page": 4886, "Article Number": null, "DOI": "10.1021/acs.macromol.7b00582", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.7b00582", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405642700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mehta, A; Zhou, L; Huynh, T; Park, S; Hyer, H; Song, ST; Bai, YL; Imholte, DD; Woolstenhulme, NE; Wachs, DM; Sohn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mehta, Abhishek; Zhou, Le; Huynh, Thinh; Park, Sharon; Hyer, Holden; Song, Shutao; Bai, Yuanli; Imholte, D. Devin; Woolstenhulme, Nicolas E.; Wachs, Daniel M.; Sohn, Yongho", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing and mechanical properties of the dense and crack free Zr-modified aluminum alloy 6061 fabricated by the laser-powder bed fusion", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For additive manufacturing such as laser powder bed fusion (LPBF), commercial aluminum alloy (AA) 6061 is typically considered unsuitable due to formation of solidification cracking and/or excessive porosity. In this study, to improve buildability/printability of AA6061, 1 wt% of Zr was alloyed to produce Zr-modified AA6061 by LPBF. Powders of unmodified and Zr-modified AA6061 were produced by gas atomization, and utilized as a feed-stock for the LPBF to fabricate specimens for microstructural examination and mechanical testing. The asbuilt unmodified AA6061 exhibited poor printability due to formation of cracks and porosity in the microstructure regardless of LPBF parameters. However, the Zr-modified AA6061 exhibited near full density, with substantial reduction in porosities without any solidification crack for a certain LPBF processing window. The improved printability of Zr-modified AA6061 was attributed to a significant grain refinement, which would reduce the solidification cracking susceptibility by hampering the epitaxial growth of long columnar cracks, as observed in unmodified AA6061. Yield strength, tensile strength and strain-at-failure for the as-built Zr-modified AA6061 were determined to be 210 MPa, 268 MPa, and 26.5%, respectively. These are superior to the tensile properties of AA6061 in O-annealed condition or in as-cast condition. After T6 heat treatment, yield strength, tensile strength and strain-at-failure of Zr-modified AA6061 were determined to be 300 MPa, 327 MPa, and 14%, which were again superior to the tensile properties of wrought AA6061 in T6 heat treated condition. Effects of Zr addition on the buildability/printability improvement and mechanical properties of AA6061 were corroborated by a variety of electron microscopic characterization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 41, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101966, "DOI": "10.1016/j.addma.2021.101966", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.101966", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663104300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anderson, CP; Bourassa, A; Miao, KC; Wolfowicz, G; Mintun, PJ; Crook, AL; Abe, H; Ul Hassan, J; Son, NT; Ohshima, T; Awschalom, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anderson, Christopher P.; Bourassa, Alexandre; Miao, Kevin C.; Wolfowicz, Gary; Mintun, Peter J.; Crook, Alexander L.; Abe, Hiroshi; Ul Hassan, Jawad; Son, Nguyen T.; Ohshima, Takeshi; Awschalom, David D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical and optical control of single spins integrated in scalable semiconductor devices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin defects in silicon carbide have the advantage of exceptional electron spin coherence combined with a near-infrared spin-photon interface, all in a material amenable to modern semiconductor fabrication. Leveraging these advantages, we integrated highly coherent single neutral divacancy spins in commercially available p-i-n structures and fabricated diodes to modulate the local electrical environment of the defects. These devices enable deterministic charge-state control and broad Stark-shift tuning exceeding 850 gigahertz. We show that charge depletion results in a narrowing of the optical linewidths by more than 50-fold, approaching the lifetime limit. These results demonstrate a method for mitigating the ubiquitous problem of spectral diffusion in solid-state emitters by engineering the electrical environment while using classical semiconductor devices to control scalable, spin-based quantum systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 6", "Publication Year": 2019, "Volume": 366, "Issue": 6470, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1225, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aax9406", "DOI Link": "http://dx.doi.org/10.1126/science.aax9406", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000502662500053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, CJ; Ma, RJ; Martínez-Pañeda, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Chuanjie; Ma, Rujin; Martinez-Paneda, Emilio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A phase field formulation for dissolution-driven stress corrosion cracking", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a new theoretical and numerical framework for modelling mechanically-assisted corrosion in elastic-plastic solids. Both pitting and stress corrosion cracking (SCC) can be captured, as well as the pit-to-crack transition. Localised corrosion is assumed to be dissolution-driven and a formulation grounded upon the film rupture-dissolution-repassivation mechanism is presented to incorporate the influence of film passivation. The model incorporates, for the first time, the role of mechanical straining as the electrochemical driving force, accelerating corrosion kinetics. The computational complexities associated with tracking the evolving metal-electrolyte interface are resolved by making use of a phase field paradigm, enabling an accurate approximation of complex SCC morphologies. The coupled electro-chemo-mechanical formulation is numerically implemented using the finite element method and an implicit time integration scheme; displacements, phase field order parameter and concentration are the primary variables. Five case studies of particular interest are addressed to showcase the predictive capabilities of the model, revealing an excellent agreement with analytical solutions and experimental measurements. By modelling these paradigmatic 2D and 3D boundary value problems we show that our formulation can capture: (i) the transition from activation-controlled corrosion to diffusion-controlled corrosion, (ii) the sensitivity of interface kinetics to mechanical stresses and strains, (iii) the role of film passivation in reducing corrosion rates, and (iv) the dependence of the stability of the passive film to local strain rates. The influence of these factors in driving the shape change of SCC defects, including the pit-to-crack transition, is a natural outcome of the model, laying the foundations for a mechanistic assessment of engineering materials and structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 132, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 147, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104254, "DOI": "10.1016/j.jmps.2020.104254", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2020.104254", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612236600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Baczewski, AT; Beaudet, TD; Benali, A; Bennett, MC; Berrill, MA; Blunt, NS; Josué, E; Borda, L; Casula, M; Ceperley, DM; Chiesa, S; Clark, BK; Clay, RC; Delaney, KT; Dewing, M; Esler, KP; Hao, HX; Heinonen, O; Kent, PRC; Krogel, JT; Kylänpää, I; Li, YW; Lopez, MG; Luo, Y; Malone, FD; Martin, RM; Mathuriya, A; McMinis, J; Melton, CA; Mitas, L; Morales, MA; Neuscamman, E; Parker, WD; Flores, SDP; Romero, NA; Rubenstein, BM; Shea, JAR; Shin, H; Shulenburger, L; Tillack, AF; Townsend, JP; Tubman, NM; Van der Goetz, B; Vincent, JE; Yang, DC; Yang, YB; Zhang, S; Zhao, LN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Jeongnim; Baczewski, Andrew T.; Beaudet, Todd D.; Benali, Anouar; Bennett, M. Chandler; Berrill, Mark A.; Blunt, Nick S.; Josue, Edgar; Borda, Landinez; Casula, Michele; Ceperley, David M.; Chiesa, Simone; Clark, Bryan K.; Clay, Raymond C., III; Delaney, Kris T.; Dewing, Mark; Esler, Kenneth P.; Hao, Hongxia; Heinonen, Olle; Kent, Paul R. C.; Krogel, Jaron T.; Kylanpaa, Ilkka; Li, Ying Wai; Lopez, M. Graham; Luo, Ye; Malone, Fionn D.; Martin, Richard M.; Mathuriya, Amrita; McMinis, Jeremy; Melton, Cody A.; Mitas, Lubos; Morales, Miguel A.; Neuscamman, Eric; Parker, William D.; Flores, Sergio D. Pineda; Romero, Nichols A.; Rubenstein, Brenda M.; Shea, Jacqueline A. R.; Shin, Hyeondeok; Shulenburger, Luke; Tillack, Andreas F.; Townsend, Joshua P.; Tubman, Norm M.; Van der Goetz, Brett; Vincent, Jordan E.; Yang, D. ChangMo; Yang, Yubo; Zhang, Shuai; Zhao, Luning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "QMCPACK: an open source ab initio quantum Monte Carlo package for the electronic structure of atoms, molecules and solids", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "QMCPACK is an open source quantum Monte Carlo package for ab initio electronic structure calculations. It supports calculations of metallic and insulating solids, molecules, atoms, and some model Hamiltonians. Implemented real space quantum Monte Carlo algorithms include variational, diffusion, and reptation Monte Carlo. QMCPACK uses Slater-Jastrow type trial wavefunctions in conjunction with a sophisticated optimizer capable of optimizing tens of thousands of parameters. The orbital space auxiliary-field quantum Monte Carlo method is also implemented, enabling cross validation between different highly accurate methods. The code is specifically optimized for calculations with large numbers of electrons on the latest high performance computing architectures, including multicore central processing unit and graphical processing unit systems. We detail the program's capabilities, outline its structure, and give examples of its use in current research calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 244, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 16", "Publication Year": 2018, "Volume": 30, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 195901, "DOI": "10.1088/1361-648X/aab9c3", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/aab9c3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430482300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HB; Wang, J; Zhou, J; Wang, CX; Lu, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Hongbo; Wang, Jue; Zhou, Jiang; Wang, Chengxin; Lu, Bingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building electrode skins for ultra-stable potassium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In nature, the human body is a perfect self-organizing and self-repairing system, with the skin protecting the internal organs and tissues from external damages. In this work, inspired by the human skin, we design a metal electrode skin (MES) to protect the metal interface. MES can increase the flatness of electrode and uniform the electric field distribution, inhibiting the growth of dendrites. In detail, an artificial film made of fluorinated graphene oxide serves as the first protection layer. At molecular level, fluorine is released and in-situ formed a robust SEI as the second protection skin for metal anode. As a result, Cu@MES parallel to K asymmetric cell is able to achieve an unprecedented cycle life (over 1600 cycles). More impressively, the full cell of K@MES parallel to Prussian blue exhibits a long cycle lifespan over 5000 cycles. This work illustrates a mechanism for metal electrode protection and provides a strategy for the applying bionics in batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2305, "DOI": "10.1038/s41467-023-38065-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38065-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001061881500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, XW; Basheer, C; Zare, RN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Xiaowei; Basheer, Chanbasha; Zare, Richard N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making ammonia from nitrogen and water microdroplets", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water (H2O) microdroplets are sprayed onto a magnetic iron oxide (Fe3O4) and Nafion-coated graphite mesh using compressed N-2 or air as the nebulizing gas. The resulting splash of microdroplets enters a mass spectrometer and is found to contain ammonia (NH3). This gas-liquid-solid heterogeneous catalytic system synthesizes ammonia in 0.2 ms. The conversion rate reaches 32.9 +/- 1.38 nmol s(-1) cm(-2) at room temperature without application of an external electric potential and without irradiation. Water microdroplets are the hydrogen source for N-2 in contact with Fe3O4. Hydrazine (H2NNH2) is also observed as a by-product and is suspected to be an intermediate in the formation of ammonia. This one-step nitrogen-fixation strategy to produce ammonia is eco-friendly and low cost, which converts widely available starting materials into a value-added product.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2023, "Volume": 120, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2301206120", "DOI": "10.1073/pnas.2301206120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2301206120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038895500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XC; Mirmoosa, MS; Asadchy, VS; Rockstuhl, C; Fan, SH; Tretyakov, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xuchen; Mirmoosa, Mohammad Sajjad; Asadchy, Viktar S.; Rockstuhl, Carsten; Fan, Shanhui; Tretyakov, Sergei A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metasurface-based realization of photonic time crystals", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photonic time crystals are artificial materials whose electromagnetic properties are uniform in space but periodically vary in time. The synthesis of these materials and experimental observation of their physics remain very challenging because of the stringent requirement for uniform modulation of material properties in volumetric samples. In this work, we extend the concept of photonic time crystals to two-dimensional artificial structures- metasurfaces. We demonstrate that time-varying metasurfaces not only preserve key physical properties of volumetric photonic time crystals despite their simpler topology but also host common momentum bandgaps shared by both surface and free-space electromagnetic waves. On the basis of a microwave metasurface design, we experimentally confirmed the exponential wave amplification inside a momentum bandgap and the possibility to probe bandgap physics by external (free-space) excitations. The proposed metasurface serves as a straightforward material platform for realizing emerging photonic space-time crystals and as a realistic system for the amplification of surface-wave signals in future wireless communications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2023, "Volume": 9, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "adg7541", "DOI": "10.1126/sciadv.adg7541", "DOI Link": "http://dx.doi.org/10.1126/sciadv.adg7541", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994524200015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stegmaier, A; Imhof, S; Helbig, T; Höfmann, T; Lee, CH; Kremer, M; Fritzsche, A; Feichtner, T; Klembt, S; Höfling, S; Boettcher, I; Fulga, IC; Ma, LB; Schmidt, OG; Greiter, M; Kiessling, T; Szameit, A; Thomale, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stegmaier, Alexander; Imhof, Stefan; Helbig, Tobias; Hoefmann, Tobias; Lee, Ching Hua; Kremer, Mark; Fritzsche, Alexander; Feichtner, Thorsten; Klembt, Sebastian; Hofling, Sven; Boettcher, Igor; Fulga, Ion Cosma; Ma, Libo; Schmidt, Oliver G.; Greiter, Martin; Kiessling, Tobias; Szameit, Alexander; Thomale, Ronny", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Defect Engineering and PT Symmetry in Non-Hermitian Electrical Circuits", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We employ electric circuit networks to study topological states of matter in non-Hermitian systems enriched by parity-time symmetry PT and chiral symmetry anti-PT (APT). The topological structure manifests itself in the complex admittance bands which yields excellent measurability and signal to noise ratio. We analyze the impact of PT-symmetric gain and loss on localized edge and defect states in a non-Hermitian Su-Schrieffer-Heeger (SSH) circuit. We realize all three symmetry phases of the system, including the APT-symmetric regime that occurs at large gain and loss. We measure the admittance spectrum and eigenstates for arbitrary boundary conditions, which allows us to resolve not only topological edge states, but also a novel PT-symmetric Z(2) invariant of the bulk. We discover the distinct properties of topological edge states and defect states in the phase diagram. In the regime that is not PT symmetric, the topological defect state disappears and only reemerges when APT symmetry is reached, while the topological edge states always prevail and only experience a shift in eigenvalue. Our findings unveil a future route for topological defect engineering and tuning in non-Hermitian systems of arbitrary dimension.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2021, "Volume": 126, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 215302, "DOI": "10.1103/PhysRevLett.126.215302", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.126.215302", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000655930100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A universal graph deep learning interatomic potential for the periodic table", "Source Title": "NATURE COMPUTATIONAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interatomic potentials (IAPs), which describe the potential energy surface of atoms, are a fundamental input for atomistic simulations. However, existing IAPs are either fitted to narrow chemistries or too inaccurate for general applications. Here we report a universal IAP for materials based on graph neural networks with three-body interactions (M3GNet). The M3GNet IAP was trained on the massive database of structural relaxations performed by the Materials Project over the past ten years and has broad applications in structural relaxation, dynamic simulations and property prediction of materials across diverse chemical spaces. About 1.8 million materials from a screening of 31 million hypothetical crystal structures were identified to be potentially stable against existing Materials Project crystals based on M3GNet energies. Of the top 2,000 materials with the lowest energies above the convex hull, 1,578 were verified to be stable using density functional theory calculations. These results demonstrate a machine learning-accelerated pathway to the discovery of synthesizable materials with exceptional properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 338, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 2, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 718, "End Page": "+", "Article Number": null, "DOI": "10.1038/s43588-022-00349-3", "DOI Link": "http://dx.doi.org/10.1038/s43588-022-00349-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000890324500016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kench, S; Cooper, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kench, Steve; Cooper, Samuel J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generating three-dimensional structures from a two-dimensional slice with generative adversarial network-based dimensionality expansion", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A generative approach called SliceGAN is demonstrated that can construct complex three-dimensional (3D) images from representative two-dimensional (2D) image examples. This is a promising approach in particular for studying microstructured materials where acquiring good-quality 3D data is challenging; 3D datasets can be created with SliceGAN, making use of high-quality 2D imaging techniques that are widely available. Generative adversarial networks (GANs) can be trained to generate three-dimensional (3D) image data, which are useful for design optimization. However, this conventionally requires 3D training data, which are challenging to obtain. Two-dimensional (2D) imaging techniques tend to be faster, higher resolution, better at phase identification and more widely available. Here we introduce a GAN architecture, SliceGAN, that is able to synthesize high-fidelity 3D datasets using a single representative 2D image. This is especially relevant for the task of material microstructure generation, as a cross-sectional micrograph can contain sufficient information to statistically reconstruct 3D samples. Our architecture implements the concept of uniform information density, which ensures both that generated volumes are equally high quality at all points in space and that arbitrarily large volumes can be generated. SliceGAN has been successfully trained on a diverse set of materials, demonstrating the widespread applicability of this tool. The quality of generated micrographs is shown through a statistical comparison of synthetic and real datasets of a battery electrode in terms of key microstructural metrics. Finally, we find that the generation time for a 10(8) voxel volume is on the order of a few seconds, yielding a path for future studies into high-throughput microstructural optimization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 299, "End Page": 305, "Article Number": null, "DOI": "10.1038/s42256-021-00322-1", "DOI Link": "http://dx.doi.org/10.1038/s42256-021-00322-1", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637745900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, HZ; Bi, XQ; Chen, HB; He, TF; Lin, Y; Zhang, YX; Ma, KQ; Feng, WY; Ma, ZF; Long, GK; Li, CX; Kan, B; Zhang, HT; Rakitin, OA; Wan, XJ; Yao, ZY; Chen, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Huazhe; Bi, Xingqi; Chen, Hongbin; He, Tengfei; Lin, Yi; Zhang, Yunxin; Ma, Kangqiao; Feng, Wanying; Ma, Zaifei; Long, Guankui; Li, Chenxi; Kan, Bin; Zhang, Hongtao; Rakitin, Oleg A.; Wan, Xiangjian; Yao, Zhaoyang; Chen, Yongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A rare case of brominated small molecule acceptors for high-efficiency organic solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Given that bromine possesses similar properties but extra merits of easily synthesizing and polarizing comparing to homomorphic fluorine and chlorine, it is quite surprising very rare high-performance brominated small molecule acceptors have been reported. This may be caused by undesirable film morphologies stemming from relatively larger steric hindrance and excessive crystallinity of bromides. To maximize the advantages of bromides while circumventing weaknesses, three acceptors (CH20, CH21 and CH22) are constructed with stepwise brominating on central units rather than conventional end groups, thus enhancing intermolecular packing, crystallinity and dielectric constant of them without damaging the favorable intermolecular packing through end groups. Consequently, PM6:CH22-based binary organic solar cells render the highest efficiency of 19.06% for brominated acceptors, more excitingly, a record-breaking efficiency of 15.70% when further thickening active layers to similar to 500 nm. By exhibiting such a rare high-performance brominated acceptor, our work highlights the great potential for achieving record-breaking organic solar cells through delicately brominating.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4707, "DOI": "10.1038/s41467-023-40423-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40423-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001043364000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nagy, R; Niethammer, M; Widmann, M; Chen, YC; Udvarhelyi, P; Bonato, C; Hassan, JU; Karhu, R; Ivanov, IG; Son, NT; Maze, JR; Ohshima, T; Soykal, ÖO; Gali, A; Lee, SY; Kaiser, F; Wrachtrup, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nagy, Roland; Niethammer, Matthias; Widmann, Matthias; Chen, Yu-Chen; Udvarhelyi, Peter; Bonato, Cristian; Hassan, Jawad Ui; Karhu, Robin; Ivanov, Ivan G.; Nguyen Tien Son; Maze, Jeronimo R.; Ohshima, Takeshi; Soykal, Oney O.; Gali, Adam; Lee, Sang-Yun; Kaiser, Florian; Wrachtrup, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-fidelity spin and optical control of single silicon-vacancy centres in silicon carbide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalable quantum networking requires quantum systems with quantum processing capabilities. Solid state spin systems with reliable spin-optical interfaces are a leading hardware in this regard. However, available systems suffer from large electron-phonon interaction or fast spin dephasing. Here, we demonstrate that the negatively charged silicon-vacancy centre in silicon carbide is immune to both drawbacks. Thanks to its (4)A(2) symmetry in ground and excited states, optical resonullces are stable with near-Fourier-transform-limited linewidths, allowing exploitation of the spin selectivity of the optical transitions. In combination with millisecond-long spin coherence times originating from the high-purity crystal, we demonstrate high-fidelity optical initialization and coherent spin control, which we exploit to show coherent coupling to single nuclear spins with similar to 1 kHz resolution. The summary of our findings makes this defect a prime candidate for realising memory-assisted quantum network applications using semiconductor-based spin-to-photon interfaces and coherently coupled nuclear spins.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1954, "DOI": "10.1038/s41467-019-09873-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09873-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465838600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kato, M; Ito, H; Hasegawa, M; Ishii, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kato, Masako; Ito, Hajime; Hasegawa, Miki; Ishii, Kazuyuki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Soft Crystals: Flexible Response Systems with High Structural Order", "Source Title": "CHEMISTRY-A EUROPEAN JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new material concept of soft crystals is proposed. Soft crystals respond to gentle stimuli such as vapor exposure and rubbing but maintain their structural order and exhibit remarkable visual changes in their shape, color, and luminescence. Various interesting examples of soft crystals are introduced in the article. By exploring the interesting formation and phase-transition phenomena of soft crystals through interdisciplinary collaboration, new materials having both the characteristics of ordered hard crystals and those of flexible soft matter are expected.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 229, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2019, "Volume": 25, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5105, "End Page": 5112, "Article Number": null, "DOI": "10.1002/chem.201805641", "DOI Link": "http://dx.doi.org/10.1002/chem.201805641", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468855200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huber, D; Reindl, M; Huo, YH; Huang, HY; Wildmann, JS; Schmidt, OG; Rastelli, A; Trotta, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huber, Daniel; Reindl, Marcus; Huo, Yongheng; Huang, Huiying; Wildmann, Johannes S.; Schmidt, Oliver G.; Rastelli, Armando; Trotta, Rinaldo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly indistinguishable and strongly entangled photons from symmetric GaAs quantum dots", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of scalable sources of non-classical light is fundamental to unlocking the technological potential of quantum photonics. Semiconductor quantum dots are emerging as near-optimal sources of indistinguishable single photons. However, their performance as sources of entangled-photon pairs are still modest compared to parametric down converters. Photons emitted from conventional Stranski-Krastanov InGaAs quantum dots have shown non-optimal levels of entanglement and indistinguishability. For quantum networks, both criteria must be met simultaneously. Here, we show that this is possible with a system that has received limited attention so far: GaAs quantum dots. They can emit triggered polarization-entangled photons with high purity (g((2))(0) = 0.002 +/- 0.002), high indistinguishability (0.93 +/- 0.07 for 2 ns pulse separation) and high entanglement fidelity (0.94 +/- 0.01). Our results show that GaAs might be the material of choice for quantum-dot entanglement sources in future quantum technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15506, "DOI": "10.1038/ncomms15506", "DOI Link": "http://dx.doi.org/10.1038/ncomms15506", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402161000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Durrell, JH; Dennis, AR; Jaroszynski, J; Ainslie, MD; Palmer, KGB; Shi, YH; Campbell, AM; Hull, J; Strasik, M; Hellstrom, EE; Cardwell, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Durrell, J. H.; Dennis, A. R.; Jaroszynski, J.; Ainslie, M. D.; Palmer, K. G. B.; Shi, Y-H; Campbell, A. M.; Hull, J.; Strasik, M.; Hellstrom, E. E.; Cardwell, D. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A trapped field of 17.6T in melt-processed, bulk Gd-Ba-Cu-O reinforced with shrink-fit steel", "Source Title": "SUPERCONDUCTOR SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability of large-grain (RE)Ba2Cu3O7-delta ((RE)BCO; RE = rare earth) bulk superconductors to trap magnetic fields is determined by their critical current. With high trapped fields, however, bulk samples are subject to a relatively large Lorentz force, and their performance is limited primarily by their tensile strength. Consequently, sample reinforcement is the key to performance improvement in these technologically important materials. In this work, we report a trapped field of 17.6 T, the largest reported to date, in a stack of two silver-doped GdBCO superconducting bulk samples, each 25 mm in diameter, fabricated by top-seeded melt growth and reinforced with shrink-fit stainless steel. This sample preparation technique has the advantage of being relatively straightforward and inexpensive to implement, and offers the prospect of easy access to portable, high magnetic fields without any requirement for a sustaining current source.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 485, "Times Cited, All Databases": 499, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 27, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 82001, "DOI": "10.1088/0953-2048/27/8/082001", "DOI Link": "http://dx.doi.org/10.1088/0953-2048/27/8/082001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000339329300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, GY; Tang, YL; Zhao, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Guoying; Tang, Yunlong; Zhao, Yaoyao Fiona", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Survey of Modeling of Lattice Structures Fabricated by Additive Manufacturing", "Source Title": "JOURNAL OF MECHANICAL DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lattice structure is a type of cellular material with trusslike frames which can be optimized for specific loading conditions. The fabrication of its intricate architecture is restricted by traditional manufacturing technologies. However, additive manufacturing (AM) enables the fabrication of complex structures by aggregation of materials in a layer-by-layer fashion, which has unlocked the potential of lattice structures. In the last decade, lattice structures have received considerable research attention focusing on the design, simulation, and fabrication for AM techniques. And different modeling approaches have been proposed to predict the mechanical performance of lattice structures. This review introduces the aspects of modeling of lattice structures and the correlation between them, summarizes the existing modeling approaches for simulation, and discusses the strength and weakness in different simulation methods. This review also summarizes the characteristics of AM in manufacturing cellular materials and discusses their influence on the modeling of lattice structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 139, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100906, "DOI": "10.1115/1.4037305", "DOI Link": "http://dx.doi.org/10.1115/1.4037305", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417293500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ginot, F; Theurkauff, I; Levis, D; Ybert, C; Bocquet, L; Berthier, L; Cottin-Bizonne, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ginot, Felix; Theurkauff, Isaac; Levis, Demian; Ybert, Christophe; Bocquet, Lyderic; Berthier, Ludovic; Cottin-Bizonne, Cecile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonequilibrium Equation of State in Suspensions of Active Colloids", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Active colloids constitute a novel class of materials composed of colloidal-scale particles locally converting chemical energy into motility, mimicking micro-organisms. Evolving far from equilibrium, these systems display structural organizations and dynamical properties distinct from thermalized colloidal assemblies. Harvesting the potential of this new class of systems requires the development of a conceptual framework to describe these intrinsically nonequilibrium systems. We use sedimentation experiments to probe the nonequilibrium equation of state of a bidimensional assembly of active Janus microspheres and conduct computer simulations of a model of self-propelled hard disks. Self-propulsion profoundly affects the equation of state, but these changes can be rationalized using equilibrium concepts. We show that active colloids behave, in the dilute limit, as an ideal gas with an activity-dependent effective temperature. At finite density, increasing the activity is similar to increasing adhesion between equilibrium particles. We quantify this effective adhesion and obtain a unique scaling law relating activity and effective adhesion in both experiments and simulations. Our results provide a new and efficient way to understand the emergence of novel phases of matter in active colloidal suspensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11004, "DOI": "10.1103/PhysRevX.5.011004", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.011004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349488400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uykur, E; Ortiz, BR; Wilson, SD; Dressel, M; Tsirlin, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uykur, Ece; Ortiz, Brenden R.; Wilson, Stephen D.; Dressel, Martin; Tsirlin, Alexander A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optical detection of the density-wave instability in the kagome metal KV3Sb5", "Source Title": "NPJ QUANTUM MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coexisting density-wave and superconducting states along with the large anomalous Hall effect in the absence of local magnetism remain intriguing and enigmatic features of the AV(3)Sb(5) kagome metals (A = K, Rb, Cs). Here, we demonstrate via optical spectroscopy and density-functional calculations that low-energy dynamics of KV3Sb5 is characterized by unconventional localized carriers, which are strongly renormalized across the density-wave transition and indicative of electronic correlations. Strong phonon anomalies are prominent not only below the density-wave transition, but also at high temperatures, suggesting an intricate interplay of phonons with the underlying electronic structure. We further propose the star-of-David and tri-hexagon (inverse star-of-David) configurations for the density-wave order in KV3Sb5. These configurations are strongly reminiscent of p-wave states expected in the Hubbard model on the kagome lattice at the filling level of the van Hove singularity. The proximity to this regime should have intriguing and far-reaching implications for the physics of KV3Sb5 and related materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16, "DOI": "10.1038/s41535-021-00420-8", "DOI Link": "http://dx.doi.org/10.1038/s41535-021-00420-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749216100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, FY; Rauch, F; Swain, A; Marder, TB; Ravat, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fangyuan; Rauch, Florian; Swain, Asim; Marder, Todd B.; Ravat, Prince", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Narrowband Circularly Polarized Light Emitters Based on 1,4-B,N-embedded Rigid Donor-Acceptor Helicenes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Narrow-band emission is essential for applicable circularly polarized luminescence (CPL) active materials in ultrahigh-definition CP-OLEDs. One of the most promising classes of CPL active molecules, helicenes, however, typically exhibit broad emission with a large Stokes shift. We present, herein, a design strategy capitalizing on intramolecular donor-acceptor interactions between nitrogen and boron atoms to address this issue. 1,4-B,N-embedded configurationally stable single- and double helicenes were synthesized straightforwardly. Both helicenes show unprecedentedly narrow fluorescence and CPL bands (full width at half maximum between 17-28 nm, 0.07-0.13 eV) along with high fluorescence quantum yields (72-85 %). Quantum chemical calculations revealed that the relative localization of the natural transition orbitals, mainly on the rigid core of the molecule, and small values of root-mean-square displacements between S-0 and S-1 state geometries, contribute to the narrower emission.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2023, "Volume": 62, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202218965", "DOI Link": "http://dx.doi.org/10.1002/anie.202218965", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000945744300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rangel, T; Fregoso, BM; Mendoza, BS; Morimoto, T; Moore, JE; Neaton, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rangel, Tonatiuh; Fregoso, Benjamin M.; Mendoza, Bernardo S.; Morimoto, Takahiro; Moore, Joel E.; Neaton, Jeffrey B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large Bulk Photovoltaic Effect and Spontaneous Polarization of Single-Layer Monochalcogenides", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use a first-principles density functional theory approach to calculate the shift current and linear absorption of uniformly illuminated single-layer Ge and Sn monochalcogenides. We predict strong absorption in the visible spectrum and a large effective three-dimensional shift current (similar to 100 mu A/V-2), larger than has been previously observed in other polar systems. Moreover, we show that the integral of the shift-current tensor is correlated to the large spontaneous effective three-dimensional electric polarization (similar to 1.9 C/m(2)). Our calculations indicate that the shift current will be largest in the visible spectrum, suggesting that these monochalcogenides may be promising for polar optoelectronic devices. A Rice-Mele tight-binding model is used to rationalize the shift-current response for these systems, and its dependence on polarization, in general terms with implications for other polar materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2017, "Volume": 119, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 67402, "DOI": "10.1103/PhysRevLett.119.067402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.067402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407100100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rees, D; Manna, K; Lu, BZ; Morimoto, T; Borrmann, H; Felser, C; Moore, JE; Torchinsky, DH; Orenstein, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rees, Dylan; Manna, Kaustuv; Lu, Baozhu; Morimoto, Takahiro; Borrmann, Horst; Felser, Claudia; Moore, J. E.; Torchinsky, Darius H.; Orenstein, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Helicity-dependent photocurrents in the chiral Weyl semimetal RhSi", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are crystals in which electron bands cross at isolated points in momentum space. Associated with each crossing point (or Weyl node) is a topological invariant known as the Berry monopole charge. The circular photogalvanic effect (CPGE), whereby circular polarized light generates a helicity-dependent photocurrent, is a notable example of a macroscopic property that emerges directly from the topology of the Weyl semimetal band structure. Recently, it was predicted that the amplitude of the CPGE associated with optical transitions near a Weyl node is proportional to its monopole charge. In chiral Weyl systems, nodes of opposite charge are non-degenerate, opening a window of wavelengths where the CPGE resulting from uncompensated Berry charge can emerge. Here, we report measurements of CPGE in the chiral Weyl semimetal RhSi, revealing a CPGE response in an energy window that closes at 0.65 eV, in agreement with the predictions of density functional theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 6, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba0509", "DOI": "10.1126/sciadv.aba0509", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba0509", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552227800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dupé, B; Hoffmann, M; Paillard, C; Heinze, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dupe, Bertrand; Hoffmann, Markus; Paillard, Charles; Heinze, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring magnetic skyrmions in ultra-thin transition metal films", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skyrmions in magnetic materials offer attractive perspectives for future spintronic applications since they are topologically stabilized spin structures on the nullometre scale, which can be manipulated with electric current densities that are by orders of magnitude lower than those required for moving domain walls. So far, they were restricted to bulk magnets with a particular chiral crystal symmetry greatly limiting the number of available systems and the adjustability of their properties. Recently, it has been experimentally discovered that magnetic skyrmion phases can also occur in ultra-thin transition metal films at surfaces. Here we present an understanding of skyrmions in such systems based on first-principles electronic structure theory. We demonstrate that the properties of magnetic skyrmions at transition metal interfaces such as their diameter and their stability can be tuned by the structure and composition of the interface and that a description beyond a micromagnetic model is required in such systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4030, "DOI": "10.1038/ncomms5030", "DOI Link": "http://dx.doi.org/10.1038/ncomms5030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000338837300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kenney, EM; Ortiz, BR; Wang, CN; Wilson, SD; Graf, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kenney, Eric M.; Ortiz, Brenden R.; Wang, Chennull; Wilson, Stephen D.; Graf, Michael J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Absence of local moments in the kagome metal KV3Sb5 as determined by muon spin spectroscopy", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have carried out muon spin relaxation and rotation measurements on the newly discovered kagome metal KV3Sb5, and find a local field dominated by weak magnetic disorder which we associate with the nuclear moments present, and a modest temperature dependence which tracks the bulk magnetic susceptibility. We find no evidence for the existence of V4+ local moments, suggesting that the physics underlying the recently reported giant unconventional anomalous Hall effect in this material warrants further studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 9", "Publication Year": 2021, "Volume": 33, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235801, "DOI": "10.1088/1361-648X/abe8f9", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/abe8f9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000649089600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ross, J; Belgodere, B; Chenthamarakshan, V; Padhi, I; Mroueh, Y; Das, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ross, Jerret; Belgodere, Brian; Chenthamarakshan, Vijil; Padhi, Inkit; Mroueh, Youssef; Das, Payel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale chemical language representations capture molecular structure and properties", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large language models have recently emerged with extraordinary capabilities, and these methods can be applied to model other kinds of sequence, such as string representations of molecules. Ross and colleagues have created a transformer-based model, trained on a large dataset of molecules, which provides good results on property prediction tasks. Models based on machine learning can enable accurate and fast molecular property predictions, which is of interest in drug discovery and material design. Various supervised machine learning models have demonstrated promising performance, but the vast chemical space and the limited availability of property labels make supervised learning challenging. Recently, unsupervised transformer-based language models pretrained on a large unlabelled corpus have produced state-of-the-art results in many downstream natural language processing tasks. Inspired by this development, we present molecular embeddings obtained by training an efficient transformer encoder model, MoLFormer, which uses rotary positional embeddings. This model employs a linear attention mechanism, coupled with highly distributed training, on SMILES sequences of 1.1 billion unlabelled molecules from the PubChem and ZINC datasets. We show that the learned molecular representation outperforms existing baselines, including supervised and self-supervised graph neural networks and language models, on several downstream tasks from ten benchmark datasets. They perform competitively on two others. Further analyses, specifically through the lens of attention, demonstrate that MoLFormer trained on chemical SMILES indeed learns the spatial relationships between atoms within a molecule. These results provide encouraging evidence that large-scale molecular language models can capture sufficient chemical and structural information to predict various distinct molecular properties, including quantum-chemical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 137, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 4, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s42256-022-00580-7", "DOI Link": "http://dx.doi.org/10.1038/s42256-022-00580-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000915646400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, X; Liu, LT; Sun, JJ; Zhang, NK; Sun, HZ; Wu, HT; Tao, WH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xu; Liu, Lintao; Sun, Jiajia; Zhang, Ningkang; Sun, Huazhang; Wu, Haitao; Tao, Wenhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of (Mg1/3Sb2/3)4+ substitution on the structure and microwave dielectric properties of Ce2Zr3(MoO4)9 ceramics", "Source Title": "JOURNAL OF ADVANCED CERAMICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ce-2[Zr1-x(Mg1/3Sb2/3)x](3)(MoO4)(9) (0.02 <= x <= 0.10) ceramics were prepared by the traditional solid-state method. A single phase, belonging to the space group of R (3) over barc, was detected by using X-ray diffraction at the sintering temperatures ranging from 700 to 850 degrees C. The microstructures of samples were examined by applying scanning electron microscopy (SEM). The crystal structure refinement of these samples was investigated in detail by performing the Rietveld refinement method. The intrinsic properties were calculated and explored via far-infrared reflectivity spectroscopy. The correlations between the chemical bond parameters and microwave dielectric properties were calculated and analyzed by Phillips-van Vechten-Levine (P-V-L) theory. Ce-2[Zr-0.94(Mg1/3Sb2/3)(0.06)](3)(MoO4)(9) ceramics with excellent dielectric properties were sintered at 725 degrees C for 6 h (epsilon(r) = 10.37, Qxf = 71,748 GHz, and tau(f) = -13.6 ppm/degrees C, epsilon(r) is the dielectric constant, Qxf is the quality factor, and tf is the temperature coefficient of resonullt frequency).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 778, "End Page": 789, "Article Number": null, "DOI": "10.1007/s40145-021-0472-3", "DOI Link": "http://dx.doi.org/10.1007/s40145-021-0472-3", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000673026700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, J; Xu, ZM; Murong, YK; Wang, L; Lei, B; Chu, LJ; Jiang, HB; Qu, WJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Jie; Xu, Zhenming; Murong, Yikang; Wang, Lei; Lei, Bin; Chu, Lijing; Jiang, Haibo; Qu, Wenjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Chemical Composition of Fine Aggregate on the Frictional Behavior of Concrete-Soil Interface under Sulfuric Acid Environment", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Through direct shear tests, this paper aimed to research the effect of fine marble aggregate on the shear strength and fractal dimension of the interface between soil and concrete corroded by sulfuric acid. More realistic concrete rough surfaces than the artificially roughened surfaces were formed by immersing four concrete plates in plastic buckets filled with sulfuric acid for different periods of time. The sand was adopted to imitate the soil. 3D laser scanner was employed to obtain the digital shapes of concrete plates subjected to sulfuric acid, and the rough surfaces were evaluated by fractal dimension. Large direct shear experiments were performed to obtain the curves of the interface shear stress and shear displacement between sand and corroded concrete plate. The method of data fitting was adopted to calculate the parameters of shear strength (i.e., friction angle and the cohesive) and the parameters of the Clough-Duncan hyperbolic model. The results indicated that as the corrosion days increased, the surface of the concrete plate became rougher, the surface fractal dimensions of the concrete corroded by sulfuric acid became bigger, and the interface friction angle became greater. The friction angle of the interface and the fractal dimensions of the surface of the concrete plate containing crushed gravel and marble sand were smaller than that of the concrete plate containing crushed gravel and river sand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 26, "Times Cited, All Databases": 26, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 22, "DOI": "10.3390/fractalfract6010022", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6010022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757579200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Azzouzi, M; Yan, J; Kirchartz, T; Liu, KK; Wang, JL; Wu, HB; Nelson, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Azzouzi, Mohammed; Yan, Jun; Kirchartz, Thomas; Liu, Kaikai; Wang, Jinliang; Wu, Hongbin; Nelson, Jenny", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nonradiative Energy Losses in Bulk-Heterojunction Organic Photovoltaics", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of solar cells based on molecular electronic materials is limited by relatively high nonradiative voltage losses. The primary pathway for nonradiative recombination in organic donor-acceptor heterojunction devices is believed to be the decay of a charge-transfer (CT) excited state to the ground state via energy transfer to vibrational modes. Recently, nonradiative voltage losses have been related to properties of the charge-transfer state such as the Franck-Condon factor describing the overlap of the CT and ground-state vibrational states and, therefore, to the energy of the CT state. However, experimental data do not always follow the trends suggested by the simple model. Here, we extend this recombination model to include other factors that influence the nonradiative decay-rate constant, and therefore the open-circuit voltage, but have not yet been explored in detail. We use the extended model to understand the observed behavior of series of small molecules: fullerene blend devices, where open-circuit voltage appears insensitive to nonradiative loss. The trend could be explained only in terms of a microstructure-dependent CT-state oscillator strength, showing that parameters other than CT-state energy can control nonradiative recombination. We present design rules for improving open-circuit voltage via the control of material parameters and propose a realistic limit to the power-conversion efficiency of organic solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 7", "Publication Year": 2018, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31055, "DOI": "10.1103/PhysRevX.8.031055", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.8.031055", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443956800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wakjira, TG; Ibrahim, M; Ebead, U; Alam, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wakjira, Tadesse G.; Ibrahim, Mohamed; Ebead, Usama; Alam, M. Shahira", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Explainable machine learning model and reliability analysis for flexural capacity prediction of RC beams strengthened in flexure with FRCM", "Source Title": "ENGINEERING STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents a data-driven approach to determine the load and flexural capacities of reinforced concrete (RC) beams strengthened with fabric reinforced cementitious matrix (FRCM) composites in flexure. A total of seven machine learning (ML) models such as kernel ridge regression, K-nearest neighbors, support vector regression, classification and regression trees, random forest, gradient boosted trees, and extreme gradient boosting (xgBoost) are evaluated to propose the best predictive model for FRCM-strengthened beams. Beam geometry, internal steel reinforcement area, FRCM reinforcement area, and mechanical characteristics of concrete, steel, and FRCM are the main input parameters included in the database. Among the studied ML models, the xgBoost model is the most accurate model with the highest coefficient of determination (R-2 = 99.3%) and least root mean square (RMSE), mean absolute error (MAE), and mean absolute percentage error (MAPE). A comparative study of the performance of the proposed and existing analytical models revealed the superior predictive capability and robustness of the proposed model. The predicted flexural and load capacities of the beams based on the existing analytical models are highly scattered and either over-conservative or unsafe. A unified SHapley Additive exPlanations approach is employed to explain the output of the best ML model and identify the most significant input features and interactions that influence the capacity of FRCM-strengthened RC beams in flexure. Furthermore, a reliability analysis is performed to calibrate the resistance reduction factor (phi) to achieve a specified target reliability index (beta(T) = 3.5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2022, "Volume": 255, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113903, "DOI": "10.1016/j.engstruct.2022.113903", "DOI Link": "http://dx.doi.org/10.1016/j.engstruct.2022.113903", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776111400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arrayago, I; Real, E; Gardner, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arrayago, I.; Real, E.; Gardner, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Description of stress-strain curves for stainless steel alloys", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is a wide variety of stainless steel alloys, but all are characterized by a rounded stress-strain response with no sharply defined yield point This behaviour can be represented analytically by different material models, the most popular of which are based on the Ramberg-Osgood formulations or extensions thereof. The degree of roundedness, the level of strain hardening, the strain at ultimate stress and the ductility at fracture of the material all vary between grades, and need to be suitably captured for an accurate representation of the material to be achieved. The aim of the present study is to provide values and predictive expressions for the key parameters in existing stainless steel material models based on the analysis of a comprehensive experimental database. The database comprises experimental stress-strain curves collected from the literature, supplemented by some tensile tests on austenitic, ferritic and duplex stainless steel coupons conducted herein. It covers a range of stainless steel alloys, annealed and cold-worked material, and data from the rolling and transverse directions. In total, more than 600 measured stress-strain curves have been collected from 15 international research groups. Each curve from the database has been analysed in order to obtain the key material parameters through a curve fitting process based on least squares adjustment techniques. These parameter values have been compared to those calculated from existing predictive models, the accuracy of which could therefore be evaluated. Revised expressions providing more accurate parameter predictions have been proposed where necessary. Finally, a second set of results, containing material parameters reported directly by others, with information of more than 400 specimens, has also been collected from the literature. Although these experimental results were not accessible as measured raw data, they enabled further confirmation of the suitability of the proposed equations. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 421, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2015, "Volume": 87, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 540, "End Page": 552, "Article Number": null, "DOI": "10.1016/j.matdes.2015.08.001", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2015.08.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363816000063", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Filipovic, N; Usjak, D; Milenkovic, MT; Zheng, K; Liverani, L; Boccaccini, AR; Stevanovic, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filipovic, Nenad; Usjak, Dusan; Milenkovic, Marina T.; Zheng, Kai; Liverani, Liliana; Boccaccini, Aldo R.; Stevanovic, Magdalena M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparative Study of the Antimicrobial Activity of Selenium nulloparticles With Different Surface Chemistry and Structure", "Source Title": "FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although selenium nulloparticles (SeNPs) have gained attention in the scientific community mostly through investigation of their anticancer activity, a great potential of this nullomaterial was recognized recently regarding its antimicrobial activity. The particle form, size, and surface chemistry have been recognized as crucial parameters determining the interaction of nullomaterials with biological entities. Furthermore, considering a narrow boundary between beneficial and toxic effects for selenium per se, it is clear that investigations of biomedical applications of SeNPs are very demanding and must be done with great precautions. The goal of this work is to evaluate the effects of SeNPs surface chemistry and structure on antimicrobial activity against several common bacterial strains, including Staphylococcus aureus (ATCC 6538), Enterococcus faecalis (ATCC 29212), Bacillus subtilis (ATCC 6633), and Kocuria rhizophila (ATCC 9341), as well as Escherichia coli (ATCC 8739), Salmonella Abony (NCTC 6017), Klebsiella pneumoniae (NCIMB 9111) and Pseudomonas aeruginosa (ATCC 9027), and the standard yeast strain Candida albicans (ATCC 10231). Three types of SeNPs were synthesized by chemical reduction approach using different stabilizers and reducing agents: (i) bovine serum albumin (BSA) + ascorbic acid, (ii) chitosan + ascorbic acid, and (iii) with glucose. A thorough physicochemical characterization of the obtained SeNPs was performed to determine the effects of varying synthesis parameters on their morphology, size, structure, and surface chemistry. All SeNPs were amorphous, with spherical morphology and size in the range 70-300 nm. However, the SeNPs obtained under different synthesis conditions, i.e. by using different stabilizers as well as reducing agents, exhibited different antimicrobial activity as well as cytotoxicity which are crucial for their applications. In this paper, the antimicrobial screening of the selected systems is presented, which was determined by the broth microdilution method, and inhibitory influence on the production of monomicrobial and dual-species biofilm was evaluated. The potential mechanism of action of different systems is proposed. Additionally, the cytotoxicity of SeNPs was examined on the MRC-5 cell line, in the same concentration interval as for antimicrobial testing. It was shown that formulation SeNPs-BSA expressed a significantly lower cytotoxic effect than the other two formulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 136, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2021, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 624621, "DOI": "10.3389/fbioe.2020.624621", "DOI Link": "http://dx.doi.org/10.3389/fbioe.2020.624621", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615960400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, HA; Liu, LX; Wang, JG; Zhou, Y; Hu, HA; Ye, XL; Liu, GC; Xu, ZX; Xu, H; Yang, W; Wang, YW; Peng, Y; Yang, PH; Sun, JQ; Yan, P; Cao, XH; Tang, BZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Huanull; Liu, Lingxiu; Wang, Jianguo; Zhou, Ying; Hu, Huanull; Ye, Xinglin; Liu, Guochang; Xu, Zhixiong; Xu, Han; Yang, Wen; Wang, Yawei; Peng, You; Yang, Pinghua; Sun, Jianqi; Yan, Ping; Cao, Xiaohua; Tang, Ben Zhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aggregation caused quenching to aggregation induced emission transformation: a precise tuning based on BN-doped polycyclic aromatic hydrocarbons toward subcellular organelle specific imaging", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polycyclic aromatic hydrocarbons (PAHs) with boron-nitrogen (BN) moieties have attracted tremendous interest due to their intriguing electronic and optoelectronic properties. However, most of the BN-fused pi-systems reported to date are difficult to modify and exhibit traditional aggregation-caused quenching (ACQ) characteristics. This phenomenon greatly limits their scope of application. Thus, continuing efforts to seek novel, structurally distinct and functionally diverse structures are highly desirable. Herein, we proposed a one-stone-two-birds strategy including simultaneous exploration of reactivity and tuning of the optical and electronic properties for BN-containing pi-skeletons through flexible regioselective functionalization engineering. In this way, three novel functionalized BN luminogens (DPA-BN-BFT, MeO-DPA-BN-BFT and DMA-DPA-BN-BFT) with similar structures were obtained. Intriguingly, DPA-BNBFT, MeO-DPA-BN-BFT and DMA-DPA-BN-BFT exhibit completely different emission behaviors. Fluorogens DPA-BN-BFT and MeO-DPA-BN-BFT exhibit a typical ACQ effect; in sharp contrast, DMADPA-BN-BFT possesses a prominent aggregation induced emission (AIE) effect. To the best of our knowledge, this is the first report to integrate ACQ and AIE properties into one BN aromatic backbone with subtle modified structures. Comprehensive analysis of the crystal structure and theoretical calculations reveal that relatively large twisting angles, multiple intermolecular interactions and tight crystal packing modes endow DMA-DPA-BN-BFT with strong AIE behavior. More importantly, cell imaging demonstrated that luminescent materials DPA-BN-BFT and DMA-DPA-BN-BFT can highly selectively and sensitively detect lipid droplets (LDs) in living MCF-7 cells. Overall, this work provides a new viewpoint of the rational design and synthesis of advanced BN-polycyclic aromatics with AIE features and triggers the discovery of new functions and properties of azaborine chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 94, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2022, "Volume": 13, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3129, "End Page": 3139, "Article Number": null, "DOI": "10.1039/d2sc00380e", "DOI Link": "http://dx.doi.org/10.1039/d2sc00380e", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754013500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, SJ; Yang, XX; Li, QH; Zhang, YG; Zhou, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Shijie; Yang, Xiaoxiao; Li, Qinghai; Zhang, Yanguo; Zhou, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breaking the temperature limit of hydrothermal carbonization of lignocellulosic biomass by decoupling temperature and pressure", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrothermal carbonization (HTC) of lignocellulosic biomass is a promising technology for the production of carbon materials with negative carbon emissions. However, the high reaction temperature and energy consumption have limited the development of HTC technology. In conventional batch reactors, the temperature and pressure are typically coupled at saturated states. In this study, a decoupled temperature and pressure hydrothermal (DTPH) reaction system was developed to decrease the temperature of the HTC reaction of lignocellulosic biomass (rice straw and poplar leaves). The properties of hydrochars were analyzed by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, X-ray diffraction (XRD), thermogravimetric analyzer (TGA), etc. to propose the reaction mechanism. The results showed that the HTC reaction of lignocellulosic biomass could be realized at a low temperature of 200 & DEG;C in the DTPH process, breaking the temperature limit (230 & DEG;C) in the conventional process. The DTPH method could break the barrier of the crystalline structure of cellulose in the lignocellulosic biomass with high cellulose content, realizing the carbonization of cellulose and hemicellulose with the dehydration, unsaturated bond formation, and aromatization. The produced hydrochar had an appearance of carbon microspheres, with high calorific values, abundant oxygen-containing functional groups, a certain degree of graphitization, and good thermal stability. Cellulose acts not only as a barrier to protect itself and hemicellulose from decomposition, but also as a key precursor for the formation of carbon microspheres. This study shows a promising method for synthesizing carbon materials from lignocellulosic biomass with a carbon-negative effect.& COPY; 2023 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communi-cations Co., Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1216, "End Page": 1227, "Article Number": null, "DOI": "10.1016/j.gee.2023.01.001", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2023.01.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001034546300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ninarello, A; Berthier, L; Coslovich, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ninarello, Andrea; Berthier, Ludovic; Coslovich, Daniele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Models and Algorithms for the Next Generation of Glass Transition Studies", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Successful computer studies of glass-forming materials need to overcome both the natural tendency to structural ordering and the dramatic increase of relaxation times at low temperatures. We present a comprehensive analysis of eleven glass-forming models to demonstrate that both challenges can be efficiently tackled using carefully designed models of size polydisperse supercooled liquids together with an efficient Monte Carlo algorithm where translational particle displacements are complemented by swaps of particle pairs. We study a broad range of size polydispersities, using both discrete and continuous mixtures, and we systematically investigate the role of particle softness, attractivity, and nonadditivity of the interactions. Each system is characterized by its robustness against structural ordering and by the efficiency of the swap Monte Carlo algorithm. We show that the combined optimization of the potential's softness, polydispersity, and nonadditivity leads to novel computer models with excellent glass-forming ability. For such models, we achieve over 10 orders of magnitude gain in the equilibration time scale using the swap Monte Carlo algorithm, thus paving the way to computational studies of static and thermodynamic properties under experimental conditions. In addition, we provide microscopic insight into the performance of the swap algorithm, which should help optimize models and algorithms even further.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 301, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2017, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21039, "DOI": "10.1103/PhysRevX.7.021039", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.7.021039", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402816600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Miao, P; Teimourpour, MH; Malzard, S; El-Ganainy, R; Schomerus, H; Feng, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Han; Miao, Pei; Teimourpour, Mohammad H.; Malzard, Simon; El-Ganainy, Ramy; Schomerus, Henning; Feng, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological hybrid silicon microlasers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological physics provides a robust framework for strategically controlling wave confinement and propagation dynamics. However, current implementations have been restricted to the limited design parameter space defined by passive topological structures. Active systems provide a more general framework where different fundamental symmetry paradigms, such as those arising from non-Hermiticity and nonlinear interaction, can generate a new landscape for topological physics and its applications. Here, we bridge this gap and present an experimental investigation of an active topological photonic system, demonstrating a topological hybrid silicon microlaser array respecting the charge-conjugation symmetry. The created new symmetry features favour the lasing of a protected zero mode, where robust single-mode laser action in the desired state prevails even with intentionally introduced perturbations. The demonstrated microlaser is hybrid implemented on a silicon-on-insulator substrate, and is thereby readily suitable for integrated silicon photonics with applications in optical communication and computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 379, "Times Cited, All Databases": 405, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 7", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 981, "DOI": "10.1038/s41467-018-03434-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03434-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426899300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, T; Zhao, FZ; Louie, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Ting; Zhao, Fangzhou; Louie, Steven G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Phases in Graphene nulloribbons: Junction States, Spin Centers, and Quantum Spin Chains", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show that semiconducting graphene nulloribbons (GNRs) of different width, edge, and end termination (synthesizable from molecular precursors with atomic precision) belong to different electronic topological classes. The topological phase of GNRs is protected by spatial symmetries and dictated by the terminating unit cell. We have derived explicit formulas for their topological invariants and shown that localized junction states developed between two GNRs of distinct topology may be tuned by lateral junction geometry. The topology of a GNR can be further modified by dopants, such as a periodic array of boron atoms. In a superlattice consisting of segments of doped and pristine GNRs, the junction states are stable spin centers, forming a Heisenberg antiferromagnetic spin 1/2 chain with tunable exchange interaction. The discoveries here not only are of scientific interest for studies of quasi-one-dimensional systems, but also open a new path for design principles of future GNR-based devices through their topological characters.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 119, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76401, "DOI": "10.1103/PhysRevLett.119.076401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.076401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407719400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Antonino, RSCMD; Fook, BRPL; Lima, VAD; Rached, RID; Lima, EPN; Lima, RJD; Covas, CAP; Fook, MVL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Martins de Queiroz Antonino, Rayane Santa Cruz; Paschoal Lia Fook, Bianca Rosa; de Oliveira Lima, Vitor Alexandre; de Farias Rached, Raid Icaro; Nascimento Lima, Eunice Paloma; da Silva Lima, Rodrigo Jose; Peniche Covas, Carlos Andres; Lia Fook, Marcus Vinicius", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation and Characterization of Chitosan Obtained from Shells of Shrimp (Litopenaeus vannamei Boone)", "Source Title": "MARINE DRUGS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The main source of commercial chitosan is the extensive deacetylation of its parent polymer chitin. It is present in green algae, the cell walls or fungi and in the exoskeleton of crustaceans. A novel procedure for preparing chitosan from shrimp shells was developed. The procedure involves two 10-minutes bleaching steps with ethanol after the usual demineralization and deproteinization processes. Before deacetylation, chitin was immersed in 12.5 M NaOH, cooled down and kept frozen for 24 h. The obtained chitosan was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), UV, X-ray diffraction (XRD) and viscosimetry. Samples of white chitosan with acetylation degrees below 9% were obtained, as determined by FTIR and UV-first derivative spectroscopy. The change in the morphology of samples was followed by SEM. The ash content of chitosan samples were all below 0.063%. Chitosan was soluble in 1% acetic acid with insoluble contents of 0.62% or less. XRD patterns exhibited the characteristic peaks of chitosan centered at 10 and 20 degrees in 2 q. The molecular weight of chitosan was between 2.3 and 2.8 x 10(5) g/mol. It is concluded that the procedure developed in the present work allowed obtaining chitosans with physical and chemical properties suitable for pharmaceutical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 15, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141, "DOI": "10.3390/md15050141", "DOI Link": "http://dx.doi.org/10.3390/md15050141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404235100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, CJ; Chen, YX; Kirschbaum, K; Appavoo, K; Sfeir, MY; Jin, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin; Appavoo, Kannatassen; Sfeir, Matthew Y.; Jin, Rongchao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural patterns at all scales in a nonmetallic chiral Au133(SR)52 nulloparticle", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Structural ordering is widely present in molecules and materials. However, the organization of molecules on the curved surface of nulloparticles is still the least understood owing to the major limitations of the current surface characterization tools. By the merits of x-ray crystallography, we reveal the structural ordering at all scales in a super robust 133-gold atom nulloparticle protected by 52 thiolate ligands, which is manifested in self-assembled hierarchical patterns starting from the metal core to the interfacial -S-Au-S- ladder-like helical stripes and further to the swirls of carbon tails. These complex surface patterns have not been observed in the smaller nulloparticles. We further demonstrate that the Au-133(SR)(52) nulloparticle exhibits nonmetallic features in optical and electron dynamics measurements. Our work uncovers the elegant self-organization strategies in assembling a highly robust nulloparticle and provides a conceptual advance in scientific understanding of pattern structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1500045", "DOI": "10.1126/sciadv.1500045", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216591000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Norte, RA; Moura, JP; Gröblacher, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Norte, R. A.; Moura, J. P.; Groblacher, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical Resonators for Quantum Optomechanics Experiments at Room Temperature", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All quantum optomechanics experiments to date operate at cryogenic temperatures, imposing severe technical challenges and fundamental constraints. Here, we present a novel design of on-chip mechanical resonators which exhibit fundamental modes with frequencies f and mechanical quality factors Q(m) sufficient to enter the optomechanical quantum regime at room temperature. We overcome previous limitations by designing ultrathin, high-stress silicon nitride (Si3N4) membranes, with tensile stress in the resonators' clamps close to the ultimate yield strength of the material. By patterning a photonic crystal on the SiN membranes, we observe reflectivities greater than 99%. These on-chip resonators have remarkably low mechanical dissipation, with Q(m) similar to 10(8), while at the same time exhibiting large reflectivities. This makes them a unique platform for experiments towards the observation of massive quantum behavior at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 285, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2016, "Volume": 116, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 147202, "DOI": "10.1103/PhysRevLett.116.147202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.116.147202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373587200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, WT; Sarabalis, CJ; Dahmani, YD; Patel, RN; Mayor, FM; McKenna, TP; Van Laer, R; Safavi-Naeini, AH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Wentao; Sarabalis, Christopher J.; Dahmani, Yanni D.; Patel, Rishi N.; Mayor, Felix M.; McKenna, Timothy P.; Van Laer, Raphael; Safavi-Naeini, Amir H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient bidirectional piezo-optomechanical transduction between microwave and optical frequency", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient interconversion of both classical and quantum information between microwave and optical frequency is an important engineering challenge. The optomechanical approach with gigahertz-frequency mechanical devices has the potential to be extremely efficient due to the large optomechanical response of common materials, and the ability to localize mechanical energy into a micron-scale volume. However, existing demonstrations suffer from some combination of low optical quality factor, low electrical-to-mechanical transduction efficiency, and low optomechanical interaction rate. Here we demonstrate an on-chip piezo-optomechanical transducer that systematically addresses all these challenges to achieve nearly three orders of magnitude improvement in conversion efficiency over previous work. Our modulator demonstrates acousto-optic modulation with V = 0.02 V. We show bidirectional conversion efficiency of 10-5 with 3.3 mu W red-detuned optical pump, and 5.5% with 323 mu W blue-detuned pump. Further study of quantum transduction at millikelvin temperatures is required to understand how the efficiency and added noise are affected by reduced mechanical dissipation, thermal conductivity, and thermal capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1166, "DOI": "10.1038/s41467-020-14863-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14863-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519260700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rose, BC; Huang, D; Zhang, ZH; Stevenson, P; Tyryshkin, AM; Sangtawesin, S; Srinivasan, S; Loudin, L; Markham, ML; Edmonds, AM; Twitchen, DJ; Lyon, SA; de Leon, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rose, Brendon C.; Huang, Ding; Zhang, Zi-Huai; Stevenson, Paul; Tyryshkin, Alexei M.; Sangtawesin, Sorawis; Srinivasan, Srikanth; Loudin, Lorne; Markham, Matthew L.; Edmonds, Andrew M.; Twitchen, Daniel J.; Lyon, Stephen A.; de Leon, Nathalie P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of an environmentally insensitive solid-state spin defect in diamond", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering coherent systems is a central goal of quantum science. Color centers in diamond are a promising approach, with the potential to combine the coherence of atoms with the scalability of a solid-state platform. We report a color center that shows insensitivity to environmental decoherence caused by phonons and electric field noise: the neutral charge state of silicon vacancy (SiV0). Through careful materials engineering, we achieved >80% conversion of implanted silicon to SiV0. SiV0 exhibits spin-lattice relaxation times approaching 1 minute and coherence times approaching 1 second. Its optical properties are very favorable, with similar to 90% of its emission into the zero-phonon line and near-transform-limited optical linewidths. These combined properties make SiV0 a promising defect for quantum network applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2018, "Volume": 361, "Issue": 6397, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 60, "End Page": 63, "Article Number": null, "DOI": "10.1126/science.aao0290", "DOI Link": "http://dx.doi.org/10.1126/science.aao0290", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437467100060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, KY; Finney, NR; Zhang, J; Moore, SL; Xian, LD; Tancogne-Dejean, N; Liu, F; Ardelean, J; Xu, XY; Halbertal, D; Watanabe, K; Taniguchi, T; Ochoa, H; Asenjo-Garcia, A; Zhu, XY; Basov, DN; Rubio, A; Dean, CR; Hone, J; Schuck, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Kaiyuan; Finney, Nathan R.; Zhang, Jin; Moore, Samuel L.; Xian, Lede; Tancogne-Dejean, Nicolas; Liu, Fang; Ardelean, Jenny; Xu, Xinyi; Halbertal, Dorri; Watanabe, K.; Taniguchi, T.; Ochoa, Hector; Asenjo-Garcia, Ana; Zhu, Xiaoyang; Basov, D. N.; Rubio, Angel; Dean, Cory R.; Hone, James; Schuck, P. James", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced tunable second harmonic generation from twistable interfaces and vertical superlattices in boron nitride homostructures", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broken symmetries induce strong even-order nonlinear optical responses in materials and at interfaces. Unlike conventional covalently bonded nonlinear crystals, van der Waals (vdW) heterostructures feature layers that can be stacked at arbitrary angles, giving complete control over the presence or lack of inversion symmetry at a crystal interface. Here, we report highly tunable second harmonic generation (SHG) from nullomechanically rotatable stacks of bulk hexagonal boron nitride (BN) crystals and introduce the term twistoptics to describe studies of optical properties in twistable vdW systems. By suppressing residual bulk effects, we observe SHG intensity modulated by a factor of more than 50, and polarization patterns determined by moire interface symmetry. Last, we demonstrate greatly enhanced conversion efficiency in vdW vertical superlattice structures with multiple symmetry-broken interfaces. Our study paves the way for compact twistoptics architectures aimed at efficient tunable frequency conversion and demonstrates SHG as a robust probe of buried vdW interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 109, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe8691", "DOI": "10.1126/sciadv.abe8691", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe8691", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625411900014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, L; Xiao, W; Zhao, MV; Yu, XZ; Wang, HT; Wang, QQ; Chu, S; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Lei; Xiao, Wang; Zhao, Mervin; Yu, Xuanze; Wang, Haotian; Wang, Qiqi; Chu, Steven; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Can N95 Respirators Be Reused after Disinfection? How Many Times?", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The coronavirus disease 2019 (COVID-19) pandemic has led to a major shortage of N95 respirators, which are essential for protecting healthcare professionals and the general public who may come into contact with the virus. Thus, it is essential to determine how we can reuse respirators and other personal protective equipment in these urgent times. We investigated multiple commonly used disinfection schemes on media with particle filtration efficiency of 95%. Heating was recently found to inactivate the virus in solution within 5 min at 70 degrees C and is among the most scalable, user-friendly methods for viral disinfection. We found that heat (<= 85 degrees C) under various humidities (<= 100% relative humidity, RH) was the most promising, nondestructive method for the preservation of filtration properties in meltblown fabrics as well as N95-grade respirators. At 85 degrees C, 30% RH, we were able to perform 50 cycles of heat treatment without significant changes in the filtration efficiency. At low humidity or dry conditions, temperatures up to 100 degrees C were not found to alter the filtration efficiency significantly within 20 cycles of treatment. Ultraviolet (UV) irradiation was a secondary choice, which was able to withstand 10 cycles of treatment and showed small degradation by 20 cycles. However, UV can potentially impact the material strength and subsequent sealing of respirators. Finally, treatments involving liquids and vapors require caution, as steam, alcohol, and household bleach all may lead to degradation of the filtration efficiency, leaving the user vulnerable to the viral aerosols.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 334, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2020, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6348, "End Page": 6356, "Article Number": null, "DOI": "10.1021/acsnullo.0c03597", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c03597", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537682300117", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YI; Shao, Q; Zhang, J; Yang, LJ; Gao, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yi Isaac; Shao, Qiang; Zhang, Jun; Yang, Lijiang; Gao, Yi Qin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced sampling in molecular dynamics", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although molecular dynamics simulations have become a useful tool in essentially all fields of chemistry, condensed matter physics, materials science, and biology, there is still a large gap between the time scale which can be reached in molecular dynamics simulations and that observed in experiments. To address the problem, many enhanced sampling methods were introduced, which effectively extend the time scale being approached in simulations. In this perspective, we review a variety of enhanced sampling methods. We first discuss collective-variables-based methods including metadynamics and variationally enhanced sampling. Then, collective variable free methods such as parallel tempering and integrated tempering methods are presented. At last, we conclude with a brief introduction of some newly developed combinatory methods. We summarize in this perspective not only the theoretical background and numerical implementation of these methods but also the new challenges and prospects in the field of the enhanced sampling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2019, "Volume": 151, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 70902, "DOI": "10.1063/1.5109531", "DOI Link": "http://dx.doi.org/10.1063/1.5109531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482456100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, MH; Rivera, P; Tuan, DV; Wilson, NP; Yang, M; Taniguchi, T; Watanabe, K; Yan, JQ; Mandrus, DG; Yu, HY; Dery, H; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Minhao; Rivera, Pasqual; Dinh Van Tuan; Wilson, Nathan P.; Yang, Min; Taniguchi, Takashi; Watanabe, Kenji; Yan, Jiaqiang; Mandrus, David G.; Yu, Hongyi; Dery, Hanull; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valley phonons and exciton complexes in a monolayer semiconductor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The coupling between spin, charge, and lattice degrees of freedom plays an important role in a wide range of fundamental phenomena. Monolayer semiconducting transitional metal dichalcogenides have emerged as an outstanding platform for studying these coupling effects. Here, we report the observation of multiple valley phonons - phonons with momentum vectors pointing to the corners of the hexagonal Brillouin zone - and the resulting exciton complexes in the monolayer semiconductor WSe2. We find that these valley phonons lead to efficient intervalley scattering of quasi particles in both exciton formation and relaxation. This leads to a series of photoluminescence peaks as valley phonon replicas of dark trions. Using identified valley phonons, we also uncover an intervalley exciton near charge neutrality. Our work not only identifies a number of previously unknown 2D excitonic species, but also shows that monolayer WSe2 is a prime candidate for studying interactions between spin, pseudospin, and zone-edge phonons. In monolayer semiconductors phonons with momentum vectors pointing to the corners of the hexagonal Brillouin zone couple strongly to carriers' spin and valley degree of freedom. Here, the authors report the observation of multiple valley phonons and the resulting exciton complexes in the monolayer semiconductor WSe2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-020-14472-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14472-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543986200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XS; Yuan, HY; Wang, XR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, X. S.; Yuan, H. Y.; Wang, X. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A theory on skyrmion size", "Source Title": "COMMUNICATIONS PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A magnetic skyrmion is a topological object consisting of a skyrmion core, an outer domain, and a wall that separates the skyrmion core from the outer domain. The skyrmion size and wall width are two fundamental quantities of a skyrmion that depend sensitively on material parameters such as exchange energy, magnetic anisotropy, Dzyaloshinskii-Moriya interaction, and magnetic field. However, quantitative understanding of the two quantities is still very poor. Here we present a general theory on skyrmion size and wall width. The two formulas we obtained agree almost perfectly with simulations and experiments for a wide range of parameters, including most of the existing materials that support skyrmions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2018, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1038/s42005-018-0029-0", "DOI Link": "http://dx.doi.org/10.1038/s42005-018-0029-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437244000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Garza, AJ; Scuseria, GE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garza, Alejandro J.; Scuseria, Gustavo E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Predicting Band Gaps with Hybrid Density Functionals", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We compare the ability of four popular hybrid density functionals (B3LYP, B3PW91, HSE, and PBE0) for predicting band gaps of semiconductors and insulators over a large benchmark set using a consistent methodology. We observe no significant statistical difference in their overall performance, although the screened hybrid HSE is more accurate for typical semiconductors. HSE can improve its accuracy for large band gap materials-without affecting that of semiconductors-by including a larger portion of Hartree-Fock exchange in its short-range. Given that screened hybrids are computationally much less expensive than their global counterparts, we conclude that they are a better option for the black box prediction of band gaps.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2016, "Volume": 7, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4165, "End Page": 4170, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b01807", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b01807", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386106600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shinotsuka, H; Tanuma, S; Powell, CJ; Penn, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shinotsuka, H.; Tanuma, S.; Powell, C. J.; Penn, D. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Calculations of electron inelastic mean free paths. X. Data for 41 elemental solids over the 50eV to 200keV range with the relativistic full Penn algorithm", "Source Title": "SURFACE AND INTERFACE ANALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have calculated inelastic mean free paths (IMFPs) for 41 elemental solids (Li, Be, graphite, diamond, glassy C, Na, Mg, Al, Si, K, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Ge, Y, Nb, Mo, Ru, Rh, Pd, Ag, In, Sn, Cs, Gd, Tb, Dy, Hf, Ta, W, Re, Os, Ir, Pt, Au, and Bi) for electron energies from 50eV to 200keV. The IMFPs were calculated from measured energy loss functions for each solid with a relativistic version of the full Penn algorithm. The calculated IMFPs could be fitted to a modified form of the relativistic Bethe equation for inelastic scattering of electrons in matter for energies from 50eV to 200keV. The average root-mean-square (RMS) deviation in these fits was 0.68%. The IMFPs were also compared with IMFPs from a relativistic version of our predictive Tanuma, and Powell and Penn (TPP-2M) equation that was developed from a modified form of the relativistic Bethe equation. In these comparisons, the average RMS deviation was 11.9% for energies between 50eV and 200keV. This RMS deviation is almost the same as that found previously in a similar comparison for the 50eV to 30keV range (12.3%). Relatively large RMS deviations were found for diamond, graphite, and cesium as in our previous comparisons. If these three elements were excluded in the comparisons, the average RMS deviation was 8.9% between 50eV and 200keV. The relativistic TPP-2M equation can thus be used to estimate IMFPs in solid materials for energies between 50eV and 200keV. We found satisfactory agreement between our calculated IMFPs and those from recent calculations and from measurements at energies of 100 and 200keV. Copyright (c) 2015 John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 290, "Times Cited, All Databases": 316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 47, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 871, "End Page": 888, "Article Number": null, "DOI": "10.1002/sia.5789", "DOI Link": "http://dx.doi.org/10.1002/sia.5789", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359626300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ying, PJ; Wilkens, L; Reith, H; Rodriguez, NP; Hong, XC; Lu, QQ; Hess, C; Nielsch, K; He, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ying, Pingjun; Wilkens, Lennart; Reith, Heiko; Rodriguez, Nicolas Perez; Hong, Xiaochen; Lu, Qiongqiong; Hess, Christian; Nielsch, Kornelius; He, Ran", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A robust thermoelectric module based on MgAgSb/Mg3(Sb,Bi)2 with a conversion efficiency of 8.5% and a maximum cooling of 72 K", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The applications of thermoelectric (TE) technology around room temperature are monopolized by bismuth telluride (Bi2Te3). However, due to the toxicity and scarcity of tellurium (Te), it is vital to develop a next-generation technology to mitigate the potential bottleneck in raw material supply for a sustainable future. Hereby, we develop a Te-free n-type compound Mg3Sb0.6Bi1.4 for near-room-temperature applications. A higher sintering temperature of up to 1073 K is found to be beneficial for reducing the electrical resistivity, but only if Mg is heavily overcompensated in the initial stoichiometry. The optimizations of processing and doping yield a high average zT of 1.1 in between 300 K and 573 K. Together with the p-type MgAgSb, we demonstrate module-level conversion efficiencies of 3% and 8.5% under temperature differences of 75 K and 260 K, respectively, and concomitantly a maximum cooling of 72 K when the module is used as a cooler. Besides, the module displays exceptional thermal robustness with a < 10% loss of the output power after thermal cycling for similar to 32 000 times between 323 K and 500 K. These proof-of-principle demonstrations will pave the way for robust, high-performance, and sustainable solid-state power generation and cooling to substitute highly scarce and toxic Bi2Te3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2022, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2557, "End Page": 2566, "Article Number": null, "DOI": "10.1039/d2ee00883a", "DOI Link": "http://dx.doi.org/10.1039/d2ee00883a", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000795995400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CL; Li, XG; Xu, HK; Li, ZY; Wang, JH; Yang, Z; Mi, ZY; Liang, XH; Su, T; Yang, CH; Wang, GY; Wang, WY; Li, YC; Chen, M; Li, CY; Linghu, KH; Han, JX; Zhang, YS; Feng, YL; Song, Y; Ma, T; Zhang, JN; Wang, RX; Zhao, P; Liu, WY; Xue, GM; Jin, YR; Yu, HF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenlu; Li, Xuegang; Xu, Huikai; Li, Zhiyuan; Wang, Junhua; Yang, Zhen; Mi, Zhenyu; Liang, Xuehui; Su, Tang; Yang, Chuhong; Wang, Guangyue; Wang, Wenyan; Li, Yongchao; Chen, Mo; Li, Chengyao; Linghu, Kehuan; Han, Jiaxiu; Zhang, Yingshan; Feng, Yulong; Song, Yu; Ma, Teng; Zhang, Jingning; Wang, Ruixia; Zhao, Peng; Liu, Weiyang; Xue, Guangming; Jin, Yirong; Yu, Haifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards practical quantum computers: transmon qubit with a lifetime approaching 0.5 milliseconds", "Source Title": "NPJ QUANTUM INFORMATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we report a breakthrough in the fabrication of a long lifetime transmon qubit. We use tantalum films as the base superconductor. By using a dry etching process, we obtained transmon qubits with a best T-1 lifetime of 503 mu s. As a comparison, we also fabricated transmon qubits with other popular materials, including niobium and aluminum, under the same design and fabrication processes. After characterizing their coherence properties, we found that qubits prepared with tantalum films have the best performance. Since the dry etching process is stable and highly anisotropic, it is much more suitable for fabricating complex scalable quantum circuits, when compared to wet etching. As a result, the current breakthrough indicates that the dry etching process of tantalum film is a promising approach to fabricate medium- or large-scale superconducting quantum circuits with a much longer lifetime, meeting the requirements for building practical quantum computers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3, "DOI": "10.1038/s41534-021-00510-2", "DOI Link": "http://dx.doi.org/10.1038/s41534-021-00510-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742352300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JL; Wang, X; Mei, KC; Chang, CH; Jiang, JH; Liu, XS; Liu, Q; Guiney, LM; Hersam, MC; Liao, YP; Meng, H; Xia, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiulong; Wang, Xiang; Mei, Kuo-Ching; Chang, Chong Hyun; Jiang, Jinhong; Liu, Xiangsheng; Liu, Qi; Guiney, Linda M.; Hersam, Mark C.; Liao, Yu-Pei; Meng, Huan; Xia, Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lateral size of graphene oxide determines differential cellular uptake and cell death pathways in Kupffer cells, LSECs, and hepatocytes", "Source Title": "nullO TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a representative two-dimensional (2D) nullomaterial, graphene oxide (GO) has shown high potential in many applications due to its large surface area, high flexibility, and excellent dispersibility in aqueous solutions. These properties make GO an ideal candidate for bio-imaging, drug delivery, and cancer therapy. When delivered to the body, GO has been shown to accumulate in the liver, the primary accumulation site of systemic delivery or secondary spread from other uptake sites, and induce liver toxicity. However, the contribution of the GO physicochemical properties and individual liver cell types to this toxicity is unclear due to property variations and diverse cell types in the liver. Herein, we compare the effects of GOs with small (GO-S) and large (GO-L) lateral sizes in three major cell types in the liver, Kupffer cells (KCs), liver sinusoidal endothelial cells (LSECs), and hepatocytes. While GOs induced cytotoxicity in KCs, they induced significantly less toxicity in LSECs and hepatocytes. For KCs, we found that GOs were phagocytosed that triggered NADPH oxidase mediated plasma membrane lipid peroxidation, which leads to PLC activation, calcium flux, mitochondrial ROS generation, and NLRP3 inflammasome activation. The subsequent caspase-1 activation induced IL-1 beta production and GSDMD-mediated pyroptosis. These effects were lateral sizedependent with GO-L showing stronger effects than GO-S. Amongst the liver cell types, decreased cell association and the absence of lipid peroxidation resulted in low cytotoxicity in LSECs and hepatocytes. Using additional GO samples with different lateral sizes, surface functionalities, or thickness, we further confirmed the differential cytotoxic effects in liver cells and the major role of GO lateral size in KUP5 pyroptosis by correlation studies. These findings delineated the GO effects on cellular uptake and cell death pathways in liver cells, and provide valuable information to further evaluate GO effects on the liver for biomedical applications. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 37, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101061, "DOI": "10.1016/j.nulltod.2020.101061", "DOI Link": "http://dx.doi.org/10.1016/j.nulltod.2020.101061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637809700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "France, RM; Geisz, JF; Song, T; Olavarria, W; Young, M; Kibbler, A; Steiner, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "France, Ryan M.; Geisz, John F.; Song, Tao; Olavarria, Waldo; Young, Michelle; Kibbler, Alan; Steiner, Myles A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triple-junction solar cells with 39.5% terrestrial and 34.2% space efficiency enabled by thick quantum well superlattices", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multijunction solar cell design is guided by both the theoretical optimal bandgap combination as well as the realistic limitations to materials with these bandgaps. For instance, triple-junction III-V multijunction solar cells commonly use GaAs as a middle cell because of its near-perfect material quality, despite its bandgap being higher than optimal for the global spectrum. Here, we modify the middle cell bandgap using thick GaInAs/GaAsP strain-balanced quantum well (QW) solar cells with excellent voltage and absorption. These high-performance QWs are incorporated into a triple-junction inverted metamorphic multijunction device consisting of a GaInP top cell, GaInAs/GaAsP QW middle cell, and lattice-mismatched GaInAs bottom cell, each of which has been highly optimized. We demonstrate triple-junction efficiencies of 39.5% and 34.2% under the AM1.5 global and AM0 space spectra, respectively, and the global efficiency is higher than previous record six-junction devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2022, "Volume": 6, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1121, "End Page": 1135, "Article Number": null, "DOI": "10.1016/j.joule.2022.04.024", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.04.024", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000832847800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tatarchuk, T; Bououdina, M; Macyk, W; Shyichuk, O; Paliychuk, N; Yaremiy, I; Al-Najar, B; Pacia, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tatarchuk, Tetiana; Bououdina, Mohamed; Macyk, Wojciech; Shyichuk, Olexander; Paliychuk, Natalia; Yaremiy, Ivan; Al-Najar, Basma; Pacia, Michal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural, Optical, and Magnetic Properties of Zn-Doped CoFe2O4 nulloparticles", "Source Title": "nullOSCALE RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The effect of Zn-doping in CoFe2O4 nulloparticles (NPs) through chemical co-precipitation route was investigated in term of structural, optical, and magnetic properties. Both XRD and FTIR analyses confirm the formation of cubic spinel phase, where the crystallite size changes with Zn content from 46 to 77 nm. The Scherrer method, Williamson-Hall (W-H) analysis, and size-strain plot method (SSPM) were used to study of crystallite sizes. The TEM results were in good agreement with the results of the SSP method. SEM observations reveal agglomeration of fine spherical-like particles. The optical band gap energy determined from diffuse reflectance spectroscopy (DRS) varies increases from 1.17 to 1.3 eV. Magnetization field loops reveal a ferromagnetic behavior with lower hysteresis loop for higher Zn content. The magnetic properties are remarkably influenced with Zn doping; saturation magnetization (M-s) increases then decreases while both coercivity (HC) and remanent magnetization (M-r) decrease continuously, which was associated with preferential site occupancy and the change in particle size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2017, "Volume": 12, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141, "DOI": "10.1186/s11671-017-1899-x", "DOI Link": "http://dx.doi.org/10.1186/s11671-017-1899-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397584600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feldmann, J; Stegmaier, M; Gruhler, N; Ríos, C; Bhaskaran, H; Wright, CD; Pernice, WHP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feldmann, J.; Stegmaier, M.; Gruhler, N.; Rios, C.; Bhaskaran, H.; Wright, C. D.; Pernice, W. H. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Calculating with light using a chip-scale all-optical abacus", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machines that simultaneously process and store multistate data at one and the same location can provide a new class of fast, powerful and efficient general-purpose computers. We demonstrate the central element of an all-optical calculator, a photonic abacus, which provides multistate compute-and-store operation by integrating functional phase-change materials with nullophotonic chips. With picosecond optical pulses we perform the fundamental arithmetic operations of addition, subtraction, multiplication, and division, including a carryover into multiple cells. This basic processing unit is embedded into a scalable phase-change photonic network and addressed optically through a two-pulse random access scheme. Our framework provides first steps towards light-based non-von Neumann arithmetic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 2", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1256, "DOI": "10.1038/s41467-017-01506-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01506-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414245000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, H; Zhang, CW; Ji, WX; Zhang, RW; Li, SS; Yan, SS; Zhang, BM; Li, P; Wang, PJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Hui; Zhang, Chang-wen; Ji, Wei-xiao; Zhang, Run-wu; Li, Sheng-shi; Yan, Shi-shen; Zhang, Bao-min; Li, Ping; Wang, Pei-ji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unexpected Giant-Gap Quantum Spin Hall Insulator in Chemically Decorated Plumbene Monolayer", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin Hall (QSH) effect of two-dimensional (2D) materials features edge states that are topologically protected from backscattering by time-reversal symmetry. However, the major obstacles to the application for QSH effect are the lack of suitable QSH insulators with a large bulk gap. Here, we predict a novel class of 2D QSH insulators in X-decorated plumbene monolayers (PbX; X = H, F, Cl, Br, I) with extraordinarily giant bulk gaps from 1.03 eV to a record value of 1.34 eV. The topological characteristic of PbX mainly originates from s-p(x,y) band inversion related to the lattice symmetry, while the effect of spin-orbital coupling (SOC) is only to open up a giant gap. Their QSH states are identified by nontrivial topological invariant Z(2) = 1, as well as a single pair of topologically protected helical edge states locating inside the bulk gap. Noticeably, the QSH gaps of PbX are tunable and robust via external strain. We also propose high-dielectric-constant BN as an ideal substrate for the experimental realization of PbX, maintaining its nontrivial topology. These novel QSH insulators with giant gaps are a promising platform to enrich topological phenomena and expand potential applications at high temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 205, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20152, "DOI": "10.1038/srep20152", "DOI Link": "http://dx.doi.org/10.1038/srep20152", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369139700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Meng, XN; Li, YC; AlMasoud, N; Wang, WS; Alomar, TS; Li, J; Ye, XM; Algadi, H; Seok, I; Li, HD; Bin Xu, B; Lu, N; El-Bahy, ZM; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Meng, Xiangning; Li, Yingchun; AlMasoud, Najla; Wang, Wensheng; Alomar, Taghrid S.; Li, Jie; Ye, Xinming; Algadi, Hassan; Seok, Ilwoo; Li, Handong; Bin Xu, Ben; Lu, Na; El-Bahy, Zeinhom M.; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compatibilizing and toughening blends of recycled acrylonitrile-butadiene-styrene/recycled high impact polystyrene blends via styrene-butadiene-glycidyl methacrylate terpolymer", "Source Title": "POLYMER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To increase the effectiveness of recovered acrylonitrile-butadiene-styrene (rABS) and recycled high impact polystyrene (rHIPS), styrene-butadiene-glycidyl methacrylate (SBG) was incorporated to the rABS/rHIPS system by melt blending for the first time. Multiple epoxy groups in SBG can combine with the butadiene ageing groups in rABS/rHIPS to generate ester groups, repairing the broken molecular chains, improving the compatibility between the two phases, and enhancing the mechanical properties of the blends. The findings demonstrated that adding SBG greatly increased the blends' molecular weight, impact strength, tensile strength, flexural strength, storage modulus, loss modulus, and complex viscosity. When SBG content was 8 wt%, the notch impact strength of the blends reached 8.84 kJ/m2, which was 108% higher than that of rABS/rHIPS. In addition, the interface between polybutadiene (PB) phase and styrene-acrylonitrile copolymer (SAN) phase became more blurred, and the compatibility of the two phases was improved, which enabled the high-value recovery of rABS/rHIPS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2023, "Volume": 272, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125856, "DOI": "10.1016/j.polymer.2023.125856", "DOI Link": "http://dx.doi.org/10.1016/j.polymer.2023.125856", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000956922300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YQ; Mak, CH; Zhang, J; Jia, GH; Cheng, KC; Song, HS; Yuan, MJ; Zhao, SJ; Kai, JJ; Colmenares, JC; Hsu, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yunqi; Mak, Chun Hong; Zhang, Jun; Jia, Guohua; Cheng, Kuan-Chen; Song, Haisheng; Yuan, Mingjian; Zhao, Shijun; Kai, Ji-Jung; Colmenares, Juan Carlos; Hsu, Hsien-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unravelling the Interfacial Dynamics of Bandgap Funneling in Bismuth-Based Halide Perovskites", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An environmentally friendly mixed-halide perovskite MA(3)Bi(2)Cl(9-)(x)I(x) with a bandgap funnel structure has been developed. However, the dynamic interfacial interactions of bandgap funneling in MA(3)Bi(2)Cl(9-)(x)I(x) perovskites in the photoelectrochemical (PEC) system remain ambiguous. In light of this, single- and mixed-halide lead-free bismuth-based hybrid perovskites-MA(3)Bi(2)Cl(9-)(y)I(y) and MA(3)Bi(2)I(9) (named MBCl-I and MBI)-in the presence and absence of the bandgap funnel structure, respectively, are prepared. Using temperature-dependent transient photoluminescence and electrochemical voltammetric techniques, the photophysical and (photo)electrochemical phenomena of solid-solid and solid-liquid interfaces for MBCl-I and MBI halide perovskites are therefore confirmed. Concerning the mixed-halide hybrid perovskites MBCl-I with a bandgap funnel structure, stronger electronic coupling arising from an enhanced overlap of electronic wavefunctions results in more efficient exciton transport. Besides, MBCl-I's effective diffusion coefficient and electron-transfer rate demonstrate efficient heterogeneous charge transfer at the solid-liquid interface, generating improved photoelectrochemical hydrogen production. Consequently, this combination of photophysical and electrochemical techniques opens up an avenue to explore the intrinsic and interfacial properties of semiconductor materials for elucidating the correlation between material characterization and device performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 35, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207835", "DOI Link": "http://dx.doi.org/10.1002/adma.202207835", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888939100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, MQ; Zhou, JC; Chen, D; Lu, HY; McLaughlin, NJ; Li, SL; Alghamdi, M; Djugba, D; Shi, J; Wang, HL; Du, CHR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Mengqi; Zhou, Jingcheng; Chen, Di; Lu, Hanyi; McLaughlin, Nathan J.; Li, Senlei; Alghamdi, Mohammed; Djugba, Dziga; Shi, Jing; Wang, Hailong; Du, Chunhui Rita", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wide field imaging of van der Waals ferromagnet Fe3GeTe2 by spin defects in hexagonal boron nitride", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride (h-BN) has been used extensively to encapsulate other van der Waals materials, protecting them from environmental degradation, and allowing integration into more complex heterostructures. Here, the authors make use of boron vacancy spin defects in h-BN using them to image the magnetic properties of a Fe3GeTe2 flake. Emergent color centers with accessible spins hosted by van der Waals materials have attracted substantial interest in recent years due to their significant potential for implementing transformative quantum sensing technologies. Hexagonal boron nitride (hBN) is naturally relevant in this context due to its remarkable ease of integration into devices consisting of low-dimensional materials. Taking advantage of boron vacancy spin defects in hBN, we report nulloscale quantum imaging of low-dimensional ferromagnetism sustained in Fe3GeTe2/hBN van der Waals heterostructures. Exploiting spin relaxometry methods, we have further observed spatially varying magnetic fluctuations in the exfoliated Fe3GeTe2 flake, whose magnitude reaches a peak value around the Curie temperature. Our results demonstrate the capability of spin defects in hBN of investigating local magnetic properties of layered materials in an accessible and precise way, which can be extended readily to a broad range of miniaturized van der Waals heterostructure systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5369, "DOI": "10.1038/s41467-022-33016-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33016-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000855320900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huberman, S; Duncan, RA; Chen, K; Song, B; Chiloyan, V; Ding, Z; Maznev, AA; Chen, G; Nelson, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huberman, S.; Duncan, R. A.; Chen, K.; Song, B.; Chiloyan, V.; Ding, Z.; Maznev, A. A.; Chen, G.; Nelson, K. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of second sound in graphite at temperatures above 100 K", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wavelike thermal transport in solids, referred to as second sound, is an exotic phenomenon previously limited to a handful of materials at low temperatures. The rare occurrence of this effect restricted its scientific and practical importance. We directly observed second sound in graphite at temperatures above 100 kelvins by using time-resolved optical measurements of thermal transport on the micrometer-length scale. Our experimental results are in qualitative agreement with ab initio calculations that predict wavelike phonon hydrodynamics. We believe that these results potentially indicate an important role of second sound in microscale transient heat transport in two-dimensional and layered materials in a wide temperature range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2019, "Volume": 364, "Issue": 6438, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 375, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav3548", "DOI Link": "http://dx.doi.org/10.1126/science.aav3548", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465643400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, ZR; Yang, XL; Li, W; Feng, TL; Ruan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Zherui; Yang, Xiaolong; Li, Wu; Feng, Tianli; Ruan, Xiulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FourPhonon: An extension module to ShengBTE for computing four-phonon scattering rates and thermal conductivity", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Four Phononis a computational package that can calculate four-phonon scattering rates in crystals. It is built withinShengBTEframework, which is a well-recognized lattice thermal conductivity solver based on Boltzmann transport equation. An adaptive energy broadening scheme is implemented for the calculation of four-phonon scattering rates. In analogy withthirdorder.pyinShengBTE, we also provide a separate python script, Fourthorder.py, to calculate fourth-order interatomic force constants. The extension module preserves all the nice features of the well-recognized lattice thermal conductivity solverShengBTE, including good parallelism and straightforward workflow. In this paper, we discuss the general theory, program design, and example calculations on Si, BAs and LiCoO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 254, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 270, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108179, "DOI": "10.1016/j.cpc.2021.108179", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.108179", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000708648400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, JJ; Al Sayem, A; Gong, Z; Surya, JB; Zou, CL; Tang, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Juanjuan; Al Sayem, Ayed; Gong, Zheng; Surya, Joshua B.; Zou, Chang-Ling; Tang, Hong X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultralow-threshold thin-film lithium niobate optical parametric oscillator", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with strong second-order (chi((2))) optical nonlinearity, especially lithium niobate, play a critical role in building optical parametric oscillators (OPOs). However, chip-scale integration of low-loss chi((2)) materials remains challenging and limits the threshold power of on-chip chi((2)) OPO. Herewe report an on-chip lithium niobate optical parametric oscillator at the telecom wavelengths using a quasi-phase-matched, high-quality microring resonator, whose threshold power (similar to 30 mu W) is 400 times lower than that in previous chi((2)) integrated photonics platforms. An on-chip power conversion efficiency of 11% is obtained from pump to signal and idler fields at a pump power of 93 mu W. The OPO wavelength tuning is achieved by varying the pump frequency and chip temperature. With the lowest power threshold among all on-chipOPOs demonstrated so far, aswell as advantages including high conversion efficiency, flexibility in quasi-phase-matching, and device scalability, the thin-film lithium niobate OPO opens new opportunities for chip-based tunable classical and quantum light sources and provides a potential platform for realizing photonic neural networks. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2021, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 539, "End Page": 544, "Article Number": null, "DOI": "10.1364/OPTICA.418984", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.418984", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000642200300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, GW; Buswell, R; Silva, WRLD; Wang, L; Xu, J; Jones, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Guowei; Buswell, Richard; Silva, Wilson Ricardo Leal da; Wang, Li; Xu, Jie; Jones, Scott Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Technology readiness: A global snapshot of 3D concrete printing and the frontiers for development", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the inception of 3D concrete printing (3DCP) in the early to mid-2000's, the commercial landscape for this technology has expanded rapidly in parallel with developments of relevant materials, production technologies and knowhow. To benchmark the state-of-the-art of 3DCP technology in the construction field, this study presents a systematic review and analysis of 3DCP's development and applications based on information from articles, patents and publicly available data. An estimation of Technology Readiness Level (TRL) for 3DCP has been formulated through expert review, and the evidence suggests this is in the region of TRL6-7 similar to that reported for polymer-based fused deposition modelling processes. A new schema for the TRL assessment process is suggested and applied to two case studies: 1) the production of decorative works; 2) the fabrication of dwellings. Finally, we have identified four frontiers for research and development that should be exploited to raise the TRL of 3DCP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 156, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106774, "DOI": "10.1016/j.cemconres.2022.106774", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2022.106774", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799142200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Antonopoulos, I; Faraca, G; Tonini, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Antonopoulos, Ioannis; Faraca, Giorgia; Tonini, Davide", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recycling of post-consumer plastic packaging waste in the EU: Recovery rates, material flows, and barriers", "Source Title": "WASTE MANAGEMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing plastic waste recycling is a milestone of European environmental policy to reduce environmental impacts and dependency on foreign resources. This is particularly challenging for plastic packaging waste, consisting of very heterogeneous fractions and typically rather contaminated. In this study, we collected primary data from plants sorting and recycling plastic packaging waste to illustrate process efficiencies, material flows, and barriers. We observed that significant losses of target materials occurred both at sorting and recycling stages. These were higher for polymers such as films, polypropylene and polystyrene, and lower for polyethylene terephthalate and high-density polyethylene. Applying material flow analysis, we estimated an overall end-of-life recycling rate for post-consumer plastic packaging waste in EU27 in 2017 of 14% (not considering waste exported as recycled; 25% otherwise). An improved scenario for 2030 showed that achieving an overall end-of-life recycling rate of about 49% was possible when best available practices and technologies were implemented. To fulfil the ambitious recycling targets set at EU27 level (55% overall recycling rate), substantial improvements are necessary at the plants, product design, collection system, and market level. Our findings further indicate that films and other problematic contaminullts in the input-waste considerably hamper the recovery rates, thus the improvement of the efficiency of the collection systems is imperative. In parallel, the development of markets for lower value fractions, e.g. polypropylene, could be a way forward to increase recycling, while improvements in the product design will considerably reduce the presence of impurities and contaminullts in the input-waste.& nbsp; (c) 2021 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2021, "Volume": 126, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 694, "End Page": 705, "Article Number": null, "DOI": "10.1016/j.wasman.2021.04.002", "DOI Link": "http://dx.doi.org/10.1016/j.wasman.2021.04.002", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000655589800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Q; Chen, C; Zhang, T; Peng, R; Yan, YJ; Wen, CHP; Lou, X; Huang, YL; Tian, JP; Dong, XL; Wang, GW; Bao, WC; Wang, QH; Yin, ZP; Zhao, ZX; Feng, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qin; Chen, Chen; Zhang, Tong; Peng, Rui; Yan, Ya-Jun; Wen, Chen-Hao-Ping; Lou, Xia; Huang, Yu-Long; Tian, Jin-Peng; Dong, Xiao-Li; Wang, Guang-Wei; Bao, Wei-Cheng; Wang, Qiang-Hua; Yin, Zhi-Ping; Zhao, Zhong-Xian; Feng, Dong-Lai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust and Clean Majorana Zero Mode in the Vortex Core of High-Temperature Superconductor (Li0.84Fe0.16)OHFeSe", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Majorana fermion, which is its own antiparticle and obeys non-Abelian statistics, plays a critical role in topological quantum computing. It can be realized as a bound state at zero energy, called a Majorana zero mode (MZM), in the vortex core of a topological superconductor, or at the ends of a nullowire when both superconductivity and strong spin orbital coupling are present. A MZM can be detected as a zero-bias conductance peak (ZBCP) in tunneling spectroscopy. However, in practice, clean and robust MZMs have not been realized in the vortices of a superconductor because of contamination from impurity states or other closely packed Caroli-de Gennes-Matricon (CdGM) states, which hampers further manipulations of MZMs. Here, using scanning tunneling spectroscopy, we show that a ZBCP well separated from the other discrete CdGM states exists ubiquitously in the cores of free vortices in the defect-free regions of (Li0.84Fe0.16)OHFeSe, which has a superconducting transition temperature of 42 K. Moreover, a Diraccone-type surface state is observed by angle-resolved photoemission spectroscopy, and its topological nature is confirmed by band calculations. The observed ZBCP can naturally be attributed to a MZM arising from the chiral topological surface state of a bulk superconductor. Thus, (Li0.84Fe0.16)OHFeSe provides an ideal platform for studying MZMs and topological quantum computing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2018, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41056, "DOI": "10.1103/PhysRevX.8.041056", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.8.041056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454636100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, YL; Pierce, AT; Park, JM; Parker, DE; Khalaf, E; Ledwith, P; Cao, Y; Lee, SH; Chen, SW; Forrester, PR; Watanabe, K; Taniguchi, T; Vishwanath, A; Jarillo-Herrero, P; Yacoby, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Yonglong; Pierce, Andrew T.; Park, Jeong Min; Parker, Daniel E.; Khalaf, Eslam; Ledwith, Patrick; Cao, Yuan; Lee, Seung Hwan; Chen, Shaowen; Forrester, Patrick R.; Watanabe, Kenji; Taniguchi, Takashi; Vishwanath, Ashvin; Jarillo-Herrero, Pablo; Yacoby, Amir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractional Chern insulators in magic-angle twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fractional Chern insulators (FCIs) are lattice analogues of fractional quantum Hall states that may provide a new avenue towards manipulating non-Abelian excitations. Early theoretical studies(1-7) have predicted their existence in systems with flat Chern bands and highlighted the critical role of a particular quantum geometry. However, FCI states have been observed only in Bernal-stacked bilayer graphene (BLG) aligned with hexagonal boron nitride (hBN)(8), in which a very large magnetic field is responsible for the existence of the Chern bands, precluding the realization of FCIs at zero field. By contrast, magic-angle twisted BLG(9-12) supports flat Chern bands at zero magnetic field(13-17), and therefore offers a promising route towards stabilizing zero-field FCIs. Here we report the observation of eight FCI states at low magnetic field in magic-angle twisted BLG enabled by high-resolution local compressibility measurements. The first of these states emerge at 5 T, and their appearance is accompanied by the simultaneous disappearance of nearby topologically trivial charge density wave states. We demonstrate that, unlike the case of the BLG/hBN platform, the principal role of the weak magnetic field is merely to redistribute the Berry curvature of the native Chern bands and thereby realize a quantum geometry favourable for the emergence of FCIs. Our findings strongly suggest that FCIs may be realized at zero magnetic field and pave the way for the exploration and manipulation of anyonic excitations in flat moire Chern bands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 270, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2021, "Volume": 600, "Issue": 7889, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 439, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04002-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04002-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000730754700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Botana, AS; Norman, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Botana, A. S.; Norman, M. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Similarities and Differences between LaNiO2 and CaCuO2 and Implications for Superconductivity", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent observation of superconductivity in hole-doped NdNiO2 has generated considerable attention. The similarities and differences between this infinite-layer nickelates and cuprates are still an open question. To address this issue we derive, via-principles calculations, essential facts related to the electronic structure and magnetism of RNiO2 (R = La, Nd) in comparison to their cuprate analog CaCuO2. From this detailed comparison, we find that RNiO2 are promising as cuprate analogs. Besides the much larger d - p energy splitting, and the presence of R 5d states near the Fermi energy in the parent compound, all other electronic-structure parameters seem to be favorable in the context of superconductivity as inferred from the cuprates. In particular, the large value of the longer-range hopping t' and the e(g) energy splitting are similar to those obtained in cuprates. Doping further acts to increase the cupratelike character of these nickelates by suppressing the self-doping effect of the R 5d bands.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11024, "DOI": "10.1103/PhysRevX.10.011024", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.10.011024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510844500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Omair, Z; Scranton, G; Pazos-Outón, LM; Xiao, TP; Steiner, MA; Ganapati, V; Peterson, PF; Holzrichter, J; Atwater, H; Yablonovitch, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Omair, Zunaid; Scranton, Gregg; Pazos-Outon, Luis M.; Xiao, T. Patrick; Steiner, Myles A.; Ganapati, Vidya; Peterson, Per F.; Holzrichter, John; Atwater, Harry; Yablonovitch, Eli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultraefficient thermophotovoltaic power conversion by band-edge spectral filtering", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermophotovoltaic power conversion utilizes thermal radiation from a local heat source to generate electricity in a photovoltaic cell. It was shown in recent years that the addition of a highly reflective rear mirror to a solar cell maximizes the extraction of luminescence. This, in turn, boosts the voltage, enabling the creation of record-breaking solar efficiency. Now we report that the rear mirror can be used to create thermophotovoltaic systems with unprecedented high thermophotovoltaic efficiency. This mirror reflects low-energy infrared photons back into the heat source, recovering their energy. Therefore, the rear mirror serves a dual function; boosting the voltage and reusing infrared thermal photons. This allows the possibility of a practical >50% efficient thermophotovoltaic system. Based on this reflective rear mirror concept, we report a thermophotovoltaic efficiency of 29.1 +/- 0.4% at an emitter temperature of 1,207 degrees C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2019, "Volume": 116, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15356, "End Page": 15361, "Article Number": null, "DOI": "10.1073/pnas.1903001116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1903001116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477812400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, Y; Pal, K; He, JG; Ozolins, V; Wolverton, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Yi; Pal, Koushik; He, Jiangang; Ozolins, Vidvuds; Wolverton, Chris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Particlelike Phonon Propagation Dominates Ultralow Lattice Thermal Conductivity in Crystalline Tl3VSe4", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate the microscopic mechanisms of ultralow lattice thermal conductivity (kappa(l)) in Tl3VSe4 by combining a first principles density functional theory based framework of anharmonic lattice dynamics with the Peierls-Boltzmann transport equation for phonons. We include contributions of the three- and four-phonon scattering processes to the phonon lifetimes as well as the temperature dependent anharmonic renormalization of phonon energies arising from an unusually strong quartic anharmonicity in Tl3VSe4. In contrast to a recent report by Mukhopadhyay et al. [Science 360, 1455 (2018)] which suggested that a significant contribution to kappa(l) arises from random walks among uncorrelated oscillators, we show that particlelike propagation of phonon excitations can successfully explain the experimentally observed ultralow kappa(l). Our findings are further supported by explicit calculations of the off-diagonal terms of the heat current operator, which are found to be small and indicate that wavelike tunneling of heat carrying vibrations is of minor importance. Our results (i) resolve the discrepancy between the theoretical and experimental kappa(l), (ii) offer new insights into the minimum kappa(l) achievable in Tl3VSe4, and (iii) highlight the importance of high order anharmonicity in low-kappa(l) systems. The methodology demonstrated here may be used to resolve the discrepancies between the experimentally measured and the theoretically calculated kappa(l) in skutterides and perovskites, as well as to understand the glasslike kappa(l) in complex crystals with strong anharmonicity, leading towards the goal of rational design of new materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2020, "Volume": 124, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 65901, "DOI": "10.1103/PhysRevLett.124.065901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.065901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513568400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HX; Boulle, O; Cros, V; Fert, A; Chshiev, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hongxin; Boulle, Olivier; Cros, Vincent; Fert, Albert; Chshiev, Mairbek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlling Dzyaloshinskii-Moriya Interaction via Chirality Dependent Atomic-Layer Stacking, Insulator Capping and Electric Field", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using first-principles calculations, we demonstrate several approaches to control Dzyaloshinskii-Moriya Interaction (DMI) in ultrathin films with perpendicular magnetic anisotropy. First, we find that DMI is significantly enhanced when the ferromagnetic (FM) layer is sandwiched between nonmagnetic (NM) layers inducing additive DMI in NM1/FM/NM2 structures. For instance, when two NM layers are chosen to induce DMI of opposite chirality in Co, e.g. NM1 representing Au, Ir, Al or Pb, and NM2 being Pt, the resulting DMI in NM1/Co/Pt trilayers is enhanced compared to Co/Pt bilayers. Moreover, DMI can be significantly enhanced further in case of using FM layer comprising Fe and Co layers. Namely, it is found that the DMI in Ir/Fe/Co/Pt structure can be enhanced by 80% compared to that of Co/Pt bilayers reaching a very large DMI amplitude of 5.59 meV/atom. Our second approach for enhancing DMI is to use oxide capping layer. We show that DMI is enhanced by 60% in Oxide/Co/Pt structures compared to Co/Pt bilayers. Moreover, we unveiled the DMI mechanism at Oxide/Co interface due to Rashba effect, which is different to Fert-Levy DMI at FM/NM interfaces. Finally, we demonstrate that DMI amplitude can be modulated using an electric field with an efficiency factor comparable to that of the electric field control of perpendicular magnetic anisotropy in transition metal/oxide interfaces. These approaches of DMI controlling pave the way for skyrmion and domain wall motion-based spintronic applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12356, "DOI": "10.1038/s41598-018-30063-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-30063-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441876700059", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bonilla, RS; Hoex, B; Hamer, P; Wilshaw, PR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bonilla, Ruy S.; Hoex, Bram; Hamer, Phillip; Wilshaw, Peter R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dielectric surface passivation for silicon solar cells: A review", "Source Title": "PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon wafer solar cells continue to be the leading photovoltaic technology, and in many places are now providing a substantial portion of electricity generation. Further adoption of this technology will require processing that minimises losses in device performance. A fundamental mechanism for efficiency loss is the recombination of photo-generated charge carriers at the unavoidable cell surfaces. Dielectric coatings have been shown to largely prevent these losses through a combination of different passivation mechanisms. This review aims to provide an overview of the dielectric passivation coatings developed in the past two decades using a standardised methodology to characterise the metrics of surface recombination across all techniques and materials. The efficacy of a large set of materials and methods has been evaluated using such metrics and a discussion on the current state and prospects for further surface passivation improvements is provided. (C) 2017 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 214, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1700293, "DOI": "10.1002/pssa.201700293", "DOI Link": "http://dx.doi.org/10.1002/pssa.201700293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404974800025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Papior, N; Lorente, N; Frederiksen, T; García, A; Brandbyge, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Papior, Nick; Lorente, Nicolas; Frederiksen, Thomas; Garcia, Alberto; Brandbyge, Mads", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improvements on non-equilibrium and transport Green function techniques: The next-generation TRANSIESTA", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present novel methods implemented within the non-equilibrium Green function code (NEGF) TRANSIESTA based on density functional theory (DR). Our flexible, next-generation DFT-NEGF code handles devices with one or multiple electrodes (N-e >= 1) with individual chemical potentials and electronic temperatures. We describe its novel methods for electrostatic gating, contour optimizations, and assertion of charge conservation, as well as the newly implemented algorithms for optimized and scalable matrix inversion, performance-critical pivoting, and hybrid parallelization. Additionally, a generic NEGF post-processing code (TBTRANS/PHTRANS) for electron and phonon transport is presented with several novelties such as Hamiltonian interpolations, N-e >= 1 electrode capability, bond-currents, generalized interface for user-defined tight-binding transport, transmission projection using eigenstates of a projected Hamiltonian, and fast inversion algorithms for large-scale simulations easily exceeding 10(6) atoms on workstation computers. The new features of both codes are demonstrated and bench-marked for relevant test systems. (C) 2016 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 309, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 212, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8, "End Page": 24, "Article Number": null, "DOI": "10.1016/j.cpc.2016.09.022", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2016.09.022", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392356000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, FY; Shi, PC; Yi, Z; Li, HL; Yi, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fuyan; Shi, Pengcheng; Yi, Zao; Li, Hailiang; Yi, Yougen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-Broadband Solar Absorber and High-Efficiency Thermal Emitter from UV to Mid-Infrared Spectrum", "Source Title": "MICROMACHINES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar energy is currently a very popular energy source because it is both clean and renewable. As a result, one of the main areas of research now is the investigation of solar absorbers with broad spectrum and high absorption efficiency. In this study, we create an absorber by superimposing three periodic Ti-Al2O3-Ti discs on a W-Ti-Al2O3 composite film structure. We evaluated the incident angle, structural components, and electromagnetic field distribution using the finite difference in time domain (FDTD) method in order to investigate the physical process by which the model achieves broadband absorption. We find that distinct wavelengths of tuned or resonullt absorption may be produced by the Ti disk array and Al2O3 through near-field coupling, cavity-mode coupling, and plasmon resonullce, all of which can effectively widen the absorption bandwidth. The findings indicate that the solar absorber's average absorption efficiency can range from 95.8% to 96% over the entire band range of 200 to 3100 nm, with the absorption bandwidth of 2811 nm (244-3055 nm) having the highest absorption rate. Additionally, the absorber only contains tungsten (W), titanium (Ti), and alumina (Al2O3), three materials with high melting points, which offers a strong assurance for the absorber's thermal stability. It also has a very high thermal radiation intensity, reaching a high radiation efficiency of 94.4% at 1000 K, and a weighted average absorption efficiency of 98.3% at AM1.5. Additionally, the incidence angle insensitivity of our suggested solar absorber is good (0-60 degrees) and polarization independence is good (0-90 degrees). These benefits enable a wide range of solar thermal photovoltaic applications for our absorber and offer numerous design options for the ideal absorber.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2023, "Volume": 14, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 985, "DOI": "10.3390/mi14050985", "DOI Link": "http://dx.doi.org/10.3390/mi14050985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000997835000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aykol, M; Dwaraknath, SS; Sun, WH; Persson, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aykol, Muratahan; Dwaraknath, Shyam S.; Sun, Wenhao; Persson, Kristin A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamic limit for synthesis of metastable inorganic materials", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing the growing number of possible or hypothesized metastable crystalline materials is extremely challenging. There is no rigorous metric to identify which compounds can or cannot be synthesized. We present a thermodynamic upper limit on the energy scale, above which the laboratory synthesis of a polymorph is highly unlikely. The limit is defined on the basis of the amorphous state, and we validate its utility by effectively classifying more than 700 polymorphs in 41 common inorganic material systems in the Materials Project for synthesizability. The amorphous limit is highly chemistry-dependent and is found to be in complete agreement with our knowledge of existing polymorphs in these 41 systems, whether made by the nature or in a laboratory. Quantifying the limits of metastability for realizable compounds, the approach is expected to find major applications in materials discovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 275, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 4, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaq0148", "DOI": "10.1126/sciadv.aaq0148", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaq0148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431374900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cofelice, M; Messia, MC; Marconi, E; Cuomo, F; Lopez, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cofelice, Martina; Messia, Maria Cristina; Marconi, Emanuele; Cuomo, Francesca; Lopez, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of the xanthan gum on the rheological properties of alginate hydrogels", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels are three-dimensional polymeric structures with remarkable physicochemical and mechanical prop-erties. The selection of biopolymers as constituents of hydrogels is of great importance to enable their use in a variety of fields. The present study proposes a mixed hydrogel of alginate and xanthan gum prepared by the in -situ gelation method. Since alginate gelation is induced by calcium crosslinking, two calcium concentrations have been used in this study. In detail, the influence of xanthan gum and calcium cations on the rheological behavior of alginate hydrogels were investigated using steady shear rheology, dynamic and transient shear rheological experiments. The results showed that the hydrogels behaved like a shear-thinning material, as Carreau fluids, and that the overall viscosity of the hydrogel was dependent on both Ca2+ and xanthan gum concentrations. The length of linear viscoelastic range was influenced by xanthan gum content only at low calcium concentration, while the storage modulus (G ') was found to increase with xanthan gum and calcium content. The interpolation of mechanical spectra with a power law demonstrated that G ' and G '' were slightly dependent on the frequency and that G ' became less frequency dependent with the addition of xanthan gum. Even though the elastic contribution of the hydrogel increased with calcium and xanthan concentration, the hydrogels obtained were not able to fully recover their original structure after the application of a high load. The behavior at large amplitude oscillation strain, mimicking real processing conditions, showed that hydrogels crosslinked with a low calcium concentration were affected by xanthan gum even at lower concentrations than hydrogels crosslinked with high calcium content. Such hydrogel mixtures could find application in research in the food industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 142, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108768, "DOI": "10.1016/j.foodhyd.2023.108768", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2023.108768", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001033701200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, F; Nielson, W; Xia, Y; Ozolins, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Fei; Nielson, Weston; Xia, Yi; Ozolins, Vidvuds", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice Anharmonicity and Thermal Conductivity from Compressive Sensing of First-Principles Calculations", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles prediction of lattice thermal conductivity kappa(L) of strongly anharmonic crystals is a long-standing challenge in solid-state physics. Making use of recent advances in information science, we propose a systematic and rigorous approach to this problem, compressive sensing lattice dynamics. Compressive sensing is used to select the physically important terms in the lattice dynamics model and determine their values in one shot. Nonintuitively, high accuracy is achieved when the model is trained on first-principles forces in quasirandom atomic configurations. The method is demonstrated for Si, NaCl, and Cu12Sb4S13, an earth-abundant thermoelectric with strong phonon-phonon interactions that limit the room-temperature kappa(L) to values near the amorphous limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2014, "Volume": 113, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 185501, "DOI": "10.1103/PhysRevLett.113.185501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.113.185501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348728400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Erickson, E; Gado, JE; Avilán, L; Bratti, F; Brizendine, RK; Cox, PA; Gill, R; Graham, R; Kim, DJ; König, G; Michener, WE; Poudel, S; Ramirez, KJ; Shakespeare, TJ; Zahn, M; Boyd, ES; Payne, CM; DuBois, JL; Pickford, AR; Beckham, GT; McGeehan, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Erickson, Erika; Gado, Japheth E.; Avilan, Luisana; Bratti, Felicia; Brizendine, Richard K.; Cox, Paul A.; Gill, Raj; Graham, Rosie; Kim, Dong-Jin; Koenig, Gerhard; Michener, William E.; Poudel, Saroj; Ramirez, Kelsey J.; Shakespeare, Thomas J.; Zahn, Michael; Boyd, Eric S.; Payne, Christina M.; DuBois, Jennifer L.; Pickford, Andrew R.; Beckham, Gregg T.; McGeehan, John E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sourcing thermotolerant poly(ethylene terephthalate) hydrolase scaffolds from natural diversity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enzymatic deconstruction of poly(ethylene terephthalate) (PET) is under intense investigation, given the ability of hydrolase enzymes to depolymerize PET to its constituent monomers near the polymer glass transition temperature. To date, reported PET hydrolases have been sourced from a relatively narrow sequence space. Here, we identify additional PET-active biocatalysts from natural diversity by using bioinformatics and machine learning to mine 74 putative thermotolerant PET hydrolases. We successfully express, purify, and assay 51 enzymes from seven distinct phylogenetic groups; observing PET hydrolysis activity on amorphous PET film from 37 enzymes in reactions spanning pH from 4.5-9.0 and temperatures from 30-70 degrees C. We conduct PET hydrolysis time-course reactions with the best-performing enzymes, where we observe differences in substrate selectivity as function of PET morphology. We employed X-ray crystallography and AlphaFold to examine the enzyme architectures of all 74 candidates, revealing protein folds and accessory domains not previously associated with PET deconstruction. Overall, this study expands the number and diversity of thermotolerant scaffolds for enzymatic PET deconstruction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7850, "DOI": "10.1038/s41467-022-35237-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35237-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001028170500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, DJ; Li, GG; Dang, PP; Zhang, QQ; Wei, Y; Qiu, L; Lian, HZ; Shang, MM; Lin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Dongjie; Li, Guogang; Dang, Peipei; Zhang, Qianqian; Wei, Yi; Qiu, Lei; Lian, Hongzhou; Shang, Mengmeng; Lin, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valence conversion and site reconstruction in near-infrared-emitting chromium-activated garnet for simultaneous enhancement of quantum efficiency and thermal stability", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achievement of high photoluminescence quantum efficiency and thermal stability is challenging for near-infrared (NIR)-emitting phosphors. Here, we designed a kill two birds with one stone strategy to simultaneously improve quantum efficiency and thermal stability of the NIR-emitting Ca3Y2-2x(ZnZr)xGe3O12:Cr garnet system by chemical unit cosubstitution, and revealed universal structure-property relationship and the luminescence optimization mechanism. The cosubstitution of [Zn2+-Zr4+] for [Y3+-Y3+] played a critical role as reductant to promote the valence transformation from Cr4+ to Cr3+, resulting from the reconstruction of octahedral sites for Cr3+. The introduction of [Zn2+-Zr4+] unit also contributed to a rigid crystal structure. These two aspects together realized the high internal quantum efficiency of 96% and excellent thermal stability of 89%@423 K. Moreover, information encryption with burning after reading was achieved based on different chemical resistance of the phosphors to acid. The developed NIR-emitting phosphor-converted light-emitting diode demonstrated promising applications in bio-tissue imaging and night vision. This work provides a new perspective for developing high-performance NIR-emitting phosphor materials. Significant improvement of quantum efficiency and thermal stability of NIR-emitting Ca3Y2-2x(ZnZr)xGe3O12:Cr was achieved by chemical unit cosubstitution, benefiting from valence reduction of Cr4+ to Cr3+ and reconstructed rigid crystal structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 248, "DOI": "10.1038/s41377-023-01283-3", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01283-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080766100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, JF; Lou, Q; Ding, ZZ; Zheng, GS; Ni, QC; Song, RW; Liu, KK; Zang, JH; Dong, L; Shen, CL; Shan, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Jiang-Fan; Lou, Qing; Ding, Zhong-Zheng; Zheng, Guang-Song; Ni, Qing-Chao; Song, Run-Wei; Liu, Kai-Kai; Zang, Jin-Hao; Dong, Lin; Shen, Cheng-Long; Shan, Chong-Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemiluminescent carbon nullodots for dynamic and guided antibacteria", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Advanced antibacterial technologies are needed to counter the rapid emergence of drug-resistant bacteria. Image-guided therapy is one of the most promising strategies for efficiently and accurately curing bacterial infections. Herein, a chemiluminescence (CL)-dynamic/guided antibacteria (CDGA) with multiple reactive oxygen species (ROS) generation capacity and chemiexcited near-infrared emission has been designed for the precise theranostics of bacterial infection by employing near-infrared emissive carbon nullodots (CDs) and peroxalate as CL fuels. Mechanistically, hydrogen peroxide generated in the bacterial microenvironment can trigger the chemically initiated electron exchange between CDs and energy-riched intermediate originated from the oxidized peroxalate, enabling bacterial induced inflammation imaging. Meanwhile, type I/II photochemical ROS production and type III ultrafast charge transfer from CDs under the self-illumination can inhibit the bacteria proliferation efficiently. The potential clinical utility of CDGA is further demonstrated in bacteria infected mice trauma model. The self-illuminating CDGA exhibits an excellent in vivo imaging quality in early detecting wound infections and internal inflammation caused by bacteria, and further are proven as efficient broad-spectrum antibacterial nullomedicines without drug-resistance, whose sterilizing rate is up to 99.99%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 4", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104, "DOI": "10.1038/s41377-023-01149-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01149-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000982190500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, H; Cheng, AJ; Wang, H; Zhao, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huan; Cheng, Aijie; Wang, Hong; Zhao, Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-fractional Allen-Cahn and Cahn-Hilliard phase-field models and their numerical investigation", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We study (time) fractional Allen-Cahn and Cahn-Hilliard phase-field models to account for the anomalously subdiffusive transport behavior in heterogeneous porous materials or memory effect of certain materials. We develop an efficient finite difference scheme and a Fourier spectral scheme to effectively treat the significantly increased memory requirement and computational complexity, which arise due to the nonlocal behavior of the time-fractional models. For time fractional Cahn-Hilliard model, we observe from the numerical results that the bigger the fractional order a is, the faster the energy decays. However, for time fractional Allen-Cahn model, we derived an opposite conclusion. Moreover, we also study the coarsening dynamics for time fractional Cahn-Hilliard model, numerical results reveal that the scaling law for the energy decays as O(t(-1/3)), which is consistent with the well-known result O(t(-1/3)) for integer order Cahn-Hilliard model. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2018, "Volume": 76, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1876, "End Page": 1892, "Article Number": null, "DOI": "10.1016/j.camwa.2018.07.036", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2018.07.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447574100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yabuta, H; Cody, GD; Engrand, C; Kebukawa, Y; De Gregorio, B; Bonal, L; Remusat, L; Stroud, R; Quirico, E; Nittler, L; Hashiguchi, M; Komatsu, M; Okumura, T; Mathurin, J; Dartois, E; Duprat, J; Takahashi, Y; Takeichi, Y; Kilcoyne, D; Yamashita, S; Dazzi, A; Deniset-Besseau, A; Sandford, S; Martins, Z; Tamenori, Y; Ohigashi, T; Suga, H; Wakabayashi, D; Verdier-Paoletti, M; Mostefaoui, S; Montagnac, G; Barosch, J; Kamide, K; Shigenaka, M; Bejach, L; Matsumoto, M; Enokido, Y; Noguchi, T; Yurimoto, H; Nakamura, T; Okazaki, R; Naraoka, H; Sakamoto, K; Connolly, HC Jr; Lauretta, DS; Abe, M; Okada, T; Yada, T; Nishimura, M; Yogata, K; Nakato, A; Yoshitake, M; Iwamae, A; Furuya, S; Hatakeda, K; Miyazaki, A; Soejima, H; Hitomi, Y; Kumagai, K; Usui, T; Hayashi, T; Yamamoto, D; Fukai, R; Sugita, S; Kitazato, K; Hirata, N; Honda, R; Morota, T; Tatsumi, E; Sakatani, N; Namiki, N; Matsumoto, K; Noguchi, R; Wada, K; Senshu, H; Ogawa, K; Yokota, Y; Ishihara, Y; Shimaki, Y; Yamada, M; Honda, C; Michikami, T; Matsuoka, M; Hirata, N; Arakawa, M; Okamoto, C; Ishiguro, M; Jaumann, R; Bibring, JP; Grott, M; Schröder, S; Otto, K; Pilorget, C; Schmitz, N; Biele, J; Ho, TM; Moussi-Soffys, A; Miura, A; Noda, H; Yamada, T; Yoshihara, K; Kawahara, K; Ikeda, H; Yamamoto, Y; Shirai, K; Kikuchi, S; Ogawa, N; Takeuchi, H; Ono, G; Mimasu, Y; Yoshikawa, K; Takei, Y; Fujii, A; Iijima, Y; Nakazawa, S; Hosoda, S; Iwata, T; Hayakawa, M; Sawada, H; Yano, H; Tsukizaki, R; Ozaki, M; Terui, F; Tanaka, S; Fujimoto, M; Yoshikawa, M; Saiki, T; Tachibana, S; Watanabe, S; Tsuda, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yabuta, Hikaru; Cody, George D.; Engrand, Cecile; Kebukawa, Yoko; De Gregorio, Bradley; Bonal, Lydie; Remusat, Laurent; Stroud, Rhonda; Quirico, Eric; Nittler, Larry; Hashiguchi, Minako; Komatsu, Mutsumi; Okumura, Taiga; Mathurin, Jeremie; Dartois, Emmanuel; Duprat, Jean; Takahashi, Yoshio; Takeichi, Yasuo; Kilcoyne, David; Yamashita, Shohei; Dazzi, Alexandre; Deniset-Besseau, Ariane; Sandford, Scott; Martins, Zita; Tamenori, Yusuke; Ohigashi, Takuji; Suga, Hiroki; Wakabayashi, Daisuke; Verdier-Paoletti, Maximilien; Mostefaoui, Smail; Montagnac, Gilles; Barosch, Jens; Kamide, Kanami; Shigenaka, Miho; Bejach, Laure; Matsumoto, Megumi; Enokido, Yuma; Noguchi, Takaaki; Yurimoto, Hisayoshi; Nakamura, Tomoki; Okazaki, Ryuji; Naraoka, Hiroshi; Sakamoto, Kanako; Connolly, Jr Harold C.; Lauretta, Dante S.; Abe, Masanao; Okada, Tatsuaki; Yada, Toru; Nishimura, Masahiro; Yogata, Kasumi; Nakato, Aiko; Yoshitake, Miwa; Iwamae, Ayako; Furuya, Shizuho; Hatakeda, Kentaro; Miyazaki, Akiko; Soejima, Hiromichi; Hitomi, Yuya; Kumagai, Kazuya; Usui, Tomohiro; Hayashi, Tasuku; Yamamoto, Daiki; Fukai, Ryota; Sugita, Seiji; Kitazato, Kohei; Hirata, Naru; Honda, Rie; Morota, Tomokatsu; Tatsumi, Eri; Sakatani, Naoya; Namiki, Noriyuki; Matsumoto, Koji; Noguchi, Rina; Wada, Koji; Senshu, Hiroki; Ogawa, Kazunori; Yokota, Yasuhiro; Ishihara, Yoshiaki; Shimaki, Yuri; Yamada, Manabu; Honda, Chikatoshi; Michikami, Tatsuhiro; Matsuoka, Moe; Hirata, Naoyuki; Arakawa, Masahiko; Okamoto, Chisato; Ishiguro, Masateru; Jaumann, Ralf; Bibring, Jean-Pierre; Grott, Matthias; Schroder, Stefan; Otto, Katharina; Pilorget, Cedric; Schmitz, Nicole; Biele, Jens; Ho, Tra-Mi; Moussi-Soffys, Aurelie; Miura, Akira; Noda, Hirotomo; Yamada, Tetsuya; Yoshihara, Keisuke; Kawahara, Kosuke; Ikeda, Hitoshi; Yamamoto, Yukio; Shirai, Kei; Kikuchi, Shota; Ogawa, Naoko; Takeuchi, Hiroshi; Ono, Go; Mimasu, Yuya; Yoshikawa, Kent; Takei, Yuto; Fujii, Atsushi; Iijima, Yu-ichi; Nakazawa, Satoru; Hosoda, Satoshi; Iwata, Takahiro; Hayakawa, Masahiko; Sawada, Hirotaka; Yano, Hajime; Tsukizaki, Ryudo; Ozaki, Masanobu; Terui, Fuyuto; Tanaka, Satoshi; Fujimoto, Masaki; Yoshikawa, Makoto; Saiki, Takanao; Tachibana, Shogo; Watanabe, Sei-ichiro; Tsuda, Yuichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Macromolecular organic matter in samples of the asteroid (162173) Ryugu", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Samples of the carbonaceous asteroid (162173) Ryugu were collected and brought to Earth by the Hayabusa2 spacecraft. We investigated the macromolecular organic matter in Ryugu samples and found that it contains aromatic and aliphatic carbon, ketone, and carboxyl functional groups. The spectroscopic features of the organic matter are consistent with those in chemically primitive carbonaceous chondrite meteorites that experienced parent-body aqueous alteration (reactions with liquid water). The morphology of the organic carbon includes nulloglobules and diffuse carbon associated with phyllosilicate and carbonate minerals. Deuterium and/or nitrogen-15 enrichments indicate that the organic matter formed in a cold molecular cloud or the presolar nebula. The diversity of the organic matter indicates variable levels of aqueous alteration on Ryugu's parent body.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2023, "Volume": 379, "Issue": 6634, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 790, "End Page": "+", "Article Number": "eabn9057", "DOI": "10.1126/science.abn9057", "DOI Link": "http://dx.doi.org/10.1126/science.abn9057", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000981616600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deacon, A; Briquet, L; Malankowska, M; Massingberd-Mundy, F; Rudic, S; Hyde, TL; Cavaye, H; Coronas, J; Poulston, S; Johnson, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deacon, Adam; Briquet, Ludovic; Malankowska, Magdalena; Massingberd-Mundy, Felicity; Rudic, Svemir; Hyde, Timothy L.; Cavaye, Hamish; Coronas, Joaquin; Poulston, Stephen; Johnson, Timothy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding the ZIF-L to ZIF-8 transformation from fundamentals to fully costed kilogram-scale production", "Source Title": "COMMUNICATIONS CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The metal-organic framework ZIF-8 has demonstrated promise for a wide range of applications, but its synthesis typically involves methodologies that are difficult or expensive to scale up. Here the authors show how the production of nullo-ZIF-8 can be conducted at the 1kg scale in an economical manner through the intermediate phase ZIF-L. The production of MOFs at large scale in a sustainable way is key if these materials are to be exploited for their promised widespread application. Much of the published literature has focused on demonstrations of preparation routes using difficult or expensive methodologies to scale. One such MOF is nullo-zeolitic imidazolate framework-8 (ZIF-8) - a material of interest for a range of possible applications. Work presented here shows how the synthesis of ZIF-8 can be tracked by a range of methods including X-ray diffraction, thermo gravimetric analysis and inelastic neutron scattering - which offer the prospect of in-line monitoring of the synthesis reaction. Herein we disclose how the production of nullo-ZIF-8 can be conducted at scale using the intermediate phase ZIF-L. By understanding the economics and demonstrating the production of 1 kg of nullo-ZIF-8 at pilot scale we have shown how this once difficult to make material can be produced to specification in a scalable and cost-efficient fashion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2022, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 18, "DOI": "10.1038/s42004-021-00613-z", "DOI Link": "http://dx.doi.org/10.1038/s42004-021-00613-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753391100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yeom, H; Maier, B; Johnson, G; Dabney, T; Lenling, M; Sridharan, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yeom, Hwasung; Maier, Benjamin; Johnson, Greg; Dabney, Tyler; Lenling, Mia; Sridharan, Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High temperature oxidation and microstructural evolution of cold spray chromium coatings on Zircaloy-4 in steam environments", "Source Title": "JOURNAL OF NUCLEAR MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxidation kinetics and microstructural evolution of cold sprayed Cr coatings on Zircaloy-4 at 1130 - 1310 degrees C in flowing steam at atmospheric pressure have been studied. The study is aimed at understanding of the response of Cr coated Zr-alloy under a steam environment and high temperatures pertinent to design basis accidents (DBAs) and beyond design basis accidents (BDBAs) in light water reactors (LWRs). Surface morphology, microstructure, and phases of post-oxidation test samples were characterized using Scanning Electron Microscopy (SEM), x-ray diffraction (XRD), and Scanning Transmission Electron Microscopy (STEM). Growth kinetics of the Cr-oxide scale and interdiffusion layers between the Cr coating and the Zr-alloy substrate were quantified from cross-sectional SEM images. Cross-sectional analysis showed that the Cr coatings offered a 50 times reduction in oxidation rate over bare Zircaloy-4 in a 1310 degrees C steam environment. Oxidation kinetics at 1130 degrees C followed parabolic law (i.e., n similar to 0.5 in power law kinetics) but at 1230 degrees C and 1310 degrees C the value of n was suppressed to below 0.5 possibly due to the volatilization of Cr species at the two highest temperatures. Interdiffusion at coating/substrate interface resulted in formation of a brittle Cr2Zr or Zr(Fe, Cr)(2) intermetallic compound layer on the order of micrometer in thickness and scattered Cr-rich precipitates were observed well below the interface within the Zr-alloy substrate after cooling. These experimental results could provide data to LWR system simulation codes for better estimation of coping time in the event of accidents. (C) 2019 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 188, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2019, "Volume": 526, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 151737, "DOI": "10.1016/j.jnucmat.2019.151737", "DOI Link": "http://dx.doi.org/10.1016/j.jnucmat.2019.151737", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500777900018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, WK; Liu, Y; Li, S; Zhong, CY; Yu, ZM; Sheng, XL; Zhao, YX; Yang, SYA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Weikang; Liu, Ying; Li, Si; Zhong, Chengyong; Yu, Zhi-Ming; Sheng, Xian-Lei; Zhao, Y. X.; Yang, Shengyuan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nodal surface semimetals: Theory and material realization", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We theoretically study the three-dimensional topological semimetals with nodal surfaces protected by crystalline symmetries. Different from the well-known nodal-point and nodal-line semimetals, in these materials, the conduction and valence bands cross on closed nodal surfaces in the Brillouin zone. We propose different classes of nodal surfaces, both in the absence and in the presence of spin-orbit coupling (SOC). In the absence of SOC, a class of nodal surfaces can be protected by space-time inversion symmetry and sublattice symmetry and characterized by a Z(2) index, while another class of nodal surfaces are guaranteed by a combination of nonsymmorphic twofold screw-rotational symmetry and time-reversal symmetry. We show that the inclusion of SOC will destroy the former class of nodal surfaces but may preserve the latter provided that the inversion symmetry is broken. We further generalize the result to magnetically ordered systems and show that protected nodal surfaces can also exist in magnetic materials without and with SOC, given that certain magnetic group symmetry requirements are satisfied. Several concrete nodal-surface material examples are predicted via the first-principles calculations. The possibility of multi-nodal-surface materials is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 294, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2018, "Volume": 97, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115125, "DOI": "10.1103/PhysRevB.97.115125", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.115125", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427112600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, X; Li, ZX; Yao, J; Dong, K; Li, XH; Hu, L; Sun, SJ; Cai, ZW; Zheng, DD; Luo, YS; Ying, BW; Hamdy, MS; Xie, LS; Liu, Q; Sun, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xun; Li, Zixiao; Yao, Jie; Dong, Kai; Li, Xiuhong; Hu, Long; Sun, Shengjun; Cai, Zhengwei; Zheng, Dongdong; Luo, Yongsong; Ying, Binwu; Hamdy, Mohamed S.; Xie, Lisi; Liu, Qian; Sun, Xuping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency electrocatalytic nitrite reduction toward ammonia synthesis on CoP@TiO2 nulloribbon array", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of nitrite (NO2-) can satisfy the necessity for NO2- contaminullt removal and deliver a sustainable pathway for ammonia (NH3) gener-ation. Its practical application yet requires highly efficient electrocatalysts to boost NH3 yield and Faradaic efficiency (FE). In this study, CoP nulloparticle-decorated TiO2 nulloribbon array on Ti plate (CoP@TiO2/TP) is verified as a high-efficiency electrocatalyst for the selective reduction of NO2- to NH3. When measured in 0.1 M NaOH with NO2-, the freestanding CoP@TiO2/TP electrode delivers a large NH3 yield of 849.57 mmol h(-1) cm(-2) and a high FE of 97.01% with good stability. Remarkably, the subsequently fabricated Zn-NO2- battery achieves a high power density of 1.24 mW cm(-2) while delivering a NH3 yield of 714.40 mg h(-1) cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2023, "Volume": 26, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107100, "DOI": "10.1016/j.isci.2023.107100", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2023.107100", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001056639600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Salim, RM; Asik, J; Sarjadi, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Md Salim, Rafidah; Asik, Jahimin; Sarjadi, Mohd Sani", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical functional groups of extractives, cellulose and lignin extracted from native Leucaena leucocephala bark", "Source Title": "WOOD SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bark from trees is considered a worthless raw material. However, this resource could be economically beneficial if utilized efficiently due to its rich chemical compounds. In this study, an ethanol toluene-soluble extractive, alpha-cellulose and lignin obtained from Leucaena leucocephala bark were characterized to determine their chemical functional groups. Based on FTIR spectral analysis, the results indicated that the bands of the functional groups of the extractive from the original bark remain unchanged; however, the absorbance intensity was found to be weaker in the group frequency and fingerprint regions. Removal of extractive, pectin, hemicellulose and lignin from the bark indirectly increased the strong absorbance intensity of cellulose. Broad peaks of OH stretching found in all spectra were assigned to the presence of phenolic OH and aliphatic structures for extractive and aromatic structures of lignin. It was revealed that aromatic functional groups were mainly found in the extractive, while water, carbonyl and ether were the dominullt groups in cellulose, and methyl, methylene, carbonyl and carboxyl groups were enriched in lignin. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 55, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 295, "End Page": 313, "Article Number": null, "DOI": "10.1007/s00226-020-01258-2", "DOI Link": "http://dx.doi.org/10.1007/s00226-020-01258-2", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Forestry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000610495100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, RX; Wu, FC; Das Sarma, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Rui-Xing; Wu, Fengcheng; Das Sarma, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mobius Insulator and Higher-Order Topology in MnBi2nTe3n+1", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose MnBi2nTe3n+1 as a magnetically tunable platform for realizing various symmetry-protected higher-order topology. Its canted antiferromagnetic phase can host exotic topological surface states with a Mobius twist that are protected by nonsymmorphic symmetry. Moreover, opposite surfaces hosting Mobius fermions are connected by one-dimensional chiral hinge modes, which offers the first material candidate of a higher-order topological Mobius insulator. We uncover a general mechanism to feasibly induce this exotic physics by applying a small in-plane magnetic field to the antiferromagnetic topological insulating phase of MnBi2nTe3n+1, as well as other proposed axion insulators. For other magnetic configurations, two classes of inversion-protected higher-order topological phases are ubiquitous in this system, which both manifest gapped surfaces and gapless chiral hinge modes. We systematically discuss their classification, microscopic mechanisms, and experimental signatures. Remarkably, the magnetic-field-induced transition between distinct chiral hinge mode configurations provides an effective topological magnetic switch.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2020, "Volume": 124, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136407, "DOI": "10.1103/PhysRevLett.124.136407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.136407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000523412800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al Rashid, A; Ahmed, W; Khalid, MY; Koç, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al Rashid, Ans; Ahmed, Waqas; Khalid, Muhammad Yasir; Koc, Muammer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vat photopolymerization of polymers and polymer composites: Processes and applications", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthesis and manufacturing of polymers and their composites have been a topic of interest recently in research and development owing to their wide margin of superiority over traditionally employed industrial materials. Polymer composites provide a higher strengths, easily customizable product properties, flexible manufacturing processes, high resistance to corrosion or erosion, and lower cost. In addition, the additive manufacturing (AM) techniques for polymer composites offer numerous benefits, including higher accuracy, lesser cost, and complexity of fabricated parts. The recent progress in AM processes has paved the way for even a broader range of design flexibilities and materials selection for several industrial sectors, including mechanical, biomedical, filtration, and electrical. However, some challenges remain in additive manufacturing for polymer composites. Vat photopolymerization (VP) processes is an AM technique that provides a benefit of relatively lower cost and higher resolutions; therefore, a comparative review of VP processes for polymers and polymer composites and their applications is presented in this study. This study aims to provide researchers with an updated understanding of the underlying challenges and opportunities. It will also help the reader to systematically reveal the research problems, gaps and future directions related to polymer composite materials and VP processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 47, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102279, "DOI": "10.1016/j.addma.2021.102279", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2021.102279", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000700574700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Artrith, N; Urban, A; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Artrith, Nongnuch; Urban, Alexander; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and accurate machine-learning interpolation of atomic energies in compositions with many species", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine-learning potentials (MLPs) for atomistic simulations are a promising alternative to conventional classical potentials. Current approaches rely on descriptors of the local atomic environment with dimensions that increase quadratically with the number of chemical species. In this paper, we demonstrate that such a scaling can be avoided in practice. We show that a mathematically simple and computationally efficient descriptor with constant complexity is sufficient to represent transition-metal oxide compositions and biomolecules containing 11 chemical species with a precision of around 3 meV/atom. This insight removes a perceived bound on the utility of MLPs and paves the way to investigate the physics of previously inaccessible materials with more than ten chemical species.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 261, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2017, "Volume": 96, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14112, "DOI": "10.1103/PhysRevB.96.014112", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.014112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406034600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bichu, YM; Alwafi, A; Liu, XM; Andrews, J; Ludwig, B; Bichu, AY; Zou, BS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bichu, Yashodhan M.; Alwafi, Abdulraheem; Liu, Xiaomo; Andrews, James; Ludwig, Bjoern; Bichu, Aditi Y.; Zou, Bingshuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in orthodontic clear aligner materials", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid technological improvements in biomaterials, computer-aided design (CAD) and manufacturing (CAM) have endorsed clear aligner therapy (CAT) as a mainstay of orthodontic treatment, and the materials employed for aligner fabrication play an all-important role in determining the clinical performance of clear aligners. This narrative review has attempted to comprehensively encompass the entire gamut of materials currently used for the fabrication of clear aligners and elucidate their characteristics that are crucial in determining their perfor-mance in an oral environment. Historical developments and current protocols in aligner fabrication, features of contemporary bioactive materials, and emerging trends related to CAT are discussed. Advances in aligner ma-terial chemistry and engineering possess the potential to bring about radical transformations in the therapeutic applications of CAT; in the absence of which, clear aligners would continue to underperform clinically, due to their inherent biomechanical constraints. Finally, while innovations in aligner materials such as shape memory polymers, direct three-dimensional (3D) printed clear aligners and bioactive materials combined with clear aligner materials are essential to further advance the applications of CAT; increased awareness of environmental responsibilities among aligner manufacturers, aligner prescribing clinicians and aligner users is essential for better alignment of our climate change goals towards a sustainable planet.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 384, "End Page": 403, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000890442600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gottschall, T; Skokov, KP; Fries, M; Taubel, A; Radulov, I; Scheibel, F; Benke, D; Riegg, S; Gutfleisch, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gottschall, Tino; Skokov, Konstantin P.; Fries, Maximilian; Taubel, Andreas; Radulov, Iliya; Scheibel, Franziska; Benke, Dimitri; Riegg, Stefan; Gutfleisch, Oliver", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making a Cool Choice: The Materials Library of Magnetic Refrigeration", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The phase-down scenario of conventional refrigerants used in gas-vapor compressors and the demand for environmentally friendly and efficient cooling make the search for alternative technologies more important than ever. Magnetic refrigeration utilizing the magnetocaloric effect of magnetic materials could be that alternative. However, there are still several challenges to be overcome before having devices that are competitive with those based on the conventional gas-vapor technology. In this paper a rigorous assessment of the most relevant examples of 14 different magnetocaloric material families is presented and those are compared in terms of their adiabatic temperature and isothermal entropy change under cycling in magnetic-field changes of 1 and 2 T, criticality aspects, and the amount of heat that they can transfer per cycle. The work is based on magnetic, direct thermometric, and calorimetric measurements made under similar conditions and in the same devices. Such a wide-ranging study has not been carried out before. This data sets the basis for more advanced modeling and machine learning approaches in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 9, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1901322, "DOI": "10.1002/aenm.201901322", "DOI Link": "http://dx.doi.org/10.1002/aenm.201901322", "Book DOI": null, "Early Access Date": "JUL 2019", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478689200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sandberg, OJ; Kaiser, C; Zeiske, S; Zarrabi, N; Gielen, S; Maes, W; Vandewal, K; Meredith, P; Armin, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sandberg, Oskar J.; Kaiser, Christina; Zeiske, Stefan; Zarrabi, Nasim; Gielen, Sam; Maes, Wouter; Vandewal, Koen; Meredith, Paul; Armin, Ardalan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mid-gap trap state-mediated dark current in organic photodiodes", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Researchers demonstrate that the dark saturation current in organic photodiodes is fundamentally limited by mid-gap trap states. This leads to an upper limit for specific detectivity. Photodiodes are ubiquitous in industry and consumer electronics. Constantly emerging new applications for photodiodes demand different mechanical and optoelectronic properties from those provided by conventional inorganic-based semiconductor devices. This has stimulated considerable interest in the use of organic semiconductors, which provide a vast palette of available optoelectronic properties, can be incorporated into flexible form factor geometries, and promise low-cost, low-embodied energy manufacturing from earth-abundant materials. The sensitivity of a photodiode depends critically on the dark current. Organic photodiodes (OPDs), however, are characterized by a much higher dark current than expected for thermally excited radiative transitions. Here we show that the dark saturation current in OPDs is fundamentally limited by mid-gap trap states. This new insight is generated by the universal trend observed for the dark saturation current of a large set of OPDs and further substantiated by sensitive external-quantum-efficiency- and temperature-dependent current measurements. Based on this insight, an upper limit for the specific detectivity is established. A detailed understanding of the origins of noise in any detector is fundamental to defining performance limitations and thus is critical to materials and device selection, and design and optimization for all applications. Our work establishes these important principles for OPDs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 17, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 368, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01173-5", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01173-5", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955527900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZM; Winkler, GW; Wu, QS; Li, J; Soluyanov, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Ziming; Winkler, Georg W.; Wu, QuanSheng; Li, Ju; Soluyanov, Alexey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Triple Point Topological Metals", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topologically protected fermionic quasiparticles appear in metals, where band degeneracies occur at the Fermi level, dictated by the band structure topology. While in some metals these quasiparticles are direct analogues of elementary fermionic particles of the relativistic quantum field theory, other metals can have symmetries that give rise to quasiparticles, fundamentally different from those known in high-energy physics. Here, we report on a new type of topological quasiparticles-triple point fermions-realized in metals with symmorphic crystal structure, which host crossings of three bands in the vicinity of the Fermi level protected by point group symmetries. We find two topologically different types of triple point fermions, both distinct from any other topological quasiparticles reported to date. We provide examples of existing materials that host triple point fermions of both types and discuss a variety of physical phenomena associated with these quasiparticles, such as the occurrence of topological surface Fermi arcs, transport anomalies, and topological Lifshitz transitions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 376, "Times Cited, All Databases": 396, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2016, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31003, "DOI": "10.1103/PhysRevX.6.031003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.6.031003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379727200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sundararaman, R; Letchworth-Weaver, K; Schwarz, KA; Gunceler, D; Ozhabes, Y; Arias, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sundararaman, Ravishankar; Letchworth-Weaver, Kendra; Schwarz, Kathleen A.; Gunceler, Deniz; Ozhabes, Yalcin; Arias, T. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "JDFTx: Software for joint density-functional theory", "Source Title": "SOFTWAREX", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Density-functional theory (DFT) has revolutionized computational prediction of atomic-scale properties from first principles in physics, chemistry and materials science. Continuing development of new methods is necessary for accurate predictions of new classes of materials and properties, and for connecting to nullo- and mesoscale properties using coarse-grained theories. JDFTx is a fully-featured open-source electronic DFT software designed specifically to facilitate rapid development of new theories, models and algorithms. Using an algebraic formulation as an abstraction layer, compact C++ 11 code automatically performs well on diverse hardware including GPUs (Graphics Processing Units). This code hosts the development of joint density-functional theory (JDFT) that combines electronic DFT with classical DFT and continuum models of liquids for first-principles calculations of solvated and electrochemical systems. In addition, the modular nature of the code makes it easy to extend and interface with, facilitating the development of multi-scale toolkits that connect to ab initio calculations, e.g. photo-excited carrier dynamics combining electron and phonon calculations with electromagnetic simulations. (C) 2017 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 359, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 278, "End Page": 284, "Article Number": null, "DOI": "10.1016/j.softx.2017.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.softx.2017.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457135200046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maurand, R; Jehl, X; Kotekar-Patil, D; Corna, A; Bohuslavskyi, H; Laviéville, R; Hutin, L; Barraud, S; Vinet, M; Sanquer, M; De Franceschi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maurand, R.; Jehl, X.; Kotekar-Patil, D.; Corna, A.; Bohuslavskyi, H.; Lavieville, R.; Hutin, L.; Barraud, S.; Vinet, M.; Sanquer, M.; De Franceschi, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A CMOS silicon spin qubit", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silicon, the main constituent of microprocessor chips, is emerging as a promising material for the realization of future quantum processors. Leveraging its well-established complementary metal-oxide-semiconductor (CMOS) technology would be a clear asset to the development of scalable quantum computing architectures and to their co-integration with classical control hardware. Here we report a silicon quantum bit (qubit) device made with an industry-standard fabrication process. The device consists of a two-gate, p-type transistor with an undoped channel. At low temperature, the first gate defines a quantum dot encoding a hole spin qubit, the second one a quantum dot used for the qubit read-out. All electrical, two-axis control of the spin qubit is achieved by applying a phase-tunable microwave modulation to the first gate. The demonstrated qubit functionality in a basic transistor-like device constitutes a promising step towards the elaboration of scalable spin qubit geometries in a readily exploitable CMOS platform.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13575, "DOI": "10.1038/ncomms13575", "DOI Link": "http://dx.doi.org/10.1038/ncomms13575", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388760300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Balakrishnull, G; Velavan, R; Batoo, KM; Raslan, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Balakrishnull, G.; Velavan, R.; Batoo, Khalid Mujasam; Raslan, Emad H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure, optical and photocatalytic properties of MgO nulloparticles", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present work is focused on the synthesize of MgO nulloparticles using combustion method. The magnesium nitrate is used as a precursor with urea as a fuel. The precursor material is dissolved in 50 ml DI water along with the fuel and the solution is heated at 80 degrees C for 2 h. Then, the solution is transferred to crucible and kept it in the temperature of 500 degrees C. The as-synthesized MgO nullopowders are analyzed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), photoluminescence (PL) and photocatalytic studies. The XRD results of MgO nulloparticles indicated the cubic structure with the crystallite size of 27 nm. The FESEM studies indicated the formation of MgO crystallites in spherical shape. In addition, MgO nulloparticles are porous and agglomerated. PL spectrum of MgO materials exhibit emission peaks, which indicates the occurrence of band to band transition with the bandgap of 2.9 eV. The photocatalytic degradation of methylene blue dye is evaluated using the as-prepared MgO nulloparticles under UV light. The photocatalytic studies indicate the 75% degradation efficiency of the catalyst after 120 min irradiation. Hence, the MgO nulloparticles (NPs) can be used for the treatment of effluents from the dye industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103013, "DOI": "10.1016/j.rinp.2020.103013", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2020.103013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540004300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shokrani, A; Dhokia, V; Newman, ST", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shokrani, Alborz; Dhokia, Vimal; Newman, Stephen T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation of the effects of cryogenic machining on surface integrity in CNC end milling of Ti-6Al-4V titanium alloy", "Source Title": "JOURNAL OF MANUFACTURING PROCESSES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents the first comprehensive investigation on the effects of cryogenic cooling using liquid nitrogen on surface integrity of Ti-6Al-4V titanium alloy workpiece in end milling operations. Titanium is classified as a notoriously difficult-to-machine material, where its machining is characterised by poor surface integrity and short tool life. Increasing productivity, whilst meeting surface integrity requirements for aerospace and medical titanium-based components has always been a challenge in machining operations. Cryogenic machining using super cold liquid nitrogen at 197 C is a method to facilitate heat dissipation from the cutting zone and reduce the chemical affinity of workpiece and cutting tool materials and therefore improving machinability. Since milling is one of the major machining operations for aerospace components, this study is concentrated on cryogenic milling. The effects of cryogenic cooling on surface integrity are compared to conventional dry and flood cooling in end milling Ti-6Al-4V titanium alloy. A series of machining experiments were conducted at various combinations of cutting parameters. Surface roughness and microscopic surface integrity were investigated and subsurface microhardness was measured for each sample. The analysis indicated that cryogenic cooling has resulted in up to 39% and 31% lower surface roughness when compared to dry and flood cooling methods, respectively. Furthermore, microscopic surface defects were significantly reduced as a result of cryogenic. The investigations indicated that cryogenic cooling considerably improves surface integrity in end milling of Ti-6Al-4V. (C) 2015 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 172, "End Page": 179, "Article Number": null, "DOI": "10.1016/j.jmapro.2015.12.002", "DOI Link": "http://dx.doi.org/10.1016/j.jmapro.2015.12.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370999200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ncube, A; Mtetwa, S; Bukhari, M; Fiorentino, G; Passaro, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ncube, Amos; Mtetwa, Sandile; Bukhari, Mahak; Fiorentino, Gabriella; Passaro, Renato", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Circular Economy and Green Chemistry: The Need for Radical Innovative Approaches in the Design for New Products", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The idea of a circular economy (CE) has gained ground over the past ten years as a means of addressing sustainable development and getting around the limitations of the current and linear dominullt production and consumption patterns. The primary goal of a CE is to encourage the adoption of closing-the-loop production methods to improve resource use efficiency, modify chemical processes, and increase product and material lifespan. According to the 2030 Agenda for Sustainable Development, which focuses on 17 Sustainable Development Goals, 14 of which call for the appropriate application of green chemistry (GC) concepts and patterns, the role that chemistry may play in the shift toward more sustainable models is critical. By serving as the foundation for novel products made from renewable feedstocks and designed to be reused, recycled, or recovered with the associated minimum energy requirements, green and sustainable chemistry could be the key to unlocking the economic potential of the CE toward new product design and ultimately solving waste management problems. The aim of this perspective paper, while using a variety of literature sources, is to essentially capture the main issues associated with the CE and GC paradigms and how these two approaches can merge toward sustainable business models and the production of new materials. This integration focuses on reducing waste, conserving resources, and minimizing negative environmental impacts, while also considering economic viability. However, the obstacles to achieving implementation of the CE and GC principles are investment, environmental education, and legislation. To advance toward the circular economy and green chemistry, international agreements should be reconsidered to provide an appropriate framework, including the creation of incentives for businesses and individuals to adopt circular practices, the establishment of education programs to promote the benefits of circular practices, and the development of regulations to support the transition to sustainable production and consumption patterns.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 16, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1752, "DOI": "10.3390/en16041752", "DOI Link": "http://dx.doi.org/10.3390/en16041752", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939300300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maras, E; Trushin, O; Stukowski, A; Ala-Nissila, T; Jónsson, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maras, E.; Trushin, O.; Stukowski, A.; Ala-Nissila, T.; Jonsson, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global transition path search for dislocation formation in Ge on Si(001)", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Global optimization of transition paths in complex atomic scale systems is addressed in the context of misfit dislocation formation in a strained Ge film on Si(001). Such paths contain multiple intermediate minima connected by minimum energy paths on the energy surface emerging from the atomic interactions in the system. The challenge is to find which intermediate states to include and to construct a path going through these intermediates in such a way that the overall activation energy for the transition is minimal. In the numerical approach presented here, intermediate minima are constructed by heredity transformations of known minimum energy structures and by identifying local minima in minimum energy paths calculated using a modified version of the nudged elastic band method. Several mechanisms for the formation of a 90 degrees misfit dislocation at the Ge Si interface are identified when this method is used to construct transition paths connecting a homogeneously strained Ge film and a film containing a misfit dislocation. One of these mechanisms which has not been reported in the literature is detailed. The activation energy for this path is calculated to be 26% smaller than the activation energy for half loop formation of a full, isolated 60 degrees dislocation. An extension of the common neighbor analysis method involving characterization of the geometrical arrangement of second nearest neighbors is used to identify and visualize the dislocations and stacking faults. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 357, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 205, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13, "End Page": 21, "Article Number": null, "DOI": "10.1016/j.cpc.2016.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2016.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378459100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YC; Kim, M; Li, W; Verlinden, P; Hallam, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuchao; Kim, Moonyong; Li Wang; Verlinden, Pierre; Hallam, Brett", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design considerations for multi-terawatt scale manufacturing of existing and future photovoltaic technologies: challenges and opportunities related to silver, indium and bismuth consumption", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To significantly impact climate change, the annual photovoltaic (PV) module production rate must dramatically increase from similar to 135 gigawatts (GW) in 2020 to similar to 3 terawatts (TW) around 2030. A key knowledge gap is the sustainable manufacturing capacity of existing and future commercial PV cell technologies imposed by scarce metals, and a suitable pathway towards sustainable manufacturing at the multi-TW scale. Assuming an upper material consumption limit as 20% of 2019 global supply, we show that the present industrial implementations of passivated emitter and rear cell (PERC), tunnel oxide passivated contact (TOPCon), and silicon heterojunction (SHJ) cells have sustainable manufacturing capacities of 377 GW (silver-limited), 227 GW (silver-limited) GW and 37 GW (indium-limited), respectively. We propose material consumption targets of 2 mg W-1, 0.38 mg W-1, and 1.8 mg W-1 for silver, indium, and bismuth, respectively, indicating significant material consumption reductions are required to meet the target production rate for sustainable multi-TW scale manufacturing in about ten years from now. The industry needs urgent innovation on screen printing technologies for PERC, TOPCon, and SHJ solar cells to reduce silver consumption beyond expectation in the Industrial Technology Roadmap for PV (ITPRV), or the widespread adoption of existing and proven copper plating technologies. Indium cannot be used in any significant manufacturing capacity for PV production, even for futuristic 30%-efficient tandem devices. The current implementation of low-temperature interconnection schemes using bismuth-based solders will be limited to 330 GW of production. With half the silver-limited sustainable manufacturing capacity as PERC, the limited efficiency gains of SHJ and TOPCon cell technologies do not justify a transition away from industrial PERC, or the introduction of indium- and bismuth limitations for SHJ solar cells. On the other hand, futuristic two-terminal tandems with efficiency potentials over 30% have a unique opportunity to reduce material consumption through substantially reduced series resistance losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2021, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5587, "End Page": 5610, "Article Number": null, "DOI": "10.1039/d1ee01814k", "DOI Link": "http://dx.doi.org/10.1039/d1ee01814k", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701569000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JJ; Park, J; Lu, IT; Maliyov, I; Tong, X; Bernardi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jin-Jian; Park, Jinsoo; Lu, I-Te; Maliyov, Ivan; Tong, Xiao; Bernardi, Marco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PERTURBO: A software package for ab initio electron-phonon interactions, charge transport and ultrafast dynamics", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "PERTURBO is a software package for first-principles calculations of charge transport and ultrafast carrier dynamics in materials. The current version focuses on electron-phonon interactions and can compute phonon-limited transport properties such as the conductivity, carrier mobility and Seebeck coefficient. It can also simulate the ultrafast nonequilibrium electron dynamics in the presence of electron-phonon scattering. PERTURBO uses results from density functional theory and density functional perturbation theory calculations as input, and employs Wannier interpolation to reduce the computational cost. It supports norm-conserving and ultrasoft pseudopotentials, spin-orbit coupling, and polar electron- phonon interactions for bulk and 2D materials. Hybrid MPI plus OpenMP parallelization is implemented to enable efficient calculations on large systems (up to at least 50 atoms) using high-performance computing. Taken together, PERTURBO provides efficient and broadly applicable ab initio tools to investigate electron-phonon interactions and carrier dynamics quantitatively in metals, semiconductors, insulators, and 2D materials. Program summary Program Title: PERTURBO CPC Library link to program files: https://doi.org/10.17632/34m2p6v79t.1 Developer's repository link: https://perturbo-code.github.io Licensing provisions: GNU General Public Licence 3.0 Programming language: FORTRAN, PYTHON External routines/libraries: LAPACK, HDF5, MPI, OPENMP, FFTW, QUANTUM-ESPRESSO, WANNIER90 Nature of problem: Computing transport properties from first-principles in materials, including the electrical conductivity, carrier mobility and Seebeck coefficient; Simulating ultrafast nonequilibrium electron dynamics, such as the relaxation of excited carriers via interactions with phonons. Solution method: We implement the first-principles Boltzmann transport equation, which employs materials properties such as the electronic structure, lattice dynamics, and electron-phonon collision terms computed with density functional theory and density functional perturbation theory. The Boltzmann transport equation is solved numerically to compute charge transport and simulate ultrafast carrier dynamics. Wannier interpolation is employed to reduce the computational cost. Additional comments: Hybrid MPI plus OpenMP parallelization is implemented to run large calculations and take advantage of high-performance computing. Most results are output to HDF5 file format, which is portable and convenient for post-processing using high-level languages such as Python and Julia. (c) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 264, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107970, "DOI": "10.1016/j.cpc.2021.107970", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.107970", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659862300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shih, M; Miao, JS; Mills, M; Ghazisaeidi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shih, Mulaine; Miao, Jiashi; Mills, Michael; Ghazisaeidi, Maryam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking fault energy in concentrated alloys", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We revisit the meaning of stacking fault energy (SFE) and the assumptions of equilibrium dissociation of lattice dislocations in concentrated alloys. SFE is a unique value in pure metals. However, in alloys beyond the dilute limit, SFE has a distribution of values depending on the local atomic environment. Conventionally, the equilibrium distance between partial dislocations is determined by a balance between the repulsive elastic interaction between the partial dislocations and a unique value for SFE. This assumption is used to determine SFE from experimental measurements of dislocation splitting distances in metals and alloys, often contradicting computational predictions. We use atomistic simulations in a model NiCo alloy to study the dislocation dissociation process in a range of compositions with positive, zero, and negative average SFE and surprisingly observe a stable, finite splitting distance in all cases at low temperatures. We then compute the decorrelation stress and examine the balance of forces on the partial dislocations, considering the local effects on SFE, and observe that even the upper bound of SFE distribution alone cannot satisfy the force balance in some cases. Furthermore, we show that in concentrated solid solutions, the resisting force caused by interaction of dislocations with the local solute environment becomes a major force acting on partial dislocations. Here, we show that the presence of a high solute/dislocation interaction, which is not easy to measure and neglected in experimental measurements of SFE, renders the experimental values of SFE unreliable. The stacking fault energy is connected to the response of crystals to deformation. Here the authors report a computational study in a model NiCo system to demonstrate the key importance of the dislocation/solute interaction for the accurate assessment of stacking fault energy in alloys beyond dilute limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 180, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3590, "DOI": "10.1038/s41467-021-23860-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23860-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000663757900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Borisenko, S; Evtushinsky, D; Gibson, Q; Yaresko, A; Koepernik, K; Kirnp, T; Ali, M; van den Brink, J; Hoesch, M; Fedorov, A; Haubold, E; KushnirenkoHD, Y; Soldatov, I; Schäfer, R; Cava, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Borisenko, Sergey; Evtushinsky, Daniil; Gibson, Quinn; Yaresko, Alexander; Koepernik, Klaus; Kirnp, Timur; Ali, Mazhar; van den Brink, Jeroen; Hoesch, Moritz; Fedorov, Alexander; Haubold, Erik; KushnirenkoHD, Yevhen; Soldatov, Ivan; Schaefer, Rudolf; Cava, Robert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-reversal symmetry breaking type-II Weyl state in YbMnBi2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spectroscopic detection of Dirac and Weyl fermions in real materials is vital for both, promising applications and fundamental bridge between high-energy and condensed-matter physics. While the presence of Dirac and noncentrosymmetric Weyl fermions is well established in many materials, the magnetic Weyl semimetals still escape direct experimental detection. In order to find a time-reversal symmetry breaking Weyl state we design two materials and present here experimental and theoretical evidence of realization of such a state in one of them, YbMnBi2. We model the time-reversal symmetry breaking observed by magnetization and magneto-optical microscopy measurements by canted antiferromagnetism and find a number of Weyl points. Using angle-resolved photoemission, we directly observe two pairs of Weyl points connected by the Fermi arcs. Our results not only provide a fundamental link between the two areas of physics, but also demonstrate the practical way to design novel materials with exotic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 161, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3424, "DOI": "10.1038/s41467-019-11393-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11393-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477952600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Sun, HX; Zhang, Y; Yu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Li; Sun, Hai-Xin; Zhang, Yang; Yu, Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Cracking and Fractal Characteristics of Bending Fractured Polypropylene Fiber-Reinforced Geopolymer Mortar", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fiber is effective in restricting cracks and improving the toughness of geopolymer composites, but few studies have focused on the surface crack characteristics of fiber-reinforced geopolymer composites. In this paper, after flexural tests of polypropylene fiber-reinforced geopolymer mortar, the surface cracking image was collected by a digital camera and cracking information was extract by deep learning. Finally, the cracking and fractal characteristics were specifically discussed. The semantic segmentation network can accurately extract surface cracks for calculating various parameters. The results showed that the mean intersection over union (mIoU) and mean pixel accuracy (mPA) of the cracks are 0.8451 and 0.9213, respectively. Generally, the crack length, width, area, and fractal dimension of the specimen are all increased with the increase in the fiber volume fraction. These crack parameters grow rapidly when the fiber content is small, and the growth of the crack parameters gradually slows down as the fiber volume fraction increases to approximately 1.5%. The highest crack parameter values were found in the geopolymer mortar, with a 0.48 water-binder ratio and 12 mm fiber length. The variation of the bottom crack length and the side crack fractal dimension can be used to represent the overall crack variation patterns. Meanwhile, the crack parameters increase with the increased fiber factor in a quadratic function. Based on these crack parameters, the critical fiber factor and dense fiber factor of polypropylene fiber-reinforced geopolymer mortar were 200 and 550, respectively. They are greater than those of fiber-reinforced Portland cementitious composites. The influence of various crack parameters on the flexural strength is in the order of the crack area, width, length, and fractal dimension.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.3390/fractalfract5040142", "DOI Link": "http://dx.doi.org/10.3390/fractalfract5040142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737056600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, MD; Dai, F; Liu, Y; Jiang, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Mingdong; Dai, Feng; Liu, Yi; Jiang, Ruochen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fracture model for assessing tensile mode crack growth resistance of rocks", "Source Title": "JOURNAL OF ROCK MECHANICS AND GEOTECHNICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Evaluating the fracture resistance of rocks is essential for predicting and preventing catastrophic failure of cracked structures in rock engineering. This investigation developed a brittle fracture model to predict tensile mode (mode I) failure loads of cracked rocks. The basic principle of the model is to estimate the reference crack corresponding to the fracture process zone (FPZ) based on the maximum normal strain (MNSN) ahead of the crack tip, and then use the effective crack to calculate the fracture toughness. We emphasize that the non-singular stress/strain terms should be considered in the description of the MNSN. In this way, the FPZ, non-singular terms and the biaxial stress state at the crack tip are simultaneously considered. The principle of the model is explicit and easy to apply. To verify the proposed model, laboratory experiments were performed on a rock material using six groups of specimens. The model predicted the specimen geometry dependence of the measured fracture toughness well. Moreover, the potential of the model in analyzing the size effect of apparent fracture toughness was discussed and validated through experimental data reported in the literature. The model was demonstrated superior to some commonly used fracture models and is an excellent tool for the safety assessment of cracked rock structures. (c) 2023 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 395, "End Page": 411, "Article Number": null, "DOI": "10.1016/j.jrmge.2022.03.001", "DOI Link": "http://dx.doi.org/10.1016/j.jrmge.2022.03.001", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950190400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blakesley, JC; Castro, FA; Kylberg, W; Dibb, GFA; Arantes, C; Valaski, R; Cremona, M; Kim, JS; Kim, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blakesley, James C.; Castro, Fernulldo A.; Kylberg, William; Dibb, George F. A.; Arantes, Caroline; Valaski, Rogerio; Cremona, Marco; Kim, Jong Soo; Kim, Ji-Seon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards reliable charge-mobility benchmark measurements for organic semiconductors", "Source Title": "ORGANIC ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charge carrier mobility is a figure of merit commonly used to rate organic semiconducting materials for their suitability in applications such as solid-state lighting or photovoltaics. Although large variations are found in published mobility values on identical materials, there is little open discussion in the literature of the reproducibility of these results. We address this with an interlaboratory study of mobility measurements performed on a set of organic semiconductors using the space-charge limited current method. We found mobility measured on nominally identical devices could vary by more than one order of magnitude, with the largest sources of variation being poor electrodes and film thickness variation. Moreover, we found that mobility values extracted from identical data by different scientists would typically vary by a factor of 3. We propose a protocol for analysis and reporting that was found to reduce this analysis variation to as little as 20%. We also present general guidelines for improving the reproducibility of benchmark mobility measurements. Crown Copyright (C) 2014 Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 259, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1263, "End Page": 1272, "Article Number": null, "DOI": "10.1016/j.orgel.2014.02.008", "DOI Link": "http://dx.doi.org/10.1016/j.orgel.2014.02.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334740100025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gómez-Coca, S; Urtizberea, A; Cremades, E; Alonso, PJ; Camón, A; Ruiz, E; Luis, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gomez-Coca, Silvia; Urtizberea, Ainhoa; Cremades, Eduard; Alonso, Pablo J.; Camon, Agustin; Ruiz, Eliseo; Luis, Fernulldo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of slow magnetic relaxation in Kramers ions with non-uniaxial anisotropy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal ions with long-lived spin states represent minimum size magnetic bits. Magnetic memory has often been associated with the combination of high spin and strong uniaxial magnetic anisotropy. Yet, slow magnetic relaxation has also been observed in some Kramers ions with dominullt easy-plane magnetic anisotropy, albeit only under an external magnetic field. Here we study the spin dynamics of cobalt(II) ions in a model molecular complex. We show, by means of quantitative first-principles calculations, that the slow relaxation in this and other similar systems is a general consequence of time-reversal symmetry that hinders direct spin-phonon processes regardless of the sign of the magnetic anisotropy. Its magnetic field dependence is a subtle manifestation of electronuclear spin entanglement, which opens relaxation channels that would otherwise be forbidden but, at the same time, masks the relaxation phenomenon at zero field. These results provide a promising strategy to synthesize atom-size magnetic memories.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 367, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4300, "DOI": "10.1038/ncomms5300", "DOI Link": "http://dx.doi.org/10.1038/ncomms5300", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340613800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, HY; Yang, CT; Ueki, T; Pittman, CC; Xu, DK; Woodard, TL; Holmes, DE; Gu, TY; Wang, FH; Lovley, DR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Hai-Yan; Yang, Chuntian; Ueki, Toshiyuki; Pittman, Conor C.; Xu, Dake; Woodard, Trevor L.; Holmes, Dawn E.; Gu, Tingyue; Wang, Fuhui; Lovley, Derek R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stainless steel corrosion via direct iron-to-microbe electron transfer by Geobacter species", "Source Title": "ISME JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microbial corrosion of iron-based materials is a substantial economic problem. A mechanistic understanding is required to develop mitigation strategies, but previous mechanistic studies have been limited to investigations with relatively pure Fe(0), which is not a common structural material. We report here that the mechanism for microbial corrosion of stainless steel, the metal of choice for many actual applications, can be significantly different from that for Fe(0). Although H-2 is often an intermediary electron carrier between the metal and microbes during Fe(0) corrosion, we found that H-2 is not abiotically produced from stainless steel, making this corrosion mechanism unlikely. Geobacter sulfurreducens and Geobacter metallireducens, electrotrophs that are known to directly accept electrons from other microbes or electrodes, extracted electrons from stainless steel via direct iron-to-microbe electron transfer. Genetic modification to prevent H-2 consumption did not negatively impact on stainless steel corrosion. Corrosion was inhibited when genes for outer-surface cytochromes that are key electrical contacts were deleted. These results indicate that a common model of microbial Fe(0) corrosion by hydrogenase-positive microbes, in which H-2 serves as an intermediary electron carrier between the metal surface and the microbe, may not apply to the microbial corrosion of stainless steel. However, direct iron-to-microbe electron transfer is a feasible route for stainless steel corrosion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 151, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 15, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3084, "End Page": 3093, "Article Number": null, "DOI": "10.1038/s41396-021-00990-2", "DOI Link": "http://dx.doi.org/10.1038/s41396-021-00990-2", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648851600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smolenski, T; Dolgirev, PE; Clemens, K; Popert, A; Shimazaki, Y; Back, P; Lu, XB; Kroner, M; Watanabe, K; Taniguchi, T; Esterlis, I; Demler, E; Imamoglu, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smolenski, Tomasz; Dolgirev, Pavel E.; Kuhlenkamp, Clemens; Popert, Alexander; Shimazaki, Yuya; Back, Patrick; Lu, Xiaobo; Kroner, Martin; Watanabe, Kenji; Taniguchi, Takashi; Esterlis, Ilya; Demler, Eugene; Imamoglu, Atac", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Signatures of Wigner crystal of electrons in a monolayer semiconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The signature of a Wigner crystal-the analogue of a solid phase for electrons-is observed via the optical reflection spectrum in a monolayer transition metal dichalcogenide. When the Coulomb repulsion between electrons dominates over their kinetic energy, electrons in two-dimensional systems are predicted to spontaneously break continuous-translation symmetry and form a quantum crystal(1). Efforts to observe(2-12) this elusive state of matter, termed a Wigner crystal, in two-dimensional extended systems have primarily focused on conductivity measurements on electrons confined to a single Landau level at high magnetic fields. Here we use optical spectroscopy to demonstrate that electrons in a monolayer semiconductor with density lower than 3 x 10(11) per centimetre squared form a Wigner crystal. The combination of a high electron effective mass and reduced dielectric screening enables us to observe electronic charge order even in the absence of a moire potential or an external magnetic field. The interactions between a resonulltly injected exciton and electrons arranged in a periodic lattice modify the exciton bandstructure so that an umklapp resonullce arises in the optical reflection spectrum, heralding the presence of charge order(13). Our findings demonstrate that charge-tunable transition metal dichalcogenide monolayers(14) enable the investigation of previously uncharted territory for many-body physics where interaction energy dominates over kinetic energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2021, "Volume": 595, "Issue": 7865, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 53, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03590-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03590-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000668662100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Molodyk, A; Samoilenkov, S; Markelov, A; Degtyarenko, P; Lee, S; Petrykin, V; Gaifullin, M; Mankevich, A; Vavilov, A; Sorbom, B; Cheng, J; Garberg, S; Kesler, L; Hartwig, Z; Gavrilkin, S; Tsvetkov, A; Okada, T; Awaji, S; Abraimov, D; Francis, A; Bradford, G; Larbalestier, D; Senatore, C; Bonura, M; Pantoja, AE; Wimbush, SC; Strickland, NM; Vasiliev, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Molodyk, A.; Samoilenkov, S.; Markelov, A.; Degtyarenko, P.; Lee, S.; Petrykin, V.; Gaifullin, M.; Mankevich, A.; Vavilov, A.; Sorbom, B.; Cheng, J.; Garberg, S.; Kesler, L.; Hartwig, Z.; Gavrilkin, S.; Tsvetkov, A.; Okada, T.; Awaji, S.; Abraimov, D.; Francis, A.; Bradford, G.; Larbalestier, D.; Senatore, C.; Bonura, M.; Pantoja, A. E.; Wimbush, S. C.; Strickland, N. M.; Vasiliev, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development and large volume production of extremely high current density YBa2Cu3O7 superconducting wires for fusion", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fusion power density produced in a tokamak is proportional to its magnetic field strength to the fourth power. Second-generation high temperature superconductor (2G HTS) wires demonstrate remarkable engineering current density (averaged over the full wire), J(E), at very high magnetic fields, driving progress in fusion and other applications. The key challenge for HTS wires has been to offer an acceptable combination of high and consistent superconducting performance in high magnetic fields, high volume supply, and low price. Here we report a very high and reproducible J(E) in practical HTS wires based on a simple YBa2Cu3O7 (YBCO) superconductor formulation with Y2O3 nulloparticles, which have been delivered in just nine months to a commercial fusion customer in the largest-volume order the HTS industry has seen to date. We demonstrate a novel YBCO superconductor formulation without the c-axis correlated nullo-columnar defects that are widely believed to be prerequisite for high in-field performance. The simplicity of this new formulation allows robust and scalable manufacturing, providing, for the first time, large volumes of consistently high performance wire, and the economies of scale necessary to lower HTS wire prices to a level acceptable for fusion and ultimately for the widespread commercial adoption of HTS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2084, "DOI": "10.1038/s41598-021-81559-z", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-81559-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613018000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tetienne, JP; Dontschuk, N; Broadway, DA; Stacey, A; Simpson, DA; Hollenberg, LCL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tetienne, Jean-Philippe; Dontschuk, Nikolai; Broadway, David A.; Stacey, Alastair; Simpson, David A.; Hollenberg, Lloyd C. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum imaging of current flow in graphene", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since its first discovery in 2004, graphene has been found to host a plethora of unusual electronic transport phenomena, making it a fascinating system for fundamental studies in condensed matter physics as well as offering tremendous opportunities for future electronic and sensing devices. Typically, electronic transport in graphene has been investigated via resistivity measurements; however, these measurements are generally blind to spatial information critical to observing and studying landmark transport phenomena in real space and in realistic imperfect devices. We apply quantum imaging to the problem and demonstrate noninvasive, highresolution imaging of current flow in monolayer graphene structures. Our method uses an engineered array of near-surface, atomic-sized quantum sensors in diamond to map the vector magnetic field and reconstruct the vector current density over graphene geometries of varying complexity, from monoribbons to junctions, with spatial resolution at the diffraction limit and a projected sensitivity to currents as small as 1 mA. The measured currentmaps reveal strong spatial variations corresponding to physical defects at the submicrometer scale. The demonstrated method opens up an important new avenue to investigate fundamental electronic and spin transport in graphene structures and devices and, more generally, in emerging two-dimensional materials and thin-film systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602429", "DOI": "10.1126/sciadv.1602429", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602429", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Williams, DF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Williams, David F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges With the Development of Biomaterials for Sustainable Tissue Engineering", "Source Title": "FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of tissue engineering has tantalizingly offered the possibility of regenerating new tissue in order to treat a multitude of diseases and conditions within the human body. Nevertheless, in spite of significant progress with in vitro and small animal studies, progress toward realizing the clinical and commercial endpoints has been slow and many would argue that ultimate goals, especially in treating those conditions which, as yet, do not have acceptable conventional therapies, may never be reached because of flawed scientific rationale. In other words, sustainable tissue engineering may not be achievable with current approaches. One of the major factors here is the choice of biomaterial that is intended, through its use as a scaffold, to guide the regeneration process. For many years, effective specifications for these biomaterials have not been well-articulated, and the requirements for biodegradability and prior FDA approval for use in medical devices, have dominated material selection processes. This essay argues that these considerations are not only wrong in principle but counter-productive in practice. Materials, such as many synthetic bioabsorbable polymers, which are designed to have no biological activity that could stimulate target cells to express new and appropriate tissue, will not be effective. It is argued here that a traditional 'scaffold' represents the wrong approach, and that tissue-engineering templates that are designed to replicate the niche, or microenvironment, of these target cells are much more likely to succeed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2019, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 127, "DOI": "10.3389/fbioe.2019.00127", "DOI Link": "http://dx.doi.org/10.3389/fbioe.2019.00127", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470740000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Langelaar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Langelaar, Matthijs", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An additive manufacturing filter for topology optimization of print-ready designs", "Source Title": "STRUCTURAL AND MULTIDISCIPLINARY OPTIMIZATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) offers exciting opportunities to manufacture parts of unprecedented complexity. Topology optimization is essential to fully exploit this capability. However, AMprocesses have specific limitations as well. When these are not considered during design optimization, modifications are generally needed in post-processing, which add costs and reduce the optimized performance. This paper presents a filter that incorporates the main characteristics of a generic AM process, and that can easily be included in conventional density-based topology optimization procedures. Use of this filter ensures that optimized designs comply with typical geometrical AM restrictions. Its performance is illustrated on compliance minimization problems, and a 2D Matlab implementation is provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 292, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 55, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 871, "End Page": 883, "Article Number": null, "DOI": "10.1007/s00158-016-1522-2", "DOI Link": "http://dx.doi.org/10.1007/s00158-016-1522-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398114200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, S; Kim, K; Efimkin, DK; Lovorn, T; Taniguchi, T; Watanabe, K; MacDonald, AH; Tutuc, E; LeRoy, BJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Shengqiang; Kim, Kyounghwan; Efimkin, Dmitry K.; Lovorn, Timothy; Taniguchi, Takashi; Watanabe, Kenji; MacDonald, Allan H.; Tutuc, Emanuel; LeRoy, Brian J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topologically Protected Helical States in Minimally Twisted Bilayer Graphene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In minimally twisted bilayer graphene, a moire pattern consisting of AB and BA stacking regions separated by domain walls forms. These domain walls are predicted to support counterpropogating topologically protected helical (TPH) edge states when the AB and BA regions are gapped. We fabricate designer moire crystals with wavelengths longer than 50 nm and demonstrate the emergence of TPH states on the domain wall network by scanning tunneling spectroscopy measurements. We observe a double-line profile of the TPH states on the domain walls, only occurring when the AB and BA regions are gapped. Our results demonstrate a practical and flexible method for TPH state network construction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 217, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2018, "Volume": 121, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37702, "DOI": "10.1103/PhysRevLett.121.037702", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.037702", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438883600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fulcheri, L; Rohani, VJ; Wyse, E; Hardman, N; Dames, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fulcheri, Laurent; Rohani, Vandad-Julien; Wyse, Elliott; Hardman, Ned; Dames, Enoch", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An energy-efficient plasma methane pyrolysis process for high yields of carbon black and hydrogen", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel thermal plasma process was developed, which enables economically viable commercial-scale hydrogen and carbon black production. Key aspects of this process are detailed in this work. Selectivity and yield of both solid, high-value carbon and gaseous hydrogen are given particular attention. For the first time, technical viability is demon-strated through lab scale reactor data which indicate methane feedstock conversions of >99%, hydrogen selectivity of >95%, solid recovery of >90%, and the ability to produce carbon particles of varying crystallinity having the potential to replace traditional furnace carbon black. The energy intensity of this process was established based on real-time operation data from the first commercial plant utilizing this process. In its current stage, this technology uses around 25 kWh per kg of H2 produced, much less than water electrolysis which requires approximately 60 kWh per kg of H2 produced. This energy in-tensity is expected to be reduced to 18-20 kWh per kg of hydrogen with improved heat recovery and energy optimization.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 48, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2920, "End Page": 2928, "Article Number": null, "DOI": "10.1016/j.ijhydene.2022.10.144", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2022.10.144", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923709100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dinkgreve, M; Paredes, J; Denn, MM; Bonn, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dinkgreve, Maureen; Paredes, Jose; Denn, Morton M.; Bonn, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On different ways of measuring the yield stress", "Source Title": "JOURNAL OF NON-NEWTONIAN FLUID MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Yield stress materials are ubiquitous, yet the best way to obtain the value of the yield stress for any given material has been the subject of considerable debate. Here we compare different methods of measuring the yield stress with conventional rheometers that have been used in the literature on a variety of materials. The main conclusion is that, at least for well-behaved (non-thixotropic) materials, the differences between the various methods are significant; on the other hand, the scaling of the measured yield stress with the volume fraction of dispersed phase shows the same dependence independently of the way in which the yield stress is obtained experimentally. The measured yield strain is similarly found to depend on the method employed. The yield stress values obtained for a simple (non-thixotropic) yield stress fluid are only similar for Herschel-Bulkley fits and stress-strain curves obtained from oscillatory measurements. Stress-strain curves with a continuous imposed stress or strain rate differ significantly, as do oscillatory measurements of the crossover between G' and G '' or the point where G' starts to differ significantly from its linear response value. The intersection of the G' and G '' curves as a function of strain consistently give the highest value of the yield stress and yield strain. In addition, many of these criteria necessitate some arbitrary definition of a crossover point. Similar conclusions apply for a class of thixotropic yield stress materials, with the stress-strain curve from the oscillatory data giving the dynamic yield stress and the Herschel-Bulkley fit either the static or dynamic yield stress, depending on how the measurement is carried out. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 238, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 233, "End Page": 241, "Article Number": null, "DOI": "10.1016/j.jnnfm.2016.11.001", "DOI Link": "http://dx.doi.org/10.1016/j.jnnfm.2016.11.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390074600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, B; Kuang, MQ; Luo, Y; Li, YK; Hu, C; Liu, JR; Xiao, Q; Zheng, XQ; Huai, LW; Peng, ST; Wei, ZY; Shen, JC; Wang, BQ; Miao, Y; Sun, XP; Ou, ZP; Cui, ST; Sun, Z; Hashimoto, M; Lu, DH; Jozwiak, C; Bostwick, A; Rotenberg, E; Moreschini, L; Lanzara, A; Wang, Y; Peng, YY; Yao, YG; Wang, ZW; He, JF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Bo; Kuang, Min-Quan; Luo, Yang; Li, Yongkai; Hu, Cheng; Liu, Jiarui; Xiao, Qian; Zheng, Xiquan; Huai, Linwei; Peng, Shuting; Wei, Zhiyuan; Shen, Jianchang; Wang, Bingqian; Miao, Yu; Sun, Xiupeng; Ou, Zhipeng; Cui, Shengtao; Sun, Zhe; Hashimoto, Makoto; Lu, Donghui; Jozwiak, Chris; Bostwick, Aaron; Rotenberg, Eli; Moreschini, Luca; Lanzara, Alessandra; Wang, Yao; Peng, Yingying; Yao, Yugui; Wang, Zhiwei; He, Junfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable Van Hove Singularity without Structural Instability in Kagome Metal CsTi3Bi5", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In kagome metal CsV3Sb5, multiple intertwined orders are accompanied by both electronic and structural instabilities. These exotic orders have attracted much recent attention, but their origins remain elusive. The newly discovered CsTi3Bi5 is a Ti-based kagome metal to parallel CsV3Sb5. Here, we report angle-resolved photoemission experiments and first-principles calculations on pristine and Cs-doped CsTi3Bi5 samples. Our results reveal that the van Hove singularity (vHS) in CsTi3Bi5 can be tuned in a large energy range without structural instability, different from that in CsV3Sb5. As such, CsTi3Bi5 provides a complementary platform to disentangle and investigate the electronic instability with a tunable vHS in kagome metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2023, "Volume": 131, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26701, "DOI": "10.1103/PhysRevLett.131.026701", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.026701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053630400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, WH; Huang, XL; Semenok, DV; Chen, S; Zhou, D; Zhang, KX; Oganov, AR; Cui, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wuhao; Huang, Xiaoli; Semenok, Dmitrii V.; Chen, Su; Zhou, Di; Zhang, Kexin; Oganov, Artem R.; Cui, Tian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancement of superconducting properties in the La-Ce-H system at moderate pressures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ternary hydrides are regarded as an important platform for exploring high-temperature superconductivity at relatively low pressures. Here, we successfully synthesized the hcp-(La,Ce)H9-10 at 113GPa with the initial La/Ce ratio close to 3:1. The high-temperature superconductivity was strikingly observed at 176K and 100GPa with the extrapolated upper critical field H-c2(0) reaching 235T. We also studied the binary La-H system for comparison, which exhibited a T-c of 103K at 78GPa. The T-c and H-c2(0) of the La-Ce-H are respectively enhanced by over 80K and 100T with respect to the binary La-H and Ce-H components. The experimental results and theoretical calculations indicate that the formation of the solid solution contributes not only to enhanced stability but also to superior superconducting properties. These results show how better superconductors can be engineered in the new hydrides by large addition of alloy-forming elements. Recently, high-temperature superconductivity has been reported in LaH10 and CeH10. Here, the authors report superconductivity in the alloy (La,Ce)H9-10 with T-c=176K at 100GPa, providing an improved compromise between high transition temperature and low pressure requirements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 9", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2660, "DOI": "10.1038/s41467-023-38254-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38254-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053796300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, BL; Li, ZJ; Chu, Y; Tudi, A; Mutailipu, M; Zhang, FF; Yang, ZH; Pan, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Bingliang; Li, Zijian; Chu, Yu; Tudi, Abudukadi; Mutailipu, Miriding; Zhang, Fangfang; Yang, Zhihua; Pan, Shilie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "(NH4)3B11PO19F3: a deep-UV nonlinear optical crystal with unique [B5PO10F]∞ layers", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper reports a new nonlinear optical crystal that has a large second harmonic generation response, a short cutoff edge and a sufficient birefringence for deep-ultraviolet phase matching. Deep-ultraviolet (DUV) nonlinear optical (NLO) crystals that can extend the output range of coherent light below 200 nm are pivotal materials for solid-state lasers. To date, KBe2BO3F2 (KBBF) is the only usable crystal that can generate DUV coherent light by direct second harmonic generation (SHG), but the layered growth habit and toxic ingredients limit its application. Herein, we report a new fluoroborophosphate, (NH4)(3)B11PO19F3 (ABPF), containing four different functional units: [BO3], [BO4], [BO3F] and [PO4]. ABPF exhibits a KBBF-like structure while eliminating the limitations of KBBF crystal. The unique [B5PO10F](infinity) layers enhance ABPF's performance; for example, it has a large SHG response (1.2 x KDP) and a sufficient birefringence (0.088 at 1064 nm) that enables the shortest phase-matching wavelength to reach the DUV region. Meanwhile, the introduction of strong B-O-P covalent bonds decreases the layered growth habit. These findings will enrich the structural chemistry of fluoroborophosphate and contribute to the discovery of more excellent DUV NLO crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 9, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1093/nsr/nwac110", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwac110", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827920000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QF; Shen, XH; Savija, B; Meng, ZZ; Tsang, DCW; Sepasgozar, S; Schlangen, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qing-feng; Shen, Xiao-han; Savija, Branko; Meng, Zhaozheng; Tsang, Daniel C. W.; Sepasgozar, Samad; Schlangen, Erik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical study of interactive ingress of calcium leaching, chloride transport and multi-ions coupling in concrete", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In circumstances with wastewater and seawater, the behavior of multi-ions including calcium, chloride and others in concrete attracts attention. The present study investigated the multiple mechanisms that could happen under the special field situation above, including calcium leaching, chloride transport and multi-ion coupling. To realize the interactive ingress of multi ions, the simulation method for the processing of the individual mechanisms and the mutual influences is adopted. The distributions of the diversified ions are analyzed with the influence of the interfacial transition zone. The time-spatial distribution of porosity and its evolution mechanisms are investigated by considering the interaction with calcium ions in both pore solution and solid phase. The results indicate that calcium leaching would dominulltly speed up chloride transport due to the coarsened pore structure, while the multi ions electrochemical coupling effect would facilitate calcium leaching in the early stage but subtly delay calcium leaching in the later stage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 165, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107072, "DOI": "10.1016/j.cemconres.2022.107072", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2022.107072", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001033575100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Sharifzadeh, M; Mac Dowell, N; Welton, T; Shah, N; Hallett, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Long; Sharifzadeh, Mahdi; Mac Dowell, Niall; Welton, Tom; Shah, Nilay; Hallett, Jason P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inexpensive ionic liquids: [HSO4]--based solvent production at bulk scale", "Source Title": "GREEN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Through more than two decades' intensive research, ionic liquids (ILs) have exhibited significant potential in various areas of research at laboratory scales. This suggests that ILs-based industrial process development will attract increasing attention in the future. However, there is one core issue that stands in the way of commercialisation: the high cost of most laboratory-synthesized ILs will limit application to small-scale, specialized processes. In this work, we evaluate the economic feasibility of two ILs synthesized via acid-base neutralization using two scenarios for each: conventional and intensification processing. Based upon our initial models, we determined the cost price of each IL and compared the energy requirements of each process option. The cost prices of triethylammonium hydrogen sulfate and 1-methylimidazolium hydrogen sulfate are estimated as $1.24 kg(-1) and $2.96-5.88 kg(-1), respectively. This compares favourably with organic solvents such as acetone or ethyl acetate, which sell for $1.30-$1.40 kg(-1). Moreover, the raw materials contribute the overwhelming majority of this cost and the intensified process using a compact plate reactor is more economical due to lower energy requirements. These results indicate that ionic liquids are not necessarily expensive, and therefore large-scale IL-based processes can become a commercial reality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2014, "Volume": 16, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3098, "End Page": 3106, "Article Number": null, "DOI": "10.1039/c4gc00016a", "DOI Link": "http://dx.doi.org/10.1039/c4gc00016a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336836100021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yokoi, T; Ma, S; Kasahara, Y; Kasahara, S; Shibauchi, T; Kurita, N; Tanaka, H; Nasu, J; Motome, Y; Hickey, C; Trebst, S; Matsuda, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yokoi, T.; Ma, S.; Kasahara, Y.; Kasahara, S.; Shibauchi, T.; Kurita, N.; Tanaka, H.; Nasu, J.; Motome, Y.; Hickey, C.; Trebst, S.; Matsuda, Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Half-integer quantized anomalous thermal Hall effect in the Kitaev material candidate α-RuCl3", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Half-integer thermal quantum Hall conductance has recently been reported for the two-dimensional honeycomb material alpha-RuCl3. We found that the half-integer thermal Hall plateau appears even for a magnetic field with no out-of-plane components. The measured field-angular variation of the quantized thermal Hall conductance has the same sign structure as the topological Chern number of the pure Kitaev spin liquid. This observation suggests that the non-Abelian topological order associated with fractionalization of the local magnetic moments persists even in the presence of non-Kitaev interactions in alpha-RuCl3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 198, "Times Cited, All Databases": 213, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 30", "Publication Year": 2021, "Volume": 373, "Issue": 6554, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 568, "End Page": "+", "Article Number": "aay5551", "DOI": "10.1126/science.aay5551", "DOI Link": "http://dx.doi.org/10.1126/science.aay5551", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000681716000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Flick, J; Ruggenthaler, M; Appel, H; Rubio, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Flick, Johannes; Ruggenthaler, Michael; Appel, Heiko; Rubio, Angel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atoms and molecules in cavities, from weak to strong coupling in quantum-electrodynamics (QED) chemistry", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we provide an overview of how well-established concepts in the fields of quantum chemistry and material sciences have to be adapted when the quantum nature of light becomes important in correlated matter-photon problems. We analyze model systems in optical cavities, where the matter-photon interaction is considered from the weak-to the strong-coupling limit and for individual photon modes as well as for the multimode case. We identify fundamental changes in Born-Oppenheimer surfaces, spectroscopic quantities, conical intersections, and efficiency for quantum control. We conclude by applying our recently developed quantum-electrodynamical density-functional theory to spontaneous emission and show how a straightforward approximation accurately describes the correlated electron-photon dynamics. This work paves the way to describe matter-photon interactions from first principles and addresses the emergence of new states of matter in chemistry and material science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 407, "Times Cited, All Databases": 419, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2017, "Volume": 114, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3026, "End Page": 3034, "Article Number": null, "DOI": "10.1073/pnas.1615509114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1615509114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396893600044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DH; Wu, WT; Fang, S; Kang, Y; Wang, XN; Hu, W; Yu, HB; Zhang, HC; Liu, X; Luo, YM; He, JH; Fu, L; Long, SB; Liu, S; Sun, HD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Danhao; Wu, Wentiao; Fang, Shi; Kang, Yang; Wang, Xiaoning; Hu, Wei; Yu, Huabin; Zhang, Haochen; Liu, Xin; Luo, Yuanmin; He, Jr-Hau; Fu, Lan; Long, Shibing; Liu, Sheng; Sun, Haiding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of polarity-switchable photoconductivity in III-nitride/MoSx core-shell nullowires", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "III-V semiconductor nullowires are indispensable building blocks for nulloscale electronic and optoelectronic devices. However, solely relying on their intrinsic physical and material properties sometimes limits device functionalities to meet the increasing demands in versatile and complex electronic world. By leveraging the distinctive nature of the one-dimensional geometry and large surface-to-volume ratio of the nullowires, new properties can be attained through monolithic integration of conventional nullowires with other easy-synthesized functional materials. Herein, we combine high-crystal-quality III-nitride nullowires with amorphous molybdenum sulfides (a-MoSx) to construct III-nitride/a-MoSx core-shell nullostructures. Upon light illumination, such nullostructures exhibit striking spectrally distinctive photodetection characteristic in photoelectrochemical environment, demonstrating a negative photoresponsivity of -100.42 mA W-1 under 254 nm illumination, and a positive photoresponsivity of 29.5 mA W-1 under 365 nm illumination. Density functional theory calculations reveal that the successful surface modification of the nullowires via a-MoSx decoration accelerates the reaction process at the electrolyte/nullowire interface, leading to the generation of opposite photocurrent signals under different photon illumination. Most importantly, such polarity-switchable photoconductivity can be further tuned for multiple wavelength bands photodetection by simply adjusting the surrounding environment and/or tailoring the nullowire composition, showing great promise to build light-wavelength controllable sensing devices in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 227, "DOI": "10.1038/s41377-022-00912-7", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00912-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827748000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kollár, AJ; Fitzpatrick, M; Houck, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kollar, Alicia J.; Fitzpatrick, Mattias; Houck, Andrew A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hyperbolic lattices in circuit quantum electrodynamics", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "After two decades of development, cavity quantum electrodynamics with superconducting circuits has emerged as a rich platform for quantum computation and simulation. Lattices of coplanar waveguide resonators constitute artificial materials for microwave photons, in which interactions between photons can be incorporateded either through the use of nonlinear resonator materials or through coupling between qubits and resonators. Here we make use of the previously overlooked property that these lattice sites are deformable and permit tight-binding lattices that are unattainable even in solid-state systems. We show that networks of coplanar waveguide resonators can create a class of materials that constitute lattices in an effective hyperbolic space with constant negative curvature. We present numerical simulations of hyperbolic analogues of the kagome lattice that show unusual densities of states in which a macroscopic number of degenerate eigenstates comprise a spectrally isolated flat band. We present a proof-of-principle experimental realization of one such lattice. This paper represents a step towards on-chip quantum simulation of materials science and interacting particles in curved space.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 4", "Publication Year": 2019, "Volume": 571, "Issue": 7763, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1348-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1348-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473755200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, S; Kang, MG; Go, D; Kim, D; Kang, JH; Lee, T; Lee, GH; Kang, J; Lee, NJ; Mokrousov, Y; Kim, S; Kim, KJ; Lee, KJ; Park, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Soogil; Kang, Min-Gu; Go, Dongwook; Kim, Dohyoung; Kang, Jun-Ho; Lee, Taekhyeon; Lee, Geun-Hee; Kang, Jaimin; Lee, Nyun Jong; Mokrousov, Yuriy; Kim, Sanghoon; Kim, Kab-Jin; Lee, Kyung-Jin; Park, Byong-Guk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient conversion of orbital Hall current to spin current for spin-orbit torque switching", "Source Title": "COMMUNICATIONS PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin Hall effect, an electric generation of spin current, allows for efficient control of magnetization. Recent theory revealed that orbital Hall effect creates orbital current, which can be much larger than spin-Hall-induced spin current. However, orbital current cannot directly exert a torque on a ferromagnet, requiring a conversion process from orbital current to spin current. Here, we report two effective methods of the conversion through spin-orbit coupling engineering, which allows us to unambiguously demonstrate orbital-current-induced spin torque, or orbital Hall torque. We find that orbital Hall torque is greatly enhanced by introducing either a rare-earth ferromagnet Gd or a Pt interfacial layer with strong spin-orbit coupling in Cr/ferromagnet structures, indicating that the orbital current generated in Cr is efficiently converted into spin current in the Gd or Pt layer. Our results offer a pathway to utilize the orbital current to further enhance the magnetization switching efficiency in spin-orbit-torque-based spintronic devices. Manipulation of the magnetization is of major importance in spintronics. The authors demonstrate that an electric field triggers a transverse flow of orbital moment: the so-called orbital Hall effect. This enables the efficient magnetization control, holding the promise for fast and miniaturized memories and sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 122, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 234, "DOI": "10.1038/s42005-021-00737-7", "DOI Link": "http://dx.doi.org/10.1038/s42005-021-00737-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000713595900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Faber, FA; Lindmaa, A; von Lilienfeld, OA; Armiento, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Faber, Felix A.; Lindmaa, Alexander; von Lilienfeld, O. Anatole; Armiento, Rickard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine Learning Energies of 2 Million Elpasolite (ABC2D6) Crystals", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Elpasolite is the predominullt quaternary crystal structure (AlNaK2F6 prototype) reported in the Inorganic Crystal Structure Database. We develop a machine learning model to calculate density functional theory quality formation energies of all similar to 2 x 10(6) pristine ABC(2)D(6) elpasolite crystals that can be made up from main-group elements (up to bismuth). Our model's accuracy can be improved systematically, reaching a mean absolute error of 0.1 eV/atom for a training set consisting of 10 x 10(3) crystals. Important bonding trends are revealed: fluoride is best suited to fit the coordination of the D site, which lowers the formation energy whereas the opposite is found for carbon. The bonding contribution of the elements A and B is very small on average. Low formation energies result from A and B being late elements from group II, C being a late (group I) element, and D being fluoride. Out of 2 x 10(6) crystals, 90 unique structures are predicted to be on the convex hull-among which is NFAl2Ca6, with a peculiar stoichiometry and a negative atomic oxidation state for Al.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 374, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2016, "Volume": 117, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 135502, "DOI": "10.1103/PhysRevLett.117.135502", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.117.135502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000383849400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, J; Kim, W; Oh, DK; Kang, H; Kim, H; Badloe, T; Kim, S; Park, C; Choi, H; Lee, H; Rho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Joohoon; Kim, Wonjoong; Oh, Dong Kyo; Kang, Hyunjung; Kim, Hongyoon; Badloe, Trevon; Kim, Seokwoo; Park, Chanwoong; Choi, Hojung; Lee, Heon; Rho, Junsuk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-step printable platform for high-efficiency metasurfaces down to the deep-ultraviolet region", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A single-step printable platform for ultraviolet (UV) metasurfaces is introduced to overcome both the scarcity of low-loss UV materials and manufacturing limitations of high cost and low throughput. By dispersing zirconium dioxide (ZrO2) nulloparticles in a UV-curable resin, ZrO2 nulloparticle-embedded-resin (nullo-PER) is developed as a printable material which has a high refractive index and low extinction coefficient from near-UV to deep-UV. In ZrO2 nullo-PER, the UV-curable resin enables direct pattern transfer and ZrO2 nulloparticles increase the refractive index of the composite while maintaining a large bandgap. With this concept, UV metasurfaces can be fabricated in a single step by nulloimprint lithography. As a proof of concept, UV metaholograms operating in near-UV and deep-UV are experimentally demonstrated with vivid and clear holographic images. The proposed method enables repeat and rapid manufacturing of UV metasurfaces, and thus will bring UV metasurfaces more close to real life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 68, "DOI": "10.1038/s41377-023-01086-6", "DOI Link": "http://dx.doi.org/10.1038/s41377-023-01086-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000946074400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kiendl, J; Hsu, MC; Wu, MCH; Reali, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kiendl, Josef; Hsu, Ming-Chen; Wu, Michael C. H.; Reali, Alessandro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isogeometric Kirchhoff-Love shell formulations for general hyperelastic materials", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present formulations for compressible and incompressible hyperelastic thin shells which can use general 3D constitutive models. The necessary plane stress condition is enforced analytically for incompressible materials and iteratively for compressible materials. The thickness stretch is statically condensed and the shell kinematics are completely described by the first and second fundamental forms of the midsurface. We use C-1-continuous isogeometric discretizations to build the numerical models. Numerical tests, including structural dynamics simulations of a bioprosthetic heart valve, show the good performance and applicability of the presented methods. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2015, "Volume": 291, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 280, "End Page": 303, "Article Number": null, "DOI": "10.1016/j.cma.2015.03.010", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2015.03.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354403300013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghimire, NJ; Dally, RL; Poudel, L; Jones, DC; Michel, D; Magar, NT; Bleuel, M; McGuire, MA; Jiang, JS; Mitchell, JF; Lynn, JW; Mazin, II", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghimire, Nirmal J.; Dally, Rebecca L.; Poudel, L.; Jones, D. C.; Michel, D.; Magar, N. Thapa; Bleuel, M.; McGuire, Michael A.; Jiang, J. S.; Mitchell, J. F.; Lynn, Jeffrey W.; Mazin, I. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Competing magnetic phases and fluctuation-driven scalar spin chirality in the kagome metal YMn6Sn6", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Identification, understanding, and manipulation of novel magnetic textures are essential for the discovery of new quantum materials for future spin-based electronic devices. In particular, materials that manifest a large response to external stimuli such as a magnetic field are subject to intense investigation. Here, we study the kagome-net magnet YMn6Sn6 by magnetometry, transport, and neutron diffraction measurements combined with first-principles calculations. We identify a number of nontrivial magnetic phases, explain their microscopic nature, and demonstrate that one of them hosts a large topological Hall effect (THE). We propose a previously unidentified fluctuation-driven mechanism, which leads to the THE at elevated temperatures. This interesting physics comes from parametrically frustrated interplanar exchange interactions that trigger strong magnetic fluctuations. Our results pave a path to chiral spin textures, promising for novel spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 6, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabe2680", "DOI": "10.1126/sciadv.abe2680", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abe2680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599905500047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Uri, A; de la Barrera, SC; Randeria, MT; Rodan-Legrain, D; Devakul, T; Crowley, PJD; Paul, N; Watanabe, K; Taniguchi, T; Lifshitz, R; Fu, L; Ashoori, RC; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Uri, Aviram; de la Barrera, Sergio C.; Randeria, Mallika T.; Rodan-Legrain, Daniel; Devakul, Trithep; Crowley, Philip J. D.; Paul, Nisarga; Watanabe, Kenji; Taniguchi, Takashi; Lifshitz, Ron; Fu, Liang; Ashoori, Raymond C.; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity and strong interactions in a tunable moire quasicrystal", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronic states in quasicrystals generally preclude a Bloch description(1), rendering them fascinating and enigmatic. Owing to their complexity and scarcity, quasicrystals are underexplored relative to periodic and amorphous structures. Here we introduce a new type of highly tunable quasicrystal easily assembled from periodic components. By twisting three layers of graphene with two different twist angles, we form two mutually incommensurate moire patterns. In contrast to many common atomic-scale quasicrystals(2,3), the quasiperiodicity in our system is defined on moire length scales of several nullometres. This 'moire quasicrystal' allows us to tune the chemical potential and thus the electronic system between a periodic-like regime at low energies and a strongly quasiperiodic regime at higher energies, the latter hosting a large density of weakly dispersing states. Notably, in the quasiperiodic regime, we observe superconductivity near a flavour-symmetry-breaking phase transition(4,5), the latter indicative of the important role that electronic interactions play in that regime. The prevalence of interacting phenomena in future systems with in situ tunability is not only useful for the study of quasiperiodic systems but may also provide insights into electronic ordering in related periodic moire crystals(6-12). We anticipate that extending this platform to engineer quasicrystals by varying the number of layers and twist angles, and by using different two-dimensional components, will lead to a new family of quantum materials to investigate the properties of strongly interacting quasicrystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 620, "Issue": 7975, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-023-06294-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06294-z", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038056400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, XM; Farahi, G; Chiu, CL; Papic, Z; Watanabe, K; Taniguchi, T; Zaletel, MP; Yazdani, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Xiaomeng; Farahi, Gelareh; Chiu, Cheng-Li; Papic, Zlatko; Watanabe, Kenji; Taniguchi, Takashi; Zaletel, Michael P.; Yazdani, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualizing broken symmetry and topological defects in a quantum Hall ferromagnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interaction between electrons in graphene under high magnetic fields drives the formation of a rich set of quantum Hall ferromagnetic (QHFM) phases with broken spin or valley symmetry. Visualizing atomic-scale electronic wave functions with scanning tunneling spectroscopy (STS), we resolved microscopic signatures of valley ordering in QHFM phases and spectral features of fractional quantum Hall phases of graphene. At charge neutrality, we observed a field-tuned continuous quantum phase transition from a valley-polarized state to an intervalley coherent state, with a Kekule distortion of its electronic density. Mapping the valley texture extracted from STS measurements of the Kekule phase, we could visualize valley skyrmion excitations localized near charged defects. Our techniques can be applied to examine valley-ordered phases and their topological excitations in a wide range of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2022, "Volume": 375, "Issue": 6578, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 321, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abm3770", "DOI Link": "http://dx.doi.org/10.1126/science.abm3770", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000745036100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JS; Chiang, CC; Xia, X; Yoo, TJ; Ren, F; Kim, H; Pearton, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jian-Sian; Chiang, Chao-Ching; Xia, Xinyi; Yoo, Timothy Jinsoo; Ren, Fan; Kim, Honggyu; Pearton, S. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Demonstration of 4.7 kV breakdown voltage in NiO/β-Ga2O3 vertical rectifiers", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Vertical heterojunction NiO/beta n-Ga2O/n(+) Ga2O3 rectifiers employing NiO layer extension beyond the rectifying contact for edge termination exhibit breakdown voltages (V-B) up to 4.7kV with a power figure-of-merits, V-B(2)/R-ON of 2GW.cm(-2), where R-ON is the on-state resistance (11.3 m Omega cm(2)). Conventional rectifiers fabricated on the same wafers without NiO showed V-B values of 840V and a power figure-of-merit of 0.11GW cm(-2). Optimization of the design of the two-layer NiO doping and thickness and also the extension beyond the rectifying contact by TCAD showed that the peak electric field at the edge of the rectifying contact could be significantly reduced. The leakage current density before breakdown was 144mA/cm(2), the forward current density was 0.8kA/cm(2) at 12V, and the turn-on voltage was in the range of 2.2-2.4 V compared to 0.8V without NiO. Transmission electron microscopy showed sharp interfaces between NiO and epitaxial Ga2O3 and a small amount of disorder from the sputtering process. Published under an exclusive license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2022, "Volume": 121, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42105, "DOI": "10.1063/5.0097564", "DOI Link": "http://dx.doi.org/10.1063/5.0097564", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884197100006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, B; Lee, DE; Hu, G; Natarajan, Y; Preethaa, S; Rathinakumar, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Bubryur; Lee, Dong-Eun; Hu, Gang; Natarajan, Yuvaraj; Preethaa, Sri; Rathinakumar, Arun Pandian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ensemble Machine Learning-Based Approach for Predicting of FRP-Concrete Interfacial Bonding", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developments in fiber-reinforced polymer (FRP) composite materials have created a huge impact on civil engineering techniques. Bonding properties of FRP led to its wide usage with concrete structures for interfacial bonding. FRP materials show great promise for rehabilitation of existing infrastructure by strengthening concrete structures. Existing machine learning-based models for predicting the FRP-concrete bond strength have not attained maximum performance in evaluating the bond strength. This paper presents an ensemble machine learning approach capable of predicting the FRP-concrete interfacial bond strength. In this work, a dataset holding details of 855 single-lap shear tests on FRP-concrete interfacial bonds extracted from the literature is used to build a bond strength prediction model. Test results hold data of different material properties and geometrical parameters influencing the FRP-concrete interfacial bond. This study employs CatBoost algorithm, an improved ensemble machine learning approach used to accurately predict bond strength of FRP-concrete interface. The algorithm performance is compared with those of other ensemble methods (i.e., histogram gradient boosting algorithm, extreme gradient boosting algorithm, and random forest). The CatBoost algorithm outperforms other ensemble methods with various performance metrics (i.e., lower root mean square error (2.310), lower covariance (21.8%), lower integral absolute error (8.8%), and higher R-square (96.1%)). A comparative study is performed between the proposed model and best performing bond strength prediction models in the literature. The results show that FRP-concrete interfacial bonding can be effectively predicted using proposed ensemble method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 37, "Times Cited, All Databases": 37, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 231, "DOI": "10.3390/math10020231", "DOI Link": "http://dx.doi.org/10.3390/math10020231", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747084300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, ZH; Zhao, NN; Yin, QW; Gong, CS; Tu, ZJ; Li, M; Song, WH; Liu, ZT; Shen, DW; Huang, YB; Liu, K; Lei, HC; Wang, SC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Zhonghao; Zhao, Ningning; Yin, Qiangwei; Gong, Chunsheng; Tu, Zhijun; Li, Man; Song, Wenhua; Liu, Zhengtai; Shen, Dawei; Huang, Yaobo; Liu, Kai; Lei, Hechang; Wang, Shancai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge-Density-Wave-Induced Bands Renormalization and Energy Gaps in a Kagome Superconductor RbV3Sb5", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently discovered Z(2) topological kagome metals AV(3)Sb(5) (A = K, Rb, and Cs) exhibit charge-densitywave (CDW) phases and novel superconducting paring states providing a versatile platform for studying the interplay between electron correlation and quantum orders. Here we directly visualize CDW-induced bands renormalization and energy gaps in RbV3Sb5 using angle-resolved photoemission spectroscopy pointing to the key role of tuning van Hove singularities to the Fermi energy in mechanisms of ordering phases. Near the CDW transition temperature, the bands around the Brillouin zone (BZ) boundary are shifted to high-binding energy, forming an M-shaped band with singularities near the Fermi energy. The Fermi surfaces are partially gapped, and the electronic states on the residual ones should be possibly dedicated to the superconductivity. Our findings are significant in understanding CDW formation and its associated superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2021, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41010, "DOI": "10.1103/PhysRevX.11.041010", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.041010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000707492800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hassandoost, R; Kotb, A; Movafagh, Z; Esmat, M; Guegan, R; Endo, S; Jevasuwan, W; Fukata, N; Sugahara, Y; Khataee, A; Yamauchi, Y; Ide, Y; Doustkhah, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hassandoost, Ramin; Kotb, Ahmed; Movafagh, Zahra; Esmat, Mohamed; Guegan, Regis; Endo, Saki; Jevasuwan, Wipakorn; Fukata, Naoki; Sugahara, Yoshiyuki; Khataee, Alireza; Yamauchi, Yusuke; Ide, Yusuke; Doustkhah, Esmail", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloarchitecturing bimetallic manganese cobaltite spinels for sonocatalytic degradation of oxytetracycline", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Degradation of contaminullts of emerging concern in aqueous media using bimetallic oxides is a promising novel strategy that requires engineering new catalytic routes in bimetallic oxides to perform advanced oxidation; however, several challenges to synthesizing and developing such materials with enhanced, sustainable catalytic features are still being investigated. This study presents the effective use of a manganese cobaltite bimetallic spinel compound for sonocatalysis. We prepared three morphologies of manganese cobaltite for using in the sonocatalytic degradation of oxytetracycline (OTC). The morphology of manganese cobaltite was tuned by changing the amounts of the Mn and Co precursors in the early stage of synthesis. Several manganese cobaltite spinels with different structures-porous layered-like cubes (MCO-PLC), layered-like ellipsoids (MCO-LE), and rough spheroids (MCO-RS) were obtained and characterized using various techniques. A promising catalytic degradation capability of MCO-PLC for OTC (10.0 mg L-1) was obtained at a natural pH within 120 min. We also investigated the reusability of MCO-PLC sonocatalyst and metal (Mn and Co) leaching in water media. The sonocatalytic mechanisms and fragments produced from OTC during degradation were determined via electron paramagnetic resonullce and gas chromatography-mass spectroscopy analyses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2022, "Volume": 431, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 133851, "DOI": "10.1016/j.cej.2021.133851", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2021.133851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000777761500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "García, A; Papior, N; Akhtar, A; Artacho, E; Blum, V; Bosoni, E; Brandimarte, P; Brandbyge, M; Cerda, JI; Corsetti, F; Cuadrado, R; Dikan, V; Ferrer, J; Gale, J; García-Fernández, P; García-Suárez, VM; García, S; Huhs, G; Illera, S; Korytár, R; Koval, P; Lebedeva, I; Lin, L; López-Tarifa, P; Mayo, SG; Mohr, S; Ordejón, P; Postnikov, A; Pouillon, Y; Pruneda, M; Robles, R; Sánchez-Portal, D; Soler, JM; Ullah, R; Yu, VWZ; Junquera, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Garcia, Alberto; Papior, Nick; Akhtar, Arsalan; Artacho, Emilio; Blum, Volker; Bosoni, Emanuele; Brandimarte, Pedro; Brandbyge, Mads; Cerda, J., I; Corsetti, Fabiano; Cuadrado, Ramon; Dikan, Vladimir; Ferrer, Jaime; Gale, Julian; Garcia-Fernulldez, Pablo; Garcia-Suarez, V. M.; Garcia, Sandra; Huhs, Georg; Illera, Sergio; Korytar, Richard; Koval, Peter; Lebedeva, Irina; Lin, Lin; Lopez-Tarifa, Pablo; Mayo, Sara G.; Mohr, Stephan; Ordejon, Pablo; Postnikov, Andrei; Pouillon, Yann; Pruneda, Miguel; Robles, Roberto; Sanchez-Portal, Daniel; Soler, Jose M.; Ullah, Rafi; Yu, Victor Wen-zhe; Junquera, Javier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Siesta: Recent developments and applications", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A review of the present status, recent enhancements, and applicability of the Siesta program is presented. Since its debut in the mid-1990s, Siesta's flexibility, efficiency, and free distribution have given advanced materials simulation capabilities to many groups worldwide. The core methodological scheme of Siesta combines finite-support pseudo-atomic orbitals as basis sets, norm-conserving pseudopotentials, and a real-space grid for the representation of charge density and potentials and the computation of their associated matrix elements. Here, we describe the more recent implementations on top of that core scheme, which include full spin-orbit interaction, non-repeated and multiple-contact ballistic electron transport, density functional theory (DFT)+U and hybrid functionals, time-dependent DFT, novel reduced-scaling solvers, density-functional perturbation theory, efficient van der Waals non-local density functionals, and enhanced molecular-dynamics options. In addition, a substantial effort has been made in enhancing interoperability and interfacing with other codes and utilities, such as wannier90 and the second-principles modeling it can be used for, an AiiDA plugin for workflow automatization, interface to Lua for steering Siesta runs, and various post-processing utilities. Siesta has also been engaged in the Electronic Structure Library effort from its inception, which has allowed the sharing of various low-level libraries, as well as data standards and support for them, particularly the PSeudopotential Markup Language definition and library for transferable pseudopotentials, and the interface to the ELectronic Structure Infrastructure library of solvers. Code sharing is made easier by the new open-source licensing model of the program. This review also presents examples of application of the capabilities of the code, as well as a view of on-going and future developments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 335, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2020, "Volume": 152, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1063/5.0005077", "DOI Link": "http://dx.doi.org/10.1063/5.0005077", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537898900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaiser, C; Sandberg, OJ; Zarrabi, N; Li, W; Meredith, P; Armin, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kaiser, Christina; Sandberg, Oskar J.; Zarrabi, Nasim; Li, Wei; Meredith, Paul; Armin, Ardalan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A universal Urbach rule for disordered organic semiconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In crystalline semiconductors, absorption onset sharpness is characterized by temperature-dependent Urbach energies. These energies quantify the static, structural disorder causing localized exponential-tail states, and dynamic disorder from electron-phonon scattering. Applicability of this exponential-tail model to disordered solids has been long debated. Nonetheless, exponential fittings are routinely applied to sub-gap absorption analysis of organic semiconductors. Herein, we elucidate the sub-gap spectral line-shapes of organic semiconductors and their blends by temperature-dependent quantum efficiency measurements. We find that sub-gap absorption due to singlet excitons is universally dominated by thermal broadening at low photon energies and the associated Urbach energy equals the thermal energy, regardless of static disorder. This is consistent with absorptions obtained from a convolution of Gaussian density of excitonic states weighted by Boltzmann-like thermally activated optical transitions. A simple model is presented that explains absorption line-shapes of disordered systems, and we also provide a strategy to determine the excitonic disorder energy. Our findings elaborate the meaning of the Urbach energy in molecular solids and relate the photo-physics to static disorder, crucial for optimizing organic solar cells for which we present a revisited radiative open-circuit voltage limit. The sub-gap absorption coefficient in organic semiconductors is often characterized by Urbach energies, which quantify both structural and dynamic disorders, yet the fundamental is not well-understood. Here, the authors provide a strategy to determine excitonic disorder energy, and reveal that absorption at energies well below the gap is universally dominated by thermal broadening.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 129, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3988, "DOI": "10.1038/s41467-021-24202-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24202-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000669943800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liaskos, C; Nie, S; Tsioliaridou, A; Pitsillides, A; Ioannidis, S; Akyildiz, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liaskos, Christos; Nie, Shuai; Tsioliaridou, Ageliki; Pitsillides, Andreas; Ioannidis, Sotiris; Akyildiz, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Wireless Communication Paradigm through Software-Controlled Metasurfaces", "Source Title": "IEEE COMMUNICATIONS MAGAZINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic waves undergo multiple uncontrollable alterations as they propagate within a wireless environment. Free space path loss, signal absorption, as well as reflections, refractions, and diffractions caused by physical objects within the environment highly affect the performance of wireless communications. Currently, such effects are intractable to account for and are treated as probabilistic factors. This article proposes a radically different approach, enabling deterministic, programmable control over the behavior of wireless environments. The key enabler is the so-called HyperSurface tile, a novel class of planar meta-materials that can interact with impinging electromagnetic waves in a controlled manner. The HyperSurface tiles can effectively re-engineer electromagnetic waves, including steering toward any desired direction, full absorption, polarization manipulation, and more. Multiple tiles are employed to coat objects such as walls, furniture, and overall, any objects in indoor and outdoor environments. An external software service calculates and deploys the optimal interaction types per tile to best fit the needs of communicating devices. Evaluation via simulations highlights the potential of the new concept.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 840, "Times Cited, All Databases": 878, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 56, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 162, "End Page": 169, "Article Number": null, "DOI": "10.1109/MCOM.2018.1700659", "DOI Link": "http://dx.doi.org/10.1109/MCOM.2018.1700659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444843900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Linka, K; Hillgärtner, M; Abdolazizi, KP; Aydin, RC; Itskov, M; Cyron, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Linka, Kevin; Hillgartner, Markus; Abdolazizi, Kian P.; Aydin, Roland C.; Itskov, Mikhail; Cyron, Christian J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constitutive artificial neural networks: A fast and general approach to predictive data-driven constitutive modeling by deep learning", "Source Title": "JOURNAL OF COMPUTATIONAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper we introduce constitutive artificial neural networks (CANNs), a novel machine learning architecture for data-driven modeling of the mechanical constitutive behavior of materials. CANNs are able to incorporate by their very design information from three different sources, namely stress-strain data, theoretical knowledge from materials theory, and diverse additional information (e.g., about microstructure or materials processing). CANNs can easily and efficiently be implemented in standard computational software. They require only a low-to-moderate amount of training data and training time to learn without human guidance the constitutive behavior also of complex nonlinear and anisotropic materials. Moreover, in a simple academic example we demonstrate how the input of microstructural data can endow CANNs with the ability to describe not only the behavior of known materials but to predict also the properties of new materials where no stress-strain data are available yet. This ability may be particularly useful for the future in-silico design of new materials. The developed source code of the CANN architecture and accompanying example data sets are available at https://github.com/ConstitutiveANN/CANN. (C) 2020 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2021, "Volume": 429, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110010, "DOI": "10.1016/j.jcp.2020.110010", "DOI Link": "http://dx.doi.org/10.1016/j.jcp.2020.110010", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618824500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klein, J; Lorke, M; Florian, M; Sigger, F; Sigl, L; Rey, S; Wierzbowski, J; Cerne, J; Müller, K; Mitterreiter, E; Zimmermann, P; Taniguchi, T; Watanabe, K; Wurstbauer, U; Kaniber, M; Knap, M; Schmidt, R; Finley, JJ; Holleitner, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klein, J.; Lorke, M.; Florian, M.; Sigger, F.; Sigl, L.; Rey, S.; Wierzbowski, J.; Cerne, J.; Mueller, K.; Mitterreiter, E.; Zimmermann, P.; Taniguchi, T.; Watanabe, K.; Wurstbauer, U.; Kaniber, M.; Knap, M.; Schmidt, R.; Finley, J. J.; Holleitner, A. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Site-selectively generated photon emitters in monolayer MoS2 via local helium ion irradiation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum light sources in solid-state systems are of major interest as a basic ingredient for integrated quantum photonic technologies. The ability to tailor quantum emitters via site-selective defect engineering is essential for realizing scalable architectures. However, a major difficulty is that defects need to be controllably positioned within the material. Here, we overcome this challenge by controllably irradiating monolayer MoS2 using a sub-nm focused helium ion beam to deterministically create defects. Subsequent encapsulation of the ion exposed MoS2 flake with high-quality hBN reveals spectrally narrow emission lines that produce photons in the visible spectral range. Based on ab-initio calculations we interpret these emission lines as stemming from the recombination of highly localized electron-hole complexes at defect states generated by the local helium ion exposure. Our approach to deterministically write optically active defect states in a single transition metal dichalcogenide layer provides a platform for realizing exotic many-body systems, including coupled single-photon sources and interacting exciton lattices that may allow the exploration of Hubbard physics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2755, "DOI": "10.1038/s41467-019-10632-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10632-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000472480700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sakakibara, H; Usui, H; Suzuki, K; Kotani, T; Aoki, H; Kuroki, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sakakibara, Hirofumi; Usui, Hidetomo; Suzuki, Katsuhiro; Kotani, Takao; Aoki, Hideo; Kuroki, Kazuhiko", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Model Construction and a Possibility of Cupratelike Pairing in a New d9 Nickelate Superconductor (Nd,Sr)NiO2", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Effective models are constructed for a newly discovered superconductor (Nd, Sr)NiO2, which has been considered as a possible nickelate analog of the cuprates. Estimation of the effective interaction, which turns out to require a multiorbital model that takes account of all the orbitals involved on the Fermi surface, shows that the effective interactions are significantly larger than in the cuprates. A fluctuation exchange study suggests occurrence of d(x2-y2)-wave superconductivity, where the transition temperature should be lowered from the cuprates due to the larger interaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2020, "Volume": 125, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77003, "DOI": "10.1103/PhysRevLett.125.077003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.077003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558974000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ho, CK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ho, Clifford K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advances in central receivers for concentrating solar applications", "Source Title": "SOLAR ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper provides a review of current state-of-the-art commercial central receiver systems and emerging technologies intended to increase the outlet temperature to >700 degrees C. Research on particle-based, gas based, and liquid-based receiver designs that can achieve these higher temperatures are discussed. Particle-based technologies include directly irradiated designs (free-falling, obstructed, centrifugal) and enclosed designs (gravity fed, fluidized). New gas-based receivers include micro-channel designs and light-trapping configurations that increase the surface area, heat transfer, and solar absorptance to enable higher fluxes and pressures. Liquid-based receivers and materials that are reviewed include high temperature halide salts (chlorides and fluorides), carbonate salts, and liquid metals (sodium and lead bismuth). Advantages and challenges associated with each of the technologies and receiver designs are presented. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 152, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 38, "End Page": 56, "Article Number": null, "DOI": "10.1016/j.solener.2017.03.048", "DOI Link": "http://dx.doi.org/10.1016/j.solener.2017.03.048", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408286900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YM; Yu, JW; Zhang, R; Yuan, J; Hultmark, S; Johnson, CE; Gallop, NP; Siegmund, B; Qian, DP; Zhang, HT; Zou, YP; Kemerink, M; Bakulin, AA; Mueller, C; Vandewal, K; Chen, XK; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuming; Yu, Jianwei; Zhang, Rui; Yuan, Jun; Hultmark, Sandra; Johnson, Catherine E.; Gallop, Nathaniel P.; Siegmund, Bernhard; Qian, Deping; Zhang, Huotian; Zou, Yingping; Kemerink, Martijn; Bakulin, Artem A.; Mueller, Christian; Vandewal, Koen; Chen, Xian-Kai; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origins of the open-circuit voltage in ternary organic solar cells and design rules for minimized voltage losses", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The power conversion efficiency of ternary organic solar cells (TOSCs), consisting of one host binary blend and one guest component, remains limited by large voltage losses. The fundamental understanding of the open-circuit voltage (V-OC) in TOSCs is controversial, limiting rational design of the guest component. In this study, we systematically investigate how the guest component affects the radiative and non-radiative related parts of V-OC of a series of TOSCs using the detailed balanced principle. We highlight that the thermal population of charge-transfer and local exciton states provided by the guest binary blend (that is, the guest-component-based binary blend) has a significant influence on the non-radiative voltage losses. Ultimately, we provide two design rules for enhancing the V-OC in TOSCs: high emission yield for the guest binary blend and similar charge-transfer-state energies for host/guest binary blends; high miscibility of the guest component with the low gap component in the host binary blend. The performance of ternary organic solar cells is limited by voltage losses. Using the detailed balance principle, Wang et al. show how the third component of the blend affects the open-circuit voltage and delineate molecular design rules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 978, "End Page": 988, "Article Number": null, "DOI": "10.1038/s41560-023-01309-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01309-5", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037353300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Zhou, SH; Shi, Y; Huang, YJ; Zhao, F; Huo, TT; Tang, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Zhou, Shihua; Shi, Yan; Huang, Yajun; Zhao, Feng; Huo, Tingting; Tang, Shengwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Influence of Fly Ash Dosages on the Permeability, Pore Structure and Fractal Features of Face Slab Concrete", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Concrete-face slabs are the primary anti-permeability structures of the concrete-face rockfill dam (CFRD), and the resistance of face slab concrete to permeability is the key factor affecting the operation and safety of CFRDs. Herein, the influences of five fly ash dosages (namely 10%, 20%, 30%, 40% and 50%) on the permeability property of face slab concretes were investigated. Moreover, the difference in the permeability caused by the fly ash dosage variations is revealed in terms of the pore structure and fractal theory. The results illustrate that: (1) The inclusion of 10-50% fly ash lowered the compressive strength of face slab concretes before 28 days of hydration, whereas it contributed to the 180-day strength increment. (2) The incorporation of 10-50% fly ash raised the average water-seepage height (D-m) and the relative permeability coefficient (K-r) of the face slab concrete by about 14-81% and 30-226% at 28 days, respectively. At 180 days, the addition of fly ash improved the 180-day impermeability by less than 30%. (3) The permeability of face slab concretes is closely correlated with their pore structures and D-s. (4) The optimal fly ash dosage in terms of the long-term impermeability and pore refinement of face slab concretes is around 30%. Nevertheless, face slab concretes containing a high dosage of fly ash must be cured for a relatively long period before they can withstand high water pressure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 47, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 476, "DOI": "10.3390/fractalfract6090476", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6090476", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000858182500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, RX; Weisen, AR; Lee, Y; Aplan, MA; Fenton, AM; Masucci, AE; Kempe, F; Sommer, M; Pester, CW; Colby, RH; Gomez, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Renxuan; Weisen, Albree R.; Lee, Youngmin; Aplan, Melissa A.; Fenton, Abigail M.; Masucci, Ashley E.; Kempe, Fabian; Sommer, Michael; Pester, Christian W.; Colby, Ralph H.; Gomez, Enrique D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Glass transition temperature from the chemical structure of conjugated polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The glass transition temperature (T-g) is a key property that dictates the applicability of conjugated polymers. The T-g demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable, or flexible electronics. Here we show that a single adjustable parameter can be used to build a relationship between the T-g and the molecular structure of 32 semiflexible (mostly conjugated) polymers that differ drastically in aromatic backbone and alkyl side chain chemistry. An effective mobility value zeta, is calculated using an assigned atomic mobility value within each repeat unit. The only adjustable parameter in the calculation of zeta is the ratio of mobility between conjugated and non-conjugated atoms. We show that. correlates strongly to the T-g, and that this simple method predicts the T-g with a root-mean-square error of 13 degrees C for conjugated polymers with alkyl side chains.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 893, "DOI": "10.1038/s41467-020-14656-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14656-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564261700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sebastián, N; Copic, M; Mertelj, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sebastian, Nerea; Copic, Martin; Mertelj, Alenka", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric nematic liquid-crystalline phases", "Source Title": "PHYSICAL REVIEW E", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent experimental realization of ferroelectric nematic liquid crystalline phases stimulated material develop-ment and numerous experimental studies of these phases, guided by their fundamental and applicative interest. In this Perspective, we give an overview of this emerging field by linking history and theoretical predictions to a general outlook of the development and properties of the materials exhibiting ferroelectric nematic phases. We will highlight the most relevant observations to date, e.g., giant dielectric permittivity values, polarization values an order of magnitude larger than in classical ferroelectric liquid crystals, and nonlinear optical coefficients comparable with several ferroelectric solid materials. Key observations of anchoring and electro-optic behavior will also be examined. The collected contributions lead to a final discussion on open challenges in materials development, theoretical description, experimental explorations, and possible applications of the ferroelectric phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 106, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21001, "DOI": "10.1103/PhysRevE.106.021001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevE.106.021001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860023200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, LN; Bandara, SR; Tan, ZZ; Leal, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Lining; Bandara, Sarith R.; Tan, Zhengzhong; Leal, Cecilia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lipid nulloparticle topology regulates endosomal escape and delivery of RNA to the cytoplasm", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "RNA therapeutics have the potential to resolve a myriad of genetic diseases. Lipid nulloparticles (LNPs) are among the most successful RNA delivery systems. Expanding their use for the treatment of more genetic diseases hinges on our ability to continuously evolve the design of LNPs with high potency, cellular-specific targeting, and low side effects. Overcoming the difficulty of releasing cargo from endocytosed LNPs remains a significant hurdle. Here, we investigate the fundamental properties of nonviral RNA nulloparticles pertaining to the activation of topological transformations of endosomal membranes and RNA translocation into the cytosol. We show that, beyond composition, LNP fusogenicity can be prescribed by designing LNP nullostructures that lower the energetic cost of fusion and fusion-pore formation with a target membrane. The inclusion of structurally active lipids leads to enhanced LNP endosomal fusion, fast evasion of endosomal entrapment, and efficacious RNA delivery. For example, conserving the lipid make-up, RNA-LNPs having cuboplex nullostructures are significantly more efficacious at endosomal escape than traditional lipoplex constructs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2023, "Volume": 120, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2301067120", "DOI": "10.1073/pnas.2301067120", "DOI Link": "http://dx.doi.org/10.1073/pnas.2301067120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001030882800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Olejník, K; Seifert, T; Kaspar, Z; Novák, V; Wadley, P; Campion, RP; Baumgartner, M; Gambardella, P; Nemec, P; Wunderlich, J; Sinova, J; Kuzel, P; Müller, M; Kampfrath, T; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Olejnik, Kamil; Seifert, Tom; Kaspar, Zdenek; Novak, Vit; Wadley, Peter; Campion, Richard P.; Baumgartner, Manuel; Gambardella, Pietro; Nemec, Petr; Wunderlich, Joerg; Sinova, Jairo; Kuzel, Petr; Mueller, Melanie; Kampfrath, Tobias; Jungwirth, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Terahertz electrical writing speed in an antiferromagnetic memory", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The speed of writing of state-of-the-art ferromagnetic memories is physically limited by an intrinsic gigahertz threshold. Recently, realization of memory devices based on antiferromagnets, in which spin directions periodically alternate from one atomic lattice site to the next has moved research in an alternative direction. We experimentally demonstrate at room temperature that the speed of reversible electrical writing in a memory device can be scaled up to terahertz using an antiferromagnet. A current-induced spin-torque mechanism is responsible for the switching in our memory devices throughout the 12-order-of-magnitude range of writing speeds from hertz to terahertz. Our work opens the path toward the development of memory-logic technology reaching the elusive terahertz band.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 251, "Times Cited, All Databases": 269, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar3566", "DOI": "10.1126/sciadv.aar3566", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar3566", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431373300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gates-Rector, S; Blanton, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gates-Rector, Stacy; Blanton, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Powder Diffraction File: a quality materials characterization database", "Source Title": "POWDER DIFFRACTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ICDD' s Powder Diffraction File (TM) (PDF (R)) is a database of inorganic and organic diffraction data used for phase identification and materials characterization by powder diffraction. The PDF has been available for over 75 years and finds application in X-ray, synchrotron, electron, and neutron diffraction analyses. With entries based on powder and single crystal data, the PDF is the only crystallographic database where every entry is editorially reviewed and marked with a quality mark that alerts the user to the reliability/quality of the submitted data. The editorial processes of ICDD' s quality management system are unique in that they are ISO 9001:2015 certified. Initially offered as text on paper cards and books, the PDF evolved to a computer-readable database in the 1960s and today is both computer and web accessible. With data mining and phase identification software available in PDF products, and the databases' compatibility with vendor (third party) software, the 1 000 000+ published PDF entries serve a wide range of disciplines covering academic, industrial, and government laboratories. Details describing the content of database entries are presented to enhance the use of the PDF. (C) 2019 International Centre for Diffraction Data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 961, "Times Cited, All Databases": 1003, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 34, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 352, "End Page": 360, "Article Number": null, "DOI": "10.1017/S0885715619000812", "DOI Link": "http://dx.doi.org/10.1017/S0885715619000812", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500163500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TT; Yvonnet, J; Zhu, QZ; Bornert, M; Chateau, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, T. T.; Yvonnet, J.; Zhu, Q. -Z.; Bornert, M.; Chateau, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A phase field method to simulate crack nucleation and propagation in strongly heterogeneous materials from direct imaging of their microstructure", "Source Title": "ENGINEERING FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, crack initiation and propagation in 2D and 3D highly heterogeneous materials models, such as those obtained by micro-CT imagery of cementitious materials, is investigated for the first time by means of the phase field method. A shifted strain split operator algorithm is proposed to handle unilateral contact within cracks in a very efficient manner. The various advantages of the phase field method for voxel-based models are discussed. More specifically, we show that the resolution related to the initial image and thus to meshes for discretizing the same microstructure does not significantly affect the simulated crack path. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 139, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18, "End Page": 39, "Article Number": null, "DOI": "10.1016/j.engfracmech.2015.03.045", "DOI Link": "http://dx.doi.org/10.1016/j.engfracmech.2015.03.045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353894300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feist, J; Garcia-Vidal, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feist, Johannes; Garcia-Vidal, Francisco J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extraordinary Exciton Conductance Induced by Strong Coupling", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate that exciton conductance in organic materials can be enhanced by several orders of magnitude when the molecules are strongly coupled to an electromagnetic mode. Using a 1D model system, we show how the formation of a collective polaritonic mode allows excitons to bypass the disordered array of molecules and jump directly from one end of the structure to the other. This finding could have important implications in the fields of exciton transistors, heat transport, photosynthesis, and biological systems in which exciton transport plays a key role.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2015, "Volume": 114, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 196402, "DOI": "10.1103/PhysRevLett.114.196402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.196402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354363600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SL; Fan, HR; Liu, X; Meng, JY; Butcher, AR; Yann, L; Yang, KF; Li, XC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Shuang-Liang; Fan, Hong-Rui; Liu, Xuan; Meng, Jianyin; Butcher, Alan R.; Yann, Lahaye; Yang, Kui-Feng; Li, Xiao-Chun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Global rare earth elements projects: New developments and supply chains", "Source Title": "ORE GEOLOGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rare earth elements (REE) are key enablers for the ongoing energy and environmental transition as they are critical raw materials in many low-carbon technologies. In the past few years, many new REE projects have been developed worldwide to replenish the market, and thus are changing the supply chains. Meanwhile, compre-hensive data are lacking regarding these projects, impeding investors and policymakers from having a clear view of the global supply of REE. This study establishes a new database of REE projects, along with detailed infor-mation sources. Based on these data, we present the current situation and give some critical perspectives on the future. It is shown that there are at least total 146 advanced and mining projects, involving over 303.4 million tons of rare earth oxides around the world and some newly designed supply chains. Among those projects, carbonatite type deposits are currently the main sources and most likely will dominullt future targets for exploration and mining. Asia remains the largest source of REE, but Greenland, Africa, and Europe show important resource potentials if environmental issues and processing technologies are well addressed. Finally, we review rare earth projects in terms of estimated value and heavy rare earth elements resources amounts, and further list some REE deposits that deserve more attention based on this new database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 81, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 157, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105428, "DOI": "10.1016/j.oregeorev.2023.105428", "DOI Link": "http://dx.doi.org/10.1016/j.oregeorev.2023.105428", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000976864900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, P; Chu, Y; Tudi, A; Xie, CW; Yang, ZH; Pan, SL; Li, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peng; Chu, Yu; Tudi, Abudukadi; Xie, Congwei; Yang, Zhihua; Pan, Shilie; Li, Junjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Combination of Structure Prediction and Experiment for the Exploration of Alkali-Earth Metal-Contained Chalcopyrite-Like IR Nonlinear Optical Material", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Design and fabrication of new infrared (IR) nonlinear optical (NLO) materials with balanced properties are urgently needed since commercial chalcopyrite-like (CL) NLO crystals are suffering from their intrinsic drawbacks. Herein, the first defect-CL (DCL) alkali-earth metal (AEM) selenide IR NLO material, DCL-MgGa2Se4, has been rationally designed and fabricated by a structure prediction and experiment combined strategy. The introduction of AEM tetrahedral unit MgSe4 effectively widens the band gap of DCL compounds. The title compound exhibits a wide band gap of 2.96 eV, resulting in a high laser induced damage threshold (LIDT) of approximate to 3.0 x AgGaS2 (AGS). Furthermore, the compound shows a suitable second harmonic generation (SHG) response (approximate to 0.9 x AGS) with a type-I phase-matching (PM) behavior and a wide IR transparent range. The results indicate that DCL-MgGa2Se4 is a promising mid-to-far IR NLO material and give some insights into the design of new CL compound with outstanding IR NLO properties based on the AEM tetrahedra and the structure predication and experiment combined strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 9, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2106120, "DOI": "10.1002/advs.202106120", "DOI Link": "http://dx.doi.org/10.1002/advs.202106120", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780138300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Volk, AA; Epps, RW; Yonemoto, DT; Masters, BS; Castellano, FN; Reyes, KG; Abolhasani, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Volk, Amanda A.; Epps, Robert W.; Yonemoto, Daniel T.; Masters, Benjamin S.; Castellano, Felix N.; Reyes, Kristofer G.; Abolhasani, Milad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "AlphaFlow: autonomous discovery and optimization of multi-step chemistry using a self-driven fluidic lab guided by reinforcement learning", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Closed-loop, autonomous experimentation enables accelerated and material-efficient exploration of large reaction spaces without the need for user intervention. However, autonomous exploration of advanced materials with complex, multi-step processes and data sparse environments remains a challenge. In this work, we present AlphaFlow, a self-driven fluidic lab capable of autonomous discovery of complex multi-step chemistries. AlphaFlow uses reinforcement learning integrated with a modular microdroplet reactor capable of performing reaction steps with variable sequence, phase separation, washing, and continuous in-situ spectral monitoring. To demonstrate the power of reinforcement learning toward high dimensionality multi-step chemistries, we use AlphaFlow to discover and optimize synthetic routes for shell-growth of core-shell semiconductor nulloparticles, inspired by colloidal atomic layer deposition (cALD). Without prior knowledge of conventional cALD parameters, AlphaFlow successfully identified and optimized a novel multi-step reaction route, with up to 40 parameters, that outperformed conventional sequences. Through this work, we demonstrate the capabilities of closed-loop, reinforcement learning-guided systems in exploring and solving challenges in multi-step nulloparticle syntheses, while relying solely on in-house generated data from a miniaturized microfluidic platform. Further application of AlphaFlow in multi-step chemistries beyond cALD can lead to accelerated fundamental knowledge generation as well as synthetic route discoveries and optimization. Autonomous exploration of materials design space is hindered by its high dimensionality and the scarcity of data. In this work, we present AlphaFlow, a self-driven lab guided by reinforcement learning that enables accelerated discovery and optimization of multi-step chemistries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1403, "DOI": "10.1038/s41467-023-37139-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37139-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055247000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Sun, Y; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yang; Sun, Yan; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Berry curvature dipole in Weyl semimetal materials: An ab initio study", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noncentrosymmetric metals are anticipated to exhibit a dc photocurrent in the nonlinear optical response caused by the Berry curvature dipole in momentum space. Weyl semimetals (WSMs) are expected to be excellent candidates for observing these nonlinear effects because they carry a large Berry curvature concentrated in small regions, i.e., near the Weyl points. We have implemented the semiclassical Berry curvature dipole formalism into an ab initio scheme and investigated the second-order nonlinear response for two representative groups of materials: the TaAs-family type-I WSMs and the MoTe2-family type-II WSMs. Both types of WSMs exhibited a Berry curvature dipole in which type-II Weyl points are usually superior to the type-I WSM because of the strong tilt. Corresponding nonlinear susceptibilities in several materials promise a nonlinear Hall effect in the dc field limit, which is within the experimentally detectable range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 186, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2018, "Volume": 97, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41101, "DOI": "10.1103/PhysRevB.97.041101", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.041101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419098700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Avila, J; Momblona, C; Boix, PP; Sessolo, M; Bolink, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Avila, Jorge; Momblona, Cristina; Boix, Pablo P.; Sessolo, Michele; Bolink, Henk J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapor-Deposited Perovskites: The Route to High-Performance Solar Cell Production?", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-quality semiconducting perovskites can be easily synthesized through several methods. The ease of fabrication has favored the adoption of lab-scale solution-processing techniques, which have yielded the highest performing devices. Most of these processes, however, are not directly applicable to larger scale and volume preparations, hindering the consolidation and market entry of this technology. Vapor-based methods, a mature technology widely adopted in the coating and semiconductor industry, could change this trend. Their application to perovskite solar cells includes a large amount of fabrication approaches, offering versatility in the employed materials as well as in the characteristics of the resulting perovskite films. It is thus essential to review the fundamentals of perovskite vapor-related techniques in order to put their real potential and challenges into perspective.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 303, "Times Cited, All Databases": 321, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 431, "End Page": 442, "Article Number": null, "DOI": "10.1016/j.joule.2017.07.014", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.07.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425301500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YF; Li, WW; Peng, YX; Tang, SW; Wang, L; Shi, Y; Li, Y; Wang, Y; Geng, ZC; Wu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yifan; Li, Wenwei; Peng, Yuxiang; Tang, Shengwen; Wang, Lei; Shi, Yan; Li, Yang; Wang, Yang; Geng, Zhicheng; Wu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydration and Fractal Analysis on Low-Heat Portland Cement Pastes Using Thermodynamics-Based Methods", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Low-heat Portland (LHP) cement is a kind of high-belite cement, which has the characteristic of low hydration heat. Currently, it is extensively used in the temperature control of mass concrete. Based on the thermodynamic database of OPC-based materials, the thermodynamic software GEM-Selektor (noted as GEMS) is used for simulating the hydration products of the LHP cement paste. Then, according to the GEMS thermodynamic simulation results, MATLAB is used to visualize the initial and ultimate stages of LHP cement pastes; the effects of curing temperature and water to cement (w/c) ratio on hydration products are addressed; and the porosity, fractal dimension, and tortuosity of different pastes are calculated. It is found that an appropriately high curing temperature is important for reducing porosity, especially in the early hydration stage. Hydration time also has a significant impact on the hydration of LHP cement paste; long hydration time may reduce the impact of temperature on hydration products. The w/c ratio is another important consideration regarding the hydration degree and porosity of LHP paste, and under different curing temperatures, hydration times, and w/c ratios, the porosity varies from 5.91-32.91%. The fractal dimension of this work agrees with the previous findings. From tortuosity analysis, it can be concluded that the high curing temperature may cause significant tortuosity, further affecting the effective diffusivity of LHP cement paste. For cement pastes with low w/c ratio, this high curing temperature effect is mainly reflected in the early hydration stage, for ones with high w/c ratio, it is in turn evident under long-term curing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 606, "DOI": "10.3390/fractalfract7080606", "DOI Link": "http://dx.doi.org/10.3390/fractalfract7080606", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055249200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peterson, CW; Li, TH; Benalcazar, WA; Hughes, TL; Bahl, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peterson, Christopher W.; Li, Tianhe; Benalcazar, Wladimir A.; Hughes, Taylor L.; Bahl, Gaurav", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fractional corner anomaly reveals higher-order topology", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spectral measurements of boundary-localized topological modes are commonly used to identify topological insulators. For high-order insulators, these modes appear at boundaries of higher codimension, such as the corners of a two-dimensional material. Unfortunately, this spectroscopic approach is only viable if the energies of the topological modes lie within the bulk bandgap, which is not required for many topological crystalline insulators. The key topological feature in these insulators is instead fractional charge density arising from filled bulk hands, but measurements of such charge distributions have not been accessible to date. We experimentally measure boundary-localized fractional charge density in rotationally symmetric two-dimensional metamaterials and find one-fourth and one-third fractionalization. We then introduce a topological indicator that allows for the unambiguous identification of higher-order topology, even without in-gap states, and we demonstrate the associated higher-order hulk-boundary correspondence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2020, "Volume": 368, "Issue": 6495, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1114, "End Page": "+", "Article Number": "aba7604", "DOI": "10.1126/science.aba7604", "DOI Link": "http://dx.doi.org/10.1126/science.aba7604", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000539738400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamarulzaman, N; Kasim, MF; Rusdi, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamarulzaman, Norlida; Kasim, Muhd Firdaus; Rusdi, Roshidah", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band Gap Narrowing and Widening of ZnO nullostructures and Doped Materials", "Source Title": "nullOSCALE RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Band gap change in doped ZnO is an observed phenomenon that is very interesting from the fundamental point of view. This work is focused on the preparation of pure and single phase nullostructured ZnO and Cu as well as Mn-doped ZnO for the purpose of understanding the mechanisms of band gap narrowing in the materials. ZnO, Zn0.99Cu0.01O and Zn0.99Mn0.01O materials were prepared using a wet chemistry method, and X-ray diffraction (XRD) results showed that all samples were pure and single phase. UV-visible spectroscopy showed that materials in the nullostructured state exhibit band gap widening with respect to their micron state while for the doped compounds exhibited band gap narrowing both in the nullo and micron states with respect to the pure ZnO materials. The degree of band gap change was dependent on the doped elements and crystallite size. X-ray photoelectron spectroscopy (XPS) revealed that there were shifts in the valence bands. From both UV-visible and XPS spectroscopy, it was found that the mechanism for band gap narrowing was due to the shifting of the valance band maximum and conduction band minimum of the materials. The mechanisms were different for different samples depending on the type of dopant and dimensional length scales of the crystallites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 291, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2015, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 346, "DOI": "10.1186/s11671-015-1034-9", "DOI Link": "http://dx.doi.org/10.1186/s11671-015-1034-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369813900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amoroso, D; Barone, P; Picozzi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amoroso, Danila; Barone, Paolo; Picozzi, Silvia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spontaneous skyrmionic lattice from anisotropic symmetric exchange in a Ni-halide monolayer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological spin structures, such as magnetic skyrmions, hold great promises for data storage applications, thanks to their inherent stability. In most cases, skyrmions are stabilized by magnetic fields in non-centrosymmetric systems displaying the chiral Dzyaloshinskii-Moriya exchange interaction, while spontaneous skyrmion lattices have been reported in centrosymmetric itinerant magnets with long-range interactions. Here, a spontaneous anti-biskyrmion lattice with unique topology and chirality is predicted in the monolayer of a semiconducting and centrosymmetric metal halide, NiI2. Our first-principles and Monte Carlo simulations reveal that the anisotropies of the short-range symmetric exchange, when combined with magnetic frustration, can lead to an emergent chiral interaction that is responsible for the predicted topological spin structures. The proposed mechanism finds a prototypical manifestation in two-dimensional magnets, thus broadening the class of materials that can host spontaneous skyrmionic states. Skyrmions, topological spin textures, are typically stabilized by the Dzyaloshinskii-Moriya interaction and an applied magnetic field. In this theoretical study, by analysing monolayer NiI2, the authors suggest that two-site anisotropy with magnetic frustration can stabilize a skyrmion lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 151, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5784, "DOI": "10.1038/s41467-020-19535-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19535-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000594648000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuate, LJN; Chen, ZZ; Lu, JL; Wen, HB; Guo, F; Shi, WL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuate, Loic Jiresse Nguetsa; Chen, Zhouze; Lu, Jialin; Wen, Huabing; Guo, Feng; Shi, Weilong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photothermal-Assisted Photocatalytic Degradation of Tetracycline in Seawater Based on the Black g-C3N4 nullosheets with Cyano Group Defects", "Source Title": "CATALYSTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a broad-spectrum antibiotic, tetracycline (TC) has been continually detected in soil and seawater environments, which poses a great threat to the ecological environment and human health. Herein, a black graphitic carbon nitride (CN-B) photocatalyst was synthesized by the one-step calcination method of urea and phloxine B for the degradation of tetracycline TC in seawater under visible light irradiation. The experimental results showed that the photocatalytic degradation rate of optimal CN-B-0.1 for TC degradation was 92% at room temperature within 2 h, which was 1.3 times that of pure CN (69%). This excellent photocatalytic degradation performance stems from the following factors: (i) ultrathin nullosheet thickness reduces the charge transfer distance; (ii) the cyanogen defect promotes photogenerated carriers' separation; (iii) and the photothermal effect of CN-B increases the reaction temperature and enhances the photocatalytic activity. This study provides new insight into the design of photocatalysts for the photothermal-assisted photocatalytic degradation of antibiotic pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1147, "DOI": "10.3390/catal13071147", "DOI Link": "http://dx.doi.org/10.3390/catal13071147", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038039700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Landi, S Jr; Segundo, IR; Freitas, E; Vasilevskiy, M; Carneiro, J; Tavares, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Landi, Salmon, Jr.; Segundo, Iran Rocha; Freitas, Elisabete; Vasilevskiy, Mikhail; Carneiro, Joaquim; Tavares, Carlos Jose", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Use and misuse of the Kubelka-Munk function to obtain the band gap energy from diffuse reflectance measurements", "Source Title": "SOLID STATE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The determination of the optical band gap energy (E-g) is important for optimization of the generation of electron/hole pairs in semiconductor materials under illumination. For this purpose, the classical theory proposed by Kubelka and Munk (K-M) has been largely employed for the study of amorphous and polycrystalline materials. In this paper, the authors demonstrate, step by step, how to use the K-M function and apply it thoroughly to the determination of the E-g of TiO2 semiconductor powder (pressed at different thicknesses) from diffuse reflectance spectroscopy (DRS) measurements. For the sample thicknesses 1-4 mm, E-g values of 3.12-3.14 eV were obtained. With this work it is envisaged a clarification to the procedure of determination of the E-g from the K-M theory and DRS data, since some drawbacks, and misconceptions have been identified in the recent literature. In particular, the widely used practice of determining the E-g of a material directly from the K-M function is found to be inadequate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 341, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114573, "DOI": "10.1016/j.ssc.2021.114573", "DOI Link": "http://dx.doi.org/10.1016/j.ssc.2021.114573", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000725057500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karni, O; Barré, E; Pareek, V; Georgaras, JD; Man, MKL; Sahoo, C; Bacon, DR; Zhu, X; Ribeiro, HB; O'Beirne, AL; Hu, J; Al-Mahboob, A; Abdelrasoul, MMM; Chan, NS; Karmakar, A; Winchester, AJ; Kim, B; Watanabe, K; Taniguchi, T; Barmak, K; Madéo, J; da Jornada, FH; Heinz, TF; Dani, KM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karni, Ouri; Barre, Elyse; Pareek, Vivek; Georgaras, Johnathan D.; Man, Michael K. L.; Sahoo, Chakradhar; Bacon, David R.; Zhu, Xing; Ribeiro, Henrique B.; O'Beirne, Aidan L.; Hu, Jenny; Al-Mahboob, Abdullah; Abdelrasoul, Mohamed M. M.; Chan, Nicholas S.; Karmakar, Arka; Winchester, Andrew J.; Kim, Bumho; Watanabe, Kenji; Taniguchi, Takashi; Barmak, Katayun; Madeo, Julien; da Jornada, Felipe H.; Heinz, Tony F.; Dani, Keshav M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure of the moire exciton captured by imaging its electron and hole", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interlayer excitons (ILXs) - electron-hole pairs bound across two atomically thin layered semiconductors - have emerged as attractive platforms to study exciton condensation(1-4), single-photon emission and other quantum information applications(5-7). Yet, despite extensive optical spectroscopic investigations(8-12), critical information about their size, valley configuration and the influence of the moire potential remains unknown. Here, in a WSe2/MoS2 heterostructure, we captured images of the time-resolved and momentum-resolved distribution of both of the particles that bind to form the ILX: the electron and the hole. We thereby obtain a direct measurement of both the ILX diameter of around 5.2 nm, comparable with the moire-unit-cell length of 6.1 nm, and the localization of its centre of mass. Surprisingly, this large ILX is found pinned to a region of only 1.8 nm diameter within the moire cell, smaller than the size of the exciton itself. This high degree of localization of the ILX is backed by Bethe-Salpeter equation calculations and demonstrates that the ILX can be localized within small moire unit cells. Unlike large moire cells, these are uniform over large regions, allowing the formation of extended arrays of localized excitations for quantum technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 603, "Issue": 7900, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 247, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04360-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04360-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936099600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, QG; Wang, B; Liang, J; Liu, J; Liang, B; Li, GL; Long, YH; Zhang, GY; Liu, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Quanguo; Wang, Bing; Liang, Jing; Liu, Jun; Liang, Bo; Li, Guangli; Long, Yaohang; Zhang, Gongyou; Liu, Hongmei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research on the construction of portable electrochemical sensors for environmental", "Source Title": "MATERIALS TODAY ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The environment is important for human survival, but because of everyday human activities, many pollutants in the drinking water, food and environment may increasingly contribute to the problem of environmental contamination and pose a significant threat to human health. Therefore, the fast and effective monitoring of environmental compound concentrations in environmental samples is required. Electrochemical sensors offer huge potential for online monitoring of specific pollutants in complex environments, owing to their high sensitivity, good selectivity, low cost, simple operation, and high accuracy. This has made them a hot topic. Furthermore, with development of portable electronic tech-nology, the portable electrochemical sensing system with miniaturization has booming in many fields. Therefore, this paper systematically reviews a variety of portable electrochemical sensors that are used for the analysis of pollutants in the environment, and summarizes the current research direction. This is expected to provide researchers with new research ideas and perspectives.(c) 2022 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 17, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100340, "DOI": "10.1016/j.mtadv.2022.100340", "DOI Link": "http://dx.doi.org/10.1016/j.mtadv.2022.100340", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000916222700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stelling, C; Singh, CR; Karg, M; König, TAF; Thelakkat, M; Retsch, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stelling, Christian; Singh, Chetan R.; Karg, Matthias; Koenig, Tobias A. F.; Thelakkat, Mukundan; Retsch, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plasmonic nullomeshes: their ambivalent role as transparent electrodes in organic solar cells", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this contribution, the optical losses and gains attributed to periodic nullohole array electrodes in polymer solar cells are systematically studied. For this, thin gold nullomeshes with hexagonally ordered holes and periodicities (P) ranging from 202 nm to 2560 nm are prepared by colloidal lithography. In combination with two different active layer materials (P3HT: PC61BM and PTB7: PC71BM), the optical properties are correlated with the power conversion efficiency (PCE) of the solar cells. A cavity mode is identified at the absorption edge of the active layer material. The resonullce wavelength of this cavity mode is hardly defined by the nullomesh periodicity but rather by the absorption of the photoactive layer. This constitutes a fundamental dilemma when using nullomeshes as ITO replacement. The highest plasmonic enhancement requires small periodicities. This is accompanied by an overall low transmittance and high parasitic absorption losses. Consequently, larger periodicities with a less efficient cavity mode, yet lower absorptive losses were found to yield the highest PCE. Nevertheless, ITO-free solar cells reaching similar to 77% PCE compared to ITO reference devices are fabricated. Concomitantly, the benefits and drawbacks of this transparent nullomesh electrode are identified, which is of high relevance for future ITO replacement strategies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 42530, "DOI": "10.1038/srep42530", "DOI Link": "http://dx.doi.org/10.1038/srep42530", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394003700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Liu, L; Zhu, YJ; Wang, LZ; Yu, DG; Liu, LY; Craig, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ying; Liu, Lin; Zhu, Yuanjie; Wang, Liangzhe; Yu, Deng-Guang; Liu, Li-ying; Craig, Duncan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tri-Layer Core-Shell Fibers from Coaxial Electrospinning for a Modified Release of Metronidazole", "Source Title": "PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers are the backbone of drug delivery. Electrospinning has greatly enriched the strategies that have been explored for developing novel drug delivery systems using polymers during the past two decades. In this study, four different kinds of polymers, i.e., the water-soluble polymer poly (vinyl alcohol) (PVA), the insoluble polymer poly(epsilon-caprolactone) (PCL), the insoluble polymer Eudragit RL100 (ERL100) and the pH-sensitive polymer Eudragit S100 (ES100) were successfully converted into types of tri-layer tri-polymer core-shell fibers through bi-fluid coaxial electrospinning. During the coaxial process, the model drug metronidazole (MTD) was loaded into the shell working fluid, which was an emulsion. The micro-formation mechanism of the tri-layer core-shell fibers from the coaxial emulsion electrospinning was proposed. Scanning electron microscope and transmission electron microscope evaluations verified the linear morphology of the resultant fibers and their obvious tri-layer multiple-chamber structures. X-ray diffraction and Fourier transform infrared spectroscopy measurements demonstrated that the drug MTD presented in the fibers in an amorphous state and was compatible with the three polymeric matrices. In vitro dissolution tests verified that the three kinds of polymer could act in a synergistic manner for a prolonged sustained-release profile of MTD in the gut. The drug controlled-release mechanisms were suggested in detail. The protocols reported here pioneer a new route for creating a tri-layer core-shell structure from both aqueous and organic solvents, and a new strategy for developing advanced drug delivery systems with sophisticated drug controlled-release profiles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 15, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2561, "DOI": "10.3390/pharmaceutics15112561", "DOI Link": "http://dx.doi.org/10.3390/pharmaceutics15112561", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001119830200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouassou, JA; Brataas, A; Linder, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouassou, Jabir Ali; Brataas, Arne; Linder, Jacob", "Book Author Full Names": null, "Group Authors": null, "Article Title": "dc Josephson Effect in Altermagnets", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability of magnetic materials to modify superconductors is an active research area for possible applications in thermoelectricity, quantum sensing, and spintronics. We consider the fundamental properties of the Josephson effect in a class of magnetic materials that recently have attracted much attention: altermagnets. We show that despite having no net magnetization and a band structure qualitatively different from ferromagnets and from conventional antiferromagnets without spin-split bands, altermagnets induce 0-& pi; oscillations. The decay length and oscillation period of the Josephson coupling are qualitatively different from ferromagnetic junctions and depend on the crystallographic orientation of the altermagnet. The Josephson effect in altermagnets thus serves a dual purpose: it acts as a signature that distinguishes altermagnetism from ferromagnetism and conventional antiferromagnetism and offers a way to control the supercurrent via flow direction anisotropy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2023, "Volume": 131, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76003, "DOI": "10.1103/PhysRevLett.131.076003", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.076003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053016000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Palermo, A; Krödel, S; Marzani, A; Daraio, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Palermo, Antonio; Kroedel, Sebastian; Marzani, Alessandro; Daraio, Chiara", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineered metabarrier as shield from seismic surface waves", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Resonullt metamaterials have been proposed to reflect or redirect elastic waves at different length scales, ranging from thermal vibrations to seismic excitation. However, for seismic excitation, where energy is mostly carried by surface waves, energy reflection and redirection might lead to harming surrounding regions. Here, we propose a seismic metabarrier able to convert seismic Rayleigh waves into shear bulk waves that propagate away from the soil surface. The metabarrier is realized by burying sub-wavelength resonullt structures under the soil surface. Each resonullt structure consists of a cylindrical mass suspended by elastomeric springs within a concrete case and can be tuned to the resonullce frequency of interest. The design allows controlling seismic waves with wavelengths from 10-to-100 m with meter-sized resonullt structures. We develop an analytical model based on effective medium theory able to capture the mode conversion mechanism. The model is used to guide the design of metabarriers for varying soil conditions and validated using finite-element simulations. We investigate the shielding performance of a metabarrier in a scaled experimental model and demonstrate that surface ground motion can be reduced up to 50% in frequency regions below 10 Hz, relevant for the protection of buildings and civil infrastructures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 39356, "DOI": "10.1038/srep39356", "DOI Link": "http://dx.doi.org/10.1038/srep39356", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389978400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lai, RN; Chen, H; Zhou, ZG; Yi, Z; Tang, B; Chen, J; Yi, YG; Tang, CJ; Zhang, JG; Sun, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lai, Runing; Chen, Hao; Zhou, Zigang; Yi, Zao; Tang, Bin; Chen, Jing; Yi, Yougen; Tang, Chaojun; Zhang, Jianguo; Sun, Tangyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of a Penta-Band Graphene-Based Terahertz Metamaterial Absorber with Fine Sensing Performance", "Source Title": "MICROMACHINES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents a new theoretical proposal for a surface plasmon resonullce (SPR) terahertz metamaterial absorber with five narrow absorption peaks. The overall structure comprises a sandwich stack consisting of a gold bottom layer, a silica medium, and a single-layer patterned graphene array on top. COMSOL simulation represents that the five absorption peaks under TE polarization are at f(I) = 1.99 THz (95.82%), f(II) = 6.00 THz (98.47%), f(III) = 7.37 THz (98.72%), f(IV) = 8.47 THz (99.87%), and f(V) = 9.38 THz (97.20%), respectively, which is almost consistent with the absorption performance under TM polarization. In contrast to noble metal absorbers, its absorption rates and resonullce frequencies can be dynamically regulated by controlling the Fermi level and relaxation time of graphene. In addition, the device can maintain high absorptivity at 0 similar to 50 degrees in TE polarization and 0 similar to 40 degrees in TM polarization. The maximum refractive index sensitivity can reach S-V = 1.75 THz/RIU, and the maximum figure of merit (FOM) can reach FOMV = 12.774 RIU-1. In conclusion, our design has the properties of dynamic tunability, polarization independence, wide-incident-angle absorption, and fine refractive index sensitivity. We believe that the device has potential applications in photodetectors, active optoelectronic devices, sensors, and other related fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 14, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802, "DOI": "10.3390/mi14091802", "DOI Link": "http://dx.doi.org/10.3390/mi14091802", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076588100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Golewski, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Golewski, G. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparative measurements of fracture toughgness combined with visual analysis of cracks propagation using the DIC technique of concretes based on cement matrix with a highly diversified composition", "Source Title": "THEORETICAL AND APPLIED FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents comparative measurements of the fracture toughness together with visual analysis of cracks propagation of concretes made of quaternary binders. A composition of the 2 most commonly used mineral additives, i.e. fly ash (FA) and silica fume (SF) in combination with nullosilica (nS), has been proposed as a partial replacement of the ordinary Portland cement (OPC) binder. The primary objective of the proposed tests was to assess: basic mechanical parameters, i.e. compressive strength - f(cm) and splitting tensile strength - f(ctm), fracture toughnessK(Ic)(S), and fracture processes in quaternary concretes. The modern and precise DIC technique was used, during the studies, in order to realised assumed tasks. It was found that modification of the binder composition with 3 pozzolanic active materials resulted in an increase in the analysed mechanical parameters for each of the combinations compared to the results obtained for the control concrete. Substitution of the binder by 3 additives resulted in a slight heterogeneity of the structure of the quaternary binder concretes. In addition, as content of FA rises throughout each of quaternary concrete series, material becomes more ductile and shows less brittle failure. Therefore composite containing: 80% OPC, 5% FA, 10% SF, and 5% nS - due to its high fracture toughness and lower brittleness - can be used in reinforced concrete structures subjected to dynamic or cyclic loads.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 121, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103553, "DOI": "10.1016/j.tafmec.2022.103553", "DOI Link": "http://dx.doi.org/10.1016/j.tafmec.2022.103553", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000856576400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sohrabi, MJ; Mirzadeh, H; Sadeghpour, S; Mahmudi, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sohrabi, Mohammad Javad; Mirzadeh, Hamed; Sadeghpour, Saeed; Mahmudi, Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain size dependent mechanical behavior and TRIP effect in a metastable austenitic stainless steel", "Source Title": "INTERNATIONAL JOURNAL OF PLASTICITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The change in the trends of mechanical behavior and martensite formation of austenitic steels versus grain size has not yet been explained for the coarse-grained regime. Moreover, the effect of grain size needs systematic investigation by considering a wide range of grain sizes from the ultrafine-grained (UFG) regime to the coarse-grained one. In response, the effect of a wide range of austenite average grain sizes from 0.5 to 192 mu m on the mechanical behavior and transformation-induced plasticity (TRIP) effect in an AISI 304L stainless steel was systematically investigated in the present work. Analysis of the tensile properties revealed that there is a tran-sition grain size range of 34 to 90 mu m, where a meaningful change in the trends of the ultimate tensile strength (UTS), total elongation, tensile toughness, work-hardening capacity, and yield ratio was observed. For instance, the total elongation increased with increasing average grain size up to the transition range but decreased at coarser grain sizes. However, the yield stress followed the Hall-Petch relationship of YS(MPa) = 134.2 + 632.6/root D(mu m) for the whole grain size range, indicating that the presence of the transition grain size range is related to the work-hardening behavior, especially the TRIP effect. The apparent stacking fault energy decreased with increasing the grain size and reached a plateau after the transition grain size range. The same trends were found for the critical strain for the onset of the TRIP effect. Moreover, increasing the grain size up to this transition range promoted the formation of deformation-induced martensite, which was followed by its suppression at coarser grain sizes. The same trends were found for the maximum work-hardening rate related to the TRIP effect. The evolution of mechanical properties and TRIP effect with the grain size up to the transition range was explained based on the dependency of apparent stacking fault energy on the grain size. However, with the constancy of apparent stacking fault energy at coarser grain sizes, the decline in the formation of shear band intersections was found to play a significant role. The latter effect was further supported by Olson-Cohen analysis and investigation of the grain size dependency of the rate of shear-band formation (alpha) and the probability of generation of the martensite embryo at shear-band intersections (beta).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 160, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103502, "DOI": "10.1016/j.ijplas.2022.103502", "DOI Link": "http://dx.doi.org/10.1016/j.ijplas.2022.103502", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000910975300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, FX; Boschloo, G; Wang, F; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Fuxiang; Boschloo, Gerrit; Wang, Feng; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and Progress in Lead-Free Halide Double Perovskite Solar Cells", "Source Title": "SOLAR RRL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead-free halide double perovskites (HDPs) with a chemical formula of A(2)B(+)B(3+)X(6) are booming as attractive alternatives to solve the toxicity issue of lead-based halide perovskites (APbX(3)). HDPs show excellent stability, a wide range of possible combinations, and attractive optoelectronic features. Although a number of novel HDPs have been studied, the power conversion efficiency of the state-of-the-art double perovskite solar cell is still far inferior to that of the dominullt Pb-based ones. Understanding the fundamental challenges is essential for further increasing device efficiency. In this review, HDPs with attractive electronic and optical properties are focused on, and current challenges in material properties and device fabrication that limit high-efficiency photovoltaics are analyzed. Finally, the promising approaches and views to overcome these bottlenecks are highlighted.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 7, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201112, "DOI": "10.1002/solr.202201112", "DOI Link": "http://dx.doi.org/10.1002/solr.202201112", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921408000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, L; Liu, YZ; Fuchter, MJ; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Li; Liu, Yizhou; Fuchter, Matthew J.; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalous circularly polarized light emission in organic light-emitting diodes caused by orbital-momentum locking", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chiral circularly polarized (CP) light is central to many photonic technologies, from the optical communication of spin information to novel display and imaging technologies. As such, there has been significant effort in the development of chiral emissive materials that enable the emission of strongly dissymmetric CP light from organic light-emitting diodes (OLEDs). It has been widely accepted that the molecular chirality of the active layer determines the favoured light handedness of the CP emission in such devices, regardless of the light-emitting direction. Here we discover that, unconventionally, oppositely propagating CP light exhibits opposite handedness, and reversing the current flow in OLEDs also switches the handedness of the emitted CP light. This direction-dependent CP emission boosts the net polarization rate by orders of magnitude by resolving an established issue in CP-OLEDs, where the CP light reflected by the back electrode typically erodes the measured dissymmetry. Through detailed theoretical analysis, we assign this anomalous CP emission to a ubiquitous topological electronic property in chiral materials, namely orbital-momentum locking. Our work paves the way to design new chiroptoelectronic devices and probes the close connections between chiral materials, topological electrons and CP light in the quantum regime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 193, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01113-9", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01113-9", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000894368000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kristensen, PK; Martínez-Pañeda, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kristensen, Philip K.; Martinez-Paneda, Emilio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase field fracture modelling using quasi-Newton methods and a new adaptive step scheme", "Source Title": "THEORETICAL AND APPLIED FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate the potential of quasi-Newton methods in facilitating convergence of monolithic solution schemes for phase field fracture modelling. Several paradigmatic boundary value problems are addressed, spanning the fields of quasi-static fracture, fatigue damage and dynamic cracking. The finite element results obtained reveal the robustness of quasi-Newton monolithic schemes, with convergence readily attained under both stable and unstable cracking conditions. Moreover, since the solution method is unconditionally stable, very significant computational gains are observed relative to the widely used staggered solution schemes. In addition, a new adaptive time increment scheme is presented to further reduce the computational cost while allowing to accurately resolve sudden changes in material behavior, such as unstable crack growth. Computation times can be reduced by several orders of magnitude, with the number of load increments required by the corresponding staggered solution being up to 3000 times higher. Quasi-Newton monolithic solution schemes can be a key enabler for large scale phase field fracture simulations. Implications are particularly relevant for the emerging field of phase field fatigue, as results show that staggered cycle-by-cycle calculations are prohibitive in mid or high cycle fatigue. The finite element codes are available to download from www.empaneda.com/codes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 107, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102446, "DOI": "10.1016/j.tafmec.2019.102446", "DOI Link": "http://dx.doi.org/10.1016/j.tafmec.2019.102446", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528008200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, HW; Zhuang, XY; Chen, PW; Alajlan, N; Rabczuk, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Hongwei; Zhuang, Xiaoying; Chen, Pengwan; Alajlan, Naif; Rabczuk, Timon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stochastic deep collocation method based on neural architecture search and transfer learning for heterogeneous porous media", "Source Title": "ENGINEERING WITH COMPUTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a stochastic deep collocation method (DCM) based on neural architecture search (NAS) and transfer learning for heterogeneous porous media. We first carry out a sensitivity analysis to determine the key hyper-parameters of the network to reduce the search space and subsequently employ hyper-parameter optimization to finally obtain the parameter values. The presented NAS based DCM also saves the weights and biases of the most favorable architectures, which is then used in the fine-tuning process. We also employ transfer learning techniques to drastically reduce the computational cost. The presented DCM is then applied to the stochastic analysis of heterogeneous porous material. Therefore, a three dimensional stochastic flow model is built providing a benchmark to the simulation of groundwater flow in highly heterogeneous aquifers. The performance of the presented NAS based DCM is verified in different dimensions using the method of manufactured solutions. We show that it significantly outperforms finite difference methods in both accuracy and computational cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 38, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 5173, "End Page": 5198, "Article Number": null, "DOI": "10.1007/s00366-021-01586-2", "DOI Link": "http://dx.doi.org/10.1007/s00366-021-01586-2", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000743875800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, MS; Abazari, R; Sanati, S; Chen, J; Sun, MYZ; Bai, CH; Kirillov, AM; Zhou, YT; Hu, GZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Mengshan; Abazari, Reza; Sanati, Soheila; Chen, Jing; Sun, Mingyuzhi; Bai, Cunhong; Kirillov, Alexander M.; Zhou, Yingtang; Hu, Guangzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compositional engineering of HKUST-1/sulfidized NiMn-LDH on functionalized MWCNTs as remarkable bifunctional electrocatalysts for water splitting", "Source Title": "CARBON ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water-splitting reactions such as the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) typically require expensive noble metal-based electrocatalysts. This has motivated researchers to develop novel, cost-effective electrocatalytic systems. In this study, a new multicomponent nullocomposite was assembled by combining functionalized multiwalled carbon nullotubes, a Cu-based metal-organic framework (MOF) (HKUST-1 or HK), and a sulfidized NiMn-layered double hydroxide (NiMn-S). The resulting nullocomposite, abbreviated as MW/HK/NiMn-S, features a unique architecture, high porosity, numerous electroactive Cu/Ni/Mn sites, fast charge transfer, excellent structural stability, and conductivity. At a current density of 10 mA cm-2, this dual-function electrocatalyst shows remarkable performance, with ultralow overpotential values of 163 mV (OER) or 73 mV (HER), as well as low Tafel slopes (57 and 75 mV dec-1, respectively). Additionally, its high turnover frequency values (4.43 s-1 for OER; 3.96 s-1 for HER) are significantly superior to those of standard noble metal-based Pt/C and IrO2 systems. The synergistic effect of the nullocomposite's different components is responsible for its enhanced electrocatalytic performance. A density functional theory study revealed that the multi-interface and multicomponent heterostructure contribute to increased electrical conductivity and decreased energy barrier, resulting in superior electrocatalytic HER/OER activity. This study presents a novel vision for designing advanced electrocatalysts with superior performance in water splitting. Various composites have been utilized in water-splitting applications. This study investigates the use of the MW/HK/NiMn-S electrocatalyst for water splitting for the first time to indicate the synergistic effect between carbon-based materials along with layered double hydroxide compounds and porous compounds of MOF. The unique features of each component in this composite can be an interesting topic in the field of water splitting. A new multiwalled carbon nullotubes/Cu-metal-organic framework/sulfidized-NiMn-layered double hydroxide (MW/HK/NiMn-S) nullocomposite was assembled, characterized, and applied as an exceptionally powerful dual-function electrocatalyst for the H2 and O2 evolution processes. The developed multi-interface engineering approach provides new perspectives for designing future dual-function electrocatalysts based on tri- or multimetallic composites with ideal conductivity, stability, and advanced water-splitting performance.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 68, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 5, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/cey2.459", "DOI Link": "http://dx.doi.org/10.1002/cey2.459", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001128755600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, J; Lin, ST; Liu, XY; Qin, Z; Yang, YY; Zang, JF; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Ji; Lin, Shaoting; Liu, Xinyue; Qin, Zhao; Yang, Yueying; Zang, Jianfeng; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fatigue-resistant adhesion of hydrogels", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The adhesion of soft connective tissues (tendons, ligaments, and cartilages) on bones in many animals can maintain high toughness (similar to 800 J m(-2)) over millions of cycles of mechanical loads. Such fatigue-resistant adhesion has not been achieved between synthetic hydrogels and engineering materials, but is highly desirable for diverse applications such as artificial cartilages and tendons, robust antifouling coatings, and hydrogel robots. Inspired by the nullostructured interfaces between tendons/ligaments/cartilages and bones, we report that bonding ordered nullocrystalline domains of synthetic hydrogels on engineering materials can give a fatigue-resistant adhesion with an interfacial fatigue threshold of 800 J m(-2), because the fatigue-crack propagation at the interface requires a higher energy to fracture the ordered nullostructures than amorphous polymer chains. Our method enables fatigue-resistant hydrogel coatings on diverse engineering materials with complex geometries. We further demonstrate that the fatigue-resistant hydrogel coatings exhibit low friction and low wear against natural cartilages.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 278, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1071, "DOI": "10.1038/s41467-020-14871-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14871-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564293100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahn, J; Xu, ZJ; Bang, J; Deng, YH; Hoang, TM; Han, QK; Ma, RM; Li, TC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahn, Jonghoon; Xu, Zhujing; Bang, Jaehoon; Deng, Yu-Hao; Hoang, Thai M.; Han, Qinkai; Ma, Ren-Min; Li, Tongcang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optically Levitated nullodumbbell Torsion Balance and GHz nullomechanical Rotor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Levitated optomechanics has great potential in precision measurements, thermodynamics, macroscopic quantum mechanics, and quantum sensing. Here we synthesize and optically levitate silica nullodumbbells in high vacuum. With a linearly polarized laser, we observe the torsional vibration of an optically levitated nullodumbbell. This levitated nullodumbbell torsion balance is a novel analog of the Cavendish torsion balance, and provides rare opportunities to observe the Casimir torque and probe the quantum nature of gravity as proposed recently. With a circularly polarized laser, we drive a 170-nm-diameter nullodumbbell to rotate beyond 1 GHz, which is the fastest nullomechanical rotor realized to date. Smaller silica nullodumbbells can sustain higher rotation frequencies. Such ultrafast rotation may be used to study material properties and probe vacuum friction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2018, "Volume": 121, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 33603, "DOI": "10.1103/PhysRevLett.121.033603", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.033603", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439308700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Le, BA; Yvonnet, J; He, QC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Le, B. A.; Yvonnet, J.; He, Q. -C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computational homogenization of nonlinear elastic materials using neural networks", "Source Title": "INTERNATIONAL JOURNAL FOR NUMERICAL METHODS IN ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a decoupled computational homogenization method for nonlinear elastic materials is proposed using neural networks. In this method, the effective potential is represented as a response surface parameterized by the macroscopic strains and some microstructural parameters. The discrete values of the effective potential are computed by finite element method through random sampling in the parameter space, and neural networks are used to approximate the surface response and to derive the macroscopic stress and tangent tensor components. We show through several numerical convergence analyses that smooth functions can be efficiently evaluated in parameter spaces with dimension up to 10, allowing to consider three-dimensional representative volume elements and an explicit dependence of the effective behavior on microstructural parameters like volume fraction. We present several applications of this technique to the homogenization of nonlinear elastic composites, involving a two-scale example of heterogeneous structure with graded nonlinear properties. Copyright (c) 2015John Wiley & Sons, Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2015, "Volume": 104, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1061, "End Page": 1084, "Article Number": null, "DOI": "10.1002/nme.4953", "DOI Link": "http://dx.doi.org/10.1002/nme.4953", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365530900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XY; Jiang, WL; Zhou, JF; Yu, DG; Liu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xinyi; Jiang, Wenlai; Zhou, Jianfeng; Yu, Deng-Guang; Liu, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Applications of Ferulic-Acid-Loaded Fibrous Films for Fruit Preservation", "Source Title": "POLYMERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this study was to develop a novel ultrathin fibrous membrane with a core-sheath structure as an antioxidant food packaging membrane. The core-sheath structure was prepared by coaxial electrospinning, and the release of active substances was regulated by its special structure. Ferulic acid (FA) was incorporated into the electrospun zein/polyethylene oxide ultrathin fibers to ensure their synergistic antioxidant properties. We found that the prepared ultrathin fibers had a good morphology and smooth surface. The internal structure of the fibers was stable, and the three materials that we used were compatible. For the different loading positions, it was observed that the core layer ferulic-acid-loaded fibers had a sustained action, while the sheath layer ferulic-acid-loaded fibers had a pre-burst action. Finally, apples were selected for packaging using fibrous membranes to simulate practical applications. The fibrous membrane was effective in reducing water loss and apple quality loss, as well as extending the shelf life. According to these experiments, the FA-loaded zein/PEO coaxial electrospinning fiber can be used as antioxidant food packaging and will also undergo more improvements in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 14, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4947, "DOI": "10.3390/polym14224947", "DOI Link": "http://dx.doi.org/10.3390/polym14224947", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000887508200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, JJ; Shojaei, S; Shojaei, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jingjie; Shojaei, Siroos; Shojaei, Saeed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Removal of drug and dye from aqueous solutions by graphene oxide: Adsorption studies and chemometrics methods", "Source Title": "NPJ CLEAN WATER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Pharmaceutical products and dyes are the main environmental pollutants in the effluent of textile, cosmetic, and pharmaceutical industries. Therefore, in this study, the central composite design (CCD) based on the response surface methodology (RSM) was used to investigate the operating parameters and determine the optimal conditions for the removal of enrofloxacin (ENF) and Rhodamine B (RhB) by graphene oxide (GO). The structure and morphology of GO were studied using scanning electron microscopes (SEM) and X-ray diffraction (XRD) techniques. Quadratic model was confirmed to describe each of the removal efficiency responses (%R) a with high correlation coefficient (R-2 = 0.9987 for ENF and R-2 = 0.9999 for RhB) (R-2-Adj = 0.9963 for ENF and R-2-Adj = 0.9991 for RhB). In optimal conditions, RhB concentration of 10 mg L-1, adsorbent amount of 0.24 g, sonication time of 23 min, ENF concentration of 10 mg L-1, and pH 7, removal rates of more than 92.5% were obtained for both analytes. Adsorption equilibrium was studied with Langmuir, Freundlich, Langmuir-Freundlich, Redlich-Peterson, Toth and Khan isotherm models. Equilibrium data were best fitted with the Langmuir-Freundlich isotherm model. Maximum adsorption capacity of ENF and RhB on GO were 45.035 mg g(-1) and 107.230 mg g(-1), respectively. The recyclability of GO was evaluated during the ENF and RhB adsorption process. The results showed that up to 4 cycles of adsorbent, the adsorption efficiency is reduced by a tiny amount. The present study showed that GO is highly effective in removing ENF and RhB from environmental water samples.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2022, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5, "DOI": "10.1038/s41545-022-00148-3", "DOI Link": "http://dx.doi.org/10.1038/s41545-022-00148-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763387500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, SYF; Cui, XM; Volkov, PA; Yoo, H; Lee, SM; Gardener, JA; Akey, AJ; Engelke, R; Ronen, Y; Zhong, RD; Gu, GD; Plugge, S; Tummuru, T; Kim, M; Franz, M; Pixley, JH; Poccia, N; Kim, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, S. Y. Frank; Cui, Xiaomeng; Volkov, Pavel A.; Yoo, Hyobin; Lee, Sangmin; Gardener, Jules A.; Akey, Austin J.; Engelke, Rebecca; Ronen, Yuval; Zhong, Ruidan; Gu, Genda; Plugge, Stephan; Tummuru, Tarun; Kim, Miyoung; Franz, Marcel; Pixley, Jedediah H.; Poccia, Nicola; Kim, Philip", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-reversal symmetry breaking superconductivity between twisted cuprate superconductors", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Twisted interfaces between stacked van der Waals (vdW) cuprate crystals present a platform for engineering superconducting order parameters by adjusting stacking angles. Using a cryogenic assembly technique, we construct twisted vdW Josephson junctions (JJs) at atomically sharp interfaces between Bi2Sr2CaCu2O8+x crystals, with quality approaching the limit set by intrinsic JJs. Near 45 degrees twist angle, we observe fractional Shapiro steps and Fraunhofer patterns, consistent with the existence of two degenerate Josephson ground states related by time-reversal symmetry (TRS). By programming the JJ current bias sequence, we controllably break TRS to place the JJ into either of the two ground states, realizing reversible Josephson diodes without external magnetic fields. Our results open a path to engineering topological devices at higher temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2023, "Volume": 382, "Issue": 6677, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1422, "End Page": 1427, "Article Number": null, "DOI": "10.1126/science.abl8371", "DOI Link": "http://dx.doi.org/10.1126/science.abl8371", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001128567800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grisafi, A; Wilkins, DM; Csányi, G; Ceriotti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grisafi, Andrea; Wilkins, David M.; Csanyi, Gabor; Ceriotti, Michele", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symmetry-Adapted Machine Learning for Tensorial Properties of Atomistic Systems", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Statistical learning methods show great promise in providing an accurate prediction of materials and molecular properties, while minimizing the need for computationally demanding electronic structure calculations. The accuracy and transferability of these models are increased significantly by encoding into the learning procedure the fundamental symmetries of rotational and permutational invariance of scalar properties. However, the prediction of tensorial properties requires that the model respects the appropriate geometric transformations, rather than invariance, when the reference frame is rotated. We introduce a formalism that extends existing schemes and makes it possible to perform machine learning of tensorial properties of arbitrary rank, and for general molecular geometries. To demonstrate it, we derive a tensor kernel adapted to rotational symmetry, which is the natural generalization of the smooth overlap of atomic positions kernel commonly used for the prediction of scalar properties at the atomic scale. The performance and generality of the approach is demonstrated by learning the instantaneous response to an external electric field of water oligomers of increasing complexity, from the isolated molecule to the condensed phase.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2018, "Volume": 120, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36002, "DOI": "10.1103/PhysRevLett.120.036002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.036002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423317300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rahmatabadi, D; Soltanmohammadi, K; Pahlavani, M; Aberoumand, M; Soleyman, E; Ghasemi, I; Baniassadi, M; Abrinia, K; Bodaghi, M; Baghani, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rahmatabadi, Davood; Soltanmohammadi, Kianoosh; Pahlavani, Mostafa; Aberoumand, Mohammad; Soleyman, Elyas; Ghasemi, Ismaeil; Baniassadi, Majid; Abrinia, Karen; Bodaghi, Mahdi; Baghani, Mostafa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shape memory performance assessment of FDM 3D printed PLA-TPU composites by Box-Behnken response surface methodology", "Source Title": "INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, for the first time, the role of manufacturing parameters of fused deposition modeling (FDM) on the shape memory effect (SME) is investigated by design of experiments. PLA-TPU blend with a weight composition of 30:70% is processed by melt mixing and then extruded into 1.75 mm filaments for 3D printing via FDM. SEM images reveal that TPU droplets are distributed in the PLA matrix, and the immiscible matrix-droplet morphology is evident. Box-Behnken design (BBD), as an experimental design of the response surface method (RSM), is implemented to fit the model between variables and responses. The shell, infill density, and nozzle temperature are selected as variables, and their effects on loading stress, recovery stress, shape fixity, and shape recovery ratio are studied in detail. An analysis of variance (ANOVA) is applied to estimate the importance of each printing parameter on the output response and assess the fitness of the presented model. The ANOVA results reveal the high accuracy of the model and the importance of the parameters. Infill density and nozzle temperature had the greatest and least roles on shape memory properties, respectively. Also, the values of shape fixity and shape recovery were obtained in the ranges of 58-100% and 53-91%, respectively. Despite many researches on 4D printing of PLA, low ductility at room temperature and high stress relaxation rate are its weakness, which are covered by adding TPU in this research. Due to the lack of similar outcomes in the specialized literature, this paper is likely to fill the gap in the state-of-the-art problem and supply pertinent data that are instrumental for FDM 3D printing of functional shape memory polymers with less material consumption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 127, "Issue": "1-2", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 935, "End Page": 950, "Article Number": null, "DOI": "10.1007/s00170-023-11571-2", "DOI Link": "http://dx.doi.org/10.1007/s00170-023-11571-2", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Automation & Control Systems; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992390500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, ZY; Jing, XL; Li, KF; Wu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Z. H. I. Y. O. N. G.; Jing, X. I. L. I.; LI, K. A. I. F. E. N. G.; Wu, B. I. A. O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental study of an intensity-modulated curvature sensor with high sensitivity based on microstructured optical fiber", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface Plasmon Resonullce (SPR) based fiber optic curvature sensors have the advantage of being insensitive to temperature and axial strain. However, they have the disadvantage of low sensitivity and small curvature detection range. To improve the performance of SPR curvature sensors, we propose an intensity-modulated microstructured optical fiber (MOF) curvature sensor. In this sensor, two no-core fibers (NCFs) are used as input-output couplers, and MOF with silver film deposited is used as sensing arms. The light in the cladding is used to excite the SPR, and the exciting resonullt valley is extremely sensitive to slight bending changes. The performance of this sensor is investigated theoretically and experimentally. Numerical results show that its cladding pattern is more favorable in the excitation of SPR effects. Experimental results show that the cladding mode of MOF is very sensitive to curvature changes, thus giving it a great advantage in bending measurements. Its sensitivity reaches 0.18 dB/m-1, and linearity reaches 0.995 in the curvature range of 0-30 m-1. The sensor has the advantages of high sensitivity, low temperature and axial strain crosstalk, compact structure, and easy fabrication, which make it attractive in the field of bending sensing.(c) 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 47, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2023, "Volume": 31, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4770, "End Page": 4782, "Article Number": null, "DOI": "10.1364/OE.479812", "DOI Link": "http://dx.doi.org/10.1364/OE.479812", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938751700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, J; Telychko, M; Hu, P; Macam, G; Mutombo, P; Zhang, HJ; Bao, Y; Cheng, F; Huang, ZQ; Qiu, ZZ; Tan, SJR; Lin, H; Jelínek, P; Chuang, FC; Wu, JS; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Jie; Telychko, Mykola; Hu, Pan; Macam, Gennevieve; Mutombo, Pingo; Zhang, Hejian; Bao, Yang; Cheng, Fang; Huang, Zhi-Quan; Qiu, Zhizhan; Tan, Sherman J. R.; Lin, Hsin; Jelinek, Pavel; Chuang, Feng-Chuan; Wu, Jishan; Lu, Jiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically precise bottom-up synthesis of π-extended [5]triangulene", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The zigzag-edged triangular graphene molecules (ZTGMs) have been predicted to host ferromagnetically coupled edge states with the net spin scaling with the molecular size, which affords large spin tunability crucial for next-generation molecular spintronics. However, the scalable synthesis of large ZTGMs and the direct observation of their edge states have been long-standing challenges because of the molecules' high chemical instability. Here, we report the bottom-up synthesis of pi-extended [5]triangulene with atomic precision via surface-assisted cyclodehydrogenation of a rationally designed molecular precursor on metallic surfaces. Atomic force microscopy measurements unambiguously resolve its ZTGM-like skeleton consisting of 15 fused benzene rings, while scanning tunneling spectroscopy measurements reveal edge-localized electronic states. Bolstered by density functional theory calculations, our results show that [5]triangulenes synthesized on Au(111) retain the open-shell pi-conjugated character with magnetic ground states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav7717", "DOI": "10.1126/sciadv.aav7717", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav7717", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478770400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QT; Luo, YQ; Yang, SK; Xiong, YY; Wang, RX; Fu, XD; Zhang, R; Hu, SF; Bao, XJ; Xu, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qingting; Luo, Yuqing; Yang, Shoukun; Xiong, Yuyue; Wang, Rongxin; Fu, Xudong; Zhang, Rong; Hu, Shengfei; Bao, Xujin; Xu, Chenxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transfer-free in-situ synthesis of high-performance polybenzimidazole grafted graphene oxide-based proton exchange membrane for high-temperature proton exchange membrane fuel cells", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The preparation of traditional graphene oxide (GO)-based proton exchange membrane (PEM) composites asks for multiple transfer steps due to the different solvent requirements of GO preparation and polymer synthesis. Moreover, GO is easy to agglomerate in polymer matrix, it is difficult to give full play to the excellent proton conductivity of single/few-layered nullosheets. Herein, a novel transfer-free in-situ method is developed to prepare poly(2,5-benzimidazole) (ABPBI)-grafted electrolytic graphene oxide (EGO) composites (ABPBI-EGO) for high-temperature (HT) PEM fuel cells applications. The process involves the in-situ electrochemical oxidation and exfoliation of graphite foil into single/few-layered EGO in Eaton's reagent and followed by in-situ synthesis of ABPBI-grafted-EGO composites in the same reagent. This strategy leads to a single or few-layered dispersion of EGO nullosheets in ABPBI matrix, thus significantly improving the physicochemical performance. By con-structing fast proton-conducting channels through single/few-layered GO nullosheets, composite membranes without free phosphoric acid exhibit superior proton conductivities over the whole temperature range of 120-180 degrees C. ABPBI-0.5EGO composite membrane-based fuel cell achieves a power density of 349 mW/cm2 at 180 degrees C, which is nearly 2.3 times higher than the original ABPBI membrane. Thus, this transfer-free in-situ strategy shows great promise for developing high-performance HT-PEMs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 559, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 232666, "DOI": "10.1016/j.jpowsour.2023.232666", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2023.232666", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000976855600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grinenko, V; Ghosh, S; Sarkar, R; Orain, JC; Nikitin, A; Elender, M; Das, D; Guguchia, Z; Brückner, F; Barber, ME; Park, J; Kikugawa, N; Sokolov, DA; Bobowski, JS; Miyoshi, T; Maeno, Y; Mackenzie, AP; Luetkens, H; Hicks, CW; Klauss, HH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grinenko, Vadim; Ghosh, Shreenullda; Sarkar, Rajib; Orain, Jean-Christophe; Nikitin, Artem; Elender, Matthias; Das, Debarchan; Guguchia, Zurab; Brueckner, Felix; Barber, Mark E.; Park, Joonbum; Kikugawa, Naoki; Sokolov, Dmitry A.; Bobowski, Jake S.; Miyoshi, Takuto; Maeno, Yoshiteru; Mackenzie, Andrew P.; Luetkens, Hubertus; Hicks, Clifford W.; Klauss, Hans-Henning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Split superconducting and time-reversal symmetry-breaking transitions in Sr2RuO4 under stress", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When strain is applied to strontium ruthenate, superconductivity emerges at a different temperature to the breaking of time-reversal symmetry. This indicates that the superconductivity could have a chiral d-wave order parameter. Strontium ruthenate (Sr2RuO4) continues to present an important test of our understanding of unconventional superconductivity, because while its normal-state electronic structure is known with precision, its superconductivity remains unexplained. There is evidence that its order parameter is chiral, but reconciling this with recent observations of the spin part of the pairing requires an order parameter that is either finely tuned or implies a new form of pairing. Therefore, a definitive resolution of whether the superconductivity of Sr2RuO4 is chiral is important for the study of superconductivity. Here we report the measurement of zero-field muon spin relaxation-a probe sensitive to weak magnetism-on samples under uniaxial stresses. We observe stress-induced splitting between the onset temperatures of superconductivity and time-reversal symmetry breaking-consistent with the qualitative expectations for a chiral order parameter-and argue that this observation cannot be explained by conventional magnetism. In addition, we report the appearance of bulk magnetic order under higher uniaxial stress, above the critical pressure at which a Lifshitz transition occurs in Sr2RuO4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 17, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 748, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-021-01182-7", "DOI Link": "http://dx.doi.org/10.1038/s41567-021-01182-7", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625818000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahdavi, K; Zinatloo-Ajabshir, S; Yousif, QA; Salavati-Niasari, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahdavi, Kamran; Zinatloo-Ajabshir, Sahar; Yousif, Qahtan A.; Salavati-Niasari, Masoud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic degradation of toxic contaminullts using Dy2O3-SiO2 ceramic nullostructured materials fabricated by a new, simple and rapid sonochemical approach", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present study is on the fabrication of new photocatalytic nullocomposites (Dy2O3-SiO2) employing a basic agent, tetraethylenepentamine (Tetrene), through a simple, efficient and, quick sonochemical approach. The features of the fabricated photocatalytic nullocomposite were examined employing a variety of microscopic and spectroscopic methods such as XRD, EDS, TEM, FTIR, DRS, and FESEM. The outcomes of morphological studies demonstrated that by proper tuning of sonication time and ultrasonic power (10 min and 400 W), a porous nullocomposite composed of sphere-shaped nulloparticles with a particle size in the range of 20 to 60 nm could be fabricated. The energy gap for the binary Dy2O3-SiO2 nullophotocatalyst was determined to be 3.41 eV, making these nullocomposite favorable for removing contaminullts. The photocatalytic performance of the optimal nullocomposite sample was tested for photodecomposition of several contaminullts including erythrosine, thymol blue, eriochrome black T, Acid Red 14, methyl orange, malachite green, and Rhodamine B. The binary Dy2O3-SiO2 nullophotocatalyst exhibited superior efficiency toward the decomposition of the studied contaminullts. It was able to degrade the erythrosine pollutant more effectively (92.9%). Optimization studies for the photocatalytic decomposition of each contaminullt demonstrated that the best performance could be achieved at a specific amount of contaminullt and nullocatalyst. Trapping experiments illustrated that hydroxyl radicals were more effectively involved in the decomposition of contaminullt molecules by Dy2O3-SiO(2 )nullophotocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 82, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105892, "DOI": "10.1016/j.ultsonch.2021.105892", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2021.105892", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788123900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anulldalakshmi, K; Venugobal, J; Ramasamy, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anulldalakshmi, K.; Venugobal, J.; Ramasamy, V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of silver nulloparticles by green synthesis method using Pedalium murex leaf extract and their antibacterial activity", "Source Title": "APPLIED nullOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, an aqueous extract of fresh leaves of Pedalium murex was used for the synthesis of silver (Ag) nulloparticles. Different biological methods are gaining recognition for the production of silver nulloparticles (AgNPs) due to their multiple applications. The use of plants in the green synthesis of nulloparticles emerges as a cost-effective and eco-friendly approach. Characterization of nulloparticles was done using different methods, which include; ultraviolet-visible spectroscopy (UV-Vis), Fourier transform infrared (FTIR), powder X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), energy dispersive X-ray analysis (EDAX), fluorescence emission spectroscopy, transmission electron microscope (TEM), dynamic light scattering (DLS), zeta potential and antibacterial activity. UV-visible spectrum of the aqueous medium containing silver nulloparticles showed absorption peak at around 430 nm. Fourier transform infrared spectra had shown that the biomolecule compounds were responsible for the reduction and capping material of silver nulloparticles. XRD study showed the particles to be crystalline in nature, with a face-centered cubic (fcc) structure. The size and stability were detected using DLS and zeta potential analysis. The antibacterial activity of AgNPs against generally found bacteria was assessed to find their potential use in silver-containing antibacterial product.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 729, "Times Cited, All Databases": 753, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 399, "End Page": 408, "Article Number": null, "DOI": "10.1007/s13204-015-0449-z", "DOI Link": "http://dx.doi.org/10.1007/s13204-015-0449-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371159300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Papadimitratos, A; Sobhansarbandi, S; Pozdin, V; Zakhidov, A; Hassanipour, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Papadimitratos, Alexios; Sobhansarbandi, Sarvenaz; Pozdin, Vladimir; Zakhidov, Anvar; Hassanipour, Fatemeh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evacuated tube solar collectors integrated with phase change materials", "Source Title": "SOLAR ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents a novel method of integrating phase change materials (PCMs) within the evacuated solar tube collectors for solar water heaters (SWHs). In this method, the heat pipe is immersed inside the phase change material, where heat is effectively accumulated and stored for an extended period of time due to thermal insulation of evacuated tubes. The benefit of this method includes improved functionality by delayed release of heat, thus providing hot water during the hours of high demand or when solar intensity is insufficient. The proposed solar collector utilizes two distinct phase change materials (dual-PCM), namely Tritriacontane and Erythritol, with melting temperatures of 72 degrees C and 118 degrees C respectively. The operation of solar water heater with the proposed solar collector is investigated during both normal and on-demand operation. The feasibility of this technology is also tested via large scale commercial solar water heaters. Beyond the improved functionality for solar water heater systems, the results from this study show efficiency improvement of 26% for the normal operation and 66% for the stagnation mode, compared with standard solar water heaters that lack phase change materials. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 129, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10, "End Page": 19, "Article Number": null, "DOI": "10.1016/j.solener.2015.12.040", "DOI Link": "http://dx.doi.org/10.1016/j.solener.2015.12.040", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373866800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, D; Mandal, A; Baxter, JM; Cheng, SW; Lee, IK; Su, HW; Liu, S; Reichman, DR; Delor, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ding; Mandal, Arkajit; Baxter, James M.; Cheng, Shan-Wen; Lee, Inki; Su, Haowen; Liu, Song; Reichman, David R.; Delor, Milan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast imaging of polariton propagation and interactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Semiconductor excitations can hybridize with cavity photons to form exciton-polaritons (EPs) with remarkable properties, including light-like energy flow combined with matter-like interactions. To fully harness these properties, EPs must retain ballistic, coherent transport despite matter-mediated interactions with lattice phonons. Here we develop a nonlinear momentum-resolved optical approach that directly images EPs in real space on femtosecond scales in a range of polaritonic architectures. We focus our analysis on EP propagation in layered halide perovskite microcavities. We reveal that EP-phonon interactions lead to a large renormalization of EP velocities at high excitonic fractions at room temperature. Despite these strong EP-phonon interactions, ballistic transport is maintained for up to half-exciton EPs, in agreement with quantum simulations of dynamic disorder shielding through light-matter hybridization. Above 50% excitonic character, rapid decoherence leads to diffusive transport. Our work provides a general framework to precisely balance EP coherence, velocity, and nonlinear interactions. Exciton-polaritons are part-light part-matter states in semiconductors. Here the authors leverage momentum-resolved optical microscopy to image ballistic and diffusive propagation of exciton-polaritons on femtosecond scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3881, "DOI": "10.1038/s41467-023-39550-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39550-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022893500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arnal, G; Anglade, J; Gavalda, S; Tournier, V; Chabot, N; Bornscheuer, UT; Weber, G; Marty, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arnal, Gregory; Anglade, Julien; Gavalda, Sabine; Tournier, Vincent; Chabot, Nicolas; Bornscheuer, Uwe T.; Weber, Gert; Marty, Alain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assessment of Four Engineered PET Degrading Enzymes Considering Large-Scale Industrial Applications", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, enzymatic recycling of the widely used polyester polyethylene terephthalate (PET) has become a complementary solution to current thermomechanical recycling for colored, opaque, and mixed PET. A large set of promising hydrolases that depolymerize PET have been found and enhanced by worldwide initiatives using various methods of protein engineering. Despite the achievements made in these works, it remains difficult to compare enzymes' performance and their applicability to large-scale reactions due to a lack of homogeneity between the experimental protocols used. Here, we pave the way for a standardized enzymatic PET hydrolysis protocol using reaction conditions relevant for larger scale hydrolysis and apply these parameters to four recently reported PET hydrolases (LCCICCG, FAST-PETase, HotPETase, and PES-H1(L92F/Q94Y)). We show that FAST-PETase and HotPETase have intrinsic limitations that may not permit their application on larger reaction scales, mainly due to their relatively low depolymerization rates. With 80% PET depolymerization, PES-H1(L92F/Q94Y) may be a suitable candidate for industrial reaction scales upon further rounds of enzyme evolution. LCCICCG outperforms the other enzymes, converting 98% of PET into the monomeric products terephthalic acid (TPA) and ethylene glycol (EG) in 24 h. In addition, we optimized the reaction conditions of LCCICCG toward economic viability, reducing the required amount of enzyme by a factor of 3 and the temperature of the reaction from 72 to 68 C-degrees. We anticipate our findings to advance enzymatic PET hydrolysis toward a coherent assessment of the enzymes and materialize feasibility at larger reaction scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2023, "Volume": 13, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13156, "End Page": 13166, "Article Number": null, "DOI": "10.1021/acscatal.3c02922", "DOI Link": "http://dx.doi.org/10.1021/acscatal.3c02922", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001072674500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, W; Si, TY; Li, XX; Li, XY; Lu, L; Ma, T; Wang, QW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Wei; Si, Tianyu; Li, Xiangxuan; Li, Xinyi; Lu, Lin; Ma, Ting; Wang, Qiuwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heat transfer analysis of phase change material composited with metal foam-fin hybrid structure in inclination container by numerical simulation and artificial neural network", "Source Title": "ENERGY REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the heat transfer performance of phase change material (PCM) plays a crucial role in designing efficient latent heat thermal energy storage (LHTES) systems. The purpose of this study is to address and elucidate the effects of the metal foam-fin hybrid structure and the inclination angle on the phase change process by using the numerical simulation method. An experimental system for the validation of the numerical models is established. The solid-liquid phase interfaces, streamlines, liquid fraction (f), the dimensionless time (Fo x Ste), and average Nusselt number ((Nu) over bar) of PCM in the container enclosure at inclination angles of 0 degrees, 30 degrees, 60 degrees, and 90 degrees with six kinds of enhanced heat transfer structures, including fin, metal foam, and metal foam-fin hybrid structures, are compared. Besides, the liquid fraction and (Nu) over bar during the phase change process are predicted by the artificial neural network (ANN). Results demonstrate that the optimized heat transfer performance of the metal foam-fin hybrid structure could reduce the melting time. In addition, the increase in the number of fins can improve the heat transfer performance and reduce heat accumulation in the top area with the inclination angle increasing. Compared to pure PCM at the inclination angle of 90 degrees, the values of Fo x Ste of metal foam-1 fin and metal foam-5 fins hybrid structures are reduced by 52.69% and 60.02%, respectively. However, the energy storage density per unit volume decreases as a function of the increasing inclination angles and the number of fins within a case. Furthermore, the excellent predictions of f and (Nu) over bar are obtained by ANN with MSE and R-2 of 9.6480 x 10(-5), 0.9990 and 0.0150, 0.9937, respectively. (C) 2022 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10203, "End Page": 10218, "Article Number": null, "DOI": "10.1016/j.egyr.2022.07.178", "DOI Link": "http://dx.doi.org/10.1016/j.egyr.2022.07.178", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000876766400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tschirhart, CL; Serlin, M; Polshyn, H; Shragai, A; Xia, Z; Zhu, J; Zhang, Y; Watanabe, K; Taniguchi, T; Huber, ME; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tschirhart, C. L.; Serlin, M.; Polshyn, H.; Shragai, A.; Xia, Z.; Zhu, J.; Zhang, Y.; Watanabe, K.; Taniguchi, T.; Huber, M. E.; Young, A. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Imaging orbital ferromagnetism in a moire Chern insulator", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrons in moire flat band systems can spontaneously break time-reversal symmetry, giving rise to a quantized anomalous Hall effect. In this study, we use a superconducting quantum interference device to image stray magnetic fields in twisted bilayer graphene aligned to hexagonal boron nitride. We find a magnetization of several Bohr magnetons per charge carrier, demonstrating that the magnetism is primarily orbital in nature. Our measurements reveal a large change in the magnetization as the chemical potential is swept across the quantum anomalous Hall gap, consistent with the expected contribution of chiral edge states to the magnetization of an orbital Chern insulator. Mapping the spatial evolution of field-driven magnetic reversal, we find a series of reproducible micrometer-scale domains pinned to structural disorder.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2021, "Volume": 372, "Issue": 6548, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1323, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd3190", "DOI Link": "http://dx.doi.org/10.1126/science.abd3190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665616000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Zhang, H; Huang, MH; Yin, HB; Jiang, K; Xiao, KT; Tang, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yang; Zhang, Hui; Huang, Minghui; Yin, Haibo; Jiang, Ke; Xiao, Kaitao; Tang, Shengwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of Different Alkali Sulfates on the Shrinkage, Hydration, Pore Structure, Fractal Dimension and Microstructure of Low-Heat Portland Cement, Medium-Heat Portland Cement and Ordinary Portland Cement", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In cement-based materials, alkalis mainly exist in the form of different alkali sulfates. In this study, the impacts of different alkali sulfates on the shrinkage, hydration, pore structure, fractal dimension and microstructure of low-heat Portland cement (LHPC), medium-heat Portland cement (MHPC) and ordinary Portland cement (OPC) are investigated. The results indicate that alkali sulfates magnify the autogenous shrinkage and drying shrinkage of cement-based materials with different mineral compositions, which are mainly related to different pore structures and hydration processes. LHPC has the lowest shrinkage. Otherwise, the effect of alkali sulfates on the autogenous shrinkage is more profound than that of drying shrinkage. Compared with the pore size distribution, the fractal dimension can better characterize the shrinkage properties of cement-based materials. It is noted that the contribution of K2SO4 (K alkali) to the promotion effect of shrinkage on cement-based materials is more significant than that of Na2SO4 (Na alkali), which cannot be ignored. The microstructure investigation of different cement-based materials by means of nuclear magnetic resonullce (NMR), mercury intrusion porosimetry (MIP) and scanning electron microscope (SEM) shows that this effect may be related to the different pore structures, crystal forms and morphologies of hydration products of cement-based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 79, "DOI": "10.3390/fractalfract5030079", "DOI Link": "http://dx.doi.org/10.3390/fractalfract5030079", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000700662300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bayliss, SL; Laorenza, DW; Mintun, PJ; Kovos, BD; Freedman, DE; Awschalom, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bayliss, S. L.; Laorenza, D. W.; Mintun, P. J.; Kovos, B. D.; Freedman, D. E.; Awschalom, D. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optically addressable molecular spins for quantum information processing", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-bearing molecules are promising building blocks for quantum technologies as they can be chemically tuned, assembled into scalable arrays, and readily incorporated into diverse device architectures. In molecular systems, optically addressing ground-state spins would enable a wide range of applications in quantum information science, as has been demonstrated for solid-state defects. However, this important functionality has remained elusive for molecules. Here, we demonstrate such optical addressability in a series of synthesized organometallic, chromium(IV) molecules. These compounds display a ground-state spin that can be initialized and read out using light and coherently manipulated with microwaves. In addition, through atomistic modification of the molecular structure, we vary the spin and optical properties of these compounds, indicating promise for designer quantum systems synthesized from the bottom-up.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2020, "Volume": 370, "Issue": 6522, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1309, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abb9352", "DOI Link": "http://dx.doi.org/10.1126/science.abb9352", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597271300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Firdaus, Y; Le Corre, VM; Khan, JI; Kan, ZP; Laquai, F; Beaujuge, PM; Anthopoulos, TD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Firdaus, Yuliar; Le Corre, Vincent M.; Khan, Jafar I.; Kan, Zhipeng; Laquai, Frederic; Beaujuge, Pierre M.; Anthopoulos, Thomas D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Key Parameters Requirements for Non-Fullerene-Based Organic Solar Cells with Power Conversion Efficiency >20%", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reported power conversion efficiencies (PCEs) of nonfullerene acceptor (NFA) based organic photovoltaics (OPVs) now exceed 14% and 17% for single-junction and two-terminal tandem cells, respectively. However, increasing the PCE further requires an improved understanding of the factors limiting the device efficiency. Here, the efficiency limits of single-junction and two-terminal tandem NFA-based OPV cells are examined with the aid of a numerical device simulator that takes into account the optical properties of the active material(s), charge recombination effects, and the hole and electron mobilities in the active layer of the device. The simulations reveal that single-junction NFA OPVs can potentially reach PCE values in excess of 18% with mobility values readily achievable in existing material systems. Furthermore, it is found that balanced electron and hole mobilities of >10(-3) cm(2) V-1 s(-1) in combination with low nongeminate recombination rate constants of 10(-12) cm(3) s(-1) could lead to PCE values in excess of 20% and 25% for single-junction and two-terminal tandem OPV cells, respectively. This analysis provides the first tangible description of the practical performance targets and useful design rules for single-junction and tandem OPVs based on NFA materials, emphasizing the need for developing new material systems that combine these desired characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 162, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1802028, "DOI": "10.1002/advs.201802028", "DOI Link": "http://dx.doi.org/10.1002/advs.201802028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467524500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, ZG; Jin, L; Rezaei, SD; Wang, H; Chen, Y; Tjiptoharsono, F; Ho, JF; Gorelik, S; Ng, RJH; Ruan, QF; Qiu, CW; Yang, JKW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, Zhaogang; Jin, Lei; Rezaei, Soroosh Daqiqeh; Wang, Hao; Chen, Yang; Tjiptoharsono, Febiana; Ho, Jinfa; Gorelik, Sergey; Ng, Ray Jia Hong; Ruan, Qifeng; Qiu, Cheng-Wei; Yang, Joel K. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Schrodinger's red pixel by quasi-bound-states-in-the-continuum", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While structural colors are ubiquitous in nature, saturated reds are mysteriously absent. This long-standing problem of achieving Schrodinger's red demands sharp transitions from stopband to a high-reflectance passband with total suppression of higher-order resonullces at blue/green wavelengths. Current approaches based on nulloantennas are insufficient to satisfy all conditions simultaneously. Here, we designed Si nulloantennas to support two partially overlapping quasi-bound-states-in-the-continuum modes with a gradient descent algorithm to achieve sharp spectral edges at red wavelengths. Meanwhile, high-order modes at blue/green wavelengths are suppressed via engineering the substrate-induced diffraction channels and the absorption of amorphous Si. This design produces possibly the most saturated and brightest reds with similar to 80% reflectance, exceeding the red vertex in sRGB and even the cadmium red pigment. Its nature of being sensitive to polarization and illumination angle could be potentially used for information encryption, and this proposed paradigm could be generalized to other Schrodinger's color pixels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm4512", "DOI": "10.1126/sciadv.abm4512", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm4512", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760195100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YW; Luke, J; Privitera, A; Rolland, N; Labanti, C; Londi, G; Lemaur, V; Toolan, DTW; Sneyd, AJ; Jeong, S; Qian, DP; Olivier, Y; Sorace, L; Kim, JS; Beljonne, D; Li, Z; Gillett, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yiwen; Luke, Joel; Privitera, Alberto; Rolland, Nicolas; Labanti, Chiara; Londi, Giacomo; Lemaur, Vincent; Toolan, Daniel T. W.; Sneyd, Alexander J.; Jeong, Soyeong; Qian, Deping; Olivier, Yoann; Sorace, Lorenzo; Kim, Ji-Seon; Beljonne, David; Li, Zhe; Gillett, Alexander J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The critical role of the donor polymer in the stability of high-performance non-fullerene acceptor organic solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor operational stability of non-fullerene electron acceptor (NFA) organic solar cells (OSCs) currently limits their commercial application. While previous studies have primarily focused on the degradation of the NFA component, we also consider here the electron donor material. We examine the stability of three represen-tative donor polymers, PM6, D18, and PTQ10, paired with the bench-mark NFA, Y6. After light soaking PM6 and D18 in air, we find an enhanced conversion of singlet excitons into trapped interchain polaron pairs on sub-100 femtosecond timescales. This process out -competes electron transfer to Y6, significantly reducing the charge generation yield. However, this pathway is absent in PTQ10. We iden-tify twisting in the benzo[1,2-b:4,5-b0]dithiophene (BDT)-thiophene motif shared by PM6 and D18 as the cause. By contrast, PTQ10 does not contain this structural motif and has improved stability. Thus, we show that the donor polymer can be a weak link for OSC sta-bility, which must be addressed collectively with the NFA.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 19", "Publication Year": 2023, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 810, "End Page": 829, "Article Number": null, "DOI": "10.1016/j.joule.2023.03.002", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.03.002", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984889900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JJ; Huang, JL; Ma, FJ; Sun, H; Cong, JL; Privat, K; Webster, RF; Cheong, SS; Yao, Y; Chin, RL; Yuan, XJ; He, MR; Sun, KW; Li, H; Mai, YH; Hameiri, Z; Ekins-Daukes, NJ; Tilley, RD; Unold, T; Green, MA; Hao, XJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jianjun; Huang, Jialiang; Ma, Fajun; Sun, Heng; Cong, Jialin; Privat, Karen; Webster, Richard F.; Cheong, Soshan; Yao, Yin; Chin, Robert Lee; Yuan, Xiaojie; He, Mingrui; Sun, Kaiwen; Li, Hui; Mai, Yaohua; Hameiri, Ziv; Ekins-Daukes, Nicholas J.; Tilley, Richard D.; Unold, Thomas; Green, Martin A.; Hao, Xiaojing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unveiling microscopic carrier loss mechanisms in 12% efficient Cu2ZnSnSe4 solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding carrier loss mechanisms at microscopic regions is imperative for the development of high-performance polycrystalline inorganic thin-film solar cells. Despite the progress achieved for kesterite, a promising environmentally benign and earth-abundant thin-film photovoltaic material, the microscopic carrier loss mechanisms and their impact on device performance remain largely unknown. Herein, we unveil these mechanisms in state-of-the-art Cu2ZnSnSe4 (CZTSe) solar cells using a framework that integrates multiple microscopic and macroscopic characterizations with three-dimensional device simulations. The results indicate the CZTSe films have a relatively long intragrain electron lifetime of 10-30 ns and small recombination losses through bandgap and/or electrostatic potential fluctuations. We identify that the effective minority carrier lifetime of CZTSe is dominated by a large grain boundary recombination velocity (similar to 10(4) cm s(-1)), which is the major limiting factor of present device performance. These findings and the framework can greatly advance the research of kesterite and other emerging photovoltaic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 107, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2022, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 754, "End Page": 764, "Article Number": null, "DOI": "10.1038/s41560-022-01078-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-022-01078-7", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828440800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guzman-Puyol, S; Hierrezuelo, J; Benítez, JJ; Tedeschi, G; Porras-Vázquez, JM; Heredia, A; Athanassiou, A; Romero, D; Heredia-Guerrero, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guzman-Puyol, Susana; Hierrezuelo, Jesus; Benitez, Jose J.; Tedeschi, Giacomo; Porras-Vazquez, Jose M.; Heredia, Antonio; Athanassiou, Athanassia; Romero, Diego; Heredia-Guerrero, Jose A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent, UV-blocking, and high barrier cellulose-based bioplastics with naringin as active food packaging materials", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free-standing, robust, and transparent bioplastics were obtained by blending cellulose and naringin at different proportions. Optical, thermal, mechanical, antioxidant, and antimicrobial properties were systematically investigated. In general, the incorporation of naringin produced important UV blocking and plasticizer effects and good antioxidant and antibacterial properties. Moreover, the barrier properties were characterized by determination of their water and oxygen transmission rates, finding that both parameters decreased by increasing the naringin content and reaching values similar to other petroleum-based plastics and cellulose derivatives used for food packaging applications. Finally, the biodegradability of these films was determined by measurement of the biological oxygen demand (BOD) in seawater, demonstrating an excellent decomposition in such conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 87, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2022, "Volume": 209, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1985, "End Page": 1994, "Article Number": null, "DOI": "10.1016/j.ijbiomac.2022.04.177", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2022.04.177", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808097200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, W; Dong, BW; Farmakidis, N; Li, X; Youngblood, N; Huang, KR; He, YH; Wright, CD; Pernice, WHP; Bhaskaran, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Wen; Dong, Bowei; Farmakidis, Nikolaos; Li, Xuan; Youngblood, Nathan; Huang, Kairan; He, Yuhan; David Wright, C.; Pernice, Wolfram H. P.; Bhaskaran, Harish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-memory photonic dot-product engine with electrically programmable weight banks", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electronically reprogrammable photonic circuits based on phase-change chalcogenides present an avenue to resolve the von-Neumann bottleneck; however, implementation of such hybrid photonic-electronic processing has not achieved computational success. Here, we achieve this milestone by demonstrating an in-memory photonic-electronic dot-product engine, one that decouples electronic programming of phase-change materials (PCMs) and photonic computation. Specifically, we develop non-volatile electronically reprogrammable PCM memory cells with a record-high 4-bit weight encoding, the lowest energy consumption per unit modulation depth (1.7 nJ/dB) for Erase operation (crystallization), and a high switching contrast (158.5%) using non-resonullt silicon-on-insulator waveguide microheater devices. This enables us to perform parallel multiplications for image processing with a superior contrast-to-noise ratio (>= 87.36) that leads to an enhanced computing accuracy (standard deviation sigma <= 0.007). An in-memory hybrid computing system is developed in hardware for convolutional processing for recognizing images from the MNIST database with inferencing accuracies of 86% and 87%. Hybrid photonic-electronic systems are essential for high-throughput neuromorphic computing. Here, the authors report an in-memory photonic-electronic dot-product engine with decoupled electronic programming of the phase-change memory cells and parallel photonic computation with high-bit operation, low energy consumption, and high accuracy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2887, "DOI": "10.1038/s41467-023-38473-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38473-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000991277000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Place, APM; Rodgers, LVH; Mundada, P; Smitham, BM; Fitzpatrick, M; Leng, ZQ; Premkumar, A; Bryon, J; Vrajitoarea, A; Sussman, S; Cheng, GM; Madhavan, T; Babla, HK; Le, XH; Gang, YQ; Jäck, B; Gyenis, A; Yao, N; Cava, RJ; de Leon, NP; Houck, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Place, Alexander P. M.; Rodgers, Lila V. H.; Mundada, Pranav; Smitham, Basil M.; Fitzpatrick, Mattias; Leng, Zhaoqi; Premkumar, Anjali; Bryon, Jacob; Vrajitoarea, Andrei; Sussman, Sara; Cheng, Guangming; Madhavan, Trisha; Babla, Harshvardhan K.; Le, Xuan Hoang; Gang, Youqi; Jack, Berthold; Gyenis, Andras; Yao, null; Cava, Robert J.; de Leon, Nathalie P.; Houck, Andrew A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New material platform for superconducting transmon qubits with coherence times exceeding 0.3 milliseconds", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The superconducting transmon qubit is a leading platform for quantum computing and quantum science. Building large, useful quantum systems based on transmon qubits will require significant improvements in qubit relaxation and coherence times, which are orders of magnitude shorter than limits imposed by bulk properties of the constituent materials. This indicates that relaxation likely originates from uncontrolled surfaces, interfaces, and contaminullts. Previous efforts to improve qubit lifetimes have focused primarily on designs that minimize contributions from surfaces. However, significant improvements in the lifetime of two-dimensional transmon qubits have remained elusive for several years. Here, we fabricate two-dimensional transmon qubits that have both lifetimes and coherence times with dynamical decoupling exceeding 0.3 milliseconds by replacing niobium with tantalum in the device. We have observed increased lifetimes for seventeen devices, indicating that these material improvements are robust, paving the way for higher gate fidelities in multi-qubit processors. Quantum computers based on superconducting transmon qubits are limited by single qubit lifetimes and coherence times, which are orders of magnitude shorter than limits imposed by bulk material properties. Here, the authors fabricate two-dimensional transmon qubits with both lifetimes and coherence times longer than 0.3 milliseconds by replacing niobium with tantalum in the device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1779, "DOI": "10.1038/s41467-021-22030-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22030-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631934100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dager, A; Uchida, T; Maekawa, T; Tachibana, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dager, Akansha; Uchida, Takashi; Maekawa, Toru; Tachibana, Masaru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and characterization of Mono-disperse Carbon Quantum Dots from Fennel Seeds: Photoluminescence analysis using Machine Learning", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, we present the synthesis of mono-dispersed C-QDs via single-step thermal decomposition process using the fennel seeds (Foeniculum vulgare). As synthesized C-QDs have excellent colloidal, photo-stability, environmental stability (pH) and do not require any additional surface passivation step to improve the fluorescence. The C-QDs show excellent PL activity and excitation-independent emission. Synthesis of excitation-independent C-QDs, to the best of our knowledge, using natural carbon source via pyrolysis process has never been achieved before. The effect of reaction time and temperature on pyrolysis provides insight into the synthesis of C-QDs. We used Machine-learning techniques (ML) such as PCA, MCR-ALS, and NMF-ARD-SO in order to provide a plausible explanation for the origin of the PL mechanism of as-synthesized C-QDs. ML techniques are capable of handling and analyzing the large PL data-set, and institutively recommend the best excitation wavelength for PL analysis. Mono-disperse C-QDs are highly desirable and have a range of potential applications in bio-sensing, cellular imaging, LED, solar cell, supercapacitor, printing, and sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14004, "DOI": "10.1038/s41598-019-50397-5", "DOI Link": "http://dx.doi.org/10.1038/s41598-019-50397-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488223900007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XM; Chen, N; Ye, DN; Zhong, AG; Liu, H; Li, ZF; Liu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xu-Min; Chen, Na; Ye, Dong-Nai; Zhong, Ai-Guo; Liu, Hui; Li, Zaifang; Liu, Shi-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structurally Complementary Star-Shaped Unfused Ring Electron Acceptors with Simultaneously Enhanced Device Parameters for Ternary Organic Solar Cells", "Source Title": "SOLAR RRL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ternary strategy has attracted extensive attention for bulk heterojunction organic solar cells (BHJ OSCs) owing to their potentially improved light harvesting, cascaded energy levels, and optimized film morphology of binary BHJs. Herein, three novel star-shaped unfused ring electron acceptors (SSUFREAs), i.e., H1-3, with and without fluorine-substituent in phenyl core or peripheral group are designed and synthesized as third components via direct C-H arylation to incorporate into PM6:Y6 BHJ films. The structure-property-performance dependence study reveals that the isotropic charge transfer, complementary star-shape structure and light absorption, and energy-level cascades of H1-3 with PM6 and Y6 allow ternary BHJs to have higher power conversion efficiency (PCE) compared to the PM6:Y6 binary BHJ. Among them, the ternary BHJ involving fluorine-free H1, i.e., H1:PM6:Y6, possesses the highest PCE (16.57%) owing to the high-lying frontier molecular orbital and the enlarged torsion angle, which enhances open-circuit voltage, inhibits the excessive crystallization of Y6, and facilitates exciton dissociation as well as collection. The findings indicate that SSUFREAs have great potential to serve as third components to optimize morphology and improve the open-circuit voltage of BHJ OSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 7, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/solr.202300143", "DOI Link": "http://dx.doi.org/10.1002/solr.202300143", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000970636000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "O'Kane, SEJ; Ai, WL; Madabattula, G; Alonso-Alvarez, D; Timms, R; Sulzer, V; Edge, JS; Wu, B; Offer, GJ; Marinescu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "O'Kane, Simon E. J.; Ai, Weilong; Madabattula, Ganesh; Alonso-Alvarez, Diego; Timms, Robert; Sulzer, Valentin; Edge, Jacqueline Sophie; Wu, Billy; Offer, Gregory J.; Marinescu, Monica", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lithium-ion battery degradation: how to model it", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting lithium-ion battery degradation is worth billions to the global automotive, aviation and energy storage industries, to improve performance and safety and reduce warranty liabilities. However, very few published models of battery degradation explicitly consider the interactions between more than two degradation mechanisms, and none do so within a single electrode. In this paper, the first published attempt to directly couple more than two degradation mechanisms in the negative electrode is reported. The results are used to map different pathways through the complicated path dependent and non-linear degradation space. Four degradation mechanisms are coupled in PyBaMM, an open source modelling environment uniquely developed to allow new physics to be implemented and explored quickly and easily. Crucially it is possible to see 'inside the model and observe the consequences of the different patterns of degradation, such as loss of lithium inventory and loss of active material. For the same cell, five different pathways that can result in end-of-life have already been found, depending on how the cell is used. Such information would enable a product designer to either extend life or predict life based upon the usage pattern. However, parameterization of the degradation models remains as a major challenge, and requires the attention of the international battery community.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2022, "Volume": 24, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7909, "End Page": 7922, "Article Number": null, "DOI": "10.1039/d2cp00417h", "DOI Link": "http://dx.doi.org/10.1039/d2cp00417h", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000771030800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tsujii, N; Nishide, A; Hayakawa, J; Mori, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tsujii, Naohito; Nishide, Akinori; Hayakawa, Jun; Mori, Takao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of enhanced thermopower due to spin fluctuation in weak itinerant ferromagnet", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing demand for higher energy efficiency calls for waste heat recovery technology. Thus, facilitating practical thermoelectric generation systems is strongly desired. One option is enhancing the thermoelectric power factor, S-2/r, where S is the Seebeck coefficient and r is the electrical resistivity, although it is still challenging because of the trade-off between S and r. We demonstrate that enhanced S-2/r can be achieved by incorporating magnetic interaction in ferromagnetic metals via the spin fluctuation arising from itinerant electrons. We show that electron-doped Heusler alloys exhibit weak ferromagnetism at T-C near room temperature with a small magnetic moment. A pronounced enhancement around T-C was observed, with a 20% improvement in the power factor from the case where spin fluctuation is suppressed by applying magnetic field. This result supports the merit of using spin fluctuation to further enhance thermoelectric properties and the potential to further probe correlations and synergy between magnetic and thermoelectric fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat5935", "DOI": "10.1126/sciadv.aat5935", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat5935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goryca, M; Li, J; Stier, AV; Taniguchi, T; Watanabe, K; Courtade, E; Shree, S; Robert, C; Urbaszek, B; Marie, X; Crooker, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goryca, M.; Li, J.; Stier, A. V.; Taniguchi, T.; Watanabe, K.; Courtade, E.; Shree, S.; Robert, C.; Urbaszek, B.; Marie, X.; Crooker, S. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing exciton masses and dielectric properties of monolayer semiconductors with high magnetic fields", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In semiconductor physics, many essential optoelectronic material parameters can be experimentally revealed via optical spectroscopy in sufficiently large magnetic fields. For monolayer transition-metal dichalcogenide semiconductors, this field scale is substantialtens of teslas or more-due to heavy carrier masses and huge exciton binding energies. Here we report absorption spectroscopy of monolayer MoS2, MoSe2, MoTe2, and WS2 in very high magnetic fields to 91 T. We follow the diamagnetic shifts and valley Zeeman splittings of not only the exciton's is ground state but also its excited 2s, 3s, ..., ns Rydberg states. This provides a direct experimental measure of the effective (reduced) exciton masses and dielectric properties. Exciton binding energies, exciton radii, and free-particle bandgaps are also determined. The measured exciton masses are heavier than theoretically predicted, especially for Mo-based monolayers. These results provide essential and quantitative parameters for the rational design of opto-electronic van der Waals heterostructures incorporating 2D semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 13", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4172, "DOI": "10.1038/s41467-019-12180-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-12180-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485685900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Winter, SM; Li, Y; Jeschke, HO; Valentí, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Winter, Stephen M.; Li, Ying; Jeschke, Harald O.; Valenti, Roser", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges in design of Kitaev materials: Magnetic interactions from competing energy scales", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, we reanalyze the magnetic interactions in the Kitaev spin-liquid candidate materials Na2IrO3, alpha-RuCl3, and alpha-Li2IrO3 using nonperturbative exact diagonalization methods. These methods are more appropriate given the relatively itinerant nature of the systems suggested in previous works. We treat all interactions up to third neighbors on equal footing. The computed terms reveal significant long-range coupling, bond anisotropy, and/or off-diagonal couplings which we argue naturally explain the observed ordered phases in these systems. Given these observations, the potential for realizing the spin-liquid state in real materials is analyzed, and synthetic challenges are defined and explained.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 412, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2016, "Volume": 93, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 214431, "DOI": "10.1103/PhysRevB.93.214431", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.214431", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378808500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paquin, F; Rivnay, J; Salleo, A; Stingelin, N; Silva-Acuña, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paquin, Francis; Rivnay, Jonathan; Salleo, Alberto; Stingelin, Natalie; Silva-Acuna, Carlos", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-phase microstructures drive exciton dissociation in neat semicrystalline polymeric semiconductors", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The optoelectronic properties of macromolecular semiconductors depend fundamentally on their solid-state microstructure and phase morphology. Hence, it is of central importance to manipulate-from the outset-the molecular arrangement and packing of this special class of polymers from the nullo-to the micrometer scale when they are integrated in thin film devices such as photovoltaic cells, transistors or light-emitting diodes, for example. One effective strategy for this purpose is to vary their molecular weight. The reason for this is that materials of different weight-average molecular weight (M-w) lead to different microstructures. Polymers of low M-w form unconnected, extended-chain crystals because of their non-entangled nature. As a result, a polycrystalline, one-phase morphology is obtained. In contrast, high-M-w materials, in which average chain lengths are longer than the length between entanglements, form two-phase morphologies comprised of crystalline moieties embedded in largely un-ordered (amorphous) regions. Here, we discuss how changes in these structural features affect exciton dissociation processes. We utilise neat regioregular poly(3-hexylthiophene) (P3HT) of varying M-w as a model system and apply time-resolved photoluminescence (PL) spectroscopy to probe the electronic landscape in a range of P3HT thin-film architectures. We find that at 10 K, PL originating from recombination of long-lived charge pairs decays over microsecond timescales. Tellingly, both the amplitude and decay-rate distribution depend strongly on M-w. In films with dominullt one-phase, chain-extended microstructures, the delayed PL is suppressed as a result of a diminished yield of photoinduced charges. Its decay is significantly slower than in two-phase microstructures. We therefore conclude that excitons in disordered regions between crystalline and amorphous phases dissociate extrinsically with yield and spatial distribution that depend intimately upon microstructure, in agreement with previous work [Paquin et al., Phys. Rev. Lett., 2011, 106, 197401]. We note, however, that independent of M-w, the delayed-PL lineshape due to charge recombination is representative of that in low-M-w microstructures. We thus hypothesize that charge recombination at these low temperatures-and likely also charge generation-occur in torsionally disordered chains forming more strongly coupled photophysical aggregates than those in the steady-state ensemble, producing a delayed PL lineshape reminiscent of that in paraffinic morphologies at steady state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 781, "Times Cited, All Databases": 803, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 10715, "End Page": 10722, "Article Number": null, "DOI": "10.1039/c5tc02043c", "DOI Link": "http://dx.doi.org/10.1039/c5tc02043c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363252200006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, YH; Xia, ZC; Kang, KF; Zhu, JC; Knueppel, P; Vaswani, C; Watanabe, K; Taniguchi, T; Mak, KF; Shan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Yihang; Xia, Zhengchao; Kang, Kaifei; Zhu, Jiacheng; Knueppel, Patrick; Vaswani, Chirag; Watanabe, Kenji; Taniguchi, Takashi; Mak, Kin Fai; Shan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamic evidence of fractional Chern insulator in moiré MoTe2", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chern insulators, which are the lattice analogues of the quantum Hall states, can potentially manifest high-temperature topological orders at zero magnetic field to enable next-generation topological quantum devices(1-3). Until now, integer Chern insulators have been experimentally demonstrated in several systems at zero magnetic field(3-8), whereas fractional Chern insulators have been reported in only graphene-based systems under a finite magnetic field(9,10). The emergence of semiconductor moire materials(11), which support tunable topological flat bands(12,13), provides an opportunity to realize fractional Chern insulators(13-16). Here we report thermodynamic evidence of both integer and fractional Chern insulators at zero magnetic field in small-angle twisted bilayer MoTe2 by combining the local electronic compressibility and magneto-optical measurements. At hole filling factor nu = 1 and 2/3, the system is incompressible and spontaneously breaks time-reversal symmetry. We show that they are integer and fractional Chern insulators, respectively, from the dispersion of the state in the filling factor with an applied magnetic field. We further demonstrate electric-field-tuned topological phase transitions involving the Chern insulators. Our findings pave the way for the demonstration of quantized fractional Hall conductance and anyonic excitation and braiding17 in semiconductor moire materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2023, "Volume": 622, "Issue": 7981, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-023-06452-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06452-3", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078346100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McClain, KR; Gould, CA; Chakarawet, K; Teat, SJ; Groshens, TJ; Long, JR; Harvey, BG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McClain, K. Randall; Gould, Colin A.; Chakarawet, Khetpakorn; Teat, Simon J.; Groshens, Thomas J.; Long, Jeffrey R.; Harvey, Benjamin G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium(III) metallocenium single-molecule magnets", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A series of dysprosium(III) metallocenium salts, [Dy(Cp-iPr4R)(2)][B(C6F5)(4)] (R = H (1), Me (2), Et (3), iPr (4)), was synthesized by reaction of Dyl(3) with the corresponding known NaCpiPr4R (R = H, iPr) and novel NaCpiPr4R (R = Me, Et) salts at high temperature, followed by iodide abstraction with [H(SiEt3)(2)][B(C6F5)(4)]. Variation of the substituents in this series results in substantial changes in molecular structure, with more sterically-encumbering cyclopentadienyl ligands promoting longer Dy-C distances and larger Cp-Dy-Cp angles. Dc and ac magnetic susceptibility data reveal that these structural changes have a considerable impact on the magnetic relaxation behavior and operating temperature of each compound. In particular, the magnetic relaxation barrier increases as the Dy-C distance decreases and the Cp-Dy-Cp angle increases. An overall 45 K increase in the magnetic blocking temperature is observed across the series, with compounds 2-4 exhibiting the highest 100 s blocking temperatures yet reported for a single-molecule magnet. Compound 2 possesses the highest operating temperature of the series with a 100 s blocking temperature of 62 K. Concomitant increases in the effective relaxation barrier and the maximum magnetic hysteresis temperature are observed, with 2 displaying a barrier of 1468 cm(-1) and open magnetic hysteresis as high as 72 K at a sweep rate of 3.1 mT s(-1). Magneto-structural correlations are discussed with the goal of guiding the synthesis of future high operating temperature Dy-III metallocenium single-molecule magnets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 449, "Times Cited, All Databases": 465, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2018, "Volume": 9, "Issue": 45, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8492, "End Page": 8503, "Article Number": null, "DOI": "10.1039/c8sc03907k", "DOI Link": "http://dx.doi.org/10.1039/c8sc03907k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451072300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cho, C; Wen, XH; Park, N; Li, ES", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cho, Choonlae; Wen, Xinhua; Park, Namkyoo; Li, Jensen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Digitally virtualized atoms for acoustic metamaterials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By designing tailor-made resonullce modes with structured atoms, metamaterials allow us to obtain constitutive parameters outside their limited range from natural materials. Nonetheless, tuning the constitutive parameters depends on our ability to modify the physical structure or external circuits attached to the metamaterials, posing a fundamental challenge to the range of tunability in many real-time applications. Here, we propose the concept of virtualized metamaterials on their signal response function to escape the boundary inherent in the physical structure of metamaterials. By replacing the resonating physical structure with a designer mathematical convolution kernel with a fast digital signal processing circuit, we demonstrate a decoupled control of the effective bulk modulus and mass density of acoustic metamaterials on-demand through a software-defined frequency dispersion. Providing freely software-reconfigurable amplitude, center frequency, bandwidth of frequency dispersion, our approach adds an additional dimension to constructing non-reciprocal, non-Hermitian, and topological systems with time-varying capability as potential applications. Tuning the constitutive parameters of metamaterials in real time depends on the ability to modify the structure or external circuits attached to the metamaterials. Here, the authors propose virtualized metamaterials, allowing the tuning of acoustic parameters on-demand through software-defined frequency dispersion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 251, "DOI": "10.1038/s41467-019-14124-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14124-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528902500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rüggeberg, M; Burgert, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rueggeberg, Markus; Burgert, Ingo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bio-Inspired Wooden Actuators for Large Scale Applications", "Source Title": "PLOS ONE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Implementing programmable actuation into materials and structures is a major topic in the field of smart materials. In particular the bilayer principle has been employed to develop actuators that respond to various kinds of stimuli. A multitude of small scale applications down to micrometer size have been developed, but up-scaling remains challenging due to either limitations in mechanical stiffness of the material or in the manufacturing processes. Here, we demonstrate the actuation of wooden bilayers in response to changes in relative humidity, making use of the high material stiffness and a good machinability to reach large scale actuation and application. Amplitude and response time of the actuation were measured and can be predicted and controlled by adapting the geometry and the constitution of the bilayers. Field tests in full weathering conditions revealed long-term stability of the actuation. The potential of the concept is shown by a first demonstrator. With the sensor and actuator intrinsically incorporated in the wooden bilayers, the daily change in relative humidity is exploited for an autonomous and solar powered movement of a tracker for solar modules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 373, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2015, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e0120718", "DOI": "10.1371/journal.pone.0120718", "DOI Link": "http://dx.doi.org/10.1371/journal.pone.0120718", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352139000031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mohseni-Shahri, FS; Moeinpour, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mohseni-Shahri, Fatemeh S.; Moeinpour, Farid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Development of a pH-sensing indicator for shrimp freshness monitoring: Curcumin and anthocyanin-loaded gelatin films", "Source Title": "FOOD SCIENCE & NUTRITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An intelligent pH-sensing indicator containing Roselle (Hibiseus sabdariffa L.) (RS) anthocyanin and curcumin (CR) was developed and characterized as on-package indicator tags to check the freshness of shrimp during the storage at 4 degrees C. FE-SEM and FT-IR analysis showed that RS and CR were successfully immobilized in the gelatin-glycerol film-forming substrate. The addition of various natural dyes increased the thickness and antioxidant action of the colorimetric film. To assess the response to changes in the pH, the colorimetric film was immersed in different buffers. Based on volatile amines secreted by shrimp, a test application of a colorimetric film containing natural dyes at a ratio of CR:RS = 1:4 (v/v) was conducted in shrimp at 4 degrees C. The total volatile basic nitrogen ( TVB-N) and the pH of shrimp were monitored during refrigerated storage for 10 days, and the color changes of the indicator were recorded simultaneously. The results indicated that the designed colorimetric film could produce various colors, which are thought to be indicative of the freshness and spoilage of packaged shrimp. Therefore, the target film can be utilized as a promising smart packaging material for monitoring the freshness of shrimp and aquatic products in real time.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 38, "Times Cited, All Databases": 38, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 11, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3898, "End Page": 3910, "Article Number": null, "DOI": "10.1002/fsn3.3375", "DOI Link": "http://dx.doi.org/10.1002/fsn3.3375", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000973385700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chmiela, S; Sauceda, HE; Poltavsky, I; Müller, KR; Tkatchenko, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chmiela, Stefan; Sauceda, Huziel E.; Poltavsky, Igor; Mueller, Klaus-Robert; Tkatchenko, Alexandre", "Book Author Full Names": null, "Group Authors": null, "Article Title": "sGDML: Constructing accurate and data efficient molecular force fields using machine learning", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an optimized implementation of the recently proposed symmetric gradient domain machine learning (sGDML) model. The sGDML model is able to faithfully reproduce global potential energy surfaces (PES) for molecules with a few dozen atoms from a limited number of user-provided reference molecular conformations and the associated atomic forces. Here, we introduce a Python software package to reconstruct and evaluate custom sGDML force fields (FFs), without requiring in-depth knowledge about the details of the model. A user-friendly command-line interface offers assistance through the complete process of model creation, in an effort to make this novel machine learning approach accessible to broad practitioners. Our paper serves as a documentation, but also includes a practical application example of how to reconstruct and use a PBEO+MBD FF for paracetamol. Finally, we show how to interface 5GDML with the FF simulation engines ASE (Larsen et al., 2017) and i-PI (Kapil et al., 2019) to run numerical experiments, including structure optimization, classical and path integral molecular dynamics and nudged elastic band calculations. (C) 2019 The Author(s). Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 240, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 38, "End Page": 45, "Article Number": null, "DOI": "10.1016/j.cpc.2019.02.007", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2019.02.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474312900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Turchenko, VA; Trukhanov, SV; Kostishin, VG; Damay, F; Porcher, F; Klygach, DS; Vakhitov, MG; Matzui, LY; Yakovenko, OS; Bozzo, B; Fina, I; Almessiere, MA; Slimani, Y; Baykal, A; Zhou, D; Trukhanov, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Turchenko, Vitalii Alexandrovich; Trukhanov, Sergei Valentnovich; Kostishin, Vladmir Grigor'evich; Damay, Francua; Porcher, Florance; Klygach, Denis Sergeevich; Vakhitov, Maxim Grigor'evich; Matzui, Lyudmila Yur'evna; Yakovenko, Olena Sergeevna; Bozzo, Bernat; Fina, Ignasi; Almessiere, Munirah Abdullah; Slimani, Yassine; Baykal, Abdulhadi; Zhou, Di; Trukhanov, Alex Valentinovich", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of In3+ cations on structure and electromagnetic state of M-type hexaferrites", "Source Title": "JOURNAL OF ENERGY CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The solid solutions of In3+ doped M-type strontium hexaferrites were produced using a conventional solid-state reaction method, and Rietveld analysis of the neutron diffraction patterns was conducted. In3+ cations occupy octahedral (4f(VI) and 12 k) and tetrahedral (4f(IV)) positions (SG = P6(3)/mmc (No. 194)). The average particle size is 837-650 nm. Curie tempearature (T-C) of the compounds monotonically decreased down to similar to 520 K with increasing x. A frustrated magnetic state was detected from ZFC and FC magnetizations. saturation magnetization (M-s) and effective magnetocrystalline anisotropy coefficient (k(eff)) were determined using the law of approach to saturation. A real permittivity (e ) maximum of similar to 3.3 at similar to 45.5 GHz and an imaginary permittivity (e//) of similar to 1.6 at similar to 42.3 GHz were observed for x = 0.1. A real permeability (mu') maximum of similar to 1.5 at similar to 36.2 GHz was observed for x = 0. A mu imaginary permeability maximum of similar to 0.8 at similar to 38.3 GHz was observed for x = 0.1. The interpretation of the results is based on the type of dielectric polarization and the natural ferromagnetic resonullce features. (c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 69, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 667, "End Page": 676, "Article Number": null, "DOI": "10.1016/j.jechem.2021.12.027", "DOI Link": "http://dx.doi.org/10.1016/j.jechem.2021.12.027", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780468400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shah, IH; Miller, SA; Jiang, DQ; Myers, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shah, Izhar Hussain; Miller, Sabbie A.; Jiang, Daqian; Myers, Rupert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cement substitution with secondary materials can reduce annual global CO2 emissions by up to 1.3 gigatons", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Population and development megatrends will drive growth in cement production, which is already one of the most challenging-to-mitigate sources of CO2 emissions. However, availabilities of conventional secondary cementitious materials (CMs) like fly ash are declining. Here, we present detailed generation rates of secondary CMs worldwide between 2002 and 2018, showing the potential for 3.5 Gt to be generated in 2018. Maximal substitution of Portland cement clinker with these materials could have avoided up to 1.3 Gt CO2-eq. emissions (similar to 44% of cement production and similar to 2.8% of anthropogenic CO2-eq. emissions) in 2018. We also show that nearly all of the highest cement producing nations can locally generate and use secondary CMs to substitute up to 50% domestic Portland cement clinker, with many countries able to potentially substitute 100% Portland cement clinker. Our results highlight the importance of pursuing regionally optimized CM mix designs and systemic approaches to decarbonizing the global CMs cycle.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5758, "DOI": "10.1038/s41467-022-33289-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33289-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000862415000022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Roy, S; Bhattacharyya, A; Peterson, C; Krishnamoorthy, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Roy, Saurav; Bhattacharyya, Arkka; Peterson, Carl; Krishnamoorthy, Sriram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2.1 kV (001)-β-Ga2O3 vertical Schottky barrier diode with high-k oxide field plate", "Source Title": "APPLIED PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a vertical beta-Ga2O3 Schottky barrier diode (SBD) with BaTiO3 as field plate oxide on a low doped thick epitaxial layer exhibiting 2.1 kV breakdown voltage. A thick drift layer of 11 mu m with a low effective doping concentration of 8 x 10(15) cm(-3) is used to achieve high breakdown voltage. Using the high-k dielectric with a dielectric constant of 248, the breakdown voltage increases from 816 V for the non-field-plated SBD to 2152 V (>2x improvement) for the field-plated SBD without compromising the on-state performance. The diode dimensions are varied to analyze the effect of edge high-field related leakage with reverse bias and also the effect of current spreading during forward operation. Very uniform distribution of breakdown voltages of 2152 +/- 20 V are observed for the diode diameters from 50 to 300 mu m for the field-plated SBDs. The on and off state power losses are also analyzed and compared with the non-field-plated devices and the switching losses are estimated analytically.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2023, "Volume": 122, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 152101, "DOI": "10.1063/5.0137935", "DOI Link": "http://dx.doi.org/10.1063/5.0137935", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967612400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Goodenough, KM; Schilling, J; Jonsson, E; Kalvig, P; Charles, N; Tuduri, J; Deady, EA; Sadeghi, M; Schiellerup, H; Müller, A; Bertrand, G; Arvanitidis, N; Eliopoulos, DG; Shaw, RA; Thrane, K; Keulen, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Goodenough, K. M.; Schilling, J.; Jonsson, E.; Kalvig, P.; Charles, N.; Tuduri, J.; Deady, E. A.; Sadeghi, M.; Schiellerup, H.; Muller, A.; Bertrand, G.; Arvanitidis, N.; Eliopoulos, D. G.; Shaw, R. A.; Thrane, K.; Keulen, N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Europe's rare earth element resource potential: An overview of REE metallogenetic provinces and their geodynamic setting", "Source Title": "ORE GEOLOGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Security of supply of a number of raw materials is of concern for the European Union; foremost among these are the rare earth elements (REE), which are used in a range of modern technologies. A number of research projects, including the EURARE and ASTER projects, have been funded in Europe to investigate various steps along the REE supply chain. This paper addresses the initial part of that supply chain, namely the potential geological resources of the REE in Europe. Although the REE are not currently mined in Europe, potential resources are known to be widespread, and many are being explored. The most important European resources are associated with alkaline igneous rocks and carbonatites, although REE deposits are also known from a range of other settings. Within Europe, a number of REE metallogenetic belts can be identified on the basis of age, tectonic setting, lithological association and known REE enrichments. This paper reviews those metallogenetic belts and sets them in their geodynamic context. The most well-known of the REE belts are of Precambrian to Palaeozoic age and occur in Greenland and the Fennoscandian Shield. Of particular importance for their REE potential are the Gardar Province of SW Greenland, the Svecofennian Belt and subsequent Mesoproterozoic rifts in Sweden, and the carbonatites of the Central Iapetus Magmatic Province. However, several zones with significant potential for REE deposits are also identified in central, southern and eastern Europe, including examples in the Bohemian Massif, the Iberian Massif, and the Carpathians. (C) 2015 British Geological Survey, NERC. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 275, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 72, "Issue": null, "Part Number": 1, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 838, "End Page": 856, "Article Number": null, "DOI": "10.1016/j.oregeorev.2015.09.019", "DOI Link": "http://dx.doi.org/10.1016/j.oregeorev.2015.09.019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology; Mineralogy; Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366345100048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karimi-Maleh, H; Karimi, F; Orooji, Y; Mansouri, G; Razmjou, A; Aygun, A; Sen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karimi-Maleh, Hassan; Karimi, Fatemeh; Orooji, Yasin; Mansouri, Ghobad; Razmjou, Amir; Aygun, Aysenur; Sen, Fatih", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new nickel-based co-crystal complex electrocatalyst amplified by NiO dope Pt nullostructure hybrid; a highly sensitive approach for determination of cysteamine in the presence of serotonin", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A highly sensitive electrocatalytic sensor was designed and fabricated by the incorporation of NiO dope Pt nullostructure hybrid (NiO-Pt-H) as conductive mediator, bis (1,10 phenullthroline) (1,10-phenullthroline-5,6-dione) nickel(II) hexafluorophosphate (B,1,10,P,1,10, PDNiPF6), and electrocatalyst into carbon paste electrode (CPE) matrix for the determination of cysteamine. The NiO-Pt-H was synthesized by one-pot synthesis strategy and characterized by XRD, elemental mapping analysis (MAP), and FESEM methods. The characterization data, which confirmed good purity and spherical shape with a diameter of ? 30.64 nm for the synthesized NiO-Pt-H. NiO-Pt-H/B,1,10, P,1,10, PDNiPF6/CPE, showed an excellent catalytic activity and was used as a powerful tool for the determination of cysteamine in the presence of serotonin. The NiO-Pt-H/B,1,10, P,1,10, PDNiPF6/CPE was able to solve the overlap problem of the two drug signals and was used for the determination of cysteamine and serotonin in concentration ranges of 0.003-200 mu M and 0.5-260 mu M with detection limits of 0.5 nM and 0.1 mu M, using square wave voltammetric method, respectively. The NiO-Pt-H/B,1,10,P,1,10,PDNiPF6/CPE showed a high-performance ability for the determination of cysteamine and serotonin in the drug and pharmaceutical serum samples with the recovery data of 98.1-103.06%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 252, "Times Cited, All Databases": 252, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41598-020-68663-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-020-68663-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000550057200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, XW; Bergara, A; Wei, XD; Song, XX; Wang, LY; Sun, RX; Liu, HY; Hemley, RJ; Wang, L; Gao, GY; Tian, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Xiaowei; Bergara, Aitor; Wei, Xudong; Song, Xiaoxu; Wang, Linyan; Sun, Rongxin; Liu, Hanyu; Hemley, Russell J.; Wang, Lin; Gao, Guoying; Tian, Yongjun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of high-Tc superconductivity in ternary lanthanum borohydrides", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The study of superconductivity in compressed hydrides is of great interest due to measurements of high critical temperatures (T-c) in the vicinity of room temperature, beginning with the observations of LaH10 at 170-190 GPa. However, the pressures required for synthesis of these high-T-c superconducting hydrides currently remain extremely high. Here we show the investigation of crystal structures and superconductivity in the La-B-H system under pressure with particle-swarm intelligence structure-searches methods in combination with first-principles calculations. Structures with seven stoichiometries, LaBH, LaBH4, LaBH6, LaBH7, LaBH8, La(BH)(3), and La(BH4)(3) were predicted to become stable under pressure. Remarkably, the hydrogen atoms in LaBH8 were found to bond with B atoms in a manner that is similar to that in H3S. Lattice dynamics calculations indicate that LaBH7 and LaBH8 become dynamically stable at pressures as low as 109 and 48 GPa, respectively. Moreover, the two phases were predicted to be superconducting with a critical temperature T-c of 93 K and 156 K at 110 GPa and 55 GPa, respectively (mu* = 0.1). The present results provide guidance for future experiments targeting hydride superconductors with both low synthesis pressures and high T-c.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 4", "Publication Year": 2021, "Volume": 104, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134501, "DOI": "10.1103/PhysRevB.104.134501", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.104.134501", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000704472400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lunkenheimer, P; Loidl, A; Riechers, B; Zaccone, A; Samwer, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lunkenheimer, Peter; Loidl, Alois; Riechers, Birte; Zaccone, Alessio; Samwer, Konrad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal expansion and the glass transition", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Lindemann criterion states that crystals melt when thermal vibrations overcome binding forces. It is now found that this picture does not hold for glasses, and that there is a universal relationship between glass temperature and thermal expansion. Melting is well understood in terms of the Lindemann criterion, which essentially states that crystalline materials melt when the thermal vibrations of their atoms become so vigorous that they shake themselves free of the binding forces. This picture does not necessarily have to hold for glasses, where the nature of the solid-liquid cross-over is highly debated. The Lindemann criterion implies that the thermal expansion coefficients of crystals are inversely proportional to their melting temperatures. Here we find that, in contrast, the thermal expansion coefficient of glasses decreases more strongly with increasing glass temperature, which marks the liquid-solid cross-over in this material class. However, this proportionality returns when the thermal expansion coefficient is scaled by the fragility, a measure of particle cooperativity. Therefore, for a glass to become liquid, it is not sufficient to simply overcome the interparticle binding energies. Instead, more energy must be invested to break up the typical cooperative particle network that is common to glassy materials. The thermal expansion coefficient of the liquid phase reveals similar anomalous behaviour and is universally enhanced by a constant factor of approximately 3. These universalities allow the estimation of glass temperatures from thermal expansion and vice versa.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 19, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 694, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-022-01920-5", "DOI Link": "http://dx.doi.org/10.1038/s41567-022-01920-5", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927616600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thai, CH; Ferreira, AJM; Bordas, SPA; Rabczuk, T; Nguyen-Xuan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thai, Chien H.; Ferreira, A. J. M.; Bordas, S. P. A.; Rabczuk, T.; Nguyen-Xuan, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isogeometric analysis of laminated composite and sandwich plates using a new inverse trigonometric shear deformation theory", "Source Title": "EUROPEAN JOURNAL OF MECHANICS A-SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents a new inverse tangent shear deformation theory (ITSDT) for the static, free vibration and buckling analysis of laminated composite and sandwich plates. In the present theory, shear stresses are vanished at the top and bottom surfaces of the plates and shear correction factors are no longer required. A weak form of the static, free vibration and buckling models for laminated composite and sandwich plates based on ITSDT is then derived and is numerically solved using an isogeometric analysis (IGA). The proposed formulation requires C-1-continuity generalized displacements and hence basis functions used in IGA fulfill this requirement. Numerical examples are provided to show high efficiency of the present method compared with other published solutions. (C) 2013 Elsevier Masson SAS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN-FEB", "Publication Year": 2014, "Volume": 43, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 89, "End Page": 108, "Article Number": null, "DOI": "10.1016/j.euromechsol.2013.09.001", "DOI Link": "http://dx.doi.org/10.1016/j.euromechsol.2013.09.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000328809100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Banerjee, A; Lampen-Kelley, P; Knolle, J; Balz, C; Aczel, AA; Winn, B; Liu, YH; Pajerowski, D; Yan, JQ; Bridges, CA; Savici, AT; Chakoumakos, BC; Lumsden, MD; Tennullt, DA; Moessner, R; Mandrus, DG; Nagler, SE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Banerjee, Arnab; Lampen-Kelley, Paula; Knolle, Johannes; Balz, Christian; Aczel, Adam Anthony; Winn, Barry; Liu, Yaohua; Pajerowski, Daniel; Yan, Jiaqiang; Bridges, Craig A.; Savici, Andrei T.; Chakoumakos, Bryan C.; Lumsden, Mark D.; Tennullt, David Alan; Moessner, Roderich; Mandrus, David G.; Nagler, Stephen E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Excitations in the field-induced quantum spin liquid state of α-RuCl3", "Source Title": "NPJ QUANTUM MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The celebrated Kitaev quantum spin liquid (QSL) is the paradigmatic example of a topological magnet with emergent excitations in the form of Majorana Fermions and gauge fluxes. Upon breaking of time-reversal symmetry, for example in an external magnetic field, these fractionalized quasiparticles acquire non-Abelian exchange statistics, an important ingredient for topologically protected quantum computing. Consequently, there has been enormous interest in exploring possible material realizations of Kitaev physics and several candidate materials have been put forward, recently including alpha-RuCl3. In the absence of a magnetic field this material orders at a finite temperature and exhibits low-energy spin wave excitations. However, at moderate energies, the spectrum is unconventional and the response shows evidence for fractional excitations. Here we use time-of-flight inelastic neutron scattering to show that the application of a sufficiently large magnetic field in the honeycomb plane suppresses the magnetic order and the spin waves, leaving a gapped continuum spectrum of magnetic excitations. Our comparisons of the scattering to the available calculations for a Kitaev QSL show that they are consistent with the magnetic field induced QSL phase.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 352, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2018, "Volume": 3, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8, "DOI": "10.1038/s41535-018-0079-2", "DOI Link": "http://dx.doi.org/10.1038/s41535-018-0079-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426316500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, WQ; Zhang, WY; Tudi, A; Wang, LY; Zhou, X; Yang, ZH; Pan, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Wenqi; Zhang, Wenyao; Tudi, Abudukadi; Wang, Liying; Zhou, Xin; Yang, Zhihua; Pan, Shilie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fluorine-Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding and exploring the functional modules (FMs) consisting of local atomic groups can promote the development of the materials with functional performances. Oxygen-containing tetrahedral modules are popular in deep-ultraviolet (DUV) optical materials, but their weak optical anisotropy is adverse to birefringence. Here, the fluorooxosulfate group is proved as a new birefringence-enhanced FM for the first time. The birefringence of fluorooxosulfates can be 4.8-15.5 times that of sulfates with the same metal cations while maintaining a DUV band gap. The polarizing microscope measurement confirms the birefringence enhancement by using the millimeter crystals experimentally. The theoretical studies from micro and macro levels further reveal a novel universal strategy that the fluorine induced anisotropic electronic distribution in fluorooxo-tetrahedral group is responsible for the enhancement of birefringence. This study will guide the future discovery of DUV optical materials with enlarged birefringence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 103, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 8, "Issue": 15, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003594, "DOI": "10.1002/advs.202003594", "DOI Link": "http://dx.doi.org/10.1002/advs.202003594", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657698800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, A; Liu, B; Liu, B; Cao, YK; Wang, J; Liao, T; Li, J; Fang, QH; Liaw, PK; Liu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Ao; Liu, Bin; Liu, Bo; Cao, Yuankui; Wang, Jian; Liao, Tao; Li, Jia; Fang, Qihong; Liaw, Peter K.; Liu, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A novel cobalt-free oxide dispersion strengthened medium-entropy alloy with outstanding mechanical properties and irradiation resistance", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A novel cobalt-free oxide dispersion strengthened (ODS) equiatomic FeCrNi medium entropy alloy (MEA) was successfully fabricated through mechanical alloying and hot extrusion (HE). The ODS FeCrNi MEA is composed of a single face-centered cubic (FCC) matrix, in which highly dispersed oxide nulloparticles, including Y2Ti2O7, Y2TiO5 and Y2O3, are uniformly distributed. Compared with the FeCrNi MEA, the ODS FeCrNi MEA exhibits the improved yield strength (1120 MPa) and ultimate tensile strength (1274 MPa) with adequate ductility retention (12.1%). Theoretical analysis of the strengthening mechanism indicates that the high strength is mainly attributed to the grain-boundary strengthening caused by fine grains and the precipitation strengthening resulted from the oxide nulloparticles. Meanwhile, the matrix that easily activates mechanical twinning during the deformation process is the main reason to ensure moderate ductility. In addition, the introduction of high-density oxide nulloparticles can disperse the defect distri-bution and suppress the defect growth and irradiation-induced segregation, leading to the excellent irra-diation resistance. These findings provide innovative guidance for the development of high-performance structural materials for future nuclear energy applications with balanced strength and ductility.(c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 20", "Publication Year": 2023, "Volume": 152, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 190, "End Page": 200, "Article Number": null, "DOI": "10.1016/j.jmst.2022.11.061", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2022.11.061", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972590700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schoetz, T; Gordon, LW; Ivanov, S; Bund, A; Mandler, D; Messinger, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schoetz, T.; Gordon, L. W.; Ivanov, S.; Bund, A.; Mandler, D.; Messinger, R. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Disentangling faradaic, pseudocapacitive, and capacitive charge storage: A tutorial for the characterization of batteries, supercapacitors, and hybrid systems", "Source Title": "ELECTROCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Today's electrochemical energy storage technologies aim to combine high specific energy and power, as well as long cycle life, into one system to meet increasing demands in performance. These properties, however, are often characteristic of either batteries (high specific energy) or capacitors (high specific power and cyclability). To merge battery-and capacitor-like properties in a hybrid energy storage system, researchers must understand and control the co-existence of multiple charge storage mechanisms. Charge storage mechanisms can be classified as faradaic, capacitive, or pseudocapacitive, where their relative contributions determine the operating principles and electrochemical performance of the system. Hybrid electrochemical energy storage systems can be better understood and analyzed if the primary charge storage mechanism is identified correctly. This tutorial review first defines faradaic and capacitive charge storage mechanisms and then clarifies the definition of pseudocapacitance using a physically intuitive framework. Then, we discuss strategies that enable these charge storage mechanisms to be quantitatively disentangled using common electrochemical techniques. Finally, we outline representative hybrid energy storage systems that combine the electrochemical characteristics of batteries, capacitors and pseudocapacitors. Modern examples are analyzed while step-by-step guides are provided for all mentioned experimental methods in the Supplementary Information.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 168, "Times Cited, All Databases": 172, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 412, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 140072, "DOI": "10.1016/j.electacta.2022.140072", "DOI Link": "http://dx.doi.org/10.1016/j.electacta.2022.140072", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778650600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, ML; Fan, XR; Xie, W; Wang, HX; Suo, LM; Wang, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Minglei; Fan, Xueru; Xie, Wei; Wang, Haoxiang; Suo, Liumin; Wang, Chengliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Proof-of-Concept of Anode-Free Rechargeable Mg Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The desperate pursuit of high gravimetric specific energy leads to the ignorance of volumetric energy density that is one of the basic requirements for batteries. Due to the high volumetric capacity, less-prone formation of dendrite, and low reduction potential of Mg metal, rechargeable Mg batteries are considered with innately high volumetric energy density. Nevertheless, the substantial elevation in energy density is compromised by extremely excessive Mg metal anode. Herein, the proof-of-concept of anode-free Mg2Mo6S8-MgS/Cu batteries is proposed, in which MgS as the premagnesiation additive constantly decomposes to replenish Mg loss by electrolyte corrosion over cycling, while both Mg2Mo6S8 and MgS acts as the active material to reversibly provide high capacities. Besides, Mg2Mo6S8 shows superior catalytic activity on the decomposition of MgS and provides the strong affinity to polysulfides to restrain their dissolution. Consequently, the anode-free Mg2Mo6S8-MgS/Cu batteries deliver a high reversible capacity of 190 mAh g(-1) with the capacity retention of 92% after 100 cycles, corresponding to the highly competitive energy density of 420 Wh L-1. The proposed anode-free Mg battery here spotlights the great promise of Mg batteries in achieving high volumetric energy densities, which will significantly expedite the advances of Mg batteries in practice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 10, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202207563", "DOI Link": "http://dx.doi.org/10.1002/advs.202207563", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953621500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, JR; Chilton, NF; Vincent, AH; Whyatt, YL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Jeffrey R.; Chilton, Nicholas F.; Vincent, Alexandre H.; Whyatt, Yasmin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong Axiality in a Dysprosium(III) Bis(borolide) Complex Leads to Magnetic Blocking at 65 K", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Substituted dysprosocenium complexes of the type [Dy(CpR)2]+ exhibit slow magnetic relaxation at cryogenic temperatures and have emerged as top-performing single-molecule magnets. The remarkable properties of these compounds derive in part from the strong axial ligand field afforded by the cyclopentadiene anions, and the design of analogous compounds with even stronger ligand fields is one promising route toward identifying new single-molecule magnets that retain a magnetic memory at even higher temperatures. Here, we report the synthesis and characterization of a dysprosium bis(borolide) compound, [K(18-crown-6)][Dy(BC4Ph5)2] (1), featuring the dysprosocenate anion [Dy(BC4Ph5)2]- with a pseudoaxial coordination environment afforded by two dianionic pentaphenyl borolide ligands. Variable-field magnetization data reveal open magnetic hysteresis up to 66 K, establishing 1 as a top performing single-molecule magnet among its dysprosocenium analogues. Ac magnetic susceptibility data indicate that 1 relaxes via an Orbach mechanism above similar to 80 K with Ueff = 1500(100) cm-1 and tau 0 = 10-12.0(9) s, whereas Raman relaxation and quantum tunneling of the magnetization dominate at lower temperatures. Compound 1 exhibits a 100 s blocking temperature of 65 K, among the highest reported for dysprosium-based single-molecule magnets. Ab initio spin dynamics calculations support the experimental Ueff and tau 0 values and enable a quantitative comparison of the relaxation dynamics of 1 and two representative dysprosocenium cations, yielding additional insights into the impact of the crystal field splitting and vibronic coupling on the observed relaxation behavior. Importantly, compound 1 represents a step toward the development of alternatives to substituted dysprosocenium single molecule magnets with increased axiality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2023, "Volume": 145, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1572, "End Page": 1579, "Article Number": null, "DOI": "10.1021/jacs.2c08568", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c08568", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918065800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Serrano, D; Kuppusamy, SK; Heinrich, B; Fuhr, O; Hunger, D; Ruben, M; Goldner, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Serrano, Diana; Kuppusamy, Senthil Kumar; Heinrich, Benoit; Fuhr, Olaf; Hunger, David; Ruben, Mario; Goldner, Philippe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-narrow optical linewidths in rare-earth molecular crystals", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rare-earth ions (REIs) are promising solid-state systems for building light-matter interfaces at the quantum level(1,2). This relies on their potential to show narrow optical and spin homogeneous linewidths, or, equivalently, long-lived quantum states. This enables the use of REIs for photonic quantum technologies such as memories for light, optical-microwave transduction and computing(3-5). However, so far, few crystalline materials have shown an environment quiet enough to fully exploit REI properties. This hinders further progress, in particular towards REI-containing integrated nullophotonics devices(6,7). Molecular systems can provide such capability but generally lack spin states. If, however, molecular systems do have spin states, they show broad optical lines that severely limit optical-to-spin coherent interfacing(8-10). Here we report on europium molecular crystals that exhibit linewidths in the tens of kilohertz range, orders of magnitude narrower than those of other molecular systems. We harness this property to demonstrate efficient optical spin initialization, coherent storage of light using an atomic frequency comb, and optical control of ion-ion interactions towards implementation of quantum gates. These results illustrate the utility of rare-earth molecular crystals as a new platform for photonic quantum technologies that combines highly coherent emitters with the unmatched versatility in composition, structure and integration capability of molecular materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 603, "Issue": 7900, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 241, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04316-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04316-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936099600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, X; Chong, KA; Su, YT; Du, LM; Zhang, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Xu; Chong, Kainull; Su, Yutai; Du, Leiming; Zhang, Guoqi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Connecting the macroscopic and mesoscopic properties of sintered silver nulloparticles by crystal plasticity finite element method", "Source Title": "ENGINEERING FRACTURE MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The stress-strain response of sintered silver nulloparticles (AgNP) materials is precisely characterized in order to adapt for numerical analysis and rational design of electronic packaging structures in this study. A framework of crystal plasticity finite element method (CPFEM) is established based on the mechanism of crystal plastic deformation to describe the mesoscopic structural influence of grain evolution on the macroscopic properties of sintered AgNP materials. Material parameters of crystal plasticity are defined and initial orientations are randomly assigned for sintered AgNP grains. To calibrate the mesoscopic mechanical properties of sintered AgNP by the proposed CPFEM, the results of CPFEM simulations and uniaxial tensile tests subjected to different strain rates and temperatures are compared in terms of the stress-strain curves as the critical macroscopic characteristics. The predicted stress and deformation distributions in the polycrystalline structure demonstrate that the significant inhomogeneity of stress and deformation is caused by the different grain orientations of sintered AgNP. Furthermore, we elucidate the fracture mechanism influenced by the temperature and strain rate and also the effect of initial crystal orientation on the plastic strain of sintered AgNP. This study sheds light on the morphology design of sintered AgNP with optimized mechanical properties and fatigue resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 28", "Publication Year": 2023, "Volume": 281, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 109137, "DOI": "10.1016/j.engfracmech.2023.109137", "DOI Link": "http://dx.doi.org/10.1016/j.engfracmech.2023.109137", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950140800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motta, C; El-Mellouhi, F; Sanvito, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motta, Carlo; El-Mellouhi, Fedwa; Sanvito, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charge carrier mobility in hybrid halide perovskites", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The charge transport properties of hybrid halide perovskites are investigated with a combination of density functional theory including van der Waals interaction and the Boltzmann theory for diffusive transport in the relaxation time approximation. We find the mobility of electrons to be in the range 5-10 cm(2)V(-1)s(-1) and that for holes within 1-5 cm(2)V(-1)s(-1), where the variations depend on the crystal structure investigated and the level of doping. Such results, in good agreement with recent experiments, set the relaxation time to about 1 ps, which is the time-scale for the molecular rotation at room temperature. For the room temperature tetragonal phase we explore two possible orientations of the organic cations and find that the mobility has a significant asymmetry depending on the direction of the current with respect to the molecular axis. This is due mostly to the way the PbI3 octahedral symmetry is broken. Interestingly we find that substituting I with Cl has minor effects on the mobilities. Our analysis suggests that the carrier mobility is probably not a key factor in determining the high solar-harvesting efficiency of this class of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 325, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 3", "Publication Year": 2015, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12746, "DOI": "10.1038/srep12746", "DOI Link": "http://dx.doi.org/10.1038/srep12746", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358848500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Demir, S; Gonzalez, MI; Darago, LE; Evans, WJ; Long, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Demir, Selvan; Gonzalez, Miguel I.; Darago, Lucy E.; Evans, William J.; Long, Jeffrey R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant coercivity and high magnetic blocking temperatures for N23- radical-bridged dilanthanide complexes upon ligand dissociation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increasing the operating temperatures of single-molecule magnets-molecules that can retain magnetic polarization in the absence of an applied field-has potential implications toward information storage and computing, and may also inform the development of new bulk magnets. Progress toward these goals relies upon the development of synthetic chemistry enabling enhancement of the thermal barrier to reversal of the magnetic moment, while suppressing alternative relaxation processes. Herein, we show that pairing the axial magnetic anisotropy enforced by tetramethylcyclopentadienyl (Cp-Me4H) capping ligands with strong magnetic exchange coupling provided by an N-2(3-) radical bridging ligand results in a series of dilanthanide complexes exhibiting exceptionally large magnetic hysteresis loops that persist to high temperatures. Significantly, reducing the coordination number of the metal centers appears to increase axial magnetic anisotropy, giving rise to larger magnetic relaxation barriers and 100-s magnetic blocking temperatures of up to 20 K, as observed for the complex [K(crypt-222)][(CpMe4H(2)Tb)(2)(mu-N-2(center dot))].", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 309, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2144, "DOI": "10.1038/s41467-017-01553-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01553-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000418236800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sanvito, S; Oses, C; Xue, JK; Tiwari, A; Zic, M; Archer, T; Tozman, P; Venkatesan, M; Coey, M; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sanvito, Stefano; Oses, Corey; Xue, Junkai; Tiwari, Anurag; Zic, Mario; Archer, Thomas; Tozman, Pelin; Venkatesan, Munuswamy; Coey, Michael; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated discovery of new magnets in the Heusler alloy family", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic materials underpin modern technologies, ranging from data storage to energy conversion to contactless sensing. However, the development of a new high-performance magnet is a long and often unpredictable process, and only about two dozen magnets are featured in mainstream applications. We describe a systematic pathway to the design of novel magnetic materials, which demonstrates a high throughput and discovery speed. On the basis of an extensive electronic structure library of Heusler alloys containing 236,115 prototypical compounds, we filtered those displaying magnetic order and established whether they can be fabricated at thermodynamic equilibrium. Specifically, we carried out a full stability analysis of intermetallic Heusler alloys made only of transition metals. Among the possible 36,540 prototypes, 248 were thermodynamically stable but only 20 were magnetic. The magnetic ordering temperature, T-C, was estimated by a regression calibrated on the experimental T-C of about 60 known compounds. As a final validation, we attempted the synthesis of a few of the predicted compounds and produced two new magnets: Co2MnTi, which displays a remarkably high T-C in perfect agreement with the predictions, and Mn2PtPd, which is an antiferromagnet. Our work paves the way for large-scale design of novel magnetic materials at potentially high speed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602241", "DOI": "10.1126/sciadv.1602241", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602241", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, W; Yoshii, T; Aziz, A; Tang, R; Pan, ZZ; Inoue, K; Kotani, M; Tanaka, H; Scholtzová, E; Tunega, D; Nishina, Y; Nishioka, K; Nakanishi, S; Zhou, Y; Terasaki, O; Nishihara, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Wei; Yoshii, Takeharu; Aziz, Alex; Tang, Rui; Pan, Zheng-Ze; Inoue, Kazutoshi; Kotani, Motoko; Tanaka, Hideki; Scholtzova, Eva; Tunega, Daniel; Nishina, Yuta; Nishioka, Kiho; Nakanishi, Shuji; Zhou, Yi; Terasaki, Osamu; Nishihara, Hirotomo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edge-Site-Free and Topological-Defect-Rich Carbon Cathode for High-Performance Lithium-Oxygen Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rational design of a stable and catalytic carbon cathode is crucial for the development of rechargeable lithium-oxygen (Li-O-2) batteries. An edge-site-free and topological-defect-rich graphene-based material is proposed as a pure carbon cathode that drastically improves Li-O-2 battery performance, even in the absence of extra catalysts and mediators. The proposed graphene-based material is synthesized using the advanced template technique coupled with high-temperature annealing at 1800 degrees C. The material possesses an edge-site-free framework and mesoporosity, which is crucial to achieve excellent electrochemical stability and an ultra-large capacity (>6700 mAh g(-1)). Moreover, both experimental and theoretical structural characterization demonstrates the presence of a significant number of topological defects, which are non-hexagonal carbon rings in the graphene framework. In situ isotopic electrochemical mass spectrometry and theoretical calculations reveal the unique catalysis of topological defects in the formation of amorphous Li2O2, which may be decomposed at low potential (similar to 3.6 V versus Li/Li+) and leads to improved cycle performance. Furthermore, a flexible electrode sheet that excludes organic binders exhibits an extremely long lifetime of up to 307 cycles (>1535 h), in the absence of solid or soluble catalysts. These findings may be used to design robust carbon cathodes for Li-O-2 batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 38, "Times Cited, All Databases": 38, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 10, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300268", "DOI Link": "http://dx.doi.org/10.1002/advs.202300268", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964136700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YR; Polski, R; Lewandowski, C; Thomson, A; Peng, Y; Choi, Y; Kim, H; Watanabe, K; Taniguchi, T; Alicea, J; von Oppen, F; Refael, G; Nadj-Perge, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yiran; Polski, Robert; Lewandowski, Cyprian; Thomson, Alex; Peng, Yang; Choi, Youngjoon; Kim, Hyunjin; Watanabe, Kenji; Taniguchi, Takashi; Alicea, Jason; von Oppen, Felix; Refael, Gil; Nadj-Perge, Stevan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promotion of superconductivity in magic-angle graphene multilayers", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene moire superlattices show an abundance of correlated insulating, topological, and superconducting phases. Whereas the origins of strong correlations and nontrivial topology can be directly linked to flat bands, the nature of superconductivity remains enigmatic. We demonstrate that magic-angle devices made of twisted tri-, quadri-, and pentalayer graphene placed on monolayer tungsten diselenide exhibit flavor polarization and superconductivity. We also observe insulating states in the tril- and quadrilayer arising at finite electric displacement fields. As the number of layers increases, superconductivity emerges over an enhanced filling-factor range, and in the pentalayer it extends well beyond the filling of four electrons per moire unit cell. Our results highlight the role of the interplay between flat and more dispersive bands in extending superconducting regions in graphene moire superlattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 377, "Issue": 6614, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1538, "End Page": 1543, "Article Number": null, "DOI": "10.1126/science.abn8585", "DOI Link": "http://dx.doi.org/10.1126/science.abn8585", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891713300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, R; Fang, ZR; Perez, C; Miller, F; Kumari, K; Saxena, A; Zheng, JJ; Geiger, SJ; Goodson, KE; Majumdar, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Rui; Fang, Zhuoran; Perez, Christopher; Miller, Forrest; Kumari, Khushboo; Saxena, Abhi; Zheng, Jiajiu; Geiger, Sarah J.; Goodson, Kenneth E.; Majumdar, Arka", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-volatile electrically programmable integrated photonics with a 5-bit operation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalable programmable photonic integrated circuits (PICs) can potentially transform the current state of classical and quantum optical information processing. However, traditional means of programming, including thermo-optic, free carrier dispersion, and Pockels effect result in either large device footprints or high static energy consumptions, significantly limiting their scalability. While chalcogenide-based non-volatile phase-change materials (PCMs) could mitigate these problems thanks to their strong index modulation and zero static power consumption, they often suffer from large absorptive loss, low cyclability, and lack of multilevel operation. Here, we report a wide -bandgap PCM antimony sulfide (Sb2S3)-clad silicon photonic platform simul-taneously achieving low loss (<1.0 dB), high extinction ratio (>10 dB), high cyclability (>1600 switching events), and 5-bit operation. These Sb2S3-based devices are programmed via on-chip silicon PIN diode heaters within sub-ms timescale, with a programming energy density of similar to 10 fJ=nm(3). Remarkably, Sb2S3 is programmed into fine intermediate states by applying multiple identical pulses, providing controllable multilevel operations. Through dynamic pulse control, we achieve 5-bit (32 levels) operations, rendering 0.50 +/- 0.16 dB per step. Using this multilevel behavior, we further trim random phase error in a balanced Mach-Zehnder interferometer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3465, "DOI": "10.1038/s41467-023-39180-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39180-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001007854800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paudel, S; Regmi, S; Janaswamy, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paudel, Sandeep; Regmi, Sumi; Janaswamy, Srinivas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of glycerol and sorbitol on cellulose-based biodegradable films", "Source Title": "FOOD PACKAGING AND SHELF LIFE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics with strong mechanical and barrier properties make them a dominullt packaging choice. Their lack of biodegradability, however, with a significant environmental threat, has driven the new generation of biode-gradable, renewable, and non-toxic packaging materials. Among several available choices, cellulose is highly suitable due to its strong and stiff molecular structure, biocompatibility, biodegradability, low toxicity, and abundance. However, cellulose-based films possess little flexibility and elongation. This study aims to understand the effect of plasticizers glycerol and sorbitol on cellulose film properties. Cellulose (0.6-0.8 g) was solubilized in 68%ZnCl2 solution and crosslinked with Ca2+ ions (50-400 mM) and plasticizer (5-25% of cellulose) to prepare films and characterized for physical and mechanical properties and soil biodegradability. Results reveal increased tensile strength and elongation at break with the plasticizer amount. The outcome is deemed to provide novel biodegradable packaging films based on cellulose and contribute to reducing plastic pollution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 37, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101090, "DOI": "10.1016/j.fpsl.2023.101090", "DOI Link": "http://dx.doi.org/10.1016/j.fpsl.2023.101090", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001007235700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ciftyurek, E; Li, ZS; Schierbaum, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ciftyurek, Engin; Li, Zheshen; Schierbaum, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorbed Oxygen Ions and Oxygen Vacancies: Their Concentration and Distribution in Metal Oxide Chemical Sensors and Influencing Role in Sensitivity and Sensing Mechanisms", "Source Title": "SENSORS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxidation reactions on semiconducting metal oxide (SMOs) surfaces have been extensively worked on in catalysis, fuel cells, and sensors. SMOs engage powerfully in energy-related applications such as batteries, supercapacitors, solid oxide fuel cells (SOFCs), and sensors. A deep understanding of SMO surface and oxygen interactions and defect engineering has become significant because all of the above-mentioned applications are based on the adsorption/absorption and consumption/transportation of adsorbed (physisorbed-chemisorbed) oxygen. More understanding of adsorbed oxygen and oxygen vacancies (V-O(center dot), V-O(center dot)center dot) is needed, as the former is the vital requirement for sensing chemical reactions, while the latter facilitates the replenishment of adsorbed oxygen ions on the surface. We determined the relation between sensor response (sensitivity) and the amounts of adsorbed oxygen ions (O-2(ads)(-), O-(ads)(-), O-2(ads)(2-), O2- ((ads))), water/hydroxide groups (H2O/OH-), oxygen vacancies (V-O(center dot), V-O(center dot)center dot ), and ordinary lattice oxygen ions (O2- (lattice)) as a function of temperature. During hydrogen (H-2) testing, the different oxidation states (W6+, W5+, and W4+) of WO3 were quantified and correlated with oxygen vacancy formation (V-O(center dot), V-O(center dot)center dot ). We used a combined application of XPS, UPS, XPEEM-LEEM, and chemical, electrical, and sensory analysis for H-2 sensing. The sensor response was extraordinarily high: 424 against H-2 at a temperature of 250 ?C was recorded and explained on the basis of defect engineering, including oxygen vacancies and chemisorbed oxygen ions and surface stoichiometry of WO3. We established a correlation between the H-2 sensing mechanism of WO3, sensor signal magnitude, the amount of adsorbed oxygen ions, and sensor testing temperature. This paper also provides a review of the detection, quantification, and identification of different adsorbed oxygen species. The different surface and bulk-sensitive characterization techniques relevant to analyzing the SMOs-based sensor are tabulated, providing the sensor designer with the chemical, physical, and electronic information extracted from each technique.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 23, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 29, "DOI": "10.3390/s23010029", "DOI Link": "http://dx.doi.org/10.3390/s23010029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918248900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suta, M; Meijerink, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suta, Markus; Meijerink, Andries", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Theoretical Framework for Ratiometric Single Ion Luminescent Thermometers-Thermodynamic and Kinetic Guidelines for Optimized Performance", "Source Title": "ADVANCED THEORY AND SIMULATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Luminescence (nullo)thermometry is an increasingly important field for remote temperature sensing with high spatial resolution. Most typically, ratiometric sensing of the luminescence emission intensities of two thermally coupled emissive states based on a Boltzmann equilibrium is used to detect the local temperature. Dependent on the temperature range and preferred spectral window, various choices for potential candidates appear possible. Despite extensive experimental research in the field, a universal theory covering the basics of luminescence thermometry is virtually nonexistent. In this manuscript, a general theoretical framework of single ion luminescent thermometers is presented that offers simple, user-friendly guidelines for both the choice of an appropriate emitter and respective embedding host material for optimum temperature sensing. The results show that the optimum performance (thermal response and sensitivity) aroundT(0)is realized for an energy gap increment E(21)between thermally coupled levels between 2k(B)T(0)and 3.41k(B)T(0). Analysis of the temperature-dependent excited state kinetics shows that host lattices in which increment E(21)can be bridged by one or two phonons are preferred over hosts in which higher order phonon processes are required. Such a framework is relevant for both a fundamental understanding of luminescent thermometers but also the targeted design of novel and superior luminescent (nullo)thermometers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000176, "DOI": "10.1002/adts.202000176", "DOI Link": "http://dx.doi.org/10.1002/adts.202000176", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000583969600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Díez-Mérida, J; Díez-Carlón, A; Yang, SY; Xie, YM; Gao, XJ; Senior, J; Watanabe, K; Taniguchi, T; Lu, X; Higginbotham, AP; Law, KT; Efetov, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Diez-Merida, J.; Diez-Carlon, A.; Yang, S. Y.; Xie, Y. -M.; Gao, X. -J.; Senior, J.; Watanabe, K.; Taniguchi, T.; Lu, X.; Higginbotham, A. P.; Law, K. T.; Efetov, Dmitri K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Symmetry-broken Josephson junctions and superconducting diodes in magic-angle twisted bilayer graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Correlated electronic states in moire matter are of great fundamental and technological interest. Here, the authors demonstrate a Josephson junction in magic-angle twisted bilayer graphene with a correlated insulator weak link, showing magnetism and programmable superconducting diode behaviour. The coexistence of gate-tunable superconducting, magnetic and topological orders in magic-angle twisted bilayer graphene provides opportunities for the creation of hybrid Josephson junctions. Here we report the fabrication of gate-defined symmetry-broken Josephson junctions in magic-angle twisted bilayer graphene, where the weak link is gate-tuned close to the correlated insulator state with a moire filling factor of upsilon = -2. We observe a phase-shifted and asymmetric Fraunhofer pattern with a pronounced magnetic hysteresis. Our theoretical calculations of the junction weak link-with valley polarization and orbital magnetization-explain most of these unconventional features. The effects persist up to the critical temperature of 3.5 K, with magnetic hysteresis observed below 800 mK. We show how the combination of magnetization and its current-induced magnetization switching allows us to realise a programmable zero-field superconducting diode. Our results represent a major advance towards the creation of future superconducting quantum electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2396, "DOI": "10.1038/s41467-023-38005-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38005-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000979744000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nunna, S; Creighton, C; Hameed, N; Naebe, M; Henderson, LC; Setty, M; Fox, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nunna, Srinivas; Creighton, Claudia; Hameed, Nishar; Naebe, Minoo; Henderson, Luke C.; Setty, Mohan; Fox, Bronwyn L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Radial structure and property relationship in the thermal stabilization of PAN precursor fibres", "Source Title": "POLYMER TESTING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we report on the role of oxygen in the evolution of radial heterogeneity in the fibre structure and properties of PAN fibres stabilized in air and vacuum at different temperatures. Modulus mapping by nullo-indentation showed heterogeneous modulus distribution in the fibres treated in air, while no variation in modulus was observed in fibres processed in vacuum. Raman spectroscopy and elemental analysis revealed that the temperature dependent oxygen diffusion from skin to core of the fibres assisted in the evolution of higher extent of sp(2)-hybridized carbons in the skin compared to core of the air treated samples. Conversely, no radial structure variations were observed in the vacuum treated fibres. Higher modulus in the skin of air-treated fibres was due to the formation of compact structures which was associated with the enhanced intermolecular interactions facilitated by the formation of C=C bonds within the polymer backbone, promoted by oxidative-dehydrogenation reaction. Supporting these observations, the fracture morphology examined by SEM showed a brittle fracture in the skin and ductile fracture in the core. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 427, "Times Cited, All Databases": 477, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 59, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 203, "End Page": 211, "Article Number": null, "DOI": "10.1016/j.polymertesting.2017.02.006", "DOI Link": "http://dx.doi.org/10.1016/j.polymertesting.2017.02.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400199700026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mbarki, F; Selmi, T; Kesraoui, A; Seffen, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mbarki, Fatma; Selmi, Taher; Kesraoui, Aida; Seffen, Mongi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-cost activated carbon preparation from Corn stigmata fibers chemically activated using H3PO4, ZnCl2 and KOH: Study of methylene blue adsorption, stochastic isotherm and fractal kinetic", "Source Title": "INDUSTRIAL CROPS AND PRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this study was to produce a low-cost activated carbon (AC) from an inexpensive precursor material, corn stigmata (CS), by chemical activation at low temperatures using H3PO4, ZnCl2 and KOH. The results were showed that activation with phosphoric acid provides an adsorbent with a larger specific surface area (S-BET) and high pore size. Textural and physicochemical properties of ACs activated with H3PO4 were then studied in different activation temperature. The increase of activation temperature from 200 degrees to 500 degrees C allows the development of many surface functions and the development of a mixture of meso and microporosity, so the S-BET increase from 0.25 to 820 m(2)/g. The physicochemical and textural properties of ACs were analyzed by N-2 adsorption-desorption, FTIR, Boehm's titration, point of zero charge (pH(PZC)), SEM and EDX. The kinetics and isotherm of methylene blue (MB) adsorption were well described by BSf and GBS models indicating the stochastic and fractal adsorption process and a highly heterogeneous AC surface. The maximum adsorption capacity toward MB, 330.5 mg/g, was high compared to many other results found in literature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 178, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114546, "DOI": "10.1016/j.indcrop.2022.114546", "DOI Link": "http://dx.doi.org/10.1016/j.indcrop.2022.114546", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779420500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jewett, AI; Stelter, D; Lambert, J; Saladi, SM; Roscioni, OM; Ricci, M; Autin, L; Maritan, M; Bashusqeh, SM; Keyes, T; Dame, RT; Shea, JE; Jensen, GJ; Goodsell, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jewett, Andrew, I; Stelter, David; Lambert, Jason; Saladi, Shyam M.; Roscioni, Otello M.; Ricci, Matteo; Autin, Ludovic; Maritan, Martina; Bashusqeh, Saeed M.; Keyes, Tom; Dame, Remus T.; Shea, Joan-Emma; Jensen, Grant J.; Goodsell, David S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Moltemplate: A Tool for Coarse-Grained Modeling of Complex Biological Matter and Soft Condensed Matter Physics", "Source Title": "JOURNAL OF MOLECULAR BIOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coarse-grained models have long been considered indispensable tools in the investigation of biomolecular dynamics and assembly. However, the process of simulating such models is arduous because unconventional force fields and particle attributes are often needed, and some systems are not in thermal equilibrium. Although modern molecular dynamics programs are highly adaptable, software designed for preparing all-atom simulations typically makes restrictive assumptions about the nature of the particles and the forces acting on them. Consequently, the use of coarse-grained models has remained challenging. Moltemplate is a file format for storing coarse-grained molecular models and the forces that act on them, as well as a program that converts moltemplate files into input files for LAMMPS, a popular molecular dynamics engine. Moltemplate has broad scope and an emphasis on generality. It accommodates new kinds of forces as they are developed for LAMMPS, making moltemplate a popular tool with thousands of users in computational chemistry, materials science, and structural biology. To demonstrate its wide functionality, we provide examples of using moltemplate to prepare simulations of fluids using many-body forces, coarse-grained organic semiconductors, and the motor-driven supercoiling and condensation of an entire bacterial chromosome. (C) 2021 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 314, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 28", "Publication Year": 2021, "Volume": 433, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 166841, "DOI": "10.1016/j.jmb.2021.166841", "DOI Link": "http://dx.doi.org/10.1016/j.jmb.2021.166841", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648520800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choudhary, K; Kalish, I; Beams, R; Tavazza, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choudhary, Kamal; Kalish, Irina; Beams, Ryan; Tavazza, Francesca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput Identification and Characterization of Two-dimensional Materials using Density functional theory", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce a simple criterion to identify two-dimensional (2D) materials based on the comparison between experimental lattice constants and lattice constants mainly obtained from Materials-Project (MP) density functional theory (DFT) calculation repository. Specifically, if the relative difference between the two lattice constants for a specific material is greater than or equal to 5%, we predict them to be good candidates for 2D materials. We have predicted at least 1356 such 2D materials. For all the systems satisfying our criterion, we manually create single layer systems and calculate their energetics, structural, electronic, and elastic properties for both the bulk and the single layer cases. Currently the database consists of 1012 bulk and 430 single layer materials, of which 371 systems are common to bulk and single layer. The rest of calculations are underway. To validate our criterion, we calculated the exfoliation energy of the suggested layered materials, and we found that in 88.9% of the cases the currently accepted criterion for exfoliation was satisfied. Also, using molybdenum telluride as a test case, we performed X-ray diffraction and Raman scattering experiments to benchmark our calculations and understand their applicability and limitations. The data is publicly available at the website http://www. ctcms.nist.gov/similar to knc6/JVASP.html.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 12", "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5179, "DOI": "10.1038/s41598-017-05402-0", "DOI Link": "http://dx.doi.org/10.1038/s41598-017-05402-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405421400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bampoulis, P; Castenmiller, C; Klaassen, DJ; van Mil, J; Liu, YC; Liu, CC; Yao, YG; Ezawa, M; Rudenko, AN; Zandvliet, HJW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bampoulis, Pantelis; Castenmiller, Carolien; Klaassen, Dennis J.; van Mil, Jelle; Liu, Yichen; Liu, Cheng-Cheng; Yao, Yugui; Ezawa, Motohiko; Rudenko, Alexander N.; Zandvliet, Harold J. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum Spin Hall States and Topological Phase Transition in Germanene", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the first experimental evidence of a topological phase transition in a monoelemental quantum spin Hall insulator. Particularly, we show that low-buckled epitaxial germanene is a quantum spin Hall insulator with a large bulk gap and robust metallic edges. Applying a critical perpendicular electric field closes the topological gap and makes germanene a Dirac semimetal. Increasing the electric field further results in the opening of a trivial gap and disappearance of the metallic edge states. This electric field -induced switching of the topological state and the sizable gap make germanene suitable for room -temperature topological field-effect transistors, which could revolutionize low-energy electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2023, "Volume": 130, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 196401, "DOI": "10.1103/PhysRevLett.130.196401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.130.196401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000996379400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lian, WT; Cao, R; Li, G; Cai, HL; Cai, ZY; Tang, RF; Zhu, CF; Yang, SF; Chen, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lian, Weitao; Cao, Rui; Li, Gang; Cai, Huiling; Cai, Zhiyuan; Tang, Rongfeng; Zhu, Changfei; Yang, Shangfeng; Chen, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Distinctive Deep-Level Defects in Non-Stoichiometric Sb2Se3 Photovoltaic Materials", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Characterizing defect levels and identifying the compositional elements in semiconducting materials are important research subject for understanding the mechanism of photogenerated carrier recombination and reducing energy loss during solar energy conversion. Here it shows that deep-level defect in antimony triselenide (Sb2Se3) is sensitively dependent on the stoichiometry. For the first time it experimentally observes the formation of amphoteric Sb-Se defect in Sb-rich Sb2Se3. This amphoteric defect possesses equivalent capability of trapping electron and hole, which plays critical role in charge recombination and device performance. In comparative investigation, it also uncovers the reason why Se-rich Sb2Se3 is able to deliver high device performance from the defect formation perspective. This study demonstrates the crucial defect types in Sb2Se3 and provides a guidance toward the fabrication of efficient Sb2Se3 photovoltaic device and relevant optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2105268, "DOI": "10.1002/advs.202105268", "DOI Link": "http://dx.doi.org/10.1002/advs.202105268", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746627400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gottscholl, A; Diez, M; Soltamov, V; Kasper, C; Sperlich, A; Kianinia, M; Bradac, C; Aharonovich, I; Dyakonov, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gottscholl, Andreas; Diez, Matthias; Soltamov, Victor; Kasper, Christian; Sperlich, Andreas; Kianinia, Mehran; Bradac, Carlo; Aharonovich, Igor; Dyakonov, Vladimir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room temperature coherent control of spin defects in hexagonal boron nitride", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optically active spin defects are promising candidates for solid-state quantum information and sensing applications. To use these defects in quantum applications coherent manipulation of their spin state is required. Here, we realize coherent control of ensembles of boron vacancy centers in hexagonal boron nitride (hBN). Specifically, by applying pulsed spin resonullce protocols, we measure a spin-lattice relaxation time of 18 microseconds and a spin coherence time of 2 microseconds at room temperature. The spin-lattice relaxation time increases by three orders of magnitude at cryogenic temperature. By applying a method to decouple the spin state from its inhomogeneous nuclear environment the optically detected magnetic resonullce linewidth is substantially reduced to several tens of kilohertz. Our results are important for the employment of van der Waals materials for quantum technologies, specifically in the context of high resolution quantum sensing of two-dimensional heterostructures, nulloscale devices, and emerging atomically thin magnets.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 7, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabf3630", "DOI": "10.1126/sciadv.abf3630", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abf3630", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636455600029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Harja, M; Buema, G; Bucur, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Harja, Maria; Buema, Gabriela; Bucur, Daniel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent advances in removal of Congo Red dye by adsorption using an industrial waste", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Congo Red dye was removed from a simulated textile wastewater solution using fly ash from a local power plant. The characterisation of fly ash was studied in detail by SEM, EDX, XRD, FTIR, BET surface area and TGA techniques. The influence of four parameters (contact time, initial concentration, adsorbent dose, and temperature) was analysed, the results showing that the adsorption capacity depends on these parameters. Thermodynamic and regeneration investigations as well are presented. The fit to pseudo-second-order kinetics models suggests that the removal process is a chemical adsorption. The Langmuir model fitted the experimental data, with a maximum adsorption capacity of 22.12 mg/g. The research is a preliminary case study that highlights that fly ash posed a very good potential as a material for Congo Red dye removal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6087, "DOI": "10.1038/s41598-022-10093-3", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-10093-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000782202600073", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, K; Liu, CL; Sun, JR; Zhao, K; Wang, LC; Song, JY; Duan, CX; Li, LW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Kai; Liu, Chunli; Sun, Jianrui; Zhao, Kun; Wang, Licheng; Song, Jinyan; Duan, Chongxiong; Li, Liwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "State of Charge Estimation of Composite Energy Storage Systems with Supercapacitors and Lithium Batteries", "Source Title": "COMPLEXITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper studies the state of charge (SOC) estimation of supercapacitors and lithium batteries in the hybrid energy storage system of electric vehicles. According to the energy storage principle of the electric vehicle composite energy storage system, the circuit models of supercapacitors and lithium batteries were established, respectively, and the model parameters were identified online using the recursive least square (RLS) method and Kalman filtering (KF) algorithm. Then, the online estimation of SOC was completed based on the Kalman filtering algorithm and unscented Kalman filtering algorithm. Finally, the experimental platform for SOC estimation was built and Matlab was used for calculation and analysis. The experimental results showed that the SOC estimation results reached a high accuracy, and the variation range of estimation error was [-0.94%, 0.34%]. For lithium batteries, the recursive least square method is combined with the 2RC model to obtain the optimal result, and the estimation error is within the range of [-1.16%, 0.85%] in the case of comprehensive weighing accuracy and calculation amount. Moreover, the system has excellent robustness and high reliability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2021, "Volume": 2021, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8816250, "DOI": "10.1155/2021/8816250", "DOI Link": "http://dx.doi.org/10.1155/2021/8816250", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625327500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gorji, MB; Mozaffar, M; Heidenreich, JN; Cao, J; Mohr, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gorji, Maysam B.; Mozaffar, Mojtaba; Heidenreich, Julian N.; Cao, Jian; Mohr, Dirk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the potential of recurrent neural networks for modeling path dependent plasticity", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mathematical description of elastoplasticity is a highly complex problem due to the possible change from elastic to elasto-plastic behavior (and vice-versa) as a function of the loading path. Advanced physics-based plasticity models usually feature numerous internal variables (often of tensorial nature) along with a set of evolution equations and complementary conditions. In the present work, an attempt is made to come up with a machine-learning based model that can replicate the predictions anisotropic Yld2000-2d model with homogeneous anisotropic hardening (HAH). For this, a series of modeling problems of increasing complexity is formulated and sequentially addressed using neural network models. It is demonstrated that basic fully-connected neural network models can capture the characteristic non-linearities in the uniaxial stress-strain response such as the Bauschinger effect, permanent softening or latent hardening. A neural network with gated recurrent units (GRUs) and fully-connected layer is proposed for the modeling of plane stress plasticity for arbitrary loading paths. After training and testing the model through comparison with the Yld200 0-2d/HAH model, the recurrent neural network model is also used to model the multi-axial stress-strain response of a two-dimensional foam. Here, the comparison with the results from unit cell simulations provided another validation of the proposed data-driven modeling approach. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 143, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103972, "DOI": "10.1016/j.jmps.2020.103972", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2020.103972", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000590251200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hemdan, BA; El-Taweel, GE; Naha, S; Goswami, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hemdan, Bahaa A.; El-Taweel, Gamila E.; Naha, Sunulldan; Goswami, Pranab", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bacterial community structure of electrogenic biofilm developed on modified graphite anode in microbial fuel cell", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Formation of electrogenic microbial biofilm on the electrode is critical for harvesting electrical power from wastewater in microbial biofuel cells (MFCs). Although the knowledge of bacterial community structures in the biofilm is vital for the rational design of MFC electrodes, an in-depth study on the subject is still awaiting. Herein, we attempt to address this issue by creating electrogenic biofilm on modified graphite anodes assembled in an air-cathode MFC. The modification was performed with reduced graphene oxide (rGO), polyaniline (PANI), and carbon nullotube (CNTs) separately. To accelerate the growth of the biofilm, soybean-potato composite (plant) powder was blended with these conductive materials during the fabrication of the anodes. The MFC fabricated with PANI-based anode delivered the current density of 324.2 mA cm(-2), followed by CNTs (248.75 mA cm(-2)), rGO (193 mA cm(-2)), and blank (without coating) (151 mA cm(-2)) graphite electrodes. Likewise, the PANI-based anode supported a robust biofilm growth containing maximum bacterial cell densities with diverse shapes and sizes of the cells and broad metabolic functionality. The alpha diversity of the biofilm developed over the anode coated with PANI was the loftiest operational taxonomic unit (2058 OUT) and Shannon index (7.56), as disclosed from the high-throughput 16S rRNA sequence analysis. Further, within these taxonomic units, exoelectrogenic phyla comprising Proteobacteria, Firmicutes, and Bacteroidetes were maximum with their corresponding level (%) 45.5, 36.2, and 9.8. The relative abundance of Gammaproteobacteria, Clostridia, and Bacilli at the class level, while Pseudomonas, Clostridium, Enterococcus, and Bifidobacterium at the genus level were comparatively higher in the PANI-based anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2023, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41598-023-27795-x", "DOI Link": "http://dx.doi.org/10.1038/s41598-023-27795-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954571900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Long, X; Mao, MH; Su, TX; Su, YT; Tian, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Long, Xu; Mao, Ming-hui; Su, Tian-xiong; Su, Yu-tai; Tian, Meng-ke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning method to predict dynamic compressive response of concrete-like material at high strain rates", "Source Title": "DEFENCE TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning (ML) methods with good applicability to complex and highly nonlinear sequences have been attracting much attention in recent years for predictions of complicated mechanical properties of various materials. As one of the widely known ML methods, back-propagation (BP) neural networks with and without optimization by genetic algorithm (GA) are also established for comparisons of time cost and prediction error. With the aim to further increase the prediction accuracy and efficiency, this paper proposes a long short-term memory (LSTM) networks model to predict the dynamic compressive per-formance of concrete-like materials at high strain rates. Dynamic explicit analysis is performed in the finite element (FE) software ABAQUS to simulate various waveforms in the split Hopkinson pressure bar (SHPB) experiments by applying different stress waves in the incident bar. The FE simulation accuracy is validated against SHPB experimental results from the viewpoint of dynamic increase factor. In order to cover more extensive loading scenarios, 60 sets of FE simulations are conducted in this paper to generate three kinds of waveforms in the incident and transmission bars of SHPB experiments. By training the proposed three networks, the nonlinear mapping relations can be reasonably established between incident, reflect, and transmission waves. Statistical measures are used to quantify the network pre-diction accuracy, confirming that the predicted stress-strain curves of concrete-like materials at high strain rates by the proposed networks agree sufficiently with those by FE simulations. It is found that compared with BP network, the GA-BP network can effectively stabilize the network structure, indicating that the GA optimization improves the prediction accuracy of the SHPB dynamic responses by per-forming the crossover and mutation operations of weights and thresholds in the original BP network. By eliminating the long-time dependencies, the proposed LSTM network achieves better results than the BP and GA-BP networks, since smaller mean square error (MSE) and higher correlation coefficient are achieved. More importantly, the proposed LSTM algorithm, after the training process with a limited number of FE simulations, could replace the time-consuming and laborious FE pre-and post-processing and modelling.(c) 2022 China Ordnullce Society. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/ 4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 77, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 23, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 100, "End Page": 111, "Article Number": null, "DOI": "10.1016/j.dt.2022.02.003", "DOI Link": "http://dx.doi.org/10.1016/j.dt.2022.02.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994781600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Song, XF; Yang, HM; Wang, L; Tang, SW; Wu, B; Mao, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Song, Xuefeng; Yang, Huamei; Wang, Lei; Tang, Shengwen; Wu, Bo; Mao, Wenting", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pore Structural and Fractal Analysis of the Effects of MgO Reactivity and Dosage on Permeability and F-T Resistance of Concrete", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Currently, the MgO expansion agent is widely used to reduce the cracking risk of concrete. The influence of MgO reactivity (50 s and 300 s) and dosage (0, 4 wt.% and 8 wt.%, by weight of binder) on the air void, pore structure, permeability and freezing-thawing (F-T) resistance of concrete were studied. The results indicate (1) the addition of 4-8 wt.% reactive MgO (with reactivity of 50 s and termed as M50 thereafter) and weak reactive MgO (with reactivity of 300 s and termed M300 thereafter) lowers the concrete's compressive strength by 4.4-17.2%, 3.9-16.4% and 1.9-14.6% at 3, 28 and 180 days, respectively. The increase in MgO dosage and reactivity tends to further reduce the concrete strength at all hydration ages. (2) Permeability of the concrete is closely related to the pore structure. M50 can densify the pore structure and lower the fraction of large capillary pores at an early age, thus it is beneficial for the impermeability of concrete. In contrast, M300 can enhance the 180-day impermeability of concrete since it can densify the pore structure only at a late age. (3) The influence of MgO on F-T resistance is minor since MgO could not change the air void parameters. (5) MgO concretes exhibit obvious fractal characteristics. The fractal dimension of the pore surface (D-s) exhibits a close relationship with the permeability property of concrete. However, no correlation can be found between F-T resistance and D-s.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113, "DOI": "10.3390/fractalfract6020113", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6020113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000763056400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Allaire, G; Geoffroy-Donders, P; Pantz, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Allaire, Gregoire; Geoffroy-Donders, Perle; Pantz, Olivier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topology optimization of modulated and oriented periodic microstructures by the homogenization method", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper is concerned with the topology optimization of structures made of periodically perforated material, where the microscopic periodic cell can be macroscopically modulated and oriented. The main idea is to optimize the homogenized formulation of this problem, which is an easy task of parametric optimization, then to project the optimal microstructure at a desired lengthscale, which is a delicate issue, albeit computationally cheap. The main novelty of our work is, in a plane setting, the conformal treatment of the optimal orientation of the microstructure. In other words, although the periodicity cell has varying parameters and orientation throughout the computational domain, the angles between its members or bars are conserved. The main application of our work is the optimization of so-called lattice materials which are becoming increasingly popular in the context of additive manufacturing. Several numerical examples are presented for compliance minimization in 2-d. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 78, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 2197, "End Page": 2229, "Article Number": null, "DOI": "10.1016/j.camwa.2018.08.007", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2018.08.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488144700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carr, S; Massatt, D; Torrisi, SB; Cazeaux, P; Luskin, M; Kaxiras, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carr, Stephen; Massatt, Daniel; Torrisi, Steven B.; Cazeaux, Paul; Luskin, Mitchell; Kaxiras, Efthimios", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Relaxation and domain formation in incommensurate two-dimensional heterostructures", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce configuration space as a natural representation for calculating the mechanical relaxation patterns of incommensurate two-dimensional (2D) bilayers. The approach can be applied to a wide variety of 2D materials through the use of a continuum model in combination with a generalized stacking fault energy for interlayer interactions. We present computational results for small-angle twisted bilayer graphene and molybdenum disulfide (MoS2), a representative material of the transition-metal dichalcogenide family of 2D semiconductors. We calculate accurate relaxations for MoS2 even at small twist-angle values, enabled by the fact that our approach does not rely on empirical atomistic potentials for interlayer coupling. The results demonstrate the efficiency of the configuration space method by computing relaxations with minimal computational cost. We also outline a general explanation of domain formation in 2D bilayers with nearly aligned lattices, taking advantage of the relationship between real space and configuration space. The configuration space approach also enables calculation of relaxations in incommensurate multilayer systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 227, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2018, "Volume": 98, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 224102, "DOI": "10.1103/PhysRevB.98.224102", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.98.224102", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452322000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, JJ; Dang, ZY; Muddassir, M; Raza, S; Zhong, AG; Wang, XX; Jin, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Juanjuan; Dang, Zhuoyu; Muddassir, Mohd.; Raza, Saleem; Zhong, Aiguo; Wang, Xiaoxiong; Jin, Juncheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Cd(II)-Based Coordination Polymer for Efficient Photocatalytic Removal of Organic Dyes", "Source Title": "MOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Coordination polymers (CPs) are a diverse class of multi-dimensional compounds that show promise as photocatalysts for degrading dyes in polluted water. Herein, a new 1D Cd(II)-based coordination polymer with the formula [Cd(bpyp)(nba)2] (1) (bpyp = 2,5-bis(pyrid-4-yl)pyridine and Hnba = 4-nitrobenzoic acid) is synthesized and characterized. In 1, the two carboxyl groups of two different nba- ligands show mu 2-eta 1:eta 1 and mu 1-eta 1:eta 1 coordination modes to connect the CdII centers and sit on either side of the chain along the b direction. The produced CP 1 was utilized as the photocatalyst in the process of the photodegradation of methyl blue (MB), methyl orange (MO), rhodamine B (RhB), and methyl violet (MV) dyes when exposed to UV light. The photocatalytic degradation activities of CP 1 were analyzed, and the results suggest that it exhibits an extraordinary efficiency in the degradation of MB, MV, MO, and RhB. RhB has a 95.52% efficiency of degradation, whereas MV has a 58.92% efficiency, MO has 35.44%, and MB has 29.24%. The photodecomposition of dyes is catalyzed mostly by center dot O2- and center dot OH-, as shown by research involving the trapping of radicals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 28, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6848, "DOI": "10.3390/molecules28196848", "DOI Link": "http://dx.doi.org/10.3390/molecules28196848", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001083019000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bedford, JD; Faulkner, DR; Lapusta, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bedford, John D.; Faulkner, Daniel R.; Lapusta, Nadia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fault rock heterogeneity can produce fault weakness and reduce fault stability", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper shows that faults comprised of heterogeneously distributed materials, as is typical for tectonic faults in nature, are weaker and more unstable than equivalent faults where the materials are homogeneously mixed together. Geological heterogeneity is abundant in crustal fault zones; however, its role in controlling the mechanical behaviour of faults is poorly constrained. Here, we present laboratory friction experiments on laterally heterogeneous faults, with patches of strong, rate-weakening quartz gouge and weak, rate-strengthening clay gouge. The experiments show that the heterogeneity leads to a significant reduction in strength and frictional stability in comparison to compositionally identical faults with homogeneously mixed gouges. We identify a combination of weakening effects, including smearing of the weak clay; differential compaction of the two gouges redistributing normal stress; and shear localization producing stress concentrations in the strong quartz patches. The results demonstrate that geological heterogeneity and its evolution can have pronounced effects on fault strength and stability and, by extension, on the occurrence of slow-slip transients versus earthquake ruptures and the characteristics of the resulting events, and should be further studied in lab experiments and earthquake source modelling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 326, "DOI": "10.1038/s41467-022-27998-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-27998-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744540800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pyzer-Knapp, EO; Pitera, JW; Staar, PWJ; Takeda, S; Laino, T; Sanders, DP; Sexton, J; Smith, JR; Curioni, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pyzer-Knapp, Edward O.; Pitera, Jed W.; Staar, Peter W. J.; Takeda, Seiji; Laino, Teodoro; Sanders, Daniel P.; Sexton, James; Smith, John R.; Curioni, Alessandro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerating materials discovery using artificial intelligence, high performance computing and robotics", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New tools enable new ways of working, and materials science is no exception. In materials discovery, traditional manual, serial, and human-intensive work is being augmented by automated, parallel, and iterative processes driven by Artificial Intelligence (AI), simulation and experimental automation. In this perspective, we describe how these new capabilities enable the acceleration and enrichment of each stage of the discovery cycle. We show, using the example of the development of a novel chemically amplified photoresist, how these technologies' impacts are amplified when they are used in concert with each other as powerful, heterogeneous workflows.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 84, "DOI": "10.1038/s41524-022-00765-z", "DOI Link": "http://dx.doi.org/10.1038/s41524-022-00765-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787774800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Iasiello, M; Mameli, M; Filippeschi, S; Bianco, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Iasiello, Marcello; Mameli, Mauro; Filippeschi, Sauro; Bianco, Nicola", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal foam/PCM melting evolution analysis: Orientation and morphology effects", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase Change Materials (PCM) are promising materials for thermal energy storage systems. Since they present a relatively low thermal conductivity, they are often embedded in an open cell a metallic foam to enhance the overall thermal conductivity. In this paper, both experimental and numerical results on PCMs coupled with aluminum foams under different heat fluxes, porosities, number of Pores Per Inch (PPIs) and orientation are presented. The test cell is equipped with a Zincum Selenide window that allows to capture the whole temperature distribution by means of a IR camera. The melting front position in time is tracked by means of a MATLAB (R) algorithm based on IR camera images that are useful for a more robust tracking of melting front. Numerical simulations are performed with references to the porous media volume-averaged approach, under the assumption of local thermal non-equilibrium between the two phases. The most updated correlations for the porous media closing coefficients are taken from the literature. All the experiments are compared with numerical simulations, showing a very good agreement. After showing the effects of the different input parameters on melting front evolution, an analysis in terms of different convective heat losses to the environment and melting temperature range is presented to appreciate how these two variables affect the melting front position. Finally, total melting front evolution has been compared between experiments and simulations, showing a good agreement. This has been evaluated for different conditions, showing that a decrease in the porosity drastically reduces the melting time, while PPI has no relevant effect and small effects can be observed from orientation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2021, "Volume": 187, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116572, "DOI": "10.1016/j.applthermaleng.2021.116572", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2021.116572", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000635626600027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Golewski, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Golewski, Grzegorz Ludwik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combined Effect of Coal Fly Ash (CFA) and nullosilica (nS) on the Strength Parameters and Microstructural Properties of Eco-Friendly Concrete", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Disposal of the coal fly ash (CFA) generated from thermal power plants in huge quantities is one of the major concerns for the industry, as well as the natural environment. On the other hand, CFA can be used within a certain percentage range in the cement concrete mix as a replacement for cement. nullomaterials can also be used to improve the properties of concrete. Therefore, this study investigated the effects of nullosilica (nS) on the mechanical parameters and microstructure of CFA cement concretes. This study utilized an nS content of 5%, along with three CFA contents, i.e., of 0, 15, and 25% by volume. Mechanical property tests and a thorough overview of changes in the structure of modified concrete were carried out to study the effect of the CFA content on the analyzed parameters of concrete containing nS. This study had the goal of elucidating the reinforcing mechanisms of CFA concrete by nS and providing design guidance for the practical engineering applications of CFA-nS composites. Based on the conducted studies, it was found that the combined usage of nS and CFA has synergistic and positive effects on improving mechanical parameters and microstructure in such concretes. The combined strengthening of a cement matrix by nS and CFA can fill the pores and microcracks in concrete composites and effectively improve the mechanical properties and microstructure of such materials. In this study, the optimal improvement was achieved when the concentration of additions was 5% nS and 15% CFA. The 28-day compressive strength and splitting tensile strength were increased by 37.68 and 36.21%, respectively, in comparison to control concrete. Tailored blended cements composed of nS and CFA content (up to 30% replacement level) can significantly improve the parameters of concrete composites, as well as reduce the carbon footprint of cement-based materials-constituting a step toward the production of eco-friendly concretes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 92, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 16, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 452, "DOI": "10.3390/en16010452", "DOI Link": "http://dx.doi.org/10.3390/en16010452", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000908832200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, Z; Xiao, H; Wang, YL; Zhao, ZP; Lin, ZY; Cheng, HC; Lee, SJ; Wang, GM; Feng, ZY; Goddard, WA ; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Zheng; Xiao, Hai; Wang, Yiliu; Zhao, Zipeng; Lin, Zhaoyang; Cheng, Hung-Chieh; Lee, Sung-Joon; Wang, Gongming; Feng, Ziying; Goddard, William A., III; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-by-Layer Degradation of Methylammonium Lead Tri-iodide Perovskite Microplates", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The methylammonium lead iodide (MAPbI(3)) perovskite has attracted considerable interest for its high-efficiency, low-cost solar cells, but is currently plagued by its poor environmental and thermal stability. To aid the development of robust devices, we investigate here the microscopic degradation pathways of MAPbI(3) microplates. Using in situ transmission electron microscopy to follow the thermal degradation process, we find that under moderate heating at 85 degrees C the crystalline structure shows a gradual evolution from tetragonal MAPbI(3) to trigonal lead iodide layered crystals with a fixed crystallographic direction. Our solid-state nudged elastic band calculations confirm that the surface-initiated layer-by-layer degradation path exhibits the lowest energy barrier for crystal transition. We further show experimentally and theoretically that encapsulation of the perovskites with boron nitride flakes suppresses the surface degradation, greatly improving its thermal stability. These studies provide mechanistic insight into the thermal stability of perovskites that suggests new designs for improved stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 223, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2017, "Volume": 1, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 548, "End Page": 562, "Article Number": null, "DOI": "10.1016/j.joule.2017.08.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2017.08.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425301500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, J; Kwon, J; Im, D; Ko, J; Nam, CY; Yang, HG; Shin, SH; Hong, SM; Hwang, SS; Yoon, HG; Lee, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Junpyo; Kwon, Jisung; Im, Dohyun; Ko, Jeonggil; Nam, Chae Yun; Yang, Hyeong Gyu; Shin, Sun Ho; Hong, Soon Man; Hwang, Seung Sang; Yoon, Ho Gyu; Lee, Albert S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Best practices for correlating electrical conductivity with broadband EMI shielding in binary filler-based conducting polymer composites", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiple conductive fillers (MWCNT, GNP, Cu@Ag dendrite, EGain) were incorporated in a commercial poly-propylene matrix through melt processing. Electrical conductivity, thermal conductivity, and EMI shielding properties of the fabricated composites were examined according to various filler compositions, and it was confirmed that the properties varied according to shape, composition, and mutual compatibility of the partic-ulate fillers. In particular, at broadband frequencies (X-, Ka-, W-band), the EMI shielding properties reached 32.6 dB (at 10 GHz), 39.3 dB (at 28 GHz), 51.1 dB (at 77 GHz) for composites comprising of PC15 (0.3 mm) and the EMI shielding mechanisms according to the material thickness (0.3, 0.5, 1 mm) and the filler content were studied. As the frequency increased from 8.2-110 GHz, the reflection properties decreased from 90.93 % to 80.99 % (at 0.3 mm), and the absorption properties increased 9.01 % to 19.01 % even for PC15 (0.3 mm). In particular, the correlation between the type of electrical conductivity and the EMI shielding properties were investigated using a theoretical (Simon, Drude) model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2023, "Volume": 455, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 140528, "DOI": "10.1016/j.cej.2022.140528", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2022.140528", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931015400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amin, M; Agwa, IS; Mashaan, N; Mahmood, S; Abd-Elrahman, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amin, Mohamed; Agwa, Ibrahim Saad; Mashaan, Nuha; Mahmood, Shaker; Abd-Elrahman, Mahmoud H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation of the Physical Mechanical Properties and Durability of Sustainable Ultra-High Performance Concrete with Recycled Waste Glass", "Source Title": "SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction material sustainability and waste reuse have emerged as significant environmental issues. Concrete is widely used in the building and engineering fields. Ultra-high performance concrete (UHPC), which has remarkably high mechanical properties, has become one of the most common concrete varieties in recent years. As a result, substantial amounts of Portland cement (PC) are frequently used, raising the initial cost of UHPC and restricting its broad use in structural applications. A significant amount of CO2 is produced and a large amount of natural resources are consumed in its production. To make UHPC production more eco-friendly and economically viable, it is advised that the PC in concrete preparations be replaced with different additives and that the recycled aggregates from various sources be substituted for natural aggregates. This research aims to develop an environmentally friendly and cost-effective UHPC by using glass waste (GW) of various sizes as an alternative to PC with replacement ratios of 0%, 10%, 20%, 30%, 40%, and 50% utilizing glass powder (GP). Fine aggregate sand (S) is also replaced by glass particles (G) with replacement ratios of 0%, 50%, and 100%. To accomplish this, 18 mixes, separated into three groups, are made and examined experimentally. Slump flow, mechanical properties, water permeability, and microstructural characteristics are all studied. According to the results, increasing the S replacement ratio with G improved workability. Furthermore, the ideal replacement ratios for replacing PC with GP and S with G to achieve high mechanical properties were 20% and 0%, respectively. Increasing the replacement rate of GP in place of PC at a fixed ratio of G to S resulted in a significant decrease in water permeability values. Finally, a microstructural analysis confirms the experimental findings. In addition, PC100-S100 was the best mix compared to PC100-S50 G50 and PC100-G100.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 99, "Times Cited, All Databases": 99, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3085, "DOI": "10.3390/su15043085", "DOI Link": "http://dx.doi.org/10.3390/su15043085", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000941433900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rogers, LJ; Jahnke, KD; Teraji, T; Marseglia, L; Müller, C; Naydenov, B; Schauffert, H; Kranz, C; Isoya, J; McGuinness, LP; Jelezko, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rogers, L. J.; Jahnke, K. D.; Teraji, T.; Marseglia, L.; Mueller, C.; Naydenov, B.; Schauffert, H.; Kranz, C.; Isoya, J.; McGuinness, L. P.; Jelezko, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple intrinsically identical single-photon emitters in the solid state", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Emitters of indistinguishable single photons are crucial for the growing field of quantum technologies. To realize scalability and increase the complexity of quantum optics technologies, multiple independent yet identical single-photon emitters are required. However, typical solid-state single-photon sources are inherently dissimilar, necessitating the use of electrical feedback or optical cavities to improve spectral overlap between distinct emitters. Here we demonstrate bright silicon vacancy (SiV-) centres in low-strain bulk diamond, which show spectral overlap of up to 91% and nearly transform-limited excitation linewidths. This is the first time that distinct single-photon emitters in the solid state have shown intrinsically identical spectral properties. Our results have impact on the application of single-photon sources for quantum optics and cryptography.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 245, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2014, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4739, "DOI": "10.1038/ncomms5739", "DOI Link": "http://dx.doi.org/10.1038/ncomms5739", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341081300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shahmoon, E; Wild, DS; Lukin, MD; Yelin, SF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shahmoon, Ephraim; Wild, Dominik S.; Lukin, Mikhail D.; Yelin, Susanne F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cooperative Resonullces in Light Scattering from Two-Dimensional Atomic Arrays", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We consider light scattering off a two-dimensional (2D) dipolar array and show how it can be tailored by properly choosing the lattice constant of the order of the incident wavelength. In particular, we demonstrate that such arrays can operate as a nearly perfect mirror for a wide range of incident angles and frequencies, and shape the emission pattern from an individual quantum emitter into a well-defined, collimated beam. These results can be understood in terms of the cooperative resonullces of the surface modes supported by the 2D array. Experimental realizations are discussed, using ultracold arrays of trapped atoms and excitons in 2D semiconductor materials, as well as potential applications ranging from atomically thin metasurfaces to single photon nonlinear optics and nullomechanics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2017, "Volume": 118, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113601, "DOI": "10.1103/PhysRevLett.118.113601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.118.113601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396266700004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, C; Gao, Y; Xiao, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chong; Gao, Yang; Xiao, Di", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic Nonlinear Hall Effect in Antiferromagnetic Tetragonal CuMnAs", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Detecting the orientation of the Neel vector is a major research topic in antiferromagnetic spintronics. Here we recognize the intrinsic nonlinear Hall effect, which is independent of the relaxation time, as a prominent contribution to the time-reversal-odd second order conductivity and can be used to detect the reversal of the Neel vector. In contrast, the Berry-curvature-dipole-induced nonlinear Hall effect depends linearly on relaxation time and is time-reversal even. We study the intrinsic nonlinear Hall effect in an antiferromagnetic metal: tetragonal CuMnAs, and show that its nonlinear Hall conductivity can reach the order of mA/V2. The dependence on the chemical potential of such nonlinear Hall conductivity can be qualitatively explained by a tilted massive Dirac model. Moreover, we demonstrate its strong temperature dependence and briefly discuss its competition with the second order Drude conductivity. Finally, a complete survey of magnetic point groups is presented, providing guidelines for finding more antiferromagnetic materials with the intrinsic nonlinear Hall effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 31", "Publication Year": 2021, "Volume": 127, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 277201, "DOI": "10.1103/PhysRevLett.127.277201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.127.277201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754466000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naveed, MA; Bilal, RMH; Baqir, MA; Bashir, MM; Ali, MM; Rahim, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naveed, Muhammad Ashar; Bilal, Rana Muhammad Hasan; Baqir, Muhammad Abuzar; Bashir, Muhammad Mehran; Ali, Muhammad Mahmood; Rahim, Arbab Abdur", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrawideband fractal metamaterial absorber made of nickel operating in the UV to IR spectrum", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullo-structure based metamaterial absorbers have been getting enormous interest owing to their widespread applications in solar cells, thermal emitters and integrated photonic devices. This paper presents a novel and ultrathin broadband metamaterial absorber comprised of a hexagonal nullo-ring shaped fractal structure. The designed fractal metamaterial absorber (FMA) is composed of a three-layer device having a metal-insulator-metal (MIM) configuration. Based on the numerical simulations, the proposed FMA manifests more than 97% absorptivity for the operating wavelength from 820 to 2520 nm. However, it shows above 80% absorption value for the entire operating wavelength from 200 to 4000 nm. To predict the angular stability of this broadband absorption device, the absorptivity was investigated under different oblique incident angles of the exciting wave by considering both transverse electric (TE)- and transverse magnetic (TM)-polarization. Further, multiple reflection theory was employed to calculate the absorption value of FMA, and it shows appreciable agreement with the simulation results. It is also anticipated that this kind of FMA has not been investigated yet with these ultrabroadband absorption characteristics. Large operating bandwidth, angular robustness, ultra-compact thickness and inclusion of low-cost and temperature-endurable nickel metal (Ni) make this nullostructure-based absorber an attractive candidate for solar photovoltaics, thermal emission, and infrared spectroscopic applications. (C) 2021 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 117, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2021, "Volume": 29, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 42911, "End Page": 42923, "Article Number": null, "DOI": "10.1364/OE.446423", "DOI Link": "http://dx.doi.org/10.1364/OE.446423", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000730136600048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Repellin, C; Dong, ZH; Zhang, YH; Senthil, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Repellin, Cecile; Dong, Zhihuan; Zhang, Ya-Hui; Senthil, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferromagnetism in Narrow Bands of Moire Superlattices", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Many graphene moire superlattices host narrow bands with nonzero valley Chem numbers. We provide analytical and numerical evidence for a robust spin and/or valley polarized insulator at total integer band filling in nearly flat bands of several different moire materials. In the limit of a perfectly flat band, we present analytical arguments in favor of the ferromagnetic state substantiated by numerical calculations. Further, we numerically evaluate its stability for a finite bandwidth. We provide exact diagonalization results for models appropriate for ABC trilayer graphene aligned with hBN, twisted double bilayer graphene, and twisted bilayer graphene aligned with hBN. We also provide DMRG results for a honeycomb lattice with a quasiflat band and nonzero Chem number, which extend our results to larger system sizes. We find a maximally spin and valley polarized insulator at all integer fillings when the band is sufficiently flat. We also show that interactions may induce effective dispersive terms strong enough to destabilize this state. These results still hold in the case of zero valley Chem number (for example, trivial side of TLG/hBN). We give an intuitive picture based on extended Wannier orbitals, and emphasize the role of the quantum geometry of the band, whose microscopic details may enhance or weaken ferromagnetism in moire materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 7", "Publication Year": 2020, "Volume": 124, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 187601, "DOI": "10.1103/PhysRevLett.124.187601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.124.187601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000530756500017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YY; Alam, MZ; Karimi, M; Upham, J; Reshef, O; Liu, C; Willner, AE; Boyd, RW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yiyu; Alam, M. Zahirul; Karimi, Mohammad; Upham, Jeremy; Reshef, Orad; Liu, Cong; Willner, Alan E.; Boyd, Robert W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband frequency translation through time refraction in an epsilon-near-zero material", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Space-time duality in paraxial optical wave propagation implies the existence of intriguing effects when light interacts with a material exhibiting two refractive indexes separated by a boundary in time. The direct consequence of such time-refraction effect is a change in the frequency of light while leaving the wavevector unchanged. Here, we experimentally show that the effect of time refraction is significantly enhanced in an epsilon-near-zero (ENZ) medium as a consequence of the optically induced unity-order refractive index change in a sub-picosecond time scale. Specifically, we demonstrate broadband and controllable shift (up to 14.9THz) in the frequency of a light beam using a time-varying subwavelength-thick indium tin oxide (ITO) film in its ENZ spectral range. Our findings hint at the possibility of designing (3+1)D metamaterials by incorporating time-varying bulk ENZ materials, and they present a unique playground to investigate various novel effects in the time domain. Here, the authors present an experimental demonstration of adiabatic frequency conversion using the concept of time boundary by exploiting the properties of an ITO film operating near its epsilon-near-zero frequency. They demonstrate a large and controllable shift up to 14.9THz.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2180, "DOI": "10.1038/s41467-020-15682-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15682-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531425900022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Okhotnikov, K; Charpentier, T; Cadars, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Okhotnikov, Kirill; Charpentier, Thibault; Cadars, Sylvian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Supercell program: a combinatorial structure-generation approach for the local-level modeling of atomic substitutions and partial occupancies in crystals", "Source Title": "JOURNAL OF CHEMINFORMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Background: Disordered compounds are crucially important for fundamental science and industrial applications. Yet most available methods to explore solid-state material properties require ideal periodicity, which, strictly speaking, does not exist in this type of materials. The supercell approximation is a way to imply periodicity to disordered systems while preserving disordered properties at the local level. Although this approach is very common, most of the reported research still uses supercells that are constructed by hand and ad-hoc. Results: This paper describes a software named supercell, which has been designed to facilitate the construction of structural models for the description of vacancy or substitution defects in otherwise periodically-ordered (crystalline) materials. The presented software allows to apply the supercell approximation systematically with an all-in-one implementation of algorithms for structure manipulation, supercell generation, permutations of atoms and vacancies, charge balancing, detecting symmetry-equivalent structures, Coulomb energy calculations and sampling output configurations. The mathematical and physical backgrounds of the program are presented, along with an explanation of the main algorithms and relevant technical details of their implementation. Practical applications of the program to different types of solid-state materials are given to illustrate some of its potential fields of application. Comparisons of the various algorithms implemented within supercell with similar solutions are presented where possible. Conclusions: The all-in-one approach to process point disordered structures, powerful command line interface, excellent performance, flexibility and GNU GPL license make the supercell program a versatile set of tools for disordered structures manipulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2016, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17, "DOI": "10.1186/s13321-016-0129-3", "DOI Link": "http://dx.doi.org/10.1186/s13321-016-0129-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373321700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, C; Li, JH; Lindsay, L; Cherns, D; Pomeroy, JW; Liu, S; Edgar, JH; Kuball, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Chao; Li, Jiahan; Lindsay, Lucas; Cherns, David; Pomeroy, James W.; Liu, Song; Edgar, James H.; Kuball, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating the thermal conductivity in hexagonal boron nitride via controlled boron isotope concentration", "Source Title": "COMMUNICATIONS PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride (h-BN) has been predicted to exhibit an in-plane thermal conductivity as high as similar to 550 W m(-1) K-1 at room temperature, making it a promising thermal management material. However, current experimental results (220-420 W m(-1) K-1) have been well below the prediction. Here, we report on the modulation of h-BN thermal conductivity by controlling the B isotope concentration. For monoisotopic B-10 h-BN, an in-plane thermal conductivity as high as 585 W m(-1) K-1 is measured at room temperature, similar to 80% higher than that of h-BN with a disordered isotope concentration (52%:48% mixture of B-10 and B-11). The temperature-dependent thermal conductivities of monoisotopic h-BN agree well with first principles calculations including only intrinsic phonon-phonon scattering. Our results illustrate the potential to achieve high thermal conductivity in h-BN and control its thermal conductivity, opening avenues for the wide application of h-BN as a next-generation thin-film material for thermal management, metamaterials and metadevices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2019, "Volume": 2, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 43, "DOI": "10.1038/s42005-019-0145-5", "DOI Link": "http://dx.doi.org/10.1038/s42005-019-0145-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467220700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mohr, D; Marcadet, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mohr, Dirk; Marcadet, Stephane J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Micromechanically-motivated phenomenological Hosford-Coulomb model for predicting ductile fracture initiation at low stress triaxialities", "Source Title": "INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A phenomenological ductile fracture initiation model for metals is developed for predicting ductile fracture in industrial practice. Its formulation is based on the assumption that the onset of fracture is imminent with the formation of a primary or secondary band of localization. The results from a unit cell analysis on a Levy-von Mises material with spherical defects revealed that a Mohr-Coulomb type of model is suitable for predicting the onset of shear and normal localization. To improve the agreement of the model predictions with experimental results, an extended Mohr-Coulomb criterion is proposed which makes use of the Hosford equivalent stress in combination with the normal stress acting on the plane of maximum shear. A fracture initiation model is obtained by transforming the localization criterion from stress space to the space of equivalent plastic strain, stress triaxiality and Lode angle parameter using the material's isotropic hardening law. Experimental results are presented for three different advanced high strength steels. For each material, the onset of fracture is characterized for five distinct stress states including butterfly shear, notched tension, tension with a central hole and punch experiments. The comparison of model predictions with the experimental results demonstrates that the proposed Hosford-Coulomb model can predict the instant of ductile fracture initiation in advanced high strength steels with good accuracy. (C) 2015 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2015, "Volume": "67-68", "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 40, "End Page": 55, "Article Number": null, "DOI": "10.1016/j.ijsolstr.2015.02.024", "DOI Link": "http://dx.doi.org/10.1016/j.ijsolstr.2015.02.024", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357243900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karp, J; Botana, AS; Norman, MR; Park, H; Zingl, M; Millis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karp, Jonathan; Botana, Antia S.; Norman, Michael R.; Park, Hyowon; Zingl, Manuel; Millis, Andrew", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Many-Body Electronic Structure of NdNiO2 and CaCuO2", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The demonstration of superconductivity in nickelate analogs of high T-c cuprates provides new perspectives on the physics of correlated electron materials. The degree to which the nickelate electronic structure is similar to that of cuprates is an important open question. This paper presents results of a comparative study of the many-body electronic structure and theoretical phase diagram of the isostructural materials CaCuO2 and NdNiO2. Both NdNiO2 and CaCuO2 are found to be charge transfer materials. Important differences include the proximity of the oxygen 2p bands to the Fermi level, the bandwidth of the transition metal-derived 3d bands, and the presence, in NdNiO2, of both Nd-derived 5d states crossing the Fermi level and a van Hove singularity that crosses the Fermi level as the out-of-plane momentum is varied. The low-energy physics of NdNiO2 is found to be that of a single Ni-derived correlated band, with additional accompanying weakly correlated bands of Nd-derived states that dope the Ni-derived band. The effective correlation strength of the Ni-derived d band crossing the Fermi level in NdNiO2 is found to be greater than that of the Cu-derived d band in CaCuO2, but the predicted magnetic transition temperature of NdNiO2 is substantially lower than that of CaCuO2 because of the smaller bandwidth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2020, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21061, "DOI": "10.1103/PhysRevX.10.021061", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.10.021061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540662900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SY; Wang, KL; Chen, Q; Wu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Songyu; Wang, Kailin; Chen, Qiao; Wu, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic hydrogen production of S-scheme TiO2/g-C3 N 4 heterojunction loaded with single-atom Ni", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "S-scheme heterostructure photocatalysts can achieve highly efficient solar energy utilization. Here, singleatom Ni species were deposited onto TiO 2 /g-C 3 N 4 (TCN) composite photocatalyst with an S-scheme heterojunction for highly efficient photocatalytic water splitting to produce hydrogen. Under solar irradiation, it realized the hydrogen production activity of 134 mu mol g -1 h -1 , about 5 times higher than the TCN without atomic Ni. In-situ Kelvin probe force microscopy characterization and the density functional calculation certify that by forming the S-scheme heterojunction, the photo-excited electrons from the TiO 2 combine with the photogenerated holes at the coupled g-C 3 N 4 driven by a built-in electric field. More importantly, the single-atom Ni species stabilized the photogenerated electrons from the g-C 3 N 4 could effectively enhance the charge separation between the holes on the valence band of TiO 2 and electrons at the conduction band of g-C 3 N 4 . Meanwhile, the Ni atoms act as the surface catalytic centers for the water reduction reaction, which greatly improves the reactivity of the photocatalyst. The present work provides a new approach for developing noble metal-free heterojunctions for high-efficiency photocatalysis. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2024, "Volume": 175, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 104, "End Page": 114, "Article Number": null, "DOI": "10.1016/j.jmst.2023.07.044", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2023.07.044", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001079213500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Parvatkar, PT; Kandambeth, S; Shaikh, AC; Nadinov, I; Yin, J; Kale, VS; Healing, G; Emwas, AH; Shekhah, O; Alshareef, HN; Mohammed, OF; Eddaoudi, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Parvatkar, Prakash T.; Kandambeth, Sharath; Shaikh, Aslam C.; Nadinov, Issatay; Yin, Jun; Kale, Vinayak S.; Healing, George; Emwas, Abdul-Hamid; Shekhah, Osama; Alshareef, Husam N.; Mohammed, Omar F.; Eddaoudi, Mohamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Tailored COF for Visible-Light Photosynthesis of 2,3-Dihydrobenzofurans", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterogeneous photocatalysis is considered as an ecofriendly and sustainable approach for addressing energy and environmental persisting issues. Recently, heterogeneous photo-catalysts based on covalent organic frameworks (COFs) have gained considerable attention due to their remarkable performance and recyclability in photocatalytic organic transformations, offering a prospective alternative to homogeneous photocatalysts based on precious metal/organic dyes. Herein, we report Hex-Aza-COF-3 as a metal-free, visible-light-activated, and reusable heterogeneous photocatalyst for the synthesis of 2,3-dihydrobenzofurans, as a pharmaceutically relevant structural motif, via the selective oxidative [3+2] cycloaddition of phenols with olefins. Moreover, we demonstrate the synthesis of natural products (+/-)-conocarpan and (+/-)-pterocarpin via the [3+2] cycloaddition reaction as an important step using Hex-Aza-COF-3 as a heterogeneous photocatalyst. Interestingly, the presence of phenazine and hexaazatriphenylene as rigid heterocyclic units in Hex-Aza-COF-3 strengthens the covalent linkages, enhances the absorption in the visible region, and narrows the energy band, leading to excellent activity, charge transport, stability, and recyclability in photocatalytic reactions, as evident from theoretical calculations and real-time information on ultrafast spectroscopic measurements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 66, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2023, "Volume": 145, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5074, "End Page": 5082, "Article Number": null, "DOI": "10.1021/jacs.2c10471", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c10471", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937909200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kola, V; Carvalho, IS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kola, Vessa; Carvalho, Isabel S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plant extracts as additives in biodegradable films and coatings in active food packaging", "Source Title": "FOOD BIOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Petroleum-based polymers are widely used and known that they cause serious environmental problems due to their non-biodegradability. To this end, researchers have focused on the development of ecological packaging materials from natural resources, such as polysaccharides and proteins. However, the films and coatings produced from natural biopolymers have fewer desirable properties than synthetic polymers. Studies have showed that plant extracts represent an interesting ingredient for biodegradable food packaging by altering the properties of biopolymers. The scope of this review is to present the latest ideas on active packaging and how plant extracts impact properties like physical, mechanical, barrier, structural, antioxidant, antimicrobial and the biodegradability of the films. Most of the plant extracts increased the thickness of the biopolymer, reduce the transparency and water vapour permeability, and have adverse effects on the mechanical properties (tensile strength and elongation at break), and alters the biodegradation rate of the films and coatings. The microstructural of the films changed when the plant extracts are added into the solution and the colour of the films depended on the variety of polyphenols that each plant extract contained. Additionally, in most cases natural extracts can boost the antioxidant and antimicrobial properties, thus improve the shelf life of packaged food. Besides the promising results obtained from the literature, there is a lot to achieve, in relation to product quality, shelf life and consumer acceptance of extract-based films on food products.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 54, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102860, "DOI": "10.1016/j.fbio.2023.102860", "DOI Link": "http://dx.doi.org/10.1016/j.fbio.2023.102860", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032271300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, AW; Chen, HY; Hao, YX; Zhang, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Aiwen; Chen, Hongyan; Hao, Yuxin; Zhang, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vibration and bending behavior of functionally graded nullocomposite doubly-curved shallow shells reinforced by graphene nulloplatelets", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free vibration and static bending of functionally graded (FG) graphene nulloplatelet (GPL) reinforced composite doubly-curved shallow shells with three distinguished distributions are analyzed. Material properties with gradient variation in the thickness aspect are evaluated by the modified Halpin-Tsai model. Mathematical model of the simply supported doubly-curved shallow shells rests upon Hamilton Principle and a higher order shear deformation theory (HSDT). The free vibration frequencies and bending deflections are gained by taking into account Navier technique. The agreement between the obtained results and ANSYS as well as the prior results in the open literature verifies the accuracy of the theory in this article. Further, parametric studies are accomplished to highlight the significant influence of GPL distribution patterns and weight fraction, stratification number, dimensions of GPLs and shells on the mechanical behavior of the system. (C) 2018 The Author. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 277, "Times Cited, All Databases": 277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 550, "End Page": 559, "Article Number": null, "DOI": "10.1016/j.rinp.2018.02.062", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2018.02.062", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435611100072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, ZJ; Xi, Q; Chen, W; Cheng, AHD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Zhuo-Jia; Xi, Qiang; Chen, Wen; Cheng, Alexander H-D", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A boundary-type meshless solver for transient heat conduction analysis of slender functionally graded materials with exponential variations", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study presents a parallel meshless solver for transient heat conduction analysis of slender functionally graded materials (FGMs) with exponential variations. In the present parallel meshless solver, a strong-form boundary collocation method, the boundary knot method (BKM), in conjunction with Laplace transform is implemented to solve the heat conduction equations of slender FGMs with exponential variations. This method is mathematically simple, easy-to-parallel, meshless, and without domain discretization. However, two ill-posed issues, the ill-conditioning dense BKM matrix and numerical inverse Laplace transform process, may lead to incorrect numerical results. Here the extended precision arithmetic (EPA) and the domain decomposition method (DDM) have been adopted to alleviate the effect of these two ill-posed issues on numerical efficiency of the present method. Then the parallel algorithm has been employed to significantly reduce the computational cost and enhance the computational capacity for the FGM structures with larger length-width ratio. To demonstrate the effectiveness of the present parallel meshless solver for transient heat conduction analysis, several benchmark examples are considered under slender FGMs with exponential variations. The present results are compared with the analytical solutions, the conventional boundary knot method and COMSOL simulation. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 76, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 760, "End Page": 773, "Article Number": null, "DOI": "10.1016/j.camwa.2018.05.017", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2018.05.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442066600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blaha, P; Schwarz, K; Tran, F; Laskowski, R; Madsen, GKH; Marks, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blaha, Peter; Schwarz, Karlheinz; Tran, Fabien; Laskowski, Robert; Madsen, Georg K. H.; Marks, Laurence D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WIEN2k: An APW+lo program for calculating the properties of solids", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The WIEN2k program is based on the augmented plane wave plus local orbitals (APW+lo) method to solve the Kohn-Sham equations of density functional theory. The APW+lo method, which considers all electrons (core and valence) self-consistently in a full-potential treatment, is implemented very efficiently in WIEN2k, since various types of parallelization are available and many optimized numerical libraries can be used. Many properties can be calculated, ranging from the basic ones, such as the electronic band structure or the optimized atomic structure, to more specialized ones such as the nuclear magnetic resonullce shielding tensor or the electric polarization. After a brief presentation of the APW+lo method, we review the usage, capabilities, and features of WIEN2k (version 19) in detail. The various options, properties, and available approximations for the exchange-correlation functional, as well as the external libraries or programs that can be used with WIEN2k, are mentioned. References to relevant applications and some examples are also given. (C) 2020 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1611, "Times Cited, All Databases": 1641, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 152, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 74101, "DOI": "10.1063/1.5143061", "DOI Link": "http://dx.doi.org/10.1063/1.5143061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519820500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rabiei, M; Palevicius, A; Monshi, A; Nasiri, S; Vilkauskas, A; Janusas, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rabiei, Marzieh; Palevicius, Arvydas; Monshi, Ahmad; Nasiri, Sohrab; Vilkauskas, Andrius; Janusas, Giedrius", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparing Methods for Calculating nullo Crystal Size of Natural Hydroxyapatite Using X-Ray Diffraction", "Source Title": "nullOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on a comparison of methods based on XRD patterns for calculating crystal size. In this case, XRD peaks were extracted from hydroxyapatite obtained from cow, pig, and chicken bones. Hydroxyapatite was synthesized through the thermal treatment of natural bones at 950 degrees C. XRD patterns were selected by adjustment of X-Pert software for each method and for calculating the size of the crystals. Methods consisted of Scherrer (three models), Monshi-Scherrer, three models of Williamson-Hall (namely the Uniform Deformation Model (UDM), the Uniform Stress Deformation Model (USDM), and the Uniform Deformation Energy Density Model (UDEDM)), Halder-Wanger (H-W), and the Size Strain Plot Method (SSP). These methods have been used and compared together. The sizes of crystallites obtained by the XRD patterns in each method for hydroxyapatite from cow, pig, and chicken were 1371, 457, and 196 nm in the Scherrer method when considering all of the available peaks together (straight line model). A new model (straight line passing the origin) gave 60, 60, and 53 nm, which shows much improvement. The average model gave 56, 58, and 52 nm, for each of the three approaches, respectively, for cow, pig, and chicken. The Monshi-Scherrer method gave 60, 60, and 57 nm. Values of 56, 62, and 65 nm were given by the UDM method. The values calculated by the USDM method were 60, 62, and 62 nm. The values of 62, 62, and 65 nm were given by the UDEDM method for cow, pig, and chicken, respectively. Furthermore, the crystal size value was 4 nm for all samples in the H-W method. Values were also calculated as 43, 62, and 57 nm in the SSP method for cow, pig, and chicken tandemly. According to the comparison of values in each method, the Scherrer method (straight line model) for considering all peaks led to unreasonable values. Nevertheless, other values were in the acceptable range, similar to the reported values in the literature. Experimental analyses, such as specific surface area by gas adsorption (Brunauer-Emmett-Teller (BET)) and Transmission Electron Microscopy (TEM), were utilized. In the final comparison, parameters of accuracy, ease of calculations, having a check point for the researcher, and difference between the obtained values and experimental analysis by BET and TEM were considered. The Monshi-Scherrer method provided ease of calculation and a decrease in errors by applying least squares to the linear plot. There is a check point for this line that the slope must not be far from one. Then, the intercept gives the most accurate crystal size. In this study, the setup of values for BET (56, 52, and 49 nm) was also similar to the Monshi-Scherrer method and the use of it in research studies of nullotechnology is advised.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 294, "Times Cited, All Databases": 297, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1627, "DOI": "10.3390/nullo10091627", "DOI Link": "http://dx.doi.org/10.3390/nullo10091627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000581347900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sääskilahti, K; Oksanen, J; Tulkki, J; Volz, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saaskilahti, K.; Oksanen, J.; Tulkki, J.; Volz, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Role of anharmonic phonon scattering in the spectrally decomposed thermal conductance at planar interfaces", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A detailed understanding of the vibrational heat transfer mechanisms between solids is essential for the efficient thermal engineering and control of nullomaterials. We investigate the frequency dependence of anharmonic scattering and interfacial thermal conduction between two acoustically mismatched solids in planar contact by calculating the spectral decomposition of the heat current flowing through an interface between two materials. The calculations are based on analyzing the correlations of atomic vibrations using the data extracted from nonequilibrium molecular dynamics simulations. Inelastic effects arising from anharmonic interactions are shown to significantly facilitate heat transfer between two mass-mismatched face-centered-cubic lattices even at frequencies exceeding the cutoff frequency of the heavier material due to (i) enhanced dissipation of evanescent vibrational modes and (ii) frequency-doubling and frequency-halving three-phonon energy transfer processes at the interface. The results provide substantial insight into interfacial energy transfer mechanisms, especially at high temperatures, where inelastic effects become important and other computational methods are ineffective.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2014, "Volume": 90, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 134312, "DOI": "10.1103/PhysRevB.90.134312", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.90.134312", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000343944500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de' Medici, L; Giovannetti, G; Capone, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de' Medici, Luca; Giovannetti, Gianluca; Capone, Massimo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective Mott Physics as a Key to Iron Superconductors", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show that electron- and hole-doped BaFe2As2 are strongly influenced by a Mott insulator that would be realized for half-filled conduction bands. Experiments show that weakly and strongly correlated conduction electrons coexist in much of the phase diagram, a differentiation which increases with hole doping. This selective Mottness is caused by the Hund's coupling effect of decoupling the charge excitations in different orbitals. Each orbital then behaves as a single-band doped Mott insulator, where the correlation degree mainly depends on how doped is each orbital from half filling. Our scenario reconciles contrasting evidences on the electronic correlation strength, implies a strong asymmetry between hole and electron doping, and establishes a deep connection with the cuprates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 315, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2014, "Volume": 112, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 177001, "DOI": "10.1103/PhysRevLett.112.177001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.177001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000341577400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kwon, Y; Lee, J; Noh, Y; Kim, D; Lee, Y; Yu, C; Roldao, JC; Feng, SY; Gierschner, J; Wannemacher, R; Kwon, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kwon, Yonghwan; Lee, Jungwook; Noh, Yeonjin; Kim, Doyon; Lee, Yungyeong; Yu, Changhoon; Roldao, Juan Carlos; Feng, Siyang; Gierschner, Johannes; Wannemacher, Reinhold; Kwon, Min Sang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation and degradation of strongly reducing cyanoarene-based radical anions towards efficient radical anion-mediated photoredox catalysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cyanoarene-based photocatalysts are widely used due to their catalytic performance, but the formation of the active species and its potential degradation pathways are poorly understood. Here, the authors investigate these pathways under commonly-used photoredox-mediated reaction conditions. Cyanoarene-based photocatalysts (PCs) have attracted significant interest owing to their superior catalytic performance for radical anion mediated photoredox catalysis. However, the factors affecting the formation and degradation of cyanoarene-based PC radical anion (PC center dot-) are still insufficiently understood. Herein, we therefore investigate the formation and degradation of cyanoarene-based PC center dot- under widely-used photoredox-mediated reaction conditions. By screening various cyanoarene-based PCs, we elucidate strategies to efficiently generate PC center dot- with adequate excited-state reduction potentials (E-red*) via supra-efficient generation of long-lived triplet excited states (T-1). To thoroughly investigate the behavior of PC center dot- in actual photoredox-mediated reactions, a reductive dehalogenation is carried out as a model reaction and identified the dominullt photodegradation pathways of the PC center dot-. Dehalogenation and photodegradation of PC center dot- are coexistent depending on the rate of electron transfer (ET) to the substrate and the photodegradation strongly depends on the electronic and steric properties of the PCs. Based on the understanding of both the formation and photodegradation of PC center dot-, we demonstrate that the efficient generation of highly reducing PC center dot- allows for the highly efficient photoredox catalyzed dehalogenation of aryl/alkyl halides at a PC loading as low as 0.001 mol% with a high oxygen tolerance. The present work provides new insights into the reactions of cyanoarene-based PC center dot- in photoredox-mediated reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 92, "DOI": "10.1038/s41467-022-35774-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35774-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935587000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, HW; Ahmad, A; Farooq, F; Ostrowski, KA; Maslak, M; Czarnecki, S; Aslam, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Hongwei; Ahmad, Ayaz; Farooq, Furqan; Ostrowski, Krzysztof Adam; Maslak, Mariusz; Czarnecki, Slawomir; Aslam, Fahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Predicting the compressive strength of concrete with fly ash admixture using machine learning algorithms", "Source Title": "CONSTRUCTION AND BUILDING MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The cementitious composites have different properties in the changing environment. Thus, knowing their mechanical properties is very important for safety reasons. The most important in the case of concrete is the Compressive strength (CS). To predict the CS of concrete Machine learning (ML) approaches has been essential. This study includes the collection of data from the experimental work and the application of ML techniques to predict the CS of concrete containing fly ash. The chemical and physical properties of all the materials used in this study were evaluated. Although, the emphasis of this research is on the use of supervised machine learning algorithms to forecast the CS of concrete. The Gene expression programming (GEP), Artificial neural network (ANN), and Decision tree (DT) algorithms were investigated for the prediction of outcome (CS). Concrete samples (cylinders) with different mix ratios were cast and tested at various ages to maintain the required data for applying it to run the models. Total 98 data points were collected from the experimental approach, in which seven parameters namely cement, fly ash, superplasticizer, coarse aggregate, fine aggregate, water, and days were taken as input to predict the output which was CS parameter. The experimental data is further validated by mean of k-fold cross-validation using R-2, root mean error (RME), and Root mean square error (RMSE). In addition, statistical checks were incorporated to evaluate the model performance. In comparison, the bagging algorithm shows high accuracy towards the prediction of outcome as indicated by its high coefficient correlation (R-2) value equals to 0.95, while R-2 value for GEP, ANN and DT comes to 0.86, 0.81 and 0.75 respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2021, "Volume": 308, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125021, "DOI": "10.1016/j.conbuildmat.2021.125021", "DOI Link": "http://dx.doi.org/10.1016/j.conbuildmat.2021.125021", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000708128700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pirtarighat, S; Ghannadnia, M; Baghshahi, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pirtarighat, Saba; Ghannadnia, Maryam; Baghshahi, Saeid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of silver nulloparticles using the plant extract of Salvia spinosa grown in vitro and their antibacterial activity assessment", "Source Title": "JOURNAL OF nullOSTRUCTURE IN CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Researchers use bionullotechnology techniques as eco-friendly and cost-effective routes to fabricate nulloparticles and nullomaterials. The present study confirms the ability of plant extract of Salvia spinosa grown under in vitro condition for the biosynthesis of silver nulloparticles (Ag NPs) for the first time. The surface plasmon resonullce found at 450nm confirmed the formation of Ag NPs. Moreover, FESEM images showed that nulloparticles had spherical morphology. Furthermore, XRD analysis confirmed the crystalline nature of the particles. FTIR analysis was carried out to identify possible biomolecules responsible in bioreduction of silver ions. Antimicrobial assay verified bactericidal activity of biosynthesized Ag NPs against Gram-positive and Gram-negative bacteria. According to the results, by growing the plants under controlled conditions, it is feasible to synthesize nulloparticles with desired properties. [GRAPHICS]", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 383, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2019, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 9, "Article Number": null, "DOI": "10.1007/s40097-018-0291-4", "DOI Link": "http://dx.doi.org/10.1007/s40097-018-0291-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459426200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kawamoto, R; Andò, E; Viggiani, G; Andrade, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kawamoto, Reid; Ando, Edward; Viggiani, Gioacchino; Andrade, Jose E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All you need is shape: Predicting shear banding in sand with LS-DEM", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents discrete element method (DEM) simulations with experimental comparisons at multiple length scales underscoring the crucial role of particle shape. The simulations build on technological advances in the DEM furnished by level sets (LS-DEM), which enable the mathematical representation of the surface of arbitrarily-shaped particles such as grains of sand. We show that this ability to model shape enables unprecedented capture of the mechanics of granular materials across scales ranging from macroscopic behavior to local behavior to particle behavior. Specifically, the model is able to predict the onset and evolution of shear banding in sands, replicating the most advanced high-fidelity experiments in triaxial compression equipped with sequential X-ray tomography imaging. We present comparisons of the model and experiment at an unprecedented level of quantitative agreement building a one-to-one model where every particle in the more than 53,000-particle array has its own avatar or numerical twin. Furthermore, the boundary conditions of the experiment are faithfully captured by modeling the membrane effect as well as the platen displacement and tilting. The results show a computational tool that can give insight into the physics and mechanics of granular materials undergoing shear deformation and failure, with computational times comparable to those of the experiment. One quantitative measure that is extracted from the LS-DEM simulations that is currently not available experimentally is the evolution of three dimensional force chains inside and outside of the shear band. We show that the rotations on the force chains are correlated to the rotations in stress principal directions. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 111, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 375, "End Page": 392, "Article Number": null, "DOI": "10.1016/j.jmps.2017.10.003", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2017.10.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424178500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghatak, A; Brandenbourger, M; van Wezel, J; Coulais, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghatak, Anullya; Brandenbourger, Martin; van Wezel, Jasper; Coulais, Corentin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of non-Hermitian topology and its bulk-edge correspondence in an active mechanical metamaterial", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological edge modes are excitations that are localized at the materials' edges and yet are characterized by a topological invariant defined in the bulk. Such bulk-edge correspondence has enabled the creation of robust electronic, electromagnetic, and mechanical transport properties across a wide range of systems, from cold atoms to metamaterials, active matter, and geophysical flows. Recently, the advent of non-Hermitian topological systems-wherein energy is not conserved-has sparked considerable theoretical advances. In particular, novel topological phases that can only exist in non-Hermitian systems have been introduced. However, whether such phases can be experimentally observed, and what their properties are, have remained open questions. Here, we identify and observe a form of bulk-edge correspondence for a particular non-Hermitian topological phase. We find that a change in the bulk non-Hermitian topological invariant leads to a change of topological edge-mode localization together with peculiar purely non-Hermitian properties. Using a quantum-to-classical analogy, we create a mechanical metamaterial with nonreciprocal interactions, in which we observe experimentally the predicted bulk-edge correspondence, demonstrating its robustness. Our results open avenues for the field of non-Hermitian topology and for manipulating waves in unprecedented fashions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2020, "Volume": 117, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 29561, "End Page": 29568, "Article Number": null, "DOI": "10.1073/pnas.2010580117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2010580117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000593967200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Go, D; Jo, D; Lee, HW; Kläui, M; Mokrousov, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Go, Dongwook; Jo, Daegeun; Lee, Hyun-Woo; Klaeui, Mathias; Mokrousov, Yuriy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orbitronics: Orbital currents in solids", "Source Title": "EPL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In solids, electronic Bloch states are formed by atomic orbitals. While it is natural to expect that orbital composition and information about Bloch states can be manipulated and transported, in analogy to the spin degree of freedom extensively studied in past decades, it has been assumed that orbital quenching by the crystal field prevents significant dynamics of orbital degrees of freedom. However, recent studies reveal that an orbital current, given by the flow of electrons with a finite orbital angular momentum, can be electrically generated and transported in wide classes of materials despite the effect of orbital quenching in the ground state. Orbital currents also play a fundamental role in the mechanisms of other transport phenomena such as spin Hall effect and valley Hall effect. Most importantly, it has been proposed that orbital currents can be used to induce magnetization dynamics, which is one of the most pivotal and explored aspects of magnetism. Here, we give an overview of recent progress and the current status of research on orbital currents. We review proposed physical mechanisms for generating orbital currents and discuss candidate materials where orbital currents are manifest. We review recent experiments on orbital current generation and transport and discuss various experimental methods to quantify this elusive object at the heart of orbitronics-an area which exploits the orbital degree of freedom as an information carrier in solid-state devices. Copyright (C) 2021 EPLA", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 142, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 135, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37001, "DOI": "10.1209/0295-5075/ac2653", "DOI Link": "http://dx.doi.org/10.1209/0295-5075/ac2653", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000731517700016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, MX; Wang, YY; Ferracci, G; Zheng, J; Cho, NJ; Lee, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Mengxiang; Wang, Yingying; Ferracci, Gaia; Zheng, Jing; Cho, Nam-Joon; Lee, Bae Hoon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gelatin methacryloyl and its hydrogels with an exceptional degree of controllability and batch-to-batch consistency", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gelatin methacryloyl (GelMA) is a versatile material for a wide range of bioapplications. There is an intense interest in developing effective chemical strategies to prepare GelMA with a high degree of batch-to-batch consistency and controllability in terms of methacryloyl functionalization and physiochemical properties. Herein, we systematically investigated the batch-to-batch reproducibility and controllability of producing GelMA (target highly and lowly substituted versions) via a one-pot strategy. To assess the GelMA product, several parameters were evaluated, including the degree of methacryloylation, secondary structure, and enzymatic degradation, along with the mechanical properties and cell viability of GelMA hydrogels. The results showed that two types of target GelMA with five batches exhibited a high degree of controllability and reproducibility in compositional, structural, and functional properties owing to the highly controllable one-pot strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6863, "DOI": "10.1038/s41598-019-42186-x", "DOI Link": "http://dx.doi.org/10.1038/s41598-019-42186-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466701900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, S; Yu, ZM; Liu, Y; Guan, S; Wang, SS; Zhang, XM; Yao, YG; Yang, SAG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Si; Yu, Zhi-Ming; Liu, Ying; Guan, Shan; Wang, Shan-Shan; Zhang, Xiaoming; Yao, Yugui; Yang, Shengyuan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Type-II nodal loops: Theory and material realization", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A nodal loop appears when two bands, typically one electronlike and one holelike, are crossing each other linearly along a one-dimensional manifold in reciprocal space. Here, we propose a type of nodal loop which emerges from the crossing between two bands which are both electronlike (or holelike) along a certain direction. Close to any point on such a loop (dubbed as a type-II nodal loop), the linear spectrum is strongly tilted and tipped over along one transverse direction, leading to marked differences in magnetic, optical, and transport responses compared with conventional (type-I) nodal loops. We show that the compound K4P3 is an example that hosts a pair of type-II nodal loops close to the Fermi level. Each loop traverses the whole Brillouin zone, and hence can only be annihilated in a pair when symmetry is preserved. The symmetry and topological protections of the loops as well as the associated surface states are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 14", "Publication Year": 2017, "Volume": 96, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 81106, "DOI": "10.1103/PhysRevB.96.081106", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.081106", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407549100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rau, JG; Lee, EKH; Kee, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rau, Jeffrey G.; Lee, Eric Kin-Ho; Kee, Hae-Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generic Spin Model for the Honeycomb Iridates beyond the Kitaev Limit", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, realizations of Kitaev physics have been sought in the A(2)IrO(3) family of honeycomb iridates, originating from oxygen-mediated exchange through edge-shared octahedra. However, for the j(eff) = 1/2 Mott insulator in these materials, exchange from direct d-orbital overlap is relevant, and it was proposed that a Heisenberg term should be added to the Kitaev model. Here, we provide the generic nearest-neighbor spin Hamiltonian when both oxygen-mediated and direct overlap are present, containing a bond-dependent off-diagonal exchange in addition to Heisenberg and Kitaev terms. We analyze this complete model using a combination of classical techniques and exact diagonalization. Near the Kitaev limit, we find new magnetic phases, 120 degrees and incommensurate spiral order, as well as extended regions of zigzag and stripy order. Possible applications to Na2IrO3 and Li2IrO3 are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 572, "Times Cited, All Databases": 610, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2014, "Volume": 112, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 77204, "DOI": "10.1103/PhysRevLett.112.077204", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.112.077204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000331953300031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ambrosetti, A; Reilly, AM; DiStasio, RA; Tkatchenko, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ambrosetti, Alberto; Reilly, Anthony M.; DiStasio, Robert A., Jr.; Tkatchenko, Alexandre", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-range correlation energy calculated from coupled atomic response functions", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An accurate determination of the electron correlation energy is an essential prerequisite for describing the structure, stability, and function in a wide variety of systems. Therefore, the development of efficient approaches for the calculation of the correlation energy (and hence the dispersion energy as well) is essential and such methods can be coupled with many density-functional approximations, local methods for the electron correlation energy, and even interatomic force fields. In this work, we build upon the previously developed many-body dispersion (MBD) framework, which is intimately linked to the random-phase approximation for the correlation energy. We separate the correlation energy into short-range contributions that are modeled by semi-local functionals and long-range contributions that are calculated by mapping the complex all-electron problem onto a set of atomic response functions coupled in the dipole approximation. We propose an effective range-separation of the coupling between the atomic response functions that extends the already broad applicability of the MBD method to non-metallic materials with highly anisotropic responses, such as layered nullostructures. Application to a variety of high-quality benchmark datasets illustrates the accuracy and applicability of the improved MBD approach, which offers the prospect of first-principles modeling of large structurally complex systems with an accurate description of the long-range correlation energy. (C) 2014 AIP Publishing LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 506, "Times Cited, All Databases": 548, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2014, "Volume": 140, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "18A508", "DOI": "10.1063/1.4865104", "DOI Link": "http://dx.doi.org/10.1063/1.4865104", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000336782700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rouzegar, R; Chekhov, AL; Behovits, Y; Serrano, BR; Syskaki, MA; Lambert, CH; Engel, D; Martens, U; Münzenberg, M; Wolf, M; Jakob, G; Kläui, M; Seifert, TS; Kampfrath, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rouzegar, R.; Chekhov, A. L.; Behovits, Y.; Serrano, B. R.; Syskaki, M. A.; Lambert, C. H.; Engel, D.; Martens, U.; Muenzenberg, M.; Wolf, M.; Jakob, G.; Klaeui, M.; Seifert, T. S.; Kampfrath, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Broadband Spintronic Terahertz Source with Peak Electric Fields Exceeding 1.5 MV/cm", "Source Title": "PHYSICAL REVIEW APPLIED", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, we improve the performance of an optically pumped spintronic terahertz emitter (STE) by a factor of up to 6 in field amplitude through an optimized photonic and thermal environment. Using high-energy pump pulses (energy 5 mJ, fluence >1 mJ/cm2, wavelength 800 nm, duration 80 fs), we routinely generate terahertz pulses with focal peak electric fields above 1.5 MV/cm, fluences of the order of 1 mJ/cm2, and a spectrum covering the range 0.1-11 THz. Remarkably, the field and fluence values are comparable to those obtained from a state-of-the-art terahertz table-top high-field source based on tilted-pulse-front optical rectification in LiNbO3. The optimized STE inherits all attractive features of the standard STE design, for example, ease of use and the straightforward rotation of the terahertz polarization plane, without the typical 75% power loss found in LiNbO3 setups. It, thus, opens up a promising pathway to nonlinear terahertz spectroscopy. Using low-energy laser pulses (2 nJ, 0.2 mJ/cm2, 800 nm, 10 fs), the emitted terahertz pulse has a focal peak electric field of 100 V/cm, which corresponds to a 2-fold improvement, and covers the spectrum 0.3-30 THz.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2023, "Volume": 19, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34018, "DOI": "10.1103/PhysRevApplied.19.034018", "DOI Link": "http://dx.doi.org/10.1103/PhysRevApplied.19.034018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953280800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alami, AH; Olabi, AG; Alashkar, A; Alasad, S; Aljaghoub, H; Rezk, H; Abdelkareem, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alami, Abdul Hai; Olabi, Abdul Ghani; Alashkar, Adnull; Alasad, Shamma; Aljaghoub, Haya; Rezk, Hegazy; Abdelkareem, Mohammad Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing in the aerospace and automotive industries: Recent trends and role in achieving sustainable development goals", "Source Title": "AIN SHAMS ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive Manufacturing (AM) is the fastest growing industrial technique, harboring innovative, cost effective and environmentally friendly solutions. Over the years, AM technologies have been utilized in the aerospace and automotive industries mainly for prototyping purposes. However, 3D printing of aircraft and automobile components and parts has recently proven its efficiency. In this paper, a comprehensive review on the utilization of AM technologies in the aerospace and automotive industries is presented. The various AM techniques are compared based on their process, materials, and applications. In addition, the opportunities and limitations of AM in aerospace and automotive industries are highlighted. Finally, the contribution of AM and 3D printing in achieving the Sustainable Development Goals (SDGs) is examined and evaluated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102516, "DOI": "10.1016/j.asej.2023.102516", "DOI Link": "http://dx.doi.org/10.1016/j.asej.2023.102516", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001092989800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "van Setten, MJ; Giantomassi, M; Bousquet, E; Verstraete, MJ; Hamann, DR; Gonze, X; Rignullese, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "van Setten, M. J.; Giantomassi, M.; Bousquet, E.; Verstraete, M. J.; Hamann, D. R.; Gonze, X.; Rignullese, G. -M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The PSEUDODOJO: Training and grading a 85 element optimized norm-conserving pseudopotential table", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations in crystalline structures are often performed with a planewave basis set. To make the number of basis functions tractable two approximations are usually introduced: core electrons are frozen and the diverging Coulomb potential near the nucleus is replaced by a smoother expression. The norm-conserving pseudopotential was the first successful method to apply these approximations in a fully ab initio way. Later on, more efficient and more exact approaches were developed based on the ultrasoft and the projector augmented wave formalisms. These formalisms are however more complex and developing new features in these frameworks is usually more difficult than in the norm conserving framework. Most of the existing tables of norm-conserving pseudopotentials, generated long ago, do not include the latest developments, are not systematically tested or are not designed primarily for high precision. In this paper, we present our PSEUDODOJO framework for developing and testing full tables of pseudopotentials, and demonstrate it with a new table generated with the ONCVPSP approach. The PSEUDODOJO is an open source project, building on the ABIPY package, for developing and systematically testing pseudopotentials. At present it contains 7 different batteries of tests executed with ABINIT, which are performed as a function of the energy cutoff. The results of these tests are then used to provide hints for the energy cutoff for actual production calculations. Our final set contains 141 pseudopotentials split into a standard and a stringent accuracy table. In total around 70,000 calculations were performed to test the pseudopotentials. The process of developing the final table led to new insights into the effects of both the core-valence partitioning and the non-linear core corrections on the stability, convergence, and transferability of norm-conserving pseudopotentials. The PSEUDODOJO hence provides a set of pseudopotentials and general purpose tools for further testing and development, focusing on highly accurate calculations and their use in the development of ab initio packages. The pseudopotential files are available on the PSEUDODOJO web-interface pseudo-dojo.org under the name NC (ONCVPSP) v0.4 in the psp8, UPF2, and PSML 1.1 formats. The webinterface also provides the inputs, which are compatible with the 3.3.1 and higher versions of ONCVPSP. All tests have been performed with ABINIT 8.4. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1303, "Times Cited, All Databases": 1349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 226, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 39, "End Page": 54, "Article Number": null, "DOI": "10.1016/j.cpc.2018.01.012", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2018.01.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428483000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Zeng, XM; Li, Y; Yang, HM; Tang, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Lei; Zeng, Xiaoman; Li, Yang; Yang, Huamei; Tang, Shengwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influences of MgO and PVA Fiber on the Abrasion and Cracking Resistance, Pore Structure and Fractal Features of Hydraulic Concrete", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Abrasion resistance and cracking resistance are two important properties determining the normal operation and reliability of hydropower projects that are subjected to erosion and abrasive action. In this study, polyvinyl alcohol (abbreviated as PVA) fiber and magnesium oxide expansive agents (abbreviated as MgO) were used together to solve the problems of cracking and abrasive damage. The effects of PVA fiber and MgO on the mechanical property, abrasion and cracking resistance, pore structures and fractal features of high-strength hydraulic concrete were investigated. The main results are: (1) The incorporation of 4-8% Type I MgO reduced the compressive strength, splitting tensile strength and the abrasion resistance by about 5-12% at 3, 28 and 180 days. Adding 1.2-2.4 kg/m(3) PVA fibers raised the splitting tensile strength of concrete by about 8.5-15.7% and slightly enhanced the compressive strength and abrasion resistance of concrete. (2) The incorporation of 4-8% Type I MgO prolongs the initial cracking time of concrete rings under drying by about 6.5-11.4 h, increased the cracking tensile stress by about 6-11% and lowered the cracking temperature by 2.3-4.5 degrees C during the cooling down stage. Adding 1.2-2.4 kg/m(3) PVA fibers was more efficient than adding 4-8% MgO in enhancing the cracking resistance to drying and temperature decline. (3) Although adding 4% MgO and 1.2-2.4 kg/m(3) PVA fibers together could not enhance the compressive strength and abrasion resistance, it could clearly prolong the cracking time, noticeably increase the tensile stress and greatly lower the racking temperature; that is, it efficiently improved the cracking resistance to drying and thermal shrinkage compared with the addition of MgO or PVA fiber alone. The utilization of a high dosage of Type I MgO of less than 8% and PVA fiber of no more than 2.4 kg/m(3) together is a practical technique to enhance the cracking resistance of hydraulic mass concretes, which are easy to crack. (4) The inclusion of MgO refined the pores, whereas the PVA fiber incorporation marginally coarsened the pores. The compressive strength and the abrasion resistance of hydraulic concretes incorporated with MgO and/or PVA fiber are not correlated with the pore structure parameters and the pore surface fractal dimensions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 674, "DOI": "10.3390/fractalfract6110674", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6110674", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000894882400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gabriel, E; Ma, CR; Graff, K; Conrado, A; Hou, DW; Xiong, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gabriel, Eric; Ma, Chunrong; Graff, Kincaid; Conrado, Angel; Hou, Dewen; Xiong, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterostructure engineering in electrode materials for sodium-ion batteries: Recent progress and perspectives", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries (SIBs) have stepped into the spotlight as a promising alternative to lithium-ion batteries for large-scale energy storage systems. However, SIB electrode materials, in general, have inferior performance than their lithium counterparts because Na+ is larger and heavier than Li+. Heterostructure engineering is a promising strategy to overcome this intrinsic limitation and achieve practical SIBs. We provide a brief review of recent progress in heterostructure engineering of electrode materials and research on how the phase interface influences Na+ storage and transport properties. Efficient strategies for the design and fabrication of heterostructures (in situ methods) are discussed, with a focus on the heterostructure formation mechanism. The heterostructure's influence on Na+ storage and transport properties arises primarily from local distortions of the structure and chemomechanical coupling at the phase interface, which may accelerate ion/electron diffusion, create additional active sites, and bolster structural stability. Finally, we offer our perspectives on the existing challenges, knowledge gaps, and opportunities for the advancement of heterostructure engineering as a means to develop practical, highperformance sodium-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 169, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100139, "DOI": "10.1016/j.esci.2023.100139", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100139", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001106929300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XX; Di Sante, D; Schwemmer, T; Hanke, W; Hwang, HY; Raghu, S; Thomale, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xianxin; Di Sante, Domenico; Schwemmer, Tilman; Hanke, Werner; Hwang, Harold Y.; Raghu, Srinivas; Thomale, Ronny", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust dx2-y2-wave superconductivity of infinite-layer nickelates", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recent observation of superconductivity in strontium-doped NdNiO2, we study the superconducting instabilities in this system from various vantage points. Starting with first-principles calculations, we construct two distinct tight-binding models, a simpler single-orbital as well as a three-orbital model, both of which capture the key low-energy degrees of freedom to varying degrees of accuracy. We study superconductivity in both models using the random phase approximation. We then analyze the problem at stronger coupling, and study the dominullt pairing instability in the associated t-J model limit. In all instances, the dominullt pairing tendency is in the d(x2-y2) channel, analogous to the cuprate superconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2020, "Volume": 101, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 60504, "DOI": "10.1103/PhysRevB.101.060504", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.101.060504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515626800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niu, HY; Niu, SW; Oganov, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niu, Haiyang; Niu, Shiwei; Oganov, Artem R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simple and accurate model of fracture toughness of solids", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fracture toughness K-IC plays an important role in materials design. Along with numerous experimental methods to measure the fracture toughness of materials, its understanding and theoretical prediction are very important. However, theoretical prediction of fracture toughness is challenging. By investigating the correlation between fracture toughness and the elastic properties of materials, we have constructed a fracture toughness model for covalent and ionic crystals. Furthermore, by introducing an enhancement factor, which is determined by the density of states at the Fermi level and atomic electronegativities, we have constructed a universal model of fracture toughness for covalent and ionic crystals, metals, and intermetallics. The predicted fracture toughnesses are in good agreement with experimental values for a series of materials. All the ingredients of the proposed model of fracture toughness can be obtained from first-principles calculations or from experiments, which makes it suitable for practical applications. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 176, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 14", "Publication Year": 2019, "Volume": 125, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 65105, "DOI": "10.1063/1.5066311", "DOI Link": "http://dx.doi.org/10.1063/1.5066311", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458877500030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lou, YS; Chen, L; Clausmeyer, T; Tekkaya, AE; Yoon, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lou, Yanshan; Chen, Lin; Clausmeyer, Till; Tekkaya, A. Erman; Yoon, Jeong Whan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modeling of ductile fracture from shear to balanced biaxial tension for sheet metals", "Source Title": "INTERNATIONAL JOURNAL OF SOLIDS AND STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A ductile fracture model is proposed to describe shear fracture of sheet metals from shear to balanced biaxial tension via uniaxial and plane strain tension. The fracture criterion models plastic damage as strain-induced void nucleation, triaxiality-governed void enlargement, Lode-controlled void torsion, and shear-restrained coalescence of voids. Its flexibility is investigated by a parameter study of the ductile fracture model proposed. The fracture model is employed to describe ductile fracture behavior of an aluminum alloy AA6082 T6 (thickness: 1.0 mm). Dogbone specimens are strained to characterize the strain hardening properties, while another four different specimens are tested to characterize fracture behavior in shear, uniaxial tension, plane strain tension and balanced biaxial tension. The loading processes are analyzed numerically with the stress invariant-based Drucker yield function which is for the first time specified for body-centered cubic and face-centered cubic metals. Fracture strains in various loading conditions are measured with a hybrid experimental-numerical approach. The measured fracture strains are then used to calibrate the ductile fracture model proposed. The ductile fracture model calibrated above is employed to predict the onset of ductile fracture for these four specimens. For the purpose of comparison, the predicted fracture strokes of these four loading conditions are compared with those predicted by the modified Mohr-Coulomb model (Bai and Wierzbicki, 2008), and two micromechanism-inspired criteria proposed recently (Lou et al., 2012, 2014). The comparison reveals that the proposed model predicts the fracture behavior in much better agreement compared with experimental results from shear to the balanced biaxial tension. Accordingly, the proposed ductile fracture criterion is recommended for the prediction of ductile fracture in sheet metal forming processes, optimization of forming parameters and design of tools for both solid elements and shell elements. Besides, the ductile fracture model proposed can also be applied in various bulk metal forming processes in case that the model is calibrated by proper sets of experiments. (C) 2017 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2017, "Volume": 112, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 169, "End Page": 184, "Article Number": null, "DOI": "10.1016/j.ijsolstr.2016.11.034", "DOI Link": "http://dx.doi.org/10.1016/j.ijsolstr.2016.11.034", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399847500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ulmer, P; Kaegi, R; Müntener, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ulmer, Peter; Kaegi, Ralf; Muntener, Othmar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimentally Derived Intermediate to Silica-rich Arc Magmas by Fractional and Equilibrium Crystallization at 1.0 GPa: an Evaluation of Phase Relationships, Compositions, Liquid Lines of Descent and Oxygen Fugacity", "Source Title": "JOURNAL OF PETROLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Differentiation of hydrous primary, mantle-derived magmas is a fundamental process to generate evolved intermediate to SiO2-rich compositions forming the bulk of the continental and island arc crust. This study focuses on the results of equilibrium and fractional crystallization experiments at 1.0GPa using two different primary magmas representing deep (90 km) and shallow (35 km) mantle extraction depths. Experiments on a hydrous high-Mg basalt were conducted at graphite-saturated and more oxidized conditions (NNO to NNOthorn2, where NNO is nickel-nickel oxide buffer) to exploit the influence of fO2 on phase assemblages and the evolution of derivative liquids. The liquid line of descent (LLD) was simulated from liquidus to near-solidus conditions ranging from 1330 degrees C to 720 degrees C. H2O contents varied from about 2.0 to more than 10wt %. The LLD covers the entire compositional range from high-Mg basalt to high-silica rhyolite and evolves from metaluminous to peraluminous compositions at 56-60wt % SiO2 under oxidizing conditions. The observed crystallization sequences and the LLD reveal contrasting behavior depending on oxidation state, H2O content and equilibrium versus fractional crystallization. Equilibrium crystallization of high-Mg basalt under reducing conditions is initially dominated by olivine fractionation followed by Cr-rich spinel, clinopyroxene (cpx), and orthopyroxene (opx). Finally, between 1060 and 1000 degrees C, amphibole formed by a peritectic reaction consuming cpxthornolivine and forming amphibolethornopx, resulting in 16% silica-undersaturated trachy-basaltic liquid. Equilibrium crystallization of the same composition under oxidizing conditions is characterized by strongly enhanced olivine and cpx fractionation and suppression of opx only occurring as a result of the peritectic amphibole-forming reaction at and below 1040 degrees C. The liquid at 980 degrees C is a peraluminous, alkali-poor, high-Al andesite representing.15% residual liquid. Fractional crystallization of the high-Mg basalt under oxidizing conditions evolves through fractionation of early olivine joined by cpx at 1200 degrees C, followed by opx and hercynitic spinel (1140-1080 degrees C) and amphibole at 1050 degrees C coexisting with cpx (and spinel) to 980 degrees C. At 950 degrees C both garnet and plagioclase (plag) join amphibole as liquidus phases. This paragenesis (plus ilmenite and apatite) persists to 750 degrees C with 16% residual liquid relative to the initial basaltic composition. Liquids evolve continuously from basalt to rhyolite, crossing the metaluminous-peraluminous boundary at about 60wt % SiO2. Fractional crystallization of the basaltic andesite starting material differs at high temperature, where opx and cpx are the liquidus phases (1200-1080 degrees C), followed by amphibole at the expense of opx. Below 950 degrees C the phase assemblage is identical except at the lowest temperature (720 degrees C), where quartz saturates in a high-silica rhyolitic liquid representing 20% of the initial basaltic andesite. Liquid compositions of the two starting compositions converge below 950 degrees C, with the exception of K2O, which behaves incompatibly along the liquid line of descent. The H2O-undersaturated fractional crystallization experiments on the high-Mg basaltic composition under relatively reducing conditions evolve towards tholeiitic or alkalic compositions owing to early plagioclase (at 1140 degrees C) and abundant opx (at 1110 degrees C) crystallization followed by garnet-cpx-plag-ilmenite at 1080 degrees C. Closed-system equilibrium crystallization under relatively oxidized conditions is characterized by significant expansion of the olivine stability field (> 250 degrees C, 1280-1000 degrees C) relative to more reducing conditions, causing depletion of the liquid in ferrous iron and increase of ferric iron. The resulting fO(2) of the coexisting basaltic liquids increases by more than 3 log units from about NNOthorn2 to NNO+5 5 over the temperature range > 1200-1040 degrees C, potentially offering an explanation for the more oxidized character of hydrous arc magmas as opposed to low-H2O tholeiitic magmas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 59, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11, "End Page": 58, "Article Number": null, "DOI": "10.1093/petrology/egy017", "DOI Link": "http://dx.doi.org/10.1093/petrology/egy017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433240400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nixon, BT; Mansouri, K; Singh, A; Du, J; Davis, JK; Lee, JG; Slabaugh, E; Vandavasi, VG; O'Neill, H; Roberts, EM; Roberts, AW; Yingling, YG; Haigler, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nixon, B. Tracy; Mansouri, Katayoun; Singh, Abhishek; Du, Juan; Davis, Jonathan K.; Lee, Jung-Goo; Slabaugh, Erin; Vandavasi, Venu Gopal; O'Neill, Hugh; Roberts, Eric M.; Roberts, Alison W.; Yingling, Yaroslava G.; Haigler, Candace H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparative Structural and Computational Analysis Supports Eighteen Cellulose Synthases in the Plant Cellulose Synthesis Complex", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A six-lobed membrane spanning cellulose synthesis complex (CSC) containing multiple cellulose synthase (CESA) glycosyltransferases mediates cellulose microfibril formation. The number of CESAs in the CSC has been debated for decades in light of changing estimates of the diameter of the smallest microfibril formed from the beta-1,4 glucan chains synthesized by one CSC. We obtained more direct evidence through generating improved transmission electron microscopy (TEM) images and image averages of the rosette-type CSC, revealing the frequent triangularity and average cross-sectional area in the plasma membrane of its individual lobes. Trimeric oligomers of two alternative CESA computational models corresponded well with individual lobe geometry. A six-fold assembly of the trimeric computational oligomer had the lowest potential energy per monomer and was consistent with rosette CSC morphology. Negative stain TEM and image averaging showed the triangularity of a recombinullt CESA cytosolic domain, consistent with previous modeling of its trimeric nature from small angle scattering (SAXS) data. Six trimeric SAXS models nearly filled the space below an average FF-TEM image of the rosette CSC. In summary, the multifaceted data support a rosette CSC with 18 CESAs that mediates the synthesis of a fundamental microfibril composed of 18 glucan chains.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 185, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 27", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28696, "DOI": "10.1038/srep28696", "DOI Link": "http://dx.doi.org/10.1038/srep28696", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378501900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, C; Kyvelou, P; Gardner, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Cheng; Kyvelou, Pinelopi; Gardner, Leroy", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stress-strain curves for wire arc additively manufactured steels", "Source Title": "ENGINEERING STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interest in the use of wire arc additive manufacturing (WAAM) in construction has increased rapidly in recent years. Key to facilitating wider application is an improved understanding of the material behaviour. In particular, with structural design by finite element analysis in mind, constitutive models to describe the full range stressstrain response of WAAM steels are needed; development of such models is the focus of the present study. WAAM normal-strength steels generally exhibit a stress-strain response featuring a well-defined yield point, a yield plateau (for machined material) or slightly inclined yield plateau (for as-built material) and subsequent strain hardening, while the stress-strain response of WAAM high-strength steels is typically rounded, with no distinct yield point or plateau. This behaviour is similar to that of conventionally-produced steels, and hence can be represented analytically using existing material models, but with suitable modifications - a quad-linear or bilinear plus nonlinear hardening model and a two-stage Ramberg-Osgood model are proposed for WAAM normal- and high-strength steels, respectively. Predictive expressions or standardised values for the input parameters required in the models are developed and calibrated against a comprehensive database of WAAM steel coupon test results collected from the literature. The experimental database comprises over 600 engineering stress-strain curves and covers different feedstock wires, surface finishes (i.e. machined and as-built), material thicknesses, directions of testing and printing strategies. The proposed material models are shown to accurately predict the full stress-strain curves of WAAM steels, and are considered to be suitable for incorporation into analytical, numerical and design models for WAAM steel structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2023, "Volume": 279, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115628, "DOI": "10.1016/j.engstruct.2023.115628", "DOI Link": "http://dx.doi.org/10.1016/j.engstruct.2023.115628", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926410600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tarique, J; Sapuan, SM; Khalina, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tarique, J.; Sapuan, S. M.; Khalina, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of glycerol plasticizer loading on the physical, mechanical, thermal, and barrier properties of arrowroot (Maranta arundinacea) starch biopolymers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This research was set out to explore the development of arrowroot starch (AS) films using glycerol (G) as plasticizer at the ratio of 15, 30, and 45% (w/w, starch basis) using solution casting technique. The developed films were analyzed in terms of physical, structural, mechanical, thermal, environmental, and barrier properties. The incorporation of glycerol to AS film-making solution reduced the brittleness and fragility of films. An increment in glycerol concentration caused an increment in film thickness, moisture content, and solubility in water, whereas density and water absorption were reduced. The tensile strength and modulus of G-plasticized AS films were reduced significantly from 9.34 to 1.95 MPa and 620.79 to 36.08 MPa, respectively, while elongation at break was enhanced from 2.41 to 57.33%. FTIR analysis revealed that intermolecular hydrogen bonding occurred between glycerol and AS in plasticized films compared to control films. The G-plasticized films showed higher thermal stability than control films. The cross-sectional micrographs revealed that the films containing 45% glycerol concentration had higher homogeneity than 15% and 30%. Water vapour permeability of plasticized films increased by an increase in glycerol concentrations. The findings of this research provide insights into the development of bio-degradable food packaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 240, "Times Cited, All Databases": 246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13900, "DOI": "10.1038/s41598-021-93094-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-93094-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672717300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Beard, CD; Goodenough, KM; Borst, AM; Wall, F; Siegfried, PR; Deady, EA; Pohl, C; Hutchison, W; Finch, AA; Walter, BF; Elliott, HAL; Brauch, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Beard, Charles D.; Goodenough, Kathryn M.; Borst, Anouk M.; Wall, Frances; Siegfried, Pete R.; Deady, Eimear A.; Pohl, Claudia; Hutchison, William; Finch, Adrian A.; Walter, Benjamin F.; Elliott, Holly A. L.; Brauch, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkaline-Silicate REE-HFSE Systems", "Source Title": "ECONOMIC GEOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of renewable energy infrastructure requires critical raw materials, such as the rare earth ele-ments (REEs, including scandium) and niobium, and is driving expansion and diversification in their sup-ply chains. Although alternative sources are being explored, the majority of the world's resources of these elements are found in alkaline-silicate rocks and carbonatites. These magmatic systems also represent major sources of fluorine and phosphorus. Exploration models for critical raw materials are comparatively less well developed than those for major and precious metals, such as iron, copper, and gold, where most of the mineral exploration industry continues to focus. The diversity of lithologic relationships and a complex nomenclature for many alkaline rock types represent further barriers to the exploration and exploitation of REE-high field strength element (HFSE) resources that will facilitate the green revolution. We used a global review of maps, cross sections, and geophysical, geochemical, and petrological observations from alkaline systems to inform our description of the alkaline-silicate REE + HFSE mineral system from continental scale (1,000s km) down to deposit scale (similar to 1 km lateral). Continental-scale targeting criteria include a geodynamic trigger for low-degree mantle melting at high pressure and a mantle source enriched in REEs, volatile elements, and alkalies. At the province and district scales, targeting criteria relate to magmatic-system longevity and the conditions required for extensive fractional crystallization and the residual enrichment of the REEs and HFSEs. A compilation of maps and geophysical data were used to construct an interactive 3-D geologic model (25-km cube) that places mineralization within a depth and horizontal reference frame. It shows typical lithologic relationships sur-rounding orthomagmatic REE-Nb-Ta-Zr-Hf mineralization in layered agpaitic syenites, roof zone REE-Nb-Ta mineralization, and mineralization of REE-Nb-Zr associated with peralkaline granites and pegmatites. The resulting geologic model is presented together with recommended geophysical and geochemical approaches for exploration targeting, as well as mineral processing and environmental factors pertinent for the development of mineral resources hosted by alkaline-silicate magmatic systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 118, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 177, "End Page": 208, "Article Number": null, "DOI": "10.5382/econgeo.4956", "DOI Link": "http://dx.doi.org/10.5382/econgeo.4956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics; Mineralogy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000936153300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nirmal, KA; Ren, WQ; Khot, AC; Kang, DY; Dongale, TD; Kim, TG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nirmal, Kiran A.; Ren, Wanqi; Khot, Atul C.; Kang, Dae Yun; Dongale, Tukaram D.; Kim, Tae Geun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible Memristive Organic Solar Cell Using Multilayer 2D Titanium Carbide MXene Electrodes", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid systems have attracted significant attention within the scientific community due to their multifunctionality, which has resulted in increasing demands for wearable electronics, green energy, and miniaturization. Furthermore, MXenes are promising two-dimensional materials that have been applied in various areas due to their unique properties. Herein, a flexible, transparent, and conductive electrode (FTCE) based on a multilayer hybrid MXene/Ag/MXene structure that can be applied to realize an inverted organic solar cell (OSC) with memory and learning functionalities is reported. This optimized FTCE exhibits high transmittance (84%), low sheet resistance (9.7 ohm sq(-1)), and reliable operation (even after 2000 bending cycles). Moreover, the OSC using this FTCE achieves a power conversion efficiency of 13.86% and sustained photovoltaic performance, even after hundreds of switching cycles. The fabricated memristive OSC (MemOSC) device also exhibits reliable resistive switching behavior at low operating voltages of 0.60 and -0.33 V (similar to biological synapses), an excellent ON/OFF ratio (10(3)), stable endurance performance (4 x 10(3)), and memory retention properties (10(4) s). Moreover, the MemOSC device can mimic synaptic functionalities on a biological time scale. Thus, MXene can potentially be used as an electrode for highly efficient OSCs with memristive functions for future intelligent solar cell modules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 10, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202300433", "DOI Link": "http://dx.doi.org/10.1002/advs.202300433", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980574700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sentef, MA; Claassen, M; Kemper, AF; Moritz, B; Oka, T; Freericks, JK; Devereaux, TP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sentef, M. A.; Claassen, M.; Kemper, A. F.; Moritz, B.; Oka, T.; Freericks, J. K.; Devereaux, T. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of Floquet band formation and local pseudospin textures in pump-probe photoemission of graphene", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrafast materials science promises optical control of physical properties of solids. Continuous-wave circularly polarized laser driving was predicted to induce a light-matter coupled state with an energy gap and a quantum Hall effect, coined Floquet topological insulator. Whereas the envisioned Floquet topological insulator requires high-frequency pumping to obtain well-separated Floquet bands, a follow-up question regards the creation of Floquet-like states in graphene with realistic low-frequency laser pulses. Here we predict that short optical pulses attainable in experiments can lead to local spectral gaps and novel pseudospin textures in graphene. Pump-probe photoemission spectroscopy can track these states by measuring sizeable energy gaps and Floquet band formation on femtosecond time scales. Analysing band crossings and pseudospin textures near the Dirac points, we identify new states with optically induced nontrivial changes of sublattice mixing that leads to Berry curvature corrections of electrical transport and magnetization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7047, "DOI": "10.1038/ncomms8047", "DOI Link": "http://dx.doi.org/10.1038/ncomms8047", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355530700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Barajas-Aguilar, AH; Irwin, JC; Garay-Tapia, AM; Schwarz, T; Delgado, FP; Brodersen, PM; Prinja, R; Kherani, N; Sandoval, SJJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hernull Barajas-Aguilar, Aaron; Irwin, J. C.; Manuel Garay-Tapia, Andres; Schwarz, Torsten; Paraguay Delgado, Francisco; Brodersen, P. M.; Prinja, Rajiv; Kherani, Nazir; Jimenez Sandoval, Sergio J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystalline structure, electronic and lattice-dynamics properties of NbTe2", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered-structure materials are currently relevant given their quasi-2D nature. Knowledge of their physical properties is currently of major interest. Niobium ditelluride possesses a monoclinic layered-structure with a distortion in the tellurium planes. This structural complexity has hindered the determination of its fundamental physical properties. In this work, NbTe 2 crystals were used to elucidate its structural, compositional, electronic and vibrational properties. These findings have been compared with calculations based on density functional theory. The chemical composition and elemental distribution at the nulloscale were obtained through atom probe tomography. Ultraviolet photoelectron spectroscopy allowed the first determination of the work function of NbTe2. Its high value, 5.32 eV, and chemical stability allow foreseeing applications such as contact in optoelectronics. Raman spectra were obtained using different excitation laser lines: 488, 633, and 785 nm. The vibrational frequencies were in agreement with those determined through density functional theory. It was possible to detect a theoretically-predicted, low-frequency, low-intensity Raman active mode not previously observed. The dispersion curves and electronic band structure were calculated, along with their corresponding density of states. The electrical properties, as well as a pseudo-gap in the density of states around the Fermi energy are characteristics proper of a semi metal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 224, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16984, "DOI": "10.1038/s41598-018-35308-4", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-35308-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450411700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rufuss, DDW; Suganthi, L; Iniyan, S; Davies, PA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rufuss, D. Dsilva Winfred; Suganthi, L.; Iniyan, S.; Davies, P. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effects of nulloparticle-enhanced phase change material (NPCM) on solar still productivity", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper investigates the effects of nulloparticle-enhanced phase change material (NPCM) on solar still operation and performance. Technical and economic aspects were considered, to show an advance on earlier works using virgin phase-change materials (PCM). Three types of nulloparticle (TiO2, CuO and GO) were impregnated individually at 0.3 wt% in paraffin to form NPCM-1, NPCM-2 and NPCM-3 respectively. Experiments were conducted with four solar stills (SS) each of 0.5 m(2) area using respectively paraffin (SSPCM), paraffin TiO2 (SSNPCM-1), paraffin-CuO (SSNPCM-2) and paraffin-GO (SSNPCM-3). There was observed an increase in thermal conductivity and a reduction in melting and solidification temperatures, with NPCM compared to PCM. The effects of NPCM on water temperature, storage temperature, hourly and annual productivity were determined. SSPCM, SSNPCM-1, SSNPCM-2 and SSNPCM-3 yielded 3.92, 4.94, 5.28 and 3.661/m(2)/day respectively, corresponding to 26 and 35% increases in productivity of SSNPCM-1 and 2 respectively over SSPCM. Economic analysis showed cost per liter (CPL) of water of $0.035, $0.028, $0.026 and $0.13 for SSPCM, SSNPCM-1, 2 and 3 respectively. Considering the advantages in productivity and CPL, SSNPCM-2 can be recommended as the best solar still compared to SSPCM, SSNPCM-1 and 3, providing clean water at less than half the cost of bottled water in India. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 10", "Publication Year": 2018, "Volume": 192, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9, "End Page": 29, "Article Number": null, "DOI": "10.1016/j.jclepro.2018.04.201", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2018.04.201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435619400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CJ; Nguyen, DD; Lai, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chia-Jung; Nguyen, Duc Dung; Lai, Jui-Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(l-Histidine)-Mediated On-Demand Therapeutic Delivery of Roughened Ceria nullocages for Treatment of Chemical Eye Injury", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of topical bioactive formulations capable of overcoming the low bioavailability of conventional eye drops is critically important for efficient management of ocular chemical burns. Herein, a nullomedicine strategy is presented to harness the surface roughness-controlled ceria nullocages (SRCNs) and poly(l-histidine) surface coatings for triggering multiple bioactive roles of intrinsically therapeutic nullocarriers and promoting transport across corneal epithelial barriers as well as achieving on-demand release of dual drugs [acetylcholine chloride (ACh) and SB431542] at the lesion site. Specifically, the high surface roughness helps improve cellular uptake and therapeutic activity of SRCNs while exerting a negligible impact on good ocular biocompatibility of the nullomaterials. Moreover, the high poly(l-histidine) coating amount can endow the SRCNs with an approximate to 24-fold enhancement in corneal penetration and an effective smart release of ACh and SB431542 in response to endogenous pH changes caused by tissue injury/inflammation. In a rat model of alkali burn, topical single-dose nulloformulation can efficaciously reduce corneal wound areas (19-fold improvement as compared to a marketed eye drops), attenuate approximate to 93% abnormal blood vessels, and restore corneal transparency to almost normal at 4 days post-administration, suggesting great promise for designing multifunctional metallic nullotherapeutics for ocular pharmacology and tissue regenerative medicine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 10, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2302174, "DOI": "10.1002/advs.202302174", "DOI Link": "http://dx.doi.org/10.1002/advs.202302174", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001025488000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiong, RC; Nie, JH; Brantly, SL; Hays, P; Sailus, R; Watanabe, K; Taniguchi, T; Tongay, S; Jin, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiong, Richen; Nie, Jacob H.; Brantly, Samuel L.; Hays, Patrick; Sailus, Renee; Watanabe, Kenji; Taniguchi, Takashi; Tongay, Sefaattin; Jin, Chenhao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Correlated insulator of excitons in WSe2/WS2 moire superlattices", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A panoply of unconventional electronic states has been observed in moire superlattices. Engineering similar bosonic phases remains, however, largely unexplored. We report the observation of a bosonic correlated insulator in tungsten diselenide/tungs ten disulfide (WSe2/WS2) moire superlattices composed of excitons, that is, tightly bound electron-hole pairs. We develop a pump probe spectroscopy method that we use to observe an exciton incompressible state at exciton filling nex = 1 and charge neutrality, indicating a correlated insulator of excitons. With varying charge density, the bosonic correlated insulator continuously transitions into an electron correlated insulator at charge filling ne = 1, suggesting a mixed correlated insulating state between the two limits. Our studies establish semiconducting moire superlattices as an intriguing platform for engineering bosonic phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 51, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2023, "Volume": 380, "Issue": 6647, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 860, "End Page": 864, "Article Number": null, "DOI": "10.1126/science.add5574", "DOI Link": "http://dx.doi.org/10.1126/science.add5574", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001476900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, FF; Chen, XL; Zhang, M; Jin, WQ; Han, SJ; Yang, ZH; Pan, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fangfang; Chen, Xinglong; Zhang, Min; Jin, Wenqi; Han, Shujuan; Yang, Zhihua; Pan, Shilie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Birefringent materials play indispensable roles in modulating the polarization of light and are vital in the laser science and technology. Currently, the design of birefringent materials operating in the deep-ultraviolet region (DUV, lambda <= 200 nm) is still a great challenge. In this work, we developed a new DUV birefringent crystal LiBO2 based on [BO2](infinity) infinite chains in the Li-B-O system, which simultaneously achieves the shortest UV cutoff edge (164 nm) and the largest birefringence (>= 0.168 at 266 nm) among all the reported borate-based DUV birefringent materials. Single crystals of LiBO2 with dimensions up to o55 x 34 mm(3) were grown by the Czochralski method, providing access to large-sized single crystal with low cost. Moreover, it has a high laser damage threshold and stable physicochemical properties. These outstanding characters unambiguously support that LiBO2 can be an excellent birefringent material for DUV application.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 12", "Publication Year": 2022, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 252, "DOI": "10.1038/s41377-022-00941-2", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-00941-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000839646600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, X; Li, CH; Ding, WF; Chen, Y; Mao, C; Xu, XF; Liu, B; Wang, DZ; Li, HN; Zhang, YB; Said, Z; Debnath, S; Jamil, M; Ali, HM; Sharma, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Xin; Li, Changhe; Ding, Wenfeng; Chen, Yun; Mao, Cong; Xu, Xuefeng; Liu, Bo; Wang, Dazhong; Li, Hao null; Zhang, Yanbin; Said, Zafar; Debnath, Sujan; Jamil, Muhammad; Ali, Hafiz Muhammad; Sharma, Shubham", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimum quantity lubrication machining of aeronautical materials using carbon group nullolubricant: From mechanisms to application", "Source Title": "CHINESE JOURNAL OF AERONAUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is an inevitable trend of sustainable manufacturing to replace flood and dry machining with minimum quantity lubrication (MQL) technology. Nevertheless, for aeronautical difficult-to -machine materials, MQL couldn't meet the high demand of cooling and lubrication due to high heat generation during machining. nullo-biolubricants, especially non-toxic carbon group nullo-enhancers (CGNs) are used, can solve this technical bottleneck. However, the machining mecha-nisms under lubrication of CGNs are unclear at complex interface between tool and workpiece, which characterized by high temperature, pressure, and speed, limited its application in factories and necessitates in-depth understanding. To fill this gap, this study concentrates on the comprehen-sive quantitative assessment of tribological characteristics based on force, tool wear, chip, and sur-face integrity in titanium alloy and nickel alloy machining and attempts to answer mechanisms systematically. First, to establish evaluation standard, the cutting mechanisms and performance improvement behavior covering antifriction, antiwear, tool failure, material removal, and surface formation of MQL were revealed. Second, the unique film formation and lubrication behaviors of CGNs in MQL turning, milling, and grinding are concluded. The influence law of molecular structure and micromorphology of CGNs was also answered and optimized options were recom-mended by considering diverse boundary conditions. Finally, in view of CGNs limitations in MQL, the future development direction is proposed, which needs to be improved in thermal stabil-ity of lubricant, activity of CGNs, controllable atomization and transportation methods, and intel-ligent formation of processing technology solutions.(c) 2021 Chinese Society of Aeronautics and Astronautics. Production and hosting by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 35, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 85, "End Page": 112, "Article Number": null, "DOI": "10.1016/j.cja.2021.08.011", "DOI Link": "http://dx.doi.org/10.1016/j.cja.2021.08.011", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874676600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XW; Xu, HM; Liu, JY; Bi, CZ; Tian, JF; Zhong, K; Wang, B; Ding, PH; Wang, XZ; Chu, PK; Xu, H; Ding, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xingwang; Xu, Hangmin; Liu, Jinyuan; Bi, Chuanzhou; Tian, Jianfeng; Zhong, Kang; Wang, Bin; Ding, Penghui; Wang, Xiaozhi; Chu, Paul K.; Xu, Hui; Ding, Jianning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking Engineering of Heterojunctions in Half-Metallic Carbon Nitride for Efficient CO2 Photoreduction", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancing charge separation in semiconductor photocatalysts is a major challenge for efficient artificial photosynthesis. Herein, a compact heterojunction is designed by embedding half-metallic C(CN)(3) (hm-CN) hydrothermally in BiOBr (BOB) as the backbone. The interface between hm-CN and BOB is seamless and formed by covalent bonding to facilitate the transmission of photoinduced electrons from BOB to hm-CN. The transient photocurrents and electrochemical impedance spectra reveal that the modified composite catalyst exhibits a larger electron transfer rate. The photocatalytic activity of hm-CN/BOB increases significantly as indicated by a CO yield that is about four times higher than that of individual components. Density-functional theory calculations verify that the heterojunction improves electron transport and decreases the reaction energy barrier, thus promoting the overall photocatalytic CO2 conversion efficiency. The half-metal nitride coupled semiconductor heterojunctions might have large potential in artificial photosynthesis and related applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 10, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2307192, "DOI": "10.1002/advs.202307192", "DOI Link": "http://dx.doi.org/10.1002/advs.202307192", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001120836200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krenn, M; Häse, F; Nigam, AK; Friederich, P; Aspuru-Guzik, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krenn, Mario; Hase, Florian; Nigam, Akshat Kumar; Friederich, Pascal; Aspuru-Guzik, Alan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-referencing embedded strings (SELFIES): A 100% robust molecular string representation", "Source Title": "MACHINE LEARNING-SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The discovery of novel materials and functional molecules can help to solve some of society's most urgent challenges, ranging from efficient energy harvesting and storage to uncovering novel pharmaceutical drug candidates. Traditionally matter engineering-generally denoted as inverse design-was based massively on human intuition and high-throughput virtual screening. The last few years have seen the emergence of significant interest in computer-inspired designs based on evolutionary or deep learning methods. The major challenge here is that the standard strings molecular representation SMILES shows substantial weaknesses in that task because large fractions of strings do not correspond to valid molecules. Here, we solve this problem at a fundamental level and introduce SELFIES (SELF-referencIng Embedded Strings), a string-based representation of molecules which is 100% robust. Every SELFIES string corresponds to a valid molecule, and SELFIES can represent every molecule. SELFIES can be directly applied in arbitrary machine learning models without the adaptation of the models; each of the generated molecule candidates is valid. In our experiments, the model's internal memory stores two orders of magnitude more diverse molecules than a similar test with SMILES. Furthermore, as all molecules are valid, it allows for explanation and interpretation of the internal working of the generative models.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 442, "Times Cited, All Databases": 478, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45024, "DOI": "10.1088/2632-2153/aba947", "DOI Link": "http://dx.doi.org/10.1088/2632-2153/aba947", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000754876300026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dolgonos, A; Mason, TO; Poeppelmeier, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dolgonos, Alex; Mason, Thomas O.; Poeppelmeier, Kenneth R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct optical band gap measurement in polycrystalline semiconductors: A critical look at the Tauc method", "Source Title": "JOURNAL OF SOLID STATE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The direct optical band gap of semiconductors is traditionally measured by extrapolating the linear region of the square of the absorption curve to the x-axis, and a variation of this method, developed by Tauc, has also been widely used. The application of the Tauc method to crystalline materials is rooted in misconception-and traditional linear extrapolation methods are inappropriate for use on degenerate semiconductors, where the occupation of conduction band energy states cannot be ignored. A new method is proposed for extracting a direct optical band gap from absorption spectra of degenerately doped bulk semiconductors. This method was applied to pseudo-absorption spectra of Sn-doped In2O3 (ITO) converted from diffuse-reflectance measurements on bulk specimens. The results of this analysis were corroborated by room-temperature photoluminescence excitation measurements, which yielded values of optical band gap and Burstein-Moss shift that are consistent with previous studies on In2O3 single crystals and thin films. (C) 2016 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 240, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 43, "End Page": 48, "Article Number": null, "DOI": "10.1016/j.jssc.2016.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.jssc.2016.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378662800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wentker, M; Greenwood, M; Leker, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wentker, Marc; Greenwood, Matthew; Leker, Jens", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Bottom-Up Approach to Lithium-Ion Battery Cost Modeling with a Focus on Cathode Active Materials", "Source Title": "ENERGIES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, we develop a method for calculating electric vehicle lithium-ion battery pack performance and cost. To begin, we construct a model allowing for calculation of cell performance and material cost using a bottom-up approach starting with real-world material costs. It thus provides a supplement to existing models, which often begin with fixed cathode active material (CAM) prices that do not reflect raw metal price fluctuations. We collect and display data from the London Metal Exchange to show that such metal prices, in this case specifically cobalt and nickel, do indeed fluctuate and cannot be assumed to remain static or decrease consistently. We input this data into our model, which allows for a visualization of the effects of these metal price fluctuations on the prices of the CAMs. CAMs analyzed include various lithium transition metal oxide-type layered oxide (NMC and NCA) technologies, as well as cubic spinel oxide (LMO), high voltage spinel oxide (LNMO), and lithium metal phosphate (LFP). The calculated CAM costs are combined with additional cell component costs in order to calculate full cell costs, which are in turn scaled up to full battery pack costs. Economies of scale are accounted for separately for each cost fraction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2019, "Volume": 12, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 504, "DOI": "10.3390/en12030504", "DOI Link": "http://dx.doi.org/10.3390/en12030504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460666200172", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Niri, AJ; Poelzer, GA; Zhang, SE; Rosenkranz, J; Pettersson, M; Ghorbani, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Niri, Anahita Jannesar; Poelzer, Gregory A.; Zhang, Steven E.; Rosenkranz, Jan; Pettersson, Maria; Ghorbani, Yousef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sustainability challenges throughout the electric vehicle battery value chain", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The global commitment to decarbonizing the transport sector has resulted in an unabated growth in the markets for electric vehicles and their batteries. Consequently, the demand for battery raw materials is continuously growing. As an illustration, to meet the net-zero emissions targets, the electric vehicle market demand for lithium, cobalt, nickel, and graphite will increase 26-times, 6-times, 12-times, and 9-times respectively between 2021 and 2050. There are diverse challenges in meeting this demand, requiring the world to embrace technological and knowledge advancements and new investments without provoking conflicts between competing goals. The uncertainties in a sustainable supply of battery minerals, environmental, social and governullce complexities, and geopolitical tensions throughout the whole battery value chain have shaped the global and regional concerns over the success of transport decarbonization. Here, focusing on the entire value chain of electric vehicle batteries, the approaches adopted by regulatory agencies, governments, mining companies, vehicle and battery manufacturers, and all the other stakeholders are evaluated. Bringing together all these aspects, this literature review broadens the scope for providing multifaceted solutions necessary to optimize the goal of transport decarbonization while upholding sustainability criteria. Consolidating the previously fragmented information, a solid foundation for more in-depth research on existing difficulties encountered by governmental and industrial actors is created. The outcomes of this study may serve as a baseline to develop a framework for a climate smart and resource efficient supply of batteries considering the unique impacts of individual players.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2024, "Volume": 191, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114176, "DOI": "10.1016/j.rser.2023.114176", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2023.114176", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001138163600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, JHY; Pak, AJ; Durumeric, AEP; Loose, TD; Voth, GA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Jaehyeok; Pak, Alexander J.; Durumeric, Aleksander E. P.; Loose, Timothy D.; Voth, Gregory A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bottom-up Coarse-Graining: Principles and Perspectives", "Source Title": "JOURNAL OF CHEMICAL THEORY AND COMPUTATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Early Access", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale computational molecular models provide scientists a means to investigate the effect of microscopic details on emergent mesoscopic behavior. Elucidating the relationship between variations on the molecular scale and macroscopic observable properties facilitates an understanding of the molecular interactions driving the properties of real world materials and complex systems (e.g., those found in biology, chemistry, and materials science). As a result, discovering an explicit, systematic connection between microscopic nature and emergent mesoscopic behavior is a fundamental goal for this type of investigation. The molecular forces critical to driving the behavior of complex heterogeneous systems are often unclear. More problematically, simulations of representative model systems are often prohibitively expensive from both spatial and temporal perspectives, impeding straightforward investigations over possible hypotheses characterizing molecular behavior. While the reduction in resolution of a study, such as moving from an atomistic simulation to that of the resolution of large coarse-grained (CG) groups of atoms, can partially ameliorate the cost of individual simulations, the relationship between the proposed microscopic details and this intermediate resolution is nontrivial and presents new obstacles to study. Small portions of these complex systems can be realistically simulated. Alone, these smaller simulations likely do not provide insight into collectively emergent behavior. However, by proposing that the driving forces in both smaller and larger systems (containing many related copies of the smaller system) have an explicit connection, systematic bottom-up CG techniques can be used to transfer CG hypotheses discovered using a smaller scale system to a larger system of primary interest. The proposed connection between different CG systems is prescribed by (i) the CG representation (mapping) and (ii) the functional form and parameters used to represent the CG energetics, which approximate potentials of mean force (PMFs). As a result, the design of CG methods that facilitate a variety of physically relevant representations, approximations, and force fields is critical to moving the frontier of systematic CG forward. Crucially, the proposed connection between the system used for parametrization and the system of interest is orthogonal to the optimization used to approximate the potential of mean force present in all systematic CG methods. The empirical efficacy of machine learning techniques on a variety of tasks provides strong motivation to consider these approaches for approximating the PMF and analyzing these approximations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 140, "Times Cited, All Databases": 146, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "2022 SEP 7", "Publication Year": 2022, "Volume": null, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1021/acs.jctc.2c00643", "DOI Link": "http://dx.doi.org/10.1021/acs.jctc.2c00643", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874973500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Verdi, C; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Verdi, Carla; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Frohlich Electron-Phonon Vertex from First Principles", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We develop a method for calculating the electron-phonon vertex in polar semiconductors and insulators from first principles. The present formalism generalizes the Frohlich vertex to the case of anisotropic materials and multiple phonon branches, and can be used either as a postprocessing correction to standard electron-phonon calculations, or in conjunction with ab initio interpolation based on maximally localized Wannier functions. We demonstrate this formalism by investigating the electron-phonon interactions in anatase TiO2, and show that the polar vertex significantly reduces the electron lifetimes and enhances the anisotropy of the coupling. The present work enables ab initio calculations of carrier mobilities, lifetimes, mass enhancement, and pairing in polar materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2015, "Volume": 115, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 176401, "DOI": "10.1103/PhysRevLett.115.176401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.115.176401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363243700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, ZM; Zhang, ZY; Liu, GB; Wu, WK; Li, XP; Zhang, RW; Yang, SYA; Yao, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhi-Ming; Zhang, Zeying; Liu, Gui-Bin; Wu, Weikang; Li, Xiao-Ping; Zhang, Run-Wu; Yang, Shengyuan A.; Yao, Yugui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encyclopedia of emergent particles in three-dimensional crystals", "Source Title": "SCIENCE BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The past decade has witnessed a surge of interest in exploring emergent particles in condensed matter systems. Novel particles, emerged as excitations around exotic band degeneracy points, continue to be reported in real materials and artificially engineered systems, but so far, we do not have a complete pic-ture on all possible types of particles that can be achieved. Here, via systematic symmetry analysis and modeling, we accomplish a complete list of all possible particles in time-reversal-invariant systems. This includes both spinful particles such as electron quasiparticles in solids, and spinless particles such as pho-nons or even excitations in electric-circuit and mechanical networks. We establish detailed correspon-dence between the particle, the symmetry condition, the effective model, and the topological character. This obtained encyclopedia concludes the search for novel emergent particles and provides concrete guidance to achieve them in physical systems. (c) 2021 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2022, "Volume": 67, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 375, "End Page": 380, "Article Number": null, "DOI": "10.1016/j.scib.2021.10.023", "DOI Link": "http://dx.doi.org/10.1016/j.scib.2021.10.023", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000760170600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuenneth, C; Ramprasad, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuenneth, Christopher; Ramprasad, Rampi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "polyBERT: a chemical language model to enable fully machine-driven ultrafast polymer informatics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymers are a vital part of everyday life. Their chemical universe is so large that it presents unprecedented opportunities as well as significant challenges to identify suitable application-specific candidates. We present a complete end-to-end machine-driven polymer informatics pipeline that can search this space for suitable candidates at unprecedented speed and accuracy. This pipeline includes a polymer chemical fingerprinting capability called polyBERT (inspired by Natural Language Processing concepts), and a multitask learning approach that maps the polyBERT fingerprints to a host of properties. polyBERT is a chemical linguist that treats the chemical structure of polymers as a chemical language. The present approach outstrips the best presently available concepts for polymer property prediction based on handcrafted fingerprint schemes in speed by two orders of magnitude while preserving accuracy, thus making it a strong candidate for deployment in scalable architectures including cloud infrastructures. The polymer universe is gigantic. Searching this space effectively requires ultrafast high-fidelity property prediction methods. Here, the authors present a chemical language model that can probe this space at unprecedented speed and accuracy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-39868-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39868-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001037937100029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gupta, M; Graziano, GV; Pendharkar, M; Dong, JT; Dempsey, CP; Palmstrom, C; Pribiag, VS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gupta, Mohit; Graziano, Gino V.; Pendharkar, Mihir; Dong, Jason T.; Dempsey, Connor P.; Palmstrom, Chris; Pribiag, Vlad S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable superconducting diode effect in a three-terminal Josephson device", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The phenomenon of non-reciprocal critical current in a Josephson device, termed the Josephson diode effect, has garnered much recent interest. Realization of the diode effect requires inversion symmetry breaking, typically obtained by spin-orbit interactions. Here we report observation of the Josephson diode effect in a three-terminal Josephson device based upon an InAs quantum well two-dimensional electron gas proximitized by an epitaxial aluminum superconducting layer. We demonstrate that the diode efficiency in our devices can be tuned by a small out-of-plane magnetic field or by electrostatic gating. We show that the Josephson diode effect in these devices is a consequence of the artificial realization of a current-phase relation that contains higher harmonics. We also show nonlinear DC intermodulation and simultaneous two-signal rectification, enabled by the multi-terminal nature of the devices. Furthermore, we show that the diode effect is an inherent property of multi-terminal Josephson devices, establishing an immediately scalable approach by which potential applications of the Josephson diode effect can be realized, agnostic to the underlying material platform. These Josephson devices may also serve as gate-tunable building blocks in designing topologically protected qubits. Non-reciprocal critical current in a Josephson junction device is known as the Josephson diode effect. Here, the authors observe such an effect in 3-terminal Josephson devices based on InAs two-dimensional electron gas proximitized by an epitaxial Al layer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 29", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3078, "DOI": "10.1038/s41467-023-38856-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38856-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001029731000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Omer, AS; El Naeem, GA; Abd-Elhamid, AI; Farahat, OOM; El-Bardan, AA; Soliman, HMA; Nayl, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Omer, Alaa Salah; El Naeem, Gamal A.; Abd-Elhamid, A. I.; Farahat, Omaima O. M.; El-Bardan, Ali A.; Soliman, Hesham M. A.; Nayl, A. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of crystal violet and methylene blue dyes using a cellulose-based adsorbent from sugercane bagasse: characterization, kinetic and isotherm studies", "Source Title": "JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biodegradable cellulose based on sugarcane bagasse is produced using alkaline treatment followed by bleaching method for dye removal. FTIR, Raman, SEM, EDS, XRD, and N-2 adsorption-desorption isotherm analysis were utilized to characterize the surface morphology and functional groups of the sugarcane bagasse (SCB) and treated sugarcane bagasse (TSCB). The TSCB was investigated to remove of Crystal violet (CV) and Methylene blue (MB). Different factors influence the adsorption processes such as contact time, adsorbent dose, dye concentration, temperature, pH, and NaCl dose were studied. The Langmuir model was investigated to study the adsorption equilibrium behavior of CV and MB dyes by TSCB. A maximum adsorption capacities (q(max)) of 107.5 and 112.9 mgg(-1) was calculated for CV and MB-dyes, respectively. Also, the adsorption processes are physi-osorption with average energy values of E = 1.151 and 1.101 KJmol(-1) for CV and MB-dyes, respectively. The kinetic data of the investigated processes were controlled by the pseudo-second order (PSO) model with q(e,cal )(mgg(-1)) values of 59.3 and 58.9 mgg(-1) for CV and MB-dyes, respectively. Suggesting that chemical mechanisms may influence the removal of CV and MB dyes. Overall, TSCB was found to be an effective, environmentally friendly, and low-cost material to remove of cationic dyes in this research. (c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2022, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3241, "End Page": 3254, "Article Number": null, "DOI": "10.1016/j.jmrt.2022.06.045", "DOI Link": "http://dx.doi.org/10.1016/j.jmrt.2022.06.045", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000828332300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nakayama, K; Li, YK; Kato, T; Liu, M; Wang, ZW; Takahashi, T; Yao, YG; Sato, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nakayama, Kosuke; Li, Yongkai; Kato, Takemi; Liu, Min; Wang, Zhiwei; Takahashi, Takashi; Yao, Yugui; Sato, Takafumi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multiple energy scales and anisotropic energy gap in the charge-density-wave phase of the kagome superconductor CsV3Sb5", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Kagome metals AV(3)Sb(5) (A = K, Rb, and Cs) exhibit superconductivity at 0.9-2.5 K and charge-density wave (CDW) at 78-103 K. Key electronic states associated with the CDW and superconductivity remain elusive. Here, we investigate low-energy excitations of CsV3Sb5 by angle-resolved photoemission spectroscopy. We found an energy gap of 50-70 meV at the Dirac-crossing points of linearly dispersive bands, pointing to an importance of spin-orbit coupling. We also found a signature of strongly Fermi-surface and momentum-dependent CDW gap characterized by the larger energy gap of maximally 70 meV for a band forming a saddle point around the M point, the smaller (0-18 meV) gap for a band forming massive Dirac cones and a zero gap at the Gamma/A-centered electron pocket. The observed highly anisotropic CDW gap which is enhanced around the M point signifies an importance of scattering channel connecting the saddle points, laying foundation for understanding the nature of CDW and superconductivity in AV(3)Sb(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2021, "Volume": 104, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "L161112", "DOI": "10.1103/PhysRevB.104.L161112", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.104.L161112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000711297800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Trukhanov, AV; Tishkevich, DI; Podgornaya, SV; Kaniukov, E; Darwish, MA; Zubar, TI; Timofeev, AV; Trukhanova, EL; Kostishin, VG; Trukhanov, SV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Trukhanov, Alex V.; Tishkevich, Daria I.; Podgornaya, Svetlana V.; Kaniukov, Egor; Darwish, Moustafa A.; Zubar, Tatiana I.; Timofeev, Andrey V.; Trukhanova, Ekaterina L.; Kostishin, Vladimir G.; Trukhanov, Sergei V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of the nullocarbon on Magnetic and Electrodynamic Properties of the Ferrite/Polymer Composites", "Source Title": "nullOMATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Binary and ternary composites (CM) based on M-type hexaferrite (HF), polymer matrix (PVDF) and carbon nullomaterials (quasi-one-dimensional carbon nullotubes-CNT and quasi-two-dimensional carbon nulloflakes-CNF) were prepared and investigated for establishing the impact of the different nullosized carbon on magnetic and electrodynamic properties. The ratio between HF and PVDF in HF + PVDF composite was fixed (85 wt% HF and 15 wt% PVDF). The concentration of CNT and CNF in CM was fixed (5 wt% from total HF + PVDF weight). The phase composition and microstructural features were investigated using XRD and SEM, respectively. It was observed that CM contains single-phase HF, gamma- and beta-PVDF and carbon nullomaterials. Thus, we produced composites that consist of mixed different phases (organic insulator matrix-PDVF; functional magnetic fillers-HF and highly electroconductive additives-CNT/CNF) in the required ratio. VSM data demonstrate that the main contribution in main magnetic characteristics belongs to magnetic fillers (HF). The principal difference in magnetic and electrodynamic properties was shown for CNT- and CNF-based composites. That confirms that the shape of nullosized carbon nullomaterials impact on physical properties of the ternary composited-based magnetic fillers in polymer dielectric matrix.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 12, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 868, "DOI": "10.3390/nullo12050868", "DOI Link": "http://dx.doi.org/10.3390/nullo12050868", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000769446300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ozcelikci, E; Kul, A; Gunal, MF; Ozel, BF; Yildirim, G; Ashour, A; Sahmaran, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozcelikci, Emircan; Kul, Anil; Gunal, Muhammed Faruk; Ozel, Behlul Furkan; Yildirim, Gurkan; Ashour, Ashraf; Sahmaran, Mustafa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A comprehensive study on the compressive strength, durability-related parameters and microstructure of geopolymer mortars based on mixed construction and demolition waste", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a viable option to upcycle construction and demolition waste (CDW) into value-added materials, geopolymer technology is emerging. Most studies investigate CDWs in a separated form or in combination with mainstream pozzolanic/cementitious materials focusing only on fundamental properties of geopolymer pastes, not consid-ering to scale such materials to the level of their application in the forms of structural mortars/concretes or to characterize long-term performance/durability. This study investigated the development and characterization of ambient-cured mortars with mixed CDW-based geopolymer binders and untreated fine recycled concrete ag-gregates (FRCA). Mixture of CDW-based roof tile (RT), red clay brick (RCB), hollow brick (HB), concrete (C), and glass (G) was used as the precursor, while ground granulated blast furnace slag (S) was used in some mixtures to partly replace CDW precursors. Compressive strength, durability-related parameters including drying shrinkage, water absorption, and efflorescence, microstructure and materials sustainability were evaluated. Results showed that 28 d compressive strength results above 30 and 50 MPa are achievable with the entirely CDW-based and slag-substituted mortars, which were found improvable to have entirely CDW-based structural concretes. Drying shrinkage of the mortars is slightly higher than that of conventional cementitious/geopolymeric systems although it can be minimized significantly through mixture optimization. Water absorption values remain comparable with the literature. CDW-based geopolymer mortars outperform Portland cement mortars in terms of CO2 emission and energy requirement. Our findings show that via utilizing CDW-based constituents in mixed form as precursor and waste aggregates, it is possible to develop greener construction materials with acceptable strength and long-term performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2023, "Volume": 396, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136522, "DOI": "10.1016/j.jclepro.2023.136522", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2023.136522", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000946603600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Serrano-Lotina, A; Portela, R; Baeza, P; Alcolea-Rodriguez, V; Villarroel, M; Avila, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Serrano-Lotina, A.; Portela, R.; Baeza, P.; Alcolea-Rodriguez, V.; Villarroel, M.; Avila, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zeta potential as a tool for functional materials development?", "Source Title": "CATALYSIS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The importance of the isoelectric point for the preparation and characterization of functional materials to understand their behavior and optimize their performance is highlighted, with especial focus on industrial catalysts. In different liquid-phase steps involved in materials synthesis, the knowledge of the surface charge as a function of the pH of the medium is fundamental, since it is the dynamizing agent of processes such as gelation, peptization, coagulation and agglomeration to form solid particles. Therefore, zeta potential (& zeta;) measurements, often based on electrophoretic migration techniques, are a powerful source of information. The basic principles are introduced to explain through relevant examples the possibilities for materials design. Regarding materials preparation, the measurement of the zeta potential to control the synthesis and coating of supports is reviewed, with special attention to shaped supports. Aspects as the influence of the binders on the supports properties depending on their mutual interaction are analyzed, with example systems based on TiO2 or Al2O3 and natural silicates such as sepiolite. Also, how the knowledge of & zeta; as a function of pH allows, by choosing the appropriate pH, the preferential impregnation of noble metals on porous supports, as well as the washcoating of dense ceramic monoliths with porous supports. Special attention has been paid to surfaces characterization based on the use of zeta potential measurements to estimate the formation and relative location of species, the apparent surface coverage, or the adsorption and reactivity, to establish synthesis strategies to achieve specific properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2023, "Volume": 423, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113862, "DOI": "10.1016/j.cattod.2022.08.004", "DOI Link": "http://dx.doi.org/10.1016/j.cattod.2022.08.004", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001063534400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bellifa, H; Benrahou, KH; Hadji, L; Houari, MSA; Tounsi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bellifa, Hichem; Benrahou, Kouider Halim; Hadji, L.; Houari, Mohammed Sid Ahmed; Tounsi, Abdelouahed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bending and free vibration analysis of functionally graded plates using a simple shear deformation theory and the concept the neutral surface position", "Source Title": "JOURNAL OF THE BRAZILIAN SOCIETY OF MECHANICAL SCIENCES AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new first-order shear deformation theory is developed for bending and dynamic behaviors of functionally graded plates. Moreover, the number of unknowns of this theory is the least one comparing with the traditional first-order and the other higher order shear deformation theories. The equations governing the axial and transverse deformations of functionally graded plates are derived based on the present first-order shear deformation plate theory and the physical neutral surface concept. There is no stretching-bending coupling effect in the neutral surface-based formulation, and consequently, the governing equations and boundary conditions of functionally graded plates based on neutral surface have the simple forms as those of isotropic plates. To examine accuracy of the present formulation, several comparison studies are investigated. It can be concluded that the proposed theory is accurate and simple in solving the static bending and free vibration behaviors of functionally graded plates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 320, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 38, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 275, "Article Number": null, "DOI": "10.1007/s40430-015-0354-0", "DOI Link": "http://dx.doi.org/10.1007/s40430-015-0354-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367457400021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hrstka, T; Gottlieb, P; Skála, R; Breiter, K; Motl, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hrstka, Tomas; Gottlieb, Paul; Skala, Roman; Breiter, Karel; Motl, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Automated mineralogy and petrology - applications of TESCAN Integrated Mineral Analyzer (TIMA)", "Source Title": "JOURNAL OF GEOSCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The collection of representative modal mineralogy data as well as textural and chemical information on statistically significant samples is becoming essential in many areas of Earth and material sciences. Automated Scanning Electron Microscopy (ASEM) systems provide an ideal solution for such tasks. This paper presents the methods and techniques used in the recently developed TESCAN Integrated Mineral Analyzer (TIMA-X) with Version 1.5 TIMA software. The benefits from the use of a fully integrated quantitative energy-dispersive X-ray spectrometry (EDS) and an advanced statistical approach to ASEM systems are demonstrated. Typically, the system can handle more than 500,000 X-ray events per second. Using a common spectral total of 1000 events this represents the acquisition of 500 spectra per second. A number of measurement modes is available to make the most effective use of these spectra depending on the application. For a back-scattered electrons (BSE) map combined with EDS data with spatial resolution of 10 mu m, this represents the high-resolution measurement of c. 1 cm(2) of a thin section or a polished rock surface in 30 minutes. A patented X-ray spectrum clustering algorithm that lowers the chemical detection limit is described and an example of its use is shown. The modal and textural (liberation, association, size etc.) data produced are statistically robust and provide information across a broad range of Earth and material sciences. A comparison with some other available instruments is also provided together with a number of case studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 63, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 47, "End Page": 63, "Article Number": null, "DOI": "10.3190/jgeosci.250", "DOI Link": "http://dx.doi.org/10.3190/jgeosci.250", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics; Mineralogy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431459800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CX; Wang, ZH; Bo, RF; Li, CY; Meng, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Chenxi; Wang, Zihe; Bo, Renfei; Li, Canyang; Meng, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of the cooling clothing integrating with phase change material on the thermal comfort of healthcare workers with personal protective equipment during the COVID-19", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearing Personal Protective Equipment (PPE) is essential to protect healthcare workers during the COVID-19, but the traditional cooling methods do not meet the requirements of epidemic prevention during the COVID-19. Therefore, the cooling clothing integrated with phase change material (PCM-CC) was proposed for healthcare workers performing nucleic acid sample collec-tion outdoors. Human experiments and subjective questionnaires were used to test the effect of wearing PCM-CC on the thermal sensations of healthcare workers and to analyze the effectiveness of PCM-CC in relieving thermal stress and thereby, improving the thermal comfort of healthcare workers. Results showed that wearing PCM-CC was effective in alleviating various heat symptoms associated with wearing PPE in a hot-temperature environment. Wearing PCM-CC reduced head and facial discomfort by 25% and 41% under the 26 degrees C thermal environment, while it improved the mean thermal sensation vote (TSV) values by 0.71 and 1.85 under the 26 degrees C and 32 degrees C thermal environments, respectively, and made the mean TSV value close to the neutral value. Meanwhile, wearing PCM-CC reduced mean skin temperatures by 0.65 degrees C, and the pronounced cooling effect was found in the chest. Wearing PCM-CC could be an effective thermoregulation measure to refine the thermal comfort of healthcare workers during the COVID-19 pandemic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 42, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102725, "DOI": "10.1016/j.csite.2023.102725", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2023.102725", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000924415300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, HX; Nguyen, TN; Abdel-Wahab, M; Bordas, SPA; Nguyen-Xuan, H; Vo, TP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, Hoang X.; Nguyen, Than N.; Abdel-Wahab, M.; Bordas, S. P. A.; Nguyen-Xuan, H.; Vo, Thuc P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A refined quasi-3D isogeometric analysis for functionally graded microplates based on the modified couple stress theory", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The isogeometric analysis associated with a novel quasi-3D shear deformation theory is proposed to investigate size-dependent behaviours of functionally graded microplates. The modified couple stress theory with only one material length scale parameter is employed to effectively capture the size-dependent effects within the microplates. Meanwhile, the quasi-3D theory which is constructed from a novel seventh-order shear deformation refined plate theory with four unknowns is able to consider both shear deformations and thickness stretching effect without requiring shear correction factors. The NURBS-based isogeometric analysis is integrated to exactly describe the geometry and approximately calculate the unknown fields with higher-order derivative and continuity requirements. The proposed approach is successfully applied to study the static bending, free vibration and buckling responses of rectangular and circular functionally graded microplates with various types of boundary conditions in which some benchmark numerical examples are presented. A number of investigations are also conducted to illustrate the effects of the material length scale, material index, and aspect ratios on the responses of the microplates. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 257, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2017, "Volume": 313, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 904, "End Page": 940, "Article Number": null, "DOI": "10.1016/j.cma.2016.10.002", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.10.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390740900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dodaro, JF; Kivelson, SA; Schattner, Y; Sun, XQ; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dodaro, J. F.; Kivelson, S. A.; Schattner, Y.; Sun, X. Q.; Wang, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phases of a phenomenological model of twisted bilayer graphene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a lattice-scale two-band generalized Hubbard model as a caricature of the electronic structure of twisted bilayer graphene. Various possible broken-symmetry phases can arise, including a nematic phase (which is a form of orbital ferromagnet) and an orbital-triplet spin-singlet superconducting phase. Concerning the mechanism of superconductivity, we propose an analogy with superconductivity in alkali-doped C-60 in which a violation of Hund's first rule plays a central role.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2018, "Volume": 98, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75154, "DOI": "10.1103/PhysRevB.98.075154", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.98.075154", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442874400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wittbrodt, B; Pearce, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wittbrodt, Ben; Pearce, Joshua M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The effects of PLA color on material properties of 3-D printed components", "Source Title": "ADDITIVE MANUFACTURING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the number of prosumer printers has expanded rapidly, they now make up the majority of the 3-D printer market and of these printers those in the open-source lineage of the RepRap also have expanded to dominate. Although still primarily used for prototyping or hobbyist production of low-value products, the RepRap has the capacity to be used for high-value distributed manufacturing. A recent study found that RepRap printed parts printed in realistic environmental conditions can match and even out perform commercial 3-D printers using proprietary FDM in terms of tensile strength with the same polymers. However, tensile strengths of the large sample set of RepRap prints fluctuated. In order to explain that fluctuation and better inform designers on RepRap print properties this study determines the effect of color and processing temperature on material properties of Lulzbot TAZ deposited PLA in various colors. Five colors (white, black, blue, gray, and natural) of commercially available filament processed from 4043D PLA is tested for crystallinity with XRD, tensile strength following ASTM D638 and the microstructure is evaluated with environmental scanning electron microscope. Results are presented showing a strong relationship between tensile strength and percent crystallinity of a 3-D printed sample and a strong relationship between percent crystallinity and the extruder temperature. Conclusions are drawn about the effects of color and processing temperature on the material properties of 3-D printed PLA to promote the open-source development of RepRap 3-D printing. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 110, "End Page": 116, "Article Number": null, "DOI": "10.1016/j.addma.2015.09.006", "DOI Link": "http://dx.doi.org/10.1016/j.addma.2015.09.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435752400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, R; Xia, HS; He, WF; Li, ZC; Zhao, J; Liu, B; Wang, YZ; Lei, Q; Kong, Y; Bai, Y; Yao, ZH; Yan, RS; Li, HS; Zhan, RX; Yang, SS; Luo, GX; Wu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Rui; Xia, Hesheng; He, Weifeng; Li, Zhichao; Zhao, Jian; Liu, Bo; Wang, Yuzhen; Lei, Qiang; Kong, Yi; Bai, Yang; Yao, Zhihui; Yan, Rongshuai; Li, Haisheng; Zhan, Rixing; Yang, Sisi; Luo, Gaoxing; Wu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Controlled water vapor transmission rate promotes wound-healing via wound re-epithelialization and contraction enhancement", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A desirable microenvironment is essential for wound healing, in which an ideal moisture content is one of the most important factors. The fundamental function and requirement for wound dressings is to keep the wound at an optimal moisture. Here, we prepared serial polyurethane (PU) membrane dressings with graded water vapor transmission rates (WVTRs), and the optimal WVTR of the dressing for wound healing was identified by both in vitro and in vivo studies. It was found that the dressing with a WVTR of 2028.3 +/- 237.8 g/m(2).24 h was able to maintain an optimal moisture content for the proliferation and regular function of epidermal cells and fibroblasts in a three-dimensional culture model. Moreover, the dressing with this optimal WTVR was found to be able to promote wound healing in a mouse skin wound model. Our finds may be helpful in the design of wound dressing for wound regeneration in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 18", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24596, "DOI": "10.1038/srep24596", "DOI Link": "http://dx.doi.org/10.1038/srep24596", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374253100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, WJ; Shen, BW; Tao, Z; Han, ZD; Kang, KF; Watanabe, K; Taniguchi, T; Mak, KF; Shan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Wenjin; Shen, Bowen; Tao, Zui; Han, Zhongdong; Kang, Kaifei; Watanabe, Kenji; Taniguchi, Takashi; Mak, Kin Fai; Shan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gate-tunable heavy fermions in a moire Kondo lattice", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Kondo lattice-a matrix of local magnetic moments coupled through spin-exchange interactions to itinerant conduction electrons-is a prototype of strongly correlated quantum matter(1-4). Usually, Kondo lattices are realized in intermetallic compounds containing lanthanide or actinide(1,2). The complex electronic structure and limited tunability of both the electron density and exchange interactions in these bulk materials pose considerable challenges to studying Kondo lattice physics. Here we report the realization of a synthetic Kondo lattice in AB-stacked MoTe2/WSe2 moire bilayers, in which the MoTe2 layer is tuned to a Mott insulating state, supporting a triangular moire lattice of local moments, and the WSe2 layer is doped with itinerant conduction carriers. We observe heavy fermions with a large Fermi surface below the Kondo temperature. We also observe the destruction of the heavy fermions by an external magnetic field with an abrupt decrease in the Fermi surface size and quasi-particle mass. We further demonstrate widely and continuously gate-tunable Kondo temperatures through either the itinerant carrier density or the Kondo interaction. Our study opens the possibility of in situ access to the phase diagram of the Kondo lattice with exotic quantum criticalities in a single device based on semiconductor moire materials(2-9).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2023, "Volume": 616, "Issue": 7955, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 61, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-05800-7", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05800-7", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952592600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yokoyama, T; Nagashima, K; Nakai, I; Young, ED; Abe, Y; Aleon, J; Alexander, CMO; Amari, S; Amelin, Y; Bajo, KI; Bizzarro, M; Bouvier, A; Carlson, RW; Chaussidon, M; Choi, BG; Dauphas, N; Davis, AM; Di Rocco, T; Fujiya, W; Fukai, R; Gautam, I; Haba, MK; Hibiya, Y; Hidaka, H; Homma, H; Hoppe, P; Huss, GR; Ichida, K; Iizuka, T; Ireland, TR; Ishikawa, A; Ito, M; Itoh, S; Kawasaki, N; Kita, NT; Kitajima, K; Kleine, T; Komatani, S; Krot, AN; Liu, MC; Masuda, Y; McKeegan, KD; Morita, M; Motomura, K; Moynier, F; Nguyen, A; Nittler, L; Onose, M; Pack, A; Park, C; Piani, L; Qin, LP; Russell, SS; Sakamoto, N; Schoenbaechler, M; Tafla, L; Tang, HL; Terada, K; Terada, Y; Usui, T; Wada, S; Wadhwa, M; Walker, RJ; Yamashita, K; Yin, QZ; Yoneda, S; Yui, H; Zhang, AC; Connolly, HC Jr; Lauretta, DS; Nakamura, T; Naraoka, H; Noguchi, T; Okazaki, R; Sakamoto, K; Yabuta, H; Abe, M; Arakawa, M; Fujii, A; Hayakawa, M; Hirata, N; Hirata, N; Honda, R; Honda, C; Hosoda, S; Iijima, Y; Ikeda, H; Ishiguro, M; Ishihara, Y; Iwata, T; Kawahara, K; Kikuchi, S; Kitazato, K; Matsumoto, K; Matsuoka, M; Michikami, T; Mimasu, Y; Miura, A; Morota, T; Nakazawa, S; Namiki, N; Noda, H; Noguchi, R; Ogawa, N; Ogawa, K; Okada, T; Okamoto, C; Ono, G; Ozaki, M; Saiki, T; Sakatani, N; Sawada, H; Senshu, H; Shimaki, Y; Shirai, K; Sugita, S; Takei, Y; Takeuchi, H; Tanaka, S; Tatsumi, E; Terui, F; Tsuda, Y; Tsukizaki, R; Wada, K; Watanabe, SI; Yamada, M; Yamada, T; Yamamoto, Y; Yano, H; Yokota, Y; Yoshihara, K; Yoshikawa, M; Yoshikawa, K; Furuya, S; Hatakeda, K; Hayashi, T; Hitomi, Y; Kumagai, K; Miyazaki, A; Nakato, A; Nishimura, M; Soejima, H; Suzuki, A; Yada, T; Yamamoto, D; Yogata, K; Yoshitake, M; Tachibana, S; Yurimoto, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yokoyama, Tetsuya; Nagashima, Kazuhide; Nakai, Izumi; Young, Edward D.; Abe, Yoshinari; Aleon, Jerome; Alexander, Conel M. O'D.; Amari, Sachiko; Amelin, Yuri; Bajo, Ken-ichi; Bizzarro, Martin; Bouvier, Audrey; Carlson, Richard W.; Chaussidon, Marc; Choi, Byeon-Gak; Dauphas, Nicolas; Davis, Andrew M.; Di Rocco, Tommaso; Fujiya, Wataru; Fukai, Ryota; Gautam, Ikshu; Haba, Makiko K.; Hibiya, Yuki; Hidaka, Hiroshi; Homma, Hisashi; Hoppe, Peter; Huss, Gary R.; Ichida, Kiyohiro; Iizuka, Tsuyoshi; Ireland, Trevor R.; Ishikawa, Akira; Ito, Motoo; Itoh, Shoichi; Kawasaki, Noriyuki; Kita, Noriko T.; Kitajima, Kouki; Kleine, Thorsten; Komatani, Shintaro; Krot, Alexander N.; Liu, Ming-Chang; Masuda, Yuki; McKeegan, Kevin D.; Morita, Mayu; Motomura, Kazuko; Moynier, Frederic; Nguyen, Ann; Nittler, Larry; Onose, Morihiko; Pack, Andreas; Park, Changkun; Piani, Laurette; Qin, Liping; Russell, Sara S.; Sakamoto, Naoya; Schoenbaechler, Maria; Tafla, Lauren; Tang, Haolan; Terada, Kentaro; Terada, Yasuko; Usui, Tomohiro; Wada, Sohei; Wadhwa, Meenakshi; Walker, Richard J.; Yamashita, Katsuyuki; Yin, Qing-Zhu; Yoneda, Shigekazu; Yui, Hiroharu; Zhang, Ai-Cheng; Connolly Jr, Harold C.; Lauretta, Dante S.; Nakamura, Tomoki; Naraoka, Hiroshi; Noguchi, Takaaki; Okazaki, Ryuji; Sakamoto, Kanako; Yabuta, Hikaru; Abe, Masanao; Arakawa, Masahiko; Fujii, Atsushi; Hayakawa, Masahiko; Hirata, Naoyuki; Hirata, Naru; Honda, Rie; Honda, Chikatoshi; Hosoda, Satoshi; Iijima, Yu-ichi; Ikeda, Hitoshi; Ishiguro, Masateru; Ishihara, Yoshiaki; Iwata, Takahiro; Kawahara, Kosuke; Kikuchi, Shota; Kitazato, Kohei; Matsumoto, Koji; Matsuoka, Moe; Michikami, Tatsuhiro; Mimasu, Yuya; Miura, Akira; Morota, Tomokatsu; Nakazawa, Satoru; Namiki, Noriyuki; Noda, Hirotomo; Noguchi, Rina; Ogawa, Naoko; Ogawa, Kazunori; Okada, Tatsuaki; Okamoto, Chisato; Ono, Go; Ozaki, Masanobu; Saiki, Takanao; Sakatani, Naoya; Sawada, Hirotaka; Senshu, Hiroki; Shimaki, Yuri; Shirai, Kei; Sugita, Seiji; Takei, Yuto; Takeuchi, Hiroshi; Tanaka, Satoshi; Tatsumi, Eri; Terui, Fuyuto; Tsuda, Yuichi; Tsukizaki, Ryudo; Wada, Koji; Watanabe, Sei-ichiro; Yamada, Manabu; Yamada, Tetsuya; Yamamoto, Yukio; Yano, Hajime; Yokota, Yasuhiro; Yoshihara, Keisuke; Yoshikawa, Makoto; Yoshikawa, Kent; Furuya, Shizuho; Hatakeda, Kentaro; Hayashi, Tasuku; Hitomi, Yuya; Kumagai, Kazuya; Miyazaki, Akiko; Nakato, Aiko; Nishimura, Masahiro; Soejima, Hiromichi; Suzuki, Ayako; Yada, Toru; Yamamoto, Daiki; Yogata, Kasumi; Yoshitake, Miwa; Tachibana, Shogo; Yurimoto, Hisayoshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Samples returned from the asteroid Ryugu are similar to Ivuna-type carbonaceous meteorites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measured the mineralogy and bulk chemical and isotopic compositions of Ryugu samples. The samples are mainly composed of materials similar to those of carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominulltly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37 degrees +/- 10 degrees C, about 5.2(-0.7)(+0.8) million (statistical) or 5.2(-2.1)(+1.6) million (systematic) years after the formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above similar to 100 degrees C. The samples have a chemical composition that more closely resembles that of the Sun's photosphere than other natural samples do.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2023, "Volume": 379, "Issue": 6634, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 786, "End Page": "+", "Article Number": "eabn7850", "DOI": "10.1126/science.abn7850", "DOI Link": "http://dx.doi.org/10.1126/science.abn7850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000981670800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, HY; Gong, HM; Jin, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Hongying; Gong, Haiming; Jin, Zhiliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In2O3-Modified Three-Dimensional nulloflower MoSx Form S-scheme Heterojunction for Efficient Hydrogen Production", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Morphology regulation and the improvement of carrier separation efficiency are important strategies for the preparation of photocatalysts with excellent performance. MoSx with a three-dimensional (3D) nulloflower morphology formed by nullosheet stacking was prepared by a simple hydrothermal method, and MoSx/In2O3 with good hydrogen evolution activity was obtained by coupling with In2O3. The preparation of the three-dimensional nulloflower morphology combined with the construction of an S-scheme heterojunction improves the electron accumulation at the active site for hydrogen evolution reaction. The UV diffuse reflection test showed that the issue of poor light absorption of In2O3 was improved. The rapid separation and transfer of electrons were effectively confirmed by characterization methods such as fluorescence spectroscopy and electrochemical tests. The most intuitively manifestation of the performance improvement of the composite material is that the optimal hydrogen evolution rate reached 6704.2 mu mol.g(-1).h(-1), which is 1.8 times that of pure MoSx. Therefore, in this study, a new idea for the development of molybdenum-based sulfides for photocatalytic hydrogen production is provided.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2022, "Volume": 38, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2201037, "DOI": "10.3866/PKU.WHXB202201037", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202201037", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000908422100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CX; Xi, MH; Huo, JR; He, CZ; Fu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chenxu; Xi, Menghui; Huo, Jinrong; He, Chaozheng; Fu, Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Computational design of BC3N2 based single atom catalyst for dramatic activation of inert CO2 and CH4 gasses into CH3COOH with ultralow CH4 dissociation barrier", "Source Title": "CHINESE CHEMICAL LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The production of CH3COOH from CO2 and CH4 has stimulated much interest due to the high energy den-sity of C-2 species. Various kinds of catalysts have been developed while the high dissociation barrier of CH4 and low selectivity still hinders the efficiency of the reaction. We have herein proposed a novel cata-lyst with single metals loaded on 2D BC3N2 substrate (M@2D-BC3N2) based on density functional theory. Among numerous candidates, Pt@2D-BC3N2 possesses the most favorable reactivity with an ultralow bar-rier of CH4 splitting (0.26 eV), which is due to the efficient capture ability of CH4 on Pt site. Besides, the selectivity for CH3COOH is also very high, which mainly stems from the unique electronic properties of molecules and substrate: The degenerated states, including s, px, py and pz, in CO2 reflects the existence of delocalized pi bonds between C and O. This can interact with states of Pt(s), Pt(pz), Pt(dxz), Pt(dyz),and Pt(z(2)) in Pt@2D-BC3N2. The kinetics model also proves that our system can promote CH3COOH production via simply increasing the temperature or the coverage of CH4 and CO2. Our results provide a reasonable illustration in clarifying mechanism and propose promising candidates with high reactivity for further study. (C) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 87, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 34, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.cclet.2022.02.018", "DOI Link": "http://dx.doi.org/10.1016/j.cclet.2022.02.018", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000893634100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, R; Lan, J; Shuaibi, M; Wood, BM; Goyal, S; Das, A; Heras-Domingo, J; Kolluru, A; Rizvi, A; Shoghi, N; Sriram, A; Therrien, F; Abed, J; Voznyy, O; Sargent, EH; Ulissi, Z; Zitnick, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tran, Richard; Lan, Janice; Shuaibi, Muhammed; Wood, Brandon M.; Goyal, Siddharth; Das, Abhishek; Heras-Domingo, Javier; Kolluru, Adeesh; Rizvi, Ammar; Shoghi, Nima; Sriram, Anuroop; Therrien, Felix; Abed, Jehad; Voznyy, Oleksandr; Sargent, Edward H.; Ulissi, Zachary; Zitnick, C. . Lawrence", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Open Catalyst 2022 (OC22) Dataset and Challenges for Oxide Electrocatalysts", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of machine learning models for electrocatalysts requires a broad set of training data to enable their use across a wide variety of materials. One class of materials that currently lacks sufficient training data is oxides, which are critical for the development of Oxygen Evolution Reaction (OER) catalysts. To address this, we developed the Open Catalyst 2022 (OC22) dataset, consisting of 62,331 Density Functional Theory (DFT) relaxations (-9,854,504 single point calculations) across a range of oxide materials, coverages, and adsorbates. We define generalized total energy tasks that enable property prediction beyond adsorption energies; we test baseline performance of several graph neural networks; and we provide predefined dataset splits to establish clear benchmarks for future efforts. In the most general task, GemNet-OC sees a -36% improvement in energy predictions when combining the chemically dissimilar Open Catalyst 2020 Data set (OC20) and OC22 datasets via fine-tuning. Similarly, we achieved a -19% improvement in total energy predictions on OC20 and a -9% improvement in force predictions in OC22 when using joint training. We demonstrate the practical utility of a top performing model by capturing literature adsorption energies and important OER scaling relationships. We expect OC22 to provide an important benchmark for models seeking to incorporate intricate long-range electrostatic and magnetic interactions in oxide surfaces. Data set and baseline models are open sourced, and a public leaderboard is available to encourage continued community developments on the total energy tasks and data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2023, "Volume": 13, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3066, "End Page": 3084, "Article Number": null, "DOI": "10.1021/acscatal.2c05426", "DOI Link": "http://dx.doi.org/10.1021/acscatal.2c05426", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000937477800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JX; Euring, M; Ostendorf, K; Zhang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jiaxiu; Euring, Markus; Ostendorf, Kolja; Zhang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biobased materials for food packaging", "Source Title": "JOURNAL OF BIORESOURCES AND BIOPRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Consumers prefer foods that are healthier with high quality and safety. Food packaging are demanded to effectively extend the shelf-life, preserve the nutrients and decrease the microbial contamination during the transport and storage of food. With the increasing concern on the environmental impacts caused by food packaging wastes, sustainable and green packaging are highly demanded to minimize the harmful effects of food packaging waste on the environment. Bio-based materials are derived from sustainable and renewable biomass, instead of finite petrochemicals. The applications of bio-based materials for food packaging are highlighted in this review. The emphasis is placed on the categories of related biobased materials, their characteristics and advantages for food packaging, as well as the strategies used to improve their performances. Though a lot of trials have been done on biobased materials for food packaging, further attempts to improve their performances, understand the functioning mechanisms and develop greener methods for the production, processing and destiny of these bio-based materials are still highly needed for the future research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 13, "Article Number": null, "DOI": "10.1016/j.jobab.2021.11.004", "DOI Link": "http://dx.doi.org/10.1016/j.jobab.2021.11.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000996336300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, JJ; Agrawal, P; Rodrigues, TA; Lopes, JG; Schell, N; He, JJ; Zeng, Z; Mishra, RS; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Jiajia; Agrawal, Priyanka; Rodrigues, Tiago A.; Lopes, J. G.; Schell, N.; He, Jingjing; Zeng, Zhi; Mishra, Rajiv S.; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Microstructure evolution and mechanical properties in a gas tungsten arc welded Fe42Mn28Co10Cr15Si5 metastable high entropy alloy", "Source Title": "MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weldability studies on high entropy alloys are still relatively scarce, delaying the deployment of these materials into real-life applications. Thus, there is an urgent need for in-depth studies of the weldability of these novel advanced engineering alloys. In the current work, an as-cast Fe42Mn28Co10Cr15Si5 metastable high entropy alloy was welded for the first time using gas tungsten arc welding. The weld thermal cycle effect on the microstructure evolution over the welded joint was examined using electron microscopy in combination with electron back scatter diffraction, synchrotron X-ray diffraction analysis, and thermodynamic calculations. Furthermore, tensile testing and hardness mapping were correlated with the microstructure evolution. The microstructure evolution across the joint is unveiled, including the origin of the & epsilon;-h.c.p. phase at different locations of the material. Different strengthening effects measured throughout the joint are associated with the weld thermal cycle and resulting microstructure. A synergistic effect of smaller grain size of the & epsilon;-h.c.p. phase in the fusion zone, overturns the reduced volume fraction of this phase, increasing the local strength of the material. Moreover, the brittle nullosized & sigma; phase was also found to play a critical role in the joints' premature failure during mechanical testing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 76, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2023, "Volume": 867, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144722, "DOI": "10.1016/j.msea.2023.144722", "DOI Link": "http://dx.doi.org/10.1016/j.msea.2023.144722", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001032033100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoffmann, M; Zimmermann, B; Müller, GP; Schürhoff, D; Kiselev, NS; Melcher, C; Blügel, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hoffmann, Markus; Zimmermann, Bernd; Mueller, Gideon P.; Schuerhoff, Daniel; Kiselev, Nikolai S.; Melcher, Christof; Bluegel, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antiskyrmions stabilized at interfaces by anisotropic Dzyaloshinskii-Moriya interactions", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chiral magnets are an emerging class of topological matter harboring localized and topologically protected vortex-like magnetic textures called skyrmions, which are currently under intense scrutiny as an entity for information storage and processing. Here, on the level of micromagnetics we rigorously show that chiral magnets can not only host skyrmions but also antiskyrmions as least energy configurations over all non-trivial homotopy classes. We derive practical criteria for their occurrence and coexistence with skyrmions that can be fulfilled by (110)-oriented interfaces depending on the electronic structure. Relating the electronic structure to an atomistic spin-lattice model by means of density functional calculations and minimizing the energy on a mesoscopic scale by applying spin-relaxation methods, we propose a double layer of Fe grown on a W(110) substrate as a practical example. We conjecture that ultra-thin magnetic films grown on semiconductor or heavy metal substrates with C-2v symmetry are prototype classes of materials hosting magnetic antiskyrmions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 210, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 308, "DOI": "10.1038/s41467-017-00313-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00313-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408069800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schachenmayer, J; Genes, C; Tignone, E; Pupillo, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schachenmayer, Johannes; Genes, Claudiu; Tignone, Edoardo; Pupillo, Guido", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cavity-Enhanced Transport of Excitons", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We show that exciton-type transport in certain materials can be dramatically modified by their inclusion in an optical cavity: the modification of the electromagnetic vacuum mode structure introduced by the cavity leads to transport via delocalized polariton modes rather than through tunneling processes in the material itself. This can help overcome exponential suppression of transmission properties as a function of the system size in the case of disorder and other imperfections. We exemplify massive improvement of transmission for excitonic wave packets through a cavity, as well as enhancement of steady-state exciton currents under incoherent pumping. These results may have implications for experiments of exciton transport in disordered organic materials. We propose that the basic phenomena can be observed in quantum simulators made of Rydberg atoms, cold molecules in optical lattices, as well as in experiments with trapped ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 254, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2015, "Volume": 114, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 196403, "DOI": "10.1103/PhysRevLett.114.196403", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.196403", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000354363600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ozawa, M; Berthier, L; Biroli, G; Rosso, A; Tarjus, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ozawa, Misaki; Berthier, Ludovic; Biroli, Giulio; Rosso, Alberto; Tarjus, Gilles", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Random critical point separates brittle and ductile yielding transitions in amorphous materials", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We combine an analytically solvable mean-field elasto-plastic model with molecular dynamics simulations of a generic glass former to demonstrate that, depending on their preparation protocol, amorphous materials can yield in two qualitatively distinct ways. We show that well-annealed systems yield in a discontinuous brittle way, as metallic and molecular glasses do. Yielding corresponds in this case to a first-order nonequilibrium phase transition. As the degree of annealing decreases, the first-order character becomes weaker and the transition terminates in a second-order critical point in the universality class of an !sing model in a random field. For even more poorly annealed systems, yielding becomes a smooth crossover, representative of the ductile rheological behavior generically observed in foams, emulsions, and colloidal glasses. Our results show that the variety of yielding behaviors found in amorphous materials does not necessarily result from the diversity of particle interactions or microscopic dynamics but is instead unified by carefully considering the role of the initial stability of the system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2018, "Volume": 115, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6656, "End Page": 6661, "Article Number": null, "DOI": "10.1073/pnas.1806156115", "DOI Link": "http://dx.doi.org/10.1073/pnas.1806156115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436245000061", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Y; Zhang, W; Tyberkevych, V; Kwok, WK; Hoffmann, A; Novosad, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Yi; Zhang, Wei; Tyberkevych, Vasyl; Kwok, Wai-Kwong; Hoffmann, Axel; Novosad, Valentine", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid magnonics: Physics, circuits, and applications for coherent information processing", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid dynamic systems have recently gained interest with respect to both fundamental physics and device applications, particularly with their potential for coherent information processing. In this perspective, we will focus on the recent rapid developments of magnon-based hybrid systems, which seek to combine magnonic excitations with diverse excitations for transformative applications in devices, circuits, and information processing. Key to their promising potentials is that magnons are highly tunable excitations and can be easily engineered to couple with various dynamic media and platforms. The capability of reaching strong coupling with many different excitations has positioned magnons well for studying solid-state coherent dynamics and exploiting unique functionality. In addition, with their gigahertz frequency bandwidth and the ease of fabrication and miniaturization, magnonic devices and systems can be conveniently integrated into microwave circuits for mimicking a broad range of device concepts that have been applied in microwave electronics, photonics, and quantum information. We will discuss a few potential directions for advancing magnon hybrid systems, including on-chip geometry, novel coherent magnonic functionality, and coherent transduction between different platforms. As a future outlook, we will discuss the opportunities and challenges of magnonic hybrid systems for their applications in quantum information and magnonic logic.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2020, "Volume": 128, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 130902, "DOI": "10.1063/5.0020277", "DOI Link": "http://dx.doi.org/10.1063/5.0020277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000578513900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YY; Cai, PG; Zhang, WL; Meng, TY; Tang, YJ; Yi, Z; Wei, KH; Li, GF; Tang, B; Yi, YG; Ameen, S; Tait, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yanying; Cai, Pinggen; Zhang, Wenlong; Meng, Tongyu; Tang, Yongjian; Yi, Zao; Wei, Kaihua; Li, Gongfa; Tang, Bin; Yi, Yougen; Ameen, Sadia; Tait, Niall", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-Wideband High-Efficiency Solar Absorber and Thermal Emitter Based on Semiconductor InAs Microstructures", "Source Title": "MICROMACHINES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the use of chemical fuels is permanently damaging the environment, the need for new energy sources is urgent for mankind. Given that solar energy is a clean and sustainable energy source, this study investigates and proposes a six-layer composite ultra-wideband high-efficiency solar absorber with an annular microstructure. It achieves this by using a combination of the properties of metamaterials and the quantum confinement effects of semiconductor materials. The substrate is W-Ti-Al2O3, and the microstructure is an annular InAs-square InAs film-Ti film combination. We used Lumerical Solutions' FDTD solution program to simulate the absorber and calculate the model's absorption, field distribution, and thermal radiation efficiency (when it is used as a thermal emitter), and further explored the physical mechanism of the model's ultra-broadband absorption. Our model has an average absorption of 95.80% in the 283-3615 nm band, 95.66% in the 280-4000 nm band, and a weighted average absorption efficiency of 95.78% under AM1.5 illumination. Meanwhile, the reflectance of the model in the 5586-20,000 nm band is all higher than 80%, with an average reflectance of 94.52%, which has a good thermal infrared suppression performance. It is 95.42% under thermal radiation at 1000 K. It has outstanding performance when employed as a thermal emitter as well. Additionally, simulation results show that the absorber has good polarization and incidence angle insensitivity. The model may be applied to photodetection, thermophotovoltaics, bio-detection, imaging, thermal ion emission, and solar water evaporation for water purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 14, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1597, "DOI": "10.3390/mi14081597", "DOI Link": "http://dx.doi.org/10.3390/mi14081597", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055762900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Almeida, T; Karamysheva, A; Valente, BFA; Silva, JM; Braz, M; Almeida, A; Silvestre, AJD; Vilela, C; Freire, CSR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Almeida, Tania; Karamysheva, Anna; Valente, Bruno F. A.; Silva, Jose M.; Braz, Marcia; Almeida, Adelaide; Silvestre, Armando J. D.; Vilela, Carla; Freire, Carmen S. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biobased ternary films of thermoplastic starch, bacterial nullocellulose and gallic acid for active food packaging", "Source Title": "FOOD HYDROCOLLOIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of active packaging technologies and biopolymeric materials are among the emerging trends for implementation of sustainability in the food packaging industry. Thus, herein, bioactive transparent nullocomposite films of thermoplastic starch (TPS) reinforced with bacterial nullocellulose (BNC) (1%, 5% and 10% w/w, relative to starch) and enriched with gallic acid (GA) (1 and 1.5% w/w, relative to starch) were prepared by the solvent casting method. The addition of BNC (& GE;5% w/w) and GA (1 and 1.5% w/w) enhanced both the mechanical properties (Young's Modulus: 1.2-2.0 GPa vs. 1.0 GPa for TPS; tensile strength: 23-39 MPa vs. 20 MPa for TPS) and the water resistance (moisture absorption and solubility in water) of the nullocomposites. All films are thermally stable up to 125 degrees C. It was also found that the addition of GA imparted the hydrocolloid TPSBNC nullocomposites with UV-blocking properties and antioxidant activity (DPPH scavenging activity above 80%). In addition, the film with 10% w/w of BNC nullofibers and 1% w/w of GA had good oxygen barrier properties with a coefficient of permeability of 0.91 & PLUSMN; 0.12 cm3 & mu;m m- 2 d-1 kPa- 1 and antibacterial activity against the gram-positive Staphylococcus aureus (reduction of about 4.5 log10 colony forming units (CFU) mL-1 after 48 h). This is the first time that antibacterial activity is reported for TPS-BNC nullocomposites. The film with 10% w/w of BNC nullofibers and 1% w/w of GA was further demonstrated to have the ability of delaying the browning and weight loss of packaged fresh cut apple stored at +4 degrees C for 7 days. All these outcomes are of great relevance for the packaging sector, thus attesting the potential of the developed TPS-BNC-GA nullocomposites as sustainable and eco-friendly film materials for active food packaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 144, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108934, "DOI": "10.1016/j.foodhyd.2023.108934", "DOI Link": "http://dx.doi.org/10.1016/j.foodhyd.2023.108934", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001025934800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Leal, W; Kotter, R; Özuyar, PG; Abubakar, IR; Eustachio, JHPP; Matandirotya, NR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Filho, Walter Leal; Kotter, Richard; Ozuyar, Pinar Goekcin; Abubakar, Ismaila Rimi; Eustachio, Joao Henrique Paulino Pires; Matandirotya, Newton R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Rare Earth Elements as Critical Raw Materials", "Source Title": "SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The boom in technological advances in recent decades has led to increased demand for rare earth elements (REEs) (also known as rare earth metals) across various industries with wide-ranging industrial applications, including in the clean energy sector, but with some environmental, economic, and social footprint concerns. This paper reviews the complexities of the production, consumption, and reuse or recovery of REEs, presenting current trends in terms of potentials and challenges associated with this. This paper in particular focuses on the supply, demand, and (environmental and economic) sustainability of REEs, as a subset of critical raw materials. It does so via a critical stocktaking of key discussions and debates in the field over the past 15 years up until now, through a thematic analysis of the published and gray (policy) literature with a grounded theory approach. The paper finds that carefully balanced lifecycle sustainability assessments are needed for assessing the respective dimensions of the extraction, processing, and reuse or recovery methods for different types of REE sources and supplies to meet current and future demands. It furthermore diagnoses the need for taking into account some shifts and substitutions among REEs also for reasons of cost and locational supplies for the security of supply. Finally, the paper provides some overall policy recommendations for addressing current problems, with a conceptual framing of the UN Sustainable Development Goals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1919, "DOI": "10.3390/su15031919", "DOI Link": "http://dx.doi.org/10.3390/su15031919", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000932557200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Zhang, JF; Dai, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hui; Zhang, Jin Feng; Dai, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic amine surface modified one-dimensional CdSe0.8S0.2-diethylenetriamine/two-dimensional SnNb2O6 S-scheme heterojunction with promoted visible-light-driven photocatalytic CO2 reduction", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving a strong redox ability and high visible-light absorption ability in a single semiconductor material is difficult. Designing a heterojunction between two semiconductor materials is a feasible method. The new step (S-scheme) heterojunction can effectively promote the separation and transfer of photogenerated electron-hole pairs and retain strong redox ability. We designed and prepared a CdSe0.8S0.2-diethylenetriamine (DETA)/SnNb2O6 heterostructure material via the solvothermal method. When CdSe0.8S0.2-DETA and SnNb2O6 form an S-scheme heterojunction, 30%CdSe0.8S0.2-DETA/SnNb2O6 exhibits the highest CO production rate (17.31 umol.g(-1).h(-1)), which is factors of 2.8 and 4.8 higher than that of traditional solvothermal SnNb2O6 (6.2 mu mol.g(-1).h(-1)) and CdSe0.8S0.2-DETA (3.6 mu mol.g(-1).h(-1)), respectively. X-ray photoelectron spectroscopy characterization data provided evidence that the transfer pathway of space charge in the CO2 reduction process was in accordance with the S-scheme. This research provides a simple strategy through which one can optimize the band structure to promote the separation of photogenerated carriers and achieve a high efficiency of CO2 reduction. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 136, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 255, "End Page": 264, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63784-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63784-6", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ningyuan, J; Owens, C; Sommer, A; Schuster, D; Simon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ningyuan, Jia; Owens, Clai; Sommer, Ariel; Schuster, David; Simon, Jonathan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time- and Site-Resolved Dynamics in a Topological Circuit", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "From studies of exotic quantum many-body phenomena to applications in spintronics and quantum information processing, topological materials are poised to revolutionize the condensed-matter frontier and the landscape of modern materials science. Accordingly, there is a broad effort to realize topologically nontrivial electronic and photonic materials for fundamental science as well as practical applications. In this work, we demonstrate the first simultaneous site-and time-resolved measurements of a time-reversal-invariant topological band structure, which we realize in a radio-frequency photonic circuit. We control band-structure topology via local permutation of a traveling-wave capacitor-inductor network, increasing robustness by going beyond the tight-binding limit. We observe a gapped density of states consistent with a modified Hofstadter spectrum at a flux per plaquette of phi= pi/2. In situ probes of the band gaps reveal spatially localized bulk states and delocalized edge states. Time-resolved measurements reveal dynamical separation of localized edge excitations into spin-polarized currents. The radio-frequency circuit paradigm is naturally compatible with nonlocal coupling schemes, allowing us to implement a Mobius strip topology inaccessible in conventional systems. This room-temperature experiment illuminates the origins of topology in band structure, and when combined with circuit quantum electrodynamics techniques, it provides a direct path to topologically ordered quantum matter.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 329, "Times Cited, All Databases": 354, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2015, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21031, "DOI": "10.1103/PhysRevX.5.021031", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.021031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356584900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Romero, AH; Allan, DC; Amadon, B; Antonius, G; Applencourt, T; Baguet, L; Bieder, J; Bottin, F; Bouchet, J; Bousquet, E; Bruneval, F; Brunin, G; Caliste, D; Côté, M; Denier, J; Dreyer, C; Ghosez, P; Giantomassi, M; Gillet, Y; Gingras, O; Hamann, DR; Hautier, G; Jollet, F; Jomard, G; Martin, A; Miranda, HPC; Naccarato, F; Petretto, G; Pike, NA; Planes, V; Prokhorenko, S; Rangel, T; Ricci, F; Rignullese, GM; Royo, M; Stengel, M; Torrent, M; van Setten, MJ; Van Troeye, B; Verstraete, MJ; Wiktor, J; Zwanziger, JW; Gonze, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Romero, Aldo H.; Allan, Douglas C.; Amadon, Bernard; Antonius, Gabriel; Applencourt, Thomas; Baguet, Lucas; Bieder, Jordan; Bottin, Francois; Bouchet, Johann; Bousquet, Eric; Bruneval, Fabien; Brunin, Guillaume; Caliste, Damien; Cote, Michel; Denier, Jules; Dreyer, Cyrus; Ghosez, Philippe; Giantomassi, Matteo; Gillet, Yannick; Gingras, Olivier; Hamann, Donald R.; Hautier, Geoffroy; Jollet, Francois; Jomard, Gerald; Martin, Alexandre; Miranda, Henrique P. C.; Naccarato, Francesco; Petretto, Guido; Pike, Nicholas A.; Planes, Valentin; Prokhorenko, Sergei; Rangel, Tonatiuh; Ricci, Fabio; Rignullese, Gian-Marco; Royo, Miquel; Stengel, Massimiliano; Torrent, Marc; van Setten, Michiel J.; Van Troeye, Benoit; Verstraete, Matthieu J.; Wiktor, Julia; Zwanziger, Josef W.; Gonze, Xavier", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ABINIT: Overview and focus on selected capabilities", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "abinit is probably the first electronic-structure package to have been released under an open-source license about 20 years ago. It implements density functional theory, density-functional perturbation theory (DFPT), many-body perturbation theory (GW approximation and Bethe-Salpeter equation), and more specific or advanced formalisms, such as dynamical mean-field theory (DMFT) and the temperature-dependent effective potential approach for anharmonic effects. Relying on planewaves for the representation of wavefunctions, density, and other space-dependent quantities, with pseudopotentials or projector-augmented waves (PAWs), it is well suited for the study of periodic materials, although nullostructures and molecules can be treated with the supercell technique. The present article starts with a brief description of the project, a summary of the theories upon which abinit relies, and a list of the associated capabilities. It then focuses on selected capabilities that might not be present in the majority of electronic structure packages either among planewave codes or, in general, treatment of strongly correlated materials using DMFT; materials under finite electric fields; properties at nuclei (electric field gradient, Mossbauer shifts, and orbital magnetization); positron annihilation; Raman intensities and electro-optic effect; and DFPT calculations of response to strain perturbation (elastic constants and piezoelectricity), spatial dispersion (flexoelectricity), electronic mobility, temperature dependence of the gap, and spin-magnetic-field perturbation. The abinit DFPT implementation is very general, including systems with van der Waals interaction or with noncollinear magnetism. Community projects are also described: generation of pseudopotential and PAW datasets, high-throughput calculations (databases of phonon band structure, second-harmonic generation, and GW computations of bandgaps), and the library libpaw. abinit has strong links with many other software projects that are briefly mentioned.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 217, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2020, "Volume": 152, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124102, "DOI": "10.1063/1.5144261", "DOI Link": "http://dx.doi.org/10.1063/1.5144261", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000523750600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, QQ; Carroll, JP; Wang, SQ; Ran, S; Broyles, C; Siddiquee, H; Butch, NP; Saha, SR; Paglione, J; Davis, JCS; Liu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Qiangqiang; Carroll, Joseph P.; Wang, Shuqiu; Ran, Sheng; Broyles, Christopher; Siddiquee, Hasan; Butch, Nicholas P.; Saha, Shanta R.; Paglione, Johnpierre; Davis, J. C. Seamus; Liu, Xiaolong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detection of a pair density wave state in UTe2", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Spin-triplet topological superconductors should exhibit many unprecedented electronic properties, including fractionalized electronic states relevant to quantum information processing. Although UTe2 may embody such bulk topological superconductivity(1-11), its superconductive order parameter Delta(k) remains unknown(12). Many diverse forms for Delta(k) are physically possible(12) in such heavy fermion materials(13). Moreover, intertwined(14,15) density waves of spin (SDW), charge (CDW) and pair (PDW) may interpose, with the latter exhibiting spatially modulating(14,15) superconductive order parameter Delta(r), electron-pair density(16-19) and pairing energy gap(17,20-23). Hence, the newly discovered CDW state(24) in UTe2 motivates the prospect that a PDW state may exist in this material(24,25). To search for it, we visualize the pairing energy gap with mu eV-scale energy resolution using superconductive scanning tunnelling microscopy (STM) tips(26-31). We detect three PDWs, each with peak-to-peak gap modulations of around 10 mu eV and at incommensurate wavevectors P-i=1,P-2,P-3 that are indistinguishable from the wavevectors Q(i=1,2,3) of the prevenient(24) CDW. Concurrent visualization of the UTe2 superconductive PDWs and the non-superconductive CDWs shows that every P-i:Q(i) pair exhibits a relative spatial phase delta phi approximate to pi. From these observations, and given UTe2 as a spin-triplet superconductor(12), this PDW state should be a spin-triplet PDW24,25. Although such states do exist(32) in superfluid He-3, for superconductors, they are unprecedented.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2023, "Volume": 618, "Issue": 7967, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 921, "End Page": 927, "Article Number": null, "DOI": "10.1038/s41586-023-05919-7", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05919-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022530900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MH; Han, X; Chen, H; Peng, Q; Huang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Meihui; Han, Xiao; Chen, Hao; Peng, Qian; Huang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A molecular descriptor of intramolecular noncovalent interaction for regulating optoelectronic properties of organic semiconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intramolecular noncovalent interactions can block molecules in a given conformation enhancing performance of organic semiconductors. Here, the authors report a molecular descriptor to weigh them that strongly correlates with the reorganization energy of excited or charged states. In recent years, intramolecular noncovalent interaction has become an important means to modulate the optoelectronic performances of organic/polymeric semiconductors. However, it lacks a deep understanding and a direct quantitative relationship among the molecular geometric structure, strength of noncovalent interaction, and optoelectronic properties in organic/polymeric semiconductors. Herein, upon systematical theoretical calculations on 56 molecules with and without noncovalent interactions (X center dot center dot center dot Y, X = O, S, Se, Te; Y = C, F, O, S, Cl), we reveal the essence of the interactions and the dependence of its strength on the molecular geometry. Importantly, a descriptor S is established as a function of several basic geometric parameters to well characterize the noncovalent interaction energy, which exhibits a good inverse correlation with the reorganization energies of the photo-excited states or electron-pumped charged states in organic/polymeric semiconductors. In particular, the experimental H-1, Se-77, and Te-125 NMR, the optical absorption and emission spectra, and single crystal structures of eight compounds fully confirm the theoretical predictions. This work provides a simple descriptor to characterize the strength of noncovalent intramolecular interactions, which is significant for molecular design and property prediction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 56, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2500, "DOI": "10.1038/s41467-023-38078-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38078-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000978872100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anderson, E; Fan, FR; Cai, JQ; Holtzmann, W; Taniguchi, T; Watanabe, K; Xiao, D; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anderson, Eric; Fan, Feng-Ren; Cai, Jiaqi; Holtzmann, William; Taniguchi, Takashi; Watanabe, Kenji; Xiao, Di; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Programming correlated magnetic states with gate-controlled moire geometry", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to control the underlying lattice geometry of a system may enable transitions between emergent quantum ground states. We report in situ gate switching between honeycomb and triangular lattice geometries of an electron many-body Hamiltonian in rhombohedral (R)-stacked molybdenum ditelluride (MoTe2) moire bilayers, resulting in switchable magnetic exchange interactions. At zero electric field, we observed a correlated ferromagnetic insulator near one hole per moire unit cell with a widely tunable Curie temperature up to 14 K. Applying an electric field switched the system into a half-filled triangular lattice with antiferromagnetic interactions; further doping this layer-polarized superlattice tuned the antiferromagnetic exchange interaction back to ferromagnetic. Our work demonstrates R-stacked MoTe2 moires to be a laboratory for engineering correlated states with nontrivial topology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2023, "Volume": 381, "Issue": 6655, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 325, "End Page": 330, "Article Number": null, "DOI": "10.1126/science.adg4268", "DOI Link": "http://dx.doi.org/10.1126/science.adg4268", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001046763100031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, QQ; Jiang, CQ; Xia, X; Wang, YF; Yan, CX; Wang, XR; Lei, T; Yang, XT; Yang, WQ; Cheng, G; Gao, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Qianqian; Jiang, Chaoqing; Xia, Xue; Wang, Yufan; Yan, Chenxing; Wang, Xiaorong; Lei, Ting; Yang, Xiaotong; Yang, Wenqin; Cheng, Guo; Gao, Huile", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pathological BBB Crossing Melanin-Like nulloparticles as Metal-Ion Chelators and Neuroinflammation Regulators against Alzheimer's Disease", "Source Title": "RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inflammatory responses, manifested in excessive oxidative stress and microglia overactivation, together with metal ion-triggered amyloid-beta (A & beta;) deposition, are critical hallmarks of Alzheimer's disease (AD). The intricate pathogenesis causes severe impairment of neurons, which, in turn, exacerbates A & beta; aggregation and facilitates AD progression. Herein, multifunctional melanin-like metal ion chelators and neuroinflammation regulators (named PDA@K) were constructed for targeted treatment of AD. In this platform, intrinsically bioactive material polydopamine nulloparticles (PDA) with potent metal ion chelating and ROS scavenging effects were decorated with the KLVFF peptide, endowing the system with the capacity of enhanced pathological blood-brain barrier (BBB) crossing and lesion site accumulation via A & beta; hitchhiking. In vitro and in vivo experiment revealed that PDA@K had high affinity toward A & beta; and were able to hitch a ride on A & beta; to achieve increased pathological BBB crossing. The engineered PDA@K effectively mitigated A & beta; aggregate and alleviated neuroinflammation. The modulated inflammatory microenvironment by PDA@K promoted microglial polarization toward the M2-like phenotype, which restored their critical functions for neuron care and plaque removal. After 3-week treatment of PDA@K, spatial learning and memory deficit as well as neurologic changes of FAD4T transgenic mice were largely rescued. Transcriptomics analysis further revealed the therapeutic mechanism of PDA@K. Our study provided an appealing paradigm for directly utilizing intrinsic properties of nullomaterials as therapeutics for AD instead of just using them as nullocarriers, which largely widen the application of nullomaterials in AD therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 40, "Times Cited, All Databases": 43, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2023, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 180, "DOI": "10.34133/research.0180", "DOI Link": "http://dx.doi.org/10.34133/research.0180", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026194500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, TL; Ruan, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Tianli; Ruan, Xiulin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum mechanical prediction of four-phonon scattering rates and reduced thermal conductivity of solids", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, first principle-based predictions of lattice thermal conductivity kappa from perturbation theory have achieved significant success. However, it only includes three-phonon scattering due to the assumption that four-phonon and higher-order processes are generally unimportant. Also, directly evaluating the scattering rates of four-phonon and higher-order processes has been a long-standing challenge. In this work, however, we have developed a formalism to explicitly determine quantum mechanical scattering probability matrices for four-phonon scattering in the full Brillouin zone, and by mitigating the computational challenge we have directly calculated four-phonon scattering rates. We find that four-phonon scattering rates are comparable to three-phonon scattering rates at medium and high temperatures, and they increase quadratically with temperature. As a consequence, kappa of Lennard-Jones argon is reduced by more than 60% at 80 K when four-phonon scattering is included. Also, in less anharmonic materials-diamond, silicon, and germanium-kappa is still reduced considerably at high temperature by four-phonon scattering by using the classical Tersoff potentials. Also, the thermal conductivity of optical phonons is dominated by the fourth-and higher-orders phonon scattering even at low temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2016, "Volume": 93, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45202, "DOI": "10.1103/PhysRevB.93.045202", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.93.045202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367665400004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abd El-Monaem, EM; Eltaweil, AS; El-Subruiti, GM; Mohy-Eldin, MS; Omer, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abd El-Monaem, Eman M.; Eltaweil, Abdelazeem S.; El-Subruiti, Gehan M.; Mohy-Eldin, Mohamed S.; Omer, Ahmed M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of nitrophenol onto a novel Fe3O4-κ-carrageenull/MIL-125(Ti) composite: process optimization, isotherms, kinetics, and mechanism", "Source Title": "ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water pollution is a dreadful affair that has incessantly aggravated, exposing our planet to danger. In particular, the persistent nitro aromatic compound like nitrophenols causes anxiety to the researchers due to their hazardous impacts, excessive usage, and removal difficulty. For this purpose, a novel multi-featured composite was constructed based on kappa-Carrageenull (kappa-Carr), MOF (MIL-125(Ti)), and magnetic Fe3O4 for efficient adsorptive removal of o-nitrophenol (o-NP). Interestingly, BET measurements revealed the high surface area of Fe3O4-kappa-Carr/MIL-125(Ti) of about 163.27 m(2)/g, while VSM showed its excellent magnetic property (20.34 emu/g). The comparison study pointed out the synergistic effect between Fe3O4, kappa-Carr, and MIL-125(Ti), forming a composite with an excellent adsorption performance toward o-NP. The adsorption data obeyed pseudo-second-order kinetic model, and Freundlich isotherm model was better fitted than Langmuir and Temkin. Furthermore, Langmuir verified the supreme adsorption capacity of o-NP onto Fe3O4-kappa-Carr/MIL-125(Ti) since the computed q(max) reached 320.26 mg/g at pH 6 and 25 & DEG;C. Furthermore, the XPS results postulated that the adsorption mechanism pf o-NP proceeded via H-bonding, pi-pi interaction, and electron donor-acceptor interactions. Interestingly, Fe3O4-kappa-Carr/MIL-125(Ti) composite retained good adsorption characteristics after reusing for five cycles, suggesting its viable applicability as an efficient, renewable, and easy-separable adsorbent for removing nitro aromatic pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 30, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 49301, "End Page": 49313, "Article Number": null, "DOI": "10.1007/s11356-023-25678-2", "DOI Link": "http://dx.doi.org/10.1007/s11356-023-25678-2", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000935681400016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Christensen, MH; Birol, T; Andersen, BM; Fernulldes, RM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Christensen, Morten H.; Birol, Turan; Andersen, Brian M.; Fernulldes, Rafael M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of the charge density wave in AV3Sb5 kagome metals", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The family of metallic kagome compounds AV(3)Sb(5) (A = K, Rb, Cs) was recently discovered to exhibit both superconductivity and charge order. The nature of the charge density wave (CDW) phase is presently unsettled, which complicates the interpretation of the superconducting ground state. In this paper, we use group theory and density functional theory (DFT) to derive and solve a phenomenological Landau model for this CDW state. The DFT results reveal three unstable phonon modes with the same in-plane momentum but different out-of-plane momenta, whose frequencies depend strongly on the electronic temperature. This is indicative of an electronically driven CDW, stabilized by features of the in-plane electronic dispersion. Motivated by the DFT analysis, we construct a Landau free-energy expansion for coupled CDW order parameters with wave vectors at the M and L points of the hexagonal Brillouin zone. We find an unusual trilinear term coupling these different order parameters, which can promote the simultaneous condensation of both CDWs even if the two modes are not nearly degenerate. We classify the different types of coupled multi -Q CDW orders, focusing on those that break the sixfold rotational symmetry and lead to a unit-cell doubling along all three crystallographic directions, as suggested by experiments. We determine a region in parameter space, characterized by large nonlinear Landau coefficients, where these phases-dubbed staggered trihexagonal and staggered Star of David-are the leading instabilities of the system. Finally, we discuss the implications of our results for the kagome metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 27", "Publication Year": 2021, "Volume": 104, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 214513, "DOI": "10.1103/PhysRevB.104.214513", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.104.214513", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737275600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baek, H; Brotons-Gisbert, M; Koong, ZX; Campbell, A; Rambach, M; Watanabe, K; Taniguchi, T; Gerardot, BD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baek, H.; Brotons-Gisbert, M.; Koong, Z. X.; Campbell, A.; Rambach, M.; Watanabe, K.; Taniguchi, T.; Gerardot, B. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly energy-tunable quantum light from moire-trapped excitons", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photon antibunching, a hallmark of quantum light, has been observed in the correlations of light from isolated atomic and atomic-like solid-state systems. Two-dimensional semiconductor heterostructures offer a unique method to create a quantum light source: Moire trapping potentials for excitons are predicted to create arrays of quantum emitters. While signatures of moire-trapped excitons have been observed, their quantum nature has yet to be confirmed. Here, we report photon antibunching from single moire-trapped interlayer excitons in a heterobilayer. Via magneto-optical spectroscopy, we demonstrate that the discrete anharmonic spectra arise from bound band-edge electron-hole pairs trapped in moire potentials. Last, we exploit the large permanent dipole of interlayer excitons to achieve large direct current (DC) Stark tuning up to 40 meV. Our results confirm the quantum nature of moire-confined excitons and open opportunities to investigate their inhomogeneity and interactions between the emitters or energetically tune single emitters into resonullce with cavity modes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 37, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba8526", "DOI": "10.1126/sciadv.aba8526", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba8526", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571356100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sitti, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sitti, Metin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Physical intelligence as a new paradigm", "Source Title": "EXTREME MECHANICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intelligence of physical agents, such as human-made (e.g., robots, autonomous cars) and biological (e.g., animals, plants) ones, is not only enabled by their computational intelligence (CI) in their brain, but also by their physical intelligence (PI) encoded in their body. Therefore, it is essential to advance the PI of human-made agents as much as possible, in addition to their CI, to operate them in unstructured and complex real-world environments like the biological agents. This article gives a perspective on what PI paradigm is, when PI can be more significant and dominullt in physical and biological agents at different length scales and how bioinspired and abstract PI methods can be created in agent bodies. PI paradigm aims to synergize and merge many research fields, such as mechanics, materials science, robotics, mechanical design, fluidics, active matter, biology, self-assembly and collective systems, to enable advanced PI capabilities in human-made agent bodies, comparable to the ones observed in biological organisms. Such capabilities would progress the future robots and other machines beyond what can be realized using the current frameworks. (C) 2021 The Author. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 165, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101340, "DOI": "10.1016/j.eml.2021.101340", "DOI Link": "http://dx.doi.org/10.1016/j.eml.2021.101340", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000661866500014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghasemi, M; Hu, HW; Peng, ZX; Rech, JJ; Angunawela, I; Carpenter, JH; Stuard, SJ; Wadsworth, A; McCulloch, I; You, W; Ade, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghasemi, Masoud; Hu, Huawei; Peng, Zhengxing; Rech, Jeromy James; Angunawela, Indunil; Carpenter, Joshua H.; Stuard, Samuel J.; Wadsworth, Andrew; McCulloch, Iain; You, Wei; Ade, Harald", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Delineation of Thermodynamic and Kinetic Factors that Control Stability in Non-fullerene Organic Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although non-fullerene small molecular acceptors (NF-SMAs) are dominating current research in organic solar cells (OSCs), measurements of thermodynamics drivers and kinetic factors determining their morphological stability are lacking. Here, we delineate and measure such factors in crystallizable NF-SMA blends and discuss four model systems with respect to their meta-stability and degree of vitrification. We determine for the first time the amorphous-amorphous phase diagram in an NF-SMA system and show that its deep quench depth can result in severe burn-in degradation. We estimate the relative phase behavior of four other materials systems. Additionally, we derive room-temperature diffusion coefficients and conclude that the morphology needs to be stabilized by vitrification corresponding to diffusion constants below 10(-22) cm(2)/s. Our results show that to achieve stability via rationalmolecular design, the thermodynamics, glass transition temperature, diffusion properties, and related structure-function relations need to be more extensively studied and understood.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1328, "End Page": 1348, "Article Number": null, "DOI": "10.1016/j.joule.2019.03.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.03.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467969300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Moriyama, T; Oda, K; Ohkochi, T; Kimata, M; Ono, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Moriyama, Takahiro; Oda, Kent; Ohkochi, Takuo; Kimata, Motoi; Ono, Teruo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spin torque control of antiferromagnetic moments in NiO", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For a long time, there were no efficient ways of controlling antiferromagnets. Quite a strong magnetic field was required to manipulate the magnetic moments because of a high molecular field and a small magnetic susceptibility. It was also difficult to detect the orientation of the magnetic moments since the net magnetic moment is effectively zero. For these reasons, research on antiferromagnets has not been progressed as drastically as that on ferromagnets which are the main materials in modern spintronic devices. Here we show that the magnetic moments in NiO, a typical natural antiferromagnet, can indeed be controlled by the spin torque with a relatively small electric current density (similar to 4 x 10(7) A/cm(2)) and their orientation is detected by the transverse resistance resulting from the spin Hall magnetoresistance. The demonstrated techniques of controlling and detecting antiferromagnets would outstandingly promote the methodologies in the recently emerged antiferromagnetic spintronics. Furthermore, our results essentially lead to a spin torque antiferromagnetic memory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14167, "DOI": "10.1038/s41598-018-32508-w", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-32508-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000445276000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dhineshbabu, NR; Rajendran, V; Nithyavathy, N; Vetumperumal, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dhineshbabu, N. R.; Rajendran, V.; Nithyavathy, N.; Vetumperumal, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study of structural and optical properties of cupric oxide nulloparticles", "Source Title": "APPLIED nullOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, cupric oxide (CuO) nulloparticles were synthesized via sonochemical method. The samples were characterized by X- ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscope, and transmission electron microscopy. The spherical CuO nulloparticles were dispersed in sodium hexametaphosphate under sonication (25 kHz) to analyze the particle size distribution and UV absorption spectra. Using these absorption spectra, we further examined the CuO nulloparticle to explore the possibility of using them as a material for applications such as solar cell and textile production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 933, "End Page": 939, "Article Number": null, "DOI": "10.1007/s13204-015-0499-2", "DOI Link": "http://dx.doi.org/10.1007/s13204-015-0499-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381937200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, DN; Liu, L; Peng, QM; Qiu, JB; Gong, H; Zhong, AG; Liu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Dongnai; Liu, Lei; Peng, Qimin; Qiu, Jiabin; Gong, Hao; Zhong, Aiguo; Liu, Shiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Controlling Thiophene Rings on D-A Polymer Photocatalysts Accessed via Direct Arylation for Hydrogen Production", "Source Title": "MOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conjugated polymer photocatalysts for hydrogen production have the advantages of an adjustable structure, strong response in the visible light region, adjustable energy levels, and easy functionalization. Using an atom- and step-economic direct C-H arylation method, dibromocyanostilbene was polymerized with thiophene, dithiophene, terthiophene, and fused thienothiophene and dithienothiophene, respectively, to produce donor-acceptor (D-A)-type linear conjugated polymers containing different thiophene derivatives with different conjugation lengths. Among them, the D-A polymer photocatalyst constructed from dithienothiophene could significantly broaden the spectral response, with a hydrogen evolution rate up to 12.15 mmol h(-1) g(-1). The results showed that the increase in the number of fused rings on thiophene building blocks was beneficial to the photocatalytic hydrogen production of cyanostyrylphene-based linear polymers. For the unfused dithiophene and terthiophene, the increase in the number of thiophene rings enabled more rotation freedom between the thiophene rings and reduced the intrinsic charge mobility, resulting in lower hydrogen production performance accordingly. This study provides a suitable process for the design of electron donors for D-A polymer photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2023, "Volume": 28, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4507, "DOI": "10.3390/molecules28114507", "DOI Link": "http://dx.doi.org/10.3390/molecules28114507", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004912600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, MF; Ni, XX; Liu, QW; Chen, CC; Deng, XH; Wang, X; Yu, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Mingfeng; Ni, Xiangxiang; Liu, Qiwei; Chen, Chengcheng; Deng, Xiaohong; Wang, Xiu; Yu, Rongrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high pressure improved gelation and digestive properties of Tai Lake whitebait myofibrillar protein", "Source Title": "FOOD CHEMISTRY-X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigated the effects of ultra-high pressure (UHP) at different levels on the physicochemical properties, gelling properties, and in vitro digestion characteristics of myofibrillar protein (MP) in Tai Lake whitebait. The alpha-helix gradually unfolded and transformed into beta-sheet as the pressure increased from 0 to 400 MPa. In addition, the elastic modulus (G') and viscous modulus (G) of the 400 MPa-treated MP samples increased by 4.8 and 3.8 times, respectively, compared with the control group. The gel properties of the MP also increased significantly after UHP treatment, e.g., the gel strength increased by a 4.8-fold when the pressure reached 400 Mpa, compared with the control group. The results of in vitro simulated digestion showed that the 400 MPa-treated MP gel samples showed a 1.8-fold increase in digestibility and a 69.6 % decrease in digestible particle size compared with the control group.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2024, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101061, "DOI": "10.1016/j.fochx.2023.101061", "DOI Link": "http://dx.doi.org/10.1016/j.fochx.2023.101061", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001137691700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YY; Miao, YH; Ojo, S; Tran, H; Abernathy, G; Grant, JM; Amoah, S; Salamo, G; Du, W; Liu, JF; Margetis, J; Tolle, J; Zhang, YH; Sun, G; Soref, RA; Li, BH; Yu, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yiyin; Miao, Yuanhao; Ojo, Solomon; Tran, Huong; Abernathy, Grey; Grant, Joshua M.; Amoah, Sylvester; Salamo, Gregory; Du, Wei; Liu, Jifeng; Margetis, Joe; Tolle, John; Zhang, Yong-Hang; Sun, Greg; Soref, Richard A.; Li, Baohua; Yu, Shui-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrically injected GeSn lasers on Si operating up to 100 K", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Monolithic lasers on Si have long been anticipated as an enabler of full photonic integration, and significant progress in GeSn material development shows promise for such laser devices. While there are many reports focused on optically pumped lasers, in this work, we demonstrate electrically injected GeSn lasers on Si. We grew a GeSn/SiGeSn heterostruc-ture diode on a Si substrate in a ridge waveguide laser device and tested it under pulsed conditions, giving consideration to the structure design to enhance the carrier and optical confinement. The peak linewidth of 0.13 nm (0.06 meV) and injection current curves indicated lasing, which was observed up to 100 K with emission peaks at 2300 nm. We recorded a threshold of 598 A/cm(2) at 10 K. The peak power and external quantum efficiency were 2.7 mW/facet and 0.3%, respectively. The results indicate advances for group-IV-based lasers, which could serve as a promising route for laser integration on Si. (c) 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 163, "Times Cited, All Databases": 169, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2020, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 924, "End Page": 928, "Article Number": null, "DOI": "10.1364/OPTICA.395687", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.395687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564176000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmed, HU; Mohammed, AS; Faraj, RH; Qaidi, SMA; Mohammed, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmed, Hemn Unis; Mohammed, Ahmed S.; Faraj, Rabar H.; Qaidi, Shaker M. A.; Mohammed, Azad A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compressive strength of geopolymer concrete modified with nullo-silica: Experimental and modeling investigations", "Source Title": "CASE STUDIES IN CONSTRUCTION MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since nullotechnology can enhance the performance of materials, significant effort has been expended in recent years to incorporate nulloparticles (NPs) into geopolymer concrete (GPC) to improve performance and produce GPC with improved characteristics. Recent efforts have been made to incorporate various nullomaterials, most notably nullo-silica (nS), into GPC to improve the composite's properties. Compressive strength (CS) is an important property of all concrete composites, including geopolymer concrete. Several mix proportion parameters and curing temperature and ages influence the CS of geopolymer concrete. As a result, developing a credible model for forecasting concrete CS is critical for saving time, energy, and money while also providing guidance for scheduling the construction process and removing formworks. This paper consists of three phases; in the first phase, a detailed review on the effect of adding nS on the CS of GPC was provided; then, in the second phase, a large amount of mixed design data were extracted from literature studies to create five different models including artificial neural network, M5Ptree, linear regression, nonlinear regression, and multi logistic regression models for forecasting the CS of GPC incorporated nS. Finally, the developed models were validated in the last phase by carrying out experimental laboratory works. Results revealed that the addition of nS improves the CS of GPC, and the ANN model estimated the CS of GPC incorporated nS more accurately than the other models. On the other hand, the alkaline solution to binder ratio, molarity, NaOH content, curing temperature, and ages were those parameters that significantly influenced the CS of GPC incorporated nS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 16, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e01036", "DOI": "10.1016/j.cscm.2022.e01036", "DOI Link": "http://dx.doi.org/10.1016/j.cscm.2022.e01036", "Book DOI": null, "Early Access Date": "MAR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000802445200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klein, DK; Fernández, M; Martin, RJ; Neff, P; Weeger, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klein, Dominik K.; Fernulldez, Mauricio; Martin, Robert J.; Neff, Patrizio; Weeger, Oliver", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyconvex anisotropic hyperelasticity with neural networks", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, two machine learning based constitutive models for finite deformations are proposed. Using input convex neural networks, the models are hyperelastic, anisotropic and fulfill the polyconvexity condition, which implies ellipticity and thus ensures material stability. The first constitutive model is based on a set of polyconvex, anisotropic and objective invariants. The second approach is formulated in terms of the deformation gradient, its cofactor and determinullt, uses group symmetrization to fulfill the material symmetry condition, and data augmentation to fulfill objectivity approximately. The extension of the dataset for the data augmentation approach is based on mechanical considerations and does not require additional experimental or simulation data. The models are calibrated with highly challenging simulation data of cubic lattice metamaterials, including finite deformations and lattice instabilities. A moderate amount of calibration data is used, based on deformations which are commonly applied in experimental investigations. While the invariant-based model shows drawbacks for several deformation modes, the model based on the deformation gradient alone is able to reproduce and predict the effective material behavior very well and exhibits excellent generalization capabilities. In addition, the models are calibrated with transversely isotropic data, generated with an analytical polyconvex potential. For this case, both models show excellent results, demonstrating the straightforward applicability of the polyconvex neural network constitutive models to other symmetry groups.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 159, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104703, "DOI": "10.1016/j.jmps.2021.104703", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2021.104703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781370000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, QM; Zhang, X; Banerjee, S; Bao, P; Barbry, M; Blunt, NS; Bogdanov, NA; Booth, GH; Chen, J; Cui, ZH; Eriksen, JJ; Gao, Y; Guo, S; Hermann, J; Hermes, MR; Koh, K; Koval, P; Lehtola, S; Li, ZD; Liu, JZ; Mardirossian, N; McClain, JD; Motta, M; Mussard, B; Pham, HQ; Pulkin, A; Purwanto, W; Robinson, PJ; Ronca, E; Sayfutyarova, E; Scheurer, M; Schurkus, HF; Smith, JET; Sun, C; Sun, SN; Upadhyay, S; Wagner, LK; Wang, X; White, A; Whitfield, JD; Williamson, MJ; Wouters, S; Yang, J; Yu, JM; Zhu, TY; Berkelbach, TC; Sharma, S; Sokolov, A; Chan, GKL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Qiming; Zhang, Xing; Banerjee, Samragni; Bao, Peng; Barbry, Marc; Blunt, Nick S.; Bogdanov, Nikolay A.; Booth, George H.; Chen, Jia; Cui, Zhi-Hao; Eriksen, Janus Juul; Gao, Yang; Guo, Sheng; Hermann, Jan; Hermes, Matthew R.; Koh, Kevin; Koval, Peter; Lehtola, Susi; Li, Zhendong; Liu, Junzi; Mardirossian, Narbe; McClain, James D.; Motta, Mario; Mussard, Bastien; Pham, Hung Q.; Pulkin, Artem; Purwanto, Wirawan; Robinson, Paul J.; Ronca, Enrico; Sayfutyarova, Elvira; Scheurer, Maximilian; Schurkus, Henry F.; Smith, James E. T.; Sun, Chong; Sun, Shi-Ning; Upadhyay, Shiv; Wagner, Lucas K.; Wang, Xiao; White, Alec; Whitfield, James Daniel; Williamson, Mark J.; Wouters, Sebastian; Yang, Jun; Yu, Jason M.; Zhu, Tianyu; Berkelbach, Timothy C.; Sharma, Sandeep; Sokolov, Alexander; Chan, Garnet Kin-Lic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent developments in the PySCF program package", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "PySCF is a Python-based general-purpose electronic structure platform that supports first-principles simulations of molecules and solids as well as accelerates the development of new methodology and complex computational workflows. This paper explains the design and philosophy behind PySCF that enables it to meet these twin objectives. With several case studies, we show how users can easily implement their own methods using PySCF as a development environment. We then summarize the capabilities of PySCF for molecular and solid-state simulations. Finally, we describe the growing ecosystem of projects that use PySCF across the domains of quantum chemistry, materials science, machine learning, and quantum information science. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 463, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2020, "Volume": 153, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 24109, "DOI": "10.1063/5.0006074", "DOI Link": "http://dx.doi.org/10.1063/5.0006074", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551896400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, ZH; Zeng, H; Zeng, XT; Chen, X; Wang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Zhenhua; Zeng, Hao; Zeng, Xiantao; Chen, Xi; Wang, Xiangyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of nullographite Conductive Concrete Mixed with Magnetite Sand Excited by Different Alkali Activators and Their Combinations on the Properties of Conductive Concrete", "Source Title": "BUILDINGS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to obtain conductive concrete with good electrical conductivity and good mechanical properties, nullographite and magnetite sand excited by different activators and their combinations are added to ordinary concrete to obtain high quality and efficient conductive concrete. The optimal mixture ratio of alkali-excited conductive concrete and the effects of different activators and their combinations on the mechanics and electrical conductivity of concrete were studied. The microstructure of alkali-excited conductive concrete was analyzed by scanning electron microscope (SEM) to study its conductive mechanism. Results show that the conductive concrete obtained by compounding sodium hydroxide, sodium sulfate and calcium hydroxide has optimal mechanical and electrical properties when the graphite is 6% cement, and magnetite sand is 40% fine aggregate. The conductive concrete sample prepared by this method has a flexural strength of 6.84 MPa, a compressive strength of 47.79 MPa and a resistivity of 4805 & omega;& BULL;cm (28 days). Compared with ordinary concrete (no nullographite and no magnetite sand), the compressive strength of conductive concrete is increased by 122.3%, the bending strength is increased by 116.5%, and the resistivity is reduced by 99.1%. SEM shows that the distribution of conductive materials in concrete is more uniform due to alkali excitation and calcium silicate hydrate (CSH) gel can be formed, which leads to better performance. The research in this paper is only a preliminary exploration of the characteristics of green conductive concrete, and the conductive heating characteristics and electromagnetic wave absorption properties of concrete, along with strength characteristics after adding conductive fillers, need to be further studied. It is suggested that further research should be carried out on the deicing characteristics of conductive concrete and the electromagnetic wave absorption properties used in stealth military engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 13, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1630, "DOI": "10.3390/buildings13071630", "DOI Link": "http://dx.doi.org/10.3390/buildings13071630", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001038184600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, YS; Nichele, F; Chi, H; Lodesani, A; Wu, YY; Ritter, MF; Haxell, DZ; Davydova, M; Ilic, S; Glezakou-Elbert, O; Varambally, A; Bergeret, S; Kamra, A; Fu, L; Lee, PA; Moodera, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Yasen; Nichele, Fabrizio; Chi, Hang; Lodesani, Alessandro; Wu, Yingying; Ritter, Markus F.; Haxell, Daniel Z.; Davydova, Margarita; Ilic, Stefan; Glezakou-Elbert, Ourania; Varambally, Amith; Bergeret, Sebastian; Kamra, Akashdeep; Fu, Liang; Lee, Patrick A.; Moodera, Jagadeesh S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ubiquitous Superconducting Diode Effect in Superconductor Thin Films", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The macroscopic coherence in superconductors supports dissipationless supercurrents that could play a central role in emerging quantum technologies. Accomplishing unequal supercurrents in the forward and backward directions would enable unprecedented functionalities. This nonreciprocity of critical super -currents is called the superconducting (SC) diode effect. We demonstrate the strong SC diode effect in conventional SC thin films, such as niobium and vanadium, employing external magnetic fields as small as 1 Oe. Interfacing the SC layer with a ferromagnetic semiconductor EuS, we further accomplish the nonvolatile SC diode effect reaching a giant efficiency of 65%. By careful control experiments and theoretical modeling, we demonstrate that the critical supercurrent nonreciprocity in SC thin films could be easily accomplished with asymmetrical vortex edge and surface barriers and the universal Meissner screening current governing the critical currents. Our engineering of the SC diode effect in simple systems opens the door for novel technologies while revealing the ubiquity of the Meissner screening effect induced SC diode effect in superconducting films, and it should be eliminated with great care in the search for exotic superconducting states harboring finite-momentum Cooper pairing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 97, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 13", "Publication Year": 2023, "Volume": 131, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27001, "DOI": "10.1103/PhysRevLett.131.027001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.027001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001052943000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZM; Hong, QL; Wang, XH; Huang, H; Chen, Y; Li, SN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zheng-Min; Hong, Qing-Ling; Wang, Xiao-Hui; Huang, Hao; Chen, Yu; Li, Shu-Ni", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RuP nulloparticles Anchored on N-doped Graphene Aerogels for Hydrazine Oxidation-Boosted Hydrogen Production", "Source Title": "ACTA PHYSICO-CHIMICA SINICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "'Green hydrogen' is a promising clean energy carrier for use instead of traditional fuels. For obtaining 'green hydrogen', electrochemical water splitting has been receiving considerable attention due to its ecofriendly and low-cost properties. However, the sluggish kinetics of the anodic oxygen evolution reaction (OER) reduces the efficiency of hydrogen production. Accordingly, the hydrazine oxidation reaction (HzOR) with low theoretical potential (-0.33 V vs. RHE) has been proposed as a reasonable alternative for the OER. In this study, graphene aerogel (GA) was utilized as a conductive substrate with a 3D porous framework. RuIII-polyethyleneimine (RuIII-PEI) complexes were adsorbed on the GA surface. Phytic acid (PA) was further adsorbed to form RuIII-PEI-GA-PA hybrids through the hydrogen bond interaction between PA and PEI, which can serve as a precursor to synthesize RuP nulloparticles anchored on N doped GA (RuP/N-GA) through the phosphorization reaction. In the pyrolysis process, the ultra-small RuP was formed at the GA surface. Additionally, the decomposition of PEI and PA can introduce abundant N and P heteroatoms into the structure of GA. As a result, RuP/N-GA hybrids achieve efficient HzOR with a low working potential of -54 mV at 10 mA & BULL;cm-2. Moreover, the novel RuP/N-GA hybrids with low Ru loading also exhibit a promising hydrogen evolution reaction (HER) activity with an overpotential of -19.6 mV at 10 mA & BULL;cm-2. Among various RuP/N-GA hybrids, the Tafel plot of HER at RuP/N-GA-900 reveals the smallest value to be 37.03 mV & BULL;dec-1, which affords the fastest HER kinetics. Meanwhile, the result suggests that the HER at RuP/N-GA-900 undergoes a Heyrovsky mechanism similar to that of Pt. The theoretical results revealed that the anchored structure and the presence of N heteroatoms can promote the HzOR on RuP nulloparticles. The free energy of hydrazine molecular adsorption on RuP/N-GA was -0.68 eV, indicating that N-doping in the RuP/N-GA structure can adjust the electronic structure of the Ru active site, which also contributes to the enhanced HzOR activity of the Ru site. Additionally, RuP/N-GA hybrids exhibited excellent cycling and long-term stability for both HER and HzOR, superior to those of commercial Pt/C. Based on the bifunctional activity of RuP/N-GA hybrids, the constructed two-electrode hydrazine split system exhibits an extremely low cell voltage of 41 mV at 10 mA & BULL;cm-2 for the hydrogen production, which achieves the goal of energy-saved hydrogen production at low voltage. The excellent electrocatalytic activity of RuP/N-GA hybrids is attributed to the ultrasmall RuP nulloparticles for abundant Ru active sites. Meanwhile, the synergistic effect between N-doping in GA frameworks with RuP nulloparticles contributes to the activity enhancement of RuP/N-GA hybrids, in which the 3D porous N-GA with few-layer morphology accelerates the electron and mass transfer and the electron interaction between N-GA and RuP nulloparticles promotes the electrocatalytic activity of RuP nulloparticles for both HER and HzOR. This study extends the bifunctional electrocatalyst for the HER and HzOR to achieve energy-saved hydrogen production and sheds new light on the design and synthesis of advanced electrocatalysts via the adsorption-phosphatization method.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2023, "Volume": 39, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2303028, "DOI": "10.3866/PKU.WHXB202303028", "DOI Link": "http://dx.doi.org/10.3866/PKU.WHXB202303028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001071597300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khan, MA; Memon, SA; Farooq, F; Javed, MF; Aslam, F; Alyousef, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khan, Mohsin Ali; Memon, Shazim Ali; Farooq, Furqan; Javed, Muhammad Faisal; Aslam, Fahid; Alyousef, Rayed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compressive Strength of Fly-Ash-Based Geopolymer Concrete by Gene Expression Programming and Random Forest", "Source Title": "ADVANCES IN CIVIL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fly ash (FA) is a residual from thermal industries that has been effectively utilized in the production of FA-based geopolymer concrete (FGPC). To avoid time-consuming and costly experimental procedures, soft computing techniques, namely, random forest regression (RFR) and gene expression programming (GEP), are used in this study to develop an empirical model for the prediction of compressive strength of FGPC. A widespread, reliable, and consistent database of compressive strength of FGPC is set up via a comprehensive literature review. +e database consists of 298 compressive strength data points. The influential parameters that are considered as input variables for modelling are curing temperature (T), curing time (t), age of the specimen (A), the molarity of NaOH solution (M), percent SiO2 solids to water ratio (% S/W) in sodium silicate (Na2SiO3) solution, percent volume of total aggregate (% A(G)), fine aggregate to the total aggregate ratio (F/A G), sodium oxide (Na2O) to water ratio (N/W) in Na2SiO3 solution, alkali or activator to the FA ratio (A(L)/F-A), Na2SiO3 to NaOH ratio (N-s/N-o), percent plasticizer (% P), and extra water added as percent FA (E-W %). RFR is an ensemble algorithm and gives outburst performance as compared to GEP. However, GEP proposed an empirical expression that can be used to estimate the compressive strength of FGPC. The accuracy and performance of both models are evaluated via statistical error checks, and external validation is considered. The proposed GEP equation is used for sensitivity analysis and parametric study and then compared with nonlinear and linear regression expressions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2021, "Volume": 2021, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6618407, "DOI": "10.1155/2021/6618407", "DOI Link": "http://dx.doi.org/10.1155/2021/6618407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617619500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, LJ; Xu, L; Rahmani, M; Neshev, D; Miroshnichenko, AE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Lujun; Xu, Lei; Rahmani, Mohsen; Neshev, Dragomir; Miroshnichenko, Andrey E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pushing the limit of high-Q mode of a single dielectric nullocavity", "Source Title": "ADVANCED PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-index dielectric resonators support different types of resonullt modes. However, it is challenging to achieve a high-Q factor in a single dielectric nullocavity due to the non-Hermitian property of the open system. We present a universal approach of finding out a series of high-Q resonullt modes in a single nonspherical dielectric cavity with a rectangular cross section by exploring the quasi bound-state-in-thecontinuum (QBIC). Unlike conventional methods relying on heavy brutal force computations (i.e., frequency scanning by the finite difference time domain method), our approach is built upon Mie mode engineering, through which many high-Q modes can be easily achieved by constructing avoid-crossing (or crossing) of the eigenvalue for pair-leaky modes. The calculated Q-factor of mode TE(5,7) can be up to Q(theory) = 2.3 x 10(4) for a freestanding square nullowire (NW) (n = 4), which is 64 times larger than the highest Q-factor (Q(theory) approximate to 360) reported so far in a single Si disk. Such high-Q modes can be attributed to suppressed radiation in the corresponding eigenchannels and simultaneously quenched electric (magnetic) field at momentum space. As a proof of concept, we experimentally demonstrate the emergence of the high-Q resonullt modes [Q approximate to 211 for mode TE(3,4), Q approximate to 380 for mode TE(3,5), and Q approximate to 294 for mode TM(3,5)] in the scattering spectrum of a single silicon NW.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 119, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16004, "DOI": "10.1117/1.AP.3.1.016004", "DOI Link": "http://dx.doi.org/10.1117/1.AP.3.1.016004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000646636300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de Jong, DH; Baoukina, S; Ingólfsson, HI; Marrink, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de Jong, Djurre H.; Baoukina, Svetlana; Ingolfsson, Helgi I.; Marrink, Siewert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Martini straight: Boosting performance using a shorter cutoff and GPUs", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In molecular dynamics simulations, sufficient sampling is of key importance and a continuous challenge in the field. The coarse grain Martini force field has been widely used to enhance sampling. In its original implementation, this force field applied a shifted Lennard-Jones potential for the non-bonded van der Waals interactions, to avoid problems related to a relatively short cutoff. Here we investigate the use of a straight cutoff Lennard-Jones potential with potential modifiers. Together with a Verlet neighbor search algorithm, the modified potential allows the use of GPUs to accelerate the computations in Gromacs. We find that this alternative potential has little influence on most of the properties studied, including partitioning free energies, bulk liquid properties and bilayer properties. At the same time, energy conservation is kept within reasonable bounds. We conclude that the newly proposed straight cutoff approach is a viable alternative to the standard shifted potentials used in Martini, offering significant speedup even in the absence of GPUs. (C) 2015 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 348, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 199, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 7, "Article Number": null, "DOI": "10.1016/j.cpc.2015.09.014", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2015.09.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367113200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZY; Liu, YL; Gou, GQ; Gao, W; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Z. Y.; Liu, Y. L.; Gou, G. Q.; Gao, W.; Chen, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of heat input on interfacial characterization of the butter joint of hot-rolling CP-Ti/Q235 bimetallic sheets by Laser plus CMT", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Composite structures made of 2 mm-thick titanium and 10 mm-thick carbon steel are widely used in infrastructures such as long-distance gas transportation. However, cracking, which is caused by intermetallic compounds (ICs), is a dominate failure mode in welds of this structure. Thus, a common way to improve the in-service life of is reduce the number of ICs. In this paper, we employ a novel hybrid welding method to fabricate composite structures of TA(2) titanium and Q235 carbon steel. Specifically, Ti and carbon steel is welded by laser and double Cold Metal Transfer (CMT) welding, respectively. The microstructure near the interface of Ti and steel is then examined using SEM, EBSD, EDS, with emphasis on the ICs in terms of chemical elements and morphologies. Results show that FeTi and Fe2Ti are the main ICs near the interface, and responsible for the failure of the welds. The effect of welding heat input on the formation of ICs is investigated as well. Results show that ICs are smaller when the heat input is low. Under low heat input circumstance, the tensile strength of the weld can reach up to 420 MPa.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 176, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10020, "DOI": "10.1038/s41598-021-89343-9", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-89343-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658810900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yadav, R; Bogdanov, NA; Katukuri, VM; Nishimoto, S; van den Brink, J; Hozoi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yadav, Ravi; Bogdanov, Nikolay A.; Katukuri, Vamshi M.; Nishimoto, Satoshi; van den Brink, Jeroen; Hozoi, Liviu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Kitaev exchange and field-induced quantum spin-liquid states in honeycomb α-RuCl3", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large anisotropic exchange in 5d and 4d oxides and halides open the door to new types of magnetic ground states and excitations, inconceivable a decade ago. A prominent case is the Kitaev spin liquid, host of remarkable properties such as protection of quantum information and the emergence of Majorana fermions. Here we discuss the promise for spin-liquid behavior in the 4d(5) honeycomb halide alpha-RuCl3. From advanced electronic-structure calculations, we find that the Kitaev interaction is ferromagnetic, as in 5d(5) iridium honeycomb oxides, and indeed defines the largest superexchange energy scale. A ferromagnetic Kitaev coupling is also supported by a detailed analysis of the field-dependent magnetization. Using exact diagonalization and density-matrix renormalization group techniques for extended Kitaev-Heisenberg spin Hamiltonians, we find indications for a transition from zigzag order to a gapped spin liquid when applying magnetic field. Our results offer a unified picture on recent magnetic and spectroscopic measurements on this material and open new perspectives on the prospect of realizing quantum spin liquids in d(5) halides and oxides in general.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 226, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37925, "DOI": "10.1038/srep37925", "DOI Link": "http://dx.doi.org/10.1038/srep37925", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388806200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Takamoto, S; Shinagawa, C; Motoki, D; Nakago, K; Li, WW; Kurata, I; Watanabe, T; Yayama, Y; Iriguchi, H; Asano, Y; Onodera, T; Ishii, T; Kudo, T; Ono, H; Sawada, R; Ishitani, R; Ong, M; Yamaguchi, T; Kataoka, T; Hayashi, A; Charoenphakdee, N; Ibuka, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Takamoto, So; Shinagawa, Chikashi; Motoki, Daisuke; Nakago, Kosuke; Li, Wenwen; Kurata, Iori; Watanabe, Taku; Yayama, Yoshihiro; Iriguchi, Hiroki; Asano, Yusuke; Onodera, Tasuku; Ishii, Takafumi; Kudo, Takao; Ono, Hideki; Sawada, Ryohto; Ishitani, Ryuichiro; Ong, Marc; Yamaguchi, Taiki; Kataoka, Toshiki; Hayashi, Akihide; Charoenphakdee, Nontawat; Ibuka, Takeshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards universal neural network potential for material discovery applicable to arbitrary combination of 45 elements", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Existing neural network potentials are generally designed for narrow target materials. Here the authors develop a neural network potential which is able to handle any combination of 45 elements and show its applicability in multiple domains. Computational material discovery is under intense study owing to its ability to explore the vast space of chemical systems. Neural network potentials (NNPs) have been shown to be particularly effective in conducting atomistic simulations for such purposes. However, existing NNPs are generally designed for narrow target materials, making them unsuitable for broader applications in material discovery. Here we report a development of universal NNP called PreFerred Potential (PFP), which is able to handle any combination of 45 elements. Particular emphasis is placed on the datasets, which include a diverse set of virtual structures used to attain the universality. We demonstrated the applicability of PFP in selected domains: lithium diffusion in LiFeSO4F, molecular adsorption in metal-organic frameworks, an order-disorder transition of Cu-Au alloys, and material discovery for a Fischer-Tropsch catalyst. They showcase the power of PFP, and this technology provides a highly useful tool for material discovery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 30", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2991, "DOI": "10.1038/s41467-022-30687-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30687-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805647600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, D; Wu, ZH; Yan, YY; Cao, J; Yang, XL; Zhao, YL; Cao, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Ding; Wu, Zihao; Yan, Yuying; Cao, Jin; Yang, Xuelin; Zhao, Yulong; Cao, Bingyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance investigation and design optimization of a battery thermal management system with thermoelectric coolers and phase change materials", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a novel battery thermal management system (BTMS) integrated with thermoelectric coolers (TECs) and phase change materials (PCMs) is developed to ensure the temperature working environment of batteries, where a fin framework is adopted to enhance the heat transfer. By establishing a transient thermal-electric-fluid multi-physics field numerical model, the thermal performance of the BTMS is thoroughly examined in two cases. The findings demonstrate that increasing the TEC input current, fin length, and thickness is beneficial for reducing the maximum temperature and PCM liquid fraction. Nevertheless, although the increase in fin length can lower the temperature difference, the influence of fin thickness and TEC input current on the temperature difference is tiny. Based on the numerical findings, the optimal fin length and thickness of 7 mm and 3 mm are obtained. In this situation, when the TEC input current is 3 A, the maximum temperature, temperature difference, and PCM liquid fraction in Case 1 are 315.10 K, 2.39 K, and 0.002, respectively, and those are respectively 318.24 K, 3.60 K, and 0.181 in Case 2. The configuration of Case 1 outperforms that of Case 2, due to the fewer TECs and greater distance from the battery pack to the TEC within Case 2. When experiencing a higher battery discharge rate, the TEC input current should also be correspondingly increased to ensure the temperature performance of the battery. The relative findings contribute to new insights into battery thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2024, "Volume": 434, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 139834, "DOI": "10.1016/j.jclepro.2023.139834", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2023.139834", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001130014000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Ji-Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fractal calculus and its geometrical explanation", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fractal calculus is very simple but extremely effective to deal with phenomena in hierarchical or porous media. Its operation is almost same with that by the advanced calculus, making it much accessible to all non-mathematicians. This paper begins with the basic concept of fractal gradient of temperature, i.e., the temperature change between two points in a fractal medium, to reveal the basic properties of fractal calculus. The fractal velocity and fractal material derivative are then introduced to deduce laws for fluid mechanics and heat conduction in fractal space. Conservation of mass in a fractal space is geometrically explained, and an approximate transform of a fractal space on a smaller scale into its continuous partner on a larger scale is illustrated by a nullofiber membrane, which is smooth on any observable scales, but its air permeability has to studied in a nullo scale, under such a small scale, the nullofiber membrane becomes a porous one. Finally an example is given to explain cocoon's heat-proof property, which cannot be unveiled by advanced calculus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 467, "Times Cited, All Databases": 469, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 272, "End Page": 276, "Article Number": null, "DOI": "10.1016/j.rinp.2018.06.011", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2018.06.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443868900043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, V; Tang, G; Liu, YC; Wang, RT; Mizuseki, H; Kawazoe, Y; Nara, J; Geng, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Vei; Tang, Gang; Liu, Ya-Chao; Wang, Ren-Tao; Mizuseki, Hiroshi; Kawazoe, Yoshiyuki; Nara, Jun; Geng, Wen Tong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Throughput Computational Screening of Two-Dimensional Semiconductors", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials have attracted great attention mainly due to their unique physical properties and ability to fulfill the demands of future nulloscale devices. By performing high-throughput first-principles calculations combined with a semiempirical van der Waals dispersion correction, we have screened 73 direct-and 183 indirect-gap 2D nonmagnetic semiconductors from nearly 1000 monolayers according to the criteria for thermodynamic, mechanical, dynamic, and thermal stabilities and conductivity type. We present the calculated lattice constants, formation energy, Young's modulus, Poisson's ratio, shear modulus, anisotropic effective mass, band structure, band gap, ionization energy, electron affinity, and simulated scanning tunnel microscopy for each candidate meeting our criteria. The resulting 2D semiconductor database (2DSdb) can be accessed via the Web site https://materialsdb.cn/2dsdb/index.html. The 2DSdb provides an ideal platform for computational modeling and design of new 2D semiconductors and heterostructures in photocatalysis, nulloscale devices, and other applications. Further, a linear fitting model was proposed to evaluate band gap, ionization energy, and electron affinity of 2D semiconductors from the density functional theory (DFT) calculated data as initial input. This model can be as precise as hybrid DFT but with much lower computational cost.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 130, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2022, "Volume": 13, "Issue": 50, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11581, "End Page": 11594, "Article Number": null, "DOI": "10.1021/acs.jpclett.2c02972", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.2c02972", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000894798400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kaçal, MR; Akman, F; Sayyed, MI; Akman, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kacal, M. R.; Akman, F.; Sayyed, M., I; Akman, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluation of gamma-ray and neutron attenuation properties of some polymers", "Source Title": "NUCLEAR ENGINEERING AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, we determined the gamma-ray attenuation characteristics of eight different polymers(Polyamide (Nylon 6) (PA-6), polyacrylonitrile (PAN), polyvinylidenechloride (PVDC), polyaniline (PANI), polyethyleneterephthalate (PET), polyphenylenesulfide (PPS), polypyrrole (PPy) and polytetrafluoroethylene (PTFE)) using transmission geometry utilizing the high resolution HPGe detector and different radioactive sources in the energy range 81-1333 keV. The experimental linear attenuation coefficient values are compared with theoretical data (WinXCOM data). The linear attenuation coefficient of all polymers reduced quickly with the increase in energy, at the beginning, while decrease more slowly in the region from 267 keV to 835 keV. The effective atomic number of PVDC and PTFE are comparatively higher than the Z(eff) of the remaining polymers, while PA-6 possesses the lowest effective atomic number. The half value layer results showed that PTFE (C2F4, highest density) is more effective to attenuate the gamma photons. Also, the theoretical results of macroscopic effective removal cross section for fast neutrons (Sigma(R)) were computed to investigate the neutron attenuation characteristics. It is found that the Sigma(R) values of the eight investigated polymers are close and ranged from 0.07058 cm(-1) for PVDC to 0.11510 cm(-1) for PA-6. (C) 2018 Korean Nuclear Society, Published by Elsevier Korea LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 51, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 818, "End Page": 824, "Article Number": null, "DOI": "10.1016/j.net.2018.11.011", "DOI Link": "http://dx.doi.org/10.1016/j.net.2018.11.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462778100022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kimchi, I; Nahum, A; Senthil, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kimchi, Itamar; Nahum, Adam; Senthil, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Valence Bonds in Random Quantum Magnets: Theory and Application to YbMgGaO4", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We analyze the effect of quenched disorder on spin-1/2 quantum magnets in which magnetic frustration promotes the formation of local singlets. Our results include a theory for 2D valence-bond solids subject to weak bond randomness, as well as extensions to stronger disorder regimes where we make connections with quantum spin liquids. We find, on various lattices, that the destruction of a valence-bond solid phase by weak quenched disorder leads inevitably to the nucleation of topological defects carrying spin-1/2 moments. This renormalizes the lattice into a strongly random spin network with interesting low-energy excitations. Similarly, when short-ranged valence bonds would be pinned by stronger disorder, we find that this putative glass is unstable to defects that carry spin-1/2 magnetic moments, and whose residual interactions decide the ultimate low-energy fate. Motivated by these results we conjecture Lieb-SchultzMattis- like restrictions on ground states for disordered magnets with spin 1/2 per statistical unit cell. These conjectures are supported by an argument for 1D spin chains. We apply insights from this study to the phenomenology of YbMgGaO4, a recently discovered triangular lattice spin-1/2 insulator which was proposed to be a quantum spin liquid. We instead explore a description based on the present theory. Experimental signatures, including unusual specific heat, thermal conductivity, and dynamical structure factor, and their behavior in a magnetic field, are predicted from the theory, and compare favorably with existing measurements on YbMgGaO4 and related materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2018, "Volume": 8, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31028, "DOI": "10.1103/PhysRevX.8.031028", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.8.031028", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439978400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Büttner, F; Lemesh, I; Beach, GSD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Buttner, Felix; Lemesh, Ivan; Beach, Geoffrey S. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of isolated magnetic skyrmions: From fundamentals to room temperature applications", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic skyrmions are topological quasiparticles of great interest for data storage applications because of their small size, high stability, and ease of manipulation via electric current. However, although models exist for some limiting cases, there is no universal theory capable of accurately describing the structure and energetics of all skyrmions. The main barrier is the complexity of non-local stray field interactions, which are usually included through crude approximations. Here we present an accurate analytical framework to treat isolated skyrmions in any material, assuming only a circularly-symmetric 360 degrees domain wall profile and a homogeneous magnetization profile in the out-of-plane direction. We establish the first rigorous criteria to distinguish stray field from DMI skyrmions, resolving a major dispute in the community. We discover new phases, such as bi-stability, a phenomenon unknown in magnetism so far. We predict materials for sub-10 nm zero field room temperature stable skyrmions suitable for applications. Finally, we derive analytical equations to describe current-driven dynamics, find a topological damping, and show how to engineer materials in which compact skyrmions can be driven at velocities >1000 m/s.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 13", "Publication Year": 2018, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4464, "DOI": "10.1038/s41598-018-22242-8", "DOI Link": "http://dx.doi.org/10.1038/s41598-018-22242-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427243300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, Q; Song, ZN; Bramante, RC; Ndione, PF; Tirawat, R; Berry, JJ; Yan, YF; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Qi; Song, Zhaoning; Bramante, Rosemary C.; Ndione, Paul F.; Tirawat, Robert; Berry, Joseph J.; Yan, Yanfa; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient bifacial single-junction perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bifacial photovoltaics (PV) harvest solar irradiance from both their front and rear surfaces, boosting energy conversion efficiency to maximize their electrical power production. For single-junction perovskite solar cells (PSCs), the performance of bifacial configurations is still far behind that of their state-of-the-art monofacial counterparts. Here, we report on highly efficient, bifacial, single-junction PSCs based on the p-i-n (or inverted) architecture. We used optical and electrical modeling to design a transparent conducting rear electrode for bifacial PSCs to enable optimized efficiency under a variety of albedo illumination conditions. The bifaciality of the PSCs was about 91%-93%. Under concurrent bifacial measurement conditions, we obtained equivalent, stabilized bifacial power output densities of 26.9, 28.5, and 30.1 mW/cm2 under albedos of 0.2, 0.3, and 0.5, respectively. We further showed that bifacial perovskite PV technology has the potential to outperform its monofacial counterparts with higher energy yields and lower levelized cost of energy (LCOE).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 19", "Publication Year": 2023, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.joule.2023.06.001", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2023.06.001", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001047725200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, GY; Wang, YB; Dewaele, A; Wu, C; Fratanduono, DE; Eggert, J; Klotz, S; Dziubek, KF; Loubeyre, P; Fat'yanov, OV; Asimow, PD; Mashimo, T; Wentzcovitch, RMM; Bass, J; Bi, Y; He, DW; Khishchenko, KV; Leinenweber, K; Li, BS; Sakai, T; Tsuchiya, T; Shimizu, K; Yamazaki, D; Mezouar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Guoyin; Wang, Yanbin; Dewaele, Agnes; Wu, Christine; Fratanduono, Dayne E.; Eggert, Jon; Klotz, Stefan; Dziubek, Kamil F.; Loubeyre, Paul; Fat'yanov, Oleg, V; Asimow, Paul D.; Mashimo, Tsutomu; Wentzcovitch, Renata M. M.; Bass, Jay; Bi, Yan; He, Duanwei; Khishchenko, Konstantin, V; Leinenweber, Kurt; Li, Baosheng; Sakai, Takeshi; Tsuchiya, Taku; Shimizu, Katsuya; Yamazaki, Daisuke; Mezouar, Mohamed", "Book Author Full Names": null, "Group Authors": "IPPS Task Grp", "Article Title": "Toward an international practical pressure scale: A proposal for an IPPS ruby gauge (IPPS-Ruby2020)", "Source Title": "HIGH PRESSURE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At the 26th AIRAPT conference in 2017, a task group was formed to work on an International Practical Pressure Scale (IPPS). This report summarizes the activities of the task group toward an IPPS ruby gauge. We have selected three different approaches to establishing the relation between pressure (P) and ruby R1-line shift (Delta lambda) with three groups of optimal reference materials for applying these approaches. Using a polynomial form of the second order, the recommended ruby gauge (referred as Ruby2020) is expressed by: P[GPa]=1.87(+/- 0.01) x 10(3) (Delta lambda/lambda(0))[1 + 5.63(+/- 0.03)(Delta lambda/lambda(0))], where lambda(0) is the wavelength of the R1-line near 694.25 nm at ambient condition. In June of 2020, the Executive Committee of AIRAPT endorsed the proposed Ruby2020. We encourage high-pressure practitioners to utilize Ruby2020 within its applicable pressure range (up to 150 GPa), so that pressure data can be directly compared across laboratories and amended consistently as better scales emerge in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2020, "Volume": 40, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 299, "End Page": 314, "Article Number": null, "DOI": "10.1080/08957959.2020.1791107", "DOI Link": "http://dx.doi.org/10.1080/08957959.2020.1791107", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551314500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alizadeh, R; Abad, JMN; Ameri, A; Mohebbi, MR; Mehdizadeh, A; Zhao, D; Karimi, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alizadeh, Rasool; Abad, Javad Mohebbi Najm; Ameri, Abolhasan; Mohebbi, Mohammad Reza; Mehdizadeh, Amirfarhang; Zhao, Dan; Karimi, Nader", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A machine learning approach to the prediction of transport and thermodynamic processes in multiphysics systems-heat transfer in a hybrid nullofluid flow in porous media", "Source Title": "JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Comprehensive analyses of transport phenomena and thermodynamics of complex multiphysics systems are laborious and computationally intensive. Yet, such analyses are often required during the design of thermal and process equipment. As a remedy, this paper puts forward a novel approach to the prediction of transport behaviours of multiphysics systems, offering significant reductions in the computational time and cost. This is based on machine learning techniques that utilize the data generated by computational fluid dynamics for training purposes. The physical system under investigation includes a stagnation-point flow of a hybrid nullofluid (Cu-Al2O3/Water) over a blunt object embedded in porous media. The problem further involves mixed convection, entropy generation, local thermal non-equilibrium and non-linear thermal radiation within the porous medium. The SVR (Support Machine Vector) model is employed to approximate velocity, temperature, Nusselt number and shear-stress as well as entropy generation and Bejan number functions. Further, PSO meta-heuristic algorithm is applied to propose correlations for Nusselt number and shear stress. The effects of Nusselt number, temperature fields and shear stress on the surface of the blunt-body as well as thermal and frictional entropy generation are analysed over a wide range of parameters. Further, it is shown that the generated correlations allow a quantitative evaluation of the contribution of a large number of variables to Nusselt number and shear stress. This makes the combined computational and artificial intelligence (AI) approach most suitable for design purposes. (C) 2021 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 135, "Times Cited, All Databases": 135, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 306, "Article Number": null, "DOI": "10.1016/j.jtice.2021.03.043", "DOI Link": "http://dx.doi.org/10.1016/j.jtice.2021.03.043", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000670893900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Suominen, HJ; Kjaergaard, M; Hamilton, AR; Shabani, J; Palmstrom, CJ; Marcus, CM; Nichele, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Suominen, H. J.; Kjaergaard, M.; Hamilton, A. R.; Shabani, J.; Palmstrom, C. J.; Marcus, C. M.; Nichele, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zero-Energy Modes from Coalescing Andreev States in a Two-Dimensional Semiconductor-Superconductor Hybrid Platform", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We investigate zero-bias conductance peaks that arise from coalescing subgap Andreev states, consistent with emerging Majorana zero modes, in hybrid semiconductor-superconductor wires defined in a two-dimensional InAs/Al heterostructure using top-down lithography and gating. The measurements indicate a hard superconducting gap, ballistic tunneling contact, and in-plane critical fields up to 3 T. Top-down lithography allows complex geometries, branched structures, and straightforward scaling to multicomponent devices compared to structures made from assembled nullowires.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 26", "Publication Year": 2017, "Volume": 119, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 176805, "DOI": "10.1103/PhysRevLett.119.176805", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.119.176805", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413770200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schmid, O; Stoeger, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schmid, Otmar; Stoeger, Tobias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface area is the biologically most effective dose metric for acute nulloparticle toxicity in the lung", "Source Title": "JOURNAL OF AEROSOL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study we provide guidance on the biologically most relevant dose metric for pulmonary toxicity of biopersistent, spherical nulloparticles (NPs). A retrospective analysis of nine in vivo studies on particle-induced, acute pulmonary toxicity in animal models (mouse, rat) was performed encompassing five different types of nullomaterials (polystyrene, titanium dioxide, carbonaceous materials, transition metal oxides (Co, Ni, Zn) and hydrothermally synthesized a-quartz) with a wide range of primary particle diameters (9-535 nm) and mass-specific BET surface areas (6-800 m(2)/g). The acute influx of polymorphonuclear neutrophils (PMNs) into the lungs after intratracheal instillation of NPs was chosen as a toxicological endpoint for acute lung inflammation. The allometrically scaled toxicological data were investigated with respect to various dose metrics, namely (primary) particle number, joint length, BET and geometric surface area, volume and mass. Surface area is identified as the biologically most relevant dose metric for spherical NPs explaining about 80% of the observed variability in acute pulmonary toxicity (R-2=0.77). None of the other dose metrics explains more than 50% of the observed variability in pulmonary inflammation. Moreover, using surface area as the dose metric allows identification of material-based toxicity classes independent of particle size. Typical materials without intrinsic toxicity - here referred to as low-solubility, low toxicity (LSLT) materials show low surface-specific toxicity with an EC50 dose of 175 m(2)/g-lung (geometric mean; sigma(g)=2.2), where EC50 represents the dose inducing 50% of the maximum effect (here 30% PMN). In contrast, transition metal oxides (here Co, Ni, Zn) materials known for their intrinsic toxicity - display a 12-fold enhanced surface-specific toxicity compared to LSLT particles (EC50 = 15 m(2)/g-lung). This analysis implies that surface-related modes of action are driving acute pulmonary toxicity for the types of NPs investigated here. The relevance of other dose metrics such as number and volume is acknowledged in the context of different modes of action, namely shape-induced toxicity (fiber paradigm) and extremely high particle lung burden (overload conditions), respectively. So which dose metric should be monitored by aerosol scientists involved in health related aerosol exposure measurements? The short answer is - all of them (except length), but there is a strong preference towards surface area. (C) 2016 The Authors. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 283, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 99, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 133, "End Page": 143, "Article Number": null, "DOI": "10.1016/j.jaerosci.2015.12.006", "DOI Link": "http://dx.doi.org/10.1016/j.jaerosci.2015.12.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381589700015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naushad, M; ALOthman, ZA; Awual, MR; Alfadul, SM; Ahamad, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naushad, Mu.; ALOthman, Zeid Abdullah; Awual, Md. Rabiul; Alfadul, Sulaiman M.; Ahamad, Tansir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of rose Bengal dye from aqueous solution by amberlite Ira-938 resin: kinetics, isotherms, and thermodynamic studies", "Source Title": "DESALINATION AND WATER TREATMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the effectiveness of amberlite IRA-938 resin for Rose Bengal (RB) dye removal from aqueous phase was evaluated. For the RB dye removal, equilibrium was achieved within 45min because rate of adsorption was fast. The adsorption equilibrium for RB dye onto amberlite IRA-938 resin was in good agreement with Langmuir adsorption isotherm. It was observed that amberlite IRA-938 resin had excellent RB dye adsorption capacity (q(m)=142.86mgg(-1) at 23 degrees C). The environmental applicability of amberlite IRA-938 resin was performed in the separation of RB dye from the tap water sample spiked with 50mgL(-1) RB dye solution. The breakthrough and exhaustive capacity were 100 and 325mgg(-1), respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2016, "Volume": 57, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13527, "End Page": 13533, "Article Number": null, "DOI": "10.1080/19443994.2015.1060169", "DOI Link": "http://dx.doi.org/10.1080/19443994.2015.1060169", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371991000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YB; Mei, JW; Ye, F; Chen, WQ; Yang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yu-Bo; Mei, Jia-Wei; Ye, Fei; Chen, Wei-Qiang; Yang, Fan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "s± -Wave Pairing and the Destructive Role of Apical-Oxygen Deficiencies in La3Ni2O7 under Pressure", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, the bilayer perovskite nickelate La3Ni2O7 has been reported to show evidence of hightemperature superconductivity (SC) under a moderate pressure of about 14 GPa. To investigate the superconducting mechanism, pairing symmetry, and the role of apical-oxygen deficiencies in this material, we perform a random-phase approximation based study on a bilayer model consisting of the d(x)(- y)(2)(2) and d(3z)(-r)(2)(2) orbitals of Ni atoms in both the pristine crystal and the crystal with apical-oxygen deficiencies. Our analysis reveals an s(+/-)-wave pairing symmetry driven by spin fluctuations. The crucial role of pressure lies in that it induces the emergence of the gamma pocket, which is involved in the strongest Fermi-surface nesting. We further found the emergence of local moments in the vicinity of apical-oxygen deficiencies, which significantly suppresses the T-c. Therefore, it is possible to significantly enhance the T-c by eliminating oxygen deficiencies during the synthesis of the samples.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2023, "Volume": 131, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 236002, "DOI": "10.1103/PhysRevLett.131.236002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.236002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001153351000006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, WP; Hou, H; Zhang, YT; Liu, W; Zhao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Weipeng; Hou, Hua; Zhang, Yuntao; Liu, Wei; Zhao, Yuhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal and solute diffusion in a-Mg dendrite growth of Mg-5wt.%Zn alloy: A phase-field study", "Source Title": "JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal and solute diffusion plays an important role in a-Mg dendrite growth, the diffu-sion mechanism of which is still unclear. Here, thermal and solute diffusion in a-Mg dendrite growth of Mg-5wt.%Zn alloy under non-isothermal solidification were studied using the phase-field method. Results show that solidification latent heat will be concen-trated at the dendrite intersection, which makes thermal field distribution non-uniform, and it is similar to the profile formed by connecting primary dendrite tips. The increase in temperature will shorten primary dendrite arms, reduce side-branching development, increase dendrite tip temperature, and decrease dendrite tip concentration stability. Moreover, solidification latent heat will first diffuse to undercooled melt, then diffuse to other areas, finally, system temperature tends to be unified. The variation range of con-centration difference is very small in the solidification process, and solute field distribution is uniform all the time. The local high-concentration areas will be formed after the su-perposition of the solute enrichment layer, and solute atoms will first diffuse to under-cooled melt through the solid-liquid interface, and then concentrate between side-branching and dendrites.& COPY; 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY-JUN", "Publication Year": 2023, "Volume": 24, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8401, "End Page": 8413, "Article Number": null, "DOI": "10.1016/j.jmrt.2023.05.024", "DOI Link": "http://dx.doi.org/10.1016/j.jmrt.2023.05.024", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042211100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, L; Xue, N; Li, WW; Liu, S; Tu, ZB; Chen, YW; Zhang, JT; Dai, S; Liu, QJ; Shi, XX; Wang, TL; Chen, ML; Huang, YQ; Xu, FL; Zhu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Ling; Xue, Na; Li, Weiwei; Liu, Song; Tu, Zhibiao; Chen, Yingwei; Zhang, Jitang; Dai, Sheng; Liu, Qijie; Shi, Xinxing; Wang, Tianle; Chen, Mengliang; Huang, Yingqi; Xu, Feilong; Zhu, Liu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Cold-Spray Parameters on Surface Roughness, Thickness and Adhesion of Copper-Based Composite Coating on Aluminum Alloy 6061 T6 Substrate", "Source Title": "PROCESSES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A solid-state cold-spray technique was employed for depositing the copper-coated graphite reinforced copper-based composite coatings on aluminum alloy 6061 T6 substrate under different process parameters. The optimum process parameters of the cold-sprayed coatings were predicted in terms of surface roughness, thickness and adhesion. The surface roughness was measured using a 3D profilometer, the thickness and element constitution were detected by an optical microscope and scanning electron microscope furnished with an energy-dispersive spectral analyzer and the adhesion was detected by the scratch test method. The microstructures of the deposited coatings were also observed by a scanning electron microscope. The results show that when the coating is not oxidized and dense, the copper-coated graphite reinforced copper-based composite coating at 800 degrees C, 5.5 MPa, possesses the lowest surface roughness, the maximum thickness and the highest adhesion among the cold-sprayed coatings. In addition, the surface roughness, thickness and adhesion of the deposited coatings are all linear with particle velocity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 959, "DOI": "10.3390/pr11030959", "DOI Link": "http://dx.doi.org/10.3390/pr11030959", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959156000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stier, AV; Wilson, NP; Velizhanin, KA; Kono, J; Xu, X; Crooker, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stier, A. V.; Wilson, N. P.; Velizhanin, K. A.; Kono, J.; Xu, X.; Crooker, S. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetooptics of Exciton Rydberg States in a Monolayer Semiconductor", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report 65 T magnetoabsorption spectroscopy of exciton Rydberg states in the archetypal monolayer semiconductor WSe2. The strongly field-dependent and distinct energy shifts of the 2s, 3s, and 4s excited neutral excitons permits their unambiguous identification and allows for quantitative comparison with leading theoretical models. Both the sizes (via low-field diamagnetic shifts) and the energies of the ns exciton states agree remarkably well with detailed numerical simulations using the nonhydrogenic screened Keldysh potential for 2D semiconductors. Moreover, at the highest magnetic fields, the nearly linear diamagnetic shifts of the weakly bound 3s and 4s excitons provide a direct experimental measure of the exciton's reduced mass m(r) = 0.20 +/- 0.01m(0).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 222, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2018, "Volume": 120, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57405, "DOI": "10.1103/PhysRevLett.120.057405", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.057405", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423991600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Q; Kewenig, M; Schneider, M; Verba, R; Kohl, F; Heinz, B; Geilen, M; Mohseni, M; Lägel, B; Ciubotaru, F; Adelmann, C; Dubs, C; Cotofana, SD; Dobrovolskiy, OV; Brächer, T; Pirro, P; Chumak, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Q.; Kewenig, M.; Schneider, M.; Verba, R.; Kohl, F.; Heinz, B.; Geilen, M.; Mohseni, M.; Laegel, B.; Ciubotaru, F.; Adelmann, C.; Dubs, C.; Cotofana, S. D.; Dobrovolskiy, O. V.; Braecher, T.; Pirro, P.; Chumak, A. V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A magnonic directional coupler for integrated magnonic half-adders", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnons, the quanta of spin waves, could be used to encode information in beyond-Moore computing applications, and magnonic device components, including logic gates, transistors and units for non-Boolean computing, have already been developed. Magnonic directional couplers, which can function as circuit building blocks, have also been explored, but have been impractical because of their millimetre dimensions and multimode spectra. Here, we report a magnonic directional coupler based on yttrium iron garnet that has submicrometre dimensions. The coupler consists of single-mode waveguides with a width of 350 nm. We use the amplitude of a spin wave to encode information and to guide it to one of the two outputs of the coupler depending on the signal magnitude, frequency and the applied magnetic field. Using micromagnetic simulations, we also propose an integrated magnonic half-adder that consists of two directional couplers and we investigate its functionality for information processing within the magnon domain. The proposed half-adder is estimated to consume energy in the order of attojoules. A magnonic directional coupler with submicrometre dimensions could be used as a building block for integrated magnonic devices, such as half-adders, that have low energy consumption and small footprint.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 765, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41928-020-00485-6", "DOI Link": "http://dx.doi.org/10.1038/s41928-020-00485-6", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000580737500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Poncé, S; Margine, ER; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ponce, Samuel; Margine, Elena R.; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Towards predictive many-body calculations of phonon-limited carrier mobilities in semiconductors", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We probe the accuracy limit of ab initio calculations of carrier mobilities in semiconductors, within the framework of the Boltzmann transport equation. By focusing on the paradigmatic case of silicon, we show that fully predictive calculations of electron and hole mobilities require many-body quasiparticle corrections to band structures and electron-phonon matrix elements, the inclusion of spin-orbit coupling, and an extremely fine sampling of inelastic scattering processes in momentum space. By considering all these factors we obtain excellent agreement with experiment, and we identify the band effective masses as the most critical parameters to achieve predictive accuracy. Our findings set a blueprint for future calculations of carrier mobilities, and pave the way to engineering transport properties in semiconductors by design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 271, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 27", "Publication Year": 2018, "Volume": 97, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 121201, "DOI": "10.1103/PhysRevB.97.121201", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.121201", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428388500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, X; Bao, S; Zhang, L; Zhang, XY; Jiao, L; Qi, H; Wang, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, X. J.; Bao, S. J.; Zhang, L. W.; Zhang, X. Y.; Jiao, L. S.; Qi, H. B.; Wang, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Zr on microstructure and properties of TC4 alloy fabricated by laser additive manufacturing", "Source Title": "JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, the effect of Zr on the microstructure of laser additive manufactured Ti-6Al-4V (TC4) alloy is studied by adding different contents of Zr (0%, 15%, 30%, 45%), and the mechanisms of strengthening and corrosion passivation are also discussed. The results show that the stability of b phase increases with increasing Zr content, when Zr content reaches 45%, the b phase is completely retained to room temperature. The microstructure of TC4 can be refined by Zr (when the content of Zr is less than or equal to 30%), and the ultra-fine martensite with twinning substructure can be formed. With the increase of Zr content to 45%, the strength of the alloy increases from 1044 MPa to 1360 MPa. The elongation decreases from 10.8% to 7.7% with the increase of Zr content to 30%. However, as the content of Zr increases to 45%, the elongation increases to 12.5%. The abnormal phenomenon of elongation is mainly due to the change of deformation mechanism from dislocation slip to stress-induced martensite transformation with the content of Zr increasing to 45%. The corrosion resistance of TC4-Zr alloys increases significantly with the increase of Zr content, which is mainly attributed to the better corrosion resistance of Zr and the better protection of ZrO2 formed in passivation film. (c) 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 79, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY-JUN", "Publication Year": 2023, "Volume": 24, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8782, "End Page": 8792, "Article Number": null, "DOI": "10.1016/j.jmrt.2023.05.137", "DOI Link": "http://dx.doi.org/10.1016/j.jmrt.2023.05.137", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001019349300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HH; Lu, YG; Cai, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Honghui; Lu, Yegang; Cai, Linying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wavelength-shift-free racetrack resonator hybrided with phase change material for photonic in-memory computing", "Source Title": "OPTICS EXPRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The photonic in-memory computing architecture based on phase change materials (PCMs) is increasingly attracting widespread attention due to its high computational efficiency and low power consumption. However, PCM-based microring resonator photonic computing devices face challenges in terms of resonullt wavelength shift (RWS) for large-scale photonic network. Here, we propose a PCM-slot-based 1 x 2 racetrack resonator with free wavelength shift for in-memory computing. The low-loss PCMs such as Sb2Se3 and Sb2S3 are utilized to fill the waveguide slot of the resonator for the low insertion (IL) and high extinction ratio (ER). The Sb2Se3-slot-based racetrack resonator has an IL of 1.3 (0.1) dB and an ER of 35.5 (8.6) dB at the drop (through) port. The corresponding IL of 0.84 (0.27) dB and ER of 18.6 (10.11) dB are obtained for the Sb2S3-slot-based device. The change in optical transmittance of the two devices at the resonullt wavelength is more than 80%. No shift of the resonullce wavelength can be achieved upon phase change among the multi-level states. Moreover, the device exhibits a high degree of fabrication tolerance. The proposed device demonstrates ultra-low RWS, high transmittance-tuning range, and low IL, which provides a new scheme for realizing an energy-efficient and large-scale in-memory computing network.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2023, "Volume": 31, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18840, "End Page": 18850, "Article Number": null, "DOI": "10.1364/OE.489525", "DOI Link": "http://dx.doi.org/10.1364/OE.489525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026189800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aslam, F; Farooq, F; Amin, MN; Khan, K; Waheed, A; Akbar, A; Javed, MF; Alyousef, R; Alabdulijabbar, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aslam, Fahid; Farooq, Furqan; Amin, Muhammad Nasir; Khan, Kaffayatullah; Waheed, Abdul; Akbar, Arslan; Javed, Muhammad Faisal; Alyousef, Rayed; Alabdulijabbar, Hisham", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Applications of Gene Expression Programming for Estimating Compressive Strength of High-Strength Concrete", "Source Title": "ADVANCES IN CIVIL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The experimental design of high-strength concrete (HSC) requires deep analysis to get the target strength. In this study, machine learning approaches and artificial intelligence python-based approaches have been utilized to predict the mechanical behaviour of HSC. The data to be used in the modelling consist of several input parameters such as cement, water, fine aggregate, and coarse aggregate in combination with a superplasticizer. Empirical relation with mathematical expression has been proposed using engineering programming. The efficiency of the models is assessed by statistical analysis with the error by using MAE, RRMSE, RSE, and comparisons were made between regression models. Moreover, variable intensity and correlation have shown that deep learning can be used to know the exact amount of materials in civil engineering rather than doing experimental work. The expression tree, as well as normalization of the graph, depicts significant accuracy between target and output values. The results reveal that machine learning proposed adamant accuracy and has elucidated performance in the prediction aspect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 167, "Times Cited, All Databases": 167, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2020, "Volume": 2020, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8850535, "DOI": "10.1155/2020/8850535", "DOI Link": "http://dx.doi.org/10.1155/2020/8850535", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000578174100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Greczynski, G; Hultman, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Greczynski, G.; Hultman, L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of sample storage type on adventitious carbon and native oxide growth: X-ray photoelectron spectroscopy study", "Source Title": "VACUUM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The type and degree of contamination on surfaces intended for X-ray photoelectron spectroscopy (XPS) studies is considered decisive for meaningful and reliable analysis as in many cases in-situ cleaning methods are not applicable or otherwise undesired. We report on the effects of sample storage environment on predominulltly carbon-and oxygen-containing species accumulating on the surfaces of fourteen types of thin film samples spanning group IVB-VIB transition metals (TMs), TM nitrides, and TM diborides. All specimens were deposited by magnetron sputtering and stored for six months in different common sample storage environments such as openly on a shelf in the office or XPS lab, or within a polypropylene wafer carrier, polystyrene box, cellulose/polyester wipers or sealed polyethylene bag. Self-consistent modelling of C 1s, O 1s, B 1s, N 1s, and metal core level spectra allowed to identify the types and quantities of surface contaminullts, metal oxidation states, and thicknesses of native oxides, as well as to address influence from storage ambient type and volume, direct sample contact to other surfaces, or material release from containers. The results reveal significant differences between the various storage types and, hence, provide guidance for all sorts of studies including even those that employ Ar+ ion etch prior to analyses, as also in such cases the amount and type of surface contaminullts may impact the outcome.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 142, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 205, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111463, "DOI": "10.1016/j.vacuum.2022.111463", "DOI Link": "http://dx.doi.org/10.1016/j.vacuum.2022.111463", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863305400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Balasubramanian, K; Pandey, AK; Abolhassani, R; Rubahn, HG; Rahman, S; Mishra, YK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Balasubramanian, Kalidasan; Pandey, Adarsh Kumar; Abolhassani, Reza; Rubahn, Horst-Gunter; Rahman, Saidur; Mishra, Yogendra Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tetrapods based engineering of organic phase change material for thermal energy storage", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase change materials (PCM) are largely assessed on their ability towards energy storage and their enthalpy efficiency of discharging the stored energy. Nevertheless, their applications are limited by the low thermal conductivity behaviour, despite their tunable transition temperature abilities. The present work demonstrates a novel concept to develop and explore PCM composite by embedding two unique zinc oxide tetrapod classes to engineer the heat transfer mechanism for potential utilization in thermal energy storage. Tetrapods embedded phase change material (TPCM) composite displayed up to 94% enhancement in thermal conductivity without compromising melting enthalpy. TPCM composite with high thermal conductivity, high heat capacity, broad photo-absorptivity, improved stability in isothermal conditions, and long thermal cycles offer attractive solutions for effective thermal energy storage, efficient solar energy harnessing, and thermal management. With demon-strated abilities, the developed TPCM composite material could play a significant role in the progress of renewable energy needs in future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 462, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141984, "DOI": "10.1016/j.cej.2023.141984", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2023.141984", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954877300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alkaykh, S; Mbarek, A; Ali-Shattle, EE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alkaykh, Suhila; Mbarek, Aicha; Ali-Shattle, Elbashir E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic degradation of methylene blue dye in aqueous solution by MnTiO3 nulloparticles under sunlight irradiation", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullophotocatalyst MnTiO3 powders were synthesized by sol-gel technique and characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), as well as their thermal behavior has been studied by differential thermal and thermogravimetric analyses (DTA/TGA). Powders morphology was analyzed by means of Transmission electron microscopy (TEM). Effect of various process parameters like amount of photocatalyst, dye concentration, solution pH and irradiation time on the extent of removal of dye were studied in detail. The photo-degradation was relatively higher using lower amount (0.005 g) of semiconductor, reached rate of 75% and 70% after 240 min for mixed MnTiO3/TiO2 and pure MnTiO3 nullocatalysts. The kinetic model of photocatalytic degradation of MB follows pseudo-first-order kinetic with a high correlation coefficient values (R-2 > 0.95). These results underline the use of effective, low-cost and easily available MnTiO3 photocatalyst for the decomposition of pollutants to water under natural sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e03663", "DOI": "10.1016/j.heliyon.2020.e03663", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2020.e03663", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529800500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mittal, A; Naushad, M; Sharma, G; ALothman, ZA; Wabaidur, SM; Alam, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mittal, Alok; Naushad, Mu.; Sharma, Gaurav; ALothman, Z. A.; Wabaidur, S. M.; Alam, Manawwer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fabrication of MWCNTs/ThO2 nullocomposite and its adsorption behavior for the removal of Pb(II) metal from aqueous medium", "Source Title": "DESALINATION AND WATER TREATMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multiwall carbon nullotubes (MWCNTs) were chemically modified to form nullocomposite with thorium oxide. The MWCNTs/ThO2 nullocomposite was characterized using different modern techniques including Fourier transform infrared spectroscopy, X-ray powdered diffraction, scanning electron microscope, and transmission electron microscope. The average size of MWCNTs/ThO2 nullocomposite was in the range from 5 to 10 nm. The nullocomposite material was investigated for its adsorption behavior for Pb(II) ions removal from its aqueous system. For the adsorption of Pb(II) by MWCNTs/ThO2, the equilibrium was achieved within 50 min. The temperature and pH have also found to play important role in the adsorption process and maximum adsorption was found at 45 degrees C and pH 5.5.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 232, "Times Cited, All Databases": 233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 57, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21863, "End Page": 21869, "Article Number": null, "DOI": "10.1080/19443994.2015.1125805", "DOI Link": "http://dx.doi.org/10.1080/19443994.2015.1125805", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000384060500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zagorac, D; Mueller, H; Ruehl, S; Zagorac, J; Rehme, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zagorac, D.; Mueller, H.; Ruehl, S.; Zagorac, J.; Rehme, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent developments in the Inorganic Crystal Structure Database: theoretical crystal structure data and related features", "Source Title": "JOURNAL OF APPLIED CRYSTALLOGRAPHY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Inorganic Crystal Structure Database (ICSD) is the world's largest database of fully evaluated and published crystal structure data, mostly obtained from experimental results. However, the purely experimental approach is no longer the only route to discover new compounds and structures. In the past few decades, numerous computational methods for simulating and predicting structures of inorganic solids have emerged, creating large numbers of theoretical crystal data. In order to take account of these new developments the scope of the ICSD was extended in 2017 to include theoretical structures which are published in peer-reviewed journals. Each theoretical structure has been carefully evaluated, and the resulting CIF has been extended and standardized. Furthermore, a first classification of theoretical data in the ICSD is presented, including additional categories used for comparison of experimental and theoretical information.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 376, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2019, "Volume": 52, "Issue": null, "Part Number": 5, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 918, "End Page": 925, "Article Number": null, "DOI": "10.1107/S160057671900997X", "DOI Link": "http://dx.doi.org/10.1107/S160057671900997X", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Crystallography", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000497756900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Brinksmeier, E; Meyer, D; Huesmann-Cordes, AG; Herrmann, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Brinksmeier, E.; Meyer, D.; Huesmann-Cordes, A. G.; Herrmann, C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metalworking fluids-Mechanisms and performance", "Source Title": "CIRP ANNALS-MANUFACTURING TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In various manufacturing processes, metalworking fluids (MWFs) are applied to ensure workpiece quality, to reduce tool wear, and to improve process productivity. The specific chemical composition of an applied MWF should be strongly dependent on the scope of application. Even small changes of the MWF-composition can influence the performance of MWFs in manufacturing processes considerably. Besides defined variations of the composition, the MWF-chemistry furthermore changes over the service life of the fluid. This paper presents the current state of the art regarding the assumed working mechanisms of MWFs including the effects of desired and undesired changes of the MWF properties. (C) 2015 CIRP.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 301, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 64, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 605, "End Page": 628, "Article Number": null, "DOI": "10.1016/j.cirp.2015.05.003", "DOI Link": "http://dx.doi.org/10.1016/j.cirp.2015.05.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362051000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeybek, Ö; Özkiliç, YO; Karalar, M; Çelik, AI; Qaidi, S; Ahmad, J; Burduhos-Nergis, DD; Burduhos-Nergis, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeybek, Ozer; Ozkilic, Yasin Onuralp; Karalar, Memduh; Celik, Ali Ihsan; Qaidi, Shaker; Ahmad, Jawad; Burduhos-Nergis, Dumitru Doru; Burduhos-Nergis, Diana Petronela", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of Replacing Cement with Waste Glass on Mechanical Properties of Concrete", "Source Title": "MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, the effect of waste glass on the mechanical properties of concrete was examined by conducting a series of compressive strength, splitting tensile strength and flexural strength tests. According to this aim, waste glass powder (WGP) was first used as a partial replacement for cement and six different ratios of WGP were utilized in concrete production: 0%, 10%, 20%, 30%, 40%, and 50%. To examine the combined effect of different ratios of WGP on concrete performance, mixed samples (10%, 20%, 30%) were then prepared by replacing cement, and fine and coarse aggregates with both WGP and crashed glass particles. Workability and slump values of concrete produced with different amounts of waste glass were determined on the fresh state of concrete, and these properties were compared with those of plain concrete. For the hardened concrete, 150 mm x 150 mm x 150 mm cubic specimens and cylindrical specimens with a diameter of 100 mm and a height of 200 mm were tested to identify the compressive strength and splitting tensile strength of the concrete produced with waste glass. Next, a three-point bending test was carried out on samples with dimensions of 100 x 100 x 400 mm, and a span length of 300 mm to obtain the flexure behavior of different mixtures. According to the results obtained, a 20% substitution of WGP as cement can be considered the optimum dose. On the other hand, for concrete produced with combined WGP and crashed glass particles, mechanical properties increased up to a certain limit and then decreased owing to poor workability. Thus, 10% can be considered the optimum replacement level, as combined waste glass shows considerably higher strength and better workability properties. Furthermore, scanning electron microscope (SEM) analysis was performed to investigate the microstructure of the composition. Good adhesion was observed between the waste glass and cementitious concrete. Lastly, practical empirical equations have been developed to determine the compressive strength, splitting tensile strength, and flexure strength of concrete with different amounts of waste glass. Instead of conducting an experiment, these strength values of the concrete produced with glass powder can be easily estimated at the design stage with the help of proposed expressions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 118, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 15, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7513, "DOI": "10.3390/ma15217513", "DOI Link": "http://dx.doi.org/10.3390/ma15217513", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000881258800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eggersmann, R; Kirchdoerfer, T; Reese, S; Stainier, L; Ortiz, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eggersmann, R.; Kirchdoerfer, T.; Reese, S.; Stainier, L.; Ortiz, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Model-Free Data-Driven inelasticity", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We extend the Data-Driven formulation of problems in elasticity of Kirchdoerfer and Ortiz (2016) to inelasticity. This extension differs fundamentally from Data-Driven problems in elasticity in that the material data set evolves in time as a consequence of the history dependence of the material. We investigate three representational paradigms for the evolving material data sets: (i) materials with memory, i. e., conditioning the material data set to the past history of deformation; (ii) differential materials, i. e., conditioning the material data set to short histories of stress and strain; and (iii) history variables, i. e., conditioning the material data set to ad hoc variables encoding partial information about the history of stress and strain. We also consider combinations of the three paradigms thereof and investigate their ability to represent the evolving data sets of different classes of inelastic materials, including viscoelasticity, viscoplasticity and plasticity. We present selected numerical examples that demonstrate the range and scope of Data-Driven inelasticity and the numerical performance of implementations thereof. (C) 2019 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2019, "Volume": 350, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": 99, "Article Number": null, "DOI": "10.1016/j.cma.2019.02.016", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2019.02.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468163500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gresch, D; Autès, G; Yazyev, OV; Troyer, M; Vanderbilt, D; Bernevig, BA; Soluyanov, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gresch, Dominik; Autes, Gabriel; Yazyev, Oleg V.; Troyer, Matthias; Vanderbilt, David; Bernevig, B. Andrei; Soluyanov, Alexey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Z2Pack: Numerical implementation of hybrid Wannier centers for identifying topological materials", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The intense theoretical and experimental interest in topological insulators and semimetals has established band structure topology as a fundamental material property. Consequently, identifying band topologies has become an important, but often challenging, problem, with no exhaustive solution at the present time. In this work we compile a series of techniques, some previously known, that allow for a solution to this problem for a large set of the possible band topologies. The method is based on tracking hybrid Wannier charge centers computed for relevant Bloch states, and it works at all levels of materials modeling: continuous k . p models, tight-binding models, and ab initio calculations. We apply the method to compute and identify Chern, Z(2), and crystalline topological insulators, as well as topological semimetal phases, using real material examples. Moreover, we provide a numerical implementation of this technique (the Z2Pack software package) that is ideally suited for high-throughput screening of materials databases for compounds with nontrivial topologies. We expect that our work will allow researchers to (a) identify topological materials optimal for experimental probes, (b) classify existing compounds, and (c) reveal materials that host novel, not yet described, topological states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 306, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 23", "Publication Year": 2017, "Volume": 95, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75146, "DOI": "10.1103/PhysRevB.95.075146", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.075146", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394659700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, N; Pratibha; Prasad, J; Yadav, A; Upadhyay, A; Neeraj; Shukla, S; Petkoska, AT; Heena; Suri, S; Gniewosz, M; Kieliszek, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Nishant; Pratibha, Jaishankar; Prasad, Jaishankar; Yadav, Ajay; Upadhyay, Ashutosh; Neeraj, Anka Trajkovska; Shukla, Shruti; Petkoska, Anka Trajkovska; Heena, Marek; Suri, Shweta; Gniewosz, Malgorzata; Kieliszek, Marek", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recent Trends in Edible Packaging for Food Applications - Perspective for the Future", "Source Title": "FOOD ENGINEERING REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Edible packaging plays an important role in protecting food products from physical, mechanical, chemical, and microbiological damages by creating a barrier against oxidation, water, and controlling enzymatic activation. The employment of active agents such as plant extracts, essential oils, cross-linkers, and nullomaterials in edible packaging promises to improve mechanical, physical, barrier, and other properties of edible materials as well as food products. In the current review, we have compiled information on the recent advances and trends in developing composite (binary and ternary) edible packaging for food application. Several types of active agents such as essential oils, plant extracts, cross-linking agents, and nullomaterials as well as their functions in edible packaging (active composite) have been discussed. The present study provides the collective information about the high- (high-pressure homogenizer, ultrasonication, and microfludizer) and low-energy (phase inversion temperature and composition and spontaneous emulsification) methods for developing nulloformulations. In addition, concepts of comprehensive studies required for developing edible coatings and films for food packaging applications, as well as overcoming challenges like consumer acceptance, regulatory requirements, and non-toxic scaling up to the commercial applications, have also been discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 718, "End Page": 747, "Article Number": null, "DOI": "10.1007/s12393-023-09358-y", "DOI Link": "http://dx.doi.org/10.1007/s12393-023-09358-y", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001087957200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Caprioglio, P; Wolff, CM; Sandberg, OJ; Armin, A; Rech, B; Albrecht, S; Neher, D; Stolterfoht, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Caprioglio, Pietro; Wolff, Christian M.; Sandberg, Oskar J.; Armin, Ardalan; Rech, Bernd; Albrecht, Steve; Neher, Dieter; Stolterfoht, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the Origin of the Ideality Factor in Perovskite Solar Cells", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The measurement of the ideality factor (n(id)) is a popular tool to infer the dominullt recombination type in perovskite solar cells (PSC). However, the true meaning of its values is often misinterpreted in complex multilayered devices such as PSC. In this work, the effects of bulk and interface recombination on the n(id) are investigated experimentally and theoretically. By coupling intensity-dependent quasi-Fermi level splitting measurements with drift diffusion simulations of complete devices and partial cell stacks, it is shown that interfacial recombination leads to a lower n(id) compared to Shockley-Read-Hall (SRH) recombination in the bulk. As such, the strongest recombination channel determines the n(id) of the complete cell. An analytical approach is used to rationalize that n(id) values between 1 and 2 can originate exclusively from a single recombination process. By expanding the study over a wide range of the interfacial energy offsets and interfacial recombination velocities, it is shown that an ideality factor of nearly 1 is usually indicative of strong first-order non-radiative interface recombination and that it correlates with a lower device performance. It is only when interface recombination is largely suppressed and bulk SRH recombination dominates that a small n(id) is again desirable.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 238, "Times Cited, All Databases": 243, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 10, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2000502, "DOI": "10.1002/aenm.202000502", "DOI Link": "http://dx.doi.org/10.1002/aenm.202000502", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000538473600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Federici, G; Biel, W; Gilbert, MR; Kemp, R; Taylor, N; Wenninger, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Federici, G.; Biel, W.; Gilbert, M. R.; Kemp, R.; Taylor, N.; Wenninger, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "European DEMO design strategy and consequences for materials", "Source Title": "NUCLEAR FUSION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Demonstrating the production of net electricity and operating with a closed fuel-cycle remain unarguably the crucial steps towards the exploitation of fusion power. These are the aims of a demonstration fusion reactor (DEMO) proposed to be built after ITER. This paper briefly describes the DEMO design options that are being considered in Europe for the current conceptual design studies as part of the Roadmap to Fusion Electricity Horizon 2020. These are not intended to represent fixed and exclusive design choices but rather 'proxies' of possible plant design options to be used to identify generic design/material issues that need to be resolved in future fusion reactor systems. The materials nuclear design requirements and the effects of radiation damage are briefly analysed with emphasis on a pulsed 'low extrapolation' system, which is being used for the initial design integration studies, based as far as possible on mature technologies and reliable regimes of operation (to be extrapolated from the ITER experience), and on the use of materials suitable for the expected level of neutron fluence. The main technical issues arising from the plasma and nuclear loads and the effects of radiation damage particularly on the structural and heat sink materials of the vessel and in-vessel components are critically discussed. The need to establish realistic target performance and a development schedule for near-term electricity production tends to favour more conservative technology choices. The readiness of the technical (physics and technology) assumptions that are being made is expected to be an important factor for the selection of the technical features of the device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 244, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 57, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 92002, "DOI": "10.1088/1741-4326/57/9/092002", "DOI Link": "http://dx.doi.org/10.1088/1741-4326/57/9/092002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407854600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kitatani, M; Si, L; Janson, O; Arita, R; Zhong, ZC; Held, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kitatani, Motoharu; Si, Liang; Janson, Oleg; Arita, Ryotaro; Zhong, Zhicheng; Held, Karsten", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickelate superconductors-a renaissance of the one-band Hubbard model", "Source Title": "NPJ QUANTUM MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recently discovered nickelate superconductors appear, at first glance, to be even more complicated multi-orbital systems than cuprates. To identify the simplest model describing the nickelates, we analyse the multi-orbital system and find that it is instead the nickelates which can be described by a one-band Hubbard model, albeit with an additional electron reservoir and only around the superconducting regime. Our calculations of the critical temperatureT(C)are in good agreement with experiment, and show that optimal doping is slightly below 20% Sr-doping. Even more promising than 3dnickelates are 4dpalladates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 162, "Times Cited, All Databases": 170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2020, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 59, "DOI": "10.1038/s41535-020-00260-y", "DOI Link": "http://dx.doi.org/10.1038/s41535-020-00260-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564998000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HB; Zhou, J; Rao, AM; Lu, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Hongbo; Zhou, Jiang; Rao, Apparao M.; Lu, Bingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cell-like-carbon-micro-spheres for robust potassium anode", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale low-cost synthesis methods for potassium ion battery (PIB) anodes with long cycle life and high capacity have remained challenging. Here, inspired by the structure of a biological cell, biomimetic carbon cells (BCCs) were synthesized and used as PIB anodes. The protruding carbon nullotubes across the BCC wall mimicked the ion-transporting channels present in the cell membrane, and enhanced the rate performance of PIBs. In addition, the robust carbon shell of the BCC could protect its overall structure, and the open space inside the BCC could accommodate the volume changes caused by K+ insertion, which greatly improved the stability of PIBs. For the first time, a stable solid electrolyte interphase layer is formed on the surface of amorphous carbon. Collectively, the unique structural characteristics of the BCCs resulted in PIBs that showed a high reversible capacity (302 mAhg(-1) at 100 mAg(-1) and 248mAhg(-1) at 500 mAg(-1)), excellent cycle stability (reversible capacity of 226 mAhg(-1) after 2100 cycles and a continuous running time of more than 15 months at a current density of 100 mAg(-1)), and an excellent rate performance (160mAhg(-1) at 1Ag(-1)). This study represents a new strategy for boosting battery performance, and could pave the way for the next generation of battery-powered applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 8, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwaa276", "DOI": "10.1093/nsr/nwaa276", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000701659300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sears, JA; Zhao, Y; Xu, Z; Lynn, JW; Kim, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sears, J. A.; Zhao, Y.; Xu, Z.; Lynn, J. W.; Kim, Young-June", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase diagram of α-RuCl3 in an in-plane magnetic field", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low-temperature magnetic phases in the layered honeycomb lattice material alpha-RuCl3 have been studied as a function of in-plane magnetic field. In zero field this material orders magnetically below 7 K with a so-called zigzag order within the honeycomb planes. Neutron diffraction data show that a relatively small applied field of 2 T is sufficient to suppress the population of the magnetic domain in which the zigzag chains run along the field direction. We found that the intensity of the magnetic peaks due to zigzag order is continuously suppressed with increasing field until their disappearance at mu H-o(c) = 8 T. At still higher fields (above 8 T) the zigzag order is destroyed, while bulk magnetization and heat capacity measurements suggest that the material enters a state with gapped magnetic excitations. We discuss the magnetic phase diagram obtained in our study in the context of a quantum phase transition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 31", "Publication Year": 2017, "Volume": 95, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 180411, "DOI": "10.1103/PhysRevB.95.180411", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.95.180411", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411500800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Carrete, J; Vermeersch, B; Katre, A; van Roekeghem, A; Wang, T; Madsen, GKH; Mingo, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Carrete, Jesus; Vermeersch, Bjorn; Katre, Ankita; van Roekeghem, Ambroise; Wang, Tao; Madsen, Georg K. H.; Mingo, Natalio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "almaBTE: A solver of the space-time dependent Boltzmann transport equation for phonons in structured materials", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "almaBTE is a software package that solves the space- and time-dependent Boltzmann transport equation for phonons, using only ab-initio calculated quantities as inputs. The program can predictively tackle phonon transport in bulk crystals and alloys, thin films, superlattices, and multiscale structures with size features in the nm-mu m range. Among many other quantities, the program can output thermal conductances and effective thermal conductivities, space-resolved average temperature profiles, and heat-current distributions resolved in frequency and space. Its first-principles character makes almaBTE especially well suited to investigate novel materials and structures. This article gives an overview of the program structure and presents illustrative examples for some of its uses. PROGRAM SUMMARY Program Title: almaBTE Program Files doi: http://dx.doLorg/10.17632/8tfzwgtp73.1 Licensing provisions: Apache License, version 2.0 Programming language: C++ External routines/libraries: BOOST, MPI, Eigen, HDF5, spglib Nature of problem: Calculation of temperature profiles, thermal flux distributions and effective thermal conductivities in structured systems where heat is carried by phonons Solution method: Solution of linearized phonon Boltzmann transport equation, Variance-reduced Monte Carlo (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 245, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2017, "Volume": 220, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 351, "End Page": 362, "Article Number": null, "DOI": "10.1016/j.cpc.2017.06.023", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2017.06.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412252300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yousefi, SR; Amiri, O; Salavati-Niasari, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yousefi, Seyede Rahele; Amiri, Omid; Salavati-Niasari, Masoud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control sonochemical parameter to prepare pure Zn0.35Fe2.65O4 nullostructures and study their photocatalytic activity", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn0.35Fe2.65O4 nullostructure was prepared as a ferrite material by using a simple sonochemistry method. The effect of different parameters such as sonication time and power were studied. By increasing sonication power and time more Fe+3 ions reduced to Fe+2. This happens because H and OH radicals produced under sonication could act as a reduction agent. Therefore by increasing power and sonication time more Fe+3 ions reduced. Pure Zn0.35Fe2.65O4 nullostructure was formed when sonication time and power were 30 min and 40 W. Surface area for pure Zn0.35Fe2.65O4 nullostructure was 64 m(2).g(-1). Afterward, Zn0.35Fe2.65O4 nullostructures were applied to treat water containing different pollutants. As-prepared nullostructures degrade 60.8, 77.9, 55.2 and 44.0% of Acid Violet 7, Acid Blue 92, Acid Red 14, and Methyl Orange under visible light during 180 min irradiation. In addition, 94.5, 84.2, and 43.0% of AV7, Phil, and Ery were degraded under UV light during 120 min irradiation. The as-synthesized Zn0.35Fe2.65O4 nullostructure was characterized through the SEM, EDX, TEM, CV, DRS, BET, VSM, and XRD.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 58, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104619, "DOI": "10.1016/j.ultsonch.2019.104619", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2019.104619", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489355000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hassan, SE; Fouda, A; Saied, E; Farag, MMS; Eid, AM; Barghoth, MG; Awad, MA; Hamza, MF; Awad, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hassan, Saad El-Din; Fouda, Amr; Saied, Ebrahim; Farag, Mohamed M. S.; Eid, Ahmed M.; Barghoth, Mohammed G.; Awad, Mohamed A.; Hamza, Mohammed F.; Awad, Mohamed F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rhizopus oryzae-Mediated Green Synthesis of Magnesium Oxide nulloparticles (MgO-NPs): A Promising Tool for Antimicrobial, Mosquitocidal Action, and Tanning Effluent Treatment", "Source Title": "JOURNAL OF FUNGI", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The metabolites of the fungal strain Rhizopus oryaze were used as a biocatalyst for the green-synthesis of magnesium oxide nulloparticles (MgO-NPs). The production methodology was optimized to attain the maximum productivity as follows: 4 mM of precursor, at pH 8, incubation temperature of 35 degrees C, and reaction time of 36 h between metabolites and precursor. The as-formed MgO-NPs were characterized by UV-Vis spectroscopy, TEM, SEM-EDX, XRD, DLS, FT-IR, and XPS analyses. These analytical techniques proved to gain crystalline, homogenous, and well-dispersed spherical MgO-NPs with an average size of 20.38 +/- 9.9 nm. The potentiality of MgO-NPs was dose- and time-dependent. The biogenic MgO-NPs was found to be a promising antimicrobial agent against the pathogens including Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa, Escherichia coli, and Candida albicans with inhibition zones of 10.6 +/- 0.4, 11.5 +/- 0.5, 13.7 +/- 0.5, 14.3 +/- 0.7, and 14.7 +/- 0.6 mm, respectively, at 200 mu g mL(-1). Moreover, MgO-NPs manifested larvicidal and adult repellence activity against Culex pipiens at very low concentrations. The highest decolorization percentages of tanning effluents were 95.6 +/- 1.6% at 100 mu g/ 100 mL after 180 min. At this condition, the physicochemical parameters of tannery effluents, including TSS, TDS, BOD, COD, and conductivity were reduced with percentages of 97.9%, 98.2%, 87.8%, 95.9%, and 97.3%, respectively. Moreover, the chromium ion was adsorbed with percentages of 98.2% at optimum experimental conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 7, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 372, "DOI": "10.3390/jof7050372", "DOI Link": "http://dx.doi.org/10.3390/jof7050372", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Microbiology; Mycology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000654325900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Loo, YY; Rukayadi, Y; Nor-Khaizura, MAR; Kuan, CH; Chieng, BW; Nishibuchi, M; Radu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Loo, Yuet Ying; Rukayadi, Yaya; Nor-Khaizura, Mahmud-Ab-Rashid; Kuan, Chee Hao; Chieng, Buong Woei; Nishibuchi, Mitsuaki; Radu, Son", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In Vitro Antimicrobial Activity of Green Synthesized Silver nulloparticles Against Selected Gram-negative Foodborne Pathogens", "Source Title": "FRONTIERS IN MICROBIOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Silver nulloparticles (AgNPs) used in this study were synthesized using pu-erh tea leaves extract with particle size of 4.06 nm. The antibacterial activity of green synthesized AgNPs against a diverse range of Gram-negative foodborne pathogens was determined using disk diffusion method, resazurin microtitre-plate assay (minimum inhibitory concentration, MIC), and minimum bactericidal concentration test (MBC). The MIC and MBC of AgNPs against Escherichia coli, Klebsiella pneumoniae, Salmonella Typhimurium, and Salmonella Enteritidis were 7.8, 3.9, 3.9, 3.9 and 7.8, 3.9, 7.8, 3.9 mu g/mL, respectively. Time-kill curves were used to evaluate the concentration between MIC and bactericidal activity of AgNPs at concentrations ranging from 0 x MIC to 8 x MIC. The killing activity of AgNPs was fast acting against all the Gram-negative bacteria tested; the reduction in the number of CFU mL(-1) was > 3 Log(10) units (99.9%) in 1-2 h. This study indicates that AgNPs exhibit a strong antimicrobial activity and thus might be developed as a new type of antimicrobial agents for the treatment of bacterial infection including multidrug resistant bacterial infection.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 413, "Times Cited, All Databases": 433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 16", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1555, "DOI": "10.3389/fmicb.2018.01555", "DOI Link": "http://dx.doi.org/10.3389/fmicb.2018.01555", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438706600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chaht, FL; Kaci, A; Houari, MSA; Tounsi, A; Bég, OA; Mahmoud, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chaht, Fouzia Larbi; Kaci, Abdelhakim; Houari, Mohammed Sid Ahmed; Tounsi, Abdelouahed; Beg, O. Anwar; Mahmoud, S. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bending and buckling analyses of functionally graded material (FGM) size-dependent nulloscale beams including the thickness stretching effect", "Source Title": "STEEL AND COMPOSITE STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper addresses theoretically the bending and buckling behaviors of size-dependent nullobeams made of functionally graded materials (FGMs) including the thickness stretching effect. The size-dependent FGM nullobeam is investigated on the basis of the nonlocal continuum model. The nonlocal elastic behavior is described by the differential constitutive model of Eringen, which enables the present model to become effective in the analysis and design of nullostructures. The present model incorporates the length scale parameter (nonlocal parameter) which can capture the small scale effect, and furthermore accounts for both shear deformation and thickness stretching effects by virtue of a sinusoidal variation of all displacements through the thickness without using shear correction factor. The material properties of FGM nullobeams are assumed to vary through the thickness according to a power law. The governing equations and the related boundary conditions are derived using the principal of minimum total potential energy. A Navier-type solution is developed for simply-supported boundary conditions, and exact expressions are proposed for the deflections and the buckling load. The effects of nonlocal parameter, aspect ratio and various material compositions on the static and stability responses of the FGM nullobeam are discussed in detail. The study is relevant to nullotechnology deployment in for example aircraft structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 365, "Times Cited, All Databases": 365, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 18, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 425, "End Page": 442, "Article Number": null, "DOI": "10.12989/scs.2015.18.2.425", "DOI Link": "http://dx.doi.org/10.12989/scs.2015.18.2.425", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352361900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JH; Abazari, R; Sanati, S; Ejsmont, A; Goscianska, J; Zhou, YT; Dubal, DP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jinhu; Abazari, Reza; Sanati, Soheila; Ejsmont, Aleksander; Goscianska, Joanna; Zhou, Yingtang; Dubal, Deepak P. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water-Stable Fluorous Metal-Organic Frameworks with Open Metal Sites and Amine Groups for Efficient Urea Electrocatalytic Oxidation", "Source Title": "SMALL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Urea oxidation reaction (UOR) is one of the promising alternative anodic reactions to water oxidation that has attracted extensive attention in green hydrogen production. The application of specifically designed electrocatalysts capable of declining energy consumption and environmental consequences is one of the major challenges in this field. Therefore, the goal is to achieve a resistant, low-cost, and environmentally friendly electrocatalyst. Herein, a water-stable fluorinated Cu(II) metalorganic framework (MOF) {[Cu-2(L)(H2O)(2)]& BULL;(5DMF)(4H(2)O)}(n) (Cu-FMOF-NH2; H4L = 3,5-bis(2,4-dicarboxylic acid)-4-(trifluoromethyl)aniline) is developed utilizing an angular tetracarboxylic acid ligand that incorporates both trifluoromethyl (-CF3) and amine (-NH2) groups. The tailored structure of Cu-FMOF-NH2 where linkers are connected by fluoride bridges and surrounded by dicopper nodes reveals a 4,24T1 topology. When employed as electrocatalyst, Cu-FMOF-NH2 requires only 1.31 V versus reversible hydrogen electrode (RHE) to deliver 10 mA cm(-2) current density in 1.0 m KOH with 0.33 m urea electrolyte and delivered an even higher current density (50 mA cm(-2)) at 1.47 V versus RHE. This performance is superior to several reported catalysts including commercial RuO2 catalyst with overpotential of 1.52 V versus RHE. This investigation opens new opportunities to develop and utilize pristine MOFs as a potential electrocatalyst for various catalytic reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 69, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 19, "Issue": 43, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/smll.202300673", "DOI Link": "http://dx.doi.org/10.1002/smll.202300673", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001017572100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Das, O; Babu, K; Shanmugam, V; Sykam, K; Tebyetekerwa, M; Neisiany, RE; Försth, M; Sas, G; Gonzalez-Libreros, J; Capezza, AJ; Hedenqvist, MS; Berto, F; Ramakrishna, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Das, Oisik; Babu, Karthik; Shanmugam, Vigneshwaran; Sykam, Kesavarao; Tebyetekerwa, Mike; Neisiany, Rasoul Esmaeely; Forsth, Michael; Sas, Gabriel; Gonzalez-Libreros, Jaime; Capezza, Antonio J.; Hedenqvist, Mikael S.; Berto, Filippo; Ramakrishna, Seeram", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Natural and industrial wastes for sustainable and renewable polymer composites", "Source Title": "RENEWABLE & SUSTAINABLE ENERGY REVIEWS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By-products management from industrial and natural (agriculture, aviculture, and others) activities and products are critical for promoting sustainability, reducing pollution, increasing storage space, minimising landfills, reducing energy consumption, and facilitating a circular economy. One of the sustainable waste management approaches is utilising them in developing biocomposites. Biocomposites are eco-friendly materials because of their sustainability and environmental benefits that have comparable performance properties to the synthetic counterparts. Biocomposites can be developed from both renewable and industrial waste, making them both energy efficient and sustainable. Because of their low weight and high strength, biocomposite materials in applications such as automobiles can minimise fuel consumption and conserve energy. Furthermore, biocomposites in energy-based applications could lead to savings in both the economy and energy consumption. Herein, a review of biocomposites made from various wastes and their related key properties (e.g. mechanical and fire) are provided. The article systematically highlights the individual wastes/by-products from agriculture and materials processing industries for composites manufacturing in terms of their waste components (materials), modifications, resultant properties, applications and energy efficiency. Finally, a perspective for the future of biowastes and industrial wastes in polymer composites is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 158, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112054, "DOI": "10.1016/j.rser.2021.112054", "DOI Link": "http://dx.doi.org/10.1016/j.rser.2021.112054", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786656800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "El-Bery, HM; Saleh, M; El-Gendy, RA; Saleh, MR; Thabet, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "El-Bery, Haitham M.; Saleh, Moushira; El-Gendy, Reem A.; Saleh, Mahmoud R.; Thabet, Safinaz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High adsorption capacity of phenol and methylene blue using activated carbon derived from lignocellulosic agriculture wastes", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The resources of clean water worldwide are very limited, and climate change is already affecting the available supplies. Therefore, developing a low-cost, highly efficient, and recyclable adsorbent to upgrade water quality has become an essential task. Herein, we report the fabrication of activated carbon (AC) adsorbents derived from lignocellulosic wastes. Both physical and chemical activation were investigated to modify the surface texture properties. The results indicated that increasing the activation temperature, whether physically or chemically, increases the specific surface area (S-BET). On the contrary, increasing the amount of the chemical activating agent significantly decreases the S-BET values. The S-BET of 1771, 2120, and 2490 m(2) g(-1) were obtained for water vapor, K2CO3 and KOH, at activation temperatures of 950 degrees C, 800 degrees C, and 800 degrees C, respectively. Methylene blue (MB) and phenol were used as adsorbates for the adsorption experiment. Adsorption of methylene blue dye revealed the ability of the water activated carbon to remove more than 95% of the dye (100 ppm) within 5 min with an adsorption capacity of 148.8 mg g(-1). For phenol adsorption, Several parameters were investigated, including initial concentration (50-250 ppm), pH (2-10), contact time (5-60 min), and temperature (25-45 degrees C). The highest adsorption capacity of phenol achieved was 158.9 mg g(-1). The kinetics of adsorption of phenol was better described by pseudo-second-order reaction while the isotherm process using Langmuir model. This study presents a roadmap for conversion of lignocellulosic biomass waste into highly efficient porous carbon adsorbents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5499, "DOI": "10.1038/s41598-022-09475-4", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-09475-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000776953600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hager, I; Sitarz, M; Mróz, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hager, Izabela; Sitarz, Mateusz; Mroz, Katarzyna", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fly-ash based geopolymer mortar for high-temperature application - Effect of slag addition", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Geopolymers are used as a Portland cement alternative in some applications. The motivation for using geopolymers is their capacity of the by-products and waste incorporation, contributing to a cleaner environment. The present study aims to evaluate the impact of temperature exposure (up to 1000 degrees C) on the microstructure and the mechanical properties of the geopolymer mortars. Four mixes were investigated with fly ash as the main precursor with four levels of slag replacement 0, 10, 30, and 50 wt%. To evaluate damage evolution, mechanical performances and identification tests were performed: ultrasonic pulse velocity, scanning electron microscope, mercury intrusion porosimetry, thermal strains measurements, differential thermal analysis and thermogravimetry. The research aimed to develop a mortar composition that is thermally stable at high temperature. Although slag addition improves the mechanical performances of fly ash geopolymer mortar considerably (compressive strength above 100 MPa), the mortar with no slag addition yielded better performances at high temperature. In this study, manufactured mortars exhibited a 30% strength increase and doubled tensile strength at 200 degrees C. Moreover, for developed mixes, a compressive strength recovery of up to 90% at 1000 degrees C was observed, demonstrating the potential of fly ash geopolymer as high-temperature application material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 154, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2021, "Volume": 316, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 128168, "DOI": "10.1016/j.jclepro.2021.128168", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2021.128168", "Book DOI": null, "Early Access Date": "JUL 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000723083800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Munkhbat, B; Wersäll, M; Baranov, DG; Antosiewicz, TJ; Shegai, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Munkhbat, Battulga; Wersall, Martin; Baranov, Denis G.; Antosiewicz, Tomasz J.; Shegai, Timur", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppression of photo-oxidation of organic chromophores by strong coupling to plasmonic nulloantennas", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intermixed light-matter quasi-particles polaritons have unique optical properties owing to their compositional nature. These intriguing hybrid states have been extensively studied over the past decades in a wide range of realizations aiming at both basic science and emerging applications. However, recently, it has been demonstrated that not only optical but also material-related properties, such as chemical reactivity and charge transport, may be significantly altered in the strong coupling regime of light-matter interactions. We show that a nulloscale system, composed of a plasmonic nulloprism strongly coupled to excitons in a J-aggregated form of organic chromophores, experiences modified excited-state dynamics and, therefore, modified photochemical reactivity. Our experimental results reveal that photobleaching, one of the most fundamental photochemical reactions, can be effectively controlled and suppressed by the degree of plasmon-exciton coupling and detuning. In particular, we observe a 100-fold stabilization of organic dyes for the red-detuned nulloparticles. Our findings contribute to understanding of photochemical properties in the strong coupling regime and may find important implications for the performance and improved stability of optical devices incorporating organic dyes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 229, "Times Cited, All Databases": 242, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaas9552", "DOI": "10.1126/sciadv.aas9552", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aas9552", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akram, N; Montazer, E; Kazi, SN; Soudagar, MEM; Ahmed, W; Zubir, MNM; Afzal, A; Muhammad, MR; Ali, HM; Márquez, FPG; Sarsam, WS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akram, Naveed; Montazer, Elham; Kazi, S. N.; Soudagar, Manzoore Elahi M.; Ahmed, Waqar; Zubir, Mohd Nashrul Mohd; Afzal, Asif; Muhammad, Mohd Ridha; Ali, Hafiz Muhammad; Marquez, Fausto Pedro Garcia; Sarsam, Wail Sami", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental investigations of the performance of a flat-plate solar collector using carbon and metal oxides based nullofluids", "Source Title": "ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalently functionalized carbon nulloplatelets and non-covalent functionalized metal oxides nulloparticles (surfactant-treated) have been used to synthesize water-based nullofluids in this paper. To prove nullofluid stability, ultraviolete-visible (UV-vis) spectroscopy is used, and the results show that nullofluid is stable for sixty days for carbon and thirty days for metal oxides. The thermophysical properties are evaluated experimentally and validated with theoretical models. Thermal conductivities of f-GNPs, SiO2, and ZnO nullofluids are enhanced by 25.68%, 11.49%, and 15.42%, respectively. Lu-Li and Bruggeman's thermal conductivity models are correctly matched with the experimental data. Similarly, the viscosity, density, and specific heat capacity of nullofluids are measured and compared with theoretical models. The enhancement in density, specific heat and viscosity of f-GNPs, ZnO, and SiO2 nullofluids are 0.12%, 0.22%, and 0.12%; 1.54%, 0.96%, and 0.73%; 12%, 9.41%, and 24.05% respectively in comparison of distilled water. A flat-plate solar collector is installed, and its thermal performance is evaluated by using carbon and metal oxides based nullofluids, following the ASHRAE standard 93-2003, at different heat flux intensities (597, 775, and 988 W/m(2)), mass flow rates (0.8, 1.2 and 1.6 kg/min), inlet fluid temperatures (30-50 degrees C) and the weight concentrations (0.025-0.2%). The thermal efficiency of the flat-plate solar collector is measured for distilled water and compared with the weight concentration (0.025-0.2%) of functionalized carbon and metal oxide-based nullofluids. A comparison of 0.1 wt% water-based nullofluids can be sequenced f-GNPs > ZnO > SiO2 because of a percentage improvement of thermal efficiency of the flat-plate solar collector obtained at a mass flow rate of 1.6 kg/min with values of 17.45% > 13.05% > 12.36%, respectively in comparison to water. (C) 2021 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2021, "Volume": 227, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 120452, "DOI": "10.1016/j.energy.2021.120452", "DOI Link": "http://dx.doi.org/10.1016/j.energy.2021.120452", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000652610900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, JQ; Zhan, CH; Wu, JH; Cui, ZX; Si, JH; Wang, QT; Peng, XF; Turng, LS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Jiaqi; Zhan, Conghua; Wu, Jiahui; Cui, Zhixiang; Si, Junhui; Wang, Qianting; Peng, Xiangfang; Turng, Lih-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Efficient Removal of Methylene Blue Dye from an Aqueous Solution Using Cellulose Acetate nullofibrous Membranes Modified by Polydopamine", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new type of deacetylated cellulose acetate (DA)@polydopamme (PDA) composite nullofiber membrane was fabricated by electrospinning and surface modification. The membrane was applied as a highly efficient adsorbent for removing methylene blue (MB) from an aqueous solution. The morphology, surface chemistry, surface wettability, and effects of operating conditions on MB adsorption ability, as well as the equilibrium, kinetics, thermodynamics, and mechanism of adsorption, were systematically studied. The results demonstrated that a uniform PDA coating layer was successfully developed on the surface of DA nullofibers. The adsorption capacity of the DA@PDA nullofiber membrane reached up to 88.2 mg/g at a temperature of 25 degrees C and a pH of 6.5 after adsorption for 30 h, which is about 8.6 times higher than that of DA nullofibers. The experimental results showed that the adsorption behavior of DA@PDA composite nullofibers followed the Weber's intraparticle diffusion model, pseudo-second-order model, and Langmuir isothermal model. A thermodynamic analysis indicated that endothermic, spontaneous, and physisorption processes occurred. Based on the experimental results, the adsorption mechanism of DA@PDA composite nullofibers was also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 214, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2020, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5389, "End Page": 5400, "Article Number": null, "DOI": "10.1021/acsomega.9b04425", "DOI Link": "http://dx.doi.org/10.1021/acsomega.9b04425", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520853400075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ouachtak, H; El Guerdaoui, A; El Haouti, R; Haounati, R; Ighnih, H; Toubi, Y; Alakhras, F; Rehman, R; Hafid, N; Addi, AA; Taha, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ouachtak, Hassan; El Guerdaoui, Anouar; El Haouti, Rachid; Haounati, Redouane; Ighnih, Hamza; Toubi, Yahya; Alakhras, Fadi; Rehman, Rabia; Hafid, Naima; Addi, Abdelaziz Ait; Taha, Mohamed Labd", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Combined molecular dynamics simulations and experimental studies of the removal of cationic dyes on the eco-friendly adsorbent of activated carbon decorated montmorillonite Mt@AC", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the combination of experimental and theoretical study to explain adsorbate/adsorbent interactions has attracted the attention of researchers. In this context, this work aims to study the adsorption of two cationic dyes, namely methylene blue (MB) and crystal violet (CV), on a green adsorbent Montmorillonite@activated carbon (Mt@AC) composite and to explain the adsorption behavior of each dye by the molecular dynamics (MD) simulation method. The eco-friendly nullocomposite Mt@AC is synthesized and characterized by the analysis methods: XRD, FTIR, BET, TGA/DTA, SEM-EDS, EDS-mapping and zeta potential. The experimental results of adsorption equilibrium show that the adsorption of the two dyes is well suited to the Langmuir adsorption model. The maximum adsorption capacity of the two dyes reaches 801.7 mg g(-1) for methylene blue and 1110.8 mg g(-1) for crystal violet. The experimental kinetics data fit well with a pseudo-first order kinetic model for the two dyes with coefficient of determination R-2 close to unity, non-linear chi-square chi(2) close to zero and lower Root Mean Square Error RMSE (R-2 -> 1 and chi(2) -> 0, RMSE lower). Molecular dynamic simulations are run to gain insights on the adsorption process. According to the RDF analysis and interaction energy calculations, the obtained results reveal a better affinity of the CV molecule with both the AC sheet and montmorillonite framework as compared with MB. This finding suggests that CV is adsorbed to a larger extent onto the nullocomposite material which is in good agreement with the adsorption isothermal experiment observations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 13, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5027, "End Page": 5044, "Article Number": null, "DOI": "10.1039/d2ra08059a", "DOI Link": "http://dx.doi.org/10.1039/d2ra08059a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928647500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sangtawesin, S; Dwyer, BL; Srinivasan, S; Allred, JJ; Rodgers, LVH; De Greve, K; Stacey, A; Dontschuk, N; O'Donnell, KM; Hu, D; Evans, DA; Jaye, C; Fischer, DA; Markham, ML; Twitchen, DJ; Park, H; Lukin, MD; de Leon, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sangtawesin, Sorawis; Dwyer, Bo L.; Srinivasan, Srikanth; Allred, James J.; Rodgers, Lila V. H.; De Greve, Kristiaan; Stacey, Alastair; Dontschuk, Nikolai; O'Donnell, Kane M.; Hu, Di; Evans, D. Andrew; Jaye, Cherno; Fischer, Daniel A.; Markham, Matthew L.; Twitchen, Daniel J.; Park, Hongkun; Lukin, Mikhail D.; de Leon, Nathalie P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origins of Diamond Surface Noise Probed by Correlating Single-Spin Measurements with Surface Spectroscopy", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The nitrogen-vacancy (NV) center in diamond exhibits spin-dependent fluorescence and long spin coherence times under ambient conditions, enabling applications in quantum information processing and sensing. NV centers near the surface can have strong interactions with external materials and spins, enabling new forms of nulloscale spectroscopy. However, NV spin coherence degrades within 100 nm of the surface, suggesting that diamond surfaces are plagued with ubiquitous defects. Prior work on characterizing near-surface noise has primarily relied on using NV centers themselves as probes; while this has the advantage of exquisite sensitivity, it provides only indirect information about the origin of the noise. Here we demonstrate that surface spectroscopy methods and single-spin measurements can be used as complementary diagnostics to understand sources of noise. We find that surface morphology is crucial for realizing reproducible chemical termination, and use this insight to achieve a highly ordered, oxygen-terminated surface with suppressed noise. We observe NV centers within 10 nm of the surface with coherence times extended by an order of magnitude.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 26", "Publication Year": 2019, "Volume": 9, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31052, "DOI": "10.1103/PhysRevX.9.031052", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.9.031052", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000488268100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shaku, B; Mofokeng, TP; Coville, NJ; Ozoemena, KI; Maubane-Nkadimeng, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shaku, B.; Mofokeng, T. P.; Coville, N. J.; Ozoemena, K. I.; Maubane-Nkadimeng, M. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomass valorisation of marula nutshell waste into nitrogen-doped activated carbon for use in high performance supercapacitors", "Source Title": "ELECTROCHIMICA ACTA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study reports on the valorisation of marula nutshell waste into a valuable electrode material for super -capacitors. Marula nutshell waste, a brown hard residue from marula fruits was valorised into a nitrogen-doped activated carbon (N-ACs) by KOH treatment and using melamine as a nitrogen source. The microporous and mesoporous nature of N-ACs exhibited a high surface area of 1427 m2 g-1 and pore volume of 0.31 cm3 g-1. Three electrode measurements were done in 6 M KOH and 2.5 M KNO3 aqueous electrolytes, to examine the materials in alkaline and neutral medium. The N-ACs exhibited a capacitance of 350 F g-1 in 6 M KOH and 248 F g-1 in 2.5 M KNO3 electrolyte. Due to low toxicity and wider operating voltage (-1.8 V) of 2.5 KNO3, the material was further analysed in a symmetric device. The high surface area, the defects, and the high content of nitrogen (5.1%) revealed that the material produced an outstanding energy density of 17.2 Wh kg- 1 and a power density of 448.7 W kg- 1 in 2.5 M KNO3 electrolyte. The conversion of marula nuts waste into N-ACs thus provide a means of converting biomass waste into a useful energy storage material for supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2023, "Volume": 442, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141828, "DOI": "10.1016/j.electacta.2023.141828", "DOI Link": "http://dx.doi.org/10.1016/j.electacta.2023.141828", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000923621100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Simoncelli, M; Marzari, N; Mauri, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Simoncelli, Michele; Marzari, Nicola; Mauri, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wigner Formulation of Thermal Transport in Solids", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two different heat-transport mechanisms are discussed in solids. In crystals, heat carriers propagate and scatter particlelike as described by Peierls's formulation of the Boltzmann transport equation for phonon wave packets. In glasses, instead, carriers behave wavelike, diffusing via a Zener-like tunneling between quasidegenerate vibrational eigenstates, as described by the Allen-Feldman equation. Recently, it has been shown that these two conduction mechanisms emerge from a Wigner transport equation, which unifies and extends the Peierls-Boltzmann and Allen-Feldman formulations, allowing one to describe also complex crystals where particlelike and wavelike conduction mechanisms coexist. Recently, it has been shown that these two conduction mechanisms emerge as limiting cases from a unified transport equation, which describes on an equal footing solids ranging from crystals to glasses; moreover, in materials with intermediate characteristics the two conduction mechanisms coexist, and it is crucial to account for both. Here, we discuss the theoretical foundations of such transport equation as is derived from the Wigner phase-space formulation of quantum mechanics, elucidating how the interplay between disorder, anharmonicity, and the quantum Bose-Einstein statistics of atomic vibrations determines thermal conductivity. This Wigner formulation argues for a preferential phase convention for the dynamical matrix in the reciprocal Bloch representation and related off-diagonal velocity operator's elements; such convention is the only one yielding a conductivity which is invariant with respect to the nonunique choice of the crystal's unit cell and is size consistent. We rationalize the conditions determining the crossover from particlelike to wavelike heat conduction, showing that phonons below the Ioffe-Regel limit (i.e., with a mean free path shorter than the interatomic spacing) contribute to heat transport due to their wavelike capability to interfere and tunnel. Finally, we show that the present approach overcomes the failures of the Peierls-Boltzmann formulation for crystals with ultralow or glasslike thermal conductivity, with case studies of materials for thermal barrier coatings and thermoelectric energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2022, "Volume": 12, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41011, "DOI": "10.1103/PhysRevX.12.041011", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.12.041011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000885293700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nuckolls, KP; Lee, RL; Oh, M; Wong, D; Soejima, T; Hong, JP; Calugaru, D; Herzog-Arbeitman, J; Bernevig, BA; Watanabe, K; Taniguchi, T; Regnault, N; Zaletel, MP; Yazdani, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nuckolls, Kevin P.; Lee, Ryan L.; Oh, Myungchul; Wong, Dillon; Soejima, Tomohiro; Hong, Jung Pyo; Calugaru, Dumitru; Herzog-Arbeitman, Jonah; Bernevig, B. Andrei; Watanabe, Kenji; Taniguchi, Takashi; Regnault, Nicolas; Zaletel, Michael P.; Yazdani, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum textures of the many-body wavefunctions in magic-angle graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interactions among electrons create novel many-body quantum phases of matter with wavefunctions that reflect electronic correlation effects, broken symmetries and collective excitations. Many quantum phases have been discovered in magic-angle twisted bilayer graphene (MATBG), including correlated insulating(1), unconventional superconducting(2-5) and magnetic topological(6-9) phases. The lack of microscopic information(10,11) of possible broken symmetries has hampered our understanding of these phases(12-17). Here we use high-resolution scanning tunnelling microscopy to study the wavefunctions of the correlated phases in MATBG. The squares of the wavefunctions of gapped phases, including those of the correlated insulating, pseudogap and superconducting phases, show distinct broken-symmetry patterns with a root 3 x root 3 super-periodicity on the graphene atomic lattice that has a complex spatial dependence on the moire scale. We introduce a symmetry-based analysis using a set of complex-valued local order parameters, which show intricate textures that distinguish the various correlated phases. We compare the observed quantum textures of the correlated insulators at fillings of +/- 2 electrons per moire unit cell to those expected for proposed theoretical ground states. In typical MATBG devices, these textures closely match those of the proposed incommensurate Kekule spiral order(15), whereas in ultralow-strain samples, our data have local symmetries like those of a time-reversal symmetric intervalley coherent phase(12). Moreover, the superconducting state of MATBG shows strong signatures of intervalley coherence, only distinguishable from those of the insulator with our phase-sensitive measurements.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 61, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2023, "Volume": 620, "Issue": 7974, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 525, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06226-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06226-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169143500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kalaycioglu, Z; Uysal, BÖ; Pekcan, Ö; Erim, FB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kalaycioglu, Zeynep; Uysal, Bengu Ozugur; Pekcan, Onder; Erim, F. Bedia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Photocatalytic Degradation of Methylene Blue Dye from Aqueous Solution with Cerium Oxide nulloparticles and Graphene Oxide-Doped Polyacrylamide", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A cerium oxide nulloparticles (CeO2-NPs)/graphene oxide (GO)/polyacrylamide (PAM) ternary composite was synthesized through free-radical polymerization of acrylamide in the presence of CeO2 nulloparticles and GO in an aqueous system. The synthesized composite material was characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy techniques and applied for the photocatalytic degradation of methylene blue (MB) dye from an aqueous solution. Tauc's model for direct transition was used to model for the optical band gap. The key operating parameters such as the amounts of CeO2-NPs and GO, pH, initial MB concentration, type of light irradiation, and contact time have been optimized to achieve the highest MB degradation percentage. The photocatalysis process was pH-dependent, and the optimum pH value was found to be 12.0. Under UV-A light, 90% dye degradation occurred in 90 min. The degradation of MB was also specified in terms of total organic carbon (TOC) and chemical oxygen demand (COD). Free-radical capture experiments were also performed to determine the role of radical species during the photocatalytic oxidation process. The photocatalytic process showed that the equilibrium data is in good agreement with the Langmuir-Hinshelwood kinetic model. A rate constant of 0.0259 min-1 was obtained. The hydrogel was also tested to assess its reusability, which is an important key factor in practical wastewater treatment. The photocatalytic activity only decreased to 75% after nine uses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 95, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 11", "Publication Year": 2023, "Volume": 8, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 13004, "End Page": 13015, "Article Number": null, "DOI": "10.1021/acsomega.3c00198", "DOI Link": "http://dx.doi.org/10.1021/acsomega.3c00198", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000970635200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Islam, N; Arif, MFH; Abu Yousuf, M; Asaduzzaman, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Islam, Nazrul; Arif, Md. Faizul Huq; Abu Yousuf, Mohammad; Asaduzzaman, Sayed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly sensitive open channel based PCF-SPR sensor for analyte refractive index sensing", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The control of light in photonic crystal fiber (PCF) is a special characteristic that is obtained due to the relations between material and light. In this paper, a surface plasmon resonullce (SPR) based PCF sensor is introduced with two open-channel which cover an extensive field of bio-detection applications. Gold (Au) is considered as an effective plasmonic ingredient. The transformation of light through the fiber core is coupled with the gold and stimulates SPR. The proposed PCF-SPR sensor reports the highest wavelength sensitivity (WS) of 7000 nm/RIU (refractive index unit) as well as an amplitude sensitivity (AS) of 593.61 RIU-1. It also acquires an increased sensor resolution of 1.43 x 10-5 RIU and a decent figure of merit (FOM) is 94.97 RIU-1. Additionally, the operating constraints of the sensor such as corresponding air-holes diameter, the pitch, gold layer (Au) thickness and open-channel radius are revised to improve detection performance. The overall measurement is carried out over a broad range of variations in refractive index (RI) from 1.33 to 1.40. The sensor's appreciable performance makes it suitable for bio-sensing applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 46, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106266, "DOI": "10.1016/j.rinp.2023.106266", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2023.106266", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000990344300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ammarullah, MI; Santoso, G; Sugiharto, S; Supriyono, T; Wibowo, DB; Kurdi, O; Tauviqirrahman, M; Jamari, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ammarullah, Muhammad Imam; Santoso, Gatot; Sugiharto, S.; Supriyono, Toto; Wibowo, Dwi Basuki; Kurdi, Ojo; Tauviqirrahman, Mohammad; Jamari, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimizing Risk of Failure from Ceramic-on-Ceramic Total Hip Prosthesis by Selecting Ceramic Materials Based on Tresca Stress", "Source Title": "SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The choice of ceramic-on-ceramic coupling in total hip prosthesis has advantages over couplings with other combinations of materials that use polyethylene and metal materials in terms of high hardness, scratch resistance, low wear rate, and increased lubrication performance. To reduce the risk of primary postoperative failure, the selection of ceramic materials for ceramic-on-ceramic coupling is a strategic step that needs to be taken. The current study aims to analyze ceramic-on-ceramic coupling with commonly used ceramic materials, namely zirconium dioxide (ZrO2), silicon nitride (Si3N4), and aluminium oxide (Al2O3), according to Tressa failure criterion for the investigation of the stress distribution. A two-dimensional axisymmetric finite element-based computational model has been used to evaluate the Tresca stress on ceramic-on-ceramic coupling under gait cycle. The results show that the use of ZrO2-on-ZrO2 couplings can reduce Tresca stress by about 17.34% and 27.23% for Si3N4-on-Si3N4 and Al2O3-on-Al2O3 couplings, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 14, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13413, "DOI": "10.3390/su142013413", "DOI Link": "http://dx.doi.org/10.3390/su142013413", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000875932800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Datta, SS; Ardekani, AM; Arratia, PE; Beris, AN; Bischofberger, I; McKinley, GH; Eggers, JG; Lopez-Aguilar, JE; Fielding, SM; Frishman, A; Graham, MD; Guasto, JS; Haward, SJ; Shen, AQ; Hormozi, S; Morozov, A; Poole, RJ; Shankar, V; Shaqfeh, ESG; Stark, H; Steinberg, V; Subramanian, G; Stone, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Datta, Sujit S.; Ardekani, Arezoo M.; Arratia, Paulo E.; Beris, Antony N.; Bischofberger, Irmgard; McKinley, Gareth H.; Eggers, Jens G.; Lopez-Aguilar, J. Esteban; Fielding, Suzanne M.; Frishman, Anna; Graham, Michael D.; Guasto, Jeffrey S.; Haward, Simon J.; Shen, Amy Q.; Hormozi, Sarah; Morozov, Alexander; Poole, Robert J.; Shankar, V.; Shaqfeh, Eric S. G.; Stark, Holger; Steinberg, Victor; Subramanian, Ganesh; Stone, Howard A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perspectives on viscoelastic flow instabilities and elastic turbulence", "Source Title": "PHYSICAL REVIEW FLUIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Viscoelastic fluids are a common subclass of rheologically complex materials that are encountered in diverse fields from biology to polymer processing. Often the flows of vis-coelastic fluids are unstable in situations where ordinary Newtonian fluids are stable, owing to the nonlinear coupling of the elastic and viscous stresses. Perhaps more surprisingly, the instabilities produce flows with many of the hallmarks of turbulence-even though the ef-fective Reynolds numbers may be O(1) or smaller. We provide perspectives on viscoelastic flow instabilities by integrating the input from speakers at a recent international workshop: historical remarks, characterization of fluids and flows, discussion of experimental and simulation tools, and modern questions and puzzles that motivate further studies of this fascinating subject. The materials here will be useful for researchers and educators alike, especially as the subject continues to evolve in both fundamental understanding and applications in engineering and the sciences.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 29", "Publication Year": 2022, "Volume": 7, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 80701, "DOI": "10.1103/PhysRevFluids.7.080701", "DOI Link": "http://dx.doi.org/10.1103/PhysRevFluids.7.080701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863183400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Heath, A; Paine, K; McManus, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Heath, Andrew; Paine, Kevin; McManus, Marcelle", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Minimising the global warming potential of clay based geopolymers", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Production of Portland cement (PC) binders contributes substantially to global CO2 production and various bodies including the Intergovernmental Panel on Climate Change (IPCC) have identified geopolymers as alternative binders with the potential to reduce these emissions. The hypothesis of this research is to investigate whether this is a realistic proposition in the light of limited waste materials such as fly ash and ground granulated blast furnace slag commonly used as geopolymer precursors. The effect of use of natural clay minerals as alternative precursors on global warming potential (GWP) is investigated. Methods of designing mixes with the lowest possible GWP are presented and these are compared to the GWP of PC and currently available metakaolin based geopolymer binders. It is concluded that it is possible to reduce the GWP by approximately 40%, but other impacts may increase. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 246, "Times Cited, All Databases": 260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2014, "Volume": 78, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 75, "End Page": 83, "Article Number": null, "DOI": "10.1016/j.jclepro.2014.04.046", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2014.04.046", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000340318300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abboud, Y; Saffaj, T; Chagraoui, A; El Bouari, A; Brouzi, K; Tanulle, O; Ihssane, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abboud, Y.; Saffaj, T.; Chagraoui, A.; El Bouari, A.; Brouzi, K.; Tanulle, O.; Ihssane, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biosynthesis, characterization and antimicrobial activity of copper oxide nulloparticles (CONPs) produced using brown alga extract (Bifurcaria bifurcata)", "Source Title": "APPLIED nullOSCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, biosynthesis of nulloparticles has attracted scientists' attention because of the necessity to develop new clean, cost-effective and efficient synthesis techniques. In particular, metal oxide nulloparticles are receiving increasing attention in a large variety of applications. However, up to now, the reports on the biopreparation and characterization of nullocrystalline copper oxide are relatively few compared to some other metal oxides. In this paper, we report for the first time the use of brown alga (Bifurcaria bifurcata) in the biosynthesis of copper oxide nulloparticles of dimensions 5-45 nm. The synthesized nullomaterial is characterized by UV-visible absorption spectroscopy and Fourier transform infrared spectrum analysis. X-ray diffraction confirms the formation and the crystalline nature of copper oxide nullomaterial. Further, these nulloparticles were found to exhibit high antibacterial activity against two different strains of bacteria Enterobacter aerogenes (Gram negative) and Staphylococcus aureus (Gram positive).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 398, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2014, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 571, "End Page": 576, "Article Number": null, "DOI": "10.1007/s13204-013-0233-x", "DOI Link": "http://dx.doi.org/10.1007/s13204-013-0233-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000209843600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Born, J; Manica, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Born, Jannis; Manica, Matteo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regression Transformer enables concurrent sequence regression and generation for molecular language modelling", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transformer models are gaining increasing popularity in modelling natural language as they can produce human-sounding text by iteratively predicting the next word in a sentence. Born and Manica apply the idea of Transformer-based text completion to property prediction of chemical compounds by providing the context of a problem and having the model complete the missing information. Despite tremendous progress of generative models in the natural sciences, their controllability remains challenging. One fundamentally missing aspect of molecular or protein generative models is an inductive bias that can reflect continuous properties of interest. To that end, we propose the Regression Transformer (RT), a method that abstracts regression as a conditional sequence modelling problem. This introduces a new direction for multitask language models, seamlessly bridging sequence regression and conditional sequence generation. We demonstrate that, despite using a nominal-scale training objective, the RT matches or surpasses the performance of conventional regression models in property prediction of small molecules, proteins and chemical reactions. Critically, priming the same model with continuous properties yields a competitive conditional generative model that outperforms specialized approaches in a substructure-constrained, property-driven molecule generation benchmark. Our dichotomous approach is facilitated by an alternating training scheme that enables the model to decorate seed sequences on the basis of desired property constraints, for example, to optimize reaction yield. We expect that the RT's capability to jointly tackle predictive and generative tasks in biochemistry can find applications in property-driven, local exploration of the chemical or protein space. Such multitask approaches will pave the road towards foundation models in materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 432, "End Page": "+", "Article Number": null, "DOI": "10.1038/s42256-023-00639-z", "DOI Link": "http://dx.doi.org/10.1038/s42256-023-00639-z", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000963904900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XF; Zhao, J; Wang, Q; Shen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaofeng; Zhao, Jia; Wang, Qi; Shen, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical approximations for a three-component Cahn-Hilliard phase-field model based on the invariant energy quadratization method", "Source Title": "MATHEMATICAL MODELS & METHODS IN APPLIED SCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "How to develop efficient numerical schemes while preserving energy stability at the discrete level is challenging for the three-component Cahn-Hilliard phase-field model. In this paper, we develop a set of first- and second-order temporal approximation schemes based on a novel Invariant Energy Quadratization approach, where all nonlinear terms are treated semi-explicitly. Consequently, the resulting numerical schemes lead to well-posed linear systems with a linear symmetric, positive definite at each time step. We prove that the developed schemes are unconditionally energy stable and present various 2D and 3D numerical simulations to demonstrate the stability and the accuracy of the schemes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2017, "Volume": 27, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1993, "End Page": 2030, "Article Number": null, "DOI": "10.1142/S0218202517500373", "DOI Link": "http://dx.doi.org/10.1142/S0218202517500373", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408991400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Silling, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Silling, S. A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stability of peridynamic correspondence material models and their particle discretizations", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Peridynamic correspondence material models provide a way to combine a material model from the local theory with the inherent capabilities of peridynamics to model long-range forces and fracture. However, correspondence models in a typical particle discretization suffer from zero-energy mode instability. These instabilities are shown here to be an aspect of material stability. A stability condition is derived for state-based materials starting from the requirement of potential energy minimization. It is shown that all correspondence materials fail this stability condition due to zero-energy deformation modes of the family. To eliminate these modes, a term is added to the correspondence strain energy density that resists deviations from a uniform deformation. The resulting material model satisfies the stability condition while effectively leaving the stress tensor unchanged. Computational examples demonstrate the effectiveness of the modified material model in avoiding zero-energy mode instability in a peridynamic particle code. (C) 2017 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 322, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 42, "End Page": 57, "Article Number": null, "DOI": "10.1016/j.cma.2017.03.043", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2017.03.043", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404823300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kozlovskiy, A; Egizbek, K; Zdorovets, M; Ibragimova, M; Shumskaya, A; Rogachev, AA; Ignatovich, Z; Kadyrzhanov, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kozlovskiy, Artem; Egizbek, Kamila; Zdorovets, Maxim, V; Ibragimova, Milana; Shumskaya, Alena; Rogachev, Alexandr A.; Ignatovich, Zhanna, V; Kadyrzhanov, Kayrat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evaluation of the Efficiency of Detection and Capture of Manganese in Aqueous Solutions of FeCeOx nullocomposites Doped with Nb2O5", "Source Title": "SENSORS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The main purpose of this work is to study the effectiveness of using FeCeO(x)nullocomposites doped with Nb(2)O(5)for the purification of aqueous solutions from manganese. X-ray diffraction, energy-dispersive analysis, scanning electron microscopy, vibrational magnetic spectroscopy, and mossbauer spectroscopy were used as research methods. It is shown that an increase in the dopant concentration leads to the transformation of the shape of nulloparticles from spherical to cubic and rhombic, followed by an increase in the size of the nulloparticles. The spherical shape of the nulloparticles is characteristic of a structure consisting of a mixture of two phases of hematite (Fe2O3) and cerium oxide CeO2. The cubic shape of nulloparticles is typical for spinel-type FeNbO(4)structures, the phase contribution of which increases with increasing dopant concentration. It is shown that doping leads not only to a decrease in the concentration of manganese in model solutions, but also to an increase in the efficiency of adsorption from 11% to 75%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 20, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4851, "DOI": "10.3390/s20174851", "DOI Link": "http://dx.doi.org/10.3390/s20174851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Instruments & Instrumentation", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569599500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XF; Zou, CL; Zhu, N; Marquardt, F; Jiang, L; Tang, HX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xufeng; Zou, Chang-Ling; Zhu, Na; Marquardt, Florian; Jiang, Liang; Tang, Hong X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnon dark modes and gradient memory", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Extensive efforts have been expended in developing hybrid quantum systems to overcome the short coherence time of superconducting circuits by introducing the naturally long-lived spin degree of freedom. Among all the possible materials, single-crystal yttrium iron garnet has shown up recently as a promising candidate for hybrid systems, and various highly coherent interactions, including strong and even ultrastrong coupling, have been demonstrated. One distinct advantage in these systems is that spins form well-defined magnon modes, which allows flexible and precise tuning. Here we demonstrate that by dissipation engineering, a non-Markovian interaction dynamics between the magnon and the microwave cavity photon can be achieved. Such a process enables us to build a magnon gradient memory to store information in the magnon dark modes, which decouple from the microwave cavity and thus preserve a long lifetime. Our findings provide a promising approach for developing long-lifetime, multimode quantum memories.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 287, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8914, "DOI": "10.1038/ncomms9914", "DOI Link": "http://dx.doi.org/10.1038/ncomms9914", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366378900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Bhattarai, S; Arnab, AA; Mohammed, MKA; Pandey, R; Ali, MH; Rahman, MF; Islam, MR; Samajdar, DP; Madan, J; Bencherif, H; Dwivedi, DK; Amami, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Bhattarai, Sagar; Arnab, A. A.; Mohammed, Mustafa K. A.; Pandey, Rahul; Ali, Md Hasan; Rahman, Md. Ferdous; Islam, Md. Rasidul; Samajdar, D. P.; Madan, Jaya; Bencherif, H.; Dwivedi, D. K.; Amami, Mongi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Harnessing the potential of CsPbBr3-based perovskite solar cells using efficient charge transport materials and global optimization", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) have become a possible alternative to traditional photovoltaic devices for their high performance, low cost, and ease of fabrication. Here in this study, the SCAPS-1D simulator numerically simulates and optimizes CsPbBr3-based PSCs under the optimum illumination situation. We explore the impact of different back metal contacts (BMCs), including Cu, Ag, Fe, C, Au, W, Pt, Se, Ni, and Pd combined with the TiO2 electron transport layer (ETL) and CFTS hole transport layer (HTL), on the performance of the devices. After optimization, the ITO/TiO2/CsPbBr3/CFTS/Ni structure showed a maximum power conversion efficiency (PCE or & eta;) of 13.86%, with Ni as a more cost-effective alternative to Au. After the optimization of the BMC the rest of the investigation is conducted both with and without HTL mode. We investigate the impact of changing the thickness and the comparison with acceptor and defect densities (with and without HTL) of the CsPbBr3 perovskite absorber layer on the PSC performance. Finally, we optimized the thickness, charge carrier densities, and defect densities of the absorber, ETL, and HTL, along with the interfacial defect densities at HTL/absorber and absorber/ETL interfaces to improve the PCE of the device; and the effect of variation of these parameters is also investigated both with and without HTL connected. The final optimized configuration achieved a V-OC of 0.87 V, J(SC) of 27.57 mA cm(-2), FF of 85.93%, and PCE of 20.73%. To further investigate the performance of the optimized device, we explore the impact of the temperature, shunt resistance, series resistance, capacitance, generation rate, recombination rate, Mott-Schottky, JV, and QE features of both with and without HTL connected. The optimized device offers the best thermal stability at a temperature of 300 K. Our study highlights the potential of CsPbBr3-based PSCs and provides valuable insights for their optimization and future development.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 81, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2023, "Volume": 13, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21044, "End Page": 21062, "Article Number": null, "DOI": "10.1039/d3ra02485g", "DOI Link": "http://dx.doi.org/10.1039/d3ra02485g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001024948000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, ZD; Bernevig, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Zhi-Da; Bernevig, B. Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magic-Angle Twisted Bilayer Graphene as a Topological Heavy Fermion Problem", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magic-angle (theta = 1.05 degrees) twisted bilayer graphene (MATBG) has shown two seemingly contradictory characters: the localization and quantum-dot-like behavior in STM experiments, and delocalization in transport experiments. We construct a model, which naturally captures the two aspects, from the BistritzerMacDonald (BM) model in a first principle spirit. A set of local flat-band orbitals (f) centered at the AA-stacking regions are responsible to the localization. A set of extended topological semimetallic conduction bands (c), which are at small energetic separation from the local orbitals, are responsible to the delocalization and transport. The topological flat bands of the BM model appear as a result of the hybridization of f and c electrons. This model then provides a new perspective for the strong correlation physics, which is now described as strongly correlated f electrons coupled to nearly free c electrons-we hence name our model as the topological heavy fermion model. Using this model, we obtain the U(4) and U(4) x U(4) symmetries of Refs. [1-5] as well as the correlated insulator phases and their energies. Simple rules for the ground states and their Chern numbers are derived. Moreover, features such as the large dispersion of the charge +/- 1 excitations [2,6,7], and the minima of the charge gap at the GM point can now, for the first time, be understood both qualitatively and quantitatively in a simple physical picture. Our mapping opens the prospect of using heavy-fermion physics machinery to the superconducting physics of MATBG.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 22", "Publication Year": 2022, "Volume": 129, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 47601, "DOI": "10.1103/PhysRevLett.129.047601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.129.047601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000840947600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aygün, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aygun, Bunyamin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High alloyed new stainless steel shielding material for gamma and fast neutron radiation", "Source Title": "NUCLEAR ENGINEERING AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stainless steel is used commonly in nuclear applications for shielding radiation, so in this study, three different types of new stainless steel samples were designed and developed. New stainless steel compound ratios were determined by using Monte Carlo Simulation program Geant 4 code. In the sample production, iron (Fe), nickel (Ni), chromium (Cr), silicium (Si), sulphur (S), carbon (C), molybdenum (Mo), manganese (Mn), wolfram (W), rhenium (Re), titanium (Ti) and vanadium (V), powder materials were used with powder metallurgy method. Total macroscopic cross sections, mean free path and transmission number were calculated for the fast neutron radiation shielding by using (Geant 4) code. In addition to neutron shielding, the gamma absorption parameters such as mass attenuation coefficients (MACS) and half value layer (HVL) were calculated using Win-XCOM software. Sulfuric acid abrasion and compressive strength tests were carried out and all samples showed good resistance to acid wear and pressure force. The neutron equivalent dose was measured using an average 4.5 MeV energy fast neutron source. Results were compared to 316LN type stainless steel, which commonly used in shielding radiation. New stainless steel samples were found to absorb neutron better than 316LN stainless steel at both low and high temperatures. (C) 2019 Korean Nuclear Society, Published by Elsevier Korea LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 192, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 52, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 647, "End Page": 653, "Article Number": null, "DOI": "10.1016/j.net.2019.08.017", "DOI Link": "http://dx.doi.org/10.1016/j.net.2019.08.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000516803800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Petousis, I; Mrdjenovich, D; Ballouz, E; Liu, M; Winston, D; Chen, W; Graf, T; Schladt, TD; Persson, KA; Prinz, FB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Petousis, Ioannis; Mrdjenovich, David; Ballouz, Eric; Liu, Miao; Winston, Donald; Chen, Wei; Graf, Tanja; Schladt, Thomas D.; Persson, Kristin A.; Prinz, Fritz B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput screening of inorganic compounds for the discovery of novel dielectric and optical materials", "Source Title": "SCIENTIFIC DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Data Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Dielectrics are an important class of materials that are ubiquitous in modern electronic applications. Even though their properties are important for the performance of devices, the number of compounds with known dielectric constant is on the order of a few hundred. Here, we use Density Functional Perturbation Theory as a way to screen for the dielectric constant and refractive index of materials in a fast and computationally efficient way. Our results constitute the largest dielectric tensors database to date, containing 1,056 compounds. Details regarding the computational methodology and technical validation are presented along with the format of our publicly available data. In addition, we integrate our dataset with the Materials Project allowing users easy access to material properties. Finally, we explain how our dataset and calculation methodology can be used in the search for novel dielectric compounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2017, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 160134, "DOI": "10.1038/sdata.2016.134", "DOI Link": "http://dx.doi.org/10.1038/sdata.2016.134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392955000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YH; Zhu, JP; Li, ML; Shao, G; Wang, HL; Zhang, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuhan; Zhu, Jinpeng; Li, Mingliang; Shao, Gang; Wang, Hailong; Zhang, Rui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal properties of high-entropy RE-disilicates controlled by high throughput composition design and optimization", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The configuration entropy was manipulated by introducing atoms with unique properties using the high throughput calculations, and five new disilicates with ideal properties which have lower thermal conductivity and controllable thermal expansion coefficient were obtained through composition design. From a microstructural perspective, the inclusion of atoms with larger ionic radius differences (reaching a 4.11 % contrast with Yb2Si2O7) can cause sever lattice shrinkage (9.49 % compared to single-component disilicates), which leads to lower thermal conductivity and a change in the thermal expansion coefficient. At 1200 degrees C, the thermal expansion coefficient of the five high-entropy disilicates ranged from 4.57 x 10-6 K- 1 to 4.84 x 10-6 K-1, and the minimum thermal conductivity was only 1.14 W/m & sdot;K. Additionally, the local charge disorder facilitates the transfer of electrons around Si-O to Sc, which reduces the covalent bond strength of Si-O and regulates the thermal expansion coefficient. This phenomenon has been proved in the five non-equimolar high-entropy disilicates with different contents of Sc, effectively regulating the thermal expansion coefficient in 4.08 x 10-6 K-1 to 5.04 x 10-6 K-1. This study presents a novel method for controlling the thermal properties of disilicates and expands the possibilities for selecting thermal protective coating materials for ultra-high temperature SiC-based ceramic composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 236, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112485, "DOI": "10.1016/j.matdes.2023.112485", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2023.112485", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001121625600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ali, NS; Kalash, KR; Ahmed, AN; Albayati, TM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ali, Nisreen S.; Kalash, Khairi R.; Ahmed, Amer N.; Albayati, Talib M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance of a solar photocatalysis reactor as pretreatment for wastewater via UV, UV/TiO2, and UV/H2O2 to control membrane fouling", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of a solar photocatalysis reactor as pretreatment for the removal of total organic carbon (TOC) and turbidity from municipal wastewater was achieved by implementing an integrated system as tertiary treatment. The process consisted of ultraviolet (UV) sunlight, UV sunlight/H2O2, and UV sunlight/TiO2 nullocatalysts as pretreatment steps to prevent ultrafiltration (UF) membrane fouling. The characterization of TiO2 was conducted with X-ray diffraction spectroscopy, Fourier-transform infrared spectroscopy, scanning electron microscopy , and Brunauer-Emmett-Teller surface area analysis. This study investigated the effect of time and solar radiation using UV, UV/H2O2, and UV/TiO2 to remove TOC and turbidity. The transmembrane pressure improvement was studied using a UF membrane system to pretreat wastewater with different UV doses of sunlight for 5 h and UV/H2O2 and UV/TiO2. The results showed that the highest removal efficiency of the turbidity and TOC reached 95% and 31%, respectively. The highest removal efficiency of the turbidity reached 40, 75, and 95% using UV, UV/H2O2, and UV/TiO2, respectively, while the optimal removal efficiency of TOC reached 20%, 30%, and 50%, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 6", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16782, "DOI": "10.1038/s41598-022-20984-0", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-20984-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000864845400088", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Müller, PC; Ertural, C; Hempelmann, J; Dronskowski, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mueller, Peter C.; Ertural, Christina; Hempelmann, Jan; Dronskowski, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal Orbital Bond Index: Covalent Bond Orders in Solids", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystal orbital bond index (COBI) is a new and intuitive method for quantifying covalent bonding in solid-state materials. COBI is based on the bond index by Wiberg and Mayer and extends their ideas to the case of translationally invariant objects, that is, crystalline matter. COBI's qualitative interpretation resembles the well-established crystal orbital overlap population and crystal orbital Hamilton population methods but should be more familiar to chemists since it directly relates to the classical bond order. In contrast to the aforementioned descriptors, COBI also allows for examining multicenter interactions within a local-orbital framework. As an additional bonding indicator, we refer to the Ewald sum for electrostatic lattice potentials, thereby enabling the calculation of electrostatic lattice energies as well as site potentials from quantum-mechanical charges as directly derived from the wave function, not from the density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 174, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2021, "Volume": 125, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7959, "End Page": 7970, "Article Number": null, "DOI": "10.1021/acs.jpcc.1c00718", "DOI Link": "http://dx.doi.org/10.1021/acs.jpcc.1c00718", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000641307100043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, X; Helbig, N; Verstraete, MJ; Bousquet, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xu; Helbig, Nicole; Verstraete, Matthieu J.; Bousquet, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "TB2J: A python package for computing magnetic interaction parameters", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present TB2J, a Python package for the automatic computation of magnetic interactions, including exchange and Dzyaloshinskii-Moriya, between atoms of magnetic crystals from the results of density functional calculations. The program is based on the Green's function method with the local rigid spin rotation treated as a perturbation. As input, the package uses the output of either Wannier90, which is interfaced with many density functional theory packages, or of codes based on localized orbitals. One of the main interests of the code is that it requires only one first-principles electronic structure calculation in the non-relativistic case (or three in the relativistic case) and from the primitive cell only to obtain the magnetic interactions up to long distances, instead of first-principles calculations of many different magnetic configurations and large supercells. The output of TB2J can be used directly for the adiabatic magnon band structure and spin dynamics calculations. A minimal user input is needed, which allows for easy integration into high-throughput workflows. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 157, "Times Cited, All Databases": 163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 264, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107938, "DOI": "10.1016/j.cpc.2021.107938", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.107938", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000659862300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Albas, SD; Ersoy, H; Akgöz, B; Civalek, Ö", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Albas, Seref D.; Ersoy, Hakan; Akgoz, Bekir; Civalek, Omer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic Analysis of a Fiber-Reinforced Composite Beam under a Moving Load by the Ritz Method", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents the dynamic responses of a fiber-reinforced composite beam under a moving load. The Timoshenko beam theory was employed to analyze the kinematics of the composite beam. The constitutive equations for motion were obtained by utilizing the Lagrange procedure. The Ritz method with polynomial functions was employed to solve the resulting equations in conjunction with the Newmark average acceleration method (NAAM). The influence of fiber orientation angle, volume fraction, and velocity of the moving load on the dynamic responses of the fiber-reinforced nonhomogeneous beam is presented and discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 109, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1048, "DOI": "10.3390/math9091048", "DOI Link": "http://dx.doi.org/10.3390/math9091048", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000650557300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kennes, DM; Lischner, J; Karrasch, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kennes, Dante M.; Lischner, Johannes; Karrasch, Christoph", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong correlations and d plus id superconductivity in twisted bilayer graphene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We compute the phase diagram of twisted bilayer graphene near the magic angle where the occurrence of flat bands enhances the effects of electron-electron interactions and thus unleashes strongly correlated phenomena. Most importantly, we find a crossover between d + id superconductivity and antiferromagnetic insulating behavior near half filling of the lowest electron band when the temperature is increased. This is consistent with recent experiments. Our results are obtained using unbiased many-body renormalization group techniques combined with a mean-field analysis of the effective couplings. We provide a qualitative understanding by considering the competition between Fermi-surface nesting and van Hove singularities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 186, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2018, "Volume": 98, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 241407, "DOI": "10.1103/PhysRevB.98.241407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.98.241407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453464600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khorrami, S; Zarrabi, A; Khaleghi, M; Danaei, M; Mozafari, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khorrami, Sadegh; Zarrabi, Ali; Khaleghi, Moj; Danaei, Marziyeh; Mozafari, M. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective cytotoxicity of green synthesized silver nulloparticles against the MCF-7 tumor cell line and their enhanced antioxidant and antimicrobial properties", "Source Title": "INTERNATIONAL JOURNAL OF nullOMEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Introduction: Silver nulloparticles (AgNPs) are of great interest due to their unique and controllable characteristics. Different synthesis methods have been proposed to produce these nulloparticles, which often require elevated temperatures/pressures or toxic solvents. Thus, green synthesis could be a replacement option as a simple, economically viable and environmentally friendly alternative approach for the synthesis of silver nulloparticles. Methods: Here, the potential of the walnut green husk was investigated in the production of silver nulloparticles. An aqueous solution extracted from walnut green husk was used as a reducing agent as well as a stabilizing agent. Then, the synthesized nulloparticles were characterized with respect of their anticancer, antioxidant, and antimicrobial properties. Results: Results showed that the synthesized nulloparticles possessed an average size of 31.4 nm with a Zeta potential of -33.8 mV, indicating high stability. A significant improvement in the cytotoxicity and antioxidant characteristics of the green synthesized Ag nulloparticles against a cancerous cell line was observed in comparison with the walnut green husk extract and a commercial silver nulloparticle (CSN). This could be due to a synergistic effect of the synthesized silver nulloparticles and their biological coating. AgNPs and the extract exhibited 70% and 40% cytotoxicity against MCF-7 cancerous cells, respectively, while CSN caused 56% cell death (at the concentration of 60 mu g/mL). It was observed that AgNPs were much less cytotoxic when tested against a noncancerous cell line (L-929) in comparison with the control material (CSN). The free radical scavenging analysis demonstrated profound anti-oxidant activity for the synthesized nulloparticles in comparison with the extract and CSN. It was also detected that the synthesized AgNPs possess antibacterial activity against nosocomial and standard strains of both Gram-positive and Gram-negative bacteria (minimum inhibitory concentration =5-30 mu g/mL). Conclusion: These findings imply that the synthesized nulloparticles using green nullotechnology could be an ideal strategy to combat cancer and infectious diseases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 378, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 13, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8013, "End Page": 8024, "Article Number": null, "DOI": "10.2147/IJN.S189295", "DOI Link": "http://dx.doi.org/10.2147/IJN.S189295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451259800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saddik, MS; Elsayed, MMA; El-Mokhtar, MA; Sedky, H; Abdel-Aleem, JA; Abu-Dief, AM; Al-Hakkani, MF; Hussein, HL; Al-Shelkamy, SA; Meligy, FY; Khames, A; Abou-Taleb, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saddik, Mohammed S.; Elsayed, Mahmoud M. A.; El-Mokhtar, Mohamed A.; Sedky, Haitham; Abdel-Aleem, Jelan A.; Abu-Dief, Ahmed M.; Al-Hakkani, Mostafa F.; Hussein, Hazem L.; Al-Shelkamy, Samah A.; Meligy, Fatma Y.; Khames, Ali; Abou-Taleb, Heba A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring of Novel Azithromycin-Loaded Zinc Oxide nulloparticles for Wound Healing", "Source Title": "PHARMACEUTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Skin is the largest mechanical barrier against invading pathogens. Following skin injury, the healing process immediately starts to regenerate the damaged tissues and to avoid complications that usually include colonization by pathogenic bacteria, leading to fever and sepsis, which further impairs and complicates the healing process. So, there is an urgent need to develop a novel pharmaceutical material that promotes the healing of infected wounds. The present work aimed to prepare and evaluate the efficacy of novel azithromycin-loaded zinc oxide nulloparticles (AZM-ZnONPs) in the treatment of infected wounds. The Box-Behnken design and response surface methodology were used to evaluate loading efficiency and release characteristics of the prepared NPs. The minimum inhibitory concentration (MIC) of the formulations was determined against Staphylococcus aureus and Escherichia coli. Moreover, the anti-bacterial and wound-healing activities of the AZM-loaded ZnONPs impregnated into hydroxyl propyl methylcellulose (HPMC) gel were evaluated in an excisional wound model in rats. The prepared ZnONPs were loaded with AZM by adsorption. The prepared ZnONPs were fully characterized by XRD, EDAX, SEM, TEM, and FT-IR analysis. Particle size distribution for the prepared ZnO and AZM-ZnONPs were determined and found to be 34 and 39 nm, respectively. The mechanism by which AZM adsorbed on the surface of ZnONPs was the best fit by the Freundlich model with a maximum load capacity of 160.4 mg/g. Anti-microbial studies showed that AZM-ZnONPs were more effective than other controls. Using an experimental infection model in rats, AZM-ZnONPs impregnated into HPMC gel enhanced bacterial clearance and epidermal regeneration, and stimulated tissue formation. In conclusion, AZM -loaded ZnONPs are a promising platform for effective and rapid healing of infected wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 91, "Times Cited, All Databases": 91, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 111, "DOI": "10.3390/pharmaceutics14010111", "DOI Link": "http://dx.doi.org/10.3390/pharmaceutics14010111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746243000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Limas, NG; Manz, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Limas, Nidia Gabaldon; Manz, Thomas A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Introducing DDEC6 atomic population analysis: part 2. Computed results for a wide range of periodic and nonperiodic materials", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Net atomic charges (NACs) are widely used throughout the chemical sciences to concisely summarize key information about charge transfer between atoms in materials. The vast majority of NAC definitions proposed to date are unsuitable for describing the wide range of material types encountered across the chemical sciences. In this article, we show the DDEC6 method reproduces important chemical, theoretical, and experimental properties across an extremely broad range of material types including small and large molecules, organometallics, nulloclusters, porous solids, nonporous solids, and solid surfaces. Some important comparisons we make are: (a) correlations between various NAC models and spectroscopically measured core-electron binding energy shifts for Ti-, Fe-, and Mo-containing solids, (b) comparisons between DDEC6 and experimentally extracted NACs for formamide and natrolite, (c) comparisons of accuracy of different NAC methods for reproducing the electrostatic potential surrounding a material across one and multiple system conformations, (d) comparisons between calculated and chemically expected electron transfer trends for atoms in numerous dense solids, solid surfaces, and molecules, (e) an assessment of NAC transferability between three crystal phases of the diisopropylammonium bromide organic ferroelectric, and (f) comparisons between DDEC6 and polarized neutron diffraction atomic spin moments for the Mn-12-acetate single-molecule magnet. We find the DDEC6 NACs are ideally suited for constructing flexible force-fields and give reasonable agreement with force-fields commonly used to simulate biomolecules and water. We find the DDEC6 method is more accurate than the DDEC3 method for analyzing a broad range of materials. This broad applicability to periodic and non-periodic materials irrespective of the basis set type makes the DDEC6 method suited for use as a default atomic population analysis method in quantum chemistry programs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 445, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45727, "End Page": 45747, "Article Number": null, "DOI": "10.1039/c6ra05507a", "DOI Link": "http://dx.doi.org/10.1039/c6ra05507a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376120100093", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "de Borst, R; Verhoosel, CV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "de Borst, Rene; Verhoosel, Clemens V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient damage vs phase-field approaches for fracture: Similarities and differences", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Gradient-enhanced damage models and phase-field models are seemingly very disparate approaches to fracture. Whereas gradient-enhanced damage models find their roots in damage mechanics, which is a smeared approach from the onset, and gradients were added to restore well-posedness beyond a critical strain level, the phase-field approach to brittle fracture departs from a discontinuous description of failure, where the distribution function is regularised, leading to the inclusion of spatial gradients as well. Herein, we will consider both approaches, and discuss their similarities and differences. The averaging (diffusion) equations for the averaging field and the phase-field will be compared, and it is shown that the diffusion equation for the phase-field can be conceived as a special case of the averaging equation of a gradient-damage model where the damage is averaged. Further, the role of the driving force is examined, and it is shown that subtle differences in the degradation functions commonly adopted in damage and phase-field approaches are key to the observation that, different from damage mechanics, the fracture process zone does not broaden in the wake of the crack tip. (C) 2016 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 248, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2016, "Volume": 312, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 78, "End Page": 94, "Article Number": null, "DOI": "10.1016/j.cma.2016.05.015", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2016.05.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389784000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hiraoka, Y; Nakamura, T; Hirata, A; Escolar, EG; Matsue, K; Nishiura, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hiraoka, Yasuaki; Nakamura, Takenobu; Hirata, Akihiko; Escolar, Emerson G.; Matsue, Kaname; Nishiura, Yasumasa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical structures of amorphous solids characterized by persistent homology", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article proposes a topological method that extracts hierarchical structures of various amorphous solids. The method is based on the persistence diagram (PD), a mathematical tool for capturing shapes of multiscale data. The input to the PDs is given by an atomic configuration and the output is expressed as 2D histograms. Then, specific distributions such as curves and islands in the PDs identify meaningful shape characteristics of the atomic configuration. Although the method can be applied to a wide variety of disordered systems, it is applied here to silica glass, the Lennard-Jones system, and Cu-Zr metallic glass as standard examples of continuous random network and random packing structures. In silica glass, the method classified the atomic rings as short-range and medium-range orders and unveiled hierarchical ring structures among them. These detailed geometric characterizations clarified a real space origin of the first sharp diffraction peak and also indicated that PDs contain information on elastic response. Even in the Lennard-Jones system and Cu-Zr metallic glass, the hierarchical structures in the atomic configurations were derived in a similar way using PDs, although the glass structures and properties substantially differ from silica glass. These results suggest that the PDs provide a unified method that extracts greater depth of geometric information in amorphous solids than conventional methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2016, "Volume": 113, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7035, "End Page": 7040, "Article Number": null, "DOI": "10.1073/pnas.1520877113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1520877113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379033400037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Spicher, S; Grimme, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Spicher, Sebastian; Grimme, Stefan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Robust Atomistic Modeling of Materials, Organometallic, and Biochemical Systems", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Modern chemistry seems to be unlimited in molecular size and elemental composition. Metal-organic frameworks or biological macromolecules involve complex architectures and a large variety of elements. Yet, a general and broadly applicable theoretical method to describe the structures and interactions of molecules beyond the 1000-atom size regime semi-quantitatively is not self-evident. For this purpose, a generic force field named GFN-FF is presented, which is completely newly developed to enable fast structure optimizations and molecular-dynamics simulations for basically any chemical structure consisting of elements up to radon. The freely available computer program requires only starting coordinates and elemental composition as input from which, fully automatically, all potential-energy terms are constructed. GFN-FF outperforms other force fields in terms of generality and accuracy, approaching the performance of much more elaborate quantum-mechanical methods in many cases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 330, "Times Cited, All Databases": 337, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2020, "Volume": 59, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 15665, "End Page": 15673, "Article Number": null, "DOI": "10.1002/anie.202004239", "DOI Link": "http://dx.doi.org/10.1002/anie.202004239", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533294800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, YN; Li, DL; Fu, Q; Pan, CX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Youning; Li, Delong; Fu, Qiang; Pan, Chunxu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of graphene microstructures on electrochemical performance for supercapacitors", "Source Title": "PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The influence of variant graphenes on electrochemical performance for supercapacitors was studied comparatively and systematically by using SEM, FTIR and Raman spectroscopy, cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS). The results revealed that: 1) the nitrogen-doped graphene (N-G) electrode exhibited the highest specific capacitance at the same voltage scan rate; 2) the specific capacitance of the N-G reached up to 243.5 F/g at 1 A/g, while regular graphite oxide (GO) was 43.5 F/g and reduced graphene oxide (rGO) was 67.9 F/g; 3) N-G exhibited the best supercapacitance performance and the superior electrochemical properties, which made it an ideal electrode material for supercapacitors. (C) 2015 Chinese Materials Research Society. Production and hosting by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 389, "Times Cited, All Databases": 401, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 25, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 379, "End Page": 385, "Article Number": null, "DOI": "10.1016/j.pnsc.2015.10.004", "DOI Link": "http://dx.doi.org/10.1016/j.pnsc.2015.10.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366561700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kroschwald, S; Maharana, S; Mateju, D; Malinovska, L; Nüske, E; Poser, I; Richter, D; Alberti, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kroschwald, Sonja; Maharana, Shovamayee; Mateju, Daniel; Malinovska, Liliana; Nueske, Elisabeth; Poser, Ina; Richter, Doris; Alberti, Simon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promiscuous interactions and protein disaggregases determine the material state of stress-inducible RNP granules", "Source Title": "ELIFE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "RNA-protein (RNP) granules have been proposed to assemble by forming solid RNA/ protein aggregates or through phase separation into a liquid RNA/protein phase. Which model describes RNP granules in living cells is still unclear. In this study, we analyze P bodies in budding yeast and find that they have liquid-like properties. Surprisingly, yeast stress granules adopt a different material state, which is reminiscent of solid protein aggregates and controlled by protein disaggregases. By using an assay to ectopically nucleate RNP granules, we further establish that RNP granule formation does not depend on amyloid-like aggregation but rather involves many promiscuous interactions. Finally, we show that stress granules have different properties in mammalian cells, where they show liquid-like behavior. Thus, we propose that the material state of RNP granules is flexible and that the solid state of yeast stress granules is an adaptation to extreme environments, made possible by the presence of a powerful disaggregation machine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 416, "Times Cited, All Databases": 496, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2015, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e06807", "DOI": "10.7554/eLife.06807", "DOI Link": "http://dx.doi.org/10.7554/eLife.06807", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Life Sciences & Biomedicine - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358925700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, L; Zhang, Y; Shi, YQ; Xue, ZG; Cao, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Li; Zhang, Yang; Shi, Yuqiong; Xue, Zhigang; Cao, Mingli", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface Cracking and Fractal Characteristics of Cement Paste after Exposure to High Temperatures", "Source Title": "FRACTAL AND FRACTIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Destruction pattern analysis of building materials subjected to fire provide the basis for strengthening, restoring the bearing capacity, and optimizing the function of the building structure. The surface cracking and fractal characteristics of calcium carbonate whisker-reinforced cement pastes subjected to high temperatures were studied herein. The test results showed that at 400 degrees C, the surface crack area, length, and fractal dimension of cement pastes specimen increases from 0 to 35 mm(2), 100 mm, and 1.0, respectively, due to the increase of vapor pressure. When the temperature is above 900 degrees C, the calcium carbonate whisker (CW) and other hydration products in the specimen begin to decompose, causing the surface crack area, length, and fractal dimension of the cement paste specimen to increase from 0 to 120 mm(2), 310 mm, and 1.2, respectively. Compared with the length and width of cracks, the area, and fractal dimension of cracks are less affected by the size and shape of specimen. This paper uses image processing methods to analyze the cracking patterns and fractal characteristics of specimens after high-temperature treatment. The aim is to elucidate the quantitative relationship between concrete material, temperature, and cracking characteristics, providing theoretical basis for structural evaluation after exposure to high temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 31, "Times Cited, All Databases": 31, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 465, "DOI": "10.3390/fractalfract6090465", "DOI Link": "http://dx.doi.org/10.3390/fractalfract6090465", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000858194100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fouda, A; Eid, AM; Abdel-Rahman, MA; EL-Belely, EF; Awad, MA; Hassan, SE; AL-Faifi, ZE; Hamza, MF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fouda, Amr; Eid, Ahmed M.; Abdel-Rahman, Mohamed Ali; EL-Belely, Ehab F.; Awad, Mohamed A.; Hassan, Saad El-Din; AL-Faifi, Zarraq E.; Hamza, Mohammed F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Antimicrobial, Cytotoxicity, Larvicidal, and Repellence Activities of Brown Algae, Cystoseira crinita-Mediated Green Synthesis of Magnesium Oxide nulloparticles", "Source Title": "FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, the metabolites secreted by brown algae, Cystoseira crinita, were used as biocatalyst for green synthesis of magnesium oxide nulloparticles (MgO-NPs). The fabricated MgO-NPs were characterized using UV-vis spectroscopy, Fourier transforms infrared spectroscopy (FT-IR), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy linked with energy-dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Data showed successful formation of crystallographic and spherical MgO-NPs with sizes of 3-18 nm at a maximum surface plasmon resonullce of 320 nm. Moreover, EDX analysis confirms the presence of Mg and O in the sample with weight percentages of 54.1% and 20.6%, respectively. Phyco-fabricated MgO-NPs showed promising activities against Gram-positive bacteria, Gram-negative bacteria, and Candida albicans with MIC values ranging between 12.5 and 50 mu g mL(-1). The IC50 value of MgO-NPs against cancer cell lines (Caco-2) was 113.4 mu g mL(-1), whereas it was 141.2 mu g mL(-1) for normal cell lines (Vero cell). Interestingly, the green synthesized MgO-NPs exhibited significant larvicidal and pupicidal activity against Musca domestica. At 10 mu g mL(-1) MgO-NPs, the highest mortality percentages were 99.0%, 95.0%, 92.2%, and 81.0% for I, II, III instars' larvae, and pupa of M. domestica, respectively, with LC50 values (3.08, 3.49, and 4.46 mu g mL(-1)), and LC90 values (7.46, 8.89, and 10.43 mu g mL(-1)), respectively. Also, MgO-NPs showed repellence activity for adults of M. domestica at 10 mu g mL(-1) with 63.0%, 77.9%, 84.9%, and 96.8% after 12, 24, 48, and 72 h, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 28", "Publication Year": 2022, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 849921, "DOI": "10.3389/fbioe.2022.849921", "DOI Link": "http://dx.doi.org/10.3389/fbioe.2022.849921", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000773000100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mendes, CR; Dilarri, G; Forsan, CF; Sapata, VDR; Lopes, PRM; de Moraes, PB; Montagnolli, RN; Ferreira, H; Bidoia, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mendes, Carolina Rosai; Dilarri, Guilherme; Forsan, Carolina Froes; Ruy Sapata, Vinicius de Moraes; Matos Lopes, Paulo Renato; de Moraes, Peterson Bueno; Montagnolli, Renato Nallin; Ferreira, Henrique; Bidoia, Ederio Dino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial action and target mechanisms of zinc oxide nulloparticles against bacterial pathogens", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc oxide nulloparticles (ZnO NPs) are one of the most widely used nulloparticulate materials due to their antimicrobial properties, but their main mechanism of action (MOA) has not been fully elucidated. This study characterized ZnO NPs by using X-ray diffraction, FT-IR spectroscopy and scanning electron microscopy. Antimicrobial activity of ZnO NPs against the clinically relevant bacteria Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, and the Gram-positive model Bacillus subtilis was evaluated by performing resazurin microtiter assay (REMA) after exposure to the ZnO NPs at concentrations ranging from 0.2 to 1.4 mM. Sensitivity was observed at 0.6 mM for the Gram-negative and 1.0 mM for the Gram-positive cells. Fluorescence microscopy was used to examine the interference of ZnO NPs on the membrane and the cell division apparatus of B. subtilis (amy::pspac-ftsZ-gfpmut1) expressing FtsZ-GFP. The results showed that ZnO NPs did not interfere with the assembly of the divisional Z-ring. However, 70% of the cells exhibited damage in the cytoplasmic membrane after 15 min of exposure to the ZnO NPs. Electrostatic forces, production of Zn2+ ions and the generation of reactive oxygen species were described as possible pathways of the bactericidal action of ZnO. Therefore, understanding the bactericidal MOA of ZnO NPs can potentially help in the construction of predictive models to fight bacterial resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2658, "DOI": "10.1038/s41598-022-06657-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-06657-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757107700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JW; Sun, C; Phan, TNL; Lee, DC; Tan, Z; Jeon, H; Cho, S; Kwon, SK; Kim, YH; Kim, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jin-Woo; Sun, Cheng; Phan, Tan Ngoc-Lan; Lee, Dong Chan; Tan, Zhengping; Jeon, Hyesu; Cho, Shinuk; Kwon, Soon-Ki; Kim, Yun-Hi; Kim, Bumjoon J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trimerized small-molecule acceptors enable high-performance organic solar cells with high open-circuit voltage and prolonged life-time", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the recent development of Y-series small-molecule acceptors (SMAs) has led to a dramatic increase in the power conversion efficiency (PCE) of organic solar cells (OSCs), the operational stability (device lifetime) of OSCs is inadequate for commercialization. In this study, we develop a new trimer acceptor (TYT), consisting of three Y-based molecules linked by electron-donating spacers, to realize an OSC with high-performance (PCE > 18%) and -stability (t(80%) lifetime > 8000 h under 1 sun illumination, in which t(80%) lifetime is the time required for the PCE of the OSC to reach 80% of its initial value). We demonstrate that the trimerization approach affords an acceptor, TYT, with an upshifted lowest unoccupied molecular orbital energy level, which, in turn, affords an efficient OSC with a high open-circuit voltage (0.964 V). In addition, the glass-transition temperature (T-g) of TYT (217 degrees C) is significantly higher than those of monomer (MYT, T-g = 80 degrees C) and dimer (DYT, T-g = 127 degrees C) acceptors, which effectively suppresses the molecular diffusion of TYT in a blend film with a polymer donor. Accordingly, a TYT-based OSC demonstrates a high PCE (18.2%) and long t(80%) lifetime under 1 sun illumination (8454 h), outperforming MYT- and DYT-based OSCs that exhibit PCEs and t(80%) lifetimes of 16.4% and 35 h, and 17.3% and 2551 h, respectively. Therefore, this study provides important guidelines for the design of electron acceptors in achieving OSCs with high performance and stability close to a commercial level.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 66, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2023, "Volume": 16, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3339, "End Page": 3349, "Article Number": null, "DOI": "10.1039/d3ee00272a", "DOI Link": "http://dx.doi.org/10.1039/d3ee00272a", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001004947600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, LJ; Yu, XH; Tang, LY; Wang, WK; Liu, QQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Lijuan; Yu, Xiaohui; Tang, Liyong; Wang, Weikang; Liu, Qinqin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow dodecahedron K3PW12O40/CdS core-shell S-scheme heterojunction for photocatalytic synergistic H2 evolution and benzyl alcohol oxidation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneous generation of clean energy, H-2, and organic products holds immense potential in the realm of photocatalysis. The S-scheme heterojunction stands out for these dual-function applications due to its robust redox capacity, facilitating both the water reduction reaction and organic oxidation reactions. In this study, a Keggin-type polymetallic oxide, H3PW12O40 hollow dodecahedron (KPW), was synthesized using a hydrothermal approach. Subsequently, cadmium sulfide (CdS) nulloparticles averaging 15 nm in size were integrated in situ onto the KPW shell, resulting in the creation of a core-shell KPW@CdS S-scheme heterojunction. This optimized composite showcased a hydrogen evolution rate of 18.7 mmol g(-1) h(-1), alongside a value-added product, benzaldehyde, with a yield of 17.5 mmol g(-1) h(-1) substantially surpassing the performance of standalone CdS. This S-scheme junction, featuring a pronounced internal electronic field, emerges between the KPW and CdS. It significantly enhances the segregation of photogenerated carriers while preserving formida-ble redox capability. Furthermore, the hollow structure augments light absorption and utility, and the core-shell architecture delivers dual reduction and oxidation sites. As a result, the interplay between the hollow core-shell configuration and the S-scheme mode intensifies the photocatalytic activity. This research provides an innovative approach to crafting hollow S-scheme heterojunc-tions, aiming to optimize photocatalytic redox reactions for effective solar energy utilization.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 88, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 52, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 164, "End Page": 175, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64507-3", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64507-3", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001122882500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, B; Chen, J; Bai, F; Nie, QK; Jia, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Bing; Chen, Jing; Bai, Fan; Nie, Qingke; Jia, Xiangxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion effect of acid/alkali on cementitious red mud-fly ash materials containing heavy metal residues", "Source Title": "ENVIRONMENTAL TECHNOLOGY & INNOVATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-strength cementitious red mud-fly ash materials (RFMs) were formed from sodium hydroxide and water glass mixed solutions, and their abilities to solidify heavy metal ions (HMs, e. g., copper and cadmium) were assessed. The mechanism for precipitation of the HMs by corrosive acid/alkali solutions was explored via toxicity leaching tests, as well as SEM, XRD, FT-IR and XPS. The results showed that when the added alkaline activator was not fully consumed, the presence of small amounts of HMs consumed the excess alkaline ions to form hydroxide precipitates that filled the pores of the RFM, so the compressive strength of the RFM increased. Otherwise, the presence of excess HMs reduced the compactness of the RFM and eventually resulted in a highly porous structure, leading to weakening of the material. Additionally, small amounts of anhydrite phases were produced in the RFM. In neutral and alkaline environments, the HMs formed precipitates or coordination complexes with hydroxyl groups, and the solidification efficiencies exceeded 99%. In acidic environments, the HMs converted from their original precipitated forms or ion-hydroxide complexes to free cations. As a result, the HMs were more likely to be separated from the RFMs. Moreover, the RFMs were more prone to disaggregation under acidic conditions, which led to destruction of the RFM microstructure and rerelease of the HMs fixed in the microstructure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2024, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103485, "DOI": "10.1016/j.eti.2023.103485", "DOI Link": "http://dx.doi.org/10.1016/j.eti.2023.103485", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001145912100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ueda, H; García-Fernández, M; Agrestini, S; Romao, CP; van den Brink, J; Spaldin, NA; Zhou, KJ; Staub, U", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ueda, Hiroki; Garcia-Fernulldez, Mirian; Agrestini, Stefano; Romao, Carl P.; van den Brink, Jeroen; Spaldin, Nicola A.; Zhou, Ke-Jin; Staub, Urs", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral phonons in quartz probed by X-rays", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The concept of chirality is of great relevance in nature, from chiral molecules such as sugar to parity transformations in particle physics. In condensed matter physics, recent studies have demonstrated chiral fermions and their relevance in emergent phenomena closely related to topology(1-3). The experimental verification of chiral phonons (bosons) remains challenging, however, despite their expected strong impact on fundamental physical properties(4-6). Here we show experimental proof of chiral phonons using resonullt inelastic X-ray scattering with circularly polarized X-rays. Using the prototypical chiral material quartz, we demonstrate that circularly polarized X-rays, which are intrinsically chiral, couple to chiral phonons at specific positions in reciprocal space, allowing us to determine the chiral dispersion of the lattice modes. Our experimental proof of chiral phonons demonstrates a new degree of freedom in condensed matter that is both of fundamental importance and opens the door to exploration of new emergent phenomena based on chiral bosons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2023, "Volume": 618, "Issue": 7967, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 946, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06016-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06016-5", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001005804900012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XX; Schwemmer, T; Müller, T; Consiglio, A; Sangiovanni, G; Di Sante, D; Iqbal, Y; Hanke, W; Schnyder, AP; Denner, MM; Fischer, MH; Neupert, T; Thomale, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xianxin; Schwemmer, Tilman; Mueller, Tobias; Consiglio, Armando; Sangiovanni, Giorgio; Di Sante, Domenico; Iqbal, Yasir; Hanke, Werner; Schnyder, Andreas P.; Denner, M. Michael; Fischer, Mark H.; Neupert, Titus; Thomale, Ronny", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nature of Unconventional Pairing in the Kagome Superconductors AV3Sb5 (A = K, Rb, Cs)", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of AV(3)Sb(5) (A = K, Rb, Cs) has uncovered an intriguing arena for exotic Fermi surface instabilities in a kagome metal. Among them, superconductivity is found in the vicinity of multiple van Hove singularities, exhibiting indications of unconventional pairing. We show that the sublattice interference mechanism is central to understanding the formation of superconductivity in a kagome metal. Starting from an appropriately chosen minimal tight-binding model with multiple van Hove singularities close to the Fermi level for AV(3)Sb(5), we provide a random phase approximation analysis of superconducting instabilities. Nonlocal Coulomb repulsion, the sublattice profile of the van Hove bands, and the interaction strength turn out to be the crucial parameters to determine the preferred pairing symmetry. Implications for potentially topological surface states are discussed, along with a proposal for additional measurements to pin down the nature of superconductivity in AV(3)Sb(5).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 183, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2021, "Volume": 127, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 177001, "DOI": "10.1103/PhysRevLett.127.177001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.127.177001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000748548600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Paul, DR; Gautam, S; Panchal, P; Nehra, SP; Choudhary, P; Sharma, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Paul, Devina Rattan; Gautam, Shubham; Panchal, Priyanka; Nehra, Satya Pal; Choudhary, Pratibha; Sharma, Anshu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ZnO-Modified g-C3N4: A Potential Photocatalyst for Environmental Application", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar energy-driven practices using semiconducting materials is an ideal approach toward wastewater remediation. In order to attain a superior photocatalyst, a composite of g-C3N4 and ZnO (GCN-ZnO) has been prepared by one-step thermal polymerization of urea and zinc carbonate basic dihydrate [ZnNO3](2).[Zn(OH)(2)](3). The GCN-ZnO0.4 sample showed an evolved morphology, increased surface area (116 m(2) g(-1)) better visible light absorption ability, and reduced band gap in comparison to GCN-pure. The GCN-ZnO0.4 sample also showed enhanced adsorption and photocatalytic activity performance, resulting in an increased reaction rate value up to 3 times that of GCN-pure, which was attributed to the phenomenon of better separation of photogenerated charge carriers resulting because of heterojunction development among interfaces of GCN-pure and ZnO. In addition, the GCN-ZnO0.4 sample showed a decent stability for four cyclic runs and established its potential use for abatement of organic wastewater pollutants in comparison to GCN-pure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 241, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2020, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3828, "End Page": 3838, "Article Number": null, "DOI": "10.1021/acsomega.9b02688", "DOI Link": "http://dx.doi.org/10.1021/acsomega.9b02688", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518851600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zinatloo-Ajabshir, S; Ghasemian, N; Mousavi-Kamazani, M; Salavati-Niasari, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zinatloo-Ajabshir, Sahar; Ghasemian, Naser; Mousavi-Kamazani, Mehdi; Salavati-Niasari, Masoud", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of zirconia on improving NOx reduction efficiency of Nd2Zr2O7 nullostructure fabricated by a new, facile and green sonochemical approach", "Source Title": "ULTRASONICS SONOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here, we offer an easy and eco-friendly sonochemical pathway to fabricate Nd2Zr2O7 nullostructures and nullocomposites with the help of Morus nigra extract as a new kind of capping agent. For the first time, the performance of Nd2Zr2O7-based ceramic nullostructure materials has been compared upon NOx abatement. Diverse kinds of techniques have been employed to specify purity and check the attributes of the fabricated Nd2Zr2O7-based nullostructurs by Moms nigra extract. Outcomes revealed the successful fabrication of Nd2Zr2O7 nullostructures and nullocomposites applying Moms nigra extract through sonochemical pathway. All nullostructured samples have been fabricated through ultrasonic probe with power of 60 W (18 KHz). Further, the fabricated Nd2Zr2O7-based ceramic nullostructure materials can be applied as potential nullocatalysts with appropriate performance for propane-SCR-NOx, since the conversion of NOx to N-2 for the best sample (Nd2Zr2O7-ZrO2 nullocomposite) was 70%. In addition, in case of Nd2Zr2O7-ZrO2 nullocomposite, the outlet quantity of CO as an unfavorable and unavoidable product was lower than the rest.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 143, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 71, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105376, "DOI": "10.1016/j.ultsonch.2020.105376", "DOI Link": "http://dx.doi.org/10.1016/j.ultsonch.2020.105376", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Acoustics; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000605591000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Czajczynska, D; Anguilano, L; Ghazal, H; Krzyzynska, R; Reynolds, AJ; Spencer, N; Jouhara, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Czajczynska, D.; Anguilano, L.; Ghazal, H.; Krzyzynska, R.; Reynolds, A. J.; Spencer, N.; Jouhara, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Potential of pyrolysis processes in the waste management sector", "Source Title": "THERMAL SCIENCE AND ENGINEERING PROGRESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fundamentals of pyrolysis, its latest developments, the different conditions of the process and its residues are of great importance in evaluating the applicability of the pyrolysis process within the waste management sector and in waste treatment. In particular the types of residue and their further use or treatment is of extreme interest as they could become the source of secondary raw materials or be used for energy generation in waste treatments. The main area of focus of this paper is the investigation of the link between the pyrolysis conditions, the chemical and mineralogical composition of their products and the benefits of pyrolysis in the waste management sector. More specifically the paper covers the fast, intermediate and slow pyrolysis of organic waste and mixtures of inorganic and organic waste from households. The influence of catalysts during fast pyrolysis on the product yield and composition is not being considered in this review. (C) 2017 Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 326, "Times Cited, All Databases": 344, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2017, "Volume": 3, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 171, "End Page": 197, "Article Number": null, "DOI": "10.1016/j.tsep.2017.06.003", "DOI Link": "http://dx.doi.org/10.1016/j.tsep.2017.06.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000639434700018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ma, YF; Sun, LL; Zhang, JJ; Chiang, CL; Pan, JJ; Wang, XY; Kwak, KJ; Li, H; Zhao, RL; Rima, XY; Zhang, C; Zhang, AA; Liu, YT; He, ZR; Hansford, D; Reategui, E; Liu, CS; Lee, AS; Yuan, Y; Lee, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ma, Yifan; Sun, Lili; Zhang, Jingjing; Chiang, Chi-ling; Pan, Junjie; Wang, Xinyu; Kwak, Kwang Joo; Li, Hong; Zhao, Renliang; Rima, Xilal Y.; Zhang, Chi; Zhang, Anull; Liu, Yutong; He, Zirui; Hansford, Derek; Reategui, Eduardo; Liu, Changsheng; Lee, Andrew S.; Yuan, Yuan; Lee, Ly James", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exosomal mRNAs for Angiogenic-Osteogenic Coupled Bone Repair", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Regenerative medicine in tissue engineering often relies on stem cells and specific growth factors at a supraphysiological dose. These approaches are costly and may cause severe side effects. Herein, therapeutic small extracellular vesicles (t-sEVs) endogenously loaded with a cocktail of human vascular endothelial growth factor A (VEGF-A) and human bone morphogenetic protein 2 (BMP-2) mRNAs within a customized injectable PEGylated poly (glycerol sebacate) acrylate (PEGS-A) hydrogel for bone regeneration in rats with challenging femur critical-size defects are introduced. Abundant t-sEVs are produced by a facile cellular nulloelectroporation system based on a commercially available track-etched membrane (TM-nulloEP) to deliver plasmid DNAs to human adipose-derived mesenchymal stem cells (hAdMSCs). Upregulated microRNAs associated with the therapeutic mRNAs are enriched in t-sEVs for enhanced angiogenic-osteogenic regeneration. Localized and controlled release of t-sEVs within the PEGS-A hydrogel leads to the retention of therapeutics in the defect site for highly efficient bone regeneration with minimal low accumulation in other organs. This study describes an easily scalable and cost-effective method to produce abundant therapeutic small extracellular vesicles (t-sEVs) carrying a cocktail of functional mRNAs (VEGF-A and BMP-2) within a customized injectable PEGylated poly (glycerol sebacate) acrylate (PEGS-A) hydrogel cage for coupling bone regeneration in rats that have challenging femur critical-size defects.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 46, "Times Cited, All Databases": 46, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2023, "Volume": 10, "Issue": 33, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202302622", "DOI Link": "http://dx.doi.org/10.1002/advs.202302622", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001084204200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, ZW; Shi, T; Geng, GZ; Li, JJ; Deng, ZL; Kivshar, Y; Li, XP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Ziwei; Shi, Tan; Geng, Guangzhou; Li, Junjie; Deng, Zi-Lan; Kivshar, Yuri; Li, Xiangping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-band polarized upconversion photoluminescence enhanced by resonullt dielectric metasurfaces", "Source Title": "ELIGHT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lanthanide-doped upconversion nulloparticles emerged recently as an attractive material platform underpinning a broad range of innovative applications such as optical cryptography, luminescent probes, and lasing. However, the intricate 4f-associated electronic transition in upconversion nulloparticles leads only to a weak photoluminescence intensity and unpolarized emission, hindering many applications that demand ultrabright and polarized light sources. Here, we present an effective strategy for achieving ultrabright and dual-band polarized upconversion photoluminescence. We employ resonullt dielectric metasurfaces supporting high-quality resonullt modes at dual upconversion bands enabling two-order-of-magnitude amplification of upconversion emissions. We demonstrate that dual-band resonullces can be selectively switched on polarization, endowing cross-polarization controlled upconversion luminescence with ultra-high degrees of polarization, reaching approximately 0.86 and 0.91 at dual emission wavelengths of 540 and 660 nm, respectively. Our strategy offers an effective approach for enhancing photon upconversion processes paving the way towards efficient low-threshold polarization upconversion lasers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21, "DOI": "10.1186/s43593-023-00054-2", "DOI Link": "http://dx.doi.org/10.1186/s43593-023-00054-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001127180700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Allaire, G; Dapogny, C; Delgado, G; Michailidis, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Allaire, G.; Dapogny, C.; Delgado, G.; Michailidis, G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MULTI-PHASE STRUCTURAL OPTIMIZATION VIA A LEVEL SET METHOD", "Source Title": "ESAIM-CONTROL OPTIMISATION AND CALCULUS OF VARIATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We consider the optimal distribution of several elastic materials in a fixed working domain. In order to optimize both the geometry and topology of the mixture we rely on the level set method for the description of the interfaces between the different phases. We discuss various approaches, based on Hadamard method of boundary variations, for computing shape derivatives which are the key ingredients for a steepest descent algorithm. The shape gradient obtained for a sharp interface involves jump of discontinuous quantities at the interface which are difficult to numerically evaluate. Therefore we suggest an alternative smoothed interface approach which yields more convenient shape derivatives. We rely on the signed distance function and we enforce a fixed width of the transition layer around the interface ( a crucial property in order to avoid increasing grey regions of fictitious materials). It turns out that the optimization of a diffuse interface has its own interest in material science, for example to optimize functionally graded materials. Several 2-d examples of compliance minimization are numerically tested which allow us to compare the shape derivatives obtained in the sharp or smoothed interface cases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2014, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 576, "End Page": 611, "Article Number": null, "DOI": "10.1051/cocv/2013076", "DOI Link": "http://dx.doi.org/10.1051/cocv/2013076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Automation & Control Systems; Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000334363200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, YR; Xiao, DD; Wu, S; Da'as, EH; Gu, YY; Bi, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Yanru; Xiao, Dongdong; Wu, Shuai; Da'as, Eman Husni; Gu, Yueyuan; Bi, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A real proton-conductive, robust, and cobalt-free cathode for proton-conducting solid oxide fuel cells with exceptional performance", "Source Title": "SUSMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of proton, oxygen-ion, and electron mixed conducting materials, known as triple-conduction materials, as cathodes for proton-conducting solid oxide fuel cells (H-SOFCs) is highly desired because they can increase fuel cell performance by extending the reaction active area. Although oxygen-ion and electron conductions can be measured directly, proton conduction in these oxides is usually estimated indirectly. Because of the instability of cathode materials in a reducing environment, direct measurement of proton conduction in cathode oxide is difficult. The La0.8Sr0.2Sc0.5Fe0.5O3-delta (LSSF) cathode material is proposed for H-SOFCs in this study, which can survive in an H-2-containing atmosphere, allowing measurement of proton conduction in LSSF by hydrogen permeation technology. Furthermore, LSSF is discovered to be a unique proton and electron mixed-conductive material with limited oxygen diffusion capability that is specifically designed for H-SOFCs. The LSSF is an appealing cathode choice for H-SOFCs due to its outstanding CO2 tolerance and matched thermal expansion coefficient, producing a record-high performance of 2032 mW cm(-2) at 700 degrees C and good long-term stability under operational conditions. The current study reveals that a new type of proton-electron mixed conducting cathode can provide promising performance for H-SOFCs, opening the way for developing high-performance cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 70, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 697, "End Page": 708, "Article Number": null, "DOI": "10.1002/sus2.156", "DOI Link": "http://dx.doi.org/10.1002/sus2.156", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001114680600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yada, T; Abe, M; Okada, T; Nakato, A; Yogata, K; Miyazaki, A; Hatakeda, K; Kumagai, K; Nishimura, M; Hitomi, Y; Soejima, H; Yoshitake, M; Iwamae, A; Furuya, S; Uesugi, M; Karouji, Y; Usui, T; Hayashi, T; Yamamoto, D; Fukai, R; Sugita, S; Cho, Y; Yumoto, K; Yabe, Y; Bibring, JP; Pilorget, C; Hamm, V; Brunetto, R; Riu, L; Lourit, L; Loizeau, D; Lequertier, G; Moussi-Soffys, A; Tachibana, S; Sawada, H; Okazaki, R; Takano, Y; Sakamoto, K; Miura, YN; Yano, H; Ireland, TR; Yamada, T; Fujimoto, M; Kitazato, K; Namiki, N; Arakawa, M; Hirata, N; Yurimoto, H; Nakamura, T; Noguchi, T; Yabuta, H; Naraoka, H; Ito, M; Nakamura, E; Uesugi, K; Kobayashi, K; Michikami, T; Kikuchi, H; Hirata, N; Ishihara, Y; Matsumoto, K; Noda, H; Noguchi, R; Shimaki, Y; Shirai, K; Ogawa, K; Wada, K; Senshu, H; Yamamoto, Y; Morota, T; Honda, R; Honda, C; Yokota, Y; Matsuoka, M; Sakatani, N; Tatsumi, E; Miura, A; Yamada, M; Fujii, A; Hirose, C; Hosoda, S; Ikeda, H; Iwata, T; Kikuchi, S; Mimasu, Y; Mori, O; Ogawa, N; Ono, G; Shimada, T; Soldini, S; Takahashi, T; Takei, Y; Takeuchi, H; Tsukizaki, R; Yoshikawa, K; Terui, F; Nakazawa, S; Tanaka, S; Saiki, T; Yoshikawa, M; Watanabe, S; Tsuda, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yada, Toru; Abe, Masanao; Okada, Tatsuaki; Nakato, Aiko; Yogata, Kasumi; Miyazaki, Akiko; Hatakeda, Kentaro; Kumagai, Kazuya; Nishimura, Masahiro; Hitomi, Yuya; Soejima, Hiromichi; Yoshitake, Miwa; Iwamae, Ayako; Furuya, Shizuho; Uesugi, Masayuki; Karouji, Yuzuru; Usui, Tomohiro; Hayashi, Tasuku; Yamamoto, Daiki; Fukai, Ryota; Sugita, Seiji; Cho, Yuichiro; Yumoto, Koki; Yabe, Yuna; Bibring, Jean-Pierre; Pilorget, Cedric; Hamm, Vincent; Brunetto, Rosario; Riu, Lucie; Lourit, Lionel; Loizeau, Damien; Lequertier, Guillaume; Moussi-Soffys, Aurelie; Tachibana, Shogo; Sawada, Hirotaka; Okazaki, Ryuji; Takano, Yoshinori; Sakamoto, Kanako; Miura, Yayoi N.; Yano, Hajime; Ireland, Trevor R.; Yamada, Tetsuya; Fujimoto, Masaki; Kitazato, Kohei; Namiki, Noriyuki; Arakawa, Masahiko; Hirata, Naru; Yurimoto, Hisayoshi; Nakamura, Tomoki; Noguchi, Takaaki; Yabuta, Hikaru; Naraoka, Hiroshi; Ito, Motoo; Nakamura, Eizo; Uesugi, Kentaro; Kobayashi, Katsura; Michikami, Tatsuhiro; Kikuchi, Hiroshi; Hirata, Naoyuki; Ishihara, Yoshiaki; Matsumoto, Koji; Noda, Hirotomo; Noguchi, Rina; Shimaki, Yuri; Shirai, Kei; Ogawa, Kazunori; Wada, Koji; Senshu, Hiroki; Yamamoto, Yukio; Morota, Tomokatsu; Honda, Rie; Honda, Chikatoshi; Yokota, Yasuhiro; Matsuoka, Moe; Sakatani, Naoya; Tatsumi, Eri; Miura, Akira; Yamada, Manabu; Fujii, Atsushi; Hirose, Chikako; Hosoda, Satoshi; Ikeda, Hitoshi; Iwata, Takahiro; Kikuchi, Shota; Mimasu, Yuya; Mori, Osamu; Ogawa, Naoko; Ono, Go; Shimada, Takanobu; Soldini, Stefania; Takahashi, Tadateru; Takei, Yuto; Takeuchi, Hiroshi; Tsukizaki, Ryudo; Yoshikawa, Kent; Terui, Fuyuto; Nakazawa, Satoru; Tanaka, Satoshi; Saiki, Takanao; Yoshikawa, Makoto; Watanabe, Sei-ichiro; Tsuda, Yuichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preliminary analysis of the Hayabusa2 samples returned from C-type asteroid Ryugu", "Source Title": "NATURE ASTRONOMY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "C-type asteroids(1) are considered to be primitive small Solar System bodies enriched in water and organics, providing clues to the origin and evolution of the Solar System and the building blocks of life. C-type asteroid 162173 Ryugu has been characterized by remote sensing(2-7) and on-asteroid measurements(8,9) with Hayabusa2 (ref. (10)). However, the ground truth provided by laboratory analysis of returned samples is invaluable to determine the fine properties of asteroids and other planetary bodies. We report preliminary results of analyses on returned samples from Ryugu of the particle size distribution, density and porosity, spectral properties and textural properties, and the results of a search for Ca-Al-rich inclusions (CAIs) and chondrules. The bulk sample mainly consists of rugged and smooth particles of millimetre to submillimetre size, confirming that the physical and chemical properties were not altered during the return from the asteroid. The power index of its size distribution is shallower than that of the surface boulder observed on Ryugu(11), indicating differences in the returned Ryugu samples. The average of the estimated bulk densities of Ryugu sample particles is 1,282 +/- 231 kg m(-3), which is lower than that of meteorites(12), suggesting a high microporosity down to the millimetre scale, extending centimetre-scale estimates from thermal measurements(5,9). The extremely dark optical to near-infrared reflectance and spectral profile with weak absorptions at 2.7 and 3.4 mu m imply a carbonaceous composition with indigenous aqueous alteration, matching the global average of Ryugu(3,4) and confirming that the sample is representative of the asteroid. Together with the absence of submillimetre CAIs and chondrules, these features indicate that Ryugu is most similar to CI chondrites but has lower albedo, higher porosity and more fragile characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 6, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 214, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41550-021-01550-6", "DOI Link": "http://dx.doi.org/10.1038/s41550-021-01550-6", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Astronomy & Astrophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733425200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sekine, A; Nomura, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sekine, Akihiko; Nomura, Kentaro", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Axion electrodynamics in topological materials", "Source Title": "JOURNAL OF APPLIED PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the intriguing properties characteristic to three-dimensional topological materials is the topological magnetoelectric phenomena arising from a topological term called the theta term. Such magnetoelectric phenomena are often termed the axion electrodynamics since the theta term has exactly the same form as the action describing the coupling between a hypothetical elementary particle, axion, and a photon. The axion was proposed about 40 years ago to solve the so-called strong CP problem in quantum chromodynamics and is now considered a candidate for dark matter. In this Tutorial, we overview theoretical and experimental studies on the axion electrodynamics in three-dimensional topological materials. Starting from the topological magnetoelectric effect in three-dimensional time-reversal invariant topological insulators, we describe the basic properties of static and dynamical axion insulators whose realizations require magnetic orderings. We also discuss the electromagnetic responses of Weyl semimetals with a focus on the chiral anomaly. We extend the concept of the axion electrodynamics in condensed matter to topological superconductors, whose responses to external fields can be described by a gravitational topological term analogous to the theta term.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 14", "Publication Year": 2021, "Volume": 129, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 141101, "DOI": "10.1063/5.0038804", "DOI Link": "http://dx.doi.org/10.1063/5.0038804", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000639965500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghalambaz, M; Zadeh, SMH; Mehryan, SAM; Pop, I; Wen, DS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghalambaz, Mohammad; Zadeh, Seyed Mohsen Hashem; Mehryan, S. A. M.; Pop, Ioan; Wen, Dongsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of melting behavior of PCMs in a cavity subject to a non-uniform magnetic field using a moving grid technique", "Source Title": "APPLIED MATHEMATICAL MODELLING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Melting flow and heat transfer of electrically conductive phase change materials subjecting to a non-uniform magnetic field are addressed in a square enclosure. The top and bottom walls of the cavity are adiabatic, and the sidewalls are isothermal at different temperatures. The temperature of the hot wall is higher than the fusion temperature of PCM (T-f), and the cold wall is at the fusion temperature or lower. At the initial time, the cavity is filled with a solid saturated PCM. In the vicinity to the hot wall, there is an external line-source magnet, inducing a magnetic field. The location of the magnetic source (Y-0) can be changed along the hot wall. The cavity domain is divided into two parts of the liquid domain and the solid domain. The moving grid method is utilized to track the phase change interface at the exact fusion temperature of T-f. The governing equations for continuity, flow and heat transfer associated with the Arbitrary Lagrangian-Eulerian (ALE) moving mesh technique are solved using the finite element method. The results are investigated for the melting behavior of PCM by the study of Hartmann number (0 <= Ha <= 50) and the location of the magnetic source (0 <= Y-0 <= 1). Outcomes show that the effect of the magnetic field on the melting behavior of PCM is negligible at the initial stages of the melting (Fo < 1.15). However, after the initial stages of the melting, the effect of the presence of a magnetic field becomes significant. Moreover, the location of the magnetic source induces a feeble effect on the melting front at the initial melting stages, but its effect on the shape of the melting front increases by the increase of the non-dimensional time. The location of the magnetic source also significantly affects the streamlines patterns. Changing the position of the magnetic source from the bottom of the cavity (Y-0 = 0.2) to the almost middle of the cavity (Y-0 = 0.6) would decrease the required non-dimensional time of full melting from Fo = 10.4 to Fo = 9.0. (C) 2019 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 77, "Issue": null, "Part Number": 2, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1936, "End Page": 1953, "Article Number": null, "DOI": "10.1016/j.apm.2019.09.015", "DOI Link": "http://dx.doi.org/10.1016/j.apm.2019.09.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503323500053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Singh, B; Kumar, I; Saxena, KK; Mohammed, KA; Khan, MI; Ben Moussa, S; Abdullaev, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Singh, Bharat; Kumar, Indradeep; Saxena, Kuldeep K.; Mohammed, Kahtan A.; Khan, M. Ijaz; Ben Moussa, Sana; Abdullaev, Sherzod Shukhratovich", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A future prospects and current scenario of aluminium metal matrix composites characteristics", "Source Title": "ALEXANDRIA ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper provides a synergistic review of the current scenario and future prospects of aluminum metal matrix composites (AMMCs). AMMCs are advanced materials that have garnered significant attention in recent years due to their unique characteristics, including high strength, low density, and excellent wear resistance. This review covers various aspects of AMMCs, including processing techniques, mechanical and physical properties, microstructural features, and applications. The review begins with an overview of different processing techniques for AMMCs, including stir casting, powder metallurgy, and infiltration methods. It then discusses the mechanical and physical properties of AMMCs, such as tensile strength, hardness, and thermal conductivity, and how these properties are influenced by various factors such as reinforcement type, size, and volume fraction. Furthermore, the microstructural features of AMMCs, including the distribution of reinforcements, are discussed in detail. The review also highlights the potential applications of AMMCs in various industries such as aerospace, automotive, and electronics. Finally, the review concludes by discussing the current scenario and future prospects of AMMCs. It highlights the challenges that need to be addressed to enhance the performance of AMMCs and the potential areas of research that could lead to the development of advanced AMMCs with superior properties. Overall, this review provides a comprehensive overview of the current status and future prospects of AMMCs and highlights the importance of continued research and development in this field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2023, "Volume": 76, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 17, "Article Number": null, "DOI": "10.1016/j.aej.2023.06.028", "DOI Link": "http://dx.doi.org/10.1016/j.aej.2023.06.028", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001020133700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khorasani, M; Ghasemi, A; Leary, M; Sharabian, E; Cordova, L; Gibson, I; Downing, D; Bateman, S; Brandt, M; Rolfe, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khorasani, Mahyar; Ghasemi, AmirHossein; Leary, Martin; Sharabian, Elmira; Cordova, Laura; Gibson, Ian; Downing, David; Bateman, Stuart; Brandt, Milan; Rolfe, Bernard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The effect of absorption ratio on meltpool features in laser-based powder bed fusion of IN718", "Source Title": "OPTICS AND LASER TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The purpose of this research is to develop a hybrid experimental and computational model to estimate the absorption of the laser for Laser-Based Powder Bed Fusion (LB-PBF) of IN718. The research also aims to find an underlying knowledge on the effect of absorption ratio on meltpool morphology. This model helps to improve the accuracy of the prediction of the meltpool morphology and the rheology of the melt tracks as well as the temperature-related phenomena in the process. In this paper, two test sets for the initial test with constant and dynamic/(process parameters dependent) absorption ratios were simulated. Melt tracks with different process parameters are printed and simulated from low to high energy density. Then, the Absorption Ratio (AR) is changed for each simulation until the same meltpool depth as the experimental results is obtained. In the next step, the temperature of the meltpool in the interaction area of the laser and material is measured from the performed simulations. Based on the obtained temperature and process parameters, a mathematical model is developed to estimate the absorption ratio in different conditions. The model is validated in hybrid computational and experimental conditions. The investigation provides the first model to calculate the absorption ratio in LB-PBF based on the temperature of the meltpool and process parameters. Results show that the developed model significantly enhances the accuracy of estimating meltpool features such as temperature, rheological and thermophysical properties of the material in the melting state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 77, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 153, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108263, "DOI": "10.1016/j.optlastec.2022.108263", "DOI Link": "http://dx.doi.org/10.1016/j.optlastec.2022.108263", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799239800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ketkaew, R; Tantirungrotechai, Y; Harding, P; Chastanet, G; Guionneau, P; Marchivie, M; Harding, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ketkaew, Rangsiman; Tantirungrotechai, Yuthana; Harding, Phimphaka; Chastanet, Guillaume; Guionneau, Philippe; Marchivie, Mathieu; Harding, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "OctaDist: a tool for calculating distortion parameters in spin crossover and coordination complexes", "Source Title": "DALTON TRANSACTIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "OctaDist is an interactive and visual program for determination of structural distortion in octahedral coordination complexes such as spin crossover complexes, single-ion magnets, perovskites or metal-organic frameworks. OctaDist computes the octahedral distortion parameters initially designed in the context of the spin-crossover phenomenon and denoted zeta, Sigma, and Theta from standard structural files. The program also provides additional tools for molecular analyses and visualization. It emphasizes performance, flexibility, ease of use, application programming interface (API) consistency, and clear documentation. The modules and classes in OctaDist can be easily customized to include new algorithms or analytical tools. OctaDist is cross-platform supported for modern operating systems and is available as open-source distributed under the GNU General Public License version 3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 196, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2021, "Volume": 50, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1086, "End Page": 1096, "Article Number": null, "DOI": "10.1039/d0dt03988h", "DOI Link": "http://dx.doi.org/10.1039/d0dt03988h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612184500035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aakeroy, CB; Bryce, DL; Desiraju, G; Frontera, A; Legon, AC; Nicotra, F; Rissanen, K; Scheiner, S; Terraneo, G; Metrangolo, P; Resnati, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aakeroy, Christer B.; Bryce, David L.; Desiraju, Gautam; Frontera, Antonio; Legon, Anthony C.; Nicotra, Francesco; Rissanen, Kari; Scheiner, Steve; Terraneo, Giancarlo; Metrangolo, Pierangelo; Resnati, Giuseppe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Definition of the chalcogen bond (IUPAC Recommendations 2019)", "Source Title": "PURE AND APPLIED CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This recommendation proposes a definition for the term chalcogen bond; it is recommended the term is used to designate the specific subset of inter- and intramolecular interactions formed by chalcogen atoms wherein the Group 16 element is the electrophilic site.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2019, "Volume": 91, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1889, "End Page": 1892, "Article Number": null, "DOI": "10.1515/pac-2018-0713", "DOI Link": "http://dx.doi.org/10.1515/pac-2018-0713", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496795300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, XY; Guo, YJ; Shan, WR; Yuan, YQ; Zhang, CR; Chen, SS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Xin-Yi; Guo, Yong-Jiang; Shan, Wen-Rui; Yuan, Yu-Qiang; Zhang, Chen-Rong; Chen, Su-Su", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magneto-optical/ferromagnetic-material computation: Backlund transformations, bilinear forms and N solitons for a generalized (3+1)-dimensional variable-coefficient modified Kadomtsev-Petviashvili system", "Source Title": "APPLIED MATHEMATICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Of current interest, magneto-optics deals with the phenomena associated with magnetic effects on matter as it emits light, having the potential applications in computer data-storage and waveguides, while ferromagnetic materials are the ones displaying ferromagnetism, such as the various forms of iron, steel, cobalt, nickel, and their alloys. In this paper, in magneto-optics, ferromagnetism, fluid mechanics and plasma physics, we investigate a generalized (3+1)-dimensional variable-coefficient modified Kadomtsev-Petviashvili system for the electromagnetic waves in a ferromagnetic material, or water waves, or dust-acoustic/ion-acoustic/dustion-acoustic waves in a plasma. Special cases of the system in those fields are listed out, such as one special case in magneto-optics, which describes the electromagnetic waves in an isotropic charge-free ferromagnetic thin film with the potential application in magneto-optic recording. With symbolic computation, we work out (1) two sets of the variable-coefficient-dependent auto-Backlund transformations along with some solitonic features, (2) the variable-coefficient-dependent bilinear forms with the Hirota method and (3) two branches of the variable-coefficient-dependent N-soliton solutions with N being a positive integer. Relevant constraints on the variable coefficients are presented. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 111, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106627, "DOI": "10.1016/j.aml.2020.106627", "DOI Link": "http://dx.doi.org/10.1016/j.aml.2020.106627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571465000044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, KX; Ren, KX; Wang, QH; Lin, YX; Ma, FC; Sun, C; Li, YW; Zhao, XS; Lai, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Kaixuan; Ren, Kaixin; Wang, Qinghong; Lin, Yuxiao; Ma, Fengcan; Sun, Chuang; Li, Yinwei; Zhao, Xinsheng; Lai, Chao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ construction of zinc-rich polymeric solid-electrolyte interface for high-performance zinc anode", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With their excellent reliability and environmental friendliness, zinc-ion batteries (ZIBs) are regarded as potential energy storage technologies. Unfortunately, their poor cycling durability and low Coulombic effectiveness (CE), driven by dendritic growth and surface passivation on the Zn anode, severely restrict their commercialization. Herein, we describe the in situ construction of a Zn-rich polymeric solid-electrolyte interface (SEI) using polyacrylic acid (PAA) as an electrolyte additive. On the one hand, the PAA SEI layer offers evenly distributed nucleation sites and promotes ion transport, hence suppressing dendrite growth. On the other hand, the SEI layer prevents direct contact between the Zn foil and the electrolyte, thus inhibiting side reactions. Additionally, the robust coordination of PAA with Zn2} and the SEI layer's good adherence to the Zn foil provide long-term protection to the Zn anode. As a result, symmetric cells and Zn/V2O5 cells all deliver prolonged cycle life and superior electrochemical efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100153, "DOI": "10.1016/j.esci.2023.100153", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100153", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078651700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Agar, O; Sayyed, MI; Akman, E; Tekin, HO; Kaçal, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Agar, O.; Sayyed, M., I; Akman, E.; Tekin, H. O.; Kacal, M. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An extensive investigation on gamma ray shielding features of Pd/Ag-based alloys", "Source Title": "NUCLEAR ENGINEERING AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A comprehensive study of photon interaction features has been made for some alloys containing Pd and Ag content to evaluate its possible use as alternative gamma radiations shielding material. The mass attenuation coefficient (mu/rho) of the present alloys was measured at various photon energies between 81 keV-1333 keV utilizing HPGe detector. The measured mu/rho values were compared to those of theoretical and computational (MCNPX code) results. The results exhibited that the mu/rho values of the studied alloys are in the same line with results of WinXCOM software and MCNPX code results at all energies. Moreover, Pd75/Ag25 alloy sample has the maximum radiation protection efficiency (about 53% at 81 keV) and lowest half value layer, which shows that Pd75/Ag25 has superior gamma radiation shielding performance among the other compared alloys. (C) 2018 Korean Nuclear Society, Published by Elsevier Korea LLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 51, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 853, "End Page": 859, "Article Number": null, "DOI": "10.1016/j.net.2018.12.014", "DOI Link": "http://dx.doi.org/10.1016/j.net.2018.12.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Nuclear Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462778100026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rajan, A; Sharma, M; Sahu, NK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rajan, Arunima; Sharma, Madhulika; Sahu, Niroj Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Assessing magnetic and inductive thermal properties of various surfactants functionalised Fe3O4 nulloparticles for hyperthermia", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work reports the fabrication of magnetite (Fe3O4) nulloparticles (NPs) coated with various biocompatible surfactants such as glutamic acid (GA), citric acid (CA), polyethylene glycol (PEG), polyvinylpyrrolidine (PVP), ethylene diamine (EDA) and cetyl-trimethyl ammonium bromide (CTAB) via co-precipitation method and their comparative inductive heating ability for hyperthermia (HT) applications. X-ray and electron diffraction analyses validated the formation of well crystallined inverse spinel structured Fe3O4 NPs (crystallite size of similar to 8-10 nm). Magnetic studies confirmed the superparamagnetic (SPM) behaviour for all the NPs with substantial magnetisation (63-68 emu/g) and enhanced magnetic susceptibility is attributed to the greater number of occupations of Fe2+ ions in the lattice as revealed by X-ray photoelectron spectroscopy (XPS). Moreover, distinctive heating response (specific absorption rate, SAR from 130 to 44 W/g) of NPs with similar size and magnetisation is observed. The present study was successful in establishing a direct correlation between relaxation time (similar to 9.42-15.92 ns) and heating efficiency of each surface functionalised NPs. Moreover, heat dissipated in different surface grafted NPs is found to be dependent on magnetic susceptibility, magnetic anisotropy and magnetic relaxation time. These results open very promising avenues to design surface functionalised magnetite NPs for effective HT applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15045, "DOI": "10.1038/s41598-020-71703-6", "DOI Link": "http://dx.doi.org/10.1038/s41598-020-71703-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577216300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krishnull, S; Koning, V; de Groot, MT; de Groot, A; Mendoza, PG; Junginger, M; Kramer, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krishnull, Subramani; Koning, Vinzenz; de Groot, Matheus Theodorus; de Groot, Arend; Mendoza, Paola Granados; Junginger, Martin; Kramer, Gert Jan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Present and future cost of alkaline and PEM electrolyser stacks", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use complementary bottom-up and top-down approaches to assess the current cost of AE and PEM stacks and how the costs are expected to come down by 2030. The total AE and PEM stack cost reduce from a range of 242-388 euro/kW and 384-1071 euro/kW in 2020 to 52-79 euro/kW and 63-234 euro/kW in 2030 respectively. The main drivers of these cost reductions are an increased current density and a reduction and/or replacement of expensive materials with cheaper alternatives. To a lesser extent, manufacturing and labor costs reduction is expected due to mass manufacturing at a GW scale. The total cost decrease is less prominent for AE than PEM due to AE's maturity. The uncertainty range for PEM stacks is due to the low TRL associated with the advanced design PEM stack.& COPY; 2023 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. This is an open access article under the CC BY license (http://creativecommons.org/ licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2023, "Volume": 48, "Issue": 83, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 32313, "End Page": 32330, "Article Number": null, "DOI": "10.1016/j.ijhydene.2023.05.031", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2023.05.031", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001072107500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shan, PF; Wang, NN; Zheng, XQ; Qiu, QZ; Peng, YY; Cheng, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shan, Pengfei; Wang, Ningning; Zheng, Xiquan; Qiu, Qingzheng; Peng, Yingying; Cheng, Jinguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pressure-Induced Color Change in the Lutetium Dihydride LuH2", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lutetium dihydride LuH2 is stable at ambient conditions. Here we show that its color undergoes sequential changes from dark blue at ambient pressure to pink at similar to 2.2 GPa and then to bright red at similar to 4 GPa upon compression in a diamond anvil cell. Such a pressure-induced color change in LuH2 is reversible and it is very similar to that recently reported in the N-doped lutetium hydride [Nature 615, 244 (2023)]. However, our preliminary resistance measurements on LuH2 under pressures up to similar to 7 GPa evidenced no superconductivity down to 1.5 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 44, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2023, "Volume": 40, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 46101, "DOI": "10.1088/0256-307X/40/4/046101", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/40/4/046101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955498300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Choudhary, K; Garrity, KF; Reid, ACE; DeCost, B; Biacchi, AJ; Walker, AHR; Trautt, Z; Hattrick-Simpers, J; Kusne, AG; Centrone, A; Davydov, A; Jiang, J; Pachter, R; Cheon, G; Reed, E; Agrawal, A; Qian, XF; Sharma, V; Zhuang, HL; Kalinin, SV; Sumpter, BG; Pilania, G; Acar, P; Mandal, S; Haule, K; Vanderbilt, D; Rabe, K; Tavazza, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Choudhary, Kamal; Garrity, Kevin F.; Reid, Andrew C. E.; DeCost, Brian; Biacchi, Adam J.; Hight Walker, Angela R.; Trautt, Zachary; Hattrick-Simpers, Jason; Kusne, A. Gilad; Centrone, Andrea; Davydov, Albert; Jiang, Jie; Pachter, Ruth; Cheon, Gowoon; Reed, Evan; Agrawal, Ankit; Qian, Xiaofeng; Sharma, Vinit; Zhuang, Houlong; Kalinin, Sergei V.; Sumpter, Bobby G.; Pilania, Ghanshyam; Acar, Pinar; Mandal, Subhasish; Haule, Kristjan; Vanderbilt, David; Rabe, Karin; Tavazza, Francesca", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The joint automated repository for various integrated simulations (JARVIS) for data-driven materials design", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Joint Automated Repository for Various Integrated Simulations (JARVIS) is an integrated infrastructure to accelerate materials discovery and design using density functional theory (DFT), classical force-fields (FF), and machine learning (ML) techniques. JARVIS is motivated by the Materials Genome Initiative (MGI) principles of developing open-access databases and tools to reduce the cost and development time of materials discovery, optimization, and deployment. The major features of JARVIS are: JARVIS-DFT, JARVIS-FF, JARVIS-ML, and JARVIS-tools. To date, JARVIS consists of approximate to 40,000 materials and approximate to 1 million calculated properties in JARVIS-DFT, approximate to 500 materials and approximate to 110 force-fields in JARVIS-FF, and approximate to 25 ML models for material-property predictions in JARVIS-ML, all of which are continuously expanding. JARVIS-tools provides scripts and workflows for running and analyzing various simulations. We compare our computational data to experiments or high-fidelity computational methods wherever applicable to evaluate error/uncertainty in predictions. In addition to the existing workflows, the infrastructure can support a wide variety of other technologically important applications as part of the data-driven materials design paradigm. The JARVIS datasets and tools are publicly available at the website: https://jarvis.nist.gov.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 12", "Publication Year": 2020, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 173, "DOI": "10.1038/s41524-020-00440-1", "DOI Link": "http://dx.doi.org/10.1038/s41524-020-00440-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000589052900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gupta, MK; Nieslony, P; Korkmaz, ME; Kuntoglu, M; Krolczyk, GM; Guenay, M; Sarikaya, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gupta, Munish Kumar; Nieslony, P.; Korkmaz, Mehmet Erdi; Kuntoglu, Mustafa; Krolczyk, G. M.; Guenay, Mustafa; Sarikaya, Murat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparison of Tool Wear, Surface Morphology, Specific Cutting Energy and Cutting Temperature in Machining of Titanium Alloys Under Hybrid and Green Cooling Strategies", "Source Title": "INTERNATIONAL JOURNAL OF PRECISION ENGINEERING AND MANUFACTURING-GREEN TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cutting energy must be reduced in order to make machining processes more eco-friendly. More energy was expended for the same amount of material removed, hence a higher specific cutting energy (SCE) implies inefficient material removal. Usually, the type of coolants or lubricants affects the SCE, or the amount of energy needed to cut a given volume of material. Therefore, the present work deals with a study of SCE in the turning of Ti-3Al-2.5V alloy under green cooling strategies. In spite of this, the research effort is also focused on the mechanism of tool wear, surface roughness, and cutting temperature under hybrid cooling, i.e., minimum quantity lubrication (MQL) and cryogenic. The tool wear rate, were explored with tool mapping analysis, and the results were compared with dry, MQL, and liquid nitrogen (LN2) conditions. The tool wear rate analysis claims that the dry condition causes more built up edge (BUE) formation. In addition, the hybrid cooling conditions are helpful in reducing the SCE while machining titanium alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1393, "End Page": 1406, "Article Number": null, "DOI": "10.1007/s40684-023-00512-9", "DOI Link": "http://dx.doi.org/10.1007/s40684-023-00512-9", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953633000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Attia, A; Tounsi, A; Bedia, EAA; Mahmoud, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Attia, Amina; Tounsi, Abdelouahed; Bedia, E. A. Adda; Mahmoud, S. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Free vibration analysis of functionally graded plates with temperature-dependent properties using various four variable refined plate theories", "Source Title": "STEEL AND COMPOSITE STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, various four variable refined plate theories are presented to analyze vibration of temperature-dependent functionally graded (FG) plates. By dividing the transverse displacement into bending and shear parts, the number of unknowns and governing equations for the present model is reduced, significantly facilitating engineering analysis. These theories account for parabolic, sinusoidal, hyperbolic, and exponential distributions of the transverse shear strains and satisfy the zero traction boundary conditions on the surfaces of the plate without using shear correction factors. Power law material properties and linear steady-state thermal loads are assumed to be graded along the thickness. Uniform, linear, nonlinear and sinusoidal thermal conditions are imposed at the upper and lower surface for simply supported FG plates. Equations of motion are derived from Hamilton's principle. Analytical solutions for the free vibration analysis are obtained based on Fourier series that satisfy the boundary conditions (Navier's method). Non-dimensional results are compared for temperature-dependent and temperature-independent FG plates and validated with known results in the literature. Numerical investigation is conducted to show the effect of material composition, plate geometry, and temperature fields on the vibration characteristics. It can be concluded that the present theories are not only accurate but also simple in predicting the free vibration responses of temperature-dependent FG plates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 187, "End Page": 212, "Article Number": null, "DOI": "10.12989/scs.2015.18.1.187", "DOI Link": "http://dx.doi.org/10.12989/scs.2015.18.1.187", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350121700010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tagarelli, F; Lopriore, E; Erkensten, D; Perea-Causín, R; Brem, S; Hagel, J; Sun, Z; Pasquale, G; Watanabe, K; Taniguchi, T; Malic, E; Kis, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tagarelli, Fedele; Lopriore, Edoardo; Erkensten, Daniel; Perea-Causin, Rauel; Brem, Samuel; Hagel, Joakim; Sun, Zhe; Pasquale, Gabriele; Watanabe, Kenji; Taniguchi, Takashi; Malic, Ermin; Kis, Andras", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical control of hybrid exciton transport in a van der Waals heterostructure", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interactions between out-of-plane dipoles in bosonic gases enable the long-range propagation of excitons. The lack of direct control over collective dipolar properties has so far limited the degrees of tunability and the microscopic understanding of exciton transport. In this work we modulate the layer hybridization and interplay between many-body interactions of excitons in a van der Waals heterostructure with an applied vertical electric field. By performing spatiotemporally resolved measurements supported by microscopic theory, we uncover the dipole-dependent properties and transport of excitons with different degrees of hybridization. Moreover, we find constant emission quantum yields of the transporting species as a function of excitation power with radiative decay mechanisms dominating over nonradiative ones, a fundamental requirement for efficient excitonic devices. Our findings provide a complete picture of the many-body effects in the transport of dilute exciton gases, and have crucial implications for studying emerging states of matter such as Bose-Einstein condensation and optoelectronic applications based on exciton propagation. The dipole-dependent propagation of hybrid excitons in a van der Waals heterostructure containing a WSe2 bilayer is characterized by modulating the layer hybridization and interplay between many-body interactions of excitons with an applied vertical electric field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 17, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 615, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-023-01198-w", "DOI Link": "http://dx.doi.org/10.1038/s41566-023-01198-w", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972787300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pandit, C; Roy, A; Ghotekar, S; Khusro, A; Islam, MN; Bin Emran, T; Lam, SE; Khandaker, MU; Bradley, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pandit, Chetan; Roy, Arpita; Ghotekar, Suresh; Khusro, Ameer; Islam, Mohammad Nazmul; Bin Emran, Talha; Lam, Siok Ee; khandaker, Mayeen Uddin; Bradley, David Andrew", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biological agents for synthesis of nulloparticles and their applications", "Source Title": "JOURNAL OF KING SAUD UNIVERSITY SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In terms of cost-efficiency, biocompatibility, environmental friendliness, and scalability, green nulloparticle (NP) synthesis is a novel field of nullotechnology that outperforms both physical and chemical approaches. Plants, bacteria, fungi, and algae have lately been used to produce metals and metal oxide nulloparticles as an alternate method. The development of alternative strategies to restrict the growth of hazardous bacteria, as well as the building of resistance by germs to various antibiotics, led to the introduction of nulloparticles as novel antimicrobial agents. Metal oxides have been found to form oxide monolayer structures for drug delivery when they react with a transporter's surface. Metal oxide nulloparticles have emerged as biomedical materials in recent years, with applications in immunotherapy, tissue treatment, diagnostics, regenerative medicine, wound healing, dentistry, and biosensing platforms. Biotoxicology and its antimicrobial, antifungal, and antiviral characteristics were hotly contested. Metal oxide nulloparticles have tremendous applicability and commercial value, as evidenced by important discoveries in the realm of nullobiomedicine in terms of locations and amounts. This paper describes the production of nullometal oxides from various green materials, as well as their applications.(c) 2022 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 34, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101869, "DOI": "10.1016/j.jksus.2022.101869", "DOI Link": "http://dx.doi.org/10.1016/j.jksus.2022.101869", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784307300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Watanabe, H; Yanase, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Watanabe, Hikaru; Yanase, Youichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral Photocurrent in Parity-Violating Magnet and Enhanced Response in Topological Antiferromagnet", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rectified electric current induced by irradiating light, a so-called photocurrent, is an established phenomenon in optoelectronic physics. In this paper, we present a comprehensive classification of the photocurrent response arising from the parity violation in bulk systems. We clarify the contrasting role of T and PT symmetries and consequently find new types of photocurrent phenomena characteristic of parity-violating magnets-the intrinsic Fermi surface effect and the gyration current. In particular, the gyration current is induced by circularly polarized light, and it is the counterpart of the shift current caused by linearly polarized light. This photocurrent adds a new functionality of materials studied in various fields of condensed matter physics such as multiferroics and spintronics. A list of materials is provided. Furthermore, we show that the gyration current is strongly enhanced by topologically nontrivial band dispersion. On the basis of the microscopic analysis of Dirac models, we demonstrate the divergent photocurrent response and elucidate the importance of the tilting of Dirac cones.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 119, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11001, "DOI": "10.1103/PhysRevX.11.011001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.11.011001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604548500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Denner, MM; Thomale, R; Neupert, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Denner, M. Michael; Thomale, Ronny; Neupert, Titus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analysis of Charge Order in the Kagome Metal AV3Sb5 (A = K,Rb,Cs)", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recent discovery of unconventional charge order, we develop a theory of electronically mediated charge density wave formation in the family of kagome metals AV(3)Sb(5) (A = K, Rb, Cs). The intertwining of van Hove filling and sublattice interference suggests a three-fold charge density wave instability at T-CDW. From there, the charge order forming below T-CDW can unfold into a variety of phases capable of exhibiting orbital currents and nematicity. We develop a Ginzburg Landau formalism to stake out the parameter space of kagome charge order. We find a nematic chiral charge order to be energetically preferred, which shows tentative agreement with experimental evidence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 156, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2021, "Volume": 127, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 217601, "DOI": "10.1103/PhysRevLett.127.217601", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.127.217601", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000721613700006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schiller, D; Finger, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schiller, David; Finger, Fritz", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application of Ti-in-zircon thermometry to granite studies: problems and possible solutions", "Source Title": "CONTRIBUTIONS TO MINERALOGY AND PETROLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of the Ti-in-zircon thermometer to granitic rock requires consideration of aTiO2 and aSiO2 during zircon crystallization. Thermodynamic software programs such as rhyolite-MELTS or Perple_X permit the estimation of aTiO2 and aSiO2 values from whole-rock geochemical data as a function of pressure and temperature. Model calculations carried out on a set of 14 different granite types at 2kbar, 5kbar, and H2O=3wt% show aSiO2 during zircon crystallization close to 1 (0.75-1) and aTiO2 generally far below unity (0.1-0.6). This would suggest that Ti-in-zircon temperatures for granites must be significantly upward corrected relative to the original TiO2- and SiO2-saturated calibration of the thermometer. Both the rhyolite-MELTS and Perple_X calculations indicate that aTiO2 is typically around 0.5 in ilmenite-bearing granites. Thus, for ilmenite-series granites (that is, almost all S-type and many I-type granites), it could be a reasonable first order approximation to apply a constant temperature correction of +70 degrees C to the Ti-in-zircon thermometer. Granites lacking the paragenesis zircon-ilmenite, that is, some A-type granites and a few special I-type granites may have even lower aTiO2 (0.1-0.5) and some of them may require a huge upward correction of Ti-in-zircon temperatures on the order of 100-200 degrees C. Using a set of Ti-in-zircon measurements from a Variscan granite of the Bohemian Massif, we introduce a novel T-dependent aTiO2 and aSiO2 correction of Ti-in-zircon calculated temperatures which is based on aTiO2-, aSiO2-T functions modelled with rhyolite-MELTS. This method takes into account that early and late zircons in granitic systems may crystallize at different aSiO2 and aTiO2. Furthermore, we highlight the usefulness of comparing the corrected results of Ti-in-zircon thermometry with bulk-rock-Zr-based zircon solubility thermometry and ideal zircon crystallization temperature distributions for granites, and we present a graphical method that enables this comparison. In addition, this paper addresses the problem that Ti-in-zircon measurements are commonly collected with only moderate spatial analytical resolution, which leads to an averaging effect and to difficulties in recording accurate crystallization temperatures. Therefore, we propose that Ti-in-zircon thermometry for granites should generally rely on the more representative median-T (T-med) value of a series of zircon analyses. Peak magma temperatures will be, in general, 35-50 degrees C above T-med, as can be modelled using zircon crystallization temperature distributions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 160, "Times Cited, All Databases": 171, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 174, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 51, "DOI": "10.1007/s00410-019-1585-3", "DOI Link": "http://dx.doi.org/10.1007/s00410-019-1585-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics; Mineralogy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469210000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sohier, T; Calandra, M; Mauri, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sohier, Thibault; Calandra, Matteo; Mauri, Francesco", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Density functional perturbation theory for gated two-dimensional heterostructures: Theoretical developments and application to flexural phonons in graphene", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ability to perform first-principles calculations of electronic and vibrational properties of two-dimensional heterostructures in a field-effect setup is crucial for the understanding and design of next-generation devices. We present here an implementation of density functional perturbation theories tailored for the case of two-dimensional heterostructures in field-effect configuration. Key ingredients are the inclusion of a truncated Coulomb interaction in the direction perpendicular to the slab and the possibility of simulating charging of the slab via field effects. With this implementation we can access total energies, force and stress tensors, the vibrational properties and the electron-phonon interaction. We demonstrate the relevance of the method by studying flexural acoustic phonons and their coupling to electrons in graphene doped by field effect. In particular, we show that while the electron-phonon coupling to those phonons can be significant in neutral graphene, it is strongly screened and negligible in doped graphene, in disagreement with other recent first-principles reports. Consequently, the gate-induced coupling with flexural acoustic modes would not be detectable in transport measurements on doped graphene.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 31", "Publication Year": 2017, "Volume": 96, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 75448, "DOI": "10.1103/PhysRevB.96.075448", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.075448", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408703600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, RS; Mannu, P; Prabhakaran, S; Nga, TTT; Kim, Y; Kim, D; Chen, JL; Dong, CL; Yoo, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Ramasamy Santhosh; Mannu, Pandian; Prabhakaran, Sampath; Nga, Ta Thi Thuy; Kim, Yangsoo; Kim, Do Hwan; Chen, Jeng-Lung; Dong, Chung-Li; Yoo, Dong Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trimetallic Oxide Electrocatalyst for Enhanced Redox Activity in Zinc-Air Batteries Evaluated by In Situ Analysis", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Researchers are investigating innovative composite materials for renewable energy and energy storage systems. The major goals of this studies are i) to develop a low-cost and stable trimetallic oxide catalyst and ii) to change the electrical environment of the active sites through site-selective Mo substitution. The effect of Mo on NiCoMoO4 is elucidated using both in situ X-ray absorption spectroscopy and X-ray diffraction analysis. Also, density functional theory strategies show that NiCoMoO4 has extraordinary catalytic redox activity because of the high adsorption energy of the Mo atom on the active crystal plane. Further, it is demonstrated that hierarchical nulloflower structures of NiCoMoO4 on reduced graphene oxide can be employed as a powerful bifunctional electrocatalyst for oxygen reduction/evolution reactions in alkaline solutions, providing a small overpotential difference of 0.75 V. Also, Zn-air batteries based on the developed bifunctional electrocatalyst exhibit outstanding cycling stability and a high-power density of 125.1 mW cm-2. This work encourages the use of Zn-air batteries in practical applications and provides an interesting concept for designing a bifunctional electrocatalyst. Both experimental and theoretical methods are used to examine how well spinel to tri-metallic catalysts via zinc-air batteries perform in processes involving oxygen reduction and oxygen evolution reactions.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 43, "Times Cited, All Databases": 44, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2023, "Volume": 10, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202303525", "DOI Link": "http://dx.doi.org/10.1002/advs.202303525", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076646400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Papaj, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Papaj, Michal", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Andreev reflection at the altermagnet-superconductor interface", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Altermagnets are a new class of magnetic materials, which exhibit large spin splitting, but due to the combined spin and real space group symmetry protection maintain zero net macroscopic magnetization. Such a characteris-tic may prove them to be superior in applications in superconducting heterostructures and thus here we investigate the Andreev reflection at the altermagnet/superconductor interface. We compare and contrast altermagnets to other magnetic materials, revealing qualitative differences in the behavior of altermagnetic junction depending on the Fermi surface orientation. We study the resonullt states arising in setups with strong tunneling barriers and show that sensitivity to nonmagnetic disorder is also dependent on the orientation. Our results provide a building block for altermagnetic superconducting heterostructures such as Josephson & pi; junctions with superior properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2023, "Volume": 108, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "L060508", "DOI": "10.1103/PhysRevB.108.L060508", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.108.L060508", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001062998800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, R; Yu, L; He, XY; Liu, HH; Ma, XY; Tao, ZZ; Wan, GL; Ahmad, N; Peng, B; Shi, L; Zhang, GQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Rong; Yu, Lai; He, Xiaoyue; Liu, Huanhuan; Ma, Xinyi; Tao, Zongzhi; Wan, Guanglin; Ahmad, Nazir; Peng, Bo; Shi, Liang; Zhang, Genqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing heterointerface of Bi/Bi2S3 with built-in electric field realizes superior sodium-ion storage capability", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bismuth sulfide (Bi2S3) is a dominullt anode material for sodium-ion batteries due to its high theoretical capacity. However, extreme volume fluctuations as well as low electrical conductivity and reaction kinetics still limit its practical applications. Herein, we construct an abundant heterointerface of Bi/Bi2S3 by engineering the structure of Bi nulloparticles embedded on Bi2S3 nullorods (denoted as Bi-Bi2S3 NRs) to effectively solve the abovementioned obstacles. Theoretical and systematic characterization results reveal that the constructed heterointerface of Bi/Bi2S3 has a built-in electric field, significantly boosts the electrical conductivity, enhances the Na+ diffusion kinetics, and buffers the volume variation. With this modification, it can deliver long cycling life, with an ultra-high capacity of 500 mAh g-1 over 500 cycles at 1 A g-1, and outstanding rate capability, with a capacity of 456 mAh g-1 even at 15 A g-1. Moreover, a full cell can achieve a high energy density of 180 Wh kg-1 at a power density of 40 W kg-1. Our research opens up a fresh path for improving the dynamics and structural stability of metal sulfide-based electrode materials for SIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 83, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100138, "DOI": "10.1016/j.esci.2023.100138", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100138", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001082566500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ellerbrock, R; Stein, M; Schaller, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ellerbrock, Ruth; Stein, Mathias; Schaller, Joerg", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparing amorphous silica, short-range-ordered silicates and silicic acid species by FTIR", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There is increased interest in the terrestrial silicon cycle in the last decades as its different compounds and species have large implications for ecosystem performance in terms of soil nutrient and water availability, ecosystem productivity as well as ecological aspects such as plant-microbe and plant-animal feedbacks. The currently existing analytical methods are limited. Fourier-transform infrared spectroscopy (FTIR) analysis is suggested being a promising tool to differentiate between the different Si species. We report here on the differentiation of varying Si-species/Si-binding (in synthetic material) using FTIR-analyses. Therefore, we collected FTIR-spectra of five different amorphous silica, Ca-silicate, sodium silicate (all particulate), a water-soluble fraction of amorphous silica and soil affected by volcanic activity and compared their spectra with existing data. A decrease of the internal order of the materials analyzed was indicated by peak broadening of the Si-O-Si absorption band. Peak shifts at this absorption band were induced by larger ions incorporated in the Si-O-Si network. Additionally, short-range ordered aluminosilicates (SROAS) have specific IR absorption bands such as the Si-O-Al band. Hence, SROAS and Si phases containing other ions can be distinguished from pure amorphous Si species using FTIR-analyses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 194, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11708, "DOI": "10.1038/s41598-022-15882-4", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-15882-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000822516700024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, FW; Zhuang, QY; Huang, G; Deng, HZ; Zhang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Fengwei; Zhuang, Qiuying; Huang, Ge; Deng, Hanzhong; Zhang, Xun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Infrared Spectrum Characteristics and Quantification of OH Groups in Coal", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The KBr pellet press method for detecting the infrared spectrum of coal is one of the commonly used methods for analyzing the types and content of functional groups in coal. However, KBr crystalline water or moisture has a significant impact on the peak position, peak shape, and peak area of the organic O-H based stretching vibration wave in coal. In this paper, the theoretical characteristics of infrared spectra of phenols and alcohols have been simulated and analyzed using the Gaussian 16 series of programs. Four infrared spectral analysis techniques, in situ infrared, KBr pellet press, dry KBr pellet press, and paste methods, have been used to detect the infrared spectra of coal. The results show that the stretching vibration peaks of free O-H radicals without hydrogen bonding are located between 3700 and 3600 cm-1. After the O-H form hydrogen bonds with each other, the O-H stretching vibration frequency moves toward the low frequency direction, and the lower the wavenumber, the more O-H content. The conventional KBr gasket manufacturing process will absorb moisture in the air to interfere with the hydroxyl absorption peak of coal, and the experimental process requires absolute drying. The relative content of hydroxyl in coal can be compared and analyzed based on the peak position, peak shape, and peak area of the hydroxyl stretching vibration wave. Quantitative analysis of hydroxyl groups in coal also requires combination of elemental analysis and X-ray photoelectron spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2023, "Volume": 8, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17064, "End Page": 17076, "Article Number": null, "DOI": "10.1021/acsomega.3c01336", "DOI Link": "http://dx.doi.org/10.1021/acsomega.3c01336", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984303500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pacheco-Peña, V; Engheta, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pacheco-Pena, Victor; Engheta, Nader", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antireflection temporal coatings", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is known that complete transmission of waves through the interface between two different media can be achieved by proper impedance matching between them. One of the most common techniques for such reflectionless propagation is the quarter-wave impedance transformer, where an additional slab of material with proper material parameters and carefully engineered dimensions is added between the two media, minimizing reflections. Metamaterials, with properly designed spatial inhomogeneity, have exhibited unprecedented ability to tailor and manipulate waves, and recently temporal metamaterials have also gained much attention, enabling spatiotemporal control of wave propagation. Here a temporal analogue of the quarter-wave impedance transformer technique, which we name antireflection temporal coating, is proposed using time-dependent materials. The proposed technique is demonstrated, analytically and numerically, using metamaterials with a time-dependent permittivity. Comparison with the conventional (spatial) impedance-matching technique is shown, demonstrating that both impedance matching and frequency conversion are achieved with our proposed temporal version. As an illustrative example, the present technique is also applied to match two waveguides with different cross sections, demonstrating an example of scenarios where it may be applied. (C) 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 159, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2020, "Volume": 7, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 323, "End Page": 331, "Article Number": null, "DOI": "10.1364/OPTICA.381175", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.381175", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528219500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Efimova, I; Bagaeva, M; Bagaev, A; Kileso, A; Chubarenko, IP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Efimova, Irina; Bagaeva, Margarita; Bagaev, Andrei; Kileso, Alexander; Chubarenko, Irina P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Secondary Microplastics Generation in the Sea Swash Zone With Coarse Bottom Sediments: Laboratory Experiments", "Source Title": "FRONTIERS IN MARINE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Marine beaches worldwide are nowadays exposed to significant contamination by plastics. On the Baltic beaches, polyethylene, polypropylene, and polystyrene are most abundant. We investigate the generation of microplastics particles (MPs, characteristic size from 0.5 to 5 mm) from larger plastic items in the sea swash zone using a laboratory rotating mixer filled with water and natural coarse beach sediment (marine pebbles). Inclination of the axis of rotation and the volume of the material were adjusted in such a way that mixing resembled a breaking wave in the swash zone. Plastic samples used were of the types most commonly found on the sea beaches. Experimental 2 x 2 cm-large plastic items made of low-density polyethylene (LDPE) were manufactured from common new garbage bags (thickness 5 mu m); those made of polypropylene (PP) and polystyrene (PS) were produced from single-use tableware; samples of foamed plastics were presented by cubes (with 2-cm sides) cut out of standard building insulator sheets (foamed PS). Four sets of 24-h-long experiments were conducted (for each type of plastic separately), with step-wise (every 3 h) examination of the generated MPs mass, number of particles, and their qualitative characteristics such as shape, quality of the surface, general behavior while mixing, etc. Statistically significant dependencies are obtained for the increase in mass and in number of MPs with time for all four used kinds of plastics. Brittle solid PS is shown to be the most productive in terms of both mass and number of MPs generated. Anisotropic springing PP is the most resistant. Tensile tearing of LDPE and fragmentation of foamed PS to compounding bubbles/spherules show the variety of mechanisms involved in fragmentation of plastics in the swash zone. Increase in MPs mass and the number of MPs particles with time, as well the link between them, are important for field monitoring and numerical modeling. Potentially shape-selective operation of sieves during sampling and sorting of MPs particles of various shapes is discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 5", "Publication Year": 2018, "Volume": 5, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 313, "DOI": "10.3389/fmars.2018.00313", "DOI Link": "http://dx.doi.org/10.3389/fmars.2018.00313", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457235800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ferreira, PP; Conway, LJ; Cucciari, A; Di Cataldo, S; Giannessi, F; Kogler, E; Eleno, LTF; Pickard, CJ; Heil, C; Boeri, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ferreira, Pedro P.; Conway, Lewis J.; Cucciari, Alessio; Di Cataldo, Simone; Giannessi, Federico; Kogler, Eva; Eleno, Luiz T. F.; Pickard, Chris J.; Heil, Christoph; Boeri, Lilia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Search for ambient superconductivity in the Lu-N-H system", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recent report of room-temperature superconductivity at near-ambient pressure in N-doped lutetium hydride, we performed a comprehensive, detailed study of the phase diagram of the Lu-N-H system, looking for superconducting phases. We combined ab initio crystal structure prediction with ephemeral data-derived interatomic potentials to sample over 200,000 different structures. Out of the more than 150 structures predicted to be metastable within similar to 50 meV from the convex hull we identify 52 viable candidates for conventional superconductivity, for which we computed their superconducting properties from Density Functional Perturbation Theory. Although for some of these structures we do predict a finite superconducting T-c, none is even remotely compatible with room-temperature superconductivity as reported by Dasenbrock et al. Our work joins the broader community effort that has followed the report of near-ambient superconductivity, confirming beyond reasonable doubt that no conventional mechanism can explain the reported T-c in Lu-N-H.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 46, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5367, "DOI": "10.1038/s41467-023-41005-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-41005-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001158944600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tjaden, B; Cooper, SJ; Brett, DJL; Kramer, D; Shearing, PR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tjaden, Bernhard; Cooper, Samuel J.; Brett, Daniel J. L.; Kramer, Denis; Shearing, Paul R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On the origin and application of the Bruggeman correlation for analysing transport phenomena in electrochemical systems", "Source Title": "CURRENT OPINION IN CHEMICAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widely used Bruggeman equations correlate tortuosity factors of porous media with their porosity. Finding diverse application from optics to bubble formation, it received considerable attention in fuel cell and battery research, recently. The ability to estimate tortuous mass transport resistance based on porosity alone is attractive, because direct access to the tortuosity factors is notoriously difficult. The correlation, however, has limitations, which are not widely appreciated owing to the limited accessibility of the original manuscript. We retrace Bruggeman's derivation, together with its initial assumptions, and comment on validity and limitations apparent from the original work to offer some guidance on its use.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 358, "Times Cited, All Databases": 388, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 12, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 44, "End Page": 51, "Article Number": null, "DOI": "10.1016/j.coche.2016.02.006", "DOI Link": "http://dx.doi.org/10.1016/j.coche.2016.02.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388513000009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Achouri, K; Tiukuvaara, V; Martin, OJF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Achouri, Karim; Tiukuvaara, Ville; Martin, Olivier J. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spatial symmetries in nonlocal multipolar metasurfaces", "Source Title": "ADVANCED PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a framework that connects the spatial symmetries of a metasurface to its material parameter tensors and its scattering matrix. This provides a simple and universal way to effortlessly determine the properties of a metasurface scattering response, such as chirality or asymmetric transmission, and which of its effective material parameters should be taken into account in the prospect of a homogenization procedure. In contrast to existing techniques, this approach does not require any a priori knowledge of group theory or complicated numerical simulation schemes, hence making it fast, easy to use and accessible. Its working principle consists in recursively solving symmetry-invariance conditions that apply to dipolar and quadrupolar material parameters, which include nonlocal interactions, as well as the metasurface scattering matrix. The overall process thus only requires listing the spatial symmetries of the metasurface. Using the proposed framework, we demonstrate the existence of multipolar extrinsic chirality, which is a form of chiral response that is achieved in geometrically achiral structures sensitive to field gradients, even at normal incidence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 44, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2023, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 46001, "DOI": "10.1117/1.AP.5.4.046001", "DOI Link": "http://dx.doi.org/10.1117/1.AP.5.4.046001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059284700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Logarzo, HJ; Capuano, G; Rimoli, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Logarzo, Hernull J.; Capuano, German; Rimoli, Julian J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Smart constitutive laws: Inelastic homogenization through machine learning", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Homogenizing the constitutive response of materials with nonlinear and history-dependent behavior at the microscale is particularly challenging. In this case, the only option is generally to homogenize numerically via concurrent multiscale models (CMMs). Unfortunately, these methods are not practical as their computational cost becomes prohibitive for engineering-scale applications. In this work, we develop an alternative formulation to CMMs that leverage state-of-the-art micromechanical modeling and advanced machine learning techniques to develop what we call smart constitutive laws (SCLs). We propose a training scheme for our SCLs that makes them suitable for arbitrary loading histories, making them equivalent to traditional constitutive models. We also show how to implement a SCL into a traditional finite element solver and investigate the response of an engineering-scale component. We compare our results to those obtained via a high fidelity simulation. Our findings indicate that SCLs can dramatically boost the computational efficiency and scalability of computational homogenization for nonlinear and history-dependent materials with arbitrary microstructures, enabling in this way the automatic and systematic generation of microstructurally-informed constitutive laws that can be adopted for the solution of macro-scale complex structures. (C) 2020 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 373, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 113482, "DOI": "10.1016/j.cma.2020.113482", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2020.113482", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000600286600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anderson, CP; Glen, EO; Zeledon, C; Bourassa, A; Jin, Y; Zhu, YZ; Vorwerk, C; Crook, AL; Abe, H; Ul-Hassan, J; Ohshima, T; Son, NT; Galli, G; Awschalom, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anderson, Christopher P.; Glen, Elena O.; Zeledon, Cyrus; Bourassa, Alexandre; Jin, Yu; Zhu, Yizhi; Vorwerk, Christian; Crook, Alexander L.; Abe, Hiroshi; Ul-Hassan, Jawad; Ohshima, Takeshi; Son, Nguyen T.; Galli, Giulia; Awschalom, David D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Five-second coherence of a single spin with single-shot readout in silicon carbide", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An outstanding hurdle for defect spin qubits in silicon carbide (SiC) is single-shot readout, a deterministic measurement of the quantum state. Here, we demonstrate single-shot readout of single defects in SiC via spin-to-charge conversion, whereby the defect's spin state is mapped onto a long-lived charge state. With this technique, we achieve over 80% readout fidelity without pre- or postselection, resulting in a high signal-to-noise ratio that enables us to measure long spin coherence times. Combined with pulsed dynamical decoupling sequences in an isotopically purified host material, we report single-spin T-2 > 5 seconds, over two orders of magnitude greater than previously reported in this system. The mapping of these coherent spin states onto single charges unlocks both single-shot readout for scalable quantum nodes and opportunities for electrical readout via integration with semiconductor devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 93, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabm5912", "DOI": "10.1126/sciadv.abm5912", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abm5912", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000750618100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Westwood, M; Zhao, XD; Chen, Z; Dames, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Westwood, Mitchell; Zhao, Xiaodong; Chen, Zhen; Dames, Chris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "4-fold enhancement in energy scavenging from fluctuating thermal resources using a temperature-doubler circuit", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oscillating thermal resources are ubiquitous thanks to the diurnal cycle and are also found in nonsolar settings. Yet in isolation, oscillating thermal resources cannot normally generate electricity because standard heat engines require two thermal terminals, a source and a sink, and hence the engine's second terminal is typically connected to some nearby constant-temperature reservoir. As an alternative, here we introduce the temperature doubler'' thermal circuit, based on two thermal diodes and two thermal capacitances. Modeling reveals how the electrical power output depends on the thermal diodes and masses. Benchtop experiments match the modeling well with no free parameters. Experiments further show that the temperature doubler generates four times more electricity than a conventional approach using a static heat sink, with a theoretical limit of an 8-fold enhancement for perfect thermal diodes and large thermal masses. This study shows how high-performance nonlinear thermal elements enable new approaches to more effective thermal-to-electrical energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2021, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2223, "End Page": 2240, "Article Number": null, "DOI": "10.1016/j.joule.2021.06.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.06.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686543600023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HH; Qin, G; Zhou, W; Li, Y; Zhou, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Henghai; Qin, Gang; Zhou, Wei; Li, Yang; Zhou, Xiaobing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing flake-like ternary rare earth Pr3Si2C2 ceramic on SiC whiskers to enhance electromagnetic wave absorption properties", "Source Title": "CERAMICS INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, flaky-like ternary Pr3Si2C2 was successfully coated in SiC whiskers (SiCw) via a molten salt process to augment the electromagnetic wave absorption (EWA) efficiency and expand the application potential of ternary rare earth silicate (RE3Si2C2) materials. Comprehensive investigations into the phase composition, morphological characteristics, EWA capacity, and corresponding mechanisms of the material were conducted. Furthermore, the electric field distribution is simulated and calculated for both vertical and horizontal incidence of the electromagnetic wave (EMW) on the specimens. Results showed that the incorporation of Pr3Si2C2 coating on SiC whiskers induces the development of heterogeneous interfaces and conductive networks, thereby augmenting polarization loss and conductive polarization, correspondingly enhancing the EWA performance of the material. In synergy with excellent attenuation ability and enhanced impedance matching, the Pr3Si2C2/SiCw composite demonstrates superior EWA performance in comparison to pristine SiCw. The minimum reflection loss (RLmin) of Pr3Si2C2/SiCw composites was achieved -48.117 dB accompanied by the effective absorption bandwidth (EAB) of 5.04 GHz at a thin thickness of merely 2.71 mm in the frequency range of 2-18 GHz. This research will serve as a valuable reference for the investigation of ternary rare earth ceramic-based EWA material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2024, "Volume": 50, "Issue": 1, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 134, "End Page": 142, "Article Number": null, "DOI": "10.1016/j.ceramint.2023.10.050", "DOI Link": "http://dx.doi.org/10.1016/j.ceramint.2023.10.050", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001131768000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kleemiss, F; Dolomanov, OV; Bodensteiner, M; Peyerimhoff, N; Midgley, L; Bourhis, LJ; Genoni, A; Malaspina, LA; Jayatilaka, D; Spencer, JL; White, F; Grundkötter-Stock, B; Steinhauer, S; Lentz, D; Puschmann, H; Grabowsky, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kleemiss, Florian; Dolomanov, Oleg V.; Bodensteiner, Michael; Peyerimhoff, Norbert; Midgley, Laura; Bourhis, Luc J.; Genoni, Alessandro; Malaspina, Lorraine A.; Jayatilaka, Dylan; Spencer, John L.; White, Fraser; Grundkoetter-Stock, Bernhard; Steinhauer, Simon; Lentz, Dieter; Puschmann, Horst; Grabowsky, Simon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accurate crystal structures and chemical properties from NoSpherA2", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The relationship between the structure and the properties of a drug or material is a key concept of chemistry. Knowledge of the three-dimensional structure is considered to be of such importance that almost every report of a new chemical compound is accompanied by an X-ray crystal structure - at least since the 1970s when diffraction equipment became widely available. Crystallographic software of that time was restricted to very limited computing power, and therefore drastic simplifications had to be made. It is these simplifications that make the determination of the correct structure, especially when it comes to hydrogen atoms, virtually impossible. We have devised a robust and fast system where modern chemical structure models replace the old assumptions, leading to correct structures from the model refinement against standard in-house diffraction data using no more than widely available software and desktop computing power. We call this system NoSpherA2 (Non-Spherical Atoms in Olex2). We explain the theoretical background of this technique and demonstrate the far-reaching effects that the improved structure quality that is now routinely available can have on the interpretation of chemical problems exemplified by five selected examples.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 235, "Times Cited, All Databases": 239, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 7", "Publication Year": 2021, "Volume": 12, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1675, "End Page": 1692, "Article Number": null, "DOI": "10.1039/d0sc05526c", "DOI Link": "http://dx.doi.org/10.1039/d0sc05526c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000617028900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, L; Zhou, JF; Chen, YN; Yu, DG; Liu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Liang; Zhou, Jianfeng; Chen, Yaoning; Yu, Deng-Guang; Liu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A combined electrohydrodynamic atomization method for preparing nullofiber/microparticle hybrid medicines", "Source Title": "FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial prostatitis is a challenging condition to treat with traditional dosage forms. Physicians often prescribe a variety of dosage forms with different administration methods, which fail to provide an efficient and convenient mode of drug delivery. The aim of this work was to develop a new type of hybrid material incorporating both electrosprayed core-shell microparticles and electrospun nullofibers. A traditional Chinese medicine (Ningmitai, NMT) and a Western medicine (ciprofloxacin, CIP) were co-encapsulated within this material and were designed to be released in a separately controlled manner. Utilizing polyvinylpyrrolidone (PVP) as a hydrophilic filament-forming polymer and pH-sensitive Eudragit (R) S100 (ES100) as the particulate polymeric matrix, a combined electrohydrodynamic atomization (EHDA) method comprising coaxial electrospraying and blending electrospinning, was used to create the hybrids in a single-step and straightforward manner. A series of characterization methods were conducted to analyze both the working process and its final products. Scanning electron microscopy and transmission electron microscopy revealed that the EHDA hybrids comprised of both CIP-PVP nullofibers and NMT-ES100 core-shell microparticles. Multiple methods confirmed the rapid release of CIP and the sustained release of NMT. The antibacterial experiments indicated that the hybrids exhibited a more potent antibacterial effect against Escherichia coli dh5 alpha and Bacillus subtilis Wb800 than either the separate nullofibers or microparticles. The amalgamation of fibrous nullomedicine and particulate micromedicine can expand the horizon of new types of medicines. The integration of electrospinning and coaxial electrospraying provides a straightforward approach to fabrication. By combining hydrophilic soluble polymers and pH-sensitive polymers in the hybrids, we can ensure the separate sequential controlled release of CIP and NMT for a potential synergistic and convenient therapy for bacterial prostatitis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 48, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2023, "Volume": 11, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1308004, "DOI": "10.3389/fbioe.2023.1308004", "DOI Link": "http://dx.doi.org/10.3389/fbioe.2023.1308004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001114186200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Berland, K; Hyldgaard, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Berland, Kristian; Hyldgaard, Per", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exchange functional that tests the robustness of the plasmon description of the van der Waals density functional", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Is the plasmon description within the nonlocal correlation of the van der Waals density functional by Dion and coworkers (vdW-DF) robust enough to describe all exchange-correlation components? To address this question, we design an exchange functional based on this plasmon description as well as recent analysis on exchange in the large-s regime. In the regime with reduced gradients s = |del n|/2nk(F)(n) smaller than approximate to 2.5, dominating the nonlocal correlation part of the binding energy, the enhancement factor F-x(s) closely resembles the Langreth-Vosko screened exchange. In the s regime beyond, dominated by exchange, F-x(s) passes smoothly over to the revised Perdew-Wang-86 form. We term the specific exchange functional LV-PW86r, wheras the full van der Waals functional version emphasizing consistent handling of exchange is termed vdW-DF-cx. Our tests indicate that vdW-DF-cx produces accurate separations and binding energies of the S22 data set of molecular dimers as well as accurate lattice constants and bulk moduli of layered materials and tightly bound solids. These results suggest that the plasmon description within vdW-DF gives a good description of both exchange and correlation effects in the low-to-moderate s regime.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 452, "Times Cited, All Databases": 489, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2014, "Volume": 89, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35412, "DOI": "10.1103/PhysRevB.89.035412", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.89.035412", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000332209600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, BC; Li, H; Ning, YQ; Fu, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Bingchao; Li, Heng; Ning, Yongquan; Fu, Mingwang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discontinuous dynamic recrystallization and nucleation mechanisms associated with 2-, 3-and 4-grain junctions of polycrystalline nickel-based superalloys", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the important role of grain junctions to the dynamic recrystallization (DRX) of nickel-based superalloys, the nucleation mechanisms operating there and the influence factors besides deformation condition on nucleation priority are still unclear. The microstructure evolution considering grain junction effects has not been explored in depth yet. In this paper, DRX nucleation at the 2-, 3- and 4-grain junctions of a nickel-based superalloy was investigated. A proposed passive grain boundary bulging (PGBB) mechanism operated well at 2-grain junctions, and accounted for the continuity of necklace structure during the early stage of hot deformation. For the 3-grain junctions, a two-step strain-induced bulging of grain boundary fragments, which closely adjoined the junctions, was found to dominate the DRX nucleation. In addition, an increasing nucleation priority from 2-, 3- to 4-grain junctions was confirmed by the established thermodynamic model, while the nucleation priority differences of the same kind grain junctions were quantitatively analyzed by using the Taylor factors of their component grains. Finally, the DRX microstructure evolution of a 4-grain stacking unit during hot deformation was described. The understanding of DRX associated with 2-, 3- to 4-grain junctions made it more effective to tailor the microstructure of nickel-based superalloy forgings. & COPY; 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 78, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 231, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112041, "DOI": "10.1016/j.matdes.2023.112041", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2023.112041", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001054755200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YF; Sigmund, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yafeng; Sigmund, Ole", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-material topology optimization for maximizing structural stability under thermo-mechanical loading", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanical structures are often simultaneously subjected to thermal and mechanical loading, both of which can lead to buckling failure. Developing efficient structural forms with better capacity for stability is important to keep structures safe. This study aims to optimize structural buckling capacity by using a density-based topology optimization scheme. Instead of treating the mechanical and thermal loadings as a single coupled part in the linearized buckling analysis, the effects of mechanical and thermal loadings are decoupled, which allows to separately analyze and optimize buckling aspects induced by mechanical or thermal loading. Two optimization models based on the decoupled analysis models are developed to respectively maximize the critical load factor of buckling induced by mechanical loading under a specified thermal loading and buckling induced by thermal loading under a specified mechanical loading. Further, based on a three-phase material model, a multi -material topology optimization scheme is employed to optimize the buckling capacity of active structures made of structural and actuating materials and prestressed structures containing prestressed components. The actuation effects are mimicked by the thermal loading of active material. The sensitivities of the objective functions and constraints are derived through the adjoint technique, and the method of moving asymptotes (MMA) is employed to solve the topology optimization problems. Numerical examples are adopted to verify the effectiveness of the proposed approach. (c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 57, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2023, "Volume": 407, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115938, "DOI": "10.1016/j.cma.2023.115938", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2023.115938", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000944818900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klar, PB; Krysiak, Y; Xu, HY; Steciuk, G; Cho, J; Zou, XD; Palatinus, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klar, Paul B.; Krysiak, Yasar; Xu, Hongyi; Steciuk, Gwladys; Cho, Jung; Zou, Xiaodong; Palatinus, Lukas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accurate structure models and absolute configuration determination using dynamical effects in continuous-rotation 3D electron diffraction data", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous-rotation 3D electron diffraction methods are increasingly popular for the structure analysis of very small organic molecular crystals and crystalline inorganic materials. Dynamical diffraction effects cause non-linear deviations from kinematical intensities that present issues in structure analysis. Here, a method for structure analysis of continuous-rotation 3D electron diffraction data is presented that takes multiple scattering effects into account. Dynamical and kinematical refinements of 12 compounds-ranging from small organic compounds to metal-organic frameworks to inorganic materials-are compared, for which the new approach yields significantly improved models in terms of accuracy and reliability with up to fourfold reduction of the noise level in difference Fourier maps. The intrinsic sensitivity of dynamical diffraction to the absolute structure is also used to assign the handedness of 58 crystals of 9 different chiral compounds, showing that 3D electron diffraction is a reliable tool for the routine determination of absolute structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 848, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-023-01186-1", "DOI Link": "http://dx.doi.org/10.1038/s41557-023-01186-1", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000975909300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Linka, K; Kuhl, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Linka, Kevin; Kuhl, Ellen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A new family of Constitutive Artificial Neural Networks towards automated model discovery", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "For more than 100 years, chemical, physical, and material scientists have proposed competing constitutive models to best characterize the behavior of natural and man-made materials in response to mechanical loading. Now, computer science offers a universal solution: Neural Networks. Neural Networks are powerful function approximators that can learn constitutive relations from large data without any knowledge of the underlying physics. However, classical Neural Networks entirely ignore a century of research in constitutive modeling, violate thermodynamic considerations, and fail to predict the behavior outside the training regime. Here we design a new family of Constitutive Artificial Neural Networks that inherently satisfy common kinematical, thermodynamical, and physical constraints and, at the same time, constrain the design space of admissible functions to create robust approximators, even in the presence of sparse data. Towards this goal we revisit the non-linear field theories of mechanics and reverse-engineer the network input to account for material objectivity, material symmetry and incompressibility; the network output to enforce thermodynamic consistency; the activation functions to implement physically reasonable restrictions; and the network architecture to ensure polyconvexity. We demonstrate that this new class of models is a generalization of the classical neo Hooke, Blatz Ko, Mooney Rivlin, Yeoh, and Demiray models and that the network weights have a clear physical interpretation in the form of shear moduli, stiffness-like parameters, and exponential coefficients. When trained with classical benchmark data for rubber under uniaxial tension, biaxial extension, and pure shear, our network autonomously selects the best constitutive model and learns its set of parameters. Our findings suggest that Constitutive Artificial Neural Networks have the potential to induce a paradigm shift in constitutive modeling, from user-defined model selection to automated model discovery. Our source code, data, and examples is available at https://github.com/LivingMatterLab/CANN.(c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 115, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2023, "Volume": 403, "Issue": null, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115731, "DOI": "10.1016/j.cma.2022.115731", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2022.115731", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906896000011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, QQ; Liu, RT; He, CH; Xia, CF; Guo, W; Xu, ZL; Xia, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Qingqing; Liu, Ruiting; He, Chaohui; Xia, Chenfeng; Guo, Wei; Xu, Zheng-Long; Xia, Bao Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced polymer-based electrolytes in zinc-air batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc-air batteries (ZABs) are expected to be some of the most promising power sources for wearable and portable electronic devices and have received widespread research interest. As an ion conductor connecting anodes and cathodes, the electrolyte is critical for the overall performance of ZABs (e.g., energy density, rechargeability, and operating voltage). Compared with liquid electrolytes, polymer-based electrolytes have superior characteristics for ZABs, such as negligible electrolyte leakage, three-phase interface stabilization, and dendrite suppression. In this perspective, we focus on recent progress in polymer-based electrolytes for ZABs. After a brief introduction to ZABs and electrolytes, we emphasize the development of polymer-based electrolytes in terms of their intrinsic properties and interfacial chemistry. Finally, challenges and viable strategies are proposed for polymer-based electrolytes in ZABs. We hope that this work will provide useful guidance to spur the development of highperformance ZABs based on advanced polymer-based electrolytes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 150, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 453, "End Page": 466, "Article Number": null, "DOI": "10.1016/j.esci.2022.08.004", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.08.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080925200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ahmad, A; Chaiyasarn, K; Farooq, F; Ahmad, W; Suparp, S; Aslam, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ahmad, Ayaz; Chaiyasarn, Krisada; Farooq, Furqan; Ahmad, Waqas; Suparp, Suniti; Aslam, Fahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Compressive Strength Prediction via Gene Expression Programming (GEP) and Artificial Neural Network (ANN) for Concrete Containing RCA", "Source Title": "BUILDINGS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To minimize the environmental risks and for sustainable development, the utilization of recycled aggregate (RA) is gaining popularity all over the world. The use of recycled coarse aggregate (RCA) in concrete is an effective way to minimize environmental pollution. RCA does not gain more attraction because of the availability of adhered mortar on its surface, which poses a harmful effect on the properties of concrete. However, a suitable mix design for RCA enables it to reach the targeted strength and be applicable for a wide range of construction projects. The targeted strength achievement from the proposed mix design at a laboratory is also a time-consuming task, which may cause a delay in the construction work. To overcome this flaw, the application of supervised machine learning (ML) algorithms, gene expression programming (GEP), and artificial neural network (ANN) was employed in this study to predict the compressive strength of RCA-based concrete. The linear coefficient correlation (R-2), mean absolute error (MAE), mean square error (MSE), and root mean square error (RMSE) were evaluated to investigate the performance of the models. The k-fold cross-validation method was also adopted for the confirmation of the model's performance. In comparison, the GEP model was more effective in terms of prediction by giving a higher correlation (R-2) value of 0.95 as compared to ANN, which gave a value of R-2 equal to 0.92. In addition, a sensitivity analysis was conducted to know about the contribution level of each parameter used to run the models. Moreover, the increment in data points and the use of other supervised ML approaches like boosting, gradient boosting, and bagging to forecast the compressive strength, would give a better response.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2021, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 324, "DOI": "10.3390/buildings11080324", "DOI Link": "http://dx.doi.org/10.3390/buildings11080324", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000688946100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, LB; Hao, JN; Johannessen, B; Ye, C; Yang, FH; Wu, C; Dou, SX; Liu, HK; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Libei; Hao, Junnull; Johannessen, Bernt; Ye, Chao; Yang, Fuhua; Wu, Chao; Dou, Shi-Xue; Liu, Hua-Kun; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid working mechanism enables highly reversible Zn electrodes", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn dendrite growth and water-related side reactions have been criticized to hinder actual applications of aqueous Zn-ion batteries. To address these issues, a series of Zn interfacial modifications of building solid/electrolyte interphase (SEI) and nucleation layers have been widely proposed, however, their effectiveness remains debatable. Here, we report a boron nitride (BN)/Nafion layer on the Zn surface to efficiently solve Zn problems through combining the hybrid working mechanisms of SEI and nucleation layers. In our protective layer, Nafion exhibits the SEI mechanism by blocking water from the Zn surface and providing abundant channels for rapid Zn2+ transmission, whilst BN nullosheets induce Zn deposition underneath with a preferred (002) orientation. Accordingly, dendrite-free and side-reaction-free Zn electrode with (002) deposition under the protective layer is realized for the first time, as reflected by its high reversibility with average Coulombic efficiency of 99.2% for > 3000 h. The protected Zn electrode also shows excellent performance in full cells when coupling with polyaniline cathode under the strict condition of lean electrolyte addition. This work highlights insights for designing highly reversible metal electrodes towards practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 112, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 3, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100096, "DOI": "10.1016/j.esci.2023.100096", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100096", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001083401000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schlipf, M; Gygi, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schlipf, Martin; Gygi, Francois", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimization algorithm for the generation of ONCV pseudopotentials", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an optimization algorithm to construct pseudopotentials and use it to generate a set of Optimized Norm-Conserving Vanderbilt (ONCV) pseudopotentials for elements up to Z = 83 (Bi) (excluding Lanthanides). We introduce a quality function that assesses the agreement of a pseudopotential calculation with all-electron FLAPW results, and the necessary plane-wave energy cutoff. This quality function allows us to use a Nelder-Mead optimization algorithm on a training set of materials to optimize the input parameters of the pseudopotential construction for most of the periodic table. We control the accuracy of the resulting pseudopotentials on a test set of materials independent of the training set. We find that the automatically constructed pseudopotentials (http://www.quantum-simulation.org) provide a good agreement with the all-electron results obtained using the FLEUR code with a plane-wave energy cutoff of approximately 60 Ry. (C) 2015 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 897, "Times Cited, All Databases": 993, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 196, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 36, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.cpc.2015.05.011", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2015.05.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362602900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZP; Gao, MS; Lei, ZX; Tong, LH; Sun, JB; Wang, YF; Wang, XY; Jiang, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiping; Gao, Mengshi; Lei, Zuxiang; Tong, Lihong; Sun, Junbo; Wang, Yufei; Wang, Xiangyu; Jiang, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ternary cementless composite based on red mud, ultra-fine fly ash, and GGBS: Synergistic utilization and geopolymerization mechanism", "Source Title": "CASE STUDIES IN CONSTRUCTION MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Industrial solid wastes, such as ultra-fine fly ash (RUFA) and ground granulated blast-furnace slag (GGBS), hold tremendous potential for recycling due to their abundance and excellent pozzolanic properties. However, red mud (RM), a highly alkaline waste, has not received comprehensive attention in the construction industry. Thus, this study investigates the synergistic effect and geopolymerization mechanism of industrial solid wastes in ternary cementless composites based on RM, RUFA, and GGBS. The experimental program includes macroscopic comparative analyses of water consumption, fluidity, setting time, permeability, and compressive strength of the ternary cementless composite. Additionally, SEM and EDS analyses examine the microscopic morphology and elemental distribution of the composite. The results indicate that RM prolongs the setting time while reducing fluidity and compressive strength. A 30% increase in RM content led to a substantial rise in the initial and final setting time by approximately 191.6% and 164.7%, respectively. In contrast, GGBS enhances the compressive characteristics of the composite systems but shortens the setting time and reduces fluidity. Notably, Group D4 demonstrates the highest compressive strength, reaching an impressive 47.3 MPa. Moreover, the content of GGBS influences the hydration products in the ternary cementless composite. At low GGBS content, the material contains a significant amount of N-A-S-H gels, whereas at high GGBS content, partial NA-S-H gels are replaced by C-A-S-H gels. These findings significantly enhance our understanding of the synergistic effect and geopolymerization mechanism of RM, RUFA, and GGBS, thereby facilitating the reuse of these three industrial solid wastes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 19, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e02410", "DOI": "10.1016/j.cscm.2023.e02410", "DOI Link": "http://dx.doi.org/10.1016/j.cscm.2023.e02410", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001106747000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhivulin, VE; Trofimov, EA; Zaitseva, OV; Sherstyuk, DP; Cherkasova, NA; Taskaev, SV; Vinnik, DA; Alekhina, YA; Perov, NS; Naidu, KCB; Elsaeedy, HI; Khandaker, MU; Tishkevich, DI; Zubar, TI; Trukhanov, AV; Trukhanov, SV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhivulin, Vladimir E.; Trofimov, Evgeniy A.; Zaitseva, Olga V.; Sherstyuk, Daria P.; Cherkasova, Natalya A.; Taskaev, Sergey V.; Vinnik, Denis A.; Alekhina, Yulia A.; Perov, Nikolay S.; Naidu, Kadiyala C. B.; Elsaeedy, Halima I.; Khandaker, Mayeen U.; Tishkevich, Daria I.; Zubar, Tatiana I.; Trukhanov, Alex V.; Trukhanov, Sergei V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation, phase stability, and magnetization behavior of high entropy hexaferrites", "Source Title": "ISCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The polycrystalline SrFe12O19 samples deeply substituted up to at.67% by Al3+, Ga3+, In3+, Co3+, and Cr3+ cations with a high configurational mixing entropy were prepared by solid-phase synthesis. Phase purity and unit cell parameters were obtained from XRD and analyzed versus the average ionic radius of the iron sublattice. The crystallite size varied around similar to 4.5 mu m. A comprehensive study of the magnetization was realized in various fields and temperatures. The saturation magnetization was calculated using the Law of Approach to Saturation. The accompanying magnetic parameters were determined. The magnetic crystallographic anisotropy coefficient and the anisotropy field were calculated. All investigated magnetization curves turned out to be nonmonotonic. The magnetic ordering and freezing temperatures were extracted from the ZFC and FC curves. The average size of magnetic clusters varied around similar to 350 nm. The high values of the configurational mixing entropy and the phenomenon of magnetic dilution were taken into account.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 96, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2023, "Volume": 26, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 107077, "DOI": "10.1016/j.isci.2023.107077", "DOI Link": "http://dx.doi.org/10.1016/j.isci.2023.107077", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001055984800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ishito, K; Mao, HL; Kousaka, Y; Togawa, Y; Iwasaki, S; Zhang, T; Murakami, S; Kishine, J; Satoh, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ishito, Kyosuke; Mao, Huiling; Kousaka, Yusuke; Togawa, Yoshihiko; Iwasaki, Satoshi; Zhang, Tiantian; Murakami, Shuichi; Kishine, Jun-ichiro; Satoh, Takuya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Truly chiral phonons in α-HgS", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The notion of chirality in dynamical systems with broken spatial symmetry but preserved time inversion symmetry has led to the concept of truly chiral phonons. These have now been observed in bulk HgS using circularly polarized Raman spectroscopy. Chirality is a manifestation of the asymmetry inherent in nature. It has been defined as the symmetry breaking of the parity of static objects, and the definition was extended to dynamic motion such that true and false chiralities were distinguished. Recently, rotating, yet not propagating, atomic motions were predicted and observed in two-dimensional materials, and they were referred to as 'chiral phonons'. A natural development would be the discovery of truly chiral phonons that propagate while rotating in three-dimensional materials. Here we used circularly polarized Raman scattering and first-principles calculations to identify truly chiral phonons in chiral bulk crystals. This approach enabled us to determine the chirality of a crystal in a non-contact and non-destructive manner. In addition, we demonstrated that the law of the conservation of pseudo-angular momentum holds between circularly polarized photons and chiral phonons. These findings are expected to help develop ways for transferring the pseudo-angular momentum from photons to electron spins via propagating chiral phonons in opto-phononic-spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 19, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 35, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-022-01790-x", "DOI Link": "http://dx.doi.org/10.1038/s41567-022-01790-x", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000876849000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fadl, M; Eames, PC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fadl, Mohamed; Eames, Philip C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical investigation of the influence of mushy zone parameter Amush on heat transfer characteristics in vertically and horizontally oriented thermal energy storage systems", "Source Title": "APPLIED THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The effect of the value used for the mushy zone parameter (A(mush)) on predicted heat transfer and melting characteristics of a phase change material (PCM) Lauric acid, in both vertical and horizontal enclosures was studied. There is a lack of clarity regarding which value of this parameter should be used for accurate simulations of phase change heat transfer, addressing this will aid in accurate simulation and design of systems for LHTES (Latent heat thermal energy storage). The numerical analysis undertaken used a commercial CFD code ANSYS FLUENT 18.2 and the enthalpy-porosity formulation. The range of mushy zone parameter used was from 10(5) to 10(7). The predicted locations of the melt front were compared to published experimental data available in the literature. The simulations provided quantitative information about the amount of energy stored and the melt fraction and providing improved understanding of the heat transfer process. Comparison between predictions using different values of A(mush), and experimental data showed that correct selection of the value of A(mus)h to be used in the momentum equations is an important parameter for accurate modelling of LHTES and has a significant influence on the solid-liquid interface shape and progression. The study reveals that increasing the value of A(mush) leads to a decrease in fluid velocity, decreasing convection and the rate of heat transfer, therefore, proper selection of the mushy zone parameter is necessary to accurately simulate LHTES systems and provide a better understanding of the phase change behaviour and heat transfer characteristics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 228, "Times Cited, All Databases": 234, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2019, "Volume": 151, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 90, "End Page": 99, "Article Number": null, "DOI": "10.1016/j.applthermaleng.2019.01.102", "DOI Link": "http://dx.doi.org/10.1016/j.applthermaleng.2019.01.102", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463122900009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, Q; Han, JC; Wang, XJ; Xu, P; Yao, T; Zhong, J; Zhong, WW; Liu, SW; Gao, TL; Zhang, ZH; Xu, LL; Song, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Qiang; Han, Jiecai; Wang, Xianjie; Xu, Ping; Yao, Tai; Zhong, Jun; Zhong, Wenwu; Liu, Shengwei; Gao, Tangling; Zhang, Zhihua; Xu, Lingling; Song, Bo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "2D Transition Metal Dichalcogenides: Design, Modulation, and Challenges in Electrocatalysis", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen has been deemed as an ideal substitute fuel to fossil energy because of its renewability and the highest energy density among all chemical fuels. One of the most economical, ecofriendly, and high-performance ways of hydrogen production is electrochemical water splitting. Recently, 2D transition metal dichalcogenides (also known as 2D TMDs) showed their utilization potentiality as cost-effective hydrogen evolution reaction (HER) catalysts in water electrolysis. Herein, recent representative research efforts and systematic progress made in 2D TMDs are reviewed, and future opportunities and challenges are discussed. Furthermore, general methods of synthesizing 2D TMDs materials are introduced in detail and the advantages and disadvantages for some specific methods are provided. This explanation includes several important regulation strategies of creating more active sites, heteroatoms doping, phase engineering, construction of heterostructures, and synergistic modulation which are capable of optimizing the electrical conductivity, exposure to the catalytic active sites, and reaction energy barrier of the electrode material to boost the HER kinetics. In the last section, the current obstacles and future chances for the development of 2D TMDs electrocatalysts are proposed to provide insight into and valuable guidelines for fabricating effective HER electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 501, "Times Cited, All Databases": 522, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 33, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1907818, "DOI": "10.1002/adma.201907818", "DOI Link": "http://dx.doi.org/10.1002/adma.201907818", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542160500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hosseinzadeh, K; Moghaddam, MAE; Asadi, A; Mogharrebi, AR; Jafari, B; Hasani, MR; Ganji, DD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hosseinzadeh, Kh; Moghaddam, M. A. Erfani; Asadi, A.; Mogharrebi, A. R.; Jafari, B.; Hasani, M. R.; Ganji, D. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of two different fins (longitudinal-tree like) and hybrid nullo-particles (MoS2 - TiO2) on solidification process in triplex latent heat thermal energy storage system", "Source Title": "ALEXANDRIA ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To tackle global warming, a reliable storage system seems crucial due to unpredictability of renewable energy. As a result, storage units based on Phase Change Material (PCM) are found to be of great worth where latent heat transfer occurring in an almost isothermal condition lay the foundation for far more compact and easy-to-fabricate storage components. Despite their advantageous, one major drawback being weak thermal conductivity needs to be addressed. So, in this study a triplex-tube heat exchanger with tree-like and rectangular fins along with hybrid nulloparticles made of MoS2 - TiO2 are put into perspective to dispose of this weakness and Galerkin Finite Element Method (GFEM) is applied using FlexPDE to analyze the solidification process and evaluate the influence of single and combined usage of fins and nulloparticles. Moreover, the credibility of this study and GFEM has been confirmed by an experimental work. The results unveiled that, while the combined usage of nulloparticles and tree-like fins gives the best result by lowering the solidification time by 78% compared to bare tube, tree-like fins claim the best performance taking 1700 s followed by rectangular fins with 3500 s if nulloparticles are out of reach. (C) 2020 The Authors. Published by Elsevier B.V. on behalf of Faculty of Engineering, Alexandria University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 141, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 60, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1967, "End Page": 1979, "Article Number": null, "DOI": "10.1016/j.aej.2020.12.001", "DOI Link": "http://dx.doi.org/10.1016/j.aej.2020.12.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613740700022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Motta, M; Ceperley, DM; Chan, GKL; Gomez, JA; Gull, E; Guo, S; Jiménez-Hoyos, CA; Lan, TN; Li, J; Ma, FJ; Millis, AJ; Prokof'ev, NV; Ray, U; Scuseria, GE; Sorella, S; Stoudenmire, EM; Sun, QM; Tupitsyn, IS; White, SR; Zgid, D; Zhang, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Motta, Mario; Ceperley, David M.; Chan, Garnet Kin-Lic; Gomez, John A.; Gull, Emanuel; Guo, Sheng; Jimenez-Hoyos, Carlos A.; Tran Nguyen Lan; Li, Jia; Ma, Fengjie; Millis, Andrew J.; Prokof'ev, Nikolay V.; Ray, Ushnish; Scuseria, Gustavo E.; Sorella, Sandro; Stoudenmire, Edwin M.; Sun, Qiming; Tupitsyn, Igor S.; White, Steven R.; Zgid, Dominika; Zhang, Shiwei", "Book Author Full Names": null, "Group Authors": "Simons Collaboration Many-Electron", "Article Title": "Towards the Solution of the Many-Electron Problem in Real Materials: Equation of State of the Hydrogen Chain with State-of-the-Art Many-Body Methods", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present numerical results for the equation of state of an infinite chain of hydrogen atoms. Avariety of modern many-body methods are employed, with exhaustive cross-checks and validation. Approaches for reaching the continuous space limit and the thermodynamic limit are investigated, proposed, and tested. The detailed comparisons provide a benchmark for assessing the current state of the art in many-body computation, and for the development of new methods. The ground-state energy per atom in the linear chain is accurately determined versus bond length, with a confidence bound given on all uncertainties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 207, "Times Cited, All Databases": 231, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 28", "Publication Year": 2017, "Volume": 7, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31059, "DOI": "10.1103/PhysRevX.7.031059", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.7.031059", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411994100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Patel, SK; Surve, J; Katkar, V; Parmar, J; Al-Zahrani, FA; Ahmed, K; Bui, FM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Patel, Shobhit K.; Surve, Jaymit; Katkar, Vijay; Parmar, Juveriya; Al-Zahrani, Fahad Ahmed; Ahmed, Kawsar; Bui, Francis Minhthang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Encoding and Tuning of THz Metasurface-Based Refractive Index Sensor With Behavior Prediction Using XGBoost Regressor", "Source Title": "IEEE ACCESS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We have investigated graphene-based three various refractive index sensors (split ring resonator (SRR), split ring resonator with thin wire (SRRTW), and thin wire (TW) refractive index sensors) for the encoding and sensing-based applications. The sensors are designed to detect the presence of hemoglobin biomolecules with high sensitivity. The results are analyzed in the form of transmittance, and electric field and detailed sensitivity analysis is also carried out for the proposed graphene-based refractive index sensors for four various concentrations of hemoglobin biomolecules. We have also investigated the sensor's performance in terms of quality factor, Q, and figure of merit (FOM). The encoding of '0' and '1' is attained by varying the graphene chemical potential fulfilling the one-digit coding. An array of these sensors can then be used for encoding-based applications. The detailed analysis of reported sensors is also carried out by checking the effect of varying physical parameters such as substrate thickness, split ring gap, and thin wire width on tunability. These sensors can be applied in biomedical or encoding-based applications. Experiments are performed using XGBoost regressor to determine, whether simulation time and resources can be reduced by using regression analysis to predict the transmittance values of intermediate frequency or not. Experimental results prove that regression analysis using XGBoost Regressor can reduce the simulation time and resources by at least 70 percent.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 24797, "End Page": 24814, "Article Number": null, "DOI": "10.1109/ACCESS.2022.3154386", "DOI Link": "http://dx.doi.org/10.1109/ACCESS.2022.3154386", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Engineering; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766544400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Manz, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Manz, Thomas A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Introducing DDEC6 atomic population analysis: part 3. Comprehensive method to compute bond orders", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing a comprehensive method to compute bond orders is a problem that has eluded chemists since Lewis's pioneering work on chemical bonding a century ago. Here, a computationally efficient method solving this problem is introduced and demonstrated for diverse materials including elements from each chemical group and period. The method is applied to non-magnetic, collinear magnetic, and noncollinear magnetic materials with localized or delocalized bonding electrons. Examples studied include the stretched O-2 molecule, 26 diatomic molecules, 3d and 5d transition metal solids, periodic materials with 1 to 8748 atoms per unit cell, a biomolecule, a hypercoordinate molecule, an electron deficient molecule, hydrogen bound systems, transition states, Lewis acid-base complexes, aromatic compounds, magnetic systems, ionic materials, dispersion bound systems, nullostructures,and other materials. From near-zero to high-order bonds were studied. Both the bond orders and the sum of bond orders for each atom are accurate across various bonding types: metallic, covalent, polar-covalent, ionic, aromatic, dative, hypercoordinate, electron deficient multi-centered, agostic, and hydrogen bonding. The method yields similar results for correlated wavefunction and density functional theory inputs and for different SZ values of a spin multiplet. The method requires only the electron and spin magnetization density distributions as input and has a computational cost scaling linearly with increasing number of atoms in the unit cell. No prior approach is as general. The method does not apply to electrides, highly timedependent states, some extremely high-energy excited states, and nuclear reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 408, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": 72, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 45552, "End Page": 45581, "Article Number": null, "DOI": "10.1039/c7ra07400j", "DOI Link": "http://dx.doi.org/10.1039/c7ra07400j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412147000038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eriksson, F; Fransson, E; Erhart, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eriksson, Fredrik; Fransson, Erik; Erhart, Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Hiphive Package for the Extraction of High-Order Force Constants by Machine Learning", "Source Title": "ADVANCED THEORY AND SIMULATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The efficient extraction of force constants (FCs) is crucial for the analysis of many thermodynamic materials properties. Approaches based on the systematic enumeration of finite differences scale poorly with system size and can rarely extend beyond third order when input data is obtained from first-principles calculations. Methods based on parameter fitting in the spirit of interatomic potentials, on the other hand, can extract FC parameters from semi-random configurations of high information density and advanced regularized regression methods can recover physical solutions from a limited amount of data. Here, the HIPHIVE Python package, that enables the construction of force constant models up to arbitrary order is presented. HIPHIVE exploits crystal symmetries to reduce the number of free parameters and then employs advanced machine learning algorithms to extract the force constants. Depending on the problem at hand, both over and underdetermined systems are handled efficiently. The FCs can be subsequently analyzed directly and or be used to carry out, for example, molecular dynamics simulations. The utility of this approach is demonstrated via several examples including ideal and defective monolayers of MoS2 as well as bulk nickel.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 289, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1800184, "DOI": "10.1002/adts.201800184", "DOI Link": "http://dx.doi.org/10.1002/adts.201800184", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468273900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Uddin, MS; Toki, GFI; Mohammed, MKA; Pandey, R; Madan, J; Rahman, MF; Islam, MR; Bhattarai, S; Bencherif, H; Samajdar, DP; Amami, M; Dwivedi, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Uddin, M. Shihab; Toki, G. F. Ishraque; Mohammed, Mustafa K. A.; Pandey, Rahul; Madan, Jaya; Rahman, Md. Ferdous; Islam, Md. Rasidul; Bhattarai, Sagar; Bencherif, H.; Samajdar, D. P.; Amami, Mongi; Dwivedi, D. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Achieving above 24% efficiency with non-toxic CsSnI3 perovskite solar cells by harnessing the potential of the absorber and charge transport layers", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead toxicity is a barrier to the widespread commercial manufacture of lead halide perovskites and their use in solar photovoltaic (PV) devices. Eco-friendly lead-free perovskite solar cells (PSCs) have been developed using certain unique non- or low-toxic perovskite materials. In this context, Sn-based perovskites have been identified as promising substitutes for Pb-based perovskites due to their similar characteristics. However, Sn-based perovskites suffer from chemical instability, which affects their performance in PSCs. This study employs theoretical simulations to identify ways to improve the efficiency of Sn-based PSCs. The simulations were conducted using the SCAPS-1D software, and a lead-free, non-toxic, and inorganic perovskite absorber layer (PAL), i.e. CsSnI3 was used in the PSC design. The properties of the hole transport layer (HTL) and electron transport layer (ETL) were tuned to optimize the performance of the device. Apart from this, seven different combinations of HTLs were studied, and the best-performing combination was found to be ITO/PCBM/CsSnI3/CFTS/Se, which achieved a power conversion efficiency (PCE) of 24.73%, an open-circuit voltage (V-OC) of 0.872 V, a short-circuit current density (J(SC)) of 33.99 mA cm(-2) and a fill factor (FF) of 83.46%. The second highest PCE of 18.41% was achieved by the ITO/PCBM/CsSnI3/CuSCN/Se structure. In addition to optimizing the structure of the PSC, this study also analyzes the current density-voltage (J-V) along with quantum efficiency (QE), as well as the impact of series resistance, shunt resistance, and working temperature, on PV performance. The results demonstrate the potential of the optimized structure identified in this study to enhance the standard PCE of PSCs. Overall, this study provides important insights into the development of lead-free absorber materials and highlights the potential of using CsSnI3 as the PAL in PSCs. The optimized structure identified in this study can be used as a base for further research to improve the efficiency of Sn-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 4", "Publication Year": 2023, "Volume": 13, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23514, "End Page": 23537, "Article Number": null, "DOI": "10.1039/d3ra02910g", "DOI Link": "http://dx.doi.org/10.1039/d3ra02910g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001042291400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tancogne-Dejean, N; Oliveira, MJT; Andrade, X; Appel, H; Borca, CH; Le Breton, G; Buchholz, F; Castro, A; Corni, S; Correa, AA; De Giovannini, U; Delgado, A; Bich, FG; Flick, J; Gil, G; Gomez, A; Helbig, N; Hübener, H; Jestädt, R; Jornet-Somoza, J; Larsen, AH; Lebedeva, IV; Lüders, M; Marques, MAL; Ohlmann, ST; Pipolo, S; Rampp, M; Rozzi, CA; Strubbe, DA; Sato, SA; Schäfer, C; Theophilou, I; Welden, A; Rubio, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tancogne-Dejean, Nicolas; Oliveira, Micael J. T.; Andrade, Xavier; Appel, Heiko; Borca, Carlos H.; Le Breton, Guillaume; Buchholz, Florian; Castro, Alberto; Corni, Stefano; Correa, Alfredo A.; De Giovannini, Umberto; Delgado, Alain; Bich, Florian G.; Flick, Johannes; Gil, Gabriel; Gomez, Adrian; Helbig, Nicole; Huebener, Hannes; Jestaedt, Rene; Jornet-Somoza, Joaquim; Larsen, Ask H.; Lebedeva, Irina, V; Lueders, Martin; Marques, Miguel A. L.; Ohlmann, Sebastian T.; Pipolo, Silvio; Rampp, Markus; Rozzi, Carlo A.; Strubbe, David A.; Sato, Shunsuke A.; Schaefer, Christian; Theophilou, Iris; Welden, Alicia; Rubio, Angel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Octopus, a computational framework for exploring light-driven phenomena and quantum dynamics in extended and finite systems", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Over the last few years, extraordinary advances in experimental and theoretical tools have allowed us to monitor and control matter at short time and atomic scales with a high degree of precision. An appealing and challenging route toward engineering materials with tailored properties is to find ways to design or selectively manipulate materials, especially at the quantum level. To this end, having a state-of-the-art ab initio computer simulation tool that enables a reliable and accurate simulation of light-induced changes in the physical and chemical properties of complex systems is of utmost importance. The first principles real-space-based Octopus project was born with that idea in mind, i.e., to provide a unique framework that allows us to describe non-equilibrium phenomena in molecular complexes, low dimensional materials, and extended systems by accounting for electronic, ionic, and photon quantum mechanical effects within a generalized time-dependent density functional theory. This article aims to present the new features that have been implemented over the last few years, including technical developments related to performance and massive parallelism. We also describe the major theoretical developments to address ultrafast light-driven processes, such as the new theoretical framework of quantum electrodynamics density-functional formalism for the description of novel light-matter hybrid states. Those advances, and others being released soon as part of the Octopus package, will allow the scientific community to simulate and characterize spatial and time-resolved spectroscopies, ultrafast phenomena in molecules and materials, and new emergent states of matter (quantum electrodynamical-materials). (C) 2020 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2020, "Volume": 152, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124119, "DOI": "10.1063/1.5142502", "DOI Link": "http://dx.doi.org/10.1063/1.5142502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522972800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reta, D; Chilton, NF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reta, Daniel; Chilton, Nicholas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Uncertainty estimates for magnetic relaxation times and magnetic relaxation parameters", "Source Title": "PHYSICAL CHEMISTRY CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of alternating current (AC) magnetometry to measure magnetic relaxation times is one of the most fundamental measurements for characterising single-molecule magnets (SMMs). These measurements, performed as a function of frequency, temperature and magnetic field, give vital information on the underlying magnetic relaxation process(es) occurring in the material. The magnetic relaxation times are usually fitted to model functions derived from spin-phonon coupling theories that allow characterisation of the mechanisms of magnetic relaxation. The parameters of these relaxation models are then often compared between different molecules in order to find trends with molecular structure that may guide the field to the next breakthrough. However, such meta-analyses of the model parameters are doomed to over-interpretation unless uncertainties in the model parameters can be quantified. Here we determine a method for obtaining uncertainty estimates in magnetic relaxation times from AC experiments, and provide a program called CC-FIT2 for fitting experimental AC data as well as the resulting relaxation times, to obtain relaxation parameters with accurate uncertainties. Applying our approach to three archetypal families of high-performance dysprosium(iii) SMMs shows that accounting for uncertainties has a significant impact on the uncertainties of relaxation parameters, and that larger uncertainties appear to correlate with crystallographic disorder in the compounds studied. We suggest that this type of analysis should become routine in the community.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 258, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 14", "Publication Year": 2019, "Volume": 21, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23567, "End Page": 23575, "Article Number": null, "DOI": "10.1039/c9cp04301b", "DOI Link": "http://dx.doi.org/10.1039/c9cp04301b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495070100029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Allan, J; Belz, S; Hoeveler, A; Hugas, M; Okuda, H; Patri, A; Rauscher, H; Silva, P; Slikker, W; Sokull-Kluettgen, B; Tong, WD; Anklam, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Allan, Jacqueline; Belz, Susanne; Hoeveler, Arnd; Hugas, Marta; Okuda, Haruhiro; Patri, Anil; Rauscher, Hubert; Silva, Primal; Slikker, William; Sokull-Kluettgen, Birgit; Tong, Weida; Anklam, Elke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulatory landscape of nullotechnology and nulloplastics from a global perspective", "Source Title": "REGULATORY TOXICOLOGY AND PHARMACOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullotechnology and more particularly nullotechnology-based products and materials have provided a huge potential for novel solutions to many of the current challenges society is facing. However, nullotechnology is also an area of product innovation that is sometimes developing faster than regulatory frameworks. This is due to the high complexity of some nullomaterials, the lack of a globally harmonised regulatory definition and the different scopes of regulation at a global level. Research organisations and regulatory bodies have spent many efforts in the last two decades to cope with these challenges. Although there has been a significant advancement related to analytical approaches for labelling purposes as well as to the development of suitable test guidelines for nullomaterials and their safety assessment, there is a still a need for greater global collaboration and consensus in the regulatory field. Furthermore, with growing societal concerns on plastic litter and tiny debris produced by degradation of littered plastic objects, the impact of micro- and nulloplastics on humans and the environment is an emerging issue. Despite increasing research and initial regulatory discussions on micro- and nulloplastics, there are still knowledge gaps and thus an urgent need for action. As nulloplastics can be classified as a specific type of incidental nullomaterials, current and future scientific investigations should take into account the existing profound knowledge on nullotechnology/nullomaterials when discussing issues around nulloplastics. This review was conceived at the 2019 Global Summit on Regulatory Sciences that took place in Stresa, Italy, on 24-26 September 2019 (GSRS 2019) and which was co-organised by the Global Coalition for Regulatory Science Research (GCRSR) and the European Commission's (EC) Joint Research Centre (JRC). The GCRSR consists of regulatory bodies from various countries around the globe including EU bodies. The 2019 Global Summit provided an excellent platform to exchange the latest information on activities carried out by regulatory bodies with a focus on the application of nullotechnology in the agriculture/food sector, on nulloplastics and on nullomedicines, including taking stock and promoting further collaboration. Recently, the topic of micro- and nulloplastics has become a new focus of the GCRSR. Besides discussing the challenges and needs, some future directions on how new tools and methodologies can improve the regulatory science were elaborated by summarising a significant portion of discussions during the summit. It has been revealed that there are still some uncertainties and knowledge gaps with regard to physicochemical properties, environmental behaviour and toxicological effects, especially as testing described in the dossiers is often done early in the product development process, and the material in the final product may behave differently. The harmonisation of methodologies for quantification and risk assessment of nullomaterials and micro/nulloplastics, the documentation of regulatory science studies and the need for sharing databases were highlighted as important aspects to look at.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 139, "Times Cited, All Databases": 143, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 122, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104885, "DOI": "10.1016/j.yrtph.2021.104885", "DOI Link": "http://dx.doi.org/10.1016/j.yrtph.2021.104885", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Legal Medicine; Pharmacology & Pharmacy; Toxicology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000647701300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Gu, Y; Liu, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yuanyuan; Gu, Yan; Liu, Jianlin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A domain-decomposition generalized finite difference method for stress analysis in three-dimensional composite materials", "Source Title": "APPLIED MATHEMATICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, a new framework for stress analysis of three-dimensional (3D) composite (multi-layered) elastic materials is presented. In our computations, the composite material is firstly decomposed into several sub-domains by using the domain-decomposition technique, and then in each of the sub-domain, the stresses are approximated by using a meshless generalized finite difference method (GFDM). Along the sub-domain interfaces, compatibility of displacements and equilibrium of tractions are imposed. The new method yields a sparse and banded matrix system which makes it very attractive for large-scale engineering simulations. Numerical examples with up to 500,000 unknowns are solved successfully using the developed GFDM code. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 147, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 104, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106226, "DOI": "10.1016/j.aml.2020.106226", "DOI Link": "http://dx.doi.org/10.1016/j.aml.2020.106226", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521510800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yuhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co-precipitated Ni/Mn shell coated nullo Cu-rich core structure: A phase-field study", "Source Title": "JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work is to clarify such pending issues as the formation paths, diversity patterns, segregation modes and magnetic effect of Ni/Mn shell-coated Cu-rich particles in Fe-15at. % Cu-1at. %Mn-1at. %Ni alloy by using the phase-field method. It is found that three nucleation mechanisms (classical nucleation, non-classical nucleation and instability decomposition) can coexist in early stage of precipitation, and four kinds of structural patterns of the co -precipitates will appear during the precipitation, growth and coarsening. The Cu-rich nulloparticles gradually transform from bcc-a-Cu to fcc-g-Cu, the Ni/Mn shell maintains bcc structure and may be precipitated on the surface of bcc-a-Cu, or fcc-g-Cu, or both surfaces in a heterogeneous nucleation mode and runs through the whole aging stage. The Ni/Mn shell inhibits the crystal structure transformation of bcc-a-Fe matrix, the internal magnetic energy and coherent elastic strain energy also inhibit phase separation and crystal structure transformation. Therefore, we can obtain the characteristic microstructure of different aging stages by adjusting the aging time, magnetic field and elastic field conditions, so as to obtain different microstructure and corresponding mechanical properties. This work is applicable to multicomponent Fe-Cu based alloys and core-shell structural materials.(c) 2022 North University of China. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV-DEC", "Publication Year": 2022, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 546, "End Page": 560, "Article Number": null, "DOI": "10.1016/j.jmrt.2022.09.032", "DOI Link": "http://dx.doi.org/10.1016/j.jmrt.2022.09.032", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867351100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elgarahy, AM; Mostafa, HY; Zaki, EG; ElSaeed, SM; Elwakeel, KZ; Akhdhar, A; Guibal, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elgarahy, Ahmed M.; Mostafa, Hamida Y.; Zaki, Elsayed G.; ElSaeed, Shymaa M.; Elwakeel, Khalid Z.; Akhdhar, Abdullah; Guibal, Eric", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Methylene blue removal from aqueous solutions using a biochar/gellan gum hydrogel composite: Effect of agitation mode on sorption kinetics", "Source Title": "INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogel membranes are prepared by casting a mixture of gellan gum (associated with PVA) and biochar produced from a local Egyptian plant. The mesoporous material is characterized by a specific surface area close to 134 m2 g-1, a residue of 28 % (at 800 ??C), and a pHPZC close to 6.43. After grinding, the material is tested for Methylene Blue sorption at pH 10.5: sorption capacity reaches 1.70 mmol MB g-1 (synergistic effect of the precursors). The sorption isotherms are fitted by both Langmuir and Sips eqs. MB sorption increases with temperature: the sorption is endothermic (??H??: 12.9 kJ mol- 1), with positive entropy (??S??: 125 J mol- 1 K-1). Uptake kinetics are controlled by agitation speed (optimum X200 rpm) and resistance to intraparticle diffusion. The profiles are strongly affected by the mode of agitation: the equilibrium time (???180 min) is reduced to 20???30 min under sonication (especially at frequency: 80 kHz). The mode of agitation controls the best fitting equation: pseudo-first order rate agitation for mechanical agitation contrary to pseudo-second order rate under sonication. The sorption of MB is poorly affected by ionic strength (loss 6 % in 45 g L-1 NaCl solution). Desorption (faster than sorption) is completely achieved using 0.7 M HCl solution. At the sixth recycling, the loss in sorption is close to 5 % (??? decrease in desorption efficiency). The process is successfully applied for the treatment of MB-spiked industrial solution: the color index decreases by 97 % with a sorbent dose close to 1 g L-1; a higher dose is required for maximum reduction of the COD (60 % at 3 g L-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 53, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2023, "Volume": 232, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123355, "DOI": "10.1016/j.ijbiomac.2023.123355", "DOI Link": "http://dx.doi.org/10.1016/j.ijbiomac.2023.123355", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000924100900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, TZ; Cao, XJ; Jiao, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tongzhou; Cao, Xuejie; Jiao, Lifang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting is a sustainable and feasible strategy for hydrogen production but is hampered by the sluggish anodic oxygen evolution reaction (OER). Herein, an effective approach is introduced to significantly decrease the cell voltage by replacing the anodic OER with a urea oxidation reaction (UOR). A Ni2P/NiMoP nullosheet catalyst with a hierarchical architecture is uniformly grown on a nickel foam (NF) substrate through a simple hydrothermal and phosphorization method. The Ni2P/NiMoP achieves impressive HER activity, with a low overpotential of only 22 mV at 10 mA cm-2 and a low Tafel slope of 34.5 mV dec -1 . In addition, the oxidation voltage is significantly reduced from 1.49 V to 1.33 V after the introduction of 0.33 M urea. Notably, a two-electrode electrolyzer employing Ni2P/NiMoP as a bifunctional catalyst exhibits a current density of 10 mA cm-2 at a cell voltage of 1.35 V and excellent long-term durability after 80 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 292, "Times Cited, All Databases": 300, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 69, "End Page": 74, "Article Number": null, "DOI": "10.1016/j.esci.2021.09.002", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2021.09.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078115900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vassallo, M; Martella, D; Barrera, G; Celegato, F; Coïsson, M; Ferrero, R; Olivetti, ES; Troia, A; Sözeri, H; Parmeggiani, C; Wiersma, DS; Tiberto, P; Manzin, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vassallo, Marta; Martella, Daniele; Barrera, Gabriele; Celegato, Federica; Coisson, Marco; Ferrero, Riccardo; Olivetti, Elena S.; Troia, Adriano; Sozeri, Huseyin; Parmeggiani, Camilla; Wiersma, Diederik S.; Tiberto, Paola; Manzin, Alessandra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improvement of Hyperthermia Properties of Iron Oxide nulloparticles by Surface Coating", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic hyperthermia is an oncological therapy that exploits magnetic nulloparticles activated by radiofrequency magnetic fields to produce a controlled temperature increase in a diseased tissue. The specific loss power (SLP) of magnetic nulloparticles or the capability to release heat can be improved using surface treatments, which can reduce agglomeration effects, thus impacting on local magnetostatic interactions. In this work, Fe3O4 nulloparticles are synthesized via a coprecipitation reaction and fully characterized in terms of structural, morphological, dimensional, magnetic, and hyperthermia properties (under the Hergt- Dutz limit). Different types of surface coatings are tested, comparing their impact on the heating efficacy and colloidal stability, resulting that sodium citrate leads to a doubling of the SLP with a substantial improvement in dispersion and stability in solution over time; an SLP value of around 170 W/g is obtained in this case for a 100 kHz and 48 kA/m magnetic field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2023, "Volume": 8, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2143, "End Page": 2154, "Article Number": null, "DOI": "10.1021/acsomega.2c06244", "DOI Link": "http://dx.doi.org/10.1021/acsomega.2c06244", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000910934800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rubel, MHK; Hossain, MA; Hossain, MK; Hossain, KM; Khatun, AA; Rahaman, M; Rahman, MF; Hossain, MM; Hossain, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rubel, M. H. K.; Hossain, M. A.; Hossain, M. Khalid; Hossain, K. M.; Khatun, A. A.; Rahaman, M.; Rahman, Md. Ferdous; Hossain, M. M.; Hossain, J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First-principles calculations to investigate structural, elastic, electronic, thermodynamic, and thermoelectric properties of CaPd3B4O12 (B = Ti, V) perovskites", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study has explored numerous physical properties of CaPd3Ti4O12 (CPTO) and CaPd3V4O12 (CPVO) quadruple perovskites employing the density functional theory (DFT) method. The calculated lattice constants show inclinable compliance with the experimental results that ensure their structural stability. The mechanical permanence of these two compounds was observed by the Born stability criteria as well. The mechanical and elastic behaviors have been rationalized to investigate elastic constants, bulk, shear, and Young's modulus, Pugh's ratio, Poisson's ratio, and elastic anisotropy indexes. The ductility and anisotropic indexes confirm that both materials are ductile and anisotropic in essence. The band structure of CPTO reveals a 0.88 and 0.46 eV direct narrow band gap while using TB-mBJ and GGA-PBE potentials, respectively, which is an indication of its fascinating semiconducting nature. Whereas, CPVO perovskite exhibits a metallic character. The calculated partial density of states indicates the strong hybridization between Pd-4d and O-2p orbital electrons for CPTO, whereas Pd-4d and V-3d-O-2p for CPVO. The study of the chemical bonding nature and electronic charge distribution graph reveals the coexistence of covalent O-V/Pd bonds, ionic O-Ti/Ca bonds, as well as metallic Ti/V-Ti/V bonding for both compounds. The Fermi surface of CPVO ensures a kind of hole as well as electron faces simultaneously, indicating multifarious band characteristics. The prediction of the static real dielectric function (optical property) of CPTO at zero energy implies its promising dielectric nature. The photoconductivity and absorption coefficient of CPBO display good qualitative compliance with the consequences of band structure computations. The calculated thermodynamic properties manifest the thermodynamical stability for CPBO, whereas phonon dispersions of CPVO exhibit stable phonon dispersion in contrast to slightly unstable phonon dispersion of CPTO. The predicted Debye temperature (theta(D)) has been utilized to correlate its topical features including thermoelectric behaviors. The studied thermoelectric transport properties of CPTO yielded a higher Seebeck coefficient (186 mu V/K), power factor (11.9 mu Wcm(-1)K(-2)), and figure of merit (ZT) value of about 0.8 at 800 K, indicating that this material could be a promising candidate for thermoelectric applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 42, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105977, "DOI": "10.1016/j.rinp.2022.105977", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2022.105977", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888857200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, LJ; Liu, XW; Lv, GC; Zhu, RL; Tian, LT; Liu, M; Li, YX; Rao, WX; Liu, TM; Liao, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Lijuan; Liu, Xuewen; Lv, Guocheng; Zhu, Runliang; Tian, Lintao; Liu, Meng; Li, Yuxin; Rao, Wenxiu; Liu, Tianming; Liao, Libing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study on the adsorption properties of methyl orange by natural one-dimensional nullo-mineral materials with different structures", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methyl orange (MO) is a common anionic azo dye that is harmful to the environment and biology, so it must be treated innocuously before it can be discharged. Adsorption is an effective method to remove anionic dyes. nullotube mineral is a natural one-dimensional adsorption material, and its unique morphology and structure endow it with good adsorption capacity. Although there are many related studies, there is a lack of in-depth discussions on the influence of nullotube's composition and structure on the adsorption of dyes and other pollutants. In this paper, two kinds of natural one-dimensional silicate minerals [halloysite nullotubes (HNTs) and chrysotile nullotubes (ChNTs)] with similar morphology but slightly different compositions and crystal structures were used as adsorbents, and MO solution was used as simulate pollutants. It is the first time to discuss in depth the influence of the composition and structure of nullotube minerals on their charge properties and the adsorption performance of methyl orange dyes. It is found that HNTs and ChNTs have different adsorption capacity due to the difference of electronegativity between Al3+ and Mg2+ in the crystal, so they possess negative and positive charges respectively in near-neutral solution, which leads to the adsorption capacity of MO by ChNTs with positive charges which is greater than that of HNTs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 148, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10640, "DOI": "10.1038/s41598-021-90235-1", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-90235-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000657522700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rifaie-Graham, O; Galensowske, NFB; Dean, C; Pollard, J; Balog, S; Gouveia, MG; Chami, M; Vian, A; Amstad, E; Lattuada, M; Bruns, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rifaie-Graham, Omar; Galensowske, Nikolas F. B.; Dean, Charlie; Pollard, Jonas; Balog, Sandor; Gouveia, Micael G.; Chami, Mohamed; Vian, Antoine; Amstad, Esther; Lattuada, Marco; Bruns, Nico", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Shear Stress-Responsive Polymersome nulloreactors Inspired by the Marine Bioluminescence of Dinoflagellates", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Some marine plankton called dinoflagellates emit light in response to the movement of surrounding water, resulting in a phenomenon called milky seas or sea sparkle. The underlying concept, a shear-stress induced permeabilisation of biocatalytic reaction compartments, is transferred to polymer-based nulloreactors. Amphiphilic block copolymers that carry nucleobases in their hydrophobic block are self-assembled into polymersomes. The membrane of the vesicles can be transiently switched between an impermeable and a semipermeable state by shear forces occurring in flow or during turbulent mixing of polymersome dispersions. Nucleobase pairs in the hydrophobic leaflet separate when mechanical force is applied, exposing their hydrogen bonding motifs and therefore making the membrane less hydrophobic and more permeable for water soluble compounds. This polarity switch is used to release payload of the polymersomes on demand, and to activate biocatalytic reactions in the interior of the polymersomes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2021, "Volume": 60, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 904, "End Page": 909, "Article Number": null, "DOI": "10.1002/anie.202010099", "DOI Link": "http://dx.doi.org/10.1002/anie.202010099", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000588424500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Isobe, H; Xu, SY; Fu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Isobe, Hiroki; Xu, Su-Yang; Fu, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-frequency rectification via chiral Bloch electrons", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rectification is a process that converts electromagnetic fields into a direct current. Such a process underlies a wide range of technologies such as wireless communication, wireless charging, energy harvesting, and infrared detection. Existing rectifiers are mostly based on semiconductor diodes, with limited applicability to small-voltage or high-frequency inputs. Here, we present an alternative approach to current rectification that uses the intrinsic electronic properties of quantum crystals without using semiconductor junctions. We identify a previously unknown mechanism for rectification from skew scattering due to the inherent chirality of itinerant electrons in time-reversal invariant but inversion-breaking materials. Our calculations reveal large, tunable rectification effects in graphene multi-layers and transition metal dichalcogenides. Our work demonstrates the possibility of realizing high-frequency rectifiers by rational material design and quantum wave function engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 6, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaay2497", "DOI": "10.1126/sciadv.aay2497", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aay2497", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000523298500011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lustig, E; Sharabi, Y; Segev, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lustig, Eran; Sharabi, Yonatan; Segev, Mordechai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological aspects of photonic time crystals", "Source Title": "OPTICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We find topological band structures in photonic time crystals-materials in which the refractive index varies periodically and abruptly in time. When the refractive index changes abruptly, the light experiences time refraction and time reflection, analogous to refraction and reflection in photonic crystals. The interference between time-refracted and time-reflected waves gives rise to dispersion bands, which are gapped in the momentum. We show theoretically that photonic time crystals can be in a topologically nontrivial phase, and calculate the topological invariant associated with the momentum bands, which is expressed in the phase between the forward- and backward-propagating waves. When an interface is generated between two time crystals of different topologies, the Zak phase yields a localized interface state, manifested as a localized temporal peak. (C) 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2018, "Volume": 5, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1390, "End Page": 1395, "Article Number": null, "DOI": "10.1364/OPTICA.5.001390", "DOI Link": "http://dx.doi.org/10.1364/OPTICA.5.001390", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450664900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mubeen, K; Irshad, A; Safeen, A; Aziz, U; Safeen, K; Ghani, T; Khan, K; Ali, Z; Ul Haq, I; Shah, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mubeen, Khalida; Irshad, Afshan; Safeen, Akif; Aziz, Uzma; Safeen, Kashif; Ghani, Tayyaba; Khan, Kamran; Ali, Zulfqar; Ul Haq, Ihsan; Shah, Attaullah", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Band structure tuning of ZnO/CuO composites for enhanced photocatalytic activity", "Source Title": "JOURNAL OF SAUDI CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The toxic dye pigments, even in small quantities, can damage ecosystems. Removing organic, inorganic, and microbiological contaminullts from wastewater via heterogeneous photo -catalysis is a promising method. Herein, we report the band structure tuning of ZnO/CuO nullocomposites to enhance photocatalytic activity. The nullocomposites were synthesized by a chemical approach using step-wise implantation of p-type semiconductor CuO to n-type semicon-ductor ZnO. Various characterization techniques such as X-ray diffraction analysis (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray analysis (EDX) and UV spectroscopy were used to investigate the crystal structure, surface morphology, elemental com-position and optical properties of the synthesized samples. As the CuO content increased from 10% to 50% in ZnO/CuO nullocomposites, the optical bandgap decreased from 3.36 to 2.14 eV. The photocatalytic activity of the samples was evaluated against the degradation of methylene blue (MB) under visible irradiation. Our study demonstrates a novel p-n junction oxide photocatalyst based on wt. 10% CuO/ZnO with superior photocatalytic activity. Effectively 66.6% increase in degradation rate was achieved for wt. 10% CuO/ZnO nullocomposite compared to pure ZnO nulloparticles. & COPY; 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 57, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 27, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101639, "DOI": "10.1016/j.jscs.2023.101639", "DOI Link": "http://dx.doi.org/10.1016/j.jscs.2023.101639", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001026956300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, N; Li, WW; Shao, L; Tu, ZB; Chen, YW; Dai, S; Ye, NY; Zhang, JT; Liu, QJ; Wang, JF; Zhang, M; Shi, XX; Wang, TL; Chen, ML; Huang, YQ; Xu, FL; Zhu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Na; Li, Weiwei; Shao, Ling; Tu, Zhibiao; Chen, Yingwei; Dai, Sheng; Ye, Nengyong; Zhang, Jitang; Liu, Qijie; Wang, Jinfang; Zhang, Meng; Shi, Xinxing; Wang, Tianle; Chen, Mengliang; Huang, Yingqi; Xu, Feilong; Zhu, Liu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Comparison of Cold-Sprayed Coatings of Copper-Based Composite Deposited on AZ31B Magnesium Alloy and 6061 T6 Aluminum Alloy Substrates", "Source Title": "MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-coated graphite and copper mixture powders were deposited on AZ31B magnesium alloy and 6061 T6 aluminum alloy substrates under different process parameters by a solid-state cold spray technique. The microstructure of the copper-coated graphite and copper composite coatings was visually examined using photographs taken with an optical microscope and a scanning electron microscope. The surface roughness of the coatings was investigated with a 3D profilometer. The thickness of the coatings was determined through the analysis of the microstructure images, while the adhesion of the coatings was characterized using the scratch test method. The results indicate that the surface roughness of the coatings sprayed on the two different substrates gradually decreases as gas temperature and gas pressure increase. Additionally, the thickness and adhesion of the coatings deposited on the two different substrates both increase with an increase in gas temperature and gas pressure. Comparing the surface roughness, thickness, and adhesion of the coatings deposited on the two different substrates, the surface roughness and adhesion of the coatings on the soft substrate are greater than those of the coatings on the hard substrate, while the thickness of the coatings is not obviously affected by the hardness of the substrate. Furthermore, it is noteworthy that the surface roughness, thickness, and adhesion of the copper-coated graphite and copper composite coatings sprayed on the two different substrates exhibit a distinct linear relationship with particle velocity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 68, "Times Cited, All Databases": 69, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 16, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5120, "DOI": "10.3390/ma16145120", "DOI Link": "http://dx.doi.org/10.3390/ma16145120", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001068098900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rehan, AI; Rasee, AI; Awual, ME; Waliullah, RM; Hossain, MS; Kubra, KT; Salman, MS; Sheikh, MC; Marwani, HM; Khaleque, MA; Islam, A; Awual, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rehan, Ariyan Islam; Rasee, Adiba Islam; Awual, Mrs Eti; Waliullah, R. M.; Hossain, Mohammed Sohrab; Kubra, Khadiza Tul; Salman, Md. Shad; Sheikh, Md. Chanmiya; Marwani, Hadi M.; Khaleque, Md. Abdul; Islam, Aminul; Awual, Md. Rabiul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving toxic dye removal and remediation using novel nullocomposite fibrous adsorbent", "Source Title": "COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with regulated nulloscale morphology provide capabilities to remove dangerous pollutants from wastewater, by adsorption. In this study, the chitosan-based composite fibrous adsorbent was fabricated and used as a novel and facile eliminator in the process of removing cationic methyl orange (MO) from the water medium. Different methods were applied to check the properties of the desired composite fibrous adsorbent. The removal value showed that the chitosan-embedded composite fibrous adsorbent has super characteristics and can be removed the organic dye from the water. The influence of pH, time, temperature, eliminator quantity, and MO content was explored. With increasing time and eliminator quantity, the adsorption efficiency increased. The composite fibrous adsorbent with the advantage of its high functionality and combined micro-nullomorphology features, has emerged as a very promising candidate for obtaining versatile and robust adsorbents. This work presents how the tunned synthesis of composite fibrous adsorbent tailored their nulloarchitecture giving rise to adsorption capacities toward cleaning aqueous samples polluted with MO dye. The composite fibrous adsorbent was prepared by the direct immobilization method, with normal aging temperature, in order to study the effect of synthesis conditions on the adsorption properties of MO dye. The solution acidity was exhibited as the key factor, and a suitable pH of 5.50 was selected based on the efficiency. The competing ions were not adversely affected in the dye adsorption as defined by the stable bonding mechanism. The adsorption data were highly fitted with the Langmuir adsorption model with monolayer coverage. The determined maximum adsorption was 175.45 mg/g, which was comparable with the other forms of materials. The adsorbed MO dye elution was evaluated using ethanol and then the composite fibrous adsorbent was ready to use for MO dye adsorption after washing with water without significant loss in its functionality. Therefore, we explored the tunned morphology of composite fibrous adsorbent for obtaining performant adsorbents for the elimination of refractory pollutants in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2023, "Volume": 673, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 131859, "DOI": "10.1016/j.colsurfa.2023.131859", "DOI Link": "http://dx.doi.org/10.1016/j.colsurfa.2023.131859", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001144186400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zanatta, AR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zanatta, A. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revisiting the optical bandgap of semiconductors and the proposal of a unified methodology to its determination", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Along the last two centuries, the story of semiconductor materials ranged from a mix of disbelief and frustration to one of the most successful technological achievements ever seen. Such a progress comprised the development of materials and models that, allied to the knowledge provided by spectroscopic techniques, resulted in the (nowadays) omnipresent electronic gadgets. Within this context, optically-based methods were of special importance since, amongst others, they presented details about the electronic states and energy bandgap E-gap of semiconductors which, ultimately, decided about their application in devices. Stimulated by these aspects, this work investigated the semiconductors silicon, germanium, and gallium-arsenide in the crystalline (bulk and powder) and amorphous (film) forms. The detailed analysis of the experimental results indicates that accurate E-gap values can be obtained by fitting a sigmoid (Boltzmann) function to their corresponding optical absorption spectra. The method is straightforward and, contrary to the traditional approaches to determine E-gap, it is exempt from errors due to experimental spectra acquisition and data processing. Additionally, it complies with the requirements of direct, indirect, and amorphous bandgap semiconductors, and it is able to probe the (dis)order of the material as well. In view of these characteristics, a new-unified methodology based on the fitting of the absorption spectrum with a Boltzmann function is being proposed to efficiently determine the optical bandgap of semiconductor materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 276, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2019, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11225, "DOI": "10.1038/s41598-019-47670-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-019-47670-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478575000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, Y; Tice, MM; Schmidt, ME; Treiman, AH; Kizovski, TV; Hurowitz, JA; Allwood, AC; Henneke, J; Pedersen, DAK; VanBommel, SJ; Jones, MWM; Knight, AL; Orenstein, BJ; Clark, BC; Elam, WT; Heirwegh, CM; Barber, T; Beegle, LW; Benzerara, K; Bernard, S; Beyssac, O; Bosak, T; Brown, AJ; Cardarelli, EL; Catling, DC; Christian, JR; Cloutis, EA; Cohen, BA; Davidoff, S; Fairen, AG; Farley, KA; Flannery, DT; Galvin, A; Grotzinger, JP; Gupta, S; Hall, J; Herd, CDK; Hickman-Lewis, K; Hodyss, RP; Horgan, BHN; Johnson, JR; Jorgensen, JL; Kah, LC; Maki, JN; Mandon, L; Mangold, N; McCubbin, FM; McLennull, SM; Moore, K; Nachon, M; Nemere, P; Nothdurft, LD; Nunez, JI; O'Neil, L; Quantin-Nataf, CM; Sautter, V; Shuster, DL; Siebach, KL; Simon, JI; Sinclair, KP; Stack, KM; Steele, A; Tarnas, JD; Tosca, NJ; Uckert, K; Udry, A; Wade, LA; Weiss, BP; Wiens, RC; Williford, KH; Zorzano, MP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Y.; Tice, M. M.; Schmidt, M. E.; Treiman, A. H.; Kizovski, T. V.; Hurowitz, J. A.; Allwood, A. C.; Henneke, J.; Pedersen, D. A. K.; VanBommel, S. J.; Jones, M. W. M.; Knight, A. L.; Orenstein, B. J.; Clark, B. C.; Elam, W. T.; Heirwegh, C. M.; Barber, T.; Beegle, L. W.; Benzerara, K.; Bernard, S.; Beyssac, O.; Bosak, T.; Brown, A. J.; Cardarelli, E. L.; Catling, D. C.; Christian, J. R.; Cloutis, E. A.; Cohen, B. A.; Davidoff, S.; Fairen, A. G.; Farley, K. A.; Flannery, D. T.; Galvin, A.; Grotzinger, J. P.; Gupta, S.; Hall, J.; Herd, C. D. K.; Hickman-Lewis, K.; Hodyss, R. P.; Horgan, B. H. N.; Johnson, J. R.; Jorgensen, J. L.; Kah, L. C.; Maki, J. N.; Mandon, L.; Mangold, N.; McCubbin, F. M.; McLennull, S. M.; Moore, K.; Nachon, M.; Nemere, P.; Nothdurft, L. D.; Nunez, J. I.; O'Neil, L.; Quantin-Nataf, C. M.; Sautter, V.; Shuster, D. L.; Siebach, K. L.; Simon, J. I.; Sinclair, K. P.; Stack, K. M.; Steele, A.; Tarnas, J. D.; Tosca, N. J.; Uckert, K.; Udry, A.; Wade, L. A.; Weiss, B. P.; Wiens, R. C.; Williford, K. H.; Zorzano, M. -P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An olivine cumulate outcrop on the floor of Jezero crater, Mars", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The geological units on the floor of Jezero crater, Mars, are part of a wider regional stratigraphy of olivine-rich rocks, which extends well beyond the crater. We investigated the petrology of olivine and carbonate-bearing rocks of the Seitah formation in the floor of Jezero. Using multispectral images and x-ray fluorescence data, acquired by the Perseverance rover, we performed a petrographic analysis of the Bastide and Brac outcrops within this unit. We found that these outcrops are composed of igneous rock, moderately altered by aqueous fluid. The igneous rocks are mainly made of coarse-grained olivine, similar to some martian meteorites. We interpret them as an olivine cumulate, formed by settling and enrichment of olivine through multistage cooling of a thick magma body.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 88, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 30", "Publication Year": 2022, "Volume": 377, "Issue": 6614, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1513, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abo2756", "DOI Link": "http://dx.doi.org/10.1126/science.abo2756", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891713300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ilic, S; Bergeret, FS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ilic, S.; Bergeret, F. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Theory of the Supercurrent Diode Effect in Rashba Superconductors with Arbitrary Disorder", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We calculate the nonreciprocal critical current and quantify the supercurrent diode effect in twodimensional Rashba superconductors with arbitrary disorder, using the quasiclassical Eilenberger equation. The nonreciprocity is caused by the helical superconducting state, which appears when both inversion and time-reversal symmetries are broken. In the absence of disorder, we find a very strong diode effect, with the nonreciprocity exceeding 40% at optimal temperatures, magnetic fields, and spin-orbit coupling. We establish that the effect persists even in the presence of strong disorder. We show that the sign of the diode effect changes as magnetic field and disorder are increased, reflecting the changes in the nature of the helical state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 115, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 128, "Issue": 17, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 177001, "DOI": "10.1103/PhysRevLett.128.177001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.128.177001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000804588400009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Po, HC; Watanabe, H; Vishwanath, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Po, Hoi Chun; Watanabe, Haruki; Vishwanath, Ashvin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fragile Topology and Wannier Obstructions", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological phases, such as Chern insulators, are defined in terms of additive indices that are stable against the addition of trivial degrees of freedom. Such topology presents an obstruction to any Wannier representation, namely, the representation of the electronic states in terms of symmetric, exponentially localized Wannier functions. Here, we address the converse question: Do obstructions to Wannier representation imply stable band topology? We answer this in the negative, pointing out that some bands can also display a distinct type of fragile topology. Bands with fragile topology do not admit any Wannier representation by themselves, but such a representation becomes possible once certain additional trivial degrees of freedom are supplied. We construct a physical model of fragile topology on the honeycomb lattice that also helps resolve a recent puzzle in band theory. This model provides a counterexample to the assumption that splitting of an elementary band representation introduced in [B. Bradlyn et al., Topological quantum chemistry, Nature (London) 547, 298 (2017)] leads to bands that are individually topological. Instead, half of the split bands of our model realize a trivial band with exponentially localized symmetric Wannier functions, whereas the second half possess fragile topology. Our work highlights an important and previously overlooked connection between band structure and Wannier functions, and is expected to have far-reaching consequences given the central role played by Wannier functions in the modeling of real materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 273, "Times Cited, All Databases": 293, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 18", "Publication Year": 2018, "Volume": 121, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 126402, "DOI": "10.1103/PhysRevLett.121.126402", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.126402", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444961000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Awual, E; Salman, MS; Hasan, MM; Hasan, MN; Kubra, KT; Sheikh, MC; Rasee, AI; Rehan, AI; Waliullah, RM; Hossain, MS; Marwani, HM; Asiri, AM; Rahman, MM; Islam, A; Khaleque, MA; Awual, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Awual, Eti; Salman, Md Shad; Hasan, Md Munjur; Hasan, Md Nazmul; Kubra, Khadiza Tul; Sheikh, Md Chanmiya; Rasee, Adiba Islam; Rehan, Ariyan Islam; Waliullah, R. M.; Hossain, Mohammed Sohrab; Marwani, Hadi M.; Asiri, Abdullah M.; Rahman, Mohammed M.; Islam, Aminul; Khaleque, Md Abdul; Awual, Md Rabiul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand imprinted composite adsorbent for effective Ni(II) ion monitoring and removal from contaminated water", "Source Title": "JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heavy metal especially nickel (Ni(II)) is the most pernicious kind of pollution since it is both poisonous and difficult to break down in nature and can cause many human disorders and diseases. The monitoring and removal of Ni(II) ions optically is required to enhance the quality of the water and make it appropriate for drinking as well as other uses around the residence. Therefore, the goal of the current work was to synthesize ligand imprinted composite adsorbent (MCA) and utilize it as an adsorbent to monitor and remove Ni(II) ions from the water. Based on the findings gathered, the MCA that was synthesized had a large particle size with a high surface area even after the ligand impregnation. The MCA was enhanced significantly in color with the contact of Ni(II) ion with limit detection at 0.35 mu g/L. The maximum level of Ni(II) ions was eliminated (99 %) when the pH was adjusted to 5.50. The Langmuir model was also used to study the adsorption equilibrium data and the maximum adsorption capacity was 167.55 mg/g. Additionally, the method can selectively detect and remove Ni(II) even in the presence of diverse metal ions. Overall, the MCA offers an ideal platform for the on-site monitoring and removal of heavy metal ions, especially in resource-limited areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2024, "Volume": 131, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 585, "End Page": 592, "Article Number": null, "DOI": "10.1016/j.jiec.2023.10.062", "DOI Link": "http://dx.doi.org/10.1016/j.jiec.2023.10.062", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142454000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Qiu, JY; Wang, XD; Chen, L; Cao, GP; Wang, JL; Zhang, H; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Li; Qiu, Jingyi; Wang, Xiaodan; Chen, Long; Cao, Gaoping; Wang, Jianlong; Zhang, Hao; He, Xiangming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Insights for understanding multiscale degradation of LiFePO4 cathodes", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries (LIBs) based on olivine LiFePO4 (LFP) offer long cycle/calendar life and good safety, making them one of the dominullt batteries in energy storage stations and electric vehicles, especially in China. Yet scientists have a weak understanding of LFP cathode degradation, which restricts the further development of LFP materials and batteries. Here, we critically review reports on LFP cathode degradation with respect to different electric parameters (including C-rates, storage, and long cycling), mechanical stresses, and thermal fields. The detailed chemical and physical aspects of degradation mechanisms at various scales (i.e., from atomic to devices) and their causes are comprehensively summarized, and discussions of related concerns are provided in each section. We close with a systematic overview of LFP degradation research and mediation strategies, suggesting future directions for developing robust, safe LFP batteries with long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 120, "Times Cited, All Databases": 125, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 125, "End Page": 137, "Article Number": null, "DOI": "10.1016/j.esci.2022.03.006", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.03.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080874600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Raizada, P; Sudhaik, A; Patial, S; Hasija, V; Khan, AAP; Singh, P; Gautam, S; Kaur, M; Nguyen, VH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Raizada, Pankaj; Sudhaik, Anita; Patial, Shilpa; Hasija, Vasudha; Khan, Aftab Aslam Parwaz; Singh, Pardeep; Gautam, Sourav; Kaur, Manpreet; Van-Huy Nguyen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering nullostructures of CuO-based photocatalysts for water treatment: Current progress and future challenges", "Source Title": "ARABIAN JOURNAL OF CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nowadays, increasing extortions regarding environmental problems and energy scarcity have stuck the development and endurance of human society. The issue of inorganic and organic pollutants that exist in water from agricultural, domestic, and industrial activities has directed the development of advanced technologies to address the challenges of water scarcity efficiently. To solve this major issue, various scientists and researchers are looking for novel and effective technologies that can efficiently remove pollutants from wastewater. nulloscale metal oxide materials have been proposed due to their distinctive size, physical and chemical properties along with promising applications. Cupric Oxide (CuO) is one of the most commonly used benchmark photocatalysts in photodegradation owing to the fact that they are cost-effective, non-toxic, and more efficient in absorption across a significant fraction of solar spectrum. In this review, we have summarized synthetic strategies of CuO fabrication, modification methods with applications for water treatment purposes. Moreover, an elaborative discussion on feasible strategies includes; binary and ternary heterojunction formation, Z-scheme based photocatalytic system, incorporation of rare earth/transition metal ions as dopants, and carbonaceous materials serving as a support system. The mechanistic insight inferring photo-induced charge separation and transfer, the functional reactive radical species involved in a photocatalytic reaction, have been successfully featured and examined. Finally, a conclusive remark regarding current studies and unresolved challenges related to CuO are put forth for future perspectives. (C) 2020 The Author(s). Published by Elsevier B.V. on behalf of King Saud University.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 230, "Times Cited, All Databases": 232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2020, "Volume": 13, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8424, "End Page": 8457, "Article Number": null, "DOI": "10.1016/j.arabjc.2020.06.031", "DOI Link": "http://dx.doi.org/10.1016/j.arabjc.2020.06.031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000583851900064", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PF; Dai, X; Xu, P; Hu, SJ; Xiong, XY; Zou, KY; Guo, SW; Sun, JJ; Zhang, CF; Liu, YN; Zhou, TF; Chen, YZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Peifan; Dai, Xin; Xu, Peng; Hu, Sijiang; Xiong, Xuyang; Zou, Kunyang; Guo, Shengwu; Sun, Junjie; Zhang, Chaofeng; Liu, Yongning; Zhou, Tengfei; Chen, Yuanzhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hierarchical and lamellar porous carbon as interconnected sulfur host and polysulfide-proof interlayer for Li-S batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A robust three-dimensional (3D) interconnected sulfur host and a polysulfide-proof interlayer are key components in high-performance Li-S batteries. Herein, cellulose-based 3D hierarchical porous carbon (HPC) and twodimensional (2D) lamellar porous carbon (LPC) are employed as the sulfur host and polysulfide-proof interlayer, respectively, for a Li-S battery. The 3D HPC displays a cross-linked macroporous structure, which allows high sulfur loading and restriction capability and provides unobstructed electrolyte diffusion channels. With a stackable carbon sheet of 2D LPC that has a large plane view size and is ultrathin and porous, the LPC-coated separator effectively inhibits polysulfides. An optimized combination of the HPC and LPC yields an electrode structure that effectively protects the lithium anode against corrosion by polysulfides, giving the cell a high capacity of 1339.4 mAh g-1 and high stability, with a capacity decay rate of 0.021% per cycle at 0.2C. This work provides a new understanding of biomaterials and offers a novel strategy to improve the performance of Li-S batteries for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100088, "DOI": "10.1016/j.esci.2022.100088", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.100088", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081057800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sardari, PT; Mohammed, HI; Giddings, D; Walker, GS; Gillott, M; Grant, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sardari, Pouyan Talebizadeh; Mohammed, Hayder I.; Giddings, Donald; Walker, Gavin S.; Gillott, Mark; Grant, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical study of a multiple-segment metal foam-PCM latent heat storage unit: Effect of porosity, pore density and location of heat source", "Source Title": "ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study numerically investigates the performance of the melting process for a PCM based heat storage system under the effect of different variables in a vertical container with a copper metal foam. Different cases were studied and compared including the effects of variable porosities and pore densities, non-equilibrium porous medium model, a multiple-segment metal foam case and different heater locations in the system on the liquid fraction and temperature as presented by contour plots and diagrams. The results show high performance for the copper foam-PCM unit compared with on its own PCM, for reducing the melting time by almost 85%. By changing the location of constant temperature heater from the bottom to the side and top surface, the melting time decreases by 70.5% and 4.7%, respectively. By using a multiple-segment porous system, the melting time reduces by 3.5% compared with the case of uniform porosity. Furthermore, the more accurate non-equilibrium numerical model shows a 7.4% difference in the melting time compared with the equilibrium model. This study optimises the design to improve practical application performance and to reduce waste energy. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 178, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 15", "Publication Year": 2019, "Volume": 189, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116108, "DOI": "10.1016/j.energy.2019.116108", "DOI Link": "http://dx.doi.org/10.1016/j.energy.2019.116108", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000506901100090", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, JZ; Cao, XF; Sun, T; Fan, J; Miao, H; Chen, Z; Li, D; Liu, EZ; Zhu, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Jingzhuo; Cao, Xiaofei; Sun, Tao; Fan, Jun; Miao, Hui; Chen, Zhong; Li, Dong; Liu, Enzhou; Zhu, Yonghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-scheme Co3(PO4)2/Twinned-Cd0.5Zn0.5S homo-heterojunction for enhanced photocatalytic H2 evolution", "Source Title": "CHEMICAL ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heterojunction photocatalysts have been demonstrated to be effective for the interfacial charge transfer and utilization, if the charge transfer in bulk phase can be promoted, more photoinduced charges can be utilized to achieve a higher efficiency of light energy conversion. Herein, twinned-Cd0.5Zn0.5S (T-CZS) homojunction formed by zinc blende Cd0.5Zn0.5S (ZB-CZS) and wurtzite Cd0.5Zn0.5S (WZ-CZS) is obtained via a facile hydrothermal method, and then Co-3(PO4)(2) is introduced to the surface of T-CZS to form homo-heterojunction using a solvent evaporation strategy. The photocatalytic H-2 evolution tests show that the activity of T-CZS is obviously higher than ZB-CZS or WZ-CZS, and Co-3(PO4)(2) can increase the H-2 releasing rate of T-CZS from 13.0 mmol center dot h(-1)center dot g(-1) to 64.8 mmol center dot h(-1)center dot g(-1) over 5.7 wt% Co-3(PO4)(2)/T-CZS. The apparent quantum efficiency (AQE) can reach 6.4% under 400 nm light irradiation. Under 800 nm near-infrared light (NIR), the H-2 releasing rate can reach 0.23 mmol center dot h(-1)center dot g(-1). The investigation shows that the carrier transfer between T-CZS and Co-3(PO4)(2) follows the S-scheme transfer path according to the electron paramagnetic resonullce spectroscopy analysis and calculation by density flooding theory (DFT) The enhanced activity of Co-3(PO4)(2)/T-CZS can be mainly attributed to the homo-heterojunction synergistic effect between ZB-CZS/WZ-CZS homojunction in T-CZS and the S-scheme heterojunction between T-CZS and Co-3(PO4)(2), which well avoids the rapid recombination of bulk and surface electron-hole pairs by accelerating charge transfer. Meanwhile, the improved light-harvesting ability, more active sites and lower H-2 production overpotential induced by Co-3(PO4)(2), jointly contribute to a quick kinetics of H-2 evolution. In addition, other metal phosphates MPO4 (M = Ba, Bi, Ag and Zn) are also employed to enhance the activity of T-CZS, they are all effective candidates for construction homo-heterojunction with T-CZS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2023, "Volume": 471, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 144587, "DOI": "10.1016/j.cej.2023.144587", "DOI Link": "http://dx.doi.org/10.1016/j.cej.2023.144587", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001163264900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, X; Yu, XY; Wang, LP; Zeng, YH; Mao, LH; Liu, SM; Xie, HH; He, GC; Huang, ZQ; Liu, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Xiang; Yu, Xinyang; Wang, Liping; Zeng, Yuhui; Mao, Linghan; Liu, Shanming; Xie, Honghui; He, Guichun; Huang, Zhiqiang; Liu, Zhilin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation of cinnamic hydroxamic acid collector and study on flotation characteristics and mechanism of scheelite", "Source Title": "INTERNATIONAL JOURNAL OF MINING SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, using methyl cinnamate as raw material, the new cinnamic hydroxamic acid collector (CIHA) was synthesized by the hydroxylamine method. The collector performance of hydroxamic acid was investigated for scheelite and gangue calcite, and the flotation separation test of scheelite and calcite was carried out with CIHA as the collector. The interaction mechanism between hydroxamic acid and scheelite minerals has also been investigated through zeta potential, Fourier transform infrared spectroscopy (FTIR) experiments, X-ray photoelectron spectroscopy (XPS) experiments, and density functional theory (DFT) calculation. The single mineral flotation test and artificially mixed ore showed that CIHA had an excellent collection effect and selectivity. Zeta potential, FTIR, and XPS showed that CIHA was adsorbed on the scheelite surface by strong chemical adsorption. The active group of CIHA was analyzed through quantum chemical calculation. It was speculated that C@O and NAO bonds could synthesize a five-membered chelated hydroxamic acid group with Ca element chelate on scheelite surface, changing hydrophobicity and making it more likely to emerge from the pulp. & COPY; 2023 Published by Elsevier B.V. on behalf of China University of Mining & Technology. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 46, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 33, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 773, "End Page": 781, "Article Number": null, "DOI": "10.1016/j.ijmst.2022.11.009", "DOI Link": "http://dx.doi.org/10.1016/j.ijmst.2022.11.009", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mining & Mineral Processing", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001035399400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alanazi, A; Yekeen, N; Ali, M; Ali, M; Abu-Mahfouz, IS; Keshavarz, A; Iglauer, S; Hoteit, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alanazi, Amer; Yekeen, Nurudeen; Ali, Mujahid; Ali, Muhammad; Abu-Mahfouz, Israa S.; Keshavarz, Alireza; Iglauer, Stefan; Hoteit, Hussein", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Influence of organics and gas mixing on hydrogen/brine and methane/brine wettability using Jordanian oil shale rocks: Implications for hydrogen geological storage", "Source Title": "JOURNAL OF ENERGY STORAGE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The substitution of fossil fuel with clean hydrogen (H2) has been identified as a promising route to achieve net zero carbon emissions by this century. However, enough H2 must be stored underground at an industrial scale to achieve this objective due to the low volumetric energy density of H2. In underground H2 storage, cushion gases, such as methane (CH4), are required to maintain a safe operational formation pressure during the withdrawal or injection of H2. The wetting characteristics of geological formations in the presence of H2, cushion gas, and the resultant gas mixture in the mixing zone between them are essential for determining storage capacities. Therefore, the present work measured the contact angles of four Jordanian oil shale rocks with H2, CH4, and H2- CH4/brine mixture systems and their interfacial tension (IFT) in geological storage (geo-storage) conditions (pressures of 0.1 to 1600 psi and temperature at 323 K) to evaluate the residual and structural trapping potential and efficiency of CH4 as a cushion gas. Various analytical methods were employed to comprehend the bulk mineralogy, elemental composition, topographic characterization, functional groups, and surface properties of the Jordanian oil shale rocks. The total organic carbon (TOC) effect on wettability was demonstrated and compared with previous studies. The Jordanian oil shale samples with high to ultrahigh TOC of 13 % to 18 % exhibited high brine advancing/receding contact angles. The rock samples became hydrophobic at the highest experimental pressure and temperature conditions (1600 psi and 323 K). The rock/CH4/brine contact angles were higher than the rock/H2/brine contact angles, and the H2-CH4/brine mixture contact angles remained in between those for pure gases. Moreover, the IFT displayed the inverse trend, where the H2/brine IFT measured higher than the CH4/brine IFT. The results suggest that the H2 geo-storage in the tested organic-rich source rocks could be favorable when CH4 is used as a cushion gas, consistent with previous studies using synthetically acid -aged shale samples. For the first time, the present work used organic-rich rocks from Jordanian oil shale to present a more realistic situation and evaluate the influence of missing organic material and gas on the H2/brine/ rock wettability during H2 geo-storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 54, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 62, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106865, "DOI": "10.1016/j.est.2023.106865", "DOI Link": "http://dx.doi.org/10.1016/j.est.2023.106865", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000939813900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, WS; Wei, W; Zhu, HW; Hu, YJ; Jiang, H; Li, CZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Wenshuai; Wei, Wu; Zhu, Huawei; Hu, Yanjie; Jiang, Hao; Li, Chunzhong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In situ surface engineering enables high interface stability and rapid reaction kinetics for Ni-rich cathodes", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered oxide cathodes with high Ni content promise high energy density and competitive cost for Li-ion batteries (LIBs). However, Ni-rich cathodes suffer from irreversible interface reconstruction and undesirable cracking with severe performance degradation upon long-term operation, especially at elevated temperatures. Herein, we demonstrate in situ surface engineering of Ni-rich cathodes to construct a dual ion/electron-conductive NiTiO3 coating layer and Ti gradient doping (NC90-Ti@NTO) in parallel. The dual-modification synergy helps to build a thin, robust cathode-electrolyte interface with rapid Li-ion transport and enhanced reaction kinetics, and effec-tively prevents unfavorable crystalline phase transformation during long-term cycling under harsh environments. The optimized NC90-Ti@NTO delivers a high reversible capacity of 221.0 mAh g-1 at 0.1C and 158.9 mAh g-1 at 10C. Impressively, it exhibits a capacity retention of 88.4% at 25 degrees C after 500 cycles and 90.7% at 55 degrees C after 300 cycles in a pouch-type full battery. This finding provides viable clues for stabilizing the lattice and interfacial chemistry of Ni-rich cathodes to achieve durable LIBs with high energy density.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 94, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100082, "DOI": "10.1016/j.esci.2022.10.008", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.10.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078542400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dell'Isola, F; Giorgio, I; Pawlikowski, M; Rizzi, NL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "dell'Isola, F.; Giorgio, I.; Pawlikowski, M.; Rizzi, N. L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large deformations of planar extensible beams and pantographic lattices: heuristic homogenization, experimental and numerical examples of equilibrium", "Source Title": "PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this paper is to find a computationally efficient and predictive model for the class of systems that we call 'pantographic structures'. The interest in these materials was increased by the possibilities opened by the diffusion of technology of three-dimensional printing. They can be regarded, once choosing a suitable length scale, as families of beams (also called fibres) interconnected to each other by pivots and undergoing large displacements and large deformations. There are, however, relatively few 'ready-to-use' results in the literature of nonlinear beam theory. In this paper, we consider a discrete spring model for extensible beams and propose a heuristic homogenization technique of the kind first used by Piola to formulate a continuum fully nonlinear beam model. The homogenized energy which we obtain has some peculiar and interesting features which we start to describe by solving numerically some exemplary deformation problems. Furthermore, we consider pantographic structures, find the corresponding homogenized second gradient deformation energies and study some planar problems. Numerical solutions for these two-dimensional problems are obtained via minimization of energy and are compared with some experimental measurements, in which elongation phenomena cannot be neglected.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 298, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2016, "Volume": 472, "Issue": 2185, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 20150790, "DOI": "10.1098/rspa.2015.0790", "DOI Link": "http://dx.doi.org/10.1098/rspa.2015.0790", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368479000025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HM; Khaliullin, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huimei; Khaliullin, Giniyat", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pseudospin exchange interactions in d7 cobalt compounds: Possible realization of the Kitaev model", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The current efforts to find the materials hosting Kitaev model physics have been focused on Mott insulators of d(5) pseudospin-1/2 ions Ir4+ and Ru3+ with t(2g)(5) (S = 1/2, L = 1) electronic configuration. Here we propose that the Kitaev model can be realized in materials based on d(7) ions with t(2g)(5) e(g)(2) (S = 3/2, L = 1) configuration such as Co2+, which also host the pseudospin-1/2 magnetism. Considering possible exchange processes, we have derived the d(7) pseudospin-1/2 interactions in 90 degrees bonding geometry. The obtained Hamiltonian comprises the bond-directional Kitaev K and isotropic Heisenberg J interactions as in the case of d(5) ions. However, we find that the presence of additional spin-active e(g) electrons radically changes the balance between Kitaev and Heisenberg couplings. Most remarkably, we show that the exchange processes involving e(g) spins are highly sensitive to whether the system is in Mott (U < Delta) or charge-transfer (U > Delta) insulating regime. In the latter case, to which many cobalt compounds do actually belong, the antiferromagnetic Heisenberg coupling J is strongly suppressed and spin-liquid phase can be stabilized. The results suggest cobalt-based materials as promising candidates for the realization of the Kitaev model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2018, "Volume": 97, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14407, "DOI": "10.1103/PhysRevB.97.014407", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.014407", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419613800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Behler, J; Csányi, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Behler, Joerg; Csanyi, Gabor", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning potentials for extended systems: a perspective", "Source Title": "EUROPEAN PHYSICAL JOURNAL B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the past two and a half decades machine learning potentials have evolved from a special purpose solution to a broadly applicable tool for large-scale atomistic simulations. By combining the efficiency of empirical potentials and force fields with an accuracy close to first-principles calculations they now enable computer simulations of a wide range of molecules and materials. In this perspective, we summarize the present status of these new types of models for extended systems, which are increasingly used for materials modelling. There are several approaches, but they all have in common that they exploit the locality of atomic properties in some form. Long-range interactions, most prominently electrostatic interactions, can also be included even for systems in which non-local charge transfer leads to an electronic structure that depends globally on all atomic positions. Remaining challenges and limitations of current approaches are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 134, "Times Cited, All Databases": 140, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 94, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1140/epjb/s10051-021-00156-1", "DOI Link": "http://dx.doi.org/10.1140/epjb/s10051-021-00156-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000691561500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, HT; Fu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Huitao; Fu, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantum Oscillation from In-Gap States and a Non-Hermitian Landau Level Problem", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by recent experiments on Kondo insulators, we theoretically study quantum oscillations from disorder-induced in-gap states in small-gap insulators. By solving a non-Hermitian Landau level problem that incorporates the imaginary part of electron's self-energy, we show that the oscillation period is determined by the Fermi surface area in the absence of the hybridization gap, and we derive an analytical formula for the oscillation amplitude as a function of the indirect band gap, scattering rates, and temperature. Over a wide parameter range, we find that the effective mass is controlled by scattering rates, while the Dingle factor is controlled by the indirect band gap. We also show the important effect of scattering rates in reshaping the quasiparticle dispersion in connection with angle-resolved photoemission measurements on heavy fermion materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2018, "Volume": 121, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 26403, "DOI": "10.1103/PhysRevLett.121.026403", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.121.026403", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438191700021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Prandini, G; Marrazzo, A; Castelli, IE; Mounet, N; Marzari, N", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Prandini, Gianluca; Marrazzo, Antimo; Castelli, Ivano E.; Mounet, Nicolas; Marzari, Nicola", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Precision and efficiency in solid-state pseudopotential calculations", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the enormous success and popularity of density-functional theory, systematic verification and validation studies are still limited in number and scope. Here, we propose a protocol to test publicly available pseudopotential libraries, based on several independent criteria including verification against all-electron equations of state and plane-wave convergence tests for phonon frequencies, band structure, cohesive energy and pressure. Adopting these criteria we obtain curated pseudopotential libraries (named SSSP or standard solid-state pseudopotential libraries), that we target for high-throughput materials screening (SSSP efficiency) and high-precision materials modelling (SSSP precision). This latter scores highest among open-source pseudopotential libraries available in the.-factor test of equations of states of elemental solids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 547, "Times Cited, All Databases": 576, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 6", "Publication Year": 2018, "Volume": 4, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 72, "DOI": "10.1038/s41524-018-0127-2", "DOI Link": "http://dx.doi.org/10.1038/s41524-018-0127-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452923300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hamidi, A; Houari, MSA; Mahmoud, SR; Tounsi, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hamidi, Ahmed; Houari, Mohammed Sid Ahmed; Mahmoud, S. R.; Tounsi, Abdelouahed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A sinusoidal plate theory with 5-unknowns and stretching effect for thermomechanical bending of functionally graded sandwich plates", "Source Title": "STEEL AND COMPOSITE STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this research, a simple but accurate sinusoidal plate theory for the thermomechanical bending analysis of functionally graded sandwich plates is presented. The main advantage of this approach is that, in addition to incorporating the thickness stretching effect, it deals with only 5 unknowns as the first order shear deformation theory (FSDT), instead of 6 as in the well-known conventional sinusoidal plate theory (SPT). The material properties of the sandwich plate faces are assumed to vary according to a power law distribution in terms of the volume fractions of the constituents. The core layer is made of an isotropic ceramic material. Comparison studies are performed to check the validity of the present results from which it can be concluded that the proposed theory is accurate and efficient in predicting the thermomechanical behavior of functionally graded sandwich plates. The effect of side-to-thickness ratio, aspect ratio, the volume fraction exponent, and the loading conditions on the thermomechanical response of functionally graded sandwich plates is also investigated and discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 18, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 235, "End Page": 253, "Article Number": null, "DOI": "10.12989/scs.2015.18.1.235", "DOI Link": "http://dx.doi.org/10.12989/scs.2015.18.1.235", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350121700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ourari, S; Dusanowski, L; Horvath, SP; Uysal, MT; Phenicie, CM; Stevenson, P; Raha, M; Chen, ST; Cava, RJ; de Leon, NP; Thompson, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ourari, Salim; Dusanowski, Lukasz; Horvath, Sebastian P.; Uysal, Mehmet T.; Phenicie, Christopher M.; Stevenson, Paul; Raha, Mouktik; Chen, Songtao; Cava, Robert J.; de Leon, Nathalie P.; Thompson, Jeff D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Indistinguishable telecom band photons from a single Er ion in the solid state", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic defects in the solid state are a key component of quantum repeater networks for long-distance quantum communication(1). Recently, there has been significant interest in rare earth ions(2-4), in particular Er3+ for its telecom band optical transition(5-7) that allows long-distance transmission in optical fibres. However, the development of repeater nodes based on rare earth ions has been hampered by optical spectral diffusion, precluding indistinguishable single-photon generation. Here, we implant Er3+ into CaWO4, a material that combines a non-polar site symmetry, low decoherence from nuclear spins(8) and is free of background rare earth ions, to realize significantly reduced optical spectral diffusion. For shallow implanted ions coupled to nullophotonic cavities with large Purcell factor, we observe single-scan optical linewidths of 150 kHz and long-term spectral diffusion of 63 kHz, both close to the Purcell-enhanced radiative linewidth of 21 kHz. This enables the observation of Hong-Ou-Mandel interference(9) between successively emitted photons with a visibility of V = 80(4)%, measured after a 36 km delay line. We also observe spin relaxation times T-1,T-s = 3.7 s and T-2,T-s > 200 mu s, with the latter limited by paramagnetic impurities in the crystal instead of nuclear spins. This represents a notable step towards the construction of telecom band quantum repeater networks with single Er3+ ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 54, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 31", "Publication Year": 2023, "Volume": 620, "Issue": 7976, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 977, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06281-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06281-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001063488500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Armstrong, S; Breschi, L; Özcan, M; Pfefferkorn, F; Ferrari, M; Van Meerbeek, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Armstrong, Steve; Breschi, Lorenzo; Ozcan, Mutlu; Pfefferkorn, Frank; Ferrari, Marco; Van Meerbeek, Bart", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Academy of Dental Materials guidance on in vitro testing of dental composite bonding effectiveness to dentin/enamel using micro-tensile bond strength (μTBS) approach", "Source Title": "DENTAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Objective. An ideal dental adhesive should provide retentive strength, marginal seal, be relatively simple to achieve and demonstrate clinical durability. Future improvements in adhesive bonding to tooth structure require in vitro test methods that provide reliable data for materials development and/or evaluation of experimental variables. The objective of this project was to identify a test method that is relatively easy to perform, repeatable and ultimately useful for predicting clinical outcomes. Methods. The Academy of Dental Materials initiated a project to develop and distribute guidance documents on laboratory test methods that are useful for the evaluation of dental adhesives and cements, composite resins and ceramics. Results. The dental adhesive sub-group has identified the micro-tensile bond strength test, especially after subjecting the specimens to a durability challenge, as currently the best practical surrogate measure of dental composite restoration retention. Conclusion. The following mu TBS guidance is meant to aid the researcher in conducting the ii,TBS test. The authors, while recognizing the limitations of a static, strength-based test method, welcome comments and suggestions for improvements of this guidance document in future revisions. (C) 2016 The Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 353, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 33, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 133, "End Page": 143, "Article Number": null, "DOI": "10.1016/j.dental.2016.11.015", "DOI Link": "http://dx.doi.org/10.1016/j.dental.2016.11.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Dentistry, Oral Surgery & Medicine; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396409800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ammarullah, MI; Hartono, R; Supriyono, T; Santoso, G; Sugiharto, S; Permana, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ammarullah, Muhammad Imam; Hartono, Rachmad; Supriyono, Toto; Santoso, Gatot; Sugiharto, S.; Permana, Muki Satya", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polycrystalline Diamond as a Potential Material for the Hard-on-Hard Bearing of Total Hip Prosthesis: Von Mises Stress Analysis", "Source Title": "BIOMEDICINES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to polymeric wear debris causing osteolysis from polymer, metal ions causing metallosis from metal, and brittle characteristic causing fracture failure from ceramic in the application on bearing of total hip prosthesis requires the availability of new material options as a solution to these problems. Polycrystalline diamond (PCD) has the potential to become the selected material for hard-on-hard bearing in view of its advantages in terms of mechanical properties and biocompatibility. The present study contributes to confirming the potential of PCD to replace metals and ceramics for hard-on-hard bearing through von Mises stress investigations. A computational simulation using a 2D axisymmetric finite element model of hard-on-hard bearing under gait loading has been performed. The percentage of maximum von Mises stress to respective yield strength from PCD-on-PCD is the lowest at 2.47%, with CoCrMo (cobalt chromium molybdenum)-on-CoCrMo at 10.79%, and Al2O3 (aluminium oxide)-on-Al2O3 at 13.49%. This confirms that the use of PCD as a hard-on-hard bearing material is the safest option compared to the investigated metal and ceramic hard-on-hard bearings from the mechanical perspective.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 11, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 951, "DOI": "10.3390/biomedicines11030951", "DOI Link": "http://dx.doi.org/10.3390/biomedicines11030951", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Research & Experimental Medicine; Pharmacology & Pharmacy", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000957154100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Isametova, ME; Nussipali, R; Martyushev, N; Malozyomov, B; Efremenkov, EA; Isametov, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Isametova, Madina E.; Nussipali, Rollan; Martyushev, Nikita, V; Malozyomov, Boris, V; Efremenkov, Egor A.; Isametov, Aysen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mathematical Modeling of the Reliability of Polymer Composite Materials", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An urgent task in creating and using composite materials is the assessment and prediction of their performance properties and reliability. Currently, when studying the reliability of the materials, there is little experimental data, mathematical descriptions, and models for both probabilistic and deterministic methods to assess reliability. Based on the obtained experimental data, this article discusses the development of a methodology for predicting reliability. The article also proposes a statistical model for assessing reliability by the criterion of the structural strength of products made of polymer composite materials. The characteristics of the reliability changes in the materials when in operation are presented. The calculation allowed obtaining graphs showing the dispersion and statistical variability of the characteristics of polypropylene-based polymeric materials at the design, production, and operation stages of the product life cycle. The computational experimental results for determining the influence of the shape of inclusions and mass on the mechanical properties of a polymer composite material aimed at improving the strength characteristics of the products are presented. Based on a computational experiment in the MSC Digimat MF nonlinear solver, equations are provided to demonstrate the regression dependence of the strength of a part made of a polymer composite material on technological factors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 33, "Times Cited, All Databases": 33, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 10, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3978, "DOI": "10.3390/math10213978", "DOI Link": "http://dx.doi.org/10.3390/math10213978", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000883157400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elnour, AY; Alghyamah, AA; Shaikh, HM; Poulose, AM; Al-Zahrani, SM; Anis, A; Al-Wabel, MI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elnour, Ahmed Y.; Alghyamah, Abdulaziz A.; Shaikh, Hamid M.; Poulose, Anesh M.; Al-Zahrani, Saeed M.; Anis, Arfat; Al-Wabel, Mohammad, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Pyrolysis Temperature on Biochar Microstructural Evolution, Physicochemical Characteristics, and Its Influence on Biochar/Polypropylene Composites", "Source Title": "APPLIED SCIENCES-BASEL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Environmental management through effective utilization of biowastes has been a topic of intensive research in recent years. This study examines the effect of pyrolysis temperature on the physical and morphological characteristic of biochar (BC) derived from lignocellulosic wastes. The biochar was prepared by pyrolysing date palm biomass at various temperatures, i.e., 300, 400, 500, 600, and 700 degrees C. These pyrolysed biochars were then characterized for their carbon content, mineral compositions, chemical functionalities, and morphological structures, for understanding their physicochemical characteristics and microstructural evolution. It was revealed that the pyrolytic condition plays a key role in the formation of biochar microstructure. These biochar samples were then utilized without any further treatments/purifications for their practical application as reinforcement materials for polymer composites. They were blended with a polypropylene matrix by a melt mixing technique followed by injection molding process. The type of biochar was found to significantly affect the composites properties. Differences in microstructure, surface chemistry, and chemical compositions of BCs were observed to be determining factors affecting the compatibility and thermomechanical properties of resulted composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 193, "Times Cited, All Databases": 204, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2019, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1149, "DOI": "10.3390/app9061149", "DOI Link": "http://dx.doi.org/10.3390/app9061149", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465017200107", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Young, JB; Hughes, RW; Tamura, AM; Bailey, LS; Stewart, KA; Sumerlin, BS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Young, James B.; Hughes, Rhys W.; Tamura, Ariana M.; Bailey, Laura S.; Stewart, Kevin A.; Sumerlin, Brent S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the bulk depolymerization of poly(methyl methacrylate) (PMMA) at significantly lower temperatures than previously re-ported methods through the incorporation of thermolytically labile end-groups via reversible-deactivation radical polymerization (RDRP). The combination of alpha-end N-hydroxyphthalimide esters and omega-end trithiocarbonates allows for near-quantitative depoly-merization of PMMA in the bulk, with >90% methyl methacrylate (MMA) recovery for subsequent repolymerization. This depolymerization methodology enables catalyst-and solvent-free reversion to monomer on a multigram scale at temperatures up to 250degree celsius lower than current industrial methods. These reactions are per-formed in an efficient and high-yielding manner, establishing a viable route to depolymerize PMMA on large scales.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 64, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2023, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1016/j.chempr.2023.07.004", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2023.07.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001159343000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fernández-Tena, A; Pérez-Camargo, RA; Coulembier, O; Sangroniz, L; Aranburu, N; Guerrica-Echevarria, G; Liu, GM; Wang, DJ; Cavallo, D; Müller, AJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fernulldez-Tena, Ainhoa; Perez-Camargo, Ricardo Arpad; Coulembier, Olivier; Sangroniz, Leire; Aranburu, Nora; Guerrica-Echevarria, Gonzalo; Liu, Guoming; Wang, Dujin; Cavallo, Dario; Mueller, Alejandro J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Molecular Weight on the Crystallization and Melt Memory of Poly(ε-caprolactone) (PCL)", "Source Title": "MACROMOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The role of the molecular weight in the crystallizationulld meltmemory of poly(epsilon-caprolactone) (PCL) was investigated. To thisend, 10 PCL samples of synthetic and commercial origin and differentchain ends, covering a number-average molecular weight (M (n)) range between 0.48 and 70.5 kg/mol, were analyzed.Polarized light optical microscopy, differential scanning calorimetry,and small-angle X-ray scattering (SAXS) were employed for in-depthcharacterization. The thermal transitions, morphology, crystallizationkinetics, structural parameters, and memory effects were evaluatedas a function of M (n). The melting temperatureand the equilibrium melting temperature saturate at a particular M (n). Instead, the crystallization temperatureand the degree of crystallinity display an optimum M (n) at which the parameters reach a maximum, describinga bell-shaped behavior as a function of M (n). Similarly, the primary nucleation rate, spherulitic growth rate,and overall crystallization rate exhibit a bell-shaped behavior asa function of M (n), attributed to a competitionbetween nucleation and diffusion. SAXS analysis, which includes thelong period and lamellar thickness determination, revealed that at M (n) < 2.0 kg/mol, PCL crystallizes in an extended-chainconformation, while at M (n) >= 2.0kg/mol, folded chains are already present. In line with these results,the morphological study showed that the PCL crystallizes as axialitesat M (n) < 2.0 kg/mol and at higher M (n) as spherulites. The melt memory effect ofPCL, studied by self-nucleation experiments, increases with M (n) due to the simultaneous increase of entanglementsand the number of chain folding within the constituent crystallinelamellae per chain. Successive self-nucleation and annealing (SSA)experiments revealed that the PCL samples exhibit a similar SSA profile,indicating that the M (n) does not influencethe intermolecular interactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2023, "Volume": 56, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4602, "End Page": 4620, "Article Number": null, "DOI": "10.1021/acs.macromol.3c00234", "DOI Link": "http://dx.doi.org/10.1021/acs.macromol.3c00234", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001006506000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, HY; Hu, RZ; Feng, SR; Lin, ZQ; Zhu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Hanyin; Hu, Renzong; Feng, Sirui; Lin, Zhiqun; Zhu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "SiO-Sn2Fe@C composites with uniformly distributed Sn2Fe nulloparticles as fast-charging anodes for lithium-ion batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "SiO-based materials represent a promising class of anodes for lithium-ion batteries (LIBs), with a high theoretical capacity and appropriate and safe Li-insertion potential. However, SiO experiences a large volume change during the electrochemical reaction, low Li diffusivity, and low electron conductivity, resulting in degradation and low rate capability for LIBs. Here, we report on the rapid crafting of SiO-Sn2Fe@C composites via a one-step plasma milling process, leading to an alloy of Sn and Fe and in turn refining SiO and Sn2Fe into nulloparticles that are well dispersed in a nullosized, few-layer graphene matrix. The Sn and Fe nulloparticles generated during the first Liinsertion process form a stable network to improve Li diffusivity and electron conductivity. As an anode material, the SiO-Sn2Fe@C composite manifests high reversible capacities, superior cycling stability, and excellent rate capability. The capacity retention is found to be as high as 95% and 84% at the 100th and 300th cycles under 0.3 C. During rate capability testing at 3, 6, and 11 C, the capacity retentions are 71%, 60%, and 50%, respectively. This study highlights that this simple, one-step plasma milling strategy can further improve SiO-based anode materials for high-performance LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100080, "DOI": "10.1016/j.esci.2022.10.006", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.10.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078540700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chuai, M; Yang, JL; Wang, MM; Yuan, Y; Liu, ZC; Xu, Y; Yin, YC; Sun, JF; Zheng, XH; Chen, N; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chuai, Mingyan; Yang, Jinlong; Wang, Mingming; Yuan, Yuan; Liu, Zaichun; Xu, Yan; Yin, Yichen; Sun, Jifei; Zheng, Xinhua; Chen, Na; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance Zn battery with transition metal ions co-regulated electrolytic MnO2", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolytic MnO2/Zn batteries have attracted extensive attention for use in large-scale energy storage applications due to their low cost, high output voltage, safety, and environmental friendliness. However, the poor electrical conductivity of MnO2 limits its deposition and dissolution at large capacities, which leads to sluggish reaction kinetics and drastic capacity decay. Here, we report a theory-guided design principle for an electrolytic MnO2/Zn battery co-regulated with transition metal ions that has improved electrochemical performance in terms of deposition and stripping chemistries. We start with first-principles calculations to predict the electrolytic effects of regulating transition metal ions in the deposition/stripping chemistry of the MnO2 cathode. The results indicate that with the simultaneous incorporation of strongly electronegative Co and Ni, the MnO2 cathode tends to possess more active electron states, faster charge-transfer kinetics, and better electrical conductivity than either MnO2 regulated with Co or Ni on their own, or pristine MnO2; hence, this co-regulation is beneficial for the cathode solid/liquid MnO2/Mn2+ reactions. We then fabricate and demonstrate a novel Co2+ and Ni2+ co regulated MnO2/Zn (Co-Ni-MnO2/Zn) battery that yields significantly better electrochemical performance, finding that the synergistic regulation of Co and Ni on MnO2 can significantly increase its intrinsic conductivity and achieve high rates and Coulombic efficiencies at large capacities. The aqueous Co-Ni-MnO2/Zn battery exhibits a high rate (10C, 100 mA cm-2), high Coulombic efficiency (91.89%), and excellent cycling stability (600 cycles without decay) at a large areal capacity of 10 mAh cm-2. Our proposed strategy of co-regulation with transition metal ions offers a versatile approach for improving the electrochemical performance of aqueous electrolytic MnO2/Zn batteries in large-scale energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 158, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 178, "End Page": 185, "Article Number": null, "DOI": "10.1016/j.esci.2021.11.002", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2021.11.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080742800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Watanabe, H; Poe, HC; Vishwanath, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Watanabe, Haruki; Poe, Hoi Chun; Vishwanath, Ashvin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structure and topology of band structures in the 1651 magnetic space groups", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The properties of electrons in magnetically ordered crystals are of interest both from the viewpoint of realizing novel topological phases, such as magnetic Weyl semimetals, and from the application perspective of creating energy-efficient memories. A systematic study of symmetry and topology in magnetic materials has been challenging given that there are 1651 magnetic space groups (MSGs). By using an efficient representation of allowed band structures, we obtain a systematic description of several basic properties of free electrons in all MSGs in three dimensions, as well as in the 528 magnetic layer groups relevant to two-dimensional magnetic materials. We compute constraints on electron fillings and band connectivity compatible with insulating behavior. In addition, by contrasting with atomic insulators, we identify band topology entailed by the symmetry transformation of bands, as determined by the MSG alone. We provide an application of our results to identifying topological semimetals arising in periodic arrangements of hedgehog-like magnetic textures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 4, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat8685", "DOI": "10.1126/sciadv.aat8685", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat8685", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443498100078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kawaguchi, S; Takemoto, M; Osaka, K; Nishibori, E; Moriyoshi, C; Kubota, Y; Kuroiwa, Y; Sugimoto, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kawaguchi, S.; Takemoto, M.; Osaka, K.; Nishibori, E.; Moriyoshi, C.; Kubota, Y.; Kuroiwa, Y.; Sugimoto, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-throughput powder diffraction measurement system consisting of multiple MYTHEN detectors at beamline BL02B2 of SPring-8", "Source Title": "REVIEW OF SCIENTIFIC INSTRUMENTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this study, we developed a user-friendly automatic powder diffraction measurement system for Debye-Scherrer geometry using a capillary sample at beamline BL02B2 of SPring-8. The measurement system consists of six one-dimensional solid-state (MYTHEN) detectors, a compact autosampler, wide-range temperature control systems, and a gas handling system. This system enables to do the automatic measurement of temperature dependence of the diffraction patterns for multiple samples. We introduced two measurement modes in the MYTHEN system and developed new attachments for the sample environment such as a gas handling system. The measurement modes and the attachments can offer in situ and/or time-resolved measurements in an extended temperature range between 25 K and 1473 K and various gas atmospheres and pressures. The results of the commissioning and performance measurements using reference materials (NIST CeO2 674b and Si 640c), V2O3 and Ti2O3, and a nulloporous coordination polymer are presented. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 88, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 85111, "DOI": "10.1063/1.4999454", "DOI Link": "http://dx.doi.org/10.1063/1.4999454", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Instruments & Instrumentation; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000409178100077", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Lin, LF; Moreo, A; Dagotto, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yang; Lin, Ling-Fang; Moreo, Adriana; Dagotto, Elbio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic structure, dimer physics, orbital-selective behavior, and magnetic tendencies in the bilayer nickelate superconductor La3Ni2O7 under pressure", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by the recently reported high-temperature superconductivity in the bilayer La3Ni2O7 (LNO) under pressure, here we comprehensively study this system using ab initio techniques. The Ni 3d orbitals have a large bandwidth at ambient pressure, increasing by similar to 22% at 29.5 GPa. Without electronic interactions, the Ni d3z2-r2 orbitals form a bonding-antibonding molecular orbital state via the O pz inducing a dimer lattice in the LNO bilayers. The Fermi surface consists of two-electron sheets with mixed eg orbitals and a hole pocket defined by the d3z2-r2 orbital, suggesting a Ni two-orbital minimum model. Different from the infinite-layer nickelate, we obtained a large interorbital hopping between d3z2-r2 and dx2-y2 states in LNO, caused by the ligand bridge of in-plane O px or py orbitals connecting those two orbitals, inducing d -p a-bonding characteristics. The competition between the intraorbital and interorbital hoppings leads to an interesting dominullt spin stripe (n, 0) order because of bond ferromagnetic tendencies via the recently discussed half-empty mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 78, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 28", "Publication Year": 2023, "Volume": 108, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "L180510", "DOI": "10.1103/PhysRevB.108.L180510", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.108.L180510", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001141822000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thi, TUD; Nguyen, TT; Thi, YD; Thi, KHT; Phan, BT; Pham, KN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tu Uyen Doan Thi; Trung Thoai Nguyen; Dang Thi, Y.; Kieu Hanh Ta Thi; Bach Thang Phan; Kim Ngoc Pham", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of ZnO nulloparticles using orange fruit peel extract for antibacterial activities", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper presents an efficient, environmentally friendly, and simple approach for the green synthesis of ZnO nulloparticles (ZnO NPs) using orange fruit peel extract. This approach aims to both minimize the use of toxic chemicals in nulloparticle fabrication and enhance the antibacterial activity and biomedical applications of ZnO nulloparticles. In this work, an aqueous extract of orange peel was used as the biological reduction agent for the synthesis of ZnO NPs from zinc acetate dihydrate. It was found that the size and morphology of the ZnO NPs significantly depended on physicochemical parameters such as the annealing temperature and pH during NP synthesis. The ZnO NPs exhibited strong antibacterial activity towardEscherichia coli(E. coli) andStaphylococcus aureus(S. aureus) without UV illumination at an NP concentration of 0.025 mg mL(-1)after 8 h of incubation. In particular, the bactericidal activity towardsS. aureusvaried extensively with the synthesis parameters. This study presents an efficient green synthesis route for ZnO NPs with a wide range of potential applications, especially in the biomedical field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 314, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 23", "Publication Year": 2020, "Volume": 10, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23899, "End Page": 23907, "Article Number": null, "DOI": "10.1039/d0ra04926c", "DOI Link": "http://dx.doi.org/10.1039/d0ra04926c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000544674800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hamdia, KM; Zhuang, XY; Rabczuk, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hamdia, Khader M.; Zhuang, Xiaoying; Rabczuk, Timon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An efficient optimization approach for designing machine learning models based on genetic algorithm", "Source Title": "NEURAL COMPUTING & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning (ML) methods have shown powerful performance in different application. Nonetheless, designing ML models remains a challenge and requires further research as most procedures adopt a trial and error strategy. In this study, we present a methodology to optimize the architecture and the feature configurations of ML models considering a supervised learning process. The proposed approach employs genetic algorithm (GA)-based integer-valued optimization for two ML models, namely deep neural networks (DNN) and adaptive neuro-fuzzy inference system (ANFIS). The selected variables in the DNN optimization problems are the number of hidden layers, their number of neurons and their activation function, while the type and the number of membership functions are the design variables in the ANFIS optimization problem. The mean squared error (MSE) between the predictions and the target outputs is minimized as the optimization fitness function. The proposed scheme is validated through a case study of computational material design. We apply the method to predict the fracture energy of polymer/nulloparticles composites (PNCs) with a database gathered from the literature. The optimized DNN model shows superior prediction accuracy compared to the classical one-hidden layer network. Also, it outperforms ANFIS with significantly lower number of generations in GA. The proposed method can be easily extended to optimize similar architecture properties of ML models in various complex systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 179, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 33, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1923, "End Page": 1933, "Article Number": null, "DOI": "10.1007/s00521-020-05035-x", "DOI Link": "http://dx.doi.org/10.1007/s00521-020-05035-x", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541389000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Felice, IO; Shen, JJ; Barragan, AFC; Moura, IAB; Li, BQ; Wang, BB; Khodaverdi, H; Mohri, M; Schell, N; Ghafoori, E; Santos, TG; Oliveira, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Felice, Igor O.; Shen, Jiajia; Barragan, Andre F. C.; Moura, Isaque A. B.; Li, Binqiang; Wang, Binbin; Khodaverdi, Hesamodin; Mohri, Maryam; Schell, Norbert; Ghafoori, Elyas; Santos, Telmo G.; Oliveira, J. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire and arc additive manufacturing of Fe-based shape memory alloys: Microstructure, mechanical and functional behavior", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Shape memory alloys (SMA) are a class of smart materials with inherent shape memory and superelastic characteristics. Unlike other SMAs, iron-based SMAs (Fe-SMA) offer cost-effectiveness, weldability, and robust mechanical strength for the construction industry. Thus, applying these promising materials to advanced manufacturing processes is of considerable industrial and academic relevance. This study aims to present a pioneer application of a Fe-Mn-Si-Cr-Ni-V-C SMA to arc-based directed energy deposition additive manufacturing, namely wire and arc additive manufacturing (WAAM), examining the microstructure evolution and mechanical/functional response. The WAAM-fabricated Fe-SMAs presented negligible porosity and high deposition efficiency. Microstructure characterization encompassing elec-tron microscopy and high energy synchrotron X-ray diffraction revealed that the as-deposited material is primarily composed by y FCC phase with modest amounts of VC, 6 and a phases. Tensile and cyclic testing highlighted the Fe-SMA's excellent mechanical and functional response. Tensile testing revealed a yield strength and fracture stress of 472 and 821 MPa, respectively, with a fracture strain of 26%. After uniaxial tensile loading to fracture, the y ! 6 phase transformation was clearly evidenced with post- mortem synchrotron X-ray diffraction analysis. The cyclic stability during 100 load/unloading cycles was also evaluated, showcasing the potential applicability of the fabricated material for structural applications. (c) 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 82, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 231, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 112004, "DOI": "10.1016/j.matdes.2023.112004", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2023.112004", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001163399100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, YH; Sun, YY; Hou, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Yuhong; Sun, Yuanyang; Hou, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Core-shell structure nulloprecipitates in Fe-xCu-3.0Mn-1.5Ni-1.5Al alloys: A phase field study", "Source Title": "PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The core-shell structure precipitatates of Fe-xCu-3.0Mn-1.5Ni-1.5Al alloys under internal and external strain was investigated by using a multicomponent continuous phase field model based on Gibbs free energy of sub regular solution. Results show that the early cluster nuclei are not pure Cu, and Mn/Ni/Al also gather in the same position of Cu rich nuclei, resulting in four core-shell structures in precipitation. In the absence of external strain, the morphology of precipitates is mainly determined by interfacial energy, intrinsic elastic anisotropy and lattice distortion between new phase and parent phase. Intrinsic elastic strain energy can inhibit precipitation, while has no obvious effect on particle morphology. In coarsening, the elastic energy decreases due to the combination of particles. The loading direction and magnitude of the applied elastic strain field can control the morphology of precipitates. The external strain and the interaction between Mn, Ni and Al promote the joining and merging of adjacent core-shell particles. This work has guiding significance for the design of Fe-xCu-3.0Mn-1.5Ni-1.5Al alloys and other core-shell precipitates materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 116, "Times Cited, All Databases": 117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 32, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 358, "End Page": 368, "Article Number": null, "DOI": "10.1016/j.pnsc.2022.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.pnsc.2022.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000827419700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vasiliev, G; Kubo, AL; Vija, H; Kahru, A; Bondar, D; Karpichev, Y; Bondarenko, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vasiliev, Grigory; Kubo, Anna-Liisa; Vija, Heiki; Kahru, Anne; Bondar, Denys; Karpichev, Yevgen; Bondarenko, Olesja", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic antibacterial effect of copper and silver nulloparticles and their mechanism of action", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bacterial infections are one of the leading causes of death worldwide. In the case of topical bacterial infections such as wound infections, silver (Ag) has historically been one of the most widely used antibacterials. However, scientific publications have demonstrated the adverse effects of silver on human cells, ecotoxicity and insufficient antibacterial effect for the complete elimination of bacterial infections. The use of Ag in the form of nulloparticles (NPs, 1-100 nm) allows to control the release of antibacterial Ag ions but is still not sufficient to eliminate infection and avoid cytotoxicity. In this study, we tested the potency of differently functionalized copper oxide (CuO) NPs to enhance the antibacterial properties of Ag NPs. The antibacterial effect of the mixture of CuO NPs (CuO, CuO-NH2 and CuO-COOH NPs) with Ag NPs (uncoated and coated) was studied. CuO and Ag NP combinations were more efficient than Cu or Ag (NPs) alone against a wide range of bacteria, including antibiotic-resistant strains such as gram-negative Escherichia coli and Pseudomonas aeruginosa as well as gram-positive Staphylococcus aureus, Enterococcus faecalis and Streptococcus dysgalactiae. We showed that positively charged CuO NPs enhanced the antibacterial effect of Ag NPs up to 6 times. Notably, compared to the synergy of CuO and Ag NPs, the synergy of respective metal ions was low, suggesting that NP surface is required for the enhanced antibacterial effect. We also studied the mechanisms of synergy and showed that the production of Cu+ ions, faster dissolution of Ag+ from Ag NPs and lower binding of Ag+ by proteins of the incubation media in the presence of Cu2+ were the main mechanisms of the synergy. In summary, CuO and Ag NP combinations allowed increasing the antibacterial effect up to 6 times. Thus, using CuO and Ag NP combinations enables to retain excellent antibacterial effects due to Ag and synergy and enhances beneficial effects, since Cu is a vital microelement for human cells. Thus, we suggest using combinations of Ag and CuO NPs in antibacterial materials, such as wound care products, to increase the antibacterial effect of Ag, improve safety and prevent and cure topical bacterial infections.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2023, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 9202, "DOI": "10.1038/s41598-023-36460-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-023-36460-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001007425500042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pourjabari, A; Hajilak, ZE; Mohammadi, A; Habibi, M; Safarpour, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pourjabari, Amin; Hajilak, Zanyar Esmailpoor; Mohammadi, Alireza; Habibi, Mostafa; Safarpour, Hamed", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Porosity on free and forced vibration characteristics of the GPL reinforcement composite nullostructures", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article investigates the influence of porosity on free and forced vibration characteristics of a nulloshell reinforced by graphene platelets (GPL). The material properties of piecewise graphene-reinforced composites (GPLRCs) are assumed to be graded in the thickness direction of a cylindrical nulloshell and estimated using a nullomechanical model. In addition, because of imperfection of the current structure, three kinds of porosity distributions are considered. The nullostructure is modeled using modified strain gradient theory (MSGT) which is a size-dependent theory with three length scale parameters. The novelty of the current study is to consider the effects of porosity, GPLRC and MSGT on dynamic and static behaviors of the nullostructure. Considering three length scale parameters (l(0) = 5h, l(1) = 3h, l(2) = 5h) in MSGT leads to a better agreement with MD simulation in comparison by other theories. Finally, effects of different factors on static and dynamic behaviors of the porous nullostructure are examined in detail. (C) 2019 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 197, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 77, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2608, "End Page": 2626, "Article Number": null, "DOI": "10.1016/j.camwa.2018.12.041", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2018.12.041", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466455700003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, H; Liu, YF; Liu, XL; Wang, XK; Tian, H; Waterhouse, GIN; Kruger, PE; Telfer, SG; Ma, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hui; Liu, Yanfang; Liu, Xiaolu; Wang, Xiangke; Tian, He; Waterhouse, Geoffrey I. N.; Kruger, Paul E.; Telfer, Shane G.; Ma, Shengqian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-scale synthesis of N-doped carbon capsules supporting atomically dispersed iron for efficient oxygen reduction reaction electrocatalysis", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The large-scale synthesis of platinum-free electrocatalysts for the oxygen reduction reaction (ORR) remains a grand challenge. We report the large-scale production of stable and active ORR electrocatalysts based on iron, an earth-abundant element. A core-shell zeolitic imidazolate framework-tannic acid coordination polymer composite (ZIF-8@K-TA) was utilized as the catalyst precursor, which was transformed into iron atoms dispersed in hollow porous nitrogen-doped carbon capsules (H-Fe-Nx-C) through ion exchange and pyrolysis. H-Fe-Nx-C features site-isolated single-atom iron centers coordinated to nitrogen in graphitic layers, high levels of nitrogen doping, and high permeability to incoming gases. Benefiting from these characteristics, H-Fe-Nx-C demonstrated efficient electrocatalytic activity (E1/2 1/4 0.92 V, vs. RHE) and stability towards the ORR in both alkaline and acidic media. In ORR performance, it surpassed the majority of recently reported Fe-N-C catalysts and the standard Pt/C catalyst. In addition, H-Fe-Nx-C showed outstanding tolerance to methanol.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 157, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 227, "End Page": 234, "Article Number": null, "DOI": "10.1016/j.esci.2022.02.005", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.02.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080877600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Budde, G; Burkhardt, C; Brennecka, GA; Fischer-Gödde, M; Kruijer, TS; Kleine, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Budde, Gerrit; Burkhardt, Christoph; Brennecka, Gregory A.; Fischer-Goedde, Mario; Kruijer, Thomas S.; Kleine, Thorsten", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molybdenum isotopic evidence for the origin of chondrules and a distinct genetic heritage of carbonaceous and non-carbonaceous meteorites", "Source Title": "EARTH AND PLANETARY SCIENCE LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nucleosynthetic isotope anomalies are powerful tracers to determine the provenullce of meteorites and their components, and to identify genetic links between these materials. Here we show that chondrules and matrix separated from the Allende CV3 chondrite have complementary nucleosynthetic Mo isotope anomalies. These anomalies result from the enrichment of a presolar carrier enriched in s-process Mo into the matrix, and the corresponding depletion of this carrier in the chondrules. This carrier most likely is a metal and so the uneven distribution of presolar material probably results from metal silicate fractionation during chondrule formation. The Mo isotope anomalies correlate with those reported for W isotopes on the same samples in an earlier study, suggesting that the isotope variations for both Mo and W are caused by the heterogeneous distribution of the same carrier. The isotopic complementary of chondrules and matrix indicates that both components are genetically linked and formed together from one common reservoir of solar nebula dust. As such, the isotopic data require that most chondrules formed in the solar nebula and are not a product of protoplanetary impacts. Allende chondrules and matrix together with bulk carbonaceous chondrites and some iron meteorites (groups IID, IIIF, and IVB) show uniform excesses in Mo-92, Mo-95, and Mo-97 that result from the addition of supernova material to the solar nebula region in which these carbonaceous meteorites formed. Non carbonaceous meteorites (enstatite and ordinary chondrites as well as most iron meteorites) do not contain this material, demonstrating that two distinct Mo isotope reservoirs co-existed in the early solar nebula that remained spatially separated for several million years. This separation was most likely achieved through the formation of the gas giants, which cleared the disk between the inner and outer solar system regions parental to the non-carbonaceous and carbonaceous meteorites. The Mo isotope dichotomy of meteorites provides a new means to determine the provenullce of meteoritic and planetary materials, and to assess genetic links between chondrites and differentiated meteorites. (C) 2016 The Author(s). Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 225, "Times Cited, All Databases": 235, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2016, "Volume": 454, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 293, "End Page": 303, "Article Number": null, "DOI": "10.1016/j.epsl.2016.09.020", "DOI Link": "http://dx.doi.org/10.1016/j.epsl.2016.09.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geochemistry & Geophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386645700029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XF; Zhao, J; Wang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaofeng; Zhao, Jia; Wang, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical approximations for the molecular beam epitaxial growth model based on the invariant energy quadratization method", "Source Title": "JOURNAL OF COMPUTATIONAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The Molecular Beam Epitaxial model is derived from the variation of a free energy, that consists of either a fourth order Ginzburg Landau double well potential or a nonlinear logarithmic potential in terms of the gradient of a height function. One challenge in solving the MBE model numerically is how to develop proper temporal discretization for the nonlinear terms in order to preserve energy stability at the time-discrete level. In this paper, we resolve this issue by developing a first and second order time-stepping scheme based on the Invariant Energy Quadratization (IEQ) method. The novelty is that all nonlinear terms are treated semi-explicitly, and the resulted semi-discrete equations form a linear system at each time step. Moreover, the linear operator is symmetric positive definite and thus can be solved efficiently. We then prove that all proposed schemes are unconditionally energy stable. The semi-discrete schemes are further discretized in space using finite difference methods and implemented on GPUs for high-performance computing. Various 2D and 3D numerical examples are presented to demonstrate stability and accuracy of the proposed schemes. (C) 2016 Elsevier Inc. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 255, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2017, "Volume": 333, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 104, "End Page": 127, "Article Number": null, "DOI": "10.1016/j.jcp.2016.12.025", "DOI Link": "http://dx.doi.org/10.1016/j.jcp.2016.12.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393733100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XY; Li, FF; Li, YJ; Gao, XY; Yang, XH; Sunden, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xinyu; Li, Fangfei; Li, Yuanji; Gao, Xinyu; Yang, Xiaohu; Sunden, Bengt", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation and optimization on melting performance of a triplex-tube heat storage tank by rotational mechanism", "Source Title": "INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phase change heat storage is the backbone of energy storage technology, but its storage time is affected by the low thermal conductivity of phase change materials. Therefore, the melting performance of a triplex-tube latent heat thermal energy storage unit (T-LHTESU) in a phase change heat storage system is studied in this paper, and the rotation mechanism is applied to the unit. Firstly, a numerical model of the T-LHTESU considering the rotation mechanism is constructed, and the validity of the rotation unit is verified by comparison with experimental data. In this unit, N -eicosane is used as a phase change material for heat exchange. The effects of different rotational speeds on the liquid phase distribution, temperature distribution, flow velocity distribution, total energy storage, and energy storage efficiency of the T-LHTESU are studied. The results show that the melting time of this unit at 0.1 and 1 rpm is 46.98 and 69.35% lower than that of the stationary model, respectively. The total amount of stored heat is decreased by 0.67 and 2.17%, and the heat storage efficiency is increased by 87.34% and 219.19%, respectively. This indicates that the addition of the rotation mechanism greatly increases the heat storage efficiency of the T-LHTESU and reduces its total melting time, while the reduction of the total energy stored in the melting cycle is small. Then it is proved that rotation improves the single heat transfer mechanism of the stationary model and eliminates the thermal deposition caused by natural convection by studying the internal temperature/velocity response of the stationary model and the speed of 0.1 rpm. The related geometric structure of the model is optimized by response surface optimization design based on 0.1 rpm rotation speed. The influence of each variable on the target response is obtained, and compared with the original model, the melting time of the optimized model is reduced by 12.24%. Finally, based on the geometric optimization design, the influence of element physical factors (temperature and material of fin/tube wall) on the related melting properties is studied. This study is helpful to promote the effective use of rotation mechanism in phase change heat storage systems and has a certain guiding role in the structural design. (c) 2023 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ )", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2023, "Volume": 205, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123892, "DOI": "10.1016/j.ijheatmasstransfer.2023.123892", "DOI Link": "http://dx.doi.org/10.1016/j.ijheatmasstransfer.2023.123892", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics; Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927336200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Timrov, I; Marzari, N; Cococcioni, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Timrov, Iurii; Marzari, Nicola; Cococcioni, Matteo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-consistent Hubbard parameters from density-functional perturbation theory in the ultrasoft and projector-augmented wave formulations", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The self-consistent evaluation of Hubbard parameters using linear-response theory is crucial for quantitatively predictive calculations based on Hubbard-corrected density-functional theory. Here, we extend a recently introduced approach based on density-functional perturbation theory (DFPT) for the calculation of the onsite Hubbard U to also compute the intersite Hubbard V. DFPT allows us to reduce significantly computational costs, improve numerical accuracy, and fully automate the calculation of the Hubbard parameters by recasting the linear response of a localized perturbation into an array of monochromatic perturbations that can be calculated in the primitive cell. In addition, here we generalize the entire formalism from norm-conserving to ultrasoft and projector-augmented wave formulations, and to metallic ground states. After benchmarking DFPT against the conventional real-space Hubbard linear response in a supercell, we demonstrate the effectiveness of the present extended Hubbard formulation in determining the equilibrium crystal structure of LixMnPO4 (x = 0, 1) and the subtle energetics of Li intercalation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 29", "Publication Year": 2021, "Volume": 103, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45141, "DOI": "10.1103/PhysRevB.103.045141", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.103.045141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613141300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huo, HY; Rupp, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huo, Haoyan; Rupp, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unified representation of molecules and crystals for machine learning", "Source Title": "MACHINE LEARNING-SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate simulations of atomistic systems from first principles are limited by computational cost. In high-throughput settings, machine learning can reduce these costs significantly by accurately interpolating between reference calculations. For this, kernel learning approaches crucially require a representation that accommodates arbitrary atomistic systems. We introduce a many-body tensor representation that is invariant to translations, rotations, and nuclear permutations of same elements, unique, differentiable, can represent molecules and crystals, and is fast to compute. Empirical evidence for competitive energy and force prediction errors is presented for changes in molecular structure, crystal chemistry, and molecular dynamics using kernel regression and symmetric gradient-domain machine learning as models. Applicability is demonstrated for phase diagrams of Pt-group/transition-metal binary systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 118, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2022, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45017, "DOI": "10.1088/2632-2153/aca005", "DOI Link": "http://dx.doi.org/10.1088/2632-2153/aca005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888563800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, P; Wu, DX; Wang, TJ; Li, J; Deng, PL; Chen, Q; Shen, YJ; Chen, Y; Tian, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Peng; Wu, Daoxiong; Wang, Tian-Jiao; Li, Jing; Deng, Peilin; Chen, Qi; Shen, Yijun; Chen, Yu; Tian, Xinlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single atomic cobalt electrocatalyst for efficient oxygen reduction reaction", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Robust oxygen reduction reaction (ORR) catalysts are essential for energy storage and conversion devices, but their development remains challenging. Herein, we design a single-atom catalyst featuring isolated Co anchored on nitrogen-doped carbon (Co-SAC/NC) via a highly efficient plasma-bombing strategy. With a high loading (up to 2.5 wt%), the well-dispersed single Co atoms in Co-SAC/NC give it robust ORR performance in an alkaline medium. It also demonstrates excellent battery performance when implemented as the air-cathode catalyst in a zinc-air battery (ZAB). Theoretical calculations reveal that the Co-N4 moiety experiences an extraction/recov-ery structural evolution during the ORR process, and the reaction's rate-determining step is the formation of OOH* (reaction intermediate). This work provides a new strategy for designing robust ORR catalysts for high-performance ZABs and other energy-conversion devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 181, "Times Cited, All Databases": 188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 399, "End Page": 404, "Article Number": null, "DOI": "10.1016/j.esci.2022.05.004", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.05.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080903200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YR; Fang, JX; Joo, KI; Wong, MK; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yarong; Fang, Jinxu; Joo, Kye-Il; Wong, Michael K.; Wang, Pin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Codelivery of Chemotherapeutics via Crosslinked Multilamellar Liposomal Vesicles to Overcome Multidrug Resistance in Tumor", "Source Title": "PLOS ONE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multidrug resistance (MDR) is a significant challenge to effective cancer chemotherapy treatment. However, the development of a drug delivery system that allows for the sustained release of combined drugs with improved vesicle stability could overcome MDR in cancer cells. To achieve this, we have demonstrated codelivery of doxorubicin (Dox) and paclitaxel (PTX) via a crosslinked multilamellar vesicle (cMLV). This combinatorial delivery system achieves enhanced drug accumulation and retention, in turn resulting in improved cytotoxicity against tumor cells, including drug-resistant cells. Moreover, this delivery approach significantly overcomes MDR by reducing the expression of P-glycoprotein (P-gp) in cancer cells, thus improving antitumor activity in vivo. Thus, by enhancing drug delivery to tumors and lowering the apoptotic threshold of individual drugs, this combinatorial delivery system represents a potentially promising multimodal therapeutic strategy to overcome MDR in cancer therapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 287, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2014, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e110611", "DOI": "10.1371/journal.pone.0110611", "DOI Link": "http://dx.doi.org/10.1371/journal.pone.0110611", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345204100095", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Migas, DB; Turchenko, VA; Rutkauskas, AV; Trukhanov, SV; Zubar, TI; Tishkevich, DI; Trukhanov, AV; Skorodumova, NV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Migas, Dmitry B.; Turchenko, Vitaliy A.; Rutkauskas, A. V.; Trukhanov, Sergey V.; Zubar, Tatiana I.; Tishkevich, Daria I.; Trukhanov, Alex V.; Skorodumova, Natalia V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature induced structural and polarization features in BaFe12O19", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY C", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the observation of a peculiar polarization behavior of BaFe12O19 in electric field where the linear polarization is detected at temperatures below 150 K whereas at higher temperatures a hysteresis-like polarization response is observed. At the same time, the performed neutron diffraction analysis shows no variations in crystal or magnetic structures with temperature. Based on the results of ab initio calculations we suggest the mechanism able to explain the experimentally observed behavior. We show that specific Fe atoms do not occupy the positions formally assigned to them by the conventional centrosymmetric P6(3)/mmc (#194) space group (z = 0.25; 0.75) as these positions correspond to local energy maxima. Instead, these Fe atoms are shifted along the z-axis to positions z = 0.259 (0.241) and z = 0.759 (0.741), which correspond to local energy minima. To an inversion center move between these minima Fe atoms need to overcome an energy barrier. This barrier is rather insignificant for smaller volumes but it becomes larger for expanded volumes due to coupling between the displacements of these Fe atoms. Additionally, our analysis suggests that the non-centrosymmetric and polar P6(3)mc (#186) space group could be appropriate for the description of the BaFe12O19 structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2023, "Volume": 11, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12406, "End Page": 12414, "Article Number": null, "DOI": "10.1039/d3tc01533e", "DOI Link": "http://dx.doi.org/10.1039/d3tc01533e", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059918400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lauro, SN; Burrow, JN; Mullins, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lauro, Samantha N.; Burrow, James N.; Mullins, Buddie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Restructuring the lithium-ion battery: A perspective on electrode architectures", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The lithium-ion battery (LIB) has enabled portable energy storage, yet increasing societal demands have motivated a new generation of more advanced LIBs. Although the discovery and optimization of battery active materials has been the subject of extensive study since the 1980s, the most disruptive advancements of commercial LIBs in the past decade stem instead from overall cell design and engineering. In pursuit of higher energy density and fast-charging capability, strategies focused on tuning the properties of composite electrode architectures (e.g., porosity, conductivity, tortuosity, spatial heterogeneity) by restructuring the inactive component matrix of LIB electrode films have recently garnered attention. This perspective explores recent advances in electrode design through an applied lens, emphasizing synthetic platforms and future research directions that are scalable, commercially feasible, and applicable to a wide range of active materials. We introduce and critically assess recently proposed strategies for structuring electrode architectures, including spatial gradients of local composition and microstructure; metal-foil current collector alternatives; and electrode templating techniques, evaluating both achievements in battery performance and commercial applicability. Coupled with improved active materials, new electrode architectures hold promise to unlock next generation LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 108, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100152, "DOI": "10.1016/j.esci.2023.100152", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2023.100152", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081482300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, FF; Huang, XY; Li, YJ; Lu, L; Meng, XZ; Yang, XH; Sundén, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Fangfei; Huang, Xinyu; Li, Yuanji; Lu, Liu; Meng, Xiangzhao; Yang, Xiaohu; Sunden, Bengt", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Application and analysis of flip mechanism in the melting process of a triplex-tube latent heat energy storage unit", "Source Title": "ENERGY REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to improve the characteristics of uneven melting in the melting process of the horizontal latent heat energy storage system, the triplex-tube latent heat energy storage unit is taken as the research object, and the flip mechanism is applied to its melting process. Numerical simulation is used for the research, and the numerical model is verified by experimental data. The results show that under different dimensionless times, the melting performance of the unit can be significantly improved by a single flip. When the dimensionless time is 0.4576, it is found that the total melting time of the unit is reduced by 16.17 %, the average heat absorption rate is increased by 14.7 %, but the total heat energy absorption is reduced by 3.85 %. The results show that the addition of a flip can effectively shorten the melting time and increase the heat absorption rate, but it has a negative effect on the total heat absorption in one melting cycle. Moreover, through the comparison of dynamic flow rate, dynamic temperature response, and temperature interval, it is shown that the addition of flip effectively reduces the negative influence of the hard-to-melt zone on the melting performance of the unit during the melting process. The flip mechanism reduces the proportion of high-temperature phase change material in the melting process and makes the melting process more uniform.(c) 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3989, "End Page": 4004, "Article Number": null, "DOI": "10.1016/j.egyr.2023.03.037", "DOI Link": "http://dx.doi.org/10.1016/j.egyr.2023.03.037", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952248700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gaspar, MC; Braga, MEM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gaspar, Marisa C.; Braga, Mara E. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Edible films and coatings based on agrifood residues: a new trend in the food packaging research", "Source Title": "CURRENT OPINION IN FOOD SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Food packaging trends have been changing in the last years, mainly due to consumer concerns about plastic pollution and agrifood waste. Recent advances in the development of edible films and coatings are discussed. These systems can be much more than packaging, with additional functions such as antioxidant, antimicrobial, and nutritional properties, among others. Challenges in industrial processes and/or in some films' properties are addressed from the authors' point of view. The use of agrifood residues in these packaging systems is included as a promising strategy that promotes sustainability and circular economy. The authors consider that more research and actions are needed to achieve the best packaging material for each food product with reduced production costs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 42, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 50, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101006, "DOI": "10.1016/j.cofs.2023.101006", "DOI Link": "http://dx.doi.org/10.1016/j.cofs.2023.101006", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953473100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Algarni, M; Alazwari, MA; Safaei, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Algarni, Mohammed; Alazwari, Mashhour A.; Safaei, Mohammad Reza", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimization of nullo-Additive Characteristics to Improve the Efficiency of a Shell and Tube Thermal Energy Storage System Using a Hybrid Procedure: DOE, ANN, MCDM, MOO, and CFD Modeling", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using nullo-enhanced phase change material (NePCM) rather than pure PCM significantly affects the melting/solidification duration and the stored energy, which are two critical design parameters for latent heat thermal energy storage (LHTES) systems. The present article employs a hybrid procedure based on the design of experiments (DOE), computational fluid dynamics (CFD), artificial neural networks (ANNs), multi-objective optimization (MOO), and multi-criteria decision making (MCDM) to optimize the properties of nullo-additives dispersed in a shell and tube LHTES system containing paraffin wax as a phase change material (PCM). Four important properties of nullo-additives were considered as optimization variables: volume fraction and thermophysical properties, precisely, specific heat, density, and thermal conductivity. The primary objective was to simultaneously reduce the melting duration and increase the total stored energy. To this end, a five-step hybrid optimization process is presented in this paper. In the first step, the DOE technique is used to design the required simulations for the optimal search of the design space. The second step simulates the melting process through a CFD approach. The third step, which utilizes ANNs, presents polynomial models for objective functions in terms of optimization variables. MOO is used in the fourth step to generate a set of optimal Pareto points. Finally, in the fifth step, selected optimal points with various features are provided using various MCDM methods. The results indicate that nearly 97% of the Pareto points in the considered shell and tube LHTES system had a nullo-additive thermal conductivity greater than 180 Wm(-1)K(-1). Furthermore, the density of nullo-additives was observed to be greater than 9950 kgm(-3) for approximately 86% of the optimal solutions. Additionally, approximately 95% of optimal points had a nullo-additive specific heat of greater than 795 Jkg(-1)K(-1).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 44, "Times Cited, All Databases": 44, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 9, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3235, "DOI": "10.3390/math9243235", "DOI Link": "http://dx.doi.org/10.3390/math9243235", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000735913800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wei, LS; Deng, WJ; Li, SS; Wu, ZG; Cai, JH; Luo, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wei, Lansheng; Deng, Weijie; Li, Shanshan; Wu, Zhengguo; Cai, Jihai; Luo, Jiwen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sandwich-like chitosan porous carbon Spheres/MXene composite with high specific capacitance and rate performance for supercapacitors", "Source Title": "JOURNAL OF BIORESOURCES AND BIOPRODUCTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of porous carbon microspheres derived from pure biomass in supercapacitors is restricted due to their limited reactive groups. MXene owns a combination of redox Faradic surface with good metallic conductivity and hydrophilicity, which assists to obtain high pseudocapaci-tance and energy density. Herein, Ti3C2TxMXene was introduced to chitosan-based porous carbon microsphere (CPCM) to fabricated sandwich-like structure (CPCM/MXene) through electrostatic interaction. The Ti3C2T x protected the spherical structure of CPCM. Meanwhile, CPCM hindered the reaggregation of Ti3C2T x by inserting in the Ti3C2T x layers, promoting the electrolyte migra-tion kinetics. The synergistic effect endowed CPCM/MXene high specific capacitance of 362 F/g at current density of 0.5 A/g and acceptable cycling stability with 93.87% capacitance retention at a high current density of 10 A/g after 10,000 cycles. Furthermore, CPCM/MXene displayed a high energy density of 27.8 W/(h center dot kg) at 500.0 W/kg of power density. These satisfactory perfor-mances prove that combining Ti3C2T x MXene nullosheets with porous carbon microspheres is a considering method to construct a new generation electrode material of supercapacitor.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 116, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": 72, "Article Number": null, "DOI": "10.1016/j.jobab.2021.10.001", "DOI Link": "http://dx.doi.org/10.1016/j.jobab.2021.10.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994983000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mevada, D; Panchal, H; Ahmadein, M; Zayed, ME; Alsaleh, NA; Djuansjah, J; Moustafa, EB; Elsheikh, AH; Sadasivuni, KK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mevada, Dinesh; Panchal, Hitesh; Ahmadein, M.; Zayed, Mohamed E.; Alsaleh, Naser A.; Djuansjah, Joy; Moustafa, Essam B.; Elsheikh, Ammar H.; Sadasivuni, Kishor Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Investigation and performance analysis of solar still with energy storage materials: An energy- exergy efficiency analysis", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Researchers have attempted different Energy storage materials (ESM) in solar stills (SS) to improve distillate yield. In this experimental work, an attempt was made to increase the distillate yield & efficiency of SS, using good absorbing and heat transfer capacity of ESM. A comparison was made between a conventional solar still (CSS) and a solar still with energy storage materials (SSWESM) in this experiment. Different energy storage materials like black color glass ball (BCGB), black granite (BG) and white marble stone (WMS) were used in equal quantity during experimental work. CSS and SSWESM had daily distillate yield of 1.4 kg/m2 and 2.5 kg/m2, respectively. The ESM boosts water evaporation during the day and releases heat at night, resulting in a higher distillate yield than CSS. Meanwhile, the exergy efficiency (eta(exe)) of CSS and SSWESM were 4.99% and 12.55% respectively. Also the SSWESM gives 72.6% more daily efficiency (eta) than CSS.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 110, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 29, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101687, "DOI": "10.1016/j.csite.2021.101687", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2021.101687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791215900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Elsheikh, AH; Shanmugan, S; Sathyamurthy, R; Thakur, AK; Issa, M; Panchal, H; Muthuramalingam, T; Kumar, R; Sharifpur, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Elsheikh, Ammar H.; Shanmugan, S.; Sathyamurthy, Ravishankar; Thakur, Amrit Kumar; Issa, Mohamed; Panchal, Hitesh; Muthuramalingam, T.; Kumar, Ravinder; Sharifpur, Mohsen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-cost bilayered structure for improving the performance of solar stills: Performance/cost analysis and water yield prediction using machine learning", "Source Title": "SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper aims to enhance the performance of conventional solar still (CSS) using a low cost heat localization bilayered structure (HLBS). The HLBS consists of a bottom supporting layer (SL) made of low thermal conductivity as well as low density material and a top absorbing layer (AL) made of a photo thermal material with a high sunlight absorptivity as well as an enhanced conversion efficiency. The developed HLBS helps in increasing the evaporation rate and minimize the heat losses in a modified solar still (MSS). Two similar SSs were designed and tested to evaluate SSs' performance without and with HLBS (CSS and MSS). Moreover, three machine learning (ML) methods were utilized as predictive tools to obtain the water yield of the SSs, namely artificial neural network (ANN), support vector machine (SVM), and adaptive neuro-fuzzy inference system (ANFIS). The prediction accuracy of the models was evaluated using different statistical measured. The obtained results showed that the daily freshwater yield, energy efficiency, and exergy efficiency of the MSS was enhanced by 34%, 34%, and 46% compared with that of CSS. The production cost per liter of the MSS is 0.015 $/L. Moreover, SVM outperformed other ML methods for both SSs based on different statistical measures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 49, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101783, "DOI": "10.1016/j.seta.2021.101783", "DOI Link": "http://dx.doi.org/10.1016/j.seta.2021.101783", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000874474600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qu, WZ; He, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qu, Wenzhen; He, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A spatial-temporal GFDM with an additional condition for transient heat conduction analysis of FGMs", "Source Title": "APPLIED MATHEMATICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, a spatial-temporal generalized finite difference method (GFDM) with an additional condition is proposed for two-dimensional (2D) transient heat conduction analysis of functionally graded materials (FGMs). The 2D time dependent problem is explored as the three-dimensional (3D) stationary problem by treating the temporal direction as the third dimension. Based on the time-marching procedure with the GFDM, an additional condition is introduced to ensure well-posedness of the 3D stationary problem. Numerical experiment is presented to illustrate the performance of the developed method, and a comparison of numerical precision is made between the present approach and the conventional GFDM. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 75, "Times Cited, All Databases": 76, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 110, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106579, "DOI": "10.1016/j.aml.2020.106579", "DOI Link": "http://dx.doi.org/10.1016/j.aml.2020.106579", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571533500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Novikov, DS; Jensen, JH; Helpern, JA; Fieremans, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Novikov, Dmitry S.; Jensen, Jens H.; Helpern, Joseph A.; Fieremans, Els", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing mesoscopic structural universality with diffusion", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Measuring molecular diffusion is widely used for characterizing materials and living organisms noninvasively. This characterization relies on relations between macroscopic diffusion metrics and structure at the mesoscopic scale commensurate with the diffusion length. Establishing such relations remains a fundamental challenge, hindering progress in materials science, porous media, and biomedical imaging. Here we show that the dynamical exponent in the time dependence of the diffusion coefficient distinguishes between the universality classes of the mesoscopic structural complexity. Our approach enables the interpretation of diffusion measurements by objectively selecting and modeling the most relevant structural features. As an example, the specific values of the dynamical exponent allow us to identify the relevant mesoscopic structure affecting MRI-measured water diffusion in muscles and in brain, and to elucidate the structural changes behind the decrease of diffusion coefficient in ischemic stroke.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 250, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2014, "Volume": 111, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5088, "End Page": 5093, "Article Number": null, "DOI": "10.1073/pnas.1316944111", "DOI Link": "http://dx.doi.org/10.1073/pnas.1316944111", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000333985200025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Lin, LF; Moreo, A; Maier, TA; Dagotto, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yang; Lin, Ling-Fang; Moreo, Adriana; Maier, Thomas A.; Dagotto, Elbio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trends in electronic structures and s±-wave pairing for the rare-earth series in bilayer nickelate superconductor R3Ni2O7", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of pressure-induced superconductivity in the bilayer La3Ni2O7 (LNO) has opened a new platform for the study of unconventional superconductors. In this publication, we investigate theoretically the whole family of bilayer 327-type nickelates R3Ni2O7 (R = rare-earth elements) under pressure. From La to Lu, the lattice constants and volume decrease, leading to enhanced in-plane and out-of-plane hoppings, resulting in an effectively reduced electronic correlation U/W. Furthermore, the Ni's t2g states shift away from the eg states, while the crystal-field splitting between d3z2-r2 and dx2-y2 is almost unchanged. In addition, six candidates were found to become stable in the Fmmm phase, with increasing values of critical pressure as the atomic number increases. Similar to the case of LNO, the s +/--wave pairing tendency dominates in all candidates, due to the nesting between the M = (r, r) and the X = (r, 0) and Y = (0, r) points in the Brillouin zone. Then, Tc is expected to decrease as the radius of rare-earth (RE) ions decreases. Our results suggest that LNO is already the optimal candidate, with Ce a close competitor, among the whole of the RE bilayer nickelates, and to increase Tc we suggest growing on special substrates with larger in-plane lattice spacings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 23", "Publication Year": 2023, "Volume": 108, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 165141, "DOI": "10.1103/PhysRevB.108.165141", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.108.165141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001099459200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aroob, S; Carabineiro, SAC; Taj, MB; Bibi, I; Raheel, A; Javed, T; Yahya, R; Alelwani, W; Verpoort, F; Kamwilaisak, K; Al-Farraj, S; Sillanpää, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aroob, Sadia; Carabineiro, Sonia A. C.; Taj, Muhammad Babar; Bibi, Ismat; Raheel, Ahmad; Javed, Tariq; Yahya, Rana; Alelwani, Walla; Verpoort, Francis; Kamwilaisak, Khanita; Al-Farraj, Saleh; Sillanpaa, Mika", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green Synthesis and Photocatalytic Dye Degradation Activity of CuO nulloparticles", "Source Title": "CATALYSTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The degradation of dyes is a difficult task due to their persistent and stable nature; therefore, developing materials with desirable properties to degrade dyes is an important area of research. In the present study, we propose a simple, one-pot mechanochemical approach to synthesize CuO nulloparticles (NPs) using the leaf extract of Seriphidium oliverianum, as a reducing and stabilizing agent. The CuO NPs were characterized via X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) and Fourier-transform infrared spectroscopy (FTIR). The photocatalytic activity of CuO NPs was monitored using ultraviolet-visible (UV-Vis) spectroscopy. The CuO NPs exhibited high potential for the degradation of water-soluble industrial dyes. The degradation rates for methyl green (MG) and methyl orange (MO) were 65.231% +/- 0.242 and 65.078% +/- 0.392, respectively. Bio-mechanochemically synthesized CuO NPs proved to be good candidates for efficiently removing dyes from water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 72, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 13, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.3390/catal13030502", "DOI Link": "http://dx.doi.org/10.3390/catal13030502", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000957660200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cano, J; Bradlyn, B; Wang, ZJ; Elcoro, L; Vergniory, MG; Felser, C; Aroyo, MI; Bernevig, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cano, Jennifer; Bradlyn, Barry; Wang, Zhijun; Elcoro, L.; Vergniory, M. G.; Felser, C.; Aroyo, M. I.; Bernevig, B. Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Building blocks of topological quantum chemistry: Elementary band representations", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The link between chemical orbitals described by local degrees of freedom and band theory, which is defined in momentum space, was proposed by Zak several decades ago for spinless systems with and without time reversal in his theory of elementary band representations. In a recent paper [Bradlyn et al., Nature (London) 547, 298 (2017)] we introduced the generalization of this theory to the experimentally relevant situation of spin-orbit coupled systems with time-reversal symmetry and proved that all bands that do not transform as band representations are topological. Here we give the full details of this construction. We prove that elementary band representations are either connected as bands in the Brillouin zone and are described by localizedWannier orbitals respecting the symmetries of the lattice (including time reversal when applicable), or, if disconnected, describe topological insulators. We then show how to generate a band representation from a particular Wyckoff position and determine which Wyckoff positions generate elementary band representations for all space groups. This theory applies to spinful and spinless systems, in all dimensions, with and without time reversal. We introduce a homotopic notion of equivalence and show that it results in a finer classification of topological phases than approaches based only on the symmetry of wave functions at special points in the Brillouin zone. Utilizing a mapping of the band connectivity into a graph theory problem, we show in companion papers which Wyckoff positions can generate disconnected elementary band representations, furnishing a natural avenue for a systematic materials search.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 187, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2018, "Volume": 97, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 35139, "DOI": "10.1103/PhysRevB.97.035139", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.97.035139", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423115200012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tichapondwa, SM; Newman, JP; Kubheka, O", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tichapondwa, S. M.; Newman, J. P.; Kubheka, O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of TiO2 phase on the photocatalytic degradation of methylene blue dye", "Source Title": "PHYSICS AND CHEMISTRY OF THE EARTH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Several industrial processes make use of dyes in order to impart colour into their products. These processes release large amounts of dye-containing wastewater which can be hazardous to human health and the environment. This has necessitated the development of cheap, reliable and sustainable technologies that can remediate the effluent, heterogeneous TiO2 photocatalysis is one such technology that has proven successful. Different polymorphs of TiO2 exist and literature suggests that the photocatalytic efficiency of various phases depends on the target pollutant. This study investigated the photocatalytic degradation of methylene blue (MB) dye using of three commercial TiO2 powders with different crystal phases as catalysts. The materials properties for each catalyst were first determined using x-ray diffraction and microscopy. Degradation studies were then conducted on 10 ppm MB solutions using the three powders. Degussa P25 TiO2, a mixture of anatase and rutile was the most efficient compared to the neat anatase and rutile powders, degrading 81.4% of the MB. This catalyst was chosen for optimisation studies, where 95% degradation was achieved at a 0.5 g/L catalyst loading and pH of 10. The degree of mineralisation decreased with increasing MB concentration. The effect of metal doping on the photocatalytic performance of the catalyst was also investigated. Copper doping increased degradation by 2% whilst zinc reduced it to 90%. The complete decolourisation of the MB coupled with the significant decrease in TOC upon completion of the degradation process, indicate that Degussa P25 catalysed photocatalysis is a viable pretreatment technology in dye contaminated wastewater treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 153, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2020, "Volume": 118, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102900, "DOI": "10.1016/j.pce.2020.102900", "DOI Link": "http://dx.doi.org/10.1016/j.pce.2020.102900", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Geology; Meteorology & Atmospheric Sciences; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000575782800008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, X; Wan, X; Liu, QT; Li, YC; Li, WW; Shui, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Xu; Wan, Xin; Liu, Qingtao; Li, Yongcheng; Li, Wenwen; Shui, Jianglan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphated IrMo bimetallic cluster for efficient hydrogen evolution reaction", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing low-cost, high-performance electrocatalysts for the hydrogen evolution reaction (HER) is essential for producing hydrogen from renewable energy sources. Herein, we report phosphated IrMo bimetallic clusters supported by macroporous nitrogen-doped carbon (IrMoP/MNC) as a highly efficient alkaline HER catalyst. The experimental and theoretical results demonstrate that P and Mo synergistically tune the electronic structure of atomically dispersed Ir to improve adsorption of the reactant H2O and desorption of the product OH-. P itself serves as an active site and cooperates with the nearby Ir atom to significantly enhance the HER kinetics. Even with only 2.6 wt% Ir in the catalyst, IrMoP/MNC exhibits an ultralow overpotential of 14 mV at 10 mA cm-2, as well as an unprecedented high mass activity of 18.58 A mgIr-1 at an overpotential of 100 mV, superior to commercial Pt/C and overwhelmingly better than other Ir-based electrocatalysts. This study demonstrates a multilevel design strategy to effectively improve the atom efficiency of a noble metal, involving spatial geometry, local electronic structure, and dual-atom synergy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 304, "End Page": 310, "Article Number": null, "DOI": "10.1016/j.esci.2022.04.002", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.04.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078328600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mohammed, M; Jawad, AJM; Mohammed, AM; Oleiwi, JK; Adam, T; Osman, AF; Dahham, OS; Betar, BO; Gopinath, SCB; Jaafar, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mohammed, Mohammed; Jawad, Anwar Ja'afar Mohamad; Mohammed, Aeshah M.; Oleiwi, Jawad K.; Adam, Tijjani; Osman, Azlin F.; Dahham, Omar S.; Betar, Bashir O.; Gopinath, Subash C. B.; Jaafar, Mustafa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Challenges and advancement in water absorption of natural fiber-reinforced polymer composites", "Source Title": "POLYMER TESTING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural fibres (NFRs) composite materials are acquiring popularity in the modern world due to their eco-friendliness and superior mechanical properties. Although it has been shown that determining this is a hercu-lean endeavour in the literature, the water absorption (WA) qualities of the natural fibre (NFR) are crucial in the progressive degradation of the features of the resulting composites. This article seeks to report exhaustively on studies pertaining to the WA attributes of polymer composites reinforced with NFRs. This article provides an overview of NFR, its characterization, and the issues related to its addition to the matrix. The primary purpose of this research study is to investigate existing studies on the problems associated with the creation of cellulosic fibre hybrid composites, water absorption, and its impact on the tensile (TS), flexural (FS), and impact strength (IS) of NFR reinforced composites. We reviewed various surface treatments (ST) applied to NFR, including alkali treatment, silane treatment, acetylation, as well as recent advancements aimed at mitigating WA, enhancing hydrophobicity, and improving the interfacial bonding (IB) between NFR and the polymer matrix (PM). Addi-tionally, we assessed the effectiveness of utilizing nulloparticles (NAPs) in specific ST of NFR to minimize water absorption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 126, "Times Cited, All Databases": 126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108083, "DOI": "10.1016/j.polymertesting.2023.108083", "DOI Link": "http://dx.doi.org/10.1016/j.polymertesting.2023.108083", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001035316400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Postai, DL; Demarchi, CA; Zanatta, F; Melo, DCC; Rodrigues, CA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Postai, Debora Luiza; Demarchi, Carla Albertina; Zanatta, Francielle; Cipriani Melo, Danielle Caroline; Rodrigues, Clovis Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of rhodamine B and methylene blue dyes using waste of seeds of Aleurites Moluccana, a low cost adsorbent", "Source Title": "ALEXANDRIA ENGINEERING JOURNAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Removal of the cationic dyes rhodamine B (RhB) and methylene blue (MB) by waste seeds Aleurites moluccana (WAM) was studied in a batch system. The adsorbent was characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), point of zero charge measurement, and the Boehm titration method. The effects of contact time and pH were investigated for the removal of cationic dyes. An increase in pH from 3 to 9 was accompanied by an approximately three-fold increase in the amount of dye adsorbed. The adsorptions equilibrium values were obtained and analyzed using the Langmuir, Freundlich, Sips, and Redlich-Peterson equations, the Sips isotherm being the one that showed the best correlation with the experimental values. The maximum adsorption capacities of the dyes were 178 mg/g for the MB and 117 mg/g for the RhB. The kinetic sorption was evaluated by the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models, where it was observed that sorption follows the pseudo-second-order kinetic model. The study of thermodynamics showed that the adsorption is a spontaneous and endothermic process. The results indicate that waste seeds of A. moluccana could be used as a low cost material for the removal of cationic dyes from wastewater. (C) 2016 Faculty of Engineering, Alexandria University. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 210, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 55, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1713, "End Page": 1723, "Article Number": null, "DOI": "10.1016/j.aej.2016.03.017", "DOI Link": "http://dx.doi.org/10.1016/j.aej.2016.03.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378931300094", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Atri, A; Echabaane, M; Bouzidi, A; Harabi, I; Soucase, BM; Ben Chaâbane, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Atri, Afrah; Echabaane, Mosaab; Bouzidi, Amel; Harabi, Imen; Soucase, Bernabe Mari; Ben Chaabane, Rafik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of copper oxide nulloparticles using Ephedra Alata plant extract and a study of their antifungal, antibacterial activity and photocatalytic performance under sunlight", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, copper oxide (CuO NPs) was synthesized by an eco-friendly, simple, low-cost, and economical synthesis method using Ephedra Alata aqueous plant extract as a reducing and capping agent. The biosynthesized CuO-NPs were compared with chemically obtained CuO-NPs to investigate the effect of the preparation method on the structural, optical, morphological, antibacterial, antifungal, and photocatalytic properties under solar irradiation. The CuO NPs were characterized using X-ray diffraction (XRD), UV-VIS spectroscopy, Fourier transform infrared spectrometer (FTIR) analysis, and field emission scanning electron microscopy with energy dispersive X-ray spectroscopy (FESEM-EDX). The photocatalytic activities of biosynthetic CuO-NPs and chemically prepared CuO-NPs were studied using methylene blue upon exposure to solar irradiation. The results showed that the biosynthesized CuO photocatalyst was more effi-cient than the chemically synthesized CuO-NPs for Methylene Blue (MB) degradation under solar irradiation, with MB degradation rates of 93.4% and 80.2%, respectively. In addition, antibac-terial and antifungal activities were evaluated. The disk diffusion technique was used to test the biosynthesized CuO-NPs against gram-negative bacteria, Staphylococcus aureus and Bacillus sub-tilis, as well as C. Albicans and S. cerevisiae. The biosynthesized CuO-NPs showed efficient anti-bacterial and antifungal activity. The obtained results revealed that the biosynthesized CuO-NPs can play a vital role in the destruction of pathogenic bacteria, the degradation of dyes, and the activity of antifungal agents in the bioremediation of industrial and domestic waste.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e13484", "DOI": "10.1016/j.heliyon.2023.e13484", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2023.e13484", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968490900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZQ; Zhou, M; Qin, LP; Chen, MH; Chen, ZX; Guo, S; Wang, LB; Fang, GZ; Liang, SQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ziqing; Zhou, Miao; Qin, Liping; Chen, Minghui; Chen, Zixian; Guo, Shan; Wang, Liangbing; Fang, Guozhao; Liang, Shuquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simultaneous regulation of cations and anions in an electrolyte for high-capacity, high-stability aqueous zinc-vanadium batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Safe, inexpensive aqueous zinc-ion batteries (AZIBs) are regarded as promising energy storage devices. However, they still face issues, including dissolution and collapse of the cathode as well as H2 evolution and the growth of Zn dendrites on the Zn anode. Herein, we simultaneously regulate the cations and anions in the electrolyte for high-capacity, high-stability aqueous zinc-vanadium (Zn-V) batteries based on a bimetallic cation-doped Na0.33K0.1V2O5 center dot nH2O cathode. We demonstrate that Na+ cations suppress cathode dissolution and restrain Zn dendrite growth on the anode via an electrostatic shield effect. We also illustrate that ClO4- anions participate in energy storage at the cathode and are reduced to Cl-, generating a protective layer on the Zn anode surface and providing a stable interface to decrease Zn dendrites and H2 evolution during long-term cycling. When Na+ and ClO4- are introduced into an aqueous ZnSO4 electrolyte, a Zn/Zn symmetric cell shows durable and reversible Zn stripping/plating for 1500 h at a current density of 1 mA cm-2 and with an area capacity of 1 mAh cm-2. Zn/ Na0.33K0.1V2O5 center dot nH2O full batteries exhibit a high capacity of 600 mAh g-1 at 0.1 A g-1 and long-term cycling performance for 5000 cycles, with a capacity of 200 mAh g-1 at 20 A g-1.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2022, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 209, "End Page": 218, "Article Number": null, "DOI": "10.1016/j.esci.2022.03.002", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.03.002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078391300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khan, AAP; Sonu; Sudhaik, A; Raizada, P; Khan, A; Rub, MA; Azum, N; Alotaibi, MM; Singh, P; Asiri, AM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khan, Aftab Aslam Parwaz; Sonu; Sudhaik, Anita; Raizada, Pankaj; Khan, Anish; Rub, Malik Abdul; Azum, Naved; Alotaibi, Maha M.; Singh, Pardeep; Asiri, Abdullah M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "AgI coupled SiO2@CuFe2O4 novel photocatalytic nullo-material for photo-degradation of organic dyes", "Source Title": "CATALYSIS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "S-scheme-based hydrothermal synthesis of SiO2@CuFe2O4-AgI composites was effectively described in this work. The photo-degradation of hazardous dyes like methylene blue (MB) and methyl orange (MO) was utilized to test nullocomposites with variable weight percent of AgI for photocatalytic activity in the visible range. In terms of photocatalytic activity, SiO2@CuFe2O4-AgI with a 15% AgI loading beat both pure and hybrid composites. In terms of MO degradation, the hybrid composite with 15% AgI loading degrades 16 times and 8 times faster than pristine CuFe2O4 and AgI samples, respectively, while in terms of MB degradation, it degrades 18.67 times faster and 9.33 times faster than pristine samples. The increased surface area decreased the recombination rate of photogenerated e(-) -h(+) pairs, quicker separation of photogenerated carriers, and high redox capacity of SiO2@CuFe2O4-AgI (15%) all contribute to improved photocatalytic performance. The hybrid composite chemically stable and reusable even after 10 cycles. Because of the coordinated Fermi level between CuFe2O4 and AgI, SiO2 acts as a transfer bridge for electrons in a layered structure. Furthermore, the scavenger experiment demonstrates that center dot O-2-, center dot OH, and h(+) are significant reactive species that efficiently aided the photodegradation of dyes. Current research proposes a novel and cost-efficient method for creating a stable semiconductor-based photocatalytic system and a viable strategy for future applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 56, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 179, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106685, "DOI": "10.1016/j.catcom.2023.106685", "DOI Link": "http://dx.doi.org/10.1016/j.catcom.2023.106685", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002371600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Turchenko, VA; Trukhanov, S; Kostishin, VG; Damay, F; Porcher, F; Klygach, DS; Vakhitov, MG; Lyakhov, D; Michels, D; Bozzo, B; Fina, ; Almessiere, MA; Slimani, Y; Baykal, A; Zhou, D; Trukhanov, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Turchenko, V. A.; Trukhanov, S., V; Kostishin, V. G.; Damay, F.; Porcher, F.; Klygach, D. S.; Vakhitov, M. G.; Lyakhov, D.; Michels, D.; Bozzo, B.; Fina, I; Almessiere, M. A.; Slimani, Y.; Baykal, A.; Zhou, D.; Trukhanov, A., V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Features of structure, magnetic state and electrodynamic performance of SrFe12-xInxO19", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Indium-substituted strontium hexaferrites were prepared by the conventional solid-phase reaction method. Neutron diffraction patterns were obtained at room temperature and analyzed using the Rietveld methods. A linear dependence of the unit cell parameters is found. In3+ cations are located mainly in octahedral positions of 4f(VI) and 12 k. The average crystallite size varies within 0.84-0.65 mu m. With increasing substitution, the T-C Curie temperature decreases monotonically down to similar to 520 K. ZFC and FC measurements showed a frustrated state. Upon substitution, the average and maximum sizes of ferrimagnetic clusters change in the opposite direction. The M-r remanent magnetization decreases down to similar to 20.2 emu/g at room temperature. The M-s spontaneous magnetization and the k(eff) effective magnetocrystalline anisotropy constant are determined. With increasing substitution, the maximum of the epsilon' real part of permittivity decreases in magnitude from similar to 3.3 to similar to 1.9 and shifts towards low frequencies from similar to 45.5 GHz to similar to 37.4 GHz. The maximum of the tg(alpha) dielectric loss tangent decreases from similar to 1.0 to similar to 0.7 and shifts towards low frequencies from similar to 40.6 GHz to similar to 37.3 GHz. The low-frequency maximum of the mu' real part of permeability decreases from similar to 1.8 to similar to 0.9 and slightly shifts towards high frequencies up to similar to 34.7 GHz. The maximum of the tg(delta) magnetic loss tangent decreases from similar to 0.7 to similar to 0.5 and shifts slightly towards low frequencies from similar to 40.5 GHz to similar to 37.7 GHz. The discussion of microwave properties is based on the saturation magnetization, natural ferromagnetic resonullce and dielectric polarization types.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 127, "Times Cited, All Databases": 127, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 18342, "DOI": "10.1038/s41598-021-97684-8", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-97684-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696347000109", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, LS; Guo, RT; Fang, SS; Chen, J; Gao, JQ; Mei, Y; Zhang, S; Deng, WT; Zou, GQ; Hou, HS; Ji, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Lianshan; Guo, Ruiting; Fang, Susu; Chen, Jun; Gao, Jinqiang; Mei, Yu; Zhang, Shu; Deng, Wentao; Zou, Guoqiang; Hou, Hongshuai; Ji, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid growth in global electric vehicles (EVs) sales has promoted the development of Co-free, Ni-rich layered cathodes for state-of-the-art high energy-density, inexpensive lithium-ion batteries (LIBs). However, progress in their commercial use has been seriously hampered by exasperating performance deterioration and safety concerns. Herein, a robust single-crystalline, Co-free, Ni-rich LiNi0.95Mn0.05O2 (SC-NM95) cathode is successfully designed using a molten salt-assisted method, and it exhibits better structural stability and cycling durability than those of polycrystalline LiNi0.95Mn0.05O2 (PC-NM95). Notably, the SC-NM95 cathode achieves a high discharge capacity of 218.2 mAh g(-1), together with a high energy density of 837.3 Wh kg(-1) at 0.1 C, mainly due to abundant Ni2+/Ni3+ redox. It also presents an outstanding capacity retention (84.4%) after 200 cycles at 1 C, because its integrated single-crystalline structure effectively inhibits particle microcracking and surface phase transformation. In contrast, the PC-NM95 cathode suffers from rapid capacity fading owing to the nucleation and propagation of intergranular microcracking during cycling, facilitating aggravated parasitic reactions and rock-salt phase accumulation. This work provides a fundamental strategy for designing high-performance single-crystalline, Co-free, Ni-rich cathode materials and also represents an important breakthrough in developing high-safe, low-cost, and high-energy LIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 150, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 116, "End Page": 124, "Article Number": null, "DOI": "10.1016/j.esci.2022.02.006", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.02.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081745900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Noguchi, T; Matsumoto, T; Miyake, A; Igami, Y; Haruta, M; Saito, H; Hata, S; Seto, Y; Miyahara, M; Tomioka, N; Ishii, HA; Bradley, JP; Ohtaki, KK; Dobrica, E; Leroux, H; Le Guillou, C; Jacob, D; de la Peña, F; Laforet, S; Marinova, M; Langenhorst, F; Harries, D; Beck, P; Phan, TH; Rebois, R; Abreu, NM; Gray, J; Zega, T; Zanetta, PM; Thompson, MS; Stroud, R; Burgess, K; Cymes, BA; Bridges, JC; Hicks, L; Lee, MR; Daly, L; Bland, PA; Zolensky, ME; Frank, DR; Martinez, J; Tsuchiyama, A; Yasutake, M; Matsuno, J; Okumura, S; Mitsukawa, I; Uesugi, K; Uesugi, M; Takeuchi, A; Sun, MQ; Enju, S; Takigawa, A; Michikami, T; Nakamura, T; Matsumoto, M; Nakauchi, Y; Abe, M; Arakawa, M; Fujii, A; Hayakawa, M; Hirata, N; Hirata, N; Honda, R; Honda, C; Hosoda, S; Iijima, Y; Ikeda, H; Ishiguro, M; Ishihara, Y; Iwata, T; Kawahara, K; Kikuchi, S; Kitazato, K; Matsumoto, K; Matsuoka, M; Mimasu, Y; Miura, A; Morota, T; Nakazawa, S; Namiki, N; Noda, H; Noguchi, R; Ogawa, N; Ogawa, K; Okada, T; Okamoto, C; Ono, G; Ozaki, M; Saiki, T; Sakatani, N; Sawada, H; Senshu, H; Shimaki, Y; Shirai, K; Sugita, S; Takei, Y; Takeuchi, H; Tanaka, S; Tatsumi, E; Terui, F; Tsukizaki, R; Wada, K; Yamada, M; Yamada, T; Yamamoto, Y; Yano, H; Yokota, Y; Yoshihara, K; Yoshikawa, M; Yoshikawa, K; Fukai, R; Furuya, S; Hatakeda, K; Hayashi, T; Hitomi, Y; Kumagai, K; Miyazaki, A; Nakato, A; Nishimura, M; Soejima, H; Suzuki, A; Usui, T; Yada, T; Yamamoto, D; Yogata, K; Yoshitake, M; Connolly, HC ; Lauretta, DS; Yurimoto, H; Nagashima, K; Kawasaki, N; Sakamoto, N; Okazaki, R; Yabuta, H; Naraoka, H; Sakamoto, K; Tachibana, S; Watanabe, S; Tsuda, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Noguchi, Takaaki; Matsumoto, Toru; Miyake, Akira; Igami, Yohei; Haruta, Mitsutaka; Saito, Hikaru; Hata, Satoshi; Seto, Yusuke; Miyahara, Masaaki; Tomioka, Naotaka; Ishii, Hope A.; Bradley, John P.; Ohtaki, Kenta K.; Dobrica, Elena; Leroux, Hugues; Le Guillou, Corentin; Jacob, Damien; de la Pena, Francisco; Laforet, Sylvain; Marinova, Maya; Langenhorst, Falko; Harries, Dennis; Beck, Pierre; Phan, Thi H., V; Rebois, Rolando; Abreu, Neyda M.; Gray, Jennifer; Zega, Thomas; Zanetta, Pierre-M; Thompson, Michelle S.; Stroud, Rhonda; Burgess, Kate; Cymes, Brittany A.; Bridges, John C.; Hicks, Leon; Lee, Martin R.; Daly, Luke; Bland, Phil A.; Zolensky, Michael E.; Frank, David R.; Martinez, James; Tsuchiyama, Akira; Yasutake, Masahiro; Matsuno, Junya; Okumura, Shota; Mitsukawa, Itaru; Uesugi, Kentaro; Uesugi, Masayuki; Takeuchi, Akihisa; Sun, Mingqi; Enju, Satomi; Takigawa, Aki; Michikami, Tatsuhiro; Nakamura, Tomoki; Matsumoto, Megumi; Nakauchi, Yusuke; Abe, Masanao; Arakawa, Masahiko; Fujii, Atsushi; Hayakawa, Masahiko; Hirata, Naru; Hirata, Naoyuki; Honda, Rie; Honda, Chikatoshi; Hosoda, Satoshi; Iijima, Yu-ichi; Ikeda, Hitoshi; Ishiguro, Masateru; Ishihara, Yoshiaki; Iwata, Takahiro; Kawahara, Kousuke; Kikuchi, Shota; Kitazato, Kohei; Matsumoto, Koji; Matsuoka, Moe; Mimasu, Yuya; Miura, Akira; Morota, Tomokatsu; Nakazawa, Satoru; Namiki, Noriyuki; Noda, Hirotomo; Noguchi, Rina; Ogawa, Naoko; Ogawa, Kazunori; Okada, Tatsuaki; Okamoto, Chisato; Ono, Go; Ozaki, Masanobu; Saiki, Takanao; Sakatani, Naoya; Sawada, Hirotaka; Senshu, Hiroki; Shimaki, Yuri; Shirai, Kei; Sugita, Seiji; Takei, Yuto; Takeuchi, Hiroshi; Tanaka, Satoshi; Tatsumi, Eri; Terui, Fuyuto; Tsukizaki, Ryudo; Wada, Koji; Yamada, Manabu; Yamada, Tetsuya; Yamamoto, Yukio; Yano, Hajime; Yokota, Yasuhiro; Yoshihara, Keisuke; Yoshikawa, Makoto; Yoshikawa, Kent; Fukai, Ryohta; Furuya, Shizuho; Hatakeda, Kentaro; Hayashi, Tasuku; Hitomi, Yuya; Kumagai, Kazuya; Miyazaki, Akiko; Nakato, Aiko; Nishimura, Masahiro; Soejima, Hiromichi; Suzuki, Ayako, I; Usui, Tomohiro; Yada, Toru; Yamamoto, Daiki; Yogata, Kasumi; Yoshitake, Miwa; Connolly, Harold C., Jr.; Lauretta, Dante S.; Yurimoto, Hisayoshi; Nagashima, Kazuhide; Kawasaki, Noriyuki; Sakamoto, Naoya; Okazaki, Ryuji; Yabuta, Hikaru; Naraoka, Hiroshi; Sakamoto, Kanako; Tachibana, Shogo; Watanabe, Sei-ichiro; Tsuda, Yuichi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A dehydrated space-weathered skin cloaking the hydrated interior of Ryugu", "Source Title": "NATURE ASTRONOMY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Without a protective atmosphere, space-exposed surfaces of airless Solar System bodies gradually experience an alteration in composition, structure and optical properties through a collective process called space weathering. The return of samples from near-Earth asteroid (162173) Ryugu by Hayabusa2 provides the first opportunity for laboratory study of space-weathering signatures on the most abundant type of inner solar system body: a C-type asteroid, composed of materials largely unchanged since the formation of the Solar System. Weathered Ryugu grains show areas of surface amorphization and partial melting of phyllosilicates, in which reduction from Fe3+ to Fe2+ and dehydration developed. Space weathering probably contributed to dehydration by dehydroxylation of Ryugu surface phyllosilicates that had already lost interlayer water molecules and to weakening of the 2.7 mu m hydroxyl (-OH) band in reflectance spectra. For C-type asteroids in general, this indicates that a weak 2.7 mu m band can signify space-weathering-induced surface dehydration, rather than bulk volatile loss.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 84, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 170, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41550-022-01841-6", "DOI Link": "http://dx.doi.org/10.1038/s41550-022-01841-6", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Astronomy & Astrophysics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000927949200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Franzke, YJ; Holzer, C; Andersen, JH; Begusic, T; Bruder, F; Coriani, S; Della Sala, F; Fabiano, E; Fedotov, DA; Fürst, S; Gillhuber, S; Grotjahn, R; Kaupp, M; Kehry, M; Krstic, M; Mack, F; Majumdar, S; Nguyen, BD; Parker, SM; Pauly, F; Pausch, A; Perlt, E; Phun, GS; Rajabi, A; Rappoport, D; Samal, B; Schrader, T; Sharma, M; Tapavicza, E; Tress, RS; Voora, V; Wodynski, A; Yu, JM; Zerulla, B; Furche, F; Hättig, C; Sierka, M; Tew, DP; Weigend, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Franzke, Yannick; Holzer, Christof H.; Andersen, Josefine H.; Begusic, Tomislav; Bruder, Florian; Coriani, Sonia; Della Sala, Fabio; Fabiano, Eduardo; Fedotov, Daniil A.; Fuerst, Susanne; Gillhuber, Sebastian; Grotjahn, Robin; Kaupp, Martin; Kehry, Max; Krstic, Marjan; Mack, Fabian; Majumdar, Sourav; Nguyen, Brian D.; Parker, Shane M.; Pauly, Fabian; Pausch, Ansgar; Perlt, Eva; Phun, Gabriel S.; Rajabi, Ahmadreza; Rappoport, Dmitrij; Samal, Bibek; Schrader, Tim; Sharma, Manas; Tapavicza, Enrico; Tress, Robert S.; Voora, Vamsee; Wodynski, Artur; Yu, Jason M.; Zerulla, Benedikt; Furche, Filipp; Haettig, Christof; Sierka, Marek; Tew, David P.; Weigend, Florian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "TURBOMOLE: Today and Tomorrow", "Source Title": "JOURNAL OF CHEMICAL THEORY AND COMPUTATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "TURBOMOLE is a highlyoptimized software suite for large-scalequantum-chemical and materials science simulations of molecules, clusters,extended systems, and periodic solids. TURBOMOLE uses Gaussian basissets and has been designed with robust and fast quantum-chemical applicationsin mind, ranging from homogeneous and heterogeneous catalysis to inorganicand organic chemistry and various types of spectroscopy, light-matterinteractions, and biochemistry. This Perspective briefly surveys TURBOMOLE'sfunctionality and highlights recent developments that have taken placebetween 2020 and 2023, comprising new electronic structure methodsfor molecules and solids, previously unavailable molecular properties,embedding, and molecular dynamics approaches. Select features underdevelopment are reviewed to illustrate the continuous growth of theprogram suite, including nuclear electronic orbital methods, Hartree-Fock-basedadiabatic connection models, simplified time-dependent density functionaltheory, relativistic effects and magnetic properties, and multiscalemodeling of optical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 104, "Times Cited, All Databases": 104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2023, "Volume": 19, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6859, "End Page": 6890, "Article Number": null, "DOI": "10.1021/acs.jctc.3c00347", "DOI Link": "http://dx.doi.org/10.1021/acs.jctc.3c00347", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001021324700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, YX; Zhao, H; Liu, H; Zhao, P; Yu, DG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Yuexin; Zhao, Hua; Liu, Hui; Zhao, Ping; Yu, Deng-Guang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrosprayed Stearic-Acid-Coated Ethylcellulose Microparticles for an Improved Sustained Release of Anticancer Drug", "Source Title": "GELS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustained release is highly desired for efficacious, safe and convenient drug delivery, particularly for those anticancer drug molecules with toxicity. In this study, a modified coaxial electrospraying process was developed to coat a hydrophobic lipid, i.e., stearic acid (SA), on composites composed of the anticancer drug tamoxifen citrate (TC) and insoluble polymeric matrix ethylcellulose (EC). Compared with the electrosprayed TC-EC composite microparticles M1, the electrosprayed SA-coated hybrid microparticles M2 were able to provide an improved TC sustained-release profile. The 30% and 90% loaded drug sustained-release time periods were extended to 3.21 h and 19.43 h for M2, respectively, which were significantly longer than those provided by M1 (0.88 h and 9.98 h, respectively). The morphology, inner structure, physical state, and compatibility of the components of the particles M1 and M2 were disclosed through SEM, TEM, XRD, and FTIR. Based on the analyses, the drug sustained-release mechanism of multiple factors co-acting for microparticles M2 is suggested, which include the reasonable selections and organizations of lipid and polymeric excipient, the blank SA shell drug loading, the regularly round shape, and also the high density. The reported protocols pioneered a brand-new manner for developing sustained drug delivery hybrids through a combination of insoluble cellulose gels and lipid using modified coaxial electrospraying.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 62, "Times Cited, All Databases": 62, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 9, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 700, "DOI": "10.3390/gels9090700", "DOI Link": "http://dx.doi.org/10.3390/gels9090700", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Polymer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001073613400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Far, BF; Omrani, M; Jamal, MRN; Javanshir, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Far, Bahareh Farasati; Omrani, Mohsen; Jamal, Mohammad Reza Naimi; Javanshir, Shahrzad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-responsive chitosan-based hydrogels for controlled release of vincristine", "Source Title": "COMMUNICATIONS CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As medical research progresses, the derivation and development of biological materials such as hydrogels have steadily gained more interest. The biocompatibility and non-toxicity of chitosan make chitosan hydrogels potential carriers for drug delivery. This work aims to develop two multi-reactive, safe, and highly swellable bio-hydrogels consisting of chitosan-graft-glycerol (CS-g-gly) and carboxymethyl chitosan-graft-glycerol (CMCS-g-gly), for sustained and controlled drug release, improved bioavailability along with entrapment in nullocarriers, which reduces side effects of vincristine sulphate. CS-g-gly and CMCS-g-gly are successfully prepared and fully characterized using analytical techniques. Under various conditions, the prepared hydrogels exhibit a high swelling ratio. Vincristine-loaded CS-g-gly (VCR/CS-g-gly), and CMCS-g-gly (VCR/CMCS-g-gly) show high encapsulation efficiency between 72.28-89.97%, and 56.97-71.91%, respectively. VCR/CS-g-gly show a sustained release behavior, and the maximum release of VCR from hydrogels reached 82% after 120 h of incubation. MCF-7 (breast cancer cell line) and MCF-10 (normal breast cell line) are evaluated for cell viability and apoptosis induction. The in-vitro anti-tumor efficacy is investigated using flow cytometry. The tetrazolium-based MTT assay of hydrogels shows no evidence of significant cytotoxicity in MCF-7 and MCF-10 cells. According to these findings, these hydrogels can effectively deliver drugs to MCF-7 and other breast cancer cells. Hydrogels exhibit advantageous biocompatibility as carriers of chemotherapeutic agents, and those composed of natural polymers such as chitosan additionally offer biodegradability, environmental benefits, and low cost. Here, the authors develop highly swellable bio-hydrogels consisting of chitosan-graft-glycerol and carboxymethyl chitosan-graft-glycerol for sustained and pH-controlled anticancer vincristine sulfate release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2023, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28, "DOI": "10.1038/s42004-023-00829-1", "DOI Link": "http://dx.doi.org/10.1038/s42004-023-00829-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000932545200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hirthe, S; Chalopin, T; Bourgund, D; Bojovic, P; Bohrdt, A; Demler, E; Grusdt, F; Bloch, I; Hilker, TA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hirthe, Sarah; Chalopin, Thomas; Bourgund, Dominik; Bojovic, Petar; Bohrdt, Annabelle; Demler, Eugene; Grusdt, Fabian; Bloch, Immanuel; Hilker, Timon A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetically mediated hole pairing in fermionic ladders of ultracold atoms", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional superconductivity emerges from pairing of charge carriers-electrons or holes-mediated by phonons(1). In many unconventional superconductors, the pairing mechanism is conjectured to be mediated by magnetic correlations(2), as captured by models of mobile charges in doped antiferromagnets(3). However, a precise understanding of the underlying mechanism in real materials is still lacking and has been driving experimental and theoretical research for the past 40 years. Early theoretical studies predicted magnetic-mediated pairing of dopants in ladder systems(4-8), in which idealized theoretical toy models explained how pairing can emerge despite repulsive interactions(9). Here we experimentally observe this long-standing theoretical prediction, reporting hole pairing due to magnetic correlations in a quantum gas of ultracold atoms. By engineering doped antiferromagnetic ladders with mixed-dimensional couplings(10), we suppress Pauli blocking of holes at short length scales. This results in a marked increase in binding energy and decrease in pair size, enabling us to observe pairs of holes predominulltly occupying the same rung of the ladder. We find a hole-hole binding energy of the order of the superexchange energy and, upon increased doping, we observe spatial structures in the pair distribution, indicating repulsion between bound hole pairs. By engineering a configuration in which binding is strongly enhanced, we delineate a strategy to increase the critical temperature for superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 53, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 613, "Issue": 7944, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 463, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05437-y", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05437-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955590300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Donley, GJ; Singh, PK; Shetty, A; Rogers, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Donley, Gavin J.; Singh, Piyush K.; Shetty, Abhishek; Rogers, Simon A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elucidating the G overshoot in soft materials with a yield transition via a time-resolved experimental strain decomposition", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials that exhibit yielding behavior are used in many applications, from spreadable foods and cosmetics to direct write three-dimensional printing inks and filled rubbers. Their key design feature is the ability to transition behaviorally from solid to fluid under sufficient load or deformation. Despite its widespread applications, little is known about the dynamics of yielding in real processes, as the nonequilibrium nature of the transition impedes understanding. We demonstrate an iteratively punctuated rheological protocol that combines strain-controlled oscillatory shear with stress-controlled recovery tests. This technique provides an experimental decomposition of recoverable and unrecoverable strains, allowing for solidlike and fluid-like contributions to a yield stress material's behavior to be separated in a time-resolved manner. Using this protocol, we investigate the overshoot in loss modulus seen in materials that yield. We show that this phenomenon is caused by the transition from primarily solid-like, viscoelastic dissipation in the linear regime to primarily fluid-like, plastic flow at larger amplitudes. We compare and contrast this with a viscoelastic liquid with no yielding behavior, where the contribution to energy dissipation from viscous flow dominates over the entire range of amplitudes tested.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 149, "Times Cited, All Databases": 156, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 8", "Publication Year": 2020, "Volume": 117, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 21945, "End Page": 21952, "Article Number": null, "DOI": "10.1073/pnas.2003869117", "DOI Link": "http://dx.doi.org/10.1073/pnas.2003869117", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572967300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Melaibari, A; Daikh, AA; Basha, M; Abdalla, AW; Othman, R; Almitani, KH; Hamed, MA; Abdelrahman, A; Eltaher, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Melaibari, Ammar; Daikh, Ahmed Amine; Basha, Muhammad; Abdalla, Ahmed W.; Othman, Ramzi; Almitani, Khalid H.; Hamed, Mostafa A.; Abdelrahman, Alaa; Eltaher, Mohamed A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Free Vibration of FG-CNTRCs nullo-Plates/Shells with Temperature-Dependent Properties", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article presents a mathematical continuum model to analyze the free vibration response of cross-ply carbon-nullotube-reinforced composite laminated nulloplates and nulloshells, including microstructure and length scale effects. Different shell geometries, such as plate (infinite radii), spherical, cylindrical, hyperbolic-paraboloid and elliptical-paraboloid are considered in the analysis. By employing Hamilton's variational principle, the equations of motion are derived based on hyperbolic sine function shear deformation theory. Then, the derived equations are solved analytically using the Galerkin approach. Two types of material distribution are proposed. Higher-order nonlocal strain gradient theory is employed to capture influences of shear deformation, length scale parameter (nonlocal) and material/microstructurescale parameter (gradient). Temperature-dependent material properties are considered. The validation of the proposed mathematical model is presented. Detailed parametric analyses are carried out to highlight the effects of the carbon nullotubes (CNT) distribution pattern, the thickness stretching, the geometry of the plate/shell, the boundary conditions, the total number of layers, the length scale and the material scale parameters, on the vibrational frequencies of CNTRC laminated nulloplates and nulloshells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 583, "DOI": "10.3390/math10040583", "DOI Link": "http://dx.doi.org/10.3390/math10040583", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000774288000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tran, VT; Nguyen, TK; Nguyen-Xuan, H; Wahab, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Van-Thien Tran; Trung-Kien Nguyen; Nguyen-Xuan, H.; Wahab, Magd Abdel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vibration and buckling optimization of functionally graded porous microplates using BCMO-ANN algorithm", "Source Title": "THIN-WALLED STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A BCMO-ANN algorithm for vibration and buckling optimization of functionally graded porous (FGP) microplates is proposed in this paper. The theory is based on a unified framework of higher-order shear deformation theory and modified couple stress theory. A combination of artificial neural network (ANN) and balancing composite motion optimization (BCMO) is developed to solve the optimization problems and predict stochastic vibration and buckling behaviors of functionally graded porous microplates with uncertainties of material properties. The characteristic equations are derived from Hamilton's principle and approximation of field variables under Ritz-type exponential series. Numerical results are obtained to investigate the effects of the material distribution, material length scale, porosity density and boundary conditions on natural frequencies and critical buckling loads of functionally graded porous microplates. The novel results derived from this paper can be used as future references.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 144, "Times Cited, All Databases": 144, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 182, "Issue": null, "Part Number": "B", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 110267, "DOI": "10.1016/j.tws.2022.110267", "DOI Link": "http://dx.doi.org/10.1016/j.tws.2022.110267", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000880128200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CY; Zhang, CQ; Pan, JL; Sun, GW; Shi, ZD; Li, CH; Chang, XQ; Sun, GZ; Zhou, JY; Cabot, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chao Yue; Zhang, Chaoqi; Pan, Jiang Long; Sun, Guo Wen; Shi, Zude; Li, Canhuang; Chang, Xingqi; Sun, Geng Zhi; Zhou, Jin Yuan; Cabot, Andreu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Surface strain-enhanced MoS2 as a high-performance cathode catalyst for lithium-sulfur batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries (LSBs) are one of the main candidates for the next generation of energy storage systems. To improve the performance of LSBs, we herein propose the use of strained MoS2 (s-MoS2) as a catalytically active sulfur host. The introduction of strain in the MoS2 surface, which alters its atomic positions and expands the S-Mo-S angle, shifts the d-band center closer to the Fermi level and provides the surface with abundant and highly active catalytic sites; these enhance the catalyst's ability to adsorb lithium polysulfides (LiPS), accelerating its catalytic conversion and promoting lithium-ion transferability. Strain is generated through the synthesis of core-shell nulloparticles, using different metal sulfides as strain-inducing cores. s-MoS2 nulloparticles are sup-ported on carbon nullofibers (CNF/s-MoS2), and the resulting electrodes are characterized by capacities of 1290 and 657 mAh g-1 at 0.2 and 5 C, respectively, with a 0.05% capacity decay rate per cycle at 8 C during 700 cycles. Overall, this work not only provides an ingenious and effective strategy to regulate LiPS adsorption and con-version through strain engineering, but also indicates a path toward the application of strain engineering in other energy storage and conversion fields.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 98, "Times Cited, All Databases": 101, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 405, "End Page": 415, "Article Number": null, "DOI": "10.1016/j.esci.2022.07.001", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.07.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080904600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saykin, DR; Farhang, C; Kountz, ED; Chen, D; Ortiz, BR; Shekhar, C; Felser, C; Wilson, SD; Thomale, R; Xia, J; Kapitulnik, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saykin, David R.; Farhang, Camron; Kountz, Erik D.; Chen, Dong; Ortiz, Brenden R.; Shekhar, Chandra; Felser, Claudia; Wilson, Stephen D.; Thomale, Ronny; Xia, Jing; Kapitulnik, Aharon", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Resolution Polar Kerr Effect Studies of CsV3Sb5: Tests for Time-Reversal Symmetry Breaking below the Charge-Order Transition", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report high resolution polar Kerr effect measurements on CsV3Sb5 single crystals in search of signatures of spontaneous time-reversal symmetry breaking below the charge-order transition at T* 94 K. Utilizing two different versions of zero-area loop Sagnac interferometers operating at 1550 nm wavelength, each with the fundamental attribute that without a time-reversal symmetry breaking sample at its path, the interferometer is perfectly reciprocal, we find no observable Kerr effect to within the noise floor limit of the apparatus at 30 nulloradians. Simultaneous coherent reflection ratio measurements confirm the sharpness of the charge-order transition in the same optical volume as the Kerr measurements. At finite magnetic field we observe a sharp onset of a diamagnetic shift in the Kerr signal at T* , which persists down to the lowest temperature without change in trend. Since 1550 nm is an energy that was shown to capture all features of the optical properties of the material that interact with the charge-order transition, we are led to conclude that it is highly unlikely that time-reversal symmetry is broken in the charge ordered state in CsV3Sb5.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 48, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2023, "Volume": 131, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16901, "DOI": "10.1103/PhysRevLett.131.016901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.131.016901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001052998900013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kawamura, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kawamura, Mitsuaki", "Book Author Full Names": null, "Group Authors": null, "Article Title": "FermiSurfer: Fermi-surface viewer providing multiple representation schemes", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "FermiSurfer is a newly developed Fermi-surface viewer designed to facilitate the understanding of the physical properties of metals. It can display the Fermi surfaces of a material, color plots of arbitrary k-dependent quantities, the Fermi surface at arbitrary cross sections (Fermi lines), cross- or parallel-eye three-dimensional stereogram views, nodal lines, extremal orbits, and highlight the occupied or empty side of the Fermi surface. In addition, various first-principles software packages can produce input for FermiSurfer. This paper explains how to use FermiSurfer and demonstrates its usefulness by investigating the origin of the anisotropic superconductivity of YNi2B2C. (C) 2019 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 248, "Times Cited, All Databases": 259, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 239, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 197, "End Page": 203, "Article Number": null, "DOI": "10.1016/j.cpc.2019.01.017", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2019.01.017", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466248000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Winter, SM; Riedl, K; Maksimov, PA; Chernyshev, AL; Honecker, A; Valentí, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Winter, Stephen M.; Riedl, Kira; Maksimov, Pavel A.; Chernyshev, Alexander L.; Honecker, Andreas; Valenti, Roser", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Breakdown of magnons in a strongly spin-orbital coupled magnet", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The description of quantized collective excitations stands as a landmark in the quantum theory of condensed matter. A prominent example occurs in conventional magnets, which support bosonic magnons-quantized harmonic fluctuations of the ordered spins. In striking contrast is the recent discovery that strongly spin-orbital-coupled magnets, such as alpha-RuCl3, may display a broad excitation continuum inconsistent with conventional magnons. Due to incomplete knowledge of the underlying interactions unraveling the nature of this continuum remains challenging. The most discussed explanation refers to a coherent continuum of fractional excitations analogous to the celebrated Kitaev spin liquid. Here, we present a more general scenario. We propose that the observed continuum represents incoherent excitations originating from strong magnetic anharmonicity that naturally occurs in such materials. This scenario fully explains the observed inelastic magnetic response of a-RuCl3 and reveals the presence of nontrivial excitations in such materials extending well beyond the Kitaev state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 202, "Times Cited, All Databases": 218, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 27", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1152, "DOI": "10.1038/s41467-017-01177-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01177-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413832800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, J; Wang, DP; Si, GY; Teo, SL; Wang, QA; Lin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jia; Wang, Dapeng; Si, Guangyuan; Teo, Siew Lang; Wang, Qian; Lin, Jiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Planar peristrophic multiplexing metasurfaces", "Source Title": "OPTO-ELECTRONIC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As a promising counterpart of two-dimensional metamaterials, metasurfaces enable to arbitrarily control the wavefront of light at subwavelength scale and hold promise for planar holography and applicable multiplexing devices. Nevertheless, the degrees of freedom (DoF) to orthogonally multiplex data have been almost exhausted. Compared with state-of-the-art methods that extensively employ the orthogonal basis such as wavelength, polarization or orbital angular momentum, we propose an unprecedented method of peristrophic multiplexing by combining the spatial frequency orthogonality with the subwavelength detour phase principle. The orthogonal relationship between the spatial frequency of incident light and the locally shifted building blocks of metasurfaces can be regarded as an additional DoF. We experimentally demon-strate the viability of the multiplexed holograms. Moreover, this newly-explored orthogonality is compatible with conven-tional DoFs. Our findings will contribute to the development of multiplexing metasurfaces and provide a novel solution to nullophotonics, such as large-capacity chip-scale devices and highly integrated communication.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 75, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2023, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 220141, "DOI": "10.29026/oea.2023.220141", "DOI Link": "http://dx.doi.org/10.29026/oea.2023.220141", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001087391200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SL; Wang, PY; Chen, BB; Li, RJ; Ren, NY; Li, YC; Shi, B; Huang, Q; Zhao, Y; Grätzel, M; Zhang, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sanlong; Wang, Pengyang; Chen, Bingbing; Li, Renjie; Ren, Ningyu; Li, Yucheng; Shi, Biao; Huang, Qian; Zhao, Ying; Gratzel, Michael; Zhang, Xiaodan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Suppressed recombination for monolithic inorganic perovskite/silicon tandem solar cells with an approximate efficiency of 23%", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potentially temperature-resistant inorganic perovskite/silicon tandem solar cells (TSCs) are promising devices for boosting efficiency past the single-junction silicon limit. However, undesirable non-radiative recombination generally leads to a significant voltage deficit. Here, we introduce an effective strategy using nickel iodide, an inorganic halide salt, to passivate iodine vacancies and suppress non-radiative recombination. NiI2-treated CsPbI3-xBrx inorganic perovskite solar cells with a 1.80 eV bandgap exhibited an efficiency of 19.53% and a voltage of 1.36 V, corresponding to a voltage deficit of 0.44 V. Importantly, the treated device demonstrated excellent operational stability, maintaining 95.7% of its initial efficiency after maximum power point tracking for 300 h under continuous illumination in a N2 atmosphere. By combining this inorganic perovskite top cell with a narrower bandgap silicon bottom cell, we for the first time achieved monolithic inorganic perovskite/silicon TSCs, which exhibited an efficiency of 22.95% with an open-circuit voltage of 2.04 V. This work provides a promising strategy for using inorganic passivation materials to achieve efficient and stable solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 111, "Times Cited, All Databases": 114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 2, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 339, "End Page": 346, "Article Number": null, "DOI": "10.1016/j.esci.2022.04.001", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.04.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080902100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Günther, MM; Rosmej, ON; Tavana, P; Gyrdymov, M; Skobliakov, A; Kantsyrev, A; Zähter, S; Borisenko, NG; Pukhov, A; Andreev, NE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guenther, M. M.; Rosmej, O. N.; Tavana, P.; Gyrdymov, M.; Skobliakov, A.; Kantsyrev, A.; Zahter, S.; Borisenko, N. G.; Pukhov, A.; Andreev, N. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Forward-looking insights in laser-generated ultraintense γ-ray and neutron sources for nuclear application and science", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-intense MeV photon and neutron beams are indispensable tools in many research fields such as nuclear, atomic and material science as well as in medical and biophysical applications. For applications in laboratory nuclear astrophysics, neutron fluxes in excess of 10(21) n/ (cm(2) s) are required. Such ultra-high fluxes are unattainable with existing conventional reactor- and accelerator-based facilities. Currently discussed concepts for generating highflux neutron beams are based on ultra-high power multi-petawatt lasers operating around 10(23) W/cm(2) intensities. Here, we present an efficient concept for generating gamma and neutron beams based on enhanced production of direct laser-accelerated electrons in relativistic laser interactions with a long-scale near critical density plasma at 10(19) W/cm(2) intensity. Experimental insights in the laser-driven generation of ultra-intense, well-directed multi-MeV beams of photons more than 10(12) ph/sr and an ultra-high intense neutron source with greater than 6 x 10(10) neutrons per shot are presented. More than 1.4% laser-to-gamma conversion efficiency above 10 MeV and 0.05% laser-to-neutron conversion efficiency were recorded, already at moderate relativistic laser intensities and ps pulse duration. This approach promises a strong boost of the diagnostic potential of existing kJ PW laser systems used for Inertial Confinement Fusion (ICF) research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 79, "Times Cited, All Databases": 92, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 170, "DOI": "10.1038/s41467-021-27694-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27694-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000916631400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Melaibari, A; Daikh, AA; Basha, M; Wagih, A; Othman, R; Almitani, KH; Hamed, MA; Abdelrahman, A; Eltaher, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Melaibari, Ammar; Daikh, Ahmed Amine; Basha, Muhammad; Wagih, Ahmed; Othman, Ramzi; Almitani, Khalid H.; Hamed, Mostafa A.; Abdelrahman, Alaa; Eltaher, Mohamed A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Dynamic Analysis of Randomly Oriented Functionally Graded Carbon nullotubes/Fiber-Reinforced Composite Laminated Shells with Different Geometries", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The present study demonstrates the free vibration behavior of composite laminated shells reinforced by both randomly oriented single-walled carbon nullotubes (SWCNTs) and functionally graded fibers. The shell structures with different principal radii of curvature are considered, such as cylindrical, spherical, elliptical-paraboloid shell, hyperbolic-paraboloid shell, and plate. The volume fraction of the fibers has a linear variation along the shell thickness from layer to layer, while the volume fraction of CNTs is constant in all shell layers and uniformly distributed. The fiber-reinforced elements are distributed with three functions which are V-distribution, O-distribution, and X-distribution in addition to the uniform distribution. A numerical analysis was carried out systematically to validate the proposed solution. A new analytical solution is presented based on the Galerkin approach for shells and is exploited to illustrate the influence of some factors on the free vibration behavior of CNTs/fibe-reinforced composite (CNTs/F-RC) laminated shells, including the distributions and volume fractions, various boundary conditions, and geometrical properties of the reinforcement materials. The proposed solution is shown to be an effective theoretical tool to analyze the free vibration response of shells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 35, "Times Cited, All Databases": 35, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 408, "DOI": "10.3390/math10030408", "DOI Link": "http://dx.doi.org/10.3390/math10030408", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000756534000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Speranza, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Speranza, Giorgio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning the Oxygen Content of Reduced Graphene Oxide and Effects on Its Properties", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The need to recover the graphene properties in terms of electrical and thermal conductivity calls for the application of reduction processes leading to the removal of oxygen atoms from the graphene oxide sheet surface. The recombination of carbon-carbon double bonds causes a partial recovery of the original graphene properties mainly limited by the presence of residual oxygen atoms and lattice defects. However, the loss of polar oxygen-based functional groups renders the material dispersibility rather complicated. In addition, oxygen-containing functional groups are reaction sites useful to further bind active molecules to engineer the reduced graphene sheets. For these reasons, a variety of chemical processes are described in the literature to reduce the graphene oxide. However, it is greatly important to select a chemical process enabling a thin modulation of the residual oxygen content thus tuning the properties of the final product. In this work, we will present a chemical-processing technique based on the hydroiodic acid to carefully control the degree of residual oxidation. Graphene oxides were reduced using hydroiodic acid with concentrations from 0.06 to 0.95 mol L-1. Their properties were characterized in detail and tested, and the results showed that their oxygen content was finely tuned from 33.6 to 10.7 atom %. This allows carefully tailoring the material properties with respect to the desired application, which is exemplified by the variation of the bulk resistance from 92 Omega to 14.8 M Omega of the film from the obtained rGO.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 174, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2021, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6195, "End Page": 6205, "Article Number": null, "DOI": "10.1021/acsomega.0c05578", "DOI Link": "http://dx.doi.org/10.1021/acsomega.0c05578", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629031700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, Y; Fan, CM; Fu, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Yan; Fan, Chia-Ming; Fu, Zhuojia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Localized Method of Fundamental Solutions for Three-Dimensional Elasticity Problems: Theory", "Source Title": "ADVANCES IN APPLIED MATHEMATICS AND MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A localized version of the method of fundamental solution (LMFS) is devised in this paper for the numerical solutions of three-dimensional (3D) elasticity problems. The present method combines the advantages of high computational efficiency of localized discretization schemes and the pseudo-spectral convergence rate of the classical MFS formulation. Such a combination will be an important improvement to the classical MFS for complicated and large-scale engineering simulations. Numerical examples with up to 100,000 unknowns can be solved without any difficulty on a personal computer using the developed methodologies. The advantages, disadvantages and potential applications of the proposed method, as compared with the classical MFS and boundary element method (BEM), are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 50, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2021, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1520, "End Page": 1534, "Article Number": null, "DOI": "10.4208/aamm.OA-2020-0134", "DOI Link": "http://dx.doi.org/10.4208/aamm.OA-2020-0134", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000691691900010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hemlata; Meena, PR; Singh, AP; Tejavath, KK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hemlata; Meena, Prem Raj; Singh, Arvind Pratap; Tejavath, Kiran Kumar", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biosynthesis of Silver nulloparticles Using Cucumis prophetarum Aqueous Leaf Extract and Their Antibacterial and Antiproliferative Activity Against Cancer Cell Lines", "Source Title": "ACS OMEGA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biosynthesized nulloparticles are gaining attention because of biologically active plant secondary metabolites that help in green synthesis and also due to their unique biological applications. This study reports a facile, ecofriendly, reliable, and cost-effective synthesis of silver nulloparticles using the aqueous leaf extract of Cucumis prophetarum (C. prophetarum) and their antibacterial and antiproliferative activity. Silver nulloparticles were biosynthesized using the aqueous leaf extract of C. prophetarum, which acted as a reducing and capping agent. The biosynthesized C. prophetarum silver nulloparticles (Cp-AgNPs) were characterized using different techniques, such as UV-visible spectroscopy, dynamic light scattering (DLS), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDAX). Phytochemical analysis was performed to determine the phytochemicals responsible for the reduction and capping of the biosynthesized Cp-AgNPs. The antioxidant activity of the biosynthesized nulloparticles was determined using 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 3-ethylbenzothiazoline-6-sulfonic acid (ARTS) assays. Their antibacterial activity was checked against Staphylococcus aureus (Gram- positive) and Salmonella typhi (Gram-negative) bacteria. The biosynthesized nulloparticles showed dosage-dependent inhibition activity with a significant zone of inhibition and were more effective toward S. typhi as compared to S. aureus. Their antiproliferative activity was evaluated using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay on selected cancer cell lines. The IC50 values of Cp-AgNPs on A549, MDA MB 231, HepG2, and MCF-7 were found to be 105.8, 81.1, 94.2, and 65.6 mu g/mL, respectively, and this showed that the Cp-AgNPs were more potent toward MCF-7 as compared to other cell lines used in this study. This work revealed that the biosynthesized silver nulloparticles using C. prophetarum leaf extract were associated with good antibacterial activity and antiproliferative potential against selected cancer cell lines. The biosynthesized C. prophetarum AgNPs can be further exploited as a potential candidate for antioxidant, antibacterial, and anticancer agents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 295, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2020, "Volume": 5, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5520, "End Page": 5528, "Article Number": null, "DOI": "10.1021/acsomega.0c00155", "DOI Link": "http://dx.doi.org/10.1021/acsomega.0c00155", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520853400090", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, SD; Liu, ZH; Migorski, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Shengda; Liu, Zhenhai; Migorski, Stanislaw", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A class of fractional differential hemivariational inequalities with application to contact problem", "Source Title": "ZEITSCHRIFT FUR ANGEWANDTE MATHEMATIK UND PHYSIK", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, we study a class of generalized differential hemivariational inequalities of parabolic type involving the time fractional order derivative operator in Banach spaces. We use the Rothe method combined with surjectivity of multivalued pseudomonotone operators and properties of the Clarke generalized gradient to establish existence of solution to the abstract inequality. As an illustrative application, a frictional quasistatic contact problem for viscoelastic materials with adhesion is investigated, in which the friction and contact conditions are described by the Clarke generalized gradient of nonconvex and nonsmooth functionals, and the constitutive relation is modeled by the fractional Kelvin-Voigt law.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 69, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 36, "DOI": "10.1007/s00033-018-0929-6", "DOI Link": "http://dx.doi.org/10.1007/s00033-018-0929-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428112300016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Belkorissat, I; Houari, MSA; Tounsi, A; Bedia, EAA; Mahmoud, SR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Belkorissat, Ismahene; Houari, Mohammed Sid Ahmed; Tounsi, Abdelouahed; Bedia, E. A. Adda; Mahmoud, S. R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On vibration properties of functionally graded nullo-plate using a new nonlocal refined four variable model", "Source Title": "STEEL AND COMPOSITE STRUCTURES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this paper, a new nonlocal hyperbolic refined plate model is presented for free vibration properties of functionally graded (FG) plates. This nonlocal nullo-plate model incorporates the length scale parameter which can capture the small scale effect. The displacement field of the present theory is chosen based on a hyperbolic variation in the in-plane displacements through the thickness of the nullo-plate. By dividing the transverse displacement into the bending and shear parts, the number of unknowns and equations of motion of the present theory is reduced, significantly facilitating structural analysis. The material properties are assumed to vary only in the thickness direction and the effective properties for the FG nullo-plate are computed using Mori-Tanaka homogenization scheme. The governing equations of motion are derived based on the nonlocal differential constitutive relations of Eringen in conjunction with the refined four variable plate theory via Hamilton's principle. Analytical solution for the simply supported FG nullo-plates is obtained to verify the theory by comparing its results with other available solutions in the open literature. The effects of nonlocal parameter, the plate thickness, the plate aspect ratio, and various material compositions on the dynamic response of the FG nullo-plate are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 342, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 18, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1063, "End Page": 1081, "Article Number": null, "DOI": "10.12989/scs.2015.18.4.1063", "DOI Link": "http://dx.doi.org/10.12989/scs.2015.18.4.1063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352370400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bassam, AM; Sopian, K; Ibrahim, A; Al-Aasam, AB; Dayer, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bassam, Abdulsahib M.; Sopian, Kamaruzzaman; Ibrahim, Adnull; Al-Aasam, Anwer B.; Dayer, Mojtaba", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental analysis of photovoltaic thermal collector (PVT) with nullo PCM and micro-fins tube counterclockwise twisted tape nullofluid", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A hybrid PVT (photovoltaic thermal system) nullofluid circulation system was tested, which included a micro-fin tube (inner grooved) and twisted tape with nullo PCM (phase change material). The use of nulloparticles allowed the nullo PCM and nullofluid to have higher thermal conductivities, improving their performance. Experiments were carried out within a controlled environment by utilizing an indoor solar simulator with a solar irradiance level of 800W/m2. The PVT system used water/SiC (0.6, 0.3) vol% nullofluid as a working fluid. The nulloPCM comprises 1% SiC nulloparticles, which enhance thermal, electrical (photovoltaic), and photovoltaic thermal efficiency (total efficiency). The mass flow rate range is 0.008-0.058 kg/s. The energy analysis showed that the PVT had an electrical efficiency of 10.8%. The system's maximum thermal efficacy was 83.3% for the PVT with the T (twisted tape), MF (micro-fins), NF (nullofluids), and NPCM (nullo PCM). The percentage of improved electrical power compared between the bare PV and the PVT NF T NF NPCM was 44.5%. The micro fin tube with twisted tape improved the heat transfer properties for enhanced thermal performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 63, "Times Cited, All Databases": 63, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 45, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102883, "DOI": "10.1016/j.csite.2023.102883", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2023.102883", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971344000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, JR; Wang, B; Hao, JX; Ding, HB; Fan, L; Tao, RQ; Yang, HG; Zhou, J; Lu, BA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Jiarui; Wang, Bin; Hao, Jiaxin; Ding, Hongbo; Fan, Ling; Tao, Renqian; Yang, Hongguan; Zhou, Jiang; Lu, Bingan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-crystalline Mn-based oxide as a high-rate and long-life cathode material for potassium-ion battery", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mn-based oxides are promising cathode materials for potassium-ion batteries due to their high theoretical capacity and abundant raw materials. However, the anisotropic properties of their conventional polycrystalline structures lead to insufficient rate capability and cycle life. Here, a single-crystal Mn-based layered oxide, P3'-type K0.35Mn0.8Fe0.1Cu0.1O2 (KMFCO), is designed and synthesized through a bimetallic co-induction effect and used as a cathode for potassium-ion battery. Benefiting from a unique single-crystal structure that is devoid of grain boundaries, it achieves a higher K+ transport rate and a reduced volume change during the K+ intercalation/ deintercalation process. Accordingly, the single-crystal P3'-type KMFCO delivers superior rate capability (52.9 mAh g-1 at 1000 mA g-1) and excellent cycling stability (91.1% capacity retention after 500 cycles at 500 mA g-1). A full cell assembled with the P3'-type KMFCO cathode and a graphite anode also exhibits a high reversible capacity (81.2 mAh g-1 at 100 mA g-1) and excellent cycling performance (97% capacity retention after 300 cycles). The strategy of developing single-crystal materials may offer a new pathway for maintaining structural stability and improving the rate capability of layered manganese oxide cathodes and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 100081, "DOI": "10.1016/j.esci.2022.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081080300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Akgöz, B; Civalek, Ö", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Akgoz, Bekir; Civalek, Omer", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Buckling Analysis of Functionally Graded Tapered Microbeams via Rayleigh-Ritz Method", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present study, the buckling problem of nonhomogeneous microbeams with a variable cross-section is analyzed. The microcolumn considered in this study is made of functionally graded materials in the longitudinal direction and the cross-section of the microcolumn varies continuously throughout the axial direction. The Bernoulli-Euler beam theory in conjunction with modified strain gradient theory are employed to model the structure by considering the size effect. The Rayleigh-Ritz numerical solution method is used to solve the eigenvalue problem for various conditions. The influences of changes in the cross-section and Young's modulus, size dependency, and non-classical boundary conditions are examined in detail. It is observed that the size effect becomes more pronounced for smaller sizes and differences between the classical and non-classical buckling loads increase by increasing the taper ratios.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 106, "Times Cited, All Databases": 106, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 10, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4429, "DOI": "10.3390/math10234429", "DOI Link": "http://dx.doi.org/10.3390/math10234429", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000896278600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Zuo, YX; Ye, WK; Li, XG; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Zuo, Yunxing; Ye, Weike; Li, Xiangguo; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Learning properties of ordered and disordered materials from multi-fidelity data", "Source Title": "NATURE COMPUTATIONAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting the properties of a material from the arrangement of its atoms is a fundamental goal in materials science. While machine learning has emerged in recent years as a new paradigm to provide rapid predictions of materials properties, their practical utility is limited by the scarcity of high-fidelity data. Here, we develop multi-fidelity graph networks as a universal approach to achieve accurate predictions of materials properties with small data sizes. As a proof of concept, we show that the inclusion of low-fidelity Perdew-Burke-Ernzerhof band gaps greatly enhances the resolution of latent structural features in materials graphs, leading to a 22-45% decrease in the mean absolute errors of experimental band gap predictions. We further demonstrate that learned elemental embeddings in materials graph networks provide a natural approach to model disorder in materials, addressing a fundamental gap in the computational prediction of materials properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 153, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 46, "End Page": "+", "Article Number": null, "DOI": "10.1038/s43588-020-00002-x", "DOI Link": "http://dx.doi.org/10.1038/s43588-020-00002-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888550400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jaffri, SB; Ahmad, KS; Abrahams, I; Kousseff, CJ; Nielsen, CB; Almutairi, BO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jaffri, Shaan Bibi; Ahmad, Khuram Shahzad; Abrahams, Isaac; Kousseff, Christina J.; Nielsen, Christian B.; Almutairi, Bader O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rare earth (Sm/Eu/Tm) doped ZrO2 driven electro-catalysis, energy storage, and scaffolding in high-performance perovskite solar cells", "Source Title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current work presents the first report on the modification of zirconia (ZrO2) by doping it with the lanthanides oxides i.e. [samarium, europium, and thulium] forming a [Sm/Eu/Tm] co-doped ZrO2 system. Lanthanide doping tailored the structure of host material by causing considerable bandgap energy shrinkage from 4.04 to 3.57 eV and reduction in the crystallite size from 67.92 to 45.23 nm. Profound electro-catalytic potential was reflected analyzed via linear sweep voltammetry showing the excellent of developed catalytic to-wards H2 evolution with lower overpotential i.e. 133 mV and Tafel slope of 119.3 mV dec-1. While for O2 evolution, the electro-catalyst succeeded in gaining overpotential and Tafel slope values of 310 mV and 294.8 mV dec-1, respectively. With such values, this material has surpassed the conventional electro-catalysts and is proved to be an excellent hydrogen producing electro-catalyst. The electrical charge storage potential was analyzed for [Sm/ Eu/Tm] co-doped ZrO2 decorated nickel foam electrode for development into a super-capacitor. This electrode was impressively stable for 10 cycles after 20 days checked through cyclic voltammetry. Furthermore, an augmented specific capacitance of 447 F g-1was achieved by the doped electrode when compared with the pristine one approaching 83.69 F g-1. The electrical energy storage capacity of [Sm/Eu/Tm] co-doped ZrO2 is even higher than the conventionally used metal oxides. In terms of the interfacial electrode electrolyte, electrochemical impedance spectroscopy was done expressing the excellent ionic diffusion and electrochemically active sites for [Sm/Eu/Tm] co-doped ZrO2 electrode with minimal resistance. The developed doped system was used a spacer layer in a cesium lead halide perovskite solar cells having planar architecture. The spacer layer containing solar cell device succeeded in gaining a power conversion efficiency of 16.31% and a fill factor of 78% evaluated via photo-current measurements carried out under artificial solar irradiance. The impressively higher fill factor shows the effective passivation and scaffolding by the [Sm/Eu/Tm] co-doped ZrO2. The associated device was also marked by negligible hysteresis. Chrono-potentiometry and chrono-amperometry expressed commendable accelerated service lives for 100 min inside an electrolyte. The lanthanide co-doped ZrO2 is an effective material for the utilization in energy systems associated with the electro-catalysis of water, charge storage electrode for super-capacitors, and photovoltaic solar to electrical energy conversion. .(c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 47, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2023, "Volume": 48, "Issue": 75, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 29119, "End Page": 29141, "Article Number": null, "DOI": "10.1016/j.ijhydene.2023.04.085", "DOI Link": "http://dx.doi.org/10.1016/j.ijhydene.2023.04.085", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001122861400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, H; Soldatov, MA; Roldugin, V; Liu, QH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Hui; Soldatov, Mikhail A.; Roldugin, Victor; Liu, Qinghua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum single-atom catalyst with self-adjustable valence state for large-current-density acidic water oxidation", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The design of active acidic oxygen evolution reaction (OER) catalysts is of paramount importance to achieve efficient large-current-density industrial hydrogen fuel production via water electrolysis. Herein, we develop a Pt-based catalyst with high electrochemical activity for the OER in acidic conditions under a large current. We achieve this by modulating the electronic structure of Pt into a high-valence, electron-accessible Pt-1((2.4+delta)+)(delta = 0-0.7) state during the reaction. This electron-accessible Pt-1((2.4+delta)+) single-site catalyst can effectively maintain a large OER current density of 120 mA cm(-2) for more than 12 h in 0.5 M H2SO4 at a low overpotential of 405 mV, and it shows a high mass activity of similar to 3350 A g(metal)(-1) at 10 mA cm(-2) current density and 232 mV overpotential. Using in situ synchrotron radiation infrared and X-ray absorption spectroscopies, we directly observe in an experiment that a key (*O)-Pt-1-C2N2 intermediate is produced by the potential-driven structural optimization of square pyramidal Pt-1-C2N2 moieties; this highly favors the dissociation of H2O over Pt-1((2.4+delta)+) sites and prevents over-oxidation and dissolution of the active sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 147, "Times Cited, All Databases": 155, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 102, "End Page": 109, "Article Number": null, "DOI": "10.1016/j.esci.2021.12.007", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2021.12.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001081749000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dong, JF; Guan, ZW; Chai, H; Wang, QY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dong, J. F.; Guan, Z. W.; Chai, H. K.; Wang, Q. Y.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High temperature behaviour of basalt fibre-steel tube reinforced concrete columns with recycled aggregates under monotonous and fatigue loading", "Source Title": "CONSTRUCTION AND BUILDING MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Experimental and numerical investigations were carried out to evaluate the effects of incorporating recycled coarse aggregates (RCA) on the mechanical behaviour of inner steel-tube reinforced concrete columns exposed to high temperature. The specimens were reinforced with basalt fibres (BF) and strengthened by carbon fibre reinforced polymer (CFRP) sheets, which were subjected to mechanical loading in monotonous and cyclic ar-rangements. Test results show that at room temperature (RT), incorporation of the chopped BF has reduced both the tensile strength and flexural strength of concrete specimens prepared with recycled aggregate concrete (RAC) but not their static elastic modulus. On the other hand, the BF has improved crack resistance of the steel tube reinforced RAC (STRC) column specimens. Also, the reduction in mass and dynamic elastic modulus of BF reinforced STRC specimens are lower than those of STRC at a given RCA replacement ratio and exposure tem-perature. Furthermore, improvements in mechanical performance under monotonous and fatigue loading was observed for STRC columns reinforced with BF and externally bonded CFRP sheets with high-temperature exposure (HTE). Therefore, it is possible that BF reinforced STRC columns could be used to reduce risk of brittle structural collapse when exposed to fire or elevated temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 67, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2023, "Volume": 389, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 131737, "DOI": "10.1016/j.conbuildmat.2023.131737", "DOI Link": "http://dx.doi.org/10.1016/j.conbuildmat.2023.131737", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "N", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002054100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naseer, KA; Marimuthu, K; Mahmoud, KA; Sayyed, MI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naseer, K. A.; Marimuthu, K.; Mahmoud, K. A.; Sayyed, M. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Impact of Bi2O3 modifier concentration on barium-zincborate glasses: physical, structural, elastic, and radiation-shielding properties", "Source Title": "EUROPEAN PHYSICAL JOURNAL PLUS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A sequence of Bi2O3 varying barium-zincborate (BZX) glasses with the chemical composition (60-x) B2O3-20ZnO-20BaCO(3)-xBi(2)O(3)-0.5Dy(2)O(3) (where x=0, 5, 10, 15, 20, 25, and 30 in wt%) is fabricated by melt-quenching method. The fabricated samples were examined for the variation in physical, structural, elastic, and radiation-shielding properties with the Bi2O3 concentration. The structural and compositional evaluations are done using XRD and FTIR spectra. The BZX matrixes consist of the trigonal-planar and tetrahedral groups of borates, BiO3 and BiO6 units of Bi2O3, and the non-bridging oxygen in general. The average single-bond strength values substantiate the increasing ionic nature of the BZX glasses. The variation in the density and molar volume of the BZX series discussed in terms of various structural and elastic properties. The glass-coded BZ15 was found to be the best candidate for the sound-resistant applications based on the atomic packing fraction and the acoustic impedance studies. With MCNP5 simulation, the mass attenuation coefficient (MAC) values of all the samples were calculated and compared with a theoretical approach using the XCOM program. As the amount of Bi2O3 increases, the linear attenuation coefficient (LAC) increases with it at all energies. The LAC values varied between 0.2805 and 0.5269 cm(-1) for the investigated glasses at 0.81 MeV. BZ30 glass is the more effective shield due to the highest MAC and LAC values", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 152, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2021, "Volume": 136, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 116, "DOI": "10.1140/epjp/s13360-020-01056-6", "DOI Link": "http://dx.doi.org/10.1140/epjp/s13360-020-01056-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000612941600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, MM; Meng, YH; Li, K; Ahmad, T; Chen, N; Xu, Y; Sun, JF; Chuai, MY; Zheng, XH; Yuan, Y; Shen, CY; Zhang, ZQ; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mingming; Meng, Yahan; Li, Ke; Ahmad, Touqeer; Chen, Na; Xu, Yan; Sun, Jifei; Chuai, Mingyan; Zheng, Xinhua; Yuan, Yuan; Shen, Chunyue; Zhang, Ziqi; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward dendrite-free and anti-corrosion Zn anodes by regulating a bismuth-based energizer", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous rechargeable zinc metal batteries display high theoretical capacity along with economical effectiveness, environmental benignity and high safety. However, dendritic growth and chemical corrosion at the Zn anodes limit their widespread applications. Here, we construct a Zn/Bi electrode via in-situ growth of a Bi-based ener-gizer upon Zn metal surface using a replacement reaction. Experimental and theoretical calculations reveal that the Bi-based energizer composed of metallic Bi and ZnBi alloy contributes to Zn plating/stripping due to strong adsorption energy and fast ion transport rates. The resultant Zn/Bi electrode not only circumvents Zn dendrite growth but also improves Zn anode anti-corrosion performance. Specifically, the corrosion current of the Zn/Bi electrode is reduced by 90% compared to bare Zn. Impressively, an ultra-low overpotential of 12 mV and stable cycling for 4000 h are achieved in a Zn/Bi symmetric cell. A Zn-Cu/Bi asymmetric cell displays a cycle life of 1000 cycles, with an average Coulombic efficiency as high as 99.6%. In addition, an assembled Zn/Bi-activated carbon hybrid capacitor exhibits a stable life of more than 50,000 cycles, an energy density of 64 Wh kg-1, and a power density of 7 kW kg-1. The capacity retention rate of a Zn/Bi-MnO2 full cell is improved by over 150% compared to a Zn-MnO2 cell without the Bi-based energizer. Our findings open a new arena for the industrial-ization of Zn metal batteries for large-scale energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 146, "Times Cited, All Databases": 152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 509, "End Page": 517, "Article Number": null, "DOI": "10.1016/j.esci.2022.04.003", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.04.003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001080933700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdullah, M; John, P; Fawy, KF; Manzoor, S; Butt, KY; Abid, AG; Messali, M; Najam-Ul-Haq, M; Ashiq, MN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdullah, Muhammad; John, Peter; Fawy, Khaled Fahmi; Manzoor, Sumaira; Butt, Kashif Younas; Abid, Abdul Ghafoor; Messali, Mouslim; Najam-Ul-Haq, Muhammad; Ashiq, Muhammad Naeem", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile synthesis of the SnTe/SnSe binary nullocomposite via a hydrothermal route for flexible solid-state supercapacitors", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Environmental degradation and energy shortage are the two biggest problems facing the world right now. Because of the limited supply of non-renewable sources, the production of environment-friendly energy and its storage has gained significant importance. Pseudocapacitors have lately caught the interest of energy specialists due to their greater energy/power density and prolonged cycle life. In this work, binding-free SnTe/SnSe (STSS) electrodes deposited onto Ni foam (NF) as the conductive substrate have been developed by a facile hydrothermal route for supercapacitor applications. Several analytical tools were utilized to study the morphological, structural and textural characteristics. The electrochemical results obtained from a three-electrode system suggest that the STSS electrode material exhibits great specific capacitance (C-s) of 1276 F g(-1), specific energy (E-d) of 46.45 W h kg(-1) and specific power (P-d) of 256 W kg(-1) @ 1 A g(-1). The results of C-dl indicate that the STSS (31.28 mF) has a larger C-dl value than those of SnTe (23.22 mF) and SnSe (26.35 mF). The analysis of electrochemical stability indicates that the STSS displays structural stability over 5000 cycles with a maximum capacitance retention of 96%. The Nyquist plot profile displayed a smaller R-ct value for STSS (0.89 ?) than SnSe (1.13 ?) and SnTe (1.97 ?). The symmetric behavior of STSS was determined in 2.0 M potassium hydroxide. The results reveal that this material has a specific capacitance of 537.72 F g(-1) and specific energy of 78.32 W h kg(-1). These findings suggest that the STSS electrode might serve as a potential candidate for supercapacitors and other energy-saving equipment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 80, "Times Cited, All Databases": 80, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2023, "Volume": 13, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 12009, "End Page": 12022, "Article Number": null, "DOI": "10.1039/d3ra01028g", "DOI Link": "http://dx.doi.org/10.1039/d3ra01028g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000971817600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, Q; Yang, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Qiong; Yang, Yi-feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-To superconductivity by mobilizing local spin singlets and possible route to higher To in pressurized La3Ni2O7", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We clarify the pairing mechanism of high-Tc superconductivity in bilayer La3Ni2O7 under high pressure by employing the static auxiliary field Monte Carlo approach to simulate a minimal effective model that contains local d(z)(2) interlayer spin singlets and metallic d(x)(2)-y(2) bands. Superconductivity is induced when the local spin singlet pairs are mobilized and attain long-distance phase coherence by hybridization with the metallic bands. When projected onto realistic Fermi surfaces, it yields a nodeless s-wave gap on the gamma Fermi surface, and extended s-wave gaps of the same (opposite) sign on the alpha (beta) Fermi surface due to its bonding (antibonding) character, with nodes or gap minima along the diagonal direction of the two-dimensional Brillouin zone. We find a dual role of the hybridization that not only induces global phase coherence but also competes with the spin singlet formation. This lead to a tentative phase diagram where T-c varies nonmonotonically with the hybridization, in good correspondence with experimental observations. A roughly linear relation is obtained for realistic hopping and hybridization parameters: T-c approximate to 0.04-0.05J, where J is the interlayer superexchange interaction. We emphasize the peculiar tunability of the bilayer structure and propose that Tc may be further enhanced by hole doping or applying uniaxial pressure along the c axis on superconducting La3Ni2O7. Our work provides reliable numerical evidence for the pairing mechanism of high-T(c )superconductivity in La3Ni2O7 and points out a potential route to achieve even higher T-c.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 60, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 16", "Publication Year": 2023, "Volume": 108, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "L140504", "DOI": "10.1103/PhysRevB.108.L140504", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.108.L140504", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001127396000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhuiyan, MSH; Miah, MY; Paul, SC; Das Aka, T; Saha, O; Rahaman, MM; Sharif, MJI; Habiba, O; Ashaduzzaman, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhuiyan, Md. Shakhawat Hossen; Miah, Muhammed Yusuf; Paul, Shujit Chandra; Das Aka, Tutun; Saha, Otun; Rahaman, Md Mizanur; Sharif, Md Jahidul Islam; Habiba, Ommay; Ashaduzzaman, Md", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of iron oxide nulloparticle using Carica papaya leaf extract: application for photocatalytic degradation of remazol yellow RR dye and antibacterial activity", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Synthesis of iron oxide nulloparticles by the recently developed green approach is extremely promising because of its non-toxicity and environmentally friendly behavior. In this study, nullo scaled iron oxide particles (alpha-Fe2O3) were synthesized from hexahydrate ferric chloride (FeCl3 center dot 6H(2)O) with the addition of papaya (Carica papaya) leaf extract under atmospheric conditions. The synthesis of iron oxide nulloparticles was confirmed by systematic characterization using FTIR, XRD, FESEM, EDX and TGA studies. The removal efficiency of remazol yellow RR dye with the synthesized iron oxide nulloparticles as a photocatalyst was determined along with emphasizing on the parameters of catalyst dosage, initial dye concentration and pH. Increasing the dose of iron oxide nulloparticles enhanced the decolorization of the dyes and a maximum 76.6% dye degradation was occurred at pH 2 after 6 h at a catalyst dose of 0.8 g/L. Unit removal capacity of the photocatalyst was found to be 340 mg/g at dye concentration of 70 ppm and at a catalyst dose of 0.4 g/L. The synthesized nulloparticles showed moderate antibacterial activity against Klebsiella spp., E.Coli, Pseudomonas spp., S.aureus bacterial strains. Although the cytotoxic effect of nulloparticles against Hela, BHK-21 and Vero cell line was found to be toxic at maximum doses but it can be considered for tumor cell damage because it showed excellent activity against the Hela and BHK-21 cell lines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 269, "Times Cited, All Databases": 273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e04603", "DOI": "10.1016/j.heliyon.2020.e04603", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2020.e04603", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568753100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shariati, A; Jung, DW; Mohammad-Sedighi, H; Zur, KK; Habibi, M; Safa, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shariati, Ali; Jung, Dong Won; Mohammad-Sedighi, Hamid; Zur, Krzysztof Kamil; Habibi, Mostafa; Safa, Maryam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stability and Dynamics of Viscoelastic Moving Rayleigh Beams with an Asymmetrical Distribution of Material Parameters", "Source Title": "SYMMETRY-BASEL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this article, vibration of viscoelastic axially functionally graded (AFG) moving Rayleigh and Euler-Bernoulli (EB) beams are investigated and compared, aiming at a performance improvement of translating systems. Additionally, a detailed study is performed to elucidate the influence of various factors, such as the rotary inertia factor and axial gradation of material on the stability borders of the system. The material properties of the beam are distributed linearly or exponentially in the longitudinal direction. The Galerkin procedure and eigenvalue analysis are adopted to acquire the natural frequencies, dynamic configuration, and instability thresholds of the system. Furthermore, an exact analytical expression for the critical velocity of the AFG moving Rayleigh beams is presented. The stability maps and critical velocity contours for various material distributions are examined. In the case of variable density and elastic modulus, it is demonstrated that linear and exponential distributions provide a more stable system, respectively. Furthermore, the results revealed that the decrease of density gradient parameter and the increase of the elastic modulus gradient parameter enhance the natural frequencies and enlarge the instability threshold of the system. Hence, the density and elastic modulus gradients play opposite roles in the dynamic behavior of the system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 166, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 12, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 586, "DOI": "10.3390/sym12040586", "DOI Link": "http://dx.doi.org/10.3390/sym12040586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540222200097", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Siddiqa, S; Begum, N; Hossain, MA; Abrar, MN; Gorla, RSR; Al-Mdallal, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Siddiqa, Sadia; Begum, Naheed; Hossain, Md Anwar; Abrar, M. N.; Gorla, Rama Subba Reddy; Al-Mdallal, Qasem", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of thermal radiation on conjugate natural convection flow of a micropolar fluid along a vertical surface", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article investigates the behavior of conjugate natural convection over a finite vertical surface immersed in a micropolar fluid in the presence of intense thermal radiation. The governing boundary layer equations are made dimensionless and then transformed into suitable form by introducing the non-similarity transformations. The reduced system of parabolic partial differential equations is integrated numerically along the vertical plate by using an implicit finite difference Keller-box method. The features of fluid flow and heat transfer characteristics for various values of micropolar or material parameter, K, conjugate parameter, B, and thermal radiation parameter, R-d, are analyzed and presented graphically. Results are presented for the local skin friction coefficient, heat transfer rate and couple stress coefficient for high Prandtl number. It is found that skin friction coefficient and couple stress coefficient reduces whereas heat transfer rate enhances when the micro-inertia parameter increases. All the physical quantities get augmented with thermal radiation. (C) 2020 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 58, "Times Cited, All Databases": 58, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2021, "Volume": 83, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 74, "End Page": 83, "Article Number": null, "DOI": "10.1016/j.camwa.2020.01.011", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2020.01.011", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609880200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Golewski, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Golewski, Grzegorz Ludwik", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Concrete Composites Based on Quaternary Blended Cements with a Reduced Width of Initial Microcracks", "Source Title": "APPLIED SCIENCES-BASEL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article is devoted to the study of the combined effect of siliceous fly ash (FA), silica fume (SF), and nullosilica (nS) on the cement matrix morphology and size of microcracks occurring in the Interfacial Transition Zone (ITZ) between the coarse aggregate and the cement paste of concrete composites based on ordinary Portland cement (OPC). The manuscript contains analyses of width of microcracks (Wc) occurring in the ITZ area of concretes based on quaternary blended cements and changes in ITZ morphology in the concretes in question. Experiments were planned for four types of concrete. Three of them were composites based on quaternary blended cements (QBC), while the fourth was reference concrete (REF). Based on the observations of the matrices of individual composites, it was found that the REF concrete was characterized by the most heterogeneous structure. However, substitution of part of the cement binder with active pozzolanic additives resulted in a more compact and homogenous structure of the cement matrix in each of the QBC series concretes. Moreover, when analyzing the average Wc values, it should be stated that the modification of the basic structure of the cement matrix present in the REF concrete resulted in a significant reduction of the analyzed parameter in all concretes of the QBC series. For QBC-1, QBC-2, and QBC-3, the Wc values were 0.70 & mu;m, 0.59 & mu;m, and 0.79 & mu;m, respectively, indicating a decrease of 38%, almost 48%, and 30%, respectively, compared with the working condition of concrete without additives. On the basis of the above results, it can therefore be concluded that the proposed modification of the binder composition in the analyzed materials clearly leads to homogenization of the composite structure and limitation of initial internal damages in concrete.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 74, "Times Cited, All Databases": 74, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 13, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7338, "DOI": "10.3390/app13127338", "DOI Link": "http://dx.doi.org/10.3390/app13127338", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001013941000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Khalaf, E; Chatterjee, S; Bultinck, N; Zaletel, MP; Vishwanath, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Khalaf, Eslam; Chatterjee, Shubhayu; Bultinck, Nick; Zaletel, Michael P.; Vishwanath, Ashvin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Charged skyrmions and topological origin of superconductivity in magic-angle graphene", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological solitons, a class of stable nonlinear excitations, appear in diverse domains as in the Skyrme model of nuclear forces. Here, we argue that similar excitations play an important role in a remarkable material obtained on stacking and twisting two sheets of graphene. Close to a magic twist angle, insulating behavior is observed, which gives way to superconductivity on doping. Here, we propose a unifying description of both observations. A symmetry breaking condensate leads to the ordered insulator, while topological solitons in the condensate-skyrmions-are shown to be charge 2e bosons. Condensation of skyrmions leads to a superconductor, whose physical properties we calculate. More generally, we show how topological textures can mitigate Coulomb repulsion and provide a previously unexplored route to superconductivity. Our mechanism not only clarifies why several other moire materials do not show superconductivity but also points to unexplored platforms where robust superconductivity is anticipated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 138, "Times Cited, All Databases": 161, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 7, "Issue": 19, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabf5299", "DOI": "10.1126/sciadv.abf5299", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abf5299", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648332700028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shah, NA; Wakif, A; El-Zahar, ER; Ahmad, S; Yook, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shah, Nehad Ali; Wakif, Abderrahim; El-Zahar, Essam R.; Ahmad, Sohail; Yook, Se-Jin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Numerical simulation of a thermally enhanced EMHD flow of a heterogeneous micropolar mixture comprising (60%)-ethylene glycol (EG), (40%)-water (W), and copper oxide nullomaterials (CuO)", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the past decades, the thermal and rheological properties of nullofluids have attracted much attention from many investigators due to their numerous applications as promising enhanced working fluids. The present numerical analysis intended to evidence the main hydro-thermal and mass transport appearances featuring the convective flows of an exceptional non-homogeneous micropolar mixture (i.e., 60% of ethylene glycol, 40% of pure water, and copper oxide nullomaterials) over an impermeable horizontal electromagnetic surface (i.e., Riga plate), which is heated convectively in the presence of a particular variable heat source. For this purpose, several admissible physical theories and hypotheses are adopted herein to derive the foremost conservation equations based on the renovated Buongiorno's formulation and some more realistic boundary conditions. Further, the leading partial differential equations (PDEs) are transformed into a system of ordinary differential equations (ODEs), which are tacked thereafter numerically using an efficient GDQNRM procedure. After performing multiple validations with the recent literature results, the aspects of the studied EMHD convective micropolar nullofluid flow are spotted accordingly and then discussed comprehensively via multiple figures and tables. As prominent results, it is found that the micropolarity and electrically conducting trends of the nullofluidic medium play an important role in the hastening of the nullofluid motion. Also, it is explored that the thermally enhancing influence of the thermophoresis diffusive mechanism can be reinforced more by the existence of an internal heat source along with an appropriate convective heating process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 102, "Times Cited, All Databases": 102, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 35, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102046, "DOI": "10.1016/j.csite.2022.102046", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2022.102046", "Book DOI": null, "Early Access Date": "MAY 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810888000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sundaresh, A; Väyrynen, J; Lyanda-Geller, Y; Rokhinson, LP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sundaresh, Anullthesh; Vayrynen, Jukka I.; Lyanda-Geller, Yuli; Rokhinson, Leonid P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Diamagnetic mechanism of critical current non-reciprocity in multilayered superconductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A superconducting diode effect was recently reported in Nb/V/Ta superlattices, but the mechanism is not yet clear. Here, the authors study non-reciprocal critical current in Al/InAs nullowires and propose a generic extrinsic mechanism involving field-generated diamagnetic currents, which may explain the earlier Nb/V/Ta results. The suggestion that non-reciprocal critical current (NRC) may be an intrinsic property of non-centrosymmetric superconductors has generated renewed theoretical and experimental interest motivated by an analogy with the non-reciprocal resistivity due to the magnetochiral effect in uniform materials with broken spatial and time-reversal symmetry. Theoretically it has been understood that terms linear in the Cooper pair momentum do not contribute to NRC, although the role of higher-order terms remains unclear. In this work we show that critical current non-reciprocity is a generic property of multilayered superconductor structures in the presence of magnetic field-generated diamagnetic currents. In the regime of an intermediate coupling between the layers, the Josephson vortices are predicted to form at high fields and currents. Experimentally, we report the observation of NRC in nullowires fabricated from InAs/Al heterostructures. The effect is independent of the crystallographic orientation of the wire, ruling out an intrinsic origin of NRC. Non-monotonic NRC evolution with magnetic field is consistent with the generation of diamagnetic currents and formation of the Josephson vortices. This extrinsic NRC mechanism can be used to design novel devices for superconducting circuits.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 42, "Times Cited, All Databases": 42, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 23", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1628, "DOI": "10.1038/s41467-023-36786-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36786-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001016963000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Naher, MI; Naqib, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Naher, M., I; Naqib, S. H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An ab-initio study on structural, elastic, electronic, bonding, thermal, and optical properties of topological Weyl semimetal TaX (X=P, As)", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent days, study of topological Weyl semimetals have become an active branch of physics and materials science because they led to realization of the Weyl fermions and exhibited protected Fermi arc surface states. Therefore, topological Weyl semimetals TaX (X=P, As) are important electronic systems to investigate both from the point of view of fundamental physics and potential applications. In this work, we have studied the structural, elastic, mechanical, electronic, bonding, acoustic, thermal and optical properties of TaX (X=P, As) in detail via first-principles method using the density functional theory. A comprehensive study of elastic constants and moduli shows that both TaP and TaAs possesses low to medium level of elastic anisotropy (depending on the measure), reasonably good machinability, mixed bonding characteristics with ionic and covalent contributions, brittle nature and relatively high Vickers hardness with a low Debye temperature and melting temperature. The minimum thermal conductivities and anisotropies of TaX (X=P, As) are calculated. Bond population analysis supports the bonding nature as predicted by the elastic parameters. The bulk electronic band structure calculations reveal clear semi-metallic features with quasi-linear energy dispersions in certain sections of the Brillouin zone near the Fermi level. A pseudogap in the electronic energy density of states at the Fermi level separating the bonding and the antibonding states indicates significant electronic stability of tetragonal TaX (X=P, As).The reflectivity spectra show almost non-selective behavior over a wide range of photon energy encompassing visible to mid-ultraviolet regions. High reflectivity over wide spectral range makes TaX suitable as reflecting coating. TaX (X=P, As) are very efficient absorber of ultraviolet radiation. Both the compounds are moderately optically anisotropic owing to the anisotropic nature of the electronic band structure. The refractive indices are very high in the infrared to visible range. All the energy dependent optical parameters show metallic features and are in complete accord with the underlying bulk electronic density of states calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 124, "Times Cited, All Databases": 124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5592, "DOI": "10.1038/s41598-021-85074-z", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-85074-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630440000060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rayssi, C; El Kossi, S; Dhahri, J; Khirouni, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rayssi, Ch; El Kossi, S.; Dhahri, J.; Khirouni, K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Frequency and temperature-dependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1-xCo4x/3O3 (0 ≤ x ≤ 0.1)", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The dielectric properties of Ca0.85Er0.1Ti1-xCo4x/3O3 (CETCox) (x = 0.00, 0.05 and 0.10), prepared by a sal-gel method, were systematically characterized. The temperature and frequency dependence of the dielectric properties showed a major effect of the grain and grain boundary. The dielectric constant and dielectric loss of CETCox decreased sharply with increasing frequency. This is referred to as the Maxwell-Wagner type of polarization in accordance with Koop's theory. As a function of temperature, the dielectric loss and the real part of permittivity decreased with increasing frequency as well as Co rate. Indeed, a classical ferroelectric behavior was observed for x = 0.00. The non-ferroelectric state of the grain boundary and its correlation with structure, however, proved the existence of a relaxor behavior for x = 0.05 and 0.10. The complex electric modulus analysis M*(omega) confirmed that the relaxation process is thermally activated. The normalized imaginary part of the modulus indicated that the relaxation process is dominated by the short range movement of charge carriers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 409, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2018, "Volume": 8, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 17139, "End Page": 17150, "Article Number": null, "DOI": "10.1039/c8ra00794b", "DOI Link": "http://dx.doi.org/10.1039/c8ra00794b", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435822200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, SY; Zhu, Z; Mortazavi, M; El-Sherbeeny, AM; Mehrabi, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Shaoyong; Zhu, Zhun; Mortazavi, Mina; El-Sherbeeny, Ahmed M. M.; Mehrabi, Peyman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Analytical Assessment of the Structural Behavior of a Specific Composite Floor System at Elevated Temperatures Using a Newly Developed Hybrid Intelligence Method", "Source Title": "BUILDINGS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The aim of this paper is to study the performance of a composite floor system at different heat stages using artificial intelligence to derive a sustainable design and to select the most critical factors for a sustainable floor system at elevated temperatures. In a composite floor system, load bearing is due to composite action between steel and concrete materials which is achieved by using shear connectors. Although shear connectors play an important role in the performance of a composite floor system by transferring shear force from the concrete to the steel profile, if the composite floor system is exposed to high temperature conditions excessive deformations may reduce the shear-bearing capacity of the composite floor system. Therefore, in this paper, the slip response of angle shear connectors is evaluated by using artificial intelligence techniques to determine the performance of a composite floor system during high temperatures. Accordingly, authenticated experimental data on monotonic loading of a composite steel-concrete floor system in different heat stages were employed for analytical assessment. Moreover, an artificial neural network was developed with a fuzzy system (ANFIS) optimized by using a genetic algorithm (GA) and particle swarm optimization (PSO), namely the ANFIS-PSO-GA (ANPG) method. In addition, the results of the ANPG method were compared with those of an extreme learning machine (ELM) method and a radial basis function network (RBFN) method. The mechanical and geometrical properties of the shear connectors and the temperatures were included in the dataset. Based on the results, although the behavior of the composite floor system was accurately predicted by the three methods, the RBFN and ANPG methods represented the most accurate values for split-tensile load and slip prediction, respectively. Based on the numerical results, since the slip response had a rational relationship with the load and geometrical parameters, it was dramatically predictable. In addition, slip response and temperature were determined as the most critical factors affecting the shear-bearing capacity of the composite floor system at elevated temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 59, "Times Cited, All Databases": 59, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 13, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 799, "DOI": "10.3390/buildings13030799", "DOI Link": "http://dx.doi.org/10.3390/buildings13030799", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000957299600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Essa, FA; Abdullah, AS; Alawee, WH; Alarjani, A; Alqsair, UF; Shanmugan, S; Omara, ZM; Younes, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Essa, F. A.; Abdullah, A. S.; Alawee, Wissam H.; Alarjani, A.; Alqsair, Umar F.; Shanmugan, S.; Omara, Z. M.; Younes, M. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental enhancement of tubular solar still performance using rotating cylinder, nulloparticles' coating, parabolic solar concentrator, and phase change material", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is known to us that the problem of freshwater shortage is constantly exacerbated by the rapid population increase and the great diversity of different industries that need water to continue their work. It is also well known that solar stills are one of the thermal solutions to this problem, but they are disadvantaged by their low productivity. So, this study presents an experimental study to improve the performance of the tubular solar still with rotating drum (TDSS) using nulloparticles' coating, parabolic solar concentrator (PSC), and phase change material (PCM). Different operating variables were tested in this study. This combination of using PSC and PCM is investigated for the first time in TDSS. PSC was used to concentrate the solar rays on the back side of the drum, which raised the evaporation rate. The nulloparticles coating was used to paint the surfaces of the drum and basin still to change the film-wise mechanism of water to drop-wise. In addition, the effect of various rotating speeds of drum on the performance of TDSS was investigated. The experimental results revealed that using the rotating cylinder inside the tubular solar still (TSS) increased the productivity of the distiller as compared to that of the conventional solar still (CSS). Furthermore, the TDSS with nulloparticles' coating provided a productivity of 6650 mL/m(2).day compared to 2800 mL/m(2) .day for the CSS with an enhancement by 137%. Besides, the maximum increase in productivity of TDSS when using PSC and PCM was obtained at 0.3 rpm, where the productivity improvement was around 195% and 218%, respectively. The thermal efficiency of the CSS was around 32-34%. Highest thermal efficiency of the TDSS with PCM was 63.8% at 0.3 rpm. Also, the cost of distilled water of TDSS with nulloparticles' coating, PSC, and PCM is 0.024 $/L compared to 0.029 $/L for the CSS, and the payback time was around 5 and 3 months, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 29, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101705, "DOI": "10.1016/j.csite.2021.101705", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2021.101705", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000791215900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Senkov, ON; Miracle, DB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Senkov, O. N.; Miracle, D. B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Generalization of intrinsic ductile-to-brittle criteria by Pugh and Pettifor for materials with a cubic crystal structure", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two classical criteria, by Pugh and Pettifor, have been widely used by metallurgists to predict whether a material will be brittle or ductile. A phenomenological correlation by Pugh between metal brittleness and its shear modulus to bulk modulus ratio was established more than 60 years ago. Nearly four decades later Pettifor conducted a quantum mechanical analysis of bond hybridization in a series of intermetallics and derived a separate ductility criterion based on the difference between two single-crystal elastic constants, C-12-C-44. In this paper, we discover the link between these two criteria and show that they are identical for materials with cubic crystal structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 108, "Times Cited, All Databases": 110, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4531, "DOI": "10.1038/s41598-021-83953-z", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-83953-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626619500020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kamislioglu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kamislioglu, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Research on the effects of bismuth borate glass system on nuclear radiation shielding parameters", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been an increasing number of research and development activities focusing on the use of different glass systems for their nuclear radiation shielding features. In this study a simulation study has been carried out at a wide photon energy region in order to investigate the radiation protection feature of bismuth borate glasses. This study has been conducted to evaluate the proficiency level of six different glass systems (70-x)B2O3 + xBi(2)O(3) + 15ZnO + 15Na(2)O (where x = 0, 5, 10, 15, 20 and 25 mol%) exposed to photon, charged particle (H-1) and (He+2) and neutron. For this investigation, transmission factors (TF), mass attenuation coefficient (MAC), half value layer (HVL), tenth value layer (TVL), mean free path (MFP), effective atomic number (Zeff), effective electron density (Neff) have been computed. The results confirm that the parameters of the examined glasses MAC, HVL, TVL, MFP, Z(eff), and N-eff are associated with photon energy and chemical composition. In addition, neutron effective cross-sections (Sigma R) have been computed for bismuth borates and it was seen a good harmony. The computations for present samples have been examined over a broad energy range from 0.01 to 20 MeV and theoretical results have been obtained by using MCNPX software for transmission factors. In addition, simulation results have been calculated with the WinXCom program. Furthermore, MSP and PR calculations of the bismuth borate glass have been performed to figure out the radiation shielding features. For that reason, the SRIM code has been used to simulate H-1 and He+2 particles. Considering the results obtained from this research, which examines the radiation protection of bismuth borate glasses, indicates that the best shielding achievement (while the HVL, TVL, MFP, TF have the lowest and the highest (Sigma R) values) is reached at 25% Bi2O3. As can be seen in the results, the addition of bismuth affirms that the use of such glass systems improves the radiation protection feature. In particular, 25%Bi2O3 glass system has been proved to show superior shielding properties for gamma radiation in combination with charged particles. Since the glass sample with the highest bismuth additive is 25% Bi2O3, the most radiation protection effect is also seen in this example. The obtained material has a satisfactory radiation shielding property as bismuth is added to the mixture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 128, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 22, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103844, "DOI": "10.1016/j.rinp.2021.103844", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2021.103844", "Book DOI": null, "Early Access Date": "JAN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000630406800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Modi, S; Yadav, VK; Amari, A; Alyami, AY; Gacem, A; Harharah, HN; Fulekar, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Modi, Shreya; Yadav, Virendra Kumar; Amari, Abdelfattah; Alyami, Abeer Yousef; Gacem, Amel; Harharah, Hamed N.; Fulekar, Madhusudan Hiraman", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic Degradation of Methylene Blue Dye from Wastewater by Using Doped Zinc Oxide nulloparticles", "Source Title": "WATER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "ZnO is a semiconductor material that has important physical and chemical properties, which are frequently and significantly enhanced by the addition of impurities, such as doping. A study of the structural properties of pristine and functionalized (i.e., doped with Antimony and Tungsten) ZnO nulloparticles has been conducted for the photocatalyst-based degradation of methylene blue (MB) dye under both Ultraviolet (UV) and solar light. Authors have used a 1% concentration of dopant for doping purposes. The synthesized materials were characterized for structural analysis, functional group identification, spectroscopic measurements, and morphological examination using X-ray diffraction (XRD), Fourier transform-infrared (FTIR), UV-Vis spectroscopy (UV-Vis), and Field emission scanning electron microscope (FESEM) techniques. XRD analysis confirmed that the synthesized-doped materials retained the wurtzite hexagonal structure with a purity of 99%. Transmission electron microscope (TEM) analysis data reveals the average size of pure ZnO-NPs was found to be 7 nm; after doping the size was found to be increased to 18 nm and 9.55 nm, respectively, for ZnO-W and ZnO-Sb. As per FESEM analysis results, minor morphological changes were observed after doping. The Ultraviolet Differential reflectance spectroscopy UV-DRS study revealed the confirmation of ZnO doping with antimony and tungsten, which exhibited a blue shift. The decrease in the band-gap on doping makes the ZnO-NPs more efficient for photocatalytic applications. The photocatalytic efficiency of pristine and doped ZnO-NPs catalysts for methylene blue photocatalytic degradation (PCD) was analyzed under both UV and solar irradiation. This study analyzed the effect of pH, nullo-photocatalyst dose, and initial dye concentration (ICD) on the PCD of MB. The obtained analytical results showed that the ideal conditions for the PCD of MB dye are as follows: pH = 9, the quantity of the nullo-photocatalyst used was 300 mg/L, and an initial MB dye dose of 10 ppm. These conditions lead to a PCD of about 91% of the MB dye by using ZnO-Sb nullo-photocatalyst on exposure to solar radiation. The reusability study also revealed the stability of nullo-photocatalysts. The current research may pave the way for the removal of hazardous dyes from wastewater discharged by many industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 52, "Times Cited, All Databases": 52, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2023, "Volume": 15, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2275, "DOI": "10.3390/w15122275", "DOI Link": "http://dx.doi.org/10.3390/w15122275", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Water Resources", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001017811200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Massoudi, J; Smari, M; Nouri, K; Dhahri, E; Khirouni, K; Bertaina, S; Bessais, L; Hlil, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Massoudi, Jalel; Smari, Mourad; Nouri, Kamel; Dhahri, Essebti; Khirouni, Kamel; Bertaina, Sylvain; Bessais, Lotfi; Hlil, El Kebir", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic and spectroscopic properties of Ni-Zn-Al ferrite spinel: from the nulloscale to microscale", "Source Title": "RSC ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This article presents the annealing effect on the structural, elastic, thermodynamic, optical, magnetic, and electric properties of Ni0.6Zn0.4Fe1.5Al0.5O4(NZFAO) nulloparticles (NPs). The samples were successfully synthesized by the sol-gel method followed by annealing of the as-synthesized at 600, 800, 900, 1050, and 1200 degrees C. This approach yielded the formation of a highly crystalline structure with crystallite size ranging from 17 nm to 40 nm. X-ray diffraction (XRD), scanning electron microscopy (SEM) techniques, as well as energy disperse spectroscopy (EDS), Fourier transform infrared (FTIR) and Raman spectroscopy, were used in order to determine the structural and morphological properties of the prepared samples. Rietveld XRD refinement reveals that Ni-Zn-Al ferrite nulloparticles crystallize in inverse cubic (Fd3m) spinel structure. Using FTIR spectra, the elastic and thermodynamic properties were estimated. It was observed that the particle size had a pronounced effect on elastic and thermodynamic properties. Magnetic measurements were performed up to 700 K. The prepared ferrite samples present the highest Curie temperature, which decreases with increasing particle size and which is consistent with finite-size scaling. The thickness of the surface shell of about 1 nm was estimated from size-dependent magnetization measurements using the core-shell model. Besides, spin resonullce, magnetostriction, temperature coefficient of resistance (TCR), and electrical resistivity properties have been scientifically studied and appear to be different according to their size. The optical properties of synthesized NZFAO nulloparticles were investigated, and the differences caused by the particle sizes are discussed on the basis of the phonon confinement effect. This effect was also inspected by the Raman analysis. Tuning of the physical properties suggests that the Ni-Zn-Al ferrite samples may be promising for multifunctional diverse applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2020, "Volume": 10, "Issue": 57, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 34556, "End Page": 34580, "Article Number": null, "DOI": "10.1039/d0ra05522k", "DOI Link": "http://dx.doi.org/10.1039/d0ra05522k", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000572299600025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Linden, L; Klein, DK; Kalina, KA; Brummund, J; Weeger, O; Kästner, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Linden, Lennart; Klein, Dominik K.; Kalina, Karl A.; Brummund, Joerg; Weeger, Oliver; Kaestner, Markus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neural networks meet hyperelasticity: A guide to enforcing physics", "Source Title": "JOURNAL OF THE MECHANICS AND PHYSICS OF SOLIDS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present work, a hyperelastic constitutive model based on neural networks is proposed which fulfills all common constitutive conditions by construction, and in particular, is applicable to compressible material behavior. Using different sets of invariants as inputs, a hyperelastic potential is formulated as a convex neural network, thus fulfilling symmetry of the stress tensor, objectivity, material symmetry, polyconvexity, and thermodynamic consistency. In addition, a physically sensible stress behavior of the model is ensured by using analytical growth terms, as well as normalization terms which ensure the undeformed state to be stress free and with zero energy. In particular, polyconvex, invariant-based stress normalization terms are formulated for both isotropic and transversely isotropic material behavior. By fulfilling all of these conditions in an exact way, the proposed physics-augmented model combines a sound mechanical basis with the extraordinary flexibility that neural networks offer. Thus, it harmonizes the theory of hyperelasticity developed in the last decades with the up-to-date techniques of machine learning. Furthermore, the non-negativity of the hyperelastic neural network-based potentials is numerically examined by sampling the space of admissible deformations states, which, to the best of the authors' knowledge, is the only possibility for the considered nonlinear compressible models. For the isotropic neural network model, the sampling space required for that is reduced by analytical considerations. In addition, a proof for the non-negativity of the compressible NeoHooke potential is presented. The applicability of the model is demonstrated by calibrating it on data generated with analytical potentials, which is followed by an application of the model to finite element simulations. In addition, an adaption of the model to noisy data is shown and its extrapolation capability is compared to models with reduced physical background. Within all numerical examples, excellent and physically meaningful predictions have been achieved with the proposed physics-augmented neural network.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 64, "Times Cited, All Databases": 65, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 179, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105363, "DOI": "10.1016/j.jmps.2023.105363", "DOI Link": "http://dx.doi.org/10.1016/j.jmps.2023.105363", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Mechanics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001045887000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chu, YM; Jakeer, S; Reddy, SRR; Rupa, ML; Trabelsi, Y; Khan, MI; Hejazi, HA; Makhdoum, BM; Eldin, SM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chu, Yu-Ming; Jakeer, Shaik; Reddy, S. R. R.; Rupa, M. Lakshmi; Trabelsi, Youssef; Khan, M. Ijaz; Hejazi, Hala A.; Makhdoum, Basim M.; Eldin, Sayed M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Double diffusion effect on the bio-convective magnetized flow of tangent hyperbolic liquid by a stretched nullo-material with Arrhenius Catalysts", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The idea of activation energy appearing in a chemical reaction has been widely applied to the production of biodiesel, hydrogen, oil storage, geothermal manufacturing, base liquid mechanics, oil emulsified, food manufacturing, a significant renewable energy source, as well as sewage systems. This study aims to investigate the resultant repercussions of double diffusion, activation energy, Brownian motion, thermal radiation, thermophoresis, viscous dissipation, magnetic field, and Joule heating on bioconvection of a tangent hyperbolic nullofluid flow over a vertical stretching porous surface containing microbe (gyrotactic microorganisms). The fluid transport equations are converted into ordinary differential equations using appropriate self-similarity variables after being solved using the finite difference method. The impacts of key parameters on the fluid's transport properties are depicted in graphs and tables. When the dimensionless activation energy is higher, the mass transfer rate at the stretched nullomaterial sheet drops. The nullofluid concentration near the sheet minimizes by increasing the porosity parameter value, but the opposite behavior happens far from the sheet.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2023, "Volume": 44, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102838, "DOI": "10.1016/j.csite.2023.102838", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2023.102838", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000964802600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Axelrod, S; Gómez-Bombarelli, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Axelrod, Simon; Gomez-Bombarelli, Rafael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "GEOM, energy-annotated molecular conformations for property prediction and molecular generation", "Source Title": "SCIENTIFIC DATA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Data Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Machine learning (ML) outperforms traditional approaches in many molecular design tasks. ML models usually predict molecular properties from a 2D chemical graph or a single 3D structure, but neither of these representations accounts for the ensemble of 3D conformers that are accessible to a molecule. Property prediction could be improved by using conformer ensembles as input, but there is no large-scale dataset that contains graphs annotated with accurate conformers and experimental data. Here we use advanced sampling and semi-empirical density functional theory (DFT) to generate 37 million molecular conformations for over 450,000 molecules. The Geometric Ensemble Of Molecules (GEOM) dataset contains conformers for 133,000 species from QM9, and 317,000 species with experimental data related to biophysics, physiology, and physical chemistry. Ensembles of 1,511 species with BACE-1 inhibition data are also labeled with high-quality DFT free energies in an implicit water solvent, and 534 ensembles are further optimized with DFT. GEOM will assist in the development of models that predict properties from conformer ensembles, and generative models that sample 3D conformations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 114, "Times Cited, All Databases": 120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2022, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 185, "DOI": "10.1038/s41597-022-01288-4", "DOI Link": "http://dx.doi.org/10.1038/s41597-022-01288-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000784545900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Esedoglu, S; Otto, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Esedoglu, Selim; Otto, Felix", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Threshold Dynamics for Networks with Arbitrary Surface Tensions", "Source Title": "COMMUNICATIONS ON PURE AND APPLIED MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present and study a new algorithm for simulating the N-phase mean curvature motion for an arbitrary set of (isotropic) N(N-1)/2 surface tensions. The departure point is the threshold dynamics algorithm of Merriman, Bence, and Osher for the two-phase case. A new energetic interpretation of this algorithm allows us to extend it in a natural way to the case of N phases, for arbitrary surface tensions and arbitrary (isotropic) mobilities. For a large class of surface tensions, the algorithm is shown to be consistent in the sense that at every time step, it decreases an energy functional that is an approximation (in the sense of Gamma convergence) of the interfacial energy. A broad range of numerical tests shows good convergence properties. An important application is the motion of grain boundaries in polycrystalline materials: It is also established that the above-mentioned large class of surface tensions contains the Read-Shockley surface tensions, both in the two-dimensional and three-dimensional settings.(c) 2015 Wiley Periodicals, Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 123, "Times Cited, All Databases": 130, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 68, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 808, "End Page": 864, "Article Number": null, "DOI": "10.1002/cpa.21527", "DOI Link": "http://dx.doi.org/10.1002/cpa.21527", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351776300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Flaschel, M; Kumar, S; De Lorenzis, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Flaschel, Moritz; Kumar, Siddhant; De Lorenzis, Laura", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Automated discovery of generalized standard material models with EUCLID", "Source Title": "COMPUTER METHODS IN APPLIED MECHANICS AND ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We extend the scope of our recently developed approach for unsupervised automated discovery of material laws (denoted as EUCLID) to the general case of a material belonging to an unknown class of constitutive behavior. To this end, we leverage the theory of generalized standard materials, which encompasses a plethora of important constitutive classes including elasticity, viscosity, plasticity and arbitrary combinations thereof. We show that, based only on full-field kinematic measurements and net reaction forces, EUCLID is able to automatically discover the two scalar thermodynamic potentials, namely, the Helmholtz free energy and the dissipation potential, which completely define the behavior of generalized standard materials. The a priori enforced constraint of convexity on these potentials guarantees by construction stability and thermodynamic consistency of the discovered model; balance of linear momentum acts as a fundamental constraint to replace the availability of stress- strain labeled pairs; sparsity promoting regularization enables the automatic selection of a small subset from a possibly large number of candidate model features and thus leads to a parsimonious, i.e., simple and interpretable, model. Importantly, since model features go hand in hand with the correspondingly active internal variables, sparse regression automatically induces a parsimonious selection of the few internal variables needed for an accurate but simple description of the material behavior. A fully automatic procedure leads to the selection of the hyperparameter controlling the weight of the sparsity promoting regularization term, in order to strike a user-defined balance between model accuracy and simplicity. By testing the method on synthetic data including artificial noise, we demonstrate that EUCLID is able to automatically discover the true hidden material model from a large catalogue of constitutive classes, including elasticity, viscoelasticity, elastoplasticity, viscoplasticity, isotropic and kinematic hardening.(c) 2022 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 405, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 115867, "DOI": "10.1016/j.cma.2022.115867", "DOI Link": "http://dx.doi.org/10.1016/j.cma.2022.115867", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000921592100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tarani, E; Arvanitidis, I; Christofilos, D; Bikiaris, DN; Chrissafis, K; Vourlias, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tarani, Evangelia; Arvanitidis, Ioannis; Christofilos, Dimitrios; Bikiaris, Dimitrios N. N.; Chrissafis, Konstantinos; Vourlias, George", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Calculation of the degree of crystallinity of HDPE/GNPs nullocomposites by using various experimental techniques: a comparative study", "Source Title": "JOURNAL OF MATERIALS SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This work is a comparative study of four different techniques to determine the crystallinity of high-density polyethylene (HDPE) nullocomposites filled with different diameter sizes (5, 15 and 25 mu m) of graphene nulloplatelets (GNPs) at various amounts (0.5-5 wt%). The structure of HDPE/GNPs nullocomposites was extensively studied by using different experimental methods, such as X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy. To further provide a complete comparison, differential scanning calorimetry measurements were utilized to calculate the crystallinity values, while temperature-modulated DSC was employed to investigate the possible mechanism of the different crystalline structures. It was found that these methods can be used to estimate the crystallinity, but the sample parameters and experimental conditions must be taken into consideration. All the techniques showed that the crystallinity depends on GNPs size and content. The distance between dispersed platelets was substantial at low concentrations of GNPs, making it comparatively easy for additional nucleation sites to incorporate the polymer matrix, and the crystal nucleus was simply formed. However, at high concentrations of GNPs, the diffusion of polymer chains to the growing crystallites was hindered by large GNPs particles, despite the formation of additional nucleation sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 93, "Times Cited, All Databases": 95, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 58, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1621, "End Page": 1639, "Article Number": null, "DOI": "10.1007/s10853-022-08125-4", "DOI Link": "http://dx.doi.org/10.1007/s10853-022-08125-4", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911934800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, M; Li, XY; Chen, X; Li, BQ; Kaskel, S; Zhang, Q; Huang, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng; Li, Xi-Yao; Chen, Xiang; Li, Bo-Quan; Kaskel, Stefan; Zhang, Qiang; Huang, Jia-Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoting the sulfur redox kinetics by mixed organodiselenides in high-energy-density lithium-sulfur batteries", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur (Li-S) batteries are considered as a highly promising energy storage system due to their ultrahigh theoretical energy density. However, the sluggish kinetics of the complex multi-electron sulfur redox reactions seriously hinders the actual battery performance especially under practical working conditions. Homogeneous redox mediation, through elaborately designing the additive molecules, is an effective approach to promote the sulfur redox kinetics. Herein a promoter of mixed organodiselenides (mixed-Se) is proposed to comprehensively improve the sulfur redox kinetics following the redox comediation principles. Concretely, diphenyl diselenide promotes the liquid-liquid conversion between polysulfides and the solid-liquid conversion regarding lithium sulfide oxidation to polysulfides, while dimethyl diselenide enhances the liquid-solid conversion regarding lithium sulfide deposition. Consequently, the mixed-Se promoter endows a high discharge capacity of 1002 mAh g-1 with high sulfur loading of 4.0 mg cm-2 384 Wh kg-1 at 0.025 C in 1.5 Ah-level Li-S pouch cells. This work affords an effective kinetic promoter to construct high-energy-density Li-S batteries and inspires molecular design of kinetic promoters toward targeted energy-related redox reactions. , a high capacity retention of 81.6% after 200 cycles at 0.5 C, and a high actual energy density of", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 175, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 44, "End Page": 52, "Article Number": null, "DOI": "10.1016/j.esci.2021.08.001", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2021.08.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078115400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XW; Ma, W; Liang, DH; Cai, WS; Zhao, SY; Zang, ZG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xianwen; Ma, Wen; Liang, Dehai; Cai, Wensi; Zhao, Shuangyi; Zang, Zhigang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance CsPbBr3@Cs4PbBr6/SiO2 nullocrystals via double coating layers for white light emission and visible light communication", "Source Title": "ESCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to their outstanding optoelectronic properties, all-inorganic CsPbBr3 perovskite nullocrystals (NCs) are regarded as excellent materials for various optoelectronic applications. Unfortunately, their practical applications are limited by poor stability against water, heat, and polar solvents. Here, we propose a facile synthesis strategy for CsPbBr3@Cs4PbBr6 NCs via tetraoctylammonium bromide ligand induction at room temperature. The resulting CsPbBr3@Cs4PbBr6 NCs show a high photoluminescence quantum yield of 94%. In order to prevent Cs4PbBr6 from being converted back to CsPbBr3 NCs when exposed to water, a second coating layer of SiO2 is formed on the surface of the CsPbBr3@Cs4PbBr6 NCs by the facile hydrolysis of tetramethoxysilane. The resulting CsPbBr3@Cs4PbBr6/SiO2 NCs with their double coating structure have outstanding stability against not only a polar solvent (ethanol) but also water and heat. The as-prepared CsPbBr3@Cs4PbBr6/SiO2 NCs serve as green emitters in efficient white light-emitting diodes (WLEDs) with a high color rendering index (CRI) of 91 and a high power efficiency 59.87 lm W-1. Furthermore, the use of these WLEDs in visible light communication (VLC) results in a maximum rate of 44.53 Mbps, suggesting the great potential of the reported methods and materials for solidstate illumination and VLC.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 100, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 2, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 646, "End Page": 654, "Article Number": null, "DOI": "10.1016/j.esci.2022.10.005", "DOI Link": "http://dx.doi.org/10.1016/j.esci.2022.10.005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001093164600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Alamdari, S; Ghamsari, MS; Lee, C; Han, W; Park, HH; Tafreshi, MJ; Afarideh, H; Ara, MHM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Alamdari, Sanaz; Ghamsari, Morteza Sasani; Lee, Chan; Han, Wooje; Park, Hyung-Ho; Tafreshi, Majid Jafar; Afarideh, Hosein; Ara, Mohammad Hosein Majles", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Preparation and Characterization of Zinc Oxide nulloparticles Using Leaf Extract of Sambucus ebulus", "Source Title": "APPLIED SCIENCES-BASEL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plants are one of the best sources to obtain a variety of natural surfactants in the field of green synthesizing material. Sambucus ebulus, which has unique natural properties, has been considered a promising material in traditional Asian medicine. In this context, zinc oxide nulloparticles (ZnO NPs) were prepared using S. ebulus leaf extract, and their physicochemical properties were investigated. X-ray diffraction (XRD) results revealed that the prepared ZnO NPs are highly crystalline, having a wurtzite crystal structure. The average crystallite size of prepared NPs was around 17 nm. Green synthesized NPs showed excellent absorption in the UV region as well as strong yellow-orange emission at room temperature. Prepared nulloparticles exhibited good antibacterial activity against various organisms and a passable photocatalytic degradation of methylene blue dye pollutants. The obtained results demonstrated that the biosynthesized ZnO NPs reveal interesting characteristics for various potential applications in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 10, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3620, "DOI": "10.3390/app10103620", "DOI Link": "http://dx.doi.org/10.3390/app10103620", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000541440000281", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Szasz, A; Motruk, J; Zaletel, MP; Moore, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Szasz, Aaron; Motruk, Johannes; Zaletel, Michael P.; Moore, Joel E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chiral Spin Liquid Phase of the Triangular Lattice Hubbard Model: A Density Matrix Renormalization Group Study", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Motivated by experimental studies that have found signatures of a quantum spin liquid phase in organic crystals whose structure is well described by the two-dimensional triangular lattice, we study the Hubbard model on this lattice at half filling using the infinite-system density matrix renormalization group (iDMRG) method. On infinite cylinders with finite circumference, we identify an intermediate phase between observed metallic behavior at low interaction strength and Mott insulating spin-ordered behavior at strong interactions. Chiral ordering from spontaneous breaking of time-reversal symmetry, a fractionally quantized spin Hall response, and characteristic level statistics in the entanglement spectrum in the intermediate phase provide strong evidence for the existence of a chiral spin liquid in the full two-dimensional limit of the model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 22", "Publication Year": 2020, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 21042, "DOI": "10.1103/PhysRevX.10.021042", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.10.021042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000535192400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maghrabie, HM; Mohamed, ASA; Fahmy, AM; Samee, AAA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maghrabie, Hussein M.; Mohamed, A. S. A.; Fahmy, Amany M.; Samee, Ahmed A. Abdel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance enhancement of PV panels using phase change material (PCM): An experimental implementation", "Source Title": "CASE STUDIES IN THERMAL ENGINEERING", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In the present study, cooling of a photovoltaic (PV) panel using a phase change material (PCM) of paraffin wax RT-42 attached to a panel back surface is experimentally investigated. Two identical PV panels having a maximum electrical generated power of 40 W are employed to perform the outdoor experiments: a reference PV panel (PVr) and another integrated with PCM (PV-PCM). The current implementation is conducted with different thicknesses of PCM (1, 2, and 3 cm) varying the tilt angle of PV panels at 15 degrees, 20 degrees, 25 degrees, and 30 degrees. The infrared thermal camera is used to record the temperature distribution over the front surface of the PVr and PV-PCM panels. Results indicate that the highest temperature distribution appeared at the upper portion of the PV panels, whereas the lower part of the PV panels shows the lowest temperature distribution. At a tilt angle of 15 degrees, the temperature at the panel's top side is higher than that of the bottom side by 17.1%, 15.7%, and 13.2% for PCM thickness of 1, 2, and, 3 cm, respectively. There is also enhancement in the electrical power output of 15.8% for the PV-PCM panel with a 3 cm PCM thickness over the reference panel (PVr) at a tilt angle of 30 degrees. Relatedly, elevating the tilt angle from 15 degrees to 30 degrees improves the electrical efficiency of PV-PCM with a 3 cm thickness of the PCM by 7.4%. Finally, using PCM with a thickness of 3 cm enhances the electrical efficiency of the PV-PCM panel by 14.4% compared to that for the PVr at a tilt angle of 30 degrees.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 50, "Times Cited, All Databases": 51, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 42, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102741, "DOI": "10.1016/j.csite.2023.102741", "DOI Link": "http://dx.doi.org/10.1016/j.csite.2023.102741", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Thermodynamics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000926225000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, RC; Wang, JF; Qiu, TS; Han, YJ; Fu, XM; Shi, YZ; Liu, XS; Liu, TH; Zhang, ZT; Chu, ZT; Qiu, CW; Qu, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Ruichao; Wang, Jiafu; Qiu, Tianshuo; Han, Yajuan; Fu, Xinmin; Shi, Yuzhi; Liu, Xingsi; Liu, Tonghao; Zhang, Zhongtao; Chu, Zuntian; Qiu, Cheng-Wei; Qu, Shaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Remotely mind-controlled metasurface via brainwaves", "Source Title": "ELIGHT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The power of controlling objects with mind has captivated a popular fascination to human beings. One possible path is to employ brain signal collecting technologies together with emerging programmable metasurfaces (PM), whose functions or operating modes can be switched or customized via on-site programming or pre-defined software. Nevertheless, most of existing PMs are wire-connected to users, manually-controlled and not real-time. Here, we propose the concept of remotely mind-controlled metasurface (RMCM) via brainwaves. Rather than DC voltage from power supply or AC voltages from signal generators, the metasurface is controlled by brainwaves collected in real time and transmitted wirelessly from the user. As an example, we demonstrated a RMCM whose scattering pattern can be altered dynamically according to the user's brain waves via Bluetooth. The attention intensity information is extracted as the control signal and a mapping between attention intensity and scattering pattern of the metasurface is established. With such a framework, we experimentally demonstrated and verified a prototype of such metasurface system which can be remotely controlled by the user to modify its scattering pattern. This work paves a new way to intelligent metasurfaces and may find applications in health monitoring, 5G/6G communications, smart sensors, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 85, "Times Cited, All Databases": 90, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 11", "Publication Year": 2022, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10, "DOI": "10.1186/s43593-022-00016-0", "DOI Link": "http://dx.doi.org/10.1186/s43593-022-00016-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001093209100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, RY; Petit, L; Franke, DP; Dehollain, JP; Helsen, J; Steudtner, M; Thomas, NK; Yoscovits, ZR; Singh, KJ; Wehner, S; Vandersypen, LMK; Clarke, JS; Veldhorst, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ruoyu; Petit, Luca; Franke, David P.; Dehollain, Juan Pablo; Helsen, Jonas; Steudtner, Mark; Thomas, Nicole K.; Yoscovits, Zachary R.; Singh, Kanwal J.; Wehner, Stephanie; Vandersypen, Lieven M. K.; Clarke, James S.; Veldhorst, Menno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A crossbar network for silicon quantum dot qubits", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The spin states of single electrons in gate-defined quantum dots satisfy crucial requirements for a practical quantum computer. These include extremely long coherence times, high-fidelity quantum operation, and the ability to shuttle electrons as a mechanism for on-chip flying qubits. To increase the number of qubits to the thousands or millions of qubits needed for practical quantum information, we present an architecture based on shared control and a scalable number of lines. Crucially, the control lines define the qubit grid, such that no local components are required. Our design enables qubit coupling beyond nearest neighbors, providing prospects for nonplanar quantum error correction protocols. Fabrication is based on a three-layer design to define qubit and tunnel barrier gates. We show that a double stripline on top of the structure can drive high-fidelity single-qubit rotations. Self-aligned inhomogeneous magnetic fields induced by direct currents through superconducting gates enable qubit address ability and readout. Qubit coupling is based on the exchange interaction, and we show that parallel two-qubit gates can be performed at the detuning-noise insensitive point. While the architecture requires a high level of uniformity in the materials and critical dimensions to enable shared control, it stands out for its simplicity and provides prospects for large-scale quantum computation in the near future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 236, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2018, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar3960", "DOI": "10.1126/sciadv.aar3960", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar3960", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443176100014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Monaco, GT; Fantuzzi, N; Fabbrocino, F; Luciano, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tocci Monaco, Giovanni; Fantuzzi, Nicholas; Fabbrocino, Francesco; Luciano, Raimondo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trigonometric Solution for the Bending Analysis of Magneto-Electro-Elastic Strain Gradient Nonlocal nulloplates in Hygro-Thermal Environment", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nulloplates have been extensively utilized in the recent years for applications in nulloengineering as sensors and actuators. Due to their operative nulloscale, the mechanical behavior of such structures might also be influenced by inter-atomic material interactions. For these reasons, nonlocal models are usually introduced for studying their mechanical behavior. Sensor technology of plate structures should be formulated with coupled mechanics where elastic, magnetic and electric fields interact among themselves. In addition, the effect of hygro-thermal environments are also considered since their presence might effect the nulloplate behavior. In this work a trigonometric approach is developed for investigating smart composite nulloplates using a strain gradient nonlocal procedure. Convergence of the present method is also reported in terms of displacements and electro-magnetic potentials. Results agree well with the literature and open novel applications in this field for further developments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 49, "Times Cited, All Databases": 49, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 567, "DOI": "10.3390/math9050567", "DOI Link": "http://dx.doi.org/10.3390/math9050567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000628358900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Escobedo-Morales, A; Ruiz-López, II; Ruiz-Peralta, MD; Tepech-Carrillo, L; Sánchez-Cantú, M; Moreno-Orea, JE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Escobedo-Morales, A.; Ruiz-Lopez, I. I.; Ruiz-Peralta, M. deL.; Tepech-Carrillo, L.; Sanchez-Cantu, M.; Moreno-Orea, J. E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Automated method for the determination of the band gap energy of pure and mixed powder samples using diffuse reflectance spectroscopy", "Source Title": "HELIYON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An automated method to determine the band gap energy (E-g) of pure and mixed powder compounds using diffuse reflectance spectroscopy is presented. This method is based on a five-step algorithm that mimics the judgment made by an expert analyst in identifying the linear segments in Tauc plots and subsequent estimation of the Eg value. It is demonstrated that the method to estimate Eg by intersecting the straight-line fit of the Tauc segment with the photon energy axis is not appropriate for those samples containing more than one optical absorbing phase because systematic underestimation of the Eg value results. The automated method accounts for such cases by introducing a base line function. The robustness of the implemented algorithm was tested using three model systems, ZnO-Al2O3, ZnO-CoO and ZnO-CdO. The estimated Eg's using the automated method differ in less than 1% than those obtained by its manual counterpart.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 165, "Times Cited, All Databases": 173, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2019, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e01505", "DOI": "10.1016/j.heliyon.2019.e01505", "DOI Link": "http://dx.doi.org/10.1016/j.heliyon.2019.e01505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466970300062", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bhujun, B; Tan, MTT; Shanmugam, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bhujun, Bhamini; Tan, Michelle T. T.; Shanmugam, Anulldan S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Study of mixed ternary transition metal ferrites as potential electrodes for supercapacitor applications", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullocrystallites of three mixed ternary transition metal ferrite (MTTMF) were prepared by a facile solgel method and adopted as electrode material for supercapacitors. The phase development of the samples was determined using Fourier transform infrared (FT-IR) and thermal gravimetric analysis (TG). X-ray diffraction (XRD) analysis revealed the formation of a single-phase spinel ferrite in CuCoFe2O4 (CuCoF), NiCoFe2O4 (NiCoF) and NiCuFe2O4 (NiCuF). The surface characteristics and elemental composition of the nullocomposites have been studied by means of field emission scanning electron microscopy (FESEM), as well as energy dispersive spectroscopy (EDS). The electrochemical performance of the nullomaterials was evaluated using a two-electrode configuration by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic technique in 1 M KOH electrolyte and was found to be in the order of: CuCoF > NiCoF > NiCuF. A maximum specific capacitance of 221 Fg(-1) was obtained with CuCoF at a scan rate of 5 mV s(-1). In addition to an excellent cycling stability, an energy density of 7.9 kW kg(-1) was obtained at a current density of 1 Ag-1. The high electrochemical performance of the MTTMF nullocomposites obtained indicates that these materials are promising electrodes for supercapacitors. (C) 2016 The Authors. Published by Elsevier B. V. This is an open access article under the CC BY-NC-ND license.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 189, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 345, "End Page": 353, "Article Number": null, "DOI": "10.1016/j.rinp.2016.04.010", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2016.04.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417531500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chauhan, A; Verma, R; Kumari, S; Sharma, A; Shandilya, P; Li, XK; Batoo, KM; Imran, A; Kulshrestha, S; Kumar, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chauhan, Ankush; Verma, Ritesh; Kumari, Swati; Sharma, Anulld; Shandilya, Pooja; Li, Xiangkai; Batoo, Khalid Mujasam; Imran, Ahamad; Kulshrestha, Saurabh; Kumar, Rajesh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Photocatalytic dye degradation and antimicrobial activities of Pure and Ag-doped ZnO using Cannabis sativa leaf extract", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile green route has been employed for the synthesis of ZnO and Ag-doped ZnO using Cannabis sativa as a reducing and stabilizing agent. The as-synthesized nulloparticles were characterized and tested for photocatalytic dye degradation and antimicrobial activity. The results suggested that nulloparticles have shown antimicrobial activity against different human pathogenic bacteria (Escherichia coli, Klebsiella pneumonia, MRSA, Pseudomonas aeruginosa, Salmonella typhi, Staphylococcus aureus) and fungal strains (Fusarium spp. and Rosellinia necatrix). Ag-doped nulloparticles comparatively have shown better removal Congo red and methyl orange under visible light. Therefore, green synthesized nulloparticles could have beneficial applications in environmental science and biological field.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2020, "Volume": 10, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7881, "DOI": "10.1038/s41598-020-64419-0", "DOI Link": "http://dx.doi.org/10.1038/s41598-020-64419-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000559780100051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Babbush, R; Wiebe, N; McClean, J; McClain, J; Neven, H; Chan, GKL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Babbush, Ryan; Wiebe, Nathan; McClean, Jarrod; McClain, James; Neven, Hartmut; Chan, Garnet Kin-Lic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-Depth Quantum Simulation of Materials", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum simulation of the electronic structure problem is one of the most researched applications of quantum computing. The majority of quantum algorithms for this problem encode the wavefunction using N Gaussian orbitals, leading to Hamiltonians with O(N-4) second-quantized terms. We avoid this overhead and extend methods to condensed phase materials by utilizing a dual form of the plane wave basis which diagonalizes the potential operator, leading to a Hamiltonian representation with O(N-2) second-quantized terms. Using this representation, we can implement single Trotter steps of the Hamiltonians with linear gate depth on a planar lattice. Properties of the basis allow us to deploy Trotter-and Taylor-series-based simulations with respective circuit depths of O(N-7/2) and (O) over tilde (N-8/3) for fixed charge densities. Variational algorithms also require significantly fewer measurements in this basis, ameliorating a primary challenge of that approach. While our approach applies to the simulation of arbitrary electronic structure problems, the basis sets explored in this work will be most practical for treating periodic systems, such as crystalline materials, in the near term. We conclude with a proposal to simulate the uniform electron gas (jellium) using a low-depth variational ansatz realizable on near-term quantum devices. From these results, we identify simulations of low-density jellium as a promising first setting to explore quantum supremacy in electronic structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 236, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 21", "Publication Year": 2018, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11044, "DOI": "10.1103/PhysRevX.8.011044", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.8.011044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427988900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vijay, S; Haah, J; Fu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vijay, Sagar; Haah, Jeongwan; Fu, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fracton topological order, generalized lattice gauge theory, and duality", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce a generalization of conventional lattice gauge theory to describe fracton topological phases, which are characterized by immobile, pointlike topological excitations, and subextensive topological degeneracy. We demonstrate a duality between fracton topological order and interacting spin systems with symmetries along extensive, lower-dimensional subsystems, which may be used to systematically search for and characterize fracton topological phases. Commutative algebra and elementary algebraic geometry provide an effective mathematical tool set for our results. Our work paves the way for identifying possible material realizations of fracton topological phases.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 385, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 28", "Publication Year": 2016, "Volume": 94, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 235157, "DOI": "10.1103/PhysRevB.94.235157", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.94.235157", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391011000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gross, MF; Schneider, JLG; Wei, Y; Chen, Y; Kalt, S; Kadic, M; Liu, XN; Hu, GK; Wegener, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gross, Michael Fidelis; Schneider, Jonathan Ludwig Guenter; Wei, Yu; Chen, Yi; Kalt, Sebastian; Kadic, Muamer; Liu, Xiaoning; Hu, Genkai; Wegener, Martin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tetramode Metamaterials as Phonon Polarizers", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In classical Cauchy elasticity, 3D materials exhibit six eigenmodes of deformation. Following the 1995 work of Milton and Cherkaev, extremal elastic materials can be classified by the number of eigenmodes, N, out of these six that are easy. Using Greek number words, this leads to hexamode (N = 6), pentamode (N = 5), tetramode (N = 4), trimode (N = 3), dimode (N = 2), and monomode (N = 1) materials. While hexamode materials are unstable in all regards, the possibility of pentamode metamaterials (meta-fluids) has attracted considerable attention throughout the last decade. Here, inspired by the 2021 theoretical work of Wei, Liu, and Hu, microstructured 3D polymer-based tetramode metamaterials are designed and characterized by numerical band-structure calculations, fabricated by laser printing, characterized by ultrasound experiments, and compared to the theoretical ideal. An application in terms of a compact and broadband polarizer for acoustical phonons at ultrasound frequencies is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 73, "Times Cited, All Databases": 73, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 35, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202211801", "DOI Link": "http://dx.doi.org/10.1002/adma.202211801", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950845200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, ZT; Wang, FJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Zengtao; Wang, Fajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Localized Method of Fundamental Solutions for Acoustic Analysis Inside a Car Cavity with Sound-Absorbing Material", "Source Title": "ADVANCES IN APPLIED MATHEMATICS AND MECHANICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This paper documents the first attempt to apply a localized method of fun-damental solutions (LMFS) to the acoustic analysis of car cavity containing sound-absorbing materials. The LMFS is a recently developed meshless approach with the merits of being mathematically simple, numerically accurate, and requiring less com-puter time and storage. Compared with the traditional method of fundamental so-lutions (MFS) with a full interpolation matrix, the LMFS can obtain a sparse banded linear algebraic system, and can circumvent the perplexing issue of fictitious bound-ary encountered in the MFS for complex solution domains. In the LMFS, only circular or spherical fictitious boundary is involved. Based on these advantages, the method can be regarded as a competitive alternative to the standard method, especially for high-dimensional and large-scale problems. Three benchmark numerical examples are provided to verify the effectiveness and performance of the present method for the solution of car cavity acoustic problems with impedance conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 21, "Times Cited, All Databases": 21, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 182, "End Page": 201, "Article Number": null, "DOI": "10.4208/aamm.OA-2021-0197", "DOI Link": "http://dx.doi.org/10.4208/aamm.OA-2021-0197", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Mechanics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000880390000007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qureshi, MZA; Faisal, M; Raza, Q; Ali, B; Botmart, T; Shah, NA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qureshi, M. Zubair Akbar; Faisal, M.; Raza, Qadeer; Ali, Bagh; Botmart, Thongchai; Shah, Nehad Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Morphological nullolayer impact on hybrid nullofluids flow due to dispersion of polymer/CNT matrix nullocomposite material", "Source Title": "AIMS MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The objective of this study is to explore the heat transfer properties and flow features of an MHD hybrid nullofluid due to the dispersion of polymer/CNT matrix nullocomposite material through orthogonal permeable disks with the impact of morphological nullolayer. Matrix nullocomposites (MNC) are high-performance materials with unique properties and design opportunities. These MNC materials are beneficial in a variety of applications, spanning from packaging to biomedical applications, due to their exceptional thermophysical properties. The present innovative study is the dispersion of polymeric/ceramic matrix nullocomposite material on magnetized hybrid nullofluids flow through the orthogonal porous coaxial disks is deliberated. Further, we also examined the numerically prominence of the permeability (A*) function consisting of the Permeable Reynold number associated with the expansion/contraction ratio. The morphological significant effects of these nullomaterials on flow and heat transfer characteristics are explored. The mathematical structure, as well as empirical relations for nullocomposite materials, are formulated as partial differential equations, which are then translated into ordinary differential expressions using appropriate variables. The Runge-Kutta and shooting methods are utilized to find the accurate numerical solution. Variations in skin friction coefficient and Nusselt number at the lower and upper walls of disks, as well as heat transfer rate measurements, are computed using important engineering physical factors. A comparison table and graph of effective nullolayer thermal conductivity (ENTC) and non-effective nullolayer thermal conductivity are presented. It is observed that the increment in nullolayer thickness (0.4-1.6), enhanced the ENTC and thermal phenomena. By the enhancement in hybrid nulloparticles volume fraction (2% to 6%), significant enhancement in Nusselt number is noticed. This novel work may be beneficial for nullotechnology and relevant nullocomponents.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 84, "Times Cited, All Databases": 85, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2022, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 633, "End Page": 656, "Article Number": null, "DOI": "10.3934/math.2023030", "DOI Link": "http://dx.doi.org/10.3934/math.2023030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000868702900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Conti, S; Focardi, M; Iurlano, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Conti, S.; Focardi, M.; Iurlano, F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase field approximation of cohesive fracture models", "Source Title": "ANNALES DE L INSTITUT HENRI POINCARE-ANALYSE NON LINEAIRE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We obtain a cohesive fracture model as Gamma-limit epsilon -> 0, of scalar damage models in which the elastic coefficient is computed from the damage variable v through a function f(epsilon) of the form f(epsilon)(v) = min{1, epsilon(1/2) f(v)}, with f diverging for v close to the value describing undamaged material. The resulting fracture energy can be determined by solving a one-dimensional vectorial optimal profile problem. It is linear in the opening s at small values of s and has a finite limit as s -> infinity. If in addition the function f is allowed to depend on the parameter epsilon, for specific choices we recover in the limit Dugdale's and Griffith's fracture models, and models with surface energy density having a power-law growth at small openings. (C) 2015 Elsevier Masson SAS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 96, "Times Cited, All Databases": 98, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL-AUG", "Publication Year": 2016, "Volume": 33, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1033, "End Page": 1067, "Article Number": null, "DOI": "10.1016/j.anihpc.2015.02.001", "DOI Link": "http://dx.doi.org/10.1016/j.anihpc.2015.02.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380599400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abdullah, OG; Aziz, SB; Rasheed, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abdullah, Omed Gh.; Aziz, Shujahadeen B.; Rasheed, Mariwan A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Structural and optical characterization of PVA:KMnO4 based solid polymer electrolyte", "Source Title": "RESULTS IN PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid polymer electrolyte films of polyvinyl alcohol (PVA) doped with a different weight percent of potassium permanganate (KMnO4) were prepared by standard solution cast method. XRD and FTIR techniques were performed for structural study. Complex formation between the PVA polymer and KMnO4 salt was confirmed by Fourier transform infrared (FTIR) spectroscopy. The description of crystalline nature of the solid polymer electrolyte films has been confirmed by XRD analysis. The UV-Visible absorption spectra were analyzed in terms of absorption formula for non-crystalline materials. The fundamental optical parameters such as optical band gap energy, refractive index, optical conductivity, and dielectric constants have been investigated and showed a clear dependence on the KMnO4 concentration. The observed value of optical band gap energy for pure PVA is about 6.27 eV and decreases to a value 3.12 eV for the film sample formed with 4 wt% KMnO4 salt. The calculated values of refractive index and the dielectric constants of the polymer electrolyte films increase with increasing KMnO4 content. (C) 2016 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 221, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1103, "End Page": 1108, "Article Number": null, "DOI": "10.1016/j.rinp.2016.11.050", "DOI Link": "http://dx.doi.org/10.1016/j.rinp.2016.11.050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389770300197", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Abbas, IA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Abbas, Ibrahim A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Eigenvalue approach in a three-dimensional generalized thermoelastic interactions with temperature-dependent material properties", "Source Title": "COMPUTERS & MATHEMATICS WITH APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A three-dimensional model of the generalized thermoelasticity without energy dissipation under temperature-dependent mechanical properties is established. The modulus of elasticity is taken as a linear function of the reference temperature. The resulting formulation in the context of Green and Naghdi model II is applied to a half-space subjected to a time-dependent heat source and traction free surface. The normal mode analysis and eigenvalue approach techniques are used to solve the resulting non-dimensional coupled equations. Numerical results for the field quantities are given in the physical domain and illustrated graphically. The results are also compared to results obtained in the case of temperature-independent modulus of elasticity. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 105, "Times Cited, All Databases": 105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2014, "Volume": 68, "Issue": 12, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2036, "End Page": 2056, "Article Number": null, "DOI": "10.1016/j.camwa.2014.09.016", "DOI Link": "http://dx.doi.org/10.1016/j.camwa.2014.09.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347758600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XF; Yu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xiaofang; Yu, Tie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Simulating Crystal Structure, Acidity, Proton Distribution, and IR Spectra of Acid Zeolite HSAPO-34: A High Accuracy Study", "Source Title": "MOLECULES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is a challenge to characterize the acid properties of microporous materials in either experiments or theory. This study presents the crystal structure, acid site, acid strength, proton siting, and IR spectra of HSAPO-34 from the SCAN + rVV10 method. The results indicate: the crystal structures of various acid sites of HSAPO-34 deviate from the space group of R3 over bar ; the acid strength inferred from the DPE value likely decreases with the proton binding sites at O(2), O(4), O(1),and O(3), contrary to the stability order in view of the internal energy; the calculated ensemble-averaged DPE is about 1525 kJ/mol at 673.15 K; and the proton siting and the proton distribution are distinctly influenced by the temperature: at low temperatures, the proton is predominulltly located at O(3), while it prefers O(2) at high temperatures, and the proton at O(4) assumedly has the least distribution at 273.15-773.15 K. In line with the neutron diffraction experiment, a correction factor of 0.979 is needed to correct for the calculated hydroxyl stretching vibration (nu(O-H)) of HSAPO-34. It seems that the SCAN meta-GGA method, compensating for some drawbacks of the GGA method, could provide satisfying results regarding the acid properties of HSAPO-34.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 46, "Times Cited, All Databases": 46, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 28, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8087, "DOI": "10.3390/molecules28248087", "DOI Link": "http://dx.doi.org/10.3390/molecules28248087", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biochemistry & Molecular Biology; Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001131451900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Oves, M; Rauf, MA; Aslam, M; Qari, HA; Sonbol, H; Ahmad, I; Zaman, GS; Saeed, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Oves, Mohammad; Rauf, Mohd Ahmar; Aslam, Mohammad; Qari, Huda A.; Sonbol, Hana; Ahmad, Irfan; Zaman, Gaffar Sarwar; Saeed, Mohd", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Green synthesis of silver nulloparticles by Conocarpus Lancifolius plant extract and their antimicrobial and anticancer activities", "Source Title": "SAUDI JOURNAL OF BIOLOGICAL SCIENCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to drug addiction and the emergence of antibiotic resistance in pathogens, the disease load and medication intake have risen worldwide. The alternative treatment for drug-resistant infections is nullo formulation-based antimicrobial agents. The plant extract of Conocarpus Lancifolius fruits was used to synthesize silver nulloparticles in the current study, and it was further employed as an antimicrobial and anticancer agent. nulloparticles have been characterized by UV-visible spectrometer revealed the notable peak of kmax = 410-442 nm, which confirms the reduction of silver ion to elemental silver nulloparticles, and the biological moieties in the synthesis were further confirmed by FTIR analysis. The stability and crystalline nature of materials were approved by XRD analysis and expected the size of the nullomaterials of 21 to 173 nm analyzed by a nullophox particle-size analyzer. In vitro, synthesized materials act as an antibacterial agent against Streptococcus pneumonia and Staphylococcus aureus. The inhibition zones of 18 and 24 mm have been estimated to be antibacterial activity against both bacteria. The potency of up to 100% of AgNPs for bacterial strains was incubated overnight at 60 lg/ml. Based on our results, biogenic AgNPs reveal significant activity against fungal pathogen Rhizopusus stolonifera and Aspergillus flavus that cause leading infectious diseases. Additionally, nullomaterials were biocompatible and demonstrated the potential anticancer activities against MDA MB-231 cells after 24-hour exposure. (c) 2021 The Authors. Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 460, "End Page": 471, "Article Number": null, "DOI": "10.1016/j.sjbs.2021.09.007", "DOI Link": "http://dx.doi.org/10.1016/j.sjbs.2021.09.007", "Book DOI": null, "Early Access Date": "DEC 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Life Sciences & Biomedicine - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000734847800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Patel, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Patel, Piyush K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Device simulation of highly efficient eco-friendly CH3NH3SnI3 perovskite solar cell", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photoexcited lead-free perovskite CH3NH3SnI3 based solar cell device was simulated using a solar cell capacitance simulator. It was modeled to investigate its output characteristics under AM 1.5G illumination. Simulation efforts are focused on the thickness, acceptor concentration and defect density of absorber layer on photovoltaic properties of solar cell device. In addition, the impact of various metal contact work function was also investigated. The simulation results indicate that an absorber thickness of 500 nm is appropriate for a good photovoltaic cell. Oxidation of Sn2+ into Sn4+ was considered and it is found that the reduction of acceptor concentration of absorber layer significantly improves the device performance. Further, optimizing the defect density (10(14) cm(-3)) of the perovskite absorber layer, encouraging results of the J(sc) of 40.14 mA/cm(2), V-oc of 0.93 V, FF of 75.78% and PCE of 28.39% were achieved. Finally, an anode material with a high work function is necessary to get the device's better performance. The high-power conversion efficiency opens a new avenue for attaining clean energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 199, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 4", "Publication Year": 2021, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3082, "DOI": "10.1038/s41598-021-82817-w", "DOI Link": "http://dx.doi.org/10.1038/s41598-021-82817-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000618049600040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin Mobarak, M; Hossain, MS; Chowdhury, F; Ahmed, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin Mobarak, Mashrafi; Hossain, Md Sahadat; Chowdhury, Fariha; Ahmed, Samina", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and characterization of CuO nulloparticles utilizing waste fish scale and exploitation of XRD peak profile analysis for approximating the structural parameters", "Source Title": "ARABIAN JOURNAL OF CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this research, we strived to utilize waste fish scale (labeo rohita) for synthesizing CuO nullo-particles (CuO NPs), which gained much attention due to its distinctive properties and versatile applications. Upon the heat treatment, the collagen content of the fish scale got transformed into gelatin which in turn converted the precursor material into CuO NPs. The X-Ray diffraction (XRD) analysis confirmed the formation of CuO NPs and revealed the structure to be of monoclinic lattice. The structural parameters i.e. crystallite size, lattice parameters, microstrain, dislocation density was evaluated for the synthesized CuO NPs using the XRD data. Scherrer's Method (SM), Scherrer Equation Average Method (SEAM), Linear Straight Line Method (LSLM), Straight Line Passing the Origin Method (SLPOM), Monshi Scherrer Method (MSM), Williamson-Hall Method (WHM), Size-Strain Plot Method (SSPM), Halder-Wagner Method (HWM) was exploited for the estimation of crystallite size. According to the calculations, the crystallite size was found to be 87 nm, 41 nm, 1980 nm, 62 nm, 66 nm, 28 nm, 13 nm, 13 nm respectively and the dislocation density was found to be 1.32 x 10(-4), 5.95 x 10(-4), 0.002 x 10(-4), 2.60 x 10(-4), 2.29 x 10(-4), 12.75 x 10(-4), 59.17 x 10(-4) and 59.17 x 10(-4) respectively. UV-Vis absorption analysis also confirmed the formation of CuO NPs based on the absorption peak at 262 nm (lambda(max)) and Tauc Plot method was used to calculate the optical band gap which was 3.84 eV. Functional group, especially the Cu-O bonding was confirmed by the Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) data. Field Emission Scanning Electron Microscopy (FESEM) showed three different shapes of CuO NPs which was also confirmed by Transmission Electron Microscopy (TEM). Particle size was determined based on FESEM and TEM image using imageJ software and also by the Dynamic Light Scattering (DLS) technique. Thermal analysis showed a four stage weight loss in case of Thermogravimetric (TGA) analysis and three conversion steps was observed in Differential Scanning Calorimetric (DSC) analysis. Such synthesis pathway is evidently green and facile for synthesizing CuO NPs with potentiality of various applications and also utilization of waste fish scale is a perquisite. (C) 2022 The Author(s). Published by Elsevier B.V. on behalf of King Saud University.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 121, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 15, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 104117, "DOI": "10.1016/j.arabjc.2022.104117", "DOI Link": "http://dx.doi.org/10.1016/j.arabjc.2022.104117", "Book DOI": null, "Early Access Date": "JUL 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000870760300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ghandourah, EE; Daikh, AA; Alhawsawi, AM; Fallatah, OA; Eltaher, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ghandourah, Emad E.; Daikh, Ahmed A.; Alhawsawi, Abdulsalam M.; Fallatah, Othman A.; Eltaher, Mohamed A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bending and Buckling of FG-GRNC Laminated Plates via Quasi-3D Nonlocal Strain Gradient Theory", "Source Title": "MATHEMATICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To improve the structural stiffness, strength and reduce the weight of nulloplate structure, functionally graded (FG) graphene-reinforced nullocomposite (GRNC) laminated plates are exploited in this paper. The bending and buckling behaviors of FG-GRNC laminated nulloplates are investigated by using novel quasi-3D hyperbolic higher order shear deformation plate theory in conjunction with modified continuum nonlocal strain gradient theory, which considered both length and material scale parameters. The modified model of Halpin-Tsai is employed to calculate the effective Young's modulus of the GRNC plate along the thickness direction, and Poisson's ratio and mass density are computed by using the rule of mixture. An analytical approach of the Galerkin method is developed to solve governing equilibrium equations of the GRNC nulloplate and obtain closed-form solutions for bending deflection, stress distributions and critical buckling loads. A detailed parametric analysis is carried out to highlight influences of length scale parameter (nonlocal), material scale parameter (gradient), distribution pattern, the GPL weight fraction, thickness stretching, geometry and size of GPLs, geometry of the plate and the total number of layers on the stresses, deformation and critical buckling loads. Some details are studied exclusively for the first time, such as stresses and nonlocality effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 30, "Times Cited, All Databases": 30, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1321, "DOI": "10.3390/math10081321", "DOI Link": "http://dx.doi.org/10.3390/math10081321", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785387000001", "Web of Science Record": "View Full Record in Web of Science" } ]